CHAPMAN'S MINERALS AND GEOLOGY OF ONTARIO AND QUEBEC. BY THE SAME AUTHOR. I. AN OUTLINE OF THE GEOLOGY OF CANADA BASED ON A SUBDIVISION OF THE PROVINCES INTO NATURAL AREAS. With six sketch-maps and 86 figures of characteristic fossils. II. BLOWPIPE PRACTICE. WITH ORIGINAL TABLES FOR THE DETERMINATION OF ALL KNOWN MINERALS. Favourable mention is made of this work in the later editions of Von Kobell's celebrated Tafeln zur Bestimmung der Mineralien. III. ASSAY NOTES. PRACTICAL INSTRUCTIONS FOR THE DETERMINATION BY FURNACE ASSAY OF GOLD AND SILVER IN ROCKS AND ORES. Second Edition. IV. THE MINERAL INDICATOR: A PRACTICAL GUIDE TO THE DETERMINATION OF MINERALS OF GENERAL OCCURENCE. THE MINERALS AND GEOLOGY OF CENTRAL CANADA, COMPRISING THE . PROVINCES OF ONTARIO AND QUEBEC. ndro2oic Vlll. CONTENTS. PART IV. FOSSILIZED ORGANIC BODIES 209 Plant Remains (210-220). Thallogens (211). Acrogena (215). Gynmo- sperms (219). Monocotyledons (220). Dicotyledons (220). Animal Remains (221-292). Protozoa (221). Polystomata (223). Coeleuterata (225). Echinodermata (236). Vermes ^248). Arthropoda (250). Molluscoidea (265). Mollusca (275). Tunicata (290). Verte- brata (290). PART V. SYSTEMATIC OUTLINE OF THE GEOLOGY or CENTRAL CANADA, COMPRISING THE PROVINCES OF ONTARIO AND QUEBEC 293 PROVINCE OF ONTARIO (294-333). Introductory Notice (294). Geo- logical Subdivisions (296). District of the Upper Lakes (297). East- ern Archaean District (304). Lower Ottawa District (308). Lake Ontario District (322). Erie and Huron District (321). M. nitoulin District (329). Northern Palaeozoic Area (331). PROVINCE OF QUEBEC (333-354). Introductory Notice (333). Geolo- gical Subdivisions (335). Northern Archaean District (336). District of the Upper St. Lawrence (338). Anticosti and Mingan District (342). Appalachian or Eastern Townships and Gaspe District (344). Appendix : — Sequence of Rock Formations in Ontario and Quebec INDEX. 357 ADDITIONS AND CORRECTIONS. P. 6, note— for "thas"read "that." P. 17, line 8— for "pa" read "pan." P. 22, line 11— for " fluorhydric " read "hydrofluoric." P. 51, insert in bracket 18-BB, on charcoal, white incrustation and arsenical odour — Mispickel (some varieties), No. 22. P. 57, insert at the commencement of the "not malleable" series— Tin-white or greyish. BB, arsenical odour— Mispickel (some varieties) i\o 22 6 ~ f°r "SIMPLE SUBSTANCE" read "SIMPLE STAN CSS SUB- P. 64, line 15-add :" Gold occurs also in many of the veins around Big Stone Bay Lake of the Woods ; and quite recently it has been discovered in nd elsewhere in the Huronian rocks of the P. 64, line 28— after Riviere du Loup, add (Beauce Co). '. 71— add Sudbury to the localities of Purple Copper Pyrites. P. 76, line 13— for " Cape Ibberwash " read " Cape Ipperwash." P. 84, line 15— for "altered Silurian" read "crystalline." f Crystals on these Pages are Pla^d in reversed . 90, line 8 from bottom— for "from" read "form." P. 93, for "distinct" read "distinctive." P. 99, line 2— for " iron is " read " iron oxides ore." 104, lines 7 and 8 from bottom-erase " or Upper Laurentian strata." P. 110 — transpose lines 5 and 6. P. 110, line 15— for "Nepheletic" read " Nephelitic." P. 1 15-add Sheffield to localities of Phlogopite. A valuable deposit of this species of mica has been recently discovered in the township. P. 126, line 6 from bottom — for "or" read "of." P. 127, line 2— for "Bentick" read "Bentinck." P. 128, last line— for " chlorite " read "chloritic." P. 130, line 8 from bottom— for " from " read "form." P. 148, line 4— for "more limited" read "a more or less limited depth " P. 149, line 26— for " exhibit " read "exhibits." '" The lette^g «hews its pro- P. 169, line B-add : a very fine-grained variety, with predominating feldst>< has been named granulite or feldspar-rock. P. 172, line 11 — for " agillite " read "argillite." P. 172, line 24— for " Huronian rock " read "Huronian rocks." P. 173, line 5 from bottom— for " from " read " form." P. 189, line 17— add "at" before "Gros Cap." P. 191, line 22— for " are not uncommon " read " have been fouud." X. ADDITIONS AND CORRECTIONS. P. 191, line 5 from bottom — insert "lava-like products " after " but." P. 204, line 21 — for " Equiseta " read '• Equiseti." P. 205, line 10— for "Parts V. and VI." read " Part V." P. 207, Jines 6 and 7 — erase " and to have been experienced also in the extrer south." P. 210, line 26 — for " literal " read "littoral." P. 216, line 16 — for "hollow- jointed" read "hollow, jointed." P. 224, lines 19, 23, 25— for " siliceons " read "siliceous." P. 227, line 8 from bottom— insert after " all " " Upper Cambrian or." P. 229, line 2 from bottom — for " Hydrocorolla " read " Hydrocoralla. P. 232, line 3— insert (7) before " Syringopora." P. 239, line 3 from bottom — for "bifercating " read " bifurcating." P. 240, line 22 — f or " Enerincus and Enerinite " read ' ' Encrinus and Encrinil P. 241, line 11 — for "oval" read "anal." P. 245, line 10 — for "species" read "examples." P. 248, line 3 under Vermes — for " six " read " seven." P. 251, note — for " Phyllorarida " read " Phyllocarida. " P. 254, line 24— for "states " read " slates." P. 260, line 23— for " Limulas " read "Limulus." P. 266, under Fig. 181 — for " Fenstella " read " Fenestella." P. 267, line 10 — for " Brachipods" read " Brachiopods. P. 269, lines 6 and 10 from bottom— for "Brown" read "Bronn." P. 272, line 10 from bottom— for " Pernian " read " Permian." P. 279, line 8 — for "arrange" read "arranged." P. 280, line 6 — for " Prosobranchiala " read " Prosobranchiata. " P. 284, line 1— for "Cytolites" read " Cyrtolites." P. 288, line 9— for " Tetrebranchiata" read " Tetrabranchiata. " P. 289, line 5 from bottom — for " resembling " read " resembles." P. 302, at close of first paragraph — add : " Quite recently, important dis- coveries of Native gold and auriferous ore have been made in the vicinity of Sudbury : more especially in Dennison township." P. 340, line 8 — for "outlying" read "inlying." A POPULAR EXPOSITION OP THE MINERALS AND GEOLOGY OF CENTRAL CANADA. INTRODUCTORY NOTICE. The aim of the present work is to impart, in a simple and con- densed form, a practical knowledge of Canadian minerals and rock formations, including with the latter, the various fossilized bodies which so many of these rocks contain, and by which their respective ages and positions are principally established. Geology, in the proper acceptation of the term, comprises the History of the Earth as distinct from records of human action and progress : a history revealed to us by the study of the rock masses which lie around and beneath us ; and by a comparison of the results of ancient phenomena, as exhibited in these rocks, with the forces and agencies still at work in modifying the surface of the globe. As Geology is thus essentially based on the study of rocks and their contents, and as rocks are not only made up of a certain number of simple minerals, but contain also many of these latter in veins and other more or less accidental forms of occurrence, it is advisable at the outset to obtain a certain knowledge of the distinctive characters of minerals, and of the ap- plication of these characters to the determination of mineral bodies generally. This achieved, we may proceed to the study of the more extended mineral masses, or rocks proper : their classification, struc- tural characters, composition, modes of formation, and other related points of inquiry. The study of Organic Remains comes next in order— these bodies, the representatives of departed forms of life, occurring in great numbers in many strata. They serve not only for the practical identification of the rock groups in which they are enclosed — thus enabling us to determine, for instance, whether a 2 2 INTRODUCTORY NOTICE. given bed lie above or below the great coal formation or other geological horizon — but they make known also many interesting facts with regard to the climatic relations of the Past, and serve to explain to some extent the embryology and development of existing forms. Finally, with the information obtained from these prelimi- nary sections, the reader may turn with profit to the study of our local geology. In accordance with these views, the subject-matter of the present treatise is discussed under the following sub-divisions : I. — The Distinctive Characters of Minerals. II. — The Minerals of Central Canada, or Provinces of Ontaric and Quebec. III. — Rocks and Rock-producing Agencies. IV. — Fossilized Organic Bodies. V. — The Geology of Central Canada — comprising the Sub- divisions, Characteristic Fossils, Economic Materials, and Distribution, of the various Geological Formations oc- curring within the Provinces of Ontario and Quebec. PART I. THE DISTINCTIVE CHARACTERS OF MINERALS. Preliminary Remarks .—The various bodies which occur in Natur are of two general kinds-Organic and Inorganic, respectively Th former constitute Vegetables and Animals, and all bodies of vege e or animal origin. In the living state, they possess certain structural parts or organs by which they assimilate or take into the* .bstance external matter, and thus increase in bulk or maintain vitahty Inorganic bodies, on the other hand, are entirely destitute of functional organs of this nature. They comprise all product of chemical, electrical and mechanical forces, acting independent? of hfe; and thus mclude all metals, stones, and rocks, and also air and water. Mineral or inorganic bodies are in themselves, also, of two general Some possess a definite composition and definite physical characters Others are mixed bodies or compounds of more or variable character. The former constitute simple minerals or nT erals proper ; the latter form rocks or rock-matters. In Parts I and this Treat,se, minerals proper are alone considered. Rocks ar scz.'Srjr under reviev in part ra - * - 3SLT±fti^- onr T by, certain characters form, degree of hardness, Mineral characters are of two principal kinds : physical or external and ckemwal, respectively. Physical characters comprise the variTus properties exhibited under ordinary conditions by mineral bodi s colour, form, Ac. are examples, Chemical characters, on the other hand compose the properties developed in minerals by the applica- on of heat, or by the action of acids or other re-agents, by which in general, a certain amount of chemical decomposition is effected 4 MINERALS AND GEOLOGY A. -PHYSICAL CHARACTERS OR PROPERTIES. The physical properties of minerals are somewhat numerous ; but many, although of the highest interest in indicating the existence of natural laws, and in their relations to physical science generally, are not readily available as a means of mineral discrimination. These, consequently, will be omitted from consideration in the following pages ; and the other characters will be discussed only in so far as they admit of direct application to the end in view —namely, the practical discrimination of minerals one from another.* The following are the characters in question : 1. ASPECT OR LUSTRE. 2. COLOUR. 3. STREAK. 4. FORM. 5. STRUCTURE. 6. HARDNESS. 7. SPECIFIC GRAVITY. 8. RELATIVE MALLEABILITY. 9. MAGNETISM. 10. TASTE. Aspect or Lustre. — In reference to this character we have to con- sider first, the kind, and, secondly, the degree or intensity of lustre, as possessed by the mineral under examination. The kind of lustre may be either metallic, as that of a piece of copper, silver, &c. ; or sub-metallic, as that of most kinds of anthracite coal ; or non-metallic, as that of stones in general. Of the non-metallic there are several varieties, as, more especially : the adamantine lustre or that of the * Viewed collectively, the Physical Characters of Minerals may be arranged for the purposes of study, under six groups, as follows : FIRST GROUP : — Morphological Characters : — 1, Form. 2, Surface-condition. 3, Structure. 4, Cleavage. 5, Fracture. SECOND GROUP -.—Optical Characters :— 1, Aspect or Kind of Lustre. 2, Degree of Lustre. 3, Colour. 4, Streak. 5, Degree of Transparency. 6, Refraction. 7, Polarization. THIRD GKOUP -.—Cohesion Characters :— 1, Hardness. 2, Tenacity. 3, Malleability. 4, Ex- pansibility. FOURTH GROUP:— Sensationary Characters:— 1, Weight (Specific Gravity). 2, Feel. 3, Taste, 4, Odour. 5. Sound. FIFTH GROUP : — Physical Characters, proper : — 1, Magnetism. 2, Electricity. 3, Phos- phorescence. SIXTH GROUP : — Epigenic Characters : — 1, Tarnish. 2, Ordinary Disintegration and Decom- position. 3, Efflorescence. 4, Deliquescence. OF CENTRAL CANADA PART I. diamond, carbonate of lead, &c.; the vitreous or glassy lustre- example : rock crystal; the resinous lustre— ex.: native sulphur; the pearly lustre— ex.: talc; the silky lustre (usually accompanying a fibrous structure)— ex.; fibrous gypsum ; the stony aspect; the earthy aspect, &c. These terms sufficiently explain themselves. Occasionally, two kinds of non-metallic lustre are simultaneously present -either blended, as seen in obsidian, which exhibits a " resino- vitreous " aspect ; or distinct as regards different crystal faces or external and internal surfaces. Many of the so-called Zeolites, for example, pre- sent a pearly lustre on the surfaces produced by cleavage (see beyond), whilst the external lustre is vitreous. In Apophyllite, the basal or terminal crystal-plane is pearly, the others vitreous. Micas, and some few other minerals, present a pseudo-metallic lustre. This may be distinguished from the metallic lustre properly so-called, by being accompanied by a degree of translucency, or by the powder of the mineral being white or faintly coloured : minerals of a true metallic aspect being always opaque, whilst their powder is either black or dictinctly coloured. Very few minerals exhibit (in their different varieties) more than one general kind of lustre : metallic or non- metallic. Thus, galena (the common ore of lead), copper pyrites, &c., always present a metallic lustre ; whilst, on the other hand, quartz, feldspar, calc-spar, gypsum, &c., are never metallic in aspect. ' Hence, by means of this easily-recognized character, we may divide all minerals into two broad groups ; and thus, if we pick up a specimen, and wish to ascertain its name, we need only look for it among the minerals of that group with which it agrees in lustre. The first step towards the determinataion of the substance will in this way be effected. The degree of lustre may be either splendent, shining, glistening, glimmering or dull ; but the character is one of comparatively little importance. Colour.— When combined with a metallic aspect, colour becomes a definite character, and is thus of much value in the determination of minerals. As regards a substance of metallic aspect, for example, specimens brought from different localities, or occurring under different conditions, rarely vary in colour beyond a slight difference of depth or shade. Thus, galena the common ore of lead is always lead-gray; copper pyrites, always brass-yellow; native gold, always 6 MINERALS AND GEOLOGY gold-yellow ; and so forth. When accompanied, however, by a vitreous or other non-metallic lustre, colour becomes a character of no practical value, as a mineral of non-metallic aspect may present, in its different varieties, every variety of colour. Thus, we have col- ourless quartz, amethystine or violet quartz, red quartz, yellow quartz, &c. Also, feldspars, fluorspars, and other minerals of variable colour : just as in the Vegetable Kingdom, we have red, white and yellow roses, and dahlias, &c., of almost every hue. The more common shades of metallic colour are as follows. w, ., ( Silver-white ex. Native silver. ' \ Tin- white ex. Pure tin ; cobalt ore. p ( Lead-grey ex. Galena. ' 1 Steel-grey ex. Specular iron ore. Black Iron-black (usually with sub-metallic lustre) ex. Magnetic iron ore. ! Gold-yellow ex. Native gold. Brass-yellow ex. Copper pyrites. Bronze-yellow (a brownish-yellow) ex. Magnetic pyrites. Red Copper-red ex. Native copper. These metallic colours are often more or less obscured by a black, brownish, purple, or iridescent surface-tarnish. In noting the colour of a mineral, this must be constantly borne in mind, and if possible a newly-fractured surface should be observed. The non-metallic col- ours comprise, white, grey, black, blue, green, red, yellow, and brown, with their various shades and intermixtures : as orange-yellow, straw- yellow, reddish-brown, greenish-black, &c. In minerals of a non- metallic aspect, the colour is sometimes uniform ; and at other times, two or more colours are present together in spots, bands, &c., as in the varieties of quartz called agate, blood-stone, jasper, and so forth- In most varieties of Labradorite, or Labrador Feldspar, a beautiful play or change of colour is observable in certain directions. The finer varieties of Opal also exhibit a beautiful and well known iridescence. Streak. — Under this technical term is comprised the appearance or colour of the scratch, produced by drawing or " streaking " a mineral across a file or piece of unglazed porcelain. The character is a valuable one on account of its uniformity : as no matter how varied the colour of a mineral may be in different specimens, the streak will remain of one and the same colour throughout. Thus, blue, green, yellow, red, violet, and other specimens of fluor spar, quartz, &c., exhibit equally a white or "uncoloured" streak. The streak is sometimes " unchanged," OF CENTRAL CANADA PART I. 7 or of the same tint as the external colour of the mineral ; but far more frequently it presents a different colour. Thus, whilst Cinnabar, the ore of mercury, has a red colour and reS streak, Realgar, red sulphide of arsenic, has a red colour and orange-yellow streak ; Copper Pyrites, a brass-yellow colour, and greenish-black streak ; and so forth. In cer- tain malleable and sectile minerals, the scratched surface presents an increase of lustre. The streak is then said to be " shining." Finally, it should be remarked, that in trying the streak of very hard minerals, we must crush a small fragment to powder, in place of using the file; because otherwise, a greyish-black streak, arising from the abrasion of the file, might very possibly be obtained, and so conduce to error. Form. — The forms assumed by natural bodies are of two general kinds: (I) Accidental or Irregular, depending rather on external conditions than on the actual nature of the body : and (2), Essential or Regular. Accidental forms occur only as monstrosities in Organic Nature. Amongst minerals, on the other hand, they are of frequent occurrence ; but the Mineral Kingdom possesses also its definite or essential forms. These, whether transparent or opaque, are termed crystals. This term was first applied to transparent vitreous speci- mens of quartz or rock-crystal, from the resemblance of these to ice ; but as it was subsequently found that many opaque specimens of quartz present exactly similar forms, and that opaque as well as transparent forms of other minerals occur, the term, in scientific language, gradually lost its original signification, and came to be applied to all the geometrical or regular forms of minerals and other inorganic bodies, whether transparent, translucent, or opaque. As already remarked, minerals of a metallic lustre are always opaque ; and many of these, galena, iron-pyrites, arsenical-pyrites, &c., occur frequently in very regular and symmetrical crystals. As regards the regular or essential forms of Nature, two distinct and in a measure antagonistic form-producing powers — Vitality and Crystallization — thus appear to exist. Forms which arise from a development of the vital force, exhibit rounded and confluent out- lines ; whilst those produced by crystallization are made up of plain surfaces, meeting, in sharp edges, under definite and constant angles.* * This law is affected within slight limits by isomorphous replacements, and also by changes of temperature. The law itself appears to have been discovered by Nicolaus Steno (a naturalized Florentine) as early as 1669, but its true importance was not appreciated until the 8 MINERALS AND GEOLOGY Crystals originate in almost all cases in which matter passes from a gaseous or liquid into a solid state ; but if the process take place too quickly, or the matter solidify without free space for expansion, crystalline masses, in place of regular crystals, will result. If a small fragment of arsenical pyrites, or native arsenic, be heated at one end of an open and narrow glass tube, the arsenic, in volatilizing^ will combine with oxygen from the atmosphere, and form arsenious acid, which will be deposited at the other end of the tube, in the form of minute octahedrons (Fig. 3, below). In like manner, if a few par- ticles of common salt be dissolved in a small quantity of water, and a drop of the solution be evaporated gently (or be left to evaporate spontaneously) on a piece of glass, numerous little cubes and hopper- shaped cubical aggregations will result. Boiling water, again, satu- rated with common alum, will deposit octahedral crystals on cooling: the cooled water not being able to retain in solution the full amount of alum dissolved by the hot water. Finally, it may be observed that bismuth, antimony, and many other bodies, crystallize by slow cooling from the molten state. Although, as explained above, crystals usually originate when matter passes slowly from the gaseous or liquid condition into the solid state, crystallization and solidification are not actually identical. Various substances, such as silica in cer- tain conditions, its hydrate (constituting the different opals), gums, many resins, &c., appear to resist altogether the action of crystal- lization. The crystal forms and combinations met with in Nature, exclusive of those produced by the chemist in his laboratory, are exceedingly numerous, many thousands being known to exist. By the help of certain laws, however, and, more especially, by the aid of one, termed "the Law of Symmetry," we are enabled to resolve these multitudinous combinations into six groups or systems. The forms of the same group combine together, and may be deduced mathematically from each other; whilst those of distinct groups are unrelated. Thus, although the cube, the rhombic dodecahedron, and the regular octahedron (Figs. 1, 2 & 3) appear at first sight to be unconnected forms, their co-relations may re-announcement, or rather re-discovery of the law in 1772, by the French crystallographer, Rome de 1'Isle. Many of the contemporaries of the latter — amongst others the celebrated Buffon — attempted to deny its existence ; but being susceptible of practical proof, its truth was soon established. OF CENTRAL CANADA PART I. be readily shown by the Law of Symmetry. This law, for instance, exacts one of three things, of which the most important is to this effect, viz., that if an edge or angle of a crystal be modified in any way, all the similar edges or angles in the crystal must be modified in a similar manner. Now the cube has twelve similar edges and eight similar angles. Consequently, if one edge or one angle be truncated, or, to use a term more in conformity with the actual operations of Nature, if one of these be suppressed during the formation of the crystal, the other edges (or angles) must be suppressed also ; and if the new planes, which thus arise, be extended .until they meet, the rhombic dodecahedron on the one hand, and the regular octahedron on the other, will result.* These forms, moreover, as well as their intermediate oscillations, frequently occur in the same substancee : red oxide of copper may be cited as an example. But between the cube, a square prism, a regular hexagonal prism, and a rhombic prism, no relations of this kind exist. Neither are these solids related physicially : their optical, thermal, and other physical charac- ters are equally distinct. By considerations of this sort, therefore, we are able to establish six (or really seven) distinct Crystal Systems. These (named chiefly in accordance with the relations of their axes, or certain right lines assumed to pass through the centre of each crystal, and terminate in opposite planes, edges, or angles) are enumerated in the annexed tabular view : Crystal-axes of one length (The Regular or Isopolar System (including the Refraction, single . . . . . } cu.be' rhombic dodecahedron, octahedron, &c., ^ with their various combinations. ) f The Tetragonal System (including square-based Crystal-axes of two lengths. prisms and pyramids with their various corn- Kef raction, double, with) binations.) one neutral line or optical \ The Hexagonal System (including regular hexa- ; gonal prisms and pyramids, rhombohedrons, \. &c., with their combinations.) * The Law of Symmetry, in its exact acception, may be thus expressed : (1.) If an edge or angle of a crystal be modified, all the similar edges or angles will exhibit a similar modification. Or (2.) One-half or one-mth of the corresponding angles or edges, in alternate positions, will be equally modified. Example.— Cube and Tetrahedron (Boracite ; Arseniate of Iron.) Or (3. ) All the similar edges or angles will be modified by one-half or one-mth the normal or regular number of planes. Example.— Cube and Pentagonal Dodecahedron (Iron Pyrites, Cobaltine.) Conditions 2 and 3 produce hemihedrons or part-forms. 10 MINERALS AND GEOLOGY Crystal-axes of three lengths Refraction, double, with two neutral lines or optical rThe, Rhombic or Ortho-Rhombic Axes at right- 1 Sy*tem ("w^ng nght rect.^n' •J gular pnsms and pyramids, rhombic prisms and pyramids, One axis ob- lique. All the axes oblique. V. and combinations of these). The Clino-Rhombic or Monoclinic System (including oblique rec- tangular and rhombic com- binations). The Triclinic or Anorthic System (including doubly -oblique com- binations). The study of these Crystal groups, and that of crystal forms and combinations generally, constitutes the science of Crystallography. To enter into the details of this science would extend our present discussion much beyond its proposed limits and object, the simple determination of commonly occurring minerals ; but it will be advis- able for the student to impress upon his memory the names of the groups in question, with the general aspect of their more common forms and combinations, as given in the following enumeration. The Isopolar or Regidar System. — This group includes the cube (Fig. 1), the rhombic dodecahedron (Fig. 2), the regular octahedron (Fig. 3), trapezohedrons (Fig. 4), pentagonal dodecahedrons (Fig. 5), &c. Figs. 6 and 6* are combinations of the cube and octahedron ; IG. 1. FIG. 2. FIG. FIG. 4. FIG. 5. FIG. 6. FIG. 6*. FIG. 7. No. 7, a combination of the cube and pentagonal dodecahedron. Native gold, silver, copper, iron pyrites, galena, zinc blende, grey copper ore, red copper ore, magnetic iron ore, spinel, garnet, fluor spar, rock salt, and numerous other minerals, crystallize in this system. OF CENTRAL CANADA PART I. 11 The Tetragonal System — This includes, principally, square-based prisms and pyramids, and their combinations. Figures 8 to 9 are ex- FIG. 8. FIG. 8 a. FIG. amples of Tetragonal crystals. Amongst minerals, Copper Pyrites, Tinstone, Rutile, Anatase, Zircon, Idocrase, Scapolite &c., may be cited as belonging to the group. The Hexagonal System. — Regular six-sibed prisms (Fig. 10, and pyramids (Fig. 11), combinations of these (Fig. 12), three- sided prisms, rhombohedrons (Figs. 13 and 14), and scalenohedrons (Fig. 15) ; are included under this system. Graphite, Red Silver Ores, Cinnabar, Specular Iron Ore, Corundum, Quartz, Beryl, Tourmaline, Apatite or Phosphate of Lime, Phosphate and Arseniate of Lead, Calcite, \\ FIG. 13. FIG. 14. FIG. 14.* FIG. 15. Dolomite, and Carbonate of Iron, are some of the principle minerals which belong to it. The Rhombic System — This system includes right-rhombic prisms, rectangular prisms, rhombic octahedrons, &c., and their combinations. Fig. 16 is a rhombic prism ; Figs. 17 to 21 represent other crystals of 12 MINERALS AND GEOLOGY this system. Prismatic Iron-pyrites, Mispickel or Arsenical-pyrites, Native Sulphur, Topaz, Staurolite, Arragonite, Heavy spar, Celestine, FIG. 16. FIG. 17. FIG. 17.' FIG. 18. FIG. 19. FIG. 20. FIG. 21. FIG. and Epsom salt, are some of the principal minerals which belong to the Rhombic group. The Monoclinic or C lino- Rhombic System. — Rhombic prisms and pyramids, and rectangular prisms and pyramids, with oblique or sloping base, belong to this system. Figs. 22 to 24 are Monoclinic combinations. Characteristic minerals comprise : Augite, Horn- blende, Epidote, Sphene, Orthoclase or Potash Feldspar, Gypsum, and Iron Vitriol or Sulphate of Iron. FIG. 23. FIG. 24. FIG. 25. The Triclinic or Anorthic System — The forms of this system are oblique in two directions. The crystals in general are more or less flat and unsymmetrical in appearance, No two planes meet at right angles ; and there are never more than two similar planes present in any crystal belonging to the group. Axinite, Albite or Soda-Feld- spar, and Sulphate of Copper, Fig. 25, are examples of Triclinic minerals. OF CENTRAL CANADA PART I. 13 The Irregular Forms assumed by minerals are of very subordinate importance. The following are some of the more common : — Globular or nodular, ex. quartz, iron pyrites ; reniform or kidney-shaped, ex. quartz, &c. ; botryoidal or mammillated : a form made up of a series of rounded elevations and depressions, or otherwise exhibiting a sur- face of this character, ex. red and brown iron ore, calcedony, &c. • stalactitic, ex. calc. spar, &c. ; coralliform, resembling certain branch- ing corals, ex. arragonite ; acicular, in minute needle-like forms, ex. millerite ; dendritic or arborescent, a branching form, often made up of small aggregated crystals, ex. native silver, native copper, &c. ; filiform or wire-like, ex. native silver. When a mineral presents a perfectly indefinite shape, it is said to be massive. Other terms used in connection with the irregular forms of minerals, such as incrusting, disseminated, &c., explain themselves. The term amorphous is applied to obsidian, opal, and other minerals in which crystalline structure and cleavage planes are altogether wanting. Structure and Cleavage. — In the majority of minerals a certain kind of structure, or, in other words, the shape as well as the mode of aggregation of the smaller masses of which they are composed, is always observable. Structure in minerals may be either lamellar, laminar OY foliated, prismatic, fibrous, granular or compact. When the mineral, as in most varieties of calc-spar, heavy-spar, feldspar, and gypsum, for example, is made up of broad, tabular masses pro- ducing a more or less stratified appearance, the structure is said to be lamellar. When the tabular masses (whether straight, wavy or curved) become extremely thin or leafy, as in mica more especially, the structure is said to be laminar, or foliated, or sometimes mica- ceous. The scaly structure is a variety of this, in which the laminse are of small size. When the component masses are much longer than broad or deep, as in many specimens of tourmaline, beryl, calc- spar, &c., the structure is said to be prismatic or columnar. When the prismatic concretions become very narrow, the fibrous structure originates. Fibrous minerals may have either: a straight or parallel- fibrous structure, as in many specimens of gypsum, calc-spar, &c. ; an irregularly-fibrous structure, as in many specimens of augite and hornblende; or a radiated -fibrous structure, as in the radiated varieties of iron pyrites, natrolite, wavellite, and many other minerals, — the fibres radiating from one or more central points. Minerals made up 14 MINERALS AND GEOLOGY of small grains or granular masses are said to have a granular struc- ture ; ex. granular or saccharoidal limestone, granular gypsum, &c. Finally, when the component particles are not apparent, the mineral is said to have a compact structure, as in the native malleable metals, obsidian, and most varieties of quartz. Hard and vitreous minerals of a compact structure (ex. obsidian) generally show, when broken, a conchoidal fracture, or a series of circular markings resembling the lines of growth on the external surface of a bivalve shell. Almost all minerals, especially those of a lamellar structure, break or separate more readily in certain directions than in others. This peculiarity is called cleavage. When cleavage takes place in more than one direction, the resulting fragments have often a perfectly regular or definite form. Thus the purer specimens rof calc-spar, no matter what their external form, break very readily into rhombo- heclrons, which measure 105° 5' over their obtuse edges. Galena, the common ore of lead, yields rectangular or cubical cleavage forms j whilst the cubes of fluor-spar break off most readily at the corners or angles, and yield regular octahedrons (Figs. 6 and 3). Hardness. — The hardness of a mineral is its relative power of resisting abrasion, not that of resisting blows, as many of the hardest minerals are exceedingly brittle. Practically, the character is of great importance. By its aid, gypsum may be distinguished in a moment from calc-spar or ordinary limestone, calc-spar from feldspar, and copper pyrites from iron pyrites, not to mention other examples.* The degree of hardness in minerals is conventionally assumed to vary from 1 to 10 (1 being the lowest), as in the following scale, devised by the German mineralogist, Mohs, and now generally adopted : 1. Foliated TALC. 2. ROCK SALT, a transparent cleavable variety. 3 CALCAREOUS SPAR, a transparent variety. 4. FLUOR SPAR. 5. APATITE. * Gypsum may be scratched by the finger-nail ; Calc-spar and copper pyrites are scratched easily by a knife ; whilst feldspar and iron pyrites are hard enough to scratch window-glass. Some years ago, as mentioned by Sir William Logan, a farmer in the Ottawa district was put to much expense and annoyance by mistaking feldspar for crystalline limestone, and attempting to burn it into lime. On a late visit to the township of Marmora, we found, near a deserted kiln, a large heap of quartz fragments, on which n similar attempt had evidently been made. OF CENTRAL CANADA — PART I. 15 6. FELDSPAR. 7. EOCK CRYSTAL. 8. TOPAZ. 9. CORUNDUM. 10. THE DIAMOND. In order to ascertain the hardness of a mineral by means of this scale, we attempt to scratch the substance, under examination, by the different specimens belonging to the scale, beginning with the hardest, in order not to expose the specimens to unnecessary wear. Or, proceeding in another manner, we take a fine file, and compare the hardness of the mineral with that of the individual members of the scale, by drawing the file quickly across them. The comparative hardness is estimated by the resistance offered to the file ; by the noise occasioned by the file in passing across the specimens ; and by the amount of powder so produced. The degree of hardness of the mineral is then said to be equal to that of the member of the scale with which it agrees the nearest. Thus, if the mineral agree in hardness with fluor-spar, we say, in its description, H (or hardness) = 4. If, on the other hand, it be somewhat softer than fluor-spar, but harder than calcareous spar, we say, H = 3.5. Finally, if, as frequently happens, the hardness of a mineral vary slightly in different specimens, the limits of the hardness are always stated. Thus, if in some specimens, a mineral agree in hardness with calc- spar. and in others with fluor-spar, we say, H = 3 to 4 ; or, more commonly, H = 3 — 4. If the hardness be very rigorously tested, it will frequently be found to differ slightly on different faces of a crystallized specimen, or on the broad faces and the edges of the lamina of foliated specimens ; but this, so far as regards the simple deter- mination of minerals, is practically of little moment. As the minerals of which the scale of Mbhs consists are not in all places obtainable, or always at hand when required, the author of this work devised, many years ago, a scale of hardness so contrived as to agree closely enough for practical purposes with that of Mohs, whilst exacting for its application only such objects as are always to be met with. The following is tho scale in question : its use explains itself. 16 MINERALS AND GEOLOGY Chapman's Convenieat Scale of Hardness, to correspond with of Mohs. 1. Yields easily to the nail. 2. Does not yield to the nail. Does not scratch a copper coin.* 3. Scratches a copper coin, but is also scratched by one, being of about the same degree of hardness. 4. Not scratched by a copper coin. Does not scratch glass (ordinary window-glass). 5. Scratches glass very feebly. Yields easily to the knife. 6. Scratches glass easily 7. Yields with difficulty to the edge of a file. 8. 9, 10. Harder than flint or rock-crystal. Convenient objects for the estimation of degrees of hardness above No. 7 cannot be easily obtained ; but that is of little consequence, as there are but few minerals which exhibit a higher degree, and these are readily distinguished by other characters. Specific Gravity. — This is also a character of great value in the determination of minerals. The specific gravity of a body is its weight compared with the weight of an equal bulk of pure water. In order to ascertain the specific gravity of a mineral, we weigh the specimen first in a: and then in water. The loss of weight in the latter case exactly equals the weight of the displaced water, or, in other words, of a volume of water equal to the volume of the mineral. The specific gravity of pure water, at a temperature of about 62°, being assumed to equal 1, or unity, it follows that the specific gravity of a mineral is obtained by dividing the weight of the latter in air by its loss of weight in water. Thus, if a = the- weight in air, and w = the weight in water, G, or sp. qr. = -?—• a — w Example. — A piece of calcareous spar weighs 66 grs. in air, and 42 grs. when immersed in rain or distilled water. Hence its sp. gr. - "-'..- 2-75. 66 — 42 24 The weight of the mineral may be ascertained most conveniently, and with sufficient exactness for general purposes, by a pair of small scales such as are commonly called " apothecaries' scales." These may * Thas is, an old-fashioned copper coin, not a modern bronze coin. The scale was published in 1843. I I OF CENTRAL CANADA PART I. 17 be purchased for a couple of dollars or even less. A small hole must be made in the centre of one of the pans for the passage of a horse- hair or silken thread (about four inches in length) furnished at its free end with a " slip-knot " or running noose to hold the specimen whilst this is being weighed in water. The strings of the perforated pan may also be somewhat shortened, but the balance must in this case be brought into equilibrium by a few strokes of a file on the under side of the other pan, or by attaching thinner strings to it. As an application of specific gravity, apart from the employment of the character in the determination of minerals, it may be observed that the weight of masses of rock, heaps of ore, etc., may be readily ascertained by reference to this property. The length, breadth, and depth of the body being taken in feet and decimal parts of a foot, and these dimensions being multiplied together, we get the contents of the body in cubic feet. This value is then multiplied by 62.32, the weight in Ibs. of a cubic foot of water. This gives the weight of an equal bulk of water, which must finally be multiplied by the average sp. gr. of the body. The weight of the latter is thus obtained in Ibs. This weight divided by 2,000 gives the weight in American or Canadian tons ; and by dividing it by 2,240, we get the weight in British tons. Relative Malleability. — Some few minerals, a< • native gold, native silver, sulphide of silver, native copper, &c., are malleable or ductile, flattening out when struck, instead of breaking. A few other minerals, as talc, serpentine, &c., are sectile, or admit of being cut by a knife ; whilst the majority of minerals are brittle, or incapable of being cut or beaten out without breaking. In testing the relative malleability of a mineral, a small fragment should be placed on a little anvil, or block of steel polished on one of its faces, and struck once or twice by a light hammer. To prevent the fragment from flying off when struck, it may be covered by a strip of thin paper, held down by the forefinger and thumb of the left hand. Thus treated, malleable bodies flatten into discs or spangles, whilst brittle substances break into powder. Magnetism. — Few minerals attract the magnet in their natural condition, although many do so after exposure to the blowpipe. (See below. ) In trying if a mineral be magnetic, we chip off a small fragment, and apply to it a little horse-shoe magnet, such as may be 3 18 MINERALS AND GEOLOGY purchased anywhere for a quarter of a dollar ; or otherwise we appl the specimen to a properly suspended magnetic needle. In this manner many of the black granular masses which occur so frequently in our Gneissoid or Laurentian rocks, and in the boulders derived from these, may easily be recognised as magnetic iron ore.* Most specimens of this mineral (and also of magnetic pyrites) exhibit "polarity," or attract, from a given point, one end of the needle, and repel the other. Taste. — This is a very characteristic although limited property, being, of course, exhibited only by soluble minerals. In these, the taste may be saline, as in Rock Salt ; or bitter, as in Epsom Salt ; or metallic, as in Sulphate of Iron, and so forth. B. CHEMICAL CHARACTERS. The chemical characters of principal use in the determination of minerals comprise the phenomena developed by the action of acids, and those produced by the application of the blowpipe. Before referring to these characters, the reader should be familiar with cer- tain chemical terms of common employment in Mineralogy. A substance of any kind, whether of natural or artificial formation, must be either a simple or a compound substance. If the former, it cannot be decomposed or subdivided into more simple bodies by any process of art. If compound, on the other hand, a decomposition of this kind may be more or less readily effected. Thus, whilst from a piece of sulphur, copper, or iron, if pure, nothing but sulphur, copper or iron respectively, can be extracted, a piece of copper pyrites will yield all three of these substances — each, as before, resisting further subdivision. Hence sulphur, copper, and iron are regarded as simple substances, whilst copper pyrites is a compound body. These so-called "simple" substances, it must be understood, may not be, and probably are not, absolutely simple; but they are simple, id est, undecomposable, in the present state of science. They are often known as Elements. Up to the present time between sixty and seventy have been recognized, but many occur only in a few rare minerals. Some — oxygen, nitrogen, chlorine, fluorine, hydrogen — exist in the free state as gases ; two at ordinary temperatures are liquid ; the rest * The other dark -coloured cleavable masses, in these rocks, consist mostly of mica, ho n- blende, or tourmaline. OF CENTRAL CANADA PART I. 19 are solid. Some few occur naturally, at times, in the free or simple state. These form the so-called "native substances" (as Native Sulphur, Native Platinum, Native Gold, &c.,) of Mineralogists. Others occur only in combination. Some have a remarkable tendency to attack and combine with other bodies. Oxygen, chlorine, fluorine, sulphur and arsenic, in reference to natural compounds, may be especially cited in this respect. The binary compounds formed by these elements may be more or less passive bodies or bases, or active bodies or acids, although in some cases a strict line of demarcation cannot be drawn between the two. The bases have their generic name always terminated by the monosyllable " ide." Thus oxygen, in forming a compound of this kind, produces an oxide j chlorine, a chloride ; fluorine, a fluoride ; sulphur, a sul- phide ; and arsenic, an arsenide. Sulphur and arsenic compounds of this sort were formerly known as "sulphurets" and " arseniurets," but these terms have now passed out of use. When more than one compound of the above kind occurs, a distinctive prefix is added to the term. Thus red oxide of copper is often known as the " sub- oxide," whilst the black oxide of copper is known as " oxide " simply. The red oxide contains two parts (combining weights,) of copper to one of oxygen ; the black oxide, equal parts (combining weights,) of each element. In like manner the oxide or protoxide of iron con- sists of equal combining weights of iron and oxygen, whilst the the sesquioxide or peroxide has one-and-a-half parts of oxygen to one of iron — or, as more commonly given, three combining weights of the former to two of the latter element. [By some authors these compounds are known, respectively, as cuprous and cupric oxide, ferrous and ferric oxide — the termination " ic " denoting the presence of the larger amount of oxygen.] Active or " mineralizing " com- pounds into which the above and other elements enter, are still com- monly known as " acids," although many of these, it must be remem- bered, are insoluble compounds, and hence have no acid properties in the common acceptation of the term. By many modern chemists they are designated as " anhydrides." For present purposes we need only refer to oxygen compounds of this class. In these, the combi- ning weights of oxygen are always greater than in bases or oxides proper. Some elements form, with oxygen, several acids. Where two exist, the one with least oxygen has its generic name terminat- 20 MINERALS AND GEOLOGY ing in the monosyllable " ous " — as sulphurous acid, arsenious acid, tfec. ; whilst the monosyllable " ic " terminates the generic name of the more highly oxidized compound, as sulphuric acid, arsenic acid, &c. As regards minerals or natural inorganic substances, "ous" acids are all but unknown. The more common acids of the Mineral Kingdom — some of which occur both in the free state and in com- bination with bases, others in the latter condition only — comprise Silicic acid, (conventionally known as Silica), Carbonic acid, Sul- phuric acid, Phosphoric acid, Arsenic acid, Zirconium G-lucinum Yttrium, &c . . . . Thorium Magnesium Calcium Strontium Barium Lithium . • Natrium y. Kalium . . . 1 PHOSPHOR-SALT. The glasses produced by the fusion of constituent bodies with this reagent are for the greater part identical with those obtained by the use of borax, although somewhat less deeply coloured as a general rule. The principal ex- ceptions are the glasses formed in a reducing flame with compounds of Molyb- denum, Tungstenum, and Titanium, respectively. The molybdenum glass presents, when cold, a fine green colour, and the tungstenum glass becomes greenish-blue. If the latter contain iron, the colour of the glass is changed to blood-red or brownish red. Titanium in the presence of iron gives a similar reaction ; but when free from iron, the glass is yellow whilst hot, and violet- coloured when cold. Phosphor salt is an important reagent for the detection of silica in silicates, as the silica remains for the greater part undissolved in the glass, in the form of a translucent flocculent mass technically known as a "silica skeleton," the associated constituents being gradually taken up by the flux. A small amount of silica is also generally dissolved, but this is precipi- tated as the bead cools, rendering it semi-transparent or opaline. Phosphor- salt is likewise employed for the detection of chlorine, &c. (See Experiment 3, page 43. CARBONATE OF SODA. This reagent is principally used to promote the reduction of oxidized and other bodies to the metallic state, as explained under the description of that process. (Operation 6, below. ) It is also of frequent employment as a test for sulphur in sulphides and oxidized bodies. (See under Reactions.) It is rarely used, on the other hand, for the formation of glasses on platinum wire, except as a test for the presence of manganese ; although when employed, in this man- ner, it serves to distinguish salts of the alkalies, and those of strontia and baryta from all other salts : the alkalies, with baryta and strontia, dissolv- ing completely and rapidly in the bead, whereas lime, magnesia, alumina, and 36 MINERALS AND GEOLOGY other bases, remain unattacked. Manganese compounds form by oxidizing fusion with this reagent a green glass, which becomes blue or bluish-green and opaque on cooling. A very minute amount of manganese may be thus detected. The delicacy of the test is increased by the addition of a small quantity of nitre, as this promotes oxidation ; and if the 'substance contain much lime, magnesia, iron oxides, or other bodies more or less insoluble in carb. soda, it is advisable to add a little borax to the test-mixture. The blue or bluish-green bead thus produced, is technically known as a "turquoise enamel." Chromium compounds produce a somewhat similar reaction ; but if the bead be saturated with silica or boracic acid, it will remain green in the latter case. If the green colour result from the presence of manganese, on the other hand, a violet or amethystine glass will be obtained. Some other appli- cations of carbonate of soda as a blowpipe re-agent will be found under the head of REACTIONS. 6. Reduction : — This term denotes the process by which an oxidized or other compound is converted into the metallic state. Some 'com- pounds become reduced by simple ignition ; others require for their reduction the addition of certain reagents ; and some, again, resist re- duction altogether. The reduced metal is in some cases so highly volatile that it connot be obtained except by a kind of distillatory process. In other cases, one or more fusible globules, or a number of minute infusible grains, are obtained in blowpipe operations. Re- ducible metals may be thus distributed into three groups, as shown (with omission of a few metals of rare occurrence) in the annexed Table :— A. Yielding metallic globules : — Gold, Silver, Copper, Tin, Lead, Bismuth, Anti- mony. B. Yielding infusible metallic grains : — Platinum, Iron, Nickel, Cobalt, Molyb- denum, Tungstenum. C. Yielding metallic vapours only, when treated on charcoal : — Mercury, Arsenic, Cadmium, Zinc. A metal of the first group may be obtained, unless present in very small quantity, by a simple fusion of the previously roasted test-sub- stance, with some carbonate of soda, on charcoal, in a good reducing flame (Fig. 33 above). In ordinary cases, metallic globules are rapidly produced by this treatment. By a little management the globules may be brought together so as to form a single large globule. This must be tested on the anvil as regards its relative malleability, &c. Gold, silver, copper, tin and lead are malleable ; bismuth and anti- mony, more or less brittle. Gold and silver (if pure) retain a bright OF CENTRAL CANADA PART I. 37 surface after subj ection fco an oxidating flame. Copper becomes covered with a black film, and tin with a white crust. Lead and bismuth volatilize more or less readily, and deposit on the charcoal a yellow coating of oxide. Antimony is rapidly volatilized with deposition of a dense white incrustation, on the charcoal. It is not, of course always necessary to subject the test-substance to a previous roasting (Opera- tion 4, above) but it is always safer to do so. Sulphur in most, and arsenic in all cases, must be driven off by this preliminary treatment before the actual process of reduction is attempted. When the metal to be reduced belongs to the second group, or if the amount of fusible metal in the test-substance do not exceed 4 or 5 per cent., the operation is performed as follows. A small portion of the substance in powder — subjected previously to the roasting pro- cess, if it contain sulphur or arsenic— is mixed with 3 or 4 volumes of carbonate of soda (or neutral oxalate of potash, or a mixture of about equal parts of carb-soda and cyanide of potassium — the latter, it must be remembered, a highly poisonous substance), and the mix- ture is exposed on charcoal to a good reducing flame, until all the alkaline salt has become absorbed. Some more of the flux is then added and the operation is repeated until the whole or the greater part of the test-matter is also absorbed. The charcoal at this spot is finally separated by a sharp knife-point and carefully ground to powder in a small agate mortar or porcelain capsule, whilst a fine stream of water is protected upon it from time to time, until all the carbonaceous and other non-metallic particles are gradually washed away. For this purpose, the mortar or capsule may be placed in the centre of an ordinary plate ; and if the operator be not provided with a chemical washing-bottle, he may use a small syringe, or, still more economically, a simple piece of glass tubing, five or six inches in length and about the fourth of an inch in diameter, drawn out at one end to a point. This is filled by suction, and the water expelled, with the necessary force, by blowing down the tube. The metallic grains or spangles obtained by this process must be examined by the magnet. Those of iron, nickel and cobalt are magnetic. Sometimes, however, when but a trace or very small percentage of reducible metal is contained in the test-substance, its presence is only indicated by a few metallic streaks on the sides and bottom of the mortar. Metallic markings of this kind can be removed by a piece of pumice. 38 MINERALS AND GEOLOGY Metallic compounds referable to the third group, yield no metal charcoal, or by other treatment in open contact with the atmosphere. The presence of arsenic, however, is easily made known by the garlic - like odour evolved during fusion with reducing agents (or alone) on charcoal. Cadmium and zinc may also be recognized by the oxidized sublimates which they deposit on the charcoal. The Cadmium subli- mate is reddish-brown ; the zinc snblimate, lemon-yellow and phos- phorescent whilst hot, and white when cold. Mercury forms no incrustation on charcoal ; but its presence in any compound may be determined by reduction with carbonate of soda or iron-fillings in a glass tube of narrow diameter. A small test-tube or piece of glass tubing closed at one end before the blow-pipe, may be used for the experiment. The test-substance, in powder, mixed with 3 or 4 vols. of perfectly dry carb. soda, is inserted into the tube by means of a narrow strip of glazed writing-paper bent into the form of a trough, so as to prevent the sides of the glass from being soiled, and the mix- ture is strongly ignited by the spirit-lamp or by the blowpipe-flame. If mercury be present, a grey metallic sublimate will be formed near the upper part of the tube. By friction with an iron wire, or the narrow end of a quill-pen, &c., the sublimate may be brought into the form of fluid globules, which can be poured out of the tube, and are thus easily recognized as metallic mercury. 7. Cupellation: — Gold and silver are separated by this process from other metals. The test-metal is fused with several times its weight of pure lead. The button, thus obtained, is exposed to an oxidating fusion on a porous support of bone-ash, known as a cupel. The lead and other so-called base metals become oxidized by this treat- ment, and are partly volatilized, and partly absorbed by the bone-ash, a globule of gold or silver (or the two combined) being finally left on the surface of the cupel. For blowpipe operations, cupels are gen- erally made by pressing a small quantity of dry boneash into a cir- cular iron mould, the latter being fixed, when presented to the flame, in a special support, consisting essentially of a wooden foot and pillar with three or four short cross-wires (between which the cupel-mould rests) at the top of the latter. Instruments of this kind cannot be obtained in remote places, but the process may be performed equally well by the use of a small iron spoon, of about half-an-inch in dia- meter. Enough bone-ash to fill this, is taken up in it, and warmed OF CENTRAL CANADA PART I. 39 over the spirit-lamp or by the blowpipe flame. The spoon is then placed on the blowpipe anvil, and, whilst the smooth or unused end of the agate pestle (or other similar object, a glass button cemented to a cork, for example) is pressed firmly on the surface of the bone- ash, the handle of the spoon is moved three or four times from side to side. The surface of the cupel thus formed is then exposed for a few moments to the point of the flame, so as to render the bone- ash thoroughly dry ; and if its smooth condition be in any way affected by this treatment, the pressure with the pestle is repeated. Another equally good, if not better support consists of a cylindrical piece of pumice or well-baked clay with a small saucer-shaped depression for the bone-ash at its transverse end. The substance to be cupelled must be in the metallic state ; if not in this condition, therefore, it must first be subjected to the reducing process described above. In actual assaying or quantitative operations, this process is modified in various ways, but in the present work, in which merely a brief out- line of the use of the blowpipe is attempted, it would be out of place to enter into these details. The piece of test-metal, which may weigh about a couple of grains (or from 100 to 200 milligrammes) is wrapped in a piece of pure lead-foil of three or four times its weight, and the whole is exposed on the surface of the cupel to the extreme point of a clear oxidating flame. If the substance consist of argentiferous lead, as obtained from galena, tfec., the addition of the lead-foil is of course unnecessary.* Six or seven grains (or from 400 to 500 milli- grammes) may be taken for the experiment : a beginner, at least, will not find it advisable to operate on a larger quantity at one time. As * " In reducing galena, with a view to test the reduced lead for silver by cupellation, the reduc- tion may be conveniently performed as follows : a small portion of the galena, crushed to powder, is mixed with about twice its volume of carb. soda to which a little borax has been added. This is made into a stiff paste by the moistened knife-blade or blowpipe spatula, and a short piece of thin iron wire is stuck through it. The whole is then placed in a tolerably deep cavity scooped in a good piece of charcoal, and is exposed for a couple of minutes to the action of a reducing flame. By a little management, the minute globules of lead, which first result, can easily be made to run into a single globule. The iron assists in taking up sulphur from the galena. When sufficiently cool the fused mass is removad by a sharp knife-point, and flattened (under a strip of paper) on the anvil. The disc of reduced lead, thus separated from the slag, is then ready for cupellation." CHAPMAN'S BLOWPIPE PRACTICE. In the case of ordinary ores or matters suspected to contain gold or silver, tha roasted test- substance must be mixed with about an equal quantity of pure litharge or granulated lead and a proper amount of flux, aud subjected to fusion in a charcoal cavity. The lead or reduced litharge takes up any gold oa silver that may be in the ore, and this is set free by subsequent cupellation as described above. 40 MINERALS AND GEOLOGY soon as fusion takes place, the cupel must be moved somewhat farther from the flame, so as to allow merely the outer envelope of the latter, or the warm air which surrounds this, to play over the surface of the globule. By this treatment, the lead will become gradually con- verted into a fusible and crystalline slag. When this collects in large quantity, the position of the cupel must be slightly altered, so as to cause the globule to flow towards its edge, the surface of the lead being thus kept free for continued oxidation. When the globule becomes reduced to about a fourth or fifth of its original bulk, the process is discontinued, and the cupel set on the anvil to cool.* This is the first or concentration stage of the process. Another cupel is then prepared and dried ; and the concentrated globule (after being carefully separated from the slag in which it is imbedded) is placed on this, and again subjected to the oxidizing influence of the flame. During this second part of the process, the flame is made to play more on the surface of the cupel around the lead button, than on the button itself, by which a complete absorption of the oxidized lead is effected. The flame should be sharp and finely pointed, and urged down on the cupel at an angle of forty or forty-five degrees. Finally, if the test-metal contain gold or silver, a minute globule of one (or both) of these metals will be left on the surface of the bone-ash. By concentrating several portions of a test-substance, melting the concen- trated globules together, again concentrating, and finally completing the cupellation, as small an amount as half-an-ounce of gold or silver in a ton of ore — or in round numbers, about one part in sixty- thousand --may be readily detected by the blowpipe. During cupellation, the process sometimes becomes suddenly arrested. This may arise from the temperature being too low, in which case the point of the blue flame must be brought for an instant on the surface of the globule, until complete fusion again ensue. Or the hindrance may arise from the boneash becoming saturated, when a fresh cupel must be taken. Or. it may be occasioned, especially if much copper or nickel be present, by an insufficient quantity of lead. In this latter case, a piece of pure lead must be placed in contact with the globule, and the two. fused together ; the cupel being then * This is not always necessary, as in many cases the entire cupellation may be effected without interruption on the same cupel. OF CENTKAL CANADA PART I. 41 moved backward from the flame, and the oxidizing process again established. Reactions /—Certain reactions of the more commonly occurring constituents of mineral bodies have already been mentioned in illus- tration of the various operations given above. In the present place a few additional reactions are described, and the whole are arranged in systematic form.* A. DETERMINATION OF THE CHEMICAL GROUP TO WHICH A MINEARL MAY BELONG. In the examination of a mineral by the blowpipe, it is advisable to look first to its general chemical nature — or, in other words, to deter- mine the chemical group to whicn it belongs — and afterwards, to seek for the base or bases which it may contain. The more important chemical groups of natural occurrence, comprise : Sulphides, Arsenides, Chlorides, Fluorides, Oxides, Sulphates. Silicates, Carbonates, Borates, Nitrates, Phosphates, and Arseniates. The group of simple Oxides can only be determined by negative characters, but the other groups are easly recognized by a few simple experiments. Experiment 1. Fuse the substance, in powder, with 2 or 3 vols. of carb. soda and a little borax, in a good reducing Jlame, on charcoal. This experiment serves directly for the detection of Sulphides, Sul- phates, Arsenides, and Arseniates. a. A strong odour of garlic is emitted : — Arsenides and Arseniafes. The former possess a metallic aspect, and emit the garlic "odour when ignited per se. The latter never exhibit a metallic aspect. As occur- ing in nature, arseniates are mostly of a green, blue, or red colour, depending on the nature of the base. b. A reddish or dark mass is produced. This, when moistened and placed on a bright silver coin or on a glazed visiting card, forms a dark stain. The moistened mass smells also of sulphuretted hydro- gen : Sulphides and Sulphates. The former possess a metallic aspect, or, if the lustre be non-metallic, the streak is always distinctly col- oured, f With few exceptions, they omit an odour of burning brim- stone (sulphurous acid) when ignited per se ; and in the open tube, * A more complete method for the rapid determination of the chemical nature and composi- tion of mineral bodies will be found in the author's BLOWPIPE PRACTICE, pages 60-65. t Certain specimens of Zinc Blende are the only exceptions to this, so far at least as regards naturally occurring- minerals, to which alone the statements of the text apply. 42 MINERALS AND GEOLOGY the evolved acid reddens moistened litmus-paper. (See Operation 4, above.) The natural sulphates do not possess a metallic aspect, and the streak is either colourless or pale green or blue. They do not omit the smell of brimstone when heated, Other results, if exhibited, may be noted down for after reference. Remarks : — Reactions a and b are sometimes produced by the same mineral, from the simultaneous presence of sulphur and arsenic, (Arse- nical Pyrites, Realgar, Orpiment, &c.) Reaction b is also produced by Selenides and Seleniates, but these are of exceedingly rare occurrence , and they evolve at the same time a strong odour of cabbage-water or decomposing vegetable matter. The rare tellurides also exhibit the reaction. Experiment 2. Fuse a solid particle of the test-mineral with phos- phor-salt on platinum wire. This experiment serves directly for the detection of Carbonates and Silicates. a. The substance dissolves rapidly and with marked effervescence : — Carbonates (essentially).* Note : — Sulphates, Phosphates, and various other compounds, also dissolve readily by fusion with phosphor-salt, but produce no effer- vescence. b. The substance dissolves in part only, the undissolved portion retaining the original form of the test-fragment but becoming more or less translucent. (On cooling, the glass often becomes opales- cent) : — Silicates (see under " Phosphor-salt," page 35, above). Free silica, or quartz, melts into a clear glass with carb. soda, in expelling, with effervescence, the carbonic acid from the latter. Some silicates produce the same reaction. The test-substance should be added little by little. If the soda be in excess, the glass remains opaque, and with too much silica it becomes infusible. Note : — Other reactions that may ensue from this experiment, such as the coloration of the glass, &c., may serve to detect the base or bases in combination with the carbonic or silicic acid. These reactions, therefore, should be noted down for after reference. *Nitrates and certain bodies (Pyrolusite or Black Manganese Ore, &c.) which evolve oxygen on ignition, also dissolve in phosphor-salt with effervescence before the blowpipe ; but these bodies are of comparatively exceptional occurrence. To avoid risk of error, however, the sub- stance may be warmed in a test tube with a few drops of hydrochloric acid. Thus treated, all carbonates dissolve with marked effervesence, and evolve a colorless, inodorous gas. OF CENTRAL CANADA PART I. 43 Experiment 3. Dissolve a few particles of black oxide of copper in phosphor-salt on platinum wire, so as to form a strongly-coloured glass. (Or simply melt some of the salt in a loop of thin copper-wire.) To this, add the test-substance, in powder, and expose the whole to the point of the blue cone. This experiment serves directly for the detection of chlorides. a. The fused bead is surrounded by a bright azure-blue flame. Note : — The coloration is produced by the volatilization of chloride of copper. It ceases therefore, after a time, but may be renewed by more of the test-substance being fused into the bead. The rare Bromides and Iodides can also be distinguished by this experiment. The former produce a blue flame with green streaks and edges, the latter a bright emerald-green coloration. Experiment 4- Moisten the substance, in powder, with a drop of sul- phuric acid, and expose on platinum wire to the point of the blue flame. This experiment serves for the detection of Phosphates and Borates. as these bodies impart, when thus treated, a clearly marked green colour to the flame-border. The borates communicate also a green colour — after previous treatment with a few drops of sulphuric acid — to the flame of alcohol. The phosphates and borates of natural occur- rence are without metallic aspect. All dissolve readily in borax and phosphor-salt before the blowpipe. Many communicate a green colour to the point of the flame when strongly ignited, per se. It must not be forgotten, however, that certain other bodies, oxide of copper, baryta, &c., also colour the flame green. Phosphates may also be detected as follows : — Melt some of the substance in fine powder with about 3 vols. of carb. soda, on platinum wire, or in a small platinum spoon. Treat the fused mass with a few drops of boiling water (in a test-tube, or, better, in a small porcelain or plati- num capsule, over the spirit lamp), decant the clear solution ftpm the insoluble residuum, add some nitric acid, and place in the solution a fragment of ammonium molybdate. This forms a canary-yellow precipitate with solutions of phosphates. In most cases the mineral may be treated directly (in powder) with nitric acid, and the diluted solution tested with ammonium molybdate. The yellow precipitate rapidly forms on the solution being warmed. It is readily soluble in ammonia. 44 MINERALS AND GEOLOGY Experiment 5. Heat a small portion of the substance, in powder, at the bottom of a test-tube, with a few drops of strong sulphuric acid. This experiment serves for the detection of Fluorides and Nitrates. a. The inside of the tube is more or less corroded, and also covered, where damp, with a deposit of silica : — Fluorides. The results are best seen by washing out the tube, and then drying thoroughly in the flame of the spirit lamp. The corrosion arises from the formation of a compound of fluorine and hydrogen which readily attacks silica, pro- ducing a volatile compound of fluorine and silicon. This is decom- dosed by water, with deposition of silica. The latter re-action may be seen on the damp sides of the glass, and still more distinctly if a piece of narrow tubing with a drop of water at the end (kept there by the pressure of the finger at the other extremity) be brought within the mouth of the test-tube. The deposit of silica adheres to the glass with great tenacity. b. Brownish or orange-coloured fumes are evolved : — Nitrates. The fumes possess the peculiar sweetish smell of nitrous acid. A.11 nitrates of natural occurrence are more or less soluble in water. They deflagrate when ignited on charcoal or in contact with other organic bodies. B> REACTIONS OF THE MORE COMMON MINERAL BASES. In many minerals, the so-called base — lead, for example, in sul phide of lead (galena), copper in red or black oxide of copper, baryta in carbonate of baryta, and so forth — may be easily recognized by the use of the blowpipe. This is especially the case, when the base con- sists of a single and easily reducible metal or metallic oxide, such as silver, lead, copper, tin, &c., or where it imparts a colour to borax or other reagents, as in the case of copper, iron, cobalt, nickel, manganese, &c.; or forms a deposit on charcoal, communicates a colour to the flame, or exhibits other characteristic reactions. Evei when several bodies of this kind are present together in the baf their recognition, as a general rule, is easily effected. Earthy am alkaline bases, when in the form of carbonates, sulphates, phosphates, fluorides, [Also Iserine (No. 32) Hardness sufficient to scratch glass 7 Hardness insufficient to scratch glass 15 ( BB, emitting fumes, or odour of garlic or brimstone 8 | BB, 110 fumes or odour 10- ( Colour, light brass-yellow 9 ( Colour, tin-white or greyish ARSENICAL PYRITES (No. 22. )• In cubes or other Monometric Crystals (p. 14), or massive IRON PYRITES (No. 20.) In pointed, Prismatic Crystals of the Rhombic System (p. 16.), mostly arranged in curved rows Marcasite or Prismatic Pyrites* (No, 21.) in ( BB, easily fusible Wolfram (No. 39.) j BB, infusible, or nearly so 11 ( Streak-powder, dull-red SPECULAR IRON ORE (No. 29. ) ( Streak powder, black or brown 12 ,„ I Strongly magnetic MAGNETIC IRON ORE (No. 31.) j Not (or very feebly) magnetic 13- o \ Streak, black, brown, reddish-brown, or greenish 14 ( Streak, brownish-yellow. Yielding water in the bulb- tube. . . BROWN IRON ORE (No. 34.) ( Black, sub-metallic. BB, with phosphor-salt in R. F,, a fine green glass 14 1 CHROMIC IRON ORE (No. 33.) ( Black, sub-metallic. BB, with phosphor-salt in R. F., a red-brown glass TlTANIFEROUS IRON ORE (No. 30.)* , - ( More or less distinctly malleable 16 10 Not malleable " 20 16 BB, no fumes, or deposit on charcoal 17 BB, copious fumes, or incrustation on charcoal 18 * Iron Pyrites and Marcasite have exactly the same, composition (Sulphur 53.3, Iron 46.7) but their crystal forms are quite distinct. Iron Pyrites is very abundant : Marcasite, in Canada,, comparatively rare. Marcasite is especially prone to decomposition. ; specimens are thus often, coated wit a greenish-white efforescence, or minute hair-like crystals, of sulphate of iron. OF CENTRAL CANADA PART II. 51 ( Colour, yellow (soft) : , . . .GOLD (No 3 ) 17 I £ Sllvei"wnite (soft) SILVER (No. 5. ) ) 0. copper-red (soft) COPPER (No. 6. . C. steel-grey ; magnetic (hard) Meteoric Iron (No. 10. ) 18 < ^' on cnareoal> a copious yellow incrustation 19 ( BB, on charcoal, no incrustation. Colour, black. . SILVER GLANCE (No. 11.) 19 ( Colour, lead-grey. Perfectly malleable . , Lead (No 7 ) ( Colour, tin-white. Slightly malleable . , , . Bismuth (No.' 8.) Structure distinctly scaly or micaceous, the substance admitting of sepa- ration into thin leaves, plates, or scales 21 Structure not micaceous or scaly } JJaj king or soiling '.'.'.]'.'..'. 21 ' / JNot marking or soiling 23 2j 5 Marking on paper. Streak, black 22 i Not marking. Streak, white or greyish (Mica) ...'.' . . . . .... .' . .' . .' 21 Us. 21 bis \ £Totattacked by acids... MUSCOVITE or POTASH-MICA (No. 77.) I Decomposed (in powder) by sulphuric acid PHLOGOPITE or MAGNESIA MICA (No. 78.) j Colour, black. BB. not dissolved by fluxes GRAPHITE (No 1 ) 22 , Colour, lead-grey, BB, giving sulphur-reaction (see p. 44) with carb ' soda and borax MOLYBDENITE (No. 23.) ( Attracting the magnetic needle. Colour, brownish-yellow MAGNETIC PYRITES (No. 19.) ( JN ot anectmg the magnetic needle 24 24 i -^' easily fusible (with or without previous decrepitation) . . .25 I BB, infusible, or nearly so ' 34 9£ ( BB, a magnetic globule 26 ( Fusion-globule not magnetic 28 dark'lead gre7 .............................. Teunantite (No Colour metallic-ellow or red 26 bis 3 In acicular form only -. . Millerite' (No. IS. ) I Not acicular 07 ( Colour brass yellow (sometimes with iridescent tarnish COPPER PYRITES (No. 16.) 27 j Colour reddish, but with purple tarnish BORNITE, (Horse- flesh Ore, No. 15.) Colour pale-red or yellowish. BB, yielding arsenical fumes Nickeline some examples, (No. 17.) 28 j Colour pale-red or yellowish Nickeline (most examples, No. 17.) ( Colour, metallic white or grey 29 29 j BB, no coating on charcoal COPPER GLANCE (No. 14.) I BB, a white or yellow coating on charcoal .30 «JQ | BB, a white coating on charcoal 31 | BB, a yellow incrustation on charcoal .32 31 j Lamellar or flne-granular in structure Native Antimony (No. 9 ) / Fibrous or bladed Antimony Glance (No. 25.) ( BB, with mixture of potassium iodide and sulphur forming on charcoal a vivid scarlet coating 33 ( BB, as above, no scarlet coating 33 bis 52 MINERALS AND GEOLOGV ( Sp gr. over 9, reddish tin white Native Bismuth, (No. 8.) I Sp. gr. under 7, light lead-grey, often iridescent Bismuth Glance (No. 24.) , . j Breaking into rectangular fragments GALENA (Mo. J2.) '8 I BB, yielding antiinonial fumes. . . .Menighinite aud Plumbigerous Antimony Ore, (Nos. 25 and 25 />;*.) Lustre distinctly metallic ; streak greyish-black ; mostly fibrous or acicular ...Maniranite (No. 35.) Lustre sub-metallic ; streak, mostly pale brown ; BB, sulphur-reaction, p. 44 .ZINC HLi-;.N DE (No. 13.) r Soluble or partially soluble in water. Taste bitter or metallic. Occur- ring chiefly as an efflorescence or incrustation 36 35 -j ( Occurring in earthly masses or crusts (which soil or mark | Insoluble ] more or less) 39 ( Occurring under other conditions 48 BB, with borax, a coloured glass or bead 37 BB, with borax, a white or colourless beard 38 ( Solution giving a deep blue precipitate with red or yellow "prussiate of 37 ] potash."* Green Vitriol (Sulphate of Iron) (No. 100.) ( Solution giving a greenish-white precipitate with " yellow prussiate." Sulphate of Nickel (No. 101.) ( BB, with nitrate of cobalt, a blue mass after ignition (see p. 34.) 38 ) Alum (No. li ( BB, with nitrate of cobalt, a pale-red mass Epsomite (No. 99.) OQ j Colour, yellow or yellowish-brown 40 | Colour, red, black, brownish -black, blue, or green 43 BB, taking fire and burning with blue flame Sulphur (No. 2.) BB, not inflammable . . 41 BB, becoming black and magnetic 42 BB, not rendered magnetic Uran Oehre (No. 37 .) .^ ( Occurring in thin crusts on bituminous shale Humboldtine (No. 108.) " | Occurring under other conditions YELLOW OCHRE (No. 34.) ( Colour, red. BB, becoming magnetic .. RED OCHRE and SCALY RED 43] IRON ORE (No. 29.) ( C. black, dark -brown, blue, or green 44 44 \ Q' black or dark-brown 45 j C. blue or green , 46 !BB, inflammable Asphalt (No. 110.) BB, not inflammable. Forming with carb-soda a ''turquoise enamel," p. 39 EARTHY MANGANESE ORE (No. 36. ) 47 (Green Carbonate of Copper) (No. 95. ) ,~ j Colour, blue 47 Colour, green. Effervescing in acids Malachite (Green Carbonate * As the iron is always partly peroxidized, a blue precipitate is produced by either of these reagents. OF CENTRAL CANADA PART II. 53 ( Effervescing in acids ; BB, reactions of Copper (p. 37. ). . Blue Carbonate of Copper (No. 95. ) 3B, rendered magnetic Vivianite (Phosphate of Iron) (No. 104.) 48 •! -^arc^uess sufficient to scratch window-glass distinctly 49 I Hardness insufficient to scratch glass distinctly 69 49 \ Fusible or partially fusible, per se* 50 I Infusible, per se 61 *n i Sp. gr. = 3.0 or less. (Colour, mostly pale..). . 51 )U j Sp. gr. o ver 3. 0 \ . . . 56 51 j Yielding water by ignition in bulb-tube (see p. 34) 52 i Not yielding water, or yielding traces only, on ignition 53 ( Fusible on thin edges, only. C. dark-green Chloritoid (No. 81.) 52 j Easily fusible. C. light-green, greenish- white PREHNITE (No. 67.) ( Easily fusible. C. peach-blossom red Wilsonite : var. of Scapolite (No. 63.) 53 j Easily fusible SCAPOLITE OR WERNERITE (No. 63. ) | Fusible on edges only, unless in thin splinters 54 ( White, red, &c. In masses with smooth rectangular cleavage. . . 54 j ORTHOCLASE (No. 57. ) Cleavage not rectangular. Cleavage planes faintly striated 55 ( White, reddish, &c. BB, imparting a yellow colour to the flame ALBITE (No. 58.) ( Grey, often with coloured reflections LABRADORITE (No. 60.) In rhombic dodecahedrons or trapezohedrous (p. 14), or in imbedded granular masses mostly of a red colour GARNET (No. 47.) In fibrous masses or prismatic crystals 57 I In black, brown, or green triangular prisms (often broken and disjointed 57 < or in fibres with triangular cross fracture TOURMALINE (No. 46. ) ( In other forms g'g _ j In tetragonal (square prismatic) crystals (p. 15). Sp. gr. 3.5 or more. . Idocrase (No. 48.) ( In other forms 59 i Fusible into a globule or rounded mass AMPHIBOLE (No 52 ) PYROXENE (No. 53. ) -b usible on th-e surface, only, into a dull slag or scoria 60 ( In flat wedge-like crystals, mostly dark-brown or yellowish SPHENE(No.51.) in green nbrous masses and long prismatic crystals EPIDOTE (No. 49. ) 61 j Streak-powder, white, or greyish in dark specimens .62 ( Streak-powder, black, brown, greenish or red ' 66 * In testing this character, only a thin, pointed 56 54 MINERALS AND GEOLOGY Sp. gr. under 2.8 ; H = 7.0 ; vitreous ; fusible with carb-soda into a 62 «! clear glass QUARTZ (No. 43.) Sp. gr. overS.0 63 rq j Harder than quartz ' 64 M / Less hard than quartz , 65 { Crystallization, Hexagonal ; H = 9.0 ; sp. gr. 3.8 — 4.1 Corundum (No. 41.) j Crystallization, Octahedral (Regular System); H = 8.0 ; sp. gr... . I 3,5_45 Spinel (No. 42.) * ] Cystallization, Square-pyramidal (Tetragonal System) ; H=7.5 ; sp. gr. 4.0—4.7 Zircon (No. 44.) | Crystallization, Rectangular-prismatic; H = 7.0 — 7.5 ; sp. gr. 3. 1 — I 3'.2 Andalusite (No. 45.) ( Red or orange ; Lustre inclined to semi-metallic ; sp. gr. 4. 1 — 4. 3 Rutile (No. 40.) rp. J Yellow ; in small granular masses (mostly with graphite in crystalline limestone); sp. gr. 3. 1 — 3.2 Condrodite (N7o. 56. ) j Green, brownish-yellow ; in crystalline grains in eruptive rocks ; sp. gr. I 3.3 — 3.5 » Olivine (No. 55.) Strongly magnetic MAGNETIC IRON ORE (No. 31.) Feebly (or non-) magnetic 67 ( Streak-powder, black or brown 68 [Streak-powder, pull-red RED IRON ORE (No. 29.) BB, with borax, an emerald-green glass CHROMIC IRON ORE (No. 33.) BB, with borax, a dingy-green glass.. . TITANIFEROUS IRON ORE (No. 30.) fiq ( BB, fusible, or imparting distinct colour to the flame, or both 70 J | BB, infusible (or fusible only at the external point) 77 ( BB, easily dissolved by borax or phosphor-salt, the saturated glass be- 70 l coming opaque on cooling or when flamed (p. 37) 71 y BB, slowly and incompletely dissolved by borax or phosphor- salt, a ( " silica skeleton" (p. 39) separating in the latter reagent 74 „, ( BB, yielding sulphur-reaction with carb-soda and silver foil (p. 44) .... 72 | BB, no sulphur-reaction with carb-soda, &c. Mostly in cubical crystals . . FLUOR SPAR (No. 106.) 72 ( Yielding a large amount of water by ignition in bulb-tube i^-V GYPSUM (No. 98.) \ » A JL JL kJ ^jf J.TA \ J-l \J. i/ S •** (k) Pearly-white, brown, black, &c. In leafy and scaly masse with more or less pseudo-metallic lustre. Splitting into thin plates : — The various Micas, including more espe- cially : Muscovite or Potash-Mica (No. 77), and Phlogo- (_ pite or Magnesia- Mica (No. 78). a, >J. ses OF CENTRAL CANADA PART II. 59 ^ ( (1) Streak, pale-brown. Colour, brown, black, yellow, &c. Mostly in in- distinct crystals or small cleavable masses : — Zinc Blende (No. 13). (ra) Streak, dull or bright-red. Colour, brick-red. Magnetic after ig- nition : — Red Ochre and other varieties of Red Iron Ore (No. 20). j>» (n) Streak, brownish-yellow. C., dark or light- brown. Magnetic after iguition, and yielding water in the bulb.tube : — Yellow Ochre and Brown or Bog Iron Ore (No. 34). (o) Streak, pale-green ; colour, green : — Malachite (No. 94). Some Chlorites (No. 80). (p) Streak, pale-blue ; colour, blue. Mostly in crusts or earthy masses : — Blue Carbonate of Copper (No. 95). Also Phosphate of Iron (No. 104.) SYSTEMATIC ARRANGEMENT OF MINERALS. Mineral bodies are characterized partly by composition, and partly by physical properties. Composition alone, is not sufficient in all cases to define or individualize a mineral species, as certain substances — Carbon, for instance, in Graphite and the Diamond ; Carbonate of Lime, in Calcite and and Arragonite — may occur in nature under two or more distinct physical conditions. On the other hand, a close resemblance, in general aspect and other physical characters, may be exhibited by minerals of very dissimilar composition. Minerals have thus a double nature, so to say — chemical and physical : the one frequently in apparent opposition to the other ; and in this lies the difficulty of framing a satisfactory classification of minerals. A system of arrangement based on chemical composition, although un- avoidably artificial in many of its details, is especially convenient for practical reference, and on the whole is perhaps best suited to meet the requirements of the general student. A system of this kind is adopted, therefore, in the present work. It comprises five leading- groups or classes. First, a group of simple or so-called Native Sub- stances, as Native Sulphur, Native Gold, Native Silver, &c., the naturally occurring elementary bodies of chemical language (See under " Chemical Characters " in Part I). Secondly, a group of Sul- phides and Arsenides, or compounds of sulphur, or of arsenic, with various metals : galena, iron pyrites, arsenical pyrites, are examples. Thirdly, a large group of oxygenized compounds, including Simple Oxides, as red iron ore, &c., and various so-called oxygen-salts, as Silicates, Carbonates, Sulphates, and the like. (See explanation of Chemical Terms in Part I. Also the explanatory remarks prefixed to the different groups and sub-divisions, in the following pages.) MINERALS AND GEOLOGY Fourthly, a group of Fluorides and Chlorides, compounds of nuori: or chlorine with bases. And, finally, a small group of carbonaceous matters, usually classed as Organico-Chemical substances, and re- garded commonly as products of alteration derived from Organic Nature. The sub-divisions of the system adopted, are shewn by- way of index, in the annexed tabular view. I. —SIMPLE SUBSTANCES : A. Native Non-Metallic Substances (1—2). B. Native Metals (3-10). II. — ARSENIDES AND SULPHIDES : A. Sulphides of Silver, Lead, and Zinc (11-13.) B. Sulphides of Copper (14-16). C. Arsenides and Sulphides of Nickel and Iron (17-22). D. Sulphide of Molybdenum (23). E. Sulphides of Bismuth and Antimony (24-26). III. — OXYGEN COMPOUNDS : A. Copper Oxides (27-28). Iron Oxides : B. C. D. E. F. G. H. (1) Hematite group of Iron Oxides (29-30). (2) Magnetite group of Iron Oxides (31-33). (3) Limonite group of Iron Oxides (34). Manganese Oxides (35-36). Uranium Oxides (37-38). Tungstenum Compounds (39). Titanium Oxides (40). Alumina and Aluminates (41-42). Silica and Silicates : (1) Quartz group (43). (2) Group of Basic Silicates (44-51). (4) (5) 16) (7) Group of Pyroxenic Silicates (52-54). Group of Chrysolitic Silicates (55-56). Group of Feldspathic Silicates ss (57-59). Group of Calcareo-Feldspathic Silicates (60-64). Group of Nephelitic Silicates (65-66). (8) Group of Zeolitic Silicates (67-76)' (9) Group of Micaceous and Chloritic Silicates (77-81). (10) Group of Talcose Silicates (82-83). (11) Group of Kaolinic Silicates (84-85). (12) Group of Copper and Nickel Silicates (86-87). I. Carbonates : (1) Group of Anhydrous Carbonates (88-93). (2) Group of Hydrous Carbonates (94-95). K. Sulphates (96-102). L. Phosphates and Arseniates (103-105). IV. — FLUORIDES AND CHLORIDES : A. Fluorides (106). B. Chlorides (107). V. — BODIES OF ASSUMED ORGANIC ORIGIN : A. Oxalates (108). B. Carbonaceous substances (109-113). OF CENTRAL CANADA — PART II. 61 I.— SIMPLE SUBSTANCE. [This group includes the Native Non-Metallic Elements and Native Metals of Canadian occurrence. Three of these, Graphite,— often termed Plumbago or "Black Lead," but consisting essentially of carbon, — Native Gold, and Native Silver, are entitled to rank amongst the economic products of the country ; and Native Copper may even- tually perhaps be added to the list. The rest occur in small quantities only, or under more or less obscure conditions.] A. NATIVE NON-METALLIC SUBSTANCES. 1. Graphite (Plumbago) :— Iron-black or dark steel-grey, with black lustrous streak, and metallic or sub-metallic aspect. Found occasion- ally in tabular hexagonal crystals, but more commonly in small scales, and in foliated and granular masses, which soil the hands, and leave a dark metallic trace on paper. Very sectile, and greasy or soapy to the touch. H = 1.0 — 2.0; sp. gr. 2.0 — 2.3 in pure specimens, but sometimes as high as 2.5. BB, quite infusible, and not dissolved by borax or ordinary fluxes. Consists essentially of carbon, with a variable amount of intimately intermixed siliceous or ferruginous matter, the so-called "ash." This, which becomes visible when the carbon is burnt off by long continued ignition, may vary from a mere trace to 40 or 50 per cent. The actual amount of ash scarcely affects the value of the plumbago. Samples holding 40 or more per cent, may possess as much marketable value as others in which no more than 8 or 10 per cent, is present. But a great deal depends on the composition of the ash, at least as regards certain uses. If the ash contain more than a very slight amount of lime or magnesia, the graphite is scarcely suitable for the manufacture of crucibles. A selected sample, from Buckingham, on the Ottawa, shewed the follow- ing composition : Carbon 80. 12 ( Silica 12.86 j Alumina 4 33 Ash 18 58 J *ron Oxide • 1-'07 Lime 0.16 | Magnesia .......*.'.'. trace Moisture 1.30 I Loss 0.18 Another sample yielded: moisture 1.14, ash 22.06, carbon 76.80. ^ In the form of small scales and flaky masses, graphite is widely disseminated throughout the area occupied by the Lauren tian series of rocks (Part V.) It occurs most commonly in the beds of crystalline limestone of this series ; but sometimes also in the gneissoid strata, MINERALS AND GEOLOGY where it appears occasionally to replace the mica of these rocks. It- occurs also in large flakes in some of the beds of iron-ore associated with the Laurentian limestones, as at Hull, on the Ottawa. In other places, graphite forms large lenticular masses, or actual beds a foot or more in thickness, in these limestones. Occasionally also, it occurs in the form of distinct veins, traversing different strata of the Lauren- tian series. The more important localities comprise, the townships- of Buckingham, Lochabar, Petite Nation, and Grenville, on the left bank of the Ottawa, where this useful mineral occurs in comparative abundance, and is more or less largely worked. Other localities com- prise, more especially, the township of Burgess in Lanark county, and Loughborough and Bedford in Frontenac ; but small quantities are met with in almost every locality in which crystalline limestone occurs. Graphite is found also in thin coatings and finely disseminated scales amongst many of the altered slates of the metamorphic region south of the St. Lawrence (See Part V.), as in Melborne, Shipton, and elsewhere, but nowhere in workable quantities. The chief employment of graphite or plumbago is in the manufacture of draw- ing pencils, and refractory crucibles, the common kinds and refuse being used as a polishing material for stoves, grates, - OF CEVT.RAFj CANADA PART II. APPENDIX TO GROUP I. 10. Meteoric Iron: — Dark steel-grey; malleable; strongly magnetic; H == 4.5 ; sp. gr. about 7.4 ; fracture, hackly. BB, infusible. An irregular mass of malleable iron weighing about 750 Ibs. was •discovered in 1854, on the surface of the ground, in the Township of Madoc. Its examination by Dr. Sterry Hunt showed the presence of 6.35 per cent of Nickel, with other characters belonging to ordinary examples of meteoric iron. It exhibits a dark coating of oxide, and contains a small amount of intermixed phosphide of iron (Schreiber- site) and magnetic pyrites. Nitric acid brings out on the polished surface the so-called Widmannstadt's figures, or intersecting lines and zigzag markings indicative of an irregular crystalline structure. II.— ARSENIDES AND SULPHIDES. [This sub-division contains the various compounds of arsenic and sulphur with metallic bases, hitherto found in Central Canada. These may be conveniently described under five groups, as follows : Sul- phides of Silver, Lead, and Zinc ; Sulphides of Copper ; Arsenides and Sulphides of Nickel and Iron ; Sulphide of Molybdenum ; and .Sulphides of Bismuth and Antimony.] A. — SULPHIDES OF SILVER, LEAD, AND ZINC. 11. Silver Glance or Argentite : — Black, or dark lead-grey; malle- able; Regular in crystallization, but occurring commonly in small irregular masses, or in leafy or delicate arborescent forms. H = 2.0 - 2.5 ; sp.gr. 7.2 — 7.4. BB, melts with bubbling, and yields a globule of metallic silver. 1 00 parts contain normally : Sulphur 12.90, Ril ver 87. 10. Hitherto, only found with native silver, Batchewahning Bay, Echo Lake, Bruce Mines, &c. It occurs also in many of the copper-ore veins of the Eastern Townships, as in Leeds (at the Harvey Hill and other mines), Halifax, Sutton, Brome, Shef- OF CENTRAL CANADA PART II. 71 ford, Stukely, Brompton, Acton, Melbourne, Cleveland, &c. Also reported from Coteau St. Genevieve, near Quebec. 15. Purple or Variegated Pyrites (Bornite, Erubescite, Horse-flesh Ore) : — Pale brownish-red, but always presenting a rich purple or variegated tarnish ; streak, greyish-black. Regular, but rarely cry- stallized ; mostly in irregular masses. Brittle. H = 3.0; sp.gr. 4.5 — 5.5. BB, fusible into a dark magnetic globule. Composition somewhat variable, but averaging : Sulphur 25, Copper 60, Iron 15. A sample from Lake Huron gave the author : Sulphur 24.03, Copper 63.19, Iron 11.86. This valuable mineral (the "horse-flesh ore" of miners) occurs in large and small masses, imbedded in, or scattered through, many of the altered strata of the Eastern Townships ; and also, though less abundantly, in quartz veins traversing these strata. Some of the more important localities comprise the celebrated Acton mine in Acton Township, the Halifax mine in the township of the same name, Sweet's mine in Sutton, Cold Spring mine and Balrath mine in Melbourne, the St. Francis mine in Cleveland, and the Harvey Hill mine in Leeds ; but it occurs also in other parts of these townships, as well as, more or less', throughout the entire district, associated most commonly with the ordinary or yelloy pyrites, and frequently with earthy malachite, copper glance, native copper, galena, &c. The country rock is usually a dolomitic limestone, or a chloritic or micaceous slate. See further, under Copper Pyrites, below. In other parts of Canada, this ore occurs but sparingly. It has been found at the Wellington and Bruce mines on Lake Huron j and in veins at Point-aux-Mines, Maimanse, and elsewhere, on Lake Sup- erior. Lake Huron specimens sometimes exhibit pseuodmorphs (tetra- hedrons of the Tetragonal System after Copper Pyrites. 16. Copper Pyrites (Chalkopyrite) /-—Brass-yellow, often with varie- gated tarnish ; streak, dark green, or greenish-black. Tetragonal in crystallization, but commonly found in irregular masses. Brittle. H = 3.5 — 4.0 ; sp. gr. 4.1 — 4.3. BB, melts into a dark magnetic globule ; after roasting, yields, with carb. soda, metallic copper. One hundred parts contain : Sulphur 34.9, Copper 34.6, Iron 30.5 This is the common ore of copper. It is familiarly known as " yel- low copper ore." It occurs in small quantities, both in veins and in scattered masses, among the Laurentian strata of various localities : MINERALS AND GEOLOGY more especially in the townships of Lake, Madoc, Elzevir, Hungerford, &c., in the County of Hastings ; North Burgess in. Lanark ; Escott and Bastard in Leeds, and throughout the gneissoid region generally between the Ottawa and Lake Huron. The accompanying veinstone is mostly calcspar, but in some places it consists of quartz, or is of a granitic nature. Specks of galena, blende, and iron pyrites, usually accompany the copper ore. This mineral has been found also in calc- spar veins traversing gneiss in Kildare, Joliette County, in the Pro- vince of Quebec. In the Huronian strata, this ore is far more abundant. Numerous veins, with quartz gangue, occur on the north shore of Lake Huron. Many of these veins carry workable quantities of copper pyrites, accompanied in most cases by small portions of variegated pyrites, and also by copper glance, iron pyrites, &c. The best known are those of the Bruce and Wellington Mines ; but others occur at Copper Bay, White Fish River, Spanish River, Garden River, Root River, Echo Lake, and elsewhere in that district. Yery large quantities have lately been found in the vicinity of Sudbury. Copper Pyrites occurs also in many localities on the east and north shores of Lake Superior, in veins traversing strata apparently of Cam- brian age (see Part V). These are known as the Copper-Bearing series of Lake Superior. Among other localities may be enumerated : Bach e wanning Bay, Maimanse, Point-aux-Mines, Mica Bay, Black River, Black Bay, Thunder Bay, and locations between Thunder Bay and Dog Lake on the Kaministiquia. Some of rhese veins carry but small quantities of ore, but others are exeedingly rich : those especially which occur in the vicinity of Black Bay, and in the country north of Thunder Bay. Samples from these latter districts, collected per- sonally, and others obtained by Mr. S. J. Dawson, have yielded amounts of gold varying from a few dwts. to about an oz. troy in the ton of 2000 Ibs. of ore. The gangue of these veins is either quartz, or a mixture of calcspar, heavy spar, amethystine quartz, and fluor spar ; and the copper ore is generally accompanied by galena, zinc blende, and iron pyrites. Finally, Copper Pyrites is widely distributed throughout many of the Eastern Townships in the Province of Quebec. In some places, the copper of this region is entirely in the form of yellow pyrites ; in others, chiefly in the state of purple or variegated ore (No 15, OF CENTRAL CANADA PART II. 73 above). The more important localities of the yellow ore, lie in the townships of Stukely (Grand Trunk)Mine, &c.), Ely (Ely Mine, rnbinations of cube and octahedron, in sim- ple octahedrons, pen- tagonal dodecahedrons, &c. (Figs. 37 — 41.) Found still more fre- quently in granular, nodular, and other irre- gular masses. H = 6.0 — 6.5 ; sp. gr. 4.8 —52. BE, emits sul- FlGS- 37 to «. phurous fumes, and melts into a dark magnetic globule. One hun- dred parts contain: Sulphur 53.3, Iron 46.7, but a small portion of the iron is occasionally replaced by cobalt or nickel. Many varieties, also, contain traces of both gold and silver. (In this connectiou, it may be observed that a percentage of 0.01 is equivalent to 2 oz. 18 dwts. 8 grs. (troy) in the ton of 2000 Ibs., or to 3 oz. 5 dwts. 8 grs. (troy) in the British ton of 2240 Ibs.) Iron Pyrites is of exceedingly common occurrence. It is present, more or less, in almost every mineral vein ; and occurs also, in crystals, grains, and irregular masses, in rocks of all ages and of various kinds. It sometimes forms the substance of organic remains, as in examples of Trilobites, &c., from the Utica Slate of Whitby and other localities. In this condition it arises most probably from the alteration of carbo- nate of iron. In the Laurentian rocks of North Hastings and adjacent counties, in the copper-bearing series. of Lake Superior, and in the altered strata of the Eastern Townships south of the St. Lawrence, auriferous varieties have been noticed ; but the amount of gold in these is scarce- ly sufficient to defray the cost of its extraction. In Elizabethtown (Lot 19, Range 2), near Brockville, and elsewhere in this vicinity, some large beds or veins of a cbbaltic variety occur. Large veins occur also in Clarendon, on the Ottawa ; in Terrebonne and Lanoraie ; in Hastings, and throughout that district ; as well as on the north shores of Lakes Huron and Superior. Extensive deposits are like- wise seen in some of the Eastern Townships (Garthby, Ascot, FlG' 50' alumina 72, magnesia 28, per cent. • in the black varieties (Pleo- naste, Ceylanite), the magnesia is largely replaced, however, by oxide of iron ; and in the dark green or greenish-black varieties (Gahnite, Automolite) it is almost entirely replaced by oxide of zinc. Small octahedrons and grains of a pale-blue colour (much resem- bling the spinel which occurs under similar conditions at Aker, in Sweden) are found in a crystalline limestone in the Seigniory of Daillebout, Jolliette County, in the Province of Quebec. Large and often very symetrical black crystals occur in crystalline limestone in Burgess, Lanark Co. ; and less perfect examples of a similar colour, accompanying fluor spar, apatite, and white orthoclase crystals, are found in a vein of flesh-red calcite, in the Township of Ross, in Renfrew County, on the Ottawa. H. SILICA AND SILICATES.* [This division comprises the different varieties of Quartz and Opal, or silica in the free state ; together with the natural compounds of silica with various bases, such as alumina, the iron oxides, magnesia, lime, soda, potash, and the like. Some of these silicates yield water when ignited ; others are anhydrous in their normal condition, but frequently yield traces of water as the result of incipient decomposi- tion. It is not possible t) arrange the silicates strictly in accordance with their bases, without separating, in many instances, substances which in general characters are closely allied ; and in some cases, an * For details respecting the crystallization characters of the silicates generally, the reader may consult the Notes attached to the Mineral Tables in the author's Blowpipe Practice. 92 MINERALS AND GEOLOGY arrangement of this kind would lead to a separation of varieti« of one and the same mineral. In the garnets, for example, cer- tain varieties contain magnesia, and others lime or oxide of iron, Chrysolitic Silicates ; (5) Feldspathic Silicates; (6) Calcareo-Feldspathic Silicates; (7) Nephelitic Silicates; (8) Zeolitic Silicates; (9) Micaceous and Chloritic Silicates ; (10) Talcose Silicates; (11) Kaolinic Silicates ; (1'2) Copper and Nickel Silicates. (1) QUARTZ GROUP. [This group includes the different conditions of Silica in its free or uncombined state. These conditions aje principally three : the crystalline anhydrous condition — yielding the different varieties of Quartz ; the Calcedonic condition ; and the uncrystalline, generally hydrated condition, giving rise to the various Opals. 43. Quartz : — Colourless or variously coloured, and vitreous or stony in aspect. Streak (normally) white. Frequently found in Hexagonal crystals, consisting almost invariably of a six-sided prism, transversely striated, and terminated by the planes of a six-sided pyramid. In many examples, however, the pyramidal planes, more especially, are of very unequal size, some of the faces being often abnormally developed so as to produce the partial or complete obliteration of the rest. The point of the pyramid is thus often ex- 94 MINERALS AND GEOLOGY tended into an edge, as in some of the accompanying figures. Qua occurs also, and more frequently, in masses of irregular shape, as well as in nodu- in lar and stalactitic forms, and in small grains. Cleavage, scarcely observ- able: fracturecon- choidal and un- even. H = 7.0 ; sp. gr. 2.5 — 2.8, mostly about 2.65. FIGS. 51 TO 53. BB, per se, quite infusible ; with carb. soda, melts with effervescence (due to the expulsion of the carbonic acid of the flux) into a trans- parent glass. Insoluble in the ordinary mineral acids. Consists, normally, of pure silica, the tints of the coloured varieties being due to accidental amounts of iron and manganese oxides, bituminous matter and other inessential ingredients. The principal varieties of Quartz, hitherto met with in Canada, are as follows : — ( a) Common Quartz, Rock Crystal : — Vitreous or stony • mostly colourless, but sometimes pale reddish, yellowish, greenish or grey. Forms an essential component of granite, mica-schist, gneiss, quartz- rock and various other crystalline rocks, and is thus present through- out the wide area occupied by our Laurentian strata, as well as in many localities where Huronian rocks prevail, and amongst the crys- talline strata of the Eastern Townships (see Part V.). Very common also in mineral veins : as in those of Thunder Bay, Lake Superior ; the Bruce Mines, Lake Huron ; Harvey's Hill Mine, in Leeds ; and elsewhere. Occasionally present likewise, in fissures and cavi- ties in limestone rocks, as in the vicinity of Quebec, where the crystals are known as Quebec diamonds. (b) Smoky Quartz : — In brownish crystals : Thunder Bay, Lake Superior ; also near Quebec ; and elsewhere. (<•) Amethyst : — In violet-coloured crystals, sometimes of large size. Fine specimens, associated with fluor spar, calcspar, pyrites, native silver, &c., occur in veins on Thunder Bay and throughout that district ; also on Spar Island, farther west, on Lake Superior. Many of these crystals present a deep reddish-brown colour on the OF CENTRAL CANADA— PART II. 95 outer surface, arising from a deposition of numerous minute spots of jasper or sesquioxide of iron. The colouring matter appears to con- sist in certain cases of a minute trace of some silver compound. (d) Chalcedony : — In nodular semi-tianslucent masses of a yellow- ish, grey, or reddish colour. Occasionally present in the amygdaloidal traps of Lake Superior. Also in thin bands or veins, with Jasper, on the River Ouelle in Kamouraska. The nodules pass more or less into semi-opal. (e) Agate : — In nodular masses of various clouded or banded colours, either feebly translucent or opaque. Yery abundant in the amygdaloidal traps of St. Ignace, Agate Island, Michipicoten, etc., on the north shore of Lake Superior, and in the shingle beaches of these islands. Also in the conglomerates of Gaspe' ; and in the pebbly beaches along the shores of Gaspe' Bay, arising from the destruction of these conglomerates. (f) Jasper : — In opaque rounded masses, and in beds, of a brown, red, green and other colour; sometimes striped or banded; and always more or less dull or earthly-looking on the fractured surface. Some remarkable quartz-rocks, evidently altered conglomerates, containing pebbles of red Jasper, occur on the north-west shore of Lake Huron. Many of the dark green and striped slates of Lake Huron, also, may be regarded as closely akin to Jasper. At Bachewahnung, on the east shore of Lake Superior, bands of red Jasper are associated with hematitic iron ore ; and layers and imbedded nodules occur in the copper-bearing series of the north shore, around Thunder Bay, &c. Many of the so-called agates of this region are properly Jaspers. Beds and layers of red Jasper, in places very ferruginous, are found in the crystalline strata of the Eastern Townships, as in Sherbrooke, Shipton, Broughton, &c., and on the River Ouelle. Jasper pebbles are associated also with agates in the conglomerates and Shingle beaches of Gaspe. (g) Chert or Hornstone : — Yellowish, brownish, reddish-white, grey, black, &c. Mostly in nodular and irregularly-shaped masses, and occasionally in beds and veins which often present a cellular or brecciated structure. Translucent to nearly opaque. Closely allied to Chalcedony and Flint. Occurs in the form of veins tra- versing syenite in the township of Grenville, at first pointed out by Sir William Logan. Also in layers, &c., in the upper copper- 96 MINERALS AND GEOLOGY bearing series of Thunder Bay, Lake Superior, and abundantly- imbedded nodular masses, and in thin layers in the Corniferous Formation of the Devonian series of Western Canada, on the shore of Lake Erie, (fee. ; as well as occasionally under similar conditions in limestones of the Niagara and Trenton groups. Hornstone, or related silicious matter, forms the fossilizing substance of most of the corals and brachipods of our Western Devonian beds, as well as that of many of the organic remains found in Silurian strata, as at Pauquette's Rapids on the Ottawa, and elsewhere. ( h) Sandstones ; Sands ; Gravel : — Sandstones consist essentially of quartz grains, cemented together, or consolidated by pressure (see Part III) ; whilst sands and gravel consist of the same substance in loose grains and pebbles. These rock matters, although occasionally colourless, usually exhibit various shades of yellow, brown, or red, from the presence of sesquioxide of iron. Sandstones are also occasionally of a green or greyish-green colour, in which case part of the iron is in the condition of protoxide. S6me of our purest sandstones and quartz sands are found at the following localities : Pittsburg township (near Kingston) ; Charleston Lake, in Escott ; Vaudreuil, on the Lower Ottawa ; Beauharnois ; the Gres Rapids, on the St. Maurice • Township of Batiscan ; and also near Brock- ville, Perth, Owen Sound, Dundas, &c. (see Part Y.) (2) GROUP OF BASIC SILICATES. [This group includes a small number of silicates in which the per- centage of silica varies from 30 to 40. The specific gravity is com- paratively high (=3.0 to 4.75) ; and the hardness sufficient in all cases to scratch glass strongly (=5.5 to 7.5, but mostly over 6.0)]. 44. Zircon: — Brown, red, reddish-yellow, with resino- vitreous aspect. In Tegragonal crystals, mostly square prisms, terminated at each extremity by a four-planed pyramid (Figs. 54, 55) ; occasionally also in small granular masses. H = 7.5 . sp. gr. 4.0 — 4.75. BB, quite infusible. Not attacked by acids. Consists of : silica 33.2, zirconia 66.8. Occurs with plumbago, wollastonite, pyroxene, FlQ. 54. FlG. 55< FlG< 69> Fl0i 70< ponent of trachytes and ordinary lavas. In the Laurentian strata so widely developed throughout the more northern portions of Canada (see Part Y), this mineral is consequently largely present ; and well denned cleavable masses, mostly of a flesh-red or greyish- white colour, may be obtained in almost every district in which gneissoid rocks occur, more especially from the coarser granitic veins by which these rocks are so commonly traversed. Some of the more remarkable Laurentian localities comprise : the townships of North Burgess, Elmsley, Grenville, Chatham, &c. : also the township of Ross, and other places in the neighbourhood of Calumet Falls ; and several spots on the north shore of Lake Huron. In Burgess (Lot 3, Con. 6), among other varieties, a striped red and brownish ortho- clase occurs. This presents iridescent reflections, and is the variety known as Perthite. It contains soda as well as potash. In Ross (Renfrew County) large white crystals occur with apatite and spinel OF CENTRAL CANADA PART II. 107 in calcite veins. Pale-red and other varieties are found in the Ottawa region, especially in the phosphate deposits. Orthoclase occurs also in the metamorphic strata south of the St. Lawrence, as in veins cutting altered slates in the townships of Inverness, Leeds, and Sutton ; and it is likewise present in many of the eruptive rocks of this district, notably in the porphyritic trachyte of Chambly, and in the trachytes of Montreal and Brome. These varieties, ac- cording to Dr. Sterry Hunt's analyess (Report: 1863, p. 476) con- tain nearly equal amounts of potash and soda. Orthoclase, in com- mon with other feldspathic silicates, yields by atmospheric decompo- sition, a white earthy clay, largely used, under the term of Kaolin, in the manufacture of porcelain. 58. Albite or Soda Feldspar : — White, red, greyish-white, &c., sometimes with pale-blueish or pearly opalescence. Triclinic in crystallization, but occurring commonly in lamellar masses, readily cleavable in two directions under angles of 93° 36 v arid 86° 24\ One of the cleavage planes usually exhibits a delicate striatiou. In other respects, Albite closely resembles Orthoclase. H = 6.0 ; sp. gr. 2.55 — 2.65. Average composition : silica 68, alumina 20, soda (with trace of potash, &c.) 12. Albite is a constituent of many trappean rocks, and it occurs also in certain granites and syenites, and in various metamorphic strata. An opalescent variety, known as Peristerite, occurs in the township of Bathurst (Lot 1 9, Con. 9), and also on the north shore of Stony Lake, in Burleigh. A white variety in cleavable masses of considerable size forms the feldspathic portion of certain granitic and gneissoid rocks of the more northern districts of the county of Ottawa. Fine crystals are also said to occur in a vein on Lake Massawippi (Stanstead), in the metamorphic region of the Eastern Townships. 59. Oligodase : — White, greenish, pale-grey. Triclinic in crystal- lization, and closely allied in all its characters to Albite, but contain- ing a somewhat smaller percentage of silica. The cleavage planes meet at angles of 95° 50' and 86° 10'. Occurs in Canada, according to Dr. Sterry Hunt, associated with black amphibole in the eruptive mass of Mount Johnson, in the district of Iberville, near the east shore of the River Richelieu. (6) GROUP OF CALCARBO-FELDBPATHIC SILICATES. [The minerals of this group are very closely related to those of the preceding division, but they are essentially lime-holding, and 108 MINERALS AND GEOLOGY contain a lower per centage of silica. They are more readily fus moreover ; and are decomposed, or at least strongly attacked, by hy- drochloric acid.] 60. Labradorite or Lime Feldspar: — Grey, greyish-white, greenish white, greyish-blue, with frequently reflections of a beautiful blue, green, orange or other colour. Triclinic in crystallization, but rarely occurring otherwise than in cleavable lamellar masses, the cleavage planes, which usually present a delicate striation, meeting at angles of 93° 40' and 86° 20'. H=6.0 ; sp. gr. 2.66—2.76. BB, in thin splinters, readily fusible. Decomposed, or strongly attacked, in powder, by hydrochloric acid. Average composition : silica 53, alumina 30, lime 12.5, soda 4.5. This species enters into the com- position of various trappean rocks, and it also forms, both alone and in admixture with other triclinic feldspars, large masses of crystal- line structure associated with gneiss and other metamorphic strata. In this latter condition, it predominates amongst the Upper Lauren- tian or so-called Labrador series of Canada (see Parts III. and V.). Fine examples occur in St. JeYdme, Morin, Abercrombie and Mille Isles, in the County of Terrebonne, north-west of Montreal ; and in boulders (probably from the above sources) scattered over Grenville Township, on the Lower Ottawa. The Labradorite of these locali- ties is frequently opaque- white on the surface from semi-decom posi- tion or weathering. A pale-blue and greyish variety, without opalescence, occurs in Chateau Richer (Montgomery County), below Quebec. Pale greenish-blue and other opalescent examples have been obtained from boulders in the Townships of Drummond and Lanark, west of the Ottawa ; and a range of feldspathic rocks, pre- senting fine examples of colour-reflecting Labradorite, occurs on the north shore of Lake Huron, east and south-east of French River. The occurrence of Labradorite at the latter locality was first made known by Dr. Bigsby. A granular variety, in which the opalescent tints only shew under the magnifying glass, occurs with scattered pyrites in a vein traversing Laurentian gneiss in the vicinity of Haliburton, Ontario. 6 1 . Andesite : — This is a somewhat doubtful species apparently intermediate in character between Albite or Oligoclase and Labra- dorite. A reddish, feldspathic mineral in cleavable and striated masses, from the Labrador rocks of Chateau Richer, below Quebec, OF CENTRAL CANADA PART II. 109 is referred to it by Dr. Sterry Hunt. Report for 1863, p. 478. Average composition : silica 59£, alumina 25f , lime 7}, soda 5, potash 1. Sp. gr. 2.66 — 2.67. 62. Anorthite : — This species is also very closely related to both Labradorite and Albite. It occurs in Triclinic crystals and cleavable masses of a greenish-white, reddish, pale-grey and other colour, with H = 6 — 6.5, and sp. gr. 2.66 —2.79. Fusible, and more or less readily decomposed by hydrochloric acid. Average composition : silica 44 — 47, alumina 30 — 35, lime 14 — 18; with small per- centage of soda, potash, &c. A variety found in boulders in the vicinity of Ottawa city was originally described under the name of Bytownite. Some of the feldspar of Chateau Richer, according to Dr. Sterry Hunt, belongs probably to this species. The feldspar which enters into the composition of the diorite of the Yamaska Mountain is also referred to it by the same observer; and fine crystals of Anorthite, according to Mr. Thomas Macfarlane, occur in a large dyke of dioritic porphyry, of which several rocky islets in the vicinity of Thunder Cape, Lake Superior, are mainly composed. *** The two following species are placed for convenience in this group, as they are essentially lime-containing silicates, fusible, and decomposable in hy- drochloric acid. 63. Wernerite or Scapolite : — White, grey, red, greenish, &c. Occurring in crystals of the Tetrrgonal System (mostly combinations of a square-based prism and pyramid), and in lamellar, columnar and sub-fibrous masses. H — 5.5 — 6.0 (under normal conditions, but often somewhat lower from incipient decomposition of the specimen) ; sp. gr. 2.6 — 2.8. BB, easily fusible, mostly with strong bubbling. Partially decomposed by hydrochloric acid. Average composition : silica 48, alumina 28, lime 18, soda 5, the latter some- times largely replaced by potash. Carbonate of lime and a small percentage of water are very constantly present in altered or weathered specimens. Scapolite occurs in the Laurentian limestones of Calumet Island, and in Grenville Township, on the Ottawa, as well as in most of the phosphate deposits of the Ottawa region. Also in large crystals and cleavable masses, with sphene and augite, in the Laurentian strata of Hunterstown, Maskinonge County, Quebec; and at Golden Lake, in Algona Township, County of Renfrew. An altered or semi-decomposed variety in violet-red or no MINERALS AND GEOLOGY greyish-red cleavable masses, from the vicinity of Perth, in Lanarl County, has been described under the name of Wilsonite. 64. Wollastonite : — White, pale-greenish, brown, grey, &c. Clino- rhcmbic in crystallization, and of the pyroxene type, but occurring sp. gr. 2.7 — 2.9. BB, more or less readily fusible. Decomposed, commonly in thin tabular masses of fibrous structure. H = 4.5 — 5.0 ; with separation of gelatinous silica, by hydrochloric acid. Essential composition : silica 51,7, line 48.3. In Canada, fibrous Wollastonite occurs in many of the crystalline limestones of the Laurentian series, mixed more or less intimately with pyroxene, mica, quartz, and other minerals. Grenville Township in Argen- teuil County, St. Jerome and Morin in Terrebonne, North Burgess in Lanark, and Bastard in Leeds County, are the best known localities. (7) GROUP OF NEPHELETIC SILICATES. [This group includes a small number of essentially anhydrous sili- cates of alumina and soda, in some of which chloride of sodium is also present, whilst others contain traces of chlorine or sulphuric acid. They fuse more or less readily, and gelatinize in acids. Canadian examples are .comparatively unimportant.] 65. Nepheline, including Elceolite : — White, brownish, greenish, blueish-grey, yellowish, dull-red. Hexagonal in crystallization, but occurring commonly in cleavable masses of a more or less greasy or vitreo-resinous lustre, forming the variety known as Elseolite. H = 5.5 — 6.0 ; sp. gr. 2.5 — 2.65. BB, easily fusible. Decomposed readily by acids, with separation of gelatinous or slimy silica. Average composition: silica 44, alumina 44, soda 17, potash 5. This species is said to occur in small orange-red granular masses in boulders with orthoclase and black ainphibole, on Pie Island, Lake Superior. Also, it is stated by Dr. Sterry Hunt, in white crystals in the granitic trachyte of Brome. (Jancrinite, a closely allied silicate, occurs, according to Dr. B. J. Harrington, in the nepheline- syenites of Beloeil and Montreal. 66. Sodalite: — Blue, greyish, colourless, and falls into powder. Soluble in acids with strong effervescence. Composition identical with that of calcite : carbonate of lime being thus a dimorphous body — i.e,, a substance capable of .assuming two distinct sets of physical characters. Fibrous arragonite 126 MINERALS AND GEOLOGY appears to occur sparingly amongst the Lake Superior traps ; and occasionally in stalactitic coatings on the sides of cracks in some of our limestone rocks, as in the township of Tring, and elsewhere, but no very distinct or crystallized examples have as yet been found. 90. Dolomite (Pearl Spar, Bitter Spar) : — White, grey, brownish, per cent, of iro: clay ironstone, as occurring in the Carboniferous strata of Europe and the United States, supplies a large number of furnaces, and yields metal of good quality. The nodules have usually a strongly- marked slaty structure ; and, when broken, they almost invariably exhibit the impression of a fern frond, fish skeleton, or other organic body. Small fragments after ignition before the blow-pipe, or in. a glass tube held over a common spLit lamp, assume at first a red colour, and then become black and magnetic. 93 bis. Strontianite : — This carbonate is stated by Dr. B. J. Har- rington to occur in the form of white fibrous tufts in cracks in some concretionary limestone masses in the Utica slate of St. Helen's Island, Montreal. It imparts a crimson colour to the blowpipe flame. (2) GROUP OF HYDROUS CARBOXATES. [This group is only represented in Canada by the some\vhat proble- matical Dawsonite, and by the two cupreous carbonates Malachite and Azurite ; and these latter species do not occur in well character- ized examples, but merely as incrustations on Copper Ores, or in the form of stains and small earthy masses in copper-holding rocks.] 94. Dawsonite : — In. white, thin-bladed aggregations or coatings on compact trachyte, Montreal, H = 3 ; sp. gr. 2.4, contains, according to Dr. Harrington, alumina, soda, lime, carbonic acid, and water. 95. Malachite or Green Carbonate of Copper : — Green of various shades, with pale-green streak. Monoclinic in crystallization, but crystals exceedingly rare. Mostly in botryoidal masses of concentric lamellar, and fibrous structure ; in earthy coatings on copper ores ; and in the form of streaks and markings in copper-holding rocks. H = 3.5 — 4.0 (in the solid state) ; sp. gr. 3.7 — 4.0. BB, tinges the flame green, and becomes rapidly reduced to metallic copper. Soluble in acids with effervescence. Essential composition : carbonic acid 20, oxide of copper 72, water 8. Occurs in small quantities with copper glance, native silver, &c., in a calc-spar vein on Spar Island, Lake Superior, and in small earthy incrustations and markings amongst many of the copper ores and associated veinstones of Lake Superior and Lake Huron, generally. Also under similar conditions in Madoc, Marmora, and various other localities in which copper pyrites occur in larger or smaller quantities ; and especially in the chlorite and OF CENTRAL CANADA — PART II. 129 other altered rocks of the metamorphic country south of the St. Law- rence, as in the townships of Leeds, Halifax, Inverness, Hani, Shipton, Cleveland, Stukely, Bolton, Brome, Sutton, &c. 96. Azurite or Blue Carbonate of Copper : — This species has hither- to been recognized only in small incrustations and stains of a blue colour, associated with malachite, at most of the localities named under No. 95, above. The blue carbonate contains : carbonic acid 25.6, oxide of copper 69.2, water 5.2. K. SULPHATES. [The mineral substances placed under this division may be regarded, according to the commonly received view, as compounds of sulphuric acid with one or more oxidized bases, such as baryta, lime, oxide of lead, alumina, and the like. As regards physical characters, these bodies exhibit a non-metallic aspect, and either a colourless or a very faintly-coloured streak, the colour in the latter case being green or blue, or occasionally yellow. They afford representatives of all the systems of crystallization : Rhombic and Clino-Rhombic types being especially abundant. H = 1.0 — 4.0. The sulphates may be easily distinguished from carbonates, phosphates, silicates, &c., by fusion in a reducing flame on charcoal with carb-soda ; or better with a mixture of carb-soda and a little borax, as the latter reagent facilitates the decomposition of earthy sulphates, and prevents the absorption of the fused mass. An alkaline sulphide is formed by this treatment. When moistened, and placed on a piece of silver or on lead test-paper (a bright coin or glazed visiting card may be used as a substitute), the fused mass produces a black or brown stain of sulphide of silver or sulphide of lead. The stain may be easily removed from the silver by friction with moist bone-ash. Amongst the sulphates generally, several natural groups stand out with great prominence. The Rhombic group of anhydrous species, for example, containing the Sulphates of Baryta, Strontia, Lime, Lead, &c. ; the Gypsum group ; the Monometric group of Alums ; the Prismatic group of Vitriols ; and others of subordinate impor- tance. The sulphates hitherto found in Canada, are too few, however, to admit of distribution into special groups of this kind. In the descriptions which follow, the anhydrous species Barytine and Celes- 10 130 MINERALS AND GEOLOGY tine are placed first. To these, succeeds the hydrous sulphate, Gy] sum ; and a few sapid types of obscure or comparatively rare occur- rence, close the list.] 97. Barytine or Heavy Spar : — White, yellow, reddish, pale-blue, grey, &c. Crystallization Rhombic (Figs. 77-78, and other combina- tions). Occurs very commonly in lamellar masses and aggregations of large flat crystals with cleavage angles of 101° 40', 78° 20\ and 90°, yielding a right rhombic prism. Also in masses of a granular or more or less compact structure. H = 3.0 — 3.5 ; sp. gr. 4.3 — 4.7, mostly about 4.4 — 4.5. BB, generally decrepitates, tinges the flame pale-green, and melts with great difficulty, often at the point only, into a white enamel. Dissolves entirely in carb-soda before the blowpipe. Not attacked by acids. Normal composition : sulphuric acid 34.33, baryta 65.67. This mineral occurs abundantly in many parts of Canada. In the Laurentian strata, FIG. 77. FIG. 78. it occurs in veins per se, and as a gangue or veinstone with galena — more especially in the townships of Lansdowne in Leeds County • Bathurst and North Burgess in Lanark County ; McNab, Renfrew County ; Dummer and Galway, in Peterborough County ; and Som- merville in Victoria County. A broad vein of white crystalline heavy spar is exposed along the side of the road in lot 7 of the 10th concession of Hull, near the Gatineau River. Red crystals were discovered by Mr. Murray on Iron Island, Lake Nipissing ] and other examples have been met with in the copper-ore veins of Lake Huron. Isolated pale reddish-yellow crystals (Fig. 78) were found by the writer (Canadian Journal, November, 1885,) in veins in Neebing Township near Fort William, Thunder Bay, Lake Superior, and sub- sequently in other mineral veins in that region. Massive and sub- crystalline varieties from also large veins on Jarvis Island, near Pigeon River west of Fort William, and also on Pie Island ; and other veins of a similar character are said to occur east of Thunder Cape, as at Edward Island in Black Bay, and elsewhere. Heavy Spar has also been noticed in some of the serpentines and other altered strata of the Eastern metauiorphic region south of the St. Lawrence, as on the Bras River, where a white variety occurs in small veins. Nodular masses of a red or reddish-yellow colour occur with fibrous OF CENTRAL CANADA PART II. 131 and granular gypsum in the Hudson River strata of Cape Rich on Georgian Bay ; and small crystals and crystalline masses are occasion- ally found in cavities of the dolomitic limestones of the Calciferous and Niagara groups, as near Brockville, and in the vicinity of Niagara Falls. Heavy Spar is employed in the manufacture of paints, and is too frequently used in this connection as a fraudulent substitute for white lead. It is also the chief source of the baryta salts of the laboratory. 98. C destine: — White, blue, grey, pale-red, &c. Rhombic in crystallization, the crystals frequently bearing a close resemblance to those of heavy spar. Occurring also in lamellar and crystalline masses, with cleavage angles of about 104°, 76°, and90°, yielding a right rhombic prizm ; and in masses of fibrous or granular struc- ture. H — 3.0 - 3.5 ; sp. gr. 3.95 — 3.97. BB, imparts a crimson colour to the point and border of the flame, and melts into a white alkaline enamel. Dissolves entirely, by fusion, in carb. soda. Not attacked by acids. Normal composition : sulphuric acid 43.6, stron- tia 56.4. This mineral occurs chiefly in sedimentary rock-forma- tions : very rarely in mineral veins or in crystalline rocks. In Central Canada, it is found somewhat abundantly in the interior of small cavities in the Black River or Trenton limestone of Kingston ; and also, with crystals of dolomite, gypsum, fluor spar, blende, and other minerals, in cavities in the Niagara limestone, as in the vicinity of the Falls ; around Owen Sound ; on Drummond Island ; and on the Grand Manitoulin, Lake Huron. A red variety has been recently found by Mr. Roche in freestone of the Medina formation at the forks of the Credit. Celestine is the principal source of strontia salts, used in pyrotechny to impart a red colour to rockets and signal lights, and for laboratory purposes. 99. Gypsum (Hydrous Sulphate of Lime, Selenite, &c,) : — White grey, yellowish, pale-red, «fec. Monoclinic in crystallization, the crys- tals very commonly as in Fig. 79 a, or in arrow-headed twins as in Fig. b, also in lamellar and foliated crystalline masses with strongly pronounced cleavage in one direction, and in fibrous and granular masses, the latter often forming rock deposits. The cleavage planes present a more or less pearly aspect, the other a FlGi 79> 132 MINERALS AND GEOLOGY crystal-faces exhibiting a vitreous or pearly-vitreous lustre. Granu- lar and rock varieties have mostly a dull earthy aspect. H — 1.0« 2.0; sp. gr. 2.25 — 2.35. Sectile, and, in thin lamellae, somewhat flexible. Becomes opaque when held at the edge of a lamp or candle- flame. BB, exfoliates, and melts into a white caustic enamel. In the bulb- tube yields a large amount of water. Soluble in hydro- chloric acid. Dissolves also, if in tine powder, in a large amount of water, and more readily in a solution of rock. salt. Normal composi- tion : sulphuric acid 46.51, lime 32.56, water 20.93. The transpar- ent crystals aud cleavable varieties are commonly termed selenite ; and the fibrous and fine granular varieties form the alabaster and satin spar of lapidaries, but these names are also bestowed on similar- varieties of carbonate of lime. When deprived of its water by ex- posure to a low red heat, gypsum is converted into plaster ov. Plaster- of Paris. Crystalline and fibrous masses, and occasionally distinct crystals of gypsum, associated with crystals of quartz,, dolomite, &c., occur in. cavities of many of the Silurian strata in Canada, and thin bands are interstratified in places with the shales and limestones of some of these formations. Gypsum occurs under these conditions in the- Calciferous formation of Beauharnois, the Hudson River formation of Point Rich on Georgian Bay, the Medina formation of St. Vincent,, and in the Clinton and Niagara strata in the vicinity of the Falls,. Hamilton, Dundas, and elsewhere. Rock masses of granular and compact gypsum, more or less mixedi with carbonate of lime, characterize the Onondaga Formation of" Western Canada, and occur largely in the valley of the Grand River :. more especially in the townships of Dumfries, Brantford, Oneida, Seneca, and Cayuga; as well as throughout the tract of country,, generally, between the eastern extremity of Lake Erie and the mouth- of the Saugeen. (See under the Onondaga Formation, in Part V.) The greater part of the gypsum from these localities is ground for agricultural use. 100. Epsomite (Epsom Sak) :-. — White or greyish. Soluble : taste,, strongly bitter. Rhombic in crystallization, but occurring chiefly in fibrous tufts and earthy or botryoidal incrusting masses. H = 2.0^ or less. BB, runs at first into liquid fusion, and then forms am alkaline infusible crust which., assumes a flesh-red colour if moistened OF CENTRAL CANADA PART II. 133 •with a drop of nitrate of cobalt and again ignited. Yields a large amount of water in the bulb-tube. Normal composition : sulphuric acid 32.52, magnesia 16.26, water 51.22. Occurs in Canada, as an •efflorescence or incrustation, on exposed surfaces, and on the edges of the planes of bedding, of shales and other strata, where it is formed ^apparently by the action of percolating water containing soluble matters derived from the decomposition of pyrites. It occurs thus in some of the slaty talcose layers associated with the iron ores of Marmora, and also on the weathered shales of the Utica series, near Montreal, Quebec, and Collingwood ; and still more abundantly 011 -some of the dolomitic beds of the Clinton and Niagara Formation, as near Dundas and elsewhere. Sulphate of magnesia occurs also in solution in the Tuscarora water, and in some other mineral springs. 101. Iron Vitriol (Green Vitriol, Copperas, Melaiiterite, &c.) : — Pale-green, greenish -white ; brownish-yellow by partial decomposition. Monoclmic in crystallization, but occurring mostly in efflorescent -crusts and minute hair-like indistinct crystals. Soluble : taste, inky ;and metallic. H = 2.0, or less. BB, blackens and becomes mag- netic. In the bulb-tube yields a large amount of water, and gives off sulphurous acid. The aqueous solution gives a deep-blue pre- oipitate with " red prussiate of potash ;" and in general also with the yellow prussiate, from the presence of more or less sesquioxide of iron. Normal composition : sulphuric acid 28.8, protoxide of Iron 25.9, water 45.3. Occurs on decomposing pyrites and marcasite, ^and on the exposed surfaces of rocks in which these minerals are present. It is thus found, in small quantities, on many of the ores from the mineral veins of Lake Superior, Lake Huron, the Hastings a^egion, and other parts of Canada. A specimen of iron pyrites from the Gal way Lead Mine in the northern part of the county of Peter- borough, became covered in the course of a few weeks with delicate tufts of minute acicular crystals of this mineral. 102. Nickel Vitriol (Morenosite) : — Pale-green, greenish-white. In efflorescent tufts of minute crystals on nickel ores. Soluble : taste, strongly metallic. BB, evolves sulphurous acid, swells up, and forms & dark grey mass. With borax, gives reactions of nickel oxide (see Part I.). In the bulb-tube yields a large amount of water. If free from iron, the aqueous solution does not yield a blue precipitate with «*ed or yellow " prussiate of potash." Normal composition : sulphuric 134 MINERALS AND GEOLOGY acid 28.5, oxide of nickel 26.7, water 44.8. Detected by Dr. Steriy Hunt, as an efflorescence on an aresenical nickel ore from the Wallace Mine, Lake Huron. (See No. 17, above.) 103. Alum: — Normally, white, but sometimes stained of a yel- lowish or brownish colour by sesquioxide of iron and other impurities. Monometric in crystallization, but occurring commonly in earthy efflorescent crusts. Soluble : taste, sharp and more or less bitter. BB, froths up and forms a white earthy mass which assumes a fine blue colour if moistened with a drop of nitrate of cobalt, and again ignited. Normal composition : sulphuric acid 33.75, alumina 10. 82, potash 9.95, water 45.48. Occurs in considerable abundance on the exposed face of some high bluffs of argillaceous shale (belonging to the Animikie series) on Slate River, a tributary of the Kaministiquia,, about twelve miles west of Fort William, Lake Superior. L. PHOSPHATES AND ARSENIATES. [These compounds are composed of phosphoric acid or arsenic acid with various bases. They present a vitreous or other non-metallia aspect. Phosphates when moistened with a drop of sulphuric acid (and many without this addition), impart a green colour to the point of the blowpipe flame. When fused, in powder, with carb. soda in, a platinum spoon, an alkaline phosphate is formed, soluble in water. The clear solution decanted from the insoluble residuum, and acidified by a few drops of nitric acid, yields a canary yellow precipitate with a drop or two (or small fragment) of ammonium molybdate. Arseniates, when mixed in powder with some carb. soda, and ignited on charcoal in a reducing flame, emit a very distinct odour of garlic^ Canadian examples, of this group, amount to only three in number, as riven below ; but, one of these, the lime fluor-phosphate. Apatite* occurs in comparative abundance, and is a substance of great com- mercial value.] 104. Apatite (Phosphate of Lime) : — Green, blueish-green, vioJet- red, rose-red, brownish, greenish- white, &c. — shades of green and dull-red being often present in the same specimen. Lustre, vitreous and vitreo-resinous, with frequently a slight opalescence on one of the cleavage planes: Crystalliza ion, Hexagonal : the crystals con- sisting most commonly of six-sided prisms, often of large size, and OF CENTRAL CANADA PART II. 135 frequently with rounded edges. Occurs also in lamellar cleavable masses, and occasionally in globular and other shapes with fibrous structure. H = 4.5 - 5.5, normally 5.0. Sp. gr. 2.9 - 3.3, most i ommonly about about 3.18 to 3.2. BB, in most cases quite infusible, but some varieties FIG. 79.* vitrify slightly at the point of the assay-fragment after exposure to a long-sustained blast. The powder moistened with sulphuric acid tinges the flame-point distinctly green. Melts and dissolves readily in borax and phosphor-salt, forming a glass which becomes opaque on cooling or when flamed. (See under Blowpipe-reactions in Part I.) Easily soluble in nitric or hydrochloric acid. The diluted solution, saturated with ammonia, yields a copious white precipitate of phos- phate of lime. This precipitate assumes a canary-yellow tint if treated with a solution of nitrate of silver, or if a crystal of that substance be laid in it whilst still moist. The presence of phosphoric acid may also be rendered evident in the diluted nitric acid solution by the formation of a clear-yellow precipitate with rnolybdate of ammonium.* Apatite consists essentially of phosphate of lime (or calcium, phosphorus and oxygen) combined with in general about 8 or 10 per cent, of fluoride of calcium or chloride of calcium, or with a mixture of both, the fluoride usually preponderating. Canadian examples appear to be essentially fluor apatites. The normal com- position of an apatite of this kind is equivalent to : phosphoric acid 42.26, lime 55.60, fluorine 3.37 ; or tribasic phosphate of lime 92.26, fluoride of calcium 7.74 ; but samples even when dressed for shipping usually contain a good deal of intermixed calcite and mica scales, and rarely run higher in tribasic phosphate than about 80 per cent. Extensive deposits of this mineral, chiefly in the form of veins, occur in the Laurentian strata of North Burgess and North Elmsley in the County of Lanark. These veins cut the enclosing strata transversely, and vary in width from an inch or two to several feet. The apatite, in crystals, and in cleavable and granular masses, is associated with phlogopite, pyroxene, and other silicates. Where * The test-solution is prepared by dissolving some of the crystallilzed molybdate in a very small quantity of water, nitric acid being added to the solution until the cloudiness or thick recipitate, which forms at first, becomes redissolved. When this is added to the solution of the mineral, the whole must be gently warmed. A yellow coloration, succeeded by a yellow precipitate, then quickly ensues. 136 MINERALS AND GEOLOGY the veins occur in contact with crystalline limestones, these latter contain in many places detached crystals and grains of apatite, with occasional masses of that substance. The most important phosphate region, however, lies on the left bank of the Ottawa, in Buckingham and adjacent townships, where the apatite occurs in the form of large lenticular masses and crystals in broad veins, with pyroxene, mag- nesiari mica (phlogopite), calcite, and other minerals.* Apatite occurs also in connexion with crystalline limestone, associated with fluor spar and octahedrons of black spinel, in the township of Ross in Renfrew county on the Ottawa • and with quartz and and calcite, at Calumet Falls. Small shews also are seen in many of the lime- stone bands throughout the Laurentian country between the Ottawa and Georgian Bay. Transparent pink and purple crystals are also reported by Dr. S terry Hunt to occur in association with crystals of augite in a mass of erupted dolerite (see Part III) at St. Roch on the River Achigan. Apatite has likewise been found, in a quartz vein carrying copper pyrites and native copper, with large plates of white mica, in the township of Burford, in the metainorphic district south of the St. Lawrence. Finally, it may be observed, small nodular masses consisting in great part of phosphate of lime, mixed with carbonates of lime and magnesia, sand, and other matters, are scattered through a conglom- erate of the (Lower Silurian) Chazy formation at the Allumette Rapids ', and similar nodules occur in limestone strata of the same formation in the townships of Hawkesbury and Lochiel, west of the Ottawa ; as well as in strata of the Quebec group at Point Levis, and on the River Ouelle. These phosphatic nodules present a chocolate or blackish-brown colour, and contain in some cases frag- ments of the shells of Imgulse (see Part IV) and other organic bodies. They are supposed to be coprolites or fossilized excrementous mat- ters. When heated, they emit an odour of burnt animal matter, and evolve ammonia. Phosphate of lime, when converted into super- phosphate by treatment with sulphuric acid, constitutes an agricul- tural fertilizer of the highest value. * Crystals of apatite consist most commonly of a simple hexagonal prism with large basal plane, but our Canadian crystals, when unbroken, are terminated by the planes of an obtuse hexagonal pyramid, the basal plane being thus entirely suppressed. This combination has hitherto been only seen in the so-called spargelstein of German mineralogists, from the mountains near Jumilla in the south east of Spain, and in the variety known as moroxite fror Arendal in Norway. CENTRAL CANADA PART II. .04. Vivianite (Hydrated Phosphate of Iron) : — Blue, bluish-green (normally, colourless, but becomes blue on exposure) ; streak pale- blue or blueish-white. Monoclinic in crystallization, with very per- fect cleavage in one direction, but found more commonly in bladed and fibrous varieties, and in earthy masses, often forming, when in the latter condition, beds or layers of a certain extent. H = 1.0 — 2.0; sp. gr. 2.55 — 2.7. BB, tinges the flame-point pale-green (from presence of phosphoric acid), and yields a dark magnetic globule. In the bulb-tube gives off a large amount of water. Normal composi- tion : phosphoric acid 28.30, iron protoxide 43.00, water 28.70, but the iron in the coloured varieties is always partly in the state of sesquioxide, and the earthy varieties moreover are usually mixed with a certain amount of clay, sand, iron ochres, manganese ochre, or other foreign matters. In Canada, this mineral has only been found in an earthy condition, underlying a bed of bog iron ore, in Yaudreuil, on the Lower Ottawa. 105. Cobalt Bloom (Erythrine, Arseniate of Cobalt) : — Occurs only (as regards Canada) in the form of a slight efflorescence or in- crustation, of a peach-blossom red colour, on the silver-holding calc spar of Prince's Location, on the north-west shore of Lake Superior ; and also, but in traces only, in the more recently discovered silver bearing vein near Thunder Cape. Normal composition : arsenic acid 38.25, oxide of cobalt 37.85, water 23.90 ; but sometimes mixed with arsenious acid. IV. FLUORIDES AND CHLORIDES. [This subdivision comprises the compounds of Fluorine and Chlo- rine, respectively, with metallic bases, such as sodium, calcium, alu- minum, lead, silver, and the like. These compounds present a non- metaliic aspect ; and they exhibit a general resemblance, also, in other characters, to many so-called oxygen salts, more especially to certain phosphates, borates, carbonates, and sulphates. Amongst Canadian minerals, however, as at present discovered, we have but a single representative of each group.] A. FLUORIDES. [The only Fluoride as yet discovered in Canada, is the fluoride of calcium, long known under its popular name of Fluor Spar. In a strictly natural classification, this mineral should occupy a place in 138 MINERALS AND GEOLOGY the immediate vicinity of the Apatite and Gale-Spar groups. The fluorides generally, when treated, in powder, with hot sulphuric acid,, evolve fumes of hydrofluoric acid which exert a strongly corrosive action on glass. The powdered substance may be warmed with some sulphuric acid in a platinum or lead crucible covered with a glass plate, when the under surface of the latter will be quickly corroded. In making the experiment, great care must be taken not to inhale the evolved fumes, as these are highly injurious. See also under "Blow- pipe Reactions/' in Part I.) 106. Fluor Spar: — Occasionally colourless, but more commonly violet or amethyst-blue, dark blueish-green, pale-green, pale blueish- grey, yellow, brownish, or rose- red, the edges and angles of many crystals being more deeply tinted than the other parts, or sometimes presenting a distinctly different tint or shade of colour. Streak, white. Crystallization, regular; the crystals mostly cubes, or cubes with bevelled edges (Figs. 80 and 81.) The corners of these cubes break off very readily, in consequence of the strongly-pronounced octahedral cleavage possessed by the mineral. H = 4.0 ; sp. gr. 3.1 — 3.2. Emits a blueish or other coloured phosphorescent light, when moderately heated in the form of powder. BB, generally decrepi- tates violently (see Part I), and fuses into an opaque white bead, which becomes caustic after strong ignition. Decomposed, with evo- lution of corrosive fumes, by hot sulphuric acid. The evolved fumes consist of hydrofluoric acid, which strongly corrodes the surface of glass. Average composition : fluorine 48*72, calcium (the metallic base of lime » 51.28. Fluor Spar occurs very generally in association with metallic ores in veins. It also forms per se, or in con- nection with calcite, the substance of many narrow FIG. so. FIG. si. FIG. 82. veins ; and it occurs likewise in cavities and small fissures in lime- stone and other rocks, and is occasionally disseminated through beds of crystalline limestone. The finest examples hitherto discovered in Canada, have been obtained from a large vug or cavity in a vein of amethyst-quartz on the north-east shore of Thunder Bay, Lake Superior. The fluor spar from this spot forms large cubes of two or OF CENTRAL CANADA PART II. 139 iree inches in diameter, which rest on equally large pyramids of amethyst-quartz, and are coated with iron pyrites in minute cubes* the whole being surmounted, here and there, by scalenohedrons of calcite. The fluor spar is partly of a pale greenish tint, but mostly of a violet or amethystine colour. Pale green and purple cubes occur also in most of the metalliferous veins of Thunder Bay and the surrounding region, mostly with quartz, calcite, blende, galena, and copper and iron pyrites, as at Prince's Mine, the Shuniah Mine, in several veins in the township of Neebing, and in others near Black Bay and Terrace Bay, on Fluor Island in Neepigon Bay, and else- where. Also in amygdaloidal greenstone, near Cape Gargantua. Finer spar occurs likewise, according to Mr. Murray, in association with specular iron ore, in crystalline limestone on Lake Nipissing. It occurs also, with apatite, in crystalline limestone in the township of Ross, in Renfrew county on the Ottawa, and also, with heavy spar, in Hull, and elsewhere in that district. Also in veins, with galena and calcite, in Trenton limestone in contact with gneiss at Baie St. Paul ; and in narrow veins In the Trenton limestone of the vicinity of Montreal, and the Utica slates of Quebec. Small crystals have likewise been obtained, from fissures and cavities of the Niagara strata, in the neighbourhood of the Falls, and on the escarpment at Hamilton. B. CHLORIDES. [This group is represented in Canada by a single type, the highly important Chloride of Sodium, or Rock Salt. The presence of chlo- rine in mineral bodies is easily ascertained by the blowpipe. Some phosphor-salt, with a few particles of black oxide of copper, is fused in a loop of platinum wire, so as to produce a deeply-coloured glass. To this, a small portion of the test-substance, in powder, is added,, and the glass during fusion is held just within the point or edge of the flame. The latter, if chlorine be present, will assume a rich azure-blue colour from the volatilization of chloride of copper. Many chlorides are soluble in water. None possess a metallic lustre, nor is the degree of hardness in any species sufficient to scratch ordinary glass. ] 108. Rock Satt : — Colourless, and also variousiy coloured by acci- dental impurities, as sesquioxide of iron, organic matters, or occupy comparatively low ground. The River Humber near To- ronto, for example, flows at the lower part of its course over a. denuded anticlinal of this character.* Finally, it may be observed,. Fig. 89. that when strata lie in parallel beds (as in Figs. 85 and 89), the* stratification is said to be conformable or concordant. When on the other hand, the beds are not parallel, the stratification is said to be unconformable. The accompany- ing section, in which the inclined beds belong to the Laurentianr and the overlying beds to the Lower Silurian Series (see Part V.), as shewn on Crow Lake, north of Marmora village, is an example of uncomformable strati- fication, or of want of concor- dance between these two series of rocks. As explained further Fig. 90. on, a want of conformability indicates almost invariably the com- mencement of a new geological period. Both horizontal and inclined strata frequently exhibit fractures of greater or less extent. Mineral veins, it may be mentioned, consist essentially of cracks or fractures formed at some more or less remote period in the surrounding rocks, and filled subsequently by various* agencies, with sparry, earthy, and metallic matters. The strata on one side of a fracture are often displaced, being thrown up or do win as it were. This peculiarity is technically termed a fault. The * Professor Robert Bell in his Report on the Manitoulin Islands, has pointed out the occur- rence of fifteen anticlinals, crossing the Great Manitoulin in a general north and south direc- tion. These anticlinals give rise on the north shore of the island to deep indentations or bays,, and inland to a series of parallel lakes. OF CENTRAL CANADA — PART III. 165 \(Z&r .-.V-TiY^^, levels occupied by a displaced bed are sometimes only a few inches, and at other times upwards of a thousand feet, apart. At the first formation of a fault or slip, an escarpment or terrace of greater or less height must necessarily Imve been produced ; but in very few •cases (if in any case unconnected with existing earthquake phenomena) is any- thing of this kind now observable, the ground having been levelled •down at some after period by the agency of denudation. In moun- tainous districts the fracturing of strata has sometimes given rise to narrow gorges or so-called " valleys of dislocation," but most of these have been subsequently enlarged by the atmospheric disintegration of the surrounding rocks, and by the streams or torrents of which they usually form the channels. In most faults the displaced beds have slipped downwards, and have thus been brought into a lower position than that which they originally occupied ; but occasionally, -as in the so-called " reversed faults," they have been forced upwards, so as in some instances to overlie the other beds. (d) Metamorphism. — Many strata afford undeniable proofs of having been greatly altered, as regards texture and other mineral characters, from their original sedimentary condition. In many in- •8Lances, indeed, the original composition of the rock appears to have been changed. Strata thus affected, are commonly known as meta- morphic or altered rocks. In some cases a passage can be traced from the altered into the unaltered parts of the rock; but, frequently, where •rocks have been subjected to this action, the alteration has extended •over wide areas, and has been more or less complete. It consists most commonly in the assumption of a crystalline structure, and is very generally accompanied by the presence of crystallized minerals and other indications of chemical action. In numerous instances, metamorphism, on a limited scale, has •evidently resulted from the direct intrusion of eruptive rock matters amongst sedimentary formations. Where trap dykes or masses of granite, for example, have been thrust up through fissures in ordinary strata, the latter are seen in many cases to have been more or less altered around the points of contact, as though by the agency of intense heat, or by that of steam or other gases acting under pressure. 166 MINERALS AND GEOLOGY Coal has been thus converted, within a certain distance of interpene- trating trap masses, into cinder and coke; earthy limestone, into- crystalline marble ; sandstone into quartz rock, and so forth ; and somewhat analogous effects are occasionally produced in sandstone- blocks that have been long exposed to heat and heated vapours in the interior of certain furnaces. These effects, however, have not always followed the intrusion of eruptive rocks; and in no case do they appear to have extended far into the mass of the surrounding strata. The alteration of extensive regions therefore, such as the wide area occu- pied by the Laurentian strata of Canada (see Part V.), points evidently- to some more general although probably related cause, in explanation of the facts of metamorphism.* Whatever view be adopted respecting the internal condition of the earth, it is clear that immense spaces filled or partially filled with molten and vaporous matter must have- existed through untold ages at certain depths beneath the surface rocks ; and the chemical action going on within these spaces, and emanating from them, may be regarded as sufficient to produce the- results in question, even if we cannot explain, to our thorough satis- faction, the actual processes involved in the production of these effects. See further under the METAMORPHIC ROCKS described below. A special effect of metainorphism, developed moie particularly in? fine-grained argillaceous strata, is the production of slaty cleavage* Rocks thus affected, exhibit a more or less strongly-pronounced fissile texture, arising from the presence of numerous divisional planes run- ning parallel with one another through the rock, and usually in a direction inclined to that of the planes of deposition. It is not always easy, in inclined strata, to distinguish the latter planes from planes of cleavage; but their direction is generally revealed by the presence of fossils, or by intercalated layers of a different shade of colour, degree of fineness, &c., across which the cleavage lines com- monly pass without interruption. Cleavage in rocks, as shown by this latter condition, and by the fact that fossil bodies and imbedded stones are frequently drawn out or unnaturally elongated in th& direction of the cleavage planes, is evidently a superinduced effect ; but much obscurity still prevails with regard to its actual origin. * We follow here the generally received view respecting the nature of these stratified, or at least laminated, crystalline rocks. But the assumed metamorphic character of these rocks is contested by some observers— in Canada, notabiy by Mr. Thomas Macfarlane— who regard them as original formations. Impartially considered, this view is not without strong grounds of probability. OF CENTRAL CANADA PART III. 167 It is usually attributed to mechanical pressure acting laterally upon the rock during elevations or depressions of contiguous areas ; but it may be really due to the effect of long continued heat on confined masses of damp strata. Moist clay, for example, if exposed in a covered vessel to a certain degree of furnace heat, almost invariably assumes a fissile texture ; and the same peculiarity is observable in ordinary biscuits, and more especially in those which have undergone an extra firing for ships' use. Oblique cleavage is exhibited by many of the clay-slates of the Eastern Townships, as those of Mel- bourne, Cleveland, Kingsey, &c. : but the clay slates of Lake Superior and other parts of the province, though more or lesa finely laminated, appear to be entirely destitute of true cleavage planes of this character. III. METAMORPHIC OR CRYSTALLINE STRATIFORM ROCKS. The rocks of this series are stratified or laminated rocks of a more or less crystalline aspect. In their mineral characters they frequently bear a great resemblance to eruptive rocks, to which indeed they are closely allied — almost every metamorphic rock having its repre- sentative in the eruptive series; but they differ from these latter by their general conditions of occurrence. As explained above, many sedimentary strata are seen to have assumed a crystalline texture, or to have lost more or less completely their normal sedimentary aspect, in the vicinity of intrusive masses of granite, greenstone, or other eruptive rocks. An alteration of this kind is known as local meta- morphism. Earthy or ordinary limestones and dolomites are thus occasionally converted into hard crystalline marble, often veined with green and other coloured streaks and patches of serpentine, and filled in many cases with crystals and crystalline particles of graphite, pyroxene, amphibole, various micas, tourmaline, garnets, pyrites and other minerals, foreign to the rock in its sedimentary condition. In like manner, sandstones are changed in colour and texture, and are often converted into quartz-rock or some variety of gneiss ; and clay- slates are transformed into mica-slate, talc- slate, hornblende-rock, and other so-called crystalline schists and gneissoid aggregations. These metamorphic results are probably due in part to the agency of various gases and heated vapours which accompanied the protu- sioii of the eruptive mass. Alterations of a similar kind, but ex- 168 MINERALS AND GEOLOGY tending over wide areas, are assumed, on the other hand, to have taken place in many localities, without the direct intervention of eruptive rocks. This widely extended metamorphism has probably been effected by alkaline and other solutions acting on the heated rocks, or by the agency of superheated steam and other vapours on deeply-seated strata, or by other causes more or less immediately connected with the presence of subterranean heat. In many cases there can be no question as to these crystalline strata being really altered sedimentary deposits, and thus, by inference, a similar origin is generally attributed to all rucks of this character. Whilst sedi- mentary rocks, proper, are the products of surface action, and erup- tive rocks — as regards their present condition, if not in all cases their actual origin — are products of internal or subterranean forces, meta- morphic formations may be regarded as the result of both external and internal agencies. The metamorphic rocks of Canada belong, as regards their geo- logical position, to two essentially distinct series. The older series of Archaean age, comprises the rock formations of the Laurentian and Huronian periods, and occupies all the more northern and north- western portions of Quebec and Ontario, its strata consisting chiefly of enormous beds of gneiss, crystalline limestone, siliceous slates, and other rocks, enumerated below, and described more fully in Part Y. The higher or less ancient series is apparently intermediate in posi- tion between the Huronian and Cambrian formations. Its strata are chiefly developed in the form of chloritic and talcose slates and beds of serpentine, throughout the Eastern townships and adjoining region south of the St. Lawrence, in the Province of Quebec. The following are the more important metamorphic rocks of Cana- dian occurrence : — Gneiss : — This rock is made up normally of three minerals — quartz feldspar and mica ; the two latter being generally the common potash species, orthoclase and muscovite (See Part I.). In some districts, however, the rock consists almost entirely of quartz and feldspar, mica being absent or very sparingly present. In coarsely crystalline varieties of the rock, the component minerals are easily recognized. The feldspar is usually white or red, and is present in distinctly cleavable grains or masses ; the mica is in leafy masses or small scales of a silvery white, brown or black colour; and the quartz in OF CENTRAL CANADA — PART III. 169 •colourless vitreous grains. The striped or banded aspect of the rock generally serves to distinguish it, in hand specimens, from granite • -and when seen in position, its stratified structure is in most cases very apparent. Vast beds of gneiss, and strata of gneissoid rock in which the component minerals are more or less indistinct, occur throughout the wide area occupied by the Laurentian rocks of the more northern regions of Canada (see Part V.), and also here and there, in the less ancient crystalline district south of the St. Law- rence. Most of the boulders scattered so abundantly over the sur- face of Canada, consist of micaceous gneiss, or of the hornblendic variety described below. In some localities the mica of ordinary gneiss is partially replaced by scales of graphite. Syenitic or Hornblendic Gneiss : — This rock only differs from ordinary gneiss by containing hornblende in place of mica ; but the two rocks frequently merge into one another, both hornblende and mica being present in certain varieties. Normally, the hornblendic variety of gneiss is composed of red or grey feldspar, with quartz, and black or green hornblende. The three minerals are sometimes very distinct ; but in other cases they are intimately blended, so as to form a dark-green rock, which passes, by the gradual diminution •of the quartz, into hornblende-slate or amphibolite. Syenitic gneiss occurs abundantly, with ordinary or micaceous gneiss, in the Lauren- tian districts of Canada (see Part V.). Mica Slate : — This is H foliated or schistose rock, composed essen- tially of quartz and mica. It is generally of a dark-grey, greyish- green, or silvery- white colour, and occasionally black ; and some varieties are highly lustrous from the presence of intermixed graphite, -as in many parts of the " Eastern Townships " of Quebec. It passes into clay-slate, and also into fine-grained gneiss and other rocks of this series. Mica-slate occurs here and there throughout the Lau- rentian area of Canada, and in the crystalline districts south of the St. Lawrence (see Part V.) ; but characteristic examples are rare — the rocks in question being rather micaceous slates than mica-slate as commonly defined. Pyroxenite or Augite-Rock : — This rock, of subordinate occurrence, consists at times of almost pure augite or pyroxene, but in general it forms a granular compound of augite and some kind of feldspar, more or less intermixed with carbonate of lime. Frequently, also, it con- 170 MINERALS AND GEOLOGY tains chlorite, with grains of magnetic iron ore and other minerals.. The normal colour is dark green. Examples occur here and there in connection with becte of crystalline limestone and iron ores of the- Laurentian Formation, as at Calumet Falls on the Ottawa, and parts of Madoc, Marmora, Tudor, and adjacent townships. In many cases pyroxenite cannot be distinguished from hornblende rock ; and it closely resembles also, in general character and composition, certain eruptive masses and dykes belonging to the trappean series. Many Laurentian pyroxenites, indeed, are probably of igneous origin. Amphibolite or Hornblende Rock : — This metamorphic product is sometimes described as diorite, but the latter term is properly restricted to eruptive greenstones of similar composition. Horn- blende Rock is composed normally of a mixture of hornblende and soda-feldspar, but at times it consists of almost pure hornblende.. Many varieties are also more or less calcareous, and in some, both mica and quartz are occasionally present. These pass into syenitic gneiss. The texture of the rock is compact, granular, fibrous or slaty. The slaty varieties are commonly known as Hornblende Schist, and the fibrous as Actynolite Rock or Schist. Examples occur in some abundance among the Laurentian strata of Marmora,. Madoc, Elzevir, Blythfield, and throughout the Laurentian country generally, between the Ottawa and Lake Huron ; also at various, places on Lake Superior, as at Point-aux-Mines, Goulais River, and elsewhere ; but many of the hornblende rocks of these districts may be really eruptive masses. Hornblendic rocks and slates form part also of the crystalline deposits of Beauce and other districts of the Eastern Townships. Wollastonite-Rock :— The mineral Wollastonite (No. 64, Part II), mixed with feldspar, pyroxene, quartz, calcite, and other minerals, occasionally form beds in the Laurentian series, mostly in association with crystalline limestone. Where the Wollastonite predominates, the rock presents a granular-fibrous structure, and is white or pale- greenish in colour. Examples occur in the counties of Argenteuil, Terrebonne, Leeds, &c., but are comparatively unimportant. Epidote-Rock /—This is also of subordinate occurrence. It consists of a mixture of quartz and epidote, and presents both granular and compact varieties, mostly of a pale-green colour. Examples have- been recognized amongst the Shickshock Mountains of Gaspe ; and others occur in Melbourne and other parts of the Eastern Townships. OF CENTRAL CANADA PART III. 171 Garnet- Rock : — Subordinate beds of this rock, composed essentially of granular red garnets and crystalline quartz, occur among the Laurentian strata of St. Jerome on the Ottawa, and Rawdon in Montcalm county ; and also, according to Mr. Richardson, in asso- ciation with micaceous schists at Baie St. Paul. Dr. Sterry Hunt has likewise made known the occurrence of beds of more or less com- pact and light-coloured garnet amongst the metamorphic series of the Eastern Townships. See under " Garnet," Part II. Quartzite or Quartz-Rock : — This rock consists normally of pure crystalline quartz, either colourless, or of pale shades of red, yellow, green, or smoky-brown. Coarse and more or less opaque varieties, passing into quartzose sandstone and chert, exhibit various colours, however ; and the rock is often green and greenish-grey from admix- ture with chlorite. Some cherts are black from the presence of anthracitic matter. Enormous beds of quartzite, frequently very pure, occur in the Laurentian series of strata, as on the River Rouge in the county of Argenteuil, and elsewhere; and these rocks are still more characteristic of Huronian strata. Laurentian quartzose conglomerates occur in the townships of Bastard and Rawdon ; and a very remarkable conglomerate of the Huronian series, consisting of pebbles of colourless quartz and red jasper in a colourless, green- ish-white or pale-yellowish quartzose base, is met with in the Bruce Mines district. These crystalline conglomerates show unmistakably the metamorphic origin of the rock. Beds of chert and jaspery quartz occur also in places on Lake Superior, and in the crystalline region south of the St. Lawrence (see Part V). Siliceous Slate : — This rock is probably an altered clay-slate. It passes into impure quartz-rock or jasper; consists essentially of a silicate of alumina; is hard or more or less slaty, and usually of a greenish-grey colour, or dark green from intermixed chlorite, and occasionally striped or zoned with lines of black, green, or red. Ex- amples of siliceous slates are of common occurrence on the north shore of Lake Huron, and amongst the Huronian strata of the Rive Dore* and other localities on Lake Superior. In many places, these slates hold rounded pebbles or masses of gneiss, syenite, &c., and thus form " slate conglomerates." Augillite : — This is one of the least altered rocks of the metamor- phic series. It is simply a more or less indurated clay-slate, and commonly presents a black or bluish-black or dark-grey colour, but 172 MINERALS AND GEOLOGY some varieties are dull chocolate-red, and others greenish-grey — th< rock passing by insensible transitions into ordinary unaltered shales on the one-hand, and into silicious and micaeous slates on the other. Many argillites are highly lustrous from intermixed graphite, and some contain small straw-like crystals of chiastolite or andalusite, as described under that mineral in Part II. Dark and more or less lustrous varieties are common in Huronian strata, and are still more abundant in the higher Animikie series of Thunder Bay, Lake Superior (see Part V), and in various parts of the altered region south of the St. Lawrence. In the latter district, as in Beauce and elsewhere, many of the green, purplish, and red agillites present a nacreous talcose aspect, but, as shewn by Dr. Hunt's analysis, they contain little or no magnesia. Chlorite Slate : — This metamorphic rock in its normal aspect is a compound of chlorite and quartz, possessing a distinct green colour and a foliated or schistose structure ; but in many examples the structure becomes fine-granular or almost compact. Tn Canada, chlorite slates, passing into chloritic strata in which the typical character of the rock is more or less obscured, occur sparingly in the Laurentian series, mostly in connection with iron ores. A bed of a dark green colour, filled with numerous small octahedrons of mag- netic iron ore, occurs in the township of Gal way. Other examples, but often of -somewhat obscure schistose structure, are characteristic of the Huronian rock throughout the vast region north of Lake Huron and Lake Superior. In the crystalline region south of the St. Lawrence, chloritic slates are also abundant, and most of the copper ores of the Eastern Townships are associated with these strata. Other beds contain intercalated scales and layers of specular or mica- ceous iron ore ; and in the Townships of Bolton and Broughton, more or less compact or subfoliated beds of greenish-grey chlorite, known as " potstone," form workable beds of good quality. (See Part II, No. 80). Steatite or Soapstone-Rock : — This rock consists of granular or slaty talc, frequently intermingled with carbonate of lime or dolo- mite. It usually presents a greyish or greenish- white colour, and when pure is very sectile. A bed of somewhat inferior quality, from intermixture with calcareous matter, occurs in the Laurentian strata of Elzevir. The closely related substance known as Pyrallolite (see OF CENTRAL CANADA PART III. 173 under No. 82, in Part II), also forms beds among Laurentian strata, as in Grenville, Ramsay, and elsewhere. Many deposits of more or less compact soapstone occur likewise in the higher crystalline series of the Eastern Townships, as in various parts of Bolton more especially, and also in Potton, Sutton, Stanstead, Leeds, and Yau_ dreuil. Ophiolite or Serpentine Rock : — This rock consists essentially of the hydrated magnesian silicate, Serpentine, described fully in Part IT. It usually presents a green, brown, greenish-grey, or pale yellowish colour, often veined or mottled with lines and patches of darker or lighter green, red or reddish brown ; and it forms more or less compact beds, frequently of great extent and thickness. Sub- ordinate examples occur in the Laurentian strata of many localities, mostly associated with bands of crystalline limestone, as in the town- ship of Grenville, and at Calumet Island on the Ottawa ; also in Burgess, and elsewhere ; but the crystalline districts south of the St. Lawrence contain the most abundant and important deposits of ser- pentine rock, as at Mount Albert in Gaspe, and in the Eastern Townships of Melbourne, Oxford, Brougham, Bolton, Ham, and Garthby, more especially. The serpentine of these districts is very commonly associated with beds of chromic iron ore ; and many ex- amples are intermixed with crystalline calcite or dolomite, forming ornamental " serpentine-marbles " of green, chocolate-brown and other colours. Crystalline Lim&stone : — This rock consists of carbonate of lime in a crystalline or semi-crystalline condition. It is usually white, light grey, or pale reddish, in colour, and is sometimes veined or spotted with yellow, green, blueish-grey and other tints. It presents most commonly a fine or coarse granular structure, much resembling that of loaf sugar, whence the name " saccharoidal limestone " by which this rock is often known ; but some varieties are more or less com- pact \ and others present in places a fibrous aspect, from inter- mingled tremolite or white hornblende, or light varieties of pyroxene. The finer kinds from the ordinary marbles of commerce. In Canada, large beds of crystalline limestone, often containing scales of graphite, and crystals of apatite, pyroxene, amphibole, mica and other minerals, occur among the Laurentian and Huronian series of strata in numerous localities (See Part Y) ; and also among the crystalline FERALS AND GEOLOGY strata south of the St. Lawrence. In the latter district, as already mentioned, some of these limestone beds are intermixed with green -and other coloured serpentines, but many of the so-called serpentine marbles from the Eastern Townships are mixtures of serpentine with dolomite or magnesite. Crystalline Dolomite : — This rock resembles crystalline limestone in colour and other external characters, but consists of carbonate of lime and carbonate of magnesia, and only effervesces when tested with heated acid (See Part I). It occurs, here and there, amongst the Laurentian strata, as at Lake Mazinaw in the County of Frontenac, and elsewhere. Also among the strata of the Eastern Townships, in which district beds of crystalline magnesite (See Part II), mixed with mica, serpentine, &c., are likewise present. These magnesian beds, as pointed out by Dr. S terry Hunt, assume a yellowish or dull-red colour by weathering. ^ Crystalline Iron Ores: — Vast beds of Magnetic, Specular and Titaniferous Iron Ore, occur locally amongst the rocks of the Laur- entian series, and should thus be referred to in connexion with the metamorphic formations of Canada. The strata of the metamorphic region south of the St. Lawrence are also especially characterized in certain localities by the presence of chromic iron ore in rock masses ; and many of the chloritic and other schistose strata of this region pass locally into "iron slates" or "specular schists," by the addition of micaceous hematite or specular ore. The distinctive characters of these Iron Ores, and their principal localities, ar.e given in Part II. IV. MASSIVE OR UNSTRATIFIED ROCKS. The rocks of this division are commonly known as Igneous or Erup- tive Rocks. With regard to the igneous formation of certain members of the Eruptive Series, there can be no possible doubt ; but the actual mode of formation of other rocks of this group is involved in great obscurity. All agree, however, in being essentially devoid of true planes of stratification. They occur either in irregular unstratified masses ; or in sheets or apparent beds, intercalated amongst, or over- flowing, stratified deposits ; or in the form of more or less tortuous veins ; or in broader and simpler veins, technically known as " dykes," which frequently terminate at their upper extremity in OF CENTRAL CANADA PART JII. 175 FIG. 92. overlying step-like and columnar sheets of matter. And in these conditions, they are frequently seen to traverse older rocks of the same class, or to penetrate various stratified formations. They are thus essentially intrusive rocks ; and they are also, in the words of Humboldt, essen- tially endogenous rocks — i. e., they •come from more or less deeply- seated sources within or beneath the Earth's crust, from whence they have been forced up from time to time through cracks and fissures opened in the overlying or surrounding rock masses. From this it follows, as a general rule, that the intrusive rocks in question must have been at one time in a soft and plastic state, if not in an actually fluid condi- tion. Certain trachytic and basaltic rocks — members of this group; described below — cannot be distinguished by chemical or minera- logical characters from ordinary lavas ; and the former existence of many basalts in a molten or highly heated condition is established by the effects produced by veins or dykes of these rocks on coal beds and other strata through which they have been erupted. Coal in contact with dykes of this kind, has been burnt into cinder, or converted into coke ; clays have been baked into brick-like masses ; sandstones rendered more or less vitreous ; and various limestones, to cite no further instances, have been hardened and altered into marbles of crystalline texture. Intrusive veins and masses of granite and syenite are also known to have produced metamorphic effects on the rocks which they traverse. But in many instances no alterations of this kind have followed the intrusion of a vein or mass of unstra. tified rock amongst sedimentary deposits. Hence it is clear that although the intrusive rock must have been in a soft or plastic •condition, it could not in these latter cases have been in a molten or intensely heated sta'te. Occasionally also, solid granitic' masses appear to have been thrust up amongst overlying strata, the intru- .sion being followed necessarily by signs of great mechanical disturbance. The condition of the quartz in granite and syenite, is 176 MINERALS AND GEOLOGY opposed to the view of igneous fusion ; and yet quartz of the sai character does occur sparingly in many trachytes, and under condi- tions not favourable to the idea that it may have been subsequently introduced by aqueous agencies. Through these trachytes, moreover, there is a gradual passage into actual lavas or known fusion-products;, whilst, on the other hand, many syenites (containing free quartz) merge gradually into greenstone and basalt, products intimately related to augitic lavas. It is, of course, impossible to say in what form a rock belonging now to the eruptive .class may actually have originated. It may have been produced from, an earlier formed igneous or crystalline mass, or from a sedimentary deposit buried deeply under overlying beds. The endogenous or subterranean agencies, whatever they may have been, that rendered granite and syenite plastic and crystalline, also produced the crystalline texture and other related characters of gneiss, mica schist, hornblende rock, and other members of the metamorphic series. It is now very generally assumed that whilst ordinary lavas and most trachytes and trappean (or basaltic) rocks have solidified from a molten condition, other rocks of this class, the granites and syenites more especially, have been rendered plastic and crystalline by "hydro-igneous" agency. These rocks, in other words, are thought to have undergone a kind of aqueous fusion and subsequent crystallization, the water, originally present in them, having been retained for a time by the pressure exerted on the plastic mass at great depths. But this view, it must be understood, is entirely hypothetical, and in many respecta is far from satisfactory. All that is really known may be thus expressed : — Two sets of forces are concerned, either alone or con jointly, in the production of rock masses generally. One set, entirely external, or consisting essentially in the action of the atmosphere and waters on the surface of the earth-mass, produces the sedimentary or stratified rocks proper. The other forces, of internal or subter- ranean origin, produce the unstratified rocks, as we now see these latter, and lead to the crystallization and metamorphism of sedimen- tary strata brought within their influence. But whether granites, syenites, traps, and trachytes, be igneous or non-igneous rocks, they are evidently related products, and members of a common class. These rocks are arranged by Sir Charles Lyell in two broad divisions : Volcanic and Plutonic rocks ; but it is impossible to draw OF CENTRAL CANADA — PART III. 177 a distinct line of demarcation between the two. Granite and syenite for example, are placed in the Plutonic series, and trachyte, green- stone, basalt, &c., in the Volcanic division; but certain granitic trachytes connect the granites with the volcanic rocks ; and in like manner, certain greenstones merge on the one hand into syenite, and on the other (the distinction between augite and hornblende, except in a purely mineralogical or crystallographic point of view, being practically of little moment) they pass into augitic lavas. This equally affects the sub-division into Volcanic, Trappean, and Granite rocks, adopted by other observers. I would therefore propose, as an arrangement of convenience, the distribution of our Canadian Erup- tive rocks into the following groups : — 1. Granites and Syenites ; 2. Anorthosites ; 3. Traps and Greenstones ; 4. Trachytes ; 5. Obsi- dians ; 6. Lavas. 1 . Granites : — The rocks of this group possess, normally, a crystal- line aspect and strongly-marked granular, structure, the term granite being derived from the latter character. Granites are also especially characterized by the presence of free silica or quartz in a crystalline condition. They occur occasionally in broad, straight veins or dykes, but are most commonly seen in the form of complicated, ramifying veins, or in large irregular masses which have often broken through and tilted up the surrounding rocks. Where a granite mass lies in contact with another rock, the latter will necessarily be the older formation if it be tilted up or otherwise mechanically affected by the granite ; or if it be chemically altered near the points of contact ; or if portions of its substance (in a more or less altered state) be enclosed within the granite mass ; or if the granite run into it in the form of veins (Fig. 93). On the other hand, if the adjacent rock rest in un- disturbed position on the surface of the granite, and ex- hibit no chemical alteration, it may FlG- 93- FlG- 94« be inferred to be the more recent of the two (Fig. 94). Granitic veins frequently cross or intersect each other : intersected veins be- ing necessarily older than those by which they are intersected. The diagram (Fig. 95) exhibits three veins of different ages. No. 1 is the oldest vein, as it is cut and also displaced or " faulted " by the other two. No. 3, again, is the most recent of the series, as it tra- 13 178 MINERALS AND GEOLOGY FIG. 95. verses and displaces both Nos. and 2. Granite rocks, by the decomposition of one of their es- sential components, feldspar, have become converted in some dis- tricts into white or light-coloured clays, largely used, under the name of kaolin, in the manufac- ture of porcelain. Granite, properly so-called, is composed of three minerals : quartz, feldspar and mica. The feldspar is usually the potash species Ortho- clase (see No. 57, Part II), but is occasionally represented by the Soda species Albite (Part II, No. 58), or by Oligoclase (No. 59). The mica is generally the common potash species Muscovite (Part II, No. 77), but is sometimes mixed with, or occasionally replaced by, one of the magnesiaii micas. As a general rule, the quartz, in granite, occurs in vitreous colourless grains ; the feldspar, in red, white, pink, or occasionally green or grey, lamellar masses, which exhibit smooth and somewhat pearly cleavage planes ; and the mica is mostly in small scales, or larger folise, of a pearly-metallic aspect, and silvery white, black, brown, pearl-grey, or greenish in colour. In coarse- grained granites, these component minerals are readily distinguish- able ; but in rocks of fine-grain, they become blended into a common granitic mass. The mica frequently dies out, or is very sparingly present, in which case the rock is sometimes known as Pegmatite, but this name is applied by German lithologists to coarse-grained granites containing a small amount of silvery- white mica in compar- atively large scales or leaves. Occasionally also in these quartzo- feldspathic granites, the quartz is arranged in the form of narrow, irregular crystals in more or less distinct bands, producing, in transverse sections, the appearance of a cuniform or Assy- rian inscription : whence the term "gra- phic granite " sometimes bestowed on this variety. When, again, the quartz and feldspar become intimately blended, so as to possess more or less the appearance of a simple mineral, the rock has been termed Felsite or Petrosilex. Very frequently, through a FIG. OF CENTRAL CANADA PART III. 179 base of this, or of ordinary granite, numerous crystals of feldspar are distributed, when the rock is known as porphyry, or, better, as por- phyritic gra die or porphyritic felsite (Fig. 97). The imbedded crys- tals often show the twin or compound structure so common in feldspathic sili- cates. The term " porphyry " (from nop- vary in different parts of its own length. Next to the stems, fragments of crinoid arms are of most frequent occurrence. In the following enumeration, therefore, of some of our more commonly occurring forms, the genera are arranged after the more easily recognised arm- characters : § 1. Arms with pinnulce, Glyptocrinus : — Pinnulse very fine ; arm-plates in single row ; calyx-plates radiately ridged ; stem generally round, the plates alternating in diameter, (sometimes pen- tangular) ; stem-orifice, five angled. Figure 154. Thysanocrinus : — arms long and thin, bifurca- ting ; arm plates in a double row, otherwise much like Glyptocrinus : Silurian and Devonian, Dendrocrinus : — arms thin, long, much branch- ing ; calyx-plates, large ; stem five-angled. Lower Silurian. Heterocrinus : — arms long, simple or bifercat- ing, with strong pinnulse ; arm plates in single row ; stem variable. Lower Silurian. In 1882, the Author proposed a new classification of the Crinoids in three groups and twenty- 240 MINERALS AFD GEOLOGY § 2. arms without pinnulce. Palceocrinus : — arms long and thin, of equal size, without pinnuls bifurcating. Lower Silurian. Hybocrinus : — arms very long and thin, not bifurcating, and with- out pinnulse ; Lower Silurian. Cheirocri nus (including Calcecrinus, &c.): — arms very long, decum- bent, unequal in size, with single row of plates. Silurian, Devonian. Ichthyocrinus : — arms short, without pinnulse, more or less in close contact throughout their length, gradually merging into the calyx ; arm plates in one row ; stem round, with small circular orifice. Roof of calyx composed of small, imbricating plates. Upper Silurian to Carboniferous. Figure 155 represents our principle species. Lecanocrinus : — Closely allied to Ichthyocrinus (if not really identical), but calyx plates larger and less numerous. L. elegans, Trenton Formation, is our best known species. FIG Other typical genera of the tesselated crinoids, Ichthyocrinus icevi*. comprise : Pisocrinus, Marsupites (a stemless form), Niagara Formation- Actinocrinus, Crotalocrinus, &c. The Articulata (see above) comprise, more especially, Enerinus (to which the " lily enerinite," E. liliifor- mis, of Triassic strata, belongs) ; Apiocrinus (including the " pear enerinite " of Jurassic strata) ; Pentacrinus, Antedon or Comatula, &c, but no examples of this group occur in Central Canada. II. CYSTIDEA. The Cystideans from an entirely extinct group of Cambrian and Silurian age. They present relations, in some cases obscure, in others very marked, to both crinoids and blastoids. The typical cystidean may be described as an oval or spherical body, covered two distinctive sections, the groups based on the presence or absence of a canaliculated struc- ture in the plates of the calyx and arms. A synopsis is published in the Transactions of the Royal Society of Canada : vol. 1, pp. 113-116. 'i'his grouping is not followed here— as in a little work of this unpretending character (dealing only with local forms, necessarily limited in number) it would be out of place to enter into the classification details which it involves OF CENTRAL CANADA — PART IV, 241 with calcareous plates united at their edges, without, or with merely rudimentary arms, and attached to the sea-floor by a short stem. Some, however, appear to have had no stem ; and in one or two gen- era closely related to the crinoids (Porocrinus, Caryocrinus) a well- developed system of arms was present. Two other salient characters are commonly present, also, in all typical cystideans. These com- prise a so-called " pyramidal orifice," and a system of pores or mi- nute fissures, by which some or all of the plates are traversed. The " pyramidal orifice " is an opening, usually near the summit of the body closed by several triagular plates, forming a five or six-sided elevation. It was most probably the oval orifice*. A second opening is generally present at the upper part of the body, and occasionally a third opening is seen. An enlarged view of a pyramidal orifice is shown in figure 156. The pores so commonly present in cystideans, have not been recognised in all genera. When present, they are either scat- tered irregularly over the surface of the body ; or are grouped in twos in small oval areas, on some or most of the plates ; or otherwise are arranged in fine lines forming lozenge-shaped areas, the so-called Fig. 156. " pectinated rhombs," or " hydrospires," which extend across the sutures into adjacent plates, as shown in enlarged form in figure 157-6. Figure A. shows a series of paired or double pores. No very satisfactory classification of cystideans has yet been proposed, but these forms may be arranged conveniently under five sections, as follows : — § 1. Occultiperforata : — Without visible or distinct pores ; but pores Fig 157j5 may perhaps open on the sides of the plates between the sutures. Canadian genera include : Amygdalocystites (Billings) : with few body-plates and two recumbent arms: Trenton formation; Ateleo- cystites (Billings) with plane and convex sides, respectively, and two free arms : Silurian, Devonian ; and Malocystites, with numerous * It is regarded by some palaeontologists as the mouth, and by others as an ovarian aperture. The system of valves, closing from without, would appear to indicate that it was an orifice ot emission, not of entiance. 16 242 MINERALS AND GEOLOGY body plates and several recumbent arms or pseudo-ambulacra : Lower Silurian. § 2. Biperforata : With double pores, in small separate areas, on the body plates. The section includes : — Gomphocystites (Hall) with somewhat club- shaped body covered with numerous plates : Niagara formation ; Holocystites, etc. §3. Rhombiperforata : — With numerous pores (or fine linear grooves) in rhdmbic areas which extend into adjacent plates. Includes Porocrinus (Billings), a small crinoid-resembling form, with few body-plates, distinct arms, and pore-areas at the angles of the plates : Trenton formation ; Caryocrinus, also a crinoid-like form, but of larger size, with radiately ornamented body-plates, distinct arms, and long stem : Niagara formation ; and Echinosphcerites (not yet found in Canada), with globular body, covered with numerous, small, hexagonal plates : Lower Silurian. § 4. Pauciperforata : With pectinated rhombs more or less apart and comparatively few in number. Includes Pleurocystites (Billings) with few body plates on one side of the body, and many smaller ones on the other side, two arms and short stem, the latter made up of round plates alternating in diame- ter : Chazy to Hudson River formations ; Glyptocys- tites (Fig. 158.); Callocystites, etc. § 5. Tectiperforata : — With hydrospire at upper surface of body. This section includes, with probably a few other Fi 15g imperfectly known types, the blastoid-resembling 0am cmrnnss) L°' Codonaster, in which the form is more or less conical Trenton formation. or top-shaped, with flat or truncated upper surface carrying a five-rayed pseudo-ambulacral star, and intervening narrow plates, between which occur the minutely punctured lines of the hydrospire. Apart from the presence of the latter, the form and general arrangement of the body-plates are those of a typical blastoid : Devonian, Carboniferous. OF CENTRAL CANADA — PART IV. 243 III BLASTOIDEA. This class, like that of the Cystoidea to which it is more or less closely related, is entirely extinct, and chiefly characteristic of De- vonian and Carboniferous strata. The typical Blastoid has an oval or bud-shaped body, covered with comparatively large, regularly arranged plates, with a five-rayed "pseudo-ambulacral star" at the summit. The pseudo-ambulacral plates carried, it is supposed, small piimulse during the life of the animal. At the underside of the body there is usually a short stem. The known or supposed genera (for some are of very doubtful position) may be ar- ranged as follows : § 1. Without any inter-ambulacral aper- tures : This section includes Pentremites Fig- 159> (with broad-ambulacral areas, and comparatively large basal plates i.e. those immediately above the stem), Upper Silurian, Devonian, Carboniferous ; Granatocrinus (with long and narrow pseud-ambu- lacral areas and very small basal plates) Carboniferous ; and Eleutho- crinus (stemless, with four linear and one short pseud-ambulacral area) Devonian. § 2. With (anal) aperture in one of the inter-ambulacral spaces : Orophocrinus (with general aspect like that of Pentremites), Carbon- iferous. Nucleocrinus (with very minute based plates, and long pseudambulacral areas) Devonian, Carboniferous. Stephanocrinus? (with long basals, and five sharp points at the summit of the calyx) Upper Silurian : Niagara formation. Blastoids are rare among Canadian fossils, but examples of Nucleo- crinus and Stephanocrinus are occasionally met with. Fig. 160 shows the upper surface (about twice enlarged) of Nucleocrinns Canadensis (Mont- gomery), perhaps identical with N. lucina (Hall), from the Hamilton formation of l^F Nucleocrinus Bosanquet township in south-western On- W Canadensis. De- tario.* Fig. 160 bis. is a figure of Stephan- ocrinus angulatus of the Niagara formation. *%**»«*»«• anguiatu*. * A full description of this species by its discoverer, Prof. H. Montgomery, an old student and graduate of Toronto University, will be found in the Canadian Naturalist, vol. x, No. 2 244 MINERALS AND GEOLOGY t IV EDRIOASTERIDA. This class, entirely extinct and Palseozoic, comprises a very limited number of representatives. These apparently connect the cystideans with the star fishes. They are stemless, circular, de- pressed forms, varying from about a quarter of an inch to a little over an inch in diameter. The under side of the body is unknown. The upper side carries a five-rayed ambulacroid star, composed of a double series of interlocking plates. The rays are curved in some forms, and straight in others ; and are entirely confined to the upper surface of the body. The margin of the disciform body is covered with very small imbricating or partially-overlapping, scale-like plates. The other parts or inter-ambulacroid spaces are protected also by imbricating plates, but of somewhat larger size; and a "pyramidal orifice," resembling that of a cystidean, is situated in one of these inter-radial spaces. The principal genera comprise : (1) Agelacrinites, with curved rays, like the "arms" of many ophiurian star-fishes ; and (2) Hemicystites, with short, straight rays.* Species of both genera occur in our Silu- * The generic name Agelacrinus (now more commonly written Agelacrinites) was given by Vanuxem to these forms, from the Greek, ayeXr;, a herd or crowd — the first found examples consisting of several individuals heaped or crowded together. But this condition of occurrence is purely accidental. It was also thought that these forms, although without a stem, were always attached to shells or other submarine objects by their broad base ; and this idea is still retained by many writers. Hence the term Edrioasterida of Billings, from e6paio Sizemaloent0n F<*" but much smaller, rarely exceeding the 12th of an inch in length, and its surface is tuberculated or embossed. 3. Phyllopoda: — This sub-division may be made to include the Copepoda, Cladocera, and Phyllopoda, proper — small* aquatic types, * The large, phyllopod resembling types, Hymenocaris, Dictyocaris, &c. of early palaeozoic age, are now separated from the Phyllopods, proper, and placed in a distinct group, the Phyllo- rarida of Packard. As shewn by Packard and Claus, they appear to form a connecting link between the lower and higher crustaceans : the Entomostraca and Malacostraca of many classifications. They form the sub-division Leptostraca of Claus. MINERALS AND GEOLOGY with flattened, natatory feet. The Copepods represented by the modern Cyclops, Argulus, ° r -Di • Diagram of a typical brachiopod known. Whilst most Of the PaleeOZOlC in normal position. genera are extinct, some few — as lingula, rhynconella, terebratula, &c. — still offer living representatives. The two valves of the brachiopod are of unequal size, but always equilateral. As regards the latter character, therefore, a straight line drawn vertically through the middle of each valve will divide the shell into two symmetrically equal parts. This serves to distin- guish at a glance a brachiopod shell from the shells of ordinary bivalve mollusca, or, at least, from the great majority of these, as some few, the Pectens for example, have nearly equilateral shells. The larger valve in brachiopods is almost always the ventral valve ; its " beak " or " umbo " is sometimes very prominent, sometimes depressed or inconspicuous ; and in some genera it is perforated for the passage of the pedicel. The smaller or dorsal valve is in some cases articulated by short projecting processes or " teeth " to the larger valve, whilst in other cases the articulation is very indistinct j and in one group of forms, including the lingulidce, occurs at the Frontenac mining location in Loughborough township, about 12 miles north of Kingston. The Calciferous and Chazy Formations which intervene, in the Pa- laeozoic area of the lower Ottawa, between the Potsdam and the Tren- ton formations, have not been recognized within the present district. The Trenton for Black River and Trenton) Formation is repre- sented chiefly by dark -grey thick-bedded limestones overlaid by lime- stone shales. The upper beds are in places exceedingly fossiliferous, and most of the lower beds yield excellent building stones. One of these latter beds is capable of employment, for the greater part, as a lithographic stone. It forms a continuous band, running north-west from the vicinity of Kingston, through Marmora, etc., to Georgian Bay. The thickness of the formation in this district averages about 700 or 750 feet. The northern boundary runs from the St. Lawrence a little east of Kingston, through North Hastings, Peterborough, South Victoria, Ontario, and Simcoe, to near the mouth of the River Severn on Georgian Bay — a chain of small lakes indicating its course throughout the greater part of the distance. North of these lakes, gneissoid Laurentian rocks occur in highly tilted beds, whilst the Trenton (or Black River) strata, 011 the south, occupy a nearly hori- zontal position. The southern boundary of the formation constitutes the coast of Lake Ontario from Kingston to the neighbourhood of Newcastle a few miles west of Port Hope. From that point the formation turns towards the north-west, and passing across Dur- ham, Ontario, and Simcoe, comes out on Nottawasaga Bay, west of Collingwood. The intermediate country, however is very thickly overlaid in most places by Drift and superficial deposits. Some of the more frequently occurring fossils comprise : Lithophycus Ottawa- ensis (fig. Ill); Stromatopora rugosa (fig. 127) ; Monticulipora (or Stenopora) fibrosa (fig. 136); Columnaria alveolata (fig. 142); Petraia corniculam (fig. 148) ; Glyptocrinus decadactylus (fig. 154) ; Le-perditia Canadensis (fig. 165); Asaphus platyceplialus (fig. 168) ; Trinudeus concentricus (fig. 172); Cheirurus pleurexanthemus (fig. 173;; Calymene Blumenbacldi (fig. 178); Strophomena alternata 316 MINERALS AND GEOLOGY (tig. 194) ; Leptcena sericea (fig. 196) ; Orthis testudinaria (fig. 197) ; Orthis tricenaria (fig. 198); Platystrophia lynx (fig. 200); Orlicu- loidea Circe (fig. 202) ; Linyula quadrata (fig. 206) ; Ambonyckia radiata (fig. 208) ; Conularia Trentonensis (fig. 218) ; Pleurotomaria Progne (fig. 219) ; Murchisonia gracilis (fig. 220) ; Madurea Logani (fig. 222) ; Platyceras angidatum (fig. 223) ; Subulites elongatus (fig. 225) ; Orthoceras proteiforme (fig. 232). Characteristic exposures of the Black River and Trenton strata of this district may be seen more especially at the following spots : Kingston city and environs, where the limestone beds contain in places crystallized examples of celestine (page 131), gypsum (page 131), and other minerals ; Clare River in Sheffield township ; Crow River near Marmora ; Shannon ville ; River Moira at Belleville and else- where ; Ox Point, Bay of Quinte' ; Rednersville on the south shore of the Bay ; Trenton, Healy's Falls, and elsewhere, on the Trent River ; environs of Peterborough ; river banks at Lakefield ; Quarry near Burleigh Falls on Stony Lake ; Bobcaygeon ; Balsam Lake, south shore ; Fenelon Falls ; Raver Scugog near Lindsay ; north east shore of Lake Couchiching ; and Lake St. John in Rama township, where the strata are seen in unconformable contact with the underlying Laurentian gneiss. The Utica Formation is made up almost entirely of dark -brown or black bituminous shales, interstratified here and there with beds of dark limestone, the total thickness of the Formation in this district being under 100 feet. The shales weather light grey, and yield by atmospheric disintegration a soil of much fertility. In some localities, as in the townships of Collingwood and Whitby, they are sufficiently bituminous to yield a considerable quantity of mineral oil by dis- tillation. The Collingwood shales, for example, have yielded as much as 20 gallons of oil to the ton of shale ; but the distilleries have long been closed, in consequence of the large and cheap supply of mineral oil furnished by the petroleum wells of Western Ontario and the United States. The more characteristic Utica fossils com- prise: Diplograptus pristis (fig. 132); Asaphus Canadensis, the pygidium especially, (fig. 169); Triartkrus Beckii (fig. 177); Lingula obtusa (fig. 207) ; Rhynconella increbescens (fig. 191), and some other species which occur in both the underlying Trenton and overlying Hudson River Strata — the formations constituting strictly a single I OF CENTRAL CANADA PART V. jroup. The trilobites Asaphus Canadensis and Triarthrus Beckii appear however to be confined to the Utica strata. These range along the shore of Lake Ontario from a little west of Port Hope to a short distance west of Whitby ; sweeping from these points, in a comparatively narrow band, towards the north-west, and coming out on Nottawasaga Bay a mile or two west of Collingwood ; but within the intervening space the formation is entirely concealed by over- lying Drift and superficial deposits. Good exposures may be seen, however, in the vicinity of Whitby, and on the lake shore under the " Blue Mountains" a few miles west of Collingwood harbour. The Hudson River Formation consists essentially of shaly thin- bedded sandstones, mostly of a greenish-grey or drab colour but weathering rusty-brown. These shaly sandstones, formerly known as Lorraine shales, are interstratified here and there with a few cal- careous beds. The total thickness of the Formation in this district is about 750 feet. Its fossils are in great part identical with those of the underlying Trenton and Utica beds, these three so called formations forming properly a single subdivision of the Lower Silurian series : dolomitic and other limestones characterising the lower part ; bituminous shales (with more or less distinct fossils) the central portion ; and arenaceous shales, holding many of the lower limestone fossils, the upper part. Some of the more common fossils of the Hudson River strata comprise : Climacograptus bicornis (fig. 132); Diplograptus pristis (fig. 132*); Monticulipora fibrosa (fig. 136); Glyptocrinus decadactylus (fig, 154); Galymene Blumen- bachii=C. senaria (fig. 178); Asaphus platycephalus (fig. 168); Trinucleus concentricus (fig. 172) ; Strophomena alternate (fig. 194 ) : Leptcena sericea (fig. 196); Ambonychia radiata (tig. 208) ; Modiola modiolopsis (fig. 209) ; Murchisonia gracilis (fig. 220) ; Bellerophon bilobatus (fig. 221); Cyrtolites ( Bellerophon ) ornatus ; and Orthoceras crebriseptum (fig. 233). The formation constitutes the shore-line of Lake Ontario from the River Rouge, in the township of Pickering, to the River Credit, west of Toronto. From these points, although much obscured by overlying Drift and more recent deposits, it extends to the north and north-west, and forms the shore of Nottawasaga Bay in the townships of Collingwood, St. Vincent, Keppel and Albemarle. Good exposures, at most of which fossils may be obtained, occur on the banks of the Humber, Mimico, Etobicoke, 318 MINERALS AND GEOLOGY and Credit ; also at Point Boucher on Nottawasaga Bay, and at Cape Rich, Point William, Cape Crocker, and Point Montresor, farther west. The Medina Formation is regarded as forming the base of the Upper Silurian series It is chiefly made up of red marls and soft red sandstones, interstratified with red and green arenaceous shales, and capped by a bed of fine-grained sandstone — commonly known as the "grey-band" — averaging about ten or twelve feet in thicknes?, but presenting in places a thickness of over thirty feet. This grey sandstone is largely quarried for building purposes in the township of Nottawasaga, and at Dundas, Hamilton, and other places along the great Niagara escarpment. The Medina formation, presenting collectively a thickness of about 600 feet, extends along the shore of Lake Ontario westward from the vicinity of the River Credit to the escarpment (or so called " mountain ") at Hamilton ; and it occupies the strip of land lying between the escarpment and the lake as far as the Dominion boundary on the Niagara River. Northwards, it extends through the^townships of East and West Flamborougb, Nelson, Caledon, Mono, Mulmur, and Nottawasaga : from- whence, turning westward, it continues along the course of the escarpment, but with greatly diminished thickness, and loss of the " grey-band," to the base of the bold promontory known as Cabot's Head on Georgian Bay. Fossils are of comparatively rare occurrence in this formation. The principal comprise : the fucoid Arthrophycus Harlani (fig. 113) and a small lingula, L. oblonga (fig. 127). The best ex- posures occur about Wellington Square, Hamilton, Dundas, Queen- ston, and Georgetown, and at the Dennis quarries in Nottawasaga. The Clinton Formation which immediately succeeds the Medina, consists at its lower part essentially of green, red, and greyish shales, in places more or less ferruginous ; and at its upper part mostly of dolomitic limestones. The lower portion should properly be referred to the Medina Formation, and the upper part to the Niagara. The lower shales hold casts, often in great abundance, of Arthrophycus Harlani (fig. 113), and remains of a small coral (or bryozoon) Hdi- pora fragilis. The formation, generally, follows the course of the Niagara escarpment between the Niagara River and Georgian Bay — gradually increasing in thickness, from a few feet to about 100 feet, between these points. Conventionally, all the beds lying above the )F CENTRAL CANADA PART V. grey-band " and beneath the limestone containing shells or casts of the brachiopod Pentamerus oblongus (fig. 193) are given to the Clin- ton Formation. Exposures occur, chiefly, on the Well and Canal and elsewhere in the vicinity of Thorold ; also, with greatly increased thickness, immediately around Hamilton ; in road-cuttings at Dun- das ; in the gorges of the Noisy and Mad Rivers in Nottawasaga ; at spots on Beaver River ; and at Cape Chin, Cape Commodore, and Cabot's Head on Georgian Bay. The celebrated "Thorold cement " is manufactured from a limestone of this Formation. Glacial and Post-Glacial Deposits : — The greater portion of the Lake Ontario District is overlaid by clays, sands and gravels of the Glacial and Post-Glacial periods. Beneath these deposits, many strata, limestones especially, are seen when first uncovered, to be striated and polished by glacial action. The striaB run in some places towards the south-west, and in others towards the south-east ; and the same rock-surface occasionally exhibits both S.W. and S.E. striations. These so called superficial deposits admit in ascending order of the following subdivisions : (i.) Boulder Clay formation ; (ii.) Erie Clay formation; (iii.) Saugeen Clay and Sand formation; (iv.) Artemisia Gravel formation; (v.) Algoma Sand formation; and (vi.) Recent deposits, proper, as shell-marls, bog iron ore, and peat. The Boulder Clay or " Till " consists of thick beds of boulder- holding clay, without subordinate stratification. The boulders vary in size from small pebbles to masses of considerable dimensions ; and they consist for the greater part of gneissoid and other crystalline rocks brought down from the Archaean northern region by glaciers or icebergs during the long period of cold which more or less immedi- ately preceded the existing epoch. See ante, page 207. Many of the included boulders, even those of small size, shew marks of polish- ing and striation. In some places, especially on ridges and high lands within the district, the Drift is represented by accumulations of boulders alone, without accompanying clay. Stratified ciays, also holding boulders in some localities, overlie the unstratified drift clays very generally, and are known as "Erie clays." They are more or less calcareous, and yield white or light-coloured bricks. Deposits occur at North Toronto, Cobourg, Belleville, Dundas, and numerous other places within the district. The so called Saugeen clays (which yield red bricks) and their accompanying sands succeed the Erie clay 320 MINERALS AND GEOLOGY deposit, and occur more or less all over the Province. Beds of coarse gravel mixed with boulders, known as the Artemisia Gravel forma- tion, occupying a somewhat higher horizon than that of the stratified Saugeen clays and sands, occur especially (as regards this district) along the base of the Niagara escarpment in the townships of Arte- mesia, Osprey, Mulmur, Mono, and Albion, where they form the chief mass of the " Oak Ridges." These latter extend from the es- carpment eastwards, and rise in the township of King and adjacent townships to elevations of from 700 to 760 feet, above Lake Ontario. In many places the gravels are seen to be distinctly stratified, and here and there they hold gneissoid and other boulders of large size. The Algoma sands consist of still higher accumulations of white or light-coloured lacustrine sands, practically free from stones or boulders, and often shewing signs of oblique stratification. These lacustrine sands occur extensively throughout the district, as seen along the line of the Canadian Pacific Railway between Toronto and Peter- borough, in cuttings on the Grand Trunk between Scarborough and Hamilton, around Barrie on Lake Simcoe, and elsewhere. Many fresh- water shells (Unio complanatus, Cyclas similis, Planorbis trivolvis, Limncea palustris, etc.,) identical with those now living in our lakes and streams, occur at various levels in these and other re- lated beds — their presence in these deposits apparently indicating the former union of our lake-waters into one vast fresh-water sea. In this case, the water must have been held up in the east by a greater elevation of the gneissoid belt of rock which crosses the St. Lawrence between Brockville and Kingston, and expands into the wild district of the Adirondack Mountains in the State of New York ; or perhaps by an enormous glacier, descending from the latter region and ex- tending northwards into Canada. The shells of recent species of mollusca found in the Post-Glacial deposits east of this gneissoid belt, belong to marine or brackish- water species : whilst those within the Lake Ontario District, and country to the west, are all fresh- water types. The most abundant of the recent deposits, proper, of this region, are the beds of shell marl which occur at numerous local- ities, forming the floor and margin of small lakes and swamps. This substance is a white or light-coloured calcareous deposit, con- taining minute shells of species of cyclas, planorbis, and other fresh- water mollusca. 'RAL CANADA PART V. THE ERIE AND HURON DISTRICT. This district — occupied throughout by comparatively undisturbed limestones and other strata of the Upper Silurian and Devonian series, with overlying Drift clays and sands, and more recent super- ficial deposits — is essentially an agricultural area of great fertility. It lies immediately west of the Lake Ontario District, and is sepa- rated from the latter by the great Niagara escarpment which runs, as stated above, from the Niagara River — by Queenston, Thorold, Grimsby, Hamilton, Dundas, Georgetown, etc., — to Cabot's Head on Georgian Bay. On the south, the district is bounded by Lake Erie ; and on the west by Lake Huron. The greater portion of its area forms an elevated table-land of from 1,000 to 1,200 feet above the sea. Along its north-eastern edge the ground rises in places to an altitude of nearly 1,600 feet ; but it slopes gradually towards Lake Erie on the south (565 feet above the sea), and towards Lake Huron (578 feet above the sea-level) in the west. Its surface, except where cut by river- valleys, is generally even ; and the district presents a marked contrast to the lower region of Lake Ontario by the almost total absence of inland bodies of water. It is traversed, however, by many important rivers, and especially by the Grand River, flowing into Lake Erie ; the Thames, flowing into Lake St. Clair ; and the Maitland and Saugeen, flowing into Lake Huron. The eastern and north-eastern boundary, along the great escarpment, is also cut through by numerous smaller streams. These enter the Lake Ontario District, consequently, through deep ravines, many of which are of a very wild and picturesque character. The strata of the district consist, in its more eastern portions, of Upper Silurian representatives, with various Devonian formations in the west. They follow each other (in ascending order) from north- east to south-west, generally, and comprise : The Niagara formation (with some Upper Clinton beds), the Guelph formation, the Onondaga or Gypsiferous, and the Eurypterus or Lower Helderberg formations, of the Upper Silurian series ; and the Oriskany, Corniferous, Hamilton or Lambton, and Chemung-Portage formations, of Devonian age. These strata, although practically undisturbed, are affected by several moderate anticlinals running across the more central part of the district in a general east and west or south-west direction ; and 21 322 MINERALS AND GEOLOGY it is thought that the petroleum of this part of the region has brought towards the surface by fissures resulting from these anti- clinals. A transverse or nearly north and south fold, forming a trough or synclinal filled with higher Devonian strata (of the Hamilton or Lambton formation), also occurs in the south-western portion of the district between Lake Erie and the south point of Lake Huron. The Niagara Formation in this district, is made up of dark-gray calcareous shales and thick-bedded limestones, both of which are more or less magnesian and bituminous. Its lower limit is regarded, con- ventionally, as indicated by a magnesian limestone holding shells ot the brachiopod Pentamerus oblongus (tig. 19 ); but this " Peiit- amerus bed " is referred by the New York geologists to the upper part of the underlying Clinton formation. At Niagara Falls, the dark shales present a thickness of about 80 feet, and form the lower portion of the escarped face over which the cataract breaks, whilst the upper portion of the cliff is composed of thick-bedded limestones. Along the gorge, the shales are mostly concealed by the slope or talus of detrital matter which rests against the cliff face ; but they may be seen on the side of the steep road which leads from the old ferry to the Clifton House, and at several other spots. Some of the beds of this formation yield excellent hydraulic lime, much of the " Thorold cement " being manufactured from the lime obtained from them. Many of the Niagara beds are rich in fossils. The more common species comprise : The corals : Favosites Gothlandica (=F. Niagarensis fig. 137,); and Halysites catemdatus (the so-called "chain coral" fig. 139); the Bryozoon, Fenestella elegans (fig. 181); the Brachiopods : Pentamerus oblongus (fig. 193); Orthis elegantula (fig. 197) ; Spirifer Niagarensis and S. radiatus (fig. 184) ; and the Trilobites, Calymene Blumenbachii (ranging upwards from earlier strata, fig. 167, 178); Homalonotus delphinocephalus (fig. 179) and Dalmannites limulurus (fig. 175). The formation extends a few iniles westward from the edge of the great line of escarpment — already described as running from the Niagara River, by Hamilton, Georgetown, etc., to Cabot's Head on Georgian Bay — and then passes under the succeeding Guelph formation. It thus marks the eastern and northern limits of the table-land of which the Erie and Huron district largely consists. Good exposures occur more especially at the Niagara Falls and on the adjacent banks of the river (where the OF CENTRAL CANADA PART V. 323 limestones are overlaid by terraces of fresh-water clay and sand of Post-Glacial age) ; also on the Welland Canal near Thorold ; along the upper part of the escarpment or " mountain " by Grimsby, Hamilton, Dimdas, Ancaster, Rockwood, etc. ; 011 the River Credit in Caleclon, as at Bellefontaine and elsewhere, and on the Nottawa and Beaver Rivers, where it forms high and precipitous cliffs ; at various other points in Mulmur, Nottawasaga, Artemisia, and Eu- phrasia ; about Owen's Sound ; and at Cape Paulet, Cape Chin, and the upper part of Cabot's Head. In the immediate vicinity of Rock- wood, some large caverns occur in a dolomitic limestone (thickly interspersed with, crinoid stems) belonging to this formation ; and deceptive veins and strings of galena have been noticed in the same township (Eramosa), as well as in the Niagara strata of Mulmur and Clinton. The Guelph Formation is represented for the greater part by white or light-coloured dolomites of a peculiar semi-crystalline or granular texture, containing, among other fossils, large casts of a lamellibran- chiate mollusk, the Megalomus Canadensis (fig. 210). The coral, Am- plexus laxatus (fig. 143) ; the brachiopod, Trimerella acuminata (fig. 1:01) ; several species of Murchisonia, Holopea Guelphensis (fig. 224); and Phragmoceras Hector (fig. 229), are also characteristic. The formation extends over a considerable area, chiefly in the counties of Waterloo, Wellington, and Grey, but it is greatly concealed by over- lying Drift and other superficial deposits. The principal exposures occur on the River Speed in the vicinity of Guelph ; at Elora, near the junction of the Grand and Irvine Rivers, where the strata form high cliffs ; also on other parts of the Grand River, as at Fergus, Preston, and Gait ; near Hespeler, again, on the railway between Guelph and Brantford ; and on the rocky Saugeen River in Bentinck. At most of these localities excellent building-stones are obtained. The Onondaga or Gypsiferous Formation consists, in Canada, of thin-bedded dolomites of a yellowish or pale grey colour, associated with greenish calcareo-argillaceous shales and with large masses or irregular beds of gypsum. These deposits appear to have been largely formed from precipitates thrown down in* ancient salt-lakes or bays in which an active evaporation was going on. They contain only a few obscure traces of organic remains ; but hopper-shaped and prismatic casts, derived from crystals of ordinary salt, soluble- sul- 324 MINERALS AND GEOLOGY phates, etc., are not uncommon in some of their beds. The gypsui is mostly of an earthy or granular texture, and is always more or less mixed with carbonates. The formation enters Canada a short distance above the Falls on the Niagara River, and includes the whole of Grand Island in this portion of its area. From thence, it follows the general outcrop of the Guelph formation to the vicinity of the Saugeen Hiver on Lake Huron. It thus includes portions of Welland, Haldimand, Brant, Oxford (north-east corner), Waterloo, Perth and Bruce ; but throughout much of this area it is covered by Glacial and other superficial deposits. Exposures may be seen near Waterloo village, Bertie township, on the Niagara River ; along the Grand River between Cayuga and Paris, and near the Don Mills ; on the Upper Saugeen, near Ay ton and Neustadt, in Normanby township ; around Walkerton on the Saugeen, in Brant, and at various points down the river : as at the elbow in the south-west corner of Elderslie, a little below Paisley. The gypsum or ''plaster" deposits are chiefly quarried at Cayuga, Indiana, and York, in the township of Seneca; at Mount Healy and elsewhere in Oneida • largely around Paris ; and at various places in Brantford township. Some of the dolomitic and argillaceous shales of the formation, as those which outcrop near Walkerton, etc., furnish valuable material for the manufacture of hydraulic cement ; and it is apparently from this formation that the brine — obtained in the vicinities of Goderich, Seaforth and Clinton, by deep borings through overlying deposits — is essentially derived. The Lower Helderberg or Eurypterus Formation, as occurring in this district, represents merely a small portion of the " Lower Helderberg group " of New York. It is made up of a few thin- bedded dolomites, with some interstratified shales and a brecciated bed (composed chiefly of dolomite fragments) at its base. These strata, which collectively do not exceed fifty feet in thickness, appear to represent the lower portion — the "Water-lime" or " Tentaculite limestone" — of the Helderberg series proper. They are chiefly characterized by the presence of fragmentary examples of a peculiar crustacean, Eurypterus remipes (fig. 180), belonging to the Mero- stomata, an almost extinct order, but represented in existing nature by the Limulus or Xiphosure. The formation probably extends as a thin band along the western border of the Onondaga formation OF CENTRAL CANADA — PART V. 325 between Lake Erie and Lake Huron, but the only known exposures are in the Lake Erie townships of Bertie and Cayuga. The Oriskany Formation, the first in ascending order of the Devo- nian series, is also but sparingly present in the district. It is represented chiefly by a layer of chert or hornstone (containing much iron pyrites) at the base, with a succeeding brecciated bed (made up in part of chert fragments), and some quartzose grits or sandstones : the entire thickness varying from about six to ten feet. Its fossils are chiefly identical with those of the overlying Corni- ferous strata, but are mixed in places with Upper Silurian types. Some of the more common comprise : Favosifes Gothlandica (fig. 137); Zaphrentis prolifica (fig. 144) ; Strophomena rhomboidalis (fig. 195); Atrypa reticularis (fig. 188) and Calymene Blumenbachii (fig. 178\ The formation enters Canada in the township of Bertie in the north-east corner of Lake Erie, and appears to run as a thin band along the southern edge of the Eurypterus or Onondaga formation at least as far as the country of Norfolk ; but the only known exposures occur at Bertie, Dunn, North Cayuga, Oneida, ;md Windham. From the exposure in North Cayuga, a little north of the Talbot Road, good millstones have been quarried. The Corniferous Formation, as recognized in Western Canada, includes the " Onondaga limestone" and "Corniferous limestone" of New York geologists. It is made up essentially of more or less bituminous limestones, containing, in places, nodular masses of chert, or interstratined with bands of that substance, and associated here and there with beds of calcareous sandstone and bituminous shale. The thickness of these strata, collectively, is estimated at about 200 feet. The limestones contain, as a rule, a great abundance of silici- fied fossils, mostly brachiopods, corals, and crinoidal stems. The common forms comprise : The corals, Michelinea convexa (fig. 138) ; Syringopora Maclurei (with coarse cell-tubes, fig. 140) and S. Hisin- geri (with narrow-cells, fig. 141); and the simple horn-shaped types? Zaphrentis prolifica (fig. 144) and Z. gigantea, the latter often a couple of inches in diameter and five or six inches in length. The bracuiopods, Strophomena rhomboidalis (tig. 195); Atrypa reticularis (fig. 188) ; Spirifer mucronatus (fig. 185) ; S. gregarius (fig. 184 bin) ; Spirigera concentrica (fig. 187) and Stricklandia elongata — most of which occur also in higher Devonian strata. The trilobite Phacops 326 MINERALS AND GEOLOGY bufo (fig. 174) is also a common Corniferous type. In the district under review, the formation occupies two large areas, separated by a broad intervening belt of the succeeding Hamilton or Lambton for- mation. The more eastern of these areas extends over portions of Welland, Haldimand, Norfolk, Brant, Oxford, Perth, Huron and Bruce ; and the western area occupies parts of Lambton, Kent and Essex. Exposures occur more particularly on or near the shore of Lake Erie in the following townships : Bertie, Humberstone (as at Rama's farm, near Port Colborne, a noted fossil locality), Dunn, Rainham, Walpole and Woodhouse. Also in North and South Cayuga; near Woodstock village ; and at St. Mary's (another locality especially rich in fossils). The formation outcrops likewise at various places in Carrick, Brant, Bruce and Kincardine ; and again, farther south, as near Port Albert and Goderich, and in the vicinity of Amherstburg in Maiden. At many of these localities, and especially at the large exposure in Maiden, building-stones of very superior quality are obtained. The Hamilton or Lambton Formation,* as defined in Canada, represents merely the middle portion of the " Hamilton formation " of the New York geologists. It consists mainly of soft calcareous shales associated with some beds of encrinal limestone. The fossils are identical for the greater part with those of the Corniferous forma- tion ; but the brachiopods, Spirifer mucronatns (fig. 185) ; Spirigera concentrica (fig. 187); Atrypa reticularis (fig. 188); and Ortkis Vanuxemi (fig. 199) are especially abundant in these higher beds. The formation in this district is estimated at about 250 feet in thick- ness. It extends across the counties of Norfolk, Elgin, Kent, Middlesex and Lambton, and also the south pait of Huron, but is much obscured throughout this area by overlying clays, sands, and other Drift and superficial deposits. The best exposures occur in the township of Bosanquet, in the north-west corner of Lambton. The formation is chiefly of interest as constituting the essential petroleum * The name by which this formation is commonly known, is derived from the village of Hamilton, in Madison county, New York. It is often supposed, in Canada, to refer to our city of Hamilton, on the western extremity of Lake Ontario, where the strata belong to a much lower horizon — that of the Medina formation, lying at the base of the Upper Silurian series. In consequence of this very prevalent misconception (of which some curious instances might be given), the writer proposed some years ago to call this group of strata, as occurring in Canada, the Lambton formation, after the county in which it is principally developed in Western Ontario. OF CENTRAL CANADA PART V. 327 area or oil district of Western Canada, although the deeper borings, from which the petroleum is chiefly obtained, appear to pass through its strata into the underlying Corniferous formation. Natural springs have been noticed in various parts of the district, as in Mosa, Enniskillen, Zone, Orford, etc. In the township of Enniskillen, overflows from springs of this kind have formed deposits of solid bitumen or " mineral tar," varying in thickness from an inch or two to nearly a couple of feet, and extending over an acre or more of ground. One of these deposits or " gum beds," in the northern part of the township, is covered by several feet of Drift clay ; and in places it presents a leafy or shaly texture, and contains impressions of leaves and insects. As proved by the very different results obtained in many instances from closely contiguous borings, the petroleum is evidently confined to comparatively narrow and tortuous channels, within limited belts of country. These belts are characterized, both in the United States and Canada, by the presence of anticlinals, by which a more or less fissured condition of the strata has been pro- duced. The petroleum in these fissures is almost always accompanied by salt or brackish water, and inflammable gas is usually emitted on the first tapping of the fissure. As a rule, the wells become gradu- ally impoverished, and frequently end by yielding water only. The petroleum, as first obtained, is of a dark colour and more or less viscid consistency. When decolourized and purified it loses about forty per cent — five barrels of crude oil yielding about three barrels of refined oil. The Portage, or Portage-Chemuny Formation, as seen in Canada, is made up of dark bituminous shales, holding in places large cal- careous concretions, and also much iron pyrites, with occasional fish- scales and spines, and impressions of long-flattened stems of a calamite (tig. 119). Here and there these shales become coated, by weathering, with a* yellow crust of oxalate of iron. The formation extends pro- bably over a considerable area around Lake St. Clair and the adjoin- ing country ; but it is thickly overlaid by Drift and superficial deposits throughout the greater part of this area, and the only well-recognized exposures occur at Kettle-point, or Cape. Ipperwash. in the township of Bosanquet, on Lake Huron, and at one or two places in the town- ships of Warwick and Brooke. As seen at these spots, the thickness of the formation does not exceed twelve or fifteen feet. 328 MINERALS AND GEOLOGY Deposits of Glacial, Post-Glacial and more recent age are spread very generally over the Silurian and Devonian strata of this district — a wide break in the geological succession occurring here as in other parts of the Province. These deposits comprise in ascending order : (i.) The Boulder-clay or Lower Drift formation; (ii.) the stratified " Erie Clay " formation ; (iii.) The Saugeen Clay and Sand formation ; (iv.) The Artemisia Gravel and (v.) the Algoma sand deposits; with (vi.) a series of recent accumulations, proper. The Lower or true Drift Formation consists of a thick deposit of unstratified clay, holding Laurentian and other boulders. It appears to be essentially a Glacier formation, derived in chief part from the grinding action of ice on the surface of the subjacent rocks. As a rule, it is greatly concealed from observation; and much of its original substance has undoubtedly been removed, or otherwise re- arranged in the form of succeeding deposits, by the subsequent action of water. The Upper Drift deposits consist principally of dark blue or gray calcareous clays, arranged in distinct layers, and containing, as a rule, numerous stones and boulders, but no shells or other fossils. These "Erie clays" yield white or light-yellow bricks. In places, as near Brantford, etc., their planes of stratification are greatly con- torted. Good displays occur along the north shore of Lake Erie generally ; also near Clark Point, etc., and adjacent coast of Lake Huron; and at Woodstock, St. Mary's, London, and elsewhere throughout the district. The Lower Fresh-water deposits, or " Saugeen clays and sands." where in contact with the "Erie" or underlying boulder-holding clays, commonly rest on the denuded surface of the latter. The clays present a very general brown colour, and although more or less calcareous, they yield, as a rule, red bricks. All are distinctly strati- fied, and, in most cases, boulders are but sparingly present in them. Good exposures, showing the blue or Erie clay below, occur more especially near Port Talbot and Port Stanley on Lake Erie. Others may be seen around Woodstock ; and also between Clark Point and Port Frank on Lake Huron, as well as at various spots on the Saugeen, around Walkerton, and throughout the township of Brant generally. Layers of sand and gravel are commonly associated with these clays; and a deposit of coarse gravel with boulders — the "Artemisia gravel'' of the Geological Survey — extends largely CENTRAL CANADA PART V. throughout the country between the Grand Elver and Georgian Bay, and is seen near Brantford and elsewhere to overlie the blue or Erie clay. In many parts, again, of the Erie and Huron district (as in the more western portion of the Lake Ontario region, already described) the brown clays, or in their absence the underlying deposits, are capped by lacustrine sands and gravels, some of which contain shells of fresh-water mollusca — species of uiiio, cyclas, amnicola, valvata, planorbis, physa, limnsea, melania, &c. — still inhabiting our lakes and streams ; and similar shells are occasionally found in the clay beds. Terraced deposits containing fresh-water shells of this kind occur especially around Niagara Falls. Other examples have been seen in the vicinities of Paris, Brantford, Walkerton, &c. In addi- tion to these Glacial and Post- Glacial accumulations, various deposits of still more recent origin occur within the district. The principal comprise : the sandy flats of the Grand River and other streams ; the beds of shell- marl which underlie and margin most of the swampy areas ; the ochre deposits of the counties of Middlesex and Norfolk ; and the peat beds of Humberstone and Wainfleet on Lake Erie. THE MANITOULIN DISTRICT. This district may be regarded as an outlying portion of the Ontario and Erie districts combined, the Silurian strata of these extend- ing into it, and ranging continuously throughout its area. It comprises the Great Manitoulin Island, eighty miles in length, lying along the north shore of Lake Huron, with the La Cloche and other smaller islands between the Manitoulin and the Lake Huron coast, and Oockburn Island, St. Joseph's Island, Campement d'Ours, &c., farther west. Drummond Island belongs also, geologically, to the district, but lies beyond the Canadian boundary. The more northern portion of the Great Manitoulin contains numerous lakes, and its north shore is indented by comparatively deep bays. These appear to lie in synclinal folds, formed by a series of undulations (with north and south axes) which traverse the Island throughout its length.* The strata of the district succeed each other from north to south, the *See "Reports on the Manitoulin Islands," by Dr. Robert Bell, by whom these anticlinals were first pointed out, in Geological Survey Reports for 1866 and 1867. 330 MINERALS AND GEOLOGY general dip being in the latter direction. They comprise a slight development of Huroiiian quartzites, with representatives of the Chazy, Black River and Trenton, Utica, Hudson River, Clinton, Niagara, and Guelph formations. The Huroniaii outcrops occur principally in the form of bare, rocky ledges, but are only seen at one or two places, principally at Shequenandod village, near the eastern extremity of the Great Manitoulin, on La Cloche Island, and on the Island of Campement d'Ours, near the entrance to St. Mary's River. Exposures of reddish marls and light-coloured sandstones on the north side of La Cloche Island are commonly referred to the Chazy division ; and the thin bedded sandstones (provisionally known as the Ste. Marie sandstones), which occur in small outlying patches on Campement d'Ours and St. Joseph's Island, are thought, as regards their geological positon to represent the same formation. The southern portions of La Cloche Island, and the smaller islets imme- diately west, are occupied entirely, or essentially, by dark gray dolornitic limestones cf the lower part of the Trenton (or so-called Black River) series — the higher beds merging into the Trenton division proper, and supporting at one or two points small strips or patches of Utica shale. The Bigsby, Thessalon, and other rocky islands farther west, and a large part of Campement d'Ours and St. Joseph's Island, belong to the same series. From the La Cloche group of islands these Trenton strata extend across the intervening channel, and crop out in several places as a fringe along the north coast of the Great Manitoulin. They show principally in the Mani- towaning headland, and also between Little Current and West Bay. Southwards, the dark bituminous shales of the Utica formation come up, and range entirely through the islands. Good exposures occur at Shequenandod village (where the shales incline against an outcrop of Huronian quartzite), and at Cape Smyth. At the latter spot the formation is capped by a considerable thickness cf arenaceous shales and sandstones, very rich in fossils, belonging to the Hudson River series. This latter formation ranges also entirely through the Great Manitoulin, and extends over Barrie Island on the north. It is fol- lowed along its southern border by a series of strata holding Clinton fossils. These strata consist mostly of light-coloured dolomites capped by a bed of red marl — the best soil on the island, according to Dr. Bell, resulting from the disintegration of the latter. South of these CENTRAL CANADA — PART V. 331 Jlinton beds, a steep escarpment of Niagara limestone runs through the central part of the island, facing the north, following in its strike the same east and west direction as the other formations of the district- From the top of the escarpment, the limestones extend in a series of steps to the south shore, where they become covered in places by patches of semi-crystalline dolomites belonging to the Guelph for- mation. The southern portion of the Great Manitoulin is thus occupied entirely by these Upper Silurian strata, and broad shelves of bare limestone-rock form large portions of its surface. A con- tinuous outcrop occurs along this south shore ; but the best exposures are seen in the lower beds along the line of escarpment, more especially about Lake Manitou and Lake Wolsey (and intervening country), and around the south shore of Bayfield Sound. Cockburn Island) immediately west of the Great Manitoulin, is also underlaid through- out its whole extent by Niagara limestone. The other formations recognizejd within the district consist of Drift clays and higher sand deposits — the " Algoma Sand" of the Geological Survey. The clays appear to belong essentially to the lower or unstratified Drift. They occur in great thickness upon St. Joseph's Island, and are overlaid very generally on Cockburn Island by the higher Algoma sands. Both divisions are also seen on the Great Manitoulin and elsewhere throughout the district. Detached boulders, mostly of Huronian rock, occur likewise in many places ; and glacial striae and furrows are seen on almost all the exposed rock- Surfaces. The strise have a general south-westerly direction, but vary from a few degrees west of south to about S. 50° W. Petroleum springs occur both on the Great Manitoulin and on some of the other islands of the Manitoulin group. The petroleum appears to come from the Utica shales ; but although the formation has been penetrated and even traversed by several wells or borings, no permanent supply has hitherto been obtained. THE NORTHERN PALEOZOIC AREA. This area comprises a large extent of comparatively flat country, ranging around the south shore of James' Bay to beyond the Pro- vince boundary on Albany River, and stretching from these points in 332 MINERALS AND GEOLOGY a general south-westerly direction towards the " Height of Land." Moose River on the east, and Albany River on the west, flow mainly within its limits. The area still remains practically unexplored, but it is known to be underlaid around its more southern and western portion by cal - careous strata of Upper Silurian age (resting immediately on the Huronian and Laurentian rocks of the great Archaean region around the Height of Land) ; and northerly and easterly, by Devonian formations extending to the shores of the Bay. These paleozoic strata, however, are almost entirely concealed by a thick surface covering of Glacial and Post-Glacial clays. Where visible on Moose River, the underlying rock, according to Dr. Bell (Report of 1875) consists of bituminous grey and drab limestone, holding Devonian fossils* • and on the banks of this river Dr. Bell observed a deposit of spathic-iron-ore weathering into brown hematite, and also grey and white gypsiferous deposits. In. the post-glacial clays (Report for 1877) the same observer discovered a considerable bed of lignite, varying in thickness from eighteen inches to six feet. These post- glacial deposits contain also in many places detached crystals of gypsum, (see page 131), and shells of my a truncata, tellina groen- landica, saxicava rugosa (figs. 214, 215, 216, page 278), so character- istic of the post-glacial deposits of Eastern Canada. Our knowledge of the country around James' Bay is derived principally from the valuable Reports on Hudson's Bay by Dr. Bell of the Geological Survey of Canada, but the region referre I to in these Reports lies mostly beyond the area now under consideration, and, indeed, beyond the Province of Ontario.! The following ex- tract, however, from the Report for 1879 applies in chief part to the present district. " To the south and south-west of James' Bay, in the latitude of Devonshire and Cornwall, there is a large tract in which much of the land is well-wooded, but although little or no rock comes to the surface over an immense area, neither the soil nor the * In addition to the Devonian species cited in Dr. Bell's report, the author has fonnd in col- lections made by the stipendiary magistrate, Mr. E. B. Borron — Zaphrentis prolifica, Z. gigan- tea, Cystiphyllum Senacaense, Amplexus lax:itus, Phxagmoceras (Hector ?), and the pygidium of Daltnanites limulurus or a closely allied species. t Useful information may also be derived from the Report presented to the Ontario Govern- ment by Mr. Borron, in 1882, on the portion of the Hudson's Bay basin lying within the pro- vince boundary. OF CENTRAL CANADA PART V. 333 climate is suitable for carrying on agriculture as a principal occu- pation until we have passed over more than half the distance to Lake Winnipeg. This region appears to offer no engineering difficulties to the construction of a railway from the sea-coast to the better country beyond. Some of the timber found in the country which sends its waters into James' Bay may prove to be of value for ex- port. Among the kinds which it produces, may be mentioned white, red, and pitch pine, black and white spruce, balsam, larch, white cedar, and white birch. The numerous rivers which converge to- wards the head of James' Bay offer facilities for " driving " timber to points at which it may be shipped by sea-going vessels." PROVINCE OF QUEBEC. INTRODUCTORY NOTICE. This Province is separated from Ontario on the west by almost the entire course of the Ottawa River, and by a line drawn directly north from Lake Temiscamingue : but a small area on the Ontario side of the Ottawa at its junction with the St. Lawrence, although properly within the limits of the western province, is given to Que- bec. This area includes the small counties of Vandreuil and Sou- langes. On the south, the Province of Quebec is bounded by the northern portions of the States of New York, Vermont, New Hamp- shire, and Maine; and by the New Brunswick counties of Victoria and Restigouche, and the Bay of Chaleurs. The St. Lawrence Gulf, Labrador, and Hudson's Bay bound it on the east and north, but its limits in the latter direction are still practically undefined. Its area is approximately stated at 190,0^0 square miles. The river St. Lawrence, widening into its majestic Gulf, traverses the province from south-west to north-east, and receives, as principal affluents on its northern bank, the Ottawa, the Assomption, the St. Maurice, the St. Anne, the Montmorency, and the Saguenay ; and on its southern bank, the Richelieu, the St. Francis, the Chaudiere, the Du Loup, Metis and other rivers. Two mountain ranges follow roughly the course of the St. Lawrence : and to these, in con- 334 MINERALS AND GEOLOGY y junction with the great river and its affluents, the physical charact of the province is chiefly subordinate. The range on the north (with an average elevation of 1500 feet above the sea, rising in places to over 2,000 feet) constitutes the Laurentide Mountains, and runs roughly parallel with the Ottawa until within about 30 miles of its rnouth, when the range curves towards the east, and skirting the St. Lawrence a short distance inland, strikes the river at Cape Tourinente a little below the city of Quebec. From this point it follows the north shore of the river and Gulf to beyond the province boundary in Labrador. This range and the country which it traverses consist of greatly corrugated archaean gneiss, broken through by various dioritic and feldspathic rocks. The southern range is properly a continuation of the great Appalachian, chain of the United States. It is known in Canada as the Notre Dame and Shickshock Mountain .Range. It traverses the Eastern Townships, and gradually approach- ing the St. Lawrence, runs along the south shore, but at a distance of from 30 to about 10 or 12 miles inland, until it terminates in the high table-land of Gaspe at the extremity of the Province. This range, consisting of several roughly parallel lines of mountainous country, presents one or two points of nearly 4000 feet in altitude, and in the Gaspe peninsular the elevation averages 1,500 feet. It is made up largely of crystalline, magnesian locks, including talcose and chloritic schists and beds of ^serpentine, associated in places with micaceous and gneissoid rocks and other crystalline representa- tives, the true age of which is still more or less uncertain. On passing from the Laurentide Mountains southwards to the St. Lawrence, the gneissoid Archaean rocks become overlaid unconform- ably by Cambrian and Lower Silurian strata. Where the river enters the province, and for some distance eastward, the latter occur 011 both shores, and they continue along the north shore to beyond the city of Quebec. They reappear further east in the Mingan Islands, and also, with accompanying Upper Silurian strata, in the Island of Anticosti. On the south side of the river, Cambrian slates and other strata have been brought up by a great fault into a position apparently higher than that of the Hudson River beds. This fault, first indicated and traced out by Sir William Logan, extends along the bed of the gulf and river to the immediate vicinity of Quebec, and then turns inland towards the south-west, and continues in that OF CENTRAL CANADA PART V. 335 direction to the head of Lake Champlain, beyond the province boun- dary. All the strata to the south and east of this fault have been greatly disturbed and broken up, and have been more or less altered by metamorphic agencies. Crystalline, gneissoid and mngnesian rocks appear in part to underlie them, and partly to be mixed up with them in intricate foldings, by which their stratigraphic relations become greatly obscured. In many places also they are broken through by tr achy tic and granitic masses. As regards its geology therefore, the Province admits of a sub- division into three natural areas : the Archaean, area of the north ; the typical Palaeozoic area ; and the disturbed Appalachian district including the Eastern Townships and the Gaspe" peninsula. For con- venience of description, however, the Island of Anticosti and the Mingan Islands may be separated from the second of the above areas, and regarded as forming a distinct palaeozoic district. The positions of these areas are shewn roughly in the annexed sketch-map : FIG. 246. Sketch-Map of the Province of Quebec, shewing geological areas. 1. Northern Archaean district — shewn in part, only. 2. Palaeozoic district of the Upper St. Lawrence. 3. Palaeozoic district of Anticosti and the Gulf. 4. Appalachian and Gaspe district. Q— Quebec ; M— Montreal ; C— Lake Champlain (Northern por- tion). The dotted line indicates the direction of the great Fault. 336 MINERALS AND GEOLOGY NORTHERN ARCH^AN DISTRICT. This is essentially a region of ancient crystalline strata — rocky and mountainous in character : an eastward extension i-f the Lauren tian district of Ontario, but with certain special features of its own. It comprises the wide expanse of territory lying between the Ottawa River and Labrador, with the exception of a comparatively narrow strip of country (occupied by Lower Palaeozoic formations), extend- ing along the St. Lawrence from near the junction of the two great rivers to a point a short distance below the city of Quebec. It is traversed by the Laurentide Mountains, proper, which form within it several broken ranges curving roughly parallel with the course of the St. Lawrence. The more southern of these gradually approach the river, and run closely adjacent to it along the lower part of its course. The average height of the Laurentides generally, is from about 1,200 to 1,500 feet, but at one or two points they reach an altitude of over 2,000 feet above the sea. Numerous rivers rise among them. Some of the more important comprise : the Riviere du Moine, the Gattineau, the Riviere du Lievre, the Riviere Rouge, and the Riviere du Nord, flowing into the Ottawa ; and the PAssomp- tion, Chicot, St. Maurice, Batiscan, Ste. Anne (Portneuf), Jacques Cartier, Montmorenci, Ste. Anne (Montmorenci), Murray, Saguenay, Moisie, and other eastern rivers, flowing into the St. Lawrence. The rocks of this Archaean area consist for the greater part of typical Laurentian gneiss (composed of quartz and orthoclase, with associated mica or hornblende) interbedded wi£h quartzites and bands of crystalline limestone and iron ore. These Laurentian strata, as a rule, are more or less strongly tilted and corrugated, or otherwise disturbed. They are also traversed very generally by granitic or syenitic veins, and are broken through in places (more especially in Wentworth, Chatham, and Grenville on the Lower Ottawa) by enormous masses of eruptive syenite and greenstone. The crystalline limestones very commonly contain diopside or light-coloured pyrox- ene, phlogopite, zircon, sphene, and other crystallized silicates, with scales of graphite, and grains and crystals of fluor-apatite. The latter mineral also occurs in workable quantities, associated mostly with pyroxene, phlogopite mica, calcite, and scapolite, in broad veins which cut the gneissoid strata transversely — especially in the townships OF CENTRAL CANADA — PART V. 337 of Buckingham, Templeton, Lochaber, and Grenville, on the Ottawa,* and throughout that section of country, generally. About 20,000 tons were obtained from these deposits in 1886, and they are still being largely worked. Veins and large lenticular masses of graphite occur also in the rocks of this district, and mica of good quality has been obtained from localities in Grenville, Templeton, and adjacent townships. Iron ore in workable quantity occurs also in Hull, and elsewhere in the same district. The orthoclase gneiss- rocks which form the prevailing strata of this archeean region north of the St. Lawrence, are overlaid in some few localities by comparatively limited areas of feldspathic rock com- posed of labradorite or other triclinic lime-feldspars ; and here and there these labradoritic rocks or " anorthosites," see page 181, are apparently interstratified with the upper beds of the ordinary otho- clase gneisses. They were at one time, and are still by some observers, regarded as indicating a newer or higher series of Lauren- tian strata, and were known as the Upper Laurentian, Labrador, or Norian formation, But in the main mass of these anorthosites there is no apparaiit stratification, and they are now regarded by Dr. Selwyn as essentially eruptive rocks of Laurentian age. This view, although not absolutely free from doubt, will probably meet with general acceptance. A large area of these anorthosic rocks occurs in the counties of Argenteuil, Terrebonne, Montcalm, and Joliette ; and another, equally large, lies around the north-east and south sides of Lake St. John, at the head of the Saguenay River. Smaller areas O3cur on the north shore of the St. Lawrence in Montmorenci and Charlevoix, and a large exposure has been recognised on the branches of the river Moisie, off the Gulf. These feldspathic rocks present generally light shades of colour, and weather dull white. In most examples, some of the cleavage planes shew a blue or green opales- cent play of colour, as in typical examples of labradorite ; and occasionally, as at Chateau Richer and elsewhere, they contain scales and folise of bronze-coloured or green hypersthene or bronzite. Gai- nets, also, are frequently present in them ; and they are associated in many localities with titaniferous iron ore. A very large deposit of the latter mineral occurs in these rocks near Baie St. Paul ; and * The distinctive characters etc. , of this valuable mineral (known commercially as "phos- phate") are given on page 135. 22 338 MINERALS AND GEOLOGY titaniferous ii'on Bands are abundant around the mouth of the Moisie river on the Gulf. Attempts to utilize these titaniferous ores have been made, but hitherto without success.* In addition to the gneissic and other crystalline formations of tins northern archsean region, a few outlying patches of Lower Silurian strata, consisting mostly of Trenton limestone and Utica shales, occur here and there within its area. The largest of these Silurian outliers is seen around Lake St. John on the Upper Saguenay. As remarked by Sir William Logan, the limestones at this locality shew characteristic Black River fossils associated with those of the Trenton formation proper,! and comprise principally : Maclurea Loyani (fig. 222); Stromatopora rugosa (fig. 127) Orthoceras Biysbyi ; Lep- tcena sericea (196) ; Strophomena cdternata (fig. 194); Murchisonia gradlis (fig. 220) ; Calymene Blumenbachii (fig. 179), etc. — with, near the base of the series, Halysites catemdatus (fig. 139), typically, an Upper Silurian form. The fossils of the overlying Utica shales in- clude various graptolites, broken crinoidal stems, species of discina, &c., and the characteristic Utica trilobite Triarthrus Beckii (fig. 177). A small exposure of Hudson River beds is seen also on Snake Island in the lake. Glacial boulders, clays, and gravels, with Post-Glacial sands and other superficial deposits, are distributed, as in other parts of Canada, more or less generally throughout this region ; and many of the harder rocks shew glacial striae. These run most commonly either towards the south-east or south-west ; but at some spots their direc- tion is nearly north and south \ and, in others, not far removed from east and west. DISTRICT OF THE UPPER ST. LAWRENCE. This is essentially a Palseozoic area, occupied — apart from some isolated eruptive-masses — by sandstones, limestones, and other strata, * The presence of titanium in an iron ore is objectionable chiefly for the following reasons : (1) It diminishes, of course, the percentage of iron in the ore ; (2) it renders the ore very re- fractory ; and (3) it scours the ore, carrying off a large amount of iron in the form of slag. To prevent the latter effect, a comparatively large amount of lime is required, and this fills up the furnace with an unproductive burden. Very little titanium goes into the pig metal, even when highly titaniferous ores are used. t A similar association of Black River and Trenton types was pointed out by the author, many years ago, as occurring at Shannonville in Ontario. The two so-called formations cannot in fact be properly disunited. OF CENTRAL CANADA PART V. 339 which retain their original sedimentary aspect, and occur, for the greater part, in undisturbed beds. It extends along both sides of the St. Lawrenc3 from the western boundary of the Province to the neighbourhood of Quebec. In the west, it includes the counties of Vaudreuil and Soulanges, lying in the point of the triangular space immediately west of the junction of the Ottawa and St. Lawrence Rivers. From the county of Vaudivuil, its northern boundary crosses tho Ottawa, and then, keeping entirely on the north side of the St. Lawrence, runs along the southern edge of the Laurentide district already described, and gradually approaching the river, strikes it a short distance below Quebec. Its southern limit runs from the south-west corner of Huntingdon (south of the St. Law- rence), along the boundary-line between the Province and the State of New York, to a little beyond the River Richelieu at the northern extremity of Lake Champlain ; and east of this, the district is bounded by the disturded and metamorphic area of the Eastern Townships — its actual limits in this direction being a remarkable line of dislocation, with accompanying fault, running (as first traced out by Sir William Logan) from near the north-east end of Lake Champlain to the vicinity of Point Levis, and from thence, by the City of Quebec, along the north side of the Island of Orleans, and down the river and Gulf, between the Island of Anticosti and the Gasp£ shore. The rock-formations of the district belong to three distinct series,, namely : stratified Palaeozoic formations ; eruptive rocks ; and Glacial and other Post- Cainozoic deposits. The stratified rocks, pro- per, consist of representatives of the Potsdam, Calciferous, Chazy,. Black River and Trenton, Utica, and Hudson River formations — with some small exposures, south of the St. Lawrence, of strata re- ferred to the Medina group ; and a few outlying patches of Upper Silurian strata (belonging to the Lower Helderberg formation) in the vicinity of Montreal. These formations are broken through in places by large eruptive masses of trachytic and trappean rock, forming a series of picturesque motmtains, which rise abruptly from the generally level surface of the district in the more southern and western portions of its area ; and in addition to these Palaeozoic and Eruptive rocks, Glacial and Post-Glacial accumulations, with deposits- of comparatively modern origin, occur throughout the district generally. 340 MINERALS AND GEOLOGY The Potsdam beds consist of coarse conglomerates and fine-grained siliceous sandstones — the latter in many localities sufficiently pure for glass-manufacture and for the hearths of furnaces. The formation is largely displayed in Hemmingford Mountain, and over large portions of Huntingdon, Chateauguay, and Beauharnois, from whence it crosses the St. Lawrence, and spreads over a large part of Soulanges and Vaudreuil ; and from thence, passing across the western end of the Island of Montreal and Isle Bizard, it wraps around a large outlying mass of Laurentian gneiss (forming Mont Calvaire on the north shore), and continues uninterruptedly along the edge of the Laurentide district as far east as the River Chicot, where the continuity of the strata is broken by a fault, and limestones of the Trenton formation are let down against the Potsdam beds. East of this point, the formation only appears at one or two places — notably on the St. Maurice, where it exhibits a slight thickness of nearly horizontal beds of conglomerate and sandstone, resting upon gneiss. Throughout its range, as far east as the Chicot, it is accompanied by sandy and dolomitic limestones of the Calciferous formation, and these cover large areas south of the St. Lawrence, and in the country around the junction of the St. Lawrence and Ottawa. East of this formation, on the south aide of the St. Lawrence, limestones of the Chazy and Trenton series, and dark bituminous shales of the Utica formation, with succeeding sandstones and arenaceous shales of the Hudson River formation, largely prevail — the latter, especially, east of Riche- lieu River. These formations cross the St. Lawrence, and range in regular sequence along the north shore between the Calciferous out- •crop and the river bank. The intervening Island of Montreal, Isle Je*sus, Isle Bizard, etc., consist essentially of Chazy, Trenton, and Utica strata — -the Hudson River beds coming up farther east. The Chazy limestones of Caughnawaga and St. Domenique on the south shore, those of Ste. GeneVieve on the Island of Montreal, of Isle Bizard, and of St. Lin on the north shore, yield marbles (red-spotted or uniformly red) of good quality. East of the River Chicot, which enters the St. Lawrence on the north shore, near the upper or western extremity of the expansion known as Lake St. Peter, the comparatively narrow strip of country between the Laurentian gneissoid rocks and the river margin is occupied almost entirely by Trenton, Utica, and Hudson River strata — one or two small ex- OF CENTRAL CANADA PART V. 341 posures of the Potsdam formation on the St. Maurice and at St. Ambroise alone representing the lower beds as seen west of the Chicot fault. In this eastern portion of the district, the strata are tilted in many places at considerable angles, as near Pointe aux Trembles, Montinorenci Falls, etc., and their continuity at these spots is more or less disturbed by minor faults.* As stated above, the Lower Silurian strata of the more southern and western portions of the Upper St. Lawrence district are broken through in places by trachytic and trappean masses, forming a series of isolated mountains which rise above the generally level surface of the country to elevations of from 600 to 800 feet. Most of these occur apparently upon a single line of fissure traversing the district in a general south-easterly direction. They comprise : (1) the Mountain of Rigaud in Yaudreuil, composed partly of a purely feldspathic% and partly of a dioritic or hornblendic trachyte, porphy- ritic in places ; (2) the Montreal Mountain, composed essentially of augitic trap or dolerite, but traversed by dykes of compact and granitic trachyte ; (3) Montarville or Boucherville Mountain, also essentially trappean in composition ; (4) Belceil, a dioritic and micaceous trachyte ; (5) Monnoir or Mount Johnson (south of Beloeil), of the same mineral character ; (6) Rouge mont, in Rouville County, a trappean mass like that of Montreal in general composition ; and (7), the Yamaska Mountain, essentially a micaceous trachyte. The Mountains of Brome and Shefford belong to the same eruptive series, but lie within the crystalline district to the east. In addition to these principal masses, many dykes of similar character traverse the surrounding strata ; and some of these in the neighbourhood of Montreal and Lachine are intercalated with the soft shales of the Utica series, which have become more or less worn away, leaving the associated trap bands in the form of projecting ledges. Most of the rapicfs in this part of the St. Lawrence have been thus produced. The superficial deposits of the district comprise Glacial boulders and related clays and gravels, with Post-Glacial and recent accumu- lations. Drift or Glacial deposits, proper, are of general distribution ; and in some places, as on the Rigaud Mountain, the boulders form roughly parallel ridges, several feet in height. The Glacial strise of the country have two prevailing directions — south-west and south- * The fossils in these various Lower Silurian formations are practically identical with those of the same formations in Ontario : see ante, pages 315 to 317. 342 MINERALS AND GEOLOGY east respectively. The Post-Glacial deposits belong chiefly to series, as first determined by Sir J. W. Dawson of Montreal: a lowe1 deep-sea formation, known as the " Leda Clay;" and a succeeding deposit' apparently a shallow-sea or shore-line accumulation, known as " Saxi- cava Sand." These occur widely within the district, and at various elevations.* On Montreal Mountain, beds of Saxicava sand, for example, form a series of terraces, one of which is at an altitude of nearly 500 feet above the present sea level. Beauport, below Quebec, is another locality at which these deposits are well exposed ; but they occur also, and over large areas, around Murray Bay, as well as on the Lower St. Maurice, and elsewhere. The more recent formations of the district comprise, principally, the bog iron ore and ochres of the St. Maurice and other localities on the north shore of the St. Lawrence ; the great peat-beds of Lanoraye, Lavaltrie, St. Sulpice, 0 feet in thickness. There is hardly a single stream connected with the Chaudiere valley that does not carry more or less gold, chiefly in the gravel which fills the cracks and crevices of the rock which forms its bed. But the greater portion of this surface gold has long since been extracted-— at least, as regards the smaller streams and rivers where the bed-rock can be easily got * Of Beauce County : not the Riviere du Loup of Kamouraska and Teraiscouta on the St. Lawrence 23 354 MINERALS AND GEOLOGY at and explored. It has been ascertained, however, that, in many if not in all cases, these existing streams and rivers flowed at one time in older and lower channels beneath their present beds. The ancient and in general wider channels have been subsequently covered up and hidden by deposits ot glacial and post-glacial age, consisting, as already stated, of gravels and black magnetic sand in immediate contact with the bed-rock, overlaid by clays and boulder-clays, other gravels (in some places auriferous) and vegetable soil. The clays and boulder-clays contain apparently no trace of gold ; and it is i.nly in the lowest layer of gravel immediately above the bed-rock, and in the cracks and hollows and behind projecting ridges of the bed-rock itself, that gold occurs in paying quantity. All underground work- ings therefore have to be carried down to the rock floor. When the gravel is washed, a certain amount of black magnetic sand is almost always found with the gold in the sluices, but this arises from the comparative density of the sand. The black sand, in itself, is no absolute indication of the presence of gold in alluvial gravels, as it occurs almost everywhere in the detritus of our crystalline rocks. The Leda Clay and Saxicava Sand deposits (see page 342) are largely displayed on the Trois Pistoles, Cacouna, Riviere du Loup (Temiscouta), St. Anne, Matanne, Metis, and other rivers, at various elevations from three or four, to over two hundred feet above the present sea-level. The more superficial deposits of the district include the bog-iron ores of Stanbridge, Farnham, Simpson, Ascot, Stanstead, Ireland, St. Lambert, St. Vallier, Vallery, Cacouna, and ether sites ; the ochres of Durham ; the shell marls of Stanstead, New Carlisle, etc.; and the peat beds of the Riviere Ouelle, Riviere du Loup, Metis, Rimouski, and Madawaska — most of which are of great extent, and from five to ten or fifteen feet in depth. OF CENTRAL CANADA— PART V. 355 APPENDIX. Sequence of Rock Formations recognized within the Provinces of Ontario and Quebec. Fifr*&- POST-CAINOZOIC FORMATIONS : 24. Deposits of Recent Origin. 23. Post-Glacial Deposits. 22. Drift or Glacial Deposits. PALEOZOIC FORMATIONS : — — • — Carboniferous : 21. Bonaventure Fn. Devonian : /^ 20. Portage-Chemung Fn. 19. Hamilton (or Lambton) Fn. 18. Corniferous Fn. 17. Oriskany Fn. Upper Silurian : 1 6. Lower Helderberg or Etirypterus Fn. 15. Onondaga or Gypsiferous Fn. 14. Guelph Fn. 13. Niagara Fn. 12. Clinton Fn. 11. Medina Fn. Lower (or Cambrio-) Silurian : 10. Hudson River Fn. 9. UticaFn. 8. Trenton (and Black River) Fn. 7. Chazy Fn. Cambrian : 6. Calciferous (including Quebec) Fn. 5. Potsdam Fn. 4. Keweenian Fn. 3. Animikie Fn. ARCHAEAN FORMATIONS : 2. Huronian Fn. 1. Laurentian Fn. INDEX. 357 INDEX. Abercrombie, 108. Abranchiata, 249. Acanthodes, 291. Acmite, 104. Acrogens, 215. Actinidee, 236. Actinocrinus, 240. Actinolite, 102. Acids, action of, 20. Action of the Atmosphere, 154. " " Streams and Rivers, 154. " Sea, 155. Actinophrys, 221. Acton, 144, 346. Adamantine Spar, 90. Addington, 82, 313. Adirondack Mts., 294, 320. Agalmatolite, 120. Agate, 95, 186. Agate Island, 186. Agelacrinites, 224. Aglossata, 275. Agnostus, 254. Albany Paver, 294, 331. Albeinarle, 317. Albion, 314. Albite, 107. Alcyonaria, 235. Algas, 212. Algoma Sand, 319, 320, 328, 331. Allanite, 100. Alum, 134. Alumette Lake and Rapids, 136, 179. Alvsolites, 231. Ambonychia, 276- Amherstburg, 326. Amethyst, 94. Amianthus, 102. Amoeba, 221. Amphibole, 102. Amphibolite, 170. Amphipoda, 262. Ammonites, 205, 288. Amphioxus, 290. Amplexus, 233, 323, 332. Ainygdaloidal Trap, 182, 186, 300, 352. Amygdalocystites, 241. Analcime, 113. Anamesite, 187. Ancaster, 323. Andesite, 108. Angiosperms, 206, 220. Animals, Classification of, 221. Animal Remains, 221-292. Animikie Formation, 172, 299, 302, 303. Annelida, 249. Annularia, 217. Anomura, 262. Anorthite, 109. Anorthosites, 181, 337. Antedon, 240. Anticlinals, 163. Anticosti, 145, 334, 342, 343, 344. Antimony : Glance, 79, Grey Ore of, 79. Native, 66, 347- Oxy-sulphide, 80, 347. Sulphide, 79, 347. AnthocoraUa, 235. Anthraxolite, 143. Antipathidse, 236. Apatite, 134, 307, 336. Aphanite, 187, Aphrodite, 119. Apiocrinus, 240. ApophyUite, 113. Aporosa, 236. Appalachian District, 344-354. Appalachian Mts., 344. Apus, 252. Aqueous rocks, 155. Arachnida, 263. Area, 276. Argenteuil, 96, 98, 99, 105, 110. Argentite, 67, 302. Archaean Age, 203. Archaean Districts, 295-304, 336-338 358 INDEX. Archaeocyathus, 225. Argenteuil, 84, 181, 337. Argillaceous, rocks, 151. Argillites, 171, 346. Argonaut, 289. Argulus, 253. Arnprior, 125, 304, 308. Arragonite, 125. Arsenical Nickel, 73. Pyrites, 77, 307. Arsenic, detection of, 32, 41. Arsenides, 67, 73. Artemisia, 320. Artemisia Gravel, 319, 320, 328. Arthrophycus, £13, 318. Arthropoda, 250. Articulata (Brachiopods), 268. Articulata (Crinoids), 238. Asaphus, 254, 255, 310, 311, 315; 317. Asbestus, 102, 348. Ascideans, 290. Ascoceras, 287. Ascot, 73, 87, 115, 347. Asiphonida, 275. Aspect, in minerals, 4. Asphalt, 143. Asteroidea, 245. Asterophyllites, 217. Astrseidae, 236. Astylospongia, 225. Athyris, 269, 325, 326. Atlantic^, 283. Atrypa, 270, 325, 326. Aubert Gallion, 88. Augite, 103, 182, 186, 336. Augite Kock, 169. Augitic Trap, 341. Aulopora, 235. Auriferous gravel, 353. Automolite, 91. Avicula, 276. Axis, anticlinal, 163. " synchinal, 163. Ayton, 324. Azurite, 129. Baie St. Paul, 83. 101, 105, 337. Balanus, 251. Balsam Lake, 74, 314, 316. Barnston, 180, 352. Barrack Hill (Ottawa), 311. Barrie (Frontenac Co.), 80, 99, 126, 308. Barrie (Simcoe Co.) 320. Barytine (Barite), 130. Basalt, 186. Bathyurus, 255. Bastard limestone, 309. Bathurst, 130, 180. Batiscan, 87. Bay of Chaleurs, 333, 351, 353. Bay of Quint6, 316. Bay St. Paul, 83, 101, 105, 337. Beatricia, 343. Beckwith, 145. Beauce Co., 64, 88, 118, 350. Beauharnois Co., 96, 132, 340. Beauport, 142, 342. Beaver Mine, 300. Bedford, 62, 69, 84, 306. Belemnites, 205, 289. Bekeil, 104, 110, 185, 188, 341. Belfontaine, 313, 322. Belinurus, 260. Bellerophon, 281, 282, 317. Belleville, 316, 319. Belmont, 84, 118, 306. Belmont Lake, 314. Beiitinck, 127. Bertie, 324, 325. Beyrichia, 251. Bigsby Island, 330, Big Stone Bay, 299, 301. Bismuth, Native, 66. Glance, 79. Biotite, 115. Bitter Spar, 126. Bitumen (Asphalt), 143, 351. Bituminous shales, 142, 311, 316. Bivalve Entomostracans, 251. Bizard, Isle, 340. Black Bay, 68, 72, 130, 185, 302, 303. Black Copper Ore, 81. Black Lead (Graphite), 61, 337. Black River limestone, 310, 315, 316, 339. Blastoids, 243. Blende, 69. Blende Lake, 303. Blowpipe, use of, 22-48. Blue Mts. (Collingwood), 317. Bobcageon, 316. Bog Iron Ore, 86, 342, 354. Bog Manganese Ore, 88. Bolton township, 73, 84, 86, 88, 114, 115, 117, 127, 347. Bonaventure Formation, 351. Bonaventure Island, 351. Bornite, 71, 303, 347. Bosanquet, 141, 243, 326, 327. Bothriocidaris, 247. Bouider Clay and Boulders, 300, 311. 314, 319, 328, 338, 341, 353. Brachiopoda, 266-274. Brachiura, 262. INDEX. 359: Branchiata, 249. Branchifera, 280, 281, 283. Branchipus, 252. Brant, 324, 326. Brantford, 132, 329. Breccias, 153. Brick Clays, 319, 328. Bridgewater, 117, Brisingida, 246. Brockville, 96, 294, 304, 308, 309, 312, 320. Brome, 73, 83, 103, 107, 115, 116, 190, 345, 349. Brome, Gale, and Shefford Mts., 351. Brompton, 99. Brompton Lake, 99. Bronteus, 256. Bronzite, 116. Brooke, 327. Broughton, 99, 116, 118, 172, 348. Brown Iron Ore, 86, 332, 342. Bruce Co., 324, 326. Bruce Mines, 71, 303. Bryozoa, 265. Buccinum, 283. Buckingham, 62, 96, 115. Bulb-tube, 30. Burford, 136, 352. Burgess, 62, 98, 106, 115, 118, 130, 135, 308. Burleigh, 180. Burleigh Falls, 316. Bythotrephis, 212. Bytownite, 109. Cabot's Head, 295, 313, 318, 319. Cacouna, 88. Calamites, 204, 216. Cainozoic Age, 205. Calcareous rocks, 151. Calcedony, 95. Calciferous Formation, 309, 340, 343, 348. Calcite (Calc Spar), 122. Calcispongias, 224. Calc Tufa, 124. Caledon, 318, 322. Calumet Falls, 98, 100, 101, 104, 106, 136, 170. Calumet Island, 109, 118. Calymene, 259,260, 311, 315, 317, 322, 325. Cambridge, 311. Camden, 87. Camerella, 270. Campement d' Ours, 329, 330. Canadian minerals : Determinative Tables of, 50, 57, Descriptions of, 61-145. Canadian Rock Formations, see Parts iii., v., vi., generally; also page 355. Cancrinite, 110. Cape Chin, 319, 322. C. Commodore, 319. C. Crocker. C. d' Espoir, 350. C. Gargantua, 66. C. Ipperwash, 76, 141, 216, 327. C. Maimanse, 189.| C. Paulet, 322. C. Rich, 130, 131. C. Rosier, 343", 349. C. Smythe, 330. C. Tourmente, 114. Celenterata, 225-236. Chaudiere Falls, 308. Chaudiere River and Valley, 63, 69, 119, 345, 349, 353. Chazy Formation, 310, 340, 343. Cheirocrinus, 240. Cheirurus (Ceraurus), 257, 310, 315, Chemical Characters of minerals, 18- 48. Chert, 95, 325. Chiastolite, 97, 352. Chiton, 280. Chlorastrolite, 111. Chlorides, 139-141. Chlorite, 115. Chlorite slate, 172, 297. Chloritic schists, 297, 346, 347. Chloritoid. 116. Chonetes, 272. Chrome garnet, 98, 99. Chromic Iron Ore, 85, 347. Chromiferous mica, 114. Chrysocolla, 121. Chrysolite (Olivinc), 105. Chrysotile (Serpentine-asbestus), 118, 347. Cirrhipedia, 250. Circular discs in Conifers, 220. Cladocera, 251. Clarence, 145, 311. Clarendon, 75, 98, 100. Clark Point, 328. Clay Iron Ore, 127. Clay slate, 151, 299, 349, 350, 353. Cleveland, 73, 88, 115, 348, 350, Cleavage iu minerals, 13. Cleavage, slaty, 166. Climactichnites, 213, 214, 309. Clinometer-Compass, 163.* Clinton, 140, 323, 324. * The cut illustrating this instrument has been placed incorrectly on one of its sides. The lettering shews the proper position of the instrument. 360 INDEX. Clinton Formation, 318, 322, 330. Clisiophyllum, 233. Clistenterata, 268. Clymenia, 288. Coal, 144. Cobalt Bloom, 137. Cobourg, 319. Cockburn Island, 329. Coccolite, 104. Codonaster, 2.42. Coleraine, 118, 348. Collingwood township, 316, 317, Colour in minerals, 5. Columnaria, 232, 315. Comatula, 240. Compton, 350, 352. Conchifera, 275. Conchoidal fracture, 14. Concordant stratification, 164. Condrodite (Chondrodite). 105. Conformable stratification, 164. Conglomerates, 153, 297, 305, 348, 351. Conifers, 219. Conocephalites, 259. Conifrontes, 258. Conocardium, 277. Consolidation of sediments, 157. Conularia, 279, 316. Copepoda, 251. Copper : Carbonates, 128, 129. Native, 65, 303, 347. Glance, 70, 347. Pyrites, 71, 303, 347. Purple Pyrites, 71, 303, 347. Silicate, 121. Copper-bearing rocks of Lake Super- ior : — see Animikie an 1 Keween- ian formations. Corals, 230-236. Cordaites, 218. Corniferous Formation, 96, 325. Cornwall, 310. Corundum, 90. Couchiching, Lake, 316. Conidse, 283. Craniadae, 273. Credit, River, 131, 317. Crinoidea, 237-240. Crosby, 84, 105, 306. Crossocoralla, 235. Crow Lake, 164. Crow River, 307, 316. Crown Point mine, 302. Crustacea, 250-262. Cryptogams, 211. Crystals, 7-12. Crystalline dolomite, 174, 346, 351. Crystalline limestone, 125, 173, 297, 305, 336, 346. Cumberland, 145, 308. Cupellation, 38. Cuttle Fish, 289. Cyathophyllum, 233. Cycads, 219. Cyclas, 277. Cyclopterus, 291. Cyprseidae, 283. Cypris, 251. Cyrena, 277. Cyrtoceras, 286. Cyrtodonta, 277. Cyrtolites, 281. Cyrtina, 269. Cystidea, 240-242. Cystiphyllum, 231, 234. Dalmanites, 258, 322. Datolite, 112. Dawsonite, 128. Decapoda (Crustaceans), 262. Decapoda (Cephalopods), 289. Delthyris (Platystrophia), 272. Dendocrinus, 239. Dennis quarries, 318. Dennison township, (see Addenda). Dentalium, 278. Denudation, 161. Dereham, 142. Devonian Formations, 325-327, 332, 350. Diabase, 188. ^ Diallage, 116. Diatoms, 215. Dibranchiata, 289. Dichoprionidians, 228. Dicotyledons, 211, 220. Dicranograptus, 228. Dictyonema, 229. Didymograptus, 227-8. Dikelocephalus, 256. Diopside, 103. Diorite, 188, 302. Dip of strata, 162. Diplograptus, 228. Diprionidians, 227. Discina, 273. Discomedusse, 226. Dislocation of strata. Dolerite, 186, 341. Dolomite, 126, 151', 174, 346, 351. Dolomitic limestone, 152. Domite, 190. Don, River, 313. Don Mills (Grand River), 324. INDEX. 361 Dorsibranchiata, 249. Douglastown, 143. Drift deposits, 300, 305, 311, 314, 319, 320, 328, 338, 338, 341, 344, 353. Drummond Island, 131. Dudswell, 125, 350, 351. Dumfries, 127, 132. Dundas, 82, 96, 132, 133, 313, 318, 319. Dunn, 325. Durham, 87, 313. Dykes, 174, 175, 181, 183, 184, 298, 300, 302, 341, 353. Eardly, 87. Earthy manganese ore, 88. Eastern Townships (Quebec), 64, 66, 69, 71, 73, 75, 79, 82, 84, 85, 86, 87, 95, 100, 101, 114, 115, 116, 117, 118, 126, 129, 172, 173, 344, 345, 346. Echinocystites, 244. Echinodermata, 236-248. Echinoidea, 247. Echo Lake, 66, 303. Economic minerals, Of Archaean rocks. 301-303, 306-308, 337 347 Of Paleozoic rocks, 312, 319, 324, 327, 351. Of Post-Cainozoic deposits, 319, 329, 342, 344, 353, 354. Edrioasteridge, 244. Edwardsburg, 308. Ekeolite, 110. Elephas, 292. Elderslie, 324. Elevation of strata, 158. Elevation, Valleys of, 163. Elizabethtown, 75. Elmsley, 106, 135. Elora, 127. Elzevir, 63, 84, 87, 99, 117, 172, 308. Emery, 90. Encrinites (Criuoids), 237. Encrinus, 240. Endoceras, 288. Endogenous rocks, 175. Enniskillen, 142, 143, 327. Eozoon, 222. Eospongia, 225. Epidote, 100. Epidote-rock, 170. Epsomite, 132. Equisetaceaj, 216. Eramosa, 69, 323. Erie and Huron District, 321-331. Erie Clay, 319, 323. Errantia, 249. Erubescite (Bornite), 71, 303, 347. Eruptive Rocks, 175, 297, 336, 341, 352. Essex, 326. Etchemin River, 66, 345, 353, 354. Euomphalus. 281, 309. Euelephas, 292. Euryalida, 245. Eurypterus, 261. Eurypterus, (Lower Helderberg) For- mation, 324. False bedding, 157. Famine River, 64, 345, 353. Faraday township, 84, 306. Farnham, 354. Faults in strata, 164, 165, 334, 339, 340. Favosites, 231, 232, 325, 332. Feldspars, 106-109. Feldspar-rock (Feldspathic gneiss), 168. Felsite, 178. Fenelon Falls, 316. Fenestella, 266. Fergus, 323. Ferns, 204, 217. Finch, 145. Firolidge, 283. Fishes, 204, 205, 291. Fistulipora, 231. Fitzroy, 308. Fitzroy Island (Niagara Formation, Georgian Bay). Flamborough, 318. Flaming process, 33. Fleurant Point, 351. Flint, 95, 325, (chert). Flower-pot Islands (Niagara Forma- tion, Georgian Bay). Fluor Island, 139. Fluorides, 137. Fluor Spar, 138. Footwall in veins, 193. Foraminifera, 222. Form : Regular 7 ; Irregular 13. Fort William (Lake Snperior), 66, 67, 130, 134. Fossilized Organic Bodies, 209-289. Animal Remains, 221-292. " Vegetable Remains, 210- 220, 351. Fracturing of sti'ata, 164. French River. 262 INDEX, Frontenac Co., 69, 78, 126, 192, 304, 313 Frontones, 256, Fungiiliu, 236. Fusibility in minerals, 28. Fusidae, 283. Gale Mountain (Brome) 352. Galena, 67, 303, 307, 323. Gait, 323. Galway township, 69, 98, 123, 133, 172, 307. Gananoque, 304, 307. Garden River, 68, 302. Garnet, 98, 297, 304. Garnet-rock, 171. Garthby, 118. Gash veins, 194, 322. Gaspe, 68, 95, 118, 127, 334, 344, 345, 350, 352. Gaspe Bay, 351, 353. Gasp6 limestones and sandstones, 68, 350. Gasteropoda, 279. Genthite, 121. Geological Ages and Periods, Table of, 201. Georgetown, 313, 318. Georgian Bay, 313, 215, 318. Gephyrea, 249. Glacial Formation, 207, 300, 311, 314, 319, 328, 331, 338, 341, 353. Glacial strife, 300, 306, 311, 319, 331. Glaciers, 155, 207, 300. Glamorgan, 84, 306. Glaucom'te, 121. Glauconitic sandstones, 348. Glossophora, 275. Gloucester, 145 Glyptocrinus, 239. Gneiss, 168, 169, 203, 297, 305, 334, 336, 337, 346. Goderich, 324. Gold, 62, 301, 307, 353. see also the Addenda. Gomphoceras, 286. Goniatites, 205, 289. Gorgonidas, 235. Goulais Bay, 187. Goulbourne, 145. Grand Island, 324. Grand River, 132, 323. Granite, 177, 178, 297, 298, 304, 305, 352. Granitoid Trachyte, 190, 341, 352. Graphic granite, 178, 179. Graphite, 61, 337. Graptolites, 226, 228, 311, 316, 317, 348. Green's Creek, 291, 311. Greenstone, 182, 187, 299, 336, 353. Grenville (P.Q.), 62, 95, 100, 103, 106, 108, 109, 110, 118, 145, 179, 336. Grey Band (Medina Formation), 318. Grimsby, 321. Gros Cap, 187, 189. Guelph, 127, 323, 324. Guelph Formation, 323. Gulf, St. Lawrence, 333, 338, 342. Gum Beds, 143, 327. Gymnosperms, 219. Gymnolsemata, 266. Gymnosomata, 278. Gypsiferous Formation, 323. Gypsum, 131, 324, 332. Hematite, 81, 303, 306, 337. Haldimand, 324, 326. Haliburton, 84, 108, 304. Halifax township (P.Q.), 83. Hallowell Spring, 141. Halysites, 232, 322, 338. Ham township, 66, 79, 80, 86, 118, 346, 347, 348. Hamilton, 124, 139, 291, 295, 312, 318, 321. Hamilton Formation, 326. Hanging- wall in veins, 193. Hardness in minerals, 14, 16. Harrington, 145. Harpes, 258. Harvey Hill mine, 347. Hastings Co., 64, 72, 75, 82, 120, 304, 306, 313. Hawkesbury, 136, 310. Healey's Falls, 316. Heavy Spar, 130. Heliopora, 318. Heliophylltan, 233. Helix, 280. Hematite, 81, 303, 306, 337. Hemicystites, 244. Hemrningford, 145, 340. Hereford, 180, 352. Herschel, 84. Hespeler, 323. Heterocrinus, 239. Heteromyaria, 276. Heteropoda, 283. Hexapoda (Insecta), 264. Hinchinbrook, 76. Holopea, 282. Holostomata, 281. Holothuroidea, 248. Homalonotus, 260, 322. Homomyaria, 276. Hornblende, 102. Hornblende-rock or slate, 170. INDEX. 363 Hornblendic gneiss, 169. Hornblendic granite, 179. Hornstone, 95. " Horses " in mineral veins, 195. Horseflesh Ore (Bornite), 71, 303, 347. Huckleberry Hills, 305, 307. Hudson River Formation, 311, 317, 330, 340, 343, 349. Hull, 82, 84, 130, 139, 337. Hull cement, 312. Humber, River, 313, 317. Humberstone, 145, 326. Humboldtine, 141. Huntington, 124, 340, 346, (mine). Huntly, 145, 310. Huron Co., 326. Huronia, 288. Huron, Lake, 66, 68, 70, 72, 73, 76, 85, 95, 297, 298, 300, 301, 303, 321, 329. Huronian Formation, 297, 299. Hyacinth (Zircon), 97. Hybocrinus, 240. Hydraulic limestone, 152, 324. Hydrocoralla, 229. Hydromedusae, 226. Hymenocaris, 261. Hydrozoa, 226. Hypersthene, 105, 337. Hypersthene-rock, 182. Ichthyocrinus, 240. Idocrase, 100. Igneous rocks, 175. Illfenus, 255, 310. Ilmenite, 83. Inarticulata, 272. Incellata, 235. Indiana township, 324. " Infusorial " marls, 215. Inornata, 231. Insecta, 264. Integri-radiata, 277. Integri-stellata, 234. Intrusive rocks, 175. Ipperwash, Cape, 76, 141, 216, 327. Ireland township, 87. Iridescent Feldspars, 107, 108, 337. Iricl-Osmium, 64. Iron Island, 82, 130. Iron Ores, 81, 174, 303, 306, 337, 342, 347. Iron Oxalate, 141. Iron Pyrites, 74, 327, 352. Iron Vitriol, 133, Iserine, 85. Isidacese, 235. Island of Orleans, 76, 339, 348. Isle Bizard, 340. Isle Jesus, 340. Isle Royale, 111. Isopoda, 262. Isoteles (Asaphus), 255. Ives mine, 195, 347. James' Bay, 294, 296, 353. Jargon, 97. Jarvis Island, 130. Jasper, 95. Jasper, conglomerate, 95, 171. JolietteCo., 91, 115, 337. Kaministiquia River, 72, 76, 184. Kamouraska, 345, 349. Kaolin, 107. Kaolinite, 119. Kenny on, 311. Kent, 326. Kepple, 317. Kermesite, 80, 348. Kettle Point, 76, 141, 216, 327. Keweenian Formation, 299, 303. Kincardine, 140. King, 314, 320. Kingsey, 348. Kingston, 70, 131, 294, 312, 315. 316, 320. Knowlton Lake, 314. Labradorite, 108, 109, 337. "Labrador Formation," 181, 337. Lachine, 190. La Cloche Islands, 329, 330. Lakefield, 316. Lake township, 69, 307. Lake Ontario District, 312-320. Lakes : Allumette, 114, 179. Balsam, 74. Belmont, 314. Brompton, 99. Champlain, 335, 342, 345. Charleston, 96, 98, 309. Couchiching, 89, 316. Crow, 164. Eagle, 303. Echo, 72, 303. Eel, 314. Erie, 321, 325, 328. Of the Woods, 299, 301, 302, 304. Golden, 109. Hollow, 101. Huron, 66. 68, 70, 72, 73, 76, 85, 95, 295, 297, 298, 301, 321. Knowlton, 314. Loughborough, 314. Magog, 345. Manitou, 331. 364 INDEX. Lakes — Continued. Mazinaw, 126, 174. Megantic, 180, 352. Memphramagog, 86, 120, 345, 346, Metapedia, 345. Moira, 90. Muskoka, 101, 305. Neepigon, 299, 300, 311. Nipissing, 82, 130, 304, 306. Otty, 309. Ontario, 312, 313, 314, 315, 317. Rice, 314. St. Clair, 321, 327. St. Francis, 97, 180, 345, 352. St. John(P.Q.), 337, 338. St. John (Ont.j, 316. St. Peter, 340. Scugog, 314. Silver, 303. Simcoe, 295, 313. Stoney, 98, 107, 180, 305. Superior, 65, 68, 72, 82, 85, 111, 112, 187, 294, 296, 297, 299, 300. Temiscamingue, 294, 297. Temiscouata, 345, Wolsey, 331. Lambton Co., 326. Lambton (Hamilton) Formation, 326. Lamellibranchiata, 275. Lanark Co., 84, 103, 110, 135, 309. Lanordie, 145, 342. Lansdowne, 69, 130. Latiformes (Trilobites), 254. Laumontite, 112. Laurentian Formation, 169, 297, 305, 336. Laurentide Mountains, 334, 336. Lauzun Formation, 347. La Valtrie, 145, 342. Lead sulphide (galena) 67, 303,307,323. Lecanocrinus, 240. Leda Clay Formation, 342, 353. 354. Leda truncata, 277, 342 (note). Leeds, 69, 71, 78, 105, 110, 130, 348. Lennoxville, 69. Leperditia, 251. Lepidodendroecese, 217. Lepidodendron, 204, 218. Leptaena, 271. Levis Formation, 347, 348. Lichas, 256. Lima, 276. Limestones, 125, 151, 152, 173. see also under different Formations. Lime, Carbonate, 122. Feldspars, 108, 109, 337. Phosphate, 134, 307, 336. Sulphate, 131, 324, 332. Limerick, 69, 307. Limnea, 278. Limonite, 86, 332, 342. Limulus, 260. Lincoln Co., 69. Lingula, 273, 274, 309, 310, 316, 318, 348. Lingulella, 274. Linobolus. 273. Lithographic stone, 125, 315. Little Current, 329. Little Gaspe" Cove, 351. Lituites, 286, 287. Lochiel, 136, 310, 311. Lochaber, 62, 336. Loganellus, 258. Loganite, 116. Loganograptus, 228, 348. London, Ont., 328. Longueuil, 145. L'Orignal, 310, 311, 312. Lotbiniere, 64, 144. Loughborough, 62, 123, 192, 307, 314, 315. Lower Helderberg Formation, 324, 339 Lower Ottawa District, 308-312. Lucina, 277. Lustre in minerals, 4. Lutterworth, 102. Lycopodiacese, 217. Machaeracanthus, 291. McKay's Mountain, 299. McNab township, 82, 306, 508. Maclurea, 281, 282, 310, 316, 338. Macrura, 262. Madoc, 63, 67, 74, 84, 99, 101, 103, 305, 306. Magdalen River (Gaspe"), 345, 349. Magnesia Mica, 114, 337. Sulphate, 132. Magnesite, 127. Magnetic Iron Ore (Magnetite), 83, 304, 306, 337, 347. Magnetic Pyrites, 74. Magnetic Iron Sands, 63, 85, 354. Magnetism in minerals, 1 7 . Maimanse, 71, 89, 99, 100. Malachite, 128. Malacodermata, 236. Maiden, 326. Malleability in minerals, 17. Mallotus, 291, 312. Mammoth, 292. Manganese carbonate, 127. Manganese Ores, 87, 88. Manganese, detection of, 36. Manitoulin District, 329-331. INDEX. 365 Manitoulin Island, 131, 142, 164, 295, Marble,' 125, 312, 340, 346, 351. Marcasite, 76. Marmora, 63, 84, 99, 118, 305, 306, 307, 315. Martite, 82, 85. Maskinonge Co., 99, 109. Massive rocks, 174-191. Mastodon, 292. Medina Formation, 318. Megalomus, 277, 323. Megantic, Lake, 180, 352. Megantic Mountains, 352. Memphramagog, Lake, 86, 120, 345, 346, 350. Melbourne township, 62, 71, 73, 86, 100, 115, 118, 125, 348, 350. Menighinite, 80. Merostomata, 260. Mesozoic Age, 205. Metamorphic Rocks, 167, 168, 297, 305, 336, 346. Metamorphism, 165. Meteor c Iron, 67. Micas, 114, 337. Mica schist, 169. Michelinea, 231, 232, 325. Michipicoten Island, 65, 95, 100, 113, 121, 186, 189, 298, 300, 303. Michipicoten River, 298. Middlesex Co., 329. Millerite, 73. Mlllepora, 231. Millstones, 325. Mimico River, 317. Miiiden, 84, 306. Mineral Veins, 191-198 Mingan coast and Islands, 334, 342, 343. Mispickel, 77, 307. Modiolopsis, 276. Moira Lake, 90. Moira River, 307, 313, 316. Mollusca, 265-289. Molluscoidea, 265-274. Molybdenite, 78. Monmouth, 84. Monnoir (Mt. Johnson), 184 188, 341. Mono, 318, 320. Monocotyledons, 205, 220. Monomerella, 273. Monomyaria, 276. Monoprionidians, 228. Montarville, 105, 187, 341. Montcalm Co., 83, 337. Monticulipora, 231. Montmorenci River, 333; Falls, 341 Montreal, 103, 104, 105, 107, 110, 185, 187, 341, 342. Moose River, 331. Morin, 108, 110. Mosa, 142, 327. Mt. Albert, 86, 99, 103. 118, 346, 348. Mt. Johnson, 103, 107,A184, 188, 341 Mulmur, 69, 318, 320, 322. Mundic, 74. Murchisonia, 281, 282, 310, 316, 317. Muricidee, 283. Murray Bay, 99, 344. Muscovite, 114. Muskoka, 101, 305. Mya, 278, 332. Myriapoda, 263. Mytilus, 276. Naptha, 141. Native Antimony, 66, 347. N. Bismuth, 66. N. Copper, 65, 303, 347. N. Gold, 62, 301, 307, 353. see also the Addenda. N. Lead, 66. N. Silver, 64, 302. Natrolite, 112. Nautilus, 285. Neebing, 76, 130, 139. Neepigon, Lake and River, 299, 300, 311. Nelson, 318. Nepean, 145, 309, 310. Nepheline, 110. Neustadt, 324. Niagara Escarpment, 295, 314, 318, 321. Niagara Falls, 126, 131, 132, 322, 324, 329. Niagara Formation, 124, 322, 330, 343. Niagara River, 313, 318. Nickel Ores, 73, 346. Nickel Vitriol, 133. Nipissing, Lake. 82, 130, 304, 306. Noisy River, 124, 319. Norian rocks, 337. Norfolk Co., 87, 326. Normanby, 324. Northern Archaean District (Quebec), 336. Northern Palaeozoic Area(0ntario)331. Northumberland, 313. Ndtre Dame Mountains, 334, 344, 346. Nottawasaga Bay, etc., 313, 315, 317, 318. 366 INDEX. Nucleobranchiata, 283. Nucleocrinus, 243. Nudibranchiata, 280. Nucula, 276. Oak Ridges, 320. Oblique bedding, 157. Obolus, 274. Obsidian, 191. Ochres, 87, 89, 329, 342, 354. Octopus, 289. Oculinidse, 239. Ogygia, 255. Oli ligoclase, 107. Olivine, 105. Oneida, 132, 322. 325. Onondaga Formation, 132. Ontario, Geology of, 294-323. Operculata (Corals), 234. Ophileta, 281, 309. Ophiolite (Serpentine), 173, 346. Ophiuroidea, 245. Opisthobranchiata, 280. Orbiculoidea, 273. Orford township, 74, 79, 103, 125, 346, 350, Organic Remains, 209-292. Orillia, 85. Oriskany Formation, 325. Orleans, Island of, 76, 339, 348. Ormoceras, 288. Orthis, 271, 272, 310, 316, 322, 326. Orthite, 100. Orthoceras, 286, 288, 316, 317. Orthoconcha, 276. Orthoclase, 106, 168, 178, 181, 336, 352. Osgoode, 311. Ornabruck, 145. Ostracoda, 251. Ostrasa, 276. Ottawa, 109, 308, 310, 311, 312. Ottawa Co., 99, 100, 107, 109. Ottawa River, 136, 294, 308, 310, 311. Outliers, 161, 305, 338. Ouvarovite (Chrome garnet), 98. Owen Sound, 131, 323. Owl's Head Mountain, 346. Oxalateof Iron, 141. Oxford Co., 324. Oxford township, 142. Oxides, 80, 86, 87, 89. Ox Point, 316. Paguridffi, 262. Paisley, 324. Pakenham, 125. Palasterina, 246. Palseaster, 246. Palseocrinus, 240. Palaeozoic Age, 204. Paradoxides, 257. Pauquette's Rapids, 96. Paris (Ont.), 324, 329. Parophite, 120. Pasceolus, 223. • Peat, 145, 342, 344, 354. Pecten, 276. Peel Co., 313. Pegmatite, 178. Pembroke, 179, 305. Pennatula, 235. Pennine, 115. Pentamerus, 271, 319, 322. Pentremites, 243. Perce, 351. Perforata, 236. Peristerite, 106. Peterborough, 316. Peterborough Co., 70, 304, 313. Petraia, 234. Petraster, 246. Petroleum, 141, 327, 331. Petrosilex, 178. Phacops, 257, 258, 325. Phaneropleuron, 291. Phillipsastrea, 233. Phlogopite, 114, 336. Pholerite, 119. Phonolite, 190. Phosphate (Apatite), 134, 308, 336. Phosphates, 134. Phragmoceras, 286, 287, 332. Phyllocarida, 261. Phyllograptus, 228, 348. Phyllopoda, 251. Physical Characters of minerals, 3-18. Pic River, 82, 84, 299, 302. Pickering, 317. Pie Island (Lake Superior), 130, 299, 302. Pigeon River, 70, 130, 300. Pillar sandstones, 348. Finite, 120. Pisocrinus, 240. Pitchblende, 89. Pitchstone, 191. Placophora, 280. Planorbis, 278, 320. Plantagenet, 145, 308, 311. Plant Remains, 210-220. Plaster of Paris, 132, 324. Platinum, 64. Platyceras, 281, 282, 316. Platystrophia, 271, 272, 316. Pleurocystites, 242. Pleurotomaria, 281, 282, 310, 316. Plumbago (Graphite), 61, 337. Plutonic Rocks, 176. Pointe aux Mines, 70, 72, 139. Points aux Trembles, 341. Point Boucher, 318. P. LeMs, 136, 144, 339, 349. P. Montresor, 318. P. Rich, 130, 131, 1$2, 318. P. William, 318. Polycystina, 223. Polyifera (Corals), 229. Polystomata, 223. Polystomella, 222. Polyzoa, 265. Porifera, 223. Poritidae, 236. Porphyry, 179. Porphyritic granite, 179. Porphyritic trachyte, 190. Porcupine vein, 302. Portage- Chemung Formation, 327. Port Albert, 326. P. Colborne, 326. P. Frank, 328. P. Hope, 317. P. Stanley, 328. P. Talbot, 328. Post-Cainozoic Period, 207. Post-Glacial deposits, 291, 300, 315, 319, 320, 328, 333, 338, 342, 344, 353, 354. Potstone, 172, 348. Potsdam Formation, 308, 314, 340. Potton township, 100, 103, 117,172, 346. Prehnite, 111. Prescott, 309. Prince's Location, 65, 67, 113, 303. Prismatic Pyrites, 76. Productus, 272. Prosobranchiata, 280. Protichtites, 213, 309. Protogine, 179. Protozoa, 221. Pseudo-metallic lustre, 5. Pseudopodifera, 221. Psilophyton, 218. Pterichthys, 291. Pteropoda, 278. Pterygotus, 261. Pulmonata, 280, Purple Copper Pyrites, 71, 347. Pusilliformes, 254. Pygidium, in Trilo bites, 254. Pyrallolite, 117. Pyrites : Arsenical, 77, 307. Cockscomb, 76. Copper, 71, 303, 347. Pyrites— Continued. Cubical, 74, 327, 352. Iron, 74, 327, 352. Magnetic, 74. Prismatic, 76. Purple, 71, 303, 347. Radiated, 76. Pyroxene, 103, 336. Pyroxenite, 169, 186. Quartz, 93. Quartzites (Quartz Rock), 171, 297, 305, 336, 346. Quebec City, 88, 144, 339. "Quebec Group," 347, 348. Quebec Province, 91, 115, 333, 335-354. Queenston, 318, 321. Quinte, Bay of, 313, 316. Rabbit Hill mine, 301. Radiolaria, 222, 223. Radiated Pyrites, 76. Radnor, 87. Rainham, 326. Rama, 316. Ramsay, 69, 123, 307. Rawdon, S3, 99. Receptaculites, 223. Red Antimony Ore, 80, 347 . Red Copper Ore, 80. Red Coral, 235. Red Iron Ore, 81. Rednersville, 316. Renfrew, 84, 106, 109, 114, 139, 310. Renilla, 235. Renselacrite, 117- Rhizopods (Pseudopodifera), 221. Rhodochrosite, 127. Rhyuconella, 270, 310, 316. Rice Lake, 314. Rigaud Mountain, 188, 341. Rivers : Achigan, 136. Albany, 294, 351. Assomption, 333, 336. Batiscan, 87, 336. Beaver, 124, 319. Bonnechere, 30o. Bras, 130. Cacouna, 354. Cascapedia, 345. Chatte, 152, 345. Chaudiere, 63, 69, 85, 333, 345, 349, 350, 353. Chicot, 340. Clare, 316. Credit, 131, 317, 318, 322. Crow, 307. Des Plantes, 63, 345, 353. 368 INDEX, Rivers — Continued. Detroit, 294. Don, 313. Du Lievre, 336. Du Loup (Beauce), 63, 353. Du Loup (Kamouraska), 333, 354. Du Moine, 336. Du Nord, 336. Etchemin, 66, 345, 353, 354. Etobicoke, 317. Famine, 63, 345, 353. Garden, 68, 72, 303. Gatineau, 130, 336. Gilbert, 85, 353. Goulais, 189, 301. Grand, 132, 321, 323, 324. Guillaume, 63. Holland, 313, Humber, 313, 317. Irvine, 323. Kaministiquia, 76, 134, 184, 301. Mad, 319. Madawaska, 103, 101, 145, 312, 354. Magdalen, 345, 349. Magpie, 298. Maitland, 140, 321. Matanne, 345, 354. Matapediac, 345. Metis, 145, 333, 345, 354. Metgermet, 63. Mimico, 317. Mitchipicoten, 298. Montmorenci, 33, 336. Moira, 307, 313, 316. Moisie, 336, 337, 338. Moose, 351. Muskoka, 101. Nation, 294. Neepigon, 301. Niagara, 313, 318, 325. Noisy, 124, 319. Nottawasaga, 125, 313. Ottawa, 136, 308, 334, 336. Ouelle, 95, 136, 145, 354. Pabos, 350. Pic, 82, 84, 298. Pigeon, 130, 299, 300. Richelieu, 107, 333. Rideau, 311. Rimouski, 145. Root, 72. Rouge (Ont.), 317. Rouge (P.Q.), 99, 336. Ste. Anne, 87, 333, 336. Ste. Anne des Monts, 348. St. Francis, 63, 85, 333, 345. St. Lawrence, 295, 308, 315, 333, 339, 342, 344, 348. Rivers — Continued. St. Mary, 301, 330. St. Maurice, 87, 96, 114, 333, 336, 340. Saguenay, 336, 338. Salmon, 313. Saugeen, 132, 321, 324, 323. Scugog,.313. Seaforth, 324. Severn, 304, 313, 315. Slate, 111, 134, 184. South Nation, 308, 311. Spanish, 298. Speed, 323. Thames, 321. Touffe des-Pins, 63. Trent, 313, 316. Trois Pistoles, 345, 354. Wahnapitae, 298. Yamaska, 345. Rocks : Classification of, 147. Structural Characters, etc., 150-207. Formations of Central Canada, 355. Eruptive, 174-191. Metamorphic, 167-174. Sedimeutary, 150-167. Rock Crystal, 94. Rock Oil, 141. Rock Salt, 139. Rockwood, 124, 323. Ross, 84, 106, 136, 139. Rougemont, 105, 187, 341. Roxborough, 145. Ruby, 90. Russell Co., 309, 310. Rutile, 89. Ste. Anue, 87, 333, 336 (Portnent), 354. Ste. Anne des Monts, 348. St. Armand, 82, 100, 115, 125. St. Catharines, 141. St. Dominique, 342, St. Etiene, 145. St. Flavien, 66. St. Francis, 63, 83, 99, 103, 118, 120, 333, 345. St. George (Beauce), 63, 350. St. Giles, 64. St. Helen's Island, 128. St. Henri, 66. St. Ignace, 65, 95, 111, 123, 300. St. Jerome, 74, 98, 99, 105, 110. St. Joseph, 100, 125, 349. St. Joseph's Island, 329. St. Lawrence (River), 294, 308, 315, 333, 339, 342, 344, 348. St. Lambert, 354. 360 St. Lin, 125, 340. Ste. Marie (Beauce), 63, 88, 145. Ste. Marie sandstones (Lake Huron), 330. St. Marys, 326, 328. St. Maurice, 87, 336. St. Nicholas, 120. Ste. Roselie, 145. St. Roche, 136, 341. St. Sulpice, 145, 341. St. Sylvester, 88. St. Urbam, 105. St. Vallier, 354. St. Vincent, 132, 317. Sabella, 249. Sacharoidal limestone, 173. Saguenay River, 336. Sahlite, 103. > anclstones. 96, 151. SaultdeSte. Marie, 301. 303. Saugeen Clays and Sands, 319, 328. Saugeen River, 132, 321, 324, 328, Saxicava, 278, 332, 342. Saxicava Sand, 342, 353, 354. Scaphopoda, 278. Scapolite, 109.. 336. Scarborough (Out.) 320. Schorl, 97. Sclerobasica, 236. ,-colithus cavities, 249, 309. Scugog Lake, 314. Seaforth, 140, 324. Sea Urchins, 247. Sedimentary Rocks, 150-167. Sediments, derivation of, 153. Sediments, consolidation of, 157. Selenite, 131. Seneca township, 132, 324. Sepia, 289. Serpentine, 118, 173, 347. Serpentine-Asbestus, 118, 347. Serpentine-marble, 118, 173, 346, 347. Serpula, 249. Severn River, 304, 313, 315. Shannon ville, 316. Shebandowan district, 302. Sheffield township, 79, 145, 316. Sheflord, 103, 115, 346, 349. Shefford Mountain, 103, ICO. 352. Shell Marl, 152, 312, 320, 342, 354. Sherbrooke, 349. Sherrington, 145, 342. Shickshock Mountains, 170, 334, 344, 345, 346. Shipton, 62, 100, 346. Shuniah (Duncan) Mine, 195, 302. Sigillaria, 217, 219. Siderite, 127. Silicates, 91-121. 24 Sillery strata, 348. Siliceous slate, 171. Silurian Formations : Lower, 308-311, 314-319, 330, 340, 343, 349, 355. Upper, 322-324, 33J, 332, 343, 350, 355. Silver, detection of, 39. Silver Creek vein, 302. Silver Islet, 65, 302. Silver Glance, 67, 302. Silver Lake, 303. Silver, Native, 64. 302. Simcoe Co., 87, 313. Simcoe, Lake, 314. Simpson, 87. Singleton mine, 302. Sinupalliata, 277. Siphouida, 275. Siphonostomata, 283. Sipunculus, 249. Slate River, 184. iSlaty Cleavage, 166. Smith's Falls, 309. Siiowdon township, 84, 306. Soapstone, 117, 172, H3, 348. Socialite, 110. Solaster, 246. Somerville, 69, 307. SoulangesCo., 333, 339, 340. Spanish River, 72, 2i!S. Si ar Island, 65, 113, 128. Specific Gravity, 16. Specular Iron Ure. 81. Specujar-iron schists, 174, 304, 346. Sphalerite (Blende), 69, 303. bpathic Iron Ore, 127. Sphene, 102, 336. S^iculosa, 235. Spinel, 91, 115. Spiriferidse, 269. Spirifer, 269, 322, 325, 326. Spirigera (Athyris), 269, 325, 326. Spirigerina (Atrypa), 270, S25, 326. Spirorbis, 249. Sponges, 223, 224. Stalactites and Stalagmites, 125. Stanstead, 87, 88, 348, 352. Steatite, 117, 172. Stellerida, 246. Stenaster, 246. Stenopora, 231, 315, 317. Stephanocrinus, 24X, Stigmaria, 219, 351. Stilbite. 1121. Stirling, 314. Stocks (Ore), 192, S06. Stoke Mountains, 344, 346. Stornapoda, 262. 370 INDEX. Stormont, 310. Storrington, 180, 314. Stratification, 164. Streak in minerals, 6. Stricklandia, 270. Strike of strata, 162. Stromatopora, 225, 315, 338. Strombidfe, 283. Strontianite, 128. Strophomena, 271, 310, 311, 315, 317, 325. Structure in minerals, 7. Stukely, 345. Sturgeon Lake, 313, Subulites, 282. Sudbury, 72, 298, 001, 302, 303. see also the Addenda. Suffield mine, 347. Superficial deposits, 291, 300, 315, 319, 320, 328, 333, 338, 342, 344, 353, 354. Superior, Lake, 65, 68, 72, 85, 111, 112, 299. 300. Sulphates, 129-134. Sulphate of : alumina, 134. baryta, 130. iron, 133. lime, 131. magnesia, 132. nickel, 133, strontia, 131. Sulphides, 67-80. Sulphide of : copper, 70, 71. iron, 74, 76. lead, 67. molybdenum, 78. nickel, 73. silver, 67. Sulphur, 62. Sutton township (P.Q.), 73, 74, 83, 99, 101, 114, 115, 117, 127, 345. Sutton Mountain, 346. Syenite, 180, 298, 336. Syenitic gneiss, 169. Syenitic granite, 179, 305, 307. Synclinal axis, 163. Syringopora, 232, 325, Tabular Distribution of Canadian minerals, 50, 57. Tabular Sequence of Eock Formations, I x 355. Tasuiaster, 245. Talc, 117. Talcose granite, 179. Talcose schists, 346. Tarnish in minerals, 6. Tar Point, 133, 351, 335. Tectibranchiata, 280. Tellina, 278, 332. Tellurium, 302. Temiscainingue, Lake, 294, 297. Templeton, 82, 84, 96, 115, 136, 336 Tentaculites, 279. Tentaculite limestone, 324. Terebratulida, 270 Terrace Cove, 78, 139. Terreboune. 74, 75, 108, 337. Tesselata, 238 Tetrabranchiata, 285. Thallogens, 212. Thames, Eiver, 321. Thecosomata, 278. Thessalon, 330. Thetford, 118, 348. Thomsonite, 112. Thorold, 319, 321. Thorold cement, 319, 322. Thousand Isles, 149. Three Eivers, 87. Thunder Bay, 68, 94, 117, 138, 139, 144, 192, 300, 302. Thunder Cape, 109, 183, 299. * Titaniferous Magnetite, 85, 306,[338. Titanite, 102. - Titanium Oxides, 89. Toronto, 160, 317, 319, 320. Tourmaline, 97. Trachytes, 189, 190, 341, 349. Traps, 183, 186, 299, 341, 353. Trap dykes, 183, 184, 352. Trap tufa, 153. Tremolite, 102. Trent Eiver, 313. Trenton, 316. Trenton Formation, 310, 315, 330, 338, 340, 343. Triarthrus, 259, 311, 316. Trimerella, 275, 323. Tring, 88, 126. Trilobites, 250-260. Trinucleus, 257, 315, 317. Tripoli, 215. Trois Pistoles, 345, 354. Tubicola, 249. Tubipora, 235. Tubulifera, 235. Tudor, 69, 77, 79, 84, 101, 306, 307. Tufa, calcareous, 124. Tungstenum Compounds, 89. Tunicata, 290. TurbicolidfB, 346. Tuscorora water, 133. Unio, 276, 320. Unstratified rocks, 174-191. 371 Ipper Copper-bearing rocks (Lake Superior), 65, 299. Upper Lakes, District of, 297-304. Upper Silurian Series, 322-324, 331, 332, 343, 350, 355. Upper St. Lawrence District, 338-342. Uran. ochre, 89. Urastella, 246. Utica Formation, 311, 316, 330, 338, 349. Vallery, 354. Valleys of Denudation, 161. Dislocation, 165. Elevation, 163. Undulation, 163. Vaudreuil Co., 87, 96, 137, 333, 339, 340. Vaudreuil (Beauce), 63. Veins, mineral, 119-198. Verines, 248. Vertebrata, 290. Vesiculosa, 234. Vesiculo-stellata, 233. Vesuvian, 100. Victoria Co. (Ont.), 306, 313. Victoria Mountain (P.Q.), 346. Virgularia, 235. Vivianite, 137. Vugs in mineral veins, 123, 194. Wainfleet, 145, 329. Wakefield, 340. Walkerton, 324, 328. Wallace mine, 73, 82, 134, 303. Walpole, 326. Warwick, 327. Waterloo Co., 324. Weedon, 350. Welland, 319, 322, 324, 326. Wellington Mines, 72, 126. Wellington Square, 318. WentworthCo. (Ont.), 313. Wentworth (P.Q.), 103, 181, 32b. Wernerite (Scapolite), 109, 336. Westbury, 350. Westmeath, 145. Whetstones, 348. Whitby, 316, 317. Wilsonite (Scapolite), 110. Windham, 325. Wolfestown, 348, 349. Wolfram, 89. Wollaston, 306. Wollastonite, 110. Wollastonite Rock, 170. Wolsey, Lake, 331. Woodhouse, 336. Wood, Lake of the, 299, 301, 302, 304. Yamaska Mountain, 101, 103, 109, 188, 190, 341. Yamaska River, 345. Yellow Ochre, 86, 329, 342, 354. Yellow Copper-ore, 71, 347. Yeo's Island, 114. Young township, 309. Zaphrentis, 233, 325. Zinc Blende, 69, 303. Zircon, 96, 336. Zoantharia, 235. Zoanthidae, 236. Zone township, 327. Chajprnon, E 3" The vooo 1828 cental Ccfnbdo FEB 2 1994 NOV 2 3 1994 LIBRARY UNIVERSITY OF TORONTO