. * 3 +1 ie. fees ae 2 ee Me > Vou. 10. Jury 1831. No. 55. ~ ' bd » rm v- ve "EES ay 4% } SIME NEA NEA ME AME AMEANEA MEA MEANE) Published the First Day of every Month.—Price 2s. 6d. x i ae ANG) : | THE me C BS PHILOSOPHICAL MAGAZINE @ t 4 AND ae CSS . <3 ANNALS OF PHILOSOPHY: < es ; ; COMPREHENDING we2 THE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL SS é +] AND FINE ARTS, AGRICULTURE, MANUFACTURES, s AND COMMERCE. Ce Pee| = NEW SERIES. = N° 55.—J U LY 1831. eZ *. WITH AN ENGRAVING Illustrative of Mr. Sturceon’s Experiments on the Thermo- Magnetism of Homogeneous Bodies. ReurYeehe ts. aan ls ee . BY : RICHARD TAYLOR, F.S.A. L.S. G.S. M, Astr. S. &c. : AND RICHARD PHILLIPS, F.R.S. L. & E. F.G.S. &c. y —— a ; , ? mA London : PRINTED BY AND FOR RICHARD TAYLOR, RED LION COURT, FLEET STREET, . Printer to the University of London. Sold by Longman, Rees, Orme, Brown, and Green; Baldwin and Cradock ; Cadell; Sherwood, Gilbert, and Piper; Simpkin and Marshall; Under- wood; and S. Highley, London :—and by Adam Black, Edinburgh ; Smith and Son, Glasgow: and Hodges and M‘Arthur, Dublin. FEY ACY AY ACY ACY » TO CORRESPONDENTS, We have to acknowledge the receipt of the following Communications, all which will meet with the earliest attention:—Mr. WaTERSTONE on a New Dynamico-Chemical Principle ; Mr. BLackwaut’s Examination of ; M. Virey'’s Observations on Aéronautic Spiders ; Mr. Nixon on the Horizon-Sector; and Mr. BROOKE’s Mineralogical Notices. D. T. will receive a private communication : his Notice on the Flight of Insects will be inserted in our next, Youne’s Elements of the Differential Calculus ; Part I. of the Transac- tions of the Natural History Society of Newcastle-upon-Tyne ; and Mr. Rewnie's Edition of Monracu’s Ornithological Dictionary, have been received for Review. The latter work will be reviewed in our next. *«* The Editors request that all Communications intended Sor immediate insertion may be sent to the care of Mr. Richard Taylor, Printing Office, fied Lion Court, Fleet Street, London, at furthest by the 15th day of the month, or they will be too late to appear in the ensuing Number. Sa pe ee —— a — Vou. 10. -AvGust 1831. No. 56. RUE AMEAMEAMEAMEAMEA MAMA NANCE Published the First Day of every Month.—Price 2s. 6d. : ) ublish ) PHILOSOPHICAL MAGAZINE by] 73 «alana Cans Ba ihe a ANNALS OF PHILOSOPHY: COMPREHENDING (S SINAN \ \\, \ Yat ae t » \) ir¥4) I A\| \, Gj ¥ nN ss THE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL (@§- 7 Sa r< eZ AND COMMERCE. ; badg >) —— (‘2 = — Pe NEW SERIES. on = S Acs Ne 56.—A U GUST 1831. On 4 S << >> 2. BY PHO 8 | K, S| RICHARD TAYLOR, F.S.A. L.S. G.S. M. Astr. S. &c. ot : . yee Etta 2 RICHARD PHILLIPS, F.R.S. L. & E. F.G.S. &c. > S en S (> SS (‘2 = London ; a “ PRINTED BY AND FOR RICHARD TAYLOR, RED LION COURT, FLEET STREET, res Printer to the University of London. a o Rees, Orme, Brown, and Green; Baldwin and Cradock ; (yj < Se es Ss ere ciltert, tie Piper; Simpkin and Marshall ; Under. Beat wood; and 8. Highley, London :—and by Adam Black, Edinburgh ; Smith = and Son, Glasgow: and Hodges and M‘Arthur, Dublin. YAS VARY WEY SUEY AE Y SUEY MEY EY ACY EY AE ( - TO CORRESPONDENTS. Recommendations similar to those constituting the Paper “Ona more eeconomical Application of Solar Heat,” have already frequently been made public.—We shall have much pleasure in receiving the Communi- cations offered by Mr. Henwoop.—The Review of Mr. Rennix’s Edition of Montacu’s Ornithological Dictionary is unavoidably postponed till — our next Number; in which we shall also notice Mr. Youne’s very elegant and perspicuous Treatise on the Differential Calculus. ——————————————————————————————___———————————sssss__ nnn: *,* The Editors request that all Communications intended for immediate insertion may be sent to the care of Mr. Richard Taylor, Printing Office, Red Lion Court, Fleet Street, London, at furthest by the 15th day of the month, or they will be too late to appear in the ensuing Number. GENERAL SCIENTIFIC MEETING AT YORK. f ise Council of the Yorkshire Philosophical Society having received intimation from men of scientific eminence in various parts of the kingdom, of a general wish that the friends of science should assemble at York during the ensuing autumn, we are directed to announce that the Society has offered the use of its apartments for the accommodation of the meeting, which will commence on the 26th of September, and that arrange- ments will be made for the personal convenience of those who may attend it. It will greatly facilitate these arrangements if all who purpose to come to the meeting would signify their intention as early as possible (by a letter, post-paid) to the Secretaries. WitLiAM Vernon Harcourt, Vice-President. Wo. Gray, Jun. Joun Puituirs, } Secretaries, Yorkshire Museum, York, July 22, 1831. } UME, MEANEAMEANEA MEA MEA ME lished the First Day of every Month.—Price 2s. 6d. THE + PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY: =| [HE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL AND FINE ARTS, AGRICULTURE, MANUFACTURES, ANG AND COMMERCE. NEW SERIES. Ne 57.—SEPTEMBER 1831. WITH A PLATE Illustrative of Mr. DanreLu’s New Register-Pyrometer. BY RICHARD TAYLOR, F.S.A. L.S. G.S. M. Astr. S. &e. AND RICHARD PHILLIPS, F.R.S. L. & E. F.G.S. &c. as London : PRINTED BY AND FOR RICHARD TAYLOR, RED LION COURT, FLEET STREET, Printer to the University of London. Sold by Longman, Rees, Orme, Brown, and Green; Baldwin and Cradock ; Cadell; Sherwood, Gilbert, and Piper; Simpkin and Marshall ; Under- wood; and S. Highley, London :—and by Adam Black, Edinburgh ; Smith and Son, Glasgow: and Hodges and M‘Arthur, Dublin. NEY EY AE YAY AH Y He Y HEY SHE Vot. 10. SEPTEMBER 1831. No. 57. TMERESESESESESES ENE ENE Ee TO CORRESPONDENTS. Communications have been received from StmpLex, Mr. Nixon, and Mr. Henwoop, all which will meet with the earliest attention. Mr.Waterstonr’s Letter did not reach us until his Paper was printed; it shall be inserted in our next, if agreeable to his wish. We have to thank Dr. ScuwE1GGER-SEIDEL for the Numbers for the present year of his Neues Jahrbuch der Chemie und Physik. A Review of Mr. Youne’s Elements of the Differential Calculus ; and the first portion of a detailed Critical Examination of Mr, Renniz’s Introduction and “Plan of Study” &c. prefixed to his new Edition of Montagu’s Ornithological Dictionary, have been prepared: but an accu- mulation of Papers, &c. requiring immediate insertion, have obliged us, though with reluctance, to postpone them till our next. GENERAL SCIENTIFIC MEETING AT YORK. A hare Council of the Yorkshire Philosophical Society having received intimation from men of scientific eminence in various parts of the kingdom, of a general wish that the friends of science should assemble at York during the ensuing autumn, we are directed to announce that the Society has offered the use of its apartments for the accommodation of the meeting, which will commence on the 26th of September, and that arrange- ments will be made for the personal convenience of those who may attend it. It will greatly facilitate these arrangements if all who purpose to come to the meeting would signify their intention as early as possible (by a letter, post-paid) to the Secretaries. WiLL1AM VERNON Harcourt, Vice-President. Wo. Gray, Jun. Joun PuILuips, Yorkshire Museum, York, July 22, 1831. \ Secretaries. On the First of September will be Published, Price Nine Shillings in Cloth, LEMENTS OF THE INTEGRAL CALCULUS; with its Ap- plications to Geometry, and to the Summation of Infinite Series, &c, By J, R. YOUNG. Published by J. Souter, School Library, 73 St. Paul’s Churchyard. Of whom may be had, lately published, by the same Author, 2. The ELEMENTS of the DIFFERENTIAL CALCULUS; comprehending the General Theory of Curve Surfaces and of Curves of Double Curvature, in which are pointed out and corrected several important Errors that have hitherto remained unnoticed in the Works of Lacrancr, Lacrorx, &c. 7s. in cloth, 3. An ELEMENTARY TREATISE ON ALGEBRA, ‘Theoretical and Prae- tical; with attempts to simplify some of the more difficult parts of the Sciences, par- ticularly the Demonstration of the Binomial Theorem, in its most general form; the Solution of Equations of the higher orders; the Summation of Infinite Series, &c. 8yo, boards. 10s. 6d. 4. An ELEMENTARY TREATISE on the COMPUTATION of LOGA- RITHMS;; intended as a Supplement to the various Books on Aigebra. 12mo. 2s, 6d. 5. ELEMENTS OF GEOMETRY; containing a New and Universal Treatise on the Doctrine of Proportions, together with Notes, in which are pointed out and cor- rected several important Errors that haye hitherto remained unnoticed in the writings of Geometers. 8vo, 8s. 6. The ELEMENTS OF ANALYTICAL GEOMETRY; comprehending the Doctrine of the Conic Sections, and the general Theory of Curves and Surfaces of the second order, with a variety of local Problems on Lines and Surfaces. Intended for the use of Mathematical Students in Schools and Universities. 7s. cloth. * If works like the present be introduced generally into our schools and colleges, the Continent will not long boast of its immense superiority over the country of Newton, in eyery branch of modern analytical science,”—The Atlas, July 25, 1830. ae ee eee ee ye Ay - » Vot. 10. OcToBeER 1831. No. 58. wy MEK k eS) plished the First Day a every Month—Price Qs. 6d. Ne =) THE eS PHILOSOPHICAL MAGAZINES z AND i ANNALS OF PHILOSOPHY: EANEANEANG x aS GANGAN A MEAMEAMEAMEAMEAMEANEANEANEAR THE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL a AND FINE ARTS, AGRICULTURE, MANUFACTURES, . AND COMMERCE. NEW SERIES. N° 58.—OC TOBER 1831. BY RICHARD TAYLOR, F.S.A. L.S. G.S. M. Astr. S. &e. AND RICHARD PHILLIPS, F.R.S. L. &E. F.G.S. &c. London : PRINTED BY AND FOR RICHARD TAYLOR, RED LION COURT, FLEET STREET, Printer to the University of London. Sold by Longman, Rees, Orme, Brown, and Green; Baldwin and Cradock ; Cadell; Sherwood, Gilbert, and Pie Simpkin and Marshall; and §. Highley, London:—and by Adam Black, Edinburgh ; Smith and Son, Glasgow :—and Hodges and M‘Arthur, Dublin :—and by G. G. Bennis, at the Library and News Rooms, 55 Rue neuve St. Augustin, Paris. LANEY ICN AMV AWE YAY ACY TAC ACY AY HEYA TO CORRESPONDENTS. We have to thank Dr. Henry for his interesting communication ; and we shall be happy to receive the additions to it which he has promised. Mr. Henwoop’s Notice of his Geological Survey of the Mines of Cornwall will be inserted in our next ; in which also we shall endeavour to insert, if possible, Mr. Hawortu’s thirteenth Decade of New Succu- Jent Plants. Communications have also been received from Mr. Merk te, the Rev. P. Keiru, and Simpcex. We intend taking the first opportunity of inserting the account of Dr. Pearson’s “ Introduction to Practical Astronomy.” It is our intention at the end of the present volume, to publish a Sup- plementary Number, containing a General Methodical Index to the first ten volumes of the New Series of the Philosophical Magazine and Annals of Philosophy. *,* The Editors request that all Communications intended for immediate insertion may be sent to the care of Mr. Richard Taylor, Printing Office, Red Lion Court, Fleet Street, London, at furthest by the 15th day of the month, or they will be too late to appear in the ensuing Number. This Day is Published, A LETTER to Dr. DAVID BOSWELL REID, Experimental As- sistant to Dr. Horr, &c.; in answer to his Pamphlet. entitled ‘An Exposure of the Misrepresentations in the Philosophical Magazine and Annals,” &c. By RICHARD PHILLIPS, F.R.S. L.& E., &c. Samuel Highley, 174 Fleet Street.—Price 1s. ee . 7 Vot. 10. NovemBeER 1831. No. 59. MGAMEAMEAMEAMEAMEAMEAMEAMEA ME) WANS Published the First Day of every Month.—Price 2s. 6d. i) | THE PHILOSOPHICAL MAGAZINE} WG} ihe I Vi; < AND i) ANNALS OF PHILOSOPHY: = COMPREHENDING Ss THE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL AND FINE ARTS, AGRICULTURE, MANUFACTURES, AND COMMERCE. ea ee ON ean NEW SERIES. No 59.-N OV EMBER 1831. HN AACY ACY ALY AY AE YAR Y ACY AN ee EN ary SETS i BY. RICHARD TAYLOR, F.S.A. L.S. G.S. M. Astr. S. &c. AND : RICHARD PHILLIPS, F.R.S. L. & E. F.G.S. &c, Y, ca i i GANGA €/\5 at London : PRINTED BY AND FOR RICHARD TAYLOR, RED LION COURT, FLEET STREET, Printer to the University of London, Sold by Longman, Rees Orme, Brown, and Green; Baldwin and Cradock ; “Cadell bs) nerwood, Gilbert, and fg st Simpkin and Marshall ; and §. Highley, London :—and by Adam Black, Edinburgh ; Smith and Son, Glasgow :—and Hodges and M‘Arthur, Dublin :—and by G. G. Bennis, at ews Rooms, 55 Rue neuve St. Augustin, Paris. / f 4 Y At‘ TO CORRESPONDENTS, The Rey. P, Kz1rn’s Paper “ On the Susceptibilities of Living Struc- tures,” is intended for early insertion. SIMPLEx in our next. It is our intention at the end of the present volume, to publish a Sup- plementary Number, containing a General Analytical Index to the first ten volumes of the New Series of the Philosophical Magazine and Annals of Philosophy. *,* The Editors request that all Communications intended for immediate insertion may be sent to the care of Mr. Richard Taylor, Printing Office, Red Lion Court, Fleet Street, London, at furthest by the 15th day of the month, or they will be too late to appear in the ensuing Number. Just published, in Royal Octavo, Price 10s., or, on Coloured Paper, Price 12s. (Second Edition.) ABLE OF LOGARITHMS OF THE NATURAL NUMBERS from 1 to 108,000. $ By CHARLES BABBAGE, Esq. Lucasian Professor of Mathematics in the University of Cambridge, F.R.S. &c. &c. Printed for B, Fellowes, Ludgate-street ; of whom may be had, by the same Author, REFLECTIONS on THE DecLiINE oF SCIENCE IN ENGLAND. 8yo, Price 7s. 6d. A CompaRATive View oF THE DIFFERENT INSTITUTIONS FOR THE AssuRANCE or Lives. 8vo. Price 10s. 6d. Also, TaBLes oF Locaritumic Sines, Co-sines, TANGENTS, AND Co- TANGENTS, to accompany Mr. Babbage’s TasLE or LoGARITHMS. Royal Octavo. Price 12s. Just published, Price 1s. A SYLLABUS OF A COURSE OF EXPERIMENTAL LEC- ‘™ TURES ON THE THEORY OF EQUILIBRIUM, to be de- livered at King’s College, London, in the October Term of the Year 1831, By the Rev. H. MOSELEY, Professor of Natural and Experimental Philosophy. Printed for B. Fellowes, (Bookseller and Publisher to the College, ) 39 Ludgate-street. Published the First Day every ‘“Month.—Price Qs. 6d. 2 THE PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY: THE VARIOUS BRANCHES OF SCIENCE, THE LIBERAL { AND FINE ARTS, AGRICULTURE, MANUFACTURES, AND COMMERCE. en NEW SERIES. Ne 60.—-D ECE MBER 1831. fe ae Ts Pat TER Ee ne BY RICHARD TAYLOR, F.S.A. LS. G.S. Astr. S. &c. AND RICHARD PHILLIPS, F.R.S.L. & E. F.G.S. &c. Lonvon ; RED LION COURT, FLEET STREET, Printer to the University of London. PRINTED BY AND FOR RICHARD TAYLOR, Sold by Longman, Rees, Orme, Brown, and §. Highley, London :—and by Adam Black, Edinburgh ; Smith and Son, Glasgow :—and Hodges and M‘Arthur, Dublin :—and by G. G. Bennis, at 55 Rue neuve St, Augustin, Paris. LAY CY AY AAC Y AE GV AY AE VARY Green; Baldwin and Cradock ; Cadell; Sherwood, Gilbert, and net Simpkin and Marshall ; and | Gx \, a LGN AY AY aM AIX \ TO CORRESPONDENTS. The Rev. B. Powett’s Paper on the Interference of Light will be inserted in our next. A paper on a new Anemometer has been received ; and also Commu- nications from Mr. Merxriz, Mr. S. SHarrre, Mr. BLackwAa.u, the Roya. GeoLocicAt Society oF CoRNWALL, and the Betrast Na- TURAL History Society, all which will meet with speedy attention. Mr. Fearn’s Works on Cerebral Vision and Color Images in the. Brain, have been received for review. Anxious to render the GENERAL ANALYTICAL INDEX to the first — ten volumes of our New Series as complete an analysis as possible of the contents of the work, the care and attention requisite for that pur- pose will, we find, prevent its being ready until the 1st of February next, when it will be published as an additional Number of the Phil. Mag. and Annals. This supersedes the necessity of occupying any of the pages of the present Number with a separate Index to Volume X. with which the General Index will be arranged to bind. SimPLEx is unavoidably deferred till our next Number. WESTERN LITERARY and SCIENTIFIC INSTITUTION, 47 LEIcESTER SQUARE. O* Thursday, December 8th, Mr. E. W. BRAYLEY, Jun. A.L.S., will commence a Course of Lectures on the PHENOMENA AND History oF Ienzous Meteors anp METEORITES. MATHEMATICAL AND PHILOSOPHICAL BOOKS. S. MAYNARD, Bookseller, 91, Crown-Court, Dorset- Street, Fleet-Street, gE Si leave to inform the Nobility and Gentry, that he has constantly on Sale a valuable Collection of scarce Mathematical and Philoso- phical Books, both English and Foreign, at very moderate prices. Catalogues may be had, gratis, upon application as above. As S. M. devotes the chief part of his attention to the procuring of scarce and valuable Books in the above Sciences, he trusts that if honoured with the Orders of scientific Gentlemen, he shall be able to execute them with entire satisfaction. THE POLYTECHNIC LIBRARY. The Second Volume of this Work, containing 360 pages of Letter-press, and 35 Wood-cuts, Price 4s. in Cloth, will be published on the Ist of December, viz. HE DOMESTIC CHEMIST; comprising Instructions for the Dr- _* TeEcTion of ADULTERATIONS in nearly three hundred of the most important Preparations employed in Domestic (Economy, Medicine, and the Arts. To which are subjoined, the Art of DetecTine Porsons in Food and Organic Mixtures, and a Popular Introduction to the Principles of CHEMICAL ANALYsIS. Printed for Bumpus and Griffin, $ Skinner Street, London; and Richard Griffin & Co., Glasgow, THE PHILOSOPHICAL MAGAZINE, OR ANNALS OF CHEMISTRY, MATHEMATICS, ASTRONOMY, NATURAL HISTORY, AND GENERAL SCIENCE. BY RICHARD TAYLOR, Fellow of the Society of Antiquaries, and of the Linnean, Geological, Royal Astronomical, Royal Asiatic, and Royal Geographical Societies ; Hon. Memb. of the Nat. Hist. Society of Moscow ; AND RICHARD PHILLIPS, Fellow of the Royal Societies of London and Edinburgh, of the Geological Society of London, &c. &c. “Nec aranearum sane textus ideo melior quia ex se fila gignunt, nec noster vilior quia ex alienis libamus ut apes.” Just. Lirs. Monit. Polit. lib.i. cap. 1. VOL. X. NEW AND UNITED SERIES OF THE PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY. JULY—DECEMBER, 1831. LONDON: PRINTED BY RICHARD TAYLOR, RED LION COURT, FLEET STREET, Printer to the University of London. SOILD BY LONGMAN, REES, ORME, BROWN, AND GREEN; CADELL; BALDWIN AND CRADOCKS SHERWOOD, GILBERT, AND PIPER; SIMPKIN AND MARSHALL; AND §S, HIGHLEY, LONDON‘i—~BY ADAM BLACK, EDINBURGH 5 SMITH AND SON, GLASGOW ; HODGES AND M‘ARTHUR, DUBLIN; AND G, G. BENNIS, PARIS, TABLE OF CONTENTS. NUMBER LV.—JULY. Page Mr. W. Sturgeon on the Thermo-Magnetism of Homogeneous Bodies; with illustrative Experiments (continued)........ Mr. J. E. Drinkwater on Simple Elimination .............. Prof. Encke on the Solar Eclipses and Transit of Mercury over the Sun’s Disc in 1832............ 2+ eeeeee ee ceee corres Rev. P. Keith on the Conditions of Life (continued) Proceedings of the Royal Society ........---.+eeeee- eure —— Geological Society... 0 5.0. 00004. ee Astronomical: Societys: 2)... 206.0505. Zoological Society -.........+2..+5+- at the Friday-Evening Meetings of the Royal Institution of Great Britain ..........00..0.--ceeee eee Dr. Forster’s Account of an Aérial Voyage made in a Balloon on Saturday the 30th of April 1831 MANN. PCE) a siete Se nin ibte = mie in ain Scientist ay eloyerec nad shana Occultations of Planets and fixed Stars by the Moon, in July 1831. Computed for Greenwich, by T. Henderson, Esq. ; and circulated by the Astronomical Society.............. Dr. Burney’s Results of a Meteorological Journal for 1830, kept at the Observatory of the Royal Academy, Gosport, PUB SRS Chain b elRcts plete eh eleierel nim helm ote Mint aie sie ga 'ee Mr. Giddy’s Extract from the Meteorological Journal kept at ROUZADCE 555 «cis 5 ite =ainrtelern'e * Sle oil ois foie asa (ales fetter ope ete teag ote Meteorological Observations. ......... ce.ss-seeseeeccees Meteorological Observations made by Mr. Thompson at the Garden of the Horticultural Society at Chiswick, near London; by Mr. Giddy at Penzance, Dr. Burney at Gosport, and Mr. Veall at Boston eevee reer ee ee ee ee es ee ee ee NUMBER LVI.—AUGUST. Mr. J. W. Lubbock on some Problems in Analytical Geometry. Mr. J. Nixon’s Particulars of the Measurement, by various Methods, of the instrumental Error of the Horizon-Sector described in Phil. Mag. vol. lix. (continued) ........++++- Mr. W. J. Henwood’s Notes on some recent Improvements of the Steam-Engines in Cornwall.........-0.++eeseseeeee Mr. J. Prideaux on Chemical Symbols and Notation ; in Reply to Professor Whewell Vinssus O12 019 0:09.05 00 EDO MOE » DBO 4 6 010.8 1 80 iv CONTENTS. Page Mr. H. J. Brooke on Poonahlite, a new Species of Mineral; on the Identity of Zeagonite and Phillipsite, &c.; and other MGIiepePIINDICES tiles ie aes ao ss Wath eatir asia 3 109 Rev. H. Coddington on the Theories of Achromatization, &c. RRC COP IDEs) GTI cde sas csa'e x craic » -'ss' se eiores 112 Mr. W. Sturgeon on the Thermo-Magnetism of Homogeneous Bodies; with illustrative Experiments.................- 116 Rev. P. Keith on the Conditions of Life............ . 124 Mr. G, Innes on the Statement in the Nautical Almanac for 1833, of the Time of Beginning of the Solar Eclipse of the 16th of July in that Year ; together with the correct Times of that Eclipse, computed for Greenwich............ ... 135 Errata in Schumacher’s Ephemeris of the Distances of the four Planets Venus, Mars, Jupiter, and Saturn, from the Moon’s Centre, &c., for 1833, published by the Admiralty.. 136 Mr. S. Sharpe on the Theory of Differences .............. 137 Prof. Airy’s New Optical Experiments.............0000005 141 Proceedings of the Geological Society .................- 143 ——_——-_—————- Zoological Society .................. 145 General Scientific Meeting at York—On the Rapid Flight of Tnseataied: pnd isin.’ picts’ Late ie) 8a, I Sittin ¢ PSEC 150 Process for preparing Hydrocyanic Acid—Vanadium, a New Br etaL oh six ron BE ee enc Aten PAC Pree A be, 151 Magnesium........ pha. tieisin, AAs lei eo. ae 152 IM: Gay-Hussacion:Oxalic Aeiditying.cv work. aia) A 153 M. H. Braconnot on Gallic and Pyrogallic Acid...... ..... 154 Mr. J. Hemming’s Analysis of Tennantite—New Patents .... 157 Occultations of Planets and Fixed Stars by the Moon, in August 1831. Computed for Greenwich, by T. Henderson, Esq.; and circulated by the Astronomical Society—Meteorological ROUELY BENING coals) 3 5) 4.5 a= 5 ms oats Daca hh lel aa 158 NUMBER LVII.—SEPTEMBER. Mr. 1. J. Brooke on Isomorphism., ..5.;.. 05.24% 25. denchiaes 161 Mr. J. J. Waterstone’s Exposition of a New Dynamico-Chemical BAMMNCLLE e tw acche thy Wythe nad hie salt aieichcsote Reve Dolla toe e ere 170 Mr. J. Blackwall’s Examination of M. Virey’s Observations on Aéronautic Spiders, published in the Bulletin des Sciences ORS Te Ee a alo aati PR LIRE 180 Mr. H. J. Brooke on Mengite, a new Species of Mineral; on the Characters of Aeschenite ; on Sarcolite, as distinct from Anal- cime and Gmelinite; with other Mineralogical Notices..... 187 Mr. J. F. Daniell on a New Register-Pyrometer, for Measuring the Expansions of Solids, and determining the higher De- grees of Temperature upon the common Thermometric Redle: (commnucd)'s, cia mae spies os + cos Bcos > cos (A—/); then the actual entrance of %’s centre on the ©’s dise will take place at the apparent time of the place of observation : May 4. 19> 54/ 6! 4+ 1— 118'"6 cos § lor 30 Professor Encke on the Solar Eclipses For the termination of the transit put NW = 229° 15) =B! = + 2° 56'0; and calculate cos ¢' = sin 6! sin ¢ + cos f! cos > cos (A'—I); and %’s centre will leave the ©’s disc ic May 5. 25 42! 55” + 2+ 118'"8 cos ¢ apparent time of the place of observation. The contacts of the limbs will respectively take place about 1’ 33’ sooner or later. For Berlin, where o = 52°31"'2, 1=31° 3!5, we find cos = +0°3873 cos = —0°5375 3’s centre enters on x. atc, § 21257! 34" § App. time of ==) == .leayes the ©’s disc 446 5 Berlin. The entrance on the ©’s disc takes place 32° eastward, the parting from the ©’s disc 87° westward, of the northernmost point of the ©’s disc. The duration of the transit of each second in arc of §’s diameter over the ©’s disc is = 17'3 in time. Solar Eclipse, July 27, 1832. App. time of Berlin. Beginning on the earth in general......seeccesseersereee OF 11’ in 294° 29’ east longitude from Ferro. 10 59 north latitude. Beginning of the total eclipse on the earth........... 1 6 in 280° 5/ east longitude from Ferro. 12 53 north latitude. Total eclipse at NOON .....scescsssssscscseccccscssssescesece 2 AT in 349° 23’ east longitude from Ferro. 24 34°5 north latitude. End of the total eclipse on the earth......ssccsseereeeee 4 31 in 54°24! east longitude from Ferro. 2 47 south latitude. End of the eclipse on the earth in general......0. 5 26 - in 38°11’ east longitude from Ferro. 4 23 south latitude. The eastern limit of visibility of this eclipse runs through Europe, from the north coast of Ireland above Greenwich, along the boundary of Germany and France, to the coast of Dalmatia. To a country to the westward it will be visible ; in Germany it will not be visible. The western limit em- braces the greatest part of North America and a great oe a out and Transit of Mercury in 1882. 31 South America. Almost all Africa may see it; but only the west coast of Asia. For calculating the beginning and end of the eclipse for places in Europe the following formulze may be made use of: Let the longitude of a place from Berlin = / (negative if west), the corrected latitude = ¢, and let the following values be calculated : wu = 1°8816 cos ¢ sin (45° + 2) v = 1'7773 sin ¢ — 0°6177 Cos ¢ cos (45° + 7) au! = 0°4926 cos @ cos(45° + 2) wv = 01617 cos > sin (45° + 2) m sin M = + 0:2404 — u m cos M = + 071431 —v nm sin N = + 1:0862 — w/ ncosN = + 01554 —v/ m sin(M—N) = cost, where ) must always be taken positive and less than 180°. The time of beginning and termination of the eclipse will then respectively be : sin h sh —N) = 3h 41 7, 00s (M N) + ia apparent time of the place of observation expressed in hours and parts of an hour; the upper sign referring to the begin- ning, the lower to the termination of the eclipse. The angles which, at those two moments the respective radius of the sun’s disc at the point of contact forms with the horary circle of the sun’s centre, counted from north through east to 360°, will be respectively iQ=90°+ N+, and the magnitude of the eclipse in inches will be = 25.sin3*. Elements of Solar Eclipses. Apparent time of Berlin. February 1. July 27. ® V1» 9f 25's) 2849! 2"7 Longitude of ( and ©.......00064/912° 8! 45!2/124°26! 47!""5 Horary motion of ¢ in longitude 30 24 °8 87 51 ‘1 SG gees sas 2 32-2 2 235 f, OP ccseicaspectsssthatseesel tO). 1 Of D|+0. & Sao Horary motion of «( in latitude |— 2 49°1/+ 3 30°5 TB PAVAMEME DT faskeesees | Sha v or | 6 {Fe #2 | | 6 [1 | € [Fo |S ffs | Sreniqay § 013-2 vee trl9 |§ Piloie lr ©) @ [Ror Arenuve S i 4 >| a 4 S$ a | a Q fo) fo} alE| EIS) lol £ oo) fe Elala @l Fz B) 2) |Z! |e! |Z we S ols] SIEIR/ERISIBIOLI Els] a) alel 4] 2) 2/2) 2/2) alyez ele] ele)! sl 2lz Sal Ble ele igieee eels) s | eISl21e12 1212/8 |S sl lel Elel Fle] S/S] ote S| a | eS eels Si aiBelScy? 8) w/e] & ST) 21E |e] 8 | 38) 1" 8) Sis) Ss) Filo] ©) Se OF Ss Poe sie 2 zleleisiPiey sisi“| go | 21 Bpe | 8] e = | Es) * 313 S e| |e Ss g am tig "19/218 a\° rl] oie = abl ieee > a os 3 z 2|\+ Re ete a g She Spel Fe 5 & Srl sees = Lv) oO S e e ‘vusuiouxyg dieydsouny ‘spno[g Jo suoNeoyTpoyy “SPUTAA et} JO aTeIg ‘(penunuos) ATV ANNUAL N. S. Vol. 10. No. 55. July 1831. 74 Meteorological Summary for 1830.—Hampshire. ANNUAL RESULTS FOR 1830. Barometer. Inches. Greatest pressure of the atmosphere, March 26. Wind N. W. 30-620 Least ditto ditto January 20. Wind E. 28-600 Hapge-of the quicksilver- vc 6. = rye. cok lov oy be oe ck Bek 2-020 Annual! mean pressure of the atmosphere .........+..... 29-918 Mean pressure for 175 days with the moon in North decl. 929-930 for 179 days with the moon in South decl. 29-951 Annual mean pressure at 8 o’clock A.M. .............. 29-917 at’ DO; CLOCK Tee Mn temas Bete arch 29-919 ah OS COC ae eer eis Se a 29°920 Greatest range of the quicksilver in January............ 1-990 Least range of ditto in October: >see Sens} 0°750 Greatest annual,variation in 24 hours in January ........ 1°050 Least of the greatest variations in 24 hours in May ...... 0-330 Aggregate of the spaces described by the rising and falling GP the quite ks W yer. Se orw-aais wea cw eter vee -wrereier th eee 72'330 INGER GN CUANDO ss ne wens Stoke vel rele uN hoe Eke. Sate ae 234 Six’s Thermometer. Degrees Greatest thermometrical heat, July 29. Wind E.......... 84 ee cold, February 2. Wind N.E..... 13 Range of the thermometer between the extremes ........ ia Annual mean temperature of the external air........... 49°80 ee at 8: ALM. .% 2 48°33 —_—_—- ————- at 8 P.M..... 48°85 Oe I eee at2 P.M, .... 5409 Greatest range in Pourmary so). a... - cee ene fee aoe 40:00 Least of the greatest monthly ranges in September....... 24:00 Arnal Mea TAREE: he jane ee pee Argan eicistre cissverein’ «'bi «fs 42 === ast LO MSO AeAStr aw. Lal vor eicieiace cla tute =) SOUP CAS PLO OULD pele had cite caialien Pelei soso 42 as\-> Sonthtomsouti-West a.) niaciesee ceté chess 16 === Sonthemesu to, WES. 2. 2. eects) ccarele 965 a2 = - WEEE OR NOEL AWESL co. aman ole ond oes 575 — i NOTteNVERS LO. NOLEDis 5,60. Se eehy oe serie « 52 365 Clouds, agreeably to the Nomenclature, or the Number of Days on which each Modification has appeared. Days: Days CIDTUS ro 40 1. es 234 Onorulusges oss. 209 Cirrocumulus.. 119 Cumulostratus... 217 Cirrostratus... 333 NIM DESIR Ai, Oerercte 199 Stratis... « HP nage: General State of the Weather. Days. A transparent atmosphere without clouds... .. 49 Fair, with various modifications of clouds..... 1572 An overcast sky without rain............... 965 ye SLPS SO Ae ote ati min wie a alate tele 5 Rainy haily-and-snow soi 2 wre Seater sselave steerer 57 365 Atmospheric Phenomena. No. Anthelia, or mock-suns opposite to the true sun 2 Parhelia, or mock-suns on the sides ofthetrue sun 14 Paraselenz, or mock-moons...........2-+e+ 6 DIAN URLOS Recs serrata sa rcisie tee exe. ° aputicse oats ee MEIGS ahr ct en eae eens eoske, aa cg cco s.s 21 Rainbows......... Pa ESTO I TT 14 eens teenies sere, eee ent 8 90 PENIEE TE! OOTEMIER fe. Ate oot eGtare ole wines < * ple ly Lightning, days on which it happened...... pats 4 Thunder, ditto Ni Waa ge gas lea laa 5 Evaporation. Inches. Greatest monthly quantity in May.........- 4°80 Least monthly quantity in February........ 0°72 Total amount for the year....... Sete atels. wore. 28°60 Rain. Greatest monthly depth in November......--- 4695 Least monthly depth in October..........+-- 0°595 Total amount for the year, near the ground,... 28*350 The instruments with which the observations were made are the same as those in former years, with the exception, that instead of the horizontal thermometer, a Six’s thermometer has been used. L2 BAROME- 76 Meteorological Summary for 1830.— Hampshire. BAROMETRICAL PressuRE.—The mean pressure this year is +i, of an inch higher than the mean of the last fifteen years ; but the number of changes is less than in any year in that period. On the 19th of January a depression of 1:05 inch of mercury occurred, with a strong wind, first from South-east, and then from the North-east, accompanied with a heavy fall of snow. The mean of the pressures at 8, 2 and 8 o’clock coincides with the annual mean pressure. TremMPERATURE.—The mean temperature of the external air this year is lower than that of any year since 1816. The mean tem- perature of January and the first part of February was very low, and we have never registered so low a degree of temperature as that which occurred in the night of the 2nd of February. There is a difference of half a degree between the annual mean tempera- ture at 8 A.M. and 8 P.M., the latter being the highest. The annual mean temperature of spring-water this year is the lowest during the last ten years. Winps.—The duration of the South-west wind this year is un- precedented, being more than one-fourth of the period; the wind from the West is the next in duration; but that from the South has prevailed the least number of days. The North-east and South-east winds are equal in point of time. The number of strong gales of wind, or days on which they have prevailed this year, is as in the following scale: N. | N.E.| E. | S.E.| S. |S.W.| W. | N.W.| Gales. Ay | bos |. i 6 45 )| ASH 8) 4) 103 January was very cold and cloudy, with frequent falls of snow ; it having snowed more or less on fifteen days. February was rather dry and mostly frosty, with a cloudy atmo- sphere, and occasional gales of wind. The minimum temperature in the night of the 2nd was the lowest that had occurred the last fifteen years, March was fine, calm, and very dry, and a high pressure pre- vailed the latter part of the month, when the spring began to open. April commenced with a snow-storm for several hours, and was alternately fine and showery, with frequent strong gales. In the night of the 4th the frost was severe, and did much injury to the bloom of the trees in open situations. Vegetation was checked the first part of the period by the cold nights and hoar frosts; but the warm rains, followed by clear sunny days during the latter part, caused a rapid growth. May was dry and pleasant, with much warm sunshine till the 20th, when the air became arid and blighty, and the roads very dusty, insomuch that vegetation began to droop. The latter part of the month was showery, accompanied with strong gales. June was cold, showery and windy. The crops of grass, from the nature of the weather in the spring, were generally sat ut Annual Meteorological Results at Penzance. 77 but from a continuance of wet, much of the early cut grass was spoilt before it could be put in ricks sufficiently dry. July was also cold, showery, and windy till the 12th; but the latter part of the month was fine and dry, with four or five hot days and nights, which matured the wheat. August was fine and dry till the 8th, during which time much exertion was made by the agriculturists in securing the wheat crops. The remainder of the month was showery and windy ; and as scarcely any good opportunity occurred to get in the wheat in a dry state, much was lost out of the standing sheaves in the fields before it could be carried. September was wet and windy, which occasioned difficulties in getting in the barley and oat crops, both of which were abundant, and far superior in quality to those of several years past. The fruit crops were also abundant, but they were generally deficient in na- tural flavour, and mostly worm-eaten. October was very dry, calm, and fine, with a high atmospheric pressure. November was boisterous and wet, which caused floods in many places; but the air was mild for the season, with the exception of a few days. December was also wet and windy, and after the 10th, cold and frosty, with snow at intervals, and a low pressure. The frequency of aurore boreales in the autumn was remarkable: fair descriptions of their appearances may be seen under the monthly meteorological reports in this work. Extract from the Meteorological Journal kept at Penzance by Mr. Gippy. ANNUAL RESULTS. Register de rometer. 7 Barometer Thermometer. 3 3 Se 25 py 30°50 | 29:00 |29:970 | 48 | 23 | 37:0 30:20 | 29°45 |29°877 | 53 | 19 | 40:0 30°32 | 29.35 |30°018 | 61 | 39 | 48'8 30°10 | 29°20 |29°735 | 62 | 32 | 49°5 30°25 | 29°30 |29°814 | 65 | 42 | 54:5 30°10 | 29°30 |29°830 | 67 | 45 | 567 30°20 | 29°32 |29°895 | 76 | 49 | 60°5 30°25 | 29°40 |29°835 | 68 | 47 | 58:3 30°30 | 29°25 |29°805 | 64) 45] 55°4 30°40 } 29°82 |30:120 | 62 | 43 | 54:0 30°30 | 28°95 |29°730 | 58 | 39 | 49°5 30°40 | 28-60 |29-625 | 53 | 25 | 43:0 30°50 | 28-60 |29°8546) 76 | 19 | 50°6 |42°475/175 |190 1829 | 30°50 | 28°85 |29°8710) 71 | 19 | 50°4 |43:045 |182 183. NW. The rain-gauge is at the ground-level, and the dry days comprehend those days on which no fall whatever takes place,—not the slightest shower. METEORO- 78 Meteorological Observations for May 1831. METEOROLOGICAL OBSERVATIONS FOR MAY 1831. Gosport :—Numerical Results for the Month. Barom. Max. 30-303, May 9. Wind N.E.—Min. 29-478. May 1. Wind S. Range of the mercury 0-825. Mean barometrical pressure for the month ......... Shep secseeeeeee 29-920 Spaces described by the rising and falling of the mercury....... coves 4096 Greatest variation in 24 hours 0:286.—Number of changes 22. Therm. Max. 72°. May 25. Wind S.E.—Min. 35°. May 6. Wind N. Range 37°.—Mean temp. of exter. air 54°76. For 31 days with © in 6 52°85 Max. var. in 24 hours 20°:00.—Mean temp. of spring-water at 8 A.M. 49-60 De Luc’s Whalebone Hygrometer. Greatest humidity of the atmosphere, in the evening of the 29th.... 94° Greatest dryness of the atmosphere, in the afternoon of the 18th... 43 Fear gcse Miesete tate sacnecs crates ancsacaesssuccsanvesaasoneccesstaaane 51 Mean at 2 P.M. 57°-5.—Mean at 8 A.M. 62°-7,—Mean at 8 P.M. 68°5 of three observations each day at 8, 2, and 8 o’clock.......... 62:9 Evaporation for the month 6-35 inches. Rain in the pluviameter near the ground 2-07 inches. Prevailing winds, S.E. and N.E. Summary of the Weather. A clear sky, 53; fine, with various modifications of clouds, 1533; an over- cast sky without rain, 43; rain, 53.—Total 31 days. Clouds. Cirrus. Cirrocumulus. Cirrostratus. Stratus. Cumulus. Cumulostr. Nimbus. 25 10 25 0 22 15 13 Scale of the prevailing Winds, N. N.E. EeeSBe Se eS Wie Wick Nn Days. 33 8 4s 85 2) ay 1 1 31 General Observations—This month has been alternately wet and dry ; the dry period was from the 5th to the 19th, during which time no rain fell here, and the air was frequently arid with a North-east wind, accom- panied with a great evaporation. For several days upwards of three-tenths of an inch evaporated, and on the 18th, the day before the rain came on, half an inch in depth ascended from the evaporator, which clearly indicates the greater power of the air in eliciting heat, and carrying off so much moisture from near the surface of the earth immediately before the change from dryness to rain, and which was verified by the hygrometer’s, then pointing out the maximum dryness for the month. There were several hoar frosts in the first part of the month, when great blights prevailed, and their effects have since been made manifest by the trees being much thinned of their fruit. Comparatively speaking there were but a few warm days this month, and the mean temperature of the external air is about one degree under the mean of May for many years past. On the 5th, at three P.M. a heavy flash of lightning was experienced here, and was succeeded by a loud clap of thunder; distant thunder also frequently occurred in the morning of the 24th. At half-past ten o’clock in the night of the 30th, a few light corasca- tions ascended due North from an aurora borealis, which was low in the Northern horizon, and two meteors fell over it. This may be considered late in the spring for its appearance, as the evening twilight in that quarter is getting long, and being of a similar appearance to that of an aurora, it renders it imperceptible in the summer months, fail he Meteorological Observations for May 1831. 79 The planet Mercury was seen here with the naked eye in the fine even- ings, from the Ist to the 13th; and Venus was seen at ncon of the 16th, notwithstanding she is still in the superior part of her orbit. The atmospheric and meteoric phenomena that have come within our observations this month, are one solar and two Junar halos, two meteors, one rainbow, one aurora borealis, lightning and thunder on the 5th, distant thunder on the 24th, and four gales of wind, namely, two from the North- east, and two from the East. Occultation of Jupiter and his Satellites by the Moon.—The following were the apparent astronomical times here, on June the Ist, when the immersions and emersions of Jupiter and his Satellites occurred, with the exception of the 4th Satellite, the times of whose immersion and emersion are given by approximation. IMMERSIONS. EMERSIONS. The 4th Satellite at... 12"40748* | The 4th Satellite at ... 132497 6° The lst Satellite at... 12 57 50 | The lst Satelliteat ... 14 6 10 Jupiter’s western limb at 12 59 49 | Jupiter’s western limb 14 7 50 Jupiter’s centre at ..... 13 1 45 ) Jupiter’s centre at...... 14 9 47 Jupiter’s eastern limb at 13 3 42 | Jupiter’s eastern limbat 14 11 45 The 2nd Satellite at... 13 6 10 | The 2nd Satellite at... 14 12 25 The 3rd Satellite at... 13 10 41 | The 3rd Satellite at... 14 17 43 The occultation of Jupiter lasted 1 hour 8 minutes 3 seconds, From the motion of the Satellites the times of their occultations do not exactly agree with that of their primary. Jupiter was not so nicely dichotomized on the Moon’s enlightened limb as on her dark side: and after his emersion he appeared with an apparently enlarged disc, and shone more brilliantly than before his immersion, as well as his Satellites. REMARKS, London. — May 1. Cloudy: showers. 2. Heavy rain, with thunder. 3. Showers: fine at night. 4. Showers, with intervals of bright sun. 5. Fine in the morning: showers: clear and cold at night. 6. Fine: cloudy: clear at night, with severe frost for the advanced state of vegetation. 7, 8. Fine: frosty at nights. 9—13. Fine, but cold and very dry. 14. Fine: slight frost at night. 15,16. Fine. 17,18. Verydry. 19. Fine: rain at night. 20. Cloudy: heavy thunder shower in the afternoon. 21, 22. Over- cast. 23. Cloudy: thunder in the afternoon. 24. Fine: dull and hazy, with thunder at night. 25—28. Fine. 29. Wet. 30. Cloudy: fine. 31. Foggy in the morning: fine. Penzance.—May 1. Fine. 2,%.Clear: showers. 4,5, Fair: hail showers. 6—s. Fair. 9, 10. Clear. 11. Fair. 12, 13.Clear. 14, 15. Fair. 16. Clear. 17. Fair. 18. Clear: a shower. |19. Fair: rain. 20, Fair. 21. Clear. 22. Fair, 23. Fair: foggy. 24. Foggy: fair. 25. Fair. 26. Fair: rain at night. 27.Rain. 28, Fair: rain. 29. Rain. 30. Fair: rain. 31, Rain. Boston. — May 1.Fine. 2.Cloudy. 3.Rain. 4. Cloudy: rain a.m. andpv.m. 5.Fine:rain p.m. 6,7. Fine. 8.Cloudy. 9—12. Fine. 18—15. Cloudy. 16—19.Fine. 20, Cloudy: shower p.m. 21. Cloudy. 22.Fine. 23, Cloudy: rain, with thunder and lightning early a.m, 24, Fine. 25. Cloudy. 26, Fine. 27—30.Cloudy. 31, Fine. Meteoro- ce-9 G-FS| SE | aL | 9€ | 99 | gz | BL | PP-60 \RLP.6z |COE-0€ |_O£-6z | 0%-0F ZSF-62 |LEE-0F 96-0 |OL0-2 OPT-Z 18-% apm cod \goz. = | op. | a | a | as |‘an| L¢| 19 | €9 | $9 | 9G | OF | Lo | 75-62 |0L8.6z [226-62 | 18-6 | 8.60 |L68.62 [£86.60 jf vee foe [ogre [vee | e+ fumqeal «as |-as | «a | Lo} 6b | Fo | 6F | F9 | OF | 89 | SP-6z |016-62 |0£6-62 | 08.62 | 28.6% 66.60 [696.62 jof +++ 1OPP. zt: go. | «++ joxyea] -as | -as | as | S| €¢ | So | £9 | Fo | 6P | 99 | 29-62 |998-62 |L26.66 | 08-66 | 58-60 \S8L.66 |PS6-62 |6% s+ fotze o1z |‘ | tt fumeo] x | *s | “8 G19] €S | 19 | 39 | Fo | Os OL | 1-62 |006-62 |£66:62 | 08-66 | 08-6 |$26.6c |L86-6z |8% “+ loop. ood | °° | SP. juyeo| an | ‘as | ‘2 | PG) 1G | LS PS | LG | 6P | LO | 8h-6z |O8L-6z |06L-6z | 04-62 | SL-6z S8L.6z G8-63 |L ver | ove | eee Lea | ox | cas |-an| Lol] €¢| 99 | €¢ | €9 | 6P | aL | g-62 |SLL-6z |Lz8-6z | 9-66 | £2.62 6LL.6z |€F8-66/90 O wee face [eee [eee | ore [om | eas [eas [eax 9] 99 | 22 | #9 | 99 | Lh | SL | LS-62 |118-62 |298-62 | 01-66 | 08-60 0F8.62 |148-62 |S% Jogo. | | ot | ee | ee [tax] ‘Ss [MN] £9] SS | 69 | ZS | SO €S | gL | LE-6z |L08-62 |619:62 | 04-62 | 82-6 \1€8.6z |€£8-66 |PS wp. Pere [ttt | tet oz [van fems an] x | og] Lo | 69 | OF | 79 | PS | LL ZE-6% |L98-6z |L06-62 | 08-62 | 06.62 |S78.6z |000-0€ |€% vee fase fore fee loz. [om [ow [tan] x | 19] 99 | 89 | 6h | 09 | 0S | 69 | 09-62 666-62 |0€0-0€ | 00-0€ | 00.08 |796.6z |F00-0€ \Z% s+ logo. | | ot | Gt. foreo| *x [*mN | “| BS] €S | 99 | 0S | €9 | 1S | 69 | 17-6 L18-62 |LL6-62 | 06-62 | 00-0€ 916.62 |£66-62 |1% ve loop. {°° | U1 | ot. [mre] “as | “ms | “Ss | 09) 99 | Lo | 2S | G9 | 6P GL | 0£-62 |g6L-6z |898-6z | 09-62 | 08-62 Zh9.6z 9£8-6z 0% ++ 1960. |99: | oF | oz. | as] “| *38| "= | 09] SS | F9 | HS | LS | ES | 89 | CE-6z 199-62 |0€L-6z | $$-6% | 09.6% \00L.62 |SLL-6z |61 we fee [ee |e | ge, | ca | as] as] = [¢-19]| PS | So | 0S | 99 | ZS | OL | 25-62 /gh8.6z |910-0£ | $9.62 | $8.6 988-62 ££0-0€ jst C€ vee [ose [ore [eee | gp, fuea| va | ‘as | ‘& [¢-19| £9 | 29 | 6F | 9 | IP | PL | 09-62 |680-0€ |802-08 G6-6% | 00-08 |S11-0€ |Z1Z-0€ |L1 vee [vee log, [emu | cas] as] ‘NX | GCG] LP | 09 | €h | 19 | LE | EL | 29-62 OLI-0£ |70%-0€ | 00-0€ | 00.0€ |6E1-0€ |10Z-0€ |9T vee [ose [ere | eee | og, |umpeol +s | as} *s | og ab | SS | Ph | 09 | LE | £9 | 09-62 |€L0-0€ |880-0€ | 26-62 | 6-66 SZ0.0€ PLO-0€ |SI vee [ove fore | eee | Gg, fumqeol an | “as | x | Lp] 66 | 99 | sh | 9G | TE | LO | 09-6z |LL0.0€ |901-0€ 06-62 | 06-62 |€90.0€ |L60-0€ {PI vee fave [eee | eee | og, [urea] can | ‘AN | “ON |G.0G] EF | 09 | SP | G9 | OF | 99 | 05-62 |096-62 £20.08 06-62 | 06:62 676-62 \6S0-08 ET deel frvas” | "the | eee |. og, | Tak | tas | "HN | “BS | GS) SP) 09 tr | £9 | SE | Lo | 79-62 |0S0.0€ |EFI-0F | ZO0.0€ | S0-0€ |O10-0€ |LET-0€ OT e we fase [oe [ee | og. | ca | -an| “a | ‘a | Og] €b | 69] PP | 99 | CE | 19 | GL.6z |9ST-0€ |S6I-0€ | 00-0€ | 00-0€ |10Z.0£ Goz-0€ |11 gf | 9S'| 92-62 |LZ1-0€ |SP1-0€ | 96-62 | 00.08 |161-0€ |PEZ-0F OT 6€ | 6 | 06-62 |L1Z-0€ |COE-0F | OL-0€ | S1-0€ |P1z-0€ |LPE-0F 6 CE | 1G | Z8-6% |161-0€ |Z6Z-08 | 00-0£ | 0Z.0€ |SSz-0€ |FRz-0£ 8 ££ | SG | 96-66 |OF0-0€ |C1T-0€ | 06-62 | 06.6% Ch0-0€ |LSE.08 L 8% | 1G | 32-66 |9€8-62 |££6-6z | 98-62 | $8-62 PEL-6z |LP6.60 9 BE | 99 | 10-62 |€SS-62 |P89-62 | 09-62 | 99-6 PPS-6z Sz9.60 S DP 6€ | 99 | 20-6z |89S-6z |00L-6% | 09-62 | Z9-6z |89S-6z |L6S-62 7 g. |GLr. \S9% | or. | + mre, *m |"MN| “S | ZG) GE | 99 | EP | oS ss l¢o, | e+ | «s | tus} ‘N | 'S | oG| PH | 8S | OF | SS 0-0 |O£T- ge OFo. |SIT-0, t+ | o€.o|tTea| “ms | “MS } “Ms OG] OS | 19 | 6F | ZO | SP | Z9 | 90-62 929-62 |80L-6% | 09-62 | 09-62 |€S9-6z |[89-62 € w+ logo. [°° | ade | te futtvo| as] ‘BS | “| 0G) 29 | F9 | LP | 19 | LP | 19 | 1-62 606-6 |£09-62 | Sb-6z | 06-62 |9bS-62 609-62 | s+ Iocz.o] °°" |Po.0] *** fuatvol ms | ‘as | *s |G.g¢) 19 | 29 | 6b | 19 | OF | LO | 88:82 |8L7-60 966-62 | 0€-62 | SE-6% |ZSP-6 |PES-6 | LAPIN : tt pg UTA XV] UIT XPTA|ONIAL XVI yey FQ] “UN | XPT “UA | “XON | “UDN | “XBAM| . ere eis) Pl el el el ee rts as eat % So 3 Eb 3 4 | 8 a|za yaodsoy |‘a0uezuag} *UopuoT |Uo}sog qiodsoy aoueZzudg uopuo'T maHOH ¢ ti o jos td uley ‘deag purl *19}9UIOULIOY T, *oJaUIOILET ‘u0jsog JD TIFI4 “py pun Guodsoy qo AINUN “MCT ‘aouvzuag : THE PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY. ——. [NEW SERIES. ]} AUGUST 1831. VII. On some Problems in Analytical Geometry. By J. W. Lussock, Esq. V.P. § Treas. R.S.* Lt the equation to any curve surface of the second order be Ar +Cy?+Ke+ Bry+ Lzy+ Mrz+ Du+ Ey+ Nz4+F=0, (F (Xs Ys z) = 0) the coordinate axes x, y, x being inclined to each other at any angle, and let ¢ be the distance of any point (#, 8, y) from (x,y %), (25%, =) being situated on the curve surface. ge? = (w—a)? + (y—B)* + (zy)? + 2(c—a) (y—B) cosxy + 2 (y—B) (zy) coszy + 2(z—y) (w@—a) cosxz (1 If Q is a Maximum or minimum and A is some indeterminate quantity, a{2de+ By+ Ms+ D}\ =2-a+(y—f)costy+(z—y) cosrx (2) af{2Cy+ Br+ Lz +E} =y-B+ (e—«) cosry+(z-y) cosey (3) a{2K24+Ly+Me+ N} =2-y+(e—«) coszxr+(y—P) coszy (4) Eliminating 4, {2Ar+ By+Mz + Di {y—B + (t—2) cosay + (z—y) cos zy} ={2Cy+Be+ Le+ E} {e—a + (y—f) cosry +(2—y) cosrs} (5) {2 Cy+Bea+Let+ E}{ s—y + («—«) cos za + (y—f) coszy} ={2k2+ Ly+Mr+N}{ y—B + (e—«) cosy + (s—y) coszy} (6) which are the equations to curve surfaces whose intersections determine the points from which the normals can be drawn from the point «, 8, y to the curve F' (2, y, 2). * Communicated by the Author, N.S. Vol. 10. No, 56. Aug. 1831. M Let 82 Mr. Lubbock on some Problems in Analytical Geometry. Let D=0, E= 0, N= 0; then multiplying equations (2) (3) and (4) first by x, y and z respectively, then by e—a, y—B and z—y respectively, and then by «, 8, y respectively, and adding together the results, # being the distance of the point a, B, y from the centre, and r the distance of the point in which the normal cuts the curve surface, from the centre, ra=r+yt+ 24+ 2xry cosxry+2zycoszy + 2ercossx R= 248 +7°+ 2aPcosry+2yBcoszy+2yacoszx » is therefore evidently independent of the direction of the axes X, ¥/, 2 Eliminating 2, y, z from the equations A{2Ax+ By + Mz} =x2+ ycosxy +2 cos xz A{2Cy+ Bat+ Lz} =y+xrcosry + zcoszy a{2Kz+Ly+ Mr} =2+4+ rcoszx + ycoszy which obtain upon the supposition that a, 6, y = 0, in which 72 Casey A "a. 2F 7? 4k#C4+4404+44K4+2°4+ B24 —2F*) —2BLcoszr—2BMcoszy —2ML cosyr pr 8AKC —2 AL2—-2K B’—-2CM*? —2MLB —cos xx cos xy) —2 M (cos xr— cos ry cos xy) 8AKC—2AL? —2K B-2CIM-2MLB 2Csin?sxr+2 Ksin2ry +2 sin?zy 44 F: —2L (cos zy—cos xx cos vy)— 2 B (cos ry a —8 F3) 1— cos? zy — cos?ry — cos*ze+ 2cos xx cosry cosz 1 y y ycoszy} _ G4 8AKC—2AL2?—-2K B2—2CM*—2MLB rg If m,n, p are the principal axes of the surface, the coefficient of * = m? +n? + p? of 7? = mp? + m?n? + n2p? and the quantity independent of 7 = m? n° p* because m?, n*, p are evidently the roots of the equation. If the curve surface be referred to conjugate axes m’, n!, p’ so that 3 Az=m' pl, C = m?n?, K = m?n? B=0, L=0, M= 0, F=—\n? nip? re a (m’? i nie 4 p) rs +(p? rn? sin? yz + p? m” sin? z 2 + mn? sin? x y) 1° —m! n! pl? (1 —cos? zy—cos” © y—cos® 227 +2 cos zx cos xy cos zy) = 0. Whence Mr. Lubbock on some Problems in Analytical Geometry. 83 Whence m'? + n? + p® = m® + n° + p pin? sin?y + p? m2 sin? zx + mn! sin * xy =pnr+pm + m? n? m!? nip? (1 —cos? zy—cos® xy —Cos*2 x +2 COs 2x COS TY COS zy) = mn? p® which are the known properties of the conjugate diameters ; the first and third of these theorems appear to have been first proved by M. Livet, in the thirteenth Number of the Journal de ? Ecole Polytechnique; and the second by M. Brianchon in a memoir “ Sur la Théorie des Axes conjugués, et des Mo- mens d’Inertie des Corps,” Journal de ? Ecole Polytechnique, vol. viil. p. 65. . If a’, y/, 2! are the coordinates of any point in the normal drawn from the origin, which coincides with the centre, of the curve surface, Av 4+Cy+K24+Bay+Lzey+ Mer+F=0 ay! vz a eee (2 Aa! + By! + M2) (y +2 cosay+ 2 cos zy) = (2Cy+Ba + Lz) (e+ y coszy + z! cos x z) (2Cy' + Bal + L#) (2 + a cosza + y' cos zy) = (2K2 4+ Ly + Mo’) (y+ a cosry + z! cos zy) which are equations to conical surfaces whose intersections are the principal axes of the curve surface, Av? + Cy 4+ K2+ Boy+ Ley + Mrz + F=0. Transferring the origin to the point a, P, y Adc +Cy+K2+Bry+Lzy+ Mez+ Dat Eyt Ng + £='0 D=-—2Aa—BB-—Cy E =—2C6—-—Ba—Ly N=—2Ky—L6-—Mae foAr + By + Mi +D} {y'—B + (a'—a) cosry + (xy) cos ty } ={2Cy + Be +L? +E} {af—a + (y’—B) cos Ty +(x/—y) cos x} {2Cy + Bo + Le + EB} {2 — 7 + (2-4) (cosee + (y!—B) cos xy} ={2K/+Ly +Mz +N} {y/— B + (2-4) cos zy + (x'—y) cos zy} In order to have the equations to these conical surfaces which determine the principal axes in the most general case possible, it is only necessary to substitute in the preceding M2 equations 84 Mr. Lubbock on some Problems in Analytical Geometry. equations the values of «, 6, y, found by elimination, in terms of A, B, C, D, E, L, M, N from equations of lines 29, 30, 31. If the equation to the curve surface be in the form n? p? x? +m? p?y? + mn? 2° = m? n? p*, and a, 8, y are the co- ordinates of the point, as before, from which normals are drawn, my (w—a) = na ( y—B) n° x (y—B) = py (2-7) pa (z—y) = mz (4—a) These are the equations to cylinders which have for their bases equilateral hyperbolas, and which pass through the centre of the curve surface and the point «, f, y. Let 2’, y',2' be the coordinates of any point in the normal drawn from the point «, 8, y to the point x,y,z in the curve surface, . t—a w—a z—a 2-4 ype 6 zy Ry Eliminating 2, y, z between these equations, (ay —B a)? {m?(z'—a) + n° (y'—BY + p?(2—7)} = (n?—m’)? (2! —a)? (y/—B)? (ya! —a y!)? {m? (a! —a)? + n® (y'—B)? + p? (n'—yP} = (m?—p?) (ey)? (e=2)° (6 z'—y y')? {m? (a'—a)? =f n? (y'—6)? + oy (2! —y)*} = (p—m®)? (y'—8)? (2!) which are the equations of conical surfaces whose intersections are the normals which can be drawn from the point a, f, y to the curve surface, The equation to the cone which circumscribes the surface n? p? x* de m? p* y? ate m? n2 x? — m? n® p*, and whose vertex coincides with the point a, 8, y, is n? p*(x—a)* + m? p? (y—B)? + mn? (2-7)? — p* (Bx—ay)?—m? (az—yx)*—n* (yy—B2)? = 0; and the equation to the plane of contact is wpac+mp By +n? myz = mn? p* These equations relative to the circumscribing cone are given in various works on analytical geometry. If the ellipse ng? + m? y? = m2 nt be considered, and if the axes x and y, be at right angles, Ax = m (x—a) ay =n? (y—B) and Mr: Lubbock on some Problems in Analytical Geometry. 85 and eliminating A, (m?—n*) ry—may+ npr =0 which is the equation to an equilateral hyperbola (see fig. 1.), which cuts the ellipse in the points to which normals can be drawn from the point a, 8. The asymptotes to the hyper- bola are parallel to the principal axes of the curve; it passes through the centre and the point (a, 6) ; the coordinates of 2 n? m—n its centre are When « or 8 = 0, m?—n* the hyperbola merges into two straight lines at right angles to each other; and when the point («, @) coincides with the centre, these lines become the principal axes of the curve. If the equation to the curve be y° = 2p, the equation to the corresponding hyperbola is ry —(e—p)y+ pp = 0. The centre is situated on the axis of the parabola at a distance a — p from the vertex. This construction is given by Apol- lonius. See Bossut, Histoire des Mathématiques, vol. i. p. 37. If 2! and y' be the coordinates of any point in the normal, a! —a Sabah Dipelleg "doer OR mae and eliminating x and y between this equation and the equa- tions n? x + my? = m?n?; (m°—n*)cy—may +n’ pe = 0, we have : fm? (x!—a) + n*(y'—p)?} {Br—ay}?—(m'—n'y (a'—a)* (y'—AY = 0 which is the equation to the normals drawn from any point ape. When m = 2, the ellipse becomes a circle; in this case pam 86 Mr. Lubbock on some Problems in Analytical Geometry. 62—ay = 0, which is the equation to the line joining the centre of the circle and the point « 6. It is evident that since the hyperbola (m?—n*?)xny—mayt+n’px=0 is the same for all similar ellipses, there will be one, as fig. 1., which touches the hyperbola. In this case two of the normals, as P N;, P N,, coincide and become equal ; after this the ellipse diminishes, one branch of the hyperbola ceases to cut the ellipse, and only two normals can be drawn from the, point «£ to the ellipse. When the ellipse touches the hyperbola, the values of aa are the same in both. Let 2/2? + my? = n/m’ be the equation to this ellipse, then { (m?—n*) 2—m*? ain’? 2 = my {(m?—n*)y + n? B} nm on? and since — > —— m2 m!? {(m?—n?) c—m*a} n? x = my {(m°—n°) y + n° B} and eliminating x and y between this equation and the equa- tions (m? — n®)xy—mayt+nwBar =O and my? + n? x = mn? m—n? = fit ot 4+ n3 Br }+ the equation to the evolute of the ellipse. And hence from any point within the evolute of an ellipse four normals can be drawn from any point to the curve, from any point without it only two. On the Determination of the Foci. Let n° x? + my? = m? n° and let the the curve be referred to any other coordinates x! and y' by putting a(x! +a!) + b(y + B') for x and a’ (a! + a!) + U(y' + 6’) for y Ax? + Bay + Cy? + Da+ Ey+iF=0 A=ra+ma?®, B=2(n?ab+ ma'l), C= n?b?+ mb” D=2 (naa! + nab pl + ma?a + mabp’) E = 2(n?b? pl + n2 b? a! + m? bd? B! + m? b? a!) F = n2 a al? 4 n2 6? BP +2n? a!B! +m? be? iS eb 2 m2? al ba! B! —m* n= Now let the equation 42!+ Ba'y! + Cy? + Da'+ Hy’+F=0 be Mr. Lubbock on some Problems in Analytical Geometry. 87 be transferred to polar coordinates by putting ra" for x" and rb" for y',r being the distance of any point from the origin, (Ad? + Bab" + CBP?)r? + (Da! + ED')r+ F=0 —Da’—Eb! iis { + {(D?—4AF) a? + 2(DE —4BF) a’ b” \ + (E—4cF) 0" 2 (Ad ae Ba' pl ae Cor) and since a? + J? + 2a"b"cosry = 1 — Da'!—Eb’” r =| { D’—4 AF + 2(DE—2 BF— D?—4 AF) cos a} +{H?—4 CF—D°+4AF}b"}2 YX, (A qll2 ae Ba! bl + Co) which value of 7 will be rational in terms of a” and Bb” if F?—4CF—-D’?+4dF=0 DE—2 BF — (D—4AF) cosxy =0 putting for A, B, C, D, E and F their values above, it will be found, after many reductions, that these equations may be put in the form (a’b aE ab’ (p? a al?) —_ (a® a 6?) m2 a n2 (ab —al/) (a! 6+ BP? cosx’y’) = (n?—m?*) (a? cos a! y! — a b) In these equations «' and 6! are measured from the center of the curve in the direction of the axes x’ and y': the equa- tions to the same curve, found either by similar substitutions for the quantities 4, B,C, D, Z, and F' or by transforming the last two equations, referred to coordinate axes coinciding with the principal axes of the curve, are (a°—b”) (a?— 6") + 2 (bb’—aa') aB = (a*—b”) (m?—n?2) aa’ (a#°—B*) + (a°—b”) a8 = aa! (m?—n?) making 8 = 0 in these equations e=m—n, a= + Wf (m—n?) making « = 0, B= + Vo (n?—m?) If m > n, the latter value of 6 is imaginary, and therefore these curves cut one another in two points only, which are si- tuated on the major axis at the distance + 4/ m?—n” from the centre. This result is entirely independent of the quantities a, b, a’, ’, that is, of the direction of the axes 2’ and y/; and hence it is evident that there are only two points from which the distance r to the curve is rational in terms of a” and b”. These points are called the foci. The 88 Mr. Nixon on the Measurement of the The curves whose intersections give the foci are equilateral hyperbolas. (See fig. 2.) It is easy to show generally that the equation to the curve mene Av?+Bry+Cy+De+Hy+F=0, the foci result from the intersection of the curves: { B?—4 AC} (2°—y*) + {2 BE—4 DC} wx—{2 BD—-4 EAhy + B-—4CF-— D?+4AF=0 § B—4ACtay+ {BD—2AE}x + {BE—2DCily+2BF—ED —}{B—4 ACh + {2BD—4 AE} y+ Di—44 Fhoos xy =0 VIII. Particulars of the Measurement, by various Methods, of the instrumental Error of the Horizon-Sector described in Phil. Mag. vol. lix. By Joun Nrxon, Esg.* pee horizon-sector may be described, sufficiently for our present purpose, as a telescopic-level, having attached to each side of its telescope a vertical plate with a divided arc carrying at the centre of the divisions a short horizontal axis on which moves an index supporting a spirit-level. The Ys are fixed to a bar of brass, of which one end, formed into a sort of horizontal axis, connects the bar to a frame or stand beneath, which latter serves, by means of rack-work, &c. to. raise or depress the telescope. * Communicated by the Author: see Phil. Mag. vol. lix. p. 130. First instrumental Error of his Horizon-Sector. 89 First Method.—By finding the horizontal inclination of the upper surface of the telescopic tube, resting within its Ys, with the bubble of its level at the reversing point. Support for the Sector.—A block of compact micaceous sand- stone, (estimated to weigh two tons and a half,) hewn, with trifling waste of the material, into a pillar nine feet long, and of the average diameter of two feet, was set up, at the bottom of a pit four feet and a half deep, with its thicker end based on bedded rock. ‘The excavation being gradually filled up with earth well rammed down, the pillar became so firmly fixed, that no change of situation of the observer, nor appli- cation of his utmost force against its sides, affected its inclina- tion more than a fraction of asecond. After a lapse of some days (extremely variable in the temperature), the top of the pillar was worked as even and as horizontal as practicable. Three cylinders of lead, each three inches in diameter and nearly an inch thick, introduced within the lower part of the frame of the sector, served effectually to keep it steadily in its place upon the pillar. Description of the Proof-Level.—The level tube, made to order by the celebrated Fortin of Paris, is twelve inches long, one inch in external diameter, but considerably less within, the sides (to prevent flexure) being so thick as to require some care in reading off the divisions without parallax. Each end of the tube is cemented intoa brass socket or hollow cylinder one inch and a half in length. ‘The scale contains 230 divi- sions, of one millimetre each, etched on the glass and stained red, each division being equal to little more than half a se- cond, equivalent to one sixteenth of an inch for one second. The frame of the level was a well-squared bar of mahogany full 17 inches long, 1°5 broad, and 2 inches deep (or high). At equal distances from the ends two horizontal brass plates 2 of an inch long, 4 of an inch thick, and nearly of the breadth of the bar were fastened to its upper surface by two strong screws. For the support to Fortin’s level-tube each plate carried a Y (formed out of the same piece of brass as the plate) placed at a distance of 10 inches asunder, with their angular points in a line parallel to the (vertical) sides of the frame. A brass plate $ of an inch long, 4 of an inch thick, and of the breadth of the frame was secured to each end of its under surface by four long screws driven in nearly at the corners of, and level with* the plates. These plates (previously attached to the frame) were ground to a true plane upon two} contiguous * In the measurements no part of the screw-heads would come in con- tact with the cylindrical rings of the sector. + The diameter of neither plate being equal to the length of the bar. N.S. Vol. 10. No. 56. Aug. 1831. N iron. 90 Mr. Nixon on the Measurement of the iron (?) surfaces (used in grinding the receivers of air-pumps), fixed parallel to the horizon and level with each other by means of an adjusted spirit-level. A few trials with the proof-level indicated that the cylin- drical ring of the sector the nearest to the object-glass was slightly conical; for although the proof-level had but little play between the shoulders of the two rings, yet the nearer it was moved towards the eye-end shoulder the greater the de- viation of the bubble in the opposite direction; the total range being about four seconds. To obviate this cause of inaccuracy, a long smooth hone having an even surface was fixed upon a table, and at one end of the hone was secured, in a line with it, a board rising some little above the level of the hone. Hence by drawing the proof-level to and fro, and always in one direction, with one plate on the well-oiled hone* and the other on the board, the outer end of each plate was ground down at one and the same angle. To reduce the inward ends of the plates the hone was equally raised above the ’ level of the board. The plates were Be eae now of the figure in the margin, so much only of the original surface being left as would come in contact with the cylindrical rings of the sector exactly over their Ys. To each side of the frame, at an equal distance from the end of it, was attached an upright piece of wood, both pieces being notched above for the reception of a level-tube furnished with a divided scale of about 4, th of an inch to 2”. This cross level, which served to set the brass plates transversely level, was adjusted in the following manner. A brass bar, 20 inches long, 4 inches broad, and } an inch thick (including the rim), professedly ground to an even surface, was placed upon the stone pillar and secured at the corners by four heavy weichts. The bar being of uniform thickness and the top of the pillar nearly horizontal, the proof-level could be placed with its ground plates in contact with the upper surface of the bar and reversed in direction without displacing the bubble of the cross level beyond the limits of its scale. Hence the plates would be horizontal in a ¢ransverse direction when the middle of the bubble stood at a point of the scale equal to the mean of the readings before and after reversing the frame. The brass bar, although certainly not perfectly even, could * To prevent the plates being durred in the operation the hone was constantly supplied with oil, and no other force applied than the weight of the bar. not tnstrumental Error of his Horizon-Sector. 91 not be more than 1’ or 2’ out of plane; a quantity too small to vitiate the measurements *. Measurement of the equivalent angle of the divisions of the level scales. 1. Sector levels.—The sector was placed upon the pillar in the shade, weighted, and the bubble of the cross level brought to its mark. When the sector had acquired the temperature of the air, (noted by a thermometer placed close to the pillar,) the zero of the index carrying the level then uppermost was made coincident with that of its arc. With the nut of the stand the bubble was brought nearly to the beginning of the scale, (numbered onwards from the eye-piece towards the ob- ject-glass,) and by-and-by noted and registered for both ends in one column A. With the nut of the zndez the latter was moved until the bubble had run nearly to the object-end of the scale, and its ends, perfectly stationary, registered in another column B. ‘This process forms one observation. Secondly, with the nut of the stand the bubble was again brought towards the eye-end, and by the nut of the index afterwards moved towards the object-end of the scale. ‘This constituted the se- cond observation. When five observations were completed, the total arc was read off without disturbing the instrument, and the process repeated up to about ten observations, when the final arc was read off. Half the difference between the sum of the column A and that of the column B is the de- grees of the scale answering to the arc last read off, and di- viding the latter by the above difference we obtain the value in seconds of one division of the scale. ‘This value we can confirm by the arc first read off and the difference of the two columns up to the time of reading off. ‘The results are sub- joined. Right-hand Index Level. March 6th, 1880., Arc 6’ 17" 19° =1'74 |'Temp. 86°5 fi 1°76 36 Left-hand Index Level. Mintch . ...°-1880; | Arc* 7!) 5! 19.<3.1"98 ="Pemp. 48° 8 0 1°91 <9.—, 40 April 14th, 1830. 10 38 1:96 — 60 May Aepimdyers« 8 23 1:39 — 68 6 32 1:90 — 67 * Admitting the rings of the sector to form together the frustum of a cone of which the axis (during the measurements) is inclined 16” and the upper surface 28", the error (minus) introduced by an inaccuracy of adjust- ment of the cross level amounting to 10’, would be equal to (28—16) = 12” x versed sine of 10’; or to 000005, N2 Tn 92 Mr. Nixon on the Measurement of the In most of the measurements the range of the bubble was confined between points of their scales made use of in the subsequent operations, but the result was not materially dif- ferent from that obtained by trials on nearly the whole extent of the scales. Fortin’s Level.—The value of its divisions was variously ascertained: Ist, Precisely as just described, the tube being laid upon the under surface of the horizontal bar of one index of the sector ; to which it was attached, in one case by a string, and in another by a little glue.—It was fixed parallel to the telescope of the sector with the surface of the fluid within the tube equally bisected longitudinally by the line passing through the middle of its divisions. (When transferred to the proof- frame, (the cross-level of the latter being at its mark,) before the tube was fastened within its Ys, it was made to have the surface of the contained fluid bisected as just described.) Another method of finding the value of the divisions when the tube was attached to the proof-frame, was to place it upon the rings of the sector, and compare the run of its bubble at different variations of inclination of the sector, with that of the levels of the latter. This method is free from every ob- jection to which the other is liable, except that of regulating a large instrument by a smaller and inferior one. ‘The re- sults were as follows : March 5th, 1830. Fortin’s level-tube attached by strings to index bar of sector. Are 30765 1° ==0"60. (Temp. 45° Sed: dl 0) "60 — 43 April 1830. The level-frame fastened at its ends, by rib- bons, to the cylindrical rings of the sector, and compared with the right-hand level of the latter ; AC: cossks seuss) BE Op Pv emp, 75 April 1830. The frame glued to the inside of the vertical arches of the sector, and compared with the left-hand level of the latter; PAR GES weak 1° = 0/63: \ Temp: (52° April 1830. The brass sockets of the level glued to the index bar of the sector, and a ribbon passed tightly over the middle of the glass tube and the index-bar. ‘The run of the bubble amounted to 1721 divisions. Are Egy T= "60" “Temp. 60° April 1830. Repeated with the ribbon cut off, which caused the bubble to run immediately exactly 1/’, from one end towards the middle of the tube. The result was unsatisfactory, yes the instrumental Error of his Horizon-Sector. 93 the great discordance between the values by the first and se- cond arcs, Arc 10/29% 1°=0"'"65 Temp. 60°. April 1830. Same as last, but the final arc only was read off. Arc 9/337 1° =0”65 ‘Temp. 60°. The experiments on levels differently mounted (given in Phil. Mag.and Annals, vol. v.), led me to anticipate some of the above discordances. Probably they were increased by the weight of Fortin’s level-tube, which might be sufficient, when resting upon the index-bar (which has no apparatus to clamp it to its arc), to depress it gradually. On this account it would have been advisable to have made two sets of observations, one with the telescope elevated, and the other with it depressed. In the former case the weight of the tube would tend to give an arc in excess, and in the latter case in defect. (In reply to my inquiries, M. Fortin informed me that he had not ascertained the value of the scale with extreme exact- ness, but that the divisions would be about half-a-second sez- agesimal each.) Process of measuring the horizontal inclination of the cylinder. There are three methods. One is, to place the upper sur- face of the (supposed) cylinder exactly parallel to the horizon by means of the; proof-level, and then to take it out of its Ys and replace it within them reversed in direction; the conse- quent deviation of the bubble of the sector-level being double the horizontal inclination. Or, if we have previously deter- mined the reversing point of the sector-level, the difference between that point and the one at which the bubble stands when the surface of the cylinder has been rendered horizontal by the proof-level, gives, without reversion of the cylinder, the inclination required. In this method it is not necessary that the proof-level should be strictly parallel to the cylinder, or its plates truly horizontal in the transverse direction ; but, onthe other hand, we measure the inclination by the sector- levels which are inferior to that of Fortin. As it is almost impossible to place the cylinder with its upper surface hori- zontal to the fraction of a second, it must be noted which end of the cylinder stood the highest, and the amount, in the case of the thicker end, must be apt aed from the measurement. Every visible particle of dust being carefully removed from the cylinder and the Ys, the proof-level was placed upon the gard with one side of the bar resting within and against the adjacent are of the sector, and the opposite side of the bar against 94 Mr. Nixon on the Measurement of the against the other arc*. ‘The cross-level of the sector being exactly, and that of the proof-level nearly at their respective marks, the latter was rendered perfectly so (a little at the ex- pense of the sector cross-level) by moving the arcs a second or so out of a vertical plane. ‘The proof-level and that of the sector being read off, the former was replaced reversed in direction, and read off, and finally, the cylinder being re- versed within its Ys, the sector-level uppermost was read off, but not before the proof-level had been replaced, as its weight was found to alter the sector-level about 1".—The process was then repeated, on the opposite surface of the cylinder, with the other level of the sector. In these observations it was always noted whether the telescope pointed north or south, and the readings for all the levels were registered in two co- lumns, one for the north ends, and the other for the south ends of their bubbles. The conical figure of the object-end ring of the sector has already been pointed out. With the reduced piates the proof- level could, however, be pushed close to the shoulder of either ring without causing a deviation of more than half-a-second in Fortin’s level. In reversing the sector the effect of the conical ring would be even more insignificant; the play within the Ys being scarcely perceptible. The measurements with the reduced plates were made, April 13th, 1830; Fortin’s level tube being secured within the Ys of the frame by broad ribbon passed round the sockets of the tube and the frame, and made perfectly tight by stitch- ing together the ends of the ribbon with strong thread.—On placing the eye in the plane of the horizontal plates of the proof-level, their contact with the surface of the cylinder was so uninterrupted, that scarcely a glimmering of light could be seen ‘anywhere between. The temperature being 49°, the horizontal inclination appeared to be 31"°1 by the right-hand level, and 29"2 by the other; mean 30""15. ‘The discrepancy may arise from that surface of the eye-end ring, which is uppermost when the right-hand level is made use of being slightly corroded; or partly because the scales of the two levels have not had their angular equivalents determined with equal accuracy. Second Method.—The cylinder being placed within its Ys with the bubble of its level at the reversing point, the incli- nation is found by placing the proof-level upon it direct and reversed; half the run of the bubble giving the inclination re- quired. In this method, especially when the cylindrical error is con- * The arcs are not exactly parallel to each other. . siderable, bs instrumental Error of his Horizon-Sector. 95 siderable, some care is required in keeping the plates hori- zontal in the transverse direction, and in making the proof- level parallel to the cylinder; both sources of error tending to give a measurement in defect. In some instances it was attempted to place the proof-level parallel in direction to the cylinder, by bringing the middle of each end of the former to the highest point of the adjoining shoulder of the latter; the bar being prevented from toppling by a delicate wedge of mahogany gradually introduced between the sides and the arc until the cross-level of the frame arrived at its mark. When the proof-level was placed in contact with both ares (which was more frequently the case), the deviation from parallelism with the cylinder could not possibly amount to a tenth of a degree,—a quantity too small to be sensible in its effect on the measurements*. It does not appear that there were any trials of this method with the plates reduced, and the results of those made pre- viously were, for the reason assigned, too discordant to be worth transcribing. Third Method.—This differs from the preceding one solely in completing the measurements without reference to the levels of the sector; the proof-level being noted, both direct and reversed, when in contact with the cylinder before as well as after the latter is reversed within its Ys. If the angular points of the Ys are level with each other, the proof-level will give the inclination of the cylinder alike before and after the latter is reversed; otherwise, if the inclination be made too much before, it will come out equally in defect after reversing the cylinder +. Fortin’s level-tube being glued at the sockets to the Ys of the frame, the inclination of the cylinder given April 16th, 1830, temperature 58°, by the third method, was 26"-9 with the left-hand level upwards, and 29"-1 with the other level uppermost. On the same day, the measurements repeated at a temperature of 56° were respectively 27-3 and 29-2; the mean of the whole being 28""1, or 2" less than by the first method. Multiplying the mean of the two methods by 0°586 (the Ys opening at ‘an angle of 90°), we obtain 17-1 for the constant error of collimation of the sector t. * When we measure the inclination of a plane, if we do not place the level-tube exactly at right angles to a level line drawn on the plane, we obtain a measurement (in defect) equal (when the deviation and inclina- tion are both small) to the correct quantity divided by the secant of the angle of deviation. + By precisely the same process may be found the inclination of the (mathematical) axis of rotation of a transit instrument having unequal pivots. { See page 429 of last volume. ; t 96 Mr. Nixon on the instrumental Error of his Horizon-Sector. It is a good verification of the measurements to find the reversing points of the proof-level the same on the cylinder as on a plane made as nearly horizontal in every sense as pos- sible. But it is to be remarked that unless the plates of the proof-level are true planes, the reversing point may not be the same on the cylinder as on the plane. For want of a per- fect plane this satisfactory confirmation could not be obtained; but the reversing points with the proof-level on the cylinder, as may be seen from the statement below, agreed within the fraction of a second of their mean value. April 13th, 1830. Temp. 50°. Reversing point...... 105° 105 107 107 Mean 106 April, L6th, 1880... Vem, 58° pexcavegecstiaes t demaiaulas oe SS 113 113} 1142 1134 Ls 1134 Mean 1132 AprTl 16th; 4830. | Tetnp. 56° 8s sce eeie lieth tate eee 114 114 1142 1122 1122 112 1112 Mean 113} (One division is equal to about half a second.) There is this serious objection to all the three methods, at least in their application to the sector,—that the inclination of the cylinder cannot be measured on that part of its surface which comes in contact with the Ys during the process of ad- justing the instrument. (To be continued. | IX. Notes [ 97 ] 1X. Notes on some recent Improvements of the Steain-Engines in Cornwall. By W.Jory Henwoop, F.G.S. Member of the Royal Geological Society of Cornwall. To Richard Taylor, Esq. F.S.A. F.LS. Sc. Dear Sir, HE same excuse which was offered by Mr. Farey for his long silence on the subject of my paper* may, perhaps, now serve for mine on that of hist. I shall not attempt a regular discussion of his papers, as the digressions and the many objects they embrace, would, ! fear, be unsuitable to your pages, and tiresome to your readers. I purpose confining myself to the various alterations and improvements which have been made in this county since Messrs. Boulton and Watt, and their agents, ceased to superintend the steam- engines on our mines; with the addition of a few incidental observations on some of Mr. Farey’s statements. In my former communication to you on this subject, I said that “variation in the elasticity of the steam employed by no means affects the invention [my views would have been more correctly expressed, had I said the merit or principle of the invention | of expansive working ;? and, notwithstanding Mr. Farey’s indignant attempts, he has advanced nothing which bears the semblance of proof of the contrary. ‘Mr, Farey says{, Mr, Watt “ proposed in 1782 to work his engines by stopping the supply of steam when the piston had only moved one-fourth of its course.” Will that gentleman particularize the engines in this county which now expand more than three-fourths of their stroke? ‘ Mr. Watt’s en- gines with such boilers” (which will not retain steam of more than 32 pounds per square inch above the atmosphere) “ can- not be made to exert a competent power to drain deep mines, unless the supply of steam to the cylinder is continued until the piston has run through more than half its course {.” This I humbly apprehend will depend on the size of the engine, and the weight to be lifted, I hope I shall not be charged with ‘‘altering” this sentence so as to make it ** very indefinite.” In 1801-2, Captain Trevithick erected a high-pressure engine of small size at Marazion, which was worked by steam of at least 30 pounds: on the square inch above atmospheric pressure. In 1804, as Mr. Farey admits §, the same gentle- man introduced his celebrated and valuable wrought-iron * Phil. Mag. and Annals, N.S. vol. vii. p. 323. + Ibid. p. 421, and vol. viii. p. 305. t Ibid. p. 309. § Ibid. p. 313. N.S. Vol. 10. No. 56, Aug, 1831. O cylindri- 98 Mr. W. J. Henwood’s Notes on some recent Improvements cylindricai boilers*, now universally used in this county. To these, every one at all acquainted with the Cornish improve- ments ascribes a great part of the saving we have obtained. This will further appear from an extract from a valuable work edited by John Taylor, Esq. F.R.S.+: the monthly con- sumption of coal in Dolcoath mine was in “1807, 5112 ee and the mine eee 160 fath. level under } being sunk below the §adit: adit 42 f. deep. 1808, 5184 ———— S—&s —___— 170 fathom level. 1809, 5688 ———— ———— 1810, 6840 ———— ————_— 180 fathom level. 1S Ad Okey ee Sete eee 1812t,4752. —————- _- ———__- 190 fathom level. ISI WS) SS SS 1814, 5413 ek TSR) es ee eae ates 1816§,6826 9 pena 1817, 3102 a) ea a The alteration in the boilers, was the introduction of Capt. Trevithick’s cylindrical boilers in place of the common waggon boilers, which had until then been there in use. In 1811-12, Capt. Trevithick erected a single acting en- gine of 25-inches cylinder, working with but two valves (the exhausting valve being wanting) at Huel Prosper Mine in the parish of Gwithian, which of course had a cylindrical boiler, in which the pressure of steam was more than 40 pounds on the square inch above atmospheric pressure; and the engine was so loaded that it worked full seven-eighths of the stroke expansively. Mr. Woolf, as Mr. Farey states ||, came to reside in Cornwall about the year 1813, and his “ first engines for pumping water from mines were set up by him in 1814, at Wheal Abraham and at Wheal Vor mines in Corn- wall; they had each two cylinders.” If the use of high-pressure steam acting expansively were a part of Mr. Woolf’s patent, to which he could establish a legal and exclusive right; why did he not prefer a claim on Capt. Trevithick, or the adventurers in Huel Prosper Mine, who were using an engine of that description before that gen- tleman’s arrival in Cornwall? The answer is obvious. Mr. Taylor remarks 4, “ During the whole of this year (1814), * Phil. Mag. and Annals, N.S. vol. i. p. 127. + Records of Mining, p- 163. { Alteration in the boilers this year. § In this year the old engine was replaced by a new one ;—of this more hereafter. || Phil. Mag, and Annals, vol. viii. p. 308. 4 Records of Mining, p. 156. Jeffery of the Steam-Engines in Cornwall. 99 Jeffery and Gribble’s engine at Stray Park performed the best duty, being the first that reached 35 millions, and maintain- ing for twelve months an average rate of $2 millions. Woolf’s engine at Wheal Abraham was first reported in October in this year, and performed 34 millions. Number of engines reported, 29; average duty, 20,534,232.” In the early part of 1816, a single engine of 76-inch cylinder was erected at Dolcoath mine by Messrs. Jeffree and Gribble (see preceding note), in place of an old and defective double one; which accounts for the diminished consumption of coal which the extract from Mr. Taylor’s notice of Dolcoath exhibits. In the same year Mr. Woolf replaced an old engine of 63-inch cylinder, but which had for a short time previously been worked by higher steam than usual, with one of 66-inch cylinder at Huel Abraham: the latter, if I am not mistaken, was set to work about the 12th of November. I believe I have now satisfactorily shown that Mr. Woolf, instead of being the first to introduce the expansive action of steam in one cylinder, was positively preceded several years by Capt. Trevithick, and probably so, a short time, by Messrs. Jeffree and Gribble. Mr. Farey says, ‘‘ He” (Mr. Woolf) “altered another old engine at Wheal Unity, by adding a small cylinder to it; the performance was improved in about the same degree as that of the old engine with one cylinder *.” Perhaps Mr. Farey may not be aware that after being altered the Huel Unity engine did not answer expectation, and the nossels which Mr. Woolf had put in were thrown out and replaced by others; this only made the matter worse, for the engine would not then keep the water (‘zm fork”); to remedy the defect these were removed, and those first put in were re- placed. But, to mend the matter, for several years before the engine was stopped, the use of the small cylinder was dis- pensed with, and the engine worked as a common Watt’s single engine; in which mode it is at present worked on Oppie’s shaft in Poldice mine. Whilst on the subject of alterations, I may remark that Mr. Woolf had intended adding a small cylinder to the old engine (48-inch cylinder, single) at Huel Vor but the un- toward result of his experiment at Huel Unity, prevented his making the attempt, although a cylinder was purchased for the purpose. This was subsequently, after much labour in enlarging the apertures, used by Messrs. Jeffree and Gribble as onlinder for a small double acting rotatory engine erected to move a stamping apparatus on the same mine, where it is * Phil. Mag. and Annals, N.S. vol. viii. p. 312, O02 still 100 Mr. W. J. Henwood’s Notes on some recent Improvements still at work. Mr. Farey continues *, ‘ In a short time after Mr. Woolf’s patent expired, most of the old Boulton and Watt’s engines in Cornwall were altered to work by high- pressure steam on his system: some few had an extra cylinder added.” Instead of the pressure of steam in general use being raised at that period, I assert no such alteration took place in a more marked degree, then, than had before obtained ; and the alteration which at all took place was not in conse- quence of Mr. Woolf’s assertions or performances, but of those of Capt.Trevithick. Will Mr. Farey name an engine to which a cylinder was added (that it might be worked on what he calls Mr. Woolf’s system) after the expiration of that patent? He proceeds}, ‘* The advantage of the change from low-pressure to high-pressure steam, on Mr. Woolf’s system, was manifest in all cases; but it was greater or less, according as the steam was used stronger and with more or less expansive action.” Now, I maintain that there is not a shadow of ground for this assertion, and I challenge Mr. Farey to prove its accuracy. He says, ** Previous to 1826 the steam cases were not clothed, but exposed to the air.” That the steam cases of Boulton and Watt’s engines were covered with lath and plaster whited on the outside, is notorious; their steam pipes were also encircled with straw ropes plastered and whited. ‘The steam case at Dolcoath engine was surrounded with a casing of sheet- iron ; the interval of about four inches being filled with straw, hemp, saw-dust, and other imperfect conductors of heat. Mr. Farey says §, “ Mr. Hornblower, who practised that sy- stem” (expansive working) “‘in two cylinders, did not suc- ceed so well as Mr. Watt himself, who only used one cylin- der.” I repeat, that “ variation of the elasticity of steam em- ployed by no means affects the principle of the invention ;” the superiority of one cylinder over two being proved with low-pressure steam, it appears to me “ignorance in spite of experience” to expect a contradictory result by variation of tension only; and, still stumbling over the results of his own experiments as well as those of Messrs. Watt and Horn- blower, Mr. Woolf’s engine with two cylinders at Huel Al- fred was a signal failure. The improvements which came prominently into notice in 1827 were commenced by Capt. Grose, at Huel Hope mine in Gwinear parish, in 1825. They do not in any part consist, as Mr. Farey states||, in ‘ using better boilers ;” for they are * Phil. Mag. and Annals, N.S. vol. viii. p. 312. + Ibid. { Ibid, p. 312-313. § Ibid. p. 312, note. \| Ibid. 313. precisely of the Steam-Engines in Cornwall. 101 precisely similar to those which he before says* were “ first brought into use for high pressure steam by Mr. 'Trevithick in 1804;” but in different arrangement of the flues+ round them; first introduced at Huel Hope, afterwards at Huel Towan, and subsequently in many other mines (the Consoli- dated, Huel Vor, &c.); in some degree by more attention to the temperature of the hot well; and in a great proportion by carefully covering all the vessels containing dense steam with bodies which transmit heat very slowly. That these originated with Capt. Grose, and were borrowed from him (without acknowledgement) by Mr. Woolf and others, will appear from the following extracts from Messrs. Lean’s monthly reports. Huel Vor Mine. Trelawny’s Engine. Sims and Richards, Engineers. || lHnel Towan Mine.| Consolidated Mines. Wilson’s Enginef. Best Engine.§ . rine Grose, Engineer. Woolf, Engineer. 43-5 millions. 43-1 Jan. 48-9 millions. |Taylor’s 42-8 millions. Feb. 518 —— Ditto 48-5 —— March} 53:55 —— Huel Fortune41-9 —— 45-2) = April 61-8 —— Ditto 44-] —— Ajo May 60-6 —— Ditto 43-9 —— 46-9 —— June 61-7 —— Pearce’s 42-7 —— 49-1] —— July 62:2 —— HuelFortune40-8 —— 45-5 — Aug. 61-7 —-- Pearce’s 43-2 —— 50-8 —— Sept. | 60:1 —— Huel Fortune42-5 —— 50- = —— Oct. 61-3 — Woolf's 63-7 —— 47-83 =—— Nov. 56-1 —— Ditto 67 —— ee nee Dec. 57-7 Ditto 62-4**—_— Millions. 1827: average of all the pumping engines reported 31-9 Huel Towan, Wilson’s engine ...... 58°1 —— Consolidated Mines, 12 hahaa: ; . 48°6 average of best engine ...... re - Woolf’s engine ¥ eee eeeeee ees ereeeeeee 64:4 —— Huel Vor Trelawny’s engine......... 47°2 * Phil. Mag. and Annals, N.S. vol. viii. p. 313, note. + Brewster’s Journal, vol. ix. p. 159. { Wilson’s engine was at that time the best on Huel Towan. § In the first nine months; the same engine was not every month the best. || Trelawny’s engine is the best on Huel Vor. § Woolf’s engine was not reported until October 1827. ** At an experiment made by some Cornish engineers in this month the duty was 63°6 millions, 1828. 102 Mr.W. J. Henwood’s Notes on some recent Improvements Huel Towan Mine.| Consolidated Mines. Huel Vor Mine. : Sas | : Trelawny’s i 1828, | Wilson’s Engine. | Woclt’s Engine. Sims and be as Grose, Engineer. | Woolf, Engineer.* Enci f ngineers. not reported.t 76:1 75:8 81-9 81-6 77°8 2 74 73-6 METTLE Millions. 1828: average of all the pumping engines reported 37:2 Huel Towan, Wilson’s engine... 77:2 ee Consolid. Mines, Woolf’s engine 62°5 Huel Vor, Trelawny’s engine...... 55° I think the foregoing details prove, not only that Captain Grose led the van of the more recent improvements, but that he has kept far in advance of its strides. The importance of the saving thus obtained cannot be more plainly shown than by the following extract from Mr. Taylor’s valuable “ Re- cords” t. ** In 1825, all the drainage of the Consolidated Mines was effected by three engines only; they were hard pressed by the increased depth of the mine and quantity of water, and derangement happened, which, added to the bad state of some boilers, and the pit-work, which suffered from the engines being unavoidably worked too fast, the duty of the engines fell off considerably, and, as the reports will show, did not average quite 30 millions; at that time the monthly consump- tion was Job’s engine (90-inch cylinder) 4992 bushels. Pearce’s do. (58 do. ) 3615 —— Bawden’sdo. (90 do. ) 8427 —— 17034 s* At the present time (1829) six engines are at work, as, to remedy the evils above stated, and to provide for sinking * For all 1828, it took the lead of the Consols’. engines. + In this month an experiment was made by Cornish engineers, duty 87-2 millions; and in April 1830 by Mr. Rennie and myself, duty 92,260,202 by calculation, and by waler delivered as determined by a float 83,602,022. t+ Records of Mining, p. 164. deeper of the Steam-Engines in Cornwall. 103 deeper, three additional ones have been erected, and the con- sumption of fuel now stands as under, the mines being 20 fathoms deeper than in 1825: Job’s engine (90-inch cylinder) about 2050 bushels. Pearce’s do. (65 do. \(altered)2130 —— Bawden’s do. (90 do. ) about 2050 —— Taylor’s do. (70 do. ) 1480 —— Woolf’s do. (90 do. ) 1710 —— Shears’s do. (70 do. ) 1180 —— 10,600 « The average duty of the six engines is now reported at more than 50 millions.” This difference I attribute entirely to Capt. Grose’s improvements. Mr. Farey has thought fit to charge me* with keeping back the fact of our engines having only one cylinder, and being worked with high-pressure steam, acting expansively. If he will refer to Brewster’s Journal, vol. ix. p. 160, and vol. x. p. 42, he will find papers (which although inaccurate in some minor details are substantially correct) in which the elasticity of the steam employed is_par- ticularly mentioned. He has also said that I have, in quoting, “altered” his expressions, so as to make them “ very inde- finite’ +. I believe my quotations present his ideas in quite as definite a form as that in which they stand in the original; and I do not base this assertion on my own opinion only. I may now be asked, in what respect Mr. Woolf has been a benefactor to Cornwall? I reply, In introducing accurate workmanship and some attention to proportion in the con- struction of engines, both which disappeared on Messrs. Boul- ton and Watt’s removal. These I take to be the only benefits he has conferred on the county; but they are favours of no mean order, as those who know the state of the engines in Cornwall, before his arrival in the county, will readily admit. I pass over some points of minor importance on which I could have desired to make a remark or two, as I fear I have already trespassed too long on your -patience, and I am half ashamed that the discussion has assumed so unconnected a form; but however much I may be disposed to enter further upon it, I shall deny myself the honour, unless the inquiry be in future directed to but one point at a time. Yours, &c. Perran Wharf, near Truro, Ww. J. Henwoon. April 11, 1831. » Phil. Mag, and Annals, N.S. vol. vii. p. 423. + Ibid. p. 422. X. On [ 104 ] X. On Chemical Symbols and Notation; in Reply to Pro- essor WuHEwELL. By Mr. Joun Pripreaux, Member of the Plymouth Institution. To the Editors of the Philosophical Magazine and Annals. Gentlemen, N the last Number (May 1831) of the Journal of the Royal Institution, is an article by Professor Whewell, “ On the employment of Notation in Chemistry ;” going to show the advantages of using symbols in that science; and to remove anomalies in the foreign notation, by reducing it to mathema- tical consistency and symmetry. I concur with all that is therein stated of the practical convenience and utility of such symbols, and I am glad to see Professor Whewell’s eminent name enlisted in their advocacy. ‘They constitute a prompt, impressive and peculiarly legible short-hand ; expressing in a few letters and dots what would occupy several lines of writing, and what no writing will give with the same distinctness,— a great point in a science of which the materials and modifi- cations are so numerous and so complex. In experimental notes they are of great service, placing constantly before our eyes the entire analysis of every material employed; and for the same reason, as well as on account of their compactness, are aptly suited for comparison and tabular classification. But I am not yet convinced that it is desirable to sacrifice this graphic simplicity, in order to convert them into an algebraic notation; to which, when requisite, they are easily accommo- dated. Such of your readers as feel interested in this question, and have not seen Professor Whewell’s paper, would do well to read it before proceeding with this. The chemical symbols of Berzelius were contrived ‘ pour faciliter expression des proportions chimiques, et de nous mettre en état d’enoncer briévement et avec facilité le nombre d’atémes élémentaires qui se trouve dans chaque corps com- posé.” ‘To this purpose they seem happily fitted; exhibiting, in signs no less natural than compact, the entire constitution of the substance through all the grades of analysis. Thus an atom of potassium, K (/alium in Berzelius’s Latin), oxidized with one atom oxygen K, forms potash; an atom of nitrogen N, with five atoms oxygen N, forms nitric acid, and K N forms nitrate of potash. In this concise symbol we see the acid and alkali, and the elementary composition of each: the bases expressed in their initial letters; and oxygen, the great modifier of chemical properties ; Mr. J. Prideaux on Chemical Symbols and Notation. 105 properties,—the pivot, as it were, round which chemical agency revolves,—is exhibited, in a manner equally characteristic, pro- minent and compact, by dots, corresponding to the number of atoms placed over the symbol. Again, H is hydrogen; H* three hydrogen; and NH? am- monia. C is carbon, C*? two carbon; and C*N cyanogen. HC°N is hydrocyanic acid; and NH*HC?°N hydrocyanate of ammonia. Al is aluminum; Al alumina; S sulphur; Ss sulphuric acid; and AIS sulphate of alumina. A compound salt is expressed by joining its proximate ingredients through the sign +; thus Al S+NEBS is sulphate of alumina and am- monia. When one Of the constituents is in more than one atomic proportion, it is preceded by the indicatory multiple : thus NH?S+3 Al S is ammoniacal alum, which crystallized with 25 atoms water becomes NH? S+3AI1S+ Ag*. (It is my custom to write the salifiable bases in inclined, and the acids in erect letters, NH°S+3Al S+ Aq, which is attended with some conveniences; but has not received the sanction of Berzelius, and might, though in my practice it has not so occurred, possibly interfere with his mineralogical symbols.) A principal objection, in the paper above quoted, is, that the symbols are joined in the way which, in algebra, denotes multiplication. But this juxta-position KN, and the employment of an index figure, NH?, as practised by Berzelius, lead the chemist into no error, because their subjects are not susceptible of algebraic powers, or of being multiplied into each other. We can have neither cube nor square of H (hydrogen), nor ob- tain a multiple of K by N: and the cases in which atomic calculation would necessarily generate such products are so rare that the letters x, y, &c. may be substituted, or the actual symbols adapted to the occasion; without general destruction of their conciseness, by multiplication of signs, brackets and letters. Chemical mathematics are mostly simple, but a dif- ference is to be made in the symbols, according to the more or less compound character of the individual subjects of cal- culation. If simple bodies were concerned in the process, we should represent them as 0, oxygen; c¢, carbon, &c. If alkalies and acids, as potash, nitric acid, &c. we should state them /,n; or C, n’, if preferred. But with respect to tri-silicate N.S. Vol. 10, No. 56. Aug. 1831. iy of 106 Mr. J. Prideaux on Chemical Symbols and Notation ; of alumina, sulphuret of iron, arseniuret of cobalt, &c., we should employ a single letter for each, unless their decompo- sition were concerned in the research. In short, however contrived, they must be variable and varied, as in other sci- ences, for algebraic adaptation; and they would be analytical so far only, as decomposition is connected with the calculation, as will be exemplified below. Although juxta-position implies multiplication in algebra, the signification is arbitrary; and in another science, equally mathematical, with elements susceptible of every mathematical power, we can so place them without fear of understanding CLV as Cx LxV, or 534 as5x3%x4. This position implies naturally (if the word be allowable) the meaning Berzelius attaches to it, alliance or combination; the truth of which is illustrated in the paper under review; in which one of the ablest algebraists of the age, in the very act of publicly ar- raigning it, writes Protoxide of manganese mn + 0 Mn Sesquioxide .........00000 mn + 30 Mus Dentoxidetes..i..s23085..) mn 20 Mann and by the same rule would write the oxides of osmium, Om Omm, Ommmm. Two cases are quoted from Herschel, to exemplify the ad- vantages of a more mathematical system. One describing ‘the decomposition of oxynitrate of silver by hyposulphite of lime.” “‘L represents lime; S, sulphur; s, silver; O, oxygen; N, nitric acid. He says, ‘ we have for the atoms present, before the decomposition, {L +2(S+0)} + {N+(s+0)} which afterwards group themselves thus : =(L+N)+(S+s)+(S+ 30) that is, one atom of nitrate of lime, one of sulphuret of silver, and one of free sulphuric acid.’ ” The other is of kindred character; and they are given as ‘“* very instructive examples of the use which may be made of such a notation.” The system of Berzelius is said to possess no such advantages. Of the case quoted it may be observed, that the sign + al- ternates with every letter, whether indicative of intimate com- bination, mixture or decomposition; and that an incompatible mixture is made = equivalent to a compatible one* :—that * The sign = in Mr. Whewell’s paper is employed only in the second example; but the circumstances being the same, it is needless to quote both. the zn reply to Professor Whewell. 107 the symbols are severally constructed for the occasion, free from the restrictions of any rule of intelligibility; lime, com- posed of an atom of calcium and one of oxygen, being signified by L; whilst oxide of silver, also of an atom of each ingre- dient, is made (s + O): sulphuric acid, one atom sulphur and three oxygen, is (S + 30); whilst nitric acid, of five atoms oxygen to one nitrogen, is only N. The chemistry is in fact sunk in the mathematics, simple as they are; and the scheme, without the text, is totally unintelligible. Berzelius would express it thus: Ag N with Ca 8 gives Ca N, AgS and S Ca being lime; Ag, oxide of silver; S*, two atoms hyposul- phurous acid, &c. Here you have the whole process (its chemical probability being not in question) in the symbols, as well as the proxi- mate and ultimate analyses of each ingredient. We may now contrast the proposed notation with the ex- amples before given of the symbols. Berzelius. Whewell. Nitrate of potash KN (k+0)+(n+5 0) Hydrocyanate STI CON rarer yd Heisitnia NH*HCN (n-4+3h)+(a4+20+h) Ammoniacal, 341 S4NWS {Salpotst3q}+G+a-+s 40) Do. contracted. Nitrate of potash ......cesesseseees K+n/ Hydrocyanate of ammonia...... Am+thedn Ammoniacal alum. .......sseeeees (3 Al+s/)+(Am-+s’) The multiplication of lines and brackets in the proposed notation gives it, in my view, a comparatively perplexed ap- pearance, though algebraically just. ‘The unvarying sign + alternating with every letter, loses the distinctive property, in which consists its value. ‘The increased length of the formula destroys its graphic character: and in the contracted notation this graphic property and the analytical expression are both incomplete. To apply this notation in the case quoted from Herschel, {(c +0) + 2(s + 0)} + {(n + 50) + (ag + 0)} ={(c+0) + (n+ 50)! +(s + ag) + (s + 30). or, contracted, (C + 2s’) + (Ag + n’) =(C +n’) + (Agt+s) +5. Here the full notation appears confused by the needless P2 multiplicity 108 Mr. J. Prideaux on Chemical Symbols and Notation. multiplicity of terms, &c.: the contracted does not apply; but both together will do very well. This simple case, then, amply illustrates the need of varying the structure of our symbols according to the occasion, when employed mathematically. The chief objection made to the mineralogical signs of Ber- zelius is, that “ the analysisitself is not recorded” by them. But here would seem to be some misunderstanding. Their difference from his chemical symbols is, that they do express the result of analysis only, apart from atomic relations; the let- ters signifying merely the names; and the figures giving the relative quantities of the common ingredient, oxygen; and, by consequence, the constituents, from the known proportions in which they contain it. Thus apophyllite is given by Ber- zelius, (Nouveau Systeme de Minéralogie, p.225,) KS®+8 CS i +16 Aq: recording, that the oxygen in the lime is 8 times ; in the silica, 6+8 x 3 = 30 times; and in the water, 16 times that in the potash: whence the respective ingredients may be read off, on the scale of equivalents, K 5°95; Ca, 28°25; Si, 60; Ag, 18. And the cases quoted at p. 449 of Professor Whewell’s paper are rather equivalent than identical. Berzelius employs these signs in mineralogy, because “ quant aux formules chimiques, elles sont sujettes 4 changer d’aprés des changemens dans nos idées du nombre des atomes élé- mentaires dont chaque substance est composé.” Nouv. Syst. 190. This is exemplified in the change of some of his own views since that treatise was written. He would then have construed the above formula, chemically, thus: K Si*+8 Ca Si?+ 32 Ag. Now he regards potash and lime as each containing a single atom of oxygen; and the chemical formula would be K Si? + 8CaSi + 16 4q; or without grouping K +8Ca+ 10Si +16Aq; the proportions being still preserved. And hence these signs seem peculiarly adapted to the purpose of minera- logical record. The mineralogical notation proposed in the article quoted, would require a local and chronological date to every re- corded analysis, or would involve them in the hypothetical changes of atomic chemistry. Had the above analysis of apophyllite been so stated, the quantities of lime and potash would have been reduced one half by the publication of Berzelius’s last atomic table; and the silica would have been reduced two thirds by the formula being reprinted in En- land. : With respect to the grouping in these formule, the vee of Mr. Brooke on Poonahlite and other Minerals. 109 of Professor Whewell appear to me to be just. The crystalline form must be affected by the state of the combination; and arbitrary or hypothetical statements may impede our attain- ment of correct views on a subject of prime importance in mineralogy. But I cannot yet see the propriety of sacrificing the con- cise and graphic perspicuity of the Berzelian symbols, for the purpose of reducing them to a notation, perhaps not very much more generally applicable to mathematical use; far less so to that of temporary record and tabular comparison in operative chemistry ; and in mineralogy of hazardous admissi- bility. Yours, &c. Plymouth, June 4, 1831. J. PRIDEAUX. XI. On Poonahlite, a new Species of Mineral; on the Identity of Zeagonite and Phillipsite, Sc. ; and other Mineralogical Notices. By H.J. Brooke, Esq. F.R.S. L.S. 5 G.S. To the Editors of the Philosophical Magazine and Annais. Gentlemen, I SEND you herewith a few mineralogical notices, which will probably interest some of your readers. I am yours, &c. June 11, 1831. H. J. Brooke. Thulite. In a list of minerals which I published in 1823, as an Ap- pendix to an elementary work on Crystallography, I described this mineral as having a cleavage parallel to the planes of a rhombic prism of 92° 30', which description was given on the authority of some fragments of a reddish mineral received by Mr. Heuland, from Sweden, under the name of Thulite. I since find that the mineral I then measured was Bisilicate of man- ganese. Ihave lately obtained and measured the true Thulite, and have found it agree in its cleavages and angular mea- surements with Epidote, as it had been before found to do by Mr. Levy. Reagonite. In the same list of minerals I described the crystalline form of Zeagonite as an octahedron, with a square base ; and I did this upon the authority of a crystal from Vesuvius, so named in the ticket by which it was accompanied. The crystal I then measured has since been called Zircon, but whether analysed or not I do not know. I have lately obtained specimens of the Zeagonite described by Gismondi, which I shall probably make 110 Mr. Brooke on Poonahlite, make the subject of a distinct communication, having satis- factorily ascertained that Zeagonite, Abrazite, Aricite and Phillipsite are one and the same mineral. Velvet Copper Ore of Werner. On dissolving this mineral in dilute nitric acid, a skeleton remains which is insoluble in any acid; and when the very minute portion J had to examine was placed on charcoal before the blowpipe with a drop of nitrate of cobalt, it ultimately be- came black; whence I concluded it to be silica. The part dis- solved in the dilute acid contained sulphuric acid, copper and zinc. Native Nickel, so called, although a sulphuret. I have measured the fibres of this substance, and find them regular hexagonal prisms with apparent cleavages oblique to the axis, but the cleavage planes are too imperfect for accurate measurement. Poonahlite. I am indebted to the kindness of Mr. Heuland for some specimens of a beautiful variety of apophyllite from Poonah, in the East Indies, accompanied by some slender crystals, which I at first supposed were mesotype or needle-stone, but which differ from both substances in measurement; the Poonahlite being a rhombic prism of 92° 20'.. The crystals traverse the mass of the apophyllite and matrix instead of forming groups in the cavities; and among several hundred crystals which I have examined on my own and on Mr. Heu- land’s larger specimens, I have not observed one with a na- tural termination. The hardness is nearly the same as that of needle-stone, as far as I can discover from an experiment on very small crystals. Glaucolite. This mineral has a cleavage parallel to the planes of a rhombic prism of 143° 30! nearly. Couzeranite. This is described in Leonhard’s Handbuch, as a right rect- angular prism, and by Dufresnoy in the Ann. de Chim. et de Phys. xxxviii. p. 280. as an oblique rhombic prism; and it would appear from the analysis of the latter to be a distinct species of mineral. Mr. Heuland has lately supplied me with a spe- cimen containing this substance in small imbedded crystals ; on examination of which I find that it has the form, cleavage, and angular measurements of felspar. The crystals are small, and the matrix in which they are imbedded is partly white and partly black. Those in the white part are colourless and transiucent; the identity of Zeagonite and Phillipsite, §c. 111 translucent ; those in the black part are black and opaque, and probably coloured by the same kind of matter as colours the matrix. Hence the analysis of the black crystals, which are the only ones yet analysed, must fail to give the true con- stituents of the mineral, and the theoretical chemical formula must be incorrect. The crystals are similar in form to the small single crystals of felspar coated with chlorite, which are brought from St. Gothard. Pseudomorphous Crystals from a Mine at Haytor, in Devonshire. In the year 1827 some crystals were found in this mine, which were described by Mr. W. Phillips and Mr. Levy, under the name of Haytorite*. It was obvious that the substance of the crystals was calcedony ; and as they nearly agreed in form and angular measurement with Humboldtite, it was supposed they might have derived their pseudomorphous character from crystals of that substance, although from the solidity and state of aggregation of some of the crystals which were first discovered, it was difficult to imagine the mode by which the borrowed forms could have been produced. It is, however, equally difficult to comprehend the manner in which the well- known pseudomorphous crystals of steatite, imbedded in the same substance, could have been produced. ‘These present the forms of quartz and of carbonate of lime, and they con- sist of steatite apparently homogeneous with the mass in which they are imbedded. We might indeed suppose that a cavity partly occupied by crystals of quartz and carbonate of lime had been filled by steatite; that subsequently the quartz and carbonate of lime had disappeared and left moulds which were afterwards filled by the same kind of steatite. But it is not easy to conjecture how the mould and the casts formed at very dif- ferent times should be homogeneous. With regard, however, to Haytorite,there cannot now exist a doubt ofits pseudomorphous character ; many of its crystals being hollow, sometimes very thin, and the inner surfaces mammillated like ordinary calce- dony. I have also a crystal of this substance which presents a form analogous to the common hemitrope crystals of sphene from St. Gothard, with a deep re-entering angle, and evi- dently formed within a polished cavity which it has only par~ tially filled. But in addition to the evidences of pseudomor- phism presented by many of the crystals of Haytorite, there haye been found in the same mine other pseudomorphous crystals representing several of the forms of carbonate of lime, some of which are solid, and some hollow: among these are * See Phil. Mag. and Annals, N.S. vol. i. p. 38, 40, 43,—Epir. groups 112 Mr. Coddington’s Reply to Dr. Goring. groups of very obtuse rhomboids, masses resembling pearl- spar, acute scalene dodecahedrons, and six-sided prisms with flat summits, or terminated by planes of the equiaxe crystal of Haiiy ; and in one instance that lies before me, the calcedonic cast represents one of those crystals of carbonate of lime which are frequently observed, in which a change from a flat to a modified termination of the hexagonal prism has only partially taken place. XII. On the Theories of Achromatisation, §c. in reply to Dr. Goring. By The Rev. H. Coddington. To the Editors of the Philosophical Magazine and Annals. Gentlemen, Y name having been brought before the public by Dr. Goring, in an article contained in the last number of the Edinburgh Journal of Science, in a manner which, though apparently complimentary, must lead readers to consider me as a framer of apparently fine theories, which answer no good purpose in practice, a character for which those who know me are well aware that I entertain very little respect, I would re- quest leave to make a few observations in reply, through the medium of your Journal, which I presume must find its way wherever any scientific periodical work is taken in. Dr. Goring states that my work on the Reflexion and Re- fraction of Light, whether considered as a work of originality, or as a compilation from the writings of our first opticians, is admitted to be the best publication of the kind at present extant. So far I am obliged to him: but in the next article he ‘* ventures, though well aware of what he is doing, to im- pugn the infallibility of exact science in the case of the theories of achromatisation of Professor Robison, Professor Airy, and Mr. Coddington, on the ground that no artist is able to make an achromatic instrument according to them.” Now, Sir, the plain truth of the matter is, that my work contains, to the best of my knowledge, exactly those theories which have guided all artists, from the elder Dollond down- wards, who have been competent to refer to a theory at all. To these I have added one other, (to which Dr. Goring alludes in a note,) out of respect to its inventor Professor Airy. It is one of singular ingenuity and beauty, and gave every promise of a good result, but is probably imperfect, like many other speculations of the present day, since it certainly does not answer the end proposed. The author is well aware of this, and Mr. Coddington’s Reply to Dr. Goring. 113 and speaks of it, with his accustomed modesty, as of a youth- ful production, which has at least done no harm, except, in- deed, as it appears, exhausting Mr. Tully’s patience. Dr. Goring, confessing that he cannot discover the least flaw in our theories, proposes to oppose them by facts, a prac- tice which I cannot too highly applaud, being most firmly con- vinced that no theory can be considered as worth a farthing, except for the indirect advantage of exercising the intellect, until experience has shown that it is complete and satisfactory. Instead, however, of keeping this promise he proceeds to lay down certain “ propositions, which rest only on the basis of the evidence of the eyes or experience.” Some of these pro- positions unfortunately my own limited experience enables me most flatly to deny. I will beg leave to quote them in order, with a few remarks. 1. “ When achromatism is obtained by the adjustment of lenses to particular intervals, as in the case of the Huygenian eye-piece, such achromatism is absolute and perfect, and not like that effected by the combination of a concave lens of flint- glass with a convex of plate or crown glass, which never effects a complete neutralization of the chromatic aberration, as is well known.” The Doctor seems here to confound together two distinct modifications of chromatic dispersion, which affect such instru- ments as a telescope or a microscope quite independently, and must be corrected, if necessary, on quite different principles, as I have endeavoured to explain, after Professors Robison, and Airy. The achromatism is in neither case perfect, and it is impossible to compare them, because they depend, though in different manners, on the apertures of the lenses employed as object-glasses and eye-pieces respectively, which are hardly connected with each other by any laws whatever. 2. “ The only kind of achromatism, produced by convex lenses, which is known in practice, is when two are adjusted to an interval equal to one half the sum of their focal distance or thereabouts.” Every person who knows anything of the construction of a telescope is well aware that an erecting eye-piece, consisting of four lenses, is, when properly made, just as achromatic as the Huygenian. 3. “ Many modifications of this combination may be made, as by doubling or tripling the eye- and field-glasses.” This is very true, and I have applied it with complete suc- cess, in order to correct a defect totally unconnected with chromatic dispersion. N.S. Vol. 10. No. 56. Aug. 1831. Q 4. “In 114 Mr. Coddington’s Reply to Dr. Goring. 4. *In order to form a truly achromatic erecting eye-piece, there must be a compensation both in that part which erects or forms the image, and in that which views it; therefore no achromatic erecting eye-piece can be made with so few as three lenses.” This is altogether incorrect both in theory and in practice. In an erecting eye-piece the compensation of dispersion may take place any how, provided only that it be completely ef- fected on the whole. Erecting eye-pieces of three lenses are not used, though they may be made perfectly achromatic, be- cause they are liable to another defect which cannot be com- pensated. 5. An erecting eye-piece can only be made really achro- matic, (if we do not employ concaves of flint glass,) by com- bining two Huygenian eye-pieces.” Did this gentleman ever examine the day eye-piece of a common hand telescope ? 6. “Such an eye-piece could only be used for viewing an image, and could never be employed as an engyscope, because it would have no external focus in front of the bottom glass.” This is like No. 4, inaccurate, both as to the fact and the reason. Any erecting eye-piece may be used as a microscope, though it would serve little purpose on account of the very small magnifying power that can be thus obtained. Nobody would, however, find fault with it on that account, any more than he would condemn a good carving-knife, because it would not shave him clean. ‘The Doctor then observes, that I have been at the pains of falsifying my own theories, practically at least, to the best of my abilities, by presenting to opticians a compound microscope, termed achromatic, which is con- structed according to them. He says, “I assert point blank, that his instrument is as complete a failure as anything of the sort I ever attempted myself. I have examined one of these instruments of the latest and most improved construction,made by Mr. Cary, and can, I think, be positive that both the chro- matic and spherical aberration of the objective part was wholly untouched, and that the eye-piece, consisting of four glasses, was achromatic.” The history of this instrument is briefly this: On a critical examination of all the four defects to which a compound mi- croscope of the ordinary kind is liable, I judged, from theory, aided in some little degree by my own experience and that of others, that two might be wholly removed in an instrument of small volume and price, and the other two so much reduced as to produce a microscope which might prove very useful to naturalists Mr. Coddington’s Reply to Dr. Goring. 115 naturalists who could not afford to purchase very expensive instruments. As to my success I may appeal to the Doctor himself, who confesses in the next line that NorTHING CAN SURPASS THE BEAUTY OF THE FIELD OF THIS MICROSCOPE, though his firm conviction that this instrument ought not to be good has so far warped his judgement as to make him assert, that “nothing more can be made to grow in it [the field ] than in that of any ordinary compound microscope having a well- figured object-glass of the same power, and angular aperture, used with an Huygenian eye-piece, also of equal power with that applied to the instrument in question.” Several persons have, to my knowledge, compared my in- strument, which be it remembered costs but six guineas and a half, with “ ordinary compound microscopes” made by the first opticians, for which they had paid twenty or thirty guineas, and have declared it decidedly superior in every re- spect. Ifthe Doctor means that it is not so perfect as a com- pound microscope with an achromatic olyect-glass, I agree with him most cordially. Neither is a twenty-guinea telescope, though good of its kind, equal to Sir James South’s twenty- foot equatorial. Let the Doctor produce me a microscope, or an engyscope if he likes that word better, with an achromatic object-glass, which shall magnify distinctly 360 times in linear measure, pack into a compass of about 24 cubical inches, and cost but six or seven guineas, and I shall be perfectly satisfied to yield the palm to him. In the mean time I earnestly conjure him not to diminish the value of his own praiseworthy exertions, by incautious attacks on persons who, if they allow themselves to reply to him, may easily show that while he diverts himself with throwing stones, he forgets that he dwells in a house of glass. I remain, Gentlemen, yours, &c. Trin. Coll. Cambridge, H. CoppincTon. July 8, 1831. P.S. I beg leave to add that I have no pecuniary interest whatsoever in the instrument which has thus unexpectedly furnished a subject for controversy. I furnished designs to Mr. Cary, who in a very spirited manner undertook the ne- cessary experiments at his own cost, and I certainly feel an- xious that no unfounded charges should prevent him from de- riving a fair remuneration from the sale of the microscope. Q 2 XIII. On f u6é j XIIL. On the Thermo- Magnetism of Homogeneous Bodies ; with illustrative Experiments. By Mr. Wm. Srurceon, Lecturer on Experimental Philosophy at the Hon. East India Company's Military Academy, Adiscombe. [Concluded from page 24.] Sixth Class of Experiments. 88. Experiments with irregular Masses of Antimony. ei object of these experiments was that of ascertainin if the same laws of thermo-magnetic action, as regards the crystalline arrangement of the metal and point of heat, as those which were developed in the experiments with cylinders and cones of antimony could be traced in masses of an irre- gular figure, by making the point of heat in various parts of those fine smooth extensive faces of crystalline laminze which are to be met with only in fractures of large masses which have been very gradually cooled from fusion. 89. The experiments were made by heating, separately, particular points in those lamellated faces, and then tracing the direction of the electric currents by expeditiously apply- ing the antimony to a magnetic needle, and noting minutely the character of the deflection; and it appears, from the uni- formity of the results of a considerable number of experi- ments on various pieces, that the thermo-magnetic phzno- mena elicited in irregular masses have precisely the same re- lation to the position of the metallic films and point of heat as those displayed by cylinders and other regular forms of antimony. 90. It will not be necessary to enter into a detailed account of the several experiments which were instituted for this in- quiry, as a description of those which were made on one of the irregular pieces, and of the resulting phenomena, will be sufficient to illustrate the whole. And I have every reason to believe, that the same laws which govern these phzenomena, will be found to appertain to all similar crystalline arrange- ments of antimony; that they will uniformly be developed under similar circumstances, and consequently that they are intimately related to the crystallization of the metal. 91. The piece of antimony on which these experiments were made, weighed about three pounds; it was separated by the blow of a hammer from a large mass, and the frac- ture exposed a smooth triangular face of parallel crystalline plates, without presenting any intersecting edges of metallic Jamine whatever. This triangular face will be represented by figs. 16, 17, 18; and the arrows in those figures will show the On the Thermo-Magnetism of Homogeneous Bodies. 117 the directions of the electric currents as indicated by the de- flections of the magnetic needle, when the point of heat was near to the angles a, 6, c, respectively. 92. When the spirit-lamp was held for a few moments at the angle a, still keeping the point of the flame on the face of the fracture, the electric streams were diffused over every part of that surface from the point of heat towards the op- posite edge; as shown by the directions of the arrows, fig. 16. Comparatively strong currents were detected in the edges a 6, and ac; but in consequence of the general flow of these cur- rents being nearly at right angles to the edge bc, no magnetic force could be detected when that side was held over and parallel to the needle. On leaving the face abe, the electric tide swept the general surface of the metal, flowing in various directions, and returning by numerous windings to the point of heat. By this distribution, and consequent attenuated state of the electric force, the thermo-magnetic energies were com- paratively very feeble on every part of the metal excepting the face abc; on which alone they were displayed with prompti- tude and regularity. 93. When the point of heat was at 4, the whole of the tri- angular face became again magnetic, displaying phznomena of precisely the same character as those which had been eli- cited when the point a was excited; and the distribution of the electric forces had again a decided reference to the point of heat; emanating therefrom, and flowing with as great an uniformity over the surface of the fracture as if it had been a conductor from the copper to the zinc of a single galvanic pair. ‘The arrows in fig. 17. will indicate the distribution of the electric force over the surface of the lamellated fracture when the point of heat was at b. 94. When the fracture was heated at c, the thermo-mag- netic phenomena were again displayed with very nice pre- cision and uniformity on that particular face of the metal; whilst on the other parts of the surface they were confused and irregular; showing that the electric forces on those parts were dispersed in various directions, and enfeebled by their separation, or by their returning to the point of heat, through the body or general mass of the metal. Fig. 18. will show the direction of the electric tide on the face abc, when the point c was excited by the flame of a spirit-lamp. Remarks. 95. ‘The uniformity displayed in the results of the preced- ing class of experiments confers on them a very interesting character in these investigations. In connexion with those on regular 118 Mr. W. Sturgeon on the Thermo-Magnetism of regular masses, these experiments establish a very important point, by exhibiting in the most striking and satisfactory man- ner an intimate connexion between the crystalline arrange- ment of the metal, and the distribution of the electric powers by heat; for, to whatever point in the flat lamellated face of this system or group of parallel scales heat was applied, the electric forces were directed over the planes of the laminz from the heated point; and having traversed the general sur- face of the metal, returned to that point again, across the edges of the films, in precisely the same manner as in the experi- ments with solid cones and cylinders,—a circumstance highly demonstrative that the thermo-magnetic forces in both sets of experiments have the same specific origin, and are actuated by the same cause. The fountain of all the phenomena ap- pears to be in the crystalline arrangement of the metal, and the direction of the electric and magnetic forces to be refer- able to the point of heat. 96. It very often happens that fractures such as have been described (88) (91), are bordered on some of their sides with piles or groups of laminz, unfavourably situated for experi- ments of this kind; presenting their thin edges, instead of their planes, in the face of the fracture. When, however, the method of experimenting becomes known, these trifling in- conveniences are not of much consequence to the uniformity of the thermo-magnetism displayed by the smooth part of the fracture under examination. 97. In the first place, the flat scaly surface on which the experiments are to be made, ought to be as extensive as pos- sible; at least two inches across; if larger, the better. Should any side of this face present groups of the thin edges of la- minz, they may be easily removed, either by the saw or by the hammer: if those groups be not very extensive, their re- moval will not be necessary. 98. The principal circumstance next to be observed is, that the flame of the spirit-lamp does not touch those unfavourable crystals. The selected point of heat must always be on some part of the flat lamellated face under examination, and near to some angle. A momentary heat must suffice, and the plane immediately and dexterously applied to the magnetic needle; the deflections of which will unerringly indicate the electric current to be flowing over that surface from the heated point to the opposite side. 99. I have succeeded in discovering a method of forming square bars or prisms of antimony, which observe a rigid uniformity in the display of thermo-magnetic phaznomena, by heating them either partially, or equably, at one end only. And Homogeneous Bodies ; with illustrative Experiments. 119 And I now find that I can predict with certainty the mag- netic character of any side of the bar, by paying attention to certain circumstances connected with its casting. I have cast several sets of square bars, of an uniform size and figure, under precisely the same circumstances, and have never yet found one single bar to deviate from the general law. One of those sets consisted of fifteen bars, all of which observed the same laws of thermo-magnetic action. I have, however, in vain tried to obtain them of an uniform power, the thermo-magnetism of some of them being much more energetic than that of others. This circumstance, which I hope soon to obviate, and some others which I find associated with the display of their thermo- magnetic phenomena, but which I have not yet had time to investigate, prevents my giving a description, in this place, of the circumstances under which I have hitherto cast these prisms of antimony; the thermo-magnetic character of which can easily be predicted before the metal enters the mould*. 100. In general, these bars possess a considerable degree of power as thermo-magnets ; and when four, or more of them are properly combined, their conspiring energies on the mag- netic needle may be very satisfactorily exhibited to every auditor in the most spacious lecture-room. 101. I have also been enabled to cast discs of antimony, which do not vary from each other in the character of their thermo-magnetic qualities. I have not however, as yet, had time to investigate the whole of the circumstances which I suspect to be connected with the communication of that power to the metal, and therefore beg permission to reserve the detail of the experiments till another opportunity. I mention them in this place merely as facts, which I can at any time repeat. I will further observe, however, that I am of opinion that the thermo-magnetism displayed in the prisms and discs already noticed, may be traced to the same source as that displayed in other forms of antimony; that is, to the crystalline arrange- ment of the metal; and that electricity is intimately associated with the process of crystallization generally. ‘This opinion is highly favoured by the well-known fact of electro-polarity being exhibited in the tourmaline and some of the crystallized gems: and as regards the metals, I imagine that the experi- ments and observations I have hitherto detailed, are amply * It is next to impossible to cast bars of antimony of considerable di- mensions which will not exhibit magnetic phenomena by heat; indeed, bars of almost any size, or masses of any figure whatever, whether regular or irregular, display those powers more or less. It however requires con- siderable attention to obtain several pieces of antimony which will observe an uniformity of thermo-magnetic action. demonstrative 120 Mr. W. Sturgeon on the Thermo-Magnetism of demonstrative of the connexion in that class of homogeneous bodies. And I am inclined to believe, that future labours in this curious philosophical field of research, will ultimately establish crystallography amongst those interesting sciences, which are subordinate branches, and obedient to the laws, of electricity. 103. There are, however, thermo-magnetic phenomena dis- played by homogeneous metals, when experimented with in certain forms, which do not appear to be very reconcilable to the hypothesis of electro-crystallography. ‘They seem to de- pend upon some other cause than any which that hypothesis embraces: and as they are exhibited under different circum- stances to any which have yet been noticed, the experiments by which they are elicited will require to be described as a distinct class. Seventh Class of Experiments. 104. Notwithstanding the opinions which have been set forth to show that thermo-magnetic energies are not exalted in combinations of metals, by employing them of large dimen- sions, and that a pair of particles, however small, or wires exceedingly thin, will develop the same extent of power as two bars of considerable dimensions; I was led to imagine that the same law might probably not extend to the innate mag- netism displayed in homogeneous metals by heat. My in- quiries were therefore directed to large masses of those metals, in which, whilst experimented on in small pieces, I was unable to discover the least trace of this extraordinary power; and the results were such as to answer my anticipations in the most ample and satisfactory manner. 105. Experiments with large Masses of Zinc.—The first piece of zinc in which I detected thermo-magnetic action was a rectangular cake, or flag, which had neither been rolled nor hammered. It was about 14 inches long, 8 inches broad, and ‘75 inch thick, and weighed about 17 pounds. This mass of zinc, when heated at one corner only, displayed magnetic powers in a very exalted degree, and would deflect a compass needle, on which the magnetism of the earth was not neutral- ized, 20°, by the first impulse, when one of its edges was held in the magnetic meridian and close to the glass cover of the instrument; but in consequence of a fracture in one of its edges, the thermo-magnetic phenomena were not so nicely regulated in this piece as I have found them to be in other masses of zinc, which are uniformly sound on every side. I will therefore describe experiments which were made on a whole sound flag of zinc, weighing 42 pounds, 2 feet long, 8°5 inches broad, and about 1 inch thick. 106. The Homogeneous Bodies ; with illustrative Experiments. 121 106. The thermo-magnetic phenomena were promptly and uniformly displayed by this mass of zinc, and were precisely of the same character as those which I have observed in experi- ments with all similar masses that I have yet examined. The have an evident reference to the point of heat; and I believe they may be taken asa general standard for those which would be developed by all similar masses when operated on by the same process. 107. The experiments were made by heating one corner of this mass of zinc in a common fire, and keeping the other parts of the metal as cool as possible. When thus heated, the mass was held in various directions over the magnetic needle, the deflections of which were taken as an indication for the direction of the electric currents. In this manner the thermo- magnetic powers of the zinc were ascertained, whilst it was partially heated at its several angles in succession. 108. If a, 6,¢,d, fig. 19. be permitted to represent one of the flat faces of the zinc-plate, then the arrows in that figure will give a tolerable representation of the directions of the electric forces, as indicated by the deflections of the compass- needle when the point of heat was at the angle d. By con- templating this figure, it will be observed that the electric forces are projected, as it were, from the heated angle into the body or field of the mass, over which they become generally diffused; but separating and expanding in different directions, they sweep the surface of the metal in recurving tides towards its edges, by which routes they again return to the heated point. 109. The straight arrows in fig. 19. would seem to indicate that the electric forces in those parts of the metal were di- rected in right lines, which is not strictly correct. ‘Those arrows are drawn to show the lines of greatest energy, or those parts of the metallic surface which, when presented to the needle, produce the greatest deflections, and are the deter- mined resultants of the numerous curvilinear forces which are in active play during the transient disturbance of temperature in the metal. 110. It will appear evident by inspecting the figure, that on the surface of the rectangular mass, there would necessarily be two neutral lines, one on each side of the diagonal arrow, which would be determined at right angles to the aggregate re- curving electric forces, and may be represented by the dotted lines dn,d n. These lines, are those in which amagnetic needle, unsolicited by any other force, would arrange itself, and were discovered by its uniform repose whilst situated close to those parts of the metal. The situations of the neutral lines, how- ever, are not constantly the same; for as they are determined N.S. Vol. 10. No. 56. Aug. 1831. K by 122 Mr. W. Sturgeon on the Thermo-Magnetism of by the direction of the electric forces, and those forces again by the distribution of heat, the situations of the dotted lines dn, dn, will also vary with the circumstances of heat. 111. When one of the ends ad, fig. 20. of the rectangular mass is uniformly heated, the distribution of the electric forces will be indicated by the arrows in that figure. Here again, it will be observed, that the electric forces are projected Jrom the heated end into the area of the plate, and by re- curving sweeps, return to that end again along the parallel margins of the metal. In this case, the neutral lines, and lines of greatest energy, are parallel to each other, and also parallel to the sides ab, dc of the rectangular plane. 112. As a similar distribution of the electric forces to that represented by fig. 19. is uniformly elicited by heating any of the angles separately, the same system of arrows will serve to illustrate that distribution, to whatever angle heat may be applied. If, for instance, the angle a were to be heated, the points of the straight arrows dc, da, would then be directed to a, or towards the point of heat; whilst the feathered end of the former would be directed towards 6, and that of the latter towards the angle d. The central or diagonal arrow would be directed from the angle a to the angle ¢; and in the same way the system of arrows may be considered to be situated with respect to any other heated angle. ‘The system of arrows in fig. 20. will also apply to either of the ends of the metal when uniformly heated between the angles. 113. As both faces of the zinc exhibited thermo-mag- netism of the same character in all the preceding experiments, whatever has been stated concerning those experiments will equally apply to both sides, or flat faces of the metal, and I imagine to all similar masses of zinc. I must here observe, that the electric forces very seldom reach to the cold end of the mass, but approximate thereto in proportion to the ad- vances of heat. They are the most powerful near to the heated point, and become more and more languid as they recede from it, till at length their energies are entirely lost in the more remote parts of the metal. 114. Experiments with Masses of Copper.—Copper is one of those metals, the thermo-magnetic energies of which are not very easily detected in separate homogeneous masses, un- less they be of large dimensions. The most satisfactory re- sults I have ever obtained from experiments on this metal were elicited by a rectangular mass, about two inches thick, and weighing about 95 pounds. ‘This huge piece of copper, which by the interest of Mr. Marsh I was permitted to ex- amine, belongs to the Royal Arsenal. The experiments Hes made Homogeneous Bodies ; with illustrative Experiments. 128 made in precisely the same manner as those described with masses of zinc; and the results, excepting in degree, were ex- actly the same in both metals. The thermo-magnetic energies were very promptly and uniformly displayed in this mass of copper, but were exceedingly feeble when compared to those developed by a mass of zinc less than half its size. With the latter metal, a needle, on which the terrestrial magnetic powers were in full play, could be made to sweep an arch of 100°; whilst with the unwieldy mass of copper, it required the soliciting terrestrial force to be entirely cut off from the needle in order to obtain a sweep of 6° or 8°. 115. There does not seem to be that uniformity in the dis- play of thermo-magnetism by thin metallic plates as is ob- served to be developed by those of considerable thickness. The phznomena, when thin plates are employed, although the metal be neither rolled nor hammered, assume a very ca- pricious character, and appear to be governed by laws which are not easily traced to any general standard. 116. I am not at present prepared to say to what cause these phenomena are attributable: they seem to be of a distinct order, and not referable to the laws of crystallization. They may possibly be traced to a difference in the progress of heat in the several parts of the metal, moving with dif- ferent degrees of celerity in the margin and body or area of the mass. Should this conjecture be correct (and I have some reasons to think that it is true), I imagine that this class of experiments will exhibit a very prominent feature amongst all those, which, from time to time have been advanced for the solution of the highly important problem of terrestrial mag- netism, more particularly in that branch of the inquiry which relates to the diurnal variation. 117. Experiments with Spheres of Zinc.—To carry the ana- logy of experiment still closer to terrestrial magnetic action, I have had cast, globes of zinc of different sizes, with a view of de- tecting some law by which their thermo-magnetic energies are exhibited when heat is partially distributed over the surface of the sphere, in imitation of the sun’s action on the face of the earth. One of these globes is solid, and about 5°54 inches diameter, weighing nearly 23 pounds; another, which is hollow, and 10 inches diameter, weighs 64 pounds, the thick- ness of the metal being about °75 inch. 118. With these spheres I have as yet gained but little information, owing, as I suppose, to the difficulty which I have experienced in keeping the various parts of their surfaces at temperatures sufficiently remote from each other, I have, however, succeded in deflecting a needle by applying to it the R 2 10-inch 124 Rev. P. Keith on the Conditions of Life. 10-inch globe, partially heated, to a much greater angle than any that has ever been ascribed to diurnal variation. This re- sult, insignificant as it may appear, and far from answering my expectations as to the extent of magnetic power developed by the sphere, sufficiently warrants the prosecution of the inquiry. The experiment has demonstrated the existence of the mag- netic power in a homogeneous sphere of zinc, and the deve- lopment of that power by heat. ‘The field of inquiry is thus successfully penetrated, and future investigations may possibly lead to the most interesting results. 119. A sphere of 10 inches diameter, which is the largest I can at present command, is much too small for experiments of this character. With a globe 30 or 40 inches in diameter, experiments might be made on a magnificent scale, and I ap- prehend with the most satisfactory results. A metallic sphere of such dimensions, with the necessary machinery for experi- ment, would require a sum, which perhaps but few indivi- duals would be found willing to lay out on an inquiry which of is more of a national than of an individual interest. Researches of this nature would be the most likely to be successful were they pursued under the patronage of governments, or of wealthy scientific associations. ‘The experiments might then be carried on under advantages the most favourable to insure regularity and uniformity in the results, provided they were conducted under the superintendance of persons who have proved themselves competent to the task. They might also be pursued to an extent which no individual could hope to ar- rive at, and with a success that probably might at once set this sublime philosophical problem completely at rest. Artillery Place, Woolwich. N.B. I have succeeded in magnetizing an iron sphere by means of a thermo-electric combination. The same sphere becomes very highly magnetic when under the influence of the electricity excited by a small galvanic pair immersed in salt water; giving direction and inclination to a magnetic needle, highly imitative of those phenomena as exhibited by the ac- tion of the earth. A description of the apparatus and mode of experimenting will be given in my next communication. XIV. Of the Conditions of Life. By the Rev. Patrick Kriru, [Conc'uded from page 40.] Aliment.— ALL substances capable of affording nourishment to living beings are aliments; and no living being can subsist any great length of time without the use of them. Rev. P. Keith on the Conditions of Life. 125 them. Ifa plant is deprived of the access of the moisture of the soil, it languishes, and withers, and dies. If an animal is deprived for a length of time of all nourishment, a feeling of pain is excited in the region of the stomach, followed by faint- ness and loss of strength, which, without new supplies of food, would ultimately and inevitably terminate in death. As plants cannot range the fieldsin quest of nourishment, it was necessary that some provision should be made to furnish them with due aliment, without any effort of their own; accordingly the Creator has provided that they shall find their food in the moisture of the soil in which they grow. ‘Their food is thus already digested, and they take it up in a fluid state by the slow and protracted process of absorption. Animals, on the contrary, having functions to perform incompatible with a stationary mode of existence, and with the assumption of food by the slow process of absorption, are furnished with the means of taking in, at certain intervals pointed out by the sensation of hunger, a competent supply of aliment in a solid state, which they have the means of digesting, and of preparing for final assimilation.—The food of plants consists chiefly in the moisture which they find in the soil, containing in solution a va- riety of alimentary ingredients. But we have reason to believe that they derive part of their food from the atmosphere also. The leaves attract and absorb the moisture. They inhale also its gases; and there are plants that live and thrive without any other food. The Epidendron Flos-aéris may be quoted as an example.—The food which animals affect is of various de- scriptions according to the species. Some animals are grani- vorous, as many birds. Some are graminivorous, as the sheep and the ox; others are carnivorous, as the lion and the tiger. Man eats almost anything, and drinks almost anything, but he likes to have his victuals cooked. It has been thought that a line might be drawn dividing the animal from the vegetable kingdom upon the ground of the character of the food affected by each. Such, particularly, is the opinion of M. Mirbel*. Plants feed, it is said, upon un- organized substances—earths, salts, water, gases; animals upon substances already organized; that is, either upon other animals, or upon vegetables.— We do not regard it as a very good, ora very correct rule. Animals thrive well upon milk alone, which is not an organized substance. If you say that it is the product of an organized being, let it be remembered that it is also a very good food for vegetables. In short, the chief food of plants as well as of animals is either animal or vegetable sub- stances in a state of solution; and though animals may feed * Traite d' Anat, et de Phys, veg. upon 126 Rev. P. Keith on the Conditions of Life. upon substances that are still in an organized state, yet they cannot convert them into nourishment till they have destreyed their organization in the stomach. Is it certain that all animals require a food that has once been organized?) What is the food of Cancer salinus ? A better criterion for distinguishing the animal from the plant will be found in the attribute of sensation. For though there may be some phenomena that give countenance to the idea of vegetable sensibility, yet they are not such as the phy- siologist can confidently rely upon; and as the attribute of sensation distinguishes the animal from the plant, so their as- sumption and assimilation of aliment, and their origin and mode of growth, will distinguish them both from the mineral. If this last criterion had been kept in view, the noted definition of Linnezus would have been less incorrect: “‘ Lapides crescunt ; vegetabilia crescunt et vivunt ; animalia crescunt, vivunt, et sen- tiunt*,”—Stones grow; plants grow, and live; animals grow, live, and feel. But the truth is that stones do not grow in the sense in which plants and animals grow; not by the intro- susception and distribution of aliment throughout their whole substance, but merely by the apposition of new particles added to the external surface. In this respect the definition is faulty. In other respects it is perhaps well enough; and in brevity and decision of tone it will not be easily surpassed. Upon the principle which we adopted in our definition of life, namely, that of a copious enumeration of particulars, I submit the definitions that follow, with a view to mark out the boundaries of the three kingdoms of nature :—A mineral is a mass of lifeless matter, inorganic, inert, insentient; not aug- mentable by nutrition, but attaining its bulk merely by the external and mechanical or chemical apposition of new parts or particles.—A vegetable isa living and organized body, inert, insentient; springing from and producing a germ that is aug- mentable by nutrition; and fixed, by a root, to the soil, from which it absorbs its principal nourishment already in a fluid state.—An animal is a living and organized being, self-moving, sentient; springing from and producing a germ that is aug- mentable by nutrition, and ranging in quest of aliment, which it takes up chiefly in a solid state, and subjects to the action of digestive organs. There are assignable limits, then, which separate the three kingdoms of nature; between the mineral and vegetable, orga~ nization ; between the vegetable and animal, sensation. In an unorganized body there is no community of interests among the different parts, and no part that is necessary to the well- * Philosophia Botanica, 2. being Rey. P. Keith on the Conditions of Life. 127 being of any other part. Cut or chop off any portion you please from a block of marble, and the remaining portion shall know nothing of it. In an organized body, every organ is use- ful to every other organ, and no organ is made for the sake of itself alone. Each sympathizes with all the rest, and each has a common interest in the welfare of the whole. The aliment which a plant or animal takes up it distributes to every member. Manure and water the root of a plant, and the leaf and flower will soon give indications that they participate in the benefit conferred; lop it severely, and the branches will suffer.—Give toan animal its due supply of food, and every organ is refreshed. Cut or chop off from it a limb, or part of a limb, and you ex- cite a sympathy throughout the whole fabric, with a feeling of pain and of injury expressed by cries, or manifested by con- tortions of body. . Yet the limits separating the several kingdoms are not, in all cases, conspicuously displayed.—Look at the lower orders of vegetables—the algze, the fungi; and in some of them it is with difficulty that you can discern even the faintest traces of organization. A mere crust adhering to the surface of a rock, as In the case of many of the lichens; or a mere mass of jelly _ covered with a fine epidermis, as in the case of many of the tremellz, is all that you have for a plant. It is but little ele- vated above the level of the mineral.— Look at the lower orders of animals, and you find the same want of characteristic marks among them. ‘The organization of a polype seems to be but iittle beyond that of a tremella: but its power of loco-motion, which is evident, and its capability of sensation, which is pre- sumptive, are tokens that indicate its superiority to the plant. As you advance to the higher orders of vegetables, the orga- nization begins tobe more complex, and the plant more perfect; and thus you rise through the several orders till you reach the highest and most perfect of all, producing root, stem, branch, leaf, flower, and fruit, in the perfection of their kind, and giving indications of organic and living function, and of the process of internal nutrition, in the absorption, elaboration, transmis- sion, and distribution of alimentary fluids in peculiar and ap- propriate vessels. As you advance to the higher orders of animals, the organization begins to be more complicated also, and the animal more perfect, establishing the physiological maxim—that of all organized beings, whether plants or animals, the perfection of the individual is in the direct proportion of the complexity of its organization. Hence the organization of the animal is soon found to surpass in complexity that of the vegetable. Both havea variety of organs in common— tissues—the cellular, the lamellar, the vascular, the fibrous. Both 128 Rev. P. Keith on the Conditions of Life. Both have an alimentary and a sexual apparatus; for both grow and propagate their kind. Both have an apparatus for the propulsion and distribution of fluids, which they have the capacity of assimilating to their own substance.—But animals have additional faculties, and the additional faculties in ques- tion have their source in additional organs; while the organs conferred correspond to the wants of the individual. The food of the plant is already digested ; but the animal has its food to digest. Hence the necessity of a stomach. ‘The plant is sta- tionary; but the animal moves. Hence the necessity of a muscular apparatus. The plant is insentient; but the animal is endowed with the faculty of sensation. Hence the cerebral system, the source of thought, perception, consciousness, me- mory, volition, loco-motion. In the lower orders of animals these additional properties are not very distinctly marked ; but as you ascend the scale, they become more and more visible till at last you reach man, in whom they exist in the highest degree. Aeration.—No living being can thrive, or even continue to exist, without the access and contact of atmospheric air. The seeds of vegetables will not germinate if placed in vacuo. Ray introduced some grains of lettuce-seed into the receiver of an air-pump, which he then exhausted: they did not ger minate, but they germinated upon the re-admission of the air; which shows that access of air is a condition necessary to the germination of seeds*. The experiments of Homberg seem indeed to militate somewhat against this conclusion. They are recorded in the Memoirs of the French Academy for the year 1669; and the inference deduced from them is, that seeds in general do not germinate if deprived of atmospheric air; but that cress-seed, lettuce-seed and a few others will germi- nate even in the vacuum of an air-pump. But the same ex- periments when repeated afterwards by Boyle, Muschenbroek, and Boerhaave, with a much better apparatus, did not confirm the latter part of the result. On the contrary they all tended to prove that no seed germinates in the vacuum of an air- pump, and that in the cases of germination mentioned by Homberg, the vacuum must have been very imperfect. ‘The same experiments were again repeated by Saussure the younger, who says that the seeds of peas gave indications of germination in vacuo in the course of four days, but never effected any de- velopment of parts beyond the mere protrusion of the radicle+. — We conclude, then, upon the whole, that in a perfect vacuum no seed will germinate; but that in the most perfect vacuum hitherto formed by human art, some seeds may germinate. * Phil. Trans. No. xiii. + Saussure sur la Vég. chap i, sect. 1. The > Rev. P. Keith on the Conditions of Life. 129 The same condition is necessary to the vegetating plant. Grew having discovered, in a leaf that he was examining, a number of little bags or bladders, filled as he thought with air, drew the conclusion, and maintained the doctrine, that leaves are the lungs of plants. M. Papin, with a view to as- certain the point in question, introduced into the receiver of an air-pump an entire plant, root, stem, and leaf: the con- sequence was, that it very soon died. He then introduced a plant by the root and stem only, with the leaves and branches exposed to the influence of the atmosphere: still the plant died after a while; but it lived much longer than in the former case, and warranted him in concluding, as he thought, that leaves are indeed the lungs of plants*. Whether this conclusion was legitimately drawn trom the premises, or noi, we will not at present stop to inquire. Enough was done to show that plants cannot continue to live without the access and contact of atmospheric air. They will not even grow with vigour unless they have an abundant supply; as he who has the ma- nagement of a hot-house too often discovers to his cost. The plant that grows where there is no free circulation of air springs up slender and sickly. The plant that is exposed to the action of the stormy blast springs up stout and robust. Of the truth of the same conclusion as applicable to animals, it will scarcely be necessary to offer any formal proof. It comes so completely home to every one’s own experience, that he must be a bold man who would deny it; yet if proof were wanted, it would be found in the death of many a poor mouse that has been placed in the receiver of an air-pump for the purpose of experiment. There are, it is true, some apparent exceptions to the above rule. It has been said of the Truffle, that it vegetates without the access of air, because it vegetates wholly under ground. But it is very well known that air penetrates the soil toa depth beyond that at which the Truffle is found. It does not there- fore vegetate without aération. For the same reason it has been thought that the roots or bulbs of plants whose stem dies down to the ground in the winter must needs vegetate without air. But air is conveyed to them in the moisture of the soil; and of some of them it may be said that they hybernate rather than vegetate in the winter: at any rate they are not deprived of the access of air+. But itis in the animal kingdom that the excep- * Phys. des Arb. liv. ii. chap. 3. + [We may add, in confirmation of this reasoning, that it has been shown by Mr. Bowman, (Trans, of Linn, Soc. vol. xvi. p. 413, &c.) that the squa- me of the subterranean stem of Lathraa squamaria are real leaves and organs of aération, But the same botanist remarks, that Cuseuta, Listera N.S. Vol. 10. No. 56, Aug. 1831, S Nidus 130 Rev. P. Keith on the Conditions of Life. exceptions are the most striking;—not in the department of Fishes, though their element is even the water; but in that of the Amphibia. Live toads, snakes, and lizards have been found imbedded in solid masses of stone, or of coal, at a great depth below the surface, and without any possibility of the access of air*. They are facts occurring about as often, and are about as well authenticated, as the sight of a mermaid. We cannot well refuse our assent either to the one or the other; and yet we cannot give it without a sort of sceptical reluctance. Yet if the fact in question is anything different from that of a long protracted hybernation, we are altogether without the means of accounting for it. Temperature.—The phzenomena of life have never yet been exhibited except within a certain and limited range of tempe- rature. ‘Too great a degree of heat, or too great a degree of cold, is equally injurious to it. Ata very low temperature, as towards the poles, plants and animals are often frozen to death. Ata very high temperature, as at the equator, they are apt to perish through excess of heat. But they have the capacity of preserving their due temperature under the influ- ence of many opposing causes. In the midst of the frosts and snows of winter, plants maintain a temperature which is always above that of the surrounding atmosphere; and even under the burning heat of a vertical sun their temperature is never raised very high. But different plants affect different tempe- ratures, and you cannot well naturalize them in climates to which they are not indigenous. You may indeed have all varieties of them in the same latitude; but it shall be in the conservatory, or in the hot-house, and if not, it shall be at different altitudes. ‘Tournefort noticed this fact, in the case of the plants growing on Mount Ararat; and Humboldt gives us a similar account of the vegetation of the mountainous dis- tricts of South America. In ascending the Andes within the tropics, oranges, pine-apples, and all manner of delicious fruits and vegetables, are found on the lower grounds. Maize, plantains, indigo, cacao, at an altitude of from 3000 to 5000 feet. Cotton, coffee, sugar, at the same altitude, but ascending still higher. Wheat, and other European grains, together with the oak and other forest trees, at the altitude of from 6000 to 9000 feet. The pine still lingers at an altitude of 13,000 feet above the level of the sea. From 13,000 to 15,000 feet, you have grass and lichen, which last creeps up still Nidus Avis, Monotropa, and Orobanche, are destitute of true leaves, and are consequently incapable of drawing sustenance from the atmosphere. These latter plants, therefore, appear to present real exceptions to the rule here vindicated by Mr, Keith.—Epir. | * Phil. Mag. March 1817. . higher, Rev. P. Keith on the Conditions of Life. 131 higher, adhering to the surface of the porphyritic rock, and insinuating itself even under the perpetual snow *. Similar observations are the result of our inquiries into the animal kingdom. The bear is a native of the polar regions. The elephant, lion, and tiger are indigenous only to countries near the equator. A forcible and sudden change of climate would be fatal, we may believe, to either. For although bears, lions, and elephants are found to live in countries of which they are not natives, it is only under the protection and fos- tering care of man. Man lives in almost all climates, but not with equal comfort. He can accommodate himself to cold climates by means of clothing; and to warm ones by going without it. The Greenlander inhabits regions bordering on 80° of north latitude, where the mercury freezes in the ther- mometer, that is, at 40° below zero; and yet the temperature of the blood never falls much below 96° of Fahrenheit. ‘The negro lives under the hot and burning suns of the torrid zone, and yet the temperature of the blood never rises much above 96°. Further, plants and animals seem to be endowed with extraordinary capabilities in extraordinary circumstances. On the banks of a thermal river in the island of Lugon, the largest of the Philippines, Sonnerat found the Aspalathus, or African Broom, and the Vitex Agnus-castus growing, and, as we may suppose, thriving, though their roots were swept by the water at a temperature of 174°. In Italy Conferve are are said to be found occasionally in the thermal springs, though heated even to the boiling point. In the above island of Lugon, Sonnerat saw fishes frolicking in a hot spring of the temperature of 158°. Inthe province of Quito in South Ame- rica, Humboldt saw fishes thrown up from the bottom of a volcano, together with water and heated vapour, that raised the thermometer to 210°. This was quite high enough to have killed and boiled European fishes; but the fishes in question were still alive. Wonderful as the above relation is, it is surpassed by the following facts. In 1760 when Du Hamel and Tillet were conducting some experiments that required the heat of an oven, a girl was found who offered to go into it, to note the height of the thermometer, and who performed her task with the most perfect nonchalance ; the mercury standing, ultimately, at 288°. The curiosity of philosophers being roused by the announcement of this fact, Sir Charles Blagden, Sir Joseph Banks, and some other men of science exposed themselves to a heat, first of 220°, and afterwards of 260°, without suffering any particular inconyenience. ‘The pulse was quickened to 140 beats in a minute; water was boiled and beef-steaks were * London Encyclopedia, Andes. + Library of Useful Knowledge. S 2 dressed ; 132 Rev. P. Keith on the Conditions of Life. dressed; and yet the temperature of the body never rose be- yond 101° of Fahrenheit*. Thus there is in plants and in animals something that resists and controls the influence of chemical agents, and that something is the attribute of life. The dead animal substance, the beaf-steak, was broiled, but the living animal substance remained unaffected. Connected with temperature we have the very singular phze- nomenon of the hybernation of plants and animals, that is, of some peculiar species of them; for all plants and animals do not hybernate. The state of hybernation is a state of tor- pidity, induced by a low temperature, and lasting till the colds of winter have gone. ‘The living functions are suspended. In plants there is no absorption, no nutrition, no flux of juices. In animals, there is no respiratien, no assumption of aliment, nor circulation of fluids; or, if this last process is at all carried on, itis inthe most languid manner. Yet life is not extin- guished ; it is not even injured,’ but rather it is preserved from accidents that might be fatal to it; and when the return of spring restores again the due temperature, the individual resumes its living functions, and its hybernation ceases. Among plants, the bulbous-rooted are said to hybernate, and the bulb is regarded as being the winter-quarters of the future plant. ‘They do not however hybernate in the strictest sense of the term; for if you leave them in the soil for the winter, and inspect them now and then, you will find traces of the growth and development of the infant plant, even in the season of hybernation.— But the hybernation of animals is the most complete. In them the living functions are really and truly suspended, and no traces exhibited of the growth of parts. The snake, the dormouse, the swallow+, the bat, are examples of hybernating animals. They roll themselves up into the smallest compass possible, and, as it may best suit the species, take up their winter-quarters in the earth, or in clefts of rocks, or in holes of walls looking to the south. If you detect them in their hiding-place, you may handle them or pinch them or roll them about; and they shall know nothing of it till they are exposed to the influence of a gradual warmth. ‘Their torpor is said to be the most profound at the temperature of from 5° to 7° above zero. If they are sud- * Phil. Trans. (abridged by Hutton), vol. xiii. p. 695. + Much has been written about the annual disappearance of swallows ; some maintaining that they hybernate; others that they merely emigrate. It is certain that such stragglers as have not joined in the general flight do actually hybernate. This [ can affirm with confidence, from the fact of my having once found, in the midst of winter, a solitary swallow, in a torpid state hybernating under the thatch that covered the ridge rafter of the roof of a carpenter's shop. It revived upon being exposed to the warmth of a fire; but the weather being still too cold, it soon died. denly = —— Rey. P. Keith on the Conditions of Life. 133 denly exposed to a temperature that is either much lower or much higher, they are roused indeed into life, but the expo- sure kills them. The natural and gradual increase of return- ing solar heat is that which suits them the best.—Thus the attribute of life preserves them even in hybernation, and is ready to give them fresh activity when the due temperature returns. Death.—By an irreversible decree of the original Giver of life, every living being must submit to the stroke of death, which is, as we have already observed, an extinction of all living function, and of all possibility of living function. ‘There is no exemption, there is no escape. ‘There is no way of eluding the grasp of this ghastly King of Terrors;— mors nescia flecti ;—mors ultima linea rerum. It seems a hard condition, because it deprives us of all we hold dear. What a boon, what a blessing is life! And what would a man take in exchange for it?—Even vegetables seem to be conscious of its value, though we regard them as being destitute of the faculty of sensation. In the “fine frenzy” of the poet, the trees of the forest are made to rejoice, and corn-covered valleys to laugh and to sing*. Much more is the blessing of life cognoscible by animals who are endowed with organs of sense and of feeling.—See how the tender lamb frolics in the enjoyment of its newly acquired existence !—See how the birds wanton in air !—See, above all, how man appreciates the value of the gift;—and see his “longing after immortality,”’—when parti- cipating, freely, in the gratifications which life presents, he reflects upon the plenitude of its delights, and mingling reli- gion with his mirth, ascends in holy meditation to the idea of a kind Creator, and even to the glories of a future world. However, life is liable to many accidents that tend to cut short the thread by which we hold it. Wounds, diseases, poisons, are often fatal to the life of man, as well as to other animals. A violent blow on the temples will extinguish life in an instant. Plague, pestilence, and famine, will speedily produce the like effect; and a few drops of concentrated prus- sic acid introduced into the animal circulation will cause almost immediate death. But if the individual should fortunately escape all fatal accidents, still a term will come beyond which life cannot be protracted; still it will be worn out at last by a natural and gradual decay.—Observe its progress in the plant, and the symptoms of approaching dissolution. ‘The root re- fuses to imbibe the nourishment afforded by the soil. The juices are but feebly propelled, and their assimilation effected with difficulty. The bark becomes thick and woody, and co- vered with moss or lichens. ‘The shoot becomes stunted and * Psalm Ixy, diminu- 134 Rev. P. Keith on the Conditions of Life. diminutive; and the fruit palpably degenerate, both in quantity and quality. ‘The terminal branches fade the first, then the larger branches, and then the trunk and root. The vital energy of the fabric languishes, and is at last totally extin- guished; and the plant, now exposed to the chemical action of surrounding substances which it cannot any longer resist, withers and dies away, presenting to the eye a decayed and rotten appearance, and crumbling into the dust from which it originally sprang.—Observe its progress in the animal, and you will find that the symptoms are of a similar character. It has been said indeed of man, that it is the body only, and not the mind, that suffers decay and death. But it is evident that the mind is liable to decay and to death as well as the body. If the organ perishes, its function must inevitably perish. Ifthe brain dies, its function—mind—must cease. As well might you expect that digestion should continue when life has left the stomach, as that mind should continue when life has left the brain. If the eye becomes dim, and the ear dull of hearing, and the palate incapable of tasting, and the nostril devoid of smell; so the memory becomes weak, the judgement erroneous, the understanding embarrassed, the will slow in its decisions, and the organs that are subject to it slow in their obedience; inducing “second childishness and mere oblivion;” and exhibiting man in his state of dotage “sans mouth, sans teeth, sans eyes, sans every thing.” It is but a step further to the total extinction of life, and cessation of all living function; that is, in other words, to the death of both the body and the mind. During life, all was activity, all was vital, or spontaneous motion, all was the exercise of organic function. In plants, absorption, assimilation, and distribution of fluids, with growth and development of parts. In animals, prehension, digestion, and assimilation of food; with growth, loco-motion, intellec- tion; and in man the faculty of speech ;—all referable to the agency of that subtle, invisible, and incomprehensible some- thing called life, which counteracts and controls mechanical and chemical agencies, and converts them to its own purposes. —If I move my arm from the pendant position, and raise it to a horizontal or upright position, the agency of gravitation is counteracted. If the materials that compose the living fabric do not tend to putrefaction, the agency of chemical affi- nities is counteracted. But in death there is no longer any resistance opposed to these agencies, no living action, no spon- taneous motion, no exercise of organic function: in short, the fabric is no longer a living system. Chemical and me- chanical agencies affect it merely, exerting themselves in their full strength, and reducing it, sooner or later, to the panera an Mr. Innes’s Correction in the Nautical Almanac for 1833. 135 and elementary principles out of which it was originally formed. Sleep has been said to be the image of death. But it is only a transient suspension of some of the functions of life. The exercise of function fatigues the organs, and hence they require a period of repose. Such is sleep, which lasts only till the fabric is recruited. NHybernation might be said to be the image of death also; but it depends entirely on tem- perature. When the temperature sinks to a given degree, hybernation begins; and when it rises again to the same degree, the exercise of function is resumed. But if death once super- venes, its dominion is perpetual; and its empire not to be es- caped from. It is “the undiscovered country from whose bourn no traveller returns’—the “‘cheerless night that knows no morrow.” Omnes una manet nox, Et calcanda semel via lethii— Hor. Ode 28. lib. i. that is, as regarded in a physiological light; for the morning that is yet to “dawn on the night of the grave” we are not taught to look forward to as a consequence resulting from the established order of things, but as an event emanating from the fiat of the Almighty*. Thus the phenomena of life and of death are plainly and palpably distinct. ‘They are opposite, and irreconcilable, and cannot be mistaken. Life composes, death decomposes; life rears a fabric, death destroys it; where life extends, the inte- grity of the fabric is maintained; where life ends, decomposi- tion with putrefaction begins. Such is the victory achieved by death, and the inevitable doom of every thing that lives. Ruckinge Rectory, Kent, April 26th, 1830. P. Keiru. XV. On the Statement in the Nautical Almanac for 1833, of the Time of Beginning of the Solar Eclipse of the 16th of July in that Year; together with the correct Times of that Eclipse, computed for Greenwich. By GrorceE Innes, Esq. To the Editors of the Philosophical Magazine and Annals. Gentlemen, JN the Nautical Almanac for 1833, I find the beginning of the solar eclipse of the 16th July, stated to be at 16" 5™ It appears to me probable that the units and fraction of a minute have fallen out in printing. About four years ago, I calculated the times of the above eclipse for Edinburgh and Greenwich Observatories, using Delambre’s tables of the sun, * (John y. 28, vi, 39, 40, Rom. vi. 23, 1 Cor, xv. 36, 44, 51,—Eprr.} and 136 Further corrections in the Nautical Almanac for 1833. and Damoiseau’s Lunar Tables of 1824. The times which I obtained for Edinburgh were inserted in Professor Jameson’s Journal for October—December 1828 ; and the following are the results for Greenwich. According to Burckhardt’s tables the times are about 19°5 seconds earlier. Bessel’s corrections of the Solar Tables had not reached me when I made the computations. Mean time. Apparent time. D HH. M. Ss. H. M. s. The eclipse begins, July16 17 4 5:8 16 58 23:0 Greatest obscuration — — 17 55 4% 17 49 21:2 App' ecliptical conj” — — 17 58 16°6 17 52 33°6 End of the eclipse .... — 18 49 21:9 18 43 38:7 Digits eclipsed at greatest obscuration, 8°" 47! 48!-3 on the north part of the sun’s disc. The moon will enter the sun’s disc on the west limb at 37° 12’ 20” from his vertex, in reference to the horizon. I am, Gentlemen, &c. Aberdeen, April 27th, 1831. GrorceE INNEs. XVI. Errata in Schumacher’s Ephemeris of the Distances of the four Planets Venus, Mars, Jupiter, and Saturn, from the Moon’s Centre, &c. for 1833, published by the Admiralty. By A CorRESPONDENT. “ee following errata have been kept back for some time, and would have been reserved for publication in the Nautical Almanac for 1834, but that the advantage resulting from the discovery of them would be diminished by the delay. Page. “ fo} i il 9. Sept. 17. xxi"... for 105 515 read 100 5 15 17. May 2. ——..... -— 88 44 29 88 44 29 18. May Bl eeiK eee -— 69 339 —— 109 2 39 46. Jan. 22. Log.dist. — 0°95266 —— 0:05266 Bl. June Qs. ccccccccenes ——) 5D AD’ 4. V——— — 54842 de 56. November 1. November 30. Dec. S. GS MINCE Disseessse odes jor 35 6 20°2 — 3. 62032 66. September 20. ... — 9 42 37°7—— 9 22 37°7 68. November % ...... — 12 33 53:°9-—— 12 43 53°9 75. June 30. 76. July 31. Hrs Ni 77. August 31. 88. July 19. Log. dist. for 0°63651 —— 0'69651 98. May $1. nh id 55110. No. —et DEB bd LON 99. June 7. Log. dist. — 6:97029 —— 0'97029 110. May Llescrcccceeee —= 322 2646 —— 322 27 46 Chislehurst, July 1, 1831, ) XVII. On wa 7iAl XVII. On the Theory of Differences, by SAMUEL SHARPE, Esq. F.G.S.* Prop. LPO interpolate a maximum or minimum in a series, by means of the theory of differences. This perhaps may be useful on many occasions, in practical astronomy, when the observer has a series of altitudes at equal intervals, without all the data, such as time and latitude, ne- cessary for the more rigid formula. As for instance; From a series of altitudes near the meridian, to find the meridional altitude and approximately the time of transit; which is a far more accurate method than that commonly used by sailors, of watching the sun’s ascent till it becomes stationary, which gives the time of noon with extreme inaccuracy, and the me- ridional altitude single and uncorrected by others. And again; From a series of declinations near the solstice to determine the solstitial declination. To explain the signs make Quantities First Second Third observed. | Difference. | Difference. | Difference. and w’ and /' the quantities sought. : By a well-known formula in the theory of differences, we ave rAd (pl 4 7 aa 1__9 ut Aly =a =ut+ = Aut eB Atu+ Ee aeame: and by expanding and rearranging, [1] AN us (4 Amu Abu Adu he? baw A’a ILAtuy h (Aru Aru Bary Ae a ts hea et BTN hit Atu Aa [2] which for convenience we will write Als Fie (3) and if we consider this value of « as a maximum, we may make two equal values, one on each side of it; viz. ! ! I ! nau (“P04 (2) + (“F*)c4 (A) > 4 * Communicated by the Author. N.S. Vol. 10, No, 56. Aug. 1831. 4 ly and }! ji h'8 W=u+5-A+—5,B4+5-C+4 138 Mr. S. Sharpe on the Theory of Differences. and h'—a h'i—a h'—a h’—a u=u+( . )a+( : ) B+ ( = \c+ ( 5 ) Dis] by expanding the binomials and subtracting one equation from the other, we have QaA 4ah'B . 6ah?+2a° 8ah*+ 8a? h! Cas: Lae! — then dividing by =, and, as a may be infinitely small, re- jecting those terms which then involve a, ‘ Aa }! B jl C Ae O=A+—-2B+ 558 aby 5 wae Jee whence by Newton’s method of reversing a series, we have h! A 8 A?C A’ Ss at gE hg eee ! when w’ is a maximum; and with this value of = we shall know from our original equation the value of w! as a maximum. As an example I shall take the following declinations of the sun from the Nautical Almanac for 1829. June 19 | 23°26! 30” 43! 20 | 23 27 13 — 24! + 19 — } 21 | 23 27 32 ‘ — 25 5 + 1" 22 | 23 27 26 $i — 25 23 | 23 26 55 in which A = +544, B= —11", C= —0"38. D being +005 may be neglected. U es = 2°46 — 0°31 + 0"-24, and h’ = 2 days 9° 15", being three hours wrong; and ul = 130" — 62"-8 — 49 4+ u = 23° 27! 33!"3, being 0'*5 wrong. These results are as accurate as could be expected, consi- dering the original values of « do not contain tenths of a se- ! cond; and if the value of = had been known from other data, the resulting value of u’ would have been exact. Prop. Mr. S. Sharpe of the Theory of Differences. 139 Prop. I1.—To determine the point of contrary flexure in a curve; or to interpolate a term in a series, such that its second difference is = 0 by means of the theory of differences. Instead of w+, as in the former Proposition, we now have u+u : : Ut Ms = yl, Consequently by expanding the three equations [3] [4] and [5] we have 3a°h! 16h” a? + a* BS Lae NAESR a whale a’ Oe “We Dividing by 77> and rejecting the terms then containing 4, }! hi? we have o=B+—>-3C+-—, 6D Le, Bp, GD pay ae 27 C and hence we have in equation [1] the value of w’. By this proposition and a series of altitudes of a star in the east or west, we may deduce the time of its passing the prime vertical, and its altitude when there. Hence if P be the hour-angle at the pole, L, the latitude of the place, A, the altitude on the prime vertical, D, the star’s declination, ; cos A : sin D sin P= con Ti and sin L = aa Prop. I11.—From a set of observations made at equal in- tervals to obtain one more correct, corresponding to the mean of the times. Or it may be stated, To correct the mean of a set of observations by help of the theory of differences. Let there be seven observations; then (See Baily’s Tables.) + A®*u u+3Au + SA*u + A®u u+4Au + 6A?u + 4Ar%u u,=u +5AuU + 10A2u + 10A%u te=u+6Au + 1l5A2u + 20A*%u neglecting the higher differences. Now the mean of these quantities gives us U, = t + S$Au + 5A*u + SAU, which is evidently too great by 2 Aru + 4 Abu. T2 Hence Rg hu udu ua S ae ro > S 140 Mr. S. Sharpe on the Theory of Differences. Hence, with seven observations, uw; = mean of observations —2 mean of second differences , and thus we may construct the following table: Number} Mean Quantity of Obser-| of the eaueht Value of Quantity sought. vations.| ‘Times. ae 1 |m “a ... | The observed quantity. 9 |m+ a ay Mean of observation. 2 3 |Im+h uy Do. —1 mean of A? 3h d 4 |m+ Us ses | Do. — mean of A® 3} 2 Bay NT A, Veg. vane Do. — mean of A? 5h 2 Ge tge ls Do. —3 mean of A®* 7 |Im+3h| ws o Do. —2 mean of A® Remark,— This proposition may be used on all occasions to which the rule is applicable, that “ by a single observation is meant the mean of a series,” (see Requisite Tables, Baily’s Tables, &c.) and in particular in learning the time from a single altitude observed ; when we consider that many persons have occasion to learn the time, who have neither instrument to observe a transit, nor leisure to take equal altitudes. Prop. 1V.—From an observed place of the moon, and four given places in the Nautical Almanac, to determine the time at Greenwich. This is I believe not in general solved analytically, but syn- thetically ; thus, ist, Assuming the time at Greenwich, by help of the differ- ence of longitude known approximately. 2ndly, By the theory of differences determining the moon’s place by equation {1}. I lpi Vale 5 Fau peeeh A?u + 3rdly, Thence correctly the assumed time. This equation is computed more conveniently by means of tables of the coefficients of A, A® and A’, but if such tables are not at hand would be more easily computed in the form [2]. Aru A*) as on) + (“). h! (h!—h) (h! —2h) Tae. ee q +73 1 a a a ie a a . i! Au= F(ax- oe og But Prof. Airy’s New Optical Experiments. 141 But it would be more accurate to solve the proposition by di- rect analysis; and writing this last equation as before, hl? he —- C. }! h h? By reversing the series, we have Ht hu (ay HB ak bar Sih) Ae Mow A Baia) Remark.—The rule given in the Nautical Almanac is ac- cording to equation [1], but upon the supposition that the tables are not accurate beyond A’u, and consequently that Aeu+ A*u, A*u ought to be = 0, and therefore 2 is used in- stead of A®u: thus h' ih —h) 7 KRut+A ru ES = Aut a = ( Seta but now that the tables are sufficiently accurate it would be better to use Aru. And hence it seems to me that Mr. Baily has committed an oversight; for wishing to introduce A*w, he has still employed 9 2 Aetan, which was used only on the supposition that A%u ought to be neglected, and has written }! (h'—hy A? ut A®uy hi (h'—h) (h'—2 hy 2h ( 2 ) + 6A at, corrected in the Errata to Bh —h)/ Aut A2u,\ . #! (h!—h) (h!—3 h) oT 3 )+ 6H atu instead of equation [1]. i! ul =u+ >- Aut Al wut > Au+ XVIII. New Optical Experiment by Professor Airy. [We are indebted to the kindness of a Cambridge friend for the following account of some new optical experiments made by Professor Airy: it announces some remarkable dis- coveries, which have an important bearing in the verifica- tion of the undulatory theory of light.) AN instructive variation of the experiment of Newton’s co- loured rings (suggested by the consideration of Fresnel’s formula for the intensity of reflected vibrations) has lately been made by Professor Airy. When a lens is placed on a plane 142 Prof. Airy’s New Optical Experiments. plane glass it is well known that a set of rings is seen whose centre is remarkably black: and it is indifferent whether com- mon light or polarized light be used, the only difference made by the latter being that when the plane of polarization is per- pendicular to the plane of reflection, and the angle of inci- dence is the polarizing angle, the rings disappear; but on altering the angle of incidence either way, the rings still ap- pear with the centre black. If, however, a lens is placed on a metallic surface, and the incident light is polarized in the plane perpendicular to the plane of incidence; while the angle of incidence is small, the centre of the rings is black; when it is equal to the polarizing angle of the glass the rings disappear (though there is still copious reflection from the metal): then on the smallest increase of the angle of incidence the rings are seen with their centre white, and they continue so till the angle of incidence = 90°. It is indifferent whether the light is polarized before or after reflection; and a remarkable effect may be thus produced: if common light is incident at an angle greater than the polarizing angle, the rings have a dark centre; but on placing a plate of tourmaline (with its axis perpendicular to the plane of reflection) between the eye and the lens, the rings are seen with a bright centre. The Pro- fessor conceives that the whole of these experiments are in the highest degree favourable to the theory of undulations with transversal vibrations as given by Fresnel, and to the idea (which is a necessary part of that theory) that polarization is not a modification or physical change in the light, but a reso- lution of its vibrations into two sets, one in one plane, and the other in the plane perpendicular to the former, one of which sets sometimes is suppressed and sometimes describes a dif- ferent path. The last experiment (where the character of the rings is changed after they are formed) appears almost de- cisive of this point. From the manner in which the rings alter when the tourmaline is turned, the Professor infers that the phases of the vibrations in the plane of reflection are more accelerated by reflection at metallic surfaces than those of the vibrations perpendicular to the plane of reflection. The dark centres, it is to be observed, are never so dark as when the lens is placed on glass; and the bright ones are never very bright. The result of the following experiment, like those of the former,was anticipated by theoretical considerations, and shows the clearness with which, by Fresnel’s theory, the effects of modifications can be traced whose very nature is inexpressible on any other theory. In the common polarizing apparatus, plane- Geological Society. 143 plane-polarized light is incident, and the light emerging from the interposed crystal is resolved into two streams of plane- polarized light (by the analysing plate), of which one only is transmitted to the eye. It is known that circularly or ellipti- cally polarized light will, if incident on the crystal, form rings ; but it has not been remarked as a general theorem, that rings will be visible if the analysing plate be so constructed as to resolve the light emerging from the crystal into any two kinds of light, of which it suppresses one and transmits the other to the eye. Now by means of Fresnel’s rhomb, or (imperfectly) by a film of mica, the analysing plate may be made to resolve the emergent light into two circularly-polarized rays, one of which it transmits to the eye, while the other is suppressed. Supposing the light to be thus analysed and supposing the incident light to be circularly polarized, theory gives this result: the tint will depend only on the gain or loss of the extraordinary on the ordinary ray: there will be no brushes: the appearances will not alter as the crystal is turned about the incident ray. These conclusions are completely supported by experiments on uniaxal and biaxal crystals and unan- nealed glass. Iceland spar, for instance, shows rings without brushes: nitre, &c. exhibit the lemniscates in their whole ex- tent without any interruption. Cambridge, July 25, 1831. XIX. Proceedings of Learned Societies. GEOLOGICAL SOCIETY. June 8th,— A LETTER was read, from Joshua Trimmer, Esq. to the Rev. Dr. Buckland, V.P. G.S. “On the diluvial deposits of Caernarvonshire, between the Snowdon chain of hills and the Menai strait, and on the discovery of marine shells in diluvial sand and gravel on the summit of Moel Tryfane, near Caernarvon, 1000ft above the level of the sea.” The object of this paper is to point out evidences of extensive dilu- vial action in that part of Caernarvonshire which lies at and near the N.W. base of the mountains of Snowdonia. This district is traversed in adirection from N.E. to S.W., and nearly parallel to the mountain chain, by two remarkable beds of roofing slate, well known by the name of Penrhyn Slate, dipping usually to the S.E. at a considerable angle, and extending along a series of hills of moderate elevation, between the Snowdonian chain and the Menai strait. Great part of the surface of these hills, and of the still lower ground between them and the Menai, is so covered by accumulations of drifted gravel, sand and clay, that the slate is seldom accessible, without first penn own 144 Geological Society. down through a thick bed of this diluvium. It occurs, not only in the valleys, but on the sloping sides and summits of hills, sometimes en- tirely covering the hills, at others accumulated around small project- ing crags. It is spread indiscriminately, and with little reference to the rivers that now intersect the country: its greatest observed thick- ness is about 140ft. A large proportion of this gravel is composed of pebbles and blocks of various sizes, derived from rocks that occur in Caernarvonshire ; many of these are less rolled than pebbles of another class that are mixed with them, and which have come from a greater distance, and must have been drifted upwards by some violent inundation, in a direction contrary to that of the rivers which descend from Snowdonia into the Menai. Among these pebbles are several which can be iden- tified with the granite, sienite, green-stone, serpentine and jasper of Anglesea: other granite pebbles agree with no rock in Anglesea or Wales, and resemble the granite rocks of Cumberland; some may have come from Ireland or the S.W. extremity of Scotland. There are also chalk flints, which can have come from no nearer source than the chalk of the county of Antrim. This diluvium occurs in great thickness in the lower region of the valley of the Ogwen, usually from 60 to 100ft; forming its bed, and often occupying both sides of the valley through which it flows. These sides, for a considerable distance, afford indications of having received their last form from the bursting of a lake higher up in the valley of the Ogwen. Shells, and fragments of shells, like those on the shores of the ad- jacent sea, are reported by the workmen to have been found in the sand and gravel at an elevated spot near Moel Taban, on the right bank of the Ogwen, nearly opposite the quarries of Penrhyn. Mr. Trimmer did not see them here ; but on the summit of Moel Tryfane, on the south of Caernarvon, towards Bethgellert, in a sinking made through sand and gravel, in search of slate, at about 20ft below the surface, he found marine shells in a bed of sand; they were for the most part broken, resembling the broken shells on the adjacent beach; when dry, they adhere to the tongue: the fragments are too indistinct to identify species; the genera Buccinum, Venus, Natica and Turbo occur among them. Mr. Trimmer found similar broken shells also in the diluvium of the low cliff near Beaumaris. Beneath the diluvial deposits of this district, when the surface of the slate-rock is newly laid bare, it is found to be covered with scratches, furrows and dressings, like those observed by Sir James Hall on the summit of the Costorphine and other hills near Edin- burgh. These furrows and dressings were noticed several years ago by Mr. Underwood : they are referred to the action of the diluvial currents which overspread the country with gravel: some of the larger blocks amid the gravel have also deep scratches upon their surface. Where the diluvium is argillaceous, the surface of the subjacent slate has been so protected by it, as to remain sound and fit for use as Zoological Society. 145 as roofing slate up to its line of contact with the incumbent clay ; but where the diluvium is of sand or gravel, admitting ready access of water through it to the subjacent slate rock, the slate is often in a shattered state, and bent and decomposed to the depth of many feet below the line of contact. At the close of this Meeting, which terminated the Session, the Society adjourned till Wednesday the 2nd of November. ZOOLOGICAL SOCIETY. May 31, 1831. _N. A. Vigors, Esq. in the Chair. At the request of the Chairman, Mr. Gould exhibited a specimen of the male of the Urogallus medius ; the Tetrao hybridus of Gmelin and Dr. Latham, and the Tetrao medius of M. Temminck. Mr. Yarrell observed that this individual, with one other example of the same rare species, also a male, was found among a considerable number of the Tetrao Urogallus of both sexes, brought from Nor~ way by a boat partly laden with lobsters for the London market. Some of the older writers considered this bird to be a hybrid pro- duced between the Wood Grouse and the Black Grouse, and had named it accordingly: modern authors have, however, established its distinction as a species; and the female and its egg are now known. Notwithstanding the general resemblance between these two large Wood Grouse they are decidedly and very obviously dif- ferent. Inthe Tetrao medius the beak is black ; the shining fea- thers on the front of the neck and breast are of a rich Orleans-plum- colour ; and of the 18 feathers of the tail the outer ones are the longest. In the Cock of the Wood the beak is white; the feathers on the front of the breast are of a dark glossy green ; and the centre feathers of the tail are the longest. The organ of voice in the Tetr. medius is peculiar. The trachea of this bird and that of the Tetr. Urogallus were exhibited ; and Mr. Yarrell pointed out that the trachea of the Tetr. medius, eleven inches in length, has no loose fold, like that of the Tetr. Urogallus, but descends in a straight line to thelungs. From the thyroid car- tilage two pairs of muscles follow the course of the trachea, one pair firmly attached to the trachea itself, the second pair suspended loosely in the cellular tissue. Both these pairs of muscles, after an extent of eight inches, are lost in a membranous expansion, form- ing a sheath, which invests the inferior fourth portion of the trachea, and from which sheath one muscle only on each side is sent off, immediately above the bifurcation of the bronchia, to be attached to the inner surface of the sternum. The stomach is a true gizzard of great muscular power, and the intestines and ceca, as in all the Grouse tribe, are very long: the ceca in the present instance measured each three feet in length. There is reason to believe that this bird inhabits the Apennines as well as the more northern localities assigned to it. Mr. Fox in his ‘ Synopsis of the Newcastle Museum’ quotes a note of the late _ Mr. Tunstall which states that “he knew some old Scotch gentle- men who said they remembered, that when young, there were in Scotland both the Cock of the Wood, and the Tetr. hybridus.” N.S. Vol. 10. No. 56, Aug. 1831. U Mr, 146 Zoological Society. Mr, Yarrell availed himself of the opportunity to state that the hybrid Grouse of White’s ‘ Natural History of Selborne’ is believed to be a young black Cock, having nearly completed his first moult. He added that he was indebted to Mr. Sabine for the information that the Tetr. rupestris of Pennant’s ‘Arctic Zoology’ has been killed in Perthshire, and that the specimen is preserved in the collection of Lord Stanley, the President of the Society. At the request of the Chairman, Mr. Martin referred to the notes of the dissection of a specimen of Testudo Greca which he had laid before the Committee on the 26th of April, and stated that the correctness of these notes had been subsequently confirmed by the examination of another individual of that species, in which he had observed the same lengthened form of stomach ; similar intestines ; and a cécum agreeing with that previously described. The urinary bladder also corresponded in form and size. The trachea bifurcated in the same manner; and the bronchi@ had the same remarkable sigmoid flexure, and were furnished with the compressing muscle which he had before noticed. Mr. Owen remarked that he had ascertained the existence of a cecum in another species of Tortoise, (Emys concentrica, Leconte,) which he had recently dissected. The preparation of the cecum of the Testudo Greca having been laid upon the table, it was pointed out that the part so termed in this instance consisted of a pouch formed by the oblique insertion of the small into the large intestine, the upper end of the latter being dilated as in the human subject into a cecum caput coli: but that it by no means corresponded with the ceca of birds, and might almost be regarded as wanting when contrasted with the develope- ment of the same part in some of the Ophidian Reptiles, as in the genera Python, Boa, &c. A living individual, apparently referable to the Gulo barbarus, L., was exhibited. It was presented to the Society by Edmonstone Hodgkinson, Esq, of Trinidad, who describes it as being ‘ playful and gentle, although easily excited, and very voracious. It is ex- ceedingly strong, as is indicated by its shape ; and it has the same antipathy to the water as acat.” Mr. Hodgkinson suspects that it is a native of Peru. He obtained it inVenezuela, where it was presented to him by the President, General Paez. The name he received with it was ‘the Guache ;’ but this appellation, it was observed by Mr. Bennett, was probably erroneously applied to the present animal, belonging rather to the Coati, the orthography of which is variously given as Coati, Couati, Quasje, Quachi, and Guachi. The latter form occurs in the ¢ Personal Narrative’ of the Baron Von Hum- boldt, where it evidently refers to a nocturnal species of Nasua. The form and general appearance of the animal were remarked to be altogether those of a Mustela, to which genus it is probable that it should be referred, together with the typical Gulo barbarus. A specimen of the latter was placed upon the table, from which the living animal was shown to differ by the absence of the large yellow spot beneath the neck : a remarkable distinction in this group, but on Zoological Society. 147 on the occurrence of which, unless confirmed by several specimens, it was considered improper to propose regarding it as a distinct species. A stuffed specimen and a skeleton of the Acouchy (Dasyprocta Acuschy, lllig.) having been laid on the table, the following notes on the anatomy of that animal were read by Mr. Owen. «‘ The subjects examined were the male and female , 90 bee tye 198 25 M,é1 = 153 20 M,a2 = 123 34 M,o2 = 102 28 M,e = 153 26 M,d = 135 The plane 52, as the symbol denotes, and as appears in the figure, occurs singly on each angle, instead of being ac- companied by a corresponding plane on the other side of c. Wollastonite from Vesuvius. This is the same mineral as was, according to the ticket accompanying specimens from Vesuvius, formerly named Surlonite or Zurlite. 'The crystals are generally very imperfect, and the surfaces very dull; a specimen, however, in the pos- session of Dr. Somerville presented some bright and well- defined crystals, an examination of some of which has en- abled me to give the annexed figure and measurements. The primary form is an oblique rhombic prism. There is one cleavage parallel to P, and three others parallel to the three planes a3, h, c2; that parallel to #4 is the brightest, and I have supposed it parallel to the edge of the prism, and have thus assumed a different cleavage angle from that usually assigned to tabular spar. I have, however, found acleavage corresponding to the plane /, in specimens from the Bannat, in which the cleavages usually observed and hitherto quoted are those parallel to P andc2. The ratio of the terminal and lateral edges of the prism which I have taken as the primary is very nearly as 25 to 40, and the obtuse angle of the terminal plane is 91°°56!. The planes are more than usually perfect, several of the measured angles having agreed exactly with those given by calculation. Planes Mr. Daniell on a new Register- Pyrometer. 191 Planes al, a2, a3, cl, c2, el, €2, €3, FYS- $23 Bile 5 3 1 3 2 1 | 3 1 1 Symbols O, O, O, A, A, E, E, E, D, b, B, H. P,al = 159°30! P,a2 = 150 23 P,a3 = 129 42 PA = 110 12 P,f1 = 132 55 P,,f2 = 120 42 P,M = 104 48 P.g' = 1 86 8 Pyebi =) 146007 Poe@! c= 133 33 Pje3 = 115 33 Pg = 93 52 M,M'= 95 38 Some of the crystals are hemitrope, the plane of revolution being parallel to the terminal plane. XXV. On a new Register-Pyrometer, for Measuring the Expansions of Solids, and determining the higher Degrees of Temperature upon the common Thermometric Scale. By J. Freperic Danie.t, Esq. F.R.S.* [With a Plate. ] i the year 1821 I published in the Journal of the Royal Institution} an account of a new pyrometer, and the re- sults of some experiments with it, which were the means of correcting the highly erroneous notions which had, up to that time, been generally entertained of the degrees of temperature beyond the boiling point of mercury. The instrument was capable of affording correct determinations, connected in an unexceptionable manner with the scale of the mercurial ther- mometer; but, although applicable to scientific investigation in careful hands, it could be inserted only into experimental furnaces of a particular construction, which greatly limited its use. The great desideratum still remained of a pyrometer, which might universally be applied to the higher degrees of heat, as the thermometer has long been to the lower; and which, in addition to its use in delicate researches, might eflect for the potter, the smelter, the enameler and others, in the * From the Philosophical Transactions for 1830: Part II, and revised by the Author. + Vol. xi. p. 309. routine 192 Mr. Daniell on a new Register-Pyrometer, routine of their business, what the latter daily performs for the brewer, the distiller, the sugar-refiner, and the chemist. I shall now have the honour of laying before the Royal Society a description of a contrivance which, I trust, will be found to answer all the desired purposes; and which, while simple enough to be intrusted to the hands of common work- men in every variety of fire-place, I hope to prove, by the results of my experiments, to be sufficiently delicate to extend considerably our knowledge of the expansion of metals, upon which so much labour has been bestowed by some of the first philosophers. I was not aware, at the time when I wrote the account above referred to, that the subject had been previously investigated by M. Guyton de Morveau, and that he had proposed to apply the expansion of platinum as a measure of high tempe- rature, and more particularly to the purpose of connecting the indications of Wedgwood’s pyrometer with the mercurial scale and verifying its regularity. I have since carefully studied his laborious papers in the Annales de Chimie*, and the Mémoires de 0 Institut+, which appear to have been but very little known in this country; and previously to entering upon the more particular object of the present paper, I must claim indulgence for a few remarks upon the general state of the inquiry at the time when its pursuit was abandoned by that able philosopher. M. Guyton’s pyrometer consisted of a small bar or plate of platinum 45 millimetres (1.77 inch) long, 5 millimetres (about 0.2 inch) broad, and 2 millimetres (about 0.08 inch) thick, placed in a groove formed ina piece of highly baked porcelain. One extremity of this bar rested upon the solid end, which terminated the groove, and the other pressed upon the short arm of a bent lever, the longer arm of which terminated in a point and moved on a pivot over the graduated arc of a circle ; indicating by its motion any lengthening of the bar by increase of temperature. The short arm of the lever was 2.5 milli- metres and the long arm 50 millimetres in length, and the latter carried a nonius by which the tenths of a degree might be read off. The whole was constructed of platinum ; and a plate of the same metal was made to press, in the manner of a spring, upon the extremity of the index, to prevent any dis- placement when withdrawing it from the fire. The description of this instrument in the first Essay, published in the year 1803, was not accompanied by any explanatory figure; and the notice in the Annales terminates by announcing that the * Tome xlvi. p. 276. + 1808, Second Semestre, tome ix.—181]1, ibid. tome xii. inventor for Measuring the Expansions of Solids, $c. 193 inventor had at that time only begun “a series of experiments to determine its march, to compare it with the pyrometer pieces of Wedgwood, and to ascertain the degree of confidence which might be placed in the indications of the latter.” The second Essay did not appear till the year 1808, and in it M. Guyton observes that ‘“‘many persons had expressed a wish to be made acquainted with the improvements which he had made in the instrument since its first construction; and that he had determined in consequence to give a fresh description of it accompanied by drawings, which might enable artists who undertook its construction to render it comparable. He, however, thought it right to give a previous account of the labours of others in this branch of science, and to remove certain errors which had prevailed up to that time concerning the pyrometer then most in use (Wedgwood’s), and which might possibly prove most commodious, and consequently most useful, if once the degree of exactitude could be deter- mined of which it was susceptible.’ The remainder of the paper is taken up with an account of the most accurate expe- riments upon the expansion of the metals from the time of Newton. The third and last Essay was delayed till the year 1811; and in it no further description of the platinum pyrometer is to be found; but a laborious comparison, Ist, of the indications of the platinum pyrometer with those of the mercurial themometer ; 2nd, of the same pyrometer with that of Wedgwood; and 3rd, of the degrees determined by these instruments with those previously known of the expansion, ebullition and fusion of various substances; in a range of temperature comprising the highest degrees of the thermometric scale and the lowest of Wedgwood’s. Now it is very remarkable that all M. Guyton’s efforts in this paper are directed to the valuation of the degrees deter- mined by Mr. Wedgwood’s clay pieces; but that he carries the comparison of the platinum pyrometer by actual experi- ment no higher than the melting point of antimony. He clearly establishes a great error in Mr. Wedgwood’s original estimation of his degrees to that point ; and, by calculation upon this basis, continues the correction to the melting point of iron, “en admettant toujours une progression uniforme jusque dans les plus hautes températures.” The experimental comparison was obviously stopped by some practical difficulty at higher temperatures; and it is easy to perceive in what this must have consisted. Platinum at a red heat becomes very soft and ductile; and the lever against which the pyrometric N.S. Vol. 10. No. 57. Sept. 1831. ZC bar 194 Mr. Daniell on a New Register-Pyrometer, bar pressed, being of such very slender dimensions, would obviously be liable to bend, and thus frustrate the experiment: in addition to which, I can speak from my own experience, the platinum spring plate and the centre pin would be liable to a change of texture, which would impede the motion of the lever, and it would finally become welded to the index; for a very moderate pressure at a high temperature would produce this effect. The conclusion, indeed, of these Essays seems to admit that the author did not expect that the platinum pyrometer could ever come into general use: ‘enfin, ces corrections ne peuvent manquer d’ajouter a l’utilité du pyromeétre d’argile, soit dans les travaux chimiques, soit dans les arts; quand méme le pyrometre de platine, plus exact mais moins usuel, serait ré- servé pour en assurer la marche, et pour servir 4 des recher- ches plus importantes.” M. Guyton, however, although he abundantly proves the incorrectness of Mr. Wedgwood’s estimate of the higher degrees of temperature, is very far indeed from establishing the point at which he so earnestly laboured, namely, the re- gularity of the contraction of the clay pieces; or from substi- tuting a more correct value of the degrees throughout the whole range of the gauge than the one which he so completely overturned. His comparative experiments with the platinum pyrometer, at the boiling points of mercury and linseed oil, and the melting point of antimony, led him to reduce the equivalent of each degree from 130° Fahr. to 62°°5. The zero point of the clay pyrometer was thus carried back to 517° instead of 1077°; but it seems to have escaped his notice that this zero point was declared to be a red heat visible in the day- light,—a description which cannot be mistaken, and which clearly could not be below the temperature of boiling oil, melting lead, or boiling mercury; all of which are, however, placed above it in M. Guyton’s table. M. Guyton also places the melting point of silver at the 22nd degree of Mr. Wedg- wood’s scale instead of the 28th, which was, according to his own determination, a correction first suggested by Sir James Hall in the 9th volume of Nicholson’s Journal. Taking the value of each degree at 62°°5 Fahr., it fixes this point at 1892° Fahr., which agrees very nearly with my own experiment in the paper before alluded to; but continuing the calculation up to the melting point of iron, upon the supposition of an uniform progression, the 130th degree corresponds with 8696° Fahr., which, although only about half the amount 17977° assigned by Mr. Wedgwood, is very far removed from the result of my calculation 3479°. Never- for Measuring the Expansions of Solids, &c. 195 Nevertheless, it is a curious fact, that M. Guyton’s Essay contains proof that his determination is erroneous, and that mine is a near approximation to the truth. As a collateral means of verifying the indications of instruments intended to measure high degrees of temperature, he refers to the calori- meter as capable of affording the necessary data by a calcula- tion from the amount of heat communicated to known quan- tities of ice or water by bodies in a state of incandescence; and he quotes the very exact experiments of MM. Clement and Desormes, who had in this manner determined the fol- lowing points : By the Liquefac- By the Heat com- tion of Ice. pe Water. ahr. Fahr. : Temperature of soft iron melted ... 3988° ...... 3902° Cast iron just on the point of melting 3164 ...... —- ME SPORE cane nadudiansndacadenenvauakn DLAs eee NE NAN EL ak ceacinn pices BAR a peeall she Tron just ceasing to be Spe veceee 1979 EW ST CPE TRS ee IES ia dem axneraaze ran ninnans 5 Srty esis 4 OO My own determinations of the melting point of cast iron, 3479°, of that of copper, 2548°, and of a red heat, about 1000°, agree very closely and satisfactorily with these results, with which I was unacquainted at the time of my experiments. M. Guyton’s remark upon the latter is: ‘II suffit de jeter un coup-d’ceil sur les résultats, "pour recueillir de nouvelles preuves univoques de la nécessité de réduire les valeurs données par Wedgwood aux degrés de son pyrométre. Mais je ne crains pas de dire que ces réductions sont ici portées trop loin, ainsi qu’on peut en juger en les rapprochant de celles auxquelles jai été conduit par l’ensemble des expériences rapportées dans cet essai. Ce n’est pas que je veuille répandre des doutes sur exactitude des observations dont je dois la communication aux deux habiles chimistes ci-dessus cités; mais il est aisé de faire voir que la différence des résultats est due, pour la plus grande partie, a la différence des procédés; de sorte que les évaluations quils ont données aux degrés de l’échelle de Wedgwood, peuvent, en derniére analyse, et en prenant les termes moyens dans la latitude que comportent des opérations aussi délicates, servit plutét 4 confirmer qu’a détruire le sys- teme de correction que j’ai établi.” It is worthy of observation, that had the degrees of Wedg- wood’s pyrometer been valued from this determination of the fusing point of iron, the result would have better corresponded with the whole series of phanomena. Instead of 130° Fahr. as fixed by the inventor, or 62°*5 as corrected by M. Guyton, 2C2 they 196 Mr. Daniell on a New Register- Pyrometer, they would have been estimated at about 20° Fahr.; and taking Mr. Wedgwood’s original determination of the fusing point of silver at 28° of his scale and the zero point at 1077°, the former would come out about 1650°. By raising the zero point a little, (and it is much more probable that the tempe- rature of a red heat fully visible in the day-light is above 1077° than below it,) we arrive at something like an approximation to the truth. These wide discrepancies, and the practical disuse of both Mr. Wedgwood’s and M. Guyton’s pyrometers for a long time past, prove the expediency of further investi- gating a subject of so much interest and importance. The pyrometer, which I shall now proceed to submit to the judgement of the Society, consists of two distinct parts, which I shall designate as the Register and the Scale. The first is a solid bar of black-lead earthenware, eight inches long, seven-tenths of an inch wide, and of the same thickness, cut out of a common black-lead crucible. In this a hole is drilled three-tenths of an inch in diameter, and 74 inches deep. At the upper end of this bar and on one of its sides about six-tenths of an inch in length of its substance is cut away to the depth of half the diameter of the bore. When a bar of any metal 6} inches long is dropped into this cavity, it rests against its solid end; and a cylindrical piece of porce- lain about 14 inch Jong, which I shall call the index, is placed upon the top of it, which projecting into and beyond the open part, is firmly confined to its place by a ring, or strap of pla- tinum ; which passing round the black-lead bar and over the piece of porcelain, is made to press upon the latter with any required degree of tension by means of a small wedge of por- celain inserted between the bar and the strap on the side of the former. It is obvious that when such an arrangement is exposed to a high temperature, the metallic bar will force the index forward to the amount of the excess of its expansion over that of the black-lead, and that when again cooled, it will be left at the point of greatest elongation. It may also be observed, that the exact indication of this amount is not in the slightest degree interfered with by any permanent contraction which the black-lead may undergo at high degrees of heat; as any such contraction will take place at the moment of the greatest expansion of the metal, and the index will still mark its point of furthest extension upon this contracted basis. The problem now consists in the accurate measurement of the distance which the index has been thrust forward from its original position; and although the amount can in any case be but small, there is no reason why it may not, be determined with the same precision as is now commonly attained in similar quantities Jor Measuring the Expansions of Solids, &¢. 197 quantities in astronomical and geodetical operations. For this purpose the scale is constructed of two rules of brass, accurately joined together at a right angle by their edges, and fitting square upon two sides of the black-lead bar, and of about half its length. At one end of this double rule a small plate of brass projects at a right angle, which plate, when the two sides of the former are applied to the two sides of the re- gister, is brought down upon the shoulder formed by the notch cut away at its upper end, and the whole may be thus firmly adjusted to the black-lead bar by three planes of contact. On the outside of this frame another brass rule is firml screwed down, which projecting beyond it, and bending a little so as to bring its end opposite to the cavity in the black-lead bar when applied to it, supports a moveable arm exactly 54 inches long, turning at its fixed extremity upon a centre, and at its other carrying an arc of a circle, accurately divided into degrees and thirds of a degree, whose radius is exactly 5 inches. At the centre of this circle upon the arm, and of course at the distance of half an inch from the centre of motion, another lighter arm is made to turn, one end of which, being the exact radius of the circular arc, carries a nonius with it, which moves upon the face of the are and subdivides the former graduation into minutes. ‘The other end crosses the centre; and at the exact distance of one-tenth of the radius, or the distance be- tween the two centres of motion, terminates in an obtuse steel point turned inwards at a right angle. These graduations and distances are laid down with the greatest precision by Mr. Troughton’s dividing engine. This part of the apparatus may be regarded as a pair of proportional compasses attached to the end of the brass rule and frame, whose longer legs carrying the arc and nonius are to its shorter as ten to one; and the opening of the latter being regarded as a chord of a small circle, is magnified in the same proportion by the for- mer, and measured upon the scale. A small steel spring let into the larger arm is made to press upon the smaller, so as to adjust the nonius to the commencement of the graduation ; and when forced back it tends to restore it to its original position. The annexed figures, in which all the parts are drawn of their real dimensions*, will assist the comprehension of the preceding description. Plate II. fig. 1. represents the scale. A A is the principal brass rule, upon the under side of which the frame a a a aaa isadjusted by the screws b 6, and which _ * In our plate the pyrometer is represented about one third less than its real dimensions,—Lv1v. supports 198 Mr. Daniell on a New Register-Pyrometer, supports upon its bent extremity c, the arm B moving upon the centre d, and terminating in the arc of the circle e e. C Cis the lighter arm moving upon the centre fupon the arm B, and carrying at one end the nonius g, and.at the other the steel point /, the distance of which from the centre fis exactly half an inch or one-tenth of the radius fg, and equal to the distance of the two centres fd. 7 is a small lens represented as lying down, but which may be raised by the centres & and Z perpendicularly above the nonius to facilitate the reading. m m is the steel spring, which being fixed in a cavity cut out of the arm B, presses upon a small pin 2 on the arm C, and throws the radius back to the commencement of the arc. Fig. 2. represents the register. D D D Dis the black-lead bar, with its cavityo 0. At ppp p itis cut away to the depth of half the bore. q q is the porcelain index, which is placed upon the top of the metallic bar, and confined to its place by the pressure of the platinum strap r acting by the force of the small porcelain wedge s. When an observation is to be made, the metallic bar is placed in the cavity of the register, the index is to be pressed down upon it and firmly fixed in its place by the platinum strap and porcelain wedge. ‘The scale is then to be applied by carefully adjusting the brass rules to the sides of the black- lead bar, and fixing it by pressing the cross piece (a') upon the shoulder: holding the whole together steadily in the left hand, the moveable arm should be so placed that the steel point (2) of the other leg of the compasses may rest upon the edge of the porcelain index, against which it will be pressed with some force by the spring: then moving the arm gently forward with the right hand, the point will slide along the end of the index till it drops into a small cavity (¢) formed for its reception, and which exactly coincides with the axis of the metallic bar in the register, and the centre of motion of the compasses on the brass rule. The minute of the degree must then be noted, which the nonius indicates upon the arc. A similar observation must be made after the register has been exposed to an increased temperature and again cooled; and the number of degrees or minutes which the nonius will then mark will, by a simple calculation from the known length of the radii and angle, give the length of the chord comprised between the original position of the compasses and the point to which they have moved, or the distance which the index has been forced forward. Such an operation appears complex in the description, but is in fact extremely simple after a little practice, and does not require more than a few seconds for its performance. The scale of this pyrometer being completely detached for Measuring the Expansions of Solids, &c. 199 detached from the part which is exposed to the fire, obviates one important objection which has always been made to other contrivances of the same nature, from the uncertain degree of heat and expansion to which they are liable; while the sim- plicity of that part of the arrangement which alone is subjected to great heats, renders it little liable to injury; and together with the cheapness of the materials of which it is constructed, occasions but a very trifling expense for replacing it when injured. The calculation of the absolute expansion of the bar indi- cated by the scale may be performed as follows:—As radius to double the sine of half the arc read off, and found in a table of natural sines, so will the radius B be to the chord of the same arc; and this divided by ten (the radius of B being ten times the length of the radius f/) will give the length required. Suppose the arc read off upon the scale to be 4°, Radius. Sineof2°. — Inches. Inch, then 10000000 : 0348995 X 2: : 5 : °3489950 — 10 = ‘0348995. Now in working out this proportion it will be observed, that the multiplication by 2 and by 5 being both constant may, in conjunction with the division by 1°0, be omitted ; and leaving out also the final division by 10, the case resolves itself into seeking the sine of half the arc, read off upon the scale, in a table of natural sines, and reading it as the decimal of an inch. Moreover, the chords of small arcs are so nearly propor- tional to their ares that, the number of degrees measured upon the scale never exceeding 10, they may be considered without sensible error as denoting equal increments of expansion. The following short Table of the value of a degree, and minutes of a degree, may therefore be useful in practice. TaB.e I. ao V, Inch. ie Opes OOS oo 030 = *004386 020 = 00290 OTS" "O02Z1sS 010 = :*:00145 Oro =" "00072 0 2 = +*00029 Oo 1 = 00014 _ The chord of ten degrees derived from this Table by mul- tiplying ‘00872 by 10 would therefore be -0872, whereas it is more accurately ‘0871; but the difference being only ;5,555dth of an inch may, in most cases, be disregarded. {To be continued. | XXVI. On [ 200 ] X XVI. On the Theory of the Compressibility of the Matter com- posing the Nucleus of the Earth, as confirmed by what is known of the Ellipticities of the Planets. By the Rev. J. CHauuis, Fellow of the Cambridge Philosophical Society*. Pk. YOUNG suggested that the increase of density towards the centre of the earth, might be owing to the com- pressibility of the material of which it is composed. Laplace, adopting the suggestion, obtained, in an addition to a Memoir on the Figure of the Karth (Mém. Acad. Scien. An. 1818) the law of the increase of density in proceeding from the surface to the centre, on the suppositions that the relation between the 2 pressure (p) and density (g) is expressed by p = ad ( 5 —1), (@ being the density at the surface), and that the chemical composition of the nucleus of the earth is the same throughout. He found that on these suppositions the requisite degree of compressibility, and the proportion of the density at the sur- face to the mean density, were not by any means at variance with what we know on these points by experience. ‘The cause assigned in this theory for the increase of density towards the centre, and the relation between p and g, are of so simple a na- ture, that I have been induced to inquire how far the theory is confirmed by what is known of the ellipticities of the planets. I here repeat the investigation of Laplace, modified for the purposes I have in view. Suppose the mass of the planet to be spherical. If 7 be any distance from its centre, and eg = $ (7), the attraction on a particle of the mass at a distance R from the centre is Bh , the integral being taken from r =0 to r= R. To express this force in the manner in which terrestrial gravity is usually expressed, let M = the earth’s mass, a = its radius, and g = 32} feet, the measure of the accelerative force of gravity at the earth’s surface: 2 2 - then ar : PART EMIS, is the force expressed as re- quired. Suppose that f/7*d7r(r) = (r). Then attraction (Aye fate x ee, Now —dp=AedR; 2 and —dp= — ae ede. Ang a? (RK) —W(0 Qk’ od Therefore a a ‘ pe w0) ia ae * Communicated by the Author, Hence Rev. J. Challis on the Ellipticities of the Planets. 201 2 2 Hence ¥ (R) — (0) + onary , Ede = 0; and dif 2M (Rige aRd ferentiating, R?¢ (R)+ Qneaee\ dR? ar aa) = 0. ahiat =, Qn 9 as Hence finally, eae: + ¢Re=0, ¢ being eee P . k? M The integral of this gives a = ae » 4 being the value of g at the centre. Legendre has calculated (Mém. Acad. Scien. An. 1789), that according to this law of density, ifc = the : 2 SUS ts earth’s radius, and gc = = , the ellipticity would be 568° and 1 if gc = =, the ellipticity would be 379° But it is plain from the nature of solid substances that gc cannot be so great as z, for then g would be = 0. In proportion as the value of g Ris near to x, the density is small, and decreases rapidly as R increases: and because solid substances do not admit of this rapid change of density, and at their surfaces possess a certain limited den- sity, therefore it is probable that we shall not be far wrong by assuming gc = of, In fact, this value gives an ellipticity of aa to the earth, which is very near the experimental de- termination. If now we calculate the attractive force of Jupiter at his equator, by means of the period of his fourth satellite, and the law of the inverse square of the distance, we shall find that the ratio of the centrifugal force at his equator to this force is But because the law of the inverse square 1 11°95" does not accurately hold by reason of the planet’s spheroidal shape, this value requires a correction. When the correction has been made according to the formula given in the Méc. Céleste, liv. iii. art. 35, the ratio becomes The ratio 12°348° of the centrifugal force to gravity at the equator of Saturn, calculated from the period (79°33 days) and mean distance (64°36 equatorial radii) of the extreme satellite, and from the time (10" 15’) of Saturn’s rotation, will be found to be ane" Correcting as before, the ratio becomes } nearly. Calcu- N.S. Vol. 10. No. 57. Sept. 1831. 2D lating 202 Rev. J. Challis on the Ellipticities of the Planets. lating now the ellipticities of Jupiter and Saturn by Clairaut’s =, we shall find Theorem, on the supposition that gc = for Jupiter — and for Saturn. The measurements of Professor Struve determine the ellipticity of Jupiter to be ar , and Herschel obtained < for the ellipticity of Saturn. It must be observed that the above calculations take into account only the first power of the ellipticity, and therefore cannot be very accurate with respect to Jupiter and Saturn, the ellipticities of which are not very small. We may, how- ever, affirm that the ellipticity of Jupiter accords very well with the theory we are considering. ‘That of Saturn is consi- derably less than what the theory gives. Herschel remarked an anomaly in the shape of this planet, which, however, sub- sequent observations have not yet confirmed; viz. that the equatorial diameter was not so large as a diameter about mid- way between the equatorial and the polar. It would seem, if this be true, that some cause has operated to compress the parts about the equator. The same cause would account for an ellipticity less than what our theory requires. Possibly the rings may have something to do with this. Venus, Mercury, and the Sun, in as much as they possess no ellipticity discoverable by instruments, do not contradict the theory. But Mars forms an exception. Its ellipticity is : ; 1 : ascertained by observation to be wei whereas the ratio of the centrifugal force to gravity at its equator, which ratio differs little from the ellipticity that the theory gives, will be found 1 to be 5a the earth, +1294 the ratio of the volumes, and 24°67 hours the period of its rotation. The great ellipticity of this planet, considering the time of its rotation and its small size, is re- markable, and seems not to be in accordance with Clairaut’s Theorem, unless we suppose the gravity of the planet to di- minish in passing from the equator to the pole. If the cause assigned in this theory be sufficient to account for the increase of the density of a planet towards its centre, then on the supposition that the nuclei of the planets are all as to chemical composition homogeneous, and are similarly constituted, though of different mean densities, the equation by taking *1386 for the ratio of its mass to that of ~ \ sel } re . . . Gorm) = ought to be nearly true for all, since it is nearly true Rev. J. Challis on the Ellipticities of the Planets. 203 true for the earth. Let us see what will follow from sup- posing this equation to be generally true. If the mean den- sity of the earth be d, then M = pees and g? = BRS y Bee tea 2. kas Now the velocity (V) of propagation in a medium in which 2 — p= ee —1), is = / 20, where the density is ® This may be shown by a separate consideration of this particular case, or be inferred from a general proposition respecting the velocity of propagation, which I gave in the Phil. Mag. and Annals of Philosophy, for May 1830*, where it was proved that if p + C =a?e'*", V may be found from the equation V?— a e"(1l+n)=0. We have then, ale = . ;gf= 3g8 | xe G5 ae eed Viad? and g*c?, or anak i waite Now Laplace has calculated that according to this theory the ratio of the mean density to the density at the surface of the earth is 2°42; and according to our supposition the same ratio holds true for the planets. o 2 Therefore if D = the mean density of the planet, a = 7 2 2 . . = or ae =e 54 nearly. Hence if v = the velocity of pro- pagation in the material which composes the nucleus of the 2 : earth, z f= 51, 0rv= es ca : v being calculated from this, is found to be 10°13 times the velocity of propaga- tion in air:—a result far from being improbable. Generally, ae g's Vig ee he Sy ee a Wan = at Whence goles aig ft artic Pres - ve Me m being the mass of the planet, M of the earth. * I have there shown that, the velocity of uniform propagation __ the velocity in the medium F Maoriiolag ef thadensty: This equation bears the same relation to space time motion itself, and will not seem unimportant to those who consider that the one phanomenon is nearly as frequent as the other. As the proposi- tion is quite new, and in some degree contradicts the received mode of determining the velocity of propagation, it is not likely to meet with im- mediate attention: I have therefore adverted to it here, 2 D2 The the propagation of motion, as the equation, uniform velocity = x 204 Rev. J. Challis on the Ellipticities of the Planets. The following values of a are calculated from the masses of the bodies of our system, as given by Laplace. For the Sun, 54°31; Jupiter, 5°33; Saturn, 3:06; Uranus, 1:97; the Earth, 1; Venus, ‘981; Mercury, *651; Mars, -5; the Moon, :23. It is observable that the order of magnitude of these quan-~ tities is the same as the order of the bodies arranged accord- ing to their masses. It follows, therefore, from our theory, that because in the greater masses the velocity of propagation is greater, the materials of which they are composed possess greater elastic force. This may be owing, not to any differ- ence in the constituent elements, but to a greater degree of proper caloric, or of the force, whatever it be called, by which the constituent atoms are held in their positions relatively to each other. For it is not unreasonable to suppose that the proper underived caloric of any mass, such as we know exists in the earth and forms the principal part of its caloric, is some function of the mass, and is specifically greater as the mass is greater. The Sun, which is the largest, is the hottest body of our system. According to this view, if there be granite at the surface of the moon, it will be more compressible than the granite of the earth; it will possess both a density and a compressibility depending on the mean density and compres- sibility of the moon’s nucleus. The theory we have been considering requires us to believe that the interior of a planet is solid, and not fluid. On the supposition of fluidity, it would be difficult to account for the contradiction presented by Mars to Clairaut’s Theorem. May we not conjecture, that this planet is hollow about its centre, or in the direction of its axis? Generally speaking, the least bodies of the solar system are the densest, if we set aside the satellites, which seem to partake of the density of their pri- maries. But Mars is not so dense as Mercury, Venus, or the Earth. This fact favours in some degree the conjecture. . Assuming the truth of our theory, we may readily conceive that any change in the state of the internal heat of the earth, would give rise to great changes at its suxface, and perhaps produce effects like those exhibited by geological phano- mena. Upon the whole, a review of the planets seems to favour the idea, that any increase of density towards their centres, is owing either wholly, or at least in part, to the compressibility of the matter of which their nuclei are composed. Papworth, St, Everard, Aug. 10, 1831. XXVIII. Analysis [ 205 ] XXVII. Analysis of some Salts of Mercury. By R. Pur.utes, E.RS. L. & E. &c. W HEN two parts of mercury are heated, for a short time, with three of sulphuric acid, some protosulphate of mercury is formed ; but if the heat be continued, the mercury is converted almost entirely into bipersulphate, even before the evolution of sulphurous acid gas ceases, or the whole of the metal is dissolved. When this bipersulphate of mercury is put into water it is decomposed, and a yellow precipitate, formerly called turpeth mineral, is thrown down. This salt was, I believe, first minutely examined by Four- croy (Annales de Chimie, tom. x. p. 109.), and according to his analysis, it consists of Salphuric Cid 5 2.5secscscecscssssscee 10 MECrenny Gsivse. fecevescosveusneneeseme" 16 OXYGEN. veceecscccsveccsccccscrsccsese I] WUCAUCR cas dadpivea seta de sinlid aviedactin stan chi Ss 100 MM. Braamcamp and Sequeira (Ann. de Chimie, tom. liy. p. 123.) give as the result of their analysis, Si WRNIG ACI a. cee suodushaasecede, 19 Peroxide of mercury ..........- aees Naa. Loss, attributed to moisture ...... 00°3 100:0 Dr. Thomson (System, vol. ii. p. 660.) observes, that sup- posing it to be a compound of 1 atom acid +1 atom per- oxide, its constituents will be Sulphuric acid..... Sapasactsvabsonen Mantes Peroxide of mercury .......se.s0008 84°38 100-00 In his Attempt, &c. (vol. ii. p. 403.) also Dr. Thomson con- siders this to be the true composition of this salt. Wishing, however, to determine its nature, as well as that of the salt re- maining in the solution from which it is precipitated, I put 200 grains of bipersulphate of mercury into about a quart of cold water; the yellow sulphate precipitated weighed 141-1 grains; the solution was then heated, by which 8-4 grains more were obtained ; afterwards sulphuretted hydrogen threw down 14°5 of bisulphuret of mercury. To ascertain the composition of the yellow sulphate, I heated 100 grains in a solution of soda; the peroxide of mercury separated weighed 86°9 grains; to the solution, after super- saturation with muriatic acid, muriate of barytes was added, and 37°3 206 Mr. R. Phillips’s Analysis of some Salts of Mercury. 37°3 grains of sulphate were precipitated, equivalent to 12°6 of sulphuric acid One hundred grains, therefore, yielded of Sulphuric acid ........0sesseeees coe 126 Peroxide of mercury .'......+00+6. 86°9 Loss See veseoseoesesscsoseseosecsses eee °5 100°0 I ascertained the quantity of peroxide of mercury also, by decomposing the salt with sulphuretted hydrogen; 100 grains ave 94°8 of bisulphuret of mercury = 88-2 of peroxide. Taking the mean of these experiments, the salt consists of Sulphuric acid). ...ececccseossesse 19°6 Peroxide of mercury............ 87°5 100°1 I therefore consider the yellow sulphate of mercury, as a subpersulphate constituted of Three atoms of sulphuric acid (40x 3) = 120 or 12-2 Four atoms of peroxide of mercury (216 x4) = 864 87°8 —————— 984 100°0 or it may be regarded as consisting of Two atoms of persulphate of mercury (804432) = 512 One atom of dipersulphate.......s0008 (40+432) = 472 984 This however is so unusual an atomic constitution, that I have not admitted its existence until after repeated analyses ; it will be observed, that if we add the oxygen to the mercury, in Fourcroy’s analysis, the resulting peroxide will amount to 87, with which the results of my experiments very nearly agree. With respect to the sulphuric acid and the peroxide of mer- cury remaining in solution, and which have been supposed to constitute a peculiar supersalt ; it may be observed, that when four atoms of bipersulphate of mercury are acted upon by water, a compound of three atoms of acid and four atoms of oxide is precipitated, while five atoms of sulphuric acid re- main in solution: this acid, however, prevents the decompo- sition of the whole of the bipersulphate by dissolving a por- tion of it; the quantity remaining in solution depends, to a certain extent, upon that of the water employed ; thus, when using a quart of water, as in the above related experiment, nearly 150 of the yellow subpersulphate were precipitated from 200 of the bipersulphate, but when only half the quan- tity of water was used, 155 were obtained from an equal weight : Mr. R. Phillips’s Analysis of some Salts of Mercury. 207 weight: in the former experiment, therefore, about one-tenth of the bipersulphate, and in the latter rather less, remained undecomposed. Having some reason to suppose that the compounds of carbonic acid and mercury had not been sufficiently examined, I collected all the evidence on the subject, which I have been able to obtain from the numerous authors whom I have con- sulted. Dr. Thomson (System, vol. ii. p. 658.) says; * Car- bonic acid does not attack mercury, but it may be combined with its oxide by pouring an alkaline carbonate into nitrate of mercury. The precipitate in that case is a white powder, composed according to Bergman of DACTEULY sccencsseccvesatstess, GU'9 Oxygen and acid.......... 91 100°0 ** Supposing the carbonate a compound of 1 atom carbonic acid +1 atom peroxide of mercury, it will consist of Caniinic AiG « cacateee se cade cass ts Oe PETRI O esp at tp e¥eo scones cdecneest GO 1G 100:00.” It must however be very evident that the salt obtained by Bergman was not a percarbonate so constituted ; and pro- bably it was not a percarbonate at all; for 90-9 of mercury require nearly 7°3 of oxygen for conversion into peroxide, and consequently there is left only 1°8 for carbonic acid: if we suppose it a protocarbonate, it must consist of about 90°5 prot- oxide and 9°5 carbonic acid; but for reasons, which I shall presently state, I am inclined to believe that it contained no carbonic acid whatever. In his Attempt &c. (vol. ii. p. 397.) Dr. Thomson does not mention any percarbonate of mercury; but he informs us that he obtained a white protocarbonate of mercury, by adding car- bonate of soda to a solution of nitrate of mercury ; the preci- pitate lost 14°44 per cent. by solution in nitric acid, and Dr. Thomson considers it, therefore, as a sesquiprotocarbonate of mercury, composed of One atom and a half of carbonic acid 33 or 13°7 One atom of protoxide of mercury 208 — 86°3 241 100°0 Although, as already mentioned, I have referred to many chemical writers, for evidence as to the existence and com- position of protocarbonate of mercury, yet except what I have quoted from Dr. Thomson, my an have been attended with 208 Mr. R. Phillips’s Analysis of some Salts of Mercury. with but little success; it is indeed true, that Berzelius (Essai sur la Théorie des Proportions Chimiques, table, p. 21.) states, that what he calls carbonas hydrargyrosus, consists of 9°47 car- bonic acid +90'53 protoxide of mercury, or an atom of each; but this, I take it for granted, is merely theoretical composi- tion. Berthollet (Mémoires d’ Arcueil, tom. iii. p. 89.) after men- tioning the precipitation of pernitrate of mercury, by carbo- nate of soda, to which I shall again advert: says, ‘ On a fait la méme expérience avec une dissolution nitrique de prot- oxide de mercure. Le précipité était d’un jaune clair; il a fait, aprés avoir été bien lavé, une vive effervescence avec Vacide nitrique. Lorsqu’on pousse fort loin les lotions, il prend une couleur noiratre; et méme sa surface se noircit lorsqu’ on le laisse sous l’eau;” and he afterwards adds, “ le prot- oxide se combine avec lui, [l’acide carbonique, | et peut former un carbonate, lequel cependant peut étre décomposé par la seule action de l’eau qui lui enléve l’acide carbonique, quoique difficilement.” Upon considering these statements, Iapprehend that Berthol- let took the yellow precipitate for a carbonate, and the black one for protoxide of mercury derived from its decomposition. To procure protocarbonate of mercury, I mixed a solution of carbonate of potash with one of protonitrate of mercury; the precipitate at first produced was of a yellowish colour, and it remained so until excess of the alkaline carbonate was added ; it then became immediately of a dark colour, and eventually as black as the precipitate formed by caustic potash: I have therefore no doubt that the yellowish precipitate, first ob- tained, was a subprotonitrate, and it dissolved in nitric acid without effervescence; if the solution of the nitrate be added to an excess of that of the carbonate, the precipitate is at once black. Two hundred grains of the precipitate procured with excess of carbonate of potash, and dried by exposure to the air, were dissolved in a weighed vial of dilute nitric acid; the loss of weight was only 0°5 of a grain, and was evidently one of mani- pulation merely ; this experiment I have repeated with similar results. Under these circumstances, I am of opinion that a white or yellow protocarbonate of mercury cannot be formed; that when the protocarbonate is precipitated it is ofa black colour, but loses its carbonic acid by drying in the air. Berthollet states that percarbonate of mercury cannot be formed; he says indeed, correctly, that when bipermuriate of mercury is treated with carbonate of potash, it is not enon ut Mr. J. Prideaux’s Experiments on Vanadiate of Ammonia. 209 but he is wrong in supposing that a percarbonate is not pro- cured by adding the carbonate tc a solution of pernitrate: I mixed solutions of these salts and obtained a precipitate, which had an ochre yellow colour; it was dried by exposure to the air, lost 4°4 per cent. by dissolving in dilute nitric acid, and the solution when decumposed by soda gave 96:1 of per- oxide; this salt is therefore a dipercarbonate, consisting of Two atoms of peroxide of mercury (2162) = 432 or 95:2 Moe *AtOnY Oh Car wume ACO scrcevencscssscceesca == ee 4°8 454 100°0 XXVIII. Experiments on Vanadiate of Ammonia, and on some other Compounds of Vanadium. By Mr. Joun Pri- pEAUX, Member of the Plymouth Institution. To the Editors of the Philosophical Magazine and Annals. Gentlemen, N the absence of detailed information on vanadium, a sum- mary of experiments on the minute scale, on a portion of vanadiate of ammonia, with which I was favoured in a letter from Professor Berzelius, about a month since, may be not unacceptable to your chemical readers. It was accompanied by the information, that the atomic weight of vanadium is 855°87: that it combines with 1, 2 and 3 atoms of oxygen, with the latter quantity forming vanadic acid; that by driving off the ammonia, in an open vessel, the acid would be ob- tained; and that by the same process, out of access of air, the oxide would be produced. The acid was the first subject of experiment. It is a dull orange red powder, as described in your last Number, p. 152 ; and the neutral salts it forms with alkaline and earthy bases are white; which would hardly have been expected, consider- ing the analogies of vanadium with chrome. With excess of acid, however, they are yellow. 1. Vanadiate of potash is very soluble, and showed no dis- position to crystallize, although evaporated slowly to dryness, with frequent intervals of cooling, and afterwards redissolved and left to spontaneous evaporation. 2. Vanadiate of soda is scarcely so soluble, but not more disposed to crystallize. 3. The quantities employed amounting to only about 2 grains of each salt, and the indisposition to crystallize being perhaps due to the smallness of the quantity, the two solutions were mixed and abandoned to spontaneous evaporation; the glass N.S. Vol. 10. No. 57. Sept. 1831. 2E being 210 Mr. J. Prideaux’s Experiments on Vanadiate of Ammonia, being occasionally made to vibrate, by striking on the edge with a steel blade. The salts were, however, left on the glass in two successive coatings; and a film, which had formed upon the liquor, was studded beneath with brilliant globules, in which no facets could be discovered by the microscope. 4. Vanadiate of ammonia is much less soluble, falling like cream of tartar; it crystallized freely, on cooling, in acute rhombic blades, like spear-heads. 5. Vanadiate of lime is still less soluble than the last, and also crystallized in cooling. Crystalline form not unlike the other, but thicker. The crystals were, however, so irregular that but few could be defined. 6. Vanadiate of barytes. A solution of 1°482 grains of vanadiate of ammonia, containing an atom of water, was mixed with a solution of 1*312 grain of chloride of barium; the whoie fluid became full of coagula, which settled, by boiling, into a heavy white power. The residual liquor,was evaporated and tested in the usual manner, and the decomposition was found complete, so far as could be ascertained by this mode. This precipitate affords a convenient method of recovering the vanadic acid used in experiments. Mixing together the various soluble vanadiates, solution of muriate of barytes may be added, in slight excess, keeping the liquor hot. ‘The vanadiate of barytes will quickly subside, and may be readily washed. It is then (whilst quite recent) to be thrown into 40 or 50 parts of water, with a little excess of sulphuric acid; when it will assume the deep orange colour of bi-chromate of potash. It may digest for half an hour, with occasional shaking ; when carbonate of ammonia is to be added, a small lump at a time, letting it dissolve gradually, and mixing up the liquor well before each addition, till the liquor is neutral, avoiding much excess of the carbonate. ‘The precipitate will then be white or will become so by boiling in the liquid; and after washing to remove the adhering solution will not be discoloured by fresh sulphuric acid. The liquor will contain sulphate and vanadiate of ammonia, which are to be separated by crystallization. In the following experiments, solution of vanadiate of am- monia was dropped into excess of the metallic solutions; the persulphate of iron was prepared by heating protosulphate in a test-tube with nitric acid, and contained that acid in excess; —the others were all pure. Immediate Effect. | After 12 Hours. Sulpate § No precipitate; the liquid assumed | A pulverulent yellowish- oe oi i, a greenish-yellow hue, becoming white precipitate; the rene: gradually yellower and turbid. liquid orange yellow. Green and on some other Compounds of Vanadium. colour, with a tint of green. Immediate Effect. ue An abundant flocculent dark slate Ss bh A coloured precipitate, leaving the oF alg liquid a paler shade of a similar ae deep orange. An orange-coloured precipitate at oy Little or no precipitate; the liquid | first contact, appearing greener | > pera on mixing with the blue solution ; Copper settled, pale yellowish green, : leaving the liquid a deeper shade e yok the same colour. Nitrate of Slight precipitate, pale salmon-co- Cobalt. loured, liquid scarcely altered. ( Precipitate copious and heavy, of saeete } nearly the same colour as the hong above, settling paler and more orange ; the liquid colourless. Corrosive ( An orange precipitate; heavy, Subli- settling yellower ; the liquid dull mate. pale yellowish green. Tartar F dissolv n shaking ; teres Emetic. ed on shaking ; and giving J A brownish orange coagulum, re- | that hue to the liquid. L 211 After 12 Hours. The precipitate unchang- ed; the liquid greener, like soluticn of sul- phate of iron. Unchanged. The precipitate inclines to orange colour; the liquor remains _ yel- lowish green. Unchanged. The precipitate almost bleached, probably by taking down excess of lead. The precipitate yellow; liquid the colour of chlorine. The liquid opalescent, dull pale green by re- flected, and orange by transmitted light; no precipitate. With vanadium as a base, the operations were more embar- rassing. The oxides formed simultaneously, during the decom- position of vanadiate of ammonia, and were difficult to separate. One of them would seem to possess acid properties; and the other to be partly converted into that in washing, and partly to combine with it, forming a soluble compound, not precipi- tated either by alkalies or acids*. The experiments were in- conclusive, and the description of them must be very general. Two portions of vanadiate of ammonia were decomposed by heating in a close platinum crucible: one of them had been recovered from former experiments, by precipitation with barytes, as above described, and probably was not free from sulphuric acid. The other had only been converted into vanadic acid, redissolved in liquid ammonia and crystallized. The first left an oxide of a deep blue or green colour, al- most black. As it was supposed to contain sulphuric acid, it was subjected to that acid, a drop of which turned the part with which it lay in contact, light green; but the addition of a few drops of water, after some hours, to give fluidity to the whole, turned it deep blue, and syrupy, like undiluted sul- phate of indigo. After twelve hours digestion, about 30 parts * See our last Number, p. 152,—Eprv. 2h? more 212 Mr. J. Prideaux’s Experiments on Vanadiate of Ammonia, more water were added, by which it was dissolved; and after the subsidence of a yellow sediment the solution was pale blue and strongly acidulous. The yellow sediment dissolved in liquid ammonia, and was vanadic acid. Carbonate of barytes in fine powder was added to the solu- tion, to get rid of the excess of sulphuric acid. It produced little effect, til] heat was applied; when effervescence took place, the liquid became pistachio-green, and a flocculent dark olive precipitate appeared; which gradually subsided, leaving the liquor stiil blue and acidulous. Liquid ammonia did not render it neutral, until a nearly black precipitate had fallen in considerable quantity ; almost the whole of which was taken up again by ammonia in excess. In the second attempt the precaution was taken to add car- bonate of ammonia in decomposing the salt, that the first impression of heat might fill the crucible with an atmosphere of that substance. ‘lhe remaining oxide, however, still con- tained vanadic acid. The solution in muriatic acid was blue, and could not be neutralized without precipitation. Before neutralization took place, liquid ammonia threw down an olive precipitate, and made the liquor green, as above. ‘The green liquid, poured off, and gradually neutralized with ammonia, gave a dark- brown precipitate. The olive precipitate dissolved green, the brown one blue, in muriatic acid. After various experiments, in none of which did the oxide of vanadium neutralize the acid employed, or yield with it a crystallized salt, the solutions were mixed together, and thrown into an excess of caustic potass, largely diluted. A deep brown light precipitate fell, doubtless hydrate of the oxide (most probably of the protoxide), leaving the liquor of the same colour but transparent. A portion of this liquor was withdrawn, and mixed with bi-carbonate of potash, when it bleached, but without precipitating. The remainder was then poured off and tried with muriatic acid, in slight excess, which produced the green colour mentioned before, but without disturbing the transparency. Caustic potash was then slowly added, and whilst still acidulous, an inky precipitate fell; after which a reddish brown one followed, when the liquor became neutral. } The reddish-brown and purple precipitates were both solu- ble in acids, alkalies, and distilled water, and were therefore difficult to wash ; both also reddened litmus paper. ‘The brown precipitate became purple on the surface, when no great depth of water lay on it, and at the same time square plates formed in it, very small and thin, iridescent by reflected, but deep yellow and on some other Compounds of Vanadium. 213 yellow by transmitted light, which dissolved green in muriatic acid without neutralizing it. None of these on being dissolved in alkali and neutralized, produced precipitates in the metallic solutions, similar to those with vanadiate of ammonia, and therefore none appeared to contain vanadic acid; nor did I succeed in obtaining a solution of the brown precipitate in an acid, either neutral or which could be neutralized with am- monia, without precipitation; a difficulty which I attribute to its absorption of oxygen in washing. Attempts to obtain more of it by boiling the other oxides with de-oxydating substances were also frustrated by the difficulty of separating it after- wards. The solutions and precipitates were then mixed with nitric acid in excess, and boiled together to dryness; redissolved in solution of potash and boiled until colourless ; slightly acidu- lated with muriatic acid; precipitated with muriate of barytes ; and reconverted into vanadiate of ammonia, as above. A small bulb was then blown on a bit of glass tube, which was drawn out at half an inch from the bulb, and cut off, in the con- tracted part, so as just to allow the vanadiate of ammonia to enter. This salt was mixed with about half as much carbo- nate of ammonia, and put into the bulb, which it filled. The orifice was then nearly closed, at a spirit lamp; the neck thrust into the end of a quill, which was stuffed up with tow from the other end, so as very much to impede the access of air. ‘The bulb was then heated over a spirit lamp, till am- monia ceased to pass off: yet the oxide thus prepared did not yield either a neutral solution, or one disposed to crystal- lize, with sulphuric acid; and contained itself a large propor- tion of acid. Nor did it, after various experiments, give re- sults which could elucidate those above related. Vanadium gives, particularly in the reducing flame, a green bead with borax, of a tint rather yellower than that from chrome. Upon the whole the brown powder appears to me to be hydrate of the protoxide; the purple, a combination of that substance with the deutoxide; and the crystals, the same com- bination, but with the protoxide in larger proportion. The deutoxide seems to possess acid properties; to be soluble in acids as well as alkalies; and to yield, with metallic solutions, precipitates different from those with vanadic acid. The oxide, both brown and mixed,. dissolves blue in acids; but the so- lution becomes green by the addition of alkali, though still highly acidulous. ‘The square crystals dissolve green in acids, and the water becomes green when lying upon the surface of the oxide, as it changes to purple. Hence the solution of protoxide, 214 Notices respecting New Books. protoxide, in peroxide of vanadium, would appear to be green when the latter is in excess. But I cannot claim much faith for the inferences from these minute experiments, which must be resumed (unless we have more precise information in the meanwhile) if, by finding vanadium in our own neigh- bourhood, I can obtain a larger supply. I have examined a considerable number of phosphates and arseniates of lead, in which Mr. Johnstone’s description led me to suspect that substance; and some primitive iron ores, yielding a particu- larly soft metal; but have not hitherto found any traces of vanadium. Yours, &c. Plymouth, Aug. 10, 1831. J. PripEaux. XXIX. Notices respecting New Books. The Life of Sir Humpury Davy, Bart. LL.D.late President of the Royal Society, Foreign Associate of the Royal Institute of France, &c. &c. By John Ayrton Paris, M.D. Cantab. F.R.S. &c. Fellow of the Royal College of Physicians. = 4 bate great end of biography,” Dr. Paris remarks, “is not to be found, as some would seem to imagine, in a series of dates, or in a collection of gossiping anecdotes and table talk, which, instead of lighting up and vivifying the features, hang as a cloud of dust upon the portrait ; but it is to be found in an analysis of human genius, and the development of those elements, to whose varied combinations, and nicely adjusted proportions, the mental habits, and intellectual peculiarities of distinguished men may be readily referred.” Although we admit this to be a just description of the proper aim and end of biography, yet we confess we should have great pleasure in quoting from Dr. Paris a variety of anecdotes which illustrate what he terms “superficial peculiarities ;’ for they are not only amusing, but they tend, to a certain extent, to elucidate the progress of Sir H. Davy’s genius in cultivating the science, whose limits have been so greatly extended by the variety, spendour and importance of his discoveries. In the present instance, how- ever, so much is due to the merits of the philosopher, that we can dwell but little upon the characteristics of the man. Humphry Davy was born at Penzance in Cornwall, on the 17th of December 1778 ; his ancestors it appears had long possessed a small estate at Varfell, in the parish of Ludgvan, in the Mount’s Bay, on which they resided. His father was a carver of wood; and of him Dr. Paris observes, what indeed may be said of the father of many an illustrious son, that he “is not able to discover that he was remarkable for any peculiarity of intellect; he passed through life without bustle, and quitted it with the usual regrets of friends and relatives.” His mother, whose maiden name was Grace Millet, appears Notices respecting New Books. 215 appears to have possessed remarkable placidity of temper, and an amiable and benevolent disposition. When very young he was placed at the Grammar School in Pen- zance, whence he went to Truro, where he finished his education. Although quick and industrious in his school exercises, he was found very deficient in the qualifications for the class of his age ; but by industry and attention he subsequently acquitted himself to the entire satisfaction of his master. In his boyish days he was fond of romance, of writing verses and ballads, of fireworks, shooting and fishing. The taste for poetry increased with his years, and Dr. Paris has given some specimens of his poetic talent which are not unworthy of his genius. At twelve years of age he composed an epic poem, of which, however, not even a fragment has been preserved. His love of fishing he always re- tained: it appears, indeed, to have increased, rather than dimi- nished with his years.—‘* His temper during youth,” says Dr. Paris, ‘‘ is represented as mild and amiable. He never suppressed his feel- ings, but every action was marked by ingenuousness and candour.” In February 1795 he was apprenticed to Mr. Borlase, a surgeon and apothecary, and afterwards a physician at Penzance; and al- though his mind had been for some time engrossed with philoso- phical pursuits, it does not appear that he had any decided turn for Chemistry, until after he had been placed with Mr. Borlase ; but he then commenced the study of it with ardour. “ As far as can be ascertained,” says Dr. Paris, “ one of the first original experiments on chemistry performed by him at Penzance, was for the purpose of discovering the quality of the air contained in the bladders of sea-weed, in order to obtain results in support of a favourite theory of light ; and to ascertain whether, as land vegetables are the renovators of the atmosphere of land animals, sea vegetables might not be the preservers of the equilibrium of the atmosphere of the ocean. From these experiments he concluded, that the dif- ferent orders of the marine Cryptogamia were capable of decom- posing water, when assisted by the attraction of light for oxygen.” He seems also to have paid attention to Geology while with Mr. Borlase ;—during his walks his usual companion was a hammer, with which he procured specimens from the rocks on the beach.—*« In short,” observes Dr. Paris, “it would appear that, at this period, he paid much more attention to philosophy than to physic; that he thought more of the bowels of the earth than of the stomachs of his patients; and that when he should be bleeding the sick, he was opening veins in the granite.” During his stay with Mr. Borlase he became acquainted with Mr. Davies Gilbert (then Giddy), who accidentally hearing that he was fond of chemical experiments, expressed a desire to have some conversation with him; and during this he soon discovered ample evidence of young Davy’s singular genius, and the consequence was an offer of the use of his library or any other assistance he might require for the pursuit of his studies. In October 1798 Davy quitted Penzance to superintend the Pneu- 216 Notices respecting New Books. Pneumatic Institution at Bristol, established by Dr. Beddoes for the purpose of investigating the medicinal powers of factitious airs or gases. “It is now generally acknowledged,” says Dr. Paris, ‘ that the Art of Physic has not derived any direct advantage from the application of a class of agents, which undoubtedly held forth the fairest promise of benefit.” ** The investigation, however,” he con- tihues, “ into the nature and composition of the gases paved the way to some new and important discoveries in science; so that to borrow a Baconian metaphor, although our philosophers failed in obtaining the treasure for which they so eagerly dug, they at least, by turning up and pulverizing the soil, rendered it fertile. The ingenuity of the chemist will for ever remain on record; the phan- toms of physicians have vanished into air.” In a letter to Mr. Davies Gilbert, dated Clifton, November 12, 1798, Davy says, ‘“‘ We are printing in Bristol the first volume of the West Country Collections, which will I suppose be out in the beginning of January.” Dr. Paris informs us that “the work an- nounced in the above letter was published in the commencement of the year 1799, under the title of ‘ Contributions to Physical and Medical Knowledge, principally from the West of England; col- lected by Thomas Beddoes, M.D.’” The following are Dr. Paris’s observations on this work: ‘“ ‘The first two hundred pages, constituting very nearly half the volume, are the composition of Davy, and consist of essays ‘ On Heat, Light, and the Combination of Light;’ < On Phos-oxygen, or Oxygen and its Combinations ;’ and ‘ On the Theory of Respiration.’ ‘¢ His first essay commences with an experiment, in order to show that light is not, as Lavoisier supposed, a modification or an effect, of heat, but matter of a peculiar kind, suz generis, which, when moving through space, or in a state of projection, is capable of be- coming the source of a numerous class of our sensations.” «A small gunlock was armed with an excellent flint, and on being snapped in an exhausted receiver, did not produce any light. The experiment was repeated in carbonic acid, and with a similar result. Small particles were in each case separated from the steel, which, on microscopic examination, evidently appeared to have un- dergone fusion. Whence Davy argued, that light cannot be caloric in a state of projection, or it must have been produced in these ex- periments, where heat existed to an extent sufficient to fuse steel. Nor, that it can be, as some have supposed, a vibration of the ima- ginary fluid ether ; for, granting the existence of such a fluid, it must have been present in the receiver. If, then, light be neither caloric in a state of projection, nor the vibration of an imaginary ether, it must, he says, be a substance suz generis.” ~ ** With regard to caloric, his opinion that it is not, like light, material, has been already noticed. In the present essay he main- tains the proposition by the same method of reasoning as that by which he attempts to establish the materiality of light, and which mathematicians have termed the ‘ reductio ad absurdum.’ ” “In his chapter on Light and its Combinations,” he indulges in specu- Notices respecting New Books. 207 speculations of the wildest nature, although it must be confessed that he has infused an interest into them which might almost be called dramatic. They are certainly highly characteristic of that enlightened fancy, which was perpetually on the wing, and whose flight, when afterwards tempered and directed by judgement, en- abled him to abstract the richest treasures from the recesses of abstract truth.” ‘«« Taking it for granted that caloric has no existence as a ma- terial body, or, in other words that the phenomena of repulsion do not depend upon the agency of a peculiar fluid, and that on the contrary, light is a subtile fluid acting on our organs of vision only when in a state of repulsive projection ; he proceeds to examine the French theory of combustion; the defects of which he con- siders to arise from the assumption of the imaginary fluid caloric, and the total neglect of light. He conceives that the light evolved during combustion previously existed in the oxygen gas, which he therefore proposes for the future to call PHos-oxYGEN.” «In following up this question, he would seem to consider light as the Anima Mundi, diffusing through the universe not only organi- zation, but even animation and perception.” «« Phos-oxygen, he considers as capable of combining: with addi- tional proportions of light, and of thus becoming ‘luminated phos- oxygen!’ From the decomposition of which, and the consequent liberation of light, he seeks to explain many of the most recondite phznomena of nature.” “ We cannot but admire the eagerness with which he enlists known facts into his service, and the boldness with which he ranges the wilds of creation in search of analogies for the support and il- lustration of his views. He imagines that the phos-oxygen when thus /uminated, must necessarily have its specific gravity consider- ably diminished by the combination, and that it will therefore oc- cupy the higher regions of the atmosphere; hence, he says, it is that combustion takes place at the tops of mountains at a lower temperature than in the plains, and with a greater liberation of light. The hydrogen which is disengaged from the surface of the earth, he supposes will rise until it comes into contact with this dwminated ‘acne de when by its attracting the oxygen to form water, the ight will be set free, and give origin to the phznomena of fiery meteors at a great altitude.” “The phaznomena termed ‘ Phosphorescence,’ or that ]Juminous appearance which certain bodies exhibit after exposure to heat, is attributed by this theory to the light, which may be supposed to quit such substances as soon as its particles have acquired repulsive motion by elevation of temperature.’—* The eiectric fluid is con- sidered as light in a condensed state, or, in other words, in that peculiar state in which it is not supplied with a repulsive motion sufficiently energetic to impart projection to its particles; for he observes, that its chemical action upon bodies is similar to that of light; and when supplied with repulsive motion by friction, or by the contact of bodies from which it is capable of subtracting it, it N.S. Vol. 10. No. 57. Sept. 1831. 2k loses 218 Notices respecting New Books. loses the projectile form, and becomes perceptible as light. It is extremely probable, he adds, that the great quantity of this fluid almost every where diffused over our earth is produced by the con- densation of light, in consequence of the subtraction of its repul- sive motion by black and dark bodies; while it may again recover the projectile force by the repulsive motion of the poles, caused by the revolution of the earth on its axis, and thus appear again in the state of sensible light; and hence the phenomenon of the Aurora Borealis, ov Northern Lights.” «In considering the theory of respiration, he supposes that phos- oxygen combines with the venous blood without decomposition, but that on reaching the brain, the light is liberated in the form of electricity, which he believes to be identical with the nervous fluid. On this supposition, sensations and ideas are nothing more than motions of the nervous ether ; or light exciting the medullary sub- stance of the nerves and brain into sensitive action !” “ He thinks it would be worth while to try, by a very sensible electrometer, whether an insulated muscle, when stimulated into action, would not give indications of the liberation of electric fluid, although he suspects that in man the quantity is probably too small, and two slowly liberated, to be ascertainable. In the torpedo, and in some other animals, however, it is unquestionably given out per- ceptibly during animal action.” «‘When any considerable change takes place in the organic matter of the body, so as to destroy the powers of life, new chemical at- tractions and repulsions take place, and the different principles of which the body is composed enter into new combinations. In this process, which is called putrefaction, Davy, in pursuance of this theory, thinks that in land animals the latent heat of the system enters into new combinations with oxygen and nitrogen, but that in fish no such combinations occur, and hence the luminous appear- ance which accompanies their putrefaction.” Dr. Paris very justly characterizes these essays as extraordinary ; but ‘I am not quite sure,” he adds, “ that amidst all the meteors of his fancy there may not be a gleam of truth. I allude to his theory of Respiration: it certainly does not square with the phy- siological opinions of the day ; nor did that of Newton, when he conjectured that water might contain an inflammable element ; but it was the refraction of a great truth, at that time below the hori- zon.” We admit with Dr, Paris, that the theory of phos-oxygen and luminated phos-oaygen has scarcely a parallel in extravagance and absurdity, and with him we also “ happen to know that in after life Davy bitterly regretted that he had so committed himself; any allusion to the subject became a source of painful irritation.”— This was precisely the effect produced upon him by the notice which Chenevix took of his theory in his treatise on nomenclature. After all, Dr. Paris rightly observes, “ the reader, however, will be disposed to treat him with all tenderness when he remembers that the author of these essays was barely eighteen years of age.” In a letter to Mr. Gilbert, dated Clifton, February 22, 1799, he gives Notices respecting New Books. 219 gives an account of the discovery that two pieces of canes rubbed together gave a faint light, which he shows was occasioned by the silica contained in the epidermis. In the same letter he announces a more important fact— I made a discovery yesterday, which proves how necessary it is to repeat experiments. The gaseous oxide of azote is perfectly respirable when pure. It is never dele- terious but when it contains nitrous gas. I have found a mode of obtaining it pure, and 1 breathed to-day, in the presence of Dr. Beddoes and some others, sixteen quarts of it for near seven minutes. It appears to support life longer than even oxygen gas, and absolutely intoxicated me. Pure oxygen gas produced no al- teration in my pulse, nor any other material effect; whereas this gas raised my pulse upwards of twenty strokes, made me dance about the laboratory like a madman, and has kept my spirits in a glow ever since. Is not this a proof of the truth of my theory of respiration? for this gas contains more light in proportion to its oxygen than any other, and I hope it will prove a most valuable medicine.” In the year 1800, appeared in one octavo volume, ‘ Researches, Chemical and Philosophical ; chiefly concerning Nitrous Oxide, or Dephlogisticated Nitrous Air and its Respiration. By Humphry Davy, Superintendant of the Medical Pneumatic Institution.’—This is a work containing the results of great labour and numerous ex- periments. Dr. Paris remarks that “it may perhaps appear ex- traordinary to the reader of the ‘ Researches,’ that although they were published not more than eighteen months after the appearance of his ‘ Essays on Heat and Light,’ no allusion is made in them either to his theory, or his new nomenclature. In relating his ex- periments upon respiration, he employs the conventional janguage of the schools, and the word ‘ phos-oxygen’ does not once occur in the volume. This is fully explained in a communication made by him to Mr. Nicholson, and which was printed in his Journal a short time after the publication of his Essays in the West Country Contributions; in which he says, ‘As facts have occurred to me with regard to the decomposition of bodies, which I had supposed to contain light, without any luminous appearance, I beg to be con- sidered as a sceptic with respect to my own particular theory of the combinations of light, until 1 shall have satisfactorily explained these anomalies by fresh experiments. On account of this scepti- cism, and for other reasons, [ shall in future use the common nomenclature ; excepting that, as my discoveries concerning the gaseous oxide would render it highly improper to call a principle, which in one of its combinations is capable of being absorbed by venous blood, and of increasing the powers of life, azote,—I shall name it, with Dr. Pearson, Chaptal and others, NrrroGENe; and the gaseous owide of azote | shall call Nrrrous OxipE.” “There is one circumstance connected with the views enter- tained in this work,” observes Dr. Paris, “‘ which must not be passed over without notice. Jn several passages he advocates the theory of the atmosphere being a chemical compound of oxygen and nitro- 2F2 gen; 220 Notices respecting New Books. gen; whereas in later years he was amongst the first to insist upon its being simply a mechanical mixture of these gases.” Soon after the appearance of the ‘ Researches,’ Davy was invited by Count Rumford to the Royal Institution, which had been recently formed under his auspices ; he arrived at the Institution on the 11th of March 1801, inthe capacities of Assistant Lecturer on Chemistry, Director of the Laboratory, and Assistant Editor of the Journal of the Institution : in about six weeks he was appointed Lecturer on Chemistry instead of Assistant; and in May 1802 he was styled Professor of Chemistry. On the 2st of January 1801, Davy gave the introductory lec- ture to the first regular course; this was exceedingly well received by a numerous audience, and was printed ; he had previously given occasional lectures, but this must be considered as the commence- ment of his splendid career. This course of lectures, as appears from a printed sy!labus, was divided into three parts :—the che- mistry of ponderable substances ; the chemistry of imponderable substances ; and the chemistry of the arts. From this period he continued regularly to increase in fame and popularity ; his first paper in the Journal of the Royal Institution is entitled ‘ An Account of a New Eudiometer;’ this was simply a small graduated tube di- vided into 100 parts, immersed into a solution of protosulphate or protomuriate of iron, impregnated with nitric oxide: as Dr. Priestley had not only employed this gas as a eudiometrical substance, but had shown the power of sulphate of iron in absorbing it, Dr. Paris very justly remarks, that this test “ can only be regarded as a con- venient modification of that of Priestley, in which nitrous gas was presented to the atmospheric air to be examined, without the inter- vention of any third body.” The Royal Institution Journal contains several other communica- tions from him, under the titles of ‘ Observations on different me- thods of obtaining Gallic Acid ;* ‘ On the Processes of Tanning, &c.’ All the new facts were embodied in an elaborate memoir, and read before the Royal Society, of which he was elected a Fellow on the 17th of November, 1803; in 1801 he had communicated to the Society his first paper, entitled ‘ An Account of some Galvanic Com- binations, formed by single metallic plates and fluids, analogous to the Galvanic Apparatus of M. Volta.’ After this followed the paper to which we have above alluded, and then ‘An Account of some Analytical Experiments on a Mineral Production from Devonshire, consisting principally of Alumina and Water. The Rev. William Gregor had detected the presence of fluoric acid in this substance. “The subsequent experiments of Berzelius, however,” Dr. Paris remarks, ‘‘ cleared away the obscurity in which the subject was still involved. He showed that this mineral not only contained in its composition a small portion of the neutral fluate of alumina, but he demonstrated the presence of a subphosphate of that earth, to no in- considerable amount. Much has been said of the error committed on this occasion by Davy, in overlooking thirty-three per cent. of phosphoric acid ; but the phosphate of alumina is a body that might very Nolices respecting New Books. 221 very easily have escaped notice at a period when mineral analysis was in a far less advanced state than it is at present.” We profess utter ignorance as to the parties who have said much on this occasion : the mistake might be readily pardoned at all times by those ac- quainted with the difficulties of chemical analysis ; this will be still more readily admitted, when it is recollected that Berzelius himself, certainly one of the most skilful analysts that ever existed, actually overlooked sixteen per cent. of the same acid in uranite. His next paper was entitled ‘An Account of analyzing Stones containing a fixed Alkali, by means of Boracic Acid’: for this and the above-mentioned papers the Society awarded him the Copley medal. This communication was followed by the Bakerian lecture, read on the 20th of November 1806. According to Dr. Paris, this paper “‘ unfolded the mysteries of general voltaic action ; and as far as theory goes, may be almost said to have perfected our knowledge of the chemical agencies of the pile. This grand display of scientific light burst over Europe like a spendid meteor, throwing its radiance into the deepest recesses, and opening to the view of the philosopher new and splendid regions.” The subjects investigated in this memoir are arranged by Dr. Paris as follows :—the changes produced in water by electricity; the agencies of electricity in the decomposi- tion of various compound bodies ; the transfer of certain constituent parts of bodies by the action of electricity; the passage of acids, al- kalies and other substances, through various attracting chemical menstrua, by means of electricity ; general observations on these phenomena, and on the mode of decomposition and transition ; the general principles of the chemical changes produced by electricity ; the relations between the electrical energies of bodies and their chemical affinities ; the mode of the action of the pile of Volta, with experimental elucidations ; general illustrations and applications of the foregoing facts and principles. Dr. Paris gives a_very able analysis of this paper, which we should be glad to copy if our space would allow. It is no small commendation of this paper that the author received for it the prize of the French Institute. Davy’s second Bakerian Lecture was read on the 19th of November 1807. Of this lecture Dr. Paris also gives an analysis, for which we must refer to his book: to stamp the value and importance of this communication, it would be sufficient to say that it announces the discovery of the metallic bases of the alkalies, potash and soda. On this subject Dr. Paris well remarks, ‘thus then was a discovery ef- fected, and at once rendered complete, which all the chemists in Europe had vainly attempted to accomplish. The alkalies had been tortured by every variety of experiment which ingenuity could sug- gest, or perseverance perform, but all to no purpose ; nor was the pursuit abandoned until indefatigable effort had wrecked the patience and extausted the every resource of the experimentalist. Such was the disheartening, and almost forlorn condition of the philosopher, when Davy entered the field :—he created new instruments, new powers, and fresh resources; and Nature, thus interrogated on a different plan, at once revealed her long cherished secret.” It is observed by Davy in his Bakerian Lecture, that “an account of the 222 Notices respecting New Books. the manipulations employed and the difficulties overcome would ex- ceed the limits of a lecture.” Well knowing how valuable every minute circumstance is to the chemist, Dr. Paris searched into the archives of the Institution ; the result of the examination of the Laboratory Register, we shall give in Dr. Paris’s words: ‘“ It appears from this register that Davy commenced his inquiries into the com- position of potash on the 16th, and obtained his great result on the 19th of October, 1807 *. His first experiments, however, evidently did not suggest the truth: he does not appear to have suspected the nature of the alkaline base until his last experiment, when the truth flashed upon him in the full blaze of discovery. His first note, dated the 16th, leads us to infer that he acted on a solid piece of potash, under the surface of alcohol, and several other liquids in which the alkali was not soluble; and that he obtained gaseous matter, which he called at the moment ‘ alkaligen gas,’ and which he appears to have examined most closely, without arriving at any con- clusion as to its nature. On the following day, he for the first time would seem to have developed potassium by electric action on potash under oil of turpentine, for the note records the fact of ‘ the globules giving out gas by water, which gas burnt in contact with air ;’ and then follows a query, ‘ Does it (the matter of the globules) not form gaseous compounds with ether, alcohol, and the oils?’ Here, then, he evidently imagined, that the matter of the globules, which he had never obtained from potash, except when acted upon under oil of turpentine, had formed gaseous cumpounds with the ether, alcohol and oils, in his previous experiments, and given origin to that which he had termed ‘ alkaligen gas.’ ” «« He then leaves the consideration of this gas, and attacks the un- known globules, which probably did not present any metallic ap- pearance under the circumstances in which he first saw them, for they must have been as minute as grains of sand. I rather think that he commenced his examination by introducing a globule of mercury, and uniting it with a globule of the unknown substance ; for his note says, ‘Action of the substance on mercury, forms with it a solid amalgam, which soon loses its alkaligen in the air ;’ and from the note which succeeds, he evidently considered this alkaligen (potassium) as volatile, as he says ‘it soon flies off on exposure to the air.” “ October ]9.—It is probable that in consequence of the property which the unknown substance displayed of amalgamating with mer- eury, he devised his experiment of the 19th. He took a small glass tube, about the size and shape of a thimble, into which he fused a platinum wire, and passed it through the closed end. He then put a piece of pure potash into this tube, and fused it into a mass about the wire, so as entirely to defend it from the mercury afterwards to be used. When cold, the potash was solid, but containing moist- ure enough to give it a conducting power ; he then filled the rest of the tube with mercury, and inverted it over the trough; the appa- * On the same day he decomposed soda, with somewhat different pha- nomena, ratus Royal Society. 223 ratus being thus arranged, he made the wire and the mercury alter- nately positive and negative.” Dr. Paris then gives an engraving of the autograph account of the results, the substance of which is as follows :—‘‘ When potash was introduced into a tube having a platina wire attached to it ——so— and fused into the tube so as to be aconductor, i. e. so as to contain just water enough, though solid, and inserted over mercury, when the platina was made negative, no gas wus formed, and the mercury became oxydated, and a small quantity of the alkaligen was produced round the platina wire, as was evident from its quick inflammation by the action of water. When the mercury was made the negative, gas was developed in great quan- tities from the positive wire, and none from the negative mercury, and this proved to be pure oxygene.—A capitan Experiment, PROVING THE Decomposition oF Porasu.” On the subject of this great discovery, Dr. Paris observes, “ In the progress of our ascent, it is refreshing to pause occasionally, and to cast a glance at the horizon, which widens at every increase of our elevation. By the decomposition of the alkalies and earths, what an immense stride has been made in the investigation of na- ture! In sciences kindred to chemistry, the knowledge of the com- position of these bodies, and the analogies arising from it, have opened new views and led to the solution of many problems. In geology, for instance, has it not shown, that agents may have ope- tated in the formation of rocks and earths, which had not been pre- viously known to exist? It is evident that the metals of the earths cannot remain at the surface of our globe ; but it is probable that they may constitute a part of its interior ; and such an assumption would at once offer a plausible theory in explanation of the pheno- mena of volcanoes, the formation of lavas, and the excitement and effects of subterranean heat, and might even lead to a general theory in geology.” [To be continued. ] XXX. Proceedings of Learned Societies. ROYAL SOCIETY. June 2nd — PAPER was read, “ On the Caves and Fissures in the Western District of the Mendip Hills.” By the Rev. David Williams, A.M. F.G.S., Rector of the parishes of Bleadon and Kingston-Seamoor, in the County of Somerset. Com- municated by Davies Gilbert, Esq. V.P.R.S. The first cavern described in this paper is situated at Uphill, at the very western extremity of the Mendip Hills. Its present en- trance is about midway in a mural face of transition limestone, about a hundred feet high. The fissure leading into it is nearly vertical, and was discovered by some quarry-men casually inter- secting it. Some bones and teeth being found there, the author was induced to pursue the exploration of the fissure; in the course of which he discovered bones of the rhinoceros, hyena, bear, ox, horse, hog, fox, polecat, rat and mouse, and also of birds. The bones of 224 Royal Society. of the animals of the larger species were so gnawed and splintered, and evidently of such ancient fracture, that no doubt could exist of the cave having been a hyena’s den, similar to Kirkdale and Kent’s Hole. All the ancient remains were found in the upper regions of the fissure, and were so firmly imbedded in the detritus, as not to be extracted without difficulty with the pick-axe. Further on he found a wet tenacious loam, abounding with an innumerable quan- tity of bones, belonging exclusively to birds. After working six days he came to a cavern, ten or twelve feet high, extending about forty feet from north to south, and varying from eight to twenty feet from east to west ; the floor of which was covered with bones of sheep: and on digging into the mud and sand of which it con- sisted, the bones of sheep, birds, cuttle-fish, and foxes, were disco- vered. Some fine stalactites depended from the roof, and partial spots of stalagmite appeared on the floor. Ina fissure that branched from the mouth of the main entrance there were found, among the sand, a piece of black Roman pottery, and two coins, one of Didius Julianus, and the other of Julia Mammea, together with bones of sheep, cuttle-fish, foxes, and birds. The author considers that there exist evidences of the operation of water at three distinct periods of time :—the first indicated by the bones of the hyzna, and the other gnawed bones firmly im- bedded in the diluvial detritus: the second, when sand was depo- sited by the sea in the second fissure, that washed in through the vertical chimney, and that inundated the whole valley up to Glas- tonbury: the third irruption of the sea occurring within these fif- teen hundred years, and choking up the adit from the level by which the sheep and foxes had entered, floating in the bones of the cuttle- fish, and depositing the thin crust of mud which covered the sand. The coins and pottery he supposes to have been introduced through this entrance from the level. The author next gives an account of the Hutton caverns, situated on the northern escarpment of the range, commonly called Bleadon Hill. This cavern had been discovered some time ago and noticed by Mr. Catcott in his “ Treatise on the Deluge:” but afterwards it became inaccessible by the falling in of the roof and sides. The author, led by some indications of pieces of ancient bones in the rubbish of some old pits, sought for this cavern by sinking a shaft, and succeeded in opening into it. The chambers he reached are probably the western extremity of a very extensive range of ca- verns, occurring in a region bearing marks of great disturbance, abounding in chasms and fissures, and containing a great number of bones. The principal of those discovered belong to the elephant, tiger, hyena, wolf, boar, horse, fox, hare, rabbit, rat, mouse, and bird. No trace of the bones of the ox were discovered here, al- though in the cave at Banwell Hill, about a mile distant, they abound; while, on the other hand, no vestige of the horse is met with. Among the remarkable specimens found in the Hutton caverns were the milk-teeth and other remains of a calf elephant about two years Royal Society. 225 years old, and those of a young tiger just shedding its milk-teeth ; and also the molares of a young horse that were casting their coro- nary surfaces ;—the remains of two hyznas of the extinct species ; and two or three balls of album grecum. The Banwell caves, lying about a mile to the east of Hutton, are next described. They are the property of the present Bishop of Bath and Wells ; and contain remains of the bear, wolf, fox, deer, and ox. Of the bear there are at least two species ; one of which appears to be the Ursus speleus of Blumenbach, and must have been an animal of immense size and strength. These remains were, in general, not associated according to the animals they belonged to, but indiscriminately dispersed : thus the head of a bear lay by the femur of an ox, and the jaw of a wolf lay by the antler of a deer. Hence the author infers that these bones, after accumulating for ages, were carried in by a tumultuous rush of waters, and mingled together before their final deposition. He concludes that the se- veral animals whose remains are deposited in the Banwell and Bur- lington caves belonged to a very different age and period from those found at Hutton and Uphill. An account is also given of two caves at Burrington Coomb, lying about six miles to the east of Banwell, in one of which, though similar in appearance to the caves already described, no ante- diluvian remains of animals lave been found. Several human skeletons, and flint knives and celts, were discovered there by Mr, Williams ; from which it has been inferred that it had formerly been used asa burying-ground. Inthe upper caverns, remains of the bear, elk and polecat, were discovered; the two former evidently of the extinct species. June 9.—A paper was read, entitled “‘ Researches in Physical As- tronomy.” By J.W.Lubbock, Esq., V.P., and Treasurer of the Royal Society. The author extends, in the present paper, the equations he has already given for determining the planetary inequalities, as far as the terms depending on the squares and products of the eccentricities, to the terms depending on the cubes of the eccentricities and quantities of that order, which he does by means of a table, similar to the one given in his lunar theory ; and applies them particularly to the deter- mination of the great inequality of Jupiter, or at least such part of it as depends on the first power of the disturbing force. That part which depends on the square of the disturbing force may, he thinks, be most easily calculated by the methods given in his lunar theory. He re- commends it as particularly convenient to designate the arguments of the planetary disturbances by indices. The bulk of the paper is oc- cupied by the tables, and by examples demonstrating their use. A paper was read, “On the Theory of the Elliptic Transcendents.” By James Ivory, A.M., F.R.S., &c. Fagnani discovered that the two arcs of the periphery of a given ellipse may be determined in many ways, so that their diflerence shall be equal to an assignable straight line ; and proved that any arc of a lemniscate, like that of a circle, may be multiplied any number N.S. Vol. 10. No. 57. Sept. 1831. 3 of 226 Royal Society. of times, or may be subdivided into any number of equal parts, by finite algebraic equations. What he had accomplished with respect to the arcs of the lemniscates, which are expressed by a particular elliptic integral, Euler extended to all transcendents of the same class. Landen showed that the arcs of the hyperbola may be reduced, by a proper transformation, to those of an ellipse. Lagrange furnished us with a general method for changing an elliptic function into another having a different modulus; a process which greatly facilitates the numerical calculation of this class of integrals. Legendre distributed the elliptic functions into distinct classes, and reduced them to a re- gular theory, developing many of their properties which were before unknown, and introducing many important additions and improve- ments in the theory. Mr. Abel of Christiania happily conceived the idea of expressing the amplitude of an elliptic function in terms of the function itself, which led to the discovery of many new and useful properties. Mr. Jacobi proved, by a different method, that an elliptic function may be transformed in innumerable ways into another similar function, to which it bears constantly the same proportion. But his demonstrations require long and complicated calculations ; and the train of deductions he pursues does not lead naturally to the truths which are proved, nor does it present in a connected view all the conclusions which the theory embraces. The author of the present paper gives a comprehensive view of the theory in its full extent, and deduces all the connected truths from the same principle. He finds that the sines or cosines of the amplitudes, used in the transformations, are analogous to the sines or cosines of two circular arcs, one of which is a multiple of the other; so that the former quantities are changed into the latter when the modulus is supposed to vanish in the alge- braic expression. Hence he is enabled to transfer to the elliptic transcendents the same methods of investigation that succeed in the circle : a procedure which renders the demonstrations considerably shorter, and which removes most of the difficulties, in consequence of the close analogy that subsists between the two cases. A paper was read, entitled, “ An Experimental Investigation of the Phenomena of Endosmose and Exosmose.” By William Ritchie, Esq., M.A., F.R.S., Professor of Natural Philosophy in the Royal Institu- tion of Great Britain. Mr. Porret had, in the year 1816, announced the discovery, that if a vessel containing water be divided into two compartments by a dia- phragm of bladder, and placed in the voltaic circuit, the water would rise on the negative side above its level in the positive compartment. M. Dutrochet discovered, that if alcohol be placed in one of the cham- bers, and water in the other, without employing the voltaic battery, the water will percolate through the bladder, and the fluid will rise in the chamber containing the alcohol: an action to which he gave the names of Endosmose and Exosmose, according to its direction with regard to the side of the membrane considered ; comparing its two sides to those of a Leyden jar in opposite electrical states, This electrical theory has been combated by M. Poisson : but the true expla- nation of this singular phenomenon does not appear to have been yet given. Royal Society. 227 The experiments of the author, of which an account is-given in this paper, were made with a glass tube, about an inch in diameter, one end being drawn out into a slender tube of the interior diameter of one eighth of an inch, and having a piece of bladder tied over the other end. When this Endosmometer, as it has been called, is by means of a small fannel introduced into the narrow end filled with alcohol, and immersed in water, the water penetrates through the blad- der, and the spirit rises rapidly in the narrow stem. The author found on trial that this action was apparently not affected by a pow- erful current of voltaic electricity passed through the bladder, by in- troducing positive and negative wires on both sides of it. On sub- stituting a strong solution of sulphate of zinc for the alcohol, the same negative result was obtained. The author considers the action of the animal membrane to be the consequence of its strong attraction for water, an attraction to which it owes its hygrometric properties : while, on the other hand, the membrane has no attraction for alcohol, which has itself a powerful attraction for water. The water, therefore, finds its way easily through the membrane, and uniting with the alcohol, is carried off by it, and diffused through the liquid, making room for the other portions that successively come over. Whalebone and quills have similar hygro- metric properties, and may be substituted for membranes with the same effect. All substances readily soluble in water give rise to the phenomena of endosmose, on the same principle as alcohol, such as gum, sugar, and salts. The phenomenon bears a striking resem- blance to the rise of the sap in the capillary vessels of plants, both being probably dependent on the same principle; the filamentous texture of the roots performing the function of the membrane, and the contained sap that of the attractive fluid; by the agency of which the external moisture of the earth is imbibed and raised into the interior of the plant. June 16.—A paper was read, “On the Tides in the Port of London.” By J. W. Lubbock, Esq., V.P., and Treas. R.S. This paper contains a discussion of observations of the tides made at the London Docks, and registered in various Tables, showing the time and height of high water, not only at different periods of the moon’s age, but also for the different months of the year, for every minute of the moon’s parallax, and for every three degrees of her declination. ‘The tables themselves were registered by Mr. Dessiou of the Admiralty ; but the arrangement of the tables and the methods employed are due to the author. The tides in the river Thames are extremely regular; and as the rise is considerable, the observations on them are easily made. Those at the London Docks present an uninterrupted series from the opening of the Docks in 1804 to the present time ; which is more extensive than any extant, with the exception only of that made at Brest by order of the French Government. Some observations are also given of the tides made du- ring one year at the East India Docks, under the superintendence of Captain Eastfield, and which were undertaken at the suggestion of the author, and made with extreme care. 2G2 The 228 Royal Society. The author gives an account of the mode by which the several tables were constructed ; and enters at length into the various ma- thematical considerations which the subject involves. The author was enabled, by the kindness of the Chairman and Directors of the London Dock Company, to present to the Society the books containing the complete series of original observations on the tides referred to in this paper. A paper was read, “On the Friction of Fluids.” By George Rennie, Esq., V.P.R.S. The object of the author in this paper is to trace the relation sub- sisting between the different quantities of water discharged by orifices and tubes, and the retardations arising from the friction of the fluid. The results of the experiments hitherto made with a view of ascertaining the effects of the friction attending the mutual motion of solids and fluids, are exceedingly discordant, and there- fore undeserving of confidence. Whether, for example, the retarda- tion from friction be proportional to the surfaces, or to the velo- cities, are points by no means satisfactorily determined. The experiments of the author were designed to measure the re- tardations experienced by solids moving in fluids at rest; and of fluids moving over solids. For this purpose, he employed a cylinder of wood, about eleven inches in diameter and two feet in length, traversed by an iron axle, upon the upper part of which a small pulley was fixed. A fine flexible silken cord was wound round the pulley, at one end, and had a weight attached to the other end. A frame was provided, allowing the apparatus to slide up and down; and the cylinder to be immersed at various depths into the river Thames. When the velocities were small, the retardation was found to be nearly as the surface : but with great velocities it appears to have but little relation to the extent of the surface immersed. The resistances of iron discs and wooden globes revolving in water were found to be as the squares of the velocities. From the experiments made on the quantities of water discharged by orifices of different shapes and sizes from vessels kept constantly full, the author concludes, that they are in the ratio of the areas of the orifices, independently of their shape ; and nearly as the square roots of the heights. In pipes bent at various angles the retarda- tion occasioned by the flexure was not in proportion to their num- ber. A paper was read, “ On the Sources and Nature of the Powers on which the Circulation of the Blood depends,” By A. P. Wilson Philip, M.D. F.R.S. L. & Ed. In the first part of this paper the author discusses the opinions which ascribe the powers that maintain the circulation in the veins to the elasticity of the heart, the resilience of the lungs, and the dilatation of the thoracic cavity in the act of inspiration. He shows experimentally that the circulation continues unimpaired when all those causes have ceased to operate; and that the very structure of the veins, the coats of which are so pliable as to collapse by their own weight, when empty, renders it impossible that the motion pF the ——— Roological Society. 229 the blood could be maintained in them by any cause corresponding to a power of suction in the heart, The latter part of the paper is occupied by an inquiry into the sources and nature of the powers which really support the circula- tion of the blood. The capillaries, he observes, maintain the mo- tion of their blood long after the heart has ceased to beat; this motion not being immediately affected even by the entire removal of the heart ; but being accelerated, retarded, or arrested, according as the action of the capillaries is increased, impaired, or destroyed, by agents of which the operation is wholly confined to the vessels themselves, As the destruction of the heart does not immediately influence the motion of the blood in the capillaries, so the action of this organ, when in full vigour, can produce no motion of the blood in the capillaries, when these vessels are themselves deprived of power. Experiments are related with the view of proving that the arteries and veins, and more particularly the latter, are also capable of car- rying on the blood they contain, even in opposition to the force of gravitation, with the greatest ease, and without the aid of any ex- traneous power. With regard to the nature of the power exerted by the blood-vessels, the author shows that the capillaries are as readily influenced by stimulants and by sedatives, as the heart itself; and that the arteries and veins may also be made to obey the action of stimulants ; and further, that the power of the vessels bears the same relation to the nervous system as that of the heart, which is peculiar, and very different from the relation subsisting between that system and the muscles of voluntary motion. From the whole of the facts and experiments stated in this paper, the author de- , duces the conclusions, that the circulation is maintained by the combined power of the heart and blood-vessels, and that the power of both is a muscular power. ZOOLOGICAL SOCIETY. June 14, 1831. Joshua Brookes, Esq. in the Chair. A letter addressed to the Secretary of the Society by Charles Telfair, Esq., Corr. Memb. Z. S., dated Port Louis, December 15th, 1830, was read. It referred to previous unsuccessful attempts on the part of the Society’s valuable correspondent to transport from the Mauritius to England living Gowramies and Tanrecs, and promised a repetition of the experiment. Mr. Tel- fair states that he has now a pair of living Tanrecs fully grown ready to send to England when he can place them under proper care, ‘ They live on boiled rice, but will probably not exist long upon that alone, as their natural food is chiefly composed of worms, insects, lizards, and the eggs of snails, of which it would be difficult to carry a sufficient supply in a living state on board ship. Fresh supplies might, however, be obtained at Madagascar or the Cape of Good Hope, at St. Helena, Ascension, and the Cape de Verd Islands ; and the animals might thus arrive in good health in En- gland, where they would probably survive for some time burrowing under a dungheap, or living in straw in a bhot-house or green- house, 230 Soological Society. house. An opportunity would thus be furnished of observing their habits. Inthe Mauritius they sleep through the greater part of the winter, from April to November, and are only to be found when summer heat is felt, which being generally ushered in by an electric state of the atmosphere, the negroes (with whom they are a favour- ite food) say they are awakened by the peals of thunder which precede the summer storms or ‘pluies d’orage.’ Even in summer they are not often seen beyond the holes in which they burrow, except at night. Their favourite haunts are among the old roots of clumps of bamboos. They have a very overpowering smell of musk at all times, which is increased to an extraordinary degree when they are disturbed or frightened: yet their flesh is considered so savoury by the negroes that they are unwilling to sell those which they catch, and would not exchange it for any other food, except perhaps for the ‘ ourite,’ which is the Catfish hung up in the sun until it acquires a most fcetid smell, tainting the atmosphere to a great distance ; in this state it is a chief ingredient in their fa- vourite ragout. This mode of living may be one of the causes of the peculiar odour of the skin of the woolly-headed race, which no ablutions can remove, and which is not less distinctive of their race than the colour of the skin itself.” Mr. Telfair then refers to the collection of Fishes last presented by him to the Society, portions of which were exhibited at the Meetings of the Committee on the 12th and 26th of April. He is continuing his ichthyological collections, and states the proceed- ing which he adopts in the preservation of the specimens to be as follows. ‘‘ The moment the fish is caught it is thrown intoa tub of rum; and the numbers are gradually augmented until there is no further room and the spirit begins to acquire a slight smell of the fish. They are then taken out; washed in fresh rum; and again put into clean spirit. They are then ticketed and numbered with lead and wire, and are ready to be put up in the preparation bottles as opportunities for their embarkation offer: this is done with fresh spirit also.” The success of this method was shown to be in many instances almost complete, the fishes exhibiting great beauty and brilliancy of colour. In some cases, however, it is less successful, and even the same species varies considerably in its state of preser- vation. Thus of the Julis decussatus, (Sparus decussatus, J.W. Benn.) two specimens almost equal the brilliancy depicted in the ‘ Fishes of Ceylon’ [Plate xiv.], while a third has parted with nearly the whole of its colouring, and retains merely the markings. The iron wire employed in affixing the leaden numbers has generally rusted so as to stain the fishes where it has been in contact with them, and has in some instances been so weakened by corrosion as no longer to retain the lead. Mr. Telfair concludes by referring to the neighbouring island of Madagascar, and to the interest attaching to its natural productions so far as they have been already investigated. He remarks how imperfect this investigation yet is, and gives a historical sketch of the various attempts made by European naturalists during the last — twenty years, but few of which have been attended with even mode- rate Roological Society. 231 rate success. In several instances they have been fatal to the zealous individuals who have devoted themselves to the pursuit, the climate, especially that of the coast, being generally ill suited to Euro- peans. A new attempt is about to be made under the auspices of Mr. Telfair and the Mauritius Natural History Society, from which he anticipates considerable additions to science, the individual se- lected being well adapted for the purpose by long practice in col- lecting and preserving specimens, and by being thoroughly accli- mated to Madagascar, in which he has on several occasions resided for a considerable time. Mr. Owen, having had occasion to examine recently with Mr. Yarrell the body of a Gannet, (Sula Bassana,)which died at the So- ciety’s Garden, read his notes of the examination, They referred chiefly to the situation and connections of the air-cells, and differed in some particulars from the observations recorded by Montagu, who states in the ‘Supplement to the Ornithological Dictionary’ [article Gannet], that “by reason of some valvular contrivance the skin could not be artificially inflated through the lungs;”’ and adds, “it is also clear that there is no direct communication between the sides.” “In the examination our attention was chiefly directed to the air-cells, which in this bird, as inthe Pelican, have a most extensive distribution, We commenced by gentle but continued inflation through the érachea, a pipe having been introduced into the upper larynx : in a short time the integuments of the whole of the lateral and inferior parts of the body rose, and the air-cells seemed com- pletely filled, especially that which is situated in front of the os Jurciforme, Being thus satisfied that they all had a free commu- nication with the chest, we next proceeded to see at what points these communications took place, and in what degree the air-cells communicated with each other. For that purpose the air-cells on the left side of the body were Jaid open, and shortly after those of the opposite side collapsed, indicating the existence of apertures of communication, although the septum which ran along the middle line of the body appeared at first sight imperforate. There was a free communication between the lateral air-cells of the same side of the body from the os furciforme to the side of the pelvis ; but the air-cell in front of the os furciforme remained still tensely inflated. The lateral air-cells had a free communication with the cavity of the chest at the azilla, at which part the air had entered these cells during the inflation. The pectoral muscles and those of the thigh presented a singular appearance, being as it were cleanly dissected, having the air-cells extended above and below them; the axillary vessels and nerves also passing bare and unsupported by any sur- rounding substance through these cavities. We traced the air-cells down the side of the humerus, ulna, and metacarpal bone, into all of which the air entered, and even into the bone corresponding to the first phalanx, which agrees with what Mr. Hunter has deseribed in the Pelican. (Animal (Econ. p. 92.) “ As none of these proceedings had any effect on the air-cell in front of the os furciforme, which still continued distended, it was evident 232 Soological Society. evident that inflation by the humerus could not have filled it except through the medium of the lungs themselves. We next proceeded to detach the integument from this air-cell to see its shape and ex- tent ; this required to be done with great care, as it adhered pretty closely to the skin and roots of the feathers: it was of a globular form, about four inches in diameter, and communicated with the thorax at its anterior aperture below the trachea. « Numerous strips of muscular fibres passed from various parts of the surface of the body, and were firmly attached to the skin; a beautiful fan-shaped muscle was also spread over the external sur- face of the air-cell anterior to the os furciforme. The use of these muscles appeared to be, to produce instantaneous expulsion of the air from these external cells, and by thus increasing the specific gravity of the bird to enable it to descend with the rapidity neces- sary to the capture of a living prey while swimming near the surface of the water. «« With respect to the general anatomy of this bird, it may be observed that we found the two small glands at the termination of the trachea, which are noticed by Montagu, and which exist in ad- dition to the ordinary pair lying above the bronchig, The stomach corresponded exactly with the figure given by Sir Everard Home (Comp. Anat. pl. xlvi.), the pyloric orifice being provided with the bilobed valve which is there represented, though not described in the text ; it evidently opposes a too ready egress of the contents of the stomach.” Mr. Vigors exhibited a collection of African Birds which had been presented to the Society by Henry Ellis, Esq., of Portland Place. They consisted of about one hundred and thirty species, many of them of extreme rarity and value, and a great portion un- known to the cabinets of England. They came immediately from Algoa Bay ; but were supposed to have been collected far in the interior of the country. Mr. Vigors expressed his intention of lay- ing before the Committee at an early Meeting, a descriptive cata- logue of the whole collection, as well as whatever particulars he could collect respecting the locality from which it was brought. He named and characterized in the mean time the following apparent novelties from the Insessorial Birds. Turpus eurrarus. Turd. supern? olivascenti-brunneus, subtis sub- rufescenti-albidus ; strigis tribus genarum, guttis rotundis pectoris abdominisque, tectricumque alarum notis brunnescenti-atris ; tec- tricibus alarum, rectricibusque tribus utrinque lateralibus ad apicem albo notatis. Statura paulo minor quam Twurdi iliact, Linn, PyRRHULA ALBIFRONS. Pyrr. nigra, capite nuchdque ferrugineo nitore subtinctis ; fronte maculdque remigum albis. Longitudo corporis, 73; ale, 4; caude, 3; tarsi, 3; rostri, 3, altitudo 2. Proceus cuttuRALis. Ploc. supra pallid? olivaceo-brunneus ; capite colloque in fronte aurantiacis, corpore subtus aurantiaco- flavo; gulé juguloque nigris, rostro attenuatiore. Longitudo corporis, 64. PLocEus Roological Society. 233 Proceus sPiLonotus. Ploc. capite supra corporeque subtus au- rantiacoflavis ; guld, jugulo, dorsoque summo nigris, hoc flavo maculato ; uropygio fusco-lutescente ; alis caudaque fuscis, Statura pracedentis ; rostro fortiore. PLoceus curysoGasteR. Ploc. capite genis corporeque toto supra saturate castaneo-brunneis; guld flavo et brunneo variegata ; cor- pore subtus aureo-flavo. Statura precedentium ; at rostrum mult6 validius. LAMPROMORPHA* CHALCOPEPLA. Mas, Lamp. supra splendidé viridis, cupreo nitens ; subtits alba, lateribus viridi-cupreo fascia- tis ; strigd in capitis medio, secundd superciliart, alteraque maxil- lari, maculis tectricum alarum, remigum, rectricumque, duabus mediis exceptis, albis. Foem. aut mas jun. ? Lamp. corpore supra metallic viridi ; ca ite, nucha, regioneque interscapulari cupreo splendentibus ; collo in Sronte pectoreque rufescenti ; abdomine albo, lateribus viridi-eneo *fasciatis; caudd ferrugined, viridi-eneo Jasciata ; rectricum trium utringue lateralium pogoniis, omniumque apicibus albo notatis. Statura Cuculi aurati, Gmel. CoryTHAIx PORPHYREOLOPHA. Cor. collo, abdomine medio, pec- tore, regioneque scapulari gramineo-viridibus, his subrufescenti- bus ; fronte strigdque per oculos splendidé viridibus ; capite cris- tato, alis, cauddque splendenti-purpureis ; remigum fascia latd subpurpurascenti-coccineis ; dorso abdomineque mts, tectricibusque Jemorum fusco atris ; rostro pedibusque atris, Statura Cor. Perse, Ml. Bucco nanus. Bucco supra niger, sulphureo striatus ;_strigd su- pereiliari gracili, alteraque per totam longitudinem alarum ex- tendentelatd, aurantiis ; guld crissoque sulphureis, abdomine.fus- cescenti ; fronte coccineo. Longitudo corporis, 44; rostri ad frontem, +) ad rictum 53,. Yunx Pectoratis. Y. supra pallide brunnescenti-griseus, fusco graciliter undulatus ; nuchd scapularibusque nigro notatis, caudd nigro fasciatd ; subtis albidus, collo in Sronte confertim, femorum tectricibus minis confertim, nigro fasciatis, abdomine nigro lie neato ; maculd grandi pectorali ad gulam extendente rufa ; remi- __ gibus fuscis, pogoniis externis Serrugineo fasciatis. Statura Y, Torquille, Linn. June 28, 1831. Rey. W. Kirby in the Chair, A letter from Sir Robert Ker Porter, Corr. Memb. Z. S., dated City of Caraccas, Venezuela, March 25, 1831, was read. It announced his having recently obtained possession of a specimen of the American Lapir, (Tapir Americanus, Gmel.), which it was his * A group including the shining Cuckoos of Africa, India, and New Hol- land, indicated in the Transactions of the Linnean Society, vol. xv. p. 300. Mr. Vigors expressed his belief of having lately seen a name attached to this group by some modern author ; but he could not call to his recollection the work in which it occurred. N.S. Vol. 10. No. 57. Sept. 1831. 2H intention 234 Zoological Society. intention to transmit to the Society at the earliest opportunity. It embraced a full description of the animal ; and entered at consider- able length into an account of its habits. The letter was accompa- nied by two drawings of the Tapir, and by sketches of its proboscis- like upper lip. 4 Mr. Gray exhibited the skins and skulls of two Mammalia brought from China by Mr. Reeves, together with the skull of a third, of which a skin was also in his possession. On these he proposed to found three new genera, the characters of which may be given as follows : HELIcrIs. Dentes primores $: laniarit ++: molares 3%; e quibus 3} ante- riores falsi conici compressi ; carnivori ++, in maxilld superiort 3-lobati, cum processu interno subcentrali lato 2-acuminato ; tu- berculares 34, superiores mediocres transversi, inferiores exigut. Caput elongatum. Pedes breves; plante ad calcaneum jferé nude ; digiti5—5; ungues valide, anteriores longe compress@. Cauda cylindrica mediocris. This genus, which inhabits eastern Asia, has the general appear- ance and colouring of Mydaiis, combined with a dentition resem- bling that of Gulo or Mustela, but differing from both the latter genera in the large internal central lobe of the upper carnivorous tooth. The species exhibited may be characterized in the follow- ing terms: HELIicTIs MoscHaTA. Hel. supra argentata, pilis singulis basi cinereis apice argenteo-albis, so at argenteo a latera corporis et versus apicem caude dominante, capite pedibusque anticis in Jusco-cinerascentem vergentibus ; striga inter, aliisque duabus pone, oculos, macula interauriculari nuchalique, labio superiore, mento, guld, gastreo medio, femoribusque internis, albis. The entire length of the animal is 23+ inches, of which the tail measures 8. It inhabits China, and smells strongly of musk. Mr. Gray added that the Gulo orientalis of Dr. Horsfield’s ‘ Zoolo- gical Researches in Java’ appeared to him to form a second species of the genus, closely resembling the Chinese in its general characters, and in the disposition of its colouring, but differing in its browner colour and in the larger proportion of white upon the head and back. The internal lobe of the upper carnivorous tooth in the Ja- vanese animal is also described as being anterior and very minute. PAGUMA. Dentes primores % equales: laniarii ++: molares % % 3 quorum utringue in maxilla superiori 3 falsi parvi compressi, 1 carni- vorus brevis obtusé $-lobus cum processu interno centrali, 2 tuber- culares subquadrati interné subangustati antice non producti in maxilla inferiore 4 falsi, 1 carnivorus, 1 tubercularts. Pedes postici plantigradi, ad calcaneum usque nudi callosi. Caudatonga attenuata. In the number and disposition of its teeth this genus agrees with Viverra, from which, however, it differs in their conformation. It is much like Ictides in colouring, but has about the face the pale marking Intelligence and Miscellaneous Articles. 235 marking of Paradorurus; the skin has the odour of civet. From the genus Viverra it is distinguished by the shape of its skull, the cerebral cavity being in it much larger, the space between the eyes broader, and the nose much broader and shorter. The species was characterized in the following terms : PacuMa LARvATA, Pag.grisea ; fascié alba frontalitransversa, alteraque longitudinal per frontem ad nasum ductd; caudé apice nigrescentt. Gulo larvatus. Ham. Smith in Griff. Transl. Cuv. Régn. An. ii. p. 281, c. fig. Viverra larvata. Gray, Spic. Zool. p. 9. The third genus described was founded on a glirine quadruped, nearly allied to the Bamboo-Rat (Mus Sumatrensis, Raffl.?), with which Mr, Gray associated it under the following characters. /RHIZOMYS. Dentes primores 3% maximi, elongati, triangulares, acutati: mo- lares 3 3 radicati, subcylindrici, coronis transversim subparal- lelim porcatis ; superiores interne lobati, Caput magnum. Ocult parvi apertt. Auricule nude conspicue. Corpus crassum sub- cylindricum. Pedes breves validi, digitis 5—5. Cauda mediocris, crassa, nuda. In teeth and general appearance this genus is most nearly allied to Spalax, from which it differs in its tail of moderate length, its exposed eyes and ears, and the more complex character of its molar teeth. The species of Rhizomys live moreover upon, and not under, the ground, being found about Bamboo-hedges, on the roots of which they principally subsist. The following were stated to be the distinctive characters of the two species known. Ruizomys Sivensis. Rhiz. pallidé cinerascens unicolor. Hab. in China. D. Reeves. Ruizomys Sumarrensis. Pallidé fuscus, pilis raris albidis in- terspersis ; corporis lateribus pedibusque saturatioribus ; genis pallidioribus, occipite nigrescenti lined longitudinali alba, pec- tore albido. Mus Sumatrensis, Raffles, Linn. Trans. xiii. 258? Temminck, Mus. Leyd. Spalax Javanus, Cuv. Hage Anim., ed, 2., i. 211. Hab. in Sumatra, Raffles? Temminck; Java, Cuvier. The latter species seems to have been first observed by Colonel Farquhar, in whose collection of drawings, preserved in the Museum of the Asiatic Society, a representation of it is found. Of the former we owe the discovery to Mr. Reeves. XXXI. Intelligence and Miscellaneous Articles. PREPARATION OF IODIC ACID. BY ARTHUR CONNELL, A.M. HE methods which have been hitherto followed for the formation of iodic acid, may be reduced, Mr. Connell remarks, to three : Jirst, the action of alkaline solutions, giving rise to the formation of a 2 > a hydrio- 236 Intelligence and Miscellaneous Articles. a hydriodate and an iodate, from the latter of which the iodic acid may be separated by the original method of M. Gay-Lussac, and more perfectly by the recent method of M. Serullas (Ann. de Chim. et de Phys. xliii. pp. 127 and 217); secondly, the action of euchlo- rine, as suggested by Sir H. Davy; and, thirdly, the action of water on the perchloride of iodine, and subsequent separation of iodic acid by means of alcohol, as also proposed by M. Serullas (see Phil. Mag. and Annals, N.S, vol. ix, p- 149): to these Mr, Connell pro- poses to add the agency of nitrie acid, which he thinks will be found to equal in facility of execution any of the preceding processes. The vessel employed was a rather large and tall flask, into which fifty grains of iodine and an ounce of fuming nitric acid were put; the acid was made to boil, and as soon as any iodine sublimed and condensed on the sides of the vessel, it was washed back again into the liquid by agitation. After the process had been continued some time, a precipitation of white crystalline grains was observed to take place; and the operation of boiling and washing back the sublimed iodine was continued until the free iodine had to a great extent disappeared. The whole was then decanted into a shallow basin and evaporated to dryness. Any free iodine which had re- mained was soon dissipated by the heat. The residue of the eva- poration consisted of whitish crystalline grains, which were iodic acid, retaining a little nitric acid, from which they appeared to be freed by one or two solutions in water, and re-evaporations, when they lost most of their crystalline appearance, and became a whitish deliquescent mass, occasionally with a light purplish tint, from a tendency to decomposition by the heat of evaporation. Where no particular precautions were taken to prevent loss in the state of vapour, and where the process was not continued until the entire disappearance of iodine, the quantity of acid obtained approached that of the iodine employed; a larger proportion of iodine might probably be used, with the same quantity of acid. — Jameson’s Journal, June 1831, p. 72. . NEW SCIENTIFIC BOOKS. Just published. The Twenty-second Number of Professor Leybourn’s Mathema- tical Repository is published. It contains solutions to twenty questions in different parts.of pure and mixed mathematics (and as many new ones for future solution) by various contributors. The separate papers are: 1. Two indeterminate Problems, by James Cunliffe, Esq. late of the Roy. Mil. Coll. 2. Analysis and Construction of a Geometrical Problem, by C. F. Barnwell, Esq., A.M, F.R.S. F.S.A. 3. A History of the Investigations respecting the Properties of Rule Surfaces, or such as can be generated by the motion of a right line subjected to certain conditions, by T. 8. Davies, Esq. F.R.S.E, F.R.A.S. 4. An Inquiry into the Author of the Second and Third Properties of the Stereographic Projection of the Sphere, completing the Inquiries of Delambre on that Sub- ject in his History of Astronomy, by the same Gentleman. 5. Hore Arithmetice, Intelligence and Miscellaneous Articles. 237 Arithmetice (No. 8.); or Historic Memoranda respecting circum- stances connected with his new method of Continuous Approxi- mation to the Roots of Numerical Equations, by W. G. Horner, Esq. 6. Analytical Investigation of the Curious Property of Lines of the second order which formed the Prize Question of this num- ber (geometrical demonstrations of which had been given in their proper place by Messrs. Davies and Woolhouse), by T.S. Davies, Esq. F.R.S.E. &c. 7. Researches in the Geometry of Three Di- mensions (incomplete), by the same Gentleman. 8. Pascal’s first work, being on Conics, together with an account of other papers of his on the same subject, by Leibnitz. 9. Solutions of the Sixty Problems in the Rev. John Lawson’s Geometrical Analysis of the Ancients, by the Rev. Charles Wildhore. The Number also contains lists of the mathematical papers pub- lished in the Transactions of different learned Societies; and of the Questions proposed in the Cambridge Senate House on examination for degree of A.B, and for Smith’s prizes. MR. SAULL’S GEOLOGICAL MUSEUM. W. D. Saull, F.G.S. &c. has recently become the possessor of the extensive Geological Museum of the late Mr. Sowerby, of Mead Place, Lambeth, the whole of which is now stratigraphically arranged, with the addition of Mr. Sauil’s previous collection of fossils, and will be open for the inspection of scientific gentlemen, and _ friends, every Thursday morning, at his residence No. 15, Aldersgate-street, City. LUNAR OCCULTATIONS FOR SEPTEMBER. Occultations of Planets and fixed Stars by the Moon, in September 1831. Computed for Greenwich, by THomas HENDERSON, Esq. ; and circulated by the Astronomical Society. Immersions. Emersions. Cat. Angle from Sidereal | Mean .; |Sidereal| Mean | ~ time. solartime.| 5 ¢ time. |solartime.) © (2) D Az Stars’ 1831.| Names, Magnitude. Ast. Soc. No reel ae aT iy cena i) Tia 5 AD i v7 h Sept.11| y Libre... | 4-5 |1764| 20 19| 58 Aquarii| 6 |2690\ 2 20) x% Aquarii | 5°6 |2776| 22 22) 33 Ceti..... 6 125) 3 30} o* Cancri...| 6 |1094| 4 7 ** 7| 14 34 | 141)174!) 3 22) 15 29 | 263 3) 10 7 |122) 110/23 17} 11 21 | 288 5 tf 15 011380] 152| 4 10] 16 5 | 278 15 30 | 69} 29) 5 11) 16 34 | 275 METEORO- 238 Meteorological Observations for July 1831. METEOROLOGICAL OBSERVATIONS FOR JULY 1831. Gosport :—Numerical Results for the Month. Barom. Max. 30-348. July 6. Wind N.E.—Min. 29-606. July 13. WindS.E. Range of the mercury 0-742. Mean barometrical pressure for the Month .......s.ceceseseseeseseeee 29999 Spaces described by the rising and falling of the mercury............ 3190 Greatest variation in 24 hours 0-259.—Number of changes 15, Therm. Max. 79°. July 9. Wind W.—Min. 52°. July 3. Wind W. Range 27°.—Mean temp. of exter. air 64°°68. For 31 days with © in 63°40 Max. var. in 24 hours 22°-00.— Mean temp. of spring-water at 8 A.M. 51-81 De Luc’s Whalebone Hygrometer. Greatest humidity of the atmosphere, in the evening of the 23rd.... 100° Greatest dryness of the atmosphere, in the afternoon of the 9th ... 43-0 Range Gh MG IHIeR a ifenecarsnansnsnecusssipeacnQurpnsebaagetnecnscasnesdenccue 57-0 Mean at 2 P.M. 55°-2,—Mean at 8 A.M. 61°4.— Mean at 8 P.M. 67:5 of three observations each day at 8, 2, and 8 o’clock......... 61:4 Evaporation for the month 4-55 inches. Rain in the pluviameter near the ground 3-465 inch. Prevailing winds, West. Summary of the Weather. A clear sky, 43; fine, with various modifications of clouds, 153; an over- cast sky without rain, 73; rain, 33.—Total 31 days, Clouds. Cirrus. Cirrocumulus. Cirrostratus. Stratus. Cumulus. Cumulostr. Nimbus. 23 16 Q7 3 28 23 16 Scale of the prevailing Winds. N. N.E. Be SE Sst SW We Nee Days. 2 4 TOG li 6 8 Qh 31 General Observations.—This month has been fine, with the exception of four or five days, when much rain fell here. In the evening of the 5th, Venus was in conjunction with x Leonis, and they formed a small isosceles triangle with Saturn. At midnight of the 8th several flashes of lightning ascended from the horizon in the north-east quarter. The 9th was the hottest day in the shade, and there were a few flashes of lightning in the night in the south-east horizon. Sheet lightning also occurred the fol- lowing evening. Much rain fell on the 11th, 12th, and 14th, which was accompanied with lightning and thunder. Distant thunder and lightning also occurred in the afternoons of the 16th and 28th. In the afternoon of the latter day the edge of a thunder-storm passed this place, and proceeded with some violence in its electrical effects in the direction of Berkshire. Not only in Hampshire, but in most other counties, thunder-storms have often occurred through the month, so that the period may be said to have been a war of the elements. On the 19th, 20th, 21st, and 22nd, a hard gale blew from the South- west, and on the following day it blew equally hard from the opposite point of the compass, with a copious rain, and a considerable decrease in the temperature of the air. The rain and wind lodged some of the corn in this neighbourhood. From the 25th to the end of the month the weather was dry and warm, and on several days a thermometer in the sun’s rays rose to 120 degrees, which had the effect of ripening the wheat, and harvest commenced here at the close with every prospect of good average crops. Soon after ten o’clock in the night of the 30th, an aurora borealis ap- peared, whose upper arch, though not well defined, was about 16 i 1B ae Meteorological Observations yor July 1831. 239 high in the magnetic north ; but the lower arch was low, and could not be traced in consequence of a dark vaporous herizontal cloud before it. At a quarter past ten several bright yellow columns, 20° in altitude, rese from the aurora under Polaris, when one brilliant meteor descended be- tween that star and Dubhe in Ursa Major. Coruscations continued to rise between the true and magnetic north till a quarter to eleven, when the moon was several degrees above the horizon, and the aurora disappearing. It was lately mentioned at Portsmouth by a public lecturer on aérology, that Jupiter’s attraction of the atmosphere of the earth is greater than has been generally supposed ; and that when the moon is near him, he has so powerful an attraction over our atmosphere, as to disturb its elasticity and draw it up considerably out of its spheroidal form, by which means electrical action and a condensation are produced, so as to cause heavy rain ; and that the effect is greater when Jupiter crosses the northern part of the Pacific Ocean in his north declination, and the South Sea and Atlantic Ocean in his south declination, in consequence of the abundance of va- pours arising from them. This opinion (conceived to be new by the lecturer), although not new to men of scientific pursuits, certainly deserves the strictest investigation in a meteorological point of view, it having been verified in almost all the lunations this year, even in this latitude, when the moon has been near Jupiter; and as this planet is 1312 times larger than the earth, it is not surprising if we admit the principle of attraction of the heavenly bodies, that he should conjointly with the moon exert so great an influence over our atmosphere. ‘The mean temperature of the external air this month is nearly half a degree higher than the mean of July for many years past. The atmospheric and meteoric phenomena that have come within our observations this month, are, two solar halos; one meteor; one aurora borealis ; lightning on eight days and thunder on four, and five gales of wind, namely, one from the North-east, three from the South-west, and one from the West. REMARKS. London.—July 1,2. Fine. 8. Slight rain: fine. 4:Very fine. 5. Fine: slight rain at night. 6—9. Very hot. . 10. Thunder at noon, with slight rain: very heavy storm to the eastward, 11. Hout. 12. Heavy showers. 13. Rain in the morning: fine. 14. Cloudy: rain at night. 15. Rain, with some thunder in the afternoon. 16. Cloudy, with thunder showers. 17—19. Fine. 20. Cloudy and windy, with slight rain. 21. Fine. 22. Fine, with slight showers. 23. Fine: rain atnight. 24—27. Very fine and warm. 28. Sultry: thunder, with rain towards night. 29, Very hot: thunder in the afternoon. 30, 31. Very fine. Penzance.—July 1.Fair, 2. Fair: rain. 3. Fair. 4. Misty: fair. 5. Rain: fair. 6.Clear. 7.Fair: clear. 8.Clear. 9,10. Fair. 11. Fair: rain. 12. Fair: thunder-shower. 13. Showers. 14. Fair: showers. 15. Fair: rain. 16. Fair: shower. 17. Fair. 18.Showers: fair; 19. Misty: rain. 20. Rain: showers. 21,22.Showers. 23. Heavy rain. 24—27. Clear. 28. Fair. 29—31. Clear. Boston. — July 1, 2. Fine. 3. Cloudy. 4, Fine: Therm. 74° 3 p.m. 5.Cloudy: raina.m. 6.Cloudy. 7,8.Fine. 9. Fine: Therm, 78°5, 1 p.m. 10. Cloudy: rain p.m. 11. Cloudy. 12. Fine. 13. Cloudy: rain a.m. ande.m. 14. Fine: rain, with heavy thunder-storm 1 p.m. 15,16. Rain. 17—19. Fine. 20.Cloudy. 21. Cloudy: rain early a.m. 22. Stermy. 23—25.Fine. 26.Cloudy. 27.Fine: Therm. 74° 4p.M, 28. Cloudy. 29. Fine: Therm. 80° 1 x.m. 30. Cloudy: rain early a.m. $1. Fine. Meteoro- GEG |SOV-E SOE-% 08-2 |SS-T_ a ee ee ee 98 | 8£-62 |909-62 SP£-08 09-62 | $8-0€ |Z€S-6 |P9C-0€ CLA ES SECTS ME TOS zg | 06-62 |ZP0.0€ |£g0-0€ | 86-6Z | 00-0€ |610.0€ |L60.08 | Tf Bie Heel el Osc| < (VABA ean ee, g9| 19 | SL | LS €g | 0S.6% |880-0F |SST-0F | 00-0£ | 00.0€ IZI1-0€ |SST-0€ |O£ vee [eee [eee | eee | eee lunqeo| cas | ca | ms] 99] 29 | SL | 6S oL | FS | Sg | £7.62 |801-0F |9ZI-0€ | 00.0€ | 00-0€ £90-08 |E1-0€ |6% s+ logo. °° | Po. | tt [MN [tMN | °S [AN ¢.99| 09 | LL | 09 | tL | 9S | $8 | 09-62 Q0T-0€ |OVI-0€ | OT-O€ | SL-OF |180-0€ |861-0£ |8% ccs Iuewaree| eee | sen QGa tee fenaw | 'ak "N° GO) 69: EL ec | 12 | SS | Sg | 09.62 |10Z-08 |10-08 | ST-0€ 81-0€ |ZTL-0€ [061-08 |Le PT eee cae | e-talgecan teem | -an-| si. | Gol-OG kGu. (ays 129.1 bo41 Os 09.62 SZI-0€ |O61-0€ | OT-0£ | C1-0€ |PFI-€ L61-0€ |9% wee fcc [ese | ooo | cee | om | caw | -anx| ‘= | PO] 9S | TL] FS | 69 | GP | EL | 25.60 '6Z0:0€ |SL0-0€ | $6.6 | 00-08 |SV0-0€ |6Z1-08 |S% vee [oe [eee | ees | og. | a | an] -an| ‘2 | Po] 8S | 89 | PS | $9 6P | OL | €£-60 681-62 |€26-62 OL-6% | 06.6% |SZ8-6% 956.66 |Fo Oo see 1909. \G0T/VI- | °°? | AN | cae | 8 SS ¢9| 99 | Lo | PS | €9 | PS | 89 | 22.6% £99.62 |SP8-6a | 09:66 | SL-6% |Z£S-6G lozg.6z [&% vee foes Jere log. | ct | ‘m | oms| tm [4s] Zo] PS | 89 | €S | So LV | o£ | 91-62 \LP8-6z |SS8-6z | 08-62 | 08-6z |Z08-6c L19-6z |03 Gu gO ase oo] SP [we oak | S| “ANB BD cg | g9 | SG | Sg | 0S | EL | $0.62 |189-62 |EPL-6c 0-62 | 08-62 |9£9-62 | Il vs lQz9. [SST |€0- | *** | “M | taas | *aas | “MS ¢.19| 19 | L9 | 99 | 99 | 09 | OL | €1-6 08-62 |098:62 | 08-62 | 08-6 |0SL-6% wee [eee loot. | cet | ott | tat | tas | cae | “ASS 16-29 | 69 1L | €$ | 99 | LS | €L | 92.6% |0£6-62z |8F6-66 | 06-62 | 06-60 €L8-6z Belch = lees ol Geetll ve |oean |eaag |oean TEASE PO eQG-|-OLFI_ VS: 1590) |REGeISEL L£.6@ |S$S6-6z |8S0-0€ | 00-0€ | 00-08 €16-6z zo. joer |ott | ttt | OB. | aN [taunt | can | “AN G.19| LS | al | VS | 99 | €S | 6L | SE-6z 086-62 |L¥0-0€ | 00-0€ | 00-08 626-6 G0. (CPO.1080-5) Lt) eo arlene ee ak -m | 6¢| 99 | o£ | PS | 99 | FS | EL | 2.6% 109-62 |€98-62 | $8-6% | 06-6% \S7L-6% € 0S. {o€o. O01. |S. | 7 |°AAN | tas | aun | “ANS | 09 6S | o£ | cS | Fo | PS | SL | a1-6z |09L-6z |86L-6% 01:62 | OL-6% |SEL-62 ©) (00g. 1000-1 00m S6.8 | AN. | casas ‘ms | gg! LG | g9 | €S | So | €S | PL | 02.6% \LOL-6 |1€L-6 | 09-6 | OL-6% |1ZL-6% “ati [OER Uiles| 90-4) 2°3 | = | Tas | "as | A ¢.Gg| 9$ | 89 | PS | Fo | 1S | PL | Lo.6% 909-62 |189:6z | 09-62 | 09.6% |F89-6z s+ 976. joow- |otet| “| “% | ‘as | mx ["#S| Lo) Og | 14 | Og £9 | FS | OL | £0.62 |1F9-6z |999-62 | 09-62 | 09-62 \9F9-62 al OZIOLP. |OZI- | 10. | Of: |*MN] “as | sm | “T | 19 9g | €Z | 9$ | $9 | 89 | 6L | $2.6z \SLL-6z Z06:6z| $8:6% | 06-62 |602-6z 1 vee [eee [eee 119, | vee [ure] tm [emu] “| Co} 6S | aL | 99 | 99 0S | €Z | of.6% $36-6z |8£0-0£ | 00-0€ | $0.08 |600-0€ Ol vee [ose [eve [eee | eee [easy foun | saan | tas 1.69] 09 | GZ | LS | 99 | LS | 98 | Z9-68 SIT-O€ /900-08 o1-0€ | ST.0€ for-0€ |Ig1-0€ 6 @ Oe | ea se | og, [tan] cn | cas | “Ft 1G-€9) LG eZ | 9S | 14 | 67 | 6L | $9.62 \€61-08 ZPt-0F | ST-O€ | $1-0€ |O6T-0£ |OVS-0F 8 vee [ove [ere [eee log. | 2 | a | cas | “| 29] 2G] ol | eS} tL | os gL | 08-62 OPZ-0€ |£60-0F | 0Z-0£ | 03-0F |99G-08 1£€-0€ |Z vse Jove [ere | eee | og. feupeo| cas] ‘an “2 | 99/ 19 | oL | PS oL | £9 | £8 | PL-6% ZEE-0€ |SPE-0£ | 2B-0€ Gz.0€ |LEE.0€ |F9E-0€ 9 G7 O1OGOM |OL0+0| CO || = + 9| IBS| ats:| Ass ‘m |G.z9| 69 | zl | 66 | F9 | ES | 08 | $S-6% REz-0€ |LSz-08 | 80-0€ | SI-O€ |PaT-0€ 6Gz-0€ |S C010 040" ee [vee | eee [emn| em [ems | “4 | 91 6S | ol | ZS} OL | 1S | 08 | 09.6% 8Es-0F 16z-0€ | 90-0€ | 90-0€ |1Z1-0€ |P0s-0€ |P vee fore [eee 19.0] SP-o] mea] *m [mn] “4 | PQ] oo | 12 | PS | So 1G | gL | 11-62 0F0-0€ 6z1-0€ | 00-0€ | O1-0€ |0T0-0€ |0g0-08 |€ Sst" |GGG GIOLEO meee! ee ja | ‘mn |G.96] 69 | 69 | 0S | F9 | SS | BL | LP.6c fS0-0€ £60-0€ | 00-0€ | Z0-0€ |F66-62 |Sz0-08 | exe Ce ieee Sie Gl | tS “MN | 09] €9 | IZ | 7S £9 | LP | EL | 19-6% '880-0€ |EZ1-08 OT-0€ | OL-0€ |SS0-0€ [460-08 |t 41ImL SPOTS TET OLE Le | cp scam ene ue er te ne par (allt ae a Fe ee red la s R wale a *yaodsoy |‘a0uvzueg} *Uopuo'T |WOWsog *y40dsoy *aouvzZuag *uopuo'yT ‘yoy | a | jo shugy uley dead “PULA *19]9MLOULIIY T, *1a}aWOIV *u0ps0g JD TIFIA “Mp pun Quodsoy 7 AINUNG ““T ‘souvzuag yw AaaIy “py fq fuopuoT unau ‘younsiyg yo hyaroog pounynoyLoyy ayy fo uapiny ayy 70 NOSdWOHL, “WT fig apo suorna.tasgQ 729150]0409}2 THE PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY. —=>——_ [NEW SERIES.] OCTOBER (1831. XXXII. Researches on some of the Revolutions which have taken place on the Surface of the Globe; presenting various Examples of the Coincidence between the Elevation of Beds in certain Systems of Mountains, and the sudden Changes which have produced the Lines of Demarcation observable in certain Stages of the Sedimentary Deposits. By L. Exe pe Brav- MONT*. Two great views, one a succession of violent revolutions, the other the elevation of mountain-chains by forces act- ing from beneath, having been successively introduced into geology, it was natural to inquire if they were independent of each other; if mountain-chains could be raised without producing real revolutions on the surface of the globe; if the frightful convulsions which must have accompanied the up- burst of masses so great and of an aspect so contorted as those of high mountains, were not the same with those revo- lutions on the surface of the globe which are proved to have taken place by the mineralogical and zoological lines of de- marcation observable in the sedimentary deposits. The principal object of the researches, of which the follow- ing is a brief sketch, is to show, term for term, the connection of these two series of facts. It will be necessary to premise a few words respecting the principles on which these researches have been conducted. The expression sedimentary deposits (terrains de sediment) in which we, in some measure, sum up our knowledge of those masses so widely spread over the surface of our planet, so * Extract forwarded to Mr. De la Beche in May 1831, and communi- cated by the latter to the Editors. N.S. Vol. 10. No. 58. Oct, 1831. 9 | naturally D2 Elie de Beaumont’s Researches on some of naturally carries with it the idea of horzzontality, that it is never without surprise we first hear of sedimentary beds observed in a vertical or nearly vertical position. As early as 1667, Stenon maintained that all inclined sedi- mentary beds were upraised; and since the observations of De Saussure on the Valorsine conglomerates, geologists have generally agreed in considering those sedimentary beds which are frequently observed in mountainous countries either in- clined at considerable angles, placed vertically, or even thrown over, as not having been formed in that position, but as having been so circumstanced, in consequence of phenomena which have taken place at a greater or less time after their original deposition. There are few countries where these phzenomena have been produced at so late a period, as to affect all the sedimentary deposits there existing, even abstracting the alluvion of modern rivers, which in all cases has not yet been disturbed by any phznomena of this nature. We observe along nearly all mountain chains, when we at- tentively examine them, that the most recent rocks extend horizontally up to the foot of such chains, as we should expect would be the case if they were deposited in seas or lakes of which these mountains have partly formed the shores; whilst the other sedimentary beds tilted up, and more or less con- torted on the flanks of the mountains, rise in certain points even to their highest crests. Thus in each chain, or rather in each system of chains, the series of the sedimentary rocks is divided into two distinct classes, and the point of separation of these two classes, variable from one system to another, is one of the circumstances which best characterizes each parti- cular system. At the same time that the position of the ancient and in- clined beds furnishes the best proof of the elevation of the mountains of which they constitute a part, the geological age of these beds affords the best means of determining the rela- tive age of the mountains themselves; for it is evident, the first appearance of the chain itself is necessarily intermediate between the period when the beds, now upraised, were depo- sited, and that when the strata were produced horizontally at its feet. There is nothing so essential to remark, as the constant clear line of separation between these two series of beds in each chain. This kind of observation is sanctioned by long experience. Geologists have, in fact, been long accustomed to employ the absence of parallelism in the stratification of two systems of beds, the one supporting the other, as ANDROS j the the Revolutions which have taken place on the Globe. 243 the clearest line of demarcation that can be found between two systems of consecutive sedimentary deposits. This idea, which has been developed in the lessons: of the most distin- guished professors, has, it may be said, become common. It was indeed on a fact of this nature, generalized certainly be- yond measure, that Werner founded his principal division in the series of rocks. Now it follows from this difference, always clear and without passage, between the upheaved beds and those which are horizontal, that the elevation of the beds has not been effected in a continuous and progressive manner, but that it has been produced in a space of time comprised between the periods of deposition of the two consecutive rocks, and during which no regular series of beds was produced ;— in a word, that it was sudden, and of short duration. It has been in vain attempted to explain the geological facts observable in high mountain-chains, by the action of the slow and continuous causes now in force on the surface of the globe. No satisfactory result has been obtained by these means. In fact, everything shows that the instantaneous elevation of the beds of a whole mountain-chain is an event of a different order from those which we daily witness. It is evident that such a convulsion would interrupt the slow and progressive forma- tion of the sedimentary deposits, and that some anomalous circumstance would be nearly universally observable in that point of the series of rocks which should correspond with the moment when an elevation of beds took place. It is well known that those geologists who have most carefully exa- mined the sedimentary deposits, and those naturalists who have investigated the remains of animals and vegetables which they contain, have generally remarked that between different terms of the series of these rocks there are sudden variations, not only in the position and local character of the beds, but also in the fossil animals and vegetables entombed in them. From observations which did not comprise a sufficiently ex- tensive area, some of these variations (to lessen the value of which too many attempts have perhaps been subsequently made) were at first supposed more general than they really are. When two formations appear to pass insensibly into each other, there is never more than a small depth of beds of which the classification may remain uncertain; and when certain fossils are common to two successive formations, they generally constitute a fraction, often even inconsiderable, of the total number of species found in each of the two forma- tions. ‘This is more particularly seen in the comparison in- stituted by M. Deshayes (in a work impatiently expected by geologists) between the catalogues of the species of shells 212 discovered 244 Elie de Beaumont’s Researches on some of discovered in the three groups, which he distinguishes in the beds above the chalk, and the catalogue of species now ex- isting. It is sufficient, that in the series of superimposed beds there are points more remarkable than ,others, on account of the changes they exhibit, both in the deposits and in the in- habitants of the same country, to be struck with the accordance of the two orders of considerations above noticed. Among those observations which render it impossible to consider the dislocation of beds which characterizes a moun- tainous country as the result of local phenomena, which may have been repeated in an irregular and successive manner, we may place in the first rank the constancy of the direction in which sedimentary beds are tilted up even for immense distances. Practice has taught miners from time immemorial the prin- ciple of constancy in directions, and it is one of those circum- stances which they most usefully employ in their researches. The observation of constancy in the direction of beds in the coal-measures, has served to discover a bed of coal at a di- stance, though invisible on the surface. It was by combining the observations made in numerous metallic mines, that Wer- ner arrived at the conclusion, that, in the same district, all the veins of the same nature were due to cracks parallel to each other, formed at the same time, and subsequently filled at the same period. The remarkable phenomenon of con- stancy of direction has been gradually shown to be more im- portant, by the labours of those geologists who since De Saussure and Pallas have attentively examined mountain chains. It has been admitted by degrees, that the circum- stance which best characterizes mountain-chains, when com- pared with each other, is the direction which the elevation of the beds has impressed upon them,—a direction naturally observable in the crests composed of such beds. For more than thirty years M. Humboldt has pointed out the equally remarkable accordances and discrepancies observable in the direction of mountain-chains, whether close to, or remote from, each other. M. von Buch has also shown that the mountains of Germany are divisible into at least four systems, clearly distinguishable from each other by their directions. So clear a mode of distinction even led him to conceive that the various mountain systems were produced by phzenomena independent of each other; and it is at the same time very probable, that not only, as is proved by observation, all beds upheaved at the same time have been so raised in the same direction, but also that this constancy in the direction of the upraised beds in a certain assemblage of mountains, is the result of this ia ts) the Rewolutions which have taken place on the Globe. 245 of beds having been thrown up at the same time by a single effort of nature: whence it would follow that the number of the epochs of elevation would not be unlimited, but that it would at least be equal to that of the directions of those chains which are clearly distinct,-—a number not incompatible with that of the solutions of continuity observable in the sedimen- tary deposits. it became necessary, in order to carry the subject beyond these vague and general views, that a comparison should be instituted between the number of those lines of demarcation observable in the sedimentary deposits, and the same number of mountain systems. It has been attempted to accomplish this by combining the two great principles above noticed ; namely, that the highly inclmed sedimentary beds are up- heaved strata, and that in each mountainous district all the beds upheaved at the same moment have been so raised in the same general direction. The examination of the surface of Europe has in this man- ner already led to the determination, both with respect to age and direction, of the twelve systems of mountains to be suc- cessively noticed in the sequel, as also their relation to twelve solutions of continuity observed in the series of sedimentary deposits. I. System of Westmoreland and of the Hundsruck.—:The cor- respondence of this nature which may be referred to the most ancient geological epoch has been made known by the re- searches of Professor Sedgwick, recently communicated to the Geological Society of London. ‘The mean line of bearing of the different systems of slate rocks in the lake mountains of Westmoreland, is shown by this author to be nearly N.E. by E., and S.W. by W. This causes them to abut successively against the carboniferous zone; from which it follows that they must also be unconformable to it. Professor Sedgwick strengthens this inference by reference to detailed sections : and from the whole of the evidence he concludes, that the central lake mountains were placed in their present position, not by along continued, but by a sudden movement of eleva- tion, before or during the period of the old red sandstone*. Professor Sedgwick has also shown that if lines be drawn in the principal bearing of the following chains,—viz. the southern chain of Scotland, from St. Abbs Head to the Mull of Galloway; the grauwacké chain of the Isle of Man; the slate ranges of the isle of Anglesea; the principal grauwacké * From other circumstances to be noticed in the sequel, it appears very probable that this movement of elevation was anterior to the deposition of the most recent strata of the transition series. chains 246 Elie de Beaumont’s Researches on some of chains of Wales, and the Cornish chain,—they will be nearly parallel to each other and to the line of bearing of the lake mountains. The elevation of these chains, which produce marked effects on the physical character of Great Britain, is referred by Professor Sedgwick to the same period; and the parallelism is not considered accidental, but as offering a con- firmation of the general principle,—that mountain-chains, all elevated at the same period of time, present a general paral- lelism in the bearing of their component strata. The surface of continental Europe presents many moun~ tainous countries, in which the predominant direction of the most ancient and disturbed beds is, as has been remarked for more than thirty years by M. Humboldt, but slightly re- moved from a N.E. and S.W. line. Such is, for example, the direction of the grauwacké and slate beds in the mountains of the Eiffel, the Hundsruck, and of Nassau, at the feet of which were probably deposited the coal-measures of Belgium and Saarbruck. Such is also the direction of the slate, grauwacké, and transition limestone beds of the northern and central parts of the Vosges, on the edges of which there are several small coal basins. The parallelism of this direction to that observed by Pro- fessor Sedgwick in England, added to the fact, thatin the Vosges this direction of the slate and grauwacké strata is not carried into the coal-measures, leads us naturally to suppose that the inclined position of these parallel beds of England and the Continent is due to the same catastrophe, the most ancient of any of which traces can at present be clearly recognised. Further researches may perhaps show the relation that may exist between the different parts of the Westmoreland slate rocks, and more effaced and older elevations of strata than this now under consideration. II. System of the Ballons (Vosges) and of the Hills of the Bocage (Calvados).—The observations noticed in the preceding article, only prove that the system of Westmoreland and the Hunds- ruck have been elevated before the deposition of the carboni- ferous series; but it would appear that it had been elevated even before the deposit of the more recent transition rocks. In fact, among those beds which we are in the habit of com- prising in the general denomination of transition rocks, there is a widely extended class which has not been affected by the N.E. and S.W. elevation of the ancient slates, and which may have been deposited on these beds, previously upheaved. Such are the marly and arenaceous limestones with Ortho- ceratites, Trilobites, Hysterolites, &c. which occur in Podolia, in the environs of St. Petersburg, in Sweden, and in Norv: where the Revolutions which have taken place on the Globe. 247 where they are in general but slightly removed from their original horizontal position. Such are also the transition rocks, so rich in organic remains, of Dudley and Gloucestershire, which appear to have been deposited at the foot of the pre- viously elevated mountains of Wales, and which are them- selves only affected by dislocations of a more recent date. Such would also appear to be a part of the transition beds of Southern Ireland, known by the recent researches of Mr. Weaver. This distinguished geologist remarks that some parts of the system resemble, both in mineralogical and zoo- logical characters, the rocks of Tortworth in Gloucestershire. The principal rock masses in the South of Ireland are com- posed of grauwacké, quartz rock, and limestone; they con- tain crinoidal remains, Trilobites, Orthoceratites, Ellipsolites, Ammonites, Euomphalites, Turbinites, Neritites, Melanites, and several species of Terebratula, Spirifer, Producta, and other bivalves, Hysterolites, and many genera of Polyparia. The anthracite and accompanying pyritiferous strata are charged with the remains or impressions of plants, belonging chiefly to the genera Equisetum and Calamites, with traces of Fu- coides. The transition rocks of the Bocage (Calvados) and the in- terior of Britanny bear a great resemblance to those described by Mr. Weaver in the South of Ireland. They are like them composed of numerous beds of slate, grauwacké, quartz rock, and limestone, containing fossils of the same class, and pre- senting mines of anthracite. Finally, I am induced to refer to the same epoch the slate and grauwacké rocks with anthracite (worked for profitable purposes, and which contain vegetable impressions differing but little from those discovered in the coal-measures), which form the S.E. angle of the Vosges, and which appear to rest against the granitic masses of the environs of Gerarmer, Re- miremont, and Tillot; masses which probably were themselves raised at the formation of the old N.E. and S.W. lines of elevated strata. Independently of the geological relations which are apparent between the different parts of the vast deposit of transition rocks above noticed, they have also in common remained unaffected by the ancient N.E. and S.W. system. When these beds are not horizontal, they are dislocated in directions the most marked of which, probably produced immediately after their deposit, is comprised between an FE. and W. line and one E. 15° S. and W. 15° N. Thus the masses of granite and porphyry which, in the S.E. part of 248 Elie de Beaumont’s Researches on some of of the Vosges, constitute the summits of the Ballon d’ Alsace and the Ballon de Comté, range from E. 10° or 15° S. to W. 10° or 15° N., and have thrown up the anthracitic rocks in this direction. ‘The coal-measures of Ronchamps are deposited at the foot of these mountains on the edges of the upheaved beds. The Ballon d’ Alsace rises 2586 English feet above the town of Giromagny, built on a level with the coal-measures ; and the Ballon de Gebweiler, situated more to the N.E., rises 3067 English feet above the same point. Among those in- equalities on the surface of the globe, the date of which we can with probability refer to so remote an epoch, we cannot cite any more considerable. The transition beds of Britanny and of the Bocage of Nor- mandy, on which the coal-measures of Littry and Plessis are deposited, run in a direction comprised within the above- mentioned limits, as is also the case with the transition beds of Ireland, so ably described by Mr. Weaver. The South of Ireland is a hilly and diversified region, composed of ridges having generally an east and west direction, and attaining their greatest elevation in the mountains of Kerry, where Gur- rane ‘I'val, one of Magillycuddy’s Reeks, near Killarney, rises 3410 feet above the sea. The transition rocks of the same region have a general direction from east to west, and dip to the north and south with vertical beds in the axes of the ridges. The strata, as they diminish in inclination, on each side form a succession of troughs, the beds dipping rapidly to the north or south, and bending to horizontality between the ridges. These rocks decline gradually towards the north, and finally pass beneath the unconformable deposits of the old red sand- stone and carboniferous limestone of the midland counties; a discordance rendered particularly striking by the horizontal position of the carboniferous limestone of some districts. In Devonshire and Somersetshire the grauwacké and slates, sometimes containing small seams of carbonaceous matter, also present a nearly east and west direction, and are seen clearly to have been upheaved previous to the deposition of the Exeter red conglomerate or todte liegende, because the latter covers the edges of the former, as may be seen in many situations. The grauwacké chain of Magdeburg has also a direction comprised within the above-noticed limits; and according to the observations of Professor Sedgwick and Mr. Murchison, it contains the abundant impressions of true coal plants. This same direction is again observed in the older rocks of the Hartz, where we are certain that the dislocations were in part effected the Revolutions which have taken place on the Globe. 249 effected prior to the deposition of the secondary beds which extend at the foot of the mountains; and particularly before the formation of the coal-measures of Ilefeld. This system, joined to that previously noticed, and perhaps also to others which have not yet been studied, has produced an undulated surface and a dislocated structure in the ancient land (ur und uebergangsgebirge), in the inequalities of which the first beds of that mass of rocks was deposited which Werner named fletz gebirge, and the English and French geologists secondary deposits, deposits of which the carboni- ferous series (old red sandstone, mountain limestone, and coal- measures) constitutes the lowest part. III. System of the North of England.—From the latitude of Derby to the frontiers of Scotland, the surface of England is divided by a mountainous axis, which, taken as a whole, runs nearly from south to north, stretching a little towards the N.N.W. In that chain which, being wholly formed of beds of the carboniferous series, is called the great carboniferous chain of the North of England, the forces of elevation appear on the whole to have acted (though not without considerable deviations) on a line bearing nearly north and south (inclining but a few degrees to the N.N.W. and S.S.E.). Hence great faults have originated, by one of which its western limit is tracked through the Peak of Derbyshire. This is prolonged through an anticlinal line into the high western moors of Yorkshire, and there the western escarpment of the chain is accompanied by enormous breaks from the heart of Craven to the foot of Stainmoor. Another enormous break, passing under the escarpment of the Cross-fell range, meets the pro- longed line of the Craven fault at an obtuse angle near the foot of Stainmoor. By this last fault the insulated position of the lake mountains is at once explained. In Professor Sedgwick’s memoir, whence the above is de- rived, we find direct proofs that all the fractures above men- tioned took place immediately before the formation of the conglomerates of the new red sandstone (rothe todte liegende), and he affords the strongest reasons for believing that they were produced by an action both violent and of short duration ; for we pass at once from the inclined and disrupted masses to the horizontal conglomerates now resting upon them; and there is no trace of any effect that indicates a slow progress from one system of things to the other. Lastly, Professor Sedgwick, speculating on the origin of the phenomena de- scribed, points to the different crystalline rocks which appear near the carboniferous chain (toadstone of Derbyshire, and whinstone of Cumberland). N. S. Vol. 10. No. 58. Oct. 1831. 2K The 250 Elie de Beaumont’s Researches on some of The elevation of the chain of the North of England has very probably not been an isolated phenomenon. If we glance at the geological map of England by Mr. Greenough, and that which accompanies the memoir of Dr. Buckland and Mr. Conybeare on the environs of Bristol, we are naturally led to remark that the problematical rocks which pierce and dislocate the coal deposits of Shrewsbury and Colebrooke Dale, and those which constitute the Malvern Hills, appear connected with a series of fractures which run nearly north and south, being prolonged across the recent transition beds and the carboniferous rocks to the environs of Bristol. The coast, with a north and south direction, which bounds the western part of the department of La Manche, may pro- bably also be due to a fracture of the same class as those of the great carboniferous chain of the North of England. IV. System of the Pays Bas and of South Wales.—From the environs of Aix-la-Chapelle to the small isles of St. Bride’s Bay, Pembrokeshire, over a length of about four hundred English miles, the different portions of the carboniferous series, wherever they are not concealed from observation by more recent formations, are seen in a greater or less state of com- plete dislocation. ‘There are situations, as at Liége, Mons, Valenciennes, the Boulognais, and the Mendip Hills, where they have suffered very considerable contortions and disloca- tions. Throughout a large portion of this extent, these beds, which in no part rise to great heights, are covered by more recent deposits, resting horizontally on their edges. ‘The vast sheet of recent deposits which covers the carboniferous series between the environs of Boulogne and those of Bristol, might even throw doubt on the mutual connection of the dislocations in the Pays Bas and the coasts of the Bristol Channel: it is nevertheless certain that the dislocations in both situations possess common characters; such as not widely differing from an east and west direction, without however preserving the same line of bearing for great glistances, and only producing small protuberances on the surface of the land, notwithstand- ing the contortions of the beds in the interior. In the environs of Liége and Aix-la-Chapelle, the direction of the carboniferous beds becomes nearly parallel to that of the argillaceous slates and grauwacké of the Eiffel and the Hundsruck; but it is probable that this arises from the frac- tures of the carboniferous series having been inflected in such a manner as to follow the ancient dislocations of the pre- existing rocks; for it would be difficult not to admit, from the facts previously noticed, that the elevation of the slate and grau- wacké of the Eiffel and the Hundsruck, following a direction nearly the Revolutions which have taken place on the Globe. 251 nearly N.E. and S.W., was not referrible, like that of the analogous rocks in Westmoreland, to a much more remote epoch. The dislocation of the coal-measures of Saarbruck is also probably referrible to the same epoch as that of Glamorgan- shire and the Pays Bas, as it offers nearly the same direction and characters. In the environs of Bristol the magnesian conglomerate horizontally covers the edges of the dislocated carboniferous beds, and the grés de Vosges is seen at Saarbruck in the same position. The elevation of the beds now under consideration ought therefore to be anterior to the deposition of the mag- nesian conglomerate of Bristol and of the grés de Vosges; but as the todte-liegendes (grés rouge), properly so called, does not on any point rest on the carboniferous beds elevated in the direction in question, we may be permitted to presume that their elevation took place after the deposit of the todte- liegendes. V.. System of the Rhine. — The Vosges and the Swartzwald form two groups of mountains, to a certain extent symmetrical, terminating one opposite the other in two long cliffs, the ge- neral directions of which are parallel to each other, and to the course of the Rhine which flows between them from Bale to Mayence. These two cliffs, between which extends the great valley of Alsace, are the most clearly defined characters of that assemblage of mountains which M. von Buch has grouped together under the name of the system of the Rhine. They are partly formed by beds of the grés de Vosges, and appear due to great fractures or faults, with a direction nearly S. 15° W., and N. 15° E., which have broken them after their depo- sition. The epoch of this disturbance has necessarily preceded that of the deposition of all those beds which extend from one cliff to the other, forming the slightly undulating base of the basin of Alsace, and among which occur the red or variegated sandstone (grés bigarré), the muschelkalk, and the variegated marls (marnes irisées). The last three formations have ex- tended round the mountains constituting the system of the Rhine, and mark out the winding of the coasts, bathed by the sea during that period of tranquillity which succeeded those commotions, the effects of which have been so well preserved. VIL. System of the South-west coasts of Britanny, of La Vendée, of Morvan, of the Bihmerwaldgebirge, and of the Thuringerwald. —The oolitic series, comprising the lias and its inferior sand- stone, has been deposited in an assemblage of seas and gulfs which marks out the windings of the various systems of moun- tains above noticed, and at the same time those of a peculiar 2K2 system, 252 Elie de Beaumont’s Researches on some of system, distinguished by the N.W. and S.E, direction of the greater part of its ridges and valleys, and by the beds of the red or variegated sandstone (grés bigarré), the muschelkalk, and the variegated marls (marnes irisées) being thrown out of their original position, as well as all the more ancient rocks. In the centre of France, near Avallon and Autun, the granitic and porphyritic protuberances of Morvan stretch from N.W. to S.E., disturb the coal-measures, and raise a peculiar arkose, contemporaneous with the variegated marls, to their summits ; whilst the lias and another arkose, which forms its lowest part, extend horizontally to the feet of the same protuberances and form the plains which surround them. The same direction, and in part the same geological circumstances, are observable in the hills, partly granitic, of the S. W. coast of Britanny and La Vendée. These circumstances also appear in that part of the Bohmerwaldgebirge which separates Bavaria from Bo- hemia, in the Thuringerwald, and in the lines of disturbance in the muschelkalk and the variegated marls (euper) which according to the excellent map of M. Hoffmann run in the same manner from S.E. to N.W. across the nearly flat coun- tries situated between the Hartz and the Taunus. It therefore appears that the elevation of the different parallel chains above mentioned, is referrible to that revolution on the surface of the globe to which the sudden difference observable between the variegated marls and the lias is due. VII. System of the Pilas, the Cote @ Or, and of the Erzge- birge.— Professor Sedgwick has summed up, in his last Address to the Geological Society of London, our knowledge respect- ing this system. It includes (in Eastern France) the higher elevations of the Céte d’Or and Mont Pilas, the Cevennes, and a portion of the Jura chain. It may be traced towards the valley of the Rhine, where it is suddenly cut off; but it re- appears in the chain of the Erzgebirge, between Bohemia and Saxony. It never rises into mountains of the first order, but is marked throughout (as may be seen on a good physical map) by many longitudinal ridges and furrows, ranging nearly pa- rallel to each other in a direction about north-east and south- west. So far the statement is only an enumeration of certain connected facts in physical geography. But it is followed by a coordinate series of geological phaenomena. A number of formations, including in the ascending order the whole oolitic series, enter here and there into the compo- sition of the geographical system above described ; and, with- out exception, wherever they appear all are in turn elevated, broken, or contorted; yet in their lines of range they pre- serve a parallelism to the general direction of the ridges. On the the Revolutions which have taken place on the Globe. 253 the contrary, wherever rocks of an age not older than that of the green-sand or chalk, appear in the vicinity of any portion of this system, they are either found at a dead level and expanded from the neighbouring mountains into horizontal planes, like the sea at the base of a lofty cliff; or if, since their first deposit, they have undergone any great movement, it is shown to have no relation to the bearing of the older ridges, and to have been produced at a later period. From all these combined facts follow three important con- sequences. Ist, That the whole system of parallel ridges, from one end to the other, was elevated at the same period of time, after the development of the oolitic series, and before the de- position of the green-sand and chalk. 2ndly, That the action of elevation was violent and of short continuance, for the in- clined strata are shattered and contorted; and between them and the horizontal strata there is no intermediate gradation of deposits. 3rdly, That the. period of elevation was followed by an immediate change in many of the forms of organic life. VILI. System of Mont Viso.—The French Alps and the S.W. extremity of the Jura, from the environs of Antibes and Nice to those of Pont d’Ain and Lons-le-Saulnier, present a series of crests and dislocations with a direction towards the N.N.W., in which the older beds of the Wealden formation, the green-sand, and the chalk, are upheaved as well as those of the oolitic series. The pyramid of primitive rocks of Mont Viso is traversed by enormous faults, which from their direction evidently belong to this system of fractures. The eastern crests of the Devolny, north from Gap, are composed of the most ancient beds of the system of green-sand and chalk, thrown up in the direction in question, and elevated more than 4700 English feet above the level of the sea, At the feet of these enormous escarpments, are horizontally deposited, near the Col de Bayud, and at more than 2000 feet lower down, those upper beds of the cretaceous system which are distinguished from the rest by the presence of Nummulites, Cerithia, Ampullaria, and other shells, the genera of which were long considered as not extending deeper in the series than the tertiary rocks. Thus it was between the two portions of that which is commonly termed the series of the Wealden formation, green-sand, and chalk, that the beds of the Mont Viso system have been upraised. IX. Pyreneo-Apennine System. — Professor Sedgwick pre- sented a summary of this system, in his last Address to the Geological Society of London, and I must not omit to men- tion that important parts of the whole evidence were added by Professor Sedgwick himself and Mr. Murchison, during their 254 Elie de Beaumont’s Researches on some of their last travels on the Continent. This system includes the whole chain of the Pyrenees, the northern and some other ridges of the Apennines, the calcareous chains to the N.E. of the Adriatic, those of the Morea, nearly the whole Carpathian chain, and a great series of inequalities continued from that chain through the N.E. escarpment of the Hartz mountains to the plains of Northern Germany. Through the whole of these vast regions the principal inequalities range nearly pa- rallel to each other, and have a mean bearing about west-north- west and east-south-east. So far again the statement is purely geographical, and its truth is seen at once in glancing over any good physical map of Europe; and will be still more clearly comprehended, by comparing some of the principal ranges of colour on Von Buch’s great geological map with the bearing of the Pyrenees. But it is followed by a series of co-extensive geological phenomena. Through all parts of this great system, formations of the age of the green-sand and chalk have had an enormous deve- lopment, and without exception, their strata are ruptured and contorted, and often lifted up to the very pinnacles of the mountains. But on the contrary, wherever any tertiary for- mations approach the confines of this system, they are stated to be either in a position almost as horizontal as the surface of the waters in which they were deposited; or if they have been moved at all, it is by forces uninfluenced by the parallels of the older chains. And the same three conclusions, with a mere difference of dates, follow here as in the former case. All the great parallel ridges and chains of this second system must have been suddenly and violently elevated, and at a pe- riod of time between the deposition of the chalk and the com- mencement of the tertiary groups; and the corresponding change in organic types is, in this instance, still more striking than in the former. X. System of the Islands of Corsica and Sardinia. — The beds named tertiary are far from constituting a continuous whole. Many interruptions are observable in them, each of which may have corresponded with an elevation of moun- tains effected in countries more or less near our own. An attentive examination of the nature and geographical disposition of the tertiary rocks in the north and south of France, has led me to divide them into two series: one, which is composed of the plastic clay, the calcaire grossier, and the whole gypseous formation, including the upper marine mars, scarcely passes to the S. or S.W. of the environs of Paris; whilst the other, represented in the North by the grés de Fon- tainebleau, the upper freshwater formation, and the fahluns, comprises, the Revolutions which have taken place on the Globe. 255 comprises, with few exceptions, nearly the whole tertiary de- posits of the South of France and Switzerland, and especially the lignite deposits, such as those of Fureau (Bouches du Rhone), and Keepfnach (Switzerland). The grés de Fontainebleau, resting on the marls of the gypseous formation, is the lowest portion of this series, in the same manner that the lias sand- stone, resting on the variegated marls (marnes irisées), is the lowest portion of the oolitic series. The former is to the ter- tiary arkose of Auvergne, what the latter is to the Jurassic arkose of Avallon. ‘The two tertiary series are not less di- stinguished by the remains of the large animals which they contain, than by their mode of occurrence. Certain species of Anoplotherium and Palcotherium discovered at Montmartre, characterize the former, whilst other species of Paleotherium and nearly all the species of the genus Lophiodon, the whole genus Anthracotherium, and the more ancient species of the genera Mastodon, Rhinoceros, Hippopotamus, Castor, &c., cha- racterize the latter. The line of demarcation existing between the first and se- cond of these tertiary series would appear to correspond with the elevation of the system of mountains under consideration, the predominant direction of which is from north to south, The beds of the second series are, in fact, those which alone mark out the boundaries of the mountains. Among the dislocations with a north and south direction, we find the chains which border the high valleys of the Loire and Allier, in a similar line of bearing to which are the vol- canic masses of the Dome mountains, and at the bottoms of which the fresh-water rocks of Limagne, of Auvergne, and of the high valley of the Loire have been accumulated. The valley of the Rhone which, quitting Lyon, also runs in a north and south direction, is in like manner filled up to a certain level by a tertiary deposit, the inferior beds of which, analo- gous to those of Auvergne, are also of fresh-water origin, while the upper beds are marine, and in a great measure cor- respond with the fahluns of Touraine. The same direction is observable in the islands of Corsica and Sardinia, in many valleys and small chains of the Apen- nines and of Ystria, in the disposition of many volcanic masses and metalliferous sites of Hungary, and the chain which, commencing in the middle of Servia with the Caponi, is prolonged, parallel to the meridian between Macedonia and Thessaly on the one side, and Albania on the other, bordering the valleys of the Drino and the Arta on the east. . It is worthy of remark, that the directions of the system of the Pilas and the Cote d’Or, of the system of the Pyrenees, and 256 Elie de Beaumont’s Researches on some of and that of the islands of Corsica and Sardinia, are respectively nearly parallel to those of the system of Westmoreland and the Hundsruck, of the system of the Ballons and the hills of the Bocage, and of the system of the North of England. The cor- responding directions only differ in a few degrees, and the two series have succeeded each other in the same order; leading to the supposition that there has been a kind of periodical recur- rence of the same, or nearly the same, directions of elevation. XI. System of the Western Alps.—The opinions in accord- ance with which M. Jurine named the granitic rock constitu- ting Mont Blanc Protogine, can no longer be sustained. The tertiary beds which have been deposited horizontally in that part of the valley of the Rhone which runs N. and S. are constantly contorted and thrown up as they approach the Alps. A similar observation has been made in the valley of the Danube by Professor Sedgwick and Mr. Murchison, who found the cretaceous and tertiary beds to extend horizontally to the foot of the Bohemian mountains, and to be thrown up on entering the Austrian Alps. Messrs. Lyell and Murchi- son have made analogous observations on the tertiary rocks of Lombardy. Professor Buckland and M. Brongniart have pointed out the tertiary aspect of the fossil shells discovered at the Diablerets, at more than 8000 feet above the level of the sea; shells the relative age of which certainly does not go back beyond the last portion of the cretaceous epoch. Although we are generally accustomed to consider the union of those mountains bearing the single name of the Alps as constituting an undivided whole, we can easily recognise that this vast assemblage is due to the crossing of several systems, independent of each other, and distinct both in age and direction. We should therefore not feel surprise that their structure is more confused than that of a chain thrown up by a single effort, such as the Pyrenees. Throughout nearly their whole extent, and especially on their eastern side, we still perceive traces of numerous small chains of mountains with the same direction as the Pyrenees, and elevated in like manner prior to the deposition of the tertiary rocks. The system of Mont Viso is strongly marked in the French Alps. These traces of comparatively ancient dislocations are, how- ever, often marked by disturbances of a more recent date. The highest and most complicated portions of the Alps, those near the Mont Blanc, Mont Rose, and the Finsteraar- horn, are principally due to the crossing of two recent systems which meet at an angle of from 45° to 50°, and which are di- stinguishable from the system of Mont Viso and the Pyreneo- Apennine system, as well by their age as their directions. In consequence the Revolutions which have taken place on the Globe. 257 consequence of the crossing of these two systems of furrows and ridges, the French Alps form an elbow near the Mont Blanc, and after having followed a direction from E. }° N.E. to W. 34° S.W. from Austria to the Valais, they suddenly turn to fall into a line from N.N.E. to S.S.W. If there was only a simple curve m a single chain of mountains which merely formed an arch, we should find the direction of the beds to bend and pass from the direction of one of the sy- stems to that of the other. We however observe, that the direction of the beds and crests distinctly belong either to one or to the other, and that the two systems penetrate each other, as we should conceive they must do if they are the produc- tions of two entirely distinct phenomena. In the Western Alps, that is to say, to the westward of the St. Gothard, and particularly in the mountains of Savoy and Dauphiny, the greater part of the dislocations are referrible to two systems of ridges, the mean direction of which is N.N.E. and S.S. W., or more exactly N. 26° E., and S. 26° W. The constant direction of the beds in these mountains has long since been remarked by De Saussure, and more recently by M. Brochant; and they with reason concluded, that in all those parts where this direction predominated, the beds were thrown up by a single operation of nature. It is easy to determine the geological date of this event; for we have only to examine what are the formations which have been disturbed, and what the deposits which extend horizon- tally on the edges of the dislocated and more ancient strata. In the interior of that system of ridges of which the Western Alps are principally composed, we do not find beds more re- cent than the chalk, because these ridges have been formed on a surface previously made mountainous, at the epoch of the systems of Mont Viso and the Pyrenees. But on the skirts, as also at the two extremities of the space occupied by the ridges to which the character of the Western Alps is due, we find that the dislocations which have produced the ridges are carried into the most recent tertiary deposits, as well as into the secondary rocks which support them: whence it follows, that the elevation of the beds in the system of the Western Alps took place after the deposit of those recent tertiary beds, named shelly molasse (mollasse coquilliére), beds contempo- raneous with the fahluns of 'Touraine. XII. System of the principal Chain of the Alps (from the Valais to Austria), comprising also the Chains of the Ventoux, the Liberon, and the St. Baume (Provence).—The valleys of the Isére, the Rhone, the Saone, and the Durance, present two very distinct detrital and transported formations, between N.S. Vol. 10. No. 58. Oct. 1831. 2L which 258 Elie de Beaumont’s Researches on some of which there is a want of continuity, and a sudden variation of character, constituting a new interruption in the series of sedimentary deposits. The waters which have transported the materials of the first of these formations would appear to have been received into lakes of fresh water which covered, in one direction, the N.W. portion of the department of the Isére, La Bresse, and perhaps, Alsace, and even the environs of the lake of Con- stance; and in the other, the portion of the department of the Basses Alpes between Digne, Manosque, and Barjols: whilst the materials of the second formation appear to have been violently carried by temporary currents which have discharged themselves into the Mediterranean, These latter currents are generally known as diluvial currents, though they offer nothing in common with the Deluge of history, and though their passage took place before the human race appeared on our continent, where they destroyed animals of species now extinct. Discussions will still perhaps be carried on respect- ing their origin, which may have merely been the result of the melting of the snows, instantaneously effected when the principal chain of the Alps was elevated ; but it seems generally admitted that their passage immediately followed the last dis- location of the Alpine strata. If we cast a general glance on the Alps and neighbouring countries, we may observe that the crests of the St. Baume, the Lebaron, the Ventoux, and the Montagne de Poet, in the South of France, the principal chain of the Alps from the Valais to Austria, and the less elevated crest, comprising the Pilate, &c. in Switzerland, are so many different chains, which, notwithstanding their inequality, are comparable with each other both as respects their parallelism and their common analogies to the system of the Western Alps. This parallelism and these analogies would alone afford us powerful reasons for believing that the whole of these mountain-chains were formed at the same time, and are only different parts of a single system of fractures produced at the same moment. We can at furthest conceive the idea of dividing them into two groups, —that of Provence, and that of the Alps; but we are prevented from doing this by the analogous relations observable among the different fractures, and by a general movement which we may consider the surface of a part of France to have suffered when it contracted a double slope; ascending in one direction from Dijon and Bourges towards Le Forez and Auvergne, and on the other from the shores of the Mediterranean towards the same countries. These opposed slopes present at their junction a kind of crest, situated precisely in the line of eleva- tion the Revolutions which have taken place on the Globe. 259 tion of the principal chain of the Alps. This line, which may be observed to run ina more or less marked manner from the confines of Hungary to Auvergne, appears to be connected with the principal anomalies unveiled in the interior structure of our continent by geodesical measurements and observations with the pendulum. We may even suppose that the forma- tion of this line gave, as it were, the signal for the appearance of the craters of elevation of the Cantal and Mont d’Or, round which the volcanic cones of Auvergne have been subsequently thrown up. The two opposite slopes, above mentioned, were not pro- duced until after the existence of those lakes in which the older transported substances were accumulated ; for it can be ascertained that the bottom of the lake which covered La Bresse and the N.W. portion of the department of the Isére has suffered a considerable elevation from the north towards the south, and that the bottom of the lake which extended between Digne, Manosque, and Barjols, has been elevated to a great degree from the south towards the north, The ancient deposits of transported substances, forming horizontal beds at the bottom of the latter of these lakes, on the edges of tertiary deposits, previously dislocated when the Western Alps were thrown up, are in their turn dislocated near Mezel (Basses Alpes) in the direction of the small chains which ridge Provence, such as the Ventoux and Lebaron, parallel to the principal chain of the Alps. To determine the date of this last order of dislocations it will be sufficient to remark, that the diluvian deposit is in no part affected ; that it covers the edges of the dislocated beds with no other slope than that which the current impressed on them at their origin; and that thus the elevation of the beds in question necessarily took place between the older deposit of transported substances and the passage of the diluvian cur- rents. If we attentively consider, on a terrestrial globe of suffi- cient size and good execution, the most prominent and the most recent systems of mountains which ridge Europe, we may remark that each of them forms a part of a vast system of parallel chains, which extends far beyond the countries geologically known to us. But as in all the parts of each of these systems situated in well examined portions of Europe, it has been more and more observed that parallel chains are in general contemporaneous, there is no reason to suppose that this law should suddenly cease, if its verification should be pushed still further, It is therefore natural to consider, until direct observations may show the contrary, that each of 2L2 these 260 Elie de Beaumont’s Researches on some of these vast systems, of which the European systems are re- spectively portions, originates in a single epoch of dislocation. From this view I am led to suppose, for example, that the principal chain of the Alps is contemporaneous with a vast assemblage of mountain-chains which spread round the Medi- terranean, and being prolonged across the continent of Asia, run paraliel to a great circle which should pass through the middle of Morocco and the north of the Birman empire, and appear at the same time connected with each other by paral- lelism and by the similarity of their relations to the great de- pressions of surface filled by the sea, or but slighty raised above its level. Besides the principal chain of the Alps, and the small chains of Provence, this system comprises, in Europe, the Sierra Morena, and a large portion of the Spa- nish chains, on the one hand, and the Balkan on the other: in Africa, it includes the Atlas: in Asia, the central trachytic chain of the Caucasus, crowned by the peak of Elbrouz, more elevated than the Mont Blanc, as also the long series of moun- tains which under the names of Paropamissus, Indou-Kosh, and Himalaya, bound the plains of Persia and Bengal, and contain the most elevated mountains on the surface of the earth. Iam also led to suppose that the system of the Western Alps constitutes a portion of a vast system, comprising the chain of Kiol in Scandinavia, the chains which in Morocco run from Cape Tres Furcas to Cape Blanc, and the Littoral Cordilera of Brazil. Finally, I am led to suppose that the chains of the Pyreneo- Apennine system observed in Europe, form a portion ofa vast system comprising certain chains in the north of Africa, of Egypt, of Syria, of the Caucasus, the chains which bound Mesopotamia on the north-east, and even the Ghauts of Mala- bar, and which appears in another direction, across the Atlan- tic, in the Alleghanies. The appearance of a new system of mountains which, judging from the result of our observations, has produced such violent effects on countries near them, could only have exercised an influence in distant countries by the agitation caused in the waters of the sea, and by a greater or less change produced in their level,—events which may be compared to the sudden and passing deluge noticed among the traditions of all nations as having occurred at nearly the same epoch. If this historical event was the last which has taken place on the sur- face of the globe, we are naturally led to inquire which is the mountain-chain referrible to the same date: and perhaps we may be justified in observing that the chain of the Andes, Hl volcanic the Revolutions which have taken place on the Globe. 261 volcanic vents are still in activity, (or more exactly the long cliff (_falaise) surmounted or bounded by volcanos which run on a great semicircle of the earth from Chili to the Birman country,) presents the most extensive, the most clearly defined, and as it were the least obliterated feature observable in the present exterior configuration of the globe. It has been shown, as Professor Sedgwick justly observes, that paroxysms of internal energy, accompanied by the eleva- tion of mountains, and followed by mighty waves desolating whole regions of the earth, were a part of the mechanism of Nature; and what has happened again and again, from the most ancient up to the most modern periods, may have hap- pened once during the few thousand years that man has been living on its surface. We have therefore taken away all an- terior incredibility from the fact of a recent deluge. If the general result of the preceding observations be exact, we may briefly express it by saying, that the independence of sedimentary formations is both a consequence and proof of the independence of mountain-systems. having different direc- tions. Many traces of interruptions in the series of sedimen- tary deposits are, perhaps, so slight in Europe, only because they correspond with mountain-systems which, like that so strongly marked on the shores of Mozambique and Madagas- car, have not sent any ramifications into our countries. But if the number of the surface-revolutions of the globe, and of really distinct mountain-systems be still undetermined, and if the series formed by these successive terms be still im- perfectly known, the observations already made nevertheless circumscribe within certain limits that law, which when they shall be all completely known may be manifested in their suc- cession. From the circumstance of the present heights of Mont Blanc and Mont Rosa, dating only from the later sur- face-revolutions of the globe, it is clear, that whatever defini- tive place other and higher mountains may occupy in the same series, this series will never take that gradually and regularly decreasing form which should lead to the conclusion, that the limit was attained. Nothing will show that phenomena the last paroxysms of which have been so violent should not be reproduced. However provisional the succession of terms may be which results from the preceding memoir, it is diffi- cult to foresee a modification which should so change its ' aspect, as to lead to the supposition, that the mineral crust of - the globe has lost the property of being successively ridged in various directions. It is difficult to conceive a change which would permit us to assure ourselyes that the period of tran- quillity 262 Elie de Beaumont’s Researches on some of quillity in which we live will not be disturbed in its turn by the appearance of a new system of mountains, the effect of a new dislocation of the land we inhabit, and of which earth- quakes teach us the foundations are not immovable. The independence of successive sedimentary formations is the most important result obtained from the study of the su- perficial beds of our globe; and one of the principal objects of my researches has been to show, that this great fact is a consequence, and eyen a proof, of the independence of moun- tain-systems having different directions. The fact of a general uniformity in the direction of all beds upheaved at the same epoch, and consequently in the crests formed by these beds, is perhaps as important in the study of mountains, as the independence of successive formations is in the study of superimposed beds. The sudden change of direction in passing from one group to another has permitted the division of European chains into a certain number of distinct systems, which penetrate, and sometimes cross each other without becoming confounded. I have recognised from various examples, of which the number now amounts to twelve, that there is a coincidence between the sudden changes esta- blished by the lines of demarcation observable in certain con- secutive stages of the sedimentary rocks, and the elevation of the beds of the same number of mountain-systems. Pursuing the subject as far as my means of observation and induction will permit, it has appeared to me, that the different systems, at least those which are at the same time the most striking and recent, are composed of a certain number of small chains, ranged parallel to the semicircumference of the surface of the globe, and occupying a zone of much greater length than breadth; and of which the length embraces a considerable fraction of one of the great circles of the ter- restrial sphere. It may be observed in support of the hy- pothesis of each of these mountain-systems being the product of a single epoch of dislocation, that it is easier geometrically to conceive the manner in which the solid crust of the globe may be elevated into ridges along a considerable portion of one of its great circles, than that a similar effect may have been produced in a more restricted space. However well established it may be by facts, the assem- blage of which constitutes positive geology, that the surface of the globe has presented a long series of tranquil periods, * each separated from that which followed it by a sudden and violent convulsion, in which a portion uf the earth’s crust was dislocated, —that, in a word, this surface was ridged at intervals in the Revolutions which have taken place on the Globe. 263 in different directions; the mind would not rest satisfied if it did not perceive, among those causes now in action, an ele- ment fitted from time to time to produce disturbances dif- ferent from the ordinary march of the phznomena which we now witness. The idea of volcanic action naturally presents itself when we search, in the existing state of things, for a term of com- parison with these great phenomena. ‘They nevertheless do not appear susceptible of being referred to volcanic action, unless we define it, with M. Humboldt, as being the influence exercised by the interior of a planet on its exterior covering during its different stages of refrigeration. Volcanos are frequently arranged in lines following frac- tures parallel to mountain-chains, and which originate in the elevation of such chains; but it does not appear to me that we can thence regard the elevation of the chains themselves as due to the action of volcanic foci, taking the words in their ordinary and restricted sense. We can easily conceive how a volcanic focus may produce accidents circularly and in the form of rays from a central point, but we cannot conceive how even many united focz could produce those ridges which follow a common direction through several degrees. Volcanic action, such as it is commonly understood, could not therefore be itself the first cause of these great phzeno- mena; but volcanic action appears to be related (and this is a subject which has long occupied M. Cordier, though he has considered it under another point of view) with the high tem- perature now existing in the earth. Now the secular refrigeration, that is to say, the slow dif- fusion of the primitive heat to which the planets owe their spheroidal form, and the generally regular disposition of their beds from the centre to the circumference, in the order of specific gravity,—the secular refrigeration, on the march of which M. Fourier has thrown so much light, does offer an element to which these extraordinary effects may be referred. This element is the relation which a refrigeration so advanced as that of the planetary bodies establishes between the capa- city of their solid crusts and the volume of their internal masses. In a given time, the temperature of the interior of the planets is lowered by a much greater quantity than that on their surfaces, of which the refrigeration is now nearly insen- sible. We are, undoubtedly, ignorant of the physical pro- erties of the matter composing the interior of these bodies ; But analogy leads us to consider, that the inequality of cooling above noticed would place their crusts under the necessity of continually 264 Mr. Blackwall on a new Species of Hawk. continually diminishing their capacities, notwithstanding the nearly rigorous constancy of their temperature, in order that they should not cease to embrace their internal masses ex- actly, the temperature of which diminishes sensibly. They must therefore depart in a slight and progressive manner from the spheroidal figure proper to them, and corresponding to a maximum of capacity; and the gradually increasing tendency to revert to that figure, whether it acts alone, or whether it combines with other internal causes of change which the planets may contain, may, with great probability, completely account for the ridges and protuberances which have been suddenly formed at intervals on the external crust of the earth, and probably also of all the other planets. XXXIII. On an undescribed Bird of the Family Falconidz. By Joun Brackwat1, Esq. F.L.S. &c.* [pUENc the last two years, five specimens of a minute Hawk, no account of which, there is reason to believe, has yet been published, have been brought to Manchester, at different periods, from Brazil. On inspecting this new species, it is evident from several peculiarities in its organization, that it should occupy a situation, in a natural arrangement of birds, intermediate between the Hawks and true Falcons; as it unites in itself certain features characteristic of each of those groups. Its short bill, curved from the base, the upper mandible of which is furnished on each side with a small festoon; the shortness of its wings, notwithstanding the second quill-feather is the longest, and the first has the inner web slightly emar- ginated near its termination; the moderate length of the tail and legs; the reticulated tarsi, and the acrotarsia feathered from the knee to the middle,—plainly indicate that it must be referred to the genus Gampsonyz, established by Mr. Vigors. Order. Raptores. Illiger. Family. Falconida. Leach. Subfamily. Accipitrina. Vigors. Genus. Gampsonyz. Vigors. G. Holmii. The bill, which is much curved, is black faintly tinged with blue. Plumage on the forehead and cheeks pale orange; that on the top of the head, back, scapu- lars and upper part of the wings, dark cinereous brown. Greater wing-coverts and feathers of the spurious wings * Communicated by the Author. white Mr. Brooke on Monticellite, and other Minerals. 265 white at their extremities. Each quill-feather of the wings has a broad margin of white on its inner web, and the secondaries and tertials are tipped with white. Upper tail-coverts and feathers of the tail deep cine- reous; the latter, with the exception of the two mid- dle ones, which are plain, having a border of white on their inner webs. A white collar passes over the back part of the neck, immediately behind which is a narrow parallel band of a chestnut colour. On each side of the breast a black spot is conspicuous. All the inferior parts are white except the thighs, which are of a bright rust colour, and the under coverts of the wings, which exhibit a slight tint of the same hue. Legs and feet yellow. Claws dark horn colour inclining to black. Colour of the eyes not known. Total length 9 inches ; wings, from the carpus to the tip of the second quill- feather, 5,2, ; upper mandible, from the point to the gape, in a straight line, ;; under mandible, ;° ; tarsi, 1. The specimen from which the foregoing description was taken occupies a place in the Manchester Museum. That G. Holmii bears a striking resemblance to the G. Swainsonii of Mr. Vigors cannot be denied; the white collar and chestnut-coloured band on the neck of the former, and the pure white plumage of its abdomen, constituting the most obvious points of difference between the two species. To Edward Holme, M.D., the learned and accomplished President of the Natural History Society of Manchester, (who has uniformly promoted my zoological investigations by every assistance which his extensive knowledge and valuable library could supply,) this bird is respectfully dedicated. XXXIV. On Monticellite, a new Species of Mineral; on the Characters of Zoizite; and on Cupreous Sulphate of Lead. By H.J. Brooke, Esq. F.R.S. LS. §& G.S.* Monticellite. I OBTAINED a year or two since from Mr. G. B. Sowerby, a specimen said to have come from Vesuvius, containing some imbedded crystals of a substance which I believe has not been before noticed, and of which I am not aware of having seen any other specimen. The matrix is crystalline carbonate of lime; and besides the mineral I am about to describe, it contains particles of black mica, and some minute crystals of pyroxene. On the supposition of its being an undescribed mi- neral, and from Vesuvius, I have named it after Mr. Monti- * Communicated by the Author. N.S. Vol. 10. No. 58, Oct. 1831. 2M celli, 266 Mr. Brooke on Zoizite. celli, who has published a work in illustration of the minerals found in the neighbourhood of that mountain. The general aspect of the crystals is that of quartz, and might by a cur- sory observer be mistaken for it. The colour generally is yellowish, but there are some crystals nearly colourless and nearly transparent; and on placing a portion of the specimen in dilute muriatic acid to dissolve the carbonate of lime, I found that the surfaces of the yellowish crystals became dull, and were covered with a yellowish powder, leaving the crystals less coloured than they were at first. The primary form is a right rhombic prism of about 132° 54’, a terminal edge being to a lateral edge as 1 to 1-046 very nearly. I have not observed any cleavage planes on the fractured surfaces, and the crystals are too small to allow of much other examination in this respect. The hardness is between that of apatite and felspar. ‘There is no crystal sufficiently free from the matrix to allow of the specific gravity being ascertained ; nor are the surfaces of the crystals sufficiently perfect to afford very accurate measurements. ‘The following therefore may admit of some slight correction : Plaviés®s KOR. ieee, Fe a Sigh ey Symbols .....sessseeees Be By G: M,M'= 132° 54! M,e = 145 00 ee = 141 48 hc = 138 46 Mk) = 113. 33 Zoizite. This mineral has been confounded with Epidote by Haiy, probably from the occurrence of crystals of that substance in the Zoizite of Hoff; and in this mistake he has been followed by most other writers on the subject. The late W. Phillips says, * it cleaves parallel to the planes of a right rhombic prism of about 60° and 120°.” Mr. Haidinger, in his Treatise on Mineralogy, says that Epidote and Zoizite are easily distinguished by their colours. And in reference to the angle which I had given as that of Zoizite, differing from the angle of Epidote, he says; ‘ this would render it necessary to consider Zoizite as a particular species.” Hence it is clear that Mr. Haidinger could not have examined this mineral; for ifhe had, he must immediately have perceived its difference from Epidote. I have lately obtained a small crystal of Zoizite with terminal planes, Mr. Brooke on Cupreous Sulphate of Lead. 267 planes, from which it is evident that the primary form is an oblique rhombic prism, and from the angles given below it approaches very nearly, if it be not the same as that of euclase. It has also a bright cleavage through the oblique diagonal, similar to that of euclase, and no very distinct cleavage in any other direction. The annexed figure exhibits the form of the crystal I have alluded to, the terminal planes of which are, however, too imperfect to afford accurate measurements. ela = 193° 30! (about)* ac = 107 20 ... Pyc9 = 107° 20! pe "et 45°... Pct = 120 30 a == 145 20 bb’ = 116 30 The perfect identity of the forms of Zoizite and Euclase depends obviously on the relative démensions of the primary forms, as well as upon the angles of the prisms; and as those dimensions can be deduced only from accurate measurements of the terminal planes, it is to be hoped that those who possess better crystals will supply the deficient angles, and complete the description of the form. Cupreous Sulphate of Lead. A specimen I have lately obtained of this substance has enabled me to give the annexed figure and measurements of the crystals. ‘The primary form is an oblique rhombic prism, a terminal edge of which is to a lateral edge as 19 to 8 very nearly, the plane angles of the terminal plane at the extre- mities of the oblique diagonal being 59° 12’. Planes ...... cl, €2, ¢c3, C4, c5y h. Symbols.... PB P,c3 Pyct Pyc5 M,M’ = * Corresponding planes of euclase, as measured by W. P. (See his figure.) 2M2 Hemitrope 268 Mr. Daniell on a New Register-Pyrometer, Hemitrope crystals occasionally present themselves, the plane of revolution being parallel to the plane 4, which trun- cates the edge of the prism. The angle at which the two planes P then intersect each other, is 154° 30!. XXXV. On a new Register-Pyrometer, for Measuring the Expansions of Solids, and determining the higher Degrees of Temperature upon the common Thermometric Scale. By J. Freperic Daniewy, Esq. F.R.S. [Continued from p, 199.] | SHALL now proceed to show the degree of confidence which may be placed in this new pyrometer, by comparing the result of its indications with those of the best experiments upon the expansion of metals. Those of MM. Dulong and Pe- tit* are well adapted to this purpose. These able philosophers, in their celebrated prize Memoir on the Measure of ‘Tempe- ratures, and on the Laws of the Communication of Heat, have given, from experiment, the expansion of rods of platinum and iron at different intervals between the freezing point of water and the boiling of mercury. Their mode of experi- menting was unexceptionable; but it is to be regretted that they have not corrected their final results for an error of cal- culation which has been pointed out by Mr. Crichton+ which is by no means unimportant to the reasoning which they have founded upon them. The error, however, affecting the amount of expansion in volume, is reduced to one-third in the linear expansion, which is the subject’of the present investigation, and may therefore be disregarded. The following Table of the expansion of iron and platinum is extracted from their work. Taste II. Temperature deduced Mean absolute Mean absolute from the Dilatation Dilatation cf Iron | Dilatation of Platinum of Air. for 180 degrees. for 180 degrees. ° ° pi Dey othe From 32° to 212 28200 37700 ° ° 1 pes: wis. From 392° to 572 22700 36300 Whence we deduce the linear expansion of platinum for 180° Fahrenheit, from 32° to 212° ‘00088420: and for 180°, * Ann. de Chimie et Physique, vii. 113. + Annals of Philosophy, New Series, vol. vii. p. 241. from for Measuring the Expansions of Solids, §c. 269 from 392° to 572° 00091827: and of iron, from 32° to 212° 00118203: from 392° to 572° -00146842, showing an increas- ing dilatation in each when referred to an air-thermometer. The bars of the different metals used in the following expe- riments were all exactly 6°5 inches in length. Exp. 1. A square bar of platinum 5%ths of an inch thick, was carefully arranged in the black-lead register, which was placed in the apparatus represented, upon a diminished scale, at fig. 3. (Plate II.) ais an iron tube about two inches diameter, and closed at the botom: 0 is a black-lead tube closed at the top, and fitted to the mouth of the former by grinding: c is a smaller black-lead tube projecting from the side of the latter near its upper end, and likewise fitted to its place by grinding. The whole forms a kind of alembic, which may be readily put together, and in which mercury may be easily boiled on a common fire, and the vapours collected without loss or an- noyance to the operator. The register was fixed in its place by a wire, so that when mercury was poured into the iron bottle it was prevented from floating. ‘The mercury in this experiment rose a little above half the length of the register. The whole apparatus was then placed upon a fire, and in ten minutes the mercury began to boil: in ten minutes more it freely distilled over; and in ten minutes further the apparatus was removed, the register taken out and allowed to cool. The arc measured upon the scale was in this instance 1° 17/. The experiment was repeated, merely having the head of the alembic off, and suffering the mercury to boil freely in the iron bottle for a quarter ofan hour. The arc measured was 1° 23'. The register was next allowed to float upon the mercury, so that when the head of the alembic was adjusted and the mercury made to boil, it was not immersed in the metal, but surrounded by its vapour: the reading was 1° 16'. A repeti- tion of this arrangement gave 1° 23. In another repetition of the experiment, the time was ex- tended to twenty minutes from the first boiling of the mercury; the reading of the scale was 1° 20. Again; the time was reduced to ten minutes, and the measurement was 1° 23'. In the various repetitions of this experiment the mercury freely distilled over, and the temperature was such, that every part of the black-lead tubes, in which the vapour circulated, would just scorch, but not blacken, a piece of writing paper held against them. The following Table collects these results into one view, and exhibits the expansion denoted by each reading, and the mean result, TABLE 270 Mr. Daniell on a New Register-Pyrometer, Taste III. 1°17!/)=-01119 1 23 = °01206 116 = :01105 1 23 = :01206 1 20 = +011638 1 23 = :01206—Mean 1° 20' = ‘01163. The temperature of the atmosphere was about 64° during these observations. Exzp.2. >2°—B 22 dll fe 3 2° 5 cotang s =— —A 7 7-Bi54" Cae Be as Having due regard to the following relations: Be; oe 1234 ° 9 we obtain for (x cotang x—1) cotang ~ this series: A eatt Bi pes eto hal and pa 2 3 2 5 Ce x(z)=—=- Art Tag Br + Tange C2i+ ieee Da". os By this series the value of the function may be easily calcu- lated for small values of x; for greater ones the finite ex- pression is accurate enough for calculation. The limit of the conver- of the Orbits of Double Stars. 281 convergency of the series may be most easily investigated by introducing instead of A, B, C, &c. the sums of the reciprocal even powers of numbers; if 1 1 + 3 a Ae eeccece 1 alt ge 1 1 1 sr ih 6 lic IRA eccene 1 1 1 oe e=1+ Bea tig aaah fe ts it is well known that n= a2 ™ Ea NPE | 2B y e 1234 ” 2°C . = —————. 7 123456 consequently, Qa « 4b & G6e 2 8d 2 AO) iT Sei lV NMM ib gM THATS In the distant terms of the series the ratio of two successive powers of <, say 23 ey and ca Winker ee coefficients let be represented thus : 2h, and PP eg T us will more and more approach to unity, so that the series will always. converge for z oo ——-- 582 —— «=13°7 —- | —«§» —— 59 - —— += i116 April-Sth,' 183i.) N56 Se gag BY gin a 62 te 1 — 63 13 *3* The mean of the whole is 12!8, but if we reject the fourth measurement it will become 13!'*1. By the Tenth Method. Theory.—Having demonstrated that the axis of the faulty cylinder deviates, when reversed, from the opposite of its previous direction by double the instrumental error, it is evi- dent that the line of collimation of a telescope made parallel to the axis of the cylinder before, and that of another telescope made parallel to it after the reversing took place, would be inclined to each other by twice the error. Apparatus.—In addition to the apparatus first employed, two Instrumental Error of his Horizon-Sector. 347 two substantial blocks of wood were glued, nine inches asun- der, to the upper surface of the plank towards its northern end; (occupying the place of the lantern as represented in the figure, p. 338.) These blocks, notched in the middle in a line with the cylinder and telescope, supported, on a level with the two latter, a tube of wood 14 inches long and 1°5 inch in dia- meter, containing within its southern end the additional ob- ject-glass and tube, and a fine eye-piece (by Dollond) within the northern end. Distinct vision of the cross lines, fixed at right angles to each other, between the first and second glasses of the eye-tube, being obtained by regulating their distance from the moveable eye-glass, the object-glass was adjusted to the proper focus by pointing the tube (telescope) at the sails of a distant windmill. Method of Observation.—The cylinder being removed, its place within the Ys was supplied by a tin tube (of the same diameter) blackened within, which reached so nearly from the object-glass of one telescope to that of the other that all false light could be excluded by a large piece of black cloth cover- ing the tube and object-glasses. Having placed the lantern a little beyond the eye-glass of the round telescope, the inter- secting point of the cross threads of the square telescope were moved by their micrometer screw until they bisected the ho- rizontal wire of the round telescope where crossed by the ver- tical one. Removing the lantern to beyond the eye-glass of the square telescope, the bisection, on looking through the round telescope, did not appear quite perfect or certain, being slightly affected by evident parallax. Lastly; the cylinder containing its proper object-glass only, being substituted for the removed tin tube, the line of colli- mation of its object-glass, which was situated close to that of the round telescope, was made parallel by the rack-work of the stand to that of the latter; or rather, as nearly so as the almost impossibility of placing one wire exactly before another would admit of. The cylinder being reversed, the great levels were read off, before, and then again after the line of collima- tion of its object-glass had been made parallel, by the rack- work of the stand, to that of the square telescope. In making the bisections, the lamp stood on separate apparatus near the eye-glass of the opposite telescope. The results (scarcely worth transcribing) varied in eighteen measurements from 15-5 to 27-5; mean 21-3, or 8” more than by the Lleventh method. Joun Nixon. {To be continued.] 2Y 2 XLIIL. Notice f. 948) J XLIII. Notice on Ovalic Acid. By Euwarv Turner, M.D. F.RS. L. & E. &c., Professor of Chemistry in the University of London*. N a former Number of this Journal+ I had occasion to publish some remarks on the volatility of oxalic acid; and about the same time M. Gay-Lussac published in the Annales de Chimie et de Physique, vol. xlvi. p. 218, a short memoir on the easy decomposition of oxalic acid by the agency of heatt. In my notice the sublimed acid is described as supporting a temperature of 330° Fahrenheit, without any decomposition ; while M. Gay-Lussac, speaking of the crystals in their ordi- nary state, describes them as being decomposed at so low a temperature as 236° Fahrenheit. As these statements may be thought contradictory, while at the same time a correct knowledge of these facts is required for understanding an in- teresting point of theory,—the action of the sulphuric on oxalic acid,—I have re-examined the subject with the hope of cor- recting any inadvertence which may have been committed. In the experiments which I have made with this view, the heat was applied through the medium of a small mercurial bath, heated by alamp: the acid to be decomposed was con- tained in a small glass tube, the sealed end of which was plunged into the bath, and its other extremity connected in the usual manner with a mercurial trough. The tempera- ture was ascertained by fixing the bulb of a thermometer in the bath during the whole continuance of the experiments. By operating in this way I found that my former statement was strictly correct. Oxalic acid containing only one equi- valent of water, whether prepared by merely heating the or- dinary crystals or by sublimation, sustained a temperature of 330° without yielding either water or gas. As the thermo- meter rose from $30° to 340°, gas began slowly to appear, and at 370° it was freely disengaged. It hence follows that the best temperature for subliming oxalic acid is 330°: it then sublimes with rapidity, and yet there is no loss by decomposi- tion; but before exposure to this degree of heat, the acid should previously be dried as much as possible at a lower temperature. But it does not necessarily follow, because my statement is correct, that that of M. Gay-Lussac should be erroneous. On the contrary, though we differ as to the precise degree of heat at which decomposition takes place, I find that crystallized oxalic acid, containing one equivalent of real acid and three * Communicated by the Author. + Phil. Mag. and Annals, N.S. vol. ix. p. 161. [t See also Phil. Mag. and Annals, vol. x. p. 153,-—Eprt. } of Dr. Turner’s Notice on Oxalic Acid. $49 of water, is decomposed by heat at a lower temperature than the same acid after two equivalents of water have been re- moved. Thus, on operating with the fully hydrated acid in the same manner as with that which had fully effloresced on the sand-bath, fusion took place at 209°, as stated by M. Gay-Lussac, and not at 220° as I had found in heating some crystals, which must previously have lost a little of their water of crystallization. As the temperature of the bath rose to 230°, the fused mass remained quite tranquil, yielding a little water, but not a particle of gas. At 240° there was still scarcely any gas, and very little at 250° or 270°. Even at 290°, though there was violent ebullition from the rapid escape of aqueous vapour, yet the evolution of gas was by no means abundant: it became free at 310°, and was rapid at 320°. In a second careful experiment the results were pre- cisely similar. lt is therefore apparent that oxalic acid, as deposited in crystals from solution, is decomposed at a consi- derably lower temperature than when it contains only one equivalent of water. My observation on the decomposition of oxalic acid by sul- phuric acid induces me to dissent from the explanation which M. Gay-Lussac has suggested. Sublimed oxalic acid, acted on by a considerable quantity of strong sulphuric acid, began to effervesce by being kept for a few minutes in a vessel of boiling water. The action indeed was slow, but it was per- fectly distinct and continuous, the disengaged gas consisting as usual of equal measures of carbonic oxide and carbonic acid. ‘The effervescence was much more free at 220°, and still more so at 230°; and yet the same acid, exposed to mere heat, would not have yielded a particle of gas at the tempera- ture of 330°. Oxalic acid, in its most hydrated state, if mixed with a large excess of sulphuric acid, is decomposed at nearly the same temperature as it is after having lost two-thirds of its water, effervescing with moderate freedom at 220°; whereas it may be heated by itself to 230° without decomposition. As the temperature in all these experiments was ascertained by the same thermometer, they are quite independent of any error in graduation. Such an error, which must be slight if it exist at all, cannot account for the comparative results ob- tained in my own experiments, though it may in part explain the discordance in the observations of M. Gay-Lussac and myself. It may surely therefore be inferred, that the decom- position is not due to the sole agency of heat; and we may, I apprehend, continue to explain the phanomenon on the principle which has been hitherto generally admitted. 1 concur with M. Gay-Lussac respecting the composition of 350 Mr. Daniell on a New Register-Pyrometer, of the gas evolved from fully hydrated oxalic acid when de- composed by heat. According to my observation, the ratio of carbonic oxide to carbonic acid is always nearly as five to six. A similar mixture is evolved from the acid after two-thirds of its water has been withdrawn, provided the heat be slowly applied; but when the decomposition is very rapid, I have generally obtained a still smaller proportion of carbonic oxide. On one occasion this gas did not exceed 31 per cent. The statement of M. Gay-Lussac relative to the appearance of formic acid, and the explanation which he gives of its pro- duction, appear to me perfectly correct. XLIV. On a new Register-Pyrometer, for Measuring the - Expansions of Solids, and determining the higher Degrees of Temperature upon the common Thermometric Scale. By J. Freperic DaniE.1, Esq. F.R.S. [Concluded from p. 279.] SHALL now collect together the results of the preceding experiments, for the purpose of showing what conclusions may be derived from them with regard to the degrees of tem- perature which they indicate when referred to the common thermometric scale. I shall make the calculations first upon the supposition that equal amounts of expansion denote equal increments of temperature; and I shall thus be enabled to compare the present series with that which I formerly obtained with my first pyrometer, and to offer a few remarks upon the differences of the two. I shall adopt the corrected temperature of 662° (350° cen- tigrade) for the boiling point of mercury, as proposed by MM. Dulong and Petit; which agrees very closely with the amount employed in my first calculations, and which, deduct- ing 62° for the mean temperature at which my experiments commenced, gives 600° for the interval tor which the several expansions were determined. The first column of the following Table refers to the num- ber of the experiment; the second to the mark of the register and the bar which was employed; and the third to the amount of expansion in the same, occasioned by boiling mercury, or 600° of temperature upon Fahrenheit’s scale. The fourth column exhibits the arc measured upon the scale; and the fifth the equivalent expansion. ‘The sixth contains the cor- responding temperature; the seventh records the state of the metal, which was the object of the experiment; and in the eighth I have recapitulated the corresponding results of my former Essay. TABLE Jor Measuring the Expansions of Solids, &c. 351 TaBLe X. ee : F a o,. 2|Mark of|.20°/$5 | .g BPE S 2 Register | & S/F = | & | Temperature.| Metals observed. EEE g*Eland Bar| &°|2 £73] & ane 3 5 S\4 am) 5 2h a Re a |e = ae P ° 2 - ° 7 |Platinum}0152) 5 49 |0508/2005+465|2070|Copper, fusing point.| 2548 II 8 |Platinum|-0159| 6 10 |-0537/2026+65/2091| Gold, fusing point. | 2590 Iil Tron |'0229} 9 2 |:0787|/2061+65/2126) ditto ditto 12 |Platinum|]‘0116} 4 10 |-0363/1877-+65,1942) Silver, fusing point. | 2233 13 et 0203) 7 24 |-0645/1906+65/1971 ditto ditto 14 Pieaean 0116) 6 16 |'0546|2824+-65|2889) Iron, fusing point. | 3479 17 i 0203] 2 45 |0239).708+-65| 773) Zinc, fusing point. | 648 18 ips 0245) 4 7 |0358) 876465) 941] Zinc, inflaming. The most remarkable fact displayed by the preceding com- parison is the beautiful accordance of the results obtained from two metals whose expansions are so different as those of platinum and iron. The temperature indicated by the latter exceeds that by the former in the instance of the fusing point of gold 35°, and in that of silver only 29°; and this excess is in accordance with the conclusion of MM. Dulong and Petit, exhibited in Table II., that the expansion of iron increases in the higher degrees in a greater proportion than that of platinum. The discrepancy between the temperatures derived from the observations with my first pyrometer and the present are considerable, but may be sufficiently accounted for by the dif- ferences in the circumstances of the experiments, without im- puting inaccuracy to the instrument. In the paper to which I have before alluded, I stated that “ I did not offer the re- sults as positive and accurate determinations of the different degrees, but only as nearer approximations than any that had yet been furnished from actual observation. The only method which I had it in my power to adopt for the purpose, I do not consider to be susceptible of absolute accuracy. he ar- rangement made consisted of a muffle of black-lead placed in an excellent draught-furnace. This muffle was furnished with a door, through a round hole in which the stem of the pyro- meter was passed up to the shoulder. Another door, which ‘could be stopped at pleasure, admitted a full view of the in- terior, $52 Mr. Daniell on a New Register-Pyrometer, terior. The metal to be tried was placed in a small black- lead receptacle, of the same thickness as the pyrometer tube, in the middle of the muffle. Now it is evident that the pyro- meter so situated would indicate the mean heat of the whole of the muffle; which heat might, and did, vary in different parts. Of two pieces of silver of the same size placed within an inch of each other, one fused some time before the other.” I also suggested that “* means might be contrived to surround the instrument with the metal in a state of fusion; but that it required particular opportunities, which it was to be hoped that those would avail themselves of who had them in their ower.” That the latter method is the only one which can admit of accuracy will be evident from a few reflections. Setting aside the inequality of the heat of different parts of the same heated muffle, which however is a consideration of the utmost importance, it is obvious that its temperature must consider- ably exceed the true melting point of the metal exposed to its influence. Just as a piece of ice would never melt in a cham- ber of the temperature of 32°, but would require a consider- ably higher heat in proportion to its mass to supply the ca- loric which becomes latent during the process,—a mass of iron would exhibit but little signs of liquidity till subjected to a heat much above its true point of fusion. When once ina liquid state, beth would rapidly rise to the temperature of the medium to which they were exposed. When metals are melted for the purposes of the arts, they of course require to be heated very far beyond their fusing points, that they may flow into the minutest fissures [hollows] of the moulds in which they are cast, notwithstanding the cooling influences to which they are suddenly exposed. In some of the finer castings of brass, the perfection of the work depends upon the intensity to which the metal is heated, which in some cases is urged even beyond the melting point of iron. With a fire whose power in all cases must so greatly exceed the temperature required, it is necessary to bestow great care in supplying the metal gra- dually, as we have before described; as it is inconceivable with what rapidity it rises after the solid pieces are completely dissolved. Evidence of the same fact may be derived from the experiments of MM. Clement and Desormes, which I have before quoted. They calculated the heat of melted iron at 3988°, and of iron just on the point of melting at 3164°,—a difference of 800°. And it is clear from the circumstances of the experiment, that the former must have considerably ex- ceeded the true melting point, or it never could have been transported in a liquid state from the crucible to the appa- ratus for Measuring the Expansions of Solids, &c. 353 ratus in which the water was heated or the ice melted. It is probable that the process which they employed, of the calori- meter, was not susceptible of great accuracy; but the discre- pancy of the results from those which I obtained from the metal in analogous circumstances is not great. Iron just melting ........-. 3164° by the former 2889 by pyrometer —— 275° difference. Iron melted at a high heat 3988 by the former 3479 by pyrometer —— 509° difference. A similar excess also appears in their determination of the heat of melted copper, and obviously admits of the same ex- planation. After performing these experiments upon the melting points of the metals, I was desirous of ascertaining the effects of the most intense heat which it was possible to produce in a fur- nace; and to measure the utmost limits of expansion in a platinum bar. For this purpose I made use of an excellent wind-furnace in the Royal Institution, in which upon former occasions hob-nails had been completely fused into a button. Exp. 19.—The register I, which had not been the least in- jured by the previous experiments, was fitted with a new bar of platinum which had been drawn as a wire, was ;°;ths of an inch in diameter and very ductile. The iron bar was also adjusted to a new register, and both were placed upright in a well luted crucible. About half an inch of powdered charcoal was strewed upon the bottom to prevent any adhesion; and two soft iron nails, and a piece of unglazed Wedgwood’s porcelain, were thrown in for the purpose of affording some indication of the degree of heat attained. The crucible was then set in the furnace, another smaller crucible inverted upon it, covered with coke, and the heat urged to the utmost for two hours. The fire was suffered to burn out, and the crucible with its contents removed for examination. It was sound, but the luting had been completely fused. The nails were found melted into two complete buttons, and the porcelain was partially fused upon the surface. The register I. appeared to be uninjured, but the platinum ring and wedge were loose, evidently from a contraction hav- ing taken place in the substance of the black-lead. This was no doubt owing to the heat having exceeded that at which it had been originally baked. ‘The amount of expansion conse- oagneth could not be measured. The platinum ring, both of this and the other register, exhibited a remarkable change of texture; they had become very rough and crystalline, and N.S. Vol. 10. No. 59, Nov. 1831. 22 were $54: Mr. Daniell on a new Register-Pyrometer, were perfectly brittle, breaking easily between the fingers. The platinum bar also, which there was some difficulty in removing from the cavity, presented a very extraordinary ap- pearance. It was apparently embossed with crystals, and was evidently larger at the lower end than at the top: it was also something contracted in length. Upon examination with a lens no regular facets could be detected, but it had the appear- ance of a bar constructed of plates of native platinum loosely welded together. The register which contained the iron bar was considerably bent, and had several transverse clefts in its substance, owing possibly to its having become inclined in the crucible. Partial fusion had taken place upon the surface of the bar, which had run down and formed a knot at its lower extremity. About an inch of the same end was found to have been converted into steel, but all the rest retained the character of soft iron. Exp. 20.—I repeated the last experiment with the same platinum bar in the register I. The arrangement was pre- cisely the same, with the exception of the second register with the iron bar, and the fire was maintained with equal intensity for an equal time. The iron nails were found perfectly melted, and the porce- Jain superficially fused as before. ‘The ring and wedge, how~ ever, were fixed in their places, and the index undisturbed, but the measure was unfortunately lost from an accident. The texture of the platinum ring was changed, as in the pre- vious experiment, and the bar tightly fixed in the cavity. By frequent gentle concussions it was removed without injury to the black-lead, which had some slight marks of fusion upon its surface, but was in a perfectly good condition. The bar was in a still rougher state than before, highly crystalline, and exhibited several large longitudinal clefts in its substance. It was found, by measurement with callipers, to be ,1,th of an inch larger in diameter at its lower than at its upper end, and seemed to be approaching a state of complete disintegra- tion. It was, however, perfectly hard and inflexible. My intention was to have again exposed it for several hours to the same degree of heat, with the expectation that the disin- tegration would have been complete, and that it would actually have fallen in pieces during the operation: in the mean time I chanced to make it red hot upon a common charcoal fire ; and upon attempting to lay hold of it with ‘a pair of tongs the two ends dropped off, and I only withdrew the small portion which I had grasped, and which was flattened and fractured by even this slight compression. ‘The two ends were after- wards carefully, but with difficulty, raised from the fire, fin when for Measuring the Expansions of Solids, &c. 355 when cold were perfectly hard and inflexible. I again heated a portion of the bar to a dull red, and it crumbled to powder from a slight blow with a hammer. Exp. 21. — It being a point of the greatest interest to ascertain the maximum of expansion which took place in the platinum previous to this remarkable change of structure, I adjusted the original platinum bar, with which the greater part of my experiments had been made, and which presented a perfectly smooth surface, and was very soft and ductile, in the register I. A crucible was placed in the same wind-furnace, containing only a little charcoal powder, with the iron nail and fragments of porcelain as test pieces. The fire was urged to the utmost; and when it had been continued two hours the cover was removed, and the register, previously made red hot, was carefully introduced, the cover replaced, and the ignited fuel heaped upon it. At the expiration of a quarter of an hour it was lifted out.and cautiously cooled. An ex- cellent measure was obtained, and the arc determined to be 7° 24’ = expansion ‘0645. The test pieces were found in the same state as in the pre- vious experiments. The platinum bar was loose in the cavity, and had not altered its form; but its surface had assumed a slightly crystalline texture, and it had become very hard and inflexible. The expansion registered would, upon the hypothesis be- fore assumed of equal amounts of expansion denoting equal increments of temperature, indicate a heat of 3336°; or, add- ing the initial temperature 65°, =3401°. Butit must be remem- bered that this is probably rather the temperature at which the change in the structure of the platinum took place, than the utmost heat of the furnace. ‘The latter may possibly ex- ceed the degree at which the expansion of the metal ceases, and at which its particles evidently form a new arrangement ; but this point cannot at present be determined. The coinci- dence of this result with that obtained in the former series of my experiments, is very remarkable. ‘The temperature at which I obtained the fusion of cast iron at that time was cal- culated at 3479°, and was produced by the utmost energy of an excellent wind-furnace; and this, it will be observed, is within 80° of the present maximum. Exp. 22.—Being desirous of ascertaining whether the re- gister and platinum bar had undergone any change in their rates of expansion by the intense heat to which they had been exposed, I again adjusted the latter in the register I, which had now been once immersed in melted iron, and three times subjected to the action of the wind-furnace, and boiled thena 2Z2 for 356 Mr. Daniell on a New Register-Pyrometer. for ten minutes in mercury. ‘The arc measured was 1°19/ = expansion ‘01148: the difference of 1/ may safely be ascribed to the uncertainty of the reading. The temperatures thus determined will require correction, if we adopt the conclusion derived from the experiments of MM. Dulong and Petit,—that the dilatability of solids, re- ferred to an air-thermometer, increases with the heat. The amount of this correction will be as the rate of increase; and according to those gentlemen is 11°6 of the centigrade ther- mometer, or 20°°8 Fahr. from $2° to 572°, or the calculated temperature is to the true as -00091827 : 00088420. Sup- posing the increase of dilatability to continue the same for equal intervals of temperature, which however has not yet been proved, the following Table will exhibit the corrected temperatures derived from the preceding experiments with the platinum bar. . Taste XI. Observed. Corrected. Melting point of silver .........ccsecseesvee 1942 ... 1873* — COPPET ..rocscecccceevssee 2070 ... 1996 = MOMS ads batnecndemdovassun/ S091) sony OLE | HEOR isan cxessndduceecseess 2E8Q: 040) 2786 Temperature of the maxi- : platinum... $401 ... 3280 mum of expansion of... ; If we reason in the same way from the increase of the dila- tation of iron, as laid down by the same authors, the discre- pancy between the temperature derived from the platinum and iron is very considerable; the melting point of silver coming out 1682°, and that of gold 1815° by the latter: but I con- ceive that the determination of this point in the iron is open to. objections which do not apply to the platinum, and my suspicion is confirmed by the anomalous expansion of the iron exhibited in Tables V. and IX., and to which I shall recur upon a future occasion. ar The general utility of the pyrometer, however, will in no way be affected by any uncertainty in these corrections. The indications which it is capable of affording will always be positive determinations, which it will be easy to modify by calculation, as our theories may improve. For all common purposes (and I must own that [ look forward with hope that this instrument will prove eminently useful in many of the common processes of the arts) it will not even be necessary to note the expansion indicated by the arc measured; but each minute of the degree may at once be valued in degrees of * Mr. Prinsep, from a laborious series of experiments upon the expan- sion of air confined in a bulb of gold, determines the melting point of silver to be 1830°,—Phil, Trans. 1828, p. 94. : Fahrenheit’s ne —_ Mr. W. S. MacLeay zn reply to Ruralis. 357 Fahrenheit’s scale at the time of taking its rate of expansion by the boiling of mercury: and a Table of such values should be furnished for each register by the maker of the instrument. The following, for example, would be the proper Tab ef or register I, which has been so often referred to, in which the arc for the boiling of mercury or 600° (without adding the initial temperature) was 1° 20!. TasLe XII. =) Expansion. Temperature. oy; Expansion. Temperature. 1 0c 008 (27450 0 1ON=") 00145 ash 75 0.30: = :00486 = 225 0) -Su==):0007 201237 0 20 = :00290 = 150 0 §2 = 00029 = 15 0 15 = :00218 = 112 | Oo 1 = :00014 = 7°5 With such a Table an intelligent workman could employ the instrument without any material error. Those who might object to the expense of a platinum bar may substitute an iron one for ordinary purposes, and the cost of the black-lead re- gister can never be an obstacle to its general use. Other sub- stances might obviously be employed in its construction, but the facility with which it can be worked, its small expansion, its infusibility, and the impunity with which it bears the most sudden changes of temperature (as when red hot it may even be quenched in water without injury), will probably always give the black-lead ware the preference. The only precaution to be taken with it is to expose it previously, out of the con- tact of air, to a heat at least as great as that in which it is in- tended to employ the instrument. XLV. Correction of a Quotation in a Paper “ On the Impedi- ments to the Study of Natural History,” published in the Phil. Mag. and Annals for May, 1831. By W.S. MacLeay, Esq., M.A. F.L.S. §c. To Richard Taylor, Esq. &c. &c. Dear Sir, Your Correspondent who signs himself ‘ Ruralis,” has in the Phil. Mag. and Annals for May last given us a me- lancholy picture of ‘ the Impediments to the Study of Natural History.” In his list of them, however, I think he has omitted to make mention of that impediment which I fear has most thwarted his own progress in the science. But this is of the slightest consequence ; and indeed were it all, I would not have troubled you on the present occasion. But I must beg of your Correspondent that in future, when he does me the honour to quote from any work of mine, he will cite the exact words, and not make me the author of downright nonsense. I have nowhere said that “the discovery of a natural system, being the 358 Mr. Henwood’s Notice of a Geological Survey the work ofan all-wise, all-powerful Deity, can only be hoped for from a cautious process of inductive and analogical rea- soning.” And yet this stuff is put within commas, as if I had written it. Allow me to say also, in reply to the editorial note affixed to this singular quotation, that I have nowhere desig- nated “* any attempt to unravel” the Plan of the Creation, as the Natural System. By the way of conclusion, I may remark that your Corre- spondent is happily not in any way obliged to trouble his brains with the “ repulsive and inscrutable” innovations of “ revolutionary Zoologists.” And therefore advising and hoping ~ that in future he will stick close to ‘* the familiar and popular Entomology” which amused him ‘in those happy days long gone by,” I remain, my dear Sir, yours &c. W.S. MacLeay. XLVI. Notice of a Geological Survey of the Mines of Corn- wall; with a Programme of an intended Arrangement of the leading Details of the Metalliferous Veins, §c. By W. Jory Henwoon, £.G.8. To Richard Taylor, Esq. &c. §c. Dear Sir, ib the year 1829, at the desire of R. W. Fox, Esq. of Fal- mouth, and C. Fox, Esq. of this place, who also defrayed the expenses incidental thereon, I made an examination of the leading geological features of several of the mines in Corn- wall; and a short residence in the neighbourhood of Tavi- stock, in the summer of 1830, afforded me an opportunity of extending my investigations to some of the mines there. The results of these inquiries were communicated to the Royal Geological Society of Cornwall, in October last, and were to have been honoured with a place in the forth-coming fourth volume of their Transactions. But in consequence of the liberal aid and encouragement of most of the noblemen and gentlemen resident in, and con- nected with, this county, as well as of several distinguished sci- entific men elsewhere, I have commenced a survey of all the mines in Cornwall; and I have now examined all those west of Redruth. Besides noticing the geological relations of the veins, (*lodes”, ‘cross courses,” “ flucans,” “ slides,” and ‘elvan courses”,) and of the rocks they traverse, I ascertain the temperature of every stream I find running or jetting out of the unbroken rock, and make experiments on the electro- magnetic properties of the veins*. After having gone through all the mines, I shall endeavour to arrange and classify my observations; and the Council of * Fox, Phil. Trans, 1850, part ii. the of the Mines of Cornwall. 359 the Cornwall Geological Society have kindly permitted me to withdraw the before-mentioned paper, in order to its being incorporated with the rest. When completed, I intend leaving my work at the disposal of the noblemen and gentlemen whose liberal assistance has mainly contributed to its completion. But before I proceed, I am anxious to submit to your geolo- gical readers a Programme of the manner in which I had intended arranging the details, and I shall be exceedingly obliged to any of them who will trouble themselves to point out the defects, and to suggest improvements. ‘Those who are unacquainted with the interior of a mine will doubtless notice in this outline many points of interest not described ; the contact of veins at various depths, unseen ; and a general scantiness of information. I may observe, that the excavations are not always extended to the points at which interesting phenomena may be expected; operations may have been suspended, and the sides of the excavations either fallen to- gether, been filled with water, or with foul air which ex- tinguishes candles; the vein may have been entirely worked away, and in most cases the sides are after a short period inyested with a crust of ferruginous matter, which rapidly accumulates. In a few instances I have not deemed it pru- dent to expose myself to falling rubbish, on decayed wood, or on rotten ladders. None but those who have experienced the like can fully feel the many vexatious disappointments I have had to suffer, in meeting an immovable barrier sometimes but a few fathoms, or even a few feet, from my object; after having crept hundreds of fathoms on all-four, and often on the belly, through mud and water, often beneath tottering rocks. ‘These inconveniences, to which geologists who confine themselves to the neighbourhood of the surface are not exposed, have been every-day occurrences with me; and I venture to hope that they may with some propriety be offered as an apology for the deficiencies which my outline will at every step present. I remain, &c. Perran Wharf, near Truro, Ww. J. Heywoop. August 11, 183]. PROGRAMME. Cookskitchen Mine, parish of Illogan, near Redruth, is situated on the northern side of the granitic range, of which the nearest hill (Carnarthen Cairn) is only about half a mile distant, and its acclivity is at an angle of about 7°. The phznomena of the interlying of granite and slate which here occur have been often referred to, having for a considerable time been supposed to be peculiar to this mine. ‘The eastern part of its surface is nearly horizontal; but towards the west it rapidly declines. Lode. Direction in Dip in Depth and Composition or Contents, | Slate. | Granite.} Slate. | Granite. i Small western? |........ 8°W.of NJ ....... 119f™*. Veins of radiated quartz, with Cross course i friable granite intenposeds ic)... +... (Cross Veltils sem cee rs tk HUBUE-IN.| sreratetereats 119 £™’. Two veins of radiated quartz, with} Titde “aks a vein of friable granite between them . = a2 ross t 35° E lof N. 50: | 33 f™° (In slate.) Angular masses of slate} with a vein of radiated quartz on E, dg | 87£™*. Friable granite mixed with radiated] quartz; a vein of granitic clay on W. sid ...|Surface to 10 fathoms ........ “to 10 fathoms to 40..... denatehetliatarels © aie oe | South lode .... 40 fathoms to 49....... SSE GN nis si Pei 49: Tathomsn jas: s.sevalate aoe pleiyin ein |=\<(ofaic’aiata 54f™*, Brown iron ochre, slate, quartz, iron, and yellow copper pyrites, “ walls" smooth! i 7G ese ile Mitotic o> Stee a 95 £™°. Quartz and slate with a little cop+} per pyrites's cic. Uhvcausbeew. «sa =) eee Los ditto (‘¢ walls” smooth)! | aI | | 2° N.jof W. 119f™*, W. of Cross vein, yellow sulphuret of cOpper .c..sihc5... 6. ee | E. of ditto gray sulphuret OF COPPET: soc cyesicre = 'ae) nt aa E. of West Cross course, yellow} sulphuret of copper with chlo-} rite and friable granite... ... | 5° S.lof W. Onan Me oer, 54£™°, Brown iron ore, quartz, and yellow} copper pyrites. 20.2.0) 0... clan 72£™*. Friable granite and iron pyrites . 103 f™,. Red iron ore and crystalline quartz, a vein of granitic clay on N. side | : 112f™*. Red iron ore and quartz...... | , of W. GSe. He 33f™*. Gray sulphuret of copper, brown] — || Toy’s lode..... Great lode.... 10° S. iron ochre, slate and quartz; a vein o slaty. Clay. Ge.c/% aeetatensrataie, re 73 can 67 fathoms* =f! 2.0. 4.10 tee 105 f™*. Friable granite ..........--. | Middle Engine 18° N.lof W. ..|93£™*, Quartz, chlorite, and yellow cop | lode? 2 Seat } per pyrites, two veins...........-+.+4] BT es oe cw ce. oo 5 epee te neat eae 87f™*, Friable granite and gray sulphuret of copper } ja, / jodi gneyiniaueet eerie | Hardshaft lode*| 18° S.jof W. | N. 58° |........ 31£™*, Slate, crystalline quartz and ye | low copper pyrites ........-++-+405 \ 54 £™*, Slate, a vein of slaty clay on N. side | Sawpit lode ...|2°N.ofW.)....... perpendijcular . {54 f™*. Slate, red iron ore, and felspar ¢' ‘| Lode N. of 2 |4°N.of W.|.... ecoalt Nev OD ltt aararereet 54f£™, Slate, brown iron ochre and iron Sawpit lode§ pyrites Se eivs a UAH cietewe = «ole ° oa bi } 2 4 * The out-crop of these “ lodes”’ (if there be any) is not seen. South Lode. Great Lode. Direction of Direction of Dip of Strati- eg fication or Appearance of Granite, and Eeaeeiand ce Heave, and | 2 . Sw | Cleavage of | its Dipat Junction, &c.&c.) if to the | 23 | if to the | [% a. Slate greater or | #5] greater or | Gy m0 = smaller | = smaller | 55 Angle. Angle. < Beietesn(e DOOT OE RIE Shs Ano SO ORONO Panton coe Oy iN TA Ag Bratetewrats Sere o foe meietemtehteitcalscles celal Retg tt, Gialeaoe Deep blue, dip} At this spot there is also gra-| _ N.W. 34° nite, which is traversed by many veins ofa fine-grained dark gray schorl rock . Saint latol aiae .. |Near the cross course soft, and mica more abundant than at alittle distance... . ain ie ee .. |Coarse- grained, soft, and .|Deep blue, dip| tinged red: dip of junction N. 50°. 65°} S. 22°, -eeeeee+....|Fine-grained with imbedded crystals of schorl. N. side slate, |S. side of vein granite, Pap a (ae Rskf™ SA| 39° of crystals of felspar & mica 7 Sw 5° _ a) n & 35 88 wn z3 ae 23 dip N.W.34° 2 § dip S. 12° S58 2 ft. o 2 =e : ~ AVE ( clnlo'ain'~ ¢ from his.— Ann. de Chim. et de Phys. vol. xliv. p. 27. Hydrogen being unity, Dr. Thomson's number for barytes will be 76 instead of 78 as he formerly determined; his present analysis nearly coincides with that of Berzelius. The following are the results of the three chemists mentioned. Dr. Thomson. De Saussure. Berzelius. Acid. dbeke 34°49 34:48 34°31 Base ssseue 65°51 G5:52 65°59 100:00 100-00 100-00 Epir. ON THE OXICHLORATES. BY M. SERULLAS. M. Serullas concludes from his experiments, Ist. That oxichloric (perchloric) acid forms with potash a very slightly soluble salt, re- quiring 65 times its weight of water at the temperature of 60° Fahr. 2nd, That soda forms with the same acid a very deliquescent salt, which is consequently very soluble in water, and even in the strongest alcohol. 3rd. That properties so opposite and decided, afford a method of separating potash and soda when in solution ; the latter yielding, as has been already stated, an oxichlorate very soluble in concentrated alcohol, and the former an oxichlorate which is absolutely insoluble in it. 4th. That in the same experiment any acid may be separated from the potash which is combined with it; the acid being always set at liberty by the oxichloric acid. 5th. That the employment of oxichlorate of silver for the mixtures of the chlorides of sodium and potassium, and the employment of oxichlorate of barytes for the mixture of the sulphates of these two bases, renders it, by the intervention of alcohol, extremely easy to separate all the elements completely. Oxichlorate of potash is composed of 1 Be OTe WE (RRNA AERC inp od 34°275 PIAS OC yerie eects es Actes sheroue vein: 65.725 100:000 As bitartrate of potash is soluble in 60 parts of water, and oxichlo- rate requires 65, oxichloric acid when added to a saturated solution of the bitartrate occasions slight precipitation. Oxichlorate of barytes is deliquescent, very soluble in water and in alcohol; the solution when evaporated in a stove yields long prismatic crystals ; paper impregnated with the solution burns with a fine green flame. It is composed of AGIA) Sa hee Tos bs 54°423 Base) aseue IBAA dt RHEL aie 45:577 100:000 When Intelligence and Miscellaneous Articles. 395 When heated to redness in a tube it loses about 38-102 per cent, or seven atoms of oxygen from the acid, and one atom from the base. Oxichlorate of Strontia—When the solution is evaporated to the consistence of a syrup, it assumes on cooling a mass of a crystalline appearance, which readily attracts moisture from the air. It vives a fine purple to flame. Oxichlorate of Lime.—This salt is deliquescent ; when evaporated to the consistence of a syrup it solidifies into a crystalline mass. It is soluble in alcohol, and burns with a reddish flame. Oxichlorate of Magnesia —Deliquescent, soluble in alcohol, and crystallizes in long prisms ; oxichlorate of alumina reddens litmus paper, although excess of gelatinous alumina has been used in pre- paring it ; it does not crystallize, and is soluble in alcohol. Orichlorate of Lithia.—It is prepared like the preceding salts by the direct union of the acid with the base. It crystallizes perfectly in long transparent needles, which are deliquescent and soluble in alcohol. Oxichlorate of Ammonia.—This salt is neutral ; but like ammoniacal salts in general it is rendered acid by evaporation ; it crystallizes in very fine transparent rectangular prisms, bevelled at the extremities. It is soluble in five times its weight of water, and slightly so in alco- hol. If concentrated oxichloric acid be poured into a strong solution of this salt, a precipitate is formed which might be supposed to be a supersalt ; but it is neutral, the acid having seized a portion of the water which held the salt in solution. Oxichlorate of Zinc——Obtained by the double decomposition of zinc and oxichlorate of barytes,—it crystallizes in prismatic groups : it is soluble in alcohol, and is deliquescent. Oxichlorate of Manganese.—Oxichloric acid does not act upon peroxide of manganese. The oxichlorate of the protoxide is obtained by the double decomposition of oxichlorate of barytes and protosul- phate of manganese. It crystallizes in long needles, is very deli- quescent, and is soluble in alcohol. Oxichlorate of Iron.—Prepared by the mutual decomposition of oxichlorate of barytes and protosulphate of iron : it crystallizes in long colourless needles, which remain long exposed to the air without alteration, but eventually they undergo a change analogous to that of the protosulphate of iron. By evaporation a portion is converted into peroxichlorate, some oxide being precipitated ; it hardly melts upon red hot coals. Oxichlorate of Copper.—Prepared by heating together peroxide of copper and oxichloric acid. By evaporation in a stove it gives bulky blue crystals which have no well determined form, This salt reddens litmus, deliquesces, and is soluble in alcohol. Paper im- pregnated with the aqueous solution and dried, fulminates vpon burning coals with jets of fire of a very fine blue ; when it burns with flame it is green. Oxichlorate of Lead.—Prepared by heating protoxide of lead in water and oxichloric acid ; it crystallizes in small prisms united intoa mass ; is soluble in about its own ee of water, does not deliquesce ; 3E2 its 396 Intelligence and Miscellaneous Articles. its taste is slightly sweet and very acerb ; very astringent, and much more so than acetate of lead. Protoxichlorate of Mercury.—Dissolve fresh precipitated protoxide in the acid: by evaporation, small masses of prismatic crystals are obtained radiating from a common centre; it is not deliquescent ; precipitated black by ammonia. Peroxichlorate of Mercury.—Heat the peroxide in fthe facid: it reddens litmus paper whatever may have been the excess of peroxide employed. The filtered liquor strongly concentrated and put into a stove of 88° Fahr. gave very distinct colourless transparent crystals, having the form of right prisms which are so low as to be tabular ;— at other times, and probably dependent upon the degree of concen- tration, it gave long confused prismatic crystals ; but they both ex- isted only for a short time. They dissolved in the air even in the stove. This salt is precipitated of a brick-red by potash, and white by ammonia. In alcohol it forms a white flocculent precipitate, which upon aggregating becomes reddish ; it is peroxide of mercury. The solution after filtration and concentration by evaporation, is precipi- tated of a reddish black by potash, which indicates a mixture of pro- toxichlorate and peroxichlorate ; when evaporated in a stove it yields, in the middle of the uncrystallizable liquor, small slender crystals, which fulminate on hot coals, and are precipitated black by ammonia. The crystals of peroxichlorate of mercury might perhaps be pre- served by puttingthe hot solution, properly concentrated, into a small bottle, and carefully corking it as soon as the crystals are formed. Oxichlorate of Silver—Prepared by dissolving the oxide in the acid. The solution becomes brown by exposure to the light. It did not crystallize in a stove. When dried it is a white powder, and when exposed to the air it quickly attracts moisture ; concentrated alcohol dissolves it; when dry, and strongly heated in a tube, it fuses, and concretes into a mass on cooling ; a small portion is transformed into chloride ; it is immediately decomposed at a heat a little below redness ; paper moistened with the solution, then dried at a gentle heat, detonates violently when the temperature is raised to about 400° Fahr. ;—this was proved by placing parcels of the impregnated paper upon mercury heated gradually, with a thermometer placed in it. All the oxichlorates fuse more or less vividly upon heated coals ; they generally assume a prismatic form. All that have been above described are deliquescent, except the oxichlorate of lead, protoxi- chlorate of mercury, and the oxichlorate of ammonia. In order to obtain crystals of the deliquescent oxichlorates readily, they must be dried, dissolved in strong alcohol, and after filtration evaporated in a stove. One of the characters which distinguishes the chlorates from the oxichlorates, is that the first, as well known, become of a deep yellow colour by the action of concentrated sulphuric or muriatic acid, while the oxichlorates submitted to the same test remain colourless.— Ann. de Chim, et de Phys. Mars 1831. LUNAR Meteorological Observations for September 1831. 397 LUNAR OCCULTATIONS FOR NOVEMBER. Occultations of Planets and Jjixed Stars by the Moon, in November 1831. Computed for Greenwich, by Taomas HENDERSON, Esq. ; and circulated by the Astronomical Society. ——— Stars’ 1831.| Names, Nov. 8 2 Sagittarii |16 Sagittarii 12 45 Capricor. 1633 Ceti 21/E? Orionis,. 23.2 Cancri..... 24/*° Cancri... 25 Regulus.... 26\Saturn......| ... aa Virginis . SHAHDD | Magnitude. 3 Immersions. Ss Oo 36 Angle from & Z \Sidereal| Mean ; |Sidereal a time. |solartime|¢}| 8 | time. Z ae| S bePm| hime oa Dy a 2098] 20 40 5 31 66| 89/21 49 2099}21 5 5 57 | 164} 190/21 28 2576] 1 20 9 54} 95) 127|Under 125} 3 8] 11 27 | 160) 184 3 56 777| 418] 1217] 62] 34] 517 998} 0-58 8 50 58} 21] 1 43 1122) 3 8] 10 56 9/329) 3 23 1209| Under Jhorizon | ...| ...|*2 54 -- | 8 55] 16 33} 40] 15}10 3 1551] Under jhorizon | ...| ...| 8 21 Emersions. Angle from Mean |- . solar time. F zg Z, Pe 6 19 | 200 horizon.| *... 12 15 | 250 13 16 | 310 9 35 | 298 WAT 337 10 37 | 254 17 Al | 272 15 48 | 220 SSS * At emersion, ) and star rising above horizon. METEOROLOGICAL OBSERVATIONS FOR SEPTEMBER 1831. Gosport :—Numerical Results for the Month. Barom. Max. 30-302. Sept.16. Wind N.E.—Min. 29-295. Sept.30. WindS.E. Range of the mercury 1-007. Mean barometrical pressure for the month Spaces described by the rising and falling of the mercury... Greatest variation in 24 hours 0:316.—Number of changes 13. Therm. Max. 71°. Sept. 5. Wind S.W.—Min. 45°. Sept.2. Wind N.W. Range 26°.—Mean temp. of exter. air 59°16. For 31 days with © innp60-05 Max. var. in 24 hours 19°-00.— Mean temp. of spring-water at 8 A.M. 54-01 Greatest humidity of the atmosphere, in the evening of the 27th...... 96° Greatest dryness of the atmosphere, in the afternoon of the 3rd...... 48-0 SBME VOMEIIOER, aavor er denis cacrs cells cates nets access2telerceicheanacebaes 48-0 Mean at 2 P.M. 62°-6.—Mean at 8 A.M. 70°3.— Mean at 8 P.M. 77:8 of three observations each day at 8, 2, and 8 o’clock ...... meet ides Evaporation for the month 2-40 inches. Rain in the pluviameter near the ground 3-711 inches. Prevailing wind, South-west. Summary of the Weather. A clear sky, 3; fine, with various modifications of clouds, 16}; an over- cast sky without rain, 54; rain, 5.—Total 30 days. Clouds. Cirrus, Cirrocumulus, Cirrostratus, Stratus. Cumulus, Cumulostr. Nimbus. 15 2 0 24 23 17 Scale 398 Meteorological Observations for September 1831. Scale of the prevailing Winds, Nap BEE, EB. See ase: S.-W. OW sr NEW Days. 3 5} Le Seno Sra 2 63 30 | General Observations. — The weather this month has been alternately wet and dry, and the nights were generally warm. The Ist was a cold day, with a gale from the North, and heavy rain nearly an inch in depth, which considerably lessened the temperature of the ground. Distant thunder occurred in the afternoon of the 2nd; but the night being clear, with a North-west wind, the first hoar frost ap- peared in the grass fields early in the morning of the 3rd. On the 7th and 8th, distant thunder occurred, and the lightning was vivid at mid- night of the latter day. In the evening of the 12th a faint aurora borealis appeared from half-past 8 till10 P.M. Early in the merning of the 19th a great number of swallows assembled, and suddenly departed for a warmer climate: they remained here this year only twenty-two weeks. There were a few flashes of sheet lightning in the evening of the 26th. It lightened in the night of the 27th from 7 P.M. till midnight, when a change of wind to the North-east brought on a thunder-shower. Heavy showers of rain and hail in the afternoon of the 28th were succeeded by vivid lightning, from 5 till 10 P.M. Strong forked lightning, with thunder and rain, also occurred in the evening of the 30th from 6 till 9 P.M. The mean temperature of this month is nearly a degree lower than the mean of September for many years past. The atmospheric and meteoric phznomena that have come within our observations this month, are, eleven meteors, one rainbow, one aurora borealis, lightning and thunder on five days ; and two gales of wind, namely, one from the North, the other from the South-east. REMARKS, London.—Sept. 1. Very heavy rain. 2. Fine, with showers. _ 3, 4. Fine. 5. Rain in the morning: cloudy. 6. Rain: clear at night. 7. Fine: heavy rainatnoon: clear. §.Fine. 9.Rain. 10.Cloudy: fine. 11, 12, Over- cast- 13—16. Foggy in the morning: fine. 17.Fine. 18. Slight haze: fine. 19,20.Fine. 21.Rain: fine. 22. Fogey: very fine. 23, 24. Fine. 25. Cloudy: rain at night. 26. Rain. 27. Hazy and drizzly: fine. 28. Slight fog: heavy rain and thunder at night. 29. Fine. 30, Cloudy and warm: at night much thunder and lightning, with heavy rain. Penzance.—Sept. 1. Rain. 2. Showers: clear. 3.Clear. 4. Rain. 5. Fair: rain. 6.Fair: showers. 7, 8.Showers. 9,10,Clear. 11. Fair: rain. 12. Misty: fair. 13.Fair: misty. 14. Misty: fair. 15. Clear. 16.Fair. 17.Clear. 18.Clear: fair. 19.Showers. 20,Rain. 21.Clear: ashower. 22,23. Clear. 24. Fair. 25.Misty rain. 26, 27. Misty. 28. Fair. 29. Fair: showers. 30. Rain. Boston.—Sept. 1. Cloudy: rain a.m.and p.m. 2 Cloudy. 3, 4. Fine. 5. Cloudy: rain p.m, 6.Rain. 7,8, Fine: rainp.m. 9. Cloudy: rain a., 10. Fine. 11. Cloudy: rain early a.m. 12—17. Fine, 18. Foggy. 19. Cloudy. 20,Fine. 21.Cloudy. 22.Fine. 23. Fine: rain at night. 24.Fine, 25.Fine: rain at night. 26.Fine. 27. Cloudy: lightning at night. 28. Cloudy: rain, with thunder and lightning p.m. 29. Rain. 30, Cloudy. Meteoro- Lb | Lo | Le | of | F€.60 xe 06:2 |TTL-€ SZ0-F ace eee OES | SP | TZ Er Loni tam: oS Wye) “aS | "as | *s | 69] 09 | 69 | SG | €o | ZS a ees StS) eS OSH Ca NRO mln sulacon meg “MN "S| aS | ‘HN | OG} 89 | go | 2S | Fo | 6P “A | *mS | “MS) “S | 09} 8S | SQ | gS | 99 | SS *M | "MS | “MS *S 1G.89) PS | 99 | 9S | 99 | 1S “MN |] *MS |] °MS |] *S VG! LS wo | LV v9 €S UIy@9) * A "Mm | “MS cc! LV 19 SP 19 | Zé “AM } sm | ta 1 "S| OG) SS | #9 | OS | ZO | SP *M | tS | “MS | *AA | OC) LC | 79 | 6P | 19 | SS ues; *s |"MN | *S | 8S! LP | €9 | SG | Io | IP upeo) *s | "MS | “AS /G.8C) 1¢ | 99 | OG | £9 | CF “MN |*MN | “S| 'N 1G.0C] PS | Fo | 6P | £9 | LP eee eee eee eee eee "N "NU "MN “a 9g ZG c9 os 9 67 eee coe eee eee 0Z- ‘MN "MN N. “M LS as co ¥S ro LV eee eco eee eee eee “5 ‘aS “a—aS “Tr 09 67 co 8S co eV eee eee eee eee eee uu[eo Log “as To 4 09 9S Lo gS Lo €s ie) (0}005| | ome iam 0 CaP1n fear |e | Os 19| 9S | 89 | 89 | 99 | 6F LS eeeaees 2 Clllei epee or en NN) 8 ON SIG COSC RACONIPECAln go) sec 6I- |SZ0. |*** | VO. | °** | *AN /emn | ox | MN] OC] Qh | Eo | EC v9 | SP OT« |090- | """ | O€- | GT. jared) mn |*mN [*MN | ZS! 6F | 09 | 6P | to | 1S DI- lOvE. |SLS- |OL- | ** | “M [ems | mw [eas] Gc] 6h | £9 | 6P | 09 | LP 6I- JOrt. |SPS- | SE. | *** | “| ms} sm [ms G.9¢! 0G | Fo] 19 | 19 | Ib ZE- |GOO- |OOE- | IT. | OZ | “F | ‘s jrmn|*Ms| 9] €G | gq | og €9 | LV *** 009. O89: | Go. | *** | “S |sms}*ms} *s | 19] 69] 12] 1¢ G9 | 8S *** 1Ggo. |S9%- | go. | *** /mTBd) ms | -ms | *as] ZC} 19 | go | Sc | o9 | 19 erry eee aoe “** 1 08.0) “MN | san | MN [MAN 1C.PC} 6P £9 | of | Sg | gf OF-0|*** jovO- | SO. | °** |"MN|emn] Nx] °N 16.19] SP | zo] 0G 09 | PP “7 _|096.0,079-0, 08-1) _“"* |e} x | "an | "MN | 6S) OF | 09 | 2G | LS | ov we 2 ae ey 9 we Q ac] 3 eo “UL “xe “TH xe “UNA | “LayaWOULIOY T, “U0JSOT 1D TIFT A 1» XaaTD "spy hq fuopuorT nau £6-86 20.6% £1.6% LZ.6% 10.6% ZE.6% LV.66 0S.6G ZE.6% 1Z.6@ 12.62 BE.6z 9.46% F9.6z 99.6% C¢.6% ZS.6% LS.6% LS.6@ 9£.6% TE.6G L0.6@ G1-6@ 0£.6% 0€.6% £2.62 02.6% OP.6% Pe.6% 8o-6% G63-6% 685-62 189-62 £b8-60 GL6.6¢ GZ0.0€ 602.08 6ST1.0€ 888-62 C£8-6% 698-62 888-6z SLO-0€ F0Z-0€ 19z-0€ 161-08 SET-0€ 9ST-0€ 902-08 £P0-08 968-62 9F9-6% 00L-6% RLL.6c 006.6% 868-62 bP8-6z 076-62 £88-6z 8£8-6z Per-6z, 119-62 \ELL-6z £68-62 CP0-0€ 6L0-0€ GLZ-0€ 9£2-0€ CLO-0£ €L8-62 £16.62 986-62 801-08 PLt-0€ Z0£-0€ P1z-0£ ELI-o€ P2t-0€ 6£3:0€ G11-0€ 016-62 99L-6% \6SL-66 £18-62 [16-66 8£6-6% 918-62 986-62 696-62 LZ6-6% wy %g “UL | xen ‘wodsoy “yuodson, ‘souRzuag “uopuo’T uojsog NOSCKOH,T, O1-6G | 0£.:6% 00£-62 /gzS- oe PE-6z | 0S.6% 209-62 \ST9- 62 |6 09-62 | 04-62 g0L-6 ZLL-6z 8% > 06-62 | 06.6% 608-6 |806-6z |Lz 16-62 | 76-6 046-62 |€zo. 0€ [9% 16-62 | 76-62 26-62 |L£o. O€ |S% OL-O€ | ZI-0€ |LFI-0€ |0€z.-0€ | Fz OL-0£ | O1-0€ FZI-0F |Z8I-0€ £% 06:66 | 06.6% 226-62 | \810-0£ (2% OL-6% | 08.6% £08.62 298. -63|12 O OL-62 | $8-6% |6F8-6z |298.6z 0% OL-62 | 88-62 628-62 SI6- 6% 61 G8-63 | F0.0€ |£00-0€ \oZ1.0€ St 00-0€ | ZZ-0€ |Z61-0€ |ZhZ-0F Lt GE-0F | Z3-0€ 0SZ-0€ 0Lz. of 91 OT-0€ | ZI-0€ |SPI-0€ OL1-0€ SI 00-0€ | 00-0€ 621-08 |IF1-o€ Fr 80-0€ | O1-0£ |191-0€ 61z.0€ ET 01-0£ | OL-0£ |96T-0€ {8G0-0€ rat 06.63 | $0.08 |L16-6z [001-08 IT 06-62 | 06-62% |291-6z |LF6-6z 01 CL.6% | 08-63% |Z9S-62 SPL.6z 6 GL.6 | SL.6% iLE9: 62 |LOL-66 8 LL.6% 08-63 969-62 |z08.62 |L 08-62 | 28-62 |848-6z 406.669 © Z8-6% | Z8-6% (006. 6% |£%6-6% |S GL-62 | SL-63 |ZEL-6z |SSg-62 FP £6-62 | S6.6¢ cle. 6% |S6-63 £ 06-62 | 26-62 |ghg-6z | FE6-6z % 06:66 | 06-62 | LF8-6z |6F6-6¢ | t Lideg wy | xe | uy iw | re “xe |. —-— — Ifst “a0ueZUdgT “uopuo'T ‘qiuoyy “AgjaWIOINEyT = been! [6Z-6% Z0E-08 | O1-6z G-0F |00£-62 |022-0£ “YT pun yiodsoy w AINNAT “Aq ‘gouvmUag yunsiy9 yw hyjarog qounynoaysozy ayy fo uapangyy ay} yw “GAC 89 2pou suoryvasasqo poorSoposoop2py [yeexg yaaLT yun0g Uory poy ‘speuUy pu ouizesepy [worydosopiyd a43 JO OOLO 947 I? PELL Od feur spxeg uo reputed ayy jo sardog “Wa G 78 ‘YQUOP, Youa Jo skepsany, YIANOJ puL puod—aS a4} UO JU ALAINOG IVOINOTOOZ ANL AO TONACNOASAUUOY) NV FONGIOG JO ATLLINKOD wap prAey ‘Teoydeasoagn—wrd | ‘J aung ‘oneisy—'W'd | ede Suvauury—"wrd J ‘Ae quanyNoyIoH— TARY ‘UoNIWsuy “Y— Way ‘Ogady ‘eorsojooZ—"9G dy ‘gmyerawy Jo 20g “Y—Wa GZ “eg [dy ‘sotwenbuuy—Wrd | “LT “GT qeo1Sojoagn—'W'a ¢ “OT “qagq ‘eoTM0u0.ysy—'W'V TT ‘OE “AON ‘Aja1v0g [eAOY—'SAIUVSUTAINNY » aarg WUaSIY 1Z G@ ‘IT 86 ‘xP I G3 ‘6 98 ‘SI 13 Ct 83 ‘6 ral ‘wa G ‘Aepuoyq|* *[eorydeasoary *y ‘Ayn Jad.1}g -UOYVAH Sd aur me } GI ‘¢ L LI ‘s SI “PF 13 ‘2 pe ee ‘ma g ‘Avpanqeg|**** ++ oneIsy OT *d 4aaI)9-a]AeUAq|Y 8 ‘T GBS nl] S1'9 log‘ea‘9l6alrs ‘LT ‘OL ‘8} 28 ‘08 8: ‘w'a 2g ‘Avprig| ‘nqsuy pefoy ‘Spq uuy-s,upooury 8 ct rat 6 401 $1 6 ‘wd g ‘Avpiag|* *[eorwmouoysy “‘JoaI}g-uo yng 1 P x08 9 oS 6 c I *"N'’d S$ ‘Kepsany T, a ee [Bo1s0[007 *aSN0 Ff -Jas1aul0g SI 08 ‘9T ‘3 Il So ‘PT |6e'mZ1°ST'l] 8st FP vale ‘wa $g ‘psoupa |" * * *[eo1Sojoay ‘aot S,UNIEI “3S ; Jee aves ean anje1azT JO 08 ‘9 91S | 40s‘81 "| 18% a SIF 12 W'd ¢ *pSoupa A { i reachelens = ‘r1ydjapy $1 ‘9 os'eso 6S | oe SLIL FIRS ‘Le PL ‘2lessoel's'1/¢s ‘St ‘T1] 16 ‘PL ‘2 |08 ‘Es ‘9T ‘Go w'a Tl “psoUpeM|sity Jo Ajaio0g ‘Joalig-juesoy 1Z 61 °¢ CT al Vi alte: 02 ‘9 Tee. Vivi 0g ‘9 ‘w'd [ ‘Aepsony}* *[e.nynonA1O Fy ‘aaenbg-oyog 61 ‘¢ «V6 “T LL ‘S 08 ‘9 Te ‘d LL 08 ‘9 ‘wa g ‘Aepsony|**** +‘ uvouury *ASNOF]-JOSIBUOG ‘wa g ‘Avpsanyy}* ** sarenbyuuy ‘asno}{-JasrauUl0g ‘w'a 2g ‘Aepsanyy|******* efoy 16 ‘LZ 1e'FS'LLOL'S| 48% ‘SL ‘G |6o'So'eT's'T| SS ‘OL “6 ‘a|9S “GT “S1/ss “GT “8 I] FS “AT #06 ‘bo SLT *19qWL9AO NT Te ‘2 IeFe‘ZVolel si'¢ lestsotet's'l| so ‘oT “6 ‘89% “GI ‘SI| 32 ‘GT ‘8 ‘aune “AVIA udy “OAV IAL “Areniqag | ‘Arenuep | ‘toquieoa(y “‘SuyoIaTAI JO UIT, "saTjaI00g "ZE-TEg] of uopuoT fo saipog aufiquarvgy ayy fo ssurjaapy ay, fo mpua]n) THE PHILOSOPHICAL MAGAZINE AND ANNALS OF PHILOSOPHY. —>>——_ [NEW SERIES. ] DECEMBER 1831. LI. On Isomorphism. In Reply to Mr. Brooke. By Professor WHEWELL, of Cambridge *. [X the Phil. Mag. and Annals for September last, appeared some observations * on Isomorphism,” by Mr. Brooke, in which a very unfavourable opinion was expressed of the doc- trine so designated, and of its probable effect on the pro- gress of mineralogical chemistry. Everything on this subject, which comes from a gentleman of such exact acquaintance with minerals as Mr. Brooke possesses, is well deserving no- tice; and the high claims which have been set up in favour of the theoretical and practical consequences of the doctrine in question make it very desirable to ascertain distinctly how far its pretensions are well founded. I am one of those who look to it for the solution of many difficulties in mineralogy, hitherto insurmountable, and who expect that it will lead us to the true line of junction between chemistry and crystallo- graphy. I shall be glad, therefore, to state my views of the evidence on which the doctrine of isomorphism rests, and of the validity of its proof as compared with that of the theory which Mr. Brooke opposes to it. I will begin with this last. 1. On the Theory of essential Ingredients and accidental Mixture. The old theory of the constitution of minerals, to which Mr. Brooke seems inclined to adhere in opposition to the doctrine of isomorphism, is, that each mineralogical species consists of certain parts which are essential; and that the varieties of composition which we find in actual specimens arise from the mixture of extraneous substances with these fundamental elements. Thus Mr. Brooke supposes, at least * Communicated by the Author. N.S. Vol. 10. No. 60, Dec. 1831. 3F 4.02 Prof. Whewell on Isomorphism, as an illustration, ‘‘ that amphibole consists essentially of a single atom of trisilicate of lime, and that all else which may be discovered by analysis is accidental mixture.” The difficulties of this theory appear to me to be absolutely unconquerable; and if such were the best conjecture we could make concerning the constitution of our mineral specimens, we should be compelled, I think, to despair of ever attaining any distinct or consistent knowledge of them. For if we take any table of the analyses of amphibole, for instance that in Leonhard’s Handbuch, we find, besides the lime and silica, which Mr. Brooke supposes to be essential, a proportion of magnesia varying from 2 to 25 per cent., protoxide of iron from 0 to 20 per cent., alumina from 0 to 26 per cent. and various other ingredients. The smallness of the amount of these ingredients in some cases, shows that, on any hypothesis which looks to essential elements, they are not essential; while the largeness of their amount in other cases shows that we can acquire no useful or applicable knowledge of the com- position of minerals by taking up a view in which they go for nothing. If we are to neglect 25 per cent. of magnesia or of alumina in some specimens of amphibole as accidental mixture, by what right do we take account of the lime as essential, which in no case amounts to more than 143 per cent.? The che- mical constitution of a mineral according to such a view must be a matter of mere assertion; for it not only does not ap- proximately represent all the ‘good analyses (which is what it ought to do), but it does not represent any one, within any rea- sonable limits. It does not represent the analyses any better than a dozen other suppositions would do taken at random. It appears to be, on this theory, a matter of arbitrary assump- tion which part of the analysis is to be supposed essential and which accidental: and if we could not find any better mode of considering our analyses, I cannot conceive what reason there could be for ever analysing a mineral at all. In interpreting the result, we should always have the difficulty which Dr. Johnson complained of with regard to an inaccurate narrator ;—it is of no use to be content with believing half of what he says, for we do not know which half. In some cases we may go further, and show that there cannot be any essential composition, common to all the speci- mens of the same species. What are the essential ingredients of garnet? If we again turn to Leonhard’s table, we find silica indeed common to all the analyses, but not one single ingredient besides. Alumina, lime, protoxide of iron, per- oxide of iron, protoxide of manganese, are the most common of in Reply to Mr. Brooke. 4.03 of the other ingredients; but there is not one of these which is not, in more than one case, either absent, or present in very small quantity. Shall we say then that garnet consists essen- tially of silica, and that the other substances are accidental ? that it is thus chemically identical with quartz? This appears too absurd to be thought of; and yet the doctrine of essential composition with accidental mixture appears to leave us no other alternative*. A case often quoted by the advocates of accidental mixture is the Fontainbleau spar, and this Mr. Brooke adduces. This instance has always appeared to me utterly irrelevant. ‘The carbonate of lime is here crystallized among the previously existing particles of sand; so that these are imbedded in it like plums ina pudding. There is no difficulty in such a case, any more than when any one mineral is crystallized about splinters or needles of another ;—a very common occurrence. But who would consider these splinters or needles as belong- ing to the surrounding crystals? In the Fontainbleau spar, no one doubts that the carbonate of lime gives the crystalline character, and that the quartz is caught up in it in grains. The slightest touch of acid, or scratch with the penknife, proves this. It is the easiest thing in the world to show that this is not a homogeneous or simple mineral: the question is about such as are homogeneous. Mr. Brooke would perhaps reply to this, that the Fontain- bleau spar is a palpable mixture, and that other minerals may be impalpable mixtures: that they may appear to be homo- geneous when they are not really so: and that there may be a gradual transition from mixtures obvious to the eye, like the Fontainbleau spar, to mixtures which cannot be detected by any physical character, and are discoverable only by che- mical analysis. To this I reply, that if we really cannot tell whether a spe- cimen be approximately a simple mineral, I do not see what the use can be of analysing it at all. But the way to decide this point, is to take minerals which possess the obvious qualities which may be expected to characterize simple minerals; as transparency, smooth surfaces, apparently uniform structure, bright and uninterrupted cleavage extending to the smallest fragments: all which properties the Fontainbleau spar wants. And if we do take such cases, we neither find ourselves driven to specimens manifestly very impure; nor do we find by che- mical examination, large and irregular accidental mixtures. Who ever detected, in apparently pure quartz, 10 or even 5 per cent. of extraneous mixture? Who ever discovered in pellucid * See our present Number, p. 424.—Kpir. 3F2 calc- 4.04 Prof. Whewell on Lsomorphism, calc-spar any considerable per centage of silica? If we wish to know the chemical constitution of minerais, we must take those which are apparently simple, pure, and of determinate character. If we take those which are plainly impure, mixed, and indefinite, we are not to be surprised if we find the che- mical composition also perplexed, variable, and anomalous. What can we learn by looking, in the first instance, to cases which we know to be exceptions to all rule, and which no theory pretends, or can be expected, to include? The fact which has hitherto so perplexed mineralogists is, not that zmpure specimens are of anomalous composition ; but that specimens, apparently pure, homogeneous, and well cry- stallized, vary in their ingredients in an unaccountable man- ner: and it is this variation which the doctrine of isomorphism undertakes to reduce to laws; so that the analyses of all well selected specimens of the same species shall, within reasonable narrow limits, agree with the theoretical constitution. If this theory do not teach us the nature of mineral species, it at least promises fairer than that of accidental mixture. If we learn little by comparing our analyses with a standard with which we conceive them to agree (the isomorphous composition of the species) we shall learn still less by comparing them with an assumed standard (the essential ingredients) from which it is allowed that they may differ widely and by an unknown quantity. If the half of our specimen may be something dif- ferent from what it seems, it does not appear what hope we can have of connecting what seems with what zs in minerals. If extraneous substances to the amount of 50, 60, or 70 per cent. may be “‘ cemented together and cased up” in the pure mineral, without our senses detecting the want of simplicity, how can we ever distinguish between the case and its contents? I shall suppose then that when we analyse a well-crystal- lized, well-characterized mineral, the analysis gives us an approximation to a chemical constitution belonging to the species. If this be not so, and if we do not get an approxi- mation this way, it appears pretty clear that we shall not obtain such information in any other manner. Any theory which, like that of accidental mixture, supposes that this may be no approximation at all, not only disables us from inferring anything from one analysis, but makes any possible conclu- sion from any number of analyses, entirely arbitrary, conjec- tural, and precarious in the first place; and in the next, utterly inapplicable to any new instance: while in some species, as we have mentioned with regard to garnet, we can absolutely prove a negative against that theory, and show that no one possible chemical constitution can answer to the various re- sults of analysis, even allowing admixture to any extent. Il. On in Reply to Mr. Brooke. 405 Il. On the Evidence of the Doctrine of Isomorphism. It has already been said that analyses of the same mineral often give results so widely different that it is hopeless to at- tempt to discover in them the same chemical compound of the same ingredients. This being so, we find that a law nevertheless does prevail in the analyses of the same species, connecting them together in a definite and certain manner, and bringing them under a common formula. This law is given by the doctrine of isomorphism. ‘The evidence of the doctrine must depend upon the accuracy with which it repre- sents the facts; and that the reader may judge of this, I will take the analyses of eight varieties of garnet, given by Leon- hard in his account of that species (Handbuch, p. 489). No- thing can apparently at first sight be more anomalous than these analyses. The alumina varies from 0 to 22 per cent., the lime from 0 to 34, the magnesia from 0 to 13, the protoxide of iron from 0 to 34, the protoxide of manganese from 0 to 7. If we can find any law which approximately includes these eight analyses, we shall have strong reason to believe that it has some foundation in nature. The following is the constitution of each of the eight speci- mens, expressed in atoms of the ingredients, and re- duced to such a scale that the atoms of silica are 4.* Ingredients| S | A | Fes|Fe |Mn| C | M]| K iW ap Ag 159 Sa woe ons 98 Z 11} ose "22| 2°74 | se. |p. cent. "30 | ee "05 | 2°88 | oe. | Zea coe °59| °39| °51.|.1°43 |p. cent. PLL PP PPS If * T have in this paper used the notation which I have elsewhere recom- mended (Journal of the Royal Institution, No. 111). _In this, S represents silica, A alumina, C lime, M magnesia, K potassa, Fe and Fes the prot- oxide and peroxide of iron, in which the proportions of oxygen are as 2:3; Mn the protoxide of manganese; as, arsenic, s sulphur, c’ carbonic acid. I have used the atomic numbers of Berzelius. In the Phil. Mag. and Annals for August, Mr. Prideaux has dissented from some of the views concerning chemical notation to which I have just ag Reir wi 4.06 Prof. Whewell on Isomorphism, If now in the analyses thus expressed, we add together the numbers in the columns A and Fes, and also those in the co- lumns Fe, Mn, C, M, we have certain numbers which we must compare with each other, as follows: S | A,Fes Fe, Mn, C, M. (1) 4 | 1:82 2°68 (2) 4 | 1:67 2°55 (3) 4 | 1°86 2°65 (4) 4 | 215 2°74: (5) 4 | 2-02 3°17 (6) 4 | 211 2:96 (7) 4 | 2°14 2°91 (8) | 4 | 1:97 2°92 Now in these columns the approximate equality of the numbers in each column is remarkable. None of those in the second column differ much from 2; none of those in the third column much from 3; the first column being invariably 4. We have a degree of resemblance altogether different from what appeared in the former table. And this becomes stronger when we notice, that in all the cases the number in the third column is very nearly one and a half times that in the second, and that this proportion obtains even where the numbers them- selves differ from the average, as in (2). We may observe that in this analysis (2), which is much the furthest from the mean, we have only to suppose an excess of 7 per cent. of silica, in order to make it agree with the rest; and that in this case there must be some inaccuracy in the analysis, since the pro- portions of the separate ingredients amount to 102 instead of 100. Jn (4), where the second column is too large, and the third too small, we are Jed to ask, whether it is possible that in the analysis any portion of Fe has been converted into Fes: the probability of such an inaccuracy must be left to chemists to determine. But even without making any allowances, I think the agree- ment of the above numbers is as close as we could expect, I will leave the matter to be decided by those who may attend to it. I shall use the notation which I have explained, because it is the only one which will answer my purpose, as well as the only one which is algebrai- cally consistent. Those who do not find any inconvenience, or see any incongruity, in that of Berzelius, have no reason for relinquishing it. The relative advantages of the two will be discovered by any one who has to work with them: and there would be little use in a further discussion of these on general principles. and in Reply to Mr. Brooke. 407 and sufficient to justify us in considering 2 and 3 as the stand- ard values of the second and third columns, from which values the deviations are comparatively inconsiderable. It appears then that all the above discordant analyses are nearly represented, and most of them very nearly, by this law:—that the atoms of the ingredient S, those of A and Fes taken together, and those of Fe, Mn, C and M, taken together, are respectively as the numbers 4, 2, 3. If we put this law into a formula, according to the notation explained elsewhere, it will stand thus: Garnet = 4S + 2 A, Fes + 3 Fe, Mn, C, M; which may also be put in this form, 2(S + A, Fes) + 2S + 3Fe, Mn, C, M. Or this, 2(S + A) + 28 + 3C: | where, in the latter formula, it is understood that a portion of A may be replaced by Fes, and a portion of C by M, Mn, or Fe. Since we can include the above analyses under a simple arithmetical law by supposing such replacements, while we can exhibit no such law without this supposition, this example appears to prove the usefulness of the doctrine that ingre- dients do thus replace each other; and this is the doctrine of isomorphism. Such is the kind of evidence on which the establishment of this doctrine must rest 3 and its certainty will depend on the exactness with which it will thus reduce to a common formula a number of analyses of minerals, agree- ing in crystallographicai and physical character. The above case is taken unfavourably for the doctrine of isomorphism ; for if several different chemical formulze ever meet under one crystalline form, this is perhaps most likely to occur in crystals of the tessular system, like garnet. It has however, I think, been shown, that in the case thus taken, the furmula includes all the analyses, at least within 4 or 5 per cent. ; while the doctrine of essential constitution is absolutely in- applicable, inasmuch as silica is the only ingredient common to all the cases, A similar examination of a number of analyses of amphi- bole, with a similar result, is given by Bonsdorf in the Ann, de Chim. tom. xx., and a similar discussion of pyroxene, by Rose, in the Ann. de Chim. tom. xxi. Undoubtedly in various other minerals the true constitution remains still to be dis- covered, and can be obtained only by the laborious process of making or collecting many good analyses of the mineral, well ascertained and pure, and then comparing these in a manner somewhat similar to that employed above, so as to discover 408 Prof. Whewell on Isomorphism, discover the proper formula. This labour has, as yet, been executed for a few minerals only; so that there remains still abundant occupation of this kind for the mineralogist, and it can hardly be doubted, that a clearer insight into the constitu- tion of crystalline substances will reward such researches, if diligently pursued. But the above instances, in which, in mi- nerals of the most complex and apparently confused analysis, order has been detected by the application of the doctrine of isomorphism, appear to be sufficient to assure us that that doctrine has a foundation in nature. If there be any instances in which the analyses do not con- form to the formula proposed, as Mr. Brooke asserts to be the case with regard to amphibole compared with Beudant’s formulz, there can be no doubt that we must allow either that the formula is wrong, or the mineral wrongly named, wrongly analysed, or impure. The isomorphous view of the constitu- tion of bodies has not, nor can it have, any authority beyond what it derives from its agreement with facts. The superiority of this view over that of accidental mixture, arises from its appearing that the latter gives no approximation at all to many of the analyses; while the former has given, in the cases which have been most carefully examined, a very close agree- ment, under very trying circumstances. III. On the Principles of the Doctrine of Isomorphism. Besides Mr. Brooke’s objections to the doctrine of isomor- phism as not supported by sufficient evidence, he has put for- ward several objections founded upon theoretical views, which I shall very briefly touch upon. In p. 164, he says: ‘ If soda and lime are isomorphous in relation to 1 or 2 or 3 atoms of silex, there is no obvious reason why all the other elements that are deemed isomor- phous in relation to 1 atom should not be so equally in rela- tion to 2 or 3 atoms,” &c. Mr. Brooke here and in other cases appears to assume, that if any two elements 2 and y be isomorphous in one case, they must be so in all: and this be- cause there is no obvious reason why it should be otherwise. I confess this appears to me a hazardous mode of reasoning in such matters. Whether the fact is so or not, must be de- termined by analyses, and perhaps is hardly yet decided. The elements which I have denoted by C, M, Fe, Mn, which appear to be zsomorphous in siliceous minerals, are, it would seem, plesiomorphous when combined with carbonic acid. We must, I conceive, hold such ingredients in each mineral species to be isomorphous, as appear, from analyses, to He each in Reply to Mr. Brooke. 409 each other in that species. The general laws of isomorphous elements are as yet imperfectly understood; and when we have but one analysis, it must often be difficult or impossible to decide whether any two ingredients are in definite propor- tions, or in isomorphous or plesiomorphous relation. There are many, therefore, of the general arguments em- ployed by Mr. Brooke which involve reasonings unauthorized by anything yet established as part of the doctrine of isomor- phism. IV. On Plesiomorphous Groups. We find in many cases minerals which, agreeing in the form of their chemical formula, and differing in one or more of their elements, agree also in their system of crystallization, but differ slightly in their angles and in their physical pro- perties. Thus carbonate of lime, of iron, of magnesia, (C+2c!, Fe + 2c’, M + 2c’,) and mixtures of these, all belong to the rhombohedral system, and have a certain approximate agreement of hardness, scratch, lustre, cleavage, &c. which gives them a general resemblance; while their angles vary from 105° 5’ to 107° 40!, according to the ingredients. Such minerals have been termed plesiomorphous; and it is evi- dent, as Mr. Brooke allows, that if we can range minerals into such groups, we shall have made an important Step in mineralogy. ‘ If,” he says, * the class of primary forms can be indicated with certainty by the chemical composition of a crystallized body, a benefit will so far have been conferred on science.” Several such groups appear to have been already detected: thus, besides the rhombohedral group of the form R + 2c! already noticed, we have the carbonates of baryta, strontia, lead, and lime (arragonite), which are prismatic; the sulphates of the same bases, which are also prismatic; and we have a similar group in the various species into which mineralogists have subdivided the siliceous minerals formerly included under the name felspar. Mr. Miller has suggested the possibility of another group, containing the silicates of zine, of iron (yenite), of magnesia and iron (peridot) (Camb. Trans. vol. iii. p. 419). A circumstance which gives additional importance to these groups is, that besides the agreement in the system of crystallization, and the close approximation of their angles, they are always found to possess several other physical properties in common, or with slight differences. M. Beudant has asserted a proposition concerning the dependance of the angle on the chemical constitution in these groups, which is probably not true; as Mr. Brooke has very satisfactorily shown. He has maintained, that the angle of N.S. Vol. 10. No. 60. Dec. 1831. 3G C+ 2c! 410 Prof. Whewell on Isomorphism, C + 2c! being 105° 5', and that of M + 2c! being 107° 25/, the angle of any mineral of the kind C, M + 2c’, will be in- termediate between the two angles, exactly in proportion to the mixture of C and M in its composition. Mr. Brooke has pointed out that this doctrine is not reconcilable with the measured angle and ascertained composition of Breiinnerite. Indeed it does not appear that M. Beudant has attempted to establish his law by a series of measures and analyses, and it certainly cannot be established in any other way. It would be highly interesting and important to mineralogy to deter- mine the rule according to which the alteration of the ingre- dients affects the angle of the crystal; but it is not likely that this will be done by assuming the first arbitrary conjecture as the true law of nature. It is possible that some of the groups held to be isomor- phous may be plesiomorphous only; and that more exact measurements may detect differences in angles hitherto sup- posed to be equal. This discovery would by no means di- minish the importance of the study of those substitutions of ingredients by which resembling minerals are related; and this study is undoubtedly one on which the progress of mi- neralogy will much depend. V. On Dimorphous Substances. It is well known that certain substances exhibit the curious phenomenon of two different fundamental crystalline forms, without our being able to detect any difference in the che- mical constitution of the bodies. Thus C + 2c! appearsas a rhombohedron in calc-spar, and asa prism in arragonite. Sulphur is either a right or an oblique prism *. Such dimor- phous substances certainly offer a difficulty in any attempt to connect the crystalline form with the chemical constitution ; but they present no peculiar difficulty to the theory of isomor- phous or plesiomorphous substitution. The theory of essential ingredients is at least as much embarrassed by these cases. If all that is essential to rhombohedral calc-spar be a certain proportion of lime and carbonic acid ;—if this essential com- position can impress the character of such calc-spar on 50 per cent. of silica;—how is it that sometimes, when there is not 1 or + per cent. of foreign admixture, we have quite a different crystalline form, as in arragonite? Certainly the theory of ac- cidental mixture has here no superiority; while that of iso- morphism does on the other hand fall in exactly with the fact, * From Mr. Brooke’s observations (Ann. Phil. Dec. 1823) it appears to follow that sulphate of nickel is dimorphous, crystallizing both in right rhombic prisms and in square prisms, h that in Reply to Mr. Brooke. 411 that in some specimens of arragonite a portion of strontia enters into the composition of the mineral; which is what we might expect, carbonate of strontia having a plesiomorphous relation to arragonite. In other cases, such as those adduced by Mr. Brooke, of paranthine and sodalite; of eudialyte, zircon, and olivine; it is very far from being clearly established, as yet, that the che- mical formulz of these groups can be made respectively iden- tical, even by the substitution of isomorphous elements; and it certainly has not yet been proved that in these cases the elements are isomorphous. If there be really dimorphous minerals of this kind, the observations of the last paragraph may be applied to them: at present we do not appear to pos- sess a sufficient number of good analyses of these species, to be able to determine how far they are examples of the theory. But certainly the theory of accidental mixture cannot possibly explain any difficulties of this kind, which the theory of isomor- phism will not explain at least as well. I am therefore surprised that Mr. Brooke should haye brought forwards such cases as objections to the isomorphous theory. But I am still more surprised that he should have brought forwards as objections the differences which occur in other cases, where the very essence of the theory requires that there should be a difference, and when the theory could not stand a moment if there were none. “ Arsenic,” he says, “combines with sulphur in two different proportions, and producing different primary forms. Hence the proportion of a common element, and therefore an isomorphous one, occa- sions a change, even in the system of crystallization.” No doubt the change of the proportion of an element occasions a change in the crystallization: we should have little chance of finding any connection between the elements and the cry- stallization if it were not so: as + 2s (realgar) and as + 3s (orpiment) have different chemical formule, and accordingly we find they have a different system of crystallization. How Mr. Brooke conceives that the theory of isomorphism can identify these two compounds, I cannot understand. If, when he says, “a common element, and therefore an isomorphous one,” he means that ¢wo atoms of an element are isomorphous with éhree, he certainly supposes what no advocate of isomor- phism ever dreamt of. In like manner I cannot see how the isomorphous theory offers any ground for the expectation, of which he speaks, that the sulphuret of silver, the sulphuret of copper, and the sulphuret of bismuth should present similar forms. For it is not asserted, so far as I am aware, either that the number of 8G? atoms 412 Unequal Refrangibility of Light on the undulatory Theory. atoms of sulphur is the same in each of these minerals, or that these metals can ever replace each other as isomorphous ingre- dients ; so that all ground of comparison vanishes. I will conclude with noticing the obligation which the doc- trine of isomorphous and plesiomorphous groups, as well as other parts of mineralogy, owes to Mr. Brooke himself. Thus, among other instances, (Ann. Phil. Aug. 1823,) he has re- marked the near agreement in form, of sulphate of iron and sulphate of cobalt: also(Ann. Phil. Dec. 1823) that of the sul- phate of nickel and the sulphate of zinc ; and (Ann. Phil. Jan. 1824) the exact agreement of nitrate of lead and nitrate of baryta. Trinity College, Cambridge, Nov. 7, 1831. W. W. LIL. Unequal Refrangibility of Light on the undulatory Theory. By A CorrEsPoNDENT. 6 Devan undulatory theory of light has now been shown to apply with such distinguished:success to every pheeno- menon, even the most recondite and complicated which the researches of physical optics have disclosed, that no other doubt can remain on the mind of the competent examiner of its doctrines than that which results from the single exception to its universal application ; viz. the explanation of the phz- nomenon of the unequal refrangibility of the different rays of light. In regard to this apparent exception several suggestions have been made possessing high claims to attention. With- out discussing their merit, it may be permitted to the writer of these lines to propose another which seems to him more free from objections than many of those which have pre- ceded it. It will be admitted that the same difficulty which attaches to the explanation of the modifications which the undulations undergo within the refracting medium, applies to the concep- tion of their condition in the medium out of which they enter it. If we have only one homogeneous medium, it seems im- possible to conceive more than one kind of undulation going on at the same time in it; the elasticity being an essentially constant element. If we could by any possibility conceive dif- ferent elasticities coexisting, and by consequence, vibrations impressed with different velocities giving rise to undulations of different lengths at the same time, these would of course be unequally retarded on entering the denser medium, and un-~ equal refraction would take place. The suggestion now offered consists in this,—that such a coexistence Rey. R. Murphy on the Symmetrical Functions of Roots. 413 coexistence of unequal elasticities is not only possible, but must be the case; for if the ether be an elastic fluid uniformly dif+ fused through space absolutely devoid of other matter, it fol- lows that wherever it penetrates a space filled with any me- dium, such as air, it must necessarily be attracted round each particle of air, and form spheres of a density increasing towards their centres. Amongst an infinite number of such spheres uniformly diffused, a succession of vibrations communicated in a given direction, will of course give rise to vibrations propa- gated with various velocities, according to the particular elasti- city of different parts of the disseminated medium: thus we shall have a number of coexistent vibrations producing un- dulations of different lengths which, when they are incident upon a new medium, will cause a deviation in position pro- portional to the unequal lengths of their undulations, accord- ing to the well known and established explanation of the general law of simple refraction as expressed by the undula- tory theory. November Ist, 1831. LIII. On the Symmetrical Functions of a specified Number of the Roots of an Equation. By the Rev. R. Murpuy, Fellow of Caius Coll. and of the Camb. Phil. Soc. To the Editors of the Philosophical Magazine and Annals. Gentlemen, [X a paper published in the last Number of the Transactions of the Cambridge Philosophical Society, I have given a few simple rules relative to the solution of algebraical equa- tions, with their demonstrations. The sum of any specified number of the roots taken in order from the least, upwards, and the sum of any given function of such roots, may be thence found, for any proposed equation ¢(x) = 0, containing only positive and integer powers of z. ‘The coefficients of the different terms of an equation are, as is well known, the sums of symmetrical functions of al/ the roots; and my present object is to show a simple method of obtaining the corre- sponding sums of the symmetrical functions of a specified num- ber of the roots; and as general investigations relative to a specified number of the roots are I believe new in analysis, this paper may not be unacceptable to your mathematical readers. Let ct) 5 5 dg seve» tm be the m least roots, taken in order, of the equation $ («) = 0, and A any arbitrary quantity. ‘Then by arule given in (§ 3) of the paper above referred to, we get log 414 Mr. Haworth’s Thirteenth Decade of New Succulent Plants. log (1+ Aw) + log (1+ Aa) + «+. log (1+ Acm) = coeffi- —A~A $(x) : eo Treat log om This coefficient is a func- tion of A, suppose (A). Hence (1+ Aa). (1—Ady) sereeeeee ‘ bugis cient of — in x (l+Aa¢@m) = eV) « being the base of Napier’s logarithms. Let «¥@ be expressed in powers of A, the general term being w,. A”, and suppose we equate the terms involving like powers of A, on both sides of the equation; then First; When pm, u, is zero, From the third case, it follows, that in applying this method we may always reject from (A) all the terms after that which involves ”. A process exactly similar will give the combinations p and p together, of any functions of the m least roots or their con- tinued product. Iam, Gentlemen, your obedient Servant, R. Murpuy. LIV. Decas tridecima Novarum Plantarum Succulentarum ; Autore A. H. Hawortnu, Soc. Linn. Lond.—Soc. Horticult. Lond.—Soc. Cas. Nat. Curios. Mosc.—necnon Soc. Reg. Hor- ticult. Belgic. Socius: &c. Sc. To the Editors of the Philosophical Magazine and Annals. Gentlemen, 1) Saal a longer space than usual between my communi- cations to your valuable Magazine and Annals, I send you hereunder my thirteenth Decade of New Succulent Plants, for insertion, if you please, in an early Number of that useful work. As heretofore, I have carefuliy stated the native countries of every species,—detailed, but with due precision, their botani- cal characters; and not failed to record the rich gardens from whence I have received them. And to all these particulars I have added such contrasting and other characters as may enable the gardener to grow them, the botanical tyro to un- derstand them, and every able author to appretiate and blend them with their old affinities in a scientific way. I remain, Gentlemen, yours, &c. Chelsea, Aug. 30th, 1831. A. H. Haworrn. Ord. Mr. Haworth’s Thirteenth Decade of New Succulent Plants. 415 Ord. Nat. BROMELIACE/, Juss. Gen. Pl. 49. Genus AcAvE, Linn. Gen. Pl. 582. univittata. A. (red-edged white-striped): foliis laté lorato- 1. lanceolatis acuminatis pungentibus, margine rufo acu- leato-serrato, costa univittata. Habitat in Mexico. G.H. %. Ex regio horto Berolinense communicavit amicus Dom. F. Otto, A.D. 1830. Obs. Proxima fortassé Ag. angustifolie Nob. at folia magis patula seu inflexo-concava, erecto-expansa vel parum recurvantia crassa dura seu loreo-rigida niten- tia, atro-viridia, costd laté alba, in spina atro-rufa valida affinium desinente; aculeis marginalibus distantibus validis adunco-respicientibus atro-rufis, margine ipso tenuiter cartilagineo etiam atro-rufo; mox albicante periente : swbtuws (folia) convexa pallida sive parm al- bicantia (lateribus alté viridibus) lineolis numerosis pa- rallelis contiguis longis sed deorsum szepius interruptis atro-viridibus basin versus plus minis evanescentibus. Juvenem plantam solum habeo, foliis adhuc vix pe- dalibus 9-10 lineas latis. Fortassé varictas vittata et lineolata preesingularis plantz originalis quedam absque vitta vel lineolis; nihilominus proprize species. Ord. Nat. TULIPACE/E, Kunth Synops. 1. 292. Genus Yucca Auctorum, et Nob. in Suppl. Pl. Suce. p. 31. charactere novo ampliori. Sectio *** INTEGERRIM®: foliis margine integerrimo levi, caudice 1-10-pedali valido recto. Nob. 1. c. aletriformis. Y. (The undulate-leaved): foliis capitatis erecto- recurvis undulatis lorato-attenuatis longé acuminatis viridibus nitidis levibus, margine ipso cartilagineo al- bicante integerrimo. Habitat Capite Bonz Spei, et exindé ad regium hor- tum Kewensem misit, A.D. 1823, amicus peregrinator Dom. Bowie; adhuc non floruit in horto, sed ibi pul- chré viget, Aletrem speciem simulans. G. H. hk. Obs. Caudex adhuc bipedalis firmus teres diametro sesquiunciali. Folia eleganter capitatim collecta (capite longiore quam in plurimis) et concinné basi imbricata: nunc in nostro exemplo subbipedalia, 15-16 lineas lata, sublorea, basin versus crassiora et succulentiora, supra medium 416 Mr. Haworth’s Thirteenth Decade of New Succulent Plants. medium vix undulata sed pedetentim prodeuntia in acumine longo; supra, preecipué basin versus, inflexo- canaliculata, subtus obtusé carinata, carind supra me- dium sensim sensimque evanescente. Ord. Nat. CRASSULACE, DeCand. Prod. v. 3. p. 381. Tribus 1. CrassutEx, DeCand. Prod. ib. Genus Sepum Linn. &c. Sectio AcUTIFOLIA Nod. subclavatum. S. (green club-leaved): foliis imbricatis, in ramo- 3. rum apicibus rosulas subformantibus subclavatis, tur- gidis viridibus, apicem versus attenuatis acutis. Habitat in America Septentrionali. Rami et ramuli perennes, primo anno 3-4-entales, stabiles, sed flexo-decumbentes teretes foliorum cicatri- cibus crebre et transversaliter lineolatim notati, aspe- riusculi. Folia breviora et obtusiora quam in affinibus hujus sectionis, sed levia incurva tumida et carnosa; subtus convexa, supra obsoleté depressiuscula. Floret nondum in Anglia, sed in Horto Pharmac. Chelseiano pulchré vigebat A.D. 1830. Species di- stinctissima, vix ullze valde affinis, sed prope S. Forster7, Engl. Bot. tab. 1802, locarem pro tempore. H. . Obs. Under the genus Sedum may appropriately be noticed some Seda I have long cultivated, and which it will be a botanical improvement to describe briefly as follows; for the first three appear to be distinct species: viz. Sectio optusiroLia Nob, floribus cymosis. album. S. (blunt-leaved white) : foliis clavato-ovatis viridibus teretiusculis glabris, ramis perennibus radicantibus, junioribus in Jente puberulis. Sedum album Eng. Bot. t. 1578. Sedum album y DeCand. Prod. v. 3. p. 406. Flores valdé cymosi albi. Habitat insuper muros prope Londinum. H.%. micranthum. S. (greater blunt-leaved) : foliis clavato-oblongis viridibus teretiusculis glabris, ramis perennibus radi- cantibus, junioribus in lente puberulis. Sedum album 6 micranthum, DeCand. Prod. v. 3. p. 406. Habitat prope Gloster. H. /. Communicavit amicus Rev. Dom. Ellicombe. Obs. Antecedenti simillimum, at 2-3-plo majus, flo- ribus numerosioribus minoribus petalis angustioribus. tereti- Mr. Haworth’s Thirteenth Decade of New Succulent Plants. 417 teretifolium. S. (slender blunt-leaved) : foliis zequaliter teretius- culis subelongatis parum depressis viridibus ramisque subelongatis perennibus radicantibus, omnino glaber- rimis. Sedum album «a, DeCand. Prod. 3 p. 406. quod est S. teretifolium Lam. Fl. Fr. 3. p. 84. Obs. I have not seen the flowers of this plant, which was sent to me four years ago, from the Bury Botanic Garden, as, J think, a Hertfordshire plant, gathered wild there by the late venerable Sir Thomas Cullum. Its shoots are more than twice the length of the last, and its leaves are half as long again, often cylindrical and more remote, and it is destitute of all pubescence even when magnified. I suspect it is a maritime plant, requiring a saline air, and perhaps a saline soil, to produce its flowers. It bears a greater resemblance to a Mesembryanthemum than any other Sedum I am acquainted with. Habitat prope Hereford? H. }. With the above Seda, mention may be here, and appropriately, made, of two remarkable varieties of Sedum acre, sent from the Bury Botanical Garden at the same time with the preceding; viz. acre. S. var. 6 diminutum. multoties minus quam S. acre Fing. Bot. tab. 839. An Sedum acre B glaciale, De- Cand. Prod. v. 3. p. 407? Obs. Valdé repens glomeratum, facie feré Lycopodii parvi. Lrecti rami steriles unciam alti; florentes, vix sesquiunciales. Folia magis conferta et minus viridia quam in §. acre Eng. Bot. tab. 839, in ceteris feré omnino concordat. Sed caules 2—3-, rarius 4-flori so- lum, nec 4-8, flori ut in S. acre. H. 2. Obs. This diminutive plant, my judicious friend Mr. John Denson, jun. (late Curator of the Bury Botanical Garden) assures me was gathered wild on Swaffham Heath, Norfolk; by, I think, Mr. William Christie, jun. of Clapham; and it may eventually prove to be a genuine species. The second variety may be called acre y elongatum. §. ramis pendulis 7-uncialibus; erectis 4-uncialibus, foliis laxé imbricantibus. Obs. This var. Mr. Denson mentioned not the origin of. Its shoots are three times longer than those re- presented in Zing, Bot. tab. 839, and its leaves are more patulous and more distant from each other, and it pro- N.S. Vol. 10. No. 60, Dec. 1831. 38H duces 418 Mr. Haworth’s Thirteenth Decade of New Succulent Plants. duces flowers less frequently; but it is only a variety. Hei: Genus Ecueverta DeCand. l. c. Herbe mexicane succulentze glauce perennes vel suffrutescentes, foliis crassis levibus basi solutis, et feré Sempervivi modo in rosulas laxas expansis; flori- bus racemosis seu spicatis, vel spicatim paniculatis coccineis seu luteis, pedunculis brevibus seu brevis- simis. * Floribus coccineis. lurida. E. (The dingy-leaved) subczespitosa: foliis imis lan- 4. ceolato-cuneatis lividis, superioribus lanceolatis, floribus racemoso-spicatis. Habitat in Mexico. G. H. 2. Communicavit amicus Dom. Otto. Obs. Herba succulenta perennis sive suffrutex laxé czespitosa surculis paucis brevibus. Folia paginis le- vibus glauco-fusca inflexo-concava, et nitentia, si bené culta; subéws convexa obtusé carinata, margine carti- lagineo, tenuiter exasperato; apice sepe parum re- curva acuminulata. Scapz in planta nostra tres do- drantales vel pedales, teretes et minimé sursum attenu- ati laeves pallidi seu albicantes, primo terminales, sed citits 6 progressione plante laterales et basi parum flexi, mox recti et erecti foliolosi seu bracteati. Bractee alterne, folio consimiles, gradatim sursim minores, distantes patulz, vel inter flores recurvule. Omnes bractee sic leviter scapo adnate, ut citius decidua, e levissimo tactu, et insuper terram facillimé radicantes, et (uti folia) in proprias plantas crescentes. Flores racemosi, seu racemoso-spicati; superiores confertiores ; aperti horizontales. Pedunculi breves subindé 1-2- bracteolati. Corolla ut in £. grandifolia Nob. sed magis coccinea, et certo situ rore glauco cum rubedine viva- citer violascens. Ord. Nat. EUPHORBIACE, Juss. Gen. 384. Genus Tirnymatus Mill., Nob. in Synops. Pl. Succ. p. 137. uniflorus. T. (American tuberous) tuberosus levis: foliis obo- 5. vatis subpetiolatis, floribus pedicellatis solitariis in ra- morum dichotomiis. Habitat in America Meridionali. St. 2/. Florebat in caldario regio ditissimo Horto Kewensi A.D. 1829, mense Julii, ubi descriptionem sequentem faciebam. Radix Mr. Haworth’s Thirteenth Decade of New Succulent Plants. 419 Radix feré ut in 77th. tuberoso Nob. qui est é Capite Bonz Spei, et satis cognitus. Caules pauculi subsemi- pedales exigui teretes patentes carnosuli herbacei, in caldario debiliter decumbentes furcati sive simpliciter dichotomi, apicibus assurgentibus. Folia alterna remotiuscula integerrima in petiolos (in caldario) deorsum attenuata subavenia pallidé vi- ridia satis tenuia, nihilominus carnosula. Flores pauci parvi ordinaril inconspicui. Cetera non examinavi, et post florescentiam per- fectam solum vidi. Est planta herbacea tuberosa ex- igua laevis edentula et adhuc non scripta. Ord. Nat. CACTEAL, DeCand. Prod. ». 3. p. 457. Tribus primus; seminibus parietalibus. Subgenus Ecuinocactrus Link et Otto Diss. p. 11. Cotyledones due basilares (secund. DeCand.). Jn- florescentia apicem plante versus. These stigmata are opposite to the three outer divisions of the perianthium, and conse- quently terminate the axes of the component parts of the ovarium, which he regards as composed of three simple ovaria united by their ovuliferous margins,—a structure in which the ordinary relation of stigmata to placente is that here found. In Cypripedium and Apostasia, in which the lateral stamina are perfect, and the middle one without anthera, all the lobes of the stigma are equally developed and of nearly similar form and texture, and, as Mr, Brown has proved by experiment in Cypripedium, are all equally capable of performing the function of the organ. But in most cases, that lobe which is opposite to the middle and perfect stamen and deriving its vessels from the same cord, does not perform the function of the organ, there being hardly an instance of a per- fectly developed stamen and stigma placed opposite to each other, and having the same vascular supply. To this lobe the glands al- ways belong, to which the pollen masses become attached, but from which they are always originally distinct. Its office, therefore, is essen- tially different from the lateral lobes, which are always present, more or less developed, and capable of performing their proper office. These lateral lobes are most developed in Satyrine or Ophrydea, especially in Bonatea speciosa, in which they have been mistaken for portions of the labellum. That they are, however, actually the effi- cient stigmata Mr, Brown has proved by experiment, in applying the pollen mass to their secreting surface, which was followed by the en- largement of the ovarium, [n the ordinary structure, therefore, of Orchidee, in which only one perfect stamen is produced, the corre- sponding Linnean Society. 439 sponding stigma loses entirely or in part its function, which it re- _gains in those cases where this stamen is destitute of anthera; and hence these organs, when perfect, are never placed opposite, but always alternate with each other, The tissue of the perfect stigmata in Orchidee is not materiaily different from that of other plants. It consists of densely approxi- mated utriculi, which enlarge, and are subsequently separated from each other by a viscid secretion. The channel of the style has a si- milar structure, and undergoes similar changes previous to impreg- nation. In the unimpregnated ovarium, the upper portions which correspond to the axes of the placenta, but which do not bear ovula, are neither secreting, nor do they consist of utriculi like those of the cavity of the style: and the same is observable in the six lines mar- ginal to the three placente; and these lines, both above and at the margins of the placente, Mr. Brown calls the conducting surfaces of the ovarium. The female organ is now in a proper state to be acted upon by the pollen; and Mr. Brown has satisfied himself that it acts by being brought into contact with the stigma, as Treviranus’s experiments proved, He applied the pollen to the stigmata in several tribes of Orchidee, and found that its grains, either in the entire mass or se- parately, soon produced tubes or boyauz, like those first described by Amici and Brongniart. One tube is emitted from a simple grain of pollen, their number consequently corresponding to that of the cells of the compound grain. These tubes acquire a great length, even while adhering to the grains which produce them, and have a diame- ter less than zy'yoth part of an inch. They eventually separate from the grain while immersed in the viscid secretion of the stigma. They are cylindrical, neither branched nor jointed, with apparent interrup- tions within, probably from partial coagulations, on the walls, of the contained fluid. With a magnifying power of 150 Mr. Brown has not been able to observe granules in them even in their earliest state. With a power of 300 or 400, an extremely minute transparent gra- nular matter may be detected. The tubes thus produced from the pollen mass are generally very numerous, and form a cord, which passes through the channel of the stigma orstyle. On reaching the cavity of the ovarium, this cord divides into three parts, which are applied to those upper axes of the valves which are not placentiferous, and at the top of each placenta each of these three cords again divides into two branches, the six ultimate divi- sions thus produced passing down along the margins of the placente, along what has before been called the conducting surfaces of the ova- rium. They descend to the base of the placenta, with which they are nearly in contact; but Mr. Brown has not been able satisfactorily to trace branches from them mixing with the ovula. These cords are en- tirely composed of pollen tubes, and are undoubtedly essential to fe- cundation, but in what manner they operate is unknown. Mr. Brown adopts the opinion of M, Brongniart, that the doyaux are derived from the inner membrane of the grain, and believes the correctness of this opinion to be demonstrated in Asclepiadee, in which the membranes are 440 Linnean Society. are entirely distinct. Their production he considers a vital action excited in the grain by the application of an external stimulus, which is afforded by the secretion on the surface of the stigma ; and they derive nutriment either from the particles contained in the grain, or from the conducting surfaces with which they are in contact. The first visible effect of the action of the pollen on the stigma is the enlargement of the ovarium, which, in those cases where it was reversed by torsion, untwists and resumes its original position. After impregnation the ovulum enlarges, the nucleus disappears, probably from its acquiring greater transparency, and becoming con- fluent with the substance of the testa: soon after, a minute speck about the middle of the testa becomes visible, which is the commence- ment of the future embryo. At this period a thread may be traced from its apex nearly to the open end of the testa, consisting of a simple series of short cells, the lowermost one of which is probably the original state of what, from enlargement and deposition of granular matter, becomes the opake speck or rudiment of the embryo ; the only appreciable changes in which are its increase in size and eventual cel- lular structure. In the ripe state it forms an ovate or spherical body, consisting of an uniform cellular tissue covered by a thin membrane, the base of which exhibits no indications of original attachment at that point, while at the apex the remains of the lower shrivelled joints of the thread are still often visible. The embryo, therefore, would be without albumen; the germinating point its apex, or that where the cellular thread is found ; and the seed and funiculus are without ves- sels. Asclepiadee.—The mode of impregnation in this family was sup- posed by Jussieu, Richard, Bauer, Treviranus, and by Mr. Brown, to be indirect; that is, that there was no immediate contact of the pollen with the stigma, but that the fecundating matter was conveyed from the mass through the arm and gland to the female organ. At a very early period Gleichen had observed that the pollen masses were originally distinct from the glands,—a fact which Mr. Brown had afterwards stated in 1809, and which had equally been observed and delineated by Mr. Bauer. Gleichen also states, that before the masses unite with the glands they are removed from the cells of the anthera, and implanted into the wall of the tube which surrounds the ovaria, and that in this situation a white viscid substance hangs to them, which consists of tubes containing globules; and these tubes and their contents he considers as the early preparation for the formation of pollen. He remarks, that the tops of the styles are not originally connected with the pentagonal body, and therefore, that impregnation does not usually take place until the true stigmata, or those extre- mities of the styles on which vesicles and threads are observable, have | penetrated through the substance of the pentagonal body, and are on a level with its apex. At the same time, he is disposed to believe that insects may occasionally assist in the function by carrying the fecun- dating matter directly to the stigmata, even before they enter the pentagonal body. Sprengel in 1793 asserts that insects extract the pollen — rom Linnean Society. 44] from the cells, and apply them to the apex of the stigma, which, being a secreting part, is calculated to act on the oily matter exuding from the surface of the pollen mass. In 1829 Ehrenberg describes the grains of pollen as contained in the proper membrane of the mass, which bursts in a regular manner, and as having each a tube, which tubes collectively are directed towards the point of dehiscence.: He does not say how they communi- cate with the stigma, and supposes that they form an integrant part of the grain, without being produced by the action of an external sti- mulus. In July last Mr. Brown resumed his investigations into the struc- ture and functions of the organs of this family. He verifies observa- tions made by Mr. Bauer so early as 1805, that the masses are cellu- lar, each cell containing a single grain. These cells he considers as the outer membranes of the grains of which the inner membranes are the grains described by Treviranus without tubes, and by Ehrenberg after their production. He found that the agency of insects was necessary to effect fecun- dation ; that the pollen masses were actually removed from the cell of the anthera, and immersed in the fissures formed by the projecting ale of the anther, the descending process of the stigma near its flexure being broken, so that the mass was entirely separated from the gland. The pollen mass was so placed in the fissure, that its inner or convex edge was closely pressed to that point where the tube of the united filaments is joined to the base of the corresponding an- gie of the stigma. On separating them, a white cord, consisting of slender tubes, was observed issuing from the gibbous part of the edge which had burst. On opening the mass, these tubes were found to proceed each from a grain of pollen, all directed towards the aperture. They were like those described in Orchidee. The cord had opened a passage for itself through the membrane, or, rather, had separated the upper edge of this membrane from the base of the stigma, to which it was before united. It then passed along the surface of the base of the stigma until it arrived at its articulation with the two styles ; then inclined towards the inner side of the apex, which is in some degree exposed. On opening the cavity of the style, the cord was seen passing down the centre to the commencement of the pla- centa, where it appears to terminate. These appearances, which were the result of the application of the pollen to the base of the stigma by insects, were equally obtained by Mr. Brown’s removal and application of the mass. He found that the convex edge of the mass must be the part applied, though he could detect nothing peculiar in its structure or appearance. At present he has not had sufficient opportunities to discover how impregnation is effected in those plants of this family which have erect pollen masses ; for though he has succeeded in producing the tubes in Hoya carnosa, he could not get them to communicate with the stigma, nor can he conjecture how this is to be effected. N. S. Vol. 10. No. 60. Dec. 1831. col ASTRO- 44.2 Astronomical Socrety. ASTRONOMICAL SOCIETY. June 10.—The following communications were read :— I. Observed occultation of Jupiter and his satellites by the moon, June 1, i831. 1. By the Astronomer Royal, giving the contact, immersion of Jupiter’s centre, and total immersion, by four observers; and the emersions of Jupiter and the four satellites, by seven observers, 2. By Mr. Snow, containing the complete observations of all the immersions and emersions, made in Savile Row, together with the observed transits by which the clock error was determined. Mr. Snow observes : «‘ Between the contact of the moon’s limb with the planet, and the planet’s disappearance, 1' 32" elapsed; and during that time no change of light, colour, or motion, took place in the planet, which remained uniformly of a rather more dusky colour than the moon. Soth the planet and moon were in a violent state of undu- lation during the immersion; but the moon’s undulation was seen quite distinctly upon the planet’s disc, and differed, for that small arc, inno respect from the undulation of the rest of the limb. I watched very particularly for any projection of the planet upon the moon’s edge, but could see none. «It is perhaps worth mentioning, that the planet’s second limb, during, and for several seconds after its final emersion, and in both states of the adjustment of the telescope, appeared to have a very considerable curvature towards the moon’s dark limb. The planet, however, soon returned to a shape nearly spheroidal.” 3. By Captain Smyth, containing the same observations. Captain Smyth also remarks: « Although the emersions of the satellites were perfectly distinct, they were certainly not so instantaneous as those of the small stars; which I think was more owing to light than disc. Jupiter entered into contact rather sluggishly; but though the lunar limb was tremulous from haze, there was not the slightest loss of light. Faint scintillating rays preceded the emersion, which was so gra- dual, that, as the planet re-appeared, the edge of the moon covered it with a perfectly even and black segment, which cut the belts distinctly, and formed clear sharp cusps, slowly altering until the whole body was clear. There was no appearance of raggedness from lunar mountains, and Jupiter’s belts were superbly plain while emerging; but there was not the slightest distortion of figure, diminution of light, or change of colour.” In allusion to the deviation seen by Messrs. Ross and Comfield, which is inserted in the Memoirs, Captain Smyth mentions the following fact: «“ On Thursday the 26th of June, 1828, the moon being nearly full, and the evening extremely fine, I was watching the second satellite of Jupiter as it gradually approached to transit its disc. My instrument was an excellent refractor, of 3? inches apenare: an Astronomical Society. 443 and 5 feet focal length, with a power of 100. It appeared in contact at about half-past 10, by inference, and for some minutes remained on the edge of the limb, presenting an appearance not unlike that of the lunar mountains coming into view during the first quarter of the moon, until it finally disappeared on the body of the planet. At least twelve or thirteen minutes must have elapsed, when, acci- dentally turning to Jupiter again, to my astonishment I perceived the same satellite owtsede the disc! It was in the same position as to being ina line with the apparent lower belt, where it remained distinctly visible for at least four minutes, and then suddenly va- nished.” The same phenomenon was also observed on the same evening, at different places, by Mr. Maclear and Dr. Pearson. Il. A letter from Mr. Dawes to Mr. Herschel, giving observa- tions of the double stars, 70 Ophiuchi, £ Urse Majoris, 44 Bootis, y Virginis, y and « Coronz, Castor, y Leonis, ands Bootis, made during the last and present year. Mr. Dawes is of opinion that the apparent discs are more affected by the aperture of the telescope than by any other circumstance; and that this is the principal reason why a reflector presents a smaller image of a fixed star than an achromatic of equal illuminating power. III. The reading of Mr. Herschel’s paper on the measures of 364 double stars was completed. This paper contains the micrometrical measures of the angles of position and distances of 364 double stars, observed by Mr. Her- schel with the seven-feet equatorial in his possession at Slough, the same which was used by Sir James South in his observations at Passy, and in a part of the measures of double stars in the Phzloso- phical Transactions for 1824. The individual measures, being too numerous, are not stated; but the mean results of each night’s ob- servation are set down in tabular order, with a weight attributed to each, indicative of the degree of confidence which the observer him- self attributes to them, and with notes attached, descriptive of any peculiar circumstances in the observation proper to be recorded. They comprise the results of 735 sets of measures, or from 6000 to 8000 individual observations, obtained under all atmospheric cir- cumstances, in the years 1828, 1829, and 1830. Almost all the stars observed are taken from the great catalogue of Struve. The author prefaces his observations by a comparison of his results with those already obtained by other observers in the cases where his stars have been observed by others, and draws a conclu- sion not unfavourable to the general accuracy of his angles of posi- tion ; although, in some individual cases, considerable discrepancies and even grievous errors are admitted, In the course of this com- parison he is Jed to point out, some stars as having so materially changed, at least apparently, that he is induced to recommend them for further observation, as being possibly of a binary nature. With regard to his distances, he professes himself much dissatisfied, owing to an imperfection in the micrometer attached to the instrument, $3L2 whieh Adds Astronomical Society. which is the same with that used in all its former measurements, and of which the cause has been detected too late to remedy the evil. After noticing some peculiarities in his mode of observation, and in particular its use of a red illumination of the wires, which he regards as a great improvement, he enters into a more particular examination of the bearing of his present results on the theory and history of the following stars, whose motions he considers as fully demonstrated by them, although some of them had previously been brought into question. 9 Cassiopee. y Virginis. 39 Draconis, 9 Persei. 7 Coron. e| Lyre. Castor. ° Bootis. e? Lyre. ¢ Cancri. 49 Serpentis. ¢ Sagitte. w Leonis. o Corone. 61 Cygni. y Leonis. wu Draconis. d Equulei. & Urse. 70 Ophiuchi. ¢ Aquarii. Among these the most remarkable of his conclusions refer to Castor, @ Cancri, ¢ Urse, y Virginis, and y Coron. In the cases of Castor and y Virginis, he is enabled, by the kindness of Pro- fessor Rigaud, to produce observations of their positions by Bradley and Pound, which are peculiarly valuable, as they carry back the history of these stars upwards of a century, and enable us to forma much better judgement than heretofore of their orbits, both which appear to be ellipses of considerable elongation. He describes a very ready and easy graphical process by which these orbits may be approximately laid down, and exemplifies it on y Virginis, re- specting which he concludes that the present approach of the stars, and increase of their angular velocity, will still go on for several years, until their distance is reduced to less than a single second, which, considering the brightness of both individuals, will render this asingle star to all but the very finest telescopes. Castor he also considers likely, ere very many years have elapsed, to become a close double star, and again to open to a much more considerable distance than at present. In the case of 2 Cancri, he is led by his observations to conclude that the motion is retrograde instead of direct, and much more rapid, so that this star has nearly completed a whole revolution. This conclusion is fully confirmed by his observations of the present spring (1831), and also by the observations of Mr. Dawes, which have been communicated to him very recently, and which agree in a very remarkable manner with his own, and actually suffice to trace the bimestral motion of the star, as had been previously done in the case of § Urse. 7 Corone, too, offers, if all the observations can be trusted, a still more remarkable instance of quick rotation, being already considerably advanced in its second revolution since Sir Wm. Herschel’s first discovery of it; but this will require further confirmation, owing to the extreme difficulty of the ee e Astronomical Society. 445 The periods of these two stars may be stated respectively at 55 and 43 years; that of £ Urse at 562, which last determination agrees nearly with that of M. Savary, who has assigned 58% years for this element. The period of 70 Ophiuchi has been determined by Pro- fessor Encke at 73°862 years. Lastly, Mr. Herschel subjoins some practical remarks on the management and action of telescopes, and takes occasion to intro- duce a set of measures of the positions of Saturn’s satellites, taken under remarkably favourable circumstances, and also a single ob- servation of the place of the comet of 1830, the only one he could succeed in procuring. In a subsequent letter received from Mr. Herschel, he alludes to a new method of taking the angles of position, viz., by reflected as well as by direct vision. He conceives that this method possesses two capital advantages: Ist, That the quantity directly measured is double the quantity sought, by which, of course, the error of de- termination is halved; and, 2ndly, That the error of the zero is destroyed altogether, the double are being given by the difference of readings in the limb of one and the same circle, maintained in one and the same position. Mr. Herschel also adds, that subsequent and very satisfactory measures of 4 Corone fully confirm the con- clusion above mentioned with regard to the revolution of that star. IV. On the dependence of a clock’s rate on the height of the barometer, by the Rev. Dr. Robinson. The rate of a clock of good workmanship may be assumed to depend on three things ; first, the rate at a given temperature and barometric pressure :. secondly, on the variation of temperature, as shown by the thermometer; and thirdly, upon the atmospheric pressure, measured by the barometer. The variation of temperature not only affects the materials of the pendulum, but, along with the atmospheric pressure, greatly modifies the action of the air in the way of buoyancy and inertia, &c. Possibly, the irregular action of the wheelwork, the diminution of arc from the thickening of the oil on the pallets, and even the hygrometric state of the air, may sensibly alter the rate of a clock; but the present memoir is confined to the consideration of the first-mentioned sources of error. As the changes are minute, Dr. Robinson formed equations of condition, where the quantities sought were the rate of the clock at 49° of the thermomer, and 29°5 inches of the barometer, and the retardations corresponding to a rise of 1° and 1 inch in each of these instruments respectively. The absolute gain or loss of the clock was determined with the utmost care. “A thermometer placed in the clock-case, with its bulb three inches before the pendulum rod, and on a level with the cover of the jar, and a barometer with its cistern at the same level, were noted morning and evening at half-past nine; a time chosen, not merely as likely to give mean results for the whole day, but also because it nearly bisects the average period of evening observations. The thermometer was read through a square of plate glass, cemented in 446 Astronomical Society. in the door of the case; and this being screwed close, (as described in the Armagh Observations for 1828,) all free communication with the air is precluded, and the changes of temperature within it are slower and more regular than would be possible in clocks of the ordinary construction. This made observations at other than the stated periods unnecessary. The barometer was observed whenever its movements seemed irregular, and the mean for the day corrected, if necessary, by interpolation.” Dr. Robinson then shows that the equations, when treated by the method of least squares, give, fur the gaining rate of the clock at the standard temperature and pressure, 0°,263; for the gain by an increase of 1° in the temperature (his clock was over compensated), 0°,069; and for the gain by a depression of 1 inch in the barometer, 0°,241. As the mere effect of the air's buoyancy on the mercurial pendulum is 0°,15 for a change of 1 inch in the barometer, the re- mainder is due to the inertia of the air carried along with the pen- dulum in its oscillations. Dr. Robinson finds that the barometrical pressure has no sensible effect upon the arc of vibration, and, consequently, does not affect the clock through this cause. With respect to the barometric variation of rate, having once determined its co-efficient, nothing is easier than to allow for it when any sudden change occurs: it may, however, be corrected mechanically with the utmost facility. A rise in the barometer tends to make a clock go slower. Suppose a syphon barometer to be attached to the pendulum, then a rise in the barometer will transfer a portion of the mercury in the syphon to the tube, and the effect will be the same as if a small weight were shifted from the syphon end to the tube end of the barometer. Now if the syphon be so adjusted to the pendulum, as to bore and situation, that this alteration of the mercury in the barometer will accelerate the rate as much as the increase of the air’s buoyancy and inertia retard it, the clock will be unaffected by any variation of the atmospheric ressure. Dr. Robinson shows how the syphon barometers (he places two, one on each side of the pendulum rod) may be constructed and adjusted for any particular case. «I had previously recognised the influence of the barometer on the clock before the mercurial pendulum was applied; and, without employing the method of minimum squares, satisfied myself that the effect was even greater, being nearly 0°3 for an inch. In examining this point for any given clock, it is however to be remembered, that it is always necessary to make the probable errors of observation considerably less than the quantity sought; otherwise, no conclusive result can be obtained. This may be done, either by taking the rate for intervals of several days, or by observ- ing several stars on each night.” A List Zoological Society. the Royal Observatory, Greenwich, Spica Virg . ) 2L .| Spica Virg. >) 2L 4.}11]1 Tauri >) 1L N Tauri 1L G Geminor. (281) HS veg fae g Geminor. hm s 13 17 6,08 14 2 43,42 13.17 6,94 14 50 2,08 15 34,20 24 33,76 38 35,46 54 27,40 27 32,76 1 7,24 8 53,34 5 6,04 7 5 5 5 5 6 6 6 6 7 7 Feb. 26.| 48 Leonis o! Sextantis o Bas > 2L >) 1L a Cancri .|(50) Leonis oo B Virginis 447 A List of Stars observed with the Moon, in the present year, at 13 22,98 24 42,42 35 40,74 18 27,40 28 2,80 (174) 36 25,84 | 1 6 Scorpii | 1 x 2h ] Antares 1 11 17,78 29 20,18 41 23,18 53 6,26 4 4 5 30 6,74 3 5 .| a Virginis 2 HI Fa oy h? Tauri .| 23 Libre 22 29,04 y—— 15 27 24,72 1L 15 41 37,50 (The following information respecting this list is given in the Monthly Notices of the Society, Vol. If. p. 42. “ N.B. The Astronomer Royal having kindly offered to furnish the Society, from time to time, with the observa- tions of moon-culminating stars made at Greenwich, the first series is here given for the present year; and they will be continued in the subsequent Monthly Notices, as they are received; by which means they will become more speedily accessible to those persons who are desirous of making com~- parisons of this kind.” | ZOOLOGICAL SOCIETY. August 9, 1831. Dr. Horsfield in the Chair. A letter from George Swinton, Esq., of Calcutta, Corr. Memb. Z.§., addressed to the Secretary, was read, announcing the trans- mission to England, asa present to the Society, of an entire Dugong, preserved in spirit and brine, which he hoped would arrive in a suffi- ciently perfect state to admit of its dissection. Specimens of two species of Bats, presented to the Society with a numerous and valuable collection of birds formed at Madras by Josiah Marshall Heath, Esq., F.L. & Z.S., were exhibited, and Dr. Horsfield identified them as the Megaderma Lyra, Geoff., and a new species 448 Roological Society. species of the genus Nycticeyus, Rafin. He pointed out in the former some discrepancies in the colouring from that described by M. Geoffroy Saint-Hilaire, apparently from a specimen preserved in spirit ; the individual before the Meeting agreeing much more nearly with the colours as recently described by M. Isidore Geoffroy Saint- Hilaire, from whose description it scarcely differed, except in the less intensity of the rufous tinge of the tips of the hairs of the upper surface. Of the Nycticejus two specimens were exhibited, on which Dr. Horsfield pointed out the characters by which that group had been generically distinguished from Vespertilio as circumscribed by modern authors. He remarked on the geographical distribution of the genus, which might be regarded altogether as an American form, were it not for the existence of 1 species in Java described by him in his ‘ Zoo- logical Researches’ as the Vespertilio Temminckii, and of the present species obtained on the Continent of India. As the second Indian species of this group, he regarded the present acquisition as peculiarly interesting. {t is considerablylarger than the Javanese species, from which it differs also remarkably in its colouring. Dr. Horsfield thus characterized and described the species : Nycricesus Hearn. Nyct. capite cuneato supra lateribusque planis, auriculis capite brevioribus oblongis rotundatis margine ex- teriore parum eucisis trago elongato falcato, vellere pilis sericatis brevissimis, not@o fusco, gastr@o ta Long. corporis (cauda inclusa), 6 unc. + expansio extremitatum anteriorum, 18 unc. The head is of moderate length, nearly even above and compressed at the sides. The muzzle is broad and abruptly terminated. The nose is slightly emarginate. The eyes ———-. The mouth is propor- tionally small. The lips are not rugose, and are nearly covered with delicate hairs. ‘The ears are shorter than the head; the auricle ob- long, erect, rounded, naked and slightly indented posteriorly, termi- nating below in a small lobule ; the tragus linear, erect, falciform, and shorter than the auricle. The animal is uniformly and thickly covered by a short, very soft, delicate silky hair, closely applied to the skin: this hair is about a line in length on the back, but shorter and more delicate on the head ; on the breast it is somewhat longer and downy. The colour of the body and hair above is brown with a tawny hue ; underneath fulvous with a slight tendency to gray ; the tint being uniformly distributed over the throat, breast, abdomen and sides. The transparent mem- brane is uniformly brown. The collection of Birds formed by Major James Franklin, F.R.S. &c., on the banks of the Ganges and in the mountain chain of Upper Hindoostan, and presented to the Society by the Physical Committee of the Asiatic Society of Calcutta, (which had been laid on the table on the 23rd November last,) was again exhibited. The exhibition had been conimenced at the previous Meeting of the Committee, when the Raptorial and Insessorial Birds were brought under the notice of the Members present ; and it was now concluded by the Rasorial, Zoological Society. 449 Rasorial, Wading, and Swimming Birds. On the former occasion, Mr. Vigors, and on the latter, Mr. Yarrell, availed themselves of the op- portunity to remark on the geographical distribution of many of the species contained in the collection, and on other points connected with their history. ‘They were exhibited in the order of the following Catalogue of Birds (systematically arranged) which were collected on the Ganges between Calcutta and Benares, and in the Vindhyian hills between the latter place and Gurrah Mundela, on the Ner- budda, by Major James Franklin, F.R.S. &c. Orvo I. RAPTORES. Fam. Farconiwa. Sub-Fam. Aquilina—Genus Aquila. 1, Aquina Vinput1ana. Ag. pallidé brunneo variegata ; capite, pec- tore, remigibus secundariis, cauddque saturatioribus, hujus apice albido graciliter marginato ; remigibus primariis nigris ; capitis col- lique plumis pallido-rufo lanceolatis. Longitudo 26 unc. Cawnpoor Eagle, Lath. ? Sub-Fam. Falconina.—Genus Falco. 2. Falco Subbuteo, Linn. Hobby, Penn. Le Hobereau, Buff. 3. Falco Chicquera, Daud. Chicquera Falcon, Lath. Le Chicquera, Le Vaill. 4, Falco Tinnunculus, Linn. Kestril, Penn. La Cresserelle, Buff. Sub-Fam. Buteonina.—Genus Buteo. 5. Buteo Bacha. Falco Bacha, Daud. Bacha Falcon, Lath. Le Bacha, Le Vaili. Genus Circus. 6. Circus Teesa. Cire. capite corporeque rufo-brunneis, plumarum rhachibus fuscis; dorso imo, rectricibusque ferrugineis, his fasciis subobsoletis fuscis septem circiter notatis; remigum tectricibus abdomineque albescenti notatis; femorum tectricibus crissoque rufescenti-albis ; fronte, guld, nucheque fascid gracili albis ; ros- tro pedibusque flavis, illius apice nigro. Longitudo 17+. Zuggun Falcon, Lath. ? 7. Circus cyaneus, Falco cyaneus, Linn. Hen Harrier, Penn. 8. Circus melanoleucus. Falco melanoleucus,Gmel. Black and white Indian Falcon, Penn. Le Tchoug, Le Vaill. 9. Circus rufus, Briss. Moor Buzzard, Penn. Le Busard, Buff. Sub-Fam. Milvina—Genus Elanus, Savigny. 10. Elanus Melanopterus, Leach. Le Blac, Le Vaill. Fam, Strigide.—Genus Otus. 1]. Orus Bencarensis. Ot. pallide rufescens, fusco alboque undu- latim variegatus ; nuche pectorisque plumis in medio strigaé lata brunneo-nigra notatis ; abdomine fusco graciliter fasciato ; remigibus rectricibusque lateralibus prope apicem brunneo fas- cialis, his mediis per totam longitudinem similiter notatis. N.S. Vol. 10. No. 60. Dec. 1831. 3M Longitudo 450 Soological Society. 12 13 14 15 16 17 18 19 20 21 22 23 24 Longitudo 20. Dr. Latham alludes to this as a variety of the great-eared Owl. Genus Noctua. - Nocrva Inpica. oct. cinereo-brunnea; capite guttis parvis albis, alis grandioribus notatis; abdomine albo, maculis brunneis lunulatis notato ; remigibus rectricibusque albo fasciatis ; re- gione circumoculari, gula, fascidque subgulari ad aures exten- dente albis. Foem. magis rufescens, abdomine magis fasciatim maculate. Longitudo 9. Indian Spotted Owl, Lath. ? Orvo II. INSESSORES. Tribus Fisstrostres, Fam. Meropide.—Genus Merops. . Merops Philippinus, Linn. Philippine Bee-eater, Lath. Grand Guépier des Philippines, Buff. . Merops viridis, Linn. Indian Bee-eater, Lath. Guépier a collier de Madagascar, Buff. Fam. Hirundinide.—Genus Hirundo. . Hirundo Klecho, Horsf. Klecho Swallow, Lath. Hirondelle lon- gipenne, Temm. . Hirunpo Fiticaupata. Hir. supra purpurascenti-atra, remigi- bus fuscis ; corpore subtiés maculisque rectricum omnium late- ralium albis ; capitis vertice rufo ; rectrice utrinque laterali elon- gato, ad apicem gracillimo. Statura Hir. riparie. Wire-tailed Swallow, Lath. - Hirundo riparia, Linn. Sand Martin, Penn. L’Hirondelle de rivage, Buff. Genus Cypselus. . Cypselus affinis, Hardw. Allied Swift, Hardw. . Cypselus Palmarum, Hardw. Balassian Swift, Lath. Fam. Caprimulgide.—Genus Caprimulgus. . CaprimuLeus monricotus. Cap. pallidé cinereo-brunneo, rufo, fuscoque sparsim variegatus; abdomine rufescenti-fusco fasci- ato; remigibus secundariis rufo nigroque fasciatis, primariis brunnescenti-nigris, quatuor externis fascid lata alba in medio notatis ; rectricibus sex mediis fasciis gracilibus nigris undu- latis, duabus utrinque lateralibus albis apicibus brunneis. Foem. fascid alarum rufa; caudé concolori (sine albo). Longitudo 10. Great Bombay Goatsucker, Lath.? . Caprimulgus Asiaticus, Lath., Ind. Orn. Bombay Goatsucker, Lath. Fam. Halcyonida.—Genus Alcedo. . Alcedo Bengalensis,Gmel. Little Indian Kingsfisher, Edw. . Alcedo rudis, Linn, Black and white Kingsfisher, Edw. Genus Halcyon. . Halcyon Smyrnensis. Alcedo Smyrnensis, Linn. Smyrna Kings- Jisher, Lath. Martin pécheur de la céte de Malabar, Buff. Tribus Zoological Society. 451 Tribus DenrTIRosTREs. Fam. Muscicapide.—Genus Muscicapa. 25. Muscicapa Banyumas, Horsf. Banyumas Flycatcher, Lath. Gobe- mouche Chanteur, Temm. 26. Muscicapa nitida, Lath., Ind. Orn. Nitid Flycatcher, Lath. Genus Muscipeta. 27. Muscipeta Paradisi. Muscicapa Paradisi, Linn. Paradise Fly- catcher, Lath. Gobe-mouche Tchitrec-be, roux et blanc, LeVaill. 28. Muscipeta peregrina. Parus peregrinus, Gmel. Crimson-rumped Flycatcher, Lath. Gobe-mouche Oranor, Le Vaill. Genus Rhipidura. 29. Ruipmpura auporrontata. Rhip. capite collogue nigris; dorso cinereo-nigro ; alis cauddque fusco-nigris ; fascia subgracili frontali super oculos ad nucham extendente, pectore, abdo- mine, maculis tectricum alarum, apicibusque rectricum, duabus mediis exceptis, albis. Longitudo 6. White-browed Flycatcher, Lath. ? 30. Ruiripura Fuscoventris. Rhip. capite nigro; dorso abdomine- que cinereo-nigris ; alis cauddque fusco-nigris ; strigd brevi su- perciliari colloque in fronte albis; rectricum trium lateralium apicibus albescentibus. Longitudo 73. Broad-tailed Flycatcher, Lath. ? Fam. Laniade.—Genus Ocypterus. 31. Ocypterus leucorhynchus. Lanius leucorhynchus, Linn. White- billed Shrike, Lath. Pie-griéche de Manille, Buff. Genus Edolius. 32. Edolius cerulescens. Lanius cerulescens, Linn. Fork-tailed Indian Butcher-bird, Edw. : Geaus Lanius. 33. Lanius muscicapoipes. Lan. brunnescenti-cinereus subtus albes- cens; strigd superciliari rufescenti-alba ; alis rectricibusque fusco-brunneis, his duabus lateralibus albis basi notdque ad api- cem fusco-brunneis. Foem. aut Mas jin. capite corporeque supra albido maculatis. Longitudo 6. Keroula Shrike, Lath. ? Genus Collurio. 34. Collurio Excubitor. Lanius Excubitor, var. Linn, Cinereous Shrike, var. C. Lath. 35. Collurio erythronotus, Proceed. Zool. Soc. p. 42. Grey-backed Shrike, Lath. ? 36. Cotivrio niGRicers. Col. capite supra, nuchd, alis, cauddque nigris ; guld, pectore, abdomine medio, maculdque in medio alarum, albis; dorso cinereo ; scapularibus, uropygio, abdo- minis lateribus, crissoque rufis. Longitudo 84. Indian Shrike, Lath, ? 3M2 Collurio 452 Zoological Society. 37. Collurio Hardwickii, Proceed. Zool. Soc. p. 42. Bay-backed Shrike, Lath. ? Genus Graucalus. 38. Graucalus Papuensis, Cuv. Corvus Papuensis, Gmel. Papuan Crow, Lath. Genus Ceblepyris. 39. Ceblepyris cana, Temm. Muscicapa cana, Gmel. Ash-coloured Flycatcher, Lath. 40. Ceblepyris fimbriatus, Temm. LEchenilleur frangé, Temm. Fam. Merulide.—Genus Pitta. 41. Pitta brachyura. Corvus brachyurus, Linn. Short-tailed Crow, var. B. Lath. Short-tailed Pie, Edw. Genus Oriolus. 42. Oriolus Galbula, Linn. Golden Oriole, Lath. Le Loriot, Buff. 43. Oriolus melanocephalus, Linn. Black-headed Oriole, Lath. Loriot de la Chine, Buff. 44, Orrtotus Maperaspatanus. Or. fronte, corpore supra, tectrici- bus alarum, abdomineque luteis ; capite supra, genis, remigibus, notdque mediand rectricum fusco-atris; guld alba striis fusco- atris. Longitudo 9. Oriolus Galbula, var. y. Lath. Yeliow Indian Starling, Edw. Yellow Starling from Bengal, Albin. Genus Turdus. 45. Turdus macrourus, Gmel. Long-tailed Thrush, Lath. 46. Turdus Saularis. Gracula Saularis, Linn, Pastor Saularis, Temm. Little Indian Pie, Edw. Genus Timalia. 47, Timauia Cuaranma. Tim. supra pallidé brunnescenti-, subtiis rufes- centi-cinerea ; capite corporeque supra lineis fuscis striatis ; rectricibus fusco obsolete fasciatis ; rostro pallido. Longitudo 93. Gogoye Thrush, Lath. ? 48. Timalia pileata, Horsf. Pileated Thrush, Lath. 49, TimaLiaA uypoteuca. Tim. supra rufescenti-brunnea, subtis alba ; alis rufis ; his caudéque subtis cinereis, rectricibus fusco obsoleté fasciatis ; rostro nigro. Longitudo 63. 50. Trmaia nyPeRYTHRA. Tim. supra olivascenti-brunnea; capite in Sronte corporeque toto subtis rufis ; caudd superne fusco obsoleté fasciata ; rostro pallido. Longitudo 5. Genus Ixos. 51. Ixos jocosus. Lanius jocosus, Linn. Jocose Shrike, Lath. 52. Ixos Cafer. Turdus Cafer, Linn. Cape Thrush, Lath. Le Cou. rouge, Le Vaill. 53. Ixos fulicata. Motacilla fulicata, Linn. Sooty Warbler, var. Lath, Traquet noir des Philippines, Buff. Fam. Sylviade.—Genus Tora. 54. Jora scapularis, Horsf. Scapular Wagtail, Lath. Genus Zoological Socrety. 4.53 Genus Sylvia. 55. Sylvia Hippolais, Lath. Ind. Orn. Lesser Pettichaps, Lath. Reed Wren, Lath. This is the bird alluded to under Dr. Latham’s Reed Wren, as an Indian variety called Tickra and Ticktickee. Genus Prinia. 56. PRINIA CURSITANS. Prin. corpore supra pallidé brunneo, fusco striato; guld jugulogue albis ; abdomine rufescente ; rectricibus mediis fuscis, omnibus subtis ad apicem fascia nigra albo termi- nata notatis. Longitudo 4. 57, PRINIA MACROURA. Prin. supra grisescenti-brunnea ; capite, alis, uropygioque subrufescenti tinctis ; subtus ferrugineo-albida 3 Tec- tricibus quatuor mediis saturatioribus fusco obsolete fasciatis, subtis ad apicem fusco leviter notatis. Longitudo 53. 58, PriniA GRACILIS. Prin. cinereo-grisea ; dorso, alis, cauda@que olivascentibus ; gula, pectore, ablomineque subtis albidis; rec- tricibus subtus griseis fascid nigra albo terminatd notatis. Longitudo 44. Foodkey Warbler, Lath. ? Genus Motacilla. 59. Moractuxa picata. Mot. capite, collo, corporeque supra nigris ; strigd utrinque superciliart alterdque longitudinali alarum, cor- pore subtiis, rectricibusque duabus lateralibus albis. Longitudo 9. Pied Wagtail, Lath. pl. 104. 60. Motacilla flava, Linn. Bergeronnette jaune, Buft., & Bergeronnette de printemps, Buff. Yellow Wagtail, Lath. This is the Indian bird alluded to by Dr. Latham under the head of Yellow Wagtail, called Peeluck, which is its Indian name. Genus Sazicola. 61. Saxicola rubicola, Temm. Stone Chat Warbler, Lath. Genus Phenicura. 62. Phenicura atrata, Jard. & Selb. Indian Redstart, lid. Fam. Pipride.—Genus Parus. 63. Parus atriceps, Horsf. Mésange cap-négre, Temm. Tribus ConrrostTREs. Fam. Fringillide.—Genus Alauda. 64. Araupa Caenpooua, Al. supra pallidé grisescenti-brunnea, plumis fusco in medio notatis ; corpore subtis strigdque superci- liari albis ; rectricibus brunneis, duarum utrinque lateralium po- goniis externis albis ; pectore brunneo maculato, capite cristato, Statura Al, arvensis, Linn. 65. Araupa Guueuta. AL. pallide rufescenti-brunnea, plumis in medio late et intense brunneo lineatis; subtius albescens, pectore brunneo lineato ; femoribus rufescent ibus ; rectricibus brunneis, externa utrinque fere totd, secunde pogonio externd, albis. Statura feré pracedentis. Genus 454 Zoological Society. Genus Mirafra. 66. Mirafra Javanica, Horsf. Alouette mirafre, Temm. 67. Mirarra pHenicura. Mir. pallidé cinereo-brunnea ; corpore sub- tis, remigum pogoniis internis, rectricumque basi rufis ; rostro albo, culmine apiceque fuscis. Longitudo 5. Genus Emberiza. 68. Emberizu Baghaira. Baag-geyra Lark, Lath. This bird is the common Oréolan of India, called Baghairi, 69. Emberiza Gingica, Gmel. Duree Finch, Lath. 70. Emberiza cristata, Gould’s Century of Himalayan Birds. 71. Emberiza Bengalensis. Baya Berbera, Asiat. Res. Loxia Benga- lensis, Linn. The Hindu name of this bird is Baya ; its Sanscrit name Berbera. Genus Fringilla. 72. Fringilla Amandava, Linn. Le Bengali Piqueté, Buff. 73. Fringilla formosa, Lath. Lovely Finch, Lath. 74, Fringilla Malabaria, Loavia Malabaria, Linn. Malabar Grosbeak, Lath. 75, FRINGILLA FLAVICOLLIS. Fring. supra cinereo-grisea, subtis albida; jugulo maculd flava notato; humeris ferrugineis ; alis maculis albis fascias duas exhibeniibus notatis. Longitudo 5-35. This bird, though placed amongst the Finches, differs in the form of its bill, and it may perhaps hereafter be found expedient to re- move it. Genus Ploceus. 76. Ploceus Philippinus, Cuv. Philippine Grosbeak, Lath. Fam. Sturnide.—Genus Pastor. 77. Pastor roseus, Temm. Rose-coloured Thrush, Lath. Le Roselin, Le Vaill. 78. Pastor tristis, Temm. Merle des Philippines, Buff. 79. Pastor griseus, Horsf. Le Martin gris de fer, Le Vaill. 80. Pastor Contra vel Capensis, Temm. Etouwrneau Pie, Buff. 81. Pastor Pagodarum,Temm. Le Martin Brame, Le Vaill. Fam. Corvide.—Genus Corvus. 82. Corvus Corone, Linn. Carrion Crow, Lath. This bird appears to be the common Carrion Crow of India; it differs only in size from the European Crow, and in the greater elevation of the bill. Genus Coracias. 83. Coracias Bengalensis, Linn. Blue Jay from the East Indies, Edw Genus Pica. 84. Pica vagabunda, Wagler. Rufous Magpie, Hardw. Fam. Buceride.—Genus Buceros. 85. Buceros Gingianus, Lath. Indian Hornbill, Lath. There is some confusion with regard to this bird in Dr. Latham’s General History, under the heads of Gingi and Indian Horn- bill: it is the Dhanesa of India, 86, Buceros Malabaricus,Gmel. Unicorn Hornbill, Lath. There Zoological Society. 455 There is also much confusicn with regard to this bird under the heads of pied Hornbill and Unicorn Hornbill of Latham: it is the Dhanesa of the latter, var. B. Tribus Scansores. Fam. Psittacide.—Genus Paleornis. 87. Palzornis torquatus, Vig. Psittaca Borbonica torquata, Briss. La Perruche @ double collier, Buff. 88. Palzornis Bengalensis, Vig. Psittacus Bengalensis,Gmel. Blos- som-headed Parakeet, Lath. sp. 74. var. A. 89. Patzornis FLAVICOLLARIS. Pal. viridis; capite lilacino-cano, flavo marginato ; rectricibus mediis ceruleis apice albo. Longitudo 12. According to the description, this would appear to be Dr. Latham’s yellow-collared Parrakeet ; but he refers to figures which do not correspond. Fam. Picide.—Genus Bucco. 90. Bucco canicers. Buc. gramineo-viridis ; capite, nuchd, collo, pectoreque griseis ; illius plumis in medio albido lineatis ; rostro rubro ; pedibus flavis; regione circumoculari nudd flavescenti- rubra. Longitudo 10. Fichtel’s Barbet, Lath. ? This bird is the Bura-Bussunta of India, and appears to be the same as var. A. of Dr. Latham’s Fichtel’s Barbet. 91. Bucco Philippinensis,Gmel. Barbu des Philippines, Buff. Genus Picus. 92. Picus Bengalensis, Linn. Bengal Woodpecker, Lath. 93. Picus Mahrattensis, Lath., Ind. Orn. Mahratta Woodpecker, Lath. Fam. Certhiade.—Genus Sitta. 94. SirTa CASTANEOVENTRIS. Sit. superné griseo-plumbea ; pectore abdomineque castaneis ; strigd a rictu per oculos ad nucham ex- tendente, remigibus, rectricumque pogoniis internis nigris ; guld macula que rectricum lateralium albis. Longitudo 5. Ferruginous-bellied Nuthatch, Lath. ? Genus Certhia. 95. Cerraia spttonora. Certh. supra griseo-fusca, albo maculata ; capite albo graciliter striato; gula ubdomineque albidis, hoc fusco fasciato ; caudé albo fuscoque fasciata. Longitudo 53. The tail of this bird is soft and flexible, in which respect it differs from the type of the genus, but it agrees in all others. Genus Upupa. 96. Upupa minor, Shaw. La Huppe d’ Afrique, Le Vaill. Fam, Cuculide.—Genus Leptosomus. 97. Leptosomus Afer. Cuculus Afer, Gmel. Edolian Cuckow, Shaw. Genus Cuculus. 98. Cuculus canorus, Linn. Common Cuckow, Lath. This bird, on comparison with the common Cuckow, differs so little that 456 Soological Society. that it can scarcely be called a variety; it is the common Cuckow of India, and its habits and note resemble those of the European bird. 99. Cuculus fugax, Horsf. Bychan Cuckow, Lath. The common Indian name of this bird is Pipiha or Pipeeha, from its note ; in Sanscrit Chataca. Dr. Buchanan named it Cuculus radiatus. 100. Cuculus Sonneratii, Ind.Orn.? Le petit Coucou des Indes, Sonn. ? Sonnerat’s Cuckow, Lath. ? Not having either specimen or figures to refer to, I conclude, from description alone, that this bird is Sonnerat’s Cuckow. Genus Centropus. 101. Centropus Philippensis, Cuv. Coucou des Philippines, Buff. Chestnut Coucal, Lath. This bird is the Mahooka of India, so named from its note; it is called also, by the English, Pheasant Crow. Dr. Latham’s chestnut Coucal very accurately describes it, but his figure is bad; having apparently been taken from a drawing of Gen. Hardwicke’s, which stated it to be a young bird. Dr. Buchanan named it Cuculus castaneus. Genus Eudynamys. 102. Eudynamys Orientalis. Cuculus Orientalis, Linn. Eastern black Cuckow, Lath. Coucou noir des Indes & Coukeel, Buff. This bird is the Coel of India, and the Coukeel of Buffon. 103. Eudynamys Sirkee, Centropus Sirkee, Hardw. Sirkeer Cuckow, Lath. Tribus TsnurrostREs. Fam. Meliphagide.—Genus Chloropsis. 104. Chloropsis aurifrons, Jard. & Selby. Malabar Chloropsis, Jard. & Selby. This bird Le Huréwa of India, and is well described by Dr. Latham as the Hurruwa Bee-eater. Fam. Cinnyride.—Genus Cinnyris. 105. Crynyris Ortentauis. Cinn, capite, collo, dorsoque splendidée virescenti-purpureis ; abdomine purpureo-atro; alis cauddque atris; fasciculo utrinque sub alis aurantiaco. Longitudo 4. Eastern Creeper, Lath. Orpo III. RASORES. Fam. CotumsBip2. Genus Vinago. 106. Vinago militaris. Columba militaris, Temm. Columbar Com- mandeur, Temm. Hurrial Pigeon, Lath. Genus Columba. 107. Columba tigrina, Temm. Colombe a nuque perlée, Temm. 108. Columba Cambayensis,Gmel. Colombe maillée, Yemm. 109. Columba risoria, Linn. Colombe Blonde, Temm. La Tour- iterelle Blonde, Le Vaill. Le Vaillant mentions a larger bird of this species which is common in Zoological Society. 457 in Africa ; the same thing occurs also in India, where there are two birds differing only in size. 110. Columba humilis, Temm. Colombe terrestre, Temm. Fam. PHASIANIDZ. Genus Pavo. 111. Pavo cristatus, Linn. Le Paon, Buff. Crested Peacock, Lath. Genus Tragopan. 112. Tragopan Satyrus, Cuv. Meleagris Satyrus, Linn. Horned Pheasant, Lath. Fam. TeTRAONID2. Genus Pterocles. 113. Pterocles exustus, Temm. Ganga ventre-brulé, Temm. Genus Francolinus. 114. Francolinus Ponticerianus, Temm. Francolin @ rabat, Temm. 115. Francolinus vulgaris, Steph. Le Francolin, Buff. Francolin, Edw. Genus Perdiz. 116. Perdix picta, Jard. & Selby. Painted Partridge, lid. Beauti- ful Partridge, Lath. }17. Perdix Hardwickii, Gray. Curria Partridge, Lath. 118. Perdix Cambayensis, Temm. Perdrix rousse-gorge, Temm. Genus Coturniz. 119. Coturnix dactylisonans, Meyer. Common Quail, Lath. This bird is named Ghagul ; it corresponds with the European spe- cies, and is not very common in India. 120. Coturnix Coromandelica. Perdix Coromandelica, Lath. Perdix textilis, Temm. Caille natiée, Temm. This is the most common Quail of India called Bhuteir. Dr. Bucha- nan named it Perdix olivacea. Genus Hemipodius. 121. Hemipodius Dussumier, Temm. Turnix Dussumier, Temm, Mottled Quail, Lath. Fam. StrurHsionipz. Genus Olis. 122. Otis Indica, Ind. Orn.? White-chinned Bustard, Lath. ? This bird has usually been considered as the female of the Otis aurita, and has been so figured and described ; but it is well known to be a distinct bird. It is the common Leek of India, called by the English Bastard Florican. 1 am not quite certain that Dr. Latham’s White-chinned Bustard is the bird, but his description is so near, that [ have not thought it proper to make a new species, Orvo lV. GRALLATORES. Fam. Gruipz. Genus Grus. 123. Grus Orientalis, Briss. Ardea Antigone, Linn. Indian Crane, Lath. Fam, Arprip®. Genus Mycteria. 124. Mycteria Australis. Ciconia Mycteria Australis, Hardw. Tetaar Jabiru, Lath. N.S. Vol. 10. No. 60. Dec. 1831. 3N Genus 458 Zoological Society. Genus Ardea. 125. Ardea purpurea, Linn. Le Héron pourpré huppé, Buff. Crested Purple Heron, Lath. 126. Ardea speciosa, Horsf. Darter Heron, Lath. This bird is without doubt the Darter Heron of Dr. Latham ; and the Ardea speciosa of Dr. Horsfield is, I think, merely the Ja- vanese type of the same bird. 127. Ardea Torra, Buch. Ardea Egretta, Lath. Ind. Orn. var. Ar- dea alba, Linn. var. Great Egret, Lath. Indian variety Torra or Bughletar. This is the Indian White Egret, and it differs only in size from the European species, being somewhat smaller. Dr. Buchanan named it 4rd. Torra, and when without its filiform appendages on the back, Ard. Putea; so that these Indian terms appear to correspond with Ard. Egretia and Ard. alba. 128. Ardea Caboga, Penn. Caboga Heron, Penn. Gibraltar Heron, Lath. var. A. The term Caboga is acorruption of the Indian term Gao-buga, Cow or Cattle Heron, in allusion to its frequently being seen amongst cattle, like the Gibraltar Heron. Genus Botaurus. 129. Botaurus cinnamoneus. Ardea cinnamonea, Gmel. Cinnamon Heron, Lath. Genus Nycticorax. 130. Nycticorax Europeus. Ardea Nycticorax, Linn. Night Heron, Lath. Genus Tantalus. 131. Tanialus papillosa. Ibis papillosa, Temm. Bald Ibis, Lath. Fam. ScoLopacip&. Genus Rhynchea. 132, Rhynchea Orientalis, Horsf. Cape Snipe, Lath, Bécassine de Madagascar, Buff. Genus Tringa. 133. Tringa ochropus, Linn. Green Sandpiper, Penn. 134, Tringa Glareola, Linn. Wood Sandpiper, Penn. 135. Tringa pusilla, Linn. Little Sandpiper, Lath. 136. Tringa hypoleucos, Linn. Common Sandpiper, Lath, Fam. Rauuipz. Genus Parra. 137. Parra pheenicura. Gallinula phenicura, Lath., Ind.Orn. Red- tailed Gallinule, Lath. Poule-Sultane de la Chine, Buff. 138. Parra Sinensis, Gmel. Chinese Jacana, Lath. 139. Parra Indica, Lath., Ind. Orn. Indian Jacana, Lath. Genus Rallus. 140. Rallus niger, GGmel. Black Rail, Lath. Genus Porphyrio. 141, Porphyrio hyacinthinus. Fulica Porphyrio, Linn, Purple Water- hen, Edw. Fam. Zoological Society. 459 Fam. CuarapRiaDz. Genus Vanellus. 142, Vanellus Goensis. Tringa Goensis, Lath. Vanneau armé de Goa, Buff. 143. Vanellus ventralis. Charadrius ventralis, Wagl. Spur-winged Plover, Hardw. 144. Vanellus bilobus. Charadrius bilobus, Gmel. Bilobate Sand- piper, Lath. Genus Cursorius. 145, Cursorius Asiaticus, Gmel. & Lath. Courvite de la Céte de Co- romandel, Buff. Genus Himantopus. 146. Himantopus melanopterus. Charadrius Himantopus, Linn. L’ Echasse, Buff. Genus Charadrius. 147. Cuaraprivs uiaticuLoipes. Char. supra griseo-fuscus ; fascid frontali alterdque verticali, corpore subtus, collariqgue nuchali albis ; lined sub oculis ad aures extendente, fascia ad frontem, torqueque pectorali subgracili ad nucham extendente nigris ; rectricibus, duabus mediis exceptis, albis, in medio nigro et griseo-brunneo notatis, fasciam semilunarem exhibentibus. This bird differs chiefly from the European species in size, being at least one third smaller, and in the narrowness of the pectoral band. Orpo V. NATATORES. Fam. ANATIDZ. Genus Anser. 148. Anser Indicus, Lath., Ind. Orn. Barred-headed Goose, Lath. 149. Anser melanotos, Gmel. Black-backed Goose, Lath. 150. Anser Coromandeliana, Gmel. Sarcelle de la Céte de Coroman- del, Buff. Anas Girra, Hardw. Girra Teal, Lath. Genus Anas. 151. Anas arcuata, Cuv. Siley Teal, Lath. The name of this bird in India is Siley or Silhei, from its whistling note ; the English call it whistling Teal ; it scarcely differs from the Javanese species as figured by Dr. Horsfield. 152. Anas Crecca, Linn. Common Teal, Lath. This bird is the common Teal of India, and agrees exactly with the British species. Fam. Cotympipa. Genus Podiceps. 153. Podiceps minor, Lath., Ind. Orn. Little Grebe, Lath. Fam. PELECANIDZ. Genus Carbo. 154. Carbo fuscicollis. Phalacrocorax fuscicollis, Shaw. Brown-necked Shag, Lath. Genus Plotus. 155. Plotus melanogaster, Gmel. Black-bellied Darter, Lath. Genus Slerna. 156, Sterna melanogastra, Temm. Hlirondelle de mer a ventre noir, Temm. 3N 2 August 460 Roological Society. August 23, 1831. Joseph Smith, Esq. in the Chair. Two letters from Mr. J. B. Arnold of Guernsey were read, con- taining particulars of his experiments in the naturalization of Sea Fishes in a lake chiefly supplied with fresh water. The area of the lake is about five acres ; its depth various ; and its bottom also va- rious, being muddy, gravelly, and rocky. The water is during nine months of the year drinkable for cattle, but in consequence of a supply which it receives through a tunnel communicating with the sea, is rather salt in sammer, at which season the freshes do not come down so plentifully as at other times. The fishes introduced into the lake have been the grey Mullet, Sole, Turbot, Brill, Plaice, Basse, Smelt, and grey Loach. All of these have thriven well, and are believed to have increased in numbers: the grey Mullet espe- cially is known to have bred as freely as in the sea itself. A single Whiting having been caught for three successive years, was found to have grown considerably : a Pilchard also throve well. All the above-mentioned fishes were placed ia the lake, except perhaps the Brill; but others, as the silver Bream, appear to have introduced themselves. It is even suspected that hybrid fishes have been pro- duced, as several have been caught which were unknown to persons well acquainted with the species usually met with on the coast of Guernsey. Mr. Arnold adds that Sea Fishes, after having been naturalized in his lake, have been transferred to ponds of spring water, where they have not only lived, but done well; and that such naturalized fishes have been carried to a long distance, being much more tenacious of life than those caught in the sea. Numerous specimens of Hylurgus Piniperda, Latr., presented to the Society by Barlow Hoy, Esq., were exhibited, together with specimens of the shoots of Pzxes perforated by these insects. The mode in which the young branches are destroyed by these perfora- tions has been illustrated by Mr. Lindley in Mr. Curtis’s ‘British Entomology’. Its effect was regarded by Linnzus as analogous to that of pruning. The exhibition of the collection of Fishes formed at the Mauritius by Mr. Telfair, portions of which had been brought before the Com- mittee at the Meetings in April, was resumed. From among them Mr. Bennett pointed out more particularly the following species hich he believed to have been previously undescribed. Serranus Detissiu. Serr. mazillis squamosis ; lobis pinne cau- dalis elongatis, equalibus ; radio tertio pinne dorsalis producto : superné stramineus, rubro cancellatim rivulatus, inferné lilacino- ruber ; pinnis ventralibus aurantiaco-flavis. D.+9. A. ; Affinis, ut videtur, Serr. Borbonio, Cuv. et Val. Corpus altum, al- titudo longitudinis (exclusa pinna caudali) dimidium zquans. Pinne pectorales ventrales longitudine equantes. Preoperculi angulus spina unicé magna armatus. SERRANUS MITIS. Serr. mazillis alepidotis ; radio ultimo pinna- rum dorsalis analisque elongato: corpore elongato: argenteus, dorso obscuré flavo-brunneo ; pinnis flavo tinctis ; dorsali nigro tenuiter submarginata. Reo. vA: Serr. Zoological Society. 461 Serr. filamentoso, Cuv. et Val., longior : corpus, prasertim ad hu- meros, crassius: oculus major : vertex rugosus (in Serr. filamentoso granulosus tantum): dentes antici superiores conici utrinque qua- tuor debiliores (in Serr. filamentoso majores utrinque duo): color pallidior, flavescens. Serranus TELFAIRII. Serr. maxillis alepidotis ; radio ultimo pinne dorsalis analisque elongatis : saturate roseus, dorso laté citrino maculato, posticé albidus ; lateribus argenteo viltatis, gut- tatimque conspersis ; pinna dorsali anticé citrind, basi roseo-, apice niveo-maculatd. D. +4. A- 3 Affinis, ut videtur, Serr. zonato, Cuy, et Val., quem numero ra- diorum equat, cujusque formam, etiam pinnarum, emulat. Differt pictura,’et presertim lateribus argenteo vittatis guttatisque. The latter two species form an interesting addition to a section of the genus Serranus distinguished by the elongation of the last ray of both the dorsal and the anal fin. Two other species of this sec- tion have been described by MM. Cuvier and Valenciennes, to whom they have only very recently become known. Of one of these, Serr. filamentosus, as well as of the two new species above described, spe- cimens are contained in the Mauritius collection. Diacore Ancutus. Diac. stramineo-flavescens, infra pallidior ; wittis corporis utrinque septem lilacinis, supertoribus obliquis, infe- rioribus longitudinalibus, 4ta 5tdque antice connexis angulum acutum postopercularem formantibus ; pinne dorsalis parte mollz superne tenuiter nigro marginata. D.t. Awd. Affinis, ut videtur, Dzac. duodecimlineata, Cuv. et Val.: numerus radiorum idem, vittaeque haud operculum signant. Dentes maxille superioris externi conici, distantes, subequales, duo anteriores an- gulares solum majores ; maxille inferioris minores, tres laterales medii utrinque majores. Denrex LycoGEnts. Dent. macillistransversim dentato-cristatis : dentibus conicis anticis sex, maxille inferioris lateralibus majort- bus : plumbeus, wittis dorsalibus plurimis argenteis, ventralibus distantibus fusco-flavis ; macula elongata argenteo-alba sub basi postica pinne dorsalis ; pinnis ventralibus, pectoralibus, dorsalt analique anticé rubris, caudali flavida. +h. A.3. DAscyLLus UNICOLOR. Dasc. corpore alto unicolore nigricante. D.tt. A. + Forma Dasc. marginati, Cuv. et Val. Hetases axituanis. Hel. pallid? ceruleo-fuscus?; axilla nigra; pinnis, presertim caudal analique, ceruleo-nigrescentibus. D.44. A.-r Affinis, ut videtur, Hel. anali, Cuv. et Val. Radius secundus pinnz analis fortior, sequentes longitudine aliquantulum superans. Cor- pus ovatum., Juuis Cuviert. Julis caudé subquadratd : pinne dorsalis radio primo longissimo (quam tertius triplo longiore): rufescenti-brun- neus 462 Loological Society. neus ceruleo punctulatus ; capite virescente, vittis tribus latis rufis ; pinnis dorsali analique luteis, sanguineo oblique lineatis, nigro laté marginatis, ceruleoque fimbriatis ; hujus fascia margt- nali lined ceruled longitudinali media alterdque ad basin notata. Doyen. sr. OP. 125 eas. This new species of Julis is one of those fishes, now becoming nu- merous, which might be confounded with the Julzs Aygula, ( Coris Aygula, LaCép.). The latter appears to have hitherto rested solely on the figure and description preserved by Commerson, no specimen of it having been referred to as existing in collections. A specimen of that species has, however, recently been added to the Society's Museum from a collection of fishes formed in India, and agrees well with the figure published by LaCépéde, in the truncation or even sublunation of its caudal fin, and in its general form; in its dried state its colour is uniformly dull blackish brown. This specimen was ex- hibited in illustration of the distinction between Julis Cuvier and Julis Aygula, and also to show that the fish figured under the latter name by Dr. Riippel differed in various particulars, especially in the rounded form of its caudal fin, from the species indicated by LaCé- péde. To M. Riippel’s fish, it was remarked, the name of Julis Ruppelii might properly be applied. ANGUILLA MauritiAna. Ang. mazilld superiore breviore, obtusd; rostro complanato ; pinne dorsalis initio pectoralibus quam anala propiore; lined laterali conspicud : dorso fusco pallidoque gutta- tim marmorato, lineolisque nigrescentibus interteatis notato ; pin- nis fusco nebulosis. leet Mr. Bennett availed himself of the opportunity afforded by the exhibition of the several species of Pterois contained in the Mauri- tius collection, to bring before the Committee a fish which he had formerly regarded as the Pterois volitans, under which name it was included in the catalogue of Sumatran fishes appended to the me- moir of Sir T. Stamford Raffles. It formed part of the collection presented to the Society by its founder and first President. It was thus characterized: Prerois Russet. Pter. gents spinosim late lineato-serratis ; osse infra-orbitali antico preoperculoque inferné spinosissimis : cirris parvis sex, nasali utringue duobusque infra-opercularibus : pinnis pectoralibus caudalis basin attingentibus. D.33. A.g. P.13. Kodipungi. Russel, Coromandel Fishes, No. 133. September 13, 1831. |W. Yarrell, Esq. in the Chair. At the request of the Chairman the following notes of a dissection of the Alligator Tortoise (Chelydra serpentina, Schweig.) were read by Mr. Martin. They were illustrated by preparations of the sto- mach ; of the iliwm and colon ; and of the cloaca, with the penis and urinary bladders: a drawing of the latter was also exhibited ; and a drawing of the throat, representing the esophagus and trachea in their natural positions, «The animal was a male, and most probably young : its ee rom - Soological Society. 463 from the nose to the anus being | foot 11 inches, and from the anus to the end of the tail G6 inches. The length of the carapace was 11+ inches, and its breadth, following the curve, | foot 1 inch. “On the plastron being removed, and the scapule (which are united to it by intervening muscles) being turned back, the heart, inclosed in a peritoneal sac, was exposed; the scapula in their natural posi- tion extending over it like an arch: next, and in the same cavity, (for there was no division either by muscle or membrane, ) the liver was seen, divided into two distinct portions, and stretching com- pletely across from side to side: below the liver and occupying what may be called the pelvic portion of the cavity, lay the intestines, among which on the right side was seen the colon or commencement of the large intestines enfolding the spleen. «‘ The heart consisted of one ventricle and two auricles, the right of which was the largest. The figure of the auricles was rounded, each in magnitude equalled the ventricle: both auricles contained coagulated blood. ‘The ventricle was in shape acuminate, of a red colour, and firm and fleshy in structure. Its carnee columne@ were strong, distinct, and numerous, but did not separate it into cells or chambers. «« The liver consisted of two lobes. The right lobe was divided into two parts. On its inferior surface was situated the gall-bladder buried in its substance and containing dull green bile: the duct barely half an inch long. The edge of the left lobe of the liver co- vered the stomach, which passing under it fitted an elongated furrow in the thick part of the lobe, and was closely united to it by the peri- toneum. The outer curvature of the stomach was placed in contact with the parietes of the carapace. The texture of the liver was soft and spongy, easily broken down, and pouring out an abundance of dark green fluid, with which it was saturated. The gall duct en- tered the duodenum 6 inches below the pylorus. The under surface of the liver on the right side was connected to the duodenum, and partially to the lung on the same side, by peritoneal attachments. «On the liver being removed the course of the intestines was more fully exposed. Beginning with the esophagus, which immediately on proceeding from the pharynx becomes firm and muscular (the fibres being longitudinal), we find it dipping down on the right side of the neck, keeping a straight course, passing under the right cla- vicle, then crossing below the great arch of the neck within the shell, and passing under the right laryngeal branch to the cardiac portion of the stomach; its length being 7 inches. The cardium passes over the left laryngeal branch, The length of the stomach is 7+ inches; the circumference of the thickest part 3 inches; gently narrowing to the pylorus. Its texture was firm and muscular, especially at the pyloric portion; and between the peritoneal and muscular coats numerous small white points were observed, which on being cut into were found to arise from the presence of minute worms, of three or four lines in length, coiled up under the peritoneum. « The small intestines were strong and thick: their length 3 feet ll inches, ‘Their internal surface presented longitudinal ad At their 464 Zoological Society. their termination in the large intestines there appeared the rudiment of a cecum. «Encircled by a fold of the colon was situated the spleen, of a dark red colour, and soft spongy structure, almost round in shape, and of the size of a small egg: several tortuous veins proceeded from it, and the veins and arteries of the mesentery in general were of the same character. «‘ The length of the large intestines was 1 foot’7 inches; the mus- cular coat was particularly distinct; the villous smooth}; and several black patches were observed on its surface, which exhibited great vascularity. «‘ The urinary bladder was double, or rather it might be said that there were two bladders, lying on opposite sides of the rectum, and adhering to the sides of the pelvis, each communicating by a distinct opening into the commencement of the cloaca. Their size and shape was that of a small pear: their texture very thin and fibrous, the fibres being irregularly disposed. “« The penis, 2+ inches long, lay concealed entirely within the cloaca. It was grooved along its upper surface with the furrow usual in the Tortoises, but instead of being free or disengaged, was attached by a close union throughout its whole length on the under side to the cloaca. The glans was acuminate, and full an inch from the anus. From this union of the penis to the cloaca it is difficult to conceive that it can ever be protruded externally, especially when its distance from the external orifice of the cloaca is considered. The duct of the right bladder, in length half an inch, was found to terminate just above the furrow of the penis, while that of the left opened an inch on one side of it. «The testes were about the size of a pigeon’s egg, elongated, of a bright ochre colour, and situated in the pelvic portion of the abdo- minal cavity, one on each side of the vertebral column ; their struc- ture was soft and somewhat granular. There were no suprarenal capsules. Beneath the ¢estes lay the kidneys, large, irregular in figure, glandular in structure, consisting of brain-like reduplications, and dipping between the interstices of the three lowest ribs, (or rudiments of ribs,) on each side of the vertebral column. “ The palate was smooth, with slight transverse ruge ; the pha- rynx wide, simply membranous, and capable of great extension; the tongue a smooth cartilaginous point, at the base of which the laryna opened by a very small simple rima. ‘There was no epiglottis; but around the rima aslight fold of the membrane was just percep- tible. The laryna crossing before the pharyna dipped down on the left side of the neck, and passing under the left clavicle, divided into two great branches, at about afoot from the rima: the right branch passed before the esophagus, and immediately entered the right lobe of the lungs; the left passed under the cardiac portion of the sto- mach to the left lobe. “The lungs consisted of two large and equal lobes, distinct, flat, and dark red, extending from the upper edge of the carapace as far as the pelvis, but not as in the Land Lortoises (the Indian and i or Intelligence and Miscellaneous Articles. 465 for example) attached to the whole inner surface of the shell ; their attachment was by one of their edges only to the vertebral column, and slightly to the liver. Their texture was firm, and their cells, though large, were not so irregular as in the Testudo Graca. « Between the lungs passed two singular muscles, retractors of the head, long and slender, which arising one on each side by a ten- dinous origin from the base of the cranium passed on each side of the neck, and coming in contact below its great curve, ran together down the vertebral column, and were inserted into its sides in the spaces between the 6th and 7th and 7th and 8th ribs, each by two distinct fleshy terminations. ‘«« The difference exhibited by this animal in the attachments and conformation of the lungs from the family of Tortoises in general indicates an approach, not merely in external configuration, but in internal structure, to the Alligators. Nor, although it must be con- fessed in a degree less striking, is this approach unevidenced by the structure of the urinary crgans; the bladder in this species although double is yet small, while its enormous volume in the Tortozses in general is a singular feature in their construction: the diminution of volume in this organ seems to afford another indication, not to be overlooked, of an approach to the Saurian Reptiles. *« The posterior zaves opened by two distinct orifices one quarter of an inch from the commencement of the palate and three quarters from the point of the beak: their course was obliquely upwards, and the length of each canal to the external orifice just 1 inch. “ The os hyoides consisted of an irregularly shaped body and four arched bones or processes united to it by cartilage ; from the ante- rior part of the body aspinous process partly cartilaginous proceeded to support the rudiment of atongue. The anterior pair of arched bones were connected to the base of the skull by muscles only; the second pair terminated in a broad and flat extremity, and were more abruptly curved: their use seems especially to support the pharynx, and they were not connected to the skull. The first pair were each 4 inches in length ; the second little more than 3 inches. The rings of the /arynz were perfect ; the length of the laryngeal branches 3 inches.” LVIII. Intelligence and Miscellaneous Articles. ON MUDARINE. D—D*: DUNCAN has published in the Transactions of the Royal Society of Edinburgh for the present year, an account of the active principle of the bark of the root of the Calotropis Mudarii or Mudar, which he kas called Mudarine. The bark of this root has been highly esteemed among the natives of India as a specific for the cure of cutaneous and various other diseases ; Dr. Duncan has found, however, that it possesses no specific virtue, but that it is nevertheless extremely valuable from its common medicinal properties, which cor- respond both in kind and in degree with those of ipecacuanha, To obtain mudarine, the powdered root is to be digested in cold N.S. Vol. 10. No. 60, Dec. 1831, 30 rectified 466 Intelligence and Miscellaneous Articles. rectified spirit ; when the greater part of the spirit has been distilled, the solution becomes deeper coloured, but retains its transparency. As the temperature declines, a white granular resin is deposited by a species of crystallization ; the whole is then allowed to dry spon- taneously, that all the resin may concrete ; the dry residuum is then treated with water, which dissolves the coloured portion, and leaves the resin untouched ; the solution contains mudarine. By exposure to the air, it dries readily, forming a mass of a pale brownish colour, perfectly transparent and homogeneous in appear- ance, having no tendency to crystallize, but becoming full of cracks, diverging from the centre, exceedingly brittle, and having no adhe- sion to the capsule containing it, from which it peels off spontaneously. It has no smell, and is intensely bitter, with a very peculiar nauseating taste. It is exceedingly soluble in cold water, at the ordinary tem- perature of the atmosphere. It is also soluble in alcohol, but the power of this solvent is increased by raising the temperature. It is insoluble in sulphuric ether, oil of turpentine, and olive oil. It is in the solution in water, when nearly saturated, that the pecu- liar property of mudarine is most easily exhibited. At ordinary temperatures this solution is quite fluid and transpa- rent. When heat is gradually applied, it suffers at 74° slight dimi- nution of transparency and limpidity ; these changes increase with the temperature, so that at 90° its transparency is nearly lost, and it acquires the consistence of a tremulous jelly ; but if it be then suf- fered to cool, it recovers in a day or two its original limpidity and transparency. If, instead of withdrawing the heat when it has risen to 90°, it be further increased, other changes occur ; at 95° it is fully gelatinized, and now there appears to be a separation taking place into two parts, a soft brownish coagulum and a liquid nearly colour- less, not unlike the separation of the serum from the crassamentum of the blood, as it spontaneously contracts. At 95° the coagulum contracts in size, while the fluid increases in proportion ; at 130° it seems to dissolve ; probably, however, it is only reduced in size by contraction ; at 185° the coagulum is very small, and has a tenacious pitchy consistency, and at 212° little further change occurs. The alterations which in this state it undergoes on cooling are next to be observed. At 140° the fluid is very turbid, the coagulum i is not diminished, and is hard and brittle ; at 110° the fluid is less turbid, the coagulum remarkably brittle, with a resinous fracture ; at 100° the fluid is more transparent, with thin detached pellicles on the sur- face. When cooled down even to the freezing temperature, the cva- gulum remains unaltered, and very much resembles colophony ; but, after the lapse of several days, it gradually liquefies in the portion of fluid in contact with it, without passing through the intermediate form of ajelly. The coagulum, when separated from the fluid, is a transparent brown mass, exceedingly brittle, not deliquescent; frag- ments angular, lustre resinous, taste bitter and nauseous, adhering to the teeth. In this state it seems at first not to be soluble in distilled water, but after some days it is dissolved in it, with the same phenomena as in Intelligence and Miscellaneous Articles. 467 in the fluid from which it was separated by boiling, and the solution has acquired its original properties. The dry mudarine is readily soluble in rectified spirit, and is not precipitated from the alcoholic solution by the addition of water. As long as any considerable por- tion of spirit remains, it is not coagulated by increase of temperature ; but on allowing the spirit to evaporate by exposure to the air, it re- mains dissolved in water, and has re-acquired its original properties. It would therefore seem that its tardy solubility, after being con- tracted, is owing to the state of increased aggregation ; for when this is removed by alcohol, its solubility is quickly restored. Mudarine is also extracted by the action of cold water from the powder, but it is not so easily separated from a gummy matter also dissolved, as from the resin extracted along with it by rectified spirit. Its pre- sence is, however, sufficiently demonstrated by the cold infusion gra- dually losing its transparency as its temperature is increased, and in this case it regains its former transparency, even after having been subjected for some time to the boiling temperature. We therefore see, that, in this instance a very active principle is more readily dissolved by cold than by boiling water; and it is pro- bable that there are other instances in which heat is improperly em- ployed, with the view of extracting the active principles of vegetable substances. PREPARATION OF OXICHLORATE OF POTASH. BY M. SERULLAS. When chlorate of potash is heated in a glass tube or a porcelain crucible, it fuses, boils, and yields oxygen gas. When the fire is properly managed, and after ebullition has taken place for a certain period, the mass thickens, and a moment arrives at which no more oxygen is given out without increasing the heat : if the operation be then stopped, and the salt dissolved and filtered, a great quantity of oxichlorate of potash is) obtained in small brilliant crystals; 40 parts of chlorate yielded in this way 17°5 of oxichlorate. It appears from the experiments of M. Serullas, that chlorate of potash requires a temperature higher than that of boiling mercury for its decompo- sition, and the oxichlorate a temperature considerably greater. The moment at which chlorate of potash is converted into oxichlo- rate, is ascertained by occasionally putting a spatula into the salt, and withdrawing a small portion of it. This is to be powdered, and treated with a little muriatic acid; if it gives a yellow colour, then some chlorate still remains unconverted.—... ey ot Te Onn 313 S Angle from Angle from “2 |8'Z |Sidereal| Mean |, ~|Sidere: M Taare, 9 ae time. |solartime.| $6 § pba nolakiachil ae § = (3 zu] 5 zm! 3s Dis OY hPa tl es |e m0] ey ema gs 5 21 30] 4 23 1174]185/21 57| 4 51 |214| 229 6 (2653) 2 6] 8 51 | 95)128] Under\horizon.| ... | -.. ats 5 | 255123 58] 6 23/103] 76/ 1 6| 7 31 |307/291 possuee 4 | 293} 8 56| 15 20 | 125] 164} Underlhorizon.| ... | -. 5°6 | 379} 250} 911] 53] 46) 3 28] 9 49 | 349} 350 3°4| 478/21 19] 3 37 | 99] 61/22 10] 4 27 | 293) 253 6 | 508) 0 59 7 161128} 90] 1 59 8 17 | 268 | 238 5 | 510} 118} 7 35 | 18] 343)|) almost touching Star.— Occulted to places further North. 5°6| 516} 155} 812] 61] 29] 2 42] 8 59 |333)310 1 | 528} 4 46; 11 2] 48] 53) 5 25| 11 42 | 340) 355 5°6 | 663; 0 58] 7111120} 79) 155] 8 9 |266| 227 56| 2 29] 8 42 | 290] 254 20|\2 Geminor.} 6 | 951) 2 49) 8 55 | 35/354) 3 23) 9 28 | 325| 284 22\Regulus,...| 1 {1209/13 44] 19 39 | 68]105|14 45] 20 40 | 250/290 * Double Star. METEOROLOGICAL OBSERVATIONS FOR OCTOBER 1831. Gosport :—Numerical Results for the Month. Barom. Max. 30-428. Oct. 17. Wind N.—Min. 29-231. Oct. 1. Wind S. Range of the mercury 1-197. Mean barometrical pressure for the Month .......cssceeceereereeeeee 29-904 Spaces described by the rising and falling of the mercury............ 4-865 Greatest variation in 24 hours 0:594.—Number of changes 16. Therm. Max. 68°. Oct. 6. Wind S.W.—Min. 40°. Oct. 29. Wind N.W. Range 28°.—Mean temp. of exter. air 57°°58. For 31 days with © in 59°68 Max. var. in 24 hours 19°-00.— Mean temp. of spring water at 8 A.M. 54:30 De Luc’s Whalebone Hygrometer. Greatest humidity of the atmosphere, in the evening of the 12th...... 97° Greatest dryness of the atmosphere, in the afternoon of the 5th...... 61-0 Rane onthe Wudex seve deeeteceranenneee teddideertsecccs te eces uc vase eoce eames 36-0 Mean at 2 P.M. 72°-6.—Mean at 8 A.M. 78°1.— Mean at 8 P.M. 82:0 of three observations each day at 8, 2, and 8 o’clock ......... 776 Evaporation for the month 1-60 inch. Rain in the pluviameter near the ground 4-835 inches. Prevailing wind, South-west. Summary of the Weather. A clear sky, 2; fine, with various modifications of clouds, 13; an over- cast sky without rain, 8; foggy, 4; rain, 74.—Total 31 days. Clouds. Meteorological Observations for October 1831. 471 Clouds. Cirrus. Cirrocumulus. Cirrostratus. Stratus. Cumulus. Cumulostr. Nimbus. 19 i 30 1 19 24 ee Scale of the prevailing Winds. N. N.E. Es Shee oS: SaWeaewWin ) NEW. Days. PR RE Semeeky Ts ER rep OTR ck 31 General Observations. — This month has been remarkably mild for the season, but windy and very wet, it having rained more or less on twenty- three days, and the amount is one inch and a half more than the mean depth of October for a series of years; the rain was cften accompanied with brisk gales from the South-west. From the absence of frost the mean temperature of the external air this month is four degrees higher than the mean of October for many years past; and the temperature of spring water has decreased very little from its maximum for the year. A large lunar halo presented itself several hours in the evening of the 16th, and solar halos on the 28th and 30th. On the 29th at 10 P.M. an aurora borealis appeared, and rose slowly till a quarter past 11, when its lower arch was at its greatest height in the magnetic north, viz. about 16° and 73° in extent on the horizon, At this time a few columns of light ascended from beneath the arch, but they were thin and rather faint, and did not reach much higher than the head of the Dragon. By 12 o’clock the aurora had disappeared, and was followed by a gale of wind in less than twenty-four hours. The atmospheric and meteoric phanomena that have come within our observations this month, are, one lunar and two solar halos, eight meteors, two rainbows, an aurora borealis, and eleven gales of wind, or days on which they have prevailed, namely, two from the South, seven from the South-west, and two from the West. REMARKS, London. — October 1. Cloudy and warm: rain. 2, Cloudy: fine- 3, 4. Fine: rain at nights. 5—7.Fine. 8. Cloudy: heavy rain and thunder at noon: foggy. 9. Overcast:fine. 10.Fine. 11.Rain. 12. Continued rain, becoming very heavy at night; depth amounting to the unusual quan- tity of one inch in twenty-four hours. 13. Rain: cloudy and windy at night. 14. Fine: showers. 15. Stormy and wet: clear. 16, 17. Fine. 18. Foggy. 19.Veryfine. 20. Overcast: fine. 21.Rain:clear. 22, Stormy, with rain. 23. Rain: clear. 24. Fine: overcast. 25. Rain: clear and fine: windy, with rain at night. 26. Slight showers: rain and thick fog at night. 27.Rain. 28. Very fine. 29. Slight fog: fine. 30,31. Fine. Penzance.—October 1.Fair: showers. 2.Fair. 3,4. Rain. 5,6. Fair. 7. Rain: fair. 8.Showers: fair. 9.Fair:rain. 10. Fair: showers. 11. Fair. 12. Fair: showers. 13.Fair: rain. 14—17.Fair. 18. Rain. 19. Fair. 20.Rain. 21.Fair. 22,23. Rain. 24. Fair. 25.Showers. 26. Rain. 27. Fair: showers. 28—30.Fair. 31. Fair: showers. Boston. — October 1. Rain: rain early a.m. 2, Cloudy: rain early a.m. 3. Cloudy: rain at night. 4,5. Fine: rain early a.m. 6.Rain. 7. Fine. rain early a.m. 8.Fine:rainr.m. 9.Cloudy. 10.Fine. 11. Cloudy. 12. Cloudy: rain p.m. 13.Cloudy. 14. Rainand stormy. 15—17. Fine. 18. Foggy. 19, 20. Cloudy. 21. Rain. 22. Fine: stormy night. 23. Cloudy: rain a.m. and p.m. 24. Fine. 25. Cloudy. 26. Fine. 27.Cloudy: rainatnight. 28.Fine. 29,Cloudy. 30.Fine. 31.Cloudy. Metcoro- one Ses eee 9-1 _T€ | EL | $0-60 [182-68 BZP-0€ | 01-62 | O£-06 9FZ-62 |€ch-08 ~» | Gy. |upeo| «ms | “Mm [ems | 6] oo | 6G | LP | SS | eP | 09 | P9-62 |S12.0£ |SSz-08 OL-0€ | S1.0€ ‘Lg tof 11Z-0€ |1E vee | eee | om | om [om lems | oh] 0S | PS | Sh | SS | LP | 09 | €4-6% |GLZ-08 |BI€-08 | SI-0F ZB-OE 0G7-0E 608-0€ |0€ vee | eee leuqeo} sm [tan | ems] gh] oP | 6S | Lb | 99 | 1€ | 19 | $L:6% |88Z-0€ |OLE-0€ | 02.08 ZB-OE QRZ-OE |S1E-0£ |6% fo. | vt [ran | om | om | ems [6-2b] LP | 8S | LP | 99 | 6€ | 29 | P62 jOZ1-0£ 862-08 06.6% | S1-0€ 660-0€ |0Fz.0F 8% ») ot. | St |'mn| ‘s |*ms| s | oS] oS | LG | LP | SG | OF | 19 | ST-6% 969-62 FOL-6% | 09.6% | 09.6% 269: 62 |6EL-62 |La zg. | ts | cm [ems | ems} +s 6.29] £5 | 09 | oF | SG | 0S | 19 | 16-g2 |PES.62 9F9-62 OP.6% | OF.6% 'GES-66 179.6% 9% Ly. | csr | tm | ts [ems] cs | PS] €S | 09 | oF | BS | IS | 29 | FZ-6z |6£9.62 |€88-62 01-68 | 086% 969-62 |668-6z |S% “lop. | om [em [mn | cm | Lp] SS | 89 | gh | 8G | €S | 19 | SP-6% |STI-O€ 9E1-0€ 00-08 | 00-08 \L90-0€ |660-0€ Fe 11. | tt | cms frms | tas] sa | 9S] 0S | 29 | SS | 19 | OP | 29 | 92-62% $26.62 |$66-62 69-66 | 06-62 SZB-4Z |6P6-6z £% cy. | | tm [ems | cms] +s | gh] 99 | 69 | gh | 09 | 19 | 19 | o-6% |L96.6z |€80-0€ | $8.62 06.6% 916-62 |£90-08 ZG ws loz. | cm | om | cm | ems} 9S| 6P | 09 | gh | SS | LE | 09 | $a-6% |L96-62 |SL0-0£ | 98-60 | 98.6% L€6-62 |SE0-0€ 12 O ot. | 1 | wyeo| «s | ms] ss | €¢] FS | zo | ZS | 69 | ES | £9 | SE-6% |626.6z |E£0.08 | 08-62 06-62 16-62 |Z00-08 0% vee | e+ lunvo| «a | us | sas | 09] 99 | 29 | 39 | Zo | SP | 19 | 99-66 |£80-08 |8zz-0£ | OT-0€ | O1.0€ bL0-0€ |F9t-0€ 61 ++ | oy. |wyvo| «a | as | +s | gg] So | zo | PS | Zo | €S | £9 | 08-62 |TSE-0€ |ZOE-08 | ST-0F | O6-0£ SOL-OF /BIF-0€ 8I so [eee | om | em | ce | ms 16-66] P9 | zo | 6F | 09 | GP | SO | 89-62 |89E-0£ \BzP-O£ | O£-08 | O€- 0€ ILE: -0€ |ftP-0€ Lt ve | veel om leu fean | os | pol eb | 19 | of | 6S | EF | LO | ZS-62 [908-08 |ZPE-0F | OT-0€ | 8Z-0F 8Z1-0F PIE-0£ 91 zo. |S. | a |ems |u| ‘s | LG] gh | 29 | €9 | 19 | 1P | SO | LI-6% |€6L.62 |8L6-62 | SL 62 00:08 |P6S-6% 000-0€ SI co. | ss | ca [ems | ta | ts 16-66] SS | 9 | FS | oo | SS | $9 | 16-92 /PE9.6z |S0L-62 | OF-62 | 08-62 029-66 Ggl-6c Pt go. | *** jwyeo} +s | ‘s | ‘s | 9S] 09 | G9 | FS | 69 | 19 | 89 | 40-62 |169-62 899-62 | O£-6% | PP-6% \SLS-62 |Fg9-62 let 00-1/ OL. | ** |ms| ‘as | ‘s | ZG] SS | Po | €S | 09 | GP | 99 | €1-62 |899-62 jOPL-6z | 09-62 | 09-6% 289-60 PEL.6z ZI zz. | ‘|x| ss [tus] ‘s | 9g] Zo] 19 | PS | 19 | PS | 29 | $0.62 |62L-62 |EPL-6z| 09.62 | 09. 6% ‘O1L-6z |PEL-62 | iu vee | ome lemanl ems | cms] *s 19-96] LG | 29 | oS | ZO | 9S | 29 | 00-62 |PPS-62 |PL9-62 | S9.6% | $9.62 SPS-66 799-63 | ol lol | St. wea) «ms |} -s | *s | SS} PS | 19 | Bh | 69 | OS | 9 | 90-62 969.66 £9L:62| $9.66 | 09-62 999-62 |0L-60 6 gg. | *** |wyeo| m | sm | “* | 69] £9 | 19 | FS | ZO | SP | 8S | C1-62 |FE9-6% 669-62| $S-6z | 09:62 ££9-6z |g0L-6z 8 ve | oe | os log tems] 8 | 291 99 | Lo | 9S | zo | 19 | EL | 11-60 | 12-62 |€€L-62 | 09.6% | 09-62 £E9.60 ae A ‘90: | St. |*@Nj ems | ms} *s | LG} 09 | 89 | SS | SO | 8S | 89 | 6z-60 |€26.60 |LP6.62 91.62 | 08-63 16:62 |8z6-6z 9 vee | eee [omy | om | cm | tas [6.96] S¢ | £9 | aS | zo | 0S | 99 | bz-62 |£96-62 990-08 | 18.62 | 8-62 ‘406-66 8£0-08 |S © go. | ttt [AN | ms | tm | “8 | 9G] PS | ZO] ZF | ZO | ZS | LO | 11-66 |648-6z 026-62 | 8L:6% | 8L-6% (608-62 G68: 60 of. | 0€.0| “4 | «ms | ems | tas} ZG] 99 | 99 | #9 | F9 | PS | OL | Fo-6z |60L.62 994-62 | SS-6% 09.6% \LOL-6z |€9L-6% € io. | | | +s | ss | 8 | Zo] SS} Zo} $$ | €9 | Lh | OL | aL-92 |OPE-6z 919-62 | 01-6z 0£-6% |1€£-62 |LZS-6z |% €0.0| “7° | ‘4s | cas | cas |S /$z9/ 69 | $9 | SG |_€9 | $9 | 4 | So-Be 1£2-6% PZE-6B | 01-62 | 01-66 \9bZ-62 |$60-60 |t_ “YO | o = w a S 3 oe “LOW “xUN ‘WN *xelW “OHA | “XV wiv 4g “Ul *xVl “ULI “Xe “TH *xeW ‘1881 aio | ais b| alee j40dso5 hn sis. ‘uopuo’7T |uojsog}| + “j40dsop *a0URZUdg ‘uopuoT ‘qquoyy Sl Je | en ais ee jo skugy I “CRAG “PULA *1IJOWIOWIIY, T, “19JOWIOIVET U0J80 JD TIFAA “Py pun quodsoy jo AANUNG “Mcp ‘aounxUaT O10. \090- opo. |** 010: |°** ope’ |S9e- oze. \06L: ole. | **° 0€%. |0c€- oSt. \olz- OZ: |OPI- s+ 1060: oor. |°** Olz-. \SZe- 08g: |SEL- ols, |*" ofo. |SOL- O@s- OTL. OIG: \O81-0 obo. | * Oot. |°*" Slo. | °"" O10. SPIT ORGar |e" 090. | *"* 020.0 OVL-O O | ° i) ~~ 1-8 “wey qo SUID py 49 fuopuo'yT dmau Fyounsiyy yo hyavwog qounynoyLoyy ay7 fo uapunsy ayy wv NOSdWOK,L, py Ag appu suoynasasggQ yordopooajapy CE 4 Fig L3 tad neu line id df : neutral line # rrr aN neural line ha otiom of Homogeneous Mi vidiea. Sorter Scalp, I } i f , y - < ~ Fig 19 p - a eS Be os j To ~We ) i} ( , 0) 4a ey ad ee | ny ,) 3 ee bere) E J | ~ = hel) ———— te ae — WC CHurgeons Capfterume nhs on the MhermoMaspetion of Homogencots Wocles Phii. Mag. & Annuals N. 3. Voll0 Plate 2. , Yl Ya nills hey she L- Vy WHOAET ; PINS i. | aid ay i Ss A ‘art To be had of Messrs. Treuttel and Wirtz, Treuttel, Jun. and Richter, 30 Soho-Square; and R. Hunter, St. Paul’s Churchyard. LE PROTESTANT DE GENEVE, JOURNAL THEOLOGIQUE ET RELIGIEUX. Je vous parle comme a des personnes intelligentes; jugez vous-mémes de ce que je dis.—(1 Cor. x. 15.) L* publicité, ce besoin si général de notre époque, est devenu aussi pour |’Eglise de Genéve une nécessité qu'il n’est plus possible de méconnaitre, et devant laquelle, par conséquent, il n’est plus permis de reculer. D’une part, les amis de cette Eglise demandent 4 ses con- ducteurs de manifester au public religieux quels sont les principes qui la dirigent aujourd’hui; d’autre part, ses ennemis prennent occasion de son silence pour attaquer sa doctrine, calomnier ses actes, et la taxer elle- méme de crainte ou d’infidélité. C’est donc pour répondre 4 la fois a ces demandes et a ces attaques que plusieurs membres de cette Eglise, ecclé- siastiques et laiques, croient devoir fonder un journal. Dans un premier numéro, ils exposeront en détail quelles sont Jeurs vues générales et particuliéres. Les unes et les autres se trouvent déja résumées dans le titre qu’ils ont adopté. Le Protestant de Genéve aura pour but de développer et de défendre les principes du Protestantisme, tels qu’ils sont actuellement compris et rofessés dans l’Eglise nationale de cette ville, oi, depuis trois siécles, ils ont porté, par la bénédiction du Trés-Haut, des fruits de liberté et de piété, qui n’ont pas été sans gloire. e journal recevra avec reconnaissance tous les renseignements qui ourraient lui étre transmis sur l'état religieux de la Suisse ou de étranger. Ami des Eglises chrétiennes et tolérantes qui seraient troublées par le faux zéle de l’exclusisme, il leur offre un moyen de dé- fense et de publicité qui, peut-étre, ne leur sera pas inutile. Le Protestant de Genéve paraitra le 1 et le 15 de chaque mois par cahiers de 20 a 30 pages d’impression. Les lettres et envois divers doivent étre adressés, francs de port, au bureau du journal, chez M. Abraham Cherbuliez, libraire, au haut de la Cité, a Genéve. Le prix de l'abonnement est, pour Genéve et la Suisse, de 10 fr. de France pour un an. 6 fr. id. pour six mois. Pour la France et autres pays, #15 fr. pour un an, 7 fr. pour six mois. ON 8S’ABONNE A Genéve, chez M. Ab. Cherbuliez ; A Paris, méme maison, rue de Seine St. Germain, No. 57 ; Et chez les principaux libraires de la France et de !’étranger. CONTENTS or Ne 55.— New Series. I. On the Thermo-Magnetism of Homogeneous Bodies ; with illus- trative Experiments. By Mr. WM. SturGEON, Lecturer on Experi- mental Philosophy at the Hon, East India Company’s Military Aca- demy, Adiscombe. (With a Plate.) (To be continued) ..... wo page I II. On Simple Elimination, By J. E. Drinkwater, Esq....... 24 a II, On the Solar Eclipses and Transit of Mercury over the Sun’s Disc in 1832. By Prof. ENCKE..... BE be Ln ae Re 28 IV. Of the Conditions of Life. By the Rev. Parrick KEITH, BLL. S.( Lo, be continued). « VII. On some Problems in Analytical Geometry. By J. W. Lus- BOCK, Esq. V.P. & Treas. R.S @eeeececee eeoeoe esos etree eseeaee page 81 VII. Particulars of the Measurement, by various Methods, of the instrumental Error of the Horizon-Sector described in Phil. Mag. vol. lix. By Joun Nixon, Esq. (To be continued) .........-.... 88 IX. Notes on some recent Improvements of the Steam-Engines in Cornwall. By W. Jory Henwoop, F.G.S. Member of the Royal Geological Society of Cornwall..............++eeeeeness Bs pies ae, X. On Chemical Symbols and Notation; in Reply to Professor Whewell. By Mr. Joun Pripeaux, Member of the Plymouth PeSEM GLOW 03. cic s aisiaieis ose secs n.e sete Capes PAS, 1 Fuk os ee XI. On Poonahlite, a new Species of Mineral; on the Identity of Zeagonite and Phillipsite, &c,; and other Mineralogical Notices. By ~ H. J. Brooke, Esq. F.R.S.L.S. & G'S. ........... sicies PEERES oars 109 XII. On the Theories of Achromatization, &c.in Reply to Dr. - » Goring. By the Rev. H. Coppineron.,......... es ae Raetiet ale 112 XIII. On the Thermo-Magnetism of Homogeneous Bodies; with illustrative Experiments. By Mr. Wm. Srurceon, Lecturer on Ex- perimental Philosophy at the Hon, East India Company’s Military — Academy, Adiscombe ............... PPAR eae ats a i oa niet . 116 XIV. Of the Conditions of Life. By the Rev. Parrick KEITH, -— BLS cia bis eisentieteta nin Site & pao weeleranh essa ook A als ok anatre dee ve Lee XV. On the Statement in the Nautical Almanac for }833, of the Time of Beginning of the Solar Eclipse of the 16th of July in that Year; together with the correct Times of that Eclipse, computed —~ for Greenwich. By GrorceE Innzs, Esq........... SUES Sy ee ieee XVI. Errata in Schumacher’s Ephemeris of the Distances of the ° - four Planets Venus, Mars, Jupiter, and Saturn, from the Moon’s — Centre, &c. for 1833, published by the Admiralty. By A Corre- XVIII. New Optical Experiments by Professor Airy. ........ 141 XIX, Proceedings of Learned Societies :— Geological Society ; ZQGIOR ICH ROUEEY ya ore es no rdle i's 3s: etedy ap iw Sane wes's gl bmg le -- 143-150 XX. Intelligence and Miscellaneous Articles:— General Scientific Meeting at York; On the Rapid Flight of Insects; Process for pre- paring Hydrocyanic Acid; Vanadium, a New Metal ; Magnesium; On Oxalic Acid, by M. Gay-Lussac ; On Gallic and Pyrogallic Acid, by M. Henri Braconnot; Analysis of Tennantite, by J. Hemming, Esq.; New Patents ; Occultations of Planets and Fixed Stars by the Moon in August 1831; Meteorological Observations for June — 18315; Tablepiscas a 2 See Sta es “wo eels a Speen folic paves Pama 150-160 *,° It is requested that all Communications for this Work may be addressed, | post paid, to the Care of Mr.R. Taylor, Printing Office, Red Lion Court, Fleet Street, London; where complete Sets of the Old Series of the Phi- | losophical Magazine may be had at half of the original price, wh This Day is Published, A LETTER to Dr. DAVID BOSWELL REID, Experimental As- sistant to Dr. Horr, &c.; in answer to his Pamphlet entitled *¢ An Exposure of the Misrepresentations in the Philosophical Magazine and Annals,” &c. By RICHARD PHILLIPS, F.R.S. L.& E., &c. - Samuel Highley, 174 Fleet Street. Price 1s. Just Published, in quarto, Price Thirty Shillings, Illustrated by Nine Engravings; viz. Four large folding Plates of the Survey of _ the Thames, and: the Instruments employed ; One Quarto and Two folding Plates ; of the Graphical Registrer of the Tides and Wind ; and Two Quarto Plates of _ Magnetic Apparatus, and Illustrations of the paper on Negative Quantities ; | HE PHILOSOPHICAL TRANSACTIONS OF THE ROYAL . SOCIETY of LONDON, 1831, Parr I. Contents :—Capt. Rozertson’s Observations on the Comet of 1822, _—Prof. Bartow on Fluid Refracting Telescopes.—Mr. Luszocx’s Re- "searches in Physical Astronomy.—Mr. W. Snow Harris on the Trans- ient Magnetic State of different Substances.—Mr. Davies GILBERT on _ Negative and Imaginary Quantities,—Prof. BARLow on the Phenomena _ of Terrestrial Magnetism.—Mr. Ivory on the Equilibrium of Fluids, and : 4 _ the Figure of a Homogeneous Planet.—Prof. Davy on an Electro-Che- mical Method of Detecting Metallic Poisons.—Mr,. Barry on Atmo- ? esc Electricity. —Mr. Lioyp’s Survey of the River Thames, from Lon- a on Bridge to the Sea.—Mr. Fox on the Variable Intensity of Terrestrial _Magnetism.—Mr. Patmer on a Graphical Registrer of the Tides and -Wind.—Prof. Bartow on the Errors in the Course of Vessels from Lo- _ eal Attraction.—Mr. Lussock on the Meteorological Observations made at the Royal Society.—The Meteorological Journal of the Royal Society, _ from June to December 1830. _— THE POLYTECHNIC LIBRARY. HE design of the Publishers of the «« POLYTECHNIC LIBRARY” ; is to produce a series of highly instructive Works, which the pub- lic may be tempted to buy, because they will be cheap,—be induced to read, because they will be brief,—be competent to understand, because they will be clearly written,—and be able to profit by, because they will e Works or Pracricat Uriciry. Every Volume, therefore, will Eontain a complete Treatise, relating to one of the useful Arts or Sci- neces, or the Chemical or Mechanical Trades. ‘This day is Published, Vol. I. of the « POLYTECHNIC LIBRARY,” neatly printed in 18mo, and illustrated by numerous Engravings, price wo Shillings, bound in Cloth, containing - The ART OF GLASS-BLOWING ;; or Plain Instructions for making the Cuemicat and Puitosornicar Instruments, which are formed of lass, such as Barometers, Thermometers, Hydrometers, Tube Vessels, Toys for Chemical Experiments and Recreative Philosophy. By a Printed for Bumpus and Griffin, 3 Skinner Street, London; Richard Griffin & Co., Glasgow, and Stillies, Brothers, Edinburgh :—By whom will shortly be Published Vol. II. of the Poryrecunic Lisrary, containing the DOMESTIC CHEMIST; or Instructions for the Detection of Adul- terations in Food ; and Vol. III. containing the PERFUMER’S ORA- LE; or Art of Preparing Perfumes and Cosmetics. CONTENTS or N° 57.—New Series. XXI. OnIsomorphism. By H. J. Brooke, Esq. F.R., L.,& GS. page 161. XXII. Exposition of a New Dynamico-Chemical Principle. By Mr. Joun JamES WATERSTONE,........-.265-- b aibiaays aboshenitalivbs 170 XXIII. An Examination of M. Virey’s Observations on Aéronautic Spiders, published in the Bulletin des Sciences Naturelles. By JoHN BLACK WALES SiGe HET e lao elaks: she ebeielsiv nial othlecre « fe dates SO XXIV. On Mengite, a new Species of Mineral; on the Characters of Aeschenite ; on Sarcolite, as distinct from Analcime and Gmelinite ; with other Mineralogical Notices, By H. J. Brooxs, Esq. F.R., L., ad Git IG a ER const on Aina SAN ie oi aad, ale -chaypte yore keene 187 — XXV. On a New Register-Pyrometer, for Measuring the Expan- sions of Solids, and determining the higher Degrees of Temperature ' upon the common Thermometric Scale. By J. FrepERic DANIELL, Esq. F.R.S, (With a Plate) (To be continued),......... Ma SER Fast - 191 XXVI. On the Theory of the Compressibility of the Matter com- . posing the Nucleus of the Earth, as confirmed by what is known of the Ellipticities of the Planets. By the Rev. J. Cuaxtis, Fellow of the Cambridge Philosophical Society... ..............e0000 ee: 200 XXVII. Analysis of some Salts of Mercury. By R. PHiLuips, Bose Ware BC Hy BEC oes go 3 ios en's! tie ate or nie oom tual haley piel ate Seine ao XXVIII. Experiments on Vanadiate of Ammonia, and on some other Compounds of Vanadium. By Mr.Joun PripEAux, Member of the Plymouth Institution :,..; <0 cise: otic ciecee eee Byere.s 7" 209 XXIX. Notices respecting New Books: — Dr, Paris’s Life of Sir Humphry Davy. (To be continued) ..........-0.eeaeeees snaimeeeaa XXX. Proceedings of Learned Societies: — Royal Society; | Zoological Society ........ Boies as» iy e.'es at yale mtigrer Osama -. 223-235 XXXI. Intelligence and Miscellaneous Articles:— Preparation of Iodic Acid, by Arthur Connell, A.M.; New Scientific Books; Mr. Saull’s Geological Museum; Occultations of Planets and Fixed Stars by the Moon in September 1831 ; Meteorological Observations for — July 1831 ; Table, &c..... Maecenas 2 tas’ 6) cuneate hats hat ee 235-240 Fleet Street, London; where complete Sets of the Old Series of the Phi losophical Magazine may be had at half of the original price, DR. WEBSTER’S ENGLISH DICTIONARY. DICTIONARY OF THE ENGLISH LANGUAGE, intended to exhibit:—1. The Origin and the Affinities of every English Word, as far as they have been ascertained, with its Primary Signification, as now generally established.—2. The Orthography, and the Pronunciation of Words, as sanctioned by reputable Usage, and where this Usage is di- vided, as determinable by a reference to the Principle of Analogy.— 3. Accurate and Discriminating Definitions of Technical and Scientific Terms, with numerous Authorities and Illustrations. ‘To which are pre- fixed, An Introductory Dissertation on the Origin, History, and Connec- tion of the Languages of Western Asia and of Europe, and a concise Grammar of the English Language. By N. WEBSTER, LL.D. This Work will appear in 12 Parts, each consisting of 20 Sheets, form- ing 2 vols.4to. It is not a mere improvement on Johnson’s Dictionary, but an original work, the labor of 30 years, and contains 12,000 words more than any other similar work, In respect to Etymologies and Affi- nities, it supplies the grand desideratum in English Lexicography. *,* Part XI. is just published, Price 9s. Vol, I. may be had in Cloth Boards, and Lettered, 31. 3s. The Proprietors of Dr. Wesster’s EnciisH Dictionary have pur- chased from the family of the late Rev. JonatHan Boucuer, Vicar of Epsom, the valuable and voluminous MSS. which he had, during the last fourteen years of his life, prepared for a“ GLOSSARY of PROVIN- CIAL and ARCHAZOLOGICAL WORDS,” intended as a Supple- ment to Dr. Johnson’s Dictionary: and they mean to publish these MSS. in One Volume, 4to. as a Supplement to Dr. WensTER’s Encuisu Die- TIONARY. The larger portion of the MSS. is in a state fit for publica- tion; and the Supplement will be commenced as soon as the work of Dr. Wessrter is completed. They also intend to publish an OCTAVO Edition of Dr. Wesster’s Encuisn Dictionary, which will contain all the technical and scientific definitions of the Quarto Work, but without the copious etymological matter, which will not be required by general readers for ordinary purposes. A multitude of Words collected by the Editor, will be inserted; and also a large collection of ARcHAIc TERMS from the MSS. of the late Rev. JonatHan Boucuen. Published by Black, Young, and Young, Foreign Booksellers to the King, 2 Tavistock Street, Covent Garden. CONTENTS or N° 58.—New Series. XXXII. Researches on some of the Revolutions which have taken place on the Surface of the Globe; presenting various Examples of the Coincidence between the Elevation of Beds in certain Systems of Mountains, and the sudden Changes which have produced the Lines of Demarcation observable in certain Stages of the Sedimen- tary Deposits. By L. Ex1z pz BEAuMoNT...... cove creas a npage Dal XXXIII. On an undescribed Bird of the Family Falconide, By JoHN BLACKWALL, Esq. iF.LAS. 100). cdinn seve cs cee sa nnneeels »+- 264 XXXIV. On Monticellite, a new Species of Mineral; on the Cha- racters of Zoizite; and on Cupreous Sulphate of Lead. By H. J. BROOKE, Esq. Pj Ug BGS. pac ae ciate ins = a;5ial'e nt ieee peas 265 XXXV. On a New Register-Pyrometer, for Measuring the Ex- — pansions of Solids, and determining the higher Degrees of Tempera- ture upon the common Thermometric Scale. By J. FREDERIC DantELL, Esq. F.R.S. (To be continued) ..........+ aS a egnte ae 268 XXXVI. On the Calculation of the Orbits of Double Stars. By Professor ENCKE (To be continued) ...... 0... 20es ceee rene wewics ee XXXVII. New Method of Levelling the Axis of a Transit Instru- ment, “ By' 5. Wrsons Rise sh .75 ioe hae oth 's nes a che iano enn 284 XXXVIII. Notices respecting New Books:—Young’s Elementary Treatise on the Differential Calculus ..................0020000- 287 XXXIX. Proceedings of Learned Societies: — Royal Society ; Loclopical 'Seciety'< ii. 27070 0 287. a NE es Oe, oe 293-313 XL. Intelligence and Miscellaneous Articles:— Red Colouring Matter produced by the Action of Nitric Acid upon Alcohol, &c. by M. Rouchas; Perchloric Acid; Red Solutions of Manganese ; Powerful Electro-Magnet; Marking-Ink for Linen ; Monthly Ame- rican Journal of Geology and Natural Science; Mr, Harvey’s Re- searches on Naval Architecture; List of Patents ; Occultations of Planets and Fixed Stars by the Moon in October 1831 ; Meteoro- logical Observations for August 1831 ; Table, &c........... . . 313-320 *," It is requested that all Communications for this Work may be addressed, post paid, to the Care of Mr. R. Taylor, Printing Office, Red Lion Court, Fleet Street, London; where complete Sets of the Old Series of the Phi- losophical Magazine may be had at half of the original price. Just published, Price 6s. in Cloth, ee Se ON THE MANUFACTURES IN METAL: Vol. 1. Iron and STEEL. Being Vol. 24 of “ Dr. LARDNER’s CABINET CycLoPz=pIA.” Published Oct.1, History of France. By E, E. Crowe. (3 Vols.) Vol, I1I.—To be published Dec. 1, Lives of DistincuIsHep BritisH Mitirary ComMAnpERs. By the Rev. G. R. Grete. (3 Vols.) Vol. I. Printed for Longman and Co., and John Taylor. DR. WEBSTER’S ENGLISH DICTIONARY. DICTIONARY OF THE ENGLISH LANGUAGE, intended to exhibit:—1. The Origin and the Affinities of every English Word, as far as they have been ascertained, with its Primary Signification, as now generally established.—2. The Orthography, and the Pronunciation of Words, as sanctioned by reputable Usage, and where this Usage is divided, as determinable by a reference to the Principle of Analogy.— 3. Accurate and Discriminating Definitions of Technical and Scientific Terms, with numerous Authorities and Illustrations. To which are pre- fixed, An Introductory Dissertation on the Origin, History, and Connec- tion of the Languages of Western Asia and of Europe, and a concise Grammar of the English Language. By N. WEBSTER, LL.D. This Work will appear in 12 Parts, each consisting of 20 Sheets, form- ing 2 vols,4to. It is not a mere improvement on Johnson’s Dictionary, but an original work, the labour of 30 years, and contains 12,000 words more than any other similar work, In respect to Etymologies and Affi- nities, it supplies the grand desideratum in English Lexicography. *,* Part XI. is just published, Price 9s. Vol. I. may be had in Cloth Boards, and Lettered: 31. 3s. . The Proprietors of Dr. Wesster’s ENciisn Dictionary have pur- chased from the family of the late Rev, JonatHan Boucuer, Vicar of Epsom, the valuable and voluminous MSS. which he had, during the last fourteen years of his life, prepared for a ““ GLOSSARY of PROVIN- CIAL and ARCHZOLOGICAL WORDS,” intended as a Supple- ment to Dr. Johnson’s Dictionary: and they mean to publish these MSS. in One Volume, 4to. as a Supplement to Dr. WezstER’s Encisn Dic- -gionary. The larger portion of the MSS. is in a state fit for publica- tion; and the Supplement will be commenced as soon as the wor of Dr. _ WexzsTER is completed. They also intend to publish an OCTAVO Edition of Dr. Wesster’s Enciisn Dictionary, which will contain all the technical and scientific definitions of the Quarto Work, but without the _ copious etymological matter, which will not be required by general readers for ordinary purposes. A multitude of Words collected by the Editor, _ will be inserted; and also a large collection of ArcHAIc TerMs from _ the MSS. of the late Rev. Jonatuan Boucuer. _ Published by Black, Young, and Young, Foreign Booksellers to the King, 2 Tavistock Street, Covent Garden. CONTENTS or N°59.—New Series. XLI. On Vanadium. By M. Berzetus (To be continued)... page 321 XLII. Particulars of the Measurement, by various Methods, of the Instrumental Error of the Horizon-Sector described in Phil. Mag. vol. lix. By J. Nrxon, Esq. ( To be continued) .......+.- pee OOl XLII. Notice on Oxalic Acid. By Epwarp Turvyer, M.D. F.R.S. L. & E, &c., Professor of Chemistry in the University of London,....... bee Patt «8 EES ae Betas sone alee eseeg 988 XLIV. On a New Register-Pyrometer, for Measuring the Ex- > pansions of Solids, and determining the higher Degrees of Tempera- ture upon the common Thermometric Scale. By J. FREDERIC DANTEMM E60. hMedee's siajeiiarneieged > usidwtienles eid ale I ae AEs 350: XLV. Correction of a Quotation in a Paper “On the Impediments to the Study of Natural History,” published in the Phil. Mag. and — Annals for May, 1831, By W. S, MacLeay, Esq. M.A.F.LS., &e. 357 XLVI. Notice of a Geological Survey of the Mines of Cornwall ; with a Programme of an intended Arrangement of the leading De- tails of the Metalliferous Veins, &c. By W. Jory Henwoop, F.G.S. 358 _ XLVII. Experiments on the Disinfecting Powers of increased Temperatures, with a view to the Suggestion of a Substitute for Quarantine. By Wir1i1am Henry, M.D. F.R.S, &c...... ews. OOS XLVIII. Notices respecting New Books:—Mr, Rennie’s Edition of Montagu’s Ornithological Dictionary; Dr. Paris’s Life of Sir Humphry Davy, Bart. ( To be continued) .........ee0eeees - 370-386 XLIX. Proceedings of Learned Societies : —British Association for the Promotion of Science; Zoological Society ........... 387-392 L. Intelligence and Miscellaneous Articles: — On the Atomic Weight of Barytes, by Dr. Thomson; On the Oxichlorates, by M. Serullas; Occultations of Planets and Fixed Stars by the Moon — in November 1831; Meteorological Observations for September 1831; Table, &c.; Calendar of the Meetings of the Scientific Bodies _ of London for 1831-32........ Sy thee vr,k a brat ol mene . 892-400 — *,” It is requested that all Communications for this Work may be addressed, post paid, to the Care of Mr. R. Taylor, Printing Office, Red Lion Court, Fleet Street, London; where complete Sets of the Old Series of the Phi- losophical Magazine may be had at half of the original price. y 0 f i ‘ fs ‘Sharpe (S.). On the Solid of greatest Attraction. Children (J. G.) F.R.S. On Ochsenheimer’s Genera of Lepidoptera. Articles in the Philosophical Magazine and Annals for June, July, August, September, and October, 1830, and November 1831. Vernon (Rev. W.V.) F.R.S. Chemical Examination of artificial Brucite. Herapath (W.). On the Combustion of the Diamond. Schmidt (Dr. E.). On the Dimensions of the Earth. Ivory (J.) F.R.S. On the Figure of the Earth. And, On the shortest Di- stance between two Points on the Earth’s Surface. Lubbock (J. W.) F.R.S. On the Census. Farey (J.). On Improvements in the Steam-engine. Taylor (J.) F.R.S. On the Duty of Steam-engines in Cornwall. MacLeay (W.S.) F.L.S. On the Dichotomous Method in Natural History. Roget (P.M.) Sec. R.S. Letter in refutation of an alleged Inaccuracy in the Minutes of the Council of the Royal Society. Gilbert (Davies) Pres. R.S. On the same subject. ~ Babbage (C.). F.R.S. Lucasian Professor of Mathematics, Cambridge, on the same Subject. Nixon (J.). On the Measurement (by Trigonometry) of the Heights of the principal Hills of Swaledale, Yorkshire. Galbraith (W.) M.A. On the Obliquity of the Ecliptic. Witham (H.) F.G.S. On the Vegetable Fossils found at Lennel Braes, near Coldstream, upon the Banks of the River Tweed. Bevan (B.). On the Power of Horses. Alison (R. E.). Narrative of an Excursion to the Summit of the Peak of Teneriffe in February 1829. De la Beche (H. T.) F.R.S. On the Geographical Distribution of Organic Remains in the Oolite Series of England and France. Sabine (E.) Capt. R.A. Sec. R.S. Notices occasioned by the Perusal of a late Publication by Mr. Babbage. Rumker (C.), Elements of the Comet in Pegasus ; with Observations and Elements of the same Comet, by M. Valtz, of Nimes. Fleming (Rev. Dr.). Note on Mr. MacLeay’s Abuse of the Dichotomous Method in Natural History. Sedgwick (Professor) and Murchison (R. I.), Esq. Pres. G.S. Sketch of the Structure of the Austrian Alps. , 2 Prideaux (J.). On the mean Atomic Weights of Simple Bodies, according ' to Thomson and Berzelius. Yarrell (W.) F.L.S. On a new Species of Swan. r Challis (Rev. J.). A tempt to explain theoretically the different Refran- gibility of the Rays of Light. ; Noggerath (Prof. J.). On the Magnetic Polarity of two Rocks of Basalt near Niicburg in the Eifel, ; Meikle (H.). On the Giconomy of the Steam-engine. * Conybeare Rev. W.D.). On Mr. Lyell’s ‘‘ Principles of Geology. Squire (T.). On the computed times of a late Occultation of Aldebaran. Berzelius (M.). On Vanadium. Nixon (Mr.). On his Horizon Sector. Turner (Dr.). On Oxalic Acid. Daniell (Prof.). On his New Register-Pyrometer. Henwood (W.J.). On a Geological Survey of the Mines of Cornwall. Henry (Dr.). On a Substitute for Quarantine. CONTENTS or N° 60.—Mew Series. LI. On Isomorphism. In Reply to Mr. Brooke, [With a Note on Mr, Prideaux’s remarks on Chemical Notation.] By Professor Wnrewent, of Cambridge.............-+---- cetcvses »+..- page 401 LII. Unequal Refrangibility of Light on the Undulatory Theory. By A CoRRESPONDENT........ Perea vi his a one's ve Seid Anite seth iy 442 LIII. On the Symmetrical Functions of a specified Number of the Roots of an Equation. By the Rev. R. Murruy, Fellow of Caius Coll. and of the Cambridge Philosophical Society. .............. 413 LIV. A Description of New Succulent Plants of the Natural _ Orders Bromeliacee, Tulipacee, Crassulacea, Euphorbiacee, Cactee, Ficoidee. By A, H. Hawortn, Esq. F.L.S. &.......... 00000 414 — LV. Additional Remarks on Isomorphism. st aes J. - Brooxg, Esq. PRS LAGOS! 275 250 5. eter. ol sdngeee ie as 424 LVI. Notices respecting New Books Zee Paris's Life of Sir Humphry Davy, Bart. ; Mr. Rennie’s Edition of Montagu’s Orni- thological Dictionary (To be continued) ............4..... 426-433 LVII. Proceedings of Learned Societies : —Geological Society ; Linnzan Society ; Astronomical Society ; Zoological Society.. 433-465 LVIII. Intelligence and Miscellaneous Articles :—On Mudarine; Preparation of Oxichlorate of Potash, by M. Serullas; Separation of Antimony and Tin; Dr. Gregory on White's Ephemeris; On Vanadium, by Mr. Johnstone ; List of New Patents ; Occultations of Planets and Fixed Stars by the Moon in December 1831 ; Metéaro: logical Observations for October 1831 ; Table, &c........... 465-472 Py Itvis requested that all Communications for this Work may be doesnt post paid, to the Care of Mr. R. Taylor, Printing Office, Red Lion Court, Fleet Street, London; where complete Sets of the Old Series of the Phi- : losophical Magazine may be had at half of the original price. ;