Q 11 Published monthly by the New York State Education Department IN" 363 New York State Museum JOHN M. CLARKE Director UC-NRLF B 3 Dfi3 flit MINERALOGY 4 CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY BY H. P. WHITLOCK PAGE PAGE Minerals from Rondout, Ulster co. 5| Calcite from Howes Cave 16 Calcite from Union Springs, I Datolite from Westfield, Mass. .. 19 Cayuga co 10 | Explanation of plates 23 ALBANY NEW YORK STATE EDUCATION DEPARTMENT 1905 Price 15 cents ^O' * IV V . i*. m-Jes-xooo New York State Education Department Science Division, June 13, 1905 Hon. Andrew S. Draper LL. D. Commissioner of Education DEAR SIR: I transmit herewith for publication as a bulletin of the State Museum a paper entitled Contributions from the Miner- alogic Laboratory, prepared by H. P. Whitlock, Mineralogist of this division. It is with some satisfaction that I communicate a paper, brief in itself and wholly concerned with pure science, which constitutes a really substantial addition to our knowledge of the mathematical and physical characters of New York minerals. Very truly yours, JOHN M. CLARKE Director and State Geologist Approved for publication June 14, 1905 -K Commissioner of Education ^/"L > » > » .v 5V • ...*-* i New York State Education/Department/^/,/^ : ;/ New York State Museum JOHN M. CLARKE Director Bulletin 98 MINERALOGY 4 CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY BY H. P. WHITLOCK MINERALS FROM RONDOUT, ULSTER CO. In the spring and fall of 1904, the New York State Museum came into possession, through purchase and by the gift of Mr P. E. Clark, ot a very complete and representative collection of minerals from the mines of the Newark Cement Co., at Rondout. As such a mass of mineralogic material from this interesting local- ity has probably never before been available for study, the writer has availed himself of this opportunity to contribute these brief notes in the hope that they may prove of value in furthering a detailed knowledge of the mineral occurrences of New York. The writer wishes to express his thanks to Mr Clark for the many courtesies extended to him in his work. General description. The mineral material consists princi- pally of the filling of seams or veins in the Rondout limestone which constitutes the cement rock of these deposits. Of these vein minerals calcite predominates and is characterized by a wide and interesting variation in crystal habit. Crystallized quartz and dolomite occur associated with the calcite together with pyrite and marcasite of a younger generation. All of these present characters of interest and will be described in detail. Marcasite. Marcasite occurs implanted on the calcite and quartz of the vein filling and less frequently impregnating the cal- cite in minute detached crystals. The crystals vary from 5mm in width, parallel to the b axis, to microscopic individuals. In crystal habit they present the usual types, the combination shown in figure i° representing the prevailing habit. The faces are in general marred and distorted by striations and vicinal planes to such an extent that exact goniometrical measurements were oFigures 1 and 2 are shown with the 6 axis vertical. 333194 6 NEW YORK STATE MUSEUM rendered difficult, and where fairly sharp reflections were obtained from the corresponding faces of a number of crystals, the results showed a considerable variation, probably due to incipient groupings of a number of crystals in approximately parallel position. The brachi dome r (014) was noted in a number of cases but always trending toward a connection with (on) and (ooi) by series of vicinal planes giving curved surfaces [fig. 2]. Twinning parallel to (no) is quite common producing the usual stellate forms. In one case the repeated twinning shown in figure 2 was noted. Ag- gregates of the usual "cockscomb" aspect are common. Pyrite. The pyrite which occurs at Rondout presents several features of interest both from a crystallographic and a genetic point of view. In addition to the small brilliant crystals (i milli- meter diameter) which in places thickly incrust the calcite of this locality, in a number of specimens a decided and unusual distorted habit was noticed in the pyrite crystals occurring associated with the dolomite, which latter appeared to be of a younger generation than the calcite. The distortion takes place perpendicular to the opposite faces of a cube (100) and 'varies in extent from an elonga- tion of five times the cross section to thin acicular crystals some- what resembling the acicular habit of millerite. Twinning occurs parallel to the dodecahedral (no) face [fig. 3], giving rise to L and T shaped crystals. Repeated twinning occurs in several cases. Scepter crystals resembling those common to quartz were observed in several instances, the relation between the acicular shaft and the crowning individual being that shown in figure 4. Pyrite dendrites of remarkable size and beauty occur in seams in the limestone. These bear a marked resemblance to the arborescent forms of native copper and may owe their origin to similar crys- tallographic development. Quartz. Crystallized quartz is found at Rondout for the most part in detached crystals contained in the clay pockets of the Manlius limestone which forms the hanging wall of the cement beds. These exhibit in a great number of instances the phenome- non of a clearly marked' inner crystal of smoky quartz surrounded by a secondary layer of colorless quartz. These phantoms of smoky quartz occasionally occur in series showing successive de- posits of smoky and clear quartz. Small amounts of anthracite were noted in the associated limestone. In many of the crystals a marked tendency toward parallel grouping, very similar to the occurrence of quartz at New Baltimore1, often results in cavernous crystals which closely resemble those from Stony Point, N. C. 1N. Y. State Mus. Bui. 58, pi. 1. CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY 7 Penetration twins on twinning axis c are quite common result- ing in the forms shown in figures 5 and 6. Measurements of a number of crystals yielded the following results: ZONE (lOlo), (lOIl) Forms Measured angle on 1010 Calculated angle on 1010 m (6o6_5) 33° IS' 33° i3' i (3°3.2) 27 44i 27 42 i (5o53) 25 iftft 25 i7 f (4041) ii ii ii 8 ;; (7i8i) 8° So' 8° 52' £ (1231) 24 59 25 5 S '(iiai) 38 7 37 58 The presence of vicinal forms in the zone [1010.1011] inter- fered materially with the measurement of this zone. Calcite. The vein calcite of Rondout occurs, for the most part, as a secondary deposit on dolomite and presents types of crystal- lization of marked variety and unique development. The asso- ciated pyrite which is here present in extremely minute crystals, occurs in many cases included in the larger calcite individuals ar- ranged along the crystallogenetic lines of the latter mineral in dis- tinct bands on the surface of, or as phantoms within, the crystals of the calcite. These structure lines as outlined by the pyrite in- clusions are of notable interest in their relation to the development of the calcite. Somewhat similar inclusions have been noted in the calcite from Phoenixville Pa1. A careful study of some 200 specimens has led to the division of the observed combinations of crystal forms into nine types, of which the second and third may, be regarded as variations of the same type with respect to crystal habit. DISCUSSION OF TYPES First type. The simple combination of the prism (1010) with the rhombohedron (0112) which is the prevailing type throughout the vein calcite of the Siluric limestones of the Hudson valley, is here present in crystals which occasionally reach a diameter of 3 cm. As elsewhere noted in this region, this type appears to mark a condition of regular and uninterrupted deposition as distinct from the disturbed and brecciated vein structure characteristic of some of the types to be ^subsequently discussed. The planes of the rhombohedron e (0112) are dull whereas those of the prism are fairly brilliant and marked with natural etchings. Twins occur parallel to c (oooi). 1 Smith, J. L. Am. Jour. Sci. Ser. 2. 20:251. 8 NEW YORK STATE MUSEUM Second type. The scalenohedron A (15.4.19.3) which is common in crystals from this locality is developed in long, slender forms, the brilliant faces of which give excellent reflections and are sus- ceptible of exact measurements. The rhombohedron e (0112) terminates this type [fig. 7]. Twins occur according to two laws, parallel to c (oooi) and parallel to e (0112). The pyrite inclusions observed in connection with crystals of this type take the form of phantoms outlining the faces of a steep scalenohedron, possibly A (15.4.19.3). The largest crystals of this type were 25 mm in length. Third type. As in the preceding type the scalenohedron A (15.4.19.3) and the rhombohedron e (0112) form the distinguish- ing habit of this type, but developed in rather more equal propor- tions, giving rise to crystals of rather blunter aspect. The basal scalenohedral edges are beveled by the prism e (1120) and those between the scaleonohedron and rhombohedron by the small tri- angular faces of the rhombohedron M (0441), this latter being only occasionally present. The basal plane c (oooi) is also occasionally present in this type [fig. 8]. Twins are of frequent occurrence parallel to c (oooi). The largest crystal noted measured 8 centi- meters in length. Fourth type. Crystals of this type, which were noted on but one specimen, are of prismatic habit showing a (1120) terminated by the rhombohedron e (0112) and modified by the positive scaleno- hedron A (15.4.19.3) and the negative scalenohedron n (3.16.19.2) [fig. 9]. Crystals are small but with bright faces giving fair re- flections. Fifth type. Crystals of the fifth type though by no means com- mon were noted in a number of instances. • They are characterized by the equal development of the rhombohedrons e (oii2)and y (0441), the modifying form being the prevailing scalenohedron A (15.4.19.3). The rhombohedrons of this type are notably striated parallel to their intersection edges [fig. 10]. Sixth type. Crystals referable to this type are quite common, being noted in as many as eight specimens. They are of rhombo- hedral habit, the preponderance of the rhombohedron T (0.12.12.1) (new) giving to them an aspect almost prismatic. The rhombo- hedron / (0445) which with e (0112) terminates the type is of vari- able development from a face equal to e (0112) in habit to a mere line [fig. n]. Vicinal planes are frequent in crystals of this type and are often present to such an extent as to modify the basal edges to curved lines and give to the crystal the aspect shown in figure 12. CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY 9 Seventh type. Crystals of the seventh type are rhomhphedral in aspect and present scalenohedrons of the zone [0112.1011.1120! as shown in figure 13. Of these the faces composing the middle band belong to the form v (6i7s) while those which, with the rhombo- hedron e (oi~i2), form the termination are built up faces, probably belonging to D (8.1.9.10) though the presence of vicinal planes and striations render the measurements obtained from these_faces vague and the form uncertain. The rhombohedron r (ion) and the prism a (1120) also occur. The presence of pyrite inclusions ar- ranged on the phantom faces of the rhombohedron a (ion) suggest that crystals of this type were produced by a "building up" process from secondary calcareous solutions upon primative, rhombohedral crystals. Small amounts of galena and sphalerite were found as- sociated with this phase of the Rondout calcite. Eighth type. Crystals of this type are notably larger than those heretofore described and are characterized by rather dull faces. The combination shown in figure 14 which represents this phase consists_of the positive scalenohedrons A (3142) Y (5382) and © (10.3.13.2) terminated with the rhombohedron (0112). Of these the scalenohedron A. (3142) is represented by dull and roughened faces and the scalenohedron y (5382) is frequently absent from crystals of this type. Pyrite inclusions are present on, or just below, the surface of e (oiT2),_as distinct bands bisecting the sym- metry along the edges of r (ion) and often terminating in brushes [fig. 1 5] ; in some cases noted these bands were connected by lateral extensions along the basal edges ofr (ion). Phantoms of opaque white calcite which are shown on the cleavage and take the form of the rhombohedron r (ion) suggest the secondary derivation of this type from a simpler primitive crystal. Ninth type. The rhombohedron r (ion) which gives to crystals of this type a distinct rhombohedral habit, is represented by large dull faces. The rhombohedron e (0112) which modifies the ter- minal edges, and the prism a (1120) which modifies the basal edges of r (ion) are present as narrow bright faces. The scalenohedron A (15.4.19.3) is occasionally present as a modification represented by small faces of medium brilliancy [fig. 16], TWINNING Twin crystals are quite frequent among the calcite forms from Rondout, the common type being that formed with the twinning plane parallel to c (oooi). Several instances were noted of crys- tals of the second type twinned parallel to e (0112). Figure 17 shows a crystal of the first type twinned parallel to c (oooi) in- IO NEW YORK STATE MUSEUM which the natural etchings present on the prismatic planes, em- phasize the twinning habit. Figures 18 and 19 show twin crystals of the second type twinned according to both laws mentioned above. Figure 20 shows a twin crystal of the third type. SUMMARY OF OCCURRING FORMS Forms First Second Third Fourth Fifth Sixth Seventh Eighth Ninth type type type type "type type type type type OOOI C X IOIO m X , II2O a X X X X IOII r | X X OII2 e X X x X X X X X X Q44_5 I X 0441 _ *n X 0. 12. 12. 1 T X 8.I.9.IO D X? 6l75 V X 3J42 X X 5.3-8.2. T X 10.3.13.2 Q X X X X X I5.4.I9-3 A X 3.16.19.2 n X SUMMARY OF MEASURED AND CALCULATED ANGLES'* ~y /Y^ 7 oooi ^ ohhl hkil ^ hikl hkil 4 ikhl hkil ^ khil X T [ : Z oooi ^ ohhl hkil ^ hikl hkil^ ikhl hkil £ khil Forms meas- calcu- meas- calcu- meas- calcu- meas- calcu- ' ured lated ured lated ured lated ured lated 0112 e 45° 3' 45° 3' 0445 I 38° 6' 38° i6f 0441 _ •YI 75° 43' 75° 47' 0.12. 12. 1 Tb 85° i5 85° ioi 8.I.9.IO D 7° 30' 7° 29*' 6 i"75 V 12° 4' 12° 0' 85° 54' 85° 59' 3 142 A. 24° 13' 24° 10' 66° 39' 66° 1 5$' 10.3.13.2 e 25° 19' 25° 5' 39° iSi' 39° 13' 15.4.19.3 A 95° 3' 95° 2' 22° 43' 22° 4l' 4i° 44' 41° 54' 3.16.19.2 n 16° 46' 16° 52' 44° 56' 44° 57*' aThe scalenohedron (5382) was identified by means of measurements taken with a contact oniometer. 6New. CALCITE FROM UNION SPRINGS, CAYUGA CO. In the summer of 1899 Dr John M. Clarke, then State Paleontol- ogist, found at Union Springs some extremely interesting crystals of calcite. Several specimens of these were sent to Yale Univer- CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY II sity and were described by Messrs Penfield and Ford1. The writer has found by a careful study of the bulk of the material collected by Dr Clarke (some 70 specimens) some points of additional interest not shown in the comparatively small amount of material avail- able for the above article. The calcite crystals under consideration occur in vein material in the Onondaga limestone associated with saddle-shaped aggre- gates of dolomite and more rarely with crystallized quartz. They represent two generations, separated by a period in which dolomite was deposited, of which the older consists of brilliant individuals of extremely varied habit which are for the most part small, vary- ing from 3 to 10 millimeters in length. One type of these crystals of the first generation is represented in figure i, of the article by Penfield and Ford, above cited. The crystals of the second or younger generation are generally larger in size than those of older deposition and are largely of scale- nohedral type, showing a marked tendency to twinning according to several laws. They are frequently of a dull surface and black or dark gray in color as the result of bituminous inclusions. It is these latter which have been Described at length by Penfield and Ford. The small brilliant crystals of the first generation contain frequent inclusions of pyrite chalcopyrite and marcasite in microscopic in- dividuals, the latter mineral in beautiful doubly terminated twin crystals, specially prevalent in forms of the rhombohedral type. Frequent zones of deposition of these inclusions occur which ren- ders their aspect almost that of a phantom within the crystal. Pyramidal type. The second order pyramid, y (8.8.16.3) is a peculiarly dominant form in crystals from this locality, particu- larly so with crystals of the first generation. In the type shown in figure 21 which occurs in the lining of a thin seam, the form occurs developed to the exclusion of all modifications except those of the terminal rhombohedrons r (ion) and e (0112). These crystals are exceedingly small, the largest not exceeding 4 milli- meters in length and quite brilliant, giving very satisfactory reflec- tions when measured. The pyramidal type as shown in figure 21 is, in some cases, modified by narrow faces in the prismatic zone, the type gradually merging into the combination shown in figure 23 which may be regarded as a transitional type between the pyramidal [fig. 21] and 1 Penfield. S. L. & Ford, W. C. Some Interesting Developments of Calcite Crystals. Am. Jour. Sci. IQOO. 10:237-41. 12 NEW YORK STATE MUSEUM the scalenohedral [fig. 25] types. In this series the combination shown in figure 24 forms an additional link in the sequence of development from the pyramidal to the scalenohedral types. Regarding the genetic relationships of the members of this in- teresting series, the writer can do little more than speculate. It is, however, quite apparent, from its position, which is always that of close proximity to the walls of the seam, that the pyramidal type occupies the lowest place in the crystal development, representing the oldest generation of calcite. It is equally certain that the scalenohedral type is predominant in crystals of the second gen- eration which might possibly have been, in a measure, derived from the re-solution of the first generation of calcite. Between these limits we find a variety of expressions of crystal habit which, when considered with reference to the main facts above noted, leads us to seek for the solution of the crystallogenetic problem along several lines. It is the opinion of the writer that, in the case of the Union Springs locality at least, development in crystal habit is not dependent solely on chemical or physical differences in the crystallizing solutions, but is further complicated by the presence of external forces. Occurring forms and combinations As previously noted, the second order pyramid y (8.8.16.3) is of characteristic occurrence in the Union Springs calcites, specially in those of the first generation. It is present as a series of bril- liant faces giving good reflections and only in the case of the pris- matic crystals shown in figure 22 does it show any tendency toward merging into vicinal planes. In the above exception there appear traces of a steeper pyramid which could not, however, be identified from the material at hand. Figure 22 shows a prismatic habit which is clearly a phase of the second generation. The crystals of this habit are considerably larger than those generally noted from this locality, individuals 30 millimeters in length being not uncommon. Inclusions of marcasite in microscopic crystals are so plentiful as to render the calcite, which would otherwise be transparent, quite translucent. These inclusions are distributed along planes parallel to the rhombohedron r (1101). The planes of a (1120) and y (8.8.16.3) are both sharp and brilliant as are also, to a lesser degree, those of n (3.16.19.2). As has already been shown1 the rare scalenohedron n (3.16.19.2) also occurs on crystals of prismatic habit at Rondout. The planes of e (0112) are dull and 'See page 8. . CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY 13 those of m (1010) brilliant but somewhat rounded and covered with vicinal prominences. In the combination shown in figure 23 which is represented by small, bright transparent crystals of the first generation, the pris- matic zone is developed as a narrow band encircling the crystal, both a (1120) and m (1010) being present. The second order pyramid y (8.8.16.3) which is here present as a characteristic form is beveled on alternate edges by the positive rhombohedron M(404i)lying in the zone [8.8.16.3. 16.8.8.3]. A new scalenohedron X (81.41.122.40) very near the common v (2131), is present as a prominent form. This combination is quite similar to that figured by Penfield and Ford1; it is common on a number of specimens and, as previously noted, appears genetically to form a connecting link between the pyramidal type of the first generation and the scalenohedral type of the second. Figure 24 shows a combination which mainly differs from the preceding in that the scalenohedron vl (7.4.11.3) takes the place of X as a predominating form, the latter form being present only as a subsidiary modification and frequently passing into the commoner form, v (2131). This combination is distinctly scalenohedral in habit and occurs mingled with secondary crystals of the form shown in figure 25 which latter frequently shows the suppression of the pyramid y. The type shown in figure 26 is found in crystals of the second generation which occur deposited on a thin layer of first generation calcite of rhombohedral habit [see figure 28]. These differ from all which have been previously described in two essen- tial characteristics: they are opaque and milky white in color and show a complete absence of all marcasite or pyrite inclusions. In crystallization this type is also unique showing the scalenohedron U (10.4.14.3) in the zone [4041.8.8.16.3] as a highly developed form. A negative rhombohedron rj (0441) is present as a narrow face beveling the alternate pyramidal edges. M, X, r and y are all present as bright, well defined faces. The rhombohedron r (ion) which is present as a modification on the combinations shown in figures 21, 23, 24, 26 is developed to the extent of a crystal habit in the case of the types shown in figures 27 and 28 which represent crystals of the first generation. Of these figure 27 may be regarded as a rhombohedral phase of figure 23_showing an- additional scalenohedron C (6178) in the zone [0112. 1011.1120]. The crystals, which contain the marcasite in- ^enfield, S. L. & Ford, W, E. Some Interesting Developments of Calcite Crystals. Am. Jour. Sci. 1900, 10: 237, fig. i. 14 NEW YORK STATE MUSEUM elusions characteristic of the younger calcite in this locality, often show elongation parallel to the rhombohedral zone assuming a somewhat prismatic aspect. They apparently fill a gap in the genetic series between the pyramid scalenohedral habit [fig. 23] and the distinctly rhombohedral habit shown in figure 28. Crystals of this last type [fig. 28] occur in a loosely compacted mass deposited on a layer of crypto-crystalline carbonate of lime occupying the space between the crystallized calcite and the lime- stone wall of the cavity or vug to the depth of about 5 milli- meters. The calcite crystals are piled upon this crystalline layer to the depth of from 10 to 15 millimeters, the largest individuals lying in the top layers. The order and manner of deposition sug- gest the possible derivation from a solution which originally com- pletely filled the space and deposited its dissolved carbonate of lime first from a rapidly then from a slowly cooling medium. The crystals of this type which are remarkably clear, brilliant and well developed, range in size from 5 to 20 millimeters in diameter. All the faces give excellent reflections. The middle edges of the rhombohedron r (ion) are beveled by the scalenohedron X (81.41.122.40) which throughout this occurrence replaces the com- mon form v (2131) which it approaches very closely. It was only after repeated measurement of a number of crystals, both of this and of the foregoing types that the form was considered as estab- lished. The prism a (1120) is present as a small face in this zone. In the zone of the pyramidal faces [16.8.8.3.8.8.16.3] occur the forms M (4041) and S' (19.10.29.6) both lying well within the zone and agreeing as to measured angles well within the limits of ac- curacy. The twin crystals of the second generation have been so amply described by Messrs Penfield and Ford that there is little to add. The twin crystal shown in figure 29 occurs on several specimens in milky individuals of about 20 millimeters diameter, which sug- gest in their rather peculiar development the familiar types oc- curring at Rossie, St Lawrence co1. Figure 30 shows the prevailing type of scalenohedral twin, the habit being that of the scalenohedron v. (7.4.11.3) and the twin- ning plane parallel to \he rhombohedron e (0112). The reentrant angle or "gash" is chiefly formed by the planes of y (8.8.16.3) and m (1010). 'Nason, F. L. Some New York Minerals and their Localities. N. Y. State Mus. Bui. 4. 1888. CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY SUMMARY OF MEASURED AND CALCULATED ANGLES " oooiAh.h.ah.l h.h.2hlA .X__ 2h.h.h.l hkilAhikl Y hkilAikhl z hkilAkhil Meas- Calcu- Meas- Calcu-, Meas- Calcu- Meas- Calcu- Meas- Calcu- ured lated ured lated ured lated ured lated ured lated 8.8.7^3 y 6178 1 C 77° 48' 77° 37' 58° 25' S8° 28' 59° 44' 59° 46' 9° 37' 9° 3i' a 2131 \V 75° i?' 75° 14' 35° 36' 35° 36' 47° 7' 47° i ¥ a 81.41.122.40 A'i 35° 52' 36° oo' 46° 21' 46° 20' b 7.4.11.3 vr 40° i" 40° 4' 39° 2' 39° ii' a 19.10.29.6 5' 38° 10' 38° 33'|33° i?' 33° 28' a 3.16.19.2. n X 17° 4'ji6° 52' 44° 32' 44° 57*': aFound also on calcite from Rhisnes. bNew. The prevalence of the rare pyramid y (8.8.16.3) throughout the varied types of calcite crystals occurring at Union Springs has led the writer to compare these latter with the types presenting this form, which have been noted at other localities. The pyramid y (8.8.16.3) is found in the calcite at Rhisnes, about 4500 meters northeast of Namurs in Belgium1, at Andreasberg in the Hartz2 and in the Bad Lands of South Dakota3. Regarding the crystals from Rhisnes, Cesaro has noted not only the pyramid y (8.8.16.3) above mentioned, but also the forms M (4041), y (0441), v (2131) and S'. (19.10.29.6) as well as the occurrences of the prismatic zone [1120.- 1010]. Several of his types are identical in form and habit with figures 21 and 23 as well as a twin crystal similar to figure 30. Cesaro finds evidence that many of the crystals from Rhisnes of the first generation have been formed around a parent crystal hav- ing y (8.8.16.3) as the dominant form. He announces a theory of genesis of these crystals as follows: The examination of these crystals has led us to the conclusion that they have been formed encircling a pre-existing second order pyramid and were deposited by the action of three successive mediums: the first producing pyramidal types, the second forming around the first a combination the faces of which are truncations of the lateral edges of y, the third depositing around the second stage a crystal having for fundamental form scalenohedrons of the zone [1011.1120], This sequence of generation appears to agree perfectly with that already given on page 12 with reference to the Union Springs cal- cites. The truncation of the lateral edges being produced in the latter instance by the rhombohedron M (4041) as shown in 1 Cesaro, G. Les Formes Cristallines de la Calcite de Rhisnes. Ann. de la Soc. Geol. de Belorique 1889. 16:163. 2 vqm Rath, G. PORK. Annalen 1867. 138:521. 8 Penfield. S. L. & Ford. W. E. Siliceous Calcites from the Bad Lands, Washington County, S. D. Am. Jour. Sci. 1900. 9:332. 1 6 NEW YORK STATE MUSEUM figure 23. Certainly the occurrence of such similarity in crystal habit involving one or more rare forms can not be set down as a mere coincidence and when, as will be presently pointed out, the geological conditions show a corresponding similarity at the two localities, we are led to connect the two phenomena. At Andreasberg the pyramid Y was first noted by vom Rath in 1867. Sansoni1 in 1884 failed to find this pyramid, but as pointed out by Cesaro, the doubtful scalenohedron (7.8.15.4) given by Sansoni approaches very near the pyramid (8.8.16.3) in intercepts and is probably the same. The latter compares the forms of the Rhisnes calcites with those found by Sansoni at Andreasberg and points out several interesting similarities. Both Rhisnes and Andreasberg lie in the horizon of the Devonic and Upper Carbonic rocks and present the phase of subordinate beds of limestone overlaid by graywacke, clay slate, silicious slate and quartzite. In the vicinity of Andreasberg, these strata are frequently broken through by granite masses2. These conditions show a marked analogy to those existing at Union Springs, where the limestone beds are overlaid by the shale and silicious slate of the Marcellus and Hamilton groups and show evidences of con- siderable local disturbance. The limestone on which the Union Springs pyramidal calcite crystals are deposited is unique in that the silicious residue obtained from its solution consists of minute but perfectly formed quartz crystals, As pointed out by Pen- field and Ford3 pyramidal crystals of calcite, of the form (8.8.16.3) and containing nearly 50% quartz sand, have been found in the Bad Lands of South Dakota. It would, therefore, appear that in at least two localities producing this rare pyramid as a crystal habit, the occurrence is marked by the presence of silica under rather unusual circumstances. When we add to this fact the equally significant one that the formations at Union Springs and at the Belgium and Hartz localities show in each instance dis- turbed limestone beds overlaid by strata rich in silica we would seem to have reason for connecting the pyramidal habit of calcite with a crystallizing solution carrying silica in quantities approach- ing saturation. CALCITE FROM HOWES CAVE Calcite occurs at Howes Cave, Schoharie county, N. Y. in bril- liant transparent crystals filling or partly filling the veins in the Rondout limestone. The specimens which form the basis for the 1 Sansoni. Alt. Ace. Line. Mem. 3. 1884. 19:450. 2 Phillips, J. A. & Louis, Henry. A Treatise on Ore Deposits. 1896. p. 384. 3 Penfield, S. L. & Ford, W. E. Silicious Calcites from the Bad Lands, Washington County S. D. Am. Jour. Sci. 1900. 9:352 CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY 17 following notes were collected by the writer, through the courtesy of the Helderberg Cement Co., from the mine which furnishes natural cement rock to this company. The crystals which vary in size from 40 millimeters in diameter to microscopic individuals are of uniform habit and jire invariably characterized by a marked twinning parallel to e (01^2). They are frequently associated with tufted aggregates of acicular aragonite which appears, in one instance at least, to have been derived from the re-solution of the calcite. In the instance noted a geodic mass almost completely filled with crystallized calcite yielded on fracture several fine tufts of aragonite deposited on calcite crystals of the prevailing habit which latter were found to be deeply pitted with natural etchings. Calcite crystals of a second type were found in the Helderberg limestone, overlying the Rondout, lining the fossil remains of Rhynchonella wilsoni with which portions of this forma- tion are thickly studded. These latter differ somewhat from the type of the principal occurrence and will be discussed as a supple- mentary type. The crystals of the principal type shown in figure 31 exhibit a complex combination of forms occurring in several clearly defined zones; the relation of these is shown in the spherical projection [fig. 33]. Rhombohedrons. The rhombohedron r (ion) infrequently pres- ent alternating with the low scalenohedron q (5167) which latter, although clearly defined, is without question a built up form more or less vicinal in character. The planes of r are smooth but rather dull. The rhombohedrons M (4041) and r (7071) occur as nar- row but extremely brilliant faces, giving excellent reflections and beveling the edges of U (10.4.14.3) and V (6281) respectively. In the zone with these is also found the negative rhombohedron $> (0.14.14.1) occurring as small triangular faces of fine brilliancy. The rhombohedron e (0112) is universally present as brilliant faces which make excellent points of reference in this zone. Scalenohedrons. As previously noted the scalenohedron q (5167) is present in many instances as a built up form with deeply striated faces giving poor reflections. The basal edges of q are modified by the common scalenohedron v (2131) the obtuse polar edges of which are terminated by the scalenohedrons U (10.4.14.3) and V (6281). Owing to the fact that the indexes of these latter forms are quite near those of v and to one another their intersection edges are not distinctly marked, the successions of forms tending to produce a slight rounding of the crystal toward the rhombo- l8 NEW YORK STATE MUSEUM hedral zone. Excellent reflections were, however, obtained from all of these scalenohedrons and the closeness in agreement of the observed angles with theoretical values, taken, together with the fact that the rhombohedrons M and T, which truncate the polar edges of U and V respectively, lie well in the zones of these faces, establish their identity beyond peradventure. The negative scalen- ohedron N (4.16.20.3) which is invariably present is characterized by small, sharp and brilliant faces. Twinning. A very marked tendency toward twinning parallel to the plane e (0112) results in the production of thin flat exten- sions of one individual of the pair and the formation of a deep reentering angle as shown in figure 32. So common is this form of twinning that it is rarely absent from crystals of this occurrence to which it gives a distinct character. Twinning according to this* law is common in calcite crystals and examples of it may be found in almost every important occurrence. The abnormal extension of one member of the twin above noted is, however, unique and seems to indicate a metagenic rather than a paragenic mode of twinning. The calcite crystals found in the fossil remains ofRhynchonella w i 1 s o n i show combinations of the supplementary type illustrated in figures 34 and 35. The crystals though small are remarkably brilliant and give excellent reflections in all zones. Of the ob- served forms M (4041), e (0112), r (ion) and^ (2131) are common to the crystals previously described from the underlying beds of the Rondout limestone. The scalenohedrons are all of the zone [0112.1011]. The scalenohedron E (4156), here replaces q of the principal type. This form appears as a series of well developed planes having none of the vicinal characters which mark the de- velopment of q of the principal type. The scalenohedron A (3142) occurs as a series of narrow faces between v and r. Traces of the characteristic twinning which mark the crystals of the principal type are here noted; the twinning tendency is, however, very weak and only finds expression in an occasional shallow reentering "gash." CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY IQ SUMMARY OF MEASURED AND CALCULATED ANGLES X Y z ooo iAhoh.1 hkil Ahi kl h k il A i k hi h k i 1 A k h 1 1 Meas- Calcu- Meas- Calcu- Meas- Calcu- Meas- Calcu- ured lated ured lated ured lated ured lated 7o7i r 82° 3' 81° 45*' 4041 M 75° 46' 75° 47' ion r 44° 44' 44° 37' 0.14.14.1 $ 85° 54' 85° Si*' OII2 e 26° 14*' 26° 15' aiji V 75° 27' 75° 22' 35° 28' 35° 36' 46° 56'!47° I*' 3M2 A 66° 17' 66° is*' 4iS6 E 54° 9' 54° 7' 13° 12' 13° 3i' 10.4.14.3 U " 31° il' 31° 16' 38° So' 38° 49' 6.2.8.1 V 27° 26' 27° 31' 35° 43' 35° 52' 4.16.20.3 N 21° 29' 21° 30/|420 20' 42° 27' DATOLITE FROM WESTFIELD MASS. In February 1905 the State Museum acquired by exchange from Mr R. F. Jones a number of specimens of datolite from Lane's trap quarry near Westfield Mass. As the quality of this occurrence far exceeds that of the datolite hitherto described from this region, in size, beauty and complexity of crystallization, the writer has added the following notes to the foregoing descriptions of New York minerals in the hope that the unusual interest attached to these crystals will prove sufficient excuse for such an extralimital digression. The datolite occurs in veins in a diabase which shows evidence of considerable folding and decomposition, particularly along the walls of the vein where it is entirely replaced by prochlorite. The crystals which in some instances measure 10 cm. on the b axis are deposited on a thin layer of calcite. They are cut through by deep parallel furrows due to the former presence of mica which has been dissolved away leaving the cast, partly filled with calcite of a later generation; fragments of this mica, highly altered, were found in place. In color the crystals are whiter than those from the New Jersey trap region which they strongly resemble in crystal habit. The presence of second generation calcite of the form / (0221), which also occurs associated with the datolite from West Paterson, gives added significance to this similarity. The faces 20 NEW YORK STATE MUSEUM are almost universally sharp and brilliant and fall well within several clearly marked zones, greatly facilitating the ease and accuracy of their identification.1 Cleavage was noted parallel to a, quite perfect, and parallel to c, somewhat less so ; the measured angles gave m A a (cleavage) = 32° i8J', and g A c (cleavage) = 19° 18', the calculated value for these angles being 32° 23^' and 19° 22' respectively. Figures 37 and 38 represent the prevailing crystal habit, the disposition of the planes in zones being shown in the spherical pro- jection, figure 36. The intersection of zones in the plus half of the projection is specially interesting. Three new hemipyramids were observed in zone [001.140] as narrow faces beveling the edges between jthe clino_ dome g (012) and three prominent hemipyra- mids e (112), A (ii3)_and /u, (114) in the zonefooi.no]. These gave the indexes 148, 149 and 1.4.10 respectively and were assigned the letters e', A/ and //,' '. A plane in the zone [001.120] which is quite prominent in these crystals gave the indexes 122 and is noted in the text and projections as M. An enlarged projection of a portion of one of the typical crystals drawn in reversed position to show the disposition of these rare planes is given in figure 39. Pinacoids. The three pinacoids a ,(ioo) ; b, (oio) and c (ooi) are commonly present, the two former as brilliant faces and the latter as a somewhat dull series. The clinopinacoid b which is present as a very narrow face serves as an excellent plane of reference in orienting the crystal. Prisms. The faces in the prismatic zone are characterized by considerable brilliancy. The prisms m (no) and o (120) are commonly present; r (230) was noted in two instances on quite small crystals. Domes. In the zone of the hemiorthodomes % (102) is promi- nent giving to the combination a habit very similar to the Bergen Hill and West Paterson occurrences; v (103) is often absent. The presence of one or more hemidomes between a and x was noted in several instances, but the faces were so minute and ill defined that it was impossible to obtain any definite measurements from them. The zone of the clinodomes is, on the other hand, very well developed, showing m (on), g (012), t (013) and O (018), the latter sometimes present. 1 In measuring the dull faces, notably 012 and 018 in the zone of the clinodomes and 103 in the zone of the orthodomes, the method of placing a drop of alcohol on the dull face was success- fully used to obtain a clear reflection of the goniometer signal. The face was brought into approximate position and moistened by a drop of alcohol applied by means of a dropping tube. The curved surface of the. drop at first gives the effect of a series of multiple images; these, however, as the drop reduces in thickness by evaporation, gradually merge to a center and at the instant preceding complete evaporation combine in a clear and bright image of the signal. The writer finds this expedient more satisfactory than the usual method of a cemented cover glass and suggests it for crystals not soluble in alcohol. CONTRIBUTIONS FROM THE MINERALOGIC LABORATORY 21 Pyramids. The hemipyramids of the zone [001.110] form a regular series universally present as well defined planes ; of these n (in), v (in) and e (112) are particularly well developed. The hemipyramids A (113),^ (114) and K (115) are represented by relatively narrow faces often showing natural etchings. In the zone [001.120] the planes of the hemipyramids Q (122), (3 (121), M (122), i (123) and a .(124) are represented by small narrow faces beveling the edges between the planes of the clinodome zone and those of the zone [ooi.no]. They were for_the most part identified by zone equasions. The rare faces (148), (149) and (1.4.10) have been already noted in the zone [001.140]. This series of planes gave fair reflections and were measured on five crystals, the results agreeing with theory within the limits of accuracy. Twinning was observed on one crystal 8 centimeters in length on the b axis. This crystal which is shown in figure 40 is a pene- tration twin parallel to a (100); having c for the twinning axis. The larger individual is of the snowy white color, which is common to the occurrence and which suggests the color of cryolite; the smaller individual which is shown protruding from this last is light greenish in color, transparent and resembles the typical Bergen Hill datolite. A list of the occurring forms with the measured and calculated angles is given below. SUMMARY OF OCCURRING FORMS, MEASURED AND CALCULATED ANGLES Zone [a. c] Measured Calculated a 100 ax 45° o' 45° o X 102 ex 44 53 44 Si V 103 cv 33 46 33 35 C 001 Zone [c.b] b OIO bmx 38° IS' 38° 18*' 7WX on mxm'x 103 16 103 23 g 012 gg' 64 37 64 39i t 013 mxg 19 22 19 22 n 018 gt 9 26 9 27* to, 13 43 i3 S3 Zone [a.m] m no ant 32° 25*' 32° 23*' 0 I2O ao Si 5o Si 45i r 230 or 8 12 8 10 22 NEW YORK STATE MUSEUM Zone [m.n.e] n III nm 22° 54' 22° 56' V III mv 22 56 22 57 € 112 VE 17 i8J 17 21 A US tA ii 3°i ii 33 M 114 A/* 7 36 7 4o K us /*K- 5 13 5 i7 [Zone [fi.o.a] Q ft a i M 122 121 124 I_23 122 oft Wlyfl, 3i° 47' i7 13 28 19 3i° 48' i7 13* Zone [r.< it 231 TTt \ 10° 29' 1 10° 15' Zone [g.s] * 748 ge ge' g<* 39° 59' ii 46 22 45 40° 10' ii 54 22 5l Zone [g.A] *' 149 & 32° 59' ii 26 32° 45' ii 19$ Zone [g./*] " I.4.IO % 29° n' ii 28 29° 13' II 21 EXPLANATION OF PLATES PLATE i 24 NEW YORK STATE MUSEUM 1 Marcasite from Rondout showing prevailing habit of crystals. Forms: c (ooi), m (no), e (101), / (on), S (in). 2 Marcasite from Rondout, showing repeated twinning. Forms: c (ooi), m (no), e (101), I (on). Figures i and 2 are shown with b axis vertical. 3 Pyrite from Rondout, showing cube twinned parallel to (no), producing L-shaped form. 4 Pyrite from Rondout, showing seepter crystal. 5,6 Quartz from Rondout, showing penetration twins on twinning axis c. Forms: m (1010), r (1011), m (6065), i (5053), z (0111), 5 (1121), v (7181), c (1231). 7 Calcite from Rondout showing crystals of the second type. Forms: A (15.4.19.3), e (0112). 8 Calcite from Rondout showing crystal_of the third type. Forms : c (oooi), a (1120), e (0112) A (15.4.19.3). Plate i PLATE 2 -6 NEW YORK STATE MUSEUM 9 Calcite from Rondout, showing crystal of the fourth type (pris- matic habit). Forms: a (1120), e (0112), A (15.4.19.3), n (3.16.7^.2). 10 Calcite from Rondout, showing crystal of the fifth type. Forms : e (0112), rj (0441), A (15.4.19.3). 1 1 Calcite from Rondout showing crystal of the sixth type. Forms : e (0112), / (0445), T (0.12.12.1), the latter form is new to the species. 12 Calcite from Rondout, showing variation of the sixth type. The presence of vicinal planes in the zone of the negative rhombohedrons produce highly curved faces. 13 Calcite from^Rondout, showing^ crystal of_ the • seventh type. Forms: r (io7i), e (0112), v (6175),!) (8.1.9.10) (?). 14 Calcite from Rondout, showing crystal of the eighth type. Forms: e (oiT2), X (3142), Y (53^2), 0 (10.3.13.2). Plate 2 10 11 12 14 13 PLATE 3 28 NEW YORK STATE MUSEUM 15 Calcite from Rondout, showing the development of pyrite in- clusions on crystals of the eighth type. 1 6 Calcite from Rondout, showing crystal of the ninth type (rhom- bohedral habit). Forms: a (1120), r (lore), e (01^), A (15.4.19.3). 17-20 Calcite from Rondout showing twin crystals. Figure 19 is drawn with the twinning plane e (0112) vertical. Plate 3 15 16 18 17 19 20 PLATE 4 30 NEW YORK STATE MUSEUM 21 Calcite from Union Springs, showing crystals of the pyramidal type characteristic of the first generation. Forms: y (8.8.16.3), r (ion), e (0112). 22 Calcite from Union Springs, showing crystal of prismatic habit marking one phase of the second generation. Forms: m (1010), a (1120), y (8.8.16.3), n (3.16.19.2). 23 Calcite from Union Springs, showing crystal of transitional habit between pyramidal forms of the first generation [fig. 2 1] and scalenohedral forms of the second [fig. 25]. Forms_:_w 1010), a (1120), y (8.8.16.3), r (ion), M (4041), X (81.41.122.- 40) ; the latter scalenohedron is new to the species. 24 Calcite from Union Springs, showing crystal of scalenohedral habit characteristic of the second generation, but with subsidi- ary development of the predominating forms of figure_23. Forms: m (ioio),y (8.8.16.3), r (ion), m (4041), X (81.41.122.- 40), vt (7.4.11.3). 2 5 Calcite from Union Springs showing crystal of distinctly scaleno- hedral habit. This combination is typical_of the second gener- ation. Forms: m (1010), a (1120), M (4041), v/ (7.4.11.3). 26 Calcite from Union Springs showing milky white crystal of second generation occurring with first generation crystals of rhombohedral habit [fig. 28.] Forms: m (1010), y (8.8.16.3), r (ion). M (4041), 77 (0441), X (81.41.122.40), U (10.4.14.3). 21 Plate 4 22 PLATE 5 32 NEW YORK STATE MUSEUM 27 Calcite from Union Springs, showing crystal of the first genera- tion, transitional in habit between the pyramid-scalenohedral type [Fig. 23], and the rhombohedra^ type [fig._ 28], Forms: m (1010), a (ii2o)2_y (8.8.16.3), r (ion), M (4041), e (0112), C (6178), X (81.41.122.40). . 28 Calcite from Union Springs, showing crystal of the first genera- tion_ of rhombohedral habit. Forms :_a (1120), y (8.8.^.3), r (ion), M (4041), e (0112), X (81.41.122.40), 5' (19.10.29.6). 29 Calcite from Union Springs, showing milky crystal of the second generation twinned parallel to c. Forms: a (1120), r (ion), M (4041). 30 Calcite from Union Springs, showing the prevailing type of scalenohedral twin of the second generation. This combina- tion is drawn with the twinning plane 0 (01 1 2) vertical. Forms : m (1010), 7 ($.8.16.3),^ (7.4.11.3). 31 Calcite from Howes Cave, showing principal type of crystal. Forms: M (4041)^ (7071), 3> (0.14.14.1), e (0112), q (5167), v (2131), U (10.4.7413), V (62~8i), N (4.i6.~2O~.3). 32 Calcite from Howes Cave, showing a characteristic penetration twin. Plate 5 29 31 28 30 PLATE 6 34 NEW YORK STATE MUSEUM 33 Calcite from Howes Cave. Spherical projection showing zonal relations of forms of principal type. 34 Calcite from Howes Cave showing supplementary type found in fossil remains of Rhynchone_lla wil_soni. Forms : r (1011), M (4041), E (4156), A (3142), v (2131). 35 Calcite from Howes Cave. Basal projection of figure 34. 34 35 PLATE 7 NEW YORK STATE MUSEUM 36 Datolite from Westfield Mass. Stereographic projection show- ing zonal relations of occurring forms. 37 Datolite from Westfield Mass., showing typical crystal habit. Forms: a (100), % (102), v (103), c (ooi), b (oio), mx (on), g (012), t (013), O (018), m (no), o (120), n (in), v (in), e (112), A. (113), n (114), K (7i5), Q (122), 0 (121), a (724), i (123), M (122), c' (148), A.' (149), // (1.4.10); the last three are new to the species. 38 Datolite from Westfield Mass. Basal projection of figure 37. 39 Datolite from Westfield Mass., enlarged projection of a portion of figure 37, viewed in reversed position to show the position of the new planes. 40 Datolite from Westfield Mass. Penetration twin parallel to a (100) ; having c for the twinning axis. The faces g and a are composition planes. 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U, eum Museum bul SFP 1ft etin« no, 98 UNIVERSITY OF CALIFORNIA LIBRARY NEW YORK STATE EDUCATION DEPARTMENT _ pt2 Gasteropoda Pteropoda and Cephalopoda of the .Upper H elder- berg, Hamilton, Portage and Chemung Groups. 2V. 1879. v- J. text- i5+4Q2p. v. 2, i2opl. $2.50 for 2 v, __ I & Simpson George B. v. 6 Corals and Bryozoa of the Lower and Upper Helderberg and Hamilton Groups. 24 + 298?. 6ypl. 1887. $2-5° : _ £ Clarke John M. v. 7 Trilobites and other Crustacea of the C kany Upper Helderberg, Hamilton, Portage, Chemung and Catskill Groups 64+236?. 46pL 1888. Cont. supplement to v. 5, pt2. 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