JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES VOLUME VII, 1917 BOARD OF EDITORS X. Ernest Dorsey Adolph Knopf A. S. Hitchcock BUREAU OP STANDARDS GEOLOGICAL 8UBVBY BUREAU OF PLANT INDUSTRY PUBLISHED SEMI-MONTHLY EXCEPT IN JULY, AUGUST, AND SEPTEMBER. WHEN MONTHLY BT THE WASHINGTON ACADEMY OF SCIENCES OFFICE OF PUBLICATION THE WAVERLY PRESS BALTIMORE, MD. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII JANUARY 4, 1917 No. 1 PHYSICS. — Luminescence measurements.1 N. E. Dorsey, Bu- reau of Standards. Although the excitation of phosphorescence by the radia- tions from radioactive substances was early observed it appears that no quantitative measurements of the luminosity thus pro- duced were published until 1910. In that year Marsden2 pub- lished a series of observations which showed that the lumines- cence of certain materials (zinc sulphide, willemite, and barium platinocyanide) hermetically sealed in tubes containing radium emanation decreased much more rapidly than the emanation decayed, and that the rate of decrease increased with the amount of emanation initially present. He reported only relative values. At the same time Rutherford3 advanced a theory to account for these phenomena, and showed that it agrees with Mars- den's observations, within the limits of experimental error. No later measurements of such luminosities have apparently been published, although the subject is one of considerable scientific interest. Latterly the subject has become of much practical importance, owing to an increasing use of self-lumi- nous preparations containing radioactive excitants. Besides being used for the illumination of watch dials, push buttons, etc., these preparations have a wide field of usefulness in war appliances. In the study and testing of these preparations we are con- fronted with the problem of measuring surface luminosities of 1 A contribution from the Bureau of Standards. 2 Proc. Roy. Soc, 83: 548-561. 1910. 3 Proc. Roy. Soc, 83: 5G1-572. 1910. 1 2 dorsey: luminescence measurements small areas of various sizes and shapes. Also, it is desirable that the apparatus employed be simple in construction and use, and that the results obtained be readily interpretable in terms of photometric standards. As the luminosities frequently are low, photometers of the usual types would be unsuited to the work even if their use did not necessitate a determination of the effective size of the preparation under study. With preparations of sufficient bril- liance the spectrophotometer will give the most detailed infor- mation; but this instrument is not suitable for the measurement of the total luminosity or for the comparison of such lumi- nosities when they differ in color. Other apparatus or methods that have come to our attention — such as those employed by Wood,4 Nichols and Merritt,6 Zeller,6 and Andrews7 — all appear to be in some measure ill-adapted to the present problem. The apparatus described by Andrews is the simplest, but we believe that the interpretation of its read- ings in terms of photometric standards will be difficult. In preparation for the study of self-luminous materials at the Bureau of Standards, a photometer has been devised which is exceedingly simple in construction and use, and appears to be well suited to much of this work. By the use of standardized lamps and screens the results obtained by its use can be inter- preted readily in terms of photometric standards. In its simplest form, this photometer consists of a box 2 or 3 meters long and 25 or 30 cm. square. A light carriage carry- ing a 1.5 or 2-candle electric lamp runs on ways extending the entire length of the box, the filament being in the center of the section of the box. By means of two cords attached to the carriage, one passing over a pulley at the rear end of the box, the distance of the carriage from the end of the box can be ad- justed as desired. The position of the lamp is determined by a graduated steel tape having one end attached to the carriage. * Wood, R. W., Phil. Mag. (6) 21: 209-313. 1911. 5 Nichols, E. L., and Merritt. E., Phys. Rev. 23:37-54. 1906; 32:38-53. 1911. 6 Zeller, C. A., Phys. Rev. 31: 367-375. 1910. 7 Andrews, W. S., Gen. Elec. Rev., 19:892-893. 1916. dorsey: luminescence measurements 3 Both ends of the box are closed, but in the front end is set a milk-glass window 2 or 3 cm. square, backed by a color filter so chosen as to make the transmitted light match in color the luminescent light that is to be measured. In the bottom of the front end of the box there are suitable openings through which pass the cords for operating the carriage, the steel tape, and the leads carrying the current to the lamp. The entire interior of the box, including the ways and the lamp carriage, is painted a dead black, and movable black diaphragms and screens must be so placed as to screen the milk-glass window from all light scattered from the walls of the box. All joints must be light tight, and the openings through which the cords, etc., pass must be suitably screened or provided with black cloth hoods to pre- vent the passage of light. It is desirable that the top of the box be hinged, so as to facilitate the adjustment of the dia- phragms and lamp. The photometer is used in a darkened room. As the lumi- nosities with which we are concerned are often quite faint, any stray light, such as may leak under a door, becomes very annoy- ing and should be carefully excluded. In the lamp circuit are placed a suitable ammeter and adjusting rheostats. Unless there is a second observer whose sole duty it is to keep the current at the proper value, the current should be supplied by a storage battery being used at the time by no one else. In order to make a measurement, the luminous material, ap- plied to a card or enclosed in a thin walled glass tube8 of small diameter, may be placed directly against the milk-glass screen and the position of the lamp is then adjusted by the cords until the luminosity of the milk-glass appears to be the same as that of the material. The observer's line of sight should be perpen- dicular to the milk-glass. If the color match is good the tube will almost disappear when the adjustment is correct. The luminosity of the material is inversely proportional to the 1 The tube should be painted black over two-thirds of its circumference, so as to screen the milk-glass from the light given out by the material. The unpainted side is turned toward the observer and the tube is rotated so as to reduce the visible dark line 'on one side to the smallest amount consistent with a screening of the milk-glass. 4 dorsey: luminescence measurements square of the distance of the lamp from the milk-glass screen, the constant of proportionality being determined from a care- ful photometric standardization of the lamp and of the screen and color filter as used. For example, the photometer screen and a certain specimen were found to be of equal brightness when the lamp was 70.5 cm. from the screen. The lamp was a tungsten lamp burning at the color of a 4 wpc carbon lamp and had a candlepower of 1.38 in the direction of the length of the photometer. For the light from such a source the surface brightness of the screen used had been found to be 3.96 micro- lamberts per meter-candle illumination from the rear. Conse- quently, this specimen had a surface brightness of 3.96 X 1.38 -f- (0.705)2 = 11.0 microlamberts. A micro lambert is the brightness of a perfectly diffusing and completely reflecting white surface when illuminated by a source of unit candlepower placed at a distance of 10 meters. When greater precision is desired, the top of the milk-glass window should lie in the central section of the end of the photom- eter and be so placed that the vessel containing the material under study can be placed immediately above it and so thatthe luminescent surface lies in the plane of the window. For the highest precision it is desirable that the material be contained in a thin vertical vessel with sides of thin plane glass and bot- tom of thin material so that the two luminous fields can be brought as nearly as possible into contact, so as to secure a mini- mum visibility for the line of separation. In addition to the well known errors of ordinary photometry, others of prime importance have to be guarded against. For low luminosities it is necessary that the eye of the observer be in a highly sensitive state; this condition is not attained until after he has been in total darkness for at least 15 or 20 min- utes. In order to retain this sensitive state the illumination used for reading the scale, recording the observations, or other purposes must be as faint as is consistent with the work, and must be continued only as long as is absolutely necessary. Furthermore, this light must be of such a nature that it will not affect the luminosity of the material under study. These DORSET: LUMINESCENCE MEASUREMENTS 5 conditions may be practically attained by the use of a small pocket flashlight suitably screened and provided with a ruby bulb. In order that the luminosity of the preparation shall be due solely to the radioactive excitant, it is necessary that the prepa- ration shall have been excluded from all light except its own for at least several hours before the measurement is made. During the measurements the milk-glass -window must in every case be screened from all light coming from the preparation; otherwise a false setting will be obtained. The error due to this cause may easily amount to over 10 per cent in the lumi- nosity. Another error that must be carefully guarded against at these luminosities is that due to the "Purkinje effect." By this is meant the fact that two adjoining luminous surfaces of differ- ent colors that appear to be of equal brightness when viewed from a certain distance will not appear to be of equal brightness when viewed from a different distance. This means that when we are dealing with different colors our judgment of equality of brightness is a function of the intensity of the illumination. This effect becomes very pronounced at low intensities. A further difficulty is introduced by the fact that under such conditions the judgment of equality of brightness depends upon the peculiarities of the eye of the observer; different observers judge differently. On account of both of these reasons it is important that the illuminated milk-glass be a very close color match to the material being measured. This is true even when the luminosity is so low that it produces practically no color sensation, properly so called. Under such conditions the color match must be determined by spectroscopic examination; indeed this is the best procedure in all cases. By the addition of a phosphoroscope and a constant source of illumination this photometer can be readily adapted to the study of the intensity of the luminescence excited by light, especially when the spectrum of the luminescence is a single broad band. If the luminiscence consists of a number of nar- row bands scattered throughout the visible spectrum an exact 6 LARSEN AND STEIGER: MINERALOGIC NOTES color match will in general be impossible, and difficulty may then arise from the Purkinje effect. MINERALOGY. — Miner alogic notes.1 Esper S. Larsen and George Steiger, Geological Survey. I. APHROSIDERITE FROM BRITISH COLUMBIA Introduction. A highly fossiliferous Cambrian shale or slate from the Burgess shale near Field, B. C., examined by the authors for Dr. Charles D. Walcott, carries numerous veinlets of pale green chlorite with some associated pyrite and calcite. A study of this chlorite shows that it is related to aphrosiderite. The authors are indebted to Dr. Walcott for the material here described. The slate2 is very fine-textured, so fine that much of the materia] shows aggregate polarization. It is made up largely of muscovite with some kaolinite, a very little quartz, apatite, and pyrite. Numerous dark brown to black streaks arranged parallel to the cleavage represent carbonaceous matter. An analysis of the slate, made by George Steiger, is given in column 1, table 1. It closely resembles the analysis of sericite from Diirrberg shown in column 2. The chlorite occurs in a system of rudely parallel veinlets less than a millimeter across, which are normal to the slaty cleavage; the rock tends to break through the centers of these veinlets, leaving surfaces lined with small grains of calcite and blotches of cupriferous pyrite. Physical properties. The chlorite is light-green in color, it has a hardness of about 1 or 2, and the powder analyzed had a specific gravity, as determined by the picnometer method, of 2.959, which was probably not changed by the admixed muscovite by more than ±0.01. It fuses with difficulty. In thin section the chlorite makes up most of the veinlets, but there is more or less calcite in irregular crystals in the center of the veins and some pyrite. It is nearly colorless in thin section 1 Published with the permission of the Director of the U. S. Geological Survey. 2 Walcott, C. D., Cambrian Geology and Paleontology — II, Smithsonian Misc. Coll. 57: 149-51. 1914. LARSEN AND STEIGERI MINERALOGIC NOTES 7 and is so faintly birefracting that it is easily mistaken for an isotropic mineral. It is probably very finely crystalline. Its index of refraction as measured by the immersion method is 1.625 ± 0.003. No further optical data could be determined. No cleavage was observed. Aphrosiderite from Weilburg, Prussia,3 is optically positive, and has the following indices of refraction and pleochroism: a and /3 = 1 . 612 ± 0. 003; pale olive-green. y = 1.616 ± 0.003; colorless. Chemical analysis. The aphrosiderite gelatinizes with hydro- chloric acid. Material for an analysis was carefully selected, but the best sample contained a good deal of the mica slate and a little pyrite and calcite. The calcite was removed by dilute acetic acid and the analysis was then made on that portion of the remaining sample which was soluble in HC1. The results of the analysis by George Steiger are given in column 3 of table 1. Column 3a gives the results for the acid soluble portion computed to 100 per cent. Column 3b gives the molec- ular ratios and columns 4 and 5 give the analyses of related chlorites for comparison. The analysis shows that the chlorite is near aphrosiderite and that it has the empirical formula 64(Fe,Mg)O.24Al2O3.42SiO2.60H2O, which is near 5(Fe,Mg)0. 2Al2O3.4SiO2.5H2O and between the formulas assigned to aphro- siderite and delessite. II. THURINGITE FROM COLORADO A chlorite, differing from that described above as aphrosiderite chiefly in the higher content of both ferrous and ferric iron and in the presence of considerable manganous oxide, occurs in large amount as a primary mineral in several of the veins near Creede, Colorado. The veins are of considerable size and occupy great fault fissures. The filling of the vein on which are the Ridge and Solomon mines in East Willow Creek consists largely of this chlorite with a little quartz, fluorite, and the ore minerals, galena and sphalerite. The great Amethyst vein is made up 3 Unpublished manuscript by Esper S. Larsen. 8 LARSEN AND STEIGER: MINERALOGIC NOTES largely of amethystine quartz containing galena, sphalerite, and some streaks and bodies of the chlorite; it carries much silver and some gold. The veins are in great flows of rhyolite, TABLE 1 Analyses op Slate AND CHLORITES 1 2 3 3a 3b 4 5 Si02 54.49 25.60 0.89 2.00 1.18 1.90 0.28 6.67 0.33 3.91 0.72 None 1.54 Not det. 0.08 None 0.24 None None None tr. 55.80 27.72 3.07 0.53 0.14 1.51 5.62 4.03 22.68 21.58 1.41 24.40 9.81 tr. 0.24 0.88 1 9.72 0.10 8.57 24.97 23.76 1.55 26.86 10.81 tr. 0.26 0.97 10.71 0.11 100.00 416 233 10 373 269 4 10 595 26.45 21.25 44.24 1.06 7.74 25.72 AI2O3 20.69 Fe203 4.01 FeO 27.79 MgO 11.70 CaO Na20 K20 H20- H20+ 10.05 Ti02 Zr02 C02 C P206 S03 s MnO BaO SrO CuO Insoluble 99.83 0.09 98.42 99.39 100.74 99.96 99.74 1. Middle Cambrian slate from British Columbia. 2. Sericite from Diirrberg. Quoted by Dana, System of Mineralogy, 6th edition, p. 618, analysis 41. 3. Analysis of aphrosiderite from near Field, B. C. George Steiger, analyst. 3a. Analysis of aphrosiderite computed free from gangue. Sp. Gr. = 2.96. 3b. Molecular ratios of 3a. 4. Analysis of aphrosiderite from Weilburg. Sp. Gr. = 2.8. Quoted by Dana, System of Mineralogy, 6th edition, p. 660, analysis 1. 5. Analysis of aphrosiderite from Bonscheerer. Sp. Gr. = 2.991. Quoted by Dana, System of Mineralogy, 6th edition, p. 660, analysis 3. LARSEN AND STEIGER: MINERALOGIC NOTES 9 which are very low in magnesia and iron, and the chlorite and other minerals are largely vein fillings rather than replacements. The chlorite is green in color and is soft and friable. It is fibrous to platy and is finely crystalline. An optical study of the chlorite from various parts of the Creede district shows that it varies somewhat in its optical properties and no doubt also in chemical composition. The material analyzed from the Last Chance mine on the Amethyst vein is in very minute interwoven fibers of positive elongation and optically negative character. The axial angle is moderate. The mineral is pleochroic: dark green parallel to the fibers (/3 and 7) and nearly colorless normal thereto (a). The mean index of refraction is about 1.637 =*= 0.005 and the birefrin- gence is about 0.01. The fibers are too small for a satisfactory optical study. A specimen of the mineral from the Park Regent mine, also on the Amethyst vein, showed essentially the same optical properties, but the indices of refraction are slightly higher (n = 1.643). A specimen from the Amethyst mine gave 0 = 1.638 =*= 0.003. A specimen from the Ridge mine is considerably paler in color, is less strongly pleochroic, is a little more coarsely crystalline, and has lower indices of refraction, but is otherwise similar. It is optically negative and has a moderate axial angle. X is normal to the fibers and plates and is very pale green; Z and Y are a somewhat darker olive-green. The refractive indices are: a = 1.595 ± 0.005, 7 = 1.605 ± 0.005. Another specimen from the Ridge mine consists of very minute fibers and has a mean index of refraction of about 1.585 ± 0.005. A specimen from the Solomon mine is similar but its mean index of refraction is 1.617 ± 0.005. These data indicate a moderate range in the composition of the chlorite. The mineral from the Ridge-Solomon vein with its lower index of refraction is probably higher in A1203 and lower in Fe203 and higher in MgOand lower in FeO. It ap- proaches aphrosiderite or delessite in composition. The analysis of the gouge from the Solomon mine (analysis 4, table 2), which was made up largely of chlorite but contained some quartz and 10 LARSEN AND STEIGER! MINERALOGIC NOTES chalky decomposed rhyolite with here and there a flake of seri- cite, confirms this conclusion. The thuringite from the Amethyst vein and the chlorite from the Ridge-Solomon vein are both fusible at about 4 and become magnetic on ignition. The thuringite decomposes in acid with imperfect gelatinization. A chemical analysis of thuringite from the Last Chance mine on the Amethyst vein, a few miles above Creede, is given in column 1 of table 2. The material analyzed contained a little admixed quartz. Other analyses of thuringite are given in columns 2 and 3 lor comparison, and in column 4 is given the analysis of the gouge from the Solomon mine, which, as already TABLE 2 Analyses of Thuringite and Gouge 1 2 3 4 Si02 ; 24.34 16.46 12.04 28.89 5.41 None 0.37 tr. 0.35 9.19 tr. tr. tr. tr. 2.75 23.58 16.85 14.33 33.20 1.52 0.46 j 10.45 0.09 23.70 16.54 12.13 33.14 1.85 | 0.32 > 10.90 1.16 55.25 A1203 12.10 Fe203. 1.28 FeO 10.71 MgO 9.30 CaO 0.34 Na20 0.28 K20 0.39 H20- . 1.49 H20+ 6.70 Ti02 0.15 C02 0.11 P206 tr. S 0.11 MnO 1.43 Total 99.80 100.48 99.74 99.64 1. Thuringite from the Last Chance mine near Creede, Colorado. J. G. Fair- child, analyst. 2. Thuringite, Harpers Ferry. J. L. Smith, analyst. From Dana's System of Mineralogy, 6th edition, p. 657, analysis 5. 3. Thuringite, Arkansas. J. L. Smith, analyst. From Dana's System of Mineralogy, 6th edition, p. 657, analysis 7. 4. Gouge made up largely of chlorite, from the Solomon mine near Creede, Colorado. J. G. Fairchild, analyst. LARSEN AND STEIGER: MINERALOGIC NOTES 11 mentioned, is made up largely of the chlorite of that vein but contains some quartz, some chalky decomposed rhyolite, and a few flakes of sericite. The three analyses of thuringite are very much alike, but the Creede mineral is lower in ferrous oxide and correspondingly higher in magnesia and manganous oxide; its somewhat higher content of silica may be due to admixed quartz. III. GRIFFITHITE, A NEW MEMBER OF THE CHLORITE GROUP Introduction. The authors have hesitated before proposing a new name for a member of the chlorite group, already over- burdened with names that have little significance and less place in a systematic scheme of classification. However, a chloritic mineral filling amygdaloidal cavities in a basalt collected by Mr. R. T. Hill from Cahuenga Pass, Griffith Park, Los Angeles, California, differs so greatly, both optically and chemically, from any of the chlorites previously described as to require a new name, and the name griffithite, from the locality, is pro- posed for the mineral. The amygdules of the basalt are up to an inch in largest dimension and comprise a considerable part of the rock; they are pure griffithite. Physical properties. The griffithite is dark-green in color, it has a hardness of about 1, is sectile, and has a specific gravity, as measured by the picnometer method, of 2.309. It is in basal plates and shreds, and some of the plates are a millimeter across. It has the usual cleavage of the chlorites. It fuses at about 4 with intumescence to a black magnetic slag. Optical properties. It is optically negative and 2V varies from 0° to 40°; X is normal to the cleavage. It has a strong bire- fringence and a rather strong pleochroism. The indices of refraction differ in different grains as much as 0.01; they and the pleochroism are: a = 1.485 ± 0.01; pale yellowish, 0 = 1.569 ± 0.005; olive-green, y = 1.572 ± 0.005; brownish green. 12 LARSEN AND STEIGER: MINERALOGIC NOTES Chemical properties. Griffithite gelatinizes with HC1. The material selected for the analyses showed under the microscope almost no impurities; its optical properties varied as indicated in the preceding description. The analysis by George Steiger is given in column 1 of table 3; the molecular ratios are given in column 2. TABLE 3. Analysis and Molecular Ratios of Griffithite 1 2 Si02 39.64 9.05 7.32 7.83 15.80 2.93 0.71 None 12.31 4.90 None 657 89) 46/ 109] 392 \ 52 J 11 684 272 = 5 X 131 A1203 Fe.03 = 1 X 135 FeO MeO ' = 4 X 138 CaO Na20 K20 H20- = 5 X 137 H20+ = 2 X 136 Ti02 100.49 The ratios lead to the formula 4(Mg,Fe,Ca)0.(Al,Fe)203. 5Si02.7H20 for griffithite. Prof. F. W. Clarke has kindly pro- posed the formula H4 R"4 R'"* Si50i9 + 5H20, or //// R R"'; ,Si04 = R" H -Si04 = R" H >Si03 + 5H20 -Si04 = R" H Si04 = R" H ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing in this issue. GEOPHYSICS. — Mechanics of the Panama Canal slides. G. F. Becker. U. S. Geological Survey Professional Paper 98-N. Pp. 253-261, with 3 figures. 1916. After describing the essential features of the breaks on the Culebra Cut the author points out that there is a limit to the depth of a vertical cut in an homogeneous isotropic mass, the upper surface of which is plane. This limit is that at which the pressure is sufficient to produce simple shear in the mass, and in a concluding note reasons are given for believing that 6 \ 2 multiplied by the resistance to such shear is about equal to the ultimate strength under linear compression. The depth at which one-sided relief of pressure will produce simple shear is called yv It is shown that in such a bank the profile of a surface along which the mass is strained to the elastic limit must be a form of the elastic curve, the directrix of which lies at a depth y±. The lowest or basal slide curve is one which intersects the horizontal bank at right angles. Examples are worked out for this and other cases. A complete analogy exists between the form of these curves and those which the surface of water assumes when it rises by capillarity between vertical, parallel glass plates. In view of these results the author discusses to some extent the for- mation of ruptures, the bulging of the canal bottom, and the effect upon pressure of the form of the banks. The paper includes a note on finite strains. G. F. B. PHYSICS. — The freezing point of mercury. R. M. Wilhelm. Bureau of Standards Scientific Paper No. 294. Pp. 6. 1916. The temperature at which mercury freezes is of importance in ther- mometry. It marks the lower limit to which mercurial thermometers may be used, and its location, at about — 39°C, makes it of value as a 13 14 abstracts: geology fixed point of the temperature scale below 0°C. This paper gives the result obtained and describes in detail the method used at the Bureau of Standards in making a redetermination of this constant. The temperature measurements were made by means of platinum resist- ance thermometers whose constants had been previously determined by calibration at 0°, 100°, and 444. 6°C. (the boiling point of sulphur). All the evidence at present available indicates that, down to — 40°C, the platinum resistance thermometer, calibrated as above, defines temperatures that are in agreement with those given by the standard gas thermometer. The value, —38.87°, obtained at the Bureau is in very good agreement with that found by Henning in 1913 at the Reichsanstalt, Germany. He also used platinum resistance ther- mometers and obtained -38.89°C. C. W. W. MAGNETISM. — The determination of the degree of uniformity of bars for magnetic standards. Raymond L. Sanford. Bureau of Stand- ards Scientific Paper No. 295. Pp. 14. 1916. Magnetic standard bars are used for the calibration of permeameters and for the comparison of methods of magnetic testing. One requisite of such a bar is that it shall be magnetically uniform along its length. If this condition is not fulfilled, errors may arise which can not be calculated or eliminated from the measurements, and which may be of considerable magnitude. In this paper it is shown how the degree of magnetic uniformity of a bar may be determined from observations of the distribution of magnetic leakage along the length of the bar when it is magnetized between the poles of a suitable electromagnet. The degree of uniformity is indicated by the values of the rate of change of leakage along the length of the bar. Deviations of these values from a constant indicate the presence of non-uniformities. An increase in the value indicates a magnetically hard spot while a decrease indicates a soft spot. The method may also be applied to the examination of magnetic materials for mechanical inhomogeneities and for the detec- tion of flaws. R. L. S. GEOLOGY. — Lode mining in the Quartzburg and Grimes Pass porphyry belt, Boise Basin, Idaho. E. L. Jones, Jr. U. S. Geological Survey Bulletin 640-E. Pp. 83-111, with 1 map. 1916. The Boise Basin lies near the western edge of the irregular moun- tainous area between the Salmon and Snake rivers in Idaho. The basin structure is ascribed to the sinking of a fault block approxi- abstracts: engineering 15 mately 15 miles long and 12 miles wide. The Basin is underlain domi- nantly by the granite of the great Idaho batholith, which is believed to be of late Cretaceous or early Tertiary age. During Tertiary time most of the Basin was occupied by a lake, and deposits of clay, sand, and gravel accumulated. Lava flows were erupted during and after the deposition of the sediments. Since the discovery of gold in 1862, Boise Basin has produced over $53,000,000 in precious metals. Of this amount the greater part was obtained from placers, but since the depletion of the gravels the lode deposits have been receiving more attention. The placer gold was derived from the disintegration of veins that occur in a belt of porphyr- itic dike rocks and in zones of shearing in the granite. The lodes now being worked are chiefly valuable for their gold and silver content, but with improved milling methods lead, copper, and zinc will probably add materially to the output. Monazite occurs abundantly in the placers but is not utilized. An unidentified radium-bearing mineral was found in placer gravels at one locality. E. L. J., Jr. GEOLOGY. — Tin ore in northern Lander County, Nevada. Adolph Knopf. U. S. Geological Survey Bulletin 640-G. Pp. 125-138. 1916. Tin ore has recently been found in northern Lander County, Ne- vada. The stanniferous mineral is exclusively wood tin, a form of stannic oxide concentrically banded like exogenous wood. It occurs in narrow veinlets traversing a series of rhyolite flows of middle Ter- tiary age; in places the veinlets are sufficiently closely spaced to form low grade lodes, but because of the small amount of development work so far done not much is known of the persistence and tenor of these lodes. The minerals associated with the wood tin are specular hematite, lussatite (a fibrous form of silica resembling chalcedony), chalcedony, tridymite, and opal. The deposits resemble closely those of the Mexican states of Durango, Zacatecas, and Guanajuato, but the association of wood tin with abundant tridymite and lussatite appears to be distinctive of the Nevada occurrence. A. K. ENGINEERING.— Colorado River and its utilization. E. C. LaRtje. U. S. Geological Survey Water Supply Paper 395. Pp. 231, with 25 plates and 5 figures. 1916. The region traversed by the Colorado and its tributaries is one of great interest in every respect. Various government bureaus have investigated certain questions pertaining to the water resources of 16 abstracts: technology the basin, much exploratory work has been done under private aus- pices, irrigation and power projects have been examined, railroad routes have been surveyed, and the Grand Canyon has been traversed by several persons and parties since Major Powell made the pioneer trips in 1869 and 1872. The information relating to the water resources that has been col- lected by many agencies has never been brought together so that a broad view of the possible utilization of the whole river could be ob- tained. The present report attempts the pioneer work of assembling the principal facts relating to the subject, and especially of studying the possibility of controlling the flow of the whole river by means of storage reservoirs, in order to avoid further danger of overflow to the Salton Sink and to render available for profitable use the enormous quantity of water that now flows unused and largely unusable to the Gulf of California in the form of floods. B. D. W. TECHNOLOGY. — Durability of stucco and plaster construction. R. J. Wig, J. C. Pearson, and W. E. Emley. Bureau of Standards Technologic Paper No. 70. Pp. 72. 1916. In 1915 the Bureau of Standards in cooperation with a committee which includes representatives from the Supervising Architect's Office of the Treasury Department, the American Concrete Institute, and three contracting plasterers of wide experience and from as many large cities, as well as representatives from the industries, undertook a comprehensive investigation of stucco construction. On the Bureau's grounds was erected a test structure containing 56 experimental stucco panels, each approximately 15 feet long and 10 feet high. These panels, which were completed in November, 1915, represent practi- cally all of the common types of stucco construction, a variety of mix- tures being used on metal lath, wood lath, hollow tile, brick, concrete block, plaster board, gypsum block, and concrete bases. In April, 1916, a careful inspection of the condition of the panels was made, and the present progress report and full description of the test structure was prepared. Only 2 of the 56 panels were entirely free from cracks six months after the panels were erected, and a num- ber of them were in very poor condition. On the other hand, about 40 per cent of the panels were rated as satisfactory. It should be mentioned that the smooth type of finish employed is well adapted to the bringing out of the small defects, such as cracks, blotches, uneven texture, etc. Further experimental work is needed before general con- clusions can be drawn. R. J. W. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE PHILOSOPHICAL SOCIETY OF WASHINGTON The 777th meeting was held on October 28, 1916, 'at the Cosmos Club. President Briggs in the chair; 50 persons present. The min- utes of the 776th meeting were read in abstract and approved. The Chair informed the meeting of the death on the morning of October 28, 1916, of Mr. Cleveland Abbe, a charter member of the Society. Mr. A. H. Taylor presented an illustrated paper embodying the results of an investigation in collaboration with Messrs. E. C. Crit- tenden and F. K. Richtmyer on A normal eye for the photometry of lights of different color. Individuals in general differ in their judgment of the relative brightness of lights which differ in color. Consequently, in order to assign definite values to such lights it is necessary to es- tablish some common basis of comparison and to provide means for reducing to this common basis the results obtained by different- ob- servers. For measurements of incandescent lamps it has been pro- posed to test observers by having them determine the relative trans- missions of a reddish-yellow (potassium bichromate) solution and a blue-green (copper sulphate) solution. This paper is a report of a trial of this method. For large color differences a flicker photometer must be used, and the size and brightness of the photometric field must be specified, to make the results definite. The conclusion reached was that the method proposed does give a practical means of establishing a normal eye and of reducing to the normal value the results obtained by any group of observers. The paper was discussed by Mr. Middlekauff, who referred to the intercomparisons at various laboratories of a series of glasses for the purpose of establishing a basis for the calibration of other color screens. The use of the flicker photometer necessitates no change in the photometric standards already adopted by the Bureau of Standards. Mr. W. W. Coblentz then spoke on The relative sensibility of the average eye to lights of different colors, giving the results of an investi- gation by himself and Mr. W. B. Emerson. The paper was illustrated by lantern slides. In the present investigation the methods were practically the same as those used by previous experimenters. In the visual measurements, the spectral light was compared with a stand- ard white light by means of a flicker photometer, also by an equality- of-brightness photometer. The source of white light was a standard- 17 18 proceedings: philosophical society ized vacuum tungsten lamp. A cylindrical acetylene flame was used as a source of spectral light. The distribution of energy in the spec- trum of the acetylene flame was determined with great care, in view of the fact that the disagreements in previous work seemed to be due, in part, to uncertainties in radiometrically evaluating the light stimu- lus. Sensibility curves were obtained for 130 persons, of which num- ber 5 were color-blind. The visibility curve of the average normal eye, using 125 observers, was found to be wider than previously ob- served. These data, obtained by the use of a flicker photometer, were given. Only a few observers were able to make accurate settings with the equality-of-brightness photometer. As was to be expected, the visibility curves of no two persons appear to be exactly alike. When a visibility curve does not coincide with the average there is usually a marked departure from the average visi- bility in a given spectral region. This gives rise to (1) wide visibility curves with the maximum shifted toward the red, i.e., "red sensitive," (2) narrow curves with a sharp maximum in the green, and (3) curves with the maximum shifted toward the violet. The data available indicate that among a group of persons having normal color vision about 20 per cent are (1) red sensitive, (2) blue sensitive, or (3) average, while in 10 per cent of the cases examined the color sensi- bility falls below the average (1) in the red or (2) in the blue or (3) falls below the average in both the red and the blue, thus giving rise to an apparently high sensitivity in the green. One person in 20 has a very wide visibility curve, while 4 per cent are color-blind, i.e., they confuse colors. The point of maximum sensibility was found to be very dif- ferent for different observers; for the 125 persons the mean maximum is at \m = 0.5576 /x. The curve of average visibility, when corrected for the selective transmission of the ocular media, including the yellow spot, is very symmetrical. An empirical equation of the visibility curve determined was given. Using this visibility equation and Planck's equation of black-body ra- diations, calculations were given of the luminous energy emitted by a black body at various temperatures; also the luminous efficiency, the Crova wave-length, and the mechanical equivalent of light. Using the recent measurements of the brightness of a black body, as deter- mined by Hyde, Cady, and Forsythe, and the most probable values of the radiation constants (C2 = 14,350, a = 5.7) the value is 1 lumen = 0.00161 watt of luminous flux; or 1 watt (of radiation of maximum visibility) = 621 lumens = 49.5 candles. The direct determination of 613.5 lumens of green mercury radiation, X = 0.5461 /x, (made by Ives, Coblentz, and Kingsbury, using 61 observers) when corrected for visibility V (at X = 0.5461 M) = 0.985 Vm gives 622.8 lumens per watt, in good agreement with the present determination. Discussion. Mr. Emerson emphasized the importance of taking the last observations; if only the first 40 had been used the curves would have been shifted. Mr. White asked whether the two eyes of an ob- proceedings: philosophical society 19 server could always be considered alike. Mr. Coblentz stated there was no great reason for testing the possible difference between the eyes of the observer. Mr. Swann referred to the limit of sensitivity of the human eye. Mr. Wenner noted that the visibility curve, as measured, depends on many things. What difference would there be by using equal-energy spectrum or equal light throughout spectrum? Mr. Coblentz thought that any difference would depend upon the stimulus started with. Mr. Taylor stated that it was very interesting to note the efficiency of ordinary illuminants. Mr. Wells referred to the practical application to photometry. Informal communications. Mr. W. F. G. Swann presented an in- formal communication, On the absorption of energy by an electron. In order that an electron may absorb an appreciable amount of energy from a wave falling upon it, it is frequently considered that the energy of the wave must be concentrated in a filamentary manner, the idea being that the electron can only take energy from a cross section of the advancing wave comparable with the cross section of the electron. That such an assumption is necessary has never appeared very con- clusive to the author, and the object of this work is to point out that if the difficulty of an electron's absorbing energy from a cross section of the wave, large compared with its own cross section, be admitted, we must confront this same difficulty in problems of much simpler nature than those which are generally quoted as the problems which give rise to the difficulty. Thus, suppose an electron to be placed in a uni- form field X of magnitude 1 volt per cm. The work done on it by the time it has moved a distance x is Xex. If we calculate the volume W of the original field which would contain energy equal to this amount, X2 remembering that the energy density is ^ — -v we readily find W = -^= — . Thus by the time the electron has moved 0.05 cm. in a field X J of 1 volt per cm., it will have absorbed energy equivalent to that con- tained in a volume of the original field equal to 18 X 10~8 cc, or in a sphere whose radius is about 3 X 10-3 cm. or 3 X 10'° times the ra- dius of an electron. The 778th meeting was held on November 11, 1916, at the Cosmos Club. President Briggs in the chair; 42 persons present. The min- utes of the 777th meeting were read in abstract and approved. Mr. G. K. Burgess presented a communication, illustrated with lantern slides, on The resistivity and thermoelectric properties of pure iron. There were described the apparatus and experimental methods used and results obtained in exact measurements of the resistance and the true thermoelectric power of pure iron over the temperature range 0° to 1000°C. Both series of measurements were taken in vacuo at 2° intervals using iron 99.968 pure. The characteristics of the trans- formations A2 at 768° and Az at about 910°C. and the lack of other 20 proceedings: philosophical society transformations were demonstrated. These experiments are de- scribed at length in the following: Bureau of Standards Scientific Paper No. 236 (Burgess and Kellberg on Electrical Resistance) and No. 296 (Burgess and Scott on Thermoelectric Power) also in abstract in this Journal (6:650. 1916). Discussion. Mr. L. J. Briggs asked what method was used to get the iron pure from the electrode. Mr. Burgess stated that after prying off the iron from the electrode it was melted in a crucible of magnesia and then drawn out after melting in vacuo; the stock of pure iron is kept in a vacuum. Mr. White spoke of the difficulty of ob- taining homogeneous iron and asked whether the iron used was thermo- electrically homogeneous. Mr. Wright referred to recent experiments at the laboratory of the General Electric Company in which the analy- sis of the structure of iron was made by the use of X-rays, and dis- cussed the crystalline structure of silicon-iron and electrolytic iron. By invitation Mr. L. H. Adams then gave an illustrated communi- cation on The effect of positive and of negative pressures on the resist- ance of metals. The effect of pressure on the resistance of metals was first noticed by Chwolson. His work and that of Lussana and others were briefly reviewed, and a short account was given of the various attempts that have been made, notably by Koenigsburg and by Griin- eisen, to place the variation of electrical resistance with pressure upon a theoretical basis. Pure hydrostatic pressure apparently al- ways decreases the resistance of pure metals by an amount which varies from about 1 to 30 parts per million per atmosphere. Many alloys, however, exhibit a positive pressure coefficient of resistance. The change in resistance of metals under pressure finds an important practical application in the measurement of very high pressures. Pressure gauges may be constructed of a coil of manganin or of "therlo" wire with an appropriate method for measuring small changes of re- sistance. Such gauges show no hysteresis and there is apparently no upper limit of pressure to which they may be used. Changes in re- sistance are also observed when tensile stresses are applied to metallic wires. Results were shown for the metals copper, platinum, silver, and "therlo." Now, since a tensile stress may be resolved into a negative hydrostatic pressure and two sets of shearing stresses, and since, moreover, preliminary experiments showed that shearing stresses produced no changes in the resistance (at least none greater than 10-8 per kg./cm.2), it would seem reasonable that there should be a simple relation between the two coefficients of resistance — hy- drostatic and tensile — provided only that each coefficient be properly corrected for the known elastic deformation. Results for four metals, however, failed to confirm this supposition. But it is worthy of men- tion that the corrected tension coefficients are always less and always opposite in sign to the corrected hydrostatic coefficients. Discussion. Mr. Hersey asked whether the change of resistance on stretching was permanent. Mr. Swtann asked whether any meas- urements had been made in the plane of torsion. Mr. Dickinson proceedings: philosophical society 21 spoke of the behavior of platinum resistance-thermometers under strain. Mr. Burgess referred to the possible change of state of cop- per under pressure. Mr. White spoke of the theoretical considerations involved. Messrs. Hersey and Swann considered the application of the recent theory of electrical conduction to the results. Mr. Wenner stated that the temperature coefficient of coils wound under tension at the Bureau of Standards was generally found different from that of the wire before winding; he noted also that the diagram shown by Mr. Adams for copper is very similar to that obtained for silver at the Bureau. The chair expressed to Mr. Adams the thanks of the Society for the interesting communication. Mr. F. Wenner then reported on a research made in collaboration with Mr. C. F. Hanson in a paper entitled The experimental basis for Ohm's law. Some of the experiments which led to the establishment of Ohm's law were discussed and also some of those which were made for the purpose of testing the law. It was pointed out that the ex- perimental tests are not so conclusive as has generally been supposed and that consequently a further consideration of the matter is de- sirable. Using one of the methods devised by Maxwell, results concor- dant to about 1 part in 106 were obtained — about five times the accu- racy obtained by Chrystal working under Maxwell's direction. A new method was devised, making use of a combination of a direct and two alternating currents, one with a frequency nearly but not exactly twice that of the other. The maximum value of the resulting, rapidly pulsating current changes in a slow cycle between definite limits, while the average and root mean square values may remain constant. The changing of the maximum value of the current independent of the average value would give changes in the average value of the poten- tial drop, unless the potential drop were strictly proportional to the cur- rent; while keeping the root mean square value of the current con- stant eliminates the disturbances which would result from a slow cyclic change in the heating. Only preliminary measurements have been made, but these give results concordant to about 1 part in 108. In no case has a definite departure from proportionality between current and potential drop been observed. The 779th meeting was held on November 25, 1916, at the Cosmos Club. President Briggs in the chair; 38 persons present. The min- utes of the 778th meeting were read in abstract and approved. Mr. W. P. White gave a paper, illustrated with lantern slides, on Specific heats at high temperatures. Platinum and certain silicon com- pounds were investigated. The charges were heated, usually in elec- tric heaters, and dropped into water in a calorimeter, so that the heat determination was made at ordinary temperatures under favorable conditions. The high temperature measurements in the furnace, the most critical part of the determinations, were made quite satisfactorily, first, by means of regulators which held the furnace temperature con- stant; second, by measuring temperature at the center of the charge 1/ 22 proceedings: philosophical society and by keeping the furnace temperature reasonably uniform by means of platinum-faced partitions and a suitable arrangement of the furnace winding. Duplicate results seldom differed as much as 0.001. Sys- tematic errors in calorimetry are usually much larger than the acci- dental, but numerous and varied intercomparisons seem to indicate that in this case there were few errors of any sort greater than 0.0015. The specific heats at high temperatures show in general a curvature con- cave to the . z-axis, which is merely the upper part of an »S-shaped curve characteristic of these as of all substances and explainable on the basis of the quantum hypothesis. Accepting that explanation, these curves show that the silica and silicon compounds investigated have atomic vibration periods of high frequencies comparable with those characteristic of the atoms of the diamond, whose specific heat curve is similar. These vibration frequencies are due to the oxygen in the compounds and are characteristic of oxygen compounds generally. Platinum shows an altogether different curvature at ordinary tem- peratures. The relation between the specific heats of the various substances when crystalline and when in the form of glass showed marked differences. There was also a tendency for the specific heat of the glass to increase 10 per cent or more at some rather high tem- perature; this as yet remains unexplained. Two definite kinds of in- version or transformation in the solid state were demonstrated, char- acterized by the presence in one case and the absence in the other of large variations in the specific heat below and at the temperature of inversion. Discussion. Mr. Swann noted that the agreement of the specific heats fitted in well with the quantum theory. Mr. Sosman referred to the different slopes of the heat curves for polymorphic substances and cited in particular the three forms of quartz; the question whether the cause is of atomic or molecular nature is an open one. Mr. L. J. Briggs spoke of the atomic heat of platinum at the higher tempera- tures. Mr. N. S. Osborne then presented an illustrated communication on A calorimeter for the determination of latent and specific heats of fluids. The principle of the unstirred or "aneroid" type of calorimeter has been embodied in an instrument especially designed for determinations of the specific heat and latent heat of vaporization of several sub- stances in general use as refrigerating media. Heat developed elec- trically in a coil located in the central axis of the cylindrical shell com- prising the calorimeter is distributed by conduction to the calorimeter and contents whose initial and final temperatures are measured, when in thermal equilibrium, by a platinum resistance thermometer. Heat from other sources is excluded by enveloping the calorimeter with a metal jacket, separated by an air space, and keeping this jacket dur- ing measurements at the same temperature as the calorimeter surface, using multiple thermocouples to indicate this equality. The measured heat added is used either to change the temperature of the contents or to evaporate a portion of the contents withdrawn as superheated proceedings: philosophical society 23 vapor; in the first case the specific heat is determined and in the sec- ond the latent heat of vaporization, when proper corrections are made. The unique features of this instrument are: 1. Central location of the heater and thermometer. 2. Distribution of metal connections between calorimeter and jacket to minimize errors from lead conduction. 3. Provision of a device for rapid cooling of the calorimeter. This consists of a copper ring which can be moved within the jacket so as to short-circuit thermally the insulating air space and permit the escape of heat to the cooled jacket. 4. Surface temperature equalizer for rendering the annulment of thermal leakage independent of thermal irregularities in the interior of the calorimeter. Measurements were made in the range of tem- perature from — 40°C. to + 40°C. of (a) the specific heat of liquid ammonia by two methods, one under saturation conditions, the other at constant pressure; (b) the latent heat of vaporization of ammonia; and (c) the latent heat of compression of liquid ammonia. Discussion. Mr. White thought the aneroid calorimeter a great advance in calorimetry. He discussed also the relative advantages of large and small calorimeters; a small instrument is to be preferred, provided proper care be used in the details of construction. Mr. Swann spoke of some experiences indicating the advantage of the aneroid type of instrument over the stirred-liquid type. Informal communications. Mr. M. D. Hersey presented as an in- formal communication a list of theorems relative to the errors of phy- sical measurements, which he has gradually developed during the past six years as a by-product of other work. There are five theo- rems relating to apparatus, two to observations, and seven to com- putations. The manuscript notes, such as they are, are available to any individual interested. Fragments of this work already published are to be found in the Journ. Wash. Acad. Sci., 1: 187, 1911; 3:296, 1913; 6:620, 1916; and in the B. A. Rep., Birmingham, 399, 1913. Mr. White spoke informally on the swelling and splitting, because of amalgamation by mercury, of the platinum element of a thermostat that had been stored away for two or three years. Mr. Wenner remarked that he had many times noted similar effects. Mr. Humphreys read a humorous poem giving a soldier's opinion of the climate of the Rio Grande. The 46th annual meeting (780 th regular meeting) was held on De- cember 9, 1916 in the assembly hall of the Cosmos Club. President Briggs and President-elect Buckingham in the chair; 34 persons present. The minutes of the 45th annual meeting were read. The report of the Secretaries was read by Mr. Agnew. Three members, viz., Messrs. Cleveland Abbe, Henry H. Bates, and F. B. McGuire, died during the year; 14 new members were elected; 8 members were transferred to the absent list; 2 members resigned; and 1 member was dropped. The present active membership is 149. 24 proceedings: biological society Sixteen regular meetings have been held. In accordance with the recommendation made at the 45th annual meeting, the General Com- mittee amended the By-Laws of the Committee by establishing a class of life membership to include all members who have maintained an active membership in the Society for 40 years. Messrs. Cleve- land Abbe, F. W. Clarke, Wm. H. Dall, and G. K. Gilbert became life members under this amendment. The report was ordered ac- cepted and placed on file. The Treasurer's report through December 6, 1916, was read by Mr. Sosman. The total receipts for the year, including cash balance of $109.72, were $3,234.83; the total expenditures for the year were $2,791.17; cash balance on December 6, 1916, $443.66. The total par value of the investments now held by the Society is $12,000. The report of the Auditing Committee consisting of Messrs. Mueller, Stillman, and Hostetter was read by Mr. Mueller. This Com- mittee reported the statements in the Treasurer's report had been found correct. The report was ordered accepted. The Treasurer's report was then ordered accepted and placed on file. Messrs. Ferner and Rothermel were appointed tellers. The fol- lowing officers were duly elected for the ensuing year: President: E. Buckingham; Vice-Presidents: G. K. Burgess, W. J. Humphreys, R. B. Sosman, Wm. Bowie; Treasurer: E. F. Mueller; Secretaries: P. G. Agnew, D. H. Sweet; General Committee: H. L. Curtis, N. E. Dorsey, R. L. Faris, E. G. Fischer, J. A. Fleming, D. L. Hazard, W. F. G. Swann, W. P. White, F. E. Wright. An unanimous vote of thanks was extended to the retiring Treas- urer and Secretary for their efficient services to the Society. The rough minutes of the meeting were read and approved. J. A. Fleming, Secretary. THE BIOLOGICAL SOCIETY OF WASHINGTON The 558th meeting of the Biological Society of Washington was held in the Assembly Hall of the Cosmos Club, Saturday, October 21, 1916; called to order at 8.15 by President Hay with 50 persons in attendance. The President announced the death of Prof. F. E. L. Beal, a mem- ber of the Society distinguished for his work in economic ornithology. On recommendation of the Council Mrs. Ella M. Enlows was elected to active membership. Under the heading Brief Notes and Exhibition of Specimens the following informal communications were presented. Mr. A. L. Quaintance called attention to a new peach pest related to the codling moth, lately found in the District of Columbia and immediate vicinity. These remarks were illustrated by lantern views of the insect and its work. Dr. C. W. Stiles commented on zoological nomenclature and gave notice that it was the intention to set aside the rules of strict priority proceedings: biological society 25 with reference to Holothuria and Physalia and to use these terms for the animals to which they are currently applied in the usual text books. Dr. Stiles also commented on recent cases in which trichina had figured in certain lawsuits, and expressed the view that with the purchase of meat products went the requirement that the product should be properly cared for and that in the case of pork this care required cooking before consumption; it was somewhat unfair to hold the seller of trichinous meat entirely responsible. Dr. L. O. Howard cited an instance in which a cockroach was fig- uring in a lawsuit. A man was suing a Texas railroad for damages on the ground that typhoid fever had been contracted through his drinking pop which had been contaminated by a cockroach, which had apparently been in the bottle before the man drank the pop purchased on the common carrier. The regular program consisted of an illustrated lecture by Dr. Paul Bartsch: Mollusk collecting in the Philippines. Dr. Bartsch reviewed the work of previous collectors and gave an account of his own collect- ing expedition, describing the methods and apparatus used. He spoke of mollusks as a source of food for the natives, and of their method of gathering them, and called attention to the variations cf these ani- mals as found on different islands. He showed also the necessity of exact locality determinations on specimens, and discussed the geo- graphic distribution of the Philippine molluscan fauna, pointing out its possible origin from other islands or land masses. The lecture covered not only the land mollusks but the marine forms as well. The 559th meeting of the Society was held in the Assembly Hall of the Cosmos Club, Saturday, November 4, 1916; called to order at 8 p. m. by President Hay with sixty persons present. On recommendation of the Council the following persons were elected to active membership: William B. Bell, Biological Survey; Fraxcis Harper, Biological Survey; H. E. Anthony, American Mu- seum of Natural History; and A. B. Howell, Covina, California. The President announced the death of Dr. E. A. Mearns, a mem- ber of the Council of the Society and distinguished for his work on birds, mammals, and other branches of natural history. Under the heading Brief Notes and Exhibition of Specimens, Dr. R. W. Shufeldt exhibited a specimen of the Japanese giant sala- mander and made some remarks on its habits and habitat. The regular program consisted of four papers as follows: R. H. Hutchison: A review of recent work on the house-fly. This paper was restricted to a discussion of recent studies on the preovi- position period, the range of flight, and the question of the overwinter- ing of the house-fly. The remarks on the preoviposition period sum- marized a recent bulletin of the Department of Agriculture on this subject (Bulletin 345). In discussing the range of flight, attention was directed to the fact that up to 1914 the longest recorded flight was 1700 yards. During the season of 1915 experiments were carried out 26 proceedings: biological society in a suburban locality near Washington by Max Kisliuk, Jr., under the direction of the writer. In these, several records of from 1800 to 2175 yards were obtained. These were compared with the records obtained by R. H. Parker during the same season at Miles City, Mon- tana; his longest record was 3500 yards. The question of how the house-fly overwinters in this latitude was said to be still undecided. It was pointed out that flies were not killed by the first heavy frost, as has often been stated; and that, in fact, a large percentage revived after several nights' exposure to minimum temperatures of 25° F. They are killed by temperatures of 15°F. Flies were found emerging up to the first week in December, and these late forms were found in heated buildings until the end of January. None were again seen till April 27. Other observations were cited as indicating that flies do not overwinter in the adult state; but, on the other hand, a long series of experiments and observations failed to give any positive evidence that they overwinter in the larval or pupal state. W. Dwight Pierce: Recent spread of the cotton boll weevil. A brief history of the movement of this pest through the United States sug- gests, from a study of specimens collected in all parts of the infested regions of North America, that there are three lines of dispersion. It seems probable that the boll weevil originated in Guatemala or some other portion of Central America and that the most typical strain migrated northward through the mountains of Mexico into Arizona, where it is now found as a native species on the wild cotton-like plant Thurberia thespesioides. The main migration was along the Gulf Coast, through the cultivated cotton regions, into the United States. The third line of dispersion was through Yucatan, across the Gulf, to Cuba. Specimens collected at the three termini of these dispersions appear to be very distinct varieties. That variety which is found on cultivated cotton in the United States is the smallest found and the most variable. The movement of the weevil is controlled by the amount of food supply, which regulates the time and distance of nat- ural movement by winds and floods, and by artificial agencies. The most interesting development of the present year is the extension of the weevil to the northern limits of cotton growth in Oklahoma and Arkansas into central Tennessee, eastward to the Atlantic Ocean south of Savannah, and the infestation of practically all the cotton region of Florida. The only Sea Island cotton section now not infected is that of South Carolina. E. R. Sasscer: Remarks on entomological inspection and disinfec- tion of products offered for entry into the United States. A brief review of the Plant Quarantine Act of 1912 was given, pointing out the principal features of the Act as relating to the control of stock entering the States, and what is required of the broker, the nurseryman, or other party importing plants or plant products. The quarantines re- lating to insects were referred to, and lantern slides of a number of these quarantined insects and others collected by inspectors were shown. Brief mention was made of the method of examining nursery proceedings: biological society 27 stock in the District of Columbia, and it was shown that such stock was divided naturally into (1) commercial material, including plants and plant products received by florists, department stores, and pri- vate individuals; and (2) Departmental material, including plants and plant products introduced by the various offices of the Department of Agriculture, more particularly the Office of Foreign Seed and Plant In- troduction. Some time was devoted to discussing the new method of disinfecting cotton, and lantern slides were shown exhibiting the plants which are now operating in Boston, Mass., Brooklyn, N. Y., Newark, N. J., and Oakland, Cal. H. S. Barber: An outline of the glow-worms of the American family Phongodidae. The 560th meeting of the Biological Society of Washington was held in the Assembly Hall of the Cosmos Club, Saturday, November 16, 1916; called to order by President Hay at 8 p.m. with 86 persons in attendance. On recommendation of the Council, Irwin Hoffmann was elected to active membership. Under the heading, Brief Notes and Exhibition of Specimens, Dr. O. P. Hay exhibited one of the cervical vertebrae of a deer from a deposit in Florida. He called attention to the fact that the remains of Florida deer have usually been referred to the existing species, Odocoileus osceola. A comparison of this vertebra with the correspond- ing one from recent deer, other than the Florida deer, showed that possibly the extinct Florida deer was a different species from the ex- isting deer. Dr. Hay said that there were no examples of cervical vertebrae of Florida deer for making comparisons, and that until such examples were seen the identification of the extinct deer must remain doubtful. Under the same heading Dr. Paul Bartsch called attention to a hybrid duck which he had lately seen exposed for sale in the markets. It was a cross between the black mallard and the domestic duck. The regular program consisted of two papers: H. Pittier: Forests of Panama (Illustrated by lantern slides). Professor Pittier gave first a condensed review of the results to the present date of the botanical part of the biological survey of Panama, undertaken under the auspices of the Smithsonian Institution. Then he showed how the distribution of the main ecological types of vege- tation is dependent upon the regime of the winds and of the rainfall. Mixed dicotylous forests cover at least six-tenths of the area of the Isthmus, the rest being occupied by savannas and park-like formations. Rain-forests with evergreen foliage extend over the entire northern watershed and part of Darien on the south side. Other forests of the southern slope belong to the type called monsoon-forest and are char- acterized by the presence of many species with deciduous foliage. The xerophytic character of the vegetation is more marked in the broken forests of the savanna belt, without however assuming an 28 proceedings: biological society extreme degree. The change in the composition of the vegetation with the increase in altitude has been dwelt upon by several travellers and botanical explorers of the Isthmus; it is very gradual but never- theless very radical. Several genera of trees observed at high alti- tudes are gregarious; there are, for instance, oak-forests, sub-tropical or even temperate in their general appearance. Lantern slides illus- trating types of forest, or of individual trees and flowers, were shown at the conclusion of the lecture. J. H. Paine : Scientific photography in the study of insects (Illustrated by lantern slides). M. W. Lyon, Jr., Recording Secretary. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII JANUARY 19, 1917 No. 2 MINERALOGY. — M agues ioludwigite, a new mineral.1 B. S. Butler and W. T. Schaller, Geological Survey. Introduction. In 1912, while making a reconnaissance examina- tion of the Big and Little Cottonwood districts, Utah, one of the writers, B. S. Butler, collected specimens of the rather rare mineral ludwigite.2 Specimens of this mineral from the Little Cottonwood district, in an undescribed collection made by J. M. Boutwell, were later examined. During the summer of 1916 it was possible to make more detailed observations of the occurrence of the mineral, and chemical analysis has shown the presence of an allied mineral, hitherto undescribed, for which the' name magnesioludwigite is proposed. Locality. The largest body of ludwigite observed is at the Mountain Lake mine at the head of Big Cottonwood Canyon, about 1| miles south of Brighton. Ludwigite occurs in places to the southwest of the Mountain Lake mine for more than half a mile, nearly to Lake Catherine, and also to the east. It was collected on the south side of Little Cottonwood Canyon, south- east of the Michigan-Utah boarding house. It was observed Preliminary papei . Published with the permission of the Director of the U. S. Geological Survey. 2Butler, B. S., and Loughlin, G. F. A reconnaissance of the Cottonwood- American Fork mining region, Utah. U. S. Geol. Survey Bui!. 620, p. 201. 1915. 29 30 BUTLER AND SCHALLER: MAGNESIOLUDWIGITE in rock debris near the Alta-Brighton trail north of Twin Lakes, and is abundant in the South Columbus tunnel of the South Hecla mine. It will doubtless be found at other localities in the district. Magnesioludwigite was found only in the Mountain Lake mine. Occurrence. Ludwigite occurs as a replacement of limestone at or near the contact with intrusive rocks and is associated with "contact minerals," including magnetite, forsterite, garnet, diopside, muscovite, and sulphides of iron and copper. In the Mountain Lake deposit magnetite and forsterite are the most abundant original minerals associated with the ludwigite. All of the minerals were probably formed at the same time, though the presence of veinlets of magnetite in the ludwigite and in the forsterite indicates that the magnetite continued to form after the ludwigite and forsterite had ceased to form. The sulphides also, in part at least, were formed probably later than the ludwigite and forsterite. In the Mountain Lake deposit the ludwigite is in finely fibrous crystals, forming radial and spherulitic groups which make up large masses of the mineral. These, as seen with the unaided eye or the hand lens, resemble tourmaline. There are exposed in the outcrop and on the dump many tons of a mixture of magnetite and ludwigite. The ludwigite occurs also as isolated crystals and groups of crystals in metamorphosed limestone, and from such occurrences well-defined crystals with natural crystal faces have been isolated and measured. The ludwigite is dull greenish black (Ridgway's color scale). In the outcrop of the deposit there is also much material of ivy-green color (Ridgway's color scale), which is the mineral for which the name magnesioludwigite is proposed. Its occurrence is like that of the ludwigite. Composition. Chemical analysis has shown that only 2.55 per cent of ferrous oxide is present in the ivy-green mineral, whereas typical ludwigite contains 17.01 per cent ferrous oxide. The analysis has also determined that the formula of the new mineral is MgO.Fe2O3.3MgO.B2O3, in which a small amount of ferrous oxide replaces some of the magnesia. The analysis swanton: aboriginal terms for brother and sister 31 can be interpreted as representing an isomorphous mixture of 85 per cent of magnesium borate with 15 per cent of ferrous borate. In its various properties magnesioludwigite shows the expected differences from those of the iron-richer ludwigite from Hungary. The luster is duller, the color lighter, the pleochroism and absorption weaker, and the translucency of the crushed material is markedly greater. These various changes in properties are correlated with the changes in chemical composition, and the existence of a definite series from the ferrous-iron borate to the magnesium borate is well shown by specimens of the mineral from Hungary, Montana, and Utah. This correlation is being made and will be given in full in the detailed paper now in preparation. The increased knowledge of the variation in chemical com- position and corresponding variations in other properties makes it necessary to recognize the two end members of the series of the natural magnesium-iron borates. It is therefore proposed to use the name ludwigite as a group name, similarly to the usage of the terms mica and feldspar, and to introduce the two names magnesioludwigite and ferroludwigite for the end members and for those parts of the series in which the magnesium or the ferrous-iron borate, respectively, predominates. Including the mineral pinakiolite in the group, the ludwigite group comprises then the following minerals, the term lud- wigite being usable for any member of the group until its exact relation has been determined: Group Ludwigite Species Ferroludwigite, FeO.Fe203.3MgO.B203 Magnesioludwigite, MgO.Fe203.3MgO.B203 Pinakiolite, MnO.Mn203.3MgO.B203. ANTHROPOLOGY. — Significance of the terms for brother and sister among primitive peoples. John R. Swanton, Bureau of American Ethnology. It is well known that among tribes divided into clans or gentes the terms for those relations for which we use "brother" 32 swanton: aboriginal terms for brother and sister and "sister" are extended to a large number of individuals of the same clan or gens and of approximately the same age as the speaker, but even experienced investigators are not so vividly conscious of the fact that they are by no means confined to that clan or gens. The idea of such a limitation is largely due to the fact that very many tribes, such for instance as the Iroquois, Choctaw, Chickasaw, Tlingit, Haida, and several of the Plains tribes, have only two exogamous groups, and that in such groups the men called collectively " fathers" are the husbands of the women called collectively "mothers." It happens, therefore, that the children of the father's brothers and the mother's sisters are the very same set of individuals and must always be of the exogamous division of the speaker and his own brothers and sisters. Thus it might be thought that the terms brother and sister were applied because the individuals so called were of the same clan or gens as self. In order to discover the true reason for the application of these terms we must turn to tribes having three or more exogamous groups. Among peoples of this kind with matrilineal descent the men of the father's clan will be able to marry into two or more others and their children will be of the same number of clans, while if the descent is patrilineal the women of the mother's clan will have the same variety of choice. Now, if the terms for brother and sister are primarily clan or gentile terms, they will not be applied to children of the father's clan or the mother's gens not of the clan or gens of the speaker. If they are primarily consanguineal terms they will be so applied. In the present article I shall not attempt an exhaustive study of this question but confine myself to an examination of the lists given by Morgan in his Systems of Consanguinity and Affinity1 and those recorded by Rivers in The History of Mel- anesia?! Society. The internal diversity of the two regions, each of which presents examples of tribes with exogamous di- visions and tribes without, tribes with matrilineal descent and tribes with patrilineal descent, tribes with dual divisions and tribes with multiple divisions, along with their remoteness from Smithsonian Contributions to Knowledge, vol. 17. SW ANTON: ABORIGINAL TERMS FOR BROTHER AND SISTER 33 each other, and the difference in time and circumstance under which they were recorded, promises a very fair sample of what may be looked for in primitive society as a whole. An inspection of the lists given by Morgan shows that the terms for brother and sister — elder and younger being also fre- quently distinguished — are employed by all tribes from which information is supplied except the Eskimo, who are without exogamous groups and therefore do not concern us. It is true that among certain peoples, such as the Chippewa, Ottawa, Potawatomi, Mohegan, Delaware, Spokane, and Creek, a dis- tinction is introduced between the own brother and sister and collateral brothers and sisters, who are often called " step- brothers," " step-sisters," "other brothers," and so on; but we find that in most cases these exceptional terms apply to both the child of the father's brother and the child of the mother's sis- ter; therefore their significance is mainly consanguineal and their use strengthens rather than weakens the argument for consanguinity. In one or two other cases the terms used are alternatives. Rivers yields precisely the same testimony. In his explanation of the terms employed in the island of Florida he specifically states that those for brother and sister were used "in the usual classificatory sense for all members of the clan of the same generation" and that they were applied also "in the same way to the children of the father's brothers, al- though these may be of different clans." By implication the same must be assumed in the systems recorded by him from the Torres Islands, Santa Cruz, the Reef Islands, Guadalcanar, Ysabel, and Savo, all of those in which there are more than two exogamous divisions and from which information is vouchsafed. The same is found, as we should expect, in tribes having two exogamous groups, and also in tribes without exogamous groups. In some cases these terms are so widely extended as to apply to the cross-cousins as well, the children of the father's sister and the mother's brother. The outstanding fact is, however, that the application of the terms for brother and sister is evidently governed by the relation of the parents of the persons so called to self. 34 swanton: aboriginal terms for brother and sister Precisely the same thing appears in the succeeding genera- tion, where the use of the terms son and daughter, and nephew and niece, is plainly determined by the status of the parents of those so denominated. These facts may be illustrated by the accompanying diagram, in which it is to be understood that each English expression stands for a single native term. It supposes a tribe with several clans and matrilineal descent, self male. Other systems would in- volve a few simple and readily comprehended changes. DIAGRAM ILLUSTRATING ^BROTHER" AND father's brothers' wives (clans 1, 3, 4, etc.) father's brothers (clan 2) RELATIONSHIPS. father = mother (clan 2) (clan 1) "sister" mother's sisters (clan 1) mother's sisters' husbands (clans 2, 3,4, etc.) brothers (clans 1, 3, 4, etc.) sisters (clans 1, 3,4,etc.) brothers (clan 1) self male (clan 1) sisters (clan 1) brothers (clan 1) sisters (clan 1) sons nephews sons sons nephews sons nephews and and and and and and and daughters nieces daughters daughters nieces . daughters nieces (clans 1,2, (clans 1,2, (clans 2, (clans 2, (clan 1) (clans 2, (clan 1) 3, 4, etc.) 3, 4, etc.) 3, 4, etc.) 3, 4, etc.) 3, 4, etc.) An examination of the remaining terms of relationship shows that almost the only ones which have a strictly clan or gentile connotation are those for father, mother, father's sister, and mother's brother. Those who argue for the priority of exog- amous divisions to relationship terminology and for their clan rather than consanguineal significance are therefore reduced to the assumption that such divisions first determined the four terms last given and that all of the others were developed from them on purely consanguineal lines. But even in the case of these four terms we ordinarily find a distinction between the own father and mother and the clan or gentile father and mother, and frequently there are other exceptions to a strictly swanton: aboriginal terms for brother and sister 35 clan usage of the terms. A theoiy which has to admit so many exceptions and which must grant the dominance of consan- guineal considerations in all but a few cases may well be viewed with suspicion. It is certainly a clumsy device when compared with the alternative theoiy of a simple extension of terms founded on the idea of blood relationship to groups of persons hypothetically, though not actually, related. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing iD this issue. PHYSICS. — A study of electromagnet moving coil galvanometers for use in alternating current measurements. Ernest Weibel. Bureau of Standards Scientific Paper No. 297 (Bull. Bur. Stds., 14: 23-58). 1917. This paper gives the results of a study of the electromagnet moving coil galvanometer that has led to the construction, of instruments with sensitivities much greater than those previously obtained and equal to those of the best direct current moving coil galvanometers. The theory of the instrument is developed. The equation of motion is first expressed in terms of the intrinsic constants (the moment of inertia, the moment of damping, the moment of restoration, and the moment of displacement) and the deflection, velocity, acceleration, and current in the moving coil. The current is then known from the resultant electromotive force in the moving coil circuit and the latter's constants. It is necessary in computing the resultant electromotive force to consider not only the impressed but also the induced electro- motive force. The latter is in part due to the motion of the coil in the magnetic field, causing electromagnetic damping, and in part due to the alternation of the flux linking with the coil, causing a current which results in a control torque in addition to that of the suspensions. The paper also contains descriptions and gives the performances of four instruments. The results indicate that the theory as given is fundamentally correct and therefore serves as a good basis for the design and use of instruments of this kind. E. W. GEOLOGY. — The lignite field of northwestern South Dakota. Dean E. Winchester, C. J. Hares, E. Russell Lloyd, and E. M. Parks. U. S. Geological Survey Bulletin 627. Pp. 165, with 11 plates. 1916. The report describes the geology and fuel resources of parts of Perkins and Harding counties in northwestern South Dakota. The 36 abstracts: geology 37 formations in the area include the Pierre, Fox Hills, Lance, Fort Union, White River, and Arikaree. The Lance is subdivided into three members: a lower undifferentiated portion, 425 feet thick; a middle or Ludlow lignite-bearing portion, 350 feet thick at most; and an upper marine member, the Cannonball, 225 feet thick. The marine fauna of the Cannonball member is very similar to but not identical with the fauna of the Fox Hills, which is of recognized Cretaceous age, while the flora of the Ludlow lignitic member is so much like that of the Fort Union, which is of recognized Tertiary age, that it is impossible to differentiate it from the Fort Union on the basis of the fossil leaves. Lignite beds are found in both the Lance and Fort Union formations, the more important beds occurring in the Lance formation. D. E. W. GEOLOGY. — Reconnaissance of the Conconully and Ruby mining districts, Washington. E. L. Jones, Jr. U. S. Geological Sur- vey Bulletin 640-B. Pp. i-iv, 11-36, with 1 plate. 1916. This report describes the geology and ore deposits of a small area in the central part of Okanogan County, Washington. In general the rocks comprise an older series of metamorphic rocks and a younger series of igneous rocks of batholithic origin. The metamorphic rocks consist of schists, quartzites, and limestones. Some of the schists are fine-grained and thinly laminated, but others are coarsely banded micaceous rocks that are evidently altered sandstones. The most schistose and gneissoid rocks are those which border the batholith. Closely associated with this sedimentary series are dike rocks and lavas that have undergone the same metamorphism and are probably of the same age, which is supposed to be Carboniferous. The common igneous rock of the area is a gray granite which has intruded the sedimentary rocks. It occurs over a large area and is probably a part of the Similkameen batholith. There are other igneous rocks of considerable areal extent, including a dark granite and an altered green porphyry. Dikes are abundant, particularly along the contact of the batholith with the metamorphic rocks; they include granite, diorite, pegmatite, and aplite, and probably represent the closing stage of igneous activity. The ore deposits are principally of two types, quartz veins and disseminated or replacement deposits. The quartz veins are widely distributed throughout the area, but those of proved value are grouped 38 abstracts: geology along the contact of the granite with the schists and gneisses. They are valuable for their lead-silver content and have yielded the principal output. The replacement deposits occur principally in a small area at the northern end of the Conconully district. They contain small amounts of copper and gold, but no ore has yet been produced com- mercially from them. R. W. S. GEOLOGY. — A reconnaissance of the Archean complex of the Granite Gorge, Grand Canyon, Arizona. L. F. Noble and J. Fred. Hunter. U. S. Geological Survey Professional Paper No. 98-1. Pp. 95-102, with 1 plate and 2 figures. 1916. The Tonto platform on the south side of the Granite Gorge affords a magnificent but difficultly accessible cross-section through the Archean complex, 800 feet deep and 40 miles in length. These oldest rocks of the Grand Canyon were visited in twenty localities, 67 hand specimens were collected, and eight distinct groups of rocks were recognized. The exposures within these groups are described and the petrography of the specimens is given. Estimated roughly, the gneisses (granite gneiss, hornblende gneiss, and metabasite) comprise 50 per cent of the rock exposed in the Gran- ite Gorge; the mica schist, 30 per cent; the basic intrusives, 10 per cent; and the pink siliceous intrusives, 10 per cent. It is not im- probable that the mica schists are in large part of sedimentary origin. It is believed that some of the wrinkled and contorted granite gneisses represent the original basement on which the schist series of meta- morphosed sediments was laid down; that both before and after the deposition of the sediments there were long periods of complex intru- sion, represented by amphibolites, granitic gneiss, metabasite, and metadiorite; that during and after the metamorphism of the schists and gneisses there were further intrusions of quartz diorite, gabbro, granite, pegmatite, and other rocks. It will probably be advisable, at some future time, to restrict the name "Vishnu schists," now used for the entire Archean complex, to the mica-schist series and give another name or names to the gneisses. J. F. H. GEOLOGY. — An anticlinal fold near Billings, Noble County, Oklahoma. A. E. Fath. U. S. Geological Survey Bulletin 641-E. Pp. 121- 138, with 1 plate. 1916. During February, 1916, gas was struck in small quantities at shallow depths in a well being drilled a few miles southwest of Billings, Noble abstracts: technology 39 County, Oklahoma. As this discovery was made at a place more than 20 miles distant from any other known oil and gas development, it has attracted considerable attention, winch is justified by the presence of a large anticlinal fold, a type of structure that should be favorable for the accumulation of oil and gas. A description of the anticlinal fold and a discussion of the possibilities of developing an oil and gas field here are given. R. \y# S. PALEONTOLOGY. — North American Upper Cretaceous corals of the genus Micrabacia. Lloyd William Stephenson. U. S. Geo- logical Surve3r Professional Paper 98-J. Pp. 115-131, with 4 plates. 1916. The report describes seven species and two varieties of corals of the genus Micrabacia from the United States, all but one of which, M. americana Meek and Hay den, are new. All are from the Atlantic and Gulf coastal plains, except M. americana and its variety multi- costata from the Montana group of the Western Interior. Of the coastal-plain species, M . cribraria is from the upper part of the Exogyra ponderosa zone (North Carolina — Alabama), and the remainder are from the Exogyra costata zone of Maryland, Georgia, Mississippi, and Texas. The American species are compared with the type species of the genus, M . coronula Goldfuss, a description and figures of which are included, from Essen, Prussia. Each of the species has a small disc- shaped corallum, the largest, M. rotatilis, being only 9 mm. in diame- ter; in order to illustrate the characters it is necessary to magnify them four to eight times. L. W. S. TECHNOLOGY. — The recovery of paraffin and paper stock from waste paraffin paper. W. H. Smith. Bureau of Standards Technologic Paper No. 87. Pp. 4. 1916. This paper describes a process for the recovery of the paraffin and paper stock from waste paraffin paper. The waste is pulped with exhaust steam in a vertical boiler. The wax rises to the surface and is drawn off with the hot water through a screen, the stock settling to the bottom of the boiler. The stock is transferred to a beating engine and further treated for the removal of the residual paraffin. Paper prepared from the recovered stock was free from wax and satis- factory in every respect. Practically all of the paper stock is recovered, but about ten per cent of the paraffin in the waste is lost during the process. W. H. S. M : REFERENCES Under this heading it is proposed to include, by author, title, and citation, references to all scientific papers published in or emanating from Washington. It is requested that authors cooperate with the editors by submitting titles promptly, following the style used below. These references are not intended to replace the more extended abstracts published elsewhere in this Journal. CHEMISTRY Blum, William. The determination of aluminium as oxide. Bureau of Stand- ards Scientific Paper No. 286 (Bull. Bur. Stds., 13: 515-534). 1916. Cain, J. R., Schramm, E., and Cleaves, H. E. The preparation of pure iron and iron-carbon alloys. Bureau of Standards Scientific Paper No. 266 (Bull. Bur. Stds., 13: 1-26). 1916. Clarke, F. W., and Wheeler, W. C. The inorganic constituents of alcyonaria. Proc. National Acad. Sci., 1: 552-556. 1915. Gillespie, L. J. The reaction of soil and the measurements of hydrogen-ion con- centration. Journ. Wash. Acad. Sci., 6: 7-16. 1916. Hillebrand, W. F., and Scherrer, J. A. Recovery of gallium from spelter in the United States. Journ. Ind. and Eng. Chem., 8: 225. 1916. Lubs, Herbert A., and Clark, Mansfield. On some new indicators for the colorimetric determination of hydrogen-ion concentration. Journ. Wash. Acad. Sci., 5:609-617. 1915. Waters, C. E., and Ttjttle, J. B. Some qualitative tests for gum arabic and its quantitative determination. Bureau of Standards Technologic Paper No. 67. Pp. 15. 1916. Weaver, E. R. The colorimetric determination of acetylene and its application to the determination of water. Bureau of Standards Scientific Paper No. 267 (Bull. Bur. Stds., 13: 27-65). 1916. MAMMALOGY Allen, J. A. The genotypes of Echimys and Loncheres. Proceedings of the Biological Society of Washington, 29:205-206. September 22, 1916. (Ar- gues that E. spinosus is the type of Echimys and L. chrysurus the type of Loncheres. — N. H.) Gabrielson, I. N. A second record of Nyctinomus depressus for Iowa. Pro- ceedings of the Biological Society of Washington, 29:86. April 4, 1916. (A specimen of this southwestern species taken at Marshalltown. — N. H.) Goldman, E. A. Notes on the genera Isothrix Wagner and Phyllomys Lund. Proceedings of the Biological Society of Washington, 29: 125-126. June 6, 1916. (Several species heretofore included in Isothrix are transferred to the genus Phyllomys. — N. H.) Goldman, E. A. The status of Sigmodontomys alfari Allen and Oryzomys ochraceus Allen. Proceedings of the Biological Society of Washington, 29: 127. June 6, 1916. (These specific names are synonymous, and the animal should be called Nectomys alfari. — N. H.) 40 references: mammalogy 41 Goldman, E. A. A new vesper rat from Nicaragua. Proceedings of the Bio- logical Society of Washington, 29: 155-156. September 6, 1916. (De- scribes Nyctomys sumichrasti venustulus from Greytown.— N. H.) Grinnell, J. The California lowland mink a distinct race. Proceedings of the Biological Society of Washington, 29:213-214. September 22, 1916. (De- scribes Mustela vison aestuarina from Solano County. — N. H.) Hollister, N. Descriptions of a new genus and eight new species and subspecies of African mammals. Smithsonian Miscellaneous Collections, 661: 1-8. February 10, 1916. (Cercoctenus, new genus of Macroscelidae; and new forms in the genera Surdisorex, Rhinolophus, Eptesicus, Chaerephon, Ge- netta, Mungos, and Helogale. — N. H.) Hollister, N. Three new African shrews of the genus Crocidura. Smithsonian Miscellaneous Collections, 668: 1-3. May, 1916. (C. daphnia described from Uganda; C. parvipes nisa and C. simiolus described from British East Africa.— N. H.) Hollister, N. The generic names Epimys and Rattus. Proceedings of the Biological Society of Washington, 29: 126. June 6, 1916. (Rattus the proper generic name for the Norway rat and its allies. — N. H.) Hollister, N. A systematic account of the prairie-dogs. North American Fauna No. 40. Pp. 1-37, pis. 1-7. June 20, 1916. (New subgenus, Leuco- crossuromys, for the white-tailed prairie-dogs; new subspecies Cynomys gunnisoni zuniensis, from New Mexico. — N. H.) Hollister, N. The type species of Rattus. Proceedings of the Biological So- ciety of Washington, 29: 206-207. September 22, 1916. (Mus norvegicus is the type of Rattus Fischer, 1803— N. H.) Hollister, N. Shrews collected by the Congo expedition of the American Mu- seum. Bulletin of the American Museum of Natural History, 35: 663-680, pis. 7-11. October 21, 1916. (Six new species of Crocidura and one of Sylvisorex from Belgian Congo. — N. H.) Hollister, N. Three new murine rodents from Africa. Smithsonian Miscel- laneous Collections, 6610: 1-3. October 26, 1916. (Describes new forms of Arvicanthis, Dasymys, and Mus. — N. H.) Howell, A. H. Description of a new pine mouse from Florida. Proceedings of the Biological Society of Washington, 29 : 83-84. April 4, 1916. (Pitymys parvulus, sp. nov., from Ocala. — N. H.) Jackson, H. H. T. A new bat from Porto Rico. Proceedings of the Biological Society of Washington, 29:37-38. February 24, 1916. (Describes Eptesi- cus wetmorei from Maricao.— N. H.) Lantz, D. E. Cottontail rabbits in relation to trees and farm crops. U. S. De- partment of Agriculture Farmers' Bulletin No. 702. Pp. 1-12, figs. 1-5. January 17, 1916. (Discusses the habits of cottontail rabbits and methods of controlling their numbers. — N. H.) Lantz, D. E. Laws relating to fur-bearing animals, 1916. United States De- partment of Agriculture Farmers' Bulletin No. 783. Pp. 1-28. October 19, 1916. (A summary of laws in the United States and Canada relating to fur-bearing aDimals. — N. H.) 42 references: technology Lyon, M. W., Jr. A porcupine skull with a pair of supernumerary well developed incisors in the upper jaw. Anatomical Record, 10: 459-462. April 20, 1916. (Note on abnormal dentition of Acanthion longicaudum. — N. H.) Lyon, M. W., Jr. Belgian hare, a misleading misnomer. Science, N. S., 43: 686. May 12, 1916. (Corrects error in generic identification of the Belgian "hare" in anatomical paper by C. D. Holliger. — N. H.) Lyon, M. W., Jr. Two new mammals from Sumatra. Proceedings of the Bio- logical Society of Washington, 29: 209-211. September 22, 1916. (De- scribes new forms of Rattus. — N. H.) Merriam, C. H. East Africa — Game garden of the world. American Museum Journal, 16: 145-153. March, 1916. (A review of Roosevelt and Heller's "Life-Histories of African Game Animals," 1914. — N. H.) Merriam, C. H. Ovis sheldoni, a new mountain sheep from Sierra del Rosario, Sonora, Mexico. Proceedings of the Biological Society of Washington, 29: 129-132. September 6, 1916. Merriam, C. H. Nineteen apparently new grizzly and brown bears from western America. Proceedings of the Biological Society of Washington, 29: 133- 154. September 6, 1916. (Descriptions of new species and subspecies of Ursus, with remarks on distribution and relationship of mainland and island forms. — N. H.) Miller, G. S., Jr. Note on the indigenous rodent of Santo Domingo. Proceed- ings of the Biological Society of Washington, 29:47. February 24, 1916. (Records additional specimens of Plagiodontia aedium Cuvier, hitherto known only by the type described in 1836. — N. H.) Miller, G. S., Jr. Remains of two species of Capromys from ancient burial sites in Jamaica. Proceedings of the Biological Society of Washington, 29 : 48. February 24, 1916. (A species apparently much like the form known from Little Swan Island is represented by bones; as well as remains of the pre- viously known Jamaica species, C. broivnii. — N. H.) Nelson, E. W. The larger North American mammals. National Geographic Magazine, 30: 385-472. November, 1916. (A popular account, illustrated by numerous colored pictures by L. A. Fuertes. — N. H.) Taylor, W. P. Aplodontia humboldtiana, a new mountain beaver from the Humboldt Bay district, California. Proceedings of the Biological Society of Washington, 29: 21-23. February 24, 1916. Thomas, O. Note on the name Corynorhinus megalotis. Proceedings of the Biological Society of Washington, 29: 127. June 6, 1916. (Preoccupied; replaced by Corynorhinus rafinesquii. — N. H.) TECHNOLOGY Ahlborn, G. H. Data on electric railway track leakage. Bureau of Standards Technologic Paper No. 75. Pp. 22. 1916. Botjghton, E. W. The determination of volatile thinner in oil varnish. Bureau of Standards Technologic Paper No. 76. Pp. 6. 1916. Briggs, C. A. Relative merits of long and short wheel-base test cars. The Scale Journ., 1: 5. 1915; Railway Rev., Aug. 14, 1915; Railway Age Gaz., April 21, 1916. Briggs, C. A. Automatic grain scales. Scale Journ., Jan. and May, 1916. references: technology 43 Briggs, C. A. Graphical study of railroad track scales and master scale perform* ances. Scale Journ., June. 1916; Railway Rev., July 15, 1916. Bureau of Standards. Analyzed irons and steels. Methods of analysis. Bureau of Standards Circular No. 14, 5th ed. Pp. 17. 1916. Bureau of Standards. Magnetic testing. Bureau of Standards Circular No. 17, 3d ed. Pp. 50. 1916. Bureau of Standards. Measurements for the household. Bureau of Standards Circular No. 55. Pp. 149. 1915. Burgess, G. K., and Merica, P. D. Some j oreign specifications for railway mate- rials: Rails, ivheels, axles, tires. Bureau of Standards Technologic Paper No. 61. Pp. 132. 1916. Cain, J. R., and Cleaves, H. E. Determination of carbon in steels and irons by direct combustion in oxygen at high temperatures. Bureau of Standards Tech- nologic Paper No. 69. Pp. 10. 1916. Karr, C. P., and Rawdon, Henry S. Standard test specimens of zinc bronze (Cu 88, Sn 10, Zn 2). Part I. — Preparation of specifications; Part II. — Micro- structure. Bureau of Standards Technologic Paper No. 59. Pp. 67. 1916. Lewis, Walter S. Difference in weight between raw and clean wools. Bureau of Standards Technologic Paper No. 57. Pp. 5. 1915. McCullom, B., and Ahlborn, G. H. Special studies in electrolysis mitigation. III. A report on conditions in Springfield, Ohio, loith insulated feeder system installed. Bureau of Standards Technologic Paper No. 54. Pp. 64. 1916. McCullom, B., and Logan, K. H. Special studies in electrolysis mitigation. IV. A preliminary report on electrolysis mitigation in Elyria, Ohio, with recommendations for mitigation. Bureau of Standards Technologic Paper No. 55. Pp. 49. 1916. McCullom, B., and Ahlborn, G. H. Influence of frequency of alternating or in- frequently reversed currents on electrolytic corrosion. Bureau of Standards Technologic Paper No. 72. Pp. 31. 1916. Rosa, E. B., Brooks, H. B., McCullom, B., Canada, W. J., and Glading, F. W. An investigation of enclosed cartridge fuses. Report of the Bureau of Standards in the case of Economy Fuse and Manufacturing Co. vs. Under- writers' Laboratories (Inc.), concerning the fire and accident hazard of the Economy Refillable Fuse as compared with approved fuses. Bureau of Stand- ards Technologic Paper No. 74. Pp. 199. 1916. Tuttle, J. B. Determination of barium carbonate and barium sulphate in vul- canized goods. Bureau of Standards Technologic Paper No. 64. Pp. 5. 1916; Journ. Ind. and Eng. Chem., 8: 324. 1916; Chem. Eng., 23: 129. 1916; Chem. Abs., 10: 1289. 1916. Waters, C. E., and Tuttle, J. B. Some qualitative tests for gum arabic and its quantitative determination. Bureau of Standards Technologic Paper No. 67. Pp. 15. 1916; Journ. Ind. and Eng. Chem., 8: 413-416. 1916. Waters, C. E. Data on the oxidation of automobile cylinder oils. Bureau of Standards Technologic Paper No. 73. Pp. 20. 1916; Journ. Ind. and Eng. Chem., 8: 587-592. 1916. Wig, R. J., Williams, G. M., and Gates, E. R. Strength and other properties of concretes as affected by materials and methods of preparation. Bureau of Standards Technologic Paper No. 58. Pp. 172. 1916. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE BOTANICAL SOCIETY OF WASHINGTON The sixteenth annual meeting of the Botanical Society of Washington was held in Room 32 of the Bureau of Plant Industry building, U. S. Department of Agriculture, at 1.30 p.m., October 16, 1916, with W. E. Safford acting chairman and H. L. Shantz acting secretary. The minutes of the fifteenth annual meeting were read and approved and the report of the Executive Committee read and approved. The report of the Treasurer was read and an Auditing Committee, con- sisting of P. L. Ricker and G. P. Van Eseltine, appointed by the Chair. The following officers were elected for the ensuing year: President, T. H. Kearney; Vice-President, Edgar L. Brown; Recording Secretary, Charles E. Chambliss; Corresponding Secretary, H. L. Shantz; Treasurer, F. D. Farrell. Mr. A. S. Hitchcock was nominated by the society as Vice-President of the Washington Academy of Sciences. The 115th regular meeting of the Society was held at the Cosmos Club Tuesday, November 7, 1916, at 8.00 p.m. Mr. Michael Shapovalov, Dr. Howard G. MacMillan, Dr. Joseph Rosenbaum, and Mr. F. E. Miller were elected to membership in the Society. Under Brief Notes and Reviews of Literature, Mr. W. T. Swingle called attention to a recent edition of an ancient Chinese work on bot- any, The Cheng lei pen ts'ao, originally published in 1108 A.D. Dr. A. T. Tenaka reviewed briefly a recently issued Hand Book of Plant Diseases of Japan, by Jinzo Matsumura. The following papers were presented: Notes on the life of John Bradbury: R. H. True. Information concerning the life of this early naturalist and explorer of the Missouri Valley is very meager. A considerable addition has been gained from the correspondence carried on between Bradbury and Thomas Jefferson, who greatly influenced the course of Bradbury's life and work in this country. Bradbury's life, as gathered from this and other available sources, was sketched in outline. 44 proceedings: biological society 45 Pathological problems in the distribution of -perishable plant products: C. L. Shear and W. A. Orton. The enormous losses in recent years caused by the deterioration and decay of fruits and vegetables between the field and the consumer have led to a more active interest in this subject and a desire on the part of those most directly affected to have the causes and means of prevention determined. In most cases fungi are the active agents in causing the destruction of such products, and the problem is primarily pathological. In order to devise means of avoiding these losses, a thorough knowledge of all the factors and con- ditions involved must be qbtained. Each fruit and vegetable has its own peculiarities and its own parasites. In some cases the cause of loss may be traced to the field, and in others to conditions of transporta- tion and handling. In any specific case the cause and responsibility for the loss can be determined only by careful investigation of all the facts. Specific cases of losses of strawberries, peaches, cranberries, watermelons, tomatoes, and potatoes were cited to indicate the com- plexity of the problems and the danger of drawing any general conclu- sions from insufficient data. It was shown that the means of prevent- ing such losses will depend upon the nature of the cause or causes, as determined by a knowledge of all the factors in any particular case. H. L. Shantz, Corresponding Secretary. BIOLOGICAL SOCIETY OF WASHINGTON The 561st meeting of the Society was held at the Cosmos Club, Saturday, December 2, 1916; called to order by President Hay at 8 p.m. with 50 persons in attendance. The following program was presented: W. P. Hay : The discovery of an interesting new tardigrade. Professor Hay gave a brief description of a tardigrade belonging to the genus Batillipes, discovered by him some years ago at Beaufort, N. C. It is closely related to B. mirus Richters but differs from that species in a number of important characters. The structure and relationship of the tardigrades were discussed and the conclusion was reached that Batillipes, in spite of its evident specialization along certain lines, is probably the most primitive genus of the group. From Batillipes through Halechiniscus to Oreella and Echiniscus was sug- gested as one line of development, while from Echiniscoides through Milnesium to Macrobiotus and Diphascon appears to be another. The genus Tetrakentron, with its single species T. synaptae, shows a high degree of specialization due to parasitism, and Microlyda is probably the larval form of Halechiniscus. Attention was called to the habitat of the ten animalcules belonging to these genera. Five of them, Batillipes, Halechiniscus, Microlyda, Tetrakentron, and Echiniscoides are marine; Echiniscus and Oreella are strictly terrestrial; Macrobiotus is mostly terrestrial or lacustrine, but is represented in salt water by at least two species; Diphascon is 46 proceedings: biological society terrestrial and lacustrine. The fact that the majority of the genera are marine and that this list includes all the more primitive genera points strongly to a marine origin for the group. It also supports the idea advanced by Professor Richters in 1909 that the tardigrades are probably most closely related to the chaetopod worms and should be removed from the class Arachnida in or near which the group is usually placed in our zoological text books. Professor Hay's com- munication was illustrated by charts and diagrams. J. N. Rose: Exhibition of Venezuelan plants and fruits. Dr. Rose had on exhibition a large tableful of fruits, fruit products, and various articles made of parts of Venezuelan plants. He explained their use and described the plants from which they were obtained. The specimens were obtained for the most part in the vicinity of La Guaira and Caracas. Dr. Rose's communication was discussed by Messrs. H. Pittier, M. W. Lyon, Jr., and others. M. W. Lyon, Jr.: Poisonous snakes. Dr. Lyon -gave an account of the various specific substances that have been found in snake venoms, and outlined their modes of action on the various tissues of bitten animals. He spoke of the various antiserums that have been prepared against these venoms, and their therapeutic uses. He called attention also to the non-specific treat- ment of snakebites in the light of modern statistics and experiments. He then gave a brief outline of the classification of venomous snakes, and discussed their geographic distribution and the development and structure of the poison gland and fang. His communication was illustrated by lantern slide views of skulls, glands, and fangs of poisonous snakes, of types of poisonous snakes, and of some of the histological changes caused by snake venom. It was discussed by Messrs. A. A. Doolittle, H. Pittier, H. M. Smith, H. E. Ames, and T. E. Wilcox. The 562d regular and the 37th annual meeting Of the Society was held at the Cosmos Club, Saturday, December 16, 1916; called to order by President Hay at 8 p.m. with 23 persons present. Annual reports of officers and committees were submitted. Elec- tion of officers for the year 1917 resulted as follows: President, W. P. Hay; Vice-presidents, J. N. Rose, A. D. Hopkins, Hugh M. Smith, Vernon Bailey; Recording Secretary, M. W. Lyon, Jr.; Corresponding Secretary, W. L. McAtee; Treasurer, Ned Dearborn; Members of Council, N. Hollister, J. W. Gidley, William Palmer, Alex. Wetmore, E. A. Goldman. President Hay was nominated as vice- president of the Washington Academy of Sciences. Ex-president B. W. Evermann then gave an illustrated lecture regarding the present condition of the museum of the California Academy of Science and its aims and aspirations. This was dis- cussed by Messrs. E. W. Nelson and Vernon Bailey. M. W. Lyon, Jr., Recording Secretary. proceedings: anthropological society 47 THE ANTHROPOLOGICAL SOCIETY OF WASHINGTON The 500th meeting of the Society was held at the New National Museum, October 17, 1916, at 4.30 p.m. Dr. Walter Hough, of the National Museum, read a paper on Ancient pit dwellers in New Mexico. Dr. Hough said that remains of pit dwellings were indicated on the site of stone ruins explored in western Socorro County, New Mexico, several years ago and that a large cluster of such dwellings not con- nected with stone ruins was observed subsequently near Luna, in Socorro County. The site was productive of interesting results during an exploration for the Bureau of American Ethnology last summer. The field in which the remains occur had been smoothed over by natural agencies and the positions of the houses were shown only by the stronger growth of vegetation over circular areas, this defining the pits. Some of the pits were cleared, and it was found that they were from 12 to 14 feet in diameter and 5| feet deep. Remains of roof clay and charred posts and beams indicate that the roof was supported on posts placed around the periphery of the pit. It is thus probable that more than half of the house was underground, and perhaps the position of the walls above ground were banked. The floor arrangement shows a fireplace near the center, a metate and grinding stones near the fire. In one of the pits a burnt clay wall fireplace was found. Adjoining the pits was a rectangular house also rooted with clay. Here were found numerous grinding stones, baking slabs, and remains of pottery, these being about a foot under the surface loam. This house was an open air cooking and mealing shed. Near the first pit excavated was a cemetery of infants; no remains of adults have yet been found on the site. A dance amphitheater which was about 100 feet in diameter and 10 feet deep lies on the east side of the site. It has been filled by natural agencies with about 5 feet of fire-blackened debris and in it large pine trees have matured. It is on the bank of the former and larger channel of a living stream which traverses the eastern edge of the site. The specimens found are crude metates, rubbing stones, hammer stones, baking slabs, etc.; pottery of Pueblo type, decorated and un- decorated and of some crudity; a few bone awls and small obsidian arrowheads. No stone axes were found. Dr. Hough presented the problem as he found it, and hesitated as yet to pronounce upon the affiliations of the people who constructed the pit houses. The 501st meeting of the Society was held in the Lecture Hall of the Public Library, on Tuesday evening, November 7, 1916, at 8 o'clock. The speaker was Mr. W. E. Saffoed, of the Bureau of Plant Industry, U. S. Department of Agriculture. His subject was Magic plant* of the ancient Americans. The paper was illustrated with lan- tern slides. 48 proceedings: anthropological society Mr. Safford said that the practice of magic was widely spread in both North and South America in pre-Columbian times, and in con- nection with it certain plants, principally those having narcotic prop- erties, were used ceremonially, often as incense, or to produce hal- lucinations, to call up the spirits of the dead, and to expel evil spirits from the sick and insane. The priest of the Temple of the Sun at Sagomozo, in the Andes of South America, prophesied and revealed hidden treasures while in a state of frenzy caused by the seeds of a tree datura (Brugmansia sanguined). This recalls similar practices of the priestesses of the oracle at Delphi. Another Peruvian plant with marvelous properties described by early explorers was Erythroxylon Coed, from which the valuable alkaloid cocaine is now obtained. Bags of its leaves accompanied by little gourds containing lime were found by the author in many graves near the Peruvian coast, hanging about the necks of the mummified remains of the dead. On the opposite coast of South America, or rather in Paraguay, grew the highly esteemed Ilex paraguariensis, or yerba mate. Closely allied to it is the Ilex vomitorid of the southeastern United States, from which the In- dians made the famous "black drink," used ceremonially as a magic physic, which purged them from evil and which was used also in initiat- ing their youths into manhood. Professional priests, or necromancers, were encountered by Columbus and his companions on the island of Hispaniola, who induced intoxication and called up their zemi, or gods, by means of a narcotic snuff, called cohoba, inhaled through the nostrils by means of a bifurcated tube. This snuff, hitherto believed to have been tobacco, has been identified recently by the author as the powdered seeds of a Mimosa-like tree, Piptadenia peregrina, still used in a similar way by various South American tribes of Indians, by some of whom an infusion of the seeds is also used to induce intoxication, administered as an enema by means of a pear-shaped syringe of caoutchouc. In Mexico, the early missionaries, who were called upon to stamp out the practice of witchcraft, found that the Aztecs paid divine honors to various plants, especially to huauhtli (a white-seeded Amaranthus); ololiuhqui (a Datura); peyotl (a spineless cactus, Lophophora Wil- liamsii) also called teonanacatl, or "Sacred Mushroom;" and picietl (tobacco). Of huauhtli seeds, ground to a paste with the syrup of maguey, images were made and adored, and afterwards broken into fragments and served as a kind of communion. This seed was pro- duced in such quantities that it was used in paying tribute to Monte- zuma, at the time of the Conquest. The ololiuhqui was regarded as divine, and it was considered a holy task to sweep the ground where it grew. Its spirit, addressed as the Green Woman (Xoxouhqui Cihuatl) , was invoked to expel certain diseases and to overcome weaker and inferior spirits in possession of a sick person. It is interesting to note that the use of the ololiuhqui, or toloatzin, as it was also called (Datura meteloides) , still prevails among the Zuni Indians of New Mexico, the Pai-Utes, and several tribes of southern California in certain religious and ceremonial practices, especially in initiating youths into the status proceedings: anthropological society 49 of manhood. The peyotl, or teonanacatl, called by Bancroft the "flesh of the gods," was used by the Aztecs in nocturnal feasts, very much as it is still used by Indians of the Mexican Sierra Madre and by certain tribes of the United States, who believe the visions induced by it to be supernatural. In ancient times a supply of this little narcotic plant was obtained by runners especially consecrated for the purpose, and its gathering was attended by a most formal ceremony. At the present day it is sent from the locality where it grows, along the Rio Grande, by means of parcel post. Lastly, the ceremonial and religious use of picietl, or tobacco, goes back to remote antiquity. No other narcotic plant, perhaps, has become so widely spread or so generally used and beloved by its votaries. Though of subtropical origin its cultivation had extended before the Discovery as far north as the St. Lawrence River. Beautiful pipes of many forms, representing birds, mammals, human heads, etc. have been discovered in Indian mounds near the native city of the speaker, Chillicothe, Ross County, Ohio; and more recently in Scioto county farther to the south. In addition to the aboye plants may be mentioned a certain small scarlet bean, the seed of Sophora secuncl /flora, endemic in northern Mexico and southern Texas. This also has narcotic properties, and was so much sought after by certain tribes of Indians that they have been known to exchange a pony for a string of the beans 6 feet in length. In one of the secret societies of the Iowa Indians this bean is used in the initiating ceremonial ; the beans are carried as charms or amulets by the members of the society, just as in western Mexico fragments of the peyotl, and in southern California parts of the Datura, are carried by their votaries, who believe them to be efficacious against danger and to bring good luck in hunting and war. It is interesting to note a similar practice in the Old World of carrying the root of Mandragora (or a substitute for it) as an amulet ; but most interesting of all is the similarity between the beliefs and practices of the inhabitants of the Old World and the New, in connection with narcotic and other plants held to possess magic properties. The lantern slides used to illustrate the lecture were photographs of the various magic plants discussed. This paper was discussed by Mr. James Mooney, who for a number of years has given special study to the subject of peyotl. Mr. Mooney defended those who are devoted to the peyotl ceremony and claimed that, in most cases, the assertions made against the plant and its users are based upon ignorance of the facts and are without foundation. The 502nd meeting of the Society was held at the New National Museum on Tuesday afternoon, November 21, 1916, at 4.30 o'clock. Mr. Neil M. Judd, of the U. S. National Museum, presented a paper on New types of Pueblo ruins found in western Utah, illustrating his paper with chalk drawings. Mr. Judd described a recent archeological reconnaissance of western Utah conducted under the auspices of the Bureau of American Eth- nology, stating that this resulted in the discovery of two types of pre- 50 proceedings: anthropological society historic habitations not previously reported from the Southwest. The first of these was circular in form and was made by leaning logs against cross-pieces supported by four uprights which surrounded a central fire-place. Willows, grass, and clay, in succession, covered the logs. Houses of the second type, occurring usually in groups forming vil- lages, were rectangular in shape and constructed entirely of adobe. A small series of unattached cliff-dwellings, exhibiting certain features common both to structures of this second type and to stone-walled houses south and east of the Rio Colorado, was also described. A careful study of the lesser artifacts recovered from both types of western Utah ruins indicates a close cultural relationship between their respective builders and the inhabitants of prehistoric structures in other sections of the Southwest. In a discussion of the paper Dr. J. W. Fewkes called attention to the desirability of a more accurate definition of what archeologists mean by a "pueblo." He pointed out that the term is sometimes used loosely to include all lands of ruined stone buildings in the Southwest. Inasmuch as the pueblo culture area owes its name to characteristic buildings or pueblos, he suggested that the term be limited to terraced, congested community buildings with ceremonial rooms or kivas. If this suggestion were accepted by archeologists, many ruins on the periphery of the so-called Pueblo area would have to be classified as belonging to a prepuebloan phase, or not regarded as pueblos at all. The 503rd meeting of the Society was held in the Lecture Hall of the Public Library on Tuesday evening, December 5, 1916, at 8 o'clock. At this meeting Prof. W. H. Holmes, of the U. S. National Museum, delivered an address on Outlines of American aboriginal history, illus- trated with lantern slides. Introducing his subject, Professor Holmes said it is agreed that the human race is a unit, and that it follows, therefore, that there was but one cradle and that man spread from this over the world. The early chapters of human history must always remain obscure, although evidence has been found carrying the story far back into the remote past. It was the purpose of the speaker to Indicate briefly the prob- able course taken bjr the human race in spreading from the Asiatic cradle to the New World, and also to indicate the causes and course of cultural development in the various centers of American occupancy and to suggest the causes of decline. The earliest known traces of man (or man-like being) have been found on the island of Java. In the nature of things, it was a long- time before he wandered far from his primeval home. He had to acquire the arts of the hunter and fisher before he could reach the far north and it was doubtless by way of Bering Strait that he reached the New World. Portraits were shown of the various peoples whose ancestors may have been concerned in these ancient migrations — natives of Tibet, China, and Siberia, the Eskimo, the Sioux, the Zuni, and other typical American Indians; and attention was directed to the proceedings: anthropological society 51 practical identity of these types. Referring to the development of culture in America it was shown that no culture above the hunter- fisher stage ever passed through the Bering gateway. All culture of higher grade is. therefore, American. As the early immigrants reached the more favorable localities of the continent, they engaged in agricul- ture and became sedentary. This condition led to the development of the simple arts, industries, and institutions belonging to this phase of progress. It was asked, How then do we account for the vast works in the way of temples, pyramids, and tombs, and the vast body of products of the sculptor's art, of highly embellished pottery, textiles, and metallurgy? It was shown that all were due to the dynamic forces of religion manifested through the all-powerful shamanistic classes, who sought above all things to honor the gods and to glorify themselves. But, it was asked, Why are the once splendid cities now in ruin? The reasons are readily found: The energies of the people were broken down by the ever increasing load of super-essential activi- ties. The system which permitted over-growth of these highest mani- festations of culture had within itself the germs of disaster. Numerous slides illustrating various wonderful products of sculp- tural and architectural genius developed under the absolute control of the Mayan shamanistic priesthood were shown. The paper was discussed by Dr. E. Hewett, of Santa Fe, N. M., Mr. S. G. Morley, of Cambridge, Mass., and Dr. H. J. Spixdex, of Xew York. Dr. Hewett suggested the influence of environment on the cultural development of a race, citing the discovery of metal by the earl}- inhabitants of Europe and its use in making weapons. Air. Morley spoke of the Maya hieroglyphs, and Dr. Spinden discussed the culture which preceded that of the Maya in Central America, traces of the agricultural period remaining in crude figurines, and that of the religious period in effigies of serpents and of grotesque gods. The 504th meeting of the Society was held at the New National Museum, December 19, 1916 at 4.30 p.m. Dr. Truman Michelsox, of the Bureau of American Ethnology, presented a paper entitled Notes on the Peoria Indians. Dr. Michelson said that the Peoria Indians have practically lost their ethnology, in the strictest sense of the word, although their lan- guage and folklore still remain. A study of these shows very clearly that the Peoria Indians have had two associations, the older and more intimate association being with the Ojibwa group of central Algonkins and the more recent with the Sauk, Fox, and Kickapoo. The terms of relationship support this view, as do the historical facts. The speaker then showed by means of a blackboard chart the system of consanguinity among the Peoria. In this way it was demonstrated that two factors were involved, i.e., the gentile organization and blood consanguinity. The paper was followed by a general and interesting discussion. Prof. W. H. Holmes mentioned the old quarries in northeastern Okla- 52 proceedings: anthropological society homa, near the present location of the Peoria Indians, and Dr. Ales Hrdlicka noted the importance of definite recording of the geographic distribution of Indian tribes. In reply to a question by Mr. F. W. Hodge the speaker expressed the opinion that archeological research would throw light on the early material culture of the Peoria. Dr. J. R. S wanton noted that the Indians of the Northwest coast have a myth similar to one related by the speaker, in which bones thrown into the water are said to "come to life." In the legend of the coast Indians the bones are those of a salmon, while among the Peoria the bones are those of a beaver. In response Dr. Michelson stated that the form of this legend which mentions the beaver is limited to a small area. Frances Densmore, Secretary. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII FEBRUARY 4, 1917 No. 3 PHYSICS. — Standard substances for the calibration of viscometers.1 Eugene C. Bingham and Richard F. Jackson, Bureau of Standards. (Communicated by C. W. Waidner.) For the calibration of viscometers there is a need for one or more liquids which can be easily obtained in pure condition, and which have viscosities that are greater than that of water and that are known with a considerable degree of certainty. The substances selected are mixtures of ethyl alcohol and water, and sucrose and water. Previous work upon water and alcohol being adequate, the present experiments were confined to sucrose and water. The sucrose was purified by repeated recrystalli- zation from water solution, and contained residual impurities of the order of one-thousandth of a per cent. The compositions of the solutions used in the measurements were determined by density measurements and by polariscopic tests. The viscometer used in the investigation consisted essentially of a U-tube fitted with a capillary limb surmounted by a bulb with constrictions. The bulb served as a measure of the volume of liquid forced through the capillary. A bulb of similar size and shape was sealed on the other limb. The viscometer was connected to a manometer and an apparatus for the application 1 To appear in detail as Bureau of Standards Scientific Paper No. 298. 53 54 BINGHAM AND JACKSON: VISCOSITY STANDARDS of pressure. From the observations the viscosity was calculated by the usual formula: V = Cpr-C T in which rj is the viscosity, p applied pressure, p density of liquid, t time of flow, C and C constants abbreviated from the complete viscosity formula. C was found by direct calculation, C by measuring the time of flow of pure water at 20°C. The viscosity of water at 20°C. was taken as 0.01005. The viscosity was measured at a variety of applied pressures. To obtain the true effective pressure, the height of liquid in the manometer was corrected for air buoyancy, column of connecting air, and hydrostatic head of the liquid undergoing measurement. In order to be certain that the drainage of the solution was complete, both the time of flow required to empty and that to fill the bulb were measured. Furthermore, the viscosity was found to be independent of applied pressure. To test the cal- culations and corrections the viscosity of water was measured over a considerable range of pressures. The value was found to be constant. In order to avoid the arbitrary scales of commercial viscom- eters and the inconvenient magnitudes of the absolute units, we suggest the use of the "centipoise" as a unit of viscosity. This is the one-hundredth part of the c.g.s. absolute unit. The cen- tipoise is almost exactly the viscosity of water at 20°C. (0.01005) and, hence, is at the same time the specific viscosity of any sub- stance referred to water at very near 20 °C. The existing data for the viscosity of water have been reviewed in order to obtain a value as far as possible in accord with our present knowledge. The mean value expressed as fluidity is given by the formula : = 2.1482 {{t - 8.435) + V8078.4 + (t - 8.435)2 } - 120 in which 0 is the fluidity, and t the centigrade temperature. The fluidities of mixtures of ethyl alcohol and water expressed as functions of the temperature, and of the weight and volume percentage of alcohol, will be given in the detailed paper. sosman: problems of the oxides of iron 55 The viscosity of a 39.99 per cent sucrose solution was meas- ured at temperatures varying from 0°C. to 95°C. The observed values correspond to the formula : t = 0.597 0 + 20) - ]^^ + 38.24 0 + 20 On repeating these measurements practically the same values were obtained. Measurements were made with 20.007 per cent and 59.96 per cent sucrose solutions also. The fluidities at the latter con- centration correspond to the formula: t = 1.472 (^ + 5) - ®®2 + 58.62 0 + 5 The values found in the present investigation indicate a higher viscosity than those of previous investigators. CHEMISTRY. — Some problems of the oxides of iron.1 Robert B. Sosman, Geophysical Laboratory. Starting with the general principle that the soundest prog- ress in science is made by proceeding from that which is simple and understandable to that which is more complex and less understandable, various investigators have sought to unravel the complexities of natural rocks and minerals by studying first their simplest constituents. Since it appears that under most rock-forming conditions silica (Si02), alumina (A1203), lime (CaO), and magnesia (MgO) always act as units, these oxides may be taken as the pure components in the fundamental experiments. With the oxides of iron the case is different. The equilibrium between ferrous and ferric iron in a mineral or rock can vary with every change of temperature and with every change in the amount or pressure of available oxygen. In order to under- 1 Presidential address, Chemical Society of Washington, January 11, 1917. Presented before a joint meeting of the Chemical Society and the Washington Academy of Sciences. 56 sosman: problems of the oxides of iron stand ferrous silicate and the minerals in which it occurs, there- fore, we must go back one step further ; and study the system iron-oxygen. THE PHASE-RULE DIAGRAM OF THE SYSTEM IRON-OXYGEN The logical point at which to begin a survey of the pressure- temperature-concentration relations in the two-component sys- tem iron-oxygen is with the pure component iron. We have learned a great deal in recent years about the properties of pure metallic iron, although the difficulty of preparing the metal quite free from its usual impurities of carbon, hydrogen, sulphur, phosphorus, manganese, and silicon, has delayed the determi- nation of its elementary constants. But when we add oxygen, the second component, to the sys- tem we come into a little-known region which extends as far as the compound Fe304. The solubility of oxygen in solid iron is certainly not large, but has not been accurately determined. Austin2 states that the oxygen found by analysis of iron bars does not exceed 0.29 per cent, and that the most of this seems to be in the form of oxide films in mechanical admixture. Pick- ard3 concludes from his analyses that 0.092 per cent of oxygen is soluble in liquid iron as FeO, although a part of this may sep- arate out on the solidification of the metal. It is thus evident that there is no extensive solid solution of oxygen in iron. But the small quantity that is present has a very large influence, especially on the magnetic properties of the metal, as appears from the work of Yensen.4 The next question is, what is the lowest oxide in equilibrium with metallic iron? Ferrous oxide, FeO, has been generally assumed to be the oxide lowest in oxygen, but the data concern- ing it are far from satisfactory. Various methods for preparing FeO are found in chemical literature. Mr. Hostetter and I have tried several of these, and our experience has invariably 2 Engineering, 100: 455. 1915. 3 Iron Age- 98: 184-186. 1916. * Yensen, T. D. Univ. Illinois, Eng. Exp. Station, Bulls. 72, 77, 83. 1914- 1916. sosman: problems of the oxides of iron 57 been that the product was a mixture of iron (or iron carbide) with magnetite or with some oxide intermediate in composition between FeO and Fe304. The best work on FeO has been that done by Hilpert, and his conclusion, likewise, is that the vari- ous methods commonly cited do not yield FeO, although the product sometimes has an average composition nearly equiv- alent to the composition FeO. Hilpert and Beyer5 found that by reduction of Fe203 by hydro- gen saturated with water vapor they could obtain products which were richer in ferrous iron than Fe304, but which con- tained no metallic iron. The higher the temperature of reduc- tion, the higher the percentage of "FeO." A product containing only 1.5 per cent of Fe203 was obtained by reduction at 1100°; at 700° the upper limit was 85 per cent of FeO. The reaction velocity is so slow, as equilibrium is approached, that it is difficult to say what the final solid phases would be. Hilpert believes that solid solutions exist between Fe304 and FeO, perhaps with limited miscibility, or even with intermediate compounds. We can find a possible explanation of the case of FeO by ref- erence to the somewhat analogous oxides of two other metals of the eighth group, namely, platinum and iridium.6 The evi- dence indicates that the oxide IrO, within a certain range of temperature, has a higher dissociation pressure than the oxide Ir02; hence IrO will spontaneously change into a mixture of Ir02 and metallic iridium, according to the reaction: 2IrO = Ir02 + Ir Thus, if FeO happens, over some particular range of tempera- ture, to have a higher dissociation pressure than Fe304, it is possible for the following reaction to occur: 4FeO = Fe304 + Fe The existence of such a relation would explain many of the ex- perimental results already obtained, such as the fact that, in 5 Hilpert, S., and Beyer. J. Ber. deu. chem. Ges., 44: 1608-1619. 1911. 6 Wohler and Witzmann. Zs. Elektrochem., 14: 97-107. 1908. Wohler and Frey. Ibid.,. 15: 129-142. 1909. A solid solution of Ir02with IrO or Ir forms, rather than the pure oxide Ir02. 58 sosman: problems of the oxides of iron our experience, powdered iron heated in oxygen at low pressures always yields a mixture of a black magnetic oxide (perhaps a solution of FeO in Fe304) and metallic iron. The facts are so few, however, that this explanation is not to be considered as more than a suggestion. There is one interesting geological application of this relation, if it should be found to exist. Many basic rocks, such as dia- base and gabbro, contain metallic iron. The best known occur- rence is probably that in Greenland, but other examples exist in all parts of the world. If our supposed oxygen-pressure relationship still holds when the oxides are dissolved in a silicate magma, the following reaction would occur: 4FeSi03 (in complex silicate^FesCX + Fe + Si02 (in complex silicate) At constant temperature, increasing pressure would drive this reaction in the direction of diminishing volume. The formation of FeO from Fe and Fe304 is accompanied by a con- traction of volume, according to Hilpert's data, and it appears not unlikely, therefore, that release of pressure in a rising column of molten diabase might alone account for the occurrence of metallic iron in the resulting rock, without the need of recourse to reducing agents such as entrapped organic deposits or dis- solved reducing gases. This problem calls for the measurement of dissociation pressures and specific volumes of the oxides and silicates concerned, in the region 900°-1300? The same reaction might conceivably be made a basis for a commercial method of making pure iron, free from the usual impurities which come from the use of coke as a reducing agent. Continuing our survey in the direction of increasing content of oxygen, we come to the compound ferrosoferric oxide, magne- tite (Fe304). Its melting point is 1580°, and it melts sharply to a mobile liquid which crystallizes in octahedra on cooling. Its dissociation pressure is extremely low, being less than 0.04 mm. of mercury at 1200°, and less than 0.005 mm. at 1100? Further addition of oxygen brings us into the region between Fe304 and Fe203, a region which we have recently investigated sosman: problems of the oxides of iron 59 at 1100° and 1200? These two oxides seem to form a continu- ous series of solid solutions from Fe203 to Fe304, or at least to a point so near Fe304 that it has not been possible to detect a break in the dissociation pressure curves.7 The melting temperatures (solidus and liquidus curves) of the series Fe203-Fe304 have not yet been determined. The dissociation pressure rises so rapidly with increase of temperature that at the melting temperature of the solid solution the pres- sure of oxygen will probably be found to be of the order of several atmospheres for compositions which depart much from Fe304. The melting point of Fe203 can be determined only under sufficient oxygen pressure to prevent its dissociation, and it is impossible to predict whether the melting point will be higher or lower than that of magnetite. The form of the liquidus and solidus curves (continuous, minimum, or maximum) can also not be predicted. The form of these curves is of particular interest in connection with the effect of changing oxygen pres- sure. At a given temperature it is possible that increasing the oxygen pressure might cause either fusion or solidification of the oxide, or even fusion followed by solidification, depending upon the form of the curves. The type of solid solution represented by these two oxides of iron deserves a moment's consideration. The special feature of this case is that the two constituents of the solution differ only in the proportion of volatile component which is combined with the non-volatile component. In other words one of the constituent oxides of the solid solution is produced by direct dissociation of oxygen from the other oxide. The case of Fe203-Fe304 is thus exactly analogous to the case of CoCl2.6NH3-CoCl2.2NH3, in that we may consider Fe as replaced by CoCl2 and O by NH3. The system just referred to has been studied by Biltz and Fetkenheuer,8 who find a continuous series of solid solutions, throughout which the NH3 pressure falls continuously, following a reversed curve of the same form as that shown by the iron oxides. 7 Sosman and Hostetter. Jour. Am. Chem. Soc, 38: 807-833. 1916. 8 Biltz and Fetkexhetjer. Zs. anorg. Chem., 89: 106. 1914. 60 sosman: problems of the oxides of ieon Several interesting problems are raised by the consideration of this type of solid solution. In the first place how are we to picture to ourselves its internal structure? The X-ray analysis of crystal structure is so radically altering our conceptions of the make-up of solid substances that our ideas of solid solutions have not yet become adjusted to the new facts. When it was dis- covered that certain properties of a solute in dilute aqueous solution made the solute seem quite analogous to a gas, and when it was discovered that solid solutions existed which seemed quite analogous to liquid solutions, we felt secure for a time in this extension of molecular theory from gases over into liquids and solids. The facts now need re-interpreting, but the greatest need is for more facts on the crystalline structure of solid solutions. Another problem raised by a consideration of the hematite- magnetite series is that of the continuous transition from one crystal class into another. According to the original conception of isomorphism, two compounds could enter into solid solution only if they crystallized in the same system. Now hematite is hexagonal* while magnetite is isometric; is a continuous series from one of these systems to the other possible? To say that there is a hexagonal form of magnetite, which is the form that dissolves in hematite, is merely to dodge the issue; such a state- ment becomes a meaningless form of words if the experimental consequences remain the same whether the supposed second form exists or not. A consideration of the point systems from which the crystal classes can be made up shows that we can in reality get a con- tinuous transition from cubic to hexagonal. Suppose a cubical portion of some cubic lattice to be standing on one of its corners ; then if it be compressed along the vertical diagonal axis it changes into a rhombohedron which becomes flatter with increas- ing compression, and the rhombohedron is a hexagonal form. This transition requires of course that the lattice of the isometric and hexagonal forms be thus transformable, and this can be de- termined for hematite and magnetite only by X-ray studies of their crystals. If it should then be proved that the struc- sosman: problems of the oxides of iron 61 tures of the ordinary forms of hematite and magnetite are not thus transformable, then by geometry alone, without the aid of chemistry, could we predict that there must be a break in the solid-solution series between these two oxides? A third problem of the hematite-magnetite series concerns the escaping tendency or fugacity of the oxygen which dis- sociates from the oxide. What determines the equilibrium pres- sure of this oxygen for a given composition of the solid solution? It is interesting to note the peculiar form of the oxygen pressure curve in this series. The middle portion is fairly flat, and the pressure changes slowly with change of composition. As the composition of magnetite is approached, however, the pressure begins to fall rapidly, and, conversely, it rises rapidly as the composition Fe203 is approached. We have been able to show9 that the dissociation pressure of the first small portion of oxygen from pure Fe203 at 1200° is of the order of magnitude of an atmosphere of oxygen, although the pressure rapidly falls to a few millimeters as dissociation progresses. From a theoretical standpoint there are two ways of looking upon this form of dissociation curve. On the one hand, we may consider that the curve is asymptotic to the axis of ordinates; in other words, the initial composition of the crystal corresponds exactly to the formula Fe203, and the dissociation pressure of the first few atoms of oxygen is very high. These atoms come from all parts of the crystal, and their removal brings into play forces which greatly restrain the fugacity of all the remaining oxygen atoms, causing a rapid fall in the dissociation pressure. On the other hand, we may consider, as Langmuir10 and others have shown, that there are free chemical forces at the surface of the crystal, and that these forces hold atoms of oxygen "ad- sorbed" on the surface when the crystal is exposed to air. The initial composition then is Fe203+*; in which x is a very small number. The fugacity of these surface atoms is high, but not much higher than that of oxygen atoms just within the surface. Oxygen will begin dissociating from interior parts of the crystal, 9 Hostetter and Sosman. Jour. Am Chem. Soc, 38: 1188-1198. 1916. 10 Langmuir, I. Jour. Am. Chem. Soc, 38: 2221-2295. 1916. 62 sosman: problems of the oxides of iron therefore, before all the adsorbed oxygen is removed from the surface. Mathematically speaking, we may say that the dis- sociation pressure curve is not asymptotic to the axis of ordinates, drawn at the composition Fe203, but crosses this axis at a small angle. This second conception of the case gives, I believe, the better interpretation of the facts. MAGNETIC PROPERTIES AND POLYMORPHISM OF THE OXIDES The problems so far considered are all problems which are common to nearly all the chemical elements and their compounds. But there is one field of physics in which iron holds at present the first place in interest, namely, the field of magnetism. Progress in the experimental study of magnetic properties has lagged behind experimental progress in electricity, chiefly because we possess no magnetic insulator. As has been well stated by Mr. Sanford at a recent meeting of the Philosophical Society of Washington, "Measuring magnetic properties is like measuring electrical resistance with the Wheatstone bridge and all the connections immersed in a conducting liquid." Nevertheless, rapid progress is now being made on several lines of magnetic research. The oxides of iron have been, from this standpoint, rather neglected. Measurements will be found here and there in con- nection with studies of the salts of iron, crystalline or dissolved. From these it is clear that the oxides are not to be classed mag- netically with the majority of the iron compounds. Ferric oxide is abnormally low in susceptibility, in comparison with the common salts of iron. Ferrosoferric oxide, on the other hand, belongs, as is well known, among the highly ferromagnetic substances. Ferrous oxide, again, seems to be in a class with ferric oxide. Intermediate oxides possessing a variety of com- binations of magnetic properties also exist. The inversions in ferric oxide first attract our attention. Honda11 has found that at liquid air temperatures ferric oxide has only about two-thirds as great a susceptibility as at room temperature,1 and that a change occurs rather suddenly in the 11 Honda, K., and Sone, T. Sci. Rep. Tohoku (Sendai), 3: 223-234. 1914. sosman: problems of the oxides of iron 63 neighborhood of -40? The susceptibility rises to a maxi- mum at about 600°, and then falls rapidly to about half value at 690°, where the curve changes direction practically by a right angle, the susceptibility being nearly constant from 690° to 1300? We have confirmed the high temperature inversion, placing it at 678° by means of thermal curves.12 The inversion is sharp and reproducible, and appears on both rising and falling tem- perature curves. The —40° inversion we have not yet investi- gated thermally. Curie13 discovered a similar magnetic inversion in magnetite at about 535? Barton and Williams14 confirmed this inversion, placing it about 545? Weiss and Foex15 placed the inversion at 581°, Wologdine16 at 525? The temperature of the magnetic inversion is undoubtedly influenced by the magnitude of the induction or of the magnetizing force. No thermal study of the inversion has yet been made. The principal precaution to be observed is the avoidance of oxidation of the magnetite by air. Some of the conclusions of Weiss and Foex seem to have been vitiated by a slight oxidation of their artificial magnet- ite, and a faint trace of the 678° point of Fe203 appears on their magnetite curve. The magnetic inversion in pure iron occurs at about 770°, varying somewhat with the magnetizing force to which the iron is subjected. It is found thermally at 768°, and by electrical resistance, at 757? This is the thermal inversion known as A2, whose existence in pure iron free from carbon was seriously questioned some years ago, but which has been established as an independent and characteristic inversion by the excellent work of Burgess and his co-workers at the Bureau of Standards.17 These magnetic inversions, which occur not only in iron, mag- netite, and hematite, but also in various ferrites, are all very 12 Sosman and Hostetter. Jour. Am. Chem. Soc, 38: 831. 1916. 13 Curie, P. Ann. chim. phys., 5: 322. 1895. 14 Barton, E. H., and Williams, W. British Assoc. Rep., pp. 657-658. 1892. 15 Weiss, P., and Foex, G. Arch. sci. phys. (Geneve), 31 : 5-19, 89-117. 1911. 16 Compt. rend., 148: 776. 1909. 17 Burgess and Crowe. Bull. Bur. Std., 10:315-370. 1914. Burgess and Kellberg. Ibid., 11:457-470. 1914. ' 64 sosman: problems of the oxides of iron similar in the form of their temperature-magnetism curves. In each case the effect of rising temperature appears some dis- tance below the inversion point, and increases more and more rapidly as the inversion is approached. One cannot avoid the conclusion that these inversions all have the same fundamental basis. When that basis is found, we will have considerably advanced our knowledge both of polymorphism and of magnetism. So much has been said about polymorphism (including under this term allotropy, polymerism, and all the other names given to the phenomena of sudden change of physical and chemical properties without change of percentage composition), and so much that has been said is mere quibbling over the meanings of words and phrases, that I shall not undertake any general review of the questions that are raised by the inversions of iron and its oxides. But there is one problem to which considerable attention has lately been given, namely, the problem of the two types of polymorphism in crystalline substances. Polymorphic changes in crystalline solids can be divided roughly, as is well known, into two groups. On the one hand, there are those changes which carry with them rather profound changes in physical and chemical properties and which often require considerable time to bring about. On the other hand are those reversible changes which occur without delay at a given temperature and which involve relatively small changes in crystal form and in physical properties. An excellent example of a substance showing both types distinctly is silica. Si02 occurs in three principal forms, quartz, tridymite, and cristob- alite, which are only slowly transformed one into another, and which have certain ranges of stability outside of which they frequently occur in an unstable but very persistent state. Each of these principal forms, on the other hand, possesses one or two inversion points, at which reversible crystalline changes occur: quartz at 575°; tridymite at 117° and 163°; cristobalite at a temperature varying from 200° to 275°, depending upon the previous history of the crystal.18 11 Fenner, C. N. Am. Jour. Sci., 36: 331-384. 1913. sosman: problems of the oxides of iron 65 Two different views have been held concerning the relation of these two classes of polymorphic inversion, although in our present ignorance of atomic structure neither can be very pre- cisely stated. It has been supposed, on the one hand, that the slow changes were the fundamental ones, involving a rearrange- ment of the atoms in the molecule or a change in the molecular weight, the expression "molecular weight" being considered to have a meaning in the solid as in the gaseous state. The rapid reversible inversions, then, were held to be merely rearrange- ments among the molecules, involving slight changes in the crystalline form or symmetry. But on the other hand we may consider the rapid reversible inversions as the fundamental ones, possibly occurring even with- in the atomic nucleus itself, and thereby necessarily producing some corresponding change in the spacing of the atoms. The slow and sometimes irreversible changes would then be the less fundamental, involving only a re-grouping of atoms or atom complexes. The second of these two views seems to me to be supported by the phenomena of polymorphism of the oxides of iron. It is obvious that the change can not be one that occurs in the iron atom independently of its chemical environment, for the mag- netic inversion occurs at different temperatures in the different oxides and carbides. Furthermore, corresponding inversions are yet to be found in various other compounds of iron. But there is one oxide of iron which I have not yet touched upon, whose properties shed considerable additional light on the prob- lem. I refer to the magnetic ferric oxide which was discovered by Robbins19 in 1859, was almost forgotten until recently studied by Hilpert, co and on which we are now engaged in further ex- periments. 19 Robbixs, J. Chem. News, 1: 11-12. 1859. Its discovery has usually been ascribed to Malaguti, F. Compt. rend., 55: 350-352. 1862. 20 Hilpert, S. Ber. deu. phys. Ges., 11: 293-299. 1909. Hilpert's rather dis- appointing conclusion from his excellent experiments is that "Fc4).-s functioning as an acid is the carrier of magnetism." But what is "Fei03 functioning as an acid" in a compound whose total composition is expressed by the formula Fe203? Furthermore, as Hilpert himself recognizes, not all "ferrites," in which Fe203 is assumed to be the acidic oxide, are ferromagnetic. 66 sosman: problems of the oxides of iron If precipitated magnetite is oxidized by ammonium persul- fate, or even by atmospheric air at a low temperature, the prod- uct, although it contains almost no ferrous iron and is reddish brown in color, is practically as magnetic as magnetite itself. If this magnetic oxide is heated to 750° for a few minutes, its highly magnetic character is lost, and it becomes like ordinary ferric oxide. What is still more remarkable is that the magnetic Fe203 has a Curie inversion just above 500°, similar to that of magnetite. Here, then, we have as fundamental a chemical change as it is possible to get — no mere polymerism, but a change in the formula weight with a reduction of the ferrous iron content from 33| per cent to zero; yet the magnetic susceptibility and inversion point remain the same. Except for the color, it is as if we had merely ground up the magnetite and mixed it with powdered solid oxygen. A consideration of the preceding facts concerning the inversions of iron and its compounds, and especially of the interesting properties of the magnetic form of Fe203, suggest that the mag- netic properties and the inversions of iron and its compounds are bound up with the spacing and arrangement of the iron atoms, almost without regard to the other atoms present.21 What is this structure of the iron atoms which produces the high permeability, and what is the nature of the intra-atomic change at the inversion point? These problems are on the way to a solution, for Hull has recently found by means of X-ray spectra that the lattice of metallic iron is the centered cube.22 He discovered also that this structure seems to remain unchanged through both the 21 This has been suggested for the Heusler alloys: Take. Faraday Soc. Trans., 8: 177. 1912. Professor Pupin, speaking in the recent symposium on the structure of matter, at the American Association meeting in New York, December 27, 1916, stated that he had come to the conclusion from the magnetic properties of very pure iron that its magnetism is intimately related to its crystalline structure. On the other hand, as Hilpert points out, precipitated oxides that are apparently amorphous and that pass readily into colloidal solu- tion can be made, which are magnetic and possess magnetic inversions. Have the particles of these colloids a microcrystalline structure, as yet unrecognized? 22 Paper presented at the Cleveland meeting of the American Physical Society, November, 1916. sosman: problems of the oxides of iron 67 A2 and the A3 inversions, further confirming the view expressed above, that these inversions are intra-atomic. Further light could be obtained on the problem by a comparison of the struc- tures of the magnetic and the non-magnetic forms of Fe203. This apparent dependence of magnetic properties upon the arrangement of the iron atoms in space opens up interesting possibilities. If magnetite can be oxidized to ferric oxide without loss of its magnetism, it may be possible to convert it into other compounds, or even to convert metallic iron into compounds of iron, in which the arrangement of iron atoms will remain un- disturbed. A highly magnetic compound of iron with a high electrical resistance, for example, might possess industrial as well as academic interest. Having barely touched upon some of the problems in chemistry and physics that are raised or partially solved by the study of the oxides of iron, I wish to devote the little time that remains at my disposal to the consideration of a few of the geological problems connected with these oxides. THE OXIDES OF IRON AS RELATED TO CERTAIN GEOLOGICAL PROBLEMS The oxides of iron rank high among the earth's important minerals, since metallic iron is manufactured almost exclusively from oxide ores.23 Questions of genesis of the ores of iron there- fore furnish topics of perennial interest to the economic geologist. The widespread occurrence of these ores makes them also of interest to the student of historical and structural geology. At the present time the so-called magmatic and pneumatolytic ores are attracting the most attention from a scientific standpoint, though economically they are secondary in importance to the sedimentary and residual ores. The magmatic-pneumatolytic ores range in composition all the way from magnetite to hematite. Two different modes of origin account for them. Certain large magnetite deposits are claimed to have been deposited in the lower portion of large igneous masses by gravitative settling of magnetite crystals while the mass was still molten. This 23 Carbonate ore formed only 0.006 per cent of the production in the United States in 1915. (E. F. Burchard.) 68 sosman: peoblems of the oxides of iron is the explanation offered for many of the deposits of titaniferous magnetite, such as the Ramsoy deposits of Norway.24 It has also been suggested that the magnetite may have separated by gravity as a liquid or partly liquid layer while the entire magma was still molten.25 These explanations based on magmatic differentiation have met with various difficulties, geological as well as chemical and physical. The separation of a liquid layer of pure magnetite, for instance, is hardly believable, since the melting point of magnetite is 1580°, whereas the intruding rock bodies from which it separated could hardly have been at a temperature of more than 1000? Whether small quantities of other substances might greatly lower the melting temperature of magnetite is one of the problems yet to be solved experimentally. The other mode of origin assumes that the iron was carried in the hot solution or vapor given off by an intruding igneous mass. There are many deposits for which this mode of origin seems well established. Examples of these are the magnetite deposits of Cornwall, Pennsylvania,26 and the hematite-magnetite ores of the Island of Elba.27 An interesting feature of the latter, which we discovered in the course of some magnetic measurements, is the zonal de- velopment of certain crystals.28 The hematite crystals from Elba are well known for their large size and excellent devel- opment. They are not pure Fe203, however, but contain a considerable percentage of ferrous iron. By chemical analysis and by magnetic measurements we have shown that the ferrous iron is zonally distributed, being higher in the core and base of the crystal and lower in its outer surface and free-growing tip. Evidently, the temperature or oxygen concentration, or both, were changing continuously in one direction while these crystals were being deposited. The reactions that will lead to the deposition of hematite, hematite-magnetite, or pure magnetite from a vapor or a liquid 24 Foslie, S. Norges Geol. Unders., vol. 4, 1914. 25 Daly, R. A. Origin of the iron ores at Kiruna. Vetensk. prakt. Unders. Lappland. Geology, No. 5. 1915. 26 Spencer, A. C. U. S. Geol. Survey, Bull. 359. 1908. 27 Lotti, B. Mem. descr. carta geol. Italia, II. 1S86. 28 Jour. Wash. Acad. Sci., 6: 309. 1916. sosman: problems of the oxides of iron 69 solution are yet to be investigated. It is not certain, even, what compounds of iron were originally present. The natural sus- spicion is that the iron was present as chlorides or fluorides, since these compounds are known to be volatile at comparatively Low temperatures. Many geologists have objected that in some cases the associated rocks show no trace of alteration by pneumatolytic action, or contain little or none of the element supposed to have been combined with the iron. The Kiruna magnetite ore-body of Sweden, for instance, shows sharp con- tacts against unaltered normal prophyries. But in the face of a phenomenon such as that seen at Kilauea, where vast quantities of sulfur and its compounds are given off from the lava lake, Leaving hardly a trace of sulfide of any kind in the solidified lava around the crater, we need not feel discouraged about pro- ceeding with experiments on the deposition of iron oxides from those compounds which are readily volatile and on which the basic data of temperature and concentration, at least, are obtainable. One set of facts regarding hematite deposits of the magmatic- pneumatolytic type is to be noted at this point, namely, their magnetic properties and their content of ferrous iron. We have found by some preliminary, as yet unpublished, measurements that the force exerted upon a solid solution of Fe304 in Fe203 by a non-uniform magnetic field is roughly proportional to the percentage of FeO. This holds true for both artificial and natural oxides, including even some martites high in ferrous iron. On the other hand, oxides containing ferrous iron (perhaps as carbonate or as other compounds), but in which the FeO is not in solid solution, such as the limonite from Mt. Ktaadn, Maine, have a much lower susceptibility than the corresponding solid solution. Again, an oxide formed by the oxidation of precipitated mag- netite, as has been mentioned above, may have a very high susceptibility, although the percentage of FeO may be very small. We have examined one such oxide found by Messrs. Graton and Butler in a gossan deposit. Hilpert reports that examples have been found in Europe in association with carbonate ores which ^ 70 sosman: problems of the oxides of iron are undergoing oxidation. The usual "magnetic hematite/' how- ever, owes its magnetic properties to its ferrous iron content. A simple magnetic test, then, combined with a determination of the ferrous iron, permits certain preliminary conclusions as to the origin of many natural oxides of iron. But there are other magnetic properties which we have not yet touched upon, which may be expected to vary with the composition and constitution of the oxide, such as the remanence and the coercive force, and especially the variation of the magnetic properties with tempera- ture. This correlation of magnetic, physical, and chemical proper- ties is not a small task, but it is one for which the apparatus and methods are now in good working order. The remanence, or permanent magnetization, offers particular interest. It is well known that magnetite crystals are frequently found which are very strong permanent magnets; in fact the history of magnetism dates from the discovery of these "lode- stones" by the ancients. Yet most natural magnetite is not polarized. What causes have produced the polarization and how are they related to the origin and history of the ore? There is time to touch only in the briefest way on the prob- lems connected with other types of iron ores. The study of replacement ores leads us into the still obscure problem of re- placement as a geological phenomenon, ably discussed by Lind- gren in a recent paper29 but still, unfortunately, the subject of more discussion than experiment. The secondary concen- tration of oxide ores by circulating waters is another problem in chemistry at ordinary temperatures which has not yet received the attention it deserves. Even the origin of ores which are admittedly almost unaltered is still somewhat obscure. The genesis of residual ores such as those of Cuba is not so much a problem of the oxides of iron, since these play rather a passive role, as of the weathering of iron-bearing silicates. But the origin of certain sedimentary deposits is a specific problem in the chemistry of iron, complicated, however, by a new factor, the biological. It has long been known that some of the higher bacteria play a part in the prc- 29 Lindgren. W. The nature of replacement. Econ. Geol., 7:521-535. 1912. sosman: problems of the oxides of iron 71 cipitation of hydrated ferric oxide, and the number of forms which are known to be associated in some way with the precipitation is constantly increasing. It is not yet clear in all cases whether the organism actually brings about the reaction through its own life processes, whether the precipitation is due to the de- composition of the dead organism, or whether the organism acts merely as a nucleus for the collection of agglomerating colloidal oxide. The origin of the immense and very pure iron ores of Minas Geraes, Brazil, is ascribed by Harder and Chamberlin30 to bacterial activity, apparently for the indirect reason that there are objections to any other mode of formation. The reader is left with the uneasy feeling that perhaps only our lack of knowledge prevents our objecting to the bacterial explanation as well. There is one possibility which deserves attention in this con- nection. Experiments with closed tubes show that a compara- tively moderate increase of temperature will hydrolyze various ferric salt solutions, and precipitate ferric oxide, which does not redissolve. These ferric solutions seem relatively unstable and easily hydrolyzed, and the colloidal ferric oxide only needs to be agglomerated to form a precipitate that will settle. Are there any possible variations in the composition, concentration, or temperature of sea water which would cause it to precipitate the ferric oxide from a hydrolyzed, even very dilute, ferric solution in much the same way as the Mississippi silt is precipi- tated by the waters of the Gulf of Mexico? Bacteria, able. and willing to take advantage of the conditions favorable to the reaction, need not be excluded, but, as may be the case with calcium carbonate,31 inorganic causes may be primarily responsible. The intimate association of silica with many ores, amounting even to chemical combination, as in some of the siliceous ores of the Lake Superior region, may represent a simultaneous agglomeration of colloidal silica and ferric oxide, or an adsorp- tion of ferrous and ferric iron by agglomerated silica. It is to be noted, also, that such precipitated colloids can sometimes be ;,° Jour. Geol., 23:385-404. 1915. See Johnston and Williamson. Jour. Geol., 24: 729-750. 1910. 72 sosman: problems of the oxides of iron re-dispersed (peptonized) by pure water, simply through the leaching out of the salts carried down by them from the strong precipitating solution. A method of secondary concentration js thereby suggested. It is evident that from studies in colloid chemistry we may expect considerable advances in our knowl- edge of the sedimentary ores. I have presented a rather varied list of problems, some of which may seem remote from pure chemistry, but I may possibly find an excuse in the fact that this meeting has been held as a joint meeting of the Chemical Society and the Washington Academy of Sciences. As soon as we begin to consider them in detail, we find that the problems of the oxides of iron are but phases of some of the greater problems of chemistry, physics, biology, and geology. And they can not be solved by taking thought about them; new facts, to be yielded by new experi- ments and new observations, are demanded. Nor are the problems as simple as some of them may have appeared from my statement of them. The chemist is amazed by the facile transformations of iron from ferrous to ferric, beholding the two states of oxidation acting like two absolutely different elements. The physicist stands appalled before the spectrum of iron, realizing the many unknown quantities hidden behind its thou- sands upon thousands of lines. Even the layman can get a vivid realization of the complexity of the problems involved; he has but to walk out through the country round about Wash- ington and note the bewildering play of inorganic colors every- where about him, ranging from deep brown-black through various shades of drab, brown, purple, and maroon, and through the many tints of pink, ocher, and rose, to the most brilliant of reds and orange-yellows, and then realize that almost every one of these hundreds of colors is due to an oxide or hydrated oxide of iron; he will begin to realize then that our chemical knowledge of these oxides is almost infinitesimal. One thing only is clear to us, and that is that we are only skirting around the edges of that vast body of knowledge about iron and its oxides which is, as the mining geologist says, "in sight," not to mention the unsuspected problems that lie "in depth," far beyond our farthest plans for research. RICHARDSON: DIFFUSION IN OIL-FIELD WATERS 73 GEOLOGY. — Note on the diffusion of sodium chloride in Appa- lachian oil-field waters.1 G. B. Richardson, Geological Survey. During the summer of 1915, while working in the oil fields of Butler County, Pennsylvania, I became interested in the common occurrence of brines in oil wells. Samples of salt water were collected and an analysis (A) of one was made in the Geo- logical Survey laboratory. This analysis is compared with an- other analysis (B) of deep-seated water from Washington County, Pennsylvania, made by Steiger (see table 1). The wells from TABLE 1 Analyses of Water from Deep Wells in Western Pennsylvania COMPOSITION OF ] DISSOLVED SALTS A B CI 62.29 0.10 None None 27.59 0.10 Trace 8.40 1.47 Trace Trace 0:05 Trace 61.38 so4 0.02 HC03 C03 None Br I 0.26 24.50 K 1.97 Li Ca 9.56 Ms 0.94 Sr 1.31 Ba Trace Fe" 0.06 Fe'" don cent rat ion parts per million 100.00 131,890 100.00 263,640 A. Water from "hundred-foot sand" at depth of 1359 feet, in well on farm of Charles Hoffman, 5 miles northeast of Butler, Pennsylvania. Analysis by W. B. Hicks and R. K. Bailey, U. S. Geological Survey. B. Water from Oriskany sandstone at depth of "6300" (6260?) feet, in well of Peoples Natural Gas Company, 5 miles northwest of McDonald, Pennsylvania. Analysis by George Steiger, U. S. Geological Survey. See U. S. Geol. Survey Water-Supply Paper 364, p. 9, 1914. 1 Published by permission of the Director, U. S. Geological Survey. 74 RICHARDSON: DIFFUSION IN OIL-FIELD WATERS which the samples were taken are about 40 miles apart, and the water-bearing horizons, of Devonian age, are separated stratigraphically about 4500 feet. The history of deep-seated waters of this kind is a subject of debate. In a recent number of Economic Geology I have suggested, as a working hypothesis, that the Appalachian oil- field brines are a mixture of waters originally occluded with the sediments when deposited and of meteoric waters of later origin which have entered the rocks during periods when the region was above sea level ; that these waters have leached great masses of sedimentary beds containing disseminated salt, and that they have undergone a series of changes in composition, the saline matter tending to accumulate because of the slow circu- lation dependent on the synclinal structure of the region. Among other causes of the sodium chloride content of the waters and of the increase of concentration with depth, I sug- gest that diffusion from beds of rock salt may be an impor- tant factor. Such beds in the Salina formation are known to underlie at least part of the Appalachian oil-fields. Thick deposits of rock salt actually occur 600 feet below the horizon in the well from which the water of sample B was obtained, and others may occur. It is worthy of consideration that beds of shale, especially connecting lenses of sandy shale, separating the more porous beds of sandstone in the Appalachian oil-field section may be porous to such an extent that there exists a continuous, though very irregular, network of minute pore spaces connecting the beds of rock salt with the overlying beds in which salt water is found. The deep-seated waters are under great artesian pressure, as shown by the fact that in the well from which the sample represented by analysis B was obtained the water was forced 4000 feet above the horizon where it was encoun- tered in drilling. Such pressure tends to fill with water the pores even of very fine-grained strata, and it seems plausible that in the rocks of the Appalachian oil-fields there are con- tinuous pore spaces occupied by water. If such conditions exist, diffusion must act. RICHARDSON: DIFFUSION IN OIL-FIELD WATERS 75 Table 2, based on a paper by Becker2, was kindly prepared for me by C. E. Van Orstrand. TABLE 2 Migration of Sodium Chloride in Pure Water DISTANCE TIME CONCENTRATION meters years 000 1,000,000 1.00 500 1,000,000 0.06 1000 1,000,000 0.0002 1500 1,000,000 0.00000003 000 10,000,000 1.00 500 10,000,000 0.56 1000 10,000,000 0.24 1500 10,000,000 0.08 000 20,000,000 1.00 500 20,000,000 0.68 1000 20,000,000 0.41 1500 20,000,000 0.21 The concentrations are expressed in terms of the initial con- centration at the plane of contact between a bed of salt and the base of a column of initially pure water. It is assumed that the initial concentration remains constant. The computed concentrations are of course only suggestive, and the figures can not be directly applied to the Appalachian region because initially pure water was assumed in computing the table, whereas the water through which diffusion may have occurred must have been initially saline. Nevertheless, the table is of interest in an attempt to account for the high con- centration of the brine represented by analysis B and for the general increase in concentration of Appalachian oil-field brines with depth. 2 Becker, G. F. Note on computing diffusion. Am. Jour. Sci., 3: 220-226. 1897. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing in this issue. GEOLOGY. — The Gold Log mine, Talladega County, Alabama. E. S. Bastin. U. S. Geological Survey Bulletin 640-1. Pp. 159-161. 1916. The geologic features of a gold mine that has been worked inter- mittently for seventy years near Talladega, Alabama, are described. The country rock is Talladega slate, probably of Lower Cambrian age. The ore consists of (1) irregularly interlocking white to light-gray quartz, white to pale-pink calcite, and very minor amounts of sulphides and free gold, and (2) schist partly replaced by some or all of these minerals. Chalcopyrite is the principal sulphide. Free gold occurs locally in irregular masses in the quartz. The value of the gold and silver recovered is reported to average about $4 to the ton of ore treated. R. W. S. GEOLOGY. — Ozokerite in central Utah. Heath M. Robinson. U. S. Geological Survey Bulletin 641-A. Pp. 1-16, with 1 plate. 1916. The American needs for ozokerite (a substance commonly known as mineral wax) have been largely met in the past by imports from the Galician mines in Austria, but interest in the domestic supply has recently been stimulated. The largest district in the United States in which it has been mined and prospected is an area in central Utah a little more than 12 miles long and from 1 to 4 miles wide between Gilluly and Colton. The rocks of this field have a total thickness of about 4000 feet and were deposited as nonmarine sediments in early Tertiary (Eocene) time. The lower 1000 feet of the beds exposed are known to contain ozokerite, and the remaining 3000 feet contain bituminous or oil shale 76 abstracts: geology 77 interbedded with other rocks. The principal ozokerite mines and prospects have been opened in the Wasatch formation and are scattered irregularly through a stratigraphic distance of 600 to 700 feet. The ozokerite fills cavities that have resulted from fracturing. The com- position, properties, origin, and uses of ozokerite are discussed, and the mines and prospects are described. R. W. S. GEOLOGY. — The oil and gas geology of the Foraker quadrangle, Osage County, Oklahoma. K. C. Heald. U. S. Geological Survey Bulletin 641-B. Pp. i-iv, 17-47, with 2 plates and 11 figures. 1916. This paper describes and portrays those features of the Foraker quadrangle that may be of interest and assistance in the discovery and development of accumulations of oil and gas. Under the heading "Stratigraphy" those strata valuable as key horizons in mapping structure are described in detail, and the probable positions of oil sands are given. The geologic structure is portrayed by map and stereogram, and the anticlines believed to be favorable for the accumula- tion of oil and gas are described in detail. In conclusion specific recommendations for prospecting are given, and the writer's belief concerning the probability of the occurrence of oil and gas accumulations is set forth. R. W. S. GEOLOGY. — Possibilities of oil and gas in north-central Montana. Eugene Stebinger. U. S. Geological Survey Bulletin 641-C. Pp. 49-91, with 4 plates. 1916. The thick bodies of Upper Cretaceous shale with which most of the oil and gas in both Wyoming and Alberta are associated are known to be continuous between these two localities under the plains of Montana, making it apparent that favorable structural features, especially anticlines and domes similar to those that are productive in Wyoming and Alberta, offer a chance of success with the drill in this part of Mon- tana. The facts observed appear to warrant the conclusions that a considerable gas territory, comparable in extent to the Alberta fields, may be found, and that the area shows some probability of yielding oil. The character and distribution of the sedimentary rocks, particularly those of importance in the search for oil and gas, are discussed, and the geologic structure of north-central Montana is described. Particular attention is paid to the structural features of the area of tilted and faulted rocks north and south of the Bearpaw Mountains. R. W. S. 78 abstracts: geology GEOLOGY. — Molybdenite and nickel ore in San Diego County, Cali- fornia. F. C. Calkins. U. S. Geological Survey Bulletin 640-D. Pp. 73-82. 1916. Molybdenite has been reported to occur at several places in San Diego County. The deposit near Ramona, which has attracted most attention, was visited in December, 1915. The molybdenite at this locality is unevenly disseminated in an aplite dike which cuts granite, the principal rock of the region. The deposit has not been shown to have commercial value, though further development and prospecting seem to be warranted. A nickel prospect, the Friday mine, near Julian, was also visited. The nickeliferous deposit, which has been explored to a depth of 200 or 300 feet, lies at an irregular contact between mica schist and gabbro. It consists mainly of pyrrhotite, but contains pyrite, chalcopyrite, and an iron-nickel sulphide, probably polydymite. Both in constitution and mode of occurrence it resembles the Sudbury deposits and is pre- sumably similar in origin. The sulphides are high enough in nickel to constitute ore, provided a fairly large body of them can be uncovered. F. C. C. GEOLOGY.- — Gypsum in the southern part of the Bighorn Mountains, Wyoming. Charles T. Lupton and D. Dale Condit. U. S. Geological Survey Bulletin 640-H. Pp. 139-157, with 3 plates. 1916. Gypsum has been known to occur in a belt of rocks surrounding the Bighorn and Owl Creek mountains, Wyoming, from the early days of exploration. The amount of this material at several places is great, but owing to the slight demand for it little attention has been given to its utilization until the last few years. The gypsum occurs at two horizons — the upper at or near the top of the Chugwater formation, or Red Beds, and the other in the upper part of the Embar formation. Only the upper bed, however, is of economic importance at Sheep Mountain and in the vicinity of Thermopolis. The rocks exposed in the region described in this report range in age from pre-Cambrian to Quaternary. The Embar and Chugwater formations, winch contain the gypsum beds, are described in detail. R. W. S. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE PHILOSOPHICAL SOCIETY OF WASHINGTON The 781st meeting was held on January 6, 1917, at the Cosmos Club. Vice-President Sosman in the chair; 37 persons present. The minutes of the 779th meeting were read in abstract and approved. Mr. E. Buckingham gave a paper on The effect of elastic strain on the equilibrium temperature of a solid and its liquid. By methods not in- volving any reference to the details of the theory of elasticity, a general formula was deduced for the effect on the equilibrium temperature of a solid and a liquid under a stress which produces a strain in the solid at the surface of contact with the liquid. No restrictions Avere imposed on the nature of the body or on that of the strain, except that the strain must be non-dissipative. The general formula was applied to the case of linear compression, and the result compared with some other formulas which have been proposed. It agrees with Riecke's formula but does not agree with the interpretation sometimes given to Poynting's formula. Comparison with Bridgman's formula did not lead to any definite conclusion. Mr. E. D. Williamson gave a second paper on the same subject. The particular case of an isotropic solid under the influence of a one- sided thrust was treated. Formulas were deduced by methods similar to those used by Gibbs for the change of the equilibrium temperature on the face where the thrust was applied, and also at the free surface, on the hypothesis in each case that a reversible equilibrium is possible. At the free surface the change of temperature is always negative and small, i.e. at such a surface the melting point is always lowered by a small amount by any strain whatever. On the other hand at the sur- face where the stress is applied the effect is very much greater and is negative for a push but positive for a tension. The possibility of the physical realization of this second case is in doubt. . The method can be extended to the case of solubility by the introduc- tion of another variable — namely, the concentration of the solution. The results are similar to those mentioned above, the solubilit}r being- very slightly increased over the free surface but increased or decreased on the stressed surface by a push or a tension, respectively, by a much greater amount. Mi-. J. C. Hostetter then gave an illustrated communication on The influence of non-uniform pressure on solubility. It is possible that fluctuating temperature and, perhaps, some indirect effects brought 79 80 proceedings: geological society about by pressure may account for the solidification of crystals com- pressed in contact with their solution by loosely fitting pistons — as found by James Thomson, Le Chatelier, and Spring — without the necessity of postulating large increases in solubility due to pressure. In preliminary experiments, individual crystals were subjected to stress at constant temperature by direct loading, and the effect on the concentration of the surrounding solution studied, by measuring the conductivity. No change in concentration was found. The test was sufficiently sensitive to show that the effect of non -uniform pressure is much less than that produced by the same pressure acting uniformly, and not many times greater, as had been postulated by Johnston and Adams. However, in another series of experiments in which an unloaded crystal was placed alongside a loaded crystal, the former grew at the expense of the latter, showing that a very slight increase of solubility was produced by the stress. The method of loading the crystals has a large influence on the effects found, thus indicating the importance of the stress distribution. In conclusion, the experiments of Becker and Day on the linear force of growing crystals were cited as indicating the stability of a crystal in its solution, even when subjected to pressure. In their experiments loaded crystals were found to lift the load during growth, although the pressures on the supporting edges of the crystals were finally of the order of magnitude of the crushing strength of the crystal. Discussion. The three papers were discussed by Messrs. Briggs, Buckingham, Hostetter, Sosman, and Williamson. Mr. Hostetter remarked that the reason for the effect of hydrostatic pressure on melt- ing and solubility was much more obvious than that for the similar effect due to strain in the solid only, as hydrostatic pressure directly aids or opposes the volume changes accompanying such change in state. Mr. Buckingham referred to the complications introduced by the change in cross section of a crystal under load as it dissolves. Correction. In the minutes of the 780th meeting, this Journal, 7 : 24. 1917, for " Messrs. Ferner and Rothermel were appointed tellers," read, "Messrs. Fenner and Rothermel were appointed tellers." D. H. Sweet, Secretary. THE GEOLOGICAL SOCIETY OF WASHINGTON The 311th meeting was held in the lecture room of the Cosmos Club on November 22, 1916. INFORMAL COMMUNICATION T. W. Stanton : A Cretaceous volcanic ash bed on the Great Plains in North Dakota. Near Linton, North Dakota, in the southern part of the State about 15 miles east of the Missouri River, there are several conspicuous white outcrops that at a distance suggest chalk or diato- maceous earth. At one of the best exposures, 1 mile southeast of Lin- proceedings: geological society 81 ton, the measured thickness of the white bed is 26 feet, and it lies in the Fox Hills sandstone about 35 feet above the top of the Pierre shale. The rock is very fine-grained and mostly massive, though it contains some thin-bedded layers. A sample of it has been examined by Dr. G. F. Loughlin, who finds that it "consists of 80 per cent of volcanic glass, 15 per cent of quartz and feldspar, 2 or 3 per cent of biotite (some- what bleached) and scattered grains of calcite, hornblende, magnetite, and chlorite." No fossils were found in the white ash bed itself, but in the sandstone directly overlying it distinctive Fox Hills invertebrates were collected at several horizons distributed through a total thickness of about 100 feet. A fossiliferous green band colored by greenalite, which lies 16 feet above the white bed, also contains a considerable amount of vol- canic glass, thus showing that volcanic material is not restricted to the white ash bed. This seems to be the first recorded observation of such a bed of vol- canic ash in the Cretaceous sediments of the Great Plains. The nature and location of the deposit are such that its material must have been carried a long distance in the air and finally deposited in the sea. The nearest probable source, according to present knowledge of Cretaceous volcanism in the Rocky Mountains, is in the • Livingston region, Mon- tana, about 500 miles west. Remnants of this great ash shower should occur in other parts of the Great Plains and 'Rocky Mountains, and when recognized and identified they should be of some service in the definite correlation of local sections. REGULAR PROGRAM Henry M. Eakin: The Quaternary history of central Alaska. Cen- tral Alaska is rather evenly divided between uplands that are formed by solid rocks, and a number of basins floored with Quaternary sediments that head far inland and extend, apparently without interruption, to the sea. These basins seem to be interpreted properly as pre-Quater- nary erosional depressions. The physical aspects of the region indicate that in Quaternary time the normal drainage outlets of these basins were temporarily dammed, large areas were inundated and silted up, new outlets through low passes in the rims of the old basins were formed, and the drainage of the whole region was reorganized. Various hypo- theses as to the nature of the dams have been considered, including crustal warping, lava flows, gravel deposits, and glacier extension across the old basins. The hypothesis that glaciers were the agents meets the requirements that the dams were formed simultaneously in widely separated locali- ties and were transient. For two major stream diversions and for many minor ones ice damming seems clearly indicated, and no item of posi- tive evidence antagonistic to this hypothesis has been discovered. However, complete knowledge of certain areas essential to the final solution of the problem is still lacking. 82 proceedings: geological society J. S. Diller: Was the new lava from Lassen Peak viscous at the time of its eruption? That it was viscous is indicated by the following considerations: 1. The material that rose from the volcanic chimney into the crater on the summit of Lassen Peak spread in all directions and filled the fun- nel-shaped crater to its rim, forming a lid to the volcano. 2. Upon reaching the crest of the crater's rim the lava overflowed at the lowest points, one stream flowing down the western slope of the peak and another toward Lost Creek on the northeast. 3. The flow down the west slope is about 1000 feet in length and is a normal stream of siliceous lava with very rough broken surface. That it was a hot, viscous mass beneath the surface at the time of its eruption is proved by the written testimony of a number of observers, who from 9.30 to 11.30 on the night of May 19, 1915, watched the glow and flashes of light from the flowing, breaking lava as, in plain view, it crossed the crater rim and descended the slope. 4. In the overflow stream at the head of Lost Creek the delicate, steam-torn lava was bent and folded, as if viscous, while advancing across the crater rim, and much of it was carried away by the tremendous blast of hot gas (from beneath the lid) that devastated the Hat Creek country. 5. When the hot blast escaped from beneath the lava lid a portion of the lid, apparently where hottest, subsided into the former crater and exposed a number of fracture surfaces of lava blocks. On some of these surfaces there are distinct lines of viscous flow, and as the surfaces origi- nated dining the subsidence following the great eruption in May, 1915, the lava must have been viscous at that time. G. W. Stose: Age of certain shales in Cumberland-Lebanon Valley, Pennsylvania. The shales referred to are in detached areas in the lime- stone valley. The limestones range in age from Lower Cambrian to Ordovician and may be divided into seven formations. The shales were regarded by the Pennsylvania Geological Survey as equivalent to the shales formerly called Hudson River but now called Martinsburg, which overlie the limestones and adjoin them on the northwest. In weathered outcrop the various shales are closely similar and, as east of Harrisburg they have been brought together like parts of the same for- mation, this miscorrelation is not surprising. The real age of the shales in the detached areas was determined only after tracing the seven formations of the limestone from their known outcrops in the Carlisle quadrangle, southwest of Harrisburg. The largest area of the shales south of Harrisburg was proved, by its rela- tion to the Elbrook limestone, to be the Waynesboro shale of Middle Cambrian age, and typical purple siliceous shale of the Waynesboro was later found in it. The irregular relations to other formations on its north side are due to overthrust faulting, which terminates the area against the Martinsburg shale east of Harrisburg. The Waynesboro shale occurs also in prominent hills east of Schaefferstown and in small hills near Shillington, southwest of Reading. The shale thins abruptly proceedings: botanical society 83 toward the east and north and is not visible on the north side of North Mountain, where it is probably present, although thin and covered with wash. Its greater thickness at Schaefferstown and south of Harrisburg is probably due to the fact that at these localities it is overthrust from farther south, where its thickness is greater. Certain rocks at the Cornwall mines south of Lebanon, Pennsylvania, which were regarded as Hudson River shales by the Pennsylvania Geo- logical Survey, were foimd to be metamorphosed siliceous banded lime- stones of the Conococheague limestone of Upper Cambrian age. T. Wayland Vaughan: Significance of reef coral fauna at Carrizo Creek, Imperial County, California. Owing to the lateness of the hour this paper was postponed to another meeting. At the 312th meeting, held December 20, 1916, the presidential ad- dress was delivered by the retiring President, Arthur C. Spencer: Stream terraces in the Rocky Mountain province (Illustrated). The ad- dress will be published at a later date. At the twenty-fourth annual meeting held on the same evening the following officers were elected for the ensuing year: President, Walter C. Mendenhall; Vice-Presidents, Frank H. Knowlton and Arthur L. Day; Secretaries, H. E. Merwin and Esper S. Larsen, Jr.; Treas- urer, B. L. Johnson; M ember s-at-large-of-the-Council, B. S. Butler, H. S. Gale, C. W. Gilmore, R. W. Pack, and L. W. Stephenson. Carroll H. Wegemann, Secretary. THE BOTANICAL SOCIETY OF WASHINGTON The 116th regular meeting of The Botanical Society of Washington was held in the assembly hall of the Cosmos Club at 8.00 p.m., Tuesday, December 5, 1916, President T. H. Kearney presiding. The program of the evening consisted of a symposium on the behavior of hybrids in different groups of plants. Mr. G. N. Collins discussed the behavior of Indian corn. In about 25 cases out of 50 where the vigor of first-generation hybrids had been compared with that of the parents, definite evidence of greater vigor was secured, and in no instance was there clear evidence of decreased vigor. It was suggested that the differences in the degree of vigor observed in different varietal combinations appeared to be influenced by the length of time the parental strains have been isolated. Strains which are widely separated geographically, and on this accomit proba- bly have been kept distinct for long periods of time, usually exhibit the greatest increase in vigor when crossed, while strains from the same or adjacent regions, although they may show more marked morphologi- cal differences, generally show a less marked increase in vigor in the first generation of the cross. In a cross between two varieties having many sharply contrasting characters, a comparison of the variability of the first and second gen- 84 proceedings: botanical society erations showed two characters where the first generation was more variable than the second, six characters in which the second generation was more variable than the first, and eleven characters in which there was no measurable difference. In the same cross, in correlation studies involving eleven contrasted characters with fifty-five possi- bilities of correlation, twenty cases of correlation were observed. All but five of these correlations, however, appear to be physical or physio- logical in their nature rather than genetic, such as the correlation be- tween branching space and number of branches. There are but few alternative or discontinuous characters in maize, and most of these are color differences or differences in chemical com- position, as in the endosperm characters. The discontinuous characters are for the most part Mendelian. Horny or sweet endosperm is perhaps the best example of a simple Mendelian character pair thus far encountered in maize. Horny and waxy endosperm are completely alternative, but there are definite de- partures from the expected ratios. Aleurone and endosperm color show all gradation between Mendelian monohybrid ratios and continuous inheritance. Mr. 0. F. Cook called attention to differences in behavior of dif- ferent kinds of plants and animals, as indicating a possibility that the expectation of finding general laws applicable to the whole organic world may not be realized. Each case must be treated in a specific way. Increased vigor in the first generation is one of the more general phenomena attending hybridization. In cotton, for example, when distinct types are crossed, there is usually evidence of increased vigor and hardiness. These are expressed in larger size, better yield, and a greater ability to withstand adverse conditions. By distinct types of cotton are meant types which have a range comparable to the more divergent races of men, or to the Indian zebu as distinguished from our domestic races of cattle. The cotton types appear much more diver- gent than the types of corn. • The discussion was largely confined to examples in hybridization of cotton. As a rule the conjugate or Fi generation is intermediate be- tween the parents, while splitting is pronounced in the second and later generations but with no cases of complete return to either ancestral type. As a rule there is a great deal of correlation or coherence in the characters shown in the perjugate (F2 and subsequent) generations. It has not been possible to secure a cotton combining in stable form the Upland type of vegetation and the Sea Island or Egyptian type of lint. Plants which resemble the Upland type have lint with the Upland char- acters and vice versa, but the plants that most nearly resemble the parental types in other respects are usually very inferior with respect to abundance and quality of lint. Thus, one of the results of hybridization may be described as a total loss of the increment of selection which had been developed in the parent stocks previous to crossing. Some characters are more or less dis- continuous, but others appear to be continuous. The opportunities for proceedings: botanical society 85 selection in the conjugate generation are not good, on account of the general uniformity of the plants. Selections have been carried in some cases as far as 12 generations without securing evidences of stable com- binations of desirable characters. Hybrids between Sea Island and Upland varieties were not so good as the better class of long-staple Upland varieties, when work with the hybrids was discontinued. Mr. H. V. Harlan discussed the behavior of barley hybrids. He first called attention to the strikingly different characteristics of the barley group and the sharply contrasting characters such as naked . and hulled grain, black, purple, blue, or white colors, two and six-rowed, awned and hooded heads, smooth and toothed awns, etc. Individuals of the Fi generation in barley either may be intermediate in character or may resemble one of the parents, and are quite uniform. In most of these crosses the characters are inherited in a 3 : 1 ratio. The sub- stitution of hoods in the place of the awn, which has a very decided effect upon the physiology of the plant, is dominant to the presence of awns. The smoothness or roughness of the awns behaves as a Men- delian character. There is also a correlation between the smoothness of the awn and the hairiness of the stigma. Crossing between the two- rowed and six-rowed barley often results in an intermediate variety. Such characters as the following: hulled and naked, black and white, hooded and awned, are inherited in the 1 : 3 ratio. Fertility does not necessarily follow the 1:3 ratio. Dr. C. E. Leighty discussed hybridization in wheat varieties and species. Nine groups are available for hybridization : Triticum morio- coccum, Triticum polonicum, wild wheat of Palestine, and six sub- species of Triticum sativum. All of these species and subspecies hy- bridize and fertile hybrids have been obtained, rarely, however, between Triticum monococcum and any other group. Wheat and rye hybrids have been secured always by using wheat as the female parent. Aegilops ovata and triticoides have also been used in hybridization with wheat. The first generation shows increased vigor, so far as noted, and great uniformity. Most of the characters, however, are intermediate. When wild wheat is used in hybridization the spikelets of the hybrid fall apart as does the wild wheat. In the second generation segrega- tion of most characters occurs in a 3 : 1 or 1 : 2 : 1 ratio, but in some cases the ratio may be 15 : 1 or otherwise, as when a club wheat and wheat with tapering head are crossed. In most cases the behavior can be explained on the basis of Mendel's law. Wheat hybrids are often fixed and many of the good commercial strains have originated in this way. No bud variations or mutations have been noted. Mr. J. B. Norton discussed the crosses which he and Mr. A. D. Shamel had made between wheat and rye. Wheat is always used as the mother parent, as rye refuses to set seed with foreign pollen. The first generation plants show great vigor, and though they resemble the mother at first, at blooming time the resemblance to rye increases until they would normally be mistaken for that plant. The hybrids are nearly sterile, as out of thousands of first generation flowers only three 86 proceedings: botanical society produced viable seed, the plants from which were accidentally lost. In hybrids between tobacco varieties first generation uniformity and vigor are noticed in a marked degree. In the case of oat hybrids Mr. Norton noted that the segregation in the second and later generations was normally Mendelian, though in one or two cases intermediate forms became fixed. There is a distinct coherence of characters shown when naked oats are crossed with the ordinary hulled type. Naked oats have more than three grains to the spikelet, while in hulled oats the spikelets are limited to two or three. The first generation gives a peculiar intermediate, while in the second the parent types reappear with the intermediates in a 1:2:1 ratio, showing complete coherence of the two pairs of characters. While this coherence has not been split, two strains of the intermediate type were fixed. Of asparagus hybrids a peculiar case was mentioned. Asparagus davuricus, a Chinese species, when crossed with pollen of Asparagus officinalis gave a progeny that resembled in most characters the A. davuricus mother, with the exception of a greater vigor. The first generation plants dropped their branches in the fall like A. davuricus. These hybrids were crossed back with A. officinalis, but the second gen- eration showed none of the abcission phenomena exhibited by their mother parent, although the expected ratio was 1:1. One of the first generation plants of this cross shows a vine-like habit, a character not present in either parent or in any close relative, although vining is common in other sections of the genus. Dr. W. A. Orton discussed the behavior of disease resistance in hybrids, with special reference to the wilt diseases of cotton, okra, watermelons, and cowpeas, caused by the well-known vascular parasite belonging to the genus Fusarium. In cotton, resistance which occurs in rare individuals is separated out by selection, and the crosses discussed were made between such resistant strains and other varieties of Upland cotton. Certain conditions impair the exactness of results with reference to Mendelian ratios. The strains used were not of pure type and the most resistant show some disease; uniform exposure to infection is se- cured with difficulty; the severity of the disease varies with weather conditions. Susceptible plants are killed and their progeny are not available for further study. In the first generation in cotton hybrids wilt-resistance is dominant, only a small percentage showing disease, usually less than that of the resistant parent. In the second generation there is a segregation of the wilt-resistant character and a large percentage of non-resistant plants are produced. In reciprocal crosses an effect from the female parent is apparent in the second generation. By selection from the resistant plants the selected third generation shows a marked increase in resistance. In the cowpea wilt-resistance seems to be limited to a distinct variety, the Iron. In the first generation of crosses with other varieties wilt- proceedings: botanical society 87 resistance is dominant. In the second generation about one-third of the plants were sterile, the percentage being as high as 73 in some hybrids. About 67 per cent of the plants were seed producing. In the case of the watermelon, the citron or stock melon was used in breeding for a disease-resistant variety. In the first generation in- creased vigor was very noticeable, and in the second generation char- acters were noted Which had not been noted before in either of the parents, particularly in the colors of the fruits, and also in a bitter taste not noted in either of the parents. Mr. W. J. Morse called attention to the behavior of hybrids in the soy bean, in which group study was made of the following characters: (1) flowers (white, purple); (2) pubescence (white, tawny); (3) seed (yellow, green, brown, black, bicolored); (4) cotyledons (yellow, green); (5) hypocotyl (green, purple); (6) smoothness; and (7) non-shattering. All of these are found to behave as Mendelian characters and to segre- gate according to Mendelian ratio. The only interrelation of characters noted is between the flower and the hypocotyl, the white flower being associated with the green hypocot}*! and the purple flower with the purple hypocotyl. The non-shattering character is held to be one of the most important, and hybrids with this character have been fixed. Further work on this character with the standard commercial varieties is in progress. In the course of the hybrid work numerous sterile plants have been found. Natural hybrids of Fx generation can usually be told in the field by the plants having a few smooth pods at the tip of the branches. With the cowpea a large number of crosses have been made between the different commercial sorts, seeking to combine desirable characters. A stud}* of the seed colors shows them to segregate in Mendelian ratio. Wilt and nematode resistance have been fixed in hybrids. In the case of alfalfa, when hybrids of tender forms of Medicago sativa, such as Peruvian alfalfa, are made with Medicago falcata and the offspring subjected to severe winter conditions, there appears to be no tendency toward the elimination of the. blue or purple-flowered forms, indicating that flower color is not particularly correlated with char- acters resulting in hardiness. There have been several crosses reported between rather distantly related species of Medicago, but it is believed that most of them are not true hybrids. It is believed that the Medicago sativa X prostrata hybrid is the only authentic one in the genus Medi- cago dutside of the forms which Urban lists in his classification under Medicago sativa, which include Medicago falcata and M . glandidosa. Mr. Walter T. Swingle called attention to the great difference in the behavior of Citrus from other groups mentioned, in that a larger amount of variability occurred in the first generation of the hybrids. In Citrus many of these first generation hybrids are of commercial value and may be propagated without variation from seeds which con- tain usually only false embryos originating from the nucellar tissue of the mother plant. For example, hybrids secured between Poncirus trifoliata and the common orange, Citrus sinensis, are sterile, notwith- 88 proceedings: botanical society standing which they produce an abundance of seeds. These seeds originate parthenogenetically and represent a pure strain of the female parent. But in some few cases there is a true second generation. The individuals of the first generation vary greatly. The fruit may be smaller than that of either parent, or larger than the combined fruits of the two parents; it may be smooth or hairy, lemon-colored or orange- colored, with a great profusion of oil glands or almost without any; the shape of the tree may vary; the leaves are often 5-foliolate, although one parent is unifoliolate and the other always 3-foliolate. There is a very considerable cohesion of characters in the second generation of Citrus- Poncirus hybrids. It seems all but impossible, however, to secure hard- iness and an orange flavored fruit at the same time. In the case of Citrus-Poncirus hybrids great vigor is observed in the first generation. If this first generation is crossed with a kumquat, increased vigor also is shown; but no increase in vigor results from the return cross between the first generation and the parental species. The kumquat belongs to a distinct genus, Fortunella, so that in crossing a citrange with a kumquat a trigeneric hybrid is produced, combining Citrus and Pon- cirus with Fortunella. Although the kumquat is a dwarf plant, its diversity from Citrus and Poncirus is so great that when crossed with a citrange it brings about greatly increased vigor. By crossing Pon- cirus trifoliata with the ordinary orange, and then crossing this first generation hybrid with the kumquat, a fruit somewhat resembling the lime has been produced; it has no direct genetic relationship with the latter, however. During the general discussion Mr. L. C. Corbett and Prof. William Stuart discussed the behavior of carnation hybrids, and the latter called attention to the desirability of securing as high a percentage of germination as possible in the second generation, in order that no selec- tive error be introduced into percentage determinations. Mr. Norton said that of several thousand cases of carnations grow n from commercial types, the percentage of singles never was higher than 23 per cent. H% L. Shantz, Corresponding Secretary. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII FEBRUARY 19, 1917 No. 4 BIOPHYSICS. — The living plant as a physical system.1 Lyman J. Briggs, Bureau of Plant Industry. In early investigations relating to the growth of plants, the conception of a so-called " vital force" was frequently employed in the interpretation of the observed phenomena. It was long held, for example, that the organic substances found in plants and animals were dependent in their formation upon the exist- ence of vital forces, and that in consequence such products could not be produced in the laboratory. The classical discovery of Wohler that urea could be synthesized in the laboratory revo- lutionized the conception that all animal and plant products are dependent upon some vital force for their production. Since that time many other organic substances found in or derived from plants have been prepared synthetically. Many other phenomena associated with plant growth and formerly attrib- uted to the existence of some peculiar vital force have through modern methods of investigation been satisfactorily explained from physico-chemical considerations. Until matter in that state which we term "living" can be synthesized, the doctrine of vitalism can scarcely be said to have been disproved; but it is surely being restricted more and more a's our knowledge of plant phenomena increases. The situation at present may perhaps be fairly summarized as follows: The mechanism of plant processes 1 Address of the retiring President of the Philosophical Society of Washing- ton, presented before the Society January 19, 1917. 89 90 BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM not at present explainable on a physico-chemical basis would be termed by the vitalistic school as " vital;" by the physico- chemical school, "unknown." The efficiency of plant systems. I shall ask you in what fol- lows to consider the plant from the point of view of a physical system, a system which is absorbing energy and performing useful work. Radiant energy is absorbed by this system from the sun and sky, and under some conditions heat is absorbed from the surrounding air as well. This energy is used to do work upon water and nutrients taken in through the roots and upon car- bon dioxide absorbed through the leaves. A part of the energy, through the agency of remarkable catalyzing substances — the chlorophyll bodies and the protoplasm — is employed in the transformation of the materials absorbed into plant tissue. The latter represents the useful work performed by the system, which may be quantitatively determined by measuring the heat of combustion of the total plant substance formed. The re- mainder of the absorbed energy is spent in lifting and vaporizing water, except in those cases where the temperature of the plant rises above that of the surrounding air. In such instances heat energy is also transferred to the air. Let us for the present assume that the temperature of the plant does not exceed that of the air, an assumption which leaf temperature measurements have shown to be amply justified in the case of actively growing plants in a dry atmosphere. The total energy used by the system in a given time will then be represented by the total heat equivalent of the water evaporated, plus the total heat of combustion of the plant substance devel- oped during this period. If we represent the former by Qe and the latter Qc, both expressed in gram-calories, the efficiency (E) of the system may be represented by the relation • E = —Q°— (1) Qe+Qc Both quantities are capable of direct measurement. The water evaporated can be determined by means of suitably con- trolled field experiments designed to prevent all loss of water BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM 91 except that taking place through the leaves, while the heat of combustion may be found by finally burning in a bomb calorim- eter a representative sample of the plant substance produced. Numerous investigations have been made of the water re- quirement of plants, i.e., the ratio of the weight of water absorbed by the plant during its growth period to the weight of dry matter produced. It will accordingly be convenient to transform our efficiency equation to include this term. If a mass Mw of water is transpired in the production of a mass Mp of plant tissue, and if hv and hc represent the heat of vaporization of water and the heat of combustion per gram of plant substance respectively, then Qe = MJu (2) Qc = MPhc (3) Substituting these quantities in equation (1) and remember- ing that Mw/Mv is by definition the water requirement Rw, we have E = -J— (4) he Determinations of the heat of combustion of the dry matter of various plants do not appear to have been made. In the absence of more specific data, we may assume the heat of combustion to be represented approximately by that of cellulose, namely, 4200 gram-calories per gram. By substituting this value to- gether with that of the heat of vaporization of water (536 gram- calories per gram) in equation (4) we have as a first approxima- tion to the efficiency of the plant system E = (5) 0.13 #w + l The water requirement of field crops in the Great Plains as measured by Dr. H. L. Shantz and the writer ranges from 200 to 1000, depending upon the species and the evaporation-rate.2 2 Briggs, L. J., and Shantz, H. L. Relative water requirement of plants. Journ. Agr. Research, 3: 1-63. 1914. 92 BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM The lowest water requirement so far observed in the case of a field crop was obtained at Arlington, Virginia, in 1915, where corn and sorghum gave values of 151 ± 2 and 150 ± 2 respec- tively. If we substitute these values in equation (5) we find that the efficiency of the plants with the lowest water require- ment so far measured is only about 5 per cent, while in the case of plants with a water requirement of 1000, the efficiency is less than 1 per cent. In other words, the fuel value of the plant, i.e., the potential energy stored in the plant substance, repre- sents only from 1 to 5 per cent of the energy dissipated during the growth of the plant. Since the efficiency is approximately inversely proportional to the water requirement it is of interest to consider briefly how the latter may be reduced. Two procedures are open, namely, plant selection and reduction in the evaporation rate. Dif- ferent species of plants under the same environment show wide differences in water requirement. For example, Shantz and the writer have found the water requirement of alfalfa to be ap- proximately three times that of millet, when the two species are grown in large pots side by side. It is thus evident that in a region where the rainfall is the limiting factor in plant production, the fuel value of the plant material produced will vary widely according to the water requirement of the plant. It would be of much interest in this connection to know something of the efficiency of different forest trees, but no water requirement measurements of such plants are yet available. The second means of reducing the water requirement consists in the selection of habitats where the evaporation-rate is low. Here again little is known quantitatively as to what extent the efficiency may be increased in this way, and the subject affords a wide field for exploration. It is evident that if the absorption of water from the soil is so far reduced by increasing the hu- midity that the plant receives an inadequate supply of nutri- ents from the soil, growth would be retarded from this cause. Again, if we reduce the energy dissipated in evaporation by shading the plants, a limit will be set by the minimum quantity of radiant energy necessary for the photosynthetic processes. BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM 93 The growth-rate. We pass now to the consideration of our plant system from the standpoint of the growth-rate. The plant system is remarkable in that the useful work done is ex- pended in increasing the size of the system, at least during the earlier stages of growth. Furthermore, the quantity of cata- lyzer available for transforming the absorbed substances also increases with the size of the system. Therefore, while the efficiency of the system may not change during the growth of the plant, the quantity of useful work which it is capable of doing may theoretically increase at a rate proportional to the size of the system, assuming that an adequate supply of the products used in synthesis, i.e., carbon-dioxide, water, and nutrients from the soil, are present. This hypothesis is equivalent to saying that the rate of change of the weight m of the plant system is pro- portional to the weight itself, or, put into mathematical form : dm fa. — = axm (6) at Let us now see how nearly this assumption may be realized in nature. Since it is not possible to determine directly the dry weight m without destroying the plant, we must have recourse to some indirect means of determining the mass of material present at any time. We shall, therefore, make a further assumption that the increase in size of the plant from day to day is accompanied by a corresponding increase in the quantity of water which it transpires, a quantity which as we have seen is readily meas- ured. This latter quantity, however, would obviously depend upon the weather of each day, so that we must either maintain the plant under constant conditions from day to day during the course of the experiment, or we must correct the transpiration in accordance with the intensity of the weather factors each day. The latter procedure is the one which we have actually em- ployed. This correction may be made in a simple manner by dividing the observed transpiration during a day by the observed evaporation from a shallow blackened tank for the corresponding day. This gives us a series of numbers which are proportional 94 BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM to the transpiration or water loss from the plant during a series of uniform days, providing transpiration and evaporation are influenced in the same way by the changes in the weather. Our problem then is to determine how the transpiration corrected to the basis of uniform days varies with the time, our assumption being that the daily transpiration is dependent upon and is a measure of the size of the plant. -/. O o sc /Da 1/V i s Q/v rr/£ Of>£ *0 / ( 3 of 7 C 1 ° / < i / t i ) < )/ - o o / ' o P2 24 26 2G 30 2 4 6 8 /O /2 /4 /6 Fig. 1. Graph showing linear relationship between the logarithm of the trans- piration-evaporation ratio of Sudan grass and the time. After Briggs and Shantz. If now we return to our original hypothesis, that the rate of change in the size of the plant is proportional to the size of the plant itself, we will have by substituting the transpiration- T evaporation ratio — = k for the weight m of the plant in our Mi original equation (6) dk dt = dik (6a) BRIGGS: THE LIVING PLANT AS A PHYSICAL SYSTEM 95 Integrating this equation and transforming to common log- arithms, we have logioft = at + c (7) in which c is the logarithm of k when t = 0, that is at the be- 1 1 1 1 1 I I .24 22 20 /;ivin 126 cook: the mascarene cabbage palm The inner spathes also have a distinct but very narrow carina on each side, running about halfway up. The tip is distinctly apiculate, bu1 not produced. The outer surface is even, but dull, and of a rather light rusty-brown color, while the inner surface appears smooth and shining, bu1 is marked with distinct slightly prominent longitudinal brownish lines, with finer lines and wrinkles between, representing the finer ramifications of the fibro-vascular system. The number of pinnae and several other features noted at Payta seem not to have been recorded before. Bory and Martius refer to p.tioles and other parts of leaves as sometimes tinged with red, which may have caused confusion with another palm from Reunion, de- scribed by Bory as Areca rubra, but now placed in the genus Acantho- phoenix. It is distinguished readily by the presence of spines on the trunks and leaf-bases. A third species, Areca crinita, also described by Bory from the same island, has the trunk and leaf-bases clothed with slender curved spines and hairs. This also is referred by modern botanists to Acanthophoenix. It appears from Bory's account that all three species afford edible "cabbages," but the species now referred to Acanthophoenix are said to grow in the mountains, while Areca alba is said to prefer the shores and inhabited parts of the island. It might be presumed that this is the species that is now put up in tins and shipped to Europe and America as a salad delicacy, under the name "hearts of palms" (coeur de palmier). A study of a specimen of this commercial product shows the presence of minute slender spines embedded in the loose flocculent coating of the surfaces of the embryonic leaves, which would indicate that the material repre- sents Acanthophoenix. In addition to seeds that have been received on different occasions from commercial horticulturists the Office of Seed and Plant Intro- duction, Bureau of Plant Industry, has received seeds closely similar to those collected at Payta from Mr. G. Regnard, Port Louis, Mauritius, .■iceompanied by the following note: A palm that attains a height of 50 feet. Young plants have dark rod margins on new leaves which diminishes when the tree becomes older. The true red variety is getting very scarce now as almost all the trees newly planted are a cross mixture with the white. These seeds were gathered on true red sort in a wide plantation of them. The cabbage of this palm is commonly eaten here and has a quite delicate flavor. CLARK! CRINOID FAMILY ANTEDONIDAE 127 These seeds have the Inventory number 38,696. Other importa- tions are numbered 1928, 1929, and 42,365. ZOOLOGY. — A revision of the crinoid family Antedonidae, with the diagnoses of nine new genera.1 Austin H. Clark, Na- tional Museum. The family Antedonidae is the most universally distributed of all the families of recent crinoids; its species occur everywhere, ranging from the tropical littoral in both hemispheres uninter- ruptedly down to the greatest depths at which crinoids have been found, and include all of the strictly antarctic and all of the arctic comatulids. Owing to the difficulty involved in dealing with the species of this family, which arises chiefly from the altogether extraordinary brittleness and fragility of the great majority, and the resultant lack of some essential feature or other in very many of the published descriptions, no really satisfactory disposition of the included types has as yet been proposed ; but it is believed that the following arrangement more nearly represents the true inter- relationships of the component species than any of its prede- cessors. The species referable to the family Antedonidae fall naturally into forty genera, which in turn are distributed among seven well characterized groups, ranking as subfamilies. These subfamilies with their included genera are the following : Antedoninae: Antedon, Compsometra, Mastigometra, Euantedon, Toxo- metra, Dorometra (nov.), Eumetra, Iridometra, Hybometra, Andro- metra (nov.), and Argyrometra (nov.). Thysanometrinae : Thysanometra and Coccometra. Perometrinae : Perometra, Nanometra, Erythrometra, and Hypalo- metra. Heliometrinae : Heliometra, Promachocrinus, Anthometra, Solano- metra, Florometra, and Cyclornetra. Zexometrinae : Balanometra, Psathyrometra, Leptometra, Adelometra, Zenometra, Sarametra (nov.), and Eumorphometra. Isometrinae : Isometra. 1 Published with the permission of the Secretary of the Smithsonian Institu- tion. 12 N CLARK: CRINOID FAMILY ANTEDONIDAE Bathymetkin \i:: Orthometra (nov.), Tonrometra (nov.), Fariometra (nov.), Trichometra, Hathrometra, Nepio?netra (nov.), Phrixometra iiiov.), Thaumatometra, and Bathymetra. Dorometra, gen. nov. Genotype. Antedon nana Hartlaub, 1890. Diagnosis. — P3 is much the longest and stoutest pinnule on the arm; the cirri arc XX-XLV (rarely over XL), with not over 16 segments; these have produced distal ends which overlap the proximal ends of those succeeding, and the outer are much longer than their proximal width; the size is small, the arms being from 23 mm. to 50 mm. long; the brachials have smooth, or only very finely spinous, distal edges. Geographical Range. — Red Sea to Madagascar and Mauritius, east- ward to northern Australia and the East Indies, and northward to southern Japan. Bathy metrical Range. — From the shore line down to 106 meters. Included Species. — Dorometra nana (Hartlaub), Dorometra mauritiana (A. II. Clark), Dorometra gracilis (A. H. Clark), Dorometra briseis (A. H. Clark), Dorometra parvicirra (P. H. Carpenter), Dorometra aegyptica (A; H. Clark), and Dorometra clymene (A. H. Clark). Andrometra, gen. nov. 'linotype. — Antedon psyche A. H. Clark, 1908. Diagnosis. — P2 is much longer than Pi, and longer than P3 though similar to the latter; the centrodorsal is more or less sharply conical. Geographical Range. — Andaman Islands to southern Japan. Bathymetrical Range.— From 54 to 201 (?250) meters. Included Species. — Andrometra psyche (A. H. Clark) and Andrometra initial (A. H. Clark). Argyrometra, gen. nov. Genotype. — Iridometra crispa A. H. Clark, 1908. Diagnosis.— Centrodorsal conical, broader than high, almost com- pletely covered with cirrus sockets which decrease in size toward the apex; these are from LX to LXXX in number; cirri very fragile, with 12 17 more or less elongated segments; P3 is of the same length and character as the succeeding pinnules; Pi and P2, which may be longer or shorter than the following pinnules, have 12-13 segments, and taper evenly to a point; their component segments become progressively elongated; the brachial structure resembles that of Antedon petasus; the size is small, the arms being about 30 mm. in length. Geographical Range. Hawaiian Islands to northern New Zealand. Bathymetrical Range. From 108 to 293 meters. Included Species. Argyrometra crispa (A. H. Clark) and Argyro- metra mortenst ni, nov. CLARK: CRINOID FAMILY ANTEDONIDAE 129 Argyrometra mortenseni, sp. nov. Diagnosis. — This species is easily distinguished from A. crispa by the much more expanded distal ends of the cirrus segments (in crispa the dorsal and ventral profiles of the cirrus segments are everywhere practically parallel), and by the different relationships of the earlier pinnules. Pi is 3.3 mm. long, slender and evenly tapering, composed of 12 seg- ments of which the first is slightly broader than long, the second and third are very slightly longer than broad, and the following become progressively elongated, being between four and five times as long as broad distally; the segments are cylindrical and smooth, with little or no development of spines on the distal edges. P2 is 4 mm. long, very slightly stouter, composed of 12 segments of which the distal are more elongated than those of Pi. P3 is 5 mm. long with about 12 segments, about as stout basally as P2 but tapering more slowly and hence appear- ing stouter, with relatively shorter segments which beyond the third have prominently overlapping and finely spinous distal ends. The following pinnules resemble P3. The cirri have 17 segments of which the longest are from four to six times as long as the terminal diameter. The arms are about 30 mm. long. Locality. — North Cape, New Zealand. Depth. — Sixty fathoms. Sarametra, gen. nov. Genotype. — Zenometra triserialis A. H. Clark, 1908. Diagnosis. — The division series and arm bases are very spiny; the very long rounded conical centrodorsal bears three regular columns of cirrus sockets in each radial area, the radial areas being delimited by broad bare lines; the cirri have 50-60 segments of which the proximal are more or less elongated and the distal are short, never longer than broad, and bear prominent dorsal spines; all of the pinnules are present; the size is large, the arms being about 150 mm. long. Geographical Range. — Known only from the Hawaiian Islands. Bathymetrical Range. — Between 346 and 633 meters. Included Species. — Sarametra triserialis (A. H. Clark). Orthometra, gen. nov. Genotype. — Trichometra hibernica A. H. Clark, 1913. Diagnosis. — The cirrus segments, which are 25-33 (usually nearer the latter) in number, are cylindrical, without expanded distal ends, and short, the longest (third-fifth) being about one-third again as long- as broad, and the distal slightly broader than long; the elements of the IBr series and the lower brachials are without lateral processes, and are widely free laterally. 130 CLARK : CRINOID FAMILY ANTEDONIDAE Geographical Range.— Known only from the western coast of Ireland. Bathymetrical Range.— From 698 to 900 meters. Included Species.— Orthometr a hibernica (A. H. Clark). Tonrometra, gen. no v. Genotype— Antedon remota P. H. Carpenter, 1888. hiagnosis.—The cirrus, segments, which are not more than 20 in number, are all short, the longest being not so much as twice as long as the median diameter, and have much swollen distal ends; the IBr series and lower brachials are in close lateral contact. Geographical Range.— Moluccas to Marion Island, southeast of A TIM / "| Bathymetrical Range.— From 1089 to 2880 meters. Included Species.— Tonrometra brevipes (A. H. Clark) and Tonro- metra remota (P. H. Carpenter). Fariometra, gen. nov. Genotype. — Trichometra explicata A. H. Clark, 1908. Diagnosis. — The centrodorsal is sharply conical with straight sides, nearly or quite as high as broad at the base; the proximal cirrus seg- ments are elongated, at least twice as long as the median diameter and usually much longer. Geographical Range. — Philippine Islands to Celebes. Bathymetrical Range. — From 509 to 1314 meters. Included Species. — Fariometra explicata (A. H. Clark), Fariometra scutifera A. H. Clark, and Fariometra dione A. H. Clark. Nepiometra, gen. nov. Genotype. — Antedon laevis P. H. Carpenter, 1888. Diagnosis. — The centrodorsal is rounded conical or hemispherical, not so high as broad at the base; the proximal cirrus segments are elongated, at least twice as long as the median diameter, and usually much longer; the brachials do not have strongly produced and very spinous distal (mils; at most the distal edges of the outer brachials are bordered with fine spines; the cirri have 20-30 relatively short seg- ments of which the last 6-13 are only very slightly, if at all, longer than broad; the pinnules are not especially long, and the distal pinnules are of the same length as the proximal; P2 resembles P3 and the following pinnules and is slightly longer and stouter than Pi with somewhat fewer segments which are proportionately longer; P2 may bear a gonad, though these usually begin on P3; the arms are between 25 mm. and <>() mm. in length. Geographical Range. — Kei and Meangis Islands and southern Celebes; ? ( lalapagos Islands and Panama. Bathymetrical Range. — From 204 to 1158 (?1760) meters. Included Species. — Nepiometra obscura (A. H. Clark), Nepiometra alcyon (A. H. Clark), Nepiometra laevis (P. H. Carpenter), Nepiometra io (A. H. Clark), and Nepiometra (?) parvula (Hartlaub). CLARK! CRINOID FAMILY ANTEDONIDAE 131 Phrixometra, gen. nov. Genotype. — Antedon longipinna P. H. Carpenter, 1888. Diagnosis. — The centrodorsal is rounded conical or hemispherical, not so high as broad at the base; the cirri are about XXX, 20-25; the proximal cirrus segments are elongated, at least twice as long as the median diameter and usually much longer; the brachials do not have strongly produced and very spinous distal ends ; at most the distal edges of the outer brachials are bordered with fine spines; the pinnules are very long, the proximal longer than the distal; P2 is very slightly shorter than Px, but similar to it, with about 18 elongated segments; the following pinnules are similar; the arms are about 20 mm. long. Geographical Range. — Southeastern South America. Bathy metrical Range. — Known only from 1080 meters. Included Species. — Phrixometra longipinna (P. H. Carpenter). ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing in this issue. GEOGRAPHY. — The Navajo country, a geographic and hydrographic reconnaissance of parts of Arizona, New Mexico, and Utah. Her- bert E. Gregory. U. S. Geological Survey Water-Supply Paper 380. Pp. 219, with maps, sections, and illustrations. 1916. The Navajo country includes 25,000 square miles of arid and semi- arid lands occupied by about 32,000 Indians and 500 whites. Only a small pari of it has previously been described. The report, therefore, includes an unusually full treatment of geography under the heads: historical sketch, geographic provinces, climate, soil, flora, fauna, min- eral wealth, population, and industries. Many additions have been made to existing maps, and the list of geographic terms has been re- vised. Since the future of the country depends upon the solution of the problem of water supply, particular attention was given to the oc- currence of surface and ground waters. The Colorado and the San Juan rivers are perennial; all others are intermittent or ephemeral, but their flood waters may be utilized by construction of suitable works. Manx- springs and seeps may also be developed. The sinking of wells in deposits of various types is recommended, and the parts of the region favorable for artesian flows are indicated. Except for structure sec- tions and maps and the description of water-bearing beds, the report contains little strictly geological material. Such matter will appear in Professional Paper 93, now in preparation. H. E. ('. GEODESY. — Precise leveling from Reno to Las Vegas, Nev., and from Tonopah J unction, Nev. to Laws, Cat. H. G. Avers and G. D. Cowie. U. S. Coast and Geodetic Survey, Special Publication No. 39. Pp. 49. 1916. This publication gives the results of a line of levels run in 1915 along the railroads between Reno and Las Vegas, Nevada, and between 132 abstracts: geology 133 Tonopah Junction, Nevada, and Laws, California. The line is 547 miles long and fixes the elevations of 228 permanent bench marks. The elevation of the top of rail in front of the railroad stations along the line was also determined. The elevations of the bench marks and of the top of rail in front of the railway stations are given in meters and also in feet. As in all precise leveling in the United States the datum used is mean sea level. The highest point of the line is at Sunland, Nevada, 2171 meters (7122 feet). The result of a study of the errors of leveling is also given in this publication. The practice of the observer, while setting up the instru- ment, always to face in the same direction with respect to the line of progress had a tendency to make the line of sight higher for the back sights than for the fore sights. The effect of this has been eliminated by the observer facing in opposite directions at alternate set-ups of the instrument. H. G. A. GEOLOGY. — Geology of the Hound Creek district of the Great Falls coal field, Cascade County, Montana. V. H. Barnett. U. S. Geological Survey Bulletin 641-H. Pp. 215-231, with 1 plate. 1916. This paper describes the geologic formations, the structure relating to the occurrence or absence of coal-bearing rocks, and the coal resources of the Hound Creek district. The rocks that crop out in the district belong to the Carboniferous, Jurassic, and Cretaceous systems, but detailed study was confined to the coal-bearing Kootenai formation (Lower Cretaceous). R. W. S. GEOLOGY. — Contributions to the geology and paleontology of San Juan County, New Mexico. I. Stratigraphy of a part of the Chaco River V alley. Clyde Max Bauer. U. S. Geological Survey Pro- fessional Paper 98-P. Pp. 271-278, with 8 plates. 1916. This paper is an attempt to set forth the principal features of the stratigraphy in a part of the San Juan Basin, to describe the succession of strata irrespective of possible correlations and thereby to establish a type section for the formations exposed, and to bring out their relations to the strata immediately above and below. The area studied and mapped comprises about 1500 square miles in northwestern New Mexico extending along Chaco River for about 50 miles from the Great Hogback to Meyers Creek. It includes the out- crops of strata overlying the Mesaverde formation, which have in the 134 abstracts: geology past been referred to the Lewis, Laramie, Puerco, Torrejon, and Wasatch formations. The stratified rocks of this area consist of a succession of marine, brackish-water, and fresh-water sediments, which now occur as sand- stone, slate, coal, and conglomerate, in almost every gradation and combination possible. The strata throughout the greater part of the area dip from 1° to 3° toward the center of the basin. The Mesaverde and Lewis formations and the Pictured Cliffs sandstone are accepted as described by previous workers in the San Juan Basin. The beds above the Pictured Cliffs sandstone that have been classed by others as Laramie are divided into mappable lithologic units and described as the Fruitland formation, Kirtland shale, and Ojo Alamo sandstone. A bibliography is included. R. W. S. GEOLOGY. — -Some manganese mines in Virginia and Maryland. D. F. Hewett. U. S. Geological Survey Bulletin 640-C. Pp. 37-71, with 7 figures. 1916. Six deposits of manganese ore are described with regard to location, geology, and occurrence and origin of the ore. Maps show the surface relations and underground workings of three mines. Replacement deposits of four types are recognized — deposits (1) in residual clay, (2) in the clay of a fault zone, (3) along pervious zones in schistose rocks, and (4) in sediments that fill an ancient channel. Five of the deposits are on the east side of the Great Valley in western Virginia and one is near Lynchburg in the Piedmont region. The conclusion is tentatively reached that all of these deposits, and probably many more in the belt extending from Maryland to Georgia, were formed while the early Tertiary peneplain was being established in this general region. Four of the deposits outcrop on ridges and spurs that have been so isolated since the peneplain was dissected that they have received little surface drainage since that time, but each of the deposits contains much more manganese than could be derived from the decomposition of a mass of rocks having the volume of the residual clays in which the deposits occur. The clays and manganese minerals have been mined from 200 to 260 feet below the surface and from 170 to 220 feet below water level. In two mines the zone of residual clay and associated manganese minerals extends 105 mil 130 feet, respectively, below the level of the nearest streams, which flow in channels cut in bedrock. It therefore appears that the sedimentary rocks of the region may undergo thorough decomposition abstracts: engineering 135 to greater depths not only below an extensive erosion surface but also below the present water level than has previously been considered possible. D. F. H. GEOLOGY. — Geology of the Upper Stillwater Basin, Stillwater and Carbon Counties, Montana. W. R. Calvert. U. S. Geological Srn-vey Bulletin 641-G. Pp. 199-214, with 2 plates. 1916. The rocks of this area comprise a great thickness of strata ranging from the coal measures of lower Montana (Upper Cretaceous) age to beds more than 8000 feet above the base of the Fort Union formation, of Eocene age. Older sedimentary formations and crystalline rocks are exposed in the Beartooth Mountains, along whose north base there is a profound fault that brings Paleozoic rocks into contact with Tertiary formations south of Red Lodge and with successively older strata to the west. The Cretaceous and younger rocks, both sedimentary and igneous, are described, together with the geologic structure, which is simple. A discussion of the coal resources is followed by a statement concerning oil prospects. R. W. S. ENGINEERING.— Surface water supply of the United States, 1913, Part X, the Great Basin. Nathan C. Grover, et al. U. S. Geo- logical Survey Water-Supply Paper 360, Pp. 293, with 2 plates. 1916. Surface water supply of the United States, 1914, Part I, North Atlantic slope basins. Nathan C. Grover, et al. U. S. Geo- logical Survey Water-Supply Paper 381. Pp. 192 and XXXI, with 2 plates. 1916. Surface water supply of the United States, 1914, Part II, South Atlantic and eastern Gulf of Mexico basins. Nathan C. Grover, et al. U. S. Geological Survey Water-Supply Paper 382. Pp. 66 and XXX, with 2 plates. 1916. Surface water supply of the United States, 1914, Part VII, Lower Mississippi River basin. Nathan C. Grover, et al. U. S. Geo- logical Survey Water-Supply Paper 387. Pp. 60 and XXXIV, with 2 plates. 1916. Surface water supply of the United States, 1914, Part XII, North Pacific drainage basins, B, Snake River basin. Nathan C. Grover, et al, U. S. Geological Survey Water-Supply Paper 393. Pp. 248, with 2 plates. 1916. 136 abstracts: engineering The water-supply papers listed above are parts of a series giving the results of measurements of flow of streams in the basins indicated in the titles. Numbers 382 and 387 contain appendixes giving lists of stream-gaging stations and publications relating to the water resources of the basins. B. D. W. ENGINEERING — The measurement of silt-laden streams. R. C. Pierce. U. S. Geological Survey Water-Supply Paper 400-C. Pp. 39-51, with diagrams. 1916. San Juan River, in Colorado, New Mexico, and Utah, carries an un- usually heavy load of silt, especially during the torrential floods that often occur. The formation of "sand waves" is an interesting phe- nomenon connected with the heavy silt burden of this stream. Flood measurements are very difficult and sometimes impossible because of the heavy silt load and the accompanying conditions, such as high velocities, trash and drift, shifting channel, and rapid variations in stage. By the use of a stay line and a 60-pound torpedo-shaped weighl to hold the current meter in position, with a windlass built into one end of the gage car for handling the meter and weight, it was found possible to obtain measurements during all except the very worst con- ditions. In spite of the difficulties a good record of the stream flow was obtained. R- C. P. ENGINEERING.— Surface waters of Massachusetts. C. H. Pierce and II. J. Dean. U. S. Geological Survey Water-Supply Paper 415. Pp. 433, with 12 plates. 1916. ' . This volume contains the results of stream-flow investigations in Massachusetts, and a compilation of the available records. The data are arranged on the basis of the climatic year ending September 30, thai being the division of the year now generally used by the Geologi- cal Survey fchroughoul its work of water-resources investigations. The report contains an introduction by N. C. Grover, briefly sketching the uses and development of the water resources of Massachusetts, which have at all times played an important part in the industrial and com- mercial development of the Commonwealth. An article on Topogra- phy by Arthur Keith outlines the geology of Massachusetts with special reference to the various drainage basins, and gives in non-technical language the geologic history of the river systems. The tables of dis- charge, showing the flow of the rivers as measured at the gaging sta- tions, are followed by a gazetteer of streams, which lists and describes all the streams, lakes, and ponds shown on the topographic maps of abstracts: technology 137 Massachusetts. A contour map on a scale of 1 : 250,000, printed in colors, shows the principal drainage basins and the location of gaging stations. C. H. P. ENGINEERING. — Accuracy of stream-flow data. N. C. Grover and J. C. Hoyt. U. S. Geological Survey Water-Supply Paper 400-D. Pp. 53-59. 1916. Records of stream flow at different gaging stations vary in accuracy with the permanence of the stage-discharge relation, the precision with which the discharge rating curve is defined, the refinement of gage read- ings, the frequency of gage readings, and the methods of applying the daily gage heights to the rating table to obtain the daily discharge. The contributing factors are so complex that it is generally not prac- ticable to determine mathematically the probable error. A knowledge of the approximate accuracy is needed to apply intelligently the records to different uses; and a knowledge of the sources of error and their relative effects on the accuracy of the records is essential to the proper collection of data for different uses requiring different degrees of accuracy. A study of the accuracy of the records to be collected at any station, therefore, should begin with the reconnaissance for the site and continue through the selection, establishment, maintenance, and operation of the station, the computation and interpretation of the data, and the preparation of the records for publication. N. C. G. TECHNOLOGY. — The resistance of an oil to emulsification. Winslow II. Herschel, Bureau of Standards Technologic Paper No. 86. Pp. 37. 1917. In this paper is described a new test for the emulsification of oils. Certain results obtained by such measurements are also discussed. The test may be briefly described as follows: 20 cc. of the oil to be tested and twice that volume of distilled water are heated to 55°C. in a 100 cc. cylinder, 26 mm. inside diameter, and stirred for five minutes at a speed of 1500 r.p.m. The cylinder and contents are allowed to stand at the same temperature, and readings are taken at more or less frequent intervals (according to the type of oil) of the vol- ume of oil settled out from the water. From these readings, a maxi- mum rate of settling, called " demulsibUity", is easily taken from a table. The paddle is simply a plate of metal 8.9 by 20 by 1.5 mm. Since the test is not sensitive to slight changes of paddle dimensions, they need not be exact, and no calibration is required. W. H. H. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE CHEMICAL SOCIETY OF WASHINGTON The 263rd meeting of the society was held at the Cosmos Club, October 12, 1916. The program of the meeting consisted of reports from members of the section upon the various activities at the Fall Meeting of the American Chemical Society at New York City, and on the Second National Exposition of Chemical Industries. W. D. Bigelow, director of the society, reviewed particularly the work of the directors and the reorganization of the management of the Journal of Industrial and Engineering Chemistry. J. Johnston, councilor of the section, dealt especially with the majority and minority reports of the Committee on the Proposed Code of Professional Ethics and the work of the Division of Inorganic and Physical Chemistry. Others presenting brief reviews of papers presented at the meetings of the various sections were I. K. Phelps, L. F. Kebler, R. B. Dole, L. C. Wells, J. B. Tuttle, and W. Blum. H. D. Gibbs gave an account of the Exposition and the various symposiums on subjects of present industrial importance. The 264th meeting, held at the Cosmos Club, November 9, 1916, was devoted to the annual election of officers. The following were elected: President, C. S. Hudson, Bureau of Chemistry; Secretary, E. ( . McKelvy, Bureau of Standards; Treasurer, F. P. Dewey, Bureau of the Mint; Councilors, R. B. Sosman, Geophysical Laboratory, E. B. Phelps, Hygienic Laboratory, and R. C. Wells, Geological Sur- vey; Executive Committee, J. C. Hostetter, Geophysical Laboratory, F, W. Smither, Bureau of Standards. F. C. Cook, Bureau of Chemis- try. A. Seidell, Hygienic Laboratory, F. A. Wertz, Bureau of Stand- ards, P. B. Dunbar, Bureau of Chemistry. The 265th meeting of the society was held as a joint meeting with t he Botanical Society of Washington at the Cosmos Club, November 23, 1916. Dr. Frederick B. Power, of the Bureau of Chemistry, until re- cently with the Wellcome Burroughs Laboratory, London, gave an address upon the Aims and developments of phyto-chemical research. The speaker presented the results and conclusions drawn from a great amount of work carried out in laboratories abroad and largely published in detail in British journals. Particular emphasis was placed upon the enormous opportunity for development in this almost 138 proceedings: anthropological society 139 untouched field of scientific endeavor. Chaulmoogra oil was taken as an example of a phyto-chemical material upon which a great amount of work for the purpose of determining its structure and constitution had been carried out by the speaker and his associates. The 266th meeting of the society, held at the Cosmos Club, December 14, 1916, was devoted to the presentation of motion pic- tures showing the manufacture of steel pipe, sheet tin, and tin plate. These pictures were furnished by the courtesy of the American Sheet Tin and Tin Plate Company of Pittsburgh and were presented by D. M. Buck, Metallurgical Engineer of Pittsburgh. The 267th meeting of the society, a joint meeting with the Wash- ington Academy of Sciences, was held at the Cosmos Club, January 11, 1917. R. B. Sosman, retiring president of the Chemical Society, pre- sented an address on Some problems of the oxides of iron (this Journal, 7:55-73. 1917). E. C. McKelvy, Secretary. THE SOCIETY OF AMERICAN FORESTERS At the annual meeting of the Society, held at the University Club, January 18, the following officers were elected for the ensuing year: President, Filbert Roth; Vice-President, William T. Cox; Secretary, R. Y. Stuart; Treasurer, C. R. Tillotson; Executive Council, W. B. Greeley, five years, H. S. Graves, four years, R. C. Bryant, three years, D. T. Mason, two years, Clyde Leavitt, one year. R. Y. Stuart, Secretary. THE ANTHROPOLOGICAL SOCIETY OF WASHINGTON The 505th regular meeting of the Society was held January 16. At this meeting Mr. William H. Babcock presented a paper on Certain pre-Columbian notices of the inhabitants of the Atlantic islands. Beginning at the north, the speaker referred to the well known Norse colonization of Iceland in the latter part of the ninth century and to the much earlier establishment of Irish monks at some points of its coast. From numerous Celtic local names Dr. Nansen has argued that there may have been a much greater inland Irish settlement. But per- haps these names should be explained by the fact that there were many Irish and Hebrideans among the early Norse colonists. There are also mentions of "trolls" in the saga of Grettir — and perhaps elsewhere in early Norse writings — as inhabiting hidden places of the mountainous interior. These may possibly preserve the memory of aboriginal sur- vivals from pre-Norse and pre-Irish times, but more probably they merely echo old Norse traditions or are freaks of fancy. Farther south, perhaps the oldest record is Plato's Atlantis derived from his ancester Solon, who received it, as we are told, from the Egyp- tian priests of Sais. The speaker related it in slightly condensed form with special heed to anthropologic items, but expressed the opinion that 140 proceedings: anthropological society it merely reflects the civilized life of Plato's time on the Mediterranean shores and 1 hrows no light on mankind in the Atlantic. He recited also the description of a far western island, which seems to be Madeira, given in the time of Julius Caesar by Diodorous Siculus, and added the same esl imate. He held that this applies also to Plutarch's interesting account of Ogyggia, possibly Ireland or Iceland and the continent be- yond it; also to the Irish Sea romances, or Imrama, though the home life which they at times repeated in their tales was very different from the life of the Mediterranean. In the Geography of the Arab writer Edrisi (about 1154) we seem to find, perhaps for the first time, notes of observations of real human beings on the islands of the eastern Atlantic. A list of these was given with most of the relevant items, showing great diversity in matters of culture, perhaps also of race, but in part agreeing very well with four- teenth and fifteenth century accounts of the Canary Islanders. His sources were partly mythical, partly recent Arabic, and to some extent probably also European, both classic and mediaeval. It is impractic- able to identify each island; but some of them are doubtless to be located among the Canaries, one is perhaps Madeira, and two or three at least should be credited to the Azores. We have nothing certain and ex- plicit concerning the latter after this time until the Portuguese coloni- zation, which seems to have found no one in possession, but fortu- nately there is a considerable body of information as to the Canary Islanders. The speaker quoted from Major's introduction to the Canarien of Bontier and Leverrier, a translation of a letter written at the end of 1341 by certain Florentine merchants dwelling in Seville, Spain, narrat- ing an expedition to the Canary Islands that year, of three Portuguese ships manned partly by Italian seamen. It constitutes one of the best reports ever made of the people of the Canary Islands, who at that time were less affected by European interference than afterward. Mr. Babcock mentioned a brief settlement of thirteen Spaniards in Grand Canary in 1382, and also the conquest of the islands, begun by Bethencourt in 1402 and completed about 1485. From the same source (Major's introduction) the speaker quoted Azurara's narrative (in the History of the Conquest of Guinea, published in 1448) of a slave raid on the island of Palma, participated in by a Portuguese vessel in 1443, the quotation including some account of the inhabitants of the other islands. Further quotations were given from Cadmosto's report on the Canary Islands in 1455, about the middle of the conquest, some of the islands being then still un conquered and pagan. The speaker then gave, from the body of the Canarien, several selections presenting similar anthropological matter. A few words as to matters of race and culture closed the paper. The presentation of the paper was followed by a general discussion of the subject in which the speakers were Dr. Ales Hrdlicka, Dr. John R. Swanton and Dr. Truman Michelson. Frances Densmore, Secretary. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII MARCH 19, 1917 No. 6 ELECTROCHEMISTRY.— The electrometric titration of zinc with ferrocyanide. F. Russell v. Bichowsky, Geophysi- cal Laboratory. (Communicated by Arthur L. Day.) The purpose of this note is to point out a set of very interest- ing polarization phenomena that occur at a platinum electrode when certain insoluble salts, such as zinc, ferric copper, lead, or manganous ferrocyanide, are being precipitated. Only the case of zinc ferrocyanide will be discussed here. If we place a platinum electrode in a solution of potassium ferrocyanide and titrate this solution with a solution of some zinc salt the e.m.f. of the electrode measured against some standard electrode, such as the normal calomel electrode, follows a per- fectly normal curve beginning at about — 0.08 volt (the e.m.f. of the ferrocyanide electrode) and increasing slowly with the addi- tion of the zinc solution until near the end point; on the addi- tion of a drop in excess of the amount of zinc solution necessary to precipitate all the ferrocyanide the e.m.f. increases very sharply to — 0.40 volts. With further excess the e.m.f. stays approxi- mately constant, reaching a maximum value of about — 0.45 volts. The electrometric end point is thus very sharp, and the platinum electrode is by all means the most accurate and convenient device for determining the end point of the zinc ferrocyanide titration. However, if instead of adding zinc solution to a ferrocyanide solution we reverse the process and add ferrocyanide to the 141 142 bichowsky: electrometric titration of zinc zinc solution, the initial e.m.f. of the platinum electrode, instead of having the invariant value of — 0.45 volts can be made to have almost any value between 0.0 and - 0.5 volts, depending on the previous treatment of the electrode. If the electrode has been allowed to stand in contact with a ferrocyanide solution for some time the e.m.f. will be between - 0.1 and - 0.25 volts, depending on the length of time it has been in the solution ; if it is charged to say — 2.0 volts while in contact with a zinc solution the initial e.m.f. of the electrode may reach the reversible value of — 0.45 volts, or even higher. If the electrode has been adjusted to an e.m.f. of — 0.45 volts and the titration of zinc with ferrocyanide carried through as before, the exact reverse of the previous curve is obtained, the e.m.f. begins at — 0.45 volts, drops sharply at the end point to - 0.10 and continues at nearly that value on further addition of ferrocyanide. In this case, therefore, our initial curve is rever- sible. If, however, the platinum electrode has been treated so that it shows an initial voltage of say — 0.20 volts, on adding the ferrocyanide solution the numerical value of the e.m.f. in- creases slowly, instead of decreasing, this increase continuing until the curve that is obtained by plotting e.m.f. against cc. of ferrocyanide added intercepts the normal curve. At this point the e.m.f. is a maximum. From this point on the e.m.f. curve is entirely normal, the end point being perfectly sharp and un- changed. This phenomenon is similar to the one noted by Forbes and Bartlett1 for the titration of ferrous iron with dichro- mate, but in our case not only is it possible to avoid the phe- nomenon entirely by the proper treatment of the electrode already indicated, but it is also possible not only to control the initial e.m.f. of the electrode, but also the shape and slope of the ascending (abnormal) part of the curve, thus causing the point of interception of the abnormal and normal curve to be varied. In a well stirred solution the abnormal curve starting at - 0.2 volts will almost always intercept the normal curve just before the end point is reached, however, if the stirring is made very 1 Journ. Amer. Che.m. Soc, 35: 1527. 1913. .wherry: neodymium, cause of red-violet color 143 poor so that there is any large excess of ferrocyanide in contact with the electrode before the zinc is all precipitated, the end point can be suppressed entirely; or, if by various devices the titration is carried on so that the electrode is always in contact with small concentrations of both zinc and ferrocyanide ion, the point of interception of the normal and abnormal curve can be moved almost to the beginning of the titration, the titration curve thus having a very flat rather than the usual sharp maxi- mum. Of course, in all these cases, except in the case of no stirring, the end point is perfectly sharp and reproducible, and under any of these varied conditions this method of determining the end point is much more rapid, convenient, and accurate than those employing the usual indicators (iron or uranium). All these phenomena seem to show that in cases of this type depolarization can be accomplished only by some agent (in this case ferrocyanide, in Forbes and Bartlett's case, ferrous iron) whose oxidation and reduction reactions on the platinum electrode are reversible, and that the persistent irreversibility of the Forbes and Bartlett curve and of our curve was due simply to the fact that the only substance in the solution capable of rapid reversible reaction at the electrode was removed from the possi- bility of acting — by precipitation in our case, and by the excess of an irreversible strong oxidizing agent in Forbes and Bartlett's case. This explanation is independent of any theory of the cause of polarization MINERALOGY. — Neodymium as the cause of the red-violet color in certain minerals.1 Edgar T. Wherry, U. S. Na- tional Museum. Impressed by the intense red-violet color shown by the per- manganates, many chemists are inclined to interpret the similar colors occasionally shown by normally colorless minerals, such as calcite and apatite, as due to the presence of manganese. Of course, permanganates may be at once excluded from con- sideration, for they can only be produced by a somewhat vio- 1 Published by the permission of the Secretary of the Smithsonian Institution. 144 wherry: neodymium, cause of red-violet color lenl process fusing with alkalies and then acidifying— in the course of which the minerals would be destroyed; moreover they are extremely unstable, and even if formed could hardly persist long. Finally, permanganates show a highly character- istic absorption spectrum — observable by placing their solutions between a source of white light and the slit of a spectroscope — consisting of six bands in the yellowish green, green, and green- ish blue; but not a trace of this absorption spectrum is shown by any mineral thus far studied. Certain manganic compounds, containing trivalent manganese, are, however, also red- violet in color, and may develop in min- erals under mildly oxidizing conditions. Even colorless bottle- glass, on lying out in the sunlight for a time, becomes red-violet owing to the oxidation of the manganese to that valency.2 Such manganic compounds show a single rather hazy absorption band in the greenish blue, but only indistinct general absorption of the colors complementary to red-violet. On the other hand, there is at least one other chemical ele- ment, the rare-earth metal neodymium, which has red-violet or violet-red colored compounds; and these yield a highly charac- teristic absorption spectrum, consisting of an intense band in the orange-yellow, a fainter one in the green, and, if sufficiently concentrated, additional ones in other parts of the spectrum. These bands can readily be seen if a solution of monazite in sulfuric acid is placed between the source of light and the spec- troscope slit. They can also be observed in a number of min- erals, by the use of the microspectroscope.3 Of course if the mineral occurs in large enough masses, the ordinary spectroscope may be used, and the mineral be simply placed between the source of light and the slit; those described in this note give good results by this method. It was pointed out by Headden some years ago4 that the 2 See Gortner, R. A. Journ. Amer. Chem. Soc, 39: 157-162, 1908. 3 See the writer's paper, The microspectroscope in mineralogy, Smithsonian Misc. Coll., 65, No. 5, 1915. * Am. J. Sci., [4] 21: 301, 1906. wherry: neodymium, cause of red-violet color 145 red-violet5 calcite from Joplin, Missouri, gives this neodymium absorption spectrum. This was confirmed by the writer in the paper referred to, and in addition it was noted that the red-violet calcite from Rossie, New York, shows, faintly, the same spectrum. Specimens from Sterlingbush, New York, re- cently received by the National Museum in exchange from the New York State Museum, have the same color as the latter oc- currence, and show the same absorption spectrum. That manganese is not the cause of the color of these calcites is shown by the following considerations: The calcites con- tain ferrous iron, and must accordingly have been formed under reducing rather than oxidizing conditions, so that any manga- nese present must be in the manganous state. Now manganous carbonate, the mineral rhodochrosite, is pure red in color, and that this color is not essentially changed by association of the manganese with calcium is evident from the pale red color of the so-called manganocalcite, such as occurs for instance at Franklin Furnace, New Jersey. Furthermore, many calcites known to contain moderate amounts of manganese show no color whatever. The minute trace of manganese present in these red-violet cal- cites could therefore not bj^ any possibility produce their color. There is thus both positive evidence (the absorption spec- trum) and negative evidence (the inability of manganese to pro- duce the color) in favor of the view that red-violet calcite in general owes its color to neodymium. The mineral apatite is sometimes violet in color, but, as re- corded in the writer's paper above cited, usually shows no ab- sorption spectrum. Oddly enough the well known brown apatite from Ontario, Canada, yields the absorption bands of neodym- ium, although any red-violet color that this metal produces is masked; most of the crystals show an underlying green color, due presumably to ferrous iron, the brown being only a sort of local mottling which could readily be produced by irregular distribution of a pale red-violet coloring matter. 6 An effort was made to name the colors of these calcites according to Ridg- way's "Color standards and nomenclature," but accurate comparisons of colors seen only in thick layers of a transparent mineral and those painted on sheets of paper are impracticable. The approximate position of the calcite colors is, how- ever, 67, violet-red, composed of red 52 per cent, violet, 48 per cent. 146 kempton: endosperm color and albinism in maize It would naturally be expected that an occurrence of neodym- ium-bearing apatite free from the green color of ferrous iron would actually show the red-violet; which expectation has now been fulfilled. The U. S. Geological Survey has recently trans- mitted to the National Museum an extensive series of minerals collected by Dr. W. T. Schaller in the pegmatites of southern California, among which are two kinds of violet apatite. One, the color of which is pure violet, from the Mountain Lily Mine, Oak Grove, agrees with apatites from Maine and Saxony, pre- viously examined, in color and in absence of absorption spec- trum; no guess will here be hazarded as to the cause of its color. But the other, from the San Diego Mine, Mesa Grande, has a red-violet color similar to that of the Joplin calcite, and shows an even more intense absorption spectrum, so is to be regarded as also owing its color to neodymium. GENETICS. — A correlation between endosperm color and albi- nism in maize. J. H. Kempton, Bureau of Plant Industry. (Communicated by G. N. Collins.) Seedlings in which chlorophyll does not develop occur not in- frequently in many cultivated species. Such plants are known as albinos. As photosynthesis is impossible without chloro- phyll these seedlings soon perish. Some varieties of maize pro- duce many albino seedlings, and it has been possible to isolate strains which give regularly a certain proportion of albino seed- lings. Several investigators have tested the exactness of the ratio between normal and albino plants and have concluded that albinism is a simple Mendelian character, recessive to the nor- mal form.1 1 East, E. M., and Hays, H. K. Inheritance in maize. Conn. Agr. Exp. Sta. Bull., clxvii, 1911. Emerson, It. A. The inheritance of certain forms of chlorophyll reduction in corn leaves. Nebr. Agr. Exp. Sta. Twenty-fifth annual report. 1912. Gernert, W. B. The analysis of characters in corn and their behaviour in transmission. Published by author, 1912. Miles, Frank C. A genetic and cytological study of certain types of albinism in maize. Journal of Genetics, 4: 193. 1915. kempton: endosperm color and albinism in maize 147 In studying the effects of temperature and light upon the rate of elongation of albino seedlings the writer had occasion to grow seedlings from an ear which had both yellow and white seeds, and found what appears to be a correlation between the color of the endosperm in the seed and the development of chloro- phyll in the seedlings. The ear from which this seed was se- cured was the result of a self-fertilized first generation plant of a cross between Zea tunicata and Zea ramosa. This cross has been recently described in detail by Mr. Collins.2 The ear was non-podded and had approximately three yellow seeds to one white. The actual figures were 70 yellow and 18 white. These yellow seeds were similar to those reported by other investigators of yellow endosperm in that they varied greatly in the intensity of the color, but in this instance little difficulty was encountered in segregating the white seeds. The 70 yellow seeds were divided into four groups with respect to the intensity of the color, the two darkest groups having 18 seeds each, and the two lightest groups having 17 seeds each. table i ALBINO Dark yellow . . •. Yellow, grade 1 Yellow, grade 2 Yellow, grade 3 White Total 1 2 4 6 12 25 Fortunately every seed germinated and it was immediately seen that there was a correlation between white or colorless en- dosperm and albino seedlings. The percentage of albino seed- lings from the yellow seeds is 18.6, while the white seeds pro- duced 61.5 per cent albinos. Had we been growing only the white seeds from this ear a very misleading conception of the ratio of albino to normal plants would have resulted. It is also 2 Collins, G. N. Hybrids of Zea ramosa and Zea tunicata. Read at the meet- ing of American Naturalists, New York, December 29, 1916. 148 kempton: endosperm color and albinism in maize obvious that in a population of yellow and white seeds having an association between white endosperm and albinism the per- centage of homozygous yellow plants would be greatly increased owing to the differential death rate between the yellow and white. The five classes of seeds planted with the resulting seedling classes are shown in Table 1. Arranged in the form of a fourfold table by combining the four grades of yellow the classes are as shown in Table 2. TABLE 2 NORMAL ALBINO TOTAL Yellow 57 6 13 12 70 White 18 Total...*: 63 25 88 The coefficient of association by Yule's method3 is 0.795 ±- 0.072 which is certainly too large to be ascribed to chance. Using Pearson's formula4 for the mean square contingency, C2 = 0.395 ± 0.057, which is a deviation above a zero correla- tion of 6.9 times the error. Although the number of individuals is small, the fact that the proportion of albino seedlings increased as the intensity of the endosperm color diminished may be of some significance. If it is assumed that the differences in shade between the four classes of yellow endosperm are due to sepa- rate factors, it would seem that these several factors are corre- lated with albinism, which on the linkage hypothesis would necessitate that these associated factors be located on the same chromosome. As with many simple characters there are several degrees of albinism which grade from white to yellow by imperceptible stages. The present albino seedlings, while they were easily separated from the normal plants, varied among themselves from almost pure white to an appreciable amount of yellow. 3 \ule, G. Udny. On the methods of measuring association between two attri- butes. Journal Royal Statistical Society, 75, Part VI, May, 1912. 4 Pearson and Heron. Biometrika, 9: 167. 1913. FEWKES: INITIATION AT HANO 149 As the total number of albino seedlings was small no attempt was made to classify the degrees of albinism in relation to the degrees of endosperm color. The inheritance of endosperm color has been studied by sev- eral investigators who have concluded that this character is composed of at least two factors. The results are not easily interpreted even with two factors, the investigations revealing many complications, and it is possible that these may be due at least in part to a linkage between the several factors for endo- sperm color. The present correlation may be considered in the nature of a coherence since it is highly probable that the albino character and white endosperm were brought into this cross from the tunicate parent. The progeny of a self -pollinated ear from a sister plant of the male parent of the cross between Zea ramosa and Zea tunicata was noted in 1916 as having produced many albino plants. The yellow endosperm undoubtedly came from the ramosa parent and thus far no albino seedlings have been found in the strain of Zea ramosa we have been growing. There is, however, the possibility that this apparent coher- ence is in reality a physiological correlation between white or albino endosperm and albino seedlings. As a demonstration of the truth or fallacy of this statement a strain having yellow endo- sperm, and producing gametes carrying the albino character should be crossed with a white strain lacking the albinistic ten- dency, but the final results of such a cross cannot be obtained before the fall of 1918. ETHNOLOGY. — An initiation at Hano in Hopiland, Arizona. J. Walter Fewkes, Bureau of American Ethnology. There are three pueblos on the East Mesa of the Hopi In- dians called Walpi, Sitcomovi, and Hano. These villages, situ- ated in Northeastern Arizona, are composite in population and have been affected in different degrees by influx of clans from different directions the former homes of these clans now indicated by ruins. The inhabitants of Walpi are homogeneous. Sit- comovi, originally settled by clans from Zuni, has lost the Zuni 150 FEWKES: INITIATION AT HANO idiom, but still retains a ritual which is essentially Cibolan (Zu- nian). The latter pueblo is regarded by the Zufii as one of their pueblos among the Hopi, its architectural features being those characteristic of Tewa pueblos on the Rio Grande. Archi- tecturally Hano is also Tewan, and its inhabitants retain the Tewa idiom, its mythology and ritual being distinctly Tanoan, little modified by the neighboring Walpi. The general character of the rituals in these three villages is known, but very little has been published on the ritual of the relatives of the Hano people who now live along the Rio Grande, especially as to the nature of the initiations of youths into soci- eties of priests. The Hopi introduce personifications of ances- tors in their pagan dances, and call the personators by the name, Katcinas (Cachenas), but apart from that our knowledge is fragmentary. At Hano this worship formerly survived in its original form, so that the following pages may give an idea of the initiation of boys and girls into the Katcina cult as once prac- tised, possibly still persisting, in villages along the Rio Grande. The month of February is an active one ceremonially in the calendar of the Hopi towns. It is the month when lustration rites are performed to purify the earth from the malign influ- ences of a power which through sorcery is supposed to rule it in winter. In that month, the return of the Katcinas, led by their father, the Sun or Sky-god, is personated. The clans that came to the Hopi from the south personate the return of their Sky-god in December, the clans of Sitcomovi in January, but the Katcinas are supposed to return in February and to remain about the villages until July, when their departure is celebrated in an extended farewell festival. The February ceremony is called, in secular language, the Bean Planting, because beans are sprouted in the kivas to be symbolically used by the returning Sun-god to represent the fructifying forces of nature. These sprouted beans are given at that time to the heads of all the clans by the personator of the Sky-god, in answer to their prayers, as a symbolic promise of good crops during the year. Of the various steps in initiatory rites from birth to maturity, in the life of pueblo children, none is regarded more important FEWKES: INITIATION AT HANO 151 than the last, or that in which they are taught the mysteries of the Katcinas. A child under thirteen or fourteen years of age is not supposed to understand the nature of these supernatural beings, but to believe that from time to time family ancestors or spirits of the dead revisit the pueblos and receive prayers for the good of the tribe, after which they return to ghostly homes in the underworld, through the house of the sun far to the west. At this age they are among other things made acquainted with the fact that the Katcinas are not real supernatural beings, but persona- tions by their own parents. But they must obtain this knowl- edge through initiation, some of the ordeals of which may be regarded as severe and are certainly calculated to bring out the moral courage of the novitiates. Many rites occur, one of which is a ceremonial flogging of children, which takes place in the presence of chiefs and other persons of the tribe. The rite at Hano, the subject of this article, has never been described. To understand the meaning of this event and the place the Katcina cult occupies in the pueblo mind, it may be well to say a word on this subject before we pass to the consideration of the initiatory episode. In all their cults Hopi ceremonies show many indications of the worship of divinized ancestors, but this is especially true in those of the Katcina worship. The spirit dead are supposed to become Katcinas. The breath bodies of men pass to their future home, the underworld, a realm of the de- parted, presided over by the supernatural being called the God of Germs. The population of this underworld includes not only the spirits of those long ago deceased, but also those who have lately joined them. This ghostly population is supposed to have a social organization like that inhabiting the upper world, being as on earth divided into clans with related priesthoods, in all the conditions of life duplicating what is found among the liv- ing. There are male and female Katcinas, brothers, sisters, uncles, aunts, and various other relatives on the mother's side. The clans of the underworld, after death, bear names of the liv- ing, and are symbolically characterized. We have for instance, the Bear clan, the Badger clan, and others. Prominent among all members of each underworld clan are the oldest members, 152 FEWKES: INITIATION AT HANO the ancestral parents of each clan, elevated to the cultus hero and heroine of the clan. The sun of course is father, and the earth, mother; they are common parents of all clans. With this idea of the clan arrangement of the dead in the underworld let us consider their relation to the living clans, for this is the foundation of this cultus. Clan relationship not being severed by death, the deceased members are regarded as still members of the clan, with the same obligation to the clan as when alive on earth. What is most important of all is that the powers of these spirit ancestors are regarded as most efficacious in an- swering the prayers of the living. In other words, the clansmen of earth of the Bear clan feel that by addressing prayers to their relatives in the underworld, they, with their aid, can bring about what they desire. This can be accomplished by the use of magic or other supernatural agencies. The personation of ancient members of the clans are " conjured up" to hear the petitions of those of their clan, still living.1 The February ceremonial has for its primary purpose a cele- bration of the advent of these ancestral personages, while that in July celebrates their return to their homes in the underworld. The flogging of the young initiates, like other ritualistic episodes, contain many archaic survivals that have a foundation in an early myth recounting how the cult hero was initiated by the Sun father, in like manner. The flogging ceremony at Hano, here described, took place in the larger of the two kivas, or sacred rooms, just before sunset on the 14th of February, 1900. This rite has been witnessed more than once, but the variations are slight, at most, and have no great significance. As with all pueblo ceremonies some time is occupied with preparation of the paraphernalia used, as it has to be renovated for the special purpose. The walls of the room were replastered, and its floor thoroughly swept; all secular objects, as blankets in progress of weaving, were rolled up and put away, and smaller 1 These returning clan members are represented by living members, who, for the time being, believe that they really become the members of the spirit branch of the clan which they represent. FEWKES: INITIATION AT HANO 153 objects tucked in certain niches made in the wall for that pur- pose. Boxes containing soil, in which bean seeds2 had been planted a week before, were concealed by a wagon sheet hung across the end of the room. Three personators took the prominent parts in the child flog- ging, two of whom personated the great Sky-god and the third represented the earth, or old woman, who they believe makes the germs of life grow. The personator who flogs the children rep- resents the father of all living on earth as well as inhabitants of the underworld.3 An account of his costume may be instructive as embodying their symbolic conception of these supernaturals. Each personator of the Sky-god wears on his head a mask- helmet, painted black, and adorned with clusters of feathers, long beards made of horsehair with attached feathers hanging from their chins. The body, upper arms, and thighs are painted, smut from the bottom of an old cooking pot serving for black paint. Markings are drawn with gypsum on the upper arms and thighs, and the legs and forearms are painted with the same material. Several ears of corn strung together form their belts from which, reaching to their knees, hangs a fringe of horsehair stained red, the body being naked. This crude representation of the Sky-god has the same symbolic marks as a wooden idol of this god on a Hopi altar, and is called Tunwup Katcina. The three personators dressed near a shrine outside the kiva on the trail below the pueblo and entered Hano from the east in order to preserve the illusion that they came from a distant place in the east, where the sun, whom they personify, rises. They entered the kiva where spectators had already assembled, and shortly after their appearance, the man personating the Earth-woman entered the room passing through the hatchway 2 These beans were forced to sprout in midwinter in a superheated atmosphere of the kiva, and were carried later by the Sun-god to represent symbolically fructification of food plants. Children were formerly taught that these sprout- ing beans are brought by a supernatural being, not being permitted to know that they were raised by their parents in the kiva. 3 These men belonged to Hano clans. There are two Sky-gods in their myth- ology, one representing the sun, and the other the moon. 154 FEWKES: INITIATION AT HANO down the ladder bearing a flat basket with sacred meal to be used in the ceremonies. It was about four o'clock, in the afternoon, when Anote, the village chief of the pueblo, Hano, entered the kiva, bearing in one hand two wands made of the leaves of the yucca or century plant, in the other hand his medicine bowl and a badge, indi- cating his standing as a chief. He placed this badge on the floor and deposited his medicine bowl near it. He then poured into the latter a white liquid, making passes in sequence with his hand towards the six cardinal points: north, west, south, east, above and below. He then stripped off the spines from the margins and points of the yucca leaves, scooped some of the medicine from the bowl into one hand and drew the leaves through it. Aided by another man he tied several leaves to- gether making two whips, which were laid on the placque con- taining the prayer meal brought by the old woman. By this time spectators had begun to assemble in the room, each one taking his seat on the raised floor at one end of the room. When they were seated, a number of adults, men and women, each accompanied by a child, who carried an ear of corn called "mother" in one hand, filed into the kiva and seated them- selves along the sides of the room. When all were gathered the chief began to construct a rude altar on the floor of the room. He first made a low ridge of sand a few inches high into which he planted, upright, a row of 20 wing feathers. In front of these feathers he outlined on the floor, with meal, three semicircular figures, side by side, representing rainclouds, and added parallel lines of meal symbolic of falling rain. On the middle raincloud figure he set upright the badge of his office. A few feet in front of these figures near the firehole, he outlined with a line of meal a square figure crossed by two diagonals, on the junction of which, in the middle, he laid two small feathers. Having com- pleted these preliminaries the chief took his seat back of the line of feathers and gave the signal that he was ready for the rite to begin. Shortly after, steps were heard on the kiva roof above followed by a voice hooting down the opening or hatchway, demanding permission to enter. The chief mounted the ladder FEWKES: INITIATION AT HANO 155 and spoke to those above. Immediately there followed him down the ladder the two personators of the Sky-god, and a man dressed as an old woman. These three made a circuit around the fire hole six times, after which the earth woman personator holding the basket of meal and whips, took position near the bottom of the ladder, and the two Sky-gOds stood, one on each side of the rectangular meal figure on the kiva floor. The latter then began a rapid dance bending and swaying their bodies and shouting to the assembled spectators. Each was then handed one of the yucca whips, previously prepared as mentioned above, after which they resumed their dancing, calling out loudly for the children to come and be flogged. In a short time a woman led forward a girl about 11 years old, whose garment had been semoved from her back, and placed her within the square out- lined with meal. One of the Sky-gods immediately struck the bared back with the yucca wand several times, all the while con- tinuing to dance and shout. He than passed to the other side exchanging places with his companion and the foster mother bared her back and was flogged as her child had been before her. The two Sky-gods again exchanged places, and whips, as yet un- used, were given to them, after which a man, possibly a father, led a boy forward, both stepping inside the rectangle of meal. The boy was first flogged on the back in the same manner as the little girl, and the father was struck several times also on legs and arms. As each person entered the space occupied by the meal figure he took a pinch of meal and, raising it to his lips, threw it toward the Sky-god, uttering an inaudible prayer. The flogging continued until four children, and as many foster par- ents, or the men and women accompanying the children, had been treated in this way. Generally the punishment was re- ceived by the children without a flinch, but one of the girls was frightened. The Sky-god was lenient, simply whirling his whip over her head, without striking. At the close of the flogging of initiates, other children, mostly boys, not initiates, voluntarily came forward and stood with backs bared for the whips. They were struck, oftentimes rather severely. Then adults, one after another, including the old 156 FEWKES: INITIATION AT HANO chiefs, stood up and were flogged, in the same way. As each person passed to the altar after receiving the blows he took a little liquid from the medicine bowl or meal from the basket, rubbed it on his wounds, without a word, and took his seat on the floor. The personators then left the room, after which the chief spoke at length, in Tewa idiom, to the assembled people. The author did not understand Tewa, but was told by an inter- preter that he spoke to them on the meaning of the rite. He may have explained that it was a dramatization of an old legend and that the floggers were their own relatives personating super- natural beings. Following the speech the spectators then crowded around the altar, dipped their hands in the medicine, and took a handful of meal with which they rubbed their bodies, as both liquid and meal are considered salutary. At the close r»f the ceremony the children were led out of the room by their parents to their own homes. On February 15, the day subsequent to that in which the flogging above described was performed, there was celebrated at Walpi one of the most unusual of all rites of the Bean-plant- ing festival. The main events of this ceremony were prayers to a supernatural being called Masauu, the god of planting, also known as the supernatural of the "surface of the earth." The dramatic reception of Masauu occurred in a Walpi kiva at 8 o'clock in the evening and lasted far into the night. It is such an unusual event, having been witnessed by the author but once, that although it has no direct connection with the child-flogging it is introduced here, for want of a more ap- propriate place. On the night when Masauu's visit was personated all fires throughout the East Mesa were extinguished. No one was met in the streets. • Women and children were in hiding in back rooms, and darkened house terraces were deserted, for the dread being is greatly feared by all the Hopi. Knowing that he was to be personated that night, the author resorted to the chief kiva, in Walpi, early in the evening, and found about 20 men engaged in decorating their bodies with white kaoline paint, drawing lines down their backs and legs and placing FEWKES: INITIATION AT HANO 157 great daubs of white on their cheeks and hair. None of these men were masked, but all claimed they personated sisters or brothers of Masauu. Shortly after the author's entrance they began to sing their songs, containing strains of fine archaic Hopi Indian music, closely resembling in their cadences the song sung by the antelope priests in the well-known snake dance. While these songs were being sung a priest came down the kiva hatchway bearing two large hollow gourds, the sur- faces of which had been painted black, and spattered with a wash containing glistening hematite. Each gourd was large enough to fit over the head and both were later worn as helmets by personators of Masauu. With these gourds the same priest brought two planting sticks of ancient form and two flat bas- ket plaques which were laid with great reverence alongside the masks, near the fire hole. At the advent of this man all those present ceased their singing and lighted their pipes for a formal smoke, during which the pipes were passed around, every man silently puffing clouds of smoke upon the masks. No one of that gathering spoke a word but each fervently prayed in sequence, beginning with the chief, at the conclusion of which they again returned to their usual songs. During these songs one of the chiefs raised the painted gourd helmet and talked directly to it praying for success of crops during the coming season. The songs rose and became so loud that no one could tell what was said, but the intent throughout were prayers to fertilize the fields that the corn might germinate and grow. Shortly after, while the men were still singing and the light of the fire had been shielded from all eyes by a blanket, in order to darken the room, a naked man silently and unannounced came down the ladder, not as is usually the case backwards holding on the rungs, but as one would descend a pair of t f airs. Entering the room without making the customary request, "Am I welcome here?" he slipped around back of the row of singers, peering anxiously at the masks on the floor. He fi- nally came to the front from his hiding and squatted by the fireplace. Cautiously he placed the strange human skull-like gourd helmet over his head, threw a rough blanket aroui d his 158 FEWKES: INITIATION AT HANO neck over his shoulders, and taking a planting stick in his hands assumed the kneeling posture which the Hopi take when they are planting on their farms, kneeling on one knee with the stick held vertically in his two hands. A second man who entered the kiva, in the same way donned the other helmet and without a word took his position near his predecessor. The songs of the assembled priests then became more animated and finally died down to a low murmur and ceased. The two per- sonators manipulating their planting sticks in rhythm kept time to the songs. At the conclusion of which the singers filed out of the kiva, but as each man passed the fireplace he placed in the flat basket on the floor by the side of the kneeling figures a feather, symbolic of a prayer, for a successful harvest. As the last man left the room he halted for a moment at the fireplace, with one foot on the ladder rung and announced that in the spring, at planting time, a great ceremony to the planting god would occur in the fields to the west of Walpi. The prayers throughout this rite were particularly fervent, but so low they could not be heard even a few feet away. There was no loud talking and the faces of all were very serious as befitting the reverence for the beings addressed; many even went so far as to turn their faces away from the dread being to whom they prayed. After the departure of the men the two planting gods silently gathered up the feathered prayer offerings offered them, and departed. The supernatural being called Masauu, also known as Eototo, was the chief cult being of the Fire people who migrated into the Hopi country, according to legends, from the East in pre- historic times. They formerly lived at a pueblo, now in ruins, three miles east of Walpi, called Sikyatki. A quarrel arose between Walpi and the inhabitants of Sikyatki, sometime be- fore 1540, which eventually led to the overthrow of the latter pueblo, whose people were incorporated in the former. Their cultus supernatural, Masauu, transferred to the Hopi pantheon, is still from time to time personated by descendants of the ill-fated Sikyatki, now fused with other Walpi clans. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing in this issue. GRAVITY. — Investigations of gravity and isostasy. William Bowie. U. S. Coast and Geodetic Survey, Special Publication No. 40. Pp. 196, with 18 illustrations. 1917. For a number of years the U. S. Coast and Geodetic Survey has been carrying on geodetic investigations of isostasy with special reference to the effect of isostatic compensation upon the deflection from the vertical and upon the intensity of gravity. Four reports on these investigations have appeared previously. The first one was in 1909 and the last one in 1912. The present report has as its main features: (1) The observed value of the intensity of gravity at the stations in the United States, Canada, India, and Europe, and at a few scattered stations. (2) Discussions of the relations between the gravity anomalies and the topography, the large areas of erosion and deposition, the geological formation as indicated by the surface rock, and the elevation of the station. (3) So-called regional versus the local distribution of the isostatic com- pensation. (4) The determination of a gravity equation and of the earth's flattening and the depth of compensation upon each of several assumptions. (5) Summaries of the results of the field observations with the pendulums, and descriptions of the gravity stations. (6) Illus- trations, in the pocket at the back of the volume, showing graphically much data resulting from the investigation. The results of the investigation may be summarized briefly as follows : 1. The most probable depth of compensation derived from gravity observations alone is 95 kilometers. As the author believes that the best value determined by Hay ford from deflection data is 97 kilometers and that each of these two values should have equal weight, the re- sulting best value from all geodetic data is 96 kilometers. 159 160 ABSTEACTS: PHYSICS 2. In the United States there was found a decided relation between the sign of the gravity anomalies and the coast, but there was not found any apparent relation between the anomalies and any other class of topography. 3. In the United States there was found a decided relation between the gravity anomalies and the Pre-Cambrian geologic formation. In both the United States and in India there was found a decided rela- tion between the gravity anomalies and the Cenozoic formation. No relation between the gravity anomalies and the geologic formations was found in Canada. 4. It was found from certain computations and investigations that the local distribution of compensation of the topographic feature is in general nearer the truth than regional distribution of the compensa- tion out to a distance from the station of 167 kilometers. It was not proven whether local distribution is more probable than a regional dis- tribution out to a distance of 59 kilometers from the station. 5. The best formula, resulting from this investigation, by which theoretical gravity may be computed for any latitude at sea level was based upon 348 stations; it is To = 978.039 (1+ 0.005294 sin2 0 - 0.000007 sin2 2 0) in which y0 is the value of gravity sought and 4> is the latitude of the station. 6. From the constants of the above gravity formula, was derived the value of 297.4 for the reciprocal of the flattening of the earth. This value of the flattening is very close to other values recently derived from gravity data in the United States and elsewhere. 7. The cause of the greater part of the anomalies is believed by the author to be in general the deviation from normal in the densities in the outer portion of the earth's material and probably not far below sea level. The titles of a number of articles dealing with isostasy or related subjects are given. W. B. PHYSICS. — A specific gravity balance for gases. J. D. Edwards. Bureau of Standards Technologic Paper No. 89. Pp. 20. 1917. The need of an accurate method for determining gas densities has been especially urgent in the natural gas industry. To supply this need the apparatus described in this paper was designed. The balance is enclosed in a gas tight chamber and consists of a beam which is sup- ported on 2 needle points, and which carries on one end a relatively large globe and on the other a small counterweight. The gas to be abstracts: metallography 161 studied is introduced into the balance case and its pressure is changed until the beam balances. The density is computed from the initial and the final pressures. The balance is standardized by similar observa- tions made with the case filled with air. J. D. H. CHEMISTRY. — Experiments in the destruction of fly larvae in horse manure. F. C. Cook, R. H. Hutchison, and F. M. Scales. U. S. Department of Agriculture Bulletins 118 and 245. 1914 and 1915. Experiments during 1915 in the destruction of fly larvae in horse manure. F. C. Cook and R. H. Hutchison. U. S. Department of Agriculture Bulletin 408. 1916. These three bulletins cover experiments extending over three jrears searching for satisfactory lar/icides for fly larvae to be applied to fresh horse manure (the principal breeding place of the house fly) which would be without extremely toxic properties and without in- jurious action on the fertilizing value of the manure. The study involved entomological, bacteriological, and chemical investigations. Over 50 substances have been tested of which three have been found effective and practicable. Some were excluded because of their ex- treme toxicity, such as potassium cyanide. The three that are recom- mended are borax, hellebore, and calcium cyanamid mixtures with acid phosphate. Borax in large amounts injures plant growth, hence should be ap- plied only to manure that is not to be used as a fertilizer. Powdered hellebore {Veratrum album and V. viride) applied as a solution is an effective larvicide and, because it is decomposed in the course of the fermentation, does not affect the fertilizing value of the manure even when excessive quantities are used. Calcium cyanamid mixed with acid phosphate and kainit are ef- fective and, if enough acid phosphate has been added to give an acid reaction, the nitrogen and ammonia of the manure will be retained. The mixture is an advantage in that it adds to the manure nitrogen, potash, and phosphoric acid. F. C. C. METALLOGRAPHY. — The structure of the coating on tinned sheet copper in relation to a curious case of corrosion of this material. Paul D. Merica. Bureau of Standards Technologic Paper No. 90. Pp. 18. 1917. The attention of the author has been directed to a case of local cor- rosion, or pitting, in tinned sheet copper roofing. The pits occur in 162 abstracts: botany general along the lines of surface scratches, and are apparently unre- lated to the service conditions, and to the direction of rolling of the sheet. They appeared some eight or ten years after the completion of the roof. The tin coating on copper consists of at least three layers; viz., a thin layer of CusSn immediately next to the copper, than a layer of Heycock and Neville's constituent H, containing about 60 per cent by weight of tin, and finally, a layer of the eutectic of tin and copper, in which most probably is found any lead that may have been present in the tinning mixture. The constituents of these intermediate alloy layers are more electronegative than either the tin or the copper. Con- sequently, when the copper becomes exposed, as at the bottom of scratches on the surface, it forms together with the alloy layer a gal- vanic couple, electrolytic action sets in, and the copper at these points is corroded, forming the pits mentioned. P. D. M. GEOLOGY. — Relations of the Embar and Chugwater formations in central Wyoming. D. Dale Condit. U. S. Geological Survey Profes- sional Paper 98-0. Pp. 263-270, with 3 plates and 2 figures. 1916. The Embar formation of central Wyoming, which lies between the Tensleep sandstone and the Chugwater formation, comprises several distinct facies, each of which is considered in detail, and some of the formational boundaries in the Bighorn Mountain region are redefined. In connection with the description of the gypsum and associated strata it is suggested that possibly conditions were favorable for accumu- lation of salt beds also. The chance of finding such deposits down the dip below the surface is believed to be sufficient to merit further investigation. R. W. S. BOTANY. — Maxonia, a new genus of Tropical American ferns. Carl Christensen. Smithsonian Miscellaneous Collections, 669: 1-4. 1916. The type and sole species of this new genus, M. apiifolia, is a rather rare polypodiaceous fern of Jamaica and Cuba, described by Swartz in 1801 under Dicksonia, and since variously referred to Dryopteris (or Nephrodium) and Polystichum. From Dryopteris, in which it was last placed as a special subgenus by Maxon in 1909, it differs in the unique morphology and development of the indusium, as also in its strongly dimorphic leaves and peculiar rope-like rhizome. The last two characters recall Polybotrya, between which genus and a small subgroup of Dryopteris species it is somewhat intermediate. A sub- species, M. apiifolia dualis, occurs in Guatemala. P. C. S. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE PHILOSOPHICAL SOCIETY OF WASHINGTON The 783rd meeting was held at the Cosmos Club, February 3, 1917. Vice President Burgess in the chair; 61 persons present. The min- utes of the 782nd meeting were read in abstract and approved. A letter signed by several members of the society, calling attention to the recently organized American Metric Association, was read. Mr. Arthur W. Clime, introduced by Mr. Alexander Graham Bell, presented a communication on Photoelectric radiophonic experiments. Mr. Bell, in introducing Mr. Clime, spoke of the history of se- lenium. He referred to the remarkable property possessed by crystal- line selenium of having its electrical resistance affected by light; and of the utilization of that property in the construction of the photophone. He also referred to the discovery made by the late Prof. W. G. Adams, of King's College, England, that light produced an electromotive force in crystalline selenium. Mr. Bell had suggested to Mr. Clime that this opened up a new field for scientific investigation and recommended him to follow out the experiments of Prof. Adams by applying the results to radiophonic researches. He had also pointed out to Mr. Clime that the remarkable properties of carbon in radiophonic work would well bear exploration. Mr. Clime then exhibited some of the radiophonic apparatus he has constructed, and spoke of the results that had been obtained. He showed a selenium cell which, when exposed to an intermittent beam of light, caused a telephone connected with it to emit a musical sound even when there was no battery in the circuit. The result he claimed was due to an electromotive force produced in the crystal- line selenium by the action of light. He also showed a cell in which the selenium had been replaced by lampblack. So long as there was a voltaic battery in the circuit the telephone responded well when the lampblack surface was illuminated by an interrupted beam of light, but he was unable to detect any audible effect when the batterjr was removed. A cell in which a mixture of selenium and lampblack was employed was then exhibited. In this case the sonorous responses of the telephone were very loud even when no battery was used. The musical tone was clearly perceived when the telephone was held at a distance of several inches from the ear. On. account of the magnitude of the sound produced by the selenium-carbon mixture, Mr. Clime predicted the possibility of producing, by the action of sunlight, an electromotive force of sufficient power to be of economic value. 163 164 proceedings: philosophical society Discussion. The paper was discussed by Messrs. Abbot, Bauer, and Weed. Mr. Sosman inquired as to the nature of the effect of adding carbon. Mr. Clime stated that the increase in response seemed out of all proportion to the increase in absorption due to blackening the surface. Mr. Briggs asked about a lack of symmetry in the il- luminated system, and Mr. Swann spoke of observing small electro- motive forces in very thin films of platinum illuminated by a beam of light not perpendicular to the surface. The chair expressed the thanks of the society to Mr. Clime for his interesting communication. Mr. W. W. Coblentz then gave a paper on Characteristics and com- parative sensitiveness of various types of radiometers. The various types of radiometers were divided into three groups. Group I includes radiometers which are nonselective in their re- sponse to stimuli of radiant energy of all wave lengths. In these instru- ments the radiant energy is absorbed and converted into heat. They include the Nichols radiometer, the thermocouple, the Boys radio- micrometer, and the Langley bolometer. In all these instruments the response is proportional to the stimulus, and they are well adapted for quantitative work. Group II includes substances which have the property of decreasing in electrical resistance when exposed to radiant energy of short wave- lengths, especially visible and ultraviolet rays. The phenomenon de- pends entirely upon the wave-length of the light stimulus. Many substances are "light-sensitive," e.g., copper oxide, sulphides of an- timony and silver, and crystalline selenium. The latter has been the most extensively investigated. Its sensitivity depends upon heat treat- ment, and varies with the intensity and wave-length of the light stim- ulus. After exposure to light for a few seconds, it requires a long time to recover its normal ("dark") resistance. It is not adapted to quantitative work. Group III includes the photo-electric cells, substances which, when charged to a negative potential, lose their charge when exposed to light; especially violet and ultra-violet rays. This emission of elec- trons is a surface phenomenon, easily disturbed by oxidation of the surface. The photo-electric cells investigated consisted of potassium and rubidium. .It was found that the response (galvanometer deflec- tion) was not proportional to the intensity of the stimulus, but, dif- fering from the selenium cell, this lack of proportionality of response does not appear to depend upon the wave-length of the exciting light. In 1907 Angstrom described a new method for studying solar radia- tion. By covering his pyrheliometer with a blue glass he was able to study atmospheric diffusion of solar radiation independently of the water vapor present. He obtained some very interesting data on the temporary variations in the solar constant. In view of the fact that the potassium, photoelectric cell has its maximum sensitivity in the violet, the speaker tried it as a pyrheliometer. It was found entirely too sensitive (on only 2 volts) to be used with an insensitive d'Arson- nal galvanometer. Using a higher voltage and a milliammeter, the proceedings: biological society 165 current released when the cell was exposed (through blue glass to reduce the intensity of the sun-light) was sufficient to overheat the wires and crack the glass cell. This investigation should be continued, using a less sensitive photoelectric substance. In certain spectral regions the sensitivity of the selective-radiometers is far greater than that of the non-selective instruments. The sen- sitivity of the selective instruments seems spread in the non-selective radiometer over the whole spectrum, with a corresponding reduction to a uniform and much lower value. From published data it appears that a single crystal of selenium, 1 sq. mm. in area, is 100 times as sensitive as the best selenium cell. In connection with a 36 inch tele- scope such a crystal receiver could detect a candle at a distance of 350 miles. The photoelectric cell is probably even more sensitive than the selenium cell. However, these instruments are very insensi- tive in comparison with the eye, which responds to light having an in- tensity of less than 1 X 10-9 ergs. Discussion. Mr. Abbot spoke of some radiometers of very high sen- sitivity in which the alignment of small magnetic needles was changed by the thermal expansion of the parts holding them. Mr. Swann spoke of obtaining readings by placing a Peltier j unction beside a thermo- couple and maintaining the thermocouple at a constant temperature by the Peltier effect. Mr. Abbot spoke of increasing the sensitivity by cooling the apparatus in liquid air. Mr. Coblentz stated that tem- perature differences in the surroundings make it very difficult to get consistent results. Donald H. Sweet, Secretary. THE BIOLOGICAL SOCIETY OF WASHINGTON The 564th meeting of the Society was held in the Assembly Hall of the Cosmos Club, Saturday, January 27, 1917; called to order at 8 p.m. by President Hay; 45 persons present. Under the heading of brief notes, Messrs. W. L. McAtee and A. Wetmore made remarks on certain misconceptions as to the notes of some common species of birds and as to a theory of the migration of birds. Under the heading exhibition of specimens, Dr. 0. P. Hay showed a metacarpal of a horse with well developed lateral metacarpals, and three fused metacarpals of a cow each with well developed digits. Dr. L. 0. Howard commented on an enthusiastic antimosquito convention which he had lately attended in New Jersey. The regular program consisted of two communications: H. M. Smith: Exploitation of neglected aquatic resources. Dr. Smith called attention to many forms of fishes not used as food by the Amer- ican public, but which are of pleasing taste and of good food value. Many of these have long been used for food by Europeans especially about the North Sea. He gave a brief resume of the discovery, disap- pearance, and rediscovery of the tilefish and of its successful introduc- 166 proceedings: biological society tion to the consumer through exploitation by the Bureau of Fisheries. He then described the dogfish and its habits destructive to other fish and the losses caused by it to fishermen. He told of the efforts now- being made by the Bureau of Fisheries to market the dogfish as a food. Under the name of grayfish it is now being successfully canned and marketed by some of the New England fisheries and, during the winter months when salmon are unattainable, by some of the salmon canneries on the Pacific coast. The canned meat not only consti- tutes one of the cheapest forms of protein now available, but the livers of the dog-fish yield a valuable oil; the oviducts, eggs; and the skin a leather which has many possibilities. Discussion by Messrs. Ames, Bean, and Doolittle. W. L. McAtee: Showers of organic matter. Under this heading Mr. McAtee gave a review of the various apocryphal and authentic instances in which hay, grain, various insects, encysted animalcules, worms, frogs, toads, fishes, and birds had fallen from the sky. The explanation was offered that the objects had been carried aloft by violent currents of air. The 565th meeting of the Society was held in the Assembly Hall of the Cosmos Club, Saturday, February 10, 1917; called to order at 8 p.m. by President Hay; 30 persons present. Two formal communications were presented: H. F. Taylor: A mortality of fishes on the ivest coast of Florida. During the months of October and November, 1916, by some ob- scure cause, vast numbers of fishes were killed in the region mentioned. It appears to be a recurrence of the phenomenon observed in 1844, 1854, 1878, 1880, 1882, 1883 and 1908. Of the dead fishes 63 species, repre- senting 37 families, were identified. The animals killed were confined, with the exception of king crabs, sea urchins, and sponges, to the class Pisces. Various suggested causes were examined; foul Everglade water, diseases, and volcanic eruptions are inadequate explanations. Evidence at hand seems rather to show that the cause of mortality was the release of occluded bottom gases by small seismic disturbances, or possibly by abnormally large numbers of Peridinii. Mr. Taylor's pa- per was illustrated by lantern slide views of the region involved and of strips of shore showing the large numbers of stricken fishes. His paper was discussed by Messrs. Hay, Bartsch, Goldman, Radcliffe, and others. Paul Bartsch: Changes in the avifauna about Burlington, Iowa, 1885 to 1917. From 1885 to 1893 Dr. Bartsch was resident of Bur- lington and an enthusiastic bird collector. In the ideal conditions found for birds at Burlington he had recorded 275 species. Since 1893 he has been a sporadic visitor to Burlington but has always re- tained his interest in the local avifauna. Passenger pigeons, Caro- lina parakeets, whooping and sandhill cranes, and trumpeter swans were found about Burlington, but are no longer seen. The same is true of the Mississippi kite, the swallow-tailed kite, wild turkey, and proceedings: botanical society 167 prairie chickens, the latter in times past having been shot from the speaker's porch. The prothonotary warbler, once common, appears to have gone northward. New birds now found at Burlington have come from the west, such as western meadowlark and red-shafted flicker. Other newcomers are the tufted tit and Carolina wren. Many of these changes are due to human agencies, some are unexplainable. Dr. Bartsch's paper was discussed by Messrs. Hay, McAtee, Wilcox, Goldman, Jackson, and others. M. W. Lyon, Jr., Recording Secretary. THE BOTANICAL SOCIETY OF WASHINGTON The 117th regular meeting of the Society was held in the Assembly Hall of the Cosmos Club at 8 p.m., January 2, 1917, President T. H. Kearney presiding. Mr. C. W. Warburton was elected to member- ship. Under Brief Notes and Reviews of Literature, Mr. W. T. Swingle called attention to a recent trip by Prof. E. D. Merrill of the Phil- ippine Bureau of Science, to the vicinity of Canton, China, where 3000 botanical specimens were secured. The regular program was devoted to* the subject of Plant Introduc- tion under which the following papers were presented: The need of more foreign agricultural exploration. (Illustrated) : David Fairchild. Attention was called to the need of more foreign agricultural exploration and to the fact that only a comparatively small amount of money had been expended in such work. The amount had seldom, if ever, exceeded ,$18,000 in any one year, and for the most part the expense had been much lower. The most successful type of agricultural exploration has been carried on by men who are interested in particular lines of agricultural work. Among those who have been called into the exploration work temporarily are Messrs. Kearney, Carleton, Hansen, Swingle, Cook, Collins, Oliver, Aaronsohn, Meyer, Rolfs, Bessey, Knapp, Mason, Scofield, Shamel, Dorsett, Popenoe, Young, Lake, Bolley, Shear, Tracy, and Fairchild. Attention was also called to the need of studying the methods of agri- cultural production in foreign countries, to some of the more important recent introductions, and to the difficulty in getting people to adopt new foods. The wild relatives of our crop plants; their value in breeding; how to secure them. (Illustrated) : Walter T. Swingle. The importance of the wild relatives of our cultivated plants in effective breeding for such desirable qualities as hardiness, earliness or lateness of blooming or of ripening, disease resistance, extra vigor, etc. was discussed. Fre- quently these wild relatives were found to be inconspicuous plants quite unlike the cultivated forms in appearance and were often native in remote localities. The Australian desert Kumquat, Eremocitrus glauca, for example, was originally described under the genus Triphasia and afterwards transferred to the genus Atalantia. In neither of these 168 proceedings: botanical society genera was it properly placed, since it is closely related to true citrous fruits and will hybridize with the cultivated forms. Not cursory in- spection of botanical literature, but protracted critical study of the botan- ical relationships, was necessary to make plain the desirability of the introduction of this species for the successful breeding of hardy and drouth-resistant citrous fruits. Plants not so closely related to the cultivated forms have been found useful stocks upon which to graft cultivated varieties. A properly digested taxonomic knowledge of the wild relatives of our cultivated plants was found to be indispensable as a foundation for all efficient plant introduction and plant breeding. The introduction of foreign plant diseases: R. Kent Beattie. American agriculture has been based largely on introduced plants. Only twelve of the two hundred and forty-seven species of cultivated plants studied by De Candolle in his Origin of Cultivated Plants are clearly indigenous to the United States., Diseases of American eco- nomic plants may be separated into two groups: (1) Those which have passed from native plants to the introduced hosts, such as pear blight; (2) Those which have been introduced, such as citrous canker and the chestnut bark disease. Plant disease may be introduced in three ways: (1) The diseased crop plant may be imported for commercial use; (2) The diseased crop plant may be imported for scientific pur- poses; (3) The spores of the disease-producing organism may be brought in on plants not affected by the disease. Commercial plant introduction, except field crops and florist stock, has been under a system of permit and inspection. In most states, however, the inspectors were trained as entomologists rather than pathologists, and there has been little restriction on the commercial importation of fungus plant diseases, except in the case of specifically quarantined crops. Material imported by the U. S. Department of Agriculture has undergone rigid inspection and plants which show symptoms of disease or arouse suspicion have been treated or grown under restraint until danger was passed. During the year 1916 the Pathological Inpectors of the Federal Horticultural Board while ex- amining the material imported by the U. S. Department of Agriculture found one hundred and sixty-three hosts affected with disease and de- termined one hundred and fifty-seven diseases on these .hosts. The protection and propagation of plant introductions: B. T. Gal- loway. The rapid change in public sentiment in the matter of plant sanitation and plant hygiene and the need for a -constructive policy in the matter of adequately protecting our crop plants, and at the same time not closing the doors to the development of new crop in- dustries through the introduction of plant immigrants, was discussed. The Office of Foreign Seed and Plant Introduction in the Depart- ment of Agriculture has received seeds and plants from all over the world. These seeds and plants were grown, propagated, and tested at four outlying stations. It has also acted as the agent for handling seeds and plants from foreign countries for other branches of the De- partment, for the experiment stations, and for many private and pro- proceedings: anthropological society 169 fessional experimenters throughout the country. It has recognized the clangers to our important crop industries and has endeavored to take such steps as, in the light of our present knowledge, will insure that nothing but plants free from parasitic enemies and transmissible dis- eases are distributed. The practical questions now confronting the office are as follows: (1) The organization, development, and equipment of a central plant and seed receiving station where plant introductions and plant mater- ials of all kinds may be received, inspected, treated, and held if nec- essary, under conditions that will safeguard the country, and at the same time not prove to be a bar to a safe and constructive development of new plant industries; (2) The discovery and application of methods of treating seeds and plants, cuttings, buds, bulbs, etc., in such fashion as will free them from parasitic enemies and transmissible diseases, and at the same time not injure them or completely destroy them; (3) The discovery and application of improved methods of reproducing plants by seeds and vegetative parts in such manner that they will be free from parasitic enemies and transmissible diseases; (4) The con- ducting of field tests and trials for the purpose of determining the healthfuhiess of new or promising plant immigrants, and their suit- ability for general distribution; (5) The great need of further knowledge of plant propagation and plant and soil sterilization in order to pro- vide methods which are less empirical than those in use at the present time. H. L. Shantz, Corresponding Secretary. THE ANTHROPOLOGICAL SOCIETY OF WASHINGTON ■ The 506th meeting of the Society was held in the Lecture Hall of the Public Library, Tuesday evening, February 6, 1917, at 8 o'clock. Dr. J. Walter Fewkes, of the Bureau of American Ethnology, read a paper on Prehistoric rains of the Mesa Verde National Park. This communication was mainly taken up by an outline of the work accomplished by him, in the summer of 1916, under direction of the Bureau of American Ethnology, at the request of the Department of the Interior. After a brief introduction on the situation and physical features of the Park and a short account of archeological work already accomplished, the speaker described in detail the uncovering and re- pair of one of the large pueblo-like buildings of the Mummy Lake group, situated on the Government road, 4| miles from the ruin known as Spruce-tree House. The mound excavated is one of the largest of the group, and when the work began gave no indication of the form, size, and architectural features of the building it covered. After three months' work there was brought to light a rectangular structure, 113 feet long by 100 feet wide, three stories high, with an enclosed court on the south side. The ground plan showed the existence of four circular, ceremonial rooms compactly embedded in fifty rectangular enclosures which were for- 170 proceedings: anthropological society merly used for secular purposes. The remarkable feature of this ruin is the large size of one of the circular rooms, situated in the center of a compact group of chambers. From the wide .southerly outlook this ruin has received the name, Far View House. It is a pueblo habitation; the first of its type ever brought to light on the plateau. The ruin was repaired, the tops of the kivas being treated with Portland cement to protect them from the elements. After describing the various architectural details of the building Dr. Fewkes passed to a consideration of what he termed the morpholo- gy of the structure, or the comparison of it with other types, especial- ly the cliff dwellings of the Mesa Verde. He declared that it is a new type of ruin for that region, and that there are evidences of many other examples of the same general character now indicated by mounds; we may say that formerly there were as many members of this type on the Park as cliff dwellings in the caves of the canyons. He consid- ered in detail some of the arguments bearing on the relative age of buildings like Far View House, and the cliff dwellings, and came to the conclusion that the former were the more recent, and evolved from the habitations in cliffs. Considerable time was devoted to a discussion and comparison of the so-called kiva or sacred room. He held that this chamber should be made the basis of classification of pueblo ruins, and that it was represented by the tower found widely distributed in Utah and ad- jacent regions of Colorado. He pointed out the wide-spread custom of dual styles of buildings among primitive races, one type being devoted to religious purposes, the other to habitations. He claimed that the former are always better constructed than the latter. He regarded the tower as a religious building and thought that the people who i^sed it lived in dugouts or temporary habitations that have disappeared. In the earliest times these two types were separated, but in later stages in the evolution of buildings they became united, and habitations were constructed around the bases of the towers. Later in the course of development the central original building lost its tower-like form and became the circular kiva. Several similar architectural units, by union, formed a pueblo. Dr. Fewkes pointed out that the great morphological similarity be- tween Far View House and the pueblos with central kivas and towers, many miles away, had an important bearing on the distribution or diffusion of pueblo culture. He regarded the San Juan region as the nucleus from which the pueblos south and west originated, thus sub- stantiating by archaeological evidence the legendary traditions of the inhabited and much modified historic pueblos. He claimed that there were two nuclei of distribution of house builders in the southwest, each arising in regions physiographically and climatically distinct, each possessed of different materials available for architectural ad- vancement. One arose in the Gila Valley, the other in the San Juan; the former spread toward the north, the latter to the south. Both nuclei were extinct before the historic epoch. What remained, or proceedings: anthropological society 171 that which we now know as the culture of living descendants, is the product of acculturation, due to cultural contacts in this expansion. History can afford, therefore, only an imperfect picture. We must rely on archeology, mainly architectural, and ceramic remains, sup- plemented by ethnology, to discover the nature of the culture of these two original nuclei. In a discussion of their distribution the speaker showed numerous illustrations of the prehistoric kivas, called towers, situtated in Hill Canyon, near Ouray, Utah. To these he gave the name, suggested by their site, Mushroom Rock ruins. Their more striking peculiarity is their position on the tops of inverted cones, or mushroom-like formations of rock, produced by the enormous erosion evident in the region where they occur. He said that this form of ruins was not morphologically a different type from towers, but their site was so un- usual that it was convenient to designate them by this name. While the important question of the antiquity of the cliff dwellings has not been satisfactorily answered by the observation made at Far View House, progress is being made in the accumulation of significant data bearing upon it. As long as this question remains unanswered the archeologist has plenty of research before him for many more years of field work in the Southwest. The communication was illustrated with lantern slides. The 507th meeting of the Society was held in room 44 of the New National Museum, February 20 at 4 p.m. The speaker of the after- noon was Dr. I. M. Casanowicz of the New National Museum, who pre- sented a paper on The fish in cult, myth, and symbol. Dr. Casanowicz said, "The fish, as the inhabitant of the mysterious, indestructible, never-resting water, early impressed man deeply, and was considered by him as the genius and representative of the life- producing element. Traces of the veneration of the fish, sometimes revealed in taboos, are found everywhere in ancient times and still exist in various parts of the world." An important center of ichthy- olatry in antiquity, according to the testimony of classical writers, was Syria where a fish goddess under the name of Derketo-Atargatios was worshiped as a phase of the great Semitic mother goddess Astarte, being regarded as a personification of the fructifying power of the water. Reminiscences of this cult still survive in the cherishing of sacred inviolate fishes in some places near mosques. Tales of the fish as a medium of transformation and incarnation of spirits and ghosts are met with among various nations, and in later times the fish seems to have been, next to the bird, a symbol of the departed human soul. The fish as carrier of man across the water was illustrated by the story of Arion and the dolphin as told by Her- odotus, and by the Biblical narrative contained in the book of Jonah. Parallel narratives of a man being swallowed by a sea monster were quot- ed from Greek, Polynesian, and Cherokee lore. The belief in the magical and apotropaic properties of the fish was 172 proceedings: anthropological society also found to be widespread. The fish was generally considered as a being of good omen, benevolent and beneficient toward man, and by reason of its own great fertility it was a symbol of increase and abun- dance. Various regions had their favorite species of fish which were endowed with supernatural qualities. Thus among the classical na- tions the dolphin was termed the "saviour fish" (piscis salvator). In the Far East (China and Japan) the carp was the fish of good omen, while among the ancient Irish the salmon was the "fish of wisdom," the mere sight of which brought healing. Dr. Swanton introduced the discussion of the paper by calling at- tention to the fact that migrations of Indians were influenced largely by the food supply. Thus many tribes of Indians followed the rivers and streams because of the presence of fish. Dr. Michelson men- tioned the legend of a miraculous fish among the Delaware Indians, and also noted a similarity between the ancient beliefs concerning the fish and those held by the North American Indians. Mr. E. T. Wil- liams spoke on the use of the fish in Japan and China, the latter country considering it martial in character because of its fearlessness in pro- ceeding against the current of a stream, and also because of its scales, which suggest a coat of mail. Frances Densmore, Secretary. JOURNAL OF THE WASHINGTON ACADEMY OF SCIENCES Vol. VII APRIL 4, 1917 No. 7 MATHEMATICS. — Note on multiple algebra: The reduction of real dyadics and the classification of real homogeneous strains. Edwin Bidwell Wilson, Massachusetts Institute of Tech- nology. (Communicated by Arthur L. Day.) 1. About ten years ago I printed an account of some parts of Gibbs's course of lectures on multiple algebra.1 In the classifi- cation, or reduction to a canonical form, which was there estab- lished for dyadics no attention was paid to distinctions between real and imaginary. I had in mind at that time to give the ex- tension of Gibbs's work in Vector Analysis2 needed to obtain the reduction of real dyadics to type forms, but did not publish my results. I desire now to show how the algebraic methods used by Gibbs to find the general classification lend themselves immediately to the further subdivision relative to reality. The sort of dyadic under consideration is (p. II):3 $ = a | a0 + (3 | 0° + . . . , where the antecedents a, 0, . . . are ordinary vectors and the consequents a0, 0°, . . . are (n-1) -dimensional vectors in n- dimensional space. (The vertical bars serve as separators and 1 Wilson*, Edwin* B. On the theory of double products and strains in hyper- space. Trans. Conn. Acad. Arts Sci., 14: 1-57. 1908. 2 Gibbs-Wilson. Vector Analysis, pp. 356-367. 3 The page numbers in the text refer to the memoir cited in Note 1. I here use an upper zero instead of a dash over a letter to represent an (n-l)-vector. 173 174 WILSON: REDUCTION OF REAL DYADICS have no connection with Grassmann's Erganzung.) The only kind of multiplication used in the work is the (progressive or regressive, single or multiple) combinatory product. That means that we work with the affine, not with the metric, group of linear transformations with one point fixed, i. e., with homo- geneous strains. 2. The essential steps in the reduction of a dyadic are these: (a) As there are only n2 independent dyads, any dyadic must satisfy a polynomial equation, with numerical coefficients, of degree not exceeding n-. Hence any dyadic satisfies an equation A O) = $m + ci$w_1 + . . . + cm_x 3> + cm 7=0 of lowest degree, I being the idemfactor. This equation is unique for if there were two of like lowest degree, their difference would be of lower degree (pp. 15-16.) (6) As any dyadic is homologous (commutative in multipli- cation, p. 14) with its powers and with I, the equation of lowest degree may be factored in the form: A ($) = ($ - aiy ($ - biy ($ - ciy . . . = o identical with that obtained in factoring the ordinary polynomial A (x) = xm + d xm~l + . . . + Cm_! X + cm = (x - a)p (x - b)q (x - c)r . . . =0. (c) If we set (p. 26) $ - al = ¥, * - bl = ¥ + (a - b) I, - cl = * + (a - c) I, . . . and if we divide (by the ordinary algorism of long division, which is applicable here) the expression (?-bI)q(*-cI)r . . . =AI+B*+ . . . +H*q+r+--- into I, we have the result ^I + B'^ + .-. + G'^-1 + AI +B* + ... + HVn-p where P is a polynomial of degree m — p - 1. Next, let (p. 27) WILSON: REDUCTION OF REAL DYADICS 175 /. ={AI +B*+ . . . +H*"1'13) (±-I+Bf*+ . . . +GV-1) = l-pp O) with similar expressions for Ib, Ic . . . . corresponding to each of the roots b, c, . . . . The dyadics Ia, Ib, . . . are partial idemfactors, their squares are equal to themselves, they are independent, the product of two having different subscripts vanishes (Ia Ib '= 0) , and the sum of all is the idemfactor I. (d) The dyadic may be written as a sum of terms (p. 28) $ = $/ = $ {Ia + Ib + . . . ) = $B -f- 6- + $c + . . . where the product of any two vanishes ($a $6 =0). The dy- adics ^ a ^a **-* a j • • • j are nilpotent, i. e., Z„ = 0. The series of powers (p. 29) Za, Z~a, . . . , Za , Za = 0 have increasing nullities, but the change of nullity between two succeeding powers never increases. The reduction of $ has thus been simplified to that of nilpo- tent dyadics Z. Beginning with Zv~l we may work back through descending powers to Za and hence to 3>a. We thus find the familiar result that, when expressed in matrical or quadrate form, $ consists of a set of terms along the main diagonal, with at most some terms in the next parallel partial diagonal (called shearing terms, p. 31). 3. What additional information is obtainable if the dyadic is real? The steps in the proof may be traced one at a time. (a1) The equation of least degree must be real since it is unique — a complex equation is equivalent to two. (&') The complex roots of A (x) = 0 occur in conjugate pairs of the same multiplicity. Hence if a and b are conjugate imag- inaries, p and q are equal. (c') If a and b are conjugate imaginaries, so are 3> — al and $ — bl, and hence so must be Ia and Ib, for they are obtained by similar real operations applied to conjugate imaginaries. 176 WILSON: REDUCTION OF REAL DYADICS (d') If a and b are conjugate, so are $0 and $&, and Za and Zb. If Zo is reduced to a certain standard form, one form of the con- jugate imaginary dyadic Zb will be that in which each vector (antecedent or consequent) and each scalar in Za is replaced by its conjugate value. Hence the types of Za and Zb or of <£>a and <£& must be identical relative to the distribution of shearing terms. The results thus obtained allow us to set up canonical forms for real dyadics which have imaginary latent roots. As the ante- cedents a, /3, ... of the dyads occur in conjugate imaginary pairs, the consequents which form the reciprocal set a , /3', . . . (p. 8) also occur in conjugate imaginary pairs (since they are ob- tained by multiplication and division). If there is a pair of simple roots, the corresponding terms in the reduced form of the dyadic are a a \ a + b /3 | $' where a' a = 0' 0 = 1, a /3 = p' a = 0, owing to the relations between reciprocal sets. We may write a = a{ + a2i b = ax — a2i a = «! + a2 i j3 = a{ — a2i I 0 0 „• al 0 I 0 • with the reciprocal relations yielding o i o i o on «l aj -f- a2 a2 = 1 «i a2 — a2 ax = U &i «j — a2 oc2 = U «i «2 "T «2 ai = " when real and imaginary parts are separated. Hence o o n ooi If we set a[= 2a°u a2= 2a°2, the sets a, /3, . . . and a', /3', . . . may be replaced byaba2, . . . and a{, a2, . . . On multiplying, the terms a a \ a + b p | j3' give aiai I <*i + %*i | a2 s COS0 ax | a[ + S sin0 ax \ a!2 i or a2a2 I a i+ «i«2 I «2 — S Sin0 a2 \ a\ + S COS0 a2 | a2 if a = se*. This is precisely of the Gibbs cyclotonic form, as might have been anticipated. The linear transformation or strain is a combination of stretching with elliptical rotation.4 4 An elliptical rotation of angle q is a projection of an ordinary rotation of angle q. See Vector Analysis, p. 349. WILSON: REDUCTION OF REAL DYADICS 177 The proof here given differs radically, however, from that given by Gibbs5 for the simple three dimensional case; it applies, moreover, to any pair of conjugate latent roots, simple or not, when shearing terms are absent. In case there is a double complex root with shearing, the terms in the reduced complex form of the dyadic are aa | a + ay \ y' + a \ y' + bj3 \ $' + 65 | ti + 0 | ti Multiplication shows that the corresponding real form is, in matrical notation, as follows: s cos 9 s sin 0 1 0 — s sin 6 s cos 6 0 1 0 0 s cos 6 s sin 6 0 0 — s sin 6 s cos d The extension to the case of multiple roots with various shearing terms is clear. In the matrix there are two-rowed determinants strung along the main diagonal all alike; and parallel to the main diagonal there are strung along with any distribution (depending on the distribution of the original shearing terms) two -rowed determinants, all alike, and of the special form shown above; all other places are filled with zeros. The transformation in the case of multiply complex roots with shearing might be called a cyclotonic shear. It consists of a stretch and of an elliptic rotation in a series of planes Pi, P2, . . . , Pa-ij Pk} the angles of rotation and the factors of stretching being the same for all, combined with a shift of the points in PA+1 parallel to Ph for at least some values of h. The amount of the shift is typical of the shear. For instance, in the case of a triple complex root with double shearing the vector p = Xay + ya2 + 27i + ^72 + ^«l + ^«2 suffers, in addition to the stretch and elliptical rotation, the shift + Zcti + Wa2 + M7i + #72 • ' Gibbs-Wilson. Vector Analysis, p. 360. 178 LARSEN AND WHERRY: HALLOYSITE FROM COLORADO MINERALOGY. — Halloijsite from Colorado? Esper S. Lar- sen, Geological Survey, and Edgar T. Wherry, National Museum. In the upper workings of the fluorite mine at Wagon Wheel Gap, Colorado, two amorphous hydrous aluminium silicates have been recognized which agree more or less closely with halloy- site as defined by Dana but differ from one another considerably in water content. One has essentially the composition of kao- linite, but is for the most part sensibly isotropic and has the index of refraction 1.557. It occurs in rather large amount as TABLE 1 Analyses and Theoretical Composition of Halloysite 1 2 3 4 A1203 35.75 tr. 0.80 tr. tr. 0.10 39.95 8.55 2.15 12.85 35.41 tr. 0.73 tr. tr. 0.09 40.22 8.66 2.10 12.91 35.58 tr. 0.77 tr. tr. 0.10 40.09 jlO.73 12.88 34.66 Fe203 CaO MeO K20 Na20 Si02 40 90 H20 below 100° H20 100°-400° 12.22 H20 above 400° 12.22 Total 100.15 100.12 100.15 100.00 1 and 2. Analyses of halloysite. 3. Average of 1 and 2. 4. Theoretical for A1203 . 2Si02 TABLE 2 Loss of Water by Halloysite2 TEMP. °c PER CENT LOSS TOTAL 20 Started 30 6.40] 40 0.90 50 0.75 • 8.60 60 0.50 100 0.05 110 0.00 150 0.10] 200 0.40 I 2.10 300 0.60 400 1.00 Ign. 12.90 12.90 2H20 . 2Aq. the matrix in which the mineral creedite is imbedded and has been called "isotropic kaolinite."3 The other contains more 1 Published with the permission of the Director of the U. S. Geological Sur- vey and of the Secretary of the Smithsonian Institution. 2 Lowenstein (Zeit. Anorg. Chem., 63: 88-101. 1909), found that halloysite from Laurium, Greece, lost 21.4 per cent H20 at 110°-130° or over 97 per cent H2SO4, and 6.2 per cent above 130°, but most halloysites cited by Dana behave like the one here described. 3 Larsen, Esper S., and Wells, Roger C. >Some minerals from the fluorite- barite vein near Wagon Wheel Gap, Color do. Proc. Nat. Acad. Sci., 2: 360. 1916. LARSEN AND WHERRY: HALLOYSITE FROM COLORADO 179 water, and is less abundant, forming a matrix for nodules of geark- sutite. It is white and opaline to dull in appearance, and has a hardness of about 2. Under the microscope it is isotropic and has a variable index of refraction, averaging about 1.470 ± 0.010 when first examined, but increasing to 1.542 after standing for six months in a loosely stoppered bottle in a warm room.4 Analysis (by E. T. W.) yielded the results shown in Table 1. TABLE 3 Change in Optical Properties of Halloysite with Loss op Water TOTAL HISTORY OF MINERAL H20. (approx.) OPTICAL CHARACTER n. per cent As first examined, two 25 Isotropic 1.470±0.010 months after collecting After standing six months 20 Isotropic 1.542 ±0.005 in a loosely stoppered bottle Heated for four hours to 15 Isotropic 1.555±0.003 65°C. This has the composition and index of the "isotropic kaolin- ite," which is evidently only a halloysite low in H20 Ignited powder, after 0 Partly isotropic but part- 1.541±0.003 standing one month ly birefracting due to strain; clouded Powder ignited, quickly 0 In large part isotropic but cooled, and immersed in some fragments have 1.535±0.005 index medium (organic birefringence of 0.01, liquid of known n) with large axial angle 4 Two halloy sites represented by analyses A and B of U. S. Geol. Survey Bull. 591 : 341, were examined microscopically for comparison. That represented by analysis A, from Horse Cove, Hart County, Kentucky, is pale pinkish in color and opaline in appearance. Much of it is weakly birefracting and large areas extinguish much as a unit but with a wavy effect, probably due to strain. The index of refraction is about 1.549 =*= 0.003. The halloysite represented by analy- sis B, from Edwards County, Texas, is chalky in appearance, largely isotropic, and has an index of refraction of 1.556 ="= 0.003, but contains admixed a consid- erable amount of birefracting kaolinite. However, to what extent their indexes have changed since analysis is unknown. 180 oberholser: a new family of passeriformes The water determinations (Table 2) were made by heating coarse powder in a covered platinum dish. The powder not used was kept for three months in a small vial in a balance case in which the air was dried with sulfuric acid, and was then found to have lost spontaneously 5 per cent of water. Obviously, the water in halloysite is in part only mechanically held. This part is given off very readily, and the resulting partially dehydrated material has a composition near that of kaolinite. The formula should therefore probably be written Al2O3.2SiO2.2H2O.Aq. The effects of the loss of water on the optical properties are shown in Table 3. The close approach of this and many other analyses of halloy- site to the composition Al203.2Si02.2H2O.Aq, combined with the results of optical examination given above, indicates that the material called halloysite is the amorphous mineral correspond- ing to crystalline kaolinite, holding through capillarity or adsorp- tion more or less excess water. ORNITHOLOGY. — Diagnosis of a new laniine family of Passeri- formes. Harry C. Oberholser, Bureau of Biological Sur- vey. The peculiar shrike-like Madagascar genus Tylas has commonly been considered a member of the family Pycnonotidae. This disposition has probably been due to its nuchal hairs, and to the character of its external nares, which in general resemble those of the genus Otocompsa. As Mr. W. P. Pycraft has recently shown,1 this genus is really not closely allied to the Pycnonotidae. Neither is it a member of the Prionopidae, to which family Mr. Pycraft has proposed to refer it, apparently for want of a more satisfactory place. While in some osteological respects it resembles the Prionopidae, it has also resemblances to the Muscicapidae, and, on the whole, pre- sents a very curious combination of characters, a condition re- flected in the difficulty authors have had in referring it to the proper family. That it does not belong in the Prionopidae is at once evident 1 Proc. Zool. Soc. Lond., 1907, p. 376. michelson: terms of relationships 181 from the structure of the narial capsule alone, which in the latter group is fully ossified as in the Laniidae, leaving no external nasal fossa. Since there is no other family to which the genus Tylas is properly referable, it becomes necessary to provide one for its accommodation, as follows: Tylidae, fam. nov. Family characters. — Bill relatively slender and thrush-like, the culmen rather sharply ridged, the gonys rounded and but slightly and gradually ascending, the culmen straight for its basal half, gently decurved terminally; mental apex opposite anterior end of nostril; maxilla conspicuously hooked at tip, the commissural edge notched subterminally; nostril rather small, oval, non-oper- culate, exposed, and situated in the anterior end of nasal fossa; nasal capsule not ossified; feathering of forehead covering only basal portion of nasal fossae; narial bristles rather weak, but reaching to middle of bill; rictal bristles well developed; head entirely feathered; nuchal hairs present but short; tail moder- ately long, making up somewhat less than half the total length of the bird, square or slightly emarginate, and composed of mod- erately broad, stimsh feathers; wings much longer than tail but much rounded, the first (outermost) primary spurius, but more than half as long as the next, and neither secondaries nor tertials lengthened; feet and legs of moderate size and length; tarsi scu- tellate; femur pneumatic; ectepicondylar process of humerus much reduced. The genus Tijlas Hartlaub, comprising the following five species, constitutes this monotypic family : Tylas eduardi Hartlaub ; Tylas alfredi Sharpe; Tylas albigularis Hartlaub; Tylas fulviventris Sharpe; Tylas strophiatus Stejneger. ANTHROPOLOGY. — Remarks on terms of relationship.1 Tru- man Michelson, Bureau of American Ethnology. Some years ago Kroeber2 undertook to show that terms of re- lationship are linguistic and psychological phenomena. Re- 1 Published with the permission of the Secretary of the Smithsonian Institu- tion. 2 Journ. Roy. Anthrop. Inst. Gr. Brit, and Irel., 39: 77-84. 1909. 182 michelson: terms of relationships cently Rivers3 has attempted to overthrow this view, holding that they are sociological phenomena, and consequently that it is entirely possible to infer marriage customs and social organi- zation from these terms. Lowie4 to a certain extent followed Rivers but has not followed the latter's survival-theories, nor is it likely that many American ethnologists will do so.5 The pres- ent writer6 developed Kroeber's linguistic thesis from a different angle, and also made a new point, namely, that terms of rela- tionship are likewise disseminative phenomena. Specific data from Algonquian tribes were given to establish these facts. Lowie,7 some months later, but quite independently, arrived also at this second theoretic position but extended the principle more broadly than the present writer had done. It is not without interest to note that we both assume that Iroquoian and Siouan influence has played a part in Algonquian terms of relationship. Sapir8 briefly touches upon the methodological considerations and con- cludes that thoroughly satisfactory results can not be secured without linguistic analysis of kinship terms; that existing no- menclature may be retained in the face of sociological develop- ments requiring its modification; that the factors governing kin- ship nomenclature are very complicated. Goldenweiser,9 in his review of Rivers' History of Melanesian Society, says, UA set of terms must always remain a feature of language and as such it is subject to those influences which control linguistic changes as well as to the peculiar spirit of a particular language or linguis- tic stock." The present writer10 has shown what extraordinary types of marriage we should have to assume existed formerly among the Piegans, were we to believe that marriage customs 3 Kinship and Social Organization, 1914. The History of Melanesian Society, 1914. 4 Proc. Nat. Acad. Sci., 1: 346-349. 1915. Amer. Anthrop. n. ser., 17: 223- 239, 329-340, 588-591. 1915. 5 Webster (Amer. Anthrop., n. ser., 17: 175-177. 1915) is an isolated exception. 6 Proc. Nat. Acad. Sci., 2: 297. May, 1916. 7 Holmes Anniversary Volume, 293. December, 1916. 8 Amer. Anthrop., n. ser., 18: 327, footnote 1. 1916. 9 Science, n. ser., 44: 826. 1916. 10 Holmes Anniversary Volume, 333. 1916. michelson: terms of relationships 183 might safely be inferred from terms of relationship ; whereas such marriages are fundamentally repugnant to the Piegans, and their terms of relationship are new, not old. This is, of course, a con- crete example of one of Sapir's points. Recently Swanton" quite similarly brings forward data from Creek and Chickasaw which prove the unsoundness of such inferences. The above has been cited to show that American ethnologists generally have taken a united stand against Rivers' one-sided attitude. I reopen the case because none of us has given abso- lute proof that kinship terms are borrowed. In another place'2 I have tried to prove that Cree has borrowed certain terms from Ojibwa; and somewhat similarly that Peoria has been influ- enced by Sauk, etc. I think the reasoning given there is sound, and as near absolute proof as we can expect to have in the case of prehistoric linguistic borrowing ; yet it is not absolute in so far as we have no Cree nor Ojibwa records transmitted to us his- torically, extending over several centuries, showing absolutely that such borrowing took place. The same is true regarding Peoria. English is a good language to draw on for illustrative material to prove such a point, for it has been transmitted his- torically for several centuries. Every Indo-European philolo- gist knows that sister is Scandinavian in origin, and that cousin, niece, nephew, aunt, and uncle are Romance. Furthermore all our terms of -in-law are directly or indirectly due to the latter's influence; grand-father and grand-mother are Romance in the first member of their compounds. Similarly Albanian frat " brother" is Romance in origin and is not a native word, as is shown by the phonetics. In the same way Hungarian bar at " brother" is borrowed from Slavic, a case of borrowing across linguistic stocks. [Ojibwa nimpdpa, nimdrnd (Fort William) are other illustrations of kinship terms borrowed across linguistic stocks.] These facts, long known, are brought forward simply because they seem to have escaped the attention of ethnologists. Delbriick13 was well aware of the fact that Indo-European terms of relationship 11 Amer. Anthrop. n. ser., 18: 463. 1916 [1917]. 12 Proc. Nat. Acad. Sci., 2: 297. 1916. 13 Die Verwandtschaftsnamen. Leipzig. 1889. Also in Abh. phil.-hist. Klasse sachs. Ges. Wiss., 11: 379. 1889. 184 michelson: terms of relationships are linguistic phenomena. Several terms that correspond pho- netically occur in so many Indo-European languages that it is evident they belonged to the Indo-European parent language. The social organization of the peoples speaking the historical languages had nothing to do with it, as is shown by their diverse social organization. Nor can it be said that such German com- pounds as Schwieger-mutter, Schwieger-vater, Schwieger-tochter have replaced the Old High German words by reason of a change in social organization. Similarly, the fact that the Slavic word for " father" (Old Bulgarian oibcb) has a different termination than Greek arra, Gothic atta, is of linguistic significance, not sociological. These data support my contenion referred to pre- viously.4 Let us return once more to Rivers' position. On looking over the tables given at the end of volume 1 of Rivers' History of Melanesian Society, I am convinced that after all, he may have just as much a linguistic and disseminative problem as a sociologi- cal one. For example, the social organization of Mota, Banks Islands, and Eddystone, Solomon Islands, is entirely different; nevertheless the terms for father, elder brother, and younger brother are evidently the same. Furthermore, the distribution of slightly varying forms of the words tama, Una (father and mother respectively) even across linguistic stocks, points in the same direction. As I am not a specialist in Melanesian and Polynesian linguistics, I regret that I can not thresh this out to the end, and can only indicate a problem for others to solve. ABSTRACTS Authors of scientific papers are requested to see that abstracts, preferably prepared and signed by themselves, are forwarded promptly to the editors. Each of the scientific bureaus in Washington has a representative authorized to forward such material to this journal and abstracts of official publications should be transmitted through the representative of the bureau in which they originate. The abstracts should conform in length and general style to those appearing in this issue. GEOLOGY. — Contributions to the geology and 'paleontology of San Juan County, New Mexico. 2. Vertebrate faunas of the Ojo Alamo, Kirtland, and Fruitland formations. Charles W. Gtlmore. U. S. Geological Survey Professional Paper 98-Q. Pp. 279-308, with 8 plates and 13 figures. 1916. The known vertebrate fauna of the dinosaur-bearing beds in the San Juan basin in northern New Mexico consists of a considerable number of genera and species. The dinosaur-bearing deposits are subdivided into three formations — the uppermost, or Ojo Alamo, the Kirtland, .and the Fruitland. No mammal, bird, or amphibian remains have yet been recorded from these formations. The dinosaurs were apparently the predominating vertebrates of these times, and they afford the best basis for a comparison with forms found elsewhere. The vertebrate remains from the Ojo Alamo, Kirtland, and Fruitland formations show beyond all question that they pertain to a fauna or faunas distinctly older than that of the Lance, and such evidence as there is contributes to the support of the contention that the Ojo Alamo sandstone is syn- chronous with the Judith River and Belly River formations as found in areas to the north. R. W. S. GEOLOGY. — Contributions to the geology and -paleontology of San Juan County, New Mexico. 3. Nonmarine cretaceous invertebrates of the San Juan basin. T. W. Stanton. U. S. Geological Survey Pro- fessional Paper 98-R. Pp. 309-326, with 5 plates and figures. 1916. Overlying the Pictured Cliffs sandstone with apparent conformity in the San Juan basin and underlying the Puerco formation is a group of nonmarine sediments, coal bearing in the lower part, which in many previous reports have been referred more or less doubtfully to the Lar- amie formation. The rocks occupying this interval are fully described 185 186 abstracts: geology and a considerable area of them is mapped in a stratigraphic paper by C. M. Bauer, who recognizes in them three formations, the Fruitland formation containing all the coal beds at the base, the Kirtland shale in the middle, and the Ojo Alamo sandstone at the top. The inverte- brates, which form the subject of the present paper, nearly all come from the Fruitland formation. The list of species shows that the nonmarine invertebrates of the Fruitland formation include both a fresh-water fauna and a brackish- water fauna. The fresh-water fauna is especially notable for the greatly varied development of the genus Unio and for the abundance and considerable variety of the gastropods. The invertebrate evidence as a whole favors the assignment of the Fruitland formation to an epoch considerably later than Mesaverde and Judith River, and possi- bly somewhat earlier than Lance. The Fruitland can hardly be older than Fox Hills, and the sequence from the base of the Fruitland up to the top of the Ojo Alamo, which is conformable, may include the equivalents of everything from the Fox Hills to the Lance inclusive. R. W. S. GEOLOGY. — Contributions to the geology and paleontology of San Juan County, New Mexico. 4- Flora of the Fruitland and Kirtland for- mations. F. H. Knowlton. U. S. Geological Survey Professional Paper 98-S. Pp. 327-353, with 8 plates and figures. 1916. The object of the present study is to ascertain the bearing of the fossil plants on the age of the series of coal-bearing and related rocks in San Juan basin, New Mexico. A brief historical setting for the geologic facts is given. The material on which the present report is based comprises 20 collections, of which 15 are from the Fruitland for- mation, 3 from the Kirtland shale, and only 1 from the Ojo Alamo sandstone. The bulk of the material comes from the lower or coal- bearing portion of the section, and much of this is preserved on a red baked shale, indicating proximity to coal. Of the 40 forms making up the known flora of the Fruitland and Kirtland formations, 16 have been found in other areas, and the list of these forms brings out the fact that no less than 15 are known to occur in the Montana. A further analysis of the list shows that 12 of the 15 forms occur in the Vermejo formation of Colorado and New Mexico, 10 occur in the Mesaverde, or rocks of about this age, in Wyoming and elsewhere, and 6 species are common to both these areas. On the basis of this showing the con- clusion that the Fruitland and Kirtland formations are of Montana age, seems justified. R. W. S. abstracts: phytopathology 187 PHYTOPATHOLOGY. — Mechanism of tumor growth in crown gall. Erwin F. Smith. Journ. Agr. Research, 8: 165-186, plates 4-65. 1917. This paper, with its wealth of illustrations, records the results of a series of experiments testing the effects of various fluids and vapors on plants, undertaken for the purpose of shedding light on the mechan- ism of tumor growth in crown gall. As a result of these studies the author has come to look upon excessive cell proliferation as it occurs in plant neoplasms as due, not to the direct application of stimuli such as endotoxins and other by-products of the growth of the parasite within the host cells, but to their indirect action as the removers of inhibitions. Growth is the normal function of cells but under normal conditions is alwa3^s inhibited beyond a certain point. In the case of neoplasms we have an "inhibition remover that acts locally, dis- turbing tissue equilibriums within limited areas." The author believes, furthermore, that this removal of growth inhibitions is not (or not wholty) due to a chemical action but partly at least to a physical one — ■ viz., a locally increased osmotic pressure produced by the diffusion from the cells of various substances produced within them by the parasite as a result of its metabolism, together with the resultant coun- ter movements of water and food supply, basing this belief upon the researches of Jacques Loeb in artificial parthenogenesis and fertiliza- tion, and on the results of his own experiments. The substances produced by Bacterium tumefaciens in culture media containing dextrose, Witte's peptone, calcium carbonate, and water are ammonia, alcohol, acetic acid, formic acid, amines, aldehyde, and acetone. With several of these compounds, the author produced intumescences (both hypertrophic and hyperplasial) without the in- tervention of the organism itself. In addition to obtaining small tumors with crown-gall products (ammonia, dimenthylamine, and acetic acid) the author obtained overgrowths with a great variety of other substances; hence his conclusion that the response must be physi- cal rather than chemical, i.e., due to removal of water from cells, which then divide. The plants used were the castor-oil plant (Ricinus communis), to- mato fruits, and cauliflower. The substances tested were injected hypodermically (Ricinus and tomato), placed in tiny open tubes in- serted in the pith cavity (Ricinus, the wound being sealed with col- lodion or adhesive tape), or vaporized in a tight box containing 10.5 cubic feet air space in which the plants (cauliflower) were placed for a 188 abstracts: phytopathology few minutes. The substances tested were ammonia water, the various salts of ammonia, distilled water solutions of the acid component of these salts, distilled water, 10 per cent tannic acid, 10 per cent ethyl alcohol, 2 per cent sodium chlorid, 2 per cent sodium carbonate, 5 per cent sodium bicarbonate, 1/20 normal sodium hydroxid, 5 per cent am- monium bicarbonate, clear lime water, milk of lime (caustic), 1 to 10,000 mercuric chloride, 0.5 per cent carbolic acid, chloroform water, 1 to 1,000,000 copper sulphate water, 5 per cent grape sugar, 5 per cent cane sugar, and feeble alkaline vapors arising from dilute solu- tions of urea, ammonium carbonate, and the two ammonium phos- phates, the mixed vapors of ethyl alcohol and acetic acid, and the vapor of secondary methylamine. With all these substances, even distilled water, proliferations were obtained, but no killing of cells resulted except in the case of those coming into direct contact with too strong a solution. In Ricinus when ammonia was applied, the outgrowths were from the inner surface of the pith cavity, and occurred not only in the internode containing the chemical but in several to many others above and below. Exclusive of the hyperplasia which appeared when vapor of acetic alcohol was used, one of the most striking effects obtained was the production of a stele within a stele in the pith of Ricinus by the in- jection of monobasic ammonium phosphate, and evidences of simi- lar tendencies when ammonia was used. These facts together with the author's very successful production of teratoid tumors with Bac- terium twnefaciens lead him to believe that fasciations and many similar phenomena are due to feeble infections by micro-organisms. From these experiments the author concludes "that any soluble substance whatsoever, except a killing, a plasmolyzing, or an oxygen- absorbing substance, if continually liberated in excess locally in tis- sues not adapted to them would be able to induce tumor formation, and is convinced that had it been possible to apply these stimuli re- peatedly, or better still, slowly and continually from within the cell — as does the parasite in crown gall — these striking proliferations would have developed into large irregular tumors, rupturing to the surface, i.e., into typical crowngalls. It is believed that this is the first time that galls have been produced with the chemical products of a gall- forming organism. The nature of the crown-gall products were de- termined for Doctor Smith by the Bureau of Chemistry of the United States Department of Agriculture from flask cultures set and con- trolled by him. F. H. PROCEEDINGS OF THE ACADEMY AND AFFILIATED SOCIETIES THE PHILOSOPHICAL SOCIETY OF WASHINGTON The 784th meeting was held at the Cosmos Club, February 17, 1917, President Buckingham in the chair; 69 persons present. The minutes of the 783rd meeting were read in abstract and approved. By invitation, Mr. H. Bateman presented an illustrated paper on The nature of chemical forces. Sir Joseph J. Thomson's idea1 of regard- ing chemical bonds as symbols for Faraday tubes may be developed successfully by considering solutions of Maxwell's electromagnetic equations in which the electric and magnetic forces become infinite on moving singular curves. We must first of all try to understand the nature of potential energy and so we shall commence by studying the properties of a type of radiant field with singular lines starting from the origin and running in both directions along the axis of z. The electric force E and the magnetic force H being specified by expressions of type Hx+iEx=f{a,^^V) Hy+iEy=f(a,p) d (y, z) d (a, 0) d fo x) (l) where a = t - -, 0 = log x+iyj r°- = x2 + y2 + z2 it is easy to see that there is a radial flow of energy outward from the origin. The origin 0 may be regarded as a source or singular point at which neutral particles are continually breaking up into oppositely charged fragments which travel along the axis of z in opposite direc- tions with the velocity of light. Two neighboring sources 0 and 0' whose singular lines overlap can produce radiant fields which interfere with one another in such a way that in the total field the only singularities lie in the interval 00'. This can be seen very readily by differentiating the expressions (1) 1 The corpuscular theory of matter. Constable, London (1907). Phil. Mag., May. 1914. 189 190 proceedings: philosophical society with respect to z after putting /(a/3) = 1 and writing down the values of the Jacobians. In particular, if the strengths /(a/3) of the two sources are constants which are equal in magnitude but different in sign, then as 0 and 0' approach one another the total electromagnetic field is in the limit equivalent to the electrostatic field of a point charge, the magnitude of the charge being the limit of the product 00' and the strength of one of the sources. The potential energy of an electro- static field can thus be supposed to arise from the individual and mutual energies of two interfering radiant fields whose singular lines overlap. When the strengths of the two consecutive sources 00' are not con- stant and not equal in magnitude, we obtain a type of electric point charge with two singular lines attached to it, the charges on the two lines being generally variable and together equal and opposite to the variable charge associated with the singular point. The case in which the charge on each singular line is the same is of chief interest. Interference, or a cancelling out of singularities, can also be obtained with two point charges of this general type even when they are at a finite distance apart, provided their singular lines overlap. There must also be a simple relation between the magnitudes of the two charges at associated times; this indicates that it may be possible to give a mathematical proof that the mean value of the electronic charge is the same for all electrons. It is thought that this phenomenon may have some relation to chemical saturation. The present theory may be extended to the case in which the sources or point charges are mov- ing and the singular curves are not straight lines pointing in opposite directions but are moving and changing in shape. The appropriate solution of Maxwell's equations is again of the type (1) but a and /3 are now defined by the equations. [X ~ *(«)]' + [y - V («)? + [«-$■ («)]2 = C2 [t - af, a• c c 0 o o kJ : 2- on v 2 O ® cucO J) c ID O O Id ID -C O' ID J