f'^f-f-^fi r_ ™£^ffifc-5« ■» fr^yl^-H** Mfi Q i«tim P^fc 1 . 5 1 ^S^^ji- *W?**flSBtf^ tfi m I Wfo PHILIPPINE WATER SUPPLIES v T5i= BY GEORGE W. HEISE AND A. S. BEHRMAN 152918 MANILA BUREAU OF PRINTING 1918 PHILIPPINE WATER SUPPLIES BY GEORGE W. HEISE AND A. S. BEHRMAN 152918 MANILA BUREAU OF PRINTING 1918 Department of Agriculture ani> Natural Resources Bureau of Science Manila Publication No. 11 Actual date of publication July 25, 1918 CONTENTS Page. Illustrations 5 The Improvement of Philippine Water Supplies 7 Water for Domestic Use 19 Storage and Distribution of Water 30 Purification of Waters 38 Water for Industrial Purposes 51 Mineral Waters 69 Bottled Natural and Carbonated Waters 82 Radioactivity of Philippine Waters 88 Quality of Philippine Waters 94 Methods of Water Examination 102 Interpretation of Water Analyses.... 125 Appendices. The Location of Artesian Wells in the Philippine Islands from a Geologic Viewpoint 195 The Chemical Purification of Swimming Pools 203 Report on Certain Methods of Sterilization of Water Containers.. 212 Bureau of Science Directions for the Collection and Transmission of Water Samples 215 3 ILLUSTRATIONS [The following cuts were kindly loaned by the Bureau of Public Works: Plate II, fig. 2; Plate IV; Plate V; Plate VII, figs. 1 and 2; Plate VIII; Plate IX; Plate X; Plate XI; Plate XII, figs. 1 and 2 ; and Plate XIII, fig. 2 ; and photograph of Plate XV, fig. 2.] Plate I Fig. 1. Typical provincial outhouses. 2. Outhouse in proximity to open well, Taytay, Rizal Province. Plate II Fig. 1. Flowing well, Malolos, Bulacan Province. 2. Surface well lined with earthen tile curbing, near San Miguel, Bula- can Province. Plate III Fig. 1. Open well, Pasay. 2. Open well near municipal building, Taytay. Plate IV Manduriao artesian well, Iloilo. A satisfactory type of pumping well. Plate V Diagrammatic sketch of conditions necessary to secure flowing or pumping wells. Plate VI Fig. 1. Water carriers at a public hydrant, Manila. 2. Carrying water in a bamboo tube; a common provincial method. 3. Transporting jars of water by boat. Plate VII Fig. 1. Pumping plant, Boac water system, Marinduque, Tayabas Province. 2. Hydraulic ram at work on main canal, San Miguel, Tarlac Province. Plate VIII Concrete standpipe on Mira Hill, twenty meters high. Singson waterworks at Vigan, Ilocos Sur. Plate IX Gusher well, Sorsogon. Water rising to a height of over 26 meters. Plate X Spillway of Osmena waterworks dam, Cebu, Cebu Province. Plate XI Osmena waterworks, Cebu water supply, Cebu, Cebu Province. PHILIPPINE WATER SUPPLIES Plate XII Fig. 1. Intake and spillway, Sariaya waterworks, Tayabas Province. 2. Bamboo waterwheel for hoisting irrigation water. Plate XIII Fig, 1. Water wagon used in distributing drinking water to wealthy residents, Iloilo, Iloilo. 2. Fountain containing drinking places, faucets, wash places for laundry purposes, and bathing facilities back of concrete in- closure. Plate XIV Fig. 1. Open stone aqueduct, part of the Spanish water supply system, Lucban, Tayabas Province. 2. Open ditches and gutters, part of the Spanish water supply system, Lucban, Tayabas Province. Plate XV Fig. 1. A stream flowing through Bongabon, Nueva Ecija, a town with malarial index. 2. Sibul Springs bathhouse, Bulacan Province. Plate XVI Fig. 1. Spring on seashore at Cebu, Cebu, completely covered at high tide. 2. Spring during rainy season. Plate XVII Near view of the Salinas salt spring, Salinas. Plate XVIII Fig. 1. Section of a boiler tube entirely closed with scale, taken from a neglected boiler in the provinces. 2. Section of the same tube, showing an iron cleaning rod broken off in an attempt to remove the scale. Plate XIX Fig. 1. Apparatus used in field assay of water supplies. 2. The same, ready for transportation. text figures Fig. 1. The two sides of one card. The top of the obverse is the bottom of the reverse. 2. Decomposition of calcium hypochlorite in water. 3. Plan of apparatus for washing, sterilizing, and filling demijohns used in artesian water distribution. 4. Bureau of Science form No. 41 properly filled out. PHILIPPINE WATER SUPPLIES By G. W. Heise and A. S. Behrman THE IMPROVEMENT OF PHILIPPINE WATER SUPPLIES Perhaps in no single line of endeavor has better progress been made in the Philippines, especially during the last eight or ten years, than in the improvement and development of water supplies. Previous to the American occupation little attention had been paid to the question of obtaining suitable water or of improv- ing public supplies. Many comprehensive studies of existing sources, especially of mineral springs, had been published, 1 1 Among the principal articles before the American occupation dealing with Philippine water supplies, the following may be mentioned (compiled by J. Gonzales-Nunez, chemist, Bureau of Science) : Abella y Casariego, Enrique, Aguas termosulfurosas en las emana- ciones volcanicas subordinadas al Malinao, Islas Filipinas. M. Tello, Ma- drid (1885). Hidrografia en la region del Mayon o Volcan de Albay, Islas Filipinas. M. Tello, Madrid (1885). Hidrografia. La Isla de Biliran y sus azuf rales, Islas Filipinas. M. Tello, Madrid (1885). Hidrografia y aguas termales. Descripcion fisica, geologica y minera de la Isla de Panay, Islas Filipinas. Tipo-litografia Chofre y Ca., Manila (1890). Hydrografia y manantiales. Descripcion fisica, geologica y minera de la Isla de Cebu, Filipinas. M. Tello, Madrid (1885). Manantiales termales en el Monte Maquiling y sus actuales emanaciones volcanicas, Filipinas. M. Tello, Madrid (1885). Abella, Enrique, del Rosario, Anacleto, and de Vera, Jose, Estudio descriptivo de algunas manantiales minerales de Filipinas. Tipo-litografia Chofre y Ca., Manila (1893). Becker, George F., Report on the geology of the Philippine Islands. 21st Ann. Rept., U. S. Geol. Surv. (1901). Centeno y Garcia, Jose, Lagunas del Volcan de Taal, Islas Filipinas. M. Tello, Madrid (1885). Memoria geologico-minera del Archipielago Filipino. M. Tello, Madrid (1876). Noticia acerca de los manantiales termo-minerales de Bamban y de las Salinas del Monte Blanco en Nueva Vizcaya, Filipinas. Manila (1885). Centeno, Jose, del Rosario, Anacleto, and de Vera, Jose, Memoria des- criptiva de los manantiales minero-medicinales de la Isla de Luzon, Fili- pinas. M. Tello, Madrid (1890). De la Cavada y Mendez-Vigo, A., Historia geografica, geologica y esta- distica de las Islas Filipinas. Imprenta Ramirez, Manila (1876). U . it?, :T 7 8 PHILIPPINE WATER SUPPLIES but no great progress had been made in making good water available to the bulk of the population. With comparatively few exceptions the eight million inhabitants of the Archipelago were entirely dependent on surface supplies, such as rivers and shallow wells, which were often dangerously polluted. There was probably not a single artesian well in the Islands. The single municipal supply system worthy of the name in the Phil- ippines, that of Manila, was not installed until 1882. As the water had passed through a well-populated area, it was subject to frequent and dangerous contamination. There was no mod- ern municipal sewage system in the Philippines, not even Manila being adequately provided. Such conditions were typical of the Philippines and lasted for many years after the American occupation. The Director of the Bureau of Health has said: 2 With a few exceptions, the towns throughout the Islands are compelled to get their water from small rivers, springs, wells, irrigation canals, rain water, and any other source where water can be obtained; the rivers usually have towns on both banks for almost their entire length, and as the only system of sewage disposal is the ever-present pig or fly, the ma- jority of the sewage is carried into the river by the first rain, if it has not already been -thrown or deposited there by the people themselves. Springs are never protected, wells are never covered; rain water collected from nipa roofs is not clean and soon becomes filled with mosquito larvae and other insect life. Even where pure water was available, it was frequently care- lessly handled and improperly stored, so that it became unfit to drink. Superstition and customs peculiar to the Philippines have also played a large part toward rendering water supplies unsafe at various times in the past. Pilgrimages were frequently made by thousands of people to places of religious interest, though Jagor. Viajes por Filipinas. Traduccion del aleman por S. Vidal. Aribau Co., Madrid (1876), chapters 7, 8, 9, 13, 19, and 21. Mallat, J., Les Philippines. Bertran (Editor), Paris (1846). Mellado, Sanchez, Estudio de las aguas minerales de Carcar, Cebu, Islas Filipinas (1887). Manuscrito. Montero y Vidal, Jose, El Archipielago Filipino. M. Tello, Madrid (1886), pagina 57, aguas minerales. P. P. Jesuitas, El Archipielago Filipino. Imprenta del Gobierno, Wash- ington (1900). Von Drasche, Richard, Allgemeine Oro- and Hidrographie der Insel Luzon. Fragmente zu einer Geologie der Insel Luzon, Philippinen. Wien, Verlag von Karl Gerold's Sohn (1878). Datos geologicos de la Isla de Luzon, Filipinas. Madrid (1881). 2 Annual Rep. P. I. Bur. Health (1906), 57. IMPROVEMENT OF SUPPLIES 9 these places often lacked proper sanitary facilities to provide for the needs even of their own inhabitants. Thus as many as 10,000 people in one day have visited the shrine at Antipolo, a small town until recently without adequate facilities for sewage dis- posal. The effect of so great an influx of people, many of them seeking relief from contagious diseases, can be readily imagined. To quote again from the records of the Bureau of Health : One of the greatest dangers connected with the pilgrimage [to Antipolo] is the fact that it is customary after visiting the Virgin to bathe in the river which flows by the town. The water for drinking and other domestic purposes is obtained from this river at a point below where the bathing takes place. In order to supply a better drinking water an artesian well has been dug. Unfortunately, the quality of the water is not of the very best, and on account of a slightly disagreeable taste it is almost com- pletely eschewed by the people, who still continue to obtain their water supply from the river. Another source of great danger is the lack of proper facilities for the disposal of human excrements. The sanitary facilities of the town are not nearly sufficient to meet the demands of the great number of persons who go there. Especially in the past, miraculous properties have been attrib- uted to various water sources, notably springs, and many people have come to such places to obtain the supposed benefits to be derived from the waters. In some cases these waters came from highly contaminated sources; in others, the gathering of many people about an unprotected source gave rise to serious contamination. Under such conditions it is not surprising that few Filipinos were free from intestinal parasites and that there were frequent and violent epidemics of water-borne diseases. Though there were, apparently, no serious outbreaks of typhoid fever, this disease was of common occurrence in the Philippines. Cham- berlain 3 reported the typhoid death rate in Manila as 36.8 per 100,000. Terrible outbreaks of cholera occurred, with alarming frequency. Though cholera vibrios have been seldom isolated from drinking water, it is beyond doubt that they can live for protracted periods in water 4 and that water is an important agent in spreading the disease. Dysentery, both amoebic and bacillary, was common. Though the work of Walker 5 and of Walker and Sellards 6 has shown that pathogenic amoebae do not multiply in water and that the forms normally present 3 Chamberlain, W. P., Phil Journ. Sci., Sec. B (1911), 6, 299. 4 School, O., ibid., Sec. B (1914), 9, 479. 5 Walker, E. L., ibid., Sec. B (1911), 6, 259. 6 Walker, E. L., and Sellards, A. W., ibid., Sec. B (1913), 8, 253-331. 10 PHILIPPINE WATER SUPPLIES are not injurious to man, it is certain that cysts can exist almost indefinitely in water. For a long time Manila had the highest infant-mortality rate of any city on record. There are not enough reliable sanitary statistics to enable comparisons to be drawn between Manila and the provinces, but there is no reason to believe that condi- tions were much better outside of Manila. Discussing the infant mortality in Manila, Musgrave has said: 7 The next most important faulty custom consists in the dilution of milk compounds with unsafe water. In our investigation of the causes of death of three hundred babies, it is found that tap water, either with or without boiling, is used as a diluent in most instances. As a majority of the houses of these people are at considerable distances from the nearest faucet, the water is carted by water carriers and kept in earthenware jars or other vessels under the most unsanitary conditions; in many instances whatever safety might be secured by boiling the water is destroyed by the subsequent manipulations and care of the water and by the methods employed in making the dilutions of the milk mixtures. Soon after its establishment the present civil Government instituted measures to improve conditions. Money was appro- priated for the drilling of artesian wells, legislation was enacted to encourage the installation of municipal water systems, doctors and sanitary inspectors were sent to all parts of the Islands, waters were analyzed to determine their potability, studies of water-borne diseases were made, and a general educational cam- paign was conducted. The entire credit for the progress that has been made is not due to any one branch of the Government; the work of different bureaus was coordinate, interdependent, and equally important. The construction of artesian wells and water-supply systems was greatly stimulated by Act 2264 of the Philippine Legis- lature. This Act, which was intended to minimize the cost of water installations to communities and individuals, provides — For drilling artesian wells, for the construction of water supply systems, and for the construction of cisterns where artesian wells cannot be sunk, whenever the provincial boards or municipalities interested shall adopt resolutions for the appropriation of funds covering the cost of one-third of the work, one hundred thousand pesos: Provided, That the Director of Public Works is hereby authorized to drill wells for private individuals upon the payment of one-third of the cost of the work, on condition that the public be allowed the use of the well: Provided, also, That from January first to July first, nineteen hundred and thirteen, in case of failure, when potable water is not found, the provincial board or the municipality 7 Musgrave, W. E., ibid., Sec. B (1913), 8, 465. IMPROVEMENT OP SUPPLIES 11 shall not be obliged to pay part of the expense occasioned: And provided further, That the benefits of this Act shall apply to the special Provinces of Mindoro, Palawan, and Batanes. This Act has been extended, so that its provisions are still in force (August 1917). The first deep well to be constructed by the Insular Govern- ment was installed in 1906, in Mexico, Pampanga. Since that time the Bureau of Public Works alone has constructed over a thousand wells, while provincial governments and private in- dividuals have constructed many more, of which no accurate record has been kept. The work of well-drilling performed by the Bureau of Public Works is summarized in Table I. Table I. — Wells drilled by Bureau of Public Works. Year ended June 30— Deep wells driven. Jet-rig wells driven. Insular expend- iture. 1905 _ 2 3 12 8 11 15 17 41 92 55 103 139 122 Dollars. 6,500 6,000 14, 000 21, 000 55, 000 98, 500 154, 400 154, 500 186, 900 121,300 218,300 215, 900 234,700 1906 1907 :„_ 1908 ._ 1909 112 159 199 104 54 29 1910 ___ 1911 1912 1913 _ 1913 (Julyl-Dec.31) .___ __. _ 1914 1915 „_. _ 1916 It has been estimated 8 that deep-well water is now available to over one-sixth of the entire population of the Islands.? The effect on the public health of the pure water made avail- able has been remarkable. Some towns, where artesian well water is exclusively used, have shown a 50 per cent reduction in mortality. 10 The first artesian waters were looked upon with suspicion, and even now, in some sections, an artesian well furnishing * Vickers, J. W., Quart. Bull. P. I. Bur. Pub. Works (1914), 2, No. 4, 24. 9 It should be stated, however, that the number of people to whom water from deep wells is available is far greater than the number who actually use such water and no other for drinking purposes. Thus a sanitary survey of a certain town»generally considered as being supplied with artesian water showed that all but 3,000 of a total population of 14,800 were dependent on water from surface wells or open water courses. 10 Annual Rep. P. I. Bur. Health (1912), 73. 12 PHILIPPINE WATER SUPPLIES potable water will be abandoned in favor of an open surface well that is almost certainly polluted, but with which the in- habitants are familiar. In general, however, artesian water has grown very rapidly in favor. The increasing employment of protected springs as sources of drinking water is another important contribution to the cause of the improvement of water supplies. This has been made possible, in a large measure, by the legislative Act quoted above. Many towns now obtain their drinking waters from springs through excellent distribution systems. By the protection of watersheds and the construction of stor- age and distribution systems, several rivers have been made the basis of municipal water supplies. Manila installed a new water supply system in 1908, which has had a very beneficial effect on public health. Cebu and Zamboanga also have systems using river water. About 30 towns now have their own water works completed or under construction, and many others have well-developed projects for obtaining such installations. The construction of adequate sewage disposal systems has made some progress, though perhaps not as much as has the development of water supplies. Manila, Baguio, and Cebu now have sewer systems. Soon after the American occupation a large Government fac- tory for the manufacture of ice and distilled water was installed. This plant has a daily production of almost 50,000 kilograms of ice and 20,000 liters of distilled water, in addition to which it offers the largest cold storage facilities in the Islands. Similar installations of smaller capacity have been installed elsewhere by the Federal and Insular authorities, and by private enterprise as well, so that ice and distilled water are now to be obtained in the principal cities throughout the Islands. How- ever, the introduction of distilled water, though a great benefit, was not far-reaching in its effects because it was used only by the foreign-born or by the wealthy Filipino population. The industry of bottling natural, distilled, and carbonated waters has flourished greatly. Owing to improper and careless methods of handling, bottled waters have not been an unmixed blessing. They, too, are used to a large extent only by the well-to-do, so that their effect has been restricted. Health work went hand in hand with the construction program of the Bureau of Public Works. Quarantines were established in times of epidemic, and sanitary regulations were enforced. Wells were sterilized, and their surroundings were cleaned up. In every province work for sanitary improvement was organized. IMPROVEMENT OF SUPPLIES 13 In many towns, notably in Manila and Cebu, dangerous surface wells were filled as soon as better supplies were made available. Methods of sewage disposal on a small scale were devised, and a general educational campaign was conducted. As early as 1909 a complete medical and sanitary survey of a town 31 was undertaken cooperatively between the Bureau of Health, the University of the Philippines, and the Bureau of Science. Sim- ilar studies have been carried on from time to time. 12 Recently sanitary commissions have been established by the Bureau of Health. 13 The work of these commissions, which is carried on with the cooperation of the Bureau of Science, has had great bearing on the problem of water supplies. A com- mission stays in a single town about two months, making a complete sanitary survey. In addition to the collection of vital statistics, the examination of inhabitants for parasites, the estab- lishment of clinics and dispensaries, the formation of clubs and organizations that will stimulate interest in, and keep up the work of, sanitary improvement, considerable work is done that deals directly with water-supply problems. Maps are made, showing the location of all available supplies, all sources are examined biologically, and sanitary improvements are suggested. The work of the sanitary commissions though necessarily slow and confined to limited areas is thorough, and is producing per- manent, beneficial results. The good that is being accom- plished and the bearing of this work on the question of pure water supplies may be inferred from the following : A survey of six towns showed that only 2 per cent of the inhabitants were supplied with privies; in one town in which a sanitary commission had completed its labors 46 per cent of the houses were properly equipped, and privies were available to 58 per cent of the people. The work of the Bureau of Science has kept pace with that previously described. As this Bureau is the central laboratory for all branches of the Insular Government, all the routine exami- nations of water, both chemical and biological, have been per- formed here. Each artesian well, or new source of municipal supply, has been examined by the Bureau of Science before being made available to the public. The Manila water supply "Medical survey of the town of Taytay, Phil. Journ. Sci., Sec. B (1909), 4, 207-299. ' 12 Sanitary survey of the San Jose estate and adjacent properties on Mindoro Island, Philippine Islands, with special reference to the epide- miology of malaria, ibid., Sec. B (1914), 9, 137-197. 13 Long, J. D., Pub. Health Rep. (1916), 31, 2963. 14 PHILIPPINE WATER SUPPLIES has been tested daily for a period of years. In addition to the waters analyzed for different departments of the Government, many more have been examined at the request of private in- dividuals. Instruction in the matters of sanitation has been given to officials of other bureaus. Much valuable information on water-supply problems has been collected and made avail- able through the medium of press bulletins, pamphlets, and the various publications of the Bureau. 14 Studies have been made of the mineral and salt springs 15 of the Philippines. The geolo- gists of the Bureau have given valuable assistance in deciding the location of deep wells and have given material aid in the installation of ne^ water-supply systems. In addition to matters of more or less routine nature, there has been carried on a large amount of investigation and re- search with direct bearing on the development and improve- ment of water supplies. The Manila water supply was the object of intensive study, 16 and plans for its improvement were developed. Of especially great importance have been the con- tributions to the study of water-borne diseases, such as typhoid, dysentery, and cholera. 17 Work has been also done on isolated problems, such as the purification of swimming pools, 18 the development of methods of sterilizing demijohns used for ar- tesian water, 19 and the study and development of methods of analysis. 20 The most important features of the work of the last three years has been a systematic field survey of Philippine water supplies, somewhat similar in character to the water sur- veys made under governmental auspices in the United States. For many practical purposes the field examination of water 14 Cox, A. J., Heise, G. W., and Gana, V. Q., Phil. Journ. Sci., Sec. A (1914), 9, 243-412. Heise, G. W., ibid., Sec. A (1915), 10, 135-170. Edwards, R. T., ibid., Sec. B (1908), 3, 121-128. 16 Cox, A. J., and Dar Juan, T., ibid., Sec. A (1915), 10, 375. Cox, Heise, and Gana, op. cit. 16 Bliss, C. H., Pub. P. I. Bur. Govt. Lab. (1905), No. 20, 10. Walker, E. L., Phil. Journ. Sci., Sec. B (1911), 6, 259. Heise, G. W., ibid., Sec. A (1916), 11, 1. 17 For the details of the work done on these diseases, see the papers cited in Contents and Index. , The Philippine Journal of Science, Volume I (1906) to Volume X (1915). Bur. Sci. Pub. (1917), No. 8. w Heise, G. W., and Aguilar, R. H., Phil. Journ. Sci., Sec. A (1916), 11, 105. Gabel, C. E., ibid., Sec. B (1916), 11, 63. 19 Cf. Appendix, 212. 20 Heise, G. W., and Aguilar, R. H., ibid., Sec. A (1916), 11, 37. Behrman, A. S., ibid., Sec. A (1917), 12, 291. IMPROVEMENT OF SUPPLIES 15 supplies has a number of advantages over the usual routine method of collecting samples at the source and conveying them to a central laboratory for analysis. Cultures for bacteriological examination are made of the water as it emerges from the source. Chemical analysis is completed an hour or two after the sample is drawn. Conse- quently the data obtained in both cases are genuinely representa- tive. More important even than this is the fact that the analyst himself takes the sample and, by means of a careful survey, becomes cognizant of all the factors that must be considered in passing final judgment upon the water under examination. It is true that field determinations are not capable of the refined accuracy of those of the laboratory. Only "approxi- mately quantitative" results are obtained, but for many pur- poses they are all that are necessary. The lines dividing good and bad waters for any purpose are necessarily broad, whether for drinking, for manufacturing, or for irrigation. Accord- ingly a chemical analysis will generally receive the same inter- pretation if the results are varied by 1, 2, 5, or sometimes even 10 per cent. Furthermore any loss in accuracy is more than compensated by the more representative nature of the data secured and by the wealth of other valuable information that would be impossible to obtain in the laboratory. All of these considerations make field work particularly ap- plicable to the Philippines. Water samples are often several weeks in transit before they reach the central laboratory in Manila. In addition, samples in many cases are not taken prop- erly, and the analytical work, when performed, is therefore wasted. The development of a number of projects for municipal water supplies, added to the general and rapidly increasing interest in pure water as related to the public health, made it extremely desirable that field investigations be performed. Accordingly, in 1914, the Bureau of Science took the necessary steps toward the beginning of a systematic water survey. The general plan adopted for the work was that outlined by Leighton, 21 of the United States Geological Survey. Practically no apparatus suitable for the work, however, was available ; the distance from manufacturing centers made impossible the securing of such equipment within a reasonable length of time, and funds for obtaining it were not available. Accordingly the apparatus de- 21 Leighton, M. 0., U. S. Geol. Surv., Water Supply Paper (1905), No. 151. 16 PHILIPPINE WATER SUPPLIES scribed by Leighton was as nearly as possible duplicated by the Bureau of Science mechanics with such changes as the partic- ular conditions here seemed to warrant. Reagents for the chemical work were also unavailable and were, consequently, made in the Bureau of Science laboratory. The first field trip was made in September, 1914, to Mindoro, in connection with a number of projected municipal water sys- tems. This was the beginning of a series of similar investiga- tions, which have been continued, with several interruptions, up to the present time. Owing to the very limited personnel available, it has not been possible to carry on the work as ex- tensively as conditions would warrant, but the results secured thus far have been of such great value that the continuance of the water survey on a larger scale is greatly to be desired. Even if no allowances are made for the many delays due to transportation in the Philippines, the amount of field work that may be actually accomplished within a short time is surprisingly large. During the past year over 300 examinations have been made of waters at their sources, in 8 provinces, approximately one month being spent in each province. Transportation is one of the most difficult features of field work in the Islands. There are three railroads. The largest of these operates on Luzon, north and south of Manila. The second connects the towns of Iloilo and Capiz, on Panay, and the third traverses the east coast of Cebu. A very limited portion of the Islands is thus made accessible. Between the islands, water transportation is naturally the only recourse. Numerous inter- island steamers call at the important ports at more or less regular intervals. Between the small towns, steamers are rare, and small boats, with or without sails, are commonly used. In both cases too much dependence must be placed on weather conditions to make this method of transportation very satis- factory. Land transportation, where available, is usually much more expeditious. In several sections excellent roads permit the use of automobiles. In the remainder of the lowland dis- tricts recourse is had to a variety of wheeled vehicles. In the mountains pack horses and cargadores are used. The equip- ment for field work must, consequently, be of such a nature as to meet the demands put upon it in these varied modes of transportation. Cooperation with the work of other branches of the Govern- ment has! been a notable feature of the water survey. In numerous instances, where waterworks systems were being IMPROVEMENT OF SUPPLIES 17 proposed with little-known sources for their bases, the Bureau of Public Works has been able to obtain from our files the information required, without the expense or delay of a special investigation. In one case, where the choice lay between two sources, and the pipe was already on the ground, the water survey party, which happened to be in the vicinity, was able to show that one of the sources was very desirable, while the other was only river seepage. Again several artesian wells that had been reported unsuccessful and for which payment had been refused because of the alleged poor quality of the water supplied were shown to be satisfactory when analyses were made at the sources during water-survey investigations. In this way several thousand pesos were saved to the Insular Government, as well as assuring a safe source of water to. the inhabitants. The water survey has made another contribution to the public health by its cooperation with the health officials throughout the Islands. In one cholera-infected province, chemical, bio- logical, and sanitary examinations were made of all commonly used or available drinking-water supplies. In this way the health officials were enabled to differentiate between the desirable waters and those that might be expected to spread the scourge. In another province, likewise cholera-afflicted, in which a number of deep-pumping artesian wells had been abandoned on suspi- cion of being infected, field investigations proved the purity of the artesian waters when the wells were properly kept up and showed the polluted condition of the surface wells that held a high place in the public opinion. A plan for the inspection and repair of the pumping wells was recommended to the district health officer, who promptly accepted it and made it a provincial health order at once. In still another province, where a barrio of 2,000 people was entirely dependent upon two polluted sur- face wells, it was possible, with the cooperation of the district health officer, to create sufficient interest to cause an artesian well to be drilled there within the next six months. "Miracu- lous" springs have been shown to be highly polluted sources. Nor is its contribution to public health the only practical application of the water-survey investigations. The industries have been frequently assisted. The choice of waters for boiler or other industrial purposes has in a number of instances been decided from data on file, which had been secured in a previous field examination. It is gratifying to note the appreciation of the work. In one province all the expenses of a month's field investigations were 15291.8 2 18 PHILIPPINE WATER SUPPLIES borne by the provincial government, at its own suggestion. A large industrial corporation has requested a series of investiga- tions, also at its expense. Many letters and resolutions of thanks and appreciation have been received from the various municipalities and provinces where the work of the water survey has been performed. In short, then, the advantages of the water-survey investiga- tions may be summarized as follows : A method is provided for making an intensive study of water supplies. Besides their value per se, these data are extremely useful in a variety of problems related to municipal-water supplies, to the public health, and to the industries. The expense of such a continu- ous and intensive study has been far less than would be attached to separate investigations to secure the same amount of information. From the foregoing it will be seen that field methods of examination are applicable to the Philippines and that the results obtained thus far have proved their value. The water survey of the Philippines, however, has but fairly begun, and if it is to keep pace with the general development more attention should be given ^to this work in the future than has been given in the past. The progress that has been made in recent years in sanita- tion and health conditions has been indeed gratifying, and the improvement noted, though doubtless due to many causes, must have been due in a great measure to the improvement in water supplies. There have been no epidemics of disease in recent years such as those that appeared in times past and decimated the population. Manila has been free from cases of cholera for periods of over a year at a time, and conditions in many provinces have also shown marked improvement. Best of all, there is a large and growing interest among the people them- selves. Local political candidates include measures for the improvement of water supplies as planks in their platforms; provinces have requested and appropriated funds for surveys of water supplies; the Insular Government is loaning money for municipal installations ; the field surveys of the Bureau of Science have made possible, in a number of provinces, the selec- tion of proper bases for municipal systems; private individuals are drilling artesian wells ; and in the larger towns the sale of bottled artesian and spring waters is steadily increasing. WATER FOR DOMESTIC USE The most important question pertaining to water supply prob- lems is obviously the provision of an adequate supply of water suitable for drinking purposes. Even in temperate countries this task is becoming ever more difficult, due largely to an in- creasing population and to a more complex civilization. In the Philippines, as in many tropical countries, the desired result is rendered even more difficult of achievement by the entrance of a number of other factors. Surface supplies, which are hard to protect from pollution, are used in a large measure for do- mestic purposes. In countries with temperate climates epi- demics of water-borne diseases usually decrease in violence with cold weather, owing to inhibition of bacterial growth in water and the freezing of possible avenues of contamination. In the Philippines the pollution of water and the course of an epi- demic may proceed almost unchecked throughout the year. The heavy rains of common occurrence in the tropics wash accumula- tions of filth and decayed material into the surface water, so that the amount of water-borne diseases usually increases with the advent of the rainy season. Other factors that make it difficult to obtain pure water in the Philippines and to keep it uncontaminated are high temperature and humidity, and the resultant stimulation of decay and of bacterial growth ; poverty and low standards of living; and outside of the larger cities, the lack of sanitary improvements. The problem is further com- plicated by the fact that many Philippine waters are so highly mineralized that they are not suitable for drinking purposes. The best water for human consumption is that that is as free as possible from organic matter and that contains only in relatively small amounts the normal mineral ingredients of natural water. Such waters are free from objectionable taste or smell, and besides being low in bacterial content, must be free from all injurious organisms. The amounts of mineral matter may generally, however, be varied within wide limits without producing marked physiological effects. Well-aerated water, the mineral content of which is low, namely, below 300 parts per million, is generally considered to have the best taste. Water that contains more than about 1,000 parts per million of mineral matter in solution is liable to prove laxative or to 19 20 PHILIPPINE WATER SUPPLIES have an exceptional taste, although many waters, notably the waters from mineral springs, containing as high as 2,000 parts per million, are used constantly without deleterious effects. A moderately hard water is probably to be preferred to a very soft one. Though this statement can be hardly regarded as definitely established, much evidence has been brought forward to show that the health of people living in localities where hard water is used is better than that of people using only soft water. For example, it has been claimed that people are stronger and better developed and that the nursing period of mothers lasts longer in places where hard water is used. Waters that are unfit to drink may be divided into two classes, those that are naturally nonpotable and those that have been contaminated or polluted. In the first class are included waters that contain mineral poisons, those that contain excessive amounts of salts or organic matter, or those that are highly charged with gases that impart to the water a disagreeable taste or odor. Mineral poisons are very uncommon, and the other ingredients mentioned generally make water unpalatable, so that this class is of no great significance in its application to domestic supply problems. In the second class — by far the most important — are included waters that contain sewage or industrial waste or decaying animal and vegetable matter. It is the second class of waters with which problems of domestic water supply are chiefly concerned. Under the heading Water for Domestic Use an attempt will be made to classify waters according to their sources, to discuss their importance as domestic supplies, and to give an account of some of the general factors influencing the problem of obtaining water suitable for domestic use in the Philippines. RAIN WATER 22 Because of its softness and freedom from dissolved matter, rain water is exceptionally good for domestic purposes. Es- pecially in those parts of the Philippines where both ground and surface waters are poor in quality, this source should be an important one. The average annual rainfall is so great in most parts of the Islands that, with proper storage systems entire communities may be readily provided with drinking water. 22 In Manila, for example, the average annual rainfall is 194 centimeters (76.4 inches), while in Baguio it is almost 2.5 times as great. For the distribution of rainfall in the Archipelago, see Cox, A. J., Phil. Journ. Sci., Sec. A (1911), 6, 287. WATER FOR DOMESTIC USE 21 Unfortunately faulty methods of collection and storage have made rain water usually a doubtful and frequently a dangerous source of supply. DISTILLED WATER In the past, distilled water has been a much-used source of drinking water, especially among the foreign population. How- ever, in recent years its use in Manila has been supplanted in a great measure by that of artesian well water. Opinion is divided on the comparative values of boiled and distilled water for drinking purposes. If a mineral content is desirable in water, boiled water is undoubtedly better than dis- tilled water. However, there is little evidence to show that the continued use of distilled water is harmful. Unfortunately water when boiled loses most of its air content and acquires a flat taste. The same holds true for distilled water. The deci- dedly objectionable taste that the distilled water sold in the principal Philippine cities has acquired at various times shows further the difficulty involved in keeping oil out of the distillate when water is being distilled on a large scale. As distilled water can be obtained on ship board and in the principal cities, a traveler who has accustomed himself to its peculiar taste fre- quently escapes the minor intestinal disturbances sometimes caused by abruptly changing from one kind of drinking water to another. RIVERS AND WATER COURSES Many of the Philippine water courses are low in dissolved mineral content and are chemically unobjectionable. Water from a well-safeguarded watershed is frequently very desirable for domestic use. In the Philippines, however, it is only in sparsely settled regions or in highland districts, such as Moun- tain Province, that this kind of water is obtainable in quantity from unobjectionable surroundings. In the lowlands the run-off is usually turbid. It may contain large amounts of decaying vegetable and animal matter. Above all, the density of popula- tion along the average water course and the lack of sanitary improvements in most Philippine communities make a high degree of pollution almost inevitable. In many parts of the Philippines rivers and ditches consti- tute a grave menace to health. A large number of towns have water courses flowing through them. These are generally small, subject to tidal variations, and not very clean. Frequently they represent the only sewage system in the town, yet they often J22 PHILIPPINE WATER SUPPLIES furnish water for washing and other household purposes. Bar- ber 23 has shown that they are very often breeding places for malaria mosquitoes (see Plate XIV, fig. 2). SURFACE WELLS Water from shallow wells usually has only a small mineral content and is unobjectionable from a chemical point of view. It is only with great difficulty that such water can be kept pure and uncontaminated. In Illinois 43 per cent of the wells exam- ined recently were condemned. In Indiana over 50 per cent were found polluted, and a recommendation was made that every surface well in the state be abandoned. When such is the opinion expressed in the United States, the general undesir- ability of surface wells in the Philippines must be apparent. The typical surface well in the Philippines is situated in a crowded barrio, very near to human habitations. It is generally open and uncovered and is frequently without casing or curbing, so that the first heavy rain may carry surface debris into it. The few outhouses provided for the disposal of sewage may be only a few feet distant. Animals are usually allowed to run loose in the vicinity. Washing clothes and bathing are com- monly carried on at the wellside, though no adequate drainage for the dirty water is provided. Ordinarily no one vessel is used for drawing water, each comer bringing his own and low- ering it into the well. It is only fair to state that in certain sections, principally among the wealthier residents, surface wells are lined and covered with concrete and are equipped with pumps. But this is exceptional and not the rule, and even in these cases lack of proper methods of sewage disposal and of other sanitary measures in the neighborhood usually nullify the minor precautions instituted at the well. Practically every open surface well examined by the Bureau of Science has been shown to be dangerously polluted. Field bacteriological examination of surf ace- well waters largely used for drinking in seven towns in a certain province showed colony counts averaging 15,000 at the end of twenty-four hours and 25,000 at the end of forty-eight hours. Positive presumptive tests for the presence of the B-. coli group were obtained in every instance. In spite of the many sources of good water made available, especially in recent years, surface wells still furnish a large por- tion of the water used for household purposes in the Philippines, 23 Phil Journ. Sci., Sec. B (1915), 10, 177-247. WATER FOR DOMESTIC USE 23 even in many places where better water is at hand. It cannot be too strongly emphasized that these sources constitute a grave menace to public health. The difficulty of safeguarding surface supplies from contamination is shown by the fact that during cholera epidemics excessive rainfall has increased the number of cholera cases among the people dependent on surface wells. It must be admitted, however, that, especially in isolated districts, great dependence will continue to be placed on surface wells for some time to come. In these cases an effort should be made to enforce sanitary measures that will minimize, if not eliminate, the dangers from drinking surface water. All wells should be cased, curbed, covered with water-tight (preferably cement) tops, and provided with pumps. Adequate drainage should be provided to prevent the accumulation of waste water or surface run-off, washing at the well side should be prohibited, and animals should be kept at a distance. The immediate sur- roundings should be kept clean. Above all, the well should be located as far as possible from a dwelling, stable, or outhouse, as pollution may occur by infiltration through the soil. These steps will improve the quality of the well water, but will not insure purity. A surface-well water is always questionable and should be used only until a safer supply is made available. LAKES 24 In the Philippines lakes are, on the whole, undesirable as a source of drinking water. They are generally small, frequently turbid, and usually subject to contamination. However, they are so few and widely scattered that they have little significance as sources of water for drinking purposes and merit no detailed consideration here. SPRINGS Typical spring waters are usually more highly mineralized than surface water; hence they are more likely to contain chemically objectionable ingredients. They usually contain con- siderable amounts of free carbon dioxide. In consequence they dissolve large quantities of calcium and magnesium carbonate, especially in limestone regions, and are, therefore, "hard" waters. Though the dissolved minerals will usually be much smaller in amount in shallow springs than in those that have passed through more and deeper strata, the quantity even in the latter 34 For a description of the principal Philippine lakes, cf. Pratt, W. E., Phil. Journ. ScL, Sec. A (1916), 11, 223-237: 24 PHILIPPINE WATER SUPPLIES case is usually not prohibitive. There is a great variety and abundance of springs in the Philippines, many of them com- paring favorably with some of the best-known foreign mineral and medicinal springs. A more detailed discussion of the che- mical composition of typical Philippine spring waters will be found further on. Spring waters in the Philippines have been usually found bacteriologically pure at the point of emergence. On the whole they are excellent sources for household use, and it is, therefore, not surprising that many municipal water-supply systems now derive their supply from springs. It should be noted, however, that springs are frequently subject to fluctuations, both in quality and in quantity, and should be carefully studied before they are used indiscriminately. Thus a spring of flow amply to supply a town's needs during the rainy season may be entirely inadequate after a long-continued period of drought. Further- more it frequently happens, especially in limestone formations, that surface seepage may find its way into the underground stream that supplies the spring, thus making the water unfit to drink. Such contamination is usually very hard to detect, as it may only occur at infrequent intervals. In this connection a distinction must be drawn between real springs and those that, in spite of their appearance, are nothing but seepage water from the surface or that are water from a neighboring stream that has worn an underground channel for itself. In the town of Majayjay (Laguna), for example, bacteriological examination of a group of much-used springs on a river bank showed a high degree of bacterial pollution. A close examina- tion of the surroundings revealed the fact that the supposed springs were merely the outlets for the water of a neighboring river, the exact points where the river water entered the soil being discovered. Even when a spring is uncontaminated and chemically unob- jectionable,- certain precautions are necessary to ensure a safe water supply. If possible, the ground above the spring, from which contamination might proceed, should be reserved from settlement. The surroundings of the spring should be kept scrupulously clean and guarded from trespass in much the same way as was described for shallow wells. The outlets should be kept clean and clear of weeds or accumulations of debris. When- ever possible, it should be walled in, so that it cannot become contaminated. When the water is allowed to collect in a basin or reservoir, this should be of stone or concrete and should be WATER FOR DOMESTIC USE 25 covered. An outlet pipe should be provided, from which the water can be obtained without danger of contaminating the entire supply. Adequate drainage for waste water should be, of course, ensured. BORED, DRIVEN, OR PUNCHED WELLS 25 In some parts of the Islands, where water is found at depths not greater than 15 to 17 meters, and where there are no hard strata to be pierced, iron tubes, generally 2 to 4 inches in dia- meter, have been sunk by hand or by horsepower. Such wells are frequently capable of furnishing excellent water, especially if they penetrate clayey materials and are located far enough from habitations so that the danger from surface seepage is minimized. DEEP WELLS 26 In the drilling of wells in the Philippines standard machinery was used for penetrating to great depths; for depths of less than 85 to 90 meters, and in the absence of hard or difficult strata, small, specially designed, hand-power "jet rigs" were employed. Many of the wells drilled in the Philippines are of the flowing type, and most of them are "artesian," in the generally accepted sense of the word ; that is to say, the water in them rises above the level at which it is encountered. Deep-well waters in the Philip- pines have been found as a rule to be more highly mineralized than spring waters. At times the degree of mineralization is sufficient to render the water unserviceable for drinking pur- poses. The principal impurities noted in this connection are abnormally large amounts of common salt and iron. Analyses of typical deep waters will be found in Table XVI. Biologically deep wells have been found very satisfactory, so that, on the whole, they are the most desirable sources of drinking water available for general use in the Philippines at the present time. Flowing wells are to be preferred to the other types of deep wells, not only because they require no pump, but because they are of better biological quality. The water from flowing arte- sian wells in the Philippines is sterile. This was shown by Barber, 27 who found that "the waters from the flowing wells show a remarkably high degree of bacterial purity and may be 25 For a discussion of different types of wells and their relative ad- vantages, see Fuller, M. L., U. S. Geol. Surv., Water Supply Paper (1910), No. 255. 26 For an account of well-drilling operations in the Philippines, see Vickers, J. W., Quart. Bull. P. I. Bur. Pub. Works (1914), 2, No. 4, 24. 27 Barber, M. A., Phil. Journ. Sci, Sec. B (1913), 8, 458. 26 PHILIPPINE WATER SUPPLIES regarded as safe from pollution by pathogenic bacteria," and has been amply corroborated by our field survey of waters. The conclusion is a natural one. Owing to the time the water has been underground and the filtration to which it has been probably subjected, the initial purity of artesian water as it leaves the deep strata may be safely assumed. In a flowing well the pres- sure is outward, so that the ingress of surface waters, which might introduce foreign and contaminating material, is prevented. One of the few precautions or sanitary measures that should be observed with regard to a flowing well is the provision of adequate drainage away from the source. The accumulation of water near a well is unsightly and unsanitary, and it frequently provides breeding places for mosquitoes. An improvement much to be desired in connection with the use of flowing artesian wells deals with the conservation of under- ground water supplies. Almost every well of this type in the Philippines is allowed to flow continuously. In this way not only is the greater part of the water wasted, but the supply for the future is diminished as well. The water-bearing stratum is drained, and the flow of the well gradually diminishes or even ceases entirely. When the flow is much greater than is needed by the community, the outlet should be decreased in size. To place self-closing faucets on artesian wells, so the flow would be stopped when water is not needed, would result not only in the conservation of the ground water, but also in the general sanitary improvement of the surroundings. When flowing wells are not in use the interests of the community require that they be shut off. It is as illogical to permit flowing wells to run continuously and to expect them to maintain their flow as it would be to open the fire hydrants in a city and then expect the pressure to be maintained. 28 Artesian wells are a great asset to a community, and when once they have failed through abuse or neglect, they can be seldom regenerated. Deep pumping wells, though not quite as desirable as flowing wells, usually give very excellent water if the pump is in good condition and if the casing is intact. The results of field bac- teriological examinations indicate that the average pumping well will yield bacteriologically pure or impure water depending on ^Deussen, A., and Dole, R. B., U. S. Geol. Surv., Water Supply Paper (1916);. No. 375, 168. WATER FOR DOMESTIC USE 27 whether or not the pump is protected against, or exposed to, the entrance of contaminating influences. A well that has to be primed occasionally, often with water from sources that are at least questionable, must almost inevitably become contami- nated at some time. Sanitary conditions, in general, at the well- side constitute, of course, a factor not to be neglected, but other things being equal, the condition of the pump may be taken as a fair index of the bacteriological quality of the water. This has been shown in a number of instances by examination of a well water, both when the pump was in poor operating condition and again after repairs had been made and the well had been subjected to a thorough pumping test. The results of the field bacteriological examinations of the water of a number of typical pumping artesian wells will be found in Table XVI. There are two general, preeminent evils, both of them readily obviated, that tend to lessen the value of deep pumping wells in the Philippines. One is the unsanitary condition of the sur- roundings of many wells. The necessity for keeping the sur- roundings of water sources clean has been already mentioned. Though surface seepage does not readily find entrance to a properly constructed well, contamination is always possible through imperfections at the junctions of pipes, especially when the water supply is obtained from some distance below ground level. The greater evil, however, is the general condition of the well equipment in the provinces. In a field investigation covering a large number of towns dependent on deep pumping wells, the proportion of pumps entirely inoperative or in poor condition varied from 25 to 67 per cent. It has been already pointed out that a pump in poor condition is an invitation to pollution. Exposing an otherwise pure water to contamination, or entirely depriving a community of good water, is a real evil and one that is worthy of every effort for its correction. It has been estimated that in the United States alone substitu- tion of pure for impure water supplies would save some 26,000 lives annually. Johnson, 29 in a discussion of water purification, states that pure water in urban (United States) communities alone would prevent 45,000 typhoid cases and 3,000 deaths yearly. No such estimate has been made for the Philippine Islands, but the generally unsatisfactory conditions of water supplies and the difficulty of keeping them pure, due to climatic factors, location, and local customs, make it evident that the preventable 29 Johnson, George A., Eng. Contr. (1917), 47, 46-47. 28 PHILIPPINE WATER SUPPLIES waste of life and resources is enormous. That pure water is one of the first requisites for good health in the tropics is de- monstrated by the fact that, in the Philippines, the improvement of water supplies by the drilling of artesian wells or by the utilization of springs or carefully protected water courses has been invariably followed by a marked decrease in the death rate. In some places, formerly dependent on surface supplies, the introduction and general use of artesian water has been ac- companied by a decrease in death rate as high as 50 per cent. Conditions are still far from satisfactory in many parts of the Archipelago. In too many cases dependence for drinking water is put on the nearest available source, quality often being a consideration of secondary importance. Large areas are still unsupplied with water other than that from dangerous surface wells or unclean water courses. Iloilo, a city of 50,000 inhabitants, is still unsupplied with a municipal water supply or with an adequate sewage system. Many towns now unsupplied have easily accessible sources of pure water, which might be utilized at small expense. It has been estimated 30 that from 80 to 96 per cent of the Filipinos are afflicted with intestinal parasites. The Director of the Bureau of Health in a recent statement to the press 31 has said that reports from six towns show infection with intestinal parasites ranging from 94.9 to 100 per cent. There can be little question that impure water is a great factor in bringing about such a state of affairs. The lack of proper methods for the disposal of human ex- creta 32 is a great obstacle in the way of securing suitable drink- 30 Garrison, P. E., Leynes, R., and Llamas, R., Phil. Journ. ScL, Sec. B (1909), 4, 261. "Manila Daily Bulletin, July, 1917. 32 Voy a hablaros de dos costumbres de los moros, que tienen intima relacion con la sanitacion: La de defecar en el agua y lavarse despues, no importando que el sitio sea el del manantial en que se provean del agua de beber. Cuando muere un moro los "panditas," que son los sacerdotes, se hacen cargo del cadaver, le banan bien y le exprimen el abdomen mientras haya liquido que le saiga por la boca y por el ano, y despues le envuelven en una tela blanca; terminada esta operacion, la familia del muerto, con los "panditas" y hasta los curiosos, se ponen a comer al rededor del cadaver. Esta costumbre ha sido causa de la pro- pagaeion rapida de varias enfermedades, especialmente de colera. [Fa- jar do, Jacobo, El problema sanitario en Mindanao y Sulu, Actas, Memorias y Comunicaciones de la Tercera Asamblea Regional de Medicos y Farma- ceuticos de Filipinas (1917), 297.] WATER FOR DOMESTIC USE 29 ing water and is one of the most serious menaces to public health in the Philippines. In six towns recently examined, only 28 houses with flush closets and 251 with other types of privies were found; in other words, only one home in fifty was so equipped. In poorer and more isolated communities this state of affairs is even worse. However, great progress has been made, and it is to be hoped that this progress will continue. With the advance of education and the improvement in standards of living, a corresponding improvement in water supplies may be confidently predicted. STORAGE AND DISTRIBUTION OF WATER Storage of water in large quantities has been practiced since the earliest times of which we have authentic record. The pre- historic reservoirs in New Mexico and Arizona, the remains of tanks and cisterns in India, and the installations of the Egyptians, Carthaginians, Greeks, and Romans show what stress was laid by the ancients both on the quantity and on the quality of water. An idea of the vastness of some of the ancient projects may be derived from the fact that a reservoir in Ceylon, built in 460 after Christ and recently restored, holds a body of water 6 meters (20 feet) deep, having a surface area of 1,800 hectares (7 square miles). Storage is necessary, because of the fluctuations in quantity of the average source of supply and because of the variation in the average community's demand for water, depending on the season or on the time of day. Especially in countries like the Philippines, where the rainfall occurs, for the most part, during three or four months of the year, water must be stored during the wet periods to ensure an abundant supply during the dry season. Storage, in general, would be desirable, even if not necessary, because of the improvement in quality generally effected in the water. This factor will be discussed more at length under Purification. In the Philippines storage of water on a large scale is prac- ticed in only three cities, namely, Manila, Cebu, and Zamboanga. In each case two types of reservoir are represented: an im- pounding reservoir, in which water is stored by means of a dam thrown across a river ; and a service reservoir, in which the water is kept prior to its entrance into the distribution system. These installations, together with some of the more important smaller systems, will be discussed more at length later on. In properly constructed municipal systems the impounding reservoir serves to store a raw water, the service reservoir to hold the purified supply. When water from a river is used, it is essential that the reservoir should receive water only from a watershed well protected from contamination. Therefore, when, as is usually the case, a dam is constructed to catch the water in a valley, the site of the reservoir is of great importance. 30 STORAGE AND DISTRIBUTION OF WATER 31 The bottom of the catchment area should be cleared of weeds, rubbish, and other material that will affect the water delete- riously. The reservoir should not be less than from 8 to 10 me- ters deep, in order to inhibit the growth of algae and other water plants that do not grow at greater depths and that may have a harmful influence on the water. For the same reason the sides should be as nearly perpendicular as possible, so that no growths or sediment may adhere to them. The immediate surroundings of a reservoir also require attention. The mar- gins should be kept free from weeds, accumulations of leaves, and other debris ; the adjacent strips of ground should be planted in such a way that the soil will not be washed away and that the water will be protected from dust ; and suitable channels should be provided to prevent contamination from surface drainage. In order to take the greatest advantage of the beneficial effects of storage, the inlet should be placed as far as possible from the outlet. The same precautions hold for service reservoirs as for im- pounding reservoirs. As the former are usually smaller than the latter, they can be constructed with more care and with greater attention to detail. The sides can be made steeper, and special methods can be employed to ensure a uniform period of storage or to prevent stagnation. When only a single reservoir is provided, or when water has not undergone a sufficiently long storage period in the impound- ing reservoir, it is often advantageous to have a reservoir divided into compartments. With this arrangement water will not find its way directly from inlet to oulet. Sedimentation is facilitated, and the major portion of the precipitate collects in the first com- partments and can be removed without interrupting the work of other compartments. Because of the scarcity of good water and the paucity of municipal installations in many, parts of the Philippine Archi- pelago, storage on a small scale, usually of rain water, has been much practiced. In Iloilo, a city of approximately 50,000 people, rain water continues to be one of the chief sources of water for drinking purposes. Every well-constructed house has a gal- vanized iron roof from which the rain water flows into one or more tanks. The town of Capiz has developed a project for catching rain water from the roofs of the principal public build- ings. A reenforced concrete tank with a capacity of a million liters has been recently erected. Even in places where other Waters are available, many people depend in a large measure on rain water. 32 PHILIPPINE WATER SUPPLIES There is no valid objection to the use of properly collected rain water, stored in well-constructed, frequently cleaned cisterns. All of the rain should not be collected; the first portion should be rejected by means of any of a number of automatic mechanical devices constructed for that purpose. A cistern should be made of metal, slate, or concrete rather than of wood. In the first case it must be remembered that rain water has an appreciable solvent action on metals, particularly lead and zinc, and that both of these metals are deleterious to health. The use of copper or nickel-plated iron has been recommended. 33 Cisterns should be closed, to prevent the entrance of contaminating substances, but should be so constructed that they can be cleaned out periodically. Unfortunately the advantages of rain water as a source of water supply are frequently nullified by improper methods of collecting and storage. The rain that falls on a roof, espe- cially one of nipa or thatch, should not be collected until all accumulations of dust or dirt have been thoroughly washed away. All too frequently water becomes foul and stagnant, and the cistern becomes a breeding place for mosquitoes. The common practice of collecting rain water in loosely covered ollas is strongly to be condemned for similar reasons. A settlement or community usually develops at or near a source of good drinking water. As the community enlarges and the chances of contamination increase, water must be carried increasingly greater distances. It is not surprising, therefore, that aqueducts and elaborate distribution systems have been used since very early times. There is great variation in the amount of water required for each inhabitant in different cities. The supply of ancient Rome is estimated as having furnished 1,260 liters (332 gallons) per capita per day. The weighted average per capita consumption of water for representative cities in the United States is 375 liters (100 gallons) per day; English practice is based on an estimated daily consumption of 115 liters (30 gallons) ; figures for Germany vary from 85 liters (22 gallons) to 125 liters (33 gallons). Representative data are not available for the Philippines, not only because of the relative scarcity of municipal installations, but also because very frequently such installations are not used freely and exclusively by all the community to which water is supplied. Manila uses about 225 liters (60 gal- lons) per capita per day. 83 Rideal, S. and E. K., Water Supplies. D. Appleton and Company, New York (1915), 28. STORAGE AND DISTRIBUTION OF WATER 33 Municipal water installations that include elaborate systems of house distribution are restricted in the Philippines to com- paratively few towns. Manila, Baguio, Cebu, and San Pablo (Laguna) are examples of towns well provided in this respect. The more important installations will be discussed later. In some installations water is piped directly to the various houses; in others it is piped only to conveniently located points, whence it may be carried in small containers to the individual homes. In all cases, however, public hydrants are made a part of the system, so that the people who cannot afford house con- nections can secure water free of charge. Such installations have invariably had a great beneficial effect on the health of a community. An interesting type of municipal distribution system is found in the so-called canal towns, notably those on the slopes of Mount Banajao, in Laguna and Tayabas Provinces. Lilio, Nagcarlan, Majayjay, Lucban, Tayabas, and Sariaya are typical towns of this group. By a system installed in the days of the Spanish occupation, the water from mountain springs is brought through ditches and open stone canals to a series of laterals, which dis- tribute the water to all parts of the town (Plate XIV, figs. 1 and 2). These laterals are nothing but open gutters, and not only provide readily accessible sources of water for laundry and other purposes, but frequently furnish a means for disposing of sewage and other refuse. Though these systems may have furnished a better supply of water than that available previous to their installation, they were, on the whole, extremely un- sanitary and decidedly undesirable and dangerous sources of water supply. In addition, these systems have been shown 34 to be excellent breeding places for Anopheles febrifer, the mosquito causing malaria. In view of these facts it is a source of grati- fication to know that the majority of the towns in question have either installed new systems (for instance, Sariaya) or else (for example, Majayjay and Nagcarlan) have well-developed pro- jects for obtaining a better supply. Various other methods of distribution are employed. An in- genious and economical method sometimes used for piping water to a center of population from a source not very distant is by means of a bamboo pipe line. Much of the distilled and artesian water sold in Manila is sent to the consumer by autotrucks in large tanks. The use of these tanks is carefully supervised either by the Federal or the Insular authorities, and satisfactory 34 Barber, M. A., et al., Phil. Journ. Sci., Sec. B (1915), 10, 223. 152918 3 34 PHILIPPINE WATER SUPPLIES results are obtained. A large quantity of water is also dis- tributed in bottles and demijohns. The difficulty encountered in sterilizing containers, especially in some of the smaller com- panies supplying water, has made this method of distribution unsatisfactory in certain instances. In Iloilo, spring water brought from Guimaras in paraos and water from surface wells in the outlying districts are sold from cans or from small tank carts. On the whole, this method is very unsatisfactory, because the surface wells are dangerous sources, and even the initially good water from Guimaras is frequently contaminated before it reaches the consumer. In all cases where house connections are not provided there is necessarily an intermediate carrying of the water from the source to the place of consumption. Unfortunately the con- tainers used for this delivery are not always kept clean, so that a pure water frequently becomes contaminated in transit. The commonest vessel used is a 5-gallon gasoline or oil can. Two of these, slung at opposite ends of a pole, or pinga (Plate VI, fig. 1), constitute a load for a water carrier. The charge for water thus carried depends on the distance; it varies from about 2 to 5 centavos for the cans when a source is near and from 10 to 20 centavos when a source is distant. In the provincial districts the common method of carrying water (Plate VI, fig. 2), especially among the poorer classes, is in a section of bamboo, the joint partitions of which have been removed. These bamboo tubes are easily made and cost practically nothing, while empty oil cans have a considerable market value, which increases with the distance from the large towns. For the sake of completeness brief descriptions of some of the principal Philippine municipal installations are appended. MANILA 35 The water for the municipal supply for Manila comes from an uninhabited, guarded watershed of about 1,550 square kilo- meters (600 square miles). A dam across Mariquina River, above Montalban, about 25 kilometers from Manila, gives a stor- age basin with an estimated capacity of over 4,700,000 cubic me- ters (1,250,000,000 gallons), though this amount is not actually available, owing to leakage through fissures and cracks in the 35 For a more complete discussion, see Heise, G, W., Phil. Journ. Sci^ Sec. A (1916), 11, 1-13. STORAGE AND DISTRIBUTION OP WATER 35 limestone walls of the river gorge. From Montalban the water is piped to the high ground just outside of Manila to a service reservoir, the capacity of which is about 206,000 cubic meters (54,500,000 gallons) ; thence it passes through a large service pipe to Manila, where it enters the main distribution system. In normal times the water supply is adequate for the city's needs; in periods of extended drought, however, it has been occasionally found necessary to resort to the old (Spanish) in- stallation at Santolan, which takes water directly from Mari- quina River, in a well-populated area. The water is not treated in any way until it reaches the exit of the service reservoir, where a small chlorination plant for adding chloride of lime has been installed. The water reaches the main distribution system about forty-five minutes after it has been treated. The new supply system is a tremendous improvement over the old installation. Even before chlorination was introduced, the Bureau of Health 36 pointed out that there were 300 per cent more deaths from intestinal diseases in the years just preceding the installation of the new supply than in the years immediately following and showed 37 further that when the in- adequacy of the Montalban supply made it necessary to resort to the old Santolan system a marked increase in the death rate occurred. However, the city supply is still far from being entirely satisfactory. Though a considerable improvement is effected by storage in the reservoirs, adequate sedimentation and bacterial purification do not occur. Consequently the water as it leaves the reservoir is still somewhat turbid, especially in rainy weather, and has a rather high bacterial content. Chlori- nation has failed to reduce the bacterial content to the extent usually obtained in general practice, owing partly to the turbidity and organic content of the water, partly to irregularities in dosage, and partly to the accumulation of foreign matter in the distribution system. Filter beds, as well as measures to ensure adequate sedimentation, seem to be necessary to ensure good results. CEBU The city of Cebu is supplied by the Osmeiia waterworks, completed in 1912. A reenforced concrete dam and spillway in a narrow gorge at Buhisan, about 6 kilometers from the city, 36 Ann. Rep. P. L Bur. Health (1912), 5. 37 Ibid., 47. 36 PHILIPPINE WATER SUPPLIES impound between 1,000,000 and 1,500,000 cubic meters of water — at least one hundred days' supply. In addition, a con- crete distribution tank holds some 15,000 cubic meters more. This large storage capacity gives ample time for sedimentation and purification. A distribution system with direct house con- nections and a number of public hydrants is provided. With the exception of one occasion, when a large amount of mud accumulated behind the dam, the tap water has been clear and colorless and of a very satisfactory bacteriological quality. ZAMBOANGA The municipal system of Zamboanga derives its water from a river about 10 kilometers from the poblacion. The basin formed by the dam is about 50 meters above sea level. From here the water is led through a 30-inch reenforced concrete pipe to a reservoir about 4 kilometers distant. This reservoir has a capacity of 2,270 cubic meters (600,000 gallons), approx- imately three and two-fifths days' supply for the city. Cast iron pipes conduct the water the remaining 6 kilometers to the town. The intake is cleaned once every five days ; the reservoir, once every ten. In the cfty there are 270 house connections and 53 public hydrants. In this way approximately 5,000 people are supplied, or about 20 per cent of the population of the entire municipality. BAGUIO Baguio, Mountain Province, has a well-developed water-supply system. It derives its water from a series of mountain springs of excellent chemical quality, flowing directly into compara- tively small storage basins, whence the water is pumped to the distribution system. Though the water is unobjectionable in quality during most parts of the year, it is planned to purify it further with an ultra-violet light-sterilizing apparatus. There are many other municipal distribution systems, as the appended tabular data indicate, but most of these present no unusual features that need be discussed here. Most of them employ springs or rivers and operate by gravity, but several use pumping wells with satisfactory results. In addition to the towns listed, all subprovincial capitals in Mountain Province, except Kabugao, have installed small gravity systems. STORAGE AND DISTRIBUTION OP WATER 37 Table II. — Water works completed or under construction in the Philippines. a Town. People served. Source of water. Type of system. Cost. Antipolo Well Pesos. Balayan ._ 4,350 Baguio __ _. Springs. Bani, Pangasinan Boac, Marinduque Calapan 2,000 4,000 River _ _ 18, 000 7,500 Wells- Springs Pump Capiz Rain water 13, 000 547,000 8,500 70,000 Cebu 38,000 2,000 River Gravity Duero _ __ _ Spring Jolo__ ..-_ __ __ Creek Loay ___ __ __ _ Moalbual _ _ 1,500 5,000 600 Spring do _ 15,000 7,000 9,000 Naga __ __ _ ___ ___ _ do ._ do Parang __ _ _______ River _ Pasig-. _______ .__ _ Wells Sariaya__ _ __ _ 4,200 5,000(?) 1,800 8,000 10, 000 5,000 Spring 36, 000 30, 000 8,500 64, 000 116,000 305,000 Sibonga _ _. _ _ do do Subic ... _ do Taal do Vigan ___ do _.. Zamboanga _ River __ _ _ a From data furnished by the Bureau of Public Works. PURIFICATION OF WATERS A water from a source subject to contamination by substances dangerous to health must be treated before it can be used for drinking purposes. Many methods of purification have been devised, the one to be used in any instance depending upon the quantity of water to be treated and the special conditions or factors affecting the problem in hand. Artificial purification of water on .a large scale has been tried in only one case in the Philippines, namely, in Manila, so that any discussion of methods must be necessarily based largely on experience elsewhere. 38 The discussion under Purification of Waters will deal solely with purification of waters for drinking purposes ; the treatment of water for other purposes will be discussed under industrial supplies. Methods of purification have been practiced since very early times. Medical literature written in Sanskrit, perhaps four thousand years ago, contains the following statement: 39 / It is good to keep water in copper vessels, to expose it to sunlight, and to filter it through charcoal. The use of alum for the coagulation of muddy waters has been familiar to the Chinese for thousands of years. Hippocrates, about 400 before Christ, advised boiling and filtering impure water that was intended for drinking purposes. The old Roman aqueducts were even provided with the "castella," a series of chambers that gave excellent opportunity for sedimentation to take place. Purification of water may have reference to the removal of turbidity or color (or odor and taste), to the elimination of in- jurious chemicals or those (for example, iron) causing a dis- agreeable taste, or to the destruction of pathogenic organisms. The principal methods of purification that will be considered here are self-purification, effected by storage, illumination, or aeration; physical methods, such as distillation, boiling, filtra- 35 Cf. Don, J., and Chisholm, J., Modern Methods of Water Purification. Edward Arnold, London (1911). Johnson, G. A., Purification of public water supplies, U. S. Geol. Surv., Water Supply Paper (1913), No. 315, Mead and Turneaure, Public Water Supplies. 2d ed. (1913). 39 Johnson, op. cit., 24. 38 PURIFICATION OF WATERS 39 tion, and the use of ultra-violet light ; and chemical methods, such as treatment with coagulants or the addition of copper sulphate, ozone, chlorine, or lime. PURIFICATION OF WATER ON A LARGE SCALE It is well known that water is generally improved greatly by ordinary natural processes. Sunlight and aeration are so bac- tericidal that a surprising degree of purification is frequently effected in water, especially when it becomes well aerated, by flowing over rocks or other obstructions. Unfortunately this form of self -purification cannot be relied upon to any extent in the Philippines, as the density of population along a water course usually causes a greater pollution than would be obviated by natural agencies. Storage may also be of decided value in purification under ordinary conditions both biologically and chemically. When water is impounded in a reservoir, its flow ceases or, at least, decreases so greatly that silt and suspended matter begin to settle. Flad 40 observed that after twenty-four hours of storage only 5.5 per cent of the salt originally present in Mississippi River water remained in suspension. After ninety-six hours this decreased to 3.0 per cent. In addition to clarification, a decrease in color and organic matter, and usually in hardness, is produced. The precipitate entangles bacteria and carries them down with it, so that a considerable degree of purification is effected by simple sedimentation. There are, however, other ways in which storage has beneficial influence on the biological quality of a water. Sewage bacteria and pathogenic organisms, in general, rapidly die in water, and there is strong evidence to show that ordinary forms disappear as well or, at any rate, that they do not multiply persistently. In the ordinary form of reservoir, open to the sunlight and air, a marked degree of puri- fication takes place. Houston, 41 in his reports to the Metropolitan Water Board of London, found that after three weeks' storage the total number of bacteria per cubic centimeter in Thames River water fell from 450 to 53 ; in Lee River water, from 620 to 106 ; in New River water from 220 to 48. The decrease in numbers of path- ogenic bacteria was especially rapid. In the reservoir at Law- rence, Massachusetts, where water is stored about two weeks, the bacteria removal amounts to over 93 per cent. At Wash- 4 "Rideal, op. cit. (1915), 61. 41 Rideal, op. cit. (1915), 65. 40 PHILIPPINE WATER SUPPLIES ington, D. C, the bacterial removal is about the same as in the Boonton reservoir, where the Jersey City supply is impounded; a five to six days' storage in the former and a two hundred days' storage capacity in the latter effect an average bacterial purifi- cation of 99 per cent. Even in the dark the influence of nitrifying bacteria in the presence of air may effect purification. Water remaining in the old Manila "deposito," a covered reservoir having a capacity of about 60,000 cubic meters (16,000,000 gallons), becomes prac- tically sterile in the course of a few weeks, in spite of a high initial bacterial content. Preliminary experiments 42 indicate that in the new Manila reservoir, which has about three days' storage capacity, the various factors — sedimentation, aeration, and light — produce a bacterial reduction of about 90 per cent. It frequently happens that certain forms of plant life make their appearance, especially in reservoirs of faulty construction. These may cause odors, interfere with processes of purification, and when dead contaminate the water with decaying material, causing "stagnation" of the water. The remedy or preventive measure to be applied depends on the case in hand. Reservoirs must be frequently cleaned to remove accumulations of sediment and decaying matter. Sometimes aeration is resorted to ; some- times, especially when the trouble is due to algae and other growths, the addition of very small amounts of copper sulphate "(0.15 to 1.0 part per million) gives the desired results. Trouble due to stagnation is, perhaps, more likely to appear in tropical than in temperate regions. However, the experience in Manila and Cebu indicates that, with proper construction and super- vision, reservoirs in the Philippines need give no unusual amount of difficulty. The Manila reservoir requires frequent cleaning, because of the large amount of suspended matter in the water, but no pronounced stagnation has occurred. This, however, is hardly a criterion, because of the small storage ca- pacity of the reservoir in question. The Cebu reservoir, which impounds at least one hundred days' supply, has caused trouble only on one occasion, and then the removal of the accumulated mud in the reservoir brought about a return to satisfactory conditions. So far, filtration of water on a large scale has not been at- tempted in the Philippines. Sand filters have, from time to time, been suggested for the Manila city supply, but since ex- periments in the Bureau of Science had shown that amoebae pass 42 Heise, G. W., Phil. Journ. Sci., Sec. A (1916), 11, 5. PURIFICATION OF WATERS 41 through the average filter, their introduction was not considered advisable. However, this objection to their use no longer holds, as Walker 43 has shown that the amoebae ordinarily growing in water will not cause dysentery in man. There are two kinds of sand filters, the rapid and the slow. Slow sand filters are adaptable to clear, raw water. They have a daily capacity of about 23,000 cubic meters per hectare of surface area (2,500,000 gallons per acre) ; and their cost, includ- ing settling basins and filtered water reservoir, is about 16,000 pesos per million liters' capacity (30,000 pesos per million gallons) . Aside from the initial cost of installation, the actual cost of water filtration for Manila should be about 36 centavos per capita per annum. Rapid sand filtration is particularly applicable to water highly colored or heavily charged with suspended matter. In the lat- ter case a coagulant such as alum must be used to aid the separa- tion of the substances in suspension. The filtration rate is approximately forty times that of slow sand filters, and the cost of installation, including the necessary filter building, filters, and coagulating and filtered water basins, is about 6,500 pesos per million liters' daily capacity (12,000 dollars, United States currency, per million gallons). The cost in Manila for rapid sand filtration should be about 30 centavos per capita per annum. A new open filter is not as efficient as one that has been in operation for some time. The activity of an open filter bed is chiefly centered in the first few centimeters and is due to the gelatinous film that is formed from the removed suspended and colloidal matter. In this film reside myriads of organisms, chiefly algse and bacteria, which act on, and decompose, part of the organic matter of the water being filtered. In rapid mechan- ical filtration, where coagulants are employed, an inorganic film is formed as the gelatinous mass of aluminium or iron hy- droxide subsides. Both types of filters generally remove 98 to 99 per cent of the bacterial content of the water. In recent years the sterilization of public water supplies by means of the ultra-violet rays from a quartz-mercury vapor lamp has been repeatedly accomplished with very good results. This method is simple in practice and has the advantage of adding no foreign or deleterious substances to the water so treated. 43 Walker, Phil Journ. Scl, Sec. B (1911), 6, 259. Walker and Sellards, ibid., Sec. B (1913), 8, 253. 42 PHILIPPINE WATER SUPPLIES Water can be sterilized almost instantaneously regardless of its bacterial content. The method is applicable only to very clear waters, so that sterilization of a slightly turbid water, such as that of the Manila supply, is out of the question. For small installations using clear water, ultra-violet sterilization should prove very satisfactory. The proposed utilization of a small sterilizer of this type in the Baguio water system should give good results. Sterilization by the addition of chemicals is now extensively employed, usually in conjunction with coagulants and filtration. A number of materials have been proposed, but actual practice is restricted almost exclusively to alum (coagulant) , ozone, cop- per sulphate, lime, and chlorine. The use of alum has been already mentioned in connection with filtration. Very turbid water must be clarified before it is susceptible to treatment by practically any method of purifi- cation. Alums are almost universally used for clarifying pur- poses, since they react with the carbonates normally present in water, giving rise to flocculent precipitates that inclose, and thus eliminate, not only the silt and other suspended matter, but also a large fraction of the bacterial content. There is ab- solutely no evidence to show that the introduction into the water supply of alums in properly regulated amounts has the slightest deleterious effect on the human system. The ozone treatment is relatively hard to administer, is ap- plicable only to filtered water, and though excellent results are claimed for it, is not, at the present time, very widely used. That copper sulphate is valuable as an algicide has been al- ready pointed out. It has been also used to reduce the bacterial content of water. It is probably not injurious to health, but its use is open to several objections. It causes turbidity with certain classes of water, and its bactericidal effect is not all that might be desired. Stokes 44 reports that a concentration of one part of copper sulphate in 100,000 parts of water failed to destroy fermentative bacteria. Experiments in the Bureau of Science have shown that the addition of one part per 150,000 was necessary to kill cholera vibrios in Mariquina River water. Purification of water by the use of lime alone has received much attention in recent years. The method is being employed at present in a number of municipal installations in the United States and in Europe. It is essentially a water-softening proc- 44 Am. Med. (1905), 10, 1075. PURIFICATION OF WATERS 43 ess and is especially applicable to hard waters. A slight ex- cess of lime above the requirements for softening is the basis of the "excess-lime" method of Houston, 45 in which the excess is subsequently removed by carbon dioxide or by the sulphates of iron or aluminium. The materials precipitated in the treat- ment settle rapidly and are readily filtered off. Not only is a chemical purification obtained, but a great re- duction in the number of bacteria as well. The disappearance of intestinal bacteria is particularly marked. Hoover and Scott 40 ascribe the disappearance of the colon and typhoid bacilli to the removal of carbon dioxide from the water by the lime treatment and state that "bacteria belonging to the colon or typhoid group seem to require carbon dioxide for their de- velopment." The principal reduction in the number of bacteria is due to the coagulation of the precipitated calcium carbonate and magnesium hydrate. The advantages of the lime treatment are thus summarized by Hoover and Scott: 1. The water is softened. 2. Intestinal and pathogenic bacteria are killed and thereby the water is rendered safe bacterially. 3. The water is clarified. 4. Color is removed. 5. Lime-softened water is not corrosive to iron pipe, thus no trouble is experienced from the accumulations of "red-water" in dead ends of the distribution system. ,6. The sterilizing action of lime persists indefinitely. 7. Nothing is added to the water that was not there originally, as the lime combines with the C0 2 present in the water to form calcium carbonate (CaCOs) which is insoluble and is removed. Because of its cheapness and general efficiency, chlorine, in the form of hypochlorites or liquid chlorine, is now one of the most generally used chemicals for the purification of public water supplies or the emergency sterilization of sewage. The value of calcium hypochlorite as a disinfectant was first pointed out by Koch, 47 while its application on a large scale to the disin- fection of a municipal supply was first proposed by Traube. 48 It was not until 1908, however, when hypochlorites were used 45 Eighth Rep. Metropolitan Water Board, London (1912), through Rideal, Water Supply (1915), 175. 46 Hoover, C. P., and Scott, R. D., The use of lime in water purification, Eng. News (1914), 72, 587. 47 Koch, R., Mitt. a. d. kaiserl. Gesundheitsamte (1881), 1, 234-282. 48 Traube, M., Zeitschr. f. Hyg. (1894), 16, 149-150. 44 PHILIPPINE WATER SUPPLIES successfully in water purification in the stock yards at Chica- go, 49 that the hypochlorite sterilization of municipal water supplies was adopted to any great extent. The amount of hypochlorite necessary for efficient steriliza- tion cannot be definitely stated, as it varies greatly with the quality and temperature of the water, on the methods of ad- ministration of disinfectant and distribution of water, and pos- sibly also on other factors. Water from the same source often requires different amounts of hypochlorite for treatment, depending on slight variations in the quality of the water. It may even happen that a small quantity of hypochlorite is as effective as a much larger one. 50 In general practice the most efficient quantity is usually in the neighborhood of one part of available chlorine per million of water (1 milligram per liter), though the actual amount to be used for any installation should be carefully determined by chemical and bacteriological control. Though no definite rule can be stated, it may be said that such a quantity of hypochlorite should be added that ten minutes later the addition of potassium iodide-starch indicator will give a slight blue coloration. This rule admits of exceptions. A decided advantage of chlorination is the absence of poi- sonous features. The amounts of free chlorine that reach the consumer in a well-administered distribution system are so slight that they are of no significance. It often happens that chlorinated waters acquire a percept- ibly unpleasant taste or odor. This has been frequently noted in Manila. It can be usually avoided by careful regulation of dosage, by filtration through iron, charcoal, or sand, by storage, or by the addition of suitable chemicals, such as sodium sul- phite or sodium thiosulphate. A humorous feature in connection with chlorination arises from the popular antipathy to the use of treated water. In a number of instances 51 vigorous com- plaints of the "chlorine" taste and odor of a water were made some weeks before a proposed chlorination treatment had been put into operation. In case of epidemics or of sudden contamination of waters it sometimes becomes necessary to use more than ordinary quan- 49 Johnson, G. A., U. S. Geol. Surv., Water Supply Paper (1913), No. 315, 65. 50 Stokes, W. R., and Hachtel, F. W., Journ. Am. Pub. Health Assoc. (1916), 6, 1224-1236. 61 Kellogg, Rep. U. S. Pub. Health (1914), 29, 687. PURIFICATION OF WATERS 45 tities of hypochlorites, with the result that the water becomes unpalatable. In this event the excess chlorine can be readily destroyed by the addition of "antichlors," such as the sulphite or thiosulphate of sodium. Chloride of lime is still the most commonly used chlorination agent, though at the present time both sodium hypochlorite and liquid chlorine are being used extensively. The advantages of chloride of lime are its cheapness, its compact form and the con- sequent ease with which it can be handled, transported, and stored, and the fact that its administration is comparatively simple and easy, so that the expense for equipment, labor, and supervision is not great. Simple and efficient methods have been also devised for the chloride of lime sterilization of small municipal supply systems and for use in emergencies. With the development of munic- ipal water-supply systems, such methods should be applicable in the Philippines, not only for emergency, but for ordinary sterilization. The use of liquid chlorine for water purification, first intro- duced on a commercial scale by Darnall 52 in 1910, is rapidly growing in favor. In the Philippines, where there is no chlorine gas manufactured, this method is not applicable at present, but in countries where chlorine is a cheap by-product, its use is often to be recommended. Its advantages are the fact that no salts are added to the water and that, according to report, the taste and odor of the treated water are often less than when chloride of lime is used. The disadvantages are a higher initial cost of installation, a somewhat higher cost for chemicals, the need of a higher grade of labor in administration, expert supervision, and the danger of corrosion in the administration apparatus. It appears, however, that most of these objections can be overcome or, at least, that the advantages under certain conditions out- weigh the disadvantages, for, according to Birsall, 53 the substi- tution of liquid chlorine for chloride of lime in the purification of the municipal supply of Minneapolis has proved successful, and the city "would never again return to the use of hypochlorite if it were possible to avoid it." Sodium hypochlorite is readily prepared by the electrolysis of a solution of common salt or by the interaction of common soda and bleaching powder. The salt is unstable; hence it is used only in solution, generally as an alkaline liquid containing about 52 Journ. Am. Pub. Health Assoc. (1911). 53 Birsall, L. D., Eng. News-Record (1917), 78, 539. 46 PHILIPPINE WATER SUPPLIES 10 per cent of available chlorine. Its disadvantages are a high initial cost of installation and the need for expert supervision. Its advantages are ease of administration and the fact that no objectionable salts are added to water. The claim has been made 54 that sodium hypochlorite has a greater sterilizing effect than chloride of lime and that, in the end, its use is more econom- ical. The electrolytic process appears particularly suitable for small units, such as supplies for small towns or for troops in the field. The Ornstein process 55 is used in the European war for sterilizing water supplied to English soldiers. Effi- ciency tests by the Bureau of Science on a small electrolyzer have shown that the electrolytic process could be readily adapted to meet Philippine conditions. The preceding discussion has dealt almost entirely with the removal of organisms deleterious to health. Also chemical constituents of a water may be objectionable, either because of their nature, or because of the large amounts present. As has been stated, filtration may remove part of the dissolved organic matter. The commonest inorganic materials that require special treatment for their removal are iron and calcium and magnesium compounds. Calcium and magnesium compounds, though making the water "hard," are not usually objectionable in themselves, even in comparatively large amounts, when the water is to be used for drinking purposes only. Iron is objectionable when present even in very small quanti- ties. It can be usually removed by aeration. Iron is usually present in water as ferrous bicarbonate and is acted upon by the oxygen of the air to form ferric hydroxide, which may be removed by filtration. The removal of calcium and magnesium compounds, a process known technically as water softening, is discussed at length under industrial supplies. PURIFICATION IN THE HOUSEHOLD When water must be purified in individual homes, boiling is, perhaps, the simplest safeguard in so far as contamination due to living organisms is concerned. It has not been practiced in the Philippines to any considerable extent by the mass of the population, except during times of great stress, such as cholera epidemics. Even when so practiced, the good effects have been often vitiated by subsequent handling of the water with dirty "Rideal, op. cit., 187. 55 Anon, Electrician (1917), 78, 750. PURIFICATION OF WATERS 47 hands and in dirty vessels. It will be a difficult task to bring about the general adoption of this precaution ; the cost of fuel, the inadequacy of cooking facilities in the average home, the peculiar taste of boiled water and superstitions regarding its harmful character, and lack of comprehension of the purpose of boiling, all militate against its use. Though distillation is not a common method of purification of water for home use, it has been so extensively practiced in the Philippines that it is worthy of brief mention here. Both the Federal and the Insular Governments maintain their own instal- lations. Distilled water can be obtained in most of the larger cities, either from Government or from privately owned dis- tilling plants. In Manila the price of distilled water has been 1 centavo (0.005 dollar) per liter, and until recently the foreign and wealthy native population depended entirely on this supply for drinking purposes. All dissolved or suspended matter is removed from water by distillation. The cost of equipment and fuel is an important factor in determining the feasibility of distillation as a method of purification. Another mode of purification of water for home use is filtra- tion. Many types of filters have been devised for home use. These usually employ sand, charcoal, or porous earthenware and are either attached directly to a faucet or tap or are used separately. Though many forms are really capable of purifying water if properly cared for, the usual types are too small ade- quately to purify the water passed through them, and they generally do not receive sufficient care to keep them in good condition. Various other types of sterilization appliances are made for use in the home, such as heating devices, electrical ozone gen- erators, and the like. These, however, are not of sufficiently general application to Philippine conditions to justify detailed discussion here. PURIFICATION IN THE FIELD Considerable attention has been devoted to water supplies for troops, and a number of methods of field purification are now employed. Several of these are merely slight modifications of the processes already described in connection with purification of water on a large scale and so need no extended discussion. A few, however, are possessed of special features that warrant further mention. In the United States Army the Darnall filter and Lister bag are used. The first device provides for purification by means 48 PHILIPPINE WATER SUPPLIES of coagulation and subsequent filtration through flannelette bags. Most of the suspended matter and a large part of the bacteria are thus removed. Salts of iron or aluminium are used for coagulation in the presence of some neutralizing agent such as lime or soda ash. The Lister bag is a bag of heavy canvas, holding about 150 liters (40 gallons) and provided with five spigots. Calcium hypochlorite is added to the water in the bag, effecting chemical sterilization. The Darnall filter clarifies water, but does not insure steriliza- tion. The Lister bag sterilizes, but does not clarify. A combi- nation of the two processes should be effective. Numerous other types of filters and "filter candles" are em- ployed to a limited extent, but these, as a rule, have not been found very satisfactory, except for the use of small units. The effort usually involved in their operation on a large scale is much greater than that required for other processes just as efficacious and no more expensive. Most of these filters are modifications of the Pasteur filter, consisting of porous earthenware through which the water is forced under pressure. The Berkef eld army filter is a good example of this type. A hollow porous tube is inclosed in an outer metallic case. The raw water is forced through the porous material and emerges clarified and sterile. Another filter of this type consists of an inverted funnel about the size of a watch, to which a rubber tube and mouthpiece are attached. Water can be then sucked through the tube. An- other form consists of a cup or small pail into which water slowly filters. Such devices are satisfactory only if they are frequently cleaned and sterilized, the latter being readily ac- complished by baking. Boiling is, of course, a reliable means of sterilization, and is valuable for the use of small units. Often a weak tea is made, to increase the palatibility of a water. For the purification of large supplies, however, boiling is ordinarily uneconomical and impracticable. Sterilization by ozone or by ultra-violet rays is usually im- practicable in the field, though it may be employed where electric power is available. 56 On the whole, chemical sterilization appears to be the most generally satisfactory method for troops in the field. It is cheap and efficient. Chlorine is the sterilizing agent commonly 36 Anon, Can, Engr. (1916), 30, 189-90, through Chem. Abst. (1916), 10, 1063. PURIFICATION OF WATERS 49 employed either in the gaseous condition or as calcium or so- dium hypochlorite. The United States Army has devised an efficient apparatus for sterilization with chlorine gas for camp use, 57 and sterilization of this kind seems destined to become more popular. Nelson 58 describes an apparatus for preparing chlorine in the field by the oxidation of hydrochloric acid with potassium * chlorate. While excellent results are claimed for the appa- ratus and its use, there can be no great advantage in making chlorine by this process. At present chloride of lime is more generally used than chlo- rine gas, and a number of methods have been employed for its use in the field. In permanent or semipermanent encampments its applications do not differ materially from those in municipal purification plants, which have been already discussed. For troops in temporary camps or on the march, the time factor is important. The usual procedure in this case is to add a comparatively large excess of available chlorine, providing rapid sterilization, and then to neutralize the excess with some reduc- ing agent or "antichlor." The antichlor most commonly used is sodium thiosulphate (hypo) , though the advantage of greater palatability is claimed for hydrogen peroxide. 59 The chloride of lime may be used alone or in conjunction with an alkaline permanganate solution. 60 Sodium hypochlorite may be employed, either as such, 61 or as in alkaline solution (antifor- min). Rhein 62 suggests the use of hypochlorous acid derived from the action of hydrochloric acid on concentrated antif ormin. An interesting development of field-water purification has been the sterilization of a supply for the individual soldier. In the movements of small parties of troops, particularly of cav- alry, when the camp is not within reach, the question of a small supply of potable water for immediate use often becomes a serious one. In addition to those already described, a number of methods of purification have been proposed, the majority taking the form of powders or pellets of various kinds. 57 Darnall, C. R., Water purification for troops in war, Bull. War Dept. f Office Surg. Gen. (1913), No. 2, 116. "Brit. Med. Journ. (1915). 59 Doyon and Toda, Compt. rend. Soc. biol (1916), 79, 232-233. 60 Penan, H., Journ. Pharm. chim. (1916), 13, 377-85, through Chem. Abst. (1916), 10, 2487. 61 Doyon and Toda, loc. cit. e2 Rhein, M., A new method for the sterilization of drinking water in the field, Zeitschr. f. Hyg. (1914), 78, 562-70. 152918 4 50 PHILIPPINE WATER SUPPLIES In 1901 Parkes and Rideal 68 introduced the use of sodium acid sulphate (NaHS0 4 ) for travelers and in campaigns, in the strength of 15 grains per pint (2 grams per liter). Such salt was successfully used in the Boer and English war. It is still used extensively in pellet form by the British Army. 04 The pellets are made up with oil of lemon and saccharin, to in- 4 crease the palatability, and are employed in such quantities as to provide a concentration of 0.07 per cent of free sulphuric acid in the water to be sterilized. A half hour is allowed for bac- tericidal action. A great disadvantage of this method is the corrosive action of acid solutions on the metals, such as those used in canteens. Many other substances have been proposed, most of which will give satisfactory results if they are properly used. Among them may be mentioned the use of from 4 to 6 drops of tincture of iodine, followed by a pinch of sodium thiosulphate ; 65 the addition first of potassium permanganate and then of sugar; and the use of pellets and powders, such as mixtures of salt and bleaching powder. 66 The question has been occasionally raised whether or not puri- fied water might not be injurious to health, owing to the presence of dead bacteria. With reference to this point, Vosmaer 67 has made the following calculation: Assuming a water had the enormous bacterial content of 100,000 per cubic centimeter, or 375,000,000 per gallon (3.78 liters), the space occupied by the bacteria per gallon of water would be only 0.000024 cubic inch. Since bacteria are 90 per cent water, he concludes that the amount of foreign material in water, due to the presence of bacteria, is insignificant. 63 Rideal, op. cit. (1915), 171. 64 Thorndike, Saville, Military sanitation in the present war, Am. Journ. Pub. Health (1917), 7, 547. « 5 Schweiz. Apoth. Zeitg. (1914), 52, 717, through Chem. Abst. (1915), 9, 495. m Langer, H., Chem. Tech. Rep. (1914), 38, 146. 67 Vosmaer, A., Met. & Chem. Eng. (1913), 11, 705. WATER FOR INDUSTRIAL PURPOSES So many industries require a water suitable in quality as well as abundant in supply, that it is not surprising that the problem of water supplies for industrial purposes should be considered important, but rather that its importance should be so little emphasized. The use of improper supplies is still causing an annual loss of millions of pesos, even in countries in which industries are well developed and intelligently super- vised. For example, on one section of a certain railroad in the United States the use of poor boiler water resulted in a cost, for repairing and cleaning of locomotive boilers alone, of 10 centa- vos per kilometer (16 centavos per mile) of distance run, while the total mileage of the engines was probably reduced one-half. 08 As an illustration of the saving that can be effected by the substitution of a better water for an improper supply, it may be mentioned that, according to estimation, the inhabit- ants of Glasgow, Scotland, by using the soft Loch Katrine water instead of the previous supply, save 300,000 pesos annually on the item of soap alone. 69 In view of the undeveloped state of Philippine industries in general, it is not surprising that the question of the fitness of waters for industrial purposes should have been little considered in the past. It is worthy of mention, however, that proper attention to this problem would have effected a tremendous saving in many fields of commercial enterprise. Even the most obvious factor, that of quantity, has frequently been overlooked, to the great detriment of the industry in question. Thus a certain mining company, after investing heavily in expensive machinery and equipment, found that the water available for power purposes was adequate only for a few months in the year. In another instance an agricultural enterprise, representing a large investment of foreign capital, almost failed through the neglect of the promoters to take into account the fact that the annual rainfall, though more than sufficient for their needs, was unequally distributed throughout the year. The extent to which water is used in ordinary manufacture is frequently overlooked. 68 Leighton, M. O., U. S. Geol Surv., Water Supply Paper (1903), No. 79, 14. G9 Rideal, op. cit. (1915), 141. 51 52 PHILIPPINE WATER SUPPLIES Thus it has been estimated 70 that from 40 to 1,600 liters of water are used in the manufacture of a single kilogram of paper. Failure to take quality of water into account has also proved costly in the Philippines. An annual loss of many thousands of pesos would have been avoided in one city alone by the sub- stitution, for improper boiler waters, of supplies available at comparatively small cost. A chemical analysis and its proper interpretation would have obviated a number of costly failures in cement and reenforced concrete construction. The use of a very undesirable water in one of the centers of the Philippine tanning industry has greatly impeded 71 the development of the local manufacture of leather. A factor of importance in the problem of industrial water supplies in the Philippines arises from the frequent variation in quality of certain waters. Many of the rivers that flow into the sea are affected by the tides for many kilometers inland, so that, at certain times of the day, they are decidedly brackish. For this reason a certain river water used for irrigation can be pumped on to the fields only at certain times of the day. A study of the variation in the composition of one river water enabled this laboratory to decide between two proposed types of under-water construction, with the result that one, which undoubtedly would have rapidly deteriorated, was rejected. Up to the present time, the principal industrial use of water in the Philippines has been for the production of steam, but the industrial development of the last few years indicates that the question of a suitable water for a particular purpose will assume an ever-increasing importance. Though many excellent boiler waters are available in the Philippines, the problem of securing a good water is often an exceedingly difficult one. In Manila and in Cebu the surface wa- ters supplied by the municipal systems are fairly satisfactory; in Iloilo, however, the waters available until recently were uni- formly bad. The development of new supplies in the last- mentioned place makes it probable that conditions soon will be greatly improved. On the coastal plain of Occidental Negros, the largest and most important sugar-producing district in the Islands, excellent boiler waters are obtained from the surface streams originating in the range of volcanic mountains that forms the rocky backbone of the province. Several boilers 70 Palmer, C, U. S. Geol. Surv., Water Supply Paper (1909), No. 233, 185. 71 Cf . Gana, V. Q., The leather industry of the Philippine Islands, Phil. Journ. Sri., Sec. A (1915), 10, 349-373. WATER FOR INDUSTRIAL PURPOSES 53 using these waters were found to be almost free from incrusta- tions and showed no effects of corrosion after continuous use during an entire milling season (three to six months), without more cleaning than an occasional blowing-off of the water in the boiler. On the other hand, cases might be cited of a power company that has been spending approximately 500 pesos a month in replacing incrusted and corroded boiler parts and of a large manufacturing concern that was forced to distill its water to be used for boiler feed purposes because of the entire unsuitability of the raw water. Both types of the instances mentioned are exceptional. It would be a fair statement, however, to say that comparatively few of the natural waters of the Philippines are suitable for boiler purposes without previous treatment. In practice, the nearest source is used. As intelligent treatment is the excep- tion rather than the rule, and as, in the majority of cases, there is no treatment at all, the usual boiler troubles are encountered. Because of their frequency and importance, these will be dis- cussed separately. The phenomenon of foaming is the formation of bubbles on the surface of the water in a boiler, thereby hindering the free escape of the steam. This tendency is noted in waters rich in sewage or other organic matter and is increased by the presence of mud or other suspended matter. Probably the commonest cause, however, is the high concentration of dissolved alkali salts, either those naturally occurring in the water or those re- sulting from chemical treatment of the feed water. As foaming is largely a question of surface tension, it may be temporarily relieved by surface blowing. The only remedy for foaming due to high salt concentration is blowing off and dilut- ing with fresh feed water. This is not only uneconomical in regard to fuel, but due to the greater amount of water employed, may increase the amount of incrustations. Intimately connected with foaming is the condition technically known as priming. This is the passage of water with the steam. The tendency of a boiler to prime is affected by the design of the boiler and by the steam space; it generally in- creases as the steam space diminishes. Corrosion of a boiler may be due to chemical or galvanic action. Chemical corrosion may be due to two causes — solution or oxidation. Stabler has developed the following formula for determining the corrosive quality of a water from its chemical composition, expressed in terms of parts per million: 54 PHILIPPINE WATER SUPPLIES The "coefficient of corrosion/' c = H + 0.1116 Al + 0.0361 Fe + 0.0828 Mg - 0.0336 C0 3 - 0.0165 HC0 3 . If c is positive, the water will certainly corrode a boiler. If c -f 0.0503 Ca is negative, the mineral constituents in the water will not cause corrosion. If c is negative, but c + 0.0503 Ca is positive, corrosion may or may not occur, the probability of corrosive action varying directly with the value of the expres- sion c + 0.0503 Ca. 72 A feed water's solvent action is due principally to the presence of acid. Mine waters with free mineral acids — usually sul- phuric — and waters containing hydrogen sulphide or free carbon dioxide are typical instances of acid feed waters. Marked cor- rosive tendencies have been generally ascribed to waters con- taining magnesium chloride, on the assumption that, at working boiler temperatures, hydrochloric acid is split off hydrolytically. So much evidence to the contrary has been brought forward, however, that the exact role played by magnesium chloride is still in dispute. 73 A water may become acid through the decom- position of grease that works into the boiler. This may result in serious corrosion. The presence of acid-free volatile oil is actually beneficial in a boiler, assisting in scale prevention and in the reduction of rust. Very soft waters and those with a chlorine content of over 200 parts per million will be usually found to have corrosive properties. In general, alkaline waters are not corrosive, though it has been shown that, in the case of sodium and potassium carbonates, there is a critical concentration below which solution of these salts have a corrosive, instead of protective, tendency. 74 The common remedy for acid waters is the addition of a slight excess of alkali over the amount required to combine with the mineral and organic acids present. Lime is inexpensive and usually efficient. Its use often results in the formation of a thin pro- tective scale, which prevents further corrosion. Barium hy- droxide has been also recommended for the correction of the acidity of mine waters, 75 but its relatively high cost would prob- ably prohibit its extensive use commercially. A small amount of oxidation of the boiler material normally 72 Stabler, H., U. S. Geol. Surv., Water Supply Paper (1911), No. 274, 170. 73 0st, H., Chem. Zeitg. (1902), 26, 819, 845; also Bradbury, Chem. News (1913), 108, 307. 74 Friend, J. Newton, The Corrosion of Iron and Steel. Longmans, Green & Co., New York (1911), 132. 75 Griffin, M. S., Joum. Am. Chem. Soc. (1899), 21, 676. WATER FOR INDUSTRIAL PURPOSES 55 occurs in all boilers not protected with a scale or other coating. All natural waters contain oxygen, and this, introduced with the feed water, may attack any unprotected iron with which it comes in contact. This action may be especially marked at the feed-pump discharge. Corrosion resulting from this factor may take the dangerous form of pitting, due to the accumulation of air in pockets. Ost 76 ascribes the oxidation of the iron, in part, at least, to the decomposition of the hot feed water. "Iron cannot rust in water unless oxygen is present." 7T Oxy- gen accelerates corrosion by removing the protective film of hydrogen, which is the product of electrolytic action. The re- moval of the oxygen from the feed water before it enters the boiler is, therefore, to be recommended. This is accomplished preferably by means of an open preheater or by various chem- ical methods, such as an alkaline tannin solution. Corrosion may be due to galvanic as well as to chemical action. If there is any difference of potential between the parts of a system immersed in an electrolyte, an electrochemical action will be set up. Two dissimilar metals in an electrolyte, and in electrical contact, will start such an action, in which the more electropositive metal will be worn away. Thus copper or brass feed pipes in contact with iron will set up an electro- chemical action at the expense of the more electropositive iron. Iron may itself set up electrolytic couples even if it is not segre- gated, owing to physical strains occasioned by previous heat treatment. 78 Dissimilarity of metals is not an essential condition for elec- trochemical action. Unequal stress, distortion, or temperature in different parts of the same piece of metal or lack of homo- geneity may give rise to differences of potential. It has been often observed that brass steamship propellers corrode most rapidly near the propeller shaft. This is fre- quently due to the fact that there is a greater strain at that point than at the edges, when the propeller is in motion. A differ- ence of potential is thus set up and electrolysis takes place, in which the center of the propeller is anodic and is consequently corroded. 76 Ost, H., Chem. Zeitg. (1902), 26, 820. 77 Cushman, A. S., and Gardener, H. A., The Corrosion and Preservation of Iron and Steel (1910) 101. 78 Buergess, C. F., Boiler corrosion as an electrochemical action, Journ. Western Soc. Eng, (1909), 14, 375. 56 PHILIPPINE WATER SUPPLIES The attention of the Bureau of Science was recently directed to some very badly corroded copper fire tubes in a number of locomotive boilers. These copper tubes were used in conjunc- tion with a number of small brass fire tubes, all being embedded in a copper fire sheet at one end and in an iron end-sheet at the other. The corrosion of the copper tubes occurred where they were embedded in the fire sheet, the brass tubes and iron end-sheet showing little or no corrosion. Potential measure- ments made with a millivoltmeter while the boiler was in opera- tion showed differences of potential between different parts of the copper tubes, as well as between different parts of the system copper-brass-iron. The copper tubes at the points of greatest attack were anodic to all other parts of the system. Here the phenomenon was thermoelectric. Stray currents are frequently the cause of corrosion. This is true particularly in tropical regions, where proper insulation is made exceedingly difficult by the saturated condition of the ground during the long periods of continuous rainfall. Many cases of excessive boiler corrosion observed in Manila have been accompanied by appreciable differences in potential between the boiler parts and the surrounding objects. Several methods have been suggested and some successfully adopted, for the prevention of electrolytic corrosion. They are all based on the fact that iron will be corroded only when it is the anode. Any method, therefore, that makes iron the cath- ode, will bring about the desired result. Zinc, which is electro- positive to iron, is often connected to iron. As iron is cathodic to zinc, it is thus protected from corrosion. Many cases have been recorded where zinc has been employed very satisfactorily in this way to protect boiler parts and condenser tubes. How- ever, it must be remembered that the protective influence of zinc extends only over short distances and that the zinc dissolves rapidly and must be replaced. In some cases, too, a non-conduct- ing adherent coating of zinc salts is formed, which decreases the protective action. If this coating is of zinc oxide, corrosion may be even greatly accelerated, instead of inhibited, due to the fact that zinc oxide is cathodic to iron. 79 Aluminium has been suggested as a substitute for zinc. Until a satisfactory method has been devised for its application, however, it is open to even greater objection than the zinc, as a coating of alumi- nium oxide forms quickly and is very adherent. 79 Friend, J. Newton, op. cit. (1911), 266. WATER FOR INDUSTRIAL PURPOSES 57 Another proposal that has been made 80 is to make iron the cathode by impressing a counter electromotive force from stor- age batteries or a small dynamo. In the absence of any depo- larizer, dissolved oxygen especially, a very small current should produce an electromotive force large enough to neutralize the tendency of the iron to pass into solution. The density of the current required can be calculated, within the limit of experi- mental error, from the loss in weight of the unprotected metal under the given conditions. For boiler protection, a rod of iron or carbon connected to the positive pole of a dynamo serves as the anode, the other pole being the boiler plates or tubes. A number of successful applications of this treatment have been recorded. Still another suggestion to prevent corrosion is to passivify the iron. Certain chemicals, notably oxidizing agents, render iron passive and resistant to the ordinary forms of attack. It has been calculated that the addition of 1 kilogram of potassium dichromate to 12.5 metric tons of water would prevent corro- sion. 81 This procedure, however, cannot be recommended for general practice, because, under certain conditions, oxidizing will increase, not inhibit, corrosion. For a very pure water, passivity will take place in a. bichromate solution y 160 normal, 82 and corrosion should be inhibited. In the presence of salt a reaction takes place, whereby an acid is formed, in accordance with the equation : 83 H 2 + K 2 Cr 2 7 + 2NaCl ±? K 2 Cr0 4 + Na 2 Cr0 4 + 2HC1. The hydrochloric acid formed not only may be expected to destroy the passivity of the iron, but it also attacks it, so that corrosion would be greatly accelerated. Furthermore, in the presence of free acid, potassium bichromate does not passivify iron, but instead actually accelerates corrosion, because of its strong depolarizing effect — that is, by the removal of hydrogen. This accelerated corrosion has been determined experimentally by Watts. 84 Recent experiments in this laboratory have shown that under certain conditions the corrosion of iron in acid solu- tion may be proportional to the concentration of bichromate. The most general boiler trouble experienced in the Philippines, 80 Clement and Walker, Tech. Paper, U. S. Bur. Mines (1913), No. 15. sl Cushman, A. S., Bull. U. S. Dept. Agr. (1907), No. 30. 82 Cushman, op. cit. 83 Friend, J. N., Journ. Iron Steel Inst. (1908), 2, 9, quoted by Friend,. J. N., Corrosion of Iron and Steel (1911), 163. 84 Watts, 0. P., Trans. Am. Eleetrochem. Soc. (1912), 21, 232. 58 PHILIPPINE WATER SUPPLIES however, is the formation of scale. The limestone formation, so common in the Islands, gives rise to a large number of waters with high calcium and magnesium contents. In other sections the volcanic origin of the land surface and the nature of the secondary formations are shown in high sulphate concentrations. Scale is caused by the deposition of suspended or dissolved material within the boiler shell or on the tubes and is termed sludge, sediment, or incrustation according to its texture and position. The deposition of the dissolved material at the high boiler temperature may be due to reduced solvent properties, to chemical action and precipitation, or to the concentration and crystallization that accompany the evaporation of the feed water. Mud, other suspended matter, and a portion of the dissolved organic matter may be baked into an adherent coat- ing, which will be soft or hard, depending on the nature of the other scale-forming ingredients in the feed water. Calcium and magnesium are almost always the predominating basic substances in scale and, in the form of carbonate and sul- phate, ordinarily constitute over 90 per cent of the incrustations. Iron and aluminium, although normally present in Philippine natural waters, are usually in such small amounts as to have practically a negligible effect in scale formation. As the method of removal of the scale-forming elements is dependent on their nature, it will be necessary to discuss the character of the different calcium and magnesium compounds as they occur in the raw feed water. The usual distinction made is indicated by the terms "tem- porary hardness" and "permanent hardness." Under the former head are included those compounds of calcium and magnesium that are more or less completely decomposed and precipitated by simple heating, thereby removing the basic elements. The compounds of calcium and magnesium that cause permanent hardness, however, are not removed by simple heating, and chemical treatment must be resorted to. Under temporary hardness are included the carbonates and bicarbonates of calcium and magnesium. Normal calcium car- bonate is almost insoluble in water, while magnesium carbonate is slightly soluble. In the presence of free carbon dioxide, however, both carbonates are dissolved to a much greater degree, forming the soluble bicarbonate. This condition is met with in nature by ground waters passing, often under pressure, through decaying organic matter or other sources of carbon dioxide and simultaneously or subsequently through limestone WATER FOR INDUSTRIAL PURPOSES 59 strata. In this way high concentrations of calcium and mag- nesium bicarbonates may be produced. On the escape or removal of the carbon dioxide, such as effected by heating, the normal carbonates are reformed and precipitated. Simple boil- ing will precipitate practically all of the calcium carbonate and most of the magnesium carbonate present. Neither the precipitated calcium nor magnesium carbonate produces a hard scale in the absence of other scale-forming ingredients. Ordinarily a loose, bulky sediment is formed, which may be washed out or blown off. Permanent hardness is ascribed to the chlorides and sulphates of calcium and magnesium. Magnesium sulphate and chloride and calcium chloride are increasingly soluble with increasing temperatures, so that, obviously, heating will not remove them. Calcium sulphate is unusual in that its solubility diminishes with increasing temperature, and it may, therefore, be precip- itated under boiler conditions. It is deposited as fine crystals, which mix with the mud and other scale material to form a very hard, vitrified scale, which can be removed only by chipping. Magnesium sulphate alone does not form a scale. In the presence of calcium carbonate, however, one of the hardest scales known is formed. Magnesium chloride has no signifi- cance in scale formation when alone. The corrosive effects ascribed to it have been discussed. If the chemical analysis of a feed water is available, the probable amount of scale can be fairly accurately calculated. Stabler 85 has developed a formula in which the analytical results expressed in parts per million may be used to calculate the amount (in pounds of scale per thousand gallons of water) of scale and sludge liable to be deposited on a boiler operated under the usual conditions of modern practice. The formula is: Scale =0.00833 suspended matter +0.00833 colloidal matter (=Si0 2 +Al 2 O s +Fe 2 8 ) +0.0107 Fe+0.0157 Al+0.0138 Mg+0.0246 Ca. Recalculated to express the amount of scale in kilograms per cubic meter of water, this formula becomes : Scale =0.001 suspended matter+0.001 colloidal matter+0.0013 Fe +0.0019 Al+0.00166 Mg+0.00295 Ca. The following formula of Stabler's shows in pounds per 85 U. S. GeoL Surv., Water Supply Paper (1911), No. 274, 176. 60 PHILIPPINE WATER SUPPLIES thousand gallons the probable amount of material that will be deposited as hard scale: 0.00833 SiO 9 +0.0138 Mg+ (0.016 Cl+0.0118 SO 4 -0.0246 Na -0.0145.K). Expressed as kilograms per cubic meter, the formula becomes : Hard scale=0.001 SiO 2 +0.0166 Mg+0.001 (1.92 Cl+1.42 S0 4 -2.95 Na— 1.74K). Stabler obtains a coefficient of scale hardness by dividing the amount of hard scale by the total scale. From this coefficient "h" he forecasts the nature of the scale as follows: 1. Soft scale: "h" not more than 0.25. 2. Medium scale: "h" more than 0.25, but not more than 0.5. 3. Hard scale: "h" more than 0.5. Based on the amount of encrusting ingredients, several more or less arbitrary classifications have been suggested for the suit- ability of waters for boiler purposes. The following scheme 86 is considerably used: Parts per million. Class. Less than 90 Good. 90 to 200 Fair. 200 to 430 Poor. 430 to 680 Bad. Over 680 Very bad. The amount of estimated incrustants for use in the above classifications may be conveniently determined as parts per million from Stabler's formula modified as follows: Encrustants = suspended matter (turbidity) -f colloidal matter +1.3 Fe+1.9 Al+1.66 Mg+2.95 Ca. The incrusting ingredients are also sometimes taken as equal to the ' 'soap-consuming power/' 87 This method of estimating the scale-forming materials is used as the basis of the follow- ing classification of boiler waters, adopted at a meeting of the American Association of Railway Chemists in May, 1887: Less than 15 grains per gallon (258 parts per million), good. From 15 to 20 grains per gallon (258 to 344 parts per million), fair. From 20 to 30 grains per gallon (344 to 515 parts per million), poor. From 30 to 40 grains per gallon (515 to 697 parts per million), bad. Over 40 grains per gallon (697 parts per million), very bad. "Proc. Am. Ry. Eng. & Maint. Way Assoc. (1904), 5, 595. 87 Parr, S. W., Bull III. State Geol. Surv. (1909), No. 10, 57. WATER FOR INDUSTRIAL PURPOSES 61 It will be observed that the limiting values in the two tables differ considerably. This is to be expected. The suitability of a water for boiler purposes is dependent on so many factors that a simple method of diagnosis is hardly possible. Series of numerical standards, like those given above, are of value as indications of the quality of a water. The only final criterion, however, is actual trial under working conditions. SCALE PREVENTION AND WATER SOFTENING The undesirability of scale in a boiler needs little comment. Rankine 8S states that calcium carbonate conducts heat eighteen times as badly, and calcium sulphate fifteen times as badly, as iron. It is estimated 89 that one-sixth of an inch of scale neces- sitates the use of 16 per cent more fuel; one-fourth, 50 per cent; and one-half, 150 per cent additional coal. Schmidt and Snod- grass, 90 as a result of their investigations, conclude that the structure of the scale is of as much importance in these heat losses as, or even of more importance than, its thickness or chemical composition, except in so far as the latter affects the structure. Furthermore a thick scale frequently causes overheating. The heated parts may swell and bulge to a very considerable extent, sometimes even resulting in a fracture. Again cracks may occur in thick scale, allowing sudden contact of the water with the overheated boiler surface, and blistering or cracking or even an explosion may result. The most obvious remedy for scale formation is the removal of the scale-forming elements before the water enters the boiler. In spite of the logic of this method of treatment, it is common practice to allow the incrusting material to be precipitated in the boiler. Dependence is then often placed on "boiler com- pounds^ or on various mechanical devices to induce the forma- tion of a soft, nonadherent scale or sludge, which can be blown down readily or otherwise removed. Almost without exception, the prevailing practice in the Philipines is to apply feed-water treatment in the boiler itself. The number of patented processes for the purpose of mak- ing the scale loose and bulky is exceedingly great. Among the mechanical methods may be mentioned the use of wires, chains, and brushes, to entangle the deposit. The electrolytic liberation 88 Quoted by Rideal, S. and E. K., Water Supplies (1915), 142. 89 Rideal, loc. cit. See also Shealy, E. M., Steam Boilers (1912), 287. 90 Bull Univ. III. (1907), 4, No. 15, 1. 62 PHILIPPINE WATER SUPPLIES of hydrogen from the boiler surface to remove scale has been attempted, but without coming up to expectations. 91 Kerosene, paraffin oil, and substances containing tannin, such as wood extracts, have been successfully used to keep the scale in a loose and pulverized form, in which condition it may be readily blown off. These materials enter into a large number of commercial boiler compounds. Grease of any kind is to be avoided, because it is hydrolyzed and decomposed at high tem- perature, and acids may be formed that will corrode the iron. In some cases where tallow is used the scale has been found to contain from 12 to 26 per cent of iron from the boiler plates. The removal of scale-forming ingredients from a water is technically known as "water-softening." It cannot be too strongly emphasized that this process should be carried on out- side the boiler. Much of the money spent on mechanical devices for scale prevention would yield better interest if used in prelim- inary water softening. It is still largely the custom, however, to soften water within the boiler and to remove the precipitated material in the most convenient method possible. The removal of temporary hardness is comparatively simple, and may be effected by heating, by chemical treatment, or by a combination of the two procedures. The heating process is best carried out in an open feed-water heater, by which the water is raised to the boiling point, when nearly all of the carbonates and a portion of the sulphates are precipitated. The sediment is easily removed from an open heater, while the pipes of a closed heater are soon clogged up and cleaned with difficulty. Another advantage of the open heater is that the escape of the dissolved gases is facilitated, quickening the precipitation of the scale-forming material and lessening the corrosive tendencies of the water. Nearly all of the calcium carbonate and most of the mag- nesium carbonate are thus precipitated. The same result may be achieved by the addition of an alkali, such as milk of lime or caustic soda. As the former is much cheaper and adds no soluble salt to the treated water, it is gen- erally used. In this case the reactions may be represented by the following equations: Ca (HC0 3 ) 2 +Ca (OH) 2 ~^2CaC0 3 +2H 2 0. Mg(Hcd a ) 2 +Ca(OH) 2 -^MgC0 8 +CaC0 3 +2H 2 0. The second reaction does not proceed to completion with the theoretical amount of lime, due to the solubility of the magnesium 91 Rideal, op. cit., 143. WATER FOR INDUSTRIAL PURPOSES 63 carbonate. A further amount of lime is, therefore, added to precipitate the magnesium as the more insoluble hydroxide. The removal of permanent hardness is about nine times as costly as that of temporary hardness. As has been stated, calcium sulphate may be removed by heating under pressure, but as such heating is done preferably outside the boiler, this method of removal is uneconomical. Accordingly chemical treat- ment is employed. Calcium sulphate is removed by the addition of soda ash (sodium carbonate) according to the equation: CaS0 4 +Na 2 C0 3 ->CaC0 8 +Na 2 S0 4 . Soda ash is the most important ingredient of many boiler compounds. Magnesium sulphate, which cannot be completely precipitated as the carbonate, is more completely precipitated as the less soluble hydrate by the addition of both lime and soda ash : MfirS0 4 +Na 2 C0 8 +Ca(OH)- 2 ->Mg(OH) 2 +CaC0 8 +Na 2 S0 4 . The lime-soda process is fairly efficient and comparatively cheap and is the method most extensively employed for water softening. The proper amounts of reagents calculated, the amount of scale-forming ingredients, are added to the feed water, either hot or cold, and the precipitate is allowed to settle. This settling takes place more rapidly with hot than with cold water. After the sediment has subsided, the clear water is withdrawn and conducted to a storage tank. A vertical type of water softener provides a small chemical tank on top of the softener proper, a mixing chamber, and a storage space for the softened water. The chemicals are introduced with the raw feed water into the mixing chamber by an automatic proportioning device. After precipitation has taken place, the treated water flows downward through a quartz filter into the storage space below. The amounts of lime and soda ash required to soften a water can be determined from its chemical analysis. According to Stabler 92 the number of pounds of lime (90 per cent Cap) and soda ash (95 per cent Na 2 C0 3 ) required per thousand gallons of water may be calculated from the following formulas : Lime required=0.00931 Fe+0.0288 A1+0.0214 Mg+0.258 H (from mineral acidity) +0.00426 HCO, + 0.0118 C0 2 . 92 Stabler, H., U. S. Geol. Surv., Water Supply Paper (1911), No. 274, 170. 64 PHILIPPINE WATER SUPPLIES Soda ash required=0.0167 Fe+0.0515 Al+0.0232 Ca+0.0382 Mg+0.462 H-0.0155 CO 3 -0.00763 HC0 3 . Recalculated to express the lime and soda requirements in terms of kilograms of the reagent per cubic meter of water, these formulas become : Lime required = 0.001117 Fe + 0.0034§6 Al + 0.002568 Mg + 0.030960 H+0.000511 HCO 3 +0.001416 C0 2 . Soda ash required==0;002004 Fe+0.006180 Al+0.002784 Ca+ 0.004584 Mg+0.055440 H-0.001860 CO 3 -0.000917 HC0 3 . A negative value for the second formula shows that no soda ash is required. A rapid chemical method 93 for determining the lime and soda requirements is the treatment of a definite quantity of the water first with a standard calcium hydroxide solution and again with a standard sodium carbon/ate solution, ascertaining by titration with acid in each case the amounts of alkali consumed. Considerable attention has been recently directed to the navy standard boiler compound, developed in the United States Navy. The ingredients are sodium carbonate, starch, tannic acid, and trisodium phosphate. The purpose of the sodium carbonate is to take Care of any chemical reaction and render the solution noncorrosive. The tannic acid and starch are added to prevent the formation of scale, the action being to hold the impurities in suspension in the colloidal state. The trisodium phosphate prevents the rise of the surface tension of the solution and consequent priming caused by the impurities in the water and by the application of the other ingredients in the compound. In using this compound, the proportions of the ingredients are varied according to the composition of the raw water. To prevent corrosion, A sufficient quantity must be added to each boiler to render the alkaline strength of the water in the boiler 3 per cent of normal or above, and the alkaline strength must be maintained in each boiler. 94 The precipitated material is easily blown off or washed out of the boiler. A number of instances of successful applications of this treatment have been recorded. Among the other methods of water softening the "permutit" process deserves special mention. Dr. Robert Gans, of Berlin, 93 Standard Methods for the Examination of Water and Sewage. Amer- ican Public Health Association, 755 Boylston Street, Boston, 2d ed. (1915), . 69-70. 94 Babcock, Allen H., A novel method of handling boilers to prevent corrosion and scale, Journ. Am. Soc. Mech. Eng. (1916), 38, 530. WATER FOR INDUSTRIAL PURPOSES 65 in the course of his geological researches, observed that certain members of the group of rock minerals called zeolites had the property of softening waters that passed over or through them. In 1906 Gans patented a process for the synthetic production of zeolites. The following is an empirical formula for the mate- rial now sold commercially as permutit : 2Si0 2 • A1 2 3 ■ Na 2 • 6H 2 0. When a water containing calcium or magnesium compounds is passed through a porous filter or mass of this sodium-permutit (which is insoluble in water), the sodium in the permutit is replaced by the calcium or magnesium. Thus calcium sulphate, in passing through a filter of permutit, would be converted to sodium sulphate, the calcium remaining behind, forming a cal- cium permutit, also insoluble. By regulating the flow according to the capacity of the filter, water of zero hardness may be ob- tained. The material is regenerated by passing through it a 10 per cent solution of common salt, whereby the calcium is re- placed by the sodium and passes out as calcium chloride. Com- mercial installations of permutit have been made both in the United States and in Europe, and one for feed-water softening has been recently ordered by a large factory in the Philippines. Related to permutit are the Allagit and the Reichling pro- cesses, which consist in passing the raw feed water through a filter of rocky material, which removes the scale-forming ingredients. From the foregoing it will be seen that the characteristics of a good boiler water are freedom from acidity; absence of sul- phates and magnesium salts ; low concentrations of calcium com- pounds, suspended and colloidal matter, and dissolved gases; and the presence of only small amounts of sodium and potassium salts. How hard a water may be used without treatment is decided most practically by a comparison of the cost of artificially soft- ening the water with the savings effected by thfe use of the softened water. The benefits of softening include: 95 Saving in boiler cleaning, in boiler repairs, and in fuel due to decrease in scale; fewer idle boilers; decreased depreciation of boilers; value of mate- rials removed by softening plant; and reduced liability to accident and involved losses. 95 Slightly modified from Aubert and Rogers, Industrial Chemistry for the Student and Manufacturer (1913), 52. 152918 5 66 PHILIPPINE WATER SUPPLIES The cost of softening includes : Labor and power for operating softener; softening chemicals; interest on cost of installation, depreciation of softening plant; and waste in changing water due to increased foaming tendency of the water. While it is almost invariably true that practically any cost of treat- ment will pay returns on the investment, the fact must not be overlooked that there are certain waters which should never be used for boiler purposes, and which no treatment can render suitable for such purpose. In such cases the only remedy is the securing of other feed supply or the employ- ment of evaporators for distilling the feed water as in marine service. 96 WATER FOR OTHER INDUSTRIAL PURPOSES Besides its use for steam making, water plays a most impor- tant role in the industries, not only in the process of manufac- ture, but often as part of the finished product. While, in general, the qualities most desired in a water for industrial purposes are softness and freedom from suspended matter, there are certain industries for which waters of a par- ticular composition are the most suitable. Water that is en- tirely unsuited for one manufacturing process may be very desirable for another. Waters containing sodium chloride are undesirable for soap making, yet are sometimes decidedly advantageous in brewing. Hard waters entirely unsuited for laundry or boiler use may be quite suitable for irrigation pur- poses. Waters containing calcium and magnesium sulphate, adaptable to brewing, are undesirable for soap making or boiler use. In the making of beverages and other food products, not only must the water be chemically satisfactory, but it must be hygien- ically acceptable. Typical cases in the Philippines are found in the preparation of carbonated water products, which have been already discussed, and the manufacture of ice. In con- nection with the latter, it should be remembered that artificial ice contains all the impurities of the bulk of water from which it was made, this being frozen entire. In the formation of natural ice, on the other hand, the impurities remain in the fluid portion. Cummings 97 found in natural ice exceedingly small amounts of solid residue, usually below 10 parts per mil- lion. He further observed a very large reduction in the bac- terial content of the ice as compared with that of the water from which it was formed. In three cases this reduction was from 12,000 to 125, 520 to 3, and 1,400 to 10, respectively. 9t Babcock & Wilcox Co., Steam: Its Generation and Use (1913) 100. 97 Cummings, H. S., Journ. Am. Med. Assoc. (1916), 67, 751. WATER FOR INDUSTRIAL PURPOSES 67 While in the Philippines distilled and artesian waters are used almost exclusively in the manufacture of artificial ice, an im- pure and unwholesome product sometimes results from the care- less handling of the initially pure water. Though bacteria usually die rapidly in ice, undue reliance should not be placed on this form of self -purification. The effect of the substances commonly found in water on a number of the industries will be discussed under interpretation of analyses. The Filipinos are primarily an agricultural people. The two principal crops in the Philippines that require any great amount of cultivation are rice and sugar cane ; both of these, especially the former, require much water for their development. Irrigation has been long known in the Philippines in connection with rice culture; it reaches a remarkable stage of development in the wonderful terraced paddies of the Ifugaos and other non-Chris- tian tribes of northern Luzon. While hitherto the rains have been relied upon to supply the water necessary for the growth of sugar cane, irrigation is coming into use in those localities where it can be employed. The question of the desirability of a water for irrigating pur- poses has always been an important one. Surface waters are naturally most commonly used, due to their availability and to the comparatively small effort involved in their employment. In some localities spring waters, when available and of desirable quality, are used to a considerable extent. In other places, notably in certain districts in the western part of the United States, the surface waters have been of such poor quality as to necessitate the perforation of deep artesian wells at great expense. In the Philippines surface waters are most exten- sively employed, though, in the case of "wet weather" streams, the water is oftentimes available only in the rainy season. Spring waters are also used, but to a less extent. The drilling of artesian wells to supply water for agricultural purposes is not practiced in the Philippines. The commonest deleterious substances in irrigating waters are salts of the alkalies, notably the carbonates, chlorides, and sulphates of sodium and potassium. Calcium and magnesium carbonates are seldom present in objectionable amount, both because of the fact that even very high initial concentrations are usually lowered by aeration and removal of carbon dioxide and because the addition of these carbonates very often has a bene- ficial fertilizing action. 68 PHILIPPINE WATER SUPPLIES Land would probably be injured by the best of natural waters if irrigated with them for a long period of time without natural or artificial drainage, for all irrigating waters contain alkali, and evaporation in and from the soil would result in a gradual accumulation of toxic salts. 98 Loughridge " found the relative toxicities of the alkalies to- ward common cultures of bacteria to be about as follows : Toxicity. Sodium as Na 2 C0 3 10 Sodium as NaCl 5 Sodium as Na 2 S0 4 1 The investigations indicate further that about 1,680 kilograms per hectare (1,500 pounds per acre) of sodium with a relative toxicity of 1 (as above) in 1.2 meters (4 feet) of soil is barely sufficient to affect injuriously the more sensitive common crops. Stabler used these and other similar experimental data as a basis for the calculation of an alkali coefficient that may be made from a water analysis by the means of the following formulas : (a) When Na— 0.65C1 is zero or negative, 2040 alkali coefficient K = . CI (b) When Na— 0.65C1 is positive, but not greater than 0.48SO 4 , 6620 alkali coefficient K = • Na +■ 2.6C1 (c) When Na-0.65Cl-0.48SO 4 is positive, alkali coefficient K = Na-0.32Cl-0.43SO 4 Based on the values of the alkali coefficients thus obtained, the following approximate classification of irrigating waters is given : Alkali coefficient. Class. More than 18 Good. 18 to 6 Fair. 5.9 to 1.2 Poor. Less than 1.2 Bad. 95 Stabler, Herman, TJ. S. Geol. Surv., Water Supply Paper (1911), No. 274, 177. 99 Stabler, loc. cit. MINERAL WATERS The term "mineral water" is somewhat confusing. Prac- tically all natural waters contain dissolved mineral matter and might be properly classified as mineral waters. However, in the more restricted meaning of the term, only those waters are included that have peculiar characteristics distinguishing them from ordinary spring or well water. According to Griin- hut, 100 a mineral water is identified by (a) a high content of soluble matter, (b) a high content of rare or unusual substances, or (c) a high temperature. Table III shows the substances on the basis of which he makes his classification and the limiting values for each substance: Table III. — GriinhuVs basis for classification of mineral water. Substance. Parts per million. Total solids 1,000 Free carbon dioxide 250 Lithium (Li) 1 Strontium (Sr) 10 Barium (Ba) 5 Ferrous or ferric iron (Fe) 10 Bromine ion (Br) 5 Iodine ion (I) 1 Fluorine ion (F) 2 Arsenic (As) 1.05 Total sulphur (S) 1 Metaboric acid (HB0 2 ) 5 Alkalinity 400 Radium emanation 3.5 Mache units per liter. Temperature 20° C. a a Obviously this value could not be used in a country like the Philippines, where in many localities the average temperature is much higher and water is usually from 25° to 30° C. If any of these values 101 is exceeded, the water may be re- garded as a mineral water. Mineral waters are further classified on the basis of the ingredients that give them their predominant characteristics. One of the best systems of classification is that of Haywood and Smith, 102 which is generally used in technical work. A simpler, 100 Griinhut, L., Zeitschr. f. Balneol. (1912), 4, 433^6; Wasser u. Abwasser (1912), 5, 417-20; Pharm. Zentralh. (1914), 55, 180. 101 This classification has been adopted by the Verein der Kurorte und Mineralquellen-Interessenten Deutschlands, Oesterreich-Ungarns, und der Schweiz. 102 Haywood, J. K., and Smith, B. H., Bull. U. S. Dept. Agr., Bur. Chem. (1905), 91, 11. 69 70 PHILIPPINE WATER SUPPLIES less complete classification, sufficient for the purpose of this paper, is as follows: 103 I. Thermal, Example, Los Baiios springs, Laguna. II. Carbonated (or bicarbonated) . 1. Alkaline, containing: a. Sodium bicarbonate. b. Potassium bicarbonate (rarely). Example, Dinalupihan Spring, Bataan. 2. Magnesium, containing: a. Magnesium bicarbonate. Example, Hot Spring, Puerto Galera, Mindoro. 3. Calcareous, containing: a. Calcium bicarbonate. Example, Bolocboloc Spring, Barili, Cebu. III. Chalybeate (iron, ferruginous). 1. Containing the sulphate or bicarbonate of iron. Example, Lanot Spring, Ambos Camarines. IV. Muriated waters. 1. Containing salts, mainly sodium or potassium chlorides. Example, Mainit Spring, Bontoc. V. Aperient or sulphated waters. 1. Containing sodium sulphate (Glauber's salt). Example: Klondike Spring, Benguet. 2. Magnesium sulphate (epsom salt). Example, Tancalao Spring, Tabaco, Albay. VI. Bromide and iodide waters. 1. Containing the bromides or iodides of sodium and potassium. Examples, Maaslom Spring, Cebu. (Few definitely known in the Philippines.) VII. Sulphuretted or hepatic waters. 1. Containing sodium or hydrogen sulphide. Example, Sibul Spring, Bulacan. VIII. Arsenical. 1. Containing arsenic. Example, Tiwi Spring, Albay. IX. Lithia. 1. Containing lithium salts. No good example known. 104 There are other classes of water, such as iodic, borated, and lithic; but these are not so common, or else their properties are indicated by their names, so that they need not be further dis- cussed here. It is not the intention to discuss at length the medicinal prop- erties of different Philippine waters. At best, the physiologic action of various ingredients in the minute quantities present in waters must remain in doubt. The curative properties some- times attributed to various mineral springs appear grossly exag- gerated, and it hardly seems plausible that the small amounts 103 Cf . Rideal, op. cit., 12. 104 No lithium-bearing minerals have been found in the Philippines. MINERAL WATERS 71 of mineral salts contained in such waters would have the won- derful power ascribed to them. For example, 105 Though it is true that many drugs are as efficient when given in very- small, but frequent doses, as when given in one large dose, the therapeutic value of 1 part per millon of lithium (the amount present in some waters widely advertised as lithia waters) may well be questioned, because a physician would have to prescribe 200 tumblerfuls of the water in order to administer an ordinary minimum dose. No doubt the pleasant surroundings of the average medicinal spring resort, combined with fresh air, good food, and general relaxation and exercise, contribute their share toward the im- provement in the health of a patient and help make possible the remarkable cures often recorded. Our experience in the Philippines has shown that little reli- ance can be placed on popular opinion as a criterion of the value of mineral waters. Springs supposed to be of great medicinal value have been frequently found to be of very ordinary che- mical content, whereas many waters that compare favorably with those of well-known baths and springs in foreign countries are regarded with complete indifference. A certain town has an artesian water very similar chemically to that of Sibul Springs, yet there was, until a short time ago, a decided anti- pathy to its use. Very recently wonderful curative properties were attributed to a certain artesian well, and hundreds of people traveled many kilometers to partake of its waters; yet this water is in many respects similar to a supply in another province that people frequently refuse to drink. Observations were made on one of the best-known and most popular springs a short time ago, 106 with some curious results: In order to ascertain whether the water has laxative or constipating properties a record was kept of a large series of cases for the effect which water had upon persons who visited there, with the result that diarrhoea was produced in approximately one-third of the people, constipation in another third, and the remaining third was apparently unaffected in so far as action of the bowels was concerned. However, the value of mineral waters is now so generally accepted that their use has become firmly established in ther- apeutic practice. The following statement of the medicinal values 107 of different classes of mineral waters is taken directly from Haywood and Smith. 108 105 Dole, U. S. Geol. Surv., Water Supply Paper (1910), No. 254, 25. 103 Ann. Rep. P. I. Bur. Health (1913), 32. 107 Compare also the statements on the effect of various ingredients in the chapter on Interpretation of Water Analyses. 108 Op. cit., 12. 72 PHILIPPINE WATER SUPPLIES The physiological action and therapeutic applications of the various classes of mineral waters here given do not represent the results of experiments carried on in the Bureau of Chemistry, but are gathered from works which are considered authoritative on the subject. 21 [Footnote : a Among these are Crook's Mineral Waters of the United States and Canada, Schweitzer's Mineral Waters of Missouri, and Cohen's System of Physiologic Therapeutics.] Carbonated or bicarbonateol alkaline waters. — This is one of the most important groups of mineral waters. As a class these waters are used to stimulate the secretions of the digestive tract, neutralize superacidity of the stomach, increase metabolism, dissolve uric acid, increase the flow of urine, correct acidity of the urine, and dissolve uric acid deposits. They are therefore of value in catarrhal conditions of the mucous mem- branes, rheumatism, gout, diabetes, etc. Sodic carbonated and bicarbonated alkaline waters. — Sodium carbonate or bicarbonate appears as a normal constituent of the blood, lymph, and nearly all secretions of the mucous membrane. Where conditions arise that cause any of these fluids to become acid, this class of waters is of great value in counteracting the effect. The sodic carbonated waters in- crease metabolism, dissolve uric acid, and allay irritation of the mucous membrane of the urinary tract. They have therefore been used with excellent results in treating acid dyspepsia, rheumatism, gout, and diabetes. Such waters are also of value in breaking up and eliminating uric acid deposits and uric acid sand and gravel. Potassic carbonated and bicarbonated alkaline waters have very much the same action as the sodic carbonated, except that they are perhaps better for increasing the solubility and elimination of uric acid. The chief use of such waters as these is in the treatment of stone in the bladder. Lithic carbonated and bicarbonated alkaline waters. — While lithium seldom or never occurs in waters in large enough quantities to be a pre- dominating basic constituent, still it does often appear in sufficient quan- tities to have a decided therapeutic action. These compounds are active diuretics and form a very soluble urate which is easily eliminated from the system. Waters of the above class therefore find, their greatest ap- plication in the treatment of rheumatism, rheumatic tendencies, and gout. In cases of gravel and calculi they are also valuable disintegrating agents. Magnesic carbonated and bicarbonated alkaline waters. — Such -waters as these act as mild laxatives and are perhaps the best of all the carbon- ated alkaline waters in correcting an acid condition of the stomach and curing sick headaches caused by constipation. They favor the solution of uric acid, are valuable agents in breaking up deposits in the bladder, and are much used in catarrhal conditions of the mucous membrane of the urinary organs. Calcic carbonated and bicarbonated alkaline waters. — This class of waters is quite different in its effect from the carbonated waters previously men- tioned. While the foregoing waters are evacuant and promote secretions, this class of waters constipates and decreases the secretions. Very ob- stinate cases of chronic diarrhea have been cured by a sojourn at a spring rich in calcium bicarbonate. Uric acid gravel and calculi are also dis- integrated and eliminated by the free use of the above waters. MINERAL WATERS 73 Ferruginous bicarbonated alkaline waters. — These waters increase the amount of haemoglobin and in connection therewith increase the tempera- ture, pulse, and weight. They also increase the appetite and reduce intes- tinal activity. Such waters give excellent results when used as a tonic. They find their principal application in anaemia and in general debility brought about by sexual diseases. Too long use of waters rich in iron results in constipation and derangement of the digestion. B orated alkaline waters. — There are comparatively few springs of this description which have been used to any extent. Their therapeutic ap- plication, therefore, is somewhat obscure. It may be said, in general, that such waters act as anti-acids. They promote the menstrual flow, and so may be used in catamenial irregularities. Applied locally to catar- rhal mucous membranes, they are of value. Muriated alkaline-saline waters. — These waters are especially valuable in the treatment of catarrhal conditions of the mucous membrane of the stomach, intestines, and biliary passages, and urinary tract. They in- crease the flow of urine and the excretion of uric acid. The stronger ones are often used as a gargle. Sulphated alkaline-saline waters. — These waters, like the preceding class, are valuable in the treatment of catarrhal conditions of the mucous membrane. They also act as diuretics. In large quantities they act as purgatives by increasing the peristaltic movement and liquefying the in- testinal contents. Such waters as these are especially indicated in obesity. Muriated saline waters. — As a whole these waters stimulate the secre- tion of the stomach, increase digestion, favor a more complete absorption of foods, and act as diuretics. Sodic muriated saline waters. — Where these waters are very heavily charged with sodium chlorid they are often used for baths, to increase the action of the skin, and by absorption act as a tonic. Such waters when taken internally are usually diluted. They increase the flow of gastric juice, improve the appetite, increase the flow of urine, and the urea in the same. They also prevent putrefactive changes in the intestines. Potassic muriated saline waters. — The authors do not know of any waters which belong to the muriated saline group and yet contain potas- sium as a predominating constituent. However, potassium is sometimes present in these waters in considerable quantities. Its therapeutic action is very much like that of the sodium salt. Lithic muriated saline waters. — Such waters as these would have the usual action of the muriated saline class, with an intensified diuretic effect, due to the lithium. Calcic muriated saline waters. — These waters usually have sodium as the predominating basic constituent, along with notable amounts of calcium and sometimes magnesium. In general debility these waters act as a tonic. They increase the flow of urine, sweat, and bile, and are used in the treatment of scrofulous diseases and eczema. Sulphated saline waters. — As a class, these waters are laxative or purga- tive according to the quantity taken, and should generally only be used in moderate amounts. They are especially indicated where long-continued stimulation of the intestinal activity is desired without stimulation of the vascular system. Sodic and magnesic sulphated saline waters. — In small doses these 74 PHILIPPINE WATER SUPPLIES waters act as laxatives and in large doses as purgatives. They increase the flow of the intestinal fluids and of the urine, the latter being accom- panied by an increased elimination of urea. Such waters as these are of great service in eliminating syphilitic, scrofulous, and malarial poisons from the system and in throwing off mercury and other metallic poisons. Persons suffering from obesity, dropsy, derangement of the liver, and Bright's disease are perhaps the most benefited by this class of waters. Potassic sulphated saline waters. — While potassium may be present in large enough quantities in the sulphated saline waters to deserve mention, the authors do not know Of any waters in which it is a predominating basic constituent. In so far as it is present, however, it has very much the same effect as. the two salts mentioned above. Calcic sulphated saline waters. — This class of waters forms what is known as the permanently hard group. They have no well-known ther- apeutic action. Ferruginous sulphated saline waters and aluminic sulphated saline waters. — Iron and aluminum usually occur together when either is present as a predominating metallic constituent in sulphated saline waters. Since waters containing large quantities of iron and aluminum along with sul- phuric acid ions are practically always acid, it is best to consider them under the sulphated acid group. Nitrated saline waters. — The authors have only found one water which belongs to this class, and are undecided, on account of not being able to examine the surroundings of the spring, whether the nitrates are due to organic nitrogenous matter which is in active state of decomposition or to nitrogenous matter which has been oxidized in times long past and is therefore no longer injurious. In either case, however (especially in the latter) , the existence of one water containing predominating quantities of nitrates necessitates a classification to cover this group of waters. The medicinal action of these waters has not been determined. Acid waters. — This group of waters is principally composed of the fer- ruginous-aluminic sulphated class, although there are a few acid springs which contain comparatively little iron and aluminum, but quite large amounts of calcium, sodium, or magnesium. These waters are used in relaxed conditions of the mucous membrane, especially when characterized by diarrhea or dysentery. These are also used in the treatment of exhaust- ing night sweats and impoverished conditions of the body brought about by intemperance or specific diseases. Locally they are used in treating inflamed or relaxed conditions of the mucous membrane such as are found in conjunctivitis, chronic vaginitis, etc. The ferruginous waters of this group have the usual effect of all iron waters, such as has already been described under ferruginous carbonated alkaline waters. When a water is desired for its tonic effect it is best to give it in the ferruginous car- bonated form, since it is more easily absorbed and assimilated. Iodic and bromic waters. — Since iodin and bromin usually accompany each other in mineral waters, they should be considered together. Waters of this class act as alteratives. They stimulate the lymphatic system to greater activity and promote absorption in all the tissues. Their employment is therefore indicated in the treatment of scrofula, syphilis, goiter, chronic exudations, etc. They also favor the elimination of mercury and other metallic poisons. The bromic waters also act as sedatives. Arsenic waters. — These waters act as an alterative, increase the ap- MINERAL WATERS 75 petite and digestion, and improve the whole nutrition of the body. They do this not only by increasing the secretion of the gastro-intestinal membrane, but also by checking katabolism. Such waters as these are especially valuable in the treatment of anaemia and a number of skin diseases. They are also indicated in the treatment of chronic malarial poisoning, neuralgia of anaemia origin, scrofulosis, etc. Silicious waters. — The medicinal value of these waters has not been thoroughly investigated, althought one or two investigations have been made which seem to show that they would be of value in the treatment of cancer. It has been stated that silica taken internally has caused albumin and sugar to disappear from the urine. Azotized and oxygenated waters. — Both nitrogen and oxygen are present in all waters that have come in contact with the air. On account of the limited solubility of both they can not occur in waters in very large quantities. Neither of them as they occur in waters has any medicinal value. Carbondioxated waters. — These waters contain free carbon dioxid as distinguished from the carbonated or bicarbonated waters which contain carbon dioxid in combination. Usually the heavily carbondioxated waters are also bicarbonated, but this is not necessarily true. Free carbon dioxid is present in practically all natural waters to some extent, but in some waters, notably the Saratoga, it is present in very large quanti- ties. Such waters are extremely palatable and large quantities can be drunk without causing a "full feeling." These waters tend to increase the flow of saliva and intestinal fluids, also to increase the peristaltic movements of the stomach, and therefore increase digestion. They also tend to increase the flow of urine. Obstinate cases of nausea are often relieved by the use of this class of waters. Carbureted waters. — These waters sometimes occur in coal and natural- gas regions. They are not known to have any medicinal value, but are usually considered unfit for drinking purposes. Sulphur eted waters. — These waters increase the action of the skin, in- testines, and kidneys. They also possess a decided alterative effect. They have been used in the treatment of syphilis, chronic metallic poisoning, rheumatism, and gout. They have also given excellent results in many skin diseases, hypersemia of the liver, and catarrhal conditions of the pharynx, larynx, and bronchi. The radioactive waters should be added to this list, as these have been frequently found to be of therapeutic value. Because of the importance of this class of waters, they will be discussed under a separate heading. As a general rule, better therapeutic effect has been obtained by the use of waters directly at the source than when taken at a distance, and this for a variety of reasons. Radioactivity is an evanescent quality, which cannot be conserved by bottling; natural waters are unstable and undergo changes on standing; and above all the physiological effect of imbibing waters at the source is of importance. At considerable distances from desir- able sources, however, the use of bottled waters is much practiced. 76 PHILIPPINE WATER SUPPLIES There is sound basis for this procedure, especially among trav- elers, who find it a great convenience and a direct benefit to health to be able to go from place to place without changing the kind of drinking water. As there is no inherent difference between a natural water and one artificially compounded, it is but natural that numerous successful attempts have been made to impregnate waters with salts in order to make them approximate the composition of famous mineral-spring waters. Transportation charges are thus lessened, the amount of water that can be placed on the market is not limited by the flow of a spring, and the cost of water is generally reduced materially. An artificial "Karlsbad" salt has even obtained 109 a place in the German pharmacopoeia. Its for- mula is as follows: Parts Anhydrous sodium sulphate 22 Potassium sulphate 1 Sodium chloride 9 Sodium bicarbonate 18 A supposedly better tasting preparation is compounded as follows : Parts. Potassium sulphate 1.6 Sodium chloride 10.0 Sodium bicarbonate 27.5 Anhydrous sodium sulphate 15.0 Precipitated calcium sulphate 5.0 Anhydrous magnesium sulphate 2.0 No systematic study of mineral waters has been yet under- taken on a large scale by the Bureau of Science, so that our records are still too incomplete to warrant a detailed discussion of the springs of the Philippines. The best published data on this subject are the monographs and bulletins of the Spanish Government, to which reference was made in the first footnote. The data secured by the Bureau of Science are shown in the tables of analytical results, especially Table XII. Practically every province in the Philippines has many excel- lent springs, some of them with great reputations for medicinal virtues. In addition, the drilling of artesian wells has made available a large number of excellent mineral waters. Popular preference, however, is usually given to water from a spring. A few of the more important Philippine mineral waters are briefly described below. The list contains only those that have been examined by members of the Bureau of Science staff and 109 Cohn, H., Sammlung Chem. u. chem. tech. Vortrage (1906), 10, 409-500. MINERAL WATERS 77 includes several that are not really mineral waters, but that have reputations for medicinal properties. Other sources are given in the tables. Albay. — The hot springs at Tiui have been described by Adams and Pratt, as follows: 110 Tiui Hot Spring. — The most noted hot springs of this region are near Tiui; they have been described by Jagor, von Drasche, and Abella. Abella considered them as subordinate volcanic emanations of Malinao. "Hot water accompanied by sulphurous gas issues at a place termed Jigabo, in the bed of a small stream, the Naga. This place has the nature of a fumarole. The stones in the river bad have been largely decomposed by the chemical action of the waters, and the ground and stones in places are coated with a sulphurous efflorescence. This spot is but a short distance to the west of Tiui. A small bath house has been constructed, and a pit walled up with stones serves as a pool for bathing. The temperature of the bath is regulated by conducting the desired amount of cool water from the stream into the ditch which leads the hot water to the pool. Farther up the stream there is a place where some gases emanate from the ground and the water is somewhat miner- alized. Naglagbong, which lies down the stream, is the principal point at which the hot waters of Tiui are found. There is a pool about 20 meters in diameter filled nearly to the rim with water, which steams very slightly. Around it there is a white, silicious deposit which shelves out over the water. The pool is transparent, and in the depths the water has beautiful, blue colorings, and fantastic, silicious deposits may be seen forming the sides of the basin and the narrow, irregular opening in the bottom. There is white, silicious sinter near by, covering a considerable area and grading off into bluish mud. Many minute cracks and vents occur in the sinter, from which small quantities of sulphurous gas, mixed with steam, arise. "The water near by in the shallow pools is hot, and bubbles of gas break on its surface at some places. The silicious sinter has been built up in a low, irregular, convex area on which there is what is termed the white cone. This place at one time must have contained a central opening in which the hot waters arose. The silica deposited from the water grad- ually built a rim around the opening and then sealed its mouth, leaving a small basin-like depression on the top. To the northwest on the white cone, there is another large pool of hot water and beyond it the deposits are tinged and in part vividly colored with red oxide of iron. Fantastic forms of the silicious material may be seen simulating coral growth. Foreign substances which have accumulated i\ear the hot waters are coated with the sinter." The waters are thermal, sulphureted, and arsenical. Ambos Camarines. — The Lanot and other springs on the west coast of San Miguel Bay are ferruginous, carbon-dioxated. In addition to the spring above mentioned, attention may be called to 110 Adams, G. L, and Pratt, W. E., Phil. Journ. Scl, Sec. A (1911), 6, 468-469. 78 PHILIPPINE WATER SUPPLIES the hot springs near Manito, across the bay from Legaspi. One of these on the beach is covered at high tide, but at low water it sends up a small column of steam which can sometimes be seen from passing steamships. There are other hot waters and a number of mineral springs in the region of the cordillera, but they are considered of little importance at present. 1 " Batangas.— There are a number of thermal and other mineral springs in Batangas, which, however, have not been much studied. A flowing artesian well at Batangas is worthy of men- tion (see radioactivity) as the most radioactive source yet found in the Philippines. Bulaccm. — Of the many mineral waters of Bulacan Province, only two have been sufficiently studied to merit description here. The springs at Sibul are nonthermal, mildly suphureted sources of very great capacity. A splendid bathhouse has been erected here by the Insular Government. People come from great distances for the waters, which have^ perhaps, the greatest reputation for medicinal virtues of any waters in the Islands. The usual statements based on the chemical analysis regarding the therapeutic value of these springs are undoubtedly erro- neous, as the waters are only moderately mineralized. How- ever, the springs are among the most radioactive yet found in the Philippines. The artesian well at Marilao has acquired a great reputation, and a bathhouse has been built. The waters are nonthermal and are not sufficiently mineralized to be classed as mineral waters. They are not radioactive. There is no apparent reason why they should be considered medicinal. Cebu. — At the request of the Speaker of the Philippine As- sembly an investigation of the mineral springs of Cebu was conducted by Mr. Gana, 112 of the Bureau of Science. The results of his work are incorporated in Table XII (spring waters). Cebu has many excellent thermal and mineral springs. Boloc- boloc Spring, at Barili, is nonthermal, sulphurated, bicarbonated, carbon-dioxated. Other sources are "Mainit," Naga, a thermal spring; a nonthermal sulphureted spring at Dumanjug; a hot spring at Malabuyoc; and others, whose analyses are shown in the tabular data. Iloilo. — Perhaps the best-known springs are those on Guimaras Island. They are chiefly nonthermal, calcic, bicarbonated. Laguna. — Laguna Province is well supplied with springs, 111 Adams and Pratt, loc. cit. " 2 Cox, A. J., Heise, G. W., and Gana, V. Q., Phil. Journ. Sci, Sec. A (1914), 9, 273. MINERAL WATERS 79 especially in the vicinity of Mounts Maquiling, Banajao, and San Cristobal. There are many springs in the neighborhood of Los Baiios and on the slopes of Mount Maquiling. A large sanatorium has been erected at the town of Los Banos, which attracts many visitors. The Los Baiios hot springs are only moderately mineralized. They are, however, the most highly radioactive thermal sources known in the Philippines. Pansol Springs, between Calamba and Los Baiios, have no abnormal chemical characteristics. It is popularly believed that they are alternately hot and cold. This erroneous im- pression is due to the fact that they are really a series of hot and cold springs, of very different chemical composition, which emerge into the same pool of water. These springs are located in a very beautiful grotto. A large spring, called Bumbungan, is located near Pagsanjan, on the river bank near the famous Pagsanjan gorge. A stone bathhouse, dating back to Spanish times, has been erected. The water is of very ordinary mineral composition and is only very moderately radioactive. There is a very picturesque spring at Pakil, which flows into a large pool or basin. Medicinal properties are attributed to this source, and religious pilgrimages are made to it. The water is only slightly mineralized and is moderately radioactive. Among other well-known springs, the following may be men- tioned: Sinabac, Majayjay, of ordinary mineral composition but highly radioactive, and a series of moderately radioactive springs of no abnormal chemical characteristics, such as San Diego and San Vicente, Nagcarlan; Baiio and Baiiadero, San Pablo; and San Mateo, Lilio. Leyte. — This Bureau has little first-hand information con- cerning Leyte mineral waters. Adams 113 mentions a number of thermal and cold mineral springs. He says : Besides the springs already mentioned as associated with the solfataras on Biliran Island and near Burauen in Leyte and those related to the extinct volcanoes, Mount Amandiuing and Mount Cabalian, there is a small hot spring on the west side of the point of land which projects from Leyte opposite Poro Island in the Biliran strait and a hot sulphur spring on Mount Ogris south of Mount Nipga between Abuyog and Baybay. South of Abuyog in the barrio Buenavista there is a cold mineral spring. To the west of Alangalang, on the west side of the Cabayong River, there are some small and apparently nearly buried hills which are probably 113 Adams, G. I., Phil. Journ. Sci, Sec. A (1909), 4, 345-6. 80 PHILIPPINE WATER SUPPLIES outliers of the Cordillera and at the base of one of these there is a cold mineral spring, Mindoro. — Comparatively little is known of Mindoro. The thermal, sulphureted, sulphated, bicarbonated springs of Puerto Galera may be mentioned in passing. At Calapan there are a few hot and sulphur springs that were used as baths in Spanish times. Misamis. — Springs in great variety and abundance are found in Misamis. 114 Mountain Province. — As might be expected in a volcanic, mountainous region, Mountain Province is plentifully supplied with springs. Owing to the difficulty of travel and the back- ward state of the inhabitants, these springs are comparatively little visited. Only a few of the better known hot and heavily mineralized springs will be mentioned here. Klondike springs are situated on Benguet Road, on the west bank of Bued River. They are very hot and only moderately mineralized and sulphated. There is a series of hot, sulphureted springs that have been used for medicinal purposes for many years about a kilometer below Balongabong, or Twin Peaks, on the west bank of Bued River. These springs have a temperature of 50 °C. At Itogon, only 15 to 17 kilometers from Baguio, is a series of hot, heavily mineralized springs, which were once much visited. In recent years a landslide covered some of them and changed the character of others, but they are still capable of development. As they are comparatively close to Baguio, they could be readily utilized. The hot springs near Cervantes, notably at Comillas, also have a considerable reputation for medicinal virtues. There is a remarkable series of springs at Kiangan used, in a great measure, for irrigation purposes. Though not charac- terized by any abnormal chemical ingredients, these springs are highly radioactive. One of these springs (Adukpung) is worthy of more than brief mention. It emerges from the wall of a rice paddy, only a few centimeters below the level of the water in the field, and has all the appearance of a seepage spring. It is asserted, however, that it flows throughout the year, even when the rice paddy is dry. The high radioactivity of this water and the data obtained from its chemical analysis as com- 114 Rev. Selga, S. J., secretary of the Weather Observatory, recently visited the springs on Camiguin Island and furnished the Bureau of Science with a report, which should be of value when the opportunity arrives to do intensive work on mineral waters. MINERAL WATERS 81 pared with that of the rice paddy water indicate that it is a true spring. It would be interesting to examine the water-bearing strata at this place. There are many saline springs, some of which are, or have been, used for salt making. Chief among these are the boiling hot Mainit Spring near Bontoc, whose waters, though used for salt manufacture, 115 are also used for medicinal purposes; Ba- lotoc, 10 kilometers east of Lubuagan, boiling hot and very highly mineralized; and Tukukan, Ahin, and Bungubungua, in Ifugao. Salt making at Amdangle, Ifugao, and at Asin, near Daklan, Benguet, has been discontinued, because landslides have ruined the springs. Negros. — Springs of many different kinds are common on Negros, but no intensive study of them has been yet made. There is a small sulphureted spring with reputed medicinal properties near Isabela, Occidental Negros. The springs at Mambucal on the sides of Mount Canlaon are very highly prized. Two springs in Oriental Negros are especially worthy of men- tion, namely, Masaplud, acid aluminic, sulphated, and a thermal saline spring at Palimpinon. Nueva Vizcaya. — The mineral waters of Nueva Vizcaya have not been intensively studied. The saline spring at Salinas 116 is used for salt-making. This spring issues from the top of a great white mound of calcium salts deposited from the water (Plate XVII). The water is only very slightly thermal. Palawan. — There is a salt spring at Culion. Sorsogon. — Many mineral waters are to be found in Sorsogon Province. A hot spring at Bulusan yields ferruginous, bicar- bonated, muriated water; a thermal, carbon-dioxated spring is located at Irosin; a "gushing" artesian water at Sorsogon is calcic, bicarbonated. The foregoing discussion is merely complete enough for the interpretation of the new data presented in this paper. In a country like the Philippines, where large amounts of bottled water are consumed, and almost a hundred thousand pesos' worth is imported annually, mineral waters are an asset whose utilization would be of great economic benefit. An intensive study of Philippine mineral springs should be carried on. The cost of such investigation would be only a small fraction of what is now spent annually for imported waters of no better quality than those available locally. 115 Cox, A. J., and Dar Juan, T., Phil Journ. Scl, Sec. A (1915), 10, 389. 116 Cf . Cox, A. J., and Dar Juan, T., ibid., 390. 152918 6 BOTTLED NATURAL AND CARBONATED WATERS The use of bottled waters in the Philippines is comparatively widespread. The report of the Bureau of Customs for 1916 showed that the value of imported waters for that year was 80,000 pesos. This was only 8,000 pesos less than the previous year, in spite of war conditions. When it is remem- bered that the great bulk of the imported waters is consumed in a relatively few port towns, this item becomes of considerable importance. The value of domestic bottled waters is much larger, though exact data are not available. Several causes contribute to the extensive use of bottled wa- ters in the Philippines. One is the natural fondness of the Filipino for carbonated water products, particularly the flavored ones. Another reason, which applies especially to the larger towns, is the employment of these products in connection with alcoholic beverages. By far the greatest single factor, however, that contributes to such use is the unsatisfactory condition of many of the water supplies and the desire, on the part of the consumer, to obtain a water whose purity is beyond suspicion. As has been previously mentioned, the importance of pure water for drinking purposes was not emphasized until after the American occupation. Manila alone had a municipal water system, and even this often supplied polluted water to the consumers. In 1900 the military authorities began the construction of a plant in Manila for the manufacture of ice and the distillation of water and for cold storage purposes. In June of the fol- lowing year the first ice and distilled water were sold. In 1902 the plant was taken over by the Insular Government and constituted the Bureau of Cold Storage. Five years later it became the division of cold stores of the Bureau of Supply, by which designation it is known at the present time. The use of distilled water for drinking purposes was at first confined largely to the American and European residents, but gradually spread so as to include the wealthier portion of the Filipino population. In 1913 the Bureau of Health suggested the employment of pure artesian water instead of the distilled product, as it was thought the former might be more wholesome 82 BOTTLED NATURAL AND CARBONATED WATERS 83 and palatable. Accordingly an artesian well was drilled for the division of cold stores. As water of excellent quality was obtained, the sale of distilled water has been greatly reduced since that time, its use being supplanted in great measure by that of artesian water. The Federal Government still operates distilling plants and distributes large quantities of water, not only in Manila, but in other parts of the Islands in which army posts are found. The Insular Government also operates a similar ice, cold storage, and distillation plant in Baguio, Mountain Province. Private individuals were quick to follow the example of the Insular Government. Several corporations were formed, a number of artesian wells were drilled, and the sale of artesian and distilled water soon became an important business enter- prise. Spring waters, too, received attention, notably those of Sibul and Los Banos. Several methods of distribution to the consumer have been employed. A few large tank carts are in service. More gen- eral, however, is the use of demijohns, holding about 19 liters (5 gallons), and of 1-liter bottles. Water that is initially pure may be unfit to drink when it reaches the consumer, due to unsanitary methods of bottling. Examinations made at the request of the Bureau of Health of samples taken at random from the distribution carts of various companies frequently have shown large numbers of undesirable bacteria and in some instances dangerous pollution. As these waters are not only extensively used by private individuals, but constitute the entire drinking supply of practically all of the hotels, hospitals, clubs, and other public and semi-public institutions as well, their super- vision is a matter of vital importance to the public health. The contaminated condition of several of these waters, at various times, has been a real menace to the community. In 1916, at the request of the manager of one of the largest artesian water companies in Manila, the Bureau of Science investigated the methods of bottling employed in his plant. It was found that in this, as in several similar establishments, steam sterilization for the water containers was relied upon, ; though the equipment used was entirely inadequate for the 'purpose. Under the conditions existing, it appeared that thor- ough sterilization by steam could not be economically prac- ; ticed. Accordingly a plan of chemical sterilization was devised. , This was adopted and installed by two of the largest privately , owned artesian water companies in Manila. The method has ; proved to be very efficient and economical. A detailed dis- 84 PHILIPPINE WATER SUPPLIES cussion of the process will be found in the Appendix, in the form of a . report made by the section of water analysis to the Director of the Bureau of Science in October, 1916. Outside of Manila the bottling of natural waters is confined almost entirely to a few of the large towns like Cebu, Marilao, Iloilo, and Zamboanga. Several of the United States Army posts, as has been mentioned, supply distilled or artesian water to the inhabitants of the vicinity. Accurate estimates of the extent to which bottled natural waters are employed in the Philippines cannot be made from the data available, either for the Islands as a whole, or for Manila in particular. It may be said that, even in Manila, the use of these waters has increased steadily, despite the improvements in the city supply. Their sale was at first largely among the American and European residents, but is now general among the better classes of all races. The division of cold stores, distributor of bottled natural water, sells monthly about 4,500 pesos' worth of artesian and distilled water, principally the former. Of this amount 95 per cent is delivered directly to the consumers throughout the city. Water is supplied at the rate of 1.5 centavos per liter delivered to points in the city and of 1 centavo when sold at the plant. Ap- proximately the same charge is made by the privately operated companies, though the price varies somewhat with the distance from the plant. The largest privately owned bottling company in Manila has a monthly output of natural and aerated waters valued at about 25,000 pesos, divided almost equally between the two kinds of products. Another large concern distributes each month about 2,300 pesos' worth of bottled natural waters and an amount of carbonated waters of about equal value. A large part of the output of both companies is shipped to provincial districts. When to these sales are added those of the dozen other water- bottling companies in Manila, an idea may be derived of the large extent to which these table waters are employed. While, as has been mentioned, the use of bottled natural waters is restricted almost entirely to Manila and a few of the other large towns, bottled carbonated waters are found in the most isolated provincial districts. In the more thickly settled sections almost every center of population has its plant for making "aguas gaseosas," or carbonated waters. The largest and best-equipped of these are located in Manila and in the immediate vicinity. In BOTTLED NATURAL AND CARBONATED WATERS 85 some cases they are part of a plant devoted to the bottling of natural waters and use the same water as the latter. In Manila the operations and products of these plants are subject to careful inspection by the Bureau of Health. Bacteri- ological purity is required, though no arbitrary standards have been fixed. The use of saccharin as a sugar substitute and of harmful dyes is prohibited. The carbonated water beverages now being sold in Manila are, generally speaking, of good quality. The bacterial content is usually small, and sometimes it is practically nil. Harmful dyes are rarely encountered, both because of their scarcity and be- cause of the abundance of cheap vegetable dyestuff s. Saccharin, which was commonly used in the past, is now found in less than 1 per cent of the samples examined in the Bureau of Science. In the provincial districts constant supervision is unfor- tunately impossible. As a result, the carbonated water prod- ucts manufactured and sold there are often very undesirable hygienically. In the course of the sanitary survey of an important provincial town, bacteriological examinations were made of 26 samples of carbonated water products, taken directly from the factories. The average number of bacteria per cubic centimeter was found to be 14,000, while organisms of the B. coli group were found in 38 per cent of the samples. In another town 54 per cent of 39 samples showed the presence of organisms of the B. coli group. These instances are typical. The unsatisfactory condition of these products must not be necessarily ascribed to the original quality of the waters em- ployed in their manufacture. Formerly waters from any source were used, rivers and dug wells having a prominent place. The efforts of the Philippine Health Service, however, have resulted in a more or less general abandonment of these undesirable sources, with the substitution of more suitable ones. Never- theless unwholesome beverages are often produced, even when unquestionably pure water, such as that from flowing artesian wells, is employed in their manufacture. The root of the trouble, therefore, as in the cases of the bot- tling plants in Manila, must be sought in the methods of manu- facture and handling. The equipment for the manufacture of carbonated water products in the provincial districts is usually very primitive. It is often located in a dirty, poorly lighted room in the rear of a tienda. An exceedingly simple apparatus serves for the generation of carbon dioxide from sodium bicar- bonate (baking soda) and sulphuric acid. The bottles are poorly 86 PHILIPPINE WATER SUPPLIES cleaned, a single rinsing with cold water often sufficing. The bacteriologist who collected samples of soda water in a certain town found that "open well water was used in cleaning the dirty bottles" and that "flies were very numerous." The sirups are poorly made, saccharin being sometimes employed. Instead of "crown" caps, corks are frequently employed, these being inserted and wired without previous sterilization. Under these conditions it is scarcely surprising that the bac- teriological quality of bottled waters is sometimes very poor and that fermentation of the sweetened beverages results in evil-tasting and unsalable products. At the present time the great production and sale of highly polluted bottled waters are a constant menace to health in the Philippines. It is to be hoped that funds will be soon available to provide adequate supervision of the various factories supplying the market, so that only high- grade products of uniform purity may be eventually furnished the public. It has been found difficult, even in American and European countries, to fix standards for the bacteriological quality of bottled waters. Obst 117 sent out a questionnaire to a number of bacteriologists associated with sanitary and allied problems, in an effort to learn their attitude in regard to bacterial tolerance in bottled waters. A variety of answers was secured, varying from the advocation of absolute purity to no rigid standard of any kind. Many considered the presence of B. coli the best criterion. In France, Bon jean 118 has held that it is impossible in practice to bottle a water in a strictly aseptic manner ; that the number of germs increases rapidly in the bottle after filling and would not justify the statement "not contaminated;" and that, while B. coli might indicate contamination, this germ could gain ad- mission from atmospheric dust at the time of bottling. Obst 119 aptly remarks that : It is reasonable also to assume that when people pay from 2 cents to $30 per gallon for bottled water they expect to obtain a pure, or at least a safe water. * * * Before a person undertakes to operate a water business he should be prepared both in equipment and in operating knowledge to turn out a product free from contamination. This is demonstrated to be commercially possible, without burdensome restrictions, by the number 117 Obst, M. M., Bacteria in commercial bottled waters, Bull. U. S. Dept. Agr. (1916), No. 369. 118 Bon jean, Ed., The repression of frauds in the bottled water trade, Ann. Falsifications, 2, 169-76, through Chem. Abst. (1909), 3, 1654. 119 Op. cit., 2, 3, 6, 7. BOTTLED NATURAL AND CARBONATED WATERS 87 of firms already marketing water free from contamination. It is equally evident in the ability of other firms to produce clean water after the need of doing so has been emphasized by court action. * * * The results clearly show that bottled waters can be made to conform to the requirements of the United States Public Health Service for drinking water furnished upon trains; that is, that not more than one 10 cc sample out of five should show the presence of B. coli. Experience in the Philippines has likewise demonstrated that waters can be profitably bottled under aseptic conditions. The best proof of this is the fact that the two largest bottled-water plants in Manila, employing the methods devised by the Bureau of Science, and mentioned above, are turning out products that are practically sterile. When this desirable degree of purity is so easily attained, it seems only fair to constitute it the standard condition for this class of products. The Philippines are provided with an abundance of excellent spring and artesian waters comparable in quality with foreign waters of great reputation. Many of them could be bottled, carbonated, and marketed economically. There seems to be no good reasons per se why the local demand could not be practically entirely supplied by home manufacture, thus obviating the pay- ment of relatively high prices for imported waters of no greater intrinsic value. RADIOACTIVITY OF PHILIPPINE WATERS 120 In 1896 Becquerel 121 found that uranium salts gave off peculiar radiations, which had the power of affecting a photographic plate, even though the plate was wrapped in black paper. This discovery paved the way for a series of investigations, in the course of which some thirty new elements, the so-called radioactive elements, have been discovered. 122 These elements are characterized by the fact that they give off different types of radiations and that they themselves undergo decomposition dur- ing that process. The discovery of the element radium, the typical member of the radioactive series, was reported in 1898. 123 The high market value of radium, approximately 250,000 pesos per gram, is dependent on the scarcity and importance of the substance and on the extreme care and enormous labor involved in its extraction. Thus the largest American company devoted to the extraction of radium turned out only 14 grams of radium element in a period of about three years. To achieve this production, it was necessary to work about 5,000 tons of carnotite ore. The process of extraction is laborious and expensive and re- quires expert supervision. Incidentally the ore available in the United States is becoming poorer in quality, according to recent reports, so that it is becoming increasingly difficult to operate. It may be noted, in passing, that the United States Bureau of Mines hopes soon to be able greatly to reduce the cost of radium by the introduction of improved methods of extraction. In recent years the action of radioactive substances on vital processes has been much studied, with the result that the curative properties of radium are now generally admitted. 124 A quan- 120 The following is essentially an abstract of papers previously published and presents only a brief synopsis of the work of the Bureau of Science on the radioactivity of water. For complete details of this study, the original papers [Wright, J. R., and Heise, G. W., Phil. Journ. Sci., Sec. A (1917), 12, 145; Heise, G. W., ibid., Sec. A (1917), 12, 293, 309; and Heise, G. W., Rev. Fil. Med. y Farm. (1917), 8, 169-175] should be consulted. 121 Becquerel, H., Compt. rend. Acad. sci. (1896), 122, 420. 122 Soddy, F., The Chemistry of the Radio-elements. 2d ed. Longmans, Green & Co., London (1914). 123 Curie, P., Curie, Mme., and Bemont, G., Compt. rend. Acad. sci. (1898). 124 Turner, P., Radium, its Physics and Therapeutics. Wm. Wood & Co., New York (1911). 88 RADIOACTIVITY OF PHILIPPINE WATERS 89 tity of radium salt has been recently imported to the Philippines by certain doctors to be used in medical work. The therapeutic value of radioactive substances is believed to be due primarily to the so-called B- and Y-rays. Since ra- dium produces only B-rays of feeble intensity in addition to L-rays, whereas the B- and Y-rays are produced principally by its decomposition products, it is clear that the disintegration products of radium should have therapeutic value. 125 In addition to the study of the nature and properties of radio- activity and radioactive elements, radioactive investigations have come to include a large amount of work on the radioactivity of natural substances, such as rocks, soils, waters, and air. Not only is such work an important contribution to pure science, but it is also of practical value in its bearing on the geology and the development of natural resources of a country. Early in the history of radioactive investigations it was dis- covered that many of the natural waters from different parts of the world showed a high degree of activity. It is not sur- prising, therefore, that mineral waters that are radioactive should find a place in medicinal practice. 126 Investigation has shown tliat this activity was usually due to radium emanation (the first disintegration product of radium) and only in a few isolated cases to actual radium content. The radioactivity of waters can only be effective medicinally imme- 125 A unique suggestion and one that appears to be of practical im- portance was made by H. Schlundt in Trans. Am. Electrochem. Soc. (1915), 28, 424. To quote his own words: As the supply of radium increases and its therapeutic uses unfold, its efficient use and distribution will become a matter of growing importance. The distribution of the emanation instead of radium will greatly facilitate its more general use and practically obviate the risk of loss. Speaking then not from the viewpoint of the expert in radium therapy, but as one greatly interested in the conservation of our radium supply, I venture to suggest the establishment of centers for the distribution of radium eman- ation, that is, radium banks as dispensatories of radium emanation. For example, from a radium preparation containing a gram of the metal, five tubes of emanation each equivalent in the therapeutic value to nearly 200 milligrams of radium can be prepared initially, and then as the ema- nation accumulates a dose equivalent to 160 milligrams of radium can be separated daily thereafter for a good many years, as the half -life period of radium is nearly two thousand years. The loss of one of these tubes of emanation would be relatively insignificant in comparison with the loss of its radium equivalent. 126 Curie, Mme. P., Die Radioaktivitat, Akad. Verlagsgesellschaft M. B. H. Leipzig (1912), 2, 505-506. 90 PHILIPPINE WATER SUPPLIES diately after waters issue from the ground, since radium emana- tion is a gas that can be readily removed from water by shaking or aeration, and like other radioactive substances, it soon decom- poses and disappears. In a little less than four days the activity of a water, due to its emanation content, would be normally reduced to half its original value, and at the end of four weeks it would be too slight to be of any significance. These facts serve to explain the phenomenon that certain waters of very ordinary mineral content seemed to possess medicinal properties and, furthermore, that they seemed to lose their therapeutic value when not imbibed immediately after they were taken from the source. This behavior has been repeatedly noted with mineral waters even before their radioactivity was discovered; and it is to be expected, if the medicinal effect of a water is due to radioactivity. The usual process of bottling does not conserve the emana- tion content, and since radium is so seldom found in natural waters, it is extremely doubtful if any of the ordinary bottled waters from radioactive springs contain appreciable amounts of emanation. It is obvious that, in order to obtain any benefit from radioactive waters, they must be imbibed directly at their source. Statements regarding bottled waters based on the ac- tivity of these waters at the source are generally erroneous and misleading. In the Philippines there are many springs and deep wells high in radioactivity. In the course of an extensive study during 1916 and 1917 about one hundred twenty-five typical Philippine water supplies, including many of the best-known mineral springs, were tested for radioactivity. 127 Though no water was found whose radioactivity was abnormally high, there were many that were sufficiently radioactive to compare favorably with some of the best-known foreign mineral springs. The work further gave indication of a number of local deposits of radioactive material. An interesting feature of this study is the fact that there is no apparent connection between the radioactivity of any source and its reputation for medicinal virtues. Many of the waters high in activity are regarded with entire indifference by the people, whereas certain other waters, very highly regarded, showed no abnormal mineral content and were entirely free from activity. Some of the waters, however, such as those of Los Banos and Sibul Springs, with perhaps the greatest reputa- tions, have relatively high activities. 127 Wright, J. R., and Heise, G. W., Phil Journ. Sci., Sec. A (1917), 12, 145. Heise, G. W., ibid., Sec. A (1917), 12, 293. RADIOACTIVITY OF PHILIPPINE WATERS 91 The radioactivity of a number of typical Philippine waters is shown in Table IV, coupled, for purposes of comparison, with the results of measurements on typical foreign waters. In all cases measurements of activity were made directly at the source, by means of the well-known shaking method of Schmidt. 128 Plate XIX shows the type of apparatus used, as assembled for a field determination. The measurements in the table represent radium emanation content and are expressed in terms of the weight of metallic radium that would remain in radioactive equilibrium with that amount of emanation. Table IV. — Radioactivity of typical foreign and Philippine spring waters. Location. Source. Radium emanation. Grams X 10-12 per liter. Foreign. Austria, Bad Gastein __. Rudolfs spring a 142 a 24, 000 bl39 c 1, 100 d69-13, 800 el20-4, 730 2,106 00 1,284 1,293 negative 539 528 1,297 526 880 146 365 713 606 324 nil 242 trace Do Tavern tunnel springs England, Bath _ __ King's well __ England, Buxton.. _ .. _ Japan _ ._ Springs _ _ United States of America, Colorado do . Philippine. Batangas, Batangas. _ _._ __. Artesian well Do Crater Lake, Taal Volcano Bulacan, San Miguel de Mayumo, Sibul Springs _ Sibul Springs _ Do do Laguna, Calamba, Pan sol — _ Pansol Springs Laguna, Los Banos Hot spring near sanitarium Laguna, Majayjay, Olla Laguna, Majayjay, Malinao ._ . Olla Spring,. _ _ Sinabac Spring _ _ Laguna, Nagcarlan . San Diego Spring Laguna, Pagsanjan, Maulauin ___ _ _ _ _ Small artesian well Laguna, Pagsanjan, Pinagsanhan Laguna, Pakil .. ... Bumbungan Spring _ BafLo Spring Laguna, San Pablo _. Laguna, San Pablo, Maganpun . _ Bano Spring _ Laguna, San Pablo, Santa Maria Anos Spring. Laguna, Santa Cruz Artesian well, 459 __ Municipal spring La Union, San Fernando La Union, Tomas Artesian well _ __ a Mache, H., and Bamberger, M., Sitzb. kais. Akad. Wiss., Wien., Abt. Il-a (1914), 123, 325-403, through Chem. Abst. (1915), 9, 411. *> Masson, I., and Ramsay, W., Journ. Chem. Soc. (1912), 101, 1370-1376. c MacOwen, quoted by Rideal, S., and Rideal, E. K., Water Supplies. Appleton & Co., New York (1915), 11. <* Isitani, D„ et al. Proc. Tokyo Math. Physic. Soc. (1914). e Schlundt, H., Journ. Phys. Chem. (1914), IS, 662. f Tested for radium content only. Negative results with 250 cubic centimeters. 'Schmidt, H. W., Physik. Zeitschr. (1905), 6, 561-566. 92 PHILIPPINE WATER SUPPLIES Table IV. — Radioactivity of typical foreign and Philippine spring waters — Continued. Location. Source. Radium emanation. Grams X IO-12 per liter. Philippine. Mountain, Baguio 194 381 650 negative nil nil nil nil 1,325 720 1,058 trace 114 111 263 137 95 480 195 632 Mountain, Banave Bognakan Spring Do Kiakop Spring Mountain, Bontoc ._ Spring adjacent to municipal spring Mainit Spring Mountain, Bontoc, Mainit Mountain, Buguias _ . Mountain, Cervantes _____ Hot spring on river bank opposite town _ Hotsprings _ _ Mountain, Itogon Mountain, Kiangan Do Do Mountain, Klondike _ _ _ Mountain, Mancayan___ Spring on Balili trail Mountain, Sagada Mountain, Sagada, Tetepan Small spring at Salido. _ Do _ Nueva Vizcaya, Salinas _ Salinas Spring. _ _ __ __ Nueva Vizcaya, Santa Fe Santa Fe* Spring . Nueva Vizcaya, Solano Rizal, Parafiaque __ The highest radium emanation content encountered in the course of this study was noted in a flowing well in Batangas and was equivalent to 2100 X 10 -12 grams of radium. The highest activity in a spring water was equivalent to 1300 X 10" 12 grams. It is of interest that this maximum for a spring water was shown by three sources, namely, Sibul Springs, Bulacan; Sinabac Spring, Majayjay, Laguna; and Adukpung Spring in Kiangan, Ifugao, Mountain Province. In only one Philippine water was any actual radium content found, and in this case it was present in almost negligible quantity. There was no apparent relation to be drawn between the radioactivity of waters and either their chemical quality or the geology of the strata from which they were obtained. Although emanation taken into the system by the drinking of water may be different in effect from that applied in the usual medicinal treatment and may further be different in effect from that taken into the lungs by breathing, the following analysis may be of interest : Assuming that in ordinary respiration the average human RADIOACTIVITY OF PHILIPPINE WATERS 93 being at rest breathes 7 liters of air per minute or 10.1 cubic meters per day, the emanation thus brought into contact with the human system is 770 X 10" 12 curies, if the normal emana- tion content of the air 129 in the Philippines be taken as a basis for calculation. A person would, therefore, have to drink about three-fourths of a liter of Sibul Springs water or one and one-half liters of Los Baiios waters in order to take as much emanation into his system as he secures by ordinary daily respiration alone. Before leaving this subject, it may be of interest to point out that a recent study 130 of Sibul Springs has shown that the radioactivity of a ground water may be remarkably constant for long periods of time, in spite of comparatively great fluctua- tions in the quantity of water emitted. This indicates that radioactivity is a constant quality of water and that measure- ments of radioactivity have more than transitory value. 129 Wright, J. R., and Smith, 0. F., Phil. Journ. Scl, Sec. A (1914), 9, 51-77. 130 Heise, G. W., ibid., Sec. A (1917), 12, 309. QUALITY OF PHILIPPINE WATERS The work on Philippine water supplies has not progressed sufficiently to justify many generalizations on the quality of waters; and other factors make it appear extremely unlikely that many generalizations can be made, at least for some time to come. The Philippine Archipelago is composed of about a thousand islands, many of which, "continents in miniature," with comparatively small area, must be regarded as units in a study of waters. The heterogeneity of the geologic forma- tions in many parts causes waters from sources very near to each other often to show enormous variations in quality. This variation is found both in surface and in ground waters. Thus a recent examination of the waters of the surface wells within the limits of a small town gave the following results : Table V. — Chlorine content of surface wells. Chlorine content (parts per million) . Wells. Between and 20 10 Between 20 and 40 11 Between 40 and 60 8 Between 60 and 100 8 Between 100 and 150 2 Over 150 1 Of the forty wells examined, the minimum chloride content was 9.8, and the maximum was 192. The variation in the chloride content of adjacent wells was as great as that of widely separated ones. Similarly in the case of deep wells borings within a short distance of each other may encounter different strata, and the water from them may be markedly different. Two deep wells drilled on the Bureau of Science grounds within 50 meters of each other are different, both in regard to the water- bearing strata from which their supplies are derived and in the quality and quantity of water encountered. The water of well 1 contains 725 parts per million of total solids and 70 parts of chlorine, whereas that of well 2 has 500 parts per million of total solids and 12 parts of chlorine. Three wells in Iloilo (at the Iloilo Electric Company's works), located within about 15 meters of each other and drilled to about the same depth, show similar irregularities, two being approximately similar but dif- fering from the third. 94 QUALITY OF PHILIPPINE WATERS 95 However, so far as our experience goes, there is surprisingly little change in the quality of most waters, considered individ- ually. Leaving out of consideration such factors as the ad- mixture of tidal streams by sea water, changes in water-bearing strata due to earthquakes, the deterioration of well casings, or in general, the contamination of water sources, it may be said that the quality of any water is a definite, constant property of a source over extended periods of time. In the following discussion an attempt will be made to de- scribe briefly both the quality of the water from various sources and the various factors influencing their composition. Rain water. — In the Philippines the amount of rainfall varies both with the season and with the location. Many parts of the Islands have a rainfall more or less evenly distributed throughout the year ; in other parts most of the rain occurs within a period of three or four months, followed by a season of comparative drought. 131 As might be expected in an Archipelago like the Philippines, the composition of rain water is greatly influenced by the presence of the ocean. Salt is carried far inland by the winds and is brought down with the rain. A series of measurements made on the rain water collected on the roof of the Bureau of Science 132 for a period of over a year showed a minimum chloride content of 2.2 parts per million, a maximum, during stormy weather, of 19 parts per million, and an average of a little over 5 parts per million. The average chloride content is equivalent to about 8.5 milligrams of common salt per liter of rain water. On the basis of the average annual rainfall for the city of Manila, these figures indicate a precipitation equivalent to about 165 kilograms of salt per hectare of land. It is of interest, though perhaps of no significance, to note that this figure is of the same order as that (120 kilograms) given by Prudhomme 133 as the salt requirement per hectare of coconut-palm plantations. Rivers. — It is hardly necessary to point out that rivers vary greatly in flow under the influence of rain. Many streams that are almost dry in periods of drought become raging torrents during the rainy season. Under these circumstances, changes in quality are inevitable. However, in rivers that have consider- 131 For the distribution of rainfall in the Philippines according to locality and season, cf. Cox, A. J., Phil Journ. Sri., Sec. A (1911), 6, 287 ff. 132 Most of these determinations were made by J. Gonzales Nunez, chemist, Bureau of Science. 133 Quoted by Beccari, 0., Phil. Journ. Sci, Sec. C (1917), 12, 41. 96 PHILIPPINE WATER SUPPLIES able flow throughout the year such changes may be surprisingly slight. This is well illustrated by a series of measurements made on Mariquina River, the source of the Manila water supply. In 1903. when the intake was at Santolan, the tap water was examined over a period of months, including the rainy season, at very frequent intervals. The following maximum variations were noted: Total solids, 153 to 220; chlorides, 2.1 to 4.4; and oxygen consumed, 0.65 to 2.20. 134 Since the intake has been moved to Montalban, 10 or 12 kilometers upstream, a point above which there are no human habitations or cultivated lands, the fluctuations have been even less. Total solids have varied from 150 to about 200, usually being in the neighborhood of 160. A recent series of determinations, 135 during a period of frequent heavy rains, showed chloride contents varying from 3.5 to 4.1 and "oxygen consumed'' varying from 0.67 to 1.4. Making due allowances for the effect of storage, changes of this magnitude in a water subject to tremendous fluctuations in quantity and even in appearance appear to be comparatively insignificant. It may be of interest to note, in this connection, that the temperature variation of Mariquina River water in the service reservoir was only 4° C. for an entire year. Of far greater effect on quality is the influence of the tides. Many Philippine rivers show tidal ebbs and flows for many kilometers inland. Owing to the difference in specific gravity between fresh and ocean water, the latter apparently can move far inland in a river at high tide before it mixes with and contaminates the water of the stream. Thus samples taken from Pasig River about 1 kilometer from the sea showed the following analyses : Table VI. — Analyses of water from Pasig River. Surface water. Water taken near the bottom. At high tide. At low tide. At high tide. At low tide. 90 75 8,000 69 100 3,800 380 Turbidity 60 70 760 36 17 310 40 70 70 780 18 2.8 124 5.4 95 110 31,000 Alkalinity (as CaC03> ._ Total solids Silica (Si02) Calcium (Ca) 320 14, 600 1,500 Chlorides (CI) ___ Sulphates (SO4) 1 Bliss, C. H., Pub. P. I. Bur. Govt. Lab. (1905), No. 20, 10. 'Heise, G. W., Phil Journ. Scl, Sec. A (1916), 11, 4. QUALITY OF PHILIPPINE WATERS 97 It may be mentioned that a tidal effect on the quality of Pasig River water has been noted for a distance of several kilometers upstream. The stream waters analyzed, with the exception of tidal rivers and water courses known to be contaminated, range from 45 to about 550 parts per million in total solids and from 2 to 150 in chlorine. Surface wells. — Like rivers, surface wells show great changes in quantity of water with the season. Many that are capable of yielding much water in times of rain are absolutely dry dur- ing dry weather. The frequent influx of large quantities of surface run-off, after a heavy rain, may change materially the quality of water in a surface well. Quality of surface wells has not been much studied, except with regard to their potability. They are similar in composition to average river waters. Their waters show no marked peculiarities, and they have not been sufficiently studied to justify generalizations. The surface wells listed, with the exception of a few located so near the ocean that they were obviously contaminated by sea water, range in total solids content from 164 to 1,230 parts per million and in chlorine content from 5.5 to 436 (average, about 150). Springs. — As might be expected, springs generally show great fluctuations in quantity under the influence of various factors. Most of them show a decidedly greater flow during the rainy season, even though they are protected from surface seepage. It is interesting to note that with deep-seated springs there is decided "lag," that is to say, a marked increase in flow does not occur until after a month or more of rainy weather, and furthermore, the increased flow does not materially diminish until far into the dry season. Tidal variations are also of frequent occurrence, many springs having a much greater flow at the flood than at the ebb. This is to be expected, since the general effect of tides may frequently be an increase of the hydrostatic pressure of subsoil waters. In some cases the flow may entirely cease at low tide. A peculiar case in point has been already discussed. 136 A series of springs, some fresh, some brackish, are found on the seashore at Punta Oslob, Cebu, both above and below high- water mark. The fresh- water springs have no flow at low tide and are covered at high tide, but water can be obtained from them as it emerges into the supernatant sea water. As the only springs available at low tide are brackish, and as both fresh and salt springs are close together and are easily mistaken for one another, the 13fl Heise, G. W., Phil. Journ. Scl, Sec. A (1916), 11, 125. 152918 7 98 PHILIPPINE WATER SUPPLIES erroneous belief has developed that the same springs are fresh at high tide and salt at low tide. Spring waters vary widely in quality. The total solids con- tent ranges from 24 to over 40,000 parts per million, and chlorides range from 0.7 to over 20,000. Many of the springs are so salty that ordinary salt can be recovered very profitably from them. No such variations occur in quality as have been noted in quantity. Even the temperature appears to be surprisingly constant for long periods of time. Occasionally springs are reported as alternately hot and cold, but this observation, as was pointed out in the discussion of mineral waters, is generally un- founded. In regard to chemical quality, our records indicate that, except for seismic disturbances or other unusual factors, no material changes in quality occur, in spite of marked fluctua- tions in quantity. This constancy in composition of spring waters may be inferred from a comparison of two analyses of Sibul Springs, one published in 1890, 137 the other made in 1915. Table VII. — Analyses of Sibul Springs water. Analysis by — Centeno in 1890.a Bureau of Science in 1915> Total solids -_ _ __ _ 532 30 477 13 42 154 17 550 15 460 nil 32 150 14 Silica Bicarbonates (HCO3) Sulphates __ _ Chlorides Calcium Magnesium * [Recalculated as parts per million and to same terms as those used in standard practice. b Analysis by F. Pefia, chemist, Bureau of Science. Considering the length of time that has elapsed between the two analyses, the differences in analytical methods employed, and the fact that for a period of years Sibul Springs was neg- lected, better agreement could be hardly expected. Deep wells. — The fluctuations described for springs are also encountered in deep wells. Water is encountered at many dif- ferent depths, depending on the locality in which well-drilling operations are carried on. 138 337 Centeno, J., et al., Memoria Descriptiva de los Manantiales, etc., de la Isla de Luzon. Madrid (1890), 39. 138 For a discussion of the location of artesian wells, see the article by Pratt, reprinted as the first appendix of this work. QUALITY OF PHILIPPINE WATERS 99 A large number of the wells drilled in the Islands have a natural flow, some of them supplying enormous quantities of water, notably, the famous gusher at Bayambang, Pangasinan, which supplies 1,000,000 gallons [3,800,000 liters] daily. The water from the latter is distributed through j. two main supply pipe lines, one leading to the military post at Camp ? Gregg, and the other to the town of Bayambang. In many of the provinces Mt is necessary to drill wells ranging from 600 to 800 feet [200 to 250 \ meters] in depth in order to obtain good water. In the town of Wright, [ Samar, good water was not encountered until a depth of 1,025 feet was J reached, when flowing water of excellent quality was tapped. This well ; is the deepest in the Islands which supplies good water. A number of ;, wells have been drilled to greater depths, however, but in every case except I the one mentioned above salt water was encountered below 1,000 feet. The \ deepest well ever drilled in the Islands was located on the trade school I grounds at Iloilo, and was sunk to a depth of 2,285 feet without encountering i fresh water. An interesting feature in connection with some of the wells | is the effect the ocean tide has upon the fresh-water flow, one remarkable | instance being the well at Bauan, Batangas, drilled to a depth of 298 \ feet, which flows 250 gallons per minute 18 inches above the ground surface ; at high tide, and 50 gallons per minute at low tide at the same elevation; ; in other words, the flow at high tide indicates an increase of 400 per cent ( over the flow at low tide, notwithstanding the fact that analyses of water ; samples collected at both high and low tide give identical results and show s the water to be potable and free from salt-water contamination. 139 In many borings, especially near the coast, brackish water \ is encountered during the first 30 to 70 meters, even though fresh water may be found at lower levels. In some rather excep- tional cases, in which salt water was encountered at great depths, continued drilling developed a supply of fresh water. At < Wright, Samar, salt water was found at 180 to 215 meters ; this ; was cased off, and drilling was continued. At 312 meters fresh water was found under sufficient pressure to cause a flow, which, .although slight even at ground level, did not cease entirely at 12 meters above the earth's surface. As a general rule, however, . it may be stated that fresh water is seldom found underlying salt water, and in the few cases in which such fresh water has been utilized, the well has frequently "gone bad" after more or less continued use. Of interest in this connection is a phenomenon noted occasion- ally in the Philippines, especially on small islands. It has hap- pened that water of fair quality has been encountered in deep j wells; when the amount of water pumped was large, the waters | have become too brackish for use, due, no doubt, to infiltration of Jsea water. On allowing the pumps to rest, or on decreasing r the rate of pumping, fresh water has been again obtained. ; * 9 Vickers, J. W., Quart. Bull. P. /. Bur. Pub. Works (1914), 2, No. 4, 27. I Many wells, for instance, at Iloilo and at Argao, Cebu, flow only at high tide. 100 PHILIPPINE WATER SUPPLIES The minimum temperature of deep wells drilled in the low- lands is about 28° C, but the temperature range is great. The deep-well waters range in total solids content from about 120 (well 129, Nueva Caceres, Ambos Camarines) to 8,200 parts per million (Janiuay, Iloilo) and in chlorine content from 1.5 (San Jacinto and Binalonan, Pangasinan) to 4,471 (Janiuay, Iloilo). The highest free ammonia content recorded is that of a well at Los Banos, Laguna, 70 meters deep, which showed 32.7 parts per million. Except under very exceptional circumstances, such as those previously discussed, the chemical quality of a deep-well water remains practically unchanged for long periods of time. This observation is in harmony with the experience in other coun- tries. 140 There is generally an appreciable variation in quality immediately after a well is drilled, but this appears to be due to a leaching-out of soluble ingredients from the neighboring soil and soon ceases. As was pointed out under the heading of the interpretation of analytical results, these variations often greatly impair the value of the available laboratory data and emphasize the necessity for allowing a well to reach equilibrium before its water is sent to the laboratory for analysis. Chemical qual- ity, though generally not as subject to change as biological character, also undergoes marked; alterations, so that inter- pretation of the analysis of old- water samples is sometimes very difficult. Free and albuminoid ammonia and, in general, nitro- gen in its various forms will change greatly. The amount of free carbon dioxide originally present in a water diminishes comparatively rapidly on standing, particularly if the initial con- centration is high. Many natural waters that are clear when they emerge from a well or spring quickly become turbid, owing to the escape of carbon dioxide and to the resulting precipitation of salts of metals (calcium, magnesium, and iron) previously held in solution in the form of bicarbonates. While the rela- tions existing between free carbon dioxide, bicarbonates, and normal carbonates are not exactly understood, there is no doubt that the escape of carbon dioxide affects the equilibrium of the system. It has been observed in this laboratory that samples of water kept for a considerable period of time rapidly lost their 140 Hintz, E., and Kaiser, E., Zeitschr. /. prakt GeoL (1915), 23, 122-126, through Chem. Abst. (1916), 10, 1741, state that the composition of deep- seated waters from wells is remarkably constant. QUALITY OF PHILIPPINE WATERS 101 "acidity" due to free carbon dioxide. As long as an appreciable excess of free carbon dioxide was present, the bicarbonate value remained constant, but as soon as the free carbon dioxide reached a limiting concentration — in this case, zero — normal carbonates began to form at the expense of the bicarbonates, which suffered a corresponding reduction of concentration. Other changes, such as the precipitation of suspended matter and variations in color, odor, and taste, may also occur. Such variations often lead to erroneous interpretations of water analyses, a fact which will be discussed more at length. METHODS OF WATER EXAMINATION The usual difficulties encountered in laboratories devoted to water-supply problems are, on the whole, greatly increased in the Philippines. Chief among these has been the difficulty in getting representative samples in proper condition for analysis to the Bureau of Science, in Manila, which is the central labor- atory for the Archipelago and is the only laboratory properly equipped to do water analyses. Many samples have to be trans- ported hundreds of kilometers before they can be analyzed. Since much of the transportation is by water, samples are often three or four weeks old when they reach the Bureau of Science. With the exception of those taken in Manila and at points easily accessible to it by railroad, samples rarely reach the Bureau within the time limits prescribed by the American Public Health Association. 141 The uniform, high temperature in the Philip- pines accelerates the changes that normally occur in bottled waters and greatly increases the importance of the time factor. It is not surprising, therefore, that many samples, when they do* arrive at the laboratory, are not representative. Another handicap to constructive work in the Philippines has been the difficulty in securing properly taken samples. For many years the Bureau of Science has sent out properly packed, sterile, glass-stoppered bottles, suitable for water and has issued instructions for the collection of samples. The directions of the Bureau of Science for taking water samples, as prepared for general distribution, are shown in the appendix. However, the primitive conditions in many isolated districts have resulted in improperly taken samples, usually in unsuitable and frequently in unclean containers, accompanied by little or no information that would assist in the proper interpretation of the results obtained from an analysis or would make such analysis of permanent value. In addition, there is a peculiar difficulty, for which general conditions, rather than individuals, are to blame. As has been mentioned, judgment by the Bureau of Science must be made on all artesian wells drilled by the Insular Government. The 141 Standard Methods for the Examination of Water and Sewage (1915), 1-2. 102 METHODS OF WATER EXAMINATION 103 great cost of well-drilling apparatus and the constant demand for new wells make it impracticable to keep machinery and crew idle for any length of time. Accordingly, when a well-driller strikes water that he believes to be potable, he takes a sample and forwards it to the Bureau of Science for analysis. It frequently happens that the first water from a well is not a representative sample of that well under working conditions, so that the analysis is of doubtful value as a matter of permanent record. It has been our experience that a new well, or one that has been in disuse for any protracted period of time, should be given a thorough pumping test before a sample of the water is taken for analysis. The general methods employed in the examination of water are three, namely, a sanitary survey, a microscopic and biologi- cal examination, and a chemical analysis. The sanitary survey consists of a study of the surroundings of a source and gives information concerning the possible sources of contamination; the chemical analysis, as the name implies, is a determination of the composition of the foreign ingredients suspended or dis- solved in water; the biological examination is a differentiation in kind and frequently in quantity of the smaller floating or- ganisms, both animal and vegetable (technically known as plank- ton), usually found in natural waters. These general methods, together with a discussion of the interpretation of the results of a water examination, will be taken up in the order named. SANITARY SURVEY The sanitary survey legitimately includes all external factors that might have influenced the quality of the water when the sample was taken and might affect the quality in the future. These factors, of course, vary to some extent, in every case. In addition to general information on the quantity and apparent quality of the water, possible sources of contamination, etc., the following data should be noted : Wells: A. Artesian. Depth of well; depth of casing; head; capacity; va- riations; distance from nearest houses. If pumping well, kind and condition of pumps; nature of soil and subsoil; drainage of waste water, etc. B. Surface. Depth of well; kind and depth of casing; height of curbing; nature of covering; nature of receptacles used for drawing water; distance from habitations; kind of pump, if any; nature of soil and subsoil; elevation with respect to sur- roundings; drainage of waste water; density of population, possible sources of contamination, etc. 104 PHILIPPINE WATER SUPPLIES Springs. Water-bearing stratum; apparent direction of flow; elevation; liability to contamination with surface water; distance from houses; density of population; nature of soil; variations, etc. Rivers. Nearness and relative number of houses along course; nature and slope of valley; variations, etc. It is also important to note the weather conditions at the time the sample is taken. This applies particularly during periods of heavy rains or long droughts. In all cases, the location of the source should be stated as fully and accurately as possible, to prevent the slightest pos- sibility of confusion with any other point in the vicinity. Local opinion is obviously of great importance. Prejudice and preconceived ideas have in numerous cases led to the unjust condemnation of good water and the unwarranted approval of bad. In connection with the field examination of potable waters, the general hygienic and sanitary conditions in the neighbor- hood of the source should, of course, be noted. In addition, information should be obtained as to the prevalent diseases and to the occurrence of epidemics. BIOLOGICAL EXAMINATION Both laboratory and field methods are used in making biologi- cal examinations of water. The laboratory tests are made in the Bureau of Science by the biological laboratory, and the field work is done by chemists of the division of general, in- organic, and physical chemistry. LABORATORY METHODS The usual laboratory procedure includes 24- and 48-hour colony counts, a presumptive test for B. coli or related organisms, and an examination for the commoner protozoa. The routine meth- ods of bacteriological examination employed in the biological laboratory of the Bureau of Science are as follows : 1. Agar plates are poured with 1 cubic centimeter, 0.1 cubic centimeter, and 0.05 cubic centimeter of water, counts being made at the end of twenty-four and forty-eight hours. The reported number of colonies is the mean of the two serial counts (a total of six individual counts). 2. Five fermentation tubes containing not less than 30 cubic centimeters of lactose peptone broth or bile are inoculated with 10 cubic centimeters of the water under examination, incubated for forty-eight hours at 37°C, and then observed for gas formation (presumptive test for B. coli group). 3. From each tube showing gas, litmus lactose or Endo plates are made and observed for red colonies at the end of twenty-four and forty- eight hours' incubation (isolation of organism of colon group). METHODS OF WATER EXAMINATION 105 Special methods are, of course, employed when necessary for the isolation and differentiation of uncommon organisms. FIELD METHODS The bacteriological examination in the field consists of two parts. One of these is a colony count, made from two plate cultures. The other is a presumptive test for the presence of organisms of the B. coli group, made with one or more culture tubes. The culture medium used in both cases is litmus lactose agar (1.5 to 2.0 per cent agar, 1 per cent lactose). The reaction of this medium is almost neutral, there being present barely enough alkalinity to give a slight blue color. It is put up in test tubes, in 10 cubic centimeter portions, and is thoroughly sterilized. The Petri dishes used for the plate cultures are packed into individual envelopes and then sterilized. The envelopes, made of heavy Manila paper, are about the same width as the dishes and about twice as long as they are wide. Packages of six plates, well wrapped with paper, may be transported with little danger of breakage and will remain sterile indefinitely. The pipettes used hold 1 cubic centimeter and are about 20 centimeters long. If these are not available, they may be readily made from glass tubing. The pipettes in lots of six are well wrapped in cheesecloth, having several folds of cloth between one pipette and the next. The ends of the package are tied together, and the package is inserted in a tin can just large enough for the purpose. The closed tin can containing the pipettes is then sterilized. While warm, the can is sealed with adhesive tape. When cool, the tape is well covered with paraffin. Pipettes so packed will remain sterile almost indefinitely. For several kinds of work sterile bottles may be employed. Instead of the ordinary cotton plugs, which are often either pushed in or which come out during transportation, we use a cotton-covered cork; This arrangement has been found to be very satisfactory. Ordinarily two plate cultures and one tube culture are made of every sample. Three tubes of media are thus required. The tubes are melted by heating in water over an alcohol lamp, then cooled to 45°. Plating is done at a temperature of 40 to 43° C. For a water, such as that from a spring or artesian well believed to be com- paratively pure, 0.5 and 1.0 cubic centimeter cultures are made. For a water suspected of contamination, plates may be made of 0.2, 0.1, or 0.05 cubic centimeter, depending on the apparent 106 PHILIPPINE WATER SUPPLIES degree of contamination. The water is introduced into the Petri dish, the liquefied agar added, and the plate manipulated to insure thorough mixing. After thorough cooling, the plates are returned to their envelopes and carried in an inverted position to prevent spreading of the colonies by water of condensation. The tube culture for the presumptive test is made by intro- ducing the desired amount of water into the tube of liquefied agar and mixing thoroughly by agitation. Usually 1 cubic centi- meter is taken for this test, though more or less may be employed. The upper limit will be determined by the fact that 1 per cent agar is the weakest that will solidify on cooling to the tem- peratures ordinarily encountered (25° to 30° C). Incubation is at the ordinary temperature. No special ap- paratus is, therefore, required. Colony counts are made both at the end of twenty-four and forty-eight hours, using a lens magnifying at least five diameters. The average of the two counts is the recorded value. When the number of colonies is high, the plate is marked into sectors of convenient size, and the total number of colonies is estimated, or else the number on representative areas of 1 square centimeter is determined (a small card with openings of appro- priate size and shape has been found very convenient for field work) , and the necessary calculation for the total area is made. The presence of red colonies is noted. The presence of organisms of the colon group is indicated by the formation of gas in the tube cultures and by the formation of acid, as shown by the change of litmus from blue to red. Bacteriological methods are, in general, notably inexact, al- though the data thus secured are of the greatest value. Further- more the results obtained are subject to a wide range of inter- pretation. For these reasons a discussion of the probable error involved in the field methods of bacteriological examination is scarcely necessary. The interpretation of the data thus secured, however, will be dealt with in the following chapter. CHEMICAL ANALYSIS Both laboratory and field examinations of water are made by the Bureau of Science. As the methods used differ consider- ably in the two instances, they will be discussed separately. LABORATORY METHODS The methods of chemical analysis employed in the Bureau of Science laboratory are, in general, the standard methods of the American Public Health Association. A few changes and omis- METHODS OF WATER EXAMINATION 107 sions have been made. The most important of these is with regard to the determination of nitrogen in the form of nitrates, nitrites, and free and albuminoid ammonia. None of these determinations is now made in a routine mineral analysis and only in special cases in a sanitary analysis of a water. The status of nitrogen determination has entirely changed during the last few years. As Barnard 142 has pointed out, streams loaded with sewage are often surprisingly low in nitrates. Nitrates show greater variation due to high or low water than to sewage or oxidation of nitrogenous material. Free and albuminoid ammonia generally depend more on low and high water, temperature, and normal vegetable growth than upon pollution. Furthermore, since the nitrogen content of deep wells is almost sure to be misleading, since single determinations are of doubtful value, and since the nitrogen in its various forms can be determined accurately only on fresh samples of water, the nitrates, nitrites, and free and albuminoid ammonia deter- minations may be omitted for all but exceptional cases. Similarly the determination of "oxygen-consuming power" is very seldom made when only single analyses are required. It has been repeatedly shown that this determination does not measure accurately the amount of organic matter in a water, that the values obtained vary widely with the method used, and that numerous errors may be introduced by the irregular behavior of many dissolved substances. 143 This determination is valuable chiefly as a sensitive indicator of fluctuations in a water supply kept under constant control. When a single analy- sis only is made, the results obtained for the oxygen-consuming power are of questionable value. In this laboratory the determination of oxygen consumption by digestion at room temperature with alkaline permanganate solution 144 is preferred to the standard procedure 145 of the American Public Health Association, namely, 30-minute di- gestion at boiling temperature with ^cid permanganate solu- 142 Eng. Record (1913), 68, 291. 143 For a discussion of the factors influencing the determination of oxygen-consuming power, cf. Standard Methods for the Examination of Water and Sewage (1915), 26-30; also Heise, G. W., and Aguilar, R. H., The oxygen-consuming power of natural waters, PhiL Journ. Sci., Sec. A (1915), 11, 37-47. 144 Method of Schultze, Dingler's polytech. Journ. (1868), 188, 197, as modified by Winkler, L. W., Zeitschr. f. analyt. Chem. (1914), 53, 561. 145 Standard Methods for the Examination of Water and Sewage (1915), 29. 108 PHILIPPINE WATER SUPPLIES tion. The directions for the method of procedure followed in this laboratory are as follows: Put 100 cubic centimeter samples of water into scrupulously clean bottles, add 10 cubic centimeters of (0.01 N) perman- ganate solution (containing 20 grams of sodium hydroxide per liter), and allow the samples to digest for twenty-four hours at room temperature. Acidify with 10 cubic centimeters of dilute sulphuric acid (10 per cent), allow to stand for one or two minutes, and add 2 cubic centimeters of 10 per cent potas- sium iodide solution. Titrate the liberated iodine as quickly as possible with 0.02 N sodium thiosulphate solution. The solution must be acidified before the potassium iodide is added, else nitrites will not be oxidized and concordant titrations will not be obtained. This method greatly reduces, but does not eliminate, the error due to the presence of chloride, so that, when the chloride content is large (approximately 150 parts per million or over) it is best to shake a water sample with silver oxide, to remove chlorides 146 before proceding with an analysis. Total hardness has been usually determined by calculation from the gravimetric determinations of calcium and magnesium and reported in terms of calcium carbonate. Recently the Blacher method 147 for the determination of total hardness by titration with a solution of potassium palmitate has been studied, and this method, in slightly modified form, is now included among the standard methods employed in this laboratory. 148 The only other deviation from the standard methods worthy of mention has been the substitution of dimethylaminoazo- benzene (butter yellow) in place of lacmoid, methyl orange, and erythrosin in the determination of alkalinity. Recent work indicates that the first-named indicator gives the most reliable results, the end point being almost independent of carbon dioxide. 149 The following determinations are made in a routine water analysis as carried out in this laboratory : Color, turbidity, alka- linity, acidity, total solids, silica, iron and aluminium oxides, iron, aluminium, calcium, magnesium, chlorides, normal carbonates, bicarbonates, sulphates, and total hardness. 146 Sachs, J. H., Journ. Ind. Eng. Chem. (1916), 8, 406. 147 Blacher, G., Griinberg. P., and Kissa, M., Chem. Zeitschr. (1913), 37, 568. 148 Behrman, A. S., Note on the Blacher method for the determination of hardness in water, Phil. Journ. Sci., Sec. A (1916), 11, 291. 149 Norton, J. F., and Knowles, H., Journ. Am. Chem. Soc. (1916), 38, 877. METHODS OF WATER EXAMINATION 109 Results are reported in terms of parts per million and in numerical values of two significant figures (except in the case of 5 in the place of the third significant figure, which is so reported) . This method of reporting in terms of two significant laboratory No... BUREAU OF SCIENCE WATER CHEMICAL ANALYSIS [Results expressed as parts per million.] Physical characteristics.. Chlorides (CI) • Color Normal carbonates (as _ CCh) Odor Bicarbonates (as CO3) Turbidity (us SiOt) Sulphates (SO t ) - Alkalinity (as CaCOs) Nitrates (N(h) - Acidity (as C(h) Nitrites (NOz) Total solids Three ammonia Fixed solids Albuminoid ammonia Loss on ignition Oxygen consumed Appearance on ignition Total hardness (as CaCOi) Silica (SiOz) Temporary hardness. Iron & aluminium oxides (FezOz+AlzOz) Permanent hardness Iron (Fe) Estimated encrustants Aluminium (Al) Classi&cation for boiler use Calcium (Ca) .... Magnesium (Mg) Remarks Sodium (Na) Potassium (K) BIOLOGICAL EXAMINATION Date ... Colonies per cc. 24 hrs / 48 hrs Presumptive test ProtozoA — Attempt to isolate B. coli . B. SC. POKM No. 41. BUREAU OF SCIENCE MANILA, P. I, WATER laboratory No Day and bonr of co Uection , location _ (Province.) (Town.) (Barrio.) Source Type When installed Capacity per minute: Flows Report on sanitary survey.. Quality of water. Effect of pumping . Temperature Owner. Depth of well Depth of easing . Diameter Mead above (+) or below (— ) surface.. Variations ..— Water-bearing stratum Sample collected hy I,ocal opinion Nature of examination _ Analysis requested by.. Fig. 1. The two sides of one card. The top of the obverse is the bottom of the reverse. figures is now generally accepted 150 as being consistent with the errors involved in determination. Any unusual physical characteristics such as taste and odor, not measurable quanti- tatively, are recorded. 150 Standard Methods for the Examination of Water and Sewage (1915), 14. HO PHILIPPINE WATER SUPPLIES FIELD ASSAY Recent developments in water analysis have emphasized the importance of making examinations at the source, whenever possible. The work of the Bureau of Science has shown, as indicated in a previous chapter, the need of field investigations and the peculiar applicability of field methods to Philippine conditions. Accordingly field work has been made one of the most important features of our study of water supplies. Owing to the comparative isolation of the Philippines, the great, distance from scientific or manufacturing centers, and the consequent loss of time when apparatus and supplies are procured from abroad, we have found it necessary, to a large extent, to build our own apparatus, to prepare our own reagents for field use, and to devise and adapt methods suitable to our needs. The field work of the Bureau of Science has been now carried on for three years. Because of the importance of field methods at the present time and because workers in the Philippines will continue to be dependent, in a great measure, on their own resources, we thought it advisable to describe our field methods and apparatus in detail. Our methods are based upon those described by Leighton. 151 However, several changes have been made. A "tabloid" deter- mination of acidity and a rough estimate of the total amount of solid matter have been added ; the soap method for total hardness has been replaced by a new and more accurate procedure; and several minor modifications in the details of manipulation of some of the old methods have been introduced. Other minor changes have been made in apparatus, as will become evident in the detailed description to follow. In connection with the study of potable waters, a field bacterio- logical examination is also made. This consists of 24- and 48-hour colony counts at ordinary temperature and a pre- sumptive test for B. coli or related organisms that would indicate faecal contamination. The uniform tropical temperature (25 to 30° C.) makes this bacteriological work a very simple, while a very valuable, feature of the examination. The outfit has been gradually reduced in size, although the number of determinations made has been increased, so that now enough apparatus and materials for a month's chemical work can be carried in an army telescope. This makes a package weighing less than 22 kilograms, which fits well on one side 151 Leighton, M. 0., Field assay of water, £7. S. Geol. Surv., Water Supply Paper (1905), No. 151. I; METHODS OF WATER EXAMINATION 111 of a packsaddle or on the back of a cargador. The outfit required for bacteriological work is not large, as may be seen by Plate XIX, in which the complete equipment is shown. A comprehensive sanitary survey, embracing, in so far as possible, all those features that may influence the quality of the water under examination is, of course, included in field work. The details of the methods employed in regular field examina- tion are as follows. Quantitative: Color; turbidity (as Si0 2 ) ; alkalinity (as CaC0 3 ) ; acidity (as C0 2 ) ; iron (Fe) ; chlorides (CI) ; normal carbonates (as Na 2 C0 3 ) ; bicarbonates (as CaC0 3 or HC0 3 ) by calculation; sulphates (as S0 3 ) ; total hardness (as CaC0 3 ) ; estimated encrustants, by calculation. Qualitative: Odor ; total solids ; appearance on ignition ; calcium ; classification for boiler use. Color is determined with the United States Geological Survey color outfit described by Leighton, 152 consisting of a standard length aluminium tube that is filled with the water under examination. The color of this column of water, viewed longi- tudinally, is matched by disks of colored glass that have been rated in parts per million to correspond to the platinum-cobalt standard. Iron is conveniently determined with the same outfit as used for color as described by Leighton. The only extra equipment required is a series of prepared colored disks corresponding to those by treating standard solution of iron. These disks have not been available. In lieu thereof, red and yellow glasses from the Lovibond tintometer have been employed in connection with two matched Nessler tubes in galvanized iron outer tubes. When 100 cubic centimeters of water were used in a determina- tion, it was found that a summation of 6.0 on the Lovibond scale was very nearly equal to 1 part per million of iron (as Pe). The following is the procedure employed : To 100 cubic centimeters of the water under examination in a Nessler tube add 4 cubic centimeters of concentrated nitric acid. Mix thoroughly by pouring six or seven times from one tube to another and allow to stand at least five minutes to insure complete oxidation. Then add 6 cubic centimeters of a 2 per £ent solution of potassium sulphocyanide, mix thoroughly by several pourings, and allow to stand ten minutes for the color ±o develop. Exactly at the end of ten minutes make the color ^comparison with the Lovibond glasses under the empty Nessler tube, using a piece of white paper to reflect the light. Hold the tubes with one hand sufficiently high to reflect all the light * 162 Loc. cit. 112 PHILIPPINE WATER SUPPLIES possible. Interchange the tubes several times to avoid inequaU ities of light. The tubes should be held in such a position that both may be seen with one eye. Obviously the final reading may be made either by using all the glasses under the empty Nessler tube or with some under the water as well. In this way intermediate values sometimes not otherwise obtainable may be found. In all cases the nitric acid used should be tested be- forehand for iron, this being a not infrequent impurity. Turbidity is determined with an electric turbidimeter, de- scribed in Leighton's paper. By means of an electric flash light, a cross of light is provided at the bottom of a long graduate tube! The well-shaken, turbid water is poured in until the sharp image disappears and the hazy cross of light just disappears. This is taken as the end point in the lower part of the tube. In the upper part of the tube (that is, for slightly turbid liquids) there is no hazy cross of light, and the end point is taken as the depth at which the sharp image of the cross disappears, giving place to a slightly blurred one, that is, it seems out of focus. Table VIII is provided for converting the turbidimeter depths to parts per million silica. Table VIII. — For converting readings in depths by the turbidimeter into parts per million of sulphate. Read- ing. Parts per million S03. Read- ing. Parts per million SOs. Read- ing. Parts per million SOs. Read- ing. Parts per million SOs. Read- ing. Parts per million SOs. Read- ing. Parts per million SOs. cm. cm. cm. cm. cm. cm. 1.0 522 3.2 173 5.4 104 7.6 75 10.8 53 19.0 30 1.1 478 3.3 168 5.5 103 7.7 74 11.0 52 20.0 29 1.2 442 3.4 164 5.6 101 7.8 73 11.2 51 21.0 28 1.3 410 3.5 159 5.7 99 7.9 72 11.4 50 22.0 27 1.4 383 3.6 155 5.8 97 8.0 71 11.6 49 22.5 26 1.5 359 3.7 151 5.9 96 8.1 70 11.8 48 23.0 25 1.6 338 3.8 147 6.0 94 8.2 69 12.0 47 24.0 24 1.7 319 3.9 144 6.1 93 8.3 68 12.4 46 25.0 23 1.8. 302 4.0 140 6.2 91 8.5 67 12.6 45 26.5 22 1.9 287 4.1 137 6.3 90 8.6 66 12.8 44 28.0 21 2.0 273 4.2 133 6.4 88 8.7 65 13.0 43 29.0 20 2.1 261 4.3 131 6.5 87 8.8 64 13.5 42 31.0 19 2.2 250 4.4 128 6.6 86 9.0 63 14.0 41 33.0 18 2.3 239 4.5 125 6.7 84 9.1 62 14.5 39 35.0 17 2.4 230 4.6 122 6.8 83 9.3 61 15.0 38 37.5 16 2.5 221 4.7 119 6.9 82 9.5 60 15.5 37 40.0 15 2.6 213 4.8 117 7.0 81 9.7 59 16.0 36 43.0 14 2.7 205 4.9 115 7.1 80 9.8 58 16.5 35 46.5 13 2.8 198 5.0 113 7.2 79 10.0 57 17.0 34 50.0 12 2.9 191 5.1 110 7.3 78 10.2 56 17.5 33 55.5 11 3.0 185 5.2 108 7.4 77 10.4 55 18.0 32 62.0 10 3.1 179 5.3 106 7.5 76 10.6 54 18.5 31 68.0 9 METHODS OF WATER EXAMINATION 113 Turbidity may be also determined with the turbidity rod, which consists merely of a bright platinum wire fastened at |; right angles to a tape. Under the proper conditions the tape is lowered into the water under examination, and the end point is taken as the depth at which the wire just disappears from view. The tape is calibrated directly to read parts per million silica. The disadvantage of the turbidity-rod method is the required nicety of adjustment of conditions, involving the use of a large sample under circumstances often impossible. The turbidimeter I method, on the contrary, is independent of most of these con- ditions. Only a small sample is required. Since the method is based on the diffraction of light, the accuracy of the deter- mination is almost independent of the intensity of the light and, / therefore, of the condition of the batteries and bulb. It follows |; directly that the original calibration as given by Leighton is | applicable to any well-constructed turbidimeter. No difficulty |i was experienced in having a suitable instrument constructed !{ for our purposes. '), Sulphates are also determined with the turbidimeter, as de- a, scribed by Leighton. To 100 cubic centimeters of the water are \[ added 1 cubic centimeter of HC1 (50 per cent concentrated acid \ by volume) and 1 gram of powdered crystals of solid barium /' chloride. Precipitations are conveniently made in 250 cubic ; ( centimeter glass-stoppered bottles. The water is allowed to stand for ten minutes, with frequent shakings. The turbidity |< produced is then determined with the turbidimeter as before. The sulphate content (as parts per million of S(X) is read from the table of turbidimeter depths. Calcium was formerly determined turbidimetrically by the United States Geological Survey method, but this has been abandoned because of its inaccuracy. | The qualitative field test for calcium is made by adding enough ammonia to some of the water in a test tube or bottle to make it alkaline to litmus and then adding some ammonium oxalate. Total solids are determined qualitatively by evaporating 50 cubic centimeters of the water in a porcelain casserole to dry- ness over an alcohol lamp. The solid content is reported merely as "very small/' "moderate/' "large/' etc. The residue is then ignited, and any change in "appearance on ignition" is noted. This may be a browning or blackening due to organic matter or a deep red-brown coloration due to the oxidation of con- siderable amounts of iron present. The last is of value as a confirmatory test for large amounts of iron. 152918 8 114 PHILIPPINE WATER SUPPLIES Odor is reported, wherever possible, in such a way that both the derivation and the relative amount are indicated, namely, "very slightly sulphuretted," "strongly acid," etc. Alkalinity, acidity, chlorides, normal carbonates, and total hardness are determined by the use of tablets, as outlined by Leighton. In brief, this method consists of the use of pellets containing known amounts of reagents, instead of standard solu- tions. The titrations are performed in a small (100 to 150 cubic centimeters), heavily glazed porcelain mortar, a pestle being used to crush the pellets and to stir the liquid. The volume of water used for a titration is conveniently measured from a tall 100 cubic centimeter graduated cylinder, provided with a double scale, so that both the water withdrawn and the volume remaining can be directly read. What are practically duplicate determinations can be made very rapidly in the following manner : A few pellets are crushed in the mortar, and water is added from the cylinder till the end point is reached. The volume used is noted. Several more pellets — preferably the same number as before — are added, followed by water from the cylinder until the second end point is obtained. In this way not only is it possible to secure more accurate results by taking the mean of the two values obtained than by making a single determination, but in addition, any gross error that may arise from an unclean mortar, contaminated indicator, or defective tablet can be detected and corrected. The following reagents are used in tablets in the various determinations : Sodium acid sulphate for alkalinity and normal carbonates; sodium carbonate for acidity; silver nitrate for chlorides; and potassium palmitate for total hardness. Kaolin is used as the filler and binding material for the sodium carbonate and silver nitrate pellets, while glucose is employed for those of sodium acid sulphate and potassium palmitate. Glucose is superior to kaolin, as it is completely soluble and consequently does not obscure the end point. It cannot, however, be used in the first two cases, because un- stable pellets result. Water is used in all cases in making up the pill mass. The reagent is dissolved in water and carefully stirred into the binding material. The mass is kneaded in a mortar, more water being added if necessary, until it is homo- geneous and of the desired consistency. The tablets are made in a tablet mold. We' use a hard rubber mold (No. 10, Whitall Tatum Co., for making 50 one-grain tablets at a time). The molded pellets are dusted with pow- METHODS OF WATER EXAMINATION 115 dered talc, dried in the air and then in a desiccator over calcium chloride, after which they are packed in glass tubes about 15 centimeters in length holding about forty pellets each. The tubes are sealed with paraffin, and those containing pellets of silver nitrate are covered with heavy black paper. Need- less to say, the silver nitrate pellets are made in a dark room. The silver nitrate and sodium carbonate pellets retain their strength almost indefinitely without change. Those of sodium acid sulphate lose strength very slowly and should be restandard- ized every month. The potassium palmitate pellets lose strength rather rapidly and should be restandardized weekly. For the determination of alkalinity, pellets are molded from a pill mass containing 6.5 grams of crystallized sodium bisul- , phate and 150 grams of glucose, the proportions that will yield a pill of very nearly the desired strength (one pellet equivalent to 1 milligram CaC0 3 ) . The pellets are standardized by crushing five of them in a mortar with a little distilled water and adding a drop of butter-yellow indicator solution (0.2 gram butter yellow in 100 cubic centimeters of alcohol). Tenth-normal sodium hydroxide or sodium carbonate is added till the end point is reached. From this titration the reacting value of the pellets may be readily calculated. The field determination of alkalinity is analogous to the standardization of the pellets. The 100 cubic centimeter cylin- der is filled to the mark with the water under examination. Two or three of the pellets are crushed in the mortar with a little of the water, and a drop of the indicator is added, followed by more water from the cylinder till the end point is reached. The volume of water used in the titration is noted, readings being taken to the tenth of a cubic centimeter. Two or three more pellets are added, followed by more of the water to the second end point. The alkalinity, expressed as parts per million calcium carbon- ate, is readily calculated from the number and strength of pellets and the volume of water used in the determination. Thus, if 4 pellets of sodium bisulphate, each equivalent to 1.10 milligrams of calcium carbonate, require 22.4 cubic centimeters of the water for interaction, the alkalinity will be 1,000X4X1.10 =196 22.4 and would be reported as 200 (that is, in terms of two significant figures). If normal carbonates (or hydroxides) are present, the water 116 PHILIPPINE WATER SUPPLIES will give a pink coloration with phenolphthalein. In this event the amount of normal carbonates is determined with pellets of sodium bisulphate. The procedure is identical with that for the determination of alkalinity, except that five drops of phenolphthalein indicator solution (1 per cent alcoholic) are used instead of the one drop of butter yellow. Where the normal carbonates are present only in small amount, half, or even a quarter, of a pellet may be all that can be used. As phenolphthalein is sensitive to carbonic acid, the end point in this determination is reached when only half of the alkali is neutralized. Accordingly the same sodium bisulphate pellet that was equivalent to 1.10 milligrams of calcium carbonate in the determination of alkalinity will be equivalent to twice that amount, or 2.20 milligrams, when used in the determination of normal carbonates. Thus if 2 of these pellets require 57 cubic centimeters of the water for the reaction, the results, expressed in parts per million of calcium carbonate, would be 1,000 X 2 X 2.20 ^^ 57 ~~ When, as is usually the case with Philippine waters, the phe- nolphthalein alkalinity is less than half that determined with butter yellow, the alkalinity of a natural water is caused by bicarbonates and normal carbonates and is equal to their sum. If, therefore, no normal carbonates are present, the alkalinity is numerically equal to the bicarbonates, when both are expressed in terms of calcium carbonate. If, when normal carbonates are present, the alkalinity is found to be equal to the normal car- bonates — that is, when the phenolphthalein titration is one-half that with butter yellow — the absence of bicarbonates is indicated. If the alkalinity is found greater than the normal carbonates, the difference will be the bicarbonates, all expressed as calcium carbonate. If, however, the phenolphthalein titration is more than one- half that with butter yellow, waters contain calcium or other alkaline hydrates (caustic alkalinity) . In this case the phenolph- thalein alkalinity subtracted from the butter-yellow alkalinity is equal to one-half the normal carbonate alkalinity. The caustic alkalinity is the difference between the normal carbonate and the total alkalinity. In case the phenolphthalein and butter- yellow titrations are identical, all of the alkalinity is due to hydrates. METHODS OF WATER EXAMINATION 117 The relations between the various forms of alkalinity just discussed are shown in Table IX. 153 Table IX. — Relation between normal carbonates, bicarbonates, and hydrates in natural waters, as indicated by titration with sulphuric acid (sodium bisulphate) in the cold. Car- bonates. Bicar- bonates. Hy- drates. P===0_._ _ __ 2P 2P 2 (B-P) B B-2P O 2P-B B P* B _.._ P=B P = Phenolphthalein titration. B = Butter-yellow titration. Table X. — Conversion of turbidimeter readings in centimeters to parts per million of turbidity. Reading. Turbidity as S1O2. Reading-. Turbidity as S1O2. Reading-. Turbidity as S1O2. Reading-. Turbidity as S1O2. Parts per Parts per Parts per Parts per cm. million. cm. million. cm. million. cm. million. 2.3 1,000 6.3 350 10.5 210 19.6 110 2.6 900 7.3 300 11.0 200 21.7 100 2.9 800 7.6 290 11.5 190 23.0 90 3.2 700 7.8 280 12.1 180 25.0 80 3.5 650 8.1 270 12.8 170 28.0 70 3.8 600 8.5 260 13.6 160 31.0 60 4.1 550 8.7 250 14.4 150 35.0 50 4.5 500 9.1 240 15.4 140 42.0 40 4.9 450 9.5 230 16.6 130 52.0 30 5.6 400 10.0 220 18.0 120 70.0 20 When it is desired to express normal carbonates as sodium carbonate, the calcium carbonate value is multiplied by 1.06. Similarly the bicarbonates may be converted to the bicarbonate radical by multiplying the calcium carbonate equivalent by 1.22. If a water reacts acid to phenolphthalein, the presence of carbonic or a mineral acid is indicated. In the first case bicar- bonates may be present, but normal carbonates will not. In the second case, neither bicarbonates nor normal carbonates can be present, and the water will react acid to butter yellow or methyl orange as well as to phenolphthalein. Mineral acidity, when present, is determined with pellets of sodium carbonate, using butter yellow as an indicator. Total acidity, due to the combined effect of mineral and carbonic acids, is also determined with pellets of sodium carbonate, but J Cf . Standard Methods of Water Analysis, p. 39. 118 PHILIPPINE WATER SUPPLIES in the presence of phenolphthalein as indicator. The carbonic acid acidity is the difference between the total and the mineral acidities. Mineral acidity in natural waters is rarely encountered in the Philippines. Acidity is practically always due to free carbon dioxide and is, therefore, determined with sodium carbonate pellets, using 5 to 10 drops of phenolphthalein solution as in- dicator. The manipulation is identical with that described for "alkalinity" and "normal carbonates," except that, ordinarily, only one or two tablets, or even less, will be required for a titration. Furthermore, since the kaolin in the pellets slightly obscures the end point, the discrepancy between duplicate deter- minations is usually 0.5 cubic centimeter and often 1 cubic centimeter. In the manufacture of the sodium carbonate pellets 4 grams of anhydrous sodium carbonate are used to 130 grams of kaolin. This gives a pellet of approximately the desired reacting value, namely, 1 milligram of carbon dioxide. To standardize, 5 of these pellets are triturated in a mortar with recently boiled distilled water, 5 drops of phenolphthalein solution are added, and the solution is titrated with 0.1 N sulphuric acid. If, in a field determination, it is found that 24 cubic centi- meters of the water is the average of two readings taken for the reaction with one pellet equivalent to 0.95 milligram of car- bon dioxide (phenolphthalein being used as indicator), the acidity, expressed in parts per million of carbon dioxide, would equal ^™ B =40. 24 For the determination of chlorides, "weak" and "strong" pellets of silver nitrate are employed. The former are each equivalent to about 1 milligram of chlorine, the latter to 10 milligrams. In the manufacture of the weak pellets, 12.5 grams of silver nitrate and 200 grams of kaolin are used, while 156 grams of silver nitrate and 250 grams of kaolin are the pro- portions used for the strong pellets. The pellets are standardized with a sodium chloride solution, which is conveniently made to be equivalent to 1 milligram of chlorine per cubic centimeter. Potassium chromate is used as an indicator. The determination of chlorides in the field is rapid and simple. A small quantity of water, usually only 10 or 15 cubic centi- meters, is introduced from the filled 100 cubic centimeter graduate into the mortar, and 5 drops of potassium chromate solution (5 per cent) are added as indicator. If the chlorine METHODS OF WATER EXAMINATION 119 content of the water is high, "strong" silver nitrate pellets are | added one at a time, with thorough mixing, until an excess is | indicated by the rose color of silver. chromate. If the chlorine ; content is low, "weak" pellets are added until the end point is > passed. If the chlorine content is low, that is, under 10 parts f; per million, a half or even quarter tablet will be sufficient. In i any case, after an excess of silver nitrate has been provided, j more water is added from the cylinder until the rose color is '. entirely displaced by a bright yellow, corresponding to the shade used in standardization. Check determinations may be made \ as before by adding more pellets and titrating. ! If, to react with a half of a "weak" tablet (a whole tablet 'being equivalent to 0.96 milligram CI), there were required 76 |! cubic centimeters of the water under examination, the chlorine ; content, expressed in parts per million of chlorine, would be I * a * 4-1. . ni 100 X 0.5 X 0.96 a Q found from the expression CI— - — — — =^ =6.3. I For the determination of hardness, pellets of potassium pal- mitate, made from a pill mass of glucose and potassium palmi- tate, are used. One hundred grams of glucose are used with | an amount of potassium palmitate corresponding to 15 grams ; of palmitic acid. To make potassium palmitate, palmitic acid ( is dissolved in alcohol and neutralized with normal alcoholic i, potash solution, using phenolphthalein as indicator. The result- , ing alcoholic solution is then evaporated to dryness. The resi- le due may be used without further treatment for making the I pellets. I The following method is employed for the standardization of I the pellets : A saturated solution of calcium hydroxide is pre- I; pared from pure calcium oxide. The normality of this is deter- mined by titration of 25 cubic centimeters with 0.1 N sulphuric j acid, using phenolphthalein as an indicator. One hundred cubic centimeters of the calcium hydroxide solution are then pipetted into a 200 cubic centimeter volumetric flask. A few drops of phenolphthalein solution are added, followed by normal sul- phuric acid to acid reaction. Add 0.2 N alcoholic potash, drop by drop, until a faint pink is produced. Distilled water, which has been previously boiled to expel carbon dioxide, is added to the mark. The calcium sulphate solution thus prepared is used to stand- ardize the pellets. Five of these are crushed in a mortar with a little distilled water, and 5 drops of phenolphthalein are added. The standard calcium sulphate solution is then added from a burette, until the last trace of phenolphthalein pink disappears. 120 PHILIPPINE WATER SUPPLIES From the number of cubic centimeters used and the determined strength of the calcium hydroxide solution, the strength of the pellets, expressed in terms of calcium carbonate, is calculated. Since a saturated solution of calcium hydroxide is about 0.04 N, the standard calcium sulphate solution as prepared above will be about 0.02 N, that is, 1 cubic centimeter will be equi- valent to about 1 milligram of calcium carbonate. The potassium palmitate. tablets, as prepared above, will each be found to be equivalent to 1.5 to 2 milligrams calcium carbonate. These pellets should be standardized every week, as they lose strength fairly rapidly. What this loss of strength is due to is not yet certain, but from the data at hand it seems at least possible that it may arise from an acid fermentation of the glucose, bringing about a decomposition of the potassium pal- mitate with the separation of palmitic acid. For use in the determination of total hardness, 1 cubic centi- meter graduation marks were etched on a 100 cubic centimeter cylinder, so that volumes up to 105 cubic centimeters could be read. For a determination, 100 cubic centimeters of the water, measured in this cylinder, are transferred to a dry 250 cubic centimeter bottle (the glass-stoppered variety is convenient). A very small piece of methyl orange paper is suspended in the liquid by means of a platinum wire, while normal sulphuric acid is added from a dropping bottle until the paper becomes red. The paper is then removed to avoid coloring the liquid. The liquid is then aspirated for five minutes with a continuous pressure bulb operated by hand. After aspiration, 1 cubic centi- meter of phenolphthalein is added, followed by 0.2 N alcoholic caustic potash from a pipette, till a faint pink coloration de- velops. The liquid is now returned to the cylinder, the bottle being drained as completely as possible. The volume of the liquid is noted within 0.5 cubic centimeter. This will usually be between 102 and 105 cubic centimeters. About 10 cubic centimeters of the liquid are then introduced into the mortar. One or more potassium palmitate pellets are then added, until an excess is present, that is, when a pro- nounced phenolphthalein coloration is produced. More water is then added from the cylinder, until the phenolphthalein color- ation completely disappears. The volume of water used is noted. Several more pellets are then added, followed by water, till a second end point is reached. The two determinations should check each other within 0.5 to 1 cubic centimeter. METHODS OF WATER EXAMINATION 121 It is well to use four or five pellets in the two titrations to avoid any considerable error due to the lack of uniformity in the pellets. To calculate the total hardness, it is first necessary to reduce the number of cubic centimeters of the water as used in the determination to the equivalent number of cubic centimeters of the original water, that is, before it was diluted with sul- phuric acid, phenolphthalein, and alcoholic potash. Then the total hardness is computed from the value and number of the pellets used. For example, let us suppose that the original volume of 100 cubic centimeters had been diluted to 104.5 cubic centimeters before titration with the palmitate pellets, each equivalent to 1.80 milligrams calcium carbonate. Obviously the 48.5 cubic centimeters used for the determination are equal to 48.5 ^46.4 104.5 X 100 cubic centimeters of the original water. Therefore the total hardness would be derived from the expression 1,000 X 4 X 1.80 46.4 Or, using the data above, we may represent the entire cal- culation in one line as follows. Total hardness (as parts per million calcium carbonate) is equal to 10 X 104.5 X 4 X 1.80 _ lg5 48.5 Total solids are estimated with the aid of Dole's formula, 154 slightly modified. For Philippine ground waters, the following will be found satisfactory : 100 + normal carbonates (as Na 2 C0 3 ) + bicarbonates (as CaC0 3 )+1.7 SO3 + I.6 CI. Estimated encrustants are calculated (for the clear water) from Dole's formula: 155 Estimated encrustants = Bicarbonate alkalinity (as CaC0 3 ) -j- CaS0 4 + total hardness (as Ca C0 3 ) 154 Dole, R. B., U. S. Geol. Surv., Water Supply Paper (1916), No. 399, 304. 168 U. S. Geol Surv., Water Supply Paper (1910), No. 254, 232. 122 PHILIPPINE WATER SUPPLIES Assuming the sulphates present to be there as calcium sulphate, the CaS0 4 in the above formula becomes 1.7 S0 3 . In this form the formula is available for field work. Classification for boiler use is based upon the amount of esti- mated encrustants, according to the scheme of the American Railway Engineers' Maintenance of Way Association, which has been quoted in the discussion on industrial waters. The use of the Berkefeld army filter to clarify turbid waters, as suggested by Leighton, has been discontinued in our field work, and this for several reasons. Comparatively few of the waters examined on the average field trip are turbid. An analysis of only the clear portion of a turbid water is ordinarily not of great value, and when it is desired, a clear sample is readily obtained by sedimentation or by filtration through cotton or paper. Turbidity interferes appreciably only with the deter- mination of sulphites. Its effect can be readily overcome by determining the turbidity of the liquid after adding hydro- chloric acid and before adding barium chloride and subtracting this from the reading obtained after the sulphates have been precipitated. The difference represents the sulphate turbidity, and the amount of sulphates can be determined from the table without appreciable error. In short, the Berkefeld filter has found such limited application in our work that the minor benefits derived from its use have not been commensurate with the trouble and inconvenience of carrying it. While field methods do not claim the exactness and accuracy possible in the laboratory, it is interesting to note that in several cases the values obtained by the two procedures do not differ very widely. As has been previously stated, results obtained in laboratory determinations are expressed in terms of two significant figures only. This mode of expression itself involves limits of accuracy, which permit a maximum error of about 4 per cent. The average accuracy of field determinations, as stated by Leighton and confirmed in our own work, is roughly about 5 per cent. Turbidity shows the widest variation, ranging from about 3 per cent with turbidities of 500 to 1,000 parts per million to about 16 per cent with a turbidity of 30 parts per million, the deviation increasing fairly regularly with de- creasing turbidities. There are several sources of probable error, of which the following are the most important. Using a 100 cubic centi- meter graduated cylinder, volumes cannot be read more ac- curately than to the nearest tenth of a cubic centimeter and often I METHODS OF WATER EXAMINATION 123 I f not that accurately. Further, when the mortar is washed with I I the water under examination, a certain amount remains in the ! mortar to affect the volume subsequently employed for the next [ titration. Further the lack of uniformity in the pellets may j introduce a very appreciable error. h In our own work additional sources of probable error have f been encountered with "tabloid" methods. Our pellets are [ molded by hand and are consequently not as uniform as machine- i; made pellets. This is especially true of the potassium palmitate pellets, which form a sticky pill mass that dries very quickly | and that is very difficult to mold uniformly. Again kaolin is I used in the sodium carbonate and silver nitrate pellets and I obscures the end points, thus decreasing the accuracy of the f determinations. I In the "tabloid" determinations outlined above our methods I differ from Leighton's in that, in the determination of chlorides | and of total alkalinity, Leighton treated a known quantity of | water with an excess of reagent to obtain an end point, while f in all cases we titrate a known amount of reagent with the water to secure an end point. The former method gives values that lie between certain limits, as the excess of reagent is added in the form of parts of a pellet, and consequently the exact amount of reagent required for the titration is not determined. By making the excess small, the deviation from the true value is correspondingly decreased. By our method, however, the exact titrating volume required is determined quickly and fairly accurately. The approach to the end point is thus reversed. This probably introduces an error in the determination of chlorides, which is, however, cer- tainly much less than that involved in Leighton's method. It I should be also remembered that the standardization of the pellets | is made in the same manner as the field determination, thus decreasing the probable error. In the case of the determination | of alkalinity, however, where methyl orange or butter yellow is employed as indicator, the reversed approach to the end point (that is, from acid to alkali) is theoretically the more correct of the two procedures and should, therefore, further increase the accuracy of the method as outlined above. Summing up the whole question of the accuracy of field meth- ods, it might not be out of place to quote from the introduction of Leighton's paper: To the methods hereinafter proposed the term "assay" readily lends itself. There is no attempt at water analysis. The plan contemplates 124 PHILIPPINE WATER SUPPLIES the determination of ingredients which give to water certain well-known characteristic. The methods ' * * * have been found to be more nearly accurate than was at first anticipated, though this fact, it is believed, has not greatly increased their usefulness for the purpose in view. By their use, combined with a fair amount of common sense, the essential charac- teristics of waters can be ascertained at small expense. In almost every situation in which such determinations are significant they will afford sufficiently satisfactory data. In the case of finely balanced consider- ations of a purely physical, chemical, or geologic nature, however, they are practically useless. They are intended for practical purposes and have no place in pure science. INTERPRETATION OF WATER ANALYSES When a water is very good or very bad, the judgment of its quality is usually a simple matter. Unfortunately for the analyst, however, one cannot, generally speaking, classify waters as unqualifiedly "good" or "bad." Both in laboratory and in field work it is generally impracticable to make more than one examination, and it must be admitted that a single test fre- quently affords insufficient basis for the interpretation of results. In passing judgment on the quality of water supply, one must know the purpose for which the water is intended. Water entirely unsuitable for one use may be well adapted to some other. Thus a supply that might be dangerous for drinking might be excellent for use in manufacturing processes; a hard water unsuited for laundry or boiler purposes or for soap manu- facture might be advantageously used for brewing or irrigation ; water with moderate salt content is often desirable for brewing, though it is unsuitable for soap manufacture ; a water supposed to have great medicinal value might be unfit for boiler use. Sufficient has been said in preceding discussions to show that many factors must be considered in passing judgment upon a water. Difficult as it is to set up arbitrary standards even for waters designed for industrial use, the problem of judging sup- plies intended for human consumption is even more difficult, for here the effect of various ingredients cannot be determined as accurately as it can be for technical applications. Considering first the technical applications of water, some of which have been discussed under industrial supplies, the signifi- cance of various ingredients may be summarized briefly some- what as follows: 156 Free acids, — Free mineral acids rapidly corrode metal work, and in addition to this destruction may introduce a portion of the dissolved metal into the finished product. In the paper and textile industries acids rot and streak the fabrics, in addition to decomposing some of the chemicals and dyestuffs. In the Philippines, however, very few minerally acid waters are found. 156 These statements, which are only general in character, are based chiefly on the classifications by Dole, R. B., TJ. S. Geol. Sum., Water Supply Paper (1910), No. 254, 232, and by Klut, H., Eng. Rec. (1910), 60, 498. 125 126 PHILIPPINE WATER SUPPLIES Total solids. — Over 300 parts per million of total solids (res- idue on ignition) generally make water undesirable for boiler purposes, although under certain conditions waters with many times as great a mineral content may be used. Suspended matter. — Suspended matter is objectionable in all process in which water is used for washing or comes into con- tact with food materials. It frequently causes stains or spots. For this reason even a small amount of suspended matter due to precipitated iron is especially injurious. Suspended vegetable or animal material is liable to decomposition and partial solu- tion. Water should be, therefore, freed from suspended matter before being used for laundering, dyeing, bleaching, starch and sugar making, brewing, distilling, and similar processes. Color. — Color in water is due principally to solution of vege- table matter, though in freshly drawn spring and well water it may result from iron. The chief objection to color due to vegetable matter is in the paper and textile industries, where the finished product may be tinged. Iron. — More than 0.1 part per million of iron may be objection- able in the industries. It forms greenish or black substances with materials containing tannin, which discolor hides in tan- ning and barley in melting, and which give beer bad color, odor, and taste. In all cleansing processes, especially if soap or alkali is used, precipitated iron is liable to cause rusty or dull spots. Waters containing large amounts of iron may develop growth of Crenothrix, a small filamentous plant colored with iron oxide, which clogs pipes, valves, and faucets and causes rust stains on clothes washed in the water. Manganese. — In any appreciable quantity, manganese gener- ally makes water unfit for industrial purposes. Calcium and magnesium. — The effect of waters used for boiler purposes has been already discussed. For many other indus- trial purposes they are just as undesirable. In laundering, the soap (which is a compound of sodium or potassium with certain fatty acid radicals) is decomposed, with the formation of a curd of insoluble calcium or magnesium "soaps," which have no detergent or lathering properties. Soap will continue to be wasted, and no lather will be secured, until all the calcium and magnesium have been used up. Calcium carbonate wastes eight times its weight of soap. In laundries supplied only with hard water, softening is imperative. High calcareous waters cannot be used in distilleries, because proper action is hindered by the deposition of alkaline earth INTERPRETATION OF WATER ANALYSES 127 salts on the grain in boiling, nor can they be used for diluting spirits, because they cause turbidity. In cooking, a hard water is objectionable, as a deposit of lime salts is formed upon the surface of tea leaves, meat, vegetables, etc., which hinders their extraction or hardens their tissues. It has been asserted that 'ten ounces of tea made with soft water is as strong as 18 ounces brewed with hard water'; and M. Soyer * * * proved that in the making of soup more meat is required with a hard water, and the operation takes a longer time. Vegetables have their colour darkened by the action of carbonate of lime. * * * In baking, the dough rises better, and the bread is lighter in colour, when soft water is used. im The presence of calcium and magnesium compounds may sometimes be advantageous. Thus, in brewing certain beers and ales, calcium sulphate is desirable. In paper making slightly hard waters are preferable to very soft ones, as the latter dissolve part of the calcium sulphate used for loading. Sulphates. — Hard waters with sulphates predominating are desirable in tanning heavy hides, because they swell the skins, exposing more surface for the action of the tan liquors. Sul- phates interfere with crystallization in sugar making, so that the amount of sugar retained in the mother liquor is increased. Chlorides. — More than 100 parts per million of chlorine may be injurious to plants ; more than 200 are generally detrimental to boilers. Salty waters should not be used in concrete construc- tion. In tanning, chlorides cause the hides to become thin and flabby. Waters with high salt contents obviously cannot be employed in soap making or in laundry work, as soap is insoluble in them. Beverages and food products, of course, cannot be treated with waters very high in chlorides without becoming salty. In sugar making, the animal charcoal used in clarification is deprived of its bleaching power by absorption of salt, and saline salts are incorporated in the finished sugar crystals. In the preparation of alcoholic beverages chlorides in large amount prevent the growth of yeast and interfere with the germination of the grain. Silica. — If present in large quantities, silica is considered objectionable for boiler purposes. Nitrates. — A high nitrate content spoils water for brewing, fermentation, or sugar refining. Ammonia. — Ammonia interferes with starch, brewing, or fer- mentation industries when more than a trace is present. Carbon dioxide. — Free carbon dioxide as a rule accelerates corrosion. a67 Rideal, S. and E. K., Water Supplies (1915), 141. 128 PHILIPPINE WATER SUPPLIES Hydrogen sulphide. — Hydrogen sulphide is poisonous. In addition, it is corrosive even in small quantities, and may also injure materials by discoloring and rotting them. This sub- stance is associated with such large amounts of dissolved salts in many waters that they are unfit for industrial use for reasons other than their gaseous content. Organic matter. — Organic matter of fecal origin is, of course, dangerous in any water that comes into contact with food pro- ducts. Even when not necessarily capable of producing dis- ease, it is undesirable in industrial supplies because it induces decomposition in other organic materials, such as cloth, yarn, sugar, starch, meat, or paper, by rotting and discoloring them. Other substances. — Other substances commonly occurring in Philippine waters are normally present in such small amounts as to render discussion of them unnecessary. The changes that take place in a water sample on standing frequently help to make interpretation of analyses more dif- ficult. As a typical instance may be mentioned the changes in carbon dioxide, carbonate, and bicarbonate content, previously discussed. These ingredients frequently change to such an extent that the analysis is misleading. As was pointed out in the preceding chapter, the examination of water consists of three parts — chemical analysis, bacterio- logical examination, and sanitary survey. One of these is often sufficient to determine the potability. As a general rule, how- ever, it is not enough to know that a water is good at the time of examination ; it is just as essential to find out whether it has been contaminated in the past or whether it is subject to con- tamination in the future. All methods at our disposal are gen- erally needed, therefore, to enable us accurately to judge the potability of a water. Considering first the chemical features of a water examina- tion, the common ingredients and properties of waters with respect to potability may be classified as follows: 158 Color, odor, taste, turbidity. — The best water for drinking purposes is clear and is free from objectionable color, odor, or taste. Color and turbidity in themselves are not important except when they are caused by harmful or objectionable substances. Total dissolved content. — The total dissolved content in itself has no significance. When the solid content is very high, waters are sometimes laxative or objectionable in taste. 158 Cf. also Klut, loc. cit.; Dole, loc cit. INTERPRETATION OF WATER ANALYSES 129 Hardness. — When hardness is high, it may affect the taste, but in itself it is of little importance hygienically. Alkalinity. — Alkalinity is not believed to be as objectionable as it was formerly considered to be, some waters having an alkalinity of 900 to 1,200 parts per million being palatable and having no noticeable ill effect. 159 Silica. — Silica in the quantities normally found in natural waters is not considered to have any appreciable effect on potability. Chlorides. — Chlorides are generally an indication of the amounts of salt in water. Salt in itself is not objectionable, except in so far as it affects taste or indicates sewage pollution. In the latter case it is not the actual amount of salt present, but the deviation from, the normal for any given district, that is the criterion. In some parts of the Philippines people have accustomed themselves to waters containing 800 parts of chlo- rine per million, and experience in this and other countries has demonstrated that such quantities in drinking water are not injurious to health per se. Nitrogen. — The importance of nitrogen and the forms in which it may be present have been discussed under methods of analysis. Aluminium. — Aluminium has no hygienic importance in the quantities normally found in water. Iron. — Iron, like aluminium, has no significance in the small quantities normally found in water, but it is sometimes objec- tionable because it imparts an unpleasant taste to water and because it promotes the growth of Crenothrix in pipes and re- servoirs. A good water usually contains less than 2 parts of iron per million. Calcium. — Calcium has no significance so far as known. Magnesium. — In the presence of sulphates, magnesium causes intestinal disturbances when present m large amounts. Sodium.- — Sodium and potassium have no significance. Arsenic. — Arsenic is poisonous. At least one case is known where a natural water in the Philippines contained enough 5 arsenic to be dangerous for drinking purposes. i: Lead. — Lead is a cumulative poison whose presence renders | water unfit to drink. It is seldom found in natural waters. I Copper, zinc, and tin. — Copper, zinc, and tin are not found f in natural waters in objectionable quantities. f Sulphates. — (See Magnesium.) In themselves sulphates are ( unimportant. Over 500 parts per million can be present in j 159 Ruediger, E. H., Am. J own. Pub. Health (1913), 3, 1904. 152918- 9 130 PHILIPPINE WATER SUPPLIES water without causing bad effects, though when present with magnesium, or even with sodium, large quantities sometimes cause intestinal disturbances. Hydrogen sulphide. — Hydrogen sulphide is poisonous; hence it is objectionable in large quantities. Oxygen-consuming capacity. — The oxygen-consuming capac- ity is an indication of organic matter and is often valuable when a fresh sample can be secured and when a water source can be kept under observation for some time. Philippine waters have not been sufficiently studied to enable a standard to be set up. Dissolved oxygen. — Dissolved oxygen is a valuable indication of the purity of a water when the determination is performed at short intervals. It, too, can be measured only in fresh samples. From the foregoing it is evident that, in general, the mineral content of a water may vary within wide limits without affecting its potability. It is further evident that hard and fast standards cannot be set up. It is the exception, rather than the rule, that the substances found in water by chemical analysis are in themselves injurious to health. The object of a chemical analysis, therefore, is not usually the discovery of harmful ingredients, but the determination of substances whose presence or absence indicates the possibility of contamination by material dangerous to health. Thus in mak- ing a sanitary analysis of waters, it has been customary to determine, among other things, the chloride content. Chlorides, generally present as common salt, are neither poisonous nor dangerous. However, they are found in sewage; hence a high chlorine content, or a sudden variation in the content, might be due to an influx of sewage and must be viewed with suspicion. A variation in chloride content, as, for example, a sudden shift from 50 to 150 parts per million, is to be viewed with suspicion, whereas a constant chloride content of 200, or even of 250 parts per million would not indicate contamination. It is necessary to determine the normal mineral content of waters in different localities and to base judgment of waters on their deviations from such normals. Unfortunately the work done in the Phil- ippines has been insufficient to develop normals, and as pointed out previously the waters from comparatively small districts in the Philippines show such great fluctuations that it does not appear probable that they can be developed for some time to come. Since standards, to be reliable, must be based on normals, it is clear not only that no arbitrary standards can be set up for the Philippines at the present time, but also that INTERPRETATION OF WATER ANALYSES 131 the application of foreign standards will lead to confusing or incorrect results. The many attempts that have been made to develop bacte- riological standards of purity for water have shown that bacte- riological examination, like chemical analysis, must be interpreted with great caution and in conjunction with other essential fac- tors to ensure satisfactory conclusions. Also, as with chemical analysis, only the very good or very bad waters are easily classified. Because of the essentially different bacteriological character of waters from different types of sources, it is extremely unlikely that a single fixed standard can be developed. The organisms normally found in certain classes of waters might indicate a high degree of pollution in others. A river free from pathogenic organisms might have a colony count high enough to cause a deep well to be viewed with suspicion. A water that has a high bacterial count is obviously un- desirable for human consumption, for the presence of many organisms, even harmless ones, indicates, other things being equal, that pathogenic organisms may readily find access to the water. Just what limit shall be fixed, however, is not easy to say. The standard adopted by the United States Treasury Department for drinking water supplied to the public by common carriers in interstate commerce 16 ° provides that the total num- ber of bacteria on standard agar plates, incubated for twenty- four hours at 37°, shall not exceed 100 per cubic centimeter. For public water supplies obtained from a river Frost 161 recom- mends a limit of 100 colonies per cubic centimeter on agar plates incubated for forty-eight hours at 20° and states that a really good water should show not more than from 10 to 50 colonies per cubic centimeter on standard agar incubated at 37° C. A factor that frequently increases the difficulty of inter- preting bacteriological colony counts is the rapidity with which changes take place in the number of organisms existing in water. It has been estimated l(i3 in the United States that un-iced speci- mens of water examined twenty-four hours after collection may safely contain 200 colonies (agar plates; 20° C. incubation) and that from forty-eight to seventy-two hours after collection 500 colonies may result. Though the authors conclude that the 160 Anderson, J. F., et al., U. S. Pub. Health Rep. (1914). 29, 2959-2966; Eng. News (1914), 12, 1203-4. 161 Frost, W. H., Eng. Contr. (1914), 42, 250, through Chem. Abst. (1914), 8, 3606. 162 Albert, H., Hinman, J, J., and Jordan, G., Journ. Bad. (1916), 1, 119. 132 PHILIPPINE WATER SUPPLIES results of tests on un-iced specimens may be relied upon if prop- erly ( ?) interpreted in the light of sanitary survey, great depend- ence cannot be placed on such methods. Especially in tropical countries like the Philippines the high average temperature, as compared with that of a temperate country, makes fluctuations more rapid and much greater than the figures just quoted indicate. The examination for organisms of the colon-typhoid group is a test, not so much for specific bacteria that are inimical to health, but rather for those, more readily determined, that indicate the possibility of the presence of associated pathogenic organisms. In general, the occasional presence of B. coli in very small numbers is considered permissible. According to Ander- son and others 163 not more than one out of five 10 cubic centi- meter portions of a water sample should show organisms of the B. coli group ; according to Frost 164 these organisms should never be found in 1 cubic centimeter samples and should be absent in from 70 to 90 per cent of samples of 10 cubic centimeters. According to McLaughlin 165 potable water should show not more than 2 B. coli per 100 cubic centimeters, taking the average of many samples by the Phelps method. Unfortunately the test for the B. coli group, as usually per- formed, is by no means conclusive. It has been demonstrated that organisms resembling B. coli in their behavior, but not of faecal origin, are found in surface waters even in temperate climates. 166 Certain cultures from grains belong to this type. Abundant experience in tropical water-supply problems 167 has shown that a presumptive test for the colon group can be obtained under conditions that practically exclude the possibility of fecal contamination. Waters from almost sterile wells in the Philippines have caused gas formation in litmus lactose agar. Zammit and Marich 168 record instances where springs in Malta, believed to be uncontaminated, showed coli-like organisms, as did even carefully collected rain water. To what extent the standards just discussed are applicable to Philippine problems is not established. They are typical of standard procedure elsewhere and may serve as a basis for 163 Op. cit. 164 Loc. cit. 165 McLaughlin, A. J., Pub. Health Rep. (1914), No.. 204. 160 Rogers, L. A., Journ. Bad. (1916), 1, 82. 167 Clemesha, W. W., Journ. Hyg. (1912), 12, 463. 168 Zammit, T., and Marich, E. R., Journ. State Med. (1916), 24, 76-81. INTERPRETATION OF WATER ANALYSES 133 future work. It is certain, however, that the standards that hold for temperate regions are not to be used without modifica- tion for tropical countries. This has been pointed out in con- nection with the various factors already discussed and is sup- ported by the evidence from other countries. Thus Bowles 169 has shown the inapplicability of ordinary bacteriological stand- ards to the water-supply problems in Panama and Mexico. So far as experience in the Philippines is concerned, the following general statements concerning bacteriological interpretation seem justified : ' Flowing artesian wells are practically sterile. Deep pumping wells in good condition are very low in bacterial content. The colony count should not run over 50 per cubic centimeter. If a higher bacterial content is indicated, an exami- nation of the pump should be made, as this is frequently the source of contamination. If the high content is not due to the pump, as demonstrated by a second test after necessary repairs have been made and the well has been subjected to a thorough pumping, contamination is indicated, and the water is not above suspicion. Springs, in general, are more liable to contamination than deep wells ; hence they must be examined with special care. To be above suspicion, a spring water should show less than 50 colonies per cubic centimeter. Surface wells in the Philippines, with comparatively few ex- ceptions, are subject to contamination and must be viewed with suspicion, regardless of the bacterial content indicated by a single examination. Rivers in the Philippines, unless draining a district known to be uninhabited, are to be viewed with suspicion, even though a single bacteriological examination might show them to be satis- factory at the time of examination. Bottled natural and carbonated waters should be sterile. The presumptive test for B. coli must be interpreted liberally, in conjunction with the chemical analysis and the sanitary sur- vey. A positive presumptive test obtained from a water that shows only a low colony count is not conclusive. The scope and possibility of the sanitary survey have been already described and need no detailed explanation here. Each case presents individual characteristics and problems, the proper interpretation of which depends upon the ingenuity and expe- 169 Bowles, J. T. B., Am. Joum. Pub. Health (1916), 6, 1173. 134 PHILIPPINE WATER SUPPLIES rience of the man in the field. It cannot be too strongly em- phasized that an intelligent study should be made of the source of every water of which analysis is requested, and further that, whenever possible, this survey should be made by the person called upon to interpret the analysis. Before leaving this subject, it may be mentioned that evidence other than that furnished by the ordinary examination may be needed to establish the quality of a water. Special methods are frequently adopted to secure such evidence. Thus connection between a well and a possible source of pollution may be occa- sionally demonstrated by placing a kilogram or two of salt on the suspected area and noting any appreciable rise in the chlorine content of the water. Fluorescin may be used for the same purpose, its presence giving a characteristic fluorescence to water. Or, since liquids might filter unchanged through a soil that would remove bacteria, a culture of some easily recognized organism might be used instead of salt or fluorescin. Bacillus prodigiosus has been so used with satisfactory results. The problem of judging the potability of waters can be sum- marized somewhat as follows : Each water should be regarded as a separate case and should be judged accordingly. One of the special advantages of a chemical analysis lies in the fact that it sometimes gives an indication of pollution in the past; hence the possibility of recurrence of contamination, in cases where bacteriological examination gives no indication of danger. A bacteriological examination is extremely valuable in that it makes contamination evident even in some cases in which neither chemical analysis nor a sanitary survey would detect pollution. On the other hand, neither chemical nor biological work might detect a source of danger that a sanitary survey would locate. Chemical and biological examinations are complementary; neither is all-sufficient"; and valuable as both are, they should be carefully interpreted in the light of the knowledge gained by an accurate and painstaking sanitary survey. INTERPRETATION OP WATER ANALYSES 135 -duinsa'jj o o o o QpQQQQQQQg ripppppppppppp£ O » O Oh £ P* LQrHOOCOOOCDCM UDO^OOlOi-HC-rfO C- CM 00 O 00 lO Q r-t tH O tH r-H 5 uoiVeoyissBjo > « Oh O O O O 73 r d 'O ^ ! ! ! ! ! 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Positive. -iq.uao oiqno jad s a i u o J o |3 § o r-" CO © © o © o to oo" oj 3,800 2,800 4,800 25, 000 many CO © r-1 t- o i ia © © i tH o tH i O O 03 "43 53 g n '5 o 1 PC c o T3 fu ! c ! ^ pq 1 Ph 1 PQ o o o tl tl fl J. ! ! ! '5 ! | ! f* c Ph o o Ph 'S^UB^SnjD -ui pa^Buii^sg oooooooooooo HONtONOHt-TllMOOM © CO *(8O0«0) SS9Upj[Bq IB5.0X ipooooooomooo-^oicoo *(*OS) sa^Bqdtn g 007HrliuCJeOT-101COt-TH«5Cw©<^oo©LOo6io t-" SS^ro^OONCOCOMCOrHr^&COCOrHT-H CMCOr-1 H Ifl "■* ■(a^) uoji _ JJ , C J3^_ t» W t" t- ■— < LO IlO CO ^rHOO^CMOOlOCMON'giOCCINON S © «5 ©' lO ©" CQ © r-" © © ©' ©' ©"©'©' CO i-H © ■(*00)*HPK>V CD Q r-J £ £3 £3 !£2 3! ^ 3 a oo'-* w m S M H (M H CO r-1 £ tH N CO CO -P fn C- OJ © CO ■^ CO CO "(800*0) A p. 1 U t l B 31 l y •^ipiqjnx 4-> +3 4J +5 4J •ean^Bjaduia,!, . © U3 O U5 ^ oo oo oi n! ° N N N N ID © © © io as oo od ai od N N N N w O lO lfi CO O O N 00 H M M tfi 00 l> a CO ^ M N N M OJ N (N •q^daa j © i © © CO* csi © tH co' CJi* j © © i co id ' J ^A ) Location. (Province, town, barrio.) 1 t ec c £ s s 53 u 1 J ► c 01 ,£3 a j ° i ft * i.' (tf C ■ 1 c ' CM tH rH tH tH CM I 2 IV © ^ co' co" ©' © © © © O M J © od C fi C Pi C fi CM CM CM - V CO CO to 00 ©' rH* rH © © CO © © CO ^3 cu to © © © © to to © to 00 © to © CO -# T-i to to CO © 00 00 CO CO t— i 3 < Eh O t« 43 3 •(SOO^D) *(*OS) •( 8 00H) saq-Bu o q a b d 1 a •(£00) sa * B -uoqa-eo TBmaojsj 0000 Q Q Q Q 10 O iO 10 O O CO 'J O fa o O O CO O i-l CO Th t- N to U5 W O tH CD 00 00 10 00 ■<* UJ 0) 4 d to O 00 O "tf OS IO » lO ID Tj( fl 'fl fl fj S fl fl (5 "(10) sapuotqo •(3^) UOJI •(S00) AIPPV '(S0D«D) £ % I U l [ T3 3f [ y •^q-tpiqjnj, •9.111413 jadmaj, •q^dacr l! 000000 00" ©* O O* iH o OS tD O CO O OS OOCO ~ os tA tA 1© •>*' r* •**' eg u (M0000(NCM> >> 5 O 9 '3 < CO o O 3 «3 2 .5 '3 o bo AS O .5 'u Q tf . oO -flO OS CO +3 . Mo S CD -CO 1,800 64 3.6 23 trace 960 33 160 2,200 160 3,700 71 1.0 83 60 700 2,600 130 slight 120 1,600 30 trace 36 6.3 570 nil 145 43 15 195 14 460 85 0.8 47 22 26 nil 240 110 50 230 20 570 80 1.6 50 33 30 nil 280 140 high 165 190 1,800 74 13 210 240 36 200 39.5 160 9 445 77 0.6 55 18 18 nil 190 100 450 460 62 69 2.0 0.68 20 18 11 10 32 29 trace trace 35 340 5.3 nil 420 990 220 67 60 trace 0.60 51.5 7.5 43 17 218 11 95 nil 5 150 4.6 nil 180 605 940 68 54 3.6 1.5 11 50.0 10 19 107 275 trace trace 40 380 18 nil 415 53 520 32 620 80 2.8 78.0 38 43 nil 640 trace 5 350 27 460 73 2.4 76 24 7.6 431 trace 55 520 22 580 76 1.0 77 32 29 630 trace 32 580 23 710 50 1.2 73 40 62 nil 710 trace 210 570 60 65 3.7 0.5 1.2 8.9 nil 12 6.2 85 88 trace (b) 245 nil 300 160 4.6 300 70 0.38 2.2 <2.0 12 nil 200 trace <5 90 nil 140 60 0.20 5.1 1.4 4.4 nil 110 trace 20 70 10.0 nil 210 105 90 0.06 0.24 9.7 1 6 5.5 nil 80 nil 120 250 trace trace 7.2 nil 150 trace ' (*>) 370 1, 100 420 670 560 150 trace 7.0 8.7 190 7.6 191 130 nil 450 120 26 22 1.7 1.7 37 64 30 31 44 24 390 120 290 490 235 18 6.3 4.3 150 6.2 1 high 86 7.7 31 3.4 92 : nil 130 90 trace 25 11 nil 160 , trace : nil 140 235 85 trace 25 11 8.2 nil 170 trace j n " 140 235 90 trace 22 11 6.2 nil 160 trace »«1 130 235 90 trace 22 12 6.2 nil 160 trace 290 270 275 300 290 290 300 280 98 2.5 16 60.3 12 4.4 3.4 12 13 13 12 2.5 trace 0>) I 91 trace 4.8 i 2.8 27 14 380 395 74 93 43 53 8.9 15.5 4.4 7.4 trace i I d Filtered. 158 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 79221 98447 118046 119051 119111 119211 119293 119420 119581 120551 120614 120733 120831 121352 121146 121451 121566 68518 113010 117608 117610 117444 117897 117898 119134 123402 123759 124295 124667 124511 119073 119255 119564 122156 121282 121284 121351 121837 122416 105125 122690 122771 122889 122977 123054 123196 124967 175 354 584 670 673 681 686 690 697 785 794 800 804 815 839 852 860 79 495 499 522 555 563 571 638 982 997 1000 1020 1011 640 672 688 712 780 822 846 847 882 420 942 946 952 955 961 966 1031 1910 1912 1914 1914 1914 1914 1914 1914 1914 1915 1915 1915 1915 1915 1915 1915 1915 1909 1913 1913 1913 1913 1913 1913 1914 1916 1916 1917 1917 1917 1914 1914 1914 1916 1915 1915 1915 1916 1916 1912 1916 1916 1916 1916 1916 1916 1917 Batangas, Balayan Batangas, Balayan, Calatagan Batangas, Batangas Batangas, Batangas, Calle Jaena Batangas, Batangas, Plaza of Government Building. Batangas— _. Batangas, Batangas, Calle P. Burgos.- _. —_do do ____ . Batangas, Batangas, Paharang _. Batangas, Batangas, Sampaga _ do __. Batangas, Batangas, Tolo Batangas, Batangas, Dumantay do ___ Batang-as, Batangas, Santa Rita Batangas, Batangas, Mahabang Parang Batangas, Bauan do ..... _do. -do. .do. ..do. Batangas, Batangas, Lagnas _ Batangas, Batangas, Asias ___ .-.do _ Batangas, Batangas, Cupang _ Batangas, Bauan Batangas, Bauan, Alolam .__.._ Batangas, Bauan, Bulibay Batangas, Bolbok ___ .-..do Batangas, Bolbok, Sico Batangas, Bolbok, Quipot do _ Batangas, Bolbok, Talahiban_. Batangas, Batangas, Bolbok _. Batangas, Bolbok __. do. Batang-as, Lipa do . do Batangas, Lipa, Antipolo Batangas, Lipa, Anilao do do Batangas, Ibaan._ a Yellow. Meters. 114 238 145. 7 74 77.7 128.6 136 128 115.8 65.5 67.6 80.5 87.1 67.3 68.8 106 99.6 80.7 91 125 128.9 152 153 158 46.0 79.2 68.3 67.4 94 82,9 142.9 138.7 179.8 236.2 132 160 101.5 172.2 182 43.3 37.5 34.7 43.6 19.2 102.1 47 Liters. F 568 P95 P151 P379 P379 P379 P189 P114 P132 P95 P114 P114 P114 P114 P473 P114 P45 P303 F379 P76 P76 P303 P189 P 757 P132 P38 P30 P45 P45 P45 F 19 F 57 F 76 P76 P114 F 76 P95 F 114 P30 P246 P45 P45 P45 P45- P45 P 30 P 38 nil nil nil 00 nil nil 00 6.0 2.0 nil nil nil nil nil nil nil c Brown. INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 159 +3 si >> < O o is < "o w 3 O 3 a | '3 o "a .2 13 S' 5 Q .s m ■*■» oO »H V -' B3 m oO m 380 1,300 330 380 390 360 380 370 81 63 59 74 78 68 68 6.5 3.6 3.2 1.7 3.7 3.7 3.7 trace trace 40 15 43 35.5 28 40 15 43 15 4.7 16.6 17 18 14 15 16 8.5 455 4.7 10 9.2 11.5 9.9 6.3 41.6 9.2 7.3 11 7.2 7.2 43 CO 0>) nil 270 nil 190 nil 250 360 57.5 trace 48 19 7.2 nil 280 4.1 nil 320 515 90 trace 95 22 30 nil 390 nil nil 225 380 92 2.0 57 19 14 nil 270 nil nil 245 385 90 trace 77 22 10 nil 300 trace nil 250 400 100 3.0 52 22 10 nil 305 6.0 255 400 83 0.25 56 24 14 nil 310 trace 260 370 76.5 0.7 31 22 7.7 nil 320 8.2 285 420 74.5 1.1 50 22 9.3 nil 350 trace 220 370 700 360 370 420 380 380 360 390 400 100 0.7 39 13 8.2 5.4 7.8 8.5 7.0 5.6 6.9 4.2 13 8.4 270 trace 74 79 73 88 81 71 76 95 2.0 2.8 4.8 0.4 trace 2.9 7.7 1.2 41 46 39 60 39 42 50 45 16 15 17 27 14.5 17 11 15 7.0 3.6 6.4 4.4 trace 5.1 100 trace 00 60.0 250 7.0 nil 300 <5.0 170 23 440 80 0.28 49 11 25 nil 190 <5.0 10.0 280 14 420 90 0.95 56 20 10 nil 340 trace 65.0 210 10 410 160 1.3 38 12 7.6 nil 260 3.0 60.0 380 11 530 90 0.80 90 28 10 nil 470 8.2 860 980 825 32 38 32 3.7 3.7 2.5 1.2 18 10 1.2 11 nil 166 250 110 nil 12.1 nil slight 550 nil 650 75.0 550 16 1,500 85 6.8 49 15 490 nil 670 trace 505 910 60 1.1 34 19 175 nil 620 trace 540 1,400 72.5 1.15 7.1 8.9 200 nil 660 trace 240 380 80 1.15 45 16 8.7 nil 290 trace nil 510 13 920 37 1.3 14 9 160 nil 625 trace 85.0 520 5.4 1,400 68 1.8 29.5 28 440 640 trace 295 270 94 100 3.0 0.22 35 18 10 6.2 7.8 12 15 5.9 3.0 120 32 nil 150 10.0 160 35 320 80 0.22 35 16 16 nil 200 10.0 30.0 170 45 490 100 1.9 57 53 36 nil 210 18.0 <5.0 160 32 330 100 0.5 32 12 15 nil 200 7.8 nil 125 33 290 120 0.16 26 7.5 12 nil 150 trace 200 120 23 330 200 1.6 20 <5.0 7.3 nil 140 trace 250 1 170 13 300 85 0.18 26 11 11 nil 200 trace * Turbid 160 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. nil nil 00 nil 00 00 125009 124929 93292 95430 122578 120438 119898 119947 119984 120041 115331 70173 117463 123530 123618 108462 109934 121739 87828 83743 81901 74636 118223 79477 79478 83330 83331 117767 96694 80289 91226 118408 118556 105141 85759 87524 89432 97049 98529 118047 118305 118596 47956 43533 105809 49775 78825 44052 1050 1045 307 339 935 779 713 730 736 744 92 529 988 995 436 469 873 577 3? 2? 551 167 192 619 400 224 246 279 345 364 586 603 616 162 1917 1917 1911 1911 1916 1915 1915 1915 1915 1915 1913 1909 1913 1916 1916 1912 1912 1916 1911 1910 1910 1909 1914 1910 1910 1910 1910 1913 1912 1910 1911 1914 1914 1912 1911 1911 1911 1912 1912 1914 1914 1914 1907 1907 1912 1907 1910 1907 Batangas, Ibaan __. Meters. 32 41 Liters. P 38 P 38 P 23, F 19 P 151 P 45 P 114 P 95 P 95 P 95 P 95 Batangas, Ibaan, San Jose Batangas, Nasugbu ___ do. 47 59.1 48.8 35.7 36.6 29.3 29.3 Batangas, Rosario Batangas, San Isidro Batangas, San Jose (plaza) Batangas. San Jose, Calle Burgos Batangas, San Jose, Calle Biacnabato Batangas, San Jose, Nomel Batangas, Santo Tomas Batangas, Taal 189 113 80.5 90.5 337 128 50 Batangas, Taal, Balisong P 189 P 30 P 30 P 189 P 189 P 45 nil nil 00 nil do._ Batangas, Taal, Calumpang Batangas, Tanawan ___. do .__ do Bohol, Albuquerque __ Bohol, Bacloyon, Laya _ _._ do P 61 Bohol, Dimiao, near municipal building Bohol, Inabanga 10 130.1 P 38 Bohol, Loboc, Ilaya__ _ do Bohol, Loboc, Sauang Bohol, Loboc, Villaflor Bohol, Loon .___ 79.2 P 57 Bohol, Panglao, Tagnan Bohol, Tagbilaran r Bohol, Tagbilaran, Mansasa - __ 171 P 227 do 213 28.7 142 152 119 163 124 180 157.3 135.9 134.1 P 227 P 379 F 303 F 95 F 719 F 57, P 114 F 151 F 47 F 114 ' F 76 F 227 do_. . _ Bulacan, Angat __ _. _ ._ __ Bulacan, Baliuag do—. do do do Bulacan, Baliuag, Camboag Bulacan, Baliuag, Tanauan _ Bulacan, Baliuag, Sabang __ Bulacan, Bigaa._ __ Bulacan, Bulacan _ do Bulacan, Bocaue __ 128 124 Bulacan, Calumpit _ F 64 Bulacan, Guiguinto ._ 1 Yellow. c Brown. INTERPRETATION OF WATER ANALYSES the Philippine Islands— Continued. 161 >> 5 (M o u >> < CD CQ Is +» o H O 3 33 2 "c3 O la .2 "5 u 0>O 9 .s m oo **"— ' O tfi «-£ go s CO -CO ft S w nil 10.0 120 160 40 16 330 350 640 650 400 485 330 300 365 320 270 5, 100 490 350 370 325 280 340 330 1,500 1,300 460 800 410 520 460 565 1,100 700 2,150 1,600 240 420 1,400 1,000 1,100 1,050 1,100 900 580 970 1,100 400 700 600 260 340 1,400 100 100 120 78.5 50 SO 77.5 77.5 80 120 0.14 0.24 4.0 6.5 0.48 4.0 0.5 nil trace 0.6 34 36 4.7 23 52 71.5 50 27 63 19 9.2 8.6 2.16 20 13 29 17.5 13 21 13 27 26 58 220 17 25 21 9.0 20 20 6.9 2,600 25 13 8.8 12 9.4 1.6 7.8 590 500 75 18 11 13 28 41 410 140 985 670 3.3 42 740 510 600 560 610 470 280 540 585 100 230 165 26 49 650 nil nil 150 200 nil trace 68.0 19 20 4 16.5 12 14 12.5 5.0 high 00 nil nil 00 180 320 150 175 200 130 48 13 nil nil nil nil nil nil 220 390 180 210 240 130 10.0 95.0 00 00 nil 170 140 28 28 100 200 72 84 90 0.42 0.68 6.0 3.8 0.4 31 18 36 25 39 1.2 3.0 7.6 6.7 10 nil nil 230 170 8.5 trace 57 32 33 160 nil 195 13 0.5 170 121 295 30 4.9 140 73 155 23 17 8.4 11 56 23 98 14 24 85 27 23 21.5 18 18 18 18 21 80 2.6 2.05 4.4 15.0 0.4 trace 7.7 1.3 0.4 2.0 1.0 0.2 2.0 3.3 7.7 1.7 0.6 0.8 140 170 66 110 100 130 23 94 42 24 26 30 32 29 12 21 33 4.7 9.9 trace trace 53 14 87 6.0 4.7 3.0 1.0 1.2 little 1.3 1.1 trace 0.84 0.36 0.4 4.8 288 280 81 25 180 114 27 7.2 1.9 6.7 9.5 little ; 6.1 12 14 4.8 130 1.2 1.5 93 87 1.2 trace 5.9 39 1.2 14 2.2 152918- b Turbid. -11 162 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. Well No. Year. 69012 1909 74181 1909 121872 1916 118110 1914 42794 1907 47957 1907 53508 1907 109843 426 1912 58273 " 1908 124858 1028 1917 125022 1040 1917 57479 1908 1911 113638 489 1913 111547 472 1913 115332 513 1913 117442 531 1913 102056 389 1912 60640 1908 60639 1908 119411 374-A 1914 79649 146 1910 119934 726 1915 120042 746 1915 120162 764 1915 123598 772 1916 120815 813 1915 123596 830 1916 123599 880 1916 98259 1912 78903 165 1910 123030 1916 80288 180 1910 83352 215 1914 119058 659 1914 119172 678 1914 119505 684 1914 119623 708 1914 119742 718 1915 121719 869 1916 74811 131 1909 83799 201 1910 118396 611 1914 118686 631 1914 118813 646 1914 124592 1008 1917 124756 1025 1917 124930 1039 1 1917 Locality. (Province, town, barrio,) Depth of well. Capacity L per minute. Color. Meters, Liters. Bulacan, Hagonoy, Inchausti No. 1 Bulacan, Hagonoy, Inchausti No. 3 Bulacan, Hagonoy, Santo Nino Bulacan, Marilao Bulacan, Malolos, municipal well Bulacan, Malolos, provincial well . Bulacan, Meycauayan Bulacan, Norzagaray Bulacan, Obando do do Bulacan, Polo — -do Bulacan, Pulilan Bulacan, Quingua Bulacan, San Ildefonso__ Bulacan, San Rafael Bulacan, Santa Maria Bulacan, San Miguel de Mayumo, San Miguel Bulacan, San Miguel, San Jose Cagayan, Tuguegarao ___. Capiz, Capiz Cavite, Bacoor, Alima___ do ____ do Cavite, Bacoor, Maliksi do — _do__ Cavite, Bacoor, Zapote Cavite, Cafiacao Cavite, Caridad do Cavite, Imus do _ Cavite, Imus, Talipapa do do do Cavite, Imus, Medicion 1« _ do._ ___ Cavite, Cavite Cavite, Cavite? Cavite, Kawit, Santa Isabel ..___do , _ Cavite, Kawit, Binacayan ; Cavite, Maragondon , Cavite, Kawit -___do '_.. _.'. .. a Yellow. c Brown. 56 130 137 F 19 F 38 233 216 146 174 169 F 151 F 189 F 76 F 95 F 379 395 56.4 80.4 P 114 P 76 F 49 F 57 129.8 136.9 91.4 90.8 F 76 F 26 136 P 207 72 76 135.3 77.2 250.8 91.1 160 183 119 94.5 125 58. i 20 P 151 F 26 F 379 F 57, P 5 P 76 F 227 F 45 F 26 P 189 F 38, P 227 F 61, P ; F 23, P 379 F 34, P 227 P 144 P 150 F 114 INTERPRETATION OF WATER ANALYSES the .Philippine Islands-^ Continued. 163 >> >» Id < O u ? "5 < 02 o O GQ o 35 o u t— i "a" O .3 "3 o

• oO 03 0) W 44 1.25 14 10 100 425 50 36 0.25 43 21.5 290 140 260 nil 189 nil 340 60 0.2 11 1.8 33 nil 230 little 30 75 3 7 trace 17 8.6 162 15 880 610 250 820 230 260 34 40.5 27 18 28 23.0 0.5 0.6 1.6 1.2 1.6 0.13 45 23 1.6 26 2.0 2.2 25 14 trace 0.78 0.9 trace 420 160 15 440 24 15.0 9.6 3.0 nil trace trace nil 190 nil 16.8 200.0 trace nil 180 nil 270 220 17, 000 850 870 770 2,200 280 20.0 0.36 trace trace 18.0 12 8,100 16 420 387 760 18 16.8 180.0 trace 28 94 51 36 33 18 3.2 trace 10.4 3.2 6 157 23 29 11 33 3 210 3.0 2.0 trace 0.54 60 836 12 17 little trace 21 400 380 510 119 89 40 00 195 28 trace 71.5 11 nil 238 5.2 2,870 420 17 65 0.6 trace 30 21 0.87 1.0 1,500 80 250 nil 200 nil 240 8.0 220 2.4 435 90 0.7 12 6.0 46 nil 270 17 nil 220 365 80 nil 14 nil 20 trace 240 trace nil 240 410 86 0.10 4.1 1.0 16 ■ 6.7 290 <5.0 nil 225 400 85 trace 10 trace 22 nil 270 14 nil 220 520 94 0.35 11 5.4 80 nil 270 <5.0 nil 290 10.0 390 77 0.5 36 18 14 nil 350 <5.0 510 510 760 77 71 54 1.0 . 0.4 1.1 14 9.6 18.0 5.6 2.1 120 74.5 32 160 39 <10.0 340 nil nil 410 39 380 400 380 400 350 84 89 94 78 67 2.2 1.9 1.7 12 trace 37 40 8.3 38 25 14 trace 3.2 12.5 2.2 .9.6 12 18 9.2 29 39 70 11 12 205 nil 250 16w 5 nil 275 390 80 trace 36 15 11 nil 335 1.3 nil 275 440 72.5 trace 43 13 8.0 nil 335 8.0 300 372 78 0.8 50 10.5 7.2 nil 365 little 500 500 440 460 430 370 88 81 76 84 76 ... 130 1.6 trace 1.7 3.7 1.7 0.28 4.6 1.1 23 20 5.5 36 0.96 9.1 11 0.72 16 79 80 17 19 23 8.7 23 43 5.6 31 nil 240 19 nil 300 10 <5.0 290 9.8 470 90, 0.16. .12 3.8 34 nil 350 3 nil 290 6.5 450 70 0.20 t>T 29 . arbid. 10 19 nil 350 trace 164 PHILIPPINE WATER SUPPLIES Table XV.-— Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 124774 1023 1036 1044 147 599 604 617 135 562 574 585 590 479 503 517 527 532 552 182 274 289 313 433 457 474 844 855 892 901 921 376 831 1013 967 970 956 1018 473 ■ 1917 1917 1917 1910 1908 1914 1914 1914 1910 1913 1913 1913 1913 1913 1913 1913 1913 1913 1913 1910 1911 1911 1915 1912 1912 1912 1915 1915 1916 1916 1916 1912 1915 1917 1910 1909 1913 1913 1913 1914 1913 1916 1916 1916 1916 1917 1913 Cavite, Maragondon Meters. 21 58 38 49.7 Liters. P 106 P 106 P 106 P 57 nil nil nil 124866 124931 do _.__ _ do 77565 Cavite, Naic _ ______ 58756 Cavite, Novel eta, Manila R. R. Co 118166 do 93 97.2 34.4 116 94.5 97.5 93.3 83.5 178 158 52 11 166 113 184 55 77 92 247 99 76 82 93 95.4 128 107.6 90 62.2 17 F 45 P 379, F 95 F 11, P 227 F 19 F 23, P 379 F 38 F 76, P 379 F 45 P 57 F 23 F 76 F 57 P 170 P 303 F 114, P 151 P 68 P 76 P H3 F 4, P 189 F 38 F 114 F 57 P 114 P 114 F 114 P 76 P 227 P 76 P 19 00 («) nil nil nil nil 118262 Cavite, Noveleta, San Juan _ 118555 Cavite, Noveleta, San Jose __ 77981 Cavite, Rosario __ _ ' 117646 do _ 117808 do 117889 do 118002 Cavite, Rosario, Bagbag 112413 Cavite, San Francisco de Malabon 114008 do 114934 do.. 115333 do 116860 do 117443 80790 Cavite, San Francisco de Malabon, sitios of Bucal and Tejero. Cavite, San Roque 88873 Cavite, Santa Cruz de Malabon 88878 do _ 119961 107605 Cavite, Santa Cruz de Malabon, Amaya Cavite, Santa Cruz de Malabon ___ 109674 do 110193 do 121241 121464 Cavite, Santa Cruz de Malabon, Hulugan Cavite, Tanza 122018 do 122241 do ____ 122402 Cavite, Tanza, Jalayjay ___ 99397 Cebu, Argao _ 121013 Cebu, Asturias __ 124712 Cebu, Bogo 75585 Cebu, Cavit Island, quarantine station 71504 Cebu, Cebu, municipal well 117474 Cebu, Cebu, Calle Juan Luna 23 24 40 20 29 P P P 117475 Cebu, Cebu, Lapulapu 117476 Cebu, Cebu, near railroad station 118277 Cebu, Cebu, Bagumbayan 117478 Cebu, Cebu, Carbon public market P nil nil <5 nil nil 121877 Cebu, Cebu, customhouse __ _ 123124 Cebu, Cebu, Piza 26.8 26.5 26.2 33.8 P 265 P 114 P 265 F 114 P 227 123177 Cebu, Cebu ___ 123178 do ._ 124518 Cebu, Cebu, Mambalin _ 114822 Cebu, Dalaguete _ Brown, INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 165 >» 2d < O u Is "3 m IS "o m •a +■> o O 3 Ed | i Hi .2 bo 9 .5 o 03 fl'w oO a O CD £> oO s m O CQ nil 250 30 380 110 0.27 40 14 11 nil 310 trace 2 140 30 350 120 0.48 36 14 8.9 nil 170 nil nil 210 33 350 110 0.32 39 13 17 nil 260 trace 355 800 430 440 99 72 80 90 84 110 86 79 82 6.4 0.8 3.7 0.5 0.1 3.8 1.2 trace 0.5 30 67 31.5 25.5 21 38 35 34 31 9.1 12 8.1 2.95 9.1 11 7.2 8 9.4 trace 5.3 trace 22 11 trace 48 62 24 10 12 13 14 12 11 13 9.3 16 19 6.9 9.9 14 430 440 420 420 410 380 410 360 390 400 84 84 97 87 88 1.2 4.8 4.8 3.6 2 21 9.4 37 31 16 4.6 0.42 16 7.8 trace 20 17 9.4 14 20 410 515 400 390 340 88 86 81 79 95 8 1.6 2.8 1.4 trace 22 3.8 40 36 36 4.7 0.25 13 13 16 10 76 9.9 9.9 10 11 52 29 27 4 230 nil 280 420 410 370 430 430 88 81 88 82.5 81 4.8 2.4 2 0.55 0.55 13 32 32 50 58 4.3 11 12 16 9.6 22 14 6.9 15 14 29 30 12 260 230 nil nil 320 280 trace nil 260 nil 410 80 0.4 32 12 12 trace 320 12 235 16 380 110 0.36 39 13 11 nil 290 13.5 45 240 5.4 390 93 0.5 38 8.9 11 300 11 CO 520 620 28 15 3 2.4 33 25 20 9.6 120 130 63 6 300 nil 370 <5 190 5, 650 20 380 trace 0.20 94 21 15 2,800 21 9.6 91 6.9 38 18.1 200 nil 350 trace 450 400 760 390 470 540 895 44 0.8 53 14 trace ■ r ! 48 2.5 62 20 20 nil 430 nil 49 0.36 23 20 nil 530 47 10 290 20 440 33 0.30 110 14 8.2 nil 350 50 270 23 420 33 1.8 100 15 8 nil 350 40 nil 280 28 460 35 0.48 110 16 8 nil 340 60 30 320 14 480 53 3.1 80 23 8.7 nil 390 33 1,400 1 9.6 3.6 135 1 39 530 100 b Turbid. 166 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Labora- tory No. Well No. Year. 124427 1012 1917 91642 299 1911 97268 327 1912 119323 689 1914 120047 682 1915 123511 933 1916 110499 439 1912 113543 482 1913 107186 428 1912 108062 452 1912 109063 461 1912 110053 471 1912 111546 480 1913 115624 530 1913 115942 500 1913 115946 580 1913 115947 1913 118167 600 1914 117271 541 1913 117452 1913 117739 568 1913 118057 592 1914 122955 1916 94862 308 1911 117452 97 1913 115943 1913 85947 218 1911 119138 122 1914 123041 1916 123136 1916 123311 1916 67315 1909 120297 756 1915 120627 787 1915 93552 330 1911 93927 336 1911 94992 343 1911 94993 347 1911 121478 805 1915 97537 356 1912 118119 587 1914 119055 671 1914 122092 871 1916 115625 526 1913 116335 540 1913 116824 548 1913 105449 1912 119382 685 1914 Locality. (Province, town, barrio.) Depth Capacity of well, per minute. Cebu, Danao Cebu, Mabolo '.. do Cebu, Toledo do . Cotabato, Carpenter __ Ilocos Sur, Candon do Iloilo, Iloilo do _ _.__ do--. ■ do Iloilo, Iloilo, Molo Iloilo, Iloilo _ _...do Iloilo, Iloilo, Molo Iloilo, Iloilo, Ortiz Street Iloilo, Iloilo __-do Iloilo, Iloilo, customhouse Iloilo, Iloilo do ._., Iloilo, Iloilo, Lapus-lapus Iloilo, Janiuay „_- Iloilo, Jaro Iloilo, Manduriao Iloilo, Pototan Iloilo, Santa Barbara Iloilo, Iloilo, San Miguel road, km. ll._-_ Iloilo, Iloilo, km. 11.8 Iloilo, Iloilo, km. 12.5 Laguna, Los Banos (?), Bay Laguna, Bay .—.do Laguna, Binan __■ __ .___do Laguna, Cabuyao _ Laguna Laguna, Calauan Laguna, Calamba Laguna, Famy Laguna, Mabitac Laguna, Los Bafios Laguna, Lumbang do do Laguna, Pagsanjan, No. 39 Calle Blanco Laguna, Pagsanjan c Brown. a Yellow. Meters. 60.4 187 255 42.7 51.5 44.5 76 137 77 77 79 79 91 104 99 91 61 78.9 80.5 66 348 178 10.7 152 57.9 144.8 93 75 42 40 181 110 114 93.6 114.3 91 128 95 90.2 Liters. P 227 P 379 P 132 P 61 P 61 P 151 P 38 P 53 F 76 F 38 F 8, P 114 F 68 F 57 F 11 F 76 F 45 P 57 F 57 F 11 F 45 P 76 F 57 P 76 F 132 F 19 F 45 F 30 F 246 F 57, P 189 F 114 F 454 F 454 P 170 P379 F 68 F 114; P 265 P 57 F132 F227 F151 F606 INTERPRETATION OP WATER ANALYSES the Philippine Is lapds— ^Continued. 167 Turbidity (S1O2). 5 6 4J "5 3 in O Eh O ■ 3 W h u "a u If .5 O OS j3 •S 'u S, en a . 00 «3 CO go ^ prj ly*— • ' S 05 aS Xfl 8 410 nil 580 340 320 800 1,400 30 28 43 44 30 0.60 4 1.8 1.7 0.7 19 38 105 100 86 11 41 1.1 17 30 35 6 7.8 160 465 1,600 235 1,100 730 800 1,050 700 360 1,500 800 390 830 855 240 870 1,800 875 730 4,500 1,200 275 76 245 5.2 6.6 6.1 24 29.5 38 15 12 13 16.5 21 8.3 5.4 60 37 13 10 13 190 170 20.7 460 25 29 12 47 77 150 480 90 19 nil nil 580 110 1,400 2,500 2,200 2,200 2,750 2,150 1,500 3,300 2,200 1,600 ' 2,700 2,300 1,100 2,200 3,850 2,300 2,100 8,200 3,000 1,450 630 1,100 580 420 410 790 720 470 390 380 755 350 670 370 255 520 470 260 320 290 820 740 12 1.6 67 65 44.5 72 64 55 0.8 0.4 1.6 trace 9 4 1.6 8 4.8 13 120 120 230 100 83 70 1.4 8.2 30 56 96.5 48 48.5 77 15 51 6.6 5.3 15 18 49 trace 00 CO 54 27 56 52 61 41 25.5 58 1.7 trace 3.2 27 10 0.31 10 trace 130 6.4 140 280 120 160 45 18 4.4 88 170 58 70 37 18.5 trace nil trace trace trace 23 2.05 trace 10 740 38 nil 900 77 26 54 47 50 27 7.7 0.18 0.26 0.38 110 4.1 5 22 40 0.64 0.36 5 23 26 66 2.2 trace trace trace 5 nil nil 475 340 330 nil nil 18 6.2 nil nil 565 420 500 nil nil 640 460 85 80 97 93 87 92 110 83 76 82 110 78 84 79 trace trace 0.1 trace 2.2 0.8 2.3 2.2 1.7 0.5 5.2 3.6 0.8 0.8 93.5 36 36 33 37.5 0.28 38 39 31 13 17 21 26 21 34 22 15 17 18 19 29 19 2.1 32 5.7 4.3 5.3 nil nil 760 565 nil nil 11.5 5 5.6 7.5 nil 15 460 nil 560 1.6 4.9 nil nil nil 80.0 330 16. nil 360 72 trace 10 16 66.4 b Turbid. 168 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. Well No. Year Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 119655 119976 114448 58483 58575 111668 107603 110480 112984 122359 122949 119196 92745 94767 117609 117772 123562 124576 68197 68605 68956 68930 15434 32180 54050 58254 58797 101821 104361 115482 117875 118013 118752 108775 118904 119326 119426 121039 121450 122494 123753 118767 119182 119407 118644 112111 115133 117402 703 723 508 27 440 459 493 907 949 674 326 341 553 566 984 998 78 87 93 (?)518 410 484 501 515 1915 1915 1913 1908 1908 1913 1912 1912 1913 1916 1916 1914 1911 1911 1913 1913 1916 1917 1909 1909 1909 1909 1905 1906 1907 1908 1908 1912 1912 1913 1913 1914 1914 1912 1914 1914 1914 1915 1915 1916 1916 1914 1914 1914 1914 1913 1913 1913 Laguna, Pagsanjan Meters, 70.7 133.2 155 Liters. F 76 P265 F322 Laguna, Pagsanjan, Buboy Laguna, Pila Laguna, Santa Cruz, No. 1 __ Laguna, Santa Cruz, No. 2 Laguna, Santa Cruz .._ 175 194 175 170 193.2 110 137.5 108 64 121.9 121.9 144.8 107.9 52 F757 F L02 F 1, 325 F927 F53 F379 F 64 F 38 F189 F151 F151 F 19; P 45 F 23; P 76 00 (*) 00 3.0 nil .....do .. do .... do do Laguna, Santa Cruz, Gated ... Laguna, Santa Maria__ Laguna, San Pedro Tunasan Laguna, Santa Rosa _ Laguna, Siniloan . do Leyte, Baybay __ .. <5.0 a nil 00 do .. Leyte, Carigara Leyte, Carigara, Sawang Leyte, Carigara ._ _ 69 52 do ... . Manila, Singalong farm Manila, Isla del Provisor 122 Manila, Manila railroad station ... . _ Manila, Corregidor Island-. _ 107 F265 Manila, Manila railroad station ___. Manila, Santa Cruz, No. 12 (int.) Misericordia . Manila, Sanitary Steam Laundry Manila, San Miguel, Calle Aviles Manila, No. 133 Calle Principe do (?) _ Manila, St. Scholastica's College.. _ ___ Manila, San Miguel Brewery Manila, Philippine General Hospital grounds. Manila, No. 1338 Juan Luna Manila, Insular Ice Plant 229 do 15.0 nil nil nil Manila, 1001-1023 R. Hidalgo Manila, Germinal Cigar Factory ... Manila, Bureau of Science grounds Misamis, Agusan, Cabadbaran _. do Misamis, Cagayan __ 131 167.6 50.6 93 192 P568 P227 do_ _ Mountain, Camp John Hay _. Mountain, Tagudin.. P 57 F 19 do__. _ ' INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 169 >> •So cs a 5 I is '3 m CD o EH O 3 33 fa 8 S-l "c3 O | o 8 o .5 'u o m -p aJ . oO a O CO O 4-> • oO Tur 80 80 73 76 72 90 110 98 94 62 70 38 93 100 40 54 55 35 110 110 0.1 0.4 trace 2.4 4.0 2.0 4.4 1.6 2.0 1.4 0.28 16 trace trace 3.2 4.4 1.0 0.66 2.0 4.0 21.5 82 17 15 21 37 28 29 35 19 20 61 50 44 17 24 37 34 270 340 8.7 83 12 9.4 16 8.9 5.1 5.1 6.3 7.5 12 26.5 10.0 15 5.3 4.3 14 25 62 90 41 160 5.4 5.5 20 20 24 20 20 62.5 9.1 280 6.9 16 17.5 13 310 300 35 36 39 43 190 nil nil 190 640 25 14 trace nil trace 7.7 9.0 trace trace trace trace 360 16 17 nil trace nil trace 10 16 50 <5.0 430 180 16 nil nil 520 220 5.0 20 220 220 4.6 nil nil nil 270 270 0>) oo- trace 55 35 71 22 trace 0.40 1.6 2.8 0.4 13 46.5 57 51 1.7 trace 0.72 23 24 trace 165 108 28 trace trace 870 86 00 31 35 50 100 65 7.0 11 trace trace 150 210 30 160 32.5 34.5 35 57 69 2.4 1.9 440 30 2.5 390 400 • Green. 25 62 66 26 31 43 13 50 22 74 10 70 40 22 20 bid. 8.6 trace 1.7 trace trace 0.3 trace 1.5 1.7 16 10 22 5.2 trace trace 19 5.5 6.9 1.8 3.0 6.4 4.6 6.9 17 14 20 2.6 19 2.9 7.1 11 trace 2.1 nil trace trace trace 0.4 6.4 11 33 17 2.1 0.78 trace € 67 114 3.3 20 66.5 38 130 120 150 11 0.6 6.0 nil trace nil % . nil nil 10.0 68 70 48 75 290 nil nil 18 15.5 8.9 14 83 49 26 73 320 (*>) 460 nil 560 170 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. 118958 120313 120867 122810 94613 119531 119755 120056 123431 124253 119074 119257 119595 79220 82585 120303 121120 121502 121834 119699 119843 119897 120018 122083 122646 123512 120603 124519 118529 118597 118654 118687 118905 118906 119186 119187 119188 122972 122872 122871 121000 122126 122858 122859 122366 123492 122973 122367 Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 613 769 788 908 317 691 716 731 959 992 662 677 687 179 214 762 821 848 864 711 724 737 749 884 887 947 789 1009 597 629 633 634 635 650 653 661 664 945 937 954 752 825 883 889 897 909 915 919 1914 1915 1915 1916 1911 1914 1915 1915 1916 1917 1914 1914 1914 1910 1910 1915 1915 1915 1916 1915 1915 1915 1915 1916 1916 1916 1915 1917 1914 1914 1914 1914 1914 1914 1914 1914 1914 1916 1916 1916 1915 1916 1916 1916 1916 1916 1916 1916 Nueva Ecija, Aliaga . _ _ Meters. 142.3 129.8 157.9 175.6 189 185.3 138.7 136.9 222.5 138.7 132.6 110.9 170.1 25 24 Liters. F 42 F151 F 170 F 45 F284 F45 F132 F151 F23 F26 F95 F151 F8;P151 P76 P132 : nil nil nil 00 do _ do . do Nueva Ecija, Cabanatuan __ _ do do . Nueva Ecija, Cabanatuan, Mayapyap Nueva Ecija, Cabanatuan _ _ do _ __ Nueva Ecija, Cuyapo —..do do _ Nueva Ecija, Gapan___ do do do 146.3 107.3 99.1 92 102.7 32 107 114.9 182.3 213.4 128.6 101.2 164.0 33.5 43.9 36.9 30.5 28.3 27.4. 58.2 84.4 136.9 79.2 75 16.2 4.3 32.6 59.4 20.1 42.7 33.2 29.6 F114 F 19 F45 F473 F530 F76 F379 F 95 F114 Fll F30 F34 P151 P76 P265 P 76 P 114 P 76 P 76 P 57 P 95 F11;P284 P 132 F 19 P 76 P 212 P 76 P 76 P 76 P 114 P 189 nil nil nil nil nil nil nil ( e ) dnil nil nil nil nil nil nil nil d5.0 Nueva Ecija, Gapan, Baluarte Nueva Ecija, Gapan, Santo Cristo Nueva Ecija, Nampicuan do do. Nueva Ecija, Nampicuan, Alemania __ Nueva Ecija. Quezon. _ __ Nueva Ecija, San Antonio _ do Nueva Ecija, San Isidro, Pulo Nueva Ecija, Zaragoza. __ Occidental Negros, Bacolod___ do do __„ do do do . do Occidental Negros, Bacolod, Tangut ___ Occidental Negros, Bacolod, Sumog. Occidental Negros, Binalbagan ____ — Occidental Negros, Cadiz -__ _. do . Occidental Negros, Escalante do _.__ Occidental Negros, Hinigaran, Narauis Occidental Negros, Hinigaran, Paticui Occidental Negros, Hinigaran do _ _ _ Occidental Negros, Isabela do c Brown. d Filtered. INTERPRETATION OF WATER ANALYSES the. Philippine Islands — Continued. 171 >> -p il 1 3 >> -p . '.So ~o < O o "5 < 22 "o en !$ o H O m 'a Q Is ;S o bo 8 CD .s 'u O 3 o CD oo «o o3 U 05 go s ■P , j 03-^ ! ^O Xfl 200 210 22 19 0.3 trace 3.8 7.2 1.0 trace 7.0 9.0 12 170 nil nil nil 160 nil 150 210 12 trace 7.0 trace 20 trace 190 6.0 nil 135 nil 180 9.0 0.33 4.5 trace 9.4 11 140 trace 240 200 23 15 trace nil 3.1 5.0 0.48 nil 29 15.5 19 2.1 130 nil 70 nil 115 210 15 nil 1.7 nil 24 nil 140 2.0 110 205 16 4.5 2.0 30 13 95 9.2 <5.0 190 nil 240 17 0.36 2.1 0.7 11 21 190 trace nil 160 nil 230 15 0.10 2.9 trace 18 21 160 trace 270 370 380 3.7 36 45 1.7 3.7 trace 18 30 23.2 2.95 8.2 5.5 3.2 1.0 8.2 nil 8.9 1.0 nil 220 nil 270 570 320 275 55 60 20 3.2 1.8 trace 100 58 3.5 21 16 trace 76 11 15 35 4.4 trace nil 200 24 240 200 280 20 0.2 7.1 trace 12 8.9 230 120 180 370 13 0.4 7.1 trace 58 trace 220 trace nil 220 300 19 0.2 little trace 27 12 270 trace (o) 260 380 27.5 trace 14 5.0 10 nil 320 6.0 nil 255 365 30 nil 7.0 2.2 10 nil 310 trace nil 250 435 45.5 nil 39 23 34 nil 305 14 nil 225 350 - 16.5 trace trace 7.5 32 nil 270 12 nil 180 nil 245 27 0.44 2.1 trace 11 5.9 210 4.5 nil 240 nil 355 15 0.35 10 trace 22 11 290 8.0 nil 270 nil 360 23 0.52 4.0 trace 9.7 21 290 trace nil 175 265 22.5 trace 7.2 trace 18 36 210 21 nil 180 nil 420 23 0.36 6.8 trace 21 17 190 6.1 320 240 240 250 270 290 260 320 360 100 100 120 7.7 1.7 9.7 20 15.5 8.3 9.5 7.3 0.06 9.0 65 6.4 3.0 6.5 4.0 5.4 3.8 29 1,700 10 4.2 330 trace 100 110 88 100 100 0.3 1.7 7.7 24 1.7 20 20 11 11 21 22.5 19 5.6 5.6 24 43 2.0 9.7 (*>) nil 29 150 <10 310 210 24 5.0 nil nil 370 260 310 74 1.1 30 18 trace 5.0 210 5.0 310 58 1.2 33 16 10 nil 260 13 325 545 20 1.2 140 19 34 nil 400 14 nil 340 16 445 12 0.24 110 11 16 nil 410 trace 10 390 14 790 72 0.64 12 11 125 nil 480 50 nil 270 5.0 550 90 0.98 little trace 70 nil 330 21 70 320 16 58 2.1 66 29 365 385 trace 60 250 4.6 760 50 0.70 37 40 230 nil 310 trace 300 120 24 | 215 ! 45 10 27 8.3 7.3 nil 150 <1.0 high 120 10.7 ' 250 1 92 4.2 26 7.2 12 150 trace b Turbid. : Green. 172 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. Well No. Year. 122974 931 1916 122975 936 1916 122976 943 1916 120931 771 1915 121853 776 1916 120932 778 1915 120933 790 1915 120934 801 1915 121420 807 1915 121421 808 1915 121422 816 1915 121423 817 1915 121424 818 1915 121425 823 1915 121854 827 1916 121426 828 1915 121855 833 1916 121427 834 1915 118094 538 1914 122127 858 1916 111866 462 1913 119185 594 1914 119977 707 1915 120598 795 1915 120597 796 1915 119907 733 1915 119991 734 1915 120137 740 1915 120136 741 1915 120928 745 1915 120929 750 1915 120930 759 1915 121654 851 1915 121728 867 1916 122336 875 1916 122024 893 1916 122118 900 1916 122257 905 1916 122288 918 1916 119102 621 1914 123354 969 1916 123821 987 1916 123822 994 1916 119090 654 1914 118410 588 1914 118478 620 1914 121056 829 1915 1 121653 842 1915 Locality. (Province, town, barrio.) jjeptn capacity p , of well, per minute. ool °r Occidental Negros, Isabela do __._ __ .— .do Occidental Negros, La Carlota _ do .do_ -do. _do. _do. -do. -do., .do. _do_ .do . _do. _do_ ..do _ Occidental Negros, La Carlota, Tabao Occidental Negros, Murcia Occidental Negros, Sagay Occidental Negros, San Carlos do „._. do ;___. Occidental Negros, San Enrique. do Occidental Negros, Valladolid, Pulupandan_ Occidental Negros, Valladolid, Paloca Occidental Negros, Valladolid do do do do Oriental Oriental Oriental Oriental Oriental do .. do - Oriental Oriental Oriental Oriental Oriental Oriental do__ Oriental Oriental a Yellow. Negros, Negros, Negros, Negros, Negros, Ayuquitan Ayuquitan, Amblang _ . Ayuquitan Ayuquitan, Tandayag.. Ayuquitan Negros, Negros, Negros, Negros, Negros, Negros, Bacong Bais_-_ _ ._ Bais, Cambagroy. Bais, plaza__ Dauin Dumaguete Negros, Negros, Sibulan Sibulan, Bolocboloc . Depth Meters. 30.5 ?26.2 27.4 46.9 . 50 43.3 33.2 14.3 19.8 35.7 33.8 16.5 46.3 33.5 13.7 20.4 18.3 17.7 209.4 158.5 139 245.4 198. 1 22.6 22.9 19.5 21.9 28.3 22.3 40.5 32 58.2 32.6 40.5 43.9 42.1 26.2 150 80.5 56.4 77.7 65.5 141.7 6.7 71.6 48.8 Capacity Liters. P 227 P 227 P 76 P 61 P 68 P 57 P 68 P 246 F 26 P 95 P 76 P 303 P 61 P 45 P 322 F 34 P 379 P 284 P 95 P 76 F 57 P 114 P 38 P 76 F 38 P 76 P 95 P 95 P 76 P 95 P 95 P 201 P 227 P 114 P 265 P 132 P 136 P 95 P 95 P57 P76 P76 F151 F 1, 136 P38 P38 ; Brown. INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 173 >> -p >> -p . Id < O o 1 "5 < o O 3 o W "a? a o 1$ O If .2 'o bo eg 5 o '§ 2 Q Cm m §6 m 00 150 120 24 230 100 2.4 28 4.7 8.2 nil 150 1.4 300 130 29 300 100 6.4 35 6.3 28 nil 160 trace 100 170 14 280 70 2.8 43 8.7 8.5 nil 210 nil 00 225 375 65 2.4 39 15 6.5 nil 270 21 00 219 9.0 330 88 4.3 75 13 .7.2 nil 270 23 nil 190 335 80 1.5 29 16 6.0 nil 235 16. 5 00 210 355 65 2.4 39 17 7.0 nil 260 16.5 nil 190 325 70 0.3 21.5 12 13 nil 235 12 220 350 91 0.25 46 16 7.2 nil 270 14 (b) 200 335 79.5 2.8 35 16 nil 250 13 1 (b) 190 310 81.5 2.2 19 11 7.2 nil 230 13 (b) 300 96.5 1.1 34 13 5.15 nil 230 trace (b) 200 310 80 2.8 31 15 7.2 nil 240 trace . (b) 190 305 86 1.7 34 16 6.2 nil 230 trace 00 159 13 260 110 1.0 130 16 5.1 nil 194 trace 175 310 100 0.4 34 12 9.3 nil 210 trace nil 194 4.3 330 94 0.6 19 11 12 nil 240 trace 200 350 82 0.7 13 20 14 nil 240 16.5 ; < b > 20 160 650 46.5 12 4.5 2.6 17 16 10 5.7 11 62 6.2 42 410 nil 12 480 310 360 330 37 14 30 3.2 1.7 trace 19 1.2 trace 3.37 nil trace 7.9 32 10 26 16 trace nil 250 nil 260 nil 185 315 90 trace 23 11 12.5 nil 230 trace , nil 190 320 82.5 trace 29 11 15 nil 230 trace nil 360 2,600 70 0.8 25 42 1,020 nil 440 220 nil 245 400 90 trace trace trace 3.0 340 12 * nil 250 1,200 80 trace 12.5 24 372 nil 300 110 00 180 360 90 trace 26 11 17 nil 220 45 nil 220 585 70 0.6 14 7.6 84 nil 270 41 nil 200 415 80 1.8 21.5 13 14 nil 240 51 nil 210 390 70 1.5 25 11 16 nil 260 12 270 500 84.5 0.55 102 17 45 nil 330 12 130 460 34 0.7 trace 7.4 140 17.0 140 33 5.0 180 16 2,400 64 0.4 110 51 1,109 225 100 nil 114 nil 340 38 0.32 trace little 60 nil 140 trace 50 274 nil 500 58 5.4 32 60 58 nil 330 35 100 210 27 330 80 2.04 53 17 11.5 nil 260 10 280 590 42 0.6 trace trace 83 12 340 49 250 260 100 28 12 0.48 17 27 4.3 7.0 4.3 7.5 23.64 22 10 190 nil nil 240 <20 250 nil 960 30 2.0 56 30 340 nil 300 42 10 220 nil 430 22 0.48 27 14 87 nil 270 15 00 388 2,320 100 22 3.7 1.7 40 150 8.7 93 40 1,030 6.9 60 64 160 220 740 100 60 1.7 trace 18 60 4.0 14 16 37 160 nil 192 , " 69 370 *>Tu 100 rbid. 0.7 40 12.5 47 Filtered nil 85 60 174 PHILIPPINE WATER SUPPLIES Table XV— Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 119409 117541 117565 61055 111327 113697 -48270 61945 62810 62811 113343 106871 108533 48268 61343 48269 59529 59530 119337 116861 48263 48214 48312 43673 48210 59195 59955 72249 70464 70464 64527 64528 67353 68471 69116 72964 39318 58527 61056 121974 106337 118044 121049 121506 121937 119437 85906 676 525 470 492 434 450 519 ("A") ("B") 853 415 535 832 837 870 655 226 1914 1913 1913 1908 1913 1913 1907 1908 1908 1908 1913 1912 1912 1907 1908 1907 1908 1908 1914 1913 1907 1907 1907 1907 1907 1908 1908 1909 1909 1909 1909 1909 1909 1909 1909 1909 1907 1908 1908 1916 1912 1914 1915 1915 1916 1914 1911 Oriental Negros, Zamboangnita _ _ Meters. 42.7 Liters. P303 Palawan, Iwahig- Penal Colony do Pampanga, Arayat, Santa Ana _ 139.9 P95 (<0 Pampanga, Arayat_ _ __ 157 183 P303 P189 do Pampanga, Bacolor _~_ Pampanga, Bacolor, Tinajero __ _ Pampanga, Bacolor, Cabetican _ 00 Pampanga, Bacolor, Cabalantian _. Pampanga, Bacolor ___ _ _ _ _ Pampanga, Candaba ___ _ 91 102 F 189 P 189 00 do Pampanga, Guagua _ . Pampanga, Guagua, Betis _ _ __ _ __.. _ 00 Pampanga, Lubao _ Pampanga, Lubao (B. Legarda's) _ _ do Pampanga, Lubao ___ __. _ 00 1 Pampanga, Mabalacat ___ __ _ P95 F227 F13 Pampanga, Macabebe_ _ _ Pampanga, Mexico Pampanga, Minalin __ _ __. Pampanga, San Esteban, hacienda (provin- cial well). Pampanga, San Fernando (municipal well) F38 do Pampanga, San Fernando, San Jose Pampanga, San Fernando, at new market _ _ Pampanga, San Luis, at market Pampanga, San Luis, Santa Cruz_ __ . 00 Pampang-a, Santa Rita, San Jose _ _ Pampanga, Santa Rita, San Matias Pampang*a, Santa Rita, San Isidro Pampanga, Santa Rita, Santa Monica. _ Pampang-a, Santa Rita, San Vicente Pampanga, Santa Rita, San Juan__ __ _ Pampang-a, Santo Tomas do _ Pampang-a, Sexmoan___ Pang-asinan, Aguilar 31.4 182 93.3 24.4 61.3 102.4 229.2 117 F 8; P 76 F568 P379 P227 P. 114 P76 P38 F6;P95 nil nil nil nil .00 Pang-asinan, Alcala _ Pangasinan, Asingan ___ do _ Pang-asinan. Asingan, Macalong _ Pangasinan, Asing-an Pangasinan, Balungao Pang-asinan, Bay ambang c Brown. * Yellow. INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 175 >> -P . is 5 O o < W -p O O g o w 8 5-i 'is o .3 'o bo as p 5 2 on a> •P oo 03 Q CO §6 5-i H-< M * -P . P.CO w nil 240 28 410 290 390 550 450 570 650 520 280 400 420 1,200 1,000 310 390 380 310 250 359 430 230 1,020 420 470 490 400 280 480 260 250 250 290 260 320 465 240 495 510 230 270 260 210 250 515 810 90 trace 22.5 5.4 4.2 , trace 11.5 7.2 12 19 14 30 42 36 8.3 6.0 8.8 305 250 3.5 nil 120 20 nil 1.7 _ 50 1.2 25 80 (b) 100 110 90 2.4 2.4 0.6 12 6.3 3.6 7.5 1.6 0.9 14 30 nil 90 75 80 1.6 1.6 2.8 3.4 5 11 trace 0.18 12.5 280 19 trace 80 90 83 80 90 40 80 .30 0.8 2.0 0.8 1.7 6.4 1.0 1.4 1.8 2.6 24 23 2.6 25 17 1.8 13 1.9 12 11 0.78 10 3.4 1.0 1.4 1.9 faint faint nil 20 1.5 2.8 0.66 9.7 4.2 58 34.5 9.2 135 55 30 20 10 13 32 11 6.8 7.6 8.2 8.7 8.5 4.4 8.0 16 36 20 12 14 11 15 220 360 80 0.6 3.4 1.4 2.6 40 4.0 13 2.0 185 20 90 72 nil 70 40 70 30 40 100 35 50 3.3 0.6 7.7 trace 0.5 1.1 trace 4.6 trace 5.0 41.5 62 60 27 21 50 trace trace 4.2 12 trace 5.0 1.2 5.8 47 88 189 17 76 18 trace ' 9.0 ; 24. 5 13 45 157 110 120 40 nil nil nil nil nil 190 130 150 50 b Turbid. 176 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 86306 69857 80060 123771 115144 121022 94707 68617 60753 . 67973 117520 121956 64008 64559 114821 116862 124905 91192 119637 119936 120889 93693 119676 119721 123785 120464 120615 120907 120974 121064 121240 123128 120789 118045 119079 122065 122240 123129 123122 69625 92450 122537 105444 122189 123216-A 123393 124577 259 181 521 824 335 80 75 556 39 486 533 310 698 727 811 328 714 722 761 803 810 835 840 845 962 782 558 602 898 902 923 940 90 325 927 408 899 975 985 991 1911 1909 1910 1916 1913 1915 1911 1909 1908 1909 1913 1916 1909 1909 1913 1913 1917 1911 1915 1915 1915 1911 1915 1915 1916 1915 1915 1915 1915 1915 1915 1916 1915 1914 1914 1916 1916 1916 1916 1909 1911 1916 1912 1916 1916 1916 1917 Pangasinan, Bayambang Meters. 30.5 Liters. F 1,893 Pangasinan, Bautista (property of Matias Gonzales) . Pang-asinan, Bautista _ 00 75 112.8 82 52.4 120 58 125 67 68 F38 Pangasinan, Bautista (property of Y. Sontua) _ Pangasinan, Binalonan nil P454 P95 F 132; P 265 F189 do Pangasinan, Binmaley Pangasinan, Calasiao Pangasinan, Dagupan do F568 F227 do do ___. nil Pangasinan, Lingayen 198 F189 do do 268 166 F757 F170 (») do Pangasinan, Lingayen, capitol site _ Pangasinan, Malasiqui 91 133.8 119.8 19.8 32 53.3 48.8 107 31.7 32.6 36.6 25.9 21.3 29 25.6 27.7 107.6 220.7 47.6 85.6 256.6 114.6 132 35 29.3 137 29.3 29.6 28 33.2 P946 P227 P170 F284 F322 F 283. 9 do Pangasinan, Manaoag.__ Pangasinan, Manaoag, Pan _ Pangasinan, Mangaldan do do do nil Pangasinan, Mangatarem. _ P227 F227 P227 P227 F151 P284 F114 P189 P379 P227 F57 F379 F38 F 76; P 95 do_.__ __ do do do-__ .__ nil nil nil do Pangasinan, Natividad Pangasinan, Pozorrubio Pangasinan, Rosales do__ _.. Pangasinan, Salasa nil " nil <5.0 nil do _ ___ Pangasinan, Salasa, Samat Pangasinan, Santa Barbara, „ Pangasinan, San Carlos Pangasinan, San Fabian F606 F170 F95 P61 P95 P95 do.__ ____ nil Pangasinan, San Jacinto Pangasinan, San Manuel 5.0 nil Pangasinan, San Nicolas — __do„_ __ Pangasinan, San Quintin a Yellow. c Brown. INTERPRETATION OP WATER ANALYSES 177 the Philippine Islands — Continued. 51 Eh >> 3 O o is '5 < m m O 3 AS b p "e3 O .5 5 .5 O in 0) eu . fi'S SO m a) s Wl am GO 310 280 260 730 33 1.4 10 3.9 50 32 22 240 30 00 72 40 0.8 0.56 4.1 24 slight 2.4 23 60 112 160 nil nil 200 225 250 34 15 little 2.5 1.5 6.2 36 25 150 nil 18 800 350 120 270 2,300 1,500 48 80 40 26 50 40 8.7 0.4 0.8 0.2 4.8 0.28 18 11 6.0 11 92 36 5.7 * 1.4 0.72 0.66 38 23 140 23 120 3.6 1,100 605 15 trace trace 28 26 12 00 nil 400 5.3 nil 490 600 780 1,240 595 1,900 790 690 18 23 45 50 3.2 2.6 3.2 2.0 17 29 70 24 1.9 2.5 3.9 little 230 360 600 180 900 11 250 trace 8.6 0.24 trace 60 50 1.8 1.0 93 35 24.7 11 60 trace 00 210 nil 260 nil 115 320 60 nil 13.5 trace 74 nil 140 23 nil 280 400 50 3.0 67 16 12 nil 345 10 760 440 38 35 1.8 trace 12 29 6.4 3.4 160 29 22 21 nil 220 nil 268 nil 240 440 25 trace 28 9.0 34 nil 290 17 5 180 nil 450 47 0.16 16 1.3 150 nil 220 32 nil 195 275 50 trace 36 35 19 nil 240 nil nil 180 230 50 trace 21.5 33.0 13 nil 220 nil nil 165 270 45 trace 45 35 9 nil 200 trace nil 230 320 52 trace 68. 33 14 nil 280 6.2 173 290 47 trace 33 33 27 nil 210 23 160 220 60 0.15 17 31 10 nil 195 trace 5 90 10 140 35 0.60 20 7.7 3 nil 120 trace nil 235 350 45 3.0 70 15 5.5 nil 290 20 320 190 260 34 18 46 1.7 1.7 0.62 55 8.3 85 14 6.9 21 11 7.3 11 6.4 nil 40 nil 200 nil 240 nil 210 nil 400 30 0.16 17 5.0 70 nil 255 9.4 50 10 60 150 nil nil 1,700 14 nil nil 70 180 290 35 0.4 20 3.1 <5.0 1,440 250 190 730 3.0 5.8 40 23 2.4 0.34 56 64 4.8 6.6 33 46 5 170 nil nil 210 270 290 33 93 4.4 3.5 45 45 4.2 4.6 1.5 16 38 27 130 110 5.3 nil 130 <5 130 9.2 170 27 0.26 28 2.1 4.5 nil 150 trace <5 110 4.6 160 29 0.36 27 10 5.2 nil 130 <5.0 35 120 nil 200 38 0.92 28 urbid. 10 5.2 nil 140 11 152918- 178 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. Color. 108254 117102 106814 122783 122948 124859 124962 118174 118300 118411 118617 118746 118812 119057 87525 88594 94089 93776 96857 97143 117570 117683 117992 112549 113818 121664 122139 122360 122538 122698 123053 123195 123457 123617 124449 124586 118055 119335 119548 122113 122190 122389 122539 122736 122890 119614 119692 119334 445 516 403 920 958 1021 1043 598 605 614 630 637 642 645 257 283 323 302 565 570 557 447 504 894 910 928 941 951 965 983 993 1014 1019 105 683 695 895 906 916 925 938 950 546 720 520 1912 1913 1912 1916 1916 1917 1917 1914 1914 1914 1914 1914 1914 1914 1911 1911 1911 1911 1912 1912 1913 1913 1913 1913 1913 1916 1916 1916 1916 1916 1916 1916 1916 1916 1917 1917 1914 1914 1914 1916 1916 1916 1916 1916 1916 1914 1915 1914 Pangasinan, Santo Tomas_ __ _ _ Meters. 142 179 98 148.1 33.5 128 36.6 77.7 84.7 71.3 31.7 40.8 29.9 72.5 302 174 Liters. F61 F61 F76 P57 P114 P76 P95 F95 F57 F341 F76 F265 F190 P227 P379 P681 nil a nil nil nil do . __ Pangasinan, Sual _. Pangasinan, Tayug _ . ... _ do _ Pangasinan, Umingan Pangasinan, Umingan, San Leon Pangasinan, Urdaneta do _ „ Pangasinan, Urdaneta, Mabini __ _- Pangasinan, Villasis do Pangasinan, Villasis, San Blas___ . Pangasinan, Villasis __ __ Rizal, Alabang do Rizal, Alabang, stock farm («) Rizal, Antipolo . __ _ 78 246 P189 P76 do Rizal, Antipolo, magnetic station ._ _ __ Rizal, Antipolo __ _ 19.5 11.9 96 223 94 P132 P151 P132 P379 P189 5.0 nil nil nil nil nil nil anil nil nil nil nil nil nil nil nil nil do do „ Rizal, Binangonan . _._ __ do _. „__ . Rizal, Binangonan _ . . 40.8 84.4 72.8 73.1 30.5 55.5 34.8 42.7 45.4 61 218 204.8 182.3 123.4 86.9 87.5 71.6 65.5 92.4 19.8 31.1 163.1 d. P57 P76 P57 P57 P38 P76 P57 P151 P38 P38 F76 F 15; P 76 F95 P76 P76 P76 P76 P189 P132 P114 P114 P57 do do do____ do do do do ._„ : Rizal, Cainta _ Rizal, Cainta, Santo Nino Rizal, Caloocan do _ __ do _ Rizal, Caloocan, Balintauac Rizal, Caloocan- do do do Rizal, Caloocan, Kaypascuala _ _ Rizal, Cardona do Rizal, Jalajala _ __ _ c Brown. <* Filtere INTERPRETATION OP WATER ANALYSES 179 the Philippine Islands — Continued. >> Eh JH CO .So 5 O O x> is '5 < 'o CD o O 3 P W o O la "3 O bo .s 'u £> o xn O "S . oo O Bicarbonates (HCOs). CO -p . CO 275 310 820 230 63 80 70 40 1.0 0.8 1.6 0.75 34 26 105 10 6.6 4.3 23 2.0 15 4.7 265 9.0 21 nil 45 trace 20 170 2 5 nil 200 180 150 9.5 230 80 2.0 33 10 5.5 nil 180 trace 20 130 nil 250 22 1.1 9.8 0.55 22 5.6 150 19 10 240 6 290 35 0.40 45 13 3.4 nil 290 nil 270 265 270 230 250 250 240 410 80 85 85 42 40 3.7 3.7 0.5 nil 1.7 31 30 30 35 33 2.5 3.4 0.06 24 15.0 16 17 9.2 9.7 9.7 14 17 34 31 16 12 40 90 3.7 1.8 34 34 5.2 9.4 25 16 440 440 200 465 230 300 80 90. 120 80 50 120 3.6 trace trace 6.4 trace 4.0 27 28 16 60 70 28 5.7 6.5 3.5 18 trace 5.0 27 30 8.9 80 7.0 14.0 21 2.4 3.8 17 25 4.3 (b) 190 230 4.0 3.0 110 0.9 20 6.3 2.5 470 70 1.4 30 28 63 13 <>) 460 90 trace 50 2 35 70 80 trace 185 25 3.0 trace trace 35 nil 100 21 20 310 16 645 40 0.84 70 35 70 nil 380 45 55 300 27 520 100 1.7 30 16 56 360 trace 7 270 9.3 480 44 0.42 30 28 70 nil 340 8.3 nil 300 4.6 430 40 0.38 30 27 38 nil 370 8.4 5 365 70 465 90 0.32 60 31 12 nil 445 <5.0 10 290 4.6 410 70 0.50 30 30 25 nil 360 <5.0 20 210 35 360 100 0.70 44 10 10 nil 260 4.4 5 170 9.0 580 100 0.40 45 9.0 37 nil 210 160 <5 210 14 730 100 0.56 140 11 140 nil 260 93 nil 180 4.6 730 90 nil 80 24 160 nil 220 110 320 40 8.6 4.4 trace 10 12.0 250 24 300 325 45 20 nil nil trace 3.6 trace 1.1 17 13 2.3 13 nil 185 nil 170 35 150 nil 240 37 2.4 4.2 1.0 10 12 160 17 00 140 nil 190 22 0.26 5.1 trace 4.0 18 170 trace 55 170 250 42 1.0 2.3 trace 5.7 50 150 trace 6 230 nil 290 26 0.92 33 11 6.3 nil 280 trace 5 230 nil 300 47 0.50 44 13 5.6 nil 280 trace 10 200 nil 260 38 0.72 20 4.8 4.7 nil 240 <5.0 (*>) 225 765 130 1 70 23 103 nil 270 65 <») 225 450 80 1 64 20 30 nil 270 41.0 (6) 1,130 275 30 b "p 400 urbid. 18 50 18 180 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Labora- tory No. Well No. 119513 701 120595 791 120764 806 86881 1 86881 2 123525 386 123597 392 50515 1 40608 2 59533 (i) 54655 6 57372 7 61809 8 67895 9 70116 10 68960 114443 512 115193 524 116336 534 117175 547 117532 561 117673 569 118666 627 118863 649 119028 665 119122 675 124906 72622 74671 1 74672 2 74673 3 74674 6 74675 7 112498 406 112499 423 113542 498 117553 448 117554 502 117555 546 121238 826 121540 850 121687 868 121908 876 65576 116467 117895 579 Year. 1914 1915 1915 1911 1911 1916 1916 1907 1907 1908 1908 1908 1908 1909 1909 1909 1913 1913 1913 1913 1913 1913 1914 1914 1914 1914 1917 1909 1909 1909 1909 1909 1909 1913 1913 1913 1913 1913 1913 1915 1915 1916 1916 1909 1913 1913 Locality. (Province, town, barrio.) Depth of well -do. _do. _do. Rizal, Las Pifias — San Pedro Tunasan road, Camp Gordon. Rizal, Las Pinas — San Pedro Tunasan road, Camp Hyson. Rizal, Las Pinas, poblacion... _ Rizal, Las Pinas, Pamplona Rizal, Fort William McKinley _ do do do ,.-_do do do do .. Rizal, Malabon do do_.__ do ._ _ Rizal, Malabon, Julong-Duhat __ Rizal, Malabon, Panjulo_,_ Rizal, Malabon _ _ do ■__„ _ ____ Rizal, Malabon, Baritan Rizal, Malabon, Tanyong Rizal, Malabon, Tansuya Rizal, Malabon, Malabon Sugar Co Rizal, Mariquina Rizal, Mariquina, Bayan-bayanan Rizal, Mariquina, Santo Nino do Rizal, Mariquina, San Roque Rizal, Mariquina, Calumpang Rizal, Montalban do _ do Rizal, Morong do _. Rizal, Morong, Cardona Rizal, Morong, Calle Sumulong Rizal, Morong do Rizal, Morong, Maybancal Rizal, Navotas _ Rizal, Navotas (Varadero) Rizal, Navotas, Tanza. __ 1 Composite source. a Yellow. Capacity i. per minute. Meters. 36.6 70.7 34.1 46 146 120 306 260 266 213 229 246 177 184 143 162 143 110 92.7 113.1 143.3 82.3 91.7 12 17 167 88.4 88.4 29 79.2 43.6 25.6 87.5 162 213 Liters. P114 P 114 P 151 P151 P76 F 15; F 57 F10 Fll P151 P76 P95 P76 P227 F 6; P 114 P76 P114 P114 P76 P 53 P 76 P 76 P 114 P 76 P 132 P 114 P 76 P 38 P 38 F 9; P 95 INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 181 >> < O O *>> "o 'o d S 55 "of a o O Is .2 58 .2 5 CD .5 "S ,o m CD oO gS O oO w aw w high CO <*) 345 275 290 1,235 600 800 395 450 580 640 780 2,330 430 165 50 85 80 110 84 90 15 3.0 6.0 0.8 0.6 0,44 1.3 220 110 125 33 65 7.0 32 40 24 21 5.1 22 trace 16 29 15 11 12 28 110 170 330 1,300 nil nil nil 420 340 350 420 170 230 15 13 25 5.0 <5 nil 250 210 nil 7.0 nil . nil 300 260 70 1.6 29 8.3 49 17 7.9 trace . 390 380 370 380 435 60 70 64 70 1.1 1.2 2.4 0.8 22 7.8 8 6 26 23 27 8.0 7.3 8.0 11 13 44 16 69 59 { trace trace trace 1 i 200 250 30 trace 1.6 7.2 4.8 2.0 trace 6.0 3.4 15 13 2.9 6.1 trace trace trace 4.2 nil trace i i trace trace trace 17 14 trace 320 49 1, 090 94 410 | 66 280 ! 54 300 60 550 115 32 19 54 140 ~ 270 430 370 i 40 3.7 5.5 5.8 1 74 46 18 2,260 8.9 1.6 15 2.0 3.4 140 2.9 6.4 10.0 9.3 2.4 130 8.2 7.2 8.7 9.2 26 27 110 340 68 3.7 0.20 4.1 930 0.36 9.0 6.5 170 25 33 20 4,620 380 200 400 380 250 700 185 160 170 330 320 810 330 330 340 340 270 350 320 17 nil 40 0>) 33 32 20 97 91 78 84 99 97 107 47 nil 1.4 2.4 4.4 1.6 5.6 2.0 1.35 0.4 1.3 0.2 39 32 38 33 41 100 52 28 20 35 3.0 7 8.2 7.7 22 30 36 20 trace 19 21 2.8 11 5.5 9.0 16 8.2 87 trace trace trace trace trace 00 (*0 220 220 230 234 18 nil nil nil nil 270 270 280 285 I 17 1.1 5.5 trace 36 > Turbid. c Brown. 182 Labora- tory No. Well No. 118141 595 118456 609 104599 417 105142 421 105638 424 123525 99 123525 404 67694 45 68454 80594 116 106255 429 112021 116(?) 119808 719 119823 438 119867 732 119983 438-A 120109 755 120205 120206 768 120366 121.713 856 121907 877 122147 896 122369 914 122688 934 80095 133 120101 753 123104 793 124753 1026 98991 380 116975 539 120108 763 120143 767 120278 773 120359 781 121373 798 121503 859 121737 863 121738 872 121620 P.B. 121838 878 121935 885 68170 77 112114 466 118571 258 120339 775 120520 786 120705 802 Year. 1914 1914 1912 1912 1912 1916 1916 1909 1909 1910 1912 1913 1915 1915 1915 1915 1915 1915 1915 1915 1916 1916 1916 1916 1916 1910 1915 1916 1917 1912 1913 1915 1915 1915 1915 1915 1915 1916 1916 1915 1916 1916 1909 1913 1914 1915 1915 1915 PHILIPPINE WATER SUPPLIES Table XV.— Well waters of Locality. (Province, town, barrio.) Rizal, Navotas _• Rizal, Navotas, Tangos Rizal, Paraiiaque _ do . .... do ..._ do __... do Rizal, Pasay do do do do Rizal, Pasay (market) Rizal, Pasay, San Roque Rizal, Pasay Rizal, Pasay, San Roque Rizal, Pasay, Santol___ _. Rizal, Pasay, Calle Protacio Rizal, Pasay _. Rizal, Pasay, Calle Protacio Rizal, Pasay .—.do do do do _.„. Rizal, Pasig- Rizal, Pasig - , Bagong Hog Rizal, Pasig Rizal, Pasig, Santolan Rizal, Pateros Rizal, Pililla, Kisao__ _ Rizal, Pililla do do do Rizal, San Felipe Neri do... _ Rizal, San Felipe Neri, Hag-dan Bato . Rizal, San Felipe Neri Rizal, San Juan del Monte do do Rizal, San Mateo do Rizal, San Pedro Macati do __ _. do _ Rizal, San Pedro Macati, Guadalupe _. c Brown. Depth jL»tjpLn capacity p , of well, per minute. uo,or - Meters. 181.7 214 96 136 274 148 178 229 227 142 158.5 39.6 74.4 157.3 82.6 140.2 139.6 165.5 134.7 182.3 268 34.4 29.9 81.4 35 57 30.2 45.7 45.4 48.8 263.3 13.1 9.1 104.5 213 63.7 67.4 44 266 104.2 105.5 91.7 108.2 Capacity Liters. P 47 P 227 P 227 P 170 P 568 P 151 P 189 P 189 P 45 P 114 P 114 P 57 P 57 P 303 P 227 P 76 P 38 P 114 P 76 P 38 P 227 P 227 P 38 P 95 F 19 F 9; P 227 F 76 P 284 F 38 P 19 P 114 P 38 P 57 P 45 P 76 P 189 F 11; P 76 P 76 P 76 P 114 e Green. INTERPRETATION OP WATER ANALYSES 183 ? the Philippine Islands — Continued. >> 1 5 W O o "u < m 'o CO O E-i O 53 "a? o u 8 S s 73 bo Si" 3 5 o o m ) 240 395 80 0.4 29 22 24 nil 290 trace 00 210 1,250 82 0.2 93 37 560 nil 250 31 nil 250 550 70 nil 7.2 nil 64 nil 270 53 nil 250 500 65 trace 11 trace 55 nil 305 41 nil 250 700 80 trace 29 14 170 trace 305 26 nil 250 400 90 trace 56 23 27 nil 305 nil 280 460 68 1.1 trace trace 21 nil 345 27 nil 290 nil 490 80 0.36 trace trace 49 30 300 trace 15 280 nil 535 78 0.4 7.7 trace 13 18 310 24 nil 250 1,165 90 trace 69 31 455 300 25 nil 220 nil 580 59 0.30 6.2 trace 76 5.9 270 93 3,600 395 60 32 0.8 0.5 300 34 15 11 2,000 44 120 0>) 210 nil 260 trace 20 240 40 370 1.3 35 12 20 nil 290 trace <5 210 3.2 340 70 0.72 37 3.6 38 nil 250 nil (b) 2,400 320 360 61 100 105 5.8 2.8 0.9 155 27 36 71 12 13 1,100 13 13 trace 16.8 nil 210 nil 260 nil nil 220 315 82 trace 29 20 10 nil 270 nil nil 225 355 100 trace 54 16 11 nil 270 trace nil 200 350 92 trace 27 13 24 trace 240 trace 58 500 52 0.85 7.5 2.0 79 34 32 155 180 310 80 0.55 25 trace 9.3 220 trace nil 170 2.7 290 83 0.4 22 8.7 5.0 210 trace nil 140 560 40 0.4 4.4 1.3 190 nil 170 17 nil 110 250 15 0.6 9.3 trace 27 16 104 32 nil 166 320 55 0.36 3.7 trace 16 18 190 trace 55 180 nil 300 80 2.2 8.0 trace 7.2 5.9 210 trace 240 295 300 370 35 85 40 85 0.8 2.8 0.1 trace 36 36 0.21 36 7.7 7.6 0.02 13 4.5 6.9 40 8.0 trace trace . 270 nil 265 trace 320 nil nil 160 300 80 trace 7.0 trace 23 nil 195 nil nil 65 185 20 trace l trace 3 Turbid trace 11 32 79 trace 184 PHILIPPINE WATER SUPPLIES Table XV.-— Well waters of Labora- tory No. 121029 121350 124061 101739 104044 97863 97864 97869 114276 119789 119848 119883 120043 94640 98157 118477 118544 118610 118707 123663 124325 117681 105977 118476 119498 119638 117451 117988 123020 123156 123227 123430 120102 120964 118526 118992 119203 122286 122722 121926 122158 10. 7 944 110866 118593 120128 108992 Well No. 814 841 1002 352 355 362 506 721 729 742 747 272 340 344 612 626 632 639 996 1005 311 441 393 491 692 702 537 560 948 964 976 981 715 770 593 618 862 891 437 456 223 636 419 Year. 1915 1915 1917 1912 1912 1912 1912 1912 1913 1915 1915 1915 1915 1911 1911 1912 1914 1914 1914 1914 1916 1917 1911 1913 1912 1914 1914 1915 1913 1913 1916 1916 1916 1916 1915 1915 1914 1914 1914 1916 1916 1916 1916 1912 1912 1914 1915 1912 Locality. (Province, town, barrio.) Rizal, San Pedro Macati Rizal, San Pedro Macati, Masilang Rizal, San Pedro Macati, Zobel building. Rizal, Taguig do Rizal, Tanay do do Rizal, Tanay, Barras Rizal, Tanay do._ do Rizal, Tanay, Wawa Rizal, Taytay do„ _do. _do. -do. _do. -do. Rizal, Taytay, San Juan.. Rizal, Taytay, Dolores Samar, Catbalogan Samar, Villareal Samar, Wright Sorsogon, Bacon _-. Sorsogon, Bulan do Sorsogon, Casiguran do Sorsogon, Gubat _ do _. do_._ do Sorsogon, Irosin __ do _.__ Sorsogon, Juban do ._ __ _. Sorsogon, Magallanes Sorsogon, San Fernando ._ Sorsogon, San Fernando, Buyo_. Sorsogon, San Jacinto___ _. do. Sorsogon, Sorsogon do _.__ Surigao, Butuan ___ Surigao, Surigao __ Tarlac, Camiling a Yellow. Depth of well. Meters. 106.7 98.1 98.1 149 120 19 49 34 91 63.1 41.5 45.7 139.3 155 98 242 48.8 15.2 25.9 25.9 29.3 26.5 242 216.4 311 174 106.1 129.2 156 123.4 103.6 110.3 134.4 103.9 167.6 132.6 159.7 146 121.9 106.7 109.7 94 79.2 135.9 152 Capacity per minute. Color. Liters. P 76 P 76 nil P 265 nil P 132 P 132 P 45 P 114 P 45 P 379 P 38 P 76 P 76 F 49 00 P 227 P 189 P 189 P 132 P 132 P 76 P 132 P 57 nil P 76 nil P 114 00 P 38 00 F 6; P 23 00 P 114 F 19 F 38 P 76 00 P 57 F 19; P 76 nil F 28; P 114 nil F 23; P 114 nil P 76 nil P 38 P 67 P 45 P 30 P 114 F 1,817 F 8; P 26 nil F 15 <5.0 P 76 trace F 95 F 57 P 38 P 95 c Brown. INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 185 ■2S <5 00 CO CO 50 00 <5 <5 CO 00 nil <5 10 <5 <5.0 nil (b) 100 (b) 100 (b) nil 190 235 190 250 250 245 220 150 310 O 250 255 260 240 290 290 280 355 2,100 340 740 370 150 14 4.6 29 20 30 16 310 75 11 340 440 290 1,110 1,070 340 340 370 380 415 365 330 260 660 730 610 280 460 660 370 800 390 420 1,480 990 1,000 1,800 1,295 330 330 700 730 840 530 515 675 380 380 1,300 2,500 420 1,030 425 240 420 1,510 2,570 270 82 42 91 82 50 87 79 86 75 70 77 80 73 95 63 46 88 96 88 83 63 38 19 & g 15 2.2 0.16 12 1.8 4.4 4.8 ,4.0 trace nil 0.5 0.7 1.5 7.2 trace 2.4 3.7 0.1 9.7 1.7 0.20 0.20 0.2 trace 2.9 35 2.8 18.3 31 54 52 65 41 46 70 82 32 65 92 61 18 58 55 9.8 90 33 1.5 62 0.5 67 2.5 75 trace 93 28.0 36 trace 77 0.24 25 0.36 80 0.32 74 0.5 100 0.7 120 3.0 120 5.7 110 20 9.7 1.7 93 3.0 15 56 10 31 4.6 88 4.6 89 2.8 60 3.7 25 trace 27 0.4 25 72 57 29 43 110 120 130 73 14 20 50 450 42 125 60 19 54 40 125 23 bn trace 9.4 1.0 trace 5.6 21 19 14 35 27 14 22 19 23 18 18 1.7 19 0.24 5.1 11 11 trace 23 9.2 1.2 6.5 17 16 25 14 49 37 1.2 6.0 32 145 40 56 32 10 27 68 76 14 14 15 12 305 300 3.9 4.9 4.9 13 3.0 8.0 8.0 6.7 32 170 61 6.5 11 72 14 26 5.2 54 290 150 380 760 380 6.4 43 130 180 210 76 27 38 8.7 9.7 520 140 21 130 20 6.4 9.5 630 1,120 trace oo 6.4 nil 14 nil nil nil nil nil nil SO nil nil nil nil nil nil nil nil nil nil nil nil 220 290 210 305 305 300 230 180 380 300 310 320 290 350 360 350 445 2,620 420 900 455 180 *0 3 W 15 trace 2.1 130 155 11 11 10 14 nil nil nil 6.0 250 12 170 trace 18 85 3.1 nil 34 157 18 100 82 10 23 12 17 22 <5.0 31 86 nil nil 52 trace nil 18 trace 79 7.0 500 120 trace b Turbid. 186 PHILIPPINE WATER SUPPLIES Table XV. — Well waters of Labora- tory No. Well No. Year. Locality. (Province, town, barrio.) Depth of well. Capacity per minute. 1 Color. 110789 113292 117689 116713 80297 122947 105742 121225 121226 87526 80450 117938 80287 84983 113237 114248 96819 120899 120408 120493 122348 118409 121625 122308 119882 99418 99418 451 478 549 509 359 1 2 3 178 212 316 799 735 792 623 576 866 879 699 1 2 1912 1913 1913 1913 1910 1916 1912 1915 1915 1911 1910 1913 1910 1910 1913 1913 1912 1915 1915 1915 1916 1914 1915 1.916 1915 1912 1912 Meters. 133 181 159.1 234 64 75 259 48.8 55 47 49 Liters. P 265 P 76 P 132 P 265 P 76 00 00 00 nil nil 00 00 do Tarlac, Gerona __ Tarlac, Tarlac (municipal well) _ _ Tarlac, Victoria _. __ Tayabas, Atimonan _ . P 38 P 61 P 61 F 9; P 38 F 3.8; P 19 Tayabas, Boac_ do___ do __ Tayabas, Gasan Tayabas, Hondagua, Manila railroad com- pany. Tayabas, Lucena _ 105 205 F 38 F 76 00 do Tayabas, Lucena, Hospital de Pobres . Tayabas, Laguimanoc. 244 268 39.6 34.4 21.9 269.7 131.1 36.6 103.6 75 Tayabas, Pagbilao__ __, P 76 P 38 P 53 P 114 P 38 P 246 F 57 P 45 P 132 00 3.0 140.0 nil 00 do Union, Balaoan Union, Bangar do _ Zambales, Botolan _____ Zambales, San Narciso_-~ __ do a Yellow. c Browr i. INTERPRETATION OF WATER ANALYSES the Philippine Islands — Continued. 187 >> ■p •Cm >5 .So da MO < o Q is '3 < 0} m % O O W 1u fa a o }-> p O 9 i OS p 5 .2 o CO Cm OO &o eS O xn go S CO 0) ftco P 00 290 110 460 470 345 450 490 255 465 525 400 1,100 950 1,800 460 1,800 990 1,300 1,080 870 980 240 1,100 1,700 720 1,100 635 43 2.0 42 41 4.5 10 140 81 16 73 60 11 13 28 31 245 150 700 27 610 245 475 400 290 140 5.4 430 815 225 480 190 1 11 52 94 82 30 46 27 11 29 66 45 25 59 trace 3.6 2.8 0.40 1.6 0.1 0.07 3.4 2.8 4.5 1.4 1.8 . 20 28 40 4.7 70 49 trace 7.3 26 21 4.1 16 3.5 9.0 20 3.0 17 11 5.0 5.3 9.2 14 1.1 3.7 trace nil 28 9.6 68 5.3 trace 12 230 140 140 260 00 <5 210 nil nil 260 := 165 350 nil nil 200 430 1 i 68 90 67 12 40 60 40 22 40 60 trace 3.6 10 trace trace 1.5 3.7 1.2 1.2 2.2 190 96 18 32 71 4.6 51 trace 165 93 65 51 45 11 24 9.1 8.6 12 3.8 25 110 34 trace nil trace trace 14 trace nil 33 trace nil nil 29 400 370 400 780 nil 325 300 330 640 65 00 320 250 135 5.4 trace nil 390 300 165 1 b Turbid. 188 PHILIPPINE WATER SUPPLIES Table XVI. — Artesian wells of Well No. Location. (Province, town, barrio.) Date. Tem- pera- ture. Odor. Turbidity. 2 3 1 Cebu, Asturias, poblacion 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 drawn. °C. 28 31. 29 28.8 27 28 28.5 29 31.7 32.5 29 Nil nil (») nil (a) nil trace trace 00 nil nil trace Cebu, Balamban, poblacion _ __ H2S „ Nil do Cebu, Balamban do Cebu, Toledo, poblacion do do H2S .._. -do do Nil Cebu, Tuburan, poblacion Laguna, Bay, poblacion Hydrocarbons _ do do 685 703 723 27 28 493 440 459 907 907 889 883 919 Laguna, Calamba, poblacion Nil ... Laguna, Calamba, Canlubang... _ . do Laguna, Los Banos, San Antonio 31.8 31 32 28 34.5 31.5 36 38 37.5 31.5 28.5 32.5 30.5 29 30 30 29.5 27.8 29.2 28.4 30 29.7 28.3 29 29 29 28 27.5 27.7 27.7 28 28 28 28 do 45 1 Laguna, Pagsanjan, town H2S - nil Laguna, Pagsanjan, Maulaoin ___ .-_ do nil Laguna, Pagsanjan, Buboy ... H2SandC02_-_ H2S . 00 1 nil Laguna, Santa Cruz, town do - do nil Laguna, Santa Cruz __ do H2SandC02_- H2S nil nil ! Laguna, Santa Cruz, Santo Angel do nil slight nil nil nil 20 nil nil («) nil (a) (») Laguna, Santa Cruz, Umboy... Nil Laguna, Santa Cruz, Patimbao _ do Laguna, Santa Cruz, Umboy Laguna, Santa Cruz, town _ C02 Nil Laguna, San Pablo, Santa Maria, Magda- lena. Misamis, Cagayan, poblacion do do Occidental Negros, Bacolod, poblacion Occidental Negros, Bacolod, Mandalagan___ Occidental Negros, Bacolod, poblacion.-. Occidental Negros, Hinigaran, Aranda Occidental Negros, Hinigaran, Hacienda Guanco. Occidental Negros, Hinigaran, Paticul Occidental Negros, Hinigaran, Naravis Occidental Negros, Isabela, poblacion do __._ do do ___.„__. do do do Nil nil trace 00 00 trace nil 00 00 nil nil 00 nil do do 931 do „___ _ H2S . do , Nil Occidental Negros, Saravia, poblacion do __ do do do do Occidental Negros, Saravia. Tabigue Occidental Negros, Saravia, Gahit do__ H2S Occidental Negros, Saravia, poblacion Occidental Negros, Saravia, Alicante do... Nil do * Nil when INTERPRETATION OF WATER ANALYSES "the Philippine Islands. 189 nil 20 23 8.3 46 23 33 31 15 18 31 nil nil 37 trace 11 15 trace nil trace 27 11 51 nil 32.5 17 17 40 nil nil 33 25 30 25' 30 36 20 18 nil 31 0.47 2.4 0.7 1.5 0.07 1.2 3 3.7 0.83 0.6 0.37 0.07 4 1.1 0.25 4.5 0.33 nil 0.17 0.5 nil 0.1 0.25 0.6 0.25 1.7 0.47 2.7 2.2 1.2 11 1 12 11 11 4 2.1 3.8 2.1 0.8 0.4 3.7 0.8 150 260 9 35 15 150 380 125 33 42 9 7.2 41 150 41 160 47 18 41 40 28 11 10 62 13 24 32 5.3 c R 2 53 77 8.3 5 7.3 6.6 4 5 6 6 18 110 nil nil nil nil nil nil nil nil uil nil nil nil trace trace ni nil trace nil nil nil trace nil nil nil nil 78 nil nil nil nil trace oO trace nil nil nil nil nil nil nil trace nil nil 450 560 490 670 520 670 670 560 850 630 340 280 480 320 210 700 430 490 440 490 455 360 180 570 290 305 280 230 240 305 330 *6 ftc/2 12 26 9.6 nil 18 32 65 80 nil nil trace trace trace 100 16 trace nil nil nil trace nil nil nil trace trace 28 nil trace trace trace nil nil r-i TO 59 520 310 250 440 330 340 500 170 180 150 140 200 41 44 400 120 110 82 74 94 100 79 79 100 200 135 TO +J 220 510 360 400 450 460 490 540 440 350 220 190 ft pj Poor___ Bad ... Poor.__ do - Bad „_ .....do. do. ..„.do. do . Poor... do . Fair.._ 190 250 230 220 230 280 390 380 460 490 540 18 nil nil trace nil nil nil nil nil nil nil trace Fair . 58 1 5 12 Negative. Do. Negative. Do. Do. Do. Do. Negative. Do. Positive. 13 55 11 9 10 83 1 10 36 18 45 13 5 3 10 18 66 Negative. Positive. Negative. Do. Do. Do. Negative. Do. Negative. Do. Do. Do. Do. Do. Do. Do. Do. Negative. Negative. Do. Do. * Clear when drawn ; turbidity develope on standing. 190 PHILIPPINE WATER SUPPLIES Table XVI. — Artesian wells of Well No. 344 121 120 126 127 233 101 229 91 82 77 111 250 242 466 243 103 272 340 626 632 Location. (Province, town, barrio.) Occidental Negros, Silay, poblacion Occidental Negros. Silay, Mambulac Occidental Negros, Silay, Balaring Occidental Negros, Talisay, poblacion __. do do Occidental Negros, Talisay, Bagaas Occidental Negros, Victorias, poblacion . Occidental Negros, Victorias, Viejo Nueva Vizcaya, Bagabag, poblacion Nueva Vizcaya, Bambang, poblacion Nueva Vizcaya, Bayombong, poblacion _ . Nueva Vizcaya, Solano, poblacion Rizal, Cainta Rizal, Mariquina, San Roque do Rizal, Mariquina, Santo Nino Rizal, Mariquina, Bayan-bayanan Rizal, Mariquina, Santa Elena Rizal, Montalban, poblacion do do _. do Rizal, Montalban, Burgos Rizal, Montalban, San Jose do Rizal, Pasig, Bagong Hog Rizal, Pasig, poblacion do Rizal, San Mateo, poblacion do do — .-do Rizal, San Mateo, Guinayang Rizal, San Mateo, poblacion do do do Rizal, Taytay __. do do do Sorsogon, Bulan, town Sorsogon, Irosin, town _ Sorsogon, Masbate, poblacion _. do do _._. Sorsogon, San Fernando, poblacion Sorsogon, San Fernando, Buyo Sorsogon, San Fernando, Batuan _ Date. 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1917 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 1916 Tem- pera- ture. °C. 28.4 28.5 28.3 29.4 29.5 29 28 28.9 27.5 27 25.8 27.5 29.3 28.1 28.3 28 28.3 28 28 28 27.8 28 28 27.5 27.5 28.8 28.8 29.5 29.7 27.8 28 28 27.4 29.3 28.2 28 28 29 29 29.3 29 34.8 31.2 30 29 33 31.4 32.2 Odor. Nil . .-do. __do . „do. -do. __do . __do_ ..do. -do . ..do. ..do . -.do. ..do. __do. -do. .-do. __do. -do. _.do. -do. __do. -_do. ._do. -do. -do. _-do. Nil . _do . _do. _do . .do. -do. -do. H 2 S Nil.. _do_ -do. _do. _do. _do. -do. H 2 S . _do- _do. .do. CO2-. Nil.. Turbidity. -do. (a) <•)■ nil (») nil (•) (•) 00 nil nil nil nil nil very slight nil . nil w nil nil nil nil nil nil nil nil nil nil trace nil nil faint trace nil nil nil nil nil (a) nil nil nil nil nil slight <*) nil trace (») trace trace 1 Nil when drawn. INTERPRETATION OP WATER ANALYSES 191 the Philippine Islands — Continued. 150 180 270 260 260 240 150 180 180 160 140 130 160 300 530 600 430 140 250 210 210 190 200 190 230 200 360 200 280 270 300 260 160 280 250 240 310 370 320 410 430 570 630 3,300 460 390 30 27 12 14 20 18 56 33 7 32 19 5.1 26 14 48 41 92 38 100 41 13 12 16 35 14 11 18 20 5 5 40 37 26 13 38 37 46 12 22 40 37 15 23 16 23 31 1,100 16 24 3.7 5 0.87 1.4 0.53 1.6 11 5 0.47 4.3 0.13 1.7 0.73 0.17 0.45 0.41 6 0.17 0.2 0.33 0.33 0.07 0.57 0.33 0.2 0.23 1 1.5 0.4 0.57 1.2 0.67 0.07 0.92 1.8 1.2 2.6 0.4 0.5 0.63 0.17 4.5 4.5 130 12.5 12.5 7 11 8 6 12.5 12.5 10 6.3 170 15 7 38 10 100 10 7 10 10 11 17 10 c8 03 •n u §1 '■So to O aa nil nil trace trace trace trace trace trace trace trace trace 240 24 38 100 large 53 290 trace 250 trace trace trace 170 180 150 170 400 350 380 290 96 350 160 140 150 140 120 150 Fair .... do. do . Fair ___ Poor___ do. do . do. Fair ._. Poor.__ 91 80 80 120 130 140 150 170 280 220 250 140 380 1,900 250 190 250 140 180 180 200 180 110 190 170 160 220 460 270 350 360 Fair ___ .—do . do. do . do . do . 350 540 360 690 2,600 360 290 1 Poor Fair do ... do ... Poor Fair do ... do ... do... do.. Poor Bad Poor do._ do„ Bad Poor Bad Poor Bad ____ do _. Poor do. "DOS J2 2 c ft • a to 17 12 174 18 12 422 (?) 2 6 2 200 15 23 9 18 5 28 95 19 8 210 230 40 65 Negative. Negative. Negative. Do. (?) Negative. Positive. Do. Negative. Positive. Do. Negative. Do. (?) Do. (?) Do. (?) Do. Do. Positive. Negative. Do. Do. Do. Positive. Negative. Positive. Do. Do. Do. (?) Negative. (?) Negative. Positive. Negative. Do. a Nil when drawn. APPENDICES 152918 13 193 ; APPENDICES : THE LOCATION OF ARTESIAN WELLS IN THE PHILIP- PINE ISLANDS PROM A GEOLOGIC VIEWPOINT * It will be assumed that the reader is conversant with the principles governing the phenomena of artesian wells, and in the following discussion no attempt will be made to consider the numerous factors which control the subsurface accumu- lation of water under hydrostatic conditions. The conditions under which water-bearing rocks, like inter- calated sandstone^ and shales, were laid dpwn in the Philip- pines, wb^re the distribution of land masses i$ irregular and the interruption of sedimentary processes by vulcanism yvm fv$- quent, were so variable that no single bed nor any §eries $f beds extends uniformly over great distances. Thus it is not ppssjibje here, $s it is, for instance, in Australia, %q map ejosely the outcrop of the "intake beds" nor to calculate the depths %t which such beds will be encountered over large $re$8? It is probable th&t very often wells will be drilled &t towns which need most urgently a supply of potable w&ter, iryespeetive ef the ehances of obtaining water. Frequently there will fee little chpjce between different possible locations in a small town, and it inay be found expedient to l§ ®e$se t® flow if the casing is continued e?en a, few mete^§ §feoye t the ground surfeee; that is to s§y, if su^b welte h&d been drilled I fifem a plightly higher elevation, It would h&ye been nectary \ t§ pump them, It follpwp that, other things feeing equ&l, the [< tower of two possible sites is preferable, Jioweyer, |be ©opir i feility of surface anamination should be kept in mind In this i oonneetion. A well on low ground i§ more often contaminated f fey surface waters than one on higher ground- It i$ true also I; ' '" \ *3?y Wallace E. Pratt, *eprinte4 fyom PhS< Jwrn. Se*,, Sep. 4 U9JS), I 10, 23 J. I 195 196 PHILIPPINE WATER SUPPLIES that a well should not be located too near the seashore in an attempt to get it on low ground. Too often in such a location the well encounters brackish water. Through the cooperation of the Bureau of Public Works the Bureau of Science has had access to drillers' logs for about 700 artesian wells. Samples of the drill cuttings have been sub- mitted for examination in the cases of about half of these wells. These data, and a knowledge of the general geology of the Phil- ippines, are made the basis of the following discussion. For their consideration in relation to artesian waters the geo- logic formations of the Philippines may be classed and sum- marized as shown in Table I. LITTORAL AND ALLUVIAL DEPOSITS A large proportion of the population of the Philippines lives in regions in which the land is made up of littoral and alluvial deposits. The important areas of alluvium are found in great structural valleys like the Central Plain of Luzon, the Cagayan Valley in northern Luzon, the Bicol Valley in southeastern Luzon, the Iloilo Plain in Panay, and the Cotabato and Agusan Valleys in Mindanao. The littoral deposits make up the coastal plains which fringe many of the islands, like the plain upon which the town of Cebu is located. The structural valleys have been filled up by loose clays, sands, and gravels carried down from the adjacent highlands by shifting streams and deposited along an ever-advancing shore line. The coastal plains have been built up in the same way; in many cases they rest upon a base of coral reefs, which have grown up offshore from the various land masses. Both the filled structural valleys and the coastal plains combine alluvial and littoral deposits in their structure, since the alluvium carried by streams was deposited largely at the seashore where part of it was worked over again by wave action. In either situation the littoral and alluvial deposits are surprisingly thick; in very few cases have wells passed through them into the underlying formations. A majority of the wells drilled by the Bureau of Public Works have penetrated these classes of material. A majority also of the successful wells have obtained their water from sands and gravels of littoral or alluvial or combined littoral and alluvial origin. It cannot be said, however, that littoral and alluvial deposits are uniformly productive of artesian water. Such deposits are irregular, and individual beds do not extend over large areas. On the contrary, the formation is characterized by narrow- lenses of sand or gravel or clay, such as would be ex- ARTESIAN WELLS 197 I bfl . Ti a> * £ 6 2 £ TO s .o -e I 1 3 ■* •H g grill' 8 00 'C a> «h M 1 4 <* ^ * s s s s I £ 3 *" s c t*. m ** S ►^ ^ T3 +i *H "3 ,jj o ..8 > g ■ C8 oj -g o 2 «8 H (S •5 60 .. -3 03 ti A , _g .-NO .s :s j *§ c4 O g *3 s g .6 § 1 i* « 2 3 ■cJ g I 5 -p rj X! CO I 1 2 | "5 •« ■~i 4J 0, b ,5 .JS >> p. 03 » TJ ■"3 > 2 ci «H a 3 03 en T3 > "55 a o 1 tn >> 3 > '3 o p. '3 W h [X, g . 8 o •H tJ T) fl ■ S § 1 s K *P .§ •£ 3 r 3 -5 ^ s a - 198 PHiLii¥iMfi wAtfii Applies pected in the beds of modern streams or along beaches. It is due to this feature of littoral and alluvial deposits that so often a flowing well will be secured adjacent to a drilled hole which has obtained no water or only pumping water* A striking ex- ample is the case of two wells drilled within 50 meters of each other between the Philippine General Hospital and the Bureau of Science in Manila. The first well reached a depth of 178 meters and obtained only 113 liters of water pet minute, The second well obtained 322 liters pier minute at a depth of only 137 meters. On the completion of the second well work wag resumed on the first well in an attempt to get water at the 137-meter horizon, but all efforts to this end failed. Neither of these wells flowed, but numerous experiments have demonstrated that in this class of deposits flowing Wells, nonflowing wells, and dry wells may be situated side by side. As has been said, littoral and alluvial deposits hfe made up of loosely consolidated sands* clays, and gravels. The loose character of the formation is responsible for the commonly noted phenomenon that in wells situated near the Coast line the level of the water in the well varies with the Stage of the tide in the adjacent sea. The fresh water in the upf>er part of the land mass is always percolating through pOrous beds toward the sea, and in the region of the seashore it is in some measure in a condi- tion of hydrostatic equilibrium with the sea water, "Which satu- rates the porous beds outcropping on the sea floor. The rising tide actually increases the hydrostatic pressure on the ground water in the adjacent porous beds. This effect is especially marked where an old Coral reef haS been included between the deeper beds of the formation, because the loose structure of the coral reef affords unusually free passage f dr water. Another factor which must be considered in connection with littoral and alluvial formations is the possibility of obtaining salt water in wells adjacent to the CoaSt. Littoral deposits are contaminated by the salt water in which they were formed. Close to the coast line percolation of the fresh ground water may not have been extensive enough to have removed all the original salt, particularly where the formation contains clay, which is not easily permeable. Salt w&ter is almost inevitably encountered at depth in wells near the coast line. The ground- water circulation appears to be most vigorous at depths generally less than 180 meters. Consequently, if potable water is encoun- tered in littoral or alluvial deposits at depths of from 60 to 150 meters, it is usually advisable to make arrangements to use this water even though it be of limited quantity and require IffHfopilg* tf&th€? thM t® dontiftUG drilling in the htfpe of bbtein- jtig flowing w^tet &r Water in greats quantity at e&tre*ife *'d£jpt&& Ocicasioft&lly* where it has been possible td fe&se notil | salt water, wells have been deepened and have obtained ftfc$h J water at low^i* levels* but as a rul&> fi*esh water has not been found below salt water. The discussion of alluvial and littoral deposits and combina- tions of these two classes of deposits may be extended and ap- \ plied to intermingled alluvial, littoral, and fragmental volcanic material as well. Volcanic tuffs are often and extensively 1 interbedded with alluvium and with littoral deposits in the Philippines; less frequently volcanic breccias and agglomerates Alternate with alluvial or littoral material. Volcanic tuffs, as a matter of fact, usually contain interbedded alluvium, and siihilarly alluvium usually includes some volcanic tuff. Hie com- binations of these several classes of material yield water about | p,s commonly and under about the same conditions as littoral and [,' alluvial deposits themselves. I CORALLINE LIMESTONE I i Coralline limestone is generally dry where it occurs over I extensive areas and in thickness. It is so porous and so thor- 1 oughly jointed and cavernous that water percolates through I it with little hindrance. Only in coralline limestone that is interbedded with impervious beds of clay, marl, or other material i& water confined so as to be available under hydrostatic pres- sure. Fortunately a great deal of the recent coralline limestone in the Philippines Is interbedded with impervious material and, S therefore, can often be made to yield water. Coral reefs have I been found in buried littoral deposits, and in this position were j Saturated with water under pressure. More commonly coral S reefs have been found in deposits of water-laid volcanic tuffs /hi relations which made the coral reef a natural reservoir for I ground water. But the commonest condition tinder which water I has been obtained from coralline limestone is that of interbedded coralline limestone and clayey marl. The thick marl beds are ithpefvious and confine the water ill the intervening frdfous $§Ml-re&f meifrberS of the series. Coralline limestone is mo&t abundant in the Visayah Islands, i&jpedi&lly in Cebti and BohoL On both theke islands it included ifliJrl b£ds. Good wells have been obtained ih this formation i& G&iy &bdut 50 £er cent of the trials made. The fehaftcfc df Sfte§uftteriiig salt Water is gte&t if the Well is drilled to a d#tft WBM €a»iesl it much beloW sea levsl. Ih drilling ttoatigh 200 PHILIPPINE WATER SUPPLIES coral, the hole should not advance far beyond the casing, even though the wells may stand up well, and especial watch should be maintained for impervious layers which may act as confining agents, VOLCANIC BRECCIAS AND AGGLOMERATES Volcanic breccias and agglomerates, made up of varyingly coarse and fine fragmental material embedded in tuff, are very common in the Philippines. These rocks have usually been deposited on the sea floor and, therefore, have been worked over and roughly stratified by water, but heterogeneous breccias and agglomerates of subaerial deposition are also known. These rocks are found in the immediate vicinities of old volcanoes and along lines of former volcanic activity. Much of the material is indurated and impervious, but an equal proportion, perhaps, is loose and porous. In massive breccias or agglomerates there is only slight chance of obtaining artesian water, but where the fragmental material has been deposited on a sea floor, and is, therefore, somewhat bedded, artesian water may be obtained. Wells on the south- eastern and eastern shores of Laguna de Bay have yielded good flows from this class of rock. There is a considerable area of bedded volcanic agglomerate around the base of Mount Isarog in Camarines which ought to yield water, and likewise in northern Camarines and in Sorsogon there are places at which it is suspected rocks of this nature are water-bearing. 6ft the whole, however, volcanic breccias and agglomerates are rather uncertain territory for the artesian-well driller. Mineralized water is often encountered in massive volcanic agglomerate. Hot springs and other evidences of solfataric action are associated with these rocks, so that in addition to the possibility of encountering no water there is the further chance that if water is encountered it may be too thoroughly mineralized to be potable. BEDDED VOLCANIC TUFF Bedded volcanic tuff is found extensively in southwestern Luzon and has proved to be particularly reliable as a source of artesian water. This tuff has not been indurated nor con- solidated through folding processes; it is distinctly bedded and generally porous, but the successive beds are varyingly fine- grained, so that conditions for confining water under some pres- sure are very good. Many of the wells in the bedded tuff have yielded flows, and a great majority have yielded either pumping ARTESIAN WELLS 201 or flowing water. The bedded tuff formation is, perhaps, more uniformly water-bearing than any other 1 of the Philippine rock series. TERTIARY SEDIMENTARIES The Tertiary (Miocene) sedimentaries consist of shales, sand- stones, conglomerates, and limestones. The formation is en- countered in various parts of Luzon; it makes up nearly the whole of the area of Samar; and it is important in Leyte, Cebu, Panay, and in parts of Mindanao. Coal and petroleum are found only in the Tertiary sedimentaries in the Philippines, and the distribution of these minerals may be used as a guide in this connection. The shales and sandstones are made up in large proportion of volcanic material. The series as a whole is in- durated and close-grained; consequently it carries but little water. Moreover the fine-grained beds retain a great deal of their original salt content, and this contaminates any water which is obtained from them. Only a small number of wells have penetrated the sedimentary series, and only a small pro- portion of these have been successful. Where this series of beds constitutes the underlying formation, a serious effort should be made to obtain potable waters in the surface alluvium if it is available. Deep wells are to be undertaken only as a last resort. It must be admitted that some artesian water has been obtained from the sedimentary rocks, but the flows are invariably small, and no eminently satisfactory wells have been drilled into the formation. The sandstones and the conglomerates yield water under favorable conditions, but even these rocks are too dense to be of great promise. The limestone members of the series are very cavernous and jointed, and water percolates through them readily. The lower limestone, which is very close to the base of the sedimentary series, is undoubtedly the most im- portant possible source of artesian water in this formation. At its outcrop this limestone is corroded and jointed until it is a very porous rock. The sedimentary series is usually found flanking the Cordilleras and dipping away from them, so that very often this basal limestone is exposed in a region of heavy rainfall and lies at an angle which accelerates the percolation of water along it. If the limestone in this relation were pene- trated by a well, it ought to yield water copiously. The diffi- culties are that the basal limestone is thin, discontinuous, and broken by faulting; that inasmuch as its porosity in surface exposures is due largely to solution, the limestone may not be 202 PHILIPPINE WATER SUPPLIES porous below the permanent level of grouftd water ; and finally* that its stratigr&phic position is stich that it is commonly too deeply buried, except in mountainous and consequently unin- habited regions, to b& accessible by drilling. The conditions afford a chance, however, which should be tested when oppor- tunity presents. MASSIVE IGNEOUS ROCKS Massive igneous rocks abound in all of the truly mountainous portions of the Philippine Islands. Igneous rocks* wherever present to the exclusion of other rocks, constitute the formation least favorable to the accumulation of potable artesian Water. They are impermeable to water because of their dense nonporous texture and the absence of bedding planes. It is generally im- material in this connection whether the igneous rock is of the deep-seated, holocrystalline type, such as the diorites* gabbros, peridotites, and occasional granites, or is one of the surface lava flows, such as the widely distributed andesites and less common basalts, rhyolites, and dacites* although infrequently solidified lava flows are so vesicular and porous as to be per- meable to water. Very rarely do common igneous rocks yield water in quantity. No Philippine wells have encountered w^ter in massive igneous rocks, although a dozen, perhaps, have been drilled into them. Minute quantities of water are contained along fractures and joints in igneous rocks * and often mineral- ized water is encountered in the occasional veins and sheai 4 zones ; otherwise the rocks are almost invariably dry. Obviously* there- fore, igneous rocks are to be avoided in chodMng sites for artesian wells. metamorphic rocks Metamorphic types of rocks are represented in the Philip- pines principally by schists, with subordinate gneisses and mar- bles. Because of their dense nature metamorphic rocks are not common sources of artesian water. In the Philippines they are of limited distribution and consequently unimportant; as yet fro wells have been drilled into them. Water might be obtained from buried marble, which is often cavernous, but schist and gneiss would probably be found to be dry. Schists and gneisses, together with massive igneous rocks, ai*e the basal formations in the Philippine rock series and will, therefore, be encountered ultimately in practically any locality in the Islands if the drilling proceeds to a sufficient depth. Since they are devoid of water, ho attempt should be made to continue drilling once these formations are encountered. THE CHEMICAL PURIFICATION OF SWIMMING POOLS 1 The purification of Swimming pools has long been the subject of much study, and a vast literature has been developed con- cerning it. Many methods have been suggested, notably filtra- tion, sterilization with ultra-violet rayS* and the use of ozone, topper sulphate, liquid chlorine, tod the hypochlorites of sodium* fnagnesium, or Calcium. Although these methods* or combina- tions of two or more of them, have beeii f ouiid satisfactory Under 8iost Conditions, great discrepancies exist in the results recorded. In spite of the fact that there are many factors influencing the purification of swimming 1 pools, many experimenters have treated their particular problems as though they were of general ap- plication ; henCe has arisen much difference in opinion concerning the relative merits of different purifying agents, amounts neces- sary for efficient purification* methods of application, and the like. In many cases too little attention has been paid to im- portant factors SUch as quality of water, temperature of pool, number of persons bathing turbidity and the like to enable general conclusions to be drawn from the results of different Workers. T*he treatment that is highly efficient for One water under certain Conditions may fail Utterly for a different Water under Slightly Changed conditions. Of the methods mentioned, the Use of chlorine either &S liquid chlorine or as a hypochlorite is probably the most widely practiced, and because of their Cheapness and because Of the ease with Which they can be administered, hypochlorites are em- ; ployed more than liquid chlorine. t The problem of maintaining a swimming pool in Manila in a ( Sanitary and attractive condition is rather complicated. The { Water from the municipal Supply is always slightly turbid, So I that the bottom Of a pool is generally invisible. This turbidity I not Only makes a pool unattractive and increases the danger from accidental drowning, but also militates against the action 6f disinfectants, The temperature (27° C, to 80° C.) is an added factor, aS it is nearer the bacterial optimum than that of typical I United States installations, and bacterial growth is correspond- ingly stimulated. *6y Gm. W. Heise mid R; H. Agtiil&r, abstracted from Phil Jbum. ScL, Sec. A (1916), 11, 105-123. 208 204 PHILIPPINE WATER SUPPLIES Obviously filtration should be employed as a preliminary meas- ure in the treatment of waters of the kind described; however, the lack of filtration facilities and the desirability of improving the sanitary condition of the local installations as rapidly as possible made it advisable to see what could be done with chemical methods of purification alone. Three pools were accordingly kept under observation. When water was left untreated in the local swimming pools, the bacterial count invariably reached enormous figures about the second day, and organisms of the B. coli group were practically always to be found in 1 cubic centimeter water samples after the first day. The usual chemical analyses gave little indication of this state of affairs. A slight sedimentation occurred during the first day or two in which the water was used, leading to a decreased turbidity and corresponding fluctuations in oxygen consumption and chloride content. Differences during the week in total solids and alkalinity, if any, were too slight to be of sig- nificance; neither chlorides nor oxygen consumed showed the steady increase that might have been expected ; turbidity, after the initial drop, remained practically constant. The use of copper sulphate as a disinfectant both for public water supplies and for swimming pools has been frequently rec- ommended. 2 For example, Thomas, 3 in a recent article, showed that a greater degree of bacterial purification had been effected in a swimming pool with daily additions of 0.4 part per million of copper sulphate than had previously been accomplished with a single addition of 2.5 parts per million of "hypochlorite" [0.8 ( ?) part of available chlorine] , and he concluded that the copper sulphate method was cheaper and more effective and was further superior to hypochlorite treatment because it caused no odor and was not irritating to the eyes. Unfortunately the author gives no data concerning the chemical quality of the water used nor the exact strength of hypochlorite employed. The water was filtered and refiltered, and alum was used as coagulant. As the author points out, the coagulation with alum and subsequent fil- tration removes the carbonates and bicarbonates that would otherwise hinder the action of copper sulphate. Our results with copper sulphate show clearly the unsuitability of this method to a water high in substances that react with a copper salt. The test was conducted for two weeks, 1 part of crystalline copper sulphate per million parts of water being 2 For partial bibliography see Manheimer, Publ. Health Rep, (1915) f 30, 2796. *Journ. Ind. Eng. Chem. (1915), 7, 496. THE CHEMICAL PURIFICATION OF SWIMMING POOLS 205 employed during the first week and 2 parts per million (with fresh water) during the second. In neither case was an effect on the bacterial content apparent after the first day, and long before the end of the week the colony count had reached an enormous figure, the copper sulphate seemingly exercising not the slightest inhibiting effect. The chemical analysis of the water showed little or no varia- tion. Upon addition of copper sulphate the turbidity of the water increased greatly, owing to interaction with the bicar- bonates present and subsequent precipitation of hydroxides and carbonates of copper, calcium, or magnesium. This action would account for the removal of copper sulphate and its failure as a germicide in this series of tests. Owing to the turbidity re- sulting from its use and to the lack of efficient sterilizing action, it is apparent that, without filtration, the use of copper sulphate is not to be recommended for water similar to the one under observation. A number of attempts were made to secure adequate purifi- cation with chloride of lime, different quantities being used each week. The first attempt with chloride of lime was made with an addition of 0.5 part of available chlorine 4 per million parts of water. The effect on the bacterial content was apparent for only one day, after which the count was excessive and B. colt appeared. No better results attended the addition of 1 part per million, and only with an addition of 2 parts per million could an appreciable effect on the bacterial content on the second day be ascribed to the chemical added. After the second day the bacterial increase proceeded unchecked. In none of these cases was the effect on the chemical constituents great enough notice- ably to affect the alkalinity or total solid content of the water. It might be well to note parenthetically that, although the last- mentioned concentration is far in excess of that generally em- ployed for purification, there was no complaint from users of the pool, except in one case, where a few people complained of irritations of the eyes and of the mucosae of nose and throat. In this instance it was shown that the trouble was due to careless and improper administration of the disinfectant, which allowed undissolved lumps to get into the tank. The odor was strong and persisted for days, but was not sufficiently disagreeable to be a real drawback to the use of hypochlorite. *A11 hypochlorite used was analyzed with arsenious acid, using starch- potassium-iodide paper as indicator. 206 PHILIPPINE WATER SUfTXJEB The chlorination having failed to give the desired results, a$ attempt was made to study in detail the causes of the failure and to overcome the difficulties invqlyed. It was noticed that, in general, the city water showed nq trace of "free chlorine" when it left the mains, as determined chemjU cally by acidifying 200 cubic centimeter samples of water m$ adding a drop of methyl orange, 5 the presence of chlorine feeing indicated by the bleaching of the indicator. This result wa$ rather surprising, since the water arrived at the swimming pools probably within three, almost certainly within five, hours after chlorination had taken place. Moreover, in spite of the relatively large additions of chloride of lime to the swimming pools, all trace of "free chlorine" was lost, usually within twenty-four hours, A laboratory study of the decomposition of a clear (filtered) solution of chloride of lime added to (unchlorinated) city water gave the results indicated in Table I. Table I, — Decomposition of chloride of lime in water. Minutes. Arable chlorine in parts per million. 0.8 2 0.0 30 0,3 120 Q,d.(?) From the foregoing it is apparent that the chloride of lime lost its effective strength very rapidly and that in two hours its concentration had fallen below 0.1 per million. Just what is the minimum concentration of chlorine that will keep water free from dangerous organisms is not known; certainly it cannot be much less than the concentration mentioned above. The destruction of hypochlorite must be due either to sponta- neous decomposition or to interaction with substances dissolved in water. Hypochlorites decompose, even in the dark, 6 with measurable velocity. The reaction is greatly accelerated by light, 7 especially by the visible and ultra-violet rays, and by heat. The temperature of a bath, therefore, becomes a matter of no small importance in studying purification of water with hypo- chlorite, and the amount of daylight falling on a pool may greatly affect the rate at which hypochlorite disappears. The interaction of chlorine with substances dissolved in water "Winkler, ZeifachF. f. mmw- Ghem. (191§), 2$, I, 22. *Bhaduri, Zeitschr. f. anorg. Chem. (1897), 13, 385. 1 Lewis, Joum, Ghm, Sqc, (l%l%), 101, P371. THE CHEMICAL PURIFICATION QP SWIMMING POOLS 207 has been much studied in recent years. 8 The phenomenon w generally associated with a high organic content in water, A large amount of "free chlorine" disappears immediately, alter which decomposition proceeds more slowly, but does not reach equilibrium for a long time. The amount of chlorine consumed appears to be dependent on the concentration in which it is added ; the more hypochlorite added, the more will be decomposed in a given time. The reaction proceeds more rapidly at high temperature than at low. as 07 OS as 10 20 30 40 50 60 7 80 SO WO 110 120 Fig. 2. Decomposition of calcium hypochlorite in water. Many substances are known 9 to effect the chlorine consume tioii, notably albumin and its decomposition prpdiicts, urea, glycqcpl, peptone, asparagin, and the Uke. We have determined the chlorinerconsuming pqwer of $ number of different pub- stances, using the following method : Two hundred cubic centimeter ^mples of water, qx else the Substances under examination dissolved in 200 cubic centimeter gt clistilled water, were placed in glass-stoppered bottles, Tq e&ch sample a known excess of clear (filtered) calcium foypo- cJalorite solution was added. The bqttle was stoppered and al- 8 Cf. Glaser, Arch, f, Hyg. (1912-13), 77, 165; Hairi, Zeitsch T . f. Hyg, (1913), 75, 40. a Cf. Elmanowitsch and Zaleski, Zeitsehr. /. Hyg, (1914), 78, 473; Hairi, ibid. (1913), 75, 46. 208 PHILIPPINE WATER SUPPLIES lowed to stand at room temperature (30° C.) for two hours in the diffused daylight of the laboratory. After digestion with hypo- chlorite, 2 cubic centimeters of 10 per cent potassium iodide solution and 2 cubic centimeters of 25 per cent phosphoric acid were added to each sample, and the liberated iodine was titrated with 0.02 N sodium thiosulphate solution, starch being used as an indicator. The differences in chlorine consumption are shown in Table II. Table II. — Chlorine-consuming power of different substances. Substance. Chlorine added. Chlorine con- sumed. Chlorine con- sumed per liter. Remarks. Distilled water . mg. 6.5 6.5 6.5 1.0 6.5 6.5 6.5 6.5 6.5 3.4 mg. 0.15 0.2-0.5 0.2-0.6 0.24 0.75 0.28 0.7 4.4 5.6 2.0 rag. 0.75 1. 0-2. 5 1. 0-3. 1.2 3.75 1.4 3.5 22.0 28.0 10.0 Varies from day to day. Do. Bureau of Science well. From aquarium. Reservoir water (unchlorinated) Tap water (chlorinated) _ _ . Artesian well water _. 200 cubic centimeters distilled water: Plus 0.0025 gram oxalic acid Plus 0.005 gram oxalic acid Plus 1 cubic centimeter urine Plus 0.5 cubic centimeter ± sweat- Plus 0.5 cubic centimeter saliva... It is significant that the substances given off from the human body cause the consumption of relatively large amounts of chlorine. This emphasizes the necessity of personal cleanliness on the part of the users of swimming pools if the purification of tank water by means of chlorine is to be successful. A thorough bath with soap should be taken before the pool is entered to remove all body products so far as possible, not only to avoid introducing into the water substances noxious per se, but in order to prevent the destruction of the hypochlorites to which the purifying action is due. There are, then, two distinct actions or effects: the first, the germicidal action of chlorine or hypochlorites; the second, the specific interaction between the chlorine and the substances in water. There is evidently a minimum concentration below which effective purification does not occur ; if this is reached in a short time, purification will not be adequate or lasting in its effect. It thus becomes necessary to maintain at all times in the water of a swimming pool an excess of "free chlorine" sufficient to keep up effective purifying action. With these conditions in mind, the purification of a swimming THE CHEMICAL PURIFICATION OP SWIMMING POOLS 209 pool becomes a comparatively simple matter. A relatively small amount of hypochlorite will effectively purify the water, after which it becomes necessary to keep the bacterial content within safe limits by means of repeated additions of disinfectant. That this is true is evinced by the results obtained during a series of tests in which chloride of lime was used in quantities repre- senting a daily addition of 0.5 part of "available chlorine" per million parts of water. Throughout this series the bacterial content was kept below 200 and no B. coli was found. In all cases the water remained in the pools for two weeks and was safe during the entire period. That there was no cumulative effect and that there was no large excess of chlorine at any time were shown by omitting chlorination for a single day, when the bacterial content immediately increased to dangerous propor- tions. It took more and more chlorine to produce the same effect as time went on; therefore it became advisable to change the water after about ten days or two weeks, even under the unfavorable circumstances existing in Manila; and if the water be changed weekly, the danger of contamination is very slight. An attempt made to reduce the quantity of hypochlorite to 0.25 part of available chlorine per million resulted in adequate sterilization of one swimming pool, but a decidedly unsatisfactory state of affairs in another. The former pool was used by more bathers than the latter, but the apparent anomaly was explained by the fact that the second pool was exposed to direct sunlight at certain hours of the day, which decomposed the hypochlorite and subsequently permitted bacterial infection. It is doubtful if such high concentrations of hypochlorite as those used in Manila would be necessary under average condi- tions. In addition to the poor quality of the water, the added effects of excessive temperature (almost 30° C.) and of light must be taken into account. Even in the tanks under obser- vation, where conditions were fairly uniform, each case required special treatment. The best-lighted tank required greater addi- tions of chlorine to maintain an excess of disinfectant than did the others ; while in the most poorly lighted tank the decom- position rate of hypochlorite was also the lowest. This furnishes explanation for the fact that the treatment with 0.5 part of chlorine, found necessary in one tank, was greater than the requirement for another, while the same treatment in the third caused numerous complaints of excessive and disagreeable odor. In disinfecting municipal water supplies or sewage there is a certain quantity of contaminating material present; once this is destroyed or removed, there is usually no further influx of 152918 14 210 PHILIPPINE WATER SUPPLIES noxious matter. Glaser, 10 in contradiction of the findings of Grether, 11 concluded that a single addition of disinfectant is as efficaceous as the same amount added at intervals in smaller quantities. His results may be correct for ordinary water or for sewage, but it is obvious that different conditions obtain for swimming pools, where the contaminating substances are being continually added. In the latter case the periodic addition of chlorine in small quantities, but sufficiently great to effect puri- fication, is not only preferable, but even necessary, to provide adequate protection to people using the pool. The fractional addition has the further advantage that the objectionable fea- tures of high dosage (odor, irritation of mucosae, and the like) are largely eliminated. Obviously the water in a swimming pool should be as clear as possible, not only because clear water makes a pool more attrac- tive and lessens the danger of accidental drowning, but also because it is more susceptible than turbid water to the disinfect- ing action of chlorine. Therefore water should be subjected to filtration, with or without coagulation, wherever practicable. Aside from its coagulating effect, the action of alum is beneficial in that it reacts with bicarbonated waters in such a way that the action of chloride of lime or copper sulphate is interfered with as little as possible. SUMMARY AND CONCLUSIONS The chemical purification of swimming pools has been studied with special reference to the action of copper sulphate and chloride of lime. The work was done on water that was turbid, high in bicar- bonate alkalinity, and bacteriologically unsatisfactory. Copper sulphate was found unsuited to a water of the type used. As much as 2 parts per million of available chlorine, adminis- tered as chloride of lime and at a single dose, failed to keep the bacterial content of the water within safe limits due to the rapid disappearance of available chlorine from the water. It was only with daily additions of chloride of lime that adequate puri- fication resulted. With this procedure, however, it was found possible to keep a pool bacteriologically clean for two weeks without change of water. There were noted no objectionable features arising from the large quantities of disinfectant added 10 Arch. f. Hyg. (1912), 77, 279. "Ibid. (1896), 27, 189. ' THE CHEMICAL PURIFICATION OP SWIMMING POOLS £ll (daily additions of 0.5 part of available chlorine per million parts of water). The advantages of the periodic administration of hypochlorites in small quantities over the addition of the same total amount at a single dose are discussed. The factors influencing chlorine consumption and the chlorine- binding power of various substances were studied. The tempera- ture of the water and the amount of light a pool receives greatly influence the decomposition rate of hypochlorites. Body products have an especially great binding power for chlorine, a fact that emphasizes the need of great personal cleanliness among users of swimming pools. Determinations of dissolved chlorides or of oxygen consump- tion give little or no indication of the purity of swimming-pool water. The tests that apparently give the most information are determinations of available chlorine and of chlorine-consuming capacity. In the purification of the water of swimming pools each case should be considered as a separate problem, since the procedure adapted to one may be entirely unsuited to another. Chemical study is as necessary as bacteriological to obtain the best results. The minimum quantities of hypochlorites necessary to maintain an excess of available chlorine should be first established by experiment, and these quantities should be administered at short, regular intervals. Once the dosage proper for ordinary circum- stances is known, it becomes an easy matter to keep a pool in sanitary condition. REPORT ON CERTAIN METHODS OF STERILIZATION OF WATER CONTAINERS The autoclave method of sterilizing with steam the demijohns and corks used in certain local artesian water distribution com- panies has not been satisfactory. The boilers used were too small to maintain the necessary temperature and pressure, and insufficient time was allowed for adequate sterilization, even had the necessary temperature been reached. It is doubtful whether sterilization could be effectively accomplished with steam at sufficiently low cost to ensure the companies a margin of profit at the existing prices for artesian water. The following methods were introduced into one of these plants, and supervision was maintained until the manner of operation was such that success was automatically assured. STERILIZATION OF CORKS The corks are boiled in water for ten minutes. They are kept in a 0.2 per cent solution of formaldehyde until ready for use. Just before insertion in the demijohn, they are rinsed with fresh water from the filling spout. STERILIZATION OF DEMIJOHNS The demijohn, as it comes from the consumer, is taken to the sink. Here it is closed with a cork (preferably of universal size, with easy-gripping handle), and the outside is scrubbed with soap and water. As far as possible, the water for the scrubbing is supplied by the overflow from the filling stand. After scrubbing, the demijohn is showered with fresh water from the reserve water tank, in which a circulation is thus main- tained. The cork is then removed and the demijohn is taken to a tank (A). Here the inside is rinsed with hot lye solution, kept at a temperature of 45° C. by a closed steam coil. Thence it passes to a tank (B), where it is rinsed twice with hot water, also kept at 45° C. by a closed steam coil. It now goes to the third tank (C), where it is filled with chloride of lime solution (two pounds to approximately a cubic meter of water, unheated except incidentally by the warm empty demijohns from tank B. After remaining in the chloride of lime solution for ten 212 METHODS OF STERILIZATION 213 ; minutes, the demijohn is taken to the filling stand. Here it is first rinsed by inversion over a fountain spray, with occasional turnings to assure thorough treatment. The demijohn is then filled as usual from the filling spout, after which a boy, with rubber gloves, inserts the sterilized and rinsed cork, as described under sterilization of corks. The demijohn is now ready to receive the paper cap and sealing wax, after which it is ready for transportation to the consumer. NOTES Following the plan outlined above, the demijohn never touches the floor from the time it is scrubbed until after it is corked. _Trom_^ump To waste ** Fig. 3. Plan of apparatus for washing, sterilizing, and filling demijohns used in artesian j water distribution. j The idea of sterilization with potassium permanganate was | abandoned, as the process was tedious, disagreeable to the opera- | tors, and, under present conditions, expensive. The chloride of lime bath is changed twice a day, with a daily output of from three to four hundred demijohns. The lye tank is refilled daily, the rinsing tank twice a day. The filler and rinsing spouts are provided with half -throw cocks, instead of ordinary valves, to economize time. 214 PHILIPPINE WATER SUPPLIES The three tanks are provided with overhead connections to fresh cold water, which may be used for filling the tanks, renew- ing rinse water, etc. RESULTS The methods outlined have effected economies in fuel, time, water, and chemicals. The time now necessary for a demijohn to make the complete cycle of the process is about fifteen minutes. The quality of the product obtained is satisfactory. Twenty- four hour counts made September 20 on two demijohns selected at random showed 4 and 40 colonies per cubic centimeter, re- spectively. Similar counts made on two samples submitted to this Bureau on September 26, after the last type of shower-rinse had been adopted, showed 4 and 20 colonies, respectively. Pre- sumptive tests for B. coli gave negative results in all four cases. BUREAU OF SCIENCE DIRECTIONS FOR THE COLLEC- TION AND TRANSMISSION OF WATER SAMPLES The following directions have been prepared by the Bureau of Science for general distribution to the public: Before requesting a water analysis, it is well to consult the District Health Officer or District Engineer. Furthermore it is advisable to communicate with the Bureau of Science, as it is possible that a reliable analysis of the source has been already made and that the information desired is already on file. Whenever possible, leave the taking of samples of water to the District Health Officer, the District Engineer, or other person qualified to do such work. In this way unnecessary analyses will be eliminated, undue expense will be avoided, and the analyses will be easier to interpret. Remember that the Bureau of Science can determine only the condition of a water as it arrives at the laboratory ; if a sample is incorrectly taken, if it is too old when it reaches the laboratory, or if necessary information regarding the source is withheld or is inaccurate, the results of an analysis will be misleading. QUANTITY OF WATER REQUIRED FOR ANALYSIS The minimum quantity necessary for making the ordinary physical, chemical, and microscopical analyses of water or sewage is 2.5 liters ; for the bacteriological examination, 100 cubic centi- meters. In special cases larger quantities may be required. For a complete mineral analysis, five liters should be sent. BOTTLES 1 When possible, obtain bottles directly from the Bureau of Science or through the Bureau of Health or Bureau of Public Works. These bottles are properly cleaned, sterilized, and packed in suitable containers for shipment. The bottles for the collection of samples shall have glass stop- pers, except when physical or microscopical examinations only are to be made. Pottery jugs or metal containers shall not be used. Sample bottles shall be carefully cleansed each time before 1 "The greater part of the material under this head and all under Time I Interval Between Collection and Analysis is quoted verbatim from Standard Methods for the Examination of Water and Sewage (1915), 1-2. 215 216 PHILIPPINE WATER SUPPLIES using. This may be done by treating with sulphuric acid and potassium bichromate or with alkaline permanganate, followed by a mixture of oxalic and sulphuric acids, and by thoroughly rinsing at least four times with water and draining. When clean, the stoppers and necks of the bottles shall be protected from dirt by tying cloth and thick paper over them. For shipment bottles shall be packed in cases with a separate compartment for each bottle. Wooden boxes may be lined with indented fiber paper, felt, or some similar substance or shall be provided with spring corner strips to prevent breakage. Lined wicker baskets also may be used. Bottles for bacteriological samples shall be sterilized. TIME INTERVAL BETWEEN COLLECTION AND ANALYSIS Generally speaking, the shorter the time elapsing between the collection and the analysis of a sample the more reliable will be the analytical results. Under many conditions analyses made in the field are to be commended, as data so obtained are frequently preferable to those made in a distant laboratory after the composition of the water has changed en route. The allowable time that may elapse between the collection of a sample and the beginning of its analysis cannot be stated definitely, as it depends upon the character of the sample and upon other conditions, but the following may be considered as fairly reasonable maximum limits under ordinary conditions : Physical and Chemical Analysis, Hours. Ground waters 74 Fairly pure surface waters 48 Polluted surface waters 12 Sewage effluents 6 Raw sewages 6 Microscopical Examination. Hours. Ground waters 72 Fairly pure surface waters 24 Waters containing fragile organisms immediate examination. Bacteriological Examination. Hours. Samples kept at less than 10° C. 6 COLLECTION OF SAMPLES Rinse the sample bottle several times with the water to be examined, the last time filling the bottle completely before drain- ing. Then fill the bottle and insert the stopper firmly, leaving TRANSMISSION OF WATER SAMPLES 217 a very small air space between the surface of the water and the h stopper. A piece of cloth or thick paper should be tied over the ; stopper and neck to insure cleanliness and security. The sample submitted for analysis should be a representative \ one. Thus, if the water is from a pumping well, house connec- l tion, or any piping system, the water should be allowed to flow ; long enough to clean out of the small pipes any accumulation of rust or sediment, as well as the water that has been in con- ; tact with the pipe for some time. If taken from a surface well or surface stream, the sample should be taken from a depth sufficient to avoid both surface scum and bottom mud. If taken from a spring, the water should be sampled, whenever possible, where it leaves the water-bearing stratum. BUREAU OF SCIENCE MANILA, P. I. WATER Laboratory No.. ^ Day and hour of collection ..mQ.l-.Xn>_, location S&4&&?. £.ckTi£^__Crv»x* $»Waxijm-. __Jl«i*AuiA^fe „ - ----- - SMs^-AO...., WO. Source ***»^^ T ^$M&.W^^i3,M RepoH Qn eanitary survey _^^ u _^ rL _^^ Type J*H£crvi? , ^b=a. When installed. §v^r>ju_}.J51l. _ ..%<*iV^^..«£**4^.,^ Capacity per minute: ' . . , - . , t Flows .rrr. — ; 1 *^ !: '- ■ - — Pumps &J}.A*%*^.-&4^-J??>v>yxx£ju _9^*-*^.Jl£7^rv_._.V^ " " _&:kajfc0v gJ|p-ttO. Nature of examination M-^y^Joj^.^ _ _ Analysis requested by:.. o^vy-r^.<^^\^^L Fig. 4. Bureau of Science form No. 41 properly filled out. DATA ACCOMPANYING SAMPLE Of great importance, also, are the general data relating to the conditions of the source and its surroundings. These data are listed on one side of the Bureau of Science water analysis card (Form No. 41). A copy of this form, properly filled out, is shown in fig. 4. Most of the data requested need no explanation. A few, how- ever, deserve special emphasis. 1. Location. This should be stated as fully and as accurately as possible. A properly stated location should be complete enough to prevent the slightest possibility of confusion with any other point in the vicinity. 2. Quality of water. Any marked color, odor, turbidity, or 218 PHILIPPINE WATER SUPPLIES other abnormal characteristic should be noted. If the water is normal when drawn, but develops turbidity, color, or odor on standing, a statement of these changes should be made. 3. Local opinion. What do people in the neighborhood think of the water? In case medicinal or other properties are as- cribed to it, these should be stated. 4. Nature of examination. State the purpose for which the analysis is desired, such as "for boiler purposes," "for pot- ability/' etc. 5. Report on sanitary survey. This should include all data relating to the surroundings of the source that might have affected the quality of the water at the time of sampling or that might affect it in the future. Information on the following points is especially valuable : a. Distance and relative number of nearest dwellings, out- houses, etc. 6. Condition of immediate surroundings. Is adequate drain- age provided for waste water, or does it accumulate near the source, possibly contaminating it? Are washing, bathing, etc., carried on nearby? Are pigs or other animals allowed to come near the source? c. Topography. Is the source lower or higher than its sur- roundings? Is it liable, therefore, to be contaminated by sur- face run off? Are there any other topographic features that might affect the water? d. Nature of soil and subsoil. e. Weather conditions prevailing when sample was taken. /. Variations in quantity and quality of water with season, weather changes, tide, etc. The foregoing directions for sampling water are primarily for potability tests. For samples for technical purposes, such as suitability for boilers, etc., the data required under "(5) Report on sanitary survey," -may be disregarded. However, it is very important that a representative sample be secured, and the con- tainer should be thoroughly cleaned and well stoppered. :,. .■ . . ■...;:■ ^ ■■:::;:■ :/ -V ^ ' F : £ " ' '* £■ ■■-■' I; ;#i.'v : : ^^: ; -. : :.:. : ■:;■;■ :.\"; : ;;fi r '"' ! .-C.^'..r,-,. ; , T i- * ta A^fc^i--^ ":;■.■■:. p-' :-::.—■ V: ? : ~ '^ ^m^ w^ : -W-- '"t«llii J' .. i' : ^^^fe-i^T.v^ J£ W lliii 2 3 o o Z5 o < CO CO o Q O O X o 2 < cc (5 < T #i! y -| : W*&^ I4£i M r s f:.,- .,.■■:■... -*;W^>- ^'^ > M^S3& ■■^'^■■^^ ' , ' ■■■■■::■■■■,■ .: .J;*;: o ■.:; :: :f; , ■-~ ■ ■'■■ : :- :- .. ■*■■ ■rt-' n.^4M-h.^ »t#^i#i^ « i % 1 II ■V -f-jl wge* £■■ :ii: . iii: Ife;.' ill!*- \'. c *■;'