MIT 5.80 Small-Molecule Spectroscopy and Dynamics, Fall 2008
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- Publication date
- 2008
- Topics
- spectroscopy, harmonic oscillators, matrix, hamiltonian, heisenberg, vibrating rotor, Born-Oppenheimer, diatomics, laser schemes, angular momentum, hund's cases, energy levels, second-order effects, perturbations, Wigner-Eckart, Rydberg-Klein-Rees, rigid rotor, asymmetric rotor, vibronic coupling, wavepackets
- Language
- English
The goal of this course is to illustrate the spectroscopy of small molecules in the gas phase: quantum mechanical effective Hamiltonian models for rotational, vibrational, and electronic structure; transition selection rules and relative intensities; diagnostic patterns and experimental methods for the assignment of non-textbook spectra; breakdown of the Born-Oppenheimer approximation (spectroscopic perturbations); the stationary phase approximation; nondegenerate and quasidegenerate perturbation theory (van Vleck transformation); qualitative molecular orbital theory (Walsh diagrams); the notation of atomic and molecular spectroscopy.
Instructor: Robert Field
View the complete course at: http://ocw.mit.edu/5-80F08
*NOTE: Due to technical difficulties, Lecture 32 is not available.
Album art photograph courtesy of Flickr user Jenny Spadafora. http://www.flickr.com/photos/jspad/
Instructor: Robert Field
View the complete course at: http://ocw.mit.edu/5-80F08
*NOTE: Due to technical difficulties, Lecture 32 is not available.
Album art photograph courtesy of Flickr user Jenny Spadafora. http://www.flickr.com/photos/jspad/
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brewster
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October 31, 2009
Subject: super popular video
I was looking at the "most actively downloading" files on this server tonight and just one of the files is being actively downloaded by 35 people at once. pretty great that this is class and not some pop culture.
-brewster
Subject: super popular video
I was looking at the "most actively downloading" files on this server tonight and just one of the files is being actively downloaded by 35 people at once. pretty great that this is class and not some pop culture.
-brewster
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