3 a ip ayia: RR Re ie iy ie hs NMA A, THE MANURES MOST ADVANTAGEOUSLY APPLICABLE TO THE VARIOUS KINDS OF SOILS, AND THE CAUSES OF THEIR BENEFICIAL EFFECT IN EACH PARTICULAR INSTANCE. eseeesgeeeeAGoneus Patriz, sit Utilis Agris. Fur. Sat. 14. 6; ae eaERT TG ance ) ae A : = “O93 “see | j BY RICHARD KIRWAN, Esa F.R.8.& M.R.I. A. Author of the Elements of Mineralogy, Gc. FROM THE SIXTH LONDON EDITION. PHILADELPHIA: PriInTeD By KIMBER, CONRAD, anp CO. No. 95 MARKET STREET, & 170 souTH SECOND STREEI s. 1807 a ‘eof Yea ARR, otk 28) Beh et aie en ee ie a ei i . titi % er ae ot 10 aT “2 2 . WHAT ARE THE MANURES MOST ADVANTAGE- ° OUSLY APPLICABLE TO THE VARIOUS SORTS OF SOILS; AND, WHAT ARE THE CAUSES OF THEIR BENEFICIAL EFFECT IN EACH PARTICULAR INSTANCE. —— = smal Idoneus Patriz, sit Utilis Agris. JUVEN, SAT. 14. AGRICULTURE is the art of mak- ing the earth produce the largest crop of useful vegetables at the smallest expense. It has often been remarked, that amidst the various improvements which most of the practical arts have derived from the progress lately made in natural philosophy and chemistry, none have fallen to the share of agriculture, but that it remains nearly in the same state in which it existed two thousand years ago. I am far from allowing the truth of this observation, taken +h im its totality ; to refute it, we need only compare the writings of Cato, Columella, or Pliny, with many modern tracts, or still better, with the modern practice of our best farmers. It must be granted, how- ever, that vague and fortuitous experience has contributed much more to the present Hourishing state of this art than any gene- ral principles deduced from our late ac- quired knowledge, either of the process. of vegetation, or of the nature of soils; but the skill thus fortuitously acquired is necessarily partial, and generally local; the very terms employed by the persons who most eminently possess It, are gene- rally of a vague and uncertain significa- tion. Thus Mr. Young, to whose labours the world is more indebted for the diffu- sion of agricultural knowledge than to any writer who has as yet appeared, re- marks, That in some parts of England, where husbandry ts successfully practised, any loose clay 1s called marl* ; 1n others, marl is called chalk}+ ; and, in others, clay is called loam t. Philosophic researches have been made, but not yet sufficiently noticed: muchi nformation may be derived from. Monsicur Du Hamel, and much more from the well-directed experiments of * First Eastern Tour, 178. + 2 Bath Mem. 192, 220. + 2 Bath Mem. 137. 5 Mr. Tillet*. Immense strides have been made in this career, by the illustrious Berg- man; Dr. Priestley’s experiments have thrown a new light on this, as well as on every other object of natural philosophy. Mr. Lavoisier’s new theory explains ma- ny circumstances, before inexplicable ; discoveries of great importance have been made by Mr. Senebier and Dr. Ingenhouz: even Mr. Young has not always confined his attention to the mere practical part, but sometimes happily extended it to ob- jects of a more general and speculative na- ture; but the fullest light, perhaps, has been thrown on this subject by the late discoveries of Mr. Hassentraz.t If the exact connexion of effects, with their causes; has not been so fully and so extensively traced in this as in other sub- jects, we must attribute it to the peculiar difficulties of the investigation. In other subjects, exposed to the joint operation of many causes, the effect of each, singly and exclusively taken, may be particularly examined ; the experimenter may work in his laboratory with the object always in his view ; but the secret processes of vegeta- tion take place in the dark, exposed to the various and indeterminable influences of * Mem. Par. 1772. * Annales Chymiques, Vul. 13, 14. ? | 6 the atmosphere, and require, at least, half a year for their completion. Hence. the dificulty of determining on what peculiar circumstance success or failure depends ; the diversified experience of many years can alone afford a rational foundation for solid specific conclusions. It cannot there- fore, be expected, that new, decisive, and _ direct experiments should be laid before the Academy within the time prescribed for answering this question. The resolu- tion of the first part must be deduced from a statement of facts long established by multiplied experience ; and that of the se- cond, by the application of more generai principles to the explanation of those facts. —But before we proceed to either branch ‘of this question, the distinctions and denominations, both of soils and ma- © nures, must be exactly settled and accu- rately defined. CHAP "1. OF SOILS AND MANURES+» ES ED SE SECTION f. OF SOILS. LAND, considered as the basis of ve- getation, is called soi. Soils consist of different combinations of two or more of the four primitive earths, namely, the calcareous (which I some- times call mild calx) magnesia, argill, and the silicious. For a more accurate de- scription of these I must refer to books of mineralogy ; and shall only remark, that by calcareous earths are meant chalk, and all stones that burn to lime. They are easily distinguished by their property of effervescing with acids. Magnesia is never found alone; its distinguishing character consists in afford- ing a bitter salt, generally called Epsom Salt, when combined with the vitriolic acid. Argill is that part of clay to which this ewes its property of feeling seft and unc- 8 tuous, and of hardening m fire; it is difficultly soluble in acids, and scarce ever effervesces with them. When combined with the vitrolic acid, it forms alum. S7licious Earth is often found in a stony form, such as flint or quartz; and _ still more frequently in that of a very fine sand, such as that whereof glass 1s made. It does not effervesce, nor is it soluble in any of the common acids. ‘To these we may add Iron, in that im- perfect state in which it exists when reduc- ed to rust, and commonly called Calx of Tron. | The soils most frequently met with, and which deserve a distinct consideration, are clay, chalk, sand, and gravel, clayey loam, chalky loam, sandy loam, gravelly loam, ferruginous loam, boggy soil, and heathy soil, or mountain, as it is often called. Clay is of various colours ; for we meet with white, grey, brownish red, brownish black, yellow or bluish clays; it feels smooth, and somewhat unctuous: if moist, it adheres to the fingers, and if sufficiently so, It becomes tough and ductile. If dry, it adheres more or less to the tongue: if thrown into water, it gradually diffuses itself through it, and slowly separates from it. It does not usually effervesce with acids, unless a strong heat be applied, or 9 that it contains a few calcareous particles, or magnesia. If heated, it hardens and burns to a brick. It consists of argill and fine sand, usually ‘of the silicious kind, in various propor- tions, and more or less ferruginous. ‘The argill forms generally from 20 to 75 per ewt. of the whole mass; the sand and calx of iron the remainder. ‘These are perfectly separable by boiling in strong vitrolic acid. Chalk, if not very impure, is of a white celour, moderate consistence, and dusty surface, stains the fingers, adheres ‘slightly to the tongue, does not harden when heat- ed, but, on the contrary, in a strong heat burns to lime, and loses about four-tenths of its weight. It effervesces with acids, and dissolves almost entirely therein. I shail also add, that this solution 1s not dis- turbed ‘by caustic volatile alkali, as this circumstance distinguishes it from magne- sia,—it prometes putrefaction. Sand. By this is meant small loose erains of great hardness, not cohering with water, nor softened by it. It is gene- rally -of the silicious kind, and therefore insoluble m acids. Gravel difiers from sand chiefly in size: however stones of a calcareous nature, 10 when small and rounded, are often com- prehended under that denomination. Loam denotes any soil moderately co- hesive : that is, less so than clay, and more so than loose chalk. By the author of the Body of Agriculture, it is said to bea clay mixed with sand. Doctor Hill defines it an earth composed of dissimilar particles, hard, stiff, dense, harsh, and rough to the touch, not easily ductile while moist, rea- dily diffusible in water, and composed of sand and a tough viscid clay. The defini- tion I have given seems most suited to the different species ] shall now enumerate. Clayey Loam denotes a compound soil, moderately cohesive, im which the argilla- ceous ingredient predominates. Its cohe- rence is then greater than that of any other loam, but less than that of pure clay. The other ingredient 1s a coarse sand, with or without a small mixture of the calcare- ous ingredient. It is this which farmers generally call strong, stiff, cold, and heavy . loam, in proportion as the clay abounds in it. Chalky Loam. This term indicates a loam formed of clay, coarse sand, and chalk ; in which, however, the calcareous ingredient or chalk much predominates. It is less cohesive than clayey loams. Sandy Loam denotes a loam in which i] sand predominates : it is less coherent than either the abovementioned. Sand, partly coarse and partly fine, forms from 80 to 90 per cent. of this compound. Gravelly Loam difters from the last only in containing a larger mixture of coarse sand, or pebbles. This and the two last are generally called, by farmers, /7ght or hungry soils; particularly when they have but little depth. Ferruginous Loam,or Till. This is generally of a dark brown, or reddish co- lour, and much harder than any of the pre- ceding: it consists of clay and calces of iron, more or less intimately mixed. It may be distinguished not only by its co- lour, but also by its superior weight: it sometimes effervesces with acids, and sometimes not; when it does, much of the irony part may be separated, by pouring it, when well dried, into spirit of salt ; from which the iron may afterwards be separated by alkalis or chalk. ) , Akin to this are certain vé¢rzolic soils, which, when steeped in water, impart to it the power of reddening syrup of vio- lets. These are generally of a blue colour, but. redden when heated. Boggy Soil or Bogs, consist chiefly of ligneous roots of decayed vegetables mix- 12 ed with earth, mostly argillaceous, and sand, and a coally substance derived from decayed . vegetables. Of bogs there are two sorts : the black, which contain a larger proportion of clay and of roots more perfectly decayed, with mineral oil. In the red the roots.seem less perfectly de- cayed, and to form the principal part. Heathy Soil is that which is naturally productive of heath. 13 SECTION II. OF MANURES. Manure denotes any substance or ope- ration by which a soil is improved. To improve a soil 1s to render it capable of producing corn, legumens, and the most useful grasses. The substances principally used as ma- nures, are chalk, lime, clay, sand, mar}, gypsum, ashes, stable-dung, mucks, farm- yard dung, pounded bones, sea- weeds, sweepings of. ditches, old ditches. Other manures or top-dressings, as they are em- ployed chiefly to promote the growth cf vegetables, and not merely with a view of improving the soil, I omit. The operations used to improve soils, are fallows, draining, paring and burning. Of chalk, clays, and sand, we have al- ready treated. Lime is a substance whose external characters and mode of production are well known. It differs from chalk and powdered limestone chieily Van the absence of fixed air, which is expelled from these during their calcination. This air it gree- 14 dily re-absorbs from the atmosphere, and all other bodies with which it comes in con- tact, and which can furnish it; but it can- not unite with the air unless it is previ- ously moistened. 100 parts quick-lime absorb about 28 of water. It is soluble in about 700 parts of this fluid. To re- gain its full portion of air from the atmos- phere, it requires a year or more, if not purposely spread out: it resists putrefac- tion; but with the assistance of moisture, it resolves organic substances into amucus. Marl is of three sorts; calcareous, ar- gillaceous, and silicious or sandy. All are mixtures of mild calx (7. e. chalk) with clay, in such a manner as to fall to pieces by exposure to the atmosphere more or less readily. : Calcareous Marl is that which is most commonly understood by the term Marl, without addition. It is generally of a yel- lowish white, or yellowish grey colour ; rarely brown or lead coloured. It is sel- dom found on the surface of land, but commonly a few feet under it, and on the sides of ‘hills, or rivers that flow through calcareous couniries, or under turf in bogs. Frequently of a loose texture, sometimes mocerately coherent; rarely of a stony hardness, and hence called stone-marl. Sometimes of a compact, sometimes of a 15 lamellar texture ; often so thin as to be called paper-marl. It often abounds with shells, and then is called shell-marl ; which is looked upon as the best sort. When in powder, it feels dry between the fingers ; put in water, it quickly falls to pieces or powder, and does not forma viscid mass. It chips and moulders by exposure to the air and moisture, sooner or later, accord- ing to its hardness and the proportion of its ingredients : if heated, it will not form a brick, but rather lime. It effervesces with all acids. It consists of from 33 to 80 per cent. of mild calx, and from 66 to 2U per cent. of clay. To find its composition. pour a few ounces of weak, but pure spirit of nitre, or common salt, into a Florence flask ; place them in a scale, and let them be ba- lanced ; then reduce a few ounces of dry marl into power, and let this powder be carefully and gradually thrown into the flask, until after repeated agitation no ef- fervescence is any longer perceived; let the remainder of the powdered marl be then weighed, by which the quantity pro- jected will be known; let the balance be then restored; the difference of weight between the quantity projected and that requisite to restore the balance will dis- 16 cover the weight of air lost during effer- vescence ; if the loss amounts to 13 per ewt. of the quantity of marl projected, or from 13 to 32 per cwt. the marl essayed is calcareous marl. ‘This experiment is decisive, when we are assured by the ex- ternal characters above mentioned, that the substance employed is marl of any kind; otherwise some sorts of the sparry iron-ore may be mistaken for marl. The experiments to discover the argillaceous ingredient (being too dificult for farmers). I omit. The residue left after solution, be- ing well washed, will, when duly heated, generally harden into a brick. Argillaceou: Mart contains from 68 to 80 per cent. of clay, and consequently from 32 to 20. per cent. of aerated calx. Its colour is grey or brown, or reddish brown, or yellowish or bluish grey. It feels more unctuous than the former, and adheres to the tongue : its hardness gene- rally much greater. In water it falls to pieces more slowly, and often into square pieces: it also more slowly moulders by exposure to the air and moisture, if of a loose consistence : it hardens when he:t- ed, and forms an imperfect brick. It effer- vesces With spirit of nitre or common salt, but frequentiy refuses to do so with vine- hd gar. When dried and projected into spi- rit of nitre, in a Florence flask, with the attentions above-mentioned, it 1s found to lose from 8 to 10 per cwt. of its weight. The undissolved part, well washed, will, when duly heated, harden into a brick. Silicious, or Sandy Marls, are those whose clayey part contains an excess of sand: for, if treated with acids in the manner above-mentioned, the residuum, or clayey part, will be found to contain above 75 per cwt. of sand; consequently chalk and sand are the predominant ingre- dients. The colour of this marl is brownish eray, or lead coloured: generally friable and flakey. but sometimes forms very hard lumps. It does not readily full to pieces in water. It chips and moulders by ex- posure to the air and moisture, but slowly. It effervesces with acids; but the resi- duum, after solution, will not form a brick. Limestone-Gravel. This is a marl mixed with large lumps of limestone. The marl may be either calcareous or argillace- ous ; but most commonly the former. The sandy part is also commonly calcare- ous. B is Gypsum is a compound of auicarenes earth and vitrolic acid: it forms a distinct species of the calcareous genus of fossils : of which species there are six families. The general character of this species are, 1. Solubzlity in about 500 times its weight of water, in the temperature of 60°. 2 Precipitability therefrom by all mild alkalis, and also by caustic fixed, but not by caustic volatile alkali. 3. Ineffervescence with acids, if the gypsum be pure; but some families of this species, being contaminated with mild calx, slightly effervesce. A. Insolubility, or nearly so in n the ni- trous acid, in the usual temperature of the atmosphere. 5. A specific gravity, reaching from, 2,16 to 2,31. 6. A degree of hardness, such as to ad- mit being scraped by the nail. 7. When heated nearly to redness, it calcines; and if then it be slightly sprink- led with water, it again concretes and har- dens. 8. It promotes putrefaction in a high degree. Of the six families of this species I shall describe only one; namely, that which 19 has been most advantageously employed as a manure. Descriptions of the other five should be found in treatises of mine- ralogy. It is called fibrous gypsum. Its colours are gray, yellowish or red- dish, or silvery white, or light red, or brownish yellow, or striped with one or more of these dark colours. It 1s compos- ed of fibres or striz, either straight or curved, parallel or converging to a com- mon centre, sometimes thick, sometimes fine and subtile, adhering to each other, and very brittle: its hardness such as to admit being scraped with the nail: com- monly semi-transparent ; in some, often ina high degree. Ashes. Sifted coal-ashes, those of peat and white turf-ashes, have been found useful; red turf ashes useless, and gene- rally hurtful. Wood-ashes have also been employed advantageous ly in many cases ; they contain either the four primitive earths, as Mr. Bergman asserts; or cal- careous earth chiefly, according to Achard; or calcareous and magnesia, according to D’Arcet. They also contain some pro- portion of phosphorated selenite, z. ¢. cal- careous earth united to the phosphoric acid. Almost all co atain also a small and variable propertion of common salt, Glau- 20". ber’s salt, and terrene salts, which, when in a small dose, all accelerate putrefition ; . also small bits of charcoal. Charcoal is a substance well known; it has frequently and successfully been used asa manure. Ist Young’s Annals, 152, &e. &e. S ap-boilers Waste forms an excellent manure for some soils ; it contains, by Mr. Ruckert’s Analysis, 57 per cwt. of mild calx, 11 of magnesia, 6 of argill, and 21 of silex 3 Stable Dung. This is used either fresh or putreficd ; the first is called /ong, the other short dung; it abounds in animal matter, easily runs into putrefaction, and. when putrefied serves as a leaven to hasten the decay of other dead vegetable sub- stances; its fermentation is promoted by. frequent agitation and exposure to the air; yet it : shoul d be covered to prevent water from carrying of most of its important ingredients; or at least the water that 1 im- bibes them should not be lost. Farm-yard Dung consists of various vegetables ; as straw, veeds, leaves, fern, &c. impregnated with animal matter; it ferments more slowly than the former ; 21 should be piled in heaps, and stirred, from time to time. Fern putrefies very slowly. The water that issues from it should be preserved. | Some of these manures have been ana- lysed. | “zp dfuassp yy ‘uoTyeyas0 A ‘jy ‘pedoyoAougq uz 4 ‘Wayony Z « a a a aT a ‘Se IT TG ‘9 | x18D 2g = eal = — 1|,9388 AA Siaztoq-deos: iSunp-asuoyy | epee | $1 Se | ever | crge | 1} 9% waned UFO | : (Su Nsad Yae Ty! = UO pus LG ‘O' SUVS “A : oye MA 6 ‘0 ‘sdég} ¢9‘0 g 9 ‘0 es or 18 OGT | O9St ,SUNP-CQ ua}Oy ‘S¥IA i | 220 = 62 S | vO8 BE OSS oa sauce 4 eas .Sunp sde2ays' 120 ae g S‘0 $ ‘t] fOr 88 me — | ,dunp-osuoyy YSaqy 9 0 eed oS 9 a) Se27's = _ — ,SUNP-MOD Ysaty, “aq *q] “ql “41 “aq q| “a yur gny |"urqng mi Oy g | ‘SyeS PeXlA] “ITV XOIS | Wsay | visouseyy} ‘yeop | soya, | cary | cunyguy ‘d] SOL OA OUR XVO ee pes AAnoyy | ee ee “SHYONVW HO SLNYINOOD JO ATAV IL 23 Hence they should be applied, not in- discriminately, but according to circum- stances, to be indicated in the sequel. _ Pounded bones form also manure much used in the neighbourhood of great towns. They gradually deposit their oily part, which contains a large proportion of ani- mal! coal which 1s extricated by putrefac- tion, and phosphorated calx. Hence Bone- ash is also useful. Sea-weed, particularly if mixed with earth, soon putrefies, and makes a good manure. Sweepines of Ditches abound with pu- trid matter from decayed vegetables, and hence forma manure. Old Ditches, exposing a large surface to vegetation, contain, when destroyed, a quantity of decayed vegetables, which putrefy and make a good manure ; but in this and the former case, it may be proper to distinguish of what soil they are com. posed, for reasons that will hereafter ap- pear. Fallowing, 1s the principal operation by which exhausted lands are restored to fer- tility ; its use seems to me to consist in ex- posing the roots of vegetables to decay, whereby food for a fresh growth is pre- BA pared ; the atmosphere also deposits fix- ed air and carbonaceous substance on earth long exposed to it. Draining is an operation equally neces- sary and well known, on which no more need be said here. Paring and burning reduces the roots of vegetables to coal and ashes; and thus prepares both a stimulant and nutriment for plants, as will be seen hereafter. Crt. hk ‘OF THE FOCD OF PLANTS, AND THE COMPO- SITION OF FERTILE SOILS. HAVING, in the preceding chapter, explained the nature of the different soils known in agriculture, and of the different manures whose general utility has been ascertained by long experience, we are now to inquire which of those manures are most advantageously applicable to each of those particular soils, and what are the causes of their beneficial effect in each particular instance. To proceed with order in this inquiry, we must observe, that the general effect expected from the apnlication of manure is fertility; that is, the most copious pro- duction of corn and grasses; and, since fertility is itself the result of the due ad- ministration of the food of those vegeta- bles, we must first see what that food is, and of what ingredients a soil ought to be composed, in order to contain or adminis- ter it; after which we shall indicate by a0: what manures each particular sort of soil is brought into a fertile state (which is the beneficial effect expected from them) and how in each particular case they contri- bute to the due adminstration of the vege- table food, which is the cause of their be- neficial effect. SECTION I. OF THE FOOD OF PLANTS. To discover the food of plants, particu- larly of those which form the object of our present inquiry, we must examine the nature and proportion of the substances in which they grow, and of those which they themselves contain : thus we shall be enabled to see which of the latter are de- rived fromthe former. — First, All plants (except the subaque- ous) grow in a mixed earth, moistened with rain and dew, and exposed to the at- mosphere. If this earth be chemically examined, it will be found to consist of silicious, calcareous, and argillaceous par- ticles, often also of magnesia, in various proportions, a very considerable quantity of water, and some fixed air. The most L 3 € > mehe at ~ ‘ Ty} “NT ats iy fertile, also, centain 2 small proportion of < A 27 oil, roots of decayed vegetables, a coaly substance arising from putrefaction, some traces of marine acid, and gypsum.* On the other hand, if vegetables be analysed, they will be found to contain a large pro- portion of water and charcoal ;: also fat and essential oils, resins, gums, and vegetable acids: all which are reducible to water, pure air, inflammable air and charcoal: a small proportion of fixed alkali is also found, some neutral salts, most commonly eypsum, tartar, vitriolate, common salt, and salt of sylvius. In corn, and pazticu- larly wheat, phosphorated selenite is also found. Hence we see that, on the last analysis, the only substances common to the grow- ing vegetables and the soils in which they grow, are water, coal, different earths, and salts. These, therefore, are the true food of vegetables: to them we should also add fixed air, though, by reason of its de- composition, it may not be distinctly found in them, or at least not distinguishable from that newly formed during fhezr de- composition. I shall now examine the separated func- tions of each of these ingredients. * Home, 15 Mem. D’Agriculture, Par. 1790. Encyclo- \r r r - = > ¢ ped. Vezetation, p. 277. 28 OF WATER. The agency of water in the process of vegetation, has never been doubted, though the manner in which it contributes to it has not, until of late, been distinctly perceived. Doctor Hales has shewn, that in the summer months a sun-flower weigh- ing three pounds avoirdupois, and regu- larly watered every day, passed through it, or perspired, 22 ounces each day; that 1s, nearly half its weight. He also found that a cabbage plant, weighing 1 lh. 9 oz. sometimes perspired lb. 3 oz.; but at a medium about half its weight.* Doctor Woodward found that a sprig of common spearmint, a plant that thrives best inmoist soils, weighingonly 28,25 gers... passed through it 3004 grs. in 77 days, between July and October ; that is, some- what more than its own weight each day. He did more; for he found that in that space of time the plant increased 17 ers. in weight, and yet had no other food but pure rain water. But he also found that it increased more in weight when it lived on spring-water, and still more when its food was Thames watert. From whence Z pe ~7° 7 7 Litres; 9.10, 15. +2 Phil), Trang, Albro 7 2G. 25 we may deduce, that grasses and corn, during the time of their growth, absorb about one half their weight of water each day, if the weather be favourable. Secondly, that the water they thus ae _ nourishes them merely as water, withou taking any foreign substance into the ac- count: for 3000 ers. of rain water, in Doctor Woodward’s experiment, afford- ed an increase of 17 grains; whereas, by Mareraafi’s exper iments, 5760 ¢ ors. of tise water contain only one third of” a grain of earth*. But, Thirdly, [t also follows, that water con- tributes still more to their nourishment when it conveys to them earthy and sa. line particles, as spring and ‘Thames wa- ters do. The manner Yn which pure water con- tributes to the nourishment of plants, be- sides the service it renders them in distri- buting,the nutritive parts throughout their whole structure, and forming itself a con- stituent part of all of them, may be un- derstood from modern experiments. Doc- tor Ingenhouz and Mr. Senebier have shewn that the leaves of plants exposed to the sun produce pure air: now water * 2 Margr. 6, 70. 30 has of late been proved to contain about 87 per cwt. of pure air, the remainder be- tng inflammable air. Water is then de- composed by the assistance of light with- in the vegetable ; its inflammable part is employed in the formation of oils, resins, cums, &c. its pure air is partly applied to the production of vegetable acids, and partly expelled as an excrement. Many, indeed, have asserted, that water is the sole food of vegetables ; and among the experiments adduced to prove it, that of Van Helmont, quoted by the illustrous Mr. Boyle*, is by far the most specious. He planted a trunk of willow, weighing 5lb. in an earthen vessel filled with earth dried in an oven, and then moistened with rain-water. This vessel, it appears, he sunk in the earth, and watered partly with rain-water, and occasionally with distilled. After five years he found the tree to weigh 169 lb. and the earth in which it was plant- ed, being again dried, to have lost only _ 2 oz. of its former weight, though the tree received an increase amounting to 164 Ib. Before I proceed to the explication of this experiment, 1 must remark some cir- Ca. Coe ae Van OV 2c Shaw’s Boyle, 240i ~ ol cumstances attending it: First, that the weight of the earth contained in the ves- sel at the commencement and at the end of five years, could not be exactly compared, because the same degrees of desiccation could not be exactly ascertained, and be- cause many of the fibrillze of the roots of the tree must have remained in the earth after the tree was taken out of the vessel, and these must have prevented the true loss of earth from being perceived. Secondly, That the earthen vessel must have fre- quently absorbed water impregnated with whatever substance it might contain, from the surrounding earth in which it was in- serted ; for unglazed earthern vessels easi- ly transmit moisture. (lst Hales 5, and Tillet’s Mem. Par. 1772, page 298, 304, 8vo.) Thirdly, As it appears that the pot was sunk in the earth, and received rain- water, it is probable that distilled water was seldom used. These circumstances being considered, it will easily be made to appear that the rain-water, absorbed by the tree, contain- ed as much earth as the tree can be sup- posed to contain. First, The willow ince eae in weight 164 lb. in five years; that is, at the rate of 2,7 Ib. nearly per month ; and it being an 32 aquatic, it cannot be supposed to pass less than ‘its own weight of water each day during the six vegetating months. In the first month, therefore, ity absorbed and passed 5x30=150 tb. and as each pound of rain-water contains 1¢r. of earth, 50 grains of aad must have been deposited in the plant; and allowing no more than 50 grains for ‘the deposit of each of the six months. we shall have 50x6=300 for the deposit of the first year : but at the end of the first year the plant gains an ac- cession of the 52lb. therefore, in each of the six summer months of the succeeding year, it passes 37X30=1110 Ib. of water, and receives a deposit of 370 grains ; and at the end of the second year the deposit amounts to 2220 grains. At the com- mencement of the thicd year, the tree gaining a farther accession of 32 ib. must weigh 69 lb. and pass in each of the sum- mer months 69xX30=2070 lb. of water, and receive a deposit of 690 ers.. which multiplied into 6=4140 grains. At the commencement of the fourth-year, the tree still gaming 32 1b. must weigh 1C1 1b; and if it passes i01x30 in each of the summer months, it must gain a deposit in each of 1010 ers. of earth, and at the enc of the year, 6060 AS JO At the commencement of the fifth year it weighs 133 Ib. and gains at the end of the six months 23940 grains of earth. The quantities of earth deposited each year exceed 5 lb. avoirdupois, a quantity equal to that which 169 Ib. of willow can be supposed to contain; for the commis- sioners employed to inspect the fabrica- tion of saltpetre in France, having exam- ined the quantities of ashes afforded by trees of various kinds, found that 1000 Ib. of sallow, a tree much resembling the willow, afforded 28 Ib. of ashes, and con- sequently 169 lb. should produce 4,7. I do not give this calculation, however, as rigorously exact. It is certain, that if the deposit left at the end of every month were exactly taken, the total would ex- ceed the quantity just mentioned ; but that, found even by this rude mode, sufficiently proves that water conveys a portion of earth into vegetables equal to any that the experiments hithcrto made can prove to exist in them. As to the coal, or carbonaceous princi- ple, which this willow must also have contained, it is probable that much of it existed in the earth in which the willow grew. Some is contained in all moulds or c 34 vegetable earth ; and as we are not told what sort of earth Van Helmont used, we may well suppose it was good vegetable earth, its quantity amounting to 200 Ib. This principle may also have been contain- ed in the water, for the purest rain-water contains some oleaginous particles, though in an exceeding small proportion, as Mr. Margraaff has observed* ; and all oil con- tains coal. Some also may have pas- sed from the surrounding vegetable earth through the pores of the earthen vessel. All the other experiments, adduced to prove that water is the sole food of plants, may be explained in the same manner. Grains of wheat have been made to grow on cotton moistened with water; each produced an ear, but that ear contained but one grain ¢. Here the carbonaceous sub- stance was derived from the grain, and afterwards diffused and transported through the whole plant by the water absorbed ; for it must be observed that grain, like an ege, contains much of the nourishment of its future offspring. It is thus that tulips, hyacinths, and other plants, expand and grow in mere water. | The earth contained in rain-water is * 2d Margr. 15,90. + 2d Young’s Annals, 487. Sis, united partly with the nitrous and marine acids, as Margraaff has shewn, but far the greater part only with fixed air; for the feeble traces of the two former acids could not hold in solution the 100 grains of earth which he found in 300 lb. of rain-water. By far the greatest proportion of vege- table substances consist of water. Accor- ding to Mr. Young and Ruckert, grass loses about 2-thirds of its weight on be- ing dried into hay*. Dr. Hales found a sun-fower plant, which weighed 48 ounces, to lose 36 ounces by drying in the air dur- ing thirty davst, and consequently to have lost 3-fourths of its weight. Even vegetables to appearance thoroughly dry, contain from 3-fifths to 3-fourths of their weight of watert. This water is not all in a liquid state, but, by the loss of much of its specific heat, is in a great measure solidified. * 21 Young’s Ann. 26.. 2d Ruck. 1397 ft 1st Hales, 8. ¢ Ruckert, 28. Seneb. Encyclop. Vegetation. 5%. 56 OF COAL, OR THE CARBONIC SUBSTANCE. To Mr. Hassenfraz we owe the dis- covery, that coal is an essential ingredi- ent in the food of all vegetables. Though higherto little attended to, it appears to be one of the primeval principles, as ancient as the present constitution of our globe: for it is found in fixed air, of which it constitutes above one-fourth part; and fixed air exists in lime-stones and other substances, which date from the first ori- gin of things. Coal not only forms the residuum of all vegetable substances that have undergone a slow and smothered combustion, that is, to which the free access of air has been prevented, but also of all putrid vegetable and animal bodies : hence it is found in vegetable and animal manures that have undergone putrefaction, and is the true basis of their ameliorating powers : if the water that passes through a putrefying dunghill be examined, it will be found of a brown colour; and if subjected to eva- poration, the principal part of the residuum 37 will be found to consist of coal*. All soils steeped in water communicate the same colour to it in proportion to their fertility ; and this water being evaporated, leaves also a coal, as Mr. Hassenfraz and Four- croy attest}. They also observed, that shavings of wood being left in a moist place for nine or ten months, began to re-- ceive the fermentative motion, and being then spread on land, putrefied after some time, and proved an excellent manuret. Coal, however, cannot produce its benefi- cial effects but in as much as it is soluble in water. ‘he means of rendering it so- luble are not as yet well ascertained ; ne- vertheless, 1t is even now used as a ma- nure, and with good effect).. In truth, the fertilizing power of putrid animal and vegetable substances were fully known. even in the remotest ages, but most specu- latists have hitherto attributed them to the oleaginous, mucilaginous, or saline parti- cles then developed, forgetting that land is fertilized by paring and burning, though the oleaginous and mucilaginous particles are thereby consumed or reduced to a coal, and that the quantity of mucilage, oil or salt in fertile land is so small, that it could *14 Ann. Chym. 56, + Ibid. t Ibid: § Young’s Annals. 38 not contribute the 1000th part of the weight of any vegetable; whereas coal is supplied not only by the land, but also by the fixed air combined with the earths, and also by that which is constantly set loose by various processes, and’ soon pre- cipitates by the superiority of its specific gravity, and is then condensed in, or me- chanically absorbed by, soils, or contained in dew. Lands which contain iron ina semicalcineci state, are thereby enabled to decompose fixed air, the iron, by the help of water, gradually attracting the pure air, which enters into the composition of fixed air, as Mr. Gadolin has shewn* : a disco- very which appears to me among the most important of these later times ; but these calces of iron may again be restored to their former state by union with oleagin- ous substances, as Mr. Beaume has no- ticed ; and this is one of the benefits re- sulting from the application of dung be- fore it has fully putrefiedy. Hence we may understand how soils become effect- ed and exhausted, this effect arising, in great measure, from the gradual loss of the carbonic principle deposited by vege- * Ist Chym. Ann. 1791, 53. : + The affinities of coal and iron to pure air, vary with the temperature. 39 table and animal manures, and from them passing into the growing vegetables; and also from the loss of the fixed air contain- ed in the argillaceous part of the soil, which is decomposed by vegetables ; and from the calcination of the ferruginous particles contained in the soil. I say in great measure, because other causes contribute to the diminution of fertility ; which shall presently be mentioned. Hence, also, we see why lands pastured remain longer fertile than those whose vegetable crop is carried off, as much of the carbo- naceous principle is restored by the ex- crements of the pasturing animals: why some crops exhaust more than others; because corn, and particularly wheat, con- tains more of the carbonic principle than grasses, and very little of its exuvie are left behind: why fallows are of some use; as the putrefaction of the roots of | weeds and the absorption of fixed air by clays, are thereby promoted : why vege- tables thrive most in the vicinity of towns; because the carbonic principle is copious- ly dispersed by the smoke of the vari- ous combustibles. consumed in inhabited places: why soot is so powerful a ma- nure : why burning the clods of grassy land contributes so much to its fertility, 40 ‘and then only when the fire is smothered and coal produced; besides many other agricultural phenomena, too tedious to re- late : but I must not omit that the phos-_ phoric acid is found in coal; and this en- ters into the composition of many vegeta- bles. The quantity of coal in vegetables is various, according to their various species, age, and degrees of perfection : wood and corn contain most, grasses least. Weig- leb found dry beech-wood to contain one fifth of its weight of coal*. Westrumb found trzfolium pratense, a sort of clover, to contain about one seventh. Hence, after water, it is the most copious ingre- dient in vegetables. : OF EARTHS. The next most important ingredient to the nourishment of plants is earth: and of the different earths the calcareous seems the most necessary, as it is. contained in rain-water: and, absolutely speaking, ma- ny plants may grow without imbibing any other. Mr. ‘Tilletfound corn would grow * Uber cie alkalis, p, 76. Al in pounded glass*; Mr. Succow m pound- ed fluor spar, or ponderous spar, or gyp- sumt+: but Tillet owns it grew very ill; and Hassenfraz, who repeated this experi- ment, found it scarcely grow at all when the glass or sand were contained in pots that had no hole in the bottom, through which other nutritive matter might be conveyed. It is certain, at least, from common experience, that neither grasses nor corn grow well either in mere clay, sand, or chalk ; and that in vegetables that grow most vigorously, and in a pro- per soil, three or four of the simple earths are found. Mr. Bergman, on the other hand, assures us he extracted the four earths, the silicious, argillaceous, calcare- ous, and muriatic, in different proportions from the different sorts of cornt. Mr. Ruckert, who has analysed most species of corn and grasses, found also the four above-mentioned earths tn various pro- portions in all of them. Of his analysis I shall here give a specimen, comprehend- ing, howeve ry the calcareous and muria- tic in the same column, as this last scarce- ly deserves particuiar notice : * Mem. par. 1772, 301, 8vo. + ist Chym. Ann. 1784. ¢ 5 Bergman, 94,98, Scheffer Warles, s2c. 172. £7 42 One hundred parts of the lixiviated ashes of contained of Silex. Calx. Argill. Wheat---f - 48pts. 37 15 Oats