CHAPTER XIII FERTILIZERS Fertilizers, or manures, are those materials which either increase the supply of elements in the soil, needed for the growth of plants, or exert a corrective action in making conditions more favorable for the plant's best development. Farm manures are usually mixtures of the excrement and urine of farm animals with stable litter. A distinction is sometimes made between materials which furnish plant food directly, such as nitrates, phosphates and potassium and ammonium salts, and indirect fertilisers like calcium carbonate, which neutralize soil acid as well as serve as plant foods. There are also those which furnish plant food and aid in loosening hard clay, as is *the case with manures. The direct fertilizers containing nitrogen, phosphorus and potassium furnish the elements that are most frequently lacking in soils. Availability.—The value of a fertilizer is usually determined by the per cents of the fertilizing elements and by the solubility of the compounds containing these elements in water or soil acids, also by absence of injurious salts, such as those containing boron or aluminium. Solubility is an obvious measure of avail- ability to plants. The most commonly used, easily available water-soluble salts containing nitrogen are sodium nitrate, ammonium sulphate and calcium cyanamid. Materials in which the nitrogen is available more slowly are manures, legumes ia green manuring, stubble and dead roots of plants. In these, nitrogenous organic matter is gradually broken down into simpler, soluble compounds, by bacterial action. Examples of nitrogenous materials in which the nitrogen is practically unavailable are hair, hoof, horn and leather. These are rich in nitrogen but they are insoluble and decompose very slowly in the soil. The phosphate fertilizers also present considerable variation in solubility. This subject is discussed more fully on page 275. 270