LIBRARY UNIVERSITY OF CALIFORNIA. Class UNIVERSITY OF CALIFORNIA LIBRARY OF THE .DEPARTMENT Of PI IYOIOO - p . . NOV 14 19-11 , Received .. Accessions No. (&./.%.. Book No. L2... PROPERTIES OF MATTER BY THE SAME AUTHOR. LIGHT. Third Edition. In crown 8vo, cloth, price 7s. 6cL DYNAMICS. In crown 8vo, cloth, price 7s. 6d. NEWTON'S LAWS OF MOTION. In crown 8vo, cloth, price Is. 6d. net PROPERTIES OF MATTER P. G. TAIT, M.A., SEC. R.S.E. HONORARY FELLOW OF ST. PKTKR'S COLLEGE, CAMBRIDGE, PROFESSOR OP NATURAL PHILOSOPHY IN THE UNIVERSITY OF EDINBURGH FIFTH EDITION EDITED BY W. PEDDIE, D.Sc., F.R.S.E. HARRIS PROFESSOR OF PHYSIOS IN UNIVERSITY COLLEGE, DUNDER, UNIVERSITY OF ST. ANDREWS LONDON ADAM AND CHARLES BLACK 1907 T3 First Edition published April, 1885 ; Second Edition, October, 1890 ; Third Edition, June, 1894 ; Fourth Edition, November, 1899 ; Fifth Edition, July, 1907. The Right of Translation and Reproduction is Reserved PREFACE. IT is desirable that a work so characteristic as this is should remain, in a new edition, as far as possible in the form in which it left the hands of its distinguished author. The rapid advance of physical science, in the few years which have passed since the last edition appeared, has necessitated some slight additions. In making these, the original plan of the book has been strictly adhered to, and all additions have been placed within brackets and initialed. The work of revision has been a pleasure to me, as a service gladly rendered to the memory of my former master and friend. W. PEDDIE. UNIVERSITY COLLEGE, DUNDEE, June 3, 1907. 222568 PREFACE TO THE FIRST EDITION. THE subject of this elementary work still forms in accordance with tradition from the days of Eobison, Playfair, Leslie, and Forbes the introduction to the course of Natural Philosophy in Edinburgh University. The work is (with the exception of a few isolated sections) intended for the average student ; who is sup- posed to have a sound knowledge of ordinary Geometry, and a moderate acquaintance with the elements of Algebra and of Trigonometry. But he is also supposed to have what he can easily obtain from the simpler parts of the two first chapters of Thomson and Tait's Elements of Natural Philosophy, or from Clerk-Maxwell's excellent little treatise on Matter and Motion a general acquaintance with the fundamental principles of Kinematics of a Point and of Kinetics of a Particle. To have treated these subjects at greater length than has here been attempted would have rendered it imperative to omit much of the development of im- portant parts of preliminary Physics, of which, so far as I know, there is no modern British text-book. The work was peremptorily limited to a small volume; so that the parts of these auxiliary subjects which have viii PREFACE TO THE FIRST EDITION. been admitted are mainly of two kinds : those which are really introductory to the books just mentioned, because treating of matters' usually deemed too simple for special notice ; and a few which are in a sense sup- plementary, because giving valuable results not usually included in elementary books. It is my present intention to complete my series of text-books by similar volumes on Dynamics, Sound, and Electricity. Should I succeed in bringing out such works, I shall thenceforth be enabled to introduce references to one or other, instead of the digressions which are absolutely necessary in every self-contained elementary treatise devoted to one special branch of Physics only. P. G. TAIT. COLLEGE, EDINBURGH, March 5, 1885. PREFACE TO THE SECOND EDITION. LN the present edition this Treatise has been carefully revised and considerably extended : special attention having been paid to passages where a difficulty had been found. For one of the most important additions I am indebted to M. Amagat, who has very kindly enabled me to avail myself of some of his splendid but hitherto unpublished results. These relate to the compression of fluids exposed to enormous pressures ; and, when published entire, will form a singularly interesting and practically new branch jf the subject. To some of the scientific critics of the first edition I am indebted for suggestions of real value, and I have endeavoured to profit by them. I must except, however, those which concern my treatment of the subject of Force. I have seen so much mischief done by this quasi-personi- fication of a mere sense -impression that, even in an elementary book, I am constrained to protest against it. (See 15 of the text.) I feel assured that the difficulties which are now everywhere felt as to the great scientific question of the day, the nature of what we call electricity, ire in great part due to the way in which our modes of x PREFACE TO THE SECOND EDITION. thinking have been, by early training and subsequent habit, encouraged to run in this fatal groove. To some of my other critics, more aggressive because less scientific, I have been indebted for genuine amuse- ment. Nothing is, however, without its use in this world, though it may occasionally be difficult to discover that use. It would seem, then, that the function of the unscientific critics of a scientific book is (like that of the writers of slipshod English) to furnish examiners with rich material for questions of the well-known kind : "Point out all the errors in the following passage." Nothing is more difficult than the attempt to make such passages : and the results are usually forced and awkward. From the critics I allude to they come in perfection. There is one additional remark which I must make. The majority of the illustrations in this work (whether given in words or by diagrams) are, when the contrary is not stated, to the best of my knowledge original. I make the remark lest I should be supposed to have taken them from some of the books in which they have been re- produced without acknowledgment of their source. It is flattering to have one's work thus appreciated, but the honour has its little inconveniences. P. G. TAIT. COLLEGE, EDINBURGH, July 1, 1890. PREFACE TO THE THIRD EDITION. IN spite of what I must still consider a tolerably com- plete statement of my position ( 11-15, 108, etc.), some of my critics persist in accusing me of deliberate incon- sistency in my treatment of Force. I am represented by them as first telling my readers that there is "no such thing as Force," and then introducing utter confusion by the assertion that "Matter is merely the plaything of Force" ! They appear to be unable to perceive that the idea of Force is an essential feature of Newton's Laws of Motion : and that, until we are provided with an effi- cient substitute for Newton's system, we must retain it in its integrity. To have left these statements altogether unnoticed might have been prejudicial to the book itself, in the eyes of the many weak ones who regard the dicta of a critic (especially when he is anonymous) as necessarily authoritative. To take more than this passing notice of them would be to exaggerate their importance. Since the last edition of this book was published, the whole of M. Amagat's splendid experimental results have become generally accessible : and I have made consider- able additional use of them, especially in Chaps. IX. andX. Parts of Chap. VIII. have been considerably modified, xiv PREFACE. and VI. of this work may be referred to a little pam- phlet on Newton' 's Laws of Motion, which has just been issued by the same publishers. In it I have discussed, though with studied conciseness, a good deal of important matter which the plan of this volume prevented me from introducing. The present issue has been kept up to date, so far as recent real extensions of the subjects it treats of are con- cerned. Other engrossing work has (happily ?) rendered impracticable for the moment a scheme which I had con- templated for a thorough revision of the whole plan of the volume. P. G. TAIT. COLLEGE, EDINBURGH, September 19, 1899. CONTENTS. CHAPTER I. PAG* INTRODUCTORY . . . . . ' . 1 CHAPTER II. SOME HYPOTHESES AS TO THE ULTIMATE STRUCTURE OF MATTER ...... 18 CHAPTER III. EXAMPLES OF TERMS IN COMMON USE AS APPLIED TO MATTER ...... 25 CHAPTER IV. TIME AND SPACE . . . ... 48 CHAPTER V. IMPENETRABILITY, POROSITY, DIVISIBILITY . . 83 CHAPTER VI. INERTIA, MOBILITY, CENTRIFUGAL FORCE . . 94 CHAPTER VII. GRAVITATION . . . . . .113 CHAPTER VIII. PRELIMINARY TO DEFORMABILITY AND ELASTICITY . 146 xvi CONTENTS. CHAPTER IX. PAGE COMPRESSIBILITY OF GASES AND VAPOURS . . 161 CHAPTER X. COMPRESSION OF LIQUIDS . . . . .188 CHAPTER XI. COMPRESSIBILITY AND RIGIDITY OF SOLIDS . . 205 CHAPTER XII. COHESION AND CAPILLARITY .... 242 CHAPTER XIII. DIFFUSION, OSMOSE, TRANSPIRATION, VISCOSITY, ETC. . 275 CHAPTER XIV. AGGREGATION OF PARTICLES . . . 296 CHAPTER XV. DISINTEGRATION OF THE ATOM . . . .311 APPENDIX. I. HYPOTHESES AS TO THE CONSTITUTION OF MATTER. BY PROFESSOR FLINT, D.D. . . .316 II. EXTRACTS FROM CLERK-MAXWELL'S ARTICLE "ATOM" 320 III. VITRUVIUS ON ARCHIMEDES' EXPERIMENT . . 335 IV* NOTE ON A SINGULAR PASSAGE IN THE " PRINCIPIA " 336 V. EXTRACT FROM LA IIMOR'S "AETHER AND MATTER" 344 VI. EXTRACT FROM KELVIN'S "BALTIMORE LECTURES" 346 INDEX 350 PKOPEKTIES OF MATTEE. CHAPTER I. INTRODUCTORY. 1. WE start with certain assumptions or AXIOMS, which are by no means of an a priori character, having been forced upon us by the observations and experiments of many generations : (1) The physical universe has an objective existence. (2) We become cognisant of it solely by the aid of our Senses. (3) The indications of the Senses are always imperfect, and often misleading ; but (4) The patient exercise of Reason enables us to control these indications, and gradually, but surely, to sift truth from falsehood. 2. If, for a moment, we use the word Thing to denote, generally, whatever we are constrained to allow has objective existence : i.e. exists altogether independently of our senses and of our reason : we arrive at the follow- ing conclusions : A. In the physical universe there are but two classes of things, MATTER and ENERGY. A 2 ' PROPERTY "o B. TIME and SPACE, though well known to all (in Newton's words, omnibus not!ssima\ are not things. 1 C. NUMBER, MAGNITUDE, POSITION, VELOCITY, etc., are likewise not things. D. CONSCIOUSNESS, VOLITION, eetu, are not physical. 3. So says modern physical science, and to its generally received statements we cannot but adhere. Metaphysicians, of course, who trust entirely to so- called " light of nature," have their own views on this, as on all other subjects ; but the number and variety of these views, some of which are entirely incompatible with others, form a striking contrast to the general con- sensus of opinion on the part of those who have at least tried to deserve to know. In the words of v. Helmholtz, 2 one of the chief modern authorities in science properly so-called : "The genuine metaphysician, in view of a presumed necessity of thought, looks down with an air of superiority on those who labour to investigate the facts. Has it already been forgotten how much mischief this procedure 1 " Space is . . . regarded as a condition of the possibility of phenpmena, not as a determination produced by them ; it is a representation d. priori which necessarily precedes all external phenomena : " "Time is not an empirical concept deduced from any experience, for neither) co-existence nor succession would enter into our per- ception, if the representation of time were not given d priori." - KANT, Critique of Pure Reason ; Max Miiller's Translation. 2 " Hier haben wir den achten Metaphysiker. Einer angeblichen Denknothwendigkeit gegeniiber blickt er hochmiithig auf die, welche sich um Erforschung der Thatsachen bemiihen, herab. 1st es schon vergessen, wie viel Unheil dieses Verfahren in den friiheren Entwicklungsperioden der Naturwissenschaften ange- richtet hat ? " Preface to the German Translation of the second part of Thomson and Tail's Natural Philosophy. INTRODUCTORY. 3 wrought in the earlier stages of the development of the sciences 1 " Clerk-Maxwell develops the contrast somewhat more elaborately : "... In every human pursuit there are two courses one, that which in its lowest form is called the useful, and has for its ultimate object the extension of knowledge, the dominion over Nature, and the welfare of mankind The objects of the second course are entirely self-con- tained. Theories are elaborated for theories' sake, diffi- culties are sought out and treasured as such, and no argument is to be considered perfect unless it lands the reasoner at the point from which he started. . . . " The education of man is so well provided for in the world around him, and so hopeless in any of the worlds which he makes for himself, that it becomes of the utmost importance to distinguish natural truth from artificial system, the development of a science from the envelopment of a craft." Newton, however, had long before expressed essentially the same ideas. He said : "To tell us that every species of things is endowed with an occult specific quality, by which it acts and pro- duces manifest effects, is to tell us nothing; but to derive two or three general principles of motion from phenomena, and afterwards to tell us how the proper- ties of all corporeal things follow from those manifest principles, would be a very great step in philosophy, though the causes of those principles were not yet dis- covered ; and therefore I scruple not to propose the principles of motion above mentioned, they being of very general extent, and leave the causes to be found out." 4 PROPERTIES OF MATTER. Midway between Newton's time and our own, another very great man, Young, spoke as follows of the pernicious effects of metaphysics in the ancient world : " A one of the departments of human knowledge were excluded from the pursuits ... of the Grecian sages, until Socrates introduced, into the Ionian school, a taste for metaphysical speculations, which excluded almost all disposition to reason coolly and clearly on natural causes and effects." Quotations like these might be multiplied indefinitely. But we have given enough to j ustify fully the statements made in the opening section. These statements must be our guide in all that follows. 4. A stone, a piece of lead or brass, water, air, the ether or luminiferous medium, etc., are portions of Matter; wound-up springs, water-power, wind, waves, compressed air, hot bodies, electric currents, as well as the objective phenomena corresponding to our sensations of sound and light, are examples of Energy associated with matter. For the present, at all events, we are in the habit of speaking of Energy as Kinetic when it obviously, or at least certainly, depends on motion of matter. Thus the energy of wind, waves, heat, electric currents, etc., is kinetic. But energy stored up, as in a charged thunder- cloud, a wound-up spring, a "head" of water, is called Potential. Of its intimate nature we as yet know nothing, and it is possible that it may be ultimately kinetic : i.e. dependent upon motions of inscrutably minute parts of matter. 5. All trustworthy experiments, without exception, have been found to lead to the conviction that matter is unalterable in quantity by any process at the command of man. INTRODUCTORY. 5 This is one of the strongest arguments in favour of the objective existence of matter. It was usefully employed, at the very end of last century, by Rumford in his memorable Inquiry concerning the Source of the Heat excited by Friction. 1 It forms also the indispensable foundation of modern chemistry, whose main instrument is the balance, used to determine quantity of matter with great exactness. We may speak of this property, for the sake of future reference, as the Conservation of Matter. It justifies one- half of the statement in 2, A. It is to be remarked here that the statements just made, being the direct result of experiment, are strictly applicable to gross matter only. The Ether or luminiferous and electrical medium is certainly matter, in the sense of having Inertia ( 9), but we have at present no means of investigating its conservation. 6. So far the reader (if he resemble at all the average student of our acquaintance) is not likely to feel much difficulty. His every-day experience must have long ago impressed on him the conviction of the objectivity of matter, though perhaps he may not have learned to express it in such a form of words. But it is usually otherwise when he is told that energy has an objective existence quite as certainly as has matter. He has been accustomed to the working of water-mills, let us say, and he cannot but allow that a " head " of water is something other than the water ; it is something associated with the water in virtue of its elevation. He sees and (if he be of an economic turn) he deplores the terrible waste of water-power which is stupidly permitted to go on all over the world. He allows that water-power does exist, 1 Phil. Trans., 1798. 6 PROPERTIES OF MATTER. but the waste which he laments he looks upon as its annihilation. Till within the last fifty years or so the vast majority even of scientific men held precisely the same opinion. 7. The modern doctrine of the Conservation of Energy, securely based upon the splendid investigations of Joule and others, completes the justification of our preliminary statement. Energy, like matter, has been experimentally proved to be indestructible and uncreatable by man. It exists, therefore, altogether independently of human senses and human reason, though it is known to man solely by their aid. One of the most curious passages in history is that which describes the quest of The Perpetual Motion. This was simply the attempt to discover a continuous Source of fresh mechanical energy. In 1775 the Academy of Sciences declined, for the future, to consider any scheme which professed to furnish work without corre- sponding and equivalent expenditure. But the race of Perpetual Motionists is by no means even yet extinct. The doctrine of the impossibility of the Perpetual Motion is often valuable in modern physics (see, for instance, 139 below), as it furnishes simple ex absurdo proofs of important fundamental theorems. The objectivity of energy is virtually admitted in a curious way, by its being advertised for sale. Thus in manufacturing centres, where a mill-owner has a steam- engine too powerful for his requirements, he issues a notice to the effect, " Spare Power to let." But, of course, the common phrase "price of labour" at once acknowledges the objectivity of work. 8. There is, however,, a most important point to be noticed. Energy is never found except in association INTRODUCTORY. 7 with matter. Hence we might define matter as the Vehicle or Receptacle of Energy ; and it is already more than probable that energy will ultimately be found, in all its varied forms, to depend upon Motion of matter. This is advanced, for the moment, as a mere introductory statement, instances of which will be discussed even in the present work ; but its complete treatment would require the introduction of branches of physics with which we have here nothing to do. One great argument in its favour is, that matter is found to consist of parts which preserve their identity, while energy is manifested to us only in the act of transformation, and (though measurable) cannot be identified. For this is precisely what we should expect to find if energy depends in- variably on motion of matter. 9. Beside their common characteristic, conservation, and in strange contrast to it, we have their characteristic difference. Matter is simply passive (inert is the scientific word) ; energy is perpetually undergoing transformation. The one is, as it were, the body of the physical universe; the other its life and activity. All terrestrial phenomena, from winds and waves to lightning and thunder, eruptions and earthquakes, are transformations of energy. So are alike the brief flash of a falling star, and the fiery glow from the mighty solar outbursts of incandescent hydrogen. 10. From the strictly scientific point of view, the greater part of the present work would be said to deal with energy rather than with matter. In fact, were we to speak of weight as a property of matter, in the sense that a stone of itself has weight, or even in the sense that the earth attracts the stone, we should go directly in the teeth of Newton's distinct assertion. 8 PROPERTIES OF MATTER. For such a statement (because confined to the attract- ing bodies alone) implies the existence of Action at a Distance, a very old but most pernicious heresy, of which much more than traces still exist among certain schools, even of physicists. (See Newton's words on this subject, 160 below.) Gravitation, like all other mutual actions between particles of matter, such as give rise to cohesion, elasticity, etc., must, with our present knowledge, be set down to the energy which particles of matter are found to possess when separated. The intervening mechanism by which this is to be accounted for has, as yet, only been guessed at, and none of the guesses have been succesoM. Clerk-Maxwell's success in explaining electric and magnetic attractions by something analogous to stresses and rotations in the luminiferous ether shows, however, that we need not despair of being able to dis- cover the ultimate mechanism of gravitation. But there is great convenience in separating, as far as possible, the treatment of Mass, Weight, Cohesion, Elasticity, Viscosity, etc., which we range under the general title, Properties of Matter, from that of Heat, Light, Electric Energy, etc., which can all in great measure be studied without express reference to any one special kind of matter though, as forms of energy, they exist only ( 8 above) in association with matter. Along with these forms of energy must of course be treated the allied properties of matter, such as specific heat, refractive index, conductivity, etc. Such, therefore, are foreign to the present work. And it must be remarked that, even in popular language, we invariably speak of the hardness of a body, its rigidity, its elasticity, as belonging to it in much the same sense as does its density or its atomic INTRODUCTORY. 9 weight and certainly in a much more intimate sense than does its temperature or its electric potential. It is, therefore, on the two grounds of custom and convenience that we use the term Properties of Matter as the title of this work. The error involved is not by any means so monstrous as that which all agree to perpetuate hy the use of the term Centrifugal Force. 11. The word Force must often, were it only for brevity's sake, be used in the present work. As it does not denote either matter or energy, it is not a term for anything objective ( 2, A). The idea it is meant to express is suggested to us by the " muscular sense," just as the ideas of brightness, noise, smell, or pain are sug- gested by other senses : though they do not correspond directly to anything which exists outside us. It is exceedingly difficult to realize fully the fact that noise is a mere subjective impression, even when reason has convinced us that outside the drum of the ear then- is nothing to correspond to it except a periodic com pression and dilatation of the air. Still more difficult is it to realize that outside us all it dark; and that the objective cause of even the most gorgeous of optical phenomena is an excessively rapid quivering motion of the ethereal jelly which extends- through all space. We need not, therefore, be surprised at the tenacity with which the great majority, even of scientific men, still cling to the notion of force as something objective. But if it were objective, what an absolutely astounding difficulty would have to be faced by one who tries to explain the nature of hydrostatic pressure; and who finds that by the touch of a finger on a little piston he can produce a pressure of (say) a pound weight on every 10 PROPERTIES OF MATTER. square inch of the surface of a vessel, however large, if full of water, and the same amount on every square inch of surface of every object immersed in it, even if that object consisted of hundreds of square miles of sheets of tinfoil far enough apart to let the water penetrate between them. All this, moreover, is found to disappear the moment he lifts his finger ! When we communicate energy to a body, as in pushing or drawing a carriage, the impression produced upon our muscular sense does not correspond to the energy com- municated per second, but to the energy communicated per inch of the motion. For experiment has proved that what appears to our muscular sense as a definite tension (in a cord, let us say) is associated with the com- munication of energy, to any mass of matter whatever, in direct proportion to the (linear) space through which it is exerted, altogether independently of the speed with which the mass may be already moving in the direction of the tension ; so that in equal times energy is com- municated in direct proportion to that speed. When there is no motion, no energy is communicated ; and this would certainly not be the case if communication of energy corresponded to the time during which the tension was said to act. 12. The muscular sense is far more deceptive than any other, except, perhaps, that of touch. Conjurors, ven- triloquists, perfumers, and cooks make their livelihood by practising on the imperfections of our senses of sight, hearing, smell, and taste respectively. But he who has tried the simple experiment of rolling a pea on the table lietween his first and second fingers, after crossing one- over the other, will at once recognise the extreme deceit- fulness of the sense of touch. And the muscular sense INTRODUCTORY. 11 well deserves a place beside it. So, as we know that there is but one pea, though the sense of touch vividly impresses us with the notion that there are two, we must be very wary when the muscular sense plainly suggests to us the notion of force as an objective reality. 13. Many of the terms which are now used in a strictly scientific sense had a humbler origin, having been devised entirely for the popular expression of common ideas. The term Work is a specially illustrative one. Thus, in a draw-well, the work done in bringing water to the surface would be reckoned at first in terms of the quantity of water raised: two raisings of a full bucket lifting twice as much water as one. But then it was found that, for the same quantity of water raised, the work depended on the depth of the well : doubled depth corresponding to doubled work. Again, if the bucket were filled with sand instead of water, more work was required, in proportion as sand is heavier than water. All these statements were soon found to be comprehended in the simple form : the work done is directly proportional to the weight raised and also to the height through which it is raised. Here the indications of the muscular sense stepped in, and work came to have a general meaning, viz. the product of the so-called force exerted, into the distance through which it is exerted. Had they not possessed the muscular sense, men might perhaps have been longer than they have been in recog- nising the important thing potential energy ( 4) ; but when they had come to recognise it, they would have stated that when water is raised it gains potential energy in proportion as it is raised, and perhaps they might have found it convenient to use a single term for the rate at which such energy is gained per foot of ascent. This 12 PROPERTIES OF MATTER. would probably not have been the word " Force," but it would have expressed precisely what the word force now expresses. Then they would have recognised that when energy is transmitted by a driving-belt, the amount transmitted is (ceteris paribus) directly proportional to the space through which the belt has run. They might have invented a name for the rate of transmission per foot-run of the belt ; they might even have called it the tension of the belt ; but, anyhow, it would be precisely what is now called force. Let us look at the matter from another point of view. 14. A stone, if let fall, gradually gains kinetic energy or energy of motion, and experiment shows that the energy gained is directly proportional to the vertical space fallen through. Hence we have come to say that the stone is acted upon by a force (its weight, as we call it) whose amount is practically the same at all moderate distances from the earth's surface. But, so far as we know the question scientifically, we can say no more than that the stone has potential energy (just as water in a mill-pond has head) in proportion to its elevation above the earth's surface ; and consequently, by the conservation of energy, it must acquire energy of motion in proportion to the space through which it descends. Why it has potential energy when it is raised, and why that potential energy takes the first opportunity of transforming itself into kinetic energy : thus requiring that the stone shall fall unless it be supported : are questions to be approached later. (Chap. VII.) 15. That the statement above is complete, without the introduction of the notion of force, is seen from the fact that a knowledge of the kinetic energy acquired, after a given amount of descent, enables us to determine fully INTRODUCTORY. 13 the nature of the resulting motion even when the stone is projected, obliquely or vertically, not merely allowed to fall. The question is easily 'reduced to one of mathe- matics, or rather of Kinematics, and as such the non- mathematical student must, for the present, simply accept the statement as true. And thus we have another of the many distinct and independent proofs that Force is a mere phantom sugges- , tion of our muscular sense ; though there can be no doubt that, in the present stage of development of science, the use of the term enables us greatly to condense our descriptions. But it is a matter for serious consideration whether we do not connive at a species of mystification by thus employing, in the treatment of objective phenomena, a term for a mere sensation, corresponding to nothing objective: even although it be employed solely to shorten our statements or our demonstrations. Every one knows that matter (e.g. corn, gold, diamonds) has its price ; so (as we saw in 7) has energy. We are not aware of any case in which force has been offered for sale. To " have its price" is not conclusive of objectivity, for we know that Titles, Family Secrets, and even Degrees, are occasionally sold ; but " not to have its price " is at least all but conclusive against objectivity. We are in the habit of speaking of fresh air, sunshine, &c., though obviously objective, as priceless ! 16. These introductory remarks have been brought in with the view of warning the reader that we are dealing with a subject so imperfectly known that at almost any part of it we may pass, by a single step as it were, from what is acquired certainty to what is still subject for mere conjecture 14 PROPERTIES OF MATTER. An exact and adequate conception of matter itself, could we obtain it, would almost certainly be something extremely unlike any conception of it which our senses and our reason will ever enable us to form. Our object, therefore, in what follows, is mainly to state experimental facts, and to draw from them such conclusions as seem to be least unwarrantable. 17. But, for the classification of the properties of matter, whether our classification be a good one or not, it is necessary that we should have a definition of matter. From what was said in last section it is obvious that no definition we can give is likely to be adequate. All that we can attempt, then, is to select a definition which (while not obviously erroneous) shall serve as at least a temporary basis for the classification we adopt. 18. Numberless definitions of matter have been pro- posed. 1 Here are a few of the more important : (a) That which possesses Inertia ( 9). ((3) The Receptacle or Vehicle of Energy ( 8). (y) Whatever exerts or can be acted on by Force. (8) Whatever can be perceived by our senses, especi- ally the sense of Touch. This is closely akin to the well-known definition of matter as a Permanent Possibility of Sensation. () Whatever can occupy space. () Whatever, in virtue of its motion, possesses Energy. (rj) Whatever, to set it in motion, requires the ex- penditure of Work. (0) [Torricelli, Lezioni Accademiche, 1715, p. 25.] La materia altro non e, che un vaso di Circe incan- tato, il quale serve per ricettacolo della forza, e de' 1 A remarkable collection of such (now historical) speculations, due to Professor Flint, is given in Appendix I. INTRODUCTORY. 15 momenti dell' impeto. La forza poi, e gl' impeti, sono astratti tanto sottili, son quintessenze tanto spiritose, che in altre ampolle non si posson racchiudere, fuor che nell' intima corpulenza de' solidi natural!. (0 [The Vortex Hypothesis of Lord Kelvin.] The rotating parts of an inert perfect fluid ; whose motion is absolutely continuous, which fills all space, but which is, when not rotating, absolutely unperceived by our senses. |(/c) Surfaces of misfit in a granular medium. [Hypo- thesis of Osborne Reynolds.] (A) Loci of intrinsic rotational strain in the ether. [Hypothesis of Larmor.] See App. V. (/A) Fundamentally of electric constitution. [J. J. Thomson and Kelvin.] See Chap. XV. and App. VI. , ; It should be noted that, as Larmor has pointed out, the vortex hypothesis gives no account of electric action. W. P.] 19. The mutual incompatibility of certain pairs of these definitions shows that some of them, at least, must be of the so-called metaphysical species ( 3). (a), (/?), (), (rj), above, have much in common, and, with further knowledge, may perhaps be found to differ in expression merely. At present, from want of informa- tion, we cannot be certain that any two of them are precisely equivalent. Berkeley virtually asserted that all motion is produced by the direct action of spirits on matter. Even then, the statement (/3) that matter is the receptacle or vehicle of energy holds good (but how then does energy exist in the spirit ?). But the statement that matter is whatever can exert 16 PROPERTIES OF MATTER. force (y) is to be rejected ; though it was virtually intro- duced by Cotes in his Preface to the second edition of the Principia. (8) must be rejected, if only because there is another thing besides matter (in the physical universe) which we know of, and of course only through our senses ( 1). But this is not all the error ; for we get the notion of force through our muscular sense ( 11), and force is not matter, not even a thing. Torricelli's language is poetical, and therefore his statement (6) must not be taken too literally. In his time, as in all subsequent time till well within the last half century, energy and force were very rarely distin- guished from one another. Even now they are too often confounded. (i), the most recent of these speculations, has the curious peculiarity of making matter, as we can perceive it, depend upon the existence of a particular kind of motion of a medium which, under many of the defini- tions above, would be entitled to claim the name of matter, even when it is not set in rotation. 20. But as we do not know, and are probably incapable of discovering, what matter is, we must content ourselves for the present with a definition which, while not at least obviously incorrect, shall for the time serve as a working hypothesis. "We therefore choose (e) above, i.e. we define, for the moment, as follows : Matter is whatever can occupy space. Experience has proved that it is from this side that the average student can most easily approach the subject, i.e. here, as it were, the contour lines of the ascent ( 80) are most widely separated. INTRODUCTORY. 17 21. A But this definition involves three distinct proper- ties: (1) the Volume, (2) the Form or Figure, of the space occupied ; and (3) the nature or quality of the Occupation. Hence the older classical works on our subject almost invariably speak of matter as possessing (1) Extension, (2) Form, and (3) Impenetrability. It is mainly for the sake of the first of these, and the preliminary discussions which it necessarily introduces, that we have chosen the above definition as our starting-point. 22. Before we take these up in detail, however, it may be useful to devote a short chapter to a digression on some of the more notable of the hypotheses which have been propounded as to the ultimate structure of matter. We advisedly use the word structure instead of nature, for it must be repeated, till it is fully accepted, that the discovery of the ultimate nature of matter is probably beyond the range of human intelligence. Another chapter, of a very miscellaneous character, will follow, devoted to the examination of some of the terms popularly applied to pieces of matter, and a rapid glance at the physical truths which underlie them. This is introduced to give the reader, at the very outset of his work, a general idea of its nature and extent. CHAPTER II. SOME HYPOTHESES AS TO THE ULTIMATE STRUCTURE OF MATTER. 23. THE hard Atom, glorified in the grand poem of Lucretius, but originally conceived of, some 2400 years ago, by the Greek philosophers Demokritus and Leukippus, survives (as at least an unrefuted, though a very improb- able, hypothesis) to this day. Newton made use of the hypothesis of finite, hard, atoms to explain why the speed of sound in air was found to be considerably greater than that given by his calculations ; which were accurate in themselves, but founded on erroneous or, rather, incom- plete data. But in this problem Laplace found the vera causa, and in consequence Newton's apparent support of the hypothesis of hard atoms is no longer available. Many of the postulates of this theory are with difficulty reconciled with our present knowledge ; some have been contemptuously dismissed as "inconceivable." But any one who argues on these lines becomes, ipso facto, one of the so-called metaphysicians. Let us briefly consider the main statements of this theory, but without regard to the order in which Lucretius gives them. 24. Nature works by invisible things : thus paving- ULTIMATE STKUCTURE OF MATTEK. 19 stones and ploughshares are gradually worn down without the loss of any visible particles. Reproduction [i.e. agglomeration of scattered particles so as to produce visible bodies] is slower than decay [i.e. the breaking up of bodies into invisible particles], and therefore there must be a limit to breakage, else the breaking of infinite past ages would have prevented any reproduction within finite time. Hence there exists a least in things [i.e. unbreakable parts or Atoms, "strong in solid singleness "]. But there is also void in things, else they would be jammed together, and unable to move. Here Lucretius takes the case of a fish moving in water, showing that void is necessary in order that it may be able to move. [Our modern knowledge of circulation, i.e. the motion of fluids in re-entrant paths, shows that this reasoning is baseless.] There can be no third thing besides body and void. For nothing but body can touch and be touched; and what cannot be touched is void. [Here we have the germ of the erroneous definition of matter (8) in 18 above.] The atoms are infinite in number, and the void in which they move [space] is unlimited. They have different shapes ; but the number of shapes is finite, and there is an infinite number of atoms of each shape. Nothing whose nature is apparent to sense consists of one kind of atoms only. The atoms move through void at a greater speed than does sunlight. Besides this, there is a great deal of curious speculation as to bow a vertical downpour of atoms [supposed to be a result of their weight] is, in some arbitrary way, made 20 PROPERTIES OF MATTER. consistent with their meeting one another and agglome- rating into visihle masses of matter. The basis of the whole of Lucretius' reasoning in favour of the existence of atoms lies in the gratuitous assumption that reproduction is slower than decay. This is by no means consistent with our modern knowledge, for potential energy of different masses [whether gravita- tional or chemical] is constantly tending to the agglomera- tion of parts, and on a far grander scale than that in which any known cause tends to decay or breaking up. But if there be hard atoms, they must (in all known bodies) have intervals between them ; for compressi- bility : i.e. capability of having the component atoms brought more closely together : is a characteristic of all known bodies. [Contrast this mode of arriving at the conclusion that " there must be void in things," with the erroneous mode employed by Lucretius.] 25. A refinement of this theory, mainly due to Boscovich, gets rid of the material atom altogether, substituting for it a mere mathematical point, towards or from which certain forces tend. It is supported by the assertion that we know matter only by the effects which it produces (or seems to produce), and therefore that, if these effects can be otherwise explained, we need not assume the existence of substance or body at all. This theory was, at least in part, accepted by so great an experimenter and reasoner as Faraday. It virtually substitutes force for matter as an objective thing ( 2) } and it essentially involves the heresy of distance-action ( 10). But the fatal objection to which it is exposed is that it does not seem capable of explaining inertia, which is certainly a distinctive (perhaps the most distinctive) property of matter ULTIMATE STRUCTURE OF MATTER. 21 This theory must be regarded as a mere mathematical fiction, very similar to that which (in the hands of Poisson and Gauss) contributed so much to the theory of statical Electricity ; though, of course, it could in no way aid inquiry as to what electricity is. 26. A much more plausible theory is that matter is continuous (i.e. not made up of particles situated at a distance from one another) and compressible, but in- tensely heterogeneous ; like a plum-pudding, for instance, or a mass of brick-work. The finite heterogeneousness of the most homogeneous bodies, such as water, mercury, or lead, is proved by many quite independent trains of argument based on experimental facts. If such a con- stitution of matter be assumed, it has been shown l that gravitation alone would suffice to explain at least the greater part of the phenomena which (for want of know- ledge) we at present ascribe to the so-called Molecular Forces. But it does not seem to be compatible with experimental facts; especially some of the simpler phenomena presented by gases. ( 55, 322.) 27. The most recent attempt at a theory of the structure of matter, the hypothesis of Vortex Atoms, is of a perfectly unique, self-contained character. Its postu- lates are few and simple, but the working out of anything beyond their immediate consequences is a task to tax to the utmost the powers of the greatest mathematicians for generations to come. A vortex filament, in a pefect fluid, is a true " atom ; " but it is not hard like those of Lucretius ; it cannot be cut, but that is because it necessarily wriggles away from the knife. The idea that motion is, in some sort, the basis of what we call matter is an old one : but no distinct con- 1 "W. Thomson, Pro c . R.S.E. t 1862. 22 PROPERTIES OF MATTER. ceptions on the subject were possible until v. Helmholtz, in 1858, made a grand contribution to hydrokinetics in the shape of his theory of vortex motion. 1 He proved, among other entirely novel propositions, that the rotating portions of a continuous incompressible fluid, in which there is neither viscosity nor finite slipping, maintain their identity : being thus for ever definitely differenti- ated from the non-rotating parts. He also showed that these rotating portions are necessarily arranged in con- tinuous, endless filaments : forming closed curves, which may be knotted or linked in any way : unless they extend to the bounding surface of the fluid, in which alone they can have ends. Thus, to give ends to a closed vortex filament (i.e. to cut it) we must separate the fluid mass itself, of which it is a portion : so that on Lord Kelvin's theory we must (virtually) sever space itself. Such vortex filaments (though necessarily of an im- perfect character) are produced when air is forced to escape from a box, through a circular hole in one side, by sharply pushing in the opposite side. If the air in the box be filled with smoke, or with sal-ammoniac crystals, the escaping vortex ring is visible to the eye; and the collisions of two vortex rings, which rebound from one another, and vibrate in consequence of the shock, as if they had been made of solid india-rubber, are easily exhibited. Experimental results of this kind led Lord Kelvin 2 to propound the theory that matter, such as we perceive it, is merely the rotating parts of a fluid which fills all space. This fluid, whatever it be, must have inertia : that is one of the indispensable 1 Crelle, 1858. Translated (by Tait) in Phil. Mag., 1867. 2 Proc. R.S.E., 1867. ULTIMATE STKUCTURE OF MATTER. 23 postulates of v. Helmholtz's investigation ; and the great primary objection to Lord Kelvin's theory is, that it explains matter only by the help of something else which, though it is not what we call matter, must possess what we consider to be one of the most distinctive properties of matter. 28. This theory is still in its infancy, and we cannot as yet tell whether it will pass with credit the severe ordeal which lies before it, when the properties of vortices (which must be discovered by mathematical investigation) shall be compared, one by one, with the experimentally ascer- tained properties of matter. As we have already said, this theory is self-contained ; no new hypotheses can be introduced into it ; so that it possesses, as it were, no adaptability, or capability of being modified, but must fall before the very first demonstrated insufficiency, or contra- diction, if such should ever be discovered. 29. But the really extraordinary fact, already known in this part of our subject, is the apparently perfect similarity and equality of any two particles of the same kind of gas, probably of each individual species of matter when it is reduced to the state of vapour. Of such parts, therefore, whether they be further divisible or not, each species of solid or liquid must be looked on as built up. This similarity of parts, very small indeed but still of essenti- ally finite magnitude, has been so well treated by Clerk- Maxwell that, instead of insisting upon it here, we give a considerable extract from one of his remarkable articles in Appendix II. below. 30. The further treatment of the subject of structure, involving the question of how the component parts (be they atoms or not) of bodies are put together, must be deferred to the end of the work. What has been said 24 PROPERTIES OF MATTER. above must be looked on as a mere preliminary sketch, not intended even to be fully understood until the experimental data, on which all our reasoning must be based, are brought before the reader as completely as our limits permit. CHAPTER III. EXAMPLES OF TERMS IN COMMON USE AS APPLIED TO MATTER. 31. BEFORE we proceed to a more rigorous treatment of our subject, it may be well to consider what physical truth underlies each of some of the many adjectives in common use as applied to portions of matter, such as Massive, Heavy, Plastic, Ductile, Viscous, Elastic, Rigid, Opaque, Blue, Coherent, etc. This course secures a twofold gain, so far as the beginner is concerned ; for, first, he is introduced by it, in a familiar way, to some of the more important terms which are indispensable in scientific description ; and second, he obtains a glance here and there through the whole subject of Natural Philosophy, because the pro gramme before us is so vague as to leave room for innumerable digressions, each introducing some novel but important fact or property. But we must endeavour to be brief, for whole volumes would have to be written before this subject could be nearly exhausted. 32. Every one who has used his senses to any purpose knows, before he comes to the study of our science, a great many of its phenomena, among them some of the yet unexplained. But he knows, as it were, each by 26 PROPERTIES OF MATTER. itself, and only in its more prominent features; the analysis of the appearances or impressions which he has seen and experienced, and the explanation of the physi- cal fact or process which underlies each of them, are absolutely necessary before he can understand the mode in which they must be grouped, and the reasons for such grouping. 33. Thus he knows that the moon keeps company with the earth, never receding nor approaching by more than a small fraction of the average distance. He also knows that the earth keeps, within narrow limits, at a definite distance from the sun. He has a general notion, at least, that the state of matters on the earth would become serious, as regards both animal and vegetable life, if we were to approach to even half our present distance from the sun, or recede to double that distance. But he would require to be a Newton if, without instruction, he could divine that these results are due to the very cause which keeps the bob of a conical pendulum moving in a horizontal circle. He sees ripples running along on the surface of a pool, but requires to be told that their motion depends upon the cause which rounds the drops of water on a cabbage- blade, or in a shower, and which renders it almost impossible to keep a water-surface clean. He sees what he calls a flash of lightning, but he requires to be told that what he sees is mainly particles of air heated so as to be self-luminous. He looks at the stars and thinks he sees them as they are, but he requires to be informed that he fees even the nearest of them only as it was three years ago and that it may have changed entirely in the interval. And he will certainly require to be informed, even TERMS APPLIED TO MATTER. 27 with patient iteration, that air is made up of separate and independent particles : the number of which in a single cubic inch is expressed by twenty-one places of figures, a multitude altogether beyond human conception : a busy jostling crowd, each member of which darts about in all directions, impinging on its neighbours some eight thousand million times per second. But when he has got so far, and has been told that this astounding information is as nothing to what we feel convinced that science can yet reveal, he cannot help marvelling alike at the arcana of physics, and at the patient efforts of genius which have already penetrated so far into the darkness shrouding its mysteries. 34. Take the terms Massive and Heavy as applied to a piece of matter, or the corresponding substantives, the Mass and the Weight of a body. The terms are usually regarded as equivalents, but in their origin they are completely distinct. The one is a property of the body itself, and is retained by it without increase or diminution wherever in the universe the body may be situated. The other depends for its very exist- ence on the presence of a second body, the Earth : and varies in inverse proportion to the square of the distance from the earth's centre. The destructive effects of a cannon-ball are due entirely to its mass and to the relative speed with which it impinges on the target. They have nothing to do with its weight, for they would be exactly the same (for the same relative speed) in regions so far from the earth, or other attracting body, that the ball had practically no weight at all. When an engine starts a train on a level railway, or when a man projects a curling-stone along smooth ice, 28 PROPERTIES OF MATTER. the resistance which either prime mover has to overcome is due to the mass of the body to be moved. Its weight, except indirectly through friction, has nothing to do with it. So when we open a large iron gate properly sup- ported on hinges, it is the mass with which we have to deal ; if it were lying on the ground and we tried to lift it, we should have to deal simultaneously with its weight and with its mass. The exact proportionality of the weights of bodies to their masses, at any one place on the earth's surface, was proved experimentally by Newton, and is thus no mere truism, but an essential part of the great law of gravitation. Thus a pound of matter is a definite amount, or mass, of matter, unchangeable whithersoever that matter may be carried. But the weight of a pound of matter, or a " pound- weight," as it is commonly called, is a variable quantity, depending upon the position of the body with respect to the earth ; and changes (to an easily measurable amount) as we carry the body to different latitudes, even without leaving the sea-level. 35. The common use of the balance as a means of measuring out equal quantities of matter is justified by Newton's result ; but the process is essentially an indirect one, for the balance tells only of equality of weight. If the earth were hollow at the core, the balance would cease to act in the cavity ( 140). Bodies would preserve their masses there, but would be deprived of weight, at least so far as the earth is concerned. To sum up for the present, the mass of a body is estimated by its inertia, and is taken as the measure of the amount of matter in the body ; while the weight is an accidental property, connected with the presence of TEEMS APPLIED TO MATTER. 29 another mass of matter. But it is a most remarkable fact that under the same given external conditions the weight depends upon the quantity only, and not on the quality, of the matter in a body. If a body, A, becomes heavy in consequence of the presence of another body, B, so in like wise does B become heavy in consequence of A's presence. And the weights of the two, each as produced by the attraction of the other, are exactly equal. Hence, if they be free to move, the quantities of motion (i.e. the momenta) pro- duced in a given time are equal and opposite. [Newton's Lex iii. 128.] But as the momentum is the product of the mass and the velocity, the parts of the velocities of the two bodies, due to their mutual gravitation alone, will be in amount inversely as their masses. Thus, though the weight of the whole earth, produced by the attraction of a stone, is exactly equal to that of the stone produced by the attraction of the earth, the consequent rate of fall of the earth towards the stone is less than that of the stone towards the earth in the same ratio that the mass of the stone is less than that of the earth, and is therefore usually so small as to escape observation. The moon, however, is a stone whose mass is not exces- sively smaller than that of the earth, and the consequences of the earth's fall towards the moon have to be taken account of in astronomy. 36. To properties such as mass, which depends on the size as well as on the material of a body, and weight which, in addition, depends on a second body, there correspond what are called specific properties, characteristic of the substance and independent of the dimensions of the particular specimen examined. Thus the mass of a cubic foot of any kind of matter 30 PROPERTIES OF MATTER. may be called its specific mass. But this quantity, i.e. the amount of matter in unit bulk, is usually expressed by the term Density. The weight of a cubic foot of each particular kind of matter in any locality may be called the specific weight. But as this varies, though in the same proportion for all bodies, from place to place, we use instead of it the ratio of the weight of a cubic foot of the substance to that of a cubic foot of some standard substance. This is called the Specific Gravity. Pure water, at the temperature called 4 C. (its maximum-density point), is usually taken as the standard substance. Newton's experimental result shows that the density and the specific gravity of any substance are proportional to one another, so that if the density of water at 4 C. l)e taken as unit-density, a table of specific gravities is identical with a table of densities. ( 166.) But we must repeat, the coincidence is an experimental fact, not (as yet at least) in any sense a truism. Specific gravity is, in general, much more easily measured with accuracy than is density, so that it is usually the property to be directly determined, the other simply following from it in consequence of Newton's discovery. 37. To vary the subject widely, let us now consider the term Viscous as applied to fluids. The contrasted adjective is usually taken as Mobile. When a liquid partially fills a vessel, and has come to rest, it assumes a horizontal upper surface. If the vessel be tilted, and held for a time in its new position, the liquid will again ultimately settle into a definite position, with its surface again horizontal. Practically it occupies the same bulk in each of these positions. Hence the only change it has suffered is a chsnge of / TERMS APPLIED TO MATTER. 31 But this change of form is much more rapidly attained in some liquids than in others, even v/hen they are of nearly the same density. Some (such as sulphuric ether) attain their equilibrium position so quickly that they retain energy enough to oscillate about it for some time before coming to rest; others (such as treacle) attain it only after a long time and, unless in great masses and when violently disturbed, do not oscillate but gradually creep to their final shape. Hence we call treacle viscous. To analyse this result let us consider (in a very ele- mentary case, for the general analysis of the process requires higher mathematical methods than we can employ in a work like this) what is involved in Shear: i.e. change of form of a body without change of bulk. 38. When water flows, without eddies, slowly in a rectangular channel of uniform width and depth, we know, by observation of particles suspended in it, that the upper parts flow faster than the lower, and (practically) in such a way that a column of the water, originally straight and vertical, inclines, as a whole, forwards more and more in the direction of its motion. Hence in a vertical section, along the middle of the channel, the particles originally forming the line ab in the figure will, c a' c' 6 d V d,' . FIG.1., after the lapse of a certain time, be found approximately in the line a'b'. Similarly those which were originally in 32 PROPERTIES OF MATTER. cd parallel to ab, will be found in c'd', parallel to a'b', and so situated that a'c' = ac, and of course also b'd' = bd. The figures ad, a'd", are thus parallelograms on equal bases and between the same parallels, and therefore equal in area. This shows that the water enclosed between vertical cross sections through ab and cd has the same volume as that between inclined sections (perpendicular to the sides) passing through a'b' and c'd'. There has thus been change of form only in this mass of water, and we see that it has been produced by the sliding of every horizontal layer of the water over that immediately beneath it. [The same result follows even if a'b' be not straight, for c'd' will necessarily be equal and similar to it.] A good illustration of the nature of this kind of distortion will be seen in the leaves of an opened book, especially a thick one, such as the London Directory. It is often well exhibited by piles of copies of a pamphlet, or of quires of note-paper curiously arranged in a shop- window. Now when there is resistance to sliding of one solid on another we call it Friction. Thus the viscosity of a fluid is due to its internal friction, just as the slower motion at the bottom than at the top of the channel is to be ascribed to the friction of the liquid against the solid. [Another illustration of the subject is frequently furnished by the way in which we can judge of the direction of the wind from the mere form of detached clouds, as seen at a single glance. For such clouds, if originally nearly spherical, are distorted into ellipsoids whose longer axes overhang, as it were, the direction of motion.] 39. We now see why it is that disturbances of liquids gradually die away : why the waves on a lake, or even on an ocean, last so short a time after the storm which TERMS APPLIED TO MATTER. 33 produced them has ceased. Also why winds (for there is friction in gaseous fluids as well as in liquids, though the mechanical explanation of its origin may not be quite the same) gradually die out. In either case the energy apparently lost is, as in the case of friction of solids, merely transformed into heat. We also see why it is that winds have the power of raising water-waves. The stirring of water, or oil, and the measurement of the consequent rise of temperature when the whole had come to rest, the work done in stirring being also deter- mined, was one of the processes by which Joule found, with great accuracy, the dynamical equivalent of heat. 40. It is very instructive to watch the ascent of an air-bubble in glycerine, and to compare it with that of an equal bubble in water. The experiment is easily tried with long cylindrical bottles, nearly full of different liquids, but having a small quantity of air under the stopper. When the bottle is inverted the bubble has to traverse the whole column. The (apparent) suspension in water of mud, and ex- ceedingly fine sand (to whose presence the exquisite colours of the sea and of Alpine lakes are mainly due), is merely another example of viscosity. So is the suspen- sion of fine dust, and of cloud particles, in the air. Stokes 1 calculates that a droplet of water, a thousandth of an inch in diameter, cannot fall in still air at a much greater rate than an inch and a half per second. If it be of one-tenth of that size it will fall a hundred times slower, i.e. not more than one inch per minute ! It is very remarkable that the resistance in such cases varies as the diameter of the drop. (See 316.) With larger 1 On the Effect of the internal Friction of Fluids on the Motion of Pendulums. Camb. Phil. Trans, ix. (1851), eq n (127). 34 PROPERTIES OF MATTER bodies, moving faster, the resistance is proportional to the sectional area, being then in great part due to another cause than viscosity. 41. Bodies are called Elastic or Non-elastic. Compare, for instance, the properties of a wire of steel with those of a lead wire ; or of a piece of india-rubber and a piece of clay or putty. But the popular use of these terms is generally very inaccurate. The blame rests mainly with the ordinary text-books of science, which are (as a rule) singularly at fault with regard to the whole of this special subject, including even its most elementary parts. Elasticity, in the correct use of the term, implies that property of a body in virtue of which it recovers, or tends to recover, from a deformation. The phrase " tends to recover " is scarcely scientific ; we should preferably say " requires the continued applica- tion of deforming stress ( 128) to prevent recovery, entire or partial, from deformation." Kinematics shows us that any deformation, however complex, is made up of mere changes of bulk and of form. A distortion may therefore be wholly Compression, or wholly Shear ( 37), or made up of these in any way. Hence there are two distinct kinds of Elasticity, viz. Elasticity of Bulk and Elasticity of Form. The former is possessed in perfection by all fluids, while the second is wholly absent. In solids both are present, but neither in perfection (except perhaps in very special cases, and then within very narrow limits). Thus we see that, as a necessary preliminary to in- vestigations on elasticity of bodies, we must study their capabilities of being distorted : a whole series of pro- perties, such as compressibility, extensibility, rigidity, etc. This investigation is given in Chap. VIII., and its applications in Chaps. IX., X., XL below. TERMS APPLIED TO MATTER. 35 42. In popular language, bodies are said to be White, Black, Blue, Red, etc. The investigation of the under- lying scientific facts, on which these depend, is partly physical (and therefore within our scope), but also partly physiological. The subject is thus a somewhat complex one. What do we mean by White Light ? This is a question much more physiological than physical ; dealing, as it does, with phenomena which are subjective rather than objective. Probably the true answer to it depends upon circumstances, or conditions, which may be varied in- definitely, and with them will necessarily vary what is described in terms of them. Thus, in a room lit by gas, a piece of ordinary writing- paper, or of chalk, appears white : at least if we have been in the room for some little time. But if, beside it, there be another piece of the same paper or chalk on which, through a chink, a ray of sunlight is allowed to fall (weakened, if necessary, so as to make the two appear of nearly the same brightness), we at once call the first piece of paper or chalk yellow, allowing the second to be white. Here we enter on a purely physiological question. In fact, if we accustom ourselves, for a sufficiently long time, to the observation of bodies in a room lit up only by burning sodium (which gives almost homogeneous orange light), we may ultimately come to regard bright bodies such as chalk, etc., as being white : others, of course, being merely of different shades, or degrees of blackness. This, therefore, is foreign to our present subject. For all that, it furnishes us with the means of answering an important question somewhat different from that proposed above, but now a physical question : viz. What do we mean by a white body ? 36 PROPERTIES OF MATTER. 43. Suppose two sources to exist in the room, giving different kinds of homogeneous light; one being incan- descent sodium as before, the other incandescent lithium, which (at moderate temperatures) gives a homogeneous red light. Chalk and ordinary writing-paper will still appear as white bodies to an eye which has become accustomed to the light in the room ; other bodies appear darker, but some are reddish, some of an orange tint. And thus we obtain the idea that what we call a white body is one which sends to the eye, in nearly the same proportion as it receives them, the various constituents of the light which falls upon it ; while a black body sends none ; and coloured bodies send back light which, while (in general) necessarily made up of the same con- stituents as the incident light, contains them in different proportions to those in which they fell upon it. [It would only confuse the student were we here to refer to Fluorescence.] 44. Thus white light would seem to be a mere relative term. It is conceivable that the inhabitants of worlds whose sun is a blue star, or a red star (and there are many notable examples of such stars), may have their peculiar ideas of white light, formed from their own circumstances ; as ours is formed from the light of our own sun, which is what, in contrast with these, we must call a yellow star. However this may be, the discussion above has shown what is meant by a white body. A blue body is, by similar reasoning, one which returns blue rays in greater proportion than it does those of other visible light. It is therefore said to absorb the other rays in greater proportion than it absorbs the blue rays. Now we are in a position to understand why blue and TERMS APPLIED TO MATTEfc. 37 yellow pigments, mixed together, give green : while a disc, painted with alternate sectors of the same blue and yellow, appears of a purplish colour when made to rotate rapidly. .For the light given out by the rotating disc is a mixture, in the proportion of the angles of the sectors, of the kinds of light returned by the blue and yellow separ- ately. But that which the mixed pigments send back has in great part penetrated far enough into the mass to run, as it were, the gauntlet of absorption by each of the separate components in turn, and therefore is finally made up of those rays alone which are not freely absorbed by either. To this discussion we need only add, in illustration of the conservation of energy, that a body is always found to be heated in proportion to the amount of light-energy which it absorbs. 45. Shifting our ground again, we next take the words Malleable, Ductile, Plastic, and Friable, as applied to solid bodies. All of these refer specially to the behaviour of solids under the action of stresses which tend to change their form; for the change of volume of solids, even under very great pressures, is usually very small. The first three indicate that the body preserves its continuity while yielding to such stresses, the fourth that it breaks into smaller parts rather than allow its form to be changed. And, in popular use at least, the terms imply in addition that the body is not sensibly elastic. 46. The most perfect example of a malleable body is metallic gold. The gold leaf employed for " gilding," as it is called, is prepared by a somewhat tedious process, which requires a high degree of skill in the workman. The gold is first rolled into sheets thinner than the thin- 38 PROPERTIES OF MATTER. nest writing-paper (thus already showing a high amount of plasticity) ; next it is beaten out between leaves of vellum, till its surface is increased, and therefore its thickness diminished, some twenty-fold. A small portion of this fine leaf is then placed between two pieces of gold- beater's skin ; and a more skilful workman, with a lighter hammer, again extends its surface twenty-fold. This operation can be repeated without tearing the thin film of metal, so great is its tenacity. ( 226.) Here we have one dimension (thickness) diminished in a marked manner, but the product of the other two dimensions (the surface of the leaf) is of course pro- portionally increased. 47. The action of the hammer may be practically viewed as equivalent to that of an intense pressure exerted through a very small volume, thus at every stroke apply- ing a finite amount of energy. One portion of this is changed into heat in the hammer, the anvil, and the gold leaf ; the rest is employed in doing work against the molecular forces of the gold, and thus altering its form. To show that this is the true explanation of the observed effect, we may vary the experiment by subject- ing a leaden bullet to the action of a hydrostatic press. A few strokes of the pump suffice to bruise the bullet into a mere cake. The process is essentially the same as that of gold-beating, but lead is by no means so malleable as gold. 48. This leads us, in our present discursive treatment of parts of our subject, to inquire how it is, that by means of such a machine as the Bramah press, a man can apply pressure sufficient to mould a piece of lead, whose shape he could scarcely alter to a perceptible amount by the direct pressure of the hand. TERMS APPLIED TO MATTER. 89 Here we have a first inkling of the Function of a Machine. A machine is merely a contrivance by which we can apply work in the way most suitable for the purpose we have in hand. Work (as a form of energy) is a real thing, whose amount is conserved. But we have seen that it can be measured as the product of two factors the (so-called) force exerted, and the space through which it is exerted. Hence, because even when a machine is perfect it can give out only the energy communicated to it, if there be but one movable part to which energy is supplied and another by which it is given off, the simultaneous linear motions of these two parts must be in the inverse ratio of the forces applied to them, or exerted by them, in the direction of these motions respectively. Thus we are not concerned with the interior structure, or mode of action, of a perfect machine : all we need to know is the necessary relation of the speeds of the two parts or places at which energy is taken in and given out. This is a matter of kinematics, and can be made the subject of direct measurement when the machine is caused to move, whether it be transmitting work or not. The statement just made is embodied in the vernacular phrase What is gained in power is lost in speed. Objections may freely be taken to this form of words, but it is meant to imply precisely what was said above as to the action of a perfect machine. If the machine be imperfect, as, for instance, if there be frictional heating during its working, the heat so produced represents some of the energy given to the machine, and the remainder of it is alone efficient. 40 PROPERTIES OF MATTER. 49. A substance is said to be ductile when it can be drawn into very fine wires i.e. when it admits of great exaggeration of one of its three dimensions (length) at the expense of the product of the other two (cross section). Wire -drawing is, essentially, a very coarse operation, for it has to be effected by finite stages, the wire being drawn in succession through a number of holes in a hard steel plate, in which each hole is a little smaller in diameter than the preceding one. The more nearly continuous the operation is made, the more tedious and therefore the more costly it becomes. The associated tenacity and plasticity of silver render it one of the most ductile of metals. And an ingenious idea of Wollaston's enables us, as it were, to impart to other metals much of the ductility of silver. His idea may be briefly explained by analogy as follows. Suppose a glass rod, whose core is coloured, be drawn out while softened by heating, the diameter of the core is found to be reduced in the same proportion as is that of the rod. Thus, to obtain platinum wires much finer than could be procured by direct drawing, Wollaston suggested the boring of a hole in the axis of a cylindrical rod of silver, plugging the hole with a platinum wire which just fitted it, and then drawing into fine wire the compound cylinder. When this operation has been carried to its limit, practically determined by the ductility of the silver, the diameter of the platinum has been reduced nearly in the same proportion as that of the silver ; and the silver may be at once removed from the fine platinum core by plunging the whole in an acid which freely attacks silver but has no effect on platinum. 50. Plasticity is shown, on the large scale, by many substances which, in hand specimens, appear fragile in TERMS APPLIED TO MATTER. 41 the extreme. Glacier-ice is one of these, but its behaviour is so closely connected with its thermal properties that we can only mention it here. The earth as a whole, though its rock-structure appears so rigid, has been found to be more plastic (under the tidal attraction of the moon) than a globe of glass of the same size would have been. But it is specially under the action of small but persistent forces that bodies, which are usually regarded as brittle or friable, show themselves to be really plastic. A good example of this is given by an experiment due to Lord Kelvin. Cobbler's wax is usually regarded as a very brittle body ; yet if a thick cake of it be laid upon a few corks, and have a few bullets placed on its upper surface (the whole being kept in a great mass of water to prevent any but small changes of temperature), after a few months the corks will be found to have forced their way upwards to the top of the cake, while the bullets will have penetrated to the bottom. [Tresca has investigated the flow of solid metals, and has shown that even steel flows under the action of sufficient stress. W. P.] 51. For variety, let us next take the terms Trans- parent, Translucent, and Opaque. These refer, of course, to the behaviour of a substance with regard to the passage of light through it. In common speech, a pane of ordinary window-glass is called transparent, while a piece of corrugated or of ground glass is translucent : the latter transmits rays, no doubt, but with their courses so altered that they are no longer capable of producing distinct vision of the source from which they come. Consistency would require that the term translucent should also be applied to 42 PROPERTIES OF MATTER. irregularly-heated air, or to a mixture of water and strong brine before diffusion has rendered it uniform throughout. Translucent is hardly a scientific word, unless we choose to limit its application to heterogeneous bodies. In science we speak of the degree of transparency of a homogeneous substance ; as, for instance, water more or less coloured, and employed in greater or less thickness. In such cases, besides the inevitable surface-reflection, there is more or less absorption ; and the percentage of any definite kind of incident light which unit thickness of the substance transmits is called its transparency for that kind of light. Opacity may arise from either of the two causes just mentioned. Light may enter a body, and be unable to proceed farther, as is the case with lamp black. Or it may fall on a highly polished surface, such as thinly silvered glass, and be in great part reflected without entering. In the former case it is said to be absorbed ; and, when this happens, the absorbing body is raised in temperature. The incident energy is converted from the radiant form into that of heat. In the latter case part only can enter the body; and, if it meet in succession other reflecting surfaces in sufficient number, practically the whole of it may be reflected. This is the case with a heap of pounded glass, a cloud, a mass of snow, or of froth or foam. All of these materials are transparent, but they reflect some of the incident light; and, in consequence of the multiplicity of surfaces which the light has to encounter, the greater part of it is reflected before it has penetrated deeply into the mass. Hence the whiteness and brightness of snow and clouds in full sunshine. TERMS APPLIED TO MATTER. 43 52. We have here an excellent opportunity of calling the student's attention to the distinction : a very pro- found one : between Heat and Temperature. For we have seen that energy, in the form of light, when absorbed, becomes heat in the absorbing body, and thus raises its temperature. But if the same quantity of heat had been given to a body, of the same nature but of twice the mass, the rise of temperature would have been only half as great. The very form of words here used shows at once how different are the meanings of the words temperature and heat. For the quantity of heat (so much energy, a real thing) is perfectly definite, but the effect it produces on the temperature (a mere state) depends on the quantity and quality of the mass to which it is communicated. Heat is therefore a thing, something objective; tem- perature is a mere CONDITION of the body with which the heat is temporarily associated ; a condition which in certain cases determines the physical state of the body itself, and in all cases determines its readiness to part with heat to surrounding bodies or to receive it from them. Heat may, in this connection, but only for illustration, be compared with the air compressed into the receiver of an air-gun ; temperature would then be analogous to the pressure of that air. Neither of two receivers would (except by diffusion, with which we are not at present concerned) give air to the other, when a pipe is opened between them, if the pressure were the same in both ; but air would certainly flow from the receiver in which the pressure is greater to the other ; and this, altogether independently of the relative capacities of the two receivers, or the consequent amounts of their contents. 44 PROPERTIES OF MATTER. 53. As another example, take the terms Cohesive, In- coherent, Repulsive. A lump of sandstone has considerable tenacity, which, of course, is to be ascribed to those molecular forces of which we spoke in 26. But when, in virtue of its friability, it has been pounded down into sand, it becomes an incoherent powder. And we know that it must at some time previously have been in this form, for it often contains fossil plants or fish, and it may even have pre- served (perhaps for a million or more of years) records of surface-disturbance in the form of dents made by rain or hail, or by the feet of birds or reptiles. When a sufficiently deep layer of sand is deposited, by drifting or otherwise, above this portion, its loose particles are brought by the consequent pressure so close together that their molecular forces once more come into play. The graphite, or plumbago, which forms the material for the finest drawing-pencils, is a somewhat rare and valuable mineral. In cutting it up into " leads," however carefully, a considerable portion is reduced to powder i.e. sawdust. But if this powder be exposed, in mass, to pressure sufficient to bring its particles once more within the extremely short mutual distance at which the molecular forces are sensible, these forces again come into play, and the powder becomes a solid mass, which can in turn be sawn into " leads " for a somewhat inferior class of pencils. The whole of this part of the subject, especially as regards liquids, will be fully treated later, so that we need not further consider it here. 54. But let us contrast, with the behaviour of the particles of a solid or a liquid, that of the particles of a gas or vapour. Such substances require to be subjected TERMS APPLIED TO MATTER. 45 to external pressure in order to prevent their particles from being widely scattered. When a small quantity of air is allowed to enter an exhausted receiver it dilates so as to occupy with practical uniformity the whole interior of the receiver, however large that may be. This result was, naturally enough, at first ascribed to a species of repulsion between the various particles ; but the notion was found to be an erroneous one. For the effects of a true repulsion, capable of producing the practically infinite dilatation already spoken of, could not all be consistent with the corresponding observed results. The mode of departure from them depends upon the law according to which the repulsion may be supposed to vary with the distance between two particles. Some assumed laws would give as a consequence that the particles would all be driven to the sides of the vessel, leaving the interior void. Others would require that the pressure should change in value if we were to take half the gas and con- fine it in a vessel of half the content. Others would make it different at different parts of the surface unless the vessel were truly spherical, etc. etc. The true explanation of the phenomenon becomes obvious to us when we apply heat to the gas. For it then appears that the pressure requisite to maintain the whole at a constant volume increases as the temperature is raised ; and thus that heat is, in some way, the cause of the pressure. 55. Hence we are led to what is called the Kinetic Theory of gases, whose fundamental assumption ( 33) is that the particles dart about in all directions (with an average speed which is greater the higher the tempera- ture), impinging on one another, and also upon the sides of the containing vessel. This continued series of very 46 PROPERTIES OF MATTER. small but very numerous impacts (each, by itself, absolutely escaping observation) is perceived by our senses as the so-called "pressure" exerted by the gas. Experiment shows that, when a gas is confined in a vessel of definite size, the changes of its pressure are nearly proportioned to the changes of temperature, as measured by a mercury thermometer, whether these changes be in the direction of a rise or a fall. If we assume, for a moment, that this statement is true for all ranges of temperature, even beyond those attainable in experiment, it leads us to the very important question : At what temperature does the pressure of a gas vanish ? Calculations carried out in the above way showed that, under the assumption just mentioned, all of the (so-called) permanent gases cease to exert pressure at one common temperature (about- 273 C.). Therrnodynamical theory comes to our assistance and shows that the above guess is not far from the truth : that a body, cooled to 274 C., cannot be cooled any farther; that it then is, in fact, totally deprived of heat We might, therefore, fancy that a gas, if it could be brought to this temperature, would be reduced to a mere layer of incoherent dust or powder, deposited by gravity on the lower surface of the containing vessel. But experiment has shown that gaseous particles, even while in motion, if only close enough together, exert mutual molecular forces, so that the result (on any gas) of the conditions above specified would probably be its assuming a liquid or even a solid form. In fact Andrews has shown that, for each particular substance, there is a temperature (usually called the Critical Point) such that, while the substance is at any higher temperature it is necessarily a gas, in the sense that it cannot be liquefied by any pressure, TERMS APPLIED TO MATTER. 47 however great. At any lower temperature it can be liquefied by the application of sufficient pressure, and is therefore to be regarded as a true vapour. 56. We speak of bodies as Hard and Soft. These are barely scientific terms; because, unless they are strictly defined, they may bear a great variety of meanings. Thus, for instance, we have the mineralogist's Scale of Hardness, which is often of great practical value in field- work. For there are numerous instances in which two quite different minerals (sometimes a very valuable and a very common one) are almost undistinguishable from one another so far as colour, density, and crystalline form are concerned. Chemical tests (even the comparatively coarse blowpipe tests), though they would settle a question of this kind at once, are not readily applied in the field. Hence the use of the scale of hardness, in which minerals are so arranged that every one can scratch the surface of any other which is lower in the scale. By carrying a set of twelve small specimens only, of selected minerals, the finder of a doubtful crystal can readily determine its rank among them as regards scratching; and can thus often settle in a moment what would otherwise require some time, even with the facilities of a laboratory. In such a scale diamond, of course, stands at the top, while native copper, one of the toughest of substances, is far below it. But if we were to test relative hardness by some other method, say by blows of a hammer, we should be led to arrange our specimens in a very different order. The scale above spoken of is, therefore, by no means a scientific one ; though, as we have seen, it may often give easily some useful information. CHAPTER IV. TIME AND SPACE. 57. WE begin with an extract from Kant, who, as mathe- matician and physicist, has a claim on the attention of the physical student of a very different order from that possessed by the mere metaphysicians. " Time and space are two sources of knowledge, from which various a priori synthetical cognitions can be derived. Of this pure mathematics give a splendid example in the case of our cognitions of space and its various relations. As they are both pure forms of sensuous intuition, they render synthetical propositions a priori possible. But these sources of knowledge a priori (being conditions of our sensibility only) fix their own limits, in that they can refer to objects only in so far as they are considered as phenomena, but cannot represent things as they are by themselves. This is the only field in which they are valid ; beyond it they admit of no objective application. This peculiar reality of space and time, however, leaves the truthfulness of our experience quite untouched, because we are equally sure of it, whether these things are inherent in things by themselves, or by necessity in our intuition of them only. Those, on the contrary, who maintain the absolute reality of TIME AND SPACE. 49 space and time, whether as subsisting or only as inherent, must come into conflict with the principles of experience itself. For if they admit space and time as subsisting (which is generally the view of mathematical students of nature), they have to admit two eternal infinite and self- subsisting nonentities (space and time), which exist with- out their being anything real only in order to comprehend all that is real. If they take the second view (held by some metaphysical students of nature), and look upon space and time as relations of phenomena, simultaneous or successive, abstracted from experience, though repre- sented confusedly in their abstracted form, they are obliged to deny to mathematical propositions a priori their validity with regard to real things (for instance in space), or at all events their apodictic certainty, which cannot take place a posteriori, while the a priori concep- tions of space and time are, according to their opinions, creatures of our imagination only." l On matters like these it is vain to attempt to dogma- tise. Every reader must endeavour to use his reason, as he best can, for the separation of the truth from the metaphysics in the above characteristic passage. 58. We must now take up, as indicated in 21, the property Extension, which is one of those expressly in- cluded in our provisional definition of matter. It implies that all matter has volume, or bulk. The thinnest gold leaf has finite thickness, ths finest wire has a finite cross section. In popular language this is recognised by the use of the associated terms length, breadth, arid thickness. In other words, the term extension recognises the essentially Tridimensional character of space. 1 Critique of Pure Reason. Max Muller's Translation. 50 PROPERTIES OF MATTER. Why space should have three dimensions, and not more nor less, is a question altogether beyond the range of human reason. Only those who fancy that they know what space is, would venture (at least after well con- sidering the meaning of their words) to frame such a question. 59. The proof that our space has essentially three dimensions is given in its most conclusive form by the statement, based entirely upon experience, that To assign the relative position of two points in space, three numbers (of which one at least must be a multiple of the unit of length) are necessary, and are sufficient. It is an easy matter for us, accustomed to tridimen- sional space, to imagine one or more of its dimensions to be suppressed. In fact so-called Plane Geometry is the geometry of one particular kind of two-dimensional space; Spherical Trigonometry that of another. We cannot well speak of the geometry of space of one, or of no dimensions ; but the idea we should thus attempt to express is a correct one, though the term is inappropriate. When, however, we try to conceive space of four or more dimensions, we are attempting to deal with some- thing of which we have not had experience ; and thus, though we may by analogy extend our analytical and other processes to an imagined space, in which the rela- tive position of two points depends on more than three numerical data, we can form no precise idea of how the additional dimensions would present themselves to our senses or to our reason. A few remarks on this subject will be made at the end of the chapter. 60. Space of no dimensions is a geometrical point, of which nothing further can be said TIME AND SPACE. 51 61. Space of one dimension: let us call that dimen- sion Length : is a mere geometrical line which may be curved or straight. But to be sure of the existence of this characteristic, and to understand its true nature, we must have cognisance of space of two dimensions if it be a plane curve, of three if it be tortuous. The study of all the properties of space of one dimension, though an excessively simple affair, is of very great intrinsic import- ance, besides being a necessary step towards that of the higher orders. We will, therefore, treat it so fully that a far less amount of detail will be necessary when we come to two and to three dimensions. 62. Every one, whether he be aware of the fact or not, is acquainted by experience with at least the elements of this subject. Suppose, for instance, we take as our one- dimensioned space any one of the roads or railways lead- ing from Edinburgh to London ; which we will, for the moment, suppose to be straight, and to run due south. The mile-stones, set up at equal distances along the road, mark the positions of various points in terms of the one dimension, length, which is alone involved, or, rather, to which for the present we restrict our consideration. And a Gazetteer or a Railway Guide gives us the positions of the towns or stations along the road or line : the position of each being fully described by a single number, under- stood as a multiplier of a mile or of some other specified unit of length, and with a qualification which will presently be introduced. But these numbers refer to the distance from some assumed starting-point, or Origin as it is technically called ; say, in this case, London. Thus we find in an old Road Guide, for the particular one-dimensioned space 52 PROPERTIES OF MATTER. called the East Coast Route, a column of data from which we extract the following : Miles. London ......... York .196 Berwick 337 Edinburgh ........ 395 Fractions of miles are omitted, to avoid mere arithmetical complication. From this table, by ordinary subtraction, we form a list, as below, of the lengths of what we may call the various stages of the route. Thus Miles. London to York . , . . . . .196 York to Berwick . 141 Berwick to Edinburgh . . . . .58 It will be seen that, in this list, the origin from which each number is measured is the first named of the two corresponding places, and the number itself is found by subtracting, in the first list, the number corresponding to the first of the two places from that corresponding to the second. 63. Now let us at once take the only step which presents any difficulty. Choose York as our origin, and boldly apply the rule just given, no matter what the consequences may be. The result is Miles. London . . . -196 York Berwick. . V 141 Edinburgh 199 Here there is no difficulty whatever in understanding the numbers for Berwick and for Edinburgh. They are, as before, the numbers of miles by which Berwick and Edinburgh are separated from York. Also the number TIME AND SPACE. 53 for London, when York is the origin, differs from that for York, when London is the origin, only by change of sign. So that we at once recognise the meaning of the negative sign as applied to a length in our one-dimen- sional space : it measures the length in the opposite direction to that in which a positive length is measured. The necessity for this convention, and its extreme usefulness, were early recognised in Cartesian geometry, but they had long before been applied in common arith- metic as well as in algebra. Perhaps the simplest view we can take of the subject is that afforded by a man's " balance " at the bank. So long as this is on the right side (i.e. positive) he can draw any less amount and still be on the credit side; if he overdraws (i.e. takes more out of the bank than his balance), the difference is negative, and he is to that amount indebted to the bank. 64. In the first of the three little tables above, all the places involved lay to the north of the origin (London), and were all therefore affected by the same sign (which we happened to take as + ). When York was taken as origin, Berwick and Edinburgh were to the north, and their numerical quantities were still + . But London being to the south, had a - number. It would be easy to give multiplied examples of this, but they are unnecessary. The only additional com- ments which we need make are these : (1.) When the northern direction along a line was called +, the southward necessarily became . Simi- larly had we chosen southward as + , northward would have become - . (2.) We chose for our special example a northward- 64 PROPERTIES OF MATTER. running line, but we might equally well have chosen an eastward one, etc. Hence pairs such as N". and S., E. and W., up and down, etc., must he regarded as having their members contrasted exactly as are the + and - of Algebra or of Analytical Geometry. And, just as a displacement in either direction along a line may be regarded as +, while a displacement in the opposite direction must then be regarded as - , so it is with rates of motion, i.e. Speeds, in space of one dimension. Thus the relative speed of two trains running north- ward, A at 60 miles an hour, B at 40, is 20 miles an hour northward as regards A seen from B, and 20 south- ward as regards B seen from A; so if A be moving southward at 60 miles an hour, and B northward at 40, the speed of A with regard to B is 100 miles per hour southward, and of B with regard to A 100 miles per hour northward. The idea of speed, as so many units of linear space described per unit of time, is a complex one : involving both of the fundamental ideas. We express this by saying that its Dimensions are L [*} This implies that, in whatever proportion we increase our unit of length, the measure of a speed is diminished in that proportion : while it is increased in the same proportion as that in which the unit of time is increased. Thus a speed of 5280 feet per second is but 1 mile per second; while a speed of 1 foot per second is 60 feet per minute. 65. A precisely similar distinction (as to + and - ) is TIME AND SPACE. 65 observed when our one-dimensional space is a curved line; take for example the orbit of a planet. To describe fully the position of the planet, when the orbit is given, one number alone (say the angle-vector, the angle which the radius-vector, or line joining the centres of planet and sun, makes with some fixed line in the plane of the orbit) is required. This, however, must again be qualified as + or - . (In the case of angles, we agree to call them + when they are measured in the opposite direction to that of the motion of the hands of a watch; that is, when they are described in the same sense as that in which the northern regions of the earth turn about the polar axis.) Angular velocity in one plane (i.e. rate at which the radius-vector turns) is similarly characterised. In aU cases where motion is restricted to one line the same thing holds. Thus the position of a pendulum is at every instant completely assigned by the angle the rod makes with the vertical, provided we are also told on which side the displacement is. The record kept by a self-acting tide-gauge gives at any instant the elevation or depression (again + and ) of the water above or below the mean level. Similarly with registering barometers, thermometers, etc. But, for the full appreciation of the indications of these records, they are usually made in two dimensions by the use of an important principle which will presently be explained. (68.) 66. In what precedes we have been dealing with a kind of space in which the only displacements are forward or backward ; nothing is possible (nor even con- ceivable) sideways or upwards. This characteristic applies to Time, as well as to space 56 PROPERTIES OF MATTER. of one dimension, and therefore we should expect to find, as we do find, that (with the necessary change of a word or two) all that has just been said with reference to relative position is true of events in time, as well as of points in one-dimensional space. There is no such thing as motion or displacement in time, so that this part of the analogy is wanting. Every event has its definite epoch, for ever unalterable. And of course there is no going sideways or up- wards, as it were, out of the one-dimensional course of time. Thus we find that to assign definitely the position of an event in time, provided our origin is assigned, all we need know is a single number (a multiplier of the time-unit) with its sign, + or - , signifying time after or time before that origin. Our usually adopted origin is the Christian era, and we speak of 1899 A. D. as the present year [I leave these dates as written. W. P.], while the date of the battle of Marathon is recorded as 490 B.C. The difference between the characteristics A.D. and B.C. is of precisely the same nature as that between north and south, or + and . Hence, if we wish to find the interval between the present time and the battle of Marathon, we have to subtract +1899 (the position of the new origin) from - 490. The result is - 2389, i.e. Marathon was fought 2389 years ago. Thus to change the origin, or epoch, we must perform precisely the same operation as that which gave us the table in 63, from the first table in 62. Similarly, to change our system of chronology to the year of the world (designated by A.M.) or to the old Roman (marked A.U.C.), all we need do is to subtract from each date (A.D. or B.C., regarded as + and - respectively) the assumed date of the creation of the world (4004 B.C.) or of the foundation of the city of Rome (753 B.C.). TIME AND SPACE. 57 We need say no more on such a matter. Every intel- ligent reader can make new and varied examples for himself. 67. Passing next to space of two dimensions, whether plane or spherical, we see at once from a map, or a globe, that the position of a place is given by two numbers, its Latitude and Longitude. But each of these has to be qualified for definiteness by the + or - sign, or something equivalent. Thus we have K or S. latitude, and E. or W. longitude. But there are two methods, specially applicable to the plane, which deserve closer attention in view not only of their intrinsic usefulness, but also of their bearing on the general question of tridimensional space. These are known in geometry as Rectangular and Polar co-ordinates. 68. In the first we assume two reference lines at right angles to one another, both passing through the origin, and assign the position of a point by giving its distances from these two lines. These distances are looked on as drawn towards the point from either line, and each there- fore changes sign when the point is taken on the other side of the corresponding reference line. This is symbol- ised in the cut. Ox, Oy are the two reference lines, the origin. The perpendiculars PM, PN, let fall from P on these lines, completely, and without ambiguity, define its position. For if we know OM or NP, the # of P, i.e. its distance from Oy, that condition alone limits our choice for P to points lying in PM, a line drawn parallel to Oy and everywhere at the assigned distance, x, from it. Similarly, y being given as ON or MP, the choice of points is limited to those on the line NP, all of which have this property. But two lines at right angles to each other must 58 PROPERTIES OF MATTER. intersect, and in one point only. Thus the point P is determined by the conditions without ambiguity. -X X FIG, 2. If P lie to the left of Oy, its x is negative ; if below Ox, its y is negative. The lettering in the cut, at the ends of the lines bounding the four quadrants, shows at a glance the signs of x and y when P is situated in any one of them. In general, any given relation, between the x and y of a point, limits its position to a definite Curve in the plane of the reference lines. It is often very convenient to represent such a relation by a curve ; and, in fact, most self-registering instruments actually trace such a curve for us. Thus, if intervals of time (as OM) measured from a definite instant (represented by 0) be laid off along Ox, with the corresponding heights of the thermo- meter, barometer, tide, etc., erected as perpendiculars (MP) at their extremities, we have (as the Locus of P) a curve showing the mode in which temperature, pressure of the atmosphere, etc., change as time goes on. But such curves can be traced by a pencil attached to the instrument, or by photographic processes, on a long band TIME AND SPACE. 50 of paper which is drawn horizontally past it, at a uniform rate, by clockwork. 69. In the second method mentioned in 67 the data are the length of OP (the radius-vector), and the magni- tude of < MOP (the angle-vector), 65. These are usually denoted by r and 9, respectively. Here r is always taken as a positive (or rather a signless) quantity, while 6 is posi- tive if it be measured round from Ox counter-clockwise. This is the method adopted by a surveyor when, with a chain and a theodolite, he measures a field. His reference line, Ox, is usually given by a magnetic needle attached to the theodolite. He measures the angle a;OP and the dis- tance OP, P being a corner (let us say) of the field. These two data, determined for each prominent part of the bound- ary, enable him to plot the field ; and therefore contain all the necessary numerical data for calculating its area, etc. It is also the method usually employed in dealing with orbital motion of any kind in one plane. Comparing the two methods, we see that the directed line OP may be resolved (as it is called) into OM and MP, lines in directions perpendicular to one another. Also that this resolution, in any direction, is effected by means of the cosine of the angle involved. < For x = OM = OP cos zOP = r cos 6, < y= MP = OP cos ?/OP = r sin 6. It is clear that, though we have hitherto spoken of and P as the simultaneous positions of two points, we may look on them as successive positions of one (moving) point. If we look on the displacement as having been produced uniformly, and in one second, it represents in magnitude and direction the Velocity of the moving 60 PROPERTIES OF MATTER. point ; and OM, MP represent, on the same scale, its resolved parts or components, parallel to Ox and O?/. These components are entirely independent of one another, so that to compound two or more displacements or velocities we have only to resolve each into its east- ward and its northward components, and deal with these respectively by the ordinary algebraic process, to obtain the corresponding components of the resultant. 70. As examples, we give one or two results which will be specially useful to us in later chapters. If a point be moving, in any manner whatever, we may consider its velocity alone, independent altogether of the actual path pursued. Here we are introduced to a new idea, that of Acceleration. For, as velocity is rate of change of position, acceleration is rate of change of velocity. Take any fixed point, 0, and let OP represent, in magnitude and direction, the velocity of the moving point. After one unit of time let the velocity be represented by OP X ; after two units, by OP 2 ; and so on. It is clear that all the points P, P v P 2 , etc., lie on some definite curve, which will be the more accurately traced the greater the number of points we obtain in any assigned portion of it ; i.e. the smaller we assume our unit of time. If the motion whose properties are thus studied be that of a particle of matter, this curve (which is called the Hodograpli) is necessarily continuous, for the velocity cannot alter by starts ( 120) either in magnitude or in direction. And, as OP passes TIME AND SPACE. 61 to a proximate position, OQ, by having a velocity PQ compounded with it, the Acceleration of OP is the velocity with which P moves in its curve. If the path be a plane curve, the hodograph is also plane. This construction enables us at once to solve a number of elementary problems in kinematics, which will be of great use to us in the sequel. In 64 above, we showed that the dimensions of speed (V) are In precisely the same way we see that those of accelera- tion (A) are Thus the numerical measure of acceleration is diminished in proportion as the unit of linear space is increased : but is increased in the duplicate ratio of that of the time unit. An acceleration of 1 foot per second, per second, is obviously the same as 3600 feet per minute, per minute. 71. Suppose a point to move uniformly, with speed V, in a circle of radius R. OP in the hodograph (Fig. 3) has constant length V, and its direction rotates uniformly. Hence the hodograph is another circle, also uniformly described in the same sense (i.e. clockwise or counter- clockwise), and in the same period of time. Hence the speed of P must be such that it describes a circle of radius V, in the time that a point whose speed is V takes to go round a circle of radius R. It must, therefore, be V 2 /R. Also the direction of this speed is perpendicular to OP, and therefore along the radius of the first circle. And its direction is towards the centre of that circle, 62 PROPERTIES OF MATTER. because both circles are described clockwise, or counter- clockwise. Let, now, the figure repre- sent the circle of radius R, and draw any diameter, ACA'. Then N moves round with speed V, and the acceleration of its motion is V 2 /R along NC. Remembering that accelerations and velocities are resolved like lines, we see that if NM be drawn perpendicular to AA', the speed of the point M along MC will be V MN NO' and its acceleration along MC, and towards C, will be R CN = JR 2 ^ M * The motion of M, thus defined, is called Simple Har- monic. It obviously consists in a vibration back and forward along the line AA', the speed being greatest at C, and vanishing at A and A'. The special characteristic is that the acceleration is always directed towards C, and is proportional to the displacement of M from that point. 72. If we use Newton's Fluxional Notation, in which the rate at which a quantity increases per unit of time is expressed by putting a dot over the symbol for that quantity, a second dot placed over it will signify the rate at which that rate increases, and so on. Thus, if CM above be denoted by x, the speed of M is x, and its acceleration is x. And we see ab once from the result of last section that TIME AND SPACE. 68 the negative sign being prefixed because while x is directed to the right in the figure, the acceleration is directed to the left, and conversely. Whenever, in future chapters, we meet with a relation of this kind, we will, therefore, interpret it as expressing simple harmonic motion. The multiplier of the right-hand side depends only on the ratio of V to E : what is called ( 65) the angular velocity of the radius-vector CN. If we denote this by w, the equa- tion may be written X = -u?x; an equation which belongs to all simple harmonic motions, whatever be their range of vibration, provided the angular velocity in the corresponding unform circular motion be (o, or the period of a complete revolution 27r/o>. Any such motion is therefore fully described by 05 = a COS. where a and a are absolutely arbitrary. 73. The result above was obtained by projecting uni- form circular motion on a diameter of the circle, or, what comes to the same thing, on a plane perpendicular to the plane of the circle. But an exceedingly interesting result is obtained by projecting the circular motion on any other plane. In orthogonal projection equal areas are projected into equal areas, and a circle is projected into an ellipse whose centre is the projection of the centre of the circle. Hence the projection gives motion in an ellipse, the radius-vector drawn from the centre of the ellipse tracing out equal areas in equal times, and the acceleration being still directed inwards along the radius-vector, and still bearing the same proportion to it. 74. Another extremely useful result may be obtained 64 PROPERTIES OF MATTER. by supposing the unform angular velocity in the circle to be maintained, but with a continual shrinking of the radius at a rate measured (per second) by K times its length at each instant. The velocity of the moving point is thus made up of two components, one along the circle, the other along the radius, each proportional to the radius. Hence the path is a spiral which makes a constant angle with the radius, what is called the Equiangular, or Logarithmic, Spiral. The radius- vector still revolves uniformly. 1 Let PB be the spiral, SP any radius. Then, if PT be FIG. 5. the velocity of P, and a the (constant) angle between its direction and that of PS, we see at once that whence PT sin a = o>SP, PT cos a = /cSP, K = , and therefore x = OM = ON cos 6 = r cos Q cos 6, y = MN = ON sin = r cos

co-ordinates. But it suffices to consider merely what species of constraint each of 70 PROPERTIES OF MATTER. these imposes when its value is given. All points for which r has a given value lie on a sphere whose centre is at 0. When is given, the point must lie somewhere in the vertical plane zOK When < is given, it must lie somewhere on a right cone of which is the vertex and Oz the axis. [The two latter statements are easily illustrated by means of a telescope, mounted (in the common way) on a stand which allows it to rotate either about a horizontal, or about a vertical, axis. Place it in any azimuth, and vary its altitude, it turns in a vertical plane about the horizontal axis. Place it at any altitude, and vary its azimuth, it rotates conically about the vertical axis. Hence, by means of these co-ordinates, or conditions, each definite point in its axis is constrained to lie on a sphere, a plane, and a cone, simultaneously.] 79. Two devices are in common use for enabling us to represent, on a plane (or other space of two dimensions) the third dimension. Thus, in an Admiralty chart, we find the sea-area marked over with figures denoting Soundings : i.e. the average depth of the water at certain places is written in in fathoms. These soundings are of course more numerous in regions where there are shoals or intricate channels. But it is obvious that, if they were numerous enough, they would enable us to construct a model of the sea- bottom. The soundings, therefore, supply, as it were, the necessary third dimension. But this process, though usually sufficient for purposes of navigation, is at best a rude and incomplete one. The other method, however, rises to a very high order of scientific importance, not merely from the point of view for which it was originally devised, but on account of the TIME AND SPACE. 71 extent to which its essential principles are now applied throughout the whole range of physics. We therefore devote some space to its full explanation. 80. This is called the method of Contour Lines, and is employed with great effect in the best maps, such as those of the Ordnance Survey. A contour line passes through all places which are at the same height above the sea-level. Thus the sea-margin is itself the contour line of no elevation. Suppose the water to rise one foot (vertically). There would be a new sea-margin, in general encroaching more on the land than the former ; encroaching most at places where the beach has the gentlest slope, not encroach- ing at all on a perpendicular cliff, and thrust out (seawards) from an overhanging cliff. This is the contour line of one foot elevation. It is clear that by supposing a gradual rise of the sea, or subsidence of the land, foot by foot, we could obtain a series of curves (each in its turn a sea-margin) gradually circumscribing the uncovered portion of the land, and finally closing in over its highest peak. We require no such natural convulsion as that just im- agined. Cloud strata, or fog-banks, with definite horizontal surfaces, constantly show us these appearances in hilly countries. But it is a simple matter of Levelling to trace out contour lines, and to draw them on a map of the district. For practical purposes it is usually sufficient to draw them for every 50 or 100 feet of additional elevation above the sea-level. The celebrated Parallel Roads of Glen Roy are merely contour lines, etched on the sides of the valley by long- continued but slight agitation of the margin of the water which filled the glen to various depths in succession, as the barriers which dammed it ut> were, at intervals, broken down. 72 PROPERTIES OF MATTER. Eeferring to 78, we see that a surface can be fully described in terms of one relation among x, y, and z. Let the plane of Oar, Oy, be that of the sea-level, and let the relation expressing the surface of the land be f(x, y, s) = 0. Then the contour lines, as traced on the (two-dimension) map are the curves f(x, y, 0)-0, f(x t y, 100) = 0, f(x, y, 200) = 0, etc. 81. To familiarise the student with the general appear- FIG. 7. ance of contour lines, and their relation to the form of the corresponding surface, we give those of a right cone whos^ TIME AND SPACE. 73 axis is vertical, of a hemisphere, and of a fusiform or spindle-shaped body. The fusiform body, whose contour lines are drawn, is formed by the rotation of a quadrant of a circle about a vertical tangent, the point of contact being the apex. And the contour lines are drawn, in each case, at suc- cessive heights increasing by one-fifth of the whole height of the figure. Thus the distances between successive contours, in the two last figures, form the same series of values, but in opposite order. The equality of distance between the successive contour lines of the cone indicates uniform steepness throughout. In the hemisphere the lines are closer together near the boundary of the figure, in the spindle they close in on one another towards the centre ; the hemisphere being steepest at its edges, and the spindle surface steeper towards the point. 82. In fact, the Gradient of a surface in any direction (i.e. the amount of rise per horizontal foot) is obviously, at any point, inversely as the distance in that direction between successive contour lines, for they are traced at successive equal differences of level ; and thus the dis- tance between them, along any line drawn on the map, is the space by which we must advance horizontally along that line while ascending or descending vertically through 100 feet. 83. The line of steepest slope at any point of a surface is, of course, perpendicular to each contour line where it meets it. For the contour line is horizontal, i.e. has nc slope. And in the projection on a horizontal plane this perpendicularity remains. Thus the line of greatest slope at any point is represented on the map by the shortest line which can be drawn from that point to the nearest 74 PROPERTIES OF MATTER. contour line. It is the path along which a drop of water would trickle down. It is therefore called a Stream-line. 84. If the surface be like that of a saddle (concave up- wards along the horse's back, convex upwards across it), we have at the middle of the saddle what is called, in geography, a Col or mountain-pass : the lowest point of the ridge between two neighbouring summits. The characteristic of the col is that, at such a point, a contour line intersects itself. The following sketch shows the general form of the contours near such a point. FIG. 8. In the shaded regions depicted to the right and left oi the col the ground rises, in the unshaded regions depicted above and below it falls. [The figures on the contour lines show their order of altitude above the sea-level.] Other very special peculiarities might be mentioned, but they are not necessary for the beginner; and the more mathematical reader can easily work them out for himself. 1 iSee Cayley, Phil. Mag., XVIII. 264 (1859); Clerk-Maxwell, Ibid., December 1870. TIME AND SPACE. 76 85. If we draw, by the help of the contour lines, the stream-lines (which, 83, cut them at right angles), we find that they have the following property. In regions above the level of a col, they fall away on both sides from that particular one of their number which passes from a mountain Summit down to the col, and thence up to the neighbouring summ