EORNEDY % UNI VERSITY 2 ae BRA SB 267. H3207 oon esity Library DATE DUE | e 1969 | | = & 7 a — —_MAY => 2a _s———19) : —: —— MAY [© Pa Beh. 27> =v ‘ y so e TC to pe | a py pepiway uy Fic. Y. Criollo. FIG, Z. Lorastero. aidad,. ei c.f. Vaughan Ter? BOTANY AND NOMENCLATURE. 53 thand, to the Calabacillo on the other. In a paper read before ‘the Ist West Indian Conference 1899, held at Barbadoes I stated that :— “The only attempt at the improvement of the quality of Cacao is ‘that which has been made by the selection of seed by its external character (in the pod) and the import of seed from other countries. The result is that to-day although the remains of the original types are clearly apparent, it is also clear that, though bringing good prices the Cacao as now grown is as a whole nothing less and nothing more than an aggregation of cross breed varieties.* Some few might attempt to do so, but I think a wise planter would hesitate if he was asked to show where Criollo ended and Forastero began, or where Forastero ended and Calabacillo began. The fact is that the Cacao of the West Indies is nothing more nor less than a mixture o f various strains, which again vary in and among themselves in no certain direction, and among which the characters of the ancient types appear more or less developed according to the character of their surro undings and the numerous influences which have been brought to bear upon them. The quality of the Cacao produced from these strains (or types) is variable, some selling for good prices, while other brands are decidedly inferior. The character of the leaves, the form of growth, the colour and form of the fruit, the size, shape and colour of the interior of the bean are all variable to a degree, and few trees can be found which are the exact counterpart one of the other, either in their produce or the ‘vegetative characters. The discovery (by the author in 1898) that Cacao can easily be grafted by approach now puts into the hands of the planter means whereby he can secure a crop of one particular kind or kinds at will, and further it ‘will enable him to make samples of a character formerly impossible. It will also enable him to grow such types as the Criollo or any weak grower upon the vigorous growing varieties of the Calabacillo type. When grown from seed the selection should only be made after due examination of the interior of the bean, as the quality of the finished article can generally be determined by this means. The trees selected for seed bearers should be vigorous, healthy, of good form and the blossoms should be’ efficiently protected from Cross fertilization, or if deemed expedient the flowers themselves may be artificially fertilized. It would then be seen that the produce could be made to come true to a very high percentage, and once plantations of a single type could be brought into existence, then superiority would be so obvious that no further persuasion would be required to have the method generally adopted, as it would be seen to be the most profitable practice which could be pursued. Fields would then be arranged so as to produce a sample of one certain quality, showing no variation in the size and form of bean or the quality of its interior. It would be possible to have plantations on which not a single Red pod could be found, and others on which not a single yellow one could be seen.” How easily this result could be obtained by grafting is readily to be seen, and although perhaps slightly more lengthy and expensive, it is I think a preferable mode of propagation, to that of raising from seed ; more expensive it is true, but in the * It has been found that Forastero in Ceylon gives rise to forms representing ‘every type of Cacao grown. (Martin Report to Planters’ Association, 1892.) 54 BOTANY AND NOMENCLATURE. long run I am sure would pay very handsomely, There are: excellent kinds already on Trinidad fields and the best of these should be propagated by grafting and grown under local names, such as Gordon’s “‘ Excelsior Cacao,” Leotaud’s “ Promise Cacao,” Agostini’s ‘‘Surprise Cacao,” De Cannes “ Best of all Cacao”— which would be infinitely preferable to retaining names such as Criollo, Forastero, by which the various kinds can only be very indefinitely and sometimes very inaccurately identified. The finest cacao is by general consent. admitted to be produced by the Criollo, and this is assumed to be identical or similar in character to that called the Caracas variety. I think however there is considerable doubt if this idea is correct. In | the Consular Report on the agricultural condition of Columbia, Consul Dickson mentions that “the variety chiefly grown in “ Columbia is different to that of Venezuela, which produces “ Caracas cacao, the pods being much larger, and containing a “ greater number of beans, but as the number of pods produced “by a tree is greater, wt 1s probable that on the whole the Vene- “ guelan variety is the more productive of the two. The quality “of Columbian cacao is little, if at all, inferior to that of the “ Venezuelan, but it is littte known in commerce, as only an “ insignificant amount is exported, the supply scarcely subigfying “ the demand of the country.” What this variety may be, we have no means of correctly ascertaining, but the comparison with the Caracas variety indicates that it is very near to, if not synonymous with our Forastero, and it is to be noted that such a variety would also be. “ Forastero” or foreign to the Caracas people. The late Dr. Trimen of Ceylon, in his Annual Report for 1890, fell into the error of interpreting the word “Criollo” or Crevle as being synonymous with “ wild.” It is well known, however, that the word is never used in this sense in the West Indies, the true interpretation of the word “Creole” being—one born in a country or one belonging toa country. With European Anglicans the word “ Creole” is generally supposed to have reference to a mixture of races, but it is not used in that sense in the West Indies or Jamaica. For instance, a child born of white parents in any West Indian Island, or even on the mainland of Central and South America, is a “Creole,” and just as much so, as a black or coloured child would be. In fact, “ Creole” should be translated as “native” and not ‘“ wild” or Coloured; a black or coloured child being just as much a Creole, as a white one or a mulatto and vice versa. BOTANY AND NOMENCLATURE. ov : It is important that the sense in which the word “ Creole” is used should be fully understood as we have “Criollo” as our first variety of Cacao. (Uriollo is Spanish for Creole.) If we interpret the words Criollo Cacao as Native Cacao, and Forastero as Foreign Cacao, and Calabash Cacao as Cala- bacillo Cacao, we should have had a better definition of terms, and prevent further misapplication of the word “ Criollo.” Calabacillo is so named from the resemblance of the pods to one- of the forms of the fruit of the Calabash tree (crecentia cujete, L.) The late Dr. Trimen in Annual Report Ceylon, 1890, remarks that these names appear to have had their origin in Trinidad, and doubted whether Criollo was “ever really a native plant there” (Trinidad.) The misunderstanding of the word Criollo or “Creole” probably led him to this conclusion, for it could not be native or “Creole” if imported into Trinidad unless its name was imported from South America with it, and if so, it should be known as South American Criollo or 8. American .Native Cacao, and not simply Criollo. The word “Trinitario”* is applied on the “Spanish Main” to the Cacao known as Forastero in Trinidad. and they term itso in contradistinction to their own Criollo, A plant of Trinidad would clearly be Forastero or Foreign in Venezuela, and therefore, their ‘‘Trinitario” being a foreign Cacao and supposed to have its origin in Trinidad, would properly be the Criollo of Trinidad, if the word is used in the: correct sense. It may be possible, however, that Criollo Cacao is native of both countries. The balance of probability appears to be, that its origin can be traced to South America as indicated by Dr. Trimen. In Nicaragua the plantations appeared to the author to consist principally of the Criollo type. The interior of the Nicaraguan bean is commonly white, but where the trees have been planted close to the imported Forastero, there is a most perceptible increase in the colour of the beans, and of this I can bear personal evidence. Dr. Trimen repudiated the authenticity of the word Criollo, attached to plants sent him from Trinidad, and calls them Forastero on account of their being dissimilar to “ the old Ceylon * Dr. Chittenden in Agricultural Record, Vol. IL., p. 107. 56 BOTANY AND NOMENCLATURE. Red Cacao, also called Caracas.” (Ceylon Report, 1890.) He allows however that the Forastero sent from Trinidad to Ceylon, is gradually changing character and “becoming more like the “old Ceylon Red.” It is probable that Dr. Trimen was quite correct in repudiating the name, for if the “ white seeded” wild variety is the ancient Criollo; then many of our present day forms are intermediate between that and Typical Forastero. That a change of character from distinct forms is possible is admitted, and moreover our best botanists do not find sufficient distinctive characters (notwithstanding the differences in the form, size and colour of fruit, leaf.and tree) to make more than one species of all our cultivated varieties ; which as Dr. Trimen truly says, probably trace their origin to a common wild parent, Dr. de Verteuil, now Sir L, A: A. De Verteuil, K.C.M.G., tells us in his work on Trinidad 1884 p. 242“ That from its first settlement Trinidad exported Cacao, and thaé Cacao soon gained a reputation on account of its delicious aroma. According to Gumilla it was superior to that of Caracas and other places, so much so that the crops were bought and paid for beforehand.” “In the year 1727 however, a terrible epidemic spread in the Cacao plantation” and complete ruin followed. The nature of this epidemic is indicated, for Sir Louis states “the trees were apparently healthy and vigorous, the “ flowering abundant, giving fruits but none of them came to ‘“‘ maturity as the young pods dried up before full growth.” ‘It is of course impossible to decide exactly what this disease really was, but the presence on the plantations of to-day of a disease* which might be similarly described, leads to the inference that it was of fungus origin and similar if not identical . with that recently identified. “ Thirty years later, some Aragonese Capuchin Fathers ** were successful in their attempt to revive the culture of Cacao “in the Island. They imported from the continent a new “« species (variety J. H. H.) the Forastero Cacao which, though “ giving a produce of inferior quality was nevertheless promptly ‘‘propagated as being hardier, that is the Cacao at present * cultivated in the Island.” The characteristics of Criollo cacao are the thinness of the shell of the pod its rounded beans and pale colour of the interior of the bean on section. The leaves of the tree are small when * Discussed in a later chapter. BOTANY AND NOMENCLATURE. 57 compared with the Forastero varieties, and the tree itself is not nearly so sturdy and thriving, and does not produce such regular and abundant crops as the “Forastero and Calabacillo varieties. The skin of the bean is thinner, and the interior has but a small proportion of that bitter flavour which is characteristic of the unfermented bean of Forastero and especially that of Calabacillo. The flattest beans are those produced by pods of the Calabacillo type. The beans of Forastero are intermediate between these and the rounded form of the Criollo, whic are often slightly pointed. (Fig. A.) The above sketch of beans of three typical varieties show ‘the difference in form which occurs, but there will be found intermediate forms hardly reconcilable with any of the figures so that these must be taken merely as the type forms of the varieties mentioned. (Fig. B.) Figures 4, 5 and 6, represent respectively beans of Theobroma bicolor, Nicaraguan Creole, and the best or high priced variety of Venezuelan Cacao sometimes called “Caracas” Theobroma bicolor has fruited for several years in Trinidad, since its introduction in 1893, but the beans do not enter as commercial Cacao. The Nicaraguan bean is the largest Cacao bean I have seen, and is of the finest quality, only to be approached by the finest flavoured Criollo, or ‘ Caracas.” There are rounded beans* to be found in almost every pod towards its extremities, but the proportion of rounded beans in Calabacillo is very small indeed, and the yield of this form of bean increases only as the character of the pods approaches the Criollo type. Calabacillo, or that class which gives small, rounded and smooth pods and flat beans, having a bitter taste, is the lowest type of Cacao that is grown, and requires the greatest amount of skill ‘during treatment to bring it into marketable form, the process of fermenting it, taking more than ‘double the time required for Criollo. The tree however is the strongest grower and the hardiest of all the varieties, and will thrive on poorer lands and on lands on which it would be impossible to grow the finer kinds. In the best forms of Venezuelan and Trinidad Cacao, the beans are characterised by a peculiar prominence on their sides, (see Figs 2 and 6.) Trees of the Forastero type are strong growers, and its varieties are therefore suitable for most lands in which cacao ‘can reasonably be expected to thrive. It approaches the * The word “bean” is incorrect, but as it ts the con form of expr among our cacao planters, it is used as being better understood than any other. 58 BOTANY AND NOMENCLATURE. Calabacillo type by the Amelonado variety, both red and yellow, and certainly stands as a large intermediate and variable type between Criollo and Calabacillo. In general the Forastero has a thick skin. It approaches the Criollo in form, or runs into. .Criollo by its variety Cundeamor verugosa, red and yellow ; but trees may be found bearing pods which are hardly to be distinguished from the Criollo on the one side and the Calabacillo on the other, thus showing the breadth of form covered. The planter should ascertain the character of his land with as much accuracy as possible before deciding what variety of Cacao he will plant. If very poor he can rely on Calabacillo only, if moderately rich Forastero, but on rich and lasting ground the best types may be planted. If however the best types were grafted un the strong growing Calabacillo there- would be more probability of succeeding in growing the best. varieties on inferior as well as rich soils. The generality of plantations in Trinidad contain trees so. mixed in character that it is difficult to separate one kind from another, although it cannot be doubted that it would pay well for any extra trouble, if a system of planting each type in. separate fields were adopted, The contract system which prevails in Trinidad is probably more to blame for the mixed character of the fields than any- thing else. The contractor has perhaps in the first instance planted from seeds supplied to him presumably, all of one kind. In supplying first vacancies he uses the stronger and larger growing plants, and in places where the plant has refused to. grow after planting twice or thrice, he will (rather than lose. count of a tree) put in a plant. of the strong-growing Calabacillo. In length the leaves of Criollo type vary from 5 to 12 inches and from 2 to 4 inches in breadth. Some were recently examined over three feet in length. Forastero Cacao gives the largest leaves of all. For the sake of accuracy I have made special measurements of some growing in the Royal Botanic Gardens and find that they vary from 9 to 21 inches in length, and range from 24 to 6 inches in width. The leaves of the Calabacillo type are shorter and wider in comparison with their length than either Criollo or Forastero. It must be understood, however, that these measurements are taken from extreme forms, and that the nearer the trees approach other varieties, the nearer alike are the leaves, Cacao is said to have been cultivated largely in Jamaica some two hundred years ago, but according to Long, in his History of Jamaica, the plantations were destroyed by a “ blast.” Vig. 3. Calabaein, Forastere, Criollo, Fig. A. Theobroma Nicaragua Caracas Bicolor. Creole. Cacao, FiG. Be BOTANY AND NOMENCLATURR. 59 Dr. Morris mentions that in Trinidad also the trees were visited. by ‘a blast ‘sometime during the last century.” He interprets the word “blast” as a “blow or hurricane,” but the word in East Anglian brogue has another meaning. “Blast”. is there. synonymous with “blight,” and this is confirmed by Walker’s Dictionary as follows: (o blast—to strike with some sudden plague). Either interpretation would however fully account for the destruction of planfations, especially when taken in conjunc- tion with the high rate of duties which was imposed on the article in England at about the same time. Whatever the cause, the cultivation of Cacao in Jamaica received a wonderful check, for in 1671 Long states there were as many as sixty-five walks in bearing; while in 1882 it was only grown in isolated instances until the value of the product was brought into notice by Dr. Morris when resident there as Director of Public Gardens and Plantations, when the cultivation largely increased. The introduction to Jamaica was probably effected by the Spaniards as the English only came into possession of that island in 1655, or sixteen years previous to the date mentioned, One species is mentioned by a writer (Martius) as having been found in Jamaica (Theobroma sylvestris) but accuracy of this would appear to need confirmation. It is generally admitted that Theobroma Cacao is to be- considered native of the Northern territories of South America ; and the finding of plants in Virgin Forest in Trinidad, is strong evidence that it is a native of the Island, as well as the Mainland. Spon’s Encyclopedia gives Theobroma angustifolia, T. bicolér, T. guyanensis, 7. microcarpa, T. ovalifolia, T. speciosa, T. sylvestris as producing commercial cacao, but we cannot learn upon what authority. When travelling in Central America in 1885, I found Theobroma bicolor, Humboldt and Bonbland, indigenous in the provence of Veragua, United States of Columbia. It was known as “,iger cacao,” so named from the rank smell of the seeds. It is not ih general use by the inhabitants, though it is said to be used in some manner by the Indians. It has also the name of “ Indian chocolate” and “ Wariba,” the latter being the Indian name, and appears to suggest some connection with the «“ Wari” or wild hog, probably a peccary (Dicotyles) which is known to emit from a gland on the back a strong-smelling fluid. From information gathered when in Nicaragua, and from observations made on tries introduced by the author to Trinidad, 60 BOTANY AND NOMENCLATURE. 4 which have fruited, it is certain that Commercial. Cacao of fine quality is produced by Theobroma pentagona, the beans of which are nearly double the size of the average Trinidad bean. Figure 7. shows the pod of this species compared with a pod of Forastero. . 7 Theobroma angustifolia, otherwise known as ‘* Cacao Mono’ er “Monkey Cacao” does not produce commercial Cacao as the beans are rank and ill flavoured. It has been introduced to Trinidad, but has not yet fruited. The bean of Theobroma guyanensis, Willd, is said by Don to be white, and good eating when fresh. He also says that the seeds of T. bicolor are mixed with the seeds of the coommon ‘Cacao, Theobroma angustifolia were introduced to Trinidad at the same time as 7’, bicolor, and ZT. pentagona and all three are now well established, the two latter are now bearing (1899.) Specimens of “wild Cacao” growing in the Gardens, and specimens sent me from Colombia belong to the Genus Herrania, -a near ally of Theobroma. It has been recently determined that the old Dutch Cacao of Ceylon is synonymous with the best and truest types of the Criollo of Trinidad, as a tree sent from Ceylon recently fruited in the Royal Botanic Gardens and enabled comparisons to be ‘made, when they were found to correspond in every essential particular. One of the Pachira’s P. insignis is sometimes called wild ‘Cacao—and is known in Trinidad as “Cacao Maron.” It has ‘been brought to me on more than one occasion as a “ new kind” of Cacao. The seeds are edible when roasted, but have no resemblance to Theobroma Cacao. : According to Aublet’s illustrations the pods of Theobroma guyanensis are small and oval, distinctly marked with five raised ribs and the leaves are much like those of 7. cacao but more cordate at the base. The fruit of 7. Sylvestris, from a plate by the same author, is small, smooth, yét still showing the five divisions of the pod by slight depressions or lines on the ‘outside at equal distances from each other. The leaves are small and suggestive of the ordinary form borne by “ Criollo.” The pod of 7, bicolor, Humboldt, is woody in texture, hard and dry, and specimens can be kept for any length of time. I have a specimen, collected in 1885, in the herbarium of this department, and also specimens of the leaves and flowers, and these have since been supplemented by specimens grown in the ‘Gardens, @ ‘ON 0. { VN D (Oy DUO Buje } Lf ADI O Do) PHO, YO A Mle e WE OT FIG. 7. CHAPTER \X. Diseases, &c.— Insect Pests, Fungi, Vegetable Parasites, Epiphytes, and other enemies. ORTUNATELY for the cultivator the serious diseases which at present attack the Cacao tree in the West Indies, are few, except the plant is ‘4/¢ placed in a totally unsuitable position. Perhaps e the most common disease atfecting the tree, is one which is known under the name uf Canker. This cause the stem and branches to dry in certain spots and along certain lines and generally results in the death of the tree. The cause of this disease is not yet fully clear, but a fungus of the parasitic type has been fuuad on Cacao pods, the allies of which are known to cause canker of the bark on other trees. This has been named Nectria baini?, Massee, and will be discussed later, Generally speaking, however, when trees are planted in well drained ground, little or no disease is found ; but where a poor surface svil badly drained exists, canker will appear (Canker of the bark has also been found to be due to a Nectria—December, 1899.) There is another disease found in Trinidad, Surinam, Grenada and other places, which attacks the pods in damp weather and causes them to rot and turn black, hence sometimes called *‘ black rut” or “ black Cacao.” This is due to a parasitic fungus recently studied and forwarded to Kew by the Author, where it was determined as J’hytophthora omnivora, a fungus akin to that (Phytophthora infestans) which destroys the Potato (Sulunum tuberosum.) The following extract from De Verteuil’s Trinidad, 1284, page 431, reads :— “ The prosperity of the Colony hud now reached tts culininat- ing point, Cacao selling at a very high price. But in the year 1727. according to Gunilla, not a diseuse of the trees exactly, but a bliyht attacking the pods under certain atmospherte iyiunces, deotr yet the crops.” 62 DISEASES, ETC. Pace 433 —“Govrernor Nanclares had for his successor Colonel Don Pedro de la Moneda (1757). It was about this time that an attempt was successfully made to re-introduce the Cacao plant. A new species (variety J. H. H.) the Cacao Foras- tero, which being hardier, although not yielding the same fine quality, succeeded beyond expectation. It is this quality which is stil cultivated in our days.” Therefore it appears that a thirty-years interval elapsed between the attack of the “blight” on the original Cacao, and the re-introduction, The word “ re-introduce,” however, would seem to imply that the first Cacao was introduced and not indigenous to the Island but the force of evidence is now against this view, The following account of this disease is condensed from Bulletin of the Botanical Department for July, 1899 :—The disease is due to a parasitic fungus, known as Phytophthora omnivora, a well known relative of that causing the potato -disease. This fungus is specially known in Europe by the attack it makes upon young beech seedlings and many other plants both in the open air and when grown under glass. It is nearly allied to a fungus called Pythium de Baryanum, which causes a like destruction among seedling plants, generally known as “damping off.”, Both fungi are essentially lovers of moisture, and do but little destruction in dry weather. Phytoph- thora reproduces itself in several different ways; and its oospores care capable of lying.dormant for as much as four years without losing their vitality. (Hartig on Diseases of Trees, 1894, p. 45):— “Tts gonidia (such as are formed on the surface of a Cacao pod), are capable of being blown by the wind, or conveyed by animals, insects or men. (Hartig.) ” Tubeuf, in his work on the Diseases of Plants, 1897. p. 116, says :—“ Preventive measures against the whole group of fungi to which Phytophthora belongs consists in the destruction by burying or burning of diseased and dead parts of host plants, which contain the hybernating oospores, by change of crop on infected fields, and by treatment with copper re-agents.” Phytophthora is said to cause an infectious disease. Once a cacao pod is infected, the fungus permeates the pod by means of the slender fungus filaments called hyphe and protruding through, DISEASES, ETC, 63 appear upon the surface in the form of white mould. The hyphae is enabled to pierce the epidermis from the inside by the action of a solvent substance, excreted by the growing tip of the hyphe, the protoplasm secreting a ferment which passes out and enables the tip to corrode and dissolve away the substance ‘of the cell- walls. When the hyphe has protruded from the surface conidia or sporangia are developed, and these sporangia again give rise to swarm cells, which have the power of movement in a drop of water. ‘‘ When a conidium germinates in a drop of dew or rain, the normal process is as follows: The protoplasm in the interior ‘of the pear-shaped comidium becomes divided up into about twenty or thirty little rounded masses, each of which is capable of very rapid swimming movements, then the apex of the -conidium bursts and let these motile zoospores, as they are called, escape.” (Marshall Ward, p. 280). Each zoospore then swims about for a time and at length comes to rest, commences to grow in about half-an-hour, and then begins to bore its way again into its host. “The whole process of germination and the entrance of the fungus into the tissues, up to the time when it, in turn, puts out its spore-bearing hyphe again, only occupies four days during the moist warm weather in May, June and July.” (Marshall Ward). It is probable, therefore, that under the conditions of heat and moisture, which exist in Trinidad, the organism will have still more rapid growth than in a temperate climate. The average size of a conidium, according to the above author, is 1-400th of an inch long by 1-700th of an inch broad, and the zoospores have a diameter of about 1-200th of an inch, Having such measurements it is easily seen that a single drop of water gives them as much room for movement, compara- tively speaking, as a minnow would have in a mill pond. When the fungus filaments, mycelium or hyphae, have become fully developed, many branches begin to form an oospore or egg-like spore. _ This spore is formed in a swelling of the free end ofa branch of the hyphe and contiguous to it is formed a differen- tiated branch of the same hyphae, known as an antheridium, and between these two organs, fertilization takes place. It has been noted that some 700,000 oospores may be found on a surface of less than a square inch. The oospores reach the ground in the decomposing part of plants, and it is this fact which has caused us to recommend the entire destruction of all decaying material in so strong a manner, from the time the subject was first dis- 64 DISEASES, ETC. cussed. Soil containing cospores, taken from a diseased seed bed, is said to have given rise to the disease four years afterwards, and it is therefore easy to see how readily these spores may be preserved in the decaying masses of broken and empty pods so often seen upon a cacao estate. No previous record can be found shewing Phytophthora as destroying fruit in the way that it does the cacao pod, its chief ravages having taken place on the leaves of seedling plants. With regard to remedial measures, nothing has to be added to, or taken from the former recommendations made under this head, when attention was first called to the matter, the essential point of which was, to destroy .all infected material as soon as such comes under the observations of the planter. The examination made at Kew reveals the further fact of the existence of a second parasitic fungus upon the material sent home, which proves to be new to science. This fungus has been determined as Nectria bainit, Massee n. sp. This organism is one known to botanists as an obligate parasite, and has been shown to produce ulceration or “canker” in different trees. As the canker of the Cacao tree in Ceylon is said to be caused by a Nectria, it is obviously the duty of all connected with the culture of Cacao, to watch closely whether the organism which has now been brought to light, is rare or plentiful in our plantations. It has been observed on the young blackened pods. Therefore, it cannot be said that the work is finished in regard to the investigation of these organisms, as it must of necessity be carefully continued, if our planters are to obtain that measure of protection from these fungoid pests which appears to be desirable. Phytophthora may be readily cultivated in a nutrient fluid, composed vf Agar-Agar and mucilage obtained from a half geown pod, sterilized and placed in ‘‘ Petii” dishes ; and its growth can easily be studied in an ordinary “ drop culture.” In the “ Petri” dishes it produces a characteristic out crop: on the surface of the jelly, of small white circles. The disease can be at any time reproduced on the half :ipe or full grown pods from this cultivation. Fortunately there are several Saprophytic furgi which cover up and appear to destroy the conidia of Phytophthora, aud besides these [have noticed a small mite vr ucurus, which completely: “Phytophthora omnivora,”’—The Fungus causing the “ Cacao Pod” Diseuse, highly magnified. (After Lartig.) As seen on a beech leuf. DISEASES, ETC. 65 destroys the whole growth of the parasite from the exterior of the pods. These are probably to be regarded as natural enemies. of the fungus, and may help in no uncertain way to prevent its spread. The facts of the case are now before us, the enemy is. known ; and it is now quite certain that we are facing no new danger, but one which has long been present, and one which. we have not much cause to fear if proper measures are adopted. to secure the destruction of infected material. Persons possessing a microscope may compare the material from infected pods with the drawing of the fungus which J have. had made after an illustration in Hartig’s work on the diseases of plants, It is now clear as I anticipated in a previous report, thab the disease is propagated largely in the heaps of decaying material which arise from the opened pods being left upon the field, and the first measure to be adopted is that all the empty pods must be removed from the plantations and either buried or burned. Further study is necessary before anything can be said of Nectria bainii, Massee ; as we are not as yet advised on the extent of its distribution. This fungus being new has been. named by the Kew authorities after Mr. J. P. Bain of Ortinola who was the first to send pods for examination to the office of this Department. On that lot of pods, however, no satisfactory identification of the nature of the disease could be obtained, and it was not until the receipt of other pods that the organisms. were recognized. It was then proved that the fungus could. destroy a healthy pod in some six or seven days, if inoculated with the conidia from an infected pod ; showing the infectious. character of the disease. Frum these pods also, the cultures. sent on to Kew were obtained. These proved in the words of the Director, Sir W. T. Thistleton-Dyer, “excellent material” for the final identification of the organism causing the- disease. It may be mentioned that /’hytophthora omnivora is an organism known long years ago, and has a wide distribution throughout the world. A careful experiment was made with beans from rols affected with Phytophthora and it was found that samples of diseased and healthy beans fermented and dried at the same time and in the sume way, differed very materi lly in weight. E 66 DISEASES, ETC, Tn the sample under observation 432 beans from healthy pods weighed | ih. but it took 565 beans from diseased pods, to make that weight, which is a loss of nearly 25 per cent. Professor Harrison called attention to what was probably this disease in his pamphlet on the cacao soils of Grenada, and made analyses of the diseased pods. The following table gives the composition of the dry matter of the whole fruit of the variety Forastero, in a healthy, and in a diseased state, and is followed by remarks by the Professor :— Healthy. Diseased. a, Organic matters bik 95:93 94 43 Phosphoric anhydride ... ‘81 59 Sulpburic anhydride... 18 19 Sodium chloride wise U6 gel Tron peroxide sie 05 04 Manganese oxide wea traces ‘01 ‘Calcium oxide ee 22 27 Magnesium oxide in 65 59 Potassium oxide sete 2:03 2°85 Sodium oxide ia 03 ‘40 Silica a 04 59 100-00 99-98 Taking into consideration that the healthy fruits analysed. were quite ripe, whilst the diseased ones had only attained about two-thirds of their normal development, the variations in the analytical figures have but little significance. As the contents of nitrogen and of the mineral constituents derived from the soil varied but little in the two cases, probably the prevalence of black cacao in any place is not connected with defects in the ‘composition of the soil, Wherever it has been seen occurring. the diseased condition bas appeared to be closely connected with an undrained condition of the soil or with dampness resulting from over-shading and over-crowding the trees. The remedial treatment consists in the proper drainage of the soil and, judicious pruning of both the cacao and shelter trees to let in light and air. All affected pods should be separated: a, Containing nitrogen ees 152 1°64. DISEASES, ETC. 67 from the apparently healthy ones, broken at a distance from the trees and the husks either burnt or else treated in heaps with ‘quick lime and covered with soil. As an alternative the husks might be treated with a solution of half a pound of sulphate of iron (green vitriol) to one gallon of water or with Bordeaux mixture, but we are satisfied that the destruction of the pods by burning is the most effective process. (Signed) J. B. Harrison, M.A. There are probably several other parasitic fungi which affect the cacao tree, but those mentioned are all which have been properly determined as growing upon the cacao tree in Trinidad. Among the insect. pests of Trinidad there is none for the planter to contend with worse than the “ parasol ant” (Zcodoma -cephalotes) and the “cacao beetles” (Steirastoma histrionica) and allied species. Steirastomz depresea has been found destructive to Cacao in Grenada. The beetles attack the plant by deposit- ing their eggs in crevices of the bark or small wounds, or under the bark in holes made by the, insect itself. The larve when hatched, cuts long channels through the soft wood of the branches to such an extent that a slight breeze will break away the branch, and sometimes the attack of the grub or larve is so persistent as to kill the tree. The larvae may sometimes be destroyed by probing the holes with a stout wire, thus impaling the creature at its work, This is not always possible, but where the life of a valuable tree is at stake, every endeavour shquld be made to arrest the destructive progress of the larve or grub, which can generally be found and destroyed without much injury to the tree, if a close and careful examination is made. In cutting out a grub, care should be taken to make the wound 2s small and as little jagged as possible, and to cover it at once with the mixture recommended in a former part of this work for covering of wounds made when pruning. The Parasol Ant is truly the béte noir of the Cacao planter and generally of the Agri-Horticultural community. Until one becomes fully acquainted with the persistent depredations of this creature it is hard to realize what an immense amount of damage is effected by it alone, So much is this the case that the Legislative Council of Trinidad lately passed an Ordinance which enables thé Governor to declare certain districts infected, and to enable planters to take means for their destruction. The destruction of this pest is extremely simple, but from the persistence with which impiegnated females seek the spots 68 DISEASES, ETC. that contained former nests, an equal persistence and careful watching is needed tu keep the ground clear. Where cultivation is conducted in proximity toa large area of forest lands the matter becomes a very difficult one indeed, for not only have the local nests tu be destroyed but also those in the distant wood- lands, and especially the large nests, a raid from which will frequently do irreparable damage to a plantation in a single night. There are many methods in use for compassing their destruction, the most common being that of digging out and puddling with water. Some forms of destruction are suitable for one locality and some for another. Where a constant watch for new nests is regularly kept, ay at the Royal Botanic Gardens, they do not become of any great size before they are discovered, and a dose of coal tar poured into their nest effectually disposes. of them, once and for all, at that particular spot, as they never again return where coal tar has once been-applied. Other nests can best be attacked by using the fumes of sulphur driven in by bellows or fan. A handy machine lately introduced, costing some $24.00, known as the “Asphyxiator,” can be used with sulphur or any other chemical producing deadly fumes. These ants will, when on raid from a large nest, make a track as much as 10 or 12 inches wide (from which every portion of herbage iy carefully cut away) for the purpose of carrying home to the nest the leaves they cut from the trees, and several large trees are often completely cleared of leaves and fluwers in the space of a yingle night. ach ant is able to carry a piece of leaf half an inch in diameter, and huld it in its mandibles above its head, resembling when on the march the sails of a fleet of liliputian schooners dipping and swaying to the wind. Belt, in the Naturalist in Nicaragua, studied these insects and came to the conclusion that the leaf is not used primarily for food, but is chewed up, and placed in a position where the mycelium of certain fungi at once attack it, and form fuod for the ants and their larve. Certain it is, that a peculiar mycelium is found permeating the inside of every nest, and gives te it a peculiar odour of its own, which once recognized, is again easily distinguished. Belt’s observation has since been confirmed by the observations of the writer, who fur several years had artificial nests under observation. In these the ants could be seen feeding themselves and their larvae upon the conidia of the fungus, which is actually cultivated for food by these creatures, There are several species of aphides or p'ant lice &e., which attack Cacao, but unless the plant is in bad health from some ether cause they seldom do any great harm, especially if clean'i- aess and order, are the rule on the plantation. Tt has been found however that iv-is.quite possible for any biting or sucking insect ‘DISEASES, ETC. 69 ‘to infect a Cacao pod with the spores of Phytophthora omnivora or with those of Nectria. With these are found an attendant species of ant, as occurs on many other species of plints, but the ant in this case is practically harmless, Wood ants also infest tree: on which there is decayed wood, or wood in process of decay; but the remedy for such attacks is obviously the removal of all dead or dying wood, which should never be allowed to accumulate on a well ordered plantation. Among the vegetable parasites there are one or two species of Loranthacee, which affect Cacao. These are mistletoe-like plants which are true parasites, and do considerable harm to the trees, and should be at once removed with a sharp cutting instrument as soon as seen. If the branch on which they are affixed can be spared, it should also be removed, as it is liable to reproduce the plant from the seat of union between the parasite and the tree. There are also one or two species of Cuscuta or “ Dodder” which cause considerable damage. These plants are known as “God Bush” and “ Love Vine” in several of the West Indian Islands. Ina well managed plantation they are at once removed from the trees in their younger stage, for if allowed to spread they weaken and eventually destroy the trees they affect. There are a large number of so-called “ parasites or orchids” which are found to grow on Cacao trees. Among these may be mentioned Zillandsia, Peperomia, Anthurium, Philodendron, Marcgraavia, and several species of true orchids.* True parasites such as Loranthus and Cuscuta, evidently weaken the tree by the abstraction of its juices, but the epiphy- tical growths do not take any nourishment from the tree itself, but obtain their nourishment direct from the atmosphere and from particles of food carried to their roots by the rain that falls, only affixing themselves to the tree as a holding place or suitable position for carrying on their life’s work. It is doubtful therefore if they do any direct harm to the tree, but nevertheless, 4 plantation having trees covered with such growth cannot be said to be under good cultivation, and it * The word ‘Orchids or Parasites’’ is applied indiscriminately in Trinidad to any kind of parasitical or epiphytical growth which appears on the Cacao tree. 70 DISEASES, ETC. is certainly conducive to the maintenance of the health of the tree that they should be regularly removed, as they prevent a due circulation of air. With regard to mosses and several of the lower forms of cryptogamic life which infest the trunks and branches of Cacao. trees, it is sometimes argued that they are beneficial, others however declare it best to remove them. One reason given is, that if they are removed, the process of removal will invariably destroy numbers of the flower buds which are produced on the trunk and branches. That this argument is sufficient I much doubt, and I saould be more inclined to maintain the trunk and branches (which are the fruit producing portion) in as clean a state as possible, taking care however, to enjoin the workmen to. remove these growths with the greatest care possible, so as not to injure the “cushion” or node from whence the flowers are produced. The squirrel and the rat, are both great enemies to the- Cacao planter, and it is always found that they select the best class of pods, not alone on account of the thinness of their pods, but also owing to the greater amount of sweetness that the pulp. of the Criollo varieties possess. It is for this reason that in some instances the Yorastero or thick podded varieties are planted, instead of the finer sorts, and the same argument applies to the damages done by mice, which are plentiful in some districts. The rat-like oppossum, known locally as ‘“ Manicou Gros Yeux,” is similarly credited with doing damage to Cacao, and is. invariably destroyed when found, on that account. A CHAPTER NTI. Export of Cacao.— Value of Estates,—Buildings required. —Labour, &c. Export oF Cacao. yi HE export of Cacao from Trinidad has been gradually increasing for many years, and it is probable that the exports will probably continue to increase for some years to come as the area under cultivation is being extended largely, year by year, as is shewn by the statistics of the Crown Lands Office. The following table which has been kindly compiled for me by the direction of the Collector of Customs (Hon. R. H. McCarthy) and is a valuable record of the Exports of Cacao from Trinidad during the last decade:— RETURN OF EXPORTS OF CACAO. PRODUCE OF COLONY OTHER THAN PRopwcz or CoLonyr Years. Quantity in Ibs. | Value £. Quantity in Ibs. Value £ 1891 16,188,493 439,786 2,382,784 69,694 1892 25,041,635 648,103 3,879,542 113,061 1893 19,106,553 535,055 2,707,491 80,415 1894 21,608,384 509,808 2,920,926 77,756 1895 29,458,813 620,634 3,098,772 73,978 1896 | 23,481,848 | 452,141 | 4,574,965 98,447 1897 | 23,840,665 | 532,123 | 3,917,654 73,567 1898 | 24,340,960 | 705,956 | 3,855,264 | 106,316 *1899 25,645,760 679,231 3,182,144 80,601 * To half year ending 30th June. 12: EXPORT OF CACAO, ETC. The exact acreage producing these crops is unknown as no facilities exist for ascertaining what acreage is under cultivation. In Ceylon the area under cultivation in 1892 was estimated at 12,000 acres. The crop for 1891 was 20,000 ewts, Trinidad therefore produced seven times as much as Ceylon at that date. It will be seen from this, Mr. McCarthy’s table, what an important article of commerce this product is, and as the cultiva- tion is spreading in nearly every district of the Island it is pro- bable that in a few years’ time the value of the export of Cacao will exceed that of all other vegetable products combined. With such a fact before them, it is especially incumbent on the Cacao planters of Trinidad to seek every means to improve their pro- duce so as to maintain a superior article and to be first in the markets of the world. The Ceylon planter has succeeded wonder- fully well in obtaining good prices, but it is questionable whether his Trinidad confréere does not obtain from his Forastero trees, a better return per acre, than his Ceylon brother does. From the late Dr. Trimen’s Report it appears almost certain that the quality of the bean as grown from seed imported from Trinidad is improved by Ceylon culture. The intending planter can obtain Crown Lands from the Government of Trinidad on petition at the upset price of one pound sterling per acre, exclusive of survey and other fees, but all lands are subjected to public competition before the grant is made, so that if two applicants require the same ground, it is finally obtained by the one who has the longest purse, or who is willing to pay more than his competitor, above the upset price. There are in the usual course of business small and large estates constantly passing through the market, and the price of these vary according to the locality in which they are situated, and the quality of the land. The value of an estate is usually estimated at per tree, or per 1,000 trees and not at per acre, and what might be worth in some districts but 60 cents per tree, would in other and celebrated districts be worth as much as $2 or S/4d. per tree. The best course for the intending investor is to make himself acquainted with the several districts and await his opportunity, residing in the colony and adding to his experience in the mean- time, In Trinidad as everywhere else, there are those present EXPORT OF CACAO, ETC. 73 who will not hesitate to recommend estates to buyers simply for the commission they could get from the seller, and there are others again who will accompany an intending buyer in a friendly way to visit an estate and afterwards attempt to recover an exorbitant fee for their services. Let the investor beware of such or he will probably be landed in a similar plight to that of “‘Mark Tapley,” but it is questionable whether there is “any credit in being jolly” under such circumstances. Good estates have to be waited for, and are always readily disposed of, so that the buyer should quickly make up his mind when he sees “a thing going,” which is fairly in accord with his ideas. The yield per acre, or the yield per tree of a Cacao estate is the best test of its value, especially if reliable reference can be made by the seller to the crop harvested for two or three pre- ceding years. Cacao trees begin to bear in the third or fourth years, and sometimes precocious trees will even begin earlier than this, but it is not well to let them produce a crop, as bearing will infallibly retard their growth. Dr. Morris writes (Cacao and how to cure it) :— At the sixth and on their ninth years, the Cacao tree should be in fair bearing, but they seldom reach their prime before their twelfth or fifteenth year. After this period where the trees have been carefully established and well cultivated, a Cacao estate is a comparatively permanent invest- ment, and it may be expected to continue in bearing and yield remunera- tive returns for some fifty, eighty or a hundred years. In fact, if old and exhausted trees are regularly and systematically replaced or ‘‘ supplied” there is practically no limit to the duration of a Cacao estate. The yield per tree will be seen to depend entirely upon the -quality of the land, the size of the tree and various other attend- ant circumstances, but is generally considered that a yield of 1-6 ibs. per tree which will be 10 bags of 165 tbs. each to 1,000 trees, is a first-class yield, 5 bags per 1,000 trees or 0°8 Ibs. per tree would be considered a poor yield. Taking our trees to be planted at 15 feet apart, there will ‘be 193 trees per acre nominally (of course it is never possible to maintain this regularity, on account of roads, drains, &c., but for the sake of method in the estimate we accept this number) and the yield per acre will be 193 x 1-6 tbs. = 308°8 bs. which, valued at -80/- per cwt., will produce the sum of £11 peracre, Calculating the trees at 12 feet apart we get 302 to the acre, and these at 1:5 ibs. per tree, the value per acre would be £16 3. 74 EXPORT OF CACAO, ETC. These statements were freely criticised on the issue of the- first edition, and a prominent planter wrote: ‘It is an error to state that a yield of 1-6 lbs. per tree, which will be 10 bags of 165 lbs. each, to 1,000 trees, is a first-class yield. That is an average, a high average possibly of Trinidad cacao estates ; but a first-class yield could not be under 12 bags per 1,000 trees, and in many cases 15 bags.” I see no reason however to alter the figures given in the- first edition. The working expenses of a plantation may be calculated at £3 to £5 per acre annually, more or less according to circum~ stances, facilities for obtaining labour, easy transit of produce, &e., &e. It is calculated that an estate can be established by the contract system at a cost of about £12 to £15 per acre, exclusive: of buildings. A record has been published ofa single tree which made a yield of 36 lbs. in one year, but this was exceptionally: placed, and well treated to manure. In the Royal Botanic Garden 7 lbs. of dry Cacao has been obtained from a single tree- at one picking. A method of calculating the value of an Estate was given in the Agricultural Record for 1892 as follows :—‘ Note the quantity of bags produced; that multiplied by 100 or 150 according to the quality of Cacao, facility for transport, healthy locality, buildings on the spot, &c., &c., will give correct value of the estate in dollars.” This is to say a latitude of 507 is allowed. an estate for the possession of the points mentioned. Buinpines Requirep. The buildings required on a Cacao estate are few. Where the proprietor is resident—and he always will be, if he wishes his estate to pay—there must be a comfortable residence, and therefore the expenditure under this head cannot be laid down, but must be left to the individual taste of the planter and the extent of his means, : The most important buildings on a Cacao estate are the drying houses and sweating boxes. These are generally built all in one. The sweating boxes being placed under the drying EXPORT OF CACAO, ETC. 75 floors, but sometimes they are separated, and we believe that. this latter course is the best, as during the process of fermenta- tion much moisture is given off by the bean and this cannot be- conducive to the quick drying on the floors above. The cost of houses for an estate of 300 acres would probably be some £200 to £250 each or perhaps more, if substantial buildings are to be erected and artificial drying resorted to, and several of these would be required as an estate developed. A single house will be sufficient to commence with on an estate made from Virgin Forest as the crop will be gradually increasing from year to year, and the necessary drying space should be extended so as to keep pace with the number of trees coming into bearing, but it is always better to have ample drying space, than to be for one moment cramped for room ; for much is lost and nothing gained by such a policy, as there is a liability to spoil produce when there is not sufficient room in the drying houses. It is generally considered that 80 square feet of drying surface is sufficient space for drying the produce of 1,000 trees, taking the crop of the year from beginning to end. If the planter therefore can find out what it will cost him to provide this area he can easily estimate for larger surfaces, the cost of building entirely depending upon the district in which the- plantation is situated. Next to the drying house a good storeroom and office should’ be provided and a proper range of labourers’ barracks may be required where labour has to be brought from a distance, Lapour, &e. It will be found much better to attach labour to an estate by the allowance of house room, provision ground or other privilege, than to employ casual labour as it presents itself, as. there is much more interest taken in the work when the labourer in a measure “belongs to the estate,” and looks upon it as his home, Skilled labour is highly requisite on a Cacao estate, 2.¢., the labourer must be accustomed to the work, and the higher the class of labourer employed the better will the estate be worked. Such labour is however not always obtainable, but it is certainly the best when it can be had. We are not here speaking of the- manager, foreman or ganger, but of the field hands for the pur- pose of carrying on the general work of the plantation. With. 76 EXPORT OF CACAO, ETC. managers and foreman generally, it is evidently to the interest of the proprietor to employ only those who take an intelligent interest in the work they have to carry out, and who take pride in preparing a quality of produce which shall always bear the highest stamp. With such men careful experiments may be carried on, which will lead to improvement and economy when compared with the methods now in use. The cost of labour is an item always enquired about by a new comer, and at times not easily answered, but he will under- stand that this must vary with the district and only a general idea can be given in a work of this kind. The rate of wages on a Cacao estate varies according to the work performed by the labourer, from 25c. to 60c. per day, and much of the work is done by task, a system which is much _pre- ferred by the labourer. os CHAPTER XII, The Agricultural Chemistry of Cacao. HIS Chapter is kindly contributed by Prof. J. B. Harrison, M.A., Government Analyst, é&c., &e., of British Guiana. The main features of the chapter first ~» appeared in an official report by the Professor on the svils of Grenada to the Government of that Island. The composition of the different parts of the cacao tree has been treated upon by Marcano of Venezuela (a) and in part by Boname, late of Guadeloupe, now of Mauritius (d). Opportu- nities for studying the requirements of the plant as represented by the composition of the mature trees themselves being very limited we accept for guidance the result given by Marcano. This authority estimates that a cacao tree twenty years old is made up of — Trunk as wie ave we 495 Large branches tee se we 201 Medium branches ... Be was, LN Small Shoots Sie dite sxe 12! Leaves... ate wae we OE 1000 (a) Essais d’Agronomie Tropicale. V. Marcano. () La culture de la canne 4 sucre 4!a Guadeloupe. Ph. Boname- 78 THE AGRICULTURAL CHEMISTRY OF CACAO, -and that a plantation of trees of this age growing on one acre “will contain— Nitrogen .., as was 201 hs. Phosphoric anhydride =e 95 Bs Potash... ies Pee 251 —=C« Lime wits ass ite 400, Magnesia ... ae ise lll ‘whilst the so-called suckers and other young shoots trimmed -annually from the trees contain*— Nitrogen ... aa sus 84 Ibs. Phosphoric anhydride ies 49 Potash... iss ee 42) oy Lime ag a wee 66 Cg, Magnésia ... is sé 20 4, ‘These together with the leaves which he states contain— Nitrogen ive +e is 39 Ibs. Phosphoric anhydride haa 75, Potash... he Ae 30S, Lime site ane rr 32 Cs, Magnesia .,. ae eas 10s are practically in all cases yearly returned to the soil. The fruit, of which the husks may or may not be returned to the soil according as to whether the pods are or are not broken on the field, are estimated to remove as follows :— If whole fruit removed If the pods are broken from the field. and left in the field, Nitrogen as 155 87 ibs. Phosphoricanhydride 7-9 45 4, Potash eh 22:1 37 (Cs, Lime eee 65 14° ~C«, Magnesia és 2:3 10 * This estimate appears to be excessive. — mie! Cacao Hook—I mproved. THE AGRICULTURAL CHEMISTRY OF CACAO. 79 From these figures it appears that the cacao tree whilst storing up in the plant itself relatively large proportions of the important elements of plant food present in the soil, requires for the yearly productions of young shoots, leaves and fruit not less than 138 lbs. of nitrogen, 64 lbs. of phosphoric anhydride, 94 lbs. of potash, 104 Ibs. of lime and 31 lbs. of maguesia. Under careful conditions of agricultural practice, however, of this great annual drain upon the soil but 8-7 lbs, of nitrogen, 4:5 lbs. of phosphoric anhydride, 3:7 Ibs. of potash, 1 4 lbs. of lime and 1 Ib. of magnesia are necessarily removed from it, the remainder becoming more or less available again for plant food by the decomposition of the fallen leaves, pruning and husks upon the land. Of the, in round numbers, 130 lbs. of nitrogen returned to the soil a considerable proportion, possibly 20 to 30 per cent, may be lost during the decomposition of the vegetable matter, but where the trees are shaded by the nitrogen collecting Bois Immortel or Orunoque trees (Hrythina velutina and E. umbrosa which are used on the islands, or £. glauca which is used in Guiana?) doubtless much of the amount thus lost is recouped to the soil. These considerations lead to the conclusion that a good eacao soil should be one capable of yielding to the tree in the ‘course of years a somewhat high proportion of the important ‘constituents of plant food. without exhaustion, and also capable of rapidly rendering again available the large quantities of manurial matter returned to it in the forms of pruning:, leaves fallen and broken pods. It must in addition be one in which the course of nitrification readily takes place; in other words, a fairly rich friable and well drained soil of prime importance for the successful production of cacao, THE AGRICULTURAL CHEMISTRY OF CACAO. 80 ‘sonpoad jo moavy pue Syrpenb soy qnq ‘sppare £ae0y Jo yuttooo# tio paqooqes 4ott sea ordures stTl—H’H'’ 44 90N, Gy TI 0.8 g.I 1.g 9.6 €.F1 ¥.z1 £.Q S.g [rte TOs porp are Aq poureial J91E My cle. gof. gzz. oor. Soz. vez. 9gz. 12z. 60£. zz. see aes uasoijiu SULUIB}UOZ “Ir 000.001} 000.001) 000.001} 000.001] 000.001} 000.001} 000,001) 000.001; 000.001] 000.001 z1r.€9 | g€h.6S | F6S.z2 | ozg.gg | 176.69 | Er4.19 | 60.08 | €gg.z9 | Lo9.Sq | 996.62 SOJCOTIIS 3 BOTS STQNyOSUT 1Lz. gz. ber. glz. 60£. ZOI.I £61. vLS, £0€. go. ate “ gpixo WHIpoS zbo.t zLo.1 619. gil. gZt. gz. 691. ere, ¥Sz. 167, eee aplxo WAT isLIOg LYS.1 1Lo.1 Liz. S6Pr, gibz ogg. 197.1 LoE.E Lof.1 bor. wae 9pIxo wntsause jy ‘Iu “Tu ‘yu “Tru ‘yIu 660° Sgr. gzo. gtz. zfo. | “* gyeuogieo WINID}e ) gor. Sor. oSz.z | oS. 196.4 €gr.1 It. 6L£.z SEe.t 96s. eas * gpixo wnIoed gol. ‘VU for. lz. SE, 6bz. 6ZE. €1€. 161. LYE, ia eee eee aPlxo assauesue sq g99.hr | gforgr | 41Zb | gfo.z | 6ga.g | ord.z1 | obt.41 | bzo.01 | gzo.€x | 212.6 aes se eulUny y 298.4 | 2$6.¢ 000.4 | o16.€ bL6.6 -| €€0.zr | zlo.gt | Sgr.6 | Sg0.6 | €gl.% ase “* aprxoiad uJ] ‘9081} | ‘a0"17 | Zoo, ‘Tru ‘sa0ed] | ‘s9oer} | ‘saoesy | *]rU *s30e1} | ‘saows} |-** eee a vs aul4o(y.) gsé. Lho. v1, *saoes} | SSo, Lzo. *saoed} | ‘saoezy | gir. gio. ses “* apripdyae sunygdinsg 6or. oft. £6z. +go. bir gSo. bho. gr. zgo. Zg0. ase epupdyue otoydsoy | org.or | z2S¢.S1 | Stgor | goZ.€ gbo.€ 939.6 £66.01 | zhb.or | b¥9.4 1£0.6 |19}@ paurquioo » siaj}eur ouvsIOQ I * n "I ‘ON a 8 tae ‘bon | ‘EON | ‘Z ‘ON | ‘I ‘ON 5 R s | 3 3 & a 8 8 ‘weUTNng 5 a g “epeuain s ysnug ‘hroqwioqe'y yuamuJaaoy oyy —! eueiny) ul paurmexe Ajyuecer silos ovovo pood yo seddy aiv Surmoy[oz ogy, 81 THE AGRICULTURAL CHEMISTRY OF CACAO. T-F1 F-0T a8 9-L 9-1 ia 6-1 eT [los porip sre £q poutuyed 1498 AA TLT- 60T- LST 10: 298. £90: 190. LL” Rese DasosjtU Burayyyuoy *T 000-001 | 000-00T | 000-00t | OOT-OOT | O0OOOT | 000 00T | 009-00T | O0C-D0T 982-98 er 99 188-89 eG8- TL $83-19 9F8-F6 999-88 226-06 se goqMaT[Is 3 BOLTS ET {N[osNT 08s: 098. 868- POL: £00- L80- aad OUT: nee nee eee eee apr XO WURIPOS 9¢0- 160+ 1F0- €R0- T¥O- 620+ TCO 60T: pa See OPIX WMISS & OT Fle: OgT- arr: 669-T 199- ZL0- 1¥0: eaF- ee opixe wUIs.UATAL $9B- ZGT. "e0uI} ‘oaBAL [0 [la “ru “[a ee eee EYBNOGABs WIULO[ Hy ta 96T- FRG LOL-F OT0- 10. 928 “e0vl} ae “** aplxo WNIT) 068 #80. : GOT LEP. “ya ce. 00: 800- ioe Vie eprxoiid ovomuszuryy 26-98 €0F-ST | 808-TT FLE-L 698-9T PERT FIG-L "68-8 per ES sess VOLO 6FS-26 679-6 008-FT 669-6 PLAS 266- 180°F 188-4 thee eee ee oprxodad wou *O0B1} "BABI “O0BAY ining! “QOUly *|ta “yu “OOUAY oe see) *** @QLIO/G\) 660: 8z0- 180- cr). ‘yea “Et IIT LTO» = epripéqus ony uy 0¢0- OaT- F20- eT0- Leds 00: 020- TZ0- see ee oprap£yue o1104d-0ucf 168-81 $€0-8 OF9-41 620 & TOL-8T 106-T ILF-F 98L-8 “**104UM POTIG OO PUY B19 4z¥TI OL UVBA() ‘e ON | °3 ON ‘LT ‘ON |yuoourA Ig) ‘TABUTIng | *¢ "ON % ‘ON ‘TL ‘ON “epBualy *eIVIOMIE —: Lrojovysyyesun 19a ore spyoik oy} yorya uodn ‘s10s ovoeD aood jo sojduvxe aie Supmoyloy ony, i] 82 THE AGRICULTURAL CHEMISTRY OF CACAO, _ For comparison, I insert the following Analyses made by P. Carmody, Esq., F.L.S., Government Analyst of Trinidad, of Soils from Cocoa Estates in Trinidad and Venezuela :— ANALYSIS OF SOILS, SANGRE GRANDE DISTRICT, TRINIDAD. Sample No... es 1 i) eo rn Composition oF Airn Driep Solits. Water ... ase on 6.04 3.56. 9.48 3.66 Dry Soil... gh .{ 93.96 96.44 90.52 96.34 100.00 | 100.00 | 100.00 | 100.00 ComposITION OF THE Dry Solu. *Loss on Tgnition .| 6.641 6.097 7.004 8.948 Tron Oxide, Fe, 0.5, 2.327] 2.343} 2143] 2.440 Alumina, Al, 0.5, 3.798 | 5.171] 5.652] 5.313 Lime, Ca. O. 128 084 124 148 Magnesia, Mg. O. 445 498 405 284 Potash, K., 0. 183 223 267 217 Soda, Na ,0. 173 021 081 142 Phosphoric Acid, P.p O., 133 | .096 117 116 Sulphuric Acid, 8. O., All| 053 102 .025 Chlorine, Cl. .005 .006 .008 .093 Insol, Silicates | 86.056 | 85.408 | 84.097 | 82.364 100.000 | 100.000 | 100.000 100.000 *Containing Nitrogen ... 131%) 107% = 140% 1658, Ce... Carbon... 234 Ad .139 224 {Equal toHumus ..., 403 | 784 | 242 | 386 Nitrogen as Nitric Acid...) .00253 | .00298 | .00235 00335 Reapviry AVAILABLE Porasn AND ProspHatTKs, Potash, K., O. | -O9149%) .12909%) .1162%) 0881% Phosphoric Acid, P.. O.,| .0510 .0564 .0159 -0465 83 THE AGRICULTURAL CHEMISTRY OF CACAO FOT’ | 90" 480 Tor | TOT} Zor} azo" | 20" | Teo" | 220" 280 0 Fd “ploy otogdeong e/og¢o° |>/oggo" jofozstt: jo/ogegt: lofotzot: |ofogegt: oJoggrt: |fogzer’ jo/o1Fgt: jofoger’ | fozozt: | “O oy ‘ystiog “BULVHGSOH A GNV HAVO F1dvilyay XUAVAY 6090" | OTAO" | F6A00" | 84000" | L6008" | BITTON" | 2g100° | ezeoo" | steo' | gtoo’ | ges00" | SOIBMIN SY UATONTN ie 6F3" T9¢° eLg’ gre" 048" £63" Tee" abo" are" gee jsut og pwnby | ase eee eee wae eee eee wae eae eon eee vee Lal saaal One oe * ofog6o" |alozao" frfoott jo/ozog" |ofoeza’ jfozan: |ofontt™ jofoset’ | foxer lofoest: forgot fe Bure ue, (0°00T | 000°00T | 000°00T | OD0°00T | OnA‘ONT | E90'00T | H90'00T | 000°001 | DOO'OOT 000°00T | 000°00" 9£9°68 | ZTo e8 | zeros | tees | ett 62 | OTS-9L | 2zL°TG | 296'68 FOG'SL | ORV EB | SOWING ‘JosaT 900° £00" 200° NO" P10" 60 gin” 70° 00° ato 1D ; = iS "800814 | ‘Raney | GEN 260° gto" sai C80" 670° 9¢0" 920180) 8 ‘ploy otinedjug SIl 6eT° BRE 802" OzT" 6FT" eer CFU 192" LT (70 Fa poy ofaoqd-ogiy L90" 986° ie “* (penten2ey/ ap 10K Ee oe oP ION | LLL *O FUN “epog FITT | gate) L¥3" sen | aga 81B" | BIR 96° EOE ‘0 Fx _. a88I0d IG" vor" 808° G12 OTe 9L0° 10T’ 162° eRL ‘O “SIT Spec eet" 818° 908" Tee" e0r e19° 00s ors" #69" ‘0 -*O aut sand OIF “ vee on wee ee ane ore ls 0 *1¥" “enluinyy oles | 098s | 0G9°F NEL ET | COSZE | OTF F | O00'S RGF | O08" } FO Fog fapixQ WOdT 099 | OFS | 000'6 0oL9 =| 0686 | OLee | OcseE ooLL | OT9'L | : TONMAT uO gs0'], : “MOQ LACT WH; AO Nomigoawon 00°00T | 00°COT | OO'OOT | On'OnT | OO-0OT | OO'OOT | ON'oOT | OO-0OT | 00°00T | 00°0NT | OO'O0T cFL6 | Lesh | anes | ses | c9e3 | rte | gee | OF-KG 08°06 £406 | 92°68 a“ “te sylog kay 89% 83°F 86% | OLb | er ae'¢ FOT U9 L 026 LEG FL‘OL ; ~ darn AY *SATANVG aarct my JO NOLLINOaWOD ‘II ‘I ‘II ‘I "II | ‘tT |-setacqr ‘pow +1 | vow 11] ea I] (eg mat poor) e] *yaatas} TOP “p80P Ug ‘aoresuadm0g eq! *B[OUTT.ID, | "HON ~“enzauaA ‘QVCINIUL GNV VIUTNAZANHA WOU SITIOS OVOVD JO SISA'IVNV 84 THE AGRICULTURAL CHEMISTRY OF CACAO. The samples from Grenada, St. Vincent and Demerara were personally selected, whilst those from Trinidad and Nicaragua were given to us and described as very fertile cacao soils by J. H. Hart, Esq, F.L.S., the Superintendent of the Botanic Gardens, Trinidad. With the exceptions of the Surinam, Demerara and Trinidad samples, all are of soils arising from the degradation of lavas and volcanic debris, rich in soda lime felspars. Asa rule these fertile cacao soils are fairly rich in nitrogen, and contain a somewhat high amount of potash, of which a relatively high proportion was found to be soluble in 1% citric acid solution whilst the proportion of phosphoric anhydride present appears to be of lesser importance. They can, we consider, be safely regarded as reliable types of the composition of really fertile cacao soils. As far as present experience gves in the selection of good reliable soils for cacao cultivation, if the physical conditions are in accordance with those mentioned in a previous paragraph, the most important point chemically is that the soil should contain an ample supply of availablej potash, a fair supply of nitrugen and a medium one of phosphoric anhydride and of lime, and should have either from its{chemical composition or its physical condition a marked retentive power for hygroscopic moisture. On soils of this kind large and remunerative crops of cacao may reasonably be expected even during seasons during which on other lands crops may suffer from drought. In order to obtain reliable data as to the composition of cacao grown under fairly favourable conditions at low elevations, Charles Ross, Esq., of Pln. Land of Canaan, Demerara River, supplied us with a large number‘of freshly gathered ripe pods of Cacao of two varieties: lst, the small podded, thick, smooth skinned variety with flat beans, known as Calabacillo; and 2nd, the large podded somewhat thick rough skinned variety with full tounded beans, known as ‘“ Furastero.” The former is the variety agriculturally best suited for heavy lands, being the hardiest of all varieties, and giving oa low lying land, by far heavier yields of cured Cacao than “ Forastero” does, In addi- tion we obtained from him cured heans of these varieties, May other, varieties are to be fuund growing in greater or less. THE AGRICULTURAL CHEMISTRY OF CACAO. 85 abundance in the cacao groves of British Guiana including the Criollo or Caracas kind, but as the bulk of the crops appears to consist of Forastero and Calabacillo Cacao, principally of the former, attention was confined to them. The fresh pods were found to yield as follows :— Calabacillo, Forastero. Husk me 80°59 ae 89 87 Pulp ie 761 ‘ee 4:23 Cuticles of Beans 1:77 aa 50 Kernels of Beans 10-03 aie 5:40 100-00 10.00 The yields of cured cacao are 37:5 and 35-6 per cent, of the beans and pulp of the two varieties respectively. Hence 100 lbs. of the fruit of Calabacillo will yield 7:25 lbs. of fermented cured cacao and 100 lbs. of the fruit of Forastero 3-6 lbs. There would appear to be a distinct advantage in growing cacao of the variety Calabacillo ; but the difference in the market value of the small flat brands of this variety and in that of the large plump beans of Forastero very materially reduces the apparent advantage while comparatively upon light soils of higher elevation the agricultural yield of Calabacillo is frequently less than that of Forastero. The fresh fruits were rapidly divided up into the outer husks, the cuticles of the beans and their adherent pulp, and the inner kernels of the beans or cacao nibs proper. The cured beans were also divided into cuticles and inner kernels. After weighing, all ~parts of the fresh fruit were dried at a temperature of about 140° F, uutil they ceased to lose weight, the loss of moisture noted, and the dry material carefully ground up and sampled. Analyses were afterwards made ef these portions and the results calculated back to the original state of the fruits as received. 86 THE AGRICULTURAL CHEMISTRY OF CACAO. The following show the detailed composition. of the fresh fruits of each variety, of the various parts of the fruits, and the- distribution of the constituents in the parts of the fruit :— TABLE I. Wuote Fruit or Cacao, Variety “CALABACILLO.” Water ae ne a 73-790 1. Albuminoids ... ze bee 1:470 2. Theobromine ... ene oe "234 3. Caffeine Peet on wii O15 4, Indeterminate nitrogenous matters... 067 Fat... ane aiid ie 3°093 Glucose Bis wee dae 274 Sucrose Sis ite ae 006 Starch ae se eae 844 Astringent matters eae aise 2-332 Pectin, etc. ... died ae 5231 Cacao-red was els as “888 Digestible fibre re — 5-405 Woody fibre... bu se 3122 Tartaric acid free i sie +324 Acetic acid free ies ait 054 Tartaric acid combined... i “716 Iron peroxide ... dex “ts 008 Magnesia oe i os *120 Lime See sh ae 042 Potash vis me ine 468 Soda ae ror Sis 038 Silica we ues eee ‘007 Sulphuric anhydride ae is 044 Phosphoric anbydride aa am 152 Chlorine awe oe oes 032 99-267 1, Containing nitrogen see es 212 2. 8 » ee ceo 072 3. ” ” eee eee 004 4 ” ” oo ere 0z0 Total nitrogen sn eae 325 THE AGRICULTURAL CHEMISTRY OF CACAO. pore TABLE IT. ConstITUENTS oF THE VaRtous Parrs or THE Cacao Fruit, Variety “ CALABACILLO.” Kernels of | Cuticles Hak Beans. | and pulp. ios Water bes «| 37°637 87-600 82'893 1. Albuminoids ... i 6696 ‘918 *760 2. Theobromine ... she 1:352 241 094 3. Caffeine .. se as 108 841 nil. 4, Tndeterminate nit bios ) F . genous matters f°” 531 traces, 169 Fat “ae ar ace} 299256 “444 "146 Glucose ... ice ia 991 725 132 Sucrose . ae ...| traces, ‘O66 traces. Starch ... a 3-764 945 469 Astringent matters . ? os eed actin aes 5004 395 2-225 Pectin, etc. iv saa 657 “815 1:710 Cacao-red 3 3 2-952 ‘S11 675 Digestible fibre, ete. ae 5112 4-652 D41LL Woody fibre... ve 3°030 1346 3341 Tartaric acid, free sie ‘079 "439 347 Acétic acid, free oe nil, nil. 064 Tartaricacid, combined... ATT “303 "796 Tron peroxide ... ae 032 004 005 Magnesia — aise 324 114 099 Lime... os igs 054 054 039 Potash ... oe ace 142 “190 ABA Soda... ies sa +239 041 041 Silica... ast 016 002 006 Sulphuric anhydride. aed 079 021 042 Phosphoric ae anti aise 749 115 082 Chlorine ws Sea ‘019 018 036 100-000 100-000 100-000 1, Contains nitrogen ae 1-071 147 121 2. a a ee “416 077 029 3. es — 031 ‘012 nil. 4 3 és 085 nil, 027 Total nitrogen oe 1:603 236 177 88 THE AGRICULTURAL CHEMISTRY OF CACAO. TABLE III. DistRistuTION OF THE CONSTITUENTS OF THE FrResH Cacao Fruit, Variety ‘“ CALABACILLO.” Percentage of pce of| Cuticles Husk. ; eans, | and pulp. 10:03 9:38 80°59 Water tee ..{ 3°7751 8:2169 66°7980 1, Albuminoids ... sigs 6716 0861 *6125 2. Theobromine ... bay *1355 0226 ‘0757 3. Cafleine dis as 0108 -0038 nil. 4, Indeterminate _ nitroge- nous matters uaa 0532 traces, "0136 Fat... ate ee] 299343 0413 1177 Glucose ts ae 0994 0680 1064 Sucrose i | traces, 0063 traces. Starch eae vibe 3775 “0886 3780 Astringent matters ... 5019 0370 17931 Pectin, etc. ... ape *0659 “0764 13800 Cacao-red ae aug 2961 0479 5438 Digestible fibre, ete. ... ‘5127 5316 4:3607 Woody fibre ... sd 3039 "1262 26917 Tartaric acid, free... -0079 -0412 “2748 Acetic acid, free Sad nil. nil. *0543 Tartaric acid, combined 0478 0284 6399 Tron peroxide... yea 0032 0004 0048 Magnesia wae aa 0325 0107 0765 Lime ... ace bes 0050 0051 0314 Potash... ne side 0844 0182 3659 Soda ... ei sa 0240 0038 0101 Silica ... 0016 0002 0041 Sulphuric anhydride .. 0080 0020 "0338 Phosphoric anbydride.. 0751 0408 0661 Chlorine wae 0019 ‘0016 0290 10-0293 9:3750 80-4616 1. Contains nitrogen ey 1074 0138 0975 2: ‘5 33 ses 0417 0072 0233 3. ¥i ‘i A 0031 0011 nil. 4 ie 45 0085 traces. 0217 Total nitrogen dx 1607 0221 "1425 THE AGRICULTURAL CHEMISTRY OF CACAO. 89 TABLE IV. Wuote Fruit oF Cacao, Variety “ ForAsrero.” Water aS as ee 81.877 1. Albuminoids ... si aes 1:234 2. Theobromine ... aes a 152 3. Caffeine aids site shes 015 4, Indeterminate ... wea oe 175 Fat ae ase res 1.800 Glucose Pe waa wea °927 Sucrose oie is eee 054 Starch 3 sisi ek ‘780 Astringent matters is Said A24 Pectin, etc. ... so tee 1:022 Cavao-red aad ies oes 684 Digestible fibre ae wis 4:097 Woody fibre... aie és 5-055 Tartaric acid, free dee aie 255 Acetic acid, free ate wars 053 Tartaric acid, combined ... eas 564 Tron peroxide ... ee sus 010 Magnesia ave “i ae 119 Lime axe digs dein 040 Potash wisi ane Said 368 Soda as Ee ce ‘O11 Silica re as aes 008 Sulphuric anhydride wes anid 033 Phosphoric anhydride ae as 147 Chlorine ies ess aid 006 99-910 1. Containing nitrogen see es 198 pe sy 5 oe ose 046 3. Gs 4 nee see 004 4 . » “028 ' Total nitrogen eee ose 278 90. THE AGRICULTURAL CHEMISTRY OF CACAO, TABLE V. ConsTITUENTS oF THE VARIOUS Parts oF THE Cacao Frutt, VARIETY ‘“ FonasTERo.” gore of} Cuticles Pdi: eans, | and pulp. Water ... oe .-| 36°567 83030 | 84-538 1, Albuminoids... ae 4826 1-271 1017 2, Indeterminate a 2-795 a 031 genous matters 3. Theobromine ... sa $22 “348 098 4, Caffeine... “es ets 223 059 nil. Fat ate Sa ..-| 80°602 “421 142 Sucrose ... sas 58 165 1-001 969 Glucose ... oe a3 ‘917 091 nil. Starch ... ee wi 6038 1:305 “445 Astringent matters... 4-894 108 172 Pectin, ete. ... ea 1-380 1:126 *995 Cacao-red - +e 1543 *7U5 631 . Digestible Fibre | oe 2821 6564 4:045 Woody Fibre ... = 3°458 2°455 5288 Tartaric acid, free wae 038 606 250 Acetic acid, free a nil, trace, 059 Tartaricacid,combined... “487 - 351 580 Iron peroxide ... oes 032 “010 009 Magnesia ig? ce 454 | 073 101 Lime... eis aes 105 030 037 Potash ... eos des 635 248 358 Seda ... aoe re 068: 015 073 Silica... eae 016 003 ‘008 Sulphuric anhydride ae 048 031 032 Phosphoric i li ae 1-045 098 096 Chlorine i shia 032 ‘061 026 100-000 100:000 100:000 1. Containing nitrogen... 772 *208 163 2k 4 55 ae 436 nil. “005 3. ay i ast 271 107 030 4, . 3 eed 064 017 nil. Total nitrogen w| 1:543 | 327 “190 THE AGRICULTURAL CHEMISTRY OF CACAO. 91 TABLE VI. DISTRIBUTION OF THE CONSTITUENTS OF THE FrResH Cacao Fruit, Vartery “ Forastrro.” Kernels of | Cuaticles Fads: Name of Part. Beans. and pulp. Per cent. of part ise 5:40 4°73 89:7 Water vas ..| 19746 3.9273 75-9750 1. Albuminoids... oe 2605 0501 9136 2. Indeterminate nitroge- nous matters ... te 1471 nil, 0278 3. Theobromine ... 7 “0476 0164 “OS8O 4, Caffeine hits ane 0119 "0028 nil. Fat ate aoe 16524 °0199 1:276 Glucose ibs “dea 0089 0473 8-708 Sucrose ies ise 0495 “0043 nil. Starch ate ae 3186 0617 -3999 Astringent viditers oat "2643 0051 _ 1546 Pectin, etc. ay 0745 "0532 8942 Cacao-red a 0833 0333 * 5671 Digestible fibre... es 1519 3165 3°6352 Woody fibre ... «| “1867 ‘1161 | 47523 Tartaric acid, free 0020 0286 2246 Acetic acid, free sat nil, trace. 0530 Tartaric acid, combined 0263 0166 5213 Tron Peroxide ... ave 0007 0005 0081 Magnesia 0245 0034 (907 Lime bn ire 0056 “C014 0332 Potash ne De “0343 0117 3217 Soda 2x vA -0036 0: 07 “0065 Silica 0008 “0002 0072 Sulphuric anhydride 0026 0015 0288 Phosphoric ae 0564 "0046 0864 Chlorine za a 0016 0024 0023 5°3912 4:7296 89°7898 1. Containing nitrogen... 0417 0096 1465 oe 5 5 ae 0233 nil. +0045 3. ¥5 99 ant 0146 0050 0270 4 +0232 0008 nil. Total nitrogen ...| 0830 0154 | +1780 92 THE AGRICULTURAL CHEMISTRY OF CACAO. The fruit of Calabacillo contained less water but distinctly more nitrogen, potash and phosphoric anhydride than that of Forastero. The kernels of the beans of Calabacillo were dis- tinctly richer in the alkaloids, also in astringent matter and in cacao-red than were those of Forastero, the result being that the beans of the former variety were of a harsher, more astringent flavour than those of the latter. The beans of the two varieties showed but little difference in their contents of fat, but those of Forastero were of higher contents of starch and sugars. In the cuticles and pulp from Calabacillo there were found somewhat lesser amounts both of the alkaloids and of starch and sugars than in those from Forastero. In the husks of both varieties small amounts of theobromine less than 1 per cent. were found, but no caffeine, which was present in small quantities in the kernels and cuticles of both varieties, was found in either. But little difference existed in the husks of both varieties in their contents of nitrogen and phosphoric anhydride, but those of Calabacillo contained the higher proportion of potash. When, however, the higher proportion of husk in the fruit of Forastero are taken it appears that this variety returns more nitrogen, more phos- phoric anhydride and but little less potash to the soil in the waste husks than does an equal weigh’ of the fruit of Calaba- cillo, But it requires double the weight of fruit of Forastero than of Calabacillo to produce an equal weight of cured cacao, hence the return to the soil by the husks is more than twice as great in the case of the former than that of the latter. Assuming that the average yield here of the variety Cala- baciJlo is 250 lbs. and that of Forastero 150 lbs. of cured cacao per acre respectively, we find that the amounts of the con- stituents of plant food removed from the land annually in the whole fruit, returned to the soil in the husks and either sold in the cured cacao or lost in the sweatings from the fermenting boxes are as follows :— POUNDS PER ACRE PER ANNUM. Variety or Cacao. | CaLaBAcILLo. | ForastERo. Whole |Refuse| ®°82* | Whole [Refuse|5°22* Parts of frnit referred to. fruit. | husk.| 224 | senit. | husk and - "| pnp. | *U “| pulp. Weight per acre, 6,200| 5,000| 1,200) 6,900] 6,200] 700 Nitrogen ... xen ..| 2015) 8°85) 11:30} 19°04] 11°78] 7-26 Phosphoric anhydride .., . 942) 4-10} 5°32) 10-14) 5:95) 4:19 Potash ... see ane «..{ 29-01) 22°70} 6°31) 25°39) 22-19] 3-20 Lime oes ase oe e| 2°60) 1-95 65] 2°76) = 2-29 4G Magnesia ... wee ees wf T44) 4°75] 269} 8-21) 2-66) 1:95 THE AGRICULTURAL CHEMISTRY OF CACAQ. 93 The unavoidable loss per acre in British Guiana as com- pared with that in Venezuela given by Marcano, and with that in Guadeloupe reported by Boname is as follows : — ibs. PER ACRE PER ANNUM. VENE- | GuaDE- DEMERARA. : ZUELA.| LOUPE. Calabacillo.} Forastero. | Varieties not stated. Nitrogen ids | 11°30 7°26 78 7:3 Phosphoric anhydride ...| 5°32 4:19 45 2°8 Potash ... sie wf 631 3°20 3-7 4:3 Lime... ig ox 65 ‘47 14 4 Magnesia — ws| 262 1-95 1 14 There is a general concordance in these results showing the low amounts of constituents necessarily removed from the soil of the production of a crop of cacao. Where the Erythrina is used as a shade tree, manuring ~ should be directed largely towards the upkeep of the potash and phosphates necessary to enable the shade trees to do their part as nitrogen collectors and where no shade trees are used the mineral manuring ought to be more largely supplemented by nitrogen. Thus the following mixtures or mixtures of other materials yielding the same proportions of nitrogen, phosphates and potash per acre might be advisedly tried on cacao plantations :— Erythiina used for shade. Not shaded. Nitrate of Soda na Pe I ewt. ren 2 cwt. Superphosphate of lime 36 % soluble 2 ai ont ton Potash sulphate ae Pa Toe : ” The materials should be well mixed and applied in quantity according to the number of trees planted per acre around each tree at a distance of about two to three feet from the stem. An exceler* way of applying phosphatic manures to the cacao tree is by the use of slag phosphate. This has given highly’ satisfactory results, both in British Guiana and in Grenada. Where plantations are being newly started much advantage to the growth of the plaats may be obtained by mixing the soil in the immediate vicinity of where the cacao is to be planted with from two to four tbs. of slag phosphate meal Attention has also been directed to ascertaining the changes which the Leans with the surrounding pulp undergo during the operations of fermenting aud curing. For this purpose cured beans were anaivsed of the two vrrielies from the same plantation * average rewu. a po. acie asalu.eG to be 450 Ibs. 94 THE AGRICULTURAL CHEMISTRY OF CACAO. on which the samples of the fruits had been grown. The cuticles and the husks of the beans were separately examined, the composition of the whole bean being ccalculated from the figures thus obtained. The analyses were conducted on precisely the same lines and by the same methods as those of the various parts of the fresh fruit. Unfortunately, the two varieties are never, as far as our experience goes in the West Indian colonies kept separate during fermentation, and we were forced to select our own samples from out of a very large sample of cured beans of the mixed kinds. Mr. J. H. Hart kindly examined the samples drawn and considered them to consist of typical beans of the two varieties. The following show the results of these analyses compared with those of the analyses of the similar parts of the fresh fruit dried as befure described in the Laboratory :— TABLE VII. “COMPOSITIONS OF THE DRIED AND THE FERMENTED AND CureD BEANS, CUMCLES AND ADHERENT PULP OF CALABACILLY, ia Fermented and Dried. Cured, Water... 7 i #: 5-000 7169 1, Albuminvids ae aia ee & 704 7213 9, Indeterminate nitrogenous matters ig “681 3°509 3. Theobromine ee aes - 2-023 1549 4, Caffeine aes as % "186 103 Fat... ass os 6 83°181 40-744 Glucose ea se a 2°143 “909 Sucrose sae oe i O79 “O24 Starch ... oan tas r 5-980 5249 Astringent matters a a 9-900 5306 Pectin, ete. ave wate i 1°822 2°67 Cacao-red ase whe a 4°404 2-420 Dige: tible fibre, ete. ss ree 12 048 1'-615 Woody fibre one oe ae 5515 5503 Tartaricacid, free... ire pat 629 0 535 Acetic acil. free ... an «a8 nil. 869 "Tartasic acid, combined By eet ‘974 1114 Iron peroxide ae ane i O44 105 Magnesia a5 wae 04 “BBY “686 Lime ... on wae wed 134 207 Potash .. see is bed 1312 1125 Soda ... oe ae ae "RBS, 120 Sica... ais a ane 022 "065 Sulphuricanhydride aise ote 452 "057 Phosphoric anhydride ies si 1098 1113 Chlotine vas ‘< . 044 020 100 319 , 100°00.0 1, Containing nitrogen wee aye 74 1-080 i a ee ais ay trac s. “640 a, ae + ae aK *492, B15 4, ae a _ se ‘076 “099 Total nitrogen ae re 1542 21340 < THE AGRICULTURAL CHEMISTRY OF CACAO, TABLE VIII. 95 Curictes or Cacao Beans, Variety ‘“ CALABACILLO.” we OS LS See : Fermented Dried. and cured. Water 12-400 12.400 Albuminoids ... “ re 6:092 6°750 . Indeterminate nitrogenous matters . traces. 4006 . Theobromine .. ms 1599 1:023 . Caffeine : it Ae 972 *8D5 Fat ses ‘ive a 2-946 “4000 Glucose , i a 4811 476 Sucrose a eae 941) 143 Starch ‘ is 6-271 4 865 Astringent ER Hae 2621 2113 Pectin, ete, 5 408 6:140 Cacao-red aes 3391 3° 0G Digestible fibre, ete. 36388 35:°721 Woody fibre 8 932 9.840 Tartaric acid, free 2913 °420 Acetic acid, Freee nil, ‘720 Tartaric acid, combined 2-010 3°459 Trun peroxide 026 057 Magnesia "756 “999 Lime 1358 “266 Potash 1-260 1-821 Soda 272 *219 Silica oe “013 +200 Sulphuric anhydride. . 139 085 Phosphoric Se “763 912 Chlorine A 119 ‘u19 100-0U0 100-000 Contains nitrogen 974 1-080 = a traces. 640 : : 492 ‘815 ‘076 “099 ” ” Total nitrogen 1 542 2-134 96 THE AGRICULTURAL CHEMISTRY OF CACAO. TABLE IX. KeEernets oF THE Beans or “CALABACILLO” DRIED, AND FERMENTED AND CURED. . Fermented Dried. and cured. Water hb 5-000 6-080 1. Albuminoids ... ..| 10202 7°310 2. Indeterminate nitrogenous matters . “809 3°406 3. Theobromine .. 2-059 1:659 4, Caffeine 164 058 Fat 44-574 48 400 Glucose 1:510 1:000 Sucrose traces, nil. Starch fs sais 5-735 5-329 Astringent matters =n 7-624 5 972 Pectin, ete. 1-586 1950 Cacao-red ite 4-497 2:300 Digestible fibre, etc. ... 7-287 6 182 Woody fibre ... 4617 4-600 Tartaric acid, free 120 560 Acetic acid, free nil. “900 Tartaric acid, combined °726 624 Iron peroxide 048 115. Magnesia 493 621 Lime 082 *196 Potash 1:283 ‘980 Soda 364 ATT Silica 024 037 Sulphuric anhydride... 120 ‘051 Phosphoric anhydride 1141 1179 Chlorine : avis 028 021 100-400 100:'v00 1, Containing nitrogen ... 1-662 1170 2. 99 5 129 "545 3. a ii 634 ‘BLL 4 ” ” me 47 | 14 Total nitrogen 2472 2.249 THE AGRICULTURAL CHEMISTRY OF CACAO. 97 TABLE X. Composition or THE DRIED, AND FERMENTED, AND CURED Beays,. CuticLes AND Puup oF “ Forasrero.” é Fermented Bored and cured, . Water in ate sis a 5-00 7027 1, Albuminoids ... sae 7203 6-259 2. Indeterminate nitrogenous enutbare:. 3 305 2 641 3. Theobromine . ore Seis cue 1461 1402 4, Caffeine Sid rere ah a, 331 ‘431 Fat oes ae ss we 37575 46-263: Glucose ee es af ds 1:263 ‘5386 Sucrose os vi Sie 2ae 1:20.9 nil. Starch sie Pee e & 8 545 6 337 Astringent matters ... ols ik 6-053 3-588 Pectin, ete, ... ee ee abe 2-369 1-457 Cacao- red ee eee a 2 62u 2-883 Digestible Aline ie ee Rs 10-420 9-070 ‘Woody fibre ... Se ine Suse 6°803 6-662 Tartaric acid, free... er or 657 420) Acetic acid, free ea iota sta trace. OTL Tartaric acid, combined ies G24 964 ‘981 Tron peroxide aes es i 049 0735: Magnesia tas wee das as 627 “676 Lime he ie eats lek "157 “163 Potash 26 se Gels wee 1133 945 Soda wis ala ais ae U96 195. Silica one a 022» 051 Sulphuric anhydride .. wes oe (92 016 Phosphorie one ae a 1:370 1155 Chiorine fs was oe 3 *Ld9 040 99 843 100 000 1. Containing nitrogen .. aes 1-152 1001 2. . ee Ce me 523 423 3. a. ae, fe, soe “440 422 4. . - me be 94 153 Total nitrogen... = ed 2-209 1 968 98 THE AGRICULTURAL CHEMISTRY OF CACAO, TABLE XI. CuticLes oF Cacao Beans, VARIETY FOoRASTERO. : Fermented Dried. and cured, Water is Bas wae wf 11-840 11-840 1. Albuminoids sae ‘Ade iy 6-603 6-130 2, Indeterminate nitrogenous matters...) traces, 3394 3. Theobroimine ... ee ai 1 1:808 ‘909 4, Caffeine ibe ssa ove sue “306 ‘DAT Fat aes Se se Ne “2186 8580 Glucose mee ae He — 5-200 ‘TIA Sucrose ae ays ite ies 473 nil. Starch se ie Sete eal 6-779 3 682 Astringent matters ... oi Dak 561 4-350 Pectin, ete... one eee Ree 5849 5895 Cacao-red = ike fed wae 3662 3°100 digestible fibre és oe ...| 384100 31 292 Woody fibre ... ci cer ef 12-753 9610 Tartaric acid, free... Sats ai 3148 *420 Acetic acid, free date ets ..-| traces, 1:140 ‘Tartaric acid, combined gr sd 1823 3-456 Tron peroxide... gon a one 052 “218 Magnesia ee ee ay sink 379 1 035 Lime ite dass ed a ‘156 224 Potash aes sats ‘giv — 1-283 21-38 Soda . mbt eat tats, o. ‘078 ‘194 Silier tne was af ea 015 +250 Sulphuric anhydride... es By “161 122 Phosphoric anhydride - ws “AO9 807 Chiurine se 8s dis sas *265 423 99 994 100-020 J, Containing vitrogen ... ae ies 1:056 ‘981 2. ” ” see sete ies trace, 543 3. ” ” ake . wes O44 O74 4, a ” $35 ae ied ‘O87 “TDD Total nitrogen... wee - 1-637 1:953 THE AGRICULTURAL CHEMISTRY OF CACAO. 99 TABLE XII, ‘CoMPosITION OF THE KERNELS OF THE Bans oF Forastero, Driep, AND FerMENTED AND CurED. : Fermented Pirie. and cured. Water — ste igs on 5-009 6-280 1. Albuminoids ... eats e 7-228 6:130 2. Indeterminate nitrogenous manteets,,. 4-081 2 525 -3. Theobromine ... nt eas ei 1321 1:480 4. Caffeine ows = sia ame 332 ALA Fat ae es _ ..| 45°83-1 52-120 Glucose ees wits ise een ‘D47 566 Sucrose ee eid aes — 1:373 nil, Starch mo ‘ile wee ea 9-043 6-750 Astringent matters ... ets a5 7 329 3470 Pectin, ete. ... oe ae e 2-068 ‘770 Cacao-red ae ae ster wae 2311 2 850 Digestible Ales Sas dis oe 3-969 5-762 W oody fibre ane ee a 5-435 6-200 Tartaric acid, free... was a ‘057 0-42 Acetic acid, free aa ae ws nil, | 600 Tartaric acid, combined... oe 7 49 596 Tron peroxide oe ee ine “O48 057 Magnesia i ae bie - 680 “621 Lime spe oss aoe ah 153 "154 Potash ses sen mee 5 951 ‘776 Soda das _ Be: way ‘lul 196 Silica : aus . ‘024 020 Sulphuric anhydride... ove 3 tut? tn tee Phosphoric ,, ne sr aed 1465 1-210 Chlorine des sles Aue a ‘O47 - 48 99:995 100 000 ining nitrogen ... 1:156 “980 2 Containing ee ea aa e, G ee oe ele 457 oe ean 095 119 Total nitrogen... sh - 2.310 1-960 100 THE AGRICULTURAL CHEMISTRY OF CACAQ. When the compositions of these substances are given in percentages it is difficult to perceive the changes in composition. which may have taken place during the fermentation and curing. The results obtained have therefore been recalculated on the assumption that the fat in the original beans as sub- mitted to fermentation would undergo little or no change during the process; comparison of the compositions of the por- tions of the fresh fruit submitted to fermentation and of the corresponding amount of the product yielded is thus approxi- mately obtained In the germinatiun of the seeds the fat is used up as food for the plantlet, but in the process of fermentation and sweating germination is so quickly checked that the more. readily available sugars are not all absorbed or used up. Thence itis not likely that the fat will undergo appreciable change. These are given fur both varieties in the following :— TABLE XIII. CANGES TAKING PLACE IN THE Kennel oF THE BEANS OF ‘' CALABACILLO” DURING FERMENTATION AND CURING, Fresh Cured Loss Beans. Beans. | in Curing. Water ast ies ‘ia i 37°37 3:675 | 33-962 Albaminoidls “s a - 6 696 4:419 2 O77 Inde erminate nitrogenous matters... O31 2059 1-621 Theobromive ain ree ee wee 1352 1-003 B49 Caffeine .. ves as ae oe ‘108 “082 ‘076 Fat wes pie wt wei wef 29°256 29:256 nil. Glacose aa ise x " or 991 604 “BST Sucrose wie = wee tty trace-. nil, * Siareh 2% ats 2 ‘ oe 3 764 3°221 3.3 Astringent matters... an Sas 5-004 | 360 1-394 Pectin, ete... Ea a ‘iat a G57 «1178 + ‘521 Creno-red | 252 | B90 | 1562 Digestible fibre... seis — aig i112 3737 1375 Woody fibre ae ues sit 3 030 2-780 20: Tartare void, free... Sis i ‘079 B28 | + Bay Acetic aci', free... aa age are nil. 54d + 644 Tartare seid, combined .., z ia “477 ‘BIT *100- Tron peroxide oe a a vas 32 069 + -037 Mavynesia P *B24 ee - “OSL Lime | ‘Oo4 “TES + Onde Potash “B42 *Hu2 +250 Soda °2AY “YN + UL) Silica ee se i “O16 02 + ‘006 Suaphnrie anhydride . ae “8 | Od O3L 048 1 tho prone avhyaiile aoe an ‘THY ‘T12 037 Chiviine... exe wie wen wi | “019 “G12 *Ou7 | Inu Qu 6u 442 THE AGRICULTURAL CHEMISTRY OF CACAO. 101 TABLE XIV. ‘RESULTS OF FeRMENTING AND Curinc 100 Parts or THE BEANS WITH CUTICLES AND Pup or ‘“ CALABACILLO.” Fresh. Cured. |. Loss in Curing, Water an ee .| 61-780 2:702 59-078 ' Albuminoids nde es 3904 2-719 1185 Indeterminate eg . 274 1168 | 4 -894 neous matters “Theobromine a Sa “814 *584 230 ‘Caffeine... eas ain ‘075 039 036 Fat... ‘ies wey «| 15.361 15361 nil. ‘Glucose... oe os6 862 “342 *520 Sucrose... = Bah 032 009 0238 Starch ee asa ce 2-406 1:979 497 Astringent matters oa 2-776 2000 “776 Pectin, ete. ... ie an 733 1007 |+ -374 Cacao-red ... oie rr 1772 “912 860 Digestible fibre... wf 4847 4:379 468 Woody fibre is oe 2°219 2-074 “145 Tartaric acid, free ... ou 253 “201 042 Acetic acid, free ... ee nil, 327 | 4+ 327 ‘Tartaric acid, comb. ~ “392 420 | + +028 Tyron peroxide ... is “018 039 | + 021 Magnesia ... oe es "225 258 }+ -033 ‘Lime ae site a3 054 O78 | + -024 Potash 4. se = 528 424 "104 Soda awe wes ov 143 045 098 Silica _ wes ee 009 024 | 4+ +015 Sulphuric anhydride... “194 021 | 173 Phosphoric anhydride... “442 “419 023 Chlorine... see se 012 007 ‘O11 1001 32 37°538 102 THE AGRICULTURAL CHEMISTRY OF CACAO. TABLE XV. ReEsvLts OF THE FERMENTATION AND CuRING oF 100 PARTS oF- THE Beans, Curictes anD Pup oF “ FoRASTERO.” Fresh. Cured. |. Loss in Curing. Water eee dee .| 58-261 2-570 55-754 Albuminoids 3°165 3-233 932 Indeterminate nitrogenons matters ... axe wis 1-452 -940 510 Theobromine ake Sis 641 *500 141 Caffeine... ape Biss "145 “154 + -009 Fat bs aa ..| 16509 16°509 nil. Glucose ns ee a 555 209 246. Sucrose ens me aa ‘531 nil. ‘531 Starch des ae i 3°754 2-261 1493 Astringent matters ees 2°659 1-280 1:379 Pectin, ete.. os we 1:261 520 ‘TAI Cacao-red ... ait 1151 1-028 123 Digestible fibre, oy ass 4:578 3-236 1°342 Woody fibre i is 2-989 2377 612 Tartaric acid, free... is 302° 150 ‘152 Acetic acid, free... # trace. 240 240 Tartaric acid, comb, S54 423 350 073. Tron peroxide a acd 021 028 + +007 Magnesia ... ee Bs *275 241 034 Lime wa oe dss 069 058 ‘O11 Potash ine Te ae 454 337 117 Soda es me aon “042 069 + 027 Silica s es 009 018 + 009 Sulphuric anhydride as 040 006 034 Phosphoric anhydride ae 602 ‘412 ‘190 Ciorine i nae = 039 “014 025 99-927 35-679 THE AGRICULTURAL CHEMISTRY OF CACAO. 103. TABLE XVI. CuHanaeEs TAKING PLACE IN THE Kerrnets OF tHE BrAns oF “ FoRASTERO,” DURING F'RRMENTATION AND CURING. Fresh Cured Loss Beans. Beans. | in curing. Water dies ive «| 36567 3°637 32-880 Albuminoids we 4°829 3°599 1-227 Indeterminate nitrogenous matters ... ses eae 2-725 1-482 1-243 Theobromine a ie "882 869 013 Caffeine oa oes °223 “243 + ‘021 Fat wes te ..| 30°602 30°602 Glucose... oa oe 165 "332 + ‘167 Sucrose ani ae Fe ‘917 nil. 17 Starch oe ahs So 6:038 3-963 2-075 _Astringent matters men 4:89£ 2.037 2-857 Pectin, ete. . ee ae 1:380 452 928, Cacao-red ... ewe { 548 1673 | + +140 Digestible fibre... aie 2-821 3377 | + +556 Woody fibre oe ae 3458 3°640 | + +192 Tartaric acid, free ... ve "038 "246 + 918 Acetic acid, free... ee nil. 352 | + B52 Tartaric acid, combined... ‘487 350 137 Iron peroxide is bs 032 033) | + -001 Magnesia ... ies ie “454 364 090 Lime we hg lat. “S108 090 O15 Potash . vee) “885 “455 -080 Soda tae ied see 068 “115 057 Silica - 016 ‘O12 004 Sulphuric anhydride. 48 trace. 048 Phosphoric anhydride 1-045 ‘710 335. Chlorine... en " 032 025 007 100-000 58-708 104 THE AGRICULTURAL CHEMISTRY OF CACAO. In the case of the variety Calabacillo we find that 100 parts of ‘the fresh material submitted to fermentation and curing lose 6:25 “per cent. of their weight of which 59 is water and 3-5 organic and mineral matters. Inthe kernels of the beans the loss on 100 parts -amounts to 394, of which 6°5 parts consist of solid constituents. Tn the variety Forastero, 100 parts of the material submitted to fermentation and curing, yield 35°6 parts of cured cacao a loss of 64-4 per cent. ensuing, of which 55-7 is water and 8-7 solid constituents. The kernels of the beans lose 41°3 per cent. during fermentation and curing, of which 8'4 parts are solid constituents. It is evident that when submitted to a similar fermentation -and curing, beans of the variety Forastero lose a higher propor- tion of their weight than do the small flat beans of Calabacillo. Inboth cases a considerable loss of the albuminoid constituents ensued, with, in the case of Calabacillo, an increase in the indeter- -minate nitrogenous matters. In Forastero, a loss of the latter also -appeared to have taken place. In both cases we find a loss of the alkaloidal constituents has taken place, this being greater in Calaba- -cillo than in Forastero. A marked loss of the sugars has occurred and also of the starch, pectin, gums and digestible fibre, this being much greater in the case of Forastero than in that of Calabacillo. The astringent matters and cacao-red have also decreased in about -equal proportions on the two varieties. Little change has taken place in the total quantities of tartaric acid present, but the fer- mented and cured beans contain a small proportion of acetic acid not present in the original material. Both varieties have lost some -of the more soluble constituents of their mineral ingredients. Comparison of the losses apparently undergone by the whole material submitted to fermentation, and by the kernels of the beans lead to the conclusion that, as might be expected, a certain -amount of change in place has occurred in the constituents of the kernels of the beans and the cuticles and pulp. The kernels show a much more marked loss of astringent matters than do the whole beans and to this loss much of the improvement in flavour must probably be due. It is also seen by examination of these results that it is proba- ble that during the sweating process slight changes in the position -of the constituents of the beans of the two varieties have taken place, leading in some cases to apparent gains of constituents in one or other of the kinds. It was found that the original sample consisted approximately of one-fifth beans of Calabacillo and four-fifth -beans of Forastero, THE AGRICULTURAL CHEMISTRY OF CACAO, 105 The following shows the losses resulting from the fermenta- tion of the mixture and we think may be considered as a fairly reliable indication of the changes which ordinarily take place during the fermentation and curing of cacao :— TABLE XVII. LossEgs RESULTING FROM THE FERMENTATION AND CURING OF A MIXTURE OF BEANs oF ‘CALABACILLO” AND “ ForAsTERo.” Water or 3S pea 56-419 Albuminoids dss wee ahs “982 Indeterminate nitrogenous matters 208 229 Theobromine eee ui as 159 Caffeine vs oes bes nil, Fat ane ie is nil, Glucose wes eae ia 301 Sucrose si ies vee “429 Starch on ee ie 1-280 Astringent matters ea ne 1:258 Pectin wae see see 518 Cacao-red aye bee ves 270 Digestible fibre... ae aes 1167 Woody fibre 33 in sae “518 Tartaric acid, free wt ae “130 Acetic acid, free ... See ous 257 Tartaric acid, combined ees oe 053 Tron peroxide... ay 010 Magnesia : : . 021 Lime +o erry eee 004 Potash eee oi os 114 Soda ses -_ ag 002 Silica os ele a. & ‘010 Sulphuric anhydrid bi oes 030 Phosphoric anhydride sis _ 156 Chlorine nis aed ia 022 There has occurred a loss in almost all constituents of the cacao, the only gains being in acetic acid, a product of the fer- mentation, and in iron peroxide and silica due to dirt and dust picked up during the final drying. As acheck on the accuracy of these results, a sample of the liquid running from the sweat- ine boxes was obtained, the constituents of which consist of J BS . matters removed from the fermenting material and was found to contain with the exception of theobromine, either the missing soluble constituents or the soluble products of their alteration and of that of the less soluble carbohydrates. 106 . THE AGRICULTURAL CHEMISTRY OF CACAO. TABLE XVIII. ComposiTiuoN’ of THE SWEATINGS FROM A MIXTURE oF CALABACILLO AND ForastTzRo. Water aes aie es 84°817 1. Albuminoids ... ees aes 062 2. Indeterminate nitrogenous matters... 250 Glucose ws er sis 11-604 Sucrose ove Per ae 638 Astringent matter, &e. ... oe 354 Alcohol ia is ae "180 Tartaric acid, free aes vk 340 Acetic acid, free ae des 892 Acetic acid, combined... is 290 Iron peroxide ie sie 038 Magnesia aes ee ibe 074 Lime aes ise on 029: Potash ar a se 354 Soda ane sa es 004 Sulphuric anhydride tas tee 021 Phosphoric anhydride... oe 038 Chlorine bee a igs 007 100-000. 1. Containing nitrogen iis i 010: 2 me ‘5 Sis ois 040 Examinations made by us ‘of the process of sweating showed clearly that at first an alcoholic fermentation takes place accompanied by a rise in temperature of the material; later a little acetic ether is produced either as a direct product of fer- mentation or by the interaction of the alcohol and the acetic acid! produced, and that, finally, the fermentation becomes an acetic one, the temperature in the fermenting boxes gradually rising so high as to practically stop the alcoholic fermentation, The results of the examinations and analyses show that the- process of fermentation or sweating in cacao consists in an alcoholic fermentation of the sugars in the pulp of the fruit accompanied by a loss of some of the albuminoid and indeter- minate nitrogenous constituents of the beans. Probably the albuminoid constituents are first changed into amides and other THE AGRICULTURAL CHEMISTRY OF CACAO. 107 simpler combinations which may be further broken up during the process of fermentation. Some parts of the carbohydrates. other than sugars undergo hydrolysis and either escape in the runnings from the boxes in the form of glucose, or undergo in turn the alcoholic and acetic fermentations, During this change some of the astringent matters to which the somewhat acrid taste of the raw beans is due are also hydrolysed, and thus a marked improvement in flavour is gained. Small quantities of the mineral constituents, principally of potash and phosphoric acid, are removed from the beans in the liquid escaping from the fermenting material. A slight loss in woody fibre is shown, which may be due to loss of portions of the cuticle during the operation of drying, or to changes in it by hydrolysis during fermentation, This work has necessarily only resulted in a partial and incomplete study of the results of the fermentation. The study of the changes which take place in various kinds of beans and during variously modified conditions of fermentation must be left to botanists and chemists in colonies and countries where- Cacao is an important product. Work already done in this line is fully compensated if it leads others more favourably situated to take up the study of this interesting and intricate subject, and, at any rate, the record of the investigation may be of some service and guidance to the owners and managers of plantations and to those contemplating purchasing suitable land for estab~ lishing plantations. CHAPTER XIII. Food Value of Cacao, Manufacture, &c. LONG series of analyses were published some years ago by P. L, Simmonds in “Tropical Agriculture,” but that author remarks, that the results are ‘not very flattering to chemical science, the analyses being of the most contra- dictory character, and containing discrepancies which cannot be at all reconciled with each -other”—but he nevertheless reduces them as far as he is able to -an average, as seen in the following table :— Cacao butter ae ice i 50 Albuminoids ane te eas 20 Starch inte ies ous 18 Salts tile ane wee 4 Theobromine ats dee ee 2 Miscellaneous ais ees daa 11 100 Professor Church’s analysis of cured Cacao is quoted in the ‘Chapter on Fermentation. Theobromine, according to the Professor, “is the active principle of Cacao; and the taste and aroma are mainly due to an essential oil and to Tannin,” and he -deems it a milder and less stimulating beveraget han tea or coffee. I doubt much, however, if Cacao of the class he refers to, was that which obtained for it the name of “ Theobroma,” or “ Food for the Gods.” The manufacture of Cacao as now carried out in Europe -and America presents a great contrast to the primitive methods -of preparation, which methods are found still to exist in the -countries producing it. The Professor gives four forms of preparation in which Starch, Flour, Sugar, Vanilla, Bitter Almonds, Cinnamon and other sub- ‘stances are used as adulterants, some to form ‘Soluble Cacao,” some FOOD VALUE OF CACAO, ETC, 109 “Chocolate,” some ‘Flake or Rock Cacao” and some “ Pressed Cacao”—and in most of these a portion of the original fat of the- bean has been removed. He says :—that most of the Cacao consumed in Europe is prepared for use by admixture with other substances or by remov- ing part of the fat or ‘Cacao butter.” Cacao-nibs, if simply ground, would yield a rich but heavy food but not a beverage. It may indeed be shown that 100 parts of Cacao-nibs contain heat-givers equivalent to 182 parts of starch, while the Jresh- Jormers present amount to no less than 17 parts, the ratio of the latter being as 1 to 8. One pound of Cacao-nibs might in fact produce as much as 24 oz, of the dry nitrogenous substance of muscle, This shows that one pound of Cacao-nibs is more than equal in fiesh-forming constituents to one peund of lean mutton chop, which is estimated to contain but 2 oz. of the dry nitrogenous substance of muscle or flesh But we can’t eat a pound of: Cacao-nibs at any one time, and it is seldom that more than 4 oz. is used for a breakfast cupful, and even to this is added a certain proportion of milk and sugar. ‘The value of the milk as a food constituent being as 3 oz. of the dry nitrogenous sub- stance of muscle and flesh to the lb. So that Professor Church’s remark that Cacao-nibs would yield a heavy food, but not a beverage, is somewhat wide of the mark, for it actually yields only a beverage, and is seldom, except on emergencies, taken as food. If it was consumed as ‘‘nibs” it would certainly be a “theavy food” as it appears to contain 50 %.of Fat, and 17% of Albuminoids besides other constituents. No one eats it in the form of “nibs” however, but small quantities in solution, and therefore when we take of prepared Cacao a part equal to- giz part of a pound, adding 4 ozs. boiling water and 4 ozs. milk ;. we have according to the Professor’s own analysis, the sum of 13 drams-+3 drams or a total of 48 drams of flesh-forming con- stituents in a cup of Cacao made from the ground nibs unadulterated, of which 3 drams are supplied by the added milk, or a total value of (j15) one-tenth of a pound of mutton chop. What proportion of nutriwent is contained in a cup of Cacao made from the various preparations, we are not able to gather, but we should estimate it at a very much lower figure. That Cacao-nibs, simply roasted and ground, will yield a. beverage of excellent quality when properly prepared there can be no doubt, though perhaps not one calculated to suit all tastes but unce the palate is'“ educated” to the Havour, it is preferred to any of the adulterated forms or preparations. In samples of Cacao, or *‘ Cocoa” made by the best makers uv less uian 60% of a 110 FOOD VALUE OF CACAO, ETC. Sugar has been found. This large amount of sugar is accounted for by the fact that without this addition it does not sell. Not a little prejudice exists as to the digestibility and indigestibility of Cacao Fat, and this prejudice is taken advantage of by the manufacturers in making their preparations. It is somewhat curious to note however, that some of the fat extracted from the preparation intended for use as a beverage is used in the prepar- ation of confectionery, such as ‘‘ Chocolate Creams,” when no question whatever arises as to its indigestibility. Many indeed who object to a certain amount of fat with their breakfast cacao, use ten times the amount of quite as indigestible a fat, in the form of butter, without a thought of indigestion, ‘The value of Chocvulate Creams, Chocolate Stick. and other ‘‘ Bon Bons” as a food may be estimated from the analyses. They contain from 12 to 40 % of Cacao which has a large percentage of Fat, some starches, and some albuminoids, and these added to the Food value of 60% of sugar will give total value which will be found overestimated in the majority of cases both by sellers and consumers. If the public could be persuaded to demand pure Cacao, adding the sugar themselves they would be better served. MANUFACTURE OF CHOCOLATE, The methods generally employed in Trinidad in manufac turing Chocolate from the Cacao bean are extremely simple, and the same in principle as those practised throughout Cacao growing countries; but there are a few persons who produce an article little inferior in point of manufacture to that produced in Europe. The bean after being cured and dried in a manner fit for sale can be used at any time for manufacturing into chocolate, The first process is to roast the beans in a cylinder over a slow fire, until they assume a fine brown colour, but not to heat them to such a degree as to burn them, or to destroy the essential oil which they contain, for Cacao-beans once burnt or scorched can never make upacup of first-class chocolate. When browned sutliciently the testa easily separates from the inner portion of the seed and can be cracked uff and fanned away as soun as the beans are cool enough to handle, Car2 should be taken to grind quickly after roasting. as unce roasted, Cacao soon loses flavour and aronia, and the manufactured article should always be kept in sealed or close fitting receptacles, The ‘‘nibs” wre put upon a clean piece of free stone about 2 feet square, perfectly smooth, another piece of the same material, somewhat rounded, being used as a grinder. Rubbed for some little time aud frequently turned with a small spathula, the Leans are reduced tu a paste, the fat they contain assisting the operation, Lut the grinding must be cuntinued until the FOOD VALUE OF CACAO, ETC. 111 paste hecomes perfectly smooth and even. If sweet chocolate is ‘desired to be made, sugar should be added ; if ‘ unsweetened ” nothing more has to be done but to make the paste up into such sizes of blocks or rolls as may suit the fancy of the manufacturer or the convenience of liousewife. Thexe balls, rolls, or blocks are then allowed to set or harden, which they will do in a few hours’ time, after which they can be transported any distance. The operations of roasting and grinding shuuld always be done ‘in dry weather, No adulteration is required, but still to suit some palates, Vanilla, Nutineg, Cloves, Cinnamon, and various spices may be added, but these combinations are in our estimation not equal to the flavour of the viryin Cacao, provided the volatile essential ‘oil has not been destroyed during the process of roasting, during which process it appears to be developed. A cup of m-st delicious chocolate can he made from the rolled or caked Cacao in about three minutes, in the following manner :—Grate about half an ounce of bail chocolate into an ‘enamelled saucepan, adding sufficient boiling water to cover it ; Jet it simmer for two or three minutes, add sugar and hot milk to taste and serve. If preferred equal parts of milk and water may be used. The substance removed from the Lean as fat by the more elaborate methcds in which Cacao is prepared is krown as ‘‘Cacao-Lutter.” This is a valuable concrete fat ‘melting at 10U° Fahrenheit which is expressed from the paste of the Cacac-bean by pressure while subject to steam or sun heat. On cvoling it becomes an opaque dry chocolate colored substance, somewhat brittle and shows a waxy fracture. The coloring is easily removed by filtering, while hot, through animal charcoal, when the fat becomes a clean white. It has a pleasant -chocelate odour and a bland flavour, and is much used for phar- maceutical preparations. It is chiefly remarkable for having but little tendency to rancidity. From the fact that clean fats have a remarkable affinity for the volatile or essential oils, it appears probable that a propor- tion of the aruma of chocolate is Just by the removal of the ‘Cacav-butter, and this fact would alune account for the superiority of the flavour of that Cacao in which the natural fat is all present, over that from which it has been remuved. Which way the manufacturer must make it, the public decides -of course. Usually the less the manufacturer adulterates a pure article, the Letter are his prospects for the future of his business, but in Cacao the converse appears to be the case. It is clear that more Cacao would be sold if the mixture of foreign substances was disallowed. and the planter would in cunsequeuce weap a decided Lenefit ‘trum tLe greater demand. 112 FOOD VALUE OF CACAO, ETC. If the operator desires to make a Cacao powder, he has to- express a large proportion of the fat which can readily be- done in any common press. ‘The Cacao paste must be handled in a high temperature so that all the fat is in a melted state, and the apparatus must also be kept well warm. This can, in Trinidad, be effected by working in the Sun, but in a temperate climate, artificial heat is required, and is employed in all the. Factories. The paste is put between thin layers uf cloth, neatly folded so as to prevent escape and then placed layer upon layer- in a strong press box, worked either by simple screw or by- hydraulic pressuye, Sufficient of the fat can in this way be- extracted to render the layers of paste dry, and formed into sclid thin cakes. If these are now taken and rubbed through a fine sieve, a cacao powder will be produced, in flavour equal, if not superior, to the finest brands upon the market, and unadul- terated and pure. Sugar can always be added by the consumer, and no starch is necessary to make the article into palatable- form. | Cacao powder pure and unadulterated may well be called: “* Food for the Gods” from the delicious flavour and aroma it exhibits, but the lower qualities of the manufactured article commonly sold and largely advertised would in many instances be well named in the words ‘‘Food for the Pigs,” as they certainly contain but a very small percentage of pure Cacao. To ascertain whether there was any essential difference in the character of various samples of the Cacao Bean when worked: up or manufactured for consumption three samples were obtained. from one of our largest dealers. These samples were accurately weighed to 10 lhs. each, and’ were then roasted and ground and the fat extracted by an ordinary press. The percentage of fat is not so large as might have been taken, but as in each case the means used was identical, the results are directly comparable. The character of each Cacao was exhibited most distinctly the colour and flavour of the dry powder, and by the colour, character and flavour of the fat extracted. The Cacao powder, Cocoatina, or Cocoa essence produced. is an article which can be used in the same manner as the ordinary Cacao powder of the manufac‘urers, and is a perfectly pure article. The value of the powder can be estimated if we allow a certain per cent. for loss in the process of manufacture. Ourown experience is too limited to fix this with ascuracy, but it may be for our present purpose taken as 20 per cent. FOOD VALUE OF CACAO, ETC. 113 The Cacao powder produced, is seen to average some 55 per cent. of the total weight of Cacao operated upon, and therefore we have a saleable article at a loss of 45 per cent. of the original weight. Now the value of the cacao at the time of the opera- tion was averaged at 14 cents per lb. and therefore the cost of the powder not allowing for value of fat, and sale of waste— and not admitting cost of manufacture, is more than double the cost of raw material—or some 30 cents per lb. When, however, some 15 per cent. or 20 per cent, fat is sold at 1/3d. per lb. and the husk at a lower value, it will greatly reduce the cost:of manufacture, and it can be clearly seen that Pure Cacav Powder can be produced at reasonable rates, leaving a good margin of profit, and also that the admixture of starch and sugar is not in any way required, either for the purpose of making it palatable or as an improvement tv the keeping qualities of the article. The public should therefore put down adulteration by demanding nothing but a pure Cacao powder, which is in every way a palatable and nourishing beverage. One of the facts to be noted is, that the mild flavoured and light colored Venezuelan Cacao is rated at the same value as ordinary Trinidad, although it is evident it produces a Cacao powder in every respect superior to ‘‘ Ordinary ” Trinidad Cacao. The following are the tables of results of our late experiments :— No. 1.—VeEnezuenan Fine Cuayep Cacao, VALUED AT l4c. PER LB. nm . Weight received from G. G. & Co.... . Weight when roasted and cleaned Weight of Husk ses sie va Weight of dry Cacao after fut was removed Weight of Fat extracted from 7°55 lbs, Loss during roasting and cleanivg -77 lbs. Loss during grinding and expression of fat “82 lbs. . Total loss in mannfacture ... ans ata ee Loss roasting, cleaning and extracting fat and husk 3 Dry Powder ons ace se He ven) * Fat ae wat ae sie ett easy od; MA pepo = Or Oo 2. Nores.—The loss is greater than it would be with larger quantities. Comparing samples Nos. 2 and 3, it is seen that Clay is to be esti- mated at about 13%. * Fat should be slightly more, owing tothe absorption by the bags during extraction of first example, possibly 13%. H 114 FOOD VALUE OF CACAO, ETC. No. 2.—Tarrnipap ‘ Finr Estates’ vanvgep 14$c. PER LB. 1. Weight received from G.G. & Co. ... Sas ... 10 Ibs, 2. Weight when roasted and cleaned .., saa Pe 7°86 5, 3. Weight of husk wee 168, 4. Weight of Cacao after removal of Fat... .. 5°60, 5. Weight of Fat from 7:86 lbs. as chs 2a 1-64 ,, 6. Loss roasting and cleaning “51 Ibs. 7. Loss during grinding and expression of fat -62 Ibs. 8. Total loss i ies nie wes 1:13 ,, Dry Cacao Bowie: ity ve 56: % . |Fat : aia ies 16-4 % ca i a ae a76(1L3 % Husk ... i hy si 16°3 % 100-0 No. 3.—Trinipap ‘“‘ Orpinary”’ Cacao, 14¢c. PER LB. 1. Weight received from G. G. & Co. ... sie .. 10° Ibs, 2. Weight when roasted and cleaned ... wit oes 7°80 ,, 3. Weight of husk ans ee 1°53 ,, 4, Weight of Cacao after removal ‘of Fat a a 5:48 ,, 5. Weight of Fat from 7°80 lbs. ste “6 ih 1°61 ,, 6. Loss during roasting and cleaning re ‘67 Ibs. 7. Loss during grinding and expressing fat ‘71 Ibs. 8. Total loss or a one was ae 1:38 ,, {Pet Cacao Bowiiek os