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A TREATISE

da

THE FORCES WHICH PRODUCE

TBB

ORGAlflZATION OF PLANTS.

WITH AN APPENDIX,

CONTAINING SEVERAL MEMOIES ON CAPILLARY ATTEACTIOS, ELECTIICITT, AND

THE CHEIICAL ACTION OF LIGHT.

■ T

JOHN WILLIAM DRAPER, M.D.,

PBonssoB OP CHuamr in thi uinrKKsnT of xxw-toke.

7594 3 O

NEW-YORK:

PUBLISHED BY HARPER & BROTHERS,
No. 82 Clipf-Strbbt.

18 44.

LIBRARY

I

Entered, according to Act of Congress, in the year 1844, by

Harper & Brothers,
In the Clerk's Office of the Southern District of New- York.

PREFACE.

In the autumn of 1833, during a period of convalescence from a severe attack of the fever of
the Southern States, my thoughts were first turned to the connexion of Chemistry with Vegetable

■

Physiology.

At that time, as the works on Chemistry show, comparatively but little advance had been made
in this interesting department of science. In the most popular treatises, Organic Chemistry consisted
chiefly of a descriptive history of the acids and bases of the vegetable and animal kingdoms.

It is impossible for any one to witness in those warm climates the rapidity with which all the
operations of vegetable life are carried on, without having his thoughts directed to the obvious con-
nexion which exists between these phenomena and external agents. Even in the opinion of the
uneducated planter, the rapidity of vegetable growth is connected with the warmth of the season,
and the occurrence of favourable rains, and the brilliancy of the sun.

A seed which has been buried in the ground a few days, makes its appearance above the surface.
It soon puts forth its leaves, which turn green in the light, and becomes an active laboratory of all
kinds of chemical and mechanical processes. Starch, gum, sugar, and a variety of other substances
are formed from inorganic matter, water is drawn up in large quantities from the ground, and
evaporated from the leaves.

All these phenomena unquestionably depend on the common laws of physics. Oar interest in
them is greatly increased by the close resemblance of many of them to things taking place in the
case of animal systems. The productions of vegetable life are, many of them, also apparently the
productions of animal life. The physical processes which appear in one of the great classes of
living beings, appear in the other too. Inquiries into the nature of the vital processes of plants end
in resolving problems connected with the physiology of animals.

In every plant there are two prominent operations carried forward : the production of organic
matter, and its distribution through the various parts of the vegetable system. It is to the consid-
eration of these that the following pages are chiefly devoted. As to the various transformations
which take place in the interior of these organisms, and the chemical principles involved in those
changes, anything which I might ofier would be insignificant, compared with the splendid results
which have been obtained by the German, French, and EngUsh chemists during the period which
has elapsed since these researches were first undertaken.

Any one who peruses the works on Botany and Vegetable Physiology must be struck with the
inexact views which are entertained on the mode of action of the solar rays in producing the green
colour of plants, and efiecting the decomposition of carbonic acid gas. Yet this is unquestionably
the most remarkable result in physiological and physical science. It is the transmutaUon of inor-
ganic into organized matter. With a view of giving clearness and precision to those vague notions,
I have devoted much of the following work to this point, showing how, as plants grow in water or
in air, they are furnished, upon phvsical principles, with nutrient material ; how, upon this, the sun-

IV

PREFACE.

beam acts, and how, of the rays of which that beam is composed, the yellow ray of light is the
operative principle. The mode by which the resulting decomposition is effected leads to an in-
vestigation of the absorption of light.

As will be seen from the Appendix, in these investigations I have not restricted myself exclusively
to the subjects before me, but have, in most instances, followed them out into their physical details.
The chapters of the Appendix have all been published in various American and foreign works, each
chapter being a memoir, more or less complete, on the topic on which it treats. In that Appendix,
therefore, there will be found a large amount of experimental matter, of which an immediate use is
not made. But in philosophy no new facts are superfluous. At first sight, there might seem to be
no connexion between the fixed lines of the solar spectrum and the production of chlorophyl, yet, as
will be hereafter understood, very great use may be made of the former in investigations on the
nature of the latter.

The remark which has just been made respecting the vague ideas which are entertained in rela-
tion to the mode of action of light, might also have been made in relation to capillary attraction.
This force, with exosmose and endosmose, are very favourite resources of the botanist in his diffi-
culties. In the chapters in which these topics are considered, I have endeavoured to show the
true relation which exists between endosmosis and capillary attraction, and how the latter itself
springs from electric excitement. I have shown how, in strict conformity with this principle, the
flow of the sap and the circulation of the blood may be explained ; the systemic circulation, for ex-
ample, arising as a necessary consequence of the deoxydation of arterial blood.

The theory of these circulatory movements taking place in organized structures I have not here-
tofore published, though they have been taught in my lectures in this University. It will be seen
that the peculiarity is in tracing the action to chemical changes ; that the systemic circulation arises,
as has just been said, from the deoxydation of arterial blood ; the pulmonary circulation from the
oxydation of venous blood ; and the flow of sap in flowering plants from the carbonization of water
by the sunlight in their leaves.

It might be supposed that Chapter XVIII., Ap., is intended as a reply to the criticisms on some
parts of Chapter XIII., which have been published by M. Edmond Becuueeel, in the Annales de
Chimie. When that chapter was written, I had not, however, had the opportunity of seeing his
valuable memoir. The experiments there given were not made with the iodide, but the bromide
of silver, a circumstance which relieves me from much of the weight of the criticisms of that chem-
ist. It is not only from my own experiments, but also from those of Sir J. Herschel, that I am led
to differ from M. BEcauEREL, in regarding the iodide and bromide of silver as exhibiting very dif-
ferent changes in the spectrum. M. BEcauEREL's idea that there is but little difference between them,
does not seem to be consonant to experiment.

Of the Appendix, several chapters have already been translated into different European lan-
guages, and a variety of criticisms upon them have been published. It is this circumstance which
has caused me to hasten the printing of the whole of these papers in this collected form now offered
to the public. Whatever care be taken in the preparation of such translations, it will necessarily
happen, that on many points mistakes will be made as to the meaning and views of an author.
This has happened in the present instance, both in Germany and France : for example, in Chapter
XV., which has been republished in Paris in the Annales de Chimie, errors of the kind occur.
Those who are familiar with these matters will find, when they look over th^ papers in the form

PREFACE. V

now given, that views have been thus accidentally imputed to the author which he does not enter-
tain.

It did not enter into my plan to reprint amy of the valuable memoirs which have been published
by other chemists on these topics, more especially on those relating to the chemical agencies of
light I may, however, direct the attention of the readers to a description by Sir J. Herschel, of
the spectrum alluded to in the Appendix (645). It is inserted in the Pliilosophical Magazine for
February, 1843. In this paper will be found what probably will prove to be the true theory of the
action of light on Daguerreotype plates, and the reader of this volume will be the more interested
in it, inasmuch as it contains criticisms on several of the leading doctrines here set forth.

The different chapters of the Appendix are, for the most part, reprinted from sources mentioned
under the title of each. In a few instances slight changes have been made in them ; changes which
have been rendered necessary by the mode in which they were originally published. Thus some
of these papers were printed in various American, and others in European journals, and it some-
times happens that experiments are in consequence described twice over. This repetition 1 have
avoided by removing the paragraphs involved. In this manner I have entirely omitted to republish
in this work a paper on the constitution of the atmosphere, given in the Philosophical Magazine for
October, 1838, because nearly all its experimental matter had been previously pubUshed in the
American Journal of Medical Sciences, and is given in Chapter VI.

The time has now arrived when both Vegetable and Animal Physiology are to have their founda-
tions laid on Chemistry and Natural Philosophy, the only basis which can elevate them from their
present deplorable position to that of true sciences. It is with this impression that the explanations
which I have given in this book of the mode by which light acts in determining organization, and
of the mechanical causes by which such organized matter is transmitted from point to point of
living systems (for these are the leading facts which this work is designed to illustrate), are oflered
to the attention of chemical philosophers.

John William Dkapbk.

Unhertity of Jie»-Yorh, October 1, 1844.

N.B. — The references to the Appendix are made by the number of the paragraph, thus (Ap., 100,
101). When the place referred to is in the body of the work, the letters Ap. are omitted, thus
(100, 101).

CONTENTS.

C

INTRODUCTION.

OENERAI. REMARKS ON THE INTLHENCE OF PHYSICAI, AGENTS ON ORGANIZATION AND LITK.

Object of the Work stated. — Connexion of Organization with the Imponderable Principles. — General Laws
direct all Astronomical Occurrences and Physical Events. — Transitory Nature of all Combinations, and
especially those which are Organized. — Time is an Element of Life. — Inorganic Changes are brought about
by Physical Laws, as also is the Extinction of Living Races. — Influence of Climate on the Distribution
and Character of Animals and Plants. — Relations between Animated Forms and the Atmosphere. — Influ-
ence of Currents in the Air and in the Sea. — Gradual Emancipation of the Higher Races from the Direct
Action of External Agents Page 1

CHAPTER I.

ON THE ACTION OF THE SUNBEAMS IN PRODUCING ORGANIZED BODIES.

The Growth of Confervae in Water. — Production of Green Matter by Spun Glass and Inorganic Bodies. —
It requires a Sporule, Cell, or Objective Germ. — Mode of Diffusion of Gases into Water. — Influence of
Temperature on the Process. — Action of the Sun's Rays on these Gases. — Two Atmospheres around the
Earth. — Sources of Supply of the expended Gases.

Application of these Principles to the Production of Chlorophyl in Leaves. — The Digestion of Plants . 15

CHAPTER II.

ON THE MECHANICAL CAUSE OF THE FLOW OF THE SAP IN PLANTS. IT IS DUE TO THE CARBONIZATION
OF WATER IN THE LEAVES BY THE LIGHT OF THE SUN.

The Flow of Sap and Circulation of Blood are probably due to the same Physical Cause. — Amount of Water
circulating in Plants. — Botanical Theory of the Flow of Sap — fails for the descending Sap.

Capillary Attraction described. — Elevation or Depression of Liquids depends on their wetting or not wetting
the Tube. — No Flow in an ordinary Capillary Tube. — Conditions for producing a Flow — such as Evapo-
ration, Decomposition, and Solution. — Endosmosis produced on these Principles by Solution. — Dutrochet's
Experiments. — Explanation of them. — General Law of these Movements. — Force with which they take
place. — Capillary Attraction due to Electricity.

Application of these Principles to the Ascent of the Sap. — Exhausting Action of the Leaves. — Cause of the
f Descent of the Sap.
/ The Light of the Sun is the Cause of the Flow of the Sap both in its Ascent and Descent . . .22

^ CHAPTER III.

) ON THE MECHANICAL CAUSE OF THE CIRCULATION OF THE BLOOD.

/Ancient Theory. — Description of the Systemic, Pulmonary, and Portal Circulation. — General Law of Move-
ment.— Capillary Relations of Arterial and Venous Blood to the Tissues. — The Systemic Circulation is
due to the Deoxydation of Arterial Blood, and its Direction is therefore from the Artery to the Vein.
Pulmonary Circulation. — Capillary Relations of Arterial and Venous Blood to Atmospheric Oxygen. — Pul-
•j^-- monary Circulation is due to the Oxydation of Venous Blood, and its Direction is therefore from the Venous
I to the Arterial Side. — Uses and Action of the Heart.

I Portal Circulation. — Capillary Relations of Arterial, Portal, and Venous Blood to the Liver. — Three Sources
; of Force in conducting the Portal Circulation.

Action in Asphyxia. — Case of obstructed Trachea 33

CHAPTER IV.

ON THE PHTSICAL CONSTITUTION OF THE SUNBEAMS AND ON THE PRISMATIC SPECTRUM.

Modes of isolating the Coloured Rays. — Newton's Prismatic Spectrum. — Theory of the Colours of Light. —
Illuminating Calorific and Chemical Powers of the Spectrum. — Newton's Processes for purifying the
Spectrum. — Fixed Lines. — Melloni's Experiments on the Distribution of Heat. — Physical Independence
of Heat. — Herschel's Experiments on the Thermic Spectrum. — Chemical Action of the difiierent Regions
of the Spectrum on a Daguerreotype Plate. — Chemical Action on other Bodies . . . .41

CHAPTER V.

ON THE INTERFERENCE SPECTRUM.

Defects of the Prismatic Spectrum. — Mode of forming the Interference Spectrum. — Its Peculiarities. — The
Distribution of the Colours, and Law of their Intensities. — Reflected Int«rference Spectrum. — Its Fixed
Lines. — Wave-lengths of the Seven Great Rays.

viii CONTENTS.

Melloni's Researches on the Distribution of Heat in Perfect Prismatic Spectra. — Apparent Identity of Light
and Heat.

Distribution of Chemical Force in the Interference Spectrum. — Comparison of the Fixed Lines in the Pris-
matic and Interference Spectrum. — Mode of Defining Chemical Effects by Wave-lengths or by Times of
Vibration. — Impression on Bromide of Silver. — On Chloride of Silver. — Total Change in the Distribution
of Heat in the Interference Spectrum Page 52

CHAPTER VI.

jA experi.ments proving that it is in the yellow region of the spectrum that the reduction

/ of carbonic acid by the leaves of plants takes place.

N Several Imponderable Principles in the Sunbeam. — Sennebier's Experiments to determine to which of these

,/ the Effect is due. — Experiments of Morren and Daubeny. — Defects of the Mode of operating with Absor-

/ bent Media and Glasses.

^ Decomposition of Carbonic Acid in the Prismatic Spectrum. — Process of conducting the Experiment. — It. is

/' in the Yellow Region that the Decomposition takes place. — No Gas is evolved in the Violet . . 61

CHAPTER VII.

ON THE VARIOUS IMPONDERABLE AGENTS EXISTING IN THE DIFFERENT REGIONS OF THE SPECTRUM.

Different Agents existing in the Spectrum. — Description of the Tithonic Rays. — Their Name. — Physical
Independence of Heat. — Of the Chemical Rays. — Their Constant Association with Light. — Detithonizing
Action of Yellow Solutions. — Argument for their Independence. — Other Invisible Principles in the Sun-
beam, such as the Phosphoric Rays. — Examination of the Theory of M. Becquerel . . . .65

CHAPTER VIII.

/^ IT IS YELLOW LIGHT WHICH CONTROLS THE PROCESS OF DIGESTION IN PLANTS.

Examination as to which of the Principles mentioned in the preceding Chapter is engaged in the Decompo-
sition of Carbonic Acid. — It is not Radiant Heat. — Melloni on the Ideal Coloration of Heat. — Analogies
in the Case of Light. — Herschel's Results.

It is not the Tithonic Ray. — Maximum of Decomposing Action for Carbonic Acid and Carbonaceous Com-
pounds, like the Retina, is in the Yellow Ray. — Hence the Maximum of Visible Illumination coincides
therewith 72

L

s

CHAPTER IX.

THEORY OF THE ABSORPTION OF THE TITHONIC RAYS AND LIGHT.

Estimate of the Extent and Power of the Solar Radiations. — Influence still exists in the Moonbeams. — Ab-
sorptive Action of Chlorine and Hydrogen. — Detithonization of the Ray and Tithonization of the Gaseous
Mixture. — Curve and Law. — Deductions as to Latent Light and Definite Action. — Functions discharged
by the Chlorine and Hydrogen respectively ........... 76

CHAPTER X.

THEORY OF IDEAL COLORATION.

Former Observations on Colours in the Chemical Rays. — Nomenclature derived from it. — Case of the Chry-
sotype. — Case of Bichromate of Potash. — Laws deduced. — Control of Optical Forces over Chemical Ef-
fects.— Application to Spectrum Stains. — Herschel's Law for Light. — Explanation of Variable Effects in
Films of different Thickness. — Mode of Action of the Tithonic Rays 84

CHAPTER XI.

ON THE MODE OF ACTION OF LIGHT IN DIRECTING THE DIGESTION OF PLANTS.

Connexion between Absorption and Chemical Action. — Radiant Matter is absorbed in producing different
Effects. — Reappearance of the Force expended. — Laws of Preliminary Absorption and Definite Action
observed by Plants. — Increased Rapidity of Vegetation implies increased Brilliancy of the Incident Light.
— The Sun probably a Periodic Star. — Description of the Mode of Action of Light and Radiant Heat on
Leaves . . . . . . . . . . . . . ... 91

CHAPTER XII.

ON THE NERVOUS AGENT OF PLANTS.

/^ Subdivisions of Nervous Mechanism in Animals. — Excessive Rapidity of Motion arising in these Nervous
Actions.-^Plants constructed on a Surface-type. — Oxidating Processes replaced in them by the Application
of Radiant Heat. — Difference of Action on the Upper and Under Face of the Leaf. — Light applied to one,
and Heat to the other Face. — Specific Effects produced by the different coloured Rays. — Effects of these
Radiant Principles on the Lower Tribes of Animals. — Centralization of Apparatus for different Functions.
—Analogies between Nervous Action in Animals and Imponderable Agency in Plants.— Vegetables are
the Representatives of the Resultant Action of the Ethereal Agents on Ponderable Matter. — Conclusion 99

*^

\

CONTENTS OF THE APPENDIX.

CHAPTER I.

EIPEHIMENTS MADE TO DETERMINE WHETHER LIGHT EXHIBITS ANT MAGNETIC ACTION.

Character of the Sky in Virginia. — Examination of Mr. Christie's Experiment. — Needles not affected by the
Violet Rays. — No Reaction between a Magnet or Voltaic "Currents and Light • . . Page 3

CHAPTER H. •

OW THE TIDAL MOTIONS OF MOVABLE ELECTRIC CONDUCTORS.

Description of the Phenomenon. — The Polar Wires act as Centres of Attraction.— They produce Tides. —
Cause of the Oscillations. — Cause of the Spiral Motions ........ 8

CHAPTER HI.

ON THE INTERSTITIAL MOVEMENTS WHICH TAEE PLACE AMONG THE PARTICLES OF BODIES.

Of the Mode of Passage of Liquids through Pores. — Endosmosis. — Percolation through Gum Lac, Gold
Leaf, Mica, etc. — Slow Motions in the Parts of Solid Bodies, as in Silver Coins. — Percolation through
India Rubber.^Conditions of Equilibrium. — Percolation through Masses of Water. — Percolation through
excessively thin Films of Water, as Soap Bubbles. — Analysis of Gas on the Exterior and in the Interior
6f the Soap Bubble. — General Law of the Phenomenon deduced ....... 13

CHAPTER IV.
ON INTERSTITIAL MOVEMENTS, being a Continuation of the preceding Chapter.
Diffusion takes place between the Panicles of Heterogeneous Bodies. — Differs from Chemical Attraction. —
Action of Binary Arrangements. — Action of Ternary Arrangements. — Decompositions by Binary Arrange-
ments.— Decompositions by Ternary Arrangements ......... 23

CHAPTER V.

THE PHYSICAL THEORY OF CAPILLARY ATTRACTION.

Importance of Capillary Attraction in Physiology. — Capillary Attraction is an Electrical Phenomenon. — Its
Physical Theory. — The Effect varies with Variations of Electric Disturbance. — Takes place between
Bodies of different Forms. — Physiological Illustrations 34

CHAPTER VI.

ON THE GREAT MECHANICAL FORCES GENERATED BY THE CAPILLARY ATTRACTION OF CELLULAR TISSUE.

Physiological Relations of Cellular Tissue. — Force with which Gases and Liquids pass through Cellular
Tissue. — Disturbing Action of Leakage. — The Capillar)' Force overcomes powerful Mercurial Pressure.
— Dalton's Hypothesis. — The Tissue is the Origin of the Force. — Its Absorbent and Condensing Action.
— ^ oltaic Batteries ma_v be used for producing great Pressures. — Gases pass when resisted by the Force
of many Atmospheres. — The condensed Gas acts as a Vacuum. — Co-ordination of the Results of Dalton,
Graham, and .Mitchell. — Disturbing Agencies. — Disturbance by Variation of Temperature. — Physiological
Experiments and Remarks .............. 42

CHAPTER VII.

THE PHYSICAL THEORY OF ENDOSMOSIS.

Relation of Endosmosis to Capillary Attraction. — Cases of reported Decompositions. — Can be produced by
Inorganic Masses, and therefore not due to Vitality. — Water made to wet Mercury. — Voltaic Battery- con-
trols Capillary Attraction. — .\ction of Inorganic Tissues. — Water passes through excessively small Pores.
-—Hydraulic Currents. — Deposites produced by Endosmotic Currents. — .\pparent Decomposition of Metal-
lic Salts by Membranes. — True Theory of it. — General Conclusion that Endosmosis is nothing more than
common Capillary Attraction, and never occasions true Decompositions 57

CHAPTER VIII.

ON THE USE OF A SECONDARY WIRE AS A MEASURE OF THE RELATIVE TENSION OF ELECTRIC CURRENTS.

Object of the .Memoir. — .\ction of a Secondarj- Wire. — Description of the Torsion Galvanometer. — Resist-
ance of the Secondary Wire under Variations of Tension — Condition of the C^urrent never changes. —
Tension rises with Length of Wire and with Distance of Plates. — Relation between Quantity and Tension.
— Theory of Tension of the Voltaic Battery. — Known Methods of increasing Tension of Currents. — General
I^aw- — Case of Thermo- Electricity and Slachine Electricity. — Voltaic Spark before Contact in Vacuo 73

&

X CONTKNTS Ol' 'I'HK APPKiNUIX.

CHAPTER IX.

ON THE ELECTROMOTIVE POWER OF HEAT.

Object of the Memoir. — Evperimental Arrangement to determine the Electromotive Power. — Temperatures
calculated from Quantities of Electricity. — Increase of Tension with Increase of Temperature. — Depends
on increased Resistance to Conduction. — Quantity of Electricity independent of heated Surface. — In Ther-
mo-electric Piles, the Quantity of Electricity proportional to the Number of Pairs. — Best Forms of Con-
struction of Thermo-electric Pairs Page 90

CHAPTER X.

EXPERIMENTS ON THE CHEMICAL ACTION OF SOLAR LIGHT.

Action of Absorbent Media. — Ideal Coloration of tlie Chemical Rays. — .Specific Absorption. — Colorific Ab-
sorption.— Calorific Absorption. — Specific Absor|)iion of the Chemical Rays. — Effect of Yellow Solutions.

Decomposition of Carbonic Acid by Leaves. — Penetration of Dimensions in Gases. — Decomposition of Car-
bonic Acid under various coloured Media. — Gas from Leaves contains Nitrogen. — Chemical Rays of dif-
ferent Colours. — Identity of Volume in the absorbed and evolved Gas. — Cause of the Decomposition.

Ritter's Experiments of the Non-oxygenation of Phosphorus.

Decomposition of the Salts of Silver. — Prismatic Spectruin on Bromide of Silver. — Interference of Chemical
Rays. — Salts decomposed by Light. — Moonlight and Artificial Flames are inactive.

Of Perihelion Motions. — Dew of Water and Mercury. — Iodine. — Chloride of Gold. — Non-deposition on a
Glass Plate. — Current Action. — Action of P'lame. — Action of Metal Screens. — Protecting Action of a
Metal Ring. — Is there Electricity in the Solar Ray?

Cause of the Green Colour of Leaves. — Plants grow in Lights of various Colours. — Seeds also germinate in
/Red, Yellow, and Blue Light. — Chemical Rays of different Colours 99

^ Note added to the foregoing Chapter.

AN ACCOUNT OF SOME EXPERIMENTS MADE IN THE SOUTH OF VIRGINIA ON THE LIGHT OF THE SUN 133

CHAPTER XI.

ON THE PROCESS OF DAGUERREOTYPE, AND ITS APPLICATION TO TAKING PORTRAITS FROM THE LIFE.

Daguerreotype Portraits from the Life first taken. — Spectral Images. — Preservation of the Sensitive Plate
increases the Sensitiveness. — Modifications in the Daguerreotype Process. — Moonlight, Artificial Light,
and Drummond's Light, are all Active. — Description of the original Process of taking Portraits from the
Life 136

CHAPTER XII.

ON SOME ANALOGIES BETWEEN THE PHENOMENA OF THE CHEMICAL RAYS AND THOSE OF RADIANT HEAT.

Object of the Memoir. — On the Daguerreotype Process. — Chemical Constitution of Daguerreotype Pictures.
— Spectral Images. — Film of Iodide torn off Mechanically. — Iodine is not evolved, but corrodes the Plate.
— The Chemical Rays are absorbed. — The Photographic Effects are transient. — The Chemical Rays are
not conducted. — They become Latent. — Optical Qualities control Chemical Action. — The Active Rays
are absorbed, and the Complementary reflected. — Relation of Optical Forces and Chemical Affinities 144

Note added to the preceding Chapter.

ON CERTAIN SPECTRAL APPEARANCES, AND ON THE DISCOVERY OF LATENT LIGHT .156

CHAPTER XIII.

ON A NEW IMPONDERABLE SUBSTANCE, AND ON A CLASS OF CHEMICAL RAYS ANALOGOUS TO THE RAYS OF

DARK HEAT.

Analogies between the Chemical Rays and Heat. — New Nomenclature proposed. — Tithonic Rays. — In-
dependence of Tithonic Rays and Light. — Independence of Tithonic Rays and Heat. — Dark Tithonic
Rays . . . .■ 158

Note added to the preceding Chapter.

ON THE RAPID DETITH0NI2ING POWER OF CERTAIN GASES AND VAPOURS, AND ON AN INSTANTANEOUS MEANS

OF PRODUCING SPECTRAL APPEARANCES ...... 16.5

CHAPTER XIV.

ON A NEW SYSTEM OF INACTIVE TITHONOGRAPHIC SPACES IN THE SOLAR SPECTRUM ANALOGOUS TO THE FIXED

LINES OF FRAUNHOFER, AND ON THE TITHONOTYPE.

Mode of Producing the fixed Lines. — Description of them. — Difficulty of obtaining them in the Yellow and

Green.
Daguerreotypes are dotted Surfaces. — Mode of copying them by the Tithonotype. — Polarized Structure of

the Daguerreotype Film . . . . . . . . . . • .169

CONTENTS OF THE APPENDIX. xJ

CHAPTER XV.

OK THE DECOMPOSITION OF CABBONIC ACID GAS AXD THE ALKAUXE CAEB0NATE8 HI THE UGHT OF THE SUV,

AXD ON THE TITHOXOTTFE.

Dr. Dauberiy's Experiraenis. — Importance of the Subject. — Decomposition in the Prismatic Spectrum. — De-
composition under Absorbent Media. — Decomposition is due to Light. — Disturbing Causes. — Analysis of
Gas evolved. — Decomposition of Saline Bodies. — Production of Nitrogen. — Disappearance of Oxygen. —
Character of Chlorophyl.

Tiihonotypes in Copper. — Detithonizing Power of Gases ........ Page 175

CHAPTER XVI.

DBSCKIFTION OF THE TITHONOXETBK, AM niSTRUXE.Vr FOR XEASUKING THE CHEJOCAL FOECE OF THE DtDIGO-

TITHONIC RATS.

The Instrument consists of a Mixture of Chlorine and Hydrogen. — It is acted upon by Lamp Light, an Elec-
tric Spark at a Distance, &-c. — Chlorine and Hydrogen unite in Proportion to the Amount of Light. — Mode
of measuring out known Quantities of Rays. — The Maximum of Action is in the Indigo Space.— Construc-
tion of the Instrument. — Theoretical Conditions of Equilibrium. — Preliminary .\djustraenl. — Method of
continuous Observation. — Method of interrupted Observation. — Remarkable Contraction and Expansion 187

CHAPTER XVII.

O.N TITHOXIZED CHLORIXK.

Description of the Experiment. — The Change in the Chlorine is not Transient. — There are two Suges in
the Phenomenon. — Rays are absorbed in producing this Change. — It is the Indigo Ray which is absorbed.
— The Action is positive from End to End of the Spectrum. — The Indigo Ray forms Muriatic Acid, as
well as produces the Preliminary Tithonizaiion. — Change in other Elementary Bodies. — Verification of
the preceding Results with the Tithonometer 198

CHAPTER XVIII.

FARTHER CONSIDERATIONS ON THE EDSTEXCE OF A FOrETH UIPONDERABLE.

Defects of former Eridence. — A new Photometer. — Measures of the Light transmitted by Coloured Solutions.
— Explosion of Chlorine and Hydrogen by a distant Electric Spark. — Absorptive Action of Media.

The Absorptive Action on Light and the Tithonic Ravs follows different Laws.

Opacity of Glass for Phosphoric Rays. — Determination of the Refrangibility of the Phosphoric Rays of an
Electric Spark. — Refrangibility of the same Rays in the Voluic .\rc of Flame. — Professor Henry's Ex-
periments.

These Facu sene to prove that there are more than three Imponderables 205

\

INTRODUCTION.

GENERAL REMARKS ON THE INFLUENCE OF PHYSICAL AGEIVTS ON ORGANIZATION

AND UFE.

Contents : Object of the Work stated. — Connexion of Organization with the Imponder-
able Principles. — General JLatcs direct all Astronomical Occurrences and Physical
Events. — Transitory Nature of all Combinations, and especially those which are Or-
ganized.— Titne is an Element of Life. — Inorganic Changes are brought about by
Physical Laws, as also is the Extinction of Living Races. — Influence of Climate on
the Distribution and Character of Animals and Plants. — Relations between Animated
Forms and the Atmosphere. — Influence of Currents in the Air and in the Sea. —
Gradual E/nancipation of the Higher Races from the Direct Action of External
Agents.

1. The rapid progress of organic chemistry has recently drawm the attention of sci-
entific men to manv remarkable relations which exist between animated beings and the
inorganic world. For a long period, physiological doctrines, the spirit of which, for
many ages, has undergone but little change, offered an insurmountable barrier to the
application of methods of physical research to problems connected with the phenome-
na of Ufe. On these, in our times, a successful inroad has been made, chiefly through
the aid of improved methods of chemical analysis. In a philosophical point of view,
it was the office of the seventeenth century to unfold the doctrine of universal gravita-
tion, to assign proper causes for the motions of the celestial bodies, and to develop the
great doctrines of astronomy. It was the office of the eighteenth to lay the founda-
tions of physics and chemistry, or of that group of sciences which embraces the rela-
tions and reactions of atoms. It is the office of the nineteenth to discover the laws
which obtain in the complicated structure of animated beings, those laws which give
rise to the mysterious phenomena which we call life.

2. This book, in which will be found some facts which it has happened to its author
to discover, is offered as an humble contribution among those more brilliant gifts with
which Germany, and France, and England have lately enriched vegetable and animal
physiologv. It treats of a subject which forms the connecting Irak between pure chem-
istry and those higher sciences. The great idea which it is designed to illustrate is

A

2 CONNEXION OF ORGANIZATION WITH THE IMPONDERABLES.

that which connects the production and phenomena of organized beings with the im-
ponderable principles.

3. In this work the existence of the Vital Force of physiologists — as a homogeneous
■f and separate force — is uniformly denied. The progress of science shows plainly that

living structures, far from being the product of one such homogeneous power, are rather
the resultants of the action of a multitude of natural forces. Gravity, cohesion, elasti-
city, the agency of the imponderables, and all other powers which operate both on
masses and atoms, are called into action, and hence it is that the very evolution of a
living form depends on the condition that all these various agents conspire. There is
no mystery in animated beings which time will not at last reveal. It is astonishing
that, in our days, the ancient system, which excludes all connexion with natural phi-
losophy and chemistry, and depends on the fictitious aid of a visionary force, should
continue to exist : a system which, at the outset, ought to have been broken down by
the most common considerations, such as those connected with the mechanical princi-
ples involved in the bony skeleton, the optical principles in the construction of the eye,
or the hydraulic action of the valves of the heart.

4. In their origin, all those important ideas which now constitute modern science
have been obscurely and imperfectly set forth. It is not given to the human mind,
when it emerges from the darkness of ignorance, any more than to the human eye,
when it emerges from physical darkness into the sunshine, to see all objects which are
before it in their proper aspect and position. A period of time must elapse, during
which we become accustomed to the light. Future discovery, in its progress, may
show that, of the facts brought forward in this volume, many are misplaced, and many
misapplied ; these are incidents to which all philosophical works are liable. But if it
should happen that anything contained herein shall aid in fastening the attention of
men of science on the idea which it is designed to impart, the author will have received
his reward, and the labours of ten years will not have been entirely thrown away.

5. Organized beings and organized bodies spring forth in those positions only to
Y which the rays of the sun have access. They are, therefore, limited to the atmosphere,

the sea, and the surface of the earth. Periodical vicissitudes, which are observed both
in vegetables and in animals, serve to show that this is not a mere fortuitous coinci-
dence, but rather an intimate connexion between the phenomena of life and the pres-
ence of the iaiponderables. When the sun is set, the leaves of plants no longer decom-
pose the carbonic acid of the air, but a pause takes place in the activity of their func-
tions, and they sink into a passive condition. The gaseous bodies brought from the
ground by the action of the spongioles percolate through the delicate tissues of the leaf,
and escape away into the atmosphere. At night, also, in many flowers, the petals fold
themselves together, and, for a time, all active processes cease. It is, therefore, through
an instinctive impulse, that comes over them during this period, that all animals, except
such as take their prey by night, seek places of rest. Darkness, and silence, and re-
pose are all connected together.

6. It is one of the greatest discoveries of the present age, that the races of animals
which have inhabited our globe were of successive creation ; that they constitute a

GENERAL LAWS DIRECT ALL EVENTS. 3

series, the extreme terms of which bear no resemblance to each other; that, commen-
cing with those of the earliest date, we are able to trace a constant progress both in
intellectual and structural development. In all, there are found evidences of the opera-
tion of the same formative power, acting by and resorting to the aid of the same phys-
ical principles. The trilobite, of the primary fossiliferous rocks, and man, of the most
recent, have, at the first glance, little in common, but a more attentive observation soon
shows that the idea of construction in each is so aUied, that they have both undoubt-
edly sprung from the operations of the same Intelligent Mind.

7. Do, then, these successive races of sentient beings form altogether a strictly con-
tinuous series ? As in the series of mathematiciaiis, where each term bears a definite
relation to those which precede it, and contains within itself the elemental law of those
which are to come after it, do each one of these organized beings observe a position of
relationship with those that are of earlier, and those also which are of later date ? Do
the animals and the plants of the Carboniferous Period connect those of the Silurian
with those of the Newer Pleiocene ! Were the organized mechanisms of the Old Red
Sandstone essential to the appearance and existence of those which live with us ? Are
we, in short to regard the Author of these wonderful forms as operating in each one
of these instances by the same law, and, from small beginnings, evolving and transform-
ing the most elaborate by a successive passage through those which are inferior ! or
are we to understand that, at particular and unconnected epochs, the broad hand of an
overruling Providence is to be discovered, fashioning and fi-aming each class of created
forms, irrespective of external physical forces or agents, and giving birth spontaneously
to unconnected tribes of animals and plants, which bear d« sort of relationship to one
another, and are not parts of one common plan in which there is a unity of design ?

8. The interior movements of the solar system, and the collapsing of nebular masses,
are committed to secondary agents or to immutable laws ; and these are events which,
for their completion, often require great periods of time. No invisible or extraneous
agency ever intervenes. In her predestined course, the moon revolves and exhibits
her phases, and, like the beating pendulum, though ten thousand years may have elap-
sed since its last beat, the comet — the pendulum of the universe — swings punctually past
the sun. That universe is not an unchangeable mass, but is made up of moving and
revolving orbs, which are all obedient to one common law. Do not, therefore, such
things point out, that, in the midst of all these transitory affairs, immutable principles
are involved, and a common law is incessantly in operation 1

9. In the history of the human race, it may be observed that epochs have occtirred,
which, following each other with a kind of periodicity, have stood in relationship with,
or even brought about, the conditions of modem civiHzation. As in the course of the
life of an individual there is no incident which is not in connexion with circumstances
which have preceded it, and none that does not give a bent to those that follow, we
naturally view the vicissitudes of our existence as bearing the relation of cause and
effect. We trace the circumstances of to-day from the circumstances of yesterday.
In the movements of the celestial bodies we continually see fixed events resulting from
the operation of apparently variable causes ; the waxing and waning of the moon, tlie

/

4 TRANSITORY NATURE OF ORGANIZED COMBINATIONS.

eclipses of the sun, the transitory visits of comets. On our own earth we also witness
oceanic tides which ebb and flow, and spring and summer, and autumn and winter,
following each other unceasingly. From year to year we witness the alternate in-
crease and shortening of the day, the tempests of the equinoxes, and the sultry weather
of midsummer. In the world of organization which is around us, we observe similar
mutations : there are plants which come up in spring, and die away in autumn ; and
even those hardier races which witness the changing of empires, give tokens that they
are included within this law of variation. The oak unfolds its buds into leaves, which]
periodically fall to the ground. Among sensitive beings, from time to time, different
races of animals have held dominion of the earth : at one period it has been almost thej
exclusive abode of reptiles, at another of four-footed mammalians, and at last is under]
the control of two-handed man,

10. In whatever direction, therefore, we look, we perceive the transitory nature of
all things : even with those which, from their magnitude, their remoteness, or their im-
portance, might with apparent propriety be regarded as not participating in these un-
ceasing changes, the law holds good. Throughout the universe there is no monument
that retains its primordial condition.

11. Each one of these various changes, no matter whether it concerns organic or
inorganic nature, has been the result of the action of some determining cause. The
countless systems of phenomena which have arisen are all connected together as sys-
tems of effects. In a web, as it passes from the loom, the different threads interlace
with one another, and though we soon cease to identify each as it pursues its sinuous
way, we know that the last is connected with the first; and in the web of nature each
event has been brought into relation with others that have gone before it, and others
that have succeeded it, and all are intertwined together as a series of causes and effects.

12. Understanding thus that no effect takes place except by the operation of some
prior cause, we occupy ourselves in discovering its dependances on things that have
preceded it. It is this which engages the contemplation of the greatest philosophers in
their speculations on natural phenomena, and ordinary men in the daily affairs of life.
The disasters of to-day we attribute to the errors of yesterday, and the possession of
glory, and wealth, and position in society, to plans that have been conducted well. No
man is in heart a fatalist, for each one clearly perceives that his destinies are in his
own charge ; and no small portion of human happiness or misery springs from a knowl-
edge of these things. In other tribes of life, where intellectual processes are replaced
by processes of instinct, it is very different : the wild animal which lives in the prairies
meets seasons of famine and distress without a moan. Careless for to-morrow, he
bears up with his present lot, and is utterly unconscious that he may have been the',
author of his own wo. There is with him no recording memory of whence he came,
no distracting care of whither he may go. He acts, in respect of the passing time, in
the same way that men act in respect of their whole life ; they are ignorant of what
happened in their early days of infancy, and never trouble themselves about what may
come in old age.

13. The vegetable world, from possessing no nervous system, is inherently incapable

RELATION OF ANIMALS TO MAN. g

of appreciating its own existence, and much more, therefore, of feeUng emotions of
pleasure and pain. To animals nature has given a present contentment, which is pur-
chased by ignorance ; but to men, who are endowed with reasoning powers, whose
nervous system has been so formed as to enable their mental operations, by processes
of memory, to reach over long periods of time, to combine together events which are
afar off, to decompose into their constituent parts phenomena that are complex, and to
trace each one of those parts up to its proper cause, knowledge has been given, and
the price of that knowledge is pain.

14. So far as their intellectual powers are concerned, the Ufe of animals, even of] i^
those of the higiiest orders, is analogous to the dreamy sleep of man. Overcome by
the toils of the day, the weary labourer sinks into repose, and there come before hiui
pageants and scenery connected, to a certain extent, with the external world ; but of \
that world he is wholly unconscious. Instead of the accustomed forms that he me'ets

in his daily affairs, there spring up light aerial shapes and phantasms. From recesses
in the brain, where they have been long stored, and perhaps forgotten, the recol-
lection of landscapes that he has seen of old come forth ; he views the well-known
forms unfold themselves before him : there stands the aged oak, at the foot of which he
has so often watched the setting of the sun, and there is the pale-blue sky with its
gilded clouds, and in the distance the almost invisible mountains. That fairy panorama
has its shadowy tenants, which live, and move, and breathe : the dead are also there. '
From those silent sepulchres which are within the brain, they rise again as Uving )
things, and people the scenes they once loved. They converse with and counsel the
dreamer.

15. As thus, during the night, these phantoms come up spontaneously before us, and
spontaneously disappear, and time, of which men gain a knowledge only by comparing
events, passes unnoticed away, we see to what a small extent the will controls these
phenomena. The spectres come unbidden, and they as suddenly depart, and very ^,
often, during one slumber, they change and rechange again, and memory, the arch-
conjuror, evokes scene after scene.

16. With the brute creation the same thing holds. In their daily relations with ex-
ternal nature, almost all their fiinctions are carried on by the promptings of instinct, or
in a mechanical way. So far as we can see, the current of thought seems to be little
under their control, and they have no power of effecting the collocation of ideas. They
cannot tell the passing of time, which flows away in its silent lapse, and leaves them,
as it found them, contented. Unaided by the instincts which are implanted in them,
they show but little power of reasoning from causes to effects, or from effects to causes.
Even in the most obvious cases, where actions are performed before them which, if
performed by themselves, might tend greatly to their enjoyment, they exhibit but a low
imitative power. Though he has often seen it done by man, the monkey has never
yet learned to make a fire.

17. All objects which surround us, whether animate or inanimate, are marked by a
transitory nature. They come into existence, for a while they continue, and then they
pass away. It is thus that, in the course of ages, the configuration of continents and

g TIME IS AN ELEMENT OF LIFE.

seas undergoes change — changes, however, which require long periods of time, and
which, in the course of human existence, are, for the most part, imperceptible. Com-
mencing with the inorganic world, which we see is included in this law of unceasing
variation, we discover that each of its component structures passes through its trans-
mutations more rapidly according as its constitution is more complicated. For the
same reason it is that bodies which are organized — and organization in itself implies
complicated structure — are of all forms most liable to these mutations. The dead car-
cass of an animal speedily disappears under the forms of water, annnonia, and carbonic
acid, its elemental atoms breaking up into simpler and more enduring groups. It is a i
vulgar error that a living being possesses a principle of resistance to external agents, /
while a dead one submits itself to them ; both equally change, or, of the two, the living-'
one putrefies and changes the more rapidly ; but, then, for each of the several systems
of dead and dissevered atoms, appointed routes of passage are prepared. The carbonic
acid escapes by the lungs, the nitrogenized compounds through the kidneys, and water
through both those organs and the skin. The putrefaction of an organized being is a
constant event ; it commences before birth, and continues after death ; but, though
constant, it is regulated in life, and after death the avenues of discharge are all closed,
and the mechanism appointed for removing the decaying atoms broken down.

18. Time, therefore, enters as an element in animal life. Individuals, after the prog-
ress of a few years, pass away, and, during each moment of their existence, their va-
rious parts are undergoing incessant change. There is a constant removal of all the
carbon compounds from every part of the system ; a removal which necessarily arises
in conducting locomotion, and various other functions. If an electric current is to be
passed along the wire of a voltaic battery, and is required to evolve a certain amount
of hght or heat, or to produce a certain amount of electro-magnetic motion, a fixed
amount of zinc must be consumed. If a steam engine has a given quantity of work to

\ perform, a given quantity of coal must be burned. So also in animal systems, the pro-
duction of motion can only be effected by the consumption of the parts of the animal
machine. In the higher races, in which an elaborate development of these functions
has been accomplished, the processes of transmutation go on with the greatest rapidity.

^ Among insects, which are constantly upon the wing, the combustion of the organic
atoms is at a maximum, as is also, consequently, the production of heat ; but at night,
or when they rest, the rate of respiration diminishes, the heat dechnes, and the trans-
mutation is checked. In the existence of an animal, as also in the existence of its
constituent atoms, time, therefore, enters as an element.

19. There is a constant washing away of mountains into the sea, and rivers contin-
ually tend to fill up their beds. In one region the detritus of the land, brought down
by streams, encroaches on the ocean, and makes new countries ; in another, the ocean
invades the shores, and makes changes in the shape of continents. In the vegetable

/ world, the leaves are organized in spring, and decay in autumn ; and among animals,
'O each has its own period of duration. Among all these organized structures the parts
are undergoing unceasing change. Physical forces are at work, physical phenomena
have to be originated, and physical ends to be gained. The death, therefore, of an or-

\

/v^

LAW OF CHANGE IN ATOMS, INDIMDUALS, AND RACES. 7

ganic atom in an animal, has for its object the production of a given result, and is
itself the result of the action of ordinary physical powers-

20. If, thus, the various movements I am executing in WTiting these pages arise di- ( )
rectly from the respiration of oxygen gas, and its transmission, by arterial blood, through

the svstem, and each letter that I have penned is the result of the death of parts of this j
animal frame, which, in their removal, have ended in the production of motion and
heat, it is plain (hat there is no essential difference between the death of an oiganic
atom and the extinction of an animal race. Of the thousands of animal forms which
have ceased to live, and of which, indeed, we should have no knowledge but for their
remains, which have been entogibed in the earth, what has been the cause of the dis-
appearance of each successive rSce ! How is it that, at a given epoch, these animated
forms have on a sudden stood forth, and after continuing for a time, as suddenl\" dis-
appeared ? Why is it that this disappearance does not take effect in a gradual way,
but is so abrupt an affair as to serve, in the hands of geologists, the purpose of marking (

off one epoch from another ? Do not these total disappearances point to external for-
ces of the most extensive operation as the agents that have been at work, and the end
and object of those extinctions the production of physical results ?

21. As the cause of extinction of those innumerable tribes of Ufe which have inhab-
ited the earth is directly traceable to physical events, for individuals, also, the same law
holds good. On the American Continent the mastodon is no longer seen, though but a
short time has elapsed since all the rich valleys were thronged with those enormous ele-
phants, and still, in the salt-licks, their bones are disentombed along with those of animals
that are here with us. Nor is it alone to obscure and unintelligent orders of life that this
law of extinction apphes. Within the periods of history, have not tlie same things
happened ? The founders of the greatest empires and republics have ceased to exist.
Among us, what has become of that ancient people who built the extensive structures
in tlie Western Slates ? Their name and every recollection of them have passed away.
Even before our eyes, is not the same thing happening ? From the Atlantic States,
have not the Indian races nearly disappeared ? They are borne by the tide of civili-
zation across the great Valley of the Mississippi. Among them one tribe after another
is swept away. The blood of the Mandans has ceased to flow in the veins of a single
human being. Worn down by famine, by war, and by pestilence, these children of the
forest recede before that civiUzation, the benefits of which they obstinately refuse to
receive, and, clinging with an uncontrollable instinct to a wandering and savage
life, accompany the wild animals to the remoter woods, or,' driven by their necessities,
from time to time return among us, and beg in the City of Washington for a blanket
and a little bread.

22. "^t among them there are men capable of the highest emotions and the most
noble deeds. The hand of Providence presses upon the Indian. The race, like each
individual o^ it, submits in silence to an irreversible doom. From- the day when organ-
ization first commenced on the surface of the earth, the law which it has followed has
been a law of progress and of evolvemenL A myriad types of life have been created,
and myriads of hving forms produced, and the last is the highest Even with us the

g INFLUENCE OF CLIMATE.

same thing is going on : advances in knowledge are advances in power. The civilized
man of these days is a wholly different being from the man who hved a thousand years ,
ago, and the conditions which determine his position have totally changed. With us
the position both of empires and of individuals is fixed by the possession of knowledge —
knowledge which is incessantly on the advance. Wherever intelligence has been given,
there is a requirement to join in the advancing march. The Indian stands still, and -
the penalty is death.

23. These severe results are brought about by universal laws — laws which were
not intended for individual cases. In the system of the universe an individual is not
known, but action takes place on masses. Nor are the laws of Nature ever bent to give^^ ■'•'
benefits to or bring punishment on any individual. They go into effect with an inex-
orable decision. The earth in her course pursues an irresistible march, and tides rise
and fall in the sea with a fixed fatality. In the affairs of men the same unwavering
destiny is observed, and whether it be in the case of an empire or a man, resistance to -f-
the course of events ends in an inevitable doom. He who resists the progress of civi-
lization, meets the same fate as he who resists the cataract of Niagara. There is no '
waywardness in Providence, no partialities, and no hates. It is wjitten, " He maketh ^
his sun to shine on the good and the evil, and sendeth his rains on the just and on the
unjust."

24. From these considerations, therefore, we may gather that the laws of Nature
contain provisions for the extinction and removal of successive races ; operations which
are carried on by the action of physical powers. As the death of an individual arises
from the action of external agents, so, in the same manner, does the disappearance of
a tribe : and hence we see that, as existence is under this control, it cannot take place
except when physical circumstances conspire ; as they change, so, also, must the vari-
ous forms of life undergo corresponding mutations.

25. In the constitution of all organized beings, water enters as the leading ingredient
of their fluid parts ; it is therefore obvious that there is a very limited range of temper-
ature in which the processes of life can be carried on. These thermometric limits are
between 32° and 212° Fah. Life, therefore, is comprised within a range of 180 degrees. 4-

26. In this manner we might proceed to show how the existence of individuals and
races is completely determined by external conditions. How, for the same reason that
an individual dies, so too does a tribe become extinct. Pursuing these considerations,
we might show how closely the development of the intellect itself is connected with
them ; we might compare the effect of climates in the torrid, the temperate, and the
frigid zone, and show how history bears out the truth of these views. We might ap-
peal to individual experience for the enervating effects of hot cHmates, or to the com-
mon understanding of men as to the great control which atmospheric changes exercise,
not only on our intellectual powers, but even on our bodily well-being. It is within a
narrow range of cUmate that great men have been born. In the earth's southern hemi-
sphere, as yet, not one has appeared, and in the northern they come only within certain
parallels of latitude. I am not speaking of that class of men who, in all ages and in
every country, have risen to an ephemeral elevation, and have sunk again into their na-

INFLITENCE OF TE>iPERATURE. 9

tive insignificance, so soon as the causes which have forced them from obscurity cease,
but of that other class, of whom God makes but one in a century, and gives him a
power of enchantment over his fellows, so that by a word, or even by a look, he can
•* electrify, and guide, and govern mankind."

27. It was a beautiful idea of some of the English chemists of the seventeenth cen-
tury, that our earth is nothing more than an incrusted star — a star, the light of which
has gone out. They gathered this from the well-known phenomena of hot springs,
and the increasing temperature of deep cavities. In their opinion, there was a sun in
the earth beneath, as well as a sun in the firmament above. These views are essen-
tially the same as those which are now received by geologists, who almost universally
admit the doctrine of a central heat, the surface having cooled down nearly to a con-
dition of equilibrium. Equally beautiful is the idea of M. Poisson, that the sun, in his
movements through space, successively carries his attendant planets through regions of
variable temperatures — temperatures which are variable by reason of the different amount
of stellar radiation which crosses them, and that, for many ages past, he has been com-
ing from a warmer to a colder space. Admitting this to be a true representation of the
fact, the phenomena which we witness are such as should take place. If a great mass
of rock was brought from the equator suddenly into the polar regions, it would, from
being exposed there to a low temperature, commence to radiate its heat, and in a very
short time, if examined, would be found coldest on the surface, with a temperature in-
creasing towards its centre, that increase being at first rapid, but the heat subsequently
becoming uniform. Such a rock Poisson regards as being a miniature representation
of the earth.

28. Which ever of these hypotheses is true, of one thing we are certain, that the sur-
face temperature of the globe has undergone periodic changes, and with these chan-
ges, not only has the distribution of plants and animals varied, but general disturbances
have taken place in the types of existing species. Those creations and extinctions to
which allusion has been made were all, undoubtedly, connected with these thermal dis-
turbances. There can be little doubt that the mastodontoid family was destroyed by a
general reduction of temperature. With modifications of the distribution of this all-
pervading agent, changes in the distribution of organized beings must of necessity ensue.
Even with us, were the mean temperature to rise by a few degrees, the great mamma-
lia of the torrid zone would push their excursions to the north and south. The Ben-
gal tiger would leave his jungle, and press himself into higher latitudes. It would re-
quire but a slight meteorological change to bring the orange-tree into the Middle States,
or to tempt the turkey-buzzard far to the north of New-York. And, on the other
hand, should a reverse action take place, and the mean temperature descend by a few
degrees, the indigenous animals and plants of the Northern States must pass to a lower
latitude, or become extinct The distribution of organized forms is, therefore, directly,

and their very existence indirectly, determined by the distribution of heat. Who, then, ^ '\
can doubt that all living beings depend on physical force ?

29. If these things are true with respect to the organized forms which are known
to have existed in former times — and we examine the relations obtaining between the

B

i

10 RELATION BETWEEN ANIMATED FORMS AND THE ATMOSPHERE.

present climates of the earth's surface and the animals that reside on it — how abundant
is the proof that all are still under the control of physical agents ! Things being so,
and each species having its assigned spot, from which it does noW wander, for many
ages the same inhabitants are found in the same places. They change as individuals
only : the old decline and die away, the young spring up in their stead. I do not
know whether, in taking these general reviews of the earth, we ought to have any re-
gard for individuals ; whether we ought to consider them as they come into existence
and exhibit the strength and vigour of youth, and the decrepitude and languor of old
age. Life and death are familiar to us, because as individuals we have a deep personal
interest in them ; but the cares of Nature are beyond a day. In the Drama of the Universe,
each actor performs his part, whether leading or obscure, and, though he may retirej^
from the scenes, the play goes forward to its catastrophe. Whether it be an individual
or a race, each, by the actions of its life, has given some turn to the general course of
events. In the undulations that circle on a quiet lake, each particle alternately rises
up and sinks into repose ; but that particle, minute as it was, that motion, small as it
might be, was absolutely necessary to keep up the onward motion of the waves. Under
this point of view, the destiny of each individual is connected with the destiny of the
world.

30. With each breath that I have drawn since I came into the world, I have im-
pressed a change on the earth's atmosphere. One year with another I have removed

/ therefrom eight hundred pounds of oxygen gas, and have cast into it a much greater
weight of carbonic acid, made up of the detritus of atoms which have been dismissed
from the system as unfit for the continuance of life. It is the express function of the
act of respiration to produce this result. That carbon, thus given forth, was received
in the form of food, it sated the cravings of hunger, or gratified those animal pleasures
which depend on the sense of taste. Taken by appropriate apparatus from the stom-
ach, it passed into the circulation, and, grouped with other materials, it changed into
blood ; and now, by capillary attraction, aided by the action of the heart, it was car-
ried to every part of the body, and became a constituent of a living being — a temporary
constituent only. As we have said, it is a vulgar error that the distinction between a
living and a dead body is in the circumstance that the former can maintain itself with-
(/ yout change, while the latter undergoes putrefactive decomposition. Both equally pu-

/ , , trefy, of, if there be a difference, the change goes on most quickly in a living system.

/S The true distinction rests in this, that a living body is accommodated with machinery
to remove the decomposing atoms, and hence the process is conducted in a regulated
way. A chemist looks upon life as made up of unceasing deaths. And those atoms
of carbon are removed because their life is over, and they pass, by the action of the
lungs, into the atmosphere as carbonic acid gas.

31. But their function is not ended. There, it is true, they commingle with the
elements of the air, and are no longer fit to support the respiration of man. The ways
of Nature are marvellous. This gas, cast away by animal forms, serves now as food
for plants and trees. Under the influence of the solar beams, the leaves that have been
unfolded in spring, spreading their broad expansions to the air, commence the decompo-

RELATION BETWEEN ANIMATED FORMS AND THE ATMOSPHERE.

11

sition of these effete atoms ; they undo what the animal system has done ; they release
the oxygen once more, and restore it to the air for the use of animals, and appropriate
the carbon to their own structures. From it they fashion their flowers, from it they
build up their stems or perfect their fruit, and prepare once more food for man.

32. Thus do these carbonaceous atoms run through a cycle of change, passing from
animals to vegetables, and back again from vegetable to animal systems : and the Sun,
to whom Nature has given the charge of these wonderful operations, from age to age
furnishes his unfading beams (Ap., 824). He sinks below the horizon at night, and re-
tires to the south in the winter, and performs his work by regulated and measured
steps. Even at the polar regions, where there is no morning, no no(Hi, no evening, no
midnight, where there is no rising nor setting of a star, the great orb peers above the
horizon, " and under the influence of his midnight beams, trees and plants run through
the same series of changes in a few weeks, which they accomplish in months under
the purple skies of beautiful Italy." — Berzelius.

33. As, thus, we see the sun performing the ofiice of a great life-giver, and know
that all his movements are accomplished by the operation of mechanical laws, as we
understand that all these multiplied motions are executed by the action o{ on» attract- ,
ive force, it would seem as though Nature, on the great scale, called on us to recog-?
nise the agency of mechanical laws in regulating the processes of hfe.

34. The carbonaceous matter which has flowed through the heart of man as blood,
is transferred, by respiration, to the air, and aids in the formation of forest trees or
painted flowers. The Asiatics, with whom have originated all the varieties of pagan
creeds that have spread to any extent in the world, believed in a transmigration o£^
souls ; they would have been much nearer the truth had they believed in a transmigra-
tion of bodies. The coal that we burn is the remains of forests which, in former ages,
were thronged with living things — forests that sprang, as do the trees with us, from
gases that were formed from the respiration of animals — but of animals that are all extinct.

35. Atmospheric air is, then, the grand receptacle from which all living things spring,
and to which they all return. It is the cradle of vegetable, and the coffin of animal >
life. Made up, as it is, of atoms that have once lived, that have run through innumer-
able cycles of change, the aspect of purity it presents conceals too well its history. In
its ethereal expanse are crowds of atomic forms that have once blossomed as flowers,
or participated in the pleasures and pains of animal life. Their former fiinction dis-
charged, these atoms that are dead await their turn of reorganization once more.
They occupy themselves in transmitting the many-coloured beams of light, or moving
in vibration to the tones of music. A condition so tranquil suits well their former state
and future destiny. The remains of wild beasts, or of more ferocious men, disappear
in this general tomb of dying atoms, and after a time are reorganized by the solar
l)eams once more, perhaps in those pensive wild flowers that blossom unseen in the
gloomy wastes of an American forest.

36. We know that the daily rotation of our earth on her axis determines periodic
observances in the functions of organized beings, and fixes their times of activity and
sleep ; a similar result attends upon her yearly motion in her orbit. How is it that, in
our latitudes, trees and plants awake at the coming of spring, and put forth their leaves

\

I

12 INFLUENCE OF CURRENTS IN THE AIR AND IN THE SEA.

and flowers, and then sink again into their annual skimber ? How is it, also, that wild
birds and beasts conform in their habits to the progress of the seasons, and at one time
prepare to bring forth their young, and at another anticipate, with a provident foresiglit,
the coming winter 1 Those great migrations of fishes that take place at given seasons,
and which are even connected with the well-being and wealth of nations, are deter-
mined by the occurrence of certain epochs. It is no explanation of these curious facts
to say that they depend on other facts like themselves — that an animal sleeps by night,
because his prey is also asleep ; that a fish migrates at those periods when his instincts
tell him that the food on which he lives is abundant. If, in any of these cases, we
pass from fact to fact, we uniformly come, at last, to the same conclusion, that all these
incidents are directed by astronomical events ; that the sun not only determines peri-
ods of awakening and sleep, of growth and decay, but that there is also committed to
// / him a control and regulation over all the movements of animated beings on the face of .

/ the globe. It is the luminous rays of that distant star which, faUing perpendicularly,^

produce the luxuriant vegetation of tropical regions, and his rays of heat which debili-
^ tate and enervate the human race. It is, in the polar regions, the obliquity of those
/ beams Which suffers the ground to be always covered with snow, and makes those in-
hospitable countries almost without inhabitants. The trade winds, also, which blow
uninterruptedly for ages, carry away towards the poles immense quantities of oxygen
gas, which the green parts of plants throw into the atmosphere of the torrid zone.
That oxygen is evolved by light, and is then disseminated by heat. In the sea the
same influence which thus presides in the air is also at work. The Gulf Stream,
which issues from the Mexican waters, with its temperature elevated by solar action,
determines the distribution of the Atlantic fishes ; the northern whale avoids its offen-
sive warmth, and on its sides shoals congregate which delight in a more genial heat.
As it approaches the coasts of Europe, and spreads out into a fan-like form, the va-
pours that rise from it give forth their latent heat to the air, and moderate the climates
of England and France. The coldness and sterility of corresponding latitudes in
America is there replaced by a better temperature, and agriculture, the arts of life, sci-
ence and literature, have there reached their greatest perfection. This physical agent,
thus eternally but invisibly continuing its operation, produces a thoixsand events in
which its agency is only remotely traced ; nor are those influences limited to mere
physical results ; they stand in connexion with the progress of society and the evolu-
tion of mind. A full development of the reasoning faculty can only take place where
physical circumstances conspire. It is to the climate of England and France that the
human race is indebted for the intellect of Newton and Laplace.

37. In these remote events, which thus originate among the ordinary phenomena of
the natural woVl'd, and strike us forcibly when we trace them, step by step, from their
origin to their result, we are prone, at a casual glance, to give too much weight to in-
tervening influences, and forget the final cause. Would it be too much to assert that,
with returning seasons, periods of vegetation, and the distribution of animated nature,
astronomical occurrences Ukewise direct a thousand of those daily movements which
are taking place in every part of the world ? There is no harvest which is gathered,
no famine which desolates, that has not sprung from an immediate connexion with

INDEPENDENCE OF THE HIGHER ANIMALS OF EXTERNAL AGENTS. ^3

them. In judging from a narrow circle of observation, or from an imperfect experience,
men are led to regard these as fortuitous affairs. Are they not rather brought about
by unfailing and unchangeable causes ! From century to century, the sun pours forth
his undiminished stores of light and heat ; the former, out of inot^anic material, con- ) /

strucls molecules that are organized, and from them builds up the myriads of vegetable
forms which are destined for supporting animal Ufe ; the latter, controlling the move-
ments of inorganic matter, divides into climates the earth's surface, volatilizes water
from the sea, sets the wind in motion, and directs the form, duration, and movement of
the clouds. The primitive force which is at work, producing these vital and mete- f
orological phenomena, undergoes no change in intensity from year to year; it is there- \
fore expended in producing the same amount of effect. It is through this that the ■
droughts of one country are contemporaneous with the abimdant showers of another
— the famine which threatens one place is compensated by harvests in another. As
natural laws were never meant for operation on individuals, but for action on systems
and masses, incidental vicissitudes, such as those of which we are speaking, should
never guide us in our judgment of final results. Operating with an unerring certainty,
and with an unchangeable force, the sun carries on his plastic works, as the earth, in
her daily rotations, submits herself to his beams. From this it comes to pass, that
though there may be variations in the lot of particular nations or particular individuals,
the common interests of all are protected, the common rights of all are upheld. From
the very beginning of things, every class of variation has been determined — where par-
ticular climates shall fall, where particular temperatures shall be observed, what shall
be the speed of vegetable growth, what tribes of animals shall be given — and the thing
remains fixed and unalterable.

38. One of the most striking results of organic chemistry is the relationship which
it discovers between animals and plants ; the former constituting an apparatus for ox-
ydatiou, the latter an apparatus for deoxydation. Compared together, a relation of ^
antagonism exists between them. Plants, from inorganic matter, construct their vari- '
ous tissues and parts ; these are consumed by animals, and forced back into the inor-
ganic state. It is therefore plain that the sun is the great formative agent, and ani-
mals are the destroyers. If we consider the successive races of organized beings, be-
ginning from the lowest and passing to the higher tribes, it would seem as if the gener-
al idea under which Nature has been acting is, that as the more complex structures were ''■
evolved to emancipate them from the direct control of external physical forces. The
vegetable kingdom, unendued with locomotive powers, deriving its existence directly
from external agents, is completely under their control. If the summer is too brilliant,
or rains do not fail, a plant withers and dies. In the same manner, the lower races of
animals have their existence determined by the action of physical causes ; if these be -X

favourable, they flourish ; if unfavourable, they must submit to an inevitable lot. To •

tribes that are higher, to a certain extent, the rigour of these laws is remitted, and a
certain amount of independence secured ; the African lion can retire to a shade in the
middle of the day ; yet still he is held in a state of subjection, and instinctively submits !•

to the operation of an overruling power, and is kept to the sands of his desert from ^
cool and temperate climates. The sunbeaiu is bis chain. In man qloue the emanci- "]

/

14 INDEPENDENCE OF THE HIGHER ANIMALS OF EXTERNAL AGENTS.

pation is complete ; for into his hand Nature has committed a control of the imponder-
able principles. It matters not whether it be in the torrid zone or in the frigid, he tem-
pers the seasons by his intellectual power ; he resorts to every artifice of clothing, or
to the warmth of fire ; he dissipates the natural darkness by artificial light. Devel-
oped by civilization, he is no longer a prey to natural accidents ; if the harvests of his
own country have failed him, his hands have created commerce, which brings him an
abundance from distant places. Unlike even those races which are next below him, and
which instinctively aim at the result he so perfectly accomplishes, he does not wait
upon the gifts of Nature, but compels her to minister to him. When they are oppress-
ed by hunger, whole tribes of fishes migrate in the sea, and innumerable flocks of birds
direct their flight to distant countries ; but civilized man, without calling into action
his own locomotive powers, puts his arm across the globe, and satisfies his wants.

39. What, then, are the final impressions left upon our minds by these general con-
siderations ? They teach us that hfe never occurs except in regions to which the im-
ponderable agents can have access, an observation which is equally true of vegetable x
and of animal forms ; that elementary organization directly or indirectly arises from
the plastic agency of those all-pervading forces. Whether we consider the organic or
inorganic world, all things around us are in incessant changes — changes which result
from the fixed operation of invariable laws ; that, of the successive tribes of beings
which have peopled our earth, each series may be regarded as expressing the general
relation of all physical agents at the time of its existence, the brilliancy of the sun, the
/ pressure of the air, and other such conditions ; for we see that, between those condi-
tions and the organization of the structures considered, there are fixed relations ; that
in the more highly complicated forms of beings, mutations more readily take place, and
in all, time enters as an element ; that in the same way that whole races have disap-
peared from the face of the earth, and have become extinct, so, also, do individuals die
and atoms change ; that, whatever motion is accomplished, or whatever change is brought
about, there is a consumption of material or an expenditure of force ; that, as the sur-
face of the earth is continually remodelled by physical agents, so are the vicissitudes
through which organized forms pass determined by physical powers, and bring about
physical ends. The passage of a comet, never more to return, in a hyperbolic orbit past)
the sun, is a result of the same general law that keeps a planet revolving in repeated)
circles — the extinctions of races which have heretofore taken place, or which are going
on before us, are not brought about by a direct intervention of supernumerary forces,
but are the constant result of those which are always in action. If, moreover, our
thoughts are directed to the relations which exist between climates and the character
of races, the distribution of vegetables and animals ; if we observe the antagouization of
these great classes in the result of their vital processes, their position as respects the at-
mosphere, the control which astronomical events possess over everything, the action
which currents in the air or currents in the sea exercise over the distribution of anima-
ted forms, and even over the well-being of man, we surely shall have but little difficulty
in understanding that, as in the inorganic world, so also in the world of organization,
those all-pervading forces which natural philosophers and chemists recognise are con-
stantly employed.

-v

A TREATISE

OM THK rOBCES WHICH PROMJCE

THE ORGANIZATIOIS OF PLANTS,

CHAPTER I.

O.N THE ACTION OF THE SUNBEAMS IN PRODDCING ORGANIZED BODIES.

Contents : The Growth of Conferrxz in Water. — Production of Green Matter hy Spun
Glass and Inorganic Bodies. — It requires a Sporule, Cell, or Ohjeclitx Germ. — Mode
of Diffusion of Gases into Water. — Influence of Temperature on the Process. — Action
of tlie Suns Rays on these Gases. — Two Atmospheres around the Earth. — Sources
of Supply of the expended Gases.

Application of these Principles to the Production of Chlorophyl in Leaves. — The Di-
gestion of Plants.

40. If we expose some spring water to the sunshine, though it may have been clear ^
and transparent at first, it presently begins to assume a greenish tint, and, after a while, )
flocks of green matter collect on the sides of the vessel in which it is contained. On /
these flocks, whenever the sun is shining, bubbles of gas may be seen, which, if collected,
prove to be a mixture of oxygen and nitrogen, the proportion of the two being variable.
Meantime the green matter rapidly grows, its new parts, as they are developed, being
all day long covered with air-bells, which disappear as soon as the sun is set If these
observations be made on a stream of water, the current of which runs slowly, it will be
discovered that the green matter serves as food for thousands of aquatic insects, which /-•
make their habitations in it. These insects are endued with powers of rapid locomo- /
tion, and possess a highly-organized structure ; in their turn, they fall a prey to the
fishes which frequent such streams. Organic chemistry teaches that it is the office of
vegetable life to form from inorganic matter organized molecules, and furnish them as
food for the support of animals, which simply assimilate, but do not fabricate ; we must, ^
therefore, infer that the fibrine, the albumen, the gelatine, the fat, and whatever else of i
those compound organic molecules is required for the support of fishes and insects, are i
originally formed by the action of light on that green matter. But the production of this
substance is the result of a multitude of coincident actions. The sunlight is the agent
which directs its growth, but it does not so plainly appear what is the body fi-om which
it originally springs, and on which the light exerts its influence ; whether it comes from
microscopic germs which, floating about in the air, find their way into every water, or

c

16 THE GUOWTH OF CONFEKVjK IN WATEK.

from organic cells furnished from obscure sources. The process once begun, goes on
with uniformity and rapidity so long as external circumstances are favourable. Some
of the chemists of the last century asserted that no organic nucleus was required, and
that, on putting such bodies as spun glass or amianthus into a vessel of water, on ex-
posure to light, those fibres would become covered with bubbles, and the water would
begin to turn green. But I have found that these are experiments which do not suc-
ceed except under circumstances where there is every reason to suspect the incidental
introduction of organic matter. Count Rumford has stated that yellow silk, in an
unspun state, as it comes from the worm, will cause a very rapid escape of oxygen un-
der the influence of light. It is probable, however, that here, as in the former cases,
some specific organic matter has been introduced, for the result very often cannot be
obtained.
/O 41. Similar green flocks to those of which we here speak are also found on the sur-
/ faces of rocks exposed to the sea, damp walls, and other places where there is a con-
stant moisture. They belong to the algoe or sea-weed tribe of botanists. The con-
fervas are thus described by Professor Lindley : " They consist of filaments, generally
/ simple, and are formed of two tubes, of which one, which is exterior and transparent,
/ offers no trace of organization to the most powerful eye, so that it might be called a
tube of glass, contains an inner articulated filament, filled with colouring water often
\^ almost imperceptible, but at other times a very intense green, purple, or yellow colour."

42. Admitting the existence of some objective germ, or sporule, or point on which the
/ light can act, we are able to give a pretty clear account of the process of evolution of
' ^ the green matter. When pure water is freely exposed to atmospheric air, in conse-
quence of the quality exhibited by all substances (Ap., 75) of diffusing into the inter-
stices of each other, there begin to pass into it the different gaseous bodies which have
access to it. These do not all pass with the same facility, nor are they taken up to
the same amount The relative quantity of each follows the order of its solubility. Of
the three gases to which our attention must be directed in the phenomenon we are now
considering, oxygen, nitrogen, and carbonic acid, carbonic acid passes into the water
with the greatest speed, oxygen next, and nitrogen much more slowly (Ap., 54-63),
When a state of equilibrium, therefore, has been attained, it will be discovered that the
pure water has become contaminated by the presence of these different gases, and that
they exist in it to an amount represented by their rate of solubility.

43. Spring water and river water, therefore, naturally contain these different gaseous
substances, which are intimately connected with the production of green matter. In-
deed, from the very mode in which rivers and springs are fed, the solution of gaseous
matter in them is completely secured. By the action of solar heat, vapours are rais-
ed from the sea, and ascending to the more elevated and cooler regions, give out their
latent heat, and condense into vesicles or microscopic drops, the aggregate of which
forms a mist or cloud. In this state of excessive subdivision, the drops are brought into
a perfect contact with the air, and an absorption of its constituents takes place. To
give still greater security, the drops of rain, which are nothing more than those vesicles
coalesced, as they come down from the sky pass through the subjacent aerial strata, and

AMOUNT OF WATER-GAS DETERMINED BY HEAT. jy

withdraw as much gas as they can hold. From rains w hich thus take place and fall on \
elevated regions, springs and rivers arise, containing, therefore, those gaseous materials I
which have been obtained from the atmosphere. '

44. This water-gas, as it might be termed, may be expelled entirely from water by
boiling, and by resorting to that process a knowledge of its constitution has been obtained
(Ap., 93). The power by which liquids hold gaseous substances in solution is diuiinished
by heat, and as soon as a liquid boils all extraneous gas is carried away, because, under
those circumstances, the vapour which is generated by the heat, passing in bubbles
through the mass of the liquid, exposes itself to the contained extraneous gas, which
diffuses rapidly into it, and escapes away when the bubbles burst on the top. The law
of equilibrium of diffusing gases teaches us that this process can only end in the total
removal of the contained air (Ap., 47, 48). Temperature thus controlling the quantity
of gas dissolved in water, we can easily see that in different countries the relative
amount of water-gas will differ, and that its mean quantity will be connected with the
mean annual temperature, and in those seasons during which vegetable action is ad-
vancing most rapidly, that is, in spring and summer, its amount will be determined by
the mean temperature of the spring and summer months. In tropical climates there
should be less of this gas than in temperate, but in the use which is to be made of it
for physiological purposes a compensating agency appears; the poorer water of equa- J
torial countries is acted on b}" a more brilliant ray. The light and heat of the sun
here stand in the attitude of antagonizing forces. The calorific beams, by reason of their '
obliquity in the more polar countries, allow an increased quantity of gas to be dissolved
in water ; the luminous beams which come with the same obUquity have therefore more
to operate on.

45. If saline matter be present, it acts as a disturbing agent ; for a liquid which is ^
impregnated with salt has its solvent powers greatly diminished. Bulk for bulk, there-
fore, sea water must contain a less volume of gas than fresh water.

4G. The gas thus included in the interstices of water discharges many important
functions. It is connected with the physiological operations both of the animal and
vegetable world. Being twice as rich in oxygen as atmospheric air (Ap., 93), it is des-
tined to carry on the respiratory processes of those classes of animals whose form re-
quires that their breathing apparatus should be of the most compendious figure, and
which have to live in the water. Thus, in those fishes which breathe by branchise, the
processes of combustion which are to go on in their systems depend on a supply of the
concentrated oxygen of water-gas. The fish swallows a mouthful of water, and then,
by muscular contraction, drives it out past the gills, among the threadlike fibrillar in
which venous blood is passing. Inter-transfusion in an instant takes place, oxygen
from the water-gas flashes into the venous blood and arterializes it, carbonic acid si-
multaneousl}- comes out, and, as the fish moves forward, is carried away in the current
of water.

47. A mass of water thus containing carbonic acid, oxygen, and nitrogen, with some
germ, or sporule, or objective point, on which the light can act, is exposed to the sun.
As has been said, a bubble of gas soon makes its appearance, and growth, with a devel-

C

^

J8 'WO DECOMPOSITIONS EFFECTED.

opmeiit of the green colour, takes place. If we examine the changes which are now
occurring in the water, we find that the carbonic acid is disappearing, and oxygen and
nitrogen are evolving. The growing mass increases in volume and weight. .After a
time, if proper measures are taken to cut off any farther supply of carbonic acid, the pro-
cess comes to an end. But as conducted naturally, there is a free exposure to the at-
mosphere, from which the acid diffuses, and hence, as fast as its removal by decompo-
sition takes place, new quantities are restored again.

48. The direct action which is accomplished under the influence of the light is the total
decomposition of the carbonic acid gas. Its oxygen is evolved, and its carbon goes to
form the green matter. At first sight, the supposition of the generality of chemical
writers seems to be probable, that the carbon thus evolved, while it is yet in a nascent
state, unites directly with the elements of water, and produces one of the starch family
of bodies. But the constitution of the green matter is far from being so simple.
Chemical examination, and considerations connected with the nutrition of the insects
which feed on it, serve to show that it contains more hydrogen than is necessary to
convert its oxygen into water. There is also nitrogen in it.

49. In the air-bubbles which form and finally escape, we find not pure oxygen, as is
generally supposed, but a mixture of oxygen and nitrogen gases. The source of the
former is unquestionably to be referred to the decomposed carbonic acid. From the
circumstance that in the growing mass there is an excess of hydrogen, and in the esca-
ping air a large quantity of azote, it would seem that a compound having the same ele-
ments as ammonia has been acted upon. Nevertheless, the quantity of ammonia which
is commonly dissolved in spring or river water is far too small to furnish the supply
which would be necessary. It seems, therefore, not improbable that the nitrogen nat-
urally dissolved along with the carbonic acid and oxygen in the water is indirectly
connected with the decomposition.

50. The presence of carbon, and an excess of hydrogen in the green matter, proves
that the sunshine has effected two different decompositions, the decomposition of car-
bonic acid and that of water.

51. At this stage of the description, let us pause and review the facts which have
presented themselves to us. We have arrived at the conclusion that all the solid ma-
terial under consideration is produced from gaseous matter contained in water in a state
of solution. This gaseous matter comes directly from the atmosphere; it contains the same
constituents as the atmosphere, but differs from it in having them in a diiferent proportion.
We see, therefore, that there are, as it were, two atmospheres enveloping the earth's sur-
face; one of these is the air which we breathe, the other that which exists dissolved in the
sea, and in those streams and waters that are found on the surface of the ground. Between
these a remarkable relation exists : in the common atmosphere the proportion of oxygen
to nitrogen is nearly as one to four, in the water-atmosphere it is nearly as one to two.

52. Between these two atmospheres, a constant connexion is established, through
the chemical relations of water, which receives its gaseous contents from several differ-
ent sources. Part of its carbonic acid it obtains by direct absorption from the superin-
cumbent air, and part is given to it by the respiration of fishes and other aquatic ani-

MODE OF DIFFUSION OF GASES INTO WATER. jg

uials ; for aniaial life, though carried on beneath the surface of this liquid medium, has
the same chemical object in view as when carried for.vard on the surface of the earth;
it ends in the conversion of carbon into carbonic acid, of hydrogen into water, and an
evolution of heat. Its oxygen, in the same manner, has two sources of supply, direct
absorption from the air, as in the former instance, and a still more concentrated store
in those little air-belJs that cover the green vegetable matter as long as the sun is shi-
ning ; in these the volume of oxygen is, on an average, double that of the nitrogen.
Upon them the water exerts its solvent powers, removes as much as it can carry away,
and the bubble then floats to the top of the w aler, and escapes out into the air. From
the same two sources nitrogen is also procured. With these abundant supplies, there-
fore, furnished partly from the vital changes which are taking place in its mass, and
partly from the external air, the constitution of the water-atmosphere is kept up unim-
paired.

53. All the carbon which we thus find in the green matter comes from dissolved car--^
bonic acid, all the hydrogen from water or ammonia ; the latter also furnishes a cer-
tain quantity of nitrogen, other portions of which are obtained, without any decompo-
sition, from that w hich has been dissolved out of the atmosphere. The general prin-
ciples of life carried on in the water are modelled on the same idea as in the case of
hfe carried on in the air. In both cases, vegetables act as the great formative agents,
and animals as the destructive power; and in both, the source and origin of action is
to be found in the beams of the sun. For nearly two centuries, physical science has
fully admitted the agency of that central star as the great seat of mechanical force,
which retains the different planets in their orbits. It is only of late years that we are
beginning to recognise his agency as the author of organization and life, who lays up, t
with an almost provident foresight, in vegetable productions, stores of hght and heat .
for the use of the animal world. The coal-fields which furnish us with fiiel are the re- \
mains of primeval forests, among the branches of which birds nestled at night ; and the
warmth that we receive from them, and the light that they give us, have been safely
stored up for us for thousands of centuries. Those little insects, also, which at certain
seasons cause the sea to shine with a phosphorescent light, derive their glow remotely
from the vegetable kingdom ; and the fireflies, which, in such countless multitudes, on

a summer evening in Virginia, make the grass and trees glitter with their intermitting -•^.
beams, are only pouring forth again rays which once came from the sun.

54. I have thus far considered the process of evolving green matter from a primitive
cell or seed placed under water. It is now proper to generalize on these views, and to
show that, so far from this being an insignificant case, it represents fully all that goes on
in the vegetable tribes, whether they live under the water or in the air. Let us. therefore,
proceed at once to investigate what takes place in the case of plants which are of a
more complex character, and higher in the scale of creation. If a few garden seeds of
any kind are sown in a flower-pot, and caused to germinate in a dark room, after a
while it will be perceived that they can grow for a certain space in the absence of light;
their young leaves, if any should be put forth, are of a yellow or gray- white colour, and jr
they soon fade away and die. But if these plants be brought out into the Ught, they

/

so

PRODUCTION OK CHLOROFHYL IN LEAVES.

presently begin to tarn green, they unfold their leaves, and evolve their different parts
in a natural way. From day to day their weight increases, and chemical analysis shows
that they are fixing carbon, hydrogen, oxygen, and azote. If they be made to grow in
confined glass vessels, under such circumstances that an examination can be instituted
on the changes they are impressing on the atmosphere, it is discovered that they are con-
stantly abstracting carbonic acid from it, and as long as the sun shines on them, or as
long as they are exposed to bright daylight, they continue appropriating carbon and ex-
haling a mixture of oxygen and nitrogen. The continuance of their growth depends
on a continued supply of the acid gas in due quantities. The leading facts which are
here mentioned were discovered during the last century by Priestley, who found that
when leaves of any kind are placed in water, which holds carbonic acid gas in solution,
they evolve oxygen when in the sunshine. It is not pure oxygen, but a mixture of that
gas with azote (Ap., 794). It has been objected that no conclusion can be drawn from
experiments conducted in this way in regard to vegetable functions, for a plant which
is fitted to carry on its living processes in the atmosphere is placed in an unnatural con-
dition when immersed in a vessel of water. But there is much less force in this objec-
tion than might at first sight appear. A leaf, exposed to the air, does not absorb and act
upon carbonic acid gas as a gas; its tissues and parts are saturated with water, which has
been thrown up by the capillary force of the spongioles, or, on some occasions, obtained
directly from the atmosphere by the beautiful process of nightly radiation to the sky, and
corresponding precipitation of drops of dew ; this water, thus penetrating every part of
the succulent structure, is the medium through which carbonic acid is absorbed and de-
composed. In point of fact, therefore, though plants may live in air, their mode of dis-
charging this function is the same as though they were living in water, for the absorp-
tive force of that liquid is called into play, and carbonic acid is. presented in a dissolved
state, and the case, in reality, becomes nothing more than a repetition of what goes on
when water-plants are digesting. In very many instances Nature takes extraordinary
pains to secure a rapid supply of the acid. In water-plants, which are often fixed, re-
liance is had on currents which are established by variations of specific gravity, so as
fast as one portion of water has approached to the place of decomposition and surren-
dered its gas, it is pressed away by those around, which are about to discharge the same
duty. But in aerial plants, the digestive organ unfolds a broad surface to the atmo-
sphere, and the calorific beams of the sun descending on it, by reason of its dark col-
our are readily absorbed ; a warm current, which is easily established in a mobile fluid
like air, rises rapidly ; and, as if this were not enough in multitudes of instances, the
trembling leaves are set upon slender footstalks, which give way to every passing wind,
and are thus continually brought into an extensive and ever-changing gaseous contact.
It is scarcely possible to conceive a more simple and effective contrivance, or one which
reaches more perfectly its destined end. To animals powers of locomotion are given,
with a view of securing a possession of food ; at proper seasons the wild pigeon comes
up from the southern countries, and instinctively flies thousands of miles ; and in the
case of many beasts, to procure their prey seems to be a principal cause of movement.
An animal, an oxydating machine, is driven by Nature to expend his powers of loco-

THE DIGESTION OF PLANTS. 2i

motion, and go in search of his food ; a plant, a reducing apparatus, has a more delicate
duty to perform, and Nature herself becomes its minister, and offers it a supply for all
its wants.

55. Under these circumstances, therefore, when leaves of aerial plants are placed in
carbonated water in sunshine, we can, so long as their structure remains unimpaired, ob-
serve with a certain degree of correctness the phenomena which they would exhibit
under more natural conditions. By botanists and the earlier writers on chemistry, the
function discharged by the green parts of plants is often spoken of as a species of res-
piration, analogous, to a certain extent, to animal respiration. This mistake originated
in those obscure physiological views of which the old doctrine of vitality was the pro-
lific parent. Respiration is essentially an oxydizing process, a process of combustion,"^
but the part which is played by a vegetable leaf is to obtain carbonaceous matter from
air, and store it up in a solid form in its various strictures. This solid matter thus ob-
tained is the very same which at an after period, entering the digestive organs of ani- ■
mals, is by them subjected to assimilatory processes, and finally becomes a part of their
fabric. The action which is performed by those green parts is not, then, a respiratory /
action, but one of digestion.

56. We have already said that leaves placed in spring water in sunshine evolve bub-
bles of gas. A direct sunshine is not, however, absolutely required; the same experi-
ment, if conducted with proper precautions, can be made to succeed with the diffused
skylighL The bubbles, as they form, rise to the top of the water, and if collected and
analvzed, yield, as in the case of water-plants, two substances, oxygen and nitrogen; a
little carbonic acid is always present, but that arises from the peculiar conditions under
which the experiment is made (Ap., 794).

57. Thus, by the influence of the sunlight, organic matter is added to vegetable sys-
tems, the action being accompanied by a variety of chemical decompositions and interstitial
diffusions. The substances arising are such as are necessary for the uses of tbe plant,
and in order to distribute them to the requisite parts, mechanical motion has to take
place. This, in the more highly organized plants, goes under the designation of the
flow of the sap. The descending sap, like the arterial blood of animals, contains all
the different compounds which are required by the organized structure. We shall in
the next chapter consider the causes which direct the movements of this liquid.

22 FLOW OF THE SAP AND CIRCULATION OF BLOOD DUE TO THE SAME CAUSE.

CHAPTER II.

ON THE MECHANICAL CAUSE OF THE FLOW OF THE SAP IN PLANTS. IT IS DUE TO THE
CARBONIZATION OF WATER IN THE LEAVES BY THE LIGHT OF THE SUN.

Contents : The Flow of Sap and Circulation of Blood are prohably due to the same
Physical Cause. — Amount of Water circulating in Plants. — Botanical Theory of the
Flow of Sap— fails for the descending Sap.

Capillary Attraction described. — Elevation or Depression of Liquids depends on their
wetting or not wetting the Tube. — No Flow in an ordinary Capillary Tube. — Con-
ditions for producing a FloiD — such as Evaporation, Decomposition, and Solution. —
Endosmosis produced on these Principles by Solution. — Dutrochefs Experiments. —
Explanation of them. — General Law of these Movements. — Force with which they
take place. — Capillary Attraction due to Electricity.

Application of these Principles to the Ascent of the Sap. — Exhausting Action of the
Leaves. — Cause of the Descent of the Sap.

The Light of the Sun is the Cause of the Flow of the Sap both in its Ascent and
Descent.

58. In the lower classes of plants, such as those of which we have been speaking,
which carry forward absorbent processes on every part of their surface, the mechanism
for nutrition and respiration is of the simplest character, and, as we shall hereafter see,
is nothing more than a surface action ; imbibition, nutrition, and aeration all taking
place upon the same point. But in any organized structure, as soon as types of cen-
tralization are adopted, and specific processes carried on in distant parts, the nutritious
juice must necessarily pass from place to place, and undergo in its route proper chemi-
cal changes. In its movements it must flow along predetermined channels, and take in
succession given directions. To accomplish this a circulatory apparatus is required,
adapted in each instance, as to form and character, to each peculiar organism. In the
higher classes of animal Hfe, this process of movement passes under the designation of
the circulation of the blood ; in plants, under the designation of the flow of the sap.

59. There is that unity of plan in all the works of Nature which causes us at once
to understand that in these various nieclianisms the same physical principles are resorted
to ; that the flow of the sap and the circulation of the blood are due to the same
powers. A theory of such movements, therefore, can only be true when the principles
which it involves give at once a clear account of every case, of the flow in plants and
in animals, and even in every individual instance in each of these great classes of
organized beings. Such a theory should be applicable to the movements in flowering
plants, and to all its various modifications in the less complicated orders of vegetable
life ; for each particular instance it should show why specific apparatus is required, and

AMOUNT OF WATER CIRCULATING IN PLANTS. 23

■whv, in cryptogamous plants, none whatever is necessary; it should show, among the
varieties of animal races, why this or that mechanism is employed ; why insects have no
heart, or why in fishes the aorta resembles in mechanism the portal vein of the mam-
malia. In those more elevated tribes whose functions require that several circulations
should be simultaneously carried on, it should give a clear account of the mechanism
for them, whether thev be systemic, pulmonary, or portaL The character of a true
theory is its extensive and clear application to all individual cases.

60. In tiiis and the following chapter, I propose to explain what appear to be the
true mechanical principles of the general circulation of organized beings. For some
years past I have taught these doctrines to the medical classes of this Universitv, though
until now they have not appeared in print. Founded as they are on principles strictly
physical, they form an important portion of the views set forth in this work. If among
plants light is the great agent of organization, electricity is the great motive force, which,
under a specific modification, determines the movements of nutritious juices. The im- *^
ponderable agents are the vital principle of organized systems. /

61. It will be perceived that the doctrines here given apply to all cases ; the}' are
also in harmony with physiological knowledge. They embrace not only the vegetable
and animal world, but the specific instances in each. In individual cases, they give an
account of the mechanism of the various circulations, whether they be systemic, pulmo-
nary, or portal. They also will be found to apply to those abnormal cases which arise
in disease, and ofier an exact prediction of what should take place in inflammation and
asphyxia.

62. First, therefore, let us take up the consideration of the circulation of the sap in
flowering plants, and show the physical conditions on which it depends. In the follow-
ing chapter we shall apply the same principles to the circulation of the blood.

63. Early in the spring, in the Southern States, the farmers plant their corn — the
Zea mays. In the course of some days, if the weather is warm and favourable, the seed
begins to germinate, and presently the young plant appears above the soil. As soon as
this has taken place, the shoot turns green, the radicles begin to extend themselves, and
growth rapidly sets in. In a few weeks the plant has risen to au altitude of several
feet, and exposes its large green leaves to the sun. By the end of July, or the middle
of August, its maximum height is attained, and, under favourable circumstances of cul-
ture and season, so great is that height, that a man on horseback cannot touch the tas-
sel which adorns the top of the plant with a walking-sticL All this enormous evolu-
tion of organized structure has, in the course of a few days or weeks, originated from

a seed buried in the ground — a seed which weighed but a few grains. /

■ 64. From the roots to the top of the plant, large quantities of fluid are constantly
passing, and large quantities are thrown off" from the leaves by evaporation. All this
water is obtained entirely from the soil, and all the carbonaceous matter which con- ''^
stitutes the solid part is derived from the atmosphere ; and, inasmuch as even the water
itself descended originally from the air in showers of rain or drops of dew, we are justi-
fied in saying that this immense mass of organized matter is nothing more than a por-
tion of the atmosphere, which has been condensed and fashioned in a few weeks by the '
agency of the imponderable principles.

/

34 BOTANICAL THEORY OF THK FLOW OP SAP.

65. In those hot climates, the quantity of sap which flows in a short space of time
through the vessels of such a plant is incredibly great. In the month of April, 1834, 1 cut
a vine, which was growing wild on the edge of a forest in Virginia, asunder with one blow
of an axe ; the cut surface, which was about 1! inch in diameter, exhibited its open ves-
sels, from which there poured out an uninterrupted stream of ascending sap. In the
course of eight hours there was collected of this fluid seventy ounces, and this was
probably a far less quantity than would have been raised under ordinary circumstances,
wliere tbe leaves aided the spongioles by their exhausting and pushing action, in the
way which will be presently explained. As all persons know, in these warm climates
processes of vegetation go on with extraordinary rapidity, and in summer, from the in-
tense brilliancy of the sun and the high temperature, the midday assumes peculiarities
which in colder chmates are never witnessed. In the forests of tiiose countries, at that
hour, there reigns an unbroken silence, a period of complete repose. The wild dove,
which all morning long has poured forth her plaintive note from the top of some with-
ered pine, seeks for a shady covert, and plumes her feathers in the heat of the day ;
the wanton squirrel forsakes his gambols, and retires to his nest ; the turtle dozes on
the surface of the stagnant pools. There is not a cloud upon the sky, there is not a
breath in the air. The sunbeams tren)ble upon the leaves, or sparkle upon the sand,
or steal in long gleams of light across the water. A profound silence reigns among
myriads of living things, inhabitants of those solitudes ; a silence only broken at inter-
vals by the rustling of the In-own lizard in the leaves, or the distant tap of the lazy '
red-headed woodpecker upon some hollow trunk.

66. As we have said, if at the proper season of the year the stem of a plant be divi-
ded, ascending sap will copiously flow from the extremity of the stump. If, moreover,
the part which has been cut off, and which bears the leaves, has its cut extremity im-
mersed in a vessel of water, imbibition of that water will rapidly take place, and Hfe
Be maintained for a time. From these facts, and others of a similar kind, botanists
have had no difficulty in recognising two distinct sources of action concerned in the
flow of the sap. They have shown that the spongioles or extremity of the roots, which
apparently consist of a lax cellular or spongy tissue, have the quality of impelling the
sap upward, and hence it flows from the extremity of a stem from which the upper part
has been cut off. From the fact that a branch on which the leaves still remain pos-
sesses the quality of removing water from a vessel in which its extremity is immersed,
they have regarded those organs as possessing a kind of suction power, due to the evap-
oration which takes place under the influence of heat from their superficies. The spon-
gioles, therefore, drive the sap upward, and the leaves, by their exhaustive effort, draw it.

67. But this doctrine is essentially defective. It furnishes no reason for the down-
ward flow of the sap ; none for the well-known fact that the exhausting action of the
leaves is under the control of light. To a certain extent, it is true, an evaporation ta-
king place from the leaves will conspire in its result with the movement of the ascend-
ing sap, but it must not be forgotten that it will also antagonize with the movement of
that which is descending. That there are two seats of action in the phenomenon, the
spongiole and the leaf is quite true ; but its causes a e very different from those goiier-

CAPILLARY ATTRACTION DESCRIBED. 25

ally supposed. The action in the leaf and the action in the spongioie is the same, and
it is precisely an example of what takes place in the passage of arterial blood to the
veins in the systemic circulation of the mammaha.

68. It is not worth while to expend any space here in refuting the old explanations
of these different circulatory movements, nor in detailing how, in the opinion of some
physiologists, even in the most rigid vegetable stems, the juices are propelled by alter-
nate dilatations and contractions of the woody tubes, much in the same manner as mo-
tions are executed by the dorsal vessels of certain animals. Nor need we describe how
the vital principle — that chimera of the Dark Ages, which has kept physiology in the
rear of all other sciences — can be brought to give one of its usual, and expeditious, and
unsatisfactory accounts of the phenomenon.

69. Without wasting time, therefore, on those futile explanations, let us pass at once
to the philosophical principles which are involved, and show how the doctrines of
common capillary attraction are capable of giving not only a comprehensive, l)ut
also a beautifully simple explanation of the whole phenomena, no matter whether they
are found in flowering or in flowerless plants, in sponges, or in the mammaUa.

70. Capillary attraction, of the physical cause of which I shall presently speak,
takes its name from the circumstance, that if a glass tube of small diameter, or even as
fine as a hair (capillus), be immersed at one end in water, the water immediately
rises above its true hydrostatic level to an altitude which is greater in proportion as the
tube is smaller ; in tubes of very narrow diameter, such as those here referred to, an
elevation of many inches is without any kind of difficulty obtained. Thus, mjig. 108,
if some water be placed in a cup or other vessel to the height A B, and there be plun-
ged into this water glass tubes such as D, E, the water at once spontaneously rises
in those tubes to a height which is greater in proportion as the tube is narrower. In
E, therefore, it rises higher than in D.

71. But this elevation from the true hydrostatic level only take place with certain
Hquids in certain tubes. Thus, with the same glass tubes, D and E, if quicksilver is
used instead of water, so far from there being an elevation, there is an analogous de-
pression. The liquid metal is forced down, as it were, beneath its proper level to a
greater depth in proportion as the tube is narrower. And that this depends on the
chemical relation which subsists between the liquid employed and the substance of
which the tube consists, is clearly shown by smearing the interior of a glass tube with
tallow or oil, and then immersing its end in water. The water, under these circum-
stances, so far from rising, is, like quicksilver, depressed.

72. The physical law under which these elevations and depressions takes place is
very simple, and important to be remembered. If a hquid can wet the surface of a
solid, it will rise in a tube formed of that substance ; but if a liquid cannot wet a solid,
it will be depressed below its true level in a tube formed of that substance.

73. Suppose, now, we had a glass tube immersed in water, a tube of such diameter
that it could cause the water to rise to the altitude of twelve inches, and the tube be
broken off so that it is only six inches long. The theory of capillary attraction, and
also direct experiment, show that under these circumstances the water will rise to the

D

2g CONDITIONS FOR PRODUCING A CONTINUOUS FLOW.

top of the tube, but will not Jlow over, as one might perhaps have expected. lu an or-
dinary capillary tube, therefore, nothing like a constant flow can take place, but the
liquid having attained its highest possible elevation, remains there.

74. That a continuous flow should take place, all that is necessary is, by any proper
means, either by evaporation, chemical action, or other processes, to remove away the
superficial portions of the elevated liquid when they stand at the extremity of the tube.
An illustration will show how this is accomplished. The wick of a lamp is nothing
more than an extensive system of capillary tubes, tubes which are formed by the juxta- -*
position of the cotton fibres. As common experience satisfies us, such a wick may be
immersed in a reservoir of oil for months, or even years, without any sensible poi'tion
of that hquid being removed ; but if the lamp is hghted, the process of combustion dis-
sipating the oil as fast as it reaches the upper portion of the wick, fresh quantities are
furnished from beneath, and a continual flow takes place until all the oil is gone. So
also in a spirit lamp, as long as the extinguisher is over the wick, and no evaporation
of the alcohol can take place, there is no flow ; but the moment the extinguisher is remo-
ved, so that evaporation into the atmosphere can be accomplished, there is a constant
upward flow until the alcohol is dissipated. These are results which have been long
recognised.

75. From these elementary considerations, therefore, it is clear, that although, in the
ordinary use of a capillary tube, continuous movement along it is not witnessed, that
movement readily sets in as soon as the proper conditions are fulfilled. In the two
cases we have used as illustrations, combustion in the one, and evaporation in the other, ,
gave rise to a continuous motion.

76. In the same way a variety of other ordinary causes may produce these move-
ments. Suppose,^jg. 109, we had a vessel A, containing water, and another vessel B,
containing alcohol, and between them a narrow capillary tube, C, passing. Let us
farther suppose this tube C to be previously filled with water. At its extremity which
opens into the vessel B, containing alcohol, it is clear that the water will be brought
in contact with the alcohol, but in this liquid water is soluble ; and, therefore, as fast
as that water can be presented, the alcohol will dissolve it, take it up, and remove it
away. It is plain, therefore, that there will be a constant flow of water from the ves-
sel A to the vessel B, a flow which arises from the circumstance that the water is dis-
solved from the end of the tube as fast as it presents itself, by the affinity of the alco-
hol for it. This, therefore, is nothing more than a repetition, under another form, of the
cases already used above (74) as illustrations.

76. But an attentive consideration of the facts will convince us that the affinity thus
existing between the two liquids, and which thus gives rise to a flow from A to B,
ought, after a short time, to cause portions of the alcohol to find their way through the
water in the tube C, and present themselves in a certain quantity at its entrance into
the vessel A ; there, in their turn, they are exposed at once to the pure water, which
takes up and dissolves alcohol just in the same way that alcohol takes up and dissolves
it. There must, therefore, be a constant flow of alcohol, from B to A, along the tube,
for the very same reason that there is a simultaneously constant flow of water from A
to B, in the contrary direction.

ENDOSMOSES PRODUCED ON THESE PRINCIPLES BY SOLUTION. 27

77. The general result of these considerations proves, that if two different liquids,
which can dissolve one another, communicate through a tube which both can wet,
both of them will flow through that tube contemporaneously, the one passing in one,
and the other in the opposite direction ; and it is plain that all this is nothing more
than a simple case of common capillary attraction.

73. What happens through one will, under similar circumstances, happen through
one hundred or any number of tubes. If, therefore, instead of a single tube C, a great
number of tubes were made to communicate between A and B, they would all act alike,
and through them the two liquids would simultaneously pass in opposite directions.

79. It is also obvious that the shorter we make the tube C, or the supposed collec-
tion of tubes,. the more readily will the flow take place, because the vessels A and B
are then made to communicate through a shorter obstacle. If, therefore, we take a
box, A ^,Jig. 110, and divide it water-tight by any porous obstacle C, such as a piece
of paper, or bladder, or porous earthenware, &c., which substances may be regarded as
consisting of a congeries of very short tubes, their pores answering to such short tubes,
and in the compartment A place water, and in B alcohol, through the intervening bar-
rier interchange will take place ; and if there be no leakage, and one liquid passes more
rapidly in its course than the other, not only will the interchange we have been de-
scribing take place, but there will be also an accumulation of liquid on one side of the
barrier C, and a diminution of it on the other.

80. All this is irrespective of the shape or form of the vessels, which may be cubical,
or round, or of any other figure. The essential conditions for action are to have t«o
liquids, which have an affinity for one another, placed on opposite sides of a pervious
obstacle or porous barrier, which both of them can weL Movement will then take
place in opposite directions ; and, if one liquid flows more rapidly than the other, there
will be an accumulation on that side of the barrier to which it goes, and a deficiency
on the other.

SI. M. DuTROCHET took a bladder, and, filUng it with alcohol, tied the mouth of it
tightly, so that none of the liquid could escape. He then placed it in a vessel of wa-
ter, and found that the alcohol came out of the bladder into the water, and the water -,
passed through the bladder into the alcohol, and, inasmuch as the water flowed more
rapidly than the alcohol, there was a constant accumulation within the bladder, dis-
tending it ; an accumulation taking place with sufficient force to burst it open, provi-
ded the experiment was continued long enough.

82. To these phenomena M. Dutrochet gave the name of Endosmose and Exos-
mose, the former in allusion to the current flowing inward, the latter to that flowing
outward. Physiologists were pleased with these sonorous designations, which ever
since have been used in the books. Some supposed that the force thus exerted b\- a
bladder was due to the remains of vitality still existing in it, arising from its organization.
It is, however, as we have seen, one of the ordinary cases of common capillary attrac-
tion, with which the vital force has no more conne.xion than its kindred principle 'K
Phlogiston.

83. The rise or depression of a liquid in a capillary tube is determined by its quali-

f

28 GENERAL LAW OF THESE MOVEMENTS.

ty of wetting or not wettingthe surface of that tube. Of two liquids in a given tube,
that will rise highest which will wet the tube most perfectly. And, therefore, we can
see in these movements, that if two liquids be placed on opposite sides of a porous sys-
tem, or at the opposite ends of a capillary tube, which is wetted by one more perfectly
than by the other, that one which exerts the most energetic action will flow fastest. If
a piece of bladder be soaked in water and in alcohol, it will be readily seen that the
foruier acts more powerfully on ir, giving it greater flexibility and translucency, and
having a stronger affinity for its tissues. For these reasons, if a mixture of water and
alcohol be tied up in a bladder, as is well known, the water will soak out and evapo-
rate away, but the alcohol will be retained. And for the very same reason, when these
two liquids are placed on opposite sides of such a porous body, the water moves fast-
est through it, as in the experiment of Dutrochet (81).

84. From these simple principles we deduce the following important law — important,
because it gives us at once a clear explanation of the rise of sap in trees, and a beau-
tiful exposition of the true cause of the circulation of the blood : When tioo different
liquids are brought in contact in a porous solid, lohich is wetted by both, but by tliem ,
unequally, that one which has the greatest affinity for the solid, or which wets it most
peifectly, will pass most rapidly through it, and may even drive the other entirely be-
fore it.

85. This passage is not accomplished with an insignificant force. Direct experi-
ment shows that (Ap., 145) water will thus pass into alcohol through a pervious mem-
brane with a force equal to the pressure of nearly two atmospheres. Nor is it alone
between liquids that the phenomenon takes place ; it is exhibited also by gases.
Here, again, the force with which the movement has been accomplished is surprisingly
great. Sulphurous acid will pass (Ap., 158) into atmospheric air against a pressure of
one hundred and ten pounds on the square inch, and sulphuretted hydrogen will move
through a membrane with a force that is superior to a pressure of twenty-four atmo-
spheres (Ap., 162). As a mechanical agent, capillary attraction, therefore, is fully able
to overcome any of the resistances which it has to encounter in elevating sap to the
tops of the loftiest trees, or driving blood from the remotest parts of the largest ani-
mals.

86. In the Appendix I have given (Chap. V.) an account of the physical principles
on which capillary attraction itself depends. It is needful, therefore, in this place, only
to sum up the evidence there brought forward, that it is nothing more than a manifesta-
tion of electricity, and that all capillary phenomena are cases of electrical attraction.
If we take a piece of flat glass, and place it on the surface of some mercury, the glass is
held to the metal with a considerable degree of force, so that it requires some exertion
to separate them. When this is done, and the electric condition of the mercury and
glass respectively examined, the one is found to be positively and the other negatively
electrified. They must therefore attract each other (Ap., 116) ; and it is owing to this
electric excitement, which always takes place upon the contact of bodies, that all the
phenomena of capillary attraction are due. Thus, if two pieces of plate glass are brought
in contact, they are found to cohere, because the one is positive and the other negative.

GENERAL LAW OF THESE MOVEMENTS. 29

Bs may be proved by exauiiuiug them with an electrometer. Even in those cases in
which attractive forces are developed without an apparent electric disturbance, these
principles apply. Two leaden bullets, which have been brought (Ap., 126) into con-
tact with one another, cohere strongly, but we are not able to show the development
of the separate electricities on each, because of their high conducting power. So, too,
when a piece of glass is laid on the surface of some water, and, on being lifted off, is
carried to the electroscope, no development can be detected, and the reason is obvious,
for there has been only an apparent, and not a true separation of the liquid and the
glass from each other ; the particles of the liquid have been simply lorn apart, and have
not been separated from the glass.

87. Referring, therefore, to that chapter for the proof that capillary attraction origi-
nates in electric disturbance, it is sufficient for our present purpose to remark, that it is -+,
therefore due to the very same caase as chemical affinity itself. The quality which
liquids possess of wetting or not wetting the surface of solid bodies is, therefore, nothing
more than an indication of the affinity which is between them. Quicksilver will not
wet glass, because thev have little affinity, but it will wet a surface of gold or of tin with
facility, because its affinity for those bodies is energetic. These obsenations, which
appear so simple, have very important applications ; the intensity of affinity between a
given liquid and a solid with which it is brought in contact determines their capillary
relations, and thereby determines, also, the phenomena of movement. No farther proof
of this importance is, perhaps, required than the result to which we shall be presently
led, /hut even in mas the circulation of the blood is caused by the oxydating action of that ^
liquid on the solid structures with which it is brought in contact.

88. Let us, therefore, hnally remember that the explanation of the circulation of nu-
tritious juices, both in the vegetable and the animal kingdom, rests upon this simple
physical principle, that if two liquids communicate with one another in a capillary tube,
or in a porous or parenchymatous structure, and have for that tube or structure different
chemical affinities, movement will ensue ; that liquid which has the most energetic affin-
ity will move with the greatest velocity, and may even drive the other fluid entirely be-
fore it; that this is due to common capillary attraction, which, in its turn, is due to
electric excitement.

89. These things being understood, let as proceed now to apply oar principle (84)
to the cases in hand, and commence with giving the theory of the flow of sap in plants.

90. The liquid of which the ascending sap is constituted is derived from the ground
by the action of the spongioles, and consists of water holding in solution the different
saline bodies which are necessary to the plant, along with carbonic acid, &c. This
compound fluid passes upward by the woody fibre and ducts of the alburuunr, making
its way to the leaf, on the upper surface of which, in common cases, a change in its
chemical constitution occurs through the influence of the sunlight. It obtains a cer-
tain quantity of carbon, and from being a thin watery solution, becomes much concen-
trated, and gains the under face of the leaf This elaborated sap, or latex, as it is fre-
quently called, returns now to the bark, and descends through its cellular tissue and
inter-cellular spaces, finding its way by the route of the medullary rays to all parts of

30 APPLICATION OF THESE PRINCIPLES TO THE ASCENT OF THE SAP.

tbe plant. During its descent the different vegetable principles necessary for the econ-
omy of the plant are removed from it, and a certain quantity goes down to the roots,
partly to aid in their growth, and partly to throw new qualities of ascending sap into
the tree. In this descent, the elaborated sap moves through a system of vessels which
anastomose with one another, in the same manner as the capillary vessels of animals.
These tubes go under the technical name of laticiferous tubes.

91. We see, therefore, from this description, that there are two points of this circula-
tion which require attentive consideration — the spongiole and the leaf The spongi-
oles are nothing but the young succulent extremities of the roots, which have been re-
cently formed from portions of the descending sap, but that sap is itself a species of
mucilaginous solution. Precisely, therefore, as water will pass through the tissue of a
bladder, the interior of which is filled with gum-water, so will moisture from the ground
flow through the spongiole. There is no difficulty in accounting for the rise of the as-
cending sap on the principles of capillary attraction, and, indeed, this is the explana-
tion now generally received by vegetable physiologists.

92. While, therefore, those philosophers have freely admitted the applicability of this
principle, under the name of endosmosis, to the explanation of the ascent of the sap,
they have attributed to it, as an aid, a force which comes into operation only in an
incidental way. This is the exhausting action of the leaf But it is probable that this
force takes little or no part in the movement of the sap, for any tendency to a vacuum
occurring in the leaves of a tree would cause those structures to collapse, and not
eventuate in exerting suction power on the rising fluid. It is true, that if we take (67)
a branch covered with its foliage, and dip its cut extremity into water, imbibition of that
water will rapidly take place ; but the phenomenon is certainly not due, as is ordinarily
supposed by botanists, to the exhausting action of the leaf, but to a very different cause.
The exhaustion is only an incidental affair.

93. Guided now by the principle we have laid down (88), let us predict what must
be the necessary action of the leaf The ascending sap, which we will suppose, for
situplicity's sake, to be water, rises- to the upper face of the leaf It there obtains car-
bonic acid gas from the air, of which the sunlight effects the decomposition, the result-
ing action being a change from water to a mucilaginous solution. In the tissue of the
leaf we have, therefore, two fluids engaged, water and a mucilaginous solution ; and
what must of necessity be the result 1 The water will drive the mucilaginous solution
before it (84-88), and force it back, along its proper vessels, into the stem. The imbi-
bition, therefore, that we perceived when a branch is dipped in a vessel of water, does
not arise, as the botanists say, from evaporation taking place on the leaf, but it comes
from the capillary reaction which is going on in the leaf between the water, which is
then presented as ascending sap, and the mucilaginous solution which has been formed
by the light of the sun. Evaporation, it is true, takes place, and comes into operation,
as I have said, in an incidental way, but the proper force which gives origin to the
whole phenomenon is the capillary action which is going on in the way just described.

94. It is the imperfection of the principle on which they were relying — the exhaust-
ing action of the leaf — that has caused botanists to look upon the descent of the sap

CAISK OF THE DKSCENT OF THE SAP. 31

as such a mysterious affair, for which they could offer no explanation. Physiologists v
have here stepped in with their phantom vitality, and have explained the descent of \
the elaborated sap on visionary hypotheses, that it was alive, or had obtained some
vital qualities. It had long been perceived that gravitation could have httle or nothing
to do with the motion, for the descending sap flows upward in a dependent branch.

95. What, then, is the reason that the light of die sun controls the rapidity of imbi-
bition— the speed with which the ascending current comes I Because it controls the
amount of carbonic acid gas which is reduced, and, therefore, the amount of elaborated
sap that is formed. Why is it that the flow from the roots diminishes when changes
are befalling tlie leaves, and why does it stop in the winter ? Because the mucilagi-
nous solution which is made by the light diminishes in quantity, or ceases to be formed
alto£etber. How is it that, when parts are rapidly developing, the latex moves fastest,
and the a-scendiug sap comes with most force ? Because the consumption and the con-
sequent formation of the mucilaginous matter are then at a maximum.

96. We see, therefore, that the two sources of force in a flowering plant, the spon-
giole aid the leaf, derive their power from ordinary physical principles. And these
considerations also furnish us with another instance of that unity of plan so often met
with in the work5 of Nature ; the same law which determines tlie action of the spon-
giole determines also the action of the leaf. The same idea is concerned in throwing
the sap upward into the stem, and forcing it down again from the leaf. And the rays
of the sun. which, by forming that mucilaginous body, gives rise to these concurrent
and harmonious actions, equally set in operation the tissues of the leaf which is freely-
exposed to their influence, and the absorbing mechanism of the spongiole, which is
buried, perhaps, many feet deep in the ground.

97. Whatever has been here said respecting the movements of the nutritious juice
in exogenous plants, appHes also to the case of endogens, the essential mechanism be-
ing the same in both instances.

9S. It has been clearly established, by the researches of comparative anatomists, that
the presence of a circulating machinery' is determined by the centralization of the nu-
tritive and respiratory apparatus. In exogenous and endogenous plants, from the cir-
cimistance that the liquid and solid material are introduced at distant points, the one
through the root, the other through the leaf, channels of communication from one
, to the other, and, indeed, to every part, are required, and hence the introduction of a
circulatory apparatus. In lower tribes of vegetable life, where tliis separation of func-
tion does not exist, the circulatorv mechanism is correspondingly absent ; the sea-weeds
absorb on their whole surface, and nutrition is directly carried forward at the points of
reception. In lichens there is the first appearance of a transfusory mechanism, arising
from the circumstance that on those parts which are shaded from the light absorption
most rapidly takes place ; here, probably, however, the channels of movement are the
interspaces between the cells, and the cause, simple capillary attraction. In mush-
rooms there is a more close approximation to the mechanism more fully developed in
the higher plants, for in them the rootlets absorb nutrient matter from the soil, from
which it passes, by capillary action, to every part of the system.

32 THE LIGHT OP THE SUN IS THE CAUSE OF THE FLOW OF THE SAP.

99. Thus, in the vegetable world, if we commence our examination with the lowest
orders of cellular plants, and pass successively through the mosses and ferns to the
flowering plants, we see the same physical cause in constant operation. They all ob-
tain their liquid and their solid food through the agency of capillary attraction — the
former from the soil, and the latter, in higher tribes, from the air. It is, moreover, in
virtue of its action as a capillary mass, that the ground becomes uniformly moist ;
and hence, through the operation of the same power, fluid matter is first brought to the
plant, and then distributed through it. It is in virtue of its capillary diffusion through
atmospheric air that carbonic acid gas is brought in contact with the leaves ; and when
there reduced, it is through the same force that the carbon is distributed to the grow-
ing parts. Of the energy of this force there is abundant evidence, not only that it can
cause the gradual percolation of juices through small structures, such as the minutest
moss, but also lift the sap to the tops of the highest forest trees, and, indeed, far higher
were it necessary, and drive it back again to the roots, irrespective of the agency of
gravity. Even gaseous substances, as is shown experimentally in the Appendix (Ch.
XL), pass into one another with a force greater than the pressure of a column,of wa-
ter seven hundred feet high ; so that, to elevate the sap in a tree, or to drive the blood
in an animal, is an insignificant demand on the energy which this force could put forth.

100. In conclusion, we here again remark the influence which the imponderable
principles exert in directing all kinds of movements on the surface of our globe. The
sap rises in a tree because the sun shines ; it is the light of that central orb which pro-
duces even these movements in plants. Indirectly, it is true, chemical affinities or elec-
trical agencies are brought into operation, but the prime mover of the machine is the
light, which produces a mucilaginous body, which is different in composition in differ-
ent plants, and which constitutes their proper juices.

101. The cause of the movement of the sap in flowering plants — both of the rise of ^
the crude sap upward, and of the descent of the elaborated sap downward — is the light
of the sun, which effects the decomposition of carbonic acid gas.

ANCIENT THEORY OF THE CIRCULATION. 33

CHAPTER m.

ON THE MECHANICAL CAUSE OF THF. CIRCULATION OF THE BLOOD.

Contents : Ancient Theory. — Description of the Systetnic, Pulmonary, and Portal Cir-
culation.— Genera/ Late of Movement. — Capillary Relations of Arterial and Venous
Blood to the Tissues. — The Systemic Circulation is due to the Deoxydation of Arte-
rial Blood, and its Direction is therefore from the Artery to the Vein.

Pulmonary Circulation. — Capillary Relations of Arterial and Venous Blood to Atmo-
spheric Oxygen. — Pulmonary Circulation is due to the Oxydation of Venous Blood,
and its Direction is therefore from the Venous to the Arterial Side. — Uses and Action
of the Heart.

Portal Circulation. — Capillary Relations of Arterial, Portal, and Venous Blood to the
Liver. — Three Sources of Force in conducting the Portal Circulation.

Action in Asphyxia. — Case of obstructed Trachea.

102. Let us now proceed to inquire how the physical principles which have guided
us, in the preceding chapter, in determining the cause of the flow of sap, applj to the
more iuteresting: case of the circulation of the blood in the higher animals.

103. The popular explanation which is given of the circulation of the blood in man,
refers to the heart as the prime mover of the mechanism. This central organ of im-
pulse is devoted to a double purpose. It has to throw the blood through the channel
of the arteries to every part of the system, and, receiving it back again by the veins,
has to throw it to the lungs, in which it must be submitted to the vivifying influence
of the air before it can again be restored to the system to be used for the general pur-
poses of the economy. In order to enalile it to discharge this task, it is furnished with
an appropriate valvular and tubular arrangement, and, at specific periods, contracts and
dilates, for the purpose of ejecting or sucking up the circulating liquid. In the opin-
ion of the older phvsiologists, these periodic motions take place either directly, for the
reason that the heart is alive, or, as some of them have supposed, through the myste-
rious agencv of the cerebro-spinal axis.

104. The blood, thus alternately driven from and drawn to this centre of action, is,
in this view, a living fluid, possessed of a great many extraordinary properties. A por-
tion of it extracted from the system by any of the ordinary processes of phlebotomy,
soon coagulates and dies. In what this change consists, this distinction between the
living and dead blood, does not so plainly appear. Moreover, the ancient physiologists
imputed a variety of other equally important offices to the heart; they regarded it as the
seat of the passions, such as love, and held it accountable for the various deeds in which its
possessor was concerned, a moral accountability for good and evil. These philosophical
doctrines have, to a certain extent, become interwoven in common speech, and we now
often use them without attaching any strict signification to them. Anatomical and me-

E

34 DESCRIPTION OF THE SYSTEMIC, PULMONARY, AND PORTAL CIRCULATION.

ohanical considerations might, perhaps, lead us to infer that these ancient views are not
altogether correct. There does not seem much consonance between mitral, tricuspid,
and semilunar valves, and affections or passions, or the responsibilities for good and evil.
A pump may be a very curious and ingenious piece of mechanism, but surely we can-
not regard it as a morally accountable agent.

105. For such reasons, therefore, modern physiologists are disposed to cast aside al-
together these ancient views, and look upon the heart as an ordinary but beautiful speci-
men of liydraulic contrivance, in the same way as they look upon the eye as an opti-
cal apparatus.

106. In man there are three prominent varieties of circulation : the Systemic, the
Pulmonary, and the Portal. It is necessary that we should undei-stand the nature of
each.

1st. The Systemic. — Arterial blood, which has been brought from the lungs by the
pulmonary veins into the left auricle, is forced by its contraction into the left ventricle,
the contraction of which drives it into the aorta. By this it is distributed to all parts
of the system, the arrangement of arterial tubes becoming smaller and smaller in diam-
eter until they degenerate into mere capillaries, from which it finds its way into the
ascending and descending vena cava, the terminal tubelets of which collect it, and it is
returned to the heart by the right auricle during its dilatation. In the systemic circu-
lation, therefore, the blood leaves the left ventricle as arterial blood, is finally distrib-
uted by the capillary arteries, undergoes, on its passage into the capillary veins, a chem-
ical change, gives off oxygen, from being bright red it turns dark, and, becoming venous
blood, is then brought back to the heart, entering its right auricle.

2d. Thf. Pulmonary. — The venous blood, thus brought to the right auricle, is forced
into the right ventricle when the auricle contracts. A similar contraction of the right
ventricle now forces it into the pulmonary arteries, by which it is distributed upon the
air-cells of the lungs ; here a chemical change takes place ; from being dark venous
blood, it becomes bright red arterial, and, being collected by the pulmonary veins, re-
turns, finally, to the left auricle of the heart. In the pulmonary circulation, therefore,
the blood leaves the right ventricle for the lungs, undergoes in them a change, giving
off carbonic acid, and then returns to the left auricle.

3d. The Portal. — The portal vein collecting blood from the chylopoietic viscera,
distributes it to the liver. This blood there mingles with that which has been derived
from the hepatic artery, and which has already been deoxydized in that organ. From
this portal blood, bile is secreted and passed into the biliary tubes. The changed blood
is now collected by the ramifications of the hepatic A^eins, along which it is transmitted
to the ascending vena cava. The portal circulation is, therefore, apparently not con-
nected with any central organ of impulse. It commences in a capillary system, and
terminates in a capillary system. There is no hydraulic mechanism for the purpose
of determining a current.

107. Of these different varieties of circulation, let us now select one, and show that
the principles we have employed in describing the flow of sap both upward and down-
ward, apply here also. Let us, therefore, confine for the present our considerations to

CAPILLARY RELATIONS OF ARTERIAL AND VENOUS BLOOD TO THE TISSUES. 35

the systemic circulatiou, and then proceed to show how the same principles bear on
the other varieties also. For, as has already been remarked, it is essential for a true
theory of these movements, not only to explain them in an isolated case, but also in
every instance ; to explain not only the systemic, but also the pulm(mary and the portal;
to explain not only the varieties of circulatory movement in one given individual, but
also in every tribe, no matter whether they be low or high in the scale of creation, or
whether they belong to the animal or vegetable world.

108. Let us, therefore, take as our guide the great principle laid down in the pre-
ceding chapter (84—88), That if two liquids communicate with one another in a capillary
tube, or in a porous or parenchymatous structure, and liavefor that tube or sti-ucture dif-
ferent chemical affinities, movement will ensue ; that liquid which has the most energetic
affinity will move with the greatest velocity, and may even drive the other liquid entirely
before it.

109. The arterial blood which moves along the various aortic branches, and is dis-
tributed to every part of the system, contains oxygen, which it has derived during
Its passage through the lungs. Its colour is crimson. As soon as it has reached its
destination in the minute capillary vessels, it begins to carry on its proper process of
oxydatiou, attacking in a measured way the various tissues through which it is flowing,
burning out their effete carbonaceous matter, perhaps also burning their hydrogen into
water. The direct result of this operation is an evolution of heat. But while this
chemical change in the tissues is going for^vard, the arterial blood itself is also suffering
a change in giving up its oxygen, which may be looked upon as its active principle,
and gaining in exchange the results of the combustion. From being crimson, it turns
dark ; from being arterial, it changes into venous blood.

110. Let us farther confine our thoughts to what nmst take place in a single cap-
illary tube, or in one small portion of a porous structure ; for whatever reasoning holds
in this case, will also hold for any number of capillary tubes, or any mass of parenchy-
matous structure. On the arterial side of such a tube we have the crimson arterial
blood ; on the venous side we have the dark venous blood — two different fluids ; but
what is the relation which obtains between each of these hquids, and the walls of the
tube or the substance of the parenchyma in which they are placed ? Must it not be
that the arterial blood, bearing its oxygen, ready to burn out any carbon or hydrogen
in its way, substances of which the tube or structure is composed, possesses an intense
affinity for those structures, an affinity which is at last exhiliited by its actual destruc-
tion of them \ The arterial blood, therefore, has an intense affinity for any of the
tissues ^^ ith which it is brought in contact.

111. In the next place, how is it with the venous blood, which occupies the other
extremity of the tube ? The affinities of the oxygenized — the arterial blood — have been
satisfied ; it has effected the combustion of the tissues through which it has gone, it has
changed into inert venous blood. From being red, it has turned dark. The very
change which has come upon it, or which, rather, it has undergone, is sufficient to as-
sure us that, so far as its chemical affinities for the surrounding structures are concerned,
those affinities are at an end. The venous blood, therefore, has little affinity for any
of those structures with which it is brought in contact.

gg CAUSE OF THE PULMOxNARY CIRCUJ.ATION.

112. To the mind of a chemist, the relation which exists between arterial and venonst
blood and the soft solids of the animal body may be very forcibly impressed by these
considerations. Regarding the blood itself as a mere vehicle for the introduction of
oxygen, and the carrying away of carbonic acid and water, and remembering that the
substances of the tissues acted upon are chiefly carbon and hydrogen, our final estimate
of the relation of arterial and venous blood respectively to those tissues comes to this —
the affinity of arterial blood is expressed by the affinity of oxygen for carbon and hy-
drogen ; the affinity of venous blood by that of carbonic acid for carbon, and of water
for hydrogen. Compared together, therefore, the former is the representative of a
highly energetic force, which in the latter is diminished down to zero.

113. Now what is the phenomena which our general principle (108) predicts, as
arising under these circumstances 1 Simply this, that the arterial will drive the venous
blood before it, and drive it with an inexpressible force.

114. The oxygenizing action of the arterial blood is, therefore, the trne cause of the
systemic circulation.

115. In the systemic circulation, upon these principles, the flow must he from the
artery to the vein.

116. The pulmonary circulation next presents itself. In this, as we have described
(106), there is a certain chemical change going on, the consideration of which gives
us the cause of the movement. We have seen that the motive force of the systemic
circulation arises from the deoxydation of arterial blood (114). How is it with the
pulmonary 1 We have here venous blood presenting itself on the air-cells, no longer
presenting itself to carbonaceous or hydrogenous atoms, such as constitute the soft
solids, but presenting itself to atmospheric air, or, more truly, to oxygen gas itself, which,
being the more absorbable of the constituents of the air, is taken up and held in solu-
tion by the moist walls of the air-cells. Under these circumstances, we see plainly
that we are considering a case which is precisely the converse of the former; in that
the arterial blood had an intense affinity for the carbonaceous substances with which
it was brought in contact, and the venous none. In this, the venous blood has a cor-
responding intense affinity for the oxygen which is dissolved in the tissues with which
it is in contact, and the arterial blood has none. Movement again must ensue, but as
the conditions of the affinity are reversed, so also is the direction of the motion, for
now the venous blood drives the arterial before it, and drives it with an inexpressible
force to the heart.

117. The pulmonary circulation is, therefore, due to the oxydation of the venous
blood.

118. The direction of the pulmonary circulation ought to be from the venous to the
arterial side.

119. Had we, therefore, known nothing of the circulation in the higher order of
animals, but been instructed in the chemical relations of the blood to the soft tissues
and atmospheric air, we could, upon physical principles, have predicted the existence
of that circulation, and shown what its direction in different organs must be.

120. It may strike those who are not familinr with physiological facts, that in these

USES AND ACTION OF THE HEART. 37

'■descriptions a most important omission is made — the omission of the action of the
heart, an organ plainly connected hy position and mechanism with the phenomena we
have under consideration.

121. Physiologists have Jong seen, in opposition to the popular opinion, that the
heart can only exert a verj' subsidiarj' action. Plants are wholly destitute of such an
organ, vet their juices circulate, and there are multitudes of animals which are in the
same predicament. In insects, for example, for reasons for which we can give on these
principles a clear explanation, no such central organ of impulse appears. In fishes, the
systemic circulation is carried on without a heart, and in cold-blooded animals move-
ment in the capillaries takes place after the heart has been cut out Even in man, after
death, the arterial tubes are found for the most part empty, and it is inconceivable that
this should have happened through any possible agency of the heart itself, but meets
with a very ready explanation upon the principles we have been giving. In the case of
acardiac monsters, also, which are not uncommon, the absence of a heart seems to have
exerted little agency on development and growth. Moreover, when we inquire into
the condition of the circulation in the earliest periods of existence, we find that, far
from the heart being the first to appear as a central point, and its various vessels to branch
forth from it, the vessels themselves are the first to appear, and the heart, then, is subse-
quently developed.

122. What, then, is the true oflSce of the heart ? How is it that it comes to form
so essential a portion of this mechanism ? Had the Creator predetermined that in
the construction of the circulatory apparatus of man no organ of the kind should be
employed, let us consider the final difficulties which must have arisen. The systemic
circulation originates in the deoxydation of the blood, the pulmonary in its oxydation.
We can conceive that advantage might have been taken of the excess of mechanical
force arising at the points where these chemical changes were going on, for that model
was successfully followed in the systemic circulation of fishes ; but in the case of ani-
mals which do not live in the sea, but breathe atmospheric air, there are serious diffi-
culties in the way. It is very apparent that there is no necessary connexion between
the chemical changes taking place in the lungs and those taking place in the system.
The rate of oxydation in the lungs depends on a variety of causes, and the rate of de-
oxydation is also determined by its own proper causes. There is no necessary con-
nexion between them ; and if, on either of these points of change, an excess of action
took place, the result of it must have been a disturbance of the equilibrium of the whole
circulation. At some central point, therefore, the current going to the respiratory ma-
chine and that going to the system must be intercepted — and intercepted b}' an appa-
ratus which could hold both in check, and time the movements of the one to the move-
ments of the other. In animal stmctures, motions of this kind are imiversallv accom-
plished by the help of muscular contractions, and hence arose the idea of a heart, which,
by periodic muscular contractions, should serve to adjust the flowing currents to one
another, and prevent engorgements or deficiencies in any part of the route taking place.
123. From this arrangement, also, another important advantage arose. The arterial
and venous tubes in the neighbourhood of the heart attain a considerable diameter.

38 CAUSE OF THE PORTAL CIRCULATION.

From this circumstance, they require some arrangement by which they can be filled or
emptied. The auricles of the heart relieve all their corresponding veins, to a very
great extent, from pressure ; the ventricles serve, in their turn, to fill thoroughly the
aorta and the pulmonary artery.

124. In the last place, let us turn to the portal circulation, and show how, in it, the
same physical principles apply. The blood which flows towards the liver, along the
portal vein, has been obtained by that vein from the chylopoictic viscera ; it lias, there-
fore, the same relation to the blood furnished from the different and corresponding aor-
tic branches as has the general systemic venous blood. The arterial blood, therefore,
drives it before it, in the same way that the general systemic circulation takes place,
and, passing along the portal vein, it is now distributed to the liver. In this organ it
also receives the blood which has been brought by the hepatic artery, and which has
served for the purposes of the liver.

125. The process of biliary secretion now takes place, and compounds of carbon
and hydrogen along with soda are separated as bile, and pass along the biliary tubes.
In its final effect, therefore, the chemical action of the liver closely resembles the chem-
ical action of the lungs. Compared with the resulting blood which passes along the
branches of the hepatic veins, and finds its way into the ascending vena cava, the por-
tal blood differs by containing the elements of bile.

126. Two systems of forces now conspire to drive the portal blood out of the liver
into the ascending cava. Let us consider them in succession.

1st. The blood which is coming along the capillary portal veins, and that which is
receding by the hepatic veins, compared together, as to their affinities for the structure
of the liver, obviously have this relation ; the portal blood is acted upon by the liver,
and there is separated from it the constituents of the bile ; the affinities which have
been at work in producing this result have all been satisfied, and the residual blood,
over which the liver can exert no action, constitutes that which passes into the hepatic
veins. Between the portal blood and the structure of the liver there is an energetic
affinity, betrayed by the circumstance that a chemical decomposition takes place, and
bile is separated ; and that change completed, the residue, which is no longer acted
on, forms the venous blood of the hepatic veins. In the same manner, therefore, that
in the systemic circulation arterial blood, in its passage along the capillaries, becomes
deoxydized in consequence of an affinity between its elements and those of the struc-
tures with which it is brought in contact, and drives the inert venous blood before it,
so, too, in the portal circulation, in consequence of the chemical affinities and reactions
which obtain between the portal blood and the substance of the liver — affinities and
reactions which are expressed by the separation of the bile — that blood drives before it
the inert blood which is found in the hepatic veins.

2d. But in the liver there is a second agency at work, which, conspiring in its re-
sultant, with the former, produces motion in the same direction. As we have said, the
blood of the hepatic artery, after serving for the economic purposes of the liver, is
thrown into the portal plexus. Hence arises a second force. The pressure of the ar-
terial blood in the hepatic capillaries upon this, is sufficient not onlv to impel it into

THREE SOURCES OF FORCE IN THE PORTAL CmCULATION. 39

the capillaries of the portal veins, but also to give it a pressure in a direction towards
the hepatic veins. For any pressure which arises between the arterial blood of the
hepatic and its corresponding venous blood, must give rise to motion towards the he-
patic veins ; no regurgitation can take place backward through the portal vein upon the
blood arriving from the chylopoietic viscera, because along that channel there is a pres-
sure propagated in the opposite direction, arising from the arterial blood of the aortic
branches. The pressure, therefore, arising from the relations of the hepatic arterial
blood, conspires with that arising from the pressure of the portal blood, and both to-
gether join in giving rise to motion towards the ascending cava.

127. So great are the forces which arise under these circumstances, that there is no
doubt that the blood of the hepatic artery alone could, of itself, control the circulation
of the liver without any re-enforcing aid from the portal blood. So when, from acci-
dent or otherwise, the portal vein is shut, or when from malformation it opens directly
into the ascending cava, the hepatic artery takes charge of the functions of the liver,
and directs its circulatory conditions.

12s. These views, therefore, lead us to understand that there are three sources of
force engaged, under normal circumstances, in directing the portal circulation. One
of these is found in the aortic capillaries, when they are spread on the chylopoietic
viscera, the mode of action being precisely analogous to that which obtains in the gen-
eral systemic circulation. The other two are found in the liver itself; the first is a
pressure exerted by the portal blood on that of the hepatic veinlets ; the second bv the
blood of the hepatic artery, which, conspiring with the former, urges the resulting mix-
ture along the hepatic veins into the ascending cava.

129. I might now proceed to show with what clearness these doctrines explain the
circulation of the blood in other tribes of hfe ; for example, in the case of the model
which is adopted in fishes, the aorta of which has long ago been recognised as bearing
a strong resemblance to the portal vein of the mammalia ; but, as throughout this chap-
ter these latter have been constantly referred to, I shall continue what is here to be of-
fered farther by using their type of construction for illustration. To any one who re-
flects on the principles which have been laid down, there will arise no difficulty in ex-
plaining the mechanical causes of the circulation in any particular case, more especiallv
if this plain precept is kept constantly in mind, that, for the physical reasons which have
been assigned (S8), a pressure will always he exerted in every one of these instances by the
fluid which is ready to undergo a change upon that which has already undergone it; a
pressure which, as there is no force to resist it, tcill always give rise to motion in a direc-
tion from the changing to the changed fluid.

130. As we have said, it is the character of a true theory to be applicable to all
cases, and to render a clear account of every circumstance that mav arise. A true the-
ory is like a window of crystal glass, through which we can see all objects in their
proper positions, and colours, and relations, no matter whether they are such as are
near, or those that are at a distance ; no matter whether they are directly before us, or
enter only obHquely into the field of view. A fictitious theory is like a Venitian blind,
which has to be set in a certain position with respect to the observer, and oidy shows

40 ACTION IN ASPHYXIA, ETC.

him objects for which it has been adjusted, and those in an unsatisfactory manner ; but
if he moves to one side or to the other, or endeavours to see objects which are not di-
rectly in his way, his view is intercepted, or, perhaps, unless he makes a new adjust-
ment, the light is shut out altogether.

131. Let us, therefore, see how these chemical principles will apply when the sys-
tem under consideration is no longer under normal conditions, but has passed into a
state of disturbance or of disease. It is well know^n to physicians, from the phenomena
of asphyxia, that whenever the admission of oxygen into the air-cells of the lungs is
prevented, the circulation through them simultaneously stops; but it may be renewed
again on the readmission of that gas, provided it is within a short space of time, and
recovery may and often does take place under these circumstances. What, now, is the
cause of that asphyxiated condition 1 why does the blood cease to flow ? The chem-
ical theory of the circulation of the blood through the lungs, which J have just given,
points to the oxydation of that blood as the very cause of its movement (116). It is
the pressure of the deoxydized upon the oxydized blood that drives the latter along the
pulmonary veins to the heart. But should anything intervene to prevent that oxyda-
tion taking place, no pressure can arise, and, therefore, no movement can ensue; the
conditions for asphyxia are all^resent; conditions which, however, are removed so
soon as oxydation can be reaccomplished; then movement once more takes place, and
a natural state is restored. If any evidence were required to show how litile influence
the heart possesses in controlling the pulmonary circulation, and how much depends on
the oxydation of the blood, it may be derived from the phenomena of asphyxia.

132. As another illustration, we may here bring forward and explain the fact, well
known to physiologists, that if the trachea be obstructed so that oxygen is restrained
from passing into the lungs, and asphyxia is being induced, blood taken from any of
the systemic arteries exhibits a venous aspect. What, now, does the chemical theory
say should take place in the general circulation? We are to remember (114) that the
very cause of that circulation arises from the pressure of the oxydized arterial blood
upon the deoxydized venous blood. Under the conditions supposed, we have inter-
fered with the constitution of the arterial blood, and given it a venous character; the
conditions for pressure are, therefore, not accomplished, and no pressure takes place,
and no flow from the arterial to the venous capillaries. Under these circumstances, the
impulsive action of the left ventricle must be spent in an increased pressure on the
walls of all its communicating arteries, and a simultaneous relief of pressure takes eflect
on the walls of all the veins. As, in a steam-engine, any steady variation of motion is
finally impressed upon the governor, which adjusts itself consentaneously ; so, in this
case, the heart, which acts as a governor, accommodates itself to the changes going on.
The left ventricle presently ceases in its violent effort to force the blood, and the pres-
sure on the arterial walls abates. But, if the trachea is now relieved, oxydation of the
blood goes on, pressure again takes place in the systemic capillaries, and the proper
action is restored.

133. These different facts, which might have been predicted from the theory that
the deoxydation of arterial blood is the cause of the systemic circulation, have every

ON THE PHYSICAL CONSTITUTION OF THE SUNBEAM. 4I

one beeu experimentally determined by direct experiment by Dr. Rfid (^Carpenter* s
Human Phys., p. 417).

134. We might now proceed to inquire what, on these chemical principles, ought to
take place when a reverse action ensues, as when between the arterial blood and the
tissues through which it flows those conditions are set up which lead to its more rapid
deowdalion, and the concomitant evolution of heat ; conditions w hich are found in
the various local inflammations. In these, by reason of an increased affinity between
the soft tissues and the arterial blood, deoxydation and corresponding combustion more
rapidly take place, with an abnormal elevation of temperature, and the flow of blood
to the point of disturbance is increased. The old medical aphorism, '^uhi irritatio ihi
affluxus^' translated into the precise language of modem chemistry, simply means, to
tiie point where i/s deoxydation is taking place, the arterial blood tciUjknc.

135. Bv the aid of the principles here laid down, all the various physiological or
pathological conditions which are met with in inflammation, rsphyxia, gangrene, &c.,
are presented as so manv interesting chemical problems for solution. Such cases, also,
as the non-asphyxiation of reptiles, the variable respiration and heat of insects, accord-
ing as they are in motion or at rest, the results of death from lightning, aflord abundant
opportunity for the full verification of these doctrin^. That the time has now ar-
rived when the exact sciences are to come to the aid of physiology, no one can doubt.
For many centuries past, a profitless system has been followed, the same sysiem that
formerly obtained in natural philosophy, and the uncertainties and doubts of medical
science are the best proofs of its value. It is the ruling principle of this system to sat-
isfy the inquirer for facts b}' the use of empty words, words which mean nothing and
prove nothing. Life and vitaUty, with other sonorous epithets, figure away in these
visionary speculations as though they were realities, and change their forms without
reason or rule, as do the images that we see in dreams.

CHAPTER IV.

ON THE PHYSICAL CONSTITUTION OF THE SUNBEAMS AND ON THE PRISMATIC SPECTRUM.

Contents: Modes of isolating the Coloured Rays. — Newton's Prismatic Spectrum. —
Theory of the Colours of Light. — Pluminafing Calorijic and Chemical Pmcers of the
Spectrum. — Newton s Processes for purifying the Spectrum. — Fixed Lines. — Mellon€s
Experiments on the Distrihutionof Heat. — Physical Independence of Heat. — HerscheVs
Experiments on the Thermic Spectrum. — Chemical Action of the different Begiojis
of the Spectrum on a Daguerreotype Plate. — Chemical Action on other Bodies.

136. From the foregoing observations (Ch. I.); we see that the primary formation
of organized from inorganic matter is brought about by the agency of the sunbeam, /
either directly falling on the point of change, or received in an indirect way, as the '
diff'iised light of the sky or clouds (56).

F

i

4^ VARIOUS MODES BY WHICH COLOUR IS PRODUCED.

137. In the sunbeam different principles exist, some of wiiicli are visible to the eye
and others invisible. The conjoint action of the former communicates to us an im-
pression of what we denominate white light. But in this white light there are rays
endowed with the quality of exciting the sensations of colour, such as red, yellow,
green, blue. We are required to determine which of these principles is concerned in
the physiological change we are considering. It is necessary, therefore, to describe

the SOL4R SPECTRUM.

138. A beam of light coming into a room through an ordinary window is percepti-
ble from all parts, for dust or other heterogeneous particles which are always floating
in the air scatter the rays in all directions by reflexion, and enable them to operate on
the eye. This light constitutes what is designated by optical writers as white light.
To the ordinary acceptation of the term white, it does not correspond ; it is the un-
changed, unaffected light of the sun.

139. A beam of light coming through the painted window of a cathedral falls on
the ground, or on objects in its way, and communicates to them the various tints with
which the glass has been stained. The brilliant colours which are thus developed by
the action of the glass exist originally in the white light, and are made apparent by
the absorptive action of the medium through which they have come, in a way which will
be presently explained.

140. There are al«o other modes by which, from white light, brilliant colours can be
produced. Thus, transparent media, such as gems, cut into certain shapes and polished,
when exposed to the light glisten with a play of colour. It is these brilliant hues which
give to the diamond its value as an article of female ornament. It is also in the same
way that the angular pieces of glass which are strung upon chandeliers and around gas
flames, emit in a brilliantly-lighted room so many fitful changes of colour. And in the
same way also Nature exhibits to us that most beautiful of all meteorological phenomena,
the rainbow, by refracting, reflecting, and dispersing the white light of the sun, and pro-
ducing a regular display of colours. These colours, arranged as in the rainbow, may
also be seen wherever a shower of drops of water is falling in a proper position as re-
spects the spectator and the sun ; they are often, therefore, visible when fountains are
playing; often in the sea-spray, when it is cast ashore by a brisk wind; often accom-
panying the bows of a steamboat which is moving rapidly through the water.

141. There is a third mode by which, from white light, brilliant colours are produ-
ced. It is by the interference of rays; in the same manner that two sounds may be
so situated with respect to each other as to destroy one another's eilfect, and produce
silence ; or, as two waves upon water, when the concavity of the one corresponds with
the convexity of the other, destroy one another's effect; so may two rays or waves
of light be placed, in respect of each other, that, instead of re-enforcing each other's ef-
fect, they may produce .darkness. This phenomenon, which in these different cases
passes under the general designation of interference, under ordinary circumstances, in
the case of light, is expressed by the production of brilliant colours. Such are the
beautiful and almost metallic tints that are seen on the wing-cases of certain coleopte-
rous insects, more especially certain beetles in the Southern States, which expose a

NEWTON'S PRISMATIC SPECTRUM. 43

glow of colours — greens, yellows, blues, and reds — as they change their position. So,
too, the beautiful display which is seen on the breast of the wild dove, and still more
beautifully in the feathers of the humming-bird.

142. The cause of these colours, and of the colours of light generally, was first dis-
covered bv Sir Isaac Newton, who, in his investigations, followed the second of the
methods here mentioned, the production of colour by refraction. Of late years, the at-
tention of philosophers has been much turned to the third method, that of interference ;
this, as will be presently seen, possesses, in particular cases, very great advantages over
that by refraction (140), or the first one, by absorption (139).

143. Newton's methods of investigating the production of colour b}- refraction may
be briefly described, as follows : Let a beam of light coming from the sun {s.Jig. Ill)
pass through a circular hole {a b) in the shutter of a dark room, and fall upon a piece
of glass cut into the form of a triangular prism, c d e, placed as in the figure. On the
farther side of the prism let there be a sheet of white card-board, M N, or some other
such screen, to receive the rays. The light, on its entrance into the room through the
hole in the shutter, is white, and were the prism not interposed, it would advance for-
ward on a straight line, and, falling on the screen at z, would there give a circular
white image of the sim. The interposition of the prism disturbs this white light from

its rectilinear course, and, refracting it, bends it into a new path. The disturbance pro- .
duced by the prism is of two kinds : first, the ray is moved out of the rectilinear posi- /
tion in which it would have gone ; aud, second, it no longer gives rise to a white circu-
lar image, but to an elongated and highly-coloured image, which goes under the name
of the solar spectrum. Of the intensity and beautv" of these colours it is impossible to
give any description by \%'ords. An imperfect representation of their position is given
in the frontispiece. In the coloured figure thus received on the card-board, Newton de-
tected seven different tints, red, orange, yellow, green, blue, indigo, violet Of these
colours, the red is uniformh' nearest to the point (2) to which the ray would have gone
had the prism not intervened ; the violet is most distant. And as the production of
the colours depends upon the refracting action of the prism, Newton designated the
red as the least refrangible, because it was least removed fi-om its natural course ; and
the violet as the most refrangible, because it was the most removed.

144. Now if these seven coloured rays be collected together again by any appropri-
ate arrangement, so as all to fall on one common point, that point will be of a brilliant
white, as was the point z. If two of them, as the yellow and blue, in like manner be
directed together, they will give rise to a green ; or the red and blue to a purple ; or
the yellow and red to an orange; showing, therefore, that while different coloured rays
thus give rise to compound tints, all the rays in the spectrum converged together pro-
duce white light, the same as that which originally came through the aperture a h, in
the shutter.

145. Newton, therefore, was correct in the explanation which he gave of these phe-
nomena. That the while light of the sun consists of seven differently-coloured rays,
some of which are more, and some less, refrangible bv glass. That, consequently, when
a beam falls on a triangular prism of glass, its constituent rays are not all equally re-

■44 ILLUMINATING CALORIFIC AND CHEMICAL POWER OF THE SPECTRUM.

fracted. That of them the red is least, and the violet most refracted, and, therefore,
the white image (z) which the original beam would have given, became elongated so
as to form the solar spectrum in which the constituent colours are seen.

146. Leaving now the optical arrangement by which this phenomenon is produced,
let us confine our considerations to the spectrum itself. It is to be remarked that the
purity of the constituent coloured spaces becomes greater, as the separation of the rays
is more perfect; and, as is shown in ^^. 111, these rays are diverging from one an-
other, it is obvious that the farther the screen on which they fall is placed from the
prism, the greater will be the apparent dispersion of the rays. If the screen is brought
close to the prism, the colours are but little developed, because, not being yet separated
from one another, their mixture produces white light ; but at a distance of twelve or
twenty feet, they have diverged sufficiently, and each one appears for itself

147. Inspection proves that, in this spectruni, not only do the various parts differ in
respect of the colours they show, but they also differ in their intrinsic brilliancy. A
piece of fine-printed paper, held in succession in the different colours, is legible at very
different distances. Held in the yellow, it may easily be read at a considerable dis-
tance ; but held in the violet, it must be seen close at hand, or the letters cannot be dis-
tinguished. The other coloured spaces possess intermediate powers, and, by direct ex-
periments made by Fraunhofer, it appears that the different portions of the Newtonian
spectrum have their order of illumination, as is expressed in the following table, in
which it will be perceived that the brilliancy of the yellow rays is taken as unity, and
the other rays compared therewith. The letters refer to the figure in the frontispiece.

TABLE OF THE ILLUMINATLNG POWER OF THE DIFFERENT REGIONS OF THE NEWTONIAN

SPECTRUM.

Iiileiisity ol Liglit |

111 B C 2 1
CD 29 9
PE 101)0

In E F
FG
G H

32 S

18 5
11 -

148. It is not only in illuminating power that tiiese different regions vary; they vary
also in their heating power, as is shown by their action on a thermometer. When a prism
made of flint glass is used, and the bulbs of a set of small and delicate thermometers
are plunged in the coloured spaces, it is perceived that, commencing with the violet,
each thermometer rises higher as it approaches the red region; and even beyond the
red region, where the eye can detect no trace of light, the maximum of heat occurs,
thus showing that the heat which exists in the sunbeam is an intrinsically different
agent from the light, because, by the action of a prism, it can be refracted, and is found

(j in a space in which no light exists.

149. It has been known for a long time that the white chloride of silver, and, indeed,
all the white salts of silver, when exposed to the sun, turn black (Ap., 443). A piece
of paper washed over with any of these white bodies, as the chloride, and held in the
spectrum, soon undergoes a change. In the more refrangible region, the rays begin to
effect a decomposition, which spreads far beyond the violet extremity ; and when the
bromide of siFver is used, this darkening action is simultaneously begun from end to end
of the spectrum, and chemical action extends beyond both of its extremities. In the

PROCESSES FOR PURIFYING THE SPECTRUM. 45

same manner, therefore, that from the experiment of Sir W. Herschel, in which a point
©f maximum heat was ohserved beneath the red end, the physical independence of hght
and heat was shown, so from analogous experiments on the chemical changes exhibit- '
ed by the salts of silver, the existence of a distinct class of rays, in>i8ible to the eye, //
desiguated -chemical rays," was established.

150. These general results lead us, therefore, to suppose that there exist in the so-
lar beam a variety of distinct principles, and when that beam is acted upon by a prism
of glass, those principles are parted out from each other. Among them some are visi-
ble, affecting the eye with the sensation of the various colours of light, red, yellow,
blue, &c., and others are invisible, affecting the thermometer, or producing chemical
decompositions. The general idea which we gather from these remarks is, that there
are three separate principles coexisting in the solar ray, light, heat, and a principle of
chemical action ; and when this ray is dispersed by a prism, three several spectra arise,
of which two are invisible, and one can l)e seen. Their relative position is such as is
given in fig. 112, where A B is the luminous, and therefore visible spectrum ; C D the
invisible, chemical spectrum ; E F the invisible spectrum of heat.

151. These are the apparent phenomena which are exhibited when an ordinary so-
lar spectrum is employed. But in that spectrum the several coloured spaces are far.
from being pure, and many interesting phenomena are therefore imperceptible. New-
ton, who has never been surpassed by anv experimenter in minute investigation, studied
with great attention the peculiar circumstances which conspire in the production of
the ordinary spectrum, with a view of isolating each one of tlie coloured spaces in a
state of purity.

152. First, he shows that, when an image of the sun i^i formed in a dark cham-
ber upon a screen, as at z {Jig. Ill), that image does not terminate in a sharp circular
edge, as is the case with the object himself, but is surrounded by a penumbra, the light
gradually fading away Cfig. 113). This can be wholly removed by placing a convex
lens so as to receive the ray, and give an image in its focus. And just as the solar im-
age is surrounded by the penumbral ring, so also does tiie same defect aecompanj the
rays when dispersed by the action of the prism, for the faint light of the penanibra kj.
equally decomposed and dispersed with the bright light of the central image. Such an
effect is seen in fig. 114.

153. Suppose, now, that by the use of a lens the penumbra is removed, and the di-
rect solar image (2) received on the screen is seen to be terminated by a sharp and
well-defined edge — the image, of course, will be perfectly circular. If, now, a prism is
placed behind the lens, in such a position as to intercept ihe convei^iog beam of light,
as at C (^fig. 115), where A is the aperture in the shutter, B the convex lens converging
the rays that come in through the aperture to a focus, F, where they form a circular
image of the sun, the rays are bent on one side by the prism C, and a neat spectrum
is formed on the screen at D E, with sharp edges, and devoid of any penumbral con-
timiation.

154. But the image of the sun is circular, and the spectmm itself arises from the sep-
aration and successive superposition of coloured circular images, that separation being.

4(5 PROCESSES FbR PURIFYING THE SPECTRUM.

due to the different refrangibility of those different coloured rays. Let, therefore, iff
Jig. 116, r o 1/ g b i V be a series of such circular images, all conjointly composing the
spectrum E D, arranged in their proper order, r being the red image, and v the violet ;
if we take any one of these images, such as y, and consider its constitution, we shall
find that, by reason of the overlapping of the adjacent images, there are rays in it
which belong to the images on either side, and instead of the circle y consisting of
yellow light only, it includes orange light derived from the circle o, and green light
derived from the circle g, as is obvious from the overlapping of those circles o and g,
upon the circle under consideration, y.

155. Farther, an ordinary spectrum without a penumbra differs in constitution in its
various parts. If a line, E D, be drawn through its centre longitudinally, the over-
lapping of the successive circles along that line takes place to the greatest extent ; but
if another line, m n, be drawn along its edge, on that line the successive circles do not
overlap, and, therefore, while along the axis of the spectrum, E D, the intermixture of
the rays and of the colours is at a maximum, along the edges of the spectrum there is
no overlapping, no intermixture, and each one of the coloured rays is in a state of
purity. The light of such a spectrum, therefore, becomes more and more homogene-
ous as we pass from the axis and go to the outer edge.

156. But suppose the total length of the spectrum remaining the same, those circu-
lar images are diminished in diameter, as in Jig. 117. Here, through that diminution
of diameter, overlapping is prevented, and each one of the rays is separated out for itself,
there is no superposition, and the colours are equally homogeneous in the axis of the
spectrum and on its edges.

157. This diminution in the magnitude of the circular images may be produced in
practice in several different ways. The one which Newton recommends, and which
is generally adopted, is to use the aperture in the shutter as the radiant source, instead
of the sun himself The diameter of the sun subtends an angle of about half a degree.
But over the diameter of the aperture in the shutter we have, of course, a complete
control ; we can make it half an inch, or the hundredth of an inch, as experiments re-
quire. Instead, therefore, of adjusting the screen, E D,Jig. 115, at such a distance as
to receive the image of the sun himself, we remove it farther off, until we have depicted
upon it an image of the aperture in the shutter well defined, and with sharp edges
Gn interposing the prism, we find upon the screen, when adjusted to the proper focal
point, a spectrum of the aperture, in which the separation of the rays may be carried to
any extent by diminishing its diameter.

158. When this diminution is carried too far, the quantity of light admitted becomes
very small, and under these circumstances Newton shows that great advantages arise,
by employing, instead of a circular hole, a longitudinal slit or oblong aperture; then the
separation of colour is equally perfect, and more light being admitted, the different ex-
periments may be made in a satisfactory way.

159. Under certain circumstances, it is desirable to possess a spectrum in which the
intermingling of the colours by overlapping takes place in a regular manner. The plan
adopted by Newton was to employ a triangular hole. The image of this, when form-

FIXED LINES IN THE SPECTRUM. 47^

ed by a lens and dispersed hy the action of a prism, is as is given in Jig. 118; where
the triangles overlap at the bases, A B, and the intermixture of the different colonred
rays is at a maximum, but at the other side of the spectrum the vertex of each triangle
being separate from those on either side, the colours are, of course, in a state of purity.

160. These are the chief improvements which were iutroduced by Newto.n in the
formation of the solar spectrum, and it was in one purified in the manner here descri-
bed that his most delicate experiments were made. It is extraordinary, that after he had
advanced so far as to the use of a lens, and a narrow longitudinal aperture, that the
discovery of the fixed lines escaped him. Even if his glass prism was imperfect, these
lines are easily seen with prisms made from pieces of looking-glass cemented together
and filled with a solution of sugar of lead, and such prisms Newton says that he em-
ployed.

161. The dark lines in the solar spectrum were first perceived by Dr. Wollaston,
and described by Fraunhofer. They may be seen by forming on a screen of «hite
card-board, J?g-. 2, Frontispiece, the spectrum of a narrow fissure or chink. The lens
may be a common convex lens, or an achromatic; the prism should be without veins
or other flaws ; under these circumstances, as soon as the screen is brought into the fo-
cal position, so that the spectrum is produced with sharp edges, a number of dark lines
will be seen crossing it in certain positions. Of these, a sketch is given id Jig. 103, and
in the frontispiece. These different fines have been designated by Fralnhofer by the
letters of the alphabet, as follows : A is in the red region, B in the red near its outer
end, C is beyond the middle of the red, D is in the orange, and is a double line, E is
in the green, F in the blue, G in the indigo, and H in the violet

162. Of the fixed lines, it is only the larger which can be seen by projection npon a
screen. Viewed through a telescope, a vast number of minute ones become visible.
Fralnhofer estimated them at 600, and these are now known to constitute a part only
of those which actually exist. In the solar spectrum, they maintain their position
among the different coloured spaces, and the same observation applies to the light which
comes by reflection from any of the planetary bodies. In artificial lights they are not
seen ; and in the rays which come from the various fixed stars, although they are pres-
ent, they are found in different positions and in different groups.

163. It has already been stated that when any salt of silver is exposed to the spec-
trum (149), a decomposing effect takes place, and the salt becomes black. If the spec-
tram used be one of a narrow fissure, so that the fixed lines are visible, it will be found
that the resulting impression contains them ; that where there is a fixed line there is a
corresponding want of action upon the decomposed surface ; and, farther, that beyond
the extreme violet end, and in a region where the eye can perceive no light, the chem-
ical impression reveals remarkable groups of these inactive spaces, M N O V,Jig. 103.
These extra-spectral lines were discovered about the same time by M. Becqlerel in
France, and by the author of this book. M. Becquerel's description of them was,
however, published first Their use has become essential in all chemical investigations
connected with light.

. 164. Without anticipating here what will have presently to be rtated in regard to

^ DISTRIBUTION OF HEAT.

the chemical agencies of the solar beam, our attention is first to be directed to its cal-'
orific properties. The following facts, which are gathered from the writings of M,
Melloni, who has cultivated this department of physical science with such remarka-
ble success, will serve to give an idea of the opinions which have been advocated by
that eminent philosopher.

165. The different illuminating power of the different regions of the spectrum is, of
course, plainly evident to the eye. Newton supposed that the calorific effect of the
different spectrum regions followed the same order, and, therefore, that the yellow space
was the hottest. In this view he was followed by Landriani, Sennebier, Rochon,
and others. But at a later period, Sir W. Herschel having observed that when dif-
ferent coloured pieces of glass were employed to intercept the solar rays, the amount
of heat which traversed them was not in proportion to the amoimt of hght, he made
trials on the solar spectrum by putting thermometers in its different colours and mark-
ing their elevations. In the course of these experiments he substantiated two remark-
able facts : 1st. That below the red region, and in a space where no light could be
seen, the thermometer rose. 2d. That tlie point of maximum temperature was not, as
Newton supposed, in the yellow, but totally out of the coloured spaces, and among these
dark rays which are less refrangible than the red rays of light.

166. These experiments were repeated by various chemists, and with very contra-
dictory results, some affirming the results of Sir W. Herschel, and others dissenting
from them. Seebeck, however, eventually proved that this arose from the nature of
the prism used. That when flint glass was employed, the maximum point was in the
dark rays ; that when crown glass was used, it was at the extremity of the red; for sul-
phuric acid and alcohol, it was in the orange ; for water, it was in the yellow.

167. M. Melloni repeated these experiments with the aid of an improved thermom-
eter, and established their correctness. He took a prism of crown glass, which gave the
maximum of temperature at the extremity of the red, and determined the distribution
of heat in the coloured spaces, and also in the dark region outside of the red. Then
he interposed a layer of water, so that the rays emerging from the prism were trans-
mitted through it, and again measured the temperatures in the obscure and the lumi-
nous spaces. They were found altered ; some were totally destroyed, others partially,
and others had escaped without sensible change. The greatest absorption had taken
place among the least refrangible, the action having been less and less as the red ray
was approached ; it diminished through the red, the orange, and a part of the yellow,
and then to the end of the violet it disappeared.

168. The direct effect of this partial absorption is, of course, to move the maximum
point, and bring it successively through the red, the orange, and tlie yellow region. These
experiments also show that the heat distributed through the solar spectrum is not a ho-
mogeneous agent, for the same medium acts differently on its differently refrangible parts.
In the same manner, M. Melloni showed that the calorific rays arising from artificial
sources, whether luminous or dark, were heterogeneous, and perfectly like the analo-
gous rays existing in the sunbeam. That while most transparent substances had the
quality of absorbing some of these rays, and allowing others to pass, there is one body,

INDEPENDENCE OF LIGHT AND HEAT. 49

rock-salt, which is equally permeable to them all It therefore constitutes the true
glass of radiant heat, and glass and water and other diaphanous bodies act towards heat
as coloured media do to light ; thej" possess for it an invisible coloration.

169. When, therefore, we attempt to investigate the distribution of heat in the solar
spectrum by the aid of a colourless flint glass prism, we are doing the same thins; as
if we were attempting to study its coloured spaces by employing a prism of blue or
green glass. Such an instrument would, of course, wholly disturb the proper constitu-
tion of the spectrum, absorbing some rays and letting others pass ; and as it acts towards
light so does flint glass act towards heat, because it possesses an invisible coloration
for that principle. But rock-salt, which is transparent equally to all these rays, will
not produce such an eflfect, and hence, in all investigations connected with radiant heat,
prisms of that mineral ought to be employed. When this is done, it is found that the
maximum of temperature in this normal spectrum exists in the dark space, not in con-
tact with the red extremity, as Sir W. Herschel supposed, but wholly detached from
the colours, at a mean distance equal to that which exists in the contrary' direction
between the red and the yellow. If the ra>s which form this normal spectrum are
made to pass through a plate of flint glass of suflScient thickness, the maximum ap-
proaches towards the red region; if one of ordinary glass, it passes into the red ; if water
or alcohol be used, it enters the beginning of the jellow. But, by reason of the limpid-
ity of these different media, the coloiu^ undergo no sensible alteration, and the maxi-
mum remains alw^ays invariably fixed at the beginning of the yellow.

170. Thus, the inferior bands of the spectrum may preserve the same ratio of lumi-
nous intensities, and lose the relations which exist in their temperatures. The calorific
elements do not follow the lot of their corresponding luminous elements. Therefore,
Ijoht and heat are two different agents, or two modifications essentially distinct of one
common agent. — (Melloni, Comptes Rendus, Jan., 1844, p. 39, &c.)

171. To these beautiful results of Melloni, Sir J. Herschel {Phil. Trans., 1840, p.
52) has added other very remarkable ones, obtained by a different process. If we
take a slip of thin writing paper, and, having blackened one side of it by exposure to
the smoke of a candle, adjust it so as to receive the solar spectrum, and with a flat
brush equal in breadth to the paper dipped in rectified spirits of wine, wash over the
white surface until the paper is completely saturated, and looks of a uniform black
colour, " a whitish spot begins to appear below the extreme red end of the luminous
spectram, which increases rapidly in breadth until it equals the breadth of the luminous
spectrum, and even somewhat surpasses it, and in length till it forms a long appendage
exterior to the spectrum, and extends, moreover, w iihin it, till it reaches up to, and be-
yond the centre of the yellow ray. In this state, and just as the general drving of the
paper begins by whitening the whole surface to confuse the appearances, a second sudden
and copious wash of alcohol from above downward must be applied, without disturbing
the spectrum, or in any way shaking the apparatus. The superfluous alcohol will have
hardly run off, when the phenomena of the thermic spectrum begin to appear in all
their characters ; at first faintly, and, as it were, sketched in by a dimness and dulness
of the otherwise shining and reflective surface of the wetted paper ; but this is speedily

G

50 ACTION OF THE SPECTRUM OF THE DAGUERREOTYPE PLATE.

exchanged for a perfect whiteness, marking by a clear and sharp outHne the lateral ex-
tent of the calorific rays, and by due gradations of intensity in a longitudinal direction
their law or scale of distribution, both within and without the luminous spectrum."

172. "The most singular and striking phenomenon exhibited in the thermic spec-
trum thus visibly impressed is its want of continuity." It consists of several distinct
patches, or round solar spots, as is seen in^^. 119.

173. These are the leading facts in relation to the distribution of heat in the New-
tonian spectrum. Let us, in the next place, proceed to examine the laws of the dis-
tribution and action of the chemical rays, commencing first with the decomposition of
one of the salts of silver, as, for example, the iodide of silver, which forms the basis of
the Daguerreotype.

174. The action of the Newtonian spectrum on the Daguerreotype plate is very re-
markable. Imperfect attempts were made, soon after the preparation was published,
to determine the changes which happen to this very sensitive substance. For the most
part, these, however, were made without any kind of precaution as respects the purity
of the dispersed colours — precautions which Newton, a century ago, so clearly pointed
out. Instead, therefore, of spectra of great purity, in which the length is many times
greater than the breadth, drawings were given in which the breadth of the solar image
is equal to its length. Whoever remembers that, in the experiments conducted by New-
ton with a view of determining the phenomena of homogeneous light, and in which
the lengths of his spectra were sometimes seventy times greater than their breadth, will
easily understand how small must be the value of such imperfect proofs, which, indeed,
can scarcely be called impressions of the solar spectrum.

175. The impressions obtained in July, 1842, in Virginia (A p., 645-647), and which
may be taken as almost perfect specimens of the action of this variety of spectrum,
were made by strictly following the precautions of Nk.wton (152, 153). Several of
them were obtained, representing the action under various changes in the dimensions
and figure of the aperture admitting the light ; as, for example, when it was a circle, a
triangle, a fissure. Of the former of these, a very elaborate account has been given in
the Philosophical Magazine, by Sir J. HfRscnEL (Phil. Mag., Feb., 1843), who has
deduced from it what is probably the true theory of the action of light on the Daguer-
reotype plate. In these perfect spectra there are certain peculiarities which cannot at
all times he produced; they require an exceedingly brilliant sun, and a clear sky. In
tropical latitudes there is no difficulty, during the heat of summer, in obtaining them ;
but in New- York, during a great many trials which I have made in the course of two
years, I have but once been able to reproduce them.

176. The solar spectrum obtained upon iodide of silver may be roughly divided into
two great and almost equal regions : the upper region, corresponding to the more re-
frangible rays, embraced between the blue and the extreme violet, exhibits, by a deep
dark colour, or series of colours, that a decomposition of the iodide has taken place ;
probably in those portions in which this decomposition has been complete, the iodide
has lost one half of its iodine; the lower region, which is by far the most interesting
portion of the two, and by far the most difficult to study, corresponds to the lesser re-

ANTAGONIZING ACTION OF THE TWO ENDS OF THE SPECTRUM. 51

frangible rays, which are included between the extreme red and the blue. There is
no difficulty, at any time, in securing the representation of the upper, but it is in this
lower part that the diversity of result is so great, and about which there is so much
difference of opinion among different authors.

177. I regard these two classes of rays — the more and the less refrangible — as ex-
hibiting, upon the iodide of silver, antagonizing and contrary actions, the former exert-
ing a decomposing agency, the latter a protecting agency. The circumstances under
which the lower region makes its appearance are only found when the sky has that
degree of brightness that the sensitive surface is slightly stained by it ; the spectrum
rays then exert their protecting agency on the places on which they fall, and maintain
the iodide in an undecomposed state. That this is the true statement seems clear to
me, from the circumstance that the phenomenon is independent of time. It is immate-
rial whether we expose the sensitive surface for five minutes or for an hour, no change
whatever takes place in this lower region ; the iodide remains equally imdecomposed
Now this must arise from the circumstance that the decomposing effect of the skylight
is exactly balanced by the protecting agency of the lower rays — so exactly balanced
that it is immaterial whether the exposure be for one minute or for an hour, the result-
ing action is the same.

178. This view of the relation between the more and less refrangible rays, in the
action on iodide of silver, is strengthened by what is known to take place when phos-
phorescent surfaces are exposed to the sun. In that case, as all writers agree, the lesser
refrangible rays can not only exert a protecting agency, but even extinguish the phos-
phorescent glow occasioned by those which are more refrangible.

179. Exposed to the prismatic spectrum, different compound substances give rise to
very different results. In some cases the change is limited to one, in others to other
regions of the spectrum. Thus the iodide of silver seems to be decomposed by the
more refrangible rays, the chloride exhibits a greater range of the same species of ac-
tion, the bromide is blackened by every ray from end to end of the spectrum. Of these
different results a very extensive series has been mad#J«own. They have occupied
much of the attention of Sir J. Herschel, who has published the results of his inves-
tigations in the Transactions of the Royal Society.

180. Fig. 120 shows such impressions on different substances, a being the effect on
the iodide, and b on the bromide of silver. In these it is to be remarked, that not
only does the length of the figure vary very greatly, but also the position of the maxi-
mum point.

52 THE INTERFERENCE SPECTRUM.

CHAPTER V.

ON THE INTERFERENCE SPECTRUM.

Contents : Defects of the Prismatic Spectrum. — Mode of forming the Interference
Spectrum. — Its Peculiarities. — The Distribution of the Colours, and Law of their In-
tensities.— Reflected Interference Spectrum. — Its Fixed Lines. — Wave-lengths of the
Seven Great Rays.

Mellonis Researches on the Distribution of Heat in Perfect Prismatic Spectra. — Ap-
parent Identity of Light and Heat.

Distribution of Chemical Force in the Interference Spectrum. — Comparison of the Fix-
ed Lines in the Prismatic and Interference Spectrum. — Mode of Defining Chemical
Effects by Wave-lengths or by Times of Vibration. — Imjyression on Bromide of Silver.
— On Chloride of Silver. — Total Change in the Distribution of Heat in the Inter-
ference Spectrum.

181. The prismatic spectrum is obtained in a state of the greatest purity when the
decomposed beam of light comes through a narrow fissure, and the instrumental ar-
rangement given in (153) is employed. All the fixed lines are then thrown upon the
screen, and the separation of the different homogeneous rays is accomplished, perhaps,
as perfectly as is possible.

182. But in this spectrum, as employed for investigating the chemical action of the
solar beam, very serious difficulties may be traced. If we inspect a photographic im-
pression, or if we consider the intensity of the luminous rays in its different parts, we
perceive that, as the violet end is approached, the different changes take place in a less
abrupt manner ; the light fades gradually and imperceptibly away, the photograph does
not end sharply, but, spreading itself out to a great distance, disappears so gradually
that we can scarcely say where its termination is, and the fixed lines increase in num-
ber and breadth compared with what we perceive at the red extremity.

183. These different results obviously arise from an inherent defect in the prismatic
spectrum ; a defect which originates in the very cause which gives rise to the spectrum
itself — unequal refrangibility. Of two sets of rays compared together, one set taken in
the red, and the other in the violet region, it is obvious that, in the same spectrum,
from the very circumstance of their greater refrangibility, those in the violet will be
relatively more separated from each other than those in the red. That is to say, if we
have two rays, a and b, in the red, whose indices of refraction are almost identical, and
which, projected in the spectrum, would stand close to each other, side by side, and
another pair, c and d, in the violet, whose indices of refraction bear precisely the same
relation to one another, these last, by the act of refraction, will be more separated, be-
cause they are relatively more refrangible than the former. The result of this increased
separation in the more refrangible regions is to give an apparent dilution to them, while

MODE OF FORMING THE INTERFERENCE SPECTRUM. 53

the lesser refrangible regions are concentrated. The relative position of the colours
must also vary ; the fixed lines must be placed at distances greater than the true dis-
tance, as the violet end is approached.

184. In all investigations on the chemical action of the spectrum, the greatest impor-
tance is to be attached to these considerations, for our estimates of chemical results de-
pend on the amount of action taking place in a given time. When, therefore, we ob-
tain a prismatic impression on any sensitive surface, it is very far from representing the
true character of the phenomena. The action which ought to be concentrated in a
lesser space at the more refrangible region is spread over a greater, and with that aug-
mentation au apparent diminution of the amount of action is perceived. This, of
course, should make the maximum point vary, spread out unduly the violet end, and
dilute the true effect The different regions of the prismatic spectrum cannot be fairly
compared with one another.

185. My attention having been directed to these peculiarities, I obtained from the
mint at Philadelphia, in May, 1843, a piece of ruled glass, with a view of examining
the different questions for which solutions had been apparently obtained by the defec-
tive use of the prismatic spectrum, substituting for it the interference spectrum of Fracn-
HOFER. I am particular in mentioning this date, because I perceive that, at the very
time that I was making these trials in New- York on the chemical agencies of the spec-
trum, Professor Masotti was doing the same thing for the luminous rays in Italy, as is
stated by M. Melloni, in the Comptes Rendus, Jan., 1844, p. 44 ; and it is possible
that, before the time that this volume reaches the Continent of Europe, other skilful ex-
perimenters may have followed in the course of Professor Masotti, and, perceiving the
great advantages which arise, may have applied it for the chemical rays.

186. As the interference spectrum is less known than the prismatic, I will here give
a brief account of the mode by which it is to be formed for experimental purposes, and
of its peculiarities.

187. The principal apparatus is a grating composed of a number of intervals, alter-
nately transparent and opaque. A piece of glass, with lines ruled on it with the point
of a diamond, forms the best grating ; these hues should be parallel to one another, equi-
distant, and so close that several hundreds, or even thousands of them, may be com-
prised in an inch. To so great a degree of perfection did Fraunhofer carry this kind
of work, that he obtained gratings containing 30,000 lines in the inch. A beam of
light, directed horizontally into a dark room by means of a heliostat, is to be trans-
mitted through a fissure, as in the arrangement for showing the fixed fines in the pris-
matic spectrum. At a distance of several feet, the ray is received on the ruled glass,
behind which, a few inches intervening, a piece of ground glass is placed. The lines
which are upon the glass are to be adjusted so that they are parallel to the sides of the
fissure through which the light enters. In Fradnhofer's arrangement, instead of a
ground glass, a small achromatic telescope was placed, having a mechanism for meas-
uring angular deviations, and rotating on an axis coincident with the centre of the gra-
ting ; die following facts, which may less exactly be verified with a ground glass, were
then determined. Upon the axis of the ray coming in through the fissure, a white

54 DESCRIPTION OF THE SUCCESSIVE SPECTRA AND THEIR LINES.

image of that fissure was seen ; its sides were perfectlj sharp, and of the same appear-
ance as though the grating had not intervened; on the riglit and on the left of this
image, two equal spaces, completely dark, and, beyond each of these spaces, a series
of solar spectra, each having its violet extremity pointing inward towards the central
image, and its red extremity outward. Of these spectra, the first on each side is per-
fectly insulated, but the violet of the third projects upon the red of the second, and in
the same way each successive spectrum is overlapped by those coming after it. These
spectra are situated symmetrically on each side of the central image, and with a tele-
scope, or when other proper means are used, the fixed lines are plainly visible in them.

188. In jig. 121 these phenomena are represented : A is the central white image ;
BCD.... the successive spectra on the right hand ; E F G, the symmetrical ones on
the left.

189. If, now, we measure the distance of any one of the fixed lines, for example H,
from the middle of the central image in the successive spectra on one side, we shall
find that the distances which separate that centre from this ray in the consecutive spec-
tra on one side — H' in the first, H" in the second, H'" in the third spectrum — are in
an arithmetical progression ; A H" is double, A H'" is triple of A H'. The angular sep-
aration, measured by the instrument, between a given ray and the middle of the cen-
tral image, is termed the deviation.

190. " Fraunhofer has measured thus the deviations of the principal lines, making
use of different gratings; that is to say, of gratings the lines of which were more or less
close, and in which the opaque groove was more or less large compared with the trans-
parent interval. He has proved, in this manner, that the deviation of the same line, or
of the same colour, does not depend on the ratio of the width of the groove to the
width of the transparent interval, but on the sum of those two magnitudes; that the abso-
lute value of the deviation is in the inverse ratio of this sum ; that is to say, that in
multiplying the measured deviation by the known sum of the width of a groove and a
transparent interval, we obtain a number which is constant for the same ray, whatever
may be the grating which we use. Fraunhofer has calculated upon exact and numer-
ous experiments the values of this constant for the seven principal lines of the solar
spectrum, and finds that these values are precisely equal to the lengths of undulations of
colours corresponding to those rays, such as Fresnel had obtained by other processes."
— (Lame'.)

191. Of these phenomena the undulatory theory gives a rigorous account. It
farther shows, that the deviation of one of the colours in the first spectrum, multipHed
by the sum of the breadth of one of the grooves of the grating, and of its correspond-
ing transparent part, is equal to the length of an undulation of that particular colour.
This product, therefore, is constant for all gratings, and gives an easy means of de-
termining the length of an undulation.

192. In the same spectrum, also, the deviations of any two colours are to one an-
other as the lengths of their respective undulations. For this reason, therefore, the
violet ray is situated nearest to, and the red farthest from the optical axis.

193. From a note attached to M. Melloni's memoir {Com.i)les Rendus, Jan., 1844,

THE INTERFERENCE SPECTRUM BY REFLEXION. 55

p. 43), it appears that Professor Masotti has determined that in these beautifiil spectra
the most luminous point is in the centre of the yellow ray, which is itself placed at an
equal distance from each extremity of the spectrum. From this central point the lu-
minous intensity declines regularly and equally to each end, so that the red limit and
the violet Umit have both the same luminous intensity, and are the least luminous parts
of the spectrum. M. Masotti has also shown that the colours of these two limits are
formed by ethereal waves, the lengths of which are respectively to each other in the
remarkable proportion of 2 : 1. On the frontispiece the interference and prismatic
spectra are compared side by side.

194. Before directing farther attention to the peculiarities of the interference spec-
trum, I shall proceed to explain the method of obtaining it which I have found most
suitable for chemical purposes. Through a narrow fissure, A, Jig. 4, frontispiece, I
direct a beam of light horizontally by a heliostat, and at a distance of twelve feet I
receive it upon the surface of a piece of ruled glass, the lines of which are parallel to
each other, and rigorously parallel to the heliostat fissure, A. More than a year ago I
found that there are practically great advantages in using a reflecting grating over one
in which the light is directly transmitted. The glass, B C, is therefore to be silvered
with a piece of tin foil, so as to act like a mirror, and it will be found that the tin
amalgam upon it copies perfectly all the ruled lines. In this mode of operating there
is, therefore, no difficulty in placing B C so that the ray coming from A falls perpen-
dicularly on it, for all that is required to ensure the proper adjustment is to move B C
until it is in such a position that the ray, after reflexion by it, returns back to the heli-
ostat fissure, A. At a distance from B C of six inches, I place an achromatic object
glass, D, in such a position that it shall receive perpendicularly the reflected rays of the
spectrum of the first order ; in my arrangement this happens to be the left-hand spec-
trum, as the observer looks towards the heliostat fissure, A. The achromatic lens is
thus brought as near to the grating as possible, without its edge intercepting the ray
comiug from A. In the focus of this lens, at E F, a ground glass is placed ; it is adjust-
ed in a box, E G, and so arranged that the ground glass may be removed, and any
photogenic surface put in its place. This portion of my apparatus is, however, nothing
more than the sliding part of a common Daguerreotype camera, which contains the ne-
cessary ground glass and cases for photogenic preparations.

19-5. The apparatus being properly adjusted, so that the ground glass receives the
rays perpendicularly, the spectrum will be seen depicted upon it in beautiful perfection,
exhibiting all its striking peculiarities and its fixed lines quite visible. Every precau-
tion should be used to shut out all extraneous light

196. The descriptions given of the interference spectrum by optical writers refer
to the transmitted spectrum ; but these which are obtained by reflexion are, as Fraun-
HOFER showed, like those in all respects. For several reasons, it would be preferable
to use parallel lines ruled on a piece of polished steel or speculum metal. Silvered
glass, however, ha> the advantage of not changing readily under the influence of the
various corrosive vapours used in these researches. The grating which I employ is five
eighths of an inch long, and one third of an inch broad.

56 WAVE LENGTHS OF THE SEVEN GREAT RAYS.

197. The interference spectrum is given in^^. 133 and in tlie frontispiece, with its
fixed Hnes and coloured spaces, as seen on the ground glass. By the side of it is placed the
prismatic spectrum, the spectrum of Newton. Compared together, we see that in the
latter the yellow region is among the less refrangible rays, in the former it occupies
the central position of the spectrum. The distribution of the fixed lines is also differ-
ent, though their position, as respects the coloured spaces, is the same for both spectra.
Of course the light is distributed differently in respect to its intensity in the two spec-
tra, as has been said: for the one it is a maximum in the centre, and fades away equally
to each extremity ; but for the other, the illuminating power is as given in the table
(147) derived from Fraunhofer.

198. The following table, derived from Sir J. Herschel's Treatise on Light, gives
the lengths of the waves of Ught corresponding to each one of the principal lines of the
spectrum. The Paris inch is supposed to be divided into one hundred millions of equal
parts, one of which constitutes the unit of the scale.

Length of wave corresponding to the ray B, 2541

C, 2422
" « D, 2175

" " " E, 1945

w « « F, 1794

*•• " " G, 1587

** " " H, 1464

199. In the preceding chapter, we have given a brief account of the experiments of
M. Mflloni on the distribution of heat in the spectrum, and shown (170) how he de-
duced from those results the doctrine of the physical independence of the two im-
ponderable principles. More recently, however, M. Melloni has repeated the same
experiments (Comptes Rendus, Jan., 1844), and draws from them a result diametrically
opposed to the former,

200. That a philosopher should, with the progress of knowledge, change his opin-
ions on fundamental points of science, is very far from being a fault. For more ihan
ten years M. Melloni has studied, with unexampled success, the laws and phenomena
of radiant heat. The leading doctrine which he has deduced from those researches is
that to which we have just referred, the entire physical independence of light and heat.
From recent repetitions of his former experiments, he has now arrived at a conclusion
apparently opposite, " that light is only a series of calorific indications sensible to the
organ of sight, or, vice versa, that tJie radiations of dark heat are true invisible radia-
tions of light." The arguments which have been employed (169) in discussing the
experiments of Seebeck and others, on the shifting of the maximum point when dif-
ferent diaphanous media are used from the red into the orange, or even into the yellow,
all hang upon the admission that the spectrum under consideration is sufficiently pure,
and that there is no superposition or overlapping of its parts. For, were this the case,
even where colourless and diaphanous media are used, such as crown-glass, water, sul-
phuric acid, and alcohol, though these, by reason of their transparency, do not exert
any absorbent action on the rays of light, they might, by reason of their invisible col-

DISTRIBUTION OF HEAT IN A PURE SPECTRUM. 57

oration, absorb certain of those rays which are beyond the extreme red ; and if these
obscure rays, by superposition or overlapping, extended from their proper places into
the coloured regions above, the absorptive action of the diaphanous media would then
be exercised, and apparent movements of the point of maximum take place, such as have
been actually observed — the point shifting successively from the obscure spaces into the
red, from the red to the orange, from the orange into the yellow.

201. Now, in those spectra which were formerly employed, both by Sir W. Herschel
and M. Melloni, this very difficulty must have taken place, and the results obtained
were therefore not simple, but compound. It is obvious, if we would avoid these in-
terferences, that we must employ a spectrum capable of showing the fixed lines, the
parts of which are properly separated from one another.

202. On making use of such a spectrum, M. Melloni found the maximum temper-
ature uniformly at the extremity of the red ray, it being immaterial what diapha-
nous substance had been used as a prism or as an absorbent medium. When glasses
of a brownish colour were interposed, a colour which results from their exerting an ab-
sorbent action on all the colours of the purified spectrum, it appeared that so intimately
were " these colours allied to their temperatures, that during the transmission they lost
as much heat as light, so that the ratio of these two agents remained always unaltera-
ble." From these things it is deduced, "That the luminous radiations, disengaged from
every other heterogeneous radiation, have a heat of their own, which follows exactly
the same vicissitudes, so that the different phases of a given ray of simple light may be
measured indifferently by its luminous or calorific relations."

203. Of all the departments of physical science, there is none about which so many
experimental difficulties gather as that which is connected with investigations on the
solar spectrum, which is the point of reunion of the most energetic and powerful im-
ponderable agents, visible and invisible ; and probably we shall not obtain true views
of its constitution and properties until our doctrines have changed over and over again,
and years have elapsed. In the views just cited, M. Melloni returns to the opinions
held at the beginning of this century ; those views which led to the invention of Les-
lie's photometer.

204. That some splendid generalization will hereafter unite all these imponderable
principles, we have repeatedly said ; but there are very many facts now known which
none of the views hitherto brought forward can embrace. Under these circumstances,
it would seem that the proper course to pursue is to regard each one of these agents as
physically distinct. Notwithstanding the clearness with which M. Melloni has put
forth his recent doctrines, those who have read with attention the beautiful memoirs
which he has formerly written, will pause before they assent unconditionally. It is not
by a difficult and delicate experiment, such as that now under consideration, nor even
by a series of them, that that assent will be readily obtained. There are former exper-
iments to be explained away, former measures to be accounted for, before this desirable
simplicity can be effected. It is very true that, admitting the doctrine of the identitv of
light and heat or their common dependance on one higher agent, the experiment we have
just described meets with a ready explanation; but we become involved in difficulties

H

58 MELLONI'S EXPERIMENT OF LIGHT WITHOUT HEAT.

when we attempt similar explanations for otlier facts. Thus, a thin plate of transparent
alum and a thick mass of smoky rock crystal, the former completely diaphanous, tlic lat-
ter so opaque that even when placed in the fullest light it was not possible to read large
printed characters, being compared together, the latter was found to be more transparent
to heat than the former in the proportion of 19 to 6; and, indeed, if these agents be iden-
tical, and the rays of light have a proper heat of their own, so that their amount may
be measured by a thermometer, what becomes of such experiments as the following,
brought forward, on the other side of the question, by M. Melloni, formerly, who pass-
ed a ray of light through a stratum of water, and then through a glass tinged green by
the oxide of copper? " The pu?-e light emerging from this system contains much yel-
low, and possesses, at the same time, a tinge of bluish green. li exhibits no calorific
action capable of being rendered perceptible by the most delicate thermoscopes, even when
it is so concentrated by lenses as to rival the direct rays of the sun in brilliancy." — ( Tay-
lor s Scientific Memoi?-s, vol. i., p. 392.

205. Until, therefore, an explanation can be given of this experiment, or its authenticity
disproved, the recognised rules of chemistry require that we should speak of light and
heat as distinct agents. Nor are these the only imponderable principles which are in-
volved ; there are others known to exist, the position of which is determined by these
discussions : the chemical ray.s, for example, which M. Becquerel regards as nothing
more than invisible light, adopting for them the same theory which M. Melloni has
adopted for the rays of heat. There are also rays which can excite the glow from phos-
phorescent bodies. From the time of Franklin and Canton it has been known, that
if calcined oyster shells were exposed to the rays of an electric spark, as, for example,
to the discharge of a Leyden vial, the shells would commence to shine ; but, as may
easily be proved, it has more recently been found, that if the rays thus exciting the
phosphorescent quality be transmitted through a piece of colourless flint glass, they
can no longer produce the result. It might be said that this arises from the fact that
colourless glass has an invisible coloration, and that it absorbs the rays which are far
beyond the violet, but direct experiment proves that flint glass possesses no such quality.

206. Inasmuch, therefore, as a piece of flint glass can cut ofi" those dark rays which
excite phosphorescence in the sulphuret of lime, and combinations such as that which
has been referred to (204) are known, which can separate hght from heat, we are jus-
tified in regarding these as distinct imponderable principles. They may, it is true, be
remotely identical, but they are not identical in the way here set forth. They may
all consist of similar movements or undulations of one primordial ether, but there are
points in which the mechanism of those undulations vary — circumstances which im-
press upon them physical differences. As, in the phenomena of sound, we may have
instruments which give rise to undulations of the same length and the same intensity
— instruments which are executing the same strain of music at the same time — yet we
know well enough that each one impresses its own proper modifications, which the ear
in an instant detects. At a distance, we recognise the flute, the violin, the piano, the
bugle, from one an ;t' er.

207. The imperfections of the prismatic spectrum, which have been just described

CHEMICAL EFFECTS DESCRIBED BY WAVE-LENGTHS AND TIMES OF VIBRATION. 59

as exciting so powerfiil an influence in the distribution of light and heat, are equally
perceptible in the case of chemical effects, a result which becomes apparent at once
when we operate with the interference spectrum. When, on any sensitive silver sur-
face, this spectrum is received, instead of a stain exceeding in length the coloured spa-
ces, the change is limited to a narrow region, occupied by the more refrangible rays.

208. lu^g. 133, the visible interference spectrum is given with its fixed lines, as it
appears on the ground glass of the camera. The figure in the frontispiece is drawn
from the measures of Frac.nhofer. If the two be compared together, it will be seen
that there are differences in the relative distances of the lines. These differences arise
from the mode of conducting the experiment in the two cases. Fraunhofer's spec-
trum was carefully determined, the angular deviations being measured on a graduated
arc. Fig. 133 is depicted from the appearance on the flat ground glass of the camera.

209. Before giving a description of the chemical effects of this spectrum, it is neces-
sary to explain the method of subdividing the spectrum which is here resorted to. In
the earlier discussions on the chemical effects of light, the different regions of the spec-
trum were marked out by the designations of the different coloured rays, and effects
were described as taking place in the red, or 3'ellow, or violet ra}. An improved plan
was proposed by Sir J. Herschei., and followed by him in his various writings : it
consists essentially in dividing the space which exists between the red and yellow ray,
as insulated by cobalt blue glass, into 13-30 parts, taking the centre of the yellow ray as
the zero point, and continuing the divisions equally into the more and less refrangible
regions.

210. Over these different methods the use of the fixed lines possesses very great ad-
vantages, inasmuch as we do not make reference to ideal, but to actually visible points
existing in the spectrum. Since the discovery of these lines, therefore, both M. Bec-
QUEREL and myself have used them to mark out spectrum regions. The only diflScul-
ty which is in the way is, that they do not give subdivisions minute enough for many
purposes. But this difficulty can be wholly removed, and other very great advantages
gained, b^- using them in the manner which I shall now proced to explain.

211. It has been stated that the deviations (189) of the different fixed lines, B, C, D,
in the interference spectrum, are proportional to the lengths of the undulations which
they respectively represent. By designating the different points of the spectmm by
their wave-lengths, the subdivision may be carried to any degree of minuteness ; the
measures of one author will compare with those of another, and the different phenom-
ena of chemical changes occurring through the agency of light become allied at once
with a multitude of other optical results ; as, for example, when we are told that the
decomposition of bromide of silver occurs at a maximum under the influence of a ray
which is 0-00001538 of a Paris inch in length, we recognise in an instant that this ray
falls between the fixed lines G and H, the length of G being 0-00001587, and of H
0-00001464; we see, moreover, that the point spoken of is nearer to G than to H, and, if
it were necessary, by a very simple arithmetical process, we could determine the number
of vibrations executed by that ray in thus bringing about the maximum decomposition in
billionths of a second, using the rate of the propagation of light at 192,000 miles.

^Q CHEMICAL EFFECTS OF THE INTERFERENCE SPECTRUM.

212. The fixed lines, used in this way, enable us at once to divide the interference
spectrum into any number of parts, and to indicate effects either in space or in time.
For chemical purposes, in which mathematical accuracy is scarcely attainable, all that
we have to do, in order to determine the lengths of waves producing given effects, or
the times of vibration, is to determine, upon the interference spectrum, the point at
which the change in question has taken place, and, using the numbers which Fraun-
HOFER measured for the different fixed lines, find what is its relation to them. Thus,
for example, suppose it has been found, by experiment, that a certain substance, expo-
sed to the interference spectrum, exhibited a maximum point of decomposition exactly
midway between the fixed lines F and G, which are both impressed on it, it is required
to know what is the length of the wave which brought about that decomposition in
parts of a Paris inch. The numbers given by Fraunhofer are.

For G 0-00001587,

« F 0.00001794;

and the point in question, being midway between the two, has for its wave-length
0-00001690.

213. In the frontispiece, I have annexed Fraunhofer's numbers to each ray, omit-
ting, for the sake of brevity, the ciphers.

214. In Jig. 134 is represented the effect of the interference spectrum upon a silver
plate, rendered sensitive by exposure to iodine vapour, and then to bromine. The time
of its exposure in the camera was half an hour. The point of maximum falls, as may
be determined upon the foregoing principles, nearly at the point 0-00001538. The
dotted lines, x and y, indicate the beginning and end of the stain. The maximum
point does not fall equally between the two, but is nearer to the more refrangible ex-
tremity. When this spectrum is compared with the corresponding prismatic one, in
Jig. 103, we see how great is the difference ; the effect, which is there carried far be-
yond the extra-violet regions, is here compressed down into a narrow space.

215. Fig. 135 represents a very beautiful result, obtained on a silver plate exposed
first to the vapour of iodine, and then for a short time to the vapour of chloride of
iodine. In this case the point of maximum falls nearer the Hue G. The time of ex-
posure was ten minutes. The fixed lines, which were discovered by M. Becquerel and
myself beyond the visible spectrum, are here crowded down into so small a space that
the individual groups are all found together, so that they would scarcely be recognised.

216. Fig. 136 gives a very perfect result which I obtained on a plate exposed first
to the vapour of iodine, then to bromine, and then to chloride of iodine ; the point of
maximum falls at 0-00001538, as in Jig. 134; the time of exposure was one hour.
The decomposition extended on one side beyond E, in the green space, to the point
0-00002007 ; and beyond the violet space to the point 0-00001257. As in Jig. 134,
we here again see the point of maximum is not in the middle of the image, but is to-
wards its more refrangible extremity.

217. As respects this spectrum (Jig. 136), although it extends to the yellow space, the
line E is not represented in it. I may remark of these spectra, as was formerly re-
marked (Ap., 746-747) in the case of the prismatic, that the lines D and E do not ap-

DECOMPOSITION OF CARBONIC ACID IN THE YELLOW REGION. gj

pear. M. Becquerel, as appears from the Scientific Memoirs, voL iii., pi. ix.,^^. 2,
has been more fortunate. Although, in the course of a great many experiments, I have
often obtained very beautiful results, in which the lines in the indigo and violet spaces
were given in great numbers, and many of them of that degree of minuteness as to re-
quire a lens to show them distinctly, it has never yet happened to me to see the fixed
lines D and E reproduced on a sensitive surface of any kind.

218. It may be remarked, in conclusion, that just as we see the colorific rays symmet-
rically arranged in these interference spectra, and the chemical results expressed by the
decomposition of chloride and bromide of silver crowded into a narrow space, compared
with what takes place in the prismatic spectrum, so must the same thing hold for the
rays of heat, the apparent distribution of which must be totally altered.

• CHAPTER VI.

EXPERIMENTS PROVING THAT IT IS IN THE YELLOW REGION OF THE SPECTRUM THAT THE
REDUCTION OF CARBONIC ACID BY THE LEAVES OF PLANTS TAKES PLACE.

Contents : Several Imponderable Principles in the Sunbeam. — Sennebiers Experi-
ments to determine to which of these the Effect is due. — Experiments of Morren and
Daubeny. — Defects of the Mode of operating tcilh Absorbent Media and Glasses.

Decomposition of Carbonic Acid in the Prismatic Spectrum. — Process of conducting

the Experiment. — It is in the Yellotc Region that the Decomposition takes place.— .

No Gas is evolved in the Violet. f

219. The elementary views of the constitution and nature of the spectrum which
we have given enable us now to return to the physiological problem under discussion.
From Chapter II. we see that the process of digestion of plants, so far as we have yet
examined it, maybe separated into three different chemical actions. 1st. The absorp-
tion of carbonic acid and water. 2d. The evolution of a mixture of oxygen and nitro-
gen. 3d. The retention by the plant of carbon, hydrogen, oxygen, and nitrogen.

220. There has, therefore, been a decomposition of carbonic acid, of water, and
probably of some nitrogenized compound.

221. But these extraordinary decompositions have been produced by the agency of

the sun. The most energetic reducing agents which we know are required in the .
hands of chemists to produce some of these effects. When made red hot, the vapour
of phosphorus and also potassium will accomplish the deoxydation of carbonic acid.
Plants can do the same at 50° Fah. very readily. /

222. If water be exposed to the light in glass vessels, common obser\ation assures
us that it never undergoes decomposition. In the same manner carbonic acid in a jar
remains without exhibiting any change. We shall soon discover W'hy. nnder these
circumstances, the powerful reducing agency of light is not called into action.

62 SEVERAL IMPONDERABLE PRINCIPLES IN THE SUNBEAM.

223. We have seen that the appearance of green matter in water, and the produc-
tion of chlorophjl in leaves, are the same phenomenon. In the largest trees all the
solid matter found in their branches, stems, bark, and various other parts, was originally
fabricated in the leaves, for it was in them that carbonic acid was decomposed and its
sohd material fixed. Once thus introduced into the interior of the vegetable system,
it passes through a multitude of changes; from the descending sap the different com-
pounds are removed, and lodged in their proper places. It is in this way ihat the
starch, sugar, gum, woody fibre, fibrine, albumen, caseiue, essential oils, resins, &c., are
all produced. First one and then another change is impressed on the descending juice,
and first one and then another special compound is removed from it ; but the point
from which all this cycle of changes begins may be traced back into the leaf, to the
decomposition of carbonic acid and production of chlorophyl, under the influence of
light.

224. A ray of light, as is well known (137), contains, under ordinary circumstances,
several distinct principles. 1st. A principle which impresses the organ of vision with
a specific sensation, and which is therefore spoken of explicitly as light ; of this there
are several modifications : one which produces in our eyes the sensation of a red col-
our; another, a yellow ; a third, a blue; and these, conjoined in proper proportions, give
rise to a white. 2d. A principle of radiant heat, the well-known characters of which
are the power of producing Expansion in bodies, of communicating a feeling of warmth;
in this the phenomena of coloration have been traced as in the former case. 3d. A
principle of chemical force, which seems to be intimately associated with light, but dif-
fers from Ji \t principle in wanting the power of affecting our organs of vision. From
this intimate association with light, I have suggested for this principle the name of Ti-
THONic RAYS, in allusion to the fable of Tithonus and Aurora. In this, as in the for-
mer, the quality of coloration has already been traced. 4th. A principle of phospho-
rescence, which has the distinctive character of causing certain substances, when sub-
mitted to its influence, to shine for a short time after with a transient light ; this prin-
ciple also is invisible to the eye, but differs from the tithonic rays in the fact that, un-
der certain circumstances, transparent glass is opaque to it.

225. Of these constituents, visible and invisible, in the solar beam, which is it that
has charge of that digestive function of plants which we are now considering t Is it
the light or heat, the tithonic or the phosphorescent ray ?

226. Several years ago, experiments were made by Sf.nnebier for the purpose of de-
termining this question ; his results seemed to show that the violet rays contained the
active force. More recently, in France, M. Morren commenced an inquiry of a sim-
ilar kind, and came to the conclusion that the luminous rays, and more especially the
yellow, were the cause of the phenomenon. In 1836, Dr. Daubeny published, in the
Transactions of the Royal Society, a very extensive series of experiments, the result
of which went to show that the leaves of plants decomposed carbonic acid, and turned
green most rapidly in the yellow ray, the other colours, orange, green, red, blue, indigo,
and violet, producing the same effect, more and more slowly in proportion as their illu-
minating power was less. The plan which was followed by these different chemists

EXPERIMENTS OF SENXEBIER, MORKEN, AND DAUBENY. 63

was to cause the plants to grow or to carry forward their decomposing action under
the influence of light which has passed through glass stained with the different colours
Thus, if young plants are made to grow beneath a shade of lemon-jellow glass, in a
few days it is seen that such light does not exert a destructive agency, but they grow
vigorously ; and if, simultaneously, comparative trials are made with other shades ot
different colours, such as red, blue, green, &c., an estimate may be obtained of the com-
parative effects of rays of these different colours.

227. But it is well known that lights thus produced are not monochromatic, but
contain a variety of different coloured rays ; for when the ray which passes through
them is examined by a prism, it is always dispersed into a variety of different colours.
Thus, the hght which passes through the ordinary variety of blue glass, analyzed in this
way, is found to contain red, yellow, and an abundance of indigo and violet, although it
looks of a pure blue tint. The blue Ught which passes it is therefore not a simple, but
a composite blue, made up of many other colours, the blue predominating. And as
this obser^■ation applies to almost all sorts of coloured media, their colours being com-
pound and not simple, it is obvious that when we make experiments with them we
shall be Uable to be led into error, unless we determine what rays they actually trans-
mit. Accordingly, Dr. Daube.\y determined this point in the case of each glass and
coloured medium that he used.

228. About the same time that these experiments were made in England, I com-
menced some of the same kind in the south of Virginia (Ap., 413, 497, 506, 515-517),
where, during the summer season, the light is extremely brilliant. These served to
show that under a yellow solution, such as the bichromate of potash affords when dis-
solved in water, the leaves of plants turned green, and the decomposition of carbonic
acid gas was effected.

229. Soon after this the British Association for the Advancement of Science, in
consequence of some results which had been obtained in England, which seemed to
countenance the opinion of Sennebier, that the violet rays direct the function of di-
gestion, appointed a committee to examine this matter at their expense. A number of
experiments were consequently made, very much in the same manner as those which
had been previously conducted by Dr. Daubeny ; these seemed, however, to be at va-
riance with his conclusions, and showed, that while the violet tithonic ray is the ac-
tive agent which controls the process, the yellow ray of light is exceedingly injurious.

230. But it is now known that these results, like those of Sennebier, are erroneous,
and that, as was firet discovered by Morren in France, and by Daubeny in England,
it is yellow light which directs the digestion of plants; that leaves can be greened,
and oxygen given off, and carbon fixed by light that has passed through a solution of
bichromate of potash, or through yellow glass (Ap., 784-792).

231. The proper mode of conducting these experiments is to employ the solar spec-
trum itself, a process which, it will be seen (Ap., Ch. XV.), was first resorted to in
New-York. By some appropriate optical mechanism, a ray of the sun is transmitted
into a dark room through a circular hole in one of the shutters, and kept motionless
for several hours, although the sun may have apparently moved a considerable distance

64 DECOMPOSITION 01" CARBONIC ACID IN THE PRISMATIC SPECTRUM.

over the sky. This ray {a b,Jig. 122) is to be intercepted by a glass prism, c, which
disperses it into its different coloured beams. And now, having provided a set of glass
tubes filled with spring water, or, rather, water holding carbonic acid gas in solution,
and in each placed the same number of leaves of grass or of some other plant, so that
each tube may be as nearly like all the others as may be, these tubes, inserted in a small
pneumatic trough, c d, are to be set in the spectrum of light, in its different coloured
spaces, one in the red, one in the orange, one in the yellow, &c. Care also should he
taken to exclude all extraneous light, so that that which causes any action among the
leaves may be derived from the ray which comes in through the shutter only. Very
soon, if the sky is clear and the sun brilliant, the phenomenon begins. In the tube
which is in the most luminous part of the yellow ray small bubbles are evolved, and
these rising to the top of that tube, there collect, so that after the lapse of a few hours
a sufficient quantity may be gathered for measurement and analysis. The tubes that
are in the orange and green lights simultaneously go into action, and when the sky
possesses an intense brilliancy, they will even approach in the rapidity of their action
to the maximum yellow. A few bubbles also make their appearance in the blue, but
after an exposure of many hours, if scrupulous care is taken to shut out all extraneous
light, no action whatever is perceptible in the extreme violet, where Sennebier supposed
the decomposing force to be situated. From these things we therefore gather, that it
is in the yellow light that the power controlling the function of digestion of plants is
to be found, the other coloured beams, orange, green, red, blue, &c., following in the
order of their illuminating power.

232. This prismatic experiment is one of the most beautiful objects which organic
chemistry can offer, carried on in a chamber which would be totally dark were it
not for the intensely coloured curves which are cast upon the walls by reflexion from
the tubes, curves which often are many yards in length, indicating by their gaudy tints
and brilliancy the intensity of the sun's light. The tubes and the vegetable leaves glow
with the colours in which they are immersed. Meantime, the most interesting phe-
nomenon which,.<:an be witnessed is silently going forward ; dead and inanimate matter
is, under the influence of the plastic beam, putting on the form of organization and
life. Oxygen and nitrogen gases are exhaling, chlorophyl, and gum, and sugar, fib-
rine, and albumen are coming into existence. These are compounds which, under
ordinary circumstances, are destined to be used as the food, and form part of the bodies
of animals. For it is from atmospheric air, as organic chemistry shows, that plants
spring, condensed out of it, as it were, by the agency of the solar beam; to the same
source also it is that gradually during life, and totally after death, the parts of animals
hasten to return.

233. A little reflection shows the great advantages which this mode of experiment-
ing possesses. In the white light of the solar beam there is a fixed proportion of each
of the component colours, and when such a beam is dispersed by prismatic action, and
is simultaneously received upon vegetable leaves, we, in effect, measure out to them
similar quantities of the different coloured rays, and observe the resulting action. When
pieces of glass are used, as in the former experiment (226), a great deal depends on their

OBJECTIONS TO THE USE OF COLOURED GLASSES. qq

thickness. It is easy to conceive, that although in the solar spectrom the yellow ray
is vastly more luminous than the blue, if glasses or coloured media were used in experi-
ments of any kind, results of precisely an opposite nature might be obtained. We can
imagine a piece of yellow glass so thick as actually to transmit less light than a thinner
piece of the blue. With glasses and absorbent media, therefore, not only must the na-
ture of transmitted light be discovered, but thickness must also be taken into account.
234. Suppose, as an illustration, plants were made to grow, or to decompose car-
bonic acid, under a thin piece of blue cobalt glass, such as that of which finger-glasses are
made, and the result compared with what was occurring with another set of plants in
action under a thick or deep yellow glass. It might turn out that the former would
vegetate more vigorously, and fix more carbon, and produce more chlorophyl than the
latter, because more hght actually fell upon them, though the medium through which it
came was blue. We must not forget that the mode of action in producing chemical
decomposition, and the mode of action in producing vision through such an optical
contrivance as an eye, proceed upon different principles. In the action of the eye
time does not enter as an element (Ap., 536). In the decompositions produced by ra-
diant matter, or by Ught, it does. A faintly luminous object does not become brighter
and brighter as we continue to look steadfastly at it ; it has assumed its maximum of
brilliancy at the first glance. But a faintly luminous beam, falling upon leaves of
plants, or upon any changeable compound, continues to produce an increasing effect
as time passes on. In our experiment, more and more carbonic acid is decomposed,
and more and more oxygen set free as the time is prolonged. And so when absorbent
media, as stained glass, are used, the final effect is dependant on the total amount of
Ught that has been furnished ; and hence the turbidity, or thickness, or partial opacity
of those media must be taken into account, as much as their colour-giving relations.
In the prismatic experiment this source of disturbance does not occur.

CHAPTER VII. ^

ON THE VARIOUS IMPONDERABLE AGENTS EXISTING IN THE DIFFERENT REGIONS OF

THE SPECTRUM.

Contents : Different Agents existing in the Spectrum. — Description of the Tithonic
Rays. — Their Name. — Physical Independence of Heat. — Of the Chemical Rays. —
Their Constant Association with Light. — Detithonizing Action of Yellow Solutions.
— Argument for their Independence. — Other Invisible Principles in the Sunbeam,
such as the Phosphoric Rays. — Examination of the Theory of M. Becquerel.

235. From the preceding chapter, we have arrived at the conclusion that the impon-
derable principle which directs the digestion of plants is found at a maximum in the
yellow space of the spectrum, or accompanies yellow light

236. But it has been stated (22-i) that there are no less than three other principles

I

k

66 DESCRIPTION OF THE TITHONIC RAYS.

coexisting in solar light, tithonic, calorific, and prosphorescent rays ; for the two for-
mer the phenomenon of coloration has been distinctly traced, as will appear in a sub-
sequent chapter ; for the latter, analogy would lead us to suppose that die same thing
holds.

237. In yellow light, such as can effect the decomposition of carbonic acid, a vari-
ety of other principles exist — yellow tithonic rays, yellow calorific rays, and perhaps
yellow phosphorescent rays. Prismatic experiments (Ap., 790) can only indicate the
refrangibility of the ray which produces a given effect. Experiments by absorbent me-
dia are finally required to point out its exact nature.

238. In order that the reader may possess clear views of the evidence which is to
be brought forward, showing that it is yellow light, and not tithonic, calorific, or phos-
phorescent yellow rays which superintend the formation of organic molecules out of
inorganic matter, it is necessary to set forth in a more prominent way the distinctive
characteristics which appertain to each of these principles.

239. Of the calorific rays, or rays of heat, nothing, however, need here be said. Their
physical independence of light, and separate existence, were completely established by
Melloni (170), who also discovered in them modifications analogous to coloration.

240. The existence of the tithonic rays was first ascertained during the last century.
They passed in the books under the name of chemical rays — a name still continued by
many chemists. As a multitude of phenomena with which they are connected became
known, it has been found absolutely essential to give to them a specific name, such as
can be moulded conveniently for the purposes of science, and combine readily to form
those different words which are necessary to give names to instruments in which they
are involved, or to phenomena with which they are connected — a name which, how-
ever, involves no hypothetical idea of their nature or action.

241. The most striking fact in connexion with these rays is their constant associa-
tion with light. Though the two principles are separable from each other by artificial
processes, yet, under natural circumstances, they always occur together. In sunlight,
in gas-flames, from candles, and even in the moonbeams, in which no heat is found, the
chemical and luminous rays exist together. They undergo reflexion, refraction, polar-
ization, and interference, apparently under the very same laws. But while light can
affect the eye, and bring us into relation with all the phenomena of the material world,
these rays fail to affect our organs of vision — they are invisible.

242. In view of this constant association of light and the chemical rays, and to ex-
press the idea of their near alliance to each other, and as the wants of science imper-
atively called for a specific designation, the name of tithonic rays has been suggested for
them. It is drawn from the fable of Aurora and Tithonus. This name forms compound
words with facility. It does not involve us in any speculative considerations, but merely
points out the fact that the principle to which it is given is almost always associated with
light. As has been just stated, all the mechanical laws which regulate the reflexion,
transmission, polarization, and interference of light, obtain also for this.

243. The mathematical theory of light is based upon the postulate of undulations
taking place in an ethereal medium. This theory, like the theory of universal gravi-

THEIR PHYSICAL INDEPENDENCE. gy

tation, possesses an abundant internal evidence of truth. In our times extensive and
important applications have been made of it, so that it now includes an explanation of
all the phenomena of reflexion, refraction, polarization, double refi"aciion, interference.
As yet, it has furnished no cL-ar account of the phenomena of absorption, the very phe-
nomena which are at the basis of all physiological and chemical facts in their relations
to luminous agency. As we shall presently prove, the decomposition of carbonic acid
and the fiinction of digestion in plants depend on the absorption of light Nor is
there yet included in it any representation of the various phenomena of heat In the
coarse of years, these things will probably be added, and one great generalization em-
brace all the phenomena of the imponderable agents. But the purposes of science re-
quire, until that event takes place, that we should continue to speak of the various
imponderable principles as though they were different agents, and treat them as though
they were separate existences.

244. The first decisive evidence brought forward to establish the physical independ-
ence of the heat and light of the sunbeam, as has been stated (165), was derived from
the experiments of Sir VV. Herschel, the illustrious astronomer. He foun i that, when
a beam of light is dispersed by a prism, and the resulting spectrum examined, by placing
thermometers in its different coloured spaces, the most luminous rays are not the hot-
test, the maximum temperature occurring, not in the yellow, but in the red ray ; and even
out of the red ray, and where the eye could detect no light whatever, heat was present,
for the thermometer there rose rapidly. Starting from these experiments, Mellom added
farther proof by showing that transparency for light is not necessarily transparency for
heat ; that there are certain media more or less opaque to one of these imponderables,
and more or less transparent to the other, and that, by appropriate combinations, media
can be obtained which will allow light to pass them with very little diminution of its
intensity, but which stop the heat almost entirely.

245. In the dark rays which come from a vessel of hot water, we have radiant heat
without light ; in the moonbeams we have, on the contrary, light without heat.

246. By a series of experiments of a similar kind, the physical independence of the
tithonic rays has also been established. During the last century, it was observed by
SciiEtLE, that these rays occur abundantly beyond the violet extremity of the spectrum,
where the eye can discern no trace of light, an observation essentially of the same kind
as that made by Sir W. Herschel for radiant heat In consequence of this discovery,
the occurrence of invisible rays was at once assumed, and, without any inquiry as to
their nature, their existence became an admitted fact in science.

247. It does not appear, however, that any clear views were entertained as to the
precise character of these dark rays. Writers on optics spoke of them indifferently
under the name of violet rays, chemical rays, deoxydizing rays, and invisible TB.ys. Of
all the benefits which can be conferred on an infant science, those arising from estab-
lishing clear, bold, prominent, decisive views of its fundamental agencies and their ac-
tions are by far the most valuable, for they fasten the attention forcibly. In all pro-
gressive sciences, each epoch of evolution, for sciences advance forward by starts, is
traceable to the announcement of some clear and vivid idea.

//

es

DETITHONIZING ACTION OF YELLOW SOLUTIONS.

248. As we have said, the existence of these dark rays beyond the violet end of the
spectrum was established during the last century. For, when a solar spectrum is made
to fall on a piece of paper covered over with white chloride of silver, that compound
turns black, the colour changing where blue, indigo, and violet rays fall ; the change
also extending over those spaces which are outside of the violet ray, and where there
is no light. In 1836, by using bromide of silver instead of chloride, I found that these

'L deoxydizing rays extended out of the blue light down towards the yellow (Ap., 445) ;
these experiments were published in 1837.

249. From a variety of evidence, obtained about the same time, it appeared that
when absorptive media were used, the rays of light could be deprived of much of their
chemical power. Thus, on passing a ray through a solution of bichromate of potash
(Ap., 410), it became almost inactive, refusing to produce any change on sensitive paper;
a similar result following on passing it through Dalton's solution of the quadrosnlphu-
ret of lime, and a variety of other media (Ap^, 410-509). At that early period in pho-
tographical investigations, when as yet no other chemist was engaged in these pursuits,
two important facts were published : 1st. The physical independence over a great part
of the spectrum of light and the tithonic rays (Ap., 386). 2d. That the tithonic rays
exhibit undoubted tokens of modifications answering to colours in light (Ap., 384, 433,
506). This is the foundation of the doctrine now more completely unfolded in this
work, under the designation of " The Theory of Ideal Coloration of the Tithonic Rays."

250. From their constant association with light, it is difficult to give that clear evi-
dence of the physical independence of the tithonic rays which may be given in the
case of heat. Much weight may, nevertheless, be laid upon the circumstance that, by
prismatic action, these rays can be proved to exist beyond the extreme violet region, and
even beyond that ray which Sir J. Herschel designates lavender. Evidence of the
same kind is derived from the partial action of absorbent solutions and media, which
act differently on each of these classes of rays. From observations of this kind tables
have been formed, with a view of proving this point (Ap., 673). In the Transactions
of the Royal Society, Sir John Herschel has given some of the same sort {Phil.
Trans., 1840). My results were published in 1842.

251. At one time much stress was laid on the power which certain media, such as
bichromate of potash and quadrosulphuret of lime, possess in depriving a ray of its
chemical force. This argument is still resorted to by inaccurate writers, as affording
a very popular and palpable proof that hght and the tithonic rays are different ex-
istences. " If," it is observed, " a ray of hght is passed through a solution of quadro-
sulphuret of lime, and is then received on paper covered with chloride of silver, it is
found that the light alone has gone through, and the chemical rays have been absorbed.
The one, therefore, exists independent of the other." When I first observed the power
of these yellow solutions, this was the conclusion I came to (Ap., 410, 511). But the
theory of ideal coloration, presently to be explained, deprives this argument of much of
its force ; for the rays that are transmitted by such a solution are yellow rays of light,

i;i and yellow tithonic rays ; in these the chloride of silver does not change, its decompo-
A sition being brought about by the blue tithonic rays which have been absorbed along

OTHER INVISIBLE PRINCIPLES IN THE SUNBEAM. 69

vvitli the blue li"ht. Tithonic rays are present in a beam which has passed through
quadrosulphuret of lime, but chloride of silver cannot detect them.

252. An accurate examination of the quantity of hght and the quantity of tithonic
rays passing through given solutions has, however, restored this argument to its pristine
force. Thus, it is proved, that of different media which have been tried, some trans-
mit more of the luminous and some more of the tithonic rays (Ap., Ch. XVIII.) ; that
the rate of transparency for one is often totally different from the rate of transparency

for the other ; and although we have not yet been so fortunate as to discover any given /?
medium which is opaque to one of these principles and transparent to the other, as has
been done in the case of light, their physical independence is just as certain as though
such a medium was known.

253. After commenting in the preceding paragraph on the weak point in the
argument drawn from absorbent media, it ought not to be left without showing how
experiments of that class may be rigorously used as proofs of the correctness of the
views given in 1837. It only requires that the sensitive paper or surface used should
be of such a character as to be affected by all the tithonic rays in the spectrum, irre-
spective of their order of refrangibility or ideal coloration. Such a substance is the
bromide of silver. Sir J. Herschel has used it with a similar object in view (Phil.
Trans., 1840, p. 38). Suppose, therefore, we allow a solar spectrum to fall upon such
a changeable surface, after having passed through a yellow absorbent medium, as the
bichromate of potassa. The eye at once informs us that very little of the yellow and
orange light is lost, but we must keep the surface for a long time exposed before the
yellow and orange tithonic rays will have produced such a change as they would have
produced in a few moments if the bichromate had not intervened. In this case the
experiment is a fair one, and the deduction it gives holds good, because bromide of
silver is easily decomposed by the tithonic yellow ray. The bichromate of potash,
therefore, transmits yellow and orange rays of light copiously, but it transmits the
corresponding yellow and orange tithonic ray to a far less extent. The two princi-
ples are therefore distinct.

254. That there is nothing unphilosophical in supposing that an invisible principle
such as that of which we are speaking should exist in solar light, is shown by the anal-
ogy of radiant heat, a principle equally invisible to our eyes, but of which the exist-
ence is palpable enough to our other organs of sense. In a dark room we are utterly
unable to see a vessel of hot water, but its calorific emanations are plain to the hand, ,
even at a considerable distance. In like manner, this analogy is supported by the re- //
cent discovery of Becquerel. For a long time it has been known that there are cer-
tain bodies, such as calcined oyster shells, which shine in darkness after a brief expo-
sure to the Hght. A hundred years ago it was discovered that the transient light of an
electric spark is suflScient to awaken the dormant glow of these bodies. Now Bec-
querel has shown, that to the rays which thus issue from an electric spark, and cause
this wonderful phenomenon, glass is opaque, that light can pass through glass, but the
phosphorescent rays cannot. They also are invisible to the eye.

255. It will be seen, by referring to Ch. XII. of the Ap., that there are certain phe-

/

70 EXAMINATION OF THE THEORY OF M. BEOQUEREL.

nomena which may be explained on the supposition that the invisible tithonic rays es
cape by radiation from bodies which have been impressed by them, tliose bodies simul-
taneously reverting to their original condition. These results, and similar ones, have
of late years attracted much of the attention of experimental philosophers, but the in-
quiries involved are beset by numerous difficulties (Ap., 708, &c.). There is not, how-
ever, anything impossible, or even unlikely, in this secondary radiation. A phenome-
non of exactly the same kind is visible to the eye in the case of tbe phosphorescent rays,
when the glow of light by radiation escapes away from calcined oyster shells after
they have been illuminated by an electric spark.

256. Dark, invisible rays thus exist in the sunlight, and carry on a variety of func-
tions, and control a variety of phenomena. Of solar principles, four different kinds
have been traced : rays of light, of heat, tithonic, and phosphorescent rays. The two
former are admitted to constitute recognised imponderable principles. What are the
latter two 1

2bl. In the Philosophical Magazine (see Ap., Ch. XIII.) I have some years ago
brought forward the doctrine, that we are compelled to enlarge our catalogue of im-
ponderable principles, and include these tithonic rays in it. More recently I have of-
fered similar arguments in favour of the phosphorescent rays (Ap., Ch. XVIIL).

258. This brings me to offer some remarks on the opinion expressed by M. Bec-
QUEREL, that the phenomena now under disc;jssion are due to the qualities of the re-
ceiving surfaces, and no.t to agents intrinsically different, coexisting in th^-^lar beam.
That the same beam of light, falling on snlphuret of lime, causes it \j5 phosphoresce ;
on chloride of silver, blackens it ; on the retina, gives rise to the phenomena of vision
and colour ; on a piece of black cloth, causes it to become warm. This opinion seems
to be surrounded with insurmountable difficulties, and, if admitted, would disturb some
of the best-established triiths of science.

259. No one can feel more strongly the absurdity of supposing that Nature has cre-
ated between forty and fifty elementary ponderable substances, all possessed of metallic
characters, and all so nearly alike that even a chemist is often puzzled to distinguish
them from one another. No one, upon satisfactory proof, would more willingly go
back to the alchemical doctrine in relation to these matters ; but so long as the evi-
dence on the constitution of these bodies rests where it does, the laws of chemistry
compel us to admit them to be simple and undecompounded. And, just in the same way
that I am willing to admit the existence of forty different simple metals, so, upon sim-
ilar evidence, I am free to admit the existence of fifty different imponderable agents, if
need be. Is there anything which should lead us to suppose that the imponderables
are constituted by Nature on a plan that is elaborately simple, and the ponderables on
one that is elaborately complex ? That the former are all modifications of one primor-
dial ether, and the latter intrinsically different bodies, more than a quarter of a hun-
dred of which have been discovered during the present century I

260. Before admitting the correctness of the hypothesis of M. Becquerel, that the
agent under consideration is one and indivisible, and that all the phenomena we dis-
cover are due to the receiving surfaces, and that there are as many spectra as there are

EXAMINATION OF THE THEORY OF M. BECQUEREL. 71

substances in nature, each eiving its own manifestations when exposed to the sun's ray,
we should make inquiries hke the following : How is it that a piece of black cloth ex-
posed to the moonbeams does not become warm ! How is it that a cannister of hot
water is not luminous to the eye ? In the rays that come from the moon, and those
that are emitted by warm water, is there no intrinsic difference, or does the phenom-
enon depend on the receiving surface alone ! What becomes of the beautiful exper-
iments of Mellom, on the physical independence of light and heat, since these are
mainly founded on the fact, that by the use of absorbent media we can separate one
fi-om the other ? How is it that the rays of an electric spark, passing through quartz,
can make the Bolognian stone phosphoresce, but passing through glass, equally trans-
parent and equally colourless, can do no such thing I The receiving surface is the ,
same in both cases, and, as far as human eyesight can discover, the light that comes
through the glass is as pure and unaltered as the hght that came through the quartz,
but the results are diametrically opposed. And is it not more consonant to reason to
suppose that the glass was opaque, or impervious to some agent existing in that beam,
which freely passed the quartz — opaque to it, but transparent both to light and the
dthonic rays ?

261. We might multiply cases Uke these, and give similar arguments from chemical
changes on sensitive surfaces; but the instances aheady cited seem abundantly suffi-
cient to overturn the hypothesis in question. Before it can be admitted, it must give
a reason why the retina is not affected with the sensation of vision when rays from hot
water fall on the eye, why a thermometer will not rise when placed in the moonshine,
why sulphuret of lime or barytes will not phosphoresce when covered with a piece
of glass.

262. We are thus forced to admit that rays of light, rays of heat, tithonic rays,
phosphoric rays, and probably many other radiant forms, have an independent exist-
ence, and that they can be separated, by proper processes, from each other.

263. It must, however, be understood, that the conclusion here arrived at essentially
depends on the following facts : IsL The constant visibility of light 2d. The uniform-
ity of the action which heat exhibits in expanding bodies. If the progress of science
should require us to admit that there can exist light which impresses our eyes with a
sensation of darkness, or heat which can neither raise a thermometer nor produce the
sensation of warmth, then the force of the foregoing arguments will be essentially af-
fected. Such extensive changes in the imiversal acceptation of words will, unques-
tionably, be very slowly received-

72 YELLOW LIGHT CONTROLS THE DIGESTION OF PLANTS.

CHAPTER VIII.

IT 18 YELLOW LIGHT WHICH CONTROLS THE PROCESS OF DIGESTION IN PLANTS.

Contents : Examination as to which of the Principles mentioned in the preceding
Chapter is engaged in the Decomposition of Carbonic Acid. — It is not Radiant
Heat. — }felloni on the Ideal Coloration of Heat. — Analogies in the Case of Light.
— HerscheVs Results.

It is not the Tithonic Ray. — Maximum of Decomposing Action for Carbonic Acid and
Carbonaceous Compounds, like the Retina, is in the Yellow Ray. — Hence the Maxi-
mum of Visible Illumination coincides therewith.

264. In the last chapter, and in the Appendix, Chaps. XIIL, XV., and XVIII., we
have given proofs of the separate existence of a number of independent imponder-
able principles in the solar beams, of which only one produces a specific effect upon
the eye, the others being wholly invisible, and known to us by the chemical or mechan-
ical effects they produce.

265. When, therefore, a beam of light falls upon a prism, and is decomposed by it,
and the resulting colours are received upon a screen so as to give rise to a spectrum,
such as that represented in the frontispiece, in each portion of that spectrum these dif-
ferent imponderable principles are present. For example, in the region between the
lines A and C there are red rays of light, red rays of heat, and red tithonic rays. They
are mingled together there, fortuitously, through the optical action of the prism. Their
existence is perfectly separate and independent, and any one of them may be removed
by proper processes, and the others left.

266. Confining our attention now to the yellow portion of the spectrum, in which
region the decomposition of carbonic acid takes place, it is obvious, upon these princi-
ples, that there are coexisting there yellow light, yellow heat, and yellow tithonic rays.
It remains for us to inquire to which of these three principles the decomposition of
carbonic acid and the production of green matter is due. The phosphorescent rays
may be left out of the discussion, though these, with the other three classes, are spread
all over the spectrum.

267. First let us ascertain whether radiant heat, generally, has the quality of pro-
ducing decomposition. To rays coming from a brightly-burning fire, I exposed some
vegetable leaves in water holding carbonic acid gas in solution, and, to increase the
effect, converged the calorific rays by a large metalUc concave mirror. That no doubt
might remain of the incapacity of heat to produce the phenomenon, the temperature
of the w^ater, under the influence of the radiant heat, was allowed to run up to 140°
Fah., a much higher point than is ever attained under natural circumstances. But
neither at low temperatures, nor at these elevated ones, did any visible decomposition

TOEAL COLORATION OF HEAT. 73

take place ; sho\^ing, thus, that heat alone cannot cause the digestion of plants. More-
over, as is well known to chemists, carbonic acid gas may be passed through a tube
that is white hot without giving the most remote appearances of decomposition.

268. The beautiful experiments of Mellom have proved, however, that rays of heat
emitted by bodies at different temperatures vary in their constitution. At a low tem-
perature, such as that of the human hand, the caloric emitted is of a high refrangibility,
aud possesses invisible violet coloration. As the heat rises, rays of a lower refrangi-
bilitv are sent forth, so that if we examine the character of the rays coming fi-om a se-
ries of bodies, the temperatures of which are successively higher and higher, as the
hand, a vessel of boiling water, a red-hot iron, a gas flame, the refrangibihties become
lower and lower ; the radiant heat possessing a calorific tint, which successively de-
scends through the colours of the spectrum, the violet, indigo, blue, green, yellow, &c.
From the sun, the temperature of which, therefore, must be excessively high, radiant
heat is emitted which occupies a region in the spectrum corresponding to the red rays,
and even below that is found beyond the region where red light has ceased to be visi-
ble. In the sunbeam, therefore, rays of heat of every refrangibility and every colour
are found; they occupy a space commencing with a region beyond the extreme violet,
and, descending through the whole length of the spectrum, are found beneath its lowest
extremity.

269. This is a phenomenon analogous to what we witness under similar circum-
stances in the case of light. When a lamp, the wick of which is placed very low, is
first lighted, it burns wlih a violet-coloured flame, giving forth little heat, and possess-
ing small illuminating power. By-and-by, as the combustion goes on, the colour passes
through various shades of indigo, and presently becomes of a purer blue. If the wick
is now elevated, and air more abundantly suppUed, the light increases in brilliancy ;
and, if'seen through a prism, all the colours begin to be perceptible from the violet to
the yellow and orange. Lastly, if fed with oxygen gas, or consumed in one of the im-
proved burners, the light assumes a beautiful whiteness, and, if dispersed by a prism,
exhibits all the colours of the spectrum. It is to the presence of these that its white-
ness is due, for white light contains all the coloured rays.

270. In these beautiful and perfect analogies, which may thus be traced between the
phenomena of light and heat, there are some points which require to be considered in
the case we have before us. As common observation assures us, rays of light of dif-
ferent refrangibihties excite in our eyes specific sensations ; the most refrangible ray
affects us with that sensation which produces in the mind the idea of a violet colour ;
the middle refrangible ray, a yellow ; the lesser refirangible ray, a red. And now these
impressions, thus passing along the optic nerve to the brain, originate in specific changes
which are happening to the constitution of the retina, for this dehcate expansion must,
in the nature of things, be acted upon under the influence of the light, in order to give
rise to a mental sensation. The different rays of light, each one for itself, operates in
its own way and produces its proper result.

271. Considerations Uke these would, therefore, lead us to suppose that rays of heat
of different invisible colours ought to have the property of producing specific changes.

K

74 IT IS NOT RADIANT HEAT NOR THE TITIIOMO RAY.

To them all is apparently given a power of producing expansion in bodies, and to each
one, probably, its own specific chemical powers. The experiments of Sir J. Hers-
CHEL seem already to give proof of this fact.

That the decomposition of carbonic acid by leaves is not due to yellow heat, may
be proved by causing the active light to pass through a solution of bichromate of pot-
ash, which is of an orange-yellow colour. This ray, thus treated, appears to carry on
the decomposition with nearly the same activity as the direct solar beam (Ap., 788).
In an experiment which I made, using it in a stratum of certain thickness, it seemed to
transmit the yellow and orange light with very little loss ; but acting more energetically
on the calorific ray, it transmitted of it only 26. Had this heat been the cause of the
decomposition, the rapidity with which the action took place should have been pro-
portionally reduced.

272. From such results, it is to be inferred that radiant heat generally, and the yel-
low rays of heat especially, do not produce the decomposition of carbonic acid gas in
the structure of vegetable leaves.

273. This narrows the question down to the inquiry, whether it be the yellow ray
of light or the yellow tithonic ray; for, as has been observed, the phosphorescent rays
may be left out of the discussion.

274. Experiments conducted on the same principle, and nearly in the same way,
with that already cited, serve to determine this point. If a beam which has passed
through a solution of bichromate of potash retains its power, as we know by experi-
ment, it remains for us to inquire whether that solution acts as feebly on the yellow
tithonic ray as it does on the yellow ray of light. We have already shown (251)
that this is not the case, for the tithonic ray undergoes an abundant absorption, its
force being greatly diminished, so that bromide of silver, which is easily changed by
the yellow tithonic ray, undergoes, in this disturbed and absorbed beam, a slow decom-
position. In the same way, therefore, that we determine that it could not be radiant
heat, we also determine against the tithonic rays. The decomposition of carbonic
acid, the production of chlorophyl, and the greening of plants go on with great rapid-
ity under that yellow solution, because, although it has absorbed, and therefore removed
these imponderable agents, it allows the active light to pass with little or no diminution.

275. The observation made in 237 is now understood. Analysis by the prism
serves only to point out in what particular region of the spectrum given phenomena
are produced ; it therefore narrows our discussions down within certain limits. By
introducing, in addition, the action of absorbent media, we are enabled to point out,
with a certain amount of precision, the exact agent which is involved. This use of
absorbent media conjointly with prismatic analysis, which was introduced into these
inquiries in 1837 (Ap., Ch. X.), may be expected continually to yield interesting results.

276. To the light, and more especially to the yellow light of the sun, we are to
impute the production of this, the most interesting phenomenon of organic chemistry.
Rays which come from artificial sources, such as lamps and gas flames, can also bring
it about to a degree corresponding with their intensity.

277. Whether that peculiarity of light by which it gives to us the sensation of spe-

DECOMPOSITION OF THE RETINA AND OTHER CARBON COMPOUNDS. 75

cific colours is involved, remains as yet undetermined ; we cannot say whether the
quality by which we are led to impute to a given beam a yellow colour is the same
quality which is involved in this decomposition. Whether, in short, yellow light, be-
cause it is yellow light, produces this change. Would any other coloured ray, such as
a blue, if its intensity were sufficiently elevated, produce the same result ! For we can
imagine a blue light so to be re-enforced as to possess the same intrinsic brilliancy or
illuminating power as a yellow. Under such a change, would its decomposing action
also be exalted 1

278. Prismatic experiments serve to show (Ap., 782) that the rapidity of decompo-
sition follows very closely the order of illuminating power. And this result affords an
argument, imperfect and feeble it is true, that an affirmative answer will be hereafter
given to that question.

279. But there are other reflections which naturally arise, and tend to an opposite
result. There seems to be a general relation, though the details of it have not yet been
traced, between rays of a particular refrangibility and ponderable substances of a par-
ticular kind. Thus, in the case of most of the salts of silver, the point of maximum
action falls in the violet ray. In the same way the question naturally arises. Does the
point for the maximum action on carbon compounds fall in the yellow space, and the
yellow, for that reason, become the active ray in decomposing carbonic acid, and giv-
ing a green colour to leaves ? Is it for this cause, also, that, received into the eye, the
yellow ray impresses us with the greatest illuminating power t It would be a beauti-
ful result of these researches to co-ordinate phenomena apparently so widely apart as
the formation of chlorophyl in a leaf and the regulated destruction of the retina in the
chamber of the human eye in producing the phenomena of vision. In nature there
are many results which are apparently equally distinct, and which the progress of
knowledge has shown are intimately allied. That to our organs of vision yellow light
is the most brilliant, arises from the incidental circumstance that it is a carbonaceous
compound of which the changing nervous expansion is constructed. Had it been pos-
sible for Nature to have formed a retina in which a salt of silver formed the basis, the
maximum of brilliancy of light would have shifted, and the blues would have been
among the brightest rays. Is it in the optical peculiarities of the carbon atom that all
our ideas of harmony among colours and beauty of external objects have arisen 1

280. Experimental science will probably before long trace a close connexion between
the physical properties of atoms and the physical properties of Ught It will show that
molecules of a given weight can be moved most easily by ethereal waves of a given
length, as a siretched string is thrown into vibration by atmospheric undulations of
proper dimensions; that the transverse vibrations of the ethereal particles can agitate
in a corresponding way ponderable atoms of a proper magnitude and constitution. We
shall then have no difficulty in understanding how it was that among metallic sub-
stances, those first detected to be changed by hght, such as silver, gold, mercury, lead,
have all high atomic weights ; and such as sodium and potassium, the atomic weights
of which are low, appeared to be less changeable.

76 THEORY OF ABSORPTION.

CHAPTER IX.

THEORY OF THE ABSORPTION OF THE TITHONIC RAYS AND LIGHT.

Contents : Estimate of the Extent andPoicer of the Solar Radiations. — Influence still
exists in the Moonbeams. — Absorptive Action of Chlorine and Hydrogen. — Detitho-
nization of the Ray and Tithonization of the Gaseous Mixtu?-e. — Curve and Law. —
Deductions as to Latent Light and Definite Action. — Functions discharged by the
Chlorine and Hydrogen respectively.

281. In pursuing our discussion of the phenomenon which we have under consider-
ation— the digestion of plants — we have successively traced the source of action to the
yellow region of the spectrum, and to the ray of light.

282. In what manner, then, does this light act ? How does it come to pass that it
can exert so great a force as to effect the reduction of carbonic acid in the cold ? We
have briefly seen what are the results it impresses on the forming vegetation, that the
leaf turns green and oxygen is given off". What are the corresponding and contem-
poraneous changes which happen to the light \ Action and reaction are always equal,
and if a given beam can produce a result which demands the most energetic chemical
force, it is reasonable to suppose that in doing so it undergoes itself a change.

283. These considerations show us that the question in what manner yellow light
acts in controlling the function of digestion in plants, is not only exceedingly interest-
ing in a physiological point of view, but also that it involves the whole theory of the
action of radiant matter, whether it be of light, heat, or tithonicity, in producing chemi-
cal change.

284. There are few authors who have written on the action of light or the tithonic
rays in producing chemical changes, who have not directly ascribed all those changes
to absorption of the imponderable principle. The connexion between absorption and
the production of these phenomena is clearly apparent. Still, however, in looking over
what has been written, we find little precision in those views ; instead of a distinct con-
ception of a plain fact, we find only loose and imperfect ideas.

285. In animals, voluntary and involuntary motions are under the government of the
nervous system. Each movement which is executed is attended with a corresponding
consumption of organized matter, either in the muscular or nervous tissues, or both.
The motions which my fingers are executing in writing these lines do not spring forth
from nothing, but are the offspring of the destruction, in a regulated manner, of organ-
ized matter originally derived from food. How perfect, then, is the animal machine,
which, fed from day to day by a small portion of carbonaceous matter, executes motions
with an inconceivably small expenditure of material ! How great, also, are the results
which may arise from the return of those organized atoms to their pristine inorganic

AMOUNT OF FORCE IN THE SOLAR RADIATIONS. 77

State. Thrown out from the mechanism, after their oflSce is over, they leave behind
them marks of the changes through which they have passed, and of the facts to which
they have given birth, and thus stand at last in connexion with events to which at first
they were not apparently aUied.

286. From the combustion of small quantities of carbon, we see, in improved steam-
engines, how great an amount of force can be originated, and by the oxydation of a few
grains of zinc in voltaic batteries, what surprising chemical results arise. From those
more ordinary cases of changes accomplished by the action of light, which appear to
be feeble and slowly produced, we should form the most erroneous opinions of the force
of the sun rays. General considerations might lead us to know that the principle
which has in charge the keeping up of the constitution of the atmosphere, and regula-
ting the vital functions of plants, is of great intensity. Thus, I have foimd that the
rays which are emitted from a common wax candle are superior in chemical force to
the current which is evolved by a cell of Grove's battery, the most powerftd of voltaic
combinations known, for they could effect the recomposition of muriatic acid much
faster than the battery could decompose it, and yet that battery was found competent
to maintain a platina wire white hot, and, if the views of Dr. Faraday are correct, was
evolving more electricity than is developed by any thunder storm. K this is the case
with a candle, what, then, shall we say of brilliant rays of the sun, which impinge on the
earth on all sides !

287. That force, therefore, the mode of action of which we are now to discuss, is
far from an insignificant power in Nature. In generality and intensity it rivals any that
is known ; in interest it is superior to them all, for it stands in connexion with organiza-
tion and living things.

288. Even after having undergone that enormous reduction of intensity which must
take place in reflexion from the surface of the moon, the solar rays still act with energy ;
for the moonshine produces all kinds of decompositions, acting like the sunbeam,
though in a feeble way, being probablv reduced to j^^Vo e P*^ ^^ ^^ original power (Ap., I
545). " '

289. This force, thus affecting in a radiant form vegetable organizations, produces
he results we are studying. The idea commonly entertained of its feebleness is utterly

inaccurate and wrong.

290. In proceeding now with the more immediate object of this chapter, I shall
follow the course of thought which has presented itself in my experiments. At the
risk of dwelling somewhat in tedious detail, I shall also describe the different experi-
ments from which the final arguments are drawn ; and as it will be found that the
rays of light and the tithonic rays are eventually under the government of the same
laws, similar expressions including the phenomena of both, I shall commence with giving
the theory of the absorption of the tithonic rays first, and then show how the same
theorv includes the phenomena of light This leads naturally to a division of the sub-
ject under two heads.

I. Theory of absorption of the tithonic rays.

II. Theorv of ideal coloration.

78 ABSORPTIVE ACTION OF CHLORINE AND HYDROGEN.

To the first of these the present chapter is devoted ; the following chapter to the
second.

291. When a beam of light has fallen on any changeable surface, such as a Daguer-
reotype plate, and is reflected by it, that beam will be found to have impressed a change
on the sensitive surface, greater or less in amount, according to the period of its action.
In effecting this it also suffers a change itself, and if received on a second similar sensi-
tive surface, is found to have lost the quahty of giving rise to the decomposition again.
Two changes have, therefore, occurred, a change in the ponderable body, and a change
in the incident beam. The particular experiments in proof of this fact are given in
Ap., 595.

292. Again, let us take a second instance. As is shown in Ap., Ch. XVL, a mix-
ture of chlorine and hydrogen in equal volumes undergoes combination by the influ-
ence of the rays of a lamp, and a rapid action, amounting to an explosion, by the
brighter beams of the sun. As these gases can be obtained in a state of uniform purity,
and their combination is attended with mechanical results, this forms a favourable case
for a minute investigation. With one such clear case to guide us in our researches, we
may fall back on it for illustrations, as new phenomena arise.

293. A mixture of chlorine and hydrogen, such as has been referred to, was placed
in a vessel made of plate glass, having flat and parallel sides; it was 7 inches higli, 2
broad, and 2-6 deep. It was so arranged on a small porcelain trough, that it could be
used as a gas jar. The rays of an argand lamp, properly situated, were made to pass
through it ; they therefore went through a depth of the compound gases of 2-6 inches. In
Jig. 123, A is the lamp, so adjusted as to burn steadily, B the vessel containing the
chlorine and hydrogen, C the porcelain trough, in which was placed a saturated solu-
tion of common salt, which acts on the chlorine slowly, and therefore allows us to
make any necessary experiments without much change happening in the gases under
trial. At D was placed a tithonometer (A?., Ch. XVL), to receive the rays from the
lamp, after they had emerged from the chlorine and hydrogen.

294. Two separate phenomena were now apparent: first, the mixture of chlorine
and hydrogen began to unite under the influence of the rays of the lamp ; second,
the rays which had passed through the mixture had lost very much of their chemical
power. It was not totally extinct, but the tithonometer showed that it had undergone
a very great diminution.

295. We see, therefore, that on its passage through a mixture of clilorine and hy-
drogen, the beam has become detithonized. Simultaneously, and in producing this re-
sult, we see that the sensitive mixture has become tithonized. The connexion and
sequence of the phenomena are apparent. The beam has undergone a change itself
in producing a given change in the ponderable matter. But this is the same conclu-
sion that was furnished us by the rougher experiment with iodide of silver above quo-
ted (Ap., 595).

296. At this stage of our inquiries, therefore, we have already fallen upon one of the
leading features of the doctrine of absorption ; for we perceive that, whenever tithonic
rays produce a change on a sensitive mixture, they must necessarily undergo a change
themselves, and become partially or perfectly detithonized.

PARTICULAR PHENOMENA EXHIBITED BY CHLORINE AND HYDROGEN. 79

297. From this point our inquiries naturally branch in two directions. First, The
consideration of what happens to the substance which is thus in the act of being chan-
ged or tithonized. Second, What happens to the ray in undergoing its converse change,
or being detithonized. These I shall discuss in succession.

298. Phenomena of the Tithonization of Clilorine and Hydrogen. — The tithonome-
ter enables us to ascertain the leading phenomena in a very satisfactory manner. Its
sensitive material being (Ap., 838) the very mixture the properties of which we are
considering, to determine the changes, and the rapidity of the changes which take place
in that mixture, we are only required to place a tithonometer in the rays of a lamp,
remove all external sources of disturbance, such as the action of radiant heat, &c. and
note the results.

299. To carry out these views, I have employed the arrangement represented in Jig.
124. A is an argaud lamp, which, during the period of observation, burns with uni-
formity. In front of this, and at a distance of about two inches, an arrangement of
double convex lenses, B, is placed. Beyond, at a distance of 7 inches, is a second
convex lens, 3-5 inches focus. Between B and C, a metallic screen, E, is arranged,
so that it can be easily removed or replaced, according as it is desired, to allow the
rays of the lamp to fall upon the tithonometer, or to cut them off.

300. The mode of action of the lenses of this arrangement is, to give a uniform
disc of light, M, on the sentient tube of the tithonometer. When a piece of white pa-
per is placed so as to receive this, in front of the instrument, there is a circidar disc,
which is equally luminous all over. If this condition be not exactly fulfilled, the lamp
or the lenses are to be moved and adjusted until the illumination is sensibly the same.
We have then the sentient tube of the tithonometer plunged in an area of light which
remains uniform in intensity during the period of our researches.

301. In this invariable disc of light we have to expose the mixture of chlorine and
hydrogen, and mark on the scale of the tithonometer the progress of its union. This
we do by noticing how many seconds elapse before the contraction arising from the
production of muriatic acid begins, and then how many seconds elapse as the liquid in
the index tube passes over each division.

302. In a particular experiment of this kind, the following numerical determinations
were obtained :

303. On removing the screen E, and allowing the rays to fall on the sensitive mix-
ture, first of all an expansion, amounting to half a degree upon the scale, was observed.
In sixty seconds this expansion ceased.

304. The mixture now remained stationary, no apparent change going on in it
At length, after the close of 270 seconds, it was beginning to contract, and muriatic
acid to form.

305. At the end of 45 seconds more, a contraction of half a degree had been accom-
plished ; the dimensions of the mixture were therefore now the same as when the ex-
periment first began ; this half degree of contraction compensating for the half de-
gree of expansion.

306. The number of seconds which elapsed as the liquid descended over the scale.

80

PARTICULAR PHENOMENA EXHIBITED BY CHLORINE AND HYDROGEN.

through contraction of the sentient gases, was now determined. These numbers are
contained in the following table. In one column is given the number of each divis-
ion ; in the adjacent one, the period of contraction through it.

Spaces.

Time m Seconds.

Spaces.

Time in Seconds.

Expanded i degree in . . .

60

16

18

Movement commenced . . .

270

17

18

Reached i degree of expansion

45

18

18

1

55

19

18

2

40

20

18

3

28

21

17

4

27

22

17

5

25

23

18

6

23

24

17

7

22

25

18

8

20

26

18

9

20

27

17

10

21

28

16

XI

20

29

16

18

20

30

16

13

20

31

16

14

19

32

16

15

19

Let us now take these observations and project them, as is done in ^g. 125, the
amount of contraction representing the quantities of gases that have united being laid
off on the axis of an abscissas, the times on the ordinates. But these times represent the
number of rays which have fallen on the sentient mixture ; consequently, the ordinates
of that curve represent the quantities of tithonic rays, dnd the abscissas the corre-
sponding chemical effects.

307. Inspection of the curve shows its peculiarities at once. We see that after the
first preHminary expansion has taken place, expressed by that portion between a and b,
for a certain space of time, although rays are constantly falling on the mixture and be-
ing absorbed, no visible effect is produced, there being neither expansion nor contraction,
as is shown hy b c. A certain space of time, amounting in this instance to 270 seconds,
being now accomplished, contraction, from union of the gases, begins. In that portion
of the curve c d which represents the progress of the phenomenon, the curvature is per-
petually diminishing, and at d approaches sensibly to a straight line. From d to e, which
includes the remainder of the observations, the line preserves its rectihnear character.

308. The study of the properties of this curve, or of the tabular numbers, serves to
prove that when chlorine and hydrogen unite under the influence of the tithonic rays,
there are four distinct periods of action.

1st. For a brief space the mixture expands.

2d. For a much longer period it then remains wholly stationary, neither expanding
nor contracting, although the rays are constantly falling on it and it is absorbing them.

3. Contraction arising from the production of muriatic acid begins, commencing at
first slowly, then more and more rapidly.

4th. And after that contraction has fairly set in, it goes on with uniformity, equal
quantities of muriatic acid being produced in equal times by the action of equal quan-
tities of the rays.

309. If, therefore, it is permitted us to generalize from this case of the action of rays
on one of the most sensitive substances known, a mixture of chlorine and hydrogen, we

' LATENT LIGHT. 81

should assert that when a ray falls on a sensitive componnd, its first effect is to pro-
duce an expausion. During a certain period, differing in different cases, uo cha: ge
whatever takes place, the ray being constantly absorbed, and not appearing to produce
any visible effect After a time, chemical action commences, at first more slowly, then
with a determined and constant rate of rapidity, equal quantities of the rays now pro-
ducing equal chemical effects.

310. I may here anticipate what will presently be proved, that this generaUzation
can be sustained, and that, therefore, the conclusions which we have arrived at for this
particular case, hold also for all others, not only in the cases of chemical action pro-
duced by the tithonic rays, but also of chemical action brought about by the rays of
light.

311. Let us return again to the study of the carve, or of the numbers contained in
the table. It is obvious that there are two portions of these which demand peculiar
attention; they are embraced in the second and fourth epochs referred to in (308). As
to the first and third, these are for the present of less interest.

312. What, then, is the interpretation we are to put upon that part of the curve
which is between b and c ? or, in other words, what is the interpretation we are to
give of the fact, that when a sensitive compound is exposed to a given ray, it does
not change all at once, but a certain period must elapse during which absorption is go-
ing forward, without any corresponding apparent effect ensuing, and that once accom-
plished, chemical change begins?

313. Is not this the same phenomenon which has been for a long time known in the
case of radiant heat ? When a ray of heat falls on a mass of ice at 32° Fah., in which
a thermometer is imbedded, for a certain space of time no apparent rise of temperature
takes place, but the radiation continuing long enough, a physical change is accomplish-
ed ; the ice puts on a fluid form, and now the thermometer commences to ascend,
equal quantities of heat producing, for a certain period, proportional 1}- equal effects.
Would not the table given in (306), or the curve projected in^g-. 125, answer as well
to express the phenomenon of the action of caloric upon ice, as of the tithonic rays on
a mixture of chlorine and hydrogen ?

314. It was from the study of that phenomenon in the case of ice that the doctrine
of latent heat arose ; and do not these things teach us that just as a calorific ray becomes
latent under certain circumstances, so also does a tithonic ray, and, consequently, a ray
of light 1 I regard the phenomenon of that pause which is seen before chlorine and
hydrogen unite, and during which absorption is taking effect, as setting forth in a strong,
and clear, and prominent manner, that Jis radiant heat may become latent, so also may
tithonic rays, and also rajs of light

315. Let us, in the next place, direct our attention to the second branch of the curve,
or to the fourth epoch, the changes of which are included between d and e. Rigor-
ously speaking, this is not a straight Hue. It only makes a sensible approach to one.
There are several causes which obviously interfere. When a given quantity of gase-
ous mixture is exposed to a radiant source, and the experiment we have been relating
performed, it is obvious that, as it proceeds, the volume of gas so exposed steadily di-

L

82 PRELIMINARY ABSORPTION. ^

minishes, and the effect of this must be apparently to diminish the force of the ray.
Moreover, during the progress of the trial, muriatic acid gas accunmlates, for its ab-
sorption does not instantaneously take place ; the operation of this must be the reverse
of the former, or apparently to increase the effect. To a certain extent, but not per-
fectly, these sources of error may be avoided, as I have attempted, and practically we
may discuss the branch of the curve, d e, as though it were a straight line.

316. This being understood, the result which is before us leads us obviously to this
important law, that for a given compound, equal quantities of tithonic rays, after the
prehminary latent absorption is over, give rise to equal chemical effects.

317. In thus setting forth, in as prominent a manner as I am able, these two doctrines,
1st. Of the latent condition of the rays that are at first absorbed ; and, 2d. Of the def-
inite chemical action of those that are subsequently, I am agaiu urging the same doc-
trine which three years ago (Ap., 595) I attempted to establish for iodide of silver.

318. In passing, it may be observed, that one of the gre^itest practical difficulties in
the art of photography, more especially in taking portraits from life, is connected
with this matter of preliminary latent absorption. Artists know well, that to obtain a
perfect result is the exception, and an indifferent one is the rule. It is, indeed, rare
that the relation of light and shadow is perfectly observed; the high lights most com-
monly come out unduly, the feebler lights are more slowly evolved, and very often never
come out at all. This arises from the circumstance that the sensitive surface does not
begin to change uniformly from the first instant of exposure, but the preliminary latent
stage of absorption has to be gone through ; with high lights and a brilliant illumination,
that period is passed over in an instant, and the second entered upon; but the feebler
fights have to expend themselves for a long while in passing through this stage, and
while the others have carried on their operation almost to completion, these have not
been able to leave a sensible trace of action. Theoretically, the remedy for this diffi-
culty would be, by a brief exposure to a transitory or dim light, to pass the sensitive
surface uniformly through its preliminary stage.

319. These, therefore, are the prominent phenomena which are exhibited by a mix-
ture of chlorine and hydrogen, a latent preliminary absorption, and a subsequent def-
inite chemical action. We have observed them also in iodide of silver (317), and in
various other compounds.

320. Let us direct our attention, in the next place, to what has happened to the ray.
We have already seen (295) that when, through a gaseous sensitive mixture, the beams
from a lamp are suffered to pass, and fall on the tithononieter, they are found to have
lost much of their chemical force. The beam has therefore become detithonized.

{a.) The vessel described (293) was filled with atmospheric air over the trough,
and the chemical force of the ray passing through it from the lamp {Jig. 123) was de-
termined. It was measured by the period required to cause the index to descend
through one division, and represented by 12 seconds.

(J.) The vessel was now half filled with chlorine, derived from a mixture of muriatic
acid and peroxide of manganese, and the chemical force of the ray, after passing through
it, determined as before ; it now was represented by 25i seconds.

FDXCTIONS DISCHARGED BY THE CHLORINE AM) HYDROGEN RESPECTIVELY. ^

(f.) To the chlorine an equal volnme of hydrogen was now added, the vessel being,
consequently, full of the united mixture. The force of the ray was again measured,
and fouod to be represented by 19 seconds.

(cL) Lastly, the first (a) of these preceding measures was determined again, with a
view of ascertaining whether the intensity of the lamp had declined, or the apparatus
remained in its first condition. It gave again 12 seconds.

321. Let us group these four results together, representing thus the intensity of the
beam by the time it requires to produce a given eflTect:

A beam through the glass vessel ^ . . . is seconds.

Chlorine 255 "

Chlorioe and hydrogen 19 "

Atmospheric air IS "

We therefore gather from this, that the addition of hydrogen to chlorine, far from in-
creasing its absorptive power, actually diminishes it. That in the case before us,
where to a given volume of chlorine an equal volume of hydrogen has been added, the
absorptive power is diminished to one half

322. We farther see, that the action of the beam is expended primarily on the chlo-
rine, giving to it a disposition to go into union with hydrogen, and that the functions
discharged by the chlorine and hydrogen respectively are wholly different

323. The chemical forces of the ray are easily deduced from the foregoing meas-
ures, in which the times are given, for it is obvious that they are inversely proportional
to those times.

324. The second and third experiments (b) and (c) may, without sensible error, be
taken as representing the activity of the ray in vacuo, for, as will be seen, upon prin-
ciples hereafter given, a ray which has passed through atmospheric air has not under-
gone any absorptive action, and therefore does not differ from one which has passed
a vacuum. Consequently, those measures give us the effect of chlorine, and of chlo-
rine and hydrogen, compared with a vacuum. The absorptive action of the glasses is
common to all the experiments, and may therefore be left out of the final estimate.
The difference of the resulting numbers in b and c, from the probable numbers 25'5
and 18"7, may be accounted for from the disturbing causes which are encountered, such
as the constant solution of chlorine by the salt water, &c.

325. When, therefore, a ray of light falls upon this changeable compound, chlorine
and hydrogen, the primary action takes place upon the chlorine, which becomes titho-
nized, or has a disposition given to it to go into union with the hydrogen ; the latter
gas appears to be passive, so far as the ray is concerned. In the mean time, the ray
itself becomes changed, undergoing absorption action, and being detithonized.

84 THEORY OF IDEAL COLORATION.

CHAPTER X.

THEORY OF IDEAL COLORATION.

Contents : Former Observations on Colours in the Chemical Rays. — Nomeuclniui-e
derived from it. — Case of the Chrysotype. — Case of Bichromate of Potash. — Laws
deduced. — Control of Optical Forces over Chemical Effects. — Application to Spectrum
Stains. — HerscheVs Law for Light. — Explanation of Variable Effects in Films of
different Thickness. — Mode of Action of the Tithonic Rays.

326. In the year 1837, while the study of the chemical agencies of light was yet in
its infancy, from phenomena connected with the decomposition of carbonic acid, the
synthesis of chlorine and hydrogen, and the decomposition of chloride of silver, I came
to the conclusion that there were among the chemical rays intrinsic differences, of the
same order as the differences in colour among the rays of light, and that for those rays
the doctrine of invisible coloration would have to be admitted (Ap., Ch. X.).

327. More recently, M. Melloni, to whom science is indebted for originating and de-
veloping this beautiful thought, in the case of rays of heat, has independently come to
the same conclusion. So intimately is this idea bound up with the explanation of the
phenomena, that, in the case of radiant heat, that eminent philosopher proposes to use
it as the foundation for the whole science, and for its nomenclature. — ( Taylor s Sc. Me-
moirs, vol. iii., p. 12.)

328. In what follows, I shall not attempt to introduce the doctrine in an analytical
way, or to trace the arguments and experiments which lead to its conclusions ; but, assu-
ming it at once as true, show with what facility and ease it may be brought to explain
a number of remarkable phenomena. Calling to mind the facts and views which have
been given in the preceding chapter, and more especially to the general fact, that when-
ever a ray produces a chemical effect it undergoes a change, the sensitive or changea-
ble medium absorbing some one or more of its constituents, it remains now, in addition
to the considerations there given respecting the characters of the rays, to introduce an-
other element — the element of variable refrangibility.

329. Asserting, therefore, that for the chemical rays there exist peculiarities analo-
gous to the different colours of light — pecuHarities which, by reason of the invisibility
of those rays, are known to us only by certain chemical phenomena — it remains, in
bringing forward this doctrine with clearness and precision, to adopt some provisional
nomenclature, and, for want of a better, one founded on those terms heretofore intro-
duced (242) will serve our present purposes.

330. In developing the doctrine of ideal coloration applied to the tithonic rays, I
shall therefore resort to what appears to be the simplest rule, and designate rays of dif-
ferent orders of refrangibiUty by the same nomenclature which has been used for light :
thus we shall have

ANALYSIS OF THE CHRYSOTVTE. 85

Tithonic red.

Tithonic orange.

Tithonic yellow, &c., &c^
the expressions pointing out the region of the spectrum under consideration, bat
drawing a strong and perfect distinction between the agent involved and light In the
same way other derivates will arise, such as tithonic white or black.

331. When a beam of light is dispersed by the action of a prism, and the resulting
spectrum examined by physical tests, it is easy to recognise that the quality of impart-
ing a sensation of difference of colour is not the only token of intrinsic difference in
the character of rays of different refrangibilities. Writers on the mechanical theory of
optics have assumed, that the constitutional distinction between the various colour
giving rays is the different lengths of waves which they represent To a given index
of refrangibility there belongs a particular length of wave, and a particular tint of col-
our. But there are facts connected w ith the history of light which seem to prove that
beyond this there are peculiarities which are far more profound.

332. Several years ago, Sir D. Brewster showed that, by resorting to absorbent
media, rays of any colour could be insulated in every part of the spectrum ; that red
light existed in the violet spaces, and blue light in the red. These results, being sub-
stantiated, would appear to afford a very formidable argument against the dependance
of colour on wave length.

333. I do not propose to enter here on any speculative considerations respecting the
physical causes which enable light to impart to an organ of vision the phenomena of
tints, but to show that the idea of coloration must be admitted for the chemical rays.

334. As, in the foregoing chapter, we gathered our final views respecting absorption
from considerations originally drawn from one case ; so, in this, let us examine the
phenomena exhibited in one or two cases, and then generalize from them. We have
already seen (Ap., 597), that when a ray has impinged on a sensitive surface, as on a
Daguerreotype plate, and been reflected by it, it has lost, to a great extent, the power
of again producing the same effect, or is detithonized.

335. The remarkable process discovered by Sir John Herschel, and called by him
chrysotype, enables us to verify in an easy and very satisfactory way the truth of this
remark.

336. Case of the Chrysotype. — The sensitive material employed is the ammonio-
citrate of iron; a solution, which, when viewed through small thicknesses, is of a yellow
colour. From its being a solution, it is pecuUarly fitted for these experiments.

337. When a piece of paper, washed over with this yellow solution, is exposed to
the sun behind a trough containing the same solution, the paper is found to change
very slowly, showing that the liquid in the trough is absorbing the active rays.

338. Prismatic Analysis of the Chrysotype. — (a.) I projected a motionless spectrum
on chrysotype paper, and speedily obtained an impression of a pale brown colour, which,
when brought out by neutral chloride of gold, was found to extend from a to /3, Jig.
126, X.

(b.) Having passed a beam from the heliostat, through a trough with parallel sides,

gg LAWS DEDUCED FROM IT.

containing a solution of ammonio-citrate of iron, of such strength, and in a stratum erf
such thickness, as to appear of a bright yellow colour, I dispersed it by the prism, and
received the spectrum, as before, on chrysotype paper. For a long time the paper re-
mained unchanged, but after an hour's exposure I was able to bring out a very faint
mark, the position of which was 6, e,Jig. 126, x.

339. The inference which plainly arises from these experiments is, that the active
chrysotype rays are absorbed by the ammonio-citrate of iron; or, in other words, that
this substance is sensitive, because it absorbs a peculiar class of rays. No change can
take place in chrysotype paper by rays that have passed through ammonio-citrate of
iron, because they have been absorbed, and are already expended in effecting the re-
quired decomposition.

340. The same conclusion was arrived at by experimenting in the following way:
I prepared a sensitive plate by exposure to iodine and bromine successively, which
gives, as is well known, a very changeable surface. This plate may be called, for the
sake of distinction, a test-plate.

341. On this test-plate I received a spectrum formed from a beam which had passed
through the trough containing ammonio-citrate of iron. After a suitable exposure, I
found a stain reaching from y to a, Jig. 126, y. But, as is shown in Jig. 126, x, the
rays which affect the ammonio-citrate of iron reach from a to (i. Consequently, we
perceive that those which affect the test-plate are complementary to those which affect
the chrysotype. We draw, therefore, these farther conclusions :

1st. That the rays which escape absorption hy the ammonio-citrate of iron are pre-
cisely those which do not affect it chemically.

2d. That the rays which are absorbed by the ammonio-citrate of iron are the rays
which produce chemical changes in it.

342. Let us take a second case, selecting for consideration the bichromate of potash.
Case of the Bichromate of Potash. — As is well known, a piece of paper dipped

in a solution of this salt speedily turns brown on exposure to the sun's rays ; but if there
be placed before it a trough containing a solution of the salt, then the change goes on
very slowly.

343. Prismatic Analysis of this Case. — On projecting a motionless prismatic spectrum
on this paper, an impression was obtained in a quarter of an hour, which extended from
o to ^,Jig. \T1, X.

I 344. A trough with parallel faces, filled with a solution of the salt, was next inter-
posed in the beam, and the resulting spectrum received on a bromoiodized test-plate. It
extended from y to a. Jig. 127, y.

345. In reference to the test-plate used in these cases, its applicability depends on
a fact pointed out by Sir J. Herschel {Phil. Trans., 1840, p. 38), that bromide of sil-
ver is equally affected by all the rays of the spectrum. In using it as here described,
the experimenter must assure himself that sufficient of the bromine has been employed
lo give sensitiveness to the extreme rays of the spectrum ; it should produce such a ti-
thouograph as that given m Jig. 128, the red region being fully brought out.
' 346. On examiuingj?g5. 126, r, 126, y, we perceive that they prove for the bichro-

LAWS DEDUCED FROM IT. 87

mate of potash what has been already proved for the chrysotype preparation — that the
active rays are absorbed, and that the inactive rays escape.

347. Without dwelling longer on the detail of farther instances, it appears that the
general laws under which these phenomena take place are as follows :

IsL When a rav impinges on a sensitive surface, or passes through a changeable me-
dium, with the chemical effect that takes place, the constitution of the ray is corre-
spondingly disturbed. A change in the composition of the medium involves a change
in the ray.

2d. Rays which thus disappear by absorption are occupied in disturbing the consti-
tution of the ponderable medium.

3d. Rays which are inactive, or which are not involved in the chemical change go-
ing on, escape from the medium by being transmitted or reflected.

348. The definite views which we thus gather respecting the absorption of the dif-
ferent constituents of the solar rays, and the production of chemical changes, lead us
by very simple steps to regard one as the cause and tlie other as the effect. In cases
like these, the safest way to true conclusions is, to be guided by analogies. It is true,
that the properties of the different agents in the solar beams are sufliciently distinct,
but, as radiant principles, they have certain qualities in common. The heat of a sun-
beam converged by a lens on red oxide of lead is absorbed by that substance ; oxygen
gas is given off, and a lemon-coloured protoxide remains behind ; no farther absorp-
tion of heat now takes place, and no farther chemical changes ensue. Heat, therefore,
as well as light, or the tithonic or phosphoric rays, in producing its effects, undergoes
absorption.

349. In thus making the phenomenon of absorption the fundamental fact of our the-
ories on the chemical action of the sunbeam, and in giving a distinct prominence to it,
a great deal of precision will be brought into our theoretical discussions. Almost every
experimenter has, to a certain extent, recognised the truth of these views in a general
way, though without clearly setting forth the exact conditions under which absorption
takes place. In 1841 (Ap., Ch. XII.) I pubUshed some experiments to show how
completely all the chemical changes effected by light were under the control of ab-
sorption, and that the sensitiveness of any given changeable compound could be altered
by altering its optical constitution.

3-50. So, in the case of radiant heat, a piece of polished silver exposed to the focus
of the most powerful burning mirror never melts, not because it is an infusible body,
but because such an optical constitution has been given to it, that it reflects the heat
which impinges on it. If the polish be taken off, and the surface slightly roughened,
it melts in an instant, because it can absorb the rays. So, too, different coloured pieces
of cloth, exposed to the sunshine upon snow-, will sink to different depths, because the
quality of coloration which they possess enables them to absorb the heat more or less
rapidly, and the calorific effect is determined by the optical constitution.

351. Apparently nothing can be of a more irregular character than the photographic
impressions and points of maxima left by the solar spectrum on various surfaces. With
trivial causes the position and dimensions of those impressions change, but when we

gg APPLICATION TO SPECTRUM STAINS.

come to consider their mode of origin, as thus connected with absorptive influence,
nothing is more plain or easy to understand. We must regard them as phenomena
of exactly an equivalent character to those of the different appearances exhibited by the
luminous spectrum when it is received on variously-coloured paper. For, in respect
of the tithonic rays, surfaces that have the same tint to our eyes act Hke surfaces of
different colours. A solar spectrum received on a surface of lampblack is scarcely
visible. On a piece of red paper the red and orange rays are copiously reflected, the
others more or less absorbed. On a yellow paper the yellow and orange are brilliantly
given, but the blues almost disappear ; on a blue surface the more refrangible rays are
brightest, the yellows have faded away. So, when sensitive surfaces are exposed to the
spectrum, they give us an expression of their particular action. Bromide of silver ab-
sorbs more uniformly than any other body that we know rays of every refrangibility.
In respect, therefore, of the tithonic rays, it acts as lampblack does to the luminous,
and might be regarded as a black body. Iodide of silver absorbs the blue, and reflects
the red, the orange, the yellow, and part of the green. To eyes, therefore, which could
perceive those invisible rays which it reflects, it would be seen as though acting as a
ruddy- coloured body, and giving forth rays like those which nitrous acid gas transmits.

352. When, therefore, we find on a sensitive surface which has been exposed to the
spectrum a given stain, we infer that rays corresponding in refrangibility to the place
of the stain have been absorbed, and the rest reflected or transmitted. And if this be
true, our views will be greatly facilitated if we resort to some simple method of nomen-
clature, which shall be descriptive of the facts observed. It is for this reason that we
have proposed to recognise the phenomenon of coloration for these dark rays, and speak
of red tithonic, yellow tithonic, or blue tithonic rays, as pointing out in a general man-
ner the place in the spectrum of the ray, the properties of which we are discussing.
Extending these ideas to the physical characters of ponderable bodies, we would assert,
with Melloni, that they have an invisible coloration of their own ; that bromide of sil-
ver is tithonic black, though as respects light it is white ; that iodide of silver is tithonic
red, though as respects light it is of a lemon yellow.

353. Aided by these definite views of absorptive -action, and the concomitant phe-
nomena of coloration, it becomes interesting to examine whether these principles are
applicable to cases in which chemical changes are brought about by the action of light.
It is with a view of showing that all these things hold in the decomposition of carbonic
acid by leaves under the light of the sun, that we have entered on this minute dis-
cussion.

354. The law under which the discharge of vegetable colours in the solar spectrum
takes place has not escaped the penetration of Sir J. Herschel, who has furnished us
with so much that is new in this department of science. " The rays effective in
destroying a given tint are in a great many cases those whose union produces a colour
complementary to the tint destroyed, or, at least, one belonging to that class of colours
to which such complementary tint may be referred." — (Phil. Trans., 1842, p. 189.)

355. Now this is nothing more than an expression of a particular case of absorptive
decomposition, in which light is the agent, and vegetable matter the substance involved.

HERSCHEL' LAW FOR UGHT. 89

The reason that a yellow substance is bleached by blue rays, is because it absorbs
those rays, for the very same reason, therefore, that it looks yellow. A purple vegeta-
ble body is bleached by the yellow and green rays, and because it absorbs those rays it
looks purple.

356. As respects light, the phenomena of coloration are obvious to our organs of vision ;
as respects the dark beams of heat, of chemical action, and of phosphorescence, they
must be hypothetical or ideal ; but, in the same manner that Melloni has found the
admission of them for the calorific rays of such admirable advantage, so, in tliis depart-
ment of science, similar and palpable advantages arise. Who could for a p oment
doubt that Ught and the tithonic rays were agents totally distinct, so soon as he came
to understand that to one of them iodide of silver is yellow, to the other orange ; to
one chloride of silver is white, to the other red ; to one bromide of silver is white, to
the other it is black ?

357. These principles undergo a severe test when we examine the phenomena that
arise when sensitive surfaces of different degrees of thinness are used. As is well
known, if a silver plate be exposed to the vapours of iodine, it passes through severa!
orders of colour, red, yellow, blue — red, yellow, blue, t&c, &c. In each one oi" these
series, as I formerly showed, the yellows are chemically the most sensitive (Ap., 622, &c.).

358. If, therefore, we successively expose to the solar spectrum thin plates of iodide
of silver of the above-named tints, we might infer that the resulting impression should
change its position with the colour of the plate ; that, if that colour was yellow, the
rays corresponding to the blue should be absorbed, and the spectrum impression be
found among the more refrangible rays ; that, if the colour was blue, a tint arising from
absorption of the yellow, a spectrum stain should be found corresponding to the posi-
tion of the yellow rays, and not to the blue, these last undergoing reflexion ; and,
finally, as the colour of the plate changed, so should the photographic spectrum shift
its position.

359. But, on making the experiment, I found that this result does not arise ; it is
immaterial what the colour of a Daguerreotype plate may be, the spectrum leaves upon
it an impression in an invariable position. In the absence of diffiised light, this impres-
sion is entirely among the more refrangible rays.

360. But as the colour of the plate changes, although the photographic impression
remains invariable in position, it undergoes variations in intensity. It exhibits the
deepest stain when the plate is yellow, is more faint when the plate is red, and be-
comes hardly perceptible when the plate is of a grayish metallic aspect. Time, of
course, enters as an element into these results ; a gray colour \*'ill receive as deep an
impression as a yellow, if the period of exposure be inordinately prolonged.

361. From this we gather, that on exposing films of iodide of silver of different
thicknesses, and therefore of different colours, to the spectrum, the resulting impression
does not shift its place, but, remaining fixed in position, undergoes variations in sensi-
tiveness— variations which are exhibited by differences in the depth of the stains. And
this result is a striking instance of the doctrine of ideal coloration. Upon the princi-
ples of that doctrine, it meets with a beautiful explanation.

M

90 MODE OF ACTION OF THE TITHONIC RAYS.

362. The iodide of silver is a body which copiously absorbs blue tithonic rays, d
quality arising from its chemical relations and constitution. It is unaffected by the
pure yellow and red tithonic rays, when they operate alone, and diffused light is exclu-
ded. Consequently, it can give no indications dependant on the presence or absence
of theai. The sunlight to it is monochromatic, or nearly so, for it is decomposed by
blue, indigo, and violet rays only. The phenomena, therefore, which it will exhibit
when in thin plates, are such as would be exhibited by thin transparent plates of air,
or water, or glass, on which a monochromatic light is falling. If monochromatic light
falls upon plates of glass of variable thickness, the reflected beam simply changes in
intensity, and, if the language of science permitted us to describe bodies in their opti-
cal relations as being more sensitive to light when they failed to reflect it to our eye,
and less sensitive the more copious the reflexion, we can understand that the plate of
glass would pass through all orders of sensitiveness as its thickness varied. At one
time it would reflect all the incident beam, and as it increased in thickness the ray
would diminish in intensity, and finally disappear, and, with a still farther increase, th«
brilliancy of the beam would again be reassumed, and so on through successive periods.

363. Now this is absolutely the same phenomenon as that exhibited by iodide of silver
in films of variable thickness tchen exposed to the spectrum. It depend on the ideal col-
oration of the iodide.

364. Let us examine, in the next place, what should be the event when bromide of
silver is used instead of iodide.

In order to enable us to predict the result, we have simply to consider what would
occar if a film of lampblack, or of any other perfectly absorbent body, could be obtain-
ed, of suitable thinness, and exposed to the luminous spectrum. For, to use a some-
what objectionable, but perhaps emphatic expression, bromide of silver is the lamp-
black of the tithonic rays. It is obvious that a perfectly absorbent film would uni-
formly appear black, no matter what its thickness might be. The tints of thin plates
arising in interferences among reflected or transmitted rays must, in this instance, be
absent. A film of bromide of silver must, therefore, have a uniform sensitiveness— a
sensitiveness which is independent of its thickness.

365. Having thus explained the laws of absorption and the doctrine of ideal color-
ation in this and the preceding chapter, it remains only to add a few words on the
mode of action of the tithonic rays.

366. There is no reason to believe that oxygen, hydrogen, or nitrogen gases, in
masses of ordinary magnitude, exert any perceptible absorptive effect on light, heat, or
the tithonic rays. These bodies, therefore, and all others having the same relation,
can exert no action on each other, even though they are under the influence of the
most intense radiation.

367. A mixture of oxygen and hydrogen gases, exposed to a briUiant light, can never
produce water, because neither of its constituents has the power of absorbing the in-
cident rays.

368. But a mixture of chlorine and hydrogen gas explodes in an instant under the
influence of light, because the chlorine can exert a powerful absorbent action.

CONNEXION BETWEEN ABSORPTION AND CHEMICAL ACTION. 91

' 369. From these theoretical considerations it would appear that, in the case of chlo-
rine and hydrogen, the latter gas is wholly passive ; the chlorine, being acted npoo,
absorbing the chemical rays, is thrown into such a condition that union takes place
with the hydrogen.

370. A remarkable consequence follows from these views. If the reason that oxy-
gen and hydrogen cannot form water under the influence of the sunlight be due to the
circumstance that neither of those gases can absorb tithonic rays, but are perfectly
transparent and colourless, and the reason that chlorine and hydrogen at once form mu-
riatic acid, be due to the absorbent capacity of the chlorine, it results that when a mix-
ture of these latter gases intercepts a ray, the absorbent action upon that ray should
not be ejeater than that of the chlorine alone, and even not more than one half, because
of the diluted state in which the chlorine is presented. But this is the same conclu-
sion to which we have previously arrived by direct experiment (321).

371. The views which have been given in this chapter serve to show that chemical
action is the uniform result of absorption ; but the converse of the proposition doe-; not
hold good ; absorption is not necessarily attended by chemical action. Nevertheless,
it is attended with a certain effect Even in the case of an elementary, and therefore
unchangeable substance like chlorine, a disposition or capacity for union is communi-
cated. Chlorine that has been exposed to the sun unites with hydrogen more readily
than chlorine which has been made and kept in the dark (Ap., Ch. XVIIL),

CHAPTER XI.

ON THE MODE OF ACTION OF LIGHT IN DIRECTING THE DIGESTION OF PLANTS.

Contents : Connexion beticeen Absorption and Chemical Action. — Radiant Matter is
absorbed in producing different Effects. — Reappearance of the Force expended. —
Laits of Preliminary Absorption and Definite Action observed by Plants. — Increased
Rapidity of Vegetation implies increased Brilliancy of the Incident Light. — The
Sun probably a Periodic Star. — Description of the Mode of Action of Light and
Radiant Heat on Leaves.

372. We are now ready to take up the consideration of the question proposed in ")
Chapter II. : In what manner does Ught act in directing the digestive function of
plants ?

373. From various phenomena exhibited by radiant heat, M. Melloni has developed
the doctrine of invisible calorific coloration, those of latent heat and a!-sorption having
been established many years ago. In the same manner, from phenomena connected
with the tithonic rays, we have developed for them analogous doctrines in the prece-
ding chapters. As respects light, the views which, for the other imponderables, are t
only ideal or imaginary, for it become certain; because our organs of vision inform us

/
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/

(

91^' RADIANT MATTER IS ABSORBED.

at once. A ray of light, dispersed by the action of a prism, presents to us a spectrum in
which we see plainly intrinsic differences of the various parts. Exposed to this spec-
trum, or to these coloured spaces, vegetable juices of different tints undergo modifica-
tions ; some are changed by the blue, some by the yellow, some by the red ray. If we
examine the conditions under which these things take place, as we have done for heat
and for tithonicity, we find similar evidences of absorption. Thus, chlorophyl, which
gives a green colour to leaves, undergoes a change by light, and becomes white ; and
when, by prismatic analysis, we inquire what rays are active in producing this effect, we
find that they are those which have been absorbed.

374. For plants, therefore, coloration is intimately connected with chemical action.
There is a chemical reason why leaves are green and flowers are never black, but un-
fold a painted corolla ; and, guided by these principles, we can see that all those various
active principles which are stored up, all the different juices which circulate, are con-
nected with, and have borne a certain relation to the coloured portions. In a rose, the
leaves of which are green, and petals red, and interior organs of reproduction of a gaudy
yellow, these tints do not result from a wanton play of Nature, but are rather evidences
of premeditation and forethought. As anatomists have been enabled to deduce from
their studies a testimony for the existence of a Universal Designer, so, too, might chem-
ists, from reasons on the colours of a wild flower, show that those colours are the means
of accomplishing certain ends.

375. These things hold, whatever doctrines we assume respecting the nature of light;
whether, with Newton, we regard it as consisting of emanations of particles which are
exceedingly small, or, in the more refined views of modern philosophers, as undulations
of an elastic medium. The waves of sound which pass through our atmosphere in
like manner produce striking and permanent results, and even are often connected with
those higher philosophical events which not only belong to material things, but also to
the world of intellectuality. There are strains of music which have been listened to
in youth, and have communicated a permanent impression to the brain, which, in
after life, spontaneously present themselves to the memory. It is true that these things
originate in intellectual operations, but it is equally true that the channels of commu-
nication through which they have passed from mind to mind belcHig to the inorganic
world. It is atmospheric pulsations which are thus registered in the brain. In that
wonderful organ they are stored up, and amid the hourly change of every part of the
living system, the constant introduction of new particles, the passing away of those
which are dying or effete, these aerial pictures are permanently preserved. In an in-
stant, and spontaneously, there flashes across the memory a recollection of events which
transpired half a century before, and which have been buried in oblivion. So, also,
with the undulations of light. The effect of these in no case passes away, but leaves
its permanent impression on material things, and these impressions, though for many
ages they may He dormant, reappear again at their proper time, and produce their
proper effect. Ten thousand centuries ago the sunbeams fell on the leaves of trees,
and decomposed carbonic acid just as they do now ; and the woody matter they pro-
duced was buried in the earth. In natural affairs no such thing as a system of expe-

REAPPEARANCE OF THE FORCE EXPENDED. 93

dients is known, but all results from the operation of far-reaching and immutable laws.
In those remote times events were taking place, the appUcation of which referred not
to things then existing, but to an hereafter. The earth, and the sea, and the air were
enlivened and invigorated by the sunbeams as they are now, but while present pur-
poses were subserved, the fiiture also was not forgotten. In the twilight that then ex-
isted, as it does now, the wolf followed his flying prey, and by the light of the same
stars' the royal tiger pursued his midnight maraudings. Nor is there anything op-
posed to the order of Nature in those things. Intellectual development can only take
place when a thousand natural conditions conspire. Reason and analog}' would equally
lead us to suppose that, in a majority of those globes which are scattered through the
regions of space, those conditions are not attained ; that they are, as this earth was for
countless ages, a dungeon of pestiferous exhalations, and a den of wild beasts. And
yet the formative forces of Nature are at work ; the plastic fingers of Ught, each colour
producing its proper effect, are arranging, and decomposing, and modelling, and the
work which thus goes on in silence attains perfection in the lapse of ages. In those
planets, as in this, the atmosphere and the sea are finally brought to a proper constitu-
tion, and wild animals make their appearance, and then intellectual beings. For these, .
whatever is wanted has been provided. And results which for so long a time have lain I

dormant now come into use, just as those forces which in primeval ages were expended
bv light in the reduction of carbon by leaves; carbon which has been buried in the
earth, in our times reappears again, and is, perhaps, occupied in driving the steam-ship
that carries these pages over the waves of the Atlantic Ocean.

376. Two prominent facts must always be present to the mind of a natural philoso-
pher— the indestructibility of matter, and the indestructibility of forces. Disappearances
of the one or of the other are only fictitious deceptions. Throughout the universe the
quantity of matter and the quantity of force remains forever unchanged. Material
atoms migrate from one condition to another, now putting on the form of a solid,
now of a liquid, now of a gas ; so also with forces, which are occupied in producing
sometimes one, and sometimes another effect ; but the quality of the former and the
value of the latter remains, under all circumstances, unchanged. And when such con-
siderations as those which are before us show that rays of hght of different colours
have certain offices to discharge, and certain chemical effects to produce, affinities of
given iutensities to overcome, molecules to group in determinate positions, these are
things which can only be done by the -expenditure of a certain force ; but, though that
force be expended, it is not destroyed ; it is ready to reappear firom its condition of trans- \

mutation. In the same way that, all over the American Continent, at a certain period '

after the fall of the leaf the Indian summer sets in, and in the cold weather of winter |

restores the warm days of July, the heat which is evolved from decaying leaves in the /

forests being derived from the snnrays of the preceding summer, so also every ray ,

which has been expended, no matter of what colour it may be, or what has been the f

chemical or physical result with which it has been connected, or what series of trans- •

mutations it has passed through, is ready to be restored in its pristine energy, and give •

rise toils equivalent mechanical effect. And hence we can see that although, so far

94 PRELIMINARY ABSORPTION AND DEFINITE ACTION OBSERVED BY PLANTS.

as the whole universe is concerned, the amount of force never varies, there are peri-
odical variations in its distribution. The solar rays which year after year are impin-
ging on our earth, are so much taken from him, and so much given to us ; and, judging
from these things, we should infer that the amount of force exhibited on the surface of
our globe should steadily be on the increase. Are not these also the ideas which we
conceive from geological investigations I And is it not this which, from a silent and
tenantless waste, has made that surface the abode of myriads of living things 1 that
produces all over it locomotion and activity, and that makes all the difference between
what our earth was at the beginning of the secondary epoch, and what she is now?

377. It was an observation of the older botanists, that the green parts of plants only
possess the quality of reducing carbon from the air. In other portions, and under cer-
tain circumstances, a reverse action takes place, and carbon, probably under the form
of sugar, is oxydized. This never takes place in the presence of chlorophyl. The
analogies which we have traced between the mode of action of light, heat, and the
tithonic rays, would serve to indicate, that in this remarkable decomposition the lumi-
nous rays undergo the same changes, and, indeed, act in a similar w ay to radiant heat
when it gives rise to decompositions, or the tithonic rays when they produce surface
alterations. From these analogies, we should judge that the active rays in this instance
undergo a true absorption, which is, perhaps, divided into two periods, as we have seen
is the case when chlorine and hydrogen unite (317), or iodide of silver is decomposed.
That the preliminary absorption is observed, numerous facts seem to indicate. When
leaves, immersed in water containing carbonic acid in solution, are set in the sunshine,
they do not all at once commence evolving gas, but a certain period of time elapses be-
fore the bubbles pass off with any rapidity, and that period once over, they seem to fol-
low the fluctuation of light with considerable accuracy. A cloud passing before the
sun restrains the speed of reduction, and an increased brilliancy of light is followed
by an increasing rate of decomposition. From the mode in which these experiments
are necessarily made, there is not a perfectly clear proof of the preliminary absorption,
for it is not impossible that the hesitation in evolving gas which is observed comes from
disturbing causes. It may require a certain time for the carbonated water to find its
way through the tissues of the leaf, and to reach the seat of action. It may also re-
quire a similar period of time for the evolved gas to percolate out. But still, allowing
for these disturbing actions as much time as might be reasonably supposed sufticient,
there can be little doubt that, when leaves are -brought out of the dark and set in the
sunshine, a certain period elapses before vigorous action sets in — a period which seems
to correspond to that of the preliminary absorption observed in other cases.

378. If any doubt should remain on that point, there can be none on the circum-
stance that light observes the law of definite action. Not only is this apparent from
the phenomenon taking place with a rapidity corresponding to great increases and dim-
inutions of light, but also that minor differences are rigidly observed. Even in the
spectrum, we have seen that the rate of decomposition follows very closely the order
of illuminating power, and here we have rays of various refrangibility and of different
•colours in action. If, under such circumstances, where variations of colour intervene,

CONTROL OF THE BRILLIANCY OF LIGHT. 9c

the coarse of the phenomenon seems to be directed by mtrinsic brilliancy, there can be
very Uttle doubt that, for the same colour, or for white light, the law is rigidly observed,
a brighter illumination or a greater quantity of light producing an increased effect, a
lesser illumination or a feebler light producing a diminished effect.

379. It seems to be substantiated by geological facts, that in former ages the rapidity
of vegetable growth was far greater than it is now ; that certain plants, which with
us attain only to an insignificant size, in those times reached a very great magnitude.
So ferns, which in our latitudes are now of an insignificant growth, in the same places
were formerly evolved into trees. The general character of vegetation, also, in given
latitudes, points to a former period of greater luxuriance — a period during which trop-
ical trees could grow in the temperate zone. Geologists have already concluded, from
these and a variety of other observations, that the surface temperature has undergone
a dinunution.

3S0. But there are many conditions which have to be fulfilled before so marked a
difference could have taken place. The rate of vegetable growth depends on manv
things : on the amount of aqueous vapour and carbonic acid in the air, on the mean tem-
perature of the surface, on the brilliancy of the incident light, &c. There are experi-
ments which seem to show that the constitution of the atmosphere is by no means so
favourable as it might be ; a greater quantity of carbonic acid in it is attended by a
greater rapidity of growth, and since those times of which we are speaking, great chan-
ges have taken place in this respect. Of the carbonic acid of those eras much is now
reiuoved, and shut up in the earth in those great deposites of anthracite and bituminous
coal which occur on an extensive scale in so many parts of the world. Large quanti-
ties, also, unquestionably derived from the same source, now form an integral constitu-
ent of great coral reefs and limestone rocks, some forming mountain ranges, and some
in the sea. It can admit of little doubt that, since those times, the total quantity of
organized carbon existing on the earth's surface, and constituting the parts of plants
and animals conjointly, has been on the increase — an increase attended by a diminu-
tion of the quantity unorganized in the atmosphere. M. Dcmas has well observed,
that the original atmosphere has become divided into three parts : one which still, in
a modified form, envelops the earth on all sides, constituting its present atmosphere; a
second, represented by the aggregate of vegetables and animals now existing on the
earth's surface — for plants and animals are nothing but condensed air ; a third, envel-
oped in a fossil state in the bowels of the earth. And this tri-partitiou has been main-
ly effected by the agency of the sun. To restore things to their primordial condition,
all tbese nmst be mingled together in the gaseous form, and the forces that have been
derived from the solar rays restored back to that luminary again.

381. But an excess or a diminution of carbonic acid in the air, provided the varia-
tion is within certain limits, would not exert an exclusive control over the production
of vegetable organized molecules. Variations of temperature, as common observation
shows, exert a very great effect ; the periodicity in the seasons and processes of horti-
culture are sufficient to prove this. So well, indeed, has this been understood, that ge-
ologists, from considerations on the decline of vegetable growth, have drawn the doc-

/

/

gg THE SUN PROBABLY A PERIODIC STAR.

trine of diminution of terrestrial temperature ; a doctrine which is enforced by ar^-
ments furnished as well b_y the inorganic world.

382. But radiant heat is not the primitive force which organizes the carbon atoms,
and groups them into their various forms ; it acts a subsidiary part, the decomposition
and subsequent arrangement being directed by light. Whatever facts, therefore, ex-
ist, which prove an increased activity in vegetable growth in the early times, prove also
an increased brilliancy in the light. The occurrence of an excess of carbonic acid in
the air, or of a higher temperature, is not enough. To the light, which is the vital
agent, a greater activity must be assigned. It is thus we perceive that changes in the
interior temperature of the globe can have had only an indirect connexion with what
was thus going on on its surface. And if there have been periodic vicissitudes, if plants
have once grown with excessive luxuriance, and in short spaces of time withdrawn
large quantities of carbon from the air, this is a result which is connected not so much
with internal or external temperature as with periodic variations in the brilliancy of
light.

383. Do not, therefore, these things seem to indicate that our sun is one of those
periodic stars, the light of which undergoes secular changes ; that for a series of years
or of centuries it increases in brilliancy, and then fades away ; and that, as these peri-
ods pass over, corresponding mutations in its intensity of radiation are observed 1 That,
affected by this, the rate of vegetable growth, the character of animal life, the constitu-
tion of the atmosphere is simultaneously changed in all the attendant planets 1 It is
of no consequence to say that great and almost universal mutations, such as those we
are here describing, are not consonant to the ways of Nature ; or that, in the periods
of human history, traces of such operations have never been witnessed. No observa-
tion in philosophy is more true, than that " changes which are rare in time become
frequent in eternity."

384. But among the stars these periodic variations do take place. As was discov-
ered by Sir J. Herschel, a 0?iomy, if examined, is seen to increase in brilliancy for
several days, and then to diminish. In the same way, a Cmsiopeice has its period em-
braced in 225 days. And many other instances are known. It signifies nothing that
these periods are short. In the constitution of the universe, no value is attached to
time. With men, whose period of action is embraced in a few years, the different
events of life are circumscribed by measured spaces — there is a limit beyond which hu-
man exertion cannot go ; and to adjust time and action to each other, and to measure
the one by the other, is our common duty. But in the administration of the universe
the case is different ; in eternity there are no limits of duration, and time can be ex-
pended without detriment or loss. In the pulsation of a wave of light, a part of the
millionth of a second is enough, and it is given. In the revolution of one system of
stars round another, millions of centuries are required, and they are consumed. And
so, in the case that we are considering, the glowing and fading away of one star may be
accomplished in a few days, but inconceivably great periods of time may be wanted for
the same events to transpire in another. Even philosophers are too prone to believe,
that by the short spaces of human life, or the history of nations, they can mark out pe-

DESCRIPTION OF THE ACTION OF UGHT ON LEAVES. 57

riods in eternity ; but, whether we consider the scale of space, or of time, on which the
universe is constructed, we can see that our minds are so constituted as to be equally \
onable to appreciate either extremity ; that we can attach no just idea to what is either
infinitely great or infinitely small ; and that therefore our views do not always justly
apply in natural events. Of one thing we may rest assured, that no matter how great 1
the periods that may be required for the phenomena of the universe to transpire, there I
has been, and there will be time enough for their endless repetition.

385. From considering what takes place when a green leaf is enlightened by the
sun, we are thus allured to pass on step by step to reflections on the history of the
solar system, and to changes which have happened to the earth. In the same way
that the stem of an exogenous tree is a lasting record and memorial of the returning
summers it has witnessed, each ring that we see pointing out the growth of one season,
and being, so to speak, an index of the amount of light which has been at play ; or,
when casting our eyes over the climates of the earth, we observe in the tropics a rank
^^egetation, and trees and flowers flourishing all the year round ; or, coming to the tem-
perate zones, we find a hardier growth, and the soil only yielding its fruits to human
industry and skill ; or, passing towards the poles, the stunted plants, and hchens, and
mosses, and great plains covered with perpetual snow, and even in these inclement re-
gions all vital operations under the control of astronomical causes. Do not all these
serve to set forth the entire control which the solar rays have over these phenomena,
and teach us that the same kind of reasoning w'hich applies to things taking place in
our time, applies also to things which have preceded it ; that if the section of an ex-
ogenous stem, or the climate-distribution of plants, point out a present connexion and
present relations with the sun, so do those fossils which are dug out of tlie ground
point to similar relations in former times; their magnitude and luxuriance indicate a
more brilliant rav. From the beginning of things no natural law has ever changed ; re-
sults are obtained in these times by the same operations or mechanism by which they
were obtained of old. As with us, so then, when the sunbeam falls on a leaf the yellow
ray is absorbed, and if carbonic acid is present, it undergoes decomposition, green mat-
ter is rapidly formed, a mixture of oxygen and nitrogen gases is emitted, and carbon,
oxvgen, hydrogen, and nitrogen are fixed in the plant. The seat of this action is now,
as it was then, that face of the leaf which is exposed to the sky; and the nutritious •
juice thus formed turning over to the under face of the leaf, is there concentrated by
the evaporatory action of the stomata. From these chemical changes mechanical
forces arise, and the nutritious sap is impelled downward, or brought into relation with
all parts of the plant. From it sugar, and gum, and starch, and woody fibre, albumen,
fibrine, &c., are formed, and these are lodged in various parts, or stored up for the
farther purposes of the economy'.

386. I regard, therefore, the sunlight, when acting upon plants, as operating exactly
in the same way as the chemical rays or radiant heat, when they produce their specific
phenomena. That, first of all, a certain absorption takes place, which seems to be un-
attended with any direct effect, and of the nature of which we have only an indistinct
idea ; that when this is over, the rays continuing to act, an4 the tissue of the leaves

N

g§' DESCRIPTION OF THE ACTION OF LIGHT ON LEAVES.

being filled with water holding carbonic acid in solution, part of which acid has bees'
derived from the air, and part brought through the spongioles from the soil, decompo-
sition takes place — a decomposition accomplished under the law of the definite action
of light; tha; il the rays increase in brilliancy, the chemical result goes on with more
rapidity, and if there be a diminution, the chemical result correspondingly declines j
that this action goes forward at a maximum under the influence of the yellow ray, the
orange and the green coming next in rank, and the others following in the order of their
illuminating power; that from this circumstance, the extreme violet and extreme red
seem to possess little activity, and the tithonic rays appear to be in no manner engaged,
or engaged only in an indirect way, after the same manner as radiant heat. As fast as
carbonic acid, dissolved in the vegetable juices, is disposed of, new quantities are taked
up, some little coming with the ascending sap from the ground, but the great part being
supplied from the air; for, through the air, by diffusion, gases pass with great rapidity,
and percolate through their films of water (Ap., 80). By aerial currents, by the move-
^ ment of the leaf an extensive and continually renewed contact with new portions of
air is established ; from this the carbonic acid is taken, which is dissolved in the watery
juices circulating. Brought under the luminous influence, it undergoes decomposition,
its carbon and a portion of its oxygen being appropriated (Ap., 818), and a volume of
nitrogen equal to the volume of oxygen thus appropriated, evolved along with the remain-
ing oxygen. There is, therefore, a removal of water and carbonic acid from the air; a fixa-
tion of carbon, hydrogen, oxygen, and nitrogen in the plant, and an evolution to the
air of nitrogen and oxygen. From the constant appearance of the former of these
bodies, we are led to suspect that the light acts primarily on some azotized body, the
destruction or eremacansis of which is essential to the total action (A p., 824); while
all this is going on, chlorophyl is abundantly formed, and so long as the process is ac-
complished, the leaves retain their green colour.

387. On several occasions it has been said, that th ' phenomenon here described an-
swers to a true digestive, and not to a respiratory process ; the older chemists and bot-
anists confounded it with the latter function ; but it is obvious that it does not answer
to respiration, either in mode of operation or in result. Respiration is an oxydizing
process, the object of which is to maintain the animal machine at a fixed thermomet-
ric point — a result which implies direct combustion or burning; an animal, rigorously
speaking, burns carbon like a locomotive engine. But in this action, on the contrary,
carbon is reduced from carbonic acid, and there should be a descent of temperature in-
stead of an elevation, a large amount of heat being absorbed — heat which is furnished,
under natural circumstances, by the sun, along with his light. The continued supply
of heat in this way prevents us from discovering that reduction of temperature which
should befall the leaf; and, besides this, it is exposing to the open atmosphere its broad
surface, and any thermometric disturbance is at once compensated by external agen-
cies. It is possible, indeed, that the decomposing process could not go on, save under
the conjoint presence of heat and light, though the specific function which each of
these agents discharge may be different. The action of leaves in the sunshine bears,
therefore, no sort of analogy, either in manner or in result, to the respiratory processes

NERVOUS AGENT OF PLANTS. 9g

of animals, no matter whether the mechanism be the hmgs of a mammalian or the
branchial organs of fishes. Every variety of breathing apparatus has for its object the
evolution of heat by the oxidation of carbon, or of carbon and hydrogen conjointly ;
but the object of the agency of leaves upon the air is to obtain from it carbon, or car-
bon and hydrogen. At certain periods of their history, plants themselves become ma-
chines of combustiou, when the process of fertilization requires that for a time, in a
given place, and for a specific object, there should be an elevation of temperature. Re-
sort is then had to those same processes w hich obtain in animal systems ; and sugar,
or what comes to the same thing, honey, is burned.

CHAPTER Xn.

ON THE NERVODS AGENT OF PLANTS.

Contents : Subdivisions of Nervous Mechanism in Animals. — Excessive Rapidity of
Motion arising in these Nervous Actions. — Plants constructed on a Surface-type. — Ox-
idatins Processes replaced in them by the Application of Radiant Heat. — Difference of
Action on the Upper and Under Face of the Leaf — Light applied to one, and Heat to
the other Face. — Specific Effects produced by the different-coloured Rays. — Effects of
these Radiant Principles on the Lower Tribes of Aninuds. — Centralization of Appa~
ratus for different Functiotts. — Analogies between Nervous Action in Animals and
Imponderable Agency in Plants. — Vegetables are the Representatives of the Resultant
Action of the Ethereal Agents on Ponderable Matter. — Conclusion.

388. It was the beautiful discoveries of Sir C. Bell which first forcibly drew the
attention of physiologists to the fact that diiFerent portions of the nervous system are
devoted to dififerent functions ; that in the spinal axb there is one column devoted to
sensation, and another to motion. This division of offices is doubtless carried to a far
greater extent than we have at present any means of proving. Analogy would lead us
to suppose that every function is represented by its own appropriate mechanism. It
is not alone in the great and more striking characteristic divisions of action that these
divisions of machinery are observed ; the cerebrum, the cerebellum, or the sympathetic
system, being each devoted to its specific end, they doubtless, also, exist on a far more
minute scale, in connexion with more trivial purposes.

389. If, thus, the intellectual processes and processes of movement, which are things
appertaining to the interior constitution of tlie animal system, are under the control of
a divided agency, a similar plan is resorted to in the case of those functions which put
the system in relation and communication with the exterior world. On these, the out-
ward physical agents have to expend their operation. The optic nerve, which gath-
ers on its retinal expansion the images of outward forms, transmits them to the brain.
To that cerebral tract to which it goes, the power is given to be affected by luminous

J

j^Qq excessive rapidity of motions arising

agency ; it is immaterial whether that agency consist of undulations of an ethereal me-
dium, or spend itself in producing a chemical change of the retina. The porfio mollis
of the seventh pair, also, exposes itself in the cochlea of the ear, and having the func-
tion of audition committed to it, vibrates correspondingly to those oscillatory move-
ments in the atmosphere which constitute sound. So, too, with the olfactory nerve,
which, pushing its way through the cribriform plate of the ethmoid bone, expands in a
million of ramified branches on the Schniderian membrane, and is ready to be impress-
ed by odours or smells. There is no such thing as a mutual convertibility of the offi-
ces of these different machines ; no vicarious interchange of action ; each one has its
own duty to perform, each has to discharge its proper task, and the construction of
each is suitably arranged. In human contrivances, the same necessity of result arises ;
the telescope will not answer for a piano, nor the piano for a telescope.

390. While thus the different senses of sight, of smell, of hearing, of taste, and of touch,
and all the different functions which occur in animal frames, are carried on by their own
appropriate enginery, and resort had to optic, auditory, olfactory, and respiratory cords,
these several contrivances are so arranged that the final result of their operation con-
verges inward, and is at last expended on the same point from which also spring all
the various acts of thought and intellectuality. Of that central point which is thus in
incessant agitation during the continuance of animal life, perpetually receiving impres-
sions from outward objects or the external world, perpetually, also, reflecting back
again the various determinations of the mind, how rapid and how constant must be the
movement ! We cannot comprehend how it is possible that an ethereal particle, vibra-
ting so as to produce violet light, oscillates backward and forward seven hundred and
twenty-seven millions of times in the millionth part of a second ; yet this is a fact as
well established as any other fact in the domain of science. What, then, shall we say
of that central point of reception which is within the brain, which stands ready to ex-
ecute at once all the synchronous movements impressed upon it by the various colours
of light, all the vibrations of simultaneously occurring and harmonious sounds, all the
impressions which are brought to it by the apparatus of the senses ! During the time
of wakefulness, how is it agitated by these various movements ! and during the time
of sleep, its activity is still expressed by those phantoms which we see in dreams. As,
at a telegraphic station, the observer watches the various signals through his telescope,
and reports to his government the intelHgence which is arriving, so that central vibra-
ting point reports to the mind the telegraphic despatches that are coming along the dif-
ferent nerves. Nor is it impossible that one material atom, or even a small congeries
of atoms, should be able to be thus affected at once in a thousand different ways ; a
particle of water on the surface of the ocean may be simultaneously affected by mill-
ions of waves, which may go forth from it and separate without disturbing the move-
ments of each other ; a particle of ether may be acted upon by every possible ray of
light that can reach it — it will be affected by the general action of all, and each one
will go forth and separate from all the others, undisturbed by, and undisturbing them.
But even were it not a single physical point — a physical point in our ordinary idea of
that term — even were it the whftle Irrain which is thus agitated and acted on, what but

PLANTS CONSTRUCTED ON A SURFACE TiTE. JOJ

a point in comparison with the world from which it gathers its intelligence, is the whole
mass of the brain ! Is it not affected by light which has come from systems of suns at
the uttermost ends of the universe t Does it not watch the rotation of double stars of
different colours, which occupy enormous periods of time to complete their revolutions,
and are situated M almost immeasurable distances!

391 Nenous action in animals is thus carried on by a complicated mechanism, and
the nervous agent, though ordinarily spoken of as "one and indivisible," presents itself
to oar view as the reunion of many forces, or as one force with many modifications.
To the immaterial and responsible principle which is within us, it stands in the char-
acter of a minister and messenger, to connect it with the outward natural world, to
gather impressions and enable it to react on material things. Hence arises that sub-
division of functions of which we have been speaking, a subdivision not only affecting
external impressions, but also the corresponding individual actions. The nervous and
optical mechanism of the eye is so arranged as to have entire charge over the recep-
tion of impressions conveyed by the luminiferous ether ; the auditory mechanism of the
ear is constituted so as to receive undulations of gaseous bodies like atmospheric air;
and, correspondingly, if intelligence has to be communicated to a distance, and received
by other minds through the agency of a visual organ, the motor nerves of the hand are
put in action, the fingers move, and letters appear upon the paper.

392. In steam-engines or other automatic machines, our admiration is chiefly aroused
by the regular and consentaneous manner in which their movements are performed.
At the proper instant the proper valves are sprung, and the intricate motions go on
with regularity. No one can have seen a large cotton or silk factory in which the
machinery is driven by one of these engines without being struck with this remark.
Perhaps it is weaving an elaborate pattern, and, with a discretion that almost simulates
intelligence, is putting in or leaving out the variously-coloured threads. To produce
this, a series of contrivances is made to intervene between the point of action and the
motive force, and accordingly as the result is different, so must that inter\ening mech-
anism vary. In animal systems, the same observation holds good : impressions which
come to us from the external world, and movements which result from mental opera-
tions, are all transmitted by their proper channels.

393. From the lime of Aristotle, it has been observed that the type on which vege-
tables have been constructed bears a remarkable relation to the type of animals. In
the latter all the processes of organic life, such as digestion, respiration, secretion, are
carried forward in interior cavities ; in the former they are surface actions. Thus, the
stomach, the digestive organ, is enclosed in an interior space, but the leaf, which is the
analogous organ for plants, is freely exposed, and digestion takes place upon the sur-
face. So, too, with respiration, the lungs of the mammalia are placed within the walls
of the chest, and receiving oxygen from the air, transmit it by the arterial blood to the
capillary vessels, in which the combustion of carbon is going on; but when in plants
the same result is to be attained, oxydation takes place on the petals of the corolla,
which is another surface action. In animals the attempt is to centralize everything,
to make all the functions subservient to the perfect development of one focal point, to

■i()2 OXYDATING PROCESSES REPLACED BY RADIANT HEAT,

which all the nerves of sensation go, and from which all volitions and motions arise.
In plants, the attempt is to diffuse everything, to have no centre of action, but to exe-
cute upon the periphery. It is true that the lower order of animals are constructed
on this lype of diffusion, and it is interesting to see, when in more advanced tribes the
attempt at centralization begins, how rapidly it goes on to perfect development. The
appearance of an isolated organ of digestion — a stomach — is the signal of an isolated
organ of circulation — a heart — no matter though that heart may be a mere tube, as the
dorsal vessel of many insects.

394. If thus, in animal existence, we find the various nervous machines divided off,
and the impressions of light, of sound, of taste, committed to separate apparatus, how
is it with plants 1 The rays of the sun are the true nervous principle of plants ! And
herein we see how closely the type of surface action is observed. On all sides the
leaves present their thin lamina to the light, and offer a broad surface to the sky. On
these the rays fall, and direct the digestive and other processes. When they are car-
ried on in interior cavities, and the living system assumes a certain mass, an oxydating
machine is demanded in order to keep up the temperature of the whole by the burn-
ing of carbon, and lungs, or gills, or other suitable contrivances, are resorted to. But
the principle on which the vegetable organization is constructed is simple, and except
on those particular occasions to which reference has been made (387), an apparatus
of combustion is not wanted. For with the rays of light which come from the sun
there are also rays of heat, and these impinging on the outside surface, which is the
seat of all the vegetable activity, are absorbed, and bring up the temperature to the re-
quired point. What need is there for the burning of carbon or of hydrogen, when on
all sides radiant heat is pouring in ? Nature, with a provident care, has in all ordinary
leaves provided abundantly for this elevation of temperature, and when the direct beams
do not reach them, warm currents of air that rise from the heated ground are every-
where present.

395. In a chemical point of view, it is the quality of light to produce the organiza-
tion of molecules, that is, to determine the positions of atoms as respects each other;
it is the quality of heat to determine their distances ; for the accumulation of caloric
in a body produces an expansion, a diminution of it a contraction. Light and heat,
therefore, have totally different offices to discharge, and the seats of their respective
actions are in most instances distinct. In horizontal leaves it is chiefly on the upper
face that light acts ; this, looking towards the sky, is ready to receive rays coming from
every part; it is on the under face that heat operates, directing in a great measure
through the stomata the evaporation of water. An advantage for these latter organs
is, therefore, gained. Exposed to the direct solar radiations, they would be under con-
ditions of perpetual disturbance, every cloud which passed over the sun would keep
them in a constant agitation, and interfere with their regularity of action. One of the
most prominent differences between light and heat is in their mode of propagation through
bodies; the force of the former is expended on the point upon which it falls; there is
nothing after the manner of conduction or lateral propagation; it is also the same with
the tithonic rays (Ap., 608). For this reason, when an image falls on a sensitive plate

DIKFEKENCE OF ACTION ON THE UPPER AND UNDER FACE. JOJ

id the camera obscura, a photogenic copy is obtained, every line being represented with
mathematical accuracy and the utmost sharpness; the radiation, having impinged upon
the plate, does not spread itself out laterally or undergo a process of conduction, but
only produces its effect on the portions which lie directly in the lines of light. With
radiant heat it is very different: a beam of this agent falling upon a Hmited portion of
a metallic plate, slowly affects all the rest, for the resulting rise of temperature is propa-
gated laterally from point to point, and by-and-by the whole mass undergoes an elevation.
While light and the tithonic rays, therefore, are not Hable to conduction, the reverse
holds in the case of heat. Applying these reasons to the instance before us, the rays
of light which control the digestive operation could only act in an imperfect way on
the under side of a horizontal leaf; they must produce their maximum effect on the
surface exposed, and operate elsewhere through imperfect translucency, finding their
way through short distances, because the tissues are not perfectly opaque. But the rays
of heat, which, with the Ught, fall on the upper face, are conducted with facility, or
transfused by warming the watery juices which are circulating through the organ.
Whatever changes, therefore, take place abruptly in the quantity of the incident rays,
as when clouds are suddenly crossing the sun, are not abruptly fell upon the stomata,
for the leaf, thin as it is, acts as a regulator, and, from the heat which it contains, sup-
phes the momentary defect ; the ascending sap also, which is coming through the pet-
iole, is coming at an elevated temperature, for, in the course of its ascent from the roots, it
has been warmed in its passage through the stem which is enveloped in its dark-colour-
ed bark — a colour well adapted to receive the effects of the rays of heat. There is,
therefore, a reason why the stomata are secreted in the shade, and why the seat of the
digestive action lies on the upper face of the leaf.
<k 396. Besides these well-marked differences of action produced by the rays of light
and of heat conjointly in the sunbeam, there are specific effects produced by the vari-
ous coloured rays; thus, the yellow seems to control digestion, and, as Dr. Gardner
has proved {Phil. Mag., Jan., 1844), the blue ray motion. Investigations of the dif-
ferent effects produced by the other rays of light, such as the green, the violet, the red,
or by those other principles which are invisible ; the phosphoric or the tithonic rays
can scarcely yet be said to have been made. Each of these comprises rays differing in
constitution, and differing in refrangibility, and, doubtless, to each one specific effects
are due ; thus, it appears from the experiments of Daguerre and Neipce, that the
tithonic rays have the quality of changing the constitution of resinous bodies. There
is, indeed, scarcely one of the productions of vegetable life which is not characterized
by the facility with which it undergoes mutations under the influence of these princi-
ples; thus, wax, which is yellow, bleaches rapidly; chlorophyl, which is green, turns gray;
the volatile oils harden, as is often observed; the oil of oranges turns red; guiacum, from
a yellowish brown, turns green or blue ; the colouring principle of most petals is destroy-
ed ; for example, the beautiful red of carthamus, and the purple of violets, is rapidly
bleached ; woody fibre also undergoes a disintegration, and, indeed, there is scarcely a
vegetable product on which some one of the various radiations does not leave a specific
impression. The extensive series of experiments made by Sir J. Herschel on the

^(f^ CENTRALIZATION OF NERVOUS APPARATUS.

action of light on different vegetable colours serves to prove that there is scarcely a ray-
which is not implicated in these processes; sometimes it is the red, sometimes the yel-
low, sometimes the blue. So, too, with rays differing specifically, the rays of heat of
different refrangibilities, and the tithonic rays.

397. In the lower orders of animal life, the controlling influence of the same agents
which are thus so active in the vegetable world is well marked; the movements of the
polygastric infusorials are well known to be directed, to a certain extent, by light.
There seems to be a diffused sensibility to that agent possessed by the entire surface
of these beings. Comparative anatomists have traced how, from this, which is the ob-
scurest development of specific nervous action, the nervous material begins to be col-
lected in centres, and locomotive or respiratory ganglia make their appearance. In the
case of insects, the metamorphoses of which are open to our inspection, as they pass
successively through the larva and pupa states, and finally reach their imago, or per-
fect condition, so far as the nervous system is concerned, all the transitions tend to a
concentration ; the development of a new instinct, or the production of increased loco-
motive power, is at once expressed by changes in the magnitude or position of the ner-
vous gangHons, or their connecting cords. It is true, that as soon as this concentra-
tion appears, it brings with it new qualities, and, in the more elevated orders of life, one
of the great functions of the nervous system seems to be the establishing of sympathetic
connexions between organs which are carrying on processes that are essentially differ-
ent ; between the digestive, the respiratory, the secreting apparatus. Among plants,
this high state of centralized organization is not required; the sap, driven, as we have
seen, by mere mechanical forces, makes its way from the spongioles to the leaves, and
then commences its descent. This circulatory movement is the only bond of union
between the various parts of a vegetable system. For this reason, therefore, botanists
are fully justified in their assertion, that a tree is not a simple individual, but rather a
colony of individuals. It possesses no interior nervous system, the office of which is
to bring into connexion parts that are distant, because the type upon which it is con-
structed requires no such machinery.

398. But there are considerations which enable us to trace analogies between the
mode of action of the nervous principle, even in the most elaborate forms, with thos§
more obscure, which belong to the vegetable world. As has been fully proved by phys-
iologists, all the nerves of special sensation take their origin amid the minute ramifica-
tions of bloodvessels ; and it is the changes which occur in the circulating fluid which
impress a specific action on the nervous terminations — an action at once transmitted to
the centres, and there disposed of Thus, by the heart, venous blood, from which the
elements of carbonic acid have to be expelled, is thrown into the minute ramification
of the pulmonary artery, and there, coming in contact with the terminal fibres of the
pa?- vagufn, it impresses upon them an influence — an influence which is in an instant
propagated to the respiratory nervous centres, and there is expended in producing a
reflex effect. Through the proper nervous channels, the diaphragm, the intercostals,
and the various muscles engaged in respiration, are put in action ; the capacity of the
chest increases ; a few cubic inches of atmospheric air enter the trachea, and fill the

ANALOGIES BETWEEN NERVOUS AND IMPONDERABLE ACTION. 205

larger bronchial rubes. In an instant, by diffasion (Ap., 50), the oxygen of this air leaves
its nitrogen, which in these circumstances is a more slowly-diffusing gas, finds its w ay
to the minutest air-cells, passes in an instant (Ap., 53) through the thin vascular coats,
interchauo^es with carbonic acid, and the act of arterialization is complete. The arte-
rialization of the blood is, therefore, notbing more than an ordinary chemical process,
and the nervous agency which has been brought into action is for no other end tban
the production of a mechanical effect ; for, though the act of respiration is eventually
carried on under the operation of chemical laws, mechanical movements have to pre-
cede. A division of those nerves puts an end to the process, not because respiration
is the result of a vital, a nervous, or any other such agency, but simply because the
necessarv movements which end in the introduction of oxygen gas can no longer be
accompHshed.

399. Now let us tarn to the vegetable kingdom. As long as the sun is above the
horizon, his beams, impinging upon everything, occasion an elevation of temperature.
The various objects exposed — the leaves of trees, the grass, and the surface of the
ground — become warm. Participating in this elevation of temperature, the atmo-
spheric air has its capacity for vapour increased, and that transpiration of steam which
is copiously going forward from the exposed vegetable surfaces, from the soil, and
from water, raises the dew point. But on the going down of the sun, and even before
the close of dav, a reverse action begins to be established. Radiation into space is ac-
complished, the temperature of the ground and of the leaves begins to fall, and by-and-
by the dew point is reached, and now drops of water form on those organs, and under
its influence they begin to recover the parching effect of the preceding day. The re-
duction of the atmospheric temperature down towards the dew point, thus brought
about by the conjoint agency of the ground and the exposed parts of plants, in an in-
stant puts a check upon evaporation from the leaves ; this, in its turn, reacts upon the
ascent of the sap ; it is like putting the cover over the burner of a spirit lamp; evapo-
ration from the reservoir is stopped, and simultaneously, also, the current along the cap-
illary fibres of cotton is checked. ^Vith this check upon the ascent of the sap, that
store of carbonic acid gas which exists in the soil, and which arises from the decay of
humus, or from artificial manures, is also presened ; carbonic acid which, during the
day, comes up to the leaves«»vith the circulating juice, and is decomposed by solar hght.
But, now, if a cloud intervenes, Or the sky at night be uniformly obscured, no radiation
can be accomplished, no reduction of temperature takes place, the dew point is never
reached, and evaporation goes on from the leaves, and carbonic acid gas, drawn up
from the spongioles, is expended. The reflex action of that radiant heat which came
from the sun during the day is cut off, its passage outward into the regions of space
arrested, and the dependant physiological phenomena cease to be performed. There
is ah analog}' of effect between the temporary action of an overhanging canopy of
clouds at night on the vegetable world, and the permanent injury which results to an
animal when the par vagum, one of the offices of which is, at proper moments, to in-
troduce a measured quantity of oxygen gas into the system, is divided.

400. Where, then, do these things carry our reflections I What are the elevated

6

2Qg PLANTS ARE THE RESULTANT OF IMPONDERABLE ACTION.

ideas they bring before us 1 Do they not show that the great spaces of the universe
are not empty solitudes, in which there only reside mechanical forces, in which only
the influences of gravitation and projectile action occur? Do they not teach us, that
wherever a ray of light can pass, there is the capability for organization and life ? And
of those innumerable stars which we see at night, some of which are giving forth rays
of one, and some of another colour, and a multitude of double stars, which furnish com-
plementary lights to their attendant planets, who can tell what multiplied results these
things impress on the world of organization ? In our reflections on the constitution
of the universe, though the beautiful perfection of its mechanism may excite our won-
der, do not these views of its capability for organization, of the constant presence of
light, the parent of life, call for our unbounded admiration ? Instead of regarding the
interplanetary spaces as a great vacuum, a desolate solitude, they rise before us as re-
gions filled with active forces, and ready to put on or to communicate movement and life.

401. Mental volitions are executed by muscular movements arising from the passage
of some agent along the nerves, an agent which does not require any perceptible time
for its transit, but, within the spaces which Ave have under consideration, seems to act
instantaneously — a volition originates, and contemporaneously a motion is accomplish-
ed. The speed with whicli the different radiant principles are propagated through the
ether, rivals the speed of nervous movement ; spaces such as those which we ordinarily
have to do with are passed over in an inconceivably short period of time.

402. It is not without abundant reason that we are thus led to describe the solar
radiation as discharging the part of a vegetable nervous agent, which simulates, in many
of its operations, the nervous principle of animals. Out of a limited number of ponder-
able substances, such as carbon, hydrogen, nitrogen, oxygen, and a few others, all kinds
of organized structures are formed, but then there is an extensive machinery to collate
and group together these different bodies. Light, in itself, can produce as many different
effects as there are possible combinations of colour, for each one of its rays has pecu-
liar powers of its own, and it is also attended by other invisible and imponderable prin-
ciples which have their modes of action. An organized structure of a given kind is,
therefore, the result of the operation of many of these forces, and is an expression of
their aggregate action. In the full development of a perfect tree there has been ex-
pended a measured quantity of forces, of light, or of heat, and the organized mass, as it
stands before us, the product of those forces, is the restiltant of millions of vibrations of
the luminiferous ether which have acted upon ponderable atoms ; vibrations which have
stood in a certain relation to each other, as the symmetry of the vegetable parts indi-
cates. In the operations of hunian agency, something of the same, though of a grosser
kind, may be seen. We have not, it is true, the power of calling into existence, or of
determining in an enduring shape, or of giving an imbodied form to material atoms;
but in the same manner that Nature, operating through ethereal undulations, creates the
various forms of vegetable life, there has been committed to us a similar control over
those grosser undulations which move in the atmospheric air. The imagination, the
genius of the great masters of music, have already grouped together combinations of
these waves, which are destined to an earthly immortality ; combinations which, when

PLANTS ARE THE RESULTANTS OF IMPONDERABLE ACTION. 107

once heard, leave their indelible impression oh the memory, and are to as an imbodi-
ment of symmetry and harmony. These ideal creations, which exist only for the mind,
are analogous, in very many points of view, to those more tangible creations which are
formed by ethereal waves, and which Nature has reserved in her own hands. The
symmetrical or beautiful forms which are transmitted to the brain by the eye, appeal at
last, to that same, that common principle, which receives melodious or harmonious
sounds transmitted by the ear ; and the creations of human genius, whether they be ex-
pressed in the language of music or of painting, whether they are heard in the cathe-
dral, or seen in the canvass of Claude Lorraine, give us pleasure, because their final
impression is made on a mathematical organ which is so constructed as to appreciate
whatever is symmetrical in position, whatever is graceful in figure, whatever is harmo-
nious in movement

403. From this point of view, therefore, I look upon the vegetable world as an im-
bodiment of the action of ethereal agents. A tree, when covered with blossoms in
spring, or loaded with fruit in autumn, is a resultant of the play of those active forces
which have been emitted by the sun, an expression of what has been done b>- vibratory
movements operating on ponderable molecules. As soon as the young plant has put
its ascending axis above the ground and exposed itself to the solar beam, growth rap-
idly begins to take place, and organized matter to be condensed from the air ; and now
a green colour is developed, and the stem elongates, and leaves are put forth. At the
proper epoch the reproductive organs are evolved and flowers appear, and by the end
of its annual period the plant has laid up a store of nutritive matter for the ensuing
spring, or, if such be its habit, has provided for the germs it has called into existence.
In carrnng forward all those multiplied operations which have ended in these events,
its leaves and its stem have gone npward in search of the light — light which has sym-
metrically arranged their parts and furnished their substance. But these general views
are far from giving us an accurate idea of the forces which have been expended, or
the motions which have been executed in producing the result we contemplate. An
exogenous forest tree, from its magnitude, risiug, perhaps, a hundred feet above the
ground, and spreading its branches over hundreds of square yards, may impress us with a
sense of sublimity ; a section of its stem might assure us that it had lived for a thousand
years, and its total weight could only be expressed by tons. An object like this mav,
indeed, call forth our admiration, but that admiration is expanded into astonishment
when we come to consider minutely the circumstances which have been involved in
producing the result. If we conceive a single second of time — the beat of a pendu-
lum— divided ofl' into a million of equal parts, and each one of these inconceivably
brief periods divided again into a million of other equal parts, a wave of yellow light
during one of these last small intervals has vibrated five hundred and thirty-five times.
And now that yellow light is the agent which has been mainly involved in building up
the parts of the tree, in fabricating its various structures, and during every one of a
thousand summers, from sunrise to sunset, the busy ravs have been carrving on their
operation — who, then, can conceive, when, in the billionth of a second, such enormous
numbers of movements are accomplished, how many have been spent in erecting an

108 CONCLUSION.

aged forest oak ! Who also can conceive the total amount of force employed from
century to century in arranging the vegetation of the surface of the globe !

404. I therefore regard a planetary body like the earth, in its orbitual revolution
round the sun, as a predetermined focal centre on which the emanations of that s|ar
shall be expended; first, in producing vegetable organization, and, finally, in lending their
aid to the evolution of animal intellect. The forces which Newton revealed as urging
such a body forward, or causing it to glide in its elliptic path, appear only as an incidental,
though essential part of the mechanism of the universe, the interest of which disap-
pears in that higher interest which must attach to whatever stands in intimate connex-
ion with. organization and vitality. Those many-coloured luminous wavelets which
are ceaselessly crossing the interplanetary spaces, go forward on an appointed errand,
and sooner or later discharge their final task; nor are the planets in the solar system a
colony of opaque globes, rotating, without purpose or end, around the central attractive
mass. The solar system is an orb of movement and light, full of vibrations of every
tint visible and invisible, and which here and there envelops and enshrouds revolving
points of organization and life.

GENERAL APPENDIX,

CONTAINING THE

EXPERIMENTAL DOCUMENTS.

EXPERIMENTS, &c.

CHAPTER I.

EXPERIMENTS MADE TO DETERMINE WHETHER LIGHT EXHIBITS ANY MAGNETIC ACTION.

(From the JounuU of the FratJUin InstiluU for Febnary, 1835.)

Contexts: Character of the Sky in Virginia. — Examination of Mr. Christie's Ex-
•periment. — Needles not affected hy the Violet Rays. — No Reaction between a Magnet
or Voltaic Currents and Light.

1. " The more refrangible rays of light are said to possess the property of rendering
iron and steel magnetic. The existence of this property was first asserted by Dr. Mo-
richiui, of Rome. Other observers subsequently failed in obtaining the same results ;
but in the year 1825, the fact appeared to be decisively established by the learned and
accomplished Mrs. Souierville, iu an essay pubhshed in the Transactions of the Royal
Society. In her experiments, sewing needles were rendered magnetic by exposure for
two hours to the violet ray, and the magnetic virtue was communicated in still shorter
time when the violet rays were concentrated by means of a lens. The indigo rays were
found to possess a magnetizing power almost to the same extent as the violet, and it
was observed, though in a less degree, in the blue and green rays. It is wanting in the
yellow, orange, and red. Needles were Ukewise rendered magnetic by the sun's rays
transmitted through green and blue glass. These results have been verified by M. Zan-
tedeschi, of Pavia {Bibl. Univ. for May, 1829), but their accuracy has been doubted by
Messrs. Riess and Moser, who consider that the means employed by Mrs. Somerville
for ascertaining the magnetic state of the needles were not sufficiently exact They
found the oscillation of needles to be wholly unaffected by exposure to the prismatic
colours. (Brewster's Journal, ii., p. 225, N. S.) This must still be regarded, therefore,
as one of the disputed points in science." — (^Turner?)

2. It has been supposed that this disparity of results arose entirely from local circum-
stances. A hazy atmosphere, such as is met with in the northern and middle countries
of Europe, might perhaps influence, in some manner, this peculiar property of light, when
the clearer sky of Italy allowed an opportunity of making the experiment Some, in-
deed, have thought that the observers, who were said to have verified the original re-
sults of the Italian philosopher, were themselves deceived in not having previousl}' as-
certained the magnetic state of the needles they used. That mistakes of this and a
similar kind are easily made, will appear in the course of this communication.

3. During the past summer, I have attempted to satisfy myself whether the more re-
frangible rays really exert any magnetic influence ; and happening to reside in the south

4 CHARACTER OF THE SKY IN VIRGINIA.

of Virginia, upon the same parallel of latitude as Tunis and the more northerly African
kini^doms I thought the situation too favourable to suffer such an opportunity to pass
without endeavouring to gain some decisive information on this contested point.

4. The sky of that part of Virginia is not, however, so bright as might be expected.
When unclouded, it is of a clearer blue than the sky of England, and, I think, rather
darker, approaching, by several shades, nearer to the tint of Prussian blue than that
azure colour which it has in the latter country. During a residence of twelve months,
1 saw it twice of that intense complexion which they say it has in the tropical regions.
The moon appeared globose, and her centre to bulge out like a ball, and the planet
Venus might be fancied to exhibit a well-formed crescent. The air passes from great
moisture to dryness with rapidity ; a good barometer is seldom at rest. The tempera-
ture of the sunbeam is sometimes 132 F., but the siphon barometer seldom varies more
than one inch. Clouds form and rise with great rapidity, the seasons are uncertain,
and the atmosphere is often deformed with a mistiness that obscures distinct vision.
But the dense clouds that gather in the west of an evening emulate the beauty of a
sunset on the Atlantic Ocean.

5. I am thus particular in describing the state of the atmosphere in which these ex-
periments were made, because much stress has been laid upon that circumstance, as ma-
terially affecting the results of magnetic action of the solar ray. And, as the experiments
now to be detailed lead to a negative decision, it is well to explain under what circum-
stances they were performed, that those who have come to an opposite conclusion may
have an opportunity of pointing out whether it is really owing to the state of the atmo-
sphere.

6. In the year 1824, Mr. Christie found that a needle six inches long, contained in
a brass compass box with a glass cover, suspended by a hair, and made to vibrate, al-
ternately shaded and exposed to the sun, came to rest much sooner in the latter than
in the former case. That this was not occasioned by an increase of temperature, was
proved by the needle vibrating more rapidly when its temperature was raised by other
means.

7. In repeating this experiment, I very quickly found that it depended, in a great
measure, on the nature of the suspension of the needle, and its position with respect to
the incident light, what results would be obtained. If the needle was suspended on a
point or by a thread, without torsion, both the time and the number of vibrations were
the same, whether the needle was exposed to the sunbeam or not. But, if the needle
was suspended by a hair or other organic substance, having torsion, the sunbeam would
occasion a degree of twist in the hair on its first exposure to light ;*and if the direc-
tion of that twist happened to coincide with the direction of the needle's motion, of
course the momentum of the needle was increased, and the vibrations continued longer.
A needle which vibrated forty-four times in one minute, would occasionally, owing to
this cause, vibrate nearly forty-six when suspended by a hair ; but if by a silk fibre, its
vibrations were always forty-four, the first arc of vibration being in every instance 40°.
That this action was due to a twist of the hair, as a hygrometric body, I ascertained
by means of a simple arrangement. To a brass cross-piece, A {fig- 1, pi- 1), supported

EXAMINATION OF MR. CHRISTIE'S EXPERIMENT. ^

on a Stand by two pillars, B C, a hair, t, was fastened, about the point A ; its other
extremity, g, being fastened to a whalebone spring, D, by a thread,/; the extremity, ^,
of the hair, beios; bent by the knot on one side, served as an index. On exposing the
instrument to the sunbeam, the Uttle inde.x, g, immediately moved, sometimes more than
a semicircle.

8. Thiukins to obtain more decisive effects, I concentrated the sunbeam with a lens
on the south pole of the suspended needle, and found that the needle was thrown into
a rapid, tremulous motion. But here the hot air ascending from the needle, acts upon
it as upon the sail of a windmill ; and the same effect ought to take place, to a certain
extent, on simple exposure of the half of a vibrating needle to direct light But I found
that a needle suspended in the vacuum of an air-pump by a thread without torsion, is
in no way affected by exposure to solar light.

' lAcfaes.

1 V\\ sewing needle

2 2 blue spring
• do.

No. of ribraticns in shade.

44

In tbe Eunbeun.

44

32
26

Therm in the sun. 109 to 105.— Barnin. 29.3 —Duration of Exp .60

I

9. It is said expressly in the account of Christie's experiment, that the needle was
contained in a brass compass box. It might have been that electrical currents were
excited in that box, which was the cause of the derangement in question ; I therefore
vibrated a needle, under similar circumstances, with the same result as above stated. I
should mention that this was done in a solid cylinder or ring of brass, without any seam
or soldered Junction ; but as compass boxes are generally made of sheet brass, with a
soldered seam in the side, it was barely possible that the fine line of solder acted with the
brass, as a thermo-electric couple, capable of excitation by the warmth of the sunbeam.
I therefore made a compound cylinder of copper and zinc, c z {Jig. '2, pi. 1), the edges
of which, at a and b, were neatly soldered, the junction b being highly polished, and that
at a blackened. The needle was suspended in an exhausted receiver, by a silk fibre, g,
and a ray of light, c d, coming from an aperture half an inch wide in the shutter, fell
upon the junction. The needle used in this experiment was of watch-spring ; its first
vibration was performed in an arc of forty degrees, and when the compound cyhnder was
taken away, it made thirty-two vibrations in sixty seconds in vacuo. On placing it
concentrically with the compound cylinder, and suffering the ray to impinge on the
polished junction the moment that the arc of vibration had become forty degrees, the
number of oscillations in one minute was carefully observed; six experiments gave sev-
erally the number thirty-two. On turning the blackened junction to the light, the re-
sult was still thirty-two ; and on substituting the solid brass cyhnder, three consecutive
trials gave thirty-two. The thermometer stood in the sunbeam at 103 ; the barometer
at 28.8.

] 0. By some this magnetic action of light has been attributed to the violet or more
refrangible rays only. A needle made of watch spring, about four inches long, which,
in an exhausted receiver, suspended by a filament of silk, exhibited no polarity, had one
half of it exposed to the violet ray, cast by an equi-angular prism of flint glass. This ray

6 NO REACTION BETWEEN A MAGNET OR VOLTAIC CURRENTS AND LIGHT.

was separated from the others by passing through a sUt in a metaUic screen, and half
the needle shielded from its action by a piece of paper. After two hours' exposure to
the sun, it was suspended again in the exhausted receiver, but still showed no token of
polarity ; it was then exposed to the other rays successively, with the same result. The
needle was now slightly touched, and, slowly vibrating, arranged itself along the mag-
netic meridian. The first vibration was performed in a semicircular arc, and the num-
ber of vibrations performed during one hundred oscillations of a seconds' pendulum was
twenty-seven. But, after four hours' exposure to the violet ray, as before, no evidence
of any change, either increasing or diminishing the number of oscillations, could be
gained. A column of violet light, passing through a disk of stained glass, was con-
centrated on one end of a sewing needle by means of a lens, without producing any
change in the number of vibrations it made in one minute. This needle, on some oc-
casions, however, would give unequal results ; when its first vibration was performed
in a semicircle, the number varied from forty-one to forty-three in sixty seconds. Ou
vibrating it in vacuo, its results uniformly gave the latter number very nearly.

11. The position of the needle to the incident ray is not of any consequence, whether
it receives it obliquely in the direction of the light or across it. If soft iron be substi-
tuted for steel, the results are still negative, even if the needle be arranged in the mag-
netic meridian, the line of dip, or any other position. I therefore come to the conclu-
sion that the violet ray, as developed by a prism of English flint glass, possesses no in-
fluence on the magnetic needle, and all the other rays are equally inert.

12. But, as Mrs. Somerville found that a needle placed under a piece of glass or blue
riband, having half its length protected by paper, became, in a short time, magnetic, I
tried the same experiment, but, in every instance, failed in making the needle magnetic.
When suspended by a silk fibre in vacuo, needles showed no disposition to arrange
themselves in any particular line, and when they came to rest, they were found cutting
the magnetic meridian at every angle, although the temperature of the sunbeam to which
they had been exposed on one occasion was 124° F. Great care was taken to ascer-
tain the previous non-magnetic state of the needles, and they were suspended by a fibre
without torsion. To ascertain whether anything was due to the nature of the medium,
I substituted prisms of water, alcohol, spirit of turpentine, and other essential oils, with
the same results.

13. These are the means by which, it is said, the magnetism of light was first dis-
covered ; but there are much more delicate methods of detecting such an action if it
existed, and to them, in the next place, I resorted. For, if the violet or other rays of
light exercise an influence on the magnetic needle, that action must be mutual between
them, and the light, in its turn, should suffer a derangement. To ascertain this, I ad-
mitted a divergent beam of light through a hole in the shutter of a dark room ; the cone
of luminous matter at its apex was about y^th of an inch in diameter, and a hair or oth-
er filament held in it exhibited the phenomena of diffraction, the colours being received
into the eye by a lens. Across this beam a silver wire was adjusted, each of its ex-
tremities connected with cups of mercury, which communicated with the poles of a
voltaic battery. It was expected that, if there was any action between a magnetic fila-

NO REACTION BETWEEN A MAGNET OR VOLTAIC CURRENTS AND UGHT. 7

ment and light, some derangement would be seen in the diffracted firinges when the
current passed ; but none such was observable.

14. Again, two wires were so adjusted that they could be made to approach or re-
cede from each other by a screw movement, and voltaic currents be passed in either
direction, up or down tliem, conjointly or separately ; when they were within the Tj^th
part of an inch, the fringes they produced were very perceptible, but the passage of the
current caused no alteration whatever. These experiments were also repeated in ho-
mogeneous light, with the same results.

15. A hollow prism, a b {Jig. 3, pi. 1), for containing transparent but imperfectly
conducting liquids, was traversed by a voltaic current from the battery, c z, by means of
platina wires, e e, one extremity of each of which went to the bottom of the liquid, and
the other dipped into the mercurial cups of communication, d d. A ray of light, y^
passed through the prism, and was refracted on the screen, g I, or viewed by a glass.
Some of those Unes which traverse the spectrum were at times visible ; but neither
these nor the spectrum itself suffered any perceptible alteration during the passage of
jhe current

16. Some philosophers have pointed out the different degrees of temperature which
Sir W. Herschel detected in different parts of the prismatic spectrum, as analogous to
that increase of temperature which takes place in the cells of the voltaic battery, as we
proceed from the negative to the positive pole. Hence, they have supposed that each
end of the spectrum was in an opposite electrical state. With the analogy I have
nothing to do ; but to ascertain whether the deduction from it is founded in fact, I
made this experiment I received into a tube, a b (Jig. 4, pi. 1), filled with acidu-
lated water, the whole of the prismatic spectrum cast by an equiangular prism of Eng-
lish flint glass, in that part, c, which was covered by the violet ray ; I immersed one
wire, e e e, oi a. galvanometer, arranging the other Wire,/ f, in that part, d, which re-
ceived the red ray. Alternately placing and withdrawing the arrangement from this
position, it was to be expected that either a continuous current or a wave of electricity
would pass along the galvanometer wires, producing either a permanent or transient dis-
turbance. I was not able, however, to notice such an effect ; and suspecting that, if
any electricity was developed, it might be of such low intensity as to be unable to pass
through acidulated water, I repeated the experiment, using, instead of the tube of wa-
ter, a piece of polished tin, in the shape of a parallelogram, three inches long and one
broad, to each end of which the galvanometer wires were soldered ; but the results were
still negative.

17. The general termination of these experiments would lead us to suppose, that if
there be anv reaction between galvanic or magnetic currents and solar light, they are of
such a nature as to forbid repetition in latitudes as far south as 35°.

^

DESCRIPTION OF THE PHENOMENON.

CHAPTER 11.

OF THE TIDAL MOTIONS OF MOVABLE ELECTRIC CONDUCTORS.

(From the Journal of the Franklin Institute for January, 1836.)

Contents : Description of the Phenomenon. — The Polar Wires act as Centres of At-
traction.— They prochice Tides. — Cause of the Oscillations. — Cause of the Spiral
Motions.

18. "Dans d'autres circonstances on observe encore au milieu des masses liquides,
des mouvemens singuliers qu'il est excessiveraent difficile de decrire, tant ils sont nom-
breux et changeans. Je vais essayer d'en donner une idee, en remarquant toutefois,
qu'apres avoir fait de nouibreuses experiences sur ce sujet, il m'a ete impossible d'en
saisir la loi." — (Pouillet.')

19. The singular movements here spoken of by Pouillet have likewise drawn the
attention of several other philosophers. Erman and SeruUas have both recorded in-
stances of gyratory motion produced in certain bodies, especially mercury, by the con-
tact of others. There is also a similar observation made by some of the earlier chem-
ists respecting camphor. Strange motions of an analogous description are also ob-
served in some liquids under the influence of a voltaic current ; these, in the case of
mercury, have been particularly studied by Sir J. Herschel, who obtained several re-
markable notices respecting them ; they are, however, so far as I am informed, as yet
without explanation.

20. If into a watch-glass or shallow capsule, as o a {fig. 5, pi. 1), fifty or sixty
grains of mercury be poured, and over that as much water, acidulated with sulphuric
acid, as is sufficient to cover the surface of the mercury, and the positive and negative
wires of a battery of twenty or thirty plates, arranged as indicated, the mercury being
in contact with the negative pole, and the positive pole being plunged into the water
at a short distance from it, currents are produced both in the water and in the mercury.
Supposing the power of the battery sufficient, the same effect takes place on removing
the negative wire out of the mercury into the water; but if the positive wire is in con-
tact with the mercury, and the negative with the water, there is no motion at all, or, at
most, the mercury only curls itself up into an elongated figure.

21. This motion varies according to several circumstances, but chiefly from the po-
sition of the two wires. 1st. If the wires be on opposite sides of the mercury, the metal
instantaneously elongates, and currents also are seen playing in the water. 2d. If the
negative wire be introduced into the centre of the metallic globule, and the positive
wire be brought on one side, the mercury will bulge out elliptically at both sides, near-
est and farthest from the positive pole ; and by regulating the force of the battery, either
by changing the number of the plates, or altering the strength of the solution acting on
them, the experiment may be so managed that no motion shall ensue in the mercury

DESCRIPTION OF THE PHENOMENON. 9

after this elliptical bulging is effected ; but now, if the negative wire is cautiously raised
from its position, so as to be just out of contact with the surface of the metal, the mer-
cury is immediately convulsed, and its whole surface covered with circular waves. On
lowering the negative wire to its former position, and advancing the positive, the mo-
ment it comes to the edge of the mercurial ellipsoid, the most intense convulsions are
produced, which increase until contact of the mercury and wire is obtained. 3d. If the
two wires form a kind of triangle with the globule, it turns upon itself.

22. At the same time that these movements are going on, the surface of the water
is ploughed by gentle currents, exactly resembling those produced by a breath from a
blowpipe, directed slantingly across the surface.

23. In proceeding to give an explanation of these motions, I shall not follow the an-
alytical course of experiment used in my researches, but commence with those princi-
ples on which a true explanation is founded.

24. It has long been known that the elements of compound substances were held
together in virtue of an affinity among themselves. Sir H. Davy, Berzelius, and other
chemists, were led to suspect that this was due to the electric condition of those ele-
ments, and pursuing this hypothesis in its details, several brilliant discoveries were made,
which ultimately changed the face of the science. Apart, however, from all hypothet-
ical reasoning, it was found that the poles of a voltaic battery had the power of influ-
encing the atomic constitution of bodies, so as to be able to hold all chemical combi-
nation under control. This remarkable effect was imputed to the electrical attraction
and repulsion of the battery ; but a battery which is competent to the rapid decompo-
sition of water, and even the reduction of potash, is found to give exceedingly faint
traces of any electro-dynamic effect, being unable to cause the divergence of a delicate
gold leaf electrometer, or affect the indications of a torsion balance. In the course of
certain experiments, I had occasion to notice that this effect, as to intensity, is entirely
regulated by the medium in which the experiment is made ; as, for instance, a thin
lamina of air or gaseous matter is nearly a perfect non-conductor to electricity of low
intensity, but a mass of water offers no such resistance. I hoped, therefore, that though
I might not be able to exhibit the attraction of a polar wire for a suspended needle in
the Coulomb balance, such an effect might ensue if the experiment was made with the
apparatus plunged in another atmosphere, the conducting power of which differed from
that in which we live. For the conducting power of a medium has no relation either
to its cohesion or its chemical properties, and it did not appear improbable that one
might be found, which, though it should not interfere with the freedom of motion of a
wire plunged in it, its conducting power, in relation to electricities of very low in-
tensity, might exhibit those effects in a more elevated point of view.

25. To illustrate this reasoning, I took a platina wire, a c {fig. 6, pi. 1), two inches
in length, and suspended it by a raw silk thread from a stand, h h, into a vessel filled
with acidulated water, as high as d d. The needle was so arranged that when it hung
with freedom, it was about one fourth of an inch distant from the extremities of two plati-
na-pointed wires, p n, which entered the vessel on opposite sides, and could be made to
communicate at will with the opposite poles of a battery. Now the wire p being pos-

B

jQ THE POLAR WIRES ACT AS CENTRES OF ATTRACTION.

itive, and n negative, the extremity a of the suspended needle would he negative, and
the extremity c positive by induction. The conjoined effort of the forces thus brought
to bear on the needle, acting on its opposite extremities in opposite directions, would
solicit it to move on its axis, the extremity a in the direction n' {Jig 7), and the ex-
tremity c in the direction pi ; the line of rest would be as expressed by the dots in the
fi<Ture, and slow oscillations should take place on either side of that line if the density
or other properties of the medium permitted.

26. The experiment was thus tried, and, to prevent any derangement from hygro-
mctric twist of the silk, the needle was hung on a glass thread, of sufficient length to
reach above the surface of the water, and there attached to the silk ; on passing the
current of forty-five pairs of four inch plates, the needle immediately moved, and after
two or three oscillations, took its position of rest ; on being moved to the opposite side
of the polar wire, an opposite motion ensued until the same position was gained. Du-
ring this movement, gas was freely liberated from the extremities of the polar wires,
and also from both ends of the needle, it hindered considerably that freedom of mo-
tion which I had hoped for in observing the oscillations. The experiment was also
varied by terminating the polar wires with plates of platina, with a view of increasing
the effect ; the needle was also suspended in pyroligneous ether, and the attractive pow-
er of the same battery, newly charged, was very marked ; it was not so observable in
alcohol, and still less in muriatic acid ; in ammonia, though only one end of the needle
appeared to evolve gas, it was not so obedient to the attractive force. These cir-
cumstances indicate that the phenomena of motion, as here exhibited, have not their
origin in any magnetic action produced either by the disturbance of the earth or the
passage of the voltaic currents. Magnetic action, to be complete, requires that the bod-
ies along which currents are passing should be possessed of high conducting power ;
hence a thermal current, whose tension is almost extinct, is still capable of producing a
powerful effect on a suspended needle. A current capable of producing a given devia-
tion when moving along metallic wires, would meet with resistance in passing through
water; and alcohol or ether would forbid its passage. It is, moreover, impossible to
produce any visible effect on the platina wire of this arrangement by the action of a
single pair, even possessing extensive surface, though the same pair, if cut into lesser
plates, and arranged for the production of a current of greater tension, immediately
causes the movement here described. Dr. Faraday has stated, in his recent researches
on this point, that there is not any proof that the poles of a battery do exercise any
power of attraction or repulsion {Baches Turners Che^n., p. 102 ; idem, 108) ; but that
opinion would appear to be inconsistent with the fact — there must be an accumulation
of tension on an electrode, if the medium which separates it from its fellow is not so
good a conductor as the liquid filling the cells of the battery ; and experiment warrants
this conclusion.

27. The principles here laid down also indicate the construction of a galvanometer
which I have recently fitted up. It is intended to exhibit, by the torsion of a fine fibre,
the force of attraction between the polar wires and the ends of the suspended needle.
The obstacle I have observed to the accuracy of the results furnished by it, is due to the
development of gas on the polar wires and on the needle.

THEY PRODUCE TIDES. H

28. The doctrine which I wish to establish from this experiment is, that though the
polar wires are plunged in a conducting medium, and the current is actually passing,
yet they still act as centres of attraction- The motions of mercury and other fluids are
only exemplifications of this doctrine.

29. When a spheroidal mass of conducting matter is brought in presence of a point
of attraction, situated at a distance from its surface, the particles on that surface will be
differently affected as their situation in regard to the attracting point varies. Thus, on
touching the mercurial globule, named in the first part of this paper, with a negative
wire, and introducing into the water a positive platina pole, the globule, which before
was spherical, becomes ellipsoidal, two tides are formed upon it, one directly opposite
the positive wire, and the other 180 degrees from it ; meanwhile there is an ebb in those
regions which are situate a quadrant from the point of attraction. If the positive wire
is made to revolve round the globule, both tides move, always keeping the same rela-
tive position to the point of attraction that they had at first It only requires the force
of the battery to be appropriately moderated to exhibit these phenomena with the ut-
most rigidness. And as these motions exhibit very nearly, on a small scale, that effect
which takes place on an immense scale by the joint action of the Six and Moox in
producing the tides of the ocean, I have given them the name of Tidal motions of mo-
vable Conductors.

30. Now the mechanism which produces the change of figure firom a sphere to an
ellipsoid is sufficiently obvious. We have two forces under consideration : IsL The
cohesion or gravitation of the mercurial particles upon each other ; and, 2d. The dis-
turbing force of the polar wire as a centre of attraction. As that disturbing force de-
creases in a certain ratio, as the distances increase, the mercurial particles on the side,
A (Jig- 8, pi. 1), nearest to the polar wire are more attracted by it than those in the cen-
tre, C, of the globule, and those in the centre, C, are more attracted than those at F.
The particles, therefore, at A rise towards the wire by its direct action, those at F being
less solicited towards the centre of the globule than those at E and B ; the former re-
cede from that centre, while the latter seek it.

31. It has been observed that a true theoretical tide differs in no respect from a wave*
" Suppose a spring tide actually formed on a fluid sphere, and the sun and moon then
annihilated, the elevation must sink, pressing the under waters aside, and causing them
to rise where they were depressed. The motion will not stop when the surface comes
to a level, for the waters arrive at that position with a motion continually accelerated.
They therefore pass that position, as a pendulum passes the perpendicular, and will
rise as far on the other side, forming a high water where it was low water, and low
water where it was high water. And this would go on forever, oscillating in an as-
signable time, if it were not for the viscidity of the water." Now this theoretical case
may be easily shown, for on approaching the positive wire towards the globule of mer-
cury, a particular position will be gained, at which contact will take place between the
protuberant tide on the mercury and the wire. In that moment the cause of attraction
is annihilated, the whole current of electricity now passes along perfect conductors,
hence fiilfiUing the supposed case of an actual annihilation of the sun and moon at the
time of spring tide. And the same reasoning that held in one case, equally apphes in

j^g CAUSE OF THE SPIRAL MOTIONS.

the Other ; the mercurial tide falls with an accelerated motion, and the line which before
was the conjugate axis of the ellipse, now becomes the transverse, a tide being pro-
duced at right angles to the former one. But here the strict comparison ends, for, as
the mercury ebbs from its protuberant position, the metallic connexion breaks, and tlie
wire is again put in action as a point of attraction ; the motion of the ebbing tide is
checked ; it flows once more ; once more the metallic contact is complete, and when
the tide falls, it is only to flow again, as long as the battery current passes. Tides take
place at right angles to each other, in a series too rapid to be counted, and the whole
surface of the mercury is worked into those various and beautiful undulations which
have been before referred to.

32. In endeavouring to ascertain the true cause of these phenomena, the French phi-
losophers were, I believe, the first to observe motions in the water or other liquid of
connnunication, as if a gentle wind played over its surface, bearing light bodies in its
vortex. The explanation of these appearances I here add, because no one as yet has
given it, and it affords an illustration of certain propositions delivered by Sir I. Newton,
in his Principia, concerning the doctrine of pulses in elastic fluids.

33. We have hitherto been considering a globule of mercury as a substance mathe-
matically fluid. Such, however, in effect, it is not ; the water in contact with it pos-
sesses those properties in a much more eminent degree, so that, in comparison with it,
the mercury may be regarded as a solid resisting obstacle. Now, about a year ago, I
showed that when a voltaic current passes through a system such as this of mercury
and water, the capillary pressure on the bounding surface is changed ; but, if the at-
traction of the wire which is introduced into the water, and which is the ultimate cause
of this derangement, decreases in a duplicate ratio, it follows that this disturbance ot
pressure obtains only to a limited extent on the surface of the mercury ; or, in other words,
the excess of pressure produced by a voltaic current is not spent equally on all parts of
the mercurial surface, but those which are adjacent to the positive polar wire are more
affected than those at a distance. Newton has shown {Principia, v. ii., b. ii., pr. 41),
that if the particles of a fluid do not lie in a right Une, a pressure propagated through
that fluid will not be in a rectilineal direction, but the particles that are obliquely posited
have a tendency to be urged out of their position. So the particles a a a a {fig. 9,pL
1), pressing on the particles d b, which stand obliquely to them by reason of the shape
of the mass of mercury g, have a tendency to be urged from their places towards e
and c respectively, and the motion thus produced in a fluid diverges from a rectilinear
progress into the unmoved spaces ; and such a pressure taking effect on a liquid free to
move, continually returns the moving particles to their first position, after making them
describe an elliptical orbit.

34. It has been remarked that the basis on which this explanation essentially rests
is, that a wire, from which an electric current passes, acts still as a point of attraction ;
an effect which involves the conducting and other electric properties of the system on
which the experiment is tried. Hence we gain an -insight into the cause of the paral-
ysis of these motions by the addition of certain substances ; the spiral motions going on
over the surface of the water have these explanations complicated with another con-
sideration, the figure of the mercurial mass.

OF THE MODE OF PASSAGE OF UQUIDS THROUGH PORES. j[3

CHAPTER in.

ON THE INTERSTITIAL MOVEMENTS WHICH TAKE PLACE AMONG THE PARTICLES OF BODIES.
QFivm tie Jmtnul of tke FrmnJOiM LutUxU far March and July. 1836.)

Contexts : Of the Mode of Passage of Liquids through Pores. — Endosmosis. — Perco-
lation through Gum Lac, Gold Leaf, Mica, etc. — Slow Motions in the Parts of Solid
Bodies, as in SUrer Coins. — Percolation through India Rubber. — Conditions of Equi-
librium.— Percolation through Masses of Water. — Percolation through excessirely thin
Films of Water, as Soap Bubbles. — Analysis of Gas on the Exterior and in the Inte-
rior of the Soap Bubble. — General Law of the Phenomenon deduced.

35. The interstices which exist in a great variety of bodies mav be looked upon as an
extensive system of capillary tabes, into which we should be prepared to expect that
bodies of all kinds might pass. A drop of water placed upon a porous stone or a piece
of chalk, sinks into it rapidly, but the value of the observation is lost, because it is com-
mon. If that water contained a colouring matter, we should find that, in sinking into
the chalk, the colour would be left on the surface. But here, again, commonplace princi-
ples^dictate a read}- answer : the interstices of the chalk may be supposed to be too small
to admit the colouring matter to pass, or perhaps some incongruity of shape might afford a
barrier ; yet how, upon these principles, shall we explain that mercury and other bodies
remain unmoved upon the porous mass, and show no ability to go through it, when they
will pass with readiness into the densest and closest substances, as gold ? No principle
of coaptation will explain why quicksilver will not rise in a tube of glass, or why water
rises at all. We are induced at once to refer the whole matter to the chemical condi-
tions of the bodies on which we operate, and we quickly infer that fluids do not pass
into pores by soaking or leakage, or any such commonplace principle, but that it is an
action determined by certain laws that have reference to the condition of each body sep-
arately, and their relation to each other. A question, therefore, naturally arises as to the
peculiar operation of those pores, and how changes in their position, size, and shape
affect the results of their action. A class of these phenomena is quite independent of
pores of any sensible size, where no leakage or oozing can be suspected. A piece of
sugar dissolving in water difliises itself into every part of the menstruum. Among those
excessiveh" small interstices that exist between the atoms of the water, its particles find
a dwelling, where they are sheltered fi^om all those forces that act so energetically on
the great masses of matter. Independent of gravity, they move freely in every direction ;
and, far from settling in those positions to which they might tend from their weight, they
are simultaneously and equally found in every portion of the solvent This condition
of things does not indicate a passive state, but would rather teach that a very active and
powerful force is in operation, a force that can neutralize the action of gravity and other
external agents. It is essential, therefore, clearly to understand the circumstances of

14 OF KNDDSMUSIS.

this absorption ; it may take place independently of apertures, pores, or vessels ; it may
take place between gases and gases, gases and vapours, or liquids, or solids, or mutually
and indiscriminately among them all.

36. When a liquid rises in a capillary tube, those portions only are under the direct
influence of the attractive force of the tube vi^hich are nearest to it, the central columns
being entirely unaffected. Also, when water jets out through a narrow pipe, it is only
those portions that are directly in contact with the sides of the pipe that are subject to
its resisting influences, any disturbance which the central particles feel arising indi-
rectly from their cohesion. The same applies in the passage of liquids among pores:
the diameter of these pores amounting to a certain size, they will admit a passage with-
out exerting any direct influence. Thus, a pore in a piece of charcoal may suffer a
column of water to go through it, without in any wise affecting the central portion of
that column, by reason of its size ; but should the diameter of the pore be made to de-
crease, it is obvious a limit might finally be reached, where every particle that passed
should come under the direct influence of the physical force exerted by the pore, and
none pass by mere leakage or oozing.

37. This leads us to consider the different effects that may ensue when the same
Uquid or gas passes through pores of various sizes in the same solid. An example may,
perhaps, illustrate the results : The walls of a pore are so constituted as to allow an
easy passage of one gas, as oxygen, along them, and afford more or less resistance to
another, as nitrogen gas. Now, if we suppose this pore to be of very large size, and
atmospheric air to be passing through it, little or no change will happen in the consti-
tution of the passing gas, all the internal parts of the current being »ut of the reach of
the walls of the pore ; but should the diameter of the pore be reduced to the diameter
of an atom of the compound gas, or thereabout, the oxygen, finding little or no resist-
ance, would glide through, and the nitrogen be retained, a perfect decomposition happen-
ing. This shows the importance in all investigations relative to Endosmosis, or transit
of bodies through pores, of bearing in mind that, when those pores have a certain di-
ameter, the results of experiments made on them are illusive, not representing alone the
nature and value of the force exerted by the walls of the pore, but showing effects de-
pending also on the cohesion and other properties of the passing body.

38. These observations apply to those experiments which have been made to illus-
trate the phenomena of endosmosis by forcing gases through plugs of stucco, which are
systems of capillary tubes of large size. Experiments on charcoal, plaster, &c., are also
open to the same strictures. Had these only been resorted to, the simplest phenomena
of endosmosis could not have been discovered. The disturbance t>f hydrostatic level,
which is so well shown by a sheet of gum elastic, or an animal membrane, cannot be
produced by the use of plugs with large pores or systems of capillary tubes.

39. It might at first be expected that, as the diameter of a pore decreased, its indis-
position to admit a foreign body would increase; but it is not so : that foreign atom
does not insinuate itself in a passive manner, nor does it go through the pore merely be-
cause it meets with no resistance. There is an active and very energetic force in play,
a force that is even greater than the cohesion of the parts of the pore itself. Hence,

»

PERCOLATION THROUGH GUM LAC, ET^.— SLOW MOTION IN THK PARTS OF SOLIDS. 25

under like circumstances, tbe smallness of such a pore is no bar to its receiving and
Lrau^iuittiug foreign atoms, but very often, in an experimental point of view, is the most
favourable condition under which we can study its action without any retarding or
complex causes.

40. There are some experimental illustrations of the fact, that closeness of texture is no
hiuderauce to the passage of suitable bodies. I took a narrow glass pipe, about an eighth
of an inch in diameter, and dipping one end of it into melted gum lac, expanded there-
on a bubble of that substance, by blowing at the other extremity. In this way, after a

"few trials, the bubble may be made so thin as to be translucent Such a bubble, with
air from the lungs in its interior, being exposed to an atmosphere of ammoniacal gas,
allows a free passage to it. A singular-change in the appearance of the thin membranous
bag takes place during the experiment: from being brown in the thicker parts and whitish
in those that are more translucent, it becomes of one uniform flesh colour. Now in this
state it may be regarded as one of the most impervious of all resinous bodies, and cer-
tainly of them all it has tbe closest texture ; yet, after it has thus been exposed for
a short time to ammonia, we find, on passing into its interior a httle reddened litmus
water, that the gas is present in large quantity, and must, of course, have beeu trans-
mitted along the pores in the resin.

41. On the top of a tube which contained atmospheric air and a piece of litmus pa-
per, tinged red by the fumes of muriatic acid, I fastened very careftilly a piece of gold
leaf, two tenths of an inch in diameter, with ghm-water, and suffered it to dry. The
gold leaf, when examined with a lens by transmitted hght, appeared all over of a uni-
form pea-green colour, nor could any hole or flaw be perceived in it. It was covered with
a jar of ammonia on the mercurial trough, the level of the mercury on the inside and the
outside being regulated. The gas went through the gold leaf rapidly, and in a verv
short time the test paper became uniformly blue. On using carbonic acid or sulphu-
retted hydrogen, the action was very nearly as instantaneous.

42. I split with a lancet a thin plate of Siberian mica, which for the most part ap-
peared of a flame colour, but in places where it was unequally thick, a blue or a red.
This plate, when substituted for gold leaf in the last experiment, suffered ammonia to pass
through it. A similar plate of sulphate of Ume suffered half a cubic inch of carbonic
acid to pass through it in forty minutes. Atmospheric air, in all these cases, was on the
other side.

43. These permeations, which we have noticed to take place so rapidly under favour-
able circumstances, occur likewise more slowly in nature. A sea-shell, for instance, de-
posited in that formation called London clay, in course of time loses its coagidated albu-
men, then its carbonate of lime, and its other ingredients simultaneously or successively.
These are replaced by the sulphuret of iron, by alumina, oxide of iron, &c., wldch form
together a mass of so close a texture, that it can give sparks by collision. Under such
circumstances as those which occur along the coast of the Island of Sheppey, a thin
plate of carbonate otlime is permeated readily by bisulphuret of iron, so that there is a
continued deposition and accumulation of that substance, even in the interior of a thin
shell. Hence the production of that immense quantity of fossil shells, which is there

]6 PERCOLATION THROUGH INDIA-RUBBER.— CONDITION OF EQUILIBRIUM.

used for the purpose of manufacturiug copperas for commerce. Slow motions of the
same kind occur when alloys are huried under the ground, or placed in exposed situa-
tions ; a silver Roman coin has thus been known to part with much of its copper, wliich
formed a species of crystallization on its surface, the patina of antiquarians. It is in
this way that trinkets of gold, on which small quantities of mercury have fallen, gradu-
ally recover their original l)rilliancy and purity. A number of facts of this kind, show-
ing that even in the most solid of metallic textures motions may take place, might be
referred to : these have been well considered by Boyle, in his tract on the languid mo-
tions of bodies.

44. Caoutchouc, or gum elastic, is the substance which, of all others, has furnished the
most unexceptionable results on studying the phenomena of endosmosis. It, however,
at times exerts a synthetic action, which, so far as I know, has not yet been noticed.
Having capped an open tube with a thin piece of this substance, and thrown into it*
200 measures of hydrogen gas, it was exposed to an atmosphere of 100 measures of
oxygen contained in a wider tube, into which it was raised. In eleven days the level
in both tubes had considerably risen, and the barrier, which was at first of a blackish
colour, became quite white. In sixteen days, the united volume of both gases was only
215 measures; this, on analysis, contained, only 14 per cent, of oxygen. It may here
be stated that a like mixture of 100 of oxygen and 200 of hydrogen, enclosed together
in a tube by the side of the former, had undergone little or no diminution. Now a
rough calculation shows that about one thirteenth of the united volume of the gases had
been condensed by the membrane into water, the remaining 62-35 parts of oxygen hav-
ing combined, in some chemical manner, with the substance of the caoutchouc, in the
process of bleaching it.

45. This result points out the condensing effect of a membrane, which often, in many
arrangements, will have no small influence. Thus, in Dr. Mitchell's experiment, where
two bent tubes are screwed together, with a piece of gum elastic between them, the one
tube containing oxygen, and the other a double volume of hydrogen, we should be led
to expect, from the common theory of endosmosis, that however much the levels in the
two tubes might vary relatively to each other, the united volume of the gases ought to
remain constant. If the level in the hydrogen tube rose an inch, ought not the level in
the oxygen tube to sink an inch ? But an appeal to experiment shows that such is by
no means the fact ; to a certain extent, the volume of gas in the tubes is constantly di-
minishing; it is not due to leakage into the free atmosphere, between the membrane and
the glass that presses it, at least not entirely so ; for a part of the gases is condensed by
the direct action of the barrier to form water, and the remainder unites chemically with
it. In some instances, the action is still more obvious. If a vessel of atmospheric air,
the mouth of which is covered by a piece of India-rubber, be immersed in an atmo-
sphere of deutoxide of nitrogen, it will be found that red fumes do not appear in the
vessel, nor any other obvious indication of the presence of the deutoxide, but the mem-
brane soon begins to change its colour, and from being diaphanous, becomes of a dirty
umber brown, the volumes of the gases on both sides of it diminishing.

46. Into a tube which was covered with India-rubber, standing on the shelf of the

CONDITION OF EQUILIBRIUM. ly

pneumatic troa£;h and exposed to the free atmosphere, I placed 100 measures of atmo-
spheric air and 42 of hydrogen gas, being anxious to see if any passage of the gases
would ensue, as the oxygen and hydrogen in the mixture were in nearly a due propor-
tion to form water. Motion at once began, the level of the water in the tube rising for
several hours. In the course of a few days, only a trace of hydrogen was discoverable,
the remaining gas differing very slightly from atmospheric air. The same was repeated
with a tube closed by a serous membrane, kept continually moistened ; when all motion
appeared at an end, analysis showed that there was only j'^th of the whole volume of
hydrogen beneath the membrane.

47. These experiments, which were repeated again and again with the same results,
establish an important doctrine. If a gas be confined beneath a system of pores, the
other extremity of which communicates with another gas, movement will ensue, until
tfie constitution of the gas on both sides of the system is alike. If oxygen and hydro-
gen be thus placed, they will mutually pass to each other, nor will that motion cease
until the resulting compound on both sides of the membrane is the same chemically.
This endeavour to an equalization of constitution takes place under all circumstances ;
it may, perhaps, be partially arrested by the condensing action of the barrier. There
are, therefore, two prominent conditions under which the phenomena of endosmosis
may be regarded: 1st. During the state of motion. 2d. After an equilibrium is obtained.

48. Aided by this principle, we can explain how mixtures of gases would comport
themselves when exposed to free atmospheres, or when shut up in close chambers. The
arrangement of (46) will serve as an illustration : here we have a mixture of atmospheric
air and hydrogen exposed to the free atmosphere. It is evident that, in pursuance of
an attempt to gain an equilibrium, a portion of air from the atmosphere should pass in-
ward through the membrane, and a portion of hydrogen pass out. But as soon as the
hydrogen is beyond the outside of the membrane, it is dissipated by aerial currents, or
otherwnse diffused in the mass of the atmosphere, the condition of equilibrium being in
nowise approached to, for so fast as the hydrogen escapes, it is carried off; there be-
ing continually hydrogen and atmospheric air on one side of the membrane, and onh' at-
mospheric air on the other. Eqnihbritim, therefore, can only be gained by the entire
dissipation of the hydrogen into the free air, and, accordingly, experiment indicates that
when that equilibrium is gained, the hydrogen has vanished, and atmospheric air is
found on both sides of the membrane. But very different would that action be if the
arrangements were included in a close chamber, as beneath a small glass bell ; here,
when the hydrogen comes out through the membrane, it does not escape, but continu-
ally accumulates, and motion ceases, and equihbrium is gained when the relative pro-
portion of the gases outside the membrane is the same as inside. Hydrogen, therefore,
in this case, is found on both sides of the barrier.

49. Before proceeding to give an account of the chemical changes that may happen in
virtue of the action of capillary forces, it is necessary to remark, that all the analyses of
gaseous mixtures, in which oxygen is an element, have been uniformly made by means
of binoxide of nitrogen. Living in a cUmate where no dependance can be placed on the
action of an electrical machine, and not possessing Dr. Hare's galvano-ignition apparatus,

C

28 CONDITION OF EQUILIBRIUiM.

I was led by necessity to choose between spongy platina and the binoxide of nitrogen
After an experience of some extent in tlie employment of this gas, it has not appeared
to deceive me ; it is, indeed, an eligible method in gaseous analysis where oxygen is con-
cerned. The mode of manipulation is as follows : with the sliding rod eudiometer, throw
100 measures of the gas under trial above the surface of water that has been duly ex-
posed to the atmosphere, and contained in an inverted bell, rather wide in proportion to
its depth; one made of the belly of a glass retort or a cupping-glass answers very well.
Then add 100 measures of the binoxide of nitrogen if the gas is suspected to be poor
in oxygen, but 200 or more if the gas is richer, always observing to have the binoxide
in excess. After the lapse of a minute the absorption is complete ; measure the resi-
due, and one fourth of the diminution gives the volume of oxygen : this method is anal-
ogous to that of Gay Lussac. Some idea of its correctness may be formed from the cir-
cumstance that, of 73 analyses of the air, the mean result of the amount of oxygen is
2058 per cent. My measuring rod divides each volume into decimals by a vernier ar-
rangement ; but for most purposes of analysis this is unnecessary.

50. It results, from the observations which have been made on caoutchouc by Dr,
INIitchell, that oxygen passes through it with much more facility than nitrogen. Atmo-
spheric air is also reputed to be a mixture, and not a chemical compound ; it was there-
fore an object to try whether pure oxygen might not be obtained by forcing air through
such a membrane, filtering, or, in fact, straining it through a gum elastic bag. A thin
piece of this substance was therefore tied tightly over a tube an inch in diameter and
six inches long; the tube was then filled with mercury in such a manner that the great
weight might not burst the caoutchouc ; it was then inverted and exposed to the atmo-
sphere. The membrane bulged into the tube in a deep hemispherical form ; in about
an hour its under surface was studded with bubbles of gas, and in the course of time
several cubic inches passed. This, on analysis, by means of binoxide of nitrogen, was
found not to differ sensibly from atmospheric air. A similar result was also obtained
when a thin serous membrane, a piece of peritoneum stripped from the liver, was sub-
stituted for the gum elastic. No indications whatever could be obtained that atmospheric
air was decomposed during the process. Nor is it difficult to understand and explain
how this happens, when a foreign force, equivalent to a pressure of six inches of mer-
cury, is brought to bear so advantageously on the action of a very thin membrane; for
in the case of the gum elastic, the thickness could not be estimated at more than T^i-th
of an inch, and the serous membrane was so porous that it could not sustain so heavy
a pressure without immediate leakage ; the united gas, whatever it may be, is at once
forced through, the barrier being unable to stop it. A case of the same kind is met
with when porous charcoal is used: pressure forces a gas through it entirely unchanged;
but if the effects of that pressure be avoided, chemical decompositions of a decisive
character may ensue, as we shall shortly have occasion to see. To obtain these chem-
ical effects, it is necessary that the barrier should not only have no pores of sensible
size, but that no adventitious or foreign forces be brought to act on the passing gas ; in
proportion as these conditions are fulfilled, the success of the experiment is more perfect;
and thus, as we shall proceed to point out, it is possible to strain the nitrogen ont of
atmospheric air, and procure By that means oxygen of greater or less purity.

PERCOLATION THROUGH MASSES OF WATER. ^9

61. The doctrine laid down in sections 47 and 48, of the condition of eqnilibrium
of gases on each side of a membrane, being the foundation of an explanation of all the
phenomena which have as yet been noticed, requires farther consideration and fuller
proof Some remarks have been offered on the incomplete results which are obtained
by the use of barriers consisting of pores of large size, such as stucco plugs. It is said,
however, that in the hands of Mr. Graham these have given some curious results re-
specting the rate of diffusion of gases ; experiments at once satisfactory and singular.

52. The objections above mentioned have, however, appeared to me so weighty,
that I have not made use of such barriers, but resorted to liquids, which, for closeness
of texture, uniformity of composition, and, above all, on account of our accurate knowl-
edge of their habitudes and structure, are much preferable. They, also, have given
results as ctuious, but far more satisfactory ; and though, in the management of them,
something of that dexterity of manipulation is required which practice alone can con-
fer, yet they are easy of repetition, never failing to give precise and comparable results.
They also afford the means of prolonging or hastening the close of an experiment, which
at times is invaluable ; their action, too, is very uniform ; for a film of water so thin as
to be coloured acts as well as a mass several inches in depth, but the gases passing
through it more rapidly, a state of equilibrium on both sides is obtained in a few min-
utes. The following facts will serve as an illustration: Into a tube h {Jig. 10,^/. 1},
which was conoidal at its upper end, a disk of paper, a, was fastened water-tight, and
then upon that was poured distilled water till it was about \ inch deep; the tube was
next filled at the pneumatic trough with hydrogen gas, which passed into the atmosphere
through the paper roof, and the water reposing on it ; but, though the tube was only |
inch in diameter, twenty-four hours elapsed before a column of hydrogen half an inch long
had gone out, and in seven days only one inch more. A common glass tumbler was
filled with hvdrogen gas at the pneumatic trough, and by the side of it stood a small
bottle, the height of which was about 1? inch, its diameter \\ inch, and the diameter
of its neck ' of an inch. The atmospheric air in this bottle being of the same tem-
perature as the hydrogen in the tumbler, a finger dipped in water rendered slightly viscid
with soap was passed over the mouth of the bottle, so as to leave a thin film stretched
there, the tumbler of hydrogen being then placed over it {fig. 12, pi. 1). In the course
of two minutes, the film, instead of being horizontal, became convex, and continued to
be so until it had swelled into a large spherical bubble, which capped the top of the
bottle ; in sixteen minutes this had increased so much in size and become so thin that
it was of a dark metallic lustre, and it burst at last by swelling, so as to touch the bot-
tom of the tumbler. During this experiment the barometer was at 28-8 ; thermometer
at 68-75, Fah.

53. The rapidity of this action being proportional to the thinness of the film used
as a boundary, it is obvious that the duration of an experiment may be managed by de-
termining beforehand the thickness of the film through which the gases shall pass. If
very thick, the time may be indefinitely long, and if very thin, indefinitely short Nor need
we be limited in reducing the thickness to the greatest extent, for it is found b}' experi-
ment that, however thin the film may be, it still possesses cohesion enough, and its parts

20 PERCOLATION THROUGH EXCESSIVELY THIN FILMS OF WATER, AS SOAP BUBBLES.

are still so close, that anything like mechanical straining or leakage cannot take place
through it. The first attempts to ascertain the laws of movement and equilibrium of
gases passing through liquid films were made by stretching those films over the mouths
of vials, as here described ; subsequently, for several considerations, this arrangement
was given up : the horizontal film is at first too thick, it exposes too small a surface to
the atmosphere to which it is subjected, and it is not until towards the close of the
experiment that the action becomes at all rapid. Bubbles of water made sufficiently
adhesive by a little soap were, therefore, substitnted. One of these filled with any gas,
and immersed in an atmosphere of another gas, at once exposes a large surface, and,
by swelling or collapsing, allows a free action. There are, however, three circum-
stances which tend to destroy such bubbles, and against these provision should be care-
fully made. Mechanical agitations of the surrounding air may be met by covering the
whole arrangement with a glass bell. Evaporation from the surface of the bubble, which
reduces its substance unduly, may be avoided by keeping all the gases under trial in
jars over water, until they are loaded with moisture, and thoroughly wetting the inside
of the covering-bell ; but it is not so easy to prevent that slow motion of the parts of
the bubble, which, in virtue of the earth's attraction, tends gradually to bring them to
the lowest part, while the walls of it become too thin to bear the weight, and are Hable
to burst by the expansion of the gases accumulating within.

54. After a number of trials, the following has been found to be the most suitable ar-
rangement for prosecuting these inquiries ; it is simple, not easily deranged, and allows
of sufficient latitude and change to suit other experiments. In it a soap bubble may be
preserved with certainty, for a time considerably exceeding an hour, and sometimes much
longer. As here described, it was used to illustrate the relative passages of hydrogen, oxy-
gen, and nitrogen through a watery film into atmospheric air. It is represented in section;
A A {Jig. 11, pi. 1) is a small tin saucer, about three inches in diameter and half an
inch deep ; into it water can be poured, and it also serves as a platform to support a
large cupping-glass, h. Through the centre of this tin saucer, at c, passes a glass pipe,
f, i inch in diameter, the upper extremity of which is cemented into a hole of the same
size in a round, thin piece of copper, d, which is about half an inch in diameter, the
other end of the pipe opening into another cupping-glass, k, through a perforation in its
top, the communication being capable of being cut off" by means of a cock, g ; the
lower cupping-glass serves as a support to the whole arrangement when placed upon
the shelf of the pneumatic trough. This apparatus is used as follows : The upper
cupping-glass being taken off the platform, is filled with any gas under trial, as oxygen,
and placed aside on the shelf. The lower cupping-glass is then filled with water
by depressing it in the trough, and the cock being closed, five hundred measures of
hydrogen, for instance, are thrown into it. After seeing that the copper plate, d, is
free from moisture, a drop of water, rendered slightly viscid by soap, is placed upon it
exactly over where the orifice of the pipe,/^ opens. The upper glass, containing the ox-
ygen, is now placed upon the little tin saucer platform, as in the figure. The lower
glass is next depressed in the trough, and as soon as the cock is opened, a bubble of
hydrogen containing five hundred measures expands, the spare oxygen escaping from the

PERCOLATION THROUGH EXCESSIVELY THIN FILMS OF WATER, AS SOAP BUBBLES. 21

edge of the upper glass through the water in the saucer ; the cock is next closed, and
the apparatus placed on the trough shelf as long as the operator desires the experiment
to continue. Keeping that position when the cock is once more open, the gas passes
into the lower glass until the bubble is entirely collapsed, when the cock is again closed,
the contents of the bubble being now ready for measurement or analysis. As the gas
passes from the bubble into the lower jar, the water rises from the tin saucer into the
cupping-glass above, confining the gas that was outside of the bubble ; this, by the com-
mon mode of manipulation, is to be transferred from the tin platform to the shelf of the
trough for inspection.

65. By this apparatus it was found that one thousand measures of atmospheric air,
exposed in a bubble to atmospheric air, in five successive experiments, underwent no
change either in volume or composition. The duration of the trials was severally ten,
fifteen, twenty, thirty, and sixty minutes, and the uniform result, when drawn back into
the under cupping-glass, was one thousand measures exactly, the composition of which
was the same as atmospheric air.

56. The thermometer stood at 54° FaL One thousand measures of hydrogen in
the watery fihn were subjected to atmospheric air in the upper bell; in five minutes
there remained only four hundred and seventy-two. In the second trial, one thousand
measures in twenty minutes became-four hundred and thirty-two ; and in a third, when
the same quantity of gas was confined half an hour, the residue was four hundred and
eighty measures.

57. A reverse action ensues when nitrogen is substituted for hydrogen : the bubble
swells instead of diminishing, and the resulting gas measures more. It is to be remarked,
that after the first five minutes, provided the bubble has been sufficiently thin, there
appears to be little or no change in the volume of gas, and in a great many experi-
ments it was found that motion had ceased when the bubble had increased somewhere
between 7i and 10 per cent. The thermometer standing at 55° Fah., one hundred meas-
ures of nitrogen in half an hour became one hundred and seven and a half. In another
trial, two hundred measures in the same time became two hundred and fifteen. Again,
two hundred in fifteen minutes became two hundred and sixteen. The greatest varia-
tion from this was in one case, when, after an exposure of five hundred measures for
five minutes, the bubble was found to contain five hundred and forty-five measures, or
an increase of 9 per cent.

58. Oxygen gas exposed in like manner to atmospheric air, decreased in bulk ; thus,
two hundred and fitty measures in ten minutes became one hundred and fifty-three, and
the like quantity in fifteen minutes diminished to one hundred and forty-four, which
amply proves that the passage of oxygen takes place through water more rapidly than
nitrogen. And upon this fundamental principle, chemical decompositions can be ef-
fected ; as in the last section, where we have a bubble of nitrogen gas exposed to the
atmosphere, the nitrogen outside parts with its oxygen, and passing through the barrier,
unites with the oxygen within.

59. Having thus recognised a variation in the rate of passage of gases through thin
films, it becomes a point of investigation to ascertain how long these motions may be

22 ANALYSES OF GAS ON THE EXTERIOR AND INTERIOR OF SOAP BUBBLES.

maintained, and under what circumstances a state of equilibrium will ensue. I have
already stated that the condition of rest was simply an identity of composition of the
media on both sides the membrane, a law which is rigidly observed by all gases that
have yet been tried. Four hundred measures of nitrogen gas procured by phosphorus,
but which, by standing over water, were found to have gained 3^ per cent, of oxygen,
were exposed to atmospheric air, in the apparatus above described, for thirty minutes :
at the end of that time, there were found four hundred and thirty-two measures in the
bubble, of which 15j per cent, were oxygen. Outside the bubble were ten hundred and
seventy measures, which also contained ISj per cent, of oxygen ; thermometer 57° Fab.

60. Two hundred measures of nitrogen, containing the impurity as above, were ex-
posed for thirty minutes in an atmosphere of impure oxygen, which contained nitrogen
and carbonic acid, to the amount of 13^ per cent. : at the end of that time, three hun-
dred and sixty-one and a fourth measures were found in the bubble, of which 62 per
cent, were oxygen ; and eleven hundred and forty-four and a half measures were found
outside, 621 per cent, of which were oxygen ; thermometer 55° Fah.

61. Two hundred measures of oxygen were exposed to an atmosphere of hydrogen
for fifteen minutes, at a temperature of 66° Fah. : at the end of that time, two hundred
and seven and three fourths were found in the bubble, containing 16? per cent, of ox-
ygen ; and twelve hundred and seventy-three outside, which also contained 16f per
cent, of oxygen.

62. The slower passing gases being thus found to obey a very simple law of equilib-
rium, attempts were made to ascertain whether such as carbonic acid, which are very
absorbable by water, followed the same law ; but, after many trials, no certain result
could be obtained, so rapid was the action. Five hundred measures thus confined
passed out immediately, the bubble collapsing almost as fast as it had been expanded : a
tube was therefore prepared, which had a roof of water at one extremity, about half an
inch thick, and two inches in diameter; beneath this roof five thousand measures of car-
bonic acid gas were placed, and the arrangement exposed to the atmosphere. In forty-
eight hours, analysis showed that a trace of carbonic acid still existed in the tube, which,
when washed off, about two hundred measures of unabsorbable gas remained, con-
sisting of 20-5 oxygen, 79"5 nitrogen ; and therefore atmospheric air. This experiment
would thus warrant the conclusion that gases of any kind will pass a barrier, subject to
the same regulations as those that are less absorbable ; had it been allowed to continue
for a sufficient length of time, there can be no doubt that all the carbonic acid gas pres-
ent would have escaped into the atmosphere, and atmospheric air alone been present on
both sides of the barrier.

63. Hence, the condition under which motion ceases through a barrier is identity of
chemical composition on both its sides. As gases, however, pass with different degrees
of velocity through the same liquid, results seemingly anomalous may be obtained, and
chemical decomposition may ensue ; if water recently boiled be exposed to the atmo-
sphere, it will be found in a few hours to have abstracted oxygen and nitrogen gases,
not in the same proportion, however, that exists in the circumambient air, for the gas
found in water contains ^ instead of i of oxygen ; perhaps in the course of time that

DIFFUSION TAKES PLACE BETWEEN THE PARTICLES OF HETEROGENEOUS BODIES. 23

richer gas would escape, and its place be taken by common air. We therefore con-
sider this a case in which equihbrium has not ensued, progress only being made to-
wards it, the decomposition and apparent anomaly being only the result of a more ready
solubihty and rapid passage of one gas. By taking advantage of this, it is possible to
obtain from the atmosphere oxygen of some purity. If a volume of atmospheric air be
agitated with boiled water in a close vessel, it will be found that a rapid absorption of
its oxygen ensues, while but little nitrogen is imprisoned among the pores of the liquid-
This gas, by the action of heat, may be driven off from the water, and being subjected
to another washing, may be rendered still more pure ; by successively washing and
rejecting the nitrogen left, a gas so rich in oxygen may be procured as to be equal to
some that is obtained by other processes, as by the action of sulphuric acid on perox-
ide of manganese.

CHAPTER IV.
ON INTERSTITIAL MOVEifENTS, being o Continuation of the preceding Chapter,

{Frwm tie Americn Joanal cf tkc MeJiatl Sciatca/or M*f, 1836.)

Contents : Diffusion takes place hetrceen the Particles of Heterogeneous Bodies. — Dif-
fers from Chemical Attraction. — Action of Binary Arrangements. — Action of Ternary
Arrangements. — Decompositions hy Binary Arrangements. — Decompositions by Ter-
nary Arrangements.

64. If we could place a known volume of vapour in the centre of an extensive void,
where no disturbance from without could sohcit its particles to move in one direction
rather than another, it is to be supposed that, conformably to certain laws that are
known to obtain and operate on bodies of an aerial constitution, movement would en-
sue. To an assignable limit the vapour would expand, by a species of repulsion of its
own particles. In the immense vacuum in which the solar system moves, there are orbs
that seem to fulfil this condition ; these, though they wander through very large
paths, and are disturbed by the reaction of bodies they move past, sufficiently approxi-
mate the circumstances here laid down to show that there is an extent beyond which
bodies so constituted are not disposed to e.xpand. Astronomical observations also show
that gases such as our own atmosphere is composed of do not by their expansion tres-
pass bevond a given point into a void, for then the laws upon which they are formed
react, as the firmest barrier from without would do, to prevent their farther expansion.

65. An orb so constituted could not, in any length of time, undergo any change of com-
position, structure, or figure ; for, so soon as the first motion which decided its equilibrium
was over, that equilibrium would remain undisturbed, unless forces from without were
brought to bear upon it. In a void such as we are here supposing, apart from any such
derangement, equallv a void as to force as well as to matter, the vaporous mass coidd
not be subject to any contingency.

24

DIFFERS FROM CHEMICAL AFFINITY.

66. Let us extend our supposition by placing another volume in presence of the for-
mer, differing from it in chemical composition alone. That difference would determine
certain motions of penetration, in addition to those resulting from mere mechanical action.
Not only would the united mass move so as to assume a mechanical equilibrium, but
its constituent parts would also move, so as to estabhsh a chemical equilibrium at the same
time. Wherever an atom of one of the vapours existed, there would be found one of
the other also. To bring about this result, a mutual penetration of parts is demanded, a
transit of the constituents of one vapour among those of the other. The motions that
effect this arrangement take place without any resistance, just in the way that the light
of a distant star comes into our system, undeterred by the rays of our sun, and moves
freely in every direction ; his beams also move in the vacuum, intersecting the paths of
other luminous bodies without any hinderance or shock.

67. In this state of extension, when the component atoms of a gas or vapour are sup-
posed to be stretched to their utmost limit, which we are prone to imagine can only be
done by an increase of the distance usually existing between an atom and its neigh-
bours, it is not difficult to suppose that these different motions can go on, and that a
foreign atom may insinuate itself in the interstices between others. But our ideas of
space and size being only relative, and as we know nothing of the dimensions of an ulti-
mate atom, nor of the interval that parts it from those around it, it is plain we could not,
without actual experiment, determine when a body had arrived at that state of con-
densation, or when its particles had become so closely approximated to each other as to
refuse the admission of foreign atoms between them.

68. A mass of any kind in a vacuum, and undisturbed, moves, therefore, only in that
manner which the laws of dynamics indicate. Motions of another kind, however, are
induced when the vacuum is changed for a substance ; a kind of penetration, permeation,
or absorption is the result ; nor do the mechanical conditions of bodies appear to have
any effect : with some of these phenomena we are familiar. A gas, a liquid, or a solid
may indiscriminately pass by solution into the pores of water without any reference
to their aggregation. A variety of words have been used to express this action : solution,
endosmosis, permeation, &c. ; but, parting from the simplest experimental condition, we
shall have occasion to see that all these refer to varieties of one phenomenon only.

69. If a solitary body has thus no opportunity of exhibiting the conditions of its
own arrangement as to structure or the forces that inhabit the interstices of its atoms, it is
very different with a binary arrangement. Chemists are familiar with the phenomena
exhibited when gases, solids, or liquids are exposed to each other under those circum-
stances where no direct change of composition ensues. Thus, if a cubic inch of carbonic
acid gas be exposed to a cubic inch of water, the gas in a short time passes into the
liquid mass, or is absorbed by it, with a certain degree of force and to a certain amount.
Also, aqueous gas rises from the water, and diffuses itself into the unabsorbed remainder
of the carbonic acid. After a sufficient time, no part of the carbonic acid will be found
destitute of aqueous gas, nor will any part of the water be without its equivalent of
carbonic acid. The simplest example of these combinations is furnished by the solution
of saline bodies in water, where there is no change of chemical composition, but merely

DIFFERS FROM CHEMICAL AFFINITY. 35

a detachment of the solid crystalline particles from the mass of the dissohing substance;
these pass among the interstices of the liquid, and remain there, unaffected by gravity,
being equally and uniformly difiiised. Of the powers by which this is brought about we
are not well informed, but no fact in science is better ascertained than this uniform and
equable diffusion. If^ by affinity, we mean a power that causes substances to unite with
an interchange of elements, or one which is only exerted to bring about an alteration of
composition, such a force is obviously insufficient to give rise to these effects.

70. That one particle has the power of attaching itself to another of a dissimilar
kind, without anything like change of composition, numerous facts demonstrate. The
delicate dyes that adhere to cloth-fibre offer an example ; they cannot be supposed to be
attached by any force affecting either their composition or structure, since the successfiil
operations of the artist proceed upon the supposition that the tint shall be unimpaired,
and the strength and organization of the fibre which is dyed shall remain untouched.
Now in those cases where we know that the dyeing material acts chemically on the
fibre, is there not abundant proof that the elementary changes affect the uniting bodies ?
Is not the hue of the dye changed, and does not the fabric become rotten ? Other
facts also show that these adhesions, without chemical change, are possible ; the foil
on the back of a mirror is not retained by the exercise of any force which has brought
about a change in its composition. When the dye is washed off, or the foil scraped
away, the cloth-fibre and the looking-glass are both found in their original integrity of
structure.

71. The cases here cited furnish examples of one solid uniting to another in a man-
ner that involves something different from the action of chemical affinity. There
is a whole range or class of similar combinations : a solid may unite thus with a liquid,
as sugar and water ; a liquid with a liquid, as alcohol and water ; a liquid with a gas, as
carbonic acid and water ; or a gas with a gas, as oxygen and nitrogen. All these are
cases where there is no interchange of chemical elements, and which we cannot, there-
fore, suppose to ensue in virtue of chemical force.

72. Although these actions are the result of a kind of adhesion of particle to particle,
and might, therefore, be supposed to take place in an indiscriminate or irregular man-
ner, there are some remarkable circumstances attending them which go to show the
contrary ; thus, water will dissolve a certain quantity of sulphuric ether, and no more ;
it will take up its own volume of carbonic acid, and no more ; it will hold in solution
of bisulphate of potash, sulphate of ammonia, protosulphate of iron, bicarbonate of
potash, chromate of potash, muriate of strontian, &c., half its weight, at 60 F. At the
same temperature it dissolves its own weight of sulphate of magnesia, and this com-
parison might be extended much farther. The same kind of predilection for definite
quantities obtains also in gases, as is the case with atmospheric air, where the propor-
tions of oxygen dissolved in nitrogen are as one to four, nearly.

73. All these things go to prove that the passage of the particles of one body among
the particles of another proceeds upon certain and definite laws. Whether the resi-
dence of saline atoms among the interstices of a liquid is a phenomenon of the same
sort as the adherence of dye to a fibre, it is not material to inquire. We know, by

D

2g ACTION OF BINARY ARRANGEMENTS.

experiment, that a solitary gas has a tendency to expand itself to a certain extent, but
not farther ; and we are equally assured that bodies, whether of the same or of dif-
ferent kinds, have an inclination to penetrate into each other. Where there is an ap-
parent indisposition to do this, we are not without plausible reasons for supposing it to
be through the intervention of disturbing causes. If oil and water do not commingle, it
is a result determined by the action of their cohesion, as compared with the force of
attraction between them. An interesting example of this nature is afforded by the ac-
tion of mercury on glass : under ordinary circumstances, they show no disposition to
unite, not even so much as water and oil ; but, by a suitable application of heat, the co-
hesion of the mercury may be so lessened, and its force of attraction for glass at the
same time so exalted, that it can be brought to wet it ; an experiment first successfully
performed by Laplace.

74. This nisus, or endeavour of one body to diffuse itself into the interstices of an-
other, has, under a variety of forms, been long recognised. The solution of salts, the
absorption of gas by liquids, the passage of liquids through crystals, the permeation of
porous textures, the diffusion of gases, the languid movement occurring in solids, were
known long ago. Of late years, some extension of these facts has been obtained, and
the new phenomenon, though expUcable on the same principles, is dignified by the title

ENDOSMOSIS (37).

75. For the explanation of the whole of this most interesting series of results, one
postulate alone is demanded — that all bodies ham a tendency to diffuse themselves into
the interstices of all others, with more or less intensity. Nor is it difficult to admit this
principle in its fullest extent, when we consider the numerous examples philosophy af-
fords of it. All kinds of chemical absorptions and solutions are cases of it. The dis-
turbing causes which sometimes change, or even entirely hinder these actions, we shall
consider hereafter.

76. Binary arrangements, or those in which two bodies are engaged, whether solid,
liquid, or gaseous, exhibit some circumstances which it is here necessary to point out.
Let us suppose the couple under consideration to be oxygen gas exposed to an equal
volume of water. No remarkable phenomena attend the passage of the gas into the
liquid ; there is no rise of temperature, and the whole amount absorbed is greatly less
than the bulk of the water. If another gas be substituted, as carbonic acid, though
nuich more soluble, there is still no indication of change of temperature, but ammonia
and muriatic acid condensing to a much greater amount, disengage heat. Another
couple might be assumed, as charcoal or porous masses, with oxygen or other gases, and
similar indications be obtained.

77. If, after a liquid has absorbed as much of any given gas as it is capable, we re-
move the remnant of unabsorbed gas, and in its place substitute some other of a differ-
ent kind, complex reaction ensues. The gas, already absorbed by the water, has its
condition of equihbrium disturbed, and, in conformity with the general principle (75), it
has a tendency to diffuse itself out of the water into the newly-introduced gas. This,
in its turn, has also a tendency to pass into the water. Thus, if over a volume of water,
impregnated with carbonic acid, and confined in a jar over mercury, we place a vol-

ACTION OF TERNARY ARRANGEMENTS. 27

ame of oxygen, equilibrium would not be obtained until a certain amount of carbonic
acid was found in the gas, and a certain amount of oxygen in the water. And the
same would hold in the case of any other gases or any other liquid. In the course of
experiment, examples of this case are often met with. The water commonly used in
pneumatic troughs contains both oxygen and nitrogen. If into a jar containing such
water we pass pure nitrogen, in the course of a few minutes oxygen will leave the wa-
ter to diffuse itself into the nitrogen. Had we thrown in pure oxygen, nitrogen, on the
contrary, would have deserted the water and minffled with the oxygen gas. In gaseous
analysis, this action, which obtains to a greater or less extent with every gas, often gives
rise to much perplexity.

78. Ternary Arrangements. — It is plain that the conditions of the action consid-
ered in the last paragraph may be obtained at once by suitable arrangements ; and, as
it is important that these should be well understood, I shall dwell upon them minutely.

79. In paragraph (77), we considered the reaction ensuing, first, of a single couple
or binary arrangement, and then the disturbance effected by the introduction of another
element. Could we, then, at once have exposed the volume of water by one surface to
oxygen gas, and by another to carbonic acid, the changes that were consecutive would
have been simultaneous. Let a (Jig- 13, pi. 1) be a sheet of water, on which, at its
upper surface, a volume, b, of carbonic acid reposes, and beneath its under surface, c, a
volume of oxygen ; both gases pass at once through the water, in opposite directions, into
each other. It is evident that the thinner we make the barrier of water, the more rap-
idlv will equilibrium be obtained. This I have accompUshed in the following manner,
by using mere hquid films, and for that purpose have taken advantage of soap and other
bubbles. A glass tube j inch in the bore, and seven or eight inches long, is to be drawn
out at one extremity to a capillary termination, and when the bubble is to be blown, the
other end is dipped into a solution of soap. The tube having been previously passed
through a cork, as in fig. 14, pi. 1, is now to be introduced into a clear vial or bell
glass, the neck of which the cork fits loosely ; on blowing at the capillary termination,
the bubble slowly expands in the vial, where it is protected from access of air. To
measure its diameter, I take a strip of white pasteboard, and divide it into inches and
decimals, placing it in such a position before the vial that it crosses the bubble diamet-
rically; then with a small telescope that magnifies twelve or twenty times, and at the
distance of about eight feet, I observe the bubble much magnified, the micrometrical
pasteboard apparently passing through its very substance, as is shown in the figure.

80. Through a soap bubble 153 inch in diameter, the substance of which, previous
to expansion, was contained in a cylinder \ inch in diameter and \ in height, ammonia,
either pure or diluted with atmospheric air, passes instantaneously when air from the
lungs is on the other side. Into the bottle in which the bubble is to be blown a httle
strong solution of ammonia is to be poured ; the bubble is then expanded ; at a particular
point it becomes dyed with the richest hues, and that moment the phenomenon of
endosmosis is complete : care must be had to suffer no moisture firom the mouth to
close the capillary termination of the glass tube ; and now a rod, a, dipped in muriatic
acid, is to be brought over the opening ; as the bubble is collapsing by the attraction of

S8

ACTION OF TERNARY ARRANGEMENTS.

its own parts, dense fumes of muriate of ammonia make their appearance, which continue
until the substance of the bubble has entirely returned into the tube. The extraordinary
rapidity of this action is remarkable. The bubble is scarcely blown before it is full of
anunonia ; and it is not less interesting to observe how the colours play with change
of atmosphere. A little cylinder expanded to the size of a pea, which, in common
air, is opaque white, and which would not be coloured until expanded to six or eight
times tliat diameter, becomes deeply tinged as soon as it is penetrated by ammonia.
If restored to the free atmosphere it loses all its beauty, and these aherations may be
kept up at pleasure by merely changing it from one medium to another.

81. When, for the purpose of experiment, it is desirable to have a permanent bub-
ble, a small column of moisture from the tongue must be allowed to close the capillary
termination of the tube.

82. In the same manner, hydrosulphate of ammonia is found to pass with instanta-
neous rapidity through the film, and may be detected by a paper dipped in acetate
of lead. The colours in this case become very quickly stable, as with ammonia, and
do not produce that iridescent play which the passage of certain other substances
affords. It is, however, essential to the success of these experiments that the sub-
stances about to be passed through the film shall not have any chemical action upon it.
Thus, it is not possible to use muriatic acid, which decomposes soap, but there is no
difficulty in the management of such as oxygen, hydrogen, nitrogen, &c. The passage
of hydrogen through these films is exemplified in the following table :

Diameter of a bubble of hydrogen gat exposed to atmospheric air. Diameter of a bubble of atmospheric air exposed to hydrogen gas.

tixp.

When Blown.

In two Minutes.

*

1

2
3

460
•415
•425

430
390
400

430
390
•400

Exp.

When Blown.

In two Minutes.

#

495
380
•445

I
2
3

•470
■300
•420

•485
•375
•435

83. The third column, marked *, in these tables was taken when the black spot on
the top of the bubble was about half an inch in diameter; for, as the coloured rings
were the same in each experiment, and the surface incapable of reflecting light of equal
extent, it is to be presumed that the measures were obtained under like circumstances,
as far as the thickness of the film was concerned. In all cases the bubbles were blown
by pressure on a gum elastic bag. This method of measuring the expansion, though
suitable for general purposes, cannot, however, be extensively relied on, owing to thermal
disturbance and the earth's action changing the figure from a true sphere to a prolate
spheroid.

84. It is interesting to remark with what extraordinary rapidity these permeations
take place. If we expand a small bubble in a vessel of ammonia, hydrogen, sulphuretted
hydrogen, &c., by means of the mouth, and, without removing the lips from the capillary
opening of the tube, inhale immediately the contents of the bubble, the gaseous matter
will impress the organs of taste with a very distinct savour, peculiar to the gas on which
the experiment is tried. There is a class of vapours which appears to possess little
or no affinity for water, such as ether and the essential oils ; these, however, percolate
through tissues of water with rapidity. On covering the bottom of a vial with oil of pep-

V

ACTION OF TERNARY ARRANGEMENTS. 29

permint, and then expanding a bubble, the taste of the essential oil will be perceived
when a portion of the air is drawn back out of the bubble into the mouth. With other
oils, as cajeput, and with ethers, the effect is the same ; and it is to be observed, that
durin'' the transit they work the surface of the bubble into a kind of microscopic waves,
and produce an iridescent play of colours.

85. To obviate any exception that might be taken to the use of soapy matter in these
films, or to their excessive thinness, I have employed the arrangement of section 52,
which establishes the same truths.

86. Into such a tube I threw 200 measures of hydrogen gas, and the same quantity
into one the upper extremity of which was hermetically sealed, by way of affording a
comparison. In the former, the thickness of the roof of water was about j inch, and in
24 hours the level of the water in it rose half an inch ; while in the latter it remained un-
disturbed, thus incontestably proving that hydrogen gas passes with great freedom through
masses of water. Nor is this permeability confined to that liquid alone : a tube which
was thus covered with a layer of lamp oil, in five days raised the level of the water in
it more than two inches ; and one the roof of which was of copaiba balsam, threw out
all the gas to within I of an inch of its top ; while a tube of the same size, but sealed
at the other end, that stood by them, kept its level.

87. It appears to me the reason that we have not hitherto understood the phenom-
ena of endosmosis, or the action of these ternary arrangements, as I have called them,
has arisen chiefly from the employment of substances as barriers, which were possessed
of pores of sensible size. A moment's consideration will place this in its true light:
suppose two gases were kept apart by the intervention of a plug of charcoal, in their
diffusion into each other, not only would those portions pass the barrier which were
brought along by a direct action, but a much larger quantity would slip through by
mere leakage among the pores (36). Bladder, tissues, stucco plugs, &c., which we
know to possess pores of sensible size, are open to this objection ; but the case is very
different with liquids, which, from their uniform condition and the close proximity of
their atoms, admit of no such action. A mass of stucco a foot thick would be subject
to this kind of mechanical derangement, but a sheet of water reduced to that excessive
degree of thinness that it is invisible, allows no gas to go through it by leakage, but all
passes by absorption.

88. The original experiment of Dutrochet on endosmosis, and those of Dr. Mitchell,
were examples of this class of ternary arrangements. In these cases, membranes or gum
elastic were tied over the mouths of vessels, and the result was shown by the swelling
or sinking of the barrier. These can be repeated in a more satisfactory manner with
liquids (52).

89. In this experiment we also recognise an identity of results with those which hare
heretofore excited so much attention, under the title Endosmose ; but understanding iu
this case, as we do, the conditions under which the result is obtained, there is no dif-
ficulty in extending the explanation of one experiment to the other, Endosmose is only
a complex case of simple absorption. The mechanical results here obtained, the swell-
ing or sinking: of the barrier, depend on the more rapid absorption of one gas by that

30 DECOMPOSITIONS BY BINARY ARRANGRMKNTS.

barrier. The condition under which we obtain the mechanical result will, by being
duly varied, also furnish chemical results, an investigation of which forms our next object.

90. Chemical Decomposition; awrf,j/?7-A-^, iy binary arrangements. — A sohtary ar-
rangement of any kind, whether it be of a simple or of a compound nature, has no pow-
er of change in itself; but it is conceivable that one of the latter kind — compound — on
forming part of a binary arrangement, may be differently affected ; as an illustration, let
us take atmospheric air and water, appropriately situated, to form such an arrangement
(63). In this case, were the nitrogen and oxygen equally absorbable by the liquid, no
remarkable result would ensue ; but such is not the fact ; the oxygen gas passes much
more quickly into the water than the niti'ogen, and decomposition takes place, an ex-
cess of oxygen being in the liquid, and an excess of nitrogen being left. We should,
tlierefore, expect that rain, and dew, and springs, and rivers, which have been exposed
in a very divided state to the air, ought to contain a gas richer in oxygen than that of
the atmosphere ; and such, in fact, is the case, the atmosphere containing one volume
of oxygen and four of nitrogen, the gas of water containing one of oxygen and two of
nitrogen, as we shall shortly find.

91. Instead of a gas and a liquid to form these binary arrangements, a solid and a
gas may be used. Into 500 measures of atmospheric air, a piece of charcoal, that had
been made red hot and quenched under mercury, was placed. The volume of the air
experienced a rapid diminution, and after the absorption had gone on for several hours,
there remained 205 measures, 100 of which contained only eight of oxygen. The
charcoal was now introduced into water over mercury, and commenced very actively
evolving gas, which contained only 3-75 per cent, of oxygen, and the last portions of it
that were given off, only 2-8. Solution of lime was not capable of detecting the pres-
ence of carbonic acid in the water.

92. In the place of charcoal, other porous solids might be substituted ; into a jar, a,
which contained atmospheric air, there was introduced a piece of red-hot pumice stone;
into h, a piece of clay that had been made red hot ; and into c, a piece of charcoal
quenched under water. Absorption took place in them all, and in a quarter of an hour
fl was found to contain 19 per cent, of oxygen, shortly after &was found to contain 19
per cent, of oxygen, and c, in half an hour, only 18 per cent. Also, in five hours, c only
contained 17-25 of oxygen, and in seven days, only seven per cent; but, at the same
time, a and h contained 1450 per cent. Four days after, c contained only five per cent.

93. By long boiling, I extricated all the air possible by such a process, from a quan-
tity of water, and pouring it into a glass cup, left it exposed to the atmosphere for some
days ; at the end of that period the water was again boiled in a close vessel, and the
gaseous matter it had absorbed submitted to analysis. After the carbonic acid had been
carefully washed off, its amount being about 29 per cent., it was found that the residue
contained 32 1 per cent, of oxygen gas. It is a singular fact, that an aqueous mass, in
thus decomposing atmospheric air, appears to follow a very simple law; pure spring water
and distilled water, after a competent exposure to the atmosphere, are found to contain
a gas whose elements are not in the proportion of one to four, as in the case with the
atmosphere, but in the proportion of one to two. In several analyses of the air, extrica-

DECOMPOSITIONS BY TERNARY ARRANGEMENTS. 31

ted by boiling from the water of a spring, which flows from a sandy valley, and also
from the dews which fall on a neighbouring hill, but too remote to be affected by the
exhalations of dwellings, I found the proportion, when care was taken in the analysis,
to be uniformly 33i per cent., or as 1 to 2 by volume. This gas, thus extricated, is
isomeric with protoxide of nitrogen, with the particular exception that, in the protoxide,
the two volumes of nitrogen are compressed into half their bulk.

94. In a quart jar, which was filled with spring water and inverted into a tin cap-
sule, I collected all the aeriform matter that could be disengaged from the water by
means of a fire placed beneath the jar and its tin. This gas, from many prior trials, I
knew to contain 33 "j per cent, of oxygen. When all the gas was collected that could
be extracted, at a temperature long continued close upon the boiling point, the arrange-
ment was suffered to cool, and kept undisturbed for four days ; at the close of that time,
considerably more than three fourths of the gas disengaged was reabsorbed; the residue,
on analysis, contained 5-2 -5 per cent of oxygen only. A portion of the water in the
jar was now submitted to a boiling temperatiu-e in a small close vessel, and the gas col-
lected was analyzed. It contained, instead of 33 j, rather more than 47 per cent, of
oxvgen. There cannot, therefore, be any doubt that oxygen may be obtained from the
atmosphere, in a pure and undiluted state, by the action of a tissue, or a binary, and
also a ternary arrangement.

95. Decompositions by Ternary Arrangements. — After this consideration of the
case, in which two elements are employed, we are prepared to understand how ternary
arrangements effect decompositions. Let h (Jig. 13,J>1. 1) be a compound gas, which
is placed above a barrier, a, of such a nature that one of the elements of b shall pass
more rapidly through it, or, in other words, be more readily absorbed by it than the
other. Also, lei the other substance, c, which is on the opposite side of the barrier, be
of a kind capable of removing the quicker passing element of b from the under surface
of a, as fast as it arrives there. It is immaterial how this removal be accomplished,
whether by chemically uniting with it, or by mechanical action ; the quick passing el-
ement, finding at its approach to the under surface of the barrier a ready exit, continu-
ally passes off, and its place is supplied by fresh portions from above, so that, in the
lapse of time, only the less absorbable element will be found in b.

96. The general conditions, therefore, of chemical decomposition by ternary arrange-
ments are, that one element of the compound to be decomposed shall pass more
easily through the barrier or bounding tissue than the others, and, on its arrival at the
opposite side of the barrier, it shall be rapidly removed.

97. Reasoning upon this principle, I succeeded, nearly two years ago, in effecting
decompositions in this manner, which have some important physiological applications.
Having taken a tube, one of the ends of which was expanded into a trumpet-shape, and
closed with a thin serous membrane — peritoneum stripped from the liver — which was
tightly tied on v^^th a waxed thread, while it was wet, I poured through the orifice,
which was open, a strong but clear solution of litmus in water. The tube thus situated
was placed in a wine-glass containing strong alcohol, and the level of the liquid, inside
and outside, made to coincide. The conditions for decomposition were thus fulfill-

32 ^ DECOMPOSITIONS BY TERNARY ARRANGEMENTS.

ed ; the water could find a ready passage through the serous membrane, but the col-
ouring matter could not. Now, on arriving at the under side of the membrane, the
water either was removed by uniting chemically with the alcohol, or by sinking me-
chanically through it to the bottom of the glass. Complete decomposition was effected,
all the colouring matter being retained above the membrane, and, on placing a candle
on one side of the glass and the eye on the other, dense striae of colourless water were
seen passing through the alcohol, but not a particle of the litmus escaped.

98. Under this condition, those experiments which have been instituted to demon-
strate the passage of colouring matter through the lacteals have been made. The lac-
teals do not open into an intestine with patulous mouths, but their lining membrane of
serous tissue ends bluntly in a kind of cul-de-sac. Through such a membrane, litmus,
indigo, &c., cannot penetrate, though water may find a ready passage. Hence, be-
cause we cannot colour the chyle by an injection of Htmus or indigo water, it is not to
be inferred that no medicine can pass from an intestine into the lymphatic system ; the
experiment now detailed goes to prove directly the reverse, and furnishes us with an
explanation of the uniformity of colour of the fluid in the chyliferous vessels.

99. An important circumstance in gaseous analysis may here be noticed. If a tissue,
in the act of transmitting gas, or ready to do so, be placed in contact with another gas
of a different nature, disturbance immediately ensues. A cubic inch of nitrogen gas,
made with phosphorus, but which was found to be contaminated with 4| per cent, of
oxygen, was agitated briskly in a vial containing about an ounce of spring water, such
as has been mentioned to contain a gas ^ oxygen. In one minute the nitrogen gained
one per cent, by the agitation. The same quantity of nitrogen gas, agitated in a pint
of water, gained no less than 11 per cent, of oxygen, which it had taken from the rich
gas of the water. Nor is agitation or mechanical violence necessary to produce this
important result. Into a bell filled with water, and inverted into another vessel, so as
not to touch it in any point, I threw 100 measures of a gas, 85 of which were oxygen.
After four weeks an analysis was made, and the gas in the bell found to contain only 72
per cent, of oxygen, the remainder being nitrogen. In this way, too, in the lapse of
time, from an inverted vessel, partially filled with atmospheric air, the oxygen will es-
cape into the water, and thence into the atmosphere ; and I have twice known this
event to take place, so that the residue did not contain more than three or four per
cent, of oxygen. In many of the most delicate researches of chemistry, we have this
disturbing cause in operation. Water is universally employed in our laboratories as a
means of confining gases ; it enters largely into our processes of pneumatic manipula-
tion ; and though we have hitherto neglected its action, it silently disturbs all our re-
sults. An air-bell cannot pass to the top of a jar without instant contamination : du-
ring its residence there it is subject to a continued succession of changes — at no two
moments is it the same in composition — a perfect freedom of communication existing
between it and the atmosphere.

100. As an instrument of rigid analysis, the pneumatic apparatus, so arranged, requires
to be used with circumspection. It is impossible to keep oxygen, nitrogen, or any other
gas in its original purity, if confined by water. This fluid, which, when reduced to a

DECOMPOSITIONS BY TERNARY ARRANGEMENTS. 33

thin, imperceptible film, is instantaneously penneated by almost every substance, under-
goes the like action in course of time, even in deep masses. Gases are absorbed by it,
and thrown off by it in its purest state ; how much more compUcated, then, must its
action be in that impure condition in which it is commonly used. Connected with this
point there is another : if a series of bells stand on a pneumatic trough, each will affect
all the others, communicating a part of its contents, and receiving from them in return.
A jar, containing binoxide of nitrogen, stauding by the side of one containing com-
mon air, seriously affects it I have noticed two common tumblers, filled with these
gases, and so placed, communicate with each other so fi'eely, that in 17 hours the tum-
bler originally filled with atmospheric air contained only 9f per cent of oxygen. The
habit of collecting gases at the same trough, that is destined to preserve others, is very
exceptionable ; we place the disturbing agency in circumstances the most favourable
for its action. All operations of washing are Uable to the same strictures.

101. We have assumed it as a law of nature, that any substance, when placed in con-
tact with another, has a tendency to diffuse into it.

102. It is to be remarked in reference to this, that no hypothetical cause is assumed;
it is merely taken as one of those ultimate facts which the progress of knowledge has
not explained- We do not consider whether it involves the position that two bodies
can exist in one place at one time, nor do we deny the impenetrability of matter.
But it is required of us by a crowd of facts to admit this law, as the only legitimate
position on which they can be explained. We know nodiing of the size, or figure, or
condition of the ultimate atoms of bodies ; there are, indeed, some circumstances which
would lead us to suppose that, even in the densest structures, each particle is at an
immense distance from those that are next around it, in comparison with its own
diameter. In those interstices which must necessarily exist, these phenomena of ab-
sorption may take place in accordance with laws which obtain among the molecules
of bodies. In the same way that a comet comes down from the regions of space and
traverses a planetary system, receiving impressions greater or less from each star that
it passes, and emerges back again untouched and unimpaired; so a gaseous particle
may pass through the system of atoms that constitute a solid mass, and moving therein
unimpeded and without contact with any of them, may emerge without change of
physical condition, or only a mark that its motion has been subject to those laws which
obtain in the system through which it has gone.

103. All these observations go to establish the point, that pores of a sensible size
have nothing to do with endosmosis — that it is a phenomenon depending simply on
absorption. Xo one would aver that water possessed any apertures, or vessels, or tubu-
lar arrangement.

104. The experiment of (80) does not alone prove that endosmosis takes place
through liquids and tissues the pores of which have no sensible size; it has a much more
interesting appUcation. Physiologists know that the primitive form of all organic bod-
ies is an imperforate vesicle or globule, having the power of absorbing those substances
which are around it, and decomposing them. The ultimate vesicle fields to analysis
carbon, the elements of water, and a few salts. It is a centre of vital activity, a

£

34 • IMPORTANCE OF CAPILLARY ATTRACTION IN PHYSIOLOGY.

laboratory assimilating things for its own substance. The simplest plants, confervae,
tremellse, and the simplest animals, consist alone of this structure. Let us observe
how nearly this vesicle agrees, both in its constitution and mode of action, with the
vesicle of (80). Like that, it is not only an imperforate cell, but also consists of simi-
lar elements. The properties which the organized vesicle is supposed to enjoy are
met with in the fullest extent in that which is not organized. Both have powers of
endosmosis, and a species of assimilation of things exterior to their own substance.
What property has the lowest order of animal and vegetable Ufe which that bubble
does not possess ? A thing thus endowed with vitality may well excite our interest ;
it breathes, it is nourished, it exhales.

105. By referring the phenomenon of endosmosis to absorption, such as has been
recognised by chemists, we advance one point in the simplification of our knowledge.
It gives us also a better idea of the specific action of tissues, as depending on structural
arrangement, and presents an intricate problem in its easiest form for solution ; more-
over, it is, as I know by experience, a safe guide in experimental research. We can
hardly doubt that the forces bringing about the result indicated in (80) are the same as
those which operate in Dr. Mitchell's experiment, where India-rubber is used as a bar-
rier ; and if that result receives so ample and so easy an explanation upon this doc-
trine, why should we hesitate to apply it to the other? But the composition, structure,
and habitudes of a thin, watery film, are much better known than those of a lamina of
India-rubber : we can reason with certainty respecting the one, and vary its composi-
tion to suit the purposes of experiment ; the other affords no such advantage. If, how-
ever, it should eventually be found that the simple doctrine of absorption is not suffi-
cient to explain all the phenomena of endosmosis that may hereafter be discovered, this
paper will at least prove that the cause of those phenomena is not alone enjoyed by
organic and solid tissues, but also by liquids and substances witlwut organization.

CHAPTER V.

THE PHYSICAL THEORY OP CAPILLARY ATTRACTION.

{From the American Journal of the Medical Sciences for February, 1838.)

Contents : Importance of Capillary Attraction in Physiology. — Capillary Attraction
is an Electrical Phenomenon. — Its Physical Theory. — The Effect varies with Varia-
tions of Electric Disturbance. — Takes place between Bodies of different Forms. —
Physiological Illustrations.

106. It has been alleged, as a bar to all physiological investigation, that the phenom-
ena of Ufe are of so peculiar a nature, that we must necessarily forever remain ignorant
of their causes ; that, unHke physical phenomena, which are of a simpler kind, and more
within the reach of human understanding, there is something in these inherently myste-

IMPORTANCE OF CAPILLARY ATTRACTION IN PHYSIOLOGY. 35

rious and incomprehensible. This unphilosophical impression exists not only in the
minds of the \Tilgar, but has extended itself to men well trained to scientific research ;
it is to be found in the writings of the most eminent physicians, and often affords a
plausible screen for professional ignorance. Of all the sciences, medicine is the last to
profit by the analytic method — a method which has raised other departments of knowl-
edge to their present rank. Its cultivators pursue the same course of synthesis which
was pursued in the days of the Greeks — ^they reason from hypothesis to fact, instead
of from fact to hypothesis.

107. It may, however, be boldly declared, that the science of life is not more occult
than any other of the sciences. We may, by proper investigation, carry it as far ; and
we shall only stop short at the very same point which has proved impassable in them.
Of final causes we know nothing; the immediate agent of life is not more obscure
than any of the remote physical agents. If we cannot assign any reason why a seed
germinates, can we tell why a stone falls to the earth ? is the one phenomenon any more
comprehensible than the other ! If we cannot tell how it is that one parent should
produce a countless offspring, each of which has the power of reproducing beings like
itself, neither can we tell how a spark produces an extensive conflagration. It avails
us little to say that the principle of life, like the principle of heat, possesses a radiant
character, or has a power of self-production. We are equally ignorant how the wide-
spreading flame results from a spark, and how countless myriads of seeds have origina-
ted from one primordial germ.

108. Some parts of the science of physiology are doubtless within the reach of scien-
tific investigation. Most of the functions of organic Ufe are of this character. Absorp-
tion, secretion, circulation, and respiration are carried on through the medium of tubu-
lar arrangements of different kinds, endued with specific powers. We are not well in-
formed of the nature of these actions, nor of the force giving rise to them. The changes
taking place in organic structures partake partly of a mechanical, partly of a chemical
aspect, bearing some similarity to other physical changes effected by known agents, yet
not identical with them. Some have supposed that the attraction of affinity, or the force
of capillarity, was the power in question, operating in an unusual manner, under unusual
circumstances ; but the majority of medical writers have cut the knot, instead of untying
it, and assert that it is a peculiar force, recognised under the title of vital force, life, or
nature.

109. It is, however, most unphilosophical to resort to these vain explanations, which,
after all, afford us no information, substituting only obscure terms as the causes of events
not more obscure. Had we approached the problem of pore-action in the same spirit
that has led to the development of the causes of magnetic action, a similar and equally
striking advance would have been made.

110. Capillary attraction, considered simply as a mechanical force, is not competent
to produce those changes which the pores and narrow cylinders of organic structures
give rise to. The products of glandular action are chiefly compounds of a definite
number of equivalents, bearing a strong resemblance to the products of ordinary chem-
ical action ; but still the operation of capillarity as a force producing motion is undeni-

g,g IT IS AN ELECTRICAL PHENOMENON.

able. Can it also produce chemical changes 1 Is it simply a manifestation of the elec-
tro-chemical relations of matter ?

111. Previous to entering at large into an examination of the laws of pore-action,
this query will demand an answer. We shall find, from what follows, that capillary at-
traction is a force nearly allied to, if not identical with, chemical affinity. Now the in-
vestigation of the problem of pore-action naturally divides itself into two parts. 1st.
The mechanical conditions of equilibrium and movement of fluids residing in tubes of
narrow diameter, but of any length. 2d. The chemical changes which fluids so situ-
ated undergo,

112. The identification, therefore, of the force producing the mechanical effect,
with that producing the chemical changes, is a most important point, and to this I shall
direct my attention.

113. There are two phenomena of capillary attraction, the conditions and circum-
stances of which are well known : the rise and depression of fluids in tubes of a cer-
tain diameter, and the adhesion of flat solid plates to the surface of fluids. From the
former of these this kind of attraction has derived its name; the latter furnishes us with
the means of making researches, devoid of ambiguity, in reference to the physical cause
of capillarity.

114. If a circular disk of glass, or any other solid substance (^g. 15, pi. 1), a b, be
placed on the surface of any fluid, ef,hy means of a handle c, it will adhere thereto
with a certain force, which may be measured by means of a balance, but which is suf-
ficiently evident when attempts are made to lift the disk with the hand. This force is
known under the name of capillary attraction. An investigation of its physical cause,
and the laws respecting it, involves the fundamental propositions of pore-action and
passage through tissues.

115. The phenomena of capillarity are brought about by electricity operating under
peculiar circumstances. They are due to a disturbance of the electric equilibrium, and
hence are intimately allied to all kinds of chemical and vital changes.

116. Let a h (^fig. 16) be a glass plane reposing on the surface of mercury, c d, con-
tained in an insulated vessel, and capable of being elevated by an insulating handle, e ;
let the mercury be connected with an electrometer, yj by means of a wire. Now, so
long as the glass plane and the mercury are in contact, the electrometer evinces no dis-
turbance ; but as soon as the plane a b is raised by its insulating handle, electricity is
instantly developed, and the gold leaves diverge. As there was no electrical excitement
while the plane and the metal were in contact, it is a legitimate inference that the elec-
tricity now developed was the cause of their strong attraction or adhesion ; and this is
corroborated on taking the glass plane to another electroscope, when it will be found
that it is electrified positively and the mercury negatively ; and that, consequently, when
they are brought into the vicinity of each other, a powerful attraction ?nust result.

117. A cause of attraction being thus developed, it would be very unphilosophical
to seek for other agencies where one so competent to produce all the effects is observed
to exist. For in every case where a solid plane reposes on the surface of a fluid not
wetting it, a large amount of electricity of very high tension is produced, the electricity

I

ITS PHYSICAL THEORY. 37

of the surface of the plane heing always opposite to that of the liquid. They must,
therefore, attract each other. I express here only a fact, not involving any disputed hy-
pothesis whatever, as to whether that development of electricity originates in the mere
contact of the bodies, their chemical action, or any other cause ; but it is a fact, that
when any sohd reposes upon any fluid, provided its surface does not become wetted, a
development of electricity uniformly takes place, and a powerful degree of attraction
must necessarily eusue.

118. The postulate here introduced requires explanation, for electric excitement is not
observed if the solid surface is wetted. SoUds bear a peculiar relation to liquids, being
wetted or not wetted by them. Most solids, for instance, are wetted by water, and but
few by mercury ; the surface of the glass is readily moistened by alcohol or oil, but not
by melted sulphur or mercury ; hence the latter, from its not adhering to the skin, was
called by the older chemists aqua non madefaciens manus. The circumstance that no
electrical excitement is observed whea a solid surface is wet, might appear, at first sight,
contradictory to the hypothesis here assumed. A more accurate examination, how-ever,
places it in a very different light, and shows that the phenomena observed are exactly
such as they ought to be hypothetically. If a disk of glass is placed on the surface of the
water and then removed, the gold leaves of the annexed electroscope are not affected, for,
strictly speaking, no rupture has taken place between the solid and the fluid ; the thin
film of the latter in contact with the former still remains so : it is only the cohesion of
the watery particles that is overcome, not the adhesion of the solid to the fluid, and
hence no electrical development appears.

119. Geometers have shown the exact relation a solid must bear to a fluid to be wet-
ted by it. It results from the mathematical investigations of Clairaut, that if the at-
traction of the particles of the solid for those of the fluid is more than half the attrac-
tion of these last for each other, the solid will be wetted ; but if it be less than half, the
solid will not be wetted. An experimental proof of this may be obtained by counter-
poising a disk of glass, at the end of one of the arms of a balance, by weights in the
scale, and then lowering it on the surface of some mercury in a cnp ; it will be found
that a certain weight must be added in the scale to detach it Next, in place of the
disk of glass, substitute a plate of amalgamated copper, of the same size and weighty
and ascertain the force required to detach it; this will uniformly be found more than
double the former weight. The first weight expressed the attractive force existing be-
tween a surface of glass and mercury ; the second, the cohesion of a cylinder of mer-
cury of the same diameter, and the numbers obtained experimentally corroborate the
investigations of ClairauL

120. I dwell on this part of the phenomenon because it is of no small importance ;
the same conditions that determine whether or not the surface of a solid is to be
wetted, determine also whether a liquid shall pass through a pore, and move forward
in a capillary vessel.

121. The difficulty arising from the non-development of electricity, where the solid
surface is wetted, being thus dismissed, we next inquire whether the hypothesis here
assumed will give numerical results analogous to those procured by experiment; in

3g THE EFFECT VARIES WITH VARIATION OF ELECTRIC DISTURBANCE.

Other words, if two solids which adliere to a certain fluid, with forces differing in.
amount, develop upon rupture quantities of electricity in the same ratio. As a general
result, the balance and electrometer prove that this is the case. Bees' wax, which ad-
heres to mercury with much less force than gum lac, develops likewise much less
electricity. Gum lac, which adheres less strongly than glass, Ukewise develops much
less electricity ; but when we attempt to run a comparison in this manner among a
series of substances, we find there are many disturbing causes which, in most cases, in-
capacitate us entirely from making comparable results. Much depends on the relative
conducting power of the surface employed. A plate of iron may be separated from a
surface of mercury, which does not wet it, with a very small disturbance of electric
equilibrium, arising from the high conducting power of the metalUc plate, which enables
a transfer of any free electricity to take place if the plate should tilt on one side, or any-
thing affect its horizontality during the act of separation. In proportion as the con-
ducting power increases, although the force of adhesion may remain the same, the total
effect on the electrometer should diminish ; and this is agreeable to experience. Again,
the presence of moisture on any part of the touching surfa-ces will vitiate the results ;
partly owing to its high conducting power, but chiefly to the circumstance that it hin-
ders the surfaces under trial from ever coming into contact.

122. The circumstance of this great variability in the amount of developed electricity
is in itself strong evidence of relationship between the supposed catise and the effect.
Gay-Lussac found that it required a weight, sometimes of 158, and sometimes of 296
grammes, to detach a certain disk of glass from mercury, depending on causes which
were not very apparent. An effect thus differing in amount indicates a cause of like
variability, or subject to many disturbances.

123. I regard, therefore, the agent bringing about capillary phenomena as identical
with that producing chemical action, and both as being due to electricity. The force
of cohesion bears the same relation to both, acting on both as a disturbing power.
Nay, we may even take a much more extensive view of the matter, and from the ratio
these forces bear to each other predicate the effect of their combined action, which may
be classed under three distinct heads.

1st. If the force of attraction of the particles of a solid for the particles of a fluid be
not equal to half the cohesive force of the latter for each other, the fluid will refuse to
pass through a pore of that solid substance, and in capillary vessels consisting of it will
be depressed below its hydrostatic level.

2d. If the force of electric attraction of the particles of a soUd for the particles of a
fluid exceeds half the cohesive force of the latter for each other, but is not equal to the
whole force, the fluid will pass through a pore formed of that solid substance, and in a
capillary tube of it, will rise above its hydrostatic level.

3d. If the force of electric attraction of the particles of a solid for the particles of a
fluid exceed the whole cohesion of the latter, chemical union ensues.

124. In thus assimilating the force producing pressure on planes and motion in nar-
row pipes, with the force producing chemical changes in the constitution of bodies, a
great advantage is gained in simplifying physiological investigations in respect of the

TAKES PLACE BETWEEN BODIES OF DIFFERENT FORMS. ^

action of capillary systems. It is an electrical force that determines all kinds of con-
stitutional changes developed in bodies by the chemistry of organic life, and it is a
manifestation of the very same force that carries some fluids along the almost invisilile
vessels of living structures, and denies to others a passage. All the phenomena of inor-
ganic chemistry are the result of the balancings of the force of cohesion on the one
hand, and electrical attraction on the other. If Berthollet was wrong in supposing
that chemical affinity, as an acting force, had no existence, other chemists have equally
erred in supposing that all kinds of changes, without any Umitation, were due to
it Whether we investigate the phenomena of chemistry or of capillarity, we have
the same forces to deal with, acting as antagonists to each other ; and hence the whole
effects imputed to capillary attraction may be regarded as belonging to that extensive
class which the science of chemistry considers.

125. There is a variety of facts recorded by wTiters on capillary attraction, which an
application of these principles readily explains, though hitherto they have been regarded
by philosophers as remarkable anomalies. Such is the observation of Hi vgens, that
it was possible to cause mercury to stand in a barometer seventy inches high ; or that
of P. Abat, of a singular deviation in the hydrostatic level of the same fluid in different
branches of a siphon.

126. Capillar)' attraction does not take place only between solids and fluids ; it is
exhibited when solids alone are made use of. In virtue of this power, two pieces ot
lead cohere with great energy to each other, as also is the case with two planes of pol-
ished stone or plates of glass. When glass is used, electricity of very high tension is
readily detected, one of the pieces being positive and the other negative ; it would, I
suppose, hardly be denied that the force operating in the case of glass is also the force
that operates in the case of stones. Is it not, then, a legitimate supposition, that the
adhesion of two pieces of lead is brought about by the same agent, the presence of
which Is masked by the high conducting power of the metal ?

127. Between solids and gases capillary action likewise takes place. On the sur-
face of all kinds of solids atmospheric air remains in a state of condensation, as is made
evident when such bodies are placed beneath water under an exhausted receiver ; the
air appearing in copious bubbles, studding the surface of the metal

128. Now having a power the operation of which over inorganic masses is so exten-
sive, it is for us to inquire how far the phenomena of oi^nic systems depend upon
its working. Those numerous pores, and pipes, and capillary vessels which abound in
all kinds of living structures, but of the action of which we are so ignorant, point out to us
capillary attraction as one of the great forces in play, determining all kinds of motions
and physical changes. To identify the force producing motion of a mechanical char-
acter with that effecting physical change, gives a unity to the action of powers which
have hitherto been multiplied without avail, and stamps simplicity and symmetry on
actions that are very diverse.

129. It is not alone in the vital fiinctions that we meet with applications of the prin-
ciples of capillary action ; the mechanical functions furnish numerous instances. The
organs of progression of some animals which delight to walk upon water are provided

^Q PHYSIOLOGICAL ILLUSTRATIONS.

with an apparatus of hair, calculated to repel that fluid ; hence gnats and certain other
insects have no difficulty in passing over the surface of water. By the same means the
hydra suspends itself, without effort, in that element ; for having exposed for a time the
extremity of its foot to the air, so that it may become dry, it, by repulsion, forms a cup-
shaped hollow around it, the head of the insect hanging down in the water beneath.

130. Organs of exhalation and absorption are unquestionably capillary systems.
The stomata of plants, which botanists suppose to discharge these functions, are of this
character ; they furnish a well-marked instance of the accommodatiori of apparatus to
suit physical conditions. Plants growing beneath the surface of water have no stomata ;
but if, by any means, they reach the atmosphere and vegetate in it, these organs are pro-
duced for the purpose of discharging, under the new order of things, offices which were
accompUshed by other means. The spongioles of roots, acting as capillary systems,
drive the fluids they absorb from the earth, through the tubular vessels of trees, with a
force of several atmospheres, extending themselves at a due distance from the trunk,
where they may meet with the water that falls from the leaves. In some orders of
living things, which are not accommodated with distinct orifices for the reception of
food, nutrition is accompUshed by capillary systems. In this manner the jwi-ifera ex-
pose a wide surface to the seas, and draw in nutrient matter through their microscopic
pores, discharging the surplus, as excrementitious matter, through their papillary orifices.

131. Like the lungs of the mammalia, the leaves of trees are respiratory organs, com-
posed of capillary systems ; their mechanical functions are not so complete, though
their chemical functions may be identical. They demand no nervous cords to be spread
upon them to give them motion and keep up their play ; the breezes in which they
tremble perform the office of carrying off" the exhaled impurity ; and the rays of the sun
furnish them with their vital force, enabling them to effect the decomposition of carbonic
acid, and provide a store of carbon for the purposes of the economy.

132. In identifying the mechanical with the chemical force of organic structures, we
see another proof of that unity of design existing through the entire range of living
things. Functions of all kinds are accomplished by arrangements of every sort in dif-
ferent classes, yet no one will deny that they all follow one original type. Digestion,
as it takes place in the stomach of man, appears a highly complex phenomenon, de-
pending, as some say, partly on the tissue action, partly on nervous, and partly on oth-
er powers. But are not analogous changes wrought without all this complexity of ap-
paratus in the hydatid, which may be taken as the elementary type of the stomach ; or
in the taenia, which is a colony of stomachs \ The polygastric infusorials, some of
which have hundreds of these organs, and even the mammalia, do not digest more per-
fectly than the hydra, a carnivorous polypus, which may be turned inside out without
detriment. The laws of digestion followed by the one, are followed, too, by the other.
If the organ of the one respects the presence of living matter, and refuses to act on it, so
does that of the other ; yet the one is furnished with a highly complicated assemblage of
muscular bauds, of glandular apparatus, of bloodvessels, of nerves, and the other is not.

] 33. In the higher orders of life, processes are carried on by multiplied apparatus,
without, however, deviating from the principle of the original simple type. The gift of

PHYSIOLOGICAL ILLUSTRATIONS. 41

a new faculty, or the addition of a new organ, brings with it a corresponding change
in the arrangement of the whole plan. An engineer, who wishes to adapt a machine
to the execution of some new task, alters every part, no matter how remote it may be
fi-om the acting point, until every wheel and lever executes its work co-ordinately with
all the others ; the prime mover remains unchanged, though the general character of the
machine may have undergone a renovation ; and as all machines, no matter of how
many parts they are composed, nor of how many wheels they consist, nor how intri-
cate soever may be their resulting motions, may have their power reduced to and rep-
resented b}- a simple lever, so also organic functions, though often brought about by
highlv complex arrangements, find simple representatives in the lower orders of life. A
concentration, or a development of any organ, is often demanded by change in a re-
mote part of the fabric, when even the connexion may not be very evident Animals,
consisting simplv of digesting cavities, require no vascular sjstem for propelling or con-
taining a nutritious fluid ; they are not in need of separate tissues devoted to its oxyge-
nation, nor of au insulated respiration, nor do they demand distinct biliary organs ; when
the nutritious chyle is produced in the stomach of zoophytes, it finds its way into the
inter-cellular spaces, and there circulates without vessels, undergoing through the external
tegument the chemical changes. In many insect tribes, the bronchial tubes are spent
upon the peritoneum, and respiration takes place directly upon the alimentary canal.
AVith modification of functions, change of external figure is always involved ; and as
these progress together, svstems of living things are constructed, referrible to one com-
mon original type. It is thus, in the echinodermata, we trace up successive steps, from
the sea urchin to the asterias, and from that to the pentacrinite ; a development of the
same parts of the structure continually taking effect, until the extremes bear no sort of
resemblance to each other.

134. Had the production of living things been effected by the operation of second
causes, we might look, with Lamarck, for some law of successive development which
should contain the origin of each order and species. We might regard the rudimentary
teeth of whales, or the sub-cutaneous feet of the ophidia, as abortive results of such a law.
Considering the brain as a development of the spinal axis, we might trace in the form
of the cranial bones a development of a system of vertebrae, brought about as a conse-
quence of the very same laws. We might run a parallel of analogies between the crus-
taceous and vertebrated animals, and exogenous and endogenous plants ; we might take
the cephalopodous mollusks as furnishing the first rudiments of an internal skeleton, and
trace its increasing complexity to meet certain ends until its perfect development in the
mammalia. In this latter class, we might dwell upon the uniform existence of seven
cervical vertebrae, as gi^'ing evidence of a persistence in the plan of structure in spe-
cies so remote from each other as the camelopard, tlie whale, and the mole. Parting
from the dorsal vessel of insects, the first rudiments of an aorta, we might follow out
the complications of the higher arterial systems. In all the varieties of respiration,
whether aquatic, aerial, or mixed, we might see the reproduction of one original chem-
ical design, and in every instance of a concentration of machinery or fiinctions, we
might find an impress of the action of external formative agents.

F

42 PHYSIOLOGICAL RELATIONS OF CELLULAR TISSUE.

CHAPTER VI.

ON THE GREAT MECHANICAL FORCES GENERATED BY THE CAPILLARY ATTRACTION OF

CELLULAR TISSUE.

{From the American Journal of the Medical Sciences for May, 1838.)

Contents : Physiological Relations of Cellular Tissue. — Force with ichich Gases and
Liquids pass through Cellular Tissue. — Disturbing Action of Leakage. — The Capil-
lary Force overcomes powerful Mercurial Pressure. — Dalton's Hypothesis. — The Tis-
sue is the Origin of the Force. — Its Absorbent and Condensing Action. — Voltaic
Batteries may be used for producing great Pressures. — Gases pass when resisted by
the Force of many Atmospheres. — The condensed Gas acts as a Vacuum. — Co-ordina-
tion of the Results of Dalton, Graham, and Mitchell. — Disturbing Agencies. — Dis-
turbance by Variation of Temperature. — Physiological Experiments arid Remarks.

135. Of all bodies, those alone are capable of exhibiting the phenomena of life which
consist of a cellular structure. Identity of chemical constitution does not appear to be
essential, yet it is only a limited number out of the long list of chemical elements that are
capable of organization ; these, if left alone to satisfy the conditions of their affinities
undisturbed, would most commonly give rise to the production of water, ammonia, and
carbonic acid. Life, therefore, in this point of view, has no other action than to disturb the
play of tbese affinities, and force the elementary atoms into other forms of combination;
it depends upon the success of this action whether a living or inorganic mass shall
result. A living body is endued with a pecuharity of form, and does not require an
identity of composition ; an inorganic body depends for its nature on certain and definite
composition, without auy relation to structure. It is true that most bodies, whether ele-
mentary or composite, exhibit a marked tendency to geometrical arrangements, and
all crystallizations are brought about by the operation of polar forces, but an inorganic
compound body does not of necessity require any peculiar crystalline shape, or other
form, for existence.

136. Life, then, is a state of force; the system of nature presents us with but four
of the chemical elements subject to it, for we are taught to make a distinction between
crystalline arrangement and living structure. We have not any direct evidence to show
that all simple substances are in any wise obedient to the laws of vitality, or that, when
they assume symmetrical arrangements round an axis, that it is an approach to organiza-
tion, an imperfect organization depending on the sluggishness of their character or the
incompetency of the vital forces to control the range of their affinities ; nor is there any
pr.iot that the laws directing the atomic arrangement of macled crystals bear any sort
ot analogy with those that direct the structural deposite of the radiated class of animals.
It is true that the passage of a polarized ray of light through transparent crystals has
disclosed to us the fact that their atomic constituents are held together in a state of

FORCE WITH WHICH GASES AND LIQUIDS PASS THROUGH CELLULAR TISSUE. 43

force, and we judge from the phenoraeDa of their nodal lines, when they are thrown
into vibration, that their elasticity varies in different parts ; yet the mere fact of their
permanence assures us that they are in a state of stable equilibrium. On the other
hand, organized structures are in a condition of instable equilibrium, and require a con-
tinued series of adjustments for the perpetuation of their existence. In the crystal, the
electrical or polar forces have compensated one another, and its particles being brought
into a state of rest, continue so without change; while in the living being their situation
is only momentary; they are subject to incessant vicissitude and change; their place
has to be supplied by new material ; and to accomplish this end, electrical currents
traverse the body in all directions, and machinery more or less complex is employed
to bring new matter and carry the effete away.

137. Does this cellular or areolar structure, which appears to be the essential habitat
of vitality, owe its properties to the residence of a peculiar force, or are they derived
from its organization I If the latter, we ought to find it possessed of remarkable char-
acteristics, of forces arising from the aggregation of particles.

138. It has been known for some years that gases and liquids pass through porous
structures with a considerable force. If over the mouth of a cylindrical jar a thin sheet
of India-rubber is tied, and the jar exposed to an atmosphere of ammonia or pro-
toxide of nitrogen, in the course of a short time, by the ingress of a portion of the ex-
ternal atmosphere, a pressure is created tending to rupture the membrane outward.

139. That the force exerted in this case is very great, appears from the following
experiment : In a cylindrical jar, abed {^fig. 17), four inches long, and one and a quarter
in diameter, a siphon gauge, e, was placed, and over the mouth of the jar a piece of In-
dia-rubber fortified by a layer of stout cloth was tied. Two pieces of tape, crossing each
other at the top and passing down the sides of the jar, were knotted as tightly as possible
at its bottom, and the arrangement was then exposed to an atmosphere of ammonia.
In the course of six hours, the India-rubber, notwithstanding it was forcibly held down
by the cloth and tapes, began to stretch upward, and the gauge had risen thirteen divisions
of an arbitrary scale attached to it. In twenty-four hours it had risen to nineteen and
a half, and, finally, to twenty, after which it remained stationary. On estimating the
divisions of the scale, after the experiment was over, it was found that the maximum
pressure in this case was about two thirds of an atmosphere, or ten pounds on the
square inch.

140. This effect is not confined to gases, but takes place with equal energy when
liquids only are used. In a jar containing alcohol, a gauge was placed, and a piece of
human peritoneum was stretched over the mouth, fortified by silk. The whole was
then sunk into a vessel of water. In twelve hours it was found that the level of the
fluid in the gauge had risen the whole length of the scale, and that when the maximum
pressure took effect, the gauge was exhibiting a condensation of one atmosphere exactly.

141. Here, then, we have proof that the passage through tissues is accomplished
with a degree of energy indicating that the forces which produce it are of a very high
intensity. To measure these forces, or to obtain some approximation of their value,
the following researches were made.

{

44 DISTURBING ACTION OF LEAKAGE.

142. Before, however, proceeding to the detail of these experiments, it is necessary
to allude to certain disturbing circumstances which take place, arising from extraneous
mechanical action, and vitiating the result. One of the most prominent of these is due
to the general leakage which happens through the open pores of all tissues ; a leakage
which is to be distinguished from the proper capillarj transit. If, for example, a bar-
rier of peritoneum be placed over the mouth of a vessel of water, under ordinary cir-
cumstances the escape of the water will be prevented; but if a pressure gradually in-
creasing be exerted on the water, it will rapidly ooze through every pore, and finally,
if the membrane stand the strain without rupture, will spirt through those of a large di-
ameter. This effect, to a greater or lesser extent, takes place wherever tissues have to
resist mechanical pressure ; the amount of disturbance arising from it depends mainly
on the diameter of the pores of the structure.

143. In the experiment related in section 139, we have a well-marked instance of
this disturbance. It might be inferred from that experiment, that the force with which
water passed through a piece of peritoneum into alcohol was not greater than one at-
mosphere ; whereas, in truth, it was much more ; but, as soon as the pressure within
the vessel by the infiltration of water had amounted to about one atmosphere, the alco-
hol escaped from the vessel as rapidly as the water entered, by general leakage from
the whole surface of the membrane, and the gauge, therefore, gave no evidence of the
passage of the liquid. Nor are very porous structures alone liable to this accident; the
experiment of the old Florentine academicians shows, that even through the pores of
gold, one of the densest of the metals, fluids under a severe pressure will find their way,
as appeared when they attempted to compress water in a globe of that metal.

144. This accidental passage through pores may be made visible to the eye by con-
densing about one atmosphere of air into a vessel whose mouth is closed by a sheet of
India-rubber, and then placing it in a jar filled with water ; small bubbles of air will be
seen escaping from every part of the India-rubber, and passing in great numbers through
the water.

145. It has just been stated, that the force with which water passes through a mem-
brane into alcohol is much more than one atmosphere; this may be proved by making
use of a barrier of a stouter fabric than the peritoneum here mentioned. A piece of
bladder being used in lieu of it, the gauge indicated, when the pressure was a maximum,
a force of 1-8 atmospheres ; but even this cannot be taken as the true value of the
force, for a certain period of time elapses, amounting, in this instance, to almost two
days, before the gauge reaches its highest point ; and when that is gained, the alcohol
has become considerably diluted, and agreeably to a law which will hereafter be pointed
out, the amount of force rapidly diminishes as this takes effect ; for, as soon as the
composition of the fluids on both sides of the bladder is the same, provided the temper-
ature of both is aHke, and no mechanical disturbance arises from unequal pressure, all
motion either way ceases, and this may happen long before the column of fluid in the
gauge has reached its highest point.

146. The air gauge, however, at the best, is a very imperfect indicator of the force
with which gases or liquids mingle, for it will remain stationary, even when the passage

THE CAPILLARY POWER OVERCOMES POWERFUL MECHANICAL PRESSURE. 45

is taking place with very great force, provided the rate of the bodies on both sides of
the barrier is the same. It gives erroneous results in all those cases where the me-
chanical leakage exceeds the true percolation, and hence has a very limited application
in all these experiments. Other means are therefore required to test the passage of
fluids, and for this purpose there is no arrangement more convenient than that represent-
ed in fig. 18. It consists of a tube, three eighths of an inch in diameter, and several feet
long, bent at the point b upward, and expanded at c ^ into a funnel termination. When
the instrument is in action, the longer limb, d b,is filled to some determinate height with
mercury, which also rises to a certain distance in the shorter leg, above this, and to the
height a a some fluid is placed acting as chemical test of the presence of the gas, in-
tended to be passed through the barrier c c, which is tied air tight over the funnel
mouth. The following experiment will indicate its use : Having placed this siphon
on the mercurial trough, a quantity of mercury was poured into it, sufficient to cut off"
communication between the two Umbs; then in the shorter Hmb a column of litmus
water reddened by muriatic acid, and occupying a depth of one eighth of an inch, was
introduced; over the funnel mouth a thin lamina of India-rubber was tied, and upon that
a piece of stout silk, for the purpose of strengthening the barrier, A column of mercury,
forty-three inches in height, was next placed in the long limb, and a jar of ammoniacal
gas over the short one. In the course of one minute, a cloud of dark-blue particles was
seen descending through the litmus, and in six minutes it had become uniformly blue ;
thus proving the passage of ammonia through a tissue of India-rubber, against a pressure
of almost one atmosphere and a half.

147. There were considerable difficulties encountered in the outset of these experi-
ments in tying on the India-rubber barriers, so as to withstand the high pressures to
which they were exposed without leakage ; an insidious leakage which took place be-
tween the sides of the glass and that part of the India-rubber compressed by the string
against it This, how ever, was efiectually prevented by setting fire to a piece of India-
rubber, and daubing the semi-fluid material on that part of the glass around which the
string was to pass ; then, on tightly binding on the barrier, it came into perfect contact
witli the glass, and was retained there by the sticky material, no leakage whatever taking
place, unless some part of the arrangement burst.

148. The experiment just related leads to some important conclusions ; we see that
the force of impulsion driving ammonia into atuiospheric air exceeds a pressure equiv-
alent to forty-three inches of mercury, the barometric pressure at the time being 29-73,
that is to say, exceeding by very near half an atmosphere the force which theory
would indicate. The hypothesis of Mr. Dalton, which seems to me to be ftilly con-
firmed by the observations of Mr. Thomson, founded on the experiments of Mr. Gra-
ham, assumes that gases act towards each other as vacua, or, in other words, the force
impelling the particles of one gas into the interstices of another does not exceed the
barometric pressure ; but here we find that the result apparently leads to a very diflfer-
ent conclusion. It was from an experiment of this kind that Dr. J. K. Mitchell was
led to doubt the truth of Dalton's theory, inferring from his results that gases penetrated
each other with much greater force. Such a conclusion, however, does not legitimately

•46 DALTON'S HYPOTHESIS.

follow, for it is highly probable that the nature of the barrier itself is very much
concerned in the final action. A gas may penetrate into another with a force not
greater than one atmosphere, and yet, because of the disturbing agency of the medium
through which it must go, it may succeed in lifting a column of mercury equivalent to
a pressure of many atmospheres.

149. The evidence proving that gases do not infiltrate each other with a pressure
greater than one atmosphere is very cogent. Much of its weight is derived from the
identity of the resulting volumes of commingled gases ; but the most important fact re-
lates to the passage of these substances into each other, when the barrier separating
them is very porous and has no condensing action, as is the case with a stucco plug,
which opposes simply a mechanical impediment to their motion, acting, as will be here-
after proved, merely as a temporary valve ; a mode of action totally different to that of
closer textures. The final volumes exchanged being inversely proportional to the
square root of the densities, and these final volumes representing the true initial veloci-
ties, we have a striking illustration of that law of gaseous mechanics, that the velocities
of different gases, rushing into a vacuum, are inversely proportional to the square root
of their densities. Consequently, we are constrained to infer that one gas acts towards
another in the same manner as if it were a vacuum ; and, therefore, that the force im-
pelling the particles of one gas into the interstices of another never exceeds the pres-
sure of one atmosphere.

150. In an experiment made on the passage of ammonia into atmospheric air, it was
found, that though the passage of the gas was resisted by a pressure of seventy-five inches
of mercury, or upward of two atmospheres and a half, it took place, apparently, as
readily as if no such resistance had been opposed to it. The question at once arises,
Whence is this powerful impulsive force derived ? clearly not from the action of one
gas upon the other, for there is great probability, as we have already seen, that that
force would not be able to lift more than thirty inches of mercury. The porous tissue
or barrier alone can be regarded as the seat of this power. This fact, that systems of
capillary tubes, or thin tissues, have in themselves certain powers, capable of producing
high mechanical action, and operating successfully against the severest pressures that
can be brought to bear against them, is worthy of the serious contemplation of physiol-
ogists ; it is a great error to impute the forces producing these phenomena to the gas-
eous media. In the tissue itself we must admit a source of power, a source far trans-
cending that which solicits the gases to penetrate each other. Let us next inquire
into the nature of this power.

151. It is well known that porous substances of all kinds and fluids absorb gaseous
matter very readily, in volumes varying according to circumstances. Water, for exam-
ple, absorbs its own volume of carbonic acid, and 480 times its volume of hydrochloric
acid gas. In the latter case, therefore, an extremely gi'eat condensation takes place.
So, too, a fragment of porous charcoal absorbs nearly ten times its volume of oxygen,
and ninety times its volume of ammonia ; these gases, therefore, exist on the surface of
the particles of the absorbing medium, in a state of very high compression. And the rea-
soning which here applies, appUes also in the case where the two gases are separated by

ABSORBENT AND CONDENSING ACTION OF BODIES. 47

a tissue. If, for example, we separated, by a mediam of this kind, a certain volume of
ammonia from a like volume of nitrogen gas, though at the outset of the experiment
both the gases might be existing under the same pressure, yet this equality would very
rapidly be losL The absorption of the ammonia taking place with much more rapidity
than the nitrogen, it would be presented to this latter gas, not under an equivalent pressure,
but in a state of great condensation. Under such circumstances, the transit of a gas
is not, as will be shortly shown, analogous to the case where it flows under common
pressure into a vacuum, or into another gas, but the tissue, continually acting as a per-
petual condensing engine, brings the two media in contact with each other under ex-
tremely diiferent conditions ; the one in a compressed state, but ready to exert the
whole of its elastic force, the other in a state perhaps Uitle varying from its normal
condition.

152. If tissues really exert a power of this kind, some might inquire how it is that,
when a tube closed at one end with such a structure, and filled with mercury, is sunk
in the trough to its hydrostatic level, atmospheric air, or any gas to which it is ex-
posed, does not pass through and expel the mercury from the tube. If, it might be
said, the gas is existing in such a condensed state in the tissue, what is the reason it
does not expand, and drive the mercm-y down ? Experiment proves that this is not the
case, but no argument can be drawn from it at all affecting the position here taken ;
for, as soon as the gas has gained the under side of the tissue, there is no cause
soliciting it to escape any more this way than backward into its own atmosphere;
the pressures each way are equal, and, therefore, counteract each other's effects ; or,
rather, the pressures are unequal, for that tending to expel the mercury is resisted by the
hydrostatic action of that fluid, and hence no gas can pass into the tube.

153. We can now understand the rationale of action in Mr. Graham's experiment
with plugs of stucco. He found that this material exerted a very slight absorbent
power over the gases ; oxygen, hydrogen, nitrogen, &c., not being absorbed in any
sensible quantity. When, therefore, he diffiised hydrogen into atmospheric air, the
stucco not acting mechanically on either of those substances, they were presented to
each other under equal and ordinary pressures, and they therefore began to flow into
each other just in the same way that they would have flowed into a vacuum ; but very
different is the result when we make use of sheets of India-rubber or moistened animal
membranes. The stucco plug ser\es only to make the experiment manageable by op-
posing a slight resistance to the escape of the gases, and acting, as I have said before
as a temporary valve ; so that, if a diffusion tube be fitted up in Mr. Graham's manner,
at the end of the arm of a balance, the gas does not escape so rapidly but that there is
time for a very accurate self-adjustment of the apparatus, and the volume of re-entered
air can be measured with precision.

154. It might, perhaps, be objected to the view here taken, that the condensation
which some gases experience is more than sufficient to liquefy them; and that, there-
fore, they do not act simply as gaseous bodies would do towards each other. This
condition, however, when it does take place, appears not to change the resulting phe-
nomena, as the following experiment shows. The thermometer being at 38° F., and

48 VOLTAIC BATTERIES MAY BE USED FOR PRODUCING GREAT PRESSURES.

the barometer at 29-88, atmospheric air, under a pressure of two atmospheres and a
half, was exposed, under a sheet of India-rubber, to sulphurous acid gas, care being taken
that the temperature of the mercurial trough, and all parts of the arrangement, should
be as above. The passage of the gas took place with great promptness, the litmus
water, used to detect its presence, reddening rapidly. Now sulphurous acid, according
to the experiments of Dr. Faraday, condenses into a liquid at 45° F., uhder a pressure
of thirty inches of mercury ; we know, therefore, that in this trial the gas must have
existed in a liquid condition in the barrier, and yet it passed through into atmospheric
air, under a resistance almost two and a quarter times sufficient to condense it, and at
a temperature eight degrees lower.

2 55. Having progressed thus far in this part of the inquiry on the action of tissues,
it became important to find if any pressure which could conveniently be brought into
action would restrain the passage of gaseous matter. Resort was first had to the usual
mechanical condensing apparatus ; but they were found to be ill adapted to the purpose
in hand. The necessary motions were always productive of inconvenience, and it was
not found possible to carry the condensation to the degree required, or to avoid leak-
age from some of the numerous joints. After some trouble, the following contrivance
was fallen upon, which answers the end perfectly, is not open to the serious objections
of the former, and, requiring no cock or valve, can be readily made without leakage. A
tube of glass about one third of an inch in bore, of stout substance, and about ten inches
long, is bent into a kind of siphon, so that one leg shall be about six, and the other
two inches long. The extremity, a a. Jig. 19, has a lip or rim turned round it at the
lamp ; while in the longer leg, a thin glass tube, c c, about one eighth of an inch in
bore, and closed at one end, is included to serve, as will be hereafter shown, as a gauge.
Next, the extremity, b, of the siphon is closed, there being inserted through it two pla-
tinum wires, d d,e e, parallel to each other, but not touching. The arrangement is then
ready for use. Suppose, for example, it was required to pass through India-rubber
sulphurous acid gas into atmospheric air, condensed by a pressure of five or six atmo-
spheres ; the long leg of the siphon is to be filled with water, which is excluded from
the gauge-tube c c, owing to the narrowness of its bore ; next, a strong decoction of lit-
mus is to be poured into the short leg until it is about half filled. The rim round the
extremity, a a, is then daubed with a piece of burning caoutchouc, and upon it is tied
a thin piece of that substance, with a fine but strong waxed thread. Ov^ this is tied
a piece of stout silk or cotton cloth, for the purpose of fortifying the barrier ; the wires,
d d, e e, are then made to communicate with the poles of an active voltaic battery, and
the condensation commences ; for the gas which is evolved from these electrodes rising
to the top of the tube, accumulates there, causing the column of water in the short leg to
rise and condense the atmospheric air above it. The membrane, though fortified, gives
way to a certain extent, becoming convex outward; and as the accumulation of gas in
the long leg continues, the condensation of that in the short leg increases, as is indica-
ted by the gauge c c. A very thin India-rubber, of the diameter here used, will stand a
pressure of from six to twenty atmospheres without rupture, if its silk support is good ;
and I have found that anointing the edges of the rim with the burned substance enables

VOLTAIC BATTERIES MAY BF USED FOR PRODUCING GREAT PRESSURE. 49

the operator to tie it on so that no leakage shall occur between the India-rubber and
the glass, even under the severest pressures. When the gauge shows that the required
degree of condensation is arrived at, the connexion with the battery is broken, and the
condensation, of course, stops ; the siphon being carried to the mercurial trough, taking
care to keep its position erect, its short limb is depressed under the mercury, and car-
ried into a jar containing the sulphurous acid. If, under these pressures, any of the
acid <^as finds its way into the condensed air, its presence is detected by the reddening
of the blue litmus water. It is necessary here to observe, that the indications of the
air gauge do not give a correct estimate of the amount of condensation, but always rep-
resent them higher than they are accx)rding to Marriotte's law : it has long been known
that the volume of gas dissolved by water depends, in a great measure, on the pressure
exerted on it : now^ it \vill be found, when the operation is conducted in an instrument
arranged as this, that a yery large proportion of the air in the gauge disappears in this
manner; its zero point is therefore altered, and the condensation appears higher than it
reallv is. It may be remarked, in passing, that it is surprising to w'hat an extent the
absorption of oxygen and hydrogen is carried in the longer leg, owing to their making
their appearance in a nascent form. To ascertain the true condensation, so soon as
the passage of the sulphurous acid or other gas has taken place satisfactorily, the mem-
brane is to be punctured with a pin, and when a pneumatic equilibrium is obtained, the
height of the liquid in the gauge will mark the point where the zero of the scale should
be placed.

156. Some might suppose that there is danger in making use of an apparatus like
this, where a high pressure is produced, owing to the risk of an explosion of the com-
pound gases in the long Umb, since it is stated in most works on chemistry that a mix-
ture of oxygen and hydrogen, when compressed, will explode. To ascertain if there
was any danger arising from this, as also to kno\v to what extent the condensation could
be pushed by the aid of a voltaic battery, I took a tube, a h {Jig. 20), and into the closed
extremity having fused a pair of platiniuu wires, and drawn the other into a long capil-
lary tube, bending it at tlie same time at right angles to the former, I filled it with water
(boiled until all the air mechanically enclosed in it was expelled), except a portion of the
narrow capillary part from d to c, which contained atmospheric air, to act as a gauge ;
the extremity, c, was closed. Next the platina wires were made to communicate w-ith
the poles of an active voltaic battery of 120 pairs, and gas slowly accumulated, the cur-
rent of electricity steadily passing all the time, as was indicated by the deviations of a
galvanometer, through which it was made to circulate. Observations were made every
few minutes on the progress of the experiment, the last of which indicated a pressure of
sHghtly upward of forty-three atmospheres, and shortly after it was taken the tube burst;
not, however, on account of the explosion of the gaseous materials in it, but because it
could not sustain so excessive a pressiu"e tending to burst it, a pressiu'e equivalent to that
of a column of mercury nearly thirteen hundred inches high.

157. These results lead us to some remarkable conclusions in relation to the passage
of voltaic currents. Dr. Faraday found that they cannot pass along such media as
water without effecting its decomposition ; in fact, that the transfer of elements seemed

G

50 GASES PASS WHEN RESISTED BY THE FORCE OF MANY ATMOSPHERES.

to be absolutely essential to the transit of the electricity. Now it might be supposed
that, if some powerful force were brought to bear against and antagonize this, as where,
by a severe pressure, the oxygen and hydrogen are prevented from being evolved, one of
four things must happen : 1st. That the water would become a non-conductor. 2d.
That the vessel, no matter how strong it might be, would burst. 3d. That the current
would pass without any decomposition happening; or, lastly, that the current would
pass and gas be evolved, but as fast as evolved, it would be dissolved in the water. A
quantity of boiled water was hermetically sealed up in a glass tube, which it filled en-
tirely, except a small space occupied by a bubble of air, probably not more than one
fiftieth part of an inch in diameter. A pair of platinum wires had been fixed into the
tube so as to transmit the voltaic current. The current passing freely, as was indicated
by a galvanometer, decomposition of the water ensued; extremely minute bubbles making
their appearance, the water absorbing the greatest part of them, its temperature rising
very much, so that the tube connnunicated a sensation of warmth when touched by the
finger. When the pressure was estimated to have risen to about fifty atmospheres, the
tube burst, and in an instant all the gas that had been imprisoned in the water made its
escape, throwing it into a violent effervescence. Hence we find, that when water is
enclosed hermetically in a vessel, and a galvanic current passes through it, decomposition
ensues, a portion of the gases making their appearance in a gaseous form, replacing the
small space occupied by the decomposed water, the whole of the remainder being ab-
sorbed by that fluid as fast as it is given oflF. When the pressure is high, it is probable
that the dimensions of the vessel become greater, and hence the little bubble of air ac-
cumulated exceeds in bulk the volume of decomposed water. It is also found that any
pressure up to forty or fifty atmospheres may be commanded in this way.

158. Being thus furnished with a very convenient and very portable method of con-
densation, I proceeded to examine the force of passage of gaseous matter into atmo-
spheric air. Sulphurous acid passed instantaneously into atmospheric air, against a
pressure equivalent to two hundred and twenty inches of mercury, or seven atmospheres
and a third. Some experiments were made on the absorbing action of the sample of
India-rubber here used, which had been softened in ether for the purpose of procuring
it in thin sheets. Of the gas here spoken of, it was found to absorb sixteen times its
own volume. It is to be expected that, even had a much more powerful pressure been
applied, the gas would, nevertheless, have gone through.

1 59. The curved form of the instrument described in (155) was found to present cer-
tain inconveniences when pressures upward of six or seven atmospheres were made use
of; the volume of air which, at the beginning of the experiment, occupied the greater
part of the extent of the shorter limb, had now collapsed much in its dimensions, and
owing to the unavoidable giving way of the India-rubber and its silk, had retreated out
of sight beneath it. It was not found convenient to lengthen this limb, for that entailed
a corresponding increase in the dimensions of the battery, in order to produce a given
condensation in a given time ; an objection also applying, in a measure, to the apparatus
even at lower pressures. Though I had the command of batteries, consisting of six
hundred pairs of four-inch plates, I preferred a modification in the instrument itself, than

GASES PASS WHEN RESISTED BY THE FORCE OF MANY ATMOSPHERES. 51

a resort- to such an energetic but unwieldy apparatus. A straight tube was, therefore,
taken, about three sevenths of an inch in bore (Jig- 21), and a rim turned on it ataa;
at the closed extremity the platina wires, h c, entered, a gauge tube, d d, was dropped in
between them, water was then poured in to the height, e e, and, lastly, a tube,/ con-
tainin'' the appropriate chemical test, was inserted, its bottom resting on the top of the
gauge tube. Nothing then remained but to tie on the India-rubber, with its silken sup-
port, and bv the voltaic battery to proceed to condense. In this instrument, the test fluid
was never out of sight, nor did the volume of the gas suffer any inconvenient change;
the gauge, too, was well located for observation, and a given condensation could be pro-
duced in less time, and by a less amount of electricity, than with the siphon tube ; for
the space contained between a a and e e was less in volume. As an auxiUary arrange-
ment, a glass tube, aaaa (Jig. 22), one inch in diameter and ten long, with a support, b,
was taken, and its mouth ground true, so that a piece of plate glass, e c, would close it when
placed over it ; this tube served in many cases as a gas generator, and also as a receiver
for the tube (^g. 22), which was dropped into it It is to be observed, that in the ar-
rangement here adopted, the gaseous matter evolved from water mingles with the atmo-
spheric air in the upper part around the tube,/ and, therefore, the passage of the gases
tried does not take place into atmospheric air, but into a mixture of oxygen, hydrogen,
and nitrogen gases.

160. The tube/being filled with lime-water, and a pressure amounting to ten atmo-
spheres being produced in the vessel, it was exposed to an atmosphere of carbonic acid,
generated in the tube a aa a, fig. 22, procured by dropping a few pieces of marble into
the tube, and pouring thereon dilute muriatic acid. When the vessel was full, the
plate e c was laid upon it, and any surplus gas generated escaped by Ufting it up. In
the course of a few minutes, the upper part of the tube containing lime-water began to
look milky, and in an hour, a cloud of particles of carbonate of lime had fallen to the
bottom.

161. Again, having filled the tube/ with a solution of acetate of lead, and produced
a pressure amounting to twelve atmospheres, it was exposed to sulphuretted hydrogen,
generated in the vessel,_>?o'. 22, fi-om protosulphuret of iron and dilute sulphuric acid.
In a very short time, the black sulphuret of lead appeared, giving tokens of the rapid
passage of this gas through the barrier. A comparative experiment was made, in order
to discover whether the transmission took place more slowly than when it was not re-
sisted by such a severe pressure. It appeared, however, so far as the experiment could
be tried under similar circumstances, as regards the thickness of the barrier, »&c., that
sulphuretted hydrogen went through the barrier against a pressure of three hundred and
sixty inches of mercury, as readily as if no such force were exerted against it.

162. As numerous experiments, which had been tried on various gases, had hitherto
failed to indicate any obstacle to their passage, it became necessary to know whether,
at the extremest pressures that could be commanded, they would pass through a bar-
rier. To accomplish this, I took a strong and narrow tube, and, having turned a rim
at one end and sealed fine platina wires in the other, I filled it with distilled water, and
enclosed in it a narrow capillary tube, the gaseous contents of which were small. As

55 GASES PASS WHEN RESISTED BY THE FORCE OF MANY ATMOSPHERES.

a test, in the upper part of the arrangement, and in lieu of the tube f, I placed a slip
of paper, which had been alternately soaked in acetate of lead and cai-bonate of soda ;
the India-rubber was fortified by a piece of very strong silk, which was carefully tied
on; there was not, therefore, any gaseous matter present except the small quantity of
atmospheric air in the gauge-tube. The condensation, therefore, went on with great
rapidity, a mixture of oxygen and hydrogen gradually accuuuilating in the top of the
vessel, bulging out the India-rubber and silk barrier until it was almost hemispherical.
It was my intention to try a pressure of twenty-five atmospheres; and when that was
supposed to be reached, the instrument was placed in an atmosphere of sulphuretted
hydrogen. Very soon the test paper became of a tawny appearance, and, finally, it was
quite black. The pressure, when the experiment was over, was found to be twenty-
four and a quarter atmospheres.

163. At a temperature of 48° F., and pressure of 29-74 B., sulphuretted hydrogen
gas passes into a mixture of oxygen and hydrogen, though it may be resisted by a pres-
sure of twenty-four and a quarter atmospheres, or nearly seven hundred and thirty
inches of mercury. Like sulphurous acid, it penetrates through a barrier, and then dif-
fuses into an atmosphere beyond it, at pressures greater than that which is necessary
to condense it into a liquid.

164. If, as it thus appears, no pressure which we can command is sufficient to re-
strain one gas from passing into another, we next inquire what obstacle the condensed
gas exhibits. There is abundant and conclusive evidence that, under ordinary circum-
stances of temperature and pressure, this medium bears the same relation to the perco-
lating gas that a vacuum would do ; inasmuch as the rate of discharge into it is iden-
tically the same as it is into a vacuum. For the purpose of ilhistration, we may, there-
fore, regard it to all intents as a vacuum, and reason accordingly. If the particles of
heterogeneous gases possess no repulsive tendency as respects each other, but are per-
fectly quiescent and neutral ; if the presence or absence of one makes no difference nor
produces any retardation on the motions of the particles of the other, then it is appa-
rent that it is immaterial how many of such particles are condensed together into a given
space ; owing to the want of repulsive action in those particles, that space will be as
much a vacuum to any other gas as it ever was. Now it has been shown by the ex-
periment above cited, that certain gases will diffuse into others, even though the latter
may be condensed into a space twenty-four times less than that which they would or-
dinarily occupy. The vacuum is not less a vacuum because it is contained under smaller
dimensions, any more than a torricillian vacuum is less perfect tchen the mercury is
made to rise nearly to the top of the barometric tube, than it ivas when there was a va-
cant space many inches in length. Theory would therefore indicate that these diffusions
will take place under all pressures, provided the gaseous condition subsists; and this
conclusion is abundantly borne out by the experiments herein detailed.

165. Having thus shown how it is that, when gaseous matter is on one side of a
barrier, the space so occupied may be regarded as a vacuum, even though the gas should
be highly condensed, I come next to the consideration of a much more intricate part of
•tiie subject, the action of the barrier itself as an areolar tissue, which is the more imme-

CO-ORDINATION OF DALTON'S, GRAILOrS, AND MITCHELLS RESULTS. 53

diate object of this paper. I have already stated that the results of Dr. Mitchell and
Professor Graham apparently exhibit a striking discordance ; it will here be seen that
the facts reported by those chemists can be readily co-ordinated.

166. Both of them appear to have made trials of the absorbent power of the barriers
thev respectively employed ; Professor Graham having operated on a mass of stucco
of certain dimensions, and found its absorbing power, in relation to most gases, very
low ; Dr. Mitchell on a thick cylinder of gum elastic ; but neither of them appears to
have clearly seen the importance of this element in the production of the final result.
In the case of the action of stucco, this, indeed, is a remarkable circumstance, for in all
those instances where the absorbing power of the stucco was great, the equivalent vol-
umes of diffusion, as obtained, were, without exception, erroneous. Dr. Mitchell, on
seeing certain gases pass into each other with a force that was greater than the pres-
sure of sixty-three inches of mercury, and inferring that there was no vis a tergo in
play, was obliged to impute his result to the inherent power of gaseous penetration;
hence he came into direct collision with the Daltonian hypothesis. On the other hand.
Professor Graham, supposing that, in all his erroneous cases, the deficit was to be im-
puted to the porous mass, which, in some manner, detained and absorbed the gases,
found in every other instance a full confirmation of the doctrine of a vacuum.

167. The whole phenomenon depends, however, upon the action or inactivity of
the cellular tissue itself; it will be convenient, for the better understanding of it, to con-
sider it under two heads. First, where the tissue exerts no absorbent action on the
media, or absorbs both to the same extent ; and, secondly, where one is absorbed to a
much greater extent than the other.

168. In the first case, the velocities with which any two gases pass into a vacuum are
inversely proportional to the square roots of their densities respectively ; moreover, the
volumes that so pass varv directly as the velocities, and therefore may be taken as an
index and measure of them ; but, as the mass of each gas is expressed by the product
of its density into its volume, it may be also represented by the velocity multiplied into
the density ; and, as the square of the velocity of the one, multiplied into its density, is
equal to the square of the velocity of the other multiplied into its density, whatever may
be the difference of the specific gravity of the two gases, their mechanical momentum
will always be the same; the resistance they meet with in passing through the tissue is
common to both, and equal in both cases ; and hence the initial velocities of diffiision
ought to be inversely proportional to the square roots of the densities ; and as, during
the progress of the experiment, the impelling force of the one gas is equal to the ex-
pelling force of the other, the resulting momenta of the two currents is still equal, and
the final volumes are such as are found by direct experiment.

169. We now come to consider the second case, where the cellular rissue presents
one of the gases in a condensed form to the other, or, in other words, absorbs it ; and
here we have to refer to a fundamental proposition of dynamics, that when the moving
force and the matter to be moved vary in the same proportion, the resulting velocity
will alwavs be the same. An illustration will show the application of this principle to
the case in hand. If a cylinder of air, fitted appropriately with a piston, communicates

54 CO-ORDINATION OF DALTON'S, GRAHAM'S, AND MITCHELL'S RESULTS.

with a vacuum by means of an aperture, it is immaterial whether the air be allowed to
flow into the void without any pressure, or whether it be urged by a direct action on
the piston, its velocity as it goes into the void will be in both cases the same ; for, if it
be compressed, the immediate action of the force exerted on the piston is to reduce the
air in the cyhnder to such a density that its elasticity shall be equal to the compressing
force, and because the elasticity varies directly as the density, the density of tbe air in-
creases with the impelling force. The matter to be moved is increased, therefore, in
the same proportion with the pressure, and therefore the final velocity is the same. Now
what is here said of a cylinder of compressed air, applies evidently to the action of a cellu-
lar tissue, which is nothing more than a perpetual and equable condensing engine. If it
increases the elastic force of one of the gases by compressing it, at the same time it in-
creases its density ; and, therefore, its velocity of transit is the same as though it had
not suffered any action of compression.

170. Such is the case while the gases are engaged with each other in the tissue;
but as soon as they are passed from it, and are beyond the reach of its attractive force,
a new condition of things takes place : the condensed gas being no longer under re-
straint, expands freely into a void, and when there measured, gives a resulting volume
totally different to what it would have been had not the tissue compressed it Sup-
pose, for example, we placed on one side of a tissue carbonic acid, of which it would
condense its own volume, and on the other atmospheric air, on which it exerted no
action. While the two gases were engaged together in the tissue, one would be pre-
sented to the other under an elasticity double of that which it would have had had no
absorption gone on ; but since its density is directly proportional to its elastic force, the
continual velocity with which it would rush into the other gas is the same as though
no compression had occurred ; the rate of exchange in the cellular tissue is the same
as under normal circumstances ; that is to say, every volume of air replaces 0-8091
of compressed carbonic acid ; but so soon as this gas has reached the opposite side of
the barrier, and there escapes, its elastic force being restrained by no compression,
causes it to assume its original dimensions.

171. It will be readily perceived that the theory here given depends on the princi-
ple, that however much a gas is condensed, it will at all pressures rush into a vacuum
with the same velocity. The elasticity of a gas in any state is measured by the force
under which it exists, and this is ordinarily the pressure or weight of the atmosphere ;
it follows, therefore, that though the density of gases may vary, yet they have all the
same elastic force ; but, when pressure is exerted upon them, the density and elasticity
increasing together, their velocity in rushing into a void is always, and under all pres-
sures, a constant quantity.

172. We may now apply this reasoning to certain practical cases. Mr. Graham
found that the absorption of carbonic acid by a porous plug of stucco was very small
in amount, and the absorption of atmospheric air is equally minute. Accordingly,
when these two gases are separated from each other by a screen of that substance, they
diffuse according to the law of the square roots of their density. One volume of air,
replacing 0'8091 of carbonic acid, the gas, therefore, on that side of the screen where

DISTURBING AGENCIES, AS TEMPERATURE. ^

the carbonic acid was increases in quantity. Now when, instead of a screen of stuc-
co, a tbiu lamina of India-rubber is used, which is found, upon trial, to condense one
atmosphere of carbonic acid, while it does not act upon air, the same rate of exchange
ensues ; but there is a diminution of gaseous matter on the side containing the acid,
and because the screen condenses one atmosphere, there should be found only half as
much gas as would represent the equivalent volume of difiiision had the screen pos-
sessed no condensing power.

173. One hundred and sixty-one measures of carbonic acid gas were confined in a
tube under a thin sheet of India-rubber, and suffered to diffuse for thirty-six hours. To
prevent as much as possible any disturbing action of the fluid over which the experi-
ment was tried, a saturated solution of common salt, which absorbs carbonic acid slow-
ly, was made use of The gaseous contents of the tube decreased in their dimensions
very rapidly, and when measured, were found to consist of 98 volumes only. In the
mean time, a tube closed at one end, filled with the same quantity of carbonic acid, and
placed by the side of the former, had decreased about five measures ; we may therefore
assume that the quantity of gas that should have been found in the diffusion tube ought
to have amounted to 100 measures nearly. Now the specific gravity of carbonic acid
gas is 1-527, the reciprocal of the square root of which is 0-8091. Hence, under ordi-
nary circumstances, one volume of air should replace 0-8091 of carbonic acid gas; but
as, in the experiment here tried, the barrier produced a compression, one volmiie of air
should displace 1-6182 of carbonic acid, the amount observed very nearly.

] 74. I would not here be understood to say that there are no other disturbing ac-
tions going on in cellular tissues except those which result from their absorbent power.
A great many facts show that, under pecuUar conditions, they are able to produce de-
compositions of a certain sort. Often their regular action, as indicated by theory, seems
to be entirely departed from ; great disturbance arising from the fact, that when two gases
are absorbed together bv any areolar tissue, they experience a greater condensation than
each would in a separate state. The presence of nitrogen or carbonic acid, in any
porous mass, increases the action of that mass on oxygen, more of the latter being con-
densed. A piece of charcoal, impregnated with oxygen, condenses more hydrogen than
it should do, and the presence of hydrogen facilitates the condensation of nitrogen. It
is, therefore, impossible to foretell what the result of diffusing one gas into another will
be, by simply ascertaining how many volumes of either alone will be absorbed by the
tissue, inasmuch as a greater or lesser condensation may happen when both are em-
ployed together.

175. Variations of temperature, which probably affect the power of absorption, and
thereby the diffusion of volumes, are experienced by all tissues. When charcoal, or
any other porous mass, is placed in an atmosphere of gas, which it can condense rap-
idly, its temperature rises, the effect apparently depending more on the velocity of ab-
sorption than on the final amount. In the case of ammonia, it does not even require a
thermometer to discover this increase of temperature, for it is very sensible to the touch.
On the other hand, when this condensed gas makes its escape, a corresponding dimi-
nution of temperature happens : it is immaterial by what means the liberation of the gas

gg PHYSIOLOGICAL EXPERIMENTS AND REMARKS.

is effected, the same result uniformly follows ; if, for example, a porous mass saturated
with carbonic acid be exposed to an air-pump vacuum, in connexion with a thermo-
metric arrangement, the gas, as it is liberated from the pores of the structure by the ac-
tion of the pneumatic machine, gives rise, by its expansion, to the production of cold.
Or, if the same porous mass, saturated in like manner with carbonic acid, be exposed to
an atmosphere of hydrogen, it absorbs but a small quantity of this latter substance,
while a very large amount of the former is liberated from its condensed state, and the
thermometer indicates a fall of temperature ; the resulting volume of the mixed gases
being much larger than the original volume of hydrogen. Again, if a porous mass,
which has absorbed its due volume of hydrogen, be immersed in an atmosphere of am-
monia, the resulting volume of the mixed gases is much smaller than the original amount,
and the porous mass becomes hot.

176. The observations here made on the vicissitudes of temperature which an areo-
lar mass experiences, when successively immersed in an atmosphere of different kinds,
obviously apply when the exposures, instead of being consecutive, are simultaneous. If,
for example, a barrier separates carbonic acid and hydrogen gas, and absorbs the former
to a large amount, but exerts little or no action on the latter, then the opposite sides of
that barrier will be unequally heated. Suppose, for illustration, we call that surface of
the barrier which looks towards the carbonic acid, C, and the surface looking towards
the hydrogen, H: then, because of the condensing action of the barrier on the acid gas,
the surface C will become hot ; but because the gas, so soon as it has passed the barrier,
expands, as into a void, when it reaches the surface H that surface will become cold.
We see, therefore, that immediately after the action of the membrane or barrier is first
set up, the absorption of the carbonic acid takes place on a hot surface, and its evolu-
tion from a cold one ; whereas the absorption of the hydrogen takes place on a cold
surface, and its liberation from a hot one. A modified result of course happens when
both gases are absorbed in different degrees, and any prediction of the resulting action
becomes a matter of much difficulty. Where the barrier is very thin, or has a high con-
ducting power as respects caloric, this distinct surface action may not rigidly occur, but
the whole of the structure experiences some determinate rise or diminution ; a mean of
the condition of the two surfaces respectively.

177. The obvious application of these results, in a physiological point of view, is to
the function of respiration. In no order of life, however, does the respiratory mechanism
coincide with the arrangements of two gaseous media separated from each other by a
barrier. In those tribes which breathe by lungs, the pulmonary vessels present themselves
on the remote bronchial cells, and the arrangement is, in effect, a liquid and a gas, parted
from each other by a membrane. Chemical physiologists have hastened to apply the
discovery of Dr. Mitchell in this case, and have done right. But still the chain of
evidence is incomplete, for we have not yet seen it proved that gaseous matter, in union
with a liquid, will leave it and pass through a barrier to join a gas on the other side.
The following experiment will supply this defect : A small jar, the mouth of which
was closed with India-rubber, and its opposite end made to terminate a tube one eighth
of an inch in diameter, while full of atmospheric air, was sunk in a vessel containing

RELATION OF ENDOSMOSIS TO CAPILLARY ATTRACTION. 57

water impre2;nated with carbonic acid : in a very short time, the acid gas, leaving the
water, went through the barrier, and as it accumulated in the jar, was delivered by the
short tube at the other end, and passed up in bubbles through the water.

178. Branchial respiration deviates still more from the simple type, for we have here
two fluids, presenting gaseous matter to each other for interchange through a membra-
noxis screen. In one of them the gas is in a state of solution only, but as to what its
condition in the other may be, we can scarcely say. The phenomenon, however, becomes
obviously much more complex. In bronchial respiration, the account which Mr. Graham
gives of the process by which the little cells empiy themselves into the trachea is prob-
ablv correct ; and the same observation imdoubtedly applies to the case of the respiration
of insects.

179. The issue of these investigations, besides co-ordinating the observations of Dr.
Mitchell and Professor Graham, has a far more important application. It shows as
indisputably that membranes have special mechanical functions depending on the condi-
tions of their texture ; and that often they are, in appearance, the generators of power
equal to the pressure of many atmospheres. It is not pretended, however, that the
foregoing paragraphs contain the whole theory of cellular action, the object of this
communication being limited to a discussion of some of those mechanical functions
which have led chemists to conflicting results. Writers on physiology have suspected
that membranes were springs of power, both mechanical and chemical, but the direct
proof, from actual experiment, has never until now been furnished.

CHAPTER Vn.

THE PHYSICAL THEORY OF ENDOSMOSIS.
{From tie Amaicm Jomrnal t^ the MUictd Scuneetfor August, 1838.)

Contents : Relation of Endosmosis to Capillary Attraction. — Cases of reported Decom-
positions.— Can he produced by Inorganic Masses, and therefore not due to Vitality. —
Water made to wet Mercury. — Voltaic Battery controls Capillary Attraction. — Ac-
tion of Inorganic Tissues. — Water passes through excessively small Pores. — Hy-
draulic Currents. — Deposites produced by Endosmotic Currents. — Apparent Decompo-
sition of Metallic Salts by Membranes. — True Theory of it. — General Conclusion that
Endosmosis is nothing more than common Capillary Attraction, and never occasions
true Decompositions.

180. It is the object of this communication to offer some proofs that the peculiar
force known to chemists and physiologists under the title of endosmose and exosmose,
has no existence independently of ordinary capillary attraction ; and that all the cases
described as chemical decompositions, brought about by the intervention of animal
membranes and areolar tissues, are only examples of the play of ordinary and well-
known agents.

H

58 RELATION OF ENDOSMOSIS TO CAPILLARY ATTRACTION.

181. It is necessary, before entering into a critical examination of these points, to
explain briefly the leading experiments which have been reported in connexion with
the subject. Often received upon doubtful evidence, and sometimes implying the exist-
ence of laws which, if established, would compel us to modify our opinions of chemical
agency in general, it is time that the whole of them should pass under a connected
review, their bearings upon each other be properly designated, and the true value which
ought to be attached to them ascertained. If thus examined, it will be found that they
are very far from establishing the points supposed ; and in compliance with the usages
of science, their application must be rejected.

182. We shall have to consider, 1st, those experiments which refer to changes of
hydrostatic level of liquids, and the production of mechanical results ; 2dly, those which
are reputed to be examples of chemical depositions brought about by tissue action.

83. The original experiments of Porrett, Fischer, and Dutrochet, are instances of
the first class ; from them the terms endosmose and ex osmose are derived. They are
essentially illustrations of the fact, that if two fluids be separated from one another by
a porous barrier, they will mutually traverse it, but very often not with equal velocities,
for the volume of the one passing in a given time may exceed the volume of the other,
and hence a disturbance oCitheir hydrostatic level results. If, for example, we take a
tube, and close one of its ehds with a piece of bladder, securely tied on, and fill it to a
certain mark with alcohol, and then place it in a vessel of water, taking care that the
hydrostatic level inside the tube, and that on the outside, shall coincide, in the course
of a few hours it will be found that this equilibrium has been entirely disturbed, and the
level of the alcohol risen. On reversing the arrangement, and placing the water in
the tube and alcohol on the outside, there will be, at the completion of the experiment,
a similar disturbance, but now the level will be found to have fallen.

" («.) In this way it was found that there was endosmose from water to gum-water,
to acetic acid, to nitric acid, and especially to hydrochloric acid ; but that there was
not endosmose from a liquid to itself.

" (b.) And that different animal and vegetable membranes enjoyed the same proper-
ties as bladder, in different degrees, and that plates of burned earth, or calcined slate, or
clay, and, in general, all aluminous substances, possessed analogous powers, though to
a much less extent.

" (c.) To explain these phenomena, it is necessary to resort to some force different
from ordinary capillary attraction, or, at least, to some new modification of it ; for the
forces of capillarity, such as they are now understood, are totally insufficient to produce
these results." — (Pouillet.)

184. The second class of experiments, though often affording well-marked illustra-
tions of change of hydrostatic level, is chiefly important from the instances of apparent
decomposition exhibited. From these it has been inferred, not only that membranes
possessed certain definite chemical powers, but that at times they gave proof of a predi-
lection for the passage of certain bodies in determinate directions through them.

185. If litmus water be placed on one side of a piece of bladder, and alcohol on the
other, the water will forsake the colouring matter to pass through the bladder and unite
with the alcohol.

CAN BE PRODUCED BY INORGANIC MASSES, 59

186. If ferrocyanate of potassa be tied up in a section of intestine, and immersed in a
solution of protosulphate of iron, Prussian blue will be deposited on one side of the
intestine, but not on the other ; hence it is inferred that one solution is suffered to pass
through the pores, but a hke passage is denied to the other.

187. If a solution of oxalic acid be placed on one side of a membrane, and lime-
water on the other, clouds of the insoluble oxalate of hme will form on the side of the
lime-water, but the other side will be pellucid.

188. If a volume of nitrogen gas in a soap-bubble, or under any suitable membrane,
be exposed to atmospheric air, decomposition of that air will result, its oxygen passing
through the membrane to form atmospheric air with the nitrogen within.

189. If a quantity of commercial alcohol be tied up in a bladder, and freely exposed
to the air, the water in union with that alcohol will pass through the pores of the blad-
der, and, gradually evaporating away, will leave the alcohol much stronger.

190. And, lastly, which is by far the most remarkable of these phenomena, if a tube,
the extremity of which is closed with membrane, be filled to a certain height with
distilled water, and there be placed in it a few iron nails, on adjusting it hydrostatically,
and suffering it to remain for a time in a solution of sulphate of copper, the membrane
will apparently decompose the solution of the metallic sa^ the base of which, in a
deoxidized state, will remain attached to the under side of me membrane, but the acid
and oxygen will traverse it, and be removed by uniting with the iron.

191. The body of evidence here furnished would go to show that membranes possess
remarkable habitudes with respect to liquids, and, accordingly, it has been brought
forward as the foundation of many physiological hypotheses. Nay, more, from hence it
has been assumed that these were in truth nothing more than manifestations of that
principle of vitaUty which is supposed to be the result of organization. A power,
known under the name of endosmose, distinct from all other known agents, has been
created, its especial office being to bring about certain molecular changes, in a way re-
sembling outwardly, but essentially differing, from those of chemical affinity.

192. The error of this position might readily have been detected. We surely should
not regard that as a specific force of vitaUty which is possessed by inorganic matter ;
yet, in the outset of the original experiments on the subject, it was found that alumina
exhibited the same action as bladder, though in a feebler degree. As to the amount of
force, with that we have nothing to do ; for, no matter in how small a degree soever it may
be that alumina possesses this character, the mere fact of possessing it at all goes to show
that it is not a consequence of organization, or an evidence that the substance exhibiting
it has ever been moulded by the powers of life.

193. The verification of Dutrochet's experiment with alumina becomes, therefore, a
matter of the greatest importance ; its extension to other inorganic substances would de-
cide the point, and separate at once the power by which infiltrations take place from
the powers of vitality. It has, however, been stated that those minerals in which this
property has been observed possess it in a low degree. Some chemists have extended
this observation, and class with alumina other bodies of a porous texture, as certain varie-
ties of slate. But many experiments that have been made on this point have led to er-

(JO IS THEREFORE NOT DUE TO VITALITY.

roneous results, through inattention to the conditions of hydrostatic equihbrium. If
two fluids be placed in the opposite arms of an inverted siphon, they will have a com-
mon level only when their specific gravity coincides ; and, under all other circumstances,
the height of their columns will be inversely proportional to their specific gravity re-
spectively. If, then, we take a tube, and make its extremity end in a fine capillary termi-
nation, or close it with a plug of wood or of stucco, and fill it with some dense solution,
such as chloride of sodium, sulphate of potash, or sulphate of copper, and then iunnerse
it to the same level in pure water, the level of the fluid in the tube will descend in
obedience to the laws of hydrostatics, and when a position of equilibrium is gained, the
heights of the fluid inside and outside of the tube will be inversely proportional to their
specific gravities. In all this, endosmosis or capillary attraction has no concern.

194. In structures the pores of which are of such a diameter that these adjustments of
level can freely take place, the mechanical phenomena of endosmose are not visible ;
there is no fact that can indicate what is the true action of the porous body. All
bodies which exhibit these phenomena have their pores of such a size that, while they
offer resistance to change of level by mere leakage, they allow indefinitely small colums of
the fluid they are exposed to to interchange through them.

195. We are not to expect that any of the phenomena of molecular infiltration wiU be
exhibited when the apertures through which transudation occurs are of considerable size.
If a piece of coarse linen is made use of as the separator of two fluids, those fluids will
commingle without any disturbance of hydrostatic level. Whenever this latter equilibrium
can be effected, it takes place, and entirely masks the molecular action of the mass. For
this reason, most minerals fail to show the change of level when water passes into alcohol.
They do not possess the exact kind of porosity required, either having their interstices
of so large a size that derangements of level can be quickly compensated, or, on the
other hand, being totally impervious to the liquids. I found that the common white
earthenware, when its glaze was removed, allowed water to percolate through it to gum-
water, but no disturbance of level was observed, simply because the freedom of commu-
nication between the two liquids was so great, that if one of them had a higher level than
the other purposely given to it, it soon returned to its original position of equilibrium.
A fragment of thick Hessian crucible gave the same result, as also several varieties of
slate, iron slate and mica slate, some of which were calcined and others in their ordi-
nary condition ; also a fragment of common writing slate, which had undergone semi-
vitrification in the forge. This freedom of communication was noticed in some speci-
mens of soapstone, both burned and unburned ; and while, in plaster of Paris, the ex-
periment failed because the apertures were too large, in the transparent micas it failed
for want of communication. To show, therefore, the original experiment of Dutrochet,
the interstices of the barrier must be of such a diameter that all mechanical compensa-
tions for change of level are hindered, and free molecular infiltration can take place.

196. If a tube half an inch in diameter and three or four inches long be sealed at one
end, and while the glass is yet warm be dipped into water, a number of small cracks
will be made in its bottom. This forms a very useful instrument for studying the
properties here under discussion. If it be filled to a certain mark with alcohol, and

WATER MADE TO WET MERCURY. 62

then plunged to the same level in water, an apparent endosmosis through the cracks is
the result, for the alcohol rises with considerable velocity in the tube. It is, however,
only an apparent endosmosis, for, upon closer examination, it will be found that the
motion stops when the hydrostatic equilibrium is adjusted through the chink (193). Any
of the very porous minerals show the same thing.

197. If, in the last experiment, the tube be filled with Ume-water, and then immersed
to the same level in a solution of oxahc acid, the appearance described in (187) will be
reproduced. This cautions us not to impute to membranes any predilection for passage
in certain directions ; for that may arise from extraneous circumstances, and in the in-
stance referred to, as will presently be shown, originates in a very different cause.

198. The relation existing between solids and fluids which determines their descent
or rise in capillary tubes, has been referred to heretofore in these papers (123). A con-
nexion of the phenomena of endosmosis and capillary attraction might have been traced to
the fact that no liquid will pass through a barrier the surface of the pores of which it
cannot wet. The relation of glass and quicksilver to each other, in this point of view, is
interesting. When a piece of glass is laid upon the surface of this fluid metal, contact
between them does not take place, but they are separated from each other by an ex-
ceedingly small interval. As I had failed in reproducing many of the results attempted
by means of artificial chinks in glass (196), because of their magnitude, I was led to
hope that better success would attend the same attempts by making use of the small
interstice between glass and mercury. A tube half an inch in diameter was therefore
taken, and one of its extremities, having been ground truly flat, had its roughness taken
off by exposing it carefully to the blowpipe flame. When the tube was lowered with
this extremity downward, on the surface of some pure mercury, all the parts of its
circumference touched the metal at once. A solution of green vitriol was placed in it
to a certain height, and upon the mercury ; on the oatside of it was poured a solution of
ferrocyanate of potassa. It was expected that, through the chink between the mercury
and the glass, the liquids would slowly infiltrate to each other. After several days, no
such action was observed, and the experiment, though repeated under a variety of con-
ditions, afforded no better result Now water and saline solutions, as will hereafter be
shown, pass through interstices much more minute than this can reasonably be supposed
to be ; it is evident, therefore, that the want of action is mainly due to the circumstance
that water and saline solutions generally do not wet mercury, and the laws of capillary
action would indicate that, under these circumstances, they would fail to pass through
the chink.

199. The event of this experiment points out, in an impressive manner, the general
relations that must exist between the solids and liquids of organized bodies. W'ater
will pass with great rapidity through a chink the \\idth of which is not more than the
half of a millionth part of an inch, provided it can wet both sides of that chink ; but if
this condition be not fulfilled it fails to pass, even though the width should increase to
upward of one hundred and forty-four times its former dimensions.

200. That the non-passage described is here referred to the true cause, will appear
from the following experiments. As has been stated, under ordinary circumstances.

(52 VOLTAIC BATTERY CONTROLS CAPILLARY ATTRACTION.

water does not wet the surface of pure quicksilver, but stands upon it in drops of a
more or less rounded form : if, however, the electrical relation of these substances be
changed — if the mercury be in contact with the negative pole of a voltaic battery, and
the water with the positive, a remarkable phenomenon ensues — the water now wets the
mercury. To this important fact, and its applications, I shall hereafter return.

201. The best method of showing that the voltaic battery has entire control over
capillary attraction is to take a shallow vessel containing a quantity of mercury, as A A,
fig. 23, and place upon it, in the position marked a, a drop of water ; on making this
drop comnmnicate with the positive electrode of a battery, and the mercury with the
negative, in a moment the drop loses its rounded form and spreads out in a thin sheet
on the metallic surface, completely wetting it, and according as the tension of the bat-
tery increases, the drop expands more and more. Thus, if the current from 5, 10, 20,
40, 80, &c., plates be successively passed through it, the diameter of the circular space
it occupies closely follows the increase, and appears to continue to do so until the drop
becomes so thin that the electricity, in the shape of a spark, can pass through : then,
of course, the experiment cannot be continued.

202. \{, therefore, in the arrangement of (198), the electrical relations of the saline
solution and the mercury be changed, by the process here indicated, we should expect
that the passage through the chink would take place ; and it is so. This experiment
affords q very elegant illustration of a result obtained by Porrett many years ago, which
was applied by Dutrochet to the explanation of endosmose. He observed that if two
quantities of water were separated from each other by a membranous partition, and
one of them made positive and the other negative, all the water in contact with the
positive pole would escape through the membrane into this negative partition. When,
in the arrangement of (198), the water escapes through the chink on being electrified,
it does not move slowly, by the action of its own weight, but is also impelled downward
in the way described by Porrett. For, take a tube, c c,Jig. 24, the diameter of which is
about one tenth or one twelfth of an inch, and insert in its axis a platina wire, a, then
!' t the lower extremity touch a surface of water, and a volume of that fluid will rise in
it to a certain height by common capillary attraction. If, now, the tube, charged with
its water and wire, be placed, as in the figure, on the surface of some mercury in a
watch-glass, so that the extremity of the tube shall just touch the metallic surface, and
the wire a be ihen connected with the positive electrode, and the wire h with the
negative, in an instant the water will begin to flow out of the tube, and spread over the
mercury, and will continue to do so until its level has sunk to the end of the platina
wire. With a wider tube, such as that described in (198), this passage might be impu-
ted to the mere gravitation of the parts of the fluid urging them downward ; but, in this
instance, owing to the narrowness of the tube, that force is nullified by capillary attrac-
tion. The water is therefore driven out of the tube by an active force ; and that this
is really the case, is abundantly proved by breaking the battery connexion and rais-
ing the tube slightly above the mercurial surface ; the water then precipitately re-
turns back into the tube again.

203. In Chapter V. it was shown how the common phenomena of capillary attrac-

ACTION OF INORGANIC TISSUES. 63

tion originate in electrical excitement. The fact that electricity has, therefore, an en-
tire control over the motions of fluids in capillary tubes, will not be at all surprising.
This leads us to a generic resemblance between the phenomena of chemical affinity and
those of capillarity, which deserves a much more detailed investigation. Treatises on
chemistry represent a number of disturbing agencies which frequently antagonize, and
often control the operations of affinity ; these are cohesion, elasticity, quantity of mat-
ter, gravity, and the agency of the imponderables. It is, however, a mistake to enumer-
ate either quantity of matter or gravity as ever disturbing the action of affinity. Grav-
ity, it is true, may cause the lower parts of a solution or an alloy to be denser than the
upper ; but an action of this kind is not to be accounted as an example of contrariety
in the forces. It does not exhibit them at all at variance with each other, or in any
manner neutralizing each other. Similar remarks might be made in respect to quantity
of matter. The elastic slate, being merely a condition of cohesion, influences the ac-
tion of affinity by presenting bodies under a modified form as respects their cohesion.
Strictly speaking, there are but two forces which in reality control affinity ; these are
cohesion and the agency of the imponderables. And these are the forces that control
capillary action, the phenomena of which are the results of the equilibrium of an attrac-
tive force on the one hand, and cohesion on the other. They may be regarded as
modified cases of chemical affinity, and, being brought about by the operation of the
same forces, are under the control of the same disturbing agents.

204. In (195) I have enumerated different cases of ineffectual attempts to recognise
the action of endosmosis in inorganic bodies. I have also shown the pectdiar disturbance
that arises when interstitial communication is too free, and the relation that must exist
between a soUd and a fluid for molecular transudation to happen. Now, when all these
conditions are fulfilled in any barrier, the phenomena of endosmosis wall take place ir-
respective of its nature, whether it be organic or inorganic Plates of kaoUn or porce-
lain clay from Villarica, disks of steatite from Brazil, after undergoing induration in the
fire, and a variety of compact sandstone being cemented on the end of a tube, exhibited
in a very satisfactory manner the passage of water into gum-water, even against hy-
drostatic pressures of several inches. Independent of this decisive evidence, it might
be determined that an organized tissue is not essential to this process, from the circum-
stance that common writing paper, fastened with sealing wax on the end of an open
tube, exhibits the endosmosis of water into gum-water in a much more striking manner
than bladder ; and certain inspissated juices of plants, as caoutchouc, when in thin lay-
ers, act very well, though not so rapidly. Of all substances hitherto tried, filtering pa-
per, imbued with coagulated albumen, acts most satisfactorily.

205. A repetition of these experiments, made tmder a variety of circumstances, leaves
no farther doubt as to the true character of Dutrochel's endosmosis. It is not, as some
would have us suppose, a vital or a semi-vital force ; it is nothing more than a peculiar
case of capillary action.

206. The conditions which this peculiar case requires are, that both the fluids shall
be able to wet the barrier, that in a capillary tube formed of it they should rise to dif-
ferent heights, and that they should be able to unite chemically with each other. If we

64 WATER PASSES THROUGH EXCESSIVELY SMALL PORES.

suppose a tube of such a length, with respect to its diameter, that a fluid in which it is
immersed shall rise to the top of it, and that some extraneous cause shall effect its re-
moval as fast as it reaches that position, it is evident that a continuous current will
traverse the tube. A case in point is the action of the wick of a lamp, along which
the oil continually ascends, because it is removed by chemical decomposition as fast as
it reaches the highest point of the capillary system of cotton fibres. Any other cause
which would effect its removal in as complete a manner, would equally produce a con-
tinuous current. The same explanation applies in the case of water passing through a
tissue of bladder to alcohol ; for as soon as the small columns which percolate through
that tissue meet with the alcohol, they are removed by uniting chemically with it, and
a continuous current, therefore, results. The current of alcohol that takes place in the
opposite way meets with a similar fate ; and the excess of one of these currents over
the other determines in what direction the hydrostatic level shall change. Even the
reputed decompositions brought about by endosmosis are not without very homely and
well-known analogues. The greasy wick, when dipped into a lamp containing oil and
water, removes the former without disturbing the latter.

207. It has been shown that, to exhibit the phenomena of endosmosis, pores of a cer-
tain size are necessary ; that if their diameter exceed this, the mere leakage masks ev-
ery other effect. We might next proceed to investigate what are the actual dimensions
demanded. This inquiry is not alone one of mere curiosity, but meets with important
applications in every department of physiology; and the problem, if successfully solved,
would cast a great deal of light on the interstitial communications that take place in
every part of organic structure. Vessels of an excessive degree of minuteness creep
through the finest tissues, which might almost be regarded as formed by the interlacings
of these narrow capillary tubes. The immediate apertures of communication between
the remote fibrils of the artery, the vein, and the duct of any gland, are of an indescri-
bable smallness ; yet, how great a share of the aggregate of the actions of life is car-
ried on in such little pores, which are too small for the injection of the anatomist to
reach, or even for microscopic vision to descry.

208. These pores are, however, capable of approximative admeasurement; or, at least,
their dimensions may be deteriTiined within limits of error. The method by which this
can be accomplished essentially depends on the circumstance, that if any fluid will wet
two or more solids, it will rise in capillary pipes formed of them identically to the same
height, no matter what their chemical constitution may be, provided their diameter is
the same. Thus, water will rise in a tube of glass, of serous membrane, or in a straw,
to the same height, if the diameters be alike.

209. It has been stated (199) that water will pass into a chink the width of which
is not more than the half of a millionth part of an inch, under the condition that it can
wet both faces of the chink. Sir I. Newton has shown (Optics, b. ii., p. i.) that if you
lay a convex lens of long focus on a glass plane, a series of coloured rings surrounding a
central black spot will emerge ; and it is known from simple geometrical principles, that
the greatest distance between the two glasses, in any part where the black spot appears,
does not exceed the half of a millionth part of an inch. Yet, if a drop of water be

HYDRAULIC CURRENTS. " 65

placed between the glasses, it will be perceiyed to make its way rapidly to the central
spot, certain optical changes, depending on its superior refractive power as compared
w ith atmospheric air, accompanying its progress ; and hence we infer, that if a chink
or cleft, not exceeding the half of a millionth of an inch, occurred in an animal tissue,
water would find its way into it

210. In vessels of large diameter, fluids readily adjust themselves hydrostatically, and
currents set in any direction without obstruction. When the dimensions of the con-
taining vessels become very small, a new order of things is set up, and the particles
have, as it were, to obey newly-created forces. In large masses, the action of gravity
produces the leading phenomena, and the effects of all the molecular forces vanish.
When minute quantities are operated on, the action of gravity diminishes, and fric-
tion, cohesion, capillary action, and other molecular forces, become obvious. • The me-
chanical relations, therefore, of small and large quantities are totally distinct : hydro-
static equilibrium, which is effected so readily in larger vessels, is accomplished with
more difficulty through pores, and as these decrease in their dimensions, the forces of
resistance rapidly increase. Water, at all pressures, will adjust itself hydrostatically
with great readiness, when it b obstructed by a porous medium, provided the pores are
of sensible size; but if tliat size diminishes, the resisting forces continually increasing,
the conditions of hydrostatic equiUbrium are fiilfilled with more difficulty, and at last
cease to be fiilfilled at all.

211. The foregoing remarks enable us to come to a decision in reference to the char-
acter of endosmosis, as indicated in (183). We perceive that this force, far from
being the attribute of organized matter, exhibits its phenomena when substances whose
inorganic character is unquestionable are made use of A variety of porous minerals may
be employed in lieu of organic tissues with success; and, if the endosmosis of gases be
allowed to be a phenomenon of the same kind, then we know that such liquids as
water may be employed as barriers ; a peculiar degree of porosity is required, a structure
dense enough to obstruct readily hydraulic currents, but open enough to allow very
small columns of fluid material to traverse it A crack in glass, because of its width,
allows too great a freedom of motion ; but bladder, peritoneum, or condensed cellular
tissue, fulfil, at ordinary pressures, the required condition. It is necessary, too, that
the liquids under trial shall wet the surface of the solid ; for want of this action, water
fails to pass through the narrow interstice between mercury and glass. The degree
of pressure generated either during the action, or existing at the commencement of the
experiment, is an important element, for npon it depends the appearance or non-appear-
ance of the phenomenon. Thus, at ordinary pressures, bladder will exhibit the change
of level when water passes into alcohol ; but if pressure on one side of the membrane
be increased, a hydraulic current sets through it, and the experiment fails, because the
success of the result depends on the excess of the molecular over the hydraulic current,
and in this case the latter predominates. The relation which the liquids bear to each
other is also important ; the facility with which they unite with each other, and therefore
remove each other on transuding through the barrier, may sometimes make up for an
increased size of the pores.

I

gg DEPOSITES PRODUCED BY ENDOSMOTIC CURRENTS.

212. There is no absolute diameter at which a pore will cease to permit a hydraulic cur-
rent to pass it, and the phenomena of endosmosis to counnence. Size is but one of the
elements involved in producing this action, and deviation in respect of it may be often
compensated by variations in the other conditions ; its relation to pressure is not unimpor-
tant. Water has been forced through the interstices of gold, and melted tin through
the pores of solid copper.

213. We have next to consider the different cases of decomposition, ostensibly
brought about by endosmosis.

214. If litmus water be placed on one side of a piece of bladder, and alcohol on the
other, the water will forsake the colouring matter to pass through the bladder and unite
with the alcohol ! This experiment, which was originally cited by me as explanatory
of the fact, that colouring matter in the intestines could not give its peculiar tint to the
chyle, does away with one of the most important objections to the direct absorption
of medicaments by the lacteal system. In estimating its true value among the facts
now under consideration, we shall find that it is very far from supporting the hypothesis
that chemical decompositions can be brought about by endosmosis. There is no proof
that the colouring matter, though permanently suspended in the water, is chemically
united with it ; analogies would lead us to the very opposite opinion. All that can
be predicated of this experiment is, that it exhibits a refined kind of filtration, which, prob-
ably, may hereafter become of considerable importance in its applications in the arts ; as
in the separation of colouring matter from solutions, or the preparation of medicines, such
as the vegetable alkalies, which should be formed from colourless solutions. It is prob-
able that the non-solubility of litmus in alcohol is not without its influence in this matter.

215. The results referred to in (186), (187), (188), may all be classed together. They
have been taken as proving that currents may set in determinate directions through a
membrane ; thus, it has been inferred from the experiment (187), that when a solution of
oxalic acid is on one side of a membrane, and lime-water on the other, the acid passes free-
ly through the pores, but a passage to the lime-water is denied. It has been thought that
an action of this kind was the result of organization, an important property possessed
by membranes only; hence it has been inferred that tissues allowed of the transit of
bodies in certain directions through them.

216. A more careful investigation of the circumstances deprives this phenomenon
of all its mysterious importance. It is by no means confined to tissues or organized
matter (197). If we take a cupping-glass, the edge of which is truly ground, and,
having filled it with lime-water, place it upon a piece of clean plate glass, then, on
pouring a solution of oxalic acid on the plate, so that it may encircle the edge of the
cupping-glass, it will be perceived that, while the acid solution on the outside remains
clear and colourless, innumerable streams of oxalate of lime will pass from the bottom
of the glass, and rising in white clouds, render the solution turbid. Here, surely, we
cannot ascribe any organic function to the chink between the two pieces of glass; yet
the current apparently sets only in one way, and exhibits, to all intents and purposes, a
phenomenon identically the same with that referred to in (187).

217. The instances here referred to are those which have hitherto attracted attention.

DEPOSITES PRODUCED BY ENDOSMOTIC CURRENTS.

67

Some physicians have made important, but unwarrantable deductions from them. Sacs
formed of animal tissues have been supposed to be competent to expel ScHine matters
from them bj exosmose, while they were introducing water by endosmose. No general
rule of this kind will apply, nor will the hypothesis that a current passes in one direction
only, bear the test of a close examination. It has been stated that, when oxahc acid
and lime-water are separated from each other by a membrane, a precipitate of oxalate
of lime takes place on the side of the hme-waier, and, therefore, the current sets from
the acid to the lime-water, but none in the opposite direction. The same occurs in the
case of Prussian blue, wliich is always found on one side of the membrane. The ac-
tion is correctly reported, but the inference is erroneous.

218. I took a number of tubes, open at both ends, and tied a piece of bladder on
each. They served to contain a fluid which might communicate with one of a difler-
ent kind, capable of giving a precipitate, contained in a glass receiver.

a Contained sulphocyanate of potassa in the tube, and solution of persulphate ot
iron in the reservoir.

h Contained solution of iodide of potassium in the tube, and solution of bichloride of
mercury in the reservoir.

c Contained solution of oxalic acid in the tube, and lime-water in the reservoir.

d Contained solution of chloride of barium in the tube, and dilute sulphuric acid in
the reservoir.

e Contained prussiate of potassa in the tube, and persulphate of iron in the reservoir.

f Contained prussiate of potassa in the tube, and protosulphate of iron in the reservoir.

g Contained bichromate of potassa in the tube, and acetate of lead in the reservoir.

h Contained dilute muriatic acid in the tube, and solution of nitrate of silver in the
reservoir.

i Contained solution of prussiate of potassa in the tube, and sulphate of copper in
the reservoir.

219. In the course of a few days it was found that, in the arrangement marked a, c,
d,f, the level within the tube had risen, and the deposite of sulphocyanate of iron, oxa-
late of lime, sulphate of baryta, and Prussian blue, had taken place within the tube ; in
the arrangements b and g, the precipitates of biniodide of mercury and chromate of
lead were entirely interstitial, the pores and cellular tissue of the membrane being
choked with them, but none had escaped into the fluids on either side of the barrier ;
the membranes, when thus injected, formed very pretty microscopical objects; the level
in the tube b had risen, but that in g had fallen. In the arrangements e and h, the level
in the tube had risen, but the deposite was found on the outside. In i, after several
days, no action of any kind could be perceived, due, perhaps, to the unusual thickness
of the membrane.

220. From the aggregate of these experiments we gather, that in nearly all cases
where two fluids, which, being mixed, give rise to an insoluble precipitate, are separa-
ted from each other by a membrane, the preciphate will be found on one or other
of the sides of that membrane, but hardly ever on both ; sometimes the action appears
to be checked by the choking of the pores and interstices, and then Uttle or no depos-
ite is found on either side of the tissue.

68 APPARENT DECOMPOSITION OF METALLIC SALTS BY MEMBRANES.

221. In giving an explanation of these curious facts, it is to be borne in mind, that
all the phenftraena treated of in this chapter are the results of two contemporaneous cur-
rents, endosmosis never existing without exosmose. If these currents are established
in fluids, which, by their union, give rise to solid matter, its deposite may occur under
all the forms designated (219), (220). If, for instance, the precipitate be a light mate-
rial, and one of the currents exceed the other in volume, the small particles, as they are
formed, are drifted by the current, which is acting under the greater advantage, and the
deposite will take place wholly on one side. This, I suppose, is the mode of deposite
of oxalate of lime, which always goes with the greater current. The chemical change,
or union, it is to be remembered, takes place at the point of contact of the two
fluids, which is necessarily in the membrane itself; there they neutralize one another,
and if the circumstances of the experiment permit, the more powerful current carries
before it the precipitating particles as fast as they form, and the excess of unneutralized
material in it produces a precipitate of the same kind as soon as it mingles with the
mass of fluid on the side of the membrane towards which it is going. But, if any dis-
turbing causes intervene, if the precipitated matter has any affinity for the fibre of the
membrane, in the manner of a dye, or if it be too bulky to pass through the pores, or
too ponderous for the current readily to move, it is detained on the spot where it was
generated, and in a very short time the tissue becomes choked ; the biniodide of mer-
cury is subject to these circumstances. A number of disturbing causes will often
change the results of these experiments: when, for example, the precipitating particles
have a high density, their weight may carry them in a direction even opposed to
the stronger current. The relative specific gravity of the two fluids may also deter-
mine the course in which the particles shall go.

222. That these experiments do not prove that membranes have a predilection for
passage in Certain directions through them, the results of the earlier writers are suffi-
cient to show. They have shown that when Prussian blue is deposited in this way,
sometimes the precipitate is towards the salt of iron, and sometimes towards the prus-
siate of potash, the direction it takes being often influenced by very slight causes. Nay,'
even analogous actions may be exhibited without using any membrane, barrier, or ob-
struction ; if into a half-ounce vial a quantity of strong sulphuric acid is poured, and
upon that a solution of chloride of calcium, so that the two fluids may intermix as little
as possible, in the course of a few days it will be seen that, as the fluids slowly diffuse
into each other, the sulphate of lime is deposited entirely in the supernatant solution;
and none in the strong acid, a result unquestionably depending upon their relative spe-
cific gravity and cohesion,

223. Sections (188), (189), contain examples of what has been termed in these papers
decompositions of a certain sort. In relation to the first of these, it is by no means
clearly proved that oxygen really does leave the nitrogen in the atmosphere to go
through the barrier. The two gases may respectively pass into each other, as atmo-
spheric air and nitrogen. It is true that the more probable mode of passage is that
assumed in the section quoted. If so, it does not even follow that a real chemical de-
composition happens, for there is much reason to doubt whether atmospheric air is

APPARENT DECOMPOSITION OF METALUC SALTS BY MEMBRANES. 59

Itself a compound. The same observatioa applies, to a certain extent, to the result
(189), which is an effect analogous to that produced by a few fibres of greasy cotton
when dipped into a mixture of oil and water, as in a common lamp : effects which are
totally distinct from chemical decomposition.

:;i24. The experiment referred to in (190) is apparently the most important of these
cases of tissue action. " A tube of suitable dimensions, having one of its extremities
closed with a piece of bladder, a b.Jig. 25, and filled to a certain height, e e, with pure
water, iuto which a few iron nails were dropped, was immersed in a solution of sulphate
of copper. In the course of a few days a deposite of metallic copper was found on the
surface of the membrane towards c, but none on the inner side, or upon the iron nails.
A number of other metallic salts, such as acetate of lead, nitrate of silver, &c., afford
similar results."

225. Certainly this is a remarkable phenomenon, if the conditions under which it
occurs are accurately detailed. The operation and laws of chemical aflSnity would
lead us to ascribe the decomposition of sulphate of copper to the action of the iron ;
but then it would appear that those same laws require the metallic precipitate to be
deposited on the disturbing metal ; here, however, it is found that the deposite really
occurs on the membranous tissue.

226. On placing on one side of a membrane pure water, and on the other sulphate
of copper, or any other salt reputed to be capable of decomposition under the circum-
stances given, no chemical action whatever occurred, in many days, at all analogous to
the phenomena ; but the water passed out of the tube into the copper solution with
considerable rapidity.

227. On repeating the experiment, as given in (224), in the course of six dajs the
results were as follows : A great disturbance of hydrostatic level had occurred, there
being an accumulation in the tube containing the iron nails ; the under side of the blad-
der was coated to a considerable thickness with bright metallic copper, and a small
portion, in a pulverulent form, was found on the inner edge, and here and there patches
were discovered coating the surface of the iron nails, and minute veins of copper pass-
ing through the bladder. In many repetitions of this, the.same results were uniformly
observed.

228. These numerous experiments showed that in all cases there was a perfect
metallic communication fi-om the iron nails, by means of veins of copper, through
the bladder, with the cupreous mass on the under side. A piece of zinc, z, was there-
fore suspended in the tube, a a, fig. 26, in pure water, at a distance of three quarters
of an inch above the bladder, and the arrangement exposed to a solution of acetate of
lead. For several hours no chemical action whatever occurred, the water exosmosing
towards the metallic solution, and the level in the tube, of course, falling. At the
same time, a small portion of solution of acetate of lead passed into the pure water,
as was shown, after the lapse of twenty hours, by the formation of some thin filaments
of lead on the lower edge of the zinc ; these kept increasing in length, and finally reach-
ed the bladder ; soon after, they appeared to have made their way through the pores
of that structure, and then the usual deposite occurred on the under side of the mem-

70 APPARENT DECOMPOSITION OF METALLIC SALTS BY MEMBRANES.

brane : simultaneously, the hydraulic current changed, and the level of the fluid in the
tube began to rise.

229. A semicircular piece of very thin sheet-iron was placed on the inside of the
bladder; it caused, in a very short time, a copious precipitate of the copper on that
part of the bladder on which it lay, the remainder being free from metallic deposite. A
very well-marked change of hydrostatic level occurred. On leaning the tube, the thin
piece of sheet-iron was found to adhere to the bladder ; and, on tearing away the
cupreous deposite, the little veins, communicating through the porous texture, were vis-
ible without a lens.

230. Lastly, when the relative position of the arrangement was reversed, the pieces
of iron being placed below the membrane, and the copper solution above, so that the
little filaments of metallic matter could not reach the tissue on account of their weight,
but fell down ; or when they were destroyed by mechanical means as fast as they
formed, no deposite ever occurred on the bladder.

231. The experiments (228) and (230) especially, and the other experiments incident-
ally, prove that a perfect metallic communication must extend from the decomposing
metal to the under side of the membrane, through the very substance of that structure ;
and this observation enables us to give the true theory of the process. Let aaaa {fig.
27) be a tube, divided in some portion of its length by a membranous partition, h b, on one
side of which. A, pure water is placed, containing the decomposing metal, c, and on the
other side B, the metallic solution intended to be decomposed. Owing to the obstruc-
tion caused by the membranous diaphragm, the diffusion of the water into the solution,
and of the solution into the water, will be retarded ; in the course of time, however, it
will take place. Then, as soon as any of the metallic salt has reached the lower part
of the decomposing metal, reduction ensues in virtue of the common play of chemical
affinity, the first portion of the metal thus eliminated adhering to the surface of the de-
composing metal, and forming with it an active voltaic couple ; the decomposing metal
being thereby rendered positive, and the eliminated metal negative. Of course, the re-
duction of the dissolved metal continues, the aggregate of filaments extending itself down
by its weight towards the diaphragm; and as the solution becomes stronger and stronger
the nearer the filaments approach the bladder, so the metallic deposite becomes more
abundant. No obstruction is experienced in passing through the pores of the diaphragm,
because the metallic solution is still present there, and is reduced. But the moment any
one of the metallic veins has penetrated to the under side of the membrane, the process
goes on with tenfold activity. The metallic deposite, when it first started from the de-
composing metal, was, perhaps, merely a capillary thread, for the solution through which
it was passing was so weak that a greater quantity could not be presented ; as it
neared the upper surface of the diaphragm, it became of stouter substance, because the
solution, being stronger, the supply was more abundant ; and now, having passed the
barrier and reached the strong metallic solution, the deposite is at once at a maximum.
Hence we account for the circumstance that the reduction of the metal chiefly takes
place on the under side of the membrane.

232. It may here be asked. How is the acid in the metallic solution conveyed from a

TRUE THEORY OF IT. 73

distance to the decomposing metal, so as to onite with it ? It was to encomiter this
query, and to answer it, that I have been induced to examine so much in detail the
whole of this process. There is no physical difference between the deposit es here
spoken of, and those known formerly to chemists under the name of Arbor Satumi and
Arbor Dianae ; for the bladder or other membrane being freely penetrated, impresses
no sort of action or change on the process in any wise. The same difficulty here met
with occurs in all such cases of metallic precipitations. For example, in making the
lead tree, by the action of a piece of zinc on some saturnine solution, the particles
of lead are often evolved at a distance of six or eight inches from the decomposing
metal. How, it may be asked, is the acid transported in this case ? More than a cen-
tury ago, La Condamine endeavoured to account for this, but the state of chemical
knowledge at ibat time did not enable him to assign the true reason, and he was forced
to infer that currents actually traversed the solution, making their way to the decom-
posing metal. All decompositions brought about by the agency of the voltaic battery
are cases in point. The elements of water are separately evolved when the electrodes
are manv inches apart, and the decomposition of the very salts here under considera-
tion occurs in the same way. It is now generally admitted that these decompositions
do not occur to solitary particles at a time ; but a chain of them, extending from one
electrode to the other, undergoes simultaneous decompositions and recompositions, a
process which eventuates in the elimination of the separate ingredients at opposite ex-
tremities of the chain. This explanation appUes to the case here considered.

233. In support of the explanation here given, the phenomenon of change of hydro-
static level affords a very powerful evidence. It was stated (228) that, previous to the
establishment of a voltaic current from one side of the bladder to the other, the hydrau-
lic current set from the water towards the solution, and, therefore, the level in the tube
kept fallins ; but so soon as the voltaic current passed through the barrier, the hydrau-
lic current changed, and the level in the tube rose rapidly. Similar changes of level
have been noticed, when voltaic currents pass through membranes, by Mr. Porreti and
other chemists ; they appear to be certain indexes of that molecular interchange (not
current) which eventuates in polar decomposition.

234. I therefore reject entirely this experiment, as having anything whatever to do
with the phenomena of tissue action, or as affording an example of the powerful de-
composing agency of membranes. It has been considered in detail, inasmuch as it is
as necessary, in studying the elements of a science which, like physiology, is yet in its
infancy, to discard whatever is irrelevant or erroneous, as to point out what is pertinent
and true.

235. After a very full examination of the question before us, it is not to be concealed
that the decision to which we are constrained to come is entirely unfavourable to the
opinion commonly held as respects endosmosis. To rank it as a pecuhar power is un-
questionably erroneous ; to regard it as a manifestation of organization, or the attribute
of organized structures, is equally so. Ever since the leading phenomena were made
known by Porrett, Fischer, Gustave Magnus, and Dutrochet, they have been extensively
apphed in the elucidation of kindred actions in the vital frame ; the causes of a variety

72 ENDOSMOSIS IS NOTHING MORE THAN COMMON CAPILLARY ATTRACTION.

of diseases have been explained, as also the rationale of some modes of treatment. A
premature application of principles ill understood is to be deprecated. On the discov-
ery of a new fact, it is not always easy to determine its relation and position in the
chain of knowledge ; a confused idea is generally entertained of it • nor is it until time
and experience have abstracted from it whatever was mysterious and doubtful, that we
see clearly its true locality in respect of other facts, how they bear upon it, and how it
bears upon them.

236. We conclude, therefore, that endosmosis is not a new power, nor does it bear
any pecuUar relation to organization ; but that it is a manifestation of capillary attraction.

237. That, so far as the examination in this memoir has extended, there is no case
upon record in which endosmosis has effected a real and undoubted chemical decom-
position ; that several cases of such reputed change depend plainly ou the action of
other agents ; and hence, that those reported instances of the production of secreted
fluids by dead membranes, through this power, are fanciful illusions.

2 38. The experiments here considered are such as were conceived to be the most
important, and those generally referred to, as substantiating conclusions which conflict
with that here given. If others be known not subject to these or similar strictures, I
am ignorant of them ; such may, by chance, hereafter be found ; the decision now given
refers to what have been regarded as actual proofs, and not to contingent evidence.
That chemical changes of all kinds occur in tissues and glands, is not to be doubted ; but
we must not confound together a change effected in a tissue, and one effected through
it. Urine is readily separated from arterial blood in the kidney ; yet would any one
expect, on placing blood upon a kidney, that urine would drop through it ? A candid
examination of many of the fashionable applications of endosmosis to physiological func-
tions will discover no wide difference between them and this hypothetical case.

239. It is well known that those who first cultivated this department of science,
viewed it as a case of electrical action. In this they did not go far astray ; the ma-
chinery being erroneous, though the principle was true. Capillarity is unquestionably
an electro-statical phenomenon, and hence will hereafter come to be intimately allied
with chemistry. An important and extensive series of effects, which now pass as in-
stances of electrical attraction, will be assigned to it ; such as the adhesion of colouring
matter and dyes to cloth, the silvering to a looking-glass, the solution of salts, and gen-
erally all cases of union where the uniting bodies lose none of their prominent charac-
teristics.

OBJECT OF THE MEMOIR. 'fs

CHAPTER Vm.

ON THE USE OF A SECO.NDARY WIRE AS A MEASURE OF THE RELATIVE TENSION OF

ELECTRIC CURRENTS.

(From the London and EdMurgh Philotophical Magazine for October and Noeember, 1839.)

Contents : Object of the Memoir. — Action of a Secondary Wire. — Description of the
Torsion Galvanometer. — Resistance of the Secondary Wire under Variations of Ten-
sion.— Condition of the Current never changes. — Tension rises tcith Length of Wire
and with Distance of Plates. — Relation between Quantity and Tension. — Theory of
Tension of the Voltaic Battery. — Knoicn Methods of increasing Tension of Currents.
— General Law. — Case of Thermo-Electridty and Machine Electricity. — Voltaic Spark
hefore Contact in Vacuo.

240. It is the object of this memoir to establish the following propositions :

IsL That by means of a secondary wire, we may always determine the relative ten-
sion of electric currents.

2d. That there is reason to doubt whether the processes usually supposed to affect
the condition of an electric current are ever attended with any such result ; but that,
when changes have apparently taken place, it is probable that they may be directly
traced either to a disturbance at the place of generation, or to the development of other
currents of a different character, the primary current itself remaining unchanged.

3d. That there are two different methods of accomplishing these disturbances, and
thereby of raising the elastic force of a current : 1st. That tension may be augmented
by the sacrifice of quantity; Volta's plan of a reduplicated series, and Henry's riband
coil, in its condition of equilibrium, being examples : 2d. By the introduction of new
affinities in the exciting cells ; batteries charged with nitrosulphuric acid or sulphate of
copper are examples.

4th. That the law which regulates the connexion of this diminution of quantity or
condensation with the increase of tension is the same as that which regulates the anal-
ogous phenomena of ponderable elastic fluids.

241. Incidentally, the examination of certain other points will be entered upon: for
example, a brief consideration of Lenz's law of the conducting power of wires ; this, it
will be shown, holds not only in the case of Faradian currents, but in the direct cur-
rents from hydro-electric and thermo-electric pairs, as has been advanced by some
philosophers, but denied by others.

242. The terms tension, intensity, tensile effect, &c., have had very different signifi-
cations attached to them. From this circumstance a great deal of confiision has arisen,
and it is one of the causes of that diversity of opinion and contrariety of theory which
obtain in the elementary parts of the science of electricity. For example. Dr. Faraday
appears to use the words tension and intensity as synonymous, expressive, as it were, of

K

74 ACTION OF A SECONDARY WIRE.

elastic force, chemical authors generally adopting the same signification : " The re-
moteness from the unexcited state, a condition expressed by the terms tension or inten-
sity." " By tension or intensity is meant the energy or effort with which the current
is impelled." — ( Turner, Elem. Cliem^

243. This confusion of terms leads to a confusion of facts of a much more serious
kind. English electricians uniformly state that the magnetic needle, deviating in the
neighbourhood of a current, takes no note whatever of the intensity of that current.
Continental writers, almost without exception, regard the deviation as a function of the
intensity, and the statements, therefore, appear discordant. While the effect is thus dif-
ferently described, all agree as to the facts of the case. In what follows, the term tension
will be used as expressive of the elastic force of the current, that power by which it is
enabled to pass a resisting medium ; the term intensity will be strictly confined to the
acceptation in which writers on analytical mechanics use it. "By the intensity of a force,
we understand its greater or lesser capacity to produce motion" (Boucharlat) ; and in
the case before us, the intensity will be regarded as a function of the quantity and ten-
sion conjointly. Thus, the deviation of a magnetic needle does not indicate the ten-
sion, but the intensity of a current.

244. Suppose, now, we had a current of electricity passing under a certain tension,
along a channel of conduction, as a bar of large dimensions, and were suddenly to in-
terpose in some part of its path a resisting obstacle, as, for example, a slender wire ; it is
obvious that a certain portion of the current would pass the barrier, a portion deter-
mined partly by the character and dimensions of the wire, and partly by the tension or
elastic force of the current. Let the wire under all circumstances be the same, the ab-
solute quantity of electricity be constant, but the tension thereof vary. Now, as the
tension increases, the quantity that passes the resisting wire will also increase, and as the
one diminishes, so will the other too. Under these circumstances, the absolute quantity
that passes will always be an increasing function of the tension; and as this quantity is
under all circumstances measureable by the deviations of the magnetic needle, or by the
voltameter, these instruments may be used to determine the tension, by making quan-
tity indirectly the measure thereof

245. If, therefore, we send a certain quantity of electricity, as 100 parts, to a resist-
ing wire, and find that of these 50 parts can pass the obstruction, we may assume such
a current to have a higher tension than one containing the same absolute quantity, of
which only 30 could pass ; and to have a much lower tension than one, of which 70,
80, or 90 parts could pass. In all these cases, the amount per cent, of the main cur-
rent which passes the resisting wire may be taken as the representative of the tension
of that current.

246. This obstructing, resisting wire, I call a secondary wire.

247. But it is plain that this amount per cent., of which I am speaking, in introdu-
cing this fundamental proposition, is nothing more than the ratio which exists between
the quantities passing the large and the little wires respectively. By dividing, there-
fore, the quantity that passes the secondary wire by the quantity that passes the large
wire, \Ve shall have a numercial representative of the relative tension of the current un-
der consideration.

DESCRIPTION OF THE TORSION GALVANOMETER. 75

248. Let us take an example : a single pair of plates developed a current of electri-
city, which, when measured at the torsion balance, was found equal to 20 degrees ; on
subjecting this current to a secondary wire, 7 degrees passed it Its tension might,
therefore, be represented by -3500. A second pair was now added in conformity to
the first, 31 parts passing ; but when subjected to the secondary wire, 18 were indicated.
The tension had now become -5806: in the same way, by adding three more pairs, the
tension rose to -6346.

249. It must now be borne in mind, that the numerical determinations thus procured
are entirely conventional ; their absolute value depends upon the resistance of the
secondary wire, and they therefore only express the relative condition of different
currents.

250. As a considerable advantage will be gained, and much repetition avoided, by
here indicating the mode adopted for procuring the following measures, I shall describe
at once some modifications and additions which are necessary in the torsion balance,
the instrument generally employed.

251. The voltameter has of late come much into use in investigations of this sort,
but when compared with the torsion balance, the latter is much more speedy and cer-
tain in its indications, and should generally be preferred. In point of fact, the indica-
tions of the two instruments are entirely of a different character ; the magnetic needle
shows the quantity of electricity that is passing in each indivisible portion of time, the
voltameter the quantity that has passed at the end of a finite time. In the conditions
of the action of the one, time enters as an element, in the other it does not.

252. By applying a glass thread to the needle, the late Dr. Ritchie greatly improved
the accuracy and general utility of the galvanometer ; but even with that addition,
unless certain precautions are taken, the instrument will not work satisfactorily ; the
motions of the needle are too versatile, and the tremulous state of vibration into which
it may be thrown are insuperable barriers to accuracy of measurement. A cylindrical
trough filled with water is a perfect and admirable remedy for these difficulties.

253. Another difficulty, which is very generally overlooked, is the excentric position
into which the thread is liable to be cast, when the upper micrometer has moved. The
construction of the instrument requires that the axis of motion of the upper micrometer,
the axis of the glass thread, the axis of the spindle carrying the needles, and the vane,
should be in the same vertical straight line, through whatever arc the micrometer may
have moved. Now it would be very difficult to accomplish this by any system of
adjustments.

254. Whether the instrument is arranged with one or several needles, or whether it
has a coil or merely a single strap, the vertical distance from the coil or strap, when
the index is brought to zero, ought under no circumstances to vary.

255. In a climate as hot as that in which the following experiments were made, one
of the most unpleasant deviations depends on the thread wrenching in the wax, which
is used to fasten it to the needles at one end. and to the micrometer at the other;- when
the wax softens, and the thread is moved through several degrees, it is not the free part
alone that undergoes torsion, but also that which is in the wax; hence arises an error as

^g DESCRIPTION OF THE TORSION GALVANOMETER.

respects the zero point. This I have always avoided, by ascertaining the zero at the
beginning and close of each experiment. i

. 256. After having had some experience with voltameters, deflecting galvanometers,
&c., 1 am induced to describe the instrument used in these experiments, for it will ena-
ble those who are not accustomed to the torsion balance to execute measures very
easily, which they might otherwise ineffectually attempt.

257. A A, B B {fig. 28), is a glass jar, 16 inches high, open at both ends; at A A
it is 22 inches in diameter, at B B 6 inches ; it rests upon a piece of wood 8 inches by
lU. A strap of stout sheet-copper, effe, 1 inch wide and 15 long, is bent into the
form indicated ; its extremities at e e being let into the wood, and bearing mercury
boxes, D D. The central part of this strap, irom f io f, is placed horizontally, and has
a circular aperture and side gap, as is shown '\nfig. 29, a a, through which the spindle
carrying the needle can be passed, and works.

. 258. The upper extremity of the jar, A A, is accommodated with a divided circle, in
the centre of which the key G works : this key is ground, like a stopcock, to a slightly
conical figure ; it therefore revolves very truly without any shake : it is drilled longitu-
dinally to admit the passage of the glass thread, which is secured in it by means of a
perforated straw and a drop of sealing-wax.

259. The other extremity of the thread enters a little tubular perforation in the ivory
axis, n n', and is also secured therein by wax. Only one needle is used ; it is lozenge-
shaped, and is 4^ inches long. Besides carrying this needle, the ivory axis extends an
inch and a half below it, and in a slit at its lower extremity, confines a parallelogram
of stout tinfoil, r r, an inch wide, and 2f long. When in use, this vane of tinfoil works
in a glass cup, k k, 3^ inches in diameter, which is filled with water.

260. One of the chief improvements in the instrument is connected with the needle,
and the axis on which it \vorks. The latter is a small cylinder of ivory ; it has two flat
faces filed upon it, corresponding to the direction of the needle. On each of these
faces, as is represented in {fig. 30), is drawn a vertical line, and a little to the right of
it are placed five dots. The polar extremities of the needle are accommodated with
two upright wires, p p' , p p' , an inch long, which serve as indexes; and at a distance
of 10 or 15 inches, in the magnetic meridian, a plate of metal, not shown in the figure,
with a small hole in its centre, is placed, to be used as a sight. When an observation
is to be made, the experimenter adjusts this sight in front of the instrument, either on
its north or south side ; and on looking through it, as soon as the needle moves, he
sees the index, ^p', traverse before the scale 07i the axis. There is no shake or vibra-
tion, even though any one should cross the floor or jar the table, for the index and
the scale equally participating in all these disturbances, the motion is almost as steady as
that of a shadow on a sundial ; the vane of tinfoil does not in the least interfere with
the accuracy of indication, but effectually stops the oscillations, and the utmost accuracy
may be obtained, by previously giving the index, p^', a slight bend out of the vertical
line, amd using the five dots as a diagonal vernier.

261. In the following memoir, it will be seen that the terms primary and secondary
wire are occasionally used, the former in a somewhat extended sense : I mean by i^

RESISTANCE OF THE SECONDARY WIRE UNDER VARIATIONS OF TENSION. 77

not only the thick polar wires that come from the electrometer, those which were used
being one fifth of an inch thick, but include the electroraoter itself, no matter what
its character maj be — ^if a hydro-arrangement, the plates, exciting Hquid, &c. The
secondary wires are simply long or slender wires, to obstruct the current ; of these I
have occasionally used two, the first 47 inches long, the second 290 : they are of
copper, one foot of which weighs 10-65 grs., and are covered with silk.

262. And, lastly, the measures are sometimes arranged in a form such as this :

100

50 5 -^^^O'

in which the large or upper number represents the quantity passing the primary wire, the
under or smaller number the quantity passing the secondary wire, and the decimal on
the right hand of the bracket, being the quotient of the former numbers, is, as will
presently be shown, the representative of the tension.

263. We have now to examine the foregoing proposition more minutely. Let us call
the primary wire, being that wliich is in connexion with the electromotoric source, A;
and the secondary or resisting wire, B. Now how does B act towards currents when
they are of variable character ? There is no current, no matter how low its tension
may be, that will not pass along B to a certain extent: this is abundantly proved by
such a wire transmitting a thermal current of the lowest tension and amount. But at the
other extremity of the scale is there a limiting point ! Can a wire conduct electricity of
a certain tension only to a certain amount ? I think not, for a wire of small diameter
was found upon trial to conduct a thermal current to the extent at one time of 20, and
then of 284 parts, the tension in both cases being the same ; and if it would do this in
the case of currents whose tension is so very low, the same might be looked for in
hydro-currents ; here, however, when the quantity reaches a certain point, the ignition
of the wire ensues, and its physical character is changed. Sir Humphrey Davy's experi-
ments lead to the same conclusion {Phil. Mag., Dec, 1821), nor does there appear to be
any limit to the conducting power of a wire, either for high or for low tension. If a wire
carries a certain amount of electricity, an increase of quantity or of tension will enable
it to carry more, and the converse. To this important point I shall presently return.

264. As it thus appears that any increase of the quantity which A transmits involves
also an increase of that wliich passes B, a second question arises. What is the ratio
that will be observed in the two cases ? If the quantity passing A be doubled, will the
quantity passing B be doubled also! This is a very important problem; for if the
ratio above mentioned holds, it would show that an observation by the secondary wire
will give the tension independent of the absolute quantity. Let o represent the quan-
tity traversing A, and b the quantity traversing B. Now, if the tension remains constant,

and the quantity only is variable, the ratio - is always constant, and is entirely indepen-

a
dent of the value of a.

265. This I have endeavoured to prove experimentally. I took a hydro-electric pair
of copper and zinc, each of the plates exposing about two square feet of surface, and
dipped them to difierent depths in dilute sulphuric acid. The following table exhibits
one of these results :

78 RESISTANCE OF THE SECONDARY WIRE UNDER VARIATIONS OF TENSION.

TABLE A.

Primary Wire.

Secim. Wire.

Calculated.

49

34

34

37

26

256

24

17

166

13

9-50

90

and therefore we infer that the foregoing ratio holds.

266. Currents of very low tension give proofs of the same fact. A thermal pair of
platina and palladium passed 44 through the primary, and 19-50 through the secondary
wire; and when, by increasing the temperature, 236 passed through the primary, 115
went through the secondary wire. In a pair of palladium and silver, 165 and 1130
being passed successively through the primary, 43 and 313 went through the secondary
wire. In a pair of iron and platina, 170 and 249 being successively sent through the
primary, 79 and 112 respectively passed through the secondary wire.

267. But let us farther suppose that the quantity of electricity passing at different
times through the primary wire A is constant, its tension alone undergoing an increase.
If A formerly conducted all that was presented to it, it will, under this new condition
of things, of course still do the same. Such, however, will not be the case with B, for

a greater quantity is now enabled to pass it than before, and the ratio - will give a

greater value ; we shall therefore, in this case, have a measure of the tension. But if
the tension still keeps increasing, h will continually approach to equality with a ; and
when the tension is infinitely high, these quantities are accurately equal to each other ;
or, in other words, when the elastic force of a current is infinitely high, its tension is
unity.

268. If, on the other hand, the tension becomes lower and lower, b continually de-
creases, and, finally, might be found equal to zero. The value of the ratio then be-
comes zero ; and, therefore, at the two extremes, or where the tension is unity and
where it is zero, the secondary wire, so far from ceasing to act, still truly indicates the
condition of the current.

269. While, therefore, A conducts freely the whole current, B will measure its ten-
sion under all circumstances ; but, in point of practice, we can never make the adjust-
ment here hypothetically indicated, or so arrange a wire A that it shall conduct all the
electricity presented to it. Let us, therefore, here inquire how this variable condition
of both wires will affect the result. Let the tension (t) so change by any amount as
to become (n t), then a corresponding change will happen in a and b, admitting the
principle that the quantities passing through A and B are increasing functions of (t).

If, then, (f) becomes (n i), a will become (n a). Now, if the equation - = t holds,

b = at; but, when the change impressed on (t) has happened, b will be equal
to the conjoint values of (n a) and (n t) ; and, if these values be substituted in the for-
mer ratio, the resuU is still equal to {n t) ; so that, whatever may be the change im-
pressed on (t), the formula - = t will always indicate it.

270. Having thus settled, by the foregoing simple reasoning, the fundamental doc-

CONDITION OF THE CURRENT NEVER CHANGES. 79

trine of investigation, I next proceed to apply it to the analysis of the different pro-
cesses, by which a change of tension is supposed to be impressed on an electric cur-
rent; and this leads to the consideration of the second proposition :

271. " That there is reason to doubt Avhether the processes usually supposed to af-
fect the condition of an electric current are ever attended with any such result ; but
that, when changes have apparently taken place, it is probable that they may be directly
traced either to a disturbance at the place of generation, or to the development of other
currents of a different character, the primary current itself remaining unchanged."

272. It is popularly supposed that if we pass an electric current through a wire of
certain length, coiled upon itself, a kind of inductive influence will be exerted, so that
the current shall become more and more intense as it goes. Or, if two currents are
simultaneously passed into a double helix, they will mutually fortify each other.

273. (a.) A wire, covered with silk, 48 feet long, and arranged as one circular arc,
had a current passed through it which produced a deviation of 35 degrees. The same
wire was then coiled round a piece of wood, so as to make 1.55 circumvolutions; the
deviation was still 35 ; and, therefore, no change was impressed on the current.

■ 274. (b.) A thermal current was passed through a straight wire with the following
result :

^^|-5238.

The wire was then coiled into a helix, the current passed through it and measured ; a
powerful bar magnet was next introduced into the helix, and then a rod of soft iron. But
in all these cases the measured numbers were absolutely the same as before. There-
fore there is no change impressed on the thermal current, either in relation to quantity
or tension, by making it pass along a coiled wire, or by acting on it with a magnet or
a bar of soft iron.

275. (c.) The same experiments were made with a hydro-electric current, and they
gave the same results.

276. (d.) The above-mentioned (hi) thermal current was passed along one of the wires
of a double helix, and through the other wire a hydro-current was passed, from a single
pair of plates; but the tension and quantity remained the same as before. On sending a
current of still greater intensity, viz., from a voltaic series of five pairs of plates, the same
result was still obtained ; the hydro-current had power enough to decompose water.

277. («.) On altering the polar communications, and thereby changing the course of
the current, no change whatever in the primary current, either as to quantity or ten-
sion, was observed.

278. It is well known, that by using a long wire as a discharger of a single pair of
plates, a spark will be obtained of a much more brilliant character than when the cur-
rent passes through a shorter wire ; it is upon this fact that the flat spiral riband coil is
constructed. Many electricians have supposed that the results obtained by this beau-
tifid contrivance were partly due to the inducing action of the successive spires, but
chiefly to a long and easy conducting channel being open to the current, which gath-
ers momentum in its passage. I have already shown that there is no permanent action

80

TENSION RISES WITH LENGTH OF WIRE,

of induction in the case of a coiled wire, an observation applying equally to an elon-
gated helix and to a flat spiral. Let us now determine whether the increased tension
is due to momentum.

279. A copper wire 46 feet long and A inch in diameter being arranged as the
discharger of a single pair of plates, a brilliant spark was seen to pass ; but with a wire
of the same diameter and a foot long, the spark was barely perceptible. The quantity
and tension in each case were now determined.

TABLE B.

Short wire
Long wire

39 >
12 (
13

8

I

3076
6153

Hence, by the use of a long wire, we greatly increase the tension of an electric current.
A second experiment, in which a wire i, and a third, in which a wire j of an inch in
diameter, were used, gave analogous results. In neither of these cases, however, did
the tension rise so high as in the former ; it was lower as the diameter of the wire was
greater.

280. This increase of tension follows the increase of the length of the wire, as the
following measures show.

TABLE C.

Ex.

Current from a single pair of plates

a long wire introduced

a second ditto., added

third

fourth

Quantity.

79
44
27
21
15

Tension.

■4177
•5909
•7222
■7619
■8333

Thus, by successively increasing the aggregate length of the discharging wire, the ten-
sion continually increased, commencing at -4177, and finally becoming -8333. Similar
experiments with other wires gave similar results,

281. Now is this remarkable rise of tension due to a momentum which the current
acquires on the wire 1 Or does it arise from the fact, that the wire acts simply as an
obstacle, reacting thereby on the electromotoric plates, the increase of tension being
due to them, not it ] This is easily determined; for if the rise of tension be due to the
plates and not to the wir;% a short wire, slender enough to obstruct the current to the
same extent, ought to act equally as well as the long wire.

282. This experiment, the result of which leads to the true theory of voltaic combi-
nations, I shall carefully describe.

283. I took a copper wire 46 feet long and tV inch in diameter, and found that it
Stopped a certain portion of the current coming from a single pair of plates. The mi-
crometer of the balance was now turned, and the needle brought accurately to zero.
Then I cut off from another slender copper wire such a length (2 feet 10 inches) as
to obstruct the current to the same extent as the long wire, the needle being brought,
when it was interposed in the path of the current, to zero. The secondary coil was
now introduced ; it of course stopped off a certain portion of the current ; but the mi-
crometer was again adjusted, until the needle was brought to zero. And now the long

AND WITH DISTANCE OF THE PLATES. 3I

wire being introduced, and the slender one taken away, the needle came again to zero.
But I suppose, if the long wire had impressed more tension on the current than the
slender one, either by momentum or otherwise, more electricity should have passed the
secondary wire when it was used, which is not the case.

284. Again, I took a copper wire 242 feet long and tV inch in diameter, and adjusted
to it a fine iron wire as before : the extremities of this wire were tinned; it was 12 j inches
long. Either of these wires being used as a discharger, brought the needle to the same
point of the scale. On using the secondary wire and the long wire together, I adjusted
the needle accurately to zero, and then passing the current through the fine wire and
secondary wire, it came again to zero. And this was repeated often, and so near was
the adjustment, that, when an assistant turned first one and then the other wire on, it
could not be told which was in action, or whether the current had come along the long
or the short wire. A long wire, therefore, impresses no sort of change on a current,
but merely serves as an obstacle ; for, in the first case, we had one wire sixteen times
longer than the other, and in this we have a wire more than 230 longer than the one
with which it is compared, yet the tension has increased only to the same amount in
both.

285. And the same results were obtained by the voltameter.

286. The current that flows in a simple closed voltaic circle may be resisted in two
ways : 1st, the length of the wire connecting the plates may be increased, as in the
foregoing experiments ; 2d, the connecting wire remaining of constant length, the dis-
tance of the plates may be increased : the result is the same in both cases, a rise of tension.

TABLE D.

Ki.

Disujice of the pi&les in iBcbes.

QnuiOtj.

Tenson.

I
9
9

2 75

4 50

9fl0

Ill

50

27

7297
7600

8888

So that, whether we obstruct the current by lengthening the connecting wire or by
increasing the distance of the plates, the general effect is the same, the tension imme-
diately rises ; that increase of tension being due to the plates themselves, and not to the
channel of conduction. This brings us to the third proposition,

287. " That there are two different methods of accompUshing these disturbances, and
thereby of raising the elastic force of a current. 1st. That tension may be augment-
ed by the sacrifice of quantity ; Volta's plan of a reduplicated series, and He.nry's rib-
and coil in its condition of equiUbrium, being examples. 2d. By the introduction of
new afliuities in the exciting ceUs ; batteries charged with nitrosulphuric acid or sul-
phate of copper are examples."

288. A single pair of plates, under the influence of a long wire, or the spiral coil,
presents a remarkable analogy to Volta's pairs arranged in reduplicated series. In point
of fact, they may be considered as scarcely differing from each other either in mode of
action or in effect The study of the single pair under this condition reveals at once
the theory of the voltaic action.

289. If we inspect tables B, C, D, we are at once furnished with the fimdamental
fact which is the basis of explanation. When we compare together the tension and

L

82 RELATION BETWEEN QUANTITY AND TENSION.

quantity of the electricity flowing in the primary wire, we are struck with the fact, that
whenever the one has increased, the other has diniinished. No matter what the other
conditions may be, loliether the communication is made hy a long wire or a short one,
whether the plates are near or far apart, whenever the quantity is diminished, the tension
increases ; and whenever the quantity increases, the tension is diminished.

290. The remarkable analogy of the ponderable elastic fluids, which, when their vol-
ume is diminished, or, in other words, condensation takes place, experience an increase
of tension or elastic force, is here too broadly indicated to be mistaken.

291. When I first saw that removing the plates to a greater distance apart deter-
mined a given rise in the elastic force of the current, for a time it appeared to me that
Dr. Faraday's theory of the tension being due to the affinity of the zinc for oxygen
must certainly be incorrect. A more extensive acquaintance with the facts has reversed
that opinion. If the tension be determined by the affinity of the metal for oxygen, which
must be a constant force, how comes it to pass that moving the plates to a greater dis-
tance apart can cause it to increase ? This apparent paradox, when properly under-
stood, forms a fine illustration of the truth of the doctrine advanced in the 5th, 7th, and
8th series of that philosopher's researches. In what follows I shall, therefore, regard
those doctrines as established.

292. Let us take a given pair of plates, and connect them together by a slender wire.
We find that the quantity that the plates generate is diminished, and its tension is in-
creased ; but that this has not happened either by gain of momentum or inductive
influence in the channel of communication, and we are compelled to refer the effect
to the resistance of the wire, placing the plates and the electrolyte between them in a
state of force. If this be the action of a resisting medium, we might suppose that by
continually increasing it we should continually increase the tension, and when it be-
came infinitely great, the tension would be so too. But what is the true action of a
slender wire, connecting in this way a pair of plates ? A certain amount of electricity
passes along it, but not the rcihole quantity that the plates could generate in a given time ;
yet we cannot suppose that all that does pass comes from the whole surface exposed, and
not from a fractional part thereof The water and zinc are ready to generate, and, as
it were, attempting to drive a fresh quantity of electricity through the wire; and, accord-
ingly, as the quantity that actually passes becomes a greater and greater portion of
what the system actually tends to put in motion, the tension becomes less and less.
The tension would therefore become zero if the whole circle wires, plates, and elec-
trolyte could carry air that the zinc and water could generate. The limit prescribed
to its diminution is the conducting power of the electrolyte, which is the worst con-
ductor of the system.

293. This hypothetical condition, of a tension ranging near zero, is most nearly ap-
proximated to in a thermal pair.

294. Suppose, now, that everything remains the same as respects wires, electrolyte,
distance of plates, &c., except that the dimensions of both plates are doubled. Shall
we increase the tension ? No ; for although the surface in action is doubled, and the
absolute quantity which the system could generate is doubled, yet the quantity that

THEORY OF TENSION OF THE VOLTAIC BATTERY.

83

passes both the primary and secondary wire is also doabled : the ratio - is tlierefore

the same as before. For this reason, increasing the magnitude of the plates increases
the quantity only, and not the tension.

295. Under all these circumstances, therefore, the tension depends on the ratio of
the quantity that does pass the combination, to the quantity that the system tends to
put in motioD.

296. Before, however, we can go farther in the study of these conditions of tension,
or attempt to show that the arrangement of Volta, and a single pair under the influence
of a long or thin wire, are, in point of fact, alike in principle, it is necessary that we
should understand the nature of the different disturbing actions that may arise in the
generating cells of the electromotor.

296. I took a zinc plate 7 inches long and 3 wade, and a corresponding copper :
the surface of the former was amalgamated and the latter brightened. The plates were
fixed at an immovable distance from each other, and inunersed in a jar containing 34
ounces of water. Sulphuric acid was then added by half drachms successively.

TABLE E.

Elp. I Qnutity of vnd in

QMBtitT.

1.
S.
3.

4.
5.
6.
7.
8.
9.

i

1

1*

3

3

Si

4
8

SO

39

55

72

83

98

112

121

216

555
-436
■38S
-305

•277
-245
•223
214
130

298. Here we have an exemplification of the converse of the fact already so much
insisted on. As the quantity developed fi-om the same surface gradually became greater
and greater, the tension became less and less, due to the increased conducting powers
of the fluid medium. It is the same effect that would have been produced by constant-
ly shortening the connecting wire.

299. Such is the action of increasing doses of sulphuric acid ; let us now see how
NITRIC ACID will act The copper plate being repolished, and the zinc reamalgamated,
and everything else being as at the commencement of the former trial, the latter acid
was now added to the cell in the same way that the former had been used.

TABLE F.

Qauititf of acid ui dradutt.

*

1

u

4

Exp.

QtUAtitT.

14

•7143

22

6363

36

5555

175

2400

These measures are effected with some difficulty, as the acid acts somewhat irregu-
larly, and keeps the needle vibrating.

84

THEORY OF TENSION OF THE VOLTAIC BATTERY.

300. Muriatic acid, under the same conditions and circumstances, being substi-
tuted, gave as follows :

TABLE G.

Eip.

Quantity of acid in drachms.

Quantity.

Tension.

1.

i

10

•8000

2.

1

17

•6530

3.

li

23

•6087

4.

2

29

•5517

5.

8^

34

•5000

6.

3

39

•4872

7.

3i

44

•4654

8.

4 ......

49

•4387

9.

8

82

■3169

10.

16

145

•1938

11.

24

203

•1707

301. NiTRosuLPHURic ACID, the Constituents of which were added alternately ia
equal measures, was next tried.

TABLE H.

Exp.

Acid.

Quantity of drachms.

Quantity.

Tension.

1.

Sulphuric.

i . . . .

23

•5652

2.

Nitric.

i . . . .

63

.5094

3.

Sulp.

1 ....

72

■3888

4.

Nitr.

1 ....

94

•3510

5.

Sulp.

2 . . . .

178

•2360

6.

Nitr.

2 . . . .

190

•2026

302. Solution of sulphate of copper was next experimented with.

TABLE I.

Exp.

Quantity.

Tension.

1.

a.

3.

33

74
116

■8181
•6081
•4741

These measures were procured with difficulty, owing to the flocculent deposit which
settled on the zinc, more rapidly as the solution was made stronger.

303. In the general discussion of the measures given by tables E, F, G, H, I, we still
see the operation of the same general law, that the tension rapidly diminishes as the
acid is added, and that when the same quantity of electricity developed from the same
amount of surface by these different acids is presented to the secondary wire, tiie quan-
tities that can pass that wire are very different; and on making use of these different
agents, it would appear that they can give rise to currents from the same metalline sur-
face, equal in point of quantity, but differing greatly in point of tension, in the follow-
ing order, beginning with the most powerful :

Sulphate of copper. Muriatic acid.

Nitric acid, Sulphuric acid,

Nitrosulphuric acid,

304. Of these bodies, the muriatic acid acts probably m the way that Dr. Faraday
has pointed out, but the immediate cause of the rise of tension in the others is to be
traced to the circumstance that they furnish oxygen to the nascent hydrogen ; and if the
tension of the ordinary current is made to depend on the tendency of the zinc and ox-
ygen to unite, it is reasonable to suppose that that tension will increase if a new affin-
ity be introduced, the action of which should correspond with and abet that of the zinc
for oxygen. This takes place when nitric acid or an oxysalt of easy decomposibility
is added to the solution. The tension of the current is not then determined by the af

THEORY OF TENSION OF THE VOLTAIC BATTERY. gg

finity of the zinc for oxygen only, but by all the aflSnities that can take place among all
the bodies in the exciting cell. We are, therefore, here led to expand Dr. Faraday's
theory, and to regard what follows as directly opposed to the theory of contact.

305. Upon these principles, in an ordinary arrangement of copper, zinc, and sulphuric
acid, the tension of the current is determined, by the sum of the affinities of zinc for
oxygen, and hydrogen for copper, diminished by the sum of the affinities of copper for
oxygen, oxygen for hydrogen, and hydrogen for zinc.

306. But as, under all ordinary circumstances, the affinities of hydrogen for zinc and
copper may be neglected, they being exceedingly small in comparison with the others,
we may assume,

307. That the tension of the current is equal to the affinity of oxygen for zinc, di-
minished by the sum of the affinities of hydrogen and copper respectively for oxygen.

308. If now we introduce into the exciting cells nitric acid or sulphate of copper, the
affinity of the nascent hydrogen for oxygen is satisfied, and the resistance from this
source is nearly exterminated, and the tension of the current is then equal to the dif-
ference of the affinities of zinc and copper for oxygen.

309. By thus exterminating the resistance arising from the affinity of hydrogen for
oxygen, we succeed in raising the tension greatly ; if next we get rid of the affinity of
copper for oxygen, the tension ought to become still higher. This may, in a measure,
be effected by making use of a plate of platina, as I found experimentally.

310. In all these cases, in which the tension increases without loss of quantity, we
directly trace the action to a disturbance in the exciting cells. In ordinary voltaic ar-
rangements, the maximum tension is never reached, because the affinity of zinc for ox-
ygen, which determines the current, is counteracted to a certain extent by the affinity
of oxygen for hydrogen. If we satisfy that affinity, an increase of tension is the result,
and accordingly as this is more and more nearly effected, more and more of the hydro-
gen that ought to be evolved disappears. This remarkable disappearance of hydrogen
has been heretofore noticed, but the true office it served has not been detected. If a
battery is charged with nitrosulphuric acid, the hydrogen evolved is no longer the equiv-
alent of the zinc expended ; in point of fact, the gas evolved is no longer hydrogen, but
a mixture of hydrogen and the binoxide of nitrogen, as is proved by its burning with a
green flame. I took a small pair of plates, the zinc being amalgamated and the platina
freshly cleaned, and placed them in a mixture of six ounces of water and one drachm
of sulphuric acid, arranging an inverted tube over them, so as to collect the gas from
the platina plate. I determined by weighing the zinc plate how much was expended
in evolving a given quantity of gas; and then successively adding sulphuric acid until
the total amount had reached eight drachms, it appeared that in each instance it re-
quired very nearly 1-79 grains of metal ; but on adding one drachm of nitric acid to
the mixture, the quantity expended rose at once to 2*25 grains, and on adding a
second, to 3-00 grains.

311. Therefore, unless care is taken that no oxidizing body is present, the voltame-
ter will give deceptive results. This important precept should be perpetually borne
in mind by those who employ it in investigations. A few drops of nitric acid will at

86 KNOWN METHODS OF INCREASING THE TENSION OF CURRENTS.

once vitiate its indications ; and there is reason to suspect that, under certain circum-
stances, even the dilute sulphuric acid with which it is charged may undergo partial de-
oxidation, and the evolved hydrogen indicate an amount of electricity less than is actually
passing.

312. We are, therefore, in possession of two distinct methods of indirectly increas-
ing the tension of an electric current. The first depends on the reduction of quantity ;
the second, on satisfying in the exciting cells affinities which tend to antagonize that
which determines the current.

313. Volta's plan of a reduplicated series unquestionably acts upon the first of these
principles. It is a fact admitted on all hands, and, therefore, into the proof it is un-
necessary now to go, that the apparent quantity circulating in the whole battery is not
greater than that which anyone of the pairs could generate. Dr. Faraday has already
shown how an enormous quantity of zinc is thus expended, the equivalent of electricity
being entirely sacrificed for the sake of increasing the tension. Let us see what are
tlie facts in the case. The first pair of plates develops by the oxidation of a portion
of its zinc a certain quantity of electricity, which, passing through the electrolytic con-
ductor, arrives at the second cell ; here, however, it is stopped, as a transit without de-
composition is impossible, a decomposition which it is unable to effect. Continually
tending to pass, without the passage actually taking place, it remains, as it were, on the
surface of the second zinc plate, in a condensed state, reacting on the electricity which
that plate is generating, compressing and being compressed by it, and, therefore, increas-
ing its elastic force. And the same action continually occurs, and increases the ten-
sion throughout the series.

314. A flat spiral coil, or a long connecting wire, obviously acts in the very same
way. It opposes a resistance to the passage of the current, and the plate instantly be-
comes in a forced state. We might almost regard the electric fluid as existing upon
the surface of the zinc, exerting to the utmost its elastic force to pass the barrier, and
failing that, compressing the evolved fluid as fast as it is generated, and being compressed
by it. This, also, is the case in the pile of Volta.

315. Thus far, therefore, the riband coil acts simply as a long wire, and this may
be regarded as its primary or statical effect. But, besides this, it gives rise to an
action of an entirely different character, which Professor Henry pointed out and ex-
plained. In the act of making and breaking contact in a system of which it forms a
part, Faradian currents are generated by its successive spirals ; these currents under the
latter condition, breaking contact, coincide in direction with the primary current then
just ceasing to pass. We must, however, carefully distinguish between these currents
and that which induced them. In this respect some philosophers have unguardedly
fallen into a very remarkable mistake ; it has been supposed that when a thermo-electric
current was passed through this coil, and a spark obtained, the thermal light was seen!
The case is exactly analogous to that in which similar coils pass the jaws of a horse-
shoe magnet; no one supposes that the spark then elicited is due to the electricity of
the magnet itself, but is simply a manifestation of the induced current ; the very same
thing takes place when the thermal current runs through the spires of a flat coil. So

GENERAL LAW.

87

far as I am informed, the magnetic spark and the true thermo-electric spark have never
jet been seen.

316. These observations are made in order that I may not be misunderstood. It
is not my object to consider the different arrangements that can generate a Faradian
current, and, therefore, in this point of view I dismiss the flat spiral

317. We now come to the fourth and last proposition, which is, " That the law
which regulates the connexion of the diminution of quantity or condensation with the
increase of tension, is the same as that which regulates the analogous phenomena of
ponderable elastic fluids."

318. I have not hesitated to use the terms "compression," "condensation," "elastic
force," in reference to electricity, though I well know such an application is unusnaL
But it has seemed to me that a single pair might almost be likened to a steam-engine
boiler, from which if you let the steam escape by a wide tube, its elastic force is less
and less, accordingly as the escape is more free ; but, if you put upon it a narrow tube,
the vapour rushes with vehemence through it, reaction in a moment occurs in the
boiler, the elastic force increases, and the accumulated steam pressing heavily on its
surface, the water boils in a more laboured way : this narrow tube resembles Henry's
coil, or a long or slender wire.

319. The following table exhibits numerical results obtained by the aid of one of
Dasiell's constant batteries, the tension being continually increased by the addition of
successively increasing lengths of wire

TABLE K.

Qunutj.

CllrBlMtKl.

TlBilll

P"*^- V End of ditto.

Y

75

«89

Wire interposed 6 feet long

78

78-00

8333

" " 18 "

68.50

68 30

-8304

" " 18 "

65

65i»4

-8461

U «4 24 **

a

63-30

■8548

U U ^ U

63

5313

■8679

« u 7t u

46

46-18

■8913

" " 96 "

41

41-00

-9219

320. From this table it would appear that the addition of successively increasing
lengths of wire of invariable diameter diminishes the absolute quantity of electricity
flowing, but at the same time the tension is exalted. By taking the angle of torsion as
the measure of the forces, in the second column, it is also evident that the law of the
conducting power of wires given by M. Lenz holds in the case of a hydro-electric pair.
This may be regarded as of some interest, inasmuch as the late Dr. Ritchie, in certain
papers read before the Royal Society, opposed to the very last this view, b>- the aid
of numerical determinations made with the torsion balance, the instrument here em-
ployed. In reference to the third column of the table, I have calculated it in the man-
ner given by Lenz, the value of the constant to be deduced from the reciprocals of the
angles of torsion being in this case 1318 nearly.

321. While, therefore, these results confirm, in the most pointed manner, the reason-
ing of that able philosopher, they at the same time compel us to advance a step far-

88

CASE OF THERMO-ELECTRICITY AND MACHINE ELECTRICITY.

ther, and to expand, to a certain extent, Ohm's theory of the voltaic pile. It is a con-
dition, in tracing the action of wires of different lengths, to assume that the electromo-
tive power of the generating pair is under all circumstances constant, and hence it may
be conveniently represented by unity. But the electromotive power of any pair plainly
depends on ttoo things: the quantity of electricity that the pair can evolve, and its abso-
lute tension. The theory of Ohm, as may be gathered from the memoir of Professor
Jacobi on electromotive machines, and also from M. Lenz's papers, confounds those
two important conditions.

322. Now the results given in the foregoing table, proving that wires conduct in
the inverse ratio of their lengths, prove, also, that the addition of increasing lengths of
wire does not in any wise alter the electromotive power ; yet we have clearly shown
that this addition is inevitably attended with an increase of tension. Here, therefore,
is an apparent contradiction.

323. But this contradiction is only apparent, and, when properly understood, leads to
a most remarkable result.

324. It is true that we are compelled to assume that the electro-motive power of a
pair is independent of the length of the connecting wire ; but this constancy of electro-
motive power does not necessarily imply that the relations of quantity and tension,
which conjointly produce it, are not themselves variable. In the case before us, we
have direct proof that the tension increases, and also that the quantity decreases, as
the connecting wire becomes longer, and the converse ; yet the electromotive power
varying directly with them both, they must of necessity bear such a relation to each
other, that their product shall always be equal to unity. Hence we infer,

325. That the law of Marriotte in relation to the ponderable elastic fluids holds,
also, in the case of electricity developed by voltaic action, the elastic force or tension
of a given quantity being inversely as the space it occupies.

326. The following table will at the same time estabhsh Lenz's law in the case of
thermo-electric currents, and prove that even in cases where the tension is so exceedingly
low. the elastic force of a given quantity of electricity follows the above-named law.

TABLE L.

Quantity.

Calculated.

Tension.

Without any wire . . .

720

0930

Interposed wire 1 foot long

298

298

•2080

" 2 feet long

192

192

3021

" 3

142

142

•3802

" 4

112

113

4375

« 5

93

93

•4731

" 6

80

80

•5000

The current here experimented with was generated by a pair of wires of copper and
tinned iron tV inch in diameter, and one foot long, the soldered extremity being im-
mersed in a bath of boiling water, and the free extremity carefully maintained at 59i
Fahr. ; the third column in the table being calculated by the aid of the constant 1527.

327. As respects electricity of high tension, a law extremely analogous to that here
indicated may be traced. The striking distance varies directly as the quantity accu-
mulates. If a given jar be successively charged with quantities of electricity, as the
numbers 1, 2, 3, 4, &c., the intervals of air through which the spark can pass vary di-

CASE OF THERMO-ELECTRICITY AND MACHINE ELECTRICITY.

89

rectly as those numbers. This is abundantly shown by the experiments of Lane, Har-
ris, and other philosophers.

328. Now upon what does this striking distance depend ? Plainly upon the elastic
force of the coerced fluid, and therefore the striking distance will measure the elastic
force or tension. We condense upon a given surface increasing quantities of the elec-
tric fluid, and find that the law in relation to its elastic force is, that the tension of a
given quantity is inversely as its volume. But this is the law of Marriotte in relation
to the ponderable elastic fluids.

329. The following numerical determinations were made by adding successive plates
to the first single hydro pair, and taking the values of the current on each addition. It
is ofi'ered merely as an illustration of the chief fact under discussion, and is not to be
regarded as absolutely correct, though every precaution was taken to avoid changes in
the current It shows the decrease of quantity and the increase of tension in Volta's
instrument. Of course, in reasoning upon it, the hypothetical action of each plate is
assumed to be equal to that of any other in the series.

TABLE M.

No. of Flues. QoMUkj.

Tensiail.

1.

20

3500

S.

31

-5806

3.

43

5814

4.

51

6274

6.

52

6346

330. Thermo-electric piles are well known to give the same general results, as respects
tension, that hydro-electric piles do ; they are much better suited to the purpose of the
experimenter, and give currents that are far more constant The following table rep-
resents the action of such a battery, consisting of wires of copper and tinned iron, each
element being about one foot long and -^ inch in diameter. The source of heat was
a bath of boiling water.

TABLE N.

Na.>fPuis.

QaautiiT

TeasiMi. 1

1.

256

1367

2.

305

2065

3.

325

■2707

4.

348

3072

S.

352

-3204

11.

396

5275

331. The beautiful experiments of Becquerel, and the equally elegant repetition of
them bv Dr. Golding Bird, show that the view I have here taken of the action of a sin-
gle pair is correct. The latter chemist found, that not only could a single pair decom-
pose bodies, such as iodide of potassium, &c., which easih' yield up their elements, but
that the ammoniacal amalgam might be formed, potassium reduced, and, in point of fact
any decomposition effected. And what is the plan followed ! The current is forced to
pass, in the electrolyte that is to be decomposed, an obstacle or resisting medium ; the ten-
sion instantly rises, but at a vast sacrifice of quantity, so that the magnetic needle, which
measures only the quantity passing in an indivisible portion of time, is barely affected.
Yet by continuing the current for a great length of time, the resulting decomposing
effects are finally the same as those obtained more speedily by the action of many pairs.

M

90 ELECTRIC SPARK BEFORE CONTACT IN VACUO.

332. How far the experiments given in this memoir bear upon that part of Dr. Fara-
day's researches, in which he has determined the relation of common and voltaic electricity
by measure, would form a most important subject of investigation. The results at which
he arrives are in themselves very astonishing, and are fully borne out by his decisive
experiments ; but when we come to reflect that these results were obtained by the mag-
netic needle and electro-chemical action, vve may, perhaps, pause. We may ask whether
it is possible to determine by either of these means the absolute quantity of electricity
that passes. Both measure, so to speak, the volume that flows, the one in an indivisi-
ble portion of time, the other that which has flowed at the end of a finite time ; but do
either of them measure the true absolute quantity ? Can we tell the absolute amount
of a gas without first knowing its condition as to condensation 1 Can we know hoio
much electricity is upon a prime conductor, or compare it with that evolved by a vol-
taic pile, without first knowing its state of condensation ? I shall be excused for em-
ploying these expressions in an unusual way, and for reasoning about this subtle agent
as though it were a ponderable body, inasmuch as it serves, without introducing any
hypothesis, to give us more tangible and distinct ideas of what we might otherwise
vainly attempt to express.

333. In the December number of this journal {L. and E. Phil. Mag., vol xiii., p. 401),
which has just reached me, I find some remarks of Dr. Jacobi on the galvanic spark.
Some time ago I came, by another method of experimenting, to the same conclusion.
If this spark be really projected by the tension before contact, it ought to take effect at
an unlimited distance in a perfect vacuum ; but it will be found, on making the trial,
that if an iron electrode be sealed into the upper part of a barometer tube, and the mer-
cury made to rise gradually towards its point, the spark does not pass until apparent
contact takes place : this was found in an analogous, but vain attempt to show the ther-
mo-electric spark. It cannot, however, be entirely, as that philosopher supposes, " sim-
ply a phenomenon of combustion," as it is difficult to understand how mercury can enter
into combustion in a vacuum.

CHAPTER IX

ON THE ELECTROMOTIVE POWER OP HEAT.
{From the London and Edinburgh Philosophical Magazine for June, 1840.)

Contents : Object of the Memoir. — Experimental Arrangement to determine the Elec-
tromotive Power. — Temperatures calculated from (Quantities of Electricity. — Increase
of Tension xcith increase of Temperature. — Depends on increased Resistance to Con-
duction.— Quantity of Electricity independent of heated Surface. — In Thermo-electric
Piles, the Quantity of Electricity proportional to the Number of Pairs. — Best Forms
of Construction of Thermo-electric Pairs.

334. From the memoir of M. Melloni, on the Polarization of Heat, inserted in the
second part of the first volume of the Scientific Memoirs, we learn that M. Becquerel,

EXPERIMENTAL ARRANGEMENT TO DETERMINE THE ELECTROMOTIVE POWER, gj

as well as himself, has made experiments to determine the quantities of electricity set in
motion by known increments of heat From these experiments, they conclude that
through the whole range of the thermometric scale, those quantities are directly propor-
tional to each other.

335. But as thermo-electric currents are now employed in a variety of delicate physi-
cal investigations, and as there appears to be much misconception as to their character, I
propose in this memoir to show,

IsL That equal increments of heat do not set in motion equal quantities of electricity.

2dly. That the tension undergoes a slight increase with increase of temperature; a
phenomenon due to the increased resistance to conduction of metals, when their tem-
perature rises.

3dly. That the quantity of electricity evolved at any given temperature is independ-
ent of the amount of heated surface ; a mere point being just as efficacious as an indefi-
nitely extended surface.

4th ly. That the quantities of electricity evolved in a pile of pairs are directly propor-
tional to the number of tlie elements.

336. First, then, as to the comparative march of electric development, with the rise
of temperature, in the case of pairs of different metals.

337. The experimental arrangement which I have employed is represented in jig. 31.
A A is a glass vessel about three inches in diameter, with a wide neck, through which
can be inserted a mercurial thermometer, h, and one extremity of a pair of electro-motoric
wires. The wires I have employed have generally been a foot long, and one sixteenth
of an inch in diameter. The extremity, *, of tlie wires thus introduced into the vessel
ought to be soldered with hard solder ; their free extremities dip into the glass cups, d d,
filled with mercury, and immersed in a trough, e, containing water and pounded ice. By
means of the copper wires,// one sixth of an inch thick, communication is established
with the mercury cups of the galvanometer. The coil of this galvanometer is of cop-
per wire one eighth of an inch thick, and making twelve turns only round the needles,
which are astatic. The deviations were determined by the torsion of a glass thread, in
the way described in Chapter VIII.

338. It is surprising to those who have never before seen the experiment, with what
promptitude and accmracy a copper and iron wire, soldered thus together, will indicate
temperatures.

339r In the arrangement now described, when an experiment has to be made, the
vessel A A is to be filled two thirds fiiU of water, the bulb of the thermometer being
so adjusted as to be .in the middle of the vessel, and the soldered extremity, *, of the two
wires being placed in contact* with it, and a small cover with suitable apertures ad-
justed on the top of the vessel, so that the steam, as it is generated, may rush up along-
side of the tube of the thermometer, and bring the mercurial column in it to a uniform
temperature. The communicating wires, //j are then placed in the cups, and the trough,
e, filled with water and pounded ice, and carefully surrounded with a flannel cloth. The

* If the extremity of the tbenno-electric pair be allowed to rest on the bottom of the glass vessel, do accarate results can
be obtained ; the pair does not then indicate the temperatore of the water.

92

TEMPERATURES CALCULATED FROM QUANTITIES OF ELECTRICITY.

water in the vessel A A is then gradually raised to the boiling point by means of a
spirit-lamp, and kept at that temperature until the galvanometer needles and the ther-
mometer are quite steady. The same plan must be followed when any other tempera-
ture than 212 is under trial, for the thermo-electric wires changing their temperature
more rapidly than the mercury in the thermometer, it is absolutely necessary to continue
the experiment for some minutes to bring both to the same state of equilibrium.

340. When a temperature higher than 212" Fah., but under a red heat, is required,
I substitute, in place of the vessel A A, a tubulated retort, the tubulure of which is
large enough to allow the passage of the bulb of the thermometer and the wires. A
quantity of mercury sufficient to fill the retort half full is then introduced, and the tubu-
lure being closed by appropriate pieces of soapstone, the neck of the retort is inclined
upward, so that the vapour as it rises may condense and drop back again without in-
commoding the operator. As in the former case, it is here also necessary to continue
each experiment for a few minutes, to bring the thermometer and the thermal pair to
the same condition. There is not much difficulty in obtaining any required tempera-
ture, by raising or lowering the wick of the lamp.

341. The metals I have tried were in the form of wires. They were in the state
found in commerce, and therefore not pure ; they were obtained in the shops of Phil-
adelphia

TABLE I.

Names of the pairs of Metals.

Temperatures (Fahr.). |

32 F. 1 182 F.

212 F.

662 F. 1

Copper and iron . .
Silver and palladium .
Iron and palladium .
Platina and copper .
Iron and silver . .
Iron and platina . .

0
0
0
0
0
0

93
65
112
11
89
28

17U
147
223

2G
137

.56

233-1

613

631

122

244

248^

il

In this table I have estimated the temperature of boiling mercury at 662° Fahr.
The quantities of electricity evolved, as estimated by the torsion of a glass thread, are
ranged in columns under their corresponding temperatures. Each series of numbers is
the mean of four trials, the differences of which were often imperceptible, and hardly
ever amounted to more than one degree.

342. Now if this table be constructed, the temperatures being ranged along the axis
of abscissas, and the quantities of electricity being represented by corresponding ordi-
nates, we shall have results similar to those given in _^g. 32, in which it is to be ob-
served that the curves given by the systems of silver and iron, copper and iron, and jjal-
ladium and iron, are concave to the axis of abscissas ; but those given by platina and
copper, silver and palladium, and platina and iron, are convex.

343. Let us now apply the numbers obtained by these several pairs for the calcula-
tion of temperatures, which will set their action in a more striking point of view. The
following table contains such a calculation, on the supposition that for the 90 degrees
from 32° Fahr. to 122° Fahr., the increments of electricity are proportional to the tem-
peratures.

TEMPERATURES CALCULATED FROM QUANTITIES OF ELECTRICITY.

93

TABLE n.

Temprntores hj Hm Mercanil llicnDacieter. )

3iF.

lar.

Water boils.

^iereanr bou-

' Oipper and iron . .
Silver and palladium .
Iron and palladium
Platina and copper
Iron and silver . . .

, Iron and platina . .

33
38
32
32
32
32

132
123

in

123
122
122

303
235

sn

344

170
212

267
880
539
1030
279
829

344. We are therefore led to the general conclusion that, in these six different sys-
tejns of jnetals, the detelopnients of electricity do not increase proportionally icith the
temperatures, but in some tvith greater rapidity, and in others with less.

345. The results here given I have corroborated in a variety of ways, and with a
variety of wires. A pair, consisting of copper and platina, gave for the temperature of tin,
when in the act of congealing, 452° Fahr. instead of 442° Fahr., the point usually taken.
For the melting point of lead, it gave 942^° Fahr., instead of 612° Fahr. The melt-
ing points of tin, lead, zinc, and occasionally of antimony and bismuth, were in this
manner emploved, for they allow time for the working of the torsion balance, and, with
the exception of bismuth, their temperature appears to be steady all the while they are
in a granular condition, before they finally solidify. The action of these metals on the
thermo-electric pair is easily prevented by dipping it into a cream of pipe-clay.

346. A pair of copper and platina gave for a dull red heat 1416° Fahr., and for a
bright red 2103° Fahr.

347. A pair of palladium and platina gave for a dull red 1850° Fahr., and for a bright
red 2923° Fahr.

348. Some of the combinations into which iron enters as an element give rise to
remarkable results ; thus, if we project the curve given by a system of copper and iron,
we shall find it resembling^g-. 33, where the maximum ordinate h occurs at a tempera-
ture of about 650° Fahr. ; the point c appears to be given between 700 and 800 degrees ;
d by a dull red heat ; e is very nearly the point at which an alloy of equal parts of brass
and silver melts, for if the pair be soldered with this substance, it fuses when the needles
have returned almost exactly to the zero point. With harder solders, or with wires
simply twisted, the curve may be traced on the opposite side of the axis towards ^^ its
ordinate increasing with regularity. At 60° Fahr., taking the length of the ordinate
corresponding to a temperature of 212° Fahr. as unity, the length of the maximum or-
dinate at h is 1-85, very nearly.

349. A system of silver and iron gives also a similar curve, the point h occurring at
a temperature rather higher than the analogous one for the preceding system, but still
below the boiling point of mercury.

350. Now all these things serve to show that we cannot determine with accuracy
unknown temperatures by the aid of thermo-electric currents, on the supposition that
the increments of the quantities of electricity are proportional to the increments of
temperature throughout the range of the mercurial thermometer.

351. Let us now proceed to the second proposition, " That the tension undergoes a
slight increase with increase of temperature, a phenomenon due to the increased resist-
ance to conduction of metals when their temperature rises."

94

INCREASE OF TENSION WITH INCREASE OF TEMPERATURE.

352. It will be seen, on consulting the following table, that pairs of different metals,
at the same temperature, have tensions which are apparently very different.

353. The currents, the tensions of which are here indicated, were generated by keep-
ing one end of the thermal pair in boiUng water, the other ends being maintained at a
temperature of 32° Fah.

TABLE in.

A pair of

Tension.

A pair of | Tension. |

Antimony and bismuth .

Copper and iron

Silver and lead

Lead and palladium . . .
Silver and platina ....

•137
•183
•307
•313
•380

Platina and iron

Copper and platina . . .
Platina and palladium .

Tin and iron

Platina and tin

•470
•473
•500
•518
•567

We perceive, therefore, that there apparently exist specific differences in the qualities
of electric currents derived from different sources. If, for example, we take a pair of
platina and palladium, and expose it to a temperature which shall generate a current
capable of deflecting the torsion balance through 1000 degrees, and then obstruct it by
a wire of such dimensions as to stop one half, or only allow 500 degrees to pass, and
repeat the experiment with a current generated by bismuth and antimony, the tempera-
ture being still so adjusted as to give a deflection of 1000 degrees, on making this pass
through the same intercepting wire, perhaps not much more than one eighth of it will
go through the galvanometer.

354. It might be supposed that these characteristic differences of thermal currents,
derived from different sources, were due to some modification of the electricity itself,
similar to those of radiant heat derived from different sources, or at different tempera-
tures, which M. Melloni has attempted to show are analogous to the colours of light,
being, like them, of different degrees of refrangibility, and permeating absorbent media
with different degrees of facility. For in the same way that we regard glass as trans-
parent to light, and rock salt as transparent to heat, so, too, we might regard a copper
wire or any conducting medium as transparent to electricity.

355. But this peculiarity of thermo-electric currents depends on the conducting
resistance of the system that generates them. It is possible to give a current a higher
or a lower tension, by simply making use of thin or thick wires to generate or to carry
it. In the foregoing table, the current from platina and palladium had a high tension,
because slender wires of those metals happened to be used to generate it ; and the cur-
rent from antimony and bismuth had a low tension, because thick bars of those sub-
stances were employed. In the former case, the conducting resistance was greater than
in the latter, and hence the tension of the current was higher.

356. That this is strictly true will appear on examining the current evolved by any
number of systems under the same condition of resistance to condition. I took a pair
of copper and iron, and soldered it to a simple pair of platina and copper, as is shown
^^ fiS- 34, so as to form one continuous metallic line. The point of junction formed
by the wires i (iron) and p (platina) was kept carefully at 63° Fah., by immersion in
a water-bath ; the point of junction, p (platina) and c (copper), was treated in like
manner, but that of e and i was raised to 212° Fah. Under these circumstances, it was
found that 181 degrees of electricity were evolved, of which fifty went through a given

DEPENDS ON INCREASED RESISTANCE TO CONDUCTION. 95

secondary wire. Then, raising the junction^ and c to 212* Fah., and bringing e and i
to 63° Fah., there passed at the galvanometer 71 degrees, of which 19 could traverse the
same secondary wire, but

As 181 : 50 :: 71 : 19-6;
and hence I infer that, where the conducting resistance is the same, the tension of cur-
rents from difl'erent sources does not differ.

357. These results inform us how much the tension of a current depends on the re-
sistance to conduction of the system which it traverses, as well as on the dimensions
of the system itself; an observation the value of which we shall presently see.

358. In a great number of trials which I made, I failed in getting any ♦mstworthy
results as respects tension of currents at high temperatures, on account of the difficulty
of maintaining the thermo-electric pair at the same degree without variation. By em-
ploying, however, a small blacklead furnace, to which was adapted a covered sand-
bath, into which the wires could be plunged, I succeeded at last ; for with this arrange-
ment a regulated temperature could be kept up for a length of time.

359. The experiment was made with care in the case of two systems of metals:
1st, copper and platina ; 2d, copper and iron.

1st. At the boiling point of water, a pair of copper and platina, the unexcited ex-
tremity of which was carefully maintained at 67° Fah., evolved as a mean of four trials,
three of which were absolutely identical, 123 degrees of electricity, of which 23 could
pass a secondary wire.

Then, by the aid of the furnace and sand-bath, the temperature was raised until the pair
evolved 783 degrees as a mean of four trials ; of tliese 163 could pass the secondary wire.
Now, As 783 : 163 : : 123 : 25} instead of 23,

showing, therefore, a slight rise of tension.

360. 2d. The pair oi copper and iron gave, at the boiling point of water, 300 degrees,
of which 57 passed the secondary wire. The temperature was now raised, with the
following results :

490 degrees passmg the primary, 95 the secondary wire.
553 " " " 113

545 " " « 112 " "

493 " « "110 «

It will be understood, that although the quantities of electricity indicated in the first
column do not regularly increase, the temperatures were, notwithstanding, going regu-
larly upward ; to this peculiarity of the systems into which iron enters I have already
alluded (348). Let us now compare these measures with those obtained for the boiling
point of water :

As 490 : 95 : : 300
553: 113:: 300
545 : 112 : : 300
493 : 110 : : 300

We find, therefore, that in the case of both these systems of metals, the tension slowly
rises with increase of temperature, being much better marked in the latter than in the
former instance.

58 instead of 57.

61

i(

61

((

67

u

96 QUANTITY OF ELECTRICITY INDEPENDENT OF HEATED SURFACE.

361. The increase of tension here detected depends unquestionably on increased re-
sistance to conduction, which the wires exhibit as their temperature rises, as the follow-
ing experiments show.

362. A pair of copper and iron evolved a current at the boiling point of water, which,
passing through a wire of copper eight feet long, was determined at the galvanometer to
be 176 degrees. Having twisted a part of this wire into a spiral, so as to go over the
flame of a spirit-lamp, 8 inches of it were thereby brought to a red heat ; the deviation
of the needle fell now to 165, being a deficit of 11 degrees. In this experiment, care was
taken that no heat should be transmitted along the wire to the connecting cups.

363. The same was repeated with a piece of iron wire, of the same length and un-
der the same circumstances. The current at first being 90 degrees, as soon as the spiral
was made red hot, it fell to 61 degrees, being a deficit, therefore, of nearly one third the
whole amount.

364. To the increased resistance to conduction, occasioned by an increased tempera-
ture, we are to impute the slight rise of tension observed in thermo-electric currents.
The quantities are of the same order.

365. We have next to show " that the quantity of electricity evolved at any given
temperature is independent of the amount of heated surface ; a mere point being just
as efficacious as an indefinitely extended surface."

366. The quantities of electricity evolved by hydro-electric pairs has been shown to
increase with their surfaces, but it is not so in thermo-electric arrangements. A pair
of disks of copper and iron two inches in diameter were soldered together ; they had
continuous straps projecting from them, which served to connect them with the galva-
nometer cups. At the boiling point of water they gave 62 degrees ; on being cut down
to half an inch in diameter, they still gave 62. On the disk being entirely removed,
and the copper made to touch the iron by a mere point, its extremity being roughly
sharpened, the deflection was still 62.

367. By means of a common deflecting multiplier, I obtained the following results :
1st. A copper wire being placed in a bath of mercury, the temperature of which was
240° Fah., I dipped into it a second copper wire, the temperature of which was about
60" Fah. ; the galvanometer needles moved through 15 degrees.

2d. The cold wire being sharpened to a point, and plunged deliberately into the
mercury to the bottom of the bath, the deflection was 19 degrees.

3d. But when I touched the surface of the mercury with the very point of the cold
wire, there was a deflection of 60 degrees.

368. Having laid a plate of tinned iron upon the surface of some hot mercury, it
was touched with the point of the cold wire. There was a strong deflection of the
needles in the opposite direction to what would have been the case had the mercury
been touched, and not the iron. The under surface of the iron was therefore acting as
a hot face, and the parts round the point as a cold face, being temporarily chilled by the
touch of the wire.

369. These results explain the anomalies observed by some of those who investi-
gated the course of thermo-electric currents by means of small metallic fragments.

QUANTITY OF ELECTRICITY PROPORTIONAL TO NTJMBER OF PAIRS.

97

370. It would therefore seem that, when wires of the same metal are used as electro-
motors, the quantity of electricity evolved depends on the quantity of caloric that can he
communicated in a given time. Time, therefore, under these circumstances, must enter
as an element of thermo-electric action. In the case of a single metal, the maximum
effect would be produced when the hot element is a mass, and the cold one a point.

371. And, lastly, " That the quantities of electricity evolved in a pile of pairs are
directly proportional to the number of the elements."

372. In the first trials which I made to determine the effect of increasing the nmn-
ber of pairs in a pile, the results obtained were contradictory ; by operating, however,
in the following way, the proposition was at last satisfactorily determined :

1st. The resistance to conduction was made nearly constant by uniting all the pairs
intended to be worked with at once. The current, therefore, whether generated by
one, two, three, four, or more pairs, had always to run through the same length of wire,
and experienced in all cases a uniform resistance.

2dly. By making each individual element of considerable length, the liability of trans-
mission from the hot to the cold extremity was diminished.

373. Having, therefore, taken six pairs of copper and iron wires, one sixteenth of an
inch thick, and each element 38 inches long, I formed them, by soldering their alter-
nate ends, into a continuous battery. Then I successively immersed in boiling water
one, two, three, &c., of the extremities, their length allowing freedom of motion, and
the other extremities not differing perceptibly from the temperature of the room.

374. The following table exhibits one of this series of experiments :

TABLE rv.

No. of Pun.

Cilcalmted DeTixtians.

Observed Deviations.

1.

55

55

s.

110

III

3.

168

165

4.

S30

220

5.

875

273

6.

330

332

Hence there cannot be any doubt that the quantities of electricity evolved by com-
pound batteries, at the same temperature, are directly proportional to the number of the
pairs.

375. With some general remarks, arising from the foregoing subjects, I shall conclude
this chapter.

376. It is of importance to remember that thermo-electric currents traverse metallic
masses only on account of differences of temperature existing at different points.

377. When a current of electricity, flowing from the poles of a battery, is made to
traverse a metallic sheet, the whole of it does not pass in a straight line from one pole
to the other, but diffuses itself through the metal, diverging from one point and conver-
ging to the other. The greater part of the current is found, however, to take the shortest
route.

378. Combining, therefore, the foregoing observations, we perceive that there are'
certain forms of construction which will give to thermo-electric arrangements peculiar'
advantages. For example, the surfaces united by soldering must not be too massive. Let

N

98 BEST FORMS OF CONSTRUCTING THERMOMETRIC PAIRS.

a, jig. 35, oe a bar of antimony, and h a bar of bismuth ; let them be soldered together
along the line c d, and at the point d let the temperature be raised ; a current is immc-
diatelj excited ; but this does not pass round the bars a, h, inasuiuch as it finds a shorter
and readier channel through the metals, between c and d, circulating, therefore, as in-
dicated by the arrows. Nor will the whole current pass round the bars until the tem-
perature of the soldered surface has become uniform.

379. An obvious improvement in such a combination is shown ivl Jig. 36, which
consists of the former arrangement cut out along the dotted lines : here the whole cur-
rent, so soon as it exists, is forced to pass along the bars ; and because the mass of
metal has been diminished at the line of junction, such a pair will change its tempera-
ture very quickly.

380. One of the very best forms for a thermo-electric couple is given in Jig. 37, where

0 is a semi-cylindrical bar of antimony, b one of bismuth, united together by the opposite
corners of a lozenge-shaped piece of copper, c. From its exposing so much surface,
the copper becomes hot and cold with the greatest promptitude, and, from its good con-
ducting power, it may be made very thin without injury to the current. With a pair
of bars three fourths of an inch thick, and a circular copper plate, c, having both sur-
faces blackened, I have repeated the greater part of those experiments which M. Mel-
LONi made with his multiplier.

381. The currents which circulate in a steel magnet are to all appearance perpetual.

1 thought for some time it might be possible to procure similar perpetual currents by
compound thermo-electric arrangements. Fig. 38 will serve to show the character of
these combinations, and also the cause of their failure. Let a, b, c, be wires of three
different metals, soldered together so as to form a triangle. Now, if these metals were
selected, so that a and b could form a more powerful thermo-electric pair than a and c
or b and c, it might be expected that at all temperatures an incessant current would run
round the system. Such, however, will not be found to be the case. In effect, any
one of these three serves simply as a connecting solder to the other two, and hence no
current is excited ; for the ends that have the third metal between them, although that
metal intervenes, are under exactly the same condition as the other ends which are in
contact.

382. Thermo-electric currents, evolved by pairs of different metals, do not appear to
♦ differ specifically. As different gases during combustion burn with differently-coloured

flames, and as different sources of caloric evolve rays of heat which are absorbed dif-
ferently by different media, it might be expected that a pair of wires of copper and pla-
tina would give out a current of electricity unlike that of iron and palladium. I have
made many trials on this point, adjusting a wire of copper and one of lead to each other,
so as to stop equal quantities of electricity flowing from a pair of copper and platina,
the galvanometer needles being brought to the same point, whether the long wire of
copper or the short wire of lead was employed. But, in the case of every combination
which I tried, these two wires acted alike, nor could I ever evolve a current which
would pass with more or less resistance along the lead than along the copper.

ACTION OF ABSORBENT MEDIA AND IDEAL COLOURATION. 99

I

CHAPTER X.

EXPERIMENTS ON THE CHEMICAL ACTION OP SOLAR LIGHT.

(From the Joutnal of the Franklin Imtituiefor June, July, August, and September, 1837.)

Contents: Action of Absorbent Media. — Ideal Colouration of the Chemical Bays. —
Specific Absorption. — Colorific Absorption. — Calorific Absorption. — Specific Absorp-
tion of the Chemical Rays. — Effect of Yelloio Solutions.

Deco7nposition of Carbonic Acid by Leaves. — Penetration of Dimensions in Gases. —
Decomposition of Carbonic Acid under various coloured Media. — Gas from Leaves
contains Nitrogen. — Chemical Rays of different Colours. — Identity of Volume in the
absorbed and evolved Gas. — Cause of the Decomposition.

Hitter's Experiments of the Non-oxygenation of Phosphorus.

Decomposition of the Salts of Silver. — Prismatic Spectrum on Bromide of Silver. — In-
terference of Chemical Rays. — Salts decomposed by Light. — Moonlight and Artificial
Flames are Inactive.

Of Perihelion Motions.— Deio of Water and Mercury. — Iodine. — Chloride of Gold. —
Non-deposition on a Glass Plate. — Current Action. — Action of Flame. — Action of
Metal Screens. — Protecting Action of a Metal Ring. — Is there Electricity in the
Solar Ray?

Cause of the Green Colour of Leaves. — Plants groto in Lights of various Colours. —
Seeds also germinate in Red, Yellow, and Blue Light. — Chemical Rays of different
Colours.

383. The effect of absorbent media upon the colorific rays of light has been, as was
predicted by an eminent writer on optics, of singular service in developing new views
of this subtle agent, and giving us a more precise knowledge of the complex constitu-
tion of the solar beam. Hitherto, the action of these media upon the calorific and
chemical rays has not been thoroughly investigated, nor are there, so far as I know,
any experiments on record exhibiting this matter in its full importance.

384. We have been accustomed to regard the chemical properties of the solar spec-
trum as due to the violet ray. A similar opinion was formerly maintained respecting
the calorific constitution of the red ray. The position to which we are brought by
advanced investigation has long ago estabHshed the separate existence of heat-making
rays, and the experiments here communicated give much weight to the doctrine that
the chemical rays have also a separate existence. It is true it cannot yet be proved,
though analogy and probability are favourable to the idea that there are subdivisions
both of the chemical and calorific rays, similar to those of which our senses give evi-
dence in the colorific ray, each of which is endued with distinct powers of its own.

385. How complex is, then, the constitution of the solar beam ! a ray of heat, com-
posed, perhaps, of three or more rays of different refrangibility ; a ray of light, composed

100 SPECIFIC ABSORPTION— INSTRUMENTAL ARRANGEMENTS.

of three simpler rays ; a ray endued with chemical energy, and of a similar composi-
tion to the former, as analogy would lead us to suspect. Again, each of these element-
ary rays is composed of particles, one half of which have their planes of polarization
at right angles to the other. All these elements taken together constitute a beam
of the sun's light. Emanations from the sun, after they have undergone the absorptive
action of the atmosphere of that great luminary, and of that of the earth, still reach us in
abundance, accompanying his light, and traversing the great vacuum, perhaps as far as
his attraction is felt.

386. If we take a coloured medium of any kind, and transmit through it a beam of
the sun's light, we find, on examination, that certain of the rays exciting vision are
absorbed, that the light which passes through is not homogeneous, for it is capable
of decomposition by the prism ; it is a compound coloured ray, consisting of all the
rays, complementary to those which the medium has absorbed. Nor is this absorbing
effect confined to the rays producing vision; the rays of heat suffer in like manner; some-
times those which are more refrangible are wanting, sometimes those which are of less,
or of niediura refrangibility, are absent. Often, at the same time, do the chemical rays
sustain a similar attack. There are solutions and media transparent to light, and
nearly opaque to heat ; there are others transparent to light and to heat, and opaque to
the chemical ray. It is from these facts that we are able to establish the separate
existence of three genera of rays in the sunbeam, each of which is essentially distinct
in its properties, and different in its mode of action from the others. Our eye can de-
tect, in the rays exciting vision, difference of constitution, because we are able to per-
ceive a difference of colour. Had we specific organs for indicating difference in the
heat-making, or chemical rays, perhaps we might find in them a similar constitution.

387. It is between three and four years since that the investigation which forms the
subject of this memoir was first commenced, under the form of an examination of the
properties of the chemical ray. In the Journal of the Franklin Institute some of the
earlier results are recorded, and among them the fact, that the crystallization of cam-
phor, which has long been known to take place on the enlightened sides of vessels
exposed to the sun, occurs with very great rapidity, if the glass in which it is tried be
exhausted of air. In tracing out this fact, to ascertain its cause, a field of no common
interest has been entered. I do not here present a record of the facts as they were
successively developed by an analysis of the phenomena, but place them in that order
which appears to me the best to obtain a true estimate of their bearing.

388. Into a darkened chamber, the shutter of which is seen in section at a a, jig. 39,
a beam of the sun's light may be made to pass horizontally, by means of a mirror
of silvered glass, c. The mirror which I use is one belonging to a solar microscope,
and by turning the milled screws, e e, it can be brought into any position required to
throw a beam horizontally into the room, no matter what may be the place of the sun.
A brass tube, f, belonging to the same instrument, and two inches in diameter, can
be screwed into the position figured, if desirable ; there is also a lens, g, which may oc-
casionally be fixed at g; its focus is nine inches, its diameter about two incl^s, and the
diameter of the sun's image tV of an inch.

COLORIFIC ABSORPTION. 201

389. A piece of sheet lead, about a quarter of an inch thick, is to be cut into the
form of a horse-shoe, of such magnitude that a circle one inch in diameter might be
inscribed in it Upon this lead two pieces of very pure and transparent crown glass
are cemented, so as to form a trough, for containing a variety of liquids. It is well to
accommodate this trough with a strong foot, or basis, a a, and several such troughs may
be provided. Fig. 40, ccc, the leaden horse-shoe ; hh, the glass plates.

390. A thin metallic plate, three or four inches square, having a longitudinal slit
about one inch long and xV inch wide in it, is also to be provided. It is convenient
that this, too, should be furnished with a pediment Fig. 41, a a, the slit.

391. The leus {g. Jig. 39) having been removed, by turning the screws a beam of
light is to be thrown horizontally into the room; the screen (Jig. 41) is then to be placed
before the brass tube, /i so that the slit in it may allow a narrow streak of light to pass.
The trough {Jig. 40) is then placed behind, in such a position that half the light which
comes through the slit in the screen may pass through the liquid contained in the
trough, and the other half pass by its side unintercepted. This arrangement is shown
in Jig. 42. Behind the trough is placed a flint glass prism, d,Jig. 43, and, farther still,
a white pasteboard screen, e, of suitable dimensions, a being the metallic screen, h the
trough.

392. The action of this arrangement is as follows : the beam of light cast by the
mirror into the room is entirely intercepted, except the small ponion which passed
through the slit in the metallic screen. A part of this passes through the trough, and
a part on one side of it, the middle part being obstructed by the leaden horseshoe.
Two beams of light, therefore, fall on the prism, one of which has passed through the
trough, and one which has not, and they are separated from each other by a dark in-
terval. The prism disperses both, and there fall on the pasteboard screen two spectra,
side by side, close enough for a very accurate examination. One of them has been
acted on by the fluid in the trough, the other is undisturbed. In my arrangement, the
spectrum a happens to be the natural one, and h the disturbed one {Jig. 44).

393. Let us now take an example, as an illustration of the use of this apparatus.
Fill the trough with distilled water, and let the mirror throw a horizontal beam.
Two spectra are seen on the screen, e,Jig. 43, close to each other, side by side, with a
dark interval between them. They contain, as may be perceived, all the seven col-
ours of Newton, nor does the one differ in any wise from the other, as in Jig. 45.

394. Having poured the water out of the trough, fill it with a strong, but clear solu-
tion of the chromate of potassa ; on looking at the spectra on the screen, a is still found
of its natural appearance, but by the side of it there is a distorted spectrum, formed by
the light that has passed through the trough ; the blue, the indigo, and the violet rays
are wanting, as is seen in Jig. 46. These colours have then been absorbed by the so-
lution of chromate of potassa. If this solution be poured out, and one of sulphate of
copper and ammonia poured into the trough, another kind of spectrum is produced,
where the red and much of the yellow light is wanting, as in_^^. 47. If a strong solu-
tion of Brazil wood is used, the disturbed spectrum will be found to have lost its violet,
indigo, blue, green, yellow, and a great part of its orange rays, as represented in^^. 48.

102

COLORIFIC ABSORPTION.

395. By having the two spectra side by side, and close to one another, they are
placed under circumstances most convenient for making a perfect comparative estimate
of the light vi'hich is lost. In this manner the following table has been constructed.
The specific gravity of the solutions is not given, as it is not supposed that any direct
connexion exists between the density of a solution and its absorptive power. Much
more depends on the shade of colour.

TABLE OF COLORIFIC RAYS ABSORBED BY SOLUTIONS.

Name.

Rays absorbed.

Bichromate of potassa

blue, violet.

Priissiate of potassa

extreme red, extreme violet, yellow.

Sulphate of copper

extreme red.

Chloride of gold

violet.

Chloride of platinum

extreme violet.

Sulp. copper and ammonia . . .

red, yellow.

SoUition of tannin

violet, indigo blue, orange, and a part of green.

Solution of litmus

orange, yellow, green, extreme violet.

Chromate of potassa

extreme red, blue, violet.

Linseed oil .

violet, indigo blue,
violet, blue.

Hydro-sulphate of lime

Decoc. logwood in alum-water . . .

orange, yellow, blue, and green.

Decoc. of Brazil wood

violet, indigo blue, green, yellow, orange.

Cochineal in cream of tartar solution .

yellow and part blue.

396. Some remarkable phenomena may be produced by taking double solutions ; a
beam which has passed through a stratum of solution of sulphate of copper and ammo-
nia, and then through a decoction of Brazil wood, becomes almost totally extinct.
On looking through such solutions separately at the noontide sun, he appears with
overpowering effulgence, but on using them together, only a very faint trace of a dirty
olive-green light indicates his position. The sulphate of copper and ammonia absorbs
the red rays, and the Brazil-wood decoction nearly all the remainder.

397. Already have some of these phenomena of absorption, in the hands of Sir D.
Brewster, disclosed important facts respecting the colorific rays. The colour of the
sky, and of the clouds, and of the sea, has also been long attributed to an action of this
kind, exercised by thick masses of air, or vapour, or water.

398. But this action is not alone confined to the rays producing vision, it extends to
the other elementary constituents of the spectrum. While the trough {h,Jig. 43) is filled
with a solution of sulphate of copper and ammonia, if the prism and the metallic screen
be removed, and a very delicate thermometer be plunged in the ray, a new phenome-
non is discovered ; the ray is found to be, to a great extent, deprived of the power of
exciting heat, and the thermometer shows little disposition to rise. How is this ! is it
because the red ray is gone that the sunbeam has lost its power of exciting a sensa-
tion of warmth \ It was at one time supposed that as the violet ray had the power of
determining chemical change, so the red ray possessed the power of exciting calorific
impressions.

399. Fill the trough next with a strong decoction of Brazil wood, analyze the light
which passes through it by the prism (391), and it will be found that all the rays have
been absorbed except the red. Now, in such a beam, if the red ray possess inherent
caloric, the thermometer should rise as much, or nearly as much, as if it were in the
direct solar ray ; if the colour passes unabsorbed, so too should the caloric ; but, place
the thermometer in the beam, and it does not rise. Or throw a concentrated column

»

CALORIFIC ABSORPTION. ^q3

of such light upon it by a convex lens, and it is still unmoved. We are therefore for-
ced to conclude that the rays exciting heat are independent of those exciting vision ;
that neither the red, nor the yellow, nor the blue possesses inherent caloric ; and, more-
over, that substances may be transparent to red, to yellow, or to blue light, or to all, and
yet more or less opaque to the rays of heat.

400. It is not alone among watery solutions or alcohoUc tinctures that we find
abundant instances of this kind of action; the mineral kingdom furnishes many. A
very thin lamina of pitch is transparent to red light, but almost opaque to the rays of
heat. I have examined a variety of bodies, gaseous, liquid, and sohd, and shall here
point out the method which has been followed in obtaining the results contained in the
following table.

401. The mirror being placed upon the shutter, as in (388), a plano-convex lens is
to be screwed into the tube, so as to bring the rays to a focus on one of the balls of a
very delicate differential thermometer ; the motion of the fluid is rapid, and the instru-
ment soon attains a position of equilibrium : this gives the heat of the sunbeam as con-
centrated by the lens. To find the effect of any liquid medium in absorbing these rays,
the trough filled with the substance under trial is placed at the extremity of the brass
tube, in a position as at c {Jig. 50). The cone of rays converges from the lens, a, on
the ball h ; but because the trough has plain and parallel surfaces, the rays still pass on,
and form an image on the focal ball of the thermometer. The total effect, as given by
the expansion of the air in the instrument, and which has formed the basis of the fol-
lowing table, is not, however, an exact estimate of the action of the hquid solution. In
the instrument which I am in the habit of using, the convex lens is of flint glass, and
the plates of the trough of Boston crown glass ; there are, therefore, at least two disturb-
ances, the absorbing action of the former, and still more powerful effect of the latter.
It has been considered, from the experiments of Melloni, that the power of absorption
was inversely as the power of refraction, but whether an extended train of investiga-
tions will corroborate this supposition, remains to be seen. In the following experi-
ments, the instrumental arrangement being always identical, a comparison may be insti-
tuted of the action of any two of the solutions ; but the absolute action of each cannot
be determined, except after allowing for the additional effect of the flint glass lens and
the crown glass plates. In practice, it will be found very useful to blacken the focal
ball of the thermometer, as seen at h {Jig. 50). It serves to give a larger scale of ther-
mometric expansion. It is also requisite to cover the thermometer with a very thin case
of pure and transparent glass, which prevents the disturbance of currents, and also of
the heat radiated from other bodies in the vicinity ; this introduces, however, the ab-
sorptive action of a third plate of glass ; b d\s the thermometer, and e e the glass cover
(/^•50).

402. By these arrangements, it was found that a thin stratum of pitch enclosed be-
tween two plates of crown glass, and which transmitted a homogeneous red light, ab-
sorbing all the other colours of the spectrum, allowed only nineteen rays of heat to pass
through of every hundred that fell upon it.

403. A solution of the sulphate of copper and ammonia, which absorbs the red and

104

ABSORPTION OF HEAT AND CHEMICAL RAYS.

the yellow light, being operated upon in like manner, was found to transant twenty
rays out of every hundred that fell upon it.

404. There is, however, considerable difficulty in obtaining these numerical results
with accuracy, arising partly from the difficulty of obtaining specimens of exactly the
same composition, but more especially owing to changes taking place in their colour.
In process of time, most vegetable solutions undergo spontaneous changes, and no lon-
ger give the same results. But, where the same sample is operated on, under the same
circumstances, repeated experiment assures me that this arrangement gives comparable
indications.

405. Vapours and gases may also be put under trial. The vapour of iodine, the
spectrum of which is remarkable as containing only the extreme rays, and wanting those
of medium refrangibility {Jig. 49), absorbs two thirds of the heat that impinges on it.
The vapour of nitrous acid, which stops the violet, blue, indigo, and yellow hght {_fig.
61), has a similar effect on the heat. To experiment upon these bodies, a cubical bot-
tle (Jig. 52) is very convenient to generate the vapour in, and also to transmit the
light through ; it will then replace the trough of (389), Nitrous acid vapour is best
made for these purposes from nitrate of lead.

406. Having prepared a variety of solutions for the purpose of experiment, and using
for each the same trough, thoroughly cleansed after each trial, the following table will
give an estimate of the results obtained; it is arranged according to the power of each
solution, the first on the list being the most energetic :

TABLE OF THE THERMO-ABSORPTIVE POWER OF SOLUTIONS.

Decoction of logwood in alum water,

Bichromate of potassa,

Solution of sulphate of copper and ammonia,

Hydro-sulphate of lime.

I/itmus water.

Muriate of iron.

Decoction of Brazil wood,

Oil of turpentine,

Decoction of cochineal,

Prussiate of potassa,

Solution of tannin,

Sulphate of copper,

Solution of chloride of chromium,

Chloride of platinum,

Tincture of turmeric,

Chloride of gold,

Tincture of saffron,

Oil of bergamot,

Sulpho-cyanate of iron,

Linseed oil.

Hydro-sulphate of ammonia,

Nitrous ether,

Muriate of cobalt,

Water.

407. Still more powerful effects are produced by making binary or ternary arrange-
ments. If, for instance, a beam of the sun falls upon a very thin, transparent stratum of
pitch, and then passes through a solution of sulphate of copper and ammonia, or through
linseed oil, not more than one fortieth part of the caloric is transmitted.

408. A question here naturally arises : What becomes of the heat thus lost ? does
it enter into such a combination with these media as to be detected in them by the
thermometer as sensible heat ? This is a question of much difficulty ; there are so
many disturbing causes in operation, the general results of experiment have not yet
furnished actual proof that the heat missing is to be found in the fluid solutions. I
would not, however, be understood to deny that such is the case ; only that, at present,
our information does not warrant such a conclusion. It might be supposed that these
solutions do not act by a proper absorptive power, but merely offer that kind of obstacle
to the traasmission of heat that turbid media do to light Not only, however, does

EFFECTS OF YELLOW SOLUTIONS ON THE CHEMICAL RAYS. 105

direct experiment discountenance this, but the analogy of their action on the chemical
ray renders it extremely improbable, an action which I proceed to develop, ^^. 50,
being still consulted.

409. Having removed the differential thermometer and its case, and produced a cone
of light converging from the lens, and passed it through a solution of sulphate of copper
and ammonia contained in the trough, if now we hold in the focus a piece of bibu-
lous paper imbued with chloride of silver, although little or no heat is transmitted
through the solution, yet an extremely dark spot is produced, characteristic of the black-
ening of that substance by the solar rays. Though, therefore, the double salt transmits
the rav of heat with difficulty, the ray of chemical action passes with great facihty.
If a trough containiug a strong solution of bichromate of potassa be now substituted, a
far larger quantity of light will pass, and vastly more heat; but a paper imbued with
chloride of silver being laid in the focus, jw chemical change whatever goes on, the
chloride retaining its usual whiteness.

410. I placed a piece of paper imbued with chloride of silver in a cubical box. one
of the sides of which was formed of a pair of glass plates, with a solution of bichromate
of potassa between them ; it was exposed for many days to the sun's light, and only
assumed a faint bluish stain, while a similar piece exposed to the direct rays was fully
blackened in fifteen minutes. So powerful is the action of this salt, that when a stratum
of it not more than the hundredth part of an inch thick was included between two
plate glasses, it stopped the decomposition of chloride of silver. It was after a long
examination of a variety of substances that I first became acquainted with the great
absorptive power of the chromates of potassa. In my earUer experiments, I had made
use of the chloride of platinum and the chloride of gold, both of which have an anal-
ogous action. The solutions which I have recognised as possessing this power in the
most eminent degree are,

Bichromate of potassa. Muriate of iron.

Chroraate of potassa. Chloride of gold.

Yellow hydro-sulphuret of ammonia. Chloride of platinum.

Hydro-sulphate of lime. Coloured vegetable solutions.

It is remarkable that all the mineral solutions on this Ust are yellow ; the absorptive
power, however, is by no means connected with that colour, for the yellow tint is a
compound one ; all the rays of homogeneous light are absorbed by one or other of the
bodies on the foregoing list.

411. It is interesting to know ^vhether these absorptions be really the abstraction of
something from the solar ray, or merely some change impressed upon it If light
consists of tremblings, pulses, or undulations, or any other kind of motion of a homo-
geneous elastic medium, in virtue of which it is competent to excite sensations of heat
and effect chemical changes, we might explain the action of these media as the result
of some change occurring to that motion, either in direction or degree. We might
suppose, too, that when a ray had been deprived of its power by passage through one
medium, it might have it restored, in a greater or less degree, by being transmitted
through another. I have not found, in thus comparing together nearly three hundred

O

IQQ DECOMPOSITION OF CARBONIC ACID BY LEAVES.

media, any indications of such a result, and therefore suppose that something of a
material character has been abstracted from the ray ; that it is really a loss, and not a
change.

412. Being thus possessed of the means of depriving the beams of the sun of their
heat and their chemical force, I have proceeded to examine a variety of questions
of interest. A great many changes in the constitution of bodies, on their exposure to
light, are recorded in the books of chemistry and physics, but they are there iuiputed
to light in the aggregate, without any reference to its compound character: we shall
find there are changes due to the colorific ray, changes due to the calorific ray, and
changes due to the chemical ray.

413. Decomposition of Carbonic Acid by Leaves. — One of the most important
and extensive functions exercised by radiant matter from the sun is the decomposition
of carbonic acid by vegetable leaves, and the elimination of oxygen gas. Vegetable phy-
siology looks to chemistry for information, but hitherto the chemist has not possessed
the means of perfectly developing the matter. Its intrinsic importance entitling it to
investigation, I shall not offer any apology for passing from the direct object of this
paper to the mention of some facts necessary to the thorough understanding of the
matter.

414. It would appear that there is a particular kind of combination, to which attention
has hardly yet been drawn, distinct from what is understood by chemical combination
and mechanical mixture. A pint of alcohol and a pint of water being mixed together,
the result will measure somewhat less than a quart, and the same might be indicated of
a variety of other liquids. No instance, I believe, is yet on record of a like penetration
of dimensions being observed in the case of gases ; if it exist at all, it exists to a very
small amount, and the change of volume which these bodies readily experience, by al-
teration of temperature and pressure, renders so minute an effect very difficult of detec-
tion. It has been supposed, judging from analogy, that the constituent gases of the
atmosphere, the uniting volume of which is always constant, are held together in this
manner, or that the whole volume is condensed and retained by some force of com-
pression. There are some experiments which indirectly prove this : sound passes
along different media with different velocities ; if a cannon were therefore discharged
at a distance, it should impress the ear with two distinct sounds; the one coming along
the particles of nitrogen, and the other along the particles of oxygen. But it is well
known, from observations made directly on this point, that instead of there being any
reduplication of the sound, it comes clear, distinct, fmd alone ; we have, therefore, to
infer that these two gases are held together in a state of compression.

415. In making experimental investigations on this matter, two different courses may
be followed : first, we may measure the resulting volume after the mixture of known
volumes of the gases under trial ; or, secondly, we may ascertain whether any thermal
disturbance takes place during the act of their uniting; the latter is the mode I have
followed in my researches.

416. Take a cylindrical glass {A, Jig. 53) two inches in diameter and four in height;
close its upper extremity with a flat piece of wood by means of cement ; in the centre

PENETRATION OF DIMENSIONS OF GASES. 207

of it cement a stopcock, a, of large bore; and, at a suitable distance from that centre,
make two holes, the one to have a piece of bent tube, h, cemented into it to serve as a
gauge, the other to have a piece of copper wire, c, bent into the shape (c. Jig. 54),
passed through it air-tight, by means of a cork, x, imbued with tallow. The other ex-
tremity of the cylindrical glass is likewise to be closed by a flat piece of wood larger than
the former, for the purpose of bearing a little cup, d, containing coloured water, into
which the gauge tube may dip, and in its centre it is to be perforated to admit of an
arrangement, as in Jig. bb, where <f is a perforated cupping-glass, having a stopcock,
h, mounted on it, the farther extremity of which opens into a glass pipe, c, which termi-
nates in a hole, in the centre of a flat copper circle, a, three quarters of an inch in diame-
ter : this arrangement is to be cemented, air-tight, into the flat piece of wood that closes
the lower extremity of the cjlindrical glass, as is seen mjig. 53. Moreover, beneath
the cupping-glass there is a glass reservoir, g, of suitable dimensions, filled witb water.
The object of this arrangement is to fiU a soap bubble with any gas, to expose it to at-
mospheric air, to burst it at pleasure, and to mark any thermal expansion of the two
gases by the indications of the gauge ; the mode in which this is accomplished will be
described in the following illustration.

417. The whole apparatus having stood for some time in a quiet room, along with
the gases to be tried, until they have all acquired a uniform temperature, close the
lower cock, fill the cupping-glass with hydrogen gas, and raise the reser\oir, g, so that
the level of the water may be near the top of the cupping-glass. The upper cock, a,
being open, convey through its bore, by means of a glass tube of smaller diameter, a
little soap-water, which is to be deposited on the copper circle in its centre, over where
the glass pipe, e, opens; the tube is then withdrawn. Next open slowh' the lower cock,
and as the gas is expelled from the cupping-glass by the pressure of the water in the res-
ervoir, it expands a bubble in the large cylinder, the displaced atmospheric air passing out
through the upper cock. When this bubble has attained the dimensions desired, close
both cocks, and observe if the liquid in the gauge be stationary; if so, turn the wire c
on its axis, so as to bring its crooked extremity, which is within the cylinder, in con-
tact with the bubble; it bursts, there is a thermal disturbance, and an expansion of the
two gases, for the fluid in the gauge instantly falls, and as the gases cool, it slowly re-
turns to its former position. If a bubble of atmospheric air be employed instead of a
bubble of hydrogen, these effects will not ensue. We therefore conclude, that when
hydrogen gas is mixed with atmospheric air, the temperature suddenly rises, and there-
fore that it is probable that the volume of the mixture is less than the sum of the volume
of its integrant constituents.

418. If a soap bubble, filled with hydrogen, be burst in an atmosphere of nitrogen
gas, which may be effected by using a more complex arrangement than that indicated
in the preceding section, there is also a thermal expansion, indicating that the constit-
uents of ammoniacal gas, even without chemically uniting one with another, exercise
an attraction for, or a pressure on, each other, a kind of capillary action. These com-
pounds, for they form a distinct class of bodies, a class by no means of small extent, re-
quire a distinct name. I have su^ested that of capillary compounds, because they

108 DECOMPOSITION OF CARBONIC ACID IN LIGHT OF DIFFERENT COLOURS.

exist nnder, and can be separated by, the force of capillary attraction. An example
will here illustrate what is meant. Cxygen and hydrogen gases may be mingled with
each other in the proportion of one to two, the result existing in a compressed state,
and forming a capillary compound ; the contact of flame, or the passage of an electric
spark, changes it into aqueous gas, a chemical compound ; in the former state, de-
composition is re;idily effected by capillary attraction ; in the latter it cannot produce
such a result. The general law of these decompositions by tissues without pores of
sensible size is given in Chapter IV. ; it is a very simple one, showing that a capillary
equilibrium is gained only when the composition of gaseous media on each side of a
barrier is chemically the same. This was proved by exposing extremely thin soap bub-
bles, filled with different gases, to different gaseous atmospheres, and then measuring
and analyzing the media within the bubble and without. This law is applicable not
only where a barrier separates a gas from a gas, but also when one of the gases is held
in solution by water; and in the energy with which the media endeavour to attain an
equilibrium, is to be found not only one of the causes of the decomposition of carbonic
acid by the light of the sun, but also a very fruitful source of erroneous experimenting.
Having made reference to this matter, I proceed to detail the steps which have been
taken to illustrate this decomposition.

419. Take four globular vessels, such as a {fig. 56), three or four inches in diame-
ter, with necks a couple of inches long; fill them with spring water, and put a bunch
of pine leaves in it ; immerse the end of the neck beneath the surface of the mercury
contained in a cup, h. Let one of these vessels, designated A, be exposed to the sun's
direct ray ; a second, B, to the light which has passed through a solution of bichro-
mate of potassa; a third, C, to the light which has passed through a solution of sul-
phate of copper and ammonia ; and a fourth, D, in a dark place. It will be found that
in the course of a few hours, A has eliminated most gas, B somewhat less, and C and D
none at all ; this is a very instructive experiment ; we find from A and D that the sun's
rays have the power of eliminating gas from solutions ; from B we learn that the ab-
sence of the chemical rays does not affect the apparent result, but that if the calorific
rays are obstructed, it ceases to go on.

420. A variety of experiments having thus convinced me that the mere evolution of
gas is neither due to the rays of light, nor to the chemical rays, 1 have attempted to
produce a like effect with the calorific rays emitted from a common fire ; rays in which
the light was altogether disproportioned to the heat, and the chemical power totally
wanting. The arrangement is as follows: in the focus of a concave speculum of brass
eighteen inches in diameter, I placed one of the glass globes of the preceding section,
so that it might receive the rays emitted from a common wood fire, converged on it by
the mirror. The fire was burning without flame, being what is technically called a
dead fire, and the distance of the mirror eight feet. In a few moments gas was copi-
ously liberated, more copiously than if it had even been exposed to the solar ray. In
fig. bl, this arrangement is depicted : a is the concave mirror, h the glass matrass filled
with spring water, and containing a bunch of pine leaves, c a cup of mercury into which
its neck dips.

GAS FROM LEAVES CONTALNS NITROGEN. 109

421. I shall have occasion to show, hereafter, that when a beam of light falls upon
any surface in contact with a medium, it causes that surface to exert an apparent pres-
sure on the medium, capable, at times, of producing singular effects ; it is, therefore,
probable that to this action we are to attribute the evolution of gas by vegetable leaves,
spun glass, raw silk, &c. The percolation of liquids and gases through tissues, in obe-
dience to the laws of capillary attraction, should also, on these principles, be controlled
by the action of a solar beam. If we arrange two Champagne glasses {Jig- 58), with
their footstalks cut off, each capped with a thin lamina of India-rubber, their narrow
apertures dipping into cups of water, so that they may be in all respects as like each
other as possible, and fill them with protoxide of nitrogen, we shall find that one of
them exposed to the sunbeam will throw off its gas much quicker than the other, shut
up in the dark. Or, if one of them be exposed to an atmosphere much warmer than
the other, the liquid confining the gas rises more rapidly. It has been remarked that
the experiment of which I gave an account (52), of the passage of hydrogen gas through
a thin film without pores of sensible size, is not uniformly attended with success. In
examining the causes of failure, I have been able to trace them entirely to this source ;
at a certain temperature tlie effect is scarcely perceptible, but as the thermometer rises
it becomes more and more marked. The same observations may be made of ammonia-
cal vapour. There are temperatures at which these permeations are imperceptible, but
at 75° Fab. they take place with great rapidity.

422. Radiant heat, whether of tlie sun or of terrestrial fire, impinging on the surface of
an obstacle, causes it to exert an increased action, resembling a force of attraction or
pressure, on any medium with which it may be in contact A few fibres of unspun
silk being immersed in water containing the elements of atmospheric air in solution, and
exposed to the sunshine, became speedily covered with babbles of gas. The exact
chemical constitution of these bubbles is determined by a variety of circumstances: by
the velocity of evolution, by the solvent action of the water, which is greater for one
gas than another, and by the presence or absence of the chemical rays. I shall here
be excused for remarking a circumstance which appears to me indicative of a proneness,
even in capillary compounds, to exhibit tendencies of combination by multiple volumes.
Atmospheric air contains oxygen and nitrogen in the proportion of 1 to 4 ; the gas ex-
pelled from spring water contains the same elements in the proportion of 1 to 2 ; and
the gas given off by pine leaves from water, holding carbonic acid in solution, con-
tains the same elements in the proportion of 2 to 1.

423. The chemical rays emitted from the snn are not, therefore, the cause of the
evolution of gas from liquids by fibres, or by vegetable leaves, for it takes place in their
absence ; the blue, the indigo, and the violet rays have nothing to do with it for the
same reason ; and the green, yellow, orange, and red are not tlie cause of it, for though
they are present, it refuses to go on. To the calorific ray we are, therefore, to impute
it It happens not by the action of any kind of light operating as a mere stimulus
on plants, for when the light is nearly absent, it goes on with undiminished energy.

424. The evolution of gas depending, therefore, on the rays of heat, we are next led
to inquire whether the chemical rays affect the operation in any manner. To determine

J 20 GAS FROM LEAVES CONTAINS NITROGEN.

this, I exposed a quantity of boiled water, which had been suffered to cool in vacuo,
to carbonic acid gas, of which it absorbed a certain amount. A portion of this water
was placed in the focus of the brass mirror, and was there acted upon by the non-lumi-
nous rays ; its temperature never exceeded 140° Fah! In a short time the pine leaves
commenced giving off gas very copiously, and continued to do so ; but it was found,
on trial, that nearly the whole of it was absorbed by lime-water, and that no decom-
position had occurred. Therefore, though rays of non-luminous heat are competent to
cause the evolving of gas, they are not able to cause decomposition.

425. The record of an analysis will place this effect in its true light : care being
taken that the water should be impregnated with pure carbonic acid gas, and the leaves
recent, when a sufficient quantity was evolved, 39 measures were taken, of which caustic
potassa absorbed 34. Hydrogen gas being then added, a diminution to the amount of 4
volumes was produced by a platinum ball; the remaining gas proved to be nitrogen.
The composition of this gas was, therefore,

Carbonic acid 34-00

Nitrogen 3-67

Oxygen 1-33

39-00
It is proper to observe that a change very evidently takes place in the structure of the
vegetable leaves, their colour becoming of a dirty brown, and their greenness is lost.
Whether it is a change of their acting tissue which hinders decomposition, or whether
there is some pecuUarity in the constitution of non-luminous heat, which incapacitates
it from producing those effects which result from caloric radiating from highly incan-
descent bodies, I shall proceed to discuss.

426. Let us first consider what is the action of an ordinary unchanged sunbeam on car-
bonic acid in solution, and in contact with vegetable matter. A wide distinction is
here to be made between common spring water, such as pump water, and water charged
with carbonic acid only ; the former contains a compound of oxygen and nitrogen,
isomeric with protoxide of nitrogen ; but the protoxide is a chemical compound, having
its two volumes of nitrogen compressed into one, while this is a capillary compound,
existing with an almost insensible condensation. The processes of evolving gas from
spring water and from carbonated water are essentially different ; the former taking
place by an exaltation of temperature occasioned by the impinging of radiant heat, no
kind of decomposition at all going on ; but the latter is accompanied by a true decom-
position, due to the presence of vegetable matter.

427. This case will be better understood by an analysis of the gas given off from
carbonated water. A certain volume of water had its carbonic acid and all other gas-
eous impurities expelled by long-continued boiling ; it was then rapidly cooled by refri-
geratory processes, and impregnated with pure carbonic acid gas ; being introduced
into a matrass (Jig. 56) with a bunch of pine leaves, the neck of the matrass dipping
under the surface of some mercury contained in a cup, so as to cut off communication
with the atmosphere, it was exposed to the sun, the day being very favourable, clear
and hot; 47*50 measures of the gas evolved were taken ; a piece of caustic potassa ab-

GAS FROM LEAVES CONTAINS NITROGEN. m

sorbed 3-50 measures of carbonic acid, the remainder being 44-00 measures ; 90 measures
of hydrogen were added thereto, making the full volume 13400 measures; a platinum
ball reduced this to 67-00 ; indicating 22-33 of oxygen, there remaining of nitrogen
21-67. The composition of this gas was, therefore,

Oxygen 2233

Nitrogen 21-67

Carbonic acid 3-50

47-50
To prove that the remainder here spoken of was really nitrogen, one hundred volumes
of the original gas were taken, and the electric spark passed through it ; there was no
diminution in the volume, nor any carbonic acid gas generated ; it could not, therefore,
be carbonic oxide, hydrogen gas, nor any of the carburets of hydrogen ; it possessed,
moreover, all the negative qualities of nitrogen.

428. But the solution was composed of carbonic acid and water, great care having
been taken to cut off all access of the atmosphere during its preparation, and also during
its exposure to the sun, for fear of capillary interchange of the carbonic acid with the
gaseous elements of atmospheric air. None such had occurred. From what source,
then, came the large amount of nitrogen gas evolved ? the only elements within the
matrass were carbon, hydrogen, and oxygen, yet here a large amount of nitrogen was
found, which could have come from no other source than the pine leaves.

429. In this experiment the pine leaves absorbed one measure of carbonic oxide, and
gave in exchange for it one measure of nitrogen, and the resulting gas contained, there-
fore, half its volume of nitrogen, and half of oxygen, mixed without sensible con-
densation.

430. Hitherto it has often been asserted by chemists, that when vegetable leaves were
placed in carbonated water, they absorbed the carbon, and caused the oxvgen to be
evolved. Vegetable physiologists, botanists, and others, have raised a great manv the-
ories upon this fact, which, however, a long course of experiments assures me are with-
out any foundation. There is no truth In the idea that plants absorb carbonic acid,
and assimilate carbon and evolve oxygen. On the contrary, they actually evolve nitro-
gen, and the decomposition of carbonic acid, though remotely brought about by the
action of the solar ray, is mainly due to the complex play of affinities of the elementary
constituents of the plants.

431. I will here give another example in point, substantiating the same fact under
different circumstances. Carbonated water that had been exposed vvhh due care to
the sun for two days being provided, 25-75 measures of the resulting gas were taken,
and found to contain 1-25 of carbonic acid, for caustic potassa diminished them to
24.50. Next, 31-50 measures of hydrogen were added, making in all 56-00, and a pla-
tinum ball being introduced, there remained 7-50, indicating 16-16 volumes of oxygen
and 8-34 of nitrogen, the composition of the gas being, therefore

Oxygen 1616

Nitrogen 834

Carbonic acid . . . . 12 5

25-75

J 22 CHEMICAL RAYS OF DIFFERENT COLOURS.

Allowing for unavoidable errors of manipulation, the resulting gas was, therefore, one
third nitrogen and two thirds oxygen, united without sensible condensation.

432. If any farther proof was required that the evolution of nitrogen by the plant is
an essential part of this decomposition, it is furnished by the results of an experiment
in which spun glass was used to replace the pine leaves. This arrangement, though
exposed to the sun under the most favourable circumstances, will not evolve any gas,
but on passing into it a leaf, no matter how small, decomposition at once commences,
because the requisite quantity of nitrogen is given off.

433. A box, a, h, e, e, of a cubical shape (Jig. 59), and nearly 12 inches in each of its
dimensions, had one of its sides taken out and replaced by a trough, k k, of suitable size,
consisting of two glass plates cemented at a distance of one fourth of an inch from each
other. This trough was filled with a solution of bi-chromate of potassa ; one of the
sides of the box was hung on hinges, e e, as a door, for the sake of obtaining access to
the interior. Within this little chamber, a matrass filled with carbonated water, and
enclosing a bunch of pine leaves, its neck dipping beneath the surface of some watei
in a cup, was shut up and exposed to the sun's rays, which, passing through the trough,
impinged upon it. In a short time air-bubbles were copiously given ofi', and when a
sufficient quantity was obtained for analysis, its constitution was determined. The fol-
lowing is selected from a number of analyses, being probably the most correct, and very
nearly the mean :

Carbonic acid .... 16-00

Oxygen 8*16

Nitrogen 4-84

29-00

We here remark the existence of a far larger proportion of carbonic acid, but the rela-
tive proportion of the oxygen and nitrogen is still observed with tolerable accuracy ; the
deviation may be satisfactorily referred to disturbing causes. The greater amount of
carbonic acid, as compared with sections (427) and (431), may hkewise be due to the
higher temperature of the arrangement when shut up in a close box, where currents of
air, or other cooling agents, could not have free access to it. Or it may hereafter be
found that there are chemical rays of different colours, as it were ; or, more strictly, of
different refrangibility and absorbability, and that those which find a passage through bi-
chromate of potassa can cause the decomposition of carbonic acid, though they cannot
blacken chloride of silver. The doctrine that chemical rays are nothing more than un-
dulations of an elastic medium, the waves of which vary in breadth, I shall endeavour
to support ; each of these kind of waves is competent to bring about changes peculiar to
itself Not in this place, however, to anticipate what I have to offer on these matters,
I shall continue to use the term chemical rays as expressing those which blacken chlo-
ride of silver ; and these, I say, are not engaged in the decomposition of carbonic acid.

434. From the first observations made on the decomposition of carbonic acid by
Priestley, this subject has afforded much scope for chemical speculation. Count Rum-
ford examined it successfully, but wanting means of accurate gaseous analysis, and,
above all, not understanding the doctrine and laws of interchange through tissues, his

RELATION OF VOLUME IN THE GASES ABSORBED AND EVOLVED. JJS

conclusions are devoid of that degree of precision which the advance of chemistry, in
all its departments, enables us to attain. The conclusion to which these earher phi-
losophers came was, that plants had the power of absorbing carbonic acid from the air,
and rendering oxygen in return bj elaboration from their vessels ; and this they regard-
ed as the great means employed by nature to maintain the integrity of the composition
of the atmosphere. A. similar view has been taken of this subject by almost every
philosopher who has since examined it. Professor Bcr.net, to accommodate the the-
ory to the obsen'ed facts, infers that plants exercise two functions, the one of breathing,
the other of digestion, the latter only occurring during the stimulant action of the sun-
shine. This phenomenon is, however, unquestionably, one depending on the exalted
capillary action of a tissue when radiant matter impinges on it ; and the evolution of
nitrogen, or of some other gaseous or vaporous matter, is, therefore, an essential part of
the process.

435. The analyses made in the foregoing sections show that the volume of gaS'
which remains after action is complete, is exactly the same as the volume of carbonic
acid first operated on. The best method of proving this directly is to take a tube, the
diameter of which may be half an inch or upward, which is graduated into inches and
decimal parts. Fill it with water, from which all gaseous matter has been expelled by
long-continued boiling; place a few vegetable leaves in it, carefully removing any bub-
bles of air which may be attached to them ; invert the tube in a vessel of water, and
pass into it as quickly as possible a measured quantity of pure carbonic acid, and trans-
fer it to a mercurial trough. This arrangement is seen Jig. 60. Conduct the experi-
ment first in a cool, dark place ; absorption will rapidly go on, and in a short time all,
or the greater part of the carbonic acid will disappear, a column of mercury, e e, rising
in the tube to replace the gas. It is to be remarked that it is not always easy to pro-
cure the entire absorption of all the gas, a little bubble remaining in the upper part of
the tube, containing the impurities that may have existed in the gas, and also any re-
mains of the carbonic acid, for the amount absorbed depends upon several circumstan-
ces, as the relative proportion of the volume of gas to the volume of water, the height
of the mercurial column suspended in the tube, the temperature of the arrangement, &c.
Then, on exposure to the solar rays, gas is copiously given off, the quantity continually
decreasing until farther exposure ceases to evolve any more. On makiu'^; the usual
corrections for temperature and pressure, the ajgregate of evolved gas will be found
precisely the same as the volume first operated on.

436. Sometimes, however, the volume is increased by an amount varying from -10
downward, due chiefly to a certain amount of gas given off from the leaves extrane-
ously, and partly to the capillary action of the whole system upon the elements of at-
mospheric air, which are transferred by slow degrees to the water operated upon, should
there be a film of that fluid between the mercury and the sides of the glass tube ; but,
by making allowance for these disturbing actions, the proportion of equahty will be
found to be rigidly observed by the absorbed and the evolved quantities.

437. We find, therefore, that the evolution and decomposition o carbonic acid bj
the solar ray are due to that part of it exciting heat ; that the chemical ray has no di-

P

214 CAUSE OF THE PHENOMENON.

rect agency in the matter ; it may bring about changes which, to a certam extent,
comphcate the phenomenon, but it does not produce the abstraction of any compound
of oxygen and carbon from carbonic acid. Apart from the agencies exercised by the
elements of the plant, agencies which are unquestionably of the utmost importance, the
decomposition is remotely brought about by the action of radiant matter. But non-
luminous heat, though capable of evolving gas, produces no change of its constitution ;
shall we, then, suppose that there is a difference, in point of quality, between the heat
given off by the bodies below ignition, and the heat of incandescent matter 1 Or does
the light itself aid decomposition ? An experiment may be made which appears to me
to bear directly on the answer which should be given to this query. Let a beam of
light (^fig. 61), two inches in diameter, pass through an aperture in the shutter A B, and
fall upon any medium, c d, which absorbs a certain number of the rays of heat, as
bichromate of potassa, which may be so diluted as to absorb exactly 50 rays out of every
100. Having, by nieans of a good thermometer, g, measured this, let the beam of light
pass through a second trough, ef, containing the same solution of the same strength, and
its temperature again be taken, it will appear that the ray, instead of losing half its
heat, will contain nearly all of it; or, in other words, the second trough exerts no action
on the passing beam. In an experiment tried after the manner here indicated, the ther-
mouieter having shown a loss of 50 rays by the action of the first trough, fell only to
47, or gave a loss of three rays only as the action of the second trough ; an action to be
referred, undoubtedly, to a degree of turbidness which does exist, to a small extent, in
the clearest solutions ; and also to the reflective and scattering action of the surfaces of
the troughs. Now the very same thing takes place in the case of light. A beam that
has passed througli a green, or any other coloured glass, loses much of its intensity, but
if it pass through a second plate, of the same tint, the second loss is entirely dispropor-
tionate to the former ; and the reason of this is very apparent, for if the second plate had
been of a different colour, the ray might have been much more affected,^ or even entirely
extinguished. Delaroche made an identical observation in the case of non-luminous
heat, for he proved that a plate of glass obstructed a large portion of the rays falling
on it, but that a second plate allowed these rays to pass with far less loss. Now
these experiments would lead us to conclude that there are essential differences in ra-
diant heat analogous to the differences in light. The rays of heat given off by a can-
ister of hot water may be, to use an expressive solecism, violet heat, and a piece of
transparent glass may be able to transmit green heat only ; hence, in using two plates,
the absorptive action of the first has the largest share in producing the phenomenon,
the second transmitting nearly all which passed the first, an action identical with that
of coloured glass on light. Bodies, as their temperature rises, emit more and more rays
capable of passing through glass, simply because they become of that class over which
the medium does not exercise an absorptive power.

438. The general conclusion which we are to draw from these researches is, that
the decomposition of carbonic acid gas by vegetable matter is a very complex phenom-
enon, due to the combined action of three forces : 1st, the decomposing action of a tissue;
2d, to the impinging of radiant heat ; 3d, to chemical affinity, it being probable that any

I

AO.N-OXYGILNATION OF PHOSPHORUS. 115

of these alone would be incompetent to produce this result. And in the case of gas,
such as oxygen, being evolved from spring water, we are to refer the change to the
ready decomposition of capillary compounds, compounds essentially distinct from chem-
ical, and which can suffer decomposition by the force of capillary action. The colo-
rific and the chemical rays have no influence in this latter case.

439. Nox-oxvGE.\ATio.\ OF Phosphorus. — It is stated in the books that Ritter, in
making observations on the slow combustion of phosphorus at common temperatures,
found that it emitted white fumes in the invisible red ray of the solar spectrum, but in
the invisible violet, phosphorus in a state of oxygenation was instantly extinguished.
As a similar action is alleged to take place when the sun's rays shine on ignited car-
bon, it becomes desirable to understand the mode of action : the original experiment of
Ritter was therefore repeated, with a Wew to ascertain its accuracy. A cylinder of
phosphorus, a b {Jig. 62), an inch long, and about one sixth of an inch in diameter,
was shielded from the action of aerial currents by a glass jar. In front of the jar an
equiangular prism of flint glass was placed, so that the rays of a decomposed beam of
light coming in through the shutter, c d, could successively be thrown on the phosphorus,
which was placed horizontally in the jar ; the beam of light also came nearly horizon-
tally into the room, reflected by the arrangement already described. Situated thus,
by turning the prism on its axis, any ray could be made to cover the phosphorus: the
temperature in the shade being 72° Fahr., a fine sheet of metaphosphoric acid, mingled
with vapour of phosphorus, so thin as to be almost imperceptible, except in certain po-
sitions, was obsened to be rising from the cylinder; sometimes it would form a fine
cloud, which hung for a moment on the phosphonis, and then rose gracefully in curled
wreaths. The extreme mobility of this cloud was remarkable : even the warmth of the
observer, by causing currents within the jar, would affect it ; if the hand approached, as
at A (^g. 63), the phosphoric vapour came to the side of the vessel, as it were to meet
it, and then rebounded and circulated along the top of the jar. The size, position,
and shape of this cloud, when enveloped in the red light of the prism, were deliber-
ateh marked ; its motions were merely more capricious than when in the shade. And
now, by turning the prism, the extreme violet ray was brought upon it, but neither
did its motion, nor magnitude, nor figure appear in any wise changed.

440. The impression conveyed by Ritter's experiment is, that the chemical rays
possess the faculty of hindering oxygenation. The negative conclusion here arrived
at might be due to local circumstances, and be referred to the action of the prism, as
to its composition, to the state of the atmosphere, &c.; but no better success attended
a variety of trials made on different days, and with prisms of crown glass, turpentine,
and water. Trial was therefore made of absorbing media, a beam of light being made
to pass at one time through a solution of sulphate of copper and ammonia, and at an-
other through bichromate of potassa, but the condition of the phosphorescent cloud
was found to be too rough an estimate of the real action. A cylinder of glass (A B.
Jig. 64), -75 inch in diameter and 3 inches long, was therefore fitted at its upper end
with a stopcock, a; its lower extremity was closed air-tight with a cork, through which
an inverted siphon, b b, passed, each of its limbs being four inches long, and the bore

216 NON-OXYGENATION OF PHOSPHORUli.

being ^th of an inch ; the outer limb was fitted with a scale. After having opened th^
cock, a, a stick of dry phosphorus, e, was suspended in the cylinder, which was made
very clean and dry, and the siphon being filled with water, was firmly seated in its
place and the cock closed. Now, as the phosphorus oxydized, the nietaphosphoric
acid was removed by the water present, and the level falling in the lateral limb, indi-*
cated what quantity of oxygen was consumed, and, therefore, the rate of combustion
of the phosphorus. This was expected to give a more accurate estimate of any chan->
ges occurring in the phenomenon, and was accordingly applied to detect them.

441. Beams of light of different colours being made to pass at different times through
the cylinder, so as to impinge on the phosphorus, attempts were made to ascertain the
rate of combustion for each, as also for the white light of the sun, and in the shade.
In each insulated experiment, the fluid in the gauge sunk with great regularity, more
rapidly at first, and then more slowly, but the same regularity was not observed in dif-
ferent trials. At one time the phosphorus would consume with more than double the
rapidity than it did at another, though to all appearance under identical circumstances.
If the slow combustion of phosphorus be at all affected by the action of solar light, i£
is certainly not to that extent which Ritter supposed. So far from extinguishing, the
violet rays do not exert any control over it, or if they do, it is to so small an extent
that the most delicate arrangements fail to detect it.

442. It is possible, however, that atmospheric temperature may exert an influence
on the result. During the trials here made, a thermometer in the shade ranged from
70' Fah. to 82° Fah. At these points the affinity of the combustible material for oxy-
gen may be so exalted that the action of any weaker force becomes masked. It is not
stated what were the temperatures at which the alleged results were obtained. But it
is most probable that the presence of extraneous matter was the cause of all these vari-
ations. It is well known that certain compounds of hydrogen and carbon, in ex-
tremely minute quantity, will entirely put a stop to the oxydation of phosphorus ; and
during the course of these trials, I have had abundant reason to notice errors arising
from this cause. By simply wiping out the cylinder with a linen cloth, which con-
tained an almost imperceptible trace of spirits of turpentine, an erroneous result like
that of Ritter was at once obtained.

443. Decomposition of the Salts of Silver. — Several of the salts of silver un-
dergo a remarkable change when exposed to the rays of light, the bromide, the
chloride, and the nitrate being very good examples; these, which are all white, become
of a dark colour, approaching almost to black, when exposed to the violet rays ; it is
stated that the bromide is most readily affected, yielding a brownish-black colour.

444. If a piece of paper be soaked in a solution of nitrate of silver, and then dipped
into a solution of bromide of potassium, it affords a very advantageous means of ma-
king these experiments. The chloride may occasionally be substituted for the bromide
of silver.

445. A beam of light {fig. 65, a a) entered a dark chamber horizontally, and was
obstructed in its course by a plane metallic screen, b, having a hole half an inch in
diameter in it. The beam, c, which passed through this aperture fell upon a flint

PRISMATIC SPECTRUM ON BRQifip^ QF SILVER. nj

glass equiangular prism, d, aud was dispersed by it, the spectrum, e f, being received on
the table; this spectrum was about tliree inches long. And now a piece of paper, im-
bued with bromide of silver, was placed to receive it, with the intention of ascertaining
how far the discoloration would extend. In the course of five minutes a very marked
change had taken place, and, on examination, it was found that the deepest tint had
been occasioned where the violet blended with the indigo rays; beyond this, even in
the dark space beyond the spectrum, there was a stain, as also as far in the spectrum
as where the green light merged into the yellow, an effect represented in Jig. 66, a a,
b h, being the spectrum ; during this experiment the spectrum was kept stationary.
Again, a column of light, three inches in diameter, converging from a convex lens (« a.
Jig. 67), was intercepted by a screen of pasteboard, b b, which had a circular aperture
in it half an inch in diameter; this screen was placed at such a distance from the
focus, that the circular section of the cone of Hght was half an inch in diameter, and,
therefore, passed exactly through the aperture ; a piece of the prepared bromide pa-
per was then fastened on the back of the screen, so ^ to receive the condensed
rays which passed the aperture. In a few moments a black spot appeared about the
central parts of the paper, and at the end of the experiment there was an intensely
black circle, surrounded by a brown, ring-like penumbra, as \njig. 68; the diameter of
the black spot being three quarters less than that oi the aperture through which the
light passed.

446. Interfere.xce of the Chemical Ravs. — Under certain circumstances, two
aerial vibrations, each of which, if separately striking the organs of hearing, would pro-
duce a musical sound, may so interfere with each other as to produce an unmelodious
rattling, or even silence. Also, two rays of light, whose paths bear a certain relation
to one another, instead of increasing each other's intensity, may have a directly oppo-
site effect, and, neutralizing each other, produce darkness. It becomes, therefore, a
question, not only of mere curiosity, but one whose bearings are important, to find if
the chemical rays emitted from the sun, when placed under similar circumstances,
exhibit similar phenomena. For then analogy would lead us to know that it is possible
for two rays of heat to be so situated with regard to one another, as, instead of ex-
alting the temperature of the body on which they fell, to lower it ; or, in other words,
to produce actual cold.

447. In my early trials for the solution of this question I met with many disappoint-
ments, but at last I fell upon an arrangement which yielded positive information. It is,
however, an experiment requiring careful manipulation. A horizontal beam of Ught being
projected into a room by the apparatus heretofore so often referred to, at the extremity, e e
(Jig.69), of the brass tube, a double convex lens of short focus was screwed; this brought
the rays to a point at a distance of three quarters of an inch from the lens : here
they were obstructed by a metallic screen, b b, having a round hole, c, one eighth of an
inch in diameter, perforated in it This screen revolved about a vertical axis on a pil-
lar, rf. so that it could be brought to any angle with the incident rays. The rays passing
through the round hole, c, were received on a white screen, g g, at a distance of six
inches. When the screen b b received the incident rays perpendicularly to its surface.

228 SALTS DECOMPOSED BY LIGHT.

then, of course, the image thrown on the screen g g was circular ; but if the screen b h
was made to receive these rays at an acute angle, then the image was lenticular.
Under the last condition, the phenomenon of diffraction is represented in Jig. 70, where
a a is the screen, b b the lenticular image cast on it; it is of bright white light except at
its central part, c, where there is a dark image produced by the interference of the pass-
ing rays.

448. If, in such an arrangement, the chemical rays do not interfere with each other
so as to neutralize effects, chemical action should be produced in every part of the
image, even including its central part, c ; but if, on the other hand, these rays are obe-
dient to the same laws as the rays of light, then, in the central parts of the image, no
chemical effects should ensue ; the problem is, therefore, reduced to the finding how
any compound, changeable by these rays, will comport itself on the central and peripheral
parts of such an image.

448. In place of the screen g g, a substitute was used consisting of two thin plates
of mica, with a layer of bromide of silver included between them ; these were mounted
in a little ivory frame, abed (Jig. 71), just in the manner that objects are usually mount-
ed for the use of the microscope, and the lenticular image cast upon the bromide.
After an exposure of five minutes, during which care was taken to keep the sun's place
perfectly immovable, and also to avoid all local tremour, which might make the image
traverse on the bromide, the result was very apparent, being, as represented in Jig. 72,
of the natural size ; the peripheral parts being of a deep brown, and the centre yellowish
white. Viewed through a lens, the boundary line was not sharp and distinct, but
seemed to merge by an insensible gradation into the unaffected part, as in Jig. 73. The
conclusion to be drawn from this result possesses no common interest ; for the same
reasoning which demonstrates that light consists of undulations of an elastic medium,
applies here also.

450. The chemical rays, thus closely attending the luminous rays, and being, like
them, subject to the forces bringing about reflection, refraction, and interference, it
would become a matter worthy of inquiry to find whether there be any different classes
of these rays analogous to the different coloured rays of light, or the unequally refran-
gible and absorbable rays of heat. The salts of silver are only one of a class over which
the chemical rays exert an action. The following list contains, I beHeve, all the me-
talUc salts at present known, in the constitution of which changes are brought about
by exposure to the sun:

Chloride of manganese, Iodide of mercury,

Sulpho-cyanate of iron, Chloride of mercury,

Sulphate of nickel, Bichloride of mercury,

Carbonate of lead, Chloride of silver,

Carbonate of nickel, Bromide of silver.

Nitrate of bismuth, Sulpho-cyanate of silver.

Chloride of uranium, Nitrate of silver.

Sulphate of uranium, Bromate of silver,

Nitrate of uranium. Chloride of gold.

Chloride of copper. Chloride of osmium and potassium.

MOONLIGHT AND ARTIFICIAL FLAilES ARE INACTIVE. hq

-Besides which, there are two others, whose constitution is not well known ; one pre-
pared from an alcoholic solution of the double chloride of platinum and sodium, by
the action of chloride of potassium, and the other in a similar manner from the cyanide
of platinum.

451. The changes which these bodies experience are of different kinds : some be-
come black and some turn white ; some, as the sulphate of nickel, undergo change of
crystalline arrangement. If we are to take the chloride of silver as a type of those
bodies which undergo partial reduction, it will be found probable that the change im-
pressed on them is only superficial, as analysis will show. But we cannot tell with
certainty whether a perfect reduction of some of these compounds takes place, or
whether it is a sub-salt of a dark-gray colour that results. By taking advantage of
the property which chloride of silver possesses of subsiding very slowly from neutral
solutions, so as to make them assume a milky consistency, we may present it in a state
extremely favourable to the action of the solar ray. For if a thick mass alone be ex-
posed, the central parts will not undergo the same change as the exterior, being shielded
by them from the sun. A milky solution will, after an exposure for a certain time, be-
come quite clear, the chloride precipitating, owing to the liquid becoming acidulous.
Mechanical agitation being then resorted to, to expose fresh surfaces of the precipitate
very frequently during a period of eight or ten days, and care being taken to suffer no
dust or other impurity to enter the vessel, it will be found that the powder has become
of a reddish gray, interspersed with little particles of unchanged white chloride ; these,
from their superior density, will have precipitated more readily than the gray particles;
washing and decantation will therefore readily effect a separation of them. One hun-
dred grains of the dark chloride thus treated yielded, on analysis, 79-3 of metallic silver ;
that quantity contains, therefore, 20*7 of chlorine ; it has lost by exposure 5-3 grains of
chlorine of the quantity originally contained in it

452. Other analyses, of the same sample, fiimished results not widely varying from
this, but such is not the case with analyses of different samples; these give sometimes
more, sometimes less chlorine ; they prove that the chloride of silver, as darkened by
light, is not a definite compound, but rather a mechanical mixture ; that the change of
composition is chiefly confined to the surface, and does not affect the interior of the
particles to any extent; it is true that microscopic observation shows them to have
a uniform consistency and colour, but of course reveals nothing of their internal char-
acter. An error is frequently made by writers who describe the changes happening in
this partial reduction ; it is not, as they say, hydro-chloric acid which is evolved when
the chloride is under water, bnt it is chlorine, as is made very evident by the strong,
disagreeable odour of that gas when the experiment is conducted in close vessels.

453. In addition to the hst given above of substances changed by the chemical rays,
there are some others which exhibit their action in a very marked manner. Chlorine
and hydrogen unite together with an explosion ; carbon and chlorine are also made
thus to unite in producing the per-chloride of carbon ; all kinds of vegetable colours
are bleached ; hydriodide of carbon and chloro-carbonic acid are always made by the
action of solar radiant matter.

120 PERIHELION MOTIONS.

454. It has been stated by some chemists that, while the violet extremity of the solar
spectrum blackened chloride of silver, there are other parts of it which would bleach the
salt so blackened. But it is not so, for neither does any part of a very dispersed spec-
trum, nor a beam which has passed through a variety of absorbing media, exert such an
action. These experiments I tried- repeatedly, under all the conditions of variation of
temperature and brilliancy of the solar rays, but no observation led to the inference
that there was any change of colour, or any sign of an approaching change, even after
the lapse of a whole month. Indeed, it would seem that the state of the case does not
justify any such expectation ; when the chemical rays have disengaged the chlorine, it
is gone, and lost forever to the silver, being scattered abroad in the atmosphere; if, there-
fore, the substance ever regains a white colour, chlorine must have been purposely fur-
nished from other sources, or the white substance said to result must be some compound
of unknown ingredients.

455. The light of the moon is a remarkable example of luminous rays existing with-
out either calorific or chemical rays ; the most delicate thermometric arrangements have
hitherto failed to show any rise of temperature in the moonshine. A piece of paper,
imbued with chloride of silver, may also be exposed to the rays of the full moon, con-
verging from a glass, and it will not exhibit any change ; this I proved by placing such a
paper in a situation where, for a whole night, the rays of the moon could reach it. And
the same observation applies to terrestrial flames. In none of these has the existence
of the chemical rays been detected. Chloride of silver, after being exposed for eight
hours to the bright flame of an argand lamp converged by a lens, retained its whiteness.
The same effect was witnessed when the flame of alcohol tinged red by strontian was
employed, or the yellow flame produced by chloride of sodium, and the green of boracic
acid ; in these cases the periods of exposure did not exceed half an hour.

456. Of Perihelion Motions. — Probably the most remarkable effect exhibited by the
solar rays is the motion they produce in media endued with much mobility. For many
years it has been known that camphor exposed in a bottle to the rays of the sun, formed
a crystallization on that side of the vessel nearest the luminary; but the action is so
slow, and requires such a length of time for its completion, that no successful investiga-
tion has been made as to the nature of the forces in operation. Some philosophers
have assumed, upon insufficient ground, however, that the crystallization was effected
on the most illuminated side, merely because it was the coldest, as we know that vapours
are always deposited on that part of a surface the temperature of which is the lowest.

457. About three years ago, I published a series of observations on this point. Hav-
ing found, from some theoretical considerations, that the crystallization of camphor took
place in vacuo with a rapidity convenient for experimental investigation, I was led to
make an extended inquiry into the whole matter.

458. The sun's rays have the power of causing vapours to pass to the perihelion
side of vessels in which they are confined, but, as it would appear, not at all seasons of
the year. For example, I have a certain glass fitted up for making these observations,
and in this vessel, during the months of December, January, and part of February, 1836—
37, a deposite was uniformly made towards the sun ; during the months of March, April,

PERIHELION MOTIONS. i21

aod part of May next following, although every part of the arrangement remained to all
appearance the same, yet the camphor was deposited on the side farthest from the sun.
From May until the present date, the deposite is again towards the sun. It does not
appear that any immediate cause can be assigned for this waywardness. Does it exist
in the sun's light I or in changes affecting the earth's atmosphere I or in imperceptible
changes in the instrument with which the observation is made ! As respects the latter, I
think a negative answer may be given without any hesitation; but beyond a mere ex-
pression of the fact that these anomalous circumstances do occasionally occur, I would
not be understood to speak decisively ; if periodic changes like this do occur, which is
doubtful, they have not been watched for a sufficient length of time, nor have I made
sufficient variations in my trials to be able to refer them to any distinct cause. A large
bottle containing camphor, which has been deposited therein for more than a year under
ordinary atmospheric pressures, has uniformly showed a crystallization towards the light

459. For making these experiments properly, it is necessary to possess an air-pump
receiver ground so true as to be able to maintain a vacuum for several hours, or even
days. A less perfect jar may be made to answer by fastening it down to the pump
plate with cement ; it will, however, be liable to leak when the cement becomes warm by
exposure to the sun. For many of these trials a barometer tube is sufficient Those
who are provided with a good pump and jars, accompanied with their proper transfer
plates, will have no difficulty whatever.

460. Upon the plate of the pump, or one of the transferers, a a i^fig. 74), place some
camphor in a watch-glass, c, supported by a stand ; over this place a bell-jar, and ex-
haust until the difference of level of the siphon gauge amounts to half an inch or less —
the farther the rarefaction is pushed the better — then remove the arrangement into the
sunshine. In the course of five minutes, if the atmosphere be clear and the sun bright,
small crystalline specks will be found on the side nearest to the sun ; these continually
increase in size, and at the end of two hours many beautiful stellated crystals, firom one
eighth to half an inch in diameter, will be found on that side, but on the other parts of
the glass only a few straggling ones here and there. This appearance is represented
vajig. 75; sometimes the whole side next the sun is covered with a deposite of camphor,
the other side containing none at alL

461. Having made a torricellian vacuum, in a tube upward of 33 inches long and
five eighths wide, pass into it a piece of camphor, which will rise into the void. This
arrangement, like the former, when kept in the dark shows no crystallization, even
though so kept for more than four months; but on bringing the vacuum into a beam of
the sun, crystallization rapidly goes on, and at the end of a quarter of an hour the ap-
pearance is such as is represented in^o'. 76. It is not important that the temperature
of the sunbeam or of the atmosphere should be high ; this is an experiment which
will succeed at temperatures var\-ing from 120° Fah. to 60° Fah., and probably at much
lower degrees, for it is readily performed in the depth of winter.

462. It is not a phenomenon connected with the process of crystaUization. Take
a jar twelve inches high and four in diameter, quite clean and dry, place it over a glass
of water, h (Jig. 77), and expose it to the sunshine. In this experiment it is not re-

a

122 DEW OF WATER AND MERCURY.— IODINE AND GOLD, ETC.

quired that there should be a vacuum within the jar. In the course of an hour or two,
there will be a copious dew at a, and on farther exposure drops of water will trickle
down the side of the glass, but on the opposite side not the least cloudiness will be found.

463. Barometers, hung up in such a position that the sun's rays can have access to
them, exhibit an analogous appearance, the side nearest the Ught being studded with
metallic globules.

464. In any of these experiments iodine may be substituted for camphor, provided
mercury is not present, nor any other substance on which this body acts; the most
advantageous method of using iodine is by heating it in a suitable vessel, and when
the vessel is quite full of vapour, presenting it to the sun's ray; deposition goes on, on
the sunny side, as the condensation takes place.

465. Nor is it requisite, in obtaining these results, that the material should be either
gaseous or vaporous. The rays of light have the property, as was found by Count
RuMFORD, of decomposing an aqueous solution of chloride of gold ; on making this ex-
periment in a test tube one third of an inch in diameter {fig. 78), small spangles
of metallic gold will be seen, by reflected light, on the side towards the sun, h; by
transmitted light it appears of a pale green tint, as is the colour of gold leaf. Here we
find that, under certain circumstances, solutions will deposite metallic matter, in obe-
dience to the same laws which cause the crystallization of camphor and the deposite of
aqueous dew.

466. A few pieces of camphor were laid on the plate of an air-pump, and a circle
of glass two inches in diameter {a, fig. 79) was supported on a pedestal in the midst
of them, the upper part of the glass being four or five inches above the pump plate ; it
was then covered with a jar, and exhaustion performed. On exposure to the sun for
a suitable length of time, numerous crystals were found on the jar, but none on the
circular plate, although it had received the full beams of that luminary. This experi-
ment was made with a view of determining what peculiar condition a glass surface was
placed in by exposure to the light; for experimental purposes, the rounded form of the
glass receivers being very unsuitable. It was not, therefore, without surprise I observed
that, however long the plate was continued in the beams of light, no crystallization
would ensue. A flat surface, however, being essential in the course of experiment pur-
sued, trials were repeatedly made, by various changes in the arrangement, to cause a
deposition of camphor upon such a crown glass plate ; but though in five days I could
procure starry crystals upon the bell jar of more than half an inch in diameter, in
no instance was a solitary one found on the glass plate.

467. Two circumstances may determine the precipitation of camphor crystals on a
surface : 1st. Reduction of temperature ; 2d. Increase of pressure. To the former we
cannot look for an explanation in the case before us, for there is an actual increase of
temperature in every part, and more especially on that side of the vessel which is next
to the sun. Why, then, does this condensation take place on the hottest surface, the
side nearest to the sun ? we cannot admit that the rays of heat have any active part
in bringing about the phenomenon. On the other hand, they ought rather to exert
a contrary effect, antagonizing the powers that solicit the camphor crystals to form.

CURRENT ACTION. 123

and driving them to the coldest surface. We are therefore reduced to the supposition,
that when the light of the sun impinges on a surface of glass, it places that surface in
such a condition that it exerts a pressure on the adjacent medium, immediately follow-
ed by a condensation of that medium. The state of the force here spoken of applies
to the glass surface alone ; it is not an action between the solar ray and the forces that
produce crystallization, seeing that it equally takes place in the deposite of aqueous or
mercurial dew, and even of solid gold from a solution of its chloride. In other words,
if a ray of the sun be incident on a surface of glass, it develops a force of attraction on
that surface.

468. A gaseous medium, having its temperature disturbed at any point, has a current
determined in it In a chamber, such as the bell of an air-pump, this current circulates
round the walls, ascending on the hot and descending on the cool side ; it might be
supposed that to this circumstance was due the fact of no crystals being found on the
plate of glass (466). The condensation cannot, however, be attributed to this cause ;
for if so, a lamp, or any other source of heat, would be equally effectual; it will, how-
ever, be hereafter shown that artificial flames tend to remove these depositions from
the side nearest to them, and cause them to be accumulated in the colder regions.

469. Beneath a receiver (a. Jig. 80) a cubical bottle, b, having flat sides, was placed,
and in the bottle a few pieces of camphor; the mouth of the bottle was about half an
inch in diameter, and was left open, the pressure of the atmosphere being reduced to
li inches of mercury. Temperature of the raj- 57° Fah. On examination, after the
lapse of one hour and twenty-five minutes, no crystals whatever could be found on the
receiver, and but a few sparsely scattered on the sides of the cubical vial. Now there
can be no doubt that the whole receiver was full of camphor vapour, and it does
not appear that any reason can be assigned for the anomaly of its non-crystallization.

470. Will artificial light produce analogous results ? To ascertain this, I took a
glass globe about one inch and a half in diameter, with a neck four inches long, fitted
it with a stopcock, and introduced within it a drop of water. The vapour of this
water exhibited extreme mobility ; exposure to the clouds caused its immediate deposi-
tion. A farther advantage was gained by the use of this apparatus, for by heating the
globe uniformly, until all the moisture on its surface was vaporized, and then allowing
it to cool, the particles of water readily obey the forces that soUcit them. This glass
globe, supported vertically on an appropriate stand {a. Jig. 81). was placed at a distance
of nine or ten inches fi-om a brightly-burning argand lamp, A ; to protect it from acci-
dental currents of air, and from irregidarities of radiation from other sources, the whole
arrangement was covered by a bell, h c, open at both ends, and about fifteen inches high.
It appeared, at first, that a thin dew lined the inside of the whole globe, instead of being
confined to one part; but after a certain space of time, the heat which passed from the
lamp through the protecting glass disturbed the results, the dew^ being driven to the cold-
est parts. To get rid of the effects of this heat, at a distance of about three feet from
the lamp {A., Jig. 82), a double convex glass lens, c, 2\ inches in diameter, was placed,
which brought the rays to a focus at a distance of five or six feet, where stood the glass
globe, a, covered with its protecting jar. The globe had been previously sUghtly warmed.

,'1-24 TEMPERATURE OF THE SIDES OF A JAR.

SO as to expel all the dew from its surface, and give it a uniform temperature ; in sev-
eral trials it was found that there were no evidences that the bright flame of an argand
lamp exerted any force soliciting the vapour of water to move towards one part of the
glass rather than another.

471. I took the arrangement of 462, and shut it up in a dark closet, having pre-
viously made the jar perfectly clean and dry ; it remained there for several days, that
it might be found whether those little irregularities of temperature wliich occur in such
confined chambers would cause this dew to pass to one side of the glass rather than
another ; it did not appear that such was the case, for the glass was as free from
moisture when taken out as when shut up. And now, this arrangement being placed
in the window, where the sun was brightly shining, exhibited on its perihelion surface,
in the course of three and a half minutes, a pearly dew ; and in six minutes drops of
water were trickling down that side.

• 472. But it is not essential to the success of this last experiment that the solar ray
itself should impinge on the vessel. The temperature in the shade being 94° Fah., I
placed the receiver with its cup of water in a window having a northern exposure, and
found that the dew readily made its appearance on that side which was towards the
light.

473. It might be suggested that when a vessel is exposed to the sun, that part of
the glass which is nearest to him may actually be the coldest ; such an opinion, it is
evident, rests on no sufficient grounds. A jar, a g i^fig. 83), was taken, of such dimen-
sions that it could receive the differential thermometer, c d b, the balls of which, b and c,
touched the opposite sides, and in the dark the liquid stood at zero, but on bringing
it into the sunshine, if the side a was exposed, then the ball c was warmest, and if the
side g, then the ball b was warmest, as was indicated by the motion of the liquid.
Hence we know, that in all cases where crystals of camphor, dew of water, &c., are
deposited on the side next the sun, they are so deposited in opposition to an energetic
force which tends to remove them.

474. Light which has suffered reflexion at certain angles seems to have undergone
a remarkable modification, being no longer able to put the glass into such a condition
that it can cause motion towards the sun. It is not to be inferred that any connexion
is here traced between this disturbance of the condition of light and the change im-
pressed on it by polarization. A beam of the sun falling on a plate of glass, and being
reflected at an angle of 45°, may be intercepted by any of the arrangements of sections
460, 461, as by the barometer tube. It will be found that the crystallization proceeds
with considerable rapidity, not, however, on the perihelion side of the vessel, but on
the opposite side. It is probable that this result is not dependant on the polarization of
light, inasnmch as it takes place equally well at all the angles, less and greater than the
maximum angle of polarization of glass. Light, even that of the sun, having once
undergone reflexion, has received some determinate impress, which disables it entirely
from causing camphor to crystallize on the perihelion side of vessels.

475. Another remarkable phenomenon is exhibited by the following arrangement :
Take a receiver, a {^fig. 84), twelve or fifteen inches high, and three or four in diameter;

ACTION OF A SCREEN. Jg^

place it, as usual, upon the transfer plate, with its proper charge of camphor, c. Then
cover it wilh a tin cylinder, ef, of sufficient dimensions, so that all the light may be
shut out except at one place, g, where there is a hole half or three quarters of an inch
in diameter. Under favourable circumstances, as a serene sky and bright sun, let the
arrangement be exposed, that a column of light may pass through the aperture g into
the glass; it may or it may not finally fall on the camphor at c. It would, of course,
be expected that a collection of crystals would form on the inner surface of the glass
corresponding to the aperture g. But on trial it is not so ; for however bright the sun
may shine, or however favourable other circumstances may be, not a solitary crystal
will make its appearance either there or on any other part of the vessel, provided its
temperature has been pretty uniform. On an exceedingly calm and serene day in
July, 1835, when every circumstance seemed propitious, I made this experiment, and
because the jar that I was using was not ground sufficiently true to fit the transfer
plate accurately, it had been fi.xed thereon with common cap cement, and on exposure
to the sun, the temperature of the whole arrangement rose so high that the cement
was in almost a semifluid condition ; it was one of those days when the eye cannot be-
hold the sky or look on the ground without pain, yet not one crystal could be made to
appear opposite to the aperture. But on taking off the metallic screen, and exposing
the jar, in a little more than a minute small specks were observable on the glass, and in
a quarter of an hour its perihelion side was densely coated with crystals. How are we
to explain this ? Do the edges of the aperture g impress any change on the passing
light ? Or is the glass surface placed in such a condition that it can no longer produce
the deposite of crystals ? We shall see hereafter that there are circumstances yet more
remarkable, which put us in possession of an explanation.

476. For the proper understanding of the rationale of these experiments, it is required
to know whether it be essential that the solar ray should impinge on the camphor or
not, or whether the action is exerted on the vapour only. A tube was therefore taken,
ot suitable dimensions ; in the lower part of it a fragment of camphor was deposited,
and screened as much as possible from the rays of the sun, while its upper part was
freely exposed. Crystals formed without difficulty at a distance of three or fonr inches,
or even a foot, from the camphor, but there appeared to be a limit beyond which they
did not readilv pass. A tube four feet six inches long and two inches in diameter being
exhausted, did not show on its exposed end any appearance of crystallization. Near the
camphor the deposite was pretty copious, but in advancing from it the crystals were more
sparsely scattered, until, towards the upper extremity, none could be seen. Now the
maximum quantity of vapour that can exist in a void, or among other gases, provided
the mixture be in equilibrio, depends on the lowness of the temperature of any one
part of the vessel; and hence, a long tube, one of the extremities of which is kept cold,
does not exhibit these configurations readily, because the quantity of vapour in it is
small, owing to the coldness of one part of the void space. It is not necessary, there-
fore, that the sun should shine on the camphor, the effect of the rays taking place en-
tirely on the vapour filling the void. ^

477. There is a singular action which certain bodies exert over this process. Take

226 PROTECTING ACTION OF A RING.

a receiver, able to niainiain a vacuum for some time, and liaving cut out a ring, a {Jig.
85), of tin foil, an incii and a lialf in internal diameter, and half an inch wide, paste it
upon the receiver, as at a {fig. 86) ; moreover, accommodate the receiver with its cam-
phor, as usual, and having exhausted, expose it to the direct rays of light, so that the
ring a shall be on the perihelion side. In the course of a short time that surface will
be found studded in various directions with crystals, as is to be expected ; but it will be
found that none of these crystals come within a certain distance of the ring, and that
not one is to be seen within the circle circumscribed by it. The ring, therefore, ex-
erts a kind of protecting action on the glass, hindering the deposition of crystals within
certain limits ; such a result is depicted in^g'. 87.

478. This action of a ring, formed of good conducting materials, might be sup-
posed to arise either from its adding something to the surface of the glass, or taking
something away from the glass with which it is in contact. Or it might be imputed to
some change impressed on the ray of light. Take, therefore, a ring, a (Jig. 88), and
place it before the receiver, b, at a distance of half an inch, the ring being of the same
dimensions as in the last experiment ; it will be discovered that, although the ring does
not touch the glass, it still protects it, no crystals coming within a certain distance of
the regions overshadowed by the metal ; and even at a distance from the line of shadow
not a crystal is to be seen, nor any visible in the illuminated centre.

479. Even after crystals have been formed on the surface of the jar, if it be placed
in the sunshine with a ring before it, as in the foregoing experiments, the ring will be
found not only to exert a protection on the glass, hindering any farther deposite, but
will even remove the crystals that are there.

480. This is, indeed, a remarkable circumstance ; a part of the perihelion surface
is shaded from the sun, and thereby rendered cooler, yet the crystals deposite themselves
on the hottest surface, and avoid that where it is cold. We see, now, how it happens
that, in the experiment of admitting a column of light through a hole in a screen, no
crystalline deposite was effected ; the protecting agency of the metal, whatever its power
might be due to, hindered it.

481. To give the particulars of one of these experiments. On the 11th of July I
prepared an arrangement such as the foregoing : the thermometer in the shade was at
76° Fah., and in the sun at 99° Fah., distance of the ring from the jar half an inch, its
internal diameter three quarters, and width half an inch. After proper exposure the jar
was examined ; there were no crystals on that part opposite the central opening of the
ring, and the nearest crystal to the internal border was six tenths of an inch distant
from where the shadow was projected on the glass.

482. Vapour of water exhibits similar phenomena ; a thin piece of tin foil in the form
of a cross, a ring, or any other shape, effectually prevents the deposite of water near it.

483. Instead of placing the ring outside of the glass, now let it be placed on the
inside, as at a {Jig. 89), so that it may be within one eighth of an inch of the surface.
When the crystals have fully formed, it will be discovered that the ring has exerted
the same kind of protecting agency that it did when on the outside of the glass.

484. Hitherto, a class of bodies has been tried as protectors which are without ex-

IS THE SURFACE ELECTRIFIED? 227

ception sood conductors of electricity, such as the metals. Certain indications led me
to make trial of resinous matters, which are non-conductors of electricity. Having
made the region about a (Jig. 86) of the air-pump jar very warm, over a spirit lamp,
a ring of rosin was spread on it, about the same size as the ring of tin foil which had
been formerly there. This ring of rosin was transparent, admitting the light to pass it
readily, and at a certain distance appeared of an amber colour. Having arranged the
jar as usual, and exposed it to the sun, after a certain length of time well-marked crys-
tals were deposited on the perihelion side, on which the rosin was ; these crystals not
only came up to the verge of the rosin, and filled also the inner circle, but were found
on the rosin itself.

4S5. Metallic plates of various shapes, and under various circumstances, were ex-
posed with a view of causing condensation upon them ; it was not found possible,
however, either to cause the formation of aqueous dew or crystalline deposite, except
when their temperature was below that of the medium in which they were exposed.

486. At this stage of the inquiry it becomes important to know whether, along with
the rays of light, of heat, and of chemical action, there are not also rays of radiant
electricitv emitted by the sun. Almost all operations which disturb the equilibrium of
light and heat, disturb too that of electricity, and it is well known that upon this fact
Dr. Hark founds the explanation of the action of certain voltaic arrangements, espe-
cially the calorimotor ; an explanation the correctness of which later researches make
more probable. If light, heat, and electricity are set in motion by the force of chemical
action, and are often found coexisting, there is nothing improbable in meeting them to-
gether in the case before us. It is very true that, as yet, we have not met with any
example of electricity under what we understand as a radiant form, but that it consists
of undulations of an elastic medium, like the undulations of light and heat, is not to be
doubted. The experiments of Nobili give proof of an interterence, analogous to the
interference of the rays of hght, which has served so well to refer the motions of that
fluid to the undulations of an elastic medium ; the analogies of light and heat are every-
where kept up, and we look with confidence that they will be extended hereafter to
electricity.

457. The tendency of the experiments here communicated is to show^ that certain
substances, conductors of electricity, have the faculty of depriving glass of that power by
which it causes the condensation of vapours upon it when exposed to the sun ; tliat
deposition will not take place on metaUic surfaces, but that certain vitreous and resinous
bodies interfere in no manner with the process. The inference appears obvious, that
electricity, brought into play in some unusual manner, is the cause of the phenomenon.

458. By the action of the solar ray electricity of high tension can be developed. A
copper electrical condenser was taken, the plates of which were about one fortieth of
an inch apart, and six inches in diameter ; there was nothing more in their construc-
tion than is met with in the usual arrangement Another condenser was also pro-
vided, which was connected with a gold-leaf electrometer, the plates being one inch in
diameter, and separated from each other by a very thin coat of gum-lac varnish. Trials
were repeatedly made to discover whether the apparatus w as trustw orthy. It is a com-

128 IS THE SUHFACE ELECTRIFIED 1

mon complaint against instruments intended to indicate low charges of electricity, that
they furnish evidence of an accumulation whefl none has heeu communicated ; it is
necessary, therefore, to examine an instrument to be certain that this objection cannot
be preferred against it. Having obtained this preliminary evidence in a satisfactory
manner, and having decided the effectual goodness of the instruments in other partic-
ulars, the following trial was made. The six-inch condenser was exposed to the sun-
beam for one hour, on a clear, bright day ; the charged plate was then parted and ap-
plied to the one-inch condenser ; the plates of this being parted, a small but perfectly
distinct electric action was obtained. This experiment is not, however, devoid of sources
of error, as from the friction occasioned by touching the plate of one condenser with the
plate of the other, or the heating action of the ray, which might cause currents of air
to brush over it; but it was found, by purposely rubbing one plate of the condenser
on the other, that no charge of electricity could be produced, even if the friction
were continued during some time ; and on maintaining the temperature of the condenser
at the same point to which it was brought by the sunbeam, in order to produce like
currents of air, no divergence whatever of the gold leaves was produced.

489. When the tension of electricity is high, one of the most delicate methods of
detecting its presence is by the light it emits in vacuo ; the excitation caused by the
tremulous motion of a column of mercury in a barometer tube is rendered visible by
the bright light it gives out, when no other method could discover it. On this princi-
ple, attempts were made to detect electrical action in the sunbeam, by exposing metallic
plates of large dimensions to the ray, and causing any electricity they might gather to
give out light in the vacuum ; these trials did not prove satisfactory.

490. It has been stated (439), that the cloud which rises from phosphorus, when
slowly oxidating, is endowed with great mobiUty; for certain purposes it makes a very
good electroscope. When a piece of phosphorus is shielded from the air by a bell jar,
and not exposed to disturbing action of any kind, a fine sheet of vapour rises vertically
upward. If, at a distance of several feet, an excited stick of wax be presented, the
vapour curls from its path, and leans over to the side of the glass adjacent to the cause
of the disturbance. If such a jar be exposed to the sun, a hke disturbance is exhib-
ited : as soon as the rays fall on it, it seems as though they caused each particle to
repel its fellows; the straight column, which before passed to the top of the jar, separ-
ates into confused masses, which pass forward to the perihelion side.

491. No direct proof existing that rays of electricity are emitted by the sun, and as
it does not fall within my purpose to discuss their hypothetical action, it may be suffi-
cient to give the proof, that if the surface be admitted to be electrified, these deposites
should take place. If a receiver be taken, and on any part of its interior surface a
glass rod be made to pass, the fine which it describes will be stellated with camphor
crystals, on exposure to the sun after exhaustion. This curious fact was first observed
in the case of an exhausted vessel, which had a small siphon gauge shut up in it, the
extremity of which rested against the glass ; by accident the gauge was moved half
round the glass, and in a short time after a line of crystals was observed coinciding
with the line of motion ; it was found possible afterward to repeat this result at pleas-
ure; the appearances were such as are represented in Jig. 90.

ACTION OF ABSORBENT MEDIA. 129

492. Upon the hypothesis here assumed, the deposite of crystals becomes a phenom-
enon analogous to the curious configurations described by Lichtenburg, when powders
are dusted on the surface of an electrified plate ; so close is the resemblance, that one
who sees crystallization produced by the sun for the first time, would be led, almost
involuntarily, to refer both to the same cause; suppose it granted, that when light falls on
any surface, that surface is electrified, it will exert an attraction on any particle in its vi-
cinity ; but if a conducting substance be placed in contact with the surface, not only will
it hinder deposite on the place which it occupies, but also it will rob the glass around
it for some distance ; here we find an explanation of the action of a tin foil ring.
Again, if that conducting substance be so placed as to cast its shadow on the glass, no
deposite should take place on that shadow, nor for a certain distance around it, becanse
the electricity of the adjacent parts would pass towards the unelectrified spaces, thus
conferring, by a surface conduction, a low charge to all tlie shaded parts.

493. We meet, however, if we pass beyond these simple explanations, with so many
difficulties, that we are not encouraged to seek farther confirmation of this hypothesis ;
there are some facts which prove, almost demonstratively, that electricity is not the agent
in question. If, instead of a ring of rosin, we make use of a ring of sealing-wax or a
ring of pitch, these, though they are non-conductors, do not fail to protect ; the action
of a metallic ring, when placed inside of a jar, cannot, so far as I know, receive any ex-
planation, especially if we are to admit the non-conducting power of a space filled with
camphor vapour only. It is plain and obvious that transparency and opacit}' have no-
thins to do with it ; glass and rosin, it is true, do not protect ; but oil, which is equally
transparent, protects as powerfiilly as a metal.

494. Are we to refer this singular action to the rays of light, to the rays of heat, or
to the chemical rays ! By the action of absorbent media, attempts have been made to
determine this question. A barometer tube {/ de,fig. 91) had a conical tube fixed on
its outside, so that the interstice could contain liquids at c d, w ithout leaking. Into this
torricellian vacuum I passed a piece of camphor, and exposed the arrangement to the
sun ; having filled the interstice with water, it was found to have cr3stals on the aphe-
lion side, there being a ring of them, as at « e, fig. 92, all round the tube. The water
was then poured out, and a solution of sulphate of copper and ammonia introduced. On
examination, it was found that on the side nearest the sun no crystals were to be seen,
but on the other side there was a dense layer of them, extending exactly half way round
the tube, and very much resembling the shape o{ Jig. 93. A yellow liquid, the bichro-
mate of potassa, w-as next introduced : a result to all appearance exactly Uke the former
was again produced; but having observed that the thickness of the media had a very
sensible effect, apparently due to their becoming warm, and not casting off their caloric
with sufficient rapidity by radiation, I made an alteration in the arrangement, by inter-
posing between the torricellian vacuum and the light a trough capable of containing the
different solutions. This trough being filled with solution of bichromate of potassa, and
the ray tested that it could not blacken chloride of silver, in about one hour the tube
presented the following appearance : there were some pretty large crystals which ex-
tended round the tube, as at a fig. 94, which, on the aphelion side, suddenly mounted

11

130 CAUSE OF THE GREEN COLOUR OF PLANTS.

up, froming a kind of hyperbola; on the anterior senii-circuuiference not a solitary one
was to be seen. The trough being now filled with sulphate of copper and ammonia^
the arrangement of the crystals was found to be in every respect like the former. ;

495. Supposing that this result might in some measure depend on the ray having
been subjected to reflexion before passing through the trough, I repeated the trials when
the sun's altitude was small enough to permit the rays to pass without requiring reflexr
ion, yet still the same results were uniformly obtained ; so that, whether the chemical
or the calorific rays were stopped, crystallization took place on the aphelion side of the
tube.

496. May it not, therefore, be that this attractive force originates whenever the cal-
orific ray impinges on a surface 1 It does not necessarily follow from the phenomena
that any peculiar class of rays is emitted by the sun, which bring about this action ; but
if there are such, it is a question of interest to find what is the reason that good con-
ductors of electricity render their action nugatory.

497. Botanical authors have long been aware of the important effects which solar
radiations exercise over the colour of vegetables. A plant which grows in the dark is
of a pale wliitish colour, and of a transparent aspect, possessing none of that greenness
and vigour which are so characteristically developed on exposure to the sun ; its consist-
ency is watery, and although its growth may not be stunted, its appearance is very
sickly, its secretory actions are not duly performed, and all its vital operations are car-
ried on in a depressed way. There is no longer any evolution of nitrogen from the
leaves, and, consequently, no apparent production of oxygen gas. Light, which seems
to act merely as a stimulus on the green organs of vegetables, indirectly bringing about
the decomposition of carbonic acid, though accessory,is not, however, essential to growth.
In subterranean cavities, and places far removed from the direct solar ray, plants have
a colour of their own ; and in the abysses of the ocean, at depths to which no solar
beam can penetrate, and where there is a perpetual night, they are found flourishing.

498. The green colour of leaves is presumed to be an immediate consequence of the
act of decomposing carbonic acid. It appears to me that there is some obscurity, if not
an actual error, in the view which botanists take of this matter. They suppose that,
by the stimulus of light, some portion of the green matter is enabled to decompose that
gas completely, or to accomplish its actual resolution into an equivalent volume of oxy-
gen, with the entire deposition of the carbon in the solid form ; that it is, moreover,
this carbon, so deposited, that gives origin to the green colour, seeing it forms the chro-
mule verte itself. Much useless ingenuity has been thrown away by some chemists in
explaining how carbon, the colour of which is black or a deep blue, can produce a lively
green; and even if their supposition that the modifying action of a yellow tissue spread
over it were correct, of which there is much doubt, considering the thinness of that
tissue and the lightness of its tint, yet certainly we have no necessity to resort to any
such explanation. The deposite is not carbon chemically; it contains both oxygen and
hydrogen in unknown proportions. Of all the physical characteristics of a body, col-
our is the most uncertain: after uniting in a new mode, compounds never bear the col-
ours of their constituents ; nay, more, carbon itself is not essentially of a black colour,
as the diamond proves.

PLANTS GROW IN LiGHTS OF VARIOUS COLOURS.

131

499. To a deposits of some compound, in which carbon enters as an ingredient, we
are to refer the green colour of leaves, but not to carbon itself. The earlier chemists,
who did not possess those extremely delicate methods of gas analysis which are now
available, misunderstood this matter. They stated that, on exposing a plant to the sun-
shine, in contact with carbonic acid, the carbon was separated in a concrete state, the
oxygen being left, but such is not the fact ; by no known laws can such a change be
brought about, and hence any reasoning based upon it, as to the colour of plants, is ir-
relevant. For when a plant exposed to the sun decomposes carbonic acid, a certain
volume of oxygen disappears at the same time ; in lieu of this, and in obedience to the
laws which guide the transit of gases through tissues, an equivalent volume of nitrogen
is surrendered by the plant in return. Sometimes it is carbonic oxide which is absorbed,
sometimes oxalic acid, or other compound of carbon with less proportion of oxygen. I
do not here indicate from whence that nitrogen is derived, since botanists assert that
some plants contain no nitrogen at all; it may, however, exist in their juices as gas ex-
ists in spring water, or may be retained in a compressed state on their surfaces ; it is,
however, a remarkable fact that nitrogen is always present.

500. The carbon thus taken from the acid does not pass through the tissue of the
leaf in a concrete form, or give rise to a concrete deposite; it bears with it a certain part
of the oxygen with which it was formerly united, the rest being set free ; the carbon
and oxygen so conveyed into the plant, entering into combination with hydrogen, give
rise to the chromule verte; hence we see that the green colour depends indirectly on
the decomposing action; that when this goes on without interruption, that is fully de-
veloped.

601. I took five pea plants out of the garden, as nearly resembhng each other in size
and other particulars as might be: they had just appeared above the surface of the
earth, and were beginning to put out leaves. These plants I designate by the numbers
1, 2, 3, 4, 5. Each one was planted in a small glass vessel with a hole in the bottom,
for the purpose of supplying it with water, after the manner of a common flower-pot.
Number 1 was-placed in a box into which light passed which had traversed a solution
of sulphate of copper and ammonia. No. 2, in a similar box, into which light was ad-
mitted after having undergone the action of chromate of potassa. No. 3 was placed in
the open air. No. 4, in a box into which light had passed which had been transmitted
through sulphocyanate of iron. No. 5 was shut up in a dark closet. This arrange-
ment was completed on the second day of May. With a pair of compasses the height
of each plant was ascertained, and of that and of the number of leaves a memorandum
was taken. In three days' time an examination was made.

No. 1 had attained three times its former height, and doubled its number of leaves.

No. 2, not quite twice its former height, no new leaves, in appearance not so plump
and transparent as formerly.

No. 3, twice its former size, with no fresh leaves.

No. 4, four and a half times its former size, and double its number of leaves.

No. 5, three and a half times its former size ; the leaves looked yellowish.

502. It is here proper to remark, that the increase of size is not to be taken as an

232 SEEDS ALSO GERMINATE IN RED, YELLOW, AND BLUE LIGHT.

index of any action of the absorbing medium. Some years ago, I had occasion to no-
tice that rapidity of growth was greatly influenced by the quantity of aqueous gas in
the atmosphere. Whether the observation possesses any novelty, I am not prepared
to say ; but if any one causes plants to grow in glass vessels containing the maximum
quantity of vapour which the atmosphere can hold at the temperatures under trial, tlieir
unusual increase in dimensions will present a strikingly remarkable phenomenon.

•503. In fourteen days from the commencement of this experiment another examina-
tion was made.

No. 1, all its leaves of a grass green.

No. 2, of a darker green.

No. 3, green, but of a bluish tint when compared with a plant taken from the garden.

No. 4, of a bright green.

No. 5, pale whitish yellow, with no fresh leaves, but grown to thirteen times its for-
mer height, and apparently in a vigorous condition.

With respect to No. 4, the plant under sulphocyanate of iron, I was not aware, at
the time of making this trial, of the singular properties of that substance in relation
to light ; in the course of a fortnight, which had elapsed, the solution, from being of a
deep blood red, had become perfectly colourless. No reliance is, therefore, to be placed
on this result.

504. Among a number of experiments which were instituted with an intention of
illustrating the same point, and which gave analogous results, it may be mentioned that
the seeds of common garden cress were caused to germinate and grow in the boxes
mentioned above ; and no matter what was the substance through which the light
passed, the young plants, after reaching a certain size, were always green, but those
which grew in the dark had yellow leaves and white stalks.

505. The general result of these trials goes to prove that it is not this or that species
of ray which gives rise to the colour of leaves ; the absence of the chemical ray, or
of the calorific ray, does not appear to affect it, nor have we any direct proof that the
calorific ray exercises any influence. Humboldt has stated that in the mines of Ger-
many, plants, as the poa annua, et co?npressa, jjlantago lanceolata, &c., grow in recesses
where the sun's light never comes, and, provided hydrogen gas be present, their colour
is green. In the Atlantic Ocean he saw a marine p\aut,fucus vitifolius, brought up from
the depth of 190 French feet, where, according to the calculations of Bouguer, the
light was only equal to that emitted from a candle at 203 feet distance, and yet its
colour was green. Decandolle mentions that artificial light, as that of lamps, gives
the same result ; a proof that it is certainly not the chemical, and, perhaps, not the
calorific rays, which cause the phenomenon.

506. Perhaps light, in this case, acts only as a kind of stimulus ; it would be desirable
to make trial of some plants whose leaves are naturally white ; of this class there are
several individuals ; would they or would they not cause the decomposition of carbonic
acid \ From many indications, it is not improbable that there is a variety of chemi-
cal rays, each of which brings about changes of a character appropriate to itself. As
yet we have not learned to distinguish these from each other, and are not provided with

ACTION OF ABSORBENT MEDIA AND IDEAL COLORATION. X33

the means of effecting their separation. A remarkable obserration, which appears to me
to be very much in point, was made many years ago by Professor Silliman ; it has not
obtained that attention which it deserves ; he states, that on exposure of a mixture of
chlorine and hydrogen to the light of a fire, an explosion was produced. I quote the
fact, however, only from memory, and have endeavoured to substantiate it under a
variety of circumstances, but with a want of success probably due to the absorbing ac-
tion of the glass jars used, or to the nature of the hght It is desirable that this experi-
ment should be once more repeated ; it would settle an important point — that chemical
ravs of different characters exist. I have referred to this before, for it is more than
probable that there are chemical rays not absorbable by the chromates of potassa.

Note added to the foregoing Chapter.

{Being a Letter (• Ike Editor* of tke London omd Edinburgk Pkilosopkiail Magazine, imtertei im llul Journal February, 1840.)

AN ACCOUNT OF SOME EXPERIMENTS MADE IN THE SOUTH OF VIRGINIA ON THE LIGHT

OF THE SUN.

507. Gentlemen — I have just seen in die Journals for the current month a letter
from Sir J. Herschel to the British Association for the Advancement of Science, in
reference to some remarkable actions of the different colours of the solar spectrum.

508. About five years ago, having the advantage of a bright and almost tropical sky,
I amused myself with attempting a repetition of Morichini's experiment for the magnet-
izing of steel, and was led to some results in respect to the chemical action of the
sun's rays, which appear to bear very much on the subject of the letter above alluded
to. Most of these have been published in the Journal of the Franklin Institute of Phil-
adelphia; but as they do not appear to have been noticed in England, I will ask the
favour of a page or two of your excellent Magazine, to give my testimony on a subject
which now appears to excite so much interest

509. If you pass a beam of the sun's light through a solution of chromate of po-
tassa, it can no longer blacken a piece of sensitive paper ; if you converge the light
which has thus passed through a stratum of this fluid, by means of a lens, chloride of
silver will remain for a long time, without much change, in the focus.

510. The list which was published in the Journal above named of solutions pos-
sessing this power, is as follows:

Bichromate of potassa. Muriate of iron.

Chromate of potassa. Chloride of gold.

Yellow hydro-sulphuret of ammonia. Chloride of platinum.
Hydro-sulphuret of lime.

511. It is to be remarked, that every one of these solutions is yellotc, but I also found
that a great many vegetable coloured infusions would, in like manner, absorb the chem-
ical rays, especially those which have a yellow tint.

512. When I exposed pieces of paper covered with a layer of chloride of silver

J34 PERIHELION MOTIONS.

to a beam which had passed through the red sulpho-cyanate of iron, the paper became
of a brick-red colour ; if to a beam which had passed through a solution of sulphate of
copper and ammonia, it became of a blue -brown; and, lastly, on exposing a piece in a
box, which I shall presently mention, for five days, to Hght which had been acted on by
bichromate of potassa, it became perceptibly of a faint yellowish green.

513. It is very probable that there exist in the sunlight, rays having particular chem-
ical powers.

514. A beam which has passed through bichromate of potassa does not appear to
cause the union of a mixture of chlorine and hydrogen. I kept such a mixture for
several hours in it, and could not perceive any change.

615. But this same beam can, nevertheless, enable vegetable leaves to effect the de-
composition of carbonic acid. I took a wooden box, about a cubic foot in dimensions,
and having removed its bottom, replaced it with a pair of parallel plates of glass, so ad-
justed that there was an interstice between them of half an inch, or thereabout. Into
the trough thus formed I poured a solution of bichromate of potassa, or any other salt
under trial, and the box being raised on one end, served as a closet in which bodies
could be exposed to the action of beams that had passed through any given medium.

516. In this little chamber, its trough being filled with a solution of the bichromate,
I placed a matrass containing water slightly impregnated with carbonic acid, and a
few vegetable leaves ; after a little while, air bubbles were copiously given off ; there
had been placed, similar in all respects, another, matrass in the direct rays of the sun,
and when a quantity of gas sufficient for analysis was evolved, it was found that car-
bonic acid had in both cases been decomposed, though, as might have been expected,
in the latter more energetically. The result gave a mixture of carbonic acid, oxygen,
and nitrogen : the uniform appearance of this latter body was subsequently traced to
the leaves employed.

517. Plants also become green in light that has been submitted to the action of these
yellow salts, and, therefore, deprived of the rays that blacken chloride of silver. I took a
number of pea plants out of the garden, in May, 1837, and caused them to vegetate in
light modified in this way, and also in light which had passed through sulpho-cyanate
of iron, and sulphate of copper and ammonia, &c., but in every instance the leaves
became green. It may also be mentioned that seeds of common cress were caused to
germinate and grow under these circumstances ; the young plants, after reaching a cer-
tain size, were always green, but those which had grown in the dark had yellow leaves
and white stalks.

518. Professor Silliman states, in one of the early numbers of his Journal, that he
witnessed an explosion of hydrogen and chlorine caused by the light of a common fire.

519. RiTTER was the first who asserted that the opposite extremities of the spectrum
possess opposite powers of chemical action ; he states that phosphorus will emit fumes
in the red ray, but if the violet be thrown on it, it ceases to smoke ; this experiment I
repeated often, and under favourable circumstances, but could not make it succeed.

520. I could succeed, however, in showing very beautifully the interference of that
class of chemical rays which blacken chloride and bromide of silver, but failed in trying

THESE PHENOMENA PROBABLY DUE TO RADIANT HEAT. 235

to produce their polarization for want of proper apparatus. An electric current circu-
lating in a wire does not seem to have amy influence on these chemical rays ; I found
that the same neat magnified image of the wire was obtained on chloride paper when
it was placed in a beam diverging from a lens, whether the current was made to pass
or was stopped,

521. So much for chemical actions: let me now ask your attention to a mechanical
result of solar light, which is very curious.

(a.) Having made a large air-pump jar very clean and dry, place a few pieces of
camphor on the plate of the pump, and exhaust. Carry the pump with its receiver into
the sunshine, and very soon you will see all that side which is nearest to the sun cov-
ered with crystals, but there will be few or none on tbe side which is farthest from him.
With the brilliant sun of Virginia I have seen this eflfect take place, and beautiful stel-
lated crystals appear in /our minutes, Uterally covering the whole of the upper parts
of the jar nearest the sun.

(6.) Or make a tube of half an inch or more in diameter, and upward of thirty
inches long, a torricellian vacuum ; pass up through the mercury a fragment of cam-
phor. The tube may now be kept for any length of time in the dark without anything
happening ; but bring it into the beams of the sun, and in a few minutes crystallization
will happen on the side next the luminary.

(c.) Again, paste on the inside of an air-pump jar a piece of tin foil an inch in diam-
eter, and having operated as in experiment {a), expose this side towards the sun.
Crystals will soon form, but the tin foil will protect the glass in its vicinity, and none
will be found within a certain space round the metallic circle.

(</.) Crystallization is not necessarily connected with these results: the vapour of
mercury in a torricellian void is condensed towards the light ; so, also, the dew which
settles on the inside of a jar containing water is always on the side nearest the window.
The rays of the sun have also the power of decomposing a solution of chloride of gold:
the metalline spangles are deposited on that side of the glass which is nearest to the light

Artificial light gives none of these results.

(e.) Having removed the piece of tin foil used in experiment (c), place it on a little
stand in front of the receiver; it will hinder the crystaUization taking place in the
parts on which its shadow is cast, and also for a certain space in the vicinity.

(J".) Take a jar that has already been coated with crystals, place the tin foil before
it, and it will remove all those crystals which are within its shadow.

(^.) Instead of using a piece of tin foil, as in experiment (c), make the receiver hot,
and rub upon it a piece of resin, so as to leave a transparent circle of that substance ;
expose to the light, and it will be found that the resin cannot protect the glass.

(A.) If along the inside surface of a vessel about to be exposed to the sun a glass
rod be rubbed, rows of crystals will be deposited on the lines which were described by the
end of the rod, but the vessel must be very dry for this experiment to succeed.

522. Now can we explain these singular results on any other known principle than
this : That the side of the jar nearest the sun radiates fi-eely the heat that it receives,
back again, while radiation is interfered with at the other side ; that, in point of fact,
the anterior side is the colder, and the other the hotter ?

136 HISTORICAL NOTE.

CHAPTER XL

ON THE PROCESS OF DAGUERREOTYPE, AND ITS APPLICATION TO TAKING PORTRAITS

FROM THE LIFE.

Historical Note. — This chapter contains the first published description of the process
of taking Daguerreotype portraits. Of late, both in America and in Europe, this art
has been much cultivated and improved ; it now forms a branch of industrial occupa-
tion. That it was possible by photogenic processes, such as the Daguerreotype, to ob-
tain likenesses from the life, was first announced by the author of this volume in a note
to the editors of the Philosophical Magazine, dated March 31st, 1840, as may be seen
in that Journal, June, 1840, page 535. The first Daguerreotype portraits to which al-
lusion is made in the following chapter (523) were produced in 1839, almost immedi-
ately after M. Daguerre's discovery was known in America.

It may farther be remarked, that of those spectral images which have excited so much
attention of late in Europe, under the name of Moser's images, an account is here
given, and given in connexion with the explanation of the Daguerreotype (527-544).
A successful attempt was made in Germany, in 1842, to appropriate the discovery of
these singular phenomena by the natural philosopher whose name now stands in con-
nexion with them.

Of these two incidents in the science of photography, some account may be seen in
the Edinburgh Review for January, 1843. In that work, the discovery of the art of
taking Daguerreotype portraits, and the first observations on spectral images, are attribu-
ted to their true source, the author of this book.*

* " He was the first, we believe, who, under the brilliant summer sun of New- York, took portraits with the Daguerreotype.
This branch of photography seems not to have been regarded as a possible application of Daghekre's invention, and no notice
is taken of it in the reports made to the legislative bodies of France. We have been told that Daooeere had not, at that period,
taken any portraits ; and when we consider the period of time, twenty or twenty-five minutes, which was then deemed ne-
cessary to get a Daguerreotype landscape, we do not wonder at the observation of a French author, who describes the taking
of portraits as loujours un terrain un peu fabuUux pour le Daguerreotype. Dagderre, however, and his countryman, M. Claddet,
have nobly earned the reputation of having perfected this branch of the art.

" It has been long known that if we write upon a piece of glass with a pencil of soapstone or agalmatolite, the written let-
ters, though wholly invisible, may be read by simply breathing upon the glass ; and this even though the surface has been
well cleaned after the letters had been written. Dr. Draper observed that if a piece of metal, a shilling, for example, or even
a wafer, is laid upon a cool surface of glass or polished metal, and the glass or metal breathed upon, then, if the sliilling is
tossed from the surface, and the vapour dried up spontaneously, a spectral image of the shilling will be seen by breathing
again upon the surface, the vapour dopositmg itself in a different manner upon the part previously protected by the shilling.
More recently, Professor Draper has shown that this spectral image could be revived during a period of several months of
the cold weather in the winter of 1840-41 ; but he has stated that he cannot find the reason of this result, though he regards
it as analogous to the deposition of mercurial vapour in the Daguerreotype. We have often repeated this interesting exper-
iment by keeping the protecting body, the shilling or wafer, at a distance from the glass or metallic surface, or by putting it
under a watch-glass ; and we found that the result was always the same (even after cleaning the surface with soft leather),
so that change of temperature, or any pressure upon the glass surface, were excluded as causes of the phenomena." — (^Ex-
tract from the Edinburgh Review for January, 1843, p. 339.)

DAGUERREOTYPE PORTRAITS FROM THE LIFE RRST TAKEN. 137

(From the London and Edinburgh Philosophical Magazine for Seftembtr, 1840.)

Contents : Daguerreotype Portraits from the Life first taken. — Spectral Images. —
Presertation of the Sensitive Plate increases the Sensitiveness. — Modifications in the
Daguerreotype Process. — Moonlight, Artificial Light, and Drummonds Light, are
all active. — Description of the original Process of taking Portraits from the Life.

523. Very soon after M. Dagoerre's remarkable process for photogenic drawing was
known in America, I made attempts to accomplish its application to the execution of
portraits from the life. M. Arago had already stated, in his address to the Chamber
of Deputies, that M. Daguerre expected, by a slight advance, to meet with success, bat
as yet no account has reached us of that object being attained.

524. More than one hundred instances are recorded in Berzei.ius's chemistry, in
which the agency of light brings about changes in bodies ; these are of all kinds : for-
mations of new compounds, rearrangements of elements already in union, changes of
crystallographic character, decompositions, and mechanical modifications.

525. The process of the Daguerreotype is to expose a surface of pure silver to the
action of the vapour of iodine, so as to give rise to a peculiar iodide of silver, which,
under certain circumstances, is exceedingly sensitive to light. The different operations
of polishing, washing with nitric acid, exposure to heat, &c., are only to offer a pure
silver surface ; the operation of hyposulphite of soda, and the process, which I shall
presently describe, of galvanization, are to free the plate from its sensitive coating, and
in nowise affect the depth of the shadows, as some of the French chemists at first
supposed.

526. There is but one part of the Daguerreotype which does not yield to theory :
on one point alone there is obscurity. Why does the vapour of mercury condense in
a white form on those portions of the film of iodide which have been exposed to the
influence of light ? condense to an amount which is rigidly proportional to the quantity
of incident light \

527. Even on this point there are facts which appear to have a bearing

(«.) It has long been known that if a piece of soapstone or agalmatoUte be made use
of as a pencil to write with on glass, though the letters that may have been formed are
invisible, and though the surface of the glass may subsequently have been well cleaned,
yet they will come into view as soon as the glass is breathed on.

(5.) I have often noticed that if a piece of very clear and cool glass, or, what is bet-
ter, a cold polished metallic reflector, has a little object, such as a piece of metal, laid
upon it, and the surface be breathed over once, the object being then carefully removed, as
often as you breathe again on the surface, a spectral image of it may be seen, and this
singular phenomenon may be exhibited for many days after the first trial was made.

(c.) Again, in the common experiment of engraving on glass by hydrofluoric acid,
if the vapour has been very weak, no traces will be perceived on the glass after the
wax has been removed ; but, on breathing over it, the moistiu"e condenses in such a
way as to bring all the object into view.

(d^ In (491), (521) I have described a phenomenon which relates to the crystalli-

S

138 PRESERVATION OF THE SENSITIVE PLATE INCREASES ITS SENSITIVENESS.

zation of camphor on surfaces of dry glass, on which invisible traces have been made
by the pressure of a glass rod ; this also appears to belong to the same class of effects.

528. Berzelius (Traite, vol. ii., p. 186) has attempted to explain (a) and (c) on
this principle, that the changed and unchanged surfaces radiate heat unequally. There
may be strong doubts with some as to the correctness of this, but is not the Daguerre-
otype due to the same cause, whatever it may be ?

529. We must separate carefully the chemical changes which iodide of silver under-
goes in the sunbeam from the mechanical changes which happen to the sensitive film :
iodide of silver turns black in the solar ray ; the whole success of the Daguerreotype
artist depends on his checking the process before that change shall have supervened.

530. The coating of iodine is not immediately necessary to the production of im-
ages by the mercurial vapour. The condition seems to be traceable to the metallic
surface. If you take a Daguerreotype, clean off the mercury, polish the plate thor-
oughly with rottenstone, wash it with nitric acid, and bring it to a brilliant surface, yet,
if it has not been exposed to heat, the original picture will reappear on exposure to the
mercurial vapour. Is not this a result of the same kind as those just referred to ?

531. As a polishing material for the Daguerreotype plate, common rottenstone and
oil answer very well. The plate having been planished by the workman, is to be rub-
bed down to a good surface, and as high a polish given to it as possible ; it is to be
heated and washed with nitric acid, as indicated in the French account, and finished
by being rubbed with whiting (creta prceparata), in the state of a very dry powder, go-
ing over it for the last time with a piece of clean dry cotton ; this gives an intensely
black lustre, which cannot be obtained by rottenstone alone, and thoroughly removes
any film which nitric acid may have left.

532. To coat with iodine, I make use of a box about two inches deep, in the bottom of
which that substance in coarse flakes is deposited ; no cloth intervenes, but the silvered
plate, with a temporary handle attached to it, is brought within half an inch of the
crystals, and it becomes perfectly coated in the course of from one to three minutes ; no
metallic strips are necessary to ensure this effect; if the edges and corners are thor-
oughly clean, the golden hue will appear uniformly.

533. M. Daguerre recommends that the plate, after being iodized, shall be placed
in the camera without loss of time. The longest interval, he says, ought not to exceed
an hour. " Beyond this space the action of the iodine and silver no longer possesses
the requisite photogenic properties."

534. There may be something peculiar in the preparation of the plate as I have de-
scribed it, but it is certain that this observation must be received with some limitation.
A plate which has been iodized does not appear so quickly to lose its sensitiveness.
On the other hand, by keeping it in the dark for twelve or twenty-four hours, its sen-
sitiveness is often remarkably increased. Other advantages also accrue. Those who
have made many of these photogenic experiments, will have had frequent occasion to
remark that the film of iodine is not equally sensitive all over; that there are spots or
cloudy places which do not evolve any impression ; and often the whole is in that
condition, that the bright parts alone come out, while the parts that are in shadow

MODIFICATIONS IN THE DAGUERREOTYPE. 139

do not evolve corresponding!}', nor can they be well developed, except at the risk of
solarizing the picture. Now a plate that has been kept for several hours is by no
means so Uable to these effects : I do not pretend to give any reason for this, but
merely mention it as a fact of considerable importance to the travelling Daguerreotyper;
he will find that the iodine does not lose its sensitiveness in many days.

535. In a paper read before the Royal Society, of which an abstract is given in the
April number of this Journal for the present year (p. 333), Sir John Herschel, states
that there is an absolute necessity of a perfect achromaticity in the object-glass of a
photographic camera. M. Daguerre appears to have been under the same impression,
and recommends in his published account such an object-glass.

536. All the rays of light, with, perhaps, the exception of the yellow, leave an im-
pression on the iodide of silver. The less refrangible rays, however, act much more
slowly than those which are at the opposite end of the spectrum. In the common
kinds of glass, the most energetic action takes place in the indigo, or on the boundary
of the blue. Now the retina receives an impression with equal facility from each of
the different rays, the yellow hght acting as quickly upon it as the red or the blue.
\ isiou is therefore performed independently of time, the eye catching all the colours
of the spectrum with equal facility and with equal speed. But it is not so with these
photogenic preparations. In the action of light upon them, time enters as an element ;
the blue ray may have effected its full change, while the red is yet only beginning
slowly to act ; and the red may have completed its change before the yellow has made
any sensible impression. On these principles, it is plain that an achromatic object-
glass is by no means essential for the production of fine photographs ; for if the plate be
withdrawn at a certain period, when the rays that have a maximum energy have just
completed their action, those that are more dispersed, but of slower effect, will not have
had time to leave any stain. We work, in fact, with a temporary monochromatic light.

537. Upon these principles I constructed the camera which I am in the habit of using,
with a double convex non-achromatic lens. Some of the finest proofs were procured
wiib a common spectacle lens, of fourteen inches focus, arranged at the end of a cigar
box as a camera ; a lens of this diameter answers very well for plates four inches by
three, reproducing the objects with the most admirable finish ; copperplate engravings
being represented in the minutest particulars, and the marks of the tool becoming quite
distinct under the magnifier.

538. In this instance, it is true, owing to the magnitude of the focal length compared
with the aperture, but htde difficulty ensues from chromatic aberration ; but when with
the same focal length the aperture is increased to three or four inches, then the disper-
sion becomes very sensible, and yet good proofs can be procured by working in the
method here indicated, the chief difficulty then arising from spherical aberration.

539. It has already been stated that the ray of maximum action for the Daguerreo-
type, when colourless French plate-glass is used, lies probably within the indigo space;
it therefore follows that the length of the camera should be diminished, after arranging
it to the luminous focus. The importance of this is pointed out in a paper by Mr.
TowsoN, inserted in this Journal last year; I was, however, in the habit of using this

140 MODIFICATIONS IN THE DAGUERREOTYPE.

adjustment before reading the suggestions contained in that excellent communication.
The amount of shortening which sliould be given to the camera, where the lens is fif-
teen inches focus, does not commonly exceed three tenths of an inch. If the luminous
focus be used, the proof comes out indistinct.

540. In the subsequent process of mercurializing, it is of little importance what is
the angular position. Several experimenters were for a time under the idea that au
angle of 45° or 48° was a necessary inclination, in order that the plate should take the
vapour; this arose from a misinterpretation of the printed account. Plates mercurial-
ize equally well in a horizontal as in any other position ; perhaps a slight inclination
may be of advantage, in allowing the vapour to flow with uniformity over the iodized
surface, but the chief use of an angle of 45° is to allow the operator to inspect the pro-
cess through the glass.

541. Sometimes it is advantageous to heat the mercury a second time, when the
proof is not distinctly evolved at first. Indeed, it occasionally happens, that a proof
which did not evolve at all at first, will come out quite fairly on raising the tempera-
ture of the mercury again.

542. M.Daguerre recommends two methods of removing the sensitive coating from
the plate: by washes of hyposulphite of soda, and a solution of common salt. The
former answers perfectly, the second only indifferently well. There is, however, another
process, which is very simple, and has an advantage over the former of these in cheap-
ness. It adds not a little to the magic of the whole operation, in the eyes of those
who are unaccustomed to chemical results. The plate, having been dipped into cold
water, is placed in a solution of common salt, of moderate strength ; it lies without be-
ing acted upon at all ; but if it be now touched on one corner with a piece of zinc
which has been scraped bright, the yellow coat of iodide moves off' like a wave and
disappears. It is a very pretty process. The zinc and silver forming together a vol-
taic couple, with the salt water intervening, oxidation of the zinc takes place, and the
silver surface commences to evolve hydrogen gas ; while this is in a nascent condition
it decomposes the film of iodide of silver, giving rise to the production of hydriodic acid,
which is very soluble in water, and hence instantly removed.

543. This process, therefore, differs from that with hyposulphite. The latter acts
by dissolving the iodide of silver, the former by decomposing it. It is necessary not to
leave the zinc in contact too long, or it deposits stains, and in large plates the contact
should be made at the four corners successively, to avoid this accident.

544. After the proof is washed, all the defects in the preparation of the plate become
apparent. If a film of mercury has existed on it, due to its not having been burned
sufficiently long, there will be found a want of distinctness in the shadows ; or if the
plate has not been burned at all, perhaps the former impressions which have been
obtaiiied will reappear. This accident frequently happened in my earlier trials, when
care had not been taken to give a due exposure each time to the spirit flame. Spectral
appearances of former objects, on different parts of it, emerged — an interior with Paul
Pry coming out, when the camera had been pointed at a church.

545. There is no difficulty in procuring impressions of the moon by the Daguerreo-

MOONLIGHT, ARTIFICIAL LIGHT, AND DRUMMOND'S LIGHT, ARE ALL ACTIVE. 141

type, beyond that which arises from her motion. By the aid of a lens and a heli-
ostat, I caused the moonbeams to converge on a plate, the lens being three inches in
diameter. In half an hour a very strong impression was obtained. Wiih another
arrangement of lenses I obtained a stain nearly an inch in diameter, and of the general
figure of the moon, in which the places of the dark spots might be indistinctly traced.

546. An iodized plate, being exposed for fifteen seconds only close to the flame of a
gas light, was very distinctly stained; in one minute there was a very strong impression.

547. On receiving the image of a gas light, which was eight feet distant, in the ca-
mera, for half an hour, a good representation was obtained.

548. The flame of a gas lamp was arranged within a magic lantern, and a portion
of the image of a grotesque on one of the slides received on a plate; a very good
representation was procured,

549. With Drummond's light, and the rays from a lime-pea in the oxy-hydrogen
blowpipe, the same results were obtained.

550. lu the first experiments which I made for obtaining portraits from the life,
the face of the sitter was dusted with a white powder, under an idea that otherwise
no impression could be obtained. A very few trials showed the error of this ; for
even when the sun was only dimly shining, there was no difiicolty in delineating the
features.

551. When the sun, the sitter, and the camera are situated in the same vertical
plane, if a double convex non-achromatic lens of four inches diameter and fourteen
inches focus be employed, perfect miniatures can be procured, iu the open air, in a
period varying with the character of the light, from 20 to 90 seconds. The dress, also,
is admirably given, even if it should be black ; the slight diflferences of illumination are
sufficient to characterize it, as well as to show each button, button hole, and every
fold.

552. Partly owing to the intensity of such light, which cannot be endured without
a distortion of the features, but chiefly owing to the circumstance that the rays de-
scend at too great an angle, such pictures have the disadvantage of not exhibiting the
eyes with distinctness, the shadow from the eyebrows and forehead encroaching on them.

553. To procure fine proofs, the best position is to have the line joining the head of
the sitter and the camera so arranged as to make an angle with the incident rays of
less than ten degrees, so that all the space beneath the eyebrows shall be illuminated,
and a slight shadow cast from the nose. This involves obviously the use of reflecting
mirrors to direct the ray. A single mirror would answer, and would economize time,
but in practice it is often convenient to employ two : one placed, with a suitable mech-
anism, to direct the rays in vertical lines ; and the second above it, to direct them in
an invariable course towards the sitter.

554. On a bright day, and with a sensitive plate, portraits can be obtained in the
course of five or seven minutes in the diffused daylight. The advantages, however,
which might be supposed to accrue from the features being more composed, and of a
more natural aspect, are more than counterbalanced by the difficulty of retaining them
so long in one constant mode of expression.

142 ORIGINAL PROCESS

555. But in the reflected sunshine, the eye cannot support the effulgence of the rays.
It is, therefore, absolutely necessary to pass them through some blue medium, which
shall abstract from them their heat, and take away their offensive brilliancy. I have
used for this purpose blue glass, and also ammoniaco-sulphate of copper, contained in a
large trough of plate glass, the interstice being about an inch thick, and the fluid dilu-
ted to such a point as to permit the eye to bear the light, and yet to intercept no more
than was necessary. It is not requisite, when coloured glass is employed, to make use
of a large surface ; for if the camera operation be carried on until the proof almost so-
larizes, no traces can be seen in the portrait of its edges and boundaries; but if the pro-
cess is stopped at an earlier interval, there will commonly be found a stain correspond-
ing to the figure of the glass.

556 The camera I have used, though much better ones might be constructed, has
for its objective two double convex lenses, the united focus of which for parallel rays
is only eight inches ; they are four inches in diameter in the clear, and are mounted in
a barrel, in front of which the aperture is narrowed down to 3^ inches, after the man-
ner of Daguerre's.

557. The chair in which the sitter is placed has a staff at its back, terminating in
an iron ring, that supports the head, so arranged as to have motion in directions to suit
any stature and any attitude. By simply resting the back or side of the head against
this ring, it may be kept sufficiently still to allow the minutest marks on the face to be
copied. The hands should never rest on the chest, for the motion of respiration dis-
turbs them so much as to bring them out of a thick and clumsy appearance, destroying
also the representation of the veins on the back, which, if they are held motionless, are
copied with surprising beauty.

558. It has already been stated that certain pictorial advantages attend an arrange-
ment in which the light is thrown upon the face at a small angle. This also allows
us to get rid entirely of the shadow from the background, or to compose it more grace-
fully in the picture; for this, it is well that the chair should be brought forward from
the background from three to six feet.

559. Those who undertake Daguerreotype portraitures will, of course, arrange the
backgrounds of their pictures according to their own tastes. When one that is quite
uniform is desired, a blanket or a cloth of a drab colour, properly suspended, will be
found to answer very well. Attention must be paid to the tint: white, reflecting too
much light, would solarize upon the proof before the face had had time to come out, and
owing to its reflecting all the different rays, a blur or irradiation would appear on all
edges, due to chromatic aberration. It will be readily understood that if it be desired
to introduce a vase, an urn, or other ornament, it must not be arranged against the back-
ground, but brought forward until it appears perfectly distinct on the obscured glass of
the camera.

. 560. Different parts of the dress, for the same reason, require intervals, differing con-
siderably, to be fairly copied, the white parts of a costume passing on to solarization be-
fore the yellow or black parts have made any decisive representation. We have, there-
fore, to make use of temporary expedients. A person dressed in a black coat, and

FOR TAKING PORTRAITS. 143

open waistcoat of the same colour, must put on a temporary front of a drab or flesh-
colour, or by the time that his face and the fine shadows of his woollen clothing are
evolved, his shirt will be solarized, and be blue, or even black, with a white halo around
it. Where, however, the white parts of the dress do not expose much surface, or ex-
pose it obliquely, these precautions are not essential ; the white shirt collar will scarce-
ly solarize until the face is passing into the same condition.

561. Precautions of the same kind are necessary in ladies' dresses, which should not
be selected of tints contrasting strongly.

562. It will now be readily understood that the whole art of taking Daguerreotype
miniatures consists in directing an almost horizontal beam of hght, through a blue-col-
oured medium, upon the face of the sitter, who is retained in an unconstrained posture
by an appropriate but simple mechanism, at such a distance from the background, or
so arranged with respect to the camera, that his shadow shall not be copied as a part
of his body ; the aperture of the camera should be three and a half or four inches at
least ; indeed, the larger the better, if the object glass be aplanatic.

563. If two mirrors be made use of, the time actually occupied by the camera oper-
ation varies from forty seconds to two minutes, according to the intensity of the light.
If only one mirror is employed, the time is about one fourth shorter. In the direct
sunshine, and out in the open air, the time varies from under half a minute.

564. Looking-glasses which are used to direct the solar rays, after a short time
undergo a serious deterioration ; the foil assuming a dull granular aspect, and losing its
black brilliancy. Hence the time in copying becomes gradually prolonged.

565. The arrangement of the camera, above indicated, gives reversed pictures,
the right and left sides changing places. Mr. Woolcott, an ingenious mechanician
of this city, has taken out a patent for the use of an elliptical mirror for portraiture ;
it is about seven inches in aperture, and allows him to work conveniently with plates
two inches square. The concave mirror possesses this capital advantage over the
convex lens, tlmt the proof is given in its right position, that is to say, not reversed ;
but it has the serious inconveniences of limiting the size of the plate, and representing
parts that are at all distant from the centre in a very confused manner. With the lens,
plates might be worked a foot square, or even larger.

566. Miniatures procured in the manner here laid down are in most cases striking
likenesses, though not in all. They give, of course, all the individual peculiarities — a
mole, a freckle, a wart. Owing to the circumstance that yellow and yellowish browns
are long before they impress the substance of the Daguerreotype, persons whose faces
are freckled all over give rise to the most ludicrous results, a white mottled with just as
many black dots as the sitter had yellow ones. The eye appears beautifully ; the iris
with sharpness, and the white dot of light upon it, with such strength and so much of
reality and life, as to surprise those who have never before seen it Many are per-
suaded that the pencil of the painter has been secretly employed to give this finishing
touch.

144 OBJECT OF THE MEMOIR.

CHAPTER XII.

ON SOME ANALOGIES BETWEEN THE PHF.NOMENA OF THE CHEMICAL RAYS AND THOSE

OF RADIANT HEAT.

{From the London, Edinburgh, and Dublin Philosophical Magazine for September, 1841.)

Contents : Object of the Memoir. — On the Daguerreotype Process. — Chemical Consti-
tution of Daguerreotxjpe Pictures. — Spectral Images. — Film of Iodide torn off Me-
chanically.— Iodine is not evolved, hut corrodes the Plate. — The Chemical Rays are
absorbed. — The Plioto graphic Effects are transient. — The Chemical Hays are not
conducted. — They become Latent. — Optical Qualities control Chemical Action. —
The Active Rays are absorbed, and the Complementary reflected. — Relation of Op-
tical Forces and Chemical Affinities.

567. It is the object of this memoir to estabhsh some striking analogies which ex-
ist between the plieuomena of the chemical rays and those of radiant heat.

568. As most of the experimental illustrations which I shall here give depend upon
the use of M. Daguerre's preparation (though I have numerous others which serve to
extend these truths to other combinations, and which will be published in due time), I
shall also, incidentally, give what appears to be the proper theory of the Daguerreotype.

569. Without saying anything of the laws of reflexion, refraction, polarization, and
interference, to which these rays are subject, the study of which I commenced more than
five years ago on paper rendered sensitive by the bromide of silver, farther than that a
general similitude holds in all these cases between the rays of heat and the chemical
rays, I shall at present confine my observations to estabUshing the following propositions:

1st, That the chemical action produced by the rays of light depends upon the ab-
sorption of those rays by sensitive bodies ; just as an increase of temperature is pro-
duced by the absorption of those of heat.

2d. That as a body warmed by the rays of the sun gradually loses its heat by radia-
tion, or conduction, or contact with other bodies, so likewise, by some unknown pro-
cess, photographic effects produced on sensitive surfaces are only transient, and gradu-
ally disappear.

3d. That, as when rays of heat fall on a mass of ice, its temperature rises degree
by degree, until it reaches 32° Fah., and there stops, until a certain molecular change
(liquefaction) is accomplished, and after that proceeds to rise again, so, also, the chem-
ical rays impress certain changes proportional to their quantity, up to a certain point,
and there a pause ensues ; a very large amount of light being now rendered latent or
absorbed, without any indication thereof being given by the sensitive preparation (as
the heat of fluidity is latent to the thermometer), a molecular change then setting in,
the increments of the quantity of light are again indicated by changes in the sensitive
preparation.

ON THE DAGUERREOTYPE PROCESS. 245

4th. That it depends on the chemical nature of the ponderable material what rajs
shall be absorbed.

5th. That while the specific rays thns absorbed depend upon the chemical nature of
the bodv, the absolute aitumnt is regulated by its optical quaUties, such as depend on
the condition of its surfaces and interior arrangement.

6th. It will be proved from this, that the sensitiveness of any given substance de-
pends on its chemical nature and optical quahties conjointly, and that it is possible to
exalt or diminish the sensitiveness of any given chemical compound, by changing the
character of its optical relations. We shall here meet with an explanation of some of
the facts noticed by Sir J. Herschel, Mr. Hunt, Mr. Talbot, and others, respecting
the increase of sensitiveness of the chloride of silver and other bodies.

7th. That, as when radiant heat falls on the surface of an opaque body, the rays
reflected are complementary in number to those that are absorbed, so, in the case of a
sensitive preparation, the rays reflected are complementau-y in number to those that
are absorbed.

570. Of the Dagoerreotypes. — In relation to the condition of these tablets, I shall
prove the following facts :

IsL That metallic mercury exists all over the surface of an ordinary Daguerreotype,
in the shadows as well as in the Hghts ; in the shadows it is as metallic mercury, in
the lights as silver amalgam.

•2d. That in an iodized Daguerreotype, as taken from the mercury-bath, there is
no order of superposition of the parts, that is to say, the iodide is neither upan nor
beneath the mercury, but both are, as it were, in the same plane.

3d. That when a ray of light falls upon the surface of this preparation, through all
the inter\-ening steps, and up to the point of maximum action, no iodine is evolved
from the plate ; but that in the common Daguerreotype the light communicates a ten-
dency to the atoms of the iodide to yield up to the mercurial vapour their silver, while
the iodine retires and combines with the unaffected silver around. It follows that when
such a plate is withdrawn from the mercurial vapour, there is all over it a uniform film
of iodide of silver of the very same thickness as at first ; and this has happened through
a direct corrosion of the silver by the iodine, while it was undergoing ihe mercurial
operation.

571. I pass at once to the proofs of these several propositions, commencing, for the
sake of perspicuity, with those relating to the Daguerreotype first: and 1st, That me-
tallic mercury exists all over the surface, of an ordinary Daguerreotype, in the shadows
as tcell as in the lights; in the shadows it is as metallic mercury, in the lights as silver
amalgam.

572. I took a plated copper three inches by four in surface, and having prepared it
with care, I exposed half of it to the diffused light of the day, screening the other half;
it was then mercurialized at 175° Fah., the iodide removed by hyposulphite of soda
and washed. And now a plate on which a gold leaf was spread was placed over it,
but separated, as shown in fig. 94, in the points a, h, c, by three sUps of glass. By
means of a spirit-lamp the photographic plate a, b, c, was heated, and the gilded plate

T

246 SPECTRAL IMAGES.

g k kept cool, by occasionally wetting it. On parting the plates, it was perceived that
faint but distinct traces of whitening were visible all over the gold, as well on that part
which was over the whitened half of the photograph as over that which was unchanged.

573. But as it might happen that the mercury diffused itself laterally past the imper-
fect obstacle h, I made the following decisive trials :

I iodized three silver plates. A, B, C, each three inches by four in surface, conducting
the processes for each in the same way ; and having exposed each for two minutes to
a faint daylight, I laid them aside in the dark, to be presently used as test plates, in
lieu of the gilded plate g k.

Then I took three other plates, D, E, F, of the same size, and conducting the pre-
paratory processes for each as before, I iodized D in the dark, and mercurialized it
forthwith at 170° Fah., taking the utmost care that not a ray of light should be suffered
to impinge upon it.

E was iodized, and exposed for two minutes to diffused daylight, and then mercuri-
alized at 170° Fah.

F was iodized, and exposed to the sun until it began to turn brown, an effect occur-
ring ahnost at once. It was then mercurialized at 170° Fah.

All these plates then had their sensitive coating removed by hyposulphite, and were
thoroughly washed in distilled water and dried.

574. I had, therefore, three plates, representing accurately the conditions proposed
to be investigated. D was in the condition of the most perfect shadows, E in that of
the highest lights, and F solarized. In appearance D was black, E was white, and F
bluish-gray.

Upon D, E, F, I placed A, B, C, respectively, separating each pair of plates one six-
teenth of an inch, or thereabout, by slips of glass. Then I laid them on the level sur-
face of the sand-bath, the test plates being kept cool by sponging occasionally with wa-
ter. Temperature of the sand, 200° Fah. ; duration of the experiment, fifteen minutes.

On examination, A, B, C were all found powerfully mercurialized, nor did there seem
to be any difference between them.

575. I consider, therefore, that the shadows, the demitints, the lights, and the solar-
ized portions of a Daguerreotype, are covered with mercury ; for at a temperature of
200° Fah., they all evolve it alike, a sufficiency of vapour rising from the parts that
have not been exposed to the light to bring a plate that has been so exposed to its
maximum of whiteness.*

576. In (527) I described a remarkable effect which I had noticed in these investi-
gations: that if an object, such as a wafer, be laid upon a piece of cold glass or metal,
and you breathe once on it, and as soon as the moisture has disappeared, remove the
ol)ject, and breathe again on the glass, a spectral image of the wafer will make its ap-
pearance. The impression thus communicated to the surface, under certain condi-
tions, remains there for a long time. During the cold weather last winter, I produced

» I believe that the most delicate test for the presence of mercury is a slip of silver iodized to a yellow colour, and expo-
sed for two or three minutes to a weak daylight.

FILM OF IODIDE TORN OFF MECHANICALLY. 247

such an image on the mirror of mj heliostat ; it could be revived by breathing on the
metal many weeks afterward, nor did it finally disappear until the end of several months.

577. I do not at present know what is the reason of this result, but the analogy
between it and the arrangement of mercurial globules, which cover the surface of a
Daguerreotype, is too striking to be overlooked. It proves to us that surfaces may as-
sume such a condition as to affect the deposition of vapours upon them, so as to
give rise to the reproduction of appearances of external forms. I gave, therefore,
particular attention to this point, but eventually found that silver exists in an ordinary-
Daguerreotype, in connexion with the mercury, all over the plate, in a less proportion
in the shadows, and in a greater proportion in the lights. This result was, however,
only obtained after the following fact was discovered : that the mucilage of gum-arabic,
when slowly dried in a thin layer on the surface of a Daguerreotype, splits up in
shivers, bringing along with it the white portions of the picture, and leaving the plate
clean.

578. Having, therefore, prepared three plates, D, E, F, exactly as before (573), I
poured on tliem a solution of gum, drained them so as to leave only a small quantity,
and let them dry slowly over the sand-bath. The gum separated readily, and la}' in
chips on the surface of each plate; it was easily removed to three sheets of paper,
by tapping with the finger on the back of the plate. Each was then treated alike, as
follows :

579. The gummy matter was incinerated on a platinum leaf, and the remaining
ashes transferred to a test tube, half an inch in diameter. One drop of nitric acid
and one drop of water were added ; it was boiled over a small flame, and diluted
with a little water. Dilute muriatic acid was now added, and the chloride of silver
immediately fell. In repeating this, it is necessary to attend to the state of dilation of
the acid, for if too strong, it wholly dissolves the minute quantity of chloride of silver
generated.

580. As, from the minuteness of that quantity, it was impossible to obtain a direct
quantitative analysis, I adopted the foregoing method, and added the dilute acid to all
three tubes at the same time. In D there was a faint opalescence, in E and F a cloud ;
but I could not always determine whether the deposite of E or F was most copious,
sometimes the one and sometimes the other appearing to have a slight advantage.

581. I conclude, therefore, that while the whole surface of the plate is coated with
mercury, it exists as silver amalgam chiefly in the lights, and as uncombined mercury
chiefly in the shadows, and in a mixed proportion in the demitints ; and that when a
plate is solarized, both free mercury and amalgam are present.

582. Such is the state of surface in a Daguerreotype recently formed. In the course
of time, however, a great portion of the mercury that is in the shadows, and also free
in the lights, evaporates away. When the picture has thus changed, the shadows are
metallic silver, and the lights silver amalgam.

583. 2d. That in an iodized Daguerreotype, as taken from the mercury-bath, there
is no order of superposition of the parts, that is to say, the iodide is neither upon
nor beneath the mercury, but both are, as it were, in the same plane.

248 IODINE IS NOT EVOLVED, BUT CORRODES THE PLATE.

Soon after I had ascertained the action of gum-arabic, some of it was applied to the
surface of a plate on which an impression had just been formed in the mercury-
bath. This was without removing the coat of iodine. On drying it, the gum chipped
up, as was expected, bringing away with it all the lights of the picture, and leaving
a uniform coat of yellow iodide of silver beneath. It seems, therefore, that the film
of iodide coheres more strongly to the metal plate than the amalgam ; and, farther,
from this result we should judge that the amalgam is on the surface of the iodide.

584. But this is not true ; for on three different occasions I have found that when
Russian isinglass was employed instead of gum, for purposes presently to be related
(591), the isinglass, from its stronger cohesive power, chipped off in the act of drying,
tearing up the yellow film from end to end of the plate, and leaving the amalgam,
constituting the lights, undisturbed. It is here to be understood that this action takes
place without the smallest disturbance of the lights and demitints, the plate remain-
ing in all the beauty, and brilliancy, and perfection that it would have had if it had
been carefully washed in hyposulphite of soda.

585. This is a result, however, which I cannot produce with uniformity. Most
commonly, the lights are torn up with the iodide. Had it occurred but once, I should
still have cited it with decision, for, from the very character of it, it is impossible
to be mistaken, or to commit an error of judgment It proves to us that the film
of iodide may be mechanically torn offirom the metallic surface as perfectly as it can
be dissolved offhy chemical agents — a singular fact

586. This result, therefore, proving that we can tear off the film of iodide and leave
the amalgam, can only be co-ordinated with that (583) by gum-water, in which the
amalgam is removed and the iodide left, by supposing that there is not anything like
a direct superposition in the case, and that the particles of amalgam and iodide lie,
as it were, side by side.

587. 3J. That lohen a ray of light falls upon the surface of this pi-eparation, through
all the intervening steps, and up to the point of maximum action, iw iodine is evolved
from the plate, hut that in the common Daguerreotype the light communicates a ten-
dency to the atoms of the iodide to yield up to the mercurial vapour their silver, while
the iodine retires, and combines icith the unaffected silver around. It folloios that, when
such a plate is icithdrawn from the mercurial vapour, there is all over it a uniform
film of iodide of silver, of the very same thickness as at first ; and this has happened
through a direct corrosion of the silver hy the iodine, lohile it was undergoing the
mercurial operation.

There is no difficulty in proving this directly, and the indirect evidence is copious.
If we lay a piece of paper imbued with starch on an iodized plate, and expose it to
the sun, although the plate presently assumes a dark olive-green colour, the starch re-
mains uncoloured.

588. This dark substance is probably a subiodide of silver ; the iodine, therefore,
which has been disengaged from it not having been set free, must have necessarily united
with the adjacent metallic silver : this, for very obvious reasons, there is no difficulty
in admitting.

THE CHEMICAL RAYS ARE ABSORBED. 149

589. Now, therefore, when a photogenic impression existing on the surface of a
plate in an invisible state is brought out by the action of mercury vapour, we easily
understand how this is effected. No iodine is ever evolved. But each atom of iodide
of silver that has been acted on by the light yields to the attraction of the mercury
its atom of silver, and the iodine thus set free unites with the metallic silver particles
around it, reproducing the same yellow iodide by a direct corrosion, of the plate : the
proofs that we have of this are two in number.

590. IsL Dry some mucilage of gum-arabic on a Daguerreotype just brought from
the mercury-bath ; when it has split up, we perceive that the white amalgam of silver
is removed, aud a uniform coat of yellow iodide of silver, of the very same thickness
as at first, as is proved by its colour, is left.

591. 2dly. Dry upon the same plate a solution of Russian isinglass, and, when it
has split up, it will be seen that it uniformly rends off with it the yellow iodide, leaving
the metallic plate with an exquisite polish ; and wherever the light has touched, there
it is corroded^

■ 592. These two facts, taken together, prove that in mercurializing a plate no iodine
is evolved, but that a new film of iodide of the same thickness is formed, at the
expense of the metallic surface.

593. From these facts we readily gather that on the presence of the metallic silver
the sensitiveness of this preparation mainly depends, for to the tendency which the
light has impressed on the elements of the iodide to separate is added the strong
attraction of metallic silver for nascent iodine.

594. This corrosion or biting in of the silver plates, by the conjoint action of the
mercury and iodine, gives rise to etchings that have an inexpressible charm. Could
any plan be hit upon of forcing the iodine to continue its action, the problem of pro-
ducing engraved Daguerreotypes would be solved. By another process, which will
be described hereafter, I have succeeded in producing deep etchings from Daguerreo-
types.

595. I now commence with the proofs of the leading prooositions set out with in
this communication.

And, 1st. That the chemical action produced by the rays of light depends upon the
ABSORPTION of thost roys by sensitive bodies, just as an increase of temperature is pro-
duced hy tlie absorption of those of heat.

596. Without embarrassing myself here with any considerations of the tints of thin
plates, or the colours of natural objects, I shall use the term absorption as expressive of
a loss of radiant matter, whether that loss arises from a direct union of the luminous
molecules with ponderable matter, or is rather a disappearance of effect, caused by the
interference of systems of undulations.

597. I iodized a plate to a golden-yellow colour, and exposed it to the diffused
light of day, setting it in such a position that it reflected specularly the light falling
upon it through the window to the objective of a camera-obscura, which formed an
image of it upon a second sensitive plate. The beams falling upon the sensitive plate
of course exerted their usual influence upon the iodide, which, after the lapse of a short

250 THE PHOTOGRAPHIC EFFECTS ARE TRANSIENT.

time, began to turn brown. As soon as this effect was observed, I closed the aperture
of the camera, and, taking out its plate, mercurialized it ; but it was found that the rays
reflected from the sensitive plate, although they had been converged by a lens four
inches in diameter, and formed a very bright image, had lost the quality of changing
the iodide of silver.

598. We see, therefore, that a ray of light which has impinged on the surface of
yellow iodide of silver, has lost the quality of causing any farther change on a second
similar plate on which it may fall.

599. In the practice of photogenic drawing, this observation is of much importance,
especially when lenses having large apertures are used; the rays which converge upon
the sensitive plate are reflected by it in all directions, and the camera is full of light ;
its sides reflect back again in all directions on the surface of the plate these rays, which,
if they were effective, must stain the plate in the shadows. But if the plate has been
iodized to the proper tint, this light is wholly without action, and hence the proof comes
out neat and clean.

600. Upon an iodized plate I received a solar spectrum formed by a flint-glass prism,
the ray being kept motionless by reflexion from a heliostat, and the plate so arranged as
to receive the refracted rays perpendicularly. After five minutes it was mercurialized,
and the resulting proof exhibited the place of the more refrangible colours in the most
brilliant hues. The lesser refrangible colours had also left their impress of a whitish as-
pect, but the region of the yellow was unaltered. All the different rays, therefore, ex-
cept the yellow, have the power of changing this particular preparation. Now when
a number of pieces of cloth of different colours are placed in the sunbeam, they absorb
heat in proportion as their colour is deeper. A black cloth, which does not reflect any
of those calorific rays, becomes presently hot; and in the same way Daguerre's sensi-
tive preparation absorbs all the rays which have any chemical action on it, and reflects
the yellow only, which does not affect it. In this particular lies the secret of its vast
sensitiveness, compared with the common preparations of the chloride and bromide of
silver.

601. 2d. That as a body warmed by the rays of the sun gradually loses its heat by
radiation, or conduction, or contact with other bodies, so likewise, by some unknown pro-
cess, photographic effects produced on sensitive surfaces are only transient, and gradually
disappear.

602. After a beam of light has made its impression on the iodide, if the plate be laid
aside in the dark before mercurializing, that impression decays away with more or less
rapidity ; first the faint lights disappear, then those that are stronger.

603. Having brought three plates to the same condition of iodization, and received
the image of a gas-flame in the camera on each for three minutes, I mercurialized one,
A, forthwith ; the second, B, I kept an hour, the third, C, forty-eight hours ; the rela-
tive appearance of these three images is represented \nfig. 95.

604. Those who are in the habit of taking Daguerreotypes know how much they
suffer when the process of mercurialization is deferred. To show this effect in the
extrems, I took four plates, and having prepared all alike, I exposed half of the surface
of each to a bright sky for eight seconds.

THE CHEMICAL RAYS ARE NOT CONDUCTED. 15^

No. 1, mercurialized immediately, came out Mack solarized.

2, " in five hours, " white.

3, " twenty-two hours, " same effect

4, mercurialized one hundred and forty-foar, no effect.

605. This last plate, on being submitted twice more to the vapour of mercury, gave
an indistinct mark. On exposing a corner of it to the sun, it blackened instantly ;
these results showing that the peculiar condition brought on by the action of the light
gradually disappears, the compound all the time retaining its sensitiveness.

606. Similar results are mentioned by Daguerre in the case of the changes produced
on surfaces of resinous bodies, and I have noticed them in a variety of other cases.
Now to whatever cause these phenomena are due, whether to anything analogous to
radiation, conduction, &c., it is most active during the first moment after the light has
exerted its agency, but it must also take effect even at the very time of exposure; and
it is for these reasons that it comes to pass, that when light of a double intensity is
thrown upon a metallic plate, the time required to produce a given effect is less than
one half.

607. I could conceive the intensity of a ray so adjusted, that in falling upon a given
sensitive preparation, the loss from this cause, this casting off of the active agent, should
exactly balance the primitive effect, and hence no observable change result Hereafter
"vve shall find that one cause of the non-sensitiveness of a number of bodies is to be traced
directly to the circumstance that they yield up these rays as fast as they receive them.

608. It needs no other observation than a critical examination of the sharp lines of a
Daguerreotype proof with a magnifying glass, to show that the influence of the chemical
rays is not propagated laterally on the yellow iodide of silver. Of the manifestations
which these rays may exhibit after they have lost their radiant form and become ab-
sorbed, we know but little. If they conform to the analogous laws for heat, and if the
absorbing action of bodies for this agent is inversely as their conducting power, we
perceive at once why a photographic effect produced on yellow iodide of silver retains
the utmost sharpness without any lateral spreading ; the absorbing power is almost per-
fect, the conducting should therefore be zero.

609. Zd. Tlmt, as tchen rays of heat fall on a mass of ice, its temperature rises degree
hy degree, until it reaches 32° Fah., and there stops, until a certain molecular change
{liquefaction) is accomplished, and after that proceeds to rise again, so, also, the chemical
rays impress certain c/uinges proportional to their quantity, up to a certain point, and
there a pause ensues ; a very large amount of light being now rendered latent or absorbed,
without any indication thereof being given by the sensitive preparation {as the heat of
jtuidlty is latent to the tliermometer'), a molecular change then setting in, the increments
of the quantity of light are again indicated by changes in the sensitive preparation.

610. Although in the sun the iodide of silver blackens at once, this is only the result
of a series of preliminary operations.

611. When we look at a Daguerreotype, we are strack with the remarkable grada-
tiou of tint, and we naturally infer that the amount of whitening induced by mercuriali-
zation is in direct proportion to the amount of incident light ; otherwise it would hardly
seem that the gradation of tones could be so perfect

J52 THE CHEMICAL RAYS BECOME LATENT.

612. But, in truth, it is not so. When the rays begin to act on it, the iodide cora-
niences changing, and is capable of being whitened by mercury. Step by step this
process goes on, an increased whiteness resulting from the prolonged action or increased
brilliancy of the light, until a certain point is gained, and now the iodide of silver ap-
parently undergoes no farther visible change ; but another point being gained, it begins
to assume, when mercurialized, a pale-blue tint, becoming deeper and deeper, until it
at last assumes the brilliant blue of a watch-spring. This incipient blueness goes un-
der the technical name of solarization.

613. The successful practice of the art of Daguerreotyping, therefore, depends on
limiting the action of the sun-ray to the first moments of change in the iodide ; for, if
the exposure be continued too long, the high lights become stationary, while the shad-
ows increase unduly in whiteness, and all this happens long before solarization sets in.

614. Let us examine these important phenomena more minutely. Having carefully
cleaned and iodized a silver plate three inches by four in size, it is to be kept in the
dark an hour or two.

615. By a suitable set of tin foil screens, rectangular portions of its surface, half an
inch by one eighth, are to be exposed at a constant distance to the rays of an argand
gas-burner (the one I have used is a common twelve-holed burner), the first portion
being exposed fifteen seconds, the second thirty seconds, the third forty-five seconds,
the fourth sixty seconds, &c., &c.

616. We have thus a series of discs or spaces upon the plate {a, h, c, d,Jig. 96), each
of which has been affected by known quantities of light; b being affected twice as
much as a, having received a double quantity of light ; c thrice as much as a, having
received a triple quantity, &c., &c.

617. The plate now is exposed to the vapour of mercury at 170° Fah. for ten min-
utes ; the spaces or discs all come out in their proper order, and nothing remains but
to remove the iodine.

618. An examination of one of these plates thus prepared shows us* that, commen
cing with the first space a, we discover a gradual increase of whitening effect until we
reach the seventh ; that a perfect whiteness is there attained ; that, passing on to the
sixteenth, no increase of whitening is to be perceived, although the quantities of light
that have been incident and absorbed have been continually increasing ; but as soon
as the light thus latent has reached a certain quantity, visible decomposition sets in,
indicated by a blueness, and the sensitive surface once more renders evident the incre-
ments of incident light.

619. Or, by presenting a plate covered with a screen to a sky that is clear or uni-
formly obscured, and with a regular motion, withdrawing the screen deliberately from
one end to the other, and then suddenly screening the whole, it is plain that those
parts first uncovered will have received the greatest quantity of fight, and the others
less and less. On mercuriaUzing, it will be seen that a stain will be evolved on the

* It is impossible to represent these changes in a drawing, which is simply black and white ; it will be understood that
the characteristic distinction of the spaces, from the sixteenth to the twentieth, for example, depends on their assuming a
blue tint, which continually deepens in intensity.

OPTICAL QUALITIES CONTROL CHEMICAL ACTION. I53

plate, as is represented in fig. 97 ; from a to 6 the changes have been successive ; from
6 to c no variation in the amount of whitening is perceptible ; at d solarization is com-
mencing, which becomes deeper and deeper to the end, e, of the stain.

620. The plate from which the drawing of Jig. 97 is taken gives, from a to b, ten
parts, from 5 to c seventeen parts, from d toe twelve parts ; we perceive, therefore, how
large an amount of light is absorbed, and its effects rendered latent, between the maxi-
mum of whiteness being gained and solarization setting in.

621. 4th. That it depends on the chemical nature of the ponderable material what
rays shall he absorbed.

I had prepared a number of observations in proof of this, very much of the same kind
as those which have some time ago been pubUshed in the Philosophical Transactions
by Sir J. Herschel. These refer chiefly to the variable lengths of the stains, impress-
ed by the prismatic solar spectrum on different chemical bodies, and the points of max-
imum action noticed in them. For the present, I content myself with referring to that
excellent memoir for proofs substantiating this proposition.

622. 5th. That while the specific rays thus absorbed depend upon the chemical nature
of the body, the absolute amount is regulated by its optical qualities, such as depend
on the condition of its surfaces and interior arrangement.

623. I took a polished silver plate, and, having exposed it to the vapour of iodine,
found that it passed through the following changes of colour : 1st, lemon yellow ; 2d,
golden yellow ; 3d, reddish yellow ; 4th, blue ; oth, lavender ; 6th, metallic ; 7th, yel-
low ; 8th, reddish ; 9th, green. Sue, &c., the differences of colour being produced by
the differences of thickness in the film of iodide, and not by any difference of chemical
quahty.

624. It is a common remark, originally made by M. Dagderre, that of these dif-
ferent tints that marked 2 is the most sensitive, and photogenic draughtsmen generally
suppose that the others are less eflScient from the circumstance of the film of iodide
being too thick. Some suppose, indeed, that the first yellow alone is sensitive to Ught.
We shall see, in a few moments, that this is very for from being the case.

625. Having brought nine different plates to the different colours just indicated, I re-
ceived on each the image of a uniform gas flame in the camera, treating all as nearly
alike as the case permitted. I readily found that in No. 1 there was a well-marked
action ; No. 2, still stronger, but that the rays had less and less influence down to No.
6, in which they appeared to be almost without action ; but in No. 7 they had recovered
their original power, being as energetic as in No. 2, and from that declining again ; this
is shown vafig. 98.

626. Hence we see that the sensitiveness of the iodide of silver is by no means con-
stant : that it observes periodical changes, which depend on the optical qualities of the
film, and not on its chemical composition ; and that by bringing the iodide into those
circumstances that it reflects the blue rays, we greatly reduce its sensitiveness, and still
more so when we adjust its thickness so as to give it a gray metallic aspect. But the
moment we go beyond this, and restore by an increased thickness its original colour,

U

154 THE ACTIVE RAYS ARE ABSORBED,

we restore also its sensitiveness. Here, then, in this remarkable result, we again perceive
a corroboration of our first proposition.

627. I may, however, observe in passing, that although I am describing these ac-
tions as if there was an actual absorption of the rays, and that films on metallic plates
exhibit colours, not through any mechanism like interference, but simply because they
have the power of absorbing this or that ray, there is no difficulty in translating these
observations into the language of that hypothesis. When the diffi-acted fringes given
by a hair or wire in a cone of diverging light are received on these plates, correspond-
ing marks are obtained, a dark stripe occupying the place of a yellow fringe, and a
white that of a blue. I found, more than four years ago, that this held in the case of
bromide of silver paper (446), and have since verified in a more exact way with this
French preparation. Similar phenomena of interference may be exhibited with the
chloride of silver.

628. We have it, therefore, in our power to exalt or depress the sensitiveness of any
compound by changing its optical conditions. Until now, it has been supposed that
the amount of change taking place in different bodies by the action of the rays of
light, depended wholly on their chemical constitution, and hence comparisons have
been instituted as to the relative sensitiveness of the chlorides, bromides, oxides, and
iodides of silver, &c. But it seems this liability to change depends also on other prin-
ciples, which being liable to variation, the sensitiveness of a given body varies with
them. Thus this very iodide of silver, when in a thin yellow film, is decomposed by
the feeblest rays of a taper, and even moonlight acts with energy ; yet simply by alter-
ing the thickness of its film, it becomes sluggish, blackening in the sunhght tardily, and
recovers its sensitiveness again on recovering its yellow hue.

629. We have now no difficulty in understanding how, in the preparation of ordi-
nary sensitive paper, great variations ensue by modifying the process slightly, and how,
even on a sheet which is apparently washed uniformly over, large blotches appear
which are either inordinately sensitive or not sensitive at all. If, without altering the
chemical composition of a film on metallic silver, or even its mode of aggregation, such
striking changes result by difference of thickness, how much more may we expect that
the great changes in molecular condition, which apparently trivial causes must bring
about on sensitive paper, should elevate or depress its capability of being acted on by
light ! If I mistake not, it is upon these principles that an explanation is to be given
of the successful modes of preparation which Mr. Talbot and Mr. Hunt have descri-
bed, and the action of the mordants of Sir John Herschel.

630. I therefore infer,

6th. That the sensitiveness of any given preparation depends on its chemical na-
ture and its optical qualities conjointly, and that it is possible to exalt or diminish the
sensitiveness of a given compound hy changing its optical relations.

631. 7th. That, as when radiant heat falls on the surface of an opaque body, the
rays reflected are complementary in number to those that are absorbed, so in the case of
a sensitive preparation, the rays reflected are complementary in number to those that are
absorbed.

>;

•

AND THE COMPLEMENTARY REFLECTED. I55

632. This important proposition I prove in the following way : I take a plate, A G,
Jig. 99, three inches bj- four, and b}- partially screening its surface, while in the act of
iodizing, with a proper piece of flat glass, I produce upon it five transverse bands, h,
c,d,e,f; the fifth, yj which has been longest exposed, is of a pale lavender colour; the
fourth, a bright blue ; the third, a red ; the second, a golden yellow ; and the first, un-
iodized metal ; the object of this arrangement being to expose, at the same time and
on the same plate, a series of films of different colours and of different thickness, and to
examine the action of the rays impinging on them, and the rays reflected by them.

633. Having prepared a second plate, B, and iodized it uniformly to a yellow, I
deposited it in the camera, and now placing the first plate, A G, so that the rays
coming on it through the window from the sky shall be specularly reflected to the
object-glass of the camera, and the image of A G form upon B, I allow the exposure to
continue until the yellow of A G is beginning to turn brown ; then I shut the camera
and mercurialize both plates.

634. In consequence of what has been said (625), it will be readily understood, that
of the bands on A G, the first one, which is the bare metal, does not whiten in the mer-
cury vapour ; the second, which is yellow, mercurializes powerfully ; the third, which
is red, is less affected ; the fourth, which is blue, still less ; and the fifth, which is lav-
ender, hardly perceptibly.

635. But the changes on B, which have been brought about by the rays reflected
from A G, are precisely the converse; the band, which is the image of h, is mercurial-
ized powerfully; that of c is untouched, and absolutely black, <f faintly stained, e whiten-
ed, and/ mercuriaUzed, but little less than h.

636. It follows from this, that a white stripe on B corresponds to a black one on
A G, and the converse; and for the depth of tint of the intermediate stripes, those of
the one are perfectly complementary to the corresponding ones of the other.

637. By the aid of these results, we are now able to give an account of the varia-
bility of sensitiveness in photogenic preparations ; the yellow iodide of silver is exces-
sively sensitive, because it absorbs all the chemical rays that can disturb it, while the
lavender is insensitive, because it reflects them. Under this point of view, sensitive-
ness, therefore, is directly as absorption, and inversely as reflexion.

638. The superiority of Daguerre's preparation over common sensitive paper may
now be readily understood. It absorbs all the rays that can affect it, but the chloride
of silver, spread upon paper, reflects many of the active rays. The former, when pla-
ced in the camera, gives rise to no reflexions that can be injurious ; the latter fills it
with active light, and stains the proof all over. Hence the Daguerreotype has a sharp-
ness and mathematical accuracy about its lines, and a depth in its shadows, which is
unapproachable by the other. Moreover, the translucency of the white chloride of sil-
ver, as well as its high reflecting power, permits of particles lying out of the lines of
light being affected, the luminous agent being diffiised in the paper.

639. The fact, therefore, that a given compound remains unchanged even in the
direct rays of the sun, is no proof that light cannot decompose it ; it may reflect or
transmit the active rays as fast as it receives them. It results from this, that optical

l^Q ON SPECTRAL IMAGES AND LATENT LIGHT.

forces can control, and even check the play of chemical affinities. While thus it ap-
pears that there are points of analogy between this chemical agent and radiant heat,
we must not too hastily infer that the laws which regulate the one obtain exclusively
also with the other. As is well known, there are striking analogies between radiant
heat and light, but there are also points of difference ; the convertibility of heat of one
degree of refrangibility to another does not occur with light ; there are also dissimili-
tudes in the phenomena of radiation and its consequences. I do not doubt that what
has been communicated in this memoir will, by the researches of others, be greatly
extended ; but it is not to be expected that a complete parallel can be run between
radiant heat and the chemical rays, any more than between radiant heat and light.

640. From the phenomena of the interference of these rays, of the sensitiveness or
non-sensitiveness of the same chemical compound being determined merely by the fact
of its thickness or thinness, these, and many other similar results, obviously depending
upon mechanical principles, it seems to me that very powerful evidence may be drawn
against the materiality of light, and its entering into chemical union with ponderable
atoms. Those philosophers who have endeavoured to prove the undulatory theory,
will probably find, in studying these subjects, cogent evidence in favour of their doctrines.

Note added to the preceding Chapter.

ON CERTAIN SPECTRAL APPEARANCES, AND ON THE DISCOVERY OF LATENT LIGHT.
{Being a Letter to the Editors of the London and EdirHmrgh Philosophical Magazine, insetted in thai Journal, November, 1842.)

641. Gentlemen — If there be a thing in which I have a disinclination to engage,
it is controversy of a personal kind with scientific fellow-labourers. But as, you well
know, it ordinarily happens that there is no other gain to philosophers beyond the
mere credit of their discoveries, they may be forgiven for reluctantly endeavouring to
secure this, their only reward.

642. I have recently returned from a long journey, undertaken for the purpose of
making trials on the sunlight in lower latitudes, and am surprised to see in the reports
that have reached this country of the Proceedings of the British Association, certain
announcements received from Professor Bessel, of phantoms which can be produced
on surfaces by mercury vapour, by the breath, and other means, as though the thing
were new. Years ago, if you look in your own Journal (February, 1840, p. 84 ; Sept.,
1840, p. 218 ; Sept., 1841, p. 198, 199), you will find that I had published facts of
the kind ; spectral appearances, that could be revived on metals, glass, and other bodies,
by the breath, by vapour of camphor, by mercury vapour, &c. The very purpose for
which I described them was the striking resemblance of some of them to Daguerre-
otype images. I have repeatedly shown that, by placing a coin or any other object
on iodized silver, in the dark, the vapour of mercury w^ll bring out a representation of
it. And in one of the papers just quoted, the condition under which camera images

THE SOLAR SPECTRUM ON A DAGUERREOTYPE PLATE. j 57

can be reproduced on a silver plate, even after the plate has been rubbed with rotten-
stone, is described.

643. I have farther seen (Literary Gazette, July 23, 1842, Paris letter), that the fact
that hght becomes latent in bodies, after the manner of heat, was announced in France
as a new and important discovery of Professor Moser of Konigsburg. In your own
Journal, more than a year ago, you printed a long paper written by me on this very
topic (September, 1841, p. 196, 204, 205, 206), not merely announcing the fact, but
giving rude estimates of the amounts: more exact numerical determinations I have
now nearly ready for the press.

644. But I will trouble you no farther with these private matters, simply hoping
that your numerous readers, who feel an interest in such things, will turn for tliem-
selves to the pages I have quoted.

645. The accompanying photographic impression of the solar spectrum, which I
will thank you to give to Sir John Herschel, was obtained in the south of Virginia :
probably yon can make nothing like it in England: the sunlight here, in New- York,
wholly fails to give any such result It proves that, under a brilliant sun, there is a
class of rays commencing precisely at the termination of the blue, and extending be-
yond the extreme red, which totally and perfectly arrest the action of the light of the
sky. This impression was obtained when the thermometer was 96° Fahr. in the shade,
and the negative rays seem almost as effective in protecting as the blue rays are in de-
composing iodide of silver.

646. The most remarkable part of the phenomenon is, that the same class of rays
makes its appearance again beyond the extreme lavender ray. Sir John Herschel has
already stated, in the case of bromide of silver, that these negative rays exist low down
in the spectrum. This specimen, however, proves that they exist at both ends, and
do not at all depend on the refrangibility. It was obtained with yellow iodide of sil-
ver, Daguerre's preparation, the time of exposure to the sun fifteen minutes.

647. In this impression, six different kinds of action may be distinctly traced by the
different effects produced on the mercurial amalgam. These, commencing with the most
refrangible rays, may be enumerated as follows : 1st, protecting rays ; 2d, rays that whi-
ten ; 3d, rays that blacken ; 4th, rays that whiten intensely ; 6th, rays that whiten very
feebly; 6th, protecting rays.

648. It is obvious we could obtain negative photographs by the Daguerreotype pro-
cess, by absorbing all the rays coming from natural objects, except the red, orange, yel-
low, and green, allowing, at the same time, diffused daylight to act on the plate.

649. This constitutes a great improvement in the art of photography, because it per-
mits its application, in a negative way, to landscapes. In the original French plan,
the most luminous rays are those that have least effect, while the sombre blue and violet
rays produce all the action. Pictures produced in that way never can inutate the or-
der of light and shadow in a coloured landscape.

650. If it should prove that the sunlight in tropical regions differs intrinsically from
ours, it would be a very interesting physical fact. There are strong reasons to believe
it is so. The Chevalier Frederichstal, who travelled in Central America for the Prus-

158 ANALOGIES BETWEEN THE CHEMICAL RAYS AND HEAT.

sian government, found very long exposures in the camera needful to procure impres-
sions of tiie ruined monuments of the deserted cities existing there. This was not due
to any defect in his lens ; it was a French achromatic, and I tried it in this city with
him before his departure. The proofs which he obtained, and which he did me the
favour to show me on his return, had a very remarkable aspect. More recently, in the
same country, other competent travellers have experienced like difficulties, and, as I
am informed, failed to get any impressions whatever. Are these difficulties due to the
antagonizing action of the negative rays upon the positive.

CHAPTER XIII.

ON A NEW IMPONDERABLE SUBSTANCE, AND ON A CLASS OP CHEMICAL RAYS ANALOGOUS

TO THE RAYS OF DARK HEAT.

{From the London, Edinburgh, and Dublin Philosophical Magazine for December, 1843.)

Contents : Analogies between the Chemical Rays and Heat. — New Nomenclature pro-
posed.— Tithonic Hays. — Independence of Tithonic Rays and Light. — Independence
of Tithonic Rays and Heat. — Dark Tithonic Rays.

651. In chapter twelve I have pointed out several analogies which may be observed
between the phenomena of the chemical rays and those of radiant heat.

652. In this memoir it is my intention to show still more striking points of analogy,
and also to direct the attention of chemists to equally striking points of discordance.

653. It will be seen, from the remarkable facts detailed in this paper, that we are
now forced to recognise the existence of a new imponderable agent, analogous in many
of its properties to light, heat, and electricity, yet differing as much from them all as
they do from one another.

654. So far as chemical analogies can direct us, there does not appear anything un-
philosophical in the supposition of the existence of many imponderable agents analo-
gous to those already known. The progress of science has indeed tended in different
directions in the cases of the imponderable and ponderable bodies. Among the former,
we have successively seen the agents that are concerned in galvanic phenomena and
those of magnetism merged into electricity ; but the ponderable bodies, especially those
of a metallic kind, have greatly increased in number, though, so far as their more obvi-
ous physical properties are concerned, the differences of many ar.e almost undistinguish-
able. We have thus found it necessary to invert the maxims of the early cultivators
of chemistry, who extended the number of ethereal agents very greatly, and believed
that all metals and other ponderable principles were modifications of one or two pri-
mordial and elementary forms.

655. Centuries ago it was discovered that the sun's light had the property of effect-
ing chemical changes in bodies, and it is stated that Scheele first noticed that this

NEW NOMEXCLATi:UE I'UOPOSED. 259

property was mainly due to the violet rays. Seebeck observed that chloride of silver,
exposed to the spectrum, varied its colour with the colour of the space in which it was
held, and during the present century a very large amount of new observations has been
accumulated. A new art. Photography, has come into existence.

656. The general supposition that obtains is, that the effects in question are due to
the rays of light ; hence all the words that have been introduced into use have refer-
ence to that supposition; such words as photography, photology, photometer, are derived
from this erroneous hypothesis, and lead us to confound together things which ought
to be kept essentially distinct

657. As it is the object of this paper, and others which I shall shortly publish, to call
the attention of chemists to the agent that is involved in photographic results as a
clearly-established and new imponderable substance, possessing striking analogies with
Ught and heat, yet differing as much from them both as they do from each other, I am
induced to propose for it a proper name, and to endeavour to establish for it a nomen-
clature that shall be free from ambiguity, and keep the description of its phenomena
separate from those of light. While, therefore, I show that it undergoes radiation,
reflexion, refraction, polarization, absorption, interference, &c., under the laws to which
its radiant companions, light and heat, are subject, I wish to claim for it a separate and
independent existence, to introduce it into the natural family of imponderable agents,
with light, heat, and electricity. In that family it stands as the fourth member. Is
there any reason that the progress of knowledge should not make known to us multi-
plied forms of imponderable substances as w ell as of ponderable matters ? This agent
differs from light and heat as much as lead differs from zinc or tin.

658. When novel effects, brought about by novel causes, are met with, the purposes
of science require new corresponding terms. In the case of the chemical rays of light
it is so. I have experienced the need of a nomenclature of the kind from my earliest
experiments. It is a rule of which modern philosophers know the value, that such
names ought to be free from all attending hypothesis ; for if this be not complied with,
it soon comes to pass, as knowledge advances, that terms involving theoretical ideas
lose much of their significance.

659. The chemical rays are associated with the rays of light, accompanying them
in all their movements, originating with them, and, unless disturbed, continuing to exist
along with them. But should a compound beam like this fall upon a sensitive surface,
the chemical rays sink into it, as it were, and lose all their force, and the rays of light
are left alone. Photographic results thus resulting from the reposing of the chemical
rays on the sensitive surface are not, however, in themselves durable, as will be shown
in this paper, for the rays escape away under some new form.

660. ■' Tithonus was a beautiful youth whom Aurora fell in love with and married
in heaven. The fates had made him immortal; but, unlike his bride, in the course ol
events he became feeble and decrepit, and, losing all his strength, was rocked to sleep
in a cradle. The goddess, pitying his condition, metamorphosed him into a grasshop-
per."— Mythological Dictionary.

661. The fact and the fable agree pretty well; and, indeed, the playful coincidence

1(30 TITHONIC RAYS.— INDEPENDENCE OF TITHONIC RAYS AND LIGHT.

might be carried much farther. The powers of photography, which bring architectural
remains and the forms of statuary so beautifully and impressively before us, might seem
to be prefigured by the speaking image of the son of Tithonus and Aurora, that was
to be seen in the deserts of Egypt. And besides this, such words as tithonoscope,
tithonometer, tithonography, tithonic effect, diatithonescepce, are musical in an Eng-
lish ear. In this paper I shall, therefore, use the term tithonicity and its derivatives in
the same manner that we use electricity and its derivatives.

662. This communication takes up the consideration of three distinct facts :
1st. The proof of the physical independence of tithonicity and light.

2d. The proof of the physical independence of tithonicity and heat.

3d. The proof of the existence of dark tithonic rays, analogous to the rays of
DARK heat. Under this head it will be shown that Tithonicity, like heat, enters tran-
siently into bodies, producing specific changes on them, and then slowly and invisibly
radiates away. And the physical constitution of the new class of rays thus formed
is entirely different from that of rays that come from incandescent sources : a distinction
having a striking analogy in the case of heat. Tithonicity becomes transiently and
permanently latent in bodies.

663. Figure 100 serves to show that by the agency of absorbent media we may
detect the existence of tithonic rays in every part of the spectrum unaccompanied by
light. The results there projected were obtained by an arrangement such as that in
Jig. 101. From a heliostat mirror, aa,^. beam of the sun's light was thrown in a hor-
izontal position, and falHng on a screen, & fc, a portion of it passed through a circular
aperture one fourth of an inch in diameter. At the distance of ten or twelve feet it fell
on a glass trough c c, with parallel faces, into which any coloured solution could be
placed ; immediately behind the trough there was a double convex lens, d d, of three
feet focal length, and between them a second screen, jTy^ with an aperture correspond-
ing to the centre of the lens, half an inch in diameter. Behind the lens was situated
a prism of flint glass, e, which effected the dispersion of the incident beam. Now the
lens not being achromatic, the screen r v had to be placed in an inclined position in
order to obtain a neat spectrum-image of the hole in b b, and this was attended with
the great advantage of elongating the total length of the spectrum, and, therefore, in-
creasing the measures. In order to obtain sensitive surfaces of great delicacy, the silver
plates were first iodized lightly, and then exposed to the vapour of bromine until they
attained a full golden yellow.

664. In Jig. 100, the line No. 1 represents the visible colorific spectrum ; it, with No. 2,
serves as an index of comparison for all the others. No. 2 represents the effect of a
spectrum that has not undergone the action of any absorbent medium on the bromo-
iodized plate ; the extreme red tinges the plate white, the extreme violet, brown, and all
the intermediate space is of a rich brownish violet, with a point of maximum action
nearly in its centre. The numerical subdivisions commence with 0 at the extreme red,
and are graduated on a principle which I shall explain in a future paper, which makes
the spectrum of different tithonographists comparable.

665. No. 3 shows the spectrum after absorption by the persulphocyanide of iron, and

INDEPENDENCE OF TITHONIC R^YS AND HEAT.

161

its corresponding tithonograph. This spectmm is divided into three portions, one of
which is red and yellow, a second indigo, and a third violet. But the tithonograph ex-
hibits an action far beyond the extreme red, half way through the dark space that in-
tervenes in the middle of the spectrum, both ends of this lower part projecting into
dark spaces ; while the indigo ray, ordinarily so active, does not tithonize at all.

666. Without going into a long descriptive detail of the comparison of different
spectra and their corresponding tithonographs, I shall here sum up the results which
may be gathered from an inspection of the plate.

667. By the absorbent action of the persulphocyanide of iron, we can prove the ex-
istence of invisible tithonic rays beyond the extreme red — invisible rays corresponding
to the green. We can also prove that the indigo-coloured . rays of light may exist
without tithonic effect.

668. By the absorbent action of neutral chloride of gold, we can insulate blue-col-
oured rays of light that are not tithonic.

669. The green solution formed by a mixture of bichromate of potash, muriatic acid,
and alcohol, enables us to insulate tithonic rays of the same refrangibility as the violet,
but unaccompanied by any light.

670. The solution of sulphate of copper and ammonia enables us to insulate a visible
red and yellow ray that are without tithonic power, and an invisible tithonic ray beyond
the violet.

671. The solution of litmus enables us to obtain red and green light without action,
and an invisible tithonic ray corresponding to the violet.

672. The solution of bichromate of potash enables us to obtain red and orange light
without any tithonic effect

673. Such results might be multiplied without end, for, indeed, there is scarcely
an instance in which spectra of rays that have passed absorbent media are exactly
coincident with their corresponding tithonographs. To set the matter plainly before
the reader, the following tabular view, gathered from the plate, may suffice :

Ktne <d g«hBi[iD.

C«l<«r of ueBT
titbcaiceftet.

iBTuiUe TiTBOinc nj*
rOiKtylnthc

Peraalpbocyanide of iroo . .

CUoride of gold

Chrome solution

ladigu

Blue.

Extreme red, green.

Violet.

Extreme viotet.
Violet.

Salph. copper and ammooia .

Litmus

Bichromate of potash ....

Red, yellow ....
Red, gicxni ....
Red. orange

From this, therefore, I infer the entire independence throughout the spectrum of the
luminous rays that give to the organs of vision the impression of colour and the tithonic
rays.

674. When I come to describe the dark tithonic rays that are analogous to the rays
of dark heat, and which are unaccompanied by any kind of light whatsoever, no farther
doubt can be entertained on this subject. I have also some other proofs of a very
remarkable kind, to be described hereafter, drawn from the phenomena exhibited by
tithonic rays that have undergone polarization.

675. Next, as to the independence of these rays and the rays of heat

162

DARK TITHONIC RAYS.

676. One of the most striking proofs of this is the facility with which impressions of
the moon's disc may be obtained on Daguerreotype and other sensitive plates. Even
with lenses of comparatively small diameter, and in the space of a few minutes, strong
impressions of the moon's surface may be taken. There is no more difficulty in ob-
taining these sketches than there is in copying a building or a statue, or any other ob-
ject on which the sun is shining. But the moonbeams have hitherto given no trace of
the presence of heat.

677. I found, moreover, by direct trial, that plates which had been carefully prepared,
so as to be exceedingly sensitive, were unaffected by the radiant heat of copper at any
temperature up to a red heat. These dark rays, therefore, have no kind of effect on
such surfaces. A sensitive plate may be made so hot that it cannot be touched, yet its
surface remains unchanged; and even the radiant heat emitted by brightly incandescent
bodies has no effect, as I also proved.

678. Lastly, Proof of the existence of dark tithonic rays analogous to the rays of

DARK HEAT.

679. The experiments now to be described were made with Daguerreotype plates
iodized at first to a pale lemon yellow, then brought to a golden hue by immersion in
the vapour of bromine, and lastly exposed for a short time to the vapour of iodine again.

680. Having exposed such a plate (fig. 102), ab, to the action of weak daylight, or
lamplight, for a period of time which would cause it to whiten powerfully all over if placed
in the vapour of mercury, carry it into a room which is totally dark, and suspend at a dis-
tance of one eighth of an inch from its surface a metallic screen, c d, the under surface
of which is blackened. Let all remain in the dark four or five hours, and then remove
the sensitive plate a b, and expose it to the rapour of mercury. All that portion of it
which was not covered by the screen c c? will undergo no change, but that which was
beneath c d will whiten powerfully.

681. From this remarkable result I infer that the tithonicity that had originally dis-
turbed the surface of the plate equally all over, has escaped away from those portions
that were uncovered, but that its escape has been entirely prevented by the action of the
screen ; and this must be through radiation, for the screen is at a distance, and has
never touched the plate. And, farther, that the rays that do thus escape away are abso-
lutely invisible to the eye.

682. Now suppose a piece of black cloth, placed in the rays of the sun until it has
become warm, were carried into a cold room, and half its surface screened by some
material, as a piece of glass, at a short distance ; there cannot be a doubt that the un-
covered portion would cool fast by radiation, but the screened portion more slowly, for
its radiation would be arrested by the glass plate.

683. The two cases are absolutely alike.

684. Tithonicity, therefore, radiates exactly after the manner of heat.

685. This also furnishes proof, in addition to those I have heretofore given, that not
only does tithonicity become latent in bodies, but that it becomes latent in two ways,
transiently and permanently, exactly after the manner of heat.

686. The same result is obtained when other sensitive surfaces are employed, the

DARK TITHONIC RAYS. jgg

period of time differing for different bodies. Guided, therefore, by the analogy of heat,
I perceive that bodies have a relation to this imponderable agent corresponding to that
of specific heat. It follows, therefore, with certainty, that,

687. The specific tithonicity of bodies is the prime function on which their sensi-
tiveness depends. Under this point of view the sensitiveness b inversely as the spe-
cific tithonicity.

688. The circumstances under which this experiment is made serve also to show
that metallic bodies are non-conductors of tithonicity.

689. This contrasts remarkably with their action towards heat

690. Having exposed a sensitive plate, a b, to light until it would whiten if mercnri-
alized, as before, and having prepared a second (c d,fig. 102) in total darkness, with-
out allowing auy light to have access to it, suspend this latter over the former at the
distance of one eighth of an inch, so as to cover it about half Keep the two plates in
darkness for several hours, and then mercuriaUze both. That portion, a c, of the first
not covered by the second, will not whiten ; that portion of the second, h d, not cov-
ered by the first, will also remain unchanged ; but both on those parts that have looked
towards each other will whiten.

691. From this I infer, that the portion of the first not overshadowed by the second
does not whiten, because its tithonicity escapes away under the form of dark tithonic
rays.

692. I also infer, that as both plates are nearly equally whitened on those portions
of their surfaces that have looked towards each other, the dark tithonic rays that have
escaped from the first plate, notwithstanding their invisibility, have retained their pecu-
liar chemical force, and have affected the second plate.

693. The analogy with heat is here perfectly observed. A hot, non-conducting plate,
set partialU' opposite a cold one, would warm that plate on the portion looking towards
it. and, through the consequent retardation of radiation, would retain its own heat to a
certain extent But all those portions unopposed by the cold plate would cool down
by radiation rapidly.

694. This experiment proves, in a clear and undoubted manner, the total physical
independence of tithonicity and light

695. Hence the absolute necessity of some such nomenclature as that proposed ; the
chemical ravs of hght is a misnomer.

696. On the surface of a sensitive plate that has been suitably exposed, as hereto-
fore, place a fragment of perfectly clean and colourless glass. Allow it to remain there
for four or five hours in a dark room, then mercurialize, and it will be found that the
portion on which the glass has been placed will whiten powerfully, but all the rest will
remain unchanged.

697. This, therefore, proves that colourless glass is nearly opaque to the dark tithonic
rays, a result observed, also, in the case of the dark rays of heat

698. I made a comparative trial of the relative permeability of colourless plate-glass
and common writing-paper. A sensitive surface was exposed until it had slightly, but
very plainly commenced to turn brown. On one portion I now laid a piece of clear

Ig4 DARK TITHONIC HAYS.

glass, and by the side of it a piece of writing-paper; the arrangement \tas next pla-
ced in the dark for four hours; it was tlien mercurialized at 160° Fah. for an hour,
and the result was very striking. Notwithstanding the long exposure to the mercury
vapour, all those portions that had not been covered were perfectly unaflfected, the por-
tion that had been covered by the glass was of an intensely deep brown colour, but the
portion covered by the paper was marked by a distinct, but very faint white stain. It
was therefore plain, that from the uncovered portions all the tithonicity had radiated
away ; from the portions covered by the writing-paper the same eflfect almost to the
same extent had occurred, the paper, however, slightly obstructing the passage of the
rays ; but radiation had been wholly prevented from those parts covered by the colour-
less glass.

699. Writing-paper is, therefore, far more permeable to the dark tithonic rays than
the purest plate glass.

700. This property it will be hereafter convenient to speak of under the designation
of diatithonescence or transtithonescence.

701. Blue, red, and yellow glass obstruct, to a great extent, the process of radiation.
In several trials it seemed as though the yellow was more transparent than the others,
but there was not much difference.

702. Transparent rock-salt appears to hold very nearly the same relation of diatitho-
nicity as plate glass.

703. In like manner, the following substances in thin plates obstruct the radiation of
tithonicity : Sulphate of lime, beryl, agate, rock-crystal, calc-spar, mica, wafers, metal-
lic bodies, cloth of cotton, wood, ivory, coloured glass, &c., &c.

704. The remarkable results described in the Philosophical Transactions by Sir
John Herschel (1840, p. 44), but left by him without any explanation, are of the
kind now under discussion. He found that paper washed with nitrate of silver, if ex-
posed to the sun under a piece of glass, darkened much more rapidly than if the glass
were away. This effect was by no means limited to that variety of paper, but was ob-
servable, also, with many other tithonographic compounds. Transparent minerals, such
as topaz, selenite, Iceland spar, quartz, produced the same results as glass. But on
gloomy days the phenomena did not appear, a bright sunshine being apparently requi-
site for their production. " When a piece of nitrated paper, for instance, was rolled
round a cylindrical surface of moderate convexity, covered with black velvet, and the
piece of glass laid gently in contact with it, the effect of sunshine was exalted at the
line of contact; but on either side of that line, as the interval increased, the influence of
the glass diminished, and at less than half an inch distance no difference could be per-
ceived between the impressions under the glass and in the free air."

705. Now all this is precisely what should happen if the tithonographic compound
radiates while it is undergoing decomposition. The rays which come from the sun pass
through the glass with but little loss from absorption ; falling upon the nitrate, they de-
compose it, and now it commences radiating, but the physical character of these rays
is very different from the character they possessed before impinging on the nitrate.
Noio they cannot get through the glass, before they passed without difficulty. So it is,

PRODUCTION OF SPECTRAL APPEARANCES. 165

precisely, in the case of heat. Mach of the heat of the sun passes through plate glass,
and if it falls on a dark surface that can absorb it, that surface becomes presently warm
and commences radiating; but the physical constitution of these rays is changed: they
cannot get through the glass ; and if a non-conducting black surface, half covered by a
piece of glass and half in the free air, were exposed to the sun, the covered half would,
for these obvious reasons, become the hotter. For the same reason, precisely, in the
tithonic experiment, the glass increases the final effect by obstructing radiation.

706. It is very obvious vvhj' such effects cannot be produced on gloom}' days. If
at such times we were to expose a piece of black cloth, partially covered by glass, no
difference of temperature would be perceptible in its covered and uncovered portions.
The reasons are analogous in each case,

707. An experiment, the same in principle as Sir John Herschel's, may be easily
made. Upon a sensitive plate that has been exposed a short time to a feeble light,
place a convex lens ; the arrangement being left for a time in a dark room. When
joQ have mercuriahzed, you will find a central dark point corresponding with the point
of contact, and round it a white areola that shades gradually and imperceptibly away.
With a leus with which I have occasionally made this experiment, the areola is nearly
an inch in diameter, the lens being a double convex of about t^vo inches focus.

Note added to the preceding Chapter.

ON THE RAPID DETITHONIZING POWER OF CERTAIN GASES AND VAPOURS, AND ON AN
INSTANTANEOUS MEANS OF PRODUCING SPECTRAL APPEARANCES.

(From the London, Edinburgh, and DuUin PhiUuopkieal Magashiefor Mt-rck, 1843.) >

708. For some time after I was acquainted with the phenomena mentioned in the
last chapter, and there referred to radiation, I was led to attribute them to a peculiar
property which certain gases and vapours possess, of which I propose now to give a
detailed description.

709. This property is a power of effecting a very rapid detithonization of surfaces
♦hat have been poicerfully tithouized.

710. It affords the means of instantly procuring spectral appearances of external
forms.

711. Referring now, in the first place, to the analogies of caloric: a body which has
been warmed cools down to a temperature that is in equilibrium with that of objects
around in several different ways, by radiation, by currents in the air, and often by direct
conduction, each of these tending to produce the same result

712. A sensitive surface, which has been disturbed by exposure to the daylight or
lamplight, has the quality of restoring itself to its primitive condition when kept in the
darL Dagderre noticed this in the case of certain resinous bodies ; other experi-
menters have likewise proved that it takes place with some varieties of the ordinary
photogenic preparations. I have found that it holds in the coloured films on the sur-
face of silver.

166 PRODUCTION OF SPECTRAL APPEARANCES.

713. Much of this effect is due, as I have endeavoured in the paper above quoted to
show, to a direct escape of dark rajs by a process analogous to radiation ; but much
also is due to a hitherto unknown power, possessed by electro-negative gases and va-
pours, which tends to bring about the same results. So powerfully, indeed, does this
cause operate, that, as I have said, for a length of time I attributed all the phenomena
to it.

714. I proceed now to describe some simple experiments which will bring this
matter clearly before the reader.

715. Take a bromo-iodized silver plate, expose it to the light of the sky or lamplisht
for a length of time sufficient to brown it sensibly and uniformly all over. In this state,
if it were placed in the vapour of mercury, it would solarize or blacken in every part.
But, before mercurializing, treat it as follows : Lay upon it a fragment of glass, a piece
of metal, or any other object ; immerse it for a second or two in a box containing the
vapour of iodine ; withdraw it, remove the little object, and mercurialize forthwith ;
and now you will find a perfectly-formed, block spectral impression of the object,
whatever it was, powerfully brought out by the mercury vapour ; but on all those
parts to which the iodine vapour has had access the mercury will not adhere, but the
phenomenon will take effect as though the plate had never been exposed to the light,
except on those portions on which the object, whose spectral image appears, was laid.

716. From this it would seem that the vapour of iodine has the quality of detithon-
izing a surface that has been changed by light.

717. The same process may be conducted so as to give a still more striking result.

718. Employing a prepared bromo-iodized plate, as before, expose it to any uniform
source of light for such a length of time that, if it were mercurialized, it would whiten
uniformly, and exhibit the aspect of an ordinary white Daguerreotype. Treat it as
before, by placing on it any object, pass it into the vapour of iodine, remove the object,
and mercurialize ; and now a spectral appearance of that object, of a dense ichite as-
pect, will emerge, the remainder of the plate being quite black and in the condition
of the shadows of a Daguerreotype, that is, as though it had never been exposed to
the light.

719. In order to obtain a clear idea of what passes under the foregoing circumstances,
I made the following trial.

Upon a plate prepared and deeply tithonized, as has been said, I laid a double
convex lens of about two inches focus, and exposing the plate, with the lens upon it,
to the vapour of iodine, and then removing the lens, I mercurialized. A deep-blue
spectral image emerged, of less diameter than the lens, but, Hke it, of a circular form, its
circumference being marked by as sharp a line as if it had been drawn by a pair of
compasses. Indeed, it looked as distinct and as sharp as if a blue wafer had been laid
on the plate.

720. In several successive trials I found that toe magnitude of this spectre dimin-
ished as the time of exposure to the vapour had been prolonged.

721. Next, I repeated the same trial, using the plate and lens as just described ;
but immersing the plate in the vapour of bromine instead of that of iodine, a still

DETITHONIZING ACTION. 167

more remarkable image emerged on mercurializing. This image, like the former, was
circular and black, but all around it for a certain space there was an annulus of nar-
row dimensions of pure unmercuriailzed silver, the deep black of which contrasted
strikingly with the blue black of the spectre, and its outer circumference was marked
by a faint whitening of the plate — faint, but as sharp as it is possible to conceive.

722. In a third trial, things were conducted as before, except that now chlorine,
diluted with atmospheric air, was used ; the spectre again came out, and did not differ
in any observable manner from that produced by iodine.

723. In a fourth trial, the vapour of nitrous acid was used as a detithonizer. In
this case, the edges of the spectre commonly had a gradually shading outline, and only
in one instance did I find that sharpness of termination exhibited in the other cases.

724. We therefore perceive that iodine, bromine, chlorine, and nitrous acid can de-
tithonize a surface on which light has fallen : they can undo tchat. the tithonic rays have
done.

725. In repeating these experiments, as, for example, the one by iodine, if the com-
mon iodine-box be used to effect the detithonization, two or three seconds of time is
all that is required. A longer period is demanded when the vapour is very weak, but
when strong the effect is a/most instantaneous.

726. This detithonization and production of spectral images can therefore be ac-
complished in an incredibly short space of time.

727. I made trials with other substances, such as hydrogen gas and the vapour of
liquid muriatic acid. The former to a certain extent, though not near so powerfully
as the electro-negative bodies mentioned, could produce the change in question ; the
latter seemed to be without any perceptible action.

728. To the list, with the other electro-negative substances, I beUeve oxygen ought
to be added ; for, on repeating the same experiment, and raising the temperature of the
plate iu atmospheric air so as to maintain the tithonized surface at about 200"" Fab. for
several minutes, a certain effect, which in an imperfect way resembled those already
described, was exhibited. Oxygen, therefore, diluted as in atmospheric air, at 200' Fah^
mav be regarded as possessing, to a small extent, the property in question.

729. Without multiplying the description of these experiments farther — for the in-
genuity of any one who repeats them will suggest many modifications which may give
rise to striking results — I will, in conclusion, give the reasons which have led me to
suppose that in all these phenomena two different principles are engaged — vapour ac-
tion and radiation.

730. I have stated that the electro-negative bodies possess this deiithonizing
quality in a very marked Hnanner. I do not wish it to be understood, however, that
there is any relation ofli&Ta^miization between that particular class of substances and
the tithonic rays. It appears u^s^^ that their pecuUar qualitj', in the circumstances
described, may be traced to the fact that silver, an electro-positive substance, happens
to afford the sensitive surface. I have, however, prepared a paper which takes up the
consideration of the conditions and theory involved, and will not at present anticipate
what has to be offered when that paper shall be published.

X68 DETITHONIZING ACTION.

731. The action, then, which these different gases and vapours exhibit is so intense
as to mask the feebler effect of radiation. Thus, it takes several hours' exposure
in the dark, and after a long subsequent process of mercurialization, to prove the true
radiant effect, a slow detithonization, which could be brought about by vapour action
in an instant. But whoever has seen the symmetrical, or, rather, geometrical lines
that are left when the slower process is followed, must be struck with the persuasion
that the phenomena he witnesses is obeying geometrical laws, and is not due to the
irregular action of a dilute and varying current of vapour.

732. Thus, on repeating carefully the experiment cited at the close of my last paper,
ia which a lens is laid on a tithonized surface and left in the dark, I fouud that after
tbe mercurial process was completed, the plate exhibited a dark central spot sur-
rounded by a white annulus. On drawing upon paper a section of the lens and the
sensitive surface, I found that a line drawn from the extreme edge of the white annu-
lus to the edge of the lens was a tangent to the lens at that point ; that a line drawn
from the extreme edge of the central dark spot would, after reflexion by the convex
surface of the lens, be found precisely on the edge of the white annulus; the edge of
the annulus and the edge of the spot thus having a true catoptrical relation to the curva-
ture of the lens.

733. Now, although in laboratories such as that in which my experiments are con-
ducted, the vapours of these different electro-negative bodies are unquestionably pres-
ent, and may produce a part of the phenomena witnessed, yet, inasmuch as that phe-
nomenon follows laws that are apparently of a strict geometrical kind, and to those
floating vapours we could hardly assign anything like symmetrical results — guided,
also, by the analogy of cooling bodies, which lose part of their heat through radiation,
and part through the current action of the air, and part through the conducting power
of their supports, I have been led to take the view of the phenomena in question
which I have set forth.

MODE OF PRODUCING THE FIXED UNES. jqq

CHAPTER XIV.

ON A NEW SYSTEM OF INACTIVE TITHONOGRAPHIC SPACES IN THE SOLAR SPECTRUM
ANALOGOUS TO THE FIXED LINES OF FRACNHOFER, AND ON THE TITHONOTYPE.

{From At Lmltm, Eiimhrnrgk, «U DaUUi PkUmepkumi MtgaziuefoT Mof, 1843.)

Contexts: Mode of producing the Jixed Lines. — Description of them. — Difficulty of
obtaining them in the Yellow and Green.

Daguerreotypes are dotted Surfaces. — Mode of copying them by the Tithonotype. — Po-
larized Structure of the Daguerreotype Fihn.

734. Whex a beam of the sun's light, directed horizontally by a heliostat, is thrown
into a dark room, and, passing through a chink with parallel sides, is received on the
surface of a homogeneous flint-glass prism, which refracts it at the angle of minimum
deviation, and, after its passage through the prism, is converged to a focal image on a
white screen by the action of an achromatic lens, the spectrum which results is given
in great purity, and Frauxhofer's lines are quite apparent The larger ones are seen
by the most casual inspection.

735. A tithonographic surface, after being placed in this spectrum, exhibits impres-
sions of an analogous character, being covered with the representations of multitudes
of inactive lines varying greatly in dimensions.

736. After several attempts last summer, I succeeded in discovering these lines, and
have obtained impressions of them sufficiently perfect

737. Before proceeding to the description of the mode which is to be followed, and
of the characters of the lines themselves, I cannot avoid calling attention to the re-
markable circumstance, which has frequently presented itself to me, of a great change in
the relative visibility of Frauxhofer's lines, when seen at different periods. There are
times at which the strong lines seen in a red ray are so feeble that the eye can barely
catch them, and then, again, they come out as dark as though marked in India ink on the
paper. During these changes, the other lines may or may not undergo corresponding
variations. The same observation equally applies to the blue and yellow rays. It has
seemed to me that the lines in the red are more visible as the sun approaches the hori-
zon, and those at the more rejfrangible end of the spectrum are obvious in the middle of
the day.

738. A beam of the sun, passing horizontally from a heUostat mirror into a dark
room, was received on a screen with a slit in its centre, the slit being formed by a pair
of parallel knife edges, one of which was movable by a micrometer screw ; the instru-
ment being, in fact, the common instrument used for showing diffracted fringes. The
screw was adjusted so as to give an aperture jt urIi wide, and the light, passing through,
fell upon an equiangular flint-glass prism placed at the distance of eleven feet Imme-
diately on the posterior face of the prism, the ray was received on an achromatic lens,

Y

170 DESCRIPTION OF THE FIXED LINES.

the object-glass of a telescope, and brought to a focus at the distance of six feet six
inches, at which place an arrangement was adjusted for exposing white paper screens,
on which the more prominent fixed lines might be seen, and their position marked, or
sensitive plates substituted for the screens, occup)'iug precisely the same position. The
lines on the screens could, therefore, be compared with those on the sensitive surfaces,
as to position and magnitude, with considerable accuracy. In these trials I have gen-
erally used an achromatic lens, but the lines can be beautifully seen by employing a
common double convex, if the screen be inclined forward in the way described in (663).
Either way answers very well.

739. In order to identify these lines, I have made use of the map of the spectrum,
published by Professor Powell, in the Report of the British Association for 1839.
With the instrumental arrangement described they are exceedingly distinct, and no dif-
ficulty arises in the identification of the more prominent ones. The spectrum with
which I have worked occupies upon the screen a space of nearly four inches and a
quarter in length from the red to the violet, or, more correctly speaking, from the ray
marked in that map A to the one marked k. In stating, however, that no difficulty
arises in identifying these lines, I ought to add that I am referring to that particular
map. In the figure annexed to Sir John Herschel's Treatise on Light, in the Ency-
clopedia Metiopolitana, x\\e ray marked G seems to differ from that of the report. But
Professor Powell's map being drawn from his personal observations, and with refer-
ence to these very difficulties, as it coincides with my own observations and measures,
I have employed it, and, therefore, take the letters he gives.

740. It will be understood that the whole spectrum and all its hues cannot be obtained
at one impression. The difficulty which is in the way of effecting this rests in the
circumstance that different regions of the spectrum act with different power in pro-
ducing the proper effect. Thus, if on common yellow iodide of silver the attempt were
made to procure all the lines at one trial, it would be found that the blue region would
have passed to a state of high solarization, and all its fine lines become extinguished
by being overdone long before any well-marked action could be traced at the less re-
frangible extremity. We have, therefore, to examine the different regions in succes-
sion, exposing the sensitive surface to each for a suitable length of time.

741. In ^jg'. 103, I have given on the left side a representation of the larger lines of
Fraunhofer, the letters being derived, as has been said, from Professor Powell's map.
The position of the lines is, however, copied from my own spectrum as closely as I
have been able to accomplish it.

742. In order that a comparison may be made between the new system of lines and
those of Fraunhofer, the right side of the plate gives a tithonographic representation
of them as obtained on a Daguerreotype plate which has been iodized to the yellow,
brought by the vapour of bromine to the red, and then slightly exposed to the vapour
of chloride of iodine. The map is so adjusted in the plate as to have its lines by the side
of those of Fraunhofer which have the same name. Referring, therefor^, to the plate, it
will be seen that there are, beyond the red ray, three extra-spectral lines, which I have
marked o, /3, y. These, however, I have only occasionally found, for, from the general

DIFFICULTY OF OBTAINING THEM IN THE YELLOW ANT) GREEN. 271

diminution of effect in that region, they do not always come oat in a plain and striking
manner. None of Frau.nhofer's lines in the yellow and green are given, but G and its
companions are very strongly marked, as also the group about i. But by far the most
striking in the whole tithouograph are those marked H and k ; and now, passing beyond
the violet, and out of the visible limits of the spectram, four very striking groups make
their appearance. Theiirst line of each of these groups I have marked, in continuation
of Frai xhofer's nomenclature, M, N, O, P. In L there are three lines, in M five, in
N three, in O three, and in P five.

743. Besides these larger groups, the whole tithonograph is crossed by hundreds of
minuter ones, so that it is utterly impossible to count them. If, as it has been said,
nearly 600 have been counted between A and H, I should think there must be quite
as manv between H and P. In speaking, therefore, of these Hnes as though they were
strong individual ones, the expression is to be taken with some hmitation. It is quite
likely that each of those bolder lines is made up of a great number that are excessively
narrow and close together.

744. If the absorptive action of the sun's atmosphere be the cause of this phenome-
non, that action takes place much more powerfully on the more refrangible and extra-
spectral region. The lines exhibited there are bold and strongly developed ; they are
crowded in groups together.

745. I cannot doubt, judging from analogy, that, by proper modes of investigation,
similar lines might be detected in the calorific extra-spectral region.

746. The contrast between the visible and tithonographic spectra is maintained by
the non-appearance of lines in the yellow and green regions. Once only I thought I
perceived a line corresponding to Fraunhofer's F, but it was exceedingly faint, and,
on the whole, doubtful.

747. Fraunhofer's lines, which occur on the orange, yellow, and green spaces, thus
leaving no corresponding impression, another argument is furnished of the independence
of the tithonic and luminous rays. It is probable that more perfect arrangements than
I iiave used would give the whole spectrum as though it were full of these inactive
spaces ; and in stating that nothing like Fraunhofer's lines exist in those medial re-
gions, I therefore simply wish it to be understood that I can find nothing at all cor-
responding in magnitude to the great lines marked D, E, F, though hundreds of micro-
scopic ones may probably exist in these very spaces.

748. The position of the lines as represented on the sensitive surface is found to be,
as might have been anticipated, independent of the chemical nature of that surface.
The iodide of silver gives them in the same places as the bromide.

749. An argument might be drawn, as has been said, fi-ora the absence of these lines
in the yellow and green spaces, as to the independence of the dark rays and light.
This is, however, only another proof of a fact of which we have now abundant evidence.
In 1S34, when my attention was first fixed forcibly on these things, and I began to
make prismatic analyses by the aid of sensitive paper, some of my first trials were di-
rected to the detection of these fixed lines. At that time I was employing sensitive
paper made with the bromide of silver, precisely as has been subsequently done in Eu-

172 DAGUERREOTYPES ARE DOTTED SURFACES.

rope ; a number of the results were published in the American Journals during the
year 1837. In the detection of these lines I failed entirely; but the bromuretted pa-
per enabled me, at that early period (while the attention of no other chemist was as
yet turned to these matters), to trace the blackening action from far beyond the
confines of the violet down almost to the other end of the spectrum. I distinctly
made out that the dark rays underwent interference after the manner of their luminous
companions, a result originally due to Arago, and printed some long papers in proof
of the physical independence of the chemical rays, and light, and heat, throughout the
spectrum.

750. In a paper " On the Action of the Rays of the Solar Spectrum on the Da-
guerreotype Plate," inserted in the Philosophical Magazine for the month of February,
1843, which has just reached me. Sir John Hekschel points out that a connexion
may be traced between the phenomena of coloration impressed by the spectrum and
those of Newton's rings. With striking ingenuity, he shows how a succession of pos-
itive and negative pictures may arise by prolonged solar action, and those shades of
colour which the iodide of silver exhibits, under variable exposure to light, originate.

751. This hypothesis, however, as that able philosopher proceeds to state, is not
unattended with difficulties, and after pointing out what those difficulties are, he shows
how, nevertheless, it can account for an extensive group of facts. I regret that these
difficulties are in the way, and that there are also other facts which appear to ex-
clude the theory of thin plates from these phenomena.

752. The Daguerreotype image, in all its forms, may he transferred hy any copying
process to other suitable surfaces. In other words, it may he printed from.

Ib^i. Sir David Brewster was the first to show that the colours of mother-of-pearl
might be impressed on any yielding surface. In the same manner so can the Daguerre-
otype image.

754. This is, unquestionably, the most important fact yet known in the history of
these mysterious images, both in a theoretical and in a practical point of view. In
a theoretical point of view, it shows us that it is among the phenomena of grooved, or
striated, or dotted surfaces that the Daguerreotype is to be ranged ; and, in a practical
point of view, it shows the true mode of solving the great problem of producing from
a given proof a nmltitude of copies.

755. In (594), in speaking of the action of isinglass dried on the surface of the
Daguerreotype pictures, I stated that I had succeeded with a process for multiplying
copies, and promised on a future occasion to make it known : that promise I now pro-
ceed to redeem.

756. On referring to the paper in question, the reader will perceive that the follow-
ing facts are stated (577) : that gum-arabic mucilage, dried on a common Daguerre-
otype, splits up, bringing with it the white portions ; that Russian isinglass, (584) and
(591), dried in a similar manner, does tho same thing, and will even rend off the yel-
low coating of iodine if it has not be n previously removed.

757. Now, in addition, I have to state that, if on a picture that has been fixed by a
film of gold, so as to be irremovable, a layi r of isinglass be caused to dry and split up.

MODE OF COPYING THEM BY THE TITHONOTYPE.

173

it will bear on its surface a complete impression of the drawing, all the details bein"'
given with inexpressible beauty, the minutest lines and dots being present

758. From the same plate a series of these impressions may be taken. The imao;es
that are on them may be seen either by reflected or transmitted light ; in the former in-
stance, most favourably by placing them on black velvet

759. I have hopes of improving this method so as to introduce it into efifectaal use.
The practical difficulties that are in the way rest in the circumstance that the isinglass
often splits off in chips instead of separating in one unbroken sheet. And the plate
from which the impressions are taken, or with which the printing process is carrying
on, becomes injured ; not by having its surface removed, but by the isinglass adhering
in circumscribed places, and obstinately refusing to detach itself.

760. This refinement on the art of printing, or, rather, of casting, might be supposed
to give rise to very perishable results. This, however, is far from the case ; I have
now by me proofs made nearly two years ago, and they do not seem to have under-
gone any change. They have lain loosely in a drawer.

761. I presume, therefore, that any process which can exhibit the colours of mother-
of-pearl will also exhibit Daguerreotype images. This lays open a variety of new
branches of the photographic art.

762. As a name for these processes of copying the surface of a Daguerreotype, I
would suggest the word Tithonotype.

763. To carry this process into effect, the operator proceeds as follows : The Da-
guerreotype which he designs to copy is to be covered with a thin film of gold in the
usual way, care being taken that the film is neither too thick nor too thin. If it be too
thick, the resulting copy is injured, and difficulties are more liable to arise in effecting
the separation of the gelatinous coat ; if too thin, the plate itself will suffer injury by-
having the figure torn off.

764. A clear solution of isinglass is next to be prepared ; it must be of such a con-
sistency that a drop of it poured on a cold metallic plate will speedily set. Much of
the success of the process depends on this solution being properly made. There is a
substance in the market which goes under the name of Cooper's isinglass, which I have
found much better than any other for these purposes.

765. The plate is to be arranged horizontally, with its face upward, on some proper
support, in the current of hot air that rises from a stove. The isinglass is to be poured
on until a stratum about i of an inch deep is upon the plate. It is then suffered to
dry, the process being conducted so as to occupy two or three hours. When perfectly
successful, as soon as the drying is complete, the film of isinglass, now indurated into a
tithonotype, splits off, and on being examined either by reflected or tratismitted light, will
be found to bear a minute copj' of the original.

766. To return for a while to the theory of these images. While thns it is plain
that the optical effect depends on surface configuration alone, and does not seem to
have any immediate relation to the thickness or thinness of a film, it is very different
with the chemical effect on which the whole phenomenon depends.

767. T/ie Daguerreotype film, which lias heen under the infiuence of light, is po-
larized throughout its structure previous to mercuriaiization.

174 DARK TITHONIC RAYS.

768. I use the word " polarized" in its chemical sense. An illustration will serve
to show the signification I attach to the term. When water is placed between platina
electrodes, its oxygen is liberated from one of them, and its hydrogen from the other,
and the intervening liquid assumes a polar state, a series of decompositions and combi-
nations going on. As that water is polarized, and undergoes polar decomposition, so,
too, do the same phenomena hold in the case of the Daguerreotype film.

1st. We know that no iodine is ever evolved from the plate, even under the most
prolonged action of the light (587).

2d. The cause of the final appearance of the image is due to silver being liberated on
the anterior face of the plate (592).

3d. When, by the action of gelatine, the iodine and mercury are both removed from
the plate, it is obvious that the plate has been corroded wherever the light fell. Iodine,
therefore, has been evolved on the posterior face of the film, and is the cause of this cor-
rosion.

7G9. From the circumstance, therefore, that iodine is evolved at the back of the film
and silver at its front, and the film itself remaining the same in thickness throughout, it
is obvious that there is a strong resemblance between this phenomena and that of the
polar decomposition of water. The electro-positive and electro-negative elements are
yielded up on opposite faces of the film, and its interior undergoes incessant polar chan-
ges, the opposite electric particles sliding, as it were, on one another.

770. In a note to the preceding chapter (708, &c.) I have described the remarkable
power of certain electro-negative gases in producing the rapid detithonization of sur-
faces that have been changed by light. Since that paper was sent to England, I per-
ceive, from the " Scientific Memoirs," that Professor Moser has published results of a
similar kind. The true explanation of them appears to me to be very different from
that which he gives ; for his idea of vapours containing latent rays of particular orders of
refrangibility or colour, rests on a very feeble analogy, and strikes me as entirely witliout
support.

771. The view which I have taken of these phenomena, and to which allusion was
made in the paper referred to, can be easily understood from what has just been said.
The film on a Dagu-erreotype plate, which has been disturbed by the tithonic rays, but
not yet mercurialized, is in a j^olar condition of force, its iodine is ready to unite with
a new layer of silver behind, its silver is ready to be evolved in front. If it be expo-
sed to mercurial vapours, union at once takes place on that front face, and an amalgam
is formed ; if to the vapours of iodine, or chlorine, or bromine, an iodide, chloride, or
bromide of silver is formed. In an instant, its disturbing afifinities being satisfied, the
film reverts back to its former condition of equilibrium, and is precisely in the condition
it was in before exposure to the light.

DR. DAUBKNY'S EXPERIMENTS. 275

CHAPTER XV.

ON THE DECOMPOSITION OF CARBOMC ACID GAS AND THE ALKALINE CARBONATES BY
THE LIGHT OF THE SUN, AND ON THE TITHONOTY'PE.

{From Ike Lonion, Eialmrgk, and Duilin PkUotopkical Magasine for September, 1843.)

Contents : Dr. Daubeni/'s Experiments. — Importance of the Subject. — Decomposition
in the Prismatic Spectrum. — Decomposition under Absorbent Media. — Decomposition
is due to Light. — Disturbing Causes. — Analysis of Gas evolved. — Decomposition of
Saline Bodies. — Production of Nitrogen. — Disappearance of Oxygen. — Character of
Chlorophyll.

Tithonotypes in Copper. — Detithonizing Potcer of Gases.

772. For many years it has been known that the green parts of plants under the
influence of the sunlight possess the power of decomposing carbonic acid, and setting
free its oxvgen. It is remarkable that this, which is a fundamental fact in vegetable
physiology, should not have been investigated in an accurate manner. The statements
met with in the books are often far from being correct It is sometimes said that pure
oxygen gas is evolved, that the decomposition is brought about by the so-called "chem-
ical rays ;" these, and a multitude of other such errors, pass current. So far as my
reading goes, no one has yet attempted an analysis of the phenomenon by the aid of the
prism, the only way in Avhich it can be truly discussed.

773. In a paper by Dr. Dacbeny, inserted in the Philosophical Transactions for 1836,
two facts, which I shall verify in this communication, are fully established. These are,
1st, the constant occurrence of nitrogen gas in mixture with the oxygen, an observation
originally due to Saussure, or some earlier writer ; and, 2d, that the act of decompo-
sition is due to the light of the sun. This latter result, obtained by employing col-
oured glasses or absorbent media, has not been generally received. Doubt will always
hang about results obtained in this way, and nothing but an analysis by the prism can
be satisfactory. It has happened, therefore, in books of credit published since that time,
that other interpretations of the phenomena have been given. — Johnsons Agr. Chem.,
Lect. v., § 7 ; Graham's Chem., p. 1013. '

774. In its connexions with modern organic chemistry and physiology-, the experi-
ment of the decomposition of carbonic acid by leaves assumes extraordinary interest.
To no other single experiment can the same importance be attached. When we re-
member that this decomposition is the starting-point for organization out of dead mat-
ter, that, commencing with this action of the leaf, the series of organized atoms goes
forw^ard in increasing complexity, and blood, and flesh, and cerebral matter are at its
terminus, it is clear that unusual importance belongs to precise views of this, the com-
mencing change. The beams of the sun are the authors of all organization.

775. There is but one way by which the question can be Anally settled, and that is
by conducting the experiment in the prismatic spectrum itself. When we consider the

176 IMPORTANCE OF THE SUBJECT.

feebleness of effect which takes place by reason of the dispersion of the incident beam
through the action of the prism, and the great loss of light through reflection from its
surface, it might appear a difficult operation to effect a determination in this way. En-
couraged, however, by the purity of the skies in America, I made the trial, and have met
with complete success.

776. Before entering on the experiments which I have to communicate, I cannot
avoid once more impressively calling the attention of chemists to the true character of
those emanations which are here designated "tithonic rays." It is not enough that we
admit the existence, throughout the spectrum, of dark rays, possessing the power of
bringing about chemical changes ; it is not enough that we call them chemical rays ;
there are qualities of distinction appertaining to them which mark them out as being
specific in their kind, properties which they possess totally distinct from those of light
and heat. Their title to the rank of a distinct imponderable agent is just as perfect as
that of light or heat. From heat they are to be distinguished by incapacity for metallic
conduction, and by want of the power of expanding bodies; from light, by failing to
give any impression to the organ of vision. According to the recognised rules of chem-
istry, they ought to be received as a fourth imponderable agent.

777. It is not sufficient, as has been said, to call them '' chemical rays." The term
implies that the distinctive characteristic pertaining to them is the power of changing
the composition of bodies. But do not the rays of heat eminently produce like chan-
ges ? Are not half the decompositions in chemistry brought about by the action of ca-
loric I As respects light, many instances are already known in which it produces de-
compositions and combinations ; as will be presently shown, it is the agent that brings
about the decomposition of carbonic acid. The faculty of producing a like effect is not
the distinguishing quahty of the tithonic rays, nor can the term chemical be any more
applied to them than to either of their acknowledged distinct companions. Unless,
therefore, chemists are content to admit thai a species of heat may exist devoid of the
power of expanding bodies, of giving the sensation of warmth, and of being trans-
mitted by conducting processes ; or, unless they admit that light can exist in such a
modified condition as to produce in our eyes the sensation of darkness, they will have to
admit these tithonic rays as constituting a fourth imponderable agent. The name they
may take is not a matter of importance; that which is least trammelled by hypoth-
esis is best. It is not the object of this and the foregoing chapters to show merely
that a class of invisible rays exists in the spectrum ; that has been known for a long
time ; but it is to point out the true relation of these rays to other bodies and other
forces in the world, to assert for them their title of a fourth distinct imponderable agent,
and to secure for them the admission of that title by giving them a name.

778. When the leaves of plants are placed in water from which all air has been ex-
pelled by boiling, and exposed to the sun's rays, no gas whatever is evolved from them.
When they are placed in common spring or pump water, bubbles quickly form, which,
when collected and analyzed, prove to be a mixture of oxygen and nitrogen gases ;
from a given quantity of water a fixed quantity of air is produced. When they are
exposed in water which has been boiled and then impregnated with carbonic acid, the
decomposition goes on with rapidity, and large quantities of gas are evolved.

DECOMPOSITION IN THE PRISMATIC SPECTRUM.

177

779. The obvious inference which seems to arise from these facts is, that all the ox-
ygen collected is derived from the direct decomposition of carbonic acid We shall
presently examine whether this is the correct inference.

780. Having, by long boiling and subsequent cooling, obtained water free from dis-
solved air, I saturated it with carbonic acid gas. Some grass leaves, the surfaces of
which were carefully freed from any adhering bubbles or films of air by having been
kept beneath carbonated water for three or four days, were provided. Seven glass
tubes, each half an inch in diameter and six inches long, were filled with carbonated
water, and into the upper part of each the same number of blades of grass were
placed, care being taken to have all as near as could be alike. The tubes were in-
serted side by side in a small pneumatic trough of porcelain. It is to be particularly
remarked that the blades were of a pure green aspect, as seen in the water; no glisten-
ing air-film, such as is always on freshly-gathered leaves, nor any air bubbles, were
attached to them. Great care was taken to secure this perfect freedom from air at the
outset of the experiments.

781. The little trough was now placed in such a position that a solar spectrum,
kept motionless by a heliostat and dispersed by a flint-glass prism in a horizontal di-
rection, fell upon the tubes. By bringing the trough nearer to the prism or moving it
farther off", the different coloured spaces could be made to fall at pleasure on the inverted
tubes. The beam of light was about three fourths of an inch in diameter. In a few
minutes after the commencement of the experiment, the tubes on which the orange,
yellow, and green light fell, commenced giving off minute gas bubbles, and in about an
hour and a half a quantity was collected sufficient for accurate measurement

782. The gas, thus collected in each tube, having been transferred to another ves-
sel and its quantity determined, the little trough, with all its tubes, was freely exposed
to the sunshine. All the tubes now commenced actively evolving gas, which, when col-
lected and measured, served to show the capacity of each tube for carrying on the pro-
cess. If the leaves in one were more sluggish, or exposed a smaller surface than the
others, the quantity of gas evolved in that tube was correspondingly less. As may be
readily supposed, I never could get tubes so arranged as to act precisely alike, but after
a little practice I brought them sufficiently near to equahty. And in no instance was
this testing process of the power of each tube for evolving gas omitted after the experi-
ment in the spectrum was over.

TABLE OF THE DECOMPOSITION OF CARBONIC ACID BY LIGHT OF DIFFERENT COLOITRS.

Experiment 1.

Experiment 2. |

Name of Ray.

Volame of Gas.

Name of Kay.

Volume of Gas.

Extreme red . .
Red and orange .
Yellow and green
Green and blue

Blue

Indigo ....
Violet ....

•33

2000
36 00
•10
•00
00
00

Extreme R. and red
Red and orange . .
Yellow and green
Green and blue . .

Blue

Indigo

Violet

•00

24 76

43 75

410

100

•00

•00

783. From this, it appears that the rays which cause the decomposition of carbonic
acid gas have the same place in the spectrum as the orange, the yellow, and the
green ; the extreme red, the blue, the indigo, and the violet exerting no perceptible ef-

Z

278 DECOMPOSITION UNDER ABSORBENT MEDIA.

feet. This being the case, we should expect that, by passing a beam through absorb-
ent media of such a nature that the extreme red, the blue, the indigo, and violet are
absorbed, this decomposition should nevertheless go on. A solution of bichromate of
potash nearly fulfils these conditions, and not only does it absorb the luminous rays in
question, but also all the tithonic rays, except a trace of those which correspond to the
more refrangible yellow and less refrangible green.

784. A remarkable proof of the correctness of the foregoing prismatic annlysis
comes out when leaves are made to act on carbonated water in light which has passed
through a solution of bichromate of potash. I took a wooden box of about a cubic
foot in dimensions, and having removed its bottom, adjusted to it a trough made of
pieces of plate glass. The box being set on end, its lid served as a door, and the
trough being filled with a solution of the bichromate of potash, the sun's beams came
through it, and in the interior of the box an arrangement of leaves and carbonated wa-
ter could be exposed to the rays that had escaped absorption. The thickness of the
liquid stratum was about half an inch. I had several such boxes made, so that I might
compare the simultaneous effect of light which had undergone absorption by different
media. They formed, as it were, a series of little closets in which bodies could be ex-
posed to party-coloured light — blue, yellow, red, &c.

785. Whenever an experiment was commenced in these closets, simultaneously a
similar one was commenced in the unobstructed sunshine. It is needless to repeat,
that in all these care was taken to have the different arrangements for decomposition
as nearly alike as possible.

786. On comparing together the amount of gas evolved in unabsorbed Hght and in
light that had undergone absorption by the bichromate of potash, in three out of five
trials the gas collected under the latter circumstances exceeded in volume that collected
under ihe former ; this was probably due to a slightly higher temperature which obtained
in the box.

787. On comparing together the volumes of gas collected under the bichromate of
potash and under litmus water, the latter was not equal to one half the former.

788. I compared together the gas evolved in unobstructed light, under bichromate of
potash, and under ammonio-sulphate of copper ; the results were as follows :

Unobstructed light .... 4*75
Bichromate of potash . . . 4*25
Ammonio-sulphate of copper . -75

789. Comparing these experiments, made by the aid of absorptive media, with those
made by the prism, we are enabled to come to a definite conclusion as to the character
of the rays which cause this decomposition.

790. The true office of prismatic analysis is to determine the refrangibility of the
rays which produce given actions ; but inasmuch as rays of heat, rays of light, and
tithonic rays are found throughout the spectrum, in many cases the prism fails to indi-
cate to which of these imponderable agents phenomena are to be ascribed. The case
before us furnishes a striking example. Although the decomposition of carbonic acid
is most energetically brought about by rays whose index of refraction corresponds to

DECOMPOSITION IS DUE TO LIGHT. j^79

the yellow, yet that region of the spectram is far from being devoid of heat and tithon-
icity.

791. By considering, however, the prismatic analysis and the absorptive analysis to-
gether, the following facts appear : 1st, the place of maximum action in the spectrum
corresponds to the maximum of illumination ; 2d, at the place of the maximum of
heat (which in the prism here used is beyond the extreme red) no decomposition what-
ever takes effect ; this appears, therefore, to exclude calorific influence ; 3d, the point
of maximum action of the tithonic rays, which escape absorption by the bichromate of
potash, being towards the green, does not correspond with the place of maximum de-
composition, which is the yellow ; this seems to exclude the tithonic rays ; 4th, the de-
composition taking place almost as energetically under the bichromate of potash as in
the unobstructed beams of the sun, and that salt absorbing all but a mere trace of the
tithonic rays, if the effect was due to them it ought to be retarded to an extent cor-
responding to their loss by absorption, which is far fi'om being the case ; the retardation
which is observed appearing to be attributable rather to the loss of light by reflexion
from the faces of the trough, and the partial turbidity (want of translucence) of its
glasses and solutions.

792. For these reasons, I conclude that the decomposition of carbonic acid by the
leaves of plants is brought about by the rays of light ; and that the calorific and
tithonic rays do not participate in the phenomenon. As was stated before, therefore,
the rays of light are just as much entitled to the appellation of chemical rays as those
which have heretofore passed under that name.

793. I might observe, in passing, that there is a degree of precision attached to
results of the decomposition of carbonic acid which is wholly wanting in most similar
experiments. In the stains on Daguerreotype plates, or on photographic papers, though
there is no diflaculty in ascertaining the place of maximum effect, yet nothing in the
shape of absolute measures of quantities can be obtained. When, however, gas can
be collected and its volume determined, as in the voltameter and in the experiments
just described, the results possess a degree of exactness which enables us to draw from
them definite conclusions.

794. Let us now proceed to determine the constitution of the gaseous mixture given
off during these decompositions. It is not pure oxygen, as has often been supposed and
often disproved, but a mixture of oxygen, nitrogen, and carbonic acid. It is mainly to
the ratio of the two former that attention has to be directed; the amount of the latter is
always variable iu different trials. Before proceeding to this, there are certain obser-
vations to be premised, the results of which, though familiar to chemists accustomed to
gaseous analysis, deserve a place here, for they seem to be wholly overlooked in many
of the experiments connected with the so-called respiration, but, rather, digestion of
plants recorded in the books of botany.

795. When gas of any kind is confined over water in the pneumatic trough, its con-
stitution is undergoing incessant change. A portion of it dissolves more or less slowly
in the water, and in exchange it receives from the water gas, which is always dissolved
therein. If two jars, filled with different gases, stand side by side on the shelf, each

180

ANALYSIS OF GAS EVOLVED.

is incessantly disturbing the constitution of the other, nor does this disturbance cease
until the contents of both jars are chemically the same. There are some beautiful ex-
periments of easy repetition wrhich serve to show how rapidly gases and vapours can
thus percolate through fluids. Take a pint bottle, and pass through its cork, which
ought to fit it very loosely, a glass tube a foot long, drawn narrow at its upper end. Into
the bottle put a few drops of water of ammonia. Dip the wide end of the tube into a
solution of soap, and introduce it into the interior of the bottle, adjusting it in such a po-
sition by the cork, that when air is blown in at the narrow end, the soap-bubble which
expands at the wide end may occupy the middle of the bottle. Placing the lips on the
narrow end, blow a bubble an inch or more in diameter, and, without loss of time, cau-
tiously draw back again the air from the interior of the bubble into the mouth. A
strong ammoniacal taste is at once perceived. Now it is obvious that this ammonia
must have passed with very great rapidity through the bubble.

796. A still more instructive experiment may be easily made. Take a three-ounce
bottle, with a wide neck, close the mouth of it by a film of soap-water, by passing the
moistened finger over it. Place it under a jar of protoxide of nitrogen. Instantly the
horizontality of the film is disturbed ; it swells upward, and is spontaneously expanded
by the passage of the gas through it into a bubble. The play of colour which attends
this experiment, and the excessive thinness which the film finally assumes, render this
one of the most beautiful experiments that chemistry can furnish ; for when the bubble
is almost invisible by reason of its incapacity to reflect light, and can only be seen in
particular positions, it still discharges its percolating function.

797. This percolation of gases through liquids cannot be hindered by employing
oil, or such other liquids as botanical writers seem to imagine. Through common
lamp-oil, through copaiva balsam, &c., hydrogen gas will escape with rapidity, and pro-
toxide of nitrogen and carbonic acid still faster. The law that regulates these phenom-
ena is a very simple one : the gas escapes through the confining medium with a rapidi-
ty proportioned to its solubility therein.

798. These things being understood, it is obvious that when carbonic acid is de-
composed in the experiments we have been detailing, a variable portion of that gas will
intermingle with the oxygen collected. The proportions must be variable, for it de-
pends on the amount of carbonic acid remaining behind in the water, on the speed with
which the experiment is conducted, and other variable conditions. As before stated,
therefore, I shall leave out of consideration this carbonic acid, in discussing the analy-
sis of the collected gases, because it is present by accident, and is not essentially con-
nected with the phenomena, except in one instance, where dark heat is to be employed,
as will be described presently.

ANALYSIS OF .AIR EVOLVED FROM CARBONATED WATER BY THE SUN.

Eip.

Name of Plant.

Oxygon.

Nitrogen.

1.

Pinus taeda . . .

1616

8 34

2.

do.

2716

1384

3.

do.

22-33

21-67

4.

Poa annua . . .

9000

10 00

5.

do.

77 90

22 10

799. I may remark, that this table contains a few out of a great number of experi-

DECOMPOSITION OF SALINE BODIES. 2gj

meDts, all of which might have been quoted as examples of the observations which I
wish to deduce from it IsL They all coincide in this respect, that the oxjgen is never
evolved without the simultaneous appearance of nitrogen. 2d. That when certain
leaves are employed, as those of the Pinus tada, there seems to be a very simple rela-
tion between the volumes of oxygen and nitrogen. In the first and second of those ex-
periments, the volume of the oxygen is to that of the nitrogen as two to one ; in the third,
as one to one. In certain cases this apparent simplicity of proportion is departed from;
hot from its frequent occurrence in many analyses I have made, it seems to demand at-
tentive consideration. Moreover, in other plants, as in experiments 4 and 5, the amount
of oxven is relatively greater, and between it and the nitrogen there does not appear
any exact proportion.

800. In order to ascertain whether decompositions taking place under absorbent me-
dia, as bichromate of potash, produce the same results as indicated in the foregoing ta-
ble, I made several analyses of gas collected under these circumstances. The presence
of the absorbent medium did not seem to exert any influence whatever, the general re-
sults coming out as though it had not been employed.

801. It has long been a matter of popular observation that the sunlight has the qual-
ity of extincuishing domestic fires. I do not know whether there is in reality any
ground for this opinion ; or if so, whether the phenomenon is in any way connected
with the relations of light to carbon and oxygen. Popular opinion ascribes the effect
to the light, and not the heat of the ray. To determine whether radiant heat, unaccom-
panied by light, had the power of producing the decomposition of carbonic acid through
the agency of leaves, I placed in the focus of a large brass concave mirror a vessel con-
taining some pine leaves in carbonated water. The mirror was set before a wood fire,
and after a little time the leaves began evolving bubbles. The temperature of the wa-
ter rose as high as 140° Fab., and when sufficient gas was collected, examination proved
that nearly the whole of it was absorbed by lime or potash water. From this, it is
evident that radiant heat merely Uberates the carbonic acid, and does not decompose
it This corroborates, therefore, the result of the prismatic analysis, that it is the Hght,
and not the heat, which brings about the change.

802. Decompositioti of Alkaline Salts. — The conditions under which carbonic acid
gas is decomposed being understood, I pass now to the description of similar decompo-
sitions occurring in the case of saline bodies. It has always been a subject of surprise
to chemists, that the powerfiil affinity by which carbon and oxygen are held together
should be so easily overcome at common temperatures. Even potassium cannot de-
compose carbonic acid in the cold. It might, therefore, be reasonably expected that the
energetic forces which bring about this change ought also to effect other remarkable
decompositions. In fact, as I shall now proceed to show, the decomposition of carbonic
acid is only one of a very numerous series.

803. The alkaline bicarbonates, as is well known, undergo decomposition by a slight
elevation of temperature. When boiled with water they gradually give off their second
atom of acid, and slowly pass into the condition of neutral carbonate. This easy de-
composibility led me to inquire whether green leaves, under the action of the sunlight.

282 DECOMPOSITION OF SALINE BODIES.

would effect the liberation and subsequent reduction of the acid. In the following ex-
periments it is to be observed, that the boiling is not continued long enough to affect
to any extent the constitution of the salt, and in each case any portion of free carbonic
acid extricated during the cooling of the liquid was removed by the action of the air-
pump. The solution, when finally used, contained no gaseous matter, but only the salt
dissolved in water.

804. Having boiled some distilled water to expel all gaseous matter, dissolve in it a
small quantity of bicarbonate of soda. Introduce into a test tube some leaves of grass,
fill the tube with the saline solution, which has been once more boiled to expel any air
it may have obtained from the dissolving salt, and invert the tube in some of the solu-
tion in a wine-glass, after having carefully removed all adhering bubbles of air from the
leaves by a piece of wire, or in any other convenient manner. This arrangement, kept
in the dark, undergoes no change ; but, if brought into the sunshine, bubbles of gas are
rapidly evolved, and in the course of a few hours the tube becomes half full. On de-
tonation with hydrogen this gas proves to be rich in oxygen.

805. I made some attempts to discover how much oxygen could in this way be
evolved from known quantities of bicarbonate of soda, supposing it probable that the
second atom of carbonic acid being removed and decomposed, the process would cease.
I need not detail the result of those trials ; they indicated that the supposition I had
formed was not correct. The process is not limited to the removal and decomposition
of the second atom, but goes forward, the first atom itself being in like manner decom-
posed. From this it would seem that carbonate of soda itself should be decomposed,
and experiment verifies the conclusion ; for, on using that salt instead of the bicarbo-
nate, the evolution of oxygen goes on precisely in the same way.

806. As in these experiments solid salt dissolved in water is decomposed, it is obvious
that the function by which the leaves accomplish this is very different from that of res-
piration. It is not respiration, but a tme digestion.

807. LiEBiG has shown that ammonia exists in the ascending sap. It is probable,
therefore, that it does not undergo final change before reaching the upper face (sky-
face) of the leaf There, if it be in the form of a carbonate, it unquestionably is con-
cerned in decomposition. With the natural experiment before us, we might expect
that the carbonate of ammonia used in place of the soda salts of the last experiment
would yield like them. Accordingly, it will be found, by using the officinal sesqui-
carbonate of ammonia, that leaves effect its decomposition. In numerous experiments
it has yielded me gas frequently containing more than 90 per cent, of oxygen.

808. In every instance which I have examined, the gas evolved from leaves is not
pure oxygen, but, as has been said, a variable mixture of oxygen and nitrogen. This
result is of uniform occurrence ; I have observed it in low latitudes, where the sun is
extremely brilliant, in the case of different plants ; and on referring to Dr. Daubeny's
paper ,it will appear that he has uniformly recognised the same result in England.
The very remarkable qualities which certain nitrogenized substances are known to
exhibit, acting as ferments as they are undergoing decay, might lead to the suspicion
that the decomposition of carbonic acid by leaves is due to the action of some nitro-
genized body, the eremacausis of which is promoted by the rays of the sun.

PRODUCTION OF NITROGEN. 183

. 809. There are many facts which go to prove that the decomposhion of carbonic
acid is a secondary resuh, brought about by the action of nitrogenized ferment in a state
of eremacausis, the sunlight operating in the first instance upon the ferment itself.
Plants can grow in a certain manner in dark places, and if the observations of botanists
have been correctly made, although this kind of growth may be abnormal, it eventuates
in increasing the total weight of carbon. It signifies little that in these instances lignin
may often be deficient, for other bodies of the starch family make their appearance ;
and results of this kind serve to show that, though in all ordinary cases the union of car-
bon with the elements of water is an efiect of hght, there are other cases in which, either
by ferment action, or other powers residing in the plant, the same result can be attained.

810. BoussiNGAULT States that grass leaves dried in air at 212° Fah., and burned with
oxide of copper, yield 1-3 per cent, of their dry weight of nitrogen, which nitrogen is,
of course, in combination. I found, however, that there is, besides this, included in the
tissue of the leaf a certain quantity of gas, which can be removed by the air-pump. I
presume this air is naturally enclosed in the spiral vessels. When leaves are placed in
an inverted jar with boiled water in vacuo, this gas is liberated ; at first, most copiously
from the fractured extremity; but as the process of exhaustion goes on, it exudes from
both faces of the leaf, perhaps by rending open the frail tissue in which it is imprisoned.
In leaves that have stomata on one side only, it does not pour forth from those organs
in preference to other parts, and from this it may be inferred that it does not normally
exist in the intercellular spaces. In a given weight of leaves its amount is very varia-
ble, ranging, in my experiments, from -01 to -02 cubic inch for ten grains of grass leaves.
Its constitution, as determined by analysis, is also variable, but very remarkable ; it con-
tains from 88 to 94 per cent of nitrogen.

811. It being, therefore, understood that in the tissue of the leaf a certain quantity
of gas is mechanically included, which gas differs from atmospheric air in the circum-
stance that it contains a larger volume of nitrogen, which may be removed by the air-
pump, we are in a condition to understand whether it is this nitrogen which furnishes
the supply found in the gas exhaled by leaves. The following experiment proves that
it is not :

812. I removed by continued boiling and exhaustion all the air dissolved in a solu-
tion of bicarbonate of soda. I also removed all the nitrogen from some grass leaves,
by placing them in vacuo immersed in water that had been boiled and subsequently
cooled. Then placing these leaves in the solution of the bicarbonate and in the ves-
sels in which the experiment was finally to be conducted, I kept them in vacuo for an
hour. This was done to get rid of that film of atmospheric air which always adheres
to the surface of glass vessels, and which might have disturbed the result by furnishing
nitrogen. The leaves were now exposed in the saline solution to the beams of the
sun, and presently the evolution of gas commenced. When a sufficient quantity was
collected, it was found to consist of 88 per cent, oxygen and 12 nitrogen.

813. Repetitions of this experiment prove that, although the nitrogen mechanically
enclosed in the leaf to a certain extent mingles with the oxygen evolved, and, indeed,
it could not be otherwise on account of the difiusion of gases into one another, yet the

284 DISAPPEARANCE OF OXYGEN.

true source is to be sought in some nitrogenized compound present in the leaf, which
is undergoing decomposition in a regulated way.

814. Keeping this fact clearly before us, that the source of the nitrogen found thus
in company with the oxygen, given off under the influence of light, is some nitrogeni-
zed body existing in the leaf, the following experiments will show the simple and beau-
tiful law under which this phenomenon is conducted.

815. Saussure has already determined that when plants are forced to grow in an
atmosphere of known volume, containing carbonic acid gas, after the decomposition
of the gas is completed, the total volume remains unchanged. As my experiments were
made with leaves immersed in water, I was desirous of proving whether, under these
forced circumstances, the same result would still hold good.

816. To a certain quantity of water, from which all air had been expelled, confined
in a jar over mercury, I passed 20 measures of carbonic acid gas ; by a little agitation
the water took up 15*50 measures of the acid. I now introduced into the jar some
leaves, taking the greatest care that no bubbles of air should pass along with them.
The jar was then placed in the sunshine, and the decomposition completed. Corrected
for variation of temperature and pressure, the resulting volume of the gas in two experi-
ments was 20, or precisely the same as that of the carbonic acid.

817. We may therefore infer that the volume of mixed gases evolved is precisely
equal to the volume of carbonic acid that disappears. This leads us to some very re-
markable conclusions.

818. When the leaves of plants, under the influence of light, decompose carbonic
acid, they assimilate all the carbon, and a certain proportion of oxygen disappears, at
the same time they emit a volume of nitrogen equal to that of the oxygen consumed.

819. This disappearance of oxygen and appearance of nitrogen are thus connected
with each other : they are equivalent phenomena.

820. The emission of nitrogen is thus shown not to be a mere accidental result,
but to be' profoundly connected with the whole physiological action.

821. I arrive also at this conclusion from experiments of another kind. If the nitro-
gen that appears in company with oxygen were obtained by diffusion from gas mechan-
ically shut up in the parenchyma of the leaf, it is plain, in the mode of operation which
I have followed, in which leaves are immersed under water, and no opportunity given
them of restoring their mechanically included air, if it were by any means withdrawn,
that the first portions of mixed gas evolved should be richest in nitrogen, and that the
per-centage amount should gradually become less and less, as it was removed from the
structure of the leaf: this follows from the laws of the diffusion of gases. But this is
far from being the case. It very commonly happens that more nitrogen is evolved at
tlie close of the process than at its beginning. Thus, in one of the experiments I made,
in which it was found that there was 22-2 per cent, of nitrogen in the total resulting
volume, the quantities that had been evolved in three successive periods of examination,
from the beginning to the termination of the experiment, were,

1st period, 21-8 per cent, of nitrogen.

2d " 18-8

3d " 260 " «

TITHONOTYPES IN COPPER. 286

Dur'ms: the progress of this decomposition, therefore, more nitrogen, relatively, was
evolved towards the close of the experiment than at its beginning.

822. From this result, therefore, I again infer that the nitrogen emitted by leaves is
derived from the decomposition of some azotized body, and not from air mechanically
included in their pores.

823. The following are the experimental results which I have obtained :

l3t. That the nitrogen comes from the tissue of the leaf itself; because more than
three times as much is evolved from bicarbonate of soda as is imprisoned in the struc-
ture of the leaf, removable by the air-pump.

2d. In twelve hours, from bicarbonate of soda, leaves will evolve more than five
times their own volume of gaseous matter.

3d. The quantity of nitrogen in the composition of leaves is sufficient for furnishing
all the nitrogen obtained in the gas evolved. From Boussingault's analyses it ap-
pears that they contain nearly ten times the required amount.

4th. The decomposition of some nitrogenized constituent of the leaf is essential to
the appearance of the nitrogen : there is no other available source.

824. At this stage of the inquiry a remarkable analogy appears between the func-
tion of digestion in animals and the same function in plants. Liebig has shown how,
from the transformation of the stomach itself, food becomes acted upon and is turned into
chyme : an obscure species of fermentation, brought about by the action of nitrogen-
ized bodies. So, in like manner, in plants, the decay of a nitrogenized body is inti-
mately connected with the assimilation of carbon; for, as I have stated, the process
here under discussion is a true digestion and not a respiratory process. And as there
are facts which seem to show that the primary action of the light is not upon the car-
bonic acid, but upon the nitrogenized ferment, the decomposition of the gas ensuing
as a secondary result, « it not probable that chlorophyl is the body which in veg-
etables answers to the chyle of animals f The oxygen, which disappears during ihe
decomposition of carbonic acid, disappears to bring about the eremacausis of the nitro-
genized body. And have not the gum, the starch, the lignin, and other carbonaceous
constituents of plants, all originally existed in and passed through the green stage ? It
is the quality of radiant matter to determine the position of atoms and the grouping of
molecules ; and for this the sun, the great organizer, the great life-giver, from age to
age furnishes his unfading beams. That analogies like this between the organic func-
tions of plants and animals in reality exist, we might reasonably suppose ; they are
agreeable to the general plan of nature.

Note on the Tithonotype.

825. In chapter xiv. I described a process for obtaining tithonotypes, or copies of the
surface of Daguerreotypes, by means of gelatine.

826. A very important improvement on that process — an improvement which, indeed,
has brought it almost at once to perfection — has been effected ; this is. To copy the sur-

Aa

|gg DETITHONIZTNG POWER OF GASES.

face in copper by the electrotype after it has been previously fixed by the agency of a film
of gold.

827. Those who are conversant with these matters will see at once that this is a very
different thing from the abortive attempts which were made early in the history of the
Dao:uerreotype. Many artists endeavoured to transfer its surface hy precipitating cop-
per upon it ; among others, I made trials of the kind. The results of those abortive
attempts were mere shadowy representations, which could be seen in certain lights,
and which were very unsatisfactory in their effect.*

828. The beautiful tithonotypes that are now so common in this city are made in
the following way : The Daguerreotype is carefully gilt by M. Ffzeau's process, taking
care that the film of gold is neither too thick nor too thin. The proper thickness is
readily attained after a little practice. The plate is then kept a day or two, so that it
may become enfilmed with air. The back and edges being varnished, copper is to be
deposited upon it in the usual way, the process occupying from twelve to twenty hours.
If the plate has been properly gilt, and the process conducted successfully, the tithono-
type readily splits off from the Daguerreotype.

829. The reader will understand that, when the process succeeds, the Daguerreotype
will be uninjured, and the tithonotype a perfect copy of it. If any portions are blue,
or white, or flesh-coloured, they will be seen in the same colours in the tithonotype ;
the intensity of light and shadow is also given with accuracy, and, indeed, the copy is
a perfect copy, in all respects, of the original. A great advantage is also obtained in
the reversal that takes place. The right side of the tithonotype corresponds to the right
side of the original object, and the left to the left. In the Daguerreotype it is not so.

830. Copper tithonotypes were first made in this city by Mr. Endicott, a litho-
graphic artist of distinction.

831. There is no great difificulty in obtaining from these tithonotypes duphcate copies.
An expert artist can multiply them from one another.

832. The problem of multiplying the beautiful productions of M. Daguerre is there-
fore solved.

833. I will take this opportunity of making a remark which I intended to have in-
serted in my paper " On the rapid Detithonizing power of certain Gases and Vapours,"
inserted in the March number of the Philosophical Magazine (S. 3, vol. xxii.). Amateurs
in the Daguerreotype process are often annoyed by the want of success which fre-
quently attends them. They ascribe to the atmosphere, or to the light, or to other
causes, their inability to obtain impressions. Most of these mischances are due to the
accidental presence of the vapour of iodine, or other electro-negative bodies, in the
chamber or about the apparatus. It is incredible what a brief exposure to these va-
pours will entirely destroy a picture before it is mercurialized. If the iodine box or the
bromine bottle is kept in the same room with the mercury apparatus, that circumstance
in itself is often sufficient to ensure a uniform want of success. If the little frame which
fits into the back of the camera, and which holds the silver plate, be used in the iodi-

* Professor Grove's voltaic process for etching Daguerreotypes has, however, produced better results than those here
alluded to by Dr. Draper. See Phil. Mag., S. 3, vol. xx , p. 18.— Edit. Phil. Mao.

THE INSTRUMENT CONSISTS OF A MIXTURE OF CHLORINE AND HYDROGEN. ]87

zing process, as is oftea the case, the small quantity of vapour it absorbs will destroy
every picture, or, at all events, increase the time required in the camera enormouslv.
The reason of this is easily understood. Suppose a plate in such a frame be placed in
the camera, or, what comes to the same thing, suppose a particle of iodine has fallen
into the camera, or that the wood has in any way absorbed an electro-negative vapour ;
as fast as the light makes its impression on the sensitive surface the vapour detithonizes
it, and unless the light is quite intense or the exposure much prolonged, a very feeble
proof, or no proof at all, will be obtained. In the same way, the diflSculties are greatly
increased in the process of mercuriahzation ; for the temperature resorted to being high,
if there is the least particle of iodine about the box, the picture will be inevitably and
instantly detithonized and ruined.

834. We ought, therefore, never to allow iodine, or bromine, or chlorine, to have ac-
cess to the apartment or the apparatus in which Daguerreotype operations are being
conducted.

CHAPTER XVI.

DESCRIPTIO.N OF THE TITHONOMETER, AN INSTRUMENT FOR MEASURING THE CHEMICAL

FORCE OF THE INDIGO-TITHONIC RAYS.

{From Ike Lendon, Eimimrgk, mad DuUiH Pkilotopkical Magazine for December, 1843.)

Contexts : The Instrument consists of a Mixture of Chlorine and Hydrogen. — It is
acted upon by Lamp Light, an Electric Spark at a Distance, S^c. — Chlorine and Hydro-
gen unite in Proportion to the Amount of Light. — Mode of measuring out knmcn
Quantities of Rays. — The Maximum of Action is in the Indigo Space. — Construction
of the Instruimnt. — Theoretical Conditions of Equilibrium. — Preliminary Adjust-
ment.— Method of continuous Observation. — Method of interrupted Observation. —
Remarkable Contraction and Expansion.

835. I HAVE invented an instrument for measuring the chemical force of the tithonic
rays which are found at a maximum in the indigo space, and which from that point
gradually fade away to each end of the spectrum. The sensitiveness, speed of action,
and exactitude of this instrument, will bring it to rank, as a means of physical research,
with the thermo-multiplier of M. Melloni.

836. The means which have hitherto been found available in optics for measuring
intensities of light, by a relative illumination of spaces or contrast of shadows, are ad-
mitted to be inexact The great desideratum in that science is a photometer which
can mark down effects by movements over a graduated scale. With those optical
contrivances may be classed the methods hitherto adopted for determining the force of
the tithonic rays by stains on Daguerreotype plates, or the darkening of sensitive pa-
pers. As deductions drawn in this way depend on the opinion of the observer, they
can never be perfectly satisfactory, nor bear any comparison with thermometric results.

188 IT IS ACTED ON BY LAMPLIGHT.

837. Impressed with the importance of possessing, for the study of the properties of
the tithonic rajs, some means of accurate measurement, 1 have resorted in vain to many
contrivances ; and, after much labour, have obtained at last the instrument which it is
the object of this paper to describe.

838. The tithouometer consists, essentially, of a mixture of equal measures of chlo-
rine and hydrogen gases, evolved from and confined by a fluid which absorbs neither.
This mixture is kept in a graduated tube, so arranged that the gaseous surface exposed
to the rays never varies in extent, notwithstanding the contraction which may be going
on in its volume, and the muriatic acid resulting from its union is removed by rapid
absorption.

839. The theoretical conditions of the instrument are, therefore, sufficiently simple ;
but, when we come to put them into practice, obstacles which appear at first sight insur-
mountable are met with. The means of obtaining chlorine are all troublesome ; no
liquid is known which will perfectly confine it ; it is a matter of great difficulty to mix
it in the true proportion with hydrogen, and have no excess of either. Nor is it at all
an easy affiiir to obtain pure hydrogen speedily, and both these gases diffiise with ra-
pidity through water into air.

840. Without dwelling farther on the long catalogue of difficuhies which is thus to
be encountered, I shall first give an account of the capabilities of the instrument in the
form now described, which will show to what an extent all those difficulties are al-
ready overcome. In a course of experiments on the union of chlorine and hydro-
gen, some of which were read at the last meeting of the British Association, I found
that the sensitiveness of that mixture had been greatly underrated. The statement
made in the books of chemistry, that artificial light will not affect it, is wholly erro-
neous. The feeblest gleams of a taper produce a change. No farther proof of this
is required than the tables given in this chapter, in which the radiant source was an
oil-lamp. For speed of action, no tithonographic compound can approach it; a light
which perhaps does not endure the millionth part of a second, affects it energetically,
as will be hereafter shown.

841. Proofs of the Sensitiveness of the Tithonometer. — The following illustrations
will show that the tithonometer is promptly affected by rays of the feeblest intensity,
and of the briefest duration.

842. When, on the sentient tube of the tithonometer, the image of a lamp flame
formed by a convex lens is caused to fall, the liquid instantly begins to move over the
scale, and continues its motion as long as the exposure is continued. It does not
answer to expose the tube to the direct emanations of the lamp without first absorbing
the radiant heat, or the calorific effect will mask the true result. By the interposition
of a lens this heat is absorbed, and the tithonic rays alone act.

843. If a tithonometer is exposed to daylight coming through a window, and the hand,
or a shade of any kind, is passed in front of it, its movement is in an instant arrested ;
nor can the shade be passed so rapidly that the instrument will fail to give the
proper indication.

844. The experimenter may farther assure himself of the extreme sensitiveness of

AND BY AN ELECTRIC SPARK AT A DISTANCE. 289

this mixture by placing the instrument before a window, and endeavouring to remove
and replace its screen so quickly that it shall fail to give any indication ; he will find
that it cannot be done-

845. Charge a Leyden vial, and place the tithonometer at a little distance from it,
keeping the eye steadily fixed on the scale ; discharge the jar, and the rays from the
spark will be seen to exert a vefy powerful effect, the movement taking place and ceas-
ine in an instant

846. This remarkable experiment not only serves to prove the sensitiveness of the
titl)onometer. but also brings before us new views of the powers of that extraordinary
agent, electricity. That energetic chemical effects can thus be produced at a distance
by an electric spark in its momentarv passage, effects which are of a totally different
kind from the common manifestations of electricity, is thus proved ; these phenomena
being distinct from those of induction or molecular movements taking place in the line
of discharge, they are of a radiant character, and due to the emission of tithonicity ;
and we are led at once to infer that the well-known changes brought about by passing
an electric spark through gaseous mixtures, as when oxygen and hydrogen are com-
bined into water, or chlorine and hydrogen into muriatic acid, arise from a very differ-
ent cause than those condensations and percussions by which they are often explained,
a cause far more purely chemical in its kind. If chlorine and hydrogen can be made
to imite silently by an electric spark passing outside the vessel which contains them, at
a distance of several inches, there is no difficulty in understanding why a similar effect
should take place with a violent explosion when the discharge is made through their
midst, nor how a great many mixtures may be made to unite under the same treat-
ment A flash of Ughtniug cannot take place, nor an electric spark be discharged,
without chemical changes being brought about by the radiant matter emitted-

847. Proofs of the Exactness of the Indications of the Tithonometer. — The foregoing
examples may serve to illustrate the extreme sensitiveness of the tithonometer ; I shall
next furnish proofs that its indications are exactly proportional to the quantities of fight
incident on it

848. As it is necessary, owing to the variable force of daylight, to resort to artifi-
cial means of illumination, it will be found advantageous to employ the following method
of obtaining a flame of suitable intensity :

849. Let A B {Jig. 104) be an Argand oil lamp, of which the wick is C. Over the
wick, at a distance of half an inch, or thereabout, place a plate of thin sheet copper,
three inches in diameter, perforated in its centre with a circular hole of the sauie di-
ameter as the wick, and concentric therewith. This piece of copper is represented at
d d; it should have some contrivance for raising or depressing it through a small space,
the proper height being determined by trial. On this plate the glass cylinder, e, an inch
and three quarters in diameter, and eight or ten inches long, rests.

850. When the lamp is lighted, provided the distance between the plate, d d, and the
top of the wick is properly adjusted, on putting on the glass cylinder the flame instantly
assumes an intense whiteness; by raising the wick it may be elongated to six inches or
more, and becomes exceedingly brilliant. Lamps constructed on these principles may

190

CHLORINE AND HYDROGEN UNITE IN PROPORTION TO THE

be purchased in the shops. I have, however, contented myself with using a common
Argand study-lamp, supporting the perforated plate, d d, at a proper altitude by a retort
stand. It will be easily understood that the great increase of light arises from the cir-
cumstance that the flame is drawn violently through the aperture in the plate by the
current established in the cylinder.

851. As much radiant heat is emitted by this flame, in order to diminish its action,
and also to increase the tithonic effect, 1 adopt the following arrangement: Let A B
{^/ig. 104) be the lamp; the rays emitted by it are received on a convex lens, D, four
inches and three quarters in diameter, that which I use being the large lens of a lucer-
nal microscope. This, placed at a distance of twenty-one inches from the lamp, gives
an image of the flame at a distance of thirteen inches, which is received on the sen-
tient tube of the tithonometer, F ; between the tithonometer and the lens there is a
screen, E.

852. Things being thus arranged, and the lamp lighted so as to give a flame about
three inches and a half long, the experiments may be proceeded with. It is convenient
always to work with the flame at a constant height, which may be determined by a
mark on the glass cylinder. At a given instant, by a seconds watch, the screen E is
removed, and immediately the tithonometer begins to descend. When the first minute
is elapsed, the position on the scale is read off" and registered : at the close of the sec-
ond minute the same is done, and so on with the third. &c. And now, if those num-
bers be compared, casting aside the first, they will be found equal to one another, as
the following table of experiments, made at different times and with different instru-
ments, shows :

TABLE I.

Showing that, when the radiant source is constant, the amount of movement in the tithonometer is directly proportional to the times

of exposure.

Time.

Experiments. |

1.

2.

3.

4.

5.

30"

60

90
130
150
180
210

700
8 00
750
7.75
7-75

700
875
800
7-75
7-25

1025
11 50
11 .50
1150

11.75
1300
1200

525
650
625
600
6 00
600
600

Mean

7 60

7-55

11 19

12 25

6U0

From this it will be perceived that, taking the first experiment as an example, if
at the end of 30 seconds the tithonometer has moved 7"00, at the end of 60" it has
moved 8-00 more ; at the end of 90", 7-50 more ; at the end of 120", 7-75 more : the
numbers set down in the vertical column representing the amount of motion for each
thirty seconds. And when it is recollected that the readings are all made with the
instrument in motion, the differences between the numbers do not greatly exceed the
possible errors of observation. It may be remarked that the third and fourth experi-
ments were made with a different lamp.

853. Though a certain amount of radiant heat from a source so highly incandescent
as that here used will pass the lens, its effects can never be mistaken for those of the
tithonic rays. This is easily understood when we remember that the effect of such

AMOUNT OF LIGHT.

191

transmitted heat would be to expand the gaseous mixture, but the tithonic effect is to
contract it

854. Next I shall proceed to show that the indications of the tithonometer are strictly
proportional to the quantity of rays that have impinged upon it; a double quantity pro-
ducing a double effect, a triple quantity a threefold effect, &c.

8-55. A sUght modification in the arrangement {Jig. 104) enables us to prove this in
a satbfactory way. The lens, D, being mounted in a square wooden frame, can easily
be converted into an instrument for delivering at its focal point, where the sentient
tube is placed, measured quantities of the tithonic rays, and thus becomes an invaluable
auxiliary in those researches which require known an:i predetermined quantities of tithon-
icity to be measured ouL The principle of the modification is easily apprehended.
If half the surface of the lens be screened by an opaque body, as a piece of blackened
cardboard, of course only half the quantity of rays will pass which would have passed
had the screen not been interposed. If one fourth of the lens be left uncovered, only
one fourth of the quantity will pass; but in all these instances the focal image remains
the same as before. By adjusting, therefore, upon the wooden frame of the lens two
screens, the edges of which pass through its centre, and are capable of rotation upon
that centre, we shall cut off all light when the screens are applied edge to edge; we
shall have 90° when they are rotated so as to be at right angles, and 180° when they
are superposed with their edges parallel. Thus, by setting them in different angular
positions, we can gain all quantities from 0° up to 180°, and by removing them entirely
away, reach 360°.

856. It will be understood that the effect of the instrument is to give an image of a
visible object, of which the intensitv can be made to vary at pleasure in a known pro-
portion.

857. In order, therefore, to prove that the indications of the tithonometer are pro-
portional to the quantity of impinging rays, place this measuring lens in the position D,
setting its screens at an angle of 90°. Remove the screen E, and determine the effect
on the tithonometer for one minute. At the close of the minute, and without loss of
time, turn one of the screens so as to give an angle of 180% and now the effect will be
found double what it was before, as in the following table :

TABLE n.
Skotmg that the InHeatiaiu of tkt Tithonometer are proponumat to the jutntity of Inddent Rtof*.

Qautitics.

EifwruDTOt 1. ■ Eiprnmeal a. |

Otaerrad.

Cilmlit .

VHxrrrfA.

Cmlnlalfd.

90°
180
270
360

318

4^
670

890

222
4 45
667
890

269

575

825

1100

2-75

5.50

825

1100

858. I have stated in the commencement of this paper, that the action upon the
tithonometer is limited to a ray which corresponds in refrangibility to the indigo, or,
rather, that in the indigo space its maximum action is found. The following table
serves at once to prove this fact, and also to illustrate the chemical force of the different
regions of the spectrum :

192

CONSTRUCTION OF THE INSTRUMENT.

TABLE III.
Showing that the Maximum for the Tilhonometcr is in the Indigo Space of the Spectrum.

Space.

Ray.

Force.

Space.

Ray.

Force.

0

Extreme red

■33

8

Blue-indigo . .

204 00

1

Red . . .

60

9

Indigo . . .

240 00

s

Orange . .

•75

10

Violet .

12100

3

Yellow . .

276

11

Violet. . . .

72 00

4

Green . .

1000

12

Violet. . . .

48 00

5

Green-blue

54 00

13

Violet. . . .

24 00

6

Blue . . .

108 00

14

Extra-spectral .

1200

7

Blue . . .

144 00

In this table the spaces are equal ; the centre of the red, as insulated by cobalt blue
glass, is marked as unity ; the centre of the yellow, insulated by the same, being marked
3 ; the intervening region being divided into two equal spaces, and divisions of the
same value carried on to each end of the spectrum.

859. As instruments will no doubt be hereafter invented for measuring the phenom-
ena of different classes of rays, it may prove convenient to designate the precise ray to
which they apply. Perhaps the most simple mode is to affix the name of the ray itself.
Under that nomenclature, the instrument described in this paper would take the name
of indigo-tithonometer.

860. There is no difficulty in adapting this instrument to the determination of ques-
tions relating to absorption, reflexion, and transmission. Thus, I found that a piece of
colourless French plate-glass transmitted 866 rays out of 1000.

861. Description of ths Instrument. First, of the Glass Part. — The tithonometer
consists of a glass tube bent into the form of a siphon, in which chlorine and hydro-
gen can be evolved from muriatic acid, containing chlorine in solution, by the agency
of a voltaic current. It is represented hy Jig. 105. where a i c is a clear and thin tube,
four tenths of an inch external diameter, closed at the end, a. At d, a circular piece
of metal an inch in diameter, which may be called the stage, is fastened on the tube,
the distance from d to a being 2*9 inches. At the point x, which is two inches and a
quarter from d, two platina wires, x and y, are fused into the glass, and, entering into the
interior of the tube, are destined to furnish the supply of chlorine and hydrogen ; from
the stage, d, to the point b, the inner bend of the tube is 2-6 inches, and from that
point to the top of the siphon, c, the distance is three inches and a half Through
the glass at z, three quarters of an inch from c, a third platina wire is passed ; this wire
terminates in the Httle mercury cup, r, and x and y in the cups p and q respectively.

862. Things being thus arranged, the instrument is filled with its fluid, prepared as
will presently be described ; and as the legs, a b,b c, are not parallel to each other, but
include an angle of a few degrees, in the same way that Ure's eudiometer is arranged,
there is no difficulty in transferring the liquid to the sealed leg. Enough is admitted
to fill the sealed leg and the open one partially, leaving an empty space to the top of
the tube, at c, of two and three quarter inches.

863. A stout tube, six inches long and one tenth of an inch interior diameter, ef is
now fused on at c. Its lower end opens into the main siphon tube ; its upper end is
turned over atf and is narrowed to a fine termination, so as barely to admit a pin,
but is not closed. This serves to keep out dust, and in case of a little acid passing out,
it does not flow over the scale and efface the divisions. At the back of this tube a

CONSTRUCTION OF THE INSTRUMENT. ^93

scale is placed, divided into tenths of an inch, being numbered from above downward.
Fiftv of these divisions are as many as will be required. Fig. 106 shows the termi-
nation of the narrow tube bent over the scale.

864. From a point one fourth of an inch above the stage, d, downward beyond the
bend, and to within half an inch of the wire, z, the whole tube is carefully painted with
India ink, so as to allow no light to pass ; but all the space from a fourth of an inch
above the stage, d, to the top of the tube, a, is kept as clear and transparent as possible.
This portion constitutes the sentient part of the instrument. A light metallic or paste-
board cap, A D (Jig. 107), closed at the top and open at the bottom, tliree inches long
and six tenths of an inch in diameter, blackened on its interior, may be dropped over
this sentient tube ; it being the oflSce of the stage, d, to receive the lower end of the
cap when it is dropped on the tube so as to shut out the light.

865. The foot of the instrument, k I, is of brass; it screws into the hemispherical
block, m, which may be made of hard wood or ivory ; in this three holes, p, q, r, are
made to serve as mercury cups; they should be deep and of small diameter, that the
metal may not flow out when it is inclined for the purpose of transferring. A brass cylin-
drical cover, L M, L M, may be put over the whole ; when it is desirable to preserve
it in total darkness, it should be blackened within.

866. Seco7idly, of the Fluid Part. — The fluid from which the mixture of chlorine
and hydrogen is evolved, and by which it is confined, is yellow commercial muriatic
acid, holding such a quantity of chlorine in solution that it exerts no action on the mixed
gases as they are produced. From the mode of its preparation, it always contains a
certain quantity of chloride of platina, which gives it a deep golden colour, a condition
of considerable incidental importance.

867. When muriatic acid is decomposed by voltaic electricity, its chlorine is not
evolved, but is taken up in very large quantity and held in solution ; perhaps a bichlo-
ride of hydrogen results. If through such a solution hydrogen gas is passed in minute
bubbles, it removes with it a certain portion of the chlorine. From this, therefore, it
is plain that muriatic acid thus decomposed will not yield equal measures of chlorine
and hydrogen, unless it has been previously impregnated with a certain volume of the
former gas. Nor is it possible to obtain that degree of saturation by voltaic action, no
matter how long the electrolysis is continued, if the hydrogen is allowed to pass through
the liquid.

868. Practicallv, therefore, to obtain the tithonometric liquid, we are obliged to de-
compose commercial muriatic acid in a glass vessel, the positive electrode being at the
bottom of the vessel and the negative at the surface of the liquid. Under these circum-
stances, the chlorine, as it is disengaged, is rapidly taken up, and the hydrogen being
set free without its bubbles passing through the mass, the impregnation is carried to
the point required.

869. Although this chlorinated muriatic acid cannot, of course, be kept in contact
with the platina wires without acting on them, the action is much slower than might
have been anticipated. I have examined the wires of tithonometers that have been in
active use for four months and could not perceive the platina sensibly destroyed. It is

Bb

294 THEORETICAL CONDITIONS OF EQUILIBRIUM.

well, however, to put a piece of platina foil in the bottle in which the supply of chlori-
nated muriatic acid is kept : it communicates to it slowly the proper golden tint.

870. The liquid, being impregnated with chlorine in this manner until it exhales the
odour of that gas, is to be transferred to the siphon, a b c, oi the tithonometer, and its
constitution finally adjusted as hereafter shown.

871. Thirdly, of the Voltaic Battery. — The battery which will be found most appli-
cable for these purposes consists of two Grove's cells, the zinc surrounding the platina.

872. The following are the dimensions of the pairs which I use. The platina plate
is half an inch wide and two inches long ; it dips into a cylinder of porous biscuit-
ware of the same dimensions, which contains nitric acid. Outside this porous vessel
is the zinc, which is a cylinder one inch diameter, two inches long, and two tenths
thick ; it is amalgamated. The whole is contained in a cup two inches in diameter
and two deep, which receives the dilute sulphuric acid.

873. The force of this battery is abundantly sufficient both for preparing the fluid
originally and for carrying on the tithonometric operations ; it can decompose muriatic
acid with rapidity, and will last, with ordinary care, for a long time.

874. Before passing to the mode of using the tithonometer, it is absolutely necessary
to understand certain theoretical conditions of its equilibrium ; to these in the next
place I shall revert.

875. Theoretical Conditions of Equilibrium. — The tithonometer depends for its sen-
sitiveness on the exact proportion of the mixed gases. If either one or the other is in
excess, a great diminution of delicacy is the result. The comparison of its indications
at different times depends on the certainty of evolving the gases in exact, or, at all events,
known proportions.

876. Whatever, therefore, affects the constitution of the sentient gases, alters, at the
same time, their indications. Between those gases and the fluid which confines them
certain relations subsist, the nature of which can be easily traced. Thus, if we had
equal measures of chlorine and hydrogen, and the liquid not saturated with the former,
it would be impossible to keep them without change, for, by degrees, a portion of chlo-
rine would be dissolved, and an excess of hydrogen remain ; or, if the liquid was over-
charged with chlorine, an excess of that gas would accumulate in the sentient tube.

877. It is absolutely necessary, therefore, that there should be an equilibrium be-
tween the gaseous mixture and the confining fluid.

878. As has been said, when muriatic acid is decomposed by a voltaic current, all
the chlorine is absorbed by the liquid, and accumulates therein ; the hydrogen bubbles,
however, as they rise, withdraw a certain proportion, and hence pure hydrogen passed up
through the tithonometric fluid becomes exceedingly sensitive to the light.

879. There are certain circumstances connected with the constitution and use of
the tithonometer which continually tend to change the nature of its hquid. The pla-
tina wires immersed in it, by slow degrees, give rise to a chloride of platina. It is true
that this takes place very gradually, and by far the most formidable difficulty arises from
a direct exhalation of chlorine from the narrow tube ef, for each time that the liquid
descends, a volume of air is introduced, which receives a certain amount of chlorine,

DIRECTIONS FOR USING THE TITHONOMETER.

195

which, with it, is expelled the next time the battery raises the column to zero ; and
this, going on time after time, finally impresses a marked change on the liquid I have
tried to correct this in various ways, as by terminating the end/ witli a bulb ; bat this
entails great inconvenience, as may be discovered by any one who will reflect on its
operation.

880. When by the battery we have raised the index to its zero point, if the gas and
hquid are not in equilibrio, that zero is liable to a slight change. If there be hydrogen
in excess, the zero will rise; if chlorine, the zero will fall.

881. In making what will be termed " interrupted experiments," we must not too
hastily determine the position of the index on the scale at the end of a trial. It is to
be remembered that the cause of movement over the scale arises from a condensation
of muriatic acid, but that condensation, though very rapid, is not instantaneous. Where
time is valuable, and the instrument in perfect equihbrium, this condensation mav be
instantaneously effected by simply inchning the instrument so that its liquid may pass
down to the closed end a, but not so mnch as to allow gas to escape into the other
leg ; the inclination of the two legs to each other makes this a very easy manipulation,
and the gas, thus brought into contact with an extensive liquid surface, yields up its mu-
riatic acid in a moment

882. Directions for using the Tithonometer. Preliminary Adjustment. — Having
transferred the liquid to the sealed end of the siphon, and placed the cap on the sen-
tient extremity, the voltaic battery being prepared, the operator dips its polar wires into
the cups p g, which are in connexion with the wares x y. Decomposition immediate-
ly takes place, chlorine and hydrogen rising through the Hquid, and gradually depress-
ing it, while, of course, a corresponding elevation takes place in the other limb ; this
operation is continued until the liquid has risen to the zero. It takes but a few seconds
for this to be accomplished.

883. The polar wires having been disengaged, the tithonometer is removed opposite
a window, care being taken that the light is not too strong. The cap is now lifted off
the sentient extremity, a d, and immediately the liquid descends. This exposure is
allowed to continue, and the liquid suffered to rise as much as it will to the end a.
And now, if the gases have been properly adjusted, an entire condensation will take
place, the sentient tube a d filling completely. In practice, this precision is not, how-
ever, obtained ; and if a bubble as large as a peppercorn be left, the operator will be
abundantly satisfied with the sensitiveness of his instrument. Commonly, at first, a
large residue of hydrogen gas, occupying, perhaps, an inch or more, will be left It is
to be understood that even this large surplus will disappear in a few hours by absorb-
ing chlorine. But this is not to be waited for : as soon as no farther rise takes place
in a minute or two, the siphon is to be inclined on one side, and the residue turned out
into the open leg.

884. Now, recurring to what has been said on the equilibrium, it is plain that this
excess of hydrogen arises from a want of chlorine in the tithonometric liquid. A proper
quantity must, therefore, be furnished by proceeding as follows:

885. The sentient tube being filled with the liquid by inclination, connect the polar

.196 METHODS OF CONTINUOUS AND INTERRUPTED OBSERVATION.

wires with p q, as before. These may be called generating wires. Allow the liquid to
rise in b c until the third platina wire, z, which may be called the adjusting wire, is
covered au eighth of an inch deep. Then remove the negative wire from the cup p
into the cup r, and now the conditions for saturating the liquid are complete ; hydro-
gen escaping away from the surface of the liquid at z, and chlorine continually accu-
mulating and dissolving between x and d. This having been carried on for a short
time, the gas in a d is to be turned out by inclination, and the instrument recharged.
That a proper quantity is evolved is easily ascertained by allowing total condensation
to take place, and observing that only a small bubble is left at a.

88G. It will occasionally happen in this preliminary adjustment, that an excess of
chlorine may arise from continuing the process too long. This is easily discovered by
its greenish-yellow tint, and is to be removed by inclining the instrument and turning
it out.

887. Thus adjusted, everything is ready to obtain measures of any effect, there being
two different methods by which this can be done: 1st, by continuous observation; 2d,
by interrupted observation.

888. Of the Method of Continuous Observation. — This is best described by resorting
to an example. Suppose, therefore, it is required to verify Table I., or, in other words,
to prove that the effect on the tithonometer is proportioned to its time of exposure.

Put on the cap of the sentient tube a d, connect the polar wires with p q, and raise
the liquid to zero.

Place the tithonometer so that its sentient tube will receive the rays properly.

At a given instant, marked by a seconds watch, remove the cap A D, and the liquid
at once begins to descend. At the end of the first minute read off the division over
which it is passing. Suppose it is 7. At the end of the second do the same, it should
be 14 ; at the end of the third, 21, &c., &c. This may be done until the fiftieth divis-
ion is reached, which is the terminus of the scale.

Recharge the tube by a momentary application of the polar wires : but it is conve-
nient first to remove any excess of muriatic acid gas in the sentient tube, by allowing it
time for condensation ; or, if that be inadmissible, by inclining a little on one side, so as
to give an extensive liquid contact.

889. Of the Metlwd of Interrupted Observation. — It frequently happens that obser-
vations cannot be had during a continuous descent, as when changes have to be made
in parts of apparatus or arrangements. We have, then, to resort to interrupted obser-
vations.

This method requires that the gas and liquid should be well adjusted, so that no
change can arise in volume when extensive contact is made by inclination.

The tithonometer being charged, place it in a proper position. At a given instant
remove its cap, and the liquid descends. When the time marked by a seconds watch
has elapsed, drop the cap on the sentient tube. The liquid simultaneously pauses in
its descent, but does not entirely stop, for a httle uncondensed muriatic acid still exists,
which is slowly disappearing in the sentient tube. Now incline the instrument for a
moment on one side, so that the liquid may run up to the end a, but not so much as to

REMARKABLE CONTRACTION AND EXPANSION. 297

let any gas escape. Restore it to its jjosition, and read off on the scale. It is then
ready for a second trial.

890. The difference between continuous and interrupted observation is this, that in
the latter we pause to wash out the muriatic acid ; and though this is effected by the
simplest of all possible methods, continuous observations are always to be preferred
when they can be obtained.

891. I have extended this paper to so great a length that many points on which re-
marks might have been made must be passed over. It is scarcely necessary to say that
the sentient tube must be uniformly and perfectly clean. As a general rule, also, the
first observation may be cast aside, for reasons which I will give hereafter. Farther, it
is to be remarked, as it is an essential principle that during different changes of volume
of the gas its exposed surface must never vary in extent, the liquid is not to be suffered
ro rise above the blackened portion at d. If the measures of the different parts be such
as have been here given, this cannot take place, for the liquid will fall below the fiftieth
division before its other extremity rises above d.

892. The same original volume of gas in a d will last for a long time, as we keep
replenishing it as often as the fiftieth division is reached.

893. The experimenter cannot help remarking, that on suddenly exposing the sen-
tient tube to a bright hght, the liquid for an instant rises on a scale, and on dropping the
cap, in an instant falls. This important phenomenon, which is strikingly seen under
the action of an electric spark, I shall consider hereafter.

894. In conclusion, as to comparing the tithonometric indications at different times,
if the gases have the same constitution, the observations will compare ; and if they have
not, the value can from time to time be ascertained by exposure to a lamp of constant
intensity. To this method I commonly resort

895. From the space occupied in this description the reader might be disposed to
infer that the tithonometer is a very complicated instrument, and difficult to use. He
would form, however, an erroneous opinion. The preliminary adjustment can be made
in five minutes, and with it an extensive series of measures obtained. These long
details have been entered into that the theory of the instrument may be known, and
optical artists construct it without difficulty. Though surprisingly sensitive to the ac-
tion of the indigo ray, it is as manageable by a careful experimenter as a common dif-
ferential thermometer.

198 TITHONIZED CHLORINE.

CHAPTER XVII.

ON TITHONIZED CHLORINK.

Contents : Description of the Experiment. — The Change in the Chlorine is not
Transient. — There are ttvo Stages in the Phenomenon. — Rays are absorbed in
2}roducing this Change. — It is the Indigo Ray which is absorbed. — The Action is
positive from End to End of the Spectrum. — The Indigo Ray forms Muriatic Acid,
as well as produces the Preliminary Tithonization. — Change in other Elementary
Bodies. — Verification of the preceding Results with the Tithonometer.

{From the London, Edinburgh, and Dublin Philosophical Magazine for July, 1844.)

896. Chlorine gas, which has been exposed to the daylight or to sunshine, possesses
quahties which are not possessed by chlorine which has been made in the dark.

897. This is shown by the circumstance that chlorine which has been exposed to
the sunshine has obtained from that exposure the property of speedily uniting with hy-
drogen gas ; a property not possessed by chlorine which has been made and kept in
the dark.

898. This quality gained by the chlorine arises from its having absorbed tithonic
rays corresponding in refrangibihty to the indigo. Ii is not a transient, but apparently
a permanent property, the rays so absorbed becoming latent, and the effect lasting for
an unknown period of time. The facts which I shall proceed to describe will be in-
teresting to chemists, because they plainly lead us to suspect that the descriptions we
have of the properties of all elementary and compound bodies are either inaccurate or
confused. These properties are such as bodies exhibit after they have been exposed
to the light ; we still require to know what are the properties they possess before ex-
posure to such influences.

899. Natural philosophers will also find an interest in these phenomena, for they
finally establish for the tithonic rays two important facts : 1st, that those rays are ab-
sorbed by ponderable bodies ; and, 2d, that they become latent after the manner of heat
Some years ago I endeavoured to prove that these things held for a compound sub-
stance the iodide of silver (Phil. Mag., Sept., 1841).

900. For reasons which will be obvious as the description proceeds, I shall speak
of chlorine which has been exposed to the beams of the sun as tithonized chlorine.

I. Description of the Experiment.

901. In two similar white glass tubes place equal volumes of chlorine, which has
been made from peroxide of manganese and muriatic acid by lamplight, and carefully
screened from access of daylight. Expose one of the tubes to the full sunbeams for
some minutes, or, if the light be feeble, for a quarter of an hour : the chlorine which is
in it becomes tithonized. Keep the other tube during this time carefully in a dark
place ; and now, by lamplight, add to both equal volumes of hydrogen gas. These

DESCRIPTION OF THE EXPERIMENT. 299

processes are best carried on in a small porcelain or earthenware trough, filled with a
saturated solution of common salt, which dissolves chlorine slowly ; and to avoid ex-
plosions, operate on limited quantities of the gases. Tubes that are eight inches long
and half an inch in diameter will answer very well. The two tubes now contain the
same gaseous mixture, and only differ in the circumstance that one is tithonized and
the other not. Place them, therefore, side by side before a window, through which the
entrance of daylight can be regulated by opening the shutter ; and now, if this part of
the process is conducted properly, it will be seen that the tithonized chlorine com-
mences to unite with the hydrogen, and the salt water rises in that tube. But the un-
tithonized chlorine shows no disposition to unite with its hydrogen, and the liquid in
its tube remains motionless for a long time. Finally, as it becomes slowly tithonized
by the action of the daylight impinging on it, union at last takes place. From this,
therefore, we perceive that chlorine which has been exposed to the sun will unite
promptly and energetically with hydrogen ; but chlorine that has been made and kept
in the dark shows no such property.

902. As I doubt not this remarkable experiment will be repeated by chemists, I will
add that the only point to which attention in particular is to be given, is in the final
exposure to the light. This must not be too feeble, or the action will be tedious ; but
the direct sunbeam must be sedulously excluded, or an explosion will result. A room
illuminated by one small window, looking to the north, answers very well. It need
scarcely be added, that care must be taken that both tubes are illuminated alike.

II. The Change in tJie Chlorine is not Transient.

903. Now it might be supposed that this apparent exaltation of the electro-negative
properties of the chlorine is only a transient thing which would speedily pass away,
the gas reverting to its original untithonized condition.

904. To show that this is not so, tithonize some chlorine in a tube as before. Place
It for an hour or two in the dark along with the tube of untithonized chlorine, with
which it is to be compared ; then to both add hydrogen. Expose them, as in the for-
mer experiment, to the daylight, and the result will turn out as before, the tithonized
chlorine forming muriatic acid at once, and the untithonized refusing to do so.

905. This, therefore, shows that the change which the sunbeams impress upon
chlorine is to a certain extent a permanent change, and, unlike a calorific effect, it does
not spontaneously and rapidly pass away.

III. There are two Stages in the Phenomenon.

906. Let us now proceed to make an inquiry into the nature of the change thus im-
pressed on the chlorine. This, I shall show, rests in the circumstance of the absorption
of rays which correspond in refrangibility to the indigo, and which appear to become
latent.

907. In a tube, over salt water, mix together equal volumes of untithonized chlorine
and hydrogen gas. Expose it to the daylight, marking the time at which the exposure
commences. Watch the level of the liquid in the tube narrowly, and, though station-

OQO RAYS ARE ABSORBED.

ary for a considerable time, after a certain period has elapsed it will be seen on a sud-
den to start and commence rising. Observe now how far it will rise during a period
which is equal to the time that elapsed between the first exposure and the beginning
of the rise, and it will be seen that one fourth or half of the gases will disappear.

908. It is obvious that from the first moment of exposure the rays must have been
exerting their influences on the mixture. As will presently be proved, absorption has
been all along taking place. There are, therefore, two distinct phenomena exhibited
by this experiment. There is a period during which, though large quantities of the
dark rays are disappearing, no visible change is produced ; there is a second period,
during which absorption is accompanied by a remarkable chemical effect, the produc-
tion of muriatic acid. From these things we gather that a definite amount of the
tithonic rays must disappear and become latent before muriatic acid can form. The
phenomenon is not unlike that of the disappearance of a definite quantity of heat in the
passage of ice into the condition of water.

909. A mixture of chlorine and hydrogen does not, therefore, instantly give rise to
the production of muriatic acid on exposure to the light, but, as a preliminary condition,
a certain definite amount of absorption must take place.

910. Now if this were a mere molecular disturbance, such as might be brought about
by the action of heat, we should expect to find it transient and speedily passing away.
Such, however, is far from being the case. As with simple chlorine, so with this mix-
ture, after it has been tithonized it loses its quality very slowly. I have observed that
after a week or more has elapsed since it was first exposed to the light, it commences
to contract when placed in a feeble gleam.

IV. Rays are absorbed in producing this Change.

911. I have thus far assumed that the rays which bring about these are absorbed;
the following is the proof which I have to offer :

912. Over a tube half an inch in diameter and six inches long, closed at its upper
extremity and open at its lower, invert a jar of the same length and one inch and a
half in diameter. Fill the tube and the jar at the salt water trough, about two thirds
full, with the same mixture of chlorine and hydrogen. Expose them to diffuse day-
light. Now it is clear that no rays can gain access to the tube, except after having
passed through the gaseous mixture in the jar. After a certain space of time the level
of the liquid in the jar commences to rise, but that in the tube will remain much longer
wholly stationary.

913. It therefore appears that a beam which has passed through a mixture of chlorine
and hydrogen has lost, to a great extent, the quality of bringing about the union of a
second portion of the mixed gases through which it may be caused to traverse. The
active rays have been absorbed ; they disappear from the beam, and are lost in producing
their first effect.

914. A beam of light becomes detithonized in producing a chemical effect; the
beam, as well as the medium on which it acts, becomes changed. I have a series of
results which proves th^t tt^is takes place for a great variety of compound bodies.

THE INDIGO RAY IS ABSORBED.

201

V. It is the Indigo Ray vhich is absorbed.

915. As has been said, it is a ray which corresponds in refrangibility to the indigo
which produces these results.

916. In a small porcelain trough I inverted, side by side, ten tubes, each of which
was three inches loug and one third of an inch in dianjeter, the trough being filled with
salt water. I passed into each tube a certain quantity of untithonized chlorine and
hydrogen. A beam of the sun, being directed by a heliostat into a dark room, was
dispersed horizontally by a flint glass prism, and the trough with its tubes so placed as
to oflfer an exposure to the diflerent coloured rays. The aperture which admitted the
beam was about half an inch in diameter. For a while no movement was observed in
any of the tubes ; but as soon as the preliminary absorption, previously described, was
over, and the tithonization completed, the level of the liquid began to rise. In the red
and in the orange no movement could be perceived, in the violet only after a time ; but
first of all the tube that was immersed in the indigo light was in action, and exhibited
finally a very rapid rise ; this was soon followed by the tube that was in the space
where the indigo and violet joined, then by that in the violet, and that in the blue ;
the tube in the green was next in order. The following table gives the numerical re-
sults obtained by observing the time which elapsed before movement took place in
each tube :

TABLE L

Name of Ray.

Time.

Name of Ray.

Time.

Extreme red ....

Red and orange

Yellow and green

Green and blue

Bine

*

+100 00

52 00

400

3-33

Indigo

Indigo and violet

Violet

Violet

Extreme violet

150
SOO
235
500
550

917. Many years ago, M. Berard made experiments on the explosion of chlorine and
hydrogen, and concluded, from his results, that it was brought about by the violet ray.
This was at a time when the methods of making these experiments were less exactly
known. It is a very easy matter to prove that, in reality, the indigo is the active ray,
and that, from a maximum point which is in the indigo, but towards the blue, the effect
gradually diminishes to each end of the spectrum.

918. The following table gives the calculated approximate intensity of the chemical
force for each ray, deduced from the foregoing experiment :

TABLE n.

Name of Ray.

Force.

Name of Ray.

Force.

Extreme red ....

Red and orange

Yellow and green

Green and blue

Blue

100

190

25 00

42 90

Indigo

Indigo and violet

Violet

Violet

Extreme violet

66 60
50 00
44 40
80 OO
1810

919. There is a great advantage which experiments conducted in this way possess
over those which depend for their indication on the stains impressed on Daguerreotype
plates or sensitive papers. In those cases we obtain merely a comparative contrast for
different regions of the spectrum ; in this we have absolute measures determined by a

* Even after the longest exposure I bad the means of giving it, no movement took place in the tube which was in the
extreme red, and I am doabtfiil about that in the red and orange.

Cc

202 THE ACTION IS POSITIVE THROUGH THE SPECTRUM.

definite chemical effect, and the rise of a Hquid in a graduated tube ; and from this we
gain juster views of the true constitution of the spectrum. On studying the numbers
in the foregoing table, or better still, if we project them, it will appear what an enor-
mous difference there is in the chemical force of the different rays. In the experiment
from which I have deduced this table, it appears that the force of the indigo ray ex-
ceeds that of the orange in a greater ratio tlian 66 to 1 ; and from the circumstances
under which the experiment is made, this difference must be greatly underrated. There
is always diffused light in the room coming from the intromitted beam, and this accel-
erates the rise in the less refrangible tubes ; then, again, it is impossible that the tube
which gives the greatest elevation shall coincide mathematically with the maximum
point and express the maximum effect.

920. From some estimates I have made, I am led to believe that, in point of chem-
cal force, for this mixture of chlorine and hydrogen, the indigo ray exceeds the red
in a higer ratio than 500 to 1.

VI. The Action is positive from End to End of the Spectrum.

921. M. Becquerel found that for a Daguerreotype plate, the red, the orange, and
the yellow rays possess the quality of continuing the action begun by the more refran-
gible colours ; he therefore names these " rayons continuateurs." For the same com-
pound I found that those rays, acting conjointly with the diffused daylight, exerted a
negative agency. It is therefore desirable to understand whether, with respect to the
gases now under consideration, the lesser refrangible rays exert anything in the way
of an action of depression or hinderance to union. By direct experiment, I found that
this was not the case, the action being positive from end to end of the spectrum. This
can be shown by removing the tubes, after they have been in the spectrum for an
hour or two, into the gleams of daylight. One by one they exhibit after a time a rise,
the order being the green first, then the yellow and the orange, and at last the red.
And if, at the same time, a tube which has been kept in the dark be exposed along
with them, they will all rise before it, showing that tithonization had set in and been
going on in them all ; that it had been more active in the green than in the yellow, in
the yellow than in the orange, in the orange than in the red ; and had the exposure to
the spectrum been long enough, the liquid in every one of the tubes would have risen.

VII. The Indigo Ray forms the Muriatic Acid, as well as produces the preliminary

Tithonization.

922. It only now remains to inquire, whether the rays which cause the production
of the muriatic acid are those which effect the tithonization of the chlorine ; in other
words, whether the first stage of the process is brought about by the same agent which
carries on the second. The experiment which I have just described shows that
tithonization is most actively produced by the indigo ray, and it is easy to show that it
is the same ray which carries on the second part of the process ; for if, before placing
the tubes in the prismatic spectrum, we tithonize th6m in the daylight, so that the liquid
has just commenced to rise in each, and then expose them to the spectrum, it will be

THE CHANGE IS XOT TRANSIENT. 203

found that the tube in the indigo rises most rapidly, and the others in the order stated
before. Therefore we perceive that the same ray commences, carries on, and com-
pletes the process.

923. Few substances can exceed in sensitiveness to light a mixture of chlorine and
hvdrogen previously tithonized. Brought into the obscure daylight of a gloomy cham-
ber, it is remarkable how promptly the level of the liquid in the tube rises ; how, when
the shutters are successively thrown open, the action becomes more and more ener-
getic ; and how, in an instant, it stops when the instrument is shaded by a screen.

924. I have not recorded in this communication a multitude of experiments of de-
tail, which go to support the conclusions here drawn, and which will be published at a
proper time. It has been my object on this occasion to call attention to the fact, that
chlorine, an elementary body, undergoes a change after exposure to the light ; a change
which appears to produce an exaltation of its electro-negative properties, as is shown
by its power of uniting more energetically with hydrogen. This change must not be
confounded with those transient elevations of activity due to increased temperature,
inasmuch as this is more permanent in its character. It arises from the absorption of
rays, which exist most abundantly in the indigo space of the spectrum. That the
phenomenon is due to a true absorption, is fully shown in the circumstance, that a
beam which has produced this effect has lost the quality of ever after producing a
similar result. This is borne out by what we observe to take place when a feeble
light falls on a mixture of chlorine and hydrogen which has been prepared in the dark.
A certain space of time elapses before any formation of muriatic acid occurs, during
which the absorption in question is going on ; and when that is completed, and the
mixture is tithonized, union of the gases begins, and muriatic acid forms. From end
to end of the spectrum the action is positive, and differs only in intensity ; but this
difference in intensity opens before us new views of the constitution and character of
the solar beam.

University of New-York, Jane 20, 1843.

925. The foregoing paper was written almost a year ago, and since that time I have
made several new observations corroborative of the results given.

926. Chlorine is not the only elementary substance in which the rays produce a
change. In his chapter on phosphorus, Berzelius remarks, " Light produces in it
(phosphorus) a peculiar change, of which the intimate nature is unknown ; and which,
so far as we can judge at present, does not alter its weight It makes it take a red
tint. This phenomenon occurs not only in a vacuum, even in that of a barometer, but
also in nitrogen gas, in carburetted hydrogen, under water, alcohol, oil, and other
liquids. When we expose to the sunlight phosphorus dissolved in ether, oil, or hy-
drogen gas, it instantly separates under the form of red phosphorus ; it undergoes very
rapidly this modification in violet light, or in glass vessels of a violet colour. The
light of the sun makes it easily enter into fusion in nitrogen gas, but it do s not melt
in hydrogen, and in the Torricellian vacuum it sublimes in the form of brilliant red
scales." — (Berzelius, Traite, tom. i., p. 258.)

204 ANALOGOUS CHANGE IN PHOSPHORUS.

£127. Again, when speaking of phospliuretted h} drogen, he says, " Exposed to the
influences of tiie direct solar hght this gas is decomposed, a part of the phosphorus
separates under the form of red phosphorus, and is deposited on the interior surface of
the glass. If we cover the vessel which contains the gas in. perfectly, no phosphorus
is deposited on the covered spaces." — {lb., toni. i., p. 265.)

928. As Berzelius does not give these experiments as his own, and I do not know
to whom we are indebted for them, I repeated some of them. Among other corrobo-
rative results, it appeared that a piece of phosphorus of a pale or whitish colour, in a
vessel filled with pure and dry carbonic acid gas, placed in the sunshine, exhibited the
pbenomenon in question. Eventually the phosphorus became of a deep blood-red
colour, and on the sides of the glass towards the light feathery crystals formed, the tint
of which bore a close resemblance to that of the red prussiate of potash.

929. Since the invention of the tithonometer, I have been able to observe more
closely the habitudes of chlorine. In the description given of that instrument in
Chapter XVI., it is recommended to cast aside the first observation, because it never
gives an accurate estimate of the true effect. When a mixture of chlorine and hy-
drogen is exposed, muriatic acid does not immediately form ; but a preliminary titho-
nization is necessary, and then, at the end of a certain period, contraction begins to
take place.

930. A tithonometer exposed to the daylight is much too powerfully affected to
allow of the successive stages of change to be distinctly made out ; the preliminary
tithonization is accomplished so rapidly, that the indications of it are merged and lost
in the contraction which instantly follows. It is necessary, therefore, that we should
operate with a sinall lamp-flame.

931. To such a flame I exposed a mixture of chlorine and hydrogen, and marked
the number of seconds which elapsed before contraction, arising from the production
of muriatic acid, took place. The first indications of movement occurred at the close
of 600 seconds.

The index then moved through the first degree in 480 seconds.
« " " second " 165 "

« « " third " 130 "

" « " fourth " 95

« " " fifth " 93

« « " sixth " 93

and continued to move with regularity at the same rate.

932. These observations, therefore, prove that a very large amount of radiant matter
is absorbed before chemical combination takes place ; and that in the case of chlorine
and hydrogen, the total action is divisible into two periods : the first, during which a
simple absorption is taking place without a chemical effect ; the second, during which
absorption is attended with the production of muriatic acid.

933. The facts which I am endeavouring to set forth prominently in this communi-
cation are, 1st, the preliminary tithonization just discussed ; and, 2d, the persistent
character of the change impressed upon chlorine when it has been exposed to the sun,
an effect wholly unlike a calorific effect, which would soon disanoear.

A FOURTH IMPONDKRABLE.. 205

934. By resorting to the tithonometer, we obtain information equally distinct upon
the second point, that the preliminary tithonization is not a transient effect which at
once passes away, but is, on the contrary, a persistent change.

935. I tithonized the chlorine and hydrogen contained in the instrnment, and kept
it in the dark for ten hours. On exposure to the lamp-rays it moved after a few sec-
onds, showing, therefore, that the change which had been impressed on the chlorine
was not lost In the former case, 600 seconds had elapsed before any movement was
visible.

936. When, however, we remember that the invisible images on Daguerreotype
plates, and even photographic impressions on surfaces of resin, and probably all other
similar changes, are slowly effaced, it would be premature to conclude that tithonized
chlorine does not revert to its original condition. I have sometimes thought that there
were in several of my experiments indications that this was taking place, but would not
be understood to assert it positively. Whether it be so or not, one thing is certain,
that the taking on of this condition and the loss of it is a very different affair from
anv transient exaltation of action due to a temporary elevation of temperature, or the
contrary effect produced by cooling.

CHAPTER XVin.

FARTHER CONSIDERATIONS ON THE EXISTENCE OF A FOURTH IMPONDERABLE.

Contents : Defects of former Evidence. — A new Photometer. — Measures of the Light
transmitted by Coloured Solutions. — Explosion of Chlorine and Hydrogen by a dis-
tant Electric Spark. — Absorptive Action of Media.

The Absorptive Action on Light and the Tithonic Rays foUoxcs different Latts.

Opacity of Glass for Phosphoric Rays. — Determination of the Refrangibility of the
Phosphoric Rays of an Electric Spark. — Refrangibility of the same Rays in the Vol-
taic Arc of Flame. — Professor Henrt/s Experiments.

These Facts serte to prove that there are more than three Imponderables.

{From iMt London, Eiadmrglt, mnd Dublin PkiletOfkieMi Magazuu for Augutt, 1844.)

937. In the Philosophical Magazine for December, 1842, I brought forward several
facts which had caused me to form the opinion that the chemical rays of the older optical
writers constitute, in reality, a new imponderable substance, which should be placed in
the same rank with light, heat, and electricity. To the views then given, I propose, in
this communication to return again, and furnish farther proof of their correctness. An
extended examination, which has occupied me several years, has served to deepen my
conviction of the truth of this doctrine.

93S. Great changes in the fundamental theories of science ought not to be lightly

206 DEFECTS OF FORMER EVIDENCE.

admitted. It was only after many years of discussion, and multitudes of experiments,
that the doctrine of the unity of air was destroyed, and the theory of the intrinsic dif-
ferences of gaseous bodies received. This was unquestionably the most important event
that ever happened to chemistry.

939. The imponderable principles are the true living forces of chemistry. The
circumstance that they do not exhibit the property of weight is only an incidental af-
fair, and ought never to have been regarded as their leading characteristic : they are
the regulating forces by which ponderable matter is arranged and grouped. If, then,
so great a change occurred in chemistry, on more exact views being obtained of its
pneumatic department, what may not be expected from the discussions which are ari-
sing on the nature of its great controUing forces !

940. There is another point of view from which these investigations assume a
deep interest. I have shown in Chapter XV. that, by resorting to prismatic analysis
in physiological researches, very remarkable truths appear. The function of diges-
tion, which is carried on during sunshine by the leaves of plants, is under the control
of the yellow ray. It is this which causes the decomposition of carbonic acid, furnishes
solid food, and gives the green colour. In animals similar results are produced by the
agency of a nervous system ; and not only so, but all the various operations connected
with life are conducted in the same vvay. There is one class of nerves which gives
action to the respiratory apparatus, and another which controls digestion. There is
one class which presides over motion, another which is the recipient of sensation, a
third which originates all the processes of thought and intellectuality. In the vegeta-
ble world the same idea is preserved, developed, perhaps, in a less elaborate way, but
under the guidance of a principle equally ethereal and refined. The beams of the sun
are the true nervous principle of plants. To the yellow ray is assigned their nutri-
tive processes, to the blue, their movements. We can, therefore, easily understand how
it is that botanists, who have sought in the interior of plants for indications of a ner-
vous agent, have never found them. That agent is external.

941. By the experiments that have been made for determining the nature of the
chemical radiations, the question has been brought down to very narrow limits. There
is no author who regards them as connected in any way with radiant heat, nor any,
except the wildest speculator, who traces them to electricity. The difficulty is, to offer
clear and undoubted proof that they are distinct from light. Herschel has directly
admitted this distinction, and brought forward several experiments {Phil. Trans., 1840,
p. 38, &c.) in support of this view. I have given some evidence of the kind, both re-
cently and also several years ago (1837). All these experiments depend on a com-
parison of tithonographic stains produced by solar spectra that have undergone the ac-
tion of absorptive media, and the effect of those spectra on the organ of vision ; a com-
parison, in short, of different visible spectra and their tithonographic impressions.

942. From this comparison, we endeavour to prove that invisible rays may be iso-
lated in any part of the spectrum, and, if invisible, we argue that they are not light.

943. It cannot be concealed, however, that there is a certain degree of imperfection
in this species of evidence : an accurate conclusion as to the presence or absence, or

A. NEW PHOTOMETER. 207

quantity of light, is by no means, under these circumstances, an easy aflair. In these
distorted spectra, as in the natural one, the terminations shade off gradually, and it is
difficult to say where the light in reality ends. On these terminations also, where the
Hght is so dilute and feeble, tithonographic action, ahhough faint, may, by prolonged
exposure, become not only perceptible, but even prominent. In tithonograpbic action,
time enters as an element ; in the act of vision it does not A feeble gleam does not
become more bright by constantly looking at it, but a sensitive surface exposed to such
a gleam is more and more affected as the time is increased.

944. Considerations like these demonstrate the necessity of investigating the ques-
tion in other ways, and more especially since M. Becquerel. one of the ablest writers
on these matters, has undertaken to support a doctrine which denies the existence of
the chemical rays, and imputes the whole action to light. — (Taylor's Scientific Memoirs,
vol. iii., part 12.)

945. This doctrine, however, will not, I am persuaded, stand the test of criticism :
there are facts, and these very imposing ones, which make it utterly untenable. It is
my object, in this paper, to set forth that evidence, and offer farther and clearer proof
of the physical independence of the tithonic rays and light, and indirectly establish the
existence of a new imponderable.

946. The true issue of the question, as has been said, rests in proving a clear dis-
tinction between light and the tithonic rays ; the other imponderables may be left out
of the argument. The mechanical properties of the two agents are so closely alike —
reflexion, refraction, polarization, interference, &c. — taking place under the same laws
for both, that the discussion necessarily becomes one of quantity and measure. Will
a given ray of light, disturbed by the action of absorptive media, change its luminous
and chemical relations pari passu 1 or can we alter the one and leave the other un-
touched \ Or, changing both by any process of treatment, do both change to the same
extent \

947. The final decision of this question obviously rests in obtaining accurate meas-
ures for the rays of light and for the tithonic rays. It is the comparison of those meas-
ures which is to settle the point

948. In Chapter XVI. I have described an instrument, under the name of the titho-
nometer, which gives indications by the production of muriatic acid from the union
of chlorine and hydrogen. This instrument is affected chiefly by the indigo rays, or,
more correctly speaking, by those rays which extend over the blue, indigo, and violet
spaces of the spectrum, having their maximum in the indigo. It is important that the
reader should keep this fact in mind.

949. Optical writers have been greatly embarrassed for want of a photometrical in-
strument which can measure the intensity of light ; the chief difficulty in the way is the
impossibility of contrasting together lights that differ in colour. By all, it is admitted
that the eye is able to judge of the amount of illumination of white surfaces, or the
depth of shadows within small limits of error, provided the rays compared are nearly
of the same tint

950. But in the discussion on which I am now entering, this very difficulty is in-

208 A NEW PHOTOMETER.

creased a hundred-fold. We are required to measure the intensity of light which has
passed through all sorts of absorbent media, and, therefore, has become excessively
coloured. How shall we compare together the rays which have gone through sulpho-
cyanate of iron, and are of a deep blood-red, with those that have passed through sul-
phate of copper, and are of a bright blue 1

951. Nevertheless, this problem is capable of a complete solution, and a photometer
cau be obtained which gives results comparable with those of the tithonometer : such
an instrument I have constructed ; it is exceedingly simple, as the following considera-
tions prove,

952. We are to remember that the tithonometer gives indications which are expres-
sive of the intensity of the blue rays generally ; the blue tithonic rays are the rays which
it measures. In using the term blue, it will be understood to comprehend the blue, in-
digo, and violet, or the more refrangible rays generally. It is obvious, therefore, that
the photometer which is to be used with it must measure the same blue rays, or, in
other words, the tithonometer and the photometer must be affected by rays compre-
hended between the same limits of refrangibility.

953. This can be effected by interposing in the photometer some absorbent medium,
which will admit no rays to pass it except such as are in the limits of refrangibility
with which the tithonometer is engaged. It is fortunate, as I have found, that such a
medium occurs in a solution of sulphate of copper and ammonia.

954. Let a wooden box, a b (fig. 131), six inches long, two wide, and two deep, be
provided ; in the centre of its top an aperture three quarters of an inch in diameter is
to be made ; the box must be blackened interiorly, and a rectangular prism of wood, c,
be placed in the box, with its right angle in such a position that its edge bisects as a
diameter the circular aperture ; over this wooden prism a piece of clean white paper
should be pasted, care being taken that, where it bends over the right angle of the
prism, it is folded sharp. So far the reader will recognise in this Ritchie's photome-
ter, as described in the Annals of Philosophy. Upon the aperture in the top of the
box a glass trough, g- A, is placed ; it is made by drilling a circular hole an inch in diam-
< ter in a piece of plate glass one third of an inch thick, and then placing on each side
(fit a thin piece of plate glass. This forms a circular trough, in which a strong solu-
tion of sulphate of copper and ammonia may be enclosed ; over the trough a conical
tube, d, six or eight inches long, is placed, so that the eye may see distinctly, through
the aperture in the top of the box, the disk of paper, and more especially its dividing
diameter.

955. Two small lamps, ef, are then prepared, of such dimensions that, when set op-
posite the open ends of the box, their rays may illuminate the paper; they are suppo-
sed to be adjusted so as to shine with equal intensity.

956. On looking through the tube a circle of blue light is seen, and, if the lamps are
shining equally, its two halves are equally bright. At the commencement of every ex-
periment this preliminary observation should be made, and, if necessary, the proper ad
justments secured.

957. Suppose, now, it were required to know how much blue light is transmitted by

EXPLOSIONS BY A DISTANT ELECTRIC SPARK. 209

a given solution. A trough, g, is to be provided, which may be formed by drilling a
hole two and a half inches in diameter through a thick piece of plate glass ; on each
side of this a thin piece of similar glass is laid, the trough having been filled with the
solution under investigation. Troughs made in this manner never leak ; they com-
pletely answer their purpose, and are easily washed and refilled.

958. Let the substance under trial be a concentrated solution of bichromate of pot-
ash. Having adjusted the lamps and filled the troogh, set it before one of them, sup-
porting it by a proper foot. On looking through the tube of the photometer, if the ab-
sorbent cell of the copper solution has been previously removed, the circle of light will
be seen very brightly illuminated ; one of its halves of a yellow tint, but not much less
luminous thau the other. The copper cell being now restored to its place, on looking
again through the tube there is a striking contrast — one half of the circle is of a bright
blue, but the other seems totally black ; with solutions which cut off the blue rays less
perfectly, this blackness is of course less intense ; in these cases the lamps are to be
moved into such positions that the two halves of the circle are equally illuminated, and
its dividing diameter invisible. As the eye is not disturbed with any difference of col-
our, the observation can be made within small limits of error. The calculation of the
relative intensities can then be made by the common photometrical law.

959. As this photometer is affected by rays of the same refrangibility as those which
affect the tithonometer, it is clear that if it be the rays of light which are operative in
the union of chlorine and hydrogen, the results given by the two instruments should
correspond within certain small limits of error.

960. With respect to the tithonometer, I have improved this instrument considera-
bly : by shading it with a glass case, which cuts off thermometric disturbance ; by ta-
king the observations through a small telescope, which avoids parallax ; by having the
scale movable, so as to slide along the tube; by making one charge of gas last for a
great number of experiments ; by completing the tithonization before commencing ; by
altering the position of the adjusting wire, so as to bring it nearly down to the end of
the tube. The detail of these changes would, however, detain me now too long ; they
will be given at some suitable time hereafter.

961. I may, however, record as a striking fact, that so great is the sensitiveness of
chlorine and hydrogen, that a mixture will actually explode by the rays of an electric
spark. In Chapter XVI. I have already stated that silent combination would take
place under these circumstances, but more recently I have had instruments repeatedly
destroyed by explosions residting in that way.

962. It being understood that the indications of the photometer and the tithonome-
ter correspond, that they are affected by rays of the same refrangibility, we are enabled
to proceed to the direct solution of the question, and the determination of M. Becque-
rel's h\'pothesis.

963. A transparent medium, which absorbs, to a greater or lesser extent, the more re-
frangible rays, being selected, it is required to determine whether, when a given ray has
passed through it, the chemical effect diminishes as the intensity of the more refrangi-
ble rays of light diminishes. According to M. Becquerel, the effect should be in di-

210 ABSORPTIVE ACTION OF MEDIA.

rect proportion to the quantity of light ; if, for example, the ray lost one half of its blue
light, the chemical effect should diminish one half, &c.

964. We require, therefore, two observations : first, with the photometer, to ascer-
tain how much of the light escapes the absorptive action of the medium under trial ;
second, with the tithonometer, to ascertain what quantity of the tithonic rays escapes
absorption. If the whole effect is due to light, the two observations should give the
same result.

965. Before giving the results which I have obtained in a tabular form, in order that
I may be clearly understood I will give a particular example. I took some naphtha,
the colour of which was slightly yellow, and placing it in the glass trough before de-
scribed, proceeded to determine its relation for the more refrangible rays of light. This
was done by adjusting the two lamps of the photometer till they coincided, then inter-
posing the trough between one of the lamps and the end of the photometer. On look-
ing through the tube, a great diminution of the intensity of the light on the correspond-
ing semicircle of paper was observed ; the other lamp was now removed until the
paper disc was uniformly illuminated ; the distance of the two lamps from the centre
of the box was now measured — they were respectively twelve and fifteen inches ; but
the intensity of the light is proportional to the square of the distance.

(1.) For the light in the unobstructed beam 225 or 100.

(2.) For the light in the absorbed beam 144 or 64.

Supposing, now, that the value of the unobstructed beam be represented by 100, and
we calculate the amount of light which passes through the naphtha, we find it is repre-
sented by 64 ; consequently, of every hundred rays of blue light which fell upon this
naphtha, sixty-four escaped absorption.

The naphtha trough was now carried to the tithonometer; first it was determined
how many seconds it took a given beam of light, coming from an Argand lamp, burn-
ing steadily, to move the index through one division.

(3.) For the tithonic ray of the unobstructed beam 31'.

The trough was then interposed in the coluiim of light, and the number of seconds
required to make the index move through one division determined.

. (4.) For the tithonic ray in the absorbed beam 65'.

But as the lamp might have varied in intensity, or the tithonometer in sensitiveness,
the first operation was repeated ; it gave,

(5.) For the tithonic ray of the unobstructed beam 31'.

This process of repetition was uniformly resorted to, and the mean of the two ta-
ken. It may be proper to remark, that there was rarely any perceptible difference.

966. It follows, that a ray which could effect the union of a given quantity of chlorine
and hydrogen in 31 seconds, required, after passing through the naphtha, 65 seconds.

Calculating on these principles how many of the tithonic rays passed through the
naphtha as before, we find,

(6.) For the tithonic rays in the unobstructed beam 100.

(7.) For the tithonic rays in the absorbed beam 48.

Now, comparing this result (6) and (7) with the result (1) and (2) for light, we find

ABSORPTION IN THE TWO CASES FOLLOWS DIFFERENT LAWS.

211

that the absorptive actiou of naphtha, of a slightly-yellow tint, is very much greater for
the tithonic rays than for the luminous rays.

967. Consequently, it follows that it is not the light comprehended between the ex-
treme blue and extreme violet rays which brings about the union of chlorine and h\dro-
geii, but another and invisible class of rays, which is absorbed by naphtha under a differ-
ent law for that for its action on light.

968. The foregoing example shows the mode by which I have obtained the results
of the following table :

TABLE SHOWING THE ABSORPTIVE ACTION OF CERTAIN MEDIA FOR THE
LUMINOUS AND TITHONIC RAYS.

Name.

Number of rays which escaped absorption.!

Tithonic rays.

Lurainnus rays.

Naphtha

Sulphocyanate of iroa ....

Nitrate of iron

Red prussiate of potash ....

Turpentine

Copaiva balsam

Iodide of starch

Stevens's blue ink

Litmus water

48
66
63
12
80
24
40
30
16

64
58
64
16
38
42
33
33

23

From this table, therefore, we gather that the chemical effect produced by a given ray
has no relation to the quantity of light which is in it ; that a satisfactory explanation
of the phenomena can only be given by assuming the existence and presence of an-
other agent besides the hght, and to which agent the chemical effect is due; that me-
dia are known which in their absorptive action bear relations which are totally differ-
ent for these two agents ; and, finally, that, as prismatic analysis has also previously
shown, no explanation can be given of these results by imputing them to the agency
of light, we are forced to admit the existence of another imponderable principle, the
same as that which passes in these papers under the name of tithonic rays.

969. In addition to the results obtained from the foregoing quantitative experiments,
there are other phenomena of a very novel and interesting kind, from which we may
draw an argument of overwhelming force. The discussion of these I shall now take up.

970. Early during the last century, the remarkable appearance of phosphorescence
excited in the Bologuean stone and calcined ovster-shells, attracted the attention of chem-
ists. DuFAY, in France, wrote several papers upon it; and the experiments of Wilson
in England are, perhaps, as fine a specimen of philosophical investigation as those early
times can furnish. These results, which few are now acquainted with, deserve to be
republished.

971. To Becquerel we are indebted for one of the most remarkable discoveries in
connexion with this subject He found that the rays of an electric spark which had pass-
ed through glass no longer preserved the quality of exciting phosphorescence, but
when they passed through quartz they retained that power unimpaired. This result
is very ^trikingly shown by placing a piece of colourless glass and a piece of quartz on
a surface covered with sulphuret of lime (oyster-shells calcined with sulphur), and dis-
charging a Leyden vial a little distance off. The sulphuret will glow- as brilliantly
on the part covered by the quartz as on the uncovered spaces, but unoer the glass it
wil. remain dark.

25^2 THE PHOSPHOROGENIC RAYS.

972. Nevertheless, this same sulphuret, carried into the sunshine, phosphoresces power-
fully under glass, apparently showing that there is a difference between the phosphoro-
genic emanation of the sun, for thus M.Becquerel terms it, and that of an electric spark.

973. On this radiation, as it comes from the sun, M. Becquerel has treated in his pa-
per, of which a translation is given in Taylor's Scientific Memoirs (vol. iii., part 12).
He determines the place of the phosphorogenic rays in the spectrum after they have
passed through a glass prism, and shows that the fixed lines which occur in the chem-
ical spectrum, occur also among these phosphorogenic rays.

974. In passing, I may mention that, at the time I published my account of these
fixed lines {Phil. Mag., May, 1843), I had no idea that any other chemist had seen
them. It, of course, soon appeared that M. Becquerel had some months previously
given an account of them to the French Academy. My result was wholly independ-
ent, and without any knowledge of his. On comparing the two papers, it will be seen
that there is a strong coincidence, not only in the manner of the experiment, but even
in the very phrases of description. It is this which has drawn these passing remarks
from me. Men who are pursuing the same object, and using the same resources, will
employ even words that are alike, though they speak languages that are different, and
live thousands of miles apart.

975. On examining the plate given in M. Becquerel's paper, I was struck with
the close resemblance between the phosphorogenic spectrum and that titiionographic
spectrum on iodide of silver of which Sir J. Herschel has given an elaborate account
{Phil. Mag., Feb., 1843). As far as the eye could judge, they seemed perfectly alike ; the
tithonographic spectrum in question was obtained by me in Virginia. This coincidence
was so striking that it appeared almost certain that the phosphorogenic emanations of
Becquerel were the same as my tithonic rays: there was the upper spectrum com-
mencing at the line G, and going beyond the farthest confines of the violet, exerting a
positive action ; there was also the lower spectrum, commencing at the line F and going
below the red ray, and exerting a negative action ; a phenomenon absolutely the same
as that traced on the Daguerreotype plate.

976. The phosphorogenic rays that come from the sun have the same place in the
. spectrum, or are dispersed by the prism exactly in the same way as the tithonic rays.

To all appearance these may be expressions for the same agent.

977. We must remember, however, that the phosphorogenic rays of the sun differ
from those of an electric spark. Glass to the former is transparent, to the latter it is not.

978. Before, therefore, I can carry this argument to the point on which I design it
to bear, it is necessary to ascertain the index of refraction of the rays of an electric
spark to which glass is impervious.

979. This I proceeded to determine in the following way : At the distance of six
inches from the terminations of two blunt wires, between \\ hich the spark from a Ley-
den vial was caused to pass, I placed a lens of quartz, the focus of which for parallel
rays was six inches, and then intercepted the resulting beam by a dia])liragm with a
circular aperture in it one third of an inch in diameter. I had caused an equiangular
prism of quartz to be cut and pohshed from a large and perfectly faultless rock-crystal ;

INDEX OF REFRACTIOA OF THE PHOSPHOROGEMC RAYS. 213

it was cut transverse to the axis. This prism I placed in such a way, that in disper-
sing the beam that came through the circular aperture I got rid of double refraction
and obtained only one spectrum ; this was received on a metal plate, which, having been
washed over with gum water, and sulphuret of hme dusted on it, offered a uniform
phosphorescent surface, which might be set in a vertical plane. When the spark pass-
ed, I saw that the plate teas phosphorescing on those portions where the more refrangible
rays had fallen .

980. But the transient light of a Leyden spark did not last long enough, nor was the
phosphorescence it produced powerful enough to enable me to conduct the experiment
in a way entirely satisfactory. I resorted, therefore, to the brilliant light which is ob-
tained when a piece of metal, or, what is far better, the hard variety of carbon which
is obtained from the interior of gas retorts, is lowered upon mercury entirely filling a
very small open porcelain cup, and the continuous discharge of a voltaic battery passed.
The battery used contained fifty pairs of Grove's cells, but a smaller number would
probably have been amply sufficient All the remainder of the arrangement was as just
described.

981. As soon as the light was emitted, I marked on the sulphuret of lime the begin-
ning of the red, the centre of the yellow, and the termination of the visible violet ray.
Then, stopping the current, I examined on what parts the plate was phosphorescing.
The commencement of the glow was between the indigo and the blue ; towards the
blue it extended far beyond the visible boundaries of the spectrum ; I could not see any
divisions or points of maxima on it. The surface of the plate shone all over, except
in the region of the less refi-angible rays, and there were the traces of the negative ac-
tion which M. Becquerel has so well illustrated in the case of the solar emanations;
rays which, however, were first observed in the last century.

982. It is necessary to remark, that the rays from the voltaic discharge resemble
those from an electric spark in their inabiUty to traverse glass. On this observation all
the value of the foregoing experiment depends.

983. But it can nevertheless be easily proved, that although glass is impervious to the
phosphorogenic emanation coming from the voltaic deflagration of any metallic bodies,
the observation applies to transient discharges only, A voltaic light, which lasts but
a moment, fails to cause phosphorescence through glass in the same way that an elec-
tric spark does ; but if the discharge is continued, the surface presently begins to glow;
and if maintained for several minutes, it shines as brightly as though a piece of quartz
had been used.

984. The inabihty of an electric spark to cause phosphorescence is connected with
its transient duration. The voUaic Ught enables us at pleasure to imitate the effects
of an electric spark, or those of the sun.

985. The phosphorogenic rays, whether they originate in an electric spark or from
the sun, occupying thus the same place in the spectrum, and even exhibiting the same
peculiarities as the tithonic rays on the iodide of silver, we have next to determine
whether this is an apparent or a positive identity.

986. Professor Henry, of Princeton, read a paper before the American Philosoph-

214 PHYSICAL INDEPENDENCE OF THE PHOSPHOROGENIC RAYS.

ical Society in May, 1843, in which he discussed all the leading mechanical properties
of the phosphorogenic rays, and among other important experiments, made some with
a view of determining tliis particular question. A Daguerreotype plate and some sul-
phuret of Ume were simultaneously exposed to the sky; the plate was stained, but no
effect was produced on the lime. A Daguerreotype plate and some sulphuret of lime
were exposed to the light of an electric spark ; the lime was observed to glow, but no
impression was produced on the plate. When the plate was exposed to a succession
of sparks for ten minutes, with a sheet of mica interposed, an impression was made.
Lime exposed to the moon did not phosphoresce, but a sensitive plate under the cir-
cumstances is said to be stained. In view of these different facts, Professor Henry ob-
serves, " These experiments, although not sufficiently extensive, appear to indicate that
the phosphorogenic emanation is distinct from the chemical, and that it exists in a
much greater quantity in the electric spark than either the luminous or chemical radi-
ation."

987. From Wilson's experiments, it appears that he was aware that when the phos-
phorescent surface is warmed, so as to hasten the disengagement of light, the moon-
beams may be found to have left traces of action upon it ; feeble, it is true, but never-
theless very apparent. We have seen, also, that the peculiarity of an electric spark is
due to its transient duration. Before, therefore, a final decision can be obtained on
this point, we are required to examine the effect of the tithonic rays and phosphoro-
genic emanation, under circumstances which are precisely similar as to intensity and
time.

988. For the transient rays of an electric spark, quartz is transparent, and glass is
nearly opaque. Having prepared a bromo-iodized silver plate so as to be exceedingly
sensitive, I set in front of it, at the distance of about one third of an inch, a disc of
quartz and one of crown glass, of equal thickness ; and between a pair of copper wires,
the interval of which was three eighths of an inch, I passed the spark of a Leyden vial
fifteen times ; the distance between this spark and the sensitive plate was about two
inches. On mercurializing, the plate was deeply whitened all over, equally so through
the glass, through the quartz, and on the uncovered spaces; but a spot of sealing-wax
which I had put on the glass, left its shadow on the plate beautifully depicted, as
were also the edges of the glass and the quartz. The two discs overlapped one an-
other to a certain extent, but the corresponding portion of the silver plate was as deeply
stained there as anywhere else.

989. Next I put a surface of sulphuret of lime in the place of the Daguerreotype
plate, everything remaining as before. On passing fifteen sparks, the lime phospho-
resced powerfully under the quartz, but not under the glass, so that the difference be-
tween its shadow and that of the spot of wax could not be distinctly seen.

990. For these reasons, therefore, I adopt the view expressed by Professor Henry,
that the phosphorogenic emanation and the tithonic rays are distinct. Under the same
circumstances, glass to the one is transparent, to the other it is opaque.

991. Now upon what sort of evidence is it that M. Melloni is universally admitted
to have established the physical independence of light and heat 1 Was it not by show-

THERE ARE MORE THAN THREE IMPONDERABLES. 215

mg that rock-salt is perfectly transparent to calorific rays, that glass is much less so,
that Rocbelle salt, alum, and sulphate of copper are almost opaque I It is surely impos-
sible to confound the phosphorogenic emanation of an electric spark with its rays of
light; the latter pass perfectly through glass, the former do noL So far as the eye can
distin^ish, an electric spark, the rays of which have passed through glass, difiers in no
respect from one the rays of which are received directly into the eye. If we consider
the constitution of such a ray, previous to and after its passage through glass, the eye
can discover no difference; but, as respects the phosphorogenic emanation, there was
something existing in that ray at the first of these epochs which had ceased to exist ia
it at the second ; a something not having the quality of communicating any impression
to tlie organ of vision ; and that which we cannot see, surely no man will acknowledge
to be light.

992. But the reader may inquire. What has all this discussion of the characters of the
phosphorogenic emanation to do with the existence of the tithonic rays as a fourth im-
ponderable ? A few words will show. From these considerations and experiments,
we have arrived at the conclusion that there exist in the beams of an electric spark
invisible rays, which are therefore totally distinct from light. They occupy the same
spectnim region as the tithonic rays which decompose iodide of silver ; their leading
character is, that glass, which is transparent to the rays of light, is opaque to them.

993. But the admission of this fact breaks down at once the doctrine of a trinity of
imponderables, and compels us to enlarge our list of those hving forces of chemistry.
The great obstacle which is in the way of admitting the tithonic rays as a fourth im-
ponderable, is in the circumstance that it would impress a very serious change on that
science, and apparently afford an argument of weight against the mathematical theory
of light I believe that some great generalization will hereafter prove that all these
imponderables are modifications of one primordial principle. I also beUeve that some
capital experiment will hereafter show that the forty different metals we are acquainted
with are merely modifications of one or two more simple forms ; but these are things
that we are unable to deal with now ; and viewing tLe experiments which have been
made in the last few years, not as mathematicians, but as chemists, all men must ac-
knowledge that our prevailing doctrines of the nature and number of the imponderables
are liable, before long, to undergo a very serious modification.

994. The admission that the phosphorogenic emanation and light are principles
differing from the tithonic rays and from each other, relieves us of much diflSculty in
increasing our list of imponderables. K these principles differ thus intrinsically from
one another, the question comes home to us. What are they? If electricity, and heat,
and light are three recognised imponderables, are not the tithonic rays a fourth, and the
phosphorogenic emanation a fifth ?

995. In view of this, I would suggest the propriety of ceasing to call these last by
the epithet of emanations, and of giving them the more appropriate name of phospho-
rogenic RATS.

996. And now, what appears to become of M. Becquerel's hjrpothesis, that all the
different effects we have been considering are due to hght, and are presented to us

216 CONCLUSION.

under diflferent aspects, because everything depends on the nature of the receiving sur-
face; that it is the same principle which affects the eye as Ught, decomposes chloride
of silver as a tithonic ray, and makes sulphuret of lime shine as a phosphorogenic ray ;
that the difference is not in the radiant principle, but in the surface on which it is re-
ceived 1 To go no farther in a discussion which has already extended this chapter too
much, if the agent is the same in all cases, and the difference perceived is due to the
receiving surface, how is it that a ray of Ught which has passed through a piece of
transparent glass can no longer excite phosphorescence in the sulphuret of hme 1 Can
we escape the conclusion that the ray has had something removed from it, or has had
some modification impressed on it, or, in short, that something invisible to the eye has
been taken away 1

997. To my mind these considerations are conclusive, and I therefore regard the
tithonic rays as constituting a fourth imponderable, and the phosphorogenic rays as a
fifth.

THE END.

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