te W >) he) aE STIs . ee sje "aban Se Oe. Leet Eas ee aoe a sae ses: ay Pet ish Association for the Advancement of Science, | BURLINGTON HOUSE, | LONDON, Ww. VI 7S am ae: % A fhe 150k i y Bee e pf the We flarfe ¥ lar flers are | wa fee fa trhoregh 5 Te beeiee) ton er Ghe« eam j < fe Arvccet cel Mechic Say | eee tad ay ty ‘ Rants REPORT OF THE _ SEVENTY-FOURTH MEETING Bee es! - a OF THE BRITISH ASSOCIATION ADVANCEMENT OF SCIENCE HELD AT CAMBRIDGE IN AUGUST 1904, LONDON : HN MURRAY, ALBEMARLE STREET. 1905. PRINTED BY SPOTTISWOODE AND CO. LTD., NEW-STREET SQUARE LONDON CONTENTS. =o Page OpsEcts and Rules of the Association ........c..cccscsesececeseenseeeeeecsesseees XXX1 Places and Times of Meeting, with Presidents, Vice-Presidents, and Local Secretaries from commencement ..............ecsessceescersscssscccssecececsceces xlii Trustees and General Officers, from 1831 ............ccesceececsescccceccceescseucs lvi Presidents and Secretaries of the Sections of the Association from 1832 ... vii PURO LM VCHINeDISCOUPSOS. ca..cranectaeedsrosesaceceacascesest sagemaanteasa sc ronsete se Ixxvii Lectures to the Operative Classes ........csccsccssecesenceeseneescuscessecsseeceses lxxx Officers of Sectional Committees present at the Cambridge Meeting .....:... lxxxii Committee of Recommendations at the Cambridge Meeting .................. Ixxxiil SEMESTER EN CCOUME [11 Nai ieadin neice tests veveds oval sitarestsgen teeeuteasdeteat este cns lxxxiv Table showing the Attendance and Receipts at the Annual Meetings ...... lxxxvi DIOL. COUN, VOOE—TIODK, wcancsccecanins anes wiseessasonnasscied ualevoensas cine lxxxviii Report of the Council to the General Committee ..............ccceseceseeeeeeeeee Ixxxix Committees appointed by the General Committee at the Cambridge Meet- RR EES EO Orch sa as vanali cnn genapass uno nased nisataar es opusapn ontnonan hans xcvi Communication ordered to be printed a7 extenso ...........ecseceecenceecseeeeees evi Resolutions referred to the Council for consideration, and action if desirable cvi MRO Preinils Gl NEOUO ova cdi'canes's 2 srqeestsligtetena’hlsasssnsssatvsanoanaadese evii Rome or Meating im 1905 an@it90B Pei. eo Sea eviil General Statement of Sums which have been paid on account of Grants for OPIATE SSE tee al A ea oe el i lee ne ae haan Saal cix EGS DIL 0 Tos ae Be ee oc ne me eR oo eee CXXVIli Address by the President, the Right Hon. A. J. Batrour, D.C.L., M.P., PER Satdseaeae ta dashes aisAd cahidaaehe cshives 1 <60Urd aw baasward . Lanyrowslens Ry y. Sonanitis 3 iv REPORT—1904. REPORTS ON THE STATE OF SCIENCE. [An asterisk * indicates that the title only is given. The mark + indicates the same, but with a reference to the Journal or Newspaper in which it is published in extenso. } Page Investigation of the Upper Atmosphere by Means of Kites in co-operation with a Committee of the Royal Meteorological Society —Third Report of the Committee, consisting of Dr. W. N. SHaw (Chairman), Mr. W. H. Dives (Secretary), Mr. D. ArcHipatp, Mr. C. Vernon Boys, Dr. A. Bucuan, Dr. R. T. Guazeproox, Dr. H. R. Muitz, and Professor A, Scuuster. (Drawn up by the Secretary.) ........0..cccecsscosssescessessesseens Report on the Theory of Point-groups. Part IV. By Frances HaRDCASTLE. Magnetic Observations at Falmouth Observatory.—Report of the Committee, consisting of Sir W. H. Prexcz (Chairman), Dr. R. T. GLazpBRooxK (Secre- tary), Professor W. G. Apams, Captain Ornax, Mr. W. L. Fox, Principal Sir Arraur W. RicKer, and Professor A. ScuustmR, appointed to co- operate with the Committee of the Falmouth Observatory in their Magnetic OPSOT VAMOS sii ccntecco-ccacesscessseeeededdesnpesedsicessessnc sesamiae et aaa Experiments for Improving the Construction of Practical Standards for Electrical Measurements.—Report of the Committee, consisting of Lord RayieieH (Chairman), Dr, R. T. GrazesRooxk (Secretary), Lord Ketyrn, Professors W. E. Ayrton, J. Perry, W. G. Apams, and G. CarEy Foster, Sir Otiver J. Loper, Dr. A. Murruean, Sir W. H. Preece, Professors J. D. Evererr, A. Scuuster, J. A. Fremrne, and J. J. Taomson, Dr. W. N. Saw, Dr. J. T. Borromiry, Rev. T. C. Frrzparrick, Dr. G. JOHNSTONE Stoney, Professor 8. P. THompson, Mr. J. Rennie, Principal E. H. Grirrirus, Sir A. W. Ricker, Professor H. L. Cantenpar, and Mir GORGE MAW THINY .s.skstc-tstro»seeeecnosscaivescnes adtuevcsteeundeiaaiaae nnn AppEnDIx I,—On Anomalies of Standard Cells. By F. E. Surrn... iy II.—On the Electromotive Force of Clark’s Cell. By A. P. PPROTIGR, 3 ccac25csae55 388 s2.00esuneconcesonaenae tee eee Seismological Investigations.—Ninth Report of the Committee, consisting of Professor J. W. Jupp (Chairman), Mr. J. Mrunz (Secretary), Lord Ketvin, Professor T. G. Bonney, Mr. C. V. Boys, Professor G. H. Darwin, Mr. Horacr Darwin, Major L. Darwin, Professor J. A. Ew1ne, Dr. R. T. Grazesroox, Mr. M. H. Gray, Professor C. G. Knorr, Professor R, Metpota, Mr. R. D. OrpHam, Professor J. Perry, Mr. W. E. PrumMer, Professor J. H. Poynrine, Mr. Clement Rei, Mr. Netson RicHarpson, and Professor H. H. Turnrr (Drawn up by the Secretary.) I, General Notes on Stations and Registers .............. cceseeeeeeeeens II. Comparison of Records from three Milne Horizontal Pendulums 17 29 30 33 40 42 Ee . = = CONTENTS. Vv Page Mi; Ani Improved Record Receiver ic. ...0.2.ieccsecetsnsenseoadeaeotesses 43 IV. The Origins of large Earthquakes in 1905.............:sesseeeeeeeeeees 3 VY. On International Co-operation for Seismological Work............ 45 VI. Seismological Work now in progress. ..........sssecseeeeeeeeeneeeereees 46 VII. Directions in which Seismological Work may be extended ...... 48 VIII., Experiment at the Ridgeway Fault ........ 0... s.cocccscscescertesenee 51 Underground Temperature—Twenty-third Report of the Committee, con- sisting of Professor J. D. Everrrr (Chairman and Secretary), Lord KELvin, Sir ARCHIBALD GxHIKIE, Professors Epwarp Hott, A. 8. HerscHet, and G. A. Luzour, Messrs. A. B. Wynnz, W. Gattoway, JosppH Dickinson, G. F. Deacon, E. WetHpred, and A. SrraAHAN, Professors MicH1E SMITH and H. L. Cattenpar, Mr. B. H. Brovex, and Professor Haroxp B. Drxon, appointed for the purpose of investigating the Rate of Increase of Underground Temperature downwards in various Localities of Dry Land and under Water. (Drawn up by the Secretary.) ..........cscseeeeeseeeeeeeees 51 Meteorological Observations on Ben Nevis.—Report of the Committee, consist- ing of Lord McLaren, Professor A. Crum Brown (Secretary), Sir Jon Murray, Dr. ALEXANDER Bucuan, and Mr. R. T. Omonp. (Drawn up inh Ji fey Lea CEE 8) ie wocmacBpe bose Gaacdc. POSSE CRE OOe BRO SORE EEE ppdooce contig: Honcrogooosoree 56 The Study of Hydro-aromatic Substances.—Report of the Committee, con- sisting of Dr. E. Divers (Chairman), Dr. A. W. Crosstey (Secretary), Professor W. H. Perxty, Dr. M. O. Forstsr, and Dr. H. R. Le Suzur... 60 Wave-length Tables of the Spectra of the Elements and Compounds.—Report of the Committee, consisting of Sir H. E. Roscozn (Chairman), Dr. Mar- SHALL Warts (Secretary), Sir Norman Locxyzr, Professor Sir JAmMEs Dewar, Professor G. D. Liveine, Professor A. ScHustTER, Professor W. N. Hartzey, Professor Woxtcorr Gisss, Sir W. pp W. Anyey, and Dr. W. E. EA TIERIIINE. “Sec gagre SS Cpe SaSE LARGE ace dNepcotne: dit gn 26nd Janse OseeeenoccL caceREO Eno SBre 66 ‘The Stereochemistry of Nitrogen. By H. O. Jonus, M.A., D.Sc. ............25. 169 Mynamic Isomerism. By T. M. LowRy, D.Sc. ......0....0.csseeccsseccsceseecneenes 193 ieininagmetory and Histories). ..2.1..c0¢assassmansee cscs spetiemeesessssacene 193 II. The Nature of Dynamic Isomerism..,.............000s0seecessseceeaes 196 Ii. Isomeric Changes in which Two Radicals are Interchanged ...... 200 IV. Isomeric Changes in which a Single Mobile Radical is Transferred 204 emo poicale lriverst Gm nce c ieee: tit se cecen ei teannsinwicvnsaedecemeategmione 211 VI. Chemical Properties of Dynamic Isomerides ..................2..00005+ 214 VII. Physical Properties of Dynamic Isomerides .............. ia (Op 2438 216 Wert Reverciple Polymeric Qhange’ 7.22.2 ..cc2scsnnscuveccseddocetsersseteeses “DOO The Movements of Underground Waters of North-west Yorkshire.—Fifth Report of the Committee, consisting of Professor W. W. Warts (Chair- man), Mr. A. R, DwrerRyHovssE (Secretary), Professor A. SMITHELLS, Rey. HK. Jonzs, Mr. Watrer Morrison, Mr. Groree Bray, Rev. W. LowEr Carrer, Mr. T. Farrtny, Professor P. F. Kenpatt, and Dr. J. E. Marr 225 Life-zones in the British Carboniferous Rocks.—Report of the Committee, consisting of Dr. J. E. Marr (Chairman), Dr. WHrreLton Hinp (Secretary), Mr. F. A. Batuer, Mr. G. C. Crick, Dr. A. H. Foorp, Mr. H. Fox, Professor E. J. Garwoop, Dr. G. J. Hinpe, Professor P. F. Kenpatt, Mr, R. Kinston, Mr. G. W. Lampruen, Professor G. A. Lespour, Mr. B. N. Pracu, Mr. J. T. Sropss, Mr. A. Srrawan, and Dr. H. Woopwarp. (Drawn PUY At NOMSCCKCUATY.)i stscto iii atecncasters otters stctecccelceeesntscdinteres aeceeeess 226 Erratic Blocks of the British Isles.—Ninth Report of the Committee, consisting of Dr. J. E, Marr (Chairman), Professor P. F. Kenpatt (Secretary), Professor T. G. Bonnzy, Mr. C. E. Dz Rancz, Professor W. J Sottas, Mr. R. H. Tippeman, Rey. 8. N. Harrison, Dr. J. Horns, Mr. F. M. Burton, vi REPORT—1904. si Page Mr. J. Lomas, Mr. A. R. DwerRyHouse, Mr. J. W. STATHER, Mr. W. T. Tucknr, and Mr. F. W. Harmer, appointed to investigate the Erratic Blocks of the British Isles, and to take measures for their preservation. (Drawn up by the Secretary.) ........seeecsseeeeeeeseeeeseescreesanuneeeeuueeseaeneens 237 Photographs of Geological Interest in the United Kingdom.—Fifteenth Report of the Committee, consisting of Professor JAMES Gerke (Chair- man), Professor W. W. Warts (Secretary), Professor T. G. Bonnny, Pro- fessor E. J. Garwoop, Professor S. H. Reynoxps, Dr. TrmpEst ANDERSON, Dr. J. J. H. Teatt, Mr. Goprrey Brnetry, Mr. H. Coates, Mr. C. V. Oroox, Mr. J. G. Goopcuitp, Mr. Witt1am Gray, Mr. W. JBROME Har- rison, Mr. Ropert Kinston, Mr. J. Sz. J. Paixures, Mr. A. 8. Rerp, Mr. R. Wetcn, Mr. W. Wurtaker, and Mr. H. B. Woopwarp. (Drawn up by the Secretary.) ......sssecccsssserssesecssseccsescaeeresuencsenseseeeesaseccseeenseees 242 Well-sections in Cambridgeshire. By W. Whitaker, B.A., F.R.S. ..........+5 266 Investigation of the Fossiliferous Drift Deposits at Kirmington, Lincolnshire, and at various localities in the East Riding of Yorkshire.—Report of the Committee, consisting of Mr. G. W. LamptueH (Chairman), Mr. J. W. Sraruer (Secretary), Dr. Tempnst ANDERSON, Professor J. W. Carr, Rev, W. L. Carrer, Mr. A. R. DwerryHovss, Mr. F. W. Harmer, Mr. J. H. Howarra, Rev. W. Jounson, Professor P. F. Kunparu, Mr. E, T. New- ron, Mr. H. M. Pratnaver, Mr. CLement Razin, and Mr. THomas SHEP- DAC ee ne Natad pea eure sided epGciecles dsascy'acwes guieSeeseatiasCad eden tuanena key vena 272 Investigation of the Fauna and Flora of the Trias of the British Isles.— Second Report of the Committee, consisting of Professor W. A. HeRDMAN (Chairman), Mr. J. Lomas (Secretary), Professor W. W. Warts, Professor P, F. Kenpatt, and Messrs. H. C. Beastey, E.T. Newton, A.C. Sewarp, and W. A. E. Ussoer. (Drawn up by the Secretary.) ........::sesseeeeeeeeee 275: Udenvale Caves, co. Clare.—Final Report of the Committee, consisting of Dr. R. F. Scuarrr (Chairman), Mr. R. L. Praneur (Secretary), Mr. G. Correy, Professor G. A. J. Conn, Professor D. J. Cunninenam, Mr. G. W. Lamp- LuGH, Mr. McHewry, and Mr. R. J. Ussumr, appointed to explore Irish Waves. (Drawn up) by the Chairman.) ....,<1-+-ccc-s-srsesesessseaccoranneeeettaee 288 The Influence of Salt and other Solutions on the Development of the Frog.— Report of the Committee, consisting of Professor W. F. R. Wsxpon (Chair- man), Mr. J. W. Jenxinson (Secretary), and Professor 8. J. Hicxson. (Drawn! upi by the Secretary.) <..sccwscsseacvecsseetsevccancisneesessdpaneeneeameae 288 _ The Probability of Ankylostoma becoming a Permanent Inhabitant of our Coal Mines in the event of its introduction.—Interim Report of the Com- mittee, consisting of Dr. G. H. F. Nurratt (Chairman), Mr. G. P. BrppEr (Secretary), Dr. A. E, Boycorr, Dr. J. S. Hatpans, and Mr. A. E. Surety 292 Occupation of a Table at the Marine Laboratory, Plymouth.—Report of the Committee, consisting of Mr. W. Garstane (Chairman and Secretary), Professor E. Ray Lanxuster, Mr. A. Srpewick, Professor 8. H. Vines, ANGE OLEssOr We gh elie WGRUDON ays .csciccocsuestins.sodsesen ocecnteemte soa eeman 297 Index Generum et Specierum Animalium.—Report of the Committee, consist- ing of Dr. H. Woopwarp (Chairman), Dr. F. A. Barner (Secretary), Dr. P. L, Scrarer, Rey. T. R. R. Srepsrne, and Dr. W. E. Hoyte......... 297 The Zoology of the Sandwich Islands.—Fourteenth Report of the Committee, consisting of Professor Newton (Chairman), Mr. Davin SHarp (Secretary), Dr. W. T. Buanrorp, Professor 8. J. Hickson, Dr. P. L. Scrarsr, Dr. F. Du Cane Gopman, and Mr. EDGAR A. SMITH ou... ...cceeecccseseceusceeesces 298 Coral Reefs of the Indian Region.—Fourth Report of the Committee, con- sisting of Mr. A. Sepewick (Chairman), Mv. J. Srantey GaRpDIner (Secre- tary), Professor J. W. Jupp, Mr. J. J. Lister, Mr. Francis Darwin, Dr, S. F. Harmer, and Professors A. Macatister, W. A. HerpMan, and S. J. Hickson CONTENTS. vil Page Madreporaria of the Bermuda Islands.—Report of the Committee, consisting of Professor S. J. H1cxson (Chairman), Dr. W. E. Hoyzz (Secretary), Dr. F. F. Bracxmay, Mr. J. 8. Garpiner, Professor W. A. HERDMAN, Mr. A.C. Sewarp, Professor C. S. SHERRINGTON, and Mr. A. G. Tansey, appointed to conduct an investigation into the Madreporaria of the Bermuda Islands 299 Colour-physiology of the Higher Crustacea.—First Report of the Committee, consisting of Professor S. J. Hickson (Chairman), Dr. F. W. GamBLe (Secretary), Dr. W. E. Hoyts, and Mr. F. W. Kresxe, appointed to enable Dr, F. W. Gamble and Mr. Keeble to conduct Researches in the Colour- physiology of the Higher Orustacea................:sssscsescesseceerscensceuseseneses 299 Occupation of a Table at the Zoological Station at Naples.—Report of the Committee, consisting of Professor 8. J. Hickson (Chairman), Mr. J. E. S. Moors (Secretary), Dr. E. Ray Lanxuster, Professor W. F. R. WELDON, Professor G. B. Howns, Mr. A. Szpewicx, and Professor W. C. VIKOLES TOG ST 8 SSE RE BERS aH HBP pbeber Odin ose BBE PHORUe Or: Gus BBHecOcc or AnrHeraboad "ec 300 Report on the Occupation of the Table. By E.S. GoopRicu......... 300 Terrestrial Surface Waves and Wave-like Surfaces.—Fourth Report of the Committee, consisting of Dr. J. Scorr Kerrie (Chairman), Dr. VAaugHAN CorntsH (Secretary), Lieut.-Col. F. Batrny, Mr. Jonn Mixns, and Mr. W.H. WHEELER. (Drawn up by the Secretary.) ...........scsscsesscecseeeees 301 On the Accuracy and Comparability of British and Foreign Statistics of In- ternational Trade.—Report of the Committee, consisting of Dr. HE. CaNNAN (Chairman), Dr. B. Ginssure (Secretary), Mr. A. L. Bownry, Professor S. J. Coapman, Sir R. Girren, and Mr. R. H. Ineris PALGRAVE............ 302 The Tidal Régime of the Mersey.—Report of the Committee, consisting of Lord Ketvryn (Chairman), Mr. J. N. SHoorprep (Secretary), and Professors GrorcE H. Darwin, OspoRNE REyNotps, HELE-SHAwW, and W.C. Unwin, appointed to obtain information respecting the Tidal Régime of the River Mersey, with the object of submitting the data so obtained to Harmonic ENTIBAV OIG bast sof endaptesiaals de> sikds aed edo” ssNisaiwoa teense wemslace doe eb esis aa gedadddaa’ ates 318 Archeological and Ethnological Researches in Crete.—Report of the Com- mittee, consisting of Sir Joan Evans (Chairman), Mr. J. L. Myrzs (Secre- tary), Mr. R. C. Bosanaurr, Dr. A. J. Evans, Mr. D. G. Hogartn, Pro- fessor A. MAcALISTER, and Professor W. RIDGHWAY .......ecsececeececeneeeees 321 APPENDIX,—Excavations at Knossos, Crete, 1904. By Dr. ArnrHuR J. EI VANS VT eaitevee se catewateseccans de kotise dovcnodcummecnvenesatinns 322 The Lake Village at Glastonbury.—Sixth Report of the Committee, consisting of Dr. R. Munro (Chairman), Professor W. Boyp Dawkins (Secretary), Sir Jonn Evans, Dr. ArtHurR J. Evans, Mr. Henry Batrovr, Mr. C. H. Reap, and Mr. A. Burierp. (Drawn up by Mr. ArrHurR BuLLEID and Pree Sit, GHORGEACERAY..) 2's gomecepeiiateastsste sacasaecce pines cclenes far heki« cjoanees 324 Anthropometric Investigation in Great Britain and Ireland.—Report of a Committee, consisting of Professor D. J. CunnineHAM (Chairmen), Mr. J. Gray (Secretary), Mr. N. Annanpatz, Dr. A. C. Happon, Dr. C. 8. Mynrs, Mr. J. L. Myrus, Professor A. F. Drxon, Mr. E. N. Fattatzz, Mr. Ranpatt Maclver, Professor J. Symrneron, and Dr. WATERSTON ......... 330 APPENDIX.—Pigmentation Survey of the School Children of Scotland 3385 Excavations on Roman Sites in Britain.—Report of the Committee, consisting of Dr. A. J, Evans (Chairman), Mr. J. L. Myrus (Secretary), Professor Boyp Dawxins, Mr. E. W. Brasroox, and Mr. T. Asupy, appointed to co- operate with Local Committees in Excavations on Roman Sites in Britain 337 viii REPORT—1904. # Page Anthropometric Investigations among the Native Troops of the Egyptian Army.—Report of the Committee, consisting of Professor A. MACALISTER (Chairman), Dr. C. S. Myrrs (Secretary), Sir JoHn Evans, and Professor D. J. Cunnryeuam. (Drawn up by the Secretary.) ....-seeeeesrsssseeeererees 339 Anthropological Teaching.—Interim Report of the Committee, consisting of Professor E. B. Tytor (Chairman), Mr. J. L. Myres (Secretary), Professor A. Macauisrsr, Dr. A. C. Happon, Mr. C. H. Reap, Mr. H. Barrour, Mr. F. W. Rupter, Dr. R. Munro, Professor FLrypERs PETRIE, My. H. Live Ror, and Professor D. J. CuNNINGHAM, appointed to inquire into the present state of Anthropological Teaching in the United Kingdom and elsewhere ... 341 The State of Solution of Proteids.—Second Report of the Committee, consisting of Professor HatLinuRton (Chairman), Professor E. Waymourn Rxip (Secretary), and Professor E. A. ScHAFER, appointed to investigate the state of Solution of Proteids ............cseceeceeeecnceecneeecsecneceseseecsesecneneenes 841 The Physiological Effects of Peptone and its Precursors when introduced into the Circulation Interim Report of the Committee, consisting of Professor E. A. ScHA¥FER (Chairman), Professor W. H. Tuompson (Secretary), Pro- fessor R. Boyce, and Professor C. S. SHERRINGTON .........0s:eeeeeser neers eeees 342 Metabolism of the Tissues.—Report of the Committee, consisting of Professor Goren (Chairman), Mr. J. Barcrorr (Secretary), Sir MicHanL Foster, and Professor STARLING ......sccssececcsenccecerscsserecscsccnsesestessecencececesess The Respiration of Plants.—Report of the Committee, consisting of Professor H. MarsHatt Warp (Chairman), Mr. H. Wacmr (Secretary), Mr. F. Darwin, and Professor J. B. FARMER ...........csccceessccccecsseceensescecnsecsceeuererseereens 544 Botanical Photographs.—Report of the Committee, consisting of Professor L. C. Miatt (Chairman), Professor F. E. Wuiss (Secretary), Mr. Francis Darwin, and Mr. A. G. Tanstxy, on the Registration of Photographs of Boasting UMMGO TOS rarcdy 9% cclavScbSe cab linees banaystnaemhd demas onde ee eAaeiiee Albena 345 Experimental Studies in the Physiology of Heredity.—Report of the Com- mittee, consisting of Professor H. MarsHatt Warp (Chairman), Mr. A. ©, SEwaRp (Secretary), Professor J. B. Farmer, and Dr. D. SHARP ............ 346 Report to the Committee by W. Barzson, M.A., F.RAS. ...........0665 346 The Conditions of Health essential to the Carrying-on of the Work of Instruction in Schools.—Report of the Committee, consisting of Professor C. 8. Suerrineton (Chairman), Mr. E. Wuirp Wattis (Secretary), Mr. E. W. Brazsroox, Dr. C. W. Kimuins, Professor L. C. Mratt, and Miss MAITLAND .......... Sasa dndeanhch sehr onesscaseash acetals on-cespi shou nkapnnee een 471 5. tPlan of a Combination of Atoms having the Properties of Polonium or Radinm.+ By Lord Kenyin, FURS. ............c00.+++s0deasss00 oe 472 tElectrical Insulation in Vacuum. By Lord Kevin, F.R.S.......0.000008 472 *Electrical Conductivity of Flames. By Dr. H. A. WILSON ......0000000+: 472 — go to oN D> BS =e rte Liles = ® OQ co g. fe) i=} 2; tg rm ° =] ® Lad St oO @ ° = aa] ° ct ee) fe) = ® Z ise] co) 2 o Ee) Lal (e} =e) b 3) i=} m i=} ee Pmt tt eee ee eee tase estate eee eee Rete eee eases assed es eessesseSenss esses esese® 9. The Production of Radio-active Surfaces. By ©. E. 8. PHILLIPS ......... 473 10. *The Kinetic Theory : Determination of the Size of Molecules. By J. H. SEMAING ish catnesncnsissances env Oinsvecet vsgnstts¥esieseass ads ak sestiens soem aaa 473 11. Dr. Grindley’s Experiments on Steam in the Light of the Ether-pressure Theory. By J..MAGPARLAWE GRAY |...2....1040.00s+.0020 hich Ia tr REPORT —1904. Page . Hexachlor-a-Picolin and its Derivatives. By W. J. Senu, M.A., F.R.S. 501 The Change of Conductivity in Solutions during Chemical Reactions. By _ FAY, MISTIVAIN LAE iit ts canhebrapeeae tutes ses coed delunclesisels oghiesnue deeb be eam 501 On Double Acetylides. By Major A. E. Epwarps and Professor W. R. HT ODEKUNSON MEDID My peace: ctcpsaesnlaed- sities setts 597 6. Certain Biological Aspects in the General Pathology of Malignant New Growths. By J. A. MURRAY, MiB. .........c.cesessecn+sosnesnewuesse ese mmnanme 598 7. On the Fertilisation of the Ege of the Axolotl, By J. W. Jenxnyson, GAD Bras conceebeasormtaean eeancomeaeies dents amicsasass scearievswveaeeteys seamen 600 8. Some New and Rare Isopoda taken in the British Area. By W. M. PAU DMRS ATI, Mis SCs ceria ccieecoewiecioritse stones recess sees seseeemcecps cece ta 601 9. tSome New and Rare Schizopoda from the Atlantic Slope on the West of Ireland. By E. W. L. Honr and W. M. Tarrmrsatt, B.Se............. 602 10. Some New Copepoda from the Atlantic Slopes. By G. P. Farran ...... 602 11. On a New Species of Dolichoglossus. By W. M. Tarrmrsatt, B.Sc....... 603 TUESDAY, AUGUST 23. . The Budgett Memorial : (i) Note on the Developmental Material of Polypterus obtained by the late Mr. J. 8. Budgett. By J. GRAHAM K&ERR..............:0ceeceees 604 (ii) Notes on the Development of Phyllomedusa hypochondrialis (Daud). By ahs a MDLES sepkssereancasescrsnsspoanacasechceedeseoreorude seoteas tees ranean 605 CONTENTS. xix Page 2. Rejuvenation. By Caartus Sepewick Mrwor, LL.D., 8e.D............006 606 3. An Experiment with Telegony. By Cuartes Sepewick Minor, LL.D., ERO Miele w cecht deta occu: Sea ga dds «Bu Faeliewabn Sufddsisledind valondl Cade xewecddsintes tains 606 4, The Harvard Embryological Collection. By CHARLES SepewicKk Mrnor, DE ERP redticaitg nn dev daaisiet sides ¢sGaisife dda aa gvinne nan cnet Mad sagde dade. Mee «33 606 5. The Preciitn Test in the Study of pone pa Ga By Dr. ROR GR pH NO TUATT EUS eh osc o0t cons fae0, ct tletaehandeeeeadseds fai oy aawadee 607 6. ¢The Mimetic Resemblance of Diptera for Hymenoptera, By Professor BIS POULTON PH bic Se oe vet e sbiis acshic oe ac shiiedsgoe haces cl'ysccetedusltts tener acadepe ces 607 7. The Evolution of the Horse. By Professor Henry Farrrietp Osporn... 607 8. +The Histogenesis of the Blood of the Larva of Lepidosiren. By Dr. T. H. LE TEIUIET coonocdhedodaos dances sone oaabaiog JodedonsccooJiEcesuBdagencoddeudere tacueance aa: 608 WEDNESDAY, AUGUST 24, 1, The Effects Produced by Growing Frog Embryos in Salt and other Solutions. By J. W. Jenkinson (p. ZSS)i a octane ocncceacceoryoussne cuca tee 608 2. On the Pacific, Atlantic, Japanese, and other ‘ Palolos.’ By Professor ECMNLOEEL Rus Ser caste ccsecu aoe esacl wecteces ceretestottiredeecrae utes secceceteer. 608 3. On the Elucidation of Cellular Fields of Force by Magnetic Models, By PEOLESSODNUAROUSEVARTOG: 1 2essucs dele: sas vootcadadeta ce teack alice detnarasdeoesode se 610 4, *Demonstration of Cytoplasmic Figures in Segmenting Eggs of Ryn- chelmis (Prof. Vejdovsky). By Professor Marcus HARTOG ...........0668 611 Section E—GEOGRAPHY. THURSDAY, AUGUST 18. Address by Dovetas W, FREsHFIELD, F.R.G.S., President of the Section ... 612 1, Cyrene: an Illustration of the Bearing of Geography on History. By SRE ERR TETEE NN Nig sg nea dai punk dasisgaian dain) Avdnned naa nd aecises saga sores 626 2. Ptolemy’s Map of Asia Minor: Method of Construction. By the Rev. Ae SORONEN byl) 5 cccacaticavaseuevcadactisnedasercea-concveciechescatanoudciureare 627 FRIDAY, AUGUST 19. 1, The Fulani Emirates of Northern Nigeria. By Major J. &. Burpon, M.A., PEM die ec x baixees ta he aa Uaidode cx br da tsa laa wide dattay dass Magplde babs és 628 2. Methods of Topographical Survey. By Major C. F. Crosz, C.M.G., R.E. 629 3. The Glaciers of the Caucasus. By Maurice DE Ditcny ..................04. 631 4. Scenes and Studies in the Nile Valley. By Arraur Srrva Wuirtre......... 631 MONDAY, AUGUST 22, 1, A Journey around Lake Titicaca. By Arraur W. Hitt, M.A. ......... 631 2. Glacier-bursts, By CHARLES RABOT ........ccccccceccsseecseceseveeceusenceeses 632 3. Report on Terrestrial Surface Waves (p. 301) ...........eccceeceeecseeseuseeee 633 4, Brunanburh: Identification of this Battle Site in North Lincolnshire. Peer isey, ATURE ENONT, MAN, Liss cine ddanepneae ddecviebiessdaskcesincadses 633 5. hy Lipari Islands and their Volcanoes. By Trmpnst ANDERSON, M.D. an a2 KX REPORT—1904. TUESDAY, AUGUST 23. Page 1. Exhibit of Maps and Photographs showing Effects of Earth Movements near Naples; with a Note on the Area affected by them. By R, T. GUNTHER, MAL cscssrnonns igs enehersanedawant ind gs cudeninnnae whnluete = Baanameenne aes 634 2, On the Nomenclature of the Physical Features of England and Wales. By Huei Ropert MILL, D.Sc. .....cccecseeeeeseseeeeessesneeeeseereeeseesesesees 635 3, Changes in the Fen District. By H. Yur OrpHam, M.A. ..........20.000 635 4, Vegetation of the Fen District. By Professor R. H. Yarr, M.A, ......... 636 5. Notes on the Malabar Coast of India. By R. S. Leprrr, M.A., LL.M. 6386 6. A Geographical Object Lesson: Passes of the Alps. By A. W. ANDREWS 637 7. *The Scottish Antarctic Expedition. By W.S. BRUCE .........cccceeeeseee 637 8, The First True Maps. By C. R. BEAZLEY, M.A. .....cccecsseceseceseneeeenens 637 Section F.—ECONOMIC SCIENCE AND STATISTICS. THURSDAY, AUGUST 18. Address by Professor WiLLIAM Smart, M.A., D.Phil., LL.D., President of the OCHO +. cvs.ses oh coemmuact nenpibianesbaissdnpieise' cumempaleavecteterer slides smeetan aan 639 1. Tests of National Progress. By A. LL. BowLEY, M.A, ......scccccseeseeeeenes 647 2. A Moot Point in the Theory of International Trade. By Professor F. Y. EDGHWORTH,* D.Ciic ov cock sowesspanessetacnedesacedsassaetvetnaccnelneumnaite amen 647 3. The Influence of Agricultural Improvements on Rent. By Professor AS OW. ELUS, M. AS Giacponpcecocconsseucaaesatcthiserev'ssacod cee ones ineite ta nema 647 FRIDAY, AUGUST 19. 1, The Incidence of Protective Duties on the Industry and Food Supply aaa Brance, «By YVESiGUOUG ec cnscccsncestersnaccosnavaceane satis delmasasnesemne 2, The Effect of Protection on some German Industries. By Professor _ PhOWA i 205d Sis cnet aie caeetenteereucnetices Pears axaue ditt eter weet eee eds see ne tne 651 3. Free Trade and the Labour Market. By Professor H. Drmrze............. 653 4, Economic Theory and Fiscal Policy. By L. L. Pricn, M.A. ............06 654 MONDAY, AUGUST 22. 1. The Economic Importance of the Family. By Mrs. Bosanquet............ 655 2. Cotton Growing in the Empire. By J. A. HUTTON ........:sccsereceeeeesenes 656 3. Report on the Accuracy and Comparability of British and Foreign Statis- tics of International Trade (p..302) ...5.0.....5.+2ss0ccccsconessosersteentansey™ 658 TUESDAY, AUGUST 23. 1. Changes in Nominal and Real Wages in Belgium. By Professor E. MATIATM 5.5 cvaene nooo ented sosiasinelese dorepiieassnnaucanpi'¢*nasianeeeenan sn mnceneiainnee 658 2. The Development of Towns. By T. C. HORSFALL............-+sseeeeeeeerv eee 660 3. The Town Housing Question. By Mrs, FISHER ......scsssssesceseereenereees 660 4. The Increase of Suburban Populations. By Srpney Low, B.A. ............ 661 5. The Relation between Population and Area in India. By J. A. Bainzs, | PO elaas cco ea hsa onnnes ead) onidedsasuenmamebleh tars rele tine asta non kata asta 662 6. Investigations on the Nutrition of Man. By Professor ATWATER (p. 758) 663 CONTENTS. xxl WEDNESDAY, AUGUST 24. Page 1. The Modification of the Income-tax. By W.G.S. ADAMS.......0....5..0 663 2. A proposed Substitute for the Sugar-tax. By Barnarp ELLINGER ...... 664 3. Some Features of the Labour Question in America. By C. J. Haminron 665 4, The Employment of the Graduate. By H. A. Ropurts, M.A. .........+. 666 Section G.—ENGINEERING. THURSDAY, AUGUST 18. Address by the Hon. C. A. Parsons, M.A., F.R.S., President of the Section 667 1. *The Origin of Sand Ripples. By Mrs. HERTHA AYRTON ........ceeeeeeees 676 FRIDAY, AUGUST 19. 1. tFlame Temperatures in Internal Combustion. By Ducatp Currx ...... 676 2. *On the Specific Heat of Gases at High Temperatures. By Professor tere DRONE Es EAS eee re dorcdeesctiee cere aidneceddcossaasesates ctpsedaeeneesons 676 3. tExhaust Gas Calorimetry. By Professor B. Horxrinson, M.A, »......... 676 4, +The Effect of Receiver Drop in a Compound Engine, By J. W. Hay- ROPERS ENE arc cts tues. .dusauiduusseepiertcs saechenseuaragennontdoeameazinn ins «moa 676 5. Superheated Steam: Wire-drawing and other Experiments.. By A. H. TUDO Bs A a dace eR nose so ncd ei nnge Raseecu gia teotea ste seerbeoboanda 37cun SoeMMBaer 676 MONDAY, AUGUST 22 1. Electricity from Water-Power. By A. A. CAMPBELL SWINTON............ 677 2. The Use of Electricity on the North-Kastern Bailveny and on Tyneside. By ©. H. Merz and W. McLELLAN ........:scceeseeeeceenseeeectenesen seen ecees 678 8. tTesting Alternating-current Induction Motors by a Hopkinson Method. By W. E. Sumpner and R. W. WEEKES.........006..seceseessseseeeseneeee ers 679 4, Energy Losses in Magnetising Iron. By W. M. Morpny and A, G. MMPI he pet eo atten k seats snadonsbabubws ncnncescventuecnen «a cenketeee=rt) omnes 679 5. {Distribution of Magnetic Induction in Multipolar Armatures. By W. M. PETORITON, coos sce s cee cess asitcossacueosiesdederececsessifelssnvasesiisnssgue¥art=nalestors 682 6. On Large Bulb Incandescent Electric Lamps as Secondary Standards of Light. By Professor J. A. Fremine, M.A., D.Sc., FBS. oo... eee 682 7. Some Investigations on the Ten-candle Power Harcourt Pentane Lamp made at the National Physical Laboratory. By Ciirrorp C. Parerson 683 TUESDAY, AUGUST 23. 1, Report on the Tidal Régime of the River Mersey (p. 318) «......0::.ee..eee 684 2, +The Control of the Nile. By Major Sir Hansury Brown, K.C.M.G..., 684 3. A Universal Testing Machine of 300 tons for Full-sized Structural Members. By J. H. Wioxsrpen, Pres.Inst.Mech.E. ...........sesseeeeeeees 684 4, +The Effect of Rapidly Alternating Stresses on Structural Steels. By Professor J), O. A RNOLD. ......ccoennccsscvansonce sieseresestarscensreeccaensesnsases 684. 5. The Production of Magnetic Alloys from Non-magnetic Metals. By R. A MMPPUACEEATAY | Wacuvspaecstsesrcasaccvaxsssqecsdsvevsdcudensicaccsvsesrtatsseoctiyecccerssres 685 6. *Indicator Tests on a small Petrol Engine. By Professor H. L. Cat- HENGDV AUREL EUs eter re vscacecarevertccecersccucesesssnestsioscosccbecventeccctocsssessens 686 Xx REPORT—1904. 1. tSide Slip in Motor Cars. By Horace Darwin, F.RS., and O, V. WEDNESDAY, AUGUST 24. Page IER TRITON. ag ccededececepbgecteavsthoe duoce’duocsnasica vee’ keen cp cep ¥pseie ss «Al CeMbeaeees can 686 . *An Electric Temperature Alarm. By Horace Darwiy, F.R.S. ......... 686 . The Electrical Conductivity of certain Aluminium Alloys as affected by Exposure to London Atmosphere, and a Note on their Micro-structure. By Professor ERNEST WHILSON.......:c:ssseeeeeeeeneeeeeeeeeesenseeeeesseesen eons 686 . The proposed Barrage of the River Thames. By JAMES CASEY . ......+++ 686 . Testing Alternate-current Motors by Continuous Current. By WiLn1Am (CRAP VAR MG IBN Ey \ercsseccecs os catsesceseedessnscseaneucndenans oath eueaesesammannee 687 . tThe Action of Lightning Strokes on Buildings. By KitLiInewortH PETHDIGHS: biceae ea ctonee td cnacctakcekeccedebetesbsavensdiWapcageadea seats twee +i meRmammnenas 688 Section H.—ANTHROPOLOGY. THURSDAY, AUGUST 18. Address by Henry Batrour, M.A., President of the Section .........:.s:ee0e+ 683 a, ») “> 5 Vv to The Eyolution of the Lotus Ornament. By Professor Oscar Monzetius 700 *Note on the Entomology of Scarabs. By Professor W. M. FLINpeRs PEP R UE) Colas Mal eR. sac sscos corenewecanneseoy vets en ssp epepese ee temeeemnee 700 {Excavations at Ehnasya in Egypt, with special reference to a Series of Roman Lamps. By Professor W. M. Fuinpers Perris, D.C.L., LL.D., MEM Eea © sug ice. «gees oadanBbpeeens Gnas veasu ivkvaduiemcsgnpianseces 0 ownedans Veena 701 . Recent Explorations at Great Zimbabwe. By R. N. HALL............4000++ 701 FRIDAY, AUGUST 19. . Report on Anthropometric Investigation in Great Britain and Ireland FP a) eters cs coc conut lf ecyusqackl ole civin 3 seeahane saa a seeateoue 701 . “The Alleged Physical Deterioration of the People. By Professor D. J. CunNiEVGiAM, MED), HORS. tctsiecnessasssoncassarestheesevereccsenetssigcag ammaane 701 . A Comparison of the Physical Characters of Hospital Patients with those of Healthy Individuals from the same Areas, with Suggestions as to the Influence of Selection by Disease on the Constitution of City Populations. By ECP SHRUEEATE, MEDD. ie; sesccunsecatapuntervee BEC HICE ELD oon ooce 702 An Anthropometric Survey: its Utility to Science and to the State. By VOHIN GRAY. SS Chee meee renee Pedgsneeeatisagcesssceweseart es (eee. 704 . “Discussion on Physical Deterioration and Anthropometric Survey......... 705 . The Progress of the Ethnographic Survey of Madras. By Enear RESURSTON cack coe ceiaee eR Sees Be ees ccs cee teen sincere eons siglo dees eee ee 705 . Interim Report on the Present State of Anthropological Teaching (p. 341) 706 » Recent Anthropometric Work in Scotland. By J. F. Tooumr, F.1.0. ... 706 . The Distribution and Variation of the Surnames in East Aberdeenshire in 1626 ,and.1896," By J. H. Tocwme, FLO, 2.3, .iassasanaxasetewevt sspeaneetgiee 707 MONDAY, AUGUST 22. . A Plan for a Uniform Scientific Record of the Languages of Savages. Pyotr tOHARD Tempra, Bart,,C, 0. By ssosovccacsssaposs sadduancebasssosnepeave 708 » On Group-Marriage in Australian Tribes. By A. W. Howirr ...........6 709 CONTENTS. xxl Page . The Passing of the Matriarchate. By R.S, Luppzr, M.A., LL.M. ...... 709 . An Anthropological View of the Origin of Tragedy. By Professor W. LEBEL HA WueAcyeoy MU Acree Pete aS, AoA. Ama d’s sea atematecn nei seaeviversosatee ee ssipesas 710 » The so-called Tomb of Mena at Negadeh in Upper Egypt. By Joun wid UPRERSBNES, ERNE gg coc ccctn cath ond sasuachsniuessus anise dr toosesckscocsesacsoe0t sccm sera eess's ¥xsaime ii tapt iene 795 3. Hybridisation of Cereals. By JoHn H. Witson, D.Sc. .....sseeceeeeeeeeee 796 4, The Clover Mystery: A Probable Solution, By Roserr H. Evtiot...... 797 FRIDAY, AUGUST 19. 1, On the Problems of Ecology. By Professor A. G. Tanstny, M.A., WET espe Afel a tanecsungthougionsvex} -s¢néaaeeys Cie nalana 802 9. *Exhibition of Kammatograph Photographs showing the Movements of father bey Mrs, SD. E1, SOGOU, <.ccoasstevssciduseases eas unsstnaczhevenaa ieee 802 10. *On the Artificial Formation of a New Race. By Professor G. Kizss... 802 11. The Present State of our Knowledge of the Cytology of the Cyano- piyces. By HAROLD WAGER, BLES, ~..5...cc0sccaccqaene redverssnaeereeninaa 802 12, The Virgin-woods of Java. By Dr. J. P. LOTSY ...cccccccsessssssessereeseees 803 “ Sus-SEcrion oF AGRICULTURE. 1, Analysis of the Soil by means of the Plant. By A. D. Hatt, M.A....... 804 2. The Probable Error of Agricultural Field Experiments. By A. D. BTS ks | MY Aso see ane saer vances dana scuccicstichavtnt cesrasarecsveroo regan ana 804 3. The Determination of the Availability of Insoluble Phosphate in Manures. By T. S. Dymonn, F.I.C., and GrorGn CLARKE, A.L.C. ......cceesesereee oe 805 4. The Influence of Sulphates as Manure upon the Yield and Feeding-value of Crops. By T. 8. Dymonp, F.1.0., F. Huenzs, and ©, Jure ..........5 807 5, The Improvement of Poor Clay Soils by White Clover and other Leguminose. By Professor T. H. MIDDLETON, M.A. .....csceceeescceeeeeees 808 6. A New Method of Forming Nitrites and Nitrates. By EpwAarp Joun Russet, D.Sc., and NoRMAN SMITH, M.Sc. ........ccssesssescssccccccccceeeene 809 7, The Chemical Composition of Different Varieties of Mangels. By. T. B. aon eM. and I, A. ‘Burry, BTC)! ../i.ssscsiaecestes thee oa ueuicave 810 8. Variation in the Chemical Composition of Mangels. By T. B. Woon, eens. As Benny, FLO, | 5 0,0che1c0sescoiviesWtKecavdeseugeh eaeeead 811 —_ to CONTENTS. XXVI1i MONDAY, AUGUST 22. Page On the Forms of Stems of Plants. By Lord Avesury, D.C.L., F.R.S.... 812 . *On Recent Researches on Parasitic Fungi. By Professor H. MARSHALL VAD OH OLG.S. coh osteeackeeabeopsca abet ihe Scbunmbhen see Sic tasteonraecusEivicanss 813 . *On the Vegetative Life of some Uridinee. By Professor Jako, SRE GSO Nec oe cece ccc catch othe vie wane sat. oisle ona spats olevbarat Gauiene wept ne duadmhwes'eppiatabiaes 8138 . *On the Development of the Acidium of Uromyces Poe, and on the Life- History of Puccinia Malvacearum. By V. H. Buackman and Miss ELELEN C. 1. FRASHR......0000-scsssveccssonscescrssenccscconcssenerasssaecence:sseeees 813 TUESDAY, AUGUST 23. 1, Sunshine and CO, Assimilation ; an Account of Experimental Researches, By Dr. F. F, BrackMAN and Miss MATTHAEL ........csesseeeseeeeecseenernens 818 2. Struggle for Pre-eminence and Inhibitory Stimuli in Plants. By Pro- POMBO Vay PREBRA AA Ids sisindeseeSabontctandeckasenhsisessaceeddunueds oaeussatsonsens es 814 3. On the Proteases of Plants. By Professor 8S. H. Vinus, F.R.S. .........04 814 4, Sexuality in Zygospore Formation. By Dr. A. F, BLAKESLEE............... 815 5, Some General Results of the Localisation of Alkaloids in Plants. By rafessor li, Hi RBARAY. .scasnacessis nee. s-vsaaneianphaasntacpaaemearobeaacondts eee: 815 G. The Discovery of a New Alkaloid in Strychnos Nux Vomica, By Dr. Reed TODA Maes cc owe. oe coma metena tase sie clase buaabiaeite chldcaBauued weak Made taccasaces 817 . On the Significance of the so-called Anti-ferment Reaction in Geo- tropically Stimulated Roots. By Professor F. CZAPEK ..........ssereeeeee 817 WEDNESDAY, AUGUST 24. . “A Measurement of the Great Swamp Cypress at Santa Maria del Tule, Moexicors By ALFRED -P, MADDSLAY. s.2/dij,c0c) vostacevestessoeoesendeessea sesso 817 . “Oxidising Enzymes and Katalases in Plants. By Professor R. Coopar 818 3. *On the Pollination of Gymnosperms. By Professor K. Fusr.............++ 818 4, The Dissemination and Germination of Arceuthobiwm occidentale. By Dry. EER GR ly ERERON) « wel [ses tid Soi aL wdwin Aduttoucate MubWauiaale ih sebere texas 818 5. *On the Transpiration Stream in Small Plants. By. Dr. Orro V. Darsi- BHIBE .cscoinscenuscevevessiscdduavcess doessscdesdesceed sendddedaccdtceveowsersaressca sos: 818 6. On a Brilliant Pigment appearing after Injury in Species of Jacobinia fe N.O. Acanthacem)... By. J,.PARKIN, MA. sscssccsdsecsssavedeeesescene ovvesesie 818 7. Saponarin (‘Soluble Starch’). By GuORGE BARGER ........:scceseeeeeeneee 819 8. On the Centrosome of the Hepatic. By K. Miyrxs, M.A., Ph.D... .,... 820 9. Further Cultural Experiments with ‘ Biologic Forms’ of the Hrystphacee. Ey ENTS SALMON Las. ns sbanssesepenprsoesngesdesvaristsaceme ASS eBAbenC 821 10, The Inheritance of Susceptibility and Immunity to the Attacks of Yellow GUSH ey Ebygek Eley SERENA. fay ck nae ocmseosssieviencsscesasddecdecederoosaanessces 822 11. Infection Experiments with various Uredinee. By Miss C. M. Gipson... 822 12. *On the Normal Histology of the Uredo of Puccinia glumarum. By Bet AAT S san Kane tah iini'nats onttavhn ieleak Maite eaoandeandden deeda kde aastclsde es 822 13. Pineapple Galls of the Spruce. By E. R. Burpon, BuA............eeeeeeee 822 14. *The History and Distribution of Catesby’s Pitcher Plant (Saracen Catesbei). By Professor JoHN M. MACFARLANE.........:cscceeee ceceeseeee 823 . “Observations on Two Species of Alpine Rose and their supposed Hybrids. By Professor JoHN M. MACFARLANE .....sscscsscssesecnscucavesenesseseeesssees 828 16 Ife 18. 19, 20. XXvIi REPORT—1904. ’ Page *Exhibition of a Bigeneric Hybrid between Gymnadenia and Nigritella. By Professor JoHN MM, MACKARDANH 212.210. Jscescuceovertecescodsteatossedsdeaa 823 The Destruction of Wooden Paving Blocks by the Fungus Zentinus lepideus Fr. By A. H. Reervatp Butrer, D.Sc., Ph.D: ..........eeeeee 823 The Reactions of the Fruit-bodies of Lentinus lepideus Fr. to External Stimuli. By A. H. Reernatp Butrer, D.Se., Ph.D. ........cccceeeeeeeeeees 824 The Structure of the Ascocarp in the Genus Monascus. By B. T. P. BARKER, MGAGS 203 seeseaeebeseeses gonesotodocbecdaoncondecadunckananueriace Pecan ct 824 Further Observations on the Ascocarp of Ryparobius. By B. T. P. PEM ype Nl As -\cd.s We eoeccratoa ea nic oaag osear dhaamaee tAceces 0k eid emeeas tae 825 Some Features in the Development of the Geoglossacee. By Dr. ELias SepPrNNDY Three Re sthee chu ysieet cet, SOE CHa SHOLEeOdod Ban senee rc 826 Section L.—EDUCATIONAL SCIENCE. THURSDAY, AUGUST 18. Address by the Right Rev. the Lorp BisHor or Hererorp, D.D., LL.D., Pronident: of the:-Boction’ 6, Wk sad yews. Oésiscadavescleehhd Whe ae 827 - 1. The Present Educational Position of Logic and Psychology. By Miss EDM, AONB: «5 ovotodeua Zo udsldeibedks oabsocetewneus svete tac katya her eee aaa 840 2. Comparison of the Intellectual Power of the Two Sexes. By Dr. J. pp RGROSY: ick cdi ss peceeren: Priduevaseustcitostenesesehsscaits deaees dee Oleieanancemeemaam 841 3. The Teaching of Experimental Science in the Secondary Schools of Ireland. By the Right Rev. Geranp Motnoy, D.D., D.Sc. ....cccceeee eee 842 FRIDAY, AUGUST 19. 1. Specialisation in Science Teaching in Secondary Schools. By J. H. EONAR ORES Be P css ho cek«« ncbeae todas tuaab le taete Seope« ewsneedent saps dy Ra 844 2, Short Description of ‘ Realistic Arithmetic.’ By Lieut.-Colonel G. Mac- IGIINIMANY SULA LO MENA, a oo. Bosca se the A tease secese renee aces eoca con OR te 844 3. Report on the Influence of Examinations (ps. 860), .....-eachened. ke auaeeeebaee 844 4. Discussion on School-leaving Certificates. Opened by the Rev. Canon tomes Peete MG do sAtsdisaivaemeceaca se naten senate 845 5. The Need of Scientific Method in Elementary Rural Instruction. By BAS) RATT 5 INA cae hs scmadeobhns REEMA a tosthle. gp Obs CGE yon meee «SPST ‘GI toqmeydas ‘nyHONIKUTG sprees aol SES sau oT o'd Sa “jeg peg qroqoy ag ‘uo WwSry oy, | ‘SVU “VIM “aa ‘NOSNIGON “y “ZL ‘ATH eas L teteeseseee scvare 7 (KISOIIOIM PAO] onL “AQMOLIBA JO [AVA oT, ** SplARq 4g Jo doystg pso'y ony, ‘Sad “a'W “bsg ‘uerat, “HP . Gwe bem “oom a) 0. 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REPoRT—1904. TRUSTEES AND GENERAL OFFICERS, 1831-1904. TRUSTEES. 1832-70 (Sir) R. I. MurcHIson (Bart.), | 1872 F.R.S. 1832-62 JOHN TAYLOR, Esq., F.R.S. 1832-39 C. BABBAGE, Esq., F.R.S. 1839-44 I. BATLY, Esq., I'.R.S. 184458 Rev. G. Pracock, F.R.S. | 1883 Sir J. LUBBocK, Bart. (now Lord AVEBURY), F.R.S. 1881-83 W. Sporrrswoopk, Esq., Pres. RS. Lord RAYLEIaHn, F.R.S. 1883-98 Sir Lyon (afterwards Lord) 1858-82 General E. SABINE, I’.R.S. PLAYFATR, F.R.S. 1862-81 Sir P. EqERtTON, Part., F.R.S. 1898 Prof, (Sir) A. W. Ricker, F.R.S. GENERAL TREASURERS. 1831 JONATHAN GRAY, Esq. 1832-62 JOHN TAYLOR, Esq., F.R.S. | 1891-98 Prof. A. W. Ricken, F.R.S. 1898-1904 Prof. G. C. Fostmr, F.R.S. 1862-74 W. SPOTTISWOODE, Esq., F.R.S. | 1904 Prof. JOHN Prrry, F.R.S. 1874-91 Prof. A. W. WILLIAMSON, F.R.S. | GENERAL SECRETARIES. 1832-35 Rev. W. VERNON TIARcOuRT, | 1868-71 Dr. T. A. Hrrst, F.R.S., and Dr, F.R.S. 1835-36 Rev. W. VERNON HARCOURT, ¥.R.8., and F. Batny, Esq., F.R.S. 1836-37 Rev. W. Vrrnon HARcovurt, F.R.S., and R. I. Murcnison, Esq., F.R.S, 1837-89 R. I. Murcnison, Hsq., F.R.S., and Rey. G. PrAcock, F.R.S. 1839-45 Sir R. I. Murcnison, F.R.S., and Major E. SABINE, F.R.S. 1845-50 Lieut.-Colonel EK. SABINE, F.R.S. 1850-52 General E. SABINE, F.R.S., and J. ¥. ROYLE, Esq., F.R.S. 1852-53 J. F. Royun, Esq., F.R.S. 1853-59 General E. SABINE, F.R.S. 1859-61 Prof. R. WALKER, F.R.S. 1861-62 W. Hopxins, Esq., F.R.S. 1862-63 W. Hopkins, Esq., F.R.S., and Prof. J. PHILLIPS, F.R.S. 1863-65 W. Hopkins, Esq., F.R.S., and F. GALTON, Esq., F.R.S. 1865-66 F. GALTON, Esq., F.R.S. 1866-68 I’, GALTON, Esq., F.R.S., and Dr. T. A. Hrrst, F.R.S. | 1908 T. T1oMSON, F.R.S. 1871-72 Dr.T. THOMSON,F.R.S.,and Capt. DouGLAsS GALTON, F.R.S. 1872-76 Capt. D. GALTON, F.R.S., and Dr. MICHAEL Fostmr, F.R.S. 1876-81 Capt. D. GALTON, F.R.S., and Dr. P. L. SCLATER, F.B.S. 1881-82 Capt. D. GALTON, F.R.S., and Prof. F. M. BALFourR, F.R.S. 1882-83 Capt. DoUGLAS GALTON, F.R.S. 1883-95 Sir DouaGLAs GALTON, F.R.S., and A. G. VERNON HARCOURT, Esq., F.R.S. 1895-97 A. G. VERNON TLARCOURT, Esq., ERS.,. tand 6 72robe ake Sea. ScHAFER, F.R.S. | 1897— { Prof. ScHArer, F.R.S., and Sir 1900 W.C.ROBERTS-AUSTEN,F.R.S. 1900-02 Sir W. C. ROBERTS-AUSTEN, F.R.S., and Dr. D. H: Scort, F.RS. 1902-03 Dr. D. H. Scorr, F.R.S., and Major P. A. MACMAHOoy, F.R.S. Major P. A, MACMAHON, F.R.S., and Prof. W. A. HirpMan, F.R.S. ASSISTANT GENERAL SECRETARIES. 1831 JOHN PHILLIPS, Esq., Secretary. 1832 Secretary. 1832-62 Prof. JOHN PuiLurps, F.R.S. 1862-78 G. GRIFFITH, Esq., M.A. 1878-80 J. K. H. Gorpon, Esq., B.A., Assistant Secretary. G, GRIFFITH, Hsq., M.A., Acting Secretary. 1881 | 1881-85 Prof. T. G. Bonney, F.R.S., Prof. J. D. Forrns, Acting | Secretary. 1885-90 A. T. ATCHISON, Esq., M.A., Secretary. 1890 G. GRIFFITH, Esq., M.A., Acting Secretary. 1890-1902 G. GRIFFITH, Esq., M.A. 1902-04 J. G. GARSON, Esq., M.D. 1904 A, SILVA WHITER, Esq., Assistant Secretary. PRESIDENTS AND SECRETARIES OF THE SECTIONS. lvii Presidents and Secretaries of the Sections of the Association. Date and Place Presidents MATHEMATICAL AND PHYSICAL SCIENCES. Secretaries COMMITTEE OF SCIENCES, I.—MATHEMATICS AND GENERAL PHYSICS. = Cambridge . Edinburgh 1835. Dublin 1836. Bristol 1837. Liverpool... 1838. Newcastle 1839. Birmingham 1840. Glasgow ... 1841. Plymouth 1842. Manchester 1843. Cork 1844. York......... 1845. Cambridge se eeeeees Davies Gilbert, D.C.L., F.R.S. Sir D. Brewster, F.R.S. ...... Rev. W. Whewell, F.R.S. Rev. H. Coddington. Prof. Forbes. Prof. Forbes, Prof. Lloyd. SECTION A.—MATHEMATICS AND PHYSICS. Rev. Dr. Robinson ......... Rey. William Whewell, F.R.S. |Sir D. Brewster, F.R.S. ...... Sir J. F. W. Herschel, Bart., F.R.S. Rev. Prof. Whewell, F.R.S.... Profs Forbes ol B.S... s.ssecsces | Rev. Prof. Lloyd, F.R.S....... F.R.S. Prof. M‘Culloch, M.R.I.A. The Earl of Rosse, F.R.S. Ely. Very Rev. G. Peacock, D.D.,| Prof. Sir W. R. Hamilton, Prof. Wheatstone. Prof, Forbes, W. S. Harris, F. W. Jerrard. W. S. Harris, Rev. Prof. Powell, Prof. Stevelly. Rey. Prof. Chevallier, Major Sabine, Prof. Stevelly. J. D. Chance, W. Snow Harris, Prof. Stevelly. ‘Rev. Dr. Forbes, Prof. Stevelly, Arch. Smith. Prof. Stevelly. Prof. M‘Culloch, Prof. Stevelly, Rev. W. Scoresby. ...|J. Nott, Prof. Stevelly. .../ Rev. Wm. Hey, Prof. Stevelly. |The Very Rev. the Dean of|Rev. H. Goodwin, Prof. Stevelly, | G. G. Stokes. 1846. Southamp- Sir John F. W. Herschel, | John Drew, Dr. Stevelly, G@. G. ton. 1847. Oxford 1848. Swansea ... 1849. Birmingham 1850. Edinburgh | 3art., F.R.S. Rey. Prof. Powell, F.R.S. Lord Wrottesley, F.R.S. ...... ; William Hopkins, F-.R.S....... M.A., Prof. J. D. Forbes, F.RB.S., Sec. R.S.E. 1851. Ipswich ...|Rev. W. Whewell, D.D., E.R.S. 1852. Belfast...... Prof. W. Thomson, M.A., F.R.S., F.R.S.E. Webs. dolly... 272... The Very Rev. the Dean of 1854, Liverpool... 1855. Glasgow ... 1856, Cheltenham 1857. Dublin seeeee 1858. Leeds Ely, F.B.S. Prof. G. G. Stokes, M.A., Sec. B.S. Rev. Prof. Kelland, M.A., F.B.S., F.R.S.E. Rev. R. Walker, M.A., F.R.S. Rev. T. R. Robinson, D.D., F.R.S., M.R.LA. W. Whewell, V.P.R.S. D.D., | ) Stokes. Rey. H. Price, Prof. Stevelly, G. G. Stokes. | Dr. Stevelly, G. G. Stokes. Prof. Stevelly, G, G. Stokes, W. Ridout Wills. W.J.Macquorn Rankine,Prof.Smyth, Prof. Stevelly, Prof. G. G. Stokes. S. Jackson, W. J. Macquorn Rankine, Prof. Stevelly, Prof. G. G. Stokes. Prof. Dixon, W, J. Macquorn Ran- kine, Prof. Stevelly, J. Tyndall. B. Blaydes Haworth, J. D. Sollitt, Prof. Stevelly, J. Welsh. J. Hartnup, H. G. Puckle, Prof. Stevelly, J. Tyndall, J. Welsh. Rev. Dr. Forbes, Prof. D. Gray, Prof. Tyndall. C. Brooke, Rev. T. A. Southwood, Prof. Stevelly, Rev. J. C. Turnbull. Prof. Curtis, Prof. Hennessy, P. A. Ninnis, W. J. Macquorn Rankine, Prof. Stevelly. Rey. S. Earnshaw, J. P. Hennessy, Prof. Stevelly, H.J.S.Smith, Prof. Tyndall. lviti Date and Place 1859. Aberdeen... 1860. Oxford...... 1861. Manchester 1862. Cambridge 1862. Newcastle 1864, Bath sen eeeees 1865. Birmingham 1866. Nottingham 1867. Dundee 1868. Norwich ... 1869, Exeter 1870. Liverpool... 1871. Edinburgh 1872. Brighton... 1873. Bradford ... 1874. Belfast...... 1875. Bristol seeees 1876. aoe Glasgow 1877. Plymouth... 1878. Dublin.. .. 1879. Sheffield ... 1880. Swansea ., 1881. , 1882. Southamp- ton. 1888. Southport 1884. 1885. Aberdeen... 1886, Birmingham Prof, "G. H. Darwin, M.A.,|R. REPORT—1904. Presidents The Earl of Rosse, M.A., K.P., F.R.S. Rev. B. Price, M.A., F.R.S.... G. B. Airy, M.A., D.C.L., E.R.S. Prof. G. G. Stokes, F.R.S. Prof. W.J. Macquorn Rankine, C.K., F.R.S, Prof. Cayley, M.A., F.R.S., F.R.A.S. W.Spottiswoode,M.A.,F.R.S., F.R.A.S. M.A., Prof, Wheatstone, F.R.S. D,0.b; .| Prof. Sir W. Thomson, D.C.L., F.R.S. Prof. J. Tyndall, FE.R.S. Prof. J. J. Sylvester, LL.D., F.RB.S. ; J. Clerk Maxwell, M.A., LL.D., F.B.S. LL.D., Prof. P. G. Tait, F.R.S.E. W. De La Rue, D.C.I.., F.R.S. Prof, H. J. S. Smith, F.R.S. . Rev. Prof. J. H. Jellett, M.A., M.R.I.A. Prof. Balfour Stewart, M.A., LL.D., F.R.S. Prof. Sir W. Thomson, M.A., D.C.L., F.R.S. Prof, G. C. Foster, B.A., F.R:S., Pres. Physical Soe. Rev. Prof. Salmon, D.C.L., F.B.S. George Johnstone Stoney, M.A,, F.B.S. D.D., .|Prof. W. Grylls Adams, M.A., E.BS. Prof. Sir W. Thomson, M.A., LL.D., D.C.L., F.R.S. Rt. Hon. Prof. Lord Rayleigh, M.A.,, F.R.S. Prof. 0. Henrici, Ph. D., F.R.S. LL.D., D.C.L., F.R.S. Prof. G. Chrystal, M.A., F.R.S.E. UL.D., F.R,S. Secretaries J. P. Hennessy, Prof. Maxwell, H, J. S. Smith, Prof. Stevelly. Rev. G. C. Bell, Rev. T. Rennison, Prof. Stevelly. Prof. R. B. Clifton, Prof. H. J. S. Smith, Prof. Stevelly. Prof. R. B. Clifton, Prof. H. J. S. Smith, Prof. Stevelly. Reyv.N.Ferrers,Prof. Fuller, F.Jenkin, Prof, Stevelly, Rev. C. T. Whitley. Prof. Fuller, F. Jenkin, Rev. G. Buckle, Prof. Stevelly. Rev. T. N. Hutchinson, F. Jenkin, G. S. Mathews, Prof. H. J. S. Smith, J. M. Wilson. Fleeming Jenkin, Prof.H.J.8. Smith, Rev. S. N. Swann. Rev. G. Buckle, Prof. G. C. Foster, Prof. Fuller, Prof. Swan. Prof. @. C. Foster, Rev. R. Harley, R. B. Hayward. Prof. G. C. Foster, R. B. Hayward, W. K. Clifford. Prof. W. G. Adams, W. K. Clifford, Prof. G. C, Foster, Rev. W. Allen Whitworth. ...|Prof. W. G. Adams, J. T. Bottomley, Prof. W. K. Clifford, Prof. J. D. Everett, Rev. R. Harley. Prof. W. K. Clifford, J. W. L.Glaisher, Prof. A. S. Herschel, G. F. Rodwell. Prof. W. K. Clifford, Prof. Forbes, J. W.L. Glaisher, Prof. A. 8. Herschel. J.W.L.Glaisher, Prof.Herschel, Ran- dal Nixon, J. Perry, G. F, Rodwell. Prof. W. F. Barrett, J.W.L. G@laisher, C. T. Hudson, G. F. Rodwell. Prof. W. F. Barrett, J. T. Bottomley. Prof. G. Forbes, J. W. L. Glaisher, T. Muir. Prof. W. F. Barrett, J. T. Bottomley, J. W. L. Glaisher, F. G. Landon. Prof. J. Casey, G. F. Fitzgerald, J. W. L. Glaisher, Dr. O. J. Lodge. A. H. Allen, J. W. L. Glaisher, Dr. O. J. Lodge, D. MacAlister. W. E. Ayrton, J. W. L. Glaisher, Dr. O. J. Lodge, D. MacAlister. Prof. W. E. Ayrton, Dr. 0. J. Lodge, D. MacAlister, Rev. W. Routh. W. M. Hicks, Dr. O, J. Lodge, D. MacAlister, Rev. G. Richardson. W. M. Hicks, Prof. O. J. Lodge, D. MacAlister, Prof. R. C. Rowe. Montreal ...| Prof. Sir W. Thomson, M.A.,|C. Carpmael, W. M. Hicks, A. John- son, O. J. Lodge, D. MacAlister. R. E. Baynes, R. T. Glazebrook, Prof, W. M. Hicks, Prof. W. Ingram. E. Baynes, R. T. Glazebrook, Prof, J. H. Poynting, W. N. Shaw. PRESIDENTS AND SECRETARIES OF THE SECTIONS. Date and Place 1887. 1888. 1889. 1890, 1891. 1892. 1893. 1894. 1895. 1896, 1897. 1898. 1899. 1900. 1901. 1902. 1903. 1904. 1832, 1833. 1834, 1835. 1836. 1837. Manchester Newcastle- Edinburgh Nottingham Oxford ...... Ipswich Liverpool... Toronto Bradford ... Glasgow ... Belfast Southport Cambridge Edinburgh Dublin Bristol seneee Liverpool... Presidents Prof. Sir R. S. Ball, M.A,, LL.D., F.R.S. Prof. G. F. Fitzgerald, M.A., FE.R.S. Capt. W. de W. Abney, C.B., R.E., F.B.S. W. L. Glaisher, F.R.S., V.P.R.A.S. Prof. O. J. Lodge, LL.D., F.R.S. Prof. ...c2... A, T. Atchison, F. G. Ogilvie, E. | Rigg, J. N. Shoolbred. |C. W. Cooke, J. Kenward, W. B. Marshall, H. Rigg. Car: Budenberg, W E. Rigg Cc. W. ooke; W. B. Marshall, E. | Rigg, P. K. Stothert. ..'C, W. Cooke, W. B. Marshall, Hon. | (C. A. Parsons, H. Rigg. \E. K. Clark, C. W. Cooke, W. B. Marshall, E. Rigg. \C. W. Cooke, Prof. A. C. Elliott, W. B. Marshall, E. Rigg. 'C, W. Cooke, W. b. Marshall, W. C. Popplewell, E. Rigg. . B. Marshall, PRESIDENTS AND SECRETARIES OF THE SECTIONS. Date and Place 1893. Nottingham 1894, Oxford...... 1895. Ipswich 1896, Liverpool... 1897, Toronto 1898. Bristol...... 1899. Dover 1900. Bradford ... 1901. Glasgow 1902. Belfast 1903. Southport 1904. Cambridge 1885. Aberdeen... 1886. Birmingham 1887. Manchester 1888. Bath 1889. Newcastle- upon-Tyne 1890. Leeds seeeee 189], Cardiff...... 1892. Edinburgh 1893. Nottingham 1894, Oxford...... 1895, Ipswich ... 1896, Liverpool... 1897. Toronto 1898. Bristol 1899, Dover 1902. Belfast Presidents lxxv Secretaries Jeremiah Head, M.Inst.C.E., ¥.C.8. |Prof. A. B. W. Kennedy, F.R.S., M.Inst.C.E. .|Prof. L. F. Vernon-Harcourt, M.A., M.Inst.C.E. Sir Douglas Fox, V.P.Inst.C.H. .|G. F. Deacon, M.Inst.C.E. ‘Sir J. Wolfe-Barry, K.C.B., E.R.S. Sir W. White, K.C.B., F.R.S. Sir Alex. R. Binnie, M.Inst. C.E .| RR. E. Crompton, M.Inst.C.E. .|Prof. J. Perry, FBS. ........- .|Prof. W. E. Dalby, W. T. Maccall, |C. Hawksley, M.Inst.C.E, ‘Hon. C, A. Parsons, F.R.S. ... C. W. Cooke, W. B. Marshall, E. Rigg, H. Talbot. Prof. T. Hudson Beare, C. W. Cooke, W. B. Marshall, Rev. F. J. Smith. Prof. T. Hudson Beare, C. W. Cooke, W. B. Marshall, P. G. M. Stoney. Prof, T. Hudson Beare, C. W. Cooke, 8. Dunkerley, W. B. Marshall. Prof. T. Hudson Beare, Prof, Callen- dar, W. A. Price. Prof, T. H. Beare, Prof. J. Munro, H. W. Pearson, W. A. Price. Prof. T. H. Beare, W. A. Price, H. E. Stilgoe. Prof. T. H. Beare, C, F. Charnock, Prof. S. Dunkerley, W. A. Price. H. Bamford, W.E. Dalby, W. A. Price. M. Barr, W. A. Price, J. Wylie. W. A. Price. J. B. Peace, W. T. Maccall, W. A. Price. SECTION H.—ANTHROPOLOGY. 1884. Montreal ...| E. B. Tylor, D.C.L., F.B.S....|G. W. Bloxam, W. Hurst. Francis Galton, M.A., F.R.S. Sir G. Campbell, K.C.S.L, M.P., D.C.L., F.R.G.S. | Prof. A. H. Sayce, M.A. ...... 'Lieut.-General _Pitt-Rivers, D.C.L., F.R.S. |Prof. Sir W. Turner, | LL.D., F.RS. \Dr. J. Evans, Treas. F.S.A., F.L.S., F.G.S. Prof. F. Max Miiller, M.A. ... M.B., LS., (Prof. A. Macalister, M.A.,| | KR. Howden, H. Ling Hoth. 'G. W. Bloxam, Rev. T. W. Davies, M.D., ¥.R.S. Dr. R. Munro, M.A., ¥.R.8.E. lsir W. H. Flower, K.CB., - ERS ‘Prof. W. M. Flinders Petrie,| D.C.L. Arthur J. Evans, F.5.A. ...... ... Sir W. Turner, F.R.S. ......... K. W. Brabrook, C.L. ... C. H. Read, ¥.5.A. | ERS. Dr. A. C. Haddon, F.R.S. |G. W. Bloxam, Dr. J. G. Garson, W | Hurst, Dr. A. Macgregor. |G. W. Bloxam, Dr. J. G. Garson, W. | Hurst, Dr. R. Saundby. G. W. Bloxam, Dr. J. G. Garson, Dr. A. M. Paterson. G. W. Bloxam, Dr. J. G. Garson, J. Harris Stone. G. W. Bloxam, Dr. J. G. Garson, Dr. R. Morison, Dr. R. Howden. G. W. Bloxam, Dr. C. M. Chadwick, Dr. J. G. Garson. G. W. Bloxam, Prof. R. Howden, H. Ling Roth, E. Seward. G.W. Bloxam, Dr. D. Hepburn, Prof. i} Prof, R. Howden, F. Bb. Jevons, J. L. Myres. H. Balfour, Dr. J.G.Garson, H. Ling Roth. J. L. Myres, Rev. J. J. Raven, H. Bon Ling Roth. \Prof. A. C. Haddon, J. L. Myres, Prof. A. M. Paterson. |A. F. Chamberlain, H. O. Forbes, Prof. A. C. Haddon, J. L. Myres. ...H. Balfour, J. L. Myres, G. Parker. 'H. Balfour, W. H. Hast, Prof. A. C. Haddon, J. L. Myres. ‘Rev. E. Armitage, H. Balfour, W. Crooke, J. L. Myres. D. J. Cunningham, W. Crooke, Prof. A. F. Dixon, J. F. Gemmill, J. L. Myres. Campbell, Prof. A. F. Dixon, J. L. Myres. Ixxvi Date and Place 1903. 1904, 1894, 1896. 1897. 1899. 1901. 1902. 1904. 1895. 1896. 1897. 1898. 1899, 1900. 1901. 1902. 1903. 1904, 1901, 1902. 1903. 1904, REPORT—1904. Presidents Southport /|Prof. J. Symington, F.R.S.... Cambridge iH, Balfour, wMvA. ocsecssssdedeses Secretaries E. N. Fallaize, H. S. Kingsford, EK. M. Littler, J. L. Myres. |W. L. H. Duckworth, E. N. Fallaize, H. 8. Kingsford, J. L. Myres. SECTION I.—PHYSIOLOGY (including ExpertmmentraL PATHOLOGY AND EXPERIMENTAL PsycHOLoGy). Oxford ....0 M.R.C.S. Liverpool ... Dr. W. H. Gaskell, F.R.S. Toronto ...| Prof. Michael Foster, F.R.S. Mover’ ....s6 D N. Langley, F.R.S. Glasgow ... Belfast ... |Prof. E.B.S. |Prof. E. A. Schiifer, F.R.S.,)Prof. F. Gotch, Dr. J. 8. Haldane, M. 8. Pembrey. Prof. R. Boyce, Prof. C.8. Sherrington. Prof. R. Boyce, Prof. C. 8, Sherring- ton, Dr. L. E. Shore. Dr. Howden, Dr. L. E. Shore, Dr. E. H. Starling. (Prof. J. G. McKendrick. ...... W. B. Brodie, W. A. Osborne, Prof. W. H. Thompson. W. OD. Halliburton,|J. Barcroft, Dr. W. A. Osborne, Dr. C. Shaw. Cambridge | Prof. C.S8. Sherrington, F.R.S.|J. Barcroft, Prof. T. G. Brodie, Dr. L. E. Shore. SECTION K.—BOTANY. | A. C. Seward, Prof. F. E. Weiss. 'Prof. res Gibson, A. C. Seward, | Prof. F. KE. Weiss. | Prof. J. B. Farmer, E. C. Jeffrey, A. C. Seward, Prof. F. E. Weiss. ..|A.C. Seward, H. Wager, J. W. White. |G. Dowker, A. C. Seward, H. Wager. |A. C. Seward, H. Wager, W. West. D. T. Gwynne- Vaughan, G. F’. Scott- Elliot, A. C. Seward, H. Wager. A. G. Tansley, Rev, C. H. Waddell, H. Wager, R. H. Yapp. H. Ball, A. G. Tansley, H. Wager, R. H. Yapp. Dr. F. F. Blackman, A. G. Tansley, H. H. Wager, T. B. Wood, R. Yapp. .'R. A. Gregory, W. M. Heller, R. Y. Howie, C. W. Kimmins, Prof. H. L. Withers. \Prof. R. A. Gregory, W. M. Heller, R. M. Jones, Dr. C. W. Kimmins, Prof. 13D Us iy sete W. M. Heller, Hi. t: | dnap e. Ww. Kimmins, Dr. Ipswich ...;W. T. Thiselton-Dyer, F.R.S.) Liverpool. | Dr. DI HaSedttal RS; secs Toronto ... Prof. Marshall Ward, F.R.S. Bristol v2... ‘Prof. ¥. O. Bower, F.R.S. . Dover: «2... Sir George King, F.R.S. ...... Bradford... Prof. S. H. Vines, F.R.S....... Glasgow ...| Prof. I. B. Balfour, F.B.S. ...| Belfast... Prof. J. R. Green, F.RS....... Southport A. C. Seward, F.B.S. ......... Cambridge Francis Darwin, E\R.S. ...... SECTION L.—EDUCATIONAL SCIENCE. Glasgow ... | Sir John E, Gorst, ¥.R.S. Belfast +++ Prof. H. E. Armstrong, F.R.S. Southport Sir W de W. Abney, K.C.B., | RERAS: Cambridge Bishop of Hereford, D.D. ‘ -+/J. H. Flather, Prof. R. A. Gregory, | W.M. Heller, Dr. C. W. Kimmins. a LIST OF EVENING DISCOURSES. Ixxvii LIST OF EVENING DISCOURSES. Date and Place Lecturer 1842. Manchester | Charles Vignoles, F.R.S...... ifs alls) Cope ean o-hayn a (od lh pee pee a |R. I. Murchison..,..........000.. S45, Cork ..:....:. | Prof. Owen, M.D., F.R.S....... | Prof. E. Forbes, F.R.S.......... DR EOULISON sronet ccs cence ces cad 1844. York...:..... Charles Lyell, F.RB.S. ......... Dr. Falconer, F.R.S............ 1845. Cambridge |G.B.Airy,F.R.S.,Astron.Royal R. I. Murchison, F.R.S. ...... 1846. Southamp- | Prof. Owen, M.D., F.R.S. ... ton. Charles Lyell, F.R.S. ......... W. R. Grove, F.RB.S...........5. 1847. Oxford...... Rev. Prof. B. Powell, F.R.S. Prof. M. Faraday, F.R.S....... Hugh E. Strickland, F.G.S.... 1848. Swansea ...|John Percy, M.D., F.R.S....... W. Carpenter, M.D., F.R.S.... 1849, Birmingham) Dr. Faraday, F.R.S. ............ Rev. Prof. Willis, M.A., F.R.S. 1850. Edinburgh |Prof. J. H. Bennett, M.D., F.R.S.E. Dr: Mantel, WOR.S;, ccccecsceas Subject of Discourse | The Principles and Construction of Atmospheric Railways. |The Thames Tunnel. The Geology of Russia. The Dinornis of New Zealand. The Distribution of Animal Life in the Aigean Sea. The Earl of Rosse’s Telescope. Geology of North America, .| The Gigantic Tortoise of the Siwalik Hills in India, Progress of Terrestrial Magnetism. Geology of Russia. Fossil Mammalia of the British Isles. Valley and Delta of the Mississippi. Properties of the ExplosiveSubstance discovered by Dr. Schénbein; also some Researches of his own on the Decomposition of Water by Heat. Shooting Stars. Magnetic and Diamagnetie Pheno- mena. The Dodo (Didus ineptus). Metallurgical Operations of Swansea and its Neighbourhood. Recent Microscopical Discoveries. Mr. Gassiot’s Battery. Transit of different Weights with varying Velocities on Railways. Passage of the Blood through the minute vesselsof Animals in con- nection with Nutrition. Extinct Birds of New Zealand. 1851. Ipswich ...| Prof. R. Owen, M.D., F.RB.S. G.B.Airy,F.R.S.,Astron. Royal 1852. Belfast...... Prof. G. G. Stokes, D.C.L., F.R.S. Colonel Portlock, R.E., F.R.S. 1853. Hull.........| Prof. J. Phillips, LL.D.,F.R.S., F.G.S. Robert Hunt, F.R.S............. 1854, Liverpool...| Prof. R. Owen, M.D., F.R.S. Col, E. Sabine, V.P.R.S. ...... 1855. Glasgow ...|Dr. W. B. Carpenter, F.R,S. Distinction between Plants and Animals, and their changes of Form. Total Solar Eclipse of July 28, 1851. Recent Discoveries in the properties of Light. Recent Discovery of Rock-salt at Carrickfergus, and geological and practical considerations connected with it. Some peculiar Phenomena in the Geology and Physical Geography of Yorkshire. The present state of Photography. Anthropomorphous Apes. Progress of Researches in Terrestrial Magnetism. Characters of Species. Lieut.-Col, H. Rawlinson . | Assyrian and Babylonian Antiquities and Ethnology. Ixxvili REPORT—1904. Date and Place Lecturer 1856. Cheltenham Col. Sir H. Rawlinson | 1857. Dublin...... 1858. Leeds ...... 1859. Aberdeen... 1860. Oxford...... 1862. Cambridge 1863. Newcastle 1864. Bath......... 1865. Birmingham D 1866. Nottingham 1867. Dundee...... 1868. Norwich 1869. Exeter ...... 1870. Liverpool... 1871. Edinburgh 1872. Brighton ... 1873. Bradford .., 1874. Belfast ...... W. R. Grove, F.R.S.. Prof. W. Thomson, F. ‘R. ae = ‘Rev. Dr. Livingstone, D.C.L. 'Prof. J. Phillips, LL. Prof. R. Owen, M.D., ‘Sir R. I. Murchison, | | Rev. Dr. Robinson, F.R.5. Rev. Prof. Walker, F.R.S D.,F.R.S. ERS. D.C.L.. Captain Sherard Osborn, R. N. 1861. Rigpegesicr | ExCr. W.A. Miller, M, A., F.R.S. . B. Airy, ¥.R.5 Sea Prof. Tyndall, LL.D., Prof, Odling, F.R.S. Prof. Williamson, F James Glaisher, F.R.S...... Prof. Roscoe, F.R.S. ......000s Dr. Livingstone, E.BS. 2 : | J. Beete Jukes, F.R. William Huggins, F. Dr. J. D. Hooker, F. Archibald Geikie, F. Alexander Herschel, .../J. Fergusson, F.R.S. Dr. W. Odling, F.R. Prof. J. Phillips, LL. J. Norman Lockyer, Prof, J. Tyndall, LL.D., F.R.S, Prof,W.J. Macquorn Rankine, LL.D., F.R.S. FP’. A. Abel, H.RiS..ce-s+ ue--s EA Astron. F.R.S. ee eenn ewes Reeser Ee eeseae F.R.A.S. S.. Dz. ERS. ERS. His Be yon, Babwsey ssa) ieseeseas Prof. P. Martin Duncan, M.B., F.R.S. Prof. W. K. Clifford Prof. W. C.Williamson, F.R.S. Prof. Clerk Maxwell, F.R.S. Sir John Lubbock,B F.R.S. Prof, Huxley, F.R.S. art.,M.P., eeeeeee se eseeres Subject of Discourse Recent Discoveries in Assyria and Babylonia, with the results of Cuneiform Research up to the present time. ...|Correlation of Physical Forces. ..|The Atlantic Telegraph. Recent Discoveries in Africa. The Ironstones of Yorkshire. The Fossil Mammalia of Australia. .. Geology of the Northern Highlands, ...|Electrical Discharges in highly rarefied Media. ..| Physical Constitution of the Sun, | Arctic Discovery. Spectrum Analysis. ‘ue late Eclipse of the Sun. The Forms and Action of Water. Organic Chemistry. The Chemistry of the Galvanic Bat- tery considered in relation to Dynamics. | ..|The Balloon Ascents made for the | British Association. ..|The Chemical Action of Light. .| Recent Travels in Africa. Probabilities as to the position and extent of the Coal-measures be- neath the red rocks of the Mid- land Counties. The results of Spectrum Analysis applied to Heavenly Bodies. Insular Floras. The Geological Origin of the present Scenery of Scotland. The present state of Knowledge re- garding Meteors and Meteorites. Archeology of the early Buddhist Monuments. .|Reverse Chemical Actions. | Vesuvius. .|The Physical Constitution of the Stars and Nebule. The Scientific Use of the Imagination. Stream-lines and Waves, in connec tion with Naval Architecture. ../ Some Recent Investigations and Ap- plications of Explosive Agents. The Relation of Primitive to Modern Civilisation. Insect Metamorphosis. The Aims and Instruments of Scien- tific Thought. Coal and Coal Plants. Molecules. Common Wild Flowers considered in relation to Insects. The Hypothesis that Animals are Automata, and its History. LIST OF EVENING DISCOURSES, lxxix Date and Place Lecturer Subject of Discourse 1875. Bristol ......| W.Spottiswoode,LL.D.,F.R.S.|The Colours of Polarised Light. F, J. Bramwell, F.R.S.......... Railway Safety Appliances, 1876. Glasgow ... Prof, Tait, F.R.S.H. ............| Horce, j Sir Wyville Thomson, ERS. |The ‘ Challenger’ Expedition. 1877. Plymouth...) W. Warington Smyth, M.A.,| Physical Phenomena connected with 1878. 1879. 1880. 1881. 1882. 1883. 1884. 1885. 1886. 1887. 1888, 1889. . Ipswich Dublin Sheffield .. Swansea ... Southamp- ton. Southport Montreal... Aberdeen... Birmingham Manchester Newcastle- upon-Tyne | seenee . Edinburgh . Nottingham .| W. Crookes, F.R.S. ....... F.R.S. Prof. Odling, F.R.S,.........64 G. J. Romanes, F.L.S.......... Prof. Dewar, F.R.S. ............ Prof. E. Ray Lankester, F. Prof.W.Boyd Dawkins, F. Francis Galton, F.B.S.......... Prof. Huxley, Sec. It.8. wm: | W. Spottiswoode, Pres. R.S.... Prof. Sir Wm. Thomson, F.R.S5. Prof. H. N. Moseley, F.R.S. Prot. Haioe ball tReet as on. | Prof. J. G. McKendrick. ...... Prof. O. J. Lodge, D.Sc. ...... Rev. W. H. Dallinger, F.R.S. Prof. W. G. Adams, F.R.S.... John Murray, F.R.S.E......... A, W. Riicker, M.A., ERS. Prof. W. Rutherford, M.D: ... Prof, H. B. Dixon, ERS. Col. Sir F. de Winton ......... Prof. W. E. Ayrton, F.R.S.... Prof. T. G. Bonney, D.Sc., F.RS. Prof. W. C. Roberts-Austen, F.R.S. | Walter Gardiner, M.A......... E. B, Poulton, M.A., F.R.S.... Prof, C. Vernon Boys, F.R.S. Prof. L. C. Miall, F.L.S.,F.G.8. Prof. A. W. Riicker, M.A., F.R.S. Prof. A. M. Marshall, F.R.S. Prof. J. A. Ewing, M.A., F.RB.S. Prof. A. Smithells, B.Sc. Prof. Victor Horsley, F.R.S. J. W, Gregory, D.Sc., F.G.S. Prof. J.Shield Nicholson, M.A. .. Prof, 8. P. Thompson, F.R.S. ‘Prof. Perey F, Frankland, F.R.S. the Mines of Cornwalland Devon, The New Element, Gallium. Animal Intelligence. Dissociation, or Modern Ideas of Chemical Action. .| Radiant Matter. .| Degeneration. .| Primeval Man. Mental Imagery. The Rise and Progress of Paleon- tology. The Electric Discharge, its Forms and its Functions. Tides. Pelagic Life. Recent Researches on the Distance of the Sun. Galvanic and Animal Electricity. Dust. The Modern Microscope in Re- searches on the Least and Lowest Forms of Life. The Electric Light and Atmospheric Absorption. .|The Great Ocean Basins. Soap Bubbles. The Sense of Hearing. .|The Rate of Explosions in Gases. Explorations in Central Africa. The Electrical Transmission of Power. The Foundation Stones of the Earth’s Crust. The Hardening and Tempering of Steel. How Plants maintain themselves in the Struggle for Existence. Mimicry. Quartz Fibres and their Applica- tions. Some Difficulties in the Life of Aquatic Insects. Electrical Stress. Pedigrees. Magnetic Induction. Flame. The Discovery of the Physiology of the Nervous System. Experiences and _ Prospects African Exploration. Historical Progress and Ideal So- cialism. Magnetism in Rotation. The Work of Pasteur and its various Developments. of Ixxx Date and Place REPORT—1904.. Lecturer Subject of Discourse 1896. Liverpool...) Dr. F. Elgar, F.R.S............. 1897. 1898. 1899. 1900. 1901. 1902. 1903. 1904. Toronto see seeeee Bradford ... Glasgow ... Belfast Southport Cambridge |Prof. Flinders Petrie, D.C.L. Prof. W. C. Roberts-Austen, | B.R.S. aie Milne: Stu stacsvens cos eee Prof. J. Fleming, F.R.S. ...... |Prof F. Gotch, F.R.S.... .... (Prof. Wy Sif0uds Sc: iiskcecce ese Prof. W. Ramsay, F.R.S....... Be Datwiny Wei. scsteskesecce ..| Prof. J. J. Thomson, F.RB.S.... Prof. W. F. R. Weidon, F.R.S. Dr. R. Munro Dr, ANROWG c2c.8.ncrtesaetoee Prof. G. H. Darwin, F.R.S.... Prof. H. F. Osborn Safety in Ships. Man before Writing. Canada’s Metals. Earthquakes and Volcanoes. .| Funafuti: the Study of aCoral Island. Phosphorescence. La vibration nerveuse. TheCentenary ofthe ElectricCurrent. .| Animal Electricity. | Range Finders. The Inert Constituents Atmosphere. The Movements of Plants. Becquerel Rays and Radio-activity. Inheritance. Man as Artist and Sportsman in the Paleolithic Period. The Old Chalk Sea, and some of its Teachings. of the |Ripple- Marks and Sand-Dunes, |Palxontological Discoveries in the Rocky Mountains. LECTURES TO THE OPERATIVE CLASSES. Date and Place 1867. 1868. 1869. 1870. 1872. 1873. 1874, 1875. 1876. 1877. 1879. 1880. 1881, 1882. 1883. 1884. 1887, Manchester| Prof. G. Forbes, F.R.S. 1888. Dundee...... Norwich ... Exeter seeeee Liverpool... Brighton Bradford ... Belfast Bristolizeescs Glasgow ... Plymouth... Sheffield ... Swansea ... York Southamp- ton. Southpor Montreal ... Bath Subject of Discourse Lecturer Prof. J. Tyndall, LL.D., F.R.S. Prof. Huxley, LL.D., F.R.S. Prof. Miller, M.D., F.R.S. SirJohn Lubbock, Bart.,F.R.S. ...| W.Spottiswoode,LL.D.,F.R.S. C. W. Siemens, D.C.L., F.R.S. Prot. Odling, Wuliisircacseeiecs: Dr. W. B. Carpenter, F.R.S. Commander Cameron, W. H. Preece Wi HgA VEtON ge ceeacecceecacae oss H. Seebohm, F.Z.S. ............ Prof. Osborne Reynolds, E.R.S. John Evans, D.C.L.,Treas. B.S. oer Seer ee eee eee ey SirJohn Lubbock, Bart.,F.R.S. Matter and Force. A Piece of Chalk. .|The modes of detecting the Com- position of the Sun and other Heavenly Bodies by the Spectrum, Savages. Sunshine, Sea, and Sky. Fuel. The Discovery of Oxygen. A Piece of Limestone. .| A Journey through Africa. Telegraphy and the Telephone. Electricity as a Motive Power. The North-East Passage. Raindrops, Hailstones, and Snow- flakes. Unwritten History, and how to read it. Alloys. Electric Lighting. The Customs of Savage Races. 1889. Newcastle- |B. Baker, M.Inst.C.B. .........| The Forth Bridge. upon-Tyne LECTURES TO THE OPERATIVE CLASSES. ixxxi Date and Place Lecturer . Subject of Discourse 1890. Leeds ...... Prof. J. Perry, D.Sc., F.R.S. | Spinning Tops. 1891. Cardiff...... ‘Prof. 8. P. Thompson, F.R.S. | Electricity in Mining. 1892. Edinburgh | Prof. C. Vernon Boys, F.R.S.| Electric Spark Photographs. 1893. Nottingham Prof. Vivian B. Lewes......... |\Spontaneous Combustion, 1894. Oxford...... |Prof. W. J. Sollas, F.R.S. ...|Geologies and Deluges. 1895. Ipswich ...)Dr. A. H. Fison..........0008 os |Colour, 1896. Liverpool...| Prof. J. A. Fleming, F.R.8..../The Earth a Great Magnet. 1897. Toronto .-| Dr. H. O. Forbes ......s000-.4+5 ,..|New Guinea. 1898. Bristol......| Prof. E. B. Poulton, F. RS. The ways in which Animals Warn their enemies and Signal to their | friends. 1900. Bradford ...| Prof. 8. P. Thompson, ¥.R.S. Electricity in the Industries, 1901. Glasgow ...|H. J. Mackinder, M.A.......... |The Movements of Men by Land | and Sea. 1902. Belfast ... Prof. L. C. Miall, F.R.S. ......!Gnats and Mosquitoes. 1903, Southport |Dr.J. 8. Flett wc... eee! Martinique and St. Vincent: the Eruptions of 1902. 1904, Cambridge |Dr. J. E. Marr, F.R.S. .........;The Forms of Mountains. 1904. \xxxil ~ REPORT—1904. - OFFICERS OF SECTIONAL COMMITTEES PRESENT AT THE CAMBRIDGE MEETING. SECTION A,—MATHEMATICAL AND PHYSICAL SCIENCE, President.—Prof. Horace Lamb, M.A., LL.D., F.R.S. Vice-Presidents.—C. Vernon Boys, F.R.S.; Sir John Eliot, K.C.1.E., F.R.S, ; Prof. A. R. Forsyth, F.R.S. ; Prof. J. J. Thomson, ¥.R.S. Secretaries.—C. H. Lees, D.Sc. (Recorder) ; A. R. Hinks, M.A.; R. W. H. T. Hudson, M.A.; W. J. S. Lockyer, Ph.D.; A. W. Porter, B.Sc. ; W. C. D. Whetham, M.A., F.R.S. SECTION B,—CHEMISTRY. President.—Prof. Sydney Young, D.Sc., F.R.S. Vice-Presidents.—Prof. Sir James Dewar, F.R.S.; Dr. J. J. Dobbie, F.R.S. ; Prof. W. N. Hartley, F.R.S. Secretaries.—Prof. W. J. Pope, F.R.S. (Zecorder) ; M. O. Forster, Ph.D. ; Prof. G.G. Henderson, D.Sc. ; H. O. Jones, M.A. SECTION C.— GEOLOGY. Lresident.—Aubrey Strahan, M.A., F.R.S, Vice-Presidents.—Dr. J. E. Marr, F.R.S.; J. J. H. Teall, F.R.S. ; Prof. W. W. Watts, F.R.S. Secretaries.—Herbert L. Bowman, M.A. (Recorder) ; Rev. W. L. Carter, M.A.; J. Lomas ; H. Woods, M.A. SECTION D,—ZOOLOGY, President.—William Bateson, M.A., F.R.S. Vice-Presidents.—Prof. 8. J. Hickson, F.R.S.; W. E. Hoyle, D.be. ; Adam Sedgwick, F.R.S. Secretaries.—J. Y. Simpson, D.Sc. (Recorder) ; J. H. Ashworth, D.Sc. ; L, Doncaster, M.A. ; H. W. M. Tims, B.A., M.D. SECTION E,—GEOGRAPHY. President.— Douglas W. Freshfield, F.R.G.S. Vice-Presidents.—Capt. E. W. Creak, C.B., R.N., F.R.S. ; F. H. H. Guillemard, M.D. ; Colonel Sir C. Scott Moncrieff, R.E., K.C.M.G., C.S.L. Secretaries.—Edward Heawood, M.A. (Recorder); A. J. Herbertson, Ph.D. ; H. Yule Oldham, M.A. ; E. A. Reeves. SECTION F.—ECONOMIC SCIENCE AND STATISTICS, President.—Prof. William Smart, LL.D. Vice-Presidents.—E. W. Brabrook, C.B.; Prof. H.S. Foxwell, M.A. ; Prof. A. Marshall, LL.D. Secretartes.— A. L. Bowley, M.A. (Recorder) ; J. E. Bidwell, M.A. ; Prof, >. J.Chapman, M.A.; B, W. Ginsburg, M.A., LL.D, a OFFICERS OF COMMITTEES. lxxxiii SECTION G.—ENGINEERING. President.—Hon. Charles A. Parsons, M.A., F.R.S., M.Inst.C.E. Vice-Presidents.—Ool. R. E. Crompton, C.B., M.Inst.C.E. ; C. Hawksley, M.Inst.C.E. ; Prof. B. Hopkinson, M.A. Secretarves.—W. A. Price, M.A. (Recorder) ; W.T.Maccall, M.Sc. ; J. B. Peace, M.A. SECTION H.—ANTHROPOLOGY. President.—Henry Balfour, M.A. Vice-Presidents.—Prof. A. Macalister, F.R.S. ; Prof. W. Ridgeway, M.A.; Prof. J. Symington, F.R.S. Secretaries.—J. L. Myres, M.A. (Recorder) ; W. L. H. Duckworth, M.A. ; E. N. Fallaize, M.A. ; H. 8. Kingsford, B.A. SECTION I,— PHYSIOLOGY. President.—Prof. C. 8. Sherrington, D.Sc., M.D., F.R.S. Vice-Presidents.—Prof. F. Gotch, F.R.S.; Prof. W. D. Halliburton, F.RS. ; Prof. J. N. Langley, F.R.S. Secretaries.—J. Barcroft, M.A., B.Sc. (Recorder); Prof. T. G. Brodie, M.D., F.R.S.; Dr. L. E. Shore. SECTION K,—BOTANY, President.—Francis Darwin, M.A., M.B., F.R.S. Vice-Presidents.—Prof. J. B. Farmer, F.R.S.; W. Gardiner, F.B.S. ; W. Somerville, D.S:.; Prof. H. Marshall Ward, F.B.S. Secretaries. —Harold Wager, F.R.S. (Recorder) ; Dr. F. F. Blackman, M.A.; A.G. Tansley, M.A. ; T. B. Wood, M.A. ; R.H. Yapp, M.A. SECTION L.—EDUCATIONAL SCIENCE. President.—The Right Rev. the Lord Bishop of Hereford, D.D., LL.D. Vice-Presidents.—Prof. H. E. Armstrong, F.R.S.; Oscar Browning, M.A. ; Rev. H. B. Gray, D.D. ; J. N. Keynes, D.Sc. Secrelaries.—W. M. Heller, B.Sc. (Recorder); J. H. Flather, M.A. ; Prof. R. A. Gregory ; C. W. Kimmins, M.A., D.Sc, COMMITTEE OF RECOMMENDATIONS. The President and Vice-Presidents of the Meeting ; the Presidents of former years ; the Trustees ; the General Treasurer ; the General and Assistant General Secretaries ; Prof. Horace Lamb ; Sir John Eliot ; Prof. J. J. Thomson ; Prof. Sydney Young ; Prof. W. J. Pope; Aubrey Straham ; G. W. Lamplugh ; Dr. J. E. Marr ; W. Bateson : Prof. 8. J. Hickson ; Dr. W. E. Hoyle ; Douglas W. Freshtield ; Dr. J. 8. Keltie ; E. Heawood ; Prof. Wm. Smart ; E. W. Brabrook ; Dr. E. Cannan ; Hon. Charles A. Parsons ; Col. Crompton ; W. A. Price ; Henry Balfour ; E. 8. Hartland; J. L. Myres; Prof. C. S. Sherrington ; Prof. Schafer ; J. Bareroft ; Francis Darwin ; Prof. H. Marshall Ward; H. Wager; The Bishop of Hereford; Prof, H. E. Armstrong ; W. M. Heller ; and Principal E. H. Griffiths. bs ez lxxxiv REPORT—1904. Dr. THE GENERAL TREASURER’S ACCOUNT, 1903-1904. RECEIPTS. £ SiGe Balance brought forward .....ssssssssseeeseeeneesaneeenersorseneesces Caue lt 4 Life Compositions (including Transfers) .seiseseqaseenonveanerme 423 0 0 New Annual Members’ Subscriptions ...... Bonde oectaeademeeisccc2 222 0 O Annual Subscriptions... ... EF Sec cdecuacdcutungeceteee onsen tee tent 559 0 0 Sale of Associates’ Tickets ......cssscssee seccetcerrecesecetseensssenrs 667 O O Sale of Ladies’ Tickets ......sccccscsssscscccseresseecesssessvcnvesense 365 0 O Sale of Publications ......scccccssscessccrsecesserencsentesesecesneres 127- 4 0 Dividend On Gonsols .......ccccssvescccesnccovetoedadeuesas s¥esulvne sede 155; 2 0 Dividend on India 8 per Cents. ....cseceeseseeeeeeeerereeneeetenees 103— 1-50 Interest On DepOSit...scccccserecseenseeneeneeeeree eters eneseeeneneenens 33 3 4 Income Tax Tepurned!..c tececcsneevccnsns vaste dates taslececstenes teaver 4717 4 Yo al tee ae yh bg ie es ; ee * £3351. 9. 3 Investments. £ 3. & COnNOISig gs. cueesSeceincenk conten ticicses scones deoe ine 6501 10 5 India 3 per Cents. SALA SECS CADEGIDEROCE SIONUIDO 3600 0 0 £10,101 10 5 Sir Frederick Bramwell’s Gift, 2$ per Cent. Self-cumulating Consolidated Stock ...... 58 8 5 £10,159 18 10 G. CAREY FOSTER, General Treasurer. GENERAL TREASURER’S ACCOUNT. Ixxxv from July 1, 1903, to June 30, 1904. Cr, 1903-1904. EXPENDITURE, Syl tan ed Expenses of Southport Meeting (including Printing, Adver- tising, Payment of Clerks, &¢., &¢.) ........... PS Eh eedsexs 157 10 9 Rent and Office Expenses ...........sce0eeeee etre arcs stkvaveee i BALOON meen (2 Salariess &C. even eeadeesed dsanc< tatatedes Gli ac a see ae dsiawenaees ASsidesess 527 4 6 Brinn, pHINGIn S100-4 as owbwaapake isttarsiecscase seas aisleleppaincsoes » *262 10 7 Repair, &c., of Banners ............... “aC agpORES EEE CON ar kee sononcent 713 0 Committee on Coast Changes ..........sccsceceesseeeceveusens areas Le LAGS 'G Payment of Grants made at Southport : is. id. Seismological Observations........20.cccccccssencecves 40 0 0 Investigation of the Upper Atmosphere by means ‘of Kites 50 0 0 Magnetic Observations at Falmouth .........e esse eee 60 0 0 Wave-length Tables of Spectra...........cceeecevees von 0" 0° 0 Study of Hydro-aromatic Substances ............ aaiste oe 25 0 0 Erratie Blocks...... Diveruiet cies aitahea’a duiciats ead. sniniataniaintea 10 0 0 Life-zones in British Carboniferous Rocks ............ 35 0 0 Fauna and Flora of the Trias .......... Seton 0). 0) Investigation of Fossiliferous Drifts.... ohoaee 50 0 0 Table at the Zoological Station, Naples ...........-.... 100 0 0 Index Generum et Specierum Animalium .............. 60 0 0 Development in the Frog ............65 teres ataiata sadeee LOD (0) 0 Researches on the Higher Crustacea ...........00e000 15 0 0 British and Foreign Statistics of International Trade Seon Ole Resistance of Road Vehicles to Traction ............65 909 0 0 Researches im) Oreter:cie's sisatsclaciacioate c ce, vivieie's so efakiteev ere 100 0 0 Researches in Glastonbury Lake Village elohe'al o uistetetaintae! © 25 0 0 Anthropometric Investigation on Egyptian tee suse | Sako:,.0 Excavations on Roman Sites in Britain ........ niatpeteledta 25 0 0 The State of Solution of Proteids eo P20... 0 Metabolism of Individual Tissues. awe 40" 0: 0 Botanical Photographs ......... 4 811 Respir AMON! OF PLAN tai tials wycolclee > oveels cieialanreaass wale otete 15 0 0 ixperimental Studies in Heredity ki pic tahevilaiisis See ne 35 0 0 Corresponding Societies Committee.......... eteemee SP2Oe oO 887 18 11 1941 8 5 On deposit at Bradford District Bank......... £1027 13 4 Balance at Bank of England (Western Branch) .....,......... £627 11 8 Less Cheques not presented ...... 247 18 11 Qashi in han disses eoccarvassk < eed Meets oe a ell 1410 010 £3351 9 3 * Exclusive of an outstanding Printing Bill of about £1,000, Ihave examined the above Account with the books and vouchers of the Associa tion, and certify the same to be correct. I have also verified the balance at the Bankers’, and have ascertained that the Investments are registered in the names of the Trustees, W. B. KEEN, Chartered Accountant, Approved— 3 Church Court, Old Jewry, E.C, EH. W. BRABROOK, 5 July 28, 1904. L. L. Price, } Auditors, Y Ixxxvl REPORT— 1904, Table showing the Attendance and Receipts Dateotseting | Where het President ia te | er Te 1831, Sept. 27...... Di ae ere e ....| The Earl Fitzwilliam, D.O.L.. F.R.S =< — 1832, June 19...... Oxford. ...;; ..| The Rey. W. Buckland, F.R.S. ......... —_ = 1833, June 25...,.,) Cambridge ..| The Rev. A. Sedgwick, F.R.S. eel = a 1834, Sept. 8 . Edinburgh ... Sir T. M. Brisbane, D.O.L., E.R ee ne acs 1835, Aug. 10.,....) Dublin ..... . The Rey. Provost Lloyd,LL.D., F, Se ‘s. — —_ 1836, Aug. 22. Bristol .. ., The Marquis of Lansdow ne, F.R.S.. —_ — 1837, Sept. 11, Liverpool ....... ..| The Earl of Burlington, F.R.S. i = 1838, Aug. 10...... Newcastle-on-Tyne...| The Duke of Northumberland, FRSA — — 1839, Ang. 26...... | Birmingham .| The Rey. W. Vernon Harcourt, F.R. — — 1840, Sept. 17...... Glasgow........ . The Marquis of Breadalbane, ERS. _ — 1841, July 20 ...... Plymouth .. .| The Rey. W. Whewell, F.R.S. ......... 169 65 1842, June 23, ..,) Manchester ..| The Lor d Francis Egerton, Ae Gas: e.. 303 169 1843, Aug. 17...... WGork 20. ..| The Earl of Rosse, F.R.S. ...... 109 28 1844, Sept. 26 Monk, S53 "| The Rev. G. Peacock, D.D., F.RS._ 226 150 1845, June 19.,,...) Cambridge ..... . Sir John BP. W. Herschel, Bart., PRS. 313 36 1846, Sept. 10 ...| Southampton Sir Roderick L.Murchison,Bart.. FBS. 241 10 1847, June 23 ..,... Oxford ..... . Sir Robert H. Inglis, Bart., F.R.S. ... 314 H 18 1848, Aug. 9 ...... Swansea........ .. TheMarquis of Northampton, Pres.R.8., 149 | 3 1849, Sept. 12...... birmingham . The Rev. T. R. Robinson, D.D. F.R.8.) 227 | 12 1850, July 21 ..,...| Edinburgh Sir David Brewster, K.H., F.R.S....... 235 9 1851, July 2 Ipswich ,.... .. G. B, Airy, Astronomer Royal, F.R.S. 172 8 1852, Sept.1 . Belfast .. . Lieut.-General Sabine, F.R.S. ......... 164 10 1853, Sept.3 ...... 127) Sa ... William Hopkins, F.R.S........ 141 13 1854, Sept. 20 ......| Liverpool ... The Earl of Harrowby, F.R.S. 238 23 1855, Sept. 12..,...| Glasgow..... .. The Duke of Argyll, F.R.S. .... 194 33 1856, Aug.6 ...... Cheltenham ..| Prof. C. G. B. Daubeny, M.D., F.R.S.... 182 14 1857, Aug. 26 ...... Dublin ..... "| ‘The Rev. H. Lloyd, D.D., ERS. ...... 236 15 1858, Sept. 22 ...... Leeds.., .... . Richard Owen, M.D., D. 6. L., F.B.S.. 222 | 42 1859, Sept. 14...... Aberdeen .. ... H.R.H. The Prince Consort cae 184 27 1860, June 27 ...... Oxford)... ... The Lord Wrottesley, M.A., F.R.S. ... 286 21 1861, Sept. 4 ...... Manchester ., .. William Fairbairn, LL.D., I’.R.8....... 321 113 1862,Oct. 1 .é.... ; Cambridge ........... The Rey. Professor Willis, M.A. JE.R.S.| 239 15 1863, Aug. Neweastle-on-Tyne.,., SirWilliam G. Armstrong.0.B., PDRS.| 203 36 1864, Sept. 17] .. Sir Charles Lyell, Bart., M. A, ERS. 287 40 1865, Sept. Birmingham,, ..| Prof. J. Phillips, M.A., LL.D., F-RS. 292 44 1866, Aug. 22...... | Nottingham.,, ... William R. Grove, Q. C., F.RB.S.. 207 31 1867, Sept. 4 ......) Dundee ..,...... .| The Duke of Buccleuch, K.C.B PF, RS. 167 25 1868, Aug.19...... Norwich .., Dr. Joseph D. Hooker, F.R.S. ......... 196 18 1869, Aug. 18 .,,... Exeter ..| Prof. G. G, Stokes, D.O.L., BRB sce 204 21 1870, Sept. .| Liverpool .. .| Prof. T. H, Huxley, LL.D., F.R.8. 314 39 1871, Aug. Edinburgh Prof. Sir W. Thomson, ie; D., F.R. $1 246 28 1872, Aug. Brighton .. ., Dr. W. B. Carpenter, ERS. 245 36 1873, Sept. Bradford ., as| Prot. As W. Williamson, F. 212 27 1874, Aug. Belfast ..... .| Prof. J. Tyndall, LL.D., F.R.s 162 13 1875, Aug. 25 ...... | Bristol ..... Sir John Hawkshaw, FERS 239 | 36 1876, Sepi.6 ...... Glasgow Prof. T. Andrews, MD ee aE Rs 221 35 1877, Aug. 15..,...) Plymouth... oh enor, As Thomson, M.D., F.R,. 173 | 19 1878, Aug. | Dublin .. .| W. Spottiswoode, M.A., ERS 201 18 1879, Aug. Sheffield... .| Prof. G. J. Allman, ar hans 184 16 1880, Aug. Swansea. . ...| A. O. Ramsay, LL.D., os hs 144 ll 1881, Aug. RPLOne ee .| Sir John Lubbock, ae a 272 28 1882, Aug. | Southampton . pan OC. We Siemens F.R.S. 178 17 1883, Sept.19......) Southport .... ‘| Prof. A. Cayley, D.C.L., FR. . 203 60 1884, Aug. 27 Montreal .. ...| Prof. Lord Rayleigh, F. R. - 235 20 1885, Sept.9 ....., Aberdeen .. .| Sir Lyon Playfair, K. ” B., F 225 18 1886, Sept. 1 ....., Birmingham Sir J. W. Dawson, C.M.G., F. 314 25 1887, Aug. 31....., | Manchester — .| Sir H. E. Roscoe, D. O.L., F. 428 86 BRS SOD ID 5... SabH. ecas-yspsemeecmeaee Sir F, J. Bramwell, F.R.S. : 266 36 1889, Sept. 11......| ‘| Prof. W. H. Flower, O.B., F.R.S 277 20 1890, Sept. 3 ...... .| Sir F. A. Abel, O.B., F.R.S. 259 21 1891, Aug. 19 ....,, Dr. W. Huggins, F-R.S. ; 189 24 1892, Aug.3 ...... || Sir A. Geikie, LL.D., F.B.S. ee 280 14 1893, Sept. 13....., “| Prof. J. 8. Burdon Sanderson, F.R.S, 201 17 1894, Aug. 8 .....,) Oxford’ ....... ..| The Marquis of Salisbury,K.G.,F.R.S. 327 21 1895, Sept. 11....,, ..| Sir Douglas Galton, K.C.B., F.R.S. 214 13 1896, Sept. 16...... "| Sir Joseph Lister, Bart., Pres. R.S 330 31 1897, Aug. 18....., ..| Sir John Evans, K.C. B., ER. Bae 120 8 1898, Sept.7 ...... ec] SLE Wis OFOOKES Hi bese oe 6 araace see ae 281 | 19 1899, Sept. 13......| Dover..... | Sir Michael Foster, K.C.B.,Sec.R.S..... 296 | 20 1900, Sept. 5 ....., Bradford Sir William Turner, D.O.L. » ERS. ..: 267 13 1901, Sept. 11..,... Glasgow.. ..| Prof. A. W. Riicker, D.Sc., Sec.R.S. 310 37 1902, Sept. 10....., Belfast ..... .| Prof. J. Dewar, LL. 20% TRG: eee 243 21 1903, Sept. 9 ..,.., Southport ., “| Sir Norman Lockyer, K.O.B., PRS. 250 21 1904, Aug. 17......) Cambridge .| Rt. Hon. A. J. Balfour, M.P., F.R.S 419 32 * Ladies were not admitted by purchased tickets until 1843. ( + Tickets of Admission to Sections only. ATTENDANCE AND RECEIPTS AT ANNUAL MEETINGS, at Annual Meetings of the Association. } | \ ) | | j : i | ola |! New | | Amount Grants Annual | Annual ae | Ladies Foreigners Total Pacey ata tor Scientific, Members Members i | | “Me sah nf Purposes st = a — 353 = FF wil) nee — — 22 900 = — | = = = | eles = 1298 = £20 0 0 —_ — —_— / — — _— _— 167 0 0 — = — - — 1350 = 435 0 0 ait taity t= = — = 1840 = 92212 6 = 1s ieee Es 1100* _ 2400 = 932 2. 2 6 | oe z = 34 1438 By 1595 11 0 | = ae — — 40 1353 zt 1546 16 4 46 317 = 60* = 891 a 1235 10 11 | 75 376 33+ 331% 28 1315 = 1449 17 8 | (185 = 160 = = = 1565 10 2 | 45 190 oF 260 = a = 98112 8 | 94 | 22 407 172 35 1079 a 831 9 9 | 65 Ci 39 270 196 36 857 = 685 16 0 197 40 495 203 53 1320 = 208 5 4 | 54 25 376 197 15 819 £707 0 0| 275 1 8 B2, i 33 447 237 22 1071 963 0 0) 15919 6 | 198 42 510 273 44 1241 108 0 0) 34518 0 61 | 47 244 141 37 710 620 0 0 391 9 7 63 60 510 292 9 1108 1085 0 0, 304 6 7 56 57 367 236 6 876 903 0 0 205 0 0 Ee fees EN 765 524 10 1802 —«1gg2 0 0 «638019 7 142 101 1094 543 26 2133 «29311 0 0 48016 4 104 48 412 346 9 1115= 1098 0 0 73413 9 156 120 900 569 26 2022 «2015 «0 0 50715 4 1 91 710 509 13 1698 1931 0 0 61818 2 125 179 1206 821 22 2564 2782 0 0 68411 1 wae | 59 636 463 47 1689 1604 0 0 76619 6 ioe fi) 125 1589 791 15 3138 | 3944 0 0 1111 510] 150 | 57 433 242 25 1161 1089 0 0 129316 6 | 154 | = 209 1704 1004 25 333 3640 0 0 1608 310 182 | 103 1119 1058 13 2802 2965 0 O 128915 8 | 215 | 149 766 508 23 1997 | 2297 0 0 1591 7 10 | 218 105 960 | 771 ll 2303 2469 0 0 175013 4 193 118 1163 771 7 2444 «96138 0 «0 «+1739 4 0 go =| 117 720 682 45t 2004 «= 2042:«)SsOs«d1940 0 0 299 | 107 678 600 17 1856 1931 0 0 1622 0 0| 303 195 1103 910 14 2878 ©3096 0 0 1572 0 O 311 197 976 754 21 2463 2575 0 0 1472.2 6 280 80 937 912 43 2533 «9649 0 0 1285 0. 0, 237 99 796 601 11 1983 =-2120 0 0 «1685 (0 0 232 85 817 630 12 1951 1979 0 0 115116 0 307 93 884 672 17 2248 «©9397 0 0. 960 0 0 331 185 165 | 712 25 2774 3023 0 0 1092 4 2| 238 59 446 283 11 1229 1268 0 0 1128 9 7 | 290 93. | 1985 674 17 2578 2615 0 0 72516 6} 239 74 529 349 13 1404-1425 0 «(0 «(1080 11 11 | tri. | 41 389 147 12 915 399 0 0 731 7 7 | 313 176 1230 | 514 24 2557 2689 0 0 476 8 1) 2538 79 516 189 21 1253 1986 0 0 1126 111 | 330 323 952 841 5 2714 ++ - 3369: «0 0 1083 3 3 | 317 219 826 74 26&60H.$ 1777 1855 0 0/1173 4 0 332 122 1053 447 6 2203 «2256 «0 0 1385 0 0° 428 179 1067 429 11 2453 ©2532 0 0 995 0 6 | 510 244 1985 493 92 3838 4336 «0 0 1186 18 0 | 399 100 | 639 509 12 1984 2107 0 0 1511 0 5 | 412 113° | 1024 579 21 2437 |2441 0 0| 1417 011] 368 92 680 334 12 1775 | (1776 «0 0} 78916 8 | 341 152 672 107 35 1497 «1664 0 0 102910 0| 413 | 141 733 439 50 2070 «= 2007:«0 «0s 864.10 0 | 328 57 773 268 17 1661 | «1653 0 0 90715 6) 435 | 69 941 451 77 2321 | 2175 0 0/| 58315 6 290 3 493 261 22 1324 «1986 0 0| 97715 5 | 383189 1384 873 41 3181 | 3228 Q 0/1194 6 1} 286 {125 | 682 100 41 1362 1398 0 0 105910 8 327 96 1051 639 33 2446 «©9399 0 0 1212 0 0) 324 | 68 548 120 27 1403 1328 0 0 143014 2 | 297 45 801 482 9 | 1915 | 1801 0 0, 107210 0} 374 131 794 246 20 | 1912 | 204 0 0| 945 0 0} 314 86 647 305 6 | 1620 | 1644 0 0; 947 0. 0| 319 90 688 365 21 | 1754 | 1762 0 0) 845 13 2] 449 113 1338 | 317 121 | «2789 | 2650 0 0 | 887 18.11 | Ixxxvii Year 1831 1832 1833 1834 1835 1836 1837 1838 1839 1840 1841 1842 1845 1844 1845 1846 1847 1848 1843 1850 1851 1852 1853 1854 1855 1856 1857 1858 1859 1860 1861 1862 1863 1864 1865 1866 1867 1868 1869 1870 1871 1872 1873 1874 1875 1876 1877 1878 1879 1880 1881 1882 1883 1884 1885 1886 1887 1888 1889 1890 1891 1892 1893 1894 1895 1896 1897 1892 1899 1900 1901 1962 1903 1904 } Including Ladies. § Fellows of the American Association were admitted as Hon, Members for this Meeting OFFICERS AND COUNCIL, 1904-1905. PRESIDENT. Tur Ricur Hon. A. J. BALFOUR, D.O.L., LL.D., M.P., F.B.S., Chancellor of the University of Edinburgh, VICE-PRESIDENTS. His Grace the DUKE oF DEVONSHIRE, K.G., LL.D., F.R.S., Ohancellor of the University of Cam- bridge. ALEXANDER PECKOVER, LL.D., Lord Lieutenant of Cambridgeshire, ARTHUR HAtLt, “M.A. D.L., High Sheriff of Cam- bridgeshire and Huntingdonshire. The Right Rev. the Lorp BisHor or Ey, D.D. The Right Hon, Lonrp WALSINGHAM, LL.D., F.R.S., High Steward of the University of Cambridge, The acne Hon. Lorp Rayi4icH, D.C.L., LL.D., The unit Hon, Lorp KELvin, G.C.V.O., D.C.L., LL.D., F.R.S | The Rev. F, H. CHASE, D.D., Vice-Chancellor of the University and President of Queens’ College, | Cambridge. | The Very Rev. H. Monracu Butrer, D.D., Matter | of Trinity. Mrs, Sip@wick, Principal of Newnham Oollege, | Cambridge. | J. H, OHESSHYRE DALTON, M.D., Mayor of Cam- | bridge. ROBERT STEPHENSON, Ohairman of the Oambridge- shire County Council. | JosEPH Martin, Chairman of the Isle of Ely | County Council. | P. H. Youne, Deputy Mayor of Cambridge. PRESIDENT ELECT, Professor G. H, DARWIN, M.A., LL.D., Ph.D., F.R.S, VICE-PRESIDENTS ELECT, His Excellency the Right Hon. Lorn MILNER, G.C.B., G.O.M.G., High Oommissioner for South Africa. The Hon. Sir Waurer F. Hety-HvUTCHINSON, G.C.M.G., Governor of Cape Colony. Colonel Sir Henry E, McCa.uum, K.C.M.G.,, R.E., Governor of Natal. Captain the Hon. Sir ARTHUR LAWLEY, K.C.M.G., Lientenant-Governor, Transvaal. Major Sir H. J. Gootp-Apams, K.C.M.G., Lieu- tenant-Governor, Orange River Colony. Sir W. H. Miron, K.C.M.G., Administrator of Southern Rhodesia. Sir CHaries H, T, Mercatre, Bart., M.A. Sir DAvip GILL, K.O.B., LL.D., F.R.S. THEODORE REUNERT, M.Inst.C.E. The Mayor oF Carr Town. The MAYoR OF JOHANNESBURG, The PRESIDENT OF THE PHILOSOPHICAL SOCIETY OF SouTH AFRICA. GENERAL TREASURER. Professor JoHN PERRY, D.Sc., F.R.S., Burlington House, London, W. GENERAL SECRETARIES. Major P, A. MacMAnHOoN, R.A., D.Se., F.R.S. | Professor W. A. HERDMAN, D.Sce., F.R.S. ASSISTANT SECRETARY. A. SILvA WHITE, Burlington House, London, W. CENTRAL ORGANISING COMMITTEE FOR SOUTH AFRICA, Sir Davin Gi, K.O.B., F.R.S,, Ohairman. J. D. F. Gincunrist, M.A., Ph.D., B.Se., Secretary. ORDINARY MEMBERS OF THE COUNCIL, ABNEY, Sir W., K.C.B., F.R.S. ARMSTRONG, Professor H. E., F.R.S. Bonank, J., LL.D. Bournkg, G. O., D.Sc. Bower, Professor F. O., F.R.S. BRABROOK, E. W., C.B. Brown, Dr. HorAcr T., F.R.S. CALLENDAR, Professor H. L., F.R.S, CUNNINGHAM, Professor D. J.. f F.RS. DARWIN, Major L., Sec. R.G.S. GotcH, Professor F., F.R.S, Happoy, Dr. A. O., F.R.S. HAWESLEY, C., M.Inst.C.E, HiccGs, Henry, LL.B. LANGLEY, Professor J. N., F.R. MACALISTER, Professor A,, F.R.! | McKenrnick, Professor J. G., PR MACKINDER, H. J., M.A. Nos re, Sir Ae Bart., K.C.B., F.R.S. PERKIN, Professor W. H., F.R.S. { SEwaArpD, A. O., F.R.S. Suaw, Dr. W.N., F.R.S. SHIPLEY, A. E., F.R.S. Warts, Professor W. W., F.R.S. Woopwarp, Dr. A. SMITH, F.R.S, Ss. S. EX-OFFICIO MEMBERS OF THE COUNCIL, The Trustees, the President and President Elect, the Presidents of former years, the Vice-Presidents and Viee-Presidents Elect, the General and ‘Assistant General Secretaries for the present and former years, the General Treasurers for the present and former years, and the Local Treasurer and Secretaries for the ensuing Meeting. TRUSTEES (PERMANENT). The Right Hon. Lord Avegury, D.C.L., LL.D., F.R.S., F.L.S. The Right Hon. Lord RAYLEIGH, M.A., D. C.L., LL.D., F.R.S., F.R.A.S. Sir ARTHUR W. Ricker, M.A., D.Sc., ERS. PRESIDENTS OF FORMER YEARS. Sir Joseph D. Hooker, G.C.S.1. ) Sir Archibald Geikie, Sec.R.S. | Sir Michael Foster, K.O.B., F.R.S. Lord Kelvin, G.C.V.O., F.R.S. Prof. Sir J.S. Burdon Sanderson, | Sir W. Turner, K.O.B., F.R.S. Lord Avebury, D.C.L., F.R.S, Bart., F.R.S. | Sir A. W. Riicker, D.Sc., F.R.S. Lord Rayleigh, D.C.L., F.R.S. Lord Lister, D.O.L., F.R.S. | Sir J. Dewar, LL.D., F.R.S. Sir H. £. Roscoe, D.C.L., F.R.S, Sir John Evans, K.C.B., F.R.S. | Sir Norman Lockyer, K.C.B., SirWm. Huggins, K.O.B., Pres. Sir William Crookes, F.R.S. | BRS. GENERAL OFFICERS OF FORMER YEARS. F. Galton, D.O.L., P.R.S. '. Gal a Prof. T. G. Bonney, D.Se., F.R.S. | Dr. D. H. Scott, M.A., F.R.S. Sir Michael Foster, K.C.B.,F.R.S. | A. Vernon Harcourt, F.R.S. Dr. G. Carey Foster, F.R.S. P. L. Sclater, Ph.D., F.R.S, Sir A, W. Riicker, D. Se., F.R.S, Dr. J. G. Garson. | Prof. E, A, Schiifer, F.R. Ss. l AUDITORS. E. W. Brabrook, Esq., O.B. | H, Higgs, Esq., LL.B. REPORT OF THE COUNCIL. lxxxix Report of the Council for the Year 1903-1904, presented to the General Committee at Cambridge on Wednesday, August 17, 1904. The Trustees of the Association having consented to act as Trustees for the sum of 50/., presented to the Association by the late Sir Frederick Bramwell, to provide for a report being prepared and presented at the Centenary Meeting of the Association ‘dealing with the whole question of Prime Movers in 1931, and especially with the relation between steam engines and internal-combustion engines,’ the money has been invested, in accordance with the suggestion made by Sir Frederick Bram- well, in 24 per cent. self-cumulative Consols. . The’ following resolutions having been referred to the Council by the General Committee for consideration, and action if desirable :— 1. The Committee of Section A, having received a communication from the International Meteorologicai Committee, is of opinion that the intro- duction of international uniformity in the units adopted for the records of Meteorological observations would be of great practical advantage to science, and that the Council be requested to take such steps as they may think fit toward giving effect to the resolution :— the Council appointed a Committee, consisting of Lord Rayleigh, Dr. W.N. Shaw, Dr. R. H. Scott, Mr. C. V. Boys, Dr. R. T. Glazebrook, Professor Schuster, the President, and the General Officers, to report thereon. The Council concur with the Committee in recommending that the process of arriving, if possible, at a general agreement as to the use of common units should be :— (1) To prepare a statement of the considerations which ‘would guide the choice of units ; (2) To ascertain whether the meteorological authorities in this country would entertain proposals to select units on these considerations ; (3) To ascertain whether (a) India, (b) the Colonial Organisations, would entertain similar proposals ; (4) To approach the United States upon the matter ; (5) To consult the meteorological organisations of foreign countries ; and finally (6) To report the proceedings to the Association of Academies with a view to the adoption of a general system. It would be desirable for the United States to be kept informed of the proceedings from the time that it is ascertained that the meteoro- logical organisations of this country are willing to consider the matter, but it is not desirable to challenge a categorical reply until the attitude of the Colonies and dependencies is known. A memorandum in accordance with recommendation (1) has been drawn up as a basis for discussion. The Meteorological Council, having already expressed a favourable opinion upon it from that point of view, the Council are taking steps to ascertain the views of the various authori- ties in the manner indicated in the foregoing paragraph, and it is hoped Eee st _ REPORT—1904. that arrangements will be made for a discussion of the subject in Section A at Cambridge. 2. That the Council be asked to consider the desirability of permitting the publication of the whole of the Sectional Programmes in the daily Journal at as early a date as possible. ! 3. That it is desirable that further steps should be taken to make the Reports of Committees (as distinguished from papers) communicated to the Association more accessible to the general public by the provision of Indices to the published volumes and otherwise; and that the Council be asked to consider the conditions upon which reports of Committees and Proceedings of Sections miglit be published if required: the Council appointed a Committee, consisting of Dr. Scott Keltie, Pro- fessor R. Meldola, Professor Perry, Professor W. W. Watts, the President, and the General Officers, to report on this matter. The Council recommend— (1) That the names of Members of the Sectional Committees be printed ‘solid ’—7.e. in continuous lines, and that additional names of Members elected during the meeting be added successively, at the end of the list printed in the Journal of the previous day. (2) That the whole programme, so far as settled, of the proceedings of each Section be printed in the Journal issued on Thursday and each suc- cessive morning. The Recorders of Sections should be asked to furnish the programmes of their respective Sections several days before the com- mencement of the Meeting. (3) That the publication of the list of papers read the previous day be discontinued. (4) That the changes suggested in the publication of the reports be not adopted, the existing indices being sufficient for the present. The Council desire to draw attention to the fact that two volumes of ‘Indices ’—namely, from 1831 to 1860, and from 1861 to 1890—have already been published and are on sale. 4, That the Sectional Committees be continued in existence until the new Sectional Committees are appointed, and be authorised to bring to the notice of the Council in the interval between the Annual Meetings of the Association any matter on which the action of the Council may be desired in the interests of the several Sections, and that a Committee may be summoned at any time by the President of the Section, or by the Council : the Council, having considered the resolution, recommend that it he referred to the Committee of Recommendations. 5. That the Council be requested to consider the desirability of urging upon the Government, by a deputation to the First Lord of the Treasury or otherwise, the importance of increased national provision being made for University Education : the Council considered the matter at a Special Meeting, when it was resolved :— ‘ That the President be requested to approach the various Universities aud University Colleges, and to inquire (1) whether they would be willing to join in organising a deputation to the Prime Minister to ask for increased help to such institutions from Government funds ; (2) whether they would each appoint representatives to a Joint Committee to organise such a deputation, it being understood that the deputation will consist REPORT OF THE COUNCIL. x¢ci not merely of representatives of Universities, but of all those interested in the objects which it will be the aim of the deputation to secure.’ The communication made in pursuance of the foregoing resolution by the President to the various universities, university colleges, and large organisations interested in educational science, was replied to so favour- ably by them that steps were taken to organise a deputation to the First Lord of the Treasury. A large and distinguished deputation, including representatives of all the universities, university colleges, and many county, municipal, and other educational authorities in the United Kingdom, was received by the Prime Minister, the Chancellor of the Exchequer also being present, on July 15, at the House of Commons. Prior to the deputation a memo- randum had been drawn up by the President, and agreed to by the representatives of the principal universities, pointing out the necessity of a new departure on the part of the Government in relation to State Aid for Universities. This memorandum was forwarded to Mr. Balfour some days before the date of the deputation. The deputation was intro- duced by Sir Norman Lockyer. Mr. Peiham (representing Oxford) and Dr. Chase (Vice-Chancellor of Cambridge), on behalf of the older universities, and Mr. Chamberlain (Chancellor of the University of Birmingham), on behalf of the newer universities, addressed the Prime Minister, pointing out the need for much more liberal State aid being granted for purposes of higher education. Sir W. H. White and Sir W. Ramsay spoke of the importance of endowment of university teaching in relation to the application of science to the industries of the country. Sir R. Jebb mentioned the needs of the Humanity departments of universities. Sir Henry Roscoe discussed the importance of original research and its infiuence on our national well-being. Mr. A. Mosely, C.B., pointed out what was being done in other countries in practical university training for commercial and industrial life. Mr. Bell, M.P., spoke of the importance of university training being put within the reach, as regards expense, of the most promising minds in all classes of the community, so as to widen the area of selection for the higher activities of the nation. Mr. Balfour, in reply to the deputation, said that he did not suppose there had ever been congregated in one chamber so many representatives of learning in this country, and hoped that they would forgive him if he did not wholly rise to the expectations formed of the answer he had to give on behalf of the Government. The words of his which had been quoted would, he hoped, absolve him from the necessity of again express- ing sympathy with what he took to be the main object of the deputation. Though it has been said that we have failen far behind at least two great countries in our national education, he absolutely denied that there is the smallest sign that in the production of the germinating ideas of science we have shown any inferiority. Germany has for many generations pursued the State-endowing process of applying science to industry, and in this we are far behind. The system of thought in Germany, the habits of the people, and the Government, in this respect place them at great advantage as compared to us, as far as endowment of universities can help a naticn in the industrial struggle. But the mere endowment of universities will not, he thought, add greatly to the output of original work of the first quality.. It will provide an education which will render xell REPORT—1904. fit for industrial work persons who, without university education, would be very ill-equipped indeed. He concurred with all the speakers that there is a great financial need, both in the old and new universities, for help towards this object. But there is a still greater need—namely, that capitalists should recognise the necessity of giving employment to those whom the universities turn out. There is some evidence to show that shipbuilders and manufacturers prefer the future captains of industry to begin work early in life in the old way. He thought they were wrong, but they must be convinced that they are wrong, otherwise there will be no advantage in turning out qualified students if employers are content to use the man who acquires his training by actual day-to-day labour, but is not qualified in the higher scientific attainments which are more and more becoming necessary. Another thing we want is the creation of positions which will enable a man who has exceptional gifts of originality in science to devote his life to the subjects of his predilection, so as not to be driven to another kind of life in which he will not be able to render the full service of which he is capable to his country. In Germany such positions, which must in the main be attached to the universities, are more numerous than in this country. He could conceive no more admirable use of any funds which the universities can command than the increase of such positions. Having dealt with the more general aspects of the problem presented by the various speakers, he desired to leave it to the Chancellor of the Exchequer to speak upon the more practical question of what the Government can do and what it cannot do. The Chancellor of the Exchequer said that he wished to express his interest in the work of universities, and recognised the larger part they were likely to play in our national development in the future. He con- sidered it would be a misfortune if it were to be thought that it was the duty of the State to take upon itself the whole or main cost of the higher education of the country, or if the State were to come into such relations towards university education as it occupies towards elementary education. He must bid them consider what control the State would have to exercise, and what restrictions it might feel called upon to impose if it ever took on itself the duty of supplying to the universities such large grants as had been suggested. State aid must always be accompanied by State control, and it was, he thought, dangerous for the higher education of the country thatat should have to conform itself, for the purpose of obtaining grants, to rules and regulations laid down by the Treasury. It would be not less disastrous in the interests of higher education if anything were done to relieve patriotic citizens of that sense of the importance of supporting higher education by voluntary endowment and subscription. The Govern- ment had not stinted their contributions to education as a whole. They had been spending large sums on primary and secondary education, which was a necessary equipment for any student who wished to make profitable use of the facilities the universities granted. The Government had shown their interest in universities this year by proposing to Parliament to double the grant recently given to university colleges, and had expressed a hope that in the coming year they might be able again to raise that sum so as, in round figures, to double it once more. We are not enjoy- ing one of those periods of prosperity when the Treasury could afford to be generous without having to place fresh burdens on the taxpayer. Whatever the claims of university education to further assistance, they REPORT OF THE COUNCIL. x¢lil must wait further development until the finances of the country are in an easier position. Beyond what he had stated it would be impossible to make in the next financial year further large contributions to university education. He thought that it would be of some assistance if universities would meanwhile consider to what extent they were willing to come under control if they received grants, to what extent the State was to have a voice in fixing the fees of students, and to what extent it was to direct or influence teaching, whether it was to allocate its assistance to promote special branches of study, or whether it was desired to make every university complete in itself. Since the date of the deputation the President has been in corres- pondence with representatives of the universities, and he has reported that the Deputation Committee will probably hold another meeting in order to obtain further information from the universities to be laid before the Chancellor of the Exchequer. The work of organising this deputation involved an amount of clerical work beyond the ordinary strength of the office, and special assistance had to be obtained for the purpose. Considerable expense has also been incurred in preparing and printing reports of the several meetings and conferences which have been held. 40 Vegetative Power of Seeds... 8 1 11 Questions on Human Race... 7 9 O £1449 17 8 ee 1843. Revision of the Nomenclature OL StATS <.sscccssesmesnrdeanstee 2-0 0 Reduction of Stars, British Association Catalogue ...... 25 0 0 Anomalous Tides, Firth of Hornby cies cseiemasaeeancaiee scare 120 0 O Hourly Meteorological Obser- vations at Kingussie and Inverness .....s. er a Wee) Meteorological Observations ab Plymouth: . ood: sscvsreasenc 55 0 0 Whewell’s Meteorological Ane- mometer at Plymouth ....., L050). .0 Meteorological Observations, Osler’s Anemometer at Ply- SNOW, waccus«ccsacesverasioneeees 20 0 0 Reduction of Meteorological Observations ...........sseee0s 30 0 0 Meteorological Instruments and Gratuities ..........000.- 39 6 O Construction of Anemometer BUIMVEINEES | Aiossesceease dete 5612 2 Magnetic Co-operation......... 10 8 10 Meteorological Recorder for Kew Observatory ....... wee okppOee), 10 Action of Gases on Light...... 18 16 1 Establishment at Kew Ob- servatory, Wages, Repairs, Furniture, and Sundries... 133 4 7 Experiments by Captive Bal- IOONE) seessnvaeseseansaneraemee ene 81 8 0 Oxidation of the Rails of RAL WAY Sicscnsnocnsmenesethiheee 20 0 0 Publication of Report on Fossil Reptiles ............... 40 0 0 Coloured Drawings of Rail- way Sections .........ssssee00s 147 18 3 Registration of Earthquake Shocks .. . eS exil rEPortT—1904, 1847. 1852. LS ds £ s. da. Computation of the Gaussian | Maintaining the Establish- Constants for 1829......-..0 50 0 0 ment at Kew Observatory Habits of Marine Animals... 10 0 0! (including balance of grant Physiological Action of Medi- 10) ae S}H10) Me pscenondocetbons serc- 233 17 8 CINICS) das cesancsssteewecneaseeeaee 20 0 O | Experiments on the Condue- Marine Zoology of Cornwall 10 0 0 tion of Heat ......... sisaseeee 56 2 9 Atmospheric Waves ........4--. 6 9 383 | Influence of Solar Radiations 20 0 0 Vitality of Seeds ........c.000 4 7 7 | Geological Map of Ireland... 15 0 0 Maintaining the Establish- Researches on the British An- ment at Kew Observatory 107 8 6 | melida s..scccscccccecsesseceeees 10 0 0 £208 5 4 | Vitality of Seeds ............... 10) 6252 ——————= Strength of Boiler Plates...... 10% 0) 70 1848, £304 6 7 Maintaining the Establish- | a are re ment at Kew Observatory 171 15 11 | 1853. Atmospheric Waves ..........++ 3.10 9 | Maintaining the Establish- Vitality GEISCCOShocckacesass cane 915 O ment at Kew Observatory 165 0 O Completion of Catalogue of | Experiments on the Influence SSEELTIS Wire c aisralecinisieis'c.ons oh'o 0 s'sisiaisisinin 70 0 0} of Solar Radiation ......... HY 010 On Colouring Matters ......... 5 0 0 | Researches on the British On Growth of Plants ......... 15 0 0 ANNCMOR ai catendsucteeteree = 1020170 £275 1 8 | Dredging onthe East Coast — Of Scotland ....cnecevereccssrss 10 0 0 1849, | Ethnological Queries ......... B20 30 Electrical Observations at £205 0 0 Kew Observatory ............ 50"-00 Maintaining the Establish- 1854. ment at itto.........ccecee0- Om 205 seg hats : SaEe | Maintaining the Establish- Eceprivct Pinsts mes. 00, aan eee na of Periodical 10 0 0 former grant)... 330 15 4 Bill on ‘Kcsovat otialnese Investigations on Flax......... ES 00) 0) metrical Observations 13 9 O HOt, temp cha rp eee eee |) 2 Wrourht) Iront.. .s.ssaecestasse 10; 40,70 £159 19 6 | Registration of Periodical Phenomena. .scessessacscenceos 10 0 0 1850, British Annelida ............... 10 0 0 Maintaining the Establish- Vitality of Seeds ...........:. 5.2.3 ment at Kew Observatory 255 18 0 | Conduction of Heat ............ A DeiO) Transit of Earthquake Waves 50 0 0 | £38019 7 Periodical Phenomena......... 15 0 0} Meteorological Instruments, | 1855 AZOTES\adoentrnanse men nontea sea 25 0 0 Sheree eek £345 18 0 Maintaining the Establish- ae ment at Kew Observatory 425 0 0 | Earthquake Movements ...... 10 0 O 1851. | Physical Aspect of the Moon 11 8 5 Maintaining the Establish- Vitality of Seeds ............00. LO Teil ment at Kew Observatory Map of the World............... 15 0 0 Cineludes part of grant in | Ethnological Queries ......... 5 0 0 STONE. scctevidewaseasteaienescces 309 2 2 | Dredging near Belfast......... 4 0 0 Theory of Heat ...........0000008 20 1:1] £480 16 4 Periodical Phenomena of Ani- ; els and Plants..........s0006 5080 1856 Vitality of Seeds ..........0.... 5 64M | woseatns abli 2a (hee of Solar Radiation 30 0 0 | eeu: ee cae Ethnological Inquiries......... £2) HOMO. rat me aS NES Researches on Annelida ...... 10 0 0 ial £75 £3919 7 1BBB e500 07g BIEN} O [= Panereuare a GENERAL STATEMENT. ee eee Strickland’s Ornithological RIMBON YING) scvicscsshscetecs + 100 0 6 Dredging and Dredging URIS Sees cei clciscaossseceseceasee J ss 0 Chemical Action of Light ... 20 0 0 Strength of Iron Plates ...... 10 0 0 Registration of Periodical Phenomena...........cecsereeees 10 0 O Propagation of Salmon......... 10 0 0 £734 13 9 1857. Maintaining the Establish- ment at Kew Observatory 350 0 Harthquake Wave Experi- TESUECRUS) igo nqnooteoe Hu dobiot co SRE 40 0 Dredging near Belfast......... 10 0 Dredging on the West Coast Of Scotland ............:s000s0e 10 0 Investigations into the Mol- lusea of California ......... 10 0 Experiments on Flax ......... 5 0 Natural History of Mada- ABCAR Any sa accuceu suteinceseeches 20 0 Researches on British Anne- TAO gs 3 sianiateolsicieidos bck 25 0 Report on Natural Products imported into Liverpool... 10 0 Artificial Propagation of Sal- PEO Tee e tae sain scieaciessn= = sak 10 0 Temperature of Mines......... Tes Thermometers for Subterra- nean Observations............ 5 7 HT C-DOAUS |. 62. sc eceveeececoeeeee 5 0 £507 15 1858. Maintaining the KEstablish- ment at Kew Observatory 500 0 0 Earthquake Wave LExperi- ASOD cadelectesee see scessess 0sas 25 0 0 Dredging on the West Coast DE Scotland ..........0...sse0000 10 0 0 Dredging near Dublin......... 5 0 0 Vitality of Seed ............... 5 5 0 Dredging near Belfast......... 1813 2 Report on the British Anne- PUAN ccetclentel cetessac, acassexscce 25 0 0 Experiments on the produc- tion of Heat by Motion in PES a ccclidsteesyswes ative cea 20 0 0 Report on the Natural Pro- ducts imported into Scot- DEM. cavoss asco cece peepee aes eae 10 0 0 £618 18 2 1859. Maintaining the Establish- ment at Kew Observatory 500 0 0 Dredging near Dublin......... 145 0 0 1904. Oe OS. ou oO o oo (oi XSi) j=) Cx. 8 ae Fat Osteology of Birds ............ 50 0 0 Trish Memnicata ssh. ives csticsen « 5 0 Q Manure Experiments ......... 20 0 0 | British Meduside ............... 5 0 0 Dredging Committee ......... 5 0. 0 Steam-vessels’ Performance... 5 0 0 Marine Fauna of South and West of Ireland............... 10 0 0 Photographic Chemistry ...... 10 0 0 Lanarkshire Fossils ............ 200 1 Balloon Ascents.........cces+s++ 39 11 0 £684 11 1 1860. Maintaining the Hstablish- ment at Kew Observatory 500 0 @ | Dredging near Belfast......... 16ye6) 0 | Dredging in Dublin Bay...... 14 0 0 | Inquiry into the Performance of Steam-vessels ............ 124 0 0 Explorations in the Yellow Sandstone of DuraDen .. 20 0 0 Chemico-mechanical Analysis of Rocks and Minerals...... 25 0 0 Researches on the Growth of PIGN GS 95.2 . sexe. awaseaiees beast 101,08 Researches on the Solubility Oba SaliSmrssecesee asses ee seec 30 0 0 Researches on theConstituents OL Manures’ 2224. ......0.csees 25 0 0 Balance of Captive Balloon ACCOUNTS: < sci ceeseet ees oes soe 113 6 £766 19 6 1861. Maintaining the Establish- ment at Kew Observatory.. 500 0 0 Earthquake Experiments...... 25 0 0 Dredging North and East Coasts of Scotland ......... 23 0 0 Dredging Committee :— 1860......£50 0 0 72 0 0 1861......£22 0 0 = Excavations at Dura Den...... 20 0 0 Solubility of Salts ............ 20 0 0 Steam-vessel Performance ... 150 0 0 Fossils of Lesmahagow ...... 15 0 0 | Explorations at Uriconium... 20 0 9 Chemical Alloys ............... 20 0 @ Classified Index to the Trans- ACHLONNY done eetscces ccc ces 100 0 0 Dredging in the Mersey and WES away wun aceheceteei ance 5 0 0 Wap? @ivele pestres soecesetereseaete 30 0 0 Photoheliographic Observa- LONG ipa en te earcvecevtueie ieee « 50 0 0 PYIsOUWD1etYp aeseteettocsscercnes 20 0 0 Gauging of Water............006 10 0 @ Alpine Ascents ........ ......000 6 510 Constituents of Manures...... 25 0 0 £1111 5 10 aetna oe CX1V 1862. REPORT—1904.. Lass Maintaining the EHstablish- ment at Kew Observatory 500 0 Pa ru Ma WS saaseeisaseensenswccpen 21 6 Mollusca of N.-W. of America 10 0 Natural History by Mercantile Marine <...c..0-. ngaotacet seers 5 0 Tidal Observations ..........+. 25 0 Photoheliometer at Kew ...... 40 0 Photographic Pictures of the SURE Seeecnsasasiieses ones pepenset 150 0 Rocks of Donegal............+ 25 0 Dredging Durham and North- umberland Coasts ........++6. 25 0 Connection of Storms ......... 20 0 Dredging North-east Coast DEM SCOMATGN \ehucascsecnesacee 6 9 Ravages of Teredo .........+. 3 11 Standards of Electrical Re- BISHAMICE! sccdecewpescscorsesset 50 0 Railway Accidents ...........+ 10 O Balloon Committee ...........- 200 0 Dredging Dublin Bay ......... 10 0 Dredging the Mersey ......... 5 0 Prison Diet «ccscocssssescoosecess 0 Gauging of Water Steamships’ Performance...... 150 0 Thermo-electric Currents 5 0 £1293 16 1863. Maintaining the Establish- ment at Kew Observatory... Balloon Committee deficiency Balloon Ascents (other ex- penses ) Entozoa Coal Fossils PICIViN GS <5. ..ecccscscesase Sane case Granites of Donegal............ Prison Diet Vertical Atmospheric Move- ments Dredging Shetland ............ Dredging North-east Coast of NGOUAOM re soe cecetsmanecaneacss Dredging Northumberland BNO SD ATHAIMN§,.escses 10 Kent’s Cavern Exploration... 100 Luminous Meteors ............ 20 Heat in the Blood............... 15 Fossil Crustacea ..........-.00. 25 Fossil Elephants of Malta ... 25 Waunar OD jectainiccscentwcansonns ae 20 Inverse Wave-lengths ......... 20 British Rainfall......... cesesenes 100 Poisonous Substances Anta- PONISI: .ccccanaensseseniacassane 10 Essential Oils, Chemical Con- StittMtiON,, &0C.| ea pcenedecuorboseeEe neocon 50 Reduction of Tidal Observa- MIO DSM re cirens cnnsdeens aisveciarsee 10 Calculating Tables in Theory GES NTIMDCLS ass.ciencanesssaeee 100 Meteorological Observations On Ben NEVIS .....0s0c.. 0-000 50 INE TC OTIC ISH tas. sea, casslgesdss 70 Vapour Pressures, &c., of Salt OUTMOUS Wares sseoScengt snsnisl> 25 Physical Constants of Solu- GIOTISE arsbatenetoveaness seas sean s 20 Volcanic Phenomena of Vesu- VIG Siete caste cia ic cian ceases 25 Rayeill Hissure...jcccvsssoseese 15 Earthquake Phenomena of CAN AME t aaiaaisacee eum cwaMces nek > 70 Fossil Phyllopoda of Palzeozoic ROCKS saps Scet ened iapeae toasts 25 Fossil Plants of British Ter- tiary and Secondary Beds... 50 Geological Record ............... 50 Circulation of Underground WaHONS) ccrens cussceehepse sesso 10 Naples Zoological Station 100 Zoological Literature Record. 100 Migration of Birds ............ 30 Exploration of Mount Kilima- LJALO Weare soseceaua veers sasente 25 Recent POlyZ0de...cs0se+acceensere 10 Granton Biological Station ... 100 Biological Stations on Coasts of United Kingdom ......... 150 Exploration of New Guinea... 200 Exploration of Mount Roraima 100 £1385 1886. Electrical Standards............ 40 Solar Radiation .......c)...00 ce 9 Tidal Observations ............ 50 Magnetic Observations......... 10 Observations on Ben Nevis... Physica! and Chemical Bear- 100 ings of Electrolysis ......... 20 Chemical Nomenclature ...... 5 Fossil Plants of British Ter- tiary and Secondary Beds... 20 Caves in North Wales ......... 25 Volcanic Phenomena of Vesu- VLUS! or.ac Goose coo Oo Oo: oO o So oo OP ©» 7 ie o oooooso oo S90 xX 1|o ooo eco. Sc oC {Oooo ooo ooo oocEe oO o o oo © oO J =) Oo (=) | REPORT—1904. £ Migration of Birds ............ 30 Secretion of Urine............... 10 £xploration of New Guinea... 150 Regulation of Wages under Sliding Scales ...........00. 10 Prehistoric Race in Greek Tslands\....:sssssesssasssneqsenee 20 North-Western Tribes of Ca- NAC Aoasienncondeosnse dacenameareme 50 £995 1887 Solar Radiation ..............0..+- 18 HlectrolySisic-sssa-aessns0uss 5 0 Discharge of Electricity from ROINtS he cececnec vac rues conesidens 10 0 Ultra Violet Rays of Solar MDCCHRUMT | Mesesccncas-cendeeens 50 0 International Standard for Analysis of Iron and Steel... 10 0 Isomeric Naphthalene Deriva- RAW CHiehenasipcinpsce sesseraceeeranes 25 0 Formation of Haloids ......... 25 0 Action of Light on Dyes ...... 17 10 Geological Record..........++0+ 100 O Volcanic Phenomena of Vesu- VAUS ten = cae o neces 100 0 Coral Reefs of the Indian REGION 2. sessessvesesceeaseees 30 (0 Physical and Chemical Con- stants of Sea-Water ......... 100 0O Future Dealings in Raw IPLOGUGCE) ss sressnnsneedeseteeuee 2 10 Silchester Excavation ........ 10 0 Ethnological Survey of Canada ..cccnaccess=secssncepes 50 O New Edition of ‘Anthropo- logical Notes and Queries’ 40 0 Photographs of Anthropo- logical Interest .............+. 10 0 Mental and Physical Condi- tion of Children in Schools 5 0 Ethnography of the Malay IR@niNSi lal, co nscinccmnaseneeuenes 25 0 Physiological Effects of Pep- LONE ones cvienie cenenonsomepsnmess 20 0 Comparative Histology of Suprarenal Capsules......... 20 0 Comparative Histology of @erebral Cortex... ..s:..050:.- 5 0 Electrical Changes in Mam- malian NerveS ...cccssecseees 20 0 Vascular Supply of Secreting (GEG Eh asansaonbroodse sane nooe 10 0 Fertilisation in Phzophycee 20 0 Corresponding SocietiesCom. 20 0 £1,072 10 1901. Electrical Standards ......... 45 0 0 Seismological Observations... 75 0 0 Wave-length Tables............ 414 0 Isomorphous Sulphonic Deri- vatives of Benzene ......... 35 0 0 Sle rs OO. Oo “Oe Se OF OR eee iene Ce Om ic: = 18. 1d. Life-zones in British Carbo- niferous Rocks ........++0+0+ 20 0 0 Underground Water of North- west Yorkshire ..............- 50 0 0 Exploration of Irish Caves... 15 0 0 _ Table at the Zoological Sta- tion; Naplesjioc.mcsroes rapes 100 0 0 Table at the Biological La- boratory, Plymouth ......... 20 0 0 Index Generum et Specierum Amimalium . 6.25. 5

p-+l, ¢ should be expressible as the quotient of two @-functions, and in such cases, once more, (8,2) - + + (8nZm) are m of the 2p—2 moveable zeros of a ¢-function. Now Riemann shows that the p differential equations formed from equations (A) can be completely integrated, under certain conditions : first, when m G1 70,M,1, + 2D0,m S(.-m) =[ > 7 sc iia a sd where the summations in the exponents are with respect to p, p’, and that in the outer bracket with respect to m,...m,. The adoption of u,...u, the p linearly independent integrals of the first kind, in place of the general arguments v, . . . v, and of the moduli of periodicity of the w’s in place of the constants a,,,—an adoption which is duly justified by Riemann—makes, as he says, ‘log 3 a function of a single variable z, which when s, ~ resume their original values after an arbitrary continuous change in the position of 2, is changed by linear functions of the w’s.’* Thus 3 is a one-valued function of p arguments, but of a single point on the Riemann surface, which point is the upper limit of each of the p integrals which appear in the arguments of 9. The notation employed by Riemann has not been adopted by all following writers, for he does not use the symbol of integration with upper and lower limits associated with it ; he introduces instead a symbol of his own for the values of the integrals at the upper limits, and only mentions the lower limits in words. There is, for our purpose, a certain advantage in this notation, for it draws attention to the values of an integral w, ata certain set of points which form the different upper limits of the same integrand. Thus, if «,...«,, are the m points on the surface in which a rational function of s, 2 takes the same value, then, in Riemann’s notation, wu” is the value of w, (for w=1,...p) at the point ¢, (for v=1,.. . m), for ' Loe. cit. § 16. 2 Loe. cit. § 17. » pe Pie i ON THE THEORY OF POINT-GROUPS. 27 which the values of s, z are s,, 2,; in particular, if 7,.. .%, are the p zeros which every 9-function is shown to have, then aj? is the value of w, (for w=1,.. .p) at the point », (for v=1,.. .p) for which the values of s, z are o,, ¢,.! Moreover, if in the argument of the $-function the integral w/? or «® occurs, it is possible, by allowing the point ~%, or @, (still de- fined as above) to be a variable point on the surface, to consider the $-function as a function of z, or of Z, instead of as a function of the quite unspecialised point z; this is important in connection with the identical vanishing of the $-function. The introduction of additive constants ¢,... ¢, into the arguments of the $-function is another important feature of Riemann’s discussion of the subject ; for he shows ! that in $(.., u,—e, ...) it is always possible so to determine the = i lower limits of the integrals that (...¢,...)=(... Zal?. 1 shall hold, and it is with ¢hese lower limits that he works. The establish- ment of this congruence between the additive constants of each integral and the sum of its p values at the p zeros of the 9-function Jeads to the preliminary discussion in § 23 and § 24 of the conditions under which a 9-function vanishes identically, ie., for an arbitrary position of the variable point on the surface. »—1 He first shows, in § 23, that if (...u,—e,...)=(... — Sa? coe 1 then the $-function with these arguments vanishes identically, ¢.e., for any arbitrary position of ¢; and, conversely, that if 3 vanishes identi- cally then each of its arguments w,—e¢, must be congruent to a negative sum of the values of p—1 integrals at certain p—1 points m . . . m4” Now these p—1 points may be arbitrarily chosen, and we still have p-l 2 ( ...— 3a”... } identically zero; and, since $ is an even function, 1 p-1 meanis leads to 9 ( ... Ba? ... ) being also identically zero ; whence 1 by the above converse we are led to certain p—1 points 9, . - + M-2 p-1 a 2p—2 : Beem A Sat! oy Ss ( Be ers he ) sie, tothecongruence 1 Dp 2p—2 ( tees Ba” ... )=(0,0,...0). But this shows that the last p—1 z points are dependent upon the position of the first p—1l points in such a manner that as the latter vary continuously we always have 2p-2 > da’ =0 ; and this system of differential equations is, as has been seen, 1 always satisfied by the 2y—2 moveable zeros of the ¢-function (the i ci x @ lower limits are another set of moveable zeros, since = = and when 52 €=0, 9% must = 0 but not ~®). Hence we have the important result that when a 8-function vanishes identically its p zeros are tied by a p-function. In § 24 a second important conclusion is derived from the fact that if 1 Loe. cit. § 22. 2 The precise determination of these p—1 points is as _ follows:—It is assumed that although & (...7,...) vanishes identically, yet that ++ U—a+7,. ..) does not vanish identically where np is arbitrary—the remaining y—1 zeros of this S aren .. . mp-1. 28 REPORT—1904. vanishes identically each of the arguments is congruent to the negative sum of the values of p—1 integrals at certain p—1 points ; these points, namely, are assumed to be p—1 of the p points in which any rational function takes one and the same value on the surface, and then with the notation explained above we have oe (p) —_— =.) v eine ee. =e... )=(--. aU oes & z , M4 eC) 4 = Ves, Sear eran fy (ae args | 1 Pp (v) Hence for all continuous variations of Sp) &) we have du, =0,and there- fore the p pairs of quantities s,,~, are p of the moveable zeros of o=0, wu’ where the remaining p—2 are fixed. And if w?*-+-+be the values of 2n—2 u, at these p—2 fixed points we have ic sas Yu, ; . =(0,0,...0). Whence 1 2p—2 it follows that (...¢,...)=(...—3w,...). Which results are thus p+i stated by Riemann: ‘An arbitrary system of quantities (.: 6/08 sory: l ee congruent to one system of the form {... Xa...) unless it is congruent to 9 p-2 one of the form i --—Za...}), in which case it is congruent to an in- finite number of the first-mentioned form,’ It is in these results that we find the first suggestion of a point-group— that is, of a set of points on the Riemann surface which are chosen in some definite manner out of the set in which a rational function assumes one and the same value. Moreover, in the most general form into which Riemann threw these same results in his later memoir—now to be de- scribed—we find a conspicuous feature to be the reversible relationship which exists between a pair of point-groups in the two cases which he considers— a relationship, namely, concerning the number of points in each point- group which may be arbitrarily assumed. This relationship is intimately connected with the Riemann-Roch theorem—although Riemann himself was not concerned to point this out—andis a particular case of the Theorem of Reciprocity established by Brill and Noether. The first two sections of the memoir on the vanishing of the S-functions are occupied in putting the theorems of § 23 upon a more rigorous foundation by showing that it is always possible to take such arguments for a 9-function as to ensure that it does not vanish identically in which case the results of § 23 and § 24 are true. The third section then goes on to establish these in a still more general form, by considering successive pairs of 3-functions with arguments that differ from each other in an analogous manner to those of 9(...7,...) and &(...u,—a2+r,... ), of which the first vanishes identically, but not the second, and where r, itself is of increasing complexity. Thus a typical pair of $-functions is (1) SC... a PtP 4 oP. fam —yP-Y— 4-9, , , —uP-™ De, , ey and (2) Bes ae alt — PD — ye Po ey the first of which is assumed to vanish identically, while the second, whose arguments only differ by the addition of a?-™*?—w?-™, does not. Since (2) does not vanish identically we have, by considering it as a ON THE THEORY OF POINT-GROUPS, 29 ganetion Of Z,,;,(.-. —ap..-—al™) + ule +... uP” +e...) con- gruent to the sum of the values of all its p zeros ; now the m points Ep-1+ + + €p-m are m of these zeros, since when ¢,,;=2,1 . . . 2m in L turn, we get a $-function whose arguments are of the form of (1) ; let the p—m other zeros be n, . ~~ %)-m then the above congruence, when identical terms are removed from each side, becomes eee ale, 2 2 Ja (2s ob ie Fal a yt But again, by considering (2) as a function of z,_,, we find that, 3 being an even function, (...ai?t?+... +aPo™*P—upP— 1... —uPe-m—e,... is congruent to the sum of its values at its p zeros; and that m+1 of these zeros are 741 - - - Mp—m+1, Since when 2, ;=a?t” , . .a?-™+*” in turn we get a 3-function whose arguments are of the form (1) ; now let the p—m-—1 other zeros be ¢,; . . « €)~ i, then the congruence which holds is Ret le sage er ee Jw Os ce WOES ome is toh We have thus shown that (e, . . . e,) = (ul? ... a) and also to (—u ... —u”), d.e., that the point-groups composed of the p 7’s and those composed of the p—2 «’s are congruent to each other ; and, more- over, that when m of the points » are arbitrary (p—m being uniquely determined), then m—1 of the points « are arbitrary (since p—m—1 of the p —2 are determinate). And it is easily seen that this relationship is reversible, z.¢., that if m—1 of the «’s are arbitrarily chosen, then a of the ys can be arbitrarily chosen. The 2»—2 zeros of a o-function have thus been divided into two point-groups, containing p and p—2 points respectively, and it has been shown that if m of the p points can be arbitrarily chosen, then m—1 of the p—2 points are also arbitrary, and vice versa. A precisely similar line of argument applied to the conclusions of § 23 shows that the 2»—2 zeros of a ¢ function may also be divided into two point-groups, each consisting of p—1 points, and that then, if m of one point-group are arbitrary, m of the other are also arbitrary. The connection with the Riemann-Roch theorem is at once evident ; for if in the first case dealt with above we assume that a rational function becomes infinite at p points, then, if m of these p points are arbitrary, the function has m arbitrary constants, and therefore, since by the Riemann- Roch theorem m=p—p+1+q, g=m—1, i.e., m—1, different o functions can be drawn through them, which agrees with the number of «’s which have been shown to be arbitrary ; and, conversely, if the number of infinities is p—2, and if m—1 only are arbitrary, the Riemann-Roch theorem shows that m—l=p—2—p+1+4, ie., that g=m, which agree with the number of 7’s which may be chosen arbitrarily. Magnetic Observations at Falmouth Observatory.—Report of the Committee, consisting of Sir W. H. PREEcE (Chairman), Dr. R. T. Guazeproox (Secretary), Professor W. G. Apams, Captain Crea, Mr. W. L. Fox, Principal Sir Anraur Ricker, and Professor A. SCHUSTER, appointed to co-operate with the Conumittee of the Falmouth Observatory in their Magnetic Obser- vations. THE grant voted by the Association last year has been expended in carrying on the Magnetic Observations at Falmouth Observatory. . The apparatus at the Observatory was inspected by Mr. T. W. Baker 30 REPORT— 1904. of the National Physical Laboratory in October last, and found to be working well. The results for the year 1903 have been printed in the Proceedings of the Cornwall Polytechnic Society and in the Report of the National Physical Laboratory for 1903. Dr. Chree is at present engaged in examining the Vertical Force Records for 1904, with a view to deter- mining how best to treat these. They have not hitherto been worked out in full. The records for the great magnetic storm of October 31 and Novem ber 1, 1903, were specially good, and have been reproduced in the Laboratory Report. In view of the fact that the Kew magnets are very much disturbed and that the buildings at Eskdale Muir have only just been commenced, it is in the opinion of the Committee desirable that their work should be continued. They therefore recommend their reappointment, with a grant of 50/. Experiments for improving the Construction of Practical Standards for Electrical Measurements—Report of the Committee, consisting of Lord RayLEIcH (Chairman), Dr. R.'T. GLAZEBROOK (Secretary), Lord Ketvin, Professors W. E. Ayrron, J. Perry, W. G. Apams, and G. Carry Foster, Sir OLtver J. Lope, Dr. A. MurrueapD, Sir W. H. Preece, Professors J. D. Everett, A. Scuuster, J. A. FLemine, and J. J. THomson, Dr. W. N. SHaw, Dr. J. T. BorroMtey, Rev. 'I’. C. Firzparricx, Dr. G. JOHNSTONE StonEy, Professor 8. P. THompson, Mr. J. Renniz, Principal E. H. Grirrirus, Sir A. W. Ricker, Professor H. L. CALLENDAR, and Mr. GEORGE MaTTHEY. APPENDIX PAGE I.-—On Anomalies of Standard Cells. By¥.¥E. Smirw. (From the National Physical Laboratory) . : ; : : : ; ‘ : , 33 Il.— On the Electromotive Force of a Clark Cell. By A. P. TROTTER . : . 40 Tue Committee desire to record their deep regret at the death of their colleague, Professor Everett, who had been a member of the Committee since 1881. He attended the meeting at which the present Report was considered. His work in connection with the C.G.S. system of units is of great importance and has proved of very real value to science. The Committee are glad to report that during the year considerable progress has been made with the construction of the Ampére Balance. Mr. L. Oertling has constructed the weighing mechanism, which has, however, not yet been taken over by his Committee, and the electrical parts of the instrument are nearing completion in the workshops of the National Physical Laboratory. The following particulars of progress and of applied tests may be of interest. 1. The weighing mechanism.—tThe castings, rods, tubes, screws, &c., .ntended for this had their magnetic permeability determined, and no part used in the construction has a permeability differing from unity by more than 0°001 per cent. The balance was examined for stability and sensitiveness at Messrs, a a PRACTICAL STANDARDS FOR ELECTRICAL MEASUREMENTS. 31 Oertling’s works with satisfactory results ; a difference of one-tenth of a milligramme may be detected. 2. The marble cylinders and fittings.—Insulation and permeability tests were made on various samples of marble early in the year; even- tually First Statuary Carrara Marble was chosen as most suitable for the work. An experimental marble cylinder was wound with a double helix and the insulation satisfactorily carried out; the results of the tests leave little doubt as to the advantages of the double helix. The winding of both suspended cylinders has now been completed, and it is anticipated that the fixed cylinders will be finished in September. The linear measurements and insulation tests have yet to be made. Unless unfore- seen difficulties arise the balance equipment should be completed, and the whole ready for preliminary observations by the end of the year. During the early part of the year Mr. F. E. Smith completed his researches into the construction of a mercury unit of resistance, of which some account was given in the last report. The results have been communicated to the Royal Society and are being published in the ‘Philosophical Transactions.’ The values of the various tubes (eleven in number) are very accordant, and a mercury standard of resistance of a high degree of accuracy now exists. Since the completion of his work the specification of the Clark cell has engaged Mr. Smith’s attention, and a detailed account of his work forms an Appendix to the present Report. Mr. Smith has amply confirmed the result of previous investigators that the greater part of the difficulty in obtaining entirely concordant results for the various cells set up by different experimenters is due to the mercurous sulphate. He describes three methods of preparing the paste which lead to identical results, and which have the advantage that cells set up with these pastes have, the same E.M.F. within one or two hundred thousandths of a volt immediately after manufacture. In the first method due to Professor Divers and Mr. Shimidzu the paste is prepared by the action of fuming sulphuric acid on mercury ; in the second, follow- ing Professor Carhart, it is prepared by the electrolysis of weak sulphuric acid and mercury ; while in the third mercurous sulphate is dissolved over a water bath in sulphuric acid. The acid solution is then poured into a large volume of distilled water and the mercurous sulphate is precipitated in a pure form. In all cases it is important that, as advised by Mr. Swinburne and Professor Carhart, the salt should be washed, for a Clark cell, with zinc sulphate, and for a cadmium cell with cadmium sulphate, and not with distilled water. Mr. Smith is continuing his inquiries and hopes shortly to be able to issue a complete specification for Clark and cadmium cells. The completion of the Ampére Balance will enable an absolute determination of their E.M.F. to be made. The Committee regret to report that no further progress has been made since their last report with the experiments to determine the per- manence and reliability of the platinum resistance thermometers de- scribed in that report. It was pointed out last year that a special resistance box was required to enable the work to continue ; unfortunately the funds necessary for its purchase were not forthcoming, and the work has remained stationary for a year. The Committee would consider it most unfortunate if work of & very real importance, on which a start has already been made and 32 REPORT—1904, considerable funds expended in the purchase and investigation of pure platinum wire, should lapse for want of support, and they trust that their recommendation in favour of the continuance of the work may this year be accepted. Meanwhile they would call attention to the very complete comparison up to a temperature of 1000° C. between the constant volume nitrogen thermometer, the platinum resistance thermometer, and the platinum— platinum-rhodium thermo couple communicated recently from the National Physical Laboratory to the Royal Society by Dr. Harker. The Committee have received a cordial invitation to co-operate in the Electrical Conference at St. Louis during the forthcoming autumn, and have asked Professor Perry and the Secretary, who are attending as delegates of the Institution of Electrical Engineers, to represent their views on two questions of special interest. The first of these relates to a proposal by Professor Carhart to substi- tute the saturated cadmium or Weston cell for the Clark cell as a recog- nised standard of E.M.F. The Committee are aware that the fact that the temperature coefficient of the cadmium cell is one-twentieth of that of the Clark cell offers many valuable advantages, but in view of the fact that experiments designed to lead up to a satisfactory specification of the cell are in progress at the National Physical Laboratory, and that the comple- tion of the Ampére balance would enable the absolute E.M.F. of the cell to be determined, the following resolution was passed at the last meeting :— ‘The Committee are not prepared at present to displace the Clark cell, and prefer to wait for the conclusion of the experiments at the National Physical Laboratory, and with the new balance, before coming to a deci- sion as to the value to be assigned to the E.M.F. of the saturated cadmium cell,’ The second question relates to certain proposals as to nomenclature which are to be brought forward by Dr. Kenelley. These are : (A) that a systematic nomenclature should be agreed upon for magnetic units, and (B) that the prefix ‘Abs’ should be used to indicate that a unit is given in the absolute C.G.S8. electro-magnetic system, and ‘ Abstat’ to indicate that the unit in question is in the absolute C.G.S. electrostatic system. Thus an Abs volt would be the C.G.S. electro-magnetic unit of E.M.F. and ‘ Abstat’ volt the C.G.S. electrostatic unit of E.M.F. These proposals have been discussed by the Committee, which have agreed to the following resolution :— ‘With regard to the choice of magnetic units the Committee are of opinion that the only two systems which need to be considered are the C.G.S, system and the Ampére-Volt-Ohm system, and that the quantities to be named, if any, are— 1) Magnetic Potential. 5 (2) Magnetic Flux.! (3) Magnetic Reluctance. Of the above two alternatives the Committee are in favour of the CG.S. ‘ The name ‘Maxwell’ was recommended by the Paris Congress, 1900, as the name of this unit, and this recommendation was adopted by the Committee at Bradford. PRACTICAL STANDARDS FOR ELECTRICAL MEASUREMENTS, 33 system as that on which to base any nomenclature of magnetic units, but are of opinion that a system of nomenclature is not called for.’ electro-magnetic and absolute electrostatic systems of units, and express the opinion that no system of prefixes should be employed in which each prefix does not bear some definite numerical signification. In view of the work still necessary with regard to the Ampére balance, the cadmium cell, and the platinum standard of temperature, the Committee recommend that they be reappointed, with a grant of 50/., that Lord Rayleigh be Chairman, and Dr, R. T. Glazebrook Secretary. APPENDIX I. On Anomalies of Standard Cells. By F. E. Smrru. From the National Physical Laboratory. The Committee disagree with Dr. Kenelley’s prefixes for the absolute During the past two years certain anomalies of Clark and of cadmium cells have been under investigation at the National Physical Laboratory. The work is still far from completion, but the essential results so far obtained are given in this paper. In March 1902 some experiments at Bushy House resulted in the isolation of the depolariser employed in both standards as the great disturbing element. Lord Rayleigh, in his paper in the ‘ Phil. Trans.’ for 1885, § 44, had shown this to be the case, and Mr. Swinburne arrived at the same conclusion in 1891,' while recently in America Professor H. 8. Carhart and Mr. G. A. Hulett have traced the variations in E.M.F. of the cadmium cell to the same source. A new specification of the mode of manufacture of the paste was thought to be desirable, and this problem was the first to receive attention. Im order to be independent of the variations of the other elements, cells were constructed of a type indicated by the arrangement Hg— Paste — Solution and Crystals — Paste — Hg, (4) (2) where a and 4 represent pastes made with different samples of mercurous sulphate. The Rayleigh H form of vessel was employed. Preliminary observations showed that when the same paste occupied the two limbs, ‘such a cell had no measurable E.M.F. In addition a cell typified by the arrangement Amalgam é Sol | z mo Solution & | ts and Crystals a o a | fae ~S wa Paste (B) | Hg was largely employed, a four-limb vessel, similar to two Rayleigh H form of vessels crossed, being used to set up the standard. In this case there 1 See B.A. Report, Cardiff, 1891. 1904. D 34: REPORT—1904. is one negative pole and three positive ones, and the E.M.F. between any two of them may be measured. Such a cell not only indicates whether a particular paste is abnormal or not, but each of the three groups of elements may be compared with an external standard. It is possible, of course, that a change resulting in one of the pastes may affect the neutrality of the solution, and so the E.M.F. of all three groups. All observations were made in a constant temperature room, the cells being immersed in paraftin oil. The earlier results of the investigation are omitted, but the differences in E.M.F. due to pastes made from purchased samples of mercurous sulphate are shown by measurements made of cell No. 1 (4 limbs) and cell No. 28 (2 limbs), the observations covering a period of rather more than two years. The pastes have been distinguished by the letters K, H, and R ; all were subjected to the same treatment and advantage taken of the latest methods for their preparation known at that time. TABLE es Clark Cell, No. 1 (4 limbs). | Pit drareoea Observation. ; _ a= : hoe rraeibe H>R. K>R. | Hee, |) ee Sept. 8,1902 .| +0-00213 +0:00047 | +000166 | +0-00168 Hep. 30, 95,7 195 45 | 150. 4 104 hci aes 150 16 | 104 79 WDece (De. A ei, 123 AB 80 59 Feb. 24,1903 . 94 2 Pee 52 No obs. June 24, ,, . 62 37 25 eas Ey Mavewe =. ok 37 30 aie, a3 Feb. 61904. 27 41 | —0-0v014 | —50 only 9; ,, —.-| 000001 Bk = 52 Ee It is clear that although the effect of each paste is not known two of them have certainly changed, of which one is K. Jn the chart curve HR shows the change in E.M.F. of the H group, assuming the R group to remain constant ; similarly the H ~ K curve represents the change in voltage of this group, K being assumed constant, and like remarks apply to the third curve. There is a sudden break in the directions of the curves H K and KR shown after the observations of November 2, while none is shown in H_ KR; the deflections consequently indicate that the element K must have changed in an abnormal fashion. Indeed between November 2, 1903, and July 9, 1904, the E.M.F. of the K group apparently increased by at least 00003 volt ; a rise of exceptional magnitude. —43e: —144l ce aiel eae ene May 3, ,, +30 |-—43 | —20.) 482.) — 14] 4 | aa ee ee June 13)... ,, +27 | —50 | —21 | +32 | —14 / SA Ba Son) nd uly, 995.5 +93 | —54 | —21" | +30'| —18 "96 eae The pastes 52a, 53a, 54a were prepared with the same sample of Hg,SO, ; it was purchased and prepared in a similar manner to the sulphates dealt with in Table I. 546 was also a purchased sulphate. The remaining specimens were prepared by Divers’ method. It will be observed that all the pastes change so as to reduce the E.M.F. of the cell ; but whereas the E.M.F. of the cells prepared with purchased sulphates is greater than that of W 17, those made up with the Nordhausen sulphates have in each case lower E.M.F.s. Cell No. 526 is exceptional in the fall of its voltage. The difference in the prepared pastes, though small, condemns part of the method of preparation, and further investigation became necessary. The method of preparation adopted by Dr. Carpenter was at first repeated. Close observation showed that on formation the sulphate cakes considerably, and is accompanied at the surface of contact with the mercury by a compound of a light brick-red colour. If without freeing from the acid or SO, the product is added to distilled water, reduction of part of the sulphate apparently occurs, mercury is precipitated as a black powder, and the red compound entirely disappears. (The mercury thus precipitated is a valuable addition to the paste, the conversion of mercuric sulphate to the mercurous condition being rendered possible by its pre- sence.) The salt produced by freeing the first product from SO, also loses the brick-red tint, and is finally obtained as a pure white paste. On prolonged washing with water, however, hydrolysis results and the colour changes to pale yellow. Two samples of hydrolysed mercurous sulphate were thus prepared, the one being washed for one hour with water and the other for twenty-four hours. An experimental cell indicated that the more hydrolysed product if employed to set up a cadmium cell would cause the E.M.F. of that cell to be greater by 0-00064 volt than if pre- pared with the first sample. The presence of this hydrolysed product is therefore to be avoided, and washing by water prohibited. About this time, through the kindness of Professor Ayrton, the results of some experiments by Professor H. 8. Carhart and Mr. G. A. Hulett, of the University of Michigan, were communicated to the Laboratory. Professor Carhart has also sought a standard method of preparing the depolariser, and suggests that any prepared sulphate be washed with cadmium sulphate (or zinc sulphate for Clark cells) in order to prevent hydrolysis. Prior to this, Mr. Swinburne, in a letter to Dr. Glazebrook, suggested the precipitation of the sulphate intended for Clark cells from saturated solutions of mercurous nitrate and zinc sulphate, the washing to be effected with alcohol or saturated zine sul- phate solution. PRACTICAL STANDARDS FOR ELECTRICAL MEASUREMENTS. 57 Omitting the description of further experiments, the final mode of preparing the mercurous sulphate for standard cells is here given. Fuming sulphuric acid saturated with SO, (32 per cent. of SO; is a con- venient specification) is added to sufficient pure distilled mercury to ensure the latter being always in excess. The mercury should be contained in a clean glass vessel and violently agitated by a glass stirrer, so that the product may be in a fine state of division. After seven or eight hours the reaction will be sufficiently advanced for the sulphate to be separated from the acid, but if convenient the action may go on for some days. Care- fully pour off as much of the strong acid as possible into a large volume of water or into an empty vessel, and afterwards add the pasty product left to thirty or forty times its bulk of distilled water. Mercury is precipitated and a considerable quantity of heat is evolved owing to the dilution of the acid. A few minutes suftice for the sulphate to settle, when the acid liquid may be decanted and the salt well washed by agitation with acidulated water (1 part of conc. H,SO, to 10,000 parts of distilled water). Filtering follows, a filter pump being employed to effect exhaus- tion. It is advisable next to pound the damp sulphate thoroughly in an agate mortar to ensure the absence of small caked masses, after which acidulated water is again added, filtering effected, and the salt washed on the filter-paper with two or three lots of neutral saturated cadmium sulphate solution (or zinc sulphate solution for Clark cells). The salt is now removed to a small flask, saturated cadmium sulphate solution added, and the whole well shaken and then allowed to stand for twenty-four hours. Filtering follows, then three more washings with cadmium sulphate solution, removal to a flask once more with CdSO, solution, and at the end of twenty-four hours the solution should still be neutral to Congo red. If so, the sulphate may be filtered and is ready for the manufacture cf the paste. The whole of the operations should be conducted in a room screened from sunlight. As thus prepared the mixture of mercurous sulphate and mercury is of a dark grey colour. Cells set up with paste prepared from it require no ageing, and the constancy obtained with pastes made from materials obtained from different sources is an indica- tion of the purity of the salt. Table III. gives the results of comparisons between cadmium cells set up with pastes prepared in this way and cadmium cell W17. The latter in every case has the greater E.M.F. Differences are expressed ir hundredths of a millivolt. Taste III. ee Cell No. 66 Cell No, 67 Cell No. 68 a b c a b c a b c May 12,1904) -—24 -—26 —24 se ES ” 12, ” SOT tee 20. ee =— ee ee = — 20502 -_ a ” 16, ” ae —27 —'25 —28 —_ » 16, — aD ee ail a mE 16, SO P10 P10) Hot =21" =20 = June 13, ,, — = E99 29) 27 ” 13, ” v == — 23 —22 — 23 » 13, 4 oie 20a —o1ee |) o 20s 2009 = l= 20) ¢— 9 oly 6; v5, ,) —21 —21. —20 —19, —20 —19, | -—20 -—21 —20 STEELS) 035 —20, —20, —20 —20 -21 —20 = 20. —20) —1 Gr oe eee ne) 38 REPORT—1904. The first set of observations with each cell was made about five minutes after adding the solution ; the second set of observations about twenty minutes afterwards ; and the third set three hours afterwards. For the first two sets of observations the temperature of the four-limb cells was unsteady ; for the remaining observations they and W 17 were at the same steady temperature. Other cells of the Rayleigh H form have been constructed, and the comparisons are equally satisfactory. An alternative method of preparing the salt was next sought. This second method is very simple. Any purchased sample of mercurous sulphate is heated together with mercury and concentrated H,SO, on a water-bath for half an hour, the mixture being stirred occasionally. At the end of that time the remaining solid is allowed to settle and the hot clear acid carefully poured into a large volume of distilled water. Mercu- rous sulphate is soluble to a considerable extent in hot concentrated H,SO, ; the result of the dilution is, in consequence, to precipitate the salt. As thus produced the mercurous sulphate is in a finely divided state and of a pure white colour. It is well to at once admix with a little mercury and filter. The washing is performed as before. Portions of three purchased samples of Hg,SO, were dealt with in this way, and after treatment gave identical results with the cells dealt with in Table III. The three original samples prepared in the ordinary way produced cells differing in E.M.F. from the standard by 40, 160, and 10 hundredths of a millivolt. A third method devised by Professor Carhart does not necessitate the use of concentrated acid. In order to hasten the reaction between mercury and dilute sulphuric acid (one to six) an electric current is passed from the mercury to a sheet of platinum foil suspended in the liquid. It is essential that the liquid be kept well stirred so as to keep the mercury surface exposed. Professor Carhart has employed a beaker or crystallising dish to contain the liquids, and used a current of about 0-3 ampére ; the current density, however, is not stated. At Bushy House the salt so produced has been compared with those prepared by the two previous methods. Under ordinary circumstances about three grams of the salt—very grey owing to the presence of mercury in a fine state of division—is obtained per hour. The current density at Bushy House has been about ‘01 ampére. It was gratifying to find that the product (washed as before) gave identical results with the other methods. Very violent agitation was maintained during the preparation. When the liquid is not stirred a yellow compound (apparently turpeth mineral HgSO,.2Hg0) is also produced, and cells the pastes of which are prepared with the product have an E.M.F. when first set up more than a millivolt higher than the normal. Particular stress must therefore be laid on the instruction to keep the mercury surface well exposed. The same thing was found to happen when attempting to form mercurous sulphate by the electrolysis of a saturated cadmium sulphate solution in an ]{-form vessel, the electrodes being pure mercury. It will be observed that the remarks on the depolariser apply equally to Clark and to cadmium cells. Cadmium cells alone were made up in the final tests because of their small temperature coefficients ; but Clark cells have also been set up and similar results obtained. It is also neces- sary to add that all purchased samples of Hg,SO, are not so abnormal as those dealt with in Table I., nor does the E.M.F, of an abnormal cell always fall so rapidly as is indicated there. (The rate of fall is probably a PRACTICAL STANDARDS FOR ELECTRICAL MEASUREMENTS. 39 a function of the fineness of the sulphate.) Evidence of remarkably stable cells set up with purchased mercurous sulphate is afforded by six cadmium cells made at Bushy House in April 1902: these have been in constant use, and in the case of two of them have frequently been short-circuited through 100 ohms. One of these cells is taken as a standard in the com- parisons. By reference to a seventh cell made up in June 1904 witha paste made from sulphate identical with that employed for the previous ones it is thought probable that the whole six cells have fallen -07 milli- volt since their manufacture, Table IV. gives the result of the com- parisons. TABLE IV. Date of Observation | 16>17 16>18 | 16>19 16>20 | 16>21 May 5, 1902 : | “00000 “00000 ‘00000 ‘00000 ‘00000 Sep. 12, ,, A | + 1 0 + 1 0 Feb. 25, 1903 ag 0 0 0 0 0 Dec. 14, _ ,, A ae ee: 0; | — 0; 0 0 + 0; Feb. 6, 1904 0 0 | 0 | 0 | 0 July 9, ,, : oi a8 OF | + 0, | -- 1; | = 0; | 0 At the present time the E.M.F. of a cadmium cell set up with a paste made from fuming sulphuric acid and mercury is less than that of these cells by 0°21 millivolt. With respect to the other elements of standard cells it is proposed to. investigate the cadmium and zinc amalgams, and the solutions of the sulphates of these metals, in a manner very similar to that employed for the pastes. Much valuable information has fortunately accumulated respecting the influence of impurities in these, so that probably the task is a light one. Jt is interesting to note that neither of the amalgams should have its surface exposed to the atmosphere for any length of time ; it is preferably covered with water or a solution of the sulphate of the metal. This prevents oxidation. In addition to these investigations the effects of acidity and basicity are to be determined, together with observa- tions in connection with lag, polarisation, temperature coefficients, ce. Remarks on the Rayleigh H Form and the Board of Trade Tube Form of Standard Cells. In 1892 Dr. Kahle, in a paper read before the British Association at Edinburgh, described some researches made by him on the Clark cell. Comparisons of H cells set up by him with tube cells set up by Dr. Glaze- brook at Cambridge led to the assignment of an E.M.F. to the H cell, four ten-thousandths of a volt less than that of the Board of Trade form. This difference in value has been often quoted, and is at the present time accepted as a fact. In view of the discrepancies produced by the paste, together with theoretical considerations, it was thought desirable to investigate this difference if such should exist. For this purpose the H and tube forms of cell were combined. In addition to the usual ter- minals to the H cell, a zinc rod was inserted in the limb containing the paste, so that the arrangement of the elements in this limb was in accord- ance with the specification of the Board of Trade pattern. The sole difference in the elements of the H and tube cells was therefore the sub- stitution of the zinc rod for zinc amalgam. In some cases the zinc rod 40 REPORT— 1904. was amalgamated, in others it was merely cleaned, in no case did it touch the paste. With two cadmium cells set up similarly, a rod of cadmium amalgam contained in a glass tube perforated at a few points replaced the plain cadmium rod. Very steady temperatures were main- tained before taking observations. Table V. gives the results of comparisons of these Clark and cadmium cells. The standard adopted for the Clarks was cell No. 10, a standard more than two years old and fairly constant ; that for the cadmium cells was a third cell, No. 48, made up at the same time. Cells numbered E 10 and E 11 contained a different paste from that in C3,C7,C9. The differences between H and T are small and irregular, and probably explained by the non-uniformity of the surface of the zinc rods and slight differences in the concentration of the solution. The zine rods in E 10, E 11, C 3, and C7 were amalgamated ; that in C9 was cleaned only. TABLE V.—Differences in Hundredths of a Millivolt. Matenon Clark Cells Cadmium Cells Observation] — E 10 E11 C3 C7 | C5 49 | 47 July 5,°04-2 —8|+0 » 6,, |/+0 +2/4+3 SiS iiss We ek emer (429) 759i) ase ea ma ie 9 (tt —6l+2 O46 4-2i)498 $1947 a= qa2) eroleemeeal Means |+1 -4 +2 -2,4+4 -—0,+9 +3 |+8 47 |4+2 ais “Fil The observations show that no such difference as 0-0004 volt exists between the two forms ; the difference found in 1892 is to be attributed to other causes, probably the pastes employed. APPENDIX II. On the Electromotive Force of a Clark Cell. By A. P. Trorrer. A determination of the electromotive force of the Clark cell (Wolff’s large pattern) in terms of the ampére and ohm, has been made recently at the Board of Trade Electrical Standards Laboratory. The ampére, as measured by the Standard Ampére Balance of the Board of Trade, was passed with suitable precautions through a manganin coil having a resistance of 1:4343, ohm at 15°-0 C., and the difference of potential between the ends of this coil was compared with that of the Clark cell upon a low-resistance potentiometer. After necessary corrections the electromotive force of the Clark cell was found to be 1:4329 volts at 15°0 C. The temperature of the Clark cell was read by a thermometer in an oil bath in which the cell was placed, estimating to 0°-01 C. The cell had been kept for several months in a constant-temperature room and had not varied in temperature by more than 0°-05 ©, for forty-eight hours before the comparisons. ON SEISMOLOGICAL INVESTIGATIONS. 41 4 Seismological Investigations.—Ninth Report of the Committee, consist- ing of Professor J. W. Jupp (Chairman), Mr. J. MILNE (Secretary), Lord Krzv1, Professor T. G. Bonney, Mr. C. V. Boys, Professor G. H. Darwin, Mr. Horace Darwin, Major L. Darwiy, Professor J. A. Ewine, Dr. R. T. Guazesroox, Mr. M. H. Gray, Professor C. G. Knort, Professor R. Metpota, Mr. R. D, OLDHAM, Professor J. Perry, Mr. W. #. Piummer, Professor J. H. Poyntine, Mr. CLement Ret, Mr. Netson Ricnarpson, and Professor H. H. Turner. (Drawn up by the Secretary.) [Puates I. AnD II.] CONTENTS. PAGE I. General Notes on Stations and Registers _. ; : 4 : : . 41 Il. Comparison of Records from three Milne Horizontal Pen dulums . - Aa Ill. An Improved Record Recewer : : : - : : 0 . 43 IV. The Origins of Large Earthquakes in 1903. - : é , ; . 43 V. On International Co-operation for Seismological Work : : : . 45 VI. Seismological Work now in progress . : : : - : . 46 VIL. Directions in which Seismological Work may be extended . : : . 48 . 5 51 VIII. Experiment at the Ridgenay Fault I. General Notes on Stations and Registers. Durine the past year the registers issued are Circulars Nos. 8 and 9. These refer to Shide, Kew, Bidston, Edinburgh, Paisley, Toronto, Vic- toria, B.C. ; Baltimore, San Fernando, Cairo, Ponta Delgada, Cape of Good Hope, Alipore, Bombay, Kodaikanal, Batavia, Irkutsk, Perth, Mauritius, Trinidad, Tiflis, Christchurch, Wellington, Cordova, and Tokyo. Captain H. G. Lyons, R.E., Director-General of the Survey Department at Cairo, writes that the Abbassia records terminated on December 23, 1903. On the same day they were recommenced at Helwan, long. E. 31° 21’, lat. 29° 52’. At Abbassia, in the delta, the foundations were on sand, and during wet weather may have been disturbed. At Helwan the instrument stands on a limestone pier founded on solid rock. It is anticipated that an instrument will shortly be installed at Malta. The multiplication in the number of stations, scattered as they are all over the globe, has led to a great increase in the work of correspondence and reduction which has to be undertaken at Shide. Much of this work might well be done by an assistant under the supervision of the Secretary, leaving the latter more free to devote himself to scientific problems. The Committee consider that the time has arrived when a fund should be established to provide a sufficient income for securing the continuity of the work in the future. Upon such a fund the salary of an assistant would be a principal charge. The Committee are happy to be able to report that Mr. M. H. Gray has very generously given the sum of 1,000/. to serve as the nucleus of such a fund, while the Committee on Geophysics of the Carnegie Institution of Washington have also expressed a desire to contribute to the important work which is being carried on at Shide. The Committee are in correspondence with the Executive Committee of the Carnegie Institution, and they trust that donors will come forward to assist in putting the work upon a permanent basis. Tt may here be mentioned that Mr. M. H. Gray has already given 42 REPORT—1904. material support to the station of Shide ; his brother, Mr. R. K. Gray, provided the instrument for San Fernando ; Mr. Joseph Wharton, of Philadelphia, U.S.A., gave the instrument installed at Strathmore Qol- lege, near that city ; ‘pendulum apparatus was given to Shide by Mr. A. F. Yarrow ; the instruments in Hawaii, Victoria, and Mauritius were paid for, or partially paid for, by funds put at the disposal of your Secre- tary ; while the remaining installations were established by institutions or Governments in the countries where they are now working. II. On the Comparison of Records from three Milne Horizontal Pendulums at Shide. These pendulums and their installations referred to in the following note are described in the British Association Reports, 1902, p. 60, and 1903, p. 81. Pendulum A is the type instrument, and carries a load of 243 gms. It stands on its own pier, records E.W. motion, and its period, like similar instruments in other parts of the world, has been kept at about seventeen seconds. Pendulums B and C stand on the same pier and swing on the same cast-iron upright. JB is parallel to A, and, like it, records E.W. motion. C responds to N.S. motion, but by means of an arm attached to it, similar to the arrangement shown in the British Association Reports for 1902, p. 61, fig. 1, its records are made side by side with those of B. At intervals of several months the loads carried by B and C have been purposely varied, and the object of this note is to show the differences in the results obtained in consequence of such changes. In considering these differences two points not to be overlooked are, first, that only the move- ments of A and B are comparable ; and secondly, that the swinging of B might.cause motion in C, and wice versa. The comparisons given in the following table refer to the number of records given during different periods by A, B, and C, and the number of | —--- | Number of Records Number of Early Commencements December 28, 1902, to April 28, 1903 | A B C A B Cc fe Deslas W. 243 grms. 5 = = TB, pelt, We2os - 5, : ; 35 35 31 15 12 15 |G, p. 20, W. 155, J ate ‘ April 28 to December 6, 1903 A, p. 17, W. 243 grms. . - | = = iB; pili We23t 4 5; : : “29 40 50 9 12 47 ” C, p. 20, W. 404 ae be December 8, 1903, to May 2, 1904 | (A, p. 17, W. 243 grms. _,, | 22 40 al 8 foeee poo ese 2 | C, p. 20, W. 404, ; i a | 27 [le times each of these pendulums commenced to record either sooner than the others or at least simultaneously with one of the others. P=period in seconds, and W=load carried by the booms expressed in grammes, ON SEISMOLOGICAL INVESTIGATIONS. AS During the first period the records accord fairly well with what might be expected, the small moment of C accounting for the small number of its records. In the second period, when the load on C was increased threefold, we find that it gives the largest number of records and the largest number of early commencements. The large increase in the records on B may be due to the influence of C swinging on the same support. In the last period, when B carried a load practically equal to that on C, and had its time of swing increased to thirty seconds, we see that it gave the greatest number of records and also most frequently was disturbed before the others. Although these records are not strictly comparable, and for the most part only refer to mere thickenings of the photographic trace, they suggest that an increase in load and of period in the type instruments would result in increased sensibility. Ill. Improved Record Receiver for Horizontal Pendulum Seismograph. The accompanying illustrations, figs. 1 and 2, show two views of a new seismograph recorder. The instrument consists of a light brass cylinder, D, 1 metre in circum- ference and 160 millimetres wide, mounted upon a steel spindle. One of the projecting ends of this spindle has a deep-threaded helix of 6 millimetres pitch cut in it ; this being suitably mounted upon roller bearings, advances the cylinder 6 millimetres for one turn in four hours, by a gear connection with a clock. The bromide paper carried on the cylinder is changed every 3°5 or 4 days. A cylindrical mirror has been introduced to give a greater concentra- tion of the light on to the boom-plate. For the time record mark upon the bromide paper a shutter actuated by an electro-magnet is employed, the light being shut off from seven to ten seconds every hour. For this purpose a regulating clock with suitable electric contacts is required. An example of records from the new and old form of receiver is shown in Plate I. The advantages of the new arrangement are :— 1, Although the paper moves beneath the end of the boom at more than four times the rate (250 millimetres per hour) that it does in the original receiver, only one-half the quantity of paper is used. This implies a large reduction in expense for paper and developer, the latter being applied by a brush. 2. An open diagram is obtained on which wave-periods can be measured. 3. Movements of small amplitude are easily recognised. 4, Records can be quickly inspected and are easily stored. IV. The Origins of Large Earthquakes recorded in 1903 and since 1899. The origins of the large earthquakes recorded in 1903 are indicated by this Shide register number upon the accompanying map, Plate II. In the registers (Circulars 8 and 9) there are 135 entries for this year, whilst on the map only sixty-four origins are indicated, which means that there were about seventy-one earthquakes the materials relating to which were insuf- ficient to enable their origins to be determined. Even with the origins which have been determined, the notes of interrogation attached to 44 REPORT— 1904. numbers on the map indicate that such determinations are accompanied by uncertainty. Speaking generally, it may be inferred that about 50 per cent. of the Fies. 1 AND 2. Milne’s Horizontal Pendulum (seismograph) with new L sray recording arrangement, BRASS RAILS | 6 FEET 3 SCALE ‘ ; 2 2 METRES. 2 large earthquakes have disturbed the world’s surface as a whole, whilst the remainder have only affected areas equal to those of single continents. The greatest activity is again along the Libbey Circle (radius 70° and centre 180° E. or W. long., and 60° N. lat.). Marked activity has taken place at the junction of regions E. and F., and in the eastern por- ON SEISMOLOGICAL INVESTIGATIONS. 45 tion of the E., both of which may be described as regions in which there are intersections of tectonic folds. Maps corresponding to the one here given can be found in the British Association Reports for 1900, 1902, and 1903. V. On International Co-operation for Seismological Research. In 1902 the British Government received an official invitation from Germany to take part in a Conference the object of which was to esta- blish an international inquiry about earthquakes. Acting under the advice of a Committee appointed by the Royal Society, the Board of Education appointed Professors G. H. Darwin and J. Milne to represent Great Britain at the proposed Congress, which took place in Strassburg July 23 to 28,1903. Twenty-five States or countries were represented, but the total number of delegates and guests who were at liberty to take part in the proceedings was 100, out of which sixty-two were Germans. Final results were arrived at by single voices, each country having one vote ; thus Great Britain and her colonies, like the German Empire, had each one vote only. France was not oflicially represented. The more important results arrived at were as follows :— A Central Association is to be formed with its headquarters in Strass- burg. Each contributing country will be represented by one member of a governing Committee, which elects a President, a Chief for the Central Office, and a General Secretary. The Chief will reside in Strassburg, but it was decided that the President and Secretary should be elected from outside Germany. The work of the Association would be as follows :— 1. To carry out observations after a common plan. 2. To carry out experiments on important matters. 3. To establish and support observatories. 4. To collect, study, and publish reports or réswmés of the same. The cost of this work, including a Secretary’s salary, is to be for the first twelve years about 1,000/. per annum, twelve years being the dura- tion of the Convention. The contributions to make up this sum are to be apportioned amongst the co-operating States according to their population, the British contribution to be 160/. per year. Should Great Britain join the Convention, as it will be necessary to send a representative to the Governing Committee, the total annual outlay will be about 2004. Whilst at Strassburg the British delegates explained that they were in no way empowered to pledge his Majesty’s Government, and that they had been informed that their Government would not take action that had not the support of the International Association of Academics. At the last meeting of this Association, held in London May 24 to 30, 1904, the advisability of international co-operation for purposes of seismological research was discussed, with the result that it has been referred for further consideration to the following Committee : Professors A. Schuster (Chairman), Helmert, de Lapparent, Mojsisovics, Agamennone, Karpinski, and T, C. Mendenhall. The Foreign Office and the Board of Education have been informed of this action. 46 REPORT—1904. On April 21, 1904, the Seismological Committee of the Royal Society reported to the Council of that body as follows :— (1) That this Committee is of opinion that any moderate subsidy likely to be available would be most profitably expended in support- ing the seismological work inaugurated by the British Association, and that there is urgent need of such help, which should be a first call on any such funds. (2) Assuming this need supplied, the Committee would approve the further co-ordination of the work by joining the proposed Association. VI. Notes upon Seismological Work in various Countries. 1, Austria. With the object of recording earthquakes with a local origin, Austria is divided into sixteen districts, each with many observers. ‘Their notes, which are for the most part made without the aid of special instruments, are collected at a local centre. From 120 to 200 disturbances are noted annually, and the registers are published separately or collectively by the K. Akademie der Wissenschaften in Wien. At Trieste, Laibach, Kremsmunster, Lemberg, and Pribram there are instruments to record earthquakes with a distant origin. Four of these stations have received State subventions. The registers are published in series with the above. An important publication issued by Dr. A. Belar, of Laibach, is ‘ Die Erdbebenwarte.’ In it we find articles relating to seismological investiga- tions, notes relating to such work in general, and a catalogue of the Laibach observations. 2. Belgium. Station Géophysique d’Uccle. Registers relating to earthquakes with distant origins are published every three months. 3. Germany. Strassburg issues a monthly register of earthquakes with distant origins with corresponding notes from a few foreign stations, together with a list of a few earthquakes which have been felt in various parts of the world. It is supported by the State. Hamburg issues a list similar to that issued by Strassburg, but more complete. The station was started as a private enterprise by Dr. R. Schutt, but its founder has presented the same to the city authorities. Gottingen issues a register relating to the observations made at the University. Teleseismic observations are also made at Jenaand Potsdam. It is proposed to establish thirty-four more stations within the German Empire. 4. Great Britain. A Committee of the British Association enjoys the co-operation of thirty-nine stations, which are fairly evenly distributed over the world. Each station is provided with similar apparatus intended for a particular class of teleseismic observation. The registers from these stations are published every six months, to which is added once a year a short report. These publications are distributed to the co-operating stations and to those who desire them. Support is obtained fromthe British Association, from the Royal Society, and private sources. —“— = tl a te ee ll ee re a ON SEISMOLOGICAL INVESTIGATIONS. 47 5. Greece, D. Eginitis has published a catalogue of local disturbances, 1893-1898. 6. Holland. The Magnetic and Meteorological Department in Batavia observes and publishes records relating to earthquakes of local and distant origin. Supported by the State. 7. Hungary. Earthquakes are observed by a system similar to that adopted by Austria, At Buda Pest, Agram, O’Gylla, Fiume, and at a few other stations, instruments have been installed to record earthquakes with a distant origin. 8. Italy. In Italy there are about 800 stations at which earthquakes are observed. Out of these there are fifteen first-class observatories provided with apparatus to record teleseisms and local shocks, and 150 second-class stations using seismoscopes. Since 1879 these have been under State control. The registers are published by the Central Meteorological Office in Rome, and to these are added corresponding records from nearly all the teleseismic stations of the world. This catalogue therefore practically contains the information relating to teleseisms contuined in registers issued by all other nations. A few observatories, as, for example, those at Padua and Florence, also publish their records separately. 9, Japan. Japan has at least five stations for teleseismic observations, and about eighty provided with instruments for recording local shocks. Records of these latter are made at over 1,000 centres, and as from 1,000 to 2,000 earthquakes are recorded annually, and as each of these may be noted at many centres, the number of manuscripts accumulating at the Central Observatory in Tokyo is very great. Accounts of the more important shocks are published in the ‘ Official Gazette ’ and in other newspapers. A catalogue of 8,331 shocks (1885-1892) was published in the ‘Seismological Journal,’ and a similar but more extensive catalogue is now in progress. The Earthquake Investigation Committee issue many publications relating to seismology, while papers on the same appear in the Tokyo Physico-Mathematical Society. Very many of the publications are in Chinese characters. At the University there is a Professor and an Assistant Professor of Seismology. Practically all work is supported by the Government, the Investigation Committee alone receiving 1,000. to 5,000/. a year. 10. Norway. Tn connection with the Museum in Bergen Dr. Kolderup is issuing an annual list of earthquakes felt in Norway. ll. Roumania. The ‘ Institut Météorologique de Roumanie’ issues occasional sheets relating to teleseisms. . 48 REPORT—1904. 12. Russia. In Russia and Siberia there are seven stations of the first order at which teleseismic and other shocks are recorded, and ten or twelve stations of the second order. ‘Teleseismic records and special papers are published by the ‘Commission Centrale Sismique Permanente.’ Some of the stations, like Tiflis, Taschkent, and Irkutsk, also publish their records separately. 13. Servia. Servia has a station in Belgrade. 14. Switzerland. 2 7 i } «© © © _ = In 1880 F. A. Forrel and Heim arranged an organisation to collect records relating to shocks originating in Switzerland. These are published by the Meteorological Bureau. 15. United States of North America. The Department of the Interior, in the monthly bulletin of the Philippine Weather Bureau, publish a list of teleseisms recorded in Manila, anda list of earthquakes recorded in the Philippines. In California there are about twenty stations furnished with apparatus to record local disturbances. Lists are published in the Bulletin of the U.S. Geological Survey. VIL. Directions in which Seismological Work may be extended. From the preceding section it may be inferred that at the present time there are about eighty stations at which teleseismic disturbances are recorded, and that nearly half of these are in Central Europe. To obtain a fairly even distribution of stations over the surface of the world about twenty-three more places of observation are required. A possible distribution for these is as follows :— Alaska, 1; U.S.A., Central Canada, Newfoundland, and Central America, 7 ; South America, 3 ; Iceland, 1; N. Norway, 1; Africa and Aden, 3 ; China, 2 ; the East Indies and the South Pacific, 5. A more immediate requirement is, however, the establishment in and near to districts from which world-shaking earthquakes originate of sets of ordinary seismographs, together with the co-operation of observers provided with good time-keepers, or even fairly good watches. In dis- tricts remote from telegraphs or observatories these may be rated by sun observations. A simple method of making such an observation sometimes employed at Shide and Cassamiccola is as follows. In a brick wall facing south a hole has been made which on the outside is covered by two pieces of sheet iron brought together to leave a vertical slit about 5 mm (; in.) in width and 40 cm. (16 in.) in height. The sun passing before this slit throws an image of the same upon the opposite wall 14 feet dis- tant. On this wall opposite the slit and in a north-south plane with the same there is a vertical line. When the image reaches this, the sun is due south at an observed time. To the time when this occurs the equation of time is added or subtracted and local mean noon is obtained within about one second. The object of these time observations, which may be made quite well with an ordinary watch, is to obtain the time of arrival of earth move- ment at various points round an epicentre, from which may be calculated SE ———————- ON SEISMOLOGICAL INVESTIGATIONS, 49 the positions of foci of world-shaking earthquakes, not alone from the initial disturbanve, but also from ‘after shocks,’ which latter seldom reach distant places. When we know these foci, local observations enable us to make close approximation to the times at which large earthquakes have originated ; and when this is done our knowledge of the rates at which motion has been propagated in various directions through and round the world will become more reliable. The districts where such observations are required are indicated on the map, Plate IT. District E (Japan) is already well supplied with seismographs. Dis- tricts requiring similar installations are: A (Alaska), Band C (Central America and the West Indies), and K (Caucasian Himalayan district). In each of these at least six seismographs and the means of obtaining good time are needed. Other lines upon which geophysical and seismological research might be conducted, but which have hitherto received but small attention, are numerous. Our knowledge of earthquake movement as recorded under- ground as compared with that noted upon the surface requires extension. As far as we can learn from the excellent work inaugurated in the Adalbert Shaft at Pribram by Dr. Edmund V. Mojsisovics, it would appear that the movement, at a depth of 1,115 m., is for worid-shaking disturbances practically identical with that noted on the surface, from which it may be inferred that for this class of earthquake the large waves are not a mere superficial disturbance of the earth’s crust. Whether suboceanic disturbances are accompanied by molar displace- ments and large changes in suboceanic configuration remains to be determined by soundings the results of which should be of value to the hydrographer. The fact that at certain observatories unfelt teleseismic movements are accompanied by perturbations of magnetic needles, which disturbances remain without satisfactory explanation, suggests that if such irregular per- turbations are due to the influence of local subjacent magnetic magmas, in such localities not only should magnetic intensity be abnormal, but also that the differences between the observed and calculated values for gravity should be unusual. What are the relationships between seismic and volcanic activities ? and, further, what are the relationships between such phenomena, changes of level, magnetic elements, and the value for gravity ? are also questions the answers to which are at present largely based upon hypotheses. The movements on fault lines which accompany earthquake disturb- ances require an extended investigation, while the relationship which appears to exist between the dip and strike of rock folds and earthquake movement is a subject that has received but little attention. Much has already been done to establish a relationship between earthquake frequency and certain astronomical phenomena ; but fields for investigation, as, for example, the connection between movements of the earth’s crust and the wanderings of the pole, have yet to be exploited. Again, as bearing upon earthquake occurrence, secular movements of the earth’s crust, as, for example, those which are evidenced by changes in water level, alterations in the lengths of base lines and levels, the increase or decrease in the water-holding capacity of certain basins, have yet to be subjected to extended and careful measurements. 1904. E 50 REPORT—1904. The harmonisation of results obtained from seismometry relating to the probable nature of the interior of the world with the requirements of astronomy, geodesy, the revelations of the plumb-line and the thermometer, together with various branches of physical, chemical, and geological research, constitute inquiries of profound interest. Surface warpings of the earth’s crust due to lunar or tidal influence or the variations in load which accompany changes in meteorological condi- tions may not only have a bearing upon earthquake frequency, but also may throw light upon the variations in flow and the rise and fall of subterranean waters, the escape of gases, and even perhaps assist the meteorologist in his forecasts of the weather. As illustrative of the practical outcome of seismological investigation the following may be mentioned :— From observations on the destructive effects of earthquakes, the knowledge obtained respecting the actual nature of earthquake motion, and from experiments made upon brick and other structures, new rules and formule for the use of engineers and builders have been established. In Japan and other countries these have been extensively applied in the construction of piers for bridges, tall chimneys, walls, ordinary dwellings, embankments, reservoirs, &c. Inasmuch as the new types of structures have withstood violent earth-shakings, whilst ordinary types in the neighbourhood have failed, it may be inferred that much has already been accomplished to minimise the loss of life and property. These investiga- tions have yet to be extended. The application of seismometry to the working of railways, particularly in Japan, has Jed to the localisation of faults on lines and alterations in the balancing of locomotives. The result of the latter has been to decrease the consumption of fuel. Records of the unfelt movements of earthquakes indicate the time, the position, and, what is of more importance, also the cause of certain cable interruptions. The practical importance of this latter information, especially to communities who may by cable failures be suddenly isolated from the rest of the world, is evident. The many occasions that earth- quake records have furnished definite information respecting disasters which have taken place in distant countries, correcting and extending telegraphic reports relating to the same, is another indication of the practical utility of seismic observations. Seismograms have frequently apprised us of sea waves and violent earthquakes in districts from which it is impossible to receive telegrams, whilst the absence of such records has frequently indicated that information in newspapers has been without foundation, or at least exaggerated. The localisation of the origins of world-shaking earthquakes, besides indicating suboceanic sites of geological activity, have indicated positions where the hydrographer may expect to find unusual depths. They have also shown routes to be avoided by those who lay cables. In addition to the above, a great proportion of which relates to what may be called the field work of seismology, there are many subjects bear- ing upon the same science which remain to be investigated within the walls of a laboratory ; and as it seldom happens that any one research fails to suggest new departures, the work of to-day implies new and extended investigations in the future. fee une 27 Gam. British Association, 74th Report, Cambridge 1904.) [Plate I. 1904 June27 6am ro erivvnnmriuivevrl il fied 2 4364 2 Earthquake June 26-27 N° 863 7 Deflection due im Period of Pendulum 15-55 to 2°turn of screw it} y 6 —————— Sie June 26 2am ] D aT s> i \ ANU wear nnnnneovnnn ARN YArnwrrAYYY enna} fa _/8 660 Earthquake June 25/904 _ Shide /W. 252 mm =! hour. 10 & June 25 23m 22 => Periods of movement — ‘15.55 > i | 18 2) ge CNN ee ca 60mm =/hour —________—o-9 =a fff Ih sf. ———< $< $$ 860 Earthquakes June 25 1904 Illustrating the Report on Seismological Investigation. Vambridge 1904.] [Plate II. by their B.A. Shide Registyuakes which since 1899 have originated als. ~ Baltimore 5 be British Association, 74th Report, Cambridge 1904.) Origins for 1908 are indicated by thelr BA. Shide Rogister number. from these is expressed in large numerals, Observing stations are named. The Large Earthquakes of 1908. [Plate It Earthquake districts are indicated A, B, C, &c., and the namber of earthquakes which since 1899 have originated SS 70 rm So u | | MD | 4 AS i Sy | 2 R ° 0 Bz Sante: p | | a Hf) erp A] / ) Norie 768?) a 77071 bY Cepricer { Fg Nees Kope Town & THE WORLD —---+-~-. ON ! MERCATORS PROJECTION. | is L2 |. Aatacent Ciccle__| + $e pd = 0 leagitede 90 Weal 1 70 728 "Jo Weridinn of O Greenwich wt —— Illustrating the Report on Seismological Investigation, ON SEISMOLOGICAL INVESTIGATIONS. bil VIII. The Experiment at the Ridgeway Fault. : Mr. Horace Darwin informs the Committee that he visited Upway in March last, when he took out most of the apparatus and put new in its place. This seems to be working well, and if it continues to do so _he hopes to furnish a detailed report on the relative movements of the _ two sides of the fault next year. Underground Temperature.—Twenty-third Report of the Committee, consisting of Professor J. D. Everett (Chairman and Secretary), Lord Kenvin, Sir ARCHIBALD GEIKIE, Professors Hpwarp HULL, A. S. Herscne., and G. A. Lesour, Messrs. A. B. WYNNE, W. GatLoway, JoserH Dickinson, G. F. Deacon, E. WETHERED, and A. Straan, Professors Micuiz Smita and H. L. CALLENDAR, Mr. B. H. Brouas, and Professor Harotp B. Dixon, appointed for the purpose of investigating the Rate of Increase of Underground Temperature downwards in various Localities of Dry Land and under Water. (Drawn up by the Secretary.) In response to a pressing request from the Secretary for further informa- tion respecting the Calumet and Hecla mine, Professor Agassiz, in the spring of 1903, had all the observations (covering a period of ten years) tabulated and sent with sketches to Professor T. C. Chamberlin, head of the Geological Department of the University of Chicago, who undertook tosuperintend their examination. In February 1904 Professor Chamberlin wrote the Secretary to the effect that he had only been able to prepare a preliminary report of a tentative kind, and that the material must have ‘more critical study before going into print. Subsequent information unofficially communicated renders it probable that the rate deduced will be between 1° in 120 feet and 1° in 130 feet. _ The report of the Australian Association for the Advancement of Science for 1902 contains, at p. 309, an account, by Henry C. Jenkins (Government Metallurgist, Victoria), of observations of underground temperature in deep gold mines. _ At the North Garden Gully mine, Bendigo, 99°-1 was found at 3,000 feet ; and at New Chum Railway mine, Bendigo, 107°-0 was found at 3,645 feet. The mean surface temperature inferred from observations at 182 feet and 247 feet in neighbouring shallow shafts is 61°-4; which gives the rate as 1° F. for 80 feet at both these mines. Electric-resistance platinum thermometers were used. Also slow- acting thermometers in which fine flannel is wrapped three times round the bulb, and the thermometer, with cork supports, then inclosed in a sealed glass tube. A nearly identical rate was obtained in some preliminary observations _ which were taken in less favourable circumstances in a 1,700-foot heading at South German mine, Maldon, and at the depth of 2,080 feet in the Band and Albion mine, Ballarat. The rate 1° in 80 feet is exactly the same as that found by Professor David in a bore, 2,733 feet deep, near Port Jackson.! A shaft 1,000 metres deep, recently sunk at the collieries of Ronchamp _ (Haute Saéne) in East France, is described in a series of four articles, by ! See Report for 1895. B2 52 REPORT—1904. Mons. L. Possigue, in the ‘ Bulletin de la Société de l’Industrie Minérale’ for 1903. The first 764 metres belong to the New Red Sandstone series, including Lias and Permian. The remainder include 112 m. of Upper Coal Measures, 66 m. of Lower Coal Measures, and 68 m. of Schists. The following rock temperatures were observed during the sinking :— Depth Temp. C. Depth Temp. C. Depth Temp. C. M. o | M. 2 M. 2 10 10°5 830 39°6 930 44°6 300 21:0 850 10°7 950 45:2 400 24:5 860 41:0 960 45°5 600. 31°1 870 41°5 970 45-7 700 34:2 890 42-9 990 46°4 750 36°8 900 43°5 1000 46°8 800 38°3 910 43°8 1009 47-4 The shallowest, compared with the deepest, gives an increase of 36°:9 C. in 999 m., which is at the rate of 1° C. in 27:1 m.,, or 1° F. in 49-4 feet. When the observations are plotted they show nearly a straight line from 10 m. to 600 m., its gradient being 1° C. in 28-6 m. (1° F. in 52 feet), and the remaining portion from 600 m. to 1,009 m. oscillates about a line whose gradient is 1° C. in 25-1 m. (1° F. in 46 feet). Regular observations of temperature have been taken in the Simplon Tunnel, of which only about half a kilometre remains to be pierced. On its completion Mr. Francis Fox promises a full account of the tempera- tures, which will probably be communicated to one of the London societies before the end of the present year. A large body of evidence on temperatures in deep coal mines is con- tained in the report recently published by the Royal Commission on Coal Supplies. The chief element of uncertainty in discussing the observa- tions is the mean surface temperature, which has in most cases not been directly observed, and is doubtful to the extent of 1° or more. The following list of well-determined mean surface temperatures (chiefly from the publications of the Royal Meteorological Society) seems to constitute the best material for forming a judgment. They are for . moderate elevations, except where otherwise stated :— Camden Square, London : : : : é > AGS? Bolton . : ~ : : . - 49P2 North Thoresby (Line.) , ; ‘ : . ‘ . G49P2: Rounton (North Yorks.) z . ¥ » AFP 3: Ashton-under-Lyne (elevation 405 feet) - : -, £OaD At Pendleton, near Manchester, Mr. H. Bramall took observations in the Rams mine and in the Agecroft Colliery. The deepest observation was at 3483 feet from the surface in the Rams mine, the temperature found being 100°, as shown by a thermometer left for three hours in a hole bored 35 feet into the rock and covered with a piece of cotton waste. Assuming a surface temperature 47°, we have an increase of 53° in 3,483 feet, a: 1° in 66 feet. If we take the surface temperature as 48°, it is 1° in 67 teet. At Agecroft Colliery the deepest observation was 92°°5 at 2,940 feet ; which with an assumed surface temperature 47°°5 gives 1° in 65 feet. The above-named temperature in the Rams mine was checked by ON UNDERGROUND TEMPERATURE. 53 Professor Harold Dixon in October 1902 with a slow-acting thermo- meter made by Negretti & Zambra and tested at Kew inserted in a hole 4 feet deep in the floor at the lowest point reached. The reading obtained was 100°-6, which confirms the deduction of 1° in 66 feet. In the North Staffordshire coalfieddd Mr. W. N. Atkinson, H.M. Inspector of Mines, found the following temperatures at the greatest depths reached :— Sueyd Colliery, Burslem . : . 87°5 at 2,625 feet. Glebe Colliery . ; : . We COne ta a neeO as Great Fenton Colliery F 3 , Sb Or? yy, © 2400), ©; Assuming 48° as the surface temperature, the mean rates of increase downwards are :—- Sneyd , é : ‘ : : . 1° in 66°5 feet. Glebe 2 : : : : ; fe Odie LOOT Let yyg Great Fenton . a 2 : ‘ gee eS GEO)» ce The method of observation was to drill a hole, insert a bottle of water, and, after leaving it in the hole, plugged with clay, for twenty-four hours or more, take it out, and put a thermometer into the water in the bottle. In the Sneyd Colliery observations were thus taken at thirteen depths during the sinking of a shaft, beginning with 1,104 feet and ending with 2,625 feet, and the increase shown was fairly regular. The Glebe and Great Fenton observations were also in sinking shafts. At Hamstead Colliery in South Staffordshire Mr. F. G. Meachem made observations extending over several years. He found the mean annual surface temperature to be about 49°, and the temperature of the undisturbed strata at the bottom, 1,950 feet deep, 66°. This last was ascertained by inserting a maximum and minimum thermometer, pro- tected by a metal case, into a bore-hole driven ten feet into freshly cut coal. The hole was closed with clay and left for various periods from one to fourteen days. Repeated observations gave the same result. The rate of interest hence deduced is 1° in 115 feet. A surface temperature of 48° would give 1° in 108 feet. Mr. Meachem himself says: ‘All observations show an increase of temperature in undisturbed strata of 1° F. for every 110 feet of descent beyond 65 feet from the surface.’ ! Mr. W. N. Atkinson ? obtained a nearly identical rate at a new shaft at Baggeridge Wood, 8. Staffs ; but the circumstances were unfavourable, the shaft being wet, and the observations not made till about a week after the sinking was finished. The temperature thus found was 664° ata depth of 1841 feet. Assuming a surface temperature 48}°, this is an increase of 1° in 102 feet. The Secretary has made inquiries to ascertain whether these very slow increases in South Staffordshire can be due to steep inclination. He learms from Mr. W. N. Atkinson that the strata in South Staffordshire generally are very flat and nearly level. At Hamstead the inclination averages only one in 55 (or, according to Mr. Meachem, | in 19). In North Staffordshire, on the other hand, the strata are much contorted, and the inclinations at Glebe, Great Fenton, and Sneyd range from 1 in 10 tol in 5. The suggested explanation of the difference therefore completely breaks down. ’ Trans. Inst. Min. Eng., vol. xxv. 1903, p. 271. ? Q. 2295 in Report of Commission. 5A REPORT—1904. In South Wales, in the neighbourhood of Rhondda and Aberdare, Mr. William Jenkins has taken numerous observations by a somewhat rough method, an ordinary thermometer being inserted in a hole bored 3 feet deep into the coal, with an oiled waste plugging, and taken out from time to time and reinserted till the temperature was steady, the whole time being upwards of an hour. The observations were made in various seams at depths below the surface ranging from 1,094 feet to 2,515 feet, with very varying results, the surface being 875 feet above sea-level. Taking the surface temperature as 47°, and comparing it with the deepest observation (735° at 2,515 feet), we have an increase of 264° in 2,515 feet, which is at the rate of 1° in 95 feet ; but the mode of observation is unsatisfactory. At Dowlais, in the Merthyr coalfield, Mr. H. W. Martin has taken numerous observations in several collieries by means of thermometers inserted in boreholes and left for about twenty-four hours, the instruments being apparently strong thermometers specially ordered from a local optician. The greatest depth below the surface was 2,600 feet, with temperature 77°. Assuming the surface temperature to be 49°, this gives a rate of 1° in 93 feet. The inclination of the strata averages about 1 in 7. At the Niddrie Collieries, near Edinburgh, Mr. Robert Martin has made observations in the Great Seam at the depth of 2,623 feet, and finds the ‘temperature in the solid coal face’ at this depth to be 74°. The surface ground temperatures found at four surrounding stations of the Scottish Meteorological Society (Joppa, Nookton, East Linton, Smeaton) are 46°1, 47°°6, 47°°7, 47°-9. Assuming a surface temperature of 47°°5, we have an increase at the rate of 1° in 99 feet. The strata are highly inclined, the dip ranging from 50° to 90° ; a circumstance conducive to a slow rate of increase. Hofrat Prof. H. Hofer, of Leoben, Austria, has recently issued, with the sanction of the Austrian mining authorities, a circular giving direc- tions for the taking of temperature observations during the sinking of mining shafts, and has since been furnished, at his own request, with copies of most of the reports of your Committee. The circular recom- mends the use of maximum thermometers, divided to fifths of a degree centigrade, to be inserted in holes bored to the depth of at least 2 metres in the floor or side and well plugged. The observations are to begin at 25m. from the surface, to be repeated at intervals of 50 m. till a coal seam is approached, and then at shorter intervals through and a little beyond the seam. This process is to be repeated for every seam that is traversed. A main purpose of the investigation! is to determine the influence of coal seams on the temperature of their surroundings. Hot springs have been encountered in several Austrian coal mines, and Pro- fessor Hofer ascribes their heat to chemical changes in the coal. In this connection it may be mentioned that much evidence has come before the Coal Commission of spontaneous heating of coal by exposure to the air. According to Professor Hifer the greatest heating occurs in brown coal. It seems desirable at this time to make more generally known to observers of rock temperature in mines that the simple and strong pattern of slow-action thermometer, designed by your Committee many years ago for this purpose, is still obtainable from the makers, Messrs. Negretti & 1 Oester. Zeitschrift fiir Berg- wnd Hiittennesen, 1901, p. 249, &c. Also paper to Institution of Mining Engineers, London Conference, 1904. ee —————— ————————e ee ON UNDERGROUND TEMPERATURE. ao Zambra. It is a mercurial thermometer, with extra-thick bulb, imbedded in stearine, the whole being inclosed in a hermetically sealed glass tube with a perforated copper case for protection against breakage. Professor Harold Dixon, F.R.S., who has taken a leading part in the underground temperature work of the Coal Commission, has been added to the Committee ; and two old members, Mr. James Glaisher, F.R.S., and Sir C. Le Neve Foster, F.R.S., have been lost by death. Mr. Glaisher was one of the most active members of the Committee for the first fifteen years of its existence. Meteorological Observations on Ben Nevis.—Keport of the Committee, consisting of Lord McLaren, Professor A. Crum Brown (Secretary), Sir JoHN Murray, Dr. ALEXANDER Bucuan, and Mr. R. T. Omonp. (Drawn up by Dr. Bucway.) THE Committee was appointed, as formerly, for the purpose of co-operating with the Scottish Meteorological Society in making meteorological obser- vations at the two Ben Nevis Observatories. The hourly eye observations have been made at the high-level Obser- yatory by Mr. Rankin and his assistants uninterruptedly during the year. At the low-level Observatory in Fort William the self-registering instru- ments have been in continuous use throughout. the year, The health of the observers has been good. Mr. Robert H. Mac- dougal, who has been on the staff for many years, left the Observatory in December, and Mr. W. L. A. Craig Christie was appointed. The Directors desire to thank cordially Messrs. W. G. MacConnachie, A. J. Ross, and J. H. Buchanan for their valuable services as volunteer observers while members of the ordinary staff were on holiday last summer, The results of the observations made at the two Observatories during 1903 are detailed in Table I. TasBie I. 1903 | Jan. | Feb. | farch| April | May June | July | Aug. | Sept. Oct. | Nov. | Dec. | Year Mean Pressure in Inches. Ben Nevis Ob- 24-915] 25°232| 25-325) 25°555| 25°360) 25°189] 25-405 | 24-925) 25°315) 25-056) 25-210 servatory Fort Wiliam Differences . 25°099] 25°148 29°475| 29-845] 29-863] 30:088)29°847| 29-659] 29°924/ 29°410) 29°915| 29-650) 29°760 4:560| 4°613| 4°538| 4°533| 4°487| 4°470| 4°519| 4-485| 4600] 4°594| 4°550 29-720 4621 29°726 4578 Mean Temperatures. ° ° io} ° o is) ° o ° ° ° BenWevisOb-| 22:7 | 27:3 | 24°6 | 24°5 | 33:4 | 387 | 39°38 | 37°6 | 37°3 | 31:7 | 28:3 | 24:2 | 30°8 servatory a Fort William | 38°5 | 43:2 | 41:5 | 42°7 | 49:7] 53:9 | 55°1 | 53:9 | 53°64 | 47-8 | 43:5 | 38°5 | 46°8 Differences . | 15°8 | 15°9 | 16°9 | 18:2 | 16°3 | 15:2 | 15°3 | 16°3 | 163 | 161 | 15°2 | 143 | 16°0 Extremes of Temperature: Maxima. Ben NevisOb-| 35:7 | 42°3 | 37:0 | 35°0 | 56°0 | 580; 49°6 | 49°0 | 50°0 | 40°5 | 41°9 | 36°6 | 58°0 servatory / Fort William! 50°4 | 55°6 | 56°5 | 57-6 | 71:5 | 76:0 | 71:1) 63:8 | 680 | 60°0 | 55°5 | 54:0 |} 76°0 Differences. | 14°7 | 13°3 | 19°5 | 22°6 | 15°5 | 180 | 21°5 | 148] 18:0 | 19°5 | 136 | 17-4 | 180 Eatremes of Temperature: Minima. Ben Nevis Ob- 77 | 17:0 | 149 | 12°6 | 15:7 | 22:8 | 27°7 | 31:0 | 24°3 | 22°8 | 10°9 | 13:3 (HE servatory | | | | Fort William | 213 | 32:1 | 32:3 | 29°6 | 33:4 36:2 | 40:6 | 42:2 | 35°38 | 31:0} 235 | 224 | 21:3 Differences . | 13°6 | 15:1 | 17-4 | 17:0 | 17°7 | 134] 12:99 | 11:2] 11°55 | 821 12°6 91 = 13°6 56 REPORT—1904. TABLE I.—continued. 1903 | Jan, | Feb. March) April | May | June | July | Aug. Sept. | Oct. | Nov. | Dec. | Year Rainfall in Inches. Ben NevisOb- | 33°45 | 36:24) 37:95) 8-36) 661) 6:44 | 13:26) 20:97| 10:72) 18-66) 17:27, 6-81 216-74 | servatory | | Fort William | 16°12} 17-04| 17-25) 3°81} 449) 297] 6-60] 11:95; 7:15] 13:05! 7:85! 5:611113-89 Differences | 17:33! 19:20] 20:70; 4°55| 2°12; 3°47| 6°66 | 9°02 3°57 | 5°61) 9°42) 1:20 |102°85'! Number of Days 1 in. or more fell. Ben NevisOb-; 11 Sy hy TH 4 1 2 5 7 3 8 5 3 79 servatory | | | Fort William | 5 7 7 0 1 0 1 3 1 4 | 1 251-32 Differences . 6 6 10 4 | 0 2 4 4 2 4 4 1 47 Number of Days 0:01 in. ov more fell. | Ben NevisOb-| 22 27 | 28 22 19 18 23 29 | 18 29 22 23 280 servatory | Fort William} 21 26 31 13 16 12 21 27 21 29% | 23 20 259 Differences . 1 1 | -3 9 3 6 2 2 =—3 | Ge 3 21 Mean Rainband (Scale 0-8). Ben NevisOb-| 14 24 2-0 20 2°3 3°6 27 2°6 25 3°3 2°5 15 2°4 servatory Fort William | 3°6 4°8 39 371 38 | 47 47 | 47 40 45 40 34 al Differences . 2°2 2-4 19 ie 15 i bf 2-0 2°1 15 1:2 15 19 1G Number of Hours of Bright Sunshine. Ben NevisOb-; 16 5 1l 40 79 137 76 | 23 67 16 21 18 509 servatory Fort William | 22 10 39 120 135 178 141 91 126 36 21 15 934 Differences . 6 5 28 80 56 41 65 | 68 59 20 0 +3 425 Mean Hourly Velocity of Wind in Miles. Ben NevisOb-| 22 | 17 17 | 11 | 1l 9 11 12 20 18 9 19 15 servatory | Percentage of Cloud. Ben NevisOb-| 88 98 95 80 82 74 86 95 80 96 89 93 87 servatory Fort William | 73 88 85 74 73 68 75 83 66 89 80 77 78 Differences .| 15 10 10 6 9 6 11 12 14 7 9 6 9 The above table shows for 1903 the monthly mean and extreme temperature and pressure ; the amounts of rainfall ; the number of days of rainfall, and of the days on which it equalled or exceeded an inch ; the hours of sunshine ; the mean rainband ; the mean velocity in miles per hour of the wind at the top of the mountain ; and the mean cloud amount. The mean barometric pressures at Fort William are reduced to 32° and sea-level ; but those at Ben Nevis Observatory to 32° only. At Fort William the mean atmospheric pressure was 29-760 inches, or 0-098 inch below the average of thirteen years ; whilst the mean at the top was 25-210 inches, or 0-090 inch below the average of twenty years. The mean difference for the two Observatories was 4:550 inches, the mean monthly difference varying from 4:621 inches in January to 4-470 inches in August. At both places the mean for the year was con- siderably lower than any hitherto recorded, and only in June, September, and November were the monthly means above their normals. The means for October were much lower than any yet recorded for that month, the deficiency at Fort William being as much as 0°365 inch. At the top the absolutely highest pressure for the year was 25:°941 inches at 2 P.M. on May 26, and the lowest 23-916 inches at 5 a.m. on February 27. At Fort William the extremes were 30°572 inches at 10 a.m. on November 6, and METEOROLOGICAL OBSERVATIONS ON BEN NEVIS. 57 28-326 inches at 6 a.m. on February 27. The extreme range on Ben Nevis was, therefore, 2-025 inches, and at Fort William 2:246 inches. The deviations of the mean temperatures of the months from averages of the thirteen years (1891-1903) are shown in Table IT. :— Tasie II. Fort Top of { Fort Top of William. Ben Nevis. | William. Ben Nevis. ° ° Oo Oo January . d . —02 —07 July. ; é . —2:0 —19 February . : . +46 +3°2 August . ; . —2°6 —3:2 March . . . +11 +0°3 September : . +04 —07 April : : . —2°4 —3'8 October . é . +12 + 0:3 May : ; . +00 +02 | November : . —05 —1:2 June : : . —15 -13 ~=«| December : . —16 —1%5 The most remarkable features of the year as regards temperature were the low temperatures for April and the cold weather of the summer months. At both Observatories the April mean temperatures were the lowest recorded for that month since 1891, the shade minimum at Fort William registering frost from 12th to 18th, and on 22nd and 24th ; whilst on Ben Nevis the minimum fell to 12°-6 on 17th, and the maxi- mum rose above the freezing-point on only eleven days of the month, the highest shade reading there being no higher than 35°-0, on the 6th and 9th. The absolutely highest temperature for the year at Fort William was 76°-0 on June 7, and at the top 58°-0 on the same day ; the lowest at Fort William being 21°3 on January 13, and at the top 7°-7 on January 10. In Table III. are given for each month the lowest observed hygro- metric readings at the top of Ben Nevis (reduced by means of Glaisher’s Tables) :— Tape IIT. 1903 Jan, | Feb, | Mar. | April| May | June | J uly | Aug. | Sept.| Oct. | Nov. | Dee. | | ° ° °o °o | ° °o ° ° Dry Bulb. . | 19:1 | 42:2 | 236) 161 | 42:0) 47:3 368 | 437 | 186] sto | 20) 27-0 Wet Bulb a “ 15°3 | 32-0 181 | 141 32°0 | 33°5 30°9 | 32°8 | 30°3 | 25°6 19:0 | 15:7 Dew-point . . |-12°4 | 20:2 |-10°7 | -1°3 | 20°70 | 18:3 19°3 | 20°9 | 16:9 11-0 -6°2 | -20°9 Elastic Force . . | 7024 | -109 | -025 | -041 | -108 | -099 | °104 | -112 | -093 | ‘071 -032 | -016 Relative Humidity | 23) 41 21 46 40 | 30 42 | 41 37 41 | 26 14 [Sat.= 100] | Day of Month , 8 9 Sue Gls 29 5 8 | 1 16 18} 18 29 Month of Year. 23 17 17 1 2) 24 2 | 2 9 9 | 3 23 Of these relative humidities, the lowest, 14 per cent., occurred on December 29 with a dew-point of —20°-9, that being the lowest dew-point for the year. From 9 4.M.on January 21 to noon on February 9—that is, for a period of 507hours—the atmosphere was continuously in a saturated condition, the summit of the mountain being wreathed in fog or mist throughout the period, except for one short break of three hours. The next longest periods of continuous saturation were from April 3 to 11, from September 3 to 10, and from December 9 to 17. The rainfall for the year at the top was 216-74 inches, or 55°97 inches above the average of 19 years; whilst the annual amount at Fort William was 113-89 inches, or 35:31 inches above the average for the same period. At Fort William the year was the wettest hitherto recorded, but on Ben 58 REPORT—1904. Nevis the amount was considerably below that for 1898, when the total was as much as 240712 inches. On Ben Nevis the totals for January, February, March and August were the largest hitherto recorded for these months, whilst the aggregate for the first three months was half the total for the year and considerably more*than twice the average. At Fort William, also, about half the annual amount was registered during the first three months, whilst the aggregate for that period was more than twice the average. At the top of the mountain the greatest fall recorded on a single day was 4°78 inches on January 29, the corresponding fall at Fort William being 1-78 inch ; whilst the maximum daily amount at Fort William was 3:09 inches on January 25, the fall at the top on that day being 3:03 inches. At the top of Ben Nevis the number of rainy days was 280, or 17 above the average, and at Fort William 259 days, or 25 above the average. The number of days on which 1 inch or more fell was much above the average at both observatories, Ben Nevis having no fewer than 79 such days, or 26 above the average, and Fort William 32, or 17 above the average. Of these days of heavy falls, as many as 41 occurred at Ben Nevis during the first three months of the year, and as many as 19 at Fort William. Considering also daily falls of between 0°50 inch and 0:99 inch, and less heavy falls, we have the following table : Aggregate of Falls Number of Days Daily Falls of ————— — -- B.N.O. | Fw. | BNO. F.W | ——— ae — ——— =e a 1 in. and over. : ; 5 . | 149-4in. | 51:3 in | 79 32 Pincers ia.) fg | go. a) etl ge 46 Lessthan$in. =. . . .| 283,, | 306.,, | 149 181 Higtal > Petae Pah! yet: Oe GIO. “| eM 259 Thus, on Ben Nevis nearly half, and at Fort William nearly one-third, of the number of rainy days had falls of half an inch or over, whilst at the top of the mountain such falls contributed six-sevenths of the total for the year. Again, at Fort William 45 per cent. of the annual amount was due to daily falls of 1 inch or over, and at the high-level station nearly 70 per cent. to such heavy falls. The sunshine recorder on Ben Nevis registered 509 hours out of a total possible of 4,473 hours, or 11-4 per cent. of the possible sunshine, being 227 hours below the average of twenty years. This is the smallest annual amount recorded since the Observatory was opened, the next least sunny years being 1884 with 524 hours, 1886 with 571, and 1890 with 591. The amounts for February and March were the least on record for these months, and only in June, September, and December were the totals above the average, and that by very small amounts. At Fort William the annual amount was 934 hours, being the smallest total in thirteen years and 185 hours below the average for that period. February, March, and Octo- ber had the smallest amounts on record for these months, the total of 10 hours in February being only one-fifth of the average for that month, On Ben Nevis the mean percentage of cloud was 87, and at Fort William 78, both above the average. February, March, August and October were very cloudy months, the eye estimations of cloud amount METEOROLOGICAL OBSERVATIONS ON BEN NEVIS. 59 agreeing with the small amount of sunshine registered by the sunshine recorder. On Ben Nevis the following phenomena were observed :— Auroras :—September 20 ; November 1 ; December 25. St. Elmo’s Fire :—January 3, 6, 27, 28; February 27 ; March 5, 17, - 27; May 16 ; July 23; August 3, 15, 18, 19, 20, 21 ; September 2, 10; October 5, 15, 16. Thunder and Lightning :—July 2; August 15, 19, 20, 24. Thunder only :—June 25, 29. Lightning only :—January 26, 27 ; February 20, 25; March 5, 30; June 29. Solar Halos :—April 19 (with Mock Suns) ; June 29. Lunar Halos :—January 5, 8 ; February 9 ; July 31 ; December 1. In November 1903 the Deutsche Seewarte at Hamburg, Germany, applied to the Directors for daily telegrams from the Fort William and Ben Nevis Observatories, witha view to their use, along with similar data from Continental high-level stations, in aiding the preparation for the daily forecasts for the German Empire. These telegrams have accordingly been sent for several months past, and appear regularly in the Daily Weather Report issued by the ‘Seewarte.’ Copies of the Ben Nevis observations have also been"sent on applica- tion to Dr. Hergesell, to be used in connection with the International Aéronautical Investigation. The discussion of the Ben Nevis observations on the lines indicated in our last year’s Report has been continued. The chief subjects taken up by Dr. Buchan have been a continuation of the inquiry into the relations of temperature and pressure at the two Observatories, more particularly in regard to the great movements of the atmosphere grouped under the cyclone and the anticyclone. The observations have been sorted out into the following four classes :— 1. The data for the mean hourly differences of the sea-level pressures and temperatures for the months, including all types of weather, with the exception of those days on which strong winds occurred, which rendered the barometric readings untrustworthy owing to the pumping of the mercury. 2. The second class included all those days during the fourteen years on which the difference of temperature, on the mean of the whole day, was 12°-0 or less. 3. The third class included those days on which the difference of temperature was 18°-0 or upwards. 4, All the other days were grouped under this class on which the difference of temperature lay between 12°-0 and 18°-0, showing thus the results for the days when the temperature differences were virtually about the average. This fourth class has been added to the investigation since the meeting of the British Association at Southport. Further, the averages for these four different classes have been now calculated from all the available observations made at the two Observatories from August 1900 to December 1903. The broad results are these :—(1) When the difference of the mean 60 REPORT—1904. temperatures of the day is only 12°-0, or less, the calculated sea-level - pressure for the top of the mountain is markedly greater than at Fort William, and the accompanying meteorological conditions are anti- cyclonic, the weather being clear, dry, and practically rainless ; (2) when the difference of temperature is 18°-0, or greater, the meteorological conditions are cyclonic, and the accompanying weather dull, humid, and rainy. The large result here arrived at empirically is in accordance with the principle laid down by Dalton—viz., that air charged with vapour or vaporised air is specifically lighter than when without the vapour ; or, in other words, the more vapour any given quantity of atmospheric air has in it the less is its specific gravity. Another important result is that the cases of small differences of temperature between the two Observatories are chiefly occasioned by an increase of temperature at the top of the mountain, and large differences of temperature by a decrease of temperature at the top. The intimate relation thus disclosed between the varying temperatures and sea-level pressures of a high-level and a low-level station is of prime importance in forecasting the weather, inasmuch as it reveals, in a way not hitherto attempted, the varying conditions of the hygrometric states of the atmosphere, particularly at high levels, upon which changes of weather so largely depend. The setting in of a process of saturation of the atmosphere at great heights may thus be made known, even when no cloud has yet been formed to indicate any such saturation. The important bearing of these results on such practical problems in meteoro- logy as the forecasting of the monsoons of India is evident. The Study of Hydro-aromatie Substances.—Report of the Committee, consisting of Dr. E. Divers (Chairman), Dr. A. W. CRossLEY (Secretary), Professor W. H. Perkin, Dr. M. O. Forsrer, and Dr. H. R. Le Svevr. Recent Work on Hydro-aromatic Substances. By Dr. A. W. Crossiey. Tue following is a summary of the work published on hydro-aromatic compounds since the preparation of the last report.! Petrolewm.— Roumanian petroleum ? resembles Russian and American petroleum, inasmuch as the densities of fractions taken every 2° between 50° and 70° diminish to a minimum at 60° to 62°, and then continuously increase, whilst in the case of Galician oil there is a steady increase of density throughout. A further difference from this latter oil is to be found in the composition of the fractions between 60° to 100°, which do not contain secondary hexanes, as on nitration they yield aromatic deriva- tives only. Methyl- and ethyl-hexahydrobenzene are among the hydro- carbons contained in the Roumanian oil. Hydrocarbons.— Sabatier and Senderens* have shown that, when benzene or its homologues, containing methyl groups as side-chains, are passed together with hydrogen over reduced nickel, hydrogenation takes place without complication ; whereas if the hydrocarbons contain longer ' Reports, 1903, p. 179. ? Poni, J. C. S., 1903, Abst. (1), 593. 3 Compt. Rend., 1901, 182, 1254. ON THE STUDY OF HYDRO-AROMATIC SUBSTANCES. 61 side-chains (ethyl, propyl, &c.) part of the latter is split off. For example, ‘ethylbenzene gives principally ethylhexahydrobenzene, but also small amounts of methylhexahydrobenzene. Sabatier and Mailhe! have further investigated the product obtained by passing benzene and hydrogen over reduced nickel, and find that if the temperature be maintained at 250° pure hexahydrobenzene is formed, identical in all respects with that occurring in Caucasian petroleum. If hexahydrobenzene be passed over reduced nickel at 270° to 280°, it is decomposed into benzene and hydrogen, which latter reacts with the benzene, forming methane. An energetic substitution reaction takes place when chlorine acts on hexahydrobenzene at a temperature of 0°, resulting in the formation of a mixture of mono-, di-, tri-, tetra-, and hexa-chloro- derivatives.” According to Markownikoff,? methylhexahydrobenzene has not been obtained pure by the methods so far described ; for example, when isolated from Caucasian petroleum, it is contaminated with normal heptane. It can, however, be prepared in the pure condition by the action of zinc dust on an aqueous alcoholic solution of 3-bromo-1-methylhexahydrobenzene. The hydrocarbon obtained by eliminating the elements of hydrogen bro- mide from this latter substance ‘ is a mixture of the two methyltetrahydro- benzenes with the double bonds in the 2 : 3 and 3 : 4 positions. The pure substances have been obtained by other methods.” In such hydrocarbons the influence of the side-chain is such that in the splitting off of hydrogen together with a halogen, or in the combination with a molecule containing mobile hydrogen, the latter splits off from, or combines preferably with, the carbon atom furthest removed from the side-chain, whilst the electro- negative element combines with the carbon nearest the side-chain. 1:1 : 3-trimethyl-A*-tetrahydrobenzene.® Hydroxy-derwatives.—The reaction introduced by Sabatier and Sen- derens has been extended to the preparation of aromatic alcohols. When phenol is passed together with excess of hydrogen over reduced nickel at a temperature of 140°-160°, pure hydroxyhexahydrobenzene is obtained ; 7 but if the temperature be raised to 215°—230°, the hydroxyhexahydro- benzene first formed is decomposed into ketohexahydrobenzene and hydrogen. From the mixture so produced Sabatier and Senderens have obtained the pure alcohol or ketone by, in the first case, passing the pro- duct with excess of hydrogen over reduced nickel at a temperature of 140°-150°, and in the second by passing the product without hydrogen over reduced copper at a temperature of 330°. Under similar conditions thymol and carvacrol are converted into the corresponding hexahydro- derivatives (Brunel). Todohydroxyhexahydrobenzene gives, when treated with potash or silver oxide,’ the internal oxide of 1 : 2-dihydroxyhexahydrobenzene, fy) ScH—cE, cH Sou, \cu,—CH, 1 Compt. Rend., 1903, 187, 240. 2 Bull. Soc., 1903, 29, 974. 3 Cent. Blatt., 1904 (1), 1345. 4 Cent. Blatt., 1904 (1), 1346. 5 Cent. Blatt., 1903 (2), 289; 1904 (1), 1213; Wallach, Annalen, 1903, 329, 368. 6 Harries and Weil, Ber., 1904, 37, 848, 7 Holleman, Cent. Blatt., 1904 (1), 727; Brunel, Compt. Rend., 1903, 187, 1268 ; Sabatier and Senderens, ibid., 1903, 137, 1025. 8 Brunel, Compt. Rend., 1903, 187, 62. 62 REPORT—1904. into which substance the former is easily converted by the action of water. When the internal oxide is treated with alcoholic ammonia,' there result l-amino-2-hydroxyhexahydrobenzene and two forms of dihydroxycyclo- hexylamine, NH(C,H)9-OH)>». Power and Tutin ® have isolated a levorotatory modification of quer- citol from the leaves of Gymnema sylvestre. It is demonstrated that this substance has the same constitution as d-quercitol (pentahydroxyhexa- hydrobenzene) which has been established by Kiliani and Schaefer,? and can only differ from the latter stereochemically ; but, since d-quercitol has (a), + 24°16, whilst the new quercitol has (a);,—73°°9, the one cannot be the optical antipode of the other. Eight optically active modifications of pentahydroxyhexahydrobenzene are possible, and until a further number of these isomerides are known it is impossible to assign a definite con- figuration either to d-quercitol or to the new 1-quercitol. Aldehydes and Ketones.—The general method for the preparation of aldehydes by the action of organomagnesium haloids on the esters of orthoformic acid dissolved in dry ether 4 appears to be applicable to the syuthesis of hydro-aromatic aldehydes,’ and in this way hexahydro-m- toluic aldehyde has been prepared from 3-bromo-1-methylhexahydro- benzene. The preparation of hexahydrobenzyl alcohol ® has been described by Bouveault. Methylhexylearbinol, C,;H,,.CH(CH;)OH, is obtained when acetic aldehyde is allowed to act on the magnesium compound of chloro- hexahydrobenzene.? When these alcohols are oxidised with chromic acid the former yields hexahydrobenzaldehyde and the latter hexahydroaceto- phenone. Chloro- derivatives of ketomethyldihydrobenzene.*® Acids.—When pentane-aye-tricarboxylic acid is digested with acetic anhydride and then distilled,® a remarkable decomposition takes place with elimination of carbon dioxide and water and formation of 6-ketohexa- hydrobenzoic acid. CH,—CH,—CO,H CH, PO GAG ay eae pCO. CEC. a, — CH - 00 + CO, + H,0 CH,—CH, -CO,H : \ cH, -- CH, On reduction the corresponding hydroxy- acid is obtained, which yields trans-6-bromohexahydrobenzoic acid when treated with hydrogen bromide, and this bromo- acid, under the influence of sodium carbonate, gives rise to A’-tetrahydrobenzoic acid. d-Ketohexahydrobenzoic acid combines with hydrogen cyanide to form the mixed nitriles of the cis- and trans-modifi- cations of a-hydroxyhexahydroterephthalic acid. Both the corresponding acids decompose on distillation with formation of A!-tetrahydroterephthalic acid, identical with the acid synthesised by Baeyer.!° c-Ketohexahydrobenzoic acid has been used by Perkin !! as the starting- point for the synthetical preparation of terpin, inactive terpineol, and dipentene ; but as this report does not include a consideration of the terpenes and camphors, an account of this work is not given. 1 Brunel, idid., 1903, 137, 198. 2 J. C. 8., 1904, 85, 624. 3 Ber., 1896, 29, 1762. * Tschitschibabin, Ber., 1904, 87, 186. 5 Thid., 850. 5 Compt. Rend., 1903, 187, 60. 7 Bull. Soc., 1903, 29, 1049. * Zincke, Annalen, 1903, 328, 261. 8 Perkin, J. C. S., 1904, 85, 416. 19 Annalen, 1888, 245, 160. 1 n J. C.S., 1904, 85, 654. ON THE STUDY OF HYDRO-AROMATIC SUBSTANCES. 63 Transformations.—1-Methy1-3-ketohexahydrobenzene has been con- verted into 1-methyl-2-ketohexahydrobenzene! by the series of reactions already described.” When 1 :5-dimethyl-3-keto-+!-tetrahydrobenzene * is heated with an equal weight of ammonium carbonate, a small quantity of a base is formed identical with collidine (2:4:6-trimethylpyridine). The mechanism of this process is the exact reverse of Hantzsch’s reaction * whereby dihydro- pyridine, under the influence of hydrochloric acid, yields ketotetrahydro- benzene. Tt has been shown by Demjanow and Luschnikow * that it is possible to convert a substance containing a tetramethylene ring into one con- taining a pentamethylene ring (cyclopentanol from tetramethylenemethyl- amine) ; and, in continuance of this work, Demjanow ° has now provided an example of the conversion of a ring containing six carbon atoms into one containing seven. On distilling hexahydrobenzamide with phosphorus pentoxide it yields cyanohexahydrobenzene (1), which on reduction gives the corresponding amine (2). When the hydrochloride of this amine CH, - CH, CH,—CH, CHK (1) Sex GN CH @), cH . CH, . NH, CH, —CH, CH,— CH,” oe —OH,=08 - eS CH, (3) | *\ cH, — CH,—CH, is acted on with silver nitrite it is converted intoan alcohol identical in every respect with suberyl alcohol (3), already described by Markownikoff.’ A study of the action of bromine on 3 : 5-dichloro-1 : 1-dimethyl-A?**- dihydrobenzene * has shown that the resulting hydro-aromatic bodies very readily lose hydrogen bromide to form aromatic substances, of which the two principal ones are 3 : 5-dichloro-4-bromo-o-xylene and 3 : 5-dichloro- 6-bromo-o-xylene. Since the dichlorodimethyldihydrobenzene, which forms the starting-point of the research, contains the gem-dimethyl group, the migration of one of these methyl groups becomes an essential step in the production of an aromatic compound. The reaction has therefore been worked out so as to gain an insight into the course of such changes, more especially as, on account of the symmetry of the molecule, it forms one of the simplest cases in which the wandering of an alkyl group can take place. The reaction is largely influenced by the condition of experiment, but no substance has been encountered in which an alkyl group has wandered into any but an ortho-position. The Nature of Double Linkings.—Recent experimental work has enriched our knowledge of the behaviour of substances containing double linkings, more especially as regards the property of addition. In the case of a substance containing several double bonds in the molecule, these bonds often do not behave independently of one another. Thiele’s theory ° of partial valencies provides a possible explanation of many such cases. Knoevenagel '° considers it essential to study the movement of the atoms themselves in the molecule, and assumes that doubly linked carbon atoms are ' Wallach, Annalen, 1903, 329, 368. 2 Reports, 1903, p. 181. 3 Knoevenagel and Erler, Ber., 1903, 36, 2129. 4 Annalen, 1882, 215, 297. 5 Cent. Blatt., 1903 (1), 828. 8 Cent. Blatt., 1904 (1), 1214. ™* Ber., 1893 26, R, 813. 8 Crossley, J. C. S., 1904, 85, 264. o~ - Annalen, 1899, 306, 87. 10 Ber., 1903, 36, 2803. 64. REPORT—1904. in a continuous state of oscillatory motion. In the case of a substance such as butadiene, the formation of the dibromide BrCH, -CH=CH—CH,Br, is explained by supposing the swinging motion of the carbon atoms to be taking place first in one direction and then in the opposite, as indicated in the accompanying diagram (fig. 1). Continuous motion in one direction only is prevented by the hydrogen atoms attached to the terminal carbon atoms, which come into the plane of rotation. It is quite another matter in the case of benzene, where alternate carbon atoms are supposed to rotate continuously in opposite directions, because none of the valencies which pass into the plane of rotation have hydrogen atoms attached to them ; the result is that the double linkings change their position and travel round the ring (fig. 2). HTGa. Fig. 2. oO | S So) Po Qa S Such a theory indicates the possibility of new types of isomerism, more subtle even than optical isomerism, and it is pointed out that cases of supposed polymorphism, ¢.g., the quinols and benzophenone, may be in reality manifestations of structural differences of the above type. Knoevenagel supports Lehmann’s view,' that substances exhibiting difference in crystalline form afford evidence of difference in chemical or, perhaps better, physical constitution. It is also suggested that bodies of the type of ethyl +*:°-dihydro- terephthalate should be particularly liable to lose a molecule of hydrogen, (+) HC . COOCH, Ars HO CH | ll HC CH ay HC . COOCH, (+) since the two hydrogen atoms marked (+) would be in a continuous state of bombardment, due to the swinging motion of the carbon atoms con- nected by a double bond. On increasing the temperature this state of things would become sufficiently intense to cause the partial dissociation of the molecule with evolution of hydrogen. This actually happens in the case of the above ethereal salt on heating? in an atmosphere of carbon dioxide, especially in presence of platinum black. The evolved hydrogen is much smaller in amount than required by theory, only 18 c.c. being obtained by heating one gram of the salt instead of 113 c.c. This is 1 Molehularphysih (2), 413. ? Ber,, 1903, 36, 2857. ON THE STUDY OF HYDRO-AROMATIC SUBSTANCES. 65 readily explained, for the evolved hydrogen combines with some unaltered ester, and the result of the reaction is the production of methyl terephthalate and methyl hexahydroterephthalate. Al3. Dihydrobenzene. By Dr. A. W. Crosstey. In the last report of this Committee,! brief allusion was made to the preparation of A‘‘*-dihydrobenzene ; work in this direction has now been completed, with results which entirely confirm the preliminary experi- ments. The hydrocarbon obtained from dimethyldihydroresorcin by Crossley and Le Sueur”? was proved to be 1 : 1-dimethyl-\”** dihydro- CH CH Tae (CH,).CX pu GH, CH benzene, and by submitting dihydroresorcin to an identical series of reactions a hydrocarbon was obtained,’ which differed from any previously prepared dihydrobenzene in only combining with one molecule of bromine to give a dibromodihydrobenzene melting at 104°-5. It was therefore suggested that the double bonds would be in the position 1 : 3, and the hydrocarbon prepared by Baeyer ‘ and Markownikoff® would be A***-di- hydrobenzene, which is characterised by directly adding on four atoms of bromine to form a solid tetrabromide melting at 184°. Harries and Antoni ® consider that their work proves this suggestion to be incorrect. Unfortunately it was not found possible to prepare pure A‘: *-dihydro- benzene from dihydroresorcin, but this end has now been attained by the removal of the elements of hydrogen bromide from dibromotetrahydro- benzene.’ CH, . CHBr CH=CH CH. cue =2HBr+ CH, CH K ir r x > CH, . CH, CH, —CH ; The reaction can only take place in one way, and therefore leaves no _ doubt as to the constitution of the resulting hydrocarbon, which like that obtained from dihydroresorcin only adds on two atoms of bromine to give a solid melting at 104°-5. That this latter substance is in reality a dibromodihydrobenzene is conclusively proved by the fact that on treatment with quinoline it Joses two molecules of hydrogen bromide, yielding benzene. It seems indisputable that, as already suggested, the hydrocarbon obtained from dihydroresorcin or from dibromotetrahydrobenzene is A***-dihydrobenzene, and the hydrocarbon giving the tetrabromide melting at 184° must therefore be A!‘ *-dihydrobenzene. ' Southport, 1903, p. 182. 2 J. C. 8., 1902, 81, 822. ® Crossley and Haas, J. C. S., 1903, 83, 494. + Annalen, 1894, 278, 88. 5 Annalen, 1898, 302, 29. 6 Annalen, 1903, 328, 102. 7 Proc. C.S., 1904, 20, 160. 1904. r 66 REPORT—1904. Wawe-length Tables of the Spectra of the Elements and Compounds.— Report of the Committee consisting of Sir H. E. Roscor (Chairman), Dr. MarsHauu Watts (Secretary), Sir Norman Lockyer, Professor J. Dewar, Professor G. D. Livernc, Professor A. SCHUSTER, Pro- fessor W. N. HartLey, Professor WoLcotr Gipss, Sir W. DE W. ABNEY, and Dr. W. EH. ADENEY. RUTHENIUM. Kayser, ‘ Kénigl. Preuss. Akad, Wissensch. Berlin,’ 1897. Adeney, ‘ Proc. Royal Dublin Soe.’ vol. x. (n.s.), pt. 1, No. 3. Hixner and Haschek, ‘ Sitzungsber. kais. Akad. Wissensch. Wien,’ cv. 1896, cvi. 1897. Rowland and Tatnall, ‘ Astro.-phys. Journ.’ vol. iii. p. 288, 1896. Wave-length (Kayser) Are Spectrum Spark Spectrum Adeney | Exner and Haschek 5887°371 64830 33°561 33380 28-580 28235 26:018 15157 04°461 5792°382 90-741 82°720 82-511 74°533 71°352 68-066 58°875 56:980 53°72 52°163 47°623 46:131 45°776 40°710 34°606 30°122 25°895 24:975 14391 13-025 02-522 5699°741 99-224 96°526 94-626 93°190 92-288 88-990 Intensity and - 5 NE PDF ONPRPNORPRNCORPR EWE WOWOCNKN REE RAONWKYHNOOOSO Character | | Reduction to Vacuum pete ieee A 1:60) 46 ” ” 1:59 | 4:7 9 ’ 33 ’ ” 3 7°? 3 1°58 e ” 9° ” , ” ”? ” ” 99 ” 1:57 S 39 3 ” >’ 39 3 99 > ” 3° ” ” > ” 9 ” 29 37> ” ” 1:56 55 ” 39 ° ” ” ” “5 4:8 99 ” 1:55 i > 9 9 99 29 ” ” 9 ” 99 ” > Oscillation Frequency in Vacuo 16980°9 170462 171375 38-0 52:1 53°1 59°5 91°7 17223°4 59°3 64-2 88:2 88:8 17312°7 22°3 321 59°8 66:1 752 80:0 938 98-2 99:4. 17414°7 33'3 46°7 59°8 62°6 93°9 99:1 175313 39°9 41°5 49°8 55°6 60°71 62°8 73°0 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 67 RUTHENIUM— continued. Reduction to Spark Spectrum VWatouain Rie, Wave-length Intensity Oscillation (Kayser) and i fas) |. Hxreduency Are Spectrum Adeney Exner and | Character Rect oe in Vacuo Haschek r | 5679-790 4 1°55 | 4:8 17601°5 76°720 a = 5 11:0 65°370 4 1:54 5 46°3 63-233 0 a 5 52°9 57°127 Z Pe 5 72°0 53°482 2 3 35 83°4 53°005 0 3 Ee 84:9 50°981 2 3 3 91:2 49°737 3 Sy 5 95-1 48-058 1 5 a 17700°4 47°755 0 A A 01°3 41°848 2 5 5 20°3 36°441 7 . =p 36°9 29984. 1 oe Fr 57:2 27°722 2 15. 8 64°4 19-558 0 s ss 90-2 09-360 2 AS 4:9 178224 06-958 3 3 % 31-1 03-782 3 8 is 36°2 03°370 2 s 3 41°5 00°753 2 5 ra 49'8 56582°501 2 1°52 er 179082 79°650 2 * ss 17-4 78914 2 % ES 19°7 78°594 4 Pr oe 20°8 70:906 2 5 3 45°5 69233 4 35 33 50°9 59-962 6 35 3 80°8 56°719 3) 5 a 91:3 49960 2 151 5 18013°2 40°881 3 35 a 42°8 31-220 © 2 5 3 pS 74:2 18-056 Z 53 Pe 18117°4 12°593 2 1:50 os 35°4 10°934 6 9 i 42°8 077151 0 a 3 53°3 01-230 1 % 5:0 72:7 5496-899 4 FA 5 90-4 94°575 1 5 3 95:0 84-850 2 Be 3 18227°0 84°524 6 % 8 28-1 80°507 3 3 P 41°5 79°619 4 > 95 44°3 75°377 2 1-49 93 58°6 73°050 2 is 3 663 71°755 0 Fr: 3 70°7 56°329 2n A. BS 18322°3 55018 6 = 3 26°7 62-930 1 Pr 6 338 39°618 2n 1-48 a 78°6 39°421 2 33 es 79°3 27°815 4 3 i. 184186 19:056 4 Fr 53 484 01-609 2 1:47 | 5:1 18507°9 01:234 is, . s 09:2 5386-083 | 4 5 = 61:2 68 REPORT—1904. RUTHENIUM—continued. Spark Spectrum Reduction to Wave-length Intensity Vacuum | Oscillation (Kayser) = reel aos and Frequency Are Spectrum Agios Exner and | Character ree 5 in Vacuo y Haschek x | 5378-042 3 Me pl pa 18589:0 13°505 On ob os 18604°7 65°799 2 A ne 31°5 62°271 2 1:46 rn 43°7 61°967 5 35 99 448 48°340 0 Bs 5 92°3 36°110 3 55 = 18735°1 34°901 2n ay 5 39°4 33114 3 ‘ a 45°7 15520 2 1°45 a) 18807°7 09-440 a a : 29°3 07°481 0 5 i 37°2 06°624 1 + 73 39°3 06-035 0 As 41-4 05-030 4 ¥ SS 44:9 5291°327 1 “ 5:2 93°6 84:256 4 1°44 ay 18918°9 80°989 2 9 , 30°6 75240 1 “ ee 51:2 66'988 1 55 . 81-0 66°642 1 ny F 82:2 64°113 On 2 > 91°3 57240 2 35 19016:1 51°816 1 4 35°8 45°612 2 1-43 : 58°3 45°112 0 F 5 60:2 43°109 2n 5 a5 67°4 42°560 1 nA . 69:4. 35°774 1 - 4 94-4 23°708 3 Ss, 19138°1 14:247 1 5 Pr 72:8 13-586 3 Ay = 75:2 09°667 2 1-42 5 89°9 02°285 2 rp 5° 19217°0 00°040 3 re +5 25°3 5195°171 4 i 5 43°3 76°361 0 es 5 19313°3 74:°105 0 1-41 3 2107, 71:193 6 3 - 32°5 69242 0 Ps 55 39°8 68°793 0 os 5% 41°6 68-237 0 a “p 43°6 60°167 2 s ‘ 73°9 55°302 4 a a 92:2 53°364 2 a op 99°5 51:230 4 25 re 19407°5 47°401 4 = Ad 22°0 42933 4 a aS 44-2 36°717 5 1:40 + 62°4 34°285 0 55 a 71°6 34°059 2 a 72°5 27°423 2 = - 97:7 07°230 4 or 5:4 19574°7 01°892 0 55 3 95:2 01°553 2 spel eae 96°5 5093996 4 139 | ;, 19625°6 4 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 69 RUTHENIUM—continued. Spark Spectrum Reduction to Vacuum Wave-length Intensity Oscillation (Kayser) an Frequency Are Spectrum Adeney Exner and | Character | y + pia in Vacuo Haschek A 5077°484 3 1°39 | 5:4 19689: 77243 1 er Ap 90°3 73141 2 a is 19706°2 62°815 1 1:38 3 46°5 57°487 4 xy a 67°3 537114 0 Fi aa 84:4 47-471 2 53 53 19806°5 45°570 ] ‘ Pe 14:0 41°528 0 a ee 29°9 40°908 1 ae a 32°3 40°521 1 9 a 33°'8 39°794 On 39 3 36°7 26°343 3 1:37 | 55 89°7 20°472 0 Ae i 19912°9 19-140 1 9 % 18-2 11:387 3 =e e 49:0 10°765 1 Pr 55 515 05°394 1 si 3 73°0 03°697 0 ae is 79°7 4992°891 2 i = 20023°0 87-412 il 1°36 FA 45°0 80-498 2 PA an 712'8 76°351 2 35 a 89°5 75534 0 x * 92°8 74°255 9 es Fe 98-0 69°055 2 55 3 20119°0 60°022 0 a Fr 56°7 55°416 1 bs = 74:4, 38°587 3 1:35 | 5°6 20243°1 35°805 0 a5 a 54°5 21:233 4 eee on 203144 M755 ul | 1°34 55. 53°7 10384 0 ae he 59"4 08°045 3 rt A! 69'1 05°179 1 ” ” 83°0 03°223 5 a fe 89°2 02-033 0 ae Pe 94°1 01°234 0 aA 64 97°4 4899-416 1 :. as 20405'0 95°745 4 yi ‘ 20°3 95°555 1 3 - 211 95°474 1 53 Bs 21°4 85:186 0 ne na 64°5 82832 0 a5 é 81-1 77598 0 1°33 . 963 75188 0 an = 20506°4. 74489 0 95 aa 09°4 69°952 1 : ” ” 28°5 69-314 6 ae 99 31-2 65°253 1 fi, Ps aS 48°3 63°265 0 lapse a 56°7 62°024 2 ae nd 62:1 54°731 1 ” ” 92°8 44°720 4 ” o» 20635°3 39°930 1 1°32 5 55'8 39°174 et aed : 49°0 70 REPORT—1904 RUTHENIUM—continued. Spark Spectrum Reduction to | Wavye-length Intensity Vacuum — Oscillation (Kayser) = == — and > Pa Frequency Are Spectrum H Seay ee Character eee : in Vacuo 4833°157 5. 2 1324) (5°7 20644°7 28°865 0 a as 20703°1 22°738 | 0 x A 29°4 17512 1 =r rf 519 15694 5 a 5 59°7 14°895 0 o a 63°2 13412 0 a “A 70°6 06°375 0 a 55 20800°0 05°043 2 as es 05°8 01°343 1 1°31 oc 21°8 4798607 2 BS 3 33°7 95°721 2 3 ‘5 46°3 94°547 2 » PP 51°3 81:937 1 aa 58 20906°3 74°168 0 a 24 40°2 73°325 0 2 ay 43°9 69°464 + . 5 61-2 67°315 0 Se fe 70°4 64°582 0 1°30 a 72°4 58-043 6 = ‘ 21011°2 56°402 2 3 f 18°5 53°280 0 “A 5 322 51197 0 +: ee 41°5 43°205 1 is “3 77:0 38°587 0 3 ee 97°5 33°710 4 - ay 21119'3 33°486 0 3 rc 20°3 31504 3 ne a 29°1 21:078 1 1:29 x 758 18°228 0 5 a 88°6 16201 2 a Pe 97°5 14°335 0 =f A 2120671 127146 1 53 x 15°9 09-672 4709°55 6 %» ” 27'1 04°2 1 ” ” 02°6 1 ” ” 4692°3 1 1-28 4 4690°284 90°5 4 Pp 59 21314°7 87°3 1 ” 39 85°947 86:2 1 34 ‘ 34°5 84:196 84°4 4 a 3 42°4 83°258 0 Ss es 46°7 81:966 82:2 4 ob Ss 52°6 81°563 0 * 5 54°5 775 In ” ” 74°821 | 75:0 4 mA A 853 74:0 In ee a 70°146 70°4 + oo a 21407°0 69°5 1 5 a 68°5 In =A > 67°5 In es af 62°663 | 0 ” ” 41'1 54-901 | -@ 12 9 76°8 54489 54°6 | 4 ees 99 78°7 52°371 1s taker OD 7 ) 88°5 48-293 | 9 » 9 21507°4 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 7 RUTHEN1UM—continued. 1 Spark Spectrum Reduction to | Wave-length Intensity ots Oscillation (Kayser) | ; and Frequency Are Spectrum Adeney | Exner and Character Rese a * in Vacuo | Haschek r 4647787 4647-68 5 127| 59 | 2809-7 46:967 0 bs 33 14:9 46°326 0 a oy 165 45:264 45-4 4 ec 35 21°4 42°752 1 =r Ss 331 42°548 1 - % 34:1 41°135 41°2 0 we 7 40°5 39°490 391 0 3, 55 48:2 38°569 0 “h = 52°5 35°849 36:0 4 oo ts 651 28°495 0 - 6:0 98°8 267184 1 be a 2161071 17°827 0 1-2 an 49:2 125 1 oe 10°6 In a ay | 09°5 In $5 a 05°833 05°8 2 » ’ 21705°6 02-978 0 oD 3 20°1 01°933 01:9 3 3 26°8 *4599°271 4599-30 6 9 % 36°6 96879 97:1 4 = oe 479 93°367 0 “ ‘ 64:5 93°161 0 39 a 65°4 * 92-695 92°7 4 re 3 67°7 91°717 2 a a 72°3 * 91°257 91°4 4 ne - 74:5 89°734 0 a % 818 89°177 87-4 0 35 A 84:4 85°5 1 » 99 * 84°632 84°60 4 = » | 21806:0 815 In 8 80°246 80°4 3 1:25 55 26°4 74:2 In » 25 64°862 65:0 2 3 61 21900°4 62°772 62°9 1 3% rf 10°4 21607157 4560°16 60°3 4 rr . 22°9 59°215 1 z “0 27°5 56°5 In a A * 54°696 54°70 54°71 6r 5 5 49°3 * 52:281 52°28 52°5 Pt 4 F rc 60°9 * 507112 50°11 50°3 3 » ” 714 49589 49°6 2 32 * -73°9 * 48:030 48°03 48:2 4 55 $5 81-4 * 47463 47°46 47.6 4 PC 5 84:2 47°105 47°3 2 Be zs 85°9 45°4 In 3 33 44:0 1 29 ” 42°848 42°85 42-7 1 1:24 x 22013°1 42°0 In Fe a 41-4 In 3 ss 40°05 40:2 In SS Fe 20°1 36:0 In D 55 35°0 In 5 #3 * Rowland and Tatnall: 4599°265, 4592-699, 4554°697, 4552-293, 4550°121, 4548-031, 4547-467. 4591:285, 4584°619, 4560-168, 72 REPORT—1904. RUTHENIUM—continued. Spark Spectrum Beets fe Wave-length Intensity | = Oscillation (Kayser) I and Frequency Arc Spectrum Adeney Exner and | Character | , + ht in Vacuo Haschek A | 4531:035 4531°04 4531°2 of 1:24 | 61 | 22063°9 25°616 0 | 9s 90°3 = 21-110 21°11 21°3 4 > ” 22112°4 Sal O77 17°98 18-2 4 ’ ” 27°7 * 17:060 17:06 173 4 ” ihe 322 16°421 16°42 166 2 45 or 35°3 = N33 11°35 115 4 | 99 ” 60-2 * 10°25) 10°25 104 a | 9 % 65°6 08°715 08°72 08-8 2 ae oh th 732 08-192 08°3 ] [has a5 75°7 *4498 322 4498 32 449830 4 1-23 = 22219°4 91-846 91°85 92-1 2 of 6-2 564 90°396 90°40 90°5 2 re » 63°5 88°550 88°50 88°7 4 ” ” 72°7 82°194 82°19 82:3 2 Len A 22304°3 * §80°603 80°60 80°7 4 1 er 3 12:2 79°80 79°7 1 on ree 16:3 75493 75°7 2 ss Dex 37°7 * 74:093 74:09 74:2 4 [i gs Ey es 44°7 71:200 0 lees “5 59-2 70°69 70°8 Jd a ae 61°7 67°427 67°6 2 | 1:22 % 78°0 66°511 2 ae: 99 82:7 65°649 65°65 1 ” ” 87:0 64°661 64°66 0 9 ” 91°9 * 60°209 60°21 60°19 6 % ” 22414°3 535. In a F * 49-509 49°51 49°50 t Bs = 68-2 * 44-674 44°67 44°8 4 ce - 92°6 43°3 In ob is 40°245 0 oe pom eg. 50 Si * 39:938 39°94 39°98 5 | ese 2» | 166 39°574 2 “ os | 18°5 38°6 1 a5 BS | 30°478 u 121 | 63 64°6 * 28°624 28°65 4 “5 5S 74:1 26°182 26°18 1 % ’ 865 24°958 252 3 oy , 92°8 23°143 23°3 1 es : 22602°0 * 21:629 21°63 21°7 a | 95 3 09°8 21-006 21:01 21:2 4 3 * 13:0 20°634 20°63 2 * ” 14:9 14:607 2 of or 45°7 13:°458 2 ap = 516 12058 0 ties => 58°8 * 10°207 10°21 10°17 6 lees ” 68°4 09-1 In icing aw 05°809 052 0 of 7 91:0 02°7 In 5 a3 4399-751 99°75 00:0 1 % ” 22722°3 *% 97:956 97°96 43983 f 9 » | 315 96868 | 0 “5 cathe el 37-2 * Rowland and Tatnall: 4521°124, 4517-985, 4517-063, 4511°364, 4510-265, 4498°316, 4480°617, 4474:100, 4460°194, 4449°509, 4444°681, 4439-935, 4428-631, 4421-626, 4410°193, 4397°966, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 79 RUTHENIUM—continued. Spark Spectrum Reduction to Wave-length ae a Oscillation (Kayser) i and |... | Btequency Are Spectrum Adeney Exner and | Character) , , | }_ in Vacuo Haschek A 43957125 449513 4395°4 Z E21 | 6:3 22746'1 B Ol-19) 91°19 91°5 4 1:20 fe 66°5 * 90°614 90°61 90°60 6 = ; 69°6 89°547 89°4 0 ” ” 75°1 89-150 2 4 - tel * 86°431 4386°43 86°6 4 a a3 91:3 86:1 + a5 : * §85°823 85°82 85°85 5 3: ” 94°4 * 85°563 85°56 85°60 5 ” ” 95°8 * §83°530 83°53 83°7 2 ” ’ 22806°4 81-421 81:42 81-7 2 ” ; 173 76°745 768 1 - a 41°7 73°9 1 9 ” 73°4 1 oc c * 72°381 72°38 72°38 5 ” » 64°5 71°52 71°6 2 ” > 68°8 * 71:363 4 = a 69°9 70°580 70°9 2 on fe 74:0 65°741 0 “E 6-4 99-2 64-270 64°6 2 ce ; 22906°9 63°5 1 » ” 62°872 63°2 1 “ ac 20°3 * 61-581 2 = a 21:0 * 61°372 61°37 61°40 5 “e Ke 22-1 58°5 In a 33 57:031 57°6 1 -S ** 45°0 * 54-960 54°96 55:2 3 1-19 3 55°9 * 54:300 54°30 54°32 6 5 “ 59°4 50°632 0 op of 78°8 * 49°868 49°86 49°90 5 “A “ 82°8 * 46°640 46°9 a a oa 99°9 43°178 43°7 0 = 95 230182 * 42-243 42°24 42°25 6 ” ” 23°2 41-204 41-4 2 ” > 28°6 40°503 40°7 2 or a 32°4 40°0 In oe) ” 38°829 39°1 2 ” » 41°3 * 37:427 37°43 37°6 4 os “ 48°7 373 1 ae re * 36°584 36°58 36°7 2 te 59 » 53°2 33°1 1 |» » 32°789 32°9 0 PP “5 73°4 32°655 32°66 2 ” ” 74:1 * 31°321 31°32 315 4 ~ aH 81°8 28-712 29-0 2 = “ 95:2 * 27°588 27°59 27°8 3 , ” 231012 27°489 2 ar a 01°7 * 26-987 26°99 27:2 Pt 4 ” ” 04:4 * 25°215 25:22 25°4 4 35 = 13°8 23°626 0 a * 22°3 23-120 23°15 23°3 2 Os > 25°0 21°450 2 Los 340 * Rowland and Tatnall: 4891-191, 4390°605, 4386-436, 4385°814, 4385°553, 4383'526, 4372-363, 4371°366, 4361:597, 4361°371, 4354969, 4354-296, 4349°867, 4346°645, 4342°236, 4337-431, 4336-591, 4331-329, 4327°590, 4326-986, 4325-213. 74: REPORT—1904. RUTHENIUM—continued. | é . | Spark Spectrum | Reduction to Wave-length Intensity Vacuum Oscillation ' eee) = Z 5 ve a eed Ta, Fr Frequency re Spectrum xner an haracter carat! bead in Vacuo P Adeney Teva A+ ar 4320-972 | 4321°0 0 1:19 ) 64 23137°5 20°743 2 ie dies 378 * 20:045 4320°04 20°08 5 a Bl Ss 41°4 19:274 2 See hee 45°6 -* 18:596 18°60 18°7 4 118 i 49°3 * 16°792 17:0 2 elt oe 59°0 15219 =| 4 sa eae 67°4 * 14-468 14°47 14°6 4 3 33 71°4 13°067 0 eh Aan oP 79°0 12°632 12°8 2 Sane ss 81:3 12:047 0 oe as 84:4 11-0 1 9% ES 09°361 09°6 2 Y §: 98°9 08°567 08°57 0 er 65 23203'1 * 07748 | - 07-75 07°74 4 Pe * 07°5 06:2 1 5 >» 05:0 1 a ve 2150 0 es fe VEZ 01:297 O15 ] BP ie eo 42°3 4299°3 1 +5 53 *4297 ‘887 4297°89 97°92 8 a 55 60°8 96°860 96°86 971 2 oo + 66:3 * 96-090 96°09 96°05 5 aS 5 70°4 * 94955 94°96 94°95 5 ” » 76'6 94:268 | 4 . = 80°3 * 93°441 93°44 93°48 4 s = 848 92°419 92°6 0 As a 90°4 90°692 90°69 90:9 2 a a 99°8 TOR ZO9. ie Ione 874 4 ~ eS 23318°7 * 84:502 84°49 84°50 6 ” ” 33°4 | 83-4 In 3 5 SDD 82°36 82°6 | 2 35 3 351 * §82:093 82:09 82°3 2 i. ae 46°6 81°7 1 ” 99 79°6 1 HELA LA * 78°842 2 a a 64:0 *° 77415 776 2 ” ” 72°1 73115 | 0 Ws : 95°6 72-0 |. 2 ain : = 67:0 0 “ as 66°157 ” ” 23433°8 * 65°766 65°77 65°9 2 ” ” 37:0 63°551 63°7 | 2 ‘5 ag 48°] 60°166 60°17 60°3 3 “f as 66:7 * 59-152 59°15 59°20 5 ” ” 72°3 57°6 es ne 56°790 57:0 0 ef - 85:4 56:049 | 561 0 r An 89°5 55°868 5D"7 1 3 s 90°5 48 °304 48°5 2 99 6°6 23532'2 * 46°902 46°90 46°95 4 A “5 40°0 * 46:522 46°52 46°55 4 oA ap 421 * Rowland and Tatnall: 4320-036, 4318°599, 4816°801, 4314-471, 4307°746, . 4297°870, 4296-090, 4294-948, 4293-443, 4287-204, 4284-490, 4282°367, 4282-089, 4278°844, 4277-413, 4265°762, 4259°144, 4246-893, 4246498. ates ites ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. RUTHENIUM—continued. “I Or Spark Spectrum Bedaetion. to Wave-length Intensity Noa Oscillation Kayser) and ali Frequency is Aesan Adeney cant Character | , + 7 in Vacuo 4246°359 6 117 | 66 23543°0 * 44°997 4245°05 4245°2 4 9 ” 50°5 * 43°228 43°23 43°20 6 TOGYY , ss 60°3 * 41:23) 41°23 41°25 6 PP ” 71:4 40°194 40°4 0 Py ” 76°9 40°0 1 ” ” 38°5 In ” 29 * 36°838 36°84 37:1 4 oc = 23604°0 33°6 1 ’ ” * 32-478 32°48 32°6 4 ”9 ” 20°2 31:7 1 ” ” * 30°470 30°20 30°48 6 + os 31:4 * 29°472 29°47 29°6 4 ” ” Saft 28°2 1 ” ” * 26°825 26°82 27:0 Ca 0 ro os * 25°258 25°26 25°4 3 ” ” 60°6 * 20°838 20°84 20°85 4 5 op 85°4 * 17°438 17°44 17°40 7 ” ” 23705'5 * 14-610 14°61 14°60 4 5 3 20°4 13°8 1 ” iS * 12-240 12°24 12°20 5 SC op 33°7 09°5 1 ” ” * 07°797 07°80 08-0 i 55 ; 58°8 * 06°178 06°18 06°20 4 % 3 67°9 03°5 1 115 ss 03°2 1 % > * (00°069 00:07 00°05 v4 “ 6°7 23802°5 *4199°039 419904 4199-02 4 » ” 08-2 * 97°748 97°75 97°78 4 i 5 15°6 * 97:038 97:04 97°05 2 9 3 196 95:0 1 ” ” * §89°639 899 0 3s a 61°7 88°6 In : ” 84°5 In ” ” * 82-994 83:0 0 Sy s 99°6 * 82°807 1 3 rr 23900°7 * §82°621 82°62 82°8 2 5 3 01°7 * 76°615 758 Os 2 re #3 41°9 753 2 ” ” 74°5 In ” ” 73°4 1 ” »” 70°9 In ” ” . * 70°218 70°22 70°5 2 fp a 72°'8 69°3 1 ” ” * 67°666 67°67 67°65 5 114 35 87°5 * 67-030 67°03 67°3 0 Pr FH 91:2 65°1 In ” ” ? 64°'8 In » % : 61°817 61°82 61°80 } 4 PA Fy: 24021°3 59°5 | 1 Ft J 58°2 1 ” ” * Rowland and Tatnall: 4244:992, 4243-216, 4241:215, 4236°834, 4232-481, 4230°478, 4229-475, 4226°824, 4225:256, 4220°838, 4217-427, 4214-714, 4214°604, 4212-225, 4207°798, 4206:178, 4200-062, 4199°039, 4197-745, 4197-039, 4189-631, 4182998, 4182°812, 4182-623, 4175-604, 4170-219, 4167°683, 4167-047, 4161-823. 76 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length , ; Intensity bie Oscillation (Kayser) i. t : ects 4 Raney Are Spectrum xner an aracter e: in Vacuo P Adeney Hence A+ = "4150" 475 4150748 4150°6 1 1-14 | 6°7 24086 9 48°530 48°53 48-7 1 sath We OS 98°] * 46°956 46°96 46°92 4 35 ” 24107°3 * 45°905 45°80 45°95 4 = ES 13°4 * 44°335 44°35 4 6 BS 24:4 38-923 0 = 5 54:1 * 37°410 37°41 37°6 3 % » 62°9 35°8 Os 1 fc 3 35°2 1 ” ” 3 1IS7¢ In Fc a 29°2 In 113 i * 28:°017 28:02 28°2 2 ” ” 24217'9 27 -Gl 27°61 27°7 2 > ” 20°3 26°7 In . A 25°3 In Pa as 242 1 ” ” 5123297 23°23 23°4 2 AS 3 40:0 21:287 21°4 2 FA AS 57°4 * 21-147 21°15 2 A of 58°3 * 18-678 2 50) fates 728 14°285 145 1 PD _ 98°8 = 1137532 13°53 137 2 % ” 24303 °2 FP 12:S10 12°90 12°95 4 Sa a 06:9 09°796 10:0 0 oS 4 25'°3 * 08-218 2 rs or 34°6 * 08:003 08:00 08:2 4 ’ ” 35°9 06:065 06°3 0 » % 47°4 * 02-438 02°6 2 ’ ” 68°9 01:006 01°91 02:1 4 ” » 72:1 900-533 00°53 00°6 2 Fr on 80:2 *4097- 965 | 4097" 97 4098-00 4 cs 69 95°6 97:°185 97:97 97°5 2 ~ A 24400°1 95°3 In ” ” * 91-218 | 91-22 91°5 1 1-12 se 35°7 | 88:7 1 7 5 * 85:567 85°57 | 85°62 5 35 as 69°5 83°9 1 ” ” 82:947 83:2 2 55 - 85:2 EO OSOn Lime Wee Ovi 80°76 a oA 5 98°3 79:440 | 79-6 1 » ” 24506°3 78:2 1 9 99 * '76:900 76°90 76°90 5 ” ry 21°5 74-4 1 ”? 7 73°260 73°4 2 PY % 43°4 Eo 47 73°15 2 ” cores 44°] * 71-560 718 3 % a S| 53°7 * 68:529 68°53 68°58 4 1 es dH 720 oe VSP 67°78 68-0 4 a aa 766 * 64°616 64°61 64°9 4 Fr ae | 95'7 64-262) |) 964°265 64:5 2 Bg Fs p 97°8 * 63-160 | 63°16 63°3 2 53 35 24604'5 * Rowland and Tatnall: 4063°147. 4150°470, 4148-539, 4146-939, 4145-905, 4144-324, 4137°394, 4128-035, 4127°609, 4123-227, 4121-153, 4118: 666, 4113'542. 4112-905, 4108°224, 4108-001, 4102-443, 4100-530, 4097-948, 4097- 185, 4091-223, 4085-589, 4080°757, 4076°886, 4073:156, 4071-561, 4068°529, 4067-771, 4064:615 4064-263, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. RUTHENIUM—continued. ~JI “I Spark Spectrum Pegueton Wave-length | Intensity Oscillation (Kayser) eas aha : - an ; 1 ene, Are Spectrum Adeney Haschek raracter | y 4 a in Vacuo *4063°021 1 1:12 | 69 24605°3 4060°7 In FF a 58°2 In 2 33 * 54-216 405422 54°18 4 111 AS 58'S * 52°356 52°36 52°6 nt ” » 7071 * 51°566 51°57 51°56 4 ” ” 74:9 * 49°570 49°57 49°8 2 Bs 70 87:0 47°4 In ” ”? * 46:2 2 ” ” 43°5 2n ” 2” 42-123 2 ‘3 oA 24732°5 40°620 40°7 2 : ” 41°7 Be, 39°37 39°6 4 ’ » 49°3 37°892 38°2 2 > ” 58-4 36612 37°0 2 ih, ee 5 66:2 32°650 328 In Ve ae = 90°5 * 32:363 32°36 32°6 4 ” ” 92:°3 * 31147 31°15 31°4 3 ” ” 99°8 30°6 In > cc 28°584 28°8 2 a “5 24815°8 26°650 27-0 1 > ” 27°5 * 24°848 25°1 2 ss 2c 38°3 24°449 24°7 2 as Fi 41:1 * 24-001 24:00 24:00 4 ” 33 43°9 22837 2371 2 5 Fr 511 * 92°327 22°33 22°30 5 as cf 54:2 21°146 21°15 21:4 > 3 a ry 61:0 19°699 19-70 19°9 Ir 2 ” » 70°5 18-891 | 1 33 re 75°5 158 In 1:10 14:297 14:30 14:6 2 ” ” 24904°0 13871 13°87 14:1 2 ” ” 06°6 * 13°655 13°66 13'8 4 =p 5 07°9 11-882 09°91 11°6 2 ” ” 19°0 10°3 1 = A * 08-422 08°42 08°6 2 » > 415 * 07°680 07°68 07:8 3 » ” 45-1 * 06°749 06°75 07:0 ze 3 ” 50°9 * 05'789 05°79 06:0 4 » > 56°9. 04:7 In ” ” 03°15 03°3 In Bs ci 73-2 01:8 1 ” ” 3998-2 In 2 * *3996°650 3996°65 96°6 2 » an 25013°9 96°136 96°14 96°10 4 ” » dif 94-700 1 ee °p 26°1 89°344 2 35 a3 59°7 * 87:959 87°96 | 87°95 4 55 omit 133 68°4 * 85-011 85°01 | 85-00 5 aa a 863 84°840 | 1 BOW 88-0 82°372 82°37 82:1 3 » 3 25103°5 * 79°591 79°59 79°58 2 HE Fy. 211 * Rowland and Tatnall: 4063°023, 4054:212, 4052°354, 4051°561, 4049-570, 4045-949, 4039°365, 4032-362, 4031-155, 4024°847, 4023°986, 4022-315, 4013°652, 4008-418, 4007:686, 4006-748, 4005-793, 3996°128, 3987-942, 3985-007, 3979°571. 78 REPORT— 1904. RUTHENIUM—continued. | Spark Spectrum oan ok Wave-length | Intensity Oscillation (Kayser) Pecan ae, 7 ‘e Seeney Are Spectrum | Adeney Haschek aracter |) 4 a4 in Vacuo *3978°620 3978 62 | 3978°61 4 1 LOR ied 25127°3 * 74°646 74°65 74:7 5 1:09 pat 52°3 72568 4 5 = 65°5 70°0 1 Vs ” 69°936 69°94 0 33 re 85'8 68°64 Ca 68°6 Ca 2 3 33 * 65:057 65°06 65°05 2 oe “ 25213°2 61°84 62°3 zs Bs 33°7 * 57-596 57°60 57°7 4 a a 60°8 57°376 575 2 a “c 62°2 * 52°850 52°85 52°9 0 oe * 91-1 52°436 1 ne 7:2 93°6 72 olspl 51°35 51-4 | 4 3 3 25300°7 * 50-548 50°5 3 ne Ss 05°3 * 50°366 50°37 50-4 4 a A: 06°9 * 507192 50°3 2 33 A 08-0 * 49-564 49°56 49°6 2 Neate - 33 12-1 * 46-456 46:5 2 ee : 32°0 * 45°723 45°72 45°73 0 ar? = 36°7 * 44°341 44°34 44-4 2 a of Be 45-6 43:2 In 5 ae | * 42-209 4221 42°3 4 bs a 59°3 * 41-811 41°81 42-0 3 fe 3:24 61:8 39-268 39:27 0 ” ” 78:2 * 38°045 38°05 38°2 3 6 * 86:1 34352 1 os af 25409°9 33°80 Ca 33°80 Ca 4 1-08 35 33°06 33°1 1 A or 18°3 32°444 0 = of 22:2 ol 936 31:94 31:93 4 ss ns 27°6 26°581 F 0 # 33 60:2 * 26:071 26:07 26-05 6 bas ” 63°5 eee 24-7'76 24°78 24°9 2 I 6} 2 72:0 * 23°636 23°64 23°62 6 454 x 79°4 22°476 22°5 1 5 35 86°9 21-061 21:06 21°71 4 ” ” 9771 * 19°711 0 2 + 25504°9 16°7 In = 25 * 15-000 15:00 151 4 yopuaal\aeaes 35°6 145 9 ” * 12-248 12:25 12°3 3 ”» ” 53°5 11:279 114 3 gees “ 59-9 * 09-229 09:23 09:22 5 | oe ” 73°3 * 08-907 08:91 09-0 3 eee et aice: 75°3 06:9 In = = 06°7 In » 9 067141 063 1 25 AD 93°4 02:4 | 1 at ne * 101-393 01°39 01°5 | In ZA A 256246 38989 Pt | 4 39 93 * Rowland and Tatnall: 3978-600, 3974°650, 3965-055, 3957°600, 3952-844, 3951°360, 3950°556, 3950°371, 3950°183, 3949°560, 3946-468, 3945-730, 3944-339, 3942:215, 3941°819, 3938-060, 3933-700, 3931:920, 3926:062, 3924-774, 3523-615, 3920-060, 3914-990, 3912-252, 3909:222. 3908-906, 3901:391. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ' RUTHENIUM—continued. ELEMENTS. 79 | Reduction to | | Spark Spectrum Wave-length , | Intensity Maou Oscillation eget) = 7 ae ae | : and : “ | Frequency Are Spectrum | Adeney Hecchek | Character ) 4 == in Vacuo *3898:'500 389850 | 3898°6 In 1:08 | 7:3 25643°5 Penoioo0! | | 97:39 97°5 3 a is 50°9 EON) lio dee o's dee 95:1 | In 1:07 5p 94-387 94°39 94°5 In FA ef 70-6 * 92-916 92-92 93-0 2 33 pe 80-4 * 92366 92°37 92°35 2 - . 83°9 * 91:567 91°57 91°6 4 = £ 89°3 * 90-350 90°35 90°4 2 ae 7 97°3 89°6 4 2? ” * 87-962 87:96 88-0 1 ue es 25713°1 876 2 ” ” 86°5 1 ” ” * 84-849 84°85 84:9 1 “ A 33°7 * 84-203 84:20 84:3 2 ~ oe 37°9 | 82:3 2 ” ” 80:95 81:0 1 oa nh 59°6 80:2 In #3 4 79°15 79:2 2 FA A) 71:1 * 76:23 76:2 1 5 e, 90:0 z pene 73°65 73°6 1 a [es 25808:1 72: 1 ” ” 16-2 71-4 1 » » | 71:0 ] 29 29 ; 70°8 1 ” ” * 67:965 67:97 67:95 3 » ” 46:2 a 65°55 65°6 2 - 33 62:2 63°8 In $3 ss * 62°82 62°80 6 Pe Ss 80:5 62:0 1 | 60°8 2 oe) 2”? 60:0 Fe 1 A i 59°8 1 29 ” | 58°8 ] ” obs | * 57-689 57-69 57°65 5 as ” 25915-0 572 1 alata 56°6 2 1:06) 53 54:9 1 ” ” 53°4 In 35 a x 52°26 52°3 2 af ie 51:4 51:3 1 ”? ” e 50°56 50°50 4 Ss gi 62°9 49°6 1 A A . 49-1 1 ONE: { 48:2 1 2? ” 46°7 2 "7 » | 43:2 1 2? ” | 42:'8 1 ” | ” | 42°6 1 3 ” 41-1 2 39 | > 40°9 2 99 9 * 39°815 39°82 39°82 4 ee es 260356 38°8 2 » 99 * Rowland and Tatnall: 3898-498, 3897-383, 3392-915, 3290°347, 3887:960, 3884-849, 3884-207, 3876-229, 3873-660, 3862°819, 3857°680, 3852-260, 3850°561, 3839-832. 3892°364, 3891°564, 3867°962, 3865°547, 80 REPORT—1904. RUTHENIUM—continued. Spark Spectrum Renee Wave-length Intensity Oscillation (Kayser) | and ” S arae | eikequency ae Spectrum Adeney | ee Character | , 4 | <~ in Vacuo *3838°215 3838 22 3838-2 1 1-06 | 7:3 260465 368 1 “5 os 36°71 1 as 3) = 35°19 35:2 2 =D “5 67:0 32°3 Pd 1 a a eist-946 | 31-95 31°82 4 a = 89-1 31:0 1 ~ 4 30°4 1 oo a | | 29°5 1 9 ” * 28°8359 | 28°86 28°8 2 a 23 26110°1 be 28-0 Fe 1 53 5 27°5 1 ” 9 26°3 1 ” ” Ee2p-O70 |) 2508 25:05 1 ” » 35°9 24°5 Fe 1 ee a * 22:225 | 22:23 22°19 4 ” ” 55°3 | . 20°50 20°5 Fe 1 +6 aS | 20-00 19°8 1 = » 70°77 SIO 184. | | 19-18 19:2 2 cf a 76° | 18:5 Rh 1 s 5: | 18-1 1 2 ”? * 17-439 17°44 eum 3 55 =D 87:9 169 1 | 1:05 | 7:4 | 164 | 16:3 1 Neate at 95:4 | 15:90 16-0 Fe i ” ” 98-7 a 15:0 150 2 =e “ 26204°9 j) 4s} 1 - re Ay 13:20 13-2 1 jonas a 17:3 * 12-874 12°87 12-83 3 ere ses 27°3 12-0 1 ” ” | 11°3 ay = See Lanes = | 08-82 08-7 2 Pee 5 47°4 | 06-7 1 ” ” * 05°57 05°5 2 s 69:9 | 04°70 | ” 2” | 04-20 ” » ~ 03-40. 03°4 2 6 no 853 01-4 1 ” ” 3 | 00°39 00°38 Ir 4 > x *3799-486 | 3799-49 379942 4r “ os 26311°9 * 99-040 99-04 99-05 4. “e os 15-0 * 98-205 98-21 98-18 1 5 “5 20°8 * 95°327 95°33 95:3 0 ; ”» 40°7 2 95:00 95-0 2 a as 43:1 93°3 Rh 1 fe ll 6 * 90°649 | 90°65 90-62 5 et ih 733 | 89°8 1 ” 22 | 88°8 1 “5 | | 88-0 Fe 1 ” | ” | * "867193. | 78619 86-27 5 ” » | 26404-4 | 84:30 84°4 1 ab fed 17:3 | 83-5 1 sl | * Rowland and Tatnall: 3838-201, 3835-191, 3831:934, 3828-849, 3828-319, 3825°074, 3822°233, 3819°173, 3817-424, 3814-976, 3812°869, 3808-824, 3805-570, 3803°326, 3800°393, 3799°489, 3799:042, 3798-189, 3795-316, 3795-052, 3790°655, 3786°194. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS, 81 RUTHENIUM—continued. Spark Spectrum Beteetion Wave-length Intensity Oscillation (Kayser) and ob Frequency Are Spectrum Adeney 2 ela Character | ,, | 1_ in Vacuo 3782:891 3782'89 3782°8 0 1:05 | 7:4 26434°3 81:313 81°31 81:25 3 ” ” 38-4 80:20 80°1 1 i 3 46-2 - 78:90 78:9 2 “E <5 55:3 78:00 78:0 2n a a5 616 aid 123 77°72 77°78 3 ” ” 63°6 74:6 1 1:04 35 * 73°306 73°31 73°4 0 ” ” 94:5 71-244 71°3 0 oe 15 26509:0 70:0 In x PS 69°3 1 ” » * 67:500 67°50 67:50 4 a3 3 353 65-938 66:0 0 5 6 46°3 * 64:179 64:18 64:3 1 a es 58:7 64:00 64:0 Fe 1 os zs 62°7 1 ” ” * 61:644 61°64 61:70 4 5 As 76°6 * 60-178 60:18 60°15 4 a3 FS 87:5 * 59-976 59:98 60:00 2 o -) 89-4 58°50 58°5 1 a :5 98:9 57°80 57°8 1 ” ” 26603°S 57°40 57°4 In = > 06°6 * 56-083 56:08 56:07 4 * ” 16:0 * 55865 2 * a 186 * 55-241 55:24 55:2 3 53 3 21:9 * 53°695 53°70 53°70 4 ” ” 32°9 53:00 53°0 1 4 a5 378 52°70 ” ” 52°00 52:0 1 33 Bs 45:0 50°60 50°6 1 a sy 54°9 49°60 » 9 48°40 ” ” 48-15 ” ” 47:15 47-1 1 on 2 79°4 46:372 46-4 2 . a 85:0 46:00 2? ” 45°75 45°72 6 a5 : 89-4 44-550 44:55 44:55 2 » » 97:9 * 44-367 44:37 44:35 2 es ” 99:2 43°45 43°5 1 es F 26703°8 * 42-938 42:94. 42:95 4 “A 5, 09°5 * 49-435 42°44 42°45 5 “3 -e 13-0 | 40°5 1 ” ” * 39-622 39°62 | 39-60 4 “ i, 33-2 * 39-058 39:06 | 39-1 2 ss 4 37:2 * 38-774 38°77 38°8 Pd 2 ‘i 3 39-2 * 37:904 37°90 2 1:03 rs 516 * 37:°548 37°55 37°5 3 5 s, 48-0 35:00 Fe 35:0 2 is 5 663 34:70 34°6 2 an Pa 684 33°90 34:0 In 3 Ss 74:1 | * 33-187 33:3 2 ata 792 | * Rowland and Tatnall: 3778-853, 3777°729, 3773°314, 3767:495, 3764173, 3761°655, 3760°163, 3759-979, 3756°075. 3755°868, 3755:234, 3753-684, 3744-363, ae, 3742°422, 3739°610, 3739:057, 3738-773, 3737 902, 3737 540, 3733°188. G 82 REPORT—1904. RUTHENIUM— continued. Spark Spectrum Rateeee = Wave-length Intensity Oscillation (Kayser) and | Frequency Are Spectrum Adeney pes Character | ) + == | in Vacuo | #3732170 | 3732:17 2 1:03 | 7:5 26786°5 * 31:045 3731-0 2 a EF 94°6 * 30°745 30°65 3 5 53 26803°6 * 30°587 30°59 7 » 76 04°6 * 28°170 28°17 28°15 5 “ 45 15°3 27°33 OAT UT 27°08 27°15 4 ” ” 23°1 * §26°254 26°25 26°10 4 ” ” 29°0 25°59 25°6 Ir 1 = + #25115 25°12 25°1 4 ai seas 37°2 24°663 2 a , 40°5 24:110 24°11 24:2 4 “ “5 44:5 22°80 22:9 1 ap “ 53°9 22°458 22°3 1 a 9% 56°4 * 19°474 19°47 19°52 4 Sra 3 759 18-60 18°5 1 + re 84:2 *) 17°823 17°82 178 2 ie is 89°9 eh ila 17:15 17:13 4 > ” 94°6 16°583 ] * a 26901°6 216523 | 16:32 16-4 3 ” ” 00°7 AENLS-703: jy .bs70 15°7 3 $3 5 07:2 14-788 15°0 1 ‘5 3 11-6 13°6 1 ” ” * 12-443 12°44 12°5 3 a oD 28°8 11-2 1 ” ”» | 10°5 1 53 é | 09°35 09-4 1 a ay 159] Nita | 08°15 08-2 1 ’ Pr 58-0 07°05 ” 2 * 05:506 05°51 05°5 2 » » 19°2 * 03344 03°34 03-4 2 v > 95°0 5 03:1 ul ” 2 * (02°369 02°37 02°5 2 Fy a 270021 02:0 In 43 5S * 01°457 01-4 2 a 5 08°8 01134 01:13 01:2 2 + os 111 00°487 00°5 i 5 sp 15°8 3698-016 3698-0 2 1:02 = 3a°9 *) 97°92] 3697-92 3 “ - 34°6 * 96°738 96°74 96°7 4 3 an 43°3 96-0 1 A ae +) 94°30 94-1 1 +) + 61-1 * 93°740 93°74 93°7 2 ” » 65°2 92-90 33 6 92°60 92°5 Rh 1 ” ” 91-10 SF] 1 as 3 84°5 90°179 90°18 90-19 Pd 1 t op 91:3 87:5 1 ” = | 86°742 86°74 86°6 1 3 99} ae LUG * 86-109 86°11 86-1 4 5 et 20°6 85:204 85-20 2 = ay 27:9 * Rowland and Tatnall: 3686-086. 37327170, 3731:048, 3730°737, 3730°577, 3728-173, 3727073, 3726:239, 3725°117, 3719:468, 3717°822, 3717:146, 3716°314, 3715-705, 3712-444, 3705°496, 3703°343, 3702°369, 3701:456, 3697-906, 3696-725, 3693-734, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS 83 RUTHENIUM—continued. Spark Spectrum Kee 4 Wave-length Intensity Oscillation (Kayser) Hones and ne Tae Frequency Are Spectrum Adeney Tianchek aracter | y+ <- in Vacuo | 3683-730 3683-5 ! cil 1:02 | 7:7 27138°7 82:5 In 35 5 81:8 In 3 es * 78-465 367847 78:4 4 ” ” 7175 78°222 78°22 78:2 2 3 % 78°6 78:140 2 e 53 80:0 a 77100 77:10 771 2 ri i 86°6 * 76817 76°82 76°7 3 ” ” 89:9 76°4 1 ” ” 75°60 75°7 1 is 55 98-7 * 75°408 75°41 754 3 % ” 27200°2 * 72°525 72°5 2 5 5 21°6 72°210 72°3 2 33 # 23°1 * 71:363 71:3 2 a . 30°71 * 69°694 69°69 69°79 4 ” ” 42°5 68-890 68°9 1 3 5 55°8 67:1 1 33 3 65:4 In a Ee : 64-1 1 ” ” * 63°526 63°53 63°53 5 2 ” 88-4. * 61-727 2 on 33 27301°8 * 61-486 61°49 61°57 a 2 ” 03°6 * 60°964 60:96 61:0 3 Fe 3 07°5 60°25 60-2 2 rr Ss 128 59°55 ” ” 59°0 1 ” ” 57-716 57°72 57°82 1 101 Ae 32°9 57°315 57°32 574 2 2 ” 34:8 56°50 56°7 1 oo FP 40°9 » 56:112 2 3 3 438 * 54-559 54°56 | §4°55 4 Fr - 55°6 53°857 53°86 53°9 2 ” ” 60°6 53°00 53°0 1 my 5 67:1 §2°816 0 eS r; 68°4 §2°627 0 a 35 69°9 em «62-465 52°47 | 62°5 3 re 3 Alc * 50-473 50°47 50°48 4 % 2 87:0 50°0 1 ” ° 49°75 ” ” 48°85 ” ” 48:0 Fe 1 se 33 475 1 ” ey) * 46:266 46:27 46°3 3 ” ” 27417°6 45'827 | 1 er. 3 20°9 7 | | 413 1 er ” * 40-791 40°79 i 740"7 | ct BEM) os 51:3 i) * 638°163 38°16 38°2 2 - 78 78°6 | * 37-614 37°61 37-62 4 smh | ea 82-7 | 37°0 1 » ” * 35°661 35°66 35°6 4 as 3 97°5 * 35°093 35°09 35°10 a ” > 27501°8 * 34-063 34:06 34:1 4 5: “ 09-6 * Rowland and Tatnall: 3678:456, 3677-098, 3676-808, 3675°400, 3672°521, 3671°355, 3669-688, 3663°520, 3661-721, 3661°525, 3660-961, 3654-549, 3652-460, 3650-465, 3646-262, 3640-786, 3638-161, 3637 ‘612, 3635°658, 3635-084, 3634064. ’ G2 84. i REPORT—1904. RUTHENIUM—continued. + Reduction to Spark Spectrum , agen aes Wave-length Intensity | Oscillation Li sedeeadl Exner and | Gh ae al ae Are Spectrum Adeney ingghak aracter | ) 4+ ar in Vacuo 3632°545 3632°55 36326 i 1:01 | 7:8 27521°1 * 31°860 31°86 31°9 3 PP » | 26:3 31°65 Fe al-7He | Fp ees | 29°352 | 1 ” ae. | 44:8 | 288ir | a a | 28:50 ” ” | | / 298°1 | | ” ” | as 7425 | 27°43 Pay fas | 2 | ” ” | 60:0 * 26'897 26°90 26°88 5 | 99 ” 71:0 * 25°345 25°35 | 25°30 5 7 Bae 75'8 23995 | 0 ap 5 86:1 23804 | 23:80 t= 42359 4 PP aa = 875 * 90-426 | 20:43 | 20:4 4 2 x 276132 * 19°334 19°33 | 19:4 4 a BS 21:6 | 18-90 Fe 18-8 Fe |) pe ” eT O9O7 Se 7209 172 4 1:00 “ 38:7 / 15-4 3a) ease 15°05 | ” rr) | 14-486 14:5 1 oy, we 58-6 | 13°3 1, 99" Se ee 12°6 / ” | ” 12°30 1 aay 7 11°6 a9) el heecay 10°8 1 | ” | ” 09°6 Pd 1 | Aspe] pre *3609°241 2 eo We to ee 98°8 * (08-862 08°86 08:9 2 9)! aay 277018 06°6 1 | sey ” 06-297 06°3 1 | 9 + 21°4 * 05:792 05:79 05°8 Ir 3 ° yy 25°4 03°3 1 ” ” 02°6 1 r “5 * 01°627 01°63 01°7 2 ” ” 57-4 00'8 1 ; ” *3599°913 359991 359995 4 os % 70°7 99-548 0 “5 5 73°4 99-0 1 ” cy) 97°5 1 » » * 96:315 96°32 96:28 5r 33 Sy 98°4 95°8 1 eal ie 9S 07 93°18 93°17 4r “1 79 27822°6 91:58 91:7 1 x 2 35:0 91°044 91-04 91:0 1 53 np 391 90°7 1 | one a * 89:°370 89°37 89°37 4 “ ah | 52-1 87344 87°34 87°34 2 Ay 55 67:9 85°5 1 39 9 85°3 1 9 ” 85:17 85:0 1 as x 84°8 * 84:21 84:3 2 + oF 92°3 81:31 Fe 81:4 Fe 1 oA st * Rowland and Tatnall: 3631°859, 3627-433, 3626°886, 3625°339, 3620-434, 3619°348, 3617:100, 3609-247, 3608°878, 3605°785, 3601°630, 3599-914, 3596-342, 3593°178, 3589-360, 3584349. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 85 RUTHENIUM—continued. Spark Spectrum aes Bee : Wave-length Intensity Oscillation . (Kayser) Pale ot ee and i on i Frequency | Are Spectrum Adeney Huschek Character | ) + ae in Vacuo *3579°923 3579°92 3579°8 0 1:00. |) 7:9 27925°7 78°90 78°7 1 ” 5 33°7 i 77°55 776 | 1 0-99 Fs 44:2 77:10 771 | 2 nf a 47°7 76:17 ti 33 » 75'1 1 a0 |) ce * 74744 74°74 74:7 3 BN aes 6671 74:00 ” | EE) 73°8 Ir 1 Seana css 73°3 1 » |» 72°13 72:1 1 7” np 86°6 5 719 1 ” ” * '70°743 70°74 70°74 1 of “ 97°6 68°6 1 ” ” * 67:308 | 67°31 67°3 2 » » 28024-4 66°59 66°6 2 Ais oe 30°0 | 65°5 Fe 1 AS - * 64°945 64°95 65°0 0 2 Fy 43°0 * 64-714 64°71 64:7 1 os a 44°8 * 64:517 64°52 64-6 0 ” » | 464 | 63°7 1 ” ” | 63°3 1 53 Sor) al 62°75 62°7 1 op ae 60°3 * 62°035 62°04 62:1 0 ” » 65°9 61°83 61°7 1 oS oe 67°6 61-2 1 » ” 60°85 60°8 Os 2 Fe of 754 60:00 | 60°0 1 a =p 82:0 } 59°8 1 ” ” * 57:203 57°20 | 87:2 0 Ysa ” 28104°1 57°0 Lu ” » * 56°779 56°78 56°8 0 ” 2 O7°4 * §4:002 54:00 53°9 1 fr a 29°4 50°73 | 60°7 1 cs 3:0 55-2 * 50-420 50°42 50°4 2 he ce 58-4 49-90 49°8 1 Br aa 61°8 48-70 48:6 1 a 53 713 * 47°136 47°14 47:1 1 2 » 83°7 45°9 2b | ” oF) 42°7 1 | ” 2? * 41°788 41-79 41°7 3 » >» 28226°3 41-1 1 ” 9 40°9 1 ” ” 40°3 1 ” » * 39°518 2 = of 44:8 * 39°418 39°42 39°40 2 ” ” 45:2 * 38°100 38°10 38:03 3 %3 2» 55°8 36°78 36°7 2 0:98 || 55 66°3 * 35:985 35°99 36:0 2 ” » 12°77 * 35°529 35°53 35°5 2 ” » 76°3 * 32°965 32°97 32°95 2 ” ” 96°8 * 31°545 31°55 31°5 3 ” ”» 28308°2 29°26 29°4 2 a -e 26°5 * Rowland and Tatnall: 3579-924, 3574-748, 3571-913, 3570°748, 3567-309, 3564-949, 3564719, 3564°509, 3562-043, 3557-207, 3556°773, 3553°998, 3550°419, 3547-131, $841°777, 3539°521, 3539415, 3538-100, 3535°988, 3535°537, 3532-962, 3531-543, 86 REPORT— 1904. RUTHENIUM— continued. Spark Spectrum Rees ue Wave-length Intensity Oscillation * (Kayser) n and 7 Frequency Are Spectrum Adeney patie Character | , . =e in Vacuo *3528°841 3528°84. 3528°7 2 0-98 | 8:0 28328°9 28°05 ” 2 27°39 27°3 1 on Ar 41°6. 26°6 i ” » 26°4 1 »” ” 25°7 In 3” 33 24°62 24°6 2 oe a 63°8 24:16 24-0 2 aa ss 67°5 22°4 1 ” ” 222 1 ” ” *' ~20':285 20:29 20:22 4 “p % 98:9 * 19°795 19°80 19°80 3 ao A: 28402°7 19°10 19°] 1 a 4: 08°4 18:00 ” 2 16°046 16:05 16:0 0 ” 3 33°0 152 In o ar 14911 1 pod Ne tes 42'2 * 14:649 14°65 14°60 4 ” ” 44:3 * 13-807 13°81 2 9 9 512 13°0 1 ” ” 11°5 1 ” ” 10°5 In ” ” 09°870 2 - 8:1 83:0 09°35 09°30 4 ” > 87-2 07°3 In ” ” 06:9 In ”» ” 05°9 In ” 2 04°65 ” ” 03°60 ” ” 02-578 02°58 02°5 2 ” ” 285423 01°510 1 or “ 53°1 *3499-098 3499°10 3499-05 10r 9 ” 70°7 * 98-103 98°10 98-0 1 0:97 rr) 79°6 * 96-293 2 ” 22 93°6 * 96:145 96°15 96:1 2 ” ” 94:8 * 94-410 94:2 3 Ay PT) 28609°-0 93°377 93°38 93:2 2 ” ” 17°5 92°256 92:26 92:0 1 ” ” 26:7 90°879 90°88 90°8 1 ” ” 46°8 90°30 90°3 1 ” ” 42°7 89°895 1 oo ; 53°7 88:2 In ” ” 87:87 87°7 1 ” 33 62°7 86948 2 ” ” 70°3 86°360 2 ” ”? 74:0 85°6 In So ” 83°65 83:7 1 39 a5 97°4 Sees 463 83°46 2 op oo 98:9 * 83:317 83°32 83°3 2 ’ 5 28700'1 82°499 82°5 2 + BS 06:8 82:0 1 ” 2” 81°66 23 9 * §81:465 81°47 81:42 4 ” ” 15°4 * Rowland and Tatnall: 3528832, 3520-286, 3519°785, 3514°631, 3513-799, 3499-095, 3498-086, 3496°272, 3496:°131, 3494-404, 3483-438, 3483317, 3481°449. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. RUTHENIUM — continued. 87 Reduction to Spark Spectrum Wave-length P 2 Intensity | Yeenum Oscillation (Kayser) noe ae : i an | er i es Sat) Are Spectrum Adeney Haschek aracter | y 4 == in Vacuo 3481:044 0 0:97 | 81 28718°'8 80°295 3480°30 3480°2 2 ” ” 25:0 79°45 79°5 2 AB as 32:0 776 In ” ” 77°350 hee 0 “5 =, 55:0 75:00 750 1 AG a 68:9 * 73°900 73°90 73°90 5 ” ” 78:0 73°45 73°4 1 a * 81:7 72843 72°84 72°7 2 ” ” 86°8 72°39 72°4 2 e a 90°5 70:20 : Beedle: 70-0 1 As, 69°5 1 55 a5 68°1 In > . * 67:190 67°19 67°3 2 5 8:2 28833°6 65°437 65°44 65°5 1 cpmel| Ree 48:1 63°751 0 os oo 62:2 * 63°289 63°29 63°2 4 : 3 64:0 * 62-208 62:21 62:1 2 ” ” 66°1 61°55 ” ” 59°736 59°6 2 ay “o 95°7 58°3 lb 0-9 on 57°849 0 ” Hs 28911°5 573 1 ” ” 57:05 ” ” * 56°769 56°77 56°7 4 P. A 20°5 55°888 2 a ze 27°9 55°548 55°6 2 nh iy 30°8 53°373 0 Ay A 49:0 53°056 53:06 53°0 4 % “5 51‘7 52°1 1 93 » 51:014 0 A ne 68°8 49-608 0 an B 80°6 * 49°105 49°11 49°1 4 os = 84:9 46°96 46:8 In vs ; 46°630 2 m9 oh 29005°6 46:227 46°3 2 Ps Fe 09:0 46:095 46:10 0 ne oO 10°1 45°675 0 “5 ne 13°7 45453 1 “ re 16°4 | 45:3 1 ” 9 44°574 | 1 “5 % 23°0 43818 | 0 cE Ss 29°3 43309 0 a) ro 33°6 41-942 0 % 5 45°3 * 40°361 40°36 40°4 f ” ” 58°5 39°835 2 ie a5 63:0 38°819 0 ae Ay 715 * 38-522 38°52 38°5 4 ” ” 74°1 * 36°886 36°89 5r =5 ae 87:9 * 36°481 2 = 55 91°3 36°237 0 5 ss 93°4 * 35°340 35°34 35°3 4 cs 3 29101:0 34:93 f ¥ * Rowland and Tatnall: 3473-892, 3467:192, 3463:286, 3462:186, 3456-763, 3449°107, 3440°351, 3438-510, 3436°883, 3436-475, 3435°327, 88 REPORT—1904. RUTHENIUM—continued. Spark Spectrum gett ie Wave-length | Intensity Oscillation erect) z Reda ais : 5 ay Arc Spectrum Adeney Haschek aracter | y 4 == in Vacuo 3434°325 3434°33 0 0:96 | 8:2 29109°6 * 33°406 33°41 3433°45 4 ” ” 174 * 32-909 32°91 32°9 4 ” ” 21:5 32°560 32°5 0 “6 > 24°6 * 32°354 32°35 3 3 7 26°2 31°905 0 FY) “ 37°3 * 30°910 30°91 31:05 4 . “6 38°5 30°568 30°6 0 as + 41-4 * 29:702 29-70 29°6 4 os oe 48°8 * 28-790 28-79 | 28°60 2 “o = 56°5 * 28°476 4r » | 29209°4 20°881 0 “p 53 23°9 | * 20:243 20:24 20:2 4 + = 29°3 20:0 In 99 | * 19°394 19°39 2 oc + 36°6 *" 187125 18°13 18°] 2 , ” 47°5 17°790 1 0°95 6 50°4 * 17:493 17°49 17°45 7 % ” 52°9 16°90 16°7 1 eS aca 58°0 * 16°329 16:33 16°4 1 aS “5 62°9 15°6 1 ” ” | * 14:787 14°79 14-7 3 op as 76:1 145 1 ” ” 14:422 2 LP 95 8:3 79:2 14:130 0 as sein 80°7 13°870 0 “p seal 75°4 * 12:947 12°95 12°8 3 or “ 91°9 12:221 2 “co of 98-1 e768 si7 116 4 % 9 29302°0 10°84 10-7 2 AG 55 100 10-10 ” ” 09-707 2 1 As 19-7 * 09420 09°42 09-42 5 x 22°2 09-2 2 ” ” 07-042 0 0 AS 42°7 2 Wayets 2 3 oS 45°3 * 06-017 2 = BS 51°5 05°426 0 s5 BS 56°6 03°924 03°7 1 “n = 754 02:7 1 cy) ” 02-00 4 p 0 * 01:878 01:88 3 = Ps 87:2 * 201-637 01°64 | 2 = 3 89°3 01:°304 O14 0 a “O 921 00-890 2 99 » 95°8 00°738 | 1 oO FD 97:1 * Rowland and Tatnall: 3433-397, 3432-896. 3432-348, 3430-908, 3429-689, 3428°769, 3428°460, 3426-089, 3420-236, 3419-389, 3418-117, 3417-466, 3416-320, 3414-782, 3412-939, 3411-780, 3409-424, 3406-731, 3406-025, 3401876, 3401-646, SE ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 89 RUTHENIUM—continued. Spark Spectrum Wave-length (Kayser) Are Spectrum Adeney 3400°116 | 3399°15 3399°040 99°04 98-470 96-967 96-060 95°465 * 92°654 92°65 * 92:032 92:03 91-042 * 89°639 89°64 89-250 89°25 * 88:849 88°85 87:967 87:97 * 87°368 86:390 * 85°838 * 85°609 85°61 * §85°303 85°30 83:053 81-040 * 80°301 80°30 * 719°747 79°75 79°402 * 78-165 78:17 76186 75°377 75°036 * 74°790 74°79 74115 74:12 73°45 72-922 72°92 * 71/990 71:99 71:°793 70°720 70°72 70°19 69°813 69°433 69°43 * 68588 | 68:59 68:053 67868 65°470 65:163 64:°933 * 64:230 64:23 * 62°457 62°46 * Rowland and Tatnall: Reduction to Intensity Vacuum Oscillation and yp Luc aay eeequency; Exner and | Character EH i_ in Vacuo Haschek xr 0 | 0°95 | 8:3 29402°5 3399°4 1 + { 0 ” ” 11:8 98°9 2 haa a ” 0 ane a ae 16°7 4 ee oe 32°2 0 ” | ” 37°5 95°3 0 re es 42°6 94:0 In ae “ 92°68 4 “E - 67:0 92:0 2 3 % 72-4 2 op a 81:0 89-6 4 ef, a 93°3 89:3 0 op 5 96°6 88°8 4 fr Lp 29500°1 88:0 0 s HD 07°8 87°3 2 Ar, a 13:0 86°3 2 én 3 21°5 2 ” ” 26°4 85°7 2 a % 28°4 85:2 4 inane “F 31:0 0 | 9s 9% 40°6 82°3 1 ee 9 81:6 1 ” ”> 81:0 2 ees 7 68°3 80°3 4 | ” ” 74:7 79°6 4 - FS 79°6 79°4 2 4 % 82°6 78:2 £ 5 FL 93°4 1 | 0-94 + 29610°8 2 ” ” 179 2 ” ” 20°9 74:7 4 “h ss 23°1 2 ” ” 29°0 73°5 1 oc Pr 34'8 73°3 Pd 1 - PP 0 ” ” 39°5 4 cry ” 47°7 718 0 AL ; 49°4 2 99 99 58:9 70°10 4 5 5 63'5 69°7 2 3 Fr 66°4 69°40 2 re ae 70:2 68°58 6 oc 7 776 0 ” ” 82°3 0 3 84:0 0 ” 29705°1 0 + as 07°8 648 1 es 7 09°9 64-1 4 ee ; 62°3 2 ae 7s 16:0 3392°672, 3392°032, 3389-644, 3388-846, 3387:369, 3385°836, 3385-608, 3385-207, 3380-308, 3379-744, 3378-170, 3374-790, 3371-992, 3368604, 3368°524, 3364-243, 3362-473, {Ue REVORT— 1904. RUTHENIUM— continued. Spark Spectrum Bes Wave-length Intensity Oscillation (Kayser) and Sa |) edeency, Are Spectrum Adeney Peco ead Character | , + to in Vacuo *3362°142 33621 4 0°94 | 8-4 29731°7 61:295 3361°30 61:2 2 a 5 34°5 60°20 60°0 1 > “p 42:0 * 59-230 59°23 59°30 6 ” 8°5 592 58°110 0 | ” ” 70:2 56°598 2 aS este 838 56327 56°3 2 + “5 86:1 55°803 55°7 2 A | 90°7 54001 2 an x 29806°6 * 53°776 53°6 4 + a 08°3 53°444 53°44 53°3 2 ” ” 116 63:°122 1 ry of 14:5 * 52-060 52°0 4 a “5 23°9 50°681 2 ss ae 36°3 50°363 50°36 50°30 0 rh 2 39°1 50°236 2 29 “p 40-2 49-822 49°82 0 ” ” 43°8 * 48°833 2 9 ay i 52°6 * 48145 | 48°15 48:0 2 4S * 58°8 * 47-748 * 47°75 47°6 4 “ is 62°4 46°360 0 of of 73°9 * 45°450 45°45 45°3 4 ” ” 83°7 44:934 2 “5 fF 87:5 * 44°666 44°67 zt os a 89:8 43°32 43:2 2 a rr 92°9 42-999 0 “p eH 29904°8 42854 42°85 42-7 0 less Pee | 06°4 * 41:809 41°81 41°7 4 | 99 a» | 15°4 * 41:361 413 1 2 “ 19°3 * 41:230 2 rh er 20°4 39°932 39°93 39°8 2 ” 255) 0 37°6 * 39°691 39°69 39°72 6 ” ” 34°4 39:092 0 ” | ” 39°7 38°849 2 0:93 ep 41°9 38°3 In es 1! aces 37:°963 37°96 378 4 PY 3) ees 49°9 36°774 36°6 3 Sen Takes 60°6 36°296 2 1 We tone Reuss 64:8 * 35°822 35°82 35°7 4 ” ” 69°1 34°764 0 Be =p 78°6 * 32°768 32°7 2 os co a) 966 | 32°483 0 op A 99°22 | * 32:186 32:1 4 “5 oS 30001°8 312 1 so TON 5y 28-583 2 pallies 34-3 * 27°831 27°6 + Seiae Iss 41:1 25:373 25°37 25°4 2 aa sh 53°3 * 25°136 25°14 25°0 + sf | Sis 65 3 24:509 24°51 24°6 0 as | of 71:3 24:077 2 as a 74:9 23-226 4 as | 3 82:6 22°368 22:2 4 ry) a5 90°4 * Rowland and Tatnall: 3362°151, 3359°239, 3353°790, 3352°075, 3348847, 3348°153, 3347°757, 3345°457, 3344°679, 3341°811, 3341°365, 3341230, 3339°690, 3335°836, 3332°781, 3332°190, 3327°843, 3325°136, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 91 RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length ‘ : Intensity ae Oscillation (Kayser) i eo and Frequency Are Spectrum Adeney Henan and Character | y+ +- in Vacuo 3321-634 0 0:93 | 8:6 30097°1 21°385 3321°2 2 A) BS 99:3 19-944 1 oy ip 301124 19°655 1 Suimeniiny bss 15:0 * 18-992 | 3318-99 18:8 6 woe as 21:0 * 18012 | 18:01 17:9 4 ” ”» 29:9 17:66 17°5d 2 “ a 33°71 17:045 17:05 170 1 % a3 38°7 * 16:523 16°52 16°55 6 “5 “s 43-4 * 15:590 2 oe = 519 * 15°365 15°37 15°30 3 ” 2» 54:0 15181 2 as oh 55°6 14-203 2 op A 64:5 12:99 12:7 1 Cpe nih ete 75°6 12°348 | 1 . 5 81-4 12-068 0 “4 . 84:0 11-388 | 0 a 5 90:2 * 11-090 11:09 11:0 4 ” » 929 10°220 10:2 0 ” ” 30200°9 09°965 09:97 0 ate the 59 06:1 09°38 09:2 1 SAIN Gass 08°5 09-00 be VES 08°751 08:8 0 S50. All eones 14:3 08-122 08°12 08-1 4 oa ay 20:0 07-679 O77 2 9 Fe 24°1 06°81 06°6 1 AD er 321 * 06'305 06°31 06:2 4 » ” 36°5 05-804 0 o 36 41-1 05°15 05:1 2 A ce 47:2 * (04:948 04:9 2 Be a 49°1 04:72 0 rf “5 507 04°634 2 3 Be 51°9 04-418 0 fp Hh 53°9 * (04:141 04:14 04:0 4 , rs 56°5 02°312 1 “5 oF 73°2 01:94 01:9 Pt 1 “5 Bs 76°6 01:726 01:73 01°6 5 ar a 786 01°35 Ol-l 2 ys + 81:9 3299-926 00:0 0 ” ” 95:1 * 99-479 329948 3299°3 2 0-92 a5 99:2 * 98-559 98°56 98-4 4 S 6D 30307°7 * 98-096 98°10 98-0 3 Pts dy | aete U9 * 97°393 97°39 97:2 3 - 5 19°4 * 96-786 96-79 96-6 2 Le os 24-0 * 96-252 96-25 96:1 4 a oP 28°9 94-926 0 = Pe 41:1 * 94-269 94:27 94°38 6 re 1 47°1 92°390 92-1 2 aa nr 64:4 91°789 91°8 2 a x 70:2 91°5 In “¢ on 91-250 2 7 33 750 91:0 1 %» ” * Rowland and Tatnall: 3318:965, 3318:025, 3316°524, 3315°579, 3315°363, 3311:096, 3306°310, 3304-951, 3304-126, 3299-466, 5298°549, 3298-089, 3297°389, 3296°780, 3296°248, 3294-233. 92 REPORT—1904. RUTHENIUM—continued. | Reduction to Spark Spectrum Wave-length 7 Z Intensity | Vacuam Oscillation (Kayser) E a a Frequency Arc Spectrum Adeney mo hart Character | , 4 <— in Vacuo 289°389 3289'S 2n | 0-92 | 86 30392°2 3286°55 86°8 | 1 $ 8:7 30418°3 86:040 1 sys 23°0 85°505 85°7 2 9 “5 28°0 * 85-067 4 ” | ” 32°1 84:46 84:5 1 slew cs 37°7 84:3 2 ” ” 82-744 by B2e5 | 0 er Bt 53°6 81-995 2 Ais ites ce 60°6 81-735 81-74 | S815 0 53 Saul 63-0 81:26 81-2 1 a on 67°3 80:°678 1 * BS 729 80599 80°5 2 ” 73°5 79521 2 4 83°5 * 717-699 77°70 77°6 4 = + 30500°5 76°820 76°6 0 » 39 08°7 75°87 75°7 1 es ears 17°5 * 74°831 74:83 74:7 5 ” ” 27:2 73°765 73 77 73°6 0 » ” 371 tee Boal yl 73°22 73°1 5 ” oo | 42:3 72°366 0 sere <5 50:2 72°0 In of || 71-746 0 ” ” | 560 71:2 In ae an | 70388 70°2 2 a of 68°7 69°80 sorte IMGs, ot 69:°336 2 * 3 78°5 69-087 69:05 68°93 2 ay eer 80:9 * 68°345 68°35 68°3 5 sae Wes 87:8 67°269 67:2 Os 0 phere fee es Si9 67:07 | ” ” 66°588 66°59 66°4 4 ” » | 80604°3 66:1 1 ” ” * 64:808 64°81 64:90 2 és ail 31:0 * 64:692 | 32:1 * 63-988 63:9 3 7 Fey 39°7 63°740 | 63°7 3 oa os 41-0 62°5 Os | 0 ob) xo 61-7 In ENE es * 61-257 61°1 1 or = 54°3 * 60°494 60°49 60°45 3 as Pass | 61:5 * 60°304 | 60°30 60°1 5 alle eee 63°3 * 69-811 59°81 59°6 2 Sel eA 67:9 59-111 59°11 59:0 4 OSes 74:5 * 58°176 58-18 58-0 0 ” ” 83°3 57°94 57°7 3 PA a 90°6 572 1 ” ” ‘ 56°746 0 D eS 96'8 * 56°477 56°48 56°3 4 “ - 99°3 55'356 55:2 1 » ” 30709°9 55°173 0 2 a 11-6 * 54°856 54°86 * 54°6 4 oF 3 14°6 * Rowland and Tatnall: 3285-066, 3277°697, 3274°834, 3273:208, 3268°346 $264:790, 3264°688, 3263:984, 5261-256, 3260-477, 3260°301, 3259-805, 3258-173 3256°460, 2254°834, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 9 RUTHENIUM—continued. OS Spark Spectrum Wave-length (Kayser) Are Spectrum Adeney #3254674 3254°67 53°36 | 53°136 | * 53°038 . 52-683 52-400 * 52:031 52:03 * 51°464 51°10 50°605 50°065 50:07 48:977 48-04 47°501 47°50 46-380 46:38 45°746 45°75 44:719 44:585 44:°475 * 43-638 43°64 42-978 42-283 42-28 41884 41-643 41°64 * 41°362 41°36 * 39°745 39°75 38-904 * 38°667 38°67 38-132 36101 36°10 35°85 35-431 35230 34-920. 34°39 33°650 * 32°881 32°89 32°180 31°869 31°87 30°738 29°881 28-850 * 28°651 28°65 * 28:276 * 28°021 * 27-016 27:02 * 26°497 26°50 25°418 25-03 24:72 24:18 * Rowland and Tatnall: Exner and Haschek 32545 53:2 3254°670, 3253:041, 3252-029, 3251-459, Intensity and Character Reduction to Vacuum Oscillation Frequency in Vacuo eo WONnrKNNe KDE COUN WNHNRONNOEPRONNNONNOUNWROONNNOKFOCOOCOFMNNS , | 89 ” ”? 307154 28°8 30°9 31°8 35°1 37°7 41°] 5243°632, 3241°360, 3239-727, 3238-660, 3232°872, 3228-651, 3228-280, 3228-007, 3227-027, 3226°502. REPORT—1904. RUTHENIUM— continued. Spark Spectrum Reduction to * Rowland and Tatnall: 3223°394, 3221°311, 3201°631, 3196°725, 3192°191, 3190-096. Wave-length Intensity a Oscillation " ee) Fee and es Frequency re Spectrum Adeney Heschel Character | ) 4 te in Vacuo 3223°723 0 0:91 | 89 31011°1 * ~ 23'393 3223°39 32232 ae | 3 14:3 22:07 21:9 2 a oe 27°1 21°493 21°49 21°3d 1 “5 a 32°6 * 21-303 2 m5 “A 34-4 20°899 20-90 2 0:90 “5 47°1 * 20-195 20°20 20'1 2 on “5 45-1 19°49 194 2 “0 a 519 19:274 1 op * 54:0 18-9 1 ” ” 17:96 Vien 2 Of er 66°7 * 16°641 16°64 16°5 aa 3 7 79:4 16-0 1 | ” ” 15613 0 | * 7 89-4 14-475 14:3 2 A —- 31100°4 13°33 13°3 1 “ a 11-4 * 13-098 13°10 13:0 3 > “5 13°7 12°30 ” ” 12:0 Ir In mr 5 11°38 11:3 if “3 a 30°4 10-95 ” ” 10°6 Pd 1 oh A 10:287 10°29 10°1 2 ” , 41:0 09-758 09°6 1 OD or 46-1 09:43 ” ” 08°865 1 3 AD 54:8 08542 3 tp 3 57°9 08-405 0 = ep 59:2 07°751 07°75 07°7 0 43 F 65°6 07°43 07°3 2 bs a 68°9 06°82 06:7 2 | U3 5 74:6 05-428 05-43 05°3 2 | 88-2 05:08 05:0 fe 5 915 04°36 04:2 2 es 3) 98-6 03°62 03°6 2 “9 “ 31205°8 03:0 1 ” ” 02-705 02°5 2 * 5 14:7 * 01:604 3 5 a 25°4 01°372 01:37 01:38 2 + = 27:7 3199-238 | $199-0 Ir 0 45 a 48-5 319874 98°6 2 7 53°4 98-437 98-5 2 = e 56:4 97-603 O77 0 s my 64:5 * 96-718 96°72 96°5 a “ *3 73°2 95°85 95°6 1 uf a 81:7 95-438 1 5 3 85:7 95°137 95°14 95-1 0 : Ys 88°6 93°617 93°5 2 5 = 31303°5 92°52 92°5d 1 D 53 04:5 P92 171 92°17 92-1 2 F = 07°9 91-900 91°7 2 gir el ae 20°4 91303 1 eal ees 26:2 * 90-088 90:09 89°9 4 ie as me 38°2 3220°199, 3216°646, 32137105, ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 95 RUTHENIUM—continued. Spark Spectrum Zoe - Wave-length | Intensity Oscillation (Kayser) 4 and aoa | Frequency Are Spectrum Adeney Exner and | Character | , + oes in Vacuo Haschek A *3189°835 3189°7 3 0:90 | 89 31340°7 89418 89:2 2 $ BA 44°7 88°8 1 ” ” 88-713 88°5 2 “ - 51°7 * 88-463 3188-46 88°45 5 be % 54-1 88-057 2 35 4 58:2 86°867 1 co op 69:9 * 86-171 86:16 86:0 4 os ns 76°7 85553 2 FA 5 82°8 85:276 85:28 85°3 0 3 A 85°5 84:9 1 ” ” 84-1 1 9 ” 83:9 1 ” ” 83°54 83:4 2 a a 31402°7 82:0 1 ” 2 81-312 81-4 0 0°89 “5 24:7 81-126 0 7 os 26°5 80:569 0 3 9-0 31°9 79:380 79°38 79:2 2 45 a 43°6 78843 1 * fc 49-0 Pe i159 77°16 77:18 4 a 3 65:6 76°401 76:2 3 Js fc 73°2 75°32 75°30 4 re te 84:0 75:10 4 = aA * 74:243 "74:24 74:1 Os? 4 iy 53 94°5 73°500 2 fe y 31501-9 73°221 2 53 1) 04-7 72°778 72°78 72°6 0 oS “, 09-1 71°352 2 a a 23°3 70196 70:0 2 Bs Aj 34:8 * 68-648 68-65 68°5 5 “p r 50:2 68°355 1 3 * 53:1 67-514 67°51 67°58 0 a “5 61°5 66-68 66:4 2 a ris 69:8 66:24 66:0 2 = a 74:1 65:507 0 sr re 81:5 65-307 65°31 1 sp 5 83:5 65-086 65:0 0 “ cf 85:7 64-939 64:94 65-0 0 “6 > 87:2 64:7 1 ” ” 64:1 1 ; + 64:0 1 ” 2” 63186 63°30 63°25 0 Fe ait ea 31604°7 60-80 60-78 f > A 28°6 * 60:036 60-04 60:05 4 “f o 36:2 59:003 Cai? 59-00 58-7 4 cp » 46°5 57°739 57°5 2 a ss 59-2 57°3 1 ”? ” 571 1 ” » 56:917 2 a % 67°5 56°733 0 ne s 69°3 55°90 ” » 55-4 1 ” ” * Rowland and Tatnall: 3189-843, 3188-468, 3186:162, 3177°170, 3174-254, 3168°678, 3160-042. 96 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum Eo net a Intensity acuum | Oscillation ayser) an are | Frequency Exner and 1 i Are Spectrum Adeney Haschek Character | y+ =o in Vacuo 3154:°543 2 0°89 | 9°0 31691°3 * §3°927 3153°93 3153°7 4 : ” 97°5 52°35 62-2 1 Coa =F Slike 51-780 1 Pe x 19-1 51:25 §1°3 1 feet = 24°4 * 50°803 50°80 50°5 | 4 Vaiss aa 28:9 50-283 1 = - 34:2 49-7 1 9 2 49:3 1 ” 9 48593 48°59 48°7 2 Pe a 51:2 48-138 | 0 a op 55:8 47°547 47°55 47°62 0 “6 55 61:8 * 47-323 2 o. * 64:0 46183 46:18 | 46:0 2 + 9-1 75°5 44-820 2 A 5 89-0 * 44-369 44°37 | 44:2 4 a =e 93-8 43°764 43°76 | 43-80 } 0 a5) umes 31800-0 43°46 | 43°40 4 Pe “ 03:0 41°66 | 41°5 2 O88") ¢; 21:2 * 41°081 41:08 40:9 4 Pry ” 27:1 * 40-596 40°4 3 ame “ec 29:0 40-201 1 {ates > 36-0 39°379 39°65 39°5 Pt? 2 ” ” 41:6 38-884 2 re An 49°4 38:0 | 1 ” ” 37:036 0 spe ll eeoe 68-2 * 36°663 36°66 | 3 Puede a3 719 36°451 365 | 1 eek aaa 74:1 36:044 36:04 35:98 | 2 3s OMS lap ess 78:3 35°48 | ” ” 35°170 35'1 | 0 = a 87:2 34°895 34:90 | 34:98 | 1 ss oe 89:1 33°800 2 Ley lies 31901-0 aR ea lhe 1 FS a * 32-988 32-99 ae Bs 8 09:3 32°6 2 Peel cr 32°5 2 % % 32°122 1 An 5 18:2 30°709 0 a ty 32°5 * 929-935 es 5s ay 40°4 29°717 29:7 2 7 42°7 29°574 29°5 0 ‘o 7 44°] 28'8 In ets ss 28-539 2 Boreal Gs 54°7 28:07 28:05 4 SA lee, 59°5 27°643 0 Ff o 63°9 27:387 1 eae a 66°5 26°730 26°73 26°75 2 ae oc 73:2 * 26-068 4 3 7 80:0 25°7 1 ” ” s 24:98 ” ” * 24-709 24:6 | 2 ” ” 93-9 * Rowland and Tatnall : 3140-604, 3136°671, 3132-995, 3129-951, 3126-075, 3124°720, 3153941, 3150°816, 3147°326, 3144:383, 3141-094, { ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 97 RUTHENIUM—coniinued. Spark Spectrum ee be Wave-length | Intensity eo Kayser an requenc = Beetiram Adeney Exner and | Character ees ie in ead Haschek A *3124-481 3124-48 ao 0°88 | 9:1 31996-2 * 94-277 24:28 3124+] ee. saet haere 98-3 93°83 2 ” ” 23°610 0 ir oe 32005°1 22-970 0 ” 29 11:7 22-108 1 + a 20°5 20°90 ” ” 20°650 20:7 1 a s 35:5 * 18-792 18-6 4 of a 54-6 * 18-170 | 18-0 4 if Bi 61:0 17°563 0 * x 67-2 17-181 0 - = fle 16945 | 1 is - 83-6 | 16°5 In ” ” 15°536 | 15°5 0 a - 88-1 14:53 14-4 In ifs 9-2 98-5 13-756 13°76 13°8 Pd 0 3 = 32106°4 13-502 13°3 2 Bs 55 09:0 * 12-782 12°78 12°5 2 fe - 16-4 12-408 12:3 2 - x 20:3 * 12-012 12-01 3 4, % 24:3 11°8 1 ” ” 11:24 11+1 1 3 = 32°3 * 10-641 10°64 10°5 4 x “ 38°83 10°147 0 ” ” 43°6 09:5 In me aot S| 08526 08:3 2 ss rE 61-4 * 07-829 3 = 67°6 07:698 07°70 07°72 0 6 3 68°9 07°373 0 ” ” 72°3 * 06-942 06:94 06-7 3 by oe 76°8 05:910 0 3s 87:5 * 05-524 2 sf x 915 05°382 05°38 05:2 2 5 “ 92-9 04:570 2 $ cc 32201-4 04:070 0 3 “ 06°5 03°51 03°3 2 B, x 12°3 02:50 02-5 1 * 25°4 02-2 1 ” 3” 01:7 1 0:87 ” 01:59 01-4 1 me a 32:3 * 00-953 3000-95 3000-95 4 93 = 38°9 99:8 1 a se *3099-390 99:39 99:40 5 F 54 55:2 98-954 0 S \ 58°0 98-05 97:9 2 3 . 63:0 * 97-706 97°71 97-6 4 Ee 2 72°7 a 97°2 1 } ” ” * 96-672 96-67 96°65 6 a 2 83°6 96-062 96:0 0 H x 89:9 95640 0 i bf 94°3 * 94-500 94-64 94:5 2 3 _ 32306°2 | 93-01 * Rowland and Tatnall: 3124:480, 3124-279, 3118-799, 31187182, 3112-792, 3112°031, 3110°650, 3107-825, 3106-954, 3105-523, 3100-945, 3099°390, 3097-708, 3097337, 3096°669, 3094°507. 1904. = 98 REPORT—-1904. RUTHENIUM—-continued. Spark Spectrum Bee be Wawve-length Intensity Oscillation (Kayser) F and ——==T oa | reguency: Are Spectrum Adeney Exner and | Character | 4 + Le in Vacuo Haschek r 3092-351 0 | 0°87 | 9:2 | 323286 | 92°085 | 0 | ves 3 31-4 | een O 71a. | 3091°8 2 eres Phe | 35°0 91:004 | 2 op saeedl 42°7 | 3090-54 90°5 1 3 yet vail 47°6 * 90°341 90°34 2 * SS 49°7 * 89-915 89:92 89°7 4 “5 a 54°1 * §89:252 89°25 89:2 4 ac 39 61-1 88°362 0 a P| 70:4 88-177 88°18 88-1 2 5 Par Pi 72°3 88°050 0 es a 73°7 87°039 2 +f Pe 84:2 86°888 1 sh ss 85:9 86°631 86°63 2 35 3 88°6 * 86:181 86°18 86:0 4 3 cb 93°3 85°597 0 2 oc 99°4 84°728 0 =f a 32408°6 * 84:631 84:5 2 ast hieetss 09°6 * 83:252 83-0 3 » 9°3 24:0 81:946 81°95 81:7 0 os 3 37°7 81:489 81:49 81:3 0 + ZF 42°5 81218 | 1 “3 A 45-4 * 81-009 81-01 4 ~ a 47°7 80:292 80°3 4 ee Ea 55°2 79°953 80-1 0 & a 63:3 79°27 7971 1 “ * 65°9 78:209 1 = fe aor 77°657 2 cp 33 82°9 77-175 77:18 77:0 2 ob sa 88-0 * 76°886 768 2 as es 91-1 75°412 75°41 75°3 1 ES “ 32506°6 * 73°440 73°50 4 + + 27°5 72°42 72°3 2 as “5 38°3 71°824 0 “fs S 44:6 wear ibey Pal 0 of - 45°7 71:586 71°5 2 -- = 47-1 70°6 J : ” 70°3 1 ” ” 69-289 2 . 715 * 68°3b5 68°36 68:2 4 * or 81-4 67°5 1 ec ” 66°4 2 Ps Fee ad * 64:958 64:96 64°95 4 esa a 32617°6 | 63°3 1 ; chy } thy 62°155 62°16 62-0 2 086 ,, 47°3 | 60°67 60°4 2 ” | ” 63°2 60°346 | 60°37 60-2 0 3 | 66°6 * 59:284 | 59:28 59°71 3 Th) leer 78°3 * 58-909 1 | A 82:1 58-762 58°76 58°6 2 ” ” 83°6 57°468 57°47 57:2 3 6 | Pri fi 97:5 56-971 56°97 56°92 0 + oo -« 82002'S * Rowland and Tatnall: 3091-980, 3090°348, 3089:916, 3089-259, 3086°182, 3084°637, 3083-257, 3081-010, 3076°883, 3073-442, 3071°711, 3068°363, 3064-951, 3359275, 3058891, RUTHENIUM—continued. _ ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 99 q Wave-length (Kayser) Spark Spectrum A. Exner and | Are Spectrum Adeney spears 3056877 56°192 | * 55°042 305504 3054'8 54°6 53°450 52°445 51-974 51°704 50-504 50°309 50°3 49°32 49°32 49°174 * 48°897 48°90 48°7 * 48°606 48°61 48°4 48-442 47°88 47°6 47:108 47:0 46°356 46°36 46°1 46114 * 45833 45°83 45:6 45°630 44:5 44:077 43°161 * 42-953 42°95 42°7 Ir _ * 42-598 42°60 42°3 42°025 * 40-418 40°42 40°2 40:071 40:07 39°9 39°586 38°851 38°6 * 38-289 38:1 38-078 37°9 : 37°845 37°0 36°580 36°58 36°53 35°93 35°6 _ 35°578 353 * 34:167 34:17 33°8 * 33°562 33°56 33°4 33°16 33:0 32°771 32°77 32°3 32°026 315 311 30°890 29°2 30°801 30°7 Os 29-04 28°9 28°785 27°910 27°91 27°7 27°678 27°361 277195 27°20 27-0 26°7 Intensity and Character RONOFORKFN RRO WRENN NOOCNWREWNRE ORK OCRNWNONORRO WO DR Oe eSBNoooo Wr Reduction to Vacuum A+ Oscillation * Rowland and Tatnall: 3055-039, 3048-900, 3048-603, 3045°828, 3042-944, 3042°587, 3040-420, 3038-284, 3034-169, 3033-564. H2 100 REPORT—1904. RUTHENIUM—continued. Spark Spectrum Reainetton oo Wave-length Intensity Fil ee Oscillation (Kayser) i. eat and a ee Frequency Are Spectrum Adeney eee eat Character | , 4 > 55°0 98-09 98-0 1 % * 48-9 * 97-743 97°74 97°6 2 * : 53°5 * 97:34 97-4 1 ee 9-6 58:3 * 97-011 96:89 96°6 1 5 ip 63-4 96:44 96:2 1 BS + 68-1 96:01 95:8 1 Fb % 78:4 * 95-083 95-08 94:7 5 95 5 84:5 94°54 94°5 1 ” ” 93°6 1 ” ” * 93:387 93:1 3 asl age 97:4 * Rowland and Tatnall: 3020-985, 3013-468, 3013-030, 3008-906, 3008-366, 3006°699, 3001°751, 2998-458, 2997-730, 2997-536, 2997:006, 2995-077, 2993-385. RUTHENIUM—continued. , | Reduction to ‘ Spark Spectrum Wave-length 7 i Intensity SS Oscillation (Kayser) E a an Frequency | Are Spectrum Adeney Hacchek Character | ) 4 - in Vacuo 2993-070 1 0°85 | 9°6 33400°9 2992-48 2992'5 1 leas no 075 92-080 92-08 92:0 0 3 “F 12:0 i 91-71 91°66 8 x3 a 16:2 HK 90-413 | 2 ri 55 30°5 90:0 In a 2 * 89-770 | 89°4 2 A ie 37°9 89-451 2 eke = 40-4 * 89:079 | 89-06 89-02 0 eos ms 455 88-224 88-0 1 nae is 55°1 88-047 1 ee is 571 86-453 86-45 86:5 1 ier 53 74:9 86°104 0 3 re 78:8 85:78 85:5 1 Ieee. 5 82-5 85:08 84:7 1 eee ne 90°3 |. 83°74 ” ” * 82-045 82:05 82-0 4 0°84 x 335244 81-080 81:08 80°8 0 | 99 ” 35:3 * 80:065 80:07 80:05 3 re re rf 46°7 * 79-847 79°85 79:80 3 Wes ae 49:2 78°760 78°76 78°72 2 ore F 61:4 77°596 77°60 774 0 PA ” 74:5 77°346 77°35 77:25 2 oA Fe 77°4 * 77:048 76'8 3 3 or 80°8 * 76:°707 76°71 76°62 4 9 » 84:6 75:253 1 er: ns 33601:0 a 74:79 74:7 1 5 “A 06:2 * 74-454 74°45 74:4 2 med Fo 10:0 * 74-099 3 * ac 14:0 73°743 73°74 73°7 0 a3 18:1 73°3 1 ” ” 73°08 73°0 2 ne £5 25'5 72°594 72°59 72°4 0 93 ss 31:1 71:10 70°9 1 bs PA 48-0 70°6 1 ” ” 70°5 1 ” % 69-850 69°85 0 5 9:7 62-0 69-069 69:07 68°8 4 9 ” 70°9 68-564 68-56 4 ” ” 76°6 68-233 68-11 67:9 0 ap 99 80°4 67°456 aad 2 re = 91:2 66-674 66°67 66:3 1 re e 98-1 65°820 65°72 1 % ” 337078 65°674 65°67 3 ay “ 09°4 65 286 65:29 65:2 4 35 PA 13:9 64-415 0 nA a3 23°7. 63°829 3 Fe a 30°4 on 63°52 63°50 2 Hr oe 33°9. | : 0 ; oS 43:2 62442 Ate A 0 i‘ ” 46:2 61-803 { y 62:0 2n Pr 9 60°3 61-60 ” ” __* Rowland and Tatnall: 2989-768, 2989-061, 2982-048, 2980-056, 2979-834, 2977:037, 2976-700, 2974-457, 2974-095. 102 REPORT — 1904. RuTHENIUM—continued. Spark Spectrum Reduction to Wave-length Intensity Sa Oscillation (Kayser) and ae | Frequency Are Spectrum Adeney Exner and | Character | y 4 yee in Vacuo Haschek ar 2961-097 3 0°84 | 9:7 33761°6 2960°35 2960-2 2 aa a 701 59-855 59°86 59-6 2 y, a 75°7 58-993 0 this = 85°6 58-118 3 | San 4d 95:5 57:297 0 I ie » | 338050 55-960 0 or 3 20°3 55-714 y(t oa 23-0 55°463 e - ee a 25:9 54-594 54-59 54°7 4 heats aot 358 54°4 2 Pe 99 54:371 54-20 54:0 0 A = 38:5 53116 0 + ny 52°7 52-78 526 1 a 0} 56°6 52°599 2 od Et: 58°7 52°36 52-2 2 e 61:3 51-516 51:3 2 if > 71:2 50-650 50°5 1 4 81-1 50-080 50:08 50-0 0 laos 55 87°5 49-612 49°61 | 49°5 4 oo ae 93.0 49:2 1 | ’ ” | 48:7 1 ee 3 48°47 48-2 1 o £ 33906-1 47°72 47°7 1 es a 14'8 47:102 47°10 47-0 4 - s 21-9 46:670 0 e erst 26°3 45°75 45°78 45°82 4 Z eoul 37:2 45°591 0 ay | 39-2 45°20 45-0 2 “ saat 437 44-294 0 ¥ s 54-2 44-035 44-04 43-9 3 a ae 571 43-593 43°59 1 J a 62:3 42-823 0 Oe tse 71-2 42-366 42°37 42°40 1 ee a 76-4 41°6 1 ” 35 41-0 In ee 40-474 | 403 3 af : 98°3 40-057 39:8 3 a ss | 8003-1 39-796 0 x ae. 06:2 39-247 39°25 39-0 2 s eel 12°5 37-679 0 S ; 30°7 37-448 1 aaeul 33°3 37:20 37-0 1 = sia 36-2 36-591 0 a spikes 43°3 36-380 0 : eel 45°7 367131 2 a BAT 47°8 35°67 35°5 2 a ony 54:0 34-638 0 the a8 oe 65-9 34-309 2 Wiices ee 69°7 33-367 33°37 33°38 0 Pate eit 80°7 32°6 1 | ” ” 31:35 31:2 2 lp e | 34104°1 29-87 29-6 1 res soe 21-7 29-027 29-03 29°] 0 | thes ae | 31:1 28-608 28-61 28:5 2 | | 36:1 ON WAVE-LENGTH 'TABLES OF THE SPECTRA OF THE ELEMENTS. 105 RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length 4 i Intensity Mees Oscillation (Kayser) = ay ae GR) Oo SA ag and ~~| ‘Frequency Are Spectrum Adeney Exner and | Character | y 4 ee in Vacuo Haschek 292827 0°83 | 9°8 34140°1 2927°858 27°73 2927°72 0 ” ” 44°3 27:232 2 ” ” 52°2 26°913 0 ieee 55:9 26°69 26°5 1 rf nc 58°5 25-890 25°89 0 ” ” 67°38 25°685 25:5 0 or sam | 70:2 257189 0 a ree? 76:0 24-760 0 bd eb 81-0 24-20 23°9 2 a op 875 23°40 23°1 1 » PP 96-9 22°50 22°3 2 “f “rc 34207°4 21°95 21:8 1 s 9-9 19:0 21:276 0 + + 21-7 21-068 21°07 2 “ “ 24:1 k 20°5 1 ” ” 20-369 L p 7 32°3 19-723 19°73 19°6 4 “= A 39:9 19-276 0 7 of 45:1 18-76 185 2 a ot 51-2 17°880 17:88 17:9 2 ” ” 61°6 fed saab 1 ” ” 17°353 0 3 ae 67°6 17-249 2 i 46 68-9 16351 16°47 16-48 6 I on 791 15°736 2 “ 3 86-7 14-403 14:3 2 ” ” 34302°4 14:10 14:0 2 a a 06-0 13°5 1 ” ’ 13-286 13°29 13°3 3 ” ” 15°6 13-0 1 ” ” 12-866 0 ‘6 3 20°5 12°555 12°56 0 » ” 24°2 12°451 12°45 0 on Rs 2574 10°542 2 5 35 48-0 10°10 ” ” 09-352 09°35 09°95 1 - tp 64:0 09°5 1 ” ” 09°1 Os? 2 Pe 99 08-590 0 o be 71:0 08-0 In “ fp O71 In os np 06:6 1 ” ” 06°424 06°42 06°3 3 » ” 96°6 05-952 05:9 1 on re 34402°2 05°756 05°76 om % = 04°5 04°825 04:7 0 A a 15°6 03°7 1 » » 03°3 1 ” ” 03°180 03:0 2 3 3 34:9 02-969 02:8 1 =r 3 37°6 02-223 02:22 02°10 1 sy Pe 46-4 01-890 01°74 01°8 1 aS 3 50°4 00-63 00°7 2 ” ” 65-4 99:9 1 Fh » 2899°820 | 2899-70 2899°7 1 9 » 75°0 104 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length : j Intensity sestne (Kayser) 4 - i and Are Spectrum Adeney Haschel Character Lee <- 2898:845 28987 1 0°83 | 9:9 98°650 | 98°5 3 + a 2898-40 ” % 98-0 2 ” ” 97-820 97°82 1 i 10:0 96-638 96°7 3 *F ” 95-925 95-9 1 ss i 95°554 0 ” ” 94:0 1 » ” 93°844 93°84 0 sl: 92:8 2 39 | ” 92-654. 92°65 92:5 {> i hnaee, 92-2 1 ” » 92-00 91:9 | 1 ae oS 91-762 91:5 2 as m4 91-242 91-24 2 ” ” 90:7 1 ” 99 89:9 In aH aS 89°6 1 ” ” 89-543 89°54 0 an aS 88-739 88°8 2 0°82 ~ 88-112 88-11 88-2 2 ae 5 87224 87°22 87:3 0 a 7 86°646 86°64 86-7 ot 5 af 85:60 85°6 1 = 7 85:1 1 ” ” 84-601 84:60 84:7 2 o Ee 83-701 83°70 83:8 3 7 “f 83°3 1 ” ” 82-697 2 a5 ro 82-299 82:22 82°24 2 os +n 81:373 81°37 81°5 1 A as 81-0 1 ” ” 80:637 80°64 80°6 0 ” 9 80:24 80°3 2 “6 +A 79°853 80:0 3 ap 45 79°466 0 aA aa 79:20 79°3 2 . a 78:3 Pd 1 a “S 77°930 78:04 78:1 2 AA ns 717-5 1 ” ” 77:197 Gee 2 A % 76:9 1 ” 9» 76:6 1 9 ” 76:3 1 ” ” 758 1 ” ” 755 1 ” ” 75°104 75°10 75:2 5n 50 om 74:7 1 ” ” 74161 2 53 5 73°83 73°9 2 5 Bs 73°34 73°5 2 55 5 72-468 72°5 2 aa A 71-756 71:8 4 oo 10°1 71:57 Tfilers 2 5 Fe 71:296 3 ” ” Oscillation Frequency in Vacuo 34486°6 88-9 34510°8 12°8 21°3 25°7 4671 60:4 68-1 71:0 (iif § 97°5 34607°2 14:7 25°3 32°3 44:8 568 67°6 TERY 85°4 95°7 347045 09°3 14:0 18-7 21:8 37:2 46-0 714 82°8 86:8 92°7 34803-2 11:9 14:0 17:3 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 105 RUTHENIUM—continued. Spark Spectrum Reduction to | Wave-length Intensity | Vacuum Oscillation (Kayser) and Frequency Are Spectrum Adeney Bet ond Character | 4 <- in Vacuo | 2870°8 | 2 0°82 | 101 2870°53 70°6 In i » | 2&4826°8 2870°322 2 oe 9 29-2 69-047 69°05 69:1 | 0 - on 44°8 68-662 0 = A 49°3 68-426 68°43 68°5 2 a 3 52:2 68-286 2 3 58 53°9 | 67°20 67°3 1 53 ze 67°1 66-743 66°74 66:9 5 S “ 72:7 66°41 66°6 2 5 - 76°7 66°19 66°4 2 ts aa 79°4 65°65 65°7 2 ; ¥ 86-0 64°726 0 0°81 rf 97:2 63°33 63°5 2 is es 34914:2 63°112 63:1 2 Fr oy | 168 62-963 62°96 0 ; rae 22°8 62°5 In “ * 61°833 62:0 1 oS 35 32°5 61-508 61°54 61:6 5 e oS 36°5 61:17 61:3 1 Noes, es 40°6 60°95 61-1 1 53 re 43°3 60-491 60°49 0 yon fe 48°9 60-114 60°11 60-2 + 55 es 53°5 60-0 2 ” ” 59-9 2 35 Bayt 59°65 59°6 In i ea op Yl 58-693 58-69 59-1 0 a a 68°8 58:0 2 » 9 57°88 9 0 57:770 0 = Rea 82:2 57°367 57°37 57°4 1 EC A: | 87:2 56:67 56°7 2 ns ane Ml 95°7 56°3 1 ” 39 | 56°153 56°1 2 ” » 35002°0 55995 55:9 2 5 = 04:0 55:454 55°45 55°5 0 5 ne 10°6 55:01 55:1 1 pe = 1671 54°820 54°82 54:9 0 9 x 18-4 q 54-465 54:3 0 A By 22°8 54°173 54:17 4 45 a 26:3 53-433 53°43 0 ss weit'| 35°4 ; 53°28 53:3 2 BS Hei] 37°3 , 52°7 1 spunea t 52-4 1 ” 2 | ! 51-225 1 >> shell 62°5 50°86 50°'8 2 Ar » | 67:0 50°3 In = oe, ot 49°73 49-7 2 3 A 82:2 49-399 49°40 49-4 0 = oneal 85:0 48-688 48°8 1 sant eeaet bl 93°8 47°72 47°8 1 a 10:2 35105°6 47°25 47:3 1 ott wl See 11-3 46-9 1 Ce aa 46662 46°7 0 fe | 18°6 46°430 46°5 1 oe os 21°5 45°3 or) i) 106 Wavye-length (Kayser) Are Spectrum REPORT—1904. RUTHENIUM— continued. Spark Spectrum 2843-277 42°859 42°651 41°777 40:°657 38°729 37°384 36°684 36-254 34:107 32°755 31-280 30°815 29:253 27:969 27°627 24-866 24-004 22-912 22-659 22:371 22142 21-504 21:279 19-667 19:062 18:913 18-460 Adeney |) Hysol 2844-86 2844-9 | 43:9 43-4 43-0 41-78 | 41-81 41:23 41°3 40:66 40°8 39-9 39-52 39°6 39°16 39:1 38°73 38-9 38-0 37:28 36-68 36-7 36°5 36-4 35°77 34:52 34-2 33°97 34:0 33°64 32:9 32:00 32-1 30°8 30°3 301 29-6 29-4 29:25 27-97 28:1 27-63 27°7 27°19 27°3 26°81 26:9 26°7 26°36 26-4 25°62 25°6 25:20 25°3 24-3 23°33 23-4 22-9 2266 22-62 22:3 21°50 21-48 20°8 19-2 18-46 18-6 17°74 17-7 | Intensity and Character Reduction to | Vacuum | Oscillation Frequency in Vacuo NrNORFNNRKF KE NNNRK RK ONK Kb NOSSO TINTS OTE IRS) FS as ONO bow 35156°4 60°4 65-6 68-2 79:0 85:8 92°9 352070 11°6 168 33°5 42-2 47:6 14-3 76-0 Oana SS UST Pee) ON WAVE-LENGTAH TABLES OF THE SPECTRA OF THE ELEMENTS. 107 RuTHENIUM—continued. F Reduction to | Spark Spectrum Wave-length 3 F Intensity bec | Oscillation (Kayser) i a an Frequency Are Spectrum Adeney ee Character | , 4 i- in Vacuo 28177192 2817°3 3 0°80 | 10°3 354859 16°7 In ” ” | 15:9 1 ” ” 15°410 15°6 0 3 % 35508°5 | 2815-18 15:2 1 Prva iscsi 11-4 14:7 2 ” ” 13°807 13°81 13°78 0 ei ss 28°7 13°44 13°38 4 fe ie a 33'S 12°925 13:0 2 =e) FS 48°3 12:9 1 ” ” 12:06 12:2 1 i = 50°8 11°66 11°'8 1 - 5 55°9 11:360 0 » 3 59°6 10-788 10°79 10°79 0 Es Bs 66:9 10°645 10°65 10°5 3 ios 3 68°7 10131 10°13 10°3 a o 3 752 08-335 08:5 0 7 “p 97°9 07'7 07-7 2 re " 35606-0 07°34 | O75 2 rh Es 10°6 06-845 06°85 | 06°85 0 # 33 169 : 06°5 | In 2 x | 04°94 05°1 2 s 411 | 04:0 1 ” ” 03°76 03°7 1 3 op 561 03-593 03°4 1 co 9 58-2 02-907 02°91 | O31 2 4 > 66:9 02-260 02-26 02-4 0 # ce 75°1 01°6 | 1 ” ” 01-2 1 9 ” 00-785 00°79 00°7 1 $ 94-0 | 00°6 1 9 9 00:243 0 FL: op 35701°9 00°03 9 + | 2799-71 2799°7 1 “ota bate 3 07°7 99°4 1 i le as 98-91 99:0 | 2 $ 10-4 17°'8 97°91 97°9 1 - + 30°6 | 97-20 97°3 1 Fr Be 39°6 2796°652 =: 9665 96:6 0 ss ns 46°6 | 96:10 | 96:2 1 Fr op 53°7 | 95°7 1 93 9 95-464 95°46 95:6 0 > " 61°8 94:42 94:4 2 x + 752 | 93-2 ie | Ih Sigti 92°746 2 5 96°7 92°418 92-42 92:4 2 $s “6 35800°9 91°164 91°16 91:3 0 % rE 04:1 90°695 0 rt sale ae 23:0 90:28 90°3 2 eh os 28:3. | 89°720 89°72 89:6 0 x 5) 35:5 | 88-84 88°8 2 a Pr 46:8 88°5 1 ” ” | 87:930 87:93 87:95 3 3 58°5 / 87°35 87°5 2 3 : 65°7 | 86°50 86:5 | 1 3 #8 66:9 85-90 85-92 4 84:6 108 REPORT— 1904. RUTHENIUM—continued. Spark Spectrum Paes to Wave-length Intensity ete Oscillation (Kayser) Re er a aa Rea and 7 ee Frequency Are Spectrum Adeney Haschek Character | ) 4 =a in Vacuo 2785°746 | 1 0°80 | 10°4 35886°6 | 2785-29 | 2785°3 2 ss aetieee 92°4 84-978 0 * “ 96°5 84-625 84:62 84:6 0 oD =r 35901°1 83°85 83°9 2 0:79 5 11-1 83:0 1 ” » 82-305 82°31 | 82-4 1 as eel 21:0 81:0 2n “ 5 80858 | 80:86 2 s 3 49-7 80°5 1 ” ” 80:0 1 ” ” 79°54 79°6 2 + a 66-7 79°2 2 » 9 79-081 79:08 0 ” ” 72-6 78°54 78:48 6 as = 79-7 78:2 1 2” ” 77629 77:63 778 0 elites 82°6 77°6 2 » ” | 765 1 shit |e 76-009 75°9 1 x op 36012°5 75°723 75°72 75°70 0 Peet errs 16-2 75:288 e783 1 i De &| 21°9 75:2 1 35° hel coe 74:589 | 74:7 2 a “. 31:0 74-4 1 ” 3 74:25 ” ” 732 1 “f =o 73:068 72°9 0 ce ne 50°8 72°716 72°72 0 re 6 55°3 72°55 72°58 4 $3 5 57°5 72-2 1 ” ” 71:99 72:1 1 55 un) oka 64:8 71°59 716 1 simul) os 70-0 71:15 71:3 2 Soh eres 757 70'805 709 2 Pe Pe 80:2 70°399 70°40 70°5 0 + a 85°5 69-993 0 a9 ee 90°8 69-024 69-02 69:02 4 5 10°5 361032 68-032 0 s sae 16:2 67°66 67°7 1 = = 2171 67'5 1 » 9 67:1 1 Pri nit eS 66-66 66°7 2 Hy +5 34-1 66°323 0 a9 x, 38:5 | 66-00 66-1 2 ss a 42°8 65°530 | 65°53 | 65°55 2 ssibeiheh 95 48°8 | 65:24 65°25 4 rr 52-7 64:824 65-0 2 + | 58-2 64-005 64:2 1 a “n 68-9 63513 | = 63°53 63°6 4 Mea se 753 63-232 | 63°3 2 | 29 » | 79-0 62:9 1 ” cP 62-400 62°4 2 ee eee 89:9 62°17 62:2 1 |\@ 93 os 93:0 61°60 61-7 1 eres » | 362014 61:5 In Assad Maes ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 109 RUTHENIUM— continued. Spark Spectrum pean ial Wave-length Intensity say Oscillation (Kayser) uy Gee Boe and 1 Frequency Arc Spectrum Adeney oe Character | 4 = in Vacuo | 2760°88 2760-9 2 0°79 | 10°5 36209°8 2760:268 | 60:27 | 602 0 as 93 17°8 | | 59°8 1 ” ” | 59°35 59°3 1 ” » 29°9 59-0 2 AY FF | 58°5 1 ” » 58°104 58°10 | 58:0 0 ” ” 46°3 57°912 | 1 # * 48:8 | | 575 1 ” ” 57:175 / 57-1 0 2 a4 58°5 56°7 1 9 =| | 56°6 1 ” ” 56°46 56°5 1 rE > 67°9 56-0 1 ” » 55°30 Fe “| 55°9 1 nN 55°5 1 » » 55°30 55:3 2 7 Seale 832 54:3 1 soe 3s 53°543 | = 5354 53°6 2 9 | os 363063 52°868 52°87 52°94 2 Eeiiikee Rat 15:2 52°548 52°55 | 52°59 2 a a 19°5 52°14 | §2°3 2 3 4: 24:8 51-698 | 51:9 0 ” FP 30°7 | 51-6 1 ” | ” | 51:0 1 sot anal 50-452 | 506 0 Fe 10°6 47°0 49-923 0 A cf: 54°1 49°66 49:7 2 9 + 57°5 49:26 49-4 2 is 5 62°8 49-2 2 2 6 | 48-7 1 ” ”? 48°3 In 6, . 48-03 | 48-08 4 - of 79°1 | 47°62 | 47-7 1 sh) LNs 84:5 46°991 47:00 he eee 0 fo hacen 92°9 46°75 468 2 9 ” 96°1 46-169 46°17 46-2 0 ” ”» 36403°9 45:90 45°98 | 4 = oH 07°3 45°343 0 FP *5 14:7 45:22 45°22 4 Pr ay! 16°3 44°821 0 AD “4 21°6 44-541 44°54 44°62 2 a = 25°3 44:022 44:02 44:10 2 s rE 32°3 43°57 | 43°62 4 % An 38'3 —— 43°3 In sok alas | | 42°6 2 adel beeeD 42°15 | 42:2 1 Bil ae 57:1 | 41°7 In 0-78 = | 415 1 ” ” | 41-4 In t 35 ” ome: ag 2 ” ” 40°327 40°3 1 3 op 81-4 40-085 0 Py +5 84°6 39°68 Fe | 39:8 In % 38 39°311 39°40 | 39-4 4 ayer it, ge al 94°9 39:1 1 ona ies 110 RUTHENIUM—continued. REPORT—1904. Spark Spectrum peduelion ie Wave-length Intensity es iecions Oscillation (Kayser) and Frequency Are Spectrum Adeney Hae end Character | \ 4 i- in Vacuo 2738°983 2738°9 0 0-78 | 10°6 36501°3 38:3 1 ” ” 38'0 2 ” ”? | 273787 37'8 2 A oo 14:1 37°66 ” ” 36°917 36°92 36°98 0 ” » 26°9 36-412 36°54 36°6 0 25 aS) 33°8 35°806 35°81 ° 35°9 2 as 2 41-7 34438 34:44 34°44 3 *D ss rl 59:9 | | 33°68 33°7 55 “5 70°1 33:167 33°2 0 aD oe 77-0 32°83 32'8 5s a 79°5 32:5 Ir ? 33 a 32-011 32°1 0 on + 92°5 31:48 31:5 5 55 99-6 31-028 31-1 2 Fi oS 36605°7 30°79 30°7 sf or 08°8 30°416 30°42 30°5 2 oe op 139 307115 | 0 aa a 17°9 29°540 | 29°54 29°5 2 A 2 25°6 29°04 28:9 a sia 323 27:74 2” ” 27°4 » apr! 27-063 27:06 27°1 0 Aj 10°7 58°8 26:6 ” se 25°549 25°55 25°55 4 o oY 79:2 24°95 24°95 a On 87:2 24:2 a a3 24°153 24:0 = x 97°9 23°6 9 » 23°10 23°3 = ot 36712°1 22°903 22°8 0 os 5 14:8 22-760 22°76 22°6 3 oD s 168 22°493 0 35 ES 20°3 21°937 0 A> 20 35°4 21°653 21:7 3 a a 31°7 21:3 2” ” 20°4 ” ” 19°838 19°84 19°8 0 aS os 56:2 19-610 19°61 19°7 5 ” ” 59°3 18-919 18:92 19:0 0 oF oO 68-6 17:93 18-0 5 ay ot 82-0 17510 17°51 17°45 2 = * 87°7 17°100 0 a “9 93:2 | 16°8 39 9 16°23 | 163 Be a5 36805:0 16°15 2” ” 15595 ) -albe6 2 “0 a 13°6 15326 | 153Rh 0 te As 173 | 143 Ae or | | 14:0 ” ” 13824 | 13°66 13°7 1 an a 37°7 13-272 13°14 13:2 2 oD x 45-1 12/967 | | 0 “, oS 49°3 12-493 | 12:49 | 12°43 4 a os 55°7 12169 | | 0 a 60:2 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 111 RUTHENIUM—continued. Spark Spectrum as gated © Wave-length _| Intensity ie es Kayser | an requency ios eg eciram | Adeney Pee ne Character | , 4 i Eaivecad 27119 0°78 | 10:7 11:2 ” ” 2710321 2710-32 10°3 0 s a 36885°3 | 10:0 ” ” | 09°851 0 ames 4 91:7 09-291 09-29 09°3 2 || iat 5 99°3 097157 091 0 a 3 | 36901-2 08-930 08:7 0 ~ aI 04:2 08-054 | 08-2 2 . * 16:2 | 07-41 | O75 In ee ee 25-0 | | 07-4 2 2 ” 06°6 1 a 99 | O56Rh | In - i! 05:416 | eae!) a i 52-2 04:99 | 04:9 [i oelae ; 3 58-0 04:65 04:7 2 ¥ a 62:7 04°31 04:4 1 ‘ 5s 67°3 03°891 04:0 2 Bs x 7371 03-403 03:7 0 a - 79-7 03-221 | 03-0 0 2. Es 823 02916 | 02:92 02:8 4 ff e 86:4 01:434 01-5 4 = a 87:0 / 01-09 01-2 2 es 10:8 97-6 ae | 00°77 00:8 0 x a 37015°6 A 1 ” 23 18:3 00°32 00°3 2 3 3 21'8 2699-957 00-0 1 # oe 26:8 269942 2699°5 1 % a 34-2 98-80 O-line 98°23 39 = 98-161 0 % as 51-4 1 > ” if 97°595 | | 97:8 0 a A 59°3 | 97°4 2 ”> ” 97:18 ¥ i 96-653 | 96:7 0 ae . 72-2 | 94:85 : ne 1 kg aa 97-0 9) 1 99 ” 94:25 94:3 1 Bs » 37105°3 93:9 1 pi nt 93°750 93°75 93-6 0 3 = 12-1 93-392 93°39 2 at SNe 17:1 92-199 ? 92:20 92-08 4 5 s 33:5 90-904 0 Cee 51-4 90-487 90°49 | 90-4 1 2 - 57-2 89-51 | 89:6 1 i A 70:7 88-969 88-97 1 Cea ee 78:2 88-668 1 Li of 82-3 88-216 88-22 88:4 1 ms Eas 88-6 87-580 87°58 87:7 1 o Be 97-4 87-214 | 87-21 87°3 1 PR ie a eck 2h | | 86-94 87:1 2 i ae 06°3 86:375 86:38 86°5 4 | apes im 14:0 85-94 86:1 | 1 ie i 20°1 | 85°57 85°8 aie ig ae 25-2 85:242 | 85-24 | 85:4 oeee, Peay |) 29°7 112 REPORT —1904. RUTHENIUM—continued. Spark Spectrum Reduction to Oscillation Frequency in Vacuo 47239°5 44-6 5074 63:1 93°4 37304'8 18-7 20°T 30°9 38:7 43:5 52°3 64:2 68-4 82°5 87°8 90°6 92°5 99-0 374079 30°9 33°9 60:4 64:5 69°8 77°6 375012 04:9 09-4 14:9 28°8 41°6 50°2 55-7 59-2 65°4 71°6 Wawve-length Intensity We (Kayser) E a and 1 Are Spectrum Adeney Haschek Character | y+ a 2684:540 | 2684:69 2684°9 0 0:77 | 10°8 84:172 | | 84:3 Rh 1 “ 33 83°756 | 1 ” ” 82°84 82°9 In ” ” 81-5 1 ” ” 80°66 80°7 2 ’ 2 80-0 1 > ” 79°843 19°F 1 ” ” 79°54 3 78°837 78°84 78°79 4 » 10°9 78:267 78:27 78°3 0 ” ” 77-967 0 ” ” | 77°406 77°5 0 ’ ” 77:057 77:0 0 ” | ” 76°86 ” ” 76°430 76-4 2 a a 76°27 2 ” 75°58 75:7 2 ” ” 75°273 75°27 15:2 0 ” » 74:27 74°4 2 > ” 73°930 73°7 0 ” ” 73°691 73°7 2 Py 9 73°550 2 ” ee) 73°089 73°09 73°2 0 ” ” 72°6 2 ” 2” 72-451 72°45 72°5 0 » ” 70°813 0 ” ” 70°586 70°60 70°7 0 ” ” 69°6 2 ” ” 69°24 ” ” 68°71 68-7 1 ” » 68-421 0 ” ” 68-042 68-1 1 9 =| 67°89 ” ” 67:479 67:48 67°35 1 » ” 65°803 1 ” ” 65-542 65°54 65-4 0 ” ” 65°227 65°1 0 » » 64°833 64°83 4 9 » | 64°65 ” ” | 63°85 63°6 1 ” ” 62°94 63:0 2 33. >| .95 62°36 62°3 2 ” Neo ins 61:937 | 0 2” ” 61-690 61:69 61°64 4 ’ ” 61-249 61°25 | 61:20 2 ” 60-673 | 60°8 0 39 » 59°64 59°8 2 ” 9 59°5 In } PA 58-862 0 ” 58-482 | 68-4 2 i ¥ 58-28 | ” ” 57:249 57:25 57°3 i » et 56°776 1 ” 11-0 56°641 1 ” ” 56°328 56°33 56°35 1 88-2 99:2 37604°6 22-0 28°6 30°5 35°0 | ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 113 RUTHENIUM—continued. = Spark Spectrum Reduction to Wave-length Intensity Voie | Oscillation (Kayser) an Frequency Arc Spectrum Adeney eee Character | y+ i- in Vacuo 2655°292 1 0°77 | 11:0 37649°6 55°193 0 oN ass 51:0 54:898 2654:90 2655°1 0 O276. | ss 55:2 54°563 54:7 0 i + 60:0 54:2 2 » ” 54-01 » ” 53°776 1 “ or 71:2 53°240 53:2 1 3 - 78°8 53°05 2 ” 52°7 1 ” ” 52°240 52°3 0 FD =p 93-0 52°05 ” ” 51-936 51°94 52:0 zt A cy: 97°3 51-603 51:7 Rh? 0 Er rp 37702°0 51:366 51°37 51°5 2 33 “ 05-4 50-968 50°97 0 or _ 111 50°693 50°6 0 op % 150 50:486 50°49 50°4 1 3 op 17:9 50°21 50:2 1 ny aa 21°8 50-076 0 o 4 23'8 49-608 49°7 2 s “ 30°4 48-872 48°87 48:95 2 ay op 40°9 48-706 0 By - 43°3 48°535 1 a a 45°7 47:019 48-1 1 sy y 53:1 47394 47°5 2 A ne 62:0 47-0 1 ” ” 46°715 0 “ a 717 46-087 46:09 46:1 2 . PD 80°7 45°3 1 ” ” | 44-711 44-71 44°7 0 Fi 3 37800°3 | 44°187 0 3 fe 08°6 43-600 43°60 43°7 0 ” ” 16:2 43°3 2 op of | 43°042 43°04 43-1 4 op Ae 242 | 42°607 42:5 0 is Op 304 42°3 1 ” ” 42-063 42:06 0 ” % 38:2 41-72 41°7 2 = “ 43°1 41-549 0 3 55 45°6 40°413 40°41 2 sme b S 19 39°67 39-7 2 5 ii 125 | 39°205 39°3 2 op a 79°4 38°597 38°60 38°6 2 a3 PY 87:9 38°5 1 ” ” 38:2 1 = ” 36°95 36°9 1 e ns 37911°6 36-760 36°7 2 as 33 14:3 36°617 36°62 0 3 5: 16°4 35927 35°93 36°0 Pd 4 ” ” 26°3 35°451 35°45 35°4 0 -n rh 33°2 33°93 ” ” 33°7 1 ” ” 33°537 0 F. % 60°8 32°85 32°9 2 5 3 70°7 32°584 32°5 1 98 i 745 1904, 114 REPORT—1904. RUTHENIUM—continued. Reduction to | Spark Spectrum Wave-length | A 2 | Intensity aS Oscillation (Kayser) E a and 1 Frequency | Are Spectrum | Adeney Hache | Character | 4 3 in Vacuo | 2632-210 | 2632-4 0 | 0°76 11:0! 37979-9 31°657 / 31:7 1 eee i! 87°8 | 315 1 ” | ” 2631-22 31°3 2 st kas 94-1 30°314 1 = >c 38007°1 30°19 30°2 2 + oo 090 CO 30°010 0 += mS 11°6 29°49 29°5 1 a = 19-1 28-91 B29 | 2 iP AG Bo 27-5 28-621 0 9 | 31°6 28°375 28°38 | 283Pd? 4 ” | 35:2 27°90 | ” ”? | 27°737 27°74 ) 1 a | eee 445 27°5 1 Ss. | Lioe 26°60 26°5 2 eh i595 60:9 26°444 0 aS <5 63-2 26290 | 26-1 0 pote fates 65-4 25°95 | rad ee 25°59 25°6 1 = Ss 75°6 25°5 2 ” ”> | 25-168 25°2 0 ~ = 81-7 24°87 | 249 1 * = 86-0 24°35 |; 24:3 1 “s 2 93°6 23-914 1 +s 99°9 23-76 | 23-7 In * & 38102°1 23°51 ” ” | 21 1 a le | 22-9 1 sae he 22-4 In RYU ss 21°91 21-9 1 42 - 29-0 21-46 | 24-4. 1 oth os 35°6 21:173 | 21:2 0 ss Sibees 39°8 20-713 20°71 20°8 2 7 = 46-4 207154 | 20-15 20°2 0 2 = 54°6 19°745 19°8 2 -- - 60°5 19°42 19°5 2 = + 65°3 19-105 19°2 0 -A = 69°8 18-68 ” ” 8 : | f 18-0 1 ~ “r 7°7 17-882 { = 44 : wi pes 17-29 17-2 2 3 + 96°3 16°50 16°5 1 Pe! Mare 38207°9 15-7 1 ”» ” 15179 15°18 15-2 2 = | = 27:2 14°93 15-0 2 Ss = 31-0 14-671 14:8 Pd 2 A 5a tl 34°6 14151 14:15 14-2 L = == 42:2 14-0 In os the Se kl 1337 | 13-4 In i 53-6 137143 0 5 +. 57°0 12-990 0 ae 59-2 4 12-63 12-6 2 Aa eee 64°5 IZA |) A217 12-2 2 - ae 71:3 11-99 12-0 1 ” ” 73°9 / 11-63 11°6 2 se = 79°2 11:130_ lee | 74 2 = aan 86°5 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 115 RuTHENIUM—continued. . : , | Reduction to | Spark Spectrum Wave-length 5 e Intensity Vacuum | Oscillation (Kayser) a= <= 5 an | ene | Frequency Are Spectrum ‘Adoney Los Ain Character 4 :- in Vacuo 2610718 _ 2610°2 2 0°76 | 11°0 38300°3 2609°573 09°57 | 09°6 2 0°75 | 09°5 097143 09-14 09-2 aa 5 11-2 15°5 | 08°5 1 ” ” 08-024 08-02 | 08-0 1 a 7 32-0 07°440 0 3 ric 40°6 07°18 Fe 07:0 1 = Bs 06°40 06°4 2n rr on 56°8 05-950 06:0 2 3 a 62°5 05-439 05°5 2 oe op 68-4 04409 04:41 04°3 0 “ p 85-2 03°43 0374 In os or 99°6 03-00 03-0 1 a o 384060 02°49 02°4 2 53 13°5 01-553 01°55 01:6 2 = + 27°3 01-392 0 a ne 29°7 00-840 00°7 0 9 os 37°9 00°5 ” ” 00-00 2599°9 1 re a 50°3 2599°53 Fe 99°6 a ” ” 99°5 1 ff “ 98-99 Fe 99-0 2 a3 Fe 2598-681 98°68 98°6 0 ” ” 69°8 98-07 98-1 2 “ 789 97°84 97°7 ul x oa 82°3 97°417 97°42 97°3 1 ” ” 88°5 96-043 96-04 96-0 0 ” » 38508°9 95°734 0 a re 125 94-926 95:1 2 HF rh 25°5 94°65 94°6 1 a of a 29°6 93°79 93°9 In a aS 42-4 93°6 In a rr 93°3 In ” ” 93-1 In FP a 92°3 1 ” ” 92-093 2 re FC 67°6 91-710 0 a a 73°4 91:44 91°5 2 5 a 77°4 91-201 91:20 91°3 2 + cf 80°9 91-087 1 A A, 82°6 89-886 89:9 0 a a 38600°5 89-649 89°65 89°6 2 F er 04°1 89-129 89-0 0 a rp 11°8 88-08 88-1 1 a 11°3 | 27°3 87-413 0 a an 37°3 86-95 87:0 In ag as 44-4 86°157 86°16 86-0 0 xs fr 56°1 85815 . 0 oe *r 61:2 85-412 85°6 1 oa 7 67:2 84-211 84-4 2 a op 85°2 83-131 83°13 83:2 2 5 a 387014 83-1 1 ” ” 82-7 1 ” ” 82°48 ” ” 81-990 82-1 2 7 se 20:0 . 81:6 1 7 Py 116 REPORT— 1904. RUTHENIUM—continued. Wave-length (Kayser) Arc Spectrum in Soe. 2581-216 80883 80316 79°879 79623 79°309 79-071 78°653 "77-052 75°339 73654 72512 72°370 71-068 70°180 69°840 68°854 67°981 66-666 65°277 64°674 64°503 62-252 60-920 60°347 Spark Spectrum Reduction to Intensity beg Oscillation Exner and | Cl and ey eel Adeney Haschok haracter | y 4 a= in Vacuo | 2581-23 2581°3 2 0°75 | 11:3 38730°1 81-0 1 ” » 2 ” ” 35'1 80°32 80-4 0 39 9 43°6 80:08 ” ” 79°94 79°8 0 oc es 50°2 2 ” ” 54:0 79:3 | 1 A A 58°7 79°10 2 os os 62°4 78°65 78'8 2 2» | 99 68°7 78°4 1 ” | ” 75 1 Sirs dee OF 7711 77:2 0 rhe bees: 92:7 76°17 76°3 2 Se 38806:0 Wer 2) ol Mae. nh eae } 1 ” ” 18-5 74:8 1 | 9» ” 74:20 74:3 1 ih oe 39 35°7 73°65 73°6 0 1 Sees 5 44:0 73°3 1 haa » 73°09 73°0 ] *y Pea 52°5 72°71 72°7 In - “5 58°2 2 a or 61:2 2 I) a5 ria ah 63:3 ileal; lee 2 I ae or) 81-4 70°8 2 as or 83:0 705 1 ” ” 70:0 0 poe elf) ety 96-4 69°84 69°8 2 ee ee ey 38 01°6 69°5 1 fy 2 68-93 69:1 2 |» _ 15-4 4 oo» » 16:6 68:2 1 | 3 11-4 1 : a 29:7 67°7 1 esc P 66°67 66°8 2 lias “5 49°6 66°30 66°5 2 or FE 55:2 661 1 less 65°77 65:8 2 Hess “6 63°3 65°5 Pd 1 ell se 1 ” ” 70°7 65:1 1 | ” | ” 64:73 64:9 1 | O74] 5, org) Gh a ees 64-02 64:2 2 oo aq) t| 89:9 63°78 63:8 1 x » | 93°5 63°38 63°5 1 FA EF 99-6 63-00 63:2 1 ” ” 39005°4 62°58 62°8 1 Tues 11°5 iM IGF 62°4 2 “s ay 16°7 61°7 1 lies = 61-4 1 / 29 ” 611 1 | = ; 61:0 3 Peis | ee 37°0 60°35 60°5 2 Foe lh een 45°7 1 | ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. {UTHENIUM— continued. BLA Wave-length (Kayser) Are Spectrum 2559°497 58-626 58-359 57°784 56-994 56°100 55:955 55-734 54790 54-060 52-965 52524 52°384 52-083 51°822 51-466 50-946 49-664 49-576 49-260 47-600 46°765 45°866 44-318 43-778 .43°349 43:240 42-601 41-381 40-411 39°822 38-565 37°776 36°315 35°147 Spark Spectrum | Exner and Adeney | Haschek 2559°60 |. 2559-7 58-91 58-63 | 58-7 58°13 | 58-2 57°78 | 57:9 57-25 57:3 56-96 56-9 56:10 | 56-2 55:96 55:9 55:0 54-5 53-58 53-6 52:08 | 52:10 51:82 | ~ 51:7 Pd | 5-4 49-92 50-0 49-6 49-26 49-3 ° 48-86 49-0 48-1 47:80 478 47:0 46:81 46:01 45:8 45:10 45:1 44:32 44-4 43°35 43°38 42-24 42-3 41-6 40:41 40°43 39-82 39:90 38-1 37-78 37:6 37:18 36°60 36:51 35°80 35°7 35-42 35°5 35°15 35:1 34:23 34:2 33°66 33:6 | Intensity | and | | Character . POW NWE EH ONNNE ER OSOCOOP REE PONNONMMON Cc =] 5 5 COMP OrcoorFNOONrFN RPDNonno Reduction to Wii Oscillation | Frequency Petes oes in Vacuo | ~ 0:74 11°5 | 39058:7 ” 23 ” 3 | 72:0 Ae aa 761 7 ee | 79°6 3° ” | 84:8 ” | ” | 93-0 x | ea! || 96°9 eis : 39110°6 ae eo 128 > | 9 | 16:2 2 | ” 30°7 1 Ors | be 41°9 et ss oil 46-0 22 oe tl 63°5 9 9 65-4 2 99 68:5 | 39 29 72°3 eee a ae 76:2 33. ” 81°6 ” ” 89-6 a5 » | 39205-4 » ass a 09°4 ess 99 10-7 ae ae 15-6 ”> ” 21-7 ne aoe 41:2 ” bP) 54:0 ” } 29 67:8 ” | ” 79°6 ” ” 91-6 fr » | 39300° 9 ” 06°7 9 ” | 08°4 23 el 18°3 ” > 23°8 » 9 371 > | 7) 52:2 ie teen 61:3 ” ! ” | 80°9 9 | ” 99 99 93:1 ” 99 ” ” ees ae 39415°7 ” ” 23°8 ” 2? 29:7 » 09 33:9 ” ” 48°2 ” 571 118 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum : Te etrGhl ites Wavye-length Intensity Oscillation (Kayser) ee es. and i Frequency Are Spectrum Adeney pecan Character | + — in Vacuo | [ 2533°331 2533°33 2533°3 I O74 | 115 39462:2 | 32°128 | 1 mp 5 68°7 30°67 30°6 2 25 a 39503°7 30°40 30°2 1 ce on 07-9 29°812 29°81 29°7 1 cb 116 17:0 28°813 0 os on 32°8 28:027 28°03 28-00 0 “ x 45-0 27°19 27:2 In PAW neers 58-1 26°914 Del 24 ” | ” 62-4 26-011 0 5a aS 76-7 25°726 25°68 25°6 Ir 0 e 3 81:0 25°263 0 or *s 88:3 25°12 ” ” 24:952 24:95 25:0 0 s a 99-9 24:6 1 ” » 23°9 1 ” ” 23°3 1 ” ” 22°83 22°8 1 os “s 39626-4 22-410 22°5 0 A: a 33°0 21-700 21°9 2 P 3 44:2 21:08 21:0 2 2 on 53°9 20-925 20°89 20°8 1 as a 564 20:041 0 x 5: 70°3 19°49 19-32 4 aa a 78°9 18-601 18-60 18°55 0 re “ 94°6 17°728 2 “f “ 39706°7 17°403 17°40 17°38 2 sr a5 11:9 17:00 ” » 16°882 16:9 0 ef An 20°1 16°25 16:2 In = “3 30°0 15°74 158 1 op = 38-1 15:372 15°5 1 er: 3 43°9 14:10 14°3 In An 5 64:1 13-417 13°42 13:40 2 “5 99 74:9 12:898 13-0 2 Fs a 83:1 12°79 12°7 1 a = 84:8 11-652 11-7 1 py 11°7 39802°7 11°41 11:4 In & “6 04:9 11-058 0 sel ee 121 10-238 0 Suet eke 25:2 09-709 09°6 0 ¥9 3 33°6 09-160 09-2 1 Onion biass 42°3 08-508 08-81 08-80 2 ame bss 52°6 08°377 08:4 2 NE 9s 54:8 07-090 07°13 07°16 2 ” ” 76:1 06°61 06°6 2 99 a 82°7 | 06:5 2 ” ” | 06°18 06°1 1 ie aa, 91:2 : | 05-73 05:8 Pd 1 B20, 96°38 | 055 1 % os | | 05°13 05-1 1 ames 39906°3 | 03°40 03°4 1 3 99 34:0 02:966 | 03-0 0 35 os 40°9 02°484 02°48 02°5 0 5 a 48°5 01-990 02°12 02:1 0 ” ” 56°5 01:569 017 2 ” oF) 61:2 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. RUTHENIUM—continued. Wave-length Spark Spectrum is oe) = 5 re Spectrun xner an . so Haschek 2500-940 00-484 2500°36 2500°3 2499°873 2499°-9 2499-60 99°5 99:2 98:670 98°67 98-7 Pd 98-512 98°6 98°1 97°14 97:0 95°775 95°88 95'8 94°773 94°77 94°6 94:22 94:3 94-116 94:00 93°80 92°9 92°3 92:1 91-847 91°85 91:6 91°4 91°10 91:2 90°555 90°7 90:017 89°34 89:5 88°58 88°7 Pd 88°3 88:1 87:7 87:26 87°3 86°7 Pd 86°31 86:3 84-66 84-055 84:06 84:2 83°82 83:7 83:3 83:0 82-628 82:0 81:83 81-216 81:22 81°30 80°83 81:0 80°3 79-611 79-458 79:010 79°01 79:02 78°33 78°5 78:2 77:22 77°4 77:1 76:960 76°6 76°395 76°4 75483 75:0 74:506 74:55 74115 74:2 73°55 73°8 72°81 73:0 72:215 72:22 72°6 Intensity and Character Ree eee LNDNONEF NE RENE RENE RE NNRKRKNOSO RONERrO CNrFKONNONKEFNKENNOOKNS Reduction to | Vacuum Re = ar 0: . 73 | 117 | ” ” ” | ” ” ” ” | ” ” ” ” ” ” ” ” ” ” ” ” ” ” ”? te 11:8 ” ” ” ” ” ” ” ” ” ” ” ” ” | ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” ” cP) ” ” ” ” ” ” ” ” ” ie LS | ” ” ” ” ” 2? ” ” | ” ” | | ” ” ” ” Oscillation | Frequency in Vacuo 39973°3 80°5 90°3 94-7 40009°6 12°1 34:1 56:0 73°6 81:0 82:7 40119°1 - 311 39:9 48°6 59°5 71:8 93:1 40208°5 45:0 478 68:1 81:0 91:0 97:3 40317: 19°6 40400°2 06°6 158 27:9 37°6 i 120 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length P Intensity ee Oscillation (Kayser) 4 and i F Frequency Are Spectrum Adeney Benet pnd Character | ) 4 = in Vacuo 2471-576 2471'3 0 0:73 | 11:9 40448°1 71:3 1 ” ” 70°805 0 ” » 60°7 70°608 2470°61 70°7 0 FP) ” 64:0 68°8 1 9 9 | 68°5 1 el i 67-674 C767 | FF 0 7 » | £05121 67°5 1 ” 3, alt 67°3 1 ” ” 66:4 In 7 a 65°7 il 2” ” 65°5 1 ” ” 65°1 1 ” ” 64:781 64:78 64:9 2 “ 9 59°7 64:474 0 As Py 64:7 64:0 1 »” ” 63-026 63°03 63:1 2 “ a 88-6 62°8 1 ” ” 62°20 62°3 1 ” ” 40603°2 61:506 61-7 0 9 ” 13°7 61:5 1 ” ” 60°57 ” » 60°17 60-1 1 59) CHS 35:7 59°6 1 ” ” : 59°4 1 a ve 59°146 59°15 0 or 12:0 42°6 58-706 58°8 Rh 2 a millcaaes 59°8 57°31] 57°31 | 574 0 eal ess 82-9 57:050 1 elle es 87-2 56-666 | 56-70 4 s ia 93-6 56°519 56°59 56°60 4 ” ” 96-0 56°376 0 al | ect 98°3 55°614 55°61 55°66 5 9 a 40712-0 55°005 549 2 =p seis | 21:2 54:267 54:27 54°4 0 26 i 33°6 53°85 54:0 2 a " 40°3 52°6 In ast as 51:27 51°4 2 sel 5s 83:2 511 2 Pd ye 50°650 50°90 50°7 1 ” ” 93:5 50°464 50°46 50°6 0 +. ss 96°7 49-958 1 - aL 40805 0 49°6 2 55 48-958 48-96 49-0 0 “5 5 28-0 48°4 1 as rg 47°537 47°6 In és # 45:4 46:9 1 be Bs 46°7 1 ” ” 45-519 45°52 0 ” ” 79-1 44:924 | 0 a 3 89:1 44-497 | 44°5 0 ” ” | 96°2 44:129 44:2 1 ” pe | 40902°4 43:48 43-4 2n x =| 12-1 13:2 43:036 0 ne is 21°6 41°82 | 41:6 1 | 41:0 | \ { | se ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 121 RUTHENIUM— continued. Spark Spectrum paon. = Wave-length Intensity Oscillation (Kayser) an rae Frequency Are Spectrum Adeney Exner and | Character! , 4 | Es in Vacuo Haschek A 2441°419 2441-42 | 2441-4 0 0°72 | 121 40947°7 41:051 41:05 40°9 1 3 “A 53°9 39°715 39°72 39°7 0 95 a 76°3 39°3 1 9 » 39:0 1 ” 0 38°8 1 ” ” 38°5 1 ” 93 37°3 1 251 2 37:019 37°1 0 ~ Pe 41021°7 36°6 1 amelie 363 1 ” ” 35°53 35°62 aa a rp 46°8 34-980 34:98 35'1 0 ” ” 65°9 33°81 34:0 In m “3 TT 33:2 In “ an 33°0 1 a | 32-25 32°3 2 a « | 41102-1 31:6 1 ” oh 30°8 1 ” inst 30°45 30°5 2 48 Py 32°6 29:672 29-6 2 foal | ey 45°7 29°4 1 srolingses. | 29°1 1 saeciy seen 28°98 29-0 1 35 Sy 57°5 27°82 27°8 2 i 12:2 77:0 27:26 27:2 1 56 es wy) 86°5 26°96 ” ” 91°6 26°66 26°7 1 a * 96-7 26:0 In Pea ear: 25°7 ea ease erin Fa. 24°56 24°6 1 mts y 41232°5 23°7 In en ee 22:91 23:0 2 a iy 60°5 22°30 22°4 2 Be ene 70°9 21°4 1 0-71 oD 20°905 20:9 2 te ns 94°7 20:24 20°3 1 ” ’ 41306-0 20:2 1 ” 9 20:0 1 ” ” 19:04 ia 1 35 ie 27°5 18-6 1 ” 9 18°3 1 ”? ” 17:05 Lt7Gi 2 3 5 60:6 16°64 9 9 15°82 158 2 iS a 81:6 15°30 154 2 a “f £0°5 14:93 14:9 2 3 55 96°9 14:00 14:0 2 ” ” 41412°8 13°60 13°5 2 fe es 19°6 13°32 ” ” 12:9 1 9 » 12°6 1 ” ” 12-1 1 ” 11:62 11:7 l ds 12°3 53°6 11°5 1 5 Of 11-2 1 ” ” 122 REPORT—1904. RUTHENIUM—continued. Reduction to Spark Spectrum Wave-length e : Intensity Bede Oscillation (Kayser) Nl and l Frequency Are Spectrum Adeney Exner and | Character | ) + ase in Vacuo Haschek r | 24108 1 0-71 | 12:3 2410-24 | ShOS 2 7 a3 414773 | | 10:0 1 ” ” 09-7 1 ” ” 2408-744 08-7 1 ar) Lees 41503°1 08°51 ” ” 07:997 08-00 2 DS ss 16:0 07:37 07°6 1 3 xy 26°8 07-1 1 9” 9 06°67 06:9 u re 2 38°9 06:12 ” ” 055 1 ” ” 05-4 1 35 = 05:00 05:1 1 re ket 67:7 04:9 1 99 ” 04:6 1 9 ” 02-802 02°80 | 02-90 4 a “5 41605'8 01:93 | ” ” | ecOLes | (ORS 1 oe a5 33°8 00:7 In ” ” 00°38 00°3 1 $5 “6 478 | | 9399: 28 Pe ns 98-63 ” ” _ 2398: 0 2 9 9 97 70 97:2 2 as 12°4 99-7 2396-791 96°79 96:90 2 on “4 41710°0 96:0 In a “5 95:66 95°6 1 “D a 29-7 95°3 1 ” ” 95-0 1 ” ” 94°70 99 ” 94:2 2 ” ” 93°84 93-7 1 ” ” 61:5 93°3 1 ” ” 92-501 92:7 2 i - 84:9 92°1 2 oo “5 91°73 91°8 1 x a4 98°3 |} 91-4 1 ” ” 90:6 1 Efe sao 90:4 1 ” ” 90°1 1 ” ” 88:5 1 ” ” 88°3 In 7 1 87-28 ” ” 84:3 1 ” ” 83°53 83:7 2 ” ” 41942:2 83:0 1 ” ” 82:08 82-18 4 nh 12°5 67°6 815 1 ” ” 81-2 1 is “6 81-0 1 ” ” 80°8 1 ” ” | 80°1 2 ” ” 79°94 79:9 2 ” ” 42002°4 79°54 | ” ” 77°6 In ” ” ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 123 RuTHENTUM—continued. Spark Spectrum Eedietion ve | Wave-length | Intensity arses Oscillation , acti | = ‘ | est a E eeeaneey re Spectrum xmer an aracter i. in Vacuo ‘ ied Haschek og ae 2376°30 2376°6 2 | O71 | 12°5 42069°7 ee 7 OFTL 75°80 4 ho Soe ayes 80°2 75°6 1 ee 2375°346 75°3 2 s 33 86°6 75-1 1 cr “ 74:3 1 ” ” 72:08 72:2 2 0:70 - 42144°6 70°251 70°25 70:4 2 | ~ 99 ” 771 | 702 1 ee 3s 68-7 In 3 : 68-2 Ir 1 pial All meer 67°31 67°5 2 5p 12°6 49929°4 64°6 1 » » 64:13 64:3 In op nS 86°3 63°7 In # # 62°9 1 ” ” 62°47 62°7 1 ” ” 42316°0 62°3 1 9 ” 60°8 In os 0 59-14 59°3 2 =: os 71-7 | 58-90 58°95 4 ih Aras 80:0 57-991 | 57:99 58-10 2 SS ie tes 96:2 | 62:92 53:2 2 ey) TBST 42487°7 51-411 | 51°6 2 on ay 42515°0 £1:23 51:3 1 a oh 18:2 £051 50°7 1 PA FP 31:3 £6°45 46°6 1 a Ff 42604'9 44°7 1 “ cb 43°6 1 ” ” 42-920 42:92 43:03 2 ” » 69°1 42°66 42°7 2 5 3 756 4111 ” » 40°767 _ 40°77 40°8 2 ” 12°8 42708°2 40-00 40°2 1 PP ae 22-2 39°4 1 ” ” 38°9 1 ” ” 38094 38-05 38°1 2 ” » 57:1 36°93 37:0 2 33 Pr 78:4 36'1 1 » ” 35:047 35:05 2 ” ” 428129 34°5 1 ” ” 34:05 34°71 2 ” ” 31:2 33°72 33°8 2 Saditca 37-2 32:26 32°5 In ae oss 64:0 31°81 31:9 1 ” ” 723 31:23 | 31:3 2 55 » 83:0 29°11 29:2 2 FP Hy: 42922°0 28°5 1 | % ” 28°1 1 ” ” 20°82 | 069 | ,, 20°0 2 Pe lane 18:7 1 ” ” 13°51 13°6 1 on 13:0 43210°4 09°3 1 ” ” 08°8 1 ah | sk 08-6 1 Te ol 124 REPORT—1904. RUTHENIUM—continued. Lohse, ‘ Sitzber. kaiserl. Akad. Wissensch. Berlin,’ xii. 1897. Exner and Haschek, ‘ Sitzber. kaiserl. Akad. Wissensch. Wien,’ ceviii. 1899. Kayser, ‘Abhandl, kénigl. Akad. Wissensch. Berlin,’ 1903. ee | Reduction to park Spectrum ; Vacuum ate Wave-length | Intensity Oscillation (Kayser) E a | and Sar | Frequency Are Spectrum Adeney Haschek | Character | , + 5 | in Vacuo 2308°1 In 0:69 | 13:0 2305'85 05°7 2 “5 » | 48356°0 04:97 ” ” 03:06 | ” 29 / 2298°80 2298°7 | 1 ap 13:1 | 87:9 97:28 97°5 1 a » | 484166 94:6 | 1 if ae 94:2 | 1 AS + 87:2 87:2 2 x 13°2 43708-4 83:2 | 1 ” ” 82 00 81:8 2 “3 * 43808-0 81-7 | 1 ” 2” 79°7 1 0” ” 79°4 In » | 8-7 In . S | 72:3 In 0-68 + 68-26 68:3 1 a5 isd 44073°4 63°73 63°6 1 aa alas 44161°6 | 61:1 1 ae ee | 51:7 1 ” | ” YTTRIUM. Reduction to | Wave-length | Intensity anateen Lohse Neonat Oscillation (Kayser) and Tisneriand Are Spark Frequency Are Spectrum | Character THaschor x: Ae | in Vacuo my TF 6701-188 2 | 182 4:0 | 14918-7 6687°892 2 a “ 50°6 56°056 1 181 | 4:1 15019°8 50-880 1 ” ” 33°9 13-988 1 1:80 a 151154 6585:077 1 1:79 5 81-7 77:096 1 a5 a 15200°2 64:059 1 1:78 +5 30°4 57:568 2 ” ” 45-4 38-797 3 | ” ” 89-2 05°611 1 | 1:77) 4:2 15367'1 6437:414 1 | L75'e 55 15530°0 35226 5 a5 re 35°3 02°229 33 1:74 ” 15615°4 6396°588 1 | of | > 29°1 6275:214 i | 171 | 4:3 15931°4 36°962 b 1:70 | 5 16029°2 22-787 4 169 | 4-4 65°6 18-150 b 39 3 viv) | 00:043 b AD ” 16124°7 6191:930 1 1:68 x 45:7 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS, YTTRIuUM—continued. Reduction to 125 Wavye-length | Intensity Pe Sed Lohse NACHE Oscillation (Kayser) and havosand Arce Spark Frequency Are Spectrum | Character Hacchak en bas in Vacuo peas 6182°455 b 168 | 4:4 16170°4 65°310 b 33 ap 16215°4 50°935 1 1°67 ér 53°3 48-624 b 5 cH) 59°4 38°645 aa a “ 85°9 37°893 1 FP FA 87°8 34°240 3 “ aS 97°5 32°343 b ” 22 16312°6 27°610 1 ” ” 15:2 24-701 1 oF “5 22°9 14:954 1 a fC 49:0 08-050 1 1-66 i 67°4 02:967 1 s op 81-1 6096-999 1 | or “ 97°1 89:597 1 a: oP 16417:0 88-190 2 | “p 4:5 20°7 82-800 1 | as rr 35°3 81-448 1 or Ap 39°0 73034 1 1:65 +c 59°3 60-526 1 Me - 95-7 53-998 b rp Ay 16513°5 42:778 1 1°64 a 44:2 40°463 2 “ a 40°5 36°833 b of . 60:5 25°513 I - os 91°6 23°624 2 ” ” 96°8 20°105 b on of. 16606°5 08-424 2 ” ” 37°8 07:929 1 sp 3: 40:2 04:906 1 1°63 3 48°6 03°810 b 3 nS 51°6 5987°870 b af re 93-1 827133 2 65 167119 72°324 b A “A 39°4 66-439 1 1°62 ar 55°9 50°249 2 “5 4°6 16801-4 45:946 2: 2 3 13°6 45-081 1 s “ 16:0 03:201 2 1-61 a 16935°3 5880-218 1 1:60 cE 17001°5 72:072 1 on 4°7 25:2 32-480 1 1:59 ae 17138°7 22°064 2 Fr Fy 75°4 12°888 1 1-58 rE 98-6 5797°348 1 op rf 17244°6 87:907 1 oc rb 72°7 81-901 2 ” ” 90°6 65-849 3 Pe a 42:9 44-046 3 ” ” 17404°5 43-567 1 BAe», ae 06-1 40°417 1 1:56 > 15°6 29:087 3 $5 os 50:1 27-090 ] Oe ieee 56:2 23-663 2 = tare 66-6 20°801 3 aides 753 126 REPORT—1904. YTTRIUM—continued. Reduction to Wave-length Intensity Ss Be. Lohse eee Oscillation (Kayser) an Ean enand Are Spark Frequency Are Spectrum | Character : 1 in Vacuo iz | | Haschek A+ a | | 5706926 5 1:56 | 4°8 17517°9 5675°480 3 1°55 os 17614°8 75311 2 ” ” 15°3 69°456 1 | + on 33°6 68-784 1 a5 a 35°7 * 63°148 6 | 1-54 op 53:2 61:107 1 | oes a5 59°6 57-479 1 - an 70°9 48-684 5 a a 98-4 46-909 2 a os 177041 44°898 4 2 + 10°3 35-966 1 ” ” 38°4 33°121 2 a on 47°3 32°477 2 * of 49°4 30°353 5 5; 4 56°1 24114 2 | 55 5 75°8 10-580 1 1°53 4 17818°7 06°552 3 “5 4:9 31-4 5598°537 1 5: 5 56°9 91-168 2 5 of 80°4 82-098 5 1°52 ~ 17909°5 81:295 2 oF 39 12:1 77°62] 4 > “6 23°9 67°972 3 +s ae 55°0 56°655 4 5 = 91°5 51:209 2 1-51 “ 18009°3 46:228 4 ss op 25°4 * 44-818 5 - 5 30:0 41°852 3 Rees = 39°6 27°765 6 | 35 H 85°6 25:°944 2 a5 - 88°3 21°845 6r +o 18105°0 13°856 2 1:50 “5 31:2 * 107115 5 oe N 43°5 03°665 5 os 5-0 64-7 5497°637 5 Pr a 84°6 95-802 2 ” ” 90°7 93°375 3 os as 98:7 91°634 2 35 on 18204°5 80-952 3 Hp x 40:0 73°596 4 1:49 * 64:5 66°669 6 ae i 87°7 38447 4 1-48 A 18382°6 24:588 3 A 4 18429°5 17246 2 » 0 54°6 * 03-003 4 5 xo 18503°2 5388-623 1 147) 51 52°5 80°851 3 x5 + 83-9 5290-004 2 1-45 | 5:2 18898-4 70°527 3 | 1:44 “a 18968 °2 69-712 5 | [fs gg a 71:2 40-958 2 | JCA) IP se 19075°3 * 05:890 6 | 1:42} 5:3 19203°7 00°580 5 + oF 23°3 * Rowland: 56637155, 5544°831, 5510120, 5402-982, 5205°897. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 12 YTTRIUM— continued. Wave-length (Kayser) Are Spectrum Spark Spectrum. Exner and Haschek Intensity d an Character Lohse Are Spark | Reduction to | Vacuum a A 1 Oscillation Frequency in Vacuo 7 5196-588 35°356 * 23°380 19-283 03:941 *5087°600 73°344 70°363 07:134 4982-297 74466 48:740 31°129 28°427 26°503 22-063 12°236 09-185 06°275 * 00°304 4895-436 93-620 86-832 86°464 * 83°881 81-629 79°832 79-339 63-303 60°031 56-896 55073 54°437 52-860 45°862 40:052 39°335 26°438 23°497 23°310 21°813 19°857 18-396 17-589 04986 04502 4799°491 87:078 86°753 81:217 80-360 66°280 63°142 61-169 2 VISE SSI Ae aS IL la hale aad 5:3 * Rowland : 5123-390, 5087-610, 4900°301, 4883-867. 19238°1 128 Wave-length (Kayser) Are Spectrum Intensity and Character REPORT—1904. YTTRIUM—continued. Spark Spectrum, Exner and Haschek Lohse Arc Spark 4752:970 41°595 33°637 32°565 28-710 26°031 04:818 01°165 4699-424 96-976 92°137 89-938 82-501 78°523 75°030 71-020 67-024 66°567 59-058 58:497 53951 52°309 43°863 27390 13°165 04:977 01:484 4596°771 90-972 85°505 82352 81-954 81-506 79-043 73°746 70°855 657120 64:576 59°558 55-491 54°651 44-500 42-222 34:298 27-983 27°430 22242 14-190 13°764 06°139 03°534 4492-592 91°924 87°683 87-433 84621 NE NRPNWNRFONWNPWNNNANAWNWNHNKENRWHE WR 5 WW EWN OWWNAPRNNWNWRNNHN RI DH 4527-98 27°43 22°16 06:12 87°61 Reduction to Vacuum ——_- ee Oscillation Frequency in Vacuo ON WAVE-LENGTH TABLES OF TEE SPECTRA OF THE ELEMENTS. YTTRIUM— continued. 129 Reduction to Wave-length | Intensity | eek | Lohse Maeune | Oscillation (Kayser) an Exner and | Arc Spark | Frequency Are Spectrum Character Hiaschekee || Pe aad iL in Vacuo | | a 4479-184 2 1:23 | 6-2 22319°3 77°628 4 4577°59 Ea War 27:0 77°140 4 77:10 By 29°3 75°900 4 | 75°9 Py “c 35°7 74-074 3 | 99 99 44:8 72:953 2 Ferrie lane 50-4 65-463 2 65°50 1:22 ” 87:9 46-805 4 Sed Ps 22481°8 45°491 3 | ” ” 88°7 43-834 4 43°83 ” ” 96°9 37°519 3 ” 33 | 22528°9 36°321 2 36°37 ”» ” | 35:0 33°145 1 Fae yore el 51-1 27-191 1 1:21 | 63 81:3 22-772 6 | 22°80 as » | 22604:0 18°360 1 FP ro 26°5 17°635 2 samualh oe 30°3 15552 2 2 | rae i 40°9 02°574 1 | (tal |) S2eOteT 4398-201 5 | 4398-21 heise ~ 30°2 97-904 2 | Weis 2 31:8 94-840 3 | ”» ” 47°7 94:184 2 We ee “5 51:0 93°788 1 | 1:20 _ 53-1 87-908 3 87°84 Wes FP 83°6 85-649 2 ” ” 95°3 79°499 4 ér -p 22827°4 75°794 3 99 a 46:7 75°113 8 7511 s As 50°2 71621 1 PP “0 68°5 71:144 2 ga IE tay 71-0 66-204 3 66°30 » | G4 96°8 58-895 5 58°91 » | 22935:2 57°876 + Ht ate amed i are 40°6 53°833 1 (RP ESae =<: 61:9 52-499 2 ie ee “ 68-9 48°957 a 48°91 ss mi 87°6 46°323 2 ” ” 23001°6 44:812 3 “f, “D 09°6 37°476 2 ares a 48°5 30°945 3 30°85 I ae = 83°3 24°765 1 ” » 23116-2 22°474 2 22°4. Be fr 28°5 18-182 1 1:18 oo 51:5 18-052 1 eee = 52:2 16-472 2 » aa 60-7 15°662 3 fs) At 65:0 14-080 2 ” ” 73°5 09-784 6 09°81 or ra 96-6 07:234 2 “c 6°5 23210°2 05°499 1 ” ” 19°6 02°431 5 02°45 a x9 36:2 00-526 3 on * 46°5 4291:217 3 117 =A 96°9 * Rowland: 4358-879. 1904. K 130 REPORT—1904. YTTRIUM—continued. | Reduction to Wave-length Intensity Bass Lohse ee Oscillation (Kayser) and Renaviand. Are Spark [ Frequency Arc Spectrum | Character Waschek ee | oe in Vacuo Xr } 4275°650 1 1°17 (6:5 23381°7 74:346 2 x as 88-9 72°295 2 “4 a 234001 69-001 1 5 a4 18:2 67-085 3 ie 09 28°6 51:343 5 4251°39 | 99 6°6 23515°3 50°532 1 TeLGs ees 19:9 41:924 i! oy das 67°6 35°852 3 35°94 oh aS 23601°4 32-709 2 oF 35 18-9 31:461 1 on Fp 25:9 29°351 1 ap 55 37°7 24°396 33 ” ” 65°4 20°779 4 20°81 ” ” 85:7 17:960 3 “5 5 23701°5 13°698 3 a Pe 25°5 13:174 2 ” ” 27:9 09:872 1 55 aA 471 04°847 4 04°84. ” ” 75°5 4199°442 3 4199-46 115 | 6:7 23806-°0 77°684 5 77°65 af, 33 23930°0 74:287 4 74°31 B 3 49°6 * 67:670 3 67°81 114 A 87°6 57°786 2 ae 3 24044°7 43°017 6r 43°03 AA 6:8 24130°2 28°472 6r 28°49 5 Bs 24215:2 25:079 4 25°10 1:13 ss 35:2 10°964 3 ao aD 24320°3 06°552 2 ” » 44°5 * 02°548 Tr 02°60 as = 68:3 4095'617 1 69 24409°4 * 83°862 5 83°89 Pr * 79°7 §1°391 3 1:12 a 94:0 81-089 2 ” ” 96°4 * 77-522 6r 77°54 a 4 245178 65°159 ul 65:20 oe a5 92°4 48-004 2 47°98 ~ 7:0 24696°5 * 47°774 4 47°81 IEA Wi 97°9 44-407 2 AS 5 24718°4 44-235 i} ape | Cees 19:1 * 39:°981 4 4040-0 es Ss 456 30°011 3 a5 es 248068 3987°652 3 3987°4 “1 yes 25070°3 * 82-746 6 82°75 1:10 ” 251012 78°775 1 78°74 4 BS 26°3 73°597 2 BS . 59:0 67°847 1 1:09 ss 95°5 55°237 3 » 7:2 25275°7 §4°431 1 BS os 80°9 * 61-739 3 51°76 5 ‘ 98-1 50-499 5 50°51 ” ” 25306°1 46°350 2 + rs 32°6 30°799 4 30°84 cr) ”? 25432°9 * Rowland: 4167°737, 4102:541, 4083-783, 4077-498, 4047-823, 4040-013, 3982-742, 3951°765, 3950-497. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. YrrriumM—continued. 131 Reduction to W. : Spark Vacuum aaa ave-length Intensity Spectrum. Lohse Oscillation (Kayser) and Exner and Arc Spark | Frequency Arc Spectrum | Character | Haschek euler in Vacuo A 3904-738 3 3904-72 108 7:3 25602°6 00°425 2 5 m4 31:0 3892°570 2 Pr | ode 82:7 90-281 1 1:07 of 97:3 87:928 3 nf 25713°3 78418 2 3878°47 on sf | | 76°4 §2°541 1 le 5” | £25949'6 46°805 1 1:06 | » | 88°3 40°575 2 o ne 26030°5 33°006 2 33°00 op a 81:9 26-064 2 26-00 sat II iss 26129:2 18°513 3 18°49 ” ” 80°9 *3788°839 5 3788°88 nr 74 26384:9 * '74:494 5 74°51 1:05 fr 26486:2 70°740 1 1:04 | 7:5 26512°5 47°695 3 47:70 ” | ” 26675°5 38-772 2 20 ch 26739°2 35°756 1 1:03 Se | 60°8 34:422 1 ” ” 70°4 24-920 3 Pena eras, 26838°7 18-237 3 7 aS 86:8 * 10°448 6r 10°41 a es 26941°3 3697:923 2 3697°88 ” ” 27034°6 96°721 2 Part ae 43°4 93°989 1 on rE 63:4 92°667 4 as As 73°1 82-985 1 82°85 7 77 27144:2 82-748 1 os as 459 68°640 | 3 68°67 as 5 27250°3 » 64°744 8 64°76 “ aS 719°3 61-086 2 xr ss 27306°5 56°390 2 56°30 Pf 58 416 54°796 2 54°77 ” ” 54°6 53°636 2 oo Ap 62:3 §2°801 1 7 en 68:5 46°363 2 46°35Sa 9 ” 274169 45°567 3 45:54 Pi PF 22°9 39°422 3 oe 55 69:2 35-471 2 “ 78 98°9 * 33°267 4 33°28 | Pr 7 275156 * 28-852 7 28°89 a 33 49-1 * 21-099 5 21°12 ss a 27603°2 * 11:194 6 11:19 Bs a 83:9 * (02-069 6 02°12 “r a 277540 * (0°884 7 00-90 = tt 63:1 *3593°071 5 3593-11 rr 79 278224. * 84:656 2 84°71 re 5 88°9 76209 3 os ap 27954°7 71°587 2 of Pn 90:8 52°843 4 yr be 28138°6 * 49°153 7 49°21 : 8:0 68°7 13-036 3 “5 er 28457°4 11°354 3 o: all 71:0 3499:044 3n 3 jee | -28burk * Rowland : 3788°839, 3774°473. K2 132 Wave-length Arc Spectrum REPORT—1904. YTTRIUM— continued. (Kayser) Intensity and Character *3496:233 * * * * * 85-885 84-208 68-028 61:168 54322 51-082 48-962 33°159 12-620 09:914 3397°169 90°021 88-725 83-206 82975 80-054 77:863 64923 62°381 62131 59-082 54:979 54°749 44-680 40:528 37°986 35'349 31°335 31-029 28:013 19:922 18-700 08°525 3293:599 90-713 82-594 80-055 78°576 52-408 42-408 16°812 06-652 03-450 00°386 3195-741 91-627 91-438 79-539 73179 55°785 35285 30:059 14:415 NNWwnoroa UES SCARS By OPS Ge SS See 5 DOWWE ROPE YOK OUNWN We ee eR Re eR ON ee eb Spark Spectrum. Exner and Haschek Lohse Are Spark } 3496:25 68:05 61:15 54:23 48:98 3362°20 28°11 3282°7 42°49 16°87 03°51 00°44 3195-80 73°40 35°30 14°6 | Reduction to Vacuum Penial bet A 1:03 | 81 3? ” 9 ” 33 8-2 ” > ” ” ” ” ” ” ” ” ” 8:3 ” 99 > ” 35 8-4 ”? ” ” ” ”> ” > ”? ” ” 0:94 7 ” ” ” ” 55 8°5 ” 99 > ” ” ” ” ”> ” ” 0:93 AY ”? > ” > ” ” - 86 ” ” 9° 9 0°92 ae 2” ” ” | 8:7 ” | 33 93 ” - 8:8 0:91 33 0:90 3 3 8:9 > 3 > ”> 23 2? 33 > 39 3° 0:89 | 9:0 » ” ”> ” ae 9:1 0:88 > 3° Oscillation Frequency in Vacuo 28594°1 31936°8 32099°6 * Rowland: 3328-016, 3242-395, 3216°807, 3203-435, 3200°407, 3195-705. ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. Wave-length (Kayser ) Arc Spectrum 3112151 11:924 09-007 04:808 03°846 3096°741 95998 91-850 86°981 76°634 72°479 59-639 50°015 47-252 45°489 44-956 38:599 36°710 22-404 21:844 10:255 2997-069 95°383 84:376 74°710 74042 65-096 55999 48:°533 30°128 19-167 2890°497 86585 84583 56°419 54544 26°450 22°694 18-982 13-773 00°319 2791319 85-293 60°174 30°190 23°096 26727190 2547°661 40°384 Intensity an Character HRD DO DD DD oD See a at Dt Dt Dt 9 DR 0 DD 09 et 9 00 tt 00 0D et De YTTRIUM—continued. 133 Reduction to | boris Lohse eee es Oscillation Exner and | Are Spark ete Frequency Haschek phat a | in Vacuo 3112-2 0°38 | 92 | 321229 ” ” | 25°3 ” ” / 55°4 ” ” | 98:1 | 99 | 322089 | ” ” | 82°8 3096-04 | 0871 w» | 90°6 | ” | ” 32333'9 | ” ” 84°9 | ” 9°3 32493°7 | ” ” 32537°7 036 | , 32674'3 | a le! 32777 3 | tte at leaenro ” ) ” | 26°0 | ” ” | 31°8 ” ” | 32900°4 ” ” | 16:0 » | 95 | 33076°7 0°85 | ” | 82°9 ” ” | 33210°3 ” 96 | 33359°4 ” ” | 75°1 ” ” 98°4 % ” | 33507°1 O84| ., 336146 ” 9-7 33715°9 ” 9 33819°8 ” ” | 23905°5 » | 98 | 341184 033 | 99 | 34499-1 ” ” 345862 | 0-82 | 10:0 | 34633-0 39 ” 57°1 » | 101) 349988 0°81 ” | 35021°8 ” 10°2 35369°9 ” ” 35417°0 ” | * 35529°2 00°30 » | 104 357098 ” ” | 358150 2785°32 ic lace 92-5 » | 105 36219°0 0:79 | 106 =. 36616°8 0-78 | 10°7 36712°3 ! % 10°9 37411°6 0°77 | 11:5 39240-2 | O74 | 5 39352°6 ” 11:8 40363°6 0-73 | 11:9 40575'4 2460°73 O72) 4, | 40627-7 si ee 408763 ” | ”» 82:7 peese t alate 41237°8 22°32 » ” 713 134 REPORT—1904. YTTRIUM —continued. Reduction to Wave-length Intensity Spark Lohse — | Oscillation Fl Spectrum. Ss —|F (Kayser) se Exner and Arc Spark 1 ha apd Are Spectrum | Character Haccher ee > in Vacuo 2417-364 1 | 0-72! 122 413552 2385-298 2 O-71 | 12:4 41911°1 61°883 1 | | 9 126 = 42326°5 pags | aan st: 54°266 2 5; 33 83:5 32°651 2 | 55 12°8 Pree 31°732 1 | ins — 73° 2289-087 2 i aes 13:1 43672°4 83°722 2 0-69 | 13:2 pees 83:370 1 | os 3 1: | 77°738 1 | ae ie 43890:0 74171 2 | | 0-68 | 133. 43958°7 72°884 1 | oe or 83:7 71°853 1 o » | 44003°6 67°152 1 is A ol 949 65°110 2 eA » |, Sado“ 7 64:452 2 33 a 47°5 62°768 1 - ar 80:3 60°661 1 33 134 | 44221-4 60°157 2 3 at | 31:3 59°594 2 “1 Aes | 42°3 59°339 1 Lo oa Ae 57°3 49°240 1 Was 135 444459 45°720 1 1 odes Pe, ee 43-097 3 = ” 67° 42°643 1 FS uss - 76:8 40:695 1 ass s 44615°6 36°384 u | dibs 13-6 | 44701°4 31-276 1 » | 9 | 44803°7 28-241 1 = a 64:8 27°849 | 1 | 0°67 99 72:7 Line Spectrum or SuLpuur. Eder and Valenta, ‘ Denkschr. kais. Akad. Wissensch. Wien,’ lxvii. 1898. | Wave-length 5819°543 Intensity an Character i Intensity | | Intensity Wave-length and Wave-length and ‘Character | Character 5559°129 1 5665123 | 4 567141 4n 62°741 In 36:968 3 60-289 6 26°458 5n 48°565 1 20°749 1 jme 47:296 he Mats} 18°968 3n 45920 | 2n 09-799 | 10 40°535 | 4 5478°589 2n 40°257 J 8 77649 1 16°844 4 75:209 2 06°349 | 8 73°791 8 5579°327 6 68°565 1 65007 | 8 | 54-000 10 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 135 Linu SPECTRUM OF SULPHUR—continued. ae aa Intensity | Intensity | | Intensity Wave-length | and Wave-length and | Wave-length ani Character \Character, \Character | | 5434°737 2 4661°782 | lb? | 4285°133 8 32994 10 56°916 3 83°825 2 28°907 51:043 1 83318 1 50-440 1 82-741 3 49-328 3 78670 3 01-035 sn | 48-416 1 | 69°942 4 5345°832 8 i 47-614 In | 67:959 4 20°894 8 42-024 2 | 67°255 6r 39°024 1 59-408 2 5233°187 1 24-322 In 57°603 3 30°040 1 13°618 1 53°772 10r 27-406 1 4596-368 1 50°150 1 27-072 1 91-285 1 36230 1 20°872 1 91°164 2 31182 4 19-650 3 27°590 2 12°803 8 62°118 2 21°810 2 07:482 2 527592 } 5 17397 4 01-520 2 49°723 3 4193-667 2 01°149 } 6 25°159 6 89°896 5b* 24°817 2 86°120 } 1 04:370 3 85631 2 5160-348 2 4499-450 1 78992 2 42°512 3 | 36806 | 2 75°415 3 | 85907 2 | _ 74471 7b’ | 83-647 4 74179 4 81°661 1 68-554 4 03°535 4 78°633 A: 65°255 1 5098-890 1 | 65°329 1 657127 3bv 51°874 1 | 64-618 5 62°856 10 47-499 3 \ 63°761 5b’ 62-539 2 39°596 2 i 56°584 2 53269 .| 10b” 32°657 8 | 40:043 4 49-068 2 27:408 4 32°561 } 3 47:126 3 14:248 8 31°131 lb’ | 45:266 10 11°815 3 18°982 2 44:027 1 09-762 6 17134 3 42-390 8b’ 07-010 1 15°052 4 33-041 1 4993°733 3 4393°862 3 27°724 2 927152 5 92012 2 19:377 3 42-649 2 67:037 2 \ 12-472 } 2 25-493 6 64:873 A a 12-319 2 } 5 24-269 5 627610 6 11-670 5 17°410 4n 61°671 5 05°151 1 02°656 2 60-625 1 4099-607 } 3 4885°831 3 54°739 5 99-360 2 24°353 2n 51-408 2 95-288 2 19°834 1 49-551 3 91°372 1 11-967 4 47°558 1 76024 t 92°333 2 45°637 1 72°252 3 40°444 4 70077 } 3 33°947 1 69°802 2 32°852 5 64634 3b 30°798 1 50°328 2 19-762 1 32956 4bv 4716-382 4 18°847 3 17:299 2 28-995 6 4677-804 2 | 4294-558 8b’ 11-469 1 68-738 a i> 91-606 1 09-566 1 136 REPORT—1904. LINE SPECTRUM OF SULPHUR—continued. Intensity Intensity) | Intensity Wave-length and Wave-length and Wave-length and Character Character Character 4007:995 2 3861°541 1 3618°937 1 06-700 1 60°833 3b 17:086 | 4b 04:045 1 53°280 3 3999-026 3 51:312 3br 00°307 2n 98-998 4b’ 47°319 2 3596°152 \edaacg 45336 1 94:575 3 98-127 3 42502 2b | 67°382 2n 93°706 5 39°368 2 60°857 In 91:144 4b* 38-440 10 | 56°506 rf In 37°882 8 49-920 2b 86°158 5 31°980 4 43°856 3b 83°924 6 3794°841 5 | 82°893 lb* 83°543 2b || 40°416 3 79-030 4 3499°566 ob 81:923 1 74:°713 2 | ) 80-002 4b‘ 60-030 2 97°438 iy 8 54°879 1 83°140 send 74316 1 50°927 3 79°435 8b 73°341 4 49-554 4 74:061 6 70°820 | 3b 48-039 5 71-014 In 70°640 3b 44-488 2 3390°354 3 63:279 3 27°457 3b 87:242 5 61°695 4 17864 8b 85986 2n 59°468 1 12°868 2b 77°300 1 59-189 | 2 10°604 2b 73°402 3n 54°457 i 2 09°470 6b 72°285 In 50°866 In 00323 2b 70°490 4 47°326 2n 3699-529 3b 69°624 3 45:059 1 98-046 1 68-210 2 39°897 In 96°373 3b 67°306 4 33°650 3b 89-639 1 63-294 In 32°437 2 80°671 1 56°567 In 32°104 3 78°329 4b 55°233 as a | 28°734 8 72°436 3 44:216 \c -2n 23°788 3b” 69-139 6b 41°612 lat 63°513 1 40°508 3 20:997 2 62°107 5 30°924 ed 19°550 3 56°715 3 25013 | 5b 18-312 1 55°435 1 24-160 4 127149 3 54°669 1 17:205 2 07:285 2 53°559 In 14-643 1 3899-501 2 38°267 2 08:953 3 94°159 1 37131 2 05°774 2 92°759 2b 36°305 1 01-806 1 82°366 ied 32°144 8 01-211 eee} 2d 76°353 a 2b 26°508 3 | | 64°773 1b 22°892 2 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 137 BAnp SPECTRUM OF SULPHUR. Eder and Valenta, ‘ Denkschr. kais. Akad, Wissensch. Wien,’ Ixvii. 1898. _ —ee aaa nl Intensity | Intensity | Intensity Wave-length and Wave-length and Wave-length | and Character Character, Character 6380 5582183 1 5556°189 2 20 81:192 1 55°654 Heres 6265 | 80°882 1 55-209 ie 6165 80-506 3 54°788 ie. 4: 00 807124 2 54:529 te oil 6036 79536 1 54:197 3 5967 79°012 3 53°775 \ 3b 00 78871 3 53°251 Mm 2 5838 77°750 3 52-820 3 5779 77:424 3 52514 1 12 76°891 2b 527195 1 5653 76°356 1 51°836 3 01°812 sn 75°687 3 51243 4 01-411 5 | 75244 3 50°849 4 00°894 3 74719 1 50°276 5 00-669 3 74:437 3 49-682 4b 5599-778 + 73972 1 99°477 4b 73586 3 49-067 4 98-916 4 72°356 i 2 48-694 1 98-568 + | 71-830 2 48-383 3 98-076 4 | 71:469 5 47:985 1 97-717 1 | 70°972 1 47°643 3 97°376 4 70°639 1 47°361 2 97°169 2 70°320 2 47-069 1 96°836 1 69-605 2 46-666 2 96°444 4b |) 69-112 4 46-409 2 95°898 4b || 68-632 1 46-051 3 95°505 1 68°337 3 45-638 4 94-960 5b 68-030 3 45-178 4 67-603 3 44°653 5 94-310 5b 67:235 2 44-220 4 93-864 5s 66-883 1 43-594 6 93:058 2b | 66-622 2 43°177 2 92-649 1 66°369 2 42°747 5b 92-069 1 | 65-911 2 42-214 4 91-683 + | 65-280 3 41-900 1 91-425 1 i 64-860 2 41:491 4 90-694 3 | 64-611 2 41-002 2 90:292 3b 63°976 5 40°712 5 89-798 4 63°132 1 40°235 3 88-813 2 62°717 1b 39-663 1 88-469 2 62-395 2 39°159 3 88-075 3b 61-886 3 38621 | 6G 87-408 1 61:441 4 38°189 3b 86:991 2 60°922 3b 37°836 it 3b 86°526 2b 60-407 2 37°309 5 86168 2 59°787 3 36°926 4 85°775 3 59°155 5 36°595 4 85-229 3 58-794 3 36°303 4 84-699 2 58-251 1b 35°781 6 84°331 2 35°347 4 83-900 5b 57°809 3 | 34:943 3 57296 3 34°526 6 82-913 ae 56843 5 34-132 33 82-603 eb 3 it 56-512 1 33°744 63 138 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. | Intensity Intensity | Intensity Wave-length and Wave-length and Wave-length and Character|/ Character Character 5533196 5b 5505-771 } 2s 5478692 | 6 05:278 | =< 8br 78-228 re | 04:986 j 1 77°606 8 32'691 3b || 04-681 1 77023 3b 04-295 1 76597 | 3 32:169 6 03°893 6 76:270 3 31-422 8 | 03-449 3b 75-770 4 30°767 3 | 02-589 5 75°346 5 30:214 2 | 02:213 |. 4 74-950 3 29-901 2 01-350 1 74351 } 4b 29°621 4 | 00°574 4 73°858 3s 28-912 2b 00°398 2 73°374 3 28-521 2 5499-733 oo 73049] | 2 28126 4 99°150 Q |i 72949 4 27-657 4 | 98-816 an! 72782 2 27-240 “gaa | 98-475 an | 72500 1 26-765 1 | 98-104 QZ | 72243 3 26°379 3b || 97-395 2 || 71:390 } 3 25-869 3b | 97-014 4 | 70-780 1 25°438 1 / 96-703 } on a 70-278 2 25°154. | 96-372 } ill 69-931 \ 4 24-680 In 95-401 ae 69:469 3 24-420 2n 94°777 4 69-120 1 23°540 3 | 94381 4 68°831 3 22-249 1 | 93-982 3 68-299 3 | 93:505 1 67:886 1 21-963 4 93-312 i 2 67°624 2 21-232 8 92803 8 67-053 1 20°521 2 92°105 3 66:556 1 207150 4 91-605 i 66183 3 19-515 1 91-418 | | 65-896 3 19°145 2 91103 | 65°658 2 18-761 2b 90-711 | af 65-385 1 18-529 1 90-118 a i 65-086 2 18-233 ee 89-532 ae 64-680 4 17-942 3 | 89092 =| 2 ~ #i| 64-028 2 17-556 4 88-679 4 | 63:769 1 17-038 4 88-274 | 63-400 1 16°355 5 87-967 38 | 62-975 1 15°746 1 87:510 9 | 62°751 1 15°421 1 86-790 10 62-434 2 15°155 1 86-238 1 62:160 | 3 14-240 4 85°814 4 61:820 1 13-898 } 3 85°354 2 61-473 1 13-048 4 85-075 4b 61:160 3 12°853 } 1 84-525 i) 60°815 2 12-432 3 83°741 1 60-560 3 11-963 1b 83-492 || 60:168 1 11°309 2b 83-248 2 59°531 1 10:460 3 82°813 4 59°191 2 10°160 \ 1 82395 2 58-507 4 09-594 2 81-955 3 57°79 2 09-209 3 81:398 6 57-010 3 08-806 5 80-910 2 | 56-783 07-637 2b 80-607 2 55°311 07°115 2 80:198 2 | 55-010 3b 06-599 4 | 79916 5 54-648 3 06-256 J ae 79341 6. #l 54-098 2 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. BAND SPECTRUM OF SULPHUR—continued. Wave-length 6453°462 52046 51:647 51-202 50°511 50°190 48329 47:880 47-459 47:007 46°355 45°842 45-044 44683 44-152 43°867 43°153 41-892 41:504 41°189 40-760 40°536 40°285 39°155 38-472 | 38°246 37875 37°565 36870 36°440 35°932 35°367 34426 33922 33°600 32°962 32°527 31°932 31219 30:507 30°198 29'566 29-260 28-940 28-656 28'349 28-068 27-685 27-272 26:838 } 26°655 26°197 25-712 25°390 24-908 } 24-514 $ Intensity | and || Character’ —_— NOWNON EK WE OK KE RPWRRE DOO OWONORN EWE og o iow ie IRS Ie ao aaa CS GaSe MES es NS Oo IRIS Pm rie ce he he hee ee inn be] | 139 Intensity | Intensity Wave-length and Wave-length and Character: | Character} 5424:171 J 3 5395°646 1 23°724 3 95°327 4 23°438 | 1 93:578 | 2 23°143 5 93°487 1 22°743 | 2 92°435 \ 2 22°112 3 92°082 3 21°787 1 90°967 | 1 21°467 4 | 21-078 4 | 90°716 } 2 20°793 3 | 90:214 1 20°385 2 | 89°552 3 19-994 t | 89-049 4 19-479 4 | 88-517 2 19-100 3 | 88-182 3 18-609 6 | 87504 2 17°827 a wl 87:105 1 17:359 5b 86-763 + 16°580 ) 4 | 86188 5 16°232 4 85°861 3 157149 3 85'014 In 15°416 \ 2 84:516 1 14:325 4 84°183 4 13-909 } 1 83:578 } 3 13°742 1 83:100 2 13°402 4 82°175 3 12-959 1 81-759 3 12-709 1 81-466 3 12°427 2 81:28] 3 12-061 3 80°918 1 11:737 2 | 80°318 3b 11-360 1 | 79°346 it 7 11-061 3 78:959/ | 5 10°447 5 78061 3 09-790 4 77316 \ 6 09-402 1 | 76°897 | 5 09-098 2 ! 76:462 1 08-680 2 76173 3 08°315 3 75°486 3 07:998 1 | 75158 \ 2 07691 5 | 74°695 | 2 07:047 3 74°346 3 06:547 \ 1 73°680 3 06°301 2 73°195 5 05013 3 72-690 5 04:141 2 72°046 2 02°954 3 71:433 3 02°590 1 71:147 3 01:957 2 70°810 2 01°593 1 70°473 3 01:185 3 69°944 1 00°805 1b 69°673 2s 5399-684 2 69-384 1 99-350 1 68-989 4 98-996 3 68-441 1 98-285 3 68°314 | 2 96°479 2 67:978 3 96:226 \ 2 67°588 3b 95°841 1 | 66-993 t 140 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Wave-length Intensity and \Character; Wave-length pa an | Character 5366-482 65°380 65°355 65-093 J 64-697 64-237 63°814 63-297 62-896 ) 62:520 62-140 | 61:678 61°531 } 61-158 60°892 60°627 60°279 59-806 58845 58-263 57°740 57°367 56-973 56-203 55-540 54-883 54-019 53-062 52*152 51-273 50°816 50-405 49-898 49-390 48-912 48-361 46-911 46-163 45194 44:041 43007 42°359 41-953 40-898 40°121 38°777 38°257 37890 37°476 37:285 36°556 36°127 35°510 34833 34234 33°939 33°592 ROD OR OP WR WON NOH WOON WORe Ba 5 ae tee ey ne es we OS ela Py oe Fmt | 5333-106 32817 32°525 32°153 31522 30°789 30:295 29°516 27-921 27-671 27°369 26-731 26°301 25°715 25-223 24-873 23°851 23°587 23-241 22-867 22-971 21858 21:536 | 21-240 | 20°651 | 20203 19'835 ) 19:585 19°31] 18-654 17:883 17-361 ) 17119 16:87 16-586 16-202 15°720 15°338 | 14-998 14-48] 14:125 13-614 | 13-272 | 12:879 12'506 11°760 10-621 09°823 09°410 09-071 08-191 07:°847 07:525 07:121 06°783 06231 05°874 i] im OWwWONAONN ERNE NDE ARON EWE WWWHENNNNEN ROE NEED RN Ewe bo eee oa CU GS 5 DWE we WN wo Wave-length Intensity and Character 5305°501 05°113 04-404 03-962 03-444 03-274 01-986 01381 00-924 } 00°476 5299-973 99:601 99-071 ) 98-795 | 98-154 | 97-997 J 97°312 96-983 96-015 | 95:584 | 94-551 94-031 93-300 92-240 90°799 90°330 89848 | 89-006 88-259 87°585 86-932 86-482 85°746 84-913 84450 83-016 82:630 82-289 81579 80-228 79:898 79-433 78-548 | 78-247 J 77876 77°440 77-101 76°733 76-378 75-901 75-528 74-276 73-990 73-592 73323 72-999 72689 72:335 =] CORDNNNDNE WWE Ne Re ewe ot a o NWWNWN ERK DNDN WH wh ht wwe Co BE Cael RO oe a) ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS, Wawve-length 5271-872 71-316 70°558 69:378 69-089 68:833 68-508 \ 67:847 67:401 67-254 67-024 66°540 66:155 65°512 65109 64:917 64:044 63°500 63°017 62°484 61:990 61451 \ 61:247 60:608 60269 59°841 59°552 59-192 58-607 58°340 \ 57:986 57°405 56°803 56-043 55°739 55269 54-974 54-534 54°153 53°756 53303 §2°981 52:700 §2°158 51:677 51:359 51118 | 50°512 49-820 49-315 48:958 | 48-090 47°126 46°801 } 46°336 45°587 45°015 BAND SPECTRUM OF SULPHUR—continued. an CO me ee LD DR RK whe =} =b— 5n —Ddo— 5 RS eS Ge Ree 5 bp 02 2 Go 39 9 RO LO Go HR BO Go =] bo oo bo bo to bh (Character Intensity] d | 141 Wave-length 5244:577 43-906 43°212 42-702 42282 42°027 41°737 40:856 40-069 39-682 39°320 38°477 38:114 37:089 36°527 36-079 35-472 34131 32°817 32'182 31:328 30°792 30°329 29-835 29°109 28-457 27-943 26-798 26155 25-734 25-258 24-676 | 24-454 J 23-947 | 23-671 J 23-307 29-983 J 29-245 21-546 | 21-274 | 20°690 20:229 19-882 19:544 19-201 18-668 18-037 17-704 17-019 15:935 15°409 14-796 14-451 13°835 13158 12870] 12-594 Intensity]| and || bo Go oD =] 6 Sees tae as dy ge aah oem i=} =) BB oo low DOM We RWW Re ORR ENR REN WE NNR RP REP NRE NRE REP NR RE NEN eR be 5212-052 Wave-length 11593 10-931 | 10°617 | 10:017 09-045 | 08-782 J 08-306 07-417 06-906 06-409 05-737 05-227 04:779 04-296 - 03°710 03-341 02:904 02:465 01872 01-652 01:156 00:756 00°333 5199-956 99:582 99:309 | 99-000 98-475 97:817 97:°675 \ 96-769 96:588 95-966 } — 95-728 94-782 94:048 93-436 92°734 92288 91-956 90°521 90°117 88:573 88:100 87:335 86-880 86-612 \ 86-033 85:016 84-426 83-775 83:063 82-670 82-165 81:562 81:169 Intensity] and Character) WNWNRK PNK Ore ag BOISE 2S HERS 2 Kee ROS i] 5 ee De eH ee tn 142 REPORT—1904. BAND SPECTRUM OF SULPHUR—continuced. Intensity Intensity Wave-length an Wave-length and Wave-length Character Character 5180:855 2n 5146:732 3b 78-761 2 46-257 2 5102-903 78-043 3b 45-783 4b 02-608 \ 716861 1 45:031 2 02-140 76'401 2n 44-482 3 01-965 | 76°361 In 44-000 2 00°853 75°881 In 43°458 2 | 00-494 75:229 Qn 43:131 1 | 5099-627 713-653 Qn 42574 In 98-972 73171 Qn 98-392 72-692 1 41°671 eI 97:634 72-307 1 40-923 In | 96-911 71-175 2 40:448 Qn |] 96°457 70°660 1 39-074 a 95-983 70°353 2 38-400 2 95-055 69°665 1 37°643 In 94-684. 68592 2 37-001 1 94-225 68-122 2 36624 1 93-912 | 66:239 In 36-113 1 93-098 35:663 | 2n 92-697 66:142 2n 35-398 2n 92-195 65°330 Qn 33-270 1 91-949 63-880 3 32-852 1 91:541 63-389 3 29-743 1 90-979 63-008 2 28816 2 90-162 61:691 4b 28-220 1 89-388 61-214 2 27-561 1 89-196 \ 60°816 2 26:914 In 88-322 59-844 5 25-783 In | 87-529 59:557 1 i 86-884 59-148 | In 23-942 ekin. | 86-270 58-916 | In 23-188 | In 84:475 58-194 \ Qn 22-682 iP eeIn 84-024 57-921 2n 21-987 een | 82-964 57509 1 20-490 i a 57°134 3 19500 Iti 82°415 56:689 2 18°144 [ee ae 81-412 56-275 1 17:233 bas 80-781 55826 2 15°673 oc ae 80°325 55°332 | 4 14-984 Qb 79-334 54-873 | Qb 13-655 fin 78-503 54379 3 12976 | In 78-022 53-960 3 12558 \ ain | 77-659 53-559 1 12-262 e¢in -| 75-217 53-102 2 ie ha | 74-912 52-655 3b 11-279 iene 74-576 52-281 2 10-943 | 1 74-086 51-929 3 10-152 1 73-586 51-615 1 09:767 es 72-729 51:344 1 09-186 | 2 71-923 50987 4 08-392 In 71-629 50:583 2 07:832 Qn || 71-349 50-287 1 07:195 Bt} 70-893 49-935 2 06-224 2n 70-563 49-583 3 05:412 2 70°181 48917 3b 04-594 2 | 69-757 48:163 4 04-239 3 69-355 47-535 4 03-731 ip» | Intensity NPD PDD N Wo mR WDD DWN i=] 5 a bo oo bo 5 ow a DR RR NRE RE NWNR REN DN ww — DD — =] 5 an \Character ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. BAND SPECTRUM OF SULPHUR—continued. 4999°574 \ Intensity Intensity Wave-length and Wave-length and Character Character 5039:277 2 5068-966 1 38°818 3n 68-568 3 68:099 2 38°368 1 67°529 2 37°866 3 66886 \ 2n 37:004 4 66°643 | 2 36°532 2 65°833 3 35°866 2b 65°323 2 35°366 2 64:973 1 35:030 In 64°546 \ 2 34°631 4n 64:219 1 33°881 2 63°825 2 33°261 2n 63°247 1 32°737 lb 62:779 1 | 62°315 2b 31:510 lb | 61°770 2 30°301 2b 61:189 3 28°121 1 60°756 1b 27°485 1 26°447 1 59°871 4 25°645 1 59103 3 25-008 Ll - 58°636 1 24-700 \ 2 587134 3 24°377 | 1 | 57°626 1 22-684 1 | 56-981 4 22°043 3b SO} 56°493 | 1 21°495 1 56:071 f * ey 21-003 1 55°711 fe: 20°525 2 55:444 2 19-483 2b 55086 2 18-593 lb 54°862 1 17°820 1 §4°463 1b 17:096 \ In | 53°057 ree 16°772 on. | 53°290 8 15°790 lb 52°545 3 15-215 2b §2°119 1 14:173 3n 51°440 5 13°449 In 51:044 5 12-821 2 50°370 2 11°703 4 49°590 3 11-099 3 1 10°436 2 48-953 2 09:°677 2 48°544 1 09°322 1 48°137 2 08-988 2s 47°790 4 08-224 2n 46°730 2 07:057 3b 46°266 4s 45-418 2 05°971 2b 44°712 5 05-304 3 43930 3b 03°968 | 2 43297 4 03°713 2 42°770 2n 03178 2 42°438 1 02-765 In 41-976 3 02:020 4 41-438 3 01°375 3 40°887 4 00°578 3 39-694! 3 00013 2 Wave-length 99-206 98-868 98-556 97-989 97:306 96°658 96177 95-634 95°141 94-718 94-197 93:75 93-208 92-712 92-336 91-909 91-642 91-491 | 91-059 90628 90-258 89-995 | 89:543 89:182 88-494 87:317 87:°371 85°737 85304 84-526 83:842 83-385 82°675 82-162 80:833 80°387 79:706 78-830 78-083 77286 76617 75-282 74-566 73-674 72-641 71-915 70-935 70°103 69°433 68-786 68-638 67°576 67:046 66-176 65°747 65°549 i 143 Intensity and Character | Orr bo oa wb oo 5 Ee aR eG NSD IE Oe a Se Se i=} er Oh i) ee eel oh al all) 144 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Wave-length Intensity | |. and || Character;| 4964-764 63°511 62962 62°341 61:002 60°404 59-968 58-993 58°458 58264 56-692 56°193 55-625 54:670 54-056 53°728 53°300 53°156 52°248 51°889 51-020 50°455 49-362 48-850 48458 47°790 47-408 46-968 46°464 46-006 45-609 45°195 44-803 44°179 43-903 43-555 43-169 42-909 42-439 41-989 41-552 41-174 40°737 40-403 39°87] | 39°317 39-010 38531 38:245 37°471 36°995 36:588 35-966 35:219 34-592 27-070 26-222 1 Qe ee ee ee > 5 Led BO ee Oe na Eee Coed tre oe are ey Ee me o ST ONS ISH ON aN NS ee ha ow romog Intensity} Intensity Wave-length and || Wave-length an \Character)| Character 4925-558 In || 4992772 | 3b 25-008 In 2 sl | Sia alee 23-244 1b ene = H 89406 In 23:036 J 2b ‘ 88-933 In 22-499 1 88-663 1 22-038 1 87-852 Qn 87°429 2n 85144 2n 17827 2b | 17213 | 1b | eo oe 16°603 | i | 84:205 2n 16-260 howy | 83°751 In 15-980 1 } 82°399 In 15-304. 1 81:910 In 14°505 = 81-214 3n see : | 80-245 2n 13-214 1 79°754 In 12-617 in 78913 2n 12°133 3 11:260 } 2 10:984 2 09-882 1 Qn el =a 09-715 | 2 iba 8n 09-299 1 74:927 1 i 74°455 In 08°818 3 07°653 3 73164 In : 72°732 In 06°995 1 ‘ 06-210 On Uae 05°55 71°172 3b ee \ a 70°583 2b 04793 J In 707141 lb 04:337 | 3n 69°559 lb 03-452 3 68°447 4b 03°045 2 67°300 2 02-606 In eed 3 ‘i 64:823 2b 02:198 1 \ 01:108 63°839 2b 2 E 00-249 1b 63°366 4 62°881 2b 4899:780 3 99-456 1 62°390 2 99-077 2 62°034 1 98394 4 61:169 4 97°921 2 60°656 3 96:968 3b 60°178 3 59-465 1 96°315 3 58-956 3 95-654 3 58:476 4 95-290 1 58°107 1 94°593 3b 57°626 1 56°827 5 93-603 In 56°490 2 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 145 BAND SPECTRUM OF SULPHUR—continued. Intensity. Intensity | Intensity| Wave-length and | Wave-length and Wave-length and ‘Character Character ‘Character 4855'803 2b | 4770730) | 1 || 4740189) | 3 55273 «=| «C8 70°540 | In | ssc} In 54898 | 1 | 70-009 1 | 48-416 2 54539 | 1 69-508 } 2 48:101 P Sn 54-190 Qn | 69-259 2 47-786 1 53°726 peng 68:566 a 47:533 2 53-255 2b | 68-273 | 46847) | 1 os) | 67-939 5 46:263 \ ae 67°635 1 46085 | 2 52-281 J Tests | 67°342 2 45°611 1b 51702 1 66°542 2 45252 2 51:342 33} 66:220 | 44-392 2 51-029 33} 65°504 Re | 43-967 1 50:180 2 65:221 Pe) 43°74] 1 49°707 3 64°762 1 43-465 1b 49-249 sey El 64557 8 In | 42-973 3 48-701 \ ee 64195 | 3 | 42:572 1b 48-230 | | 63°756 ae 42153 2 47-519 ret) 63476) ob = || 41:552 1 47-088 } Cae gl 63:256 eI 41148 1 46-762 | 63°042 a | 41-083 2 46-124 Ul 62°749 iy | 40-680 1b 45709 | 2 62-265 2 40:396 1b 45346 | Ib 62-098 1 sas) 1 44-599 Se | 61:397 4 39°821 2 44-298 Thi; 60°916 In | 39°673 2 43-612 * | 60°437 3b || 39:384 1 42-364 é 38-992 2 41-697 hy | 38-030 2 40°666 2b 59°854 2 37-471 2n Aisi) Ub | 59°547 1 37-188 1 so562.- | 2 | 59343 i || 36-918 In 4784°744 1 | 59:020 th 36°659 2 an | 58:466 2 || 35°814 2 83665 | 1 | 57886 } 2 || 35568 1b S20s0u ake LS | 57°818 Re | 35-051 2b 82-779 J 4 | 34-327 1 81-948 \ + 57°054 2b | 33-926 4b 81:738 ere | | 33:314 1 80°787 In 56:367 es | 33-117 1 80:396 1 56064 ye ° 32-982 1 80-170 eon 55°757 4n | 32902 1 79°179 | mi 2n 32544 1 78-738 lis >| 54°784 2n 32-416 1 78-029 Os, 5 54-489 \ 2n 31-947 2 77°641 2 | 53°379 2 31:649 4b 77-128 In | 53-150 2 31117 1 76°656 eat 52°680 2n 30:893 1 75°656 | ee || 52-021 275) 30°662 \ 1 75468 cts | 51-740 J 2 30-182 1 75°154 e-4| 51-615 2 29-822 2n 74°794 1 51144 | In 29-604 1 74-164 2 50:868 2 29°424 1 73377 2 50-626 | 1 29-244 2n 72-910 3n 50°239 2 28-825 1 71:729 1 50-029 2 28-563 } 2 71285 2 49°722 } 1 27°856 1 0012 |) 1 f 49-471 2 733. |, 1 ) 1904. 146 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Intensity | Intensity Intensity Wave-length and | Wave-length and | Wave-length and ‘Character \Character Character 4727°520 J 1 4709236 © 8b || 4690619 3 27-067 2 90:350 In 26°691 J 2 08-972 ) 1; a 26-208 3b 08-813 a. My 89-793 1 08-162 1 89-602 3 25°570 2 07:935 2b 89-278 2 25°165 1 07514 | 4 88-687 4b 24°717 } 3n 07-088 Pe a 24°341 2 06-808 3 | 88-110 3 23°901 an 06:439 4b |) 87:920 3 23756 | 1 | | 87:°675 1 23378." = 93 | ; 87-423 1 22-893 2b ae : 87-220 2 22559 | 3 05-356 2b 87-081 | 2 99991 | 4 | 86814 2 1971 | 1 ; 86-574 3 21-695 1 pears | 86-209 1 21-482 2 04-173 2b I 85-834 2 21-194 2 | | 85-453 4 20°607 Sb ore | 85-243 2 20°172 eas 03°658 2 al 2 19-783 2 a 03-223 = 84°755 3 19-199 2 | 02896 1 84:503 2 18-644 3 02°585 1 84-384 2 18-178 4 02°407 1 83-969 4 17798 l 02-114 > 83-760 4 17:505 2 01775 4 83159 1 17°185 1 01-360 =| 82:87 2 16°737 1 00°835 ER 82:617 2b 16°540 1 00:579 ia | 82-378 2 16-283 3 00°397 In 82-058 3 16-084 \ 1 00-244 2 81-671 1 15°799 3 00:036 3 81-537 3s 4699-628 2 81-240 3b 15-318 2 99°303 | 1 80-406 3 14813 2 99°010 | (1 S018 1 14:579 3 98°489 3 } 80-076 3 | 14-392 24 98-250 || 79-761 3b | 14-235 ae 97°871 2b | ros] 4 14-098 Pe! 97°421 3b 79°135 4 13°860 9 97:079 1 13°556 9 96°911 2 13°365 1 96°773 2 78-509 2 13-109 2b 95°705 1 77957 t 12826 4b 95°387 | 1 77°762 2 12°356 \ 1 94°596 2b 77407 lb 12:034 2 94°331 3b 77:047 3 tae 3 76°157 2 10-941 2 93-100 2 75°816 4 10°578 2b 92-756 | 92-526 | a Ill 75-485 3 10-270 ro, oH 92:174 || 75044 6 10-030 ye 91:727 | 74-731 3 09-796 1 | 91-360 || 74-655 2 09:579 1 91-147 1 |i 74-432 | he ON WAVE-LENGTH TABLES OF THE SPECPRA OF THE ELEMENTS. 147 BAND SPECTRUM OF SULPHUR—continued. a a SE EE EE eee Intensity Intensity Intensity Wave-length an Wave-length and Wave-length an Character} Character, Character 4673°953 i 4661°876 1 4645°448 1b 3.784} 5b 61-799 4 45°110 1 73402 \ 1 61:593 1 44°734 2 73°296 4 | 61:446 1 44-509 1 73°065 2n 61:179 1 43°994 4 72°883 3n 60°863 8 43-568 3 72°824 3 60°443 4 43°247 3 72°424 3 | 60°265 1 42-297 3 72176 3 | 60°044 1 41-927 1 71:940 3 | 59°647 8 41-736 1 71:572 3 59°493 6 41-506 4 71:383 ] 59°270 4 41-255 2b 71:268 2 58°793 2 40-831 6 70:990 2 58°505 4b 40-460 4b 70°675 6 | 39°805 3 70°435 2. || 39°373 3b 70329 6 | 39°196 2 | 57:975 3 38-540 3 | 57°496 3 38331 2b | 57°188 8 707122 6 | 56°495 3b 37946 1 69:883 6 || 37°723 2 69°474 1 567140 6 37°363 1 69°475 5 55°691 2 36°802 3 69-042 3 55°348 \ 3 36°621 2 68-801 4 54131 3 36°375 2 68:483 4 54°863 | t 35°943 2 68-338 3b 54596 J 4 35°564 1 68-040 J 3b 54°233 5 35269 2b 67°892 4 } 53°948 | 1 34:865 1 67°681 1 | 53°841 J 1 34°762 \ 1 67:554 1 53°631 2b 34:527 4 67:369 3 34°328 } 4 67°147 Ib || 537112 1 33°715 5 66°932 3b 52°971 3 33°155 1 66°787 1b 52°565 4 32-991 1 66°646 3 52°323 8 32°711 3 66°333 6 527128 2 32°460 ) 3 65-970 2 | 51°848 3 32°279 1 | 51°331 2 32-139) 4 , 51-088 c 31584 3b 65°712 2 50°814 3 31:193 2 65°357 6 50°623 3 30-924 1 64988 4b 50°493 1 30°753 2 64°721 4b | 49:993 2 30°514 1 64381 4b 49°404 6 30°409, 3 64°184 1 | 48°817 1 30°214 2 64:036 3 48-629 1 30:053 2 63°803 2b 48°399 \ 3 29°652 1 48-082 1 29°342 3 47-980 1 28°887 1 63°622 4 47:660 2 28°659 1 63°435 1 47°385 1 28-483 2 63°163 5 47:047 } In 28°202 \ 3 62-796 Qs 46:02 In 28-014 2 62°431 } 2b 46°709 aa 27°486 1 62220 4 46°404 4 27°366 } 1 62-099 } 1 45°761 4 27:101 2 L2 148 REPORT—1904. - BAND SPECTRUM OF SULPHUR—continued. Wave-length 4626:917 26°704 26°465 26-079 25°639 25-419 25-239 24-983 24-571 | 24-321. 24-194 } 23834 23-613 23:399 23-084 22°853 22578 22-379 21/876 21-703 21-285 | 21-124 20-901 20°682 | 20542 20°418 19°70 19°541 19-368 19-211 18-997 18-850 18-705 18-384 18-233 17-953 17-720 17-482 17-161 16-908 16-761 16-208 } 16-081 15-784 15-466 15-188 14786} 14:574 14-212 13-925 : ! 13°737 \ 13-566 13-478 13204} 13-204 12968 J Character i BO BO C0 rs BD BO 09 G8 A RO C9 PA Fa at Cor HH at a HR BD et BO Pas BD 09 9 BO BD 09 BO C9 HA Pat sat G9 9 BO BO BO BO Co G9 BO BD Co LO OY 1 09 | Wave-length | 4612:585 12-327 11-950 11-672 11-184 10-810 10-470 10°159 09°546 09:158 08-786 08°633 | 08-284 07-900 07-447 07°146 06°744 06-493 06-104 05°676 05°492 05:288 05:056 04°528 04-209 03-989 03°747 03-488 03°127 02°913 02-509 01°789 01-546 01-259 00°835 00-386 4599-825 99-407 98-488 98-347 98-091 97°757 97-408 96-751 96-497 96-297 95-964 95°577 95-435 95-252 95-010 94-730 94:587 94-391 94-257 94-012 93°635 SS | Intensity and Character Wave-length Intensity and haraaéee NE WNWNNNWRNAMWWW Re fom RDF ON WR RWW Ree be DNR RNR RENN NNR e 4593°533 92-784 92-190 91-815 91-591 91-420 90-985 90-712 90-533 90°509 90-062 89'818 89:458 89-164 88-936 88-551 88-423 88-051 87-921 87-616 87-218 86°855 86-594 86-415 85-987 85°760 85-634 85°407 85°175 84-908 84-666 84-477 84-288 84-016 83-834 } 83-626 83-514 83-331 } 83-086 82-673 82-321 82-111 ) 81.835 | 81-674 | 81:317) 81-058 80-890 | 80-497 80-022 79-625 79-384 79-087 78-808 78-528 E 78-363 78-068 77-884 77-548) | | eRe bh &w bo Bo 6 Bp Beer a ak em ey ak Pa ae Fm ey Oe a Ree Ren SEED ie oe mb i=} me bo 0 _ 1] =] eee hoe bom eho hoe ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS, Wave-length 4577°192 [ 76-987 76-682 | 76°388 76-210 75-953 75625 | 75°508 J 75°122 74-939 74-698 74:133 73-890 73°602 73-208 } 72-966 72-704 72-273 71-998 71-872 71-479 71-312 71-152 70-982 70-765 70-292 70-037 69-526 69-277 68-990 68-581 68-187 67-674 67-435) 67-325 67°124 66-830 66-597 66-404 65-880 65°713 65-635 | 65-335 65°198 65-062 64-798 64-437 64-230 63-864 63-552 63-412 } 63°104 62-955 62-668 62-498 61-990 61-651 61-360 BAND SPECTRUM OF SULPHUR—continued. Intensity and Character, DORE RNNNDE NE WR Ee min BS oo CRE DR WH WW WHORE RENN EWE NDNNN EWN NWR RNR Deere wow Wave-length Intensity an \Character 4561-012 60°841 60-483 } 60-194 59-882 59°743 59°601 59°31 58-952 58-770 | 58-581 f 58-267 57-946 57-495 57-223 56871 56°437 56151 55-928 55°817 55°701 55°481 55-252 54-794 54-237 53°859 ) 53°756 53°616 53284 53°112 52-962 52°272 52-553 52°392 52-211 51-966 51°741 51-403 51:027 50°764 50°445 49-993 49-628 49581 49 346 49-091 54346 \ 48-716 48-524 48°336 48-182 47°765 47-442 47-235) 47-109 | OOK KDE WHE WWRWR NN RENNER wwwre a REE We PRE WWE WR WR EDN N RE eee iow — i NnNwre a Wave-length 4546-926 46-745 | 46°582 ( 46°336 46'196 46-067 J 45°624 45-185 44-978 44:771 44:540 44-275 44-062 43°866 43-736 43-570 43-284 \ 42822 42°617 42°386 41:948 41-229 40°948 som} 40°655 40°395 | 40-244 | 39°997 39°726 } 39-470 39°194 38-982 38-681 38-438 38-192 38-003 37°778 37:490 377181 | 36-958 | 36°774 36°647 36°572 36°361 | 36005 | 35°678 35°398 35:027 34-675 34-487 34-292 34-135 ) 33-883 | 33°569 | 33-254 33-054 149 Intensity and Character Co DODO WwW CO oom) eee He CUTIES meRO I G2 BOR oR BD LOS SD O9 oPO Hm BO LO RO BO GG COORD Ee I Pe a ell Sa 150 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Intensity Intensity Wave-length | and Wave-length and Wave-length Character \Character 4532°762 8 4517837 2 4502°509 32°583 1 17°635 1 02°325 32°327 + 17:407 2 02-106 31°895 \ 1 17:096 3 01-943 31°661 3 16:947 3 01-762 31:476 1 16-433 2 01°333 31:253 4 16°177 3 01-191 30-992 6b 15°816 6 00-922 30°547 6b 15°565 4 00-578 | 30°190 4 15-320 3 00°439 J 29°995 3 15°127 1 00-7128 29°785 3 14:888 1 4499-766 29°564 3 14°667 4 99-579 29°347 \ 3 14°472 3 99-400 29°252 3 14244 3 99-274 28:967 1 13°707 a 99-052 28°655 a 13°399 5 98-873 28°340 5b 13118 3 98-645 27 240] lb 12°836 1 98:480 27°809 4b 12°650 4 98-149 27°580 In 12°349 1 97-888 27°494 \ In 12:209 1 97°672 27:097 4 12°102 1 97°524 26°740 2 11936 3 97°330 26-478 3 11-734 1 97:203 | 26:298 1 11:537 1 96°995 25:°905 4 11°345 2 96-828 25°651 2n 11:054 6 96°566 25°535 } 2n 10°791 5 96-462.) 25:277 1 10°534 1 96°373 | 25:077 2 10°212 1 96-178 24-763 4 10°015 6 95-944 24°408 uf 09°516 6 95-646 24°198 5 08-999 8b 95°494 23-782 | 8 95242) 23°660 4 08-491 4 95:237 23°348 2 08-013 2 94-993 23°208 1 07°871 2 94-596 23°083 2 07°749 1 94-508 22°861 3 07:456 4 94-023 22°581 2 07°188 4 93-807 22-400 2 07:057 4 93-637 22°027 2 06°854 1 93-281 21:667 4 06°489 4 93°045 21°338 2 06:227 6 92-805 20:999 1 05°821 3 92:679 20°797 2 05°572 3 92-310 20°614 3 05-368 1 92-187 20:081 3 05:172 2 92-096 19-750 4 04:946 8 91-835 19°511 2 04:416 2 91:472 19-211 2 04-229 2 91-289 19:074 1 03-964 5 91°110 18-665 3 03-713 3 90°806 18-492 1 03-558 3n 90°579 18°370 1 03°295 | 4s 90°375 18-181 1 02°917 | 6 90-180 18-067 | 2 02-730 2 89:911 Character) Intensity and WW 9 BORO BO HR G9 OTD HR HR G9 C2 a TR HH HS GO 69 G2 ht CD EH HB BD BD G2 GO BD G2 BD CT BO BD BD HS GO GOH BO BO G2 BO kOe Ro 5 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 151 BAND SPECTRUM OF SULPHUR—continued, iA Intensity Intensity Intensity | Wave-length and Wave-length and || Wave-length and Character \Character|| Character 4489°717 1 4476-098 } 2b 4462°573 J 2 act 10 75°867 J 2b 62°421 hep 89-085 8 75558 1 62-329 1 88-836 2 75°373 1 61-660 3 88-680 1 75°223 5 61-406 2 sso} Is | 74910 hae 61-015 4 88-574 Is 74°757 ara 60°415 4 88:215 6 74:598 2 60°206 2 87-908 } 6 74:281 ive d 60030} | 3 87:596 8 74178 Neil | 59°826 | 1 87-124 3 73°899 2Qb-—si|| 59°628 1 snr} 6 | 59°519 \ 1 86°743 3 73°614 + 59:200 2 86-495 5 73°352 4 58°855 3 86-206 5 73°107 | 1 58-503 4 85°877 2 72°948 | 1 58:293; | 4 85-803 } 2 | 72:574 \ 4 57°814 |} 3n 85-591 6 | 72°204 4 57°634 } 3n 85-401 } 6 72°139 | 2 57°429 2 85-067 5 71:964 J 6 57:300 \ 2 | 84°851 5 71:714 1 57:083 1 84-616 5 71:537 2 56:903 2n 84:375 5 71-288 1 56°708 \ Iy peas) 83-891 B)) 71198 J 1 56523 | hen 70:985 1 56-407 | | 2n 83°657 4 70°667 5 56°226 ly vein: 83:476 2 70°439 | 1 56°118 } telat 83-289 3 70°363 | 1 | 55°916 rod 1 83°109 3 707171 3 55°738 2 82-835 5 70:063 eee! 55:538 3 82-637 2 69°849 | 2 55°386 3 82-400 4 69°497 | 2b 55211 hia 82-219 4 68-997 3 55°115 es 4 81-983 5 68-565 2 54-802 1 81:787 5 68-304 2 | 54-684 1 81°632 5 68:219 J 2 | 54°504 3 81-412 2 67:964 3 54°343 1 81°136 \ 8b 67°735 3 54:176 1 80°912 | 1 | 67:566 1 54:048 2 80:779 1 67:259 2 53°87 5 1 80-501 j 8 | 67-088 3 53°49 5 80:262 2 | 66:°883 1 53°306 5 80:092 2hy || 66°727 1 53°098 \ 1 79°782 3 66°488 2 52°667 4 79°523 2 66-201 \ 2 52°303 hall 79°346 2 66-060 2 52-090 |} 1 79°265 | 4 \ 65:820 2 51:973 J 1 79°047 1 | 65°392 3 51°751 In, | 78-893 1 65232 ie 5 §1°562 1 78647 3 | 64°798 | 3 51°371 3 78-390 2 64:503 | 3 51:073 ) 2n 78°187 th Jaca Me rit : 50°881 - 3n 78023 ee! 64:210 1 | 50-608 ) 3n 78-020 8 63°850 | 4 50°296 2n 77-448 3 63°447 2n 50:0 9 4 77091 3 63°166 | 2 49-608 | 4 76:924 3 63°002 1 49:247 _ 4 76°403 | 5 il 62-868 [ 1 48993 ( | 1 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Wave-length Intensity and Character | Wave-length / Intensity) | and 4448-751 | 48-443 | 48-112 47-886 47-171 47-017 46-787 46-611 46-437 46-313 } 46-094 45-916 45-567 | 45-476 | 45-161 44-947 | 44-798 44-365 44-208 43-780 43-474 43-389 43-287 42-914 42-591 42-078 41-890 | 41°750 41-595 | 41-419 41-045 40-883 40-701 40-442 40-140 39-669 39-441 | 38-678 j 38-542 37°708 37-653 37-148 36-906 \ 36-801 36-450 36-196 35-937 35-686 35°598 35-215 35-132 | 34-742 34-596 34-429 34-173 33-997 33-583 33:2 0) v7) Re Ree DK WWNWNHN WWE WHWWRWEWNHNNRE NWN RE RPWNNNE NRF NNNNNRK RF NNNKENNWAe 4433-123 J 32-865 32-643 32-085 31-923 | 31-643 31-349 30-898 30-401 29-955 | 29-726 J 29-131 28-792 28-421 28-030 27-714 27-569 27°179 26-932 26°559 25-884 25-044 24-797 24-487 24-200 23-999 23-749 23-659 23-249 23-014 22-861 } 22-554 22-901 21-731 21-395 21-201 20-904 20°617 20-290 19°856 | 19-687 | 19-401 19-079 18-862 18-430 17:836 17-498 17-040 16-691 16-411 15-948 15-488 15°319 15°140) 14:979 | | a o a eee) o whee toh bo a > DORR RK KE DNR we | Wave-length Character || : Intensity and Ch aracter 4414-842 \ 14-603 J 14-281 14-100 | 13°74 | 13°574 13-421 13-139 12°896 12-548 } 12°373 12-001 11-682 11-448 11178 10-920 10°745 10°630 10-293 09-907 09°705 09:494 09:319 09-107 08-602 08-178 07-892 | 07:798 J 07-400 07-171 07-019 06-874 | 06-754 ) 06-517 06:317 06:117 05-698 05°415 05:156 04-161 03-867 03-633 03-318 03-012 02-750 02:594 02-133 01-499 01-433 01-015 | 00-944 j 00:730 00:536 00-289 4399-961 99-760 99-580 (9-460 Fe NNNNYNK RK NWN bl a im NONDOKNNWNNNKH PRE RE NRK RE RNY NNKP WN RR RR Rr NNWRENNY NNR REE ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. BAND SPECTRUM OF SULPHUR—continued. Wave-length 4399:172 98-889 98-712 98-425 97-836 97-623 97-141 96-889 96-549 96-180 95°605 95-250 94:886 94-321 | 94:101 J 93-751 93-742 | 93-631 J 93-421 93°172 92-936 92-768 92-471 92-134 91-941 91-655 91-479 91-306 91-005 90°751 90°331 90-099 89-919 89-574 89-155 88-858 88-495 88-144 87-842 87-636 87-350 87-208 86-917 | 86°745 J 86-457 85°849 85-615 85-441 85-010 84-945 ————, 84-661 84355 | 84°125 83-949 83-520 83-330 83°155 Intensity’ and Character ORO PN ERNARWWRE NAN WORE RE ARE NE WOWR AAA RN RM Am ar ole oO a PNWwwe he Wave-length 4382:873 82°699 82°495 82°306 Inten sity) and | Character, Wave-length 153 | Intensity and Character WWAANRENNWRNR WWE a oR RR OO oo o ES a a al ll a NONNorRK CO r WwW OD 4369°613 | 69-299 | | 69113 J 68°685 68-418 68-266 | 67-951 67-746 67466 67:146 66-968 66:678 66-468 66-202 65829 65507 65129 64-911 64745 64-481 64-208 63-919 63-730 63-482 63-262 Hm WO OL Or G2 Wo bo o —l — PRODORPER ODOR WORr®D — OONABOAWR OEE HOR WRE WDNR AWNEAMAAMAADS OR ON 154 REPORT—- 1904. BAND SPECTRUM OF SULPHUR—continued. Wave-length 4354-973 ) 54-074 53896 | 53°782 | | 53-560 | ta | 54:783 54°628 53°387 53-264 53-052 52827 52527 52°339 52:197 52-002 51-838 | 51-709 J 51-212 50-984 50°745 50°667 | 50°475 50:282 50°17 50-073 49811 49-665 49-522 49-384 49-207 48-883 48:489 48-120 47-957 47-792 47667 47-447 47-246 47-040 46°871 46-712 46-445 46061 45-680 45534 } 45232 45-019 44-763 44-560 44-339 44-106 43886 43-674 43-488 43165 Intensity. and Character Wave-length RADDA WWRWNN DOWNED WRARR RE ODWOE EEN WWE DEERE OE NDE EP RARE DEE EPO we bhe 4342-966 42-815 | 42-733 42-391 42-144 41-925 | 41:818 41-572 41:372 41-056 40-855 —— Intensity and Character OP RP ORF OP WORK Oe ONlwhh bo AON AMD E De SDH AORRADERREAUTODOBDNENWNENONWE _ oOnmw o Wave-length Intensity and Character 4329-820 | 29°415 29°162 28-799 28-675 | 28-439 | 28-230 28-118 27:945 27°646 27:445 27:149 26°794 26-606 26:420 WWWwWwWNwnwne WHE PRN WERK OWN DOORNKE ROTA 5 OAANNAWWeERORDWOWeEeOWwbee ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 155 BAND SPECTRUM OF SULPHUR—continued. Intensity / Intensity | Intensity Wave-length and | Wave-length and Wave-length and Character} Character Character 4317-258 4 4303-860 \ 3 4290-281 { 1 17°155 3 03-688 J In 90:145 | 1 17-062 3 03-246 ) 3 89979! | 2 16-969 } 1 03-137 ! 3 89-763) | 4 16°753 4 02883 1 89:435 2 16-491 2 02-606 6 89-214 | 3 16-225 4 02-338 1 89-083 J 3 15-943 3 02182 4 SS'S80 rai wel 15-740 3 01-972 1 88-781 | hie2 15-478 1 01891 } 1 88-549 | 2 15°255 2 01-688 ) 3 88-397 } 1 15-020 8 01-502 1 | 88-176 4 14814 \ 3 01-320 ) ie eal 87-956 1b 14:573 1 01-016 oe) 87-725 4 14-267 1 00°857 rt" 87°491 3 14-080 6 00-701 al | 87°305 vert 13-694 2n 00°511 4 | 87:151 ) 1 13-287 8 00:313 2 86-770 2b 13-090 In 00-179 1 86-620 } 2b 12-800 4 00-003 1 86-419 1 12°643 1 4299822 1 86-250 3 12°459 4 99°541 2 85-986 5 12-202 3 99-216 4 12-019 3 98-951 3 11-773 3 98-741 45 85144 4 11°614 1 98-588 1 84-795 3b 11:361 3 98-365 2 84386 § 2b 11°158 } 4 98-235 3 84-169 | 2b 10-959 \ 1 97:894 2 83-967 4 10°869 1 97°511 o% | 83-627 3 10°627 } 4 97-076 3 83-204 2 10°427 4 96-972 aed 82832 2 10-078 5 96-662 real) 82615 1 09°752 } 4 96°325 1 82-483 3 09°495 4 96-318 3 82169 2 09-264. 1 95875 5 82-059 2 09-075 gil | 95598 3b 81-908 3 08-797 ae | 95°353 3 81-676 | 2 08-556 1 95°135 1 81-342 2 08-376 3 94:839 5 81-128 2 07-904 2 94-503 4b 80-798 J 3 07-795 2 94°310 | Bue 4 80-626 1 07-470 5 94-164 pe | 80-480 2 07-250 1 93-895 i = 80-253 3 07°122 3 93-768 J 3 80-107 1 06-888 1 93-484 5 79-909 2 06-680 2 93-039 2 79561 3b 06-427 1 92-939 er 79°183 2 06:272 1 92-409 Be | 79-075 \ hg 2 06-084 5 92239 } ae | 78730 | 2 05°844 2 91-995 ea | 78°566 | ) 2 05-606 1 91-668 J 2 78°473 | 1 05-304 4 91-428 3 73246) | 4 05-009 4 91-210 1 77911 | Qb 04-772 1 91-048 5 77°719 | | 5 04599 1 90-762 1 77°500 | 2 04455 3 90:591)} 3 77°313 2 04-058) 3 90-421 | 1 76-929 1 156 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Intensity | | Intensity | Intensity Wave-length and | Wavye-length | and Waye-length and Character | Character | Character | 4276-758 | 2 4263-256 4 | 4250-982 1 76591 2 63.133 | ae | 49-850 3 76°312 | 4 62-758 cor || 49-631 1 76-205 J 4 62-490 4 | 49-280 2 75-906 3b | 62-212 1 48-921 2 75°658 1 61-966 | 48-655 | 4 75°522 | 1 61:759 a 48-479 1 75-297 3 61-407 3 48-215 1 75087) | Ib 60-963 2 48-109 3 74877 2b | 60-756 1 48-012 3 74°752 ) lb || 60-6389 | 2 47-817 1b 74:175 —_ 60222 | 2 47-580 ] 2 73-957 2 59967 | 1 46-998 2 73°602 4 59-804 2 46-789 } 3 73-423 B - 4 59-678 3 46°597 23 73-285 } 2 | 59-499 2- 46-317 2 72°880 | aa | 59°335 1 46-052 1 72805 | In | 59-019 3 45-901 4 72°567 2 58°897 J 1 45-704 1 72°369 || 58681 | 1 45-677 4 72-254 } 2 58-532 1 45°156 3 71-540 2 58-273 3 45-006 2 71-345 2 58-086 2 44-843 1 71-078 1 57'843 4 44-783 1 70'811 3b 57616 2 || 44-566 2 70°511 4s | 44:395 1 70-083 2b 57-275 5 44-228 2 69-832 2 57-026 1 43-944 2b 69-623 4 56-944 | ae 43-725 } 3 69432 3 56-699 2h 43-540 2 69-223 1 56-493 | 2 43-311 In 68-996 1 56115 2h 43-201 } In 68-743 1b 55'842 3 42-986 3 68-570 4 55662) | Is |i 42-733 1 68-239 4 55°580 Is | 42-554 2 68-007 1 55-287 3b | 42350 2h 67-846 1 54-953 2 | 42-081 2 67°676 1 54815 | 41-901 2 67-411 3b 54-625 o Gi 41°745 3 67:195 1 54-405 3 41595 | 1 66-996 Is 54/102 3 41-462 4 66-819 2b 53-960 { 3 41192 | 1 66-400 3 53-282 5 41068 | 2 65-986 3 53108 | 2 40-835 3 65-913 | 2 52-884 3 40-583 2 65-685 2 52504 | 1 40-339 8 52-402 1 39-840 3b 65-439 4 52-274 2 39-288 | 3 65-258 1 52°164 2 38-976 4b 64-991 3 51-962 3 38°769 | 3 64-784 1 51-643 1 38-557 4 64-565 1 51-510 4 38-187 4 64-329 3n b 37-894 4 64-141 2 51-273 3 37-608 4 64-029 ie 50°795 1 37402 | 1 63°892 2 50-679 1 37:164 (sth 63-671 2s 50-595 2 36857 | 5 63-551 In || 50289; | 1 36°581) 3 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. BAND SPECTRUM OF SULPHUR—continued. 157 Wave-length wv \Character 4236°392 36°234 35°812 35°766 35°625 35°363 35°08 34629 34°358 34:164 } 33°968 33°677 33°453 33°266 33148 32°921 J 32°766 32°415 32°100 31-458 31-322 31-111 30°841 30°642 30°539 30°341 29-969 29-668 29°427 29-062 28-860 28°656 \ 28-304 Intensity nd | | | (Sa) lon ee a POON EP REE ROOR WEE WRWWRONWERRWORE ECON RENE OONNNKEK WR AOWWRe POW bO Wave-length 4223-041 22-810 22-667 J 22-480 22-221 | 22-150 J 21-966 21/811 | 21-592 J 21-423 21-221 20-990 20-660 } 20°588 20-311 20-074 19-881 19-647 19-411 19-266 19-105 18-718 18-544 | 18-282 18-044 17-905 17-736 17-534 17°374 | 17-219 16-962 16-809 16-682 16°451 16-269 16-070 J 15:841 15-669 15539 15-272 15-189 14-656 14°106 | 13-799 13°513 13-186 12-990 12-796 12-646 12-404 12-232 11-901 pee + >= = 11-610 11-450 11°343 11-256 11-051) \Character Intensity and WTR WOR RDI WROWROON OH OE OH KwAeRwDe Ro ae ee eae ion CDNNNNWRERERRE WROD RO Wave-length 4210-943 | 10°758 } 10°659 eben) 10°324 10-139 10-006 09°745 | 09°519 09-287 ) 09-011 f 08-729 ) 08-499 08-299 07-946 07-702 07-525 07-311 07°144 06-822 06-609 06-409 06-235 05-962 05°778 05°592 / 05-326 05-037 04-897 | 04°543 04-134 03-907 | 03-798 | 03-563 03-454 03-279 03-162 03-045 02-888 02-700 02°378 01-910 01:514 eee 01-184 00-986 00:553 } 00-423 00-205 4199°853 99°600 | 99-431 99°139 98-881 | 98-698 98-459 98-272 | 97°917 | | J 1 | | | | | | | ( \Character Intensity and | | | | Go m DO bo G2 Oo Go > PROM N WW WR AWM ORE OMNWOR RN HEE OWORRNOONORNERWNWORWAARONWOUARRE 158 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. | ( Intensity Intensity Intensity Wave-length and Wave-length and Wave-length an. Character Character Character 4197-730 | 2 4185°887 | 3 i 4174-096 4 / 97:°587 1 85°747 2 73933 1 97:461 2 85°632 J 1 73°702 2 97:297 ) 3 85°479 ) | 3 73°546 ] 97-075 8 85°379 - 3 73°357 | 2 96°815 8 85°245 6 73°040 1 96-581 4 84:882 | 3 72°781 4 96392 1 84:728 | 8 72-530 6 96-227 lye 84-461 1 727318 3 96:072 ae) 84°390 | 1 72°085 1 95°616 8 84-270 2b 71:918 3 95°347 / | 4 83°846 | a 71°755 4 94-968 1 83°713 4 71°549 2 94°862 1 83°478 4 71°337 2 94:697 3 83-330 6 70°955 6 94-482 4 j 1 70-662 3 94°308 3 83:031 5 70°364 8 94-194 1 82°807 2 70°242 | 3 94-021 Ky al 82-619 3 69-932 5 93-865 t 82°364 2 69°771 1 93-720 4 82°132 3 69-567 6 93°494 2 81:974 2 69-193 3b 93°274 3 $1:°761 38 68-973 3 93-128 ara 81:583 2 68-801 4 93-032 1 81:370 5 68-608 1 92°847 3 81:188 |} |) 2 68°377 1 92°596 4 81-048 eee 68:221 6 92°313 4 80°795 | 4b 67°832 5 92°135 3 80°648 1 67-700 | UI 91:946 2 | 80°540 [ 1 67:522 4 91-660 5 80°355 ied 67:316 3 91:347 4 80°198 is: 67:028 5 91°211 | 1 \| 79-951 if 8 66°890 3 90-980 5 79°657 zt | 66-658 4 90-802 1 79°376 | 8 66-485 3 90-730 1 78°856 3 66°323 2 90°319 6b 78°696 | 5 66-200 4 90°131 3 78°322 ob 65°916 2 89-907 6 78°184. 1 65°683 4 89-716 1 78°102 j 1 65-473 5 $9°552 5 78-031 1 65:270 4 89-283 4 77°718 4 65°146 4 89-039 3 77:536 3 64956 1 88°816 4 | 77389 | 2 64:807 1 88-614 2b 77:264 1 64-611 | 3 88-290 5 76°995 2 64-416 J 3 88-079 2 76°837 6 64:247 \ 6 87:°787 } 5 76°505 3 64-094 4 87°622 5 | 76°348 | 6 63°755 4 87-422 3 || 75-982 3 | 63-532 4 87:259 1 75°756 6b 63:285 6 87:197 } 4 75°492 2 62-941 4 86:936 1 75°413 1) b || 62°729 3 seraao 4 75293 lJ 62°638 3 86°637 3 75°119 4 62°442 1 86°438 2 74°759 } 4 | 62°332 ce) 86:296 } 4 74:580 5 | 61-971) 1 86:075 | 4 74°312 | 4b Jl 61:858 | 5 il ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 159 BAND SPECTRUM OF SULPHUR—continued. nn Intensity Intensity Intensity | Wave-length and Wave-length and Wave-length and | Character Character Character \| | 4161-682 | 1 | 4150-009 ) 1 | 4136-701 2 61°572 f 4 49-890 4n 367535 i 3 61-308 | 1 49°734 3 36°202 h 3 61:173 ) 4 | 49-498 1 36°016 | 2b 60:971 \ 3 | 49-406 1 | 60-880 3 49-205 1 35°854 HP Lie 60°734 1 | 49-042 2 35°672 ee 60°559 2 | 48-905 3 35°175 t 3 | 60°377 1 48-595 5 34:987 i 3 | 60°199 3 48-227 6 34°755 1 60:034 4 48:051 1 34:570 2 59°781 1 47:897 3 34°359 4 59°670 3 47671 6n 34:060 2 59°576 3 | 47:525 \ 6n 33°852 1 59°476 3 || SATS) 1 33701 | | 2 59°365 1 | 47-025 i, 3 33°511 b 2 59°039 6 | 46°862 3 33°359 1 | 58°764 \ nS | 46:640 2b 33°268 1 58631 f | 46:469 - 1 32°923 1 58°223 | 3 | 46°311 2 32°714 2n 587129 J 3 46-099 3 327432 3 57°887 | 4 | 45°890 1 31°964 3b 57°566 8 | 45°642 5 31-717 | 1 57°173 2 45°323 1 31:575 J 2 56°922 6 | 45°176 } 1 31°343 3 56°651 \ 1 45°038 2 31131 3 | 56°485 | 1 | 44°733 2 30°785 1 | 56-240 | 3 i| 44:310 4 30°684 1 56°126 J 3 | 43°507 1 30°555 1 55°951 1 | 43°179 1 30°427 1 55°756 4 43-001 3 30°280 1 55:569 3 42784 3 307112 1 55°272 1 \ 42°796 | 2 29°894 1 55164 i 4 | 42-672 J 2 | 29°653 1 55034 i 2n. | 42°397 4b | 29°387 3 54°747 ie 2 42046 4 2 297148 1 54:672 3 41°787 3 28°915 2b 54°362 5 41:583 2 28-666 1 53:979 } 5 41:317 } 4b 28°539 1 53°709 1 41°138 1 28-406 1 53:497 5 40911 1 | 28-262 4 537168 3 40°701 4 27°939 1 53-009 1 40°389 4 27°795 } 3 52°818 2 40°017 \ 3 | b || 27°472 1 52°640 } 3 39°836 3 27:274 2 52°391 3 39°596 2 27°120 1 §2°215 3 39°435 2 | 26°994 1 52°105 3 39°224 2 26°806 2 51°886 3 38-969 3 26°604 1 51°622 4 38°842 4 26°402 1 51°410 3 38°249 1 26°205 1 51°185 1 38°019 2 26°057 1 61:011 \ 2 37°829 1 | 25°830 2 50°881 2 37°709 1 | 25°459 | 3 50°758 1 37°469 5 25°065 | 3 50°589 \ 3 37:055 1 24°859 2 | 50-493 3 36°928 2 24:694 } 2 cs 50-285 4 36856 1 24-443 2 160 REPORT—1904. BAND SPECTRUM OF SULPHUR —continued. Intensity | Intensity. Wave-length and || Wave-length and || Wave-length Character | \Character, 4124-243 3b || 4111-037) 1 4098-349 J 24-071 1 10-774 a 98-048 | 23-949 2 10°537° 3 | 97°704 } 23-789 1 10°368 | 3 97-443 23-582 1 10-058 6b 97-262 23-457 4 09°:722 | 2 97-095 | 23-298 1 96-905 23-109 1 09109} | 38 96-634 22-863 ) 2 08-839 J | 96-433 22-721 | 2 08-514 a | re 22565 1 08-322 eS | 95-972. 22146 4 08-026 oN 95-728 ] 21:881 1 07:801 en! 95-332 21:541 1 07-595 eam y 95:184 } 21-352 1 07-493 | 1 tl 94-941 } 21-098 | 3b 07-283 3 7 94-868 20°735 | 3 06-785 8 94-660 20°534 2 06-291 2n 94-475 20340 4 06-066) | 1 94369 20°176 1 05-929 | 2 93-928 20051 1 05-684 1 93-724 19°759 ae) 05572; | 2 | 93°477 19-624 LF 05375} | 2 | 93-265 } 19-371 S. ail 05-133 2 | 93-189 18-950 ] 2 fi 05-0327 | 2 | 92-971 18-862 | axa 04-868 i 92-799 } 18-445 1 04-729 2 92-678 18-311 2 04607 1 92-430 18-059 | 3 04°488 ih 92-242 17-852 4 04-351] | 2 91-974 | 17-587 } 3 04166) | 38 91-768 17-423 | 3 03-958 1 91-418 17-107 4 03694 | | 4 91-229 16-874 | 1 03:407/ | 4 91-059 16-731 J 3 03140 | 2 90589 16-408 2b | 02-973 2 90-493 { 16-084 3 | 02°755 1 90-302 15-760 as 3 02-585 4 89-954 15°529 ee || 02°410 1 89-677 15-170 | 3 02-261 1 89-442 ) 1498304) 1 02-086 3 89-283 14-743 | 2Q 01-892 1 89-127 | 14435 | 38 01-711 3 88-879 14086 | 6b 01-390 ) 3 88-611 13-730}, 7240 SSb. a) 01199 - 4 88-355 13448 a ey 01-000 ) 1 88-205 13-208 oe 00-743 i Ti 88-092 13-031 a 00°484 Le 87-807 12°895 ) 1 | 00-264 2 87:547 12-640 | viel 00-063 3 87333 12°41 | 2 || 4099-893 1 87175 12277 T ail 99-649 Loh 8 86-914 12-132 1 | 99-479 | oe. hl 86-734 11-953 2 il 99-403 | a. a 86-490 | 11-791 | ee tll 99-214 3° 86359 11-635 3 98-985 4 86134 | 11-449} 1 | 98-724 4 85-909 11-231 } 3b | 98:526 } 1 85-714 | | | In tensity’ and | oo 6 PEPE OWN RR RE RR ERE ER OORR RE Rw OWwE io” PNHOWPP RRP RR COON ROR WOR DN WR ROO ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTs. 161 BAND SPECTRUM OF SULPHUR—continued. Wavye-length 4985-445 | 19 85-193 | 84-950 84-820 84-654 84:356 84103 | 83-921 | 83-810 ! 83-590 83-264 83-115 82-873 } 82-581 82-298 180 f 81-999 81-833 81-577 81-384 81-193 80-977 80-786 80-539 80°157 79-841 79-648 79-506 79-375 79-197 78-950 | 78-870 j 78-621 78-442) 78-246 78-084 | 17-887 77-792 77-693 17-581 17-437 77-170 76°754 76-497 } 76-400 76-194 15-963 15°745 15555 75°373 | 75-208 - 75-076 | 14877 74-793 | 74-601 | 74-379 74-193 73-869 ) 04. i Intensity | | and Character Wave-length Intensity and Character io” ~— oe _ KP PWD WW WREKWWWOOR WHR eS WWW RR RWN RE NRHOWOATE ANP EPRONWOUWe WON © b | 4073-720 } 73-471 73-224 73-082 72-976 } 72-816 72-646 72538 | 72-319 72-181 72-082 7 71-522 71:370 [ 71-198 70-965 } 70-808 70-582 70-269 70-039 69-950 69°722 69-399 69-062 68-688 68-432 68-015 67:810 67°675 67-529 67°355 } 67-132 66-838 } _ PDO WWWNNDOWRNDe bo om | \| Wave-length | Intensity and Character 60°801 60-624 60°343 | 60-226 | 60-099 59-962 59°787 4060-956 59-623 59-496 59-417 59-128 38-996 | 58-855 * 58-709 58-553 58-239 58-069 57-923 57-865 | 57-644 57°397 57-123 56-958 56-708 56-454 56-331 56-046 55°883 55°676 } 55-580 | 55°325 55°159 | 54-999 | 54-794 54-609 54-435 54-296 54-157 53-896 53-768 53-523 53°304 53-162 52-964 | 52844 | 52-639 52-482 | 52-220 | 52-029 | 51-900 51-631 51386 | 51-178 50-925 | 50°807 J 50°584) 50-432 } | = OEE ROHDOE PPP RWWWOWRRDWWWRNHWONWOH HE RWONWORE ERE OORWNWNNNORHHEwomwnw REPORT— 1904. BAND SPECTRUM OF SULPHUR—continned. Wave-length 4050-285 J 49-812 49-628 49-413 49-272 } 49-009 48-803 48-605 48-341 48-016 47-842 47-699 47-448 } | 50-065 47°303 47-144 46-942 46-833 ) 46637 46-401 Wave-length Intensity | Piles Character | pes Wave-length nee and | Character. ao > DH DOWER RK COON NDE NWNWNWNWNNWWWORK RS WRRWWWNNWWWRRDHE OE WR RPP a HH bO OU bO B® bO 09 9 0 HH GO OO oa 4038-085 37°915 37-751 37:546 37:281 37°018 36°638 36°631 36°125 35-989 35°910 L 35°783 | 35°675 35413 35°147 34:967 34:714 34:538 \ 34:332 34:061 33°772 33°440 337142 32-928 32-689 32°533 32°389 32-216 CO ORR 0 o> ANAK WWW WR RE RRND NWWWWWORRRE HE WWE RN WRROOORE RDO RE WORE 4025-847 25-699 25-527 25-293 25-109 24-806 24-570 24-303 24-120 23-928 23-776 23-692 } 23-459 J 23-240 22-975 22-794 22-619 22-310 J 22-152 21-852 21-630 21-490 21-987 | 21-197 | 20-966 20°700 20:536 20:346 20-119 20-008 } 19°752 19°463 19-175 18-996 18-794 18670] 18-495 18-244 18-106 17016 17-742 17-505 17°332 17-056 16-862 16-714 16-416 16-295 | 16-145 15-689 15-460 | 15-376 15-104 14-833 } 14-743 14-519 14:337 14-183) RO EOD Ft 9 at rs 9 HR BD BD Ft BO 00 Fe at tat es 09 BD RD Fat et et BD BD BD BD 9 BO HR 9 LO OD tH OO HB BD G9 09 LO OD O9 BO BO G9 OT OT OT BO 5 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 163 BAND SPECTRUM OF SULPHUR—continued. Intensity Intensity. Intensity Wave-length and || Wave-length and Wave-length and | Character | Character (Character, 4014-024 J 1 4002-112 1 3988-550 | 2 13-600 }j 2n 01:959 i 88°322 | 2 13-347 J 2n 01-681 ies 87-955 2 13054 3 01:493 lee 2 87°772 1 12°89] 1 01:347 2 87-619 2 12-724 [ 1 01-107 3 87-288 | 3 12:567 3 00-955 } 1 87:057 1 12-450 il} 00°635 8b | 86°891 1 12-283 1 00-286 | 1 86°749 2 12°161 - 1b 00-066 J 2 86°558 2 12-041 ) 1 3999-835 2 86-331 | 2 11676 2 99-733 | 2 86-016 | 2 11-463 aa 99-637 4 85-862 3 11-209 2 99-432 1 85-394 4 11-103 3 99-243 2 85-205 } 4 10°896 1 99-125 1 84:843 3b 10°792 2 98-925 2 10°670 i! 98°721 5 84-549 1 10°473 1 98-545 1 84°385 1 10-280 1 98-340 3 84-247 4 107119 2 . 98-026 3 84-000 2 09-701 2 97°868 1 83-750 2 09-508 2 97:699 2 83-591 1 09-133 2 97°376 2 83-339 2 08-751 5 96-778 2 83°129 1 08-521 2 96-506 2 82-875 4 08-193 4 96°314 2 82°567 4 08-016 § 3 95°851 } 2 82-479 2 07°738 1 95-722 2 82-043 3 07°528 3 95°535 2 81-822 3 07°364 3 95-339 2 81:510 4b 07-196 1 95-104 2 81-275 1 07-064 1 94-846 4 80-976 3 06-865 3 94-656 2 80°743 1 06-749 3 94°355 1 80-388 4 06-566 2 94-174 2 80-176 | 1 06°397 } 3 | 93-991 1 79°946 4 06-176 3 93-667 2 79°553 2 05-787 2 93-596 3 79°374 4 05°574 2 93-407 4 79234 } 4 05-196 1 93-133 1 78-909 2 05-040 4 92°954 1 78-624 2 04-895 2 92°757 2 78-106 5 04:610 1 92-421 2 77693 ) 3 04-470 2 92-048 3 77°384 1 04-388 2 91-795 1 T7117 1 04-239 1 91-502 3 76°941 1 04:113 1 {| 91-239 1 76°758 4 03-968 2 91-040 1 76-483 | 1 03-793 2 90-829 4 76-323 2 03°477 2 90-518 2 76:163 1 03-251 3 | 90°239 “er 75°930 1 03-073 1 | 89-935 1 75°834 3 02-946 1 89-756 3 75°711 | 1 02°755 1 89-444 2 75°460 3 02-494 4 89-153 2 75-192 1 02-271 3 89-023 1 75:007 2 02-301 2 88-764 2 74-780 3 9 164. REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. | Intensity | | Intensity Intensity Wavelength | and | Wavelength | and Wave-length | and Character Character Character 3974-532 1 3962-508 3 3950°158 } 4 74-386 | 1 62-176 5 49849 3 74-212 1 61:891 ) 1 49-609 3 74-034 | 3 61-759 - 2 49-489 \ 2 73°716 2 61-615 } 3 49-258 | 4 73:516 1 61:307 | 2 48-961 | 4 73°322 De 61-162 | 1 48-687 4 73190 1 61-019 2 ss 02 4 73-012 3 60:857 1 48-364 4 72-808 3 60-678 } 2 48-139 1 72-584 } 1 60°579 i 48-009 2 72°321 3 60-398 ) 4 47°735 4 72-131 2 60:243 1 47-491 1 71-907 1 60-119 j 3 47-336 2 71°762 3 59-931 2 47-201 4 71-542 2 59-806 1 46-740 | 1 71:282' 3 59-707 1 46-502 4 70:929 4 59-497 2 46350 3 70-710 2 59°387 1 467111 4 70°504 3 59-260 1 45°844 3 70191 1 59-097 4 45606 | 3 70-008 4 58-898 1 45°540 3 69:816 2 58-794 2 457164 4 69:736 1 58-557 2 | 44-937 i 69:529 1 58-303 te 44-752 1 69-268 1 58-014 1 44-648 4 69-072 1 57843 3 44-350 3 68-955 3 57°665 4 44-136 2 68°489 3 57393 2 43-826 1 68°375 ro 57144 4 43-548 4 68-245 1 56965 3 43-311 | 4 68-096 1 56363 3 42:567 | 4 67-938 2 56161 1s 42°144 4 67-721 2 55954 ls 41-641 } 4 67:548 2 55°700 4 41-304 1 67:280 3b 55-461 1 40°765 2b 67:072 3 55-203 } 4 40-446 5 66°818 2 54-943 4 | 40°162 1 66°631 2 54-755 fs? 39-808 4 66450 3 54-404 4 39:358 5 66:257 2 54-179 } 2 38-875 1 66-083 2 54-069 2 38-762 } 1 65892 4 53-912 1 38-485 3 65°714 1 53-782 2 38-279 1 65511 4 53-608 3 38-051 2 65-294 2 53-495 1 37-425 | 3 657153 | 2 53-309 1 37°164 3 64:777 3 53:129 3 36673 4 64:553 4 52-908 3 36-278 3b 64-385 1 52647 1 35°878 2 64-248 3 52:308 2 35°460 5 63-937 38 52-071 2 35°155 3 51:837 2 34-916 3b 63-602 1 51-500 3 34:535 2 63:435 4 51-206 3 33-932 4 63-481 | 4 50-978 2 33-685 1 63-077 1 50°673 4 33-249 2b 62-789 3 50-329) 4 32-432 5b ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. 3931-947 31-712 31°416 31-078 30°874 30°559 30°237 30°106 29-691 29-461 28°856 28-403 27:°573 27:274 26-953 26°354 267111 25°837 25:272 25-042 24-802 24415 - | 24178 23-903 23°733 23288 22°813 227114 21-580 21°363 21-013 | 20°887 20-456 20°047 19°577 19-022 18-760 18-369 18-198 17:904 17542 17°389 17-046 17°834 16°527 15-966 15-322 14-906 14-683 Wave-length | ) | | J J J J 14-337 ) 13-944 13-406 13-153 12-771 12-546 12°212 11-920 11-661 11-408 } Intensity, | and | | BAND SPECTRUM OF SULPHUR—continued. 165 Character Wave-length BR OR RE WOR DNWNWNNWNWREPRNNNRRE WHR DRE wh i=] 6B WwWor De 3n 3911-050 10-911 10°624 09-914 09-148 08-846 ) 08-570 - 08-343 } 07°531 07-127 06841 06-634 06-285 05-702) 05-497 | | 05126 04:477 04-157 03-819 03-298 02-827 02-362 01:842 ) 01-622 |. 01-432 ) 00-762 00-437 | 00-181 J 3899-753 99-244 | 98-864 / 98-606 } 98-248 98-023 97-724 97°310 97-021 96°527 96:109 95-574 95-165 94-601 94-202 93-743 , 93°566 | 93:323 | 93-097 92815 92:565 91-715 91-434 91-230 90-984 90°460 90°104 89-786 Intensity and Character SA] 1] Wave-length Intensity and Character aR sec edt kl eel 0 eee PoP CaO Has AE Cae Ge 12] He em ee Ee EIS bo cw bo BO Co a IND: Cok DDR RK wee ww to BOS 09 69 3889-050 88-524. 88-121 87647 86:839 86-036 85-750 85:399 | 85183 | 84-873 84-584. 84-332 84-065 83-828 83-214 82-697 82-429 82°172 81-919 81-433 81-016 80-518 80-306 | 80-123 5 ; 79-860 | 79°635 79°325 78-660 77-925 77°365 76-982 76:560 76°103 75°707 15378 74-587 74:091 73°670 73249 72-888 72-316 72-064 71-761 71-115 70'816 70°501 i 70°275 | 69-951 } 69-766 69-156 69-037 68-645 68-104 67:509 { 66-917 66°415 65:486 65-219 64°849 | De RWWWR We ee Do we = ToS BB Bt OP RO BO BO TR BO OBO BO LO HB 09 OT BD LO BD BO OT 09 OF LO OO BONO bo | | | 166 REPORT—1904. BAND SPECTRUM OF SULPHUR—continued. Intensity) Intensity ! Intensity Wave-length | and || Wave-length and Wave-length and \Character Character es 3864'566 | 2 || 3840-021 3s 3814-984 J Ib 64-233 Pes | 39-702 In 14:573 1b 63859 2 I 39°174 2 14074 91 63°143 yl 38-868 1 13896 Tea 62-480 2b | 38-366 2 13542 pe. 3 62-091 5 38-253 BY 12-881 | 4 ere) 2 37-914 In | 12-467 os. 4 61:218 | 2 37°396 re aa 12-337 i 1 60858 | 2 12-041 3 60-516 3 37-017 33 | 11-645 2 59°787 5s 36-758 1 11-330 4 59°102 2 36-530 2 | 10-704. 3b 58-366 2b 36-088 | | 57-750 4 35-668 oo yl 09851 | 2 57-457 z 35°506 } LG) | 35-204 1 09-274 eae? 56-312 1 34-901 3 08-880 Wir 56017 \ 2 34-157 Is 08-592 1 55°810 3 33-798 In 08-377 1 55-428 3 33-505 2b 07-748 2 54-822 1 33-096 1 | 07°365 3 54-599 | 1 32-883 ee aH 07-017 2 54-281 | 1 32-630 pl 06-694 ) 2g 54°100 | 3 32-407 1 06-414 | 2b 53-686 | 3 32°135 eat 05-821 2b 53-392 | 2b 31-884. | 05:186 3 537145 1 31-497 | 04-844. 3 52-917 ) 3 30-975 2 04-423 1 52-590 | 2 30°569 | 1 04-136 ae 52-300 | 3 30269); | 2 03-676 2 51-874 J 3b 29-398 et ih 03-429 | 3 29-073 Bi Ub 03-073 2 51-752 1 28-484. 2b 02-421 we 3 51-271 | 3 Bayi tae 1 01-908 ) fo Me! 51-004 | 2 27-152 ia oT 01-645 | . 3 50°664 1b 26831 Mesa 01-199 } 2 50°395 2 25-412 | 1 00-716 lie. i 49-499 4 25°174 i= 20> J 00-252 1b 49-183 1 24-563 | 4 || 3799-893 2b 48-878 3b a 99-059 2 48-011 2b 23-537-f0 i) Qn | 98-354 rie 22-964 \ 3 97:°559 | 1b 47-666 1 22-200 ge 97-203 rea 47-259 2 21-947 1 96-889 ee 46-291 3 21-481 ie 96-362 1 46-023 Vie ve | 21-090 i 96-128 2 45-770 aie 20°881 1 95-716 2 45-300 3b 20-188 1 95-390 1 44-988 | 1 19-881 1 94-618 3 44-718 | 3 | 19-559 1 94-176 1 44-390 1 19-201 | 2 93-914 } | 2 44-095 Soe 18°954f | 2 93-564 1S. 43-471 ie 2: 18-528 oe 93-300 2 43-250 ine 2 18-323f | 1 92°841 4 42-689, | 1 | 17-796 | 3 92-451 1 ADDS8 | +2 4 16-986 eas 92-072 3 42-277 1-7) 16-626 le Os 91-713 4 41-911 3b 15-569 | 2 91-400 2 40-905 | 4 15-168) 3b 91-055 1 ON WAVE-LENGTH TABLES OF THE SPECTRA OF THE ELEMENTS. Wave-length 3790-860 90-554 89-972 89-670 89-386 | 89-096 / 88-880 | 88-476 | 88-202 | 87-843 87:466 | 87°159 | 86-839 86-639 86-143 85-818 85-321 | 85-117 | 84-668 | 84-454 83-946 83-577 83-342 83-085 \ 82-519 82-030 81-779 81-511 81-280 80-451 80-163 79-902 79-605 79-454. 78-743 78-447 78-103 77-818 17-367 77-028 76-582 76-307 } 75°542 | 715/262 J 74-795 74-240 73-983 13-655 73°361 72-913 72-422) 72-085 | 71-717 | 71-311 10°777 10-524. 70-273 69-768 | 167 BAND SPECTRUM OF SULPHUR—continued. | Intensity | Intensity | Intensity | and Wave-length and || Wave-length and Character Character Character 2 3769°651 } 3 3748-054 4 3 69-472 J 6 47-456 4 3 69°215 1 46:998 6 4 68-996 | 2 46:047 3 2b 68°583 2 45-429 2 1 68-233 3 44-749 2b 3 67°526 3 44°500 1 3 66:921 ) 3 44°186 2b 1 66:670 2 43°782 2 1 66°358 2 43°432 P) 2 65°884 | Sbe,| 42°977 2 f |] Se |g | ae 3 65:029 4b 41°515 3 1 64°717 1 41°217 2 4b 64°321 2 40°858 3 4 63°736 2 40-099 3 3 63°546 1 | 39°885 } 1 1 | 63°032 Qe || 39°617 2 1 | 39°157 2 2 62°667 2 38941 \ 2 1 38°667 2 lb 38°453 ee 2 61-920 ) 3 38°120 2 ie ba 61°646 3 Piste) 2 ib || 61-249) 3b 37-373 3 1 60°966 lb 36°744 3 1 I} 60°751 3 36-080 1 3 |] 60°505 2 35°449 2 1 60°194 3 35°014 2 3 60-006 3 34-712 2 1 l 59-748 2 34-253 3 3 59-426 1 33-794 2 3 | 59-211 1 33°128 2 2 | 58°871 4b 32°782 1 2 58°099 1 32°538 2 2 57°815 lb 32°033 | 3 1 57°502 1 31°756 | 1 2b 57°202 4s 31-573 } 1 1 56°768 2 30°971 2 | 4 56°280 3b 30°661 \ 4 | 1 55°941 1 30°067 2 | 2 55°542 4 29-845 1 2 55°115 i 29°611 1 ere 54°854 2 29-293 3 2b 54°567 iJ 29-068 1 | i 54:026 | 4 28°533 4b 1 53°722 3 3 53°385 3 28-089 1 3r 52°473 | 4 27°819 2 2 51-911 } 3) 27°314 2 2 | Bee | i | Bm | In 50°498 1 26-079 | 2 3 50°175 5 25°888 n 2 49-536 2 25°348 \ 1 In 49-284 3 oe : 49-023 1 24°785 3 48-731 6 24°569 1 8 REPORT—1904. 16 ND SPECTRU SULPHUR— ontinued. B M OF P C e. A th iti penalty Intensity ie ae th | and || Wayvye-length Shane se re ‘Character RES See Character i : | 1b 3667-340 } > 2 | 3694-708 1b | ey 3724-345 J aw pias Ib 7-07 | a0 ae il sak 1b 66:537 2 ze 4 forks b 66-217 4 see | 3 93-499 1 66-217 , He 1 93-086 Qn 66-130 } noe 1 92642 | 3n 65-695 ae in, 4 91-836 -- 3n mee 3 ee is 91-400 | ifs 64090 : 19149 1s 91-400 so 18-847 Fao 90-872 | lees ae : 18-518 f oa 1 90:552 | 1 64-080 : 10365 # ae al a 63345 | 1 1585 4 eee ae 62-877 1b 1s i 87010 | In 62656 Os 15-187 \ 1 87-010 Lee | ae = Het | 3b 86°585 | In | peel 3 14755 2 Il 86134 | 2 | cio) 1307 2 sear i 61307; | 1 13-501 } 3 85-457 1 ee Re ra 2 Aer = 60-478 } 2s 12-747 9. | 84-518 Dre: | pone ree 14 : ie 50656 | | 2 oe \ 1 S322 | 2 | obo eda 10818) 82547] ) | In ear tee a 1 81-632 | | In 59°706 2 see \ 2 |i 81-203 | 1 | On 58-508 1 10°322 4 80-939 | | ln | pos 2 ces 2 || 80-255 1 57-991 3 a 1 wai | “2 S754 2 ee 2 78997 | 3 57-068 = 07-622 - 78-907 3 so ree 1 77-806 1 56°573 3 coe ne In || 77405 | Is 56-159 2b wegen 7 76-271 2 oa 842 4 Hens 2 75°874 1 54334 2 s3. 20 ; pees B | 53-838 2 ease 2 75-233 3 | 53-838 2 230 i te tt 53-300 Qn aS 1b 73-517 2 53-300 \ 2n ce 5 ae 5 52834 1 os 1 | 72°717 In oe : 3699-907 , m7 1 a ee 1 71-894 | 2 2-274 } Hoe 2 71-632 2 52-074 2 a8 5 Fone Pe 51-200 1 re 2s 70-762 ) n oe al 25 || 70333 3 ee Hee 2 || 70-153 | 1 50-084 2 — 96-955 2 69-197 3 49825 | 1 os 1 68-701 } In 49-067 4 pemeeny 24 2 68-466 1 ee 3 ee | egos 67/951) 3 one ee 67-634 | On ON THE STEREOCHEMISTRY OF NITROGEN. 169 The Stereochemistry of Nitrogen. By H. O. Jones, M.A., D.Sc. [Ordered by the General Committee to be printed in ewtenso.] Tue stereochemistry of nitrogen has, for a number of years, attracted considerable attention, which was until recently confined chiefly to the isomerism of the tervalent compounds; of late years, however, the quin- quevalent compounds have been the subject of an exceptionally large number of investigations. The former, with the exception of a few out- standing problems, may almost be regarded as a closed chapter, whereas the latter is still in a state of rapid change. The phenomena exhibited by these compounds are so bewildering in their variety, and apparently so difficult to reconcile with one another, that this brief review of the present state of our knowledge may be useful in promoting discussion which will throw some light on the obscure problems that perplex workers in the field. The facts brought to light by the work on quinquevalent nitrogen compounds considered in conjunction with those observed by Professor Pope and his collaborators in sulphur and selenium compounds necessitate some slight alteration in the prevalent conception of valency, and have at the same time supplied the materials for such a revision of ideas. No entirely satisfactory hypothesis as to the nature of valency and the forces which act in chemical compounds has hitherto been proposed. There is, however, a growing conviction that these forces are electrical in their origin and arise in consequence of the electrical structure of the atom; if this be so, then these forces are very probably localised along certain directions outside the atom. However, without making any assumption as to the nature of these forces, the existence and stability of chemical compounds almost require that they should have a definite spatial configuration such as must be assumed in order to account for the phenomena of stereoisomerism, and further, that the most symmetrical contiguration possible would probably be the most stable. By a definite stable configuration is understood an arrangement of atoms or groups around a plurivalent atom in which each group, under the action of forces exerted on it by the plurivalent atom and by the other groups, oscillates (within limits dependent on tempera- ture and other conditions) about an equilibrium position in which it would probably be stationary at absolute zero. The lines joining the centre of the plurivalent atom to the centres of the various atoms or groups in their equilibrium positions may be called the ‘ valency directions.’ The equilibrium position for any particular radical attached to a pluri- valent atom—carbon, for example—would not be fixed, but would be dependent to some extent on the other radicals attached to the same atom, since the position taken up is the result of the action of a number of forces; hence the valency direction must also be variable to some extent. These views were quite clearly expressed by van’t Hoff soon aiter the tetrahedral configuration for carbon compounds was proposed. The new assumption, which had to be made in the light of recent experience, is that during a change of valency, such as that of sulphur from quadri- to sexa-valency,' the configuration of the molecule may alter and the radicals already present take up entirely new positions. 1 Pope and Neville, Zvans. Chem Soc., 1902, 81, 1560. 170 REPORT—1904. Assumptions of a slightly different kind have been made to account for certain phenomena observed in quinquevalent nitrogen compounds ; it has been found necessary to suppose that the position occupied by the electro- negative radical is not always the same—in fact, that the resultant effect of the forces exerted by the nitrogen atom and four electro-positive radicals is such as to attract an electro-negative radical which may enter the molecule in one of two positions. Further, in order to account for the existence of one kind of isomerism observed among tervalent nitrogen compounds (p. 172), it has been sug- gested that for three groups attached to a nitrogen atom two configurations are possible. Stress must be laid on a difficulty encountered in the whole of this field—namely, the uncertainty as to the cause of certain differences which are observed in some compounds, particularly when those differences disappear on solution, whether they are to be attributed to isomerism of an unstable kind or merely to dimorphism : this difficulty is accentuated when the compounds exhibit no distinctive differences in their chemical reactions. It has been deemed advisable in dealing with this subject to treat the tervalent and quinquevalent nitrogen compounds separately, and in the latter case to present the facts completely before entering upon any dis- cussion of them, because it is necessary to review the whole field in attempting to offer a consistent explanation of the various phenomena. The time is certainly not yet ripe for drawing any final conclusions about this complicated subject, and there is still much work to be done before a clear path through the maze-will become evident. I. TervaALent NirroGen Compounps. (i) Compounds of the type N a be. (a) The Problem of Optical Activity.—It might be expected from purely dynamical considerations that the most stable configuration for three groups attached to one atom (nitrogen) would be that in which all three groups were situated in the same plane with that atom ; the distances of the groups from the centre of the nitrogen atom would be variable and dependent on the nature of the groups, but no displacement out of the plane would be expected so long as none of the groups was asymmetric. Such a displacement apparently occurs when strain is introduced, as in the formation of cyclic compounds or double linkages, and might occur if one of the groups became asymmetric. This view is supported by the facts, since all attempts to demonstrate asymmetry in tervalent nitrogen compounds—other than cyclic compounds —have hitherto been abortive. Krafft! tried to resolve ethyl-benzylamine and p-tolyl-hydrazine by the crystallisation of their neutral tartrates ; Behrend and Kénig ? made similar experiments with the tartrates and mandelates of 8 benzyl-hydro- xylamine and f nitro-benzyl-benzyl-hydroxylamine, and Ladenburg * on the acid tartrates of methylaniline, tetrahydroquinoline, and tetrahydro- pyridine. In all cases the salts appeared to be homogeneous, their properties remaining unaltered by recrystallisation. Regarded in the light of recent experience these experiments are 1 Ber., 1890, 28, 2780. 2 Ann., 1891, 268, 175. 3 Ber., 1893, 26, 864. ON THE STEREOCHEMISTRY OF NITROGEN. 171 inconclusive, since similar attempts failed to resolve quinquevalent nitrogen compounds. The failure might have been due either to hydrolytic dissocia- tion of these salts of weak acids with weak bases, or to partial racemism, which the recent work of Professor Kipping has shown to occur so frequently. Reychler ! eliminated the first-mentioned possible cause of failure in his attempts to resolve methyl-ethyl @ naphthylamine by fractional erystallisation of its dextro-camphorsulphonate from non-hydroxylic solvents ; the writer also made a similar attempt with methyl-benzy, aniline, but no resolution was effected in either case. The evidence derived from all the foregoing experiments (with the exception of that in which p-tolyl-hydrazine was used) is useless if the change of valency direction established in the case of sulphur and selenium also occurs in nitrogen during the change from ter- to quinquevalency. There is, however, no evidence of this, and the ease with which cyclic compounds, such as pyridine and piperidine, form quaternary ammonium derivatives is not in favour of this view. On this account some experiments were made by Mr. J. P. Millington and the writer? with the object of obtaining evidence free from this objection, by avoiding a change in the valency of the nitrogen during the process of resolution. Benzyl-phenyl-hydrazine d-camphorsulphonate and the brucine salt of methyl-ethyl aniline sulphonic acid were submitted to fractional crystallisation, but without effecting any separation into fractions of different rotatory power ; in the first case it is probable that no change of valency of the nitrogen atom in question takes place, and in the second it is certain. Evidence of quite a different kind has been adduced by Messrs. Kipping and Salway.* It was proved that when an externally compen- sated acid chloride reacted with an externally compensated primary amine (each containing an asymmetric carbon atom) to form a substituted amide, this consisted of four compounds, which being enantiomorphously related in pairs give rise to two externally compensated compounds easily separable by fractional crystallisation. This, therefore, forms a method of testing for asymmetry in carbon compounds, and by analogy it should be capable of detecting asymmetry in nitrogen compounds. The products of the interaction of dl-benzyl-methyl-acetyl chloride with methyl aniline, p-toluidine, pheny]-hydrazine and benzy] aniline were examined and found to be homogeneous. The active (d) acid chloride was also allowed to react with p-toluidine and with benzyl aniline ; but, as before, the product appeared to be a chemical individual. Finally, the active chloride was treated with an active amine ; if the nitrogen atom form a centre of asymmetry, in addition to the two already present, then two compounds should be formed ; but again the product was homogeneous. Clearly, therefore, all the evidence is in favour of a plane configuration for tervalent nitrogen compounds. (b) Isomeric Tervalent Nitrogen Derivatives N a 6 c.—Although the tervalent nitrogen atom is incapable of giving rise to optical activity, it seems capable of giving rise to another kind of isomerism of which there are two distinct examples. ' Bull. Soc. Chem., 1902[3], 27, 979. 2 Proc. Camb. Phil. Soc., 1904, xii. 489. 3 Trans. Chem. Soc., 1904, 85, 438. 172 REPORT—1904. Miller and Pléchl! found that the product of the interaction of as-m- xylidine with acetaldehyde in hydrochloric acid solution was a mixture of substances which had to be separated mechanically. The two substances have the same composition and molecular weight and give the same reactions. They are represented by the formula C,;H,(CH;),NH—CH—CH, CH, CHO because (1) they give the tests for an aldehyde, (2) condense with m- xylidine to give the same product, C,H,(CH,),NH—CH—CH, C,H(CH;),N=CH—CH,, (3) give the same benzoyl derivative, and (4) are mutually transformable. They differ only in melting point (102° C. and 131° C)., crystalline form, and solubility in ether and benzene. The evidence points very clearly to some cause other than structural differences to account for this kind of isomerism, though the possibility of tautomerism has not been detinitely excluded. The other example was observed by Willgerodt? in the sym-dinitro- pheny]-pheny|-hydrazine produced by the interaction of dinitro-chlorben- zene and phenyl-hydrazine. Two isomeric substances appear to be formed, one being an amorphous powder which is readily transformed into the other and crystalline isomeride. Here also the possibility of structural difference in the nitro group hardly exists, for if it did, it would certainly be observable in many other compounds. Willgerodt offers an explanation of this isomerism based on the assumption that free rotation is limited between two nitrogen atoms; but this assumption is undesirable and is not supported by any other experimental facts. Vaubel * suggested a configuration for the nitrogen atom which would explain the above cases of isomerism, based on the following considera- tions : a nitrogen atom is capable of taking the place of a —CH group in pyridine and also of becoming quadruply linked to carbon in isocyanides. On this view the groups attached to the nitrogen are supposed to occupy definite fixed positions which are at certain different but fixed distances from the centre of the nitrogen atom. This assumption is unnecessary and is contrary to the spirit of stereochemical conceptions. Further work on this subject is much needed, but if it be definitely established that isomerism, such as that apparently exhibited by the above- mentioned substances, does exist, then it must be assumed that there are two possible positions of equilibrium for three groups attached toa nitrogen atom, one being somewhat more stable than the other. Isomerism, due to such a cause, could only be detected under favourable circumstances similar to those under which these experiments were carried out—namely, when a reaction resulting in the formation of a solid substance takes place in the cold; in all such cases one isomeride would probably readily pass into the other. 1 Ber., 1896, 29, 1462. 2 Journ. prakt. Chem., 1888, 37, 449. 3 Stereochemische Forschungen, 1899, i. 20. ON THE STEREOCHEMISTRY OF NITROGEN. Wises (ii) Cyclic Nitrogen Compounds. The evidence for isomerism of tervalent nitrogen compounds is more conclusive in those cases where the nitrogen atom forms part of a ring. ‘Ladenburg ' found that when coniine hydrochloride was distilled with zinc dust and a Jittle water a new substance called isoconiine was pro- duced ; isoconiine differs from coniine in optical rotatory power, the solu- bility of its chlorplatinate in alcohol and ether, and to a less degree in other properties. The existence of these isomerides is explained by supposing that the hydrogen atom attached to the nitrogen may be either on the same side of the plane of the piperidine ring as the propyl group or on the opposite side, thus : oS | alow, luloum, Ne ~ N—H H—N This hypothesis is not incompatible with the plane configuration of the nitrogen atom, since the strain introduced by the formation of a ring may disturb the equilibrium. Later ? Ladenburg described zsostilbazoline, an isomeride of stilbazoline differing from it chiefly in rotatory power. Isomerism of this kind should exist in the y piperidine compounds which are not optically active, but this has never been demonstrated. The case is, however, much strengthened by the discovery of the isomerism of tropine and w tropine. y tropine was obtained by Ladenburg and Roth * from hyoscine, and was prepared artificially by Willstatter* by the reduction of tropinone. Similarly, Willstatter and Miller obtained two tropylamines. In these cases there is no asymmetry in the molecule ; both compounds are inactive,and the isomerism can only be explained by the different spatial relations of the methyl and the hydroxyl or amino group thus— CH,—_CH-—-—CH, CH, CH——CH, | | N—CH, H—C—OH and CH,—N H—C—oH | | | | cH,—-CH—__—CH, CH, CH——CH, Giustiani® described isomeric benzylmalimides which differ in solu- bility and melting point, and give different monacetyl and benzoyl deriva- tives. Here, however, there is a possibility of tautomerism which has not been excluded, but if this be set aside the isomerism could be explained in the same way as that described above. 1 Ber., 1893, 26, 854. 4 Ber., 1896, 29, 936. 2 Ber., 1903, 36, 3694. 5 Ber., 1898, 31, 1212, 2655. 8 Ber., 1884, 17, 151. ® Gazz, 1892, 22, 1. 169; 1893, 23, 1. 168. 174 REPORT—1904. a—C—b (iii) Lsomerism in compounds of the type | —¢. The isomerism among compounds in which nitrogen is doubly linked to carbon is now so well established and the hypothesis of Hantzsch and Werner to explain it so abundantly supported by experimental evidence, that in this place it will suffice if a very brief statement of the most important conclusions arrived at be made, and attention called to a few points which cannot as yet be regarded as settled satisfactorily. (a) Ketoximes.—Goldschmidt! while working with V. Meyer on the oximes of benzil discovered an isomeride of benzil dioxime; later V. Meyer and Auwers discovered a third modification of the same substance? and a second monoxime of benzil.* Meyer and Auwers gave a clear and conclusive demonstration of the structural identity of these oximes‘ and proposed to account for their existence by assuming that free rotation between the carbon atoms was prevented in these compounds. The discovery of an isomeric oxime of p-chlor-benzophenone ® disposed of this view, which cannot account for the existence of a second oxime, and the hypothesis of Hantzsch and Werner © alone remained. These authors explain the isomerism of oximes by supposing that when a nitrogen atom is united to carbon by a double bond, the third valency is not in the same plane as the other two, and the group attached to it may take up two equilibrium positions one on either side of this plane. According to this hypothesis, there should be one oxime of a a—C—a co namely | a N—OH ine a—C—b a—C—b and two of CO namely | and | Be NOH HON, a prediction verified for the oximes of benzophenone and p-chlor-benzo- phenone and in many other cases. a—C—C—a Then two monoximes and three dioximes of a diketone eral 0 Fa should exist, the dioximes being represented thus : a—C—C—a a—C C—a a—C — C-—a ll ll | I | I HON N.OH HON HON NOH HON which has been verified in the case of the mono- and dioximes of benzil. The isomerism in all these cases is perfectly definite, the compounds differing in melting point, crystalline form, solubility, and some of their chemical reactions, and further are mutually transformable under the influence of heat, solvents, and suitable reagents such as acids and alkalies. The usual criterion for determining their configurations is the 1 Rer., 1883, 16, 2176. 2 Ber., 1889, 22, 537. 3 Ber., 1889, 22, 705. + Ber., 1888, 21, 784, 2510: 1889, 22, 564, 1985, 1996. ° Ber., 1890, 28, 2403. ° Ber., 1890, 28, 11; Zeit. phys. Chem., 10, 1. ON THE STEREOCHEMISTRY OF NITROGEN. Vie ‘Beckmann transformation,’! by which the oximes are transformed into substituted acid amides, thus :— a—C—b a—C=O a—C—b O=C—b l| = | and | hz | N—OH NH—d HO—N a.HN The hypothesis predicts four isomerides of compounds of the form a—C | | but until quite recently no instance of this had been HON NOH observed. Manasse” obtained three dioximes of camphorquinone, and Dr. Forster * re-examined these and obtained a fourth. In the case of the ketoximes the predictions of the hypothesis have been experimentally verified for all kinds of ketones of the aromatic but not for those of the fatty series. Most of the attempts to get isomeric oximes of fatty aldehydes and ketones have been unsuccessful ;4 the only case definitely observed is that of the oximes of oxalacetic acid,°® of which there are two definite isomers differing in melting point and in their behaviour towards ferric chloride ; with which the a acid givesa yellowish brown and the (3 a violet colour. (b) Aldoximes —The case of the aldoximes cannot be regarded with the same complacency. Beckmann ® observed that benzaldoxime when treated with sulphuric acid or with an ethereal solution of hydrogen chloride was converted into an isomeride. A long controversy then ensued between chemists who claimed that the isomerides were structurally NH different, as represented by C;,H;CH=NOH and CyH,CHC | , and O those who held the view that the differences were stereochemical, as in the case of the ketoximes. The work has been confined mainly to benzaldoxime and substituted benzaldoximes. The two benzaldoximes give respectively an oxygen and a nitrogen ester when treated with alkyl haloid compounds—a fact regarded as evidence in favour of structural isomerism. The work of H. Goldschmidt’ on the action of phenyliso- cyanate on the two oximes and that of Professors Hartley and Dobbie 8 on their absorption spectra, however, is in favour of structural identity. Fa The hypothesis of stereoisomerism is now almost universally accepted, and is supported by the phenomena exhibited by the esters, which were at first so difficult to reconcile with this view. ““f- Beckmann ® treated a (anti) benzaldoxime with sodium ethylate and benzyl chloride in the cold and obtained an oily ester which on treatment with hydrochloric acid split up partially into benzaldehyde and a benzyl- hydroxylamine and was therefore an oxygen ester, whereas by similar treatment of the @ (syn) oxime he obtained a crystalline ester which ) Ber., 1883, 16, 2176. 2 Ber., 1893, 26, 243. 3 Trans. Chem. Soc., 1903, 83, 514. + Franchimont (Ree. trav. Pays-Bas, 10, 236); Dunstan and Dymond, Zyans. Chem. Soc., 1892, 61, 470; 1894, 65, 206. 5 Piutti (Gazz., 1888, 18, 457); Ebert (Ann., 1885, 229, 76) ; Cramer (Ber., 1891, 24, 1206); Dollfus (Ber., 1892, 25, 1915); Fenton and Jones (Zrans. Chem. Soc., 1901, 79, 95). ® Ber., 1887, 20, 2766; 1889, 22, 429. 7 Ber., 1889, 22, 3112. 8 Trans. Chem. Soc., 1900, 77, 509. 9 Ber., 1889, 22, 435, 1534. 176 REPORT—1904. gave B benzyl-hydroxylamine on hydrolysis, and was therefore a nitrogen ester. Later Werner and Buso ! found that the liquid oxygen ester just re- ferred to, on treatment with hydrochloric acid underwent isomeric change during its partial hydrolysis, and gave rise to a solid oxygenester. There are consequently two isomeric oxygen esters, the existence of which can only be explained by different steric relations, and a nitrogen ester. The phenomena exhibited by the methyl] esters are complementary to those observed in the benzyl esters. Petraczek ? prepared a methyl ester by the action of sodium and methyl iodide on a benzaldoxime, which ester when hydrolysed gave a methyl-hydroxylamine, H. Goldschmidt and Kjellin® isolated an ester from the products of the interaction of 2 benzaldoxime, methy] iodide, and sodium methylate, which gave /3 methyl- hydroxylamine on hydrolysis, and was therefore a nitrogen ester ; at the same time they observed the odour characteristic of the oxygen esters and concluded that the oxygen ester of the syn oxime was formed at the same time. Finally Dr. Luxmoore?* observed that by the action of methyl bromide and hydrobromic acid on £ benzaldoxime the hydrobromide of a new nitrogen ester was produced. This ester differed from the nitrogen ester already known in being very readily hydrolysed by water to form B methyl-hydroxylamine ; it was also labile, and on standing changed into the stable syn N ester. Thus there is enough evidence to justify the conclusion that two benzyl- oxygen esters and two methyl-nitrogen esters exist, and the isomerism in these cases can only be explained on the hypothesis of stereoisomerism— thus, . | and So yo wis C,;H,ON NOC,H, CH,N N—OH,. This conclusion is supported by Goldschmidt’s work on isomeric oxygen esters of anisaldoxime and nitro-benzaldoxime.° The isomerism of the nitrogen esters is analogous to that of tropine and wy tropine. In addition to the Beckmann transformation a second criterion for the determination of configuration is applicable to the aldoximes ; one of the oximes on treatment with acetic anhydride loses water and gives a nitrile, whereas the other either remains unchanged or gives an acetyl a—C—H derivative, the former must therefore be the syn-oxime, (| , and NOH a—C—H. the latter the anti-oxime, ll HON The hypothesis of Hantzsch and Werner, which has, as we have seen, accounted in a satisfactory manner for the isomerism observed among the oximes, requires that isomerism should exist also in other compounds with 1 Ber., 1895, 28, 1278. 2 Ber., 1882, 16, 827. 3 Ber., 1891, 24, 2812. Trans. Chem. Soe., 1896, 69, 177. 5 Ber., 1890, 28, 2178. ON THE STEREOCHEMISTRY OF NITROGEN. Wye alike structure. A search for these isomerides instituted by Hantzsch and others has been successful in a number of cases. In all these casesit is more difficult to exclude the possibility of dimorphism and to show that the compounds in question are structurally identical. (c) Hydrazones and Semicarbazones.—The evidence for the existence of isomerism among hydrazones and semicarbazones is fairly conclusive, though by no means so satisfactory as for the oximes. Fehrlin ! found that the hydrazone of o-nitro-phenyl-glyoxylic acid was converted into an isomeride, when dissolved in alkalies and precipitated by the addition of acids ; the two products differed in crystalline appear- ance, melting point, solubility, and behaviour with nitric acid, but gave the same reduction product. These results were confirmed by Krause,” who found, besides, that both gave hydrazones of isatin on oxidation. Hantzsch and Kraft* by the action of phenyl-hydrazine on anisy]- phenyl-ketone on the one hand, and on its dichloride on the other, obtained two different anisyl-phenyl-ketone hydrazones which differed in appear- ance and solubility, and one of which was slowly transformed into the other in alcoholic solution. The possibility of structural differences was finally excluded by Overton * by preparing two diphenyl-hydrazones of anisyl-phenyl-ketone, and of p-tolyl-phenyl-ketone by the method used by Hantzsch ; several other hydrazones, however, could only be obtained in one form. Anschiitz and Pauly ° prepared three isomeric diphenyl-hydrazones of dioxy-tartaric ester, two of which are readily transformed into the third by heating in solution or by traces of reagents such as iodine and sulphur dioxide: behaviour which is very characteristic of stereoisomerides ; Bamberger and Schmidt ® found that two hydrazones of benzoyl-formalde- hyde could be obtained, and that these were interconvertible by means of solvents. The only aldehyde hydrazones which have been obtained in different forms are the phenyl-hydrazones of protocatechuic aldehyde,’ and of salicylic aldehyde,* and in both these cases the evidence is not sufficient to exclude the possibility of tautomerism in the benzene ring like that shown by phloroglucin. The evidence of the existence of isomeric semicarbazones is insufti- cient ; but Marckwald” has observed very definite isomerides of diphenyl thiosemicarbazine itself, which differ in melting point and in their reaction with carbonyl chloride. Their reactions are explained as follows :— C,H,NH—C—SH -. C,H,—NH—C—SH I I C,;H,—NH—N N—NH—C,H, | coal, | cocl, C,H;N—C—SH ne eS me CO N Now at ie ae —C,H,. P 1 Ber., 1890, 23, 1574. 2 Ber., 1890, 28, 3617. 3 Ber., 1891, 24, 3511. 4 Ber., 1893, 26, 18; see also Hantzsch, Ber., 26, 1. * Ber., 1895, 28, 64. ® Ber., 1901, 34, 2001. 7 Wegscheider, Monats., 1893, 14, 386. § Biltz, Ber., 1894, 27, 2288, ° Ber., 1892, 25, 3098. 1904. N 178 REPORT—1904. Both react with methyl iodide to give derivatives in which the methy] group appears to be attached to sulphur, which points to the absence of structural differences. (d) Stereoisomeric Aniles and other Compounds.—Many unsuccessful attempts to prepare aniles, Schiff’s bases, in isomeric forms were made before any indication of their existence was obtained.! A new isomeride of ethylidene aniline was isolated by Hibner,? from the product of the reaction in water, which melted at 85°5° C., whereas that already known melted at 126°C. The two compounds are mono- molecular, and the one with the lower melting point is readily converted into the other. Later, the same chemist with Peltzer? isolated two isomeric ethylidene o-toluidines, which were apparently structurally iden- tical, and of which, again, the lower melting point form could be readily transformed into the higher. Hantzsch and Schwab ‘ described two ben- zylidene p-toluidines in which the isomeride with the lower melting point is the more stable. The possibility of structural differences in simple aniles, like C,H,—N=CH—CHsz, need scarcely be considered, and the relations between the compounds exclude dimorphism, so that their exist- ence must be due to stereoisomerism. Lastly, Schall and Raschkowetzky° describe two isomeric carbo- JN—CoHs diphenylimides, of , between which there can be no structural Aw -CyH; difference. a—N (e) Compounds of the type II Azo and Diazo Compounds.—Azo NN — ’ compounds ought to exist in isomerides similar to those of oximes and hydrazones, but that they do so has never been established in a satisfac- tory manner. Janowski® has described two trinitroazotoluenes and two p-azoxytoluenes ; the evidence, however, is insufficient to allow any defi- nite conclusion to be drawn from it. The diazo compounds are well known to exist in isomeric forms, to explain which no hypothesis seems adequate except that of Hantzsch, together with the admission of structural isomerism. This subject is so involved, and moreover has so recently formed the subject of an exhaus- tive report,’ that a mere mention must suffice. Syn and antidiazo com- pounds exist, which are represented thus C,H,;—N C;H,—N | and I X—N N-X, where X represents an acidic radical, a hydroxyl group, or a metallic radical attached to oxygen. Diazonium compounds, which are structurally different from the diazo compounds, also exist. a—C—b The existing isomerides of compounds of the type ll and allied N—c types can only be satisfactorily explained with the aid of the Hantzsch- 1 Ber., 1891, 24, 3518; 25, 2020; Ann. Chem. Phys., 1896, 9, 433. 2 Ber., 1894, 27, 1299. 2 Ber., 1900, 33, 3460. 4 Ber., 1901, 34, 822. ® Ber., 1892, 25, 2880. 6 Monats., 1888, 9, 831; 1889, 10, 583; Ber., 1890, 23, 1176. 7 Morgan, Brit. Assoc. Rep., 1902, 181. ON THE STEREOCHEMISTRY OF NITROGEN, 179 Werner hypothesis, which has predicted and accounted for all the cases of isomerism of this kind hitherto observed. The absence of isomerides in some cases in which they were expected—for instance, the oximes of aliphatic aldehydes and ketones—is not to be regarded as a serious objection, since one of the compounds may be so unstable as to be almost immediately transformed into the more stable isomeride, or again, in such cases as the azo compounds, either a suitable method for preparing the isomeride may not be known, or the compound may not be reactive enough to undergo transformation by any of the methods available. II. QuinquEVALENT NiTRoGEN ComMPouNDs. Attention was first drawn to the ammonium compounds with reference to the discussion whether valency was fixed or variable, and from 1816 onwards a lively controversy waged between chemists who maintained that ammonium chloride was a molecular compound, and those who held the view that it was an atomic compound in which nitrogen was quin- quevalent. Experiments made by V. Meyer and Lecco! showed that the union of trimethylamine with ethyl iodide on the one hand, and of ethyl-dimethyl- amine with methyl iodide on the other, gave rise to the same product ; after an objection raised by Lossen? had been answered? this was regarded as strong evidence in favour of the atomic nature of these compounds. Had the results of these experiments been different an erroneous conclusion would have been arrived at. At present the doc- trine of variable valency is accepted by most chemists, and ammonium aN chloride is usually represented as H Voce ake with a quinquevalent nitro- H H gen atom attached to four atoms of hydrogen and one of chlorine. (i) The Formation of Substituted Ammonium Compounds, The rate of formation of substituted ammonium compounds from amines and alkyl halogen compounds varies to a very great extent, and is found to depend both on the alkyl groups in the amine and on that in the halogen compound, Much work has already been carried out on this sub- ject, and much more will have to be done before one can hope to under- stand the reactions. Thus Menschutkin‘ investigated the velocity of the reaction between a very large number of alkyl halogen compounds and amines ; no general conclusions can be drawn from this work, the amines being divided into three classes, according as the maximum rate of formation occurs (1) for the salt of the tertiary amine, (2) for the salt of the secondary amine, or (3) for the quaternary ammonium salt. Tn all cases iodides reacted about seven times more rapidly than bromides, and these about a hundred times faster than chlorides. It frequently happens that the same compound is formed quite rapidly in one way, and quite slowly or not at all in another way.° 1 Ber., 1874, 7, 1747; 8, 233, 936; Annalen, 1876, 180, 170. 2 Ber., 1875, 8, 49. 8 Ber., 1877, 10, 309. 4 Zeit. phys. Chem., 1895, 17, 191. 5 Of. also Proc. Chem. Soc., 1901, 17, 205. N2 180 ; REPORT— 1904. Wedekind ! compared the rate of formation of quaternary compounds from dimethylaniline and similar tertiary amines and various alkyl iodides. In all cases methyl, benzyl], and allyl iodides react much more rapidly than any others ; the order of their rapidity, however, depends on the amine used. This kind of effect is often attributed to ‘stereochemical obstruction ’ or ‘space filling,’ in the same way as the phenomena observed in the esterification of diortho substituted benzoic acids by V. Meyer. There is certainly an effect of this sort. Thus, for example, tribenzylamine, (C,H,);N, is capable of reacting with methyl iodide ; dibenzylaniline (C,H) (C,H;CH,)N is not ; and triphenylamine will not even react with hydro- chloric acid. Again, the halides of normal alkyl groups invariably react more rapidly than those of the corresponding iso groups. All the facts cannot, however, be accounted for in this way. On such a view iodides should react less rapidly than chlorides. Also Menschutkin ? finds that, whereas substitution of an alkyl group in the a position in pyridine, piperidine, or quinoline diminishes the velocity of reaction with alkyl bromides, the introduction of the same group in the / or y position increases the velocity. Much more work of a systematic kind is needed before any general conclusions on the subject can be drawn ; all that we can at present say is that the rate of formation of an ammonium compound depends both on the alkyl radicals already present in the amine, and also on that which is to be added on to it. (ii) Compounds of the Type Na,bX. The first experiments made on compounds having three radicals identical and one different were those of Meyer and Lecco already mentioned : a very large number of similar experiments have failed to produce isomerides of this type. Le Bel* found that the chloroplatinate of benzyl-triethylammonium hydroxide was the same whether produced from triethylamine and benzyl chloride or from benzyl-diethylamine and ethyl iodide, and similarly with that of trimethyl-propyl ammonium hydroxide or tripropylmethyl- ammo- nium hydroxide, whereas that of trimethyl iso-butylammonium hydroxide was found to exist in two different crystalline modifications, the one being anisotropic needles which readily changed into octahedra; the chloride of the same base also exhibits differences of a similar kind. Similar differences were observed by Le Bel* in the chloroplatinate of dimethylamine, and by Arzruni and others® in ethylamine hydrochloride, tetramethyl ammonium chloride, m-xylidine hydrochloride, tropidine chloroplatinate, and several other similar salts, Although the evidence is insufficient to show that these differences are not due to isomerism, it is highly probable that they are merely due to dimorphism. Messrs. Schryver and Collie® found that only one chloroplatinate of trimethyl-ethyl ammonium hydroxide, dimethyl] diethyl ammonium hydrox- ide, and methyl-triethyl ammonium hydroxide could be prepared. 1 Stereochemie des fiinf. Stickstoffes, 1899, 18. 2 Jour. russ. phys. Chem. Gies., 1902, 34, 411. 3 Compt. rend., 1890, 110, 145; 1891, 112, 725; Bull. Soc. Chem., 1890 [3], 4, 104. + Compt. rend., 1893, 116, 513. 5 Cf, Lehmann, Molecular Physik, vol. i. pp. 177, 539, 599; Zeit. Kryst., vol. iii. 16. 6 Proc. Chem. Soc., 1891, vii. 39. ON THE STEREOCHEMISTRY OF NITROGEN. 181 Professor Kipping observed a particularly interesting kind of isomerism among compounds of this type in which 6 and X both contain an asym- metric carbon atom.' This isomerism has now been very fully investigated in an admirable way by himself and his collaborators.” Externally compensated (d. /) a-hydrindamine when treated with d-brom-camphorsulphonic acid, with the corresponding chlor acid, or with cis x camphanic acid, was found to give rise to unequal quantities of two salts called the a and # salts, the 3 salt being that which is formed in smaller quantity. These salts differ in crystalline form, in amount of water of crystallisation, and often also in specific rotatory power ; these differences are not removed by recrystallisation from hot water, and both salts contain the inactive base. It is unnecessary to discuss the large mass of detailed work which has been done in the painstaking demonstration that only one explanation of this isomerism is possible : * a brief summary of the conclusions will suffice. It has been clearly shown that each of the two active hydrindamines, on combining with one of the above-mentioned acids, gives rise to two salts called ad and Sd and al and /3/ respectively, and that the original a salt obtained from the d-/ base is a mixture of ad and al in the form of a partially racemic compound, whereas the original 3 salt consists of a mixture of the two /3 salts or even of all four salts; in this case it is called a partially diracemic compound. In some cases there is a striking similarity between the ad and /3d or the a/ and {3 salts respectively, which may be isodimorphous and not completely separable by crystallisation. The molecular rotatory powers of the /3 series of salts in aqueous solution are frequently abnormal, which may be due to incomplete electrolytic dissociation or to activity of the nitrogen atom (see page 190). Evidence of a similar kind as to the existence of isomerides has been obtained for the brom-camphorsulphonates of benzylhydrindamine,! methylhydrindamine,* and /-menthylamine,® and for the chlor-camphor- sulphonate of d and/ methylhydrindamines,’ although in these cases it seems impracticable to isolate the salts free from their isomerides. The mandelates, tartrates, camphor-7 sulphonates, and camphor-a sulphonates (Reychler) of these bases do not exhibit the same phenomena : these salts appear to be homogeneous. This isomerism, though extremely important from a theoretical point of view, appears not to be of general occurrence. 1 Trans. Chem. Soc., 1900, 77, 861. 2 Trans. Chem. Soc., 1903, 83, 873, 889, 902. % Trans. Chem. Soc., 1903, 88, 937, 1147. + Trams. Chem. Soc., 1901, 79, 430. 5 1903, 83, 918. 6 1904, 85, 65. 7 Tattersall, 1904, 85, 169 182 REPORT—1904. (iii) Compounds of the type Nabe X. Messrs. Schryver and Collie! prepared the chloroplatinate of methyl- diethyl-isoamylammonium hydroxide from the iodides formed in the three possible ways, and found that when the processes were carried out in the cold, two crystalline modifications were obtained, an oblique and a pris- matic, the former of which was unstable and readily passed into the latter. This difference might easily be due to dimorphism, as in the case of the compounds of the type Na,6 X. The writer’ investigated the formation in two different ways of a number of compounds with two identical radicals, and found that even when the reaction was carried out in the cold, the products obtained were in all cases the same. In a few instances the crude compounds differed to a slight extent, and one might even be gummy while the other was deposited in a crystalline state ; these differences always disappeared when the substances separated from solutions. The d-camphor sulphonates prepared from both products were the same. All attempts to get isomeric piperidinium salts have also been unsuc- cessful. Thus Menschutkin* found that ethyl-allyl-piperidinium iodide produced in the two possible ways was the same and so also was the chloroplatinate. Miss de Brereton Evans‘ obtained only one form of ethyl-propyl-piperidinium iodide, the crystals of which, however, showed enantiomorphism, and Wedekind’ obtained only one form of benzyl- piperidinium iodide, methyl- and ethyl-acetates, and the corresponding bromides Aschan ® has investigated dipiperidinium derivatives, and though he obtained only one form of N.N. ethylene dipiperidinium dimethy] diiodide and the corresponding dibenzy] dichloride, found that two isomerides of ethylene-propylene dipiperidinium dibromide and of ethylene-trimethylene dipiperidinium dibromide and diiodide’ seem to exist. The first of these compounds contains an asymmetric carbon atom : OH. CH) +1: CHs—CHs;. CH,..CH, oon Pine Tis yee CH, CH, _C H——CH,| CH, CH, Mae Br CH, Br whereas the others do not: CH, CH, CH, CH, CH, CH, ares “e be Retiee eA Now OBS ¥ LY as CH, CH, | CH,—CH,—CH,| CH, CH, Br Br ! Proc. Chem. Soc., 1891, vii. 39. 2 Proce. Camb. Phil. Soe., 1901, 11, 111; Trans. Chem. Soc., 1903, 88, 1400. ® Zeit. phys. Chem., 1895, 17, 228; Ber., 1895, 28, 404. 4 Trans. Chem. Soc., 1897, 71, 522. ; 5 Stereochemie, 58. © Bev., 1899, 82, 988; Zeit. phys. Chem., 1908, 46, 304. 7 Loe, cit., 306. ON THE STEREOCHEMISTRY OF NITROGEN. 183 So far only a brief statement concerning these compounds has been made, and no full description of their properties or crystalline form has been given. The isomeric bromides differ in solubility in dilute alcohol (5:4 and 8-2) ; the iodides in solubility in water and also in their temperature of decomposition. With the exception of these compounds described by Aschan, which, as will be seen later, must show isomerism, whatever view of their con- figuration and mode of formation be adopted, no compounds of the type under discussion have been shown to exist in isomeric forms, and it may therefore be concluded that under normal conditions stable isomerides cannot exist, the limit of ‘space-filling’ having been very nearly reached in some of the compounds used by the writer. iv) Compounds of the type NabcdX. ip y No systematic efforts had been made to obtain isomerides of com- pounds of the above type before Wedekind’s experiments were undertaken. Wedekind argued, from the experiments of Messrs. Schryver and Collie and others, that the groups in ammonium compounds were mobile, and that therefore isomerism could only exist when heavy groups were used and when the limit of ‘ space-filling’ had nearly been reached. The formation of phenyl-ethyl-methyl-allyl ammonium iodide in the three possible ways,! namely (a) combination of methyl-ethyl aniline and ally] iodide, (0) allyl-ethyl aniline and methyl iodide, and (c) allyl-methyl aniline and ethyl iodide, showed that only one product was obtained, though in the first case the compound was at once deposited in a crystalline state ; whereas the other two combinations gave an amorphous product which readily became crystalline on rubbing or on separating it from solution. Similar phenomena were observed by the writer in the formation of phenyl-benzyl-ethyl-methyl ammonium iodide.? The union of benzyl iodide with ethyl-methyl aniline took place very readily and yielded a gummy solid which, on separating from solution, became crystal- line and identical with that obtained by the addition of methyl iodide, or of ethyl iodide to the corresponding tertiary amines, which was crystalline from the first. The phenomena observed by Wedekind in the phenyl-benzyl-allyl- methyl ammonium salts? are, however, of quite a different kind. This compound was prepared by the union of (a) allyliodide and methyl-benzy] aniline, (b) methyl iodide and benzyl-allyl aniline, and (c) benzyl iodide and methyl-allyl aniline. Combinations (a) and (c) take place readily and give rise to the same product, the a compound, which crystallises in the prismatic system, melts at 140-142° C., and distils partly unchanged under reduced pressure. Combination (b) takes place very slowly and gives an oily product which is induced to erystallise only with great diffi- culty and yields a very small quantity of a crystalline solid, the /? com- pound. This compound crystallises in a different form (also of the prismatic system), melts at 158-159° C., and distils unchanged under reduced pressure without melting. The «a and 8 compounds could not be transformed one into the other. Isomeric a and (3 chlorides and bromides were also prepared, which ! Stereochemie, 53; Ber., 1903, 36, 3791. 2 Trans. Chem. Soc., 1904, 85, 224. 3 Stereochemie, 33-52; Ber., 1899, 32, 517, 3561 184 REPORT—1904. differed in a similar way to the a and # iodides. Hantzsch and Horn ! prepared the a and / iodides and made experiments to exclude the possi- bility of structural differences. Both iodides react as unsaturated bodies toward alkaline permanganate, and on oxidation give formic acid,which facts show that both are allyl compounds. The writer has compared the properties of the 4 compound with those of phenyl-methy1l-benzy]-propy] and zsopropyl ammonium iodides, and found that it differs from both in melting-point and crystalline form, though in the latter particular it has a slight resemblance to the zsopropyl compound. No other case of a similar kind has been found, though Wedekind was deceived by abnormal reactions into thinking that there were isomerides of some other compounds. Thus the addition of allyl bromide to benzyl isobutyl-N-methyl-acetate and of methyl-brom-acetate to benzyl-allyl- isobutylamine gave rise to different products, the latter of which was subsequently found to be a mixture. Methyl-allyl-tetrahydroquinolinium iodide? prepared in two ways was the same, and so with ethyl-benzyl-zsotetrahydroquinolinium iodide.* The tetrahydroquinolinium derivatives produced by the addition of methyl] iodide and of methyl- and ethyl-iodo-acetates to the corresponding tertiary tetrahydroquinoline compounds and which were at first thought to be isomeric * were afterwards ° found not to have the same composition. Methyl] tetrahydroquinolinium N-methyl- and ethyl-acetate iodides were produced by the first method, but the second gave a mixture of these with kairolin hydriodide. similar tetrahydroisoquinoline compound was obtained in one form only. Wedekind has also studied the formation of compounds in which two asymmetric nitrogen atoms are present.’ Ethylene dikairolinium di- iodide was prepared in two ways and found to be the same; ethylene ditetrahydroquinolinium di-ethyl-acetate di-iodide, however, appears to be different when prepared in the two possible ways ; the specimen formed by the addition of iodo-acetic ester melts at 164-165° C., whereas that formed by the addition of ethylene di-iodide melts at 50° C., with elimination of one molecule of iodo-acetic ester. The analyses of these compounds are, however, insufficient to prove identity, and it is possible that one of them is a mixture. Wedekind examined the stable compound to ascertain if it was homo- geneous, and decided that it was. Hence, the analogy between asymme- tric nitrogen and carbon does not seem to hold here—namely, that, when two asymmetric atoms are produced, all four possible compounds should also be produced and combine in pairs to give externally compensated compounds separable by crystallisation. (v) Optical Activity of Substituted Ammonium Compounds. It was expected from analogy with carbon compounds that quinque- valent nitrogen compounds, N ab cd X, would exist in optically active forms, and repeated attempts were made to prepare such compounds before definite success was attained. Le Bel® submitted dilute aqueous solution of various salts of the type, 1 Ber., 1900, 35, 883. 2 Stereochemie, 75; loc. cit., 63. 8 Ber., 1901, 34, 3986 4 Stereochemie, 66. 5 Ber., 1902, 35, 178. 5 Ber., 1903, 36, 1158. 7 Ber., 1903, 36, 1165, 3796.8 ® Compt. rend., 112, 724. ON THE STEREOCHEMISTRY OF NITROGEN. 185 Na, b c X, and also two of the type, N abcd X—namely, methyl-ethyl- propylamine hydrochloride, and methyl-ethyl-propyl-isobuty] ammonium chloride—to the action of Penicilliwm glawewm. In the last case only the solution acquired a small but fugitive rotatory power of 0°4°-0-5°; the absence of activity in the other case was attributed to mobility of groups. This result has been contradicted by Marckwald and Droste-Huelsdoff,! but reaffirmed by Le Bel, with the addition of further details.” Wedekind * made several unsuccessful attempts to resolve the a phenyl- benzyl-allyl-methyl ammonium iodide, which was successfully resolved by Messrs. Pope and Peachey ‘ by crystallising the camphorsulphonate from non-hydroxylic solvents (acetone and ethyl acetate). The active com- pounds were then more fully investigated by Messrs. Pope and Harvey.’ The d-camphorsulphonate of the d-base had the molecular rotatory power M]p>=218° in dilute aqueous solution, the corresponding J/-1 salt had M]|>= —211° and the iodides had [M],, about + 200° in chloroform. The writer® also succeeded in resolving phenyl-benzyl-ethyl-methyl ammonium iodide in a similar way. The d-d and /-1 camphorsulphonates had [M]=+71°. The difference between the values of [M], for the basic ions in these two cases, namely 160° (approximately), and 19°5° caused by the replacement of the allyl by the ethyl! radical, is remarkable. A number of other active compounds are now being examined by Miss M. B. Thomas and the writer with a view of investigating the effect of substitution on the rotatory power. In the series containing the radicals phenyl, benzyl and methyl with propyl, isopropyl, isobuty1, and isoamy] the rotatory power appears to increase with the molecular weight of the last- mentioned radical, and in the last case far exceeds that of the allyl compound. That the resolution of ammonium compounds does not always take place so readily as in the first case examined is evident from the writer’s experiments,’ and the unsuccessful attempts of Wedekind® to resolve p-tolyl-benzyl-allyl-methyl ammonium d-camphorsulphonate, a salt very similar to that first resolved. So far no cyclic ammonium compounds have been resolved, though both « and (3 substituted pyridinium and piperidinium derivatives, and tetrahydroquinolinium compounds should be capable of giving rise to optical activity.° All attempts to obtain optically active compounds of the type Na, bc X have also been unsuccessful. Thus the writer ‘° examined a number of such compounds, Messrs. Kipping and Barrowcliff ! examined some piperidinium compounds, and Aschan !? tried to resolve the N-N ethylene-trimethylene dipiperidinium compounds, though not in an entirely satisfactory way, but in no case was there any indication of activity. Itis probable that all such compounds are planisymmetric, and therefore incapable of giving rise to optical activity. 1 Ber., 1899, 32, 560. 2 Compt. rend., 129, 548. 3 Stereochemie, 82. 4 Trans. Chem. Soc., 1899, '75, 1127. > Trans. Chem. Soc., 1901, 79, 828. ® Trans. Chem. Soc., 1903, 83, 1418 ; 1904, 85, 223. 7 Loe. cit., 1405. 8 Zeit. phys. Chem., 1903, 45, 235. ® Trans. Chem. Soc., 1903, 88, 1415. 10 Loc, cit., 1903, 88, 1406. Cp. also Harvey, Trans, Chem. Soc., 1904, 85, 412. Loe. cit., 1903, 88, 1141. 12 Loc. cit. 186 REPORT—1904. (vi) Compounds containing Asymmetric Carbon and Nitrogen Atoms. The examination of these compounds was undertaken with a view of establishing another analogy between asymmetric carbon and nitrogen atoms, and it has been shown! that when an active tertiary amine (methyl [amyl aniline) combines with an alkyl iodide (allyl or benzyl iodide), unequal quantities of the two possible compounds are produced as anti- cipated if the nitrogen behaved like a carbon atom. The two compounds formed with benzyl iodide differ somewhat in their solubility, but not enough to make a complete separation by crystallisation feasible : this can be effected by means of the camphor- sulphonates. One of the iodides is dextro- and the other is levo-rotatory ; a solution of either in chloroform in the cold or in alcohol on warming becomes converted into the other until a state of equilibrium is reached, the change from one isomeride to the other being effected by the splitting up of the salt into benzyl iodide and amine, which then recombine, as in the racemisation of active nitrogen compounds in chloroform solution. (vii) The Configuration of Quinguevalent Nitrogen Compounds. (a) A fixed Configuration necessary.—The foregoing results demand a stable configuration for the molecule of ammonium compounds, in which the nitrogen atom is quinquevalent, and is attached to five univalent atoms or groups. Werner ? still adheres to a modification of the old ‘ molecular compound hypothesis’ to account for the ammonium compounds, and regards the existence of isomerism and optical activity as an objection to the view generally accepted. Dr. J. C. Cain takes the same point of view, regards the stability of the ammonium compounds towards alkalies as a further objection, and proposes a new hypothesis in which ammonium chloride is represented as H;N=CI—H. Two of the numerous important objections to this view may be mentioned: first, there is not enough evidence to show that compounds with the structure usually assigned to ammonium salts would not be stable, and still less for concluding that tervalent halogen derivatives would be stable; and, secondly, the formule proposed to account for the isomeric hydrindamine salts— namely, a,N=X—b and a,.5N=X—a—do not account for the mode of formation of these salts, and the formule proposed for active nitrogen compounds—namely, bedN=X—a—and acdN=X—b—are not optical antimers, and could not by a single process be produced together in equal quantities. Five points cannot be arranged symmetrically around one point so as to be interequivalent ; hence either one or two of the valencies of nitrogen must be different from the others : this conclusion finds expression in all the configurations proposed, and is supported by the facts. It has been found impossible to prepare a quinquevalent nitrogen compound contain- ing no electro-negative radical nor one containing more than two such radicals.4 (b) Lhe ‘ Cubie Configuration.’—The first configuration proposed was 1 Jones, Proc. Camb. Phil. Soc., 1904, xii. 466. 2 Annalen, 1902, 322, 261. 3 Memoirs of the Manchester Lit. and Phil. Soc., 1904, 48, No. 14. + Lachmann, American Chem. Jowrn., 1896, 18, 372. ON THE STEREOCHEMISTRY OF NITROGEN. 187 the ‘cubic’ one suggested by van’t Hoff in 1878,! in which the nitrogen atom is supposed to be at the centre of a cube and the five groups at five corners, thus : The disposition of the valencies would have to be altered to meet the requirements of recent experiments. The number of isomerides required by this configuration is usually larger than by some of the others on account of the lower degree of symmetry which it possesses, and, since it has no special advantages, little use has been made of it. (c) The ‘ Double Tetrahedron’ Configuration.—The next configuration which was proposed is usually called the ‘double tetrahedron’ configuration and associated with the name of Willgerodt.2 According to this view it is assumed that the two new groups are attached at right angles to the plane of the three already present, thus giving rise to an arrangement like a double tetrahedron. This arrangement has the highest degree of symmetry Fi4, 2. 4 > of any ; it requires the existence of (1) two isomerides of the type Na,X— namely, those in which a and 6 respectively occupy one apex while X occupies the other ; (2) three isomerides of the type Na.bcX, one of which should exist in optical antimers ; and (3) four isomerides of the type NabedX, all of which should exist in optically active forms. » Ansichten tiber Org. Chem., i. 80. 2 Journ. prakt. Chem., 1890, 41, 291. 188 REPORT—1904, (d) The ‘ Pyramidal’ Configuration—Behrend! discussed other possible arrangements of the five groups, and Bischoff” proposed the ‘ pyramidal’ configuration in which the five groups are supposed to be situated at the angular points of a pyramid on a square base, the acidic radical occupying the apex thus : Fig. 3. 5 LOUD. oy aa 1 4 Considering this arrangement as originally suggested we should expect (1) no isomerides of the type Na,bX ; (2) two isomerides of the type Na,beX, one of which would be capable of existing in enantiomorphously related forms ; and (3) three isomerides of the type NabcdX, all of which should be capable of existing in optically active forms. It is evident, however, that this view must be modified somewhat, for, since it does not represent the three groups in tervalent nitrogen compounds in one plane, there are three possibilities : (a) a change of valency direction occurs ; (2) the acidic radical does not occupy the apex (this assumption increases the number of possible isomerides very con- siderably) ; (c) an interchange of position between two groups occurs during the change of valency. It is desirable to avoid the first assumption, if possible ; the last two have been made by Professor Kipping to account for the isomerism of the hydrindamine salts, and will be discussed in detail. (e) Only the Pyramidal Configuration accounts for the Facts.—To decide between these various views we have the following facts which must be accounted for : (1) The existence of stable, optically active compounds. (2) The existence of the isomeric hydrindamine salts. (3) The existence of isomerides of the type Na,bcX only in the case recorded by Aschan, and the optical inactivity of all these compounds. All the views account for (1), but the ‘double tetrahedron’ configura- tion does not account for (2), since both the new groups introduced during the change of valency are situated in the same plane symmetrically with reference to the existing groups, and are interchangeable by rotation.* 1 Ber., 1890, 28, 454. 2 Ber., 1890, 23, 1972. 8 See Trans. Chem. Soc., 88, 949. ON THE STEREOCHEMISTRY OF NITROGEN. 189 This configuration may therefore be left out of consideration, and since the ‘cubic’ has no advantages and some disadvantages, we shall confine ourselves to the ‘ pyramidal,’ which may conventionally be represented as a plane projection. 7 TEES The way in which this configuration can be made to account for (2) and (3) has already been discussed.! The argument, therefore, need only be briefly stated. In order to account for the existence of isomeric hydrindamine salts it is necessary to make one of two assumptions (5) or (c) (above) as to the manner in which the two new radicals, H and X, are attached to the amine, all three groups in the latter being in one plane with the nitrogen atom. First H and X may be placed at the two unoccupied positions at the base of the pyramid, the asymmetric group (a) being also at the base (since if it occupy the apex no isomerism arises) ; the two salts would be thus represented : m@ fom c Fig. 5. FIG. 6. He H x S< i >< a x a H This assumption requires that the compound produced by the com' bination of aX and N a 6 ¢ should have one of the configurations, Figs 7%. Fig. 8. Dd - Dd which are enantiomorphously related and should be optically active. This expectation cannot be experimentally realised. 1 Trans. Chem. Soc., 88, 1404. 190 REPORT—1904. Secondly, it is assumed that, addition having taken place as before, the radical X then changes its position with the hydrogen atom at the apex of the pyramid, thus giving rise to a compound with the con- Fig. 9. ZN, figuration (fig. 9) which would be one of the isomerides, while the untrans- formed addition product would be the other (fig. 5 or 6). On this view one isomeride (the untransformed product) is devoid of a plane of symmetry, whereas the other is planisymmetric, one should therefore have an activity due to the nitrogen atom, and this might account for the abnormal rotatory power of the salts of the £ series. This view will account (a) for the existence of one isomeride of Na,bcX and its optical inactivity, since the original addition product (fig. 10) changes Fi@g. 10. Fie. 11. x x a into a planisymmetric compound (fig. 11), and (6) for the inactivity of piperidinium compounds, which would be represented thus: Fia. 12. Fig. 13. b CH, b CH, \CH, “\CH2 : : CH Xx CH3— a | CH>----------- 4CH2 CH}----------- SoH, the plane of the piperidine ring being supposed perpendicular to the plane of the paper. A difficulty arises with regard to compounds of the type, NabedX, since they can be represented as giving rise to isomerides or not, accord- ing to the position which the new radicals are supposed to take up with reference to those already present. ON THE STEREOCHEMISTRY OF NITROGEN. 191 Since, in general, no isomerism arises, the process probably takes place as follows : Fig. 14. Be SN (abeN +dX) (adeN +X) giving rise to the same product. But in one case at least—namely, that of the a and £ phenyl-benzyl- allyl-methyl ammonium salts—different products are formed. It is true that the untransformed addition product might be expected to be an isomeride, as in the case of the hydrindamine salts, even in compounds of the type N a,bX and Na,bcX, and this may account for the labile amor- phous products observed by Wedekind and the writer in some instances. Such instances are, however, of quite a different order to the stable isomerism of the a and f phenyl-benzyl-allyl-methy] ammonium salts ; our knowledge is unfortunately insufficient to enable us to form any idea of the reason for the unique position of those salts, and the following suggestion as to their mode of production is simply tentative. Since they are both stable it is better to regard these both as transformed products which might arise thus : Fig. 15. De ; DX Hy Ne Dé} H, a ern. OH,N 40.111) (C,H;.C,;H,;.CH,N + C,;H,I) The benzyl and allyl groups are regarded as the ones which inter change their positions with the iodine atom to form the a compound. The 3 compound might arise thus : Fie, 16, C3Hs pe<[- aes CeHs CgHs C7H7 (C,H;.C,H,.C,H,N + CH,I) The benzyl radical] is regarded as more mobile than the allyl, which is in accordance with observation. In all these cases the addition of the 192 REPORT—1904. alkyl and acidic radicals in both the possible positions gives rise to a mixture of optical antimers. The isomerism observed by Wedekind in the diquinolinium compounds if established by further work is readily accounted for, since it would be expected that mobility would be diminished in these cases. Two exter- nally compensated compounds ought to be produced, but since the pro- duct was apparently homogeneous, the two compounds must either be extremely similar or one of them must be formed in extremely small quantities, as in the case of the mannose cyanhydrins. The existence and properties of the isomeric ethylene-trimethylene dipiperidinium dibromides discovered by Aschan are readily accounted for by any one of the proposed configurations, though Aschan himself says : ! ‘Das von van’t Hoff mit dem gewohnten Scharfsinn dieses Gelehrten vorgeschlagene Modell fiir den pentavalenten Stickstoff ist die einzige mir bekannte, welche die Existenz und Inaktivitaét der beiden untersuchten Dipiperidid-Dibromide erkliren kann.’ With the aid of the pyramidal configuration these isomerides would be represented thus : Fie. 17. Formed by the addition of trimethylene dibromide to ethylene dipiperidide : Fig. 18. Formed by the addition of ethylene dibromide to trimethylene dipiperidide : oan CH eG CH> CH2s__ , CHa CH3-~-.> CHa Che As CH3-"" _-°CHo Che “CH Interchange of positions between the bromine atom and one of the chains forming the central ring is not possible without almost complete disintegration of the molecule, and is improbable for other reasons, so that each bromine atom occupies a position at the base of the pyramid. The planes of the piperidine rings are in each case represented as perpendicular to the plane of the paper ; each compound has thus a plane of symmetry in the plane of the paper and would be optically inactive. Hence, the ‘ pyramidal’ configuration of Bischoff, with the assumptions made as to the mode of formation of ammonium compounds from amines, 1 Toe. cit., 318. ON THE STEREOCHEMISTRY OF NITROGEN. 193 is capable of accounting forall the observed phenomena. There are, how- ever, a number of problems which still remain to be solved, notably, the investigation of the conditions which determine the stability of isomeric compounds such as the hydrindamine salts. Notr.—Since the above was written Wedekind and Oberheide have studied the question of isomerism in the paratoluidine series.! p-tolyl- methyl-ethyl-allyl ammonium iodide was produced in two ways, and p-tolyl-methyl-allyl-benzyl ammonium iodide was produced in three ways. In this case the stable isomerism observed in the corresponding phenyl compounds does not arise, and renders this still more difficult to under- stand. These compounds, too, have resisted all attempts to resolve them into their active constituents. Dynamic Isomerism. By 'T. M. Lowry, D.Sc. [Ordered by the General Committee to be printed in extenso. | PAGE I. Introductory and Historical . : , : : . . : . 193 Il. Lhe Nature of Dynamic Isomerism . : 2 2 7196 Ill. Zsomeric Changes in which Two Radicles are A i nterchanged é - 200 IV. Zsomeric Changes in which a Single Mobile Radicle is Transfer red . . 204 V. Optical Inversion ‘ - . 3 A . 211 VI. Chemical Properties of Dynamic Tromarides : 5 F : . 214 VIL. Physical Properties of Dynamic Isomerides ; i : “ - 3 2G VIII. Reversible Polymeric Change . ° . 3 “ 5 - - . 223 I. Introductory and Historical. Berzelius.—Almost simultaneously with the discovery of isomerism the fact was recognised that isomeric compounds were sometimes capable of being converted into one another: in fact Berzelius, who in 1831 had introduced the term isomeric to express the relationship between tartaric and racemic acids, found it necessary in the following year to introduce the term metameric in order to distinguish those isomerides which differed in type and were on that account easily convertible into one another.” Berzelius’ conception of metameric compounds is very similar to that which forms the subject of the present report, which deals with the phe- nomena of dynamic isomerism or equilibrium between isomers. Liebig and Wéohler.—Of the two examples quoted by Berzelius, one (the isomerism of stannous sulphate, SnSO,, and basic stannic sulphite, SnOSO,) has not been realised, and the other (the supposed isomerism of cyanic and cyanuric acids) has proved to be an example of reversible polymeric change. The conversion of ammonium cyanate into urea, discovered by Liebig and Wéhler in 1828, is the earliest example of the type pictured by Berzelius. It is of interest to note that the first organic synthesis was effected with the aid of the first isomeric change. Butlerow.—Little progress was made in the study of dynamic isomerism until the doctrine of valency rendered possible the modern development of structural chemistry. In the modern period the first and most important contribution to the theory of dynamic isomerism is to be 1 Ber., 1904, 37, 2712. 2 Full quotations are given in Professor Armstrong’s article on ‘I omerism,’ Morley and Muir’s edition of Watts’ Dictionary of Chemistry. 1904, ) 194 REPORT—1904. found in Butlerow’s paper ‘Ueber Isodibutylen,’’ a paper which is remarkable in that it anticipated by a quarter of a century the views that are generally held at the present day. Butlerow’s experiments showed that in presence of sulphuric acid equilibrium is established between the two olefines and the two isomeric alcohols formulated below, so that on oxidising with chromic acid products were obtained characteristic of each of these four substances :— CH, eis 01 2 ik 0: ip Mey bss ay 91 CH, CH, CH, goa’ 4 sf, a vA a Sit CH C C(OHS C | sree dine sls encaros bas ate es ecgegy CH, ersgoeiicaeh 6) canada 6s: esiaietiemebeleieags 2 | | | i CMe, CMe, CMe, CMe, In no previous case had the existence of a reversible isomeric change been demonstrated, and Butlerow fully realised the importance of his discovery. At the end of his paper he suggested that a similar equilibrium between isomers might exist even in the absence of any special catalytic agent and that this would account for the formation of isomeric ethers from prussic acid GHC. iNet BE GoM eet Bs 8 5 ioe CsH,.N 36 : — __~_ ethyl cyanide prussic acid ethyl isocyanide and for a number of other abnormal changes. Subsequent investigations have fully demonstrated the correctness of Butlerow’s theory since reversible isomeric changes have been found to be of frequent occurrence, especially amongst the ketones and nitro- compounds. Isomeric change not spontaneous.—The only important modification of Butlerow’s theory that has taken place depends on the proof that has recently been given? that even the most easily convertible compounds do not change spontaneously but that in all cases a catalytic agent is necessary for the establishment of equilibrium. The necessity for a third substance in order to bring about chemical change has been per- sistently advocated by Armstrong and has been demonstrated experi- mentally by Dixon, Baker and others in the combustion of carbon monoxide and phosphorus, and in the union of hydrogen with oxygen and with chlorine. Baker has further demonstrated the remarkable fact that moisture is necessary not only for the (apparently direct) union of ammonia and hydrogen chloride, but also for the dissociation of ammonium chloride, which cannot be decomposed by heat alone. Recent observations have extended the proof to the reversible isomeric change of nitro- camphor and £-bromonitrocamphor and it has been found that even the transference of a mobile hydrogen atom cannot take place within the molecule, but is dependent on the formation of a complex molecular circuit. It is therefore impossible to maintain any longer a distinction between those isomerides which are only convertible in presence of a specially added catalytic agent and those which find in the ordinary dirt of the laboratory the catalytic agent that they need and which therefore appear to change spontaneously. 1 Ann. 1877, 189, 44. 2 Lowry, Zrans. 1899, 75, 219. ON DYNAMIC ISOMERISM. 195 Abnormal Chemical Changes explained by Butlerow’s Theory.—Simul- taneously with the development of the theory of dynamic isomerism a large number of observations were being made which have only found a satisfactory explanation in the fully developed theory. The formation of two series of ethers from prussic acid was explained by Butlerow in 1877. Baeyer in 1883 was able in a similar manner to account for CO CO aa EN PAGER the existence of isomeric ethers C,H, CO and C,H, C.OEt os NEt of isatin by supposing that one of them was derived from a labile pseudo- isatin which was converted into ordinary isatin whenever attempts were made to prepare it :— co co A \ C,H, CO or C,H, CoH EY Oa oc 4 NH N In the same way it is easy to account for the apparent identity of nitroso- phenol and quinoneoxime by supposing that one of these compounds undergoes isomeric change in the course of preparation : _> ON.C,H,OH or HON: 0,H,: 0. <_—— Laar’s Theory.—In his paper, ‘ Ueber die Méglichkeit mehrerer Struk- turformeln fiir dasselbe chemische Verbindung,’ Laar, in 1885, rendered an important service by calling attention to the existence of a large number of facts of this kind. Unfortunately he rejected the explanation given above and put forward in its place his theory of tautomerism. According to this theory the product obtained by the action of nitrous acid on phenol, or of hydroxylamine on quinone, has actually not one but both of the alternative constitutions formulated above, the hydrogen atom oscillating between the two positions indicated in the formula CH CH cH cH CN iy 7O0C POET O19 VE OY in a manner comparable with the vibrations that give rise to light. The incorrectness of Laar’s theory was proved when, in 1895 and the years immediately following, it was found that the isomeric forms of several ketones and nitro- compounds could be isolated in the solid state and were only slowly converted into one another. The necessity for a catalytic agent has also shown that the oscillation of the hydrogen atom is not an intramolecular process but, like other chemical changes, can only take place within a complex molecular circuit. The distinction between the two theories is of importance at the present time, because it is not inconceivable that tautomerism may actually exist as an intramolecular phenomenon, though all the cases to which the term has hitherto been applied:appear to be examples of dynamic isomerism. 02 196 REPORT—1904. Physical Phenomena explained by Butlerow’s Theory.—In addition to affording an explanation of many puzzling chemical changes the theory of dynamic isomerism has proved exceptionally fertile when applied to physical phenomena. Thus the gradual change of rotatory power which takes place in freshly prepared solutions of many of the sugars was observed as long ago as 1846 but has only recently been shown to be due to the establishment of equilibrium between isomeric forms of the sugar. The formation of violet salts from colourless violuric acid, of red and yellow salts from colourless p-nitrophenol and of highly dextro-rotatory salts from levo-rotatory nitrocamphor are due to similar changes or structure. Again there is good reason to suppose that many of the phenomena of luminosity are dependent on reversible isomeric change or on the analogous reversible changes involved in association and dissociation. This is almost certainly true of the fluorescence and phosphorescence or organic compounds and there is reason to think that the flash of light emitted when crystals of sugar or saccharin are crushed is also a mani- festation of isomeric change.! The bearing of Dynamic Tsomerism on Chemical and Physiological Changes.—The mere presence of the mechanism necessary for dynamic isomerism appears to facilitate chemical change and in many cases it is probably an essential factor. Thus Lapworth has recently shown? that the bromination of acetone is dependent on the presence of a minute amount of the enolic form, the ketone itself being apparently unacted on by the halogen. A similar explanation may be given of the great activity of phenol and aniline as compared with benzene and of the inhibiting influence of ortho- substitution. In this connection it is of interest to note that the most important natural organic materials, such as the sugars and the albuminoids, are very rich in those plastic groups which most frequently give rise to dynamic isomerism and to this fact their great activity may at least in part be attributed. Il. The Natwre of Dynamic Isomerism. 1. Definition. Under the heading of dynamic isomerism are included all those cases in which it is possible to establish a condition of equilibrium between isomers. It may also be defined as a condition of reversible isomeric change.? But if this definition is used it must be remembered that reversal is largely a matter of conditions and that all isomeric changes are probably accompanied by a certain amount of back-action, even though this may be too small to be detected by the methods commonly used. 2. Equilibrium between Isomers is only possible in presence of a third substance.—Proof of this was first obtained in the case of nitro- camphor,‘ solutions of which in chloroform could sometimes be kept for two or three weeks without undergoing change, although usually sufficient impurity was present in the solution to bring about equilibrium between the normal and pseudo forms in the course of a single week. CH.NO C: NO.H STEN ay Re: Be ae rg > Cae * [18 0 [82 %] 10 M\ co s 10 do [ %] Normal nitrocamphor Pseudo-nitrocamphor 1 Armstrong and Lowry, Proc. Roy. Soc. 1903, 72, 258. = Trans. Chem. Soc. 1904, 85, 30. 3 Lowry, Trans. 1899, 75, 235. + Lowry, ibid, p. 220. ON DYNAMIC ISOMERISM. 197 Similar observations have been made by Forster,! who found that a solution in chloroform of enolic a-benzoyleamphor could be ‘ preserved in darkness during twelve hours, exposed to bright sunlight during two hours and even sown with a crystal of the ketonic isomeride’ without undergoing change ; usually, however, six days were sufficient to bring about the condition of equilibrium indicated in the equation /PH COC Hs C.CO.C,H [39 %) aah oh = aE Se De at [61 %)- More recently it has been found possible to prepare solutions in benzene containing a mixture of normal and pseudo £-bromonitrocamphor which could be kept unchanged during several days in a graduated flask, but reached a condition of equilibrium in a single day when brought into contact with the softer glass of a polarimeter tube.? Of themselves, there- fore, these isomerides are as stable as, for instance, are ethyl alcohol, CH;.CH,.OH, and methyl ether, CH;.0.CH;, or methyl acetate, CH;.CO.0.CH;, and propionic acid, CH;.CH,.CO.OH; but unlike these latter substances they become isodynamic in presence of an almost incon- ceivably minute amount of impurity. The addition to a solution of nitrocamphor in benzene of 0:0001 per cent. of piperidine is sufficient to - establish equilibrium in two or three hours. 3. An Lonising Solvent may promote Isomeric Change.—-Although in the cases described neither benzene nor chloroform is capable of bringing about isomeric change, it is possible that an ionising solvent may act as the necessary ‘third substance.’ The isomeric change of nitrocamphor is accelerated to some extent by acids as well as by alkalies, and in ionising solvents the change is very rapid even when purified material is used ; as pseudo-nitrocamphor is itself a strong acid it may well act under these conditions as a catalytic agent. In the case of aqueous solutions of glucose quantitative measurements have shown that the isomeric change cannot be ascribed to acid or to basic impurities, whilst neutral salts retard rather than accelerate the change ; the effect appears, therefore, to be produced directly by the solvent, assisted, perhaps, by the feebly acid properties of the glucose itself.? 4. Many substances only become Isodynamic at High Temperatures cr in presence of a special Catalytic Agent.—Whilst it is now recognised that the changes which Butlerow regarded as spontaneous are actually brought about by a trace of acid or alkaline impurity or by an ionising solvent, there are many substances which, like the isodibutylenes, only become isodynamic under somewhat special conditions. Thus many sulphonic acids, like Butlerow’s olefines, become isodynamic when dissolved in con- centrated sulphuric acid ; again where isomeric change involves the trans- ference of an alkyl group, it may often happen that an alkyl iodide or an aluminium haloid is the only efficient agent. Apart from their great scientific and commercial importance these cases of dynamic isomerism are of interest as enabling isomerides to be directly balanced against one another of which the relative stability could otherwise be determined only indirectly from the heats of combustion. In other cases a reversible isomeric change appears to set in spontaneously when the temperature is 1 Trans. 1901, 79, 999. 2 Lowry, Proc. 1903, 19, 131. 8 Lowry, Zrans. 1903, 88, 1314. : 198 REPORT—1904. raised. A high temperature can scarcely do more than increase the activity of the impurities present in the material but these may easily be introduced at high temperature owing to incipient decomposition or to action on the walls of the containing vessel. 5. Equilibrium is determined by the Velocities of Isomeric Change in opposite directions.—The proportions of the isomerides in the ultimate mixture is determined by the ratio of the velocities with which they undergo isomeric change under the given conditions. If these velocities are equal there will be 50 per cent. of each isomeride, but if one undergoes change ninety-nine times as fast as the other, there will only be | per cent. of it in the mixture. ‘Complete’ isomeric changes are merely limiting cases in which one velocity is small compared to the other, and as it is difficult to detect a back action in which the ratio of the velocities is greater than 100 to 1, the distinction between complete and incomplete changes is of very small importance. It may be added that solids are usually incapable of undergoing isomeric change but if such a change should occur (owing, for instance, to incipient fusion or to the presence of a trace of solvent), it is usually complete, back action being possible only in the liquid or gaseous state. Thus Walker and Hambly ' have shown that the conversion of ammonium cyanate into urea, which is complete when the solution is evaporated to dryness, is reversible in solution. In a normal solution at 59-6°, 14:4 per cent. of ammonium cyanate undergoes isomeric change in a minute, and 0:0038 per cent. of urea. Equilibrium is reached when there is 5 per cent. of cyanate and 95 per cent. of urea, as indicated by the equation [5 %] NH4.0.0 N 2 CO(NH,), [95 %]. The concentration of the ammonium cyanate is then only N/20, and its velocity of change is reduced to half that in normal solution. Equi- librium is reached when the ratio 95/5 of the concentrations is equal to the ratio 7:2/0-0038 of the velocities of change in opposite directions.” Ammonium cyanate changes slowly in aqueous solutions at ordinary temperatures ; at 100° equilibrium is reached almost immediately. Am- monium thiocyanate, on the other hand, does not change in aqueous solution, but in the fused state at 170° it changes at about the same rate as ammonium cyanate in aqueous solution at 60°. The predominance of the thiocyanate in the equilibrium [75-7 %] NH,S.C: N @ CS(NH,), [24:3 %] is in marked contrast to the instability of the cyanate. 6. Isomeric Change proceeds according to a simple Logarithmic Law, and the Period of Change is the same for different Isomerides.—The logarithmic law has been verified in the case of glucose and other sugars,‘ in the case of z-bromonitrocamphor’® and in many other instances. If, however, one of the isomerides is an active catalyst, or if by reason of association or dissociation only part of the material is in a condition to undergo isomeric change, the velocity-constant may vary as the concentration changes. In the absence of such disturbances the period of change must be the same 1 Trans. 1895, 67, 746. 2 For observations on the alkyl thiocyanates see Walker and Appleyard, Trans. 1896, 69, 193 $ Reynolds and Werner, Frans. 1903, 88, 1. 4 Osalca, Zit. phys. Chem. 1900 35, 661, 5 Lowry, Zrans. 1899, 75, 227. ON DYNAMIC ISOMERISM. 199 for the different isomerides, though large accidental discrepancies may occur when isomeric change depends on a small amount of a third substance. A fair agreement between the two periods was observed in solutions in benzene of normal and pseudo z-bromonitrocamphor ! but Forster’s curves for the two a-benzoylcamphors show a period twice as great for the ketonic as for the enolic form. 7. Catalytic Agents alter the velocity of Isomeric Change but do not disturb the Equilibriwm.—Schiff? supposed that in the case of ethyl aceto-acetate CH,.CO.CH,.CO.OEt 2 CH;.C(OH) : CH.CO.OEt the material was converted by a trace of sodium ethoxide wholly into the enolic, and by a trace of piperidine wholly into the ketonic, form. This is impossible on theoretical grounds and has been disproved experi- mentally in this and in other cases.* It therefore follows that catalytic agents accelerate both isomeric changes in the same ratio. 8. The Equilibrium may be affected by the Solvent, Concentration and Temperature.—The direct effect of these is probably small, but if there is a tendency for one or both of the isomerides to polymerise, as in the case of the nitroso- and many hydroxylic compounds, or to combine with the solvent, as in the case of normal nitrocamphor dissolved in benzene, or to combine with one another, as in the case of thiourea and ammonium thiocyanate 4 or to become ionised, as in aqueous solutions of the cyanates and pseudonitro- compounds, very marked effects may be indirectly produced. Thus Wislicenus has shown ® that associating solvents and high concentrations favour the formation of the (dimolecular) enolic form of ethylic phenylformylacetate CHO.CHPh.CO,Et @ HO.CH : CPh.CO,Et. In the contrary direction, Perkin has shown® that high temperatures increase the proportion of the ketonic form of the diketones, probably by dissociating the dimolecular enolic forms. The great increase in stability of ammonium cyanate in dilute aqueous solution may be attributed to the large proportion of the salt which is then in an ionised condition and only indirectly available for isomeric change— + — CO(NH,), 2 NH,.0.CN 2 NH, | OCN. Thus Walker and Hambly’ have obtained evidence that at the dilution of N/2000 ammonium cyanate and urea would be equally stable, and would be present in equal proportions in the mixture. On somewhat similar lines Hantzsch and Kinchenberger have contended ® that nitroform in anhydrous solvents exists almost exclusively in the normal modification, but that in aqueous solutions it is mainly in the ionised pseudo- modifica- tion, psewdo-nitroform being one of the strongest known acids : - + CH(NO,), 2 (NO,),CH : NO,H 2 (NO,)CH : NO, | H. ! Loe. cit. 2 Ber, 1898, 31, 601. $ See Schaum, Ber. 1898, 31, 1964; and Lowry, Trans. 1899, 75, 223. 4 Reynolds and Werner, loc. cit. 5 Ann. 1896, 291, 182. ® Trans. 1892, 61, 801. 7 Loe. cit. 8 Ber, 1899, 32, 628. 200 REPORT—1904. 9. The Ultimate Product of Isomeric Change is a Mixtwre.—It is necessary to emphasise the fact that except when isomeric change is complete the ultimate product is not a definite compound or a new isomeride but merely a mixture. Thus if the ultimate product of the isomeric change of glucose were a definite third isomeride, as has been suggested by Lippmann,! by Tanret? and more recently by Simon,? it would be impossible by mere crystallisation to reconvert it into the labile a-glucose. So also if ammonium thiocyanate and thiourea were converted completely into the compound 3AmCNS,CS(NH,),, postulated by Reynolds and Werner, it would be impossible by mere cooling to crystallise from the fused mass anything but the compound in question. 10. The Classification of Dynamic Isomerides.—Following Butlerow’s example dynamic isomerides have usually been divided into two classes according as isomeric change takes place ‘spontaneously’ or only under special conditions. The ‘spontaneous’ changes have often been called ‘tautomeric,’ whilst the other group have been distinguished as ‘ ordinary ’ isomeric changes. Such a distinction may be convenient but cannot be defended on any other ground, for the spontaneity of the change is not an inherent property of the substance but depends on the presence or absence of a catalytic agent in the dirt that normally accompanies it. It must also be remembered that many isomeric changes which are not spontaneous at ordinary temperatures appear to become so when the temperature is raised, and the classification in question thus unconsciously involves an arbitrary temperature limit. But although no satisfactory classification of dynamic isomerides can be made on the basis of the readiness with which they undergo change, it is nevertheless possible to distinguish two principal groups, of which the second includes the majority of the so-called spon- taneous changes. These two groups are as follows : A. Isomeric changes in which two radicles are interchanged, of which neither can be split off alone as an ion. Closely related to this group are a number of cases in which a double bond is shifted in an unsaturated compound. B. Isomeric changes in which a single radicle is transferred which is capable in at least one of the isomerides of acting as an ion ; the transference is accompanied by a rearrangement of bonds in the molecule, The fact that changes of these two types usually take place under different conditions and in presence of different catalytic agents, goes far to show that the distinction is not arbitrary but fundamental. These two groups of changes are dealt with in the two following sections. Optical inversion, which includes examples from both groups, is discussed under a separate heading. III. Lsomeriec Changes in which Two Radicles are Interchanged. 1. Interchange of Radicles in Aliphatic Compounds.—Butlerow’s observation that the isodibutylenes are accompanied by isomeric alcohols is of importance not only as affording an illustration of this type of 1 Ber. 1896, 29, 203. 2 Bull. Soc. Chen. 1896, iii. 16, 195. 3 0. R. 1901, 182, 487. ON DYNAMIC 1SOMERISM. 201 dynamic isomerism but also because it proves that the interchange of H and OH depends on the separation of a molecule of water. Changes of this type frequently occur when alcohols are dissolved in sulphuric acid, as, for instance, in the production of tertiary butyl derivatives from isobutyl alcohol HO.CH,.CHMe,2CH, : CMe, + H,O2CH;.CMe,.0H. In the conversion of pinacone into pinacoline the reversible separation of a molecule of water would account for the interchange of CH; and OH. CMe,,OH Nr _,CHs.CMe, | H,0 + ; ZH,O + CMe,.CO.CH,. OMe,.0H HO.CMe% ~*~ HO.CMc OH ~ . ‘ A similar separation of HBr may be involved in the conversion, in presence of aluminium bromide, of propyl into isopropyl bromide CH,.CH,.CH,Br2 HBr + CH;.CH : CH,.2CH;.CHBr.CH, whilst in the conversion of «a into y-bromoacetoacetic ester the inter- mediate product would be a ring compound : CH CH, CO.CHBr.CO,Et? HBr + | *oH..CO,8t2.CH,Br.00.0H,.CO,Et. co 2. Isomeric Change of Unsaturated Compounds.—This is merely another phase of the preceding case, for the isomeric change depends on association with H,O, H,SO,, or HBr, instead of on dissociation, and takes place under similar conditions. Thus the undecyclenes, like Butlerow’s octylenes, are in equilibrium in presence of sulphuric acid, the proportions being indicated in the equation ! (49) CH, : CH.CH,.C,H,;2 CH,.CHOH.CH,.C,H,,2CH,.CH : CH.C,H,, (96 %). At high temperatures changes of this type take place readily in contact with platinum black or alumina, for instance,? OH, cH, | 2OCH,.CH:CH,; \CH, under conditions such as these the conversion probably depends on asso- ciation with water, the activity of a trace of moisture being greatly increased by the high temperature and the presence of the contact substance. Isomeric changes of this kind are very frequent, especially amongst the terpenes. They may lead either to the shifting of a double bond, as in the conversion of dihydrocarvone into carvenone CO.CH 00.CH CH,.CHC : CHMe : CH, 2.CH,.CHZ No.cHMe, CH,.CH, \GH,.CH,” or to a rearrangement of the ring-system in the molecule, as when pinene 1 Thoms and Mannich, Ber. 1903, 36, 2544. a Tanatar, Zeit. phys. Chem. 1902, 41, 735; Ipatieff and Huhn, Ber, 1903, 36, 202 REPORT—1904. is converted through its hydrochloride into camphene or camphor into carvenone.! In the hexachlorocycloketopentenes, studied by Kister,? the shifting of the double bond is accompanied by the transference of a halogen atom, and equilibrium is established fairly rapidly at 210°, the necessary catalyst being probably HCl, COL: CCL OCLC, *" CCl.CCl,” CCLCCI,” 76) Included in this group are the stereoisomeric changes of unsaturated compounds. The conversion of maleic into fumaric acid, which takes place at ordinary temperatures in presence of HBr, is almost complete, H.C.CO,H _ CO,H.C.H Nl I H.C.00,2° > H.0.00,H. but the dibromotolanes which are convertible at 210° are almost equally stable and are present in approximately equal quantities in the melt.’ C,H;.C.Br C,H,.C.Br [48 9%] | Fs I [52%] C,H;.C.Br Br.C.C,H; In each case isomeric change may be due to association with HBr, though another explanation is available in the case of maleic acid (compare p. 211). Amongst nitrogen compounds similar equilibria are observed in the stereoisomeric oximes 4 and the syn- and anti-diazo- compounds.” 3. Interchange of Radicles in Aromatic Compouwnds.—One of the most characteristic properties of aromatic compounds is the ease with which they undergo isomeric change, so that almost any radicle that can be attached to the nitrogen of aniline or the oxygen of phenol can be subse- quently interchanged with a hydrogen atom in the nucleus. In this way it is possible to transfer radicles as diverse as the halogens, NO,, OH, 8O3H, COPh, NHPh (semidine), PhNH, (benzidine), and (under somewhat forced conditions) CH;. The ring-substituted compounds are very stable, and the back action is usually slight, but as scarcely any attempt has yet been made to study these changes from the standpoint of equilibrium, it is impossible to say to what extent reversal occurs in any given case. Two ring-substituted compounds may exhibit a well-defined equilibrium, and such a case is found in the ethylxylenesulphide sulphonic acids,’ the stable proportions in the mixture being indicated by the equation CH, CH, SO,H/\ /\S803H [90-92 96] | | 2 | [10-8 94). \ZCHs3 \/ZCHs3 SEt SEt 1 Bredt, Annalen, 1901, 814, 369; compare Armstrong and Lowry, 7Zvans. 1902, 81, 1469, and p. 214 of this report. 2 Zeit. phys. Chem. 1895, 18, 161. 3 Wislicenus, Dekanatschrift, Leipzig, 1890. 4 Cameron, J. phys. Chem. 1898, 2, 409; Carveth, ibid. 1899, 8, 437. 5 See Dr. Morgan’s report, Belfast 1902, and Hantzsch, Die Diazoverbindungen, Ahren’s Sammlung, 1902. * Harker, Zhesis, London, 1903. ON DYNAMIC ISOMERISM. 203 The remarkable manner in which a small amount of o- acid persists in the mixture formed on sulphonating toluene affords similar evidence that this acid has a definite place in the equilibrium. 4. The Beckmann Change.—These interactions, in which an alkyl group attached to carbon is interchanged with a negative radicle attached to nitrogen, belong essentially to the group of isomeric changes now under consideration. Such changes are most frequently observed amongst the oximes and nitro- compounds, but a somewhat similar rearrangement must be assumed to occur in the preparation of amines from amides by Hofmann’s reaction and in the decomposition by heat of the acid azides. Although the mechanism of the change is only imperfectly known,! the rearrange- ment resembles very closely that by which radicles are transferred from the side chain to the nucleus in aromatic compounds ; in each case isomeric change is usually complete, and is brought about by acid rather than by alkaline agents.2_ Thus, whilst alkaline catalysts greatly accelerate the conversion of normal into pseudo- nitrocamphor, they do not bring about any further change. Acid catalysts, on the other hand, are less powerful in producing pseudo-nitrocamphor, but cause a further non reversible rearrangement of the Beckmann type whereby the nitro-compound is converted into camphory! oxime NOH ee Se Nae pk | <— CeHi< | > C.H,, O O \co alts. 9 Lat 5. Mechanism of Isomeric Changes involving an Interchange of fadicles.—These changes appear to be electrolytic in the same sense as the chlorination of ethane, in which the main constituents can act only as depolarisers and the electrolyte is probably hydrogen chloride =e C,H, CH Cl C,H;Cl HCl | —'+ | gives H CIH Cl HCl HCl The association of an olefine with HBr may thus take place in a closed electrolytic circuit in which HBr is electrolysed > > R.C.H BrH Br R.CH Br H Br | = nia atest 2!) Aap | — + 0. “EH er" Fo CHAE! “Bret < <_ whilst the reverse dissociation might be effected by the passage of a current in the opposite direction, giving rise either to the original or to the isomeric olefine. So also in the aromatic series the conversion of phenylchloroacetamide, C,H;.NCl.CO.CH, into p chloroacetanilide, Cl.C;H,.NH.CO.CH;, may be regarded as taking place in a circuit ' See Steiglitz, Amer. Chem. Journ. 1896, 18, 751; 1903, 29, 49; Slossen, 1903, 29, 289; Steiglitz and Earle, 1903, 29, 399 and 412. ? The Hofmann reaction takes place in alkaline solution, but is not an isomeric change, and can therefore hardly be quoted as an exception. 204 REPORT—1904. in which hydrogen chloride is electrolysed. But when a methyl-group is transferred there appears to be a complete separation of the radicle (e.g. as CH,Cl) and subsequent recondensation, giving rise not only to isomerides, but also to higher and lower homologues. 6. Influence of Catalytic Agents.—Isomeric changes of this type usually take place only in presence of strong acids, whilst alkalies prevent rather than assist the change,! as is shown by the stability of the salts derived from labile sulphonic acids, diazohydroxides and oximes, and by the readiness with which good yields of compounds such as phenylchloro- acetamide and /3-phenylhydroxylamine are obtained by alkaline or neutral methods of preparation. The conversion of ammonium cyanate into urea may be regarded as due to the dissociation of the cyanate and recondensa- tion of the resulting NH; and HCNO— NH, CO NH, Shave Cnet ; was (a aged CO ; NH NH,/ whatever view be taken of this condensation it is evident that the ammonia is resolved into the two radicles H and NH,, and so functions as an acid rather than as a base ; there need therefore be no hesitation in classifying this change with the dissociation and association of acids which characterise this group of isomeric changes. IV. Isomeric Changes in which a single Mobile Radicle is Transferred. To this group belong all those cases in which a mobile hydrogen atom is transferred from oxygen or sulphur to carbon or nitrogen, as in the ketones, nitro- compounds and oximes, together with the few cases in which it is possible to prepare isomeric salts from these. The transference of an anion is less frequent but Hantzsch has described a number of cases in which a mobile OH or CN group is transferred in precisely the same way as the mobile hydrogen atom. The group of changes in which a mobile hydrogen atom is transferred includes the most important cases of dynamic isomerism and forms one of the most fully investigated, and at the same time one of the most fertile, branches of organic chemistry ; the great wealth of examples must be attributed to the neutral character of the hydrogen atom, which is equally ready to play an inert part in a hydrocarbon, or to associate itself with a powerful negative radicle in the mineral and organic acids. All the members of this group undergo isomeric change with great readiness. This is probably due to the fact that in every case at least one of the isomerides is an electrolyte, and so can take its place in an electrolytic circuit instead of acting merely as a depolariser. Thus, although it is difficult to think of pseudo-acetone as anything but an unsaturated alcohol, the proximity of the double bond gives it at least a superficial resemblance to acetic acid and probably confers upon it distinct electrolytic properties : oa oe CH,.C0O.CH CH..C CH,.C 3 3 3 \cH, 3 Xo Acetone Pseudo-acetone Acetic acid. ! Exceptions to this rule are found in cases in which an interchange of radicles depends on a double ketoenolic change or on a reversible hydrolysis, as in the case of a and 8 glucose. ON DYNAMIC ISOMERISM. 205 The relative stability of the isomerides, depending as it does on the ratios of the velocities of change, is greatly influenced by substitution. The introduction of negative groups appears always to favour the production of the more acid isomeride. 1. Ketones.—The mono-ketones are almost wholly ketonic, but their behaviour on bromination! and possibly their phosphorescence when exposed to Tesla radiation, or after exposure at low temperatures to ultra- violet light, indicates that even here a trace of enol may be present, The introduction of the CO,Et group in ethylic acctoacetate makes its chemical properties entirely different from those of acetone, but does not introduce any large proportion of enol into the equilibrium.” Amongst the diketones, however, ethyl acetylacetone, CH;,.CO.CHEt.CO.CH;, though almost wholly ketonic at 95°, contains about one-third of enol at 19° ; methyl acetylacetone, CH,.CO.CH.Me.CO.CH;, contains about one-eighth of enol at 96°, and one-half at 16°; whilst acetylacetone itself, CH,.CO.CH,.CO.CH,, contains about three-fourths of enol at 93° and at 17° appears to contain a certain amount of a dienolic form CH;.CO.CH,.CO.CH, 2 CH;.CO.CH : C(OH).CH; 2 CH, :C(OH).CH : C(OH).CH, Similarly Claisen * found amongst the triketones an increasing tendency to enolisation, as benzoyl was displaced by acetyl in the series CHBz,, CHAcBz,, CHAc,.Bz, CH Ac. Camphor, like acetone, is almost wholly ketonic, though it yields an enolic benzoate, OHS | NO.OBz CHBr a-Bromocamphor,0sH,. | , is only known in the ketonic form, but the CO flash of light that appears when the crystals are crushed is perhaps an indication of the presence of a trace of the enolic form. CH.CO,Et, Hy, | ‘co acetoacetate, is also mainly ketonic,’ but solutions of a-benzoyleamphor, a ee: CoH. | , contain 60 per cent. of the enolic isomeride.® co : , When boiled with benzoyl chloride.* Ethyl camphocarboxylate, C, the analogue of ethyl 2. Aldehydes.—Enolisation of aldehyde only occurs when negative radicles are introduced into the methyl group, as in ethers of pheny!- formylacetic acid,’ oes oils H.CO.CH{ _ @HO.CH : C COR Nco.R and formylacetoacetic acid.® 1 Lapworth, Trans. 1904, 85, 30. 2 Perkin, Zrans. 1892, 61, 801. 3 Ann. 1896, 291, 25. 4 Lees, Zrans. 1903, 88, 152. 5 Briihl, Ber. 1902, 35, 3510. 6 Forster, loc. cit. 7 Wislicenus, Ann. 1896, 291, 147; Lapworth and Hann, Trans. Chem. Soc. 1502, 81, 1491. 8 Ber, 1893, 26, 2730. ~ 206 REPORT—1904. 2 Hydroxymethylene (formyl) ig is usually regarded as the enolic modification, HO.CH : oxi IP ; "and formylacetylacetone, H.CO. seo CH,),2HO.CH : C(CO.CH;) is a stronger acid than acetic. 3. Esters.—The possibility of enolisation is indicated in the formule assigned to ethylic sodiomalonate, EtO.CO.CH : C(OEt).ONa, and ethylic sodiocyanacetate, CN .CH.C(OEt).ONa,? and is of importance in deter- mining the optical inversion of carboxylic acids. In the case of ethylic dicarboxyglutaconate, (CO,Et),C : CH.CH(CO,Et)., and ethylic isa- conitate, CO,Et.CH : CH.CH(CO,Et),,? the ester itself gives a blue coloration with ferric chloride and is at least partially enolic. The green modification of ethylic succinosuccinate is not represented in a satisfactory manner cde either of the conventional formule, COH.CH, ponerse doe CO,Et and CO,Et.c’ Sc.co, Et, oes re, \cH,.COH” but the colour would be accounted for if it were formulated as OH: Et staa og é Sa: OZ. “ HOY« ‘as@tGoH7...;>OB,: and if this be correct the enolised ester is actually the stable form under certain conditions. 4. Phenols.—The strong enolic character of the phenols is lessened by substitution and by reduction, probably owing to the weakening of the benzene ring. Psewdo-phenol, O : OL and pseudo-quinol, a4 H 0:C,H K are as unstable as psewdo-camphor or pseudo-acetone, though derivatives of this type are known,‘ hut dihydroresorcinol appears to contain at least one keto-group and yields a dioxime, whilst phloroglucinol yields a trioxime, though its absorption spectrum shows that it is almost wholly enolic in solution.” 5. Amides.—These rarely, if ever, exist in an enolic form, even when forming part of an aromatic ring as in isatin, the a and y pyridones (hydroxypyridines), CH.C(OH) CH.CH cH? Sw and HO.cZ Sn, \cH : CH 7% \cH : CH 1 Claisen, Ann. 1894, 281, 306. 2 J. F. Thorpe, Trans. 1900, 77, 923. 8 Guthzeit and Dressel, Ber. 1889, 22, 1418. 4 See especially Auwers, Ber. 1902, 35, 443455, who gives asummary of recent work on the pseudo-quinols. 5 Hartley, Dobbie, and Lauder, 7rans. 1902, 81, 929. ON DYNAMIC ISOMERISM. 207 iy : CH carbostyril (hydroxyquinoline), CoH | , and cyanuric acid, N=C.0H JN : COB) HO.C Nw.c(0H) 7 and Hartley, Dobbie, and Lauder have shown that this is probably the ketonic form.! Cyanic and thiocyanic acids also yield isomeric esters, but are only known in one form, apparently the ketonic.? Lees and Shedden ? claim to have prepared the enolic form of acetyl-o-aminophenol, HO.C,;H,.N : CMe.OH, but the great stability of the substance, which does not appear to be convertible into the ketonic isomeride, is difficult to reconcile with the formula they propose. 6. Witro- compounds.—These are influenced by substitution in a similar manner to the ketones. Even in aqueous solution the conversion of the pseudo into the normal form appears to be complete in the case of nitromethane, H.CH,.NO,, nitroethane, CH;.CH,.NO,, phenylnitro- methane, C,H;.CH,.NO,, and its p-bromo- and p-nitro- derivatives ; but dinitroethane, NO,.CH,.NO,, gives a mixture of the normal and pseude forms, and—in aqueous solution only (see p. 199)—acetylnitromethane CH;.CO.CH,.NO,, benzoylnitromethane, C,;,H,.CO.CH,.NO,, bromodi- nitromethane, NO,.CBrH.NO,, and trinitromethane, (NO,),CH.NO,, appear to exist almost exclusively in the pseudo- form.4 Similar effects are produced in the camphor series, the nitro- com- pounds of which have been examined both in ionising and in non-ionising solvents. Nitrocamphane, N. In all these cases only one modification is known, CH, C,H 14 é | \CH.NO,, passes in solution completely from the pseudo- into the normal form.® Nitrocamphor, CH.NO, OC | gives a mixture, and in 3- and z-bromonitrocamphor, CH.NO, CH, Br | Noo, the influence of the keto- group is so far reinforced by the bromine that in the solid state the pseudo- is the stable form.® 7. Nitroso- compounds and Oximes.—The group >CH.NO appears to be even more unstable than the pseudo-amide group —N : COH—. 1 Trans. 1899, 75, 640. 2 Hartley, Proc. Chem. Soc. 1899, 15, 46. 8 Trans. 1903, 88, 750-763. * Hantzsch, Ber. 1899, 32, 607. 5 Forster, Trans. 1900, 77, 260. 6 The stability of the pseudo- form in the solid state is due to a decrease of solu- bility, and not to any marked increase in the proportion present in solution. 208 REPORT—1904. Schmidt! has prepared from trimethylethylene three nitroso- compounds, which he formulates as CMeH.NO CMeH.NO CMeH.NO | | and : | CMe,.0.NO CMe;.0.NO, CMe,Cl These are converted by heating or by alkalies into the isomeric oximes, X.CMe,.CMe:NOH, but the change proceeds so slowly that there has been some hesitation in accepting the formule proposed. The unexpected behaviour of these nitroso- compounds is probably due to the stability of the colourless polymerides, which must be resolved before isomeric change can take place. Piloty’s chloronitrosoethane? behaves in a precisely similar manner as indicated in the scheme (CH,.CHCI.NO],220H;.CHCI.NO =”,.2CH;.CCl : NOH. In the nitrosoaldehydrazones studied by Bamberger and Pemsel? the conversion of the nitroso- compound into the oxime involves the change of the hydrazone into an azo- compound, and the stability of the nitroso- compound is greatly increased — CH,.C(NO) : N.NH.C,H;—?CH;.C( : NOH).N : N.C,H;. The further equilibrium between the hydroximes >C : NOH and NH pseudoximes >Cg | has been so little studied that no definite con- O clusions can be drawn as to the effects of substitution ; in the cases studied by Dr. Whiteley * the stability of the two solid forms appears to be determined mainly by their solubility, and nothing is known at present of the proportions in which they are present in the solutions. 8. Other cases.—The alkyl cyanides are only known in one form, but cyanocamphor appears to exist to some extent in the acid psewdo- form, CH aN CC SINE C,H vid OPEL 8 Ee <—Us do and psewdo-cyanoform is an even stronger acid than psewdo-nitroform,” CH(CN);2(CN),C :C : NH. Dynamic isomerism is also common amongst the hydrazones and azo- compounds and the amidines. A review of all the groups in which dynamic isomerism has been observed is given by Wislicenus,® but the examples quoted above will suffice to show the general character of the observations that have been made. 9. Isodynamic salts.—Unlike hydrogen, the metallic radicles have a strong tendency to attach themselves to the most negative groups in the molecule, and isomeric change is usually both rapid and complete. By 1 Ber. 1903, 36, 1765. 2 Ber. 1902, 85, 3113. 3 Ber, 1903, 86, 57-84. * Trans. 1903, 83, 24. 5 Hantzsch and Ostwald, Ber. 1899, 32, 641. 6 ‘Ueber Tautomerie,’ Alzen’s Sammlung, 1898. ON DYNAMIC ISOMERISM. 209 taking advantage of their slight solubility, Titherley has recently prepared the labile silver salts of benzamide and acetamide, C;H;.CO.NHAg2C,H;.C(OAg) : NH, CH;.CO.NHAg?CH;.C(OAg) : NH, and Hantzsch has isolated the isodynamic forms of mercuric cyanurate.? But whilst it is possible to prepare N and O salts from the amides, the ketones appear to yield only enolic salts, and it is doubtful if metals ever become directly linked to carbon except in the carbides and perhaps the cyanides. Ethyl phenylformylacetate appears at first sight to be an exception, since it yields two series of salts: the enolic sodium salt, NaO.CH : CPh.CO,Et, prepared by the action of sodium on an ethereal solution of the ester, is converted almost instantly when dissolved in water, into an aldehydic isomeride, which gives no coloration with ferric chloride ; on the other hand, the solid aldehydic copper salt, when precipitated from aqueous solution, soon passes into an enolic isomeride, The aldehydic salt has always been formulated as Na.CO.CHPh.CO,Et, but there does not appear to be any precedent for the direct displacement of aldehydic hydrogen by metals, and the difficulty entirely disappears if the salt be regarded as derived from an enolised ester (see p, 206) ; NaO.CH : CPh.CO,Et2H.CO.CPh : C(OEt).ONa, (enolic salt) (aldehydic salt) Dynamic isomerism is also possible, though not yet proved, amongst simple inorganic salts like the sulphites Na0.S0.0NaZNa.SO,.ONa., 10, Transference of an Anion.—In the majority of organic compounds the OH group is devoid of basic properties, and it is only in cases like the ammonium, the sulphur, and the iodine bases that it is capable of functioning as ananion. Occasionally, however, the necessary conditions are fulfilled, and a state of equilibrium may be observed between an ammonium base and an isomeric carbinol, the transference of the hydroxyl- group being exactly comparable with that of the mobile hydrogen atom in the ketones and nitro- compounds.* Thus Hantzsch has shown that phenylmethylacridinium hydroxide, when liberated from its salts, is rapidly converted into the neutral isomeric phenylmethylacridol, 4 + 1 t C,H. © PACA Pat n¢ CoH Me | OH <..HO.CPh (OsHs . Becrer ne 2 (GH, Ne The case that has been most fully studied is that of the alkaloid cotarnine,°® + a CH : NMe|OH CH(OH), NM Gree AOL ahaa of MELON Me pp eas a | . CH,. CH, CH, lor, ! Trans. 1901, 79, 409. ? Ber. 1902, 35, 2717. * Hantzsch describes as pseudo- acids all those substances which, like the nitro- paraflins, are themselves neutral, but yield salts derived from an isomeric acid. Similarly psewdo- bases are neutral substances which combine with acids to form salts of an isomeric base. Occasionally the cyano- derivatives (nitrils) of the pseudo- bases (carbinols) can be converted into salt-like isomerides (substituted ammonium cyanides), and these are therefore called pseudo- salts. ‘To these three cases Hantzsch applies the term ‘ionie isomerism,’ * Hantzsch, Ber., 1899, 32, 575-600. ® Dobbie, Lauder, and Tinkler, Zrans. 1903, 83, 598. 1904, P 210 REPORT—1904. The solid alkaloid appears to be the neutral carbinol, and persists in this form when dissolved in ether or chloroform. When dissolved in water or alcohol, however, it is converted largely into the ammonium-base from which the acid salts are derived. The addition of methyl alcohol to the ethereal solution causes a gradual change from the carbinol to the basic form, but a reverse change is brought about by adding sodium hydroxide to the aqueous solution. A similar equilibrium is possible in the salts derived from cotarnine, but the chloride is known only in the ammonium form and the cyanide only in the carbinol form : : ye ee aaah Hom CH : NMe | ON : 0,5,0 60x mes 3 CH, =“- CH, \CH,.CH, + aa CHC]. NMe oe : NMe | Cl [ cating | ts CHO | CH, . CH, CH,. CH, 11. Influence of Catalytic Agents Unlike the isomeric changes of Group A, which usually take place only in presence of an acid catalyst, those involving the transference of a mobile hydrogen atom are cha- racterised by an extraordinary sensitiveness to the catalytic action of traces of alkalies. The instantaneous fall of rotatory power on adding a small amount of ammonia to freshly prepared solutions of glucose was noticed by O'Sullivan and Tompson in 1890," but it was not until some years later that the dependence of the mutarotation on isomeric change was demonstrated. Similar effects have been observed in the case of nitrocamphor,? nitrocamphane,? benzoyleamphor,’ menthy] acetoacetate, camphorquinone phenylhydrazone,” and the azo- derivatives of menthyl acetoacetate,® and no exception has yet been discovered. The smaller catalytic action of acids was first noticed in the mutarotary sugars,’ and Osaka® has shown that whilst the influence of alkalies is proportional to the concentration that of acids is proportional to the square root only. The influence of acids on nitrocamphor was at first overlooked,° though it is well marked in decinormal and centinormal solutions ; Lap- worth was the first to show that acceleration by acids is character- istic of this group of isomeric changes. An apparent exception occurs in the case of camphorquinone phenylhydrazone, the mutarotation of which is stopped by traces of acid. Neutral salts have no influence on the iso- meric change of glucose,'? but greatly accelerate that of nitrocamphor.!! This difference is probably due to the fact that pseudo-nitrocamphor is a strong acid, and is able to compete for a base even against a mineral acid. 1 Trans. 1890, 57, 920. 2 Loe. cit. p. 221. ; 3 Forster, Zrans. 1900, 77, 259. 4 Forster, Zrans. 1901, 79, 999. 5 Lapworth and Hann, Trans. 1902, 81, 1499 and 1508. 6 Lapworth, P7oc. 1903, 19, 149. 7 Levy, Zeit. phys. Chem. 1895, 17, 301; Trey, Zeit. phys. Chem. 1895, 18, 193; 1897, 22, 424. 8 Zeit. phys. Chem. 1900, 35, 661. ® Loe. cit. p. 221. 1 Lowry, Zrans. 1903, 83, 1317. 1 Loe, cit. p. 221. ON DYNAMIC ISOMERISM. 211 V. Optical Inversion. When optical isomerides become isodynamic the resulting mixture is inactive, for under normal conditions the d and / forms are equally stable. At least in the case of carbon it appears to be impossible directly to alter the point of attachment of the radicles, and the interchange on which the inversion depends can only be effected ‘by an indirect process. In many cases the inversion appears to be brought about by means of a double keto-enolic isomeric change, the inactive ‘enolic form being in equilibrium with both active forms. The proportion of enol is often exceedingly small, and isomeric change must then be slow even under the most favour- able conditions. If the mobile hydrogen atom is displaced by methyl the inversion is no longer possible. Thus in the case of phenylglycollic acid, which becomes inactive when heated alone,! or with dilute alkalies,? the inversion: is probably effected through the intermediate inactive form indicated in the equation C,H, O,H; Ho /CC CO.0H2HO °C: COW): d-acid (50 per cent.) inactive enolic acid (tra ae fe acid (50 per ile ) CH. 4 /CO.OH A similar explanation may be given of the conversion of maleic into fumaric acid, since this also involves the inter change of H and CO,H. Although changes of the keto-enolic type are exceedingly ceniiges to alkaline catalysts “the optical inversion of acids is often brought about more rapidly by acid catalysts, on account perhaps of the greater stability of the ketonic form in the metallic salts. The esters (see p. 206) would probably be racemised even more easily than the acids but for the fact that it is impossible to introduce either acids or alkaline catalysts without hydrolysing the ester. Kipping and Hunter ® have shown, however, that although benzylmethylacetic acid, C,H;.CH,.CHMe.CO,H, is unchanged when heated at 170° during two hours, the acid chloride is racemised slowly at 70° and rapidly at 100°, and this may be taken to indicate that the chloride, unlike the acid, contains an appreciable quantity of enol. d-Camphoric acid, which contains two asymmetric carbon atoms, undergoes a reversible isomeric change when heated with water or with a mixture of acetic and hydrochloric acids. Only one of the asymmetric carbon atoms carries a hydrogen atom, and this is readily inverted, giving vise to a mixture of d-camphoric and /-isocamphoric acids in unequal proportions. vy ,CO.OH CX C< mar : \co.0H Aer oe ao WP OE, Ph itee “ < oS een fie \cO0.0H \c0.0H d-camphoric acid l-isocamphoric acid ' Lewkowitsch, Ber. 1883, 16, 2721. 2 Holleman, Rec. Trav. Chim. 1898, 17, 323. 3 Trans. 1903, 88, 1008. P2 912 REPORT—1904. The second asymmetric carbon atom is not inverted, and no /-camphoric acid is produced, It is therefore possible, by merely converting into an anhydride, to restore completely the original activity of the acid. In d-tartaric acid both active carbon atoms can be inverted, giving rise to meso-tartaric and /-tartaric acids. The rate of formation of the meso- acid from the d+/ acid in presence of hydrochloric acid at 140° is 1:9 time as great as that of the d+/ from the meso- acid, and the proportions in the equilibrium are therefore those indicated in the equation Wi H ,CO.OH HO. 00.0H Hise) 19 Ose. at Nea Yd SeOMHS y= pr ee | NH | CO.0H = | (COOH, = AM Cx Cx Cz Ho’ ~ NH HO? HO’ ~ \CoOH d-acid 17:33 % meso- acid 65°4 % l- acid 17:3 % The formation of the meso- acid involves a double, and that of the /- acid a quadruple keto-enolic change, and the conversion is therefore exceedingly slow, the proportions after heating during 42 hours at 155° being only 3°4%1 : 18 % meso : 78:6 %d.' The salts undergo similar isomeric change when heated with an excess of alkali, but the proportions when equilibrium is reached appear to be 38 % / : 24 % meso : 38 % d. The reversible isomeric change which glwconic and allied acids undergo when heated with quinoline or pyridine at 130°-150° ” is of importance, not only in the synthesis of the sugars but also because of the proof it affords that a definite mechanism is needed to bring about optical inversion, and that apart from this it is impossible even to interchange the points of attachment of an H and OH group. In each case only the terminal CHOH group which carries the carboxyl is inverted, whereas if it were possible by this drastic treatment to shake the remaining CHOH groups the product would be a chaotic mixture of the sixteen acids which are theoretically possible. Closely related to the isomeric changes of the sugar-acids are those which the hexoses themselves undergo in solution, and especially in presence of alkalies. Glucose appears to exist in four isodynamic forms,’ of which the stereoisomeric a and f (hydrogen-) glucosides are the dominant forms and the aldehyde a minor constituent, the enol being present only in traces. Owing to the moderate proportion of aldo-glucose present in- the solution equilibrium is rapidly established between the a and B gluco- sides. The enolic form is common to glucose, fructose, and mannose, and the slow rate at which equilibrium is established between these three sugars, even in the presence of considerable quantities of alkali,‘ is an 1 Holleman, Rec. Trav. Chim. 1898, 17, 66. 2 Fischer, Ber. 1894, 27, 3193. 3 Compare Zrans. 1903, 83, 1314. For the proof that the a and B glucose are the parent substances of the « and £ glucosides, see E. F. Armstrong, Vans. 1903, 83, 1305, and Behrend and Roth, Ann. 1904, 331, 359. With reference to the proportions of the constituents in the mixture, see Lowry, Proc. 1904, 20, 108, For the dynamic isomerism of the methyl glucosides and of the pentacetates, see Jungius, Proc. Kon. Akad. Wet. Amsterdam, 1904, 99 and 779. 4 Lobry de Bruyn, Rec. Trav. Chim. 1895, 14, 201, ON DYNAMIC ISOMERISM. ols indication of the minute proportion of enol in the mixture. It is of interest to note that the complete equilibrium may include no less than ten isomeric sugars. / CHOH CHO CHOH CH,OH CH,OH | | | | $e CHOH CHOH COH CO COH 0) | | | \. CHOH CHOH CHOH CHOH / CHOH Pe ge ie | SF Oya \CH CHOH * CHOH CHOH CHIH | | | | | CHOH CHOH CHOH CHOH ‘CH | | | CH,0H CH,OH CH,OH CH,OH CHOH a and B glucoside aldo-glucose enolic form keto-fructose a and f fructoside (?) a and 6 mannoside (?) aldo-mannose of glucose, mannose, and fructose The inversion of tetrahydro-B-naphthylamine, C,H re CH,.CH, involves the interchange of H and NH., and the readiness with which it takes place at ordinary temperatures is in marked contrast with the great stability of compounds containing the CHOH group. Itcanscarcely be supposed that the replacement of OH by NH, destroys the fixity of the four carbon valencies, and the isomeric change may perhaps depend on the dissociation of an ammonium hydroxide base in the sense of the equation >CH.NH,+H,02>CH.NH,;.0H 2 H,0+ >C:NH, (inactive). 3 ) The salts do not appear to undergo optical inversion. Another case in which the optical isomerides are in equilibrium at ordinary temperatures is that of the d and / methylethylpropylstannic iodides,” in which isomeric change probably depends on dissociation. CH, I Op eames ee cs rey ay 4: These cases are of importance as indicating that the ‘spontaneous’ racemisation, frequently postulated in the so-called ‘chaotic’ molecules, may actually exist as a limiting case of dynamic isomerism. The optical inversion of camphor during sulphonation * necessitates the rupture of one of the three chains which connect the asymmetric carbon atoms, and occurs under conditions very similar to those which actually lead to the production of carvenone.! The inactive dynamic isomeride through which inversion is accomplished is perhaps the enolic form of dihydroeucarvone, which, like dihydrocarvone and camphor itself, 1 Pope and Harvey, Jans. 1901, 79, 74. 2 Pope and Peachey, Proc. 1900, 16, 116. 3 Kipping and Pope, Trans. 1897,'71, 958. +4 Bredt, Annalen, 1901, 314, 369, 214 REPORT—1904. may be produced by removing the elements of water from the alcohol formulated below.! CMe,0H CMe, CH | | eH’ | CH; /CH. Px | CMa” | OM Pe CH, | CH, CH, Cre | CO | | | | *"\ OMe” = eee co. ©. AGH = geen gig Se ~ CHMe CMe Oimphor Intermediate alcohol Dihydroencaryone (inactive enolic form) + t CH, :CMe CHMe, | CH C cH) SCH cu,’ oH | LN Aes | CH, C CH, co ors Ze CHMe CHMe Dihydrocarvone Carvenone VI. Chemical Properties of Dynamic Tsomerides. The addition to a mixture of isomerides in equilibrium of an agent which forms a stable compound with one isomeride brings about a complete conversion into that form. Thus although ammonium cyanate can be converted completely into urea by evaporating its aqueous solution, the reverse change is readily brought about by digesting urea with silver - nitrate. (NH,),COZAmCNO>AgCNO Again, nitrocamphor can be converted equally readily and completely into the bromo- derivative of the normal form or the potassium salt of the pseudo form. ; CH.NO, ye C:NO,H GHC | LOHud | CO v Nitrocamphor \ CBr.NO, Soe : NO,K CHC | e CO CO Bromo-derivative Potassium salt. This formation of two types of derivatives is one of the most important indications of dynamic isomerism, and is frequently observed even when only one of the isomerides can be isolated. Thus camphor and other ketones, which certainly do not yield more than the merest trace of enol, are readily converted into enolic benzoates 2 when boiled with benzoyl chloride ; again, although the conversion of pseudo into normal * Armstrong and Lowry, Zrans. 1902, 81, 1469. * Lees, Trans. 1903, 838, 152, ON DYNAMIC ISOMERISM. 215 nitrocamphane is so complete that the pseudo- form cannot be detected in the equilibrium, no difficulty is experienced in reconverting it into the potassium salt of the pseudo- form. Chemical agents, therefore, give very little information as to the nature of the equilibrium, and can only be used for separating the constituents when isomeric change proceeds slowly under the prevail- ing conditions. Thus no difficulty is experienced in separating ammonium thiocyanate and thiourea or a mixture of sulphonic acids, because at ordinary temperatures and in dilute solution these have no tendency to pass into one another, and are, in fact, no longer isodynamic. So also Kiister was able to separate the isomeric hexachlorocycloketo- pentenes by converting the B- compound into the sparingly soluble anilide, C,H;.NH.C,;Cl,0. In the case of substances such as those described in Section IV., in which the transference of a mobile radicle takes place with the utmost readiness under ordinary conditions and at atmospheric temperatures, the majority of chemical agents are useless for this purpose, especially as many of them have a very powerful catalytic action, and greatly accelerate the isomeric change. The only agent that seems to fulfil the necessary conditions is phenyl isocyanate,' which has little or no catalytic action, and may even remove any moisture or acid impurity already present in the solution ; experimentally it has been found that it combines with phloroglucinol but not with ethyl succinosuccinate, indi- eating that the former is enolic but the latter wholly ketonic ; the same agent indicates that isatin is a ketone, since it gives a substituted urea and not a urethane. co reg tases aI Pu’ CcOH kee H Sco >¢,H,Z co. [° NyZF Shee Eich: 2" NOOR)” Pseudo-isatin Tsatin Benzylidene aniline, C,H,.CH : N.C,H,, although equally ready to com- bine with ketones or enols, cannot be regarded as a trustworthy indicator, for the addition of a trace of sodium ethoxide appears to determine the formation of the enolic, whilst piperidine favours the formation of the ketonic addition-product quite independently of the proportions of ketone and enol present in the mixture.* A different class of agent is typified by ferric chloride, which inter- acts only with a minute proportion of the hydroxylic isomeride to form a coloured ferric salt. If this were insoluble a complete conversion into the hydroxylic form would ensue, but when it remains in solution it does not seriously disturb the equilibrium, and so may serve to indicate the proportion of hydroxyl present. .CH,.CO.2 . CH : COH 2 .CH : C(OFeCl,). In the case of the simple nitro-paraffins and isodynamic ketones ferric chloride can be used to follow the gradual conversion of one form into the other, but in the case of the nitro-ketones it has such a powerful catalytic action that equilibrium is established immediately, and no differ- ence can be detected either in the intensity of the colour or the rapidity ! Goldschmidt, Ber. 1890, 23, 257. * This conclusion is in agreement with that arrived at by Hartley from a study of the absorption spectra. * Schiff, Ber. 1898, 31, 601, 216 REPORT—1904. with which it is developed on adding ferric chloride to the normal and pseudo forms of 7-bromonitrocamphor.! Similar limitations are met with in the preparation of labile isomerides by chemical methods. The hydroxylic forms of many diketones? and nitroparaffins * can be prepared by acidifying a cold aqueous solution of the sodium salt with dilute mineral acids. In these cases the addition of a mineral acid is sufficient to eliminate the catalytic action of the base originally present in the salt, but stronger acids like pseudo-nitrocamphor are able to retain a proportion of the base even in competition with a mineral acid, and in this case the catalytic action of neutral salts is so great that the product is always a mixture of isomerides and not the pseudo- form. This action of neutral salts appears to have been over- looked by Hantzsch, who concluded that benzoy]nitromethane and bromo- dinitromethane existed only in the hydroxylic form in aqueous solution, a conclusion that was based entirely on the fact that no gradual decrease of conductivity was observed in freshly prepared mixtures of the sodium salts with hydrochloric acid. Another method of preparing a labile isomeride is indicated by Forster, who has succeeded in preparing the labile diketonic form of benzoyl- camphor by boiling the enolic modification with formic acid, precipitating with water, and rapidly crystallising from alcohol ;4 the method appears to depend on the formation of an easily hydrolysed formy] derivative, C(COPh)CHO CHC | and may perhaps be applicable in other cases. VII. Physical Properties of Dynamic Isomerides. 1. Crystallography.—In the majority of cases dynamic isomerides are substances of different types, and do not form isomorphous mixtures, though this does not prevent the inclusion in a crystal of small amounts of a dynamic isomeride or the staining of a colourless crystal by a coloured isomeride. Thus normal z-bromonitrocamphor is tetragonal and has a@:c=1 : 1:1002, whilst the pseudo- form is orthorhombic and has a :b : c= 1:1:2159:%° Again, although both forms of a-benzoyleamphor crystal- lise in the orthorhombic system the ketone has a :b : c=0°7375 : 1 : 10224, but the enol has a : 6 : c=0-9728 : 1 : 0°6550, and is hemihedral.® 2. Crystallisation of Fused Dynamic Isomerides.’—In the absence of 1 Lowry, 7rans. 1899, 75, 230. 2 Claisen, Ann. 1896, 291, 25; W. Wislicenus, Anm. 1896, 291, 147; Knorr, Ann. 1896, 298, 70; J. Wislicenus, Ber. 1897, 30, 639; Sitz. Stchs. Ahad. March 1, 1897; Rabe, Ber. 1899, 32, 84. * Hantzsch and Schultze, Ber. 1896, 29, 699, 2251; Konowalow, ibid. p. 2193; — Ree. Trav. Chim. 1895, 14, 121; 1896, 15, 356, 365; Forster, Zrans. 1900, 7, 258. 4 Trans. Chem. Soc. 1901, 79, 997. . > Lapworth and Kipping, Tans. 1896, 304-322. § Forster, loc. cit. 7 The crystallisation of dynamic isomerides has been very fully discussed from the standpoint of the phase rule by Bancroft (Journ. phys. Chem. 1898, 2, 143, 245), by Roozeboom (Zeit. phys. Chem. 1899, 28, 289) and by Findlay (Trans. 1904, 85, 403), but some modification of the theory is necessary in order to allow for the fact that dynamic isomerism is only possible in a tri- or tetra-molecular system, ON DYNAMIC ISOMERISM, 217 dimorphism the freezing-point curve for a mixture of two isomerides A and B has the well-known V-shaped form shown in the figure. When equilibrium exists between them the melt has a definite composition GF, which does not vary much with the temperature. The form that separates first on cooling is determined by the intersection of F G with C DE; in the figure this lies on the branch C D and the form A is the first to crystal- lise. If crystallisation is slow or isomeric change rapid, the composition of the liquid and the temperature will remain constant until the whole of the substance has crystallised out in the form A. Slow cooling thus brings about a complete isomeric change, whilst sudden chilling would give a solid of the same composition as the liquid mixture G ; usually the product will be intermediate in composition, but the exact proportions will depend on the melting-points of the isomerides, the composition of the liquid mixture, the velocity of isomeric change, and the rate of Cc F N 6 p E » G b MN 3 m O A COMPOS/T/ON 8 cooling. The temperature G at which one form is in stable equilibrium with the liquid mixture is called the ‘equilibrium temperature,’! and is readily determined as the temperature at which the substance remelts after fusion. 3. Fusion. Isomeric Change of Solids. Stability Limits.— Each iso- meride has a characteristic melting-point which is independent of isomeric change. The melting-point of the stable isomeride which separates first on cooling the melt is necessarily above the ‘equilibrium temperature,’ whilst that of the labile isomeride may be either above or below this temperature. In the case of (- and z-bromonitrocamphor the constants are :— Ly B m.p. of normal . 2 > . ’ se UE 2 m.p. of pseudo . 5 ; 2 : i F429 132° ‘equilibrium temperature . J - . 124° 100° the pseudo being the stable form in each case. When the melting-point lies above the equilibrium temperature it can be observed by rapidly heating a crystal and noting the temperature at which it fuses ; if heated slowly the crystal may melt gradually at a temperature only just above the equilibrium temperature, but in this case the fusion is a consequence of isomeric change, and will take place more and more slowly as the purity of the substance is increased. If the melting-point lies below the equilibrium temperature the fused substance will (if sufficiently impure to permit of isomeric change) soon solidify owing to the separation of crystals ‘ Lowry, Trans, 1899, 75, 233, 218 REPORT—1904. of the stable isomeride, which will again melt when the equilibrium tem- perature is reached ; frequently the melting and resolidification proceed simultaneously, and only a slight sintering is observed in the neighbour- hood of the melting-point. Although in the liquid state each isomeride is equally labile when alone, and equally stable when equilibrium is attained, in the solid state only one isomeride can be stabie at any given temperature, namely that which has the least vapour pressure ; this is usually that which has the highest melting-point, but the opposite case is not infrequently observed. In the absence of a catalyst the labile isomeride may be preserved indefi- nitely, and may even be fused without undergoing isomeric change, but usually the change commences before the melting-point is reached, and at a temperature. depending on the amount of impurity present in the crystals. This temperature Knorr has described as the stability limit,! but it cannot be regarded as a physical constant of the substance as Knorr at first supposed, and his later work has shown that in the purified material the stability limit becomes identical with the melting-point.? 4, Dissolution.—Each isomeride has a true solubility which is inde- pendent of isomeric change, and may be determined by measuring the concentration of the solution obtained when the solid and solvent have been in contact during a period of time sufficient for saturation, but not long enough for isomeric change to produce any marked effect. Ultimately, however, a condition is reached in which the solution contains a stable mixture of the isomerides and is saturated with regard to one of them. The apparent or ultimate solubility® is thus dependent on the true solubility and the composition of the mixture in equilibrium. The measurement of the initial and final solubility affords a method of determining the composition of the mixture. Thus in the case of {-bromonitrocamphor the initial solubility at 10° C.is 2 grams per 100 c.c. of benzene, and the final solubility 8 grams per 100 c.c. ; and it may, therefore, be inferred that in the ultimate mixture the isomerides are present in the ratio 1 : 3 approximately. The method has the advantage of being applicable even when only one of the isomerides can be isolated. 5. Crystallisation from Solutions.—The form that separates first on evaporating or cooling a solution is that which has the smallest apparent solubility. Usually it will be the major constituent of the mixture, but the minor constituent may separate if its true solubility is small. Slow crystallisation will then result in complete isomeric change, whilst rapid crystallisation will yield a mixture from which the constituents can sometimes be separated by picking out the crystals mechanically. The order of solubility can sometimes be reversed by changing the temperature or the solvent, or both, and in this way it may be possible to isolate and purify more than one isomeride. Thus Dr. Whiteley has shown’ that the yellow hydroxylic modification of isonitrosomalonanilide separates from chloroform or benzene, but the white pseudoxime from ethyl acetate, methyl alcohol, ether, or acetic acid, HO.N :C(CO.NHPh), _, so (from hydrocarbons) + eal (from oxygenated solvents). C(CO.NHPh), 1 Ann. 1899, 306, 70 and 88. ? Wislicenus, ‘Ueber Tautomerie,’ footnote, p. 225. 3 Lowry, Trans. 1899, 75,231. 4 Lowry, Pree, 1903, 19, 156, 5 Trans. 1903, 88, 34. ON DYNAMIC ISOMERISM. 219 Precisely similar changes are observed in the case of isonitroso-p- chlorobenzyl cyanide, /Nul CLC,H,.C(ON) : NOH 2 CLC,H,.C(ON) € ‘ (2), which crystallises from alcohol or water in colourless needles, but passes into a yellowish-green isomeride when kept or when crystallised from petroleum. The sodium salt also exists in a colourless and a yellow form.' In a somewhat similar manner Tanret ? by crystallising from alcohol at a high temperature isolated a low-rotatory form of glucose isomeric with that which separates at ordinary temperatures. Piutti and Abati have recently prepared a white and a yellow modification of p-methoxyphenylphthalimide,? which they regard as merely dimorphous ; but the difference in colour and the behaviour on heating indicate that the two forms are probably dynamic isomerides, and may be formulated as the symmetrical and unsymmetrical imide, CO C,H C.H, aie N.C,H,.OMe 2 CO 2) we C : N.C,H,.0Me (colourless) (yellow). From boiling alcohol the yellow form separates, but the white form is stable in contact with benzene at ordinary temperatures. In the case of the reduced compound, p-methoxyphenyltetrahydrophthalimide, co O,H C,H, cay, N.O;H;.OMe 2 CO Xie *: © : N.C,H,.0Me, the white form crystallises from all solvents below 70°, and the yellow form above 70°; and this appears to be a fairly definite transition temperature. Polymorphism.-—If isomeric change is rapid the crystallisation of. dynamic isomerides obeys the same laws that govern the crystallisation of polymorphous substances, and it becomes very difficult to distinguish the two phenomena. In at least two important cases dynamic isomerides have been first described as mere polymorphs, and it is probable that in other cases the polymorphism is due to differences in molecular structure. A rearrangement of the molecules in the crystal can scarcely produce any marked alteration in colour, and a difference so striking as that between yellow and red mercuric iodide must be associated with some difference in molecular structure. 6. Physical Methods of Studying Dynamic Isomerism. Mutarotation.— (1) In some cases it is possible to determine whether a liquid substance is a single compound or a mixture of isomerides in equilibrium by calculating the physical constants of the possible isomerides and noting whether the substance gives a value agreeing with one of these or intermediate in magnitude. Unfortunately the constants that can be calculated are few in number, and do not vary much in isomeric compounds ; moreover, the accumulation of negative groups gives rise to abnormally high optical constants, and the observed values often lie right outside the calculated 1 Zimmermann, J. pr. Chem. 1902, ii. 66, 353. 2 CLR, 1895, 120, 1060. 3 Ber. 1903, 36, 1000. 220 REPORT—1904. limits. Statical methods of this kind are, therefore, of little use in detect- ing dynamic isomerism, and their chief value consists in the information that they give as to the constitution that must be assigned to the domi- nant form of the parent substance and to its isomeric derivatives. Thus Briihl,! by measuring the molecular refraction and dispersion, has shown that hydroxymethylene (formyl) camphor is mainly enolic, but its bromo- derivative has the aldehydic constitution ;— C : CH.OH Pepe. Cth | and, again, that ethyl camphocarboxylate is mainly ketonic, whilst its acetyl- derivative is enclic.? CH.CO,Et 0.CO,Et C,H, 7% HOSE pe Hold 8 LN | 8 co Perkin? has also made use of the magnetic rotatory power, a property that has the advantage of being much more sensitive to changes of structure; thus, whilst the calculated molecular refractions of the two forms of ethylic phenylformylacetate differ by less than 2 per cent., the magnetic rotations of the two possible forms of ethyl acetoacetate differ by 20 per cent. ; some of the results obtained by this method have already been indicated (p. 203). (2) An analogous method depends on the fact that the composition of the stable mixture may be influenced to a very considerable extent by physical condi- tions, and properties like the molecular refraction and the magnetic rotation which are normally almost independent of temperature, solvent, and concentration may vary widely when the material examined is an isodynamic mixture. Such variations may indicate the existence of dynamic isomerism,’ though similar effects are produced by reversible polymeric change and by association with the solvent. (3) A more sensitive method of detecting dynamic isomerism consists in following the physical changes which accompany isomeric change. In the case of a pure liquid compound the physical properties reach a constant value as soon as the temperature and other physical conditions are steady, but the existence of a time-factor is a sure indication of chemical change. Thus, when ethylic acetoacetate is distilled the proportions of the isomerides are altered, and some hours elapse before the substance recovers its normal density,” though the total change only amounts to 0:0013 gram per c.c. Since crystallisation normally results in the complete separation of one of the isomerides a maximum amount of isomeric change is observed when the crystals revert to the liquid state either by fusion or by dissolution. Thus it is sometimes possible by repeated fusion to follow the gradual fall in the melting-point as the homogeneous crystals revert to an equilibrium mixture, but usually isomeric change is so rapid that a single fusion is sufficient to bring about a condition of equilibrium. Dissolution has the advantage that observations can be made at atmospheric temperatures, and that isomeric change then proceeds much more slowly than in the fused state, but the properties of the solute are often very seriously 1 Zeit. phys. Chem. 1900, 34, 31-61. 2 Ber. 1902, 35, 3510. 3 Trans. 1892, 61, 801. 4 Perkin, Briihl, Joc. cit. 5 Schaum, Ber. 1898, 31, 1964, ON DYNAMIC. ISOMERISM. 221 disguised by admixture with the solvent. Thus it would be almost impossible to detect with certainty the slight change in density or refrac- tive index which would result from a partial isomeric change in solution, and the change in magnetic rotatory power, though still appreciable, would be much smaller than in a fused substance. For this reason the method of dissolution only gives the best results when the physical property utilised has a zero value in the case of the solvent, and differs considerably in the different isomerides. These conditions are fulfilled by (1) conductivity, (2) optical rotation, (3) solubility, (4) colour. The electrical conductivity has been used with remarkable success by Hantzsch,! who has followed the gradual decrease of conductivity in solutions of the pseudo-nitroparafiins and similar compounds, freshly prepared by mixing a solution of the sodium, barium, or silver salt with a mineral acid-—e.g. :— * atin sit +-— —i+ H Cl+CH,.CH : NO, Na2.Na Cl+CH,.CH : NO, H ete 2Na 'Cl+CH,.CH,.NO,. Unfortunately the method is somewhat limited in its application, and cannot readily be applied to substances that are insoluble in water, or are only feeble electrolytes. Perhaps the most generally applicable method is that which consists in observing the mutarotation of freshly prepared solutions of optically active bodies. The isomerides usually differ widely in rotatory power, and observations can be made in any solvent and in fairly dilute solution. The rapidity and accuracy with which measurements can be made render it possible to detect changes involving only a small percentage of the material or taking place so rapidly that equilibrium is reached in the course of a few minutes. Moreover, the conditions are such that the behaviour of highly purified materials can be successfully investigated. The method has already been applied in a large number of typical cases, and can be extended to nearly every type of isomeric change. Hitherto the solubility has only been utilised in a limited number of cases,” but the method, though more tedious and perhaps less accurate than those just described, is even more widely applicable, and has the unique advantage that it gives information as to the proportions of the isomerides in solution, even when only one of these can be isolated. The recent observations of Dobbie, Lauder, and Tinkler on the ultra- violet absorption-spectra of cotarnine * show that colowr may be made the basis of a quantitative method, and the valuable results that have been obtained justify the hope that the method will be applied in many other cases. 7. Colour,—As a qualitative method the colour of dynamic isomerides has proved most valuable in indicating the occurrence of isomeric change, and it has the unique merit of rendering visible to the eye the progress of isomeric change both in the solid and in the liquid state. Moreover, since it has become possible to associate colour with definite types of structure, and even roughly to predict the probable colour of a compound having a given formula, it is often possible to determine, by means of the colour, the constitutions that must be assigned to a series of solid 1 Ber. 1896, 29, 699, 2256; 1899, 32, 607, 628, 641. 2 Lowry, Proc. 1993, 19, 156; Proc. 1904, 20, 108. 3 Trans. 1903, 88, 598. 929, REPORT—1904. isomerides. Thus it is noteworthy that the earliest indication of the possible existence of hydroxylic pseudonitro compounds was based upon observations of colour-change, and the suggestion made by Armstrong in 1892,! in order to account for the coloured salts of the nitrophenols, has been abundantly justified by the subsequent investigations of Nef, Hantzsch, and others. According to this view the colourless ethers have formule of the type EtO.C;H,.NO,, whilst the coloured salts are formulated as O:C,H,:NO,K ; in the liquid state the nitrophenols themselves may exist in both forms, HO.C,H,.NO,50 : C,H, : NO,H, but the colourless needles of p-nitrophenol must be represented by the first, and the quinone-like crystals of o-nitrophenol by the second formula. Again, of the compounds represented by the formulee— NH (1) HO.C,H,NO (2) 0: C,H,: NOH (3) O: CHL | 6 the first should be blue or green like the o and p ethers, MeO.C,H,.NO ;* the second should be red like the sodium salt, O:C,;H,: NONa, or yellow like the benzoyl- derivative O: C,H, : NOBz, whilst the third should be colourless like the pseudoquinols. The substance produced by the action of nitrous acid on phenol or of hydroxylamine on quinone separates from ether in green flakes, and gives a green solution in water, alcohol, or ether, which must contain at least a considerable proportion of the nitroso- compound (1); the colourless needles which separate from aqueous solution may be a dimolecular form of the nitroso- compound (p. 224), but must otherwise be represented by the third formula. The difference in colour between the yellow hydroximes and the colourless pseudoximes, observed by Dr. Whiteley in the derivatives of isonitrosomalonamide, has already been referred to ; a similar explanation may be given of the colour-changes observed in violuric acid and its salts (Hantzsch and Isherwood), and in ethylic isonitrosocyanacetate and its salts * NH HON : C(CN).CO,Et Aes DO(EN).COLEt 5 Qe in each case, however, the authors regard the coloured compounds as —C—O containing the group | | though this group would scarcely be —C—N.OH, likely to give rise to colour. 8. Absorption Spectra.—Whilst valuable results are obtained by merely noting the colour of dynamic isomerides, data of much greater 1 Proc. Chem. Soc. 8, 101. 2 Baeyer and Knorr, Ber. 1902, 85, 3034. 3 Miiller, Bull. Soc. Chim. 1902, iii. 27, 1019. ON DYNAMIC ISOMERISM. 293 value are afforded by a detailed study of their absorption spectra. Attention has already been called to the observations of Hartley and of Dobbie and Lauder, but further reference must be made to the recent work of Baly and Desch.! These authors have shown that neither of the ethyl- derivatives of ethyl acetoacetate give absorption bands, and con- clude that the absorption of light by ethyl acetoacetate depends directly on the occurrence of oscillatory isomeric change. They even suggest that the intensity of the absorption band is a direct indication of the rate at which the reversible isomeric change is proceeding. This theory of the origin of colour is in accord with the fact that nearly all coloured substances can be represented by two formule, and that colour is most frequent amongst aromatic compounds in which a migration of the linkages is of frequent occurrence. If this view should be confirmed by subsequent observations it would form a most important application of the theory of dynamic isomerism. 9. Luminosity—Whilst colour may perhaps depend only on the selective absorption of light-energy by certain groups of atoms, many of the phenomena of luminosity appear to be directly due to the inter- * conversion of dynamic isomerides.” The simplest of these is the flash of light that is sometimes observed when a crystal is crushed or powdered, and which in organic compounds is usually associated with one of the structures that give rise to dynamic isomerism. Thus saccharine and menthylphenylformylacetate, which give an exceedingly brilliant flash,* are normally ketonic compounds, though their solutions may contain a trace of the labile enolic isomeride 1 o,f SN tty $0, ‘so, 7 CHO.CHPh.CO.R < HO.CH : CPh.CO,R. During rapid crystallisation a small amount of the enolic form may be entangled in the crystals, and the flash of light appears to be due to the energy liberated when the labile form undergoes isomeric change at the moment of crushing. Fluorescence appears to be a modification of this phenomenon in which the labile isomeride is continuously reproduced by the action of ultra- violet light, and phosphorescence may be regarded as fluorescence taking place in a viscous medium which will only permit a gradual rever- sion to the stable form. The relationship between fluorescence and dynamic isomerism has been discussed by Hewitt, and the nature of phosphorescence may be illustrated by reference to the ketones, which become brilliantly phosphorescent after exposure to ultra-violet light at low temperatures (Dewar), probably owing to the liberation on warming of energy stored up at low temperatures in the labile enolic form. VIII. Reversible Polymeric Change. Reversible polymeric changes obey nearly all the Jaws that govern reversible isomeric change, and give rise to phenomena similar to those that have been described in the preceding sections. But whilst reversible 1 Trans. 1904, 85, 1029. * Armstrong and Lowry, Proc. Roy. Soc. 1903, 72, 258. 3 Pope, Trans. 1895, 67, 985; Lapworth, 77ans. 1902, 81, 1495. * Proc. Chem. Soe. 1900, 16, 3; Zeit. phys. Chem. 1900, 84, 1. > <— > 924 REPORT—1904. isomeric changes are limited to a comparatively small group of substances, reversible polymeric changes occur very frequently, not only in complex organic compounds, but also in the simplest inorganic substances, includ- ing even the elements. Perhaps the most notable difference consists in the fact that equilibrium is largely influenced, and indeed mainly deter- mined, by the temperature and pressure, conditions which produce only small changes in the equilibrium between dynamic isomerides. In most cases equilibrium is attained almost instantaneously. The properties of freshly melted ice are perfectly normal, and the depolymeri- sation of NO, is so rapid that it is not possible to detect any time-factor. Amongst organic compounds, however, gradual changes have occasionally been noticed. Formaldehyde shows a slow decrease of molecular weight in freshly diluted solutions,! and freshly diluted or freshly cooled solutions of gelatine only slowly assume their normal viscosity, The most striking examples of gradual changes of this type are to be found amongst the organic nitroso- compounds which exist in a blue or green monomolecular and a colourless dimolecular form.2 In the case of nitrosobutane, CMe.,;NO, Bamberger and Seligman* have plotted a complete curve showing the gradual depolymerisation in a solution in benzene at the freezing-point ; equilibrium is reached in four hours, and the decrease of molecular weight proceeds simultaneously with the development of the blue colour. There is reason to believe, however, that under favourable conditions gradual association and dissociation are not infrequent amongst simple inorganic compounds. Only in this way can the remarkable facts be explained that have been noted by many observers in studying the critical phenomena of gases, and to which attention has recently been called by Traube.t Thus, when liquid carbon dioxide is heated above its critical temperature, the upper and lower layers of gas, though easily miscible, remain distinct for a considerable period of time, and only gradually diffuse into one another. Under apparently identical conditions the density of the gas may vary in the ratio of 1 : 2°16. So also when the gas is cooled from above its critical temperature, neither the liquid nor the vapour has at first its normal density ; the meniscus is gradually dis- placed through several centimetres, equilibrium being attained only after a week has elapsed. Traube explains these results by assuming the existence of ‘ gasogenic’ and ‘liquidogenic’ molecules, but the variation of physical properties with time, to which reference has been so frequently made in the preceding pages, affords clear evidence of the occurrence of chemical change, and it can scarcely be doubted that the phenomena, uf not due to inequalities of temperature or pressure, afford indications of a reversible polymeric change similar in character to, but slower than, those which take place so rapidly in the case of water and of nitrogen peroxide. ' Inaug. Diss. Rostoch, Eschweiler ; Abst. 1890, 954. * Meyer, Ber. 1888, 21, 507; 1896, 29, 94; Thiele, Abstr. 1894, i. 217; Baeyer, Abstr. 1894, i. 252; Piloty, Ber, 1898, 81, 218, 221, 452, 457, 1878; 1902, 35, 3113; 1903, 36, 1297; Schmidt, Ber, 1903, 36, 1765; Bamberger and Rising, Ber. 1901, 84, 3877. 3 Ber. 19038, 36, 689. * Ann. d. Physik, 1902, 8, 2, 267. MOVEMENTS OF UNDERGROUND WATERS OF NORTH-WEST YORKSHIRE. 225 The Movements of Underground Waters of North-west Yorkshire.— Fifth Report of the Committee, consisting of Professor W. W. Warts (Chairman), Mr. A. R. DwerryHousE (Secretary), Pro- fessor A. SMITHELLS, Rev. E. Jones, Mr. WaLTerR Morrison, Mr. GrorGE Bray, Rev. W. Lower Carter, Mr. T. Fatr.ey, Professor P. F. KENDALL, and Dr. J. E. Marr. Tae Committee are carrying on the work in conjunction with a committee of the Yorkshire Geological and Polytechnic Society. It will be remembered that at the Southport meeting the Committee reported that the work of tracing the streams sinking on the slopes of the Ingleboro’ massif was complete, with the exception of a few small streams, These have now been traced, and the work of the Committee is there- fore completed, with the exception of the boreholes at Turn Dub men- tioned below. The work done during the current year consists of tracing the fol- lowing streams by means of fluorescein. East Side of Ingleboro’. 1, The stream sinking at P 14,' near the shooting-box on the Allot- ment, which had been unsuccessfully tested on several previous occasions, was found to issue at Austwick Beck Head (S 28). 2. A small stream to the north of last, sinking at P 18, passes by P 19, where the fluorescein was visible, to S 40, there joining the water from P 25 and P 26, previously tested. 3. The small stream sinking at the ‘Washfold’ (P 52) on Park Fell was found to communicate with the channel from Alum Pot to Footnaws Hole (S 65), where the water was strongly coloured three days after the fluorescein was introduced at P 52. Footnaws Hole, as has been pre- viously shown, discharges in normal weather at Turn Dub (S 67). West Side of Ingleboro’. 4. P93. The water from a group of small streams near Douk Cave on Fenwick Lot, Souther Scales Fell, flows underground along the direc- tion of the master joints in the limestone, and issues at S 106a, a small spring below Eller Keld. 5. The water from P 97 and P 98 on Souther Scales Fell flows to a small spring and cave known as Far Douk, but not marked on the 6-inch Ordnance Map, P 95a, and then again goes underground to join the river, somewhere on its underground course from Weathercote Cave to God’s Bridge. 6. P 101 and P 102 on Black Shiver Moss receive the waters of two small streams, the flow being to the lower end of Mere Gill Hole, where it joins the waters of Mere Gill, and again goes underground. The further course of this stream has been described in a previous report. 7. P 102a on the eastern edge of Lead Mines Moss, not marked on the 6-inch map, receives a small stream in wet weather only. This, on being tested with fluorescein, was found to communicate with S 116 near the ‘ Engine Sheds’ at the Ingleton Granite Quarries. ' The letters and numbers refer to maps published in the previous reports of the Committee. 1904. Q 226 REPORT—1904. A number of boreholes have been put down in the neighbourhood of Turn Dub (see previous reports), the result being that a thickness of from 7 to 8 feet of boulder clay has been proved below the present river-bed. This, it is considered, is sufficient to account for the passage of the underground water below the surface stream. The boreholes are still in progress, and the Committee therefore seek reappointment, with permission to retain the unexpended balance. A full account of the work of the Committee will be published in the Proceedings of the Yorkshire Geological and Polytechnic Society. Life-zones in the British Carboniferous Rocks.—Report of the Com- mittee, consisting of Dr. J. E. Marr (Chairman), Dr. WHEELTON Hinp (Secretary), Mr. F. A. BatHer, Mr. G. C. Crick, Dr. A. H. Foorp, Mr. H. Fox, Professor E. J. Garwoop, Dr. G. J. HinpeE, Professor P. F. Kenpatu, Mr. R. Kinston, Mr. G. W. LamPLuGH, Professor G. A. LEBour, Mr. B. N. Peacs, Mr. J. T. Stopss, Mr. A. Srrawan, and Dr. H. Woopwarp. (Drawn up by the Secretary.) TuE Secretary once again regrets that he has received no reports from the large majority of the members of the Committee. Work has been done by Mr. J. T. Stobbs in three districts. He has again generously given his time, and therefore the grant is only debited with travelling and out-of-pocket expenses. It was found impossible owing to mining difficulties to work the marine band which occurs in the North Staffordshire Coalfield below the Gin Mine coal. But for the sum of a few shillings a trench was dug across the strike and the beds were exposed in succession. The marine band was exposed and some few fossils were collected, but the bed was much weathered by proximity to the surface, and it was found inadvisable on this account to make any prolonged search for fossils. However, the position of the marine band with regard to the Gin Mine coal, a subject on which in the course of years a curious error had arisen, was definitely settled. Sections and a list of fossils obtained are given in Mr. Stobbs’s report. ‘ As excavations for waterworks were being carried on in the Valley of the Derwent Mr. Stobbs went there to examine the cuttings in the Pendleside Series, the upper portion of which was then exposed. A detailed report follows. It was also thought good to examine the northern boundary of the South Wales Coalfield, and as far as possible to collect from the small coal workings, confined to single seams. In the recent resurvey of the South Wales Coalfield paleontology does not seem to have had the attention paid to it which it deserves. The grant therefore has only been partially used, and the Committee ask that the balance may be retained for future work. Personally, while collecting in the Carboniferous district of the Midlands, the Secretary has been examining the Devonian Carboniferous succession in the south-west of Ireland and North Devon, the results of which are expressed in a paper published in the ‘Geological Magazine’ for August 1904. It is well known that the Carboniferous Limestone in South-west LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 227 Treland gradually dies away south-west of Cork, and in the succession at Old Head of Kinsale, and from that point westward no Limestone whatever occurs, but instead there is a thick mass of Grits and Slates, which have been called Lower Limestone Slates and Coomhola Grits. It is also known that the passage up from the Devonian Grits to Coomhola Grits is unbroken, and that the one series has no top and the other has no base. The Coomhola Grits are, however, fossiliferous and contain shells referred to Ptychopteria Damnonensis, Cucullea uni- lateralis, species which occur in the Pilton and Marwood series of Devon- shire. These beds are always classed as Upper Devonian in England, and therefore it would be well for the same line to be drawn in Ireland. The whole fauna from the Coomhola Grits should be re-examined, because I think it probable that trilobites and other species have been referred to Carboniferous forms on the supposition that the Coomhola beds were Carboniferous. The Coomhola Grits are overlaid by the Lower Carboni- ferous Slate, part of which is indeed of Carboniferous age, because it contains Posidonomya Becheri. Here then is a point of great interest. Beds with a Marwood and Pilton fauna are overlaid by grey shales and then by black with P. Becher; and in North Devon the Pilton beds are succeeded by the Lower Culm with P. Becheri in abundance in the Venn Limestones. In both districts the Devonian Carboniferous succession, apparently unbroken and conformable, is from Marwood and Pilton beds to Pendleside Series, the Carboniferous Limestone being absent in each locality ; and if there is no unconformity it follows that the Carboni- ferous Limestone was never laid down in the North Devon, Cork, and Kerry latitude. Jukes considered that the Carboniferous Slate of South-west Ireland was contemporaneous with the Carboniferous Limestone, and his views are given at length, pp. 33-37 of the ‘ Memoir of the Geological Survey’ (Ireland), Explanations of Sheets 187, 195, 196 of the maps. He visited North Devon and says: ‘TI saw that both lithologically and palzontologically, bed for bed, and fossil for fossil, the Braunton and Piltown rocks of Devon were identical with the Carboniferous slate of Cork. The Marwood sandstones and the grey grits below them that form.Baggypoint were obviously the same as our Coomhola Grits, and the red and green rocks that rise up from beneath those rocks in Morte Bay are exactly similar to the Upper Old Red Sandstone of large parts of the west of County Cork. ‘But the Coal Measures’ (by which I suppose he means the Culm, and I would that all subsequent geologists had recognised the Coal Measure horizon of these beds) ‘of Devon rest on the Carboniferous slate without intervention of any Carboniferous Limestone in its ordinary form, often without any appearance of limestone at all.’ But he carries his argu- ment too far, for he goes on to say: ‘If, however, we have Coal Measures above and Old Red Sandstone below, the rocks between them must be of the age of the Carboniferous Limestone.’ The Lower Culm is, I am convinced, of later age than the Carboniferous Limestone, and is the homotaxial equivalent of the Pendleside series, How comes it, therefore, that the Coomhola Grits and the grey portion of the so-called Lower Carboniferous Slate are mapped as Carboniferous instead of Upper Devonian ? The view advanced by Jukes, that the Carboniferous Slate is con- ‘emporaneous with the Carboniferous Limestone, is probably correct, the Q2 228 REPORT—1904. slate consisting of two portions—the lower grey or Upper Devonian, the upper black or Pendleside or Upper Carboniferous. There is no evidence of an overlap, but it must be remembered that the rocks of South-west Cork are nearly vertical, and have been much moved, and I believe the Upper or Posidonomya beds and part of the Carboniferous Limestone is a synclinal with the limbs absolutely in contact, so that the beds in the centre are doubled on themselves. During last winter Mr. J. G. Hamling, F.G.S8., of Barnstaple, kindly sent me for examination a large suite of fossils collected from the Coddon Hill beds of the Lower Culm. These so interested me that I felt it neces- sary to visit the locality, which I did under his skilled guidance. The Lower Culm of North Devon consists of two series of rocks, neither of them apparently very thick, but much folded and repeated. The Coddon Hill beds are thin laminated, white or fawn-coloured silicious beds, with the following fauna :— TRILOBITES— *Phillipsia polleni? . : , : ‘ . H. Woodward. - spatulata . : : . P . H. Woodward. Proétus coddenensis . : : : : . H. Woodward. *Paleacis humilis - : d : . Hinde. Plewrodictywm dechanianum : 3 . Kayser. Petrea, ck. P. pauciradialis : : ~ éehillsp; * Productus plicatus . : : : : . Sarres. * Chonetes laquessiana . E E : : . de Kon. * Ortholetes crenestria . ; : : ; . Philly sp: *Athyris ambigua. ugk olecanites compressus . - ; : - Sow., sp. + mivololus ‘ ; ; : » }Phillsp: Sphc Be sp. *? Stroboceras sulcatus ‘ . ; . Phill. sp. * 2? Nomismoceras spirorbis. or ees *Chenocardiola footit . : ; : 5 . Baily, sp. Radiolarians. Crinoid stems. Those species marked with an asterisk (*) occur in the lower part of the Pendleside series. The other beds of the Lower Culm are the Venn Limestones, a’ series of black carbonaceous limestones, with Posidonomya becheri, Low. Glyphioceras crenistria, Phill., sp. Pseudamusiwm fibritloswm, Salter, sp. Py sphericum, Phill. sp. Glyphioceras spirale, Phill., sp. Orthoceras sp. It is a point of difference amongst writers on the Culm as to whether the Posidonomya limestones are above or below the Coddon Hill beds. I believe for stratigraphical reasons that the Coddon Hill beds are at the base and the Venn Limestones succeed them, and also because the Paleontological succession in Derbyshire has beds with Prolecanites compressus at the base and Posidonomya Becheri immediately above them. In my paper in the ‘ Geological Magazine,’ op. ae cit., I have - gone into the stratigraphical question in detail. Immediately overlying the Postdonomya beds, if I am correct, are a series of Middle Culm grits, with occasional vegetable remains, what I consider to be the homotaxial equivalents of the "Millstone Grit, because they are intercalated between beds with Prolecanites compressus and Posidonomya Becheri and the series of clays and shales which are well a LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 229 seen at Instow, where in a bed of calcareous bullions the following fossils occur :— Gastrioceras listeri, Mart., sp. Pterinopecten papyraceus, Sow., sp. ; carbonarium, Vv. Buch. Posidoniella levis, Brown., sp. Dimorphoceras gilbertsoni, Phill. Celacanthus elegans, Newb. Orthoceras sp. Hlonichthys aitkeni, Traq. The fauna is one which I regard as characteristic of the marine part of the Gannister Series of the Lower Coal Measures. The beds above the Instow series have a wonderfully familiar appear- ance to one acquainted with the Coal Measures, and I am glad to say that Mr. E. Newell Arber has read a paper at the Royal Society which conclusively proves from the flora contained in them that the Culm- bearing series round Bideford is of Middle Coal Measure age. This is borne out by the occurrence of Carbonicola acuta at Roberts quarry, near Bideford, immediately above a rich plant bed, with well- preserved Middle Coal Measure ferns. It must remain at present an open question whether the Carboniferous Limestone is represented in the Culm series by a few feet of calcareous shales and a band or two of limestone, which is seen on the foreshore near Fremington Station. The limestone also being exposed at Fremington Pill Quarry is open to question. The shales on the foreshore contain species of Brachiopoda, which are common to the Upper Devonian and Lower Carboniferous. There are, therefore, four life-zones in the Culm— Zone of Carbonicola acuta and Zone of Posidonomya becherv. Middle Coal Measure plants. » Prolecanites compressus. Zone of Gastrioceras listeri and G. carbonarium. which definitely fix the age of the Culm of North Devon. This fossil evidence is of importance from an economic view, for it definitely shows that the beds of Culm are the representatives of the coal seams, and that any occurrence of coal in Devonshire is altogether improbable. The line of strike of the Mendip anticlinal and the Coddon Hill series have a similar relation to each other that the Carboniferous Lime- stone of Cork and Killarney has to the Devonian Carboniferous succession of the Old Head of Kinsale and Coomhola, and the absence of Carboniferous Limestone south of a fairly definite line is noticed in Devonshire and South-west Cork and Kerry. This condition of things points to a similarity of physical causes in both areas. An important paper by Mr. Vaughan, F.G.S., ‘On the Paleontological Sequence of the Carboniferous Limestone of the Bristol Area,’ was read before the Geological Society in June. The paper is not yet published, and I hesitate to criticise it ; but in any Carboniferous area with which IT am acquainted the fossils chosen by Mr. Vaughan as denoting zones and sub-zones—with one exception, that of Modiola lata, a variety probably of M. macadami—all occur together at several horizons. To quote 3.— Productus semireticulatus, P. cora, Schizophoria resupinata, and Spiriferina octoplicata occur practically at all horizons in the same beds. It is, however, a subject of congratulation that work is being com- menced on palzontological lines in the Bristol and Mendip area. The zonary divisions established by Mr. Vaughan are given in the following table. (This is the form in which these divisions are finally set out after emendation and further revision of a preliminary working system.) 230 REPORT—1904. Zones Sub-zones and Horizons € D,) Lonsdaleia floriformis. PSOE ENTE ; : { D,) Dibunophyllum cylindricum. VISHAN SEMINULA . ( ( (S,) Productus cora (mut.). (S,) Productus semireticulatus. Nive 5 (Caninia- (C) Syringothyris, sp. nov. Zone.)" | { (Z,) Schizophoria resupinata. ee ' | | (2) Spirifer aff. clathratus. TOURNAISIAN { (K,) Spiriferina octoplicata. DEEEEOBOP A) 2 . ; 1 (RK) Productus, sp. nov. a MopIoLa . ‘ : . (M) Modiola lata. | For example: Productus Cora, P. semireticulatus, and Schizophoria resupinata range as high as the upper 300 feet of the Pendleside Series in Cheshire. The first two fossils occur in the Calciferous Sandstone Series of Fife, P. Cora in the Ardens limestone, and P. semireticulatus and Schizophoria resupinata all through the Calciferous Sandstone Series. All three of these fossils occur throughout the Yoredale Series of Wens- leydale. Spirvferina octoplicata is found with all the above species at Castleton and Park Hill, Derbyshire, in the upper beds of the series, and in Fife is found throughout the Carboniferous Limestone Series and as low down as the encrinite bed in the Calciferous Limestone Series. Lonsdaleia floriformis is not found in the upper beds of the limestone in Derbyshire, but in the main or great limestone of Weardale occurs with the three forms of Brachiopoda mentioned above. Dibunophyllum cylindricum occurs in the Lower Limestone Series of the West of Scotland with Lonsdaleia floriformis, and also some way down in the Upper Limestone Series of the North-west of Ireland. It will be a curious anomaly if the distribution of the species in the isolated patch of Bristol and the Mendips is totally different from that which obtains in all other districts of Great Britain. Up to the present I have looked in vain for any species of organism which denotes a definite Horizon in the Carboniferous Limestone Series of Great Britain. It must be noted that in Belgium the Viséan is characterised by the presence of Productus giganteus, a shell absent in the Tournaisian. 1 Employed throughout the preliminary working system. LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 231 In the Midlands and Scotland P. gigantews occurs throughout the whole of the Carboniferous Limestone Series, which makes it doubtful whether there is any representative of the Tournai Limestone there. In a paper published in the ‘Geological Magazine,’ December 4, vol. v. p. 61, I referred to the anomalies of distribution throughout the Carboniferous deposits of Europe of the various species of Brachiopoda which have been stated to denote various horizons in Belgium and Russia. Owing to the deep trenching, necessary for the construction of a reservoir by the Derwent Valley Water Board in N. Derbyshire, an unusual opportunity was presented of examining the upper portion of the Pendleside Series, which consists mainly of dark laminated shales and thin sandstones. By the favour of Mr. E. Sandeman, M.Inst.C.E., we were enabled to inspect the sections and the material which was being excavated on a large scale, and to collect therefrom. The lower trench, where the work of excavation was mostly proceed- ing at the time, cuts at right angles the bottom of the valley of the river Derwent, a little to the south of Hollinclough Farm, and the following section was exposed at this point :— Fie. 1. ft. in. 1. Shales 7% 0 2. Grit 2 9 RK“ 8. Shales, with five thin grit bands . Re 4 6 QA QQY si : 5. Shales 29 6. Grit vf 7. Shale 4 0 8. Grit 1.3 9. Shale 3 0 10. Grit 6 11. Shale 5 12, Grit 5 13. Shale 932 REPORT— 1904. LAER 14, 15. 16. 17. 18, 19, 43. . Grit : . Compact shale . Argillaceous sandstone . . Shale . Grit . Compact shale . Thinly bedded grit . Micaceous shale, . Grit - “sue ieee or = fel) . Shales with lenticles of grit . . Grit . Shale with thin pipes bi coal . Grit . Shale . Grit . Shale . Grit in three beds . ‘ . Grit . Micaceous shale . Grit . Shale . Grit . : . 5 . . . DSS NEO RAs we : . Shale with nodules . - 3 “ \ Grit Shales Grit, with large caleareous bullions Shale, with large calcareous bullions . Grit Micaceous shales . —= Micaceous shale ft. in. ow Oo e = oO oOo Be oOO o co ao ance _ a o 10 oo Base not seen. LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 233 The bed ‘ 15. Shales’ was highly fossiliferous, yielding the following forms :— Orthoceras sp. Pterinopecten papyraceus, Calamites sp. Goniatites, indeterminable species of. Postdoniella levis (large). Resting on ‘18. Grit’ were numerous large ellipsoidal calcareous bullions, some of which measured 2 ft. 6in. and 1 ft. 6 in. along their major and minor axes respectively. Asa rule the bullions contained numerous goniatites, and in one of them was found a fine specimen of Acrolepis Hopkinst. In ‘17. Shales’ Posidoniella levis and Glyphioceras reticulatum were fairly abundant. From ‘ 21. Shales’ Glyphioceras reticulatwm was collected. ‘25. Compact shale’ contained large Pterinopecten papyraceus and Posidoniella levis in great numbers. ‘27. Micaceous shale’ contained Pterinopecten papyraceus, Posidoniella levis, Orthoceras sp., and Goniatites of indeterminable species. In the middle of ‘29. Shale’ was a layer containing Pterinopecten papyraceus. ‘33. Shale’ contained Glyphioceras reticulatum. ‘35. Shales with lenticles of grit’ were very fossiliferous ; Posidoniella levis, Pterinopecten papyraceus, Glyphioceras reticulatum, and Goniatite sp. were collected. ‘41. Shale’ contained Calamites sp. ‘43, Micaceous shale’ contained fragmentary plant remains. The upper trench had been similarly cut across R. Derwent, a short distance above the Abbey Farm, in measures higher in the series, where the shales were thinner and the grits were thicker and formed an increasing proportion of the strata. The succession revealed by these two trenches corresponds with the shales and sandstones towards the base of the eastern scarp of Mam Tor, near Castleton, Derbyshire. The difficulty in getting continuous sections of Pendleside shales, owing to their disturbed character and to the fact that they are commonly exposed at the bottom of valleys, has been frequently observed. Some light was thrown on the subject by the position of the beds in these trenches. Figs. 2 and 3 show the relation of these disturbances to the valley and hills, as seen in the lower trench, the same general features of which were to be observed in the upper trench also. The distance between the two trenches, measured in a straight line, is about 1# mile, and the strata forming the bed of the river are thrown into an anticlinal fold with subsidiary wrinklings in both instances. These foldings are shown in fig. 3 to be confined to the strata near the surface, which consist of the softer and more incoherent shales, whilst the hard and thick grit (No. 42 in fig. 1) may be observed to have resisted the crush movement and forms a fairly level floor to the excavation. An examination of the ground renders improbable the idea that both the trenches intersect the same anticline, and remembering that both sections occur at the bottom of deep and narrow valleys one is forced to regard the ‘ wrinkle’ and the valley itself as being related in some way a8 cause and effect. There can be no doubt that considerable ‘side- thrust’ would result from the weight of these hills, which naturally would make itself felt most on those beds forming the bottom of the valley, 234 REPORT—1904. which would, if insufficiently rigid, be crushed and crumpled, and thus prepared for rapid erosion by the stream or river. So that whilst in the Hig. 2. ue. LE no 42 Grit. (Fig.t) Scales : Horizontal, 12 inches per mile. Vertical, 400 feet per inch. early stages the incipient valley induced the side-thrust of the hills, and the consequent ‘ crushing’ of the measures in the way indicated, the latter Fig. 3. has undoubtedly reacted by powerfully promoting the deepening of the valley. Fig. 4. E Nettlebank Pec Scale : 2 chains per inch. In the North Staffordshire Coalfield it was deemed desirable to find the outcrop of a rich marine bed known to exist about the horizon of the LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 239 Gin Mine Coal. Permission to cut a trench for this purpose on their estate near Smallthorne was kindly given by Messrs. R. Heath & Co., to whom we are under great obligation. Our thanks are also due to Mr. W. Lockett for assistance and advice. The horizon was reached and its relation to the coal seam, and also its succession of life-forms, exactly made out. This was of great importance, since our previous conceptions required inversion. It was rather dis- appointing, however, to find the richest part of the horizon, consisting of a very impure and earthy limestone, to be so decomposed on the hillside, where we were working, that the fossils were incapable of preservation, and often of identification. So that the proposal to work the bed on a larger scale at this point was abandoned. The general section is shown in fig. 4, and the following is the succession of the measures constituting the ‘ marine bed,’ together with the fossils restricted to each stratum, so far as could be ascertained, viz. — ft. (1) Dark shale (2) Impure limestone é : : ; Fe (3) Dark shale . : : , ‘ : 2 oy hi Cons (1) contains— Lingula mytiloides, Discina nitida. (2) contains— Productus semireticulatus, Athyris ambigua, Chonetes Laguessiana, Nucula gibbosa, Ephippioceras costatum, Raphistoma junior, Plewronautilus armatus, Pleuro- nautilus n. sp. (with tubercles). (3) (upper layer) contains— Archeocidaris Urei, crinoid ossicles, Loxonema sp., Turbonellina, cf. 7. formosa, Orthoceras pygmaeus, Pseudamusium jfibrillosum, Nuculana acuta, Ctenvdonta levirostris. At base :— Pterinopecten papyraceus, Posidoniella sulcata. In South Wales collecting was done on the northern outcrop of the Carboniferous rocks, and the opportunity was taken of examining the ‘patchworks’ of the Coal Measures in that district. There is no doubt that great discrimination and experience are required in collecting from ‘patchworks,’ and serious errors have arisen in the past from the work of spoil-heap collectors. This is the more to be regretted, since in no other circumstances do we find such a quantity of material available for search and inspection. Owing to the personal uncertainty as to the name of the coal seam from whose associated measures the fossils have been derived the position of the ‘ patch’ where they were found will be given in terms of latitude and longitude picked off the 1-inch Ordnance maps, so that the localities may ae assistance to other workers. The horizons will be taken in descending order. A few feet below the outcrop of the Soap-vein on the patchworks, 236 REPORT—1904. west of Rhymney (51° 45’ 35” N., 3° 18’ 5” W.), thereis a thin clayband ironstone which contains in great abundance— ? Scaldia minuta or Estheria. Naiadites ? This band should form a good index-bed. Lower down on the same patchworks, near the horizon of the Elled Coal, south of Brynpwllog (51° 45’ 45” N., 3° 18’ 0” W.) were found :— Anthracomya modiolaris (common). Carbonicola acuta. From the roof of the Ras Las Coal, No. 2 Pit, Fochrhiw, the following were obtained :— Carbonicola aquilina (common). Naiadites modiolaris. Naiadites carinata 5 From the patchwork near Dowlais (51° 45’ 35’ N., 3° 20’ 15” W.), at the horizon of the 9-foot coal, the following were collected :— Anthracomya modiolaris. Naiadites carinata (common). Carbonicola aquilina (common). The Ras Las Coal has been regarded as identical with the 9-foot coal, and the above lists support this correlation. At a level near Hirwaun (51° 45/5" N., 3° 31/5" W.), about the horizon of the Cnapiog Coal, fine specimens of Carbonicola robusta were abundant. In the roof-shale of a thin coal (4 inches thick) which occurs above the grit overlying the engine coal, where it outcrops south of Clydach Colliery, the following plant remains were found :— In an exposure of black shales in the W. bank of R. Rhymney, a few yards north of Blaen Rhymney, were found— Anthracomya pumila. Beyrichia arcuata. Carbonicola acuta (numerous). Celacanthus lepturus. Naiadites modiolaris. These black shales are in the so-called Millstone Grit Series. In dark shales in the same series of rocks a horizon, about 15 inches thick, is exposed in the banks of the stream 8. of Garth (51° 46’ 15” N., 3° 20' 65’ W.), and contains— Carbonicola acuta (abundant). Carbonia sp. A little higher in the series and farther up the stream to the east, in dark shales, about 2 feet thick, the following list was obtained :— Solenomya primaeva. Edmondia sp. Ctenodonta laevirostris. Lingula mytiloides. Nucula aequalis. Higher again in the series, near Pitwellt Pond (51° 46’ 45” N ”? 3° 20’ 30’’ W.), another marine bed was seen, yielding— Lingula mytiloides. Posidoniella laevis. Quarries opposite Clydach on 8. side of R. Clydach showed the follow- ing sequence in the Carboniferous Limestone .— 1. Blue limestone in thick beds, with thin black shales intervening. 2. Purple and green marl with calcareous nodules, 15 feet thick. 3. White limestone, oolitic and very pure. —s LIFE-ZONES IN THE BRITISH CARBONIFEROUS ROCKS. 237 In the upper blue limestone, which is only used for road metal, the following were collected :— Productus hemisphericus. Lithostrotion aranaea, ee semireticulatus. * sp. Fenestella sp. In the intervening black shales were obtained — Leiopteria lunulata. Athyris ambigua. Productus margaritaceus. At a quarry at Blackrocks, in an oolitic portion of the limestone, is a grit bed containing— Athyris subtilita (abundant). Lithostrotion aranaea. 5 ambiqua. In some of the very thin black shales are— Productus hemisphericus. Athyris ambigua. In the limestone beds at Morlais Quarries were found— Productus cora (with spines). Euomphalus sp. Fe » (without spines). Bellerophon sp. Orthotetes crenistria. Lithostrotion sp. Spirifer sp. Fragments of Brachiopods. The limestone at Graig Fawr, near Cefn, contains in its upper beds— Myalina sp. Spirifer sp. Athyris ambigua (abundant). Huomphalus sp. Orthis sp Macrocheilina acuta. Orthotetes crenistria, Bellerophon sp. Productus cora (abundant). Archeocidaris Urei (plate). 3 giganteus (young). Crinoids. a longispinus. Whilst it would be premature to generalise from what has been done in South Wales, the remark may be ventured that in the Coal Measures, so far as the subject has been worked, there is to be observed the same order of succession of freshwater lamellibranchs which has already been found in the North Staffordshire Coalfield ; and mention may also be made of the apparent absence in South Wales of that fauna, which is so character- istic of the Millstone Grit Series of the Midlands, in rocks which are regarded as their equivalents, and which receive the same name. Erratic Blocks of the British Isles.—Ninth Report of the Committee, consisting of Dr. J. EH. Marr (Chairman), Professor P. F. KENDALL (Secretary), Professor T. G. Bonney, Mr. ©. E. De Rance, Professor W. J. Sortuas, Mr. R. H. Tippeman, Rev. S. N. Harrison, Dr. J. Horne, Mr. F, M. Burron, Mr. J. Lomas, Mr. A. R. DwerryuHouse, Mr. J. W. StatHer, Mr. W. T. Tucker, and Mr. F. W. Harmer, appointed to investigate the Erratic Blocks of the British Isles and to take measures for their preservation. (Drawn up by the Secretary.) THE most noteworthy records received during the current year are those which are furnished by Mr. J. Lomas from Northamptonshire, Leicester- shire, and Rutlandshire, the first and last mentioned counties appearing 238 REPORT—1904. for the first time in the reports of the Committee ; and the very interesting identifications of the source of certain beach-pebbles found near Cromer in the course of an excursion during the meeting at Cambridge. On this occasion Professor Sjogren and Professor Biackstrém, of Stockholm, identi- fied a number of Scandinavian rocks, most of which were well known to glacial workers in Yorkshire, though their place of origin was unknown. These rocks include a cancrinite-syenite from Sarna in Dalecarlia, Sweden ; quartz porphyry, also from Dalecarlia ; a fine-grained granitic rock which is a common and widespread type in Sweden ; sparagmite conglomerate from Scania; sparagmite sandstone and a series of hornblende-porphyrites from the Christiania district. Two pebbles were found, which the present writer identified as trachytes from the south-east of Scotland, a determination which was con- firmed by Dr. J. Horne, F.R.S. The discovery of a fragment of pecten in a gravel-pit at Thirsk, by Mr. J. E. Hall, of that town, is an interesting fact, as no shell-fragments had. previously been recorded so far down the vale of York. LANCASHIRE. Reported by Mr. J. Lomas, A.R.C.S. On banks of Yarrow River, above Simms’s Farm, Anglesark— Dalbeattie granite, 4 feet by 2 feet 6 inches by 1 foot 2 inches Winter Hill Stream.—1,120 feet O.D., boulders of Eskdale granite and Lake District andesites. New Road from Royston Cottage to Belmont.—1,100 feet above O.D. and over. Kinder Scout grit, very common, one 4 feet 6 inches by 3 feet by 2 feet 6 inches. Ditto, 5 feet 6 inches by 3 feet 6 inches by 4 feet. Silurian grit, 1 foot. Eskdale granite, 1 foot. Ganister, 2 feet. Lake District andesite. Among many hundreds of boulders examined were an enormous number of Carboniferous grits and sandstones, but no Mountain Lime- stone. NortTHAMPTONSHIRE. Reported by Mr. J. Lomas, 4.&.C.8. Gayton Clay-pit near Blisworth— Chalky boulder clay, containing Chalk (red and white), Chalk ammonites, flints (white, brown, and red), Bunter pebbles, Great Oolite, Keuper marl, Hannington (new well in field) — Chalk, grey flint, Carboniferous grit, Lias limestone, Great Oolite. Paine’s Siding, Glendon, near Kettering— In Chalky boulder clay many boulders of indurated Northampton Sands, some 3 feet in diameter; Trias pebbles, flints, Lincolnshire Limestone. ho (os) Ne) ON ERRATIC BLOCKS OF THE BRITISH ISLES. Rushton— Mountain Limestone, with encrinites and brachiopods. Carboniferous chert, Bunter pebbles, Chalk, and flints. North of Great Oakley— Mountain Limestone. Nortuampton.—Corby Brickworks.—Large proportion of Carboni- ferous boulders, including Mountain Limestone, chert, Millstone Grit, and ganister. Lias limestone, Great Oolite, indurated Northampton Sands, Trias pebbles, and one specimen of mica schist, 3 inches diameter. Reported by Professor P. F. KENDALL. Brick-pit near Racecourse (in Chalky boulder clay)— Spilsby sandstone. LEICESTERSHIRE. Reported by Mr. J. Lomas. East Norton Railway-cutting— Carboniferous Limestone. Millstone Grit. Carboniferous chert. Owston Gravel-pit— Chalk, flints, Lias limestone, Oolite, Bunter pebbles. Knossington.—Many boulders of Carboniferous limestone and Mill- stone Grit. Wymondham.—Old Brickworks near Station— Mountain Limestone, Chalk, flints, Bunter pebbles. Oolite, and many Lias limestones. Coston Bridge— Coarse dolerite, 3 feet diameter, Fine-grained dolerite, 1 foot diameter. Oolite, 2 feet diameter. Mountain Limestone. Marl-pit, near Saltby— Great number of Bunter pebbles, Oolite; no Lias. Quarry, behind Saltby Church (406 O.D.)— Lincolnshire Oolite ; no Chalk. Oolitic sandstone. Wykeham.—Felsitic ash from Charnwood, 2 feet 6 inches diameter. This boulder has been identified by Professor Bonney and is recorded in the Survey Memoir. 24.0 REPORT—1904. Near Grimston— Mountain Limestone, Millstone Grit, Bunter pebbles, Trias sandstone with concretions of barytes. Lias limestone; no Oolite. A few pieces of Chalk and flints. Ragdale— Many boulders of Mount Sorrel granite, several over 2 feet in diameter. Mill- stone Grit, Carboniferous sandstone, Lias limestone. Near Haby— Millstone Grit, Carboniferous sandstone and chert, Bunter pebbles, and a few flints. Thrussington Brickyard— Boulder clay, with Triassic matrix in which bands of selenite have formed. Numerous boulders of Keuper marl, with plant remains and pseudomorphs of rock salt. Bunter pebbles (some pitted), Lias limestone, no Oolite, Carboniferous lime- stone and chert Aylestone Sand-pit— Mount Sorrel granite, some with wind-etched surfaces ; Carboniferous Lime- stone and sandstone, Millstone Grit, much Keuper marl with pseudo- morphs and plants. A few Lias limestones and fossils; no Oolite. Coal; no Chalk. Blaby Clay-pu— Matrix of clay, almost pure Keuper marl, with bands of gypsum formed in boulder clay. Numerous Mount Sorrel granite, Carboniferous Limestone, Millstone Grit, Carboniferous sandstone, tea-green marls, Triassic sandstone with barytes. A few Lias fragments; no Oolite. Enderby Granite-works— Black Chalky boulder clay with Liassic matrix overlies, red boulder clay with Mountain Limestone, granite and other rocks from the West. Leicester Forest Brick-works— Red boulder clay with much Keuper marl, coal, Millstone Grit, Carboniferous sandstone, limestone and chert overlaid by Chalky boulder clay with Liassic matrix, Chalk, flints, and (?) Carboniferous sandstone. Thurmaston Brickyard— Red marly boulder clay at base with Carboniferous chert and limestone, Coal Measure sandstone and Millstone Grit, Keuper marls and Triassic sandstone, above Chalky boulder clay with many Liassic limestones and fossils. RUTLANDSHIRE, Reported by Mr. J. Lomas. Langham, near Oakham (in sewer cutting)— Middle Lias limestone, ON ERRATIC BLOCKS OF THE BRITISH ISLES. 241 Quarry, near Langham— Grown boulder clay with dolerite, oolitic limestone, Carboniferous Limestone and chert, Millstone Grit, Trias pebbles and flints. NorrFouk. Reported by Professor P, ¥, KenpDALt, Beach from Cromer to Mundesley— Rhomb porphyry; laurvikite (two varieties); cancrinite-syenite of Siarna, Dalecarlia, Sweden; quartz porphyry, Dalecarlia; fine-grained granite, Sweden; sparagmite sandstone, Scandinavia; sparagmite conglomerate, Scania, Sweden ; hornblende-porphyrite, Christiania district, Norway. YORKSHIRE BoutpEerR Committers, 1904. Reported by Mr. E. HAwKEsSWworTHh. Brompton and Osmotherley.— Between Brompton and Osmotherley, 3 miles N.E. of Northallerton, in sandy clay exposed in altering road— Whin Sill, Shap granite, Lake District voleanic series (several varieties), Carboniferous limestones and sandstones numerous, chert. Hutu Grotocicat Socrery BouLpDER CoMMITTEE. Tteported by Mr. G. W. B. Macrurx. Raywell, near Hull.—In connection with the making of the new reservoir at Raywell an interesting section has been exposed consisting of boulder clay, 10 feet thick, resting on chalk 230 feet O.D. The boulder clay appears to be in two divisions, a red upper clay and a blue or lead- coloured lower clay. Among the erratics the following was recognised :— Carboniferous Limestone, ganister, porphyrite, greywacke, basalt, &c. South Cave.—tIn the fieid adjoining the railway, 300 yards east of the railway station— Carboniferous Limestone, Lower Lias. Soft yellow sandstone, ganister, &c. Reported by Mr. Tuos. SHEPPARD. Kilnsea, near Spurn— Two Mammoth teeth. Reported by Mr. J. KE. Haut. Thirsk.—In the town gravei-pit— Fragment of Pecten. 1904. R 242 REPORT—1904. Photographs of Geological Interest in the United Kingdom.—Fifteenth Report of the Committee, consisting of Professor JAMES GEIKIE (Chairman), Professor W. W. Watts (Secretary), Professor T. G. Bonney, Professor E. J. Garwoop, Professor 8. H. REYNoLDs, Dr. Tempest ANDERSON, Dr. J. J. H. Traut, Mr. Goprrey BineLey, Mr. H. Coates, Mr. C. V. Croox, Mr. J. G. Goop- cHitD, Mr. WiLL1amM Gray, Mr. W. JERoME Harrison, Mr. Robert Kinston, Mr. J. Str. J. Puivuirs, Mr. A. 8. Rem, Mr. R. Wetcu, Mr. W. Wuraker, und Mr. H. B. Woopwarp. (Drawn up by the Secretary.) Tur Committee beg to report that once again the number of new photo- graphs received during the year exceeds that of any previous year. The accessions number 543; the total number in the collection is 4,314, and the yearly average rises to 287. About 100 other photographs have been received, but cannot be added to this year’s list. The geographical scheme annexed shows that four counties are removed from last year’s ‘black list’-—Cambridge, Kildare, Leitrim, and Wicklow having now made contributions to the collection. ‘There are still 21 non-contributing counties—two in England, one in Wales, seven in Scotland, and eleven in Ireland. To this year’s list Yorkshire makes, as so often before, the largest con- tribution, 243 ; Norfolk follows with 43, Kent with 31, and Pembroke with 30. Considerable additions are made to the lists of Buckingham, Northampton, Suffolk, Fife, Linlithgow, Renfrew, Cork, and Sligo. Previous Additions see Collection | (1904) Total ENGLAND— Buckinghamshire . - j 8 5 13 Cambridgeshire : ; ; -_- 2 2 Cornwall . * 3 5 : 57 10 67 Cumberland . - : é 43 1 44 Devonshire : : : . 178 2 180 Hampshire : ; : = 36 11 47 Hertfordshire . : ; 15 5 20 Kent : : c ; 3] 81 31 112 | Lancashire - é ‘ : 69 8 7 | Leicestershire . : ‘ sae 144 4 148 Norfolk . 3 5 ; ae 67 43 110 Northamptonshire . ; | 6 12 18 Shropshire < 3 : : b4 1 55 Somersetshire . : 3 a 70 8 78 Suffolk . : 2 ee = 21 24 45 Surrey . : : : ; 64 4 58 Worcestershire ‘ : ? 26 1 27 Yorkshire : ‘ : a 604 243 847 Others . 3 : ; sal 775 = T715 Total - | 2,308 415 2,723 ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 943 Previous Additions Collection (1904) Total | WALES— Anglesey . - : die 5 1 6 Carnarvonshire 3 : : 96 10 106 Pembrokeshire . 4 A é 15 30 45 Others . : P 5 - 134 — 134 Total . , 7 ; A 250 41 291 CHANNEL ISLANDS . 5 : 38 = 38 ISLE OF MAN . : 5 60 1 61 ScoTLAND— Edinburgh : c : : 47 7 54 Fifeshire . 3 : ‘ ; 24 19 43 Haddingtonshire . ‘ : + 1 5 Linlithgow. : 3 : 2 3 5 Renfrewshire j =| 1 4 5 Stirlingshire . ; . : 15 3 18 Others . : ; A Au 329 —_— 329 Total . ; : ‘ | 422 37 459 IRELAND— Antrim , 3 5 : a 273 5 278 Cork A 5 : ' Sit: 2 19 * 21 Down ‘ é : aul 98 | 7 105 Dublin. s 5 | 39 3 42 Kildare , 3 = 2 2 Leitrim : ‘ ¢ : — 2 2 Londonderry . ; : a 23 3 26 Sligo , 5 il 12 Wicklow . ‘ : 4 Poa = 1 1 Others . ¢ : { 3 157 — 157 Total . i 5 : ‘ 597 49 646 Rock STRUCTURES, Kc. . ; 96 — 96 SUMMARY. ENGLAND, 4 4 : ; 2,308 415 2,723 WALES : 3 3 6 - 250 41 291 CHANNEL ISLANDS ._. At 38 — 38 IsLE OF MAN . i . r 60 1 61 ScoTLAND A : ; ; 422 37 459 IRELAND , é 3 E 597 49 646 Rock STRUCTURES, kc. . | 96 — 96 Total . 5 : F } 3,771 543 4,314 It is not easy to pick out any particular series of photographs for special mention, but a set of seventeen prints from Mr. Charles C. Buckingham, and two from Mr. De Vere, all taken under the auspices of the East Kent Natural History Society, seem to be of exceptional interest. They illustrate the course and tributaries of the Kentish river Stour, and their R2 244, REPORT—1904. association with the springs known as Bournes. Mr. Buckingham has also photographed Reculvers Church from the same points of view as Lyell’s famous pictures, and the result brings home the potency of marine denudation and the need for coast defences. Mr. R. Vowell Sherring, working in conjunction with the Bourne- mouth and District Society of Natural Science, sends some beautiful prints of the Bournemouth cliffs; Mr. Mellard Reade contributes some excellent photographs of the well-known gypsum boulder of Crosby ; and Mr. Topham a series {28m the gravels of Eye in Northamptonshire. The rhythmical fretting of limestone by water in Hell Gill is illustrated by Mr. Rodwell under circumstances of considerable difficulty, and the marine destruction of the Scarborough landslips by Mr. Monckton. Mr. Leach sends photographs of a mass of Carboniferous Limestone at Tenby, supposed to show 10,000 specimens of Productus, and, curiously enough, almost the same post brought a notice that ‘the Corporation have for years been breaking up the stone for road repair, and are now in possession of a steam stone-breaker which will in the course of time cause this natural curiosity to disappear, unless some steps are taken to pre- vent it.’ Messrs. Muff and Wright have taken an ideal set of photographs of the raised beaches and platforms of Cork, which are buried under boulder- clay, blown-sand, and ‘head ;’ Mr. Pledge continues to illustrate Mr. Davies’s work on the Purbeck and Portland of the Haddenham district ; Mr. Robarts sends further contributions on the geology of Kent and Surrey from the Croydon Natural History and Scientific Society ; and Mr. Plews gives the first photographs recorded from Cambridge- shire. The importance of the contributions of members of the Committee will be realised from the fact that they are responsible for 426 photo- graphs out of a total of 541. Mr. W. Jerome Harrison, one of the earliest and most earnest of geological photographers, and perhaps the pioneer of county photographic surveys, sends no less than 270 prints out of his large collection of a lifetime. These comprise a large series of the Yorkshire coast from Bridlington to Whitby, series from Cornwall, Norfolk, and Suffolk, and our first connected set from the Cambrian rocks of St. Davids. Mr. Bingley contributes 76 prints taken in Norfolk, Suffolk, Yorkshire, Anglesey, and Carnarvon. Professor Reynolds’s work is well represented by illustrations from Hertfordshire, the Carboniferous area of Somerset, and volcanic areas in Fife, Hadding- ton, and Linlithgow. Last, but not least, Mr. Welch makes a valuable gift of 35 prints taken in Lancashire and Ireland, in connection with the work of the Belfast Naturalists’ Field Club, and of Mr. Praeger and Mr. Lamplugh. These include examples from Antrim and Cork, the glacial and associated deposits of Down and Dublin, and phenomena connected with limestones and caves in Sligo. One of the photo- graphs is both botanical and geological, for it shows the formation of tufa in a limestone-district through the agency of colonies of various mosses. To all the gentlemen named the Committee tender their best thanks, as well as to the following, who have contributed less in amount, it is true, but individual examples or series of high value: Mr. Epps, Mr. G. T. Atchison, Mr. Hopkinson, Messrs. Abley and Griffith, Mr. Hodson, ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 245 Professor Armstrong, Mr. Cobbold, Dr. Matley, Dr. Flett, Dr. Abbott, and Mr. Smith. Mr. Welch points out that one print registered last year (3289), the cemented breccia of quartzite and slate at Howth, which contained bones of mammals and fishes with land and marine shells, is now the only record of an interesting geological fact, as the block has been washed away by the sea. The third and last issue of the published series of ‘ British Geological Photographs’ was sent out to subscribers in May of this year. The com- pletion and success of its first publication scheme marks an epoch in the history of the Committee and the fulfilment of a long-cherished desire of its founders. Since the first meeting in 1890 the desirability of publishing a selected series of geological photographs has been kept before the Committee, but it was only in 1893 and 1894 that publishers were approached on the subject. With one consent they recommended us to go elsewhere, and so the matter was allowed to slumber till the Dover meeting in 1899. In that year a Sub-Committee of selection, consisting of Professor Bonney (Chairman), Professor Watts (Secretary and Editor), Professor Garwood, Dr. Mill, Dr. Teall, and Mr. H. B. Woodward, was appointed, a self- supporting subscription scheme drawn up, and a preliminary selection of typical photographs made. One hundred and ninety-three subscribers undertook to support a series which was to consist of issues of twenty photo- graphs each year for three years. It was decided to issue the series in three forms—unmounted half-plate platinotypes, mounted platinotypes, and lantern slides—and each issue was to be accompanied by descriptive letterpress. Various unforeseen circumstances delayed the first issue, but it saw the light in September 1902 ; issue ii. followed in July 1903, and the final issue in May 1904. The actual series, as published, comprised seventy- two photographs, fifty-one being standard half-plates, ten quarter-plates, and eleven whole-plates, and an equal number of lantern slides. The sub- jects ranged over most of the ordinary geologica] phenomena, the chief rock formations, and many of the more important British localities. The nega- tives were lent by thirty-four photographers, and a descriptive pamphlet of forty-two pages was written by thirty-four contributors, amongst whom are many of the most famous of contemporary British geologists. To both geologists and photographers the Committee express their warmest thanks. The estimates on which the Sub-Committee worked proved to have been well founded, and the annexed balance-sheet gives an account of all receipts and expenditure to date. It shows a balance in favour of the Committee of £95 13s. 2d., and a prospective profit of over £130 when all outstanding accounts shall have been paid. The balance-sheet, however, does not make one important point clear. Eight whole-plate platinotypes and twelve slides beyond the number agreed upon have been issued to subscribers. It is estimated that these addi- tional photographs have cost £105. If this be added to the balance in hand the total profit has been £235, of which one-half has been returned to the subscribers and the other half retained by the Committee for the purpose of carrying on the work for which it was originally established by the Association. 24.6 REPORT—1904. Balance-sheet, Publication Account, to August 18, 1904. RECEIPTS. oS ete Lb Printsonly . - 5 : : : : oo L480 Mounted prints. : : - : : - 19610 0 Slides . ‘ : : : : ‘ : Beret este (0 Prints and slides. ; 5 : : . pe es Ue) Mounts and slides , : 5 . : : - 426-1050 Mounts and prints . 3 5 ; : : - TAB 7O Prints, mounts and slides : : E i Pipa Ut beasts} 40) 821 17 0 Tess arrears unpaid ‘ : : : se Opie Total : : 3 3 5 : . 78018 O PAYMENTS, CF i Py ol Preliminary expenses and — oe 2h HOVERS Copying negatives . : 5 : ; speeZl ira Copyright and DRPCERSE, 5 E : : ‘ 619-0 Prints. iS ; : x - . 224 1 4 Mounts and mounting ‘ : ‘ 2 : See) dep sho Albums and boxes . - 4 . : : ieee! 6 Slides and arr: é : : : ; a eLiG (Ome Packing . : ; ; 3 = sey lGt 2 al Carriage of parcels. : : : ‘ : sped So OHO Printing and stationery . . . : ; phe UO. eee Office expenses : : . ‘ A : . 7 6 43 Postage . : : : : oe OS Renewing broken slides . - , 5 : Yona Sets for new subscribers : ; ; ; . 2712 4 Interest on working capital . 2 LOO Exhibition expenses (St. Louis and London) . ‘ 419 11 Balance transferred to Committee’s account (£136 12s, 2d., less unpaid £4019s.) . a i9byLS 2 Total . ; : . * A - ap (SOELS GO It was pointed out in the Report for last year that in its fourteen years’ work of collecting and storing photographs, the Committee had spent £101 10s. of the £130 granted to it by the Association. In making a clear profit of £130 the Committee may congratulate itself on having ‘earned its keep,’ and perhaps it is the only Committee of the Association which has ever succeeded in literally doing so. But, besides this, by scattering broadcast over the world typical photographs of geo- logical features and phenomena it has rendered a service to geological, and perhaps to geographical, teaching which cannot be well over-estimated. The British Association photographs are forming the nucleus of dozens of teaching-collections in the universities, schools, and museums of Britain ; and numerous foreign subscribers write that they are only unable to sub- scribe to a second series because they now want the funds to accumu- late other examples from their own countries. It is not so difficult to obtain geological photographs as it was fifteen years ago, for even the ubiquitous picture post card is sometimes frankly geological. Ata meeting of the Committee held in Cambridge on August 19, 1904, Dr. J. J. H. Teall, F.R.S., in the chair, it was unanimously agreed That this Committee desires to record its admiration of the indefatigable energy shown by its Secretary, both in carrying out the original aims of the Committee and in bringing to a successful issue the publication ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 247 of a typical series of Geological Photographs, services to Geological Science which cannot well be overestimated.’ About 100 intending subscribers to a new series have sent in their names, and the Committee recommend that such a new series be under- taken on the same terms as the last. With the smaller number of subscribers, however, the margin is narrow, and while profit to the Committee will be small, or absent, the subscribers will have to be content with the ‘contract number’ of photographs. Possibly the number of subscribers will increase when it is known that the new series will be actually carried out. Such a series will naturally be complete in itself, but it will also be supplementary to the first series, and in no way a repetition of it. The Committee would most warmly welcome any suggestions from subscribers and others as to the best points to be considered in the new series. Examples of the published series of photographs were shown at the Exhibition arranged by the Geographical Association in London and the provinces this year. Another set was sent by request to the Exhibition at St. Louis, and it is proposed to present this collection to the Geographical and Geological Department at Harvard University when the exhibition closes. To this set a gold medal has been awarded in group 16. The duplicate collection of slides has been exhibited and explained within the year by Mr. Whitaker at the following local scientific societies :—The Christ’s Hospital Natural History Society, the Greville Place Literary Society, Maida Vale, the Stratford Congregational Literary Society, and the Ashmolean Natural History Society, Oxford. Applications by Local Societies for the loan of the duplicate collection should be made to the Secretary. Either prints or slides, or both, can he lent, with a descriptive account of the slides. The carriage and the making good of any damage to slides or prints are expenses borne by the borrowing society. The Committee recommend that they be reappointed without a grant. FIFTEENTH LIST OF GEOLOGICAL PHOTOGRAPHS, Aveust 17, 1903, tro Auacust 12, 1904. This list includes the geological photographs which have been received by the Secretary of the Committee since the publication of the last report. Photographers are asked to affix the registered numbers, as given below, to their negatives for convenience of future reference. Their own numbers are added in order to enable them to do so. Copies of photographs desired can, in most instances, be obtained from the photographer direct, or from the officers of the local society under whose auspices the views were taken. The price at which copies may be obtained depends on the size of the print and on local circumstances over which the Committee have no control. The Committee do not assume the copyright of any photographs included in this list. Inquiries respecting photographs, and applications for per- mission to reproduce them, should be addressed to the photographers direct. It is recommended that, wherever the negative is suitable, the print be made by the cold-bath platinotype process. The very best photographs lose half their utility, and all their value as documentary evidence, unless accurately described ; and the Secretary would be grateful if, whenever 248 REPORT—1904. possible, such explanatory details as can be given were written on the forms supplied by him for the purpose, and not on the back of the photograph or elsewhere. Much labour and error of transcription would thereby be saved. It is well, also, to use a permanent ink for this purpose. A local number, by which the print and negative can be recognised, should be written on the back of the photograph and on the top right-hand corner of the form. Copies of photographs should be sent wnmounted to W. W. Watts, The University, Birmingham, and forms may be obtained from him. The size of photographs is indicated as follows :— L= Lantern size. 1/1 = Whole-plate. 1/4= Quarter-plate. 10;8 =10 inches by 8. 1/2 = Half-plate. 12/10 =12 inches by 10, &c. E signifies Enlargements. * Indicates that photographs and slides may be purchased from the donors, or obtained through the address given with the series. 3 LIST I. ACCESSIONS IN 1905-1904. ENGLAND. BuckKINGHAMSHIRE.—Photographed by J. H. PLepGx, 115 Richmond Road, Dalston, N.E. 1/2. Regd. INO. 4296 (B14) Cutting near Digg’s Upper Portland and Purbeck. 1903. : Farm, Haddenham. 3756 (B15) Cutting N.W. of Had- River Gravel. 1903. denham to Thame Road. 3757 (B16) Cutting S. of main road, Portlandian Pebble-bed. 1903. Thame to Aylesbury, Had- denham. 3758 (B17) Cutting S. of main road, Portland Beds. 1903. Thame to Aylesbury, Had- denham. 3759 (B18) Cutting S. of main road, Pebblé Bed in Portland. 1903. Thame to Aylesbury, Had- denham. CambBripGEe.—Photographed by A. G. PLews, Pembroke College, Cambridge. 1/4. 3760 ( ) Brick Pit at Gamlingay . Unconformity of Lower Greensand on Ampthill Clay. 1902. 3761 ( ) = “A . Unconformity of Lower Greensana on Ampthill Clay. 1903. CornwatL.—LPhotographed by W. Jerome Harrison, F.G.S., 52 Claremont Koad, Handsworth, Birmingham. 7/5. 3762. (408) Cliffs N. of Newquay Devonian Rocks. 1894. S763 (1097 F) ” ” Coast erosion. 38764 (420) Walrus Rock, N. of ‘A j Newquay. «ON PHOTOGRAPHS OF Regd. oO. 8765 (1109F) The Porth, Newquay 3766 (1106F) % x 8767 (1105 F) N. side of the Porth, Newquay. 3768 (1099F) 3 miles N. of Newquay 3769 (1528 F) Cliffs 3 to5 miles N. of Newquay. 3770 (1096 F) Bedruthan Steps. 3771 (1116F) Bedruthan . GEOLOGICAL INTEREST, 1894 ‘The Norwegian.’ Rock chasm. . Folded rocks “a CuMBERLAND.— Photographed by G. T. Arcuison, M.A., LL.B., Holmwood, Sutton Coldfield. 4297 (67) Below Watendlath, Borrow- dale. 1/2 ‘The Devil’s Punchhowl.’ 1902. DrvonsHirE.— Photographed by C. H. B. Epps, B.A., 95 Upper Tulse Hill, SW. 5/4, 3772 (1150) Bathing Beach, Ilfra- combe. 3773 (1151) Bathing Beach, Ilfra- combe. Isoclinal fold in slate, 1903. Strain-slip cleavage on large scale. 1903. Hampsuire (IsLE or WiGut).—Dhotographed by J. Hopkinson, F.G.S., Weetwocd, Watford. 3774 (14) Undercliff between Lawrence and Ventnor. (15) Undercliff between Lawrence and Ventnor. St. 3775 St. 1/4. Bands of Chert in Upper Greensand. 1903. Bands of Chert in Upper Greensand. 1903. Photographed by R. VowEtt SuHeERRinG, /.L.S., Hallatrow, near Bristol. Bournemouth and District Society of Natural Science, 4256 (1) Cliffs W. of Gordon Hotel Steps, Southbourne, Bourne- mouth, 4257 (2) E. of Gordon Hotel Steps, Southbourne, Bournemouth. 4258 (3) E. of Gordon Hotel Steps, Southbourne, Bournemouth. 4259 (4) Southbourne Cliffs, Bourne- mouth. 4260 (5) Southbournce Cliffs, Bourne- mouth. 4261 (6) Southbcurne Cliffs, Bourne- mouth. 4262 (7) Southbourne Cliffs, Bourne- mouth, Photographed by W. E. ABLEY, 4264 (320) Three miles from Win- chester, on road to Teters- field. 4265 (321) Three miles from Win- chester, on road to Peters- field. 10/8. Eocene Beds. 1904. Lignite Bed above high-water mark, 1904. Leaf Bed in situ. 1904. Silver-sand Bed and cliff erosion. 1904, Cliff erosion. 1904. Sands and clays. 1904. Kingsgate Street, Winchester. 1/1. Broad, flat floor of Chalk combe and dry watercourses at itshead. 1903. Narrow valley in continuation of combe. 1903. 250. REPORT—1904. _ HERTFORDSHIRE.—Photographed by J. Hopkinson, F.G.S., Weetwood, Watford. 1/4. 3776 (16) Lane to Bottom Farm, Lane converted into river from December Valley of the Bourne. 1903 to May 1904. 1904. 3777 (17) Gravel-pitin Bourne Valley Converted into pond from December 1903 to June1904. 1904, Photographed by Professor 8. H. Rrynotps, I/A., F.G.S., University College, Bristol. 1/4. 3778 (A 14) Railway Cutting, Chor- Pipes and pockets of Gravel in Chalk. ley Wood. 1908. 3779 (A15) Railway Cutting, Chor- Pipes and pockets of Gravel in Chalk. ley Wood. 1903. 3780 (A 16) Railway Cutting, Chor- Pipes and pockets of Gravel in Chalk. ley Wood. 19038. Kent.—Photographed by N. F. Rozparts, F.G.S., 23 Oliver Grove, South Norwood, S.E. 1/4. 3781 (28) Oldbury Hill, Ightham . Sandpit in Folkestone Beds. 1904. Kent.—-Photographed by Cuarues C, Buckinauam, 13 York Road, Canterbury. 1/4 and 1/2. 4266 (100) S.E. of Lenham . . Source of Great Stour. 1902. 4267 (101) ” e . ” ” ” 4268 (102) 1D A . Stream from spring at head of Great Stour. 1902. 4269 {03) 3 . . Lake formed where two sources of Great Stour meet, 1902. 4270 (104) Great Stour leaving Lake. 1902. 4271 (105) Milton, near Canterbury « River Stour altering its course. 1902, 4272 (106) Marsh side 4 Bed of ancient Wantsum. 1902. 4273 (107) Postling . : 5 . Source of Hast Stour. 1902. 4274 (108) Etchen Hill. . Spring at head of Elham Nailbourne. 1903. 4277 (111) Kingstone ; . Course of Lesser Stour, 1903, 4278 (112) Patrixbourne . : 5 f 4 y 4279 (113) Bekesbourne . . ‘ “1 o> a 4280 (114) Eee si - 4281 (115) Near Bekesbourne = . Springs on course of Lesser Stour. 1903. 4282 (116) 3 . Stream from springs (4281). 1903. 4283 (117) Wickhambreaux . Lesser Stour banked up for power pur- poses, 1903. 4284 (118) Lesser Stour at Seaton Mill. 1903. 4285 (119) Reculvers at high water From point of view of Lyell’s ‘ Principles,’ fig. 53. 1903. 4286 (120) " FH . From point of view of Lyell’s ‘ Principles,’ fig. 54. 1903. 4287 (121) Between Reculvers and Thanet Sands and Woolwich Beds. 1903. Herne Bay. 4288 (122) Between Reculvers and - . = Herne Bay. 4289 (123) Between Reculvers and Woolwich and Oldhaven Beds. 1903. Herne Bay. ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 251 Regd. No. 4290 (124) Between Reculvers and Woolwich and Oldhaven Beds. 1903. Herne Bay. 4291 (125) Between Reculvers and Oldhaven Gap. 1903. Herne Bay. 4292 (126) Between Reculvers and Woolwich and Oldhaven Beds and London Herne Bay. Clay. 1903. 4293 (127) Between Reculvers and London Clay crumbling over Oldhaven Herne Bay. Beds. 1903. 4294 (128) Between Reculvers and London Clay. 1903. Herne Bay. 4295 (129) Between Reculvers and 53 33 7 Herne Bay. Photographed by T. Dz Vere, Belle Vue, Harbledown, Canterbury. 1/4 4275 (109) Lyminge . s ; . Springs at head of Elham Nailbourne. 1903. 4276 (110) Derringstone . . . Course of Lesser Stour, now being used as a road. 1903. LANCASHIRE.—* Photographed by R. Wetcn, Lonsdale Street, Belfast. 1/1. 3782 (4102) Bispham Cliffs, Black- False-bedding in Glacial Sands and pool. Gravels. 1903. 3783 (4105) Bispham Cliffs, Black- Cemented Glacial Sands and Gravel fallen pool. on beach. 1903. 3784 (4103) Bispham Cliffs, Black- Cemented Glacial Sands and Gravel form- pool. ing sea-stacks. 1903. 3785 (4104) Bispham Cliffs, Black- Fallen masses of Glacial Sands and pool. Gravels. 1903. *Photographed by Messrs. Harttey Brotuers, South Road, Waterloo, and Presented by T. Metuarp Reape, 1.4.8. 1/1. 3786 ( ) Great Crosby . - . Gypsum boulder, 18 tons. 1898. 3787 ( ) ” - v - ” ” ” 3788 ( ) ” ” ” ” 3789 ( ) ” ” ” ” LEICESTERSHIRE.—Photographed by A. G. PLews, Pembroke College, Cambridge. 1/4. 38790 ( ) Charnwood Lodge Drive Cleaved Volcanic Agglomerate. 1903. Photographed by Professor H. E, Armstrone, F.2.S., 55 Granville Park, Lewisham. 1/2. 3755 ( ) Mountsorrel, Leicester . Terraced Granite surface under Keuper Marl, 1903. Photographed by G. Hopson, I.Inst.C.£., Loughborough. 1/1 and 1/4. 8791 ( ) One Barrow Quarry, Grit in Blackbrook Series. 1904. Charnwood. 3792 ( ce near Shep- Masonry dam for reservoir. 1903? shed, Regd. No. 3793 3794 3795 3796 3797 3798 3799 3800 3801 3802 3803 3804 3805 3806 3807 3808 3809 3810 3811 3812 3813 3814 3815 3816 3817 3818 3819 3820 3821 3822 3823 3824 REPORT—1904. (6143) Se aen (6144) (6145) Cliffs, ‘Happisburgh : (6146) Cliff 20 yards N. of Old Kiln, Ostend, near Happis- burgh. (6147) Cliffs, near Bacton Gap . (6148) Cliffs to N. of Bacton G ap. (6149) Cliffs between Bacton and Mundesley. (6151) Cliffs between Bacton and Mundesley. (6152) Cliffs N. of Mundesley (6153) (6163) Cliffs, East Runton, near Cromer. (6160) Runton, near Cromer (6161) —_,, i (6162) __,, (6159) Cliffs, Sheringham. (6157) Cliffs near Sheringham . (6158) (6155) Cliffs, ‘Weybourne : (6156) Cliffs 8. of Weybourne (6164) Sprowston Road, Norwich (6165) Watling’s Pit, Sprowston, Norwich. (6166) Watling’s Pit, Sprowston, Norwich. (6167) Hellesdon, Norwich ” 2 Beeston, near (6168) Mousehold Heath, Nor- wich. (6169) Plumstead Road, Nor- wich. (6171) bss a Crag Pit, wich (6172) Thorpe Crag Pit, wich. (6173) Woodlands Lane Quarry, Norwich, (6182) Forncett Nor- Nor- (6183) ” (6184) Tharston Furze Hill (6185) 2 NorroiK.—Photographed by Goprray Binauey, Thornichurst, Headingley, Leeds. 1/2. Lower Till. 1903. Laminated Beds in Lower Till. 1902, Lower and Upper Till. 1903. Contorted Beds resting on Till, 1903. Till, Contorted Drift, and River Gravel. 1903. Till, Contorted Drift, and River Gravel 1903. Contorted Drift. 1903. »” ” Contorted Till. Gravel Bea, ‘Forest Bed.’ Mass of Chalk in Contorted Drift. Masses of Chalk in Contorted Drift. Erratic of Chalk Marl. 1903. 1903. Weybourne Crag on Chalk. 1903. Contorted Drift. 1903. Crag on disturbed Chalk. 1903. Chalk Pit. 1903.” i Glacial Sands and Gravels on Brick-earth. 1903. Glacial Sands and Gravels on Brick-earth. 1908. Chalky Boulder Clay with irregular de- calcification. 1903. ‘Cannon-shot’ Gravel. 1903. ‘Cannon-shot’ Gravel on Contorted Glacial Sands. 1903. Chalk and Norwich Crag. 1903. ” ” ” Lower Glacial Sand covered with Boulder Clay. 1903. Chalky Boulder Clay, with piece of Kim- meridge Clay. 1903. Chalky Boulder Clay, with piece of Kim- meridge Clay. 1903. Chalk, Crag, Westleton Beds, and Gravel. 1903. Chalk, Crag, Westleton Beds, and Gravel. 1903. ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 253 Photographed by W. Jerome Harrison, I.G'.S., 52 Claremont Road, Handsworth, Birmingham. 7/95. Regd. No. ‘3825 (1826 F) Cliffs W. of Cromer . Large Boulder of Chalk embedded in Drift. 1896. 3826 (1836 F) Pa . Contorted Drift. 1896. 3827 (1835 F) Runton Gap, near Sandy Drift. 49 Cromer. 8828 (1873 F) Cliffs at Beeston, near Contorted Drift. 3 Sheringham. 8829 (1890 F) Beeston Cliffs. 8830 (1832 F) E.of Sheringham . 8831 (1891 F) Sheringham Beach . Sea Defences 3832 (1831 F) W. of Sheringham . Pinnacle of Chalk in "Drift. 1896. 3833 (497) Cliff-endat Weybourne Chalk and Crag. 1896. ” ” Photographed by E. Corprr, and Presented by T. SourmwE tt, The Crescent, Norwich. 1/4. 3834 (_ ) Sidestrand Church . . Landslip. 1896, Photographed by J. Carver, Unthank Road, Norwich. 1/4. 3835 (_ ) Sidestrand Church . . Landslip. 1896. NortTHAMprTonsHire.— Photographed by C. H. Toruam, 110 York Road, Montpelier, Bristol. 3836 (1) Eye. : ; . . False-bedded Gravel. 1896. meat (C2) oih,5— es : : : . Current-bedded Sand and Gravel. 1896. 3838 (3) ,, 5 ° ; : . False-bedded Sand and Gravel. 1596 3839 (4) , . ; : ; . Coarse false-bedded Gravel. 1896. . 3840 (5) ,, : ; : : . Lenticular false-bedded Sand and Gravel. 1896. 3841 (6) ,, a ; : : . Sand-bed in Gravel. 1896. 3842 (7) 5 ; : : 5 . Deposition of Sand against Gravel ridges. 1896. 3843 (8) , . . . . ~~. False anticlines owing todeposition. 1896. 3844 (9) ,, ; : 3 , . High-angle false-bedding. 1896. 3845 (10) ,, z ; : : . Low angle false-bedding. 1896. 3846 (11) ,, ; : 3 : . Filled fissure and fault in Gravel. 1896. 3847 (12) ,, : : 5 : . Fissure in Gravel. 1896. Suropsuire.—Photographed by E. 8S. Cossoup, F.G.S., Watling House, Church Stretton. 1/4. 3848 (_ ) Belswardine Brook,Shine- Unconformity of Upper Llandovery Sand- ton. stone on Shineton Shales. 1903. Somrrser.—Photographed by Professor S. H. Reynoups, 1A4., £.G.S., University College, Bristol. 1/2. 3849 (A 5) Middle Hope, Weston- Volcanic Rocks in Carboniferous Lime- super-Mare, stone. 1903. .3850 (A6) Middle Hope, Weston- Bedded Calcareous Tufts. 1903. super-Mare. 254 REPORT—1904. Regd. No. 3851 (A7) Middle Hope, Weston- Tuffs and Limestone with Calcite veining. super-Mare. 1904. 3852 (A 8) Spring Cove, near Weston JBasalt Flow in Carboniferous Limestone. 1904. 3853 (A 9) Spring Cove, near Weston Basalt Flow in Carboniferous Limestone. 1904. 3854 (A10) SpringCove,near Weston Basalt Flow in Carboniferous Limestone. 1904. 3855 (A12) South side of Cheddar Weathering along joints. 1904. Gorge. 3856 (A13) Cheddar Gorge . . Carboniferous Limestone. 1903. SurrotkK.—Photographed by Goprrey Bineiey, Thornichurst, Headingley, Leeds. 1/2. 3857 (6178) Cliffs near Kessingland Current-bedding in Glacial Sands and Gravels. 1903. 3858 (6175) Cliffs between Kessing- Chalky Boulder Clay, and Glacial Sands land and Lowestoft. and Gravels. 1903. 3859 (6176) Cliffs between Kessing- Chalky Boulder Clay, and Glacial Sands land and Lowestoft. and Gravels. 1903. 3860 (6177) Cliffs between Kessing- Chalky Boulder Clay, Glacial Sands, and land and Lowestoft. ‘Forest bed.’ 1908. 3861 (6174) Pakefield Clay Pit, near Chalky Boulder Clay on Glacial Sands. Lowestoft. 1903. 3862 (6179) South of Lowestoft . Pebble beach. 1903. 3863 (6181) Cliffs, Corton, N. of Chalky Boulder Clay, Sands and Gravels, Lowestoft. and Brick-earth. 1903. Photographed by W. Juxomm Harrison, 27.G.S., 52 Claremont Road, Handsworth, Birmingham, 112. 3864 (273) Cliffs N. of Southwold . Orange-coloured Sands. 1901. 3865 (274) , * 5 . Orange and White Sands. 1901. S866 (275) . 5; = . Pebble bed. 1901. 3867 (276) , - sy . Sands and Laminated Clays. 1901. 3868 (280) ,, 3 9 . Westleton Beds resting on Laminated Clays. 1901. 3869 (282) ,, = = . ‘Crag’ with shells near base. 1901. 3870 (277) ,, 3 a : = 3871 (278) , » “ j ~ 3872 (279) , 95 -- a re 3873 (281) ,, > 55 5 - 3874 (283) , » i : ; 3875 (284) 3876 (292) Cliffs} mile S. of League Glacial Sands and ‘Forest Bed.’ ,, Hole, 8. of Gorleston. 3877 (294) Cliffs} mile 8. of League Glacial Sands on Loam. 1901, Hole, 8. of Gorleston. 3878 (293) + mile N. of League Hole Glacial Sands. 3 3879 (295) 1 mileS. of Gorleston . Mid-glacial Sands. 1901, 3880 (296) 1 mile S.ofGorleston . rs 5 e Surrey.—Photographed by N. F. Rosarts, /.G.8., 23 Oliver Grove, South Norwood, S.E. 1/4. 3881 (21) Box Hill from Norbury Chalk escarpment. 1904. ark, 3882 (25) Worms Heath Gravel Pit . Pipe of Clay in Oldhaven Pebble Beds. 1904, ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. Regd, No. 3&8S (26) Worms Heath Gravel Pit . 3884 (27) Bughill Farm,Woldingham Wokrcerstersuire.—Photographed by C. A. MArttey, 90 St. Lawrence Road, Clontarf, Dublin. 3885 (10) Wren’s Nest Hill, Dudley . 255 ae of Clay in Oldhaven Pebble Beds. 1904. Outbreak of Croydon Bourne. 1904. D.Sc, F.G.S., 1/4. Quarries and pillars in Wenlock Lime- stone. 1901. YorksuHirk.—Photographed by Goprrrey Bineiey, Thorniehurst, Headingley, Leeds. 3836 3887 3888 3889 3890 3891 3892 3893 (6356) Spurn Head . . (6358) __,, i: : (6382) Cliffs N. of Beacon. (6383) Cliffs Beacon. (6378) Near Hasington - _ (6381) Cliffs N. of Easington . (6368) Out Newton, near Withernsea. (6369) Out Withernsea. (6370) Out Withernsea, (6371) Out Withernsea. (6372) Dimlington Cliffs . (6373) ” eer (6374) : - (6375) us = (6379) i *s Kilnsea near Kilnsea Newton, near Newton, near 3895 3896 3897 3898 3899 3900 3901 3902 3903 3904 3905 3906 3907 3908 3909 3910 3911 Newton, near (6380) (6296) Scarborough, Drive. (6322) Penny Farm Gill, near Sedbergh. (6324) Penny Farm Gill, near Sedbergh. (6237) Helm Gill, Dent Dale els . Marine (6316) River Clough, Garsdale, near Sedbergh. (6319) Hebblethwaite Gill, Sed- bergh. (6232) Ganister Quarry, Mean- wood Valley, Leeds, (6260) Ganister Quarry, Mean- wood Valley, Leeds. (6262) Ganister Quarry, Mean- wood Valley, Leeds. (6259) Ganister Quarry, Mean- wood Valley, Leeds. Wye Looking N. from Lighthouse. 1904. Looking $.W. from Lighthouse. __,, Looking towards Kilnsea Beacon. 1904. Slipped and wasting cliff. 1904. Purple Boulder Clay and Glacial Gravels. 1904. Purple Boulder Clay and Glacial Gravels, 1904. Purple Boulder Clay with slipped masses, 1904. Hessle, Purple, Laminated, and Basement Clays. Coast erosion. 1904. Basement and Purple Clays. 1904. Hessle, Purple, Laminated and Basement Clays. 1904. Basement and Purple Clays. 1904. Shelly Basement Clay capped with Purple Clay. 1904. Spring in cliff. 1904. Fossiliferous Calcareous Grit. 1903. Vertical Carboniferous Limestone. 1904. ” ” fs] Lamprophyre Dyke in Coniston Limestone. 1904. Carboniferous Conglomerate. 1904. ” ” ” Overthrust Fault. 1903. Folded Coal and Ganister. 1904. 256 REPORT—1904. Photographed by J. H. Ropwe.t, Brooklyn Villa, New Manston, Regd. No. 3912 near Leeds. ( ) Hell Gill, Mallerstang. Photographed by Louis Situ, Conisborough. 3913 (251) Conisborough . 1/2. Fretting of Limestone by water. 1/2. Undercut and weathered block of Mag- nesian Limestone. Photographed by W. JunomE Harrison, F.G.S., 52 Claremont Road, 3914 3915 3916 3917 3918 3919 3920 3921 3922 3923 3924 3925 3926 3927 3928 3929 3930 3931 3932 3933 3934 3935 3936 Handsworth, Birmingham. (310 F) Balby Sandpit, near Doncaster. (311 F) Balby Sandpit, near Doncaster. (312 F) Balby Sandpit, near Doncaster. (313 F) Balby Sandpit, near Doncaster. (314 F) Warmsworth, near Don- caster. (315 F) Warmsworth, near Don- caster. (322 F) Adel Crags, near Leeds. (476) Ackworth (292 F) Brimham Rocks, Pate- ley Bridge. (293 F) Brimham Rocks, Pate- ley Bridge. (294 F) Brimham Rocks, Pate- ley Bridge. (296 F) Brimham Rocks, Pate- ley Bridge. (297 F) Brimham Rocks, Pate- ley Bridge. (299 F) Brimham Rocks, Pate- ley Bridge. (300 F) Brimham Rocks, Pate- ley Bridge. (301 F) Brimham Rocks, Pate- ley Bridge. (302 F) Brimham Rocks, Pate- ley Bridge. (393 F) Brimham Rocks, Pate- ley Bridge. (304 F) Brimham Rocks, Pate- ley Bridge. (306 F) Brimham Rocks, Pate- ley Bridge. (307 F) Brimham Rocks, Pate- ley Bridge. (373 F) Hilderthorpe, S. of Bridlington. (590) Hilderthorpe, 5S. of Bridlington. 1/2, 7/5, and 1/1. Bunter capped by Gravels. 1903. Bunter Sandstone. 1903. Bunter capped by Gravels. 1903. Bunter. 1903. Quarry in Magnesian Limestone. 1903. ” ” »” Millstone Grit. 1903. Grindstone Quarries 1903. Wind erosion of Millstone Grit. in Coal-measures. 1903. ” ” ” ” Boulder Clay and Contorted Sands. 1898. ” ” ” ” 3971 3972 3973 3974 3975 3976 3977 ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. (592) Hilderthorpe, Bridlington. (593) Hilderthorpe, Bridlington. (2079 F) Hilderthorpe, 8. of Bridlington. (885) Flamborough from near Danes Dyke. (387) Flamborough Head S.W. of Danes Dyke. (870 F) High Stacks, borough. (371 F) High Stacks, borough. (3872 F) High Stacks, borough. (882 F) Flamborough near Hich Stacks. (2067 F) Flamborough Head (901) Flamborough Head, N. side. (367 F) Selwick borough. (369 F) Selwick borough. (865 F) Selwick borough. (866 F) Selwick borough. (884 F) Near Flamborough. (899) Near Flamborough. (891) North Sea Landing, Flamborough. (2066 F) North Sea Landing, Flamborough. (895) North Flamborough. (892) North Sea Landing, W. side. (896) North Sea Landing . (385 F) (2068 F) Ravine W. of North Sea Landing. (2076 F) Thornwick Bay, E. side. (2075 F) “ (2073 F) Thornwick o : (2069 1 ” (2061 F) Speeton Gap. (2064 F) Speeton Cliffs N. of # Gap (2060 F) Speeton (2059 F) (2065 F) Filey, Cliffs 8. of (451) Filey, Cliffs and Brigg (227) Carr Naze, Filey (228) ” ” aay 5 3 (228)iinwe,, ; (230) » (224) Filey Brigg” - (231) Filey Brigg and Cliffs 8S. of 8S. of Flam- Flam- Flam- Head, Bay, Flam- Bay, Flam- Bay, Flam- Bay, Flam- Breil Point, Breil Point, Sea Landing, 1904. Boulder Clay and Contorted Sands, 257 1898, Boulder Clay under Laminated Loam. Drift. 1898. Chalk and Drift. 1898.’ Chalk capped by Drift. Drift-filled river channel. it Chalk and Drift. i Sea Caves in Chalk. i Chalk and Boulder Clay. - ‘Adam Rock.’ 1898. ‘ Eve Rock.’ . 1898. ‘ King and Queen Rocks.’ ” ” ” Chalk and Drift, Caves. “ ” ” ” Caves in Chalk. 1898. Chalk Caves and Drift Plateau. Entrance to Church Cave. Chalk and Drift. 1898. Drift. 1898. Moraine, from Windmill. 1898. ” Drift. 1898. Boulder Clay. 1902. Boulder Clay on Corallian Rocks. Calcareous Grit. 1902. 1898. 1898, 1902. s : Corallian Rocks under Boulder Clay. 1902. REPORT—1904. (225) Filey, N. of Brigg (232) Filey Brigg and Cliffs es Gristhorpe Bay, 8. of (447) ” ” (446) (455) Gristhorpe Bay (45 0) ” ” (453) esd (457) “5 9 (448) Gristhorpe Bay, N. end (456) Gristhorpe Bay ‘ (357) Cayton Bay, Scarborough (356) ” ” (358) (862) Between Cayton and Car- nelian Bays, Scarborough. (3860) Between Cayton and Car- nelian Bays, Scarborough. (361) Between Cayton and Car- nelian Bays, Scarborough. (363) Carnelian Bay 5 (364) » (323) Scarborough Bay (322) ” ” (319) x pea Ms (318) White Nab, 8. of Scar- borough. (265) White Nab, S. of Scar- borough. (266) White Nab, 8S. of Scar- borough. (267) S.E. corner of White Nab. (320) South of Nab, Scar- borough. (848) Scarborough, Castle Hill (850) Scarborough, Castle Hill from East Pier. (830) Scarborough, Castle Hill from East Pier. (328) Scarborough, Castle Hill from East Pier. (300) Scarborough, Castle Hill from East Pier. (302) Scarborough, Castle Hill from East Pier. (305) Scarborough, Castle Hill from East Pier. (304) Scarborough, Castle Hill. (803) i. (301) Scarborough, Castle Hill, N.E. face. (244) Scarborough, Castle Hill, N. side. (251) Scarborough, N. side. (249) Scarborough, Castle Hill, . side. (243) Scarborough, N. side. Castle Hill, Castle Hill, Corallian Rocks. 1902. Oxford Clay and Corallian. 1902. ” ” ” Oolite Plant Beds. 1902. . False-bedded Oolite Sandstones. 1902. Oolite Plant Beds. 1902. Boulder of Shap Granite. 1902. Oolites. 1902. ; Purple Boulder Clay. 1902. Breaking waves. a Oolite Sandstones, oi ” ” ” Jointing in Oolite Sandstones. 1902. Purple Boulder Clay with Striated Lime- stone boulder in situ. 1902. Boulder Clay and Oolite Sandstone, i902. Lenticular Bedding in massive Sandstones. 1902. Jointing in Oolite Sandstones. 1902. Oolites. 1902. Jointing in Oolite Sandstones. 1902. Oolite Sandstones. 1902. Denudation of Oolite Sandstones. 1902. False-bedded Oolite Sandstone. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1897. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock, Oxford Clay, and Coral- lian Beds. 1902. Kellaways Rock and Oxford Clay. 1902. Oxfordian and Corallian Rocks. = Corallian Rocks. 2 Oxfordian and Corallian Rocks. ys Oxford Clay faulted against Corallian Rocks, 1902. Oxford Clay faulted against Corallian Rocks. 1902. Corallian Rocks. 1902. ON PHOTOGRAPHS OF (351) Scarborough, Castle Hill, West angle. (250) Scarborough, Castle Hill, N. side. (354) Scarborough, Castle Hill. . (325) Scarborough, Castle Hill, N.W. side. (289) Scarborough, Castle Hill. (353) ” » (355) 9 ” (247) Scarborough, North Cliff. (252) Cliffs at Peasholme, N.W. of Scarborough. (335) Scalby Beck (255) % (332) (336) Mouth of Scalby Beck (253) Scalby, near Scarborough. (256) Scalby Beck . : (296) Mouth of Scalby Beck (254) Scalby j (294) Scalby Beck (2738) (274) Coast N. of Scalby Beck . (276) ” ” (275) ” ” (272) (284) Cromer Point, N. of Scar- borough. (287) Near Cromer Point . (286) North of Cromer Point (268) Seamer Junction, near Scarborough. (269) Crossgates Quarry, Sea- mer. (270) Crossgates Quarry, Sea- mer. (283) Coast 8S. of Cloughton Wyke. (280) Coast S. of Cloughton Wyke. (281) Coast 8. of Cloughton Wyke. (285) Coast 8. of Cloughton Wyke. (282) Coast 8. of Cloughton Wyke. (310) Hayburn Wyke; Under- cliff, South of. oS nome! 8S. of Hayburn (318) Hayburn Ue (313) s (307) is (309) i (315) i (308) : (312) e as Be _ (306) ele GEOLOGICAL INTEREST. Corallian Rocks. Nodule 1902. 259 ” ” Bed in Lower Calcareous Grit. Nodule Bed in Lower Calcareous Grit. 1902. Oolites. 1902. Oolites and Drift. 1902. V-shaped ravine cut through Oolites and Boulder Clay. 1902. Cliffs of Boulder Clay. 1902. Peak of Boulder Clay on Oolites. ” Boulder Clay ‘on Oolites, 1902. Pinnacle of Boulder Clay on Ovlites. Stony Boulder Clay. Ripple-marks in Oolite Sandstone. Anticline in Oolites. Oolites. ” ” Oolites under Boulder Clay. False-bedded Oolites. Oolites. Lenticular Sandstones in Oolites. Boulder of Shap Granite. Corallian Rocks. Oolites. Plain of Marine Erosion. Oolite cliffs. Landslips in Oolites, Oolites. Stream-course. Double-waterfall. Oolites. Waterfall on shore. Oolites. ” Stream-course in Oolites. 82 REPORT—1904. (314) Hayburn ere (222) Pickering. (215) Old Quarry near Castle, Pickering. (219) Old Quarry, W. side of Valley, Pickering. (216) Quarry S. of Newbridge, Pickering. (217) Quarry S. of Newbridge, Pickering. (220) Quarry 8. of Newbridge, Pickering. (223) Quarry S. of Newbridge, Pickering. (837) Thomason Force, Goath- land. (838) Thomason Force, Goath- land. (832) Robin Hood’s Bay (1948 F) Cliffs near Saltwick (1947 F) .,, (1604 F) Cliffs E. of Whitby (808) (562) Cliffs 2 4 mile KE. of Whitby. (463) East Cliff, Whitby . (663) Cliffs E. of Whitby . (566) East Cliff, Whitby . (812) ” ” (809) » » (810) ” (811) Whitby Old Town (805) Whitby Harbour (1932 F) Whitby Scaur (1931 F) 5 (1929 F) $5 (567) os (641) %9 (564) ‘ (464) - (636) ” (568) 5 (1930 F) 5 (565) 5 : (827) Cliffs W. of Whitby . (829) 2s (484) Cliffs at ‘Upgang, W. of Whitby. (1578 F) Cliffs at Upgang, W. of Whitby. (488) Sandsend, N.W. of Whitby. (828) Cliffs } mile W. of Whitby. (594) Rigg Mill Beck, near Whitby (629) Cock Mill, 8. of ea : (3837) Runswick ES teenies (571) (573) Runswick Beach, N. ‘end . (332 F) Cliffs between Kettleness and Runswick. (1941 F) Staithes, Cliffs 8. of (1940 F) 7 Kast, Cliffs . Oolites. 1902. Corallian Rocks. > ” ” ” » ” ” ” ” ” ” “a 1897 1895. Oolite above Lias. 1897. Lias and Oolites. ee £ 1895. Sea-cavesin Lias. 1897. ” ” ’ Oolites on Upper Lias. 1897. ” < ” ” ” P A 73 Landslip Line. Be Lias and Oolites. =. Upper Lias. ” Lias at base of cliff. A; Lias and Oolites. a False-bedded Oolites. a Drift upon Oolites. " Drift, 80 to 100 feet. 1895. Boulder Clay and Sands. 1895, Lias. 1895. Faulting. 1897. 1895. Waterfall. ,, Middle Lias. 1897. Boulders on beach. 1897. - Shap Boulder on beach. 1895. Boulders. Jet Mine in Lias. 1897. Lias. % Regd. No. 4113 4114 4115 4116 4117 4118 4119 Photographed by H. W. Moncxton, 7.4 Temple, £. C. 4120 4121 4122 4123 4124 4125 4126 4127 4128 ON PHOTOGRAPHS OF (1939 F) Staithes, East Cliff (1942 F) Staithes (585) » (1943 F) (842) Staithes, North Clift (844) Staithes . (843) Cliffs, Staithes. (760) Osgodby Nab, N.W. End of Cayton Bay. (1834) Osgodby Nab, N.W. End of Cayton Bay. (1830) N.W. End of Cayton Bay. GEER) 5, . oe a : (1833) Ss (1554) Carnelian Bay, ‘hear Os- godby Nab. (1706) Carnelian Bay, near Os- godby Nab. (1702) Robin Hood’s Bay . GEOLOGICAL INTEREST. 261 Lias 1897. 7 1895. % 1897. Middle Lias. ” Lias. Middle Lias, " S., 3 Harcourt Buildings, 1/4. Estuarine Series, resting on Milleport Series. 1896. Estuarine Series, resting on Milleport Series, 1904. Landslip of Boulder Clay. 1904. ” ” ” ” ” ” Landslip of Boulder Clay. 1901. Site of Landslip of Boulder Clay, now washed away. 1902. Boulder of Granite. 1902. WALES. ANGLESEY.—Photographed by Goprrny BiInGLEy, Thorniehurst, 4129 Headingley, Leeds. (6236) South Stack Lighthouse, Holyhead. 1/4. Contortion. 1903. Carnarvon.—Photographed by Goprrey BinGLey, Thornichurst, 4130 4131 4132 4133 4134 4135 4136 4137 4138 4139 ITeadingley, Leeds. (6235) Diganwy, Llandudno (6239) Quarry, Great Orme’s Head, Llandudno. (6240) Quarry near Summit, Great Orme’s Head. (6241) Quarry near Great Orme’s Head. (6242) Quarry near Great Orme’s Head. (6243) Quarry near Great Orme’s Head. (6245) Quarry near Great Orme’s Head. (6246) Quarry near Summit, Great Orme’s Head. (6247) Quarry near Great Orme’s Head. (6249) Quarry near Great Orme’s Head. Summit, Summit, Summit, Summit, Summit, Summit, 1/4. Glaciated Boulder. 1903. Carboniferous Limestone. 1903. Fossils in Carboniferous Limestone. 1903. Carboniferous Limestone. 3 262 REPORT—1904. PemBROKE.— Photographed by A. L. Leacu, 10 Withdale Road, Plumstead, S.H. 1/2 and 1/4. Regd. No. 4140 (1) Tenby Quarry, 8.W. of town Carboniferous Limestone, with Productus. 1903. 4141 (2) = a Carboniferous Limestone, with Productus. 1903 Photographed by W. Jerome Harrison, £.G.S8., 52 Claremont Road, Handsworth, Birmingham. 1/1. 4142 (749) Gasworks Section, Haver- Llandovery Rocks. 1897, fordwest. 4143 (300 F) Caerbwdy Valley, St. Lower Cambrian Rocks. . Davids. 4144 (302 F) Caerbwdy Valley, near Glacial ‘ Tail.’ - Reservoir. 4145 (301 F) Caerbwdy Valley, St. Lower Cambrian Rocks. _,, Davids. 4146 (307 F) Caerbwdy Valley, St. ” ” ” Davids. 4147 (308 F) Caerbwdy Valley, St. ” ” ” Davids. 4148 (305 F) Caerfai Cliffs, St. ne ” ” Davids. 4149 (306 F) Caerfai Cliffs, St. : x Davids. 4150 (732) St. Non’s Arch, St. Davids y * yy 4151 (732a)St.Non’s Bay, St. Davids % a + 4152 (733) ” ” ” ” ” 4153 (301 F) ” ” ” ” ” 4154 (311F) ,, ” ” ” 4155 (730) Cliffs S. of St. Davids. ” ” ” 4156 (734) Fs = : ” ” ” 4157 (735) ” ” ” 4158 (731) Mouth of Porthclais, St. h “5 ” Davids. 4159 (747) Porthclais, St. Davids . < iy 4160 (303 F) Hs % : . ” ” 4161 (3823 F) ” ” ” 4162 (738) Ogof ‘Golchfa, St. Davids. * 55 33 4163 (743) Cambrian Conglomerate. ,, 4164 (316F) Porth- lisky, St. Davids . . Lower Cambrian Rocks. __,, 4165 (317F) Cliffs 8. of Porth-lisky. Marine denudation along joints. 1897. 4166 (318 F) . ” 4167 (739) Porth’ stinian, St. Davids : 3 4168 (740) Porth Trevethan @) ” 4169 (746) Whitesand Bay, St. Davids. Lingula Flags and Gabbro. re THE ISLE OF MAN. Photographed by C. A. Matury, D.Sc., F.G.S., 90 St. Lawrence Road, Clontarf, Dublin. 1 if 4, 4170 (9) Langness, near Castleton . Unconformity, Carboniferous on Manx Slates. 1901. ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. 263 SCOTLAND. EpinsurGu.—Photographed by Professor 8. H. Reynoutps, 1.A., 7.G.S., University College, Bristol. 1/4. Regd. No. 4171 (A 17) Salisbury Crag ‘ . Scarp of Dolerite Sill. 1902, 4172 (A18) ‘ ree ; . Dolerite Sill in Carboniferous Rocks. 1902. 4173 (A 19) ” ” ° . . ” ” ” ” 4174 (A 20) A ah : . Carboniferous Rocks overlying Dolerite. 1902. 4175 (A21) o sy : . Spheroidal Dolerite. 1902. 4176 (A 22) i Feet ; . Columnar jointing in Dolerite. 1902. 4177 (A23) Arthur’s Seat . : . Coarse Tuff below Lion’s Haunch. 1902. FirrsHire.—Photographed by Professor 8S. H. Reynotps, J/.A., F.G.S., University College, Bristol. 1/4. 4178 (A 24) By railway } mile W. of Brecciated Carboniferous Strata. 1902. Burntisland Station. 4179 (A 25) Dodhead Quarry, Burnt- Sill of ‘White Trap.’ 1902 island. 4180 (A 26) Dodhead Quarry, Burnt- Finger of Dolerite (‘ White Trap’) in Car- island. boniferous strata. 1902. 4181 (A 27) Dodhead Quarry, Burnt- ‘White Trap’ invading Carboniferous island. Rocks. 1902. 4182 (A 28) W. of Kirkcaldy . . Overthrust faults in Carboniferous Lime- stone. 1902. 4183 (A 29) Shore, W. of Kirkcaldy . Overthrust faults in Carboniferous Lime- stone. 1902. 4184 (A 30) Shore, St. Monans . . Dyke in Agglomerate of ‘Neck.’ 1902. 4185 (A 31) Shore, Ardross : - Undercut Cliff of Sandstone and Shale with thin Coals. 1902. 4186 (A 32) S.E. of Newark Castle, Small Volcanic ‘Neck.’ 1902. Elie. 4187 (A 33) S.E. of Newark Castle, % _ ‘ Hlie. 4188 (A 34) Shore,S.W.ofSt.Monans Contorted Shale near Agglomerate of ‘Neck. 1902. 4189 (A 35) 5 Contorted Shale near Agglomerate of ‘Neck.’ 1902. 4190 (A 36) Shore, Pettycur, King- Columnar Basalt. 1902. horn. 4191 (A 37) Shore, W. of Ardross . Dyke. 1902. 4192 (A 39) Shore, 4 mile E. of Amygdaloidal Basalt over Shales and Kinghorn. Limestones. 1902. 4193 (A 40) Shore, 4 mile E. of Amygdaloidal Basalt over Shales and Kinghorn. Limestones. 1902. 4194 (A 41) Elie E ; : . Agglomerate of ‘Neck.’ 1902. 4195 (A 42) ,, . : ‘ . = a a3 4196 (A 47) ,, : 5 2 . Ripple-marked Sand on shore. 1902. Happineron.— Photographed by Professor 8S. H. Reynoups, V.A., F.G.S., University College, Bristol. 1/4. 4197 (A 46) Milsey Bay, North Ber- Agglomerate. 1902. wick, 264 REPORT— 1904. 4 Linuitacow.—Photographed by Professor 8S. H. Reynoups, W.A., F.G.S., University College, Bristol. 1/4. Regd. No. 4198 (A 43) Hound Point i . Junction of Dolerite and underlying Sand- stone. 1902. 4199 (A 44) ” . . Deposit of Cockles on Shore. 1902. 4200 (A 45) ty * : : 5 = 53 a RENFREWSHIRE.—Photographed by Professor 8S. H. Rreynoups, I.A., F.G.S., University College, Bristol. 1/4. 4201 (A48) Shore,Gourock . . Contorted Gneiss, in boulder. 1902. 4202 (A49) Shore, W. of Gourock . Basalt dyke. 1902. 4203 (A50) ,, ae ee » ” 4204 (A56) ,, = ; . Marine pot-holes. 1902. STIRLINGSHIRE.— Photographed by H. W. Monckton, F.G.S., 3 Harcourt Buildings, Temple, B.C. 1/4. 4205 (471) Sauchie Craig, 3 miles Intrusive Dolerite on Carboniferous Lime- 8.W. of Stirling. stone Series. 1895. 4206 (1825) Sauchie Craig, 3 miles Intrusive Dolerite on Carboniferous Lime- 8.W. of Stirling. stone Series. 1903. 4207 (1826) Sauchie Craig, 3 miles Intrusive Dolerite on Carboniferous Lime- 8.W. of Stirling. stone Series. 1903. IRELAND, Antrim.—Photographed by C. A. Mattry, D.Sc., F.G.S., 90 St. Lawrence Road, Clontarf, Dublin. 1/4. 4208 (4) Giant’s Causeway : . Straight and curved columns. 1903. 4209 (2) The Gobbins, Island Magee Basalt Lavas. 1903. 4210 (3) 3 iG Chalk and Basalt. 1903. *Photographed by R. Wetcu, Lonsdale Street, Belfast. 1/1. 4211 (5205) Colin Glen, Belfast. - Yellow Sandstone, faulted against Glauco- nitic Sand and Red Marl. 1903. 4212 (5234) Hill’s Port undercliff, Old drainage channel outlets in Chalk Island Magee. cliff. 1902. Corx.—* Photographed by R. Wutcu, Lonsdale Street, Belfast. 1/1. 4213 (5251) East Passage, Cork Har- Longitudinal and _ transverse valleys. bour. 1904. 4214 (5252) Weavers Point, Cross- Anticline in Old Red Sandstone. 1904. haven. : 4215 (5253) Weavers Point, Cross- Cleavage in contorted Old Red Sandstone. haven. 1904, 4216 (5254) Near Weavers Point, Raised beach platform (preglacial) covered Crosshaven. with beach and ‘head.’ 1904. 4247 (5255) Ringaskiddy Cliffs, Cork Cliff of Boulder Clay. 1904. Harbour. 4218 (5256) Ballintemple Quarry, Massive Carboniferous Limestone with ork, tesselated joints. 1904, ee Regd. No. 4219 4220 4221 ON PHOTOGRAPHS OF GEOLOGICAL INTEREST. (5257) Ballintemple Quarry, Cork. (5258) Carrigrohane Cliffs (5258*) cs 265 Chert Beds in Carboniferous Limestone. 1904. Massive Carboniferous Limestone. 1904. Rift in Carboniferous Limestone, filled with Gravelly Drift. 1904. Photographed by W. B. Wriaut, B.A., and H. B. Murr, B.A., F.G.S., 4222 4223 4224 4225 4226 4227 4228 4229 4230 4231 Down.—*Photographed by R. Wetcn, Lonsdale Street, Belfast. 4232 4233 4234 4235 4236 4237 14 Hume Street, Dublin. (23 RDS) 350 yards E. of Howe Strand Coastguard Station, Courtmacsherry Bay. (24 RDS) Courtmacsherry Bay . (24a) Courtmacsherry Bay (25 RDS) Ringabella Bay, N. side (26 RDS) Nearly 500 yards EH. of Howe Strand Coastguard Station, Courtmacsherry Bay. (27 RDS) 80 yards §. of Myrtle- ville Cottage, entrance to Cork Harbour. (28 RDS) South side of Myrtle- ville Bay. (29 RDS) Clonakilty Bay, S.E. of Ballinglanna Cove. (30, RDS) 400 yards E. of Simon’s Cove, Clonakilty sect (31) Clonakilty Bay . (5236) Annadale _‘ Terra-cotta Works, Belfast. (5237) Annadale Brickworks, Belfast. sap South Quarry, Scrabo Hill Ce ‘South Quarry, Scrabo Hill (5241) Golf Links, Carnalea (5242) Near Carnalea Golf Links 1/2. Pre-glacial raised beach platform, raised beach, and overlying deposit. 1903. Raised beach gravel and sand, overlain by Boulder-clay. 1903. Raised beach gravel and sand, overlain by Boulder-clay. 1903. Striated raised beach platform, overlain by Boulder-clay. 1903. Raised beach platform, Beach Sand, Lower * Head,’ Boulder-clay, and Upper ‘ Head.’ 1903. Raised beach deposits resting on rock platform and overlain by Lower ‘ Head.’ 1903. Blown-sand beneath Lower 1903. Boulder-clay over beach gravel on rock platform; also modern rock platform. 1903. Cemented gravel on raised beach plat- form. 1903. Beach gravel on rock platform, overlain by ‘Head.’ 1903. ‘Head.’ 1/l. Thin-bedded Sands and Laminated Clays. 1903. Glacial Sands, Laminated Clay, Boulder-clay. 1903. Trias, veined and capped by sills of Dole- rite and pierced by Dyke. 1903. Trias, veined and capped by sills of Dole- rite and pierced by Dyke. 1903. Ordovician Greywacke and crushed Grap- tolitic Shales; raised beach. 1903. Ordovician Greywacke and crushed Grap- tolitic Shales; raised beach. 1903. and Photographed by C. A. Martiry, D.Sc., F.G.S., 90 St. Lawrence Road, 4238 Dusuin.—* Photographed by R. Wricn, Lonsdale Street, Belfast. 4239 Clontarf, Dublin. (5) Near Rostrevor . (5225) Esker, Greenhills . Cloughmore Boulder. 1/4. 1902. 1/1. Irregular bedding of Gravels. 1902. 266 REPORT—1904. Photographed by C. A. Matiey, D.Sc., F.G.S., 90 St. Lawrence Road, Clontarf, Dublin. 1/4. Regd. No. 4240 (8) Needle Rock, Howth . . Quartzite stack. 1902. 4241 (1) Killiney Bay ; . . Granite, Cambrian Rocks, and Drift. 1902. Kiipare.—Photographed by C. A. Matiey, D.Sc., F.G.S., 90 St. Lawrence Road, Clontarf, Dublin. 1/4. 4242 (6) Poulaphouca Waterfall . Ordovician Slates. 1902. 4243 (7) sf 7 - ” ” ” Leirrim.—*Photographed by R. Wutcu, Lonsdale Street, Belfast. 1/1. 4244 (5249) ‘Swiss Valley,’ Glencar. Landslip Valley. 1904. 4245 (2061) ~ & ” ” ” LonponDEerRyY.—* Photographed by R. Weucu, Lonsdale Street, Belfast. 1/1. 4246 (5240) Downhill , . North-west edge of Basalt plateau 1903. 4247 (5229) Portstewart Dunes . Kitchen-midden Zones in Sand ys 4248 (5229x) ” ” ” ” ” Siico.—* Photographed by R. Weucu, Lonsdale Street, Belfast. 1/1. 4249 (5248) The Glen, Knocknarea . Narrow Glen determined by Landslide and Joint-planes. 1904. 4250 (67p) is is . Mosses forming a Calcareous Tufa on Limestone Cliff. 1904. 4251 (5245) Keshcorran Caves, Bally- Series of Bone-caves along lower edge of mote. Upper Carboniferous Limestone. 1903. 4252 (5245x) Keshcorran Caves, Bal- Series of Bone-caves along lower edge of lymote. Upper Carboniferous Limestone. 1903. 4253 (5246) Keshcorran Caves, Bally- Cave in well-jointed Carboniferous Lime- mote. stone. 1903. 4254 (61p) Coffey Cave, Keshcorran. Cave in well-jointed Carboniferous Lime- stone. 1903. 4263 (5247) Main Cave, Keshcorran. Great pillar separating two mouths ; from interior. 1903. WicKxiow.—*Photographed by R. Wetcu, Lonsdale Street, Belfast. 1/1. 4255 (5228) Summit, S. of Glenasmole Gully cut into disintegrated Granite under Peat. 1904. Well-sections in Cambridgeshire. By W. Wurraker, B.A., FR.S. [Ordered by the General Committee to be printed in extenso.] Tue well-sections of Cambridgeshire have been duly noted in seven of the nine Geological Survey Memoirs that deal with the county, as follows :— 1878. ‘The Geology of the N.W. Part of Essex . . . with Parts of Cambridgeshire...’ (Sheet 47 of the map,) Five wells, os WELL-SECTIONS IN CAMBRIDGESHIRE. 267 1881. ‘The Geology of the Neighbourhood of Cambridge.’ (Sheet 51 S.W. of the map, with part of 51 N.W.) Ninety-one wells. 1886. ‘The Geology of the country between and south of Bury St. Edmunds and Newmarket.’ (Sheet 51 8.E. of the map.) Eleven wells. 1891. ‘The Geology of Parts of Cambridgeshire and of Suffolk.’ (Sheet 51 N.E. of the map, with part of 51 N.W.) Nineteen wells. 1893. ‘The Geology of South-western Norfolk and of Northern Cam- bridgeshire.’ (Sheet 65 of the map.) Eleven wells. 1900, 1904. ‘The Cretaceous Rocks of Britain,’ vol. i. and vol. iii. Two wells. : The earlier Memoir, the ‘Geology of the Fenland’ (1877), does not refer to Cambridgeshire wells. Ido not know of any further accounts of wells in the county having appeared ; but (chiefly through the kindness of the late Mr. Ingold, well- sinker, of Bishops Stortford) descriptions of twenty-one wells have come to hand, and the meeting of the British Association at Cambridge seems to be a favourable time for making them public. With the 139 already published, they bring the total to 160. No one of them is of any great depth or of special interest, but taken all together they form a useful addition to our knowledge of the county. The figures for thickness and depth are for feet. [Words in these brackets have been added by the writer. ] Balsham. Pusiic WELL NEAR THE ScHoots. 1896. Shaft, bricked for 50 feet. Made and communicated by Mr. G. Incoup. Water at 1534 feet. Thickness Depth 5 2 y Made ground ‘ : 2 Grey clay 3) 5 Brown clay . 5 10 [Boulder Clay] ] Bineclay. 1 2 30 40 Brown clay . ‘ 5 45 Chalk . ; : 25 70 [Upper Chalk] Hard clunch . : 2 72 Chalk . ; . 29 101 [? Chalk Rock] . Very hard clunch . 4 105 Hard chalk . : 50 155 [Middle Chalk] Hard clunch . 1 156 Chalk . : - 33 1594 Mr. JukEs-BrowneE notes the very hard bed as Chalk Rock with doubt. Bottisham. Poxice Srarion. Communicated by Mr. W. M. Fawcett, County Surveyor, from informa- tion from the Contractor, Mr. Lack of Cottenham. Thickness Depth 2 2 Made earth F F 6 hs Chalk marl . 24 26 [Lower Chalk] { Ginch . | 59 85 Gault (blue clay) . 5 ; . 112 197 [Lower] Greensand : - - 27 224 268 REPORT—1904. Bourn. East Hunts WATERWORKS, CLOSE TO OLD NortaH Roap RaiLway Station. 1888 ? Communicated by Mr. M. Froukes. Shaft and cylinders 169% feet, the rest bored. Water-level, 100 feet down ; lowered 45 feet, by pumping at the rate of about 60 to 70 gallons a minute, in 1888. In 1896 only 28 gallons a minute pumped. Thickness Depth Boulder clay [probably includes. gault]. 164 164 [Lower Greensand] Sand ; ; 8} 1723 [2 what] Soft blue clay . : ‘ A 202 193 If the clay be Kimeridge or Oxford Clay, the Gault must here cut down deeply into the Lower. Greensand, or there must be a deep hollow of Boulder Clay. Cambridge. In rue Yarp or Messrs. Foster & Co., Corn MERCHANTS, AT THE RaILway STATION. Communicated by Mr. W. M. Fawczrr, County Surveyor, from informa- tion from the Contractor, Mr, Lack of Cottenham. Thickness Depth Made earth (soil and gravel) . 13 13 Chalk Marl canes and grey). 4 17 [Chalk Marl] { Clunch , 322 492 Gault (Blue clay) . : 5 3 é ee s0s 180 [ Lower] Greensand - : ; : - 28 208 Cambridge. Mr. Epwarps’ Brewery. Made and communicated by Messrs. Ister & Co, Water-level, 18} feet below the surface in the bore-tube. Supply, 500 gallons a minute, with hand-pump. Thickness Depth Well, the rest bored 5 : : ‘ —_ 5 Gravel . ; ; F 6 ll Gault [clay] 5 Be 134 [Gault] A Rock 5 pha | 135 Dead green ‘sand : 4 139 P Rock and sand . 2 141 [Lower Greensand] Rese ; 5 6 147 Sani . ; 13 160 Castle Camps. Pusitic Weti. 1896. Shaft. Made and communicated by Mr. G. INGouD. Water at 115 feet. Thickness Depth Made ground : j 3 3 Blue clay 3 6 Yellow clay 4 10 Brown clay . 7 17 Chalky rubble. 6 23 [Boulder Clay] Blue clay 2 62 85 Light-grey clay . 5 90 Hurrock (chalky rubble). 2 92 Blue and light-grey clay 26 118 Hurrock (chalky rubble) with water 2 120 level 162 feet down. WELL-SECTIONS IN CAMBRIDGESHIRE Castle Camps. Borina By ROADSIDE, NEAR MALTING. 269 Made and communicated by Mr. G. INcoup. Yellow clay . Blue clay [Boulder Clay] Blue sandy loam Blue clay ; hard layer of flints at 27 feet Cherry Hinton. Nerurr Hatt (13 1884, Thickness Depth 4 4 7 11 7 18 2 40 MILE 8.W. oF THE CHURCH). Made and communicated by Mr. G. INcoup, 1. Shaft 32 feet, the rest bored. Soil : ee 3 Hard, loose clunch [Lower Chalk] | Chalk marl Coprolite-bed Gault Hard, green, sandy clay Black, sandy clay Hard, rocky greensand Rock, very hard [Gault, 1423 rf [Lower Green- Sand. sand, 503 feet] | Rock, very hard Hard sand 1893-94. Water rose to within 40 feet of the surface. Sand, changing from light to dark green 2. Seventy yards N.E. of 1. Clunch 4 [Lower Chalk] | Chalk marl Coprolite-bed Gault Plentiful supply. Thickness Depth 4 4 41 45 442 893 12 903 1364 227 2 229 42 2333 7 2403 12 242 2 244 14 2453 23 248 36 284 1893. Shaft 20 feet, the rest bored. "| 82 feet 10 inches 9 feet 2 inches 92 feet. Mr. Juxes-Browye remarks that both sites are above the outcrop of the Totternhoe Stone, as drawn on the published 1-inch map (51 8.W.). Cheveley. Stup Farm, Mr. Cooprr’s. Made and communicated by Messrs. IsteR & Co. Lined with 85 feet of tubes of 6 inches diameter, 12 feet down. Supply about 1,200 gallons an hour. Well (the rest bored) Blue clay and chalk . Blue clay and flints . Blue clay and chalk . [Boulder Clay] Red rock [? boulder]. Blue clay, chalk, and flints Blue clay and flints c Red clay and flints Hard chalk and flints Soft dry chalk . Soft dry chalk and flints [Upper Chalk] ~ Soft dry chalk Blue clay and flints . Hard chalk and flints Very hard chalk and flints 6 Hard chalk and flints Water- Thickness Depth oo 20 22 42 5 17 7 54 3 57 3 B78 103 68 3 71 + 75 20 95 10 105 57 162 ed 199 eel 250 256 7) 66 312 270 REPORT—1904. Cottenham. Pusiic Suppty, 8.W. oF THE VILLAGE. 1898. Communicated by Mr. W. B. FFouKes. About 17 feet above Ordnance Datum. Shaft of 8 feet diameter. Water-level 24 feet down. Loose clay . 20 [Gault n{ Rock we heh 3 2 | 25 feet. [Lower] Greensand . 1 Dullingham. Marine, near Rainway Station. 1876. Made and communicated by Mr. G. INGOLD. Water at 146 feet. Soil . , - ; 5 a * Soft chalk, no flints . 50 }|160 feet. Chalk. { Hard chalk, no flints . 107 Linton. 1. Ponick Sratrion. 1894. 2. Vicarace. 1896, Made and communicated by Mr. G. INcoup. 1. Old well 12 feet, the rest bored. Water-level, 8 feet down. 2. Boring. Water 15 feet down, good supply. 1. 2. Gravel . 12 9 Chalk | 108 } 120 feet { 44} Melbourn. Potice SraTioN IN THE MIDDLE OF THE VILLAGE, JUST BEHIND Inn. 1894. Made and communicated by Mr. G. Incoup. A boring, tubed for 41 feet. Water-level, 144 feet down. Yield, 5 gallons a minute. Thickness Depth 2 2 Soil : 4 5 : 3 j “ : , Brown, sandy chalk, with thin layers of clunch . : , : 4 . 12 14 Hard grey chalk [? Totternhoe Stone] 15 29 Hard clunch . : 1 30 [Lower Chalk] Light-brown chalk, with layers of clunch, changing gradually to the next below 5 F : 3 ; 15 45 Slate-coloured chalk marl . : ; 38 83 Pampisford. THe VICARAGE. Made and communicated by Mr. G. Incotp. Thickness Depth = 2 2 Made ground : : : F ; Hard white chalk. : 43 45 Light-brown clunch . 15 60 : Softer brown chalk . 107 167 [Middle ae 1ko Hard clunch . 5 : 3 170 Eeower Chale Light-brown chalk é 6 176 Blue marly chalk . : 4 180 Brown chalk . 5 : 10 190 WELL-SECTIONS IN CAMBRIDGESHIRE, 271 Sawston. Mr. Evans’ Corracrs. 1885, Bored and communicated by Mr. G. Incoup. Thickness Depth 2 2 Mould = ‘ 4 3 ‘ : Gravel . 3 : : 5 7 PPTL] 7 A) cutlets anniorann 62) tend 9 ; Hard yellow chalk : 11 20 [i Middle ang 41 Softer white chalk | 20 40 J Grey chalk . . : 70 110 Shelford. A mite E. or Station. Dr. Gaskent’s. 1891. Made and communicated by Mr. G. Incoup. Water-level, 86} feet down. Thickness Depth 75 Loose chalk . 75 Solid clunch . 6 81 [Lower Chalk" goft chalk . 7 88 Hard chalk . 30 118 West Wickham. On THE GREEN, NEAR THE WuHitTe Hart Inn. 1884. Made and communicated by Mr. G. Incoup, Some water at 20 feet, more at 36 feet. { Blue clay Si [Boulder Clay] ; Brownclay . 2 } 40 feet. { Blue clay . 35 West Wratting. By Roapsipz, on THE Common. 1885. Bored and communicated by Mr. G, Incoup. Boulder Clay, 51 feet. No water. Whittlesford. Pusnic Wetu. 1886. Bored and communicated by Mr. G. Inco. Water-level 11 feet down. Thickness Depth : ( Gravel , ‘ ij : P 14 14 [Drift] { Brown marl ; F ‘ , 10 24 White chalk, brown in places. 31 55 Chalk . 4 Loose chalk ; . : : 2 yh White chalk : : i ~ 28 85 The following is an addition to a description in the Memoir on ‘The Geology of Parts of Cambridgeshire and of Suffolk’ (1891). Newmarket. Waterworks. Made and communicated by Messrs. Istrr & Co. Made ground *, s08 Dry chalk . 20 [Chalk] | Chalk , 45 [ 90 feet. Clunch . 22 272 REPORT—1904. Investigation of the Fossiliferous Drift Deposits at Kirmington, Lincoln- shire, and at various localities in the Kast Riding of Yorkshure.— Report of the Committee, consisting of Mr. G. W. LaMPpLuGH (Chair- man), Mr. J. W. SraTHer (Secretary), Dr. TrEMpEstT ANDERSON, Professor J. W. Carr, Rev. W. L. Carrer, Mr. A. R. Dwerry- HOUSE, Mr. F. W. Harmer, Mr. J. H. Howartu, Rev. W. JOHNSON, Professor P. F. Kenpauu, Mr. E. T. Newton, Mr. H. M. PLATNAUER, Mr. CLEMENT REID, and Mr. THoMAS SHEPPARD. Owine to circumstances it has only been found possible during the present year to complete the investigation of the deposits at Kirmington and Great Limber, but it is hoped in the future to extend operations to Bielbecks and several other sections that require further elucidation. Kirmington Section. The work on this important section, which was begun last year, has now been carried to a successful conclusion ; and the results show that in some respects this section has no known parallel in English drift sections. It will be remembered that, as described in last year’s report, a brickyard is worked at this place in a mass of warp or clay containing estuarine shells with a freshwater bed at its base, and that this deposit is overlain by a bed of coarse flinty shingle, above which in one part of the pit there is found a few feet of red stony clay believed to be a boulder clay. The boring last year proved the presence of a glacial clay at some depth beneath the warp. The chief object of our investigation has been to discover the relationship of the fossiliferous warp to the Glacial Series, and to carry the boring through the superficial deposits to the chalk, which was not reached last year. During June of the present year a new boring was carried out under the personal supervision of the Chairman and Secretary, with the assist- ance of Mr. G. W. B. Macturk. Mr. Villiers, well engineer, of Beverley, undertook to put down the boring, and the Committee desire to express their indebtedness to him for the ready manner in which, at considerable personal inconvenience, he met their wishes as to the time and conditions of the work. In order to secure a section in another part of the pit, the site of the new boring was fixed at a point 80 yards north-east of last year’s boring. Although at the spot chosen the warp used for brickmaking had been excavated to a depth of 5 feet below the level of its base at the former site, this material was passed through in the new boring to a further depth of 3 feet, so that its base is here 8 feet below its position in the former boring. The total depth attained by the new boring, com- bined with the height of the open section, was 96 feet, or 41 feet lower than was reached last year. The surface of the chalk lay much deeper than was anticipated, and the borings seem to prove that the surface features of the locality are not due to the presence of chalk, as hitherto supposed, but that the rising ground has been formed by the erosion of a thick and complex mass of drift. The diameter of the second boring was at first 4 inches, narrowing ON FOSSILIFEROUS DRIFT DEPOSITS AT KIRMINGTON, LINCOLNSHIRE. 273 to 3 inches at a depth of 15 feet. It was found necessary to line the boring with tubes throughout. The section seen in the brickyard and proved in the borehole was as follows :— Surface soil (at 95 feet above O.D.) J Clay with foreign stones (see NoTH A) . : . Well-worn shingle, principally of battered flin‘s . : : Laminated warp with estuarine shells, and at its base a thin seam of peat associated with a sandy warp containing freshwater shells in one part of the pit (see NoTE B) mil 3) Clean yellow sand, with pebbles of chalk and flint 4 ee Red clay passing downwards into tough reddish-brown clay 7 Purple clay, streaked with silt and loam, passing downwards into tough purple clay with small stones including some erratics (see NOTE C) . 0 Stoneless purple clay - 5 : : 2 : stl Stoneless yellow clay . “ j : : : ¢ =) wuld 4 5 oun — Flinty gravel . : : - . : : Yellow clay and loam with small drift pebbles : : Yellow sand, full of well-rounded quartz grains and specks ofchalk . ; : : : ; : ; Yellow sand and laminated clay . : : ; : : Tough compact lead-coloured clay, with a few small foreign pebbles (see NoTH D). : , , : Tough yellow clay streaked with chalk Solid chalk and flint ‘ 5 Z| oow oo onaoon Total lor) Note A.—Among the erratic stones which this clay contains the following were identified: Basalt, porphyrites, rhomb-porphyry, grits, &c. Nore B.—Mr. Clement Reid records from this bed Serobicularia piperata, Rissoa ulve, Tellina balthica, Cardiwn edule, Mactra subtruncata, Mytilus edulis, and abundant foraminifera (see ‘Mem. Geol. Survey, Holderness,’ p. 58). Mr. Reid has examined the plant remains obtained by the Committee from the band at the base of the warp and reports as follows: ‘The plant remains obtained by Mr. Stather from the peaty warp belong to the following species :— Ranunculus sceleratus, Linn. Atriplex ? Bupatorium cannabinum, Linn. Zannichellia pedunculata, Reichb. Aster Tripolium, Linn. Scirpus setaceus, Linn. Lapsana communis, Linn. a maritimus, Linn. Mentha aquatica, Linn, i sp. Labiate (wuch crushed) Carex incurva, Lightf. ‘The list is a small one, but it indicates estuarine conditions, and suggests a sub-arctic climate. With one exception the plants are still to be found in the neighbourhood of the Humber ; but one of them, Carex incurva, is a sea-coast sedge not now ranging south of Holy Isle. ‘A striking peculiarity of the deposit is the abundant remains of the estuarine sedge, Scirpus maritimus, a plant which, growing out of a few inches of water, tends to form a thick belt through which few drifted seeds would find their way. In view of the abundance of this sedge in the bed now examined and of the like-growing reed, Phragmites communas, in the deposit which I searched some years ago, the small number of other plants yet detected is not surprising. Land plants are only repre- sented by two fruits of Zapsana, perhaps brought by birds. These fruits of oa as well as those of the sea-aster, are considerably smaller : T 274, REPORT—1904. than my recent specimens, but I have not yet had an opportunity of comparing them with fruits of the same species near their northern limit.’ From the fresh-water shell-bed associated with the peat Mr. E. T. Newton has determined Planorbis spirorbis, Bithynia tentaculata, with probably Candona (an Entom.). Nort C.—In general appearance this clay resembles the purple clay of Holderness. Among the pebbles washed out of 30 1b. of the clay brought up by the augur, chalk and flint greatly predominate, but the following rocks were also represented : Red Chalk, black flint, Spilsby sandstone, ferruginous pebbles, quartz, basalt, and porphyrites, besides many undeterminable small pebbles. Note D.—This clay is hard and tough and very different from A and C both in texture and colour. It resembles in colour the basement clay of Holderness. The pebbles are smaller in size than in C, and there is a still higher proportion of chalk and flint. Among the erratic pebbles the following are recognisable :—Basalt, porphyrite, sandstone, black flint, grit, quartz, &c. Great Limber Section. A boring was also put down under the supervision of Mr. G. W. B. Macturk, who kindly undertook to aid the Committee in this manner, at the Great Limber brickyard, three miles south-east of Kirmington, where there is a further development of warp and sand, believed by Mr. C. Reid to be of the same age as the Kirmington deposit, though no fossils have been found in it. The section seen in the brickyard and proved in the boring was as follows :-— Ft. In. Surface soil and clay with stones (at 110 feet above O.D.) 4 0 Loamy sand contorted and mixed with warp . : 4 0 Laminated blue warp with sandy streaks 10 0 Pan . : F ; 1 3 Current bedded sand 4 9 Sharp sand . ‘ : 3 : , S 0 Flint, sand, and rounded chalk pebbles . 5 0 Solid chalk with flints 5 ‘ f 1 0 Total 38 0 In comparing this section with the one at Kirmington it should be noted, (1) that no shells have been found in the laminated warp at Limber ; (2) that the warp does not rest on glacial clays; and (3) that the base of the Limber warp is 92 feet above O.D., or 28 feet higher than that of Kirmington. It would be premature to discuss the problems raised by these inter- esting sections until the work of the Committee has been carried further. For the present, therefore, we desire only to record the data thus far obtained. The thanks of the Committee are due to Mr. W. H. Crofts and Mr. G. W. B. Macturk for practical kelp in many ways ; also to the Earl of Yarborough (landlord), E, P. Hankey, Esq. (agent), and the occupiers of the brickyards—Mr. Hervey and Mr. Jno. Housan—for permission to put down the borings. The Committee request to be reappointed, with power to use the unexpended balance of last year’s grant. a INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 275 Investigation of the Fauna and Flora of the Trias of the British Isles. —Second Report of the Committee, consisting of Professor W. A. Herpman (Chairman), Mr. J. Lomas (Secretary), Professor W. W. Warts, Professor P. F. KENDALL, and Messrs. H. C. BEASLEY, E. T. Newton, A. C. Sewarp, and W. A. E. UssHer. (Drawn up by the Secretary.) (PuAtvES III.-VI.) THE work of the Committee has been continued during the past year, and reports have been received from Mr. H. C. Beasley on ‘Footprints from the Trias, Part II,’ dealing with Rhynchosauroid and Chelonoid forms ; from Mr. E. T. Newton, F.R.S., on ‘ The Triassic Fossils (excluding Rhetic) in the Museum of the Geological Survey at Jermyn Street, London ;’ and from Dr. A. Smith Woodward, F.R.S., on‘ The British Triassic Fossils in the British Museum.’ Complete lists of the Triassic fossils in the two great London museums are included in the reports, together with notes on the more interesting forms, and valuable references are given to works and papers in which the specimens are described or noticed. In the next report the Committee hopes to present similar lists and notes from museums in the provinces. Assistance in this direction has already been promised, and some progress has been made towards tracing types and interesting specimens stored in public and private collections. Tt is essential that the fossils should be correctly named, and those who have the keeping of them are reminded that any specimens sent to the Secretary will be acknowledged and returned after they have been submitted to specialists for determination. I. Report on Footprints from the Trias, Part Ll. By H. C. Brasney. Rhynchosauroid Forms. D 1-5 and KE. In the first portion of this report footprints more or less resembling those originally attributed to the Cheirotherium were described. It is proposed to deal next with those bearing some resemblance to the foot- prints attributed to the Rhynchosaurus, and for which the term Rhyncho- sauroid has been suggested. We are met with some little difficulty at the outset owing to the fact that no figures were given of the footprints described by Dr. O. D. Ward,' and which were referred to by Professor Owen,’ in his paper on Rhyncho- sawrus articeps, neither has the writer been able to find in the Shrewsbury Museum or elsewhere, up to the present, the type specimens. It is not easy to find any example that will exactly tally with the description 1 British Association Report, 1839, ‘On Footprints and Ripplemarks of the New Red Sandstone of Grimshill, Shropshire,’ by O. D. Ward, M.D. 2 Trans. Camb. Phil. Society, vol. vii. p. 355, April 11, 1842. ‘ Description of an Extinct Lacertian Reptile, Rhynchosaurus articeps (Owen), of which the bones and footprints characterise the Upper New Red Sandstone of Grimshill, near Shrews- bury, by Richard Owen, F.G.5., Hunterian Professor at the Royal College of Surgeons,’ eS Te 276 REPORT—1904. either at Grimshill or in other Lower Keuper exposures. Dr. Ward says ‘the footmarks differ from those of Cheirotherium in having only three toes armed with long nails directed forwards and not spreading out, and one hind toe, pointing backwards, having a long claw. No impression of the ball of the foot in this example, but in another there are three toes and a depression for the ball not unlike that of a dog.’ Owen in his paper compares them with the footprints from Shrewley, described by Murchison and Strickland, but says ‘ they differ from them’ (the Shrewley prints) ‘in giving more distinct terminations to the terminal claws and less distinct impressions of the connecting web. The innermost toe is more diminutive, and there is an impression, always at a definite distance from the fore toes, of a hind toe pointing backwards, and which seems to have only touched the ground with its point.’ The Shrewley prints will be dealt with later, but it may be noted that in our Lower Keuper Sand- stones in Cheshire and Shropshire no definite trace of webbing on this form has been observed (the Shrewley prints, it should be noted, are from the Upper Keuper Sandstones). It is also difficult to recognise in them the backward pointing digit. A three-toed print is in Mr, Beeby Thompson’s collection with a mark in the rear, which it has been thought may represent the point of a backward-pointing toe. A somewhat smaller but similar print has been found at Runcorn with a mark in the same position in the rear, but several similar marks are scattered close to the print, and in no case have they quite the appearance of the print of a claw. Another print of the same form, but with a short toe projecting at right angles to the rest of the foot, comes from Storeton. These seem to be varieties of the print described as D 1.! D 1. A four-toed print of which frequently the impression of only three toes is preserved; these three, presumably II-IV, gradually taper from the roots to the ungual termination, the breadth about the middle being 5 mm. when the length is 35 mm. They gradually decrease in size from IV-II. Where I is present it is much shorter than the others, but seems to vary in relative size, being in some prints more than one-half the length of II, at others not a quarter that size ; all the digits are terminated by sharp claws; the three digits lie more frequently side by side, though sometimes they /) diverge, andI usually diverges most. The usual length \ of the print is 3 or 4 cm., but occasionally instances are met with showing much smallerimpressions. The impression of V has been noticed occasionally. The proximal ends of the digits are often in actual contact, but they are also frequently found with a slight space intervening. There is no trace of the ‘ball’ mentioned by Dr. Ward, or any portion of the foot beyond the digits themselves. The width of the print at the base of the three digits is about equal to half the length of the middle or III digit (pl iii.). A very noticeable feature in these prints is a frequent lateral curva- ture with the concavity towards the inner side, and the claws are bent aside in this direction as if unable readily to penetrate the mud in which the impressions were made. Where the digits lie close side by side the cast of the impressions is i er ! All the figures are natural size, except E, p, 279. British Association, 74th Report, Cambridge, 1904.] [Puats III. / Slab of dark red sandstone from Runcorn, with natural casts of D1. About one-fourth actual size. From photograph by Mr. James Ware, of Liverpool. Collection of Mr. H, C. BEASLEY. Illustrating the Report on the Investigation of the Fauna and Flora of the Trias of the British Isles. British Association, T4th Report, Cambridge, 1904.] [Puate IV. Fic. 1.—Natural casts of D2 from Daresbury. About four-fifths natural size. From photograph by Mr, Richard Epmonps, of Liverpool. Dr, Ricker’s Collection, Museum of Liverpool University. Fic. 2.—Natural casts of E from Storeton. About two-thirds natural size. From photograph by Mr. RicHARD EpMoNDs, of Liverpool. Collection of Mr. H. C, BEASLEY. Illustrating the Report on the Investigation of the Fauna and Flora of the Trias of the British Isles. INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 277 strongly convex, as if the middle of the digits sank more deeply into the mud than their roots or terminations, the digits themselves being bent backwards. When the claws are bent sideways they frequently present a triangular impression, as if much compressed laterally ; there is, however, a possibility of this being the result of movement. A much larger print with quite the same character is occasionally found with the IV digit measuring over 6 cm. in length. It also shows the same lateral bend of the digits and claws. It is, however, not advis- able to separate it from the type just described, and it may be included under D1. The frequent absence of any trace of the V digit may either be caused by its being too short to touch the ground, or it may have been turned backwards and only occasionally have left traces of its presence. D 2. There is another form found frequently in the Runcorn district, and occasionally at Storeton and elsewhere, in which the digits are about the same length as in D 1, but are not half the thickness, and are more widely separated at the base. A small but typical example is in the Museum of the University of Liverpool, and was obtained by the late Dr. Ricketts from Daresbury. It shows the five toes, and a little in its rear there is the impression of the corresponding forefoot, or rather what we may suppose to be such, which agrees with it in form, but is somewhat less than one-half the size. In this example the digits D2. 2. at are quite straight, but they are often found bent, and with a sharp flexing of the joints of the phalanges which contrasts strongly with the more regular curvature of D 1 (pl. iv., fig. 1). The digits often have blunt, slightly thickened terminations, and no trace of a claw. This feature seems to occur very frequently in footprints, and it is uncertain D3. 4-—Left pes. whether it implies a difference in structure or is merely the result of a movement of the ex- tremity when the print was made. D 3. A third form, in some respects resem- bling these, has been found in South Staffordshire by Mr. Beeby Thompson in beds rather higher in the Lower Keuper than the footprint beds of Cheshire. It differs principally from D 1 in the form of the V digit. The first is also rather longer than in D 1 and 2. The prints are described and figured by Dr. A. 8. Woodward (‘Geol. Mag.,’ N.S., Decade IV., vol. ix., pp. 213-217, May 1902). He says: ‘The total length of the fore-foot is 0:04 M., and the maximum breadth 0:025 M. As in the hind-foot, the terminal phalanges are very distinctly shown to have the form of sharp claws, and the V digit is slightly opposed to the remainder. The joints of digits I to III are well seen, and comprise respectively two, three, and four phalanges ; but digits I and V are unfortunately indistinct. 278 REPORT— 1904. ‘The hind-foot is -relatively more elongated than the fore-foot, and measures approximately 0-07 M. in length and 0-038 M. in maximum breadth. The first four toes successively increase in size outwards, but the fifth is very small—perhaps, indeed, the smallest. The number of phalanges is two, three, or four in digits I to III respectively, and specimen No. 2 (footprint) shows clearly there are five in digit TV. The palm of the foot, so to speak, is of considerable length, and in the hind- foot much narrowed posteriorly.’ A small form about 25 mm. in length, very closely resembling this, has been noticed from Runcorn on slabs in University Museum, Liverpool, and a less perfect one in the Warrington Museum from the same place. This form differs from D 1 in the greater length of the I digit, in the presence of the impression of the palm which is never seen in the im- pressions D 1 and 2, in the opposable V digit, and also in the well-marked joints of the phalanges. Digits IJ-IV would, however, certainly coincide with many of the imperfect D1 prints. This print is fairly common in the Keuper in South Staffordshire, though seldom found nearly so perfect as those described above. Dr. Woodward suggests that these prints may be referred to Rhyncho- saurus. He also refers to the slab from the Upper Keuper of Shrewley, Warwickshire, described and figured by Murchison and Strickland,' and now in the Warwick Museum, as footprints of Rhynchosaurus. This slab, owing to its long exposure in the museum, has become deficient in the detail, but from a lithograph issued many years ago and from a sketch made in 1897 it is clear that it differs from D3. There are nine distinct pairs of feet, and in every case the fore and hind feet are side by side, the latter, the larger print, being on the outside, whereas in the South Stafford- shire example the manus is in a line with and considerably in advance of the pes. In the Shrewley slab the digits I-IV of the hind foot are distinctly webbed, and there is no trace on any of the impressions of a fifth digit. D 4. In including these under the Rhynchosauroid prints they may be distinguished as D4. Pes only four digits shown, decreasing in size from II to [V—all terminated by claws—distinct D4, 7—Left pes. mark of webbing connecting the digits claws projecting beyond it; total length of print, 4 cm. ; breadth, 25 mm. Manus, three stout toes only shown, with indistinct webbing ; total length, 2 em. These prints are interesting, as, besides giving a complete series, there is a line between the rows of impressions the whole length of the slab, apparently caused by the dragging of a tail. In the forms D1 and 3 the writer has failed to see any certain trace of webbing, though others have thought they have seen indications. It must be borne in mind that the example we have from Shrewley is from a bed of sandstone in the Upper Keuper, underneath which the Rev. P. B. Brodie has noticed the presence of shells of Lamellibranch Mollusca, and in the same bed of sandstone casts of Hstheria minutia are frequent ; so that the conditions 1 Trans. Geol, Society, 2nd series, vol. v. p. 339, plate xxviii. INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 279 were different from those under which the Lower Keuper sandstones were formed. This form might be compared with Sawrichnites rittlerianus (Hoch- stetter), represented by a cast in the British Museum of Natural History (R 1474) from the Lower Permian of Semil, Bohemia. The quarry at Shrewley has yielded many other prints which still require working out. D 5. A print of rather different proportions may conveniently be in- cluded in this group, as there is a possibility of its repre- senting the corresponding manus to one of the foregoing forms. It has not yet been seen in such a position as altogether to warrant such an assumption, though it is generally associated with prints of D 1. In D 5: Only four digits are usually shown, No. IV, about 2 cm. in length, being the longest. No. I is the shortest, 1 cm. The breadth of IV in the widest part is 4 mm. The digits are divergent, tapering, and somewhat laterally curved. They are in contact at the roots (the articulation with the metacarpals 4), which are marked by the presence of round pads. The width of the impression here is 15 mm. This form will be seen to differ from D 1 not only in its smaller size but in its greater proportional breadth and the more rapid taper of the digits. "E. There is a small footprint described! as E=Rhynchosaurus mint- mus (Morton). This was first described from fairly perfect examples of both pes and manus from Storeton, and afterwards a complete series of seven pairs of the same prints was found at Runcorn. E. 2.—Left Pes: The outer digit, probably IV, is the longest, * pes. 10 mm., on the inner side of II, and slightly in the rear is a very short hallux. h II-IV are divergent, curve inwards, and terminate in sharp claws. They frequently have very blunt ends; from the centre of each a fine sharp claw projects. There is no distinct mark of a claw on the hallux. The breadth of N the footprint across the proximal ends of the digits is 1 em. (pl. iv., fig. 2). The manus, represented by four detached toes, is much smaller than the pes, being 5 mm. long by 7 mm. broad. The digits are less diver- gent than those of the pes ; their diminutive size prevents the recognition of any details in a coarse material like sandstone. In neither the pes nor manus is there any trace of webbing. On the Runcorn slab there are four pairs of impressions of right feet and three of left. The impressions of a fore and hind foot are in every case side by side, the hind foot being on the outside, with an interval of about a centi- metre between it and the manus. The length from one of the feet to the next impression in front is 10 cm., and a line drawn outside the hind — one side would be 6 cm. distant from a corresponding line outside e left. This is a very common form, and its size varies greatly, some prints of the pes reaching 2 em. in length. The form of the print also varies very D5. 1—Manus? 1 ' Proce. Liv. Geol. Society, vol. vii. 1895, p. 402. 280 REPORT—1904. much, a variation probably due to mechanical causes and not to any difference in the form of the foot. A form rather longer than the type is seen on slabs from Coven, South Staffordshire, in the Victoria Institute, Worcester, and in the Liverpool Museum. Chelonoid Forms. F 1-2. The distinguishing features of the prints included in this group are the presence of a distinct palmar surface covering a large portion of the area of the print and of short strongly clawed digits. Fil. j. F 1. The most common and also the simplest form nan that has been seen consists of an oval gently rounded n 5 A i surface measuring about one inch by three-quarters of an inch, with marks of four or five claws a little in front of the longer margin. This is fairly common both at Runcorn and Storeton ; the best example is in a slab from Storeton, in the Bootle Museum, No. 9, which is nearly covered with them. The original label is still attached, ‘ Footmarks from Storeton of Lizards and Tortoises, Natural History Society.’ It is identical with Sawrichnites perlatus | (Fritsch), and Mr. Morton includes it in his Chelone ? subrotundus. F 2. This is a much less simple form, and presents some difficulties of interpretation. It consists of an irregular oblong about the same size as the oval of F 1, divided into regions by slight F 2. 41,.—Manus? depressions : from the front of this project four short cylindrical parallel digits, and a fifth’ in- distinctly marked is often present. Each digit is armed with a strong, sharp claw, having a . slight protuberance at its base. The claws are almost sickle-shaped, and appear to have pointed obliquely upwards, but there is a diffi- culty in making out their normal position. The best example seen is from Storeton (pl. v.). It measures 30 mm. wide by 33 mm. from the posterior margin of the print to the outer boundary of the claws. The length of the IT digit to the root of the claws is 5 mm., and the claw itself about 7 mm. Although the slab of stone is of considerable size, it unfortunately con- tains but this one recognisable print of this form. From other speci- mens it would seem to make a track 8 inches wide with length of stride 9 inches, the right and left prints alternating. Further observa- tions are required to confirm this. There is a large slab showing these prints in the Liverpool Museum. Some prints have recently been found at Runcorn of approximately the same size, but with the digits fully 1 cm. long, not including the claw, or twice the length of the type. The same elongation of the digit is also seen on a slab in Liverpool University Museum, whilst in another print close by, apparently made by the same individual, the digits are of the typical proportions. The general appearance of the prints suggests a burrowing habit and a resemblance to the foot of the common mole. It was described and figured by the writer in 1897,” together with a note from Professor Seeley ! Letter to the writer, 2 Observations regarding a Footprint from the Keuper Sandstone at Storeton, British Association, 74th Report, Cambridge, 1904.] [PuatE V. Slab of grey sandstone from Storeton, with casts of F2, D1, &c., and tracks of Invertebrates. About one-third actual size. Fio.n photograph by Mr. JAMES WAITE, of Liverpool. Collection of Mr. H. C, BrasLery. Ulustrating the Report on the Investigation of the Fauna and flora of the Trias of the British Isles. [Puatr VI British Association, 74th Report, Cambridge, 1904.] Skull of Capitosaurus stantonensis, from Stanton, North Statfordshire. Naiural History Museum, South Kensington About half natural size. ea the Report on the Investigation of the Fauna and Flora of the Trias of the British Isles. INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 281 on the apparent structure of the foot, pointing out its resemblance to that of an Anomodont reptile. Mr. Morton includes this form also in Chelone subrotundus. The print is, however, so different from F 1 that it is advisable to distinguish it as F 2. Prints of this form are occasionally found with the posterior margins of two prints in contact and the digits pointing outwards. This is probably the origin of very peculiar print described and figured by Dr. Black from Weston.! The Chelonoid forms will also include the footprints described and figured by Dr. Duncan,” from Dumfriesshire, and several of those in Sir William Jardine’s work on the ‘Ichnology of Allandale’ as well as many of the Elgin footprints. The examination of the Scotch footprints is not concluded, and their description must be deferred. Incerte Sedis. I and M. There are many forms which can hardly be included in any of the groups that have been dealt with, but which may be described here. I. This form was described and figured in 1894 by Mr. O. W. Jeffs,? from a specimen now in Chester Museum (No. 129, from Storeton), and mentioned by Mr. Morton as Rhynchosaurus tumidus and also described and figured by the writer‘ in 1898 from the ne? Chester and other examples. A small four-toed print about 25 mm. long by about half that width. Three stout fleshy digits lie close and parallel to each other, and a fourth much shorter digit on one side somewhat in the rear of the adjoining one. All the digits have blunt extremities beyond which project fine sharp claws. The divisions between the digits are usually very indistinct, but appear to be rather more than half the total length of the print. The posterior margin is not very well defined. There are a number of very small footprints which are M. }.- too imperfect generally to be described in detail ; one, however, found at Hilton Beck, Westmoreland (St. Bees Sandstone), and at Runcorn, might be noticed here. M. A very small print of triangular outline, the apex being the heel, three stout toes, the middle one rather longer than the others, which diverge equally on either side ; no traces of claws ; length of middle digit more than half that of the whole print ; length of print 5 mm. Spread of the toes at the distal extremities 4 mm. There remain for further investigation many other prints from the Lower Keuper as well as those from the Upper Keuper and those from Scotland. The tracks of invertebrates are very numerous (pl. v.), and with a Note on the probable Structure of the Foot by Professor H. G. Seeley, F.G.8., &e., by H. C. Beasley, Zrans. Liverpool Biol. Soc., vol. xi. p. 179, pl. vii. (1896-97). ‘ Observations on a Slab of New Red Sandstone from the Quarries of Weston, near Runcorn, Cheshire. Certain Impressions of Footprints in other Marking, by J. Black, M.D., Q.J.G@.S., November 1845, p. 479. * An Account of the Tracks and Footmarks of Animals found impressed on Sand- stone in the Quarry of Corncockle Muir in Dumfriesshire, by Rev. H. Duncan, D.D., Minister of Ruthwell, 7rans. Roy. Soc. Hdin., vol. xi. 1828. * Journal Liverpool Geological Association, vol. xiv. * Proc. Liverpool Geological Society, vol. viii. p. 234. 282 REPORT—1904. though their origin is very uncertain it is advisable that they should be recorded. Nore.—Mr. Morton, in his appendix to the ‘Geology of the Country around Liverpool,’ p. 299, gives names to six forms which he thinks cover all the footprints found in the district. He left a collection made by him of photographs, prints, and drawings of footprints, to which he has attached the names given by him, so that there is no difficulty in correlating his species with those described in this report, viz.— Cheirotherium storetonense = A I, II & III. 3 minus = BI& II. Rhynchosaurus _articeps = Dew: iB ? minimus = E. PA ? tumidus = als Chelone ? subrotundus = F, II. Notes on the Triassic Fossils (excluding Rhetic) in the Museum of the Geological Survey at Jermyn Street, London. By EK. T. Newron, FRS., F.GS. The number of Triassic fossils (excluding those from the Rhetic deposits) preserved in this museum is not great, but some of them are of exceptional interest. Among the imperfect plant remains Volizia is the only genus that has been recognised, and the specimens are by no means satisfactory. The little crustacean Lstheria minuta is represented by examples from several localities. Marine mollusca had not been recognised in the English Trias until about eleven years ago, when Mr. Percy Richards discovered specimens in a greenish gritty clay at Shrewley, near Warwick, which he presented to this museum. Other examples were obtained by the late Rev. P. B. Brodie, which are now in the British Museum at South Kensington. The two series formed the basis of Mr, R. B. Newton’s paper in the ‘Journal of Conchology,’ vol. vii. 1894. The remains of fishes are fairly abundant in the Trias, Elasmobranchs and Ganoids being represented in this collection, the former by spines and teeth and the latter by more or less perfect bodies. The unique Dipteronotus cyphus from the Keuper of Bromsgrove calls for special notice, as it is the type of the genus and species which was described by Egerton in 1854, and the form does not appear to have been again met with during the fifty years that have passed since that paper was published. There is a portion of a lower jaw of a Labyrinthodon from the Lower Keuper of Cubbington, Warwickshire, described by Huxley in 1859 in the Memoirs Geol. Survey, ‘The Warwickshire Coal-field,’ p. 56, which may be the same species as that described by Professor Seeley in 1876 in the ‘Quart. Journ. Geol. Soc.’ under the name of Labyrinthodon Lavist ; but our specimen is somewhat larger, and Huxley thought it indicated a jaw two feet in length. The museum possesses numerous remains of Stagonolepis Robertsoni from the Elgin Sandstone of Lossiemouth, specimens which were described by Huxley in the ‘ Quart. Journ. Geol. Soc.’ for 1859 and in the Geol. Survey Monograph, III. : ‘ Crocodilian Remains found in the Elgin Sand- stones.’ These remains consist largely of hollow moulds in blocks of INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 283 sandstone, and many of the casts made from these are figured in the above-mentioned works. —~ Other forms that have been described and figured by Huxley in the ‘Quart. Journ. Geol. Soc.’ for 1869 and 1870, and are preserved in this museum, are Paleosawrus cylindrodon, Teratosaurus (Zanclodon), and Hyperodapedon Gordoni. The remarkable horned reptile Liginia mirabilis, from the Triassic sandstone of Cutties Hillock, near Elgin, as well as several species of the Dicynodonts Gordonia and Geikia from the same locality, described in the ‘ Philosophical Transactions’ for 1893, are represented in the museum by the original casts (taken from the natural moulds in sandstone) which were figured in the plates accompanying the above-mentioned paper. The original sandstone mould of Gezkia is also here, but the other moulds are in the Survey collection at Edinburgh or in the Elgin Museum. Two other forms from the Triassic sandstone of Spynie and Lossie- mouth, which were described in the ‘ Philosophical Transactions’ for 1894 under the names of Ornithosuchus Woodwardi, N., and LErpetosuchus Granti, N., are likewise here represented by the original casts from which the figures were drawn, the sandstone specimens themselves being in the British Museum at South Kensington. Two slabs of footprints from the Elgin Sandstone of Cummingstone, near Elgin, figured by Huxley in the ‘ Memoir of the Geological Survey,’ above mentioned, are also preserved in this museum. The following isa list of all the species from the Trias (excluding Rhetic) represented in this museum, with the localities from which they were obtained. The figured specimens are indicated, and references are given. F.—Figured ; T.=Type. PLANT. Name Formation Locality Voltzia ‘ : 5 ‘ . Keuper : . Ashley Heath, Market Dray- ton. ” : . Upper Keuper . Pendock, Worcester. Fucoidal remains 4 : ef * . Rowington, Warwick. Plant remains. : : - Keuper . Bromsgrove. ” . : ; ‘ : y F . Fulford Quarry, Longton. CRUSTACEA, Estheria minuta, Alberti . . Lower Keuper . Alderley Edge, Manchester. » re oi ’ ‘ . Keuper . . Buttermill Hill, Needwood Forest. a Seas : : . “brie, ; . High House, Warwick. ” 30 ous ; ; . Upper Keuper . Hill End, 1 mile N.W. of Pendock. ” sweke : : be RETASs. : . Morton Bagot. ” Ties : . . Upper Keuper . Newent, Gloucester. ” aie 3 : : = Us . Pendock, Ledbury. ” ” : : 2 3 t. . Shrewley, Warwick. ” sae : ; > Kenuper . . Fulford Quarry, Longton. MOLLUSCA., T. Nucula keuperina, R.B.N., Upper Keuper . Shrewley, Warwick. figured ‘Journ. Conch.,’ vol. vii. 1894, p. 413, T. Pholadomya Richardsi, R.B.N., figured Joe, cit., p. 412, ” 9 = ” ” 284, Name Hybodus (Sphenonchus) ” ” Acrodus heuperinus, Murch. (teeth). (Hybodus) keuperinus (spines). Sagenodus sp. eee “oe cast . Coprolites . : Paleoniscoid fish : : Dictyopyge catopteru, Ag. . ; F. Semionotus. Figured by E. T. Newton, ‘ Quart. Journ. Geol. Soc., vol. xliii, 1887, pl. xxii. fig. 8. REPORT—1904. PISCES. Formation Trias . Upper Keuper ” ” Trias Hf sine Upper Keuper Keuper Upper Keuper Keuper i Upper Keuper Trias . Lower Keuper Upper Keuper Bunter Upper Keuper T. Dipteronotus cyphus, Eger- Keuper ton. Type. of genus and sp. figured by Egerton, ‘ Quart. Journ. Geol. Soc.,’ vol. x. 1854, pl. xi. AMPHIBTA., Labyrinthodont jaw, mentioned Lower Keuper by Huxley in‘Mem. Geol. Sury. Warwickshire Coal-field,’ p. 56 Labyrinthodont . Upper Keuper + (tooth) - BS a f Lower Keuper 3 (scute) Keuper F. Stagonolepis Robertsoni, nu- merous specimens figured by Huxley in the ‘Quart. Journ. Geol. Soc.,’ vol. xv. 1859, pl. xiv. and in ‘Mem. Geol. Surv.,’ Monograph III. ‘ Croco- dilian Remains found in Elgin Sandstones.’ Dinosaurian jaws. F. Paleéosaurus cylindrodon, fig- ured by Huxley, ‘Quart. Journ. Geol. Soc.,’ vol. xxvi. 1870, pl. ili. fig. 4. ¥. Teratosaurus (Zanclodon), fig- ured by Huxley, loc. cit., pl. iii. fig. 11. Thecodontosaurus : ~ F. Hyperodapedon Gordoni, fig- ured by Huxley, ‘ Quart. Journ. Geol. Soc., vol. xxv. 1869, p. 145. REPTILTIA., Tash. Trias ? Lower Keuper Keuper Lower Keuper Locality High House, Warwick. Hill End, 1 mile N.W. of Pendock. Shrewley, Warwick. Pendock, Worcester. High House, Warwick. Moor Court, 4 mile N. of Pen- dock. Blagdon, Somerset. Pendock, Ledbury. Shrewley, Warwick. Near Frome? Moor Court, $ mile N. of Pen- dock. Spynie, Elgin. Coton End, Warwick. Colwick Wood, Nottingham. Roan Hill, Tyrone. Colwick Wood, Nottingham. Bromsgrove, Subbington, Warwickshire. Shrewley. Glover’s Hill Cutting, Ripple, Worcester. Coton End, Warwick. Near Frome ? Lossiemouth, near Elgin. Kenilworth. Coton End, Warwick. Bristol. Coton End, Warwick. INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 285 Name Formation Locality Hyperodapedon Gordoni, men- Trias . : . Otter River, Budleigh Salter- tioned by Huxley, loc. cit., ton, Devon. pp. 141, 146, 148 T. Elginia mirabilis; Newton. Trias . : . Cutties Hillock, Elgin. T. Gordonia Traquairi; ,, rae F ; A Pe TS ds Huxleyana; ,, AL Ae : : - . i: A Duffiana; ,, ht ae . a s * Hi + Juddiana; ,, sy 2 é : 5 a T. ” sp. i ” ” p . . ” ” All the above species of Elginia and Gordonia are represented by the gutta. percha cast from which the figures were drawn. The original moulds in sandstone are either in the Geological Survey Museum at Edinburgh or in the Elgin Museum See ‘ Phil. Trans.,’ vol. clxxxiv. (1893), B, p. 431, pls. xxvi.—xli. T. Geihia elginensis, Newton. Trias . : . Cutties Hillock, Elgin. The sandstone mould as well as the gutta-percha cast from which the figures were drawn. See ‘ Phil. Trans.,’ vol. clxxxiv. B, 1893, pl. xxxvi. T. Ornithosuchus Woodwardi, ‘Trias . d . Spynie, near Elgin. Newton. Castin gutta percha, from which the drawings were made. The original specimen is in the British Museum at South Kensington. See ‘Phil. Trans.,’ vol. clxxxv. 1894, B, p. 586, pls. liv._lvi. T. Erpetosuchus Granti, New- Trias . : . Lossiemouth, near Elgin. ton. Casts in gutta percha, from which the figures were drawn. ‘The original mould in sandstone is now in the British Museum at South Kensington. See ‘ Phil. Trans.,’ vol. clxxxv. B, 1894, p. 574, pl. liii. FOOTPRINTS. Footprints . ; : : . Lower Keuper . Storeton, Cheshire. Rhynchosaurus . ‘ : : is F. Slabs of footprints of several Trias . sizes from less than an inch to nearly 8 inches long. See ‘Mem. Geol. Surv.,’ Mono- graph III., pls. xiv., xv., and XXvi., and ‘Quart. Journ. Geol. Soc.,’ vol. xv. 1859, pl. xiv,, figs. 4, 5. ” ” ” Cummingstone, near Elgin. III. List of British Triassie Fossils in British Museum. By Dr. A.Smira Woopwarp, /.2.8., F.GS., F.Z.S. REPTILIA, Erpetosuchus Granti . . E.T. Newton, ‘Phil. Trans.,’ vol. clxxxv. B, 1894, p. 574, pl. liii. Impressions of skull and portions of the skeleton, the type specimens (R. 3,139) from the Trias of Lossie- mouth or Spynie, near Elgin. Hyperodapedon Gordoni » Huxley, ‘Quart. Journ. Geol, Soc.,’ vol, xv., 1859, p. 435. 286 Hyperodapedon Gordoni Ornithosuchus Woodwardi Rhynchosaurus articeps Stenometopon Taylori Stagonolepis Robertsoni Telenpeton elginense Capitosaurus stuntonensis , REPORT—1904. Skull and skeleton (R. 699) described by Huxley in ‘Quart. Journ. Geol. Soc.,’ vol. xliii. p. 675, pl. xxvi., woodcuts land 4; also Burckhardt, ‘ Geol. Mag.,’ 1900, pp. 486 and 529. Portions of mandible (R. 3,138) figured by Huxley, op. cit., figs. 7 and 8. Fragments of skull (R. 3,137) noticed by Huxley in ‘Quart. Journ. Geol. Soc., vol. xxv., 1869, figs. 7 and 8. Portions of skull (R. 3,140) described and figured by Boulenger in ‘Phil. Trans.,’ vol. excvi. B, 1903, p. 175, pl. xi. Portions of skeleton (R. 3,148). From the Trias of Lossiemouth, near Elgin. K. T. Newton, ‘Phil. Trans.,’ vol. clxxxv. B, 1894, p. 586, pls. liv.—lvi. Skull and portions of skeleton, the type specimens (R. 2,409, 2,410). Portionsofskeleton (R.3,142),some figured by Boulenger in ‘ Phil. Trans.,’ vol. excvi. B, 1903, pl. xv. Portions of skull and skeleton (R. 3,143) figured by Boulenger, tom. cit., pl. xiv. ? Portions of skull and skeleton (R. 3,149) Trias of Spynie, near Elgin. Owen, ‘Trans. Camb. Phil. Soc.,’ vol. vii. 1842, p. 355. Skull and parts of mandible (R. 1,236) described and figured by Huxley in ‘Quart. Journ. Geol. Soc.,’ vol. xliii. 1867, p. 689, pl. xxvii., fig. 1, and wood- cuts 2 and 5. Portions of skeleton of same individual as last (R. 1,238). Right pes fig. by Huxley, loc. cit., pl. xxvii. fig. 5. Portion of skeleton (R. 1,239) figured by Huxley, Joc. cit., pl. xxvii. figs. 2-4. Palatal portion of skull (R. 1,237). Caudal region (R. 1,240). Limb (R. 1,241). From the Keuper of Grinshill, Shropshire. Boulenger, ‘ Phil. Trans.,’ vol. excvi. B, 1903, p. 178, pls. xli. and xiii. Skull and portions of skeleton, type specimens. Trias of Lossiemouth, near Elgin. Agassiz, ‘Recherches sur les Poissons Fossiles du Vieux Grés Rouge,’ 1844, p. 139. Numerous impressions of scutes and some fragments of bone. ‘Trias, Lossiemouth, near Elgin. Mantell, ‘Quart. Journ. Geol. Soc.,’ vol. vili. 1852, p. 100. Skeleton (R. 3,136) described and figured by Huxley in ‘Quart. Journ. Geol. Soc.,’ vol. xxiii. 1867, pp. 77-84, text figures A-H. Also Boulenger in ‘Proc. Zool. Soce., vol. i. 1904 (not yet published). Skull and skeleton (R. 3,144) described by Boulenger, tom. cit. Imperfect skull (R. 3,147) described by Boulenger, tom. cit. Trias, Lossiemouth, near Elgin. LABYRINTHODONTIA. A. 5. Woodward, ‘ Proc. Zool, Soc.,’ 1904, vol. ii. (not yet published). Preliminary notice by J. Ward, ‘Trans. N. Staffs Field Club,’ Feb. 22, 1900, pls. iv. and v. Type. A skull from the Lower Keuper of Stanton, near Norbury, North Staffordshire, - INVESTIGATION OF FAUNA AND FLORA OF TRIAS OF BRITISH ISLES. 287 Capitosaurus stantonensis Acrodus (?) heuperinus . Ceratodus levissimus Dictyopyge catoptera Dictyopyge superstes Phebodus Brodiei Semionotus Brodiei Estheria minuta Thracia (?) Brodiei. Pholadomya (?) Richardsi Nucula heuperina , The block of sandstone containing the skull was split along the plane of the cranial roof, leaving most of the roof bones adherent to one slab, while the impression of these with the rest of the skull remained in the counter-part slab, as shown by the photograph (plate vi.). The skull is distinguished from that of all known species of the genus by the shape of the occipital border and auditory notches, as also by other characters. PISCES. (Murchison and Strickland.) A. 8. Woodward, Catal. Foss. Fishes, B.M., pt. i, 1889, p. 281, pl. xiii, figs. 1 and 2; ‘Ann. Mag. Nat. Hist.’ (6), vol. iii. 1889, p. 297, pl. xiv., figs. 1-3, and Joe. cit., vol. xii. 1893, p. 283, pl. x., fig. 5. Teeth and dorsal fin-spines and cephalic spines from Upper Keuper of Pendock, Ripple, and Burgehill, Worcestershire ; from Shrewley and Rowington, Warwickshire. L. C. Miall, Siren. and Crossopt. Ganoids, pl. i. (‘ Pal. Soc.,’ 1878), p. 32, pl. v., fig. 2; A. S. Wood- ward, ‘Ann. Mag. Nat. Hist.’ (6), vol. xii. 1893, p. 282, pl. x., fig. 1. ; Two teeth, the type from Upper Keuper of Ripple, Worcestershire ; the other from Lower Keuper of Coton End, Warwick. (Agassiz.) R. H. Traquair, ‘ Quart. Journ. Geol. Soc.,’ vol, xxxiii., 1877, p. 567. Palg@oniscus catopterus, Agassiz, ‘ Poiss. Foss.,’ vol. ii., pt. i, p. 303 (name only), and Egerton, ‘ Quart. Journ. Geol. Soc.,’ vol. xiv., 1858, pl. xi., fig. 4. Shoals of fishes from Keuper, Roan Hill, Tyrone. (Egerton.) K. A. von Zittel, ‘Handb. Palzont.,’ vol. iii., 1887, p.203. Paleoniscus superstes, Kgerton, ‘Quart. Journ. Geol. Soc.,’ vol. xiv. 1858, p. 164, pl. xi., figs. 1-3. Type: A fish from Upper Keuper of Rowington. A. S. Woodward, ‘ Ann. Mag. Nat. Hist.’ (6), vol. xii, 1893, p. 282, pl. x., figs. 2-4. Type: Teeth from Upper Keuper of Shrewley, Warwickshire. E. T. Newton, ‘Quart. Journ. Geol. Soc.,’ vol. xliii. 1887, p. 538, pl. xxii., figs. 1-8. Type: Imperfect fishes from Upper Keuper of Shrewley, Warwickshire. CRUSTACEA. (Alberti.) From Keuper of Alderley Edge, Cheshire ; Shrewley, Warwickshire; and Pendock, Worcestershire. Also from ‘ Trias near Shrewsbury.’ MOLLUSCA. R. B. Newton. R. B. Newton. R. B. Newton. Type specimens presenting a marine facies, described by R. B. Newton, ‘Note on some Molluscan Remains lately discovered in the English Keuper,' ‘Journ. Oonchology,’ 1894, vol. vii. p. 408, 288 REPORT—1904.. Nucula keuperina . : . From Upper Keuper, Shrewley, Warwickshire, asso- ciated in the matrix with Acrodus keuperinus and Estheria minuta. PLANTA, Canpolithes, sp. . : . Seward, ‘ Catalogue Mesozoic Plants,’ B.M., pt. iv. 1904, p. 7. From Keuper of Longdon and Rowington, Warwick- shire. Also indeterminate fragments of Coniferz from Keuper of Rewington and Leicester. Idenvale Caves, Co. Clare.-—Final Report of the Committee, consisting of Dr. R. F. Scuarrr (Chairman), Mr. R. L. PRAEGER (Secretary), Mr, G. Correy, Professor G. A. J. CoLz, Professor D. J. Cun- NinGHAM, Mr. G. W. Lamptucy, Mr. McHenry, and Mr. R. J. UssHER, appointed to explore Irish Caves. (Drawn up by the Chairman. ) Since our last report was submitted to the British Association, Mr. Ussher has completed the excavations of the extensive caves of Edenvale, co. Clare, and sent altogether a collection of more than 50,000 bones to be named. Besides these there were flints and implements used by primi- tive man and relics of various periods on which it is proposed to submit a detailed report to the Royal Irish Academy during next winter. Mr. Ussher has explored other districts of Ireland with the view to continuing the cave researches, but this Committee do not propose to apply for a further grant. The Edenvale remains have not been fully determined, but so far they have yielded the following species :— Man . E . (Homo sapiens) Arctic Lemming. (Dicrostonyx torqua- Bats . : . (Several species) tus) Hedgehog . . (Frinaceus ewropeus) Domestic Ox . (Bos tawrus) Domestic Cat . (Felis domestica) Domestic Sheep. (Ovis aries) Wild Cat. . (Felis caligata) | Domestic Goat . (Capra egag7rus) Dog . : . (Canis familiaris) Domestic Pig . (Sus serafa domestica) Hox: : . (Vulpes alopex) Wild Pig . . (Sus serofa ferus) Trish Stoat . . (Putorius hibernicus) | Red Deer . . (Cervus elaphus) Marten : . (Mustela martes) Giant Deer . (Megaceros giganteus) Bear ~~ : . (Ursus arctos) Reindeer . . (Rangifer twrandus) Badger : . (Meles taxus) | Horse : . (Eqs caballis) Arctic Hare . (Lepus timidus) | Birds . C . (Many species) Rabbit : . (Lepus cuniculus) Frog . : . (Rana temporaria) Trish Rat. . (Mus hibernicus) Fishes ; . (Several species) Field-mouse . (Mus sylvaticus) Land Mollusca . (Many species) The Influence of Salt and other Solutions on the Development of the Frog.—Report of the Committee, consisting of Professor W. F. R. WELDON (Chairman), Mr. J. W. JENKINSON (Secretary), and Professor 8. J. Hickson. (Drawn up by the Secretary.) Tue object of this investigation is to discover whether the distortion of development, or monstrosity, produced by growing the eggs of the frog in a certain concentration (about 0°6 per cent.) of common salt solution is due to the physical—increased osmotic pressure—or chemical properties of the solution, or both. ON THE DEVELOPMENT OF THE FROG. 289 The monstrosity consists in (J) the failure of the blastopore to close, so that a large persistent yolk-plug is produced ; and (2) the failure of the medullary folds to close either (a) throughout, or (3) partially, generally in the region of the brain, so that a sort of anencephalous monster results. With this object the eggs have been grown in solutions whose con- centration is isotonic with that of a 0°625 per cent. solution of sodium chloride, of the following substances :— (1) Chlorides of potassium, lithium, ammonium, calcium, magnesium, barium, strontium ; (2) Bromides of these seven bases and of sodium ; (3) Todides of sodium, potassium, lithium, and ammonium ; (4) Sulphates of sodium, lithium, ammonium, and magnesium ; (5) Nitrates of sodium, lithium, ammonium, potassium, magnesium, strontium, and calcium ; (6) Cane sugar and dextrose ; (7) Urea. The external characters of the embryos produced in these solutions have been determined ; the microscopical examination of sections is in progress. The results obtained, as far as they can at present be stated, are these. The effects produced by the above solutions on the develop- ment of the frog may be divided into four classes : I. Chlorides of ammonium, strontium, barium, calcium ; bromides of ammonium, strontiwm, barium, calciwm, and magnesium, iodides of lithium, ammonium, and potassium ; nitrates of ammonium, calcium, and strontium. In all these the egg dies at a comparatively early stage, sometimes auring segmentation, sometimes when the dorsal lip of the blastopore has just appeared ; occasionally a very irregular circular lip may be completed. The large yolk-cells seem to be affected first, the small animal cells continuing to divide for some time ; but as the normal overgrowth of cells at the lip of the blastopore is prevented, the roof of the segmentation cavity is thrown into folds and wrinkles. Mesoderm cells are formed at the equator of the egg, but thrown into the segmentation cavity. Ultimately all the cells and their nuclei undergo disintegration and degeneration: they are found lying in a coagulum— easily visible to the naked eye—produced by the fusion and liquefaction of yolk-granules. It seems possible that the salts enter the tissues and there form with the carbonic acid given off by the cells insoluble carbonates, as bubbles are given off when the eggs are placed in hydrochloric acid. II. The egg loses its power of elongating in the direction of the longi- tudinal axis of the embryo, that is, remains spherical or nearly so ; differentiation of the germ-layers and of the organs of the embryo proceeds nevertheless. This effect is produced by chlorides of potassium and lithium, bromides of sodium, potassium and lithium, iodide of sodium, sulphates of lithiwm and ammonium, and nitrates of lithium and potassium. In all these a large circular blastopore is formed enclosing a corre- spondingly large yolk-plug. This yolk-plug is only very slowly withdrawn, if at all. The medullary folds may or may not close. There is variation in this 1904. U 290 REPORT—1904. respect not only between embryos grown in different solutions, but even between those grown in one and the same medium. There is a spacious bilateral archenteron extending in front of the dorsal lip of the blastopore: The mesoderm is formed in the usual manner, partly from cells in the neighbourhood of the blastoporic lip, partly by differentiation of yolk- cells which have been pushed into the segmentation cavity. This cavity is obliterated. The notochord is not formed in quite the normal fashion, that is, by the splitting off of a rod of cells from the roof of the archenteron. Its formation in these monsters recalls the mode of its origin in the Urodela, Gymnophiona, and Petromyzon ; a median strip of the whole thickness of the roof of the archenteron is folded off, while cells from the sides grow beneath this to complete the definitive roof of the gut. The following organs are formed, though their development is often abnormal ; as, for example, when the cavity of the optic vesicleis reduced to a narrow slit :— The suckers; the optic vesicles, but not the lens; the auditory vesicle ; the infundibulum ; the pituitary body; the neural crest, with the vagus and trigeminus ganglia; the protovertebree ; a trace of the splanchnoceel ; the liver diverticulum. Normal histological differentiation may set in, for example, in the cells of the suckers and of the notochord. The notochord seems to retain its capacity of growth in the direction of its long axis ; it becomes bent and twisted in both a vertical and a horizontal plane. Ultimately degeneration and disintegration of the embryonic tissues sets in. The parts most commonly affected first are the medullary groove (or tube), the lips of the blastopore (when this has not closed), and the general ectoderm. Later the yolk-cells become altered and die. These changes are as follows :— (1) Grey degeneration, seen usually in the medullary groove. The cells protrude above the surface ; the pigment retreats to the inner end, leaving the cells white ; the cells fall out. (2) Wrinkling and pitting of the surface. The ectoderm is thrown into folds ; the cells are cast out. (3) Liquefaction of the yolk-cells by fusion of yolk-granules. This cellular disintegration is accompanied by degeneration of the nuclei. It is a common occurrence for these dying embryos to become con- stricted into two parts, one portion being pushed bodily through the vitelline membrane into the jelly as an ex-ovate. III. The embryo is able to elongate, but development is abnormal, particularly in the closure of the blastopore and medullary folds. Degeneration and death eventually follow. (a) Sodium chloride and sodium nitrate. There is a large persistent yolk-plug. The medullary folds fail to close, most frequently in the region of the brain. The floor of the medullary groove here undergoes the process of ON THE DEVELOPMENT OF THE FROG. 291 grey degeneration already referred to. The lips of the blastopore are often similarly affected. The yolk-cells in the interior degenerate and liquefy ; the liquefied mass may burst through the ectoderm and spread over the surface. In spite of this, differentiation of the organs of the body proceeds until the embryo dies. Suckers, gills, tail (often double), pituitary body, optic vesicles, lens, infundibulum, auditory vesicle, neural crest. with the vagus and trigeminus ganglia ; protovertebre, pronephric thickening, and liver diverticulum are all formed. The notochord is formed in the same abnormal way as described under II., and is bent and twisted. (B) Magnesium chloride, magnesium sulphate, and magnesium nitrate, cane sugar and dextrose. The blastopore closes, though slowly ; the medullary folds do not. In the magnesium salts the brain alone remains open ; in the sugars the entire length of the medullary folds. The exposed part in all cases undergoes grey degeneration. All the organs mentioned under (a) are developed, and in addition the pericardium, together with a few endocardial cells. The tail is better developed and the embryos longer. IV. Development is nearly or quite normal ; wrea and sodium sulphate. In the former the blastopore and medullary folds close, though more slowly than usual. The organs already referred to are all formed ; in addition, the heart and pericardium, the pronephros, the splanchnoccel, the dorsal aortz and posterior cardinal and vitelline veins, and the subnotochordal rod. The notochord, though arising in the abnormal fashion observed in other cases, has well-differentiated, vacuolated cells. The myotome cells are elongate and multinucleate. Eventually the embryos die. The cells of the central nervous system and of the ectoderm degenerate. Mesoderm and yolk-cells swell up ; the latter indeed often produce a hernia-like ventral swelling behind the liver, subsequently bursting through the body-wall at this point. In sodiwm sulphate, on the other hand, development appears to be perfectly normal, and'to proceed at the normal rate. The tadpoles will live in the solution for many weeks. As the work is still incomplete it would be premature to offer any explanations or conclusions. At the same time it may be pointed out that the facts seem to contradict Bataillon’s assertion that the distorted development of the sodium chloride monster is solely the effect of the increase in the osmotic pressure. More probably the phenomena are to be attributed to the poisonous properties of the substances employed, even in the case of the sugars, the differences being due to differences in the permeability of the tissues of the embryo. The Committee ask to be reappointed in order that the microscopical investigation may be brought to a satisfactory conclusion. 292 REPORT—1904. The Probability of Ankylostoma becoming a Permanent Inhabitant of our Coal Mines in the event of its introduction.—Interim Report of the Committee, consisting of Dr. G. H. F. NurratL (Chairman), G. P. Broper (Secretary), Dr. A. E. Boycott, Dr. J. 8. HaLpane, and A. E. SHIPLEY. SUMMARY. THERE are many channels by which Ankylostoma might be introduced into British coal-mines. The conditions found underground in these mines are such that the worm would, in many cases, at any rate, probably become firmly established. In view of the expense and difficulty of eradicating the worm from any mine in which it has become established, it is of the greatest importance that preventive measures should be undertaken without delay. Complete eradication does not yet appear to have been ever accomplished. The necessary prevention is best accomplished by the provision of proper sanitary accommodation in the main roads underground and at the pit’s mouth, by regulations to prevent pollution of the pit by human feces, and by the establishment of a limited quarantine system for work- people from infected areas, with compulsory notification of cases to the Home Office. Importance of the Question. The economic importance of Ankylostoma is very great. In many tropical countries it is one of the chief causes of death ; thus in Porto Rico more than one-fifth of all deaths are due to this worm disease. In this country the underground workings of mines afford the necessary tropical conditions of temperature, and in this way provide situations in which the worm is capable of flourishing. In the Westphalian coalfield the disease became prominent about four years ago, and many cases of illness occurred. The number of men who were thus incapacitated from work was observed to be increasing rapidly ; in consequence very exten- sive efforts have been made to stamp out the disease. Hospitals were built, a special staff of doctors provided, all the men were specially examined ; those who were found to be infected were not allowed to work underground, and were all treated in the hospitals until they were free from the worm. It is impossible to state exactly even the direct expense of all these measures, but the figure certainly amounts to several hundred thousand pounds. When it is remembered that 650,000 men are employed underground in the coal-mines of Great Britain, and that it has been found that in a badly infected mine 80 per cent. of the men may have the disease, the gravity of the question is apparent. By the incidence of such an epi- demic both employers and workpeople must be seriously affected, not only in the measure of the number of men seriously ill, but also of the far greater number who have no obvious symptoms, but an impaired efficiency for work. The sanitary arrangements in Westphalia have been carried out very ANKYLOSTOMA (MINERS’ WORM). 293 thoroughly and energetically, but it has not been found possible com- pletely to eradicate the worm. The number of infected men has been greatly reduced, but a small percentage remains who still harbour the worm. This small percentage remains about the same in spite of the con- tinuance of treatment, and is, of course, always capable of introducing the disease into any fresh mine or of reinfecting the mine to any extent if preventive measures were relaxed. Before considering the probability of the spread of Ankylostoma in this country it is necessary to point out that we have hardly any definite information as to its complete absence at the present time. Only one case of the disease has been recorded in a British coal-mine, but the worm may well be present to a limited degree without causing obvious illness. A latent infection of this kind, owing to some small change in the tem- perature or the moisture of a mine, may increase to a serious epidemic at any time, or may be carried to other pits where more favourable conditions may lead to the most disastrous results. No evidence of the presence of the worm has been found in the few collieries which have been systematically examined, but it must not be assumed too readily that it is completely absent. Is there a Probability of Ankylostoma becoming established in British Coal-mines ? (A) Possible Sources of Infection. (1) The worm is endemic among the general population in nearly all tropical and sub-tropical countries (Southern Asia, Africa, South America, West Indies, &c.) and parts of North America, Australia, and in Europe south of the Alps, and in Hungary. (2) It is present among underground workers in the Westphalian coalfield and in the French and Belgian coal-mines. (3) It is present in the Cornish tin-mines, at any rate in the Cam- borne district. The infection may thus be easily introduced into this country from the tropics and Southern Europe by returned miners, or even by those who have not followed any underground employment abroad (soldiers, navvies, &c.); and from Germany, Belgium, France, and the Cornish mines by underground workers. Cases have been recorded in Lanarkshire and in Belfast in the persons of soldiers, and in the former case a man was actually working as a miner when his illness attracted attention. A large number of Poles are employed in the Lanarkshire coalfield, some of whom may have worked in Westphalia or Hungary, and Italians have lately been introduced into a metalliferous mine in the North of England. (B) Conditions found wndergrownd in British Coal-mines which would influence the establishment of the Worm. The conditions of temperature on the surface are such that practically the worm cannot spread among the ordinary population in this country. In summer the eggs may hatch and the larve develop to the infective stage in the open air, but any small danger which might arise from this source is rendered negligible by the almost universal use amongst all classes in this country of arrangements for the proper disposal of excreta. 294. REPORT—190 4. In underground workings, however, the temperature, &e., are fre- quently such that the eggs will quickly hatch and the larve develop ; there are very seldom any ‘sanitary arrangements,’ and the darkness renders it difficult to avoid coming into contact with fecal material. (1) Lemperature.—There is need of much more collected information respecting the actual temperatures found in coal-mines. It would, how- ever, appear that a temperature of 70° F. or more is found in parts of most pits, while temperatures of 80° F’. are not uncommon. The eggs may hatch and the larve reach the encapsuled stage at any temperature from 60° F. to about 95°-100° F. ; the optimum temperature seems to be about 75°-80°. Below 60° the eggs may occasionally hatch, but the larve will not grow to the infective stage. Once the larve have reached the infective stage they seem to be largely indifferent as to temperature : they certainly live longer at room temperature than at 98°, but not longer than at about 70° F. (2) Moistwre.—Some water is to be found about all mines ; even if there is very little standing water in the roads there is enough to produce a muddy condition at places. The worm cannot be propagated in com- plete absence of moisture, and the larve are soon killed by drying ; but parts, at any rate, of most mines are sufficiently wet to allow the larve to grow freely. On the other hand there may be too much water to allow the eggs to hatch. Eggs contained in feces covered with a shallow layer of water will not produce larvee at any temperature. Once hatched, however, the larvee flourish in water. (3) Hilth.—Coal-mines appear to be a good deal cleaner, from a sani- tary point of view, than metalliferous mines. This is in part due to the fact that at the face feces are generally deposited in the goaf! and covered with coal dust ; and in part to the greater prevalence of dust and to the larger area. There is, however, no failure of sufficient fecal contamination. In many instances small partly disused roads are made use of by the men for the purpose of relieving their bowels. This usage is particularly dangerous. Duration of the Infection in Man. Well-authenticated cases of infection, lasting more than six years after the last possible contact with infected materials, have been recorded. Viability of the Worm in Mines. Encapsuled larve have lived in the Gordon Laboratory for twelve months (still alive) at 68° F. There is no direct evidence as to how long they may live underground, but in water obtained from two North Staffordshire mines they suffered no ill effect, and were observed for several weeks. Natural Conditions in Mines which are unfavourable to the Worm. Parts of all, and nearly the whole of some mines, fail to produce the combination of dampness and warmth favourable to the hatching of eggs. ' The ‘goaf’ or ‘gob’ is the worked part of a mine, where the coal has been removed, The supporting timbers are withdrawn, and the roof is allowed to close on to the floor. ANKYLOSTOMA (MINERS’ WORM). 295 But if the eggs cannot hatch in certain parts which are too cool, the larve can be brought to these parts either on the boots, &c., or by the flow of water. There is no evidence to show that any substance in the coal is dele- terious to the worm, though weathered coal might contain such products. Tf the water is salt (as it is at Levant Mine) protection seems to be secured ; but traces of the heavy metals (iron, copper) do not seem to be harmful. Nothing is known of any natural enemies. In some mines the fecal deposits, wood, &c., show an abundant fauna, most commonly dipterous larvee and small nematodes other than Ankylostoma. It might be supposed that in the case of a species in which a single female produces millions (probably many millions) of eggs some specific enemy would have been developed—some organism whose special charac- ters enabled it to live on the highly nutritious contents of the eggs, or on the newly hatched larve. But if such a hostile species has been evolved it is in the tropical and sub-tropical home of Ankylostoma that it should be sought for, not in the temperate zone. In the mud of a British coal-mine the limited number of species of animals and plants are either from the surface above, or have been brought with the timber from uninfected countries. It is possible, therefore, that in a warm and moist coal-mine in Great Britain the conditions are actually more favourable to the uncontested life of the larvee than even in the tropics. It would not be out of harmony with any known facts to suppose that a single pair of worms might give rise in one generation to a progeny equal in number to the population of the British Islands. (C) Preventive Measures. (a) In non-infected mines. 1. A sufficient supply of sanitary pails, combined with a rigid system of inspection and cleaning, is all that is necessary if the use of these con- veniences can be enforced. The habit of defecating underground at all should be discouraged as much as possible : much may be done in this way by providing proper and well-looked-after accommodation at the pit’s mouth. In dry mines the feces can probably be safely disposed of by burying them under coal dust in the goaf; but in all cases permanent roads and stations should be provided with conveniences. 2, Examination of fresh hands. All men applying for work who have ever worked in tropical or South European countries, or in mines where the worm is known to be present, should be rejected till it is shown that they do not harbour the worm. It is useless doing this unless their state of health is entirely disregarded ; it is of no moment whether they are or have been ill or not, since perfectly healthy persons may carry the worm and be capable of infecting a mine. Some sort of quarantine list should be made. At the present it would include Cornwall, Westphalia, the French and Belgian coalfields, South European and all tropical countries. 3. Reduction of temperature and moisture is difficult, in most cases quite impracticable, and not necessary if proper sanitary and quarantine regulations are made and carried out. Any reduction in the moisture is, moreover, not unattended with danger from explosions. There should be no difficulty in introducing a proper system of 296 REPORT—1904. sanitary accommodation if the genuine sympathy of both the mine owners and the men’s representatives could be secured. The additional expense in providing and looking after the pails, &c., would be relatively small, and in the larger pits should be practically inappreciable. In an English colliery employing 2,000 underground hands the excreta from the men on the working roads have for the last four years been disposed of by the use of 100 movable pans, emptied on the spoil-heap once a week and recharged for use with coal dust and a disinfectant fluid. The total cost is found to come to about ll. a week, and it is stated that the fouling of the roads has now ceased. The number of hands which it would be necessary to examine indi- vidually would never be large. There is no need to examine men who live in England and are fresh to mining, or who have worked in a mine which is known to be free from the worm. In most English coalfields these would include the great majority of the men. The method of examination by means of blood-films affords a fairly satisfactory method to which the men have no objection. It seems probable that many medical officers of mines are not competent to undertake the necessary investigations ; there would, however, be no difficulty in making arrange- ments with pathological and public-health laboratories such as have been established in many parts of England. It is only in accordance with the general policy of the country as to public health that the expenses of such examinations should be provided, in part at least, out of public funds. (b) In infected mines. The conditions here are altogether different, and may require the most drastic and expensive measures of universal examination and treat- ment combined with anything that may be practicable in the way of cooling, drying, and disinfecting the mine. The great efforts made on the Continent thoroughly to disinfect infected mines, and their partial success, have been referred to in our opening paragraphs. Particulars will be found in the Blue Books and other recent publications dealing with the subject.! There is no evidence as yet of any natural process which would cause Ankylostoma to disappear from a mine in which it had once found a home. Total desertion of the mine by human beings would presumably have this effect, but it would appear necessary that such desertion should last not less than a year. And from the experience of the Westphalian and other European coaltields it would appear probable that, if Ankylostoma should ever thoroughly take possession of one of the many warm and moist British coal-mines, it will not be eliminated except by the invention of even more efficient disinfection than the drastic and expensive pro- cesses enjoined on the coal-masters by the German Government. ' See, inter alia, Parliamentary Paper [Cd. 1671], 1903 and [Cd. 1843] 1903; special supplement to the Colliery Guardian, November 6, 1903; Boycott and Haldane in the Journal of Hygiene, vol. iii. p. 95; vol. iv. p. 73 ; Boycott, ibid. p. 437. OCCUPATION OF A TABLE AT THE MARINE LABORATORY, PLYMOUTH. 297 Occupation of a Table at the Marine Laboratory, Plymouth.—Report of the Committee, consisting of Mr. W. Garstana (Chairman and Secretary), Professor KE. Ray Lanxester, Mr. A. SepGwicKk, Pro- fessor S. H. Vines, and Professor W. F. R. WELDON. Miss Icerna Sous, of Newnham College, Cambridge, occupied the British Association’s table at the Plymouth Laboratory from Sep- tember 1 to September 29, 1903, during which period she carried out an investigation on the development of spicules in Amphiwra elegans. Mr. W. Woodland, B.Sc., of University College, London, applied for the use of the Association’s table at Plymouth in the spring of the present year. This application could not be granted, owing to the fact that in the absence of the usual grant of money the Committee had no power to nominate to the table for more than one month in the year, the period for which the British Association has the right of nomination as a ‘ Founder’ of the Marine Biological Association. By the kindness of Dr. Allen, Director of the Plymouth Laboratory, Mr. Woodland was, however, accommodated at the Laboratory gratuitously during April, where he carried out a further investigation on the develop- ment of spicules in Echinoderms, more particularly in Lchinus esculentus and Thyone. The Committee ask to be reappointed with a grant of 10/., in order that they may be in a position to appoint competent investigators to work at the Plymouth Laboratory for at least three months in the year. Index Generum et Specierum Animalium.—Report of the Committee, consisting of Dr. H. Woopwarp (Chairman), Dr. F. A. BATHER (Secretary), Dr. P. L. Scuater, Rev. T. R. R. STEBBING, and De. W . EH. Hoye, Tue recording of literature by Mr. C. Davies Sherborn has proceeded regularly, though more slowly. The purchase of rare books has been continued in a most satisfactory manner. These, after serving the recorder’s purpose, are invariably offered first*to the Trustees of the British Museum. If not purchased by them, care is taken that they shall be purchased by some other public library, so as to be available to students for the future. In this way a small fund has been long maintained for acquiring otherwise inaccessible volumes, and the Association grant is left free for the actual work. The enormous number of nomina nuda met with in the literature between 1801-1850 involves a vast amount of labour, uninteresting, but none the less necessary, seeing that one of the chief objects of this index is to enable the student to find any name, whether valid or invalid, of which he is in search. The extent of the undertaking may be inferred from a single example. It appears that Dejean, the coleopterologist, is responsible in his catalogues for no fewer than 22,399 names, every one of which has to be recorded and checked, not only with four editions of his own work, but also with the diagnoses and names of his contemporaries and later authors, 298 ~ REPORT—1904. The Committee have to report with deep regret the death of Mr. Robert McLachlan, a colleague who followed the work with the keenest interest. The Committee desire to be reappointed, with the addition of the name of the Hon. Walter Rothschild, who has kindly consented to serve, and urgently press for a further grant of 100/., so that more rapid progress may be possible. The Zoology of the Sandwich Islands.—Fourteenth Report of the Committee, consisting of Professor NEwTon (Chairman), Mr. Davip SmarP (Secretary), Dr. W.'T. BLanrorp, Professor 8. J. Hickson, Dr. P. L. Scuater, Dr. F. Du Cane Gopman, and Mr. Epagar A. SMITH. Tue Committee was appointed in 1890 and has since been annually reappointed. Since the last report, Vol. III., Pt. 4, of the ‘ Fauna Hawaiiensis’ has been published by the Committee, and also the part dealing with Verte- brata, by Mr. Perkins, mentioned in the last report. The Microlepidoptera have been studied by Lord Walsingham, and it is expected that his report on them will shortly be completed. Some further progress has been made with the examination of the Coleoptera, but the working out of this Order of Insects still remains a difficulty. The Committee asks for reappointment without a grant. Coral Reefs of the Indian Region.—Fifth Report of the Committee, consisting of Mr. A. Sep@wick (Chairman), Mr. J. STanLey GARDINER (Secretary), Professor J. W. Jupp, Mr. J. J. Lister, Mr. Francis Darwin, Dr. S. F. Harmer, and Professors A. Macatister, W. A. HerpMan, and 8. J. Hickson. THE Committee have received the following report from Mr. Stanley Gardiner, who has had charge of the work : — During the year two parts of ‘The Fauna and Geography of the Maldive and Laccadive Archipelagoes’ have been published, viz. Parts II. and IIT. of Vol. II. They contain reports by Mr. Edgar Smith, on the Marine Mollusca; Mr. R. C. Punnett, on the Enteropneusta; Mr. L. A. Borradaile, on various Crustacea; the Rev. T. R. R. Stebbing on the Isopoda ; Mr. E. T. Browne, on the Hydromeduse ; Mr. Forster-Cooper, on the Antipatharia; Mr. R I. Pocock, on the Arachnida; and by Mr. Stanley Gardiner, on the Variation of the Madreporaria and the Astraeide. Part IV., completing Vol. IT., is in hand, and will contain among others, papers by Professor 8. J. Hickson, on the Gorgonians and Pennatulids ; “Professor Coutiére (of Paris), on the Alphaeidz (about seventy species) ; Surgeon-Major Alcock, on the Paguride ; Mr. L. A. Borradaile, on the Hydroids ; Mr. A. O. Walker, on the Amphipoda; Mr, A. E. Shipley, ON CORAL REEFS OF THE INDIAN REGION. 299 on the Parasites ; and Mr. J. Stanley Gardiner, on the remainder of the Madreporaria. Papers are also expected from Dr. Hoyle, on the Cephalopoda ; Dr. Norris Wolfenden, on the Copepoda ; Mr. Forster-Cooper, on the Ptero- poda ; Professor Topsent (of Rennes), on the Sponges, ce. It is proposed to summarise the zoological results in respect to the distribution of marine animals in a Supplementary Part, to be issued in 1906, when the accounts of certain other groups will have been published. This will be sent gratis to subscribers. The seven parts of the Fauna and Geography already published form a sufficient guarantee that the work will be properly completed, and the Committee consider that they may now be dissolved, Madreporaria of the Bermuda Islands.—Report of the Committee, consisting of Professor S. J. Hickson (Chairman), Dr. W. E. Hoye (Secretary), Dr. F. F. Buackman, Mr. J. S. Garprvner, Professor W. A. HerpMan, Mr. A. C. Sewarp, Professor C. S. SHERRINGTON, and Mr. A. G. TAaNSLEY, appointed to conduct an investigation into the Madreporaria of the Bermuda Islands. Tue Committee report that they have been in communication with the authorities of the Bermuda Biological Station for Research, and have been in readiness to co-operate should an opportunity have arisen. They regret, however, that such has not been the case, as no naturalist from this country has applied for facilities to work in the Bermudas. Dr. J. E. Duerden, who hoped to have been able to undertake this work, found himself unable to do so. The Committee suggest that they should be reappointed, but do not ask for a grant. Colour-phystology of the Higher Crustacea.—First Report of the Committee, consisting of Professor 8. J. Hickson (Chairman), Dr. F. W. Gamsie (Secretary), Dr. W. E. Hoyie, and Mr. F. W. KEEBLE, appointed to enable Dr. F. W. Gamble and Mr. Keeble to conduct Researches in the Colour-physiology of the Higher Crustacea. Durine the present summer Messrs. Gamble and Keeble have completed a further spell of work on the colour-physiology of the higher crustacea. By the aid of the grant allotted to this research, apparatus has been bought for the experimental investigation of the chromatophores and their contained pigments and fats in Hippolyte varians ; but as the most suit- able apparatus has only lately been found after a series of trials, the present Report is of an interim and not of a final nature. But although the work is still proceeding, Dr. Gamble reports as follows on the results obtained up to the present time. The apparatus has been set up in Mr. Keeble’s laboratory at Trégastel, Cétes-du-Nord, France, with a view of determining (i) the influence of light and darkness on the development of the pigments of Hippolyte ; (ii) the comparative suscep- tibility of Hippolyte at different periods of life ; (iii) the origin and 300 REPORT—1904. significance of the chromatophoric fat discovered and described by Messrs. Keeble and Gamble. The results of this year’s investigations, incomplete as they are, show (i) that starting with the almost colourless (z.e., adolescent) stage with which Hippolyte begins its colour-history, continued darkness induces the formation of red pigment even in the absence of food ; a conclusion that has bearings of considerable interest in relation to deep-sea and Arctic crustacea, (ii) Further, the colourless stage is one of great susceptibility. By appropriate coloured screens, a green or brown tint is rapidly induced ; whereas, in adults, the pigmentary system gives way far less readily. This susceptibility explains to a large extent the way in which Hippolyte grows into its surroundings. (iii) Finally, the origin and fate of the chromatophoric fat has been tested by a couple of experiments. The results are not yet completely worked out, and Mr. Keeble is at present engaged upon a further attempt to solve this difficult problem. But the results show that in such colour- varieties of Hippolyte as green, brown, and pink, there is under natural conditions a production of colourless fat in the chromatophores ; and that when food is withheld this chromatophoric fat is drawn upon. Occupation of a Table at the Zoological Station at Naples.—Report of the Committee, consisting of Professor 8. J. Hickson (Chairman), Mr. J. EH. S. Moore (Secretary), Dr. E. Ray LAnKeEsteEr, Professor W. F. R. Wetpon, Professor G. B. Howes, Mr. A. SEpGwick, and Professor W. C. McIntosH. Tue Committee report that during the session Mr. Goodrich occupied the table for a period of one month, and investigated the anatomy of the Chlorhemid and the excretory organs of Enteropneusta, and that Miss Vickers occupied the table for two months and carried on some investiga- tions on Alge. The Committee ask for reappointment, with a grant of 1000. Report on the Occupation of the Table, by E. 8. Goopricu. I have to thank the Committee of the British Association for the use of the table at the Naples Zoological Station during one month last Christmas 1903-04. During this short stay most of the time was spent in a search for true nephridia in Balanoglossus. The search, however, was unsuccessful, and so far no definite excretory organs have been found in the Enteropneusta. The rest of my time was occupied in the study of the anatomy of the Chlorhemid, a group of Polychete worms which is very incompletely known. I succeeded in obtaining a considerable amount of valuable material, and hope shortly to publish some account of my researches. British Association, 74th Report, Cambridge, 1904.] [Puate VII. Fie. 2.—Roll Waves spontaneously formed in the Conduit of the Griinnbach. Illustrating the Report on Terrestrial Surface Waves. ON TERRESTRIAL SURFACE WAVES AND WAVE-LIKE SURFACES. 301 Terrestrial Surface Waves and Wave-like Surfauces.—Fourth Report of the Committee, consisting of Dr. J. Scorr Kent (Chairman), Dr. VauGHAN CornisH (Secretary), Lieut.-Col. F. BatLey, Mr. JOHN MILNE, and Mr. W. H. WHEELER. (Drawn up by the Secretary.) [PLATE VII.] Tue Committee record with deep regret the death of Mr. E. A. Floyer, M.R.A.S., Mem. Inst. Egypt, a Member of this Committee, who was especially interested in the study of desert sand-dunes. A list of his principal writings upon this and other subjects, compiled by Dr. Cornish, has appeared in the ‘Journal of the Royal Asiatic Society,’ May 1904.! In the last report some account was given of observations upon the Bore of the river Severn, and of the waves in the Whirlpool Rapids of Niagara River. Further observations upon waves in rivers and upon kindred phenomena in waterfalls were commenced in May last in Switzerland, as well as observations upon Steps and Ledges produced by the Movement of Soil upon a Slope. The work is still in progress, but a preliminary account may here be given of one kind of wave of special interest now being kept under observation in the Guntenbach and Griinnbach streams, which flow in the latter part of their course in open paved conduits into the Thunersee. Each terminates in a_ waterfall which is not steady, nor merely flickering, but is affected by a regular cadence having a period of several seconds. In the case of the Griinnbach the phenomenon is easily visible at the distance of a mile with the naked eye. The amount of water at maximum is fully one-third greater than at minimum. This cadence is due to the arrival of waves resembling a bore, but travelling down channel more rapidly than the current flows. These it is proposed to call Roll Waves, from a name which a correspon- dent gives to a wave of similar form which sometimes occurs in the river Tees. Itis the form, as far as can be judged by written and verbal accounts unaccompanied by photographs, in which sudden floods some- times travel down a river, as in the recent destructive flood at Nikko, Japan. The remarkable thing about these waves in the Guntenbach and Griinnbach, however, is their periodicity, and the fact that they are spontaneously evolved without the co-operation of any special quickening, or checking, or sudden swelling of the current. They appear to depend mostly upon the shallowness of the stream (and therefore require a fairly smooth bottom), in conjunction probably with considerable swiftness. The ordinary quick throbbing of the current (to which the present writer has often referred) gives rise in these very shallow streams to ‘long waves’ whose amplitude is an appreciable fraction of the depth of the stream. The greater of these, therefore, move more rapidly than those of lesser amplitude, and can actually be seen to catch them up. They do not, however, pass them by, but, on the contrary, incorporate them; and thus the original small, rapid, irregular throb of the stream is changed, as the stream flows on, into a slow and nearly regular cadence. The period becomes longer and more regular in the lower reaches of the conduits, as can best be observed in the Griinnbach, of which the conduit is longer and * Dr, Cernish’s completed paper ‘On the Dimensions of Deep-sea Waves and their Relation to Meteorological and Geographical Conditions’ has appeared in the Geographical Journal for May 1904. 302 REPORT—1904. more smoothly paved, with nearly vertical sides. The whole process is a beautiful example of the evolution of large waves of regular period from small, irregular disturbances, and its observation, under the simplified condition of a straight conduit, is likely to assist in the more difficult task of observing waves in natural rivers where the phenomena are more irregular. The photography of wave phenomena has been continued and ex- tended in this as in former years. A selection of enlargements has been sent, by request, as part of the British Photography Exhibit, to the St. Louis Exhibition. The Committee ask for reappointment. On the Accuracy and Comparability of British and Foreign Statistics of International Trade.—Report of the Convmittee, consisting of Dr. E. Cannan (Chairman), Dr. B. GinsBurG (Secretary), Mr. A. L. Bow ey, Professor 8. J. CHAPMAN, Sir R. Girren, and Mr. R. H. INGLIS PALGRAVE. Tur Committee have added Mr. A. J. Sargent to their number. Mr. Pal- grave has unfortunately been unable to take part in their proceedings. The Committee have made such inquiries as proved possible at the Board of Trade, and of persons actually engaged in commerce, and have examined and tabulated the information contained in the official statements of trade of various countries. The main sources of their information are given below. The Committee decided to restrict their inquiries for the present year to the following countries: United Kingdom, United States, Germany, France, Belgium, Holland, Russia, and Austria. They also decided to consider mainly questions of value rather than of quantity. They divide their report under the following ten headings :— A. Definition of international trade. B. Methods of estimating value. C. Registration of origin and destination. D. Changes in A, B, and C in recent years. E. The discrepancies between statistics published by different countries. F. Relation of total of exports to the produce of a country. G. Relation of the statistics of imports and exports to the balance of trade. H. Accuracy of the figures of the United Kingdom. J. Conclusion and suggestions. K. Bibliography. A. Definition of International Trade. At first sight it seems a simple matter to define foreign or inter- national trade. To the ordinary apprehension it would appear that a complete account of international trade would give, in the first place, particulars of the quantity and value of every kind of goods crossing international frontiers in each direction. There is little difficulty in imagining an ideal world in which it would be quite easy to collect and publish such statistics, but in the actual world things are not nearly so ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 303 simple. Even the position of the national frontier is not always what we should expect ; for example, trade between France and Corsica, and between the United States and Hawaii or Porto Rico, is domestic trade ; though trade between France and Algeria, and between the United States and the Philippines, is international trade. This is a simple matter compared with the complication introduced by the existence of free zones, like the free port of Hamburg in Germany, and that of Copenhagen in Denmark. Yet the position of the customs frontier is among the least of our difficulties. We can easily imagine a world in which international trade, or goods carried across a national frontier, fell into four distinct classes, as follows :— Imports. Class 1.—Goods imported which will be used or consumed at home. Class 2.—Materials and components imported in order to be made up in the country and then exported. Class 3.—Goods imported which will be sold for export without change of form. Class 4.—Gvoods simply passing into the country on their way to another Exports. Goods produced at home and ex- ported. Manufactured articles made up of foreign materials and exported. Goods of foreign origin exported after purchase and sale within the country. The same goods passing out of the country. country without changing ownership within it. The first is sometimes called ‘ special trade,’ the second ‘improvement trade’ (Veredelungsverkehr), the third may be called entrepdt trade, and the fourth ‘transit and transhipment trade.’ The sum of the four may be called ‘ general trade,’ or this title may be confined to the sum of the first three. In the real world, however, these four classes are not sharply divided by distinct and easily ascertainable lines of demarcation. It is often impossible for anyone to say for certain when an article is imported, whether it belongs to the first, second, or third class. When an article is exported the exporter has frequently no exact knowledge as to its origin, and when it is made up of various components or ingredients, part of domestic origin and part of foreign origin, it becomes impossible to classify it under the first or second head without adopting some arbitrary standard as to the degree in which a commodity must contain foreign ingredients before it can be classified as of foreign origin. Again, the distinction between the third and fourth class is a slight one, not always easy to verify. Finally, the fourth class is not very distinctly divided from goods carried in ships past the country instead of into the country and out of it. No one would propose to reckon in the transit trade all the goods in ships which have simply passed through the territorial waters of a country, nor even those in ships which have called at a port to coal; but as to what exact amount of detention and manipulation in port is required to constitute arrival and departure of goods, considerable difference of opinion may legitimately prevail. As the benefit derived from international division of Jabour or localisation of industry is frequently very small, it is often the case that transactions in Class 4 are just as advantageous to a country as trans- actions in Class 1, but popular opinion tends to regard the ‘ special trade’ as more important than the ‘improvement trade,’ the improvement trade as 304 REPORT—1904. more important than the entrepdt trade, and the entrepédt trade as more important than the transit trade. Consequently, most countries have been in the habit of devoting more attention to the earlier classes than to the later, and the result has been that the statistics of the later classes are not sufficiently complete to allow of useful comparison between the totals for all four classes. The unfortunate result of this is that we cannot keep clear of questions of classification in the comparison of statistics of international trade. We have to compare totals which confessedly do not include all imports (all things carried in) and all exports (all things carried out), but only a portion of them, and the different countries do not agree as to what portion should be included. It is becoming the practice to call the portion of foreign trade of which the more detailed statistics are kept, the ‘special trade,’ and the whole or any larger portion of foreign trade of which any statistics of totals (quantity or value or both), the ‘ general trade,’ but the distinction is not always applicable, and is sometimes confusing. In the United Kingdom the largest total for imports includes every- thing except gold and silver and goods for transhipment,' the largest total for exports (‘British and Foreign and Colonial produce’) includes everything except gold and silver and goods transhipped.' The tran- shipment trade and imports and exports of bullion are given sepa- rately. The grand total of exports just described is divided into totals for ‘British produce’ and for ‘Foreign and Colonial produce,’ the information as to the division being obtained from the exporters—British produce meaning, apparently, not only everything grown, but also every- thing manufactured in the United Kingdom, whether composed in part or wholly of foreign materials or not. The grand total of imports is divided, so far as quantities are concerned, into totals ‘retained for home consumption’ and re-exports. Thus, if the smaller totals be taken as ‘special’ and the larger as ‘ general’ trade, it may be said that the United Kingdom special trade includes our ideal Classes 1 and 2, and the general trade Classes 1, 2, and 3. 5 The United States arrangement is the same in theory, but instead of the home consumption being ascertained by deducting quantities re- exported as declared by the exporters from the total imported, it is taken simply as the quantity and value ‘entered for consumption’ at the customs warehouse or barrier. The Committee are inquiring as to the exact treatment of re-exports. ri France includes in the ‘general trade’ everything coming in or goin out, except gold and silver, so that her grand totals include all four of Boe ideal classes. In ‘special trade’ she includes only Class 1, and such part of Class 2 as has paid duty ; but sugar is treated exceptionally, all imports and exports being included. Soke P The German ‘special trade’ totals include Classes 1 and 2, and such part of 3 and 4 as are not liable to duty and have not been dealared for re-export ; ‘general trade’ totals include in addition foreign goods re- exported after they have been in the customs warehouse. Trade with the small districts (in Hamburg, &c.) which are free of duties is regarded as foreign trade. Duty-free material for shipbuilding is not included in an of the returns, nor goods sent abroad to undergo a manufacturing ese ! A small quantity of these goods passes from port to port under customs control ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 3805 and be returned. Many changes have been made in these definitions (see Section D below). Belgium follows France as a general trade ; her special trade includes Classes 1, 2, and 3. Holland also follows France as to general trade, but compiles no returns of value for it. As to special trade, the Dutch returns include Classes 1, 2, 3, and, it is said, much of 4. Russia includes Classes 1, 2, and 3 in special trade. Austria includes Classes 1 and 3. Neither Russia nor Austria compiles totals of general trade. Attention may be specially called to the general absence of adequate distinction between home and foreign produce in exports. In the case of duty-free goods, the foreign produce is in general included in special exports, a category generally supposed to include home produce only ; if dutiable goods have paid duty and are then re-exported, they are also included as home produce. Thus France includes 44,000,000 francs’ worth of cotton in her special exports. The lines of division are deter- mined rather by fiscal circumstances than by economic principles. Table showing roughly what classes of goods (see above, p. 303) are included in the Return of Special Trade of various countries, 2 : Imports: Classes 1, 2, and 3. erated Kinedom { eer : Classes 1 and 2. OSA. . c . Classes 1, 2, and 3 (if duty free). France . x . Class 1, and Classes 2, 3, and 4 if duty has been paid, or if they are not distinguished by importers from Class ], and all sugar in Class 2. Germany : . Classes 1, 2,and most of those parts of Classes 3 and 4 which are duty free. Belgium : . Classes 1, 2, 3. Holland. d . Classes 1, 2,3, and a large part of 4 not adequately dis- tinguished. Russia . "i . Classes 1, 2, and 3. Austria . ; . Classes 1 and 3. B. Methods of Estimating Value. The typical method of valuing imports and exports is as follows. A permanent commission estimates the prices of all the main articles of trade year by year, and values all exports and imports by the price-list thus established. The list at the end of one year is used for the monthly returns of the following, but the annual returns are adjusted for the change of prices in the year in question averaged through the year. The goods are valued as at the moment of crossing the frontier. The main exception is the United States, which values imports at their price at the port of shipment in the country of origin. Thus, Bradford goods exported to the United States are entered in their accounts at their value at Liverpool. France and Belgium began to estimate values on the typical method in 1847, Austria in 1877, Germany in 1879. In Germany an allowance is made for tare, the value entered being that of the goods without their packings. In Belgium some goods are entered by the shippers by their values alone, no quantity, tale, or measurement being given ; in these cases the values declared hy the importer or exporter are accepted after scrutiny. 1904. x 306 REPORT—1904. Holland enters values as declared by shippers for dutiable goods, but the official values on which the rest of her trade statistics are based come from a fixed list many years out of date,! and her trade statistics have not the connotation as those of other nations for this reason. In Russia the values of goods are declared and compared with trade price-lists under expert advice. The United Kingdom takes declared values, but in many cases the figures are adjusted as described below. The adjustment of values to values at crossing the land frontier must be arbitrary, and there may be uncertainty at what point goods coming by sea are valued. It is quite uncertain how goods not on the official list, or not capable of brief description, would be valued in Germany, France, &c. ; presumably some form of declared value must be used.? In the United States imports are entered at the vaiue ready for shipment declared to the American Consul at the place of exportation. The values entered are those given on the invoices before inspection or appraisement for customs purposes. Exports of home produce, &c., are entered at the market value at the time and place of shipment, re-exports at their import value. It should be noticed that official values of exports have no necessarily close connection with the values actually realised abroad and remitted for separate consignments. They assume too great a uniformity in value. Also, there must be great error in pricing goods according to their description in all those cases where the goods are not seen and examined. Thus, the values affixed according to the official list to goods which do not pay duty, seem in most cases to be liable to considerable error. C. Registration of Origin and Destination. The classification of imports and exports according to origin is in a state of hopeless confusion. It is sometimes held that goods should be credited to the country where they are paid for ; thus, eggs from Austria sent to England on an order made to Austria should be credited to Austria, and not to Germany, Holland, or Belgium, through which they pass, while Swiss wines ordered of a Paris wine merchant should be credited to Paris. The place for payment is in very many branches of trade not the country of origin, and this plan, if carried out, would show the balance of trade but not its channels. The country of origin is not easily definable. A cargo of rails ordered by an English merchant to be shipped at Antwerp and delivered in Yokohama, may be duly credited either to Belgium or England, according to definition ; but if raw cotton is shipped from U.S.A, 1 The list in use is still in the main that framed in 1868, which was based on a still older list. 2 The following semi-official communication throws interesting light on this point: ‘In general there is no special difficulty in fitting unusual imports into one or other of the headings specially provided in the accounts. When, in course of time, the article becomes important, a new heading is reserved for it. ‘hus motor- cycles were formerly grouped as “ other cycles” in the French accounts, and turbines as “ machines and parts thereof of wrought iron or other common metal” in the German accounts. These articles now have separate values allotted to them. As regards pictures, the French accounts provide that objets de collection shall be valued at their declared value, and pictures are apparently classed under this head. On the other hand, in the German accounts, all pictures are entered by weight and valued accordingly, viz. at 20 marks per kilogram in 1901 and 25 marks per kilogram in 1902 and 1903.’ he ae ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 307 to England, spun in Lancashire, woven in Germany, and exported through Austria to Turkey, which is the country of origin? Jt is quite impossible to draw the line, even in theory, between simple transhipment and com- plete manufacture, and we are driven by necessity aud convenience to tabulate goods according to the place at which they are paid for, thus increasing out of reason the trade statistics of entrepét countries. Most of the countries dealt with make an effort to enter goods accord- ing to the place from which they are shipped on a through bill of lading, or to which they go by a direct (rail and steamship) trade route. Thus, Swiss goods exported through Germany to Liverpool would be given in the Swiss statistics as exported to England, though their ultimate destination might be the United States. Imports are credited, so far as known, to the country from which they started on a through journey, but very frequently, when transported by sea, simply to the port at which they were shipped. The papers available for customs inspection very frequently do not show whence the goods came or where they were ordered, but only the place from which they made a through journey ; and the actual purchaser may very likely not know the real source. In some countries no attempt is made to get over these difficulties, and goods are credited simply to the country whose frontier they first cross or over which they came, whether by sea or land ; no country succeeds in getting any homogeneous or exact returns by any other method. In the United States the statistics profess to relate simply to the country whence the goods are imported or to which they are exported, and it is not clear whether the country of origin or ultimate destination is meant or not. France has endeavoured to get the real destination or origin since 1870.' The result is that goods by rail are credited to the place of con- signment, goods by road or canal to the adjacent country, and goods by sea to the port of shipment or of lading, unless it is known that at these ports the goods were only transhipped ; except in the case of known through lines of trade, when the goods are credited to their destination or origin as far as is known. Much trade between U.S.A. and France is probably counted in her returns as with England. In Germany an attempt is made to get the real destination or origin. This is considered to be the place to or from which the goods travel in unbroken transit, or with immediate transhipment. In Belgium an attempt is made to get the real origin and ultimate destination, but with very imperfect results, the overland trade being frequently credited to the wrong country. In Holland no attempt is made in the case of goods leaving or entering the country by land, to get the real origin or destination ; but goods, whether by rail, road, river, or canal, are simply credited to the adjoining country. Goods by sea are credited to the port for which the vessel cleared, or from which she last cleared. In Austria, since 1890, the intention has been to credit goods to the country of origin or destination, but how far this intention has been carried out is not known. In Russia goods are credited to the country whose frontier they first pass or over which they arrive. In the United Kingdom the place from which imported goods have been shipped and the real destination of exports are aimed at, with results discussed below. 1 See Zableau Décennal du Commerce de la France, 1887-1896, p. xvii. x2 808 REPORT—1904. D. Changes in A, B, and C in recent years. United Kingdom.—Value of ships and boats (new), with their machinery, has been included among the value of exports of home pro- duce in 1899 and subsequent years. Changes were made in systems of valuation and tabulation in 1854 and 1870. United States.—Since 1898 the statistics given in the British Statis- tical Abstract for Foreign Countries are sometimes for the year ending June 30 and sometimes for the calendar year.' Great care must be exercised to know which is quoted in particular lists. Porto Rico and Hawaii have been regarded as part of U.S.A. in trade statistics since July 1, 1900. The Philippines are still treated as foreign. From 1866 to 1883 the values of imports included their whole cost up to their arrival in U.S.A., together with a commission of at least 24 per cent. From July 1, 1883, the values were taken as those at the place of manufacture before being packed ; since August 1, 1890, the value has been taken of the goods packed and delivered at the port ready for ship- ment, but no sea freight is included. France.—There have been no changes of importance since 1847, except that the registration of goods, according to origin and destination, has been improving since 1870. Before 1895, provisions taken on board ships for use in the voyage were regarded as exports to the countries for which the ships were bound ; they are now entered separately as ‘ Provisions de bord.’ Austria.—In 1885 goods were credited to the adjacent country, over whose frontier they passed ; in 1895 the real origin and destination were entered. The date of the change appears to have been 1890, when the trade returns were reformed. Belgium.—tThe value of rough diamonds imported, and cut diamonds exported, has been included only since 1897. Revised instructions as to registration of origin and destination were issued in 1882 and 1897, but these made no change in principle. The Committee know of no changes in the methods of dealing with trade statistics of Holland or Russia. Germany.—Changes have been so frequent and so complicated, that it is a matter of the greatest difficulty to compare year with year. In 1879 the whole system of the trade statistics was transformed, and comparisons hetween years before and after that date are practically impossible.” Before 1884 ‘a large class of imports and exports were specifically excluded, namely, all articles imported free of duty for working up and for exportation in a more finished condition (improvement trade).’3 For some time after 1884 separate totals were given for ‘special trade,’ including and excluding improvement trade, while the ‘ general trade’ totals included it. Since 1897 only the inclusive total has been published. Great care must therefore be exercised before using these totals in deciding how this trade is treated.4 1 Compare the 28th and 29th numbers. 2? See ‘Waarenverkehr des Deutschen Zollgebiets mit dem Auslande im Jahre 1880,’ I. Theil,.and the translation in C. 8211, p. 70. , 3 Quoted from C. 5597, which contains a translation of the regulations for col- lecting and tabulating German statistics (with definitions of special trade, &c.), which have been for the most part in force from 1880 till the present date. * See Cd. 1199, p. 10 note, and No. 131 of 1904, p. 3 and p. 8 note, for the corrections necessary since 1897. ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 309) From 1897 the values of ships exported or imported have been included in special and general trades. Changes of tariff have frequently affected the inclusion of commodities under one or other of the totals, as can be seen by examining the defini- tions given in A above ; there seems no possibility of estimating their effect. Considerable changes took effect in 1889, when parts of Hamburg, Bremen, and other less important districts, hitherto treated as foreign, were included in the Zollgebiet. At the same time transit trade was excluded from general imports and exports. General.—Comparisons year with year in the statistics of most of the countries discussed are liable to be vitiated (1) by changes in fiscal laws by which goods are transferred from the free to the dutiable list, and therefore (see remarks under A) from general to special trade in the enumerations ; (2) by the continual alteration in trade routes, by which goods may appear in the statistics of, say, France instead of Germany, without any change in their origin or destination, and for reasons already explained affect the ‘special’ as well as the ‘general’ trades of these countries ;' (3) by the varying success with which goods are credited to their countries of origin and of destination. While it is very unfortunate that such confusion exists, it is clear that few of the difficulties so far discussed are due to inaccuracy in the actual returns. In most countries the statistics are compiled primarily in that way which is most useful for their fiscal purposes, and secondarily in such a way as to give information to their own people. No two countries are in quite similar commericial situations, or have identical fiscal policies, and the non-comparability of statistics naturally results. The most per- fectly accurate statistics readily lead to inaccurate deductions, when their origin, nature, and limitations are not thoroughly understood. NOTE TO SECTION D. The following statistics indicate the relative importance to be attached to the changes described :— United Kingdom. 1=£1,000,000. | —— | 1899 | 1900 | 1901 | 1902 1903 | | | Value of Ships Exported Saal la Wont Cis Ih te Sel 59 4:3 Value of Total Exports, home pro- | duce (including above) . P 264°5 291°2 | 280'0 | 283-4 290°9 United States. 1= $1,000,000. = 1899 1900 — 1899 | 1900 Value of Exports to Value of Imports from Porto Rico . 2°6 43 Porto Rico . 3:2 31 Hawaii : 9:0 13-1 Hawaii n 178 20°77 Value of Total Ex- Value of Total Im- ports ee ports (including above) . 1203:9 13708 above) . . ‘ 6971 8149-9 For examples of this sort see the Report on Tariff Wars (Cd. 1938). 310 REPORT—1904. Belgium. 1 =1,000,000 francs. — 1897 1898 1899 1900 1901 Value of Exports of Cut Diamonds 58 67 67 43 44 Value of Total Exports (including above) One 3 ms . 1,626 1,787 1,949 1,923 1,828 Value of Imports of Rough Dia- monds : 55 60 60 40 42 Value of Total Imports (inclnding above) . . . . 1,873 2,045 2,260 2,216 2,221 { Germany. 1=1,000,000 marks, . Imports : Special Trade Exports : Special Trade Year From Hanse For P To Hanse After : Towns Improvement Residue Towns Improvement Residue 1881 572 _ 2,391 630 _ 2,347 1882 552 _ 2,577 685 _ 2,505 1883 556 _ 2,708 725 _ 2,547 1884 557 62 2,704 770 82 2,434 1885 502 | 57 2,442 | 693 78 2,167 1886 493 | 57 2,395 | 756 79 2,229 1887 537 61 | 2,588 | 826 89 2,309 1888 518 | 59 2,773 791 91 2,415 1899 50 96 3,965 105 135 3,062 1890 17 96 | 4,145 105 132 3,223 Excluding improve- Including improve- || Excluding improve- Including improve- ment trade and ships | ment trade and ships || ment trade and ships | ment trade and ships | 1895 4,121 — 3,318 — 1896 4,307 = 3,525 = 1897 4,524 4,681 3,500 3,635 1898 4,958 5,081 3,619 3,757 1899 5,345 5,483 4,069 4,207 1900 5,637 5,766 4,448 4,611 1901 5,309 5,421 4,309 4,431 1902 5,514 5,631 4,559 4,678 E. The Discrepancies between Statistics published by Different Countries. Many attempts have been made to reconcile the statistics of different countries, but invariably without success. For examples see the official publications, ‘Trade between the United Kingdom and France,’ 1881, ‘Trade of the United Kingdom with Germany,’ 1904, and ‘ Reports on Tariff Wars between certain European States,’ 1904 ; see also Sir Robert Giffen’s paper on the ‘Use of Import and Export Statistics,’ 1882, and Mr. Ellinger’s papers in the ‘Economic Review,’ 1902, and at the Man- chester Statistical Society, 1904 (see Section J below). In no case that the Committee know of do the values registered by country X of goods imported from country Y correspond at all closely with the values registered by Y as exported to X. As just explained, it is not in general necessary to assume inaccuracy ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 311 in the returns to account for this, for the differences in methods of tabula- tion necessarily cause very great discrepancies. Take the case of England and Belgium. We valued our exports of home produce exported to Belgium at 11,000,000/. sterling, and of foreign produce at 4,000,000/. in 1900. Belgium valued what she received at 300,000,000 francs, say 12,000,000/., in her special trade. Of the goods we send to Belgium, a great part would no doubt pass on to other countries, and in spite of regulations much of this would be entered as going to Belgium only. Indeed, the English exporter might not know its destination beyond an agent at Antwerp. On the other hand, the Belgian importer would credit part of the 4,000,000/. which we described as foreign produce to the United Kingdom, and only part to the real country of origin. Such illustrations might be multiplied indefinitely. The reader is referred to the papers just named for analyses of special cases. In addition to questions of destination, the method of valuation causes differences, especially where official values linger behind market values. Again, goods leaving X for Y may not be delivered in Y in the same year, or they may remain in the customs warehouse of Y for many months ; exact correspondence year by year is therefore not to be ex- pected. It follows that we do not know the value of our export trade, even if we assume the statements to be made correctly, to any of those countries where transit trade is of importance, and even when we group them together, there is much uncertainty ;! nor can we use the statistics of foreign countries to check our own. Similar remarks apply to imports. Further, we cannot estimate the total international trade of the world, or of the main groups of countries, for neither the general trade nor the special trade is defined in the same way in different countries, and the totals cannot therefore correctly be added. In the previous paragraphs it is assumed that the returns of quantities and values are correctly made. Below, we show reason to think that this is not invariably the case in the United Kingdom. We have no means of investigating the accuracy of the statistics of foreign countries in general ; but the process of valuation seems very faulty where official values are employed, and declared values are subject to bias, especially as they are found for the most part in the case of dutiable goods. The following comparison of the returns of trade between Europe and the United States shows how far we can obtain agreement in a case where, if the returns were accurate as to value and destination, there should apparently be close correspondence. ‘This instance is taken because the basis of valuation is very nearly the same in the exporting and importing countries, for freight is not included in either. We put all Europe, so far as figures are available, together in order, to avoid confusion of origin. The visible sources of error are the inclu- sion of Italian exports to Canada, which cannot be separated, and possibly of some Asiatic produce going from Russian Asiatic ports ; some goods registered in Europe as going to the United States may be there treated as in transit for Canada or elsewhere ; while some European trade to Canada may find its way into the United States ; and in the table is included 666,000,000 (for the ten years) value of foreign goods re- exported by us, counted in our trade, and in many cases in continental ‘ On this point see the warnings pretixed to the Board of Trade Accounts of Loreiyn Urade, and alluded to in Ca, 1761, pp. vi, 3, and 4. a l2 REPORT—1904. trade also. It will be observed that neither the amounts nor the dates of change correspond at all closely ; that, in fact, we should not know from inspection of the figures that they related nominally to the same phenomena ; and that we can only obtain an agreement even within 5 per cent. when we take the totals for ten years, giving the various errors the best chance of neutralising one another. Import Trade of U.S.A. from certain European Countries (i) as Registered by the Exporting Countries, and (ii) as estimated in U.S.A, Statistics. 1=$1,000,000. a = Year ia ites |1890 ‘1891 1892 j1398 ‘1894 11895 1896 11897 1898 ‘1899 1900| 10 years 5 | | | | i ins ~— are * ‘copesigee acre 448 | 387 394/355 | 307 | 426 | 355 | 386 | 329 | 395 | =: |Acselee Gi). —.. | 448 | 447| 390 | 456| 293 381 | 416 | 427 | 303 | 399 | 447 | f 2/8? Adjusted | 447 409 434 B48 352) 404/424 344 367 431 | _- | 3'960 | ' | ] i} The U.S.A. accounts are made up to June 30 each year. The third line in above table is obtained thus : For 1893, dof 45644 of 293=348, assuming that about two months elapse between the valuing of the goods in Europe and their entry in the U.S.A. records. The trade between the United Kingdom and U.S.A. is shown in the following table :— 1= $1,000,000. Year . : . » |1890 si No pea 1893 | 1894 1895 | l Bees 7 ‘ | 11896 1897 11898 1899 10 years | | i U.K, Accounts. | Exports from U.K.— Foreign produce ./| 68| 65 72 f Home produce - | 154] 182) 127,115} 90 U.S.A. Accounts. Imports received of | | | produce of U.K, adjusted for dates. | 192 169/174 133 | 142 | [ee ee TG | 79| 54| 71| G5) 79) 666 | 95/101] 71| 88| 1,103 | } | | 167 | 169 | 129 130 149 1,554 F, Relation of Total of Exports to the Produce of a Country. The relation of the total special exports of a country to the value of the produce of home capital and labour contained in those exports is very complex. There is no evident & priorz connection between the two ; the value of exports may go up because imported raw material or partly manufactured goods have risen in value, while the home contribution has gone down or vice versd. In the comparatively rare cases of commodities, where the whole value is due to home labour or capital, the connection i3 closer ; but even here we should often have to pay regard to the cost of imports used in the implements of manufacture, such as imported machines, coal, &e. There are in general no official published data which make it possible to 1 Austria, Greece, Italy, Spain, Portugal, Switzerland, France, United Kingdom, Belgium, Holland, Germany, Norway, Sweden, and Russia (European and Asiatic ports). In exports from Italy are included those to Canada. Exports of foreign produce of the United Kingdom are included as exports from England. ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 318 subtract the values of imported goods contained in exports, and it would be necessary to obtain separate estimates from those conversant with each important trade before we could deal with exports as relating to the produce of home industry (on this point see Memorandum 23 in Cd. 1761). We know of no similar estimate for other countries. The Belgian, German, and French treatment of their ‘improvement trade’ add greatly to the difficulties in those countries. While it is illogical to use the total values of exports to measure the real progress of production or manufacture for export before we have an estimate such as described, it is permissible to use the values of particular commodities for such a purpose, in some cases where we have sufficient means of allowing for the possible causes of error. In all cases we are much more likely to come to correct conclusions when we are making a comparison of rates of change, whether for two countries or for one country in two periods, than when we are making comparisons of absolute amount. G. Relation of the Statistics of Imports and Kxports to the Balance of Trade. The Committee do not propose to deal in detail with the causes of the difference between the total values of imports and exports, as they have been the subject of so much recent and, in some cases, well-informed discussion ; but they wish to emphasise the importance of the definitions of trade and the methods of valuing it discussed in Sections A and B. The totals to be taken are those of General Trade when it includes the whole of Classes 1, 2, and 3 with or without 4; Class 4 enters equally on the two sides of the account, and it is immaterial whether it is included or not. The method of valuation is very important. The value may be taken as any one of those in the following example :— £ Value of goods manufactured in inland town in country X . p PAWS ey AY », packed and ready for delivery in country X . ; . 1,005=a, nf », at exporting agent’s warehouse at portinX . - 1,010=2, re » on board at port in X » S : : : . . LOIZ=a, pe » insured for sea transit at port in : ‘ , > LOltSa; a » on board at port in country Y . fs : . s -. 1,050=2a; delivered to customer in country Y . : 1,055 =a, [Assuming that duty, if any, has been subtracted from ‘the last total. ] Of the sum paid by the customer in Y, 1,012/. will be received by various persons in X, and 5/. (#,;—a,) is divided among various persons in Y. As regards the country X, the total services up to 1,012/. at least must be paid by money or its equivalent from abroad; as regards the country Y, not more than 1,050/. is to be paid by exporting money or its equivalent. The intermediate 38/. (~;—x,) may be due to X or Y or other countries. In most trade accounts the value x, would be taken for exports and «, for imports. In U.S.A. 2, is taken for imports ; in Germany x, is taken for imports, but an allowance is made for part of Ha—2). There isa risk that part of «;—a, may be included in imports (if market values are taken), while part of x,;—a, may be omitted ; part of *4—a, may be omitted from, or part of w,—«, included in, exports if manufacturers’ invoices are the basis. 314 REPORT—1904. In balancing imports and exports, every part of x,—a#, must be accounted for—that is, it must be known how each part is dealt with. How far the trade accounts of the United Kingdom allow this is dis- cussed in the next section. H. The Accuracy of the Figures of the United Kingdom. Having described the meaning of the statistics published by the various countries and their relations to two of the problems (sections F and G) for which they are often used, the next question to be considered is how far the figures published really represent the facts. We have no means of knowing the correctness of the figures published by foreign countries, and will confine ourselves to considering the possible insufficien- cies or inaccuracies in those published by our Board of Trade. Quantities and Description. Imports.—Dutiable goods are weighed and measured with the utmost exactness. Free goods are in general weighed or measured at the docks, and the invoice return is generally checked by the customs-house official, who obtains the exact return from the importing agent after the goods are examined. Corrected returns of this sort are sent to the Statistical Department in large numbers. Exports.—These are not checked except (by way of test) in a percent- age of cases. There is no doubt great possibility of carelessness on the part of exporters ; where an invoice is incorrect for any reason, it is not likely they will go to the trouble of making another and different state- ment for the sake of statistical accuracy, if they can avoid it. It does not follow, however, that in general reliance may not be placed upon the returns where the exporters have no motive to deceive. Stories which we have no reason to doubt, have reached us as to intentional mis- statement in regard to particular articles of trade, but we have no means of verifying them and estimating what weight should be attached to this source of error. Description of goods.—The Board of Trade classification allows the possibility of a great change in quality without any corresponding change in the category under which goods are described. Thus, cotton cloth is only registered by length, and a thousand willion yards are given under one heading ; but cloth is not of uniform width, fineness, weight, or finish, and, in particular, cloth is often split after manufacture into half- widths. This process would double the quantitative return without any appreciable increase in the labour spent on the goods. In the case of woollen cloth, there is a more complete subdivision into heavy and light, broad and narrow, but goods may undergo great improvement in quality, weight, fineness, and finish without crossing the arbitrary line dividing narrow from broad, &ec., and therefore without showing any difference in the returns. A careful examination of the statistics of the woollen exports shows that there has probably been a very considerable increase in quality without any increase shown in the returns.! Similar difficulties probably occur in very many other trades. 1 See ‘An Inquiry in the Woollen and Worsted Trades,’ by C. Ogden and P. T. Macaulay, Bradford (1903). ON BRITISH AND FORKIGN STATISTICS OF INTERNATIONAL TRADE. 815 The bills of entry, published daily with accounts of the ships entered and cleared, and their cargoes, are based on the same information as that used by the Statistical Department in their published returns ; these bills are much used and valued by the merchants concerned, who are in a position to know the facts, and this would not be the case if they were not found to be substantially accurate. The bills give the values of those goods only whose quantities or numbers are not returned to the customs ; they therefore supply no check on prices declared. Values. The declared values of imports and exports are constantly tested at the Statistical Department by market price-lists. It is found that in general values of particular commodities as declared are confined within a small range, and agree with the lists. Directly any unusual price is shown on the declaration, inquiry is' made as to its cause. In general, then, the goods are entered at their correct value, and changes of price have instantly their effect on the trade returns. For this reason our statistics should show greater fluctuations month by month than those of the continental countries. There are even some cases where two invoices of exports are made, one pro formd for the foreign customs, and one of the true value for our own Statistical Department. While this method tends to give correct returns for the main lines of important and easily described commodities, it is clear that when goods are out of the common run, or are not capable of succinct description, the Department is at the mercy of the declarer. Whether values are official or declared, uncommon goods are likely to be valued wrongly. Lxports—In the case of exports, there is a tendency to give a cif. price instead of f.o.b. It is supposed that the export trade done on ac.if. basis is increasing in magnitude. Theinland manufacturer makes out his invoice on this basis. The exporting agent has no other information, and the f.0.b. price is never known. On the other hand, when goods are sent on consignment for sale, the price entered, whether by the agent or by the Statistical Department, is likely to be the market price, and not to include the price of placing the goods on board. Lastly, the manufacturer may enter his values at the inland market price, or at the value on the docks before lading, and this may not be corrected in all cases by the exporting agent. Imports.—Goods on consignment for sale, which form a very consider- able proportion of our imports, are valued in the returns at their market price. This includes the cost of landing and delivery. All imported wool is priced in this way, the basis being the prices realised at six weekly sales, and this price is used for the six weeks after the sale, and so lags behind its true rate. Again, goods may be invoiced so as to include in their price delivery at an inland town. Lastly, it is said that the value of goods sent from a foreign firm to an agent in England in some cases are artificially increased, so as to show no profit and escape income-tax. In the case of exports, there being no check except comparison with price-lists, entries can be filled up with any degree of carelessness so long as they do not show any abnormal deviation in price. In the case of imports, miscellaneous goods, or goods imported in small quantities, or those whose value is uncertain till they are sold, are valued almost by guess-work, 316 REPORT—1904. It would appear that the Statistical Department is mainly dependent on the values stated in manufacturers’ invoices, that in general no second invoice is made for statistical purposes, and that such a change in custom as of offering goods to foreign customers on a c.if. instead of f o.b. basis would increase the apparent value of exports without any real change. A very large trade in precious stoues, to a great extent transit to Amsterdam, is said to be carried on, and entered very imperfectly in imports and exports. The Cape Government state the value of diamonds exported from them to England, e.g., as 5,380,300/. in 1902. The English import total only includes 46,841/. in that year. If any substantial quan- tity of precious stones is, as is supposed, imported into and kept in England, they are not included in our trade returns, and affect the balance of trade. The Committee have not enough evidence to know whether, on the whole, exports or imports are under-valued or over-valued in relation to their values as defined by the Board of Trade. Destination and Origin. As regards exports, on the form which has to be filled in, the final destination, or rather the place to which the goods are consigned, has been asked for many years ; but in Parliamentary Return 131 of 1904 it is admitted that this space has not always been accurately filled up. An appeal is made in that paper to chambers of commerce and merchants to pay more attention to this statement. It is to be noted that Switzerland and Bolivia, having no seaboard, have as yet no separate place in our trade returns. As regards imports there are admittedly very many errors, and it has been practically impossible hitherto to know the origin of those goods which come from countries doing a large transit trade. In the current year 1904, an extra question has been asked on the import form and on the re-export form, asking for the country whence the goods were con- signed as distinct from the country from which the goods were shipped on a through bill. It is intended to publish a supplementary table in the annual statement of trade, containing any information which this new heading brings to light, without as yet altering the existing tabulation. The Committee welcome this as a step in advance. J. Conclusion and Suggestions. The Committee are much impressed by the extreme difficulty of hand- ling statistics of International Trade, even when dealing with the reports of the United Kingdom whose genesis and meaning are well known to them. They recommend extreme caution in using any such statistics, for even when regard is paid to all the definitions, limitations, and sources of error analysed above, it is not at all easy to know within what limits of error the statistics may be trusted. Itis possible, however, to discriminate, and to state that some of the difficulties are comparatively unimportant. The treatment of improvement trade is a small matter. The differences in method of estimating values in the United Kingdom, France, Germany, Russia, and Austria should not have much effect when a period of more than a year is in question, while the methods of Holland and U.S.A. make comparison of their statistics with those of other countries very ON BRITISH AND FOREIGN STATISTICS OF INTERNATIONAL TRADE. 317 difficult, The inaccuracies in price statements in the United Kingdom are probably of not much importance in the main lines of goods, and the aggregate value is not much affected. It is probably safe to compare the records of total imports and total exports in particular countries with their own previous records, if we pay the necessary attention to the changes discussed in Section D above. In Germany we cannot go back beyond 1880. ‘There is a widespread distrust of the trade statistics of U.S.A. We can compare the rates of increase in one country with those of another more safely than we can compare the actual amounts in par- ticular years. On the other hand, we cannot at all easily compare either the total special or the total general trades of one country with those of another. We cannot divide a country’s exports into those of home pro- duce and of foreign produce in any systematic way. We cannot, however we group countries together or analyse the figures, use the statistics repre- senting the total trade between two countries or two groups of countries, except in the roughest way, for purposes which would not be affected by a great percentage error. The Committee make the following suggestions, which should rather be regarded as statements of the kind of information they have specially felt the want of, and which does not seem impossible to obtain, than as final expressions of opinion as to the best way of remedying the defects in our knowledge. They, however, attach considerable importance to No. 6. 1. That the Board of Trade should make an inquiry, to whatever extent and in whatever way proves practicable, as to the prevalence of erroneous statements, especially of value of exports. 2. That the Board of Trade should make an estimate of the extent to which export trade is done on a c.if. basis, and as to whether any source of error is introduced in the published values by this development. 3. That in the same way an estimate should be made as to the over- valuation of imports when they are valued at market prices. 4, That the classification of goods by quantity and quality at present in use is not perfect, and that the Board of Trade should consult the chambers of commerce and others as to the methods of improving it. 5, That it should be considered whether exports of textile goods cannot be entered in some way which will give more detailed information, and make the returns more easily comparable with those of foreign countries. 6. It is very advisable for the sake of the public who use the official publications that a reasoned statement relating to the accuracy and exact meaning of the returns should be inserted in every Annual Statement of Trade, and in a more contracted form in the Statistical Abstract for the United Kingdom and in the Monthly Returns. In the same way a careful and brief criticism of the meaning and accuracy of the statistics of trade of foreign countries should be inserted in the Statistical Abstract for the Principal and other Foreign Countries. As it is, it is a matter of the very greatest difficulty for even the educated public to attach the right meaning to the official returns. The Committee regard with satisfaction the steps the Board of Trade have taken in Cd. 1761 and No. 131 of 1904 to inform the public on these matters, and trust that publications of this nature will continue to be issued, 318 REPORT—1904. If the Committee are reappointed they will be able to develop and extend the analysis they have already made, but they wish to represent that the inquiry is far too involved and difficult for them to carry to a complete issue, and that it should properly be taken up by the Govern- ment department concerned. K. Bibliography. The Committee append a list of the papers consulted in their investi- gations. They have found their labours considerably lightened by the reports drawn up by Sir Alfred Bateman for the International Institute of Statistics, in the volumes named below. ‘The Official Trade and Navigation Statistics,’ Bourne, ‘ Stat. Soc. Journ.’ 1872. Bulletin de l'Institut International de Statistique, vol. ii. p. 294; vol. xi. pp. 138 and 59; vol. xii. pp. 121 and 71. ‘The Use of Import and Export Statistics,’ Giffen, ‘Stat. Soc. Journ.’ 1882, and Essays in Finance (2nd series). ‘Thirty Years’ Export Trade, B. Ellinger,’ ‘ Econ. Review,’ 1902. ‘Value and Comparability of English and German Foreign Trade Statistics,’ B. Ellinger, Manchester Stat. Soc. (Read March 1904.) Statistical Abstracts for the United Kingdom. (Annual.) Statistical Abstracts for Foreign Countries. (Annual.) Trade and Navigation Returns of the United Kingdom. (Monthly and Annual.) ’ Waarenverkehr des Deutschen Zollgebiets mit dem Auslande. (Annual.) Tableau général du Commerce et de la Navigation de la France. (Annual.) Tableau Décennal du Commerce de la France, 1887-1896. Tableau général du Commerce de la Belgique avec les Pays étrangers. (Annual.) Holland—Statistiek van den In-, Uit-, en Doorvoer over het Jaar 1902 (and simi- larly for previous years). The Foreign Commerce and Navigation of U.S. a (Annual. ) The Statesman’s Year-book. Purliamentary Papers, §c. Trade between the United Kingdom and France: No. 405 of 1881. Statistics of the Foreign Trade of Germany: C. 5597 of 1888. British Trade and Production 1854-1895: C. 8211 of 1896 (p. 70). Comparative Statistics of Population ... in the United Kingdom and some leading Foreign Countries: C. 8322 of 1897, and Cd. 1199 of 1902. British and Foreign Trade and Industry : Cd. 1761 of 1903. Tariff Wars between certain European States: Cd. 1938 of 1904. Trade of the United Kingdom with Germany: No. 131 of 1904. The Tidal Régime of the Mersey.—Report of the Committee, consisting of Lord Kenvin (Chairman), Mr. J. N. SHOOLBRED (Secretary), and Professors GEORGE H. Darwin, OsBoRNE REYNOLDS, HELE- Suaw, and W. C. Unwin, appointed to obtain information respect- ing the Tidal Régime of the River Mersey, with the object of sub- matting the data so obtained to Harmonic Analysis. Since the Mersey Docks and Harbour Board have for the last sixty years been entrusted by Parliament with the charting, lighting, and buoying of the River Mersey, and have also under their charge the various gauges THE TIDAL REGIME OF THE MERSEY. 319 along the tidal portion of that river, the Committee considered that they would be in possession of the most accurate and authentic records respecting the tidal action which has been, and is at present, taking place in the Mersey. The Committee therefore instructed the Secre- tary to communicate with the Mersey Docks and Harbour Board to ascertain what information they would be prepared to afford to the Committee. It may not be out of place here to refer to the causes which have led to the appointment of this Committee. During the past thirty years several communications, and reports of Committees, connected with tides in the River Mersey have been presented to the Associa- tion. In 1885 Professor George Darwin communicated to the Royal Society a paper, summarising the results of the Harmonic Analysis of the Tides at various points—amongst others Liverpool—between 1857 and 1870. It is well known that of recent years, commencing in 1890, great improvements, by dredging, have been gradually carried out in the entrance to the Mersey and in the approach-channels to Liverpool. In this way about eighty million tons of sand have been removed, and about 16 feet of additional depth over the bar, at the seaward entrance, have been secured for the navigation. The gradual extension of the dock and other river walls of late years have also provided for the tidal flow, a smoother and more regular channel in the Mersey. It was therefore thought possible that the form of the tidal wave might have been somewhat affected by these causes, and that it might be ad- visable, in the interests of science, to verify again by means of the most recent tidal records the results previously arrived at, by the Harmonic Analysis of the Liverpool tides of some forty years ago. Hence the appointment of the present Committee. The Mersey Docks and Harbour Board, when approached by the Secretary of this Committee, intimated through their General Manager, Mr. Miles K. Burton, that it would afford them much pleasure to assist the Committee in any way they could ; and they directed their Marine Surveyor, Commander Henry Belam, R.N., to afford the Committee access to any documents which might be deemed desirable, in order to further the objects of the Committee. After some further correspondence it was decided that ‘The Register of Tides at the George’s Pier, Liverpool, for the year 1902’ would be best suited for Harmonic Analysis; and these records were ac- cordingly handed by the Marine Surveyor to the Secretary for that purpose. Mr. Edward Roberts, of the ‘ Nautical Almanac’ Office, well known in connection with Tidal Harmonic Analysis, who had carried out the calculations of the previous investigations into the Liverpool tides of 1857 to 1860 and 1866 to 1870, was good enough to offer the Committee to investigate the tidal registers of 1902, free of expense to them, so far as was necessary to ascertain whether there was any material difference between the results for the later period, and those of the two earlier ones. This offer of Mr. Edward Roberts having been accepted by the Com- mittee, with thanks, the ‘Register of Tides at the George’s Pier, Liverpool, for 1902,’ above referred to, was handed to him. Although it was only towards the end of May that it was found possible to do so, yet 320 REPORT—1904, Mr. Roberts has been good enough to send to the Committee, for the pur- pose of their present report, the following communication :— The Harmonic Analysis of the Tides at George’s Pier, Liverpool, for 1902. The following is the Analysis of 8, and M. Series of Liverpool, 1902 :— A (Mean Tidal Range) = 4-952 feet above O.D.S. a f H—3:188 feet M pre feet “2 « —11° 32’ “2 | « —326° 45’ S H—0:043 feet M H—0'111 feet 4 { Kk —307° 4’ 3 | « —319° 0’ M { H—0'657 feet 4 |on —244° 2! N.B.—The ‘ «’s are referred to Green- M { H—0'180 feet wich Meridian, as before. 6 | « —353° 6’ 8 | « —248° 6! These figures are subject to revision, but can be taken correct for present com- parison. I have found a few misreadings of the Tide Gauge Diagrams; it is possible that there may be a few more, but I have not time now to go thoroughly again through all the figures. It will be seen that the above are almost the exact means of the previous two sets of three and four years, previously analysed; so that it may be assumed that the tides at George’s Pier have undergone scarcely any change during the last forty years. Eltham, August 4, 1904. Comparison of Tidal Diagrams of Different Periods. The Marine Surveyor, in addition to the Register of the Liverpool Tides for 1902 dealt with by Harmonic Analysis by Mr. Edward Roberts, was good enough to place at the disposal of the Committee a number of tidal curves, taken by the various self-registering gauges established by the Mersey Docks and Harbour Board, at different points throughout the tidal portion of the river, from the Bar to Warrington. A part of these tidal curves, limited in number, owing to shortness of time, were selected by the Secretary for comparison. The several periods for comparison being 1903 as representing the present dredged state of the Bar, and the improved conditions of the tidal flow in the river ; 1893 as presenting the conditions immediately before those improvements were commenced ; and 1874 as representing a still earlier period. When, as it happened, tidal observations had been carried out under the persona] superintendence of the Secretary on certain tides, at points in the higher reaches of the river where self-registering gauges have since been established. These results, together with the records of the two then existing Mersey Docks and Harbour Board gauges, at Hilbre Island, and at George’s Pier, afforded a complete series of points identical with those of the later dates of 1893 and of 1903. The tides selected for comparison were the equinoctial springs and neaps, of the vernal equinox, in the years just indicated, and the records were those of the gauges at Hilbre (the Bar), George’s Pier, Eastham (Manchester Ship Canal entrance), Garston, Stanlaw Point, Widnes, Fidlers Ferry, and Warrington. These gauges embrace the entire tidal establishment of the River Mersey. The tidal curves, at each particular gauge, showed that no material change had occurred, during the thirty years so compared, either in the range of the tide or in the form of the curve. However, in the extreme upper reaches of the narrow fluvial portion, the tidal stream set in earlier THE TIDAL REGIME OF THE MERSEY. 321 in the flow, and remained somewhat later during the ebb, in 1903 than in 1893 and 1894. This is probably due to the increased facility afforded for the ingress of the flood tide by the deepening of the bar. That this advance in the time of ingress of the current did not show itself in the lower and deeper reaches of the river might be explained by the fact, that the quantity of water entering is small compared with the much larger quantity already there. But in the fluvial portions of the river, above referred to, the amount of water brought by the tidal current must be considerable, compared with the land water in those parts of the river. In any case the result of this comparison of tidal curves representing an interval of thirty years, and extending over the whole tidal portion of the Mersey, confirms what the Harmonic Analysis indicates for the tides of Liverpool itself. The Committee desire to be allowed to present the thanks of the Association to the Mersey Docks and Harbour Board, and to their officials the General Manager and the Marine Surveyor, for their courtesy in having placed so much information at the disposal of the Committee in order to assist them in carrying out the objects for which they were appointed. Likewise the Committee wish to record their best thanks to Mr. Edward Roberts for having, at considerable incon- venience to himself, afforded them the information above referred to as to the Harmonic Analysis of the Liverpool tides of 1902. In conclusion, the Committee desire to put on record its gratitude to Mr. Shoolbred for his care in preparing the preceding Report ; and, generally, for all the time and thought which he has devoted to the inves- tigation of the subject submitted to it by the British Association. Archeological and Ethnological Researches in Crete.—Report of the Committee, consisting of Sir JoHn Evans (Chairman), Mr. J. L. Myres (Secretary), Mr. R. C. Bosanquet, Dr. A. J. Evans, Mr. D. G. Hoaarrn, Professor A. MAcALisTER, and Professor W. Ripceway. PAGE APPENDIX: Excavations at Knossos, Crete, 1904. By Dr. ARTHUR J EVANS. 322 Tur Committee report that of the grant assigned to them at the South- port meeting of the Association the sum allocated to archeological research at Knossos has been paid over, as usual, to the Cretan Exploration Fund, and expended in furthering the exvavations of Dr. Arthur J. Evans, whose report on the season of 1904 is appended. The sum, which was allocated to ethnological research, was put at the disposal of Mr. W. L. H. Duckworth for the investigation of the physical characters of the ancient and modern population of Crete on the same conditions as last year. Mr. Duckworth, however, was not able to arrange to revisit Crete, as he had proposed, in the season of 1904, but the Com- mittee have every hope that he may be able to resume his observations there at an early date. A further grant is asked in aid of this branch of the Committee’s work. The work at Knossos also continues to promise results of the highest scientific importance, and the Committee therefore ask to be reappointed, with a further grant. 1904, Y 322 REPORT—1904. APPENDIX. Excavations at Knossos, Crete, 1904. By Dr. ArrHur J. Evans. The campaign of 1904 at Knossos had a threefold objective :—(1) the continued exploration of the lower strata of the palace itself; (2) the further investigation of dependencies lying beyond what may be called the inner enceinte ; and (3) the search for the tombs. (1) The researches within the palace area have been very extensive. Methodical explorations of the strata below the later floor levels have thrown much light on the earlier history of the site. A variety of new data have been acquired for distinguishing the first and second periods of the later palace, and fresh light has been thrown on constructions belonging to an earlier palace. The evidence of an earlier front to the west of the Central Court has become clear. New stone repositories have come to light and the original doorways of the West Magazines. In the north-west quarter further deep-walled pits have been opened out. A very important section has been cut below the pavement of the West Court revealing a succession of Middle or Early Mindan floor-levels, together with their characteristic ceramic relics. Below this, again, some seven metres of Neolithic layers were explored. In some cists of the West Magazine were found fragments of wall paintings that had adorned an upper hall on this side. Portions of a pillar shrine were represented on these, showing fetish double axes stuck into the columns. Other fragments referred to scenes of the bull-ring and crowds of spectators. A great analogy is thus presented to the ‘miniature’ frescoes found in 1900. In the north-east part of the site some of the great pithoi belonging to a magazine of the earlier palace have been built up. These are larger than any vessels of the kind yet discovered, attaining a height of over two metres. The magazines have been roofed over for their preservation. (2) A Minéan roadway paved with fine slabs has been traced running westwards from the Theatral Area for a distance of over 200 metres. The work here has been very severe, as the pavement lay at a depth of nearly twenty feet below the surface, and involved the clearing away of a mass of later structures of no account. Pits sunk to the north of this line, moreover, revealed the existence of important Minéan buildings, and in order to make a preliminary exploration of these a wide cutting had to be carried out in this direction. The traces of important structures have been thus brought to light, which derive extraordinary interest from their associations. A rich deposit of inscribed clay tablets was here found referring to the royal chariots and weapons. Near one of these, mention- ing a store of 8,640 arrows, were found the remains of two officially sealed chests containing a large number of carbonised arrows with small bronze heads. It is possible, therefore, that the structures form part of the royal arsenal. At this point, owing to the difficulty and expense of the work, and the advance of the season, the excavation had to be broken up. It is most necessary, however, that this promising area, extending along the newly discovered roadway, should be fully explored. Owing to the vast mass of earth to be removed a Décauville railway will be probably necessary. (3) On a hill about a mile north of the palace a considerable cemetery ON ARCHAEOLOGICAL AND ETHNOLOGICAL RESEARCHES IN CRETE. 323 was discovered. One hundred tombs were here opened, the contents of which showed that the bulk of them belonged to the period immediately succeeding the fall of the palace. The civilisation was, however, still high, and the character of the art displayed by the relics found showed the unbroken tradition of the Later Palace Style. Among the objects brought to light were a number of bronze vessels, implements, and arms, including swords, some of them nearly a metre in length. One of the shorter swords has a gold-plated handle engraved with a masterly design of lions hunting wild goats. The jewellery and gems discovered were of the typical ‘mature Mycenzean’ class, and a scarab found in one of the graves is of a Late Eighteenth Dynasty type. Among the painted ware ‘stirrup vases’ were specially abundant, some with magnificent decorative designs. The tombs were of three main classes: (a) Chamber tombs cut in the soft rock and approached in each case by a dromos ; in many cases these contained clay coffins, in which the dead had been deposited in cists, their knees drawn towards the chin. (6) Shaft graves, each with a lesser cavity below, containing the extended skeleton, and with a roofing of stone slabs. (c) Pits giving access to a walled cavity in the side below ; these also contained extended skeletons. Unfortunately, owing to the character of the soil, the bones were much decayed, and only in a few cases has it been possible to secure specimens for examination. :Microscope and Natural | poy G. B. Stallworthy 1 eee bo bo bo bo to bo History Society. Hertfordshire Natural History Society Percy Manning, M.A., F.S.A. Holmesdale Natural History Club. Miss Ethel Sargant. Hull Geological Society . . J. W. Stather, F.G.S, mee ares and Field Naturalists’ | T. Sheppard, F.G.S. Institution of Mining Engineers 5 eee G. M. Capell. Isle of Man Natural History and ] ,,, Antiquarian Society. | Professor W. A. Herdman, F.R.S, Leeds Geological Association . . Professor P, F. Kendall, F.G.S. Leeds Naturalists’ Club and Scientific Ananciatiga, \ H. C. Marsh. Liverpool Geographical Society . . Captain Phillips, R.N. Liverpool Geological Society . . Joseph Lomas, F.G.S. vines Nobis alge alae se \ Professor W. Boyd Dawkins, F.R.S. Manchester Geographical Society . H. Yule Oldham, M.A. Manchester Microscopical Society . F. W. Hembry, F.R.M.S. Manchester Statistical Society . . Professor §. J. Chapman, M.A. Marlborough College Natural History \ E. Meyrick, F.B.S Society. J nae CRE Midland Counties Institution of En- neat \ Rev. G, M. Capell. Midland Institute of Mining, Civil, and Mechanical Engineers. \ Rom, G, Me Gape Norfolk and Norwich Naturalists’ } arian arate Society. pes Northamptonshire Natural History \ Society and Field Club. j North of England Institute of Mining and Mechanical Engineers. } Beeby Thompson, ¥.G.S8. Rey. G. M. Capell. North Staffordshire Field Club . . W.D. Spanton, F.R.C.S. Nottingham Naturalists’ Society . Professor J. W. Carr, M.A., F.L.S. Paisley Philosophical Institution . John Woodrow, Perthshire Society of Natural Science A. S. Reid, M.A. Quekett Microscopical Club, London . John Hopkinson, F.L.S. ea Literary and peice R. Ashworth, D.Sc. Se oe ae dt, Soe anata a rocietiee on Of Belentife) Rev, R, A: Bullen, BAL, FILLS. Tyneside Geographical Society . . Herbert Shaw, F.R.G.S. Te GONE ek mien a neleere, eG Woolhope Naturalists’ Field Club - Rey. J. O. Bevan, M.A,, F.S.A. pe alas and Polytechnic } Roy Wo JohneonoE se Yorkshire Naturalists’ Union . . W. West, F.L.S. Yorkshire Philosophical Society . Dr. Tempest Anderson, B.Sc. First Conference, September 8. This Conference was presided over by Principal E. H. Griffiths, F.R.S. The Corresponding Societies Committee was represented by Mr. Whitaker, E.R.S., the Rev. J. O. Bevan, the Rev. T. R. R. Stebbing, F.R.S., Pro- fessor W. W. Watts, F.R.S., Mr. J. Hopkinson, and Mr. Rudler. The Chairman, as an old Cambridge man, offered a cordial welcome to _the Delegates, and acknowledged the courtesy of the Master and Fellows —— CORRESPONDING SOCIETIES. 38] of Gonville and Caius College in having placed some extremely convenient rooms at the disposal of the Delegates. The Secretary then read the Report of the Corresponding Societies Committee, which was adopted. The Chairman, before proceeding to deliver his Address, remarked that his object on that occasion was more to promote discussion and arouse attention on certain matters than to obtain any very definite expression of opinion. He proposed, after having read his Address, that there should be a discussion on the points raised therein, but perhaps any definite con- clusion had better be reserved until the second meeting. Principal Grittiths then read the following Address :— Tassume that the chief object of these Conferences is the quickening of general interest in the study of Natural Science and in the work of the British Association. Our duties are not those of a Section, but rather those of the husbandman who prepares the ground in the hope and belief that the Sections may hereafter reap the harvest ; or, to vary the image, we are here to study the machinery rather than its products. A study of the Reports of the Conferences of the Delegates of Corre- sponding Societies from the time that such Conferences were officially instituted in 1884 leaves the impression, at all events upon my mind, that the results have scarcely been commensurate with the expectations of those who instituted this body, or with the possibilities presented by the situation. It is stated—I believe on good authority—that there are in this king- dom something like 500 Scientific Societies with a total membership approaching 100,000, and that at the present time both the number of Societies and of the members thereof is steadily increasing. I think we may say without hesitation that the general interest of the British public in science is greater now than at any previous time in our history. Nevertheless the number of Societies affiliated to the British Association is but a small proportion of the total, and I am afraid that of many of those it may be said that the connection is nominal rather than real. Sir Norman Lockyer, in his Address at Southport, spoke as follows :— ‘We not only, then, have a scientific Parliament competent to deal with all matters, including those of national importance, relating to science, but machinery for influencing all new councils and committees dealing with local matters, the functions of which are daily becoming more important. ‘The machinery might consist of our Corresponding Societies. We already have afliliated to us seventy Societies with a membership of 25,000. Were this number increased so as to include every Scientific Society in the Empire, metropolitan and provincial, we might eventually hope for a membership of half a million.’ This of course is an impressive statement, but the weight thereof depends very greatly on the real meaning of the expression ‘atftiliated to us.’ Is this affiliation a real thing? Let us see what it means in practice. A Society consisting, perhaps, like the one I represent, of between 400 and 500 members, nominates one Delegate. Of the Delegates thus appointed it would appear from our past records that not more than some fifty or sixty per cent. present themselves at our meetings; and, although there is evidence that the action of some few Societies has been directly influenced by our proceedings, I confess that the results can hardly be 3882 REPORT—1904. considered satisfactory when we contemplate the elaborate machinery by which they have been obtained and the labours of those who have kept the machinery in action. I trust the Delegates will not suppose that I am endeavouring to belittle the importance of these Conferences. I believe that, rightly directed, we have here a body which may become an immense power for good, and that this child, which I am afraid is regarded by some as the Cinderella of the family, may grow to be one of the greatest of the daughters of the Association. Whatever may be our opinion on the fiscal question, or the extent to which we are suffering from the competition of other nations, men of all parties will, I trust, be at one in the belief that, whatever remedies may be suggested, there is urgent need of better education in science, as well as of more scientific education. Not only is the comparative pace of our competitors increasing, but unfortunately they have, as pointed out by Sir N. Lockyer, gained upon us at the start. Our immediate duty is to place the needs of higher scientific education before the people of this kingdom. Once convince ‘the man in the street’ that his business pro- sperity, nay, his very wages, are adversely affected by our inadequate system of higher education, and our difficulties will speedily vanish ! Consider a somewhat parallel case. You may remember how some fifteen to twenty-five years ago a number of able and enthusiastic men suc- ceeded in convincing the British voter that his safety and prosperity depended upon an eflicient Navy, and how, since the time that this convic- tion was brought home to the minds of our countrymen, no difficulty has been experienced in obtaining the funds necessary to create a Navy com- mensurate with our needs. Let us profit by this example. Our rulers are, I believe, already convinced of the advisability of rendering increased assistance to the cause of scientific investigation, but they cannot loosen the Imperial purse-stripgs until they know that the country is prepared to acquiesce in a liberal policy. Our task is that of ‘spade work,’ and should be even a less heavy one than that undertaken by our naval reformers, for we can show that, once established, a satisfactory system of high scientific education, so far from being a cause of continual outlay, will add to the wealth and prosperity of our country. But it may be asked, ‘What has all this to do with the constitution of this body?’ I think the connection is evident. If we could supply the links which would bind together all the Scientific Societies of this kingdom, so that in matters of national importance they would move as a united body, it would be difficult to overestimate the influence which could be thus exerted, for it is certain that amongst the members of these local Societies are included many of the most intelligent and influential men in their respective districts. At present, however, apart from their interest in natural science, these local Societies have little in common. We may picture them as a scattered heap of iron filings, and we want the British Association to be the magnet which, placed in their midst, will transform the confused assemblage into a field of symmetry and beauty. The work of local Societies is of two kinds: one may be termed educa- tional, the other technical. In the latter I include actual observational and investigational work. I confess that, at the present time, I regard the former as the more important branch. The work is educational, not only in arousing intelligent interest in the facts of natural science and CORRESPONDING SOCIETIES. 383 quickening in the individual the power of observation, but also in pro- moting the missionary spirit which will enable the members to excite the interest and sympathy of their neighbours. It is possible that our present constitution does not attach sutlicient importance to this educational part of the work. I refer especially to Regulation I., which confines the right of representation at this Conference to those Societies which publish proceedings. Now it is very doubtful if publication is the best test of merit. My own impression is that we have ‘too much cry’ for the amownt of ‘wool,’ and if we exclude from our deliberations all those Societies whose circumstances or inclinations have caused them to refrain from adding to the mass of literature under which there is danger of our being smothered, it is possible that we are excluding the very bodies whose sympathy and interest we should most wish to encourage. If we are to lay down some criterion, I would suggest that of membership rather than that of quantity of print. It is true that as the Delegates become ew-officio members of the General Committee of the Association some guarantee ought to be given that those who receive this privilege have some real knowledge of, and interest in, natural science. This difficulty might be met by the establish- ment of two classes—namely, affiliated and associated Societies. Delegates from affiliated Societies (those which undertake local investigations and publish the results) might continue to receive, as at present, the privilege of membership of the General Committee ; whereas Delegates from the associated Societies might be invited to take part in the deliberations of these Conferences and to receive copies of the reports, &c., without becoming members of the General Committee. Any local Society which has existed for a period of, say, three years, and numbers not fewer than fifty members, might well receive the right of appointing a representative. Surely we desire to throw our doors as wide open as possible ; surely we wish to give every encouragement to all scientific Societies, but more especially to those working under difficulties, to strengthen the hands of their promoters and to ask their aid and assistance in our deliberations. Moreover, it is precisely those Societies with narrow means, and whose members are possibly drawn from the working classes, that can be of the greatest use to us. They are missionaries situated where we most want them, and preaching to the unconverted. This yearly meeting of single Delegates from a few of the leading Societies, although an admirable nucleus, is not sufficient to produce crystallisation of the scientific interests in solution in the population of this kingdom. We want more frequent means of intercommunication, more power of directing individual move- ments towards one common object. I suggest that all associated and affiliated Societies should be asked to make a small contribution (to some extent proportional to their numbers) in order to defray the expenses of a Journal of Corresponding Societies, which would be published at stated intervals, An annual contribution at the rate of, say, 5s. per fifty members would, with our present constituency, produce a sum exceeding 100/. per annum, and if the suggestion as to the addition of associated Societies be accepted, I believe this sum would soon be more than doubled. The Council of the British Association might well be asked to contribute an annual grant during, say, the first three years ; after which interval I believe the scheme might become self-supporting. Such a journal should start on very unambitious lines : it should contain a list of the meetings which have taken place since the preceding week, the titles (merely) of 384 REPORT—1904. any papers which had been read, and official notices from any Societies which wished to call attention to work requiring co-operation, or to points upon which information was desired. The great use of such a journal would be that, at any time, it would be possible to unite all the connected Societies in common action for the attainment of some purpose of national or scientific importance ; and if this journal was edited under the auspices of the British Association, the connection with the Central Body would be brought home in a very real manner to the members of this scattered constituency. Few Societies would grudge this small contribution of scarcely more than one penny per annum per member. I am aware that many objections could be urged against such a scheme ; but I donot think that the difficulties are insurmountable, and, once surmounted, a great step would have been taken towards the utilisation of that general interest in natural science of which the best evidence is to be found in the growth, the numbers, the variety, and the labours of the local Societies of this kingdom. I trust it will be understood that I make these suggestions with great diftidence. I have taken no part in the work of these Conferences in the past, and it was therefore with considerable hesitation that I accepted the honour of nomination as your Chairman to-day. The circumstances under which I have been placed during the past two years, however, have strongly impressed upon me the possibilities placed at our disposal by the existence of local Societies. I am living in the midst of a great working-class population, and have been brought in contact with the workers in the coal mines of Glamorgan and Monmouth. I am also serving on educational and other bodies in which these workers are largely represented. At first it appeared to me that any demands for assistance for higher scientific education or research were regarded with indifference ; but I have found that when the facts of the situation were placed before the men or their representatives, when it was pointed out to them how greatly their employment and their interests were dependent on the results obtained by scientific investigations, their attitude of indiffer- ence—if not of suspicion—was replaced by one of sympathy and good will. Our local Societies have it in their power to bring such facts home to the people of this country, and, great as are the services which the British Association has rendered in the past, I believe if it can accomplish the task of uniting the activities of our local Societies in one common effort, it will not be reckoned amongst the least of the achievements of the Association. Having tendered this apology for my audacity, I now venture to ask the Delegates to give their consideration to the following proposals, it being understood that, even if the principles therein conveyed are approved of, these proposals will require redrafting, and that conse- quent ones connected with matters of detail will require careful con- sideration :— (1) That any Society which undertakes local scientific investigation and publishes the results may become a Society affiliated to the British Association, (2) That the Delegates of such Societies shall be members of the General Committee. (3) That any Society formed for the purpose of encouraging the study of natural knowledge which has existed for three years and numbers not fewer than fifty members may become a Society associated with the British Association. CORRESPONDING SOCIETIES. 885 (4) That all associated Societies shall have the right to appoint a Delegate to attend the Annual Conference, and that such Delegates shall have all the rights of those appointed by the affiliated Societies, except that of membership of the General Committee. (5) That all affiliated or associated Societies shall contribute annually the sum of at least 5s. for each fifty members, and that the funds thus obtained be utilised for the purposes of a ‘Journal of Corresponding Societies.’ (6) [In case proposition (5) is approved :] That the Council of the British Association be requested to make an annual grant towards the expenses of such a Journal on the understanding that such grants shall cease if the Journal become self-supporting. Mr. W. Whitaker, in opening the discussion, remarked that he had listened to this Address with very great pleasure, and was glad to find that the Chairman had been thinking on almost the same lines as he had himself for a few weeks. The speaker wished to bring before the meet- ing the terms on which Societies are affiliated, because it seemed to him that the time had come when it might be well to reconsider those terms and perhaps revise them. The existing rule is that they should take all Societies who publish original work. That rule is fixed by the General Committee. On the face of it, it was a very good rule indeed, and it had worked very well so far ; but the speaker was faced a few weeks ago with this difficulty. Visiting a Society in a fairly out-of-the-way country place he found it did not publish anything but the bare Annual Report. Yet it had a splendid museum. This was kept in very good order, with the specimens properly labelled. Why did not that Society publish ? One reason was that it had spent all its money on the museum. Did they not think it had done quite as well in keeping up that museum as if it had pub- lished ? It seemed to him that work of that sort ought to be encouraged, He suggested that, after discussion here, the Delegates should request the British Association Committee of the Corresponding Societies to consider _ the terms on which Societies are affiliated. He was sure those members of the Committee who were present would be glad to act on the lines which the Delegates desired. Whether they adopted or not all the propo- sitions the Chairman had brought forward was another question altogether, The speaker differed very much from him in details, but on the general principle he entirely agreed with him, and hoped something would be done to enforce that general principle and widen their bounds by letting them take in many Societies who really do very good work, although they publish but little. Sir Norman Lockyer said he had listened with great pleasure to the Chairman’s remarks, and, like the previous speaker, he felt that his pleasure was all the greater because they corresponded closely with some of his own views. Last year he attended the Conference at Southport chiefly to learn how the suggestion in his Presidential Address as to the formation of a great scientific organisation would be received by the Delegates. He might now explain that a British Science Guild was being started, quite independently of the British Association ; and it seemed to him that the Guild could work absolutely shoulder to shoulder with the Societies in the extension of their interests. He was rejoiced to hear the proposal that there should be more frequent communication between the representatives of the Societies than is afforded by the 1904, cc 3886 REPORT—1904. Annual Meeting of the Delegates. He could quite understand that there might be numerous questions cropping up in the course of the year which it would be very desirable to discuss in Conference. He felt cer- tain that many of the Societies would see that, in addition to the work which they were now doing, it was necessary in the interests of science to influence the man who has to vote, not only in the County Councils, but in the House of Commons. Mr. P. Ewing (Glasgow) spoke in support of the suggestions made by the Chairman. The Rev. G. B. Stallworthy (Haslemere) said he had very strong faith in the value of the local Societies, and also in the connection between the local Societies and the British Association. He felt very grateful for the pressure put upon the Societies by headquarters to make them do some- thing. This year they had succeeded at Haslemere in publishing two papers, but they were rather dry: one was a catalogue of fungi. Only about five per cent. of the members purchase such things. For all that, it had had a very healthy influence upon a small circle of the members. A practical suggestion the speaker was about to make was this, that possibly a Central Committee might consider whether it were possible to appoint a dozen responsible gentlemen who would visit these local Societies. A few of the Delegates attend the British Association, and they are able to interest just a few round about them; but the interest would be very greatly increased and deepened if a gentleman representing the British Association would come to the local Society with a message from headquarters. That message would reach the great majority of those who attend meetings. He did not regard it as a very practical test as to whether they had a museum or not. Some Societies do not own a museum, because there is already a museum existing in their locality. He thought that if admission to the Association depended upon the recommendation of one of these officials, who would come down, say, once annually or two years in succession, and report upon the nature of the Society, the kind of work done, and the healthiness of it, such a report by a responsible inspector appointed by the Council might be an important factor in determining the question of admission of the Society. Dr. G. Abbott (Tunbridge Wells) wished to support the suggestion just put forward. To his mind the solution of many of the difficulties that were felt would depend on the formation of unions of the Societies in different districts of the country. If there were a union of the Societies in four or five counties, very many more of those Societies would send Delegates to these meetings. One of the chief advantages of the union with which he was connected, the South-Eastern Union, was that it had brought the Societies together. They had got to know men who were giving good lectures, and who were prepared to repeat them. In that way many friendships had been formed and many Societies had been strengthened. The Rev. T. R. R. Stebbing called attention to one departure from precedent which he thought was of the very highest value. Last year the ~ Delegates were honoured by the attendance at this Conference of the President of the Association. This year again they had the presence of the outgoing President. What he wished to insist upon was this, that they should if possible persuade all Presidents and outgoing Presidents to do as Sir Norman Lockyer had done. He hoped that next year Mr. Balfour would take care to honour the Congress with his company. CORRESPONDING SOCIETIES. 387 He was sure that would give a very great access of dignity to this Con- ference of Delegates. In the ‘ Daily Journal’ they had a long list of the Sectional Committees, but no list of the Delegates of the Corresponding Societies! One other point. He was very gratified indeed to hear the Chairman’s suggestion to recognise the association of Societies inde- pendently of publication. If communications were of importance they should be published by some great Central Society, and if unimportant they were perhaps better left unpublished. Mr. A. O. Walker, referring to the suggested payment of 5s. per fifty members, said he represented a Society which had a thousand members, and accordingly on these terms their subscription would be 5/.a year. He was sure they could never afford it. Mr. Theodore Reunert (Johannesburg) stated that he had the honour to be President of the South African Association for the Advancement of Science, which would act as an: agency of the British Association on the occasion of their visit to South Africa in 1905, He then explained briefly what is the present state of things in South Africa scientifically. The South African Association was formed three years ago in Cape Town, during the war, with Sir David Gill as the first President; and it now has members all over South Africa, from Cape Town to the Zambesi, who number something like two thousand. Perhaps it would interest the meeting to hear that one of the most gratifying features of this new South African Association was the hearty and sympathetic support which it had received from the various Governments of South Africa. On the occasion of its first annual meeting in Cape Town the Government of Cape Colony voted something like 400/. to defray the whole cost of publishing their first year’s proceedings. The Government of the Transvaal Colony, on. the occasion of their second annual meeting, voted a similar sum for the publication of that year’s proceedings, and the various Governments among them have voted 6,000/. towards assisting in the expense of the British Association’s visit in 1905. Mr. H. Reid (South African Association for the Advancement of Science) thought that a great deal of the lack of general interest in science may be due to want of help and encouragement from the central bodies in dealing with local Societies. The discussion of the Chairman’s Address was then adjourned until the next meeting. In answer to a question by Captain Dubois Phillips, R.N., the Secre- tary said that the question of the reduction of railway rates for members of scientific societies had been under the discussion of the Committee, but no definite result had yet been attained. It was a matter involving con. siderable difficulty. The Chairman said he thought that naturalists should be treated as generously as anglers. He thought the most effective way of taking action would be to ask the Committee to draw up a statement and forward it to all the affiliated Societies with a request that they would sign it, so that there would be united representation from all parts of the country. He believed that if the Presidents and Secretaries signed a ‘ The names of the Delegates are printed in a conspicuous position in the List of Members, and before the conclusion of the Cambridge Meeting a List of Delegates appeared also in the ‘ Daily Journal’ in response to the appeal above recorded. co 2 088 REPORT—1904, statement and sent it to the managers of the railways, they would probably effect their purpose. He suggested that the Delegates should ask the Committee if they could see their way to discuss this matter, and, if pos- sible, draw up a memorial. Dr. Abbott proposed that the matter should be referred to the Corre- sponding Societies Committee to consider and take action. This was seconded and agreed to. It was resolved that an application should be made to the Committee of Recommendations, asking for the reappointment of the Corresponding Societies Committee, with a grant of 25/. The Rey. W. Johnson, B.A., B.Sc. (Yorkshire Philosophical Society), introduced the following subject :— The Utilisation of Local Musewms, with Special Reference to Schools. The selection of this subject for discussion is probably due to certain remarks made at the Southport meeting last year, when it was hinted that the local museum was often the dumping ground of curious finds for which room could not be provided by the discoverers, instead of being the centre of living interest and new growth. I presume the Association regards the local Societies as feeders, and therefore puts on us the duty of laying the foundation of the scientific habit, and of providing the means of satisfying the longing for more insight into nature. It will be at once apparent that the subject has certain limitations. We must confine our- selves almost entirely to the natural-history side of science study, partly because the general interest of workers lies there, and partly because the local museums lack storage-room for specimens suitable for illustration of the other branches. In discussing the question of ‘The Utilisation of Local Museums,’ in connection with the science work of our school, I lay down the following propositions ; (1) a great amount of material lies buzzed in local museums ; (2) it needs proper description and exhibition to make it available for the use of young students ; (3) it is very desirable that /oca/ natural history, rather than general science, should be illustrated and studied in this con- nection. Collecting, merely for possession of a collection, has been sufficiently disparaged without our adding another word of condemnation. When a young student approaches a specimen, a mere label is often inadequate to attract and inform him. Therefore it is necessary that a more or less detailed description, with drawings of separate parts, should be placed with the specimens side by side in order that there may be no mistake. The method adopted in the Natural History Museum, Cromwell Road, London, is, in my opinion, most effective to this end. There the admirable handbooks, issued in each section are taken paragraph by paragraph, and each state- ment made in the whole description is represented by a real object by its side, so marked by coloured papers, arrows, and guiding lines that a student who works through the cases in succession follows a natural sequence of treatment under scientific guidance. I have often thought that local museums have failed in developing the scientific habit because they have given undue prominence to what is special or rare. Now a beginner wants help in identifying what is common or elementary, for when, on going out on his field-days, he discovers none of the rarities dis- CORRESPONDING SOCIETIES. 389 played in his museum, he is too apt to think that none of his work is worth the trouble, and may be checked at the start in the proper classitica- tion of his work. Having made it my aim to visit local museums wherever possible, I am able to speak at first hand of the hopeless confusion which misleads and repels, in spite of the abundance of most valuable material. Some Yorkshire museums need immediate reclassification and arrangement. I would propose that each town should have a strictly limited collec- tion of the natural objects which are commonly found in that area ; that the flora and fauna should be separate ; that the district in which each is to be found should be indicated ; that, in the case of the flora, the months during which the plants may be found should be added, and that detailed descriptions by competent persons should be attached ; that in every museum there should be a large geological map of the area, with suitable vertical sections, showing the connection between the underground condi- tions and the variety of life on the surface. I should like to see in each museum a collection of the natural orders of plants, pressed specimens obtained locally and easily accessible to indi- vidual students, in order that the flora of the district might be within the knowledge of each boy and girl educated in the area. So, too, with the rocks. There should be a complete series of hand specimens of rocks illustrating the succession of strata in the neighbourhood, and, if the rocks are fossiliferous, or capable of economic use, then the fossils should be associated with the rocks and the economic products exhibited and explained. Each section should be kept in its own room for separate use. This small teaching collection need interfere in no respect at all with the general purpose of the museum as the receptacle of objects of interest of all kinds ; but would ensure, to all who wished it, a proper start on right lines, and would engender in them a keen desire to proceed to a wider knowledge of that branch which interests them. Now comes the question whether we should take the specimens to the classes in schools, or take the classes to the specimens in the museums. Personally I am in favour of the latter. I have watched with interest the growth of the latter plan in Leeds, where excellent results appear to be accruing from the admirable lectures and demonstrations of the Curator of the Leeds Museum, Mr. Crowther. But, apart from the evident success of this scheme, it would teach the young student to regard the museum as the centre of his work, and having been taken there by his teachers for the work of a course, he would soon be found there on his own account, searching for himself answers to questions which have arisen from his own work ; and every museum would become the training ground of a new set of investigators. It may be asked, when can time be found for all this? And that really is a serious question. Yet there is a good answer. During the winter holidays afternoon demonstrations could be given in every centre without dislocating any time-table ; and as there is, I believe, a strong tendency to reduce the demands of ‘home lessons’ a course of evening demonstrations during term could be no heavy inflic- tion on the children, and would be welcomed alike by them and their parents. Now, presuming we have the contents of our museums in order, so reduced in number as not to be bewildering, and so definitely described as to be intelligible, we should easily be able to get the young student to take interest in them. By taking our classes to the museum we should, 890 REPORT—1904. at any rate, teach him the way to the museum. It would accustom him to the idea of resorting to a definite place for the solution of his difficul- ties. It would make the museum the centre of distribution for much useful knowledge, whereas it is too often a swamp in which the streams of knowledge lose themselves. If we could ensure on the part of the teachers a definite acquaintance with the contents of the museums, it would be easy for them in the course of their lessons to refer their pupils to specimens which more fully illustrate the matter under discussion, and thus the grafting of one upon the other would be effected. I am not quite sure whether it would be better to depend on the curators of the museums (or of sections of the museums) for the descriptions or demon- strations, or to attempt to put this on the teachers of the schools. The advantage of the former course would be the intimate acquaintance with the subject and with the specimens of the museum ; of the latter a better acquaintance with the students and their powers, and probably a better aptitude for imparting knowledge due to professional training. If, as is, I believe, the case with the Curator of the Leeds Museum, these qualities can be found combined in the curator, I should have no hesitation about entrusting the whole of the work to him. I imagine that one of the greatest difficulties likely to be met with in the utilisation of our museums will be that of continuity of work, for if frequent changes take place in these offices, the development of the work must suffer from want of sequence. It would probably be wiser to secure, if possible, the attention and care of the science teachers of our schools. We should thus gain the double advantage of a definite interest in a science, and a definite interest in the schools which are using the museum and the course of work. The increasing number of science teachers is a guarantee of a continuous supply of curators. Especially do I think it advisable and desirable that a course of, say, four or five lectures should be given during the winter holidays on the elementary laws of meteorology, with an explanation of the instruments which are used for obtaining weather records, both how they are made and how they are used, together with the chief corrections which are needed to ensure an accurate result. In many museums these instruments are accessible to the public, and a knowledge of their use ought to be common property. There appear to be, in connection with museums, few rooms which are capable of accommodating a class of students for demonstrations. This is an obvious defect, if anything more than individual work is to be attempted, and one of the first improvements to be effected by our museum trustees will be the provision of such rooms with lanterns, screens, and lecture-room appliances adequate for the proper accomplish- ment of this work. I ought to say one word as to the cost of this new development. Many of the curatorships of our museums are honorary, and some carry a mere acknowledgment of work done. We all like to think of education as so attractive in itself, and so far producing in our pupils a thirst for more knowledge gained in a freer and larger way than is possible in schools. Moreover, we wish the museums to be the centres of diffusion of knowledge and the meeting-place of kindred spirits. There appears to be no good reason to be urged against the view that the State should, for services of this kind well rendered, provide an adequate sum for recom- pense, and it should be possible for our local authorities to hand over an CORRESPONDING SOCIETIES. 391 adequate sum to the trustees of local museums which are willing thus directly to help forward and expand the higher science teaching of our schools, corresponding control being, of course, in every case given for the proper disbursement of the assigned money. This work is at any rate as well worthy of such support as are free libraries, or municipal bands, or art-galleries, to which, of course, I have not the slightest objection. Summing up my points, I should like the great interest in Nature study which has lately sprung up to be linked definitely with the museums, that these may help the movement and in return be helped themselves ; that the provision made by curators should be wisely curtailed and definitely directed ; that the professional instinct and pride of the science teachers should be called upon to assist in a great work ; and that the success of the movement should not be imperilled by the premature uprising of the false economist, who has had no opportunity of seeing what other nations can do, and who wishes to appraise the value of any work by its immediate value in current coin. Mr. G. P. Hughes (Warwickshire Naturalists’ Club) said that the paper which had been read had come most opportunely in his case, for it dealt with a subject which had occupied his thoughts and attention for some time past. He dwelt on the importance of giving an interest to the younger generation in country places, and of getting the minds of the young people trained to the industrial interests which they must follow out in after life. If the children of the labouring classes were merely taught a few of the ordinary lessons of schools, then interest would not be directed towards what their future life is likely to be. Heheld that schoolmasters should have some acquaintance with scientific pursuits, and by the aid of museums, which in many parts of the country were dormant, these children might be brought gradually to take a much keener interest in their future life than they do at the present moment. The Rev. G. Capell remarked that he had been a school-manager for about thirty-four years, and had always felt that the difficulty was that no science was introduced by which the minds of the children could be trained and so fitted for the pursuits they were afterwards to enter into. He had been in a district in the North of France, and was immensely struck by the care taken by the French Government to train children in a knowledge of those pursuits which they were to follow in after life. There is a most elaborate system of teaching, including, in addition to scientific training, the practical use of the machinery which they will have to use in cultivating the land and in various other industries. In Germany it is the same. The children’s minds are trained practically and scientifically. That is what we want more of in England ; the practical and the scien- tific should go together. The difficulty is that schoolmasters have not been trained in that way themselves. The speaker thought that attention must be directed to this in future, and the museums would be wonderfully useful in helping masters in order that they might be better prepared to instruct the children. Mr. F. W. Rudler (Essex Field Club) explained that when in 1891 the Museuins Association held its annual meeting in Cambridge, he ventured to refer to the difficulties incidental to museum-demonstration ; and he was glad to find that a method somewhat similar to that which he suggested had been successfully carried out at Leeds. He held that the demonstration should usually be given in a separate lecture-room, and be 892 REPORT—1904. followed by adjournment to the museum. Every museum should be associated with a theatre provided with lantern and other necessary appli- ances. The interest of the museum-question in connection with the Delegates at this Conference seemed to centre in the point of contact between the local museum and the local Society. How could the one assist the other? The speaker referred to the excellent practice in certain museums of exhibiting fresh wild flowers with instructive labels—a source of much interest to young visitors. This, he held, was a department of work which could well be undertaken by the local Natural History Society. Ladies of leisure, taking an intelligent interest in botany, might assist the curator by undertaking to contribute a constant supply of fresh specimens and to furnish them with appropriate labels. Such labels, judiciously written, might convey much useful knowledge in a pleasant form, and would be read and copied by intelligent children. Although it is a great thing to bring the children to the museum, it must be remembered that there is another aspect of the question : the museum may be taken with excellent results to the children. He therefore advocated the circulation of small loan-cabinets of simple specimens—which might be arranged and distributed by the Natural History Society to the schools. The local Society might do much to relieve the curator, who was generally much over- worked and very much under-paid. Every effort to increase the useful- ness of the museum laid additional work upon his shoulders; and the speaker was glad that Mr. Johnson had proposed that museum-demonstra- tions to schools should be adequately paid for. Mr. Hopkinson referred to the Hertfordshire County Museum. At least one half of the 200 or 300 visitors per week were school children. They came in from the Board schools during meal-times, and quickly detected any additions made to the collections, which showed that they took avery great interest in the museum. Sometimes they brought all sorts of things they had collected, but at first almost worthless. For instance, they brought shells with the living animals in them. They were then instructed how to remove them, and were now bringing clean shells and sometimes really good specimens of the different varieties of land mollusca. This showed how a museum would attract children, and no doubt produce good educational results. The Rey. R. Ashington Bullen observed that, in the little parish where he lived, about a quarter of an acre of land was rented and the children were being taught agricultural pursuits. He did not think that they must take a pessimistic view of the education of the children in the country districts, for he believed that a great deal was going on there about which people in general know nothing. Mr. Whitaker remarked that, being lately in a little village in Shrop- shire, he had a conversation with a woman who told him that they encouraged the children not only to collect, but to bring in objects to the school, where they were kept in a case for a certain time. It occurred to him that this was an excellent method of interesting the children and developing a taste for museums. CORRESPONDING SOCIETIES, 398 Second Conference, August 23, 1904. Principal E. H. Griffiths, F.R.S., in the chair, followed by Dr. Tempest Anderson, B.Sc. The Corresponding Societies Committee was represented by Mr. W. Whitaker, Rev. T. R. R. Stebbing, Rev. J. O. Bevan, Mr. John Hopkinson, Dr. H. R. Mill, Mr. 'T. V. Holmes, and Mr. F. W. Rudler. Principal Griffiths, in opening the proceedings, said that he had ventured to take a certain kind of action of his own initiative since their last meeting, which he was going to ask the Conference to be good enough, if they thought fit, to confirm. He thought the remarks that were made on the proposal which he put before the Congress from the chair at the last meeting led to the conclusion that the Delegates would uphold, and were in sympathy with, the view that we ought to bring a larger number of our Societies into touch with the British Association, and that the union between the Society and the British Association should be a more real one than it is at present. The speaker ventured to translate the opinion of the meeting as that, and there was no voice to the contrary. On the other hand the question he put forward of the possibility of establishing a ‘Journal of Corresponding Societies’ was obviously one on which there were many differences of opinion ; but in any case, it must be remembered that the Conference could take no action without the Council of the Association. The Chairman thought it was inadvisable to put things off until next year, because it would be very difficult to get anything like the ordinary business done then, and unless he had submitted a recommendation to the Committee of Recommenda- tions before its meeting yesterday, all opportunity of doing anything would have been practically lost for the next two years. Therefore, on his own responsibility—and he stated at the time that it was on his own responsibility—he handed in a notice to go on the agenda paper of the Committee of Recommendations to the following effect :— ‘That a Committee be appointed, consisting of members of the Council of the Association, together with representatives of the Corre- sponding Societies, to consider the present relation between the British Association and local Scientific Societies. ‘That the Committee be empowered to make suggestions to the Council with a view to the greater utilisation of the connection between the Association and the affiliated Societies, and the extension of affiliation to other Societies which are at present excluded under Regulation JI.’ It would greatly strengthen his hands in the Committee to which he was then going if the Delegates would empower him to say that they supported the resolution. Of course it would commit the Delegates to nothing, because it was only asking for a committee to inquire into the whole matter, and unless this action were taken immediately nothing practically could be done for two years. He therefore asked the Delegates to intimate, unless they had any opposition to offer, by a show of hands that he had their authority to present this resolution. The resolution was carried unanimously and with applause. The Chairman then said that if this were agreed to by the Com- mittee of Recommendations it would be necessary for the Delegates to appoint representatives to meet the members of the Council in this 394 REPORT—1904. matter. Therefore he would ask the Delegates that afternoon to pass a formal resolution that, if this resolution were adopted by the General Committee, certain persons be appointed as representatives of the Delegates upon that Committee. It would be for that meeting to suggest the names. He suggested that they should not appoint too many, and that they should be such as would be fairly certain to attend the meetings. After a hearty vote of thanks had been passed to the Chairman for the action he had taken, he vacated the chair in favour of Dr. Tempest Anderson. It was unanimously resolved that, if the resolution referred to were passed by the General Committee, the following Delegates be appointed as representatives of the Corresponding Societies on the proposed Com- mittee—namely, the Chairman of the Conference of Delegates, Principal E. H. Griffiths ; the Chairman of the Corresponding Societies Committee, Mr. W. Whitaker ; and the Secretary of the Committee and of the Con- ference, Mr. F. W. Rudler. Mr. John Hopkinson, F.L.S., F.G.8., introduced the following subject :— On the Conformity of the Publications of Scientific Societies with certain Bibliographical Requirements. A few years ago I suggested for discussion at our Conference the subject of Dew-ponds ; and although we had a very interesting discussion upon them I heard it remarked that it was scarcely of sufficient general interest to the Corresponding Societies. The subject of my remarks on the present occasion should be of interest to all our Societies, and it is an eminently practical one ; but I must confess that it is drier than Dew-ponds are, or should be. I will introduce it by giving a recent experience of my own, chiefly as an illustration of the requirement that the title of a paper should give as clear an idea of its contents as can be given in a few words. IT am compiling, for a work to be published by the Ray Society, a Bibliography of the Freshwater Rhizopoda. I knew that in the ‘Monthly Microscopical Journal,’ for ten years the organ of the Royal Micro- scopical Society, there was a paper on a presumed freshwater rhizopod from the New Forest to which the name Pseudo ameba violacea had been given, but I could not remember the title of the paper or the author’s name. I searched the indexes to twenty volumes under the catch-words ‘ Protozoa,’ ‘ Rhizopoda,’ ‘ Pseudo-ameba,’ ‘ Freshwater,’ and ‘ New Forest.’ Under not one of these could I find a reference to the paper, and it was only by turning over the pages that the plate illustrat- ing it caught my eye in vol.x. The paper is by Dr. R. L. Maddox, and its title is ‘On an Organism found in Fresh-pond Water.’ It is indexed only under ‘ Maddox’ and ‘Organism.’ There are three faults here to which I wish to draw your attention. One is the absence of a table of contents and of a list of the plates. Such a table is, or should be, very much shorter than an index, and it enables a paper on any particular subject to be found much more readily than by the index. Another is the meagre indexing ; and the third is the unsatisfactory title of the paper. The newly-proposed genus does not appear in either title or index, there is no indication of the kind of organism—believed to be CORRESPONDING SOCIETIES. 395 a rhizopod—nor of the locality in which it was found. ‘The title should have been something like this ; ‘On Pseudo-ameba violacea, a presumed new Freshwater Rhizopod from the New Forest,’ and the principal words in this title, at least, should have been indexed. I need scarcely explain how all who write similar papers, and all editors of the publications of Scientific Societies, may apply this criti- cism and relieve the labours of others, especially of compilers of biblio- graphies. I have examined the bound volumes of most of your publications at the Office of the Association, and I find that the majority have the very serious fault that the date of publication of the several numbers, or parts, of which they are composed, is not given. The dates may have been, and probably in most cases were, on the covers ; but the covers are not bound up in the volumes, as they ought to have been—the first leaf at least— which would give date and contents, and should preferably be bound at the end of each volume. When the dates are not given in the bound volume it is impossible to ascertain when any particular paper was pub- lished, and therefore impossible to enter it in a bibliography as it should be entered. This may be of great importance in questions of priority. The month and year of issue of each separate part of which the volume consists, with the number of the first and last page in each part, should always be printed after the title-page or table of contents and list of plates ; thus, for example— Part I., pp. 1-18 . = . : . + October 1904. 4 EL9;, 492805 ix=xvi = 4 : . January 1905. This might obviate the necessity, if not the advisability, of binding the covers. A volume sometimes appears without an index, more often without a table of contents and a list of the plates or other illustrations. Occasion- ally the index is placed at the beginning of the volume; it should always be at the cnd. In one case at least a table of contenis is called an index ; in another that abomination, a collection of separate indexes, is called ‘indices,’ a term which should be restricted to its mathematical signification. A frequent fault is the separate pagination of a thin publication, usually called ‘ Annual Report and Proceedings,’ or ‘Annual Report and Transactions,’ the first part of which titles is superfluous. When, say, ten of these, of perhaps thirty pages or so each, are bound together to form a volume, how difficult it is to ascertain their contents, how difficult it would be to satisfactorily index the volume! Much rarer is the fault of making a volume so thick that it has to be bound in two. Occasionally the name of an author is given thus: ‘Mr. Myth read the following Paper on Sea-serpents.’ Initials should always be given. Occasionally the name of an author is omitted altogether. This is the case with an annual meteorological report which appears in a very useful publication called a ‘ Record of Bare Facts,’ issued by an energetic Corre- sponding Society, Now a few words about reprints. I receive one. It is paged 1 to 4. It is stated, on the cover only, to be from the proceedings of a certain Society, neither volume nor date being given. I wish to enter it in a bibliographical list. Reference to the publication from which it is reprinted is absolutely necessary. I cannot find it in any London library. 396 REPORT—1904. Eventually I get the required information from the Secretary of the Society. The reprint has not only been re-paged, but the position of the type on the pages has been altered so as to get into four pages a paper running into five—a great temptation certainly. But in all reprints, except perhaps reports of proceedings which would never have to be entered in a bibliography, the original pagination should be retained, and the title of the publication, the volume, and the date —month and year— should be printed on the paper, as well as on the cover, so that it remains if the cover be taken off, as for binding. There is one other point I should like to impress upon you. Your proceedings should be published ; that is, it should be possible to purchase them. They are then amenable to the copyright laws ; copies have to be presented to five libraries—one in London, one in Oxford, one in Cam- bridge, one in Edinburgh, and one in Dublin. That in London is the British Museum Library ; and even if you only print and do not publish your proceedings, a copy should be sent there. This is a point I cannot too strongly urge. We possess, at the Office of the Association, a very valuable and unique collection of the Proceedings of the Corresponding Societies. I hope that it will in future be kept intact, and that by more extensive and convenient premises being acquired by the Association it may be possible to improve its arrangement and make it more accessible than it is at present, and I also think that an effort should be made to get replaced certain publications which some years ago were lent and lost, so that every paper catalogued in the Reports of the Association may be readily referred to, for some of them are not now to be found in London, not even in the library of our greatest national institution, the British Museum. Mr. W. Whitaker said he should like to support what Mr. Hopkinson had stated. The speaker had wasted much time in trying to find where a paper came from in order that he might be able to quote it properly, and in many instances he had taken his separate copy to a library where the journal existed and collated it himself with the original. When one has to republish a paper it is inconceivably inconvenient to shift the type, as printers will do. Societies and editors of papers should make printers understand that they cannot do as they like in these matters. Mr. Hopkinson spoke of the Library of the British Museum. Not long ago the speaker sent some annual reports of a provincial Society to the British Museum and they were returned! They were not entered at Stationers’ Hall, and were not wanted at the Museum. The Library is so full that little things formerly received cannot be accepted now. The Rey. T. R. R. Stebbing thought that if sent tothe British Museum at South Kensington they would be received most gratefully. Mr. Whitaker observed that that is a different thing. He thought the Trustees of the future would very much regret the action of the Trustees of the present, because these thin pamphlets become so difficult to get hold of in years to come. He hoped the Delegates would notice what Mr. Hopkinson had said, and try to get the Societies to adopt some kind of system in editing. There is an opinion about that anyone can edit a journal. That is the greatest mistake possible. It requires a good deal of technical knowledge. A man can be a good writer and good reader, and yet make the worst possible editor. He had told several Societies of these defects and they had been remedied. It is for the CORRESPONDING SOCIETIES. 397 good of the Societies that the Delegates should try to get their journals printed in a regular orthodox fashion, with contents in front and index at the end. And do not go re-paging from No. 1 every single yearly issue. A Society which he had represented had committed this error for the last four years, and had occasioned him much inconvenience. The parts should be paged continuously, so that they may form a much more dignified kind of volume. When each part is paged separately, the only thing to be done is to put, in binding them, a stiff piece of coloured paper between each number and the next, otherwise it takes a long time to find any particular part. Mr. T. W. Shore (Hampshire Field Club) said that as one who worked a good deal in the British Museum he thought they might do a little more than Mr, Whitaker had suggested. He had not had any experience of the publication of pamphlets, but he did know the extreme use of them, having been for some eight years a constant worker in the reading-room. He thought that the Delegates, as a Conference, might represent to the authorities of the British Museum that they were losing some out-of-the- way information of a very valuable kind in some of the Societies’ publications ; and might ask them to reconsider their position, and to receive the publications, however small, of any Society. The Rev. T. R. R. Stebbing said that his own experience was that the Museum had not got room for its books and pamphlets, and did not care for any more. Moreover, if these pamphlets are filed there, you have to wait perhaps half or three-quarters of an hour before you get what you want. But if you go to the British Museum at South Kensington, and apply to the Librarian there, you probably get whatever you want in two or three minutes. The speaker knew that instead of rejecting pamphlets and reports and transactions every possible trouble was taken at Kensington to collect them. They are there all brought together in a small compass ; but if they go to Bloomsbury the messenger may have to travel miles before he alights upon what is wanted. There was one point he thought Mr. Hopkinson intended to insist upon, and that was the form of reports and transactions. It is extremely incon- venient to have different sizes. You do not know how to bind them up. He believed that the Royal Society itself was going to change the form of its proceedings, and he thought if our Societies were to apply in a modest way to the large London Societies for advice as to the form it is best to adopt, a uniform size might be adopted which would be a very considerable advantage for our book-shelves. Dr. G. Abbott inquired to what extent the Library of the British Association was used. He was suspicious that really the volumes sent there would be very much more appreciated if they were sent to South Kensington. Perhaps, however, both could be supplied. Mr, J. F. Tocher (Buchan Field Club) remarked that he had listened with great pleasure to Mr. Hopkinson’s paper, and thought that an en- deavour should be made to carry out some of his suggestions. As editor of the transactions of a Corresponding Society, he had felt guilty as to one or two points with regard to the publication. In his Society they did not put the number of the volume upon reprints. Otherwise he thought the Buchan Field Club attended to most of the points that were brought out. So far as the form of the transactions was concerned, he thought they would experience some difficulty with the Corresponding Societies. In the North of Scotland they had at least half a dozen Societies and half 3898 REPORT—1904. a dozen different forms of transactions. He thought there would be great difficulty in getting Societies to agree to any particular form unless the British Association gave them a definite standard form in which to publish their transactions. The Vice-Chairman (Dr. Tempest Anderson) said that the size of publications was one of the most pressing importance. He had been getting a considerable quantity of literature on the Martinique eruptions. The variety of sizes of these publications was heartrending. It was almost impossible to find anything approaching uniformity. When you take the magazine articles it is astonishing how much more uniformity prevails. Here, said the speaker, is the ‘Geographical Journal.’ That is probably one of the best sizes, but it is about half an inch too narrow. The corresponding journal in America is half an inch wider, and is able to have really good plates put in. The Journal of the Geographical Society cramps the size, and in these days of photography the extra half- inch improves the scale wonderfully. However, though the Royal Society, for instance, were to recommend all the other Societies to adopt uniformity, it is certain we should never get the public at large to press for an aiteration in the size of their favourite magazines. He thought the size of the ‘Century’ was about the average size of the magazines, and it would be very much better if all magazines were to keep to that size. As it is practically impossible to get the magazines to change their form, he con- sidered it would be a good thing if Societies would adopt the average size of the magazines and keep to it. He complained that the two Guide- books for the British Association meeting were each of a different size. Then the excursion programmes, which one would like to bind up as souvenirs of this meeting, were yet again of a different size. Mr. Hopkinson, in reply, said he had purposely excluded all reference to the size of publications, because that had been thoroughly discussed some years ago by a very influential committee, whose Report was presented at the Ipswich Meeting of the British Association in 1895 (p. 77), Demy octavo (83 inches by 52 inches) or demy quarto (11} inches by 87 inches) was the size recommended by the Committee. The smaller size was that of the British Association Reports and of the publications of a very large number of other Societies. Mr. Stebbing rather thought that public opinion had considerably changed since the date of this Report, and that a larger size was now wanted. Mr. Hopkinson said that it had at all events been decided as the standard size of the British Association, and he did not think it would be of any use to discuss the subject further. | With regard, however, to sending the proceedings of Societies to the British Museum, he remarked that every- thing published in this country ought to be sent there—to the National Library—for in order to consult books we did not want to go to South Kensington, which is miles away. He admitted that Mr. B. B. Wood- ward had done excellent work in endeavouring to get the whole of the publications of the Societies, and he hoped that the Delegates would send their publications there also; but still they must not omit the British Museum in Bloomsbury. Mr. Hopkinson proceeded to refér to the assist- ance he had received from the Library Catalogue of the Natural History Museum in his search for information which he had been unable to obtain at the British Museum owing to the latter having neglected to bind the covers of a book issued in parts, and he urged the importance of ~~ nn CORRESPONDING SOCIETIES. 399 binding the covers of scientific magazines to preserve the lists of contents as well as the dates of issue. He regretted to find that the British Museum, instead of binding the first cover of each number had lately only bound the cover of the first part and the last part, usually the one in January and the other in December. The only other point Mr. Hopkinson wished to draw attention to was this, that the Office of the British Association was, after all, the best place at which the transactions of the Corresponding Societies could be kept. Every year the titles of a selected list of papers from these transactions are published in the Report of the British Association, and if anyone wants to refer to a paper in that list he knows at once where it can be seen—at the Office of the Association. Therefore he thought it was most important that the publications should be kept there, where they are bound and carefully preserved, the cost of binding them being defrayed out of the annual grant to the Corresponding Societies Committee. The Reports of the Delegates from the various Sections were then received. Dr. H. R. Mill, representing Section A, explained that this Section was composed this year, as it had been for some time past, of two Sub- sections. ‘The Conference of Delegates naturally came more immediately - into contact with the Sub-section called, for want of a better name, Cosmical Physics, and the Committee of that Section desired him to convey to the Delegates their feeling of the value of the work that had been done by the Corresponding Societies. Although there was no specific question to be laid by the Section before the Delegates, the repre- sentative was given a free hand to make any remarks he considered appropriate to the occasion. He would refer only to meteorological observations. A number of the Societies represented there, notably those with which Mr. Hopkinson and Mr. Whitaker were connected, had given a great deal of attention to this question of meteorology, and had pub- lished each year a most admirable meteorological report of the areas they dealt with. A number of other Societies dealt with the same subject nearly as completely, and others in a more fragmentary fashion, but there was room for a great deal of improvement. The Royal Meteorological Society was endeavouring to improve the position of this country in this respect, to increase the interest in observation, and to direct it sys- tematically. They had sent outa circular in which four questions were put to the Fellows of the Society. When these were brought before the local Societies the speaker trusted that the Delegates would reinforce the action of the Fellows of the Royal Meteorological Society who approached them, and would at any rate discuss the matter. If they needed any information on the subject they should refer either to the Assistant-Secretary, Mr. Marriott, to the speaker, or to any of the officials of the Society, and that information would be furnished. He hoped on a future occasion it might be possible to make more definite suggestions than at present. The subject was one of great interest. The observations were easily made, and when brought together could be put to excellent scientific use. Mr. Whitaker (Section C) explained that it was the joint desire of the Geographical and Geological Sections to get a Committee appointed to determine and record the exact significance of local terms applied to topographical and geographical objects. All members of the Correspond- ing Societies must meet with such terms, and the Delegates are naturally 4.00 REPORT—1904. the very people to help in this matter. They should record these words and send them up to the Secretary of the Committee or to the Secretary of the British Association, As an example, Mr. Whitaker said that when he was working in the neighbourhood of Southampton there was one term that he heard confined to a little district round Southampton ; a term applied to the bleached top of a gravel, which was known there as ‘skyone.’ Howit is spelt and what it is derived from he had not the least idea ; but the name had a definite meaning there,and an economic mean- ing, because that particular sort of gravel was used for a particular object. It was interesting and ought to be recorded. Every one of the Delegates would find in their own districts some such terms, sometimes spread over a county, sometimes over a small district, sometimes over three or four counties, and it would be desirable to get at what they really meant and how they had been derived. He thought it would be interesting not only to geographers and geologists, but to students of folklore and similar subjects. The Rev. T. R. R. Stebbing explained that Section D had appointed a Sub-Committee, which eventually drew up the following report :— ‘ August 22, 1904. ‘A meeting of the Sub-Committee appointed to prepare a reply to a letter from Mr. Rudler was held to-day. Messrs. Stebbing, Knubley, and Bles were present. ‘It appears that several subjects for work by local Societies have been proposed to the Conference of Delegates of Corresponding Societies by representatives of Section D at former meetings without producing any substantial results. ‘Four subjects suggested already are : ‘1. Cave faunas : report to Rev. T. R. R. Stebbing, Ephraim Lodge, The Common, Tunbridge Wells. ‘2. Zoological changes on a given plot of land during the year: report to Professor Miall, The University, Leeds. ‘3. Compilation of local faunas. A complete working scheme has been prepared, and is actually in operation in some localities. For par- ticulars of schedules, &c., apply to Mr. Edward J. Bles, The University, Glasgow. ‘4, Systematic observations on the micro-organisms of a given pond or ditch : report to Professor West, Agricultural College, Cirencester. ‘In addition to the above the Sub-Committee suggest the two following subjects : ‘5. Overland lines of migration of birds: report to Rev. E. P. Knubley, Steeple Ashton Vicarage, Trowbridge. ‘6. Collection of slugs from all parts of the British Isles: apply for information to Mr. W. Denison Roebuck, Hyde Park Road, Leeds.’ Mr. Stebbing mentioned, in conclusion, that he would be much indebted to any member who lived in the neighbourhood of caves through which there might be flowing streams if they would let him have some information concerning the same and the fauna, and if there happened to be crustaceans he would like to have specimens. Dr. Herbertson (Section E) said that after Mr. Whitaker’s clear state- ment little remained for him to add to the request that the Corresponding CORRESPONDING SOCIETIES. 401 Societies should send to the Joint Committee of Section E and Section C information as to the local names of geographical and topographical forms. But there was one other point he should like to bring before the members of the Corresponding Societies, and that was the desirability of sending to the Royal Geographical Society reports and copies of any of their publi- cations which contained papers dealing with questions of distribution, so that these might be noticed in the Bibliography of Geography which is prepared by the Librarian of the Society. Extracts of some of the papers might then appear in the Monthly Notes, and thus be communicated to the geographers of this country. Miss Ethel Sargant said that she was not the representative of Section K, but Mr. Stebbing had asked her to report as to the information she had received with regard to orchids in reply to the appeal which had been made on a former occasion. The only communication she had received was from a Tunbridge Wells member. She had also, after many inquiries, got a little information with regard to the leaves of orchids ; but none about the seedlings, respecting which information had been also solicited. The Rev. J. O. Bevan moved a vote of thanks to the Master and Fellows of Gonville and Caius College for the services they had rendered to the Conference by enabling them to meet in that interesting room and allowing them likewise to gather in the small library, which some of them had taken advantage of. There were various reasons why they should give that vote ; one was that the College had introduced them to the information that Humility and Virtue lead to Honour. Mr. Hembry cordially seconded the vote, and the motion was carried with enthusiasm. The Rev. T. R. R. Stebbing moved, and Mr. Hopkinson seconded, a vote of thanks to the Chairman, which was carried with applause and briefly acknowledged. 1904. DD 1904. 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Se ee 1 ee o* *Aypenuue “q.10dey “ATUUOUL .“4SI[BAINgVN OL » {Ayenuue ‘suomoesuvty, -Aypenuue ‘ssurpeeoorg “A][BIUUEIq ‘SMOTZOVSUBIY, ATTeNUUes ‘ss atpedoo1g “Alyenuue ‘Teurno pr “AyTTenuue ‘suoovsuv1y, “ATQQUoUL ‘saeoulsug 4=SurUIyy ~=jo UOIIN4I4SU] JO SUOTJOVsUBLy, “a,>... >ay; and let the roots of ec— =0 be + ty,, £7 «+ +9 E Mp, Wherey,>yo> +--+.» >yYp>O0. Then the veal part of any root of a~d =0 hes between a, and a,; and the absolute value of the imaginary part is not greater than y,. The first part of this theorem is due to Bendixson;' the second seems to be new. Hitherto all the letters a, , have been taken to be real; if they are complex a modification of the theorem is necessary. Let the accented letter a’,,, represent the conjugate complex to a,,,. Then write by c= Gy, gt Cs, 5), Ch e—a(Gr,s—Os »); so that the matrices 6, c have the property expressed by the equations hs SU ESS oe Tt is known that the two equations in A, \b-—rA =0, e~rA =0, have real roots in consequence of the property just stated: denote these roots by By, Boy « « «y Bn ANd yy Yoy « + +» Yn TeSpectively, and suppose them again arranged in order of magnitude. Then the equation a—\ =0 has the property that the real ' Ofversigt af K. Vet. Akad. Férh. Stockholm, 1900; Acta Mathematica, t. 25, 1902, p. 359, TRANSACTIONS OF SECTION A. 441 part of any root lies between B, and Bn, and the absolute value of the imaginary part hes between y, and yn. The first part of this theorem is due to Hirsch,' but the second seems new. I have attempted also to obtain some connection between the invariant factors of the determinant |~—A! and those of? |b—Ac|, but hitherto without success. I have constructed, however, certain examples which show that the connection (if there is one) cannot be obtained by any very simple method, 5. On the Zeroes of Two Classes of Taylor Series. By G. H. Harpy. The problem of obtaining reasonably precise information as to the nature of the zeroes of an integral function defined by a Taylor series is one which may fairly be said to be generally impracticable, at any rate with the analytical machinery at present at our disposal. The utmost which has been accomplished in this direction is the determination of certain limits for the increase (crozssance) of the moduli of the zeroes when corresponding limits for the increase of the coefficients are given, these limits being found by the determination, as a pre- liminary step, of limits for the increase of the function itself. For this reason it seems to me that the results proved in this paper may be of interest to those who are engaged in the study of the general theory of integral functions, They are essentially results concerning particular cases, but they are very much more precise than any results so far furnished by any of the general theorems. Of the two classes of functions dealt with, the second is perhaps the more interesting in itself. On the other hand, the determination of the zeroes of the first class seems of more theoretical interest, as being effected directly from the Taylor series, whereas in dealing with the second class a preliminary transformation of the series into the more easily manipulated form of a definite integral seems to be essential. A. Functions formed by selecting terms from the exponential serties.—The general form of such functions is X APY AO) pp pies ae ACO where (7) is a positive and continually increasing function which is integral for all integral values of x. It is easy to see that (in the ordinary notation) all such functions satisfy the inequalities Ke" |/r SM (r) Se". Moreover, if the increase of (x) is regular and sufficiently rapid, the nature of the zeroes associated with the essential singularity at infinity may be determined with much precision. The essence of the proof is to determine a series of circles on each of which the behaviour of f(A) is completely dominated by that of one term. Suppose, e.7.,° p(z)=n*. Then it can be proved that if As | (N°)! ia where |e. as Hence it follows that, round the circle 7 = N°, 1 Acta Mathematica, |.c., p. 367. ? Since the invariant factors of |/—A| and |¢—A| are known to be linear, it seems quite hopeless to make any connection between these and 'a—A\, * The increase of ~(”) =n? is not quite rapid enough, | ’ r=N3, N7N, fO)= Dt ea) 442 REPORT—1904. and from this it is an immediate consequence that the number of zeroes inside the circle is exactly N°’, Again, between the circles r = N? and r=(N +1)? de f(r) = anit +6) + wen +e). The 3N?+5N +1 zeroes which lie between the circles are given by the formula AN+ r=N? + = NP Pies = ee). 3N?+3N+1 (4=0,1,...8N?+3N), p being very small. A more precise approximation to r would not be difficult, but seems superfluous, The analysis is practically the same for more general forms of (mn), and may be applied to other functions of the forms Sy” > ve ip(m)} {p() 39’ &e. B. The function fae, New oe Si(np + lyn! Concerning this function I have arrived at the following results :— i. If p and a are positive, and a region, D, of the plane be defined by the inequalities —or< as es 6,< an, then A Sa p NY = Gay"! +€), where e, is a function of A, which tends uniformly to zero when A tends to along any path inside D, and \~* is real on the real axis. ii. If D’ is the image of D in the imaginary axis Dispos ly f(a, p, 4) = —P*(—A) pf{log (—A)}*-“(1 +.) PT 1 in D’, (—d)? and {log (—X)}*-1 being real on the (negative) real axis. ill, Ifp and a are positive and a integral the zeroes of f(a, p,X) which lie above the real axis tend to the points far i EG (« ey) log (2hm) + (a—1) log log & 1 4 = + log Gs [ (2x sti NM oh 37 («+ 5) |, where / is a large positive integer. iv. If, on the other hand, a is zero or a negative integer f(a, p, d) has but a finite number of zeroes, which are all real and negative, reducing in fact to the product of e* by a polynomial. I have no doubt that the restriction introduced in li. that a is integral is quite unnecessary, and that the formula holds for all real values of a save negative integral values, with a slight modification when a is negative. But I have not been able to prove this rigorously. The function ao — rn = nn! TRANSACTIONS OF SECTION A. 443 may be treated similarly, and so may other functions formed from the sine-function as f(a, p,) is from the exponential function. Among various generalisations which may be made I may mention the following :— If ©(u) is real and continuous throughout (0,1), the zeroes of the integral function 1 1 1 : | Ou” @(u)du (p>), Py which lie above the real axis, tend to the points fi) log (Qk) + log (=) + log at +i[ Qk +1)0 +37(1 +)|. 6. Binary Canon Extension. By Lieut.-Col, ALLAN CunnincuaM, FF, The author has prepared a table showing the least Residues (R), both + and — of the powers of 2 (say of 2°), for all prime moduli (p), and also for all power of prime moduli (p*), up to p or p* > 10,000; the range of « is from « ¢{ the modulus up to 2 = 70. Thus it gives at sight the factors > 10,000 of (2*+ R), and of (2"+2*-* + 1) up to x = 70 (when Ris small), With some subsidiary work many other forms may be factorised, various congruences may be solved, and the Haupt-exponents (€) of small bases (a@) may be found, ze. the least values (€) giving af = + 1 (mod p or p*). This table is an extension of the author’s Binary Canon (published in 1900) which extended only to moduli > 1000. 7. On the Theory of Transfinite Numbers. By Dr. BE. W. Hosson, FAS. FRIDAY, AUGUST 19. SUB-SECTION oF ASTRONOMY AND CosmicaL Prysics. CHATRMAN—SriR Joun Extor, K.C.LE., M.A., F.R.S. The Chairman delivered the following Address :— When the suggestion was made to me that I should preside over this important sub-Section my first thoughts prompted me to decline the honour. The position had been filled during the past two years by two distinguished physicists, both of whom had dealt chiefly with the problems and the position of meteorological science, and hence I thought that it should be offered to some representative of cosmical physics. I also doubted whether an official meteorologist whose time has been chiefly given up to duties of administration could have anything of interest to communicate to you. However, on fuiler consideration it occurred to me that I might be able to place before you some features of Indian meteorology leading up to and assigning, as I hope, adequate reasons for the study of a portion of the field of tropical meteorology as a whole. My Address consists of three parts, viz. :— 1. A brief sketch of the broad features of the meteorology of India in their relations to the general meteorology of the Indo-oceanic region. 44,4, REPORT—1904. 2. Statement of abnormal features of the meteorology of that area for the unique period 1892-1902 illustrating the remarks in the preceding sketch. 3. Suggestion of the co-ordination of the meteorological observations of the British Empire and the creation of a central office for the investigation of problems of general meteorology. India is the most typical example of monsoon conditions, that is, of opposite air movementsof six-monthly period which, in its case, depend on the annual temperature changes in the sea and land areas of the Indian Ocean and continent of Asia. The monsoon conditions in India are intensified by its unique position and topography. It projects southwards into the Indian seas over 15° of latitude, and is protected northwards by the vast barrier of the Himalaya Mountain range and Thibetan plateau. The axis of the Himalayan range is at least 2,000 miles in length and has an average elevation of over 20,000 feet. ‘The extent of country over 10,000 feet in elevation to the north of India is from 300 to 500 miles in width. These figures will give some idea of the magnitude of India’s northern barrier. During one period of the year there is an outflow in the lower atmosphere from land to sea. The direction of the lower air drift in India is determined in part by the lie of the mountains and river valleys, and is from north-east over the greater part of the Indian seas. January is the month most typical of this air movement and of the accompanying weather conditions. During another portion of the year the lower horizontal air movement is from sea to land. This movement is much steadier and more powerful and influential in every respect than the former. July and August are the months most repre- sentative of the totality of the weather conditions of this period, Conditions similar to those of January prevail in their entirety from about the middle of December to the end of February or middle of March—the period known in India as the cold weather or cool season. The lower horizontal air movement in India during the period has its origin in Upper India, where it is very feeble, and whence it increases seawards and is of moderate force in the Bay of Bengal (mean force 2 to 3, Beaufort scale) and the Arabian Sea (mean, 2 to 4). It is fed to acertain extent by drift down the river valleys, and passes in the North-west India frontier hill ranges. There is, on the other hand, no general drift down the Himalayan river valleys or across the main ranges from Central Asia, The normal air movement in the Western Himalayas (and perhaps the whole range) is an alternating up and down, or day-and-night movement, depending upon the diurnal heating and cooling of the plains of Northern India, Hence India (in its lower air movement) is at this time completely shut off from Central Asia. The lower air movement is continued over the Indian seas southwards to a region of vertical movement over a narrow belt a little to the south of the equator. This belt is also the goal of the lower air movement of the south-east trades circulation at this time. The equatorial belt of calms is hence the termination of the lower air movement of the south-east trades and north-east monsoon. It is chiefly an area of uptake, and of outflow northwards and southwards, to replace the lower air in flow from the distant south and north. The influx to the Indian land area occurs chiefly or entirely in the upper and (perhaps) middle atmosphere. There is also, as indicated by the wind directions in the lower Assam and Burma hills, an influx from the adjacent seas in the upper portion of the lower atmosphere.' The diurnal land and sea breezes alternate with great regularity on the west coast south of Gujarat during this period, but probably do not contri- bute to the general upper influx compensating in part or whole the lower outflow. The circulation over the Indo-oceanic region hence consists at this time of two semi-independent circulations, with a common sink or goal for the lower air movement, which shifts with the season and with the relative strengths of the two movements. It is hence probable that they react on each other to some extent, and possible that general abnormal actions may affect the two similarly. ' In India the lower atmosphere may be defined as from 0 to 5,000 feet, the middle atmosphere from 5,000 to 15,000 or 20,000 feet, and the upper atmosphere above 20,000 feet, TRANSACTIONS OF SECTION A. 445 The normal weather during the period is similar to that which obtains in anti- cyclonic periods during the summer in Central Europe—viz., the prevalence of light winds, with clear or lightly clouded skies, low humidity, moderate temperature, and large diurnal range of temperature, with a bracing, exhilarating atmosphere. It is interesting to note that the air movement in India itself is from opposite directions in Northern India and the peninsula, with a belt of unsteady movement over the area of the Vindhya and Satpura hill ranges. The variations of weather conditions from the normal are as a rule inverse in these two regions—viz., Extra- tropical and Tropical India. The season of the opposite air movement is present in its most complete form in July and August, and lasts from the beginning or middle of June to the middle or end of September. It commences as a lower air movement in an anticyclonic region overthe South Indian Ocean, and is thence continued northwards to Abyssinia, South Arabia, India, and Burma. Persia, Afghanistan, and Baluchistan (where dry hot north-west winds chiefly prevail) are outside the field of this movement. ~The direction of the movement is from south, with more or less easting to the south of the equator, and with more or less westing to the north of the equator, dependent in part upon the earth’s rotation and in part upon local conditions and the influence of neighbouring land areas, and hence more effective in the Bay of Bengal than in the Arabian Sea. ‘This lower air current advances over an extensive tropical oceanic region before it reaches Southern Asia, and hence arrives charged with vast stores of aqueous vapour, which it discharges chiefly over the peninsulas of Southern Asia and the mountain region of Abyssinia. The regions of rainfall indicate the areas of upward movement terminating the lower advance of the current. The circulation is undoubtedly maintained in large part by the release or addition of energy due to the condensation of its enormous stores of aqueous vapour. The lower air movement is of very considerable eleva- tion, estimated at 15,000 to 20,000 feet in India. Above it is the outward upper return movement, in part only compensatory, and in part probably slowly filling up the Central and Southern Asian low-pressure region. The movement exhibits some interesting features in India, due to the fact that of the three areas to which it is mainly determined India alone is subject to a double influx from two sea areas in opposite directions. The current from the Arabian Sea passes eastwards across the Malabar, Konkan, and North Bombay coasts, the peninsula and Central India. The Bengal current is deflected in the north of the Bay of Bengal, and advances in a westerly direction up the Gangetic plain. Between the areas or fields of the two currents (roughly proportional to their relative strength and importance—viz., about 2 to 1) is a debatable area of variable winds and low pressure. This trough of low pressure varies in position with the relative strengths of the two currents. The cyclonic storms of the period, which are of comparatively frequent occurrence, advance along the trough. Tt is hence a factor of considerable importance in determining the distribution of the rainfall of the period. The trough is purely a resultant of the peculiar con- ditions of the air movement, and is not in cause of that movement; in other words, it is determined by it, and does not determine it. The transformation of the double circulation of the north-east monsoon period into the single circulation of the south-west monsoon over the Indo-oceanic region next requires consideration. It is evident that the chief stages in this change are (1) the discontinuance of the vertical movement over the equatorial belt ; (2) the extension of the trade winds of the south-east trades across the equatorial belt, with an accompanying increase of pressure and of horizontal air movement ; (3) the continuance of that northerly movement over the Indian seas into the peninsulas of Southern Asia. The marine data of the Indian seas collected during the past fifteen years establish fully that this transformation is primarily due to actions in the Indian Ocean, producing a movement resembling in many respects that of a bore or storm wave. The actual transition may hence be described as catastrophic, due to impulsive action. It is preceded in India by a period of preparation (as it may be termed), when 44.6- REPORT—1904. pressure and other conditions are slowly established in Southern Asia, which directly contribute to the advance of the monsoon winds over the Indian seas, but which in no way assist the preliminary burst across the equator, the first stage towards the establishment of the south-west monsoon circulation. This preliminary period is the hot-weather season, lasting from about the middle of March to the middle of June (on the average in Northern India), During this period temperature increases rapidly until the last week in May or first week of June, when maximum day temperatures ranging between 120° and 125° are usually recorded in the driest and hottest interior districts of Northern and Central India. Pressure decreases part passu in the heated land areas of Southern Asia, which become areas of low pressure and indraught relative to the neighbouring seas. The indraught only extends to a comparatively short distance landwards and seawards from the coasts, more especially in the larger sea area, the Arabian Sea, over the centre of which light variable or northerly winds obtain even immediately before the advance of the monsoon currents. In the interior of Northern and in Central India exceedingly dry and hot westerly winds prevail with great steadiness. The weather in India during this period depends almost entirely upon local thermal actions and contrasts of temperature and humidity conditions. Skies are generally free from cloud, but the air is more or less charged with dust and is excessively dry (humidities of 1 to 5 being of occasional occurrence in North- western India). The characteristic features of the dry season are hence most strikingly exhibited immediately before the advent of the wet monsoon. There is no gradual change over the greater part of India from one to the other such as would occur if the furnace, or Central Asia hot area, theory were correct. Over small isolated portions of India, including Tenasserim, Arakan, Lower Burma, Assam, Bengal, and Malabar, thunderstorms giving more or less heavy downpours occur in increasing frequency during the period. The rainfall is considerable to large in amount in these areas, and is of much agricultural value in some districts—e.g., in Assam for the tea crop. In those areas the transition to the rainy season is much less abrupt and spasmodic, the chief differences being that the rainfall in the wet season is more general and frequent, larger in amount, and rarely accompanies thunderstorms. The transformation from the hot weather to the rains is usually effected between the 1st and 15th of June. It commences in the equatorial belt with a consider- able increase of pressure and air movement accompanying a strong rush of southerly winds, the continuation of south-east trade winds, across the equator. If the burst be sufficiently strong the rush is continued northwards over the Indian seas as a wave of disturbance, squally weather, heavy rain, and much violent electric discharge or action, invading areas characterised previously by light and variable winds and fine weather. The disturbance usually increases with its northward advance, and frequently, when it reaches lat. 12° to 16° N., it concentrates into a cyclonic storm. Such a storm almost invariably marks the commencement of the monsoon in the Bay of Bengal, and in about two out of five years in the Arabian Sea. The advancing humid currents in the rear of these initial cyclonic storms or waves of disturbance march over the sea areas in a few days, and thence cross the coasts towards which they are determined by the low- pressure regions in the land areas of Southern Asia, where they produce an almost complete reversal or transformation of the weather conditions, the result of which is that moderately high temperature and small diurnal range of temperature, great humidity frequently approaching saturation, much cloud, and frequent rain obtain for the next three months over the greater part of India, until, in fact, the middle or end of September. The reverse change—viz., the withdrawal of the humid south-west currents— then commences, and is a slow process, requiring usually from two to three months for its completion. This is due to a gradual decrease of strength, and hence to a fairly continuous contraction of the field of the current, and also of its elevation or thickness. The TRANSACTIONS OF SECTION A. 447 current first withdraws from North-Western India, being replaced by light, variable, or north-westerly land winds. These land winds increase in extension and volume with the continued contraction of the south-west monsoon current. The more important phases of the contraction and withdrawal of that circulation from India are of especial interest. The first phase, the retreat of the current from North-Western India, accompanies a rise of pressure over the Persian area and North- Western India, with a shift of the trough of low pressure from W.N.W. to N. or N.E. and corresponding change of direction of the average tracks of the storms of the period. This is followed after a short period of rain in North-Eastern India and Burma by a rise of pressure in Assam, Upper Burma, and Bengal, and the withdrawal of the monsoon current from those areas. The current then recurves over the centre of the Bay, in the same manner as during the monsoon proper over the north of the Bay and Bengal, and is directed or determined to the west or Madras coast of the Bay, which hence receives frequent rain during a short period of about two months—the rainy season of the eastern and southern parts of the peninsula south of Orissa and Ganjam. These rains were formerly described as accompanying the setting in of the north-east monsoon on the Madras coast. That, however, is a misnomer, as the true north-east monsoon winds are dry land winds, and the rain-giving winds of this period in Madras are those of the south-west monsoon in its retreat or con- traction down the Bay. The period during which this rainfall occurs is hence now usually termed the retreating south-west monsoon. The year in India may hence be divided into two monsoons of nearly equal length, viz.:— (a) The north-east or dry monsoon. (6) The south-west or wet monsoon, The first terms are based on the general direction of the air movement in the Indian seas during the periods, and the second on the most prominent feature of the weather in India itself. Of an average annual total rainfall of 41 inches (according to the most trustworthy calculation), at least 85 per cent. falls during the wet season, and only 16 per cent. during the dry season. The dry monsoon in India is subdivided into— + 1, The cold-weather period. 2. The hot-weather period or transitional period of preparation for the south- west monsoon. _ The wet monsoon is subdivided into— 1, The south-west monsoon proper, or period of general rains. 2. The period of the retreating south-west monsoon and gradual slow establish. ment of the dry monsoon, Each of these periods practically covers three months, One of the most noteworthy features of the meteorology of India not referred to in the previous statement is that the storms of each period—viz., the cold- weather period, the hot-weather period, and the wet monsoon—are characteristic and special to the period. They are all in the broadest sense of the word cyclonic in character; but they originate under different conditions and exhibit very different features in each of those periods. The disturbances of the cold weather are large shallow depressions which originate in the upper humid return current of the north-east monsoon circulation chiefly in the Persian plateau region, and which drift eastward with a slight southing across Extra-tropical India. Storms do not occur south of the Deccan or peninsula-dividing ranges during this period. These storms are chiefly remarkable for the frequent development of stationary secondary depressions in the Punjab, usually of much greater intensity than the primaries; a feature of which, I believe, there is no parallel elsewhere. They are of great importance, as they give the main snow supply to the Western Himalayas and the light but 4.4.8 REPORT—1904. general occasional rain required for the wheat and other cold-weather crops of Northern India, The storms of the hot weather are local disturbances of very limited extent, usually in large areas of slight depression, and are occasionally of remarkable intensity and great violence. In the areas to which the local sea winds of the period extend (more especially Bengal and Assam) they occur chiefly as local thunderstorms with violent winds and brief heavy downpours of rain, but some- times as tornadoes rivalling those of certain districts of the United States in inten- sity and destructiveness. In the dry interior they occur as dust-storms, usually without rain, and are most violent in the driest districts, including Sind, the Punjab, and Rajputana. Occasionally, when the convective movement is especially vigorous, they develop into hailstorms of great intensity. The rainfall accom- panying these hot-weather storms is of little general agricultural value except in the tea districts of Assam and Bengal. Finally, the wet monsoon is characterised by the frequent occurrence of cyclonic storms of every degree of intensity and of very varying extent. The great majority of them originate in sea areas of nearly uniform temperature as disturbances in a massive current highly charged with aqueous vapour and subject to large variations of intensity and extension. The more prominent features of these storms, more especially of the most violent, including the hurricane winds, excessive rainfall, and the phenomena of the central calm and the accompanying storm wave, are too well known to require description. The chief importance of these storms, of which an average of about ten (of different degrees of intensity) occur every year during this period, arises from the manner in which they modify the distribution of the rainfall, discharging it abundantly over the districts traversed by the storms at the expense of the districts outside of their field. The most important and variable feature of the weather in India from the practical standpoint is rainfall. Its value depends upon its amount and occurrence in relation to the needs of the staple crops. The measurement of rainfall is carried out, on a uniform system, at upwards of 2,500 rain-gauge stations. The average distribution of rainfall, month by month and for each season, has been determined from the data of about 2,000 stations. It should, however, be recog- nised that the probability that the rainfall will conform exactly to this distri- bution in any year is nil. Average rainfall charts represent a distribution about which the actual varies from district to district more or less considerably, the local variation for prolonged periods being practically compensatory. Such mean or normal data and charts are undoubtedly of value, more especially for the deter- mination of rainfall anomalies and their relations to pressure, temperature, and other anomalies. There is apparently a tendency to assign a greater value to these charts of mean rainfall distribution than they deserve. Charts showing the amount and time distribution of the rainfall best suited for the requirements of the staple crops would—for India at least—be more interesting and valuable. This is a work that I regret has, for various reasons, not yet been carried out by the Indian Meteorological Department. In most regions in India a moderate variation (positive or negative) in the amount of the rainfall is of comparatively small importance, more especially if the precipitation occurs in amount and at intervals suited to the requirements of the crops. During the thirty-year period 1874-1903 there were six years in which the distribution of rainfall affected to a serious extent the crop returns over large areas, and the rainfall was not compensatory. In four of these years the drought was so severe and widely spread as to occasion famine, with its attendant calamities, over large areas. Severe droughts and famines occur at very irregular intervals, A noteworthy feature is that they frequently follow in pairs separated by intervals of two to four years. The previous statement of the meteorology of India has indicated the chief conditions which affect the crop returns seriously or disastrously over large areas in India. They may be summed up briefly as follows ;— (az) The dry monsoon. Absence or unusual feebleness of cold-weather storms. (6) The wet monsoon, General feebleness of the monsoon current, due either —- - - - TRANSACTIONS OF SECTION A. 449 to corresponding feebleness of the south-east trades, or to unusual diversion to East Africa, or local feebleness in a part of India due to local conditions, or to abnormal diversion to other rainfall areas in South Asia. These conditions give rise in the areas affected to one or more of the following features :— (1) Prolonged delay in the commencement of the rains. (2) Scanty rainfall during the season, with prolonged periods of fine, clear, hot weather. (8) Early termination of the rains. These features areas a rule more marked in the drier districts of the interior than in the coast districts. The effect on crop production is greatest and most disastrous in the following areas :— (1) Central Burma. 2) The Deccan, including the Bombay and Madras Deccan districts, and Hyderabad. (8) North-Western and Central India, more especially the South Punjab, East Rajputana, and the United Provinces. The following important inferences are based upon the preceding presentation of facts and the experience of the past thirty years :— (1) The lower air movement of the south-west monsoon is the northward extension of the lower movement of the south-east trades. The latter is a permanent feature of the Indo-oceanic region, and the former a periodic inya- sion of the Southern Asian seas and peninsulas initiated over equatorial regions and propagated northwards to the southern mountain barrier of the Central Asian lateau. fi (2) The primary factors determining this impulse across the equator (the first stage of the establishment of the south-west monsoon) are to be sought in the permanent field of the south-east trades, and are not due to actions in the heated areas of Southern or Central Asia, 2 (8) The pressure conditions in the heated areas of Southern Asia and North- East Africa determine the direction, volume, and intensity of the advance over the Indian seas to what may be termed three competing areas for rainfall (viz., Abyssinia, India, and Burma), These conditions are hence important factors in the third stage of the advance of the south-west monsoon current. (4) The movement when fully established by these actions over the Southern Asian seas and peninsulas is continued—Ist, by the momentum of the lower circulation ; 2ndly, by the release of energy accompanying aqueous vapour condensa- tion ; and 3rdly, by thermal actions in Southern Asia, due to direct solar activity. The termination of the lower horizontal current by vertical movement occurs irregularly over the areas of frequent heavy rain in Southern Asia and Abyssinia, and not over a heated area in Central Asia. (5) The total volume of aqueous vapour brought up by this circulation not only varies in amount from month to month during the season, but also from year to year. The largest variations (seasonal and annual) depend chiefly, if not entirely, upon actions in the source of supply—viz., the Indian Ocean. If those actions determine an increased or diminished supply across the equator into the Indian seas, there is a corresponding variation in the total precipitation of the three competing areas. Amongst such causes and actions may be prolonged and untimely diversion of the south-east trades into East Africa, as in 1896, or general weakness of the air movement over the Indian Ocean, probably eying a displacement and decreased intensity of the southern anticyclone, as in 1899, (6) The relative distribution of the total rainfall in the three areas of discharge of the aqueous vapour of the monsoon currents probably depends upon the relative intensities of the pressure conditions established during the hot weather, which are continued for a part or the whole of the monsoon by actions depending 1904, G@ A5O REPORT—1904. on the rainfall resulting from the initial pressure conditions—an example of the persistence of meteorological conditions and actions which is a prominent feature of Indian meteorology. The total rainfall of each of the three areas may differ considerably from the normal, but there may be partial or complete compen- sation on the whole. Thus it is the general (but not the invariable) rule that the rainfall variations in Burma and Assam are usually inverse to those of North- Western India and also of India as a whole. (7) The distribution of the rainfall in any one of the three competing areas (but more especially in India as the largest) may vary widely from the normal— considerable deficiency in some areas accompanying considerable excess in others. This in India is undoubtedly due to local conditions—e.g., local excess or deficiency of pressure at the commencement of the period and established during the previous hot weather. These pressure variations usually accompany abnormally prolonged and heavy snowfall or very scanty snowfall in the Western Himalayas. (8) Loeal or general drought in India during the south-west monsoon may hence be due to— (a) General weakness of the south-east trades circulation. (6) Diversion of an unusually large proportion of the south-east trades to South-East or East Africa during the monsoon period. _ fe) Larger diversion than usual of the monsoon currents to Burma or Abys- sinia. (d) Very unequal distribution in India itself, due to local conditions esta- blished during the antecedent hot weather. These factors are given in the probable order of their importance. (9) Scanty rainfall or drought during the dry season or north-east monsoon in Northern India results from absence or unusual feebleness of the cold weather storms which are the sources of rainfall at that time. (10) The most prolonged and severe droughts in North-Western and Central India are due to the partial or complete failure of the rainfall of at least two seasons in succession. (11) As the two circulations in the Indian oceanic region have a common goal in the dry season (more especially from December to March), it is probable that variations in the strength of one circulation (more especially the larger) will modify the field and strength of the other circulation. It appears that this rela- tion would be shown mest strongly between the southern circulation and the upper movement of the northern circulation. And, as cold weather storms are disturbances in that upper movement, it is possible—if not probable—that the larger variations in the number and intensity of the cold-weather storms and the amount of the cold weather precipitation may be related to conditions in the south-east trades regions. (12) There appears to be little or no relation between the position and intensity of the Central Asian anticyclone and the number of the cold-weather storms and rainfall of Northern India in any season. The meteorology of the period 1892-1902 is of especial interest for its con- firmation of the above inferences, more especially the phenomena of the variations of rainfall in India and the causes or actions to which they are due. The year 1891 was noteworthy for a severe local famine in Rajputana and the adjacent districts to the north and east consequent on prolonged and excessive snowfall in the Western Himalayas during the winter of 1890-91. The following gives a brief nay of the more prominent feature of the meteorology of this unique period :— 1. The eleven-year period 1892-1902 corresponds in length to the sun-spot period, and it may be divided into two periods of unequal length—a short period of excessive rain and a long period of deficient precipitation. The maximum of the first period was in 1893. The second period had three strongly marked minima in 1896, 1899, and 1901, that of 1899 being the absolute minimum, The following table gives, for convenience of reference, data of the mean annual and TRANSACTIONS OF SECTION A. 451 seasonal variations of rainfall of the Indian land area for each year of the period :— Variation of Mean Actual Rainfall of Period from Normal. South-west | Cold Weather : | Hot Weather : Coreiee ae | danuaryand | March to May | — Period: Mihele eee February | June to | December 1891 . 5 : + 0°34 +0°37 — 425 — 354 1892 . : : —0°39 —0°21 + 5°69 | + 5:09 1893 . . Zl} +1:63 + 2°72 | + 4:72 | + 9:07 1894 . ; 4 + 0°48 —0°76 + 6°75 + 6:47 1895 . 5 : —0:01 — 0:23 | — 1:95 — 2:19 1896 . : : —0'42 —0°82 | — 8°59 | — 4:83 1897 . : : —0:01 —0:12 — 0:02 | — O15 1898 . : : +0°50 —1-:00 + 0:93 + 0°43 1899 . : 3 —0°38 +058 — 11°34 | —11:14 1900 . : : —0:02 — 0:25 — 0:26 |; — O57 1901 . . ; +147 —0-48 — 6:12 i) a3 1902 . : ; —0:57 +016 — 164 — 2:05 Normal roughly . 1 inch 5 inches 35 inches 41 inches 2. The following gives the chief features of the rainfall of the first period, 1892-4 :— (a) The excess was almost as marked in the dry as in the wet season. This is strongly shown in the year 1893 of maximum excess. (6) The excess was on the whole more strongly exhibited in the field of the Bombay than of the Bengal current. (ce) The rainfall of the dry season was as markedly in excess in Perfia, Balu- chistan, Afghanistan, and the Himalayan area as in Northern India. (d) The maximum height of the Nile floods (in September) was above the average. They were abnormally high in 1892 and 1894. (¢) The rains were favourable over Australia and South Africa during this period, according to the reports received in India. (7) Hence, as a general inference, the rainfall was in general excess in each year of the period over the Indo-oceanic region, and not only in the south-west but also in the north-east monsoon in Southern Asia. 3, The chief features of the rainfall of the second period, 1895-1902, in the Indo-oceanic region were as follows :— (a) The rainfall was as deficient relatively to the normal in the cold weather as in the rains or wet season. (6) The cold-weather or winter precipitation was almost continuously in marked defect in Asiatic Turkey, Persia, Afyhanistan, Baluchistan, the Hima- layan area, and South Thibet. The opposite variation obtained in Central Asia, as is shown by available data for Tashkend, Samarcand, Irkutsk, and other stations. (c) The storms of the cold weather were fewer in number and feebler in character in each year of the period than on the average of the preceding sixteen years 1876-91. (d) The south-west monsoon rainfall was most largely in defect in the interior districts served by the Bombay current. (e) There was a marked tendency in each year for late commencement and early withdrawal of the monsoon currents, and for deficient rainfall through- out the whole season over the greater part of India. These features were very pronounced in the years 1896, 1899, and 1901. Q@Ga2 452 REPORT—1904. (f) The most remarkable feature of the period was that the region to the south of the equator, including South and East Africa, Mauritius, and Australia, was similarly affected. In India the years 1896 and 1899 were years of severe drought, followed by famine over very large areas. The area in which the crops failed more or less completely was about 250,000 square miles in extent in 1896 and 500,000 square miles in 1899. In the 1899-1900 famine upwards of 6,500,000 people were on famine relief for several months. The loss of cattle due to failure of water and fodder was very great, numbering many millions. In some districts from 90 to 95 per cent. of the cattle died off from slow starvation and want of water. In New South Wales and Queensland almost continuous drought prevailed from 1896 to 1902. It is estimated that over fifty millions of sheep, value 12,500,000/., were lost in New South Wales during these seven years of drought. Mr. Hutchins, Conservator of Forests, Cape Town, states that drought pre- vailed more or less persistently over the Karoo region in South Africa from 1896 to 1908, and that cattle and sheep perished by millions. He also states that the drought extended to British Central Africa from 1898 to 1903. The previous statements evidence the continuity, extension, and intensity of the drought. The Nile floods followed very closely the variations of the rainfall in Western India. The floods of the years 1899 and 1901 were both amongst the lowest on record, This shows that the rainfall in the Abyssinian region was more or less generally in defect during the period and most largely in the years 1899 and 1901, when the rainfall of the Bombay current was very deficient. Hence, as a general inference, the period 1895-1902 was characterised by more or less persistent deficiency of rainfall over practically the whole Indo- oceanic area (including Abyssinia). The economic results in the dry interior districts of India, South Africa, and Australia were the same—large loss of cattle and great loss of capital. The drought in Southern Asia was as marked in the north-east as in the south-west monsoon, and hence the variation was not seasonal but general. The variations of temperature, humidity, and cloud in India during the whole period were large and in direct accordance with the rainfall. In other words, during the period 1892-94 the air was damper, with lower temperature than usual and cloud above the normal. On the other hand, from 1895 to 1902 temperature was steadily in excess, cloud less than usual, and humidity below the normal. The most remarkable variation was that of the solar radiation as indicated by observations of the solar radiation thermometer (black bulb zm vacuo). The most interesting feature of the meteorology of the period 1892-1902 is that the variations of the solar insolation are the inverse of those which might have been expected from the cloud and humidity data. In other words, solar radiation was in excess in the period of increased humidity and cloud, and in defect during the greater part of the period of drought, decreased humidity, and cloud. The series of eight curves exhibited, out of a larger number prepared from the data of a number of stations in India at which these observations are carefully recorded, show the most important facts, and indicate that there was a continuous decrease of insolation on the average of all stations from 1891 to 1902. The curves for Aden, Calcutta, and Leh, it will be seen, agree in their most important features. The observations are quite concordant and probably represent a most important feature of the period. They indicate either a continuous and considerable decrease of emission of solar energy during the period, or unusually large absorption in the upper atmosphere. In order to decide this question comparison is necessary with similar data for other large areas, as, for example, Europe and North America, It is, however, clear that in India the insolation data of this unique period are of exceptional interest and value. The preceding statements have shown that variations of rainfall for prolonged periods similar in character have occurred, and may hence occur again, over the very laree area including the Southern Asian peninsulas, East and South Africa, TRANSACTIONS OF SECTION A. 453 Australia, and, perhaps, the Indian Ocean, The abnormal actions or conditions giving rise to these large and prolonged variations must hence be persistent for long periods, and be effective over the whole of that extensive area, and hence cannot be inferred with certainty from the examination of the data of one small portion of the area atfected—e.g., India. The variations undoubtedly accompany variations in the complete atmospheric circulation over the Indo-oceanic area, and the effective forces or actions must be such as to influence the whole movement in a similar manner in the two monsoons or seasons of inverse conditions in Southern Asia, This inference furnishes a very strong reason for the conclusion that the meteoro- logy of the whole area similarly affected from 1892 to 1902 should be studied as a whole, and not in fragmentary detail by various weather bureaus, and, as at present, without any co-ordination of the results of these bureaus. The discussion has also indicated that the south-west monsoon current is a periodic or intermittent extension of the permanent circulation of the south-east trades to the peninsulas of Southern Asia, and also that variations in the strength, volume, and direction of movement of the latter affect the extension, volume, aqueous vapour contents, and precipitation of the south-west monsoon currents in Burma, India, and Abyssinia. This fact further emphasises the necessity for the co-ordination and systematisation of the work of observation in the Indo-oceanic meteorological province and the continuous and systematic examination and dis- cussion of observations for the whole of that area. It is, of course, possible that it may be necessary to extend this work to a larger area than the Indo-oceanic region, For Sir Norman Lockyer and Dr. Lockyer have shown that similar pressure variations to those of Bombay occur over a large portion of the Eastern Hemisphere, and variations of opposite a (similar to those of Cordova) over a considerable part of the Western Hemi- sphere. The Indian Meteorological Department, with the sanction of the Government of India, is now arranging to collect and tabulate data for the whole area between the Central Asian winter anticyclone and the permanent South Indian Ocean anti- cyclone, and to utilise the information for the investigation of the causes of the large and general variations of rainfall in Burma and India from year to year. This extension of its labour is recognised as necessary for the improvement of the seasonal forecasts, an important feature of the work of the Department the value and importance of which are fully recognised by the Government of India. Possibly the practice of the Indian Meteorological Department in the preparation and issue of long-period or seasonal forecasts is considered to be not only unscientific, but not justified by comparison with facts. Professor Cleveland Abbé, in his paper on ‘The Physical Basis of Long-range Weather Forecasts,’ expresses his opinion that ‘ we are warranted in saying that during the thirteen years (1888-1900) the only real failure has been that of the prediction of the monsoon season of 1899, the year of phenomenally great drought in that country.’ This opinion is probably more favourable than I should myself give, but it is the opinion of an independent meteorologist eminently qualified to give a judgment in the matter. My own opinion with respect to weather forecasts is that there appears to be too strong a desire for absolute accuracy, possibly due to public and newspaper criticism. Certainty is not possible in weatber forecasts based on imperfect information, and in which the introduction of a single unknown factor in regions beyond observation—e.g.,the upper or middle atmosphere—may completely alter the course of events. Percentages of success are an inadequate measure of the utility of forecasts. To be of real value as estimates of utility they should be calculated rather on the information required, and which might be reasonably expected, than on that actually given. It appears to me that the striving after perfection in short-period forecasts to the exclusion of other claims is impeding the extension and progress of meteorology in other useful directions. It is absolutely essential that officials preparing or utilising forecasts should recognise that every forecast is based on imperfect information and experience, and hence that all important forecasts should be 454 REPORT—1904. expressed as probabilities, and, whenever desirable, an estimate of the value of each probability be given. The Government of India desires to have these seasonal forecasts, and has ordered its Meteorological Department to furnish them. The Government encourages the work, provides the additional means required by the Department for its proper performance, and issues the forecasts only to those who will use them as probabilities for practical guidance. ’ The importance of the work of seasonal forecasting in India may be judged from the following remarks :— India is almost exclusively an agricultural country, with a population of nearly 300 millions. The material prosperity of practically the whole people is determined by the amount and distribution of the periodic rains. The variations in the amount and period of the rains are occasionally so great as to produce the most disastrous results in the staple crops over large areas. In 1899, for example, the crops failed more or less completely over an area several times the extent of England. “There is probably no country where the meteorological problems, of which these rainfall variations form one feature, are of greater interest or more practical importance. The daily weather and rainfall reports are studied during the greater part of the year with the closest attention by the officials, from the Viceroy downwards. The Government is hence keenly interested in meteorological observation and investigation, and is most anxious to improve its meteorological service and utilise it for practical purposes, of which seasonal forecasting is one of the most important. To give two examples. A reassuring forecast at a critical period, followed by its realisation, might be of the greatest value to the agricultural population of a large province, as well as to the local and Imperial Governments. Again, a statement or forecast the probability of which was, say, at least 10 to 1 that the rains would fail more or less completely during a season over a large area might enable the Government to carry out early prudential measures for relief in the most economical and effective manner with the means at its disposal, The preparation and issue of seasonal forecasts will hence, I am confident, be in the future, as in the past, one of the most important duties of the Indian Meteoro- logical Department. There are several points in connection with weather forecasting in India which it is desirable should be borne in mind. ‘The first is that weather in India is distinguished rather by the massiveness, intensity, and persistence of abnormal features than by the frequency and rapid succession of important weather changes. It is chiefly on this account that daily weather forecasts, even if they could be communicated with the necessary rapidity, are of no value to the Indian agricultural population. Also, the empirical knowledge of the significance of the important variations as factors determining or indicating future weather accumulates much more slowly than in Europe, and it is hence doubly important that in India the empirical knowledge derived from very limited experience should be, so far as possible, regulated and controlled by theory and scientific knowledge. It shonld also be remembered that there are large differences between the meteorology of tropical and temperate regions, and also between the relation of crops to weather in India and England. ‘The instincts, habits, beliefs, education of the body of the people in England and India also differ very widely. Hence the possibilities of the practical applications of meteorological science in India cannot be judged from the European standard, and may from that standpoint be unique. The possibilities of usefulness of the work of seasonal or long-period forecasting in India are almost unlimited. To be acceptable and useful to the agricultural population of areas liable to drought they should be fairly accurate with respect to the dates of commencement and termination of the periodic rains, their general character, and the probable occurrence of prolonged breaks likely to be injurious to the chief food crops. If the forecasts were found to be fairly reliable in these respects, it is quite certain that the agricultural population would value them and —— Se TRANSACTIONS OF SECTION A. 455 use them. Indications of a growing belief in the utility and value of this feature of the work of the Department by the people in different parts of India are not wanting. The Government of India have sanctioned large changes in its Meteorological Department in order to enable it to carry out the extensions of work that recent experience has shown to be desirable. The Department is kept in touch with scientific opinion and judgment at home through the Observatories Committee of the Royal Society. ‘The relations to other scientific departments in India are maintained by a special committee termed the Board of Scientific Advice. The scientific staff has been largely increased. The solar physics observatory at Kodaikanal and the magnetic observatory at Bombay have been placed under the Meteorological Department with a view to the complete co-ordination of the depart- ments of scientific investigation for which they are maintained. Observational data for the whole Indo-oceanic area are now being collected and tabulated with a view to the early publication of daily and monthly weather reports and charts of that area. The objects of this last extension have already been indicated. It will afford the Indian meteorologists the data necessary for the investigation of the extension and intensity of the more important variations in the meteorology of the whole region, to correlate the abnormal features in the atmospheric circulation over the area, and more especially to ascertain the causes of the occasional failure of the monsoon rains in India. Finally, it will, it is hoped, enable the Department to collect the information and acquire the additional experience necessary in order to render the seasonal forecasts more reliable and satisfactory than they have been during the past six or seven years, The area to be dealt with (viz., the Indo-oceanic area) is partially covered by a number of independent meteorological systems, including those of Egypt, East, Central, and South Africa, Ceylon, Mauritius, the Straits Settlements, and Australia. Large areas, as, for example, Arabia, Persia, Afghanistan, Thibet, and the greater number of the islands of the Indian Ocean, are now almost completely unrepresented. The departments controlling these systems work independently of each other, chiefly for local objects, and are in no way officially correlated or affiliated. Their methods of observation and of discussion and publication of meteorological data differ largely. It is hence difficult, if not almost impossible, to make satisfactory comparisons of the data, and trace out for the work of current meteorology the extension or field of similar variations, their relations to each other, and their probable influence on the future weather. The work which should be carried out in order that the investigation of the meteorology of the Indo-oceanic area might he effective and as complete as possible includes the following : — (1) The extension of the field of observation by the establishment of observa- tories in unrepresented areas, and the systematic collection of marine meteorological data for the oceanic area. (2) The collection and tabulation of the data necessary to give an adequate view of the larger abnormal features of the meteorology of the whole area. (3) The direction by some authoritative body of the registration, collection, and tabulation of observations by similar methods in order to furnish strictly comparable data for discussion. (4) The preparation of summaries of data required as preliminary to the work of discussion, and for the information of the officers controlling the work of observation in the contributory areas. The earliest publication of the data should be regarded as essential for the use of officers issuing seasonal forecasts. (5) The scientific discussion of all the larger abnormal features in any consider- able part of the area and their correlation to corresponding or compensatory variations in the remainder of the area by a central office furnished with an adequate staff. (6) Possibly, sufficient authority on the part of the central office to initiate special observations required for the elucidation of special features for which there are no arrangements in the general work of the various systems. 456 REPORT—1904. The Indian Meteorological Department is making preparations to carry out a portion of this work ; and will undoubtedly do the best it can single-handed with its limited means. It cannot do the work fully and as it ought to be done. It can do nothing which requires authoritative control over the remaining meteoro- logical systems in the Indo-oceanic field. It is collecting information from those who are willing to supply it, and will utilise it for its special purposes. It isevident the work can only be carried out fully by the co-operation of the various systems subject to limited control by a central office with acknowledged imperial or general authority behind it. The most important part of the work from the standpoint of the science of meteorology is the comparison and discussion of the whole body of observations. The constitution, position, and authority of the central office is hence of the greatest importance. It is quite certain that none of the meteorological systems directly concerned can provide such a central office. If the work is to be carried out fully and systematically it can only be arranged for in England, and by the English Government assuming the general direction and control. At the present time a section of the English Meteoro- logical Office is devoted to the study of oceanic meteorology for the information of mariners. Another section should be created for the study of imperial meteorology for the benefit of its dependencies and colonies. I have reason to believe that the Government of India would contribute its share towards the cost of this extension of work. In the preceding remarks are given the chief reasons for an important exten- sion of work now in progress in the Indian Meteorological Department, an exten- sion which can only be carried out imperfectly by that Department, but which could be performed with most valuable scientific results by the co-ordination of the labours of the weather bureaus concerned, with a central institution or in- vestigating office in England under Government control, Perhaps I may be permitted, from my Indian experience, to add some general remarks bearing on the methods and progress of meteorological inquiry. In India the collection and publication of accurate current data relating to rainfall and temperature is required for the information of Government in its various Departments. The collection and examination of pressure and wind data by a central office with a view to the issue of storm and flood warnings is equally necessary. This work may, perhaps, be described as pertaining to descriptive or economic meteorology. Economic meteorology, so long as it deals only with actual facts of observa- tion, is not a science. Forecasts belong to the same department or branch of meteorology. They may be based on scientific theory and be obtained by scientific methods or the utilisation of empirical knowledge. The latter method is probably sufficient for by far the greater part of short-period forecast work, but the final development of that work and the preparation of long-period forecasts require the application of exact scientific methods and knowledge. And it is, perhaps, not too much to say that the extension of the range or period of fore- casts is a measure of the progress of meteorology as a science. India, by the simplicity and massiveness of its meteorological changes (and perhaps Australia and Africa), appears to be best suited for the earliest experiments in this work, India is, however, poor, not only in material wealth and capital as compared with England, but also in the appliances and means of scientific investigation, and hence looks to England for assistance and guidance in scientific matters, Unfortunately, England lags behind, not only the United States and Germany, but even behind India, in the important field of scientific meteorological inquiry. Tt will suffice to give a single illustration of the anomalous and inferior position which England takes in such matters. All meteorologists and scientific men generally are agreed that the exploration of the middle and upper atmosphere by any available means—e.g., kites, balloons, &c.—is of the utmost importance at the present stage of meteorological inquiry. The United States, France, and Germany have taken up the work vigorously. The English Meteorological Office is unable, for want of funds, to share or take any part in the work. The force of scientific and public opinion is apparently TRANSACTIONS OF SECTION A. 457 powerless to move the English Government to grant an extra five hundred pounds annually for this work. The English Government, on the other hand, some time ago suggested that the Indian Meteorological Department should assist. The Government of India, recognising the importance of the work, has provided the funds and sanctioned the arrangements necessary in order that its Meteorological Department may march with the most progressive nations in this investigation. India has no body of voluntary observers or independent scientific workers and investigators. Whatever is required to be done to extend practical and theoretical meteorology can only be effected by the Government Department to which that work is assigned, with the sanction and at the cost of the Government —which naturally considers chiefly its practical wants in relation to its limited resources. It is, from one point of view, a painful if not quite an unexpected experience to me, on my retirement, to find that the Government of India is, in its attitude towards meteorological inquiry, more advanced, more liberal and far-sighted than the English Government, and that England has not yet taken up seriously the work of scientific meteorological investigation. There are undoubtedly too many observations and too little serious discussion of observations. The time has arrived when investigation should go hand in hand with accurate observation, and should direct and suggest the work of observation, and also that the sciences directly related to meteorology should be considered concurrently with it. There are undoubtedly definite relations between certain classes of solar phenomena and phenomena of terrestrial magnetism. The probability of definite relations between solar and terrestrial meteorological phenomena is also generally admitted. Data for the determination of these relations are being rapidly accumulated, and numerous problems connected therewith are waiting and ripe for investigation. They are too large and complex to be undertaken by present English methods, and can only be attacked by a body of trained investigators under arrangements_ securing the continuity of method and thought requisite for the prolonged systematic inquiry gradually leading up to their complete solution, It would hence be desirable to enlarge the scope of the central institution I have suggested, so as to include in its field of labour the investigation of the relation between solar and terrestrial meteorvlogy and magnetism, so far as they can be solved by the comparison of the observations of the British Empire. The central institution would thus have large and definite fields of work and most interesting problems for investigation. It would hence contribute towards the formation of a body of scientific meteorological investigators adequate to the importance and wants of the empire, and be of the highest educational as well as scientific value. My predecessor in this position, Dr. Shaw, the head of the English Meteoro- logical Office, made some remarks in his Address last year which deserve repe- tition in connection with this idea. He said: ‘The British Empire stands to gain more by scientific knowledge, and to lose more by unscientific knowledge, of the matter than any other country. It should from its position be the most important agency for promoting the advance of meteorological science—in the first place because it possesses such admirable varying fields of observation, and in the second place because with due encouragement British intellect may achieve as fruitful results in this as in other fields of investigation.’ The establishment of the central institution as suggested above would provide a remedy for the defects pointed out by Dr. Shaw. The reorganisation of the English Meteorological Office is, I believe, under consideration. Is it too much to hope that a strong expression of opinion on the part of the British Assuciation, and the influence of the learned University at which its present meeting is held, would induce the English Government to spend an additional 5,000/. or 10,0002. annually for the promotion of meteorological investigation and the establishment of a central Imperial institution in London in connection with its Meteorological Office ? 458 REPORT—1904. The following Papers were read :— 1. The Spectra of Sun-spots. By the Rev. A. L. Cortiz, S.., F.R.A.S. The paper contains a reduction of all the observations of sun-spot spectra taken at Stonyhurst during the years 1883-1901 with a 12-prism spectroscope attached to either the 8-inch or 15-inch equatorial. A discussion of the observations of the spectra of ninety sun-spots, observed during the period 1883-1889, appeared in the ‘Memoirs R.A.S.’ vol. 1, and of twenty-four other spots observed in the period 1890-1901 in the ‘Monthly Notices R.A.S.’ vol. Ixiii. No. 8. All the observations have been taken by the same observer, and are not restricted to a few lines, but on each occasion some particular region of the spectrum between B and D has been selected for detailed study, after a general view of this part of the spectrum had been secured for determining the most widened lines. The earlier observations of the widened lines were catalogued according to Angstrém’s wave-length numbers, as corrected in the British Association ‘Catalogue of the Oscillation-frequencies of the Solar Rays’ (1878) ; the later observations according to Rowland’s numbers. The present catalogue of 346 widened lines between wave-lengths 5884'03 and 6867°46, which combines all former lists, is based on Rowland’s numbers, and contains 5486 individual observations. The chief phenomena in the spectra of sun-spots are, as regards the general absorption, a want of uniformity of blackness in various regions of the spectrum sometimes observed, and, as regards the selective line absorption, the widening of lines, darkening of lines without widening, displacement of lines, obliteration of lines, extension of the widening through the penum- bra, reversal of lines, hazy fringes to lines, and spot-bands. The following tables contain, the one, the mean relative widening of the lines of the chief elements identified, and the other, a list of the most widened lines. The numbers for relative widening are estimated in terms of the normal width of the line multi- plied by the factor 10, and for intensities are taken from Rowland’s Catalogue, where 1 is a line just clearly visible, and successive zeros indicate increasing degrees of faintness. The tables show the importance of faint lines of vanadium and titanium in the sun-spot spectra (‘ Monthly Notices R.A.S.’ vol. lviii. No. 7). These faint lines have been always, and at all times of the sun-spot period, among the most widened lines (loc. cit. vol. xlix. No. 8; vol. lxii. No. 7). The observations give no evidence of a crossing of the most widened lines at an epoch between sun- spot maximum and minimum. They show, however, that the iron lines are more affected in minimum than in maximum spots; no conclusion can be drawn as to a difference of character and temperature between maximum and minimum spots from the behaviour of such faint widened lines. The iron lines brightened in the chromosphere, which are mostly arc lines, are not differently affected in sun-spots from lines not brightened. The widening of some oxygen lines in sun-spots in the a band seems to be a real phenomenon, the single hydrogen line (C) is generally thinned, and almost reversed over spots, and frequently reversed and distorted in their immediate neighbourhood. If oxygen and hydrogen are present in sun-spots, water-vapour might be formed over them. Spot-bands sometimes seen (loc. cit. vol. xlvii. No. 1) are a probable witness to a reduction of tempera- ture sufficient for the formation of compounds, But the widened lines accredited to water-vapour occur generally in crowded parts of the spectrum, so that the widening may be really due to faint solar lines in juxtaposition with them. The predominance of vanadium and titanium in sun-spots is important in view of Mr. Fowler’s recent identification of the flutings in Secchi’s third-type stars as due to titanium or a titanium compound, and Sir Norman Lockyer’s matching of the lines intensified in the spectrum of Arcturus with lines of the same element. Professor Hale has also shown that many of the lines in the fourth-type stars are coincident with lines observed as widened in sun-spots by Mr. Maunder and myself, TRANSACTIONS OF SECTION A. 459 Tapty 1,—Relative Widening of the Lines of each Element. Total Number of | Mean Relative Element |S See ee Lines Observations | Widening = Intensity | Vanadium wt wt 11 | BSB | 123 000 | Titanium . . ‘ : 13 | 207 ea 15 Calcium . ; : : 18 | 734 51 6:3 Sodium . > - 7 4 255 51 136 Nickel . . : : 28 566 45 | 2:2 Manganese : ; 4 4 123 38 | 4:3 NE Pan 123 2593 Be | 39 Iron (chromosphere lines) 35 863 3°6 4°6 Oxygen? . ao 15 90 | 6-4 | 1-7 Me ae Water-vapour. . Py ioe ana | 43 | 08 TaBLE Il.—Lines with the Greatest Mean Widening. Relative | Wave-length Origin Spots | Widening Intensity | 5978-77 Ti / 33 11 | 1 | 99°92 Jia! 23 10 ) 0 6005°77 i Fe 21 9 1 39°95 Vv 42 10 | 0 6126°44 | Ti 15 10 1 | 54°44 Na 16 9 2 60°96 Ca if | { 3 61:50 na of = y resorts 99°40 v 26 14 0 621090 one 12 12 00 43°06 | Vv 45 28 000 61:32 Ti : 29 9 1 74-87 / i” 11 12 00 6306°02 | O 18 16 2 6405-98 / se 10 9 00 2. Lhe Temperature of the Stars. By Sir Norman Lockyer, K.C.B., FBS. 3. Criteria of Stellar Temperatures. By H. F. Newatt, Fae aks 4, Lhe Short-period Barometric See-saw and its Relation to Rainfall. By Wiuu1am J. S. Locxysr, .A., Ph.D., ERAS. The first portion of this paper dealt with the short-period barometric see-saw which has been found by the author and Sir Norman Lockyer to exist between two antipodal regions on the earth’s surface. This investigation, which has been published by the Royal Society,' has already been referred to in detail. - essence of the second portion may be briefly summarised in the following words :— _ The variation of the barometric pressure over India from year to year is the inverse of that over Cordoba, in South America—that is, when the pressure over 1 Roy. Soc. Proc., vol. 1xx. p. 501, vol. Ixxi. p, 185, and vol. Ixsiii. p. 457. 4.60 REPORT—1904. India is in excess of the normal for a year or so, that over South America is deficient or below normal. A study of this pressure variation for places widely scattered over the earth’s surface shows that the earth’s surface may be divided into two parts: one part behaving more or less like India, and the other like Cordoba. A classification of pressures of these two regions shows that a dividing line may be drawn round the earth, on the opposite sides of which barometric see-saws take place. As it seemed possible that the knowledge of this regular barometric see-saw would render possible forecasts for approaching seasons, its relation to rainfall was investigated. Since rainfall, generally speaking, accompanies low pressure, the inverted pressure curves were compared with the rainfall curves for several stations. The very close relationship between the rainfall and inverted pressure curves which was thus found to exist suggested that there was a possibility of forecasting wet and dry years. The problem becomes more difficult the further the equator is left behind and the poles approached, but it is thought that when further investigation has been made the behaviour of the pressure and consequently rainfall variations in these regions will be more completely known, 5. The Kelation between Solar Physics and Meteorology. Sy Professor BirkELanp. : 6. Experiments with Kites in the Mediterranean. By L. TetssereNc DE Bort. 7. The Relation between the Minima and following Maxima of Sun-spots. By Aurrep ANGot, Professor Wolfer published some time ago'a revision and continuation of R, Wolf's table of relative numbers of sun-spots, so we have now, for every month or year, the mean intensity of sun-spots from 1749 to 1901, When working at that table in order to verify or find some periodicities I met with a relation that was not mentioned, so I presume it may be new. ‘When the mean number of sun-spots during a year of minimum is wnder the average of all the minima, the value of the immediately following maximum is also under the average, and vice versd.’ This will be apparent from the following table, which gives the relative numbers of sun-spots (7°) during the years of minimum and the numbers (R) for the immediately following maxima, arranged according to the decreasing values of the minima. The numbers in brackets are the corresponding years :— r R 11 [1766] 106 [1769] 11 [1844] 124 [1848] 10 [1784] 132 [1787] 10 [1755] 86 [1761] 9 [1833] 138 [1837] 7 [1867] 139 [1870] 7 [1775] 154 [1778] 6 [1889] 85 [1893] tse is Hd 3 [1878] 64 [1883] 2 [1823] 71 = [1830] 0 [1810] 46 [1816] Average 65 Average 99:2 1 Astronom. Mittheil., No. 93. TRANSACTIONS OF SECTION A, 461 With the exception of the fourth line, the first six minima, all above the average, are followed by maxima above the average, and the last six minima, under the average, are followed by maxima under the average. It seems even possible that the unique exceptions in the fourth line are only apparent, for it concerns the first cycle of observations (1755-1761), and it is not unnatural to believe that the scale with which the sun-spots were then evaluated was not exactly the same as it is now. It would seem also that the interval of time between a minimum and the following maximum is smaller when the minimum is above the average and larger in the other case ; but I believe this fact has been already mentioned. If the relation indicated above holds true, we should be able to forecast one or two years in advance the general feature of a maximum of sun-spots from the observation of the preceding minimum. For instance, the last minimum (1902) has been very small ; it seems probable that the next maximum will be rather late and under the average. 8. Relation between Pressure, Temperature, and Air Circulation in the - South Atlantic Ocean. By Commander C. Hepworrtn. 9. On the Ultra-red Absorption Spectrum of Ozone and the Existence of that Gas in the Atmosphere. By Professor K, Anastrom. Already in 1861 Tyndall had found that, though oxygen transmits easily the radiation emitted from bodies of low temperature, this is by no means the case with its modification, ozone. In spite, however, of the evident importance of that discovery, it has not yet given rise to a more profound investigation of the character of this absorption, That question I have tried to solve by examin- ing the spectrum of ozone from A=0°6 » to A=14 ym" by means of the spectro- bolograph that I have constructed. The radiation was produced by a Nernst lamp of 110 volts. The absorption-tube, about 30 cm. in length, whose ends were closed by plates of rock salt, could be filled by 10 per cent. ozonised quite dry oxygen. vDhe result of that investigation is briefly the following :— In the portion of the spectrum between 0°6—4°6 yp, ozone does not seem to have any very considerable absorption-band, and as the radiation of the sun only in that part of the ultra-red spectrum has a greater intensity, it is evident that with regard to the quantitative absorption of solar radiation the ozone will not be of any greater importance. But in the following part of the spectrum ozone has several bands of great intensity, viz. :— A=48 yp. sh bs : C45 Sar, A=58p. : c ; : . Weaker. N==G$ 7a fis 9 : . ; . Uncertain. A=9'1-10°0 p ‘ : 5 . A very strong and extended band. It is evident from the position, the intensity, and the extension of these bands that the radiation from sources of low temperature must be strongly absorbed by ozone. With the already mentioned absorption-tube I have examined the absorp- tion of the integral radiation from the Nernst lamp as well as from a black surface at a temperature of 400°, 200°, and 100° C., and I have found it to be re- spectively 1°8, 11°1 18°9, and 16°5. The question arises then: Is ozone really one of the constituents in the atmo- sphere ? It is well known that the existence of ozone in the atmosphere—except after thunderstorms—has been doubted, and the chemical reactions for, determining the quantity of ozone in the atmosphere are very uncertain, The knowledge of the P 4.62 REPORT—-1904. ultra-red spectrum of ozone offers us a means of solving that question. The solar spectrum below \=4'6 p is certainly of little intensity and intersected by strong absorption-bands produced by aqueous vapour and carbonic acid ; the solar radia~ tion is, however, perceptible in all that space, and especially about A=4'8 and 9°5 we know of no stronger absorption-bands caused by these gases. I have then, with the same spectrobolograph that I have used in the investigation of the absorption-spectrum of ozone at different times, registered the solar spectrum, and I have found that the band \=4°8 as well as A=9:1—10°0 are present in the solar spectrum. During the month of March these absorption-bands in the solar spectrum were of about the same intensity as those I have found by using the absorption-tube, but in June they were much weaker, and the band \=4'8 scarcely perceptible. By this I have proved that— 1. Ozone produces a strong absorption in the ultra-red spectrum, where it is characterised by several bands of great intensity. 2. These bands are also present in the solar spectrum, where their intensity, however, is subjected to very great variations. 3, Ozone is then present in the atmosphere, and must exercise a strong but variable absorption on the radiation from the earth. It is well known that sun-spots and the electrical phenomena in the terrestrial atmosphere are connected with one another. But it is also probable that these electrical phenomena are a cause of the production of ozone in the atmosphere, and consequently the absorption of the earth-atmosphere and the climate must to a certain degree depend on the sun-spots and vary with these. It is evident that only continued investigations can teach us how much and in what manner the quantity of ozone varies in the atmosphere. For the moment I will here only insist on the importance of these investigations, for which the spectro-bolometer offers a very convenient method. 10. An Instrument for the Measurement of the Radiation from the Earth. Ly Professor K. Anastrom. A question that has hitherto been but too little studied is the radiation from the earth. It is, however, of the greatest importance, not only as a climato- logical factor of great interest, but also for our knowledge of the influence of the atmosphere on the solar radiation. : Very interesting investigations in order to determine the radiation from th earth in absolute measures have been made by Pernter, Maurer, and Homén, and lately by Exner, who has employed for these examinations my pyrheliometer with electric compensation, but there is no doubt that the screen used in these researches in order to intercept the radiation from space introduces certain errors, and that a satisfactory instrument for determinating the radiation from the earth has not yet been constructed. It seems, however, that a simple modification of my pyrheliometer witk electric compensation would lead to a very good result, and the instrument which I have constructed according to that principle has, during the time in which I have had the opportunity to test it, proved itself to be a reliable and convenient one. The modification of the pyrheliometer for that purpose consists only in exchanging the black strips of manganin for two platinum strips, one black, the other bright. These strips are placed beside each other in a little frame, Two thermo-elements are fastened to the back of these strips, and with a galvanometer it is possible to prove that the temperature of the strips is the same. The appa- ratus employed by the pyrheliometer are also used here, viz., a galvanic element, a rheostat to regulate the electric current, and an accurate amperemeter in order to determine the strength of current for heating the strips. The frame is fastened at the upper end of a bright metallic cylinder, which before the beginhhing of the observations is closed by a cover. By exposing the TRANSACTIONS OF SECTION A, 4.63 strips to radiation during the night, the black band is cooled more than the bright one, and in order to restore the equilibrium of the temperature it is necessary to conduct an electric current of certain intensity through the other. The two strips being identical, excepting the difference in radiating power of the upper surfaces, we may easily find the value of the radiation w in question. The value of the electric current being 7, the resistance of the strips per cm. m, the width 4, the ratio between the radiating power C,/e, we have : m % * NM ce 4186" 1-C,/e C,/e can be determined very accurately in the laboratory once for all, and the not quite strict supposition that this quantity is a constant can be of no great consequence to the result, C,/e being such a little quantity that a variation in it of 10 per cent. will only introduce an error of 1 per cent, in the results. This instrument has, as will be easily understood, the same advantages as the pyrheliometer—that it is independent of the loss of heat through air-currents. Among the questions which may be studied by means of this instrument I will mention the following:—(1) The variations of the radiation from the earth during the night and during the year; (2) the connection between this radiation and the quantity of humidity, ozone, and carbonic acid contained in the air; (8) ue connection between the absorption of solar radiation and the radiation from the earth. DEPARTMENT OF MATHEMATICS. The following Papers and Reports were read :— 1. The Law of Error. By Professor F. Y. Epgrwortn, D.C.L. The approximate expression for the frequency with which different values are assumed by a quantity that depends on a great number of independently varying elements is investigated by a new method: corroborating the first and second approximations, which had already been obtained, and obtaining the third, fourth, ‘and, generally, the ¢‘* approximations. The results are extended to the case in which the elements fluctuate in several dimensions, and to the case in which the compound isa function other than linear of the elements, a function capable of expansion in powers of the elements, which are not neglected. 2. Report on the Theory of Point-groups.—Part IV. By FRANcEs HaArpbcastLE.—See Reports, p. 20. 3. Motes on Plane Curves. By Harouip Hinton, WA. The effect of an ordinary multiple point of the X-th order with superlinear branches of orders 7, s, t,... on the class, deficiency, and number of inflexions of a curve is the same as the effect of {4k(A—1)—S(r—1)} nodes and 3(7-1) cusps. The number of conics through four fixed points touching a curve is 22+): the harmonic envelopes of any fixed conic 7 and (3+ ) conics passing through two fixed points on 7 and osculating the curve (or $[4n? + 4nm + m* —4n—10m— 3x] conics passing through two fixed points on 7 and having double contact with the curve) are degenerate. The number of conics through two fixed points having 4.64, REPORT—1904. double contact with a fixed conic and touching the curve is 2(z +m): the number of conics through a fixed point having double contact with a fixed conic and oscu- lating the curve is 2(8 + 1), &c. The intersections of the other circular lines through the intersections of a curve with the circular lines through any point A (the satellites of A) play an important part in the theory of curves, especially when A is a focus. For example :—At bicircular quartics through four fixed points, A, B, C, D, having B as a focus whose satellite is A, pass through a fifth fixed point and have four-point contain with the osculating circle at A. The locus of the vertices of the common self-conjugate triangle of any oscu- lating conic through two fixed points and of a fixed conic through these two points is of degree 2(3u+1), class 2(2n+4m+kx), and has 2(11m+3:) inflexions. This is an extension of the theory of evolutes. The 7-th positive pedal of a curve is of degree 2(7—1)n+27m, class rn + (7 +1)m, and has (37 + 1) inflexions, &c., &c. (7 >1). Since the 7-th negative pedal of a curve is the inverse of the 7-th positive pedal of the inverse curve, we can readily deduce the properties of negative pedals from those of positive pedals. 4. Note on a Special Homographic Transformation of Screw System Ly Sir Ropert Bart, LL.D., FBS, 5. The Theory of Vibrations. By Professor V. VOLTERRA. 6. The Stability of the Steady Motion of a Viscous Fluid. By Professor W. McF, Orr. 7. Note on the Schwarzian Deriwative. By Professor A. C. Dixon, 7.2.8. 8. Note on the Theory of Continuous Groups. By Professor A. R. Forsyru, L228. 9. Some Observations on Linear Difference Equations. By Rev. E. W. Barnes. 10. On the Use of Divergent Series in Astronomy. By Z. U. AHMAD. = ooqr ce MONDAY, AUGUST 22. The following Papers and Reports were read :— 1. Recent Improvements in the Diffraction Process of Colour Photography. By Professor R. W. Woop. TRANSACTIONS OF SECTION A, 465 2, On ‘ Reststrahlen’ and the Optical Qualities of Metals. By Professor H. Rusens. 3. On the Separation of the Finest Spectral Lines. By Dr. O. Lummer. By the realisation of the black body and the experimental work during recent years on the black radiation our knowledge of the radiation laws has reached a certain point of completion. The constant of Kirchhoff’s law is as well known now for every wave length and every temperature as is necessary for any practical purpose. Having determined experimentally the laws of black radiation up to 2,500° C., Pringsheim and I are now bringing in the radiation temperature scale based on these laws. The most important work now seems to me the study of the radiation from all bodies, especially gases, whether they conform to Kirchhoft’s law or not. To answer this promising question we must, in my opinion, study from the beginning the mechanism of gas radiation itself—energy distribution, These spectra consisting mostly of narrow lines, we must resolve these lines still further if we would draw conclusions about the existing mechanism. Led by these considerations, I began to work on the modern apparatus of high resolution, and I have brought with me the interference spectroscope, which, based on the interference fringes of a parallel glass plate, 1 worked out with Dr. Gehrcke; I am, therefore, able to show youits effect on the spectral lines pro- duced by a mercury-lamp. In our recent paper, published in the Reports of the German Physical Reichsanstalt, we gave the general theory of all apparatus of high revolving power, including the prism spectroscope, the grating, the Michelson echelon spectroscope, the interference spectroscope of Perot-Faby, and our own. Since the brilliant discovery of Zeeman we know the importance of apparatus with high resolution. Therefore, if we go further and put up apparatus of higher resolution, why should we not observe also the moving posztive electrons, if they can by any means be excited so as to produce light energy? And if the action of the electric field on the light is too small to be detected now, perhaps an apparatus of higher resolution may be able todo so. Be that as it may, only an apparatus of the highest resolving power can help us to enter into the molecule itself and give us new pictures of occurrences in the interior of an atom. Only by the aid of the most complete separation can we find the differences in the spectra of the so-called ‘homogeneous’ spectral lines, when, for example, we raise the tempera- ture of aradiant gas, or change the manner of exciting the electrons, using electric waves of a high or low period. Working in that direction with our interference spectroscope (demonstrated in the Cavendish Laboratory) we got some results which seem to us interesting, in so far as they show that vacuum tubes filled with mercury, hydrogen, sodium, helium, and argon, excited by Hertzian electric waves, give less well-defined inter- ference maxima than when excited by the induction coil. Discussing these un- expected phenomena, we are of the opinion that this loss of sharpness is not a consequence of the Doppler principle for several reasons; for example, because the intensity with Hertzian waves as the cause of luminosity is less than with the induction coil. We incline to believe that the Hertzian waves will enlarge the number of the many satellites of which, in our opinion, every line consists. Surely we can conclude that the excitement in a vacuum tube is not the result of heat, but of electrical occurrences. In my introduction I pointed out what important consequences this result has, in so far as we are not allowed to use Kirchhoft’s law for luminous bodies giving line-spectres, nor to draw conclusions from the brilliancy of these lines as to the temperature of the luminous gas. 4. Recent Work at the National Physical Laboratory. By Dr. BR. T. Guazesroox, /.2.5. 1904, HH 466 : REPORT— 1904. 5. An Effect of Electrical Vibrations in an Optically Active Medium. By Professor W. Vora. Optically active isotropic bodies, which I propose to call psewdo-isotropic bodies, differ in their physical symmetry from the ordinary or real isotropic bodies by opposite directions of rotation being not equivalent. In the case of regular crystals, which in many respects show themselves to be physically isotropic, this difference is expressed in the crystalline form; in the case of isotropic bodies the phenomenon proving the pseudo-isotropic nature is that the right-handed and left-handed circularly polarised waves are propagated with different velocities. Compared with the real isotropic, the pseudo-isotropic bodies exhibit a peculiar property as regards the action of vector fields upon them. In real isotropic media a field of either polar or axial character always establishes a parallel field of the same character; for example, an electric force establishes a parallel electric moment, a magnetic force a parallel magnetic moment. In pseudo-isotropic media, on the other hand, an avial field can establish a polar field, and vice versa. These symmetric relations have been put to account, though without a definite knowledge of that general and fundamental law, in the trials made to deduce theoretically the laws of optical activity, whereby the components of a polar vector always were combined additively in the usual differential equations with the parallel components of an azial vector; for example, with the parallel components of the curl or of the rotation of this polar vector. Such procedure has, however, hitherto furnished no results other than the mere laws of the singular optical phenomena for the deduction of which it was conceived. But it is still highly probable that the pseudo-isotropic bodies differ physically from the real isotropic bodies also in other ways than their optical properties. I wish to speak to-day of an electro-magnetic action in the proper sense of this term, which is indicated by the equations of the electro-magnetic theory of optical activity, and with the experimental realisation of which I have busied myself within the past few months. The optical equations for the pseudo-isotropic media which I have proposed, and which Professor Drude also subsequently established, with the help of a special conception of the motion of electrons, are as follows : If € be the electric force, , ,, magnetic force, v ,, 5, electric polarisation, yy) » magnetic polarisation, then, according to Maxwell and Hertz, RK=c rot H, £= —e rot G, and I put K=E+3x, L = 64395 L+ar+ bi +eH=eG, where 2, U,,...is a system of polar vectors and a, b, c, e are constants individual to these vectors. The last formula expresses by the combination of ) and € that, in the pseudo-~ isotropic media, the electric vibrations excite parallel magnetic vibrations. For deducing by theory an observable electro-magnetic effect the following problem may be considered :— Let infinite space be filled with a system of standing plane electric waves, the wave surface being parallel to the Y / plane and the electric force parallel to the f axis. In one of the loops of these standing waves let a sphere be cut from some pseudo-isotropic medium. The diameter being small in comparison with the length of the waves, the sphere is always in a homogeneous field whose strength varies periodically. TRANSACTIONS OF SECTION A, 467 If the sphere were cut from some 7'ea/ isotropic substance it would under these conditions send out electric vibrations whose directions lie exclusively in planes which pass through the f axis—that is, in mertdian planes, and which are con- nected with magnetic vibrations perpendicular to this plane. But since the sphere is pseudo-isotropic it also sends out rotational electric vibrations around the 7 axis, perpendicular to the meridian planes, connected with magnetic vibrations 2 the meridian planes. The presence of these circular electrical vibrations may be experimentally demonstrated if we surround the sphere with a flat coil of wire, placed in the equatorial plane and connected with a detector of sufficient sensibility. For a point of the equator the circular electric force has a comparatively simple value. Let v be the difference between the indices of refraction for sodium light of the two circularly polarised waves propagated within the medium, and « be the ordinary dielectric constant of the medium ; let \ be the wave length in empty space of the electric vibrations amongst which the sphere is placed, Ts/T the ratio of the periods of sodium light and of the electric waves employed; R the radius of the sphere, and Z the amplitude of the existing electric vibrations. Then, in an allowed approximation, the amplitude T of the circular electric force is given by bd. cee K f a a Ts Since v as well as T,/T and RjA are small, the coefficient of f is very small, and observations about the calculated effect may be made only in a qualitative way. I used a regularly formed piece of quartz, which was allowed with certain restrictions to be taken as a sphere of a pseudo-isotropic medium, I had Rnearly 4 em., f= 4000 volts, A=100 m. and a coil of 200 turns. In these conditions an electromotive force of about 10-* volt in the coil was to be suspected. This is a very weak effort, which can be easily cloaked by other vibrations which affect the detector ; for instance, by those coming directly from the electric oscillator. In some cases it was possible to make the disturbing effects very small, and to observe an electric vibration similar to that suspected; for the most part, however, the results were doubtful. I shall, therefore, have to lay more stress upon the interesting indications of theory than upon the results of observation, Pe=p. 6. Discussion on N-Rays, Opened by Dr. O. Lummrr. Having been asked by the Committee to open a discussion on the N-rays, I gave a short account of the experiments which Professor Rubens and I had carried out on this curious subject. We had worked hard to detect them, but had abso- lutely failed, both in the direction of photographic effect with the spark and of sub- jective observation. We made besides photometrical experiments, not previously carried out, which showed that, observing in the dark a faintly luminous screen indirectly, with a well-adapted eye, the difference of intensity must be changed at least 30 per cent. to give a perceptible effect. On the other hand, the change from direct to indirect vision increases the intensity from one to four and more, due a i fact that we observe directly with the cones of our retina, indirectly with the rods. But also in the case of continued indirect vision, which the N-ray observers maintain to be necessary, physiological processes go on in the eye which give great variability of the luminosity of such small phosphorescent screens, one of which I described under the title of the ‘Heinrich-Phenomenon.’ All our ex- periments, therefore, confirmed our opinion that all such effects, including the newest experiments of Jean Becquerel, were to be attributed to physiological causes. Mr. Butler Burke, of the Cavendish Laboratory, gave an account of his experi- ments with a view to obtaining evidence as to the nature of this new, and it might HH 2 468 REPORT—1904. almost be said, mysterious radiation. But as to the photography of the action of N-rays on asmall spark it would appear from Mr. Burke’s results that the effects obtained by M. Blondlot are due to the influence of the screens employed in increasing the capacity of the apparatus and thereby diminishing the brightness of the spark. Mr. Burke had already pointed this out in the course of his correspondence on the subject in ‘ Nature’ during the last few months. He next summarised the evidence of direct observation of luminous sources, and stated that in the course of his experiments he had tried the vision of numerous persons, but that in no case was there satisfactory evidence of any external action upon the sight. Mr, Burke then entered into the particulars given in M. Blondlot’s paper on the wave-* lengths, and emphasised the fact that the arrangements were such that unless the energy of the N-rays isenormously greater than that of the luminosity from the same source, it would be absolutely impossible to observe the diffraction fringes, the energy being reduced to about s,4;5th of the original in the arrangements em- ployed. He then pointed out that the determinations of the velocity of Rontgen rays and their polarisation would have to be reconsidered unless it can be shown that Rontgen rays produce the increased brightness of the spark which the N-rays were supposed todo, 7. Standards of Wave Length.' By Professor Kayser. 8. Report of the Committee on Electrical Standards. See Reports, p. 30. 9, Exhibition of a Magnetic Alloy containing no Tron. By R. A. HapFIELD. SuB-SECTION OF ASTRONOMY ‘AND CosmicAL Puysics. The following Papers and Reports were read :— 1. Report of the Seismological Committee.—See Reports, p. 41. 2, Report on the Investigation of the Upper Atmosphere by means of Kites.—See Reports, p. 17. 3. The Temperature of the Air in Cyclones and Anticyclones, as shown by Kite-flights at Blue Hill Observatory, U.S.A. By A. LAWRENCE Rorcu, B.S., A. This paper gave an account of an investigation of which the preliminary results were presented to the sub-section last year. The data for fourteen kite-flights, made at different seasons and in areas of high and low barometric pressure, were combined with the data previously obtained, and the mean changes of temperature, by stages of 500 metres (1,600 feet), have been determined up to an altitude of about 12,000 feet. The decrease of temperature with the increase of height is nearly uniform and is practically the same for both low and high pressures, amounting to 0°86 Fahr. per 100 metres in the former condition, and 0°88 Fahr. per 100 metres in the latter, or 1° Fahr. per 381 feet and 370 feet respectively. This 1 Published in the Phil. Mag., viii. p. 568 (1904). TRANSACTIONS OF SECTION A. 469 relatively slow decrease, as compared with the adiabatic rate, is due to the fre- quent inversions of temperature occurring at all heights in the free air. Whether the whole column of air in a cyclone is, on the average, warmer than that in the anticyclone depends chiefly upon whether its initial temperature at the ground is higher, as is usually the case when cyclonic conditions prevail in our latitudes. A more conclusive method of investigation is to plot the temperatures at the same heights in the free air during several consecutive days, when the barometric pres- sure and the air-temperature vary at the ground. This appears to have been done first by H. H. Clayton, meteorologist at Blue Hill, who utilised the daily kite- flights made there,’ one conclusion being that the maximum air-temperature at all heights (up to 12,000 feet) nearly coincides with, but slightly precedes the mini- mum of atmospheric pressure at sea-level, and that the minimum air-temperature at the different heights apparently occurs when the atmospheric pressure at sea- level is above normal, but usually some distance in advance of the maximum of atmospheric pressure there. Mr. Clayton now finds that the air in contact with mountain summits is colder than is the free air at the same height, which tends to invalidate the arguments against the convectional theory of cyclone-formation, based upon mountain observations. Kite-flights on Blue Hill are generally made once a month upon the days pre- scribed by the International Committee for Scientific Aeronautics. During 1908 there were fifteen flights, the average of the highest points reached in each flight being 7,264 feet above sea-level, and the maximum height in any flight 13,970 feet. During the present year, from January to July inclusive, the nine flights have given an average height of 8,284 feet and a maximum of 14,660 feet. During the present summer, the writer hopes, by means of ballons sondes, liberated from St. Louis, to extend the observations of temperature in the free air to a height never before attained above the American continent. 4. Problems of Astronomy. By Sir Daviw G11, K.C.B., FBS. 5, Discussion on Units used in Meteorological Measurement. Opened by Dr. W. N. Suaw, F.2.8. 6. On the Masses of the Stars. By Dr. H. N. Russewn. TUESDAY, AUGUST 23. The following Papers were read :— 1. A Correlation between the Electric Conductivity of Air and the Variation of Barometric Pressure. By JOHN Don, ILA., B.Se. From their experiments already described in the ‘Annalen der Physik’ and elsewhere, Professors Elster and Geitel have shown that an insulated electrified conductor, in free air, undergoes a loss of charge which is to be attributed only in a small measure to imperfect insulation on the part of the supports. ' The rate of loss was found to vary according to the state of the weather, being increased by bright sunshine, by winds from hilly districts and by low atmospheric pressure, while it was diminished by fog and rain and cloud, and by the presence of dust and soot in the air. In a contribution to the ‘Archives de Science’ of Geneva, in January 1904 1 See Blue Hill Observatory Bulletins, No. 1, 1899; and No. 1, 1900. 470 REPORT—1904. these observers describe the results of their investigations with regard to the effect of the soil upon the loss of electrification in a neighbouring charged conductor. They had previously been led to the conclusion that the conductivity of the air is due to the presence of free ions, and the object of their research was to discover the source from which free ions arose. That they might proceed from the surface of the ground under suitable conditions there was no reason to doubt. In the case of certain calcareous soils, the conductivity of the adjoining air was very remarkable, and, in general, air which had been for a time in immediate contact with soil acquired increased conductivity. Partly for the purpose of repeating these experiments, which had attracted attention abroad, and in part for the purpose of discovering the nature of the rela- tion between the conductivity of the air and the principal atmospheric phenomena, a series of daily observations was made on the Kast Coast of Aberdeenshire from January to May of the present year. A statement of some part of the observa- tions recorded, together with a description of the instruments employed, has already been published (‘ Elec. Review,’ March and April 1904). It was, however, at the conclusion of an extended series of experiments that it became possible to ascertain whether, and to what extent, correlations existed. It - is believed that the present series is one of the first that has been made in this country, while it is probably the largest yet attempted anywhere. The number of observations is sufficiently great to ensure a tolerably reliable result from the application of the methods of reckoning correlation. More espe- cially is this so, because each experiment was checked by two observers, and repeated if any doubt arose. During the first five months of the year great variety of weather conditions was experienced. The daily experiment consisted in aspirating a measured volume of air over the leaves of a specially constructed electroscope which had been charged to a certain potential. Any leakage on the part of the insulators was first measured and subsequently allowed for. An illustrated description of the apparatus originally employed, and after- wards somewhat improved, will be found in the ‘ Elec. Review,’ March 1904. In the improved form of electroscope the leaves are unequal in size, so that the heavier one hardly moves when a small charge is imparted. Both leaves are suspended by the finest and best silk fibres over a diaphragm, which concentrates the current of aspirated air upon them. , Now it was evident as the experiments proceeded that some relation existed between the height of the barometer and the conductivity of the atmosphere, but yet on several occasions the electroscope showed insignificant loss of charge, not only when the pressure was high but also when it was low. Further, in such cases the barometer was, as arule, steady for a time. To this there were some exceptions, On the contrary, a greater fall of potential had from time to time been observed when the barometer was falling than when it was rising, and this occurred both with high and with low pressures. Hence it seemed almost likely that the conductivity of the air was dependent on the variation of barometric pressure. A calculation was accordingly made (following generally Professor Karl Pearson’s long method), and it resulted in the discovery of this fact, that the conductivity of the air is increased by a fall of pressure, and is correlated with daily variations of pressure to the extent of 37:4 per cent. In the subjoined table the fall of the leaves of the electroscope (which were charged on the average to a divergence of about 1 cm.) is stated on the horizontal columns in 100ths of a mm. per tenth of cubic foot of air aspirated. The rise or fall of the barometer during the day preceding an observation is stated in twentieths of an inch on the vertical columns. The mean fall of the leaves for 114 observations was 11:26 hundredths of amm., and the §.D. for the series 11:73. The mean variation of pressure for the period was almost exactly zero, and the S.D. was 4°68, (BritisH Association, 1904. To face page 470. — <> 7 Totals 35 36 | 37 38 39 40 41 42 43 44 45 46 47 48 49 50 | | 1 | | | | 1 | 2 | 3 0 | | 1 } 5 | 4 | 6 P 9 | 6 | 8 — | _— — | | | 15 | | — —<—<$_ |} —__—_ | ——_—_ —— |— | | ia | | 8 a edie Ale |, te | | ae ah eae 8 3 cee SS ain] fs i (Sn a) Ve |e eae Ca —|—|;—-;-|-—- 1 | | | 5 ) | | 0 ee NN ey ee Ne ice Pereira aD teen (ncn Men Be oe rae 3 | | 2 | / | 2 | 0 — — — — = —= — pos = — — sd — — at i | | | 0 } | Necretletomdl Ole | tee Ric OM NiOcNlee Oyajncoh meter |isO. Poon \acOke Qh Be Totals Benes. | pera | Distances of ) ; | Variates es 28°74 33°74 38°74! from Mean | f any) for 3, cub. ft. of sir drawn. Correlation Table showing Variation of Pressure and Conductivity of Air To Jace paye 470 aie ©) a6 |e «jis “ 26} 7 | 2a, 30 1 a) ss | se | a9] 40] at | az) as | as | a5 | se | a7 | a8 | 49 | 20 1 = = % i. mH \> |e al lie = 1 = z T 4 1 \ 5 = Z : a= = = 1 it = = = = (5 SS \r = = : | = |e ey 143 i =| - lie = 7 = : = : = Z = Ses : =| iis = = ~ I = = = - 1 z F E meet | 2 e = =) \s SSNs z == = : = : = 1 ; aja ada lz 1}4 Pa i 2 a}oln ‘ 1 olola 1}Jojo o}1{o}o|o}o]4| ros ‘ Distanoes of oriate ; Variat ant sahil paelieml 54) 426] 326) +26) 12 4 ‘ on e74] 974 |1074 1174 12-74 ‘a7 ‘ 2074 4) from Mean e173 Meus our rise orf day f Doit is goth mm, fal ft of alr drawu TRANSACTIONS OF SECTION A. 471, The greatest rise of the barometer observed for twenty-four hours was ‘65 in. and the greatest fall -6. The fall of the leaves was zero on eighteen occasions, while it was as much as *5 mm. on four days. All the observations here given refer to a negative charge. 2. On the Ionisation of the Atmosphere. By Professor A. ScuustEr, /.2.S. I have recently described! an instrument which allows us to obtain data for the measurement of the number of ions formed in unit time in atmospheric air. A number of observations have now been made which have led to an improve- ment in the apparatus and given some interesting results. The two data used for the determination are: (1) The number of ions, determined as in Ebert’s well-known apparatus; and (2) The measurement of the rate of recombination of ions. An improvement has been effected in Ebert’s apparatus by shortening the length of the tube and the rod, so as to reduce its capacity to about 6:4 electro- static units. This shortens the time in which an observation can be carried out from a quarter of an hour to about five minutes, The electroscope in the form now used by me is placed above the cylinder instead of below, which much lessens the deposit of dust on the insulating material and thus preserves it. The leak which always takes place when the apparatus is closed, and which is partly due to the leak of supports and partly to the continuous ionisation which takes place in confined air, was observed to be much increased whenever the apparatus was taken out of doors on a clear day. This effect was ultimately traced to convection currents in the apparatus, but the manner in which these currents act has not yet been ascertained. So far as my observations allow me to judge, they suggest the existence in the air of very slow-moving ions, which only give up their chatges when they are brought into contact with metallic conductors. The observations made on Exmoor, at a height of 1,400 feet, have led to the conclusion that the state of the air, as regards its power to allow ions to recombine, varies sometimes with great rapidity, especially near the time of sunset. The air on Exmoor was found to be very pure, so as to give a slow rate of recombination. On the other hand, the number of ions in general was rather less than that found near the level of the sea. Combining these results, I come to the conclusion that the number of ions found on Exmoor during the time the observations were made was considerably less than that commonly observed at lower levels. 3. Discussion on the Radio-activity of Ordinary Matter. Opened by Professor J. J. THomson, /. 2.8. 4, On the Radio-activity of the Hot Springs of Aiau-les-Bains. By Dr. G. A. Buanc. _A research concerning the radio-activity of both the thermal waters of Aix-les- ains was made by me recently. Their temperatures are respectively 47° and 44° Centigrade. They both belong to the sulphur soda class. _ The fact which I principally wish to point out is the strong ionisation of the air inside the grotto where one of the springs is situated. Measures by means of an Elster and Geitel electroscope, surrounded by a wire netting, showed that its conductivity was about sixty times greater than that of the air outside; 1:75 lit. water of this same spring gave to 5 lit. air that had been repeatedly bubbled through it a conductivity rising to over 200 times the normal. The other spring’s \ Manchester Memoirs vol. xlvisi., No. 12 (£904). 472 REPORT—1904. water only caused a thirtyfold increase, while that due to ordinary Chambéry tap water was of only fifteen times the normal value. The maximum of effect was reached after half an hour's bubbling. The most active sediments which I could get (being collected only at a certain distance from the actual source) showed activity comparable to that of the fanghi of Battaglia and the sediments of Bad Nauheim, tested by Elster and Geitel. A viscous matter, partly organic, called Barégine, which floats on the water, showed the strongest activity; it is to be noted that this substance is formed at the spot where the waters emerge from the rock, and is then carried away by them as it floats. A great amount of emanation was obtained by repeatedly drawing air through some heated sediment; its activity decayed according to an exponential law, falling to half its value in 3-2 days. The same result was given by emanation obtained by bubbling air through the waters. A disc of tinfoil charged at — 600 volts and kept in a metal vessel containing some 100 gr. sediment showed excited activity, the rate of decay of which has not yet been precisely determined. 5. Plan of a Combination of Atoms having the Properties of Polonium or Radium.' By Lord Ketvin, F.R.S. 6. Electrical Insulation in Vacwwm.? By Lord Kevin, F.R.S. 4. Electrical Conductivity of Flames. By Dr. H. A. Witson. 8. The Electrical Properties of Hot Bodies. By Dr. O. W. Ricuarpson, 1.4. In every case of steady ionisation by hot bodies which has been examined up to the present, the quantity of electricity C discharged in unit time is connected with the temperature @ by the relation C= Aéve'/@, In this formula A and } are constants which depend on the nature of the body and on the state of its surface, and are different for positive and negative electricity. The numeric p also is a constant which does not vary sufficiently from zero to cause the variation of 4” with 6 to be comparable with that of the exponential term. me In cases like that of the negative leak from hot metals, where the ionisation in a good vacuum is a steady function of the temperature alone, a formula of this type can be deduced thermo-dynamically. The only assumption made in the proof is that the phenomenon is reversible, z.e., that the ions given off behave like a vapour, and can be in equilibrium with the metal at a definite pressure. Deduced in this way the formula for the quantity of negative electricity given off by hot bodies is found to be Ate-/6. This formula has been verified by the author ® for the cases of platinum, carbon, and sodium. Wehnelt,* who found that the negative leak from hot platinum was greatly increased by covering the surface with the oxides of barium, strontium, and calcium, showed that the same law held for the discharge from these substances, whilst more recently Owen® has found a similar relation for the negative leak from a Nernst filament. _ The case of the positive leak from hot substances is essentially different from that of the negative. Here the current is not a steady function of the tempera- ture, but decays asymptotically with time at constant temperature. The rate of ) Printed in full in Ppit. Mag., vol. viii. p. 528 (1904). Printed in full in Phit. Mag., vol. viii. p. 534 (1904). 3 Phil. Trans., A., vol. cci. p. 497. 4 Drude’s Ann., vol. xiv. p. 425. ° Phil, Mag., V1., vol. viii. p. 230, TRANSACTIONS OF SECTION A. 473 decay has been found to increase rapidly with the temperature, so that at low enough temperatures the rate of decay is inappreciable, and the leak appears to be a definite function of the temperature of the wire. In these cases, where the amount of the positive leak does not decrease perceptibly during the course of the experiments, it also is found to obey the above formula, ‘This is found to be the ease on reducing the observations given by Strutt’ for the positive leak from silver and copper in air and silver and copper oxide in hydrogen between the temperature limits of 175° C, and 331°C., and has been fully confirmed by a large series of numbers obtained by the author in investigating the emissibility imparted to a platinum wire by the luminous discharge. It also holds for the numbers given by Wehnelt? for the positive leak from the alkaline earths, and those given by Owen® for the positive leak from the Nernst filament. Generally speaking, the numbers given for the positive leak are not so accurate as those for the negative, owing to the complication caused by the falling off with time; and as we have no theoretical guidance here, we cannot be certain that in this case the index p in the formula A6ve—"/6 is equal to one-half. None of the results for the ionisation from hot bodies appear to be in disagree- ment with this formula. It holds for all temperatures where the ionisation is a definite function of the temperature, and its applicability extends over a far wider range than those cases where it can be shown to hold theoretically. In cases where the thermodynamic reasoning applies, the quantity 4 has a definite meaning, and is equal to twice the energy in calories required to set free a gram molecular weight of the ions from the hot substance. As to its magnitude, 6/2 is always of the order 10°, and varies from 2°67 x 10* for the positive leak from silver in air (Strutt, Joc. cit.) to 1°32 x 10° calories for the negative leak from hot platinum (H. A, Wilson, ‘ Phil. Trans.” A., vol. excvii. p. 415). It is not without significance that the rate of production of ions by hot substances is connected with temperature by the same formula as that which expresses the temperature variation of the velocity constant of almost all known chemical reactions. 9. The Production of Radio-active Surfaces. By C. E. 8S. PHILuips. The opacity of radium bromide to its own radiations (and especially to the X-rays) makes it necessary, in order to get the greatest action from a specimen, that the material should be spread evenly over a considerable surface. And, in addition, it has been thought advisable to find some means of distributing the radium upon a surface capable of ready sterilisation, so that, after its application for therapeutic purposes, it may be rendered completely innocuous. The following method has been found to be rapid and effective. A short length of platinum wire was coated with a layer of radio-active crystals by dipping it into a concentrated solution of radium bromide, and after drying over a flame this wire was sealed into a long straight vacuum tube. A cylinder of thin mica was then slipped into the tube, so that the wire stood axially within it. Having sealed a second wire (to serve as anode) into the tube, the apparatus was exhausted, while the radium-coated electrode remained connected with the negative terminal of an induction coil. The passage of the discharge deposited in a few moments a fairly uniform radio-active metallic layer upon the mica. A surface so prepared may be cleansed without diminishing its radio-active properties by raising it momentarily to a red heat, and appears to be a suitable means of applying comparatively small quantities of radium for therapeutic or other uses where a considerable area is required to be radiated. 10. The Kinetic Theory: Determination of the Size of Molecules. By J. H. Jeans. Phil, Mag. , VI., vol. iv. p. 98 2 Loe, cit. 8 Loe, cit. ATA REPORT—1904. 11. Dr. Grindley’s Experiments on Steam in the Light of the Ether- pressure Theory. By J. MAcFARLANE GRAY. Newton regarded the pressure of the ether as very great, and sufficient, by its slope, to account for terrestrial and stellar gravitation. Ether-pressure cannot be selective ; if it acts upon stars it must also press upon every atom of matter and be the most important of all natural forces, and the fundamental factor in every physical phenomenon. Neothermodynamics therefore begins with ether-pressure as in equilibrium with every other pressure, whether of solids, liquids, or gases. The play space of every contributory molecule of gas, as its amplitude of vibration was acquired, from absolute zero temperature—even if in an envelope of constant volume—must have been obtained by driving back the ether, and, just as external work is pv, so this internal work is also pv. The translation energy of gas is 13 times its pv; or, the constitutional energy of a gas exclusive of external work is 23 pv. Including the external pv, the total energy from absolute zero is 3} pv, and the ratio is 1-4. By this reasoning the same ratio must hold good for all gases. This paper was an examination of Dr. Grindley’s important experiments in the. light of this ether-pressure theory. 12. On a Volatile Product of the Radium Emanation. By W. C. D. Wueruay, F.2.S. Some months ago the writer and his wife found that the excited activity deposited on solid surfaces by the emanation from pitchblende was partially due to a substance volatile at ordinary temperatures. A similar result has now been obtained by the use of the emanation from radium bromide. On blowing out the emanation from a vessel in which it has stood, the walls of the vessel will be found to slowly yield a radio-active substance which diffuses into the air within the vessel. Experiments are being carried on to determine the rate of radio-active change of this substance and to investigate its other properties. Whether this product is identical with that announced by Miss Brooks (‘ Nature,’ July 21, 1904) remains to be determined. WEDNESDAY, AUGUST 24. DEPARTMENT OF PHYSICS. The following Papers were read :— 1. The Propagation of Electric Waves along Spiral Wires, and on an Appli- ance for Measuring the Length of Waves used in Wireless Telegraphy.' By J. A. Fuemine, IA., D.Sce., FRS. This paper was concerned with an experimental and theoretical treatment of the propagation of electric waves along spiral wires. The subject has engaged the attention of several physicists. Hertz has described an experiment in which he established stationary electric waves on a spiral wire and compared the distance of the nodes with the corresponding dis- tances when the wire was stretched out straight. Theoretical treatment has been given by H. C. Pocklington, and G. Siebt has devised lecture apparatus for exhibiting the propagation of stationary waves on spiral wires. The first experiments described by the author were made with a long helix of 1 Printed in full in Phil. Mag., vol. viii. p. 417 .1904). . TRANSACTIONS OF SECTION A.' AT5 insulated copper wire, wound in one layer on a wooden rod. The helix con- sisted of 5,000 turns, the length being 200 centimetres. If such a helix is placed in connection with an oscillating circuit consisting of a condenser or Leyden jar, a spark gap and a variable inductance, stationary waves could be set up on the helix by adjusting the inductance in the oscillating circuit. In order to detect the nodes and antinodes of these stationary oscillations, the author makes use of a vacuum tube, similar to that used in spectrum analysis, preferably one filled with the rare gas, Neon, which was kindly supplied to him by Sir William Ramsay. Rarefied Neon seems to be extremely sensitive to the presence of variable electric force through it; hence, if such a tube is held perpendicular to the helix and moved parallel to itself along it, it glows brightly at the antinodes but not at the nodes. In this manner the internodal distances cau be measured with considerable accuracy, and the wave-length of the stationary oscillation measured. The paper also contained a theoretical analysis of the phenomena leading tu the conclusion that the velocity with which the wave is propagated along the spiral is inversely proportional to the square rood of the product of the capacity and inductance of the helix per unit of length. The author has perfected of late years methods for measuring very small capacities and inductances, and in the case of the above-named helix the inductance is equal to 100,000 centimetres per centimetre, whilst a capacity of the helix is #4 ofa micro-microfarad (1 micro-microtarad =10~-° microfarad), ( From these data the velocity of propagation of electric waves along the helix can be shown to be 235,000,000 centimetres per second. This figure is confirmed in the following manner: The capacity and the inductance in the oscillating circuit are both measured when the first harmonic oscillation is formed on the helix, and under those conditions the half wave-length was found to be 140 centimetres, whilst the frequency in the oscillating circuit, as calculated from the capacity and inductance, was found to be 0°847 x 10°, Having, therefore, the wave-length and frequency, we find their product gives a velocity of 235,000,000 centimetres per second, which agrees with the figure determined from the constants of the helix. It was shown that the best form of inductance to be employed in connection with the oscillating circuit is a square of one turn of wire, and that the employ- ment of spiral coils leads to errors due to-passage of a dielectric current from coil to coil. On the above lines an apparatus has been devised by the author for measuring wave-lengths in connection with Hertzian wave wireless telegraphy. It is a matter of considerable importance to be able to determine the frequency and wave-length of the waves sent out by any given transmitting arrangement. The author calls this instrument a ‘Kummeter.’ It is constructed as follows: A long ebonite rod is wound over closely with silk-covered wire in one layer, and this is supported on insulating stands. On this long helix slides a metal saddle having some layers of tinfoil interposed to make good contact between the saddle and the helix. This saddle is connected by a flexible wire with the earth. One end of the helix is furnished with an insulated metal plate, which is placed in apposition to another metal plate connected to the oscillating circuit of the transmitter. The process of measuring the wave consists in sliding the saddle along until a Neon vacuum tube indicates the presence of one node halfway between the saddle and the plate. When this is the case the distance from saddle to plate is one wave-length of the stationary wave on the helix. From the constants of the helix the velocity of the wave along it can be calculated as above shown, and hence the frequency of the oscillating circuit becomes known, If this frequency is divided into the velocity of light, reckoned in feet, it gives the wave-length in feet of the wave radiated from the associated aérial, provided that the aérial radiating wire has been tuned to be in resonance with this oscillating circuit. This instrument also provides the means of measuring small inductances, and also the frequencies in oscillating circuits, which are much higher than those which can be determined by photographing the spark, 476 REPORT—1904, 2. Eddy-current Losses in Three-phase Cable-sheaths.+ By M. B. Frexps. In three-phase electric power distributions the use of three-core lead-sheathed cables is common practice. The alternating currents in the cable-cores induce eddy-currents in the sheath. If the cores have circular cross sections, and the current be evenly distributed over the section, the calculation of the sheath-loss (with certain reservations) is easy. Two effects exist which tend toward uneven current distribution in the cores: (1) the skin-effect, (2) the mutual induction effect of the cores on one another. Any uneven distribution of current flowing axially is shown to be equi- valent to a uniform distribution superposed upon an eddy-current distribution (the eddy-currents flowing axially). The complete problem therefore includes the eddy-currents induced in the cores as well as in the sheath. The eddy-currents in the cores are considered under the headings of self-induced eddy-curreuts (skin-effect) and mutually induced eddy-currents. It is shown that owing to the manner in which cable-cores are made up in practice (being stranded and twisted) the calculation of the mutually induced eddy-currents is indeterminate, but if the stranding and twisting be sufficiently carefully executed these eddy-currents are negligible. The skin-effect in circular conductors does not materially complicate the calculation of sheath loss. The mathematical calculation is then given for three-core cables having cores of circular and segmental cross-sections. In this calculation the magnetic forces due to the sheath-currents may be, and are, neglected. It is shown that for different cables having similar cross-sections, working at the same current density in the cores, and at the same frequency, the sheath-loss per unit length varies as the sixth power of the diameter, and that were it desirable, from general considerations, to build large cables, this fact alone would limit the economical size. An example of a low-tension cable is then worked out. The paper concludes by showing that just as the losses due to skin-effect of a given round conductor can be allowed for by assuming a definite increase of the specific resistance of the material for a given frequency, so in a three-core cable the extra loss due both to the skin-effect of the cores and the sheath-currents can be allowed for by assuming a definite increase of specific resistance of the core material for a given frequency. The formula for the increase of specific resistance is derived, 3. Magnetic and Electric Properties of Nickel at High Temperatures. Ly Professor C. G. Knorr. 4. On the Viscosity of Colloidal Lron Hydrate. By A. D. Dennine, U.Sc., Ph.D. Simultaneous measurements of the viscosity of similar solutions were made (i) by finding the logarithmic decrement of a glass disc swinging in the solution according to the method described by Grotrian and W. Konig (readings obtained by mirror, lamp, and scale method), and (ii) by taking time of flow of a fixed volume through the capillary tube (Hagen-Poisseuille’s transpiration method) of an Ostwald apparatus. In order to more conveniently compare the results thus obtained by the two methods the logarithmic decrement was generally calculated by means of the O, E. Meyer formula from values of viscosity obtained by method (ii). The initial values found for the viscosity 7 were, for method (i), yo, = 0'0146; for method (ii), ni9:= 00144 ; whilst for water 7,, =0:01105, 1 See also Journal Inst. Hlect, Eng , vol, xxxiii. pe 936 (19040 TRANSACTIONS OF SECTION 4, An” However, these values, especially for the swinging-disc method, were very con- siderably altered— (i) By dialysing the liquid for three or four days: e.g., not dialysed (7.c. by me), X=0:2018 ; after first dialysis, \=0°2760; after second dialysis, = 0°5162. (ii) After allowing disc to remain in solution for some time: eg., last- mentioned value had become = 0:9753 after 2880 minutes, (iii) By removing disc, washing it with water, and replacing it, caused large decreases in value: e.g., as much as 63 per cent. was once observed. (iv) By heating liquid to about 50°C. and allowing it to cool again, caused increase: eg., X for the once-dialysed liquid became, after two such heatings, =0°6571 ; whilst for the twice-dialysed, after five such heatings, the author obtained a value as high as 1'8364, z.c., nine times original value (0:2018). These results gave some very good ‘ parallel’ ‘ parabolic’ curves. (v) The influence of the size of the oscillation of disc was very marked with more viscous solutions: e.g., A=1:3889 for amplitude of 502 scale divisions ; and = 06020 for one of 42 divisions. These gave a good series of radial curves—z.e., the more viscous the liquid the steeper the curves. (vi) A violent shaking or accidental shaking, or making disc swing through large arcs, caused large decreases in values of A. Further, the ‘ zero-position’ (with the more viscous solutions) of the image of the cross-wires on the scale suffered large displacements to right or left of initial position accordingly as the disc was set in motion by bringing up the N. or the S. pole of a magnet to the directing magnet supported above the disc: e.7., on one occasion a displacement of as much as 658°5 scale divisions was obtained by holding second magnet for a few seconds near the directing magnet—this was with a small disc, when solution was very viscous. An explanation of these apparently very irregular results is to be found in Professor Quincke’s ‘ Schaum-zellen’ theory of a colloid, viz., that such a ‘ pseudo- solution’ really consists of two solutions, A and B (like milk or an emulsion of oil and water), the one, A, being rich in colloidal substance, heavier and more viscous than the other, B, and which possess at their common surfaces of separa- tion a surface-tension, which will vary with the common surface, z.e., with the formation of the small Quincke Schaumwinde, particles, spheres, &c. The values found by the transpiration method also showed a gradual increase during the course of these experiments, but far less strongly emphasised and not subjected to such irregularities. The flow of the colloidal solution through the solution in the one direction in the Ostwald apparatus does not favour the forma- tion of the foam-cells, walls, &c. 5. Magnetic Double Refraction of Colloidal Iron Hydrate, By A. D. Dennine, I.Sc., Ph.D. The magnetic double refraction of iron salts has often been looked for, but up to the present only observed by J. Kerr (‘ Brush Grating Experiments,’ Brit, Assoc. Report, 1901), and by Qu. Majorana (Rendic. Acc. det Lincei, 1902) and Schmaus (Ann. d. Physik, 1903), with old specimens of ‘ Bravais’s Iron.’ These experi- menters found very transient results and give no absolute values for the same. Having found very remarkable results for the viscosity of the colloidal Fe(OH), from Merck, it was deemed desirable to examine if solution would show properties of magnetic double refraction. But although the author made many (more than eighty) different experiments under various conditions—z.c., after repeated dialysis, frequent heating and cooling, by varying concentrations and various magnetic field strengths in differently shaped polarisation tubes—he has only been able to find traces of such properties. Only on one occasion have really measurable results with this solution from Merck been obtained. This was after slowly evaporating a portion until it con- tained approximately 20 per cent. Fe. Then, by placing a few drops between thin glass strips on the poles of the electro-magnet, a displacement of the interference 478 ‘ REPORT—1904. bands of a Babinet’s compensator = 74, wave-length with a field strength (=H) of 24,300 C.G.S. units was obtained. After 13 hours the displacement had decreased by 50 per cent.; on the next day no traces of the phenomenon were to be found. Much more remunerative results were obtained with a solution of ‘ Bravais’s Tron’ obtained from a Heidelberg apothecary, e.g., with a solution (¢ = 1:0041) containing 0:295 per cent. Fe (=e). A displacement (=f) of ¢ A with a field strength (=H) of 4460C.G.S, units was obtained in a polarisation-tube length =/)=5:5 centimetres—a value which gave a specific magnetic double refraction (k) =0'89 x 10-8, Further, the author was able to confirm Majorana’s results that the phenomenon obeys the law B=k Hle. He found, further, that % decreased with the time: e.g., the last value given above was 12 per cent. smaller after a lapse of ten days. He could not find that shape of trough or previous shaking of solution had an influence on the result. Apparently the Merck ferric hydrate and the Bravais’s iron have not the same chemical constitution. Oddly enough, no solution of Fe(OH), that was in the Heidelberg Physics In- stitute during the course of above experiments showed traces of double refraction, when subjected to a sudden and quick motion, as previously found by Professor Quincke (Ann. d. Physik, 1902). Schmaus’s explanation of the suspension character of the solution is nothing more than Quincke’s ‘ Schaum-Theorie.’ 6. An Experimental Verification of Newton's Second Law. By W. D. Eacar, M.A. Teachers of dynamics have recourse to the movements of the heavenly bodies for supplying the proof of Newton’s Laws; and Galileo’s work is as a rule neglected. As the average student of dynamics is not an astronomer, modern scientific methods seem to require something more tangible, and this paper de- scribes an attempt to supply it. The acceleration is measured by the wave-lengths traced on a moving trolley by a vibrating steel spring carrying a paint-brush. ‘The trolley runs down a plane of which the inclination can be varied, and the force down the plane is measured by the weight which, hanging over a pulley, will just permit the trolley to run down with uniform speed. The apparatus of the trolley and steel spring is described by Mr. W. C. Fletcher (Chief Inspector of Secondary Schools) in the ‘School World’ for May 1904. Mr. Fletcher used the same force with varying masses, The writer of the paper has adapted the method to the same mass moving under varying forces. 7. Ona Modification of FitzGerald's Model of the Ether. By J. BuTLER BURKE. FitzGerald represented the mechanism of the electro-magnetic field by a number of parallel wheels connected with india-rubber bands passing round their circumferences, the wheels rotating round parallel axes. Thus, if one of the wheels rotates faster than the rest the bands round it become strained on one side and loosened on the other. This represents the state of polarisation, the opposite sides being in opposite states. If the axes are connected by strong springs instead of being fixed to a board, we have a model of an ether which transmits the ordinary electro-magnetic dis- placements, and at the same time behaves as an elastic solid, thereby transmitting longitudinal and another class of distortional waves. Such an ether, which would be slightly compressible, would, although approximately satisfying Maxwell's equa- tions, at the same time propagate longitudinal waves. These waves, if they exist TRANSACTIONS OF SECTION A. 479 throughout all space, would give rise to gravitational foree between bodies varying inversely as the square of the distance, and, if of sufficiently high fre- quency, much higher than the Réntgen rays, the absorption would be proportional to the mass, and so also would be the pressure. The velocity of propagation would be very much greater than that of light, and this would therefore not be open to Laplace’s objection that gravitation, if it were propagated at the same speed as light, would give rise to planetary disturbances which could easily be detected. The frequency would have to be very great, so that the law of force should be that of the inverse square for small bodies. It seems therefore in accordance with this theory that the wave-length is comparable with the molecular dimensions when the law of attraction no longer follows the inverse square law. It is note- worthy that the hydrogen molecules repel when those of other gases attract. Thus the longitudinal wave-length would appear to be comparable with the dimension of the hydrogen molecule. The repulsion is due to the pressure of the scattered radiation. Similarly with electrons. But although two hydrogen atoms or any two molecules of that order of magnitude may repel each other, and also two electrons, yet a large molecule will attract a very much smaller one, so that a molecule the dimensions of hydrogen atoms will attract an electron because of the sereening action of the larger molecules on the smaller. This appears to be in accordance with electrostatic attraction of unlike charges and repulsion of like ones. Thus the theory is promising in many ways, and is being developed further. 8. On the Electric and Thermic Conductivities of certain Alloys of Iron. By Professor W. F. Barrett, F.2.S., and R. A. HApriexp. 9. On a New Apparatus for producing Magnetic Fields of Force. By Professor Marcus Harrtoe. From a square base-plate of cast iron arise four brass columns with a screw- thread on their upper ends to take large flat nuts, which support a wooden plate with circular perforations at regular intervals. On the iron plate rest the electro- magnets (5), each consisting of a cylindrical coil (c) with both terminals below, and a cylindrical soft iron core which projects through a hole in the wooden plate. A source of direct current, an amperemeter, a rheostat, and a mercury commutator (e) (to allow of the ready alteration of the direction of the current in the individual coils), complete the apparatus. The material I employ is magnetite (mineral Fe,0,), finely powdered and levigated, or iron filings levigated in alcohol; this powder may be shaken on paper or suspended in glycerine, balsam dissolved or melted, or liquefied gelatine. As a rule a thin layer of the mixture is sufficient, spread on a glass or china plate giving an axial section of the field. I have with this apparatus produced several interesting variants of the classical figures of the magnetic field obtained by the agitation of paper strewn with iron filings. Sus-Section or AstRoNoMy AND CosmicaL Puysics. The following Reports and Papers were read :— 1. Report on the Magnetic Observations at Falmouth Observatery. See Reports, p. 29. 2. Report on Meteorological Observations on Ben Nevis.—See Reports, p. 55. 4.80 REPORT—1904. 3. Some Results with the Solar Physics Observatory Photo-Spectro-Helio- graph. By Wii1u1amM J. 8. Lockyer, M.A,, Ph.D., PRAS., This paper contained a description of the spectro-heliograph and the results which have been produced with it. The complete instrument for taking photographs of the sun in monochromatic light consists of three parts: a siderostat, a lens for throwing the solar image on the primary slit, and the spectro-heliograph, The first carries a plane mirror of 18 inches in diameter and has electric slow motions which are operated at the spectro-heliograph. The lens, a Taylor photo- visual, has an aperture of 12 inches and a focal length of 18 feet. The spectro- heliograph moves horizontally in a direction at right angles to the incident beam on the primary slit. It consists of one triangular frame moving on another triangular frame, the former rolling on three balls supported by the latter. This movement is operated by a falling weight, and controlled by a piston moving in an oil chamber. On the movable frame is fixed a double tube, at the extremities of which are fixed the two 4-inch Taylor photo-visual lenses and the two slits. The spectrum is formed in the plane of the secondary slit by means of a 6-inch plane mirror and a 6-inch prism of 45° angle. Nearly in contact with the secondary slit, but independent of its motion, is placed the plate-carrier. The diameter of the solar image on the primary slit is 23 inches, and this is also the size of the monochromatic image at the secondary slit. The dispersion is such that the length of spectrum from F—K is 1°62 inches. The secondary slit is so adjustable that the ‘K’ line of calcium can be com- pletely isolated, and this slit is also so curved that the line can be isolated through- out its whole length. Up to the present time the ‘K’ line has alone been utilised, and, whenever possible, photographs have been secured of the ‘ K’ radiations on the disc and those round it. In the case of the former, with a summer sun and untarnished mirrors, good pictures can be secured in 15 seconds, but this time has to be considerably prolonged during the other months of the year. In the case of the ‘K’ radiations round the disc, or the prominences, under similar weather conditions, 15 minutes is required for a full exposure. These pictures are obtained by placing in front of the primary slit a metal disc equal in diameter to the solar image. The photographs exhibited showed numerous pictures of the disc taken during May, June, and July of the present year, all of which showed fine detail and surface mottling. Several composite photographs, that is, pictures showing the solar disc and limb photographed on the same plate but consecutively, were also exhibited. Attention was also drawn to the very rapid changes which the prominences on the limb underwent in comparatively short intervals of time. Thus, on July 14 a prominence in the north-west quadrant of the sun in an interval of one hour changed from 160,000 miles in length to 96,000 miles, while its height increased from 50,000 to 60,000 miles in the same time. Another instance occurred on July 19, when an enormous prominence, 192,000 miles in length, grew to 216,000 miles in five hours, At the same time its height changed from 55,000 to 60,000 miles. At the present time the instrument is being employed to obtain, as far as is possible, a daily record of the ‘K’ radiation on the disc and the prominences on the limb; but it is hoped, as soon as a sufficiently large grating can be secured, to investigate the distribution of other substances. 4, On the Unsymmetrical Distribution of Rainfall about the Path of a Barometric Depression. By Hueu Rosert Mitt, D.Se. Heavy rains are usually divisible into those accompanying thunderstorms and those accompanying ordinary cyclonic disturbances. In ten cases of the latter TRANSACTIONS OF SECTION A. 481 type occurring in the British Isles, maps were prepared on which the areas receiving a rainfall exceeding half an inch, one inch, two inches, &c., were laid down from the daily observations of observers reporting to ‘ British Rainfall.’ The path of the associated cyclone was inserted from the Monthly Summary o’ the ‘ Weekly Weather Report.’ ‘ Z ; In nine of these cases it was found that, irrespective of the direction in which the cyclone travelled, the area of heavy rainfall (exceeding one inch in twenty-four hours) lay almost entirely on the left of the path, and that the wet area was in advance of the centre. The tenth case was one of nearly symmetrical distribution about the path. The relationship cannot be accidental, and suggests both theoretical and practical considerations of great interest, according with the views of the circula- tion of air in a cyclone recently put forward by Dr. W. N. Shaw, and suggesting a more definite basis for forecasting heavy rains. It must of course be remembered that all cyclones of equal depth of depression and rate of progressive movement are not rain-bearing to the same extent. The cyclone of February 27, 1903, which produced most disastrous damage by wind, brought little rain. The somewhat similar depression of September 10, 1903, remembered as occurring during the meeting of the British Association at Southport, brought a widespread rainfall, but no very serious wind. The remarkable rainfall of June 13, 14, and 15, 1903, between Cambridge and the Thames Valley, when one inch or more per day fell on three consecutive days, was associated with a depression which followed an elliptical path with the wettest area always on its left, a very unusual course, producing an unprecedented rainfall in a comparatively dry area. 5, The Application to Meteorology of the Theory of Correlation. Ly Miss F. E. Cave. During the last few years the methods of the theory of correlation have been applied to the records of barometric observations taken during the years 1879 to 1898 at various stations on each side of the Atlantic. The correlations between Wilmington (North Carolina) and Halifax (Nova Scotia), two stations about a thousand miles apart, have been calculated, different intervals being allowed between the corresponding observations. The magnitude of the correlation varies with the interval, being greatest when Halifax is taken one day later than Wilmington. This seems to indicate a drift of barometric conditions northwards and eastwards ; and the satisfactory results obtained in this case encourage the writer to hope that the application of similar methods to readings taken at stations on opposite sides -of the Atlantic, a longer interval being allowed, may lead to the discovery of correlations sufficiently large to be of use in the practical work of prediction. It has also been found that the correlation between simultaneous barometric heights at two stations lying north and south of each other, at a sufficient distance apart, may be a negative quantity of considerable magnitude, and that the correla- tion varies with the distance in a manner which deserves further investigation. The application to meteorology of the theory of correlation may be of import- ance, both for prediction and also in leading up to fuller knowledge of the laws of the atmosphere, by supplying more detailed information than is otherwise obtain- able as to the connection between different stations as regards either the barometric heights there or any other of the quantities with which meteorology deals, 6. The Development of the Aeroplane. By Major B. Bapren-Powstt. The day is undoubtedly drawing near when we shall be utilising the highway of the air for travel, and it is now becoming an interesting question as to what form the motor car of the skies is to take, , ‘ 1904, It 482 REPORT—1904. During the last few years much has been done in the construction of navigable balloons, but only proving, in my opinion, how insuperable are the difficulties of attaining really practical results. The aeroplane, which may be defined as a plane surface propelled through the air at a small horizontal inclination, so that the resulting pressure of the air supports it against the action of gravity, gives promise of far better results. Wings, vertical-acting screws, and aeroplanes proper all come under this definition. The action of the air on an inclined surface requires more study, as theory and practice in this matter are at considerable variance. With small models, as shown, a vertically lifting screw can, despite theory, lift as great a weight into the air asa horizontally propelled plane. I have been making a number of experiments in this line, as well as with man-carrying aeroplanes driven by the impetus gained by sliding down an inclined plane. The latter haye been chiefly to get at an idea of the strength required in the different parts of construction, and to test the balance of the machine. But results in all these lines tend to show that a great amount of careful experiment is necessary before we can hope for good results, though the prospects are decidedly hopeful. 7. Plato’s Theory of the Planets. By Professor D’Arcy W. Tuompson, C.B. 8. Report on Underground Temperature.—See Reports, p. 51. 9. Zur Flugfrage. By Dr. F. Hirret, 10. Upper Air-currents and their Relation to the Audibility of Sound. By Rev. J. M. Bacon, Investigations carried out during a long series of balloon ascents have revealed a very remarkable complexity in the upper air-currents which, from their nature, would escape the notice of the observer on earth. A number of light bodies, of varying sizes and differently constituted, have been prepared and allowed to float away into space at different heights and under different circumstances ; and these, carefully watched, have shown the existence of minor but headlong currents, hold- ing determined courses frequently at variance with that of the balloon, It has been proved that dominant but diverse air-streams will glide one above another in juxtaposition without commingling, and that upper currents maintaining the same level will occasionally alter their course, presumably in obedience to some con- figuration of the earth below; while, at all heights, ascending or descending air- streams, greater or lesser, will obtrude themselves in a way which is often wholly unaccountable, Ina manner equally capricious, and apparently dependent on the above, sounds conveyed through the upper air will be carried sometimes to abnormal distances in directions at variance with the ground current, being borne to earth over far but favoured plots of ground, while they may pass unheard over districts which might be considered well within sound range. These results, which have been obtained largely by organised observation of the hearing of aerial bombs, will presumably account for the occasional surprisingly far travel of sound signals; or, again, their failure at short ranges. 1l. On the Effect of Electric Avr-currents. By Professor Srtim Lemstr6m. The author, after referring to suggested explanations of the magnetic and electrical conditions of the earth, draws attention to the fact established by Wijkander that TRANSACTIONS OF SECTION A. 483 the sign of the variations of magnetic declination changes on passing from one side to the other of the ‘belt of polar light,’ that is, of the belt of maximum frequency of displays of the aurora borealis. He regards this fact as proving that the aurora is caused by vertical (or nearly vertical) electric discharges in the atmosphere above the belt of auroras, In connection with this he mentions that during the Finnish International Polar Expedition to Sodankyla and Kultala, real auroral beams, showing in the spectroscope the characteristic auroral line X= 5569, were produced on mountain-tops in Finnish Lapland ‘by means of a simple point apparatus conducted to the earth.’ On not fewer than sixteen occasions the same ray was observed in all directions when there was no visible aurora, and it was found that the air itself radiated the light producing this ray. The author goes on to state that during several expeditions to the Polar regions he had observed the rich development of vegetation during the short summer, an observation which had also been made by others. In consequence of experiments made subsequently, he was led to attribute this luxuriance of vegetation to the electric air-currents prevalent in the auroral belt. The experi- ments referred to were performed by means of a network of wire furnished with points and supported on insulating poles above the ground. This was connected with the positive pole of a modified form of Wimshurst electrical machine, the negative pole of which was connected with the earth. The author finds that the electric air-currents brought about in this way will produce, if duly applied, such effects as the following :— 1, An increased growth of all plants, amounting in an ordinary good field to about 40 per cent. 2. A change in the chemical composition of grain and roots resulting in an augmentation of the protein and albumenoid matter in rye of about 20 per cent., in barley of about 12 oe cent., and of about 9 per cent. in oats, and causing an increase in the amount of sugar in sugar-beets of from_13 to 18 per cent. The author has no doubt that similar changes would take place in all sorts of plants under the like conditions, and he commends the matter (further details of which he has given in a small book entitled ‘ Electricity in Agriculture and Horti- culture,’ published by the ‘ Electrician ’ Publishing Company, London, 1904) to the attention of those who may have the opportunity of experimenting further upon it, 12. The Rainfall of the Midland and Eastern Counties of England. By Joun Hopkinson, Vice-Pres. R.Met.Soc., Assoc.Inst.C.L£. This paper concludes the series on the rainfall of the English counties, and contains an account of the rainfall of Shropshire, Stafford, Warwick, Leicester and Rutland, Northampton, Huntingdon, Bedford, Cambridge, Norfolk, and Suffolk. These counties comprise an area of 10,626 square miles, which is rather more than one-fifth that of England, and between one-eleventh and one-twelfth that of the British Isles. The mean monthly rainfall for the ten years 1881 to 1890 at 52 stations in these counties has been computed, and the mean annual rainfall at 106 stations, being one to the nearest 100 square miles in each county. Rutland is included with Leicester on account of its small area, 149 square miles; and of the ten stations allotted to the two counties, Leicester, with 806 square miles, has eight, and Rutland two. Norfolk is much the largest of these counties, having an area of 2,026 square miles, its annual rainfall, therefore, being computed from the records of 20 stations. The annual means at the 106 stations are:—Shropshire (13 stations), 30°36 inches ; Stafford (12 stations), 28-98 inches; Warwick (8 stations), 26-64, inches ; Leicester and Rutland (10 stations), 26°62 inches; Northampton (10 sta- tions, 25°81 inches; Huntingdon (4 stations), 23°39 inches; Bedford (5 stations), 22'59 inches; Cambridge (8 stations), 22:90 inches; Norfolk (20 stations), 25:44 inches; and Suffolk (15 stations), 24:76 inches; the mean rainfall for the whole area being 26:29 inches. During the ten years 1881 to 1890 the rainfall in this part of England was 112 484, REPORT—1904. rather less than that for the twenty-five years ending 1890 and that for the thirty years ending 1895, Twenty stations give a mean for the ten years 1881-90 of 25:99 inches, for the twenty-five years 1866-90 of 26:96 inches, and for the thirty years 1866-95 of 26-58 inches, the excess in this latter period thus being 0°59 inch, or about 2} per cent., over the mean fall at the same stations for the ten years 1881-90. The true mean for the 106 stations for the thirty years would, therefore, probably be a little under 27 inches. The mean fall for the thirty years at the 20 stations in five-yearly periods was as follows :—For the first lustrum, 1866-70, 25:25 inches; for the second, 1871-75, 27-45 inches ; for the third, 1876-80, 30:11 inches; for the fourth, 1881-85, 27'79.inches; for the fifth, 1886-90, 24:19 inches; and for the sixth, 1891-95, 24°68 inches. The monthly and annual means for each county and for the whole area at the 52 stations are as follows :— Mean Rainfall in the Midland Counties of England, 1881-90. | coll s 4, « 8 q 2 o va os & nm s wn FI m eI ae 3 n a n nD | = f= n — . - (B83 /28|/28/68| 8 | 28 | 8 | 28 | 48 | 48 | 38 — |83/83/23/28| Bs | Be | ES | Se | 22 | 2 | 83 | or o+ Es ue s+ ae ov Ses) 5a ers =e | on |} en | Em | on an # Sn | Ba y Zn aR ge | So] So )/gr] aa en Ba gx Ss 2 x n = 3 I =} RR a 3 z fq o J 4 Ins. | Ins. | Ins. | Ins. Ins Ins. Ins. Ins Ins. Ins. Tas. January . | 2°68 | 2°15 | 2°03 | 1°89 1:94 131 1°47 1°41 1°72 158 1°89 February 2°07 | 1:76 | 1:80 | 1°78 1:88 1:26 1:37 1:33 157 147 1°68 March 2°09 | 2°06 | 1:77 | 1°85 1-73 1:29 1°47 | 1°43 1:72 161 1:78 April 2°04 | 1°88 | 1°87 | 2°00 1:76 1°84 E7T + |e 1463 1°55 1:49 1-76 May 2°63 | 2°32 | 2°27 | 2:28 2°10 207 1:97 191 1°76 171 2°10 June 2°42 | 2°50 | 2°22] 2:00 1°84 177 1°94 1:94 1:73 1°62 2°03 July | 268 | 2°65 | 2°77 | 2°61 3°02 3°12 2°50 2°63 2°72 2°60 2-70 August . | 2°84 | 2°73 | 2°37 | 2°56 1:94 2°13 1:93 2°02 2°19 1:95 2°34 September . 2°45 | 2°59 | 2°34 | 2°29 2°28 2 52 2°06 2°27 2°66 2°64 2°46 October . 3-21 | 2°90 | 2°73 | 2°93 2°61 2°52 2°30 2°58 3°26 314 2°94 November .| 3°46 | 2°93 | 2°90 | 2°57 2°66 2°21 2°22 2°23 2°62 2°56 271 December . | 2°47 | 2°34 | 2°00 | 2°07 -1:90 154 1°64 171 211 1:99 2°08 Year... | 31°04 | 28°81 | 27°07 | 26°83 | 25°66 23°58 22°58 22°98 25°67 24°36 26°47 The rainfall in these counties follows the general rule of increase from east to west, except near the sea-coast on the east. Dividing the counties into three groups—west, midland, and east—34 stations for the western group, Shropshire, Stafford, and Warwick, give an annual mean of 28°88 inches; 37 stations for the middle group, Leicester, Rutland, Northampton, Huntingdon, Bedford, and Cam- bridge, give an annual mean of 24°73 inches; and 35 stations for the eastern group, Norfolk and Suffolk, give an annual mean of 25°15 inches. In the first group the driest months are: February, mean 1:88 inch ; March, mean 1-97 inch; and April, mean 1:93 inch. In the second group the driest months are: January, mean 1:60 inch; February, mean 1°52 inch; and March, mean 1°55 inch; and in the third group the driest months are February and April, each with a mean fall of 1°52 inch, while January and March are nearly as dry, the former having a mean fall of 1-65 inch and the latter of 1:66 inch. In the first group the wettest months are October, mean 2°95 inches, and November, mean 3:10 inches; in the second group the wettest months are July, mean 2°78 inches, and October, mean 2-59 inches; and in the third group the wettest month is October, mean 3:20 inches, July following with 2°66 inches, September with 2°65 inches, and November with 2:59 inches. Huntingdon, Bedford, and Cambridge are the driest counties, except in April, when Suffolk is the driest, Norfolk drier than Huntingdon and Bedford, and TRANSACTIONS OF SECTION A. 485 Northampton drier than Huntingdon; in May, when Norfolk and Suffolk are the driest; in June, when Suffolk is the driest and Norfolk and Northampton are drier than Bedford and Cambridge ; in July, when several counties are drier than Huntingdon, and Suffolk and Leicester drier than Cambridge; in August, when Northampton and Suffolk are drier than Huntingdon and Cambridge; and in September, when Northampton is drier than Huntingdon. Shropshire is the wettest county, except in June, when Stafford is the wettest, and in July and September, when several counties are wetter. Particulars of the stations, with the mean and extreme annual rainfall at each, are given with the complete paper, and also a map showing the position of the stations and their height above mean sea-level. 13. The Rainfall of England, 1861-1900. By Joun Horxinson, Vice-Pres. R.Met.Soc., Assoc. Inst.C.L. The rainfall of the English counties has been dealt with in a series of papers read before the Association, each treating of a group of counties: the South-Western at the Bristol meeting in 1898, the South-Eastern at the Dover meeting in 1899, the Northern at the Bradford meeting in 1900, and the Midland at the present meeting. It now remains to summarise the general results and to extend the period, so far as annual rainfall is concerned, to the end of the nine- teenth century. The following table gives the monthly rainfall of each group of counties and of the whole of England for the ten years 1881-1890 :— Taste I.—Mean Monthly Rainfall in England, 1881-90. (288 Stations.) | | | ] | ] ) Counties | Jan, Feb. Mar. | Apr. May | June) July | Aug. Sept. | Oct. Nov.| Dec. | | | | | | me. | | Ins. | Ins. | Ins Ins. Ins. | Ins. | Ins.» | Ins. | Ins. Ins. | Ins. | Ins. | Northern, . . 3804 | 2°32 | 2°82 | 2:15 | 2°50 | 2:27 | 3°60 3°19 | 3°14 | 3°72 | 3°72 | 3:09 Midland A . | 189 | 168 |.1°78 | 1:76 | 2°10 | 2°03 | 2°70 | 3:34 | 2°46 | 2:94 | 271 | 2°08 South-Eastern «| 214 | 1:91 | 184 | 1:77 | 1:97 | 1°86 | 2°50 | 2:07 | 2°37 | 297 | 3:06 | 2°24 South-Western . 3°06 | 2°63 | 2°49 | 2°30 | 2°31 | 2°33 | 3°12 | 2°66 | 2°88 | 3°59 | 410° | 3:32 ere oan Wess aaa England . | 262 | 218 | 2°31 | 203 | 225 | a14 | 3:05 | 2-63 | 277 | 3:37 | 347 | 276 It will be seen that the Northern and South-Western counties have muck more rain throughout the year than the Midland and South-Hastern. In each month from January to July the Northern and South-Western counties alternate in being the wettest; from July to October the Northern are the wettest; and in November and December the South-Western. From January to April the Midland counties are the driest; from May to September the South-Kastern are the driest ; and from October to December the Midland. In spring and summer the Northern counties are wetter than the South-Western ; in autumn and winter there is very little difference between them. In summer the South-Eastern counties are drier than the Midland; in winter the Midland are drier than the South-Eastern ; in spring and autumn they are about the same. io These results are from the records of 288 stations, and the annual means are: Northern counties (94 stations), 35°56 inches ; Midland (52), 26°47 inches ; South- Eastern (70), 26°72 inches ; South-Western (72), 34°79 inches. The annual means computed for 502 stations, one station to every 100 square miles in each county, for the same period, are: Northern counties (184 stations), 36°16 inches; MidJand (106), 26:29 inches ; South-Eastern (99), 26-80 inches; South-Western (113), 34:08 inches. The mean fall for the whole of England, computed for the 288 stations, is 31:59 inches, and for the 502 stations 31:76 inches. These results are sufficiently 486 REPORT-—1904. close to show that the stations from which the monthly means are deduced are fairly representative. Although 502 stations may be a sufficient number from which to compute the rainfall of England for a given period, a much longer period than ten years is required for an estimate of the true average to be arrived at. For this the shortest period which can be taken is thirty years, and forty years give a more satisfactory result. But when we come to work at this period the difficulty arises that the number of consecutive records is inadequate. This difficulty may to some extent be overcome by computing the probable rainfall for the larger number of stations from that at the smaller number for a long period. The following table gives the rainfall in 5-yearly periods from 1861 to 1900 at 50 stations, 18 being in the Northern counties, 11 in the Midland, 10 in the South-Eastern, and 11 in the South-Western :— Taste Il.—Mean Annual Rainfall in England, 1861-1900. (50 Stations.) i} Counties 1861-65 |1866-70 |1871-75 | 1876-80 | 1881-85 | 1886-90 | 1891-95 | 1896-1900 | 1861-1900 Tns. Ins. Ins. Ins. Ins. Tos. Ins. Ins, Ins. Northern . .]| 34°43 37°13 37°75 38°92 38°22 33°34 34:98 35°68 36°31 Midland . : 22°40 24:07 26°90 29°35 27°04 23°79 23°82 22°62 24:99 South-Eastern . 25°85 27°80 28°39 31°62 27°60 25°80 27°45 27°72 25°03 South-Western . 31°23 33°65 37°57 38°75 35°46 30°55 31°86 3155 33°83 as ae England . «| 29°36 31°63 33°45 35°51 33°03 29°14 30°32 29:91 3154 The mean rainfall at the 50 stations for the ten years 1881 -90 being 31:08 inches, and for the forty years 1861-1900, 31:54 inches, and the mean rainfall at the 502 stations for the ten years 1881-90 being 31-76 inches, it follows by proportion that the mean for the forty years for the 502 stations would be 32:23 inches, or there- abouts. Other periods may also be taken, and the following table gives the results of comparison with the ten years 1881-90 of the mean rainfall at 16 stations for sixty years, at 50 for forty years, and at 100 for twenty-five years :— Taste I1I.—Mean Annual Rainfall in England for Various Periods compared with 1881-90. 16 Stations 50 Stations 100 Stations 502 Stations Counties o_o OO | No. 1841-1900 | 1881-90 | No.) 1861-1900 | 1881-90 | No.| 1866-90 | 1881-90 | No.| 1881-90 Ins. Ins. Ins. Ins. Ins. Ins, Ins. Northern . 36°45 36°68 | 18 36°31 35°78 40| 39°80 38°54 | 184] 36°16 6 Midland . -| 3 25°51 25°96 | 11 24:99 25°91 | 20| 26°96 25°99 | 106} 26°29 South-Eastern . | 3 29°08 2820 | 10 25°03 26°70 | 20} 27°79 26°19 | 99] 26°80 South-Western. | 4 37°53 36°08 | 11 33°83 33°00 | 20) 37°66 35°86 | 113) 34°08 England . - | 16 33°21 32°93 | 50 31°54 31°08 | 100} 34-40 33°02 |502| 31°76 By proportion the probable mean rainfall for the twenty-five years 1866-90 (a wet period) comes out as 33:09 inches, and for the sixty years 1841-1900 as 32:03 inches. It must be understood that the results for the 16, 50, and 100 stations are considered of value only for comparing one period with another, and not as giving in themselves a true indication of the actual mean rainfall of the periods to which they relate. TRANSACTIONS OF SECTION A. 487 By the same method of computation, carried out in a somewhat different manner, gradually extending the period, with a smaller and smaller number ot stations, a slightly different result was arrived at, the mean rainfall of England coming out at 32°41 inches for the forty years 1861-1900, for the sixty years 1841-1900 at 32:28 inches, and for the seventy years 1831-1900 at 32:25 inches. Taking into consideration the extreme variability of rainfall, the divergence in these results is too small to affect the value, for all practical purposes, of this method of computing average rainfall, and it is extremely improbable that any method of equal or greater accuracy by which the average rainfall over England may be computed for a long period will give a result appreciably less than 32 or more than 323 inches. 488 REPORT—1904. Section B.— CHEMISTRY. PRESIDENT OF THE SECTION—-Professor SypNey Youne, D.Sc., F.R.S. THURSDAY, AUGUST 18. The President delivered the following Address :— THe researches of Hermann Kopp on the molecular volumes and boiling-poinis of chemical compounds extended over half a century, beginning with his inaugural dissertation on the densities of oxides in 1838, and concluding in 1889 with a review of the whole of the work done on the subject. In his second paper Kopp considered the molecular volumes of solid compounds, and arrived at the conclusion that truly isomorphous substances have the same atomic or molecular volume, but that in other cases the volumes are usually different. Schréder also made the same observation at about the same time. Now, isomorphous substances have analogous chemical formule, and are usually of similar chemical character, and it is interesting to notice that at this early date the fact was recognised that close chemical relationship is associated with similarity in physical properties. For about the first six years Kopp was engaged in the consideration of the results obtained by other observers, and from these results he deduced the most important of his generalisations. As regards boiling-points, Kopp, in 1842, concluded that a constant difference in chemical composition is accompanied by a constant difference in boiling-point, and he adopted the value 18° as the rise due to the replacement of the methyl] by the ethyl group in organic compounds, although the observed differences varied between 11°-0 and 24°°8. Two years later he found in sixteen comparisons differ- ences varying from 8° to 33°; but he doubted the correctness of the extreme values, and took 19° as the true value; he further suggested that this is the constant difference for an addition of CH, in any homologous series, and he pointed out that the observed difference was most regular in the case of the fatty acids. Kopp was also of opinion that isomeric compounds with the same composition and the same vapour density have the same boiling-point. The paucity of experimental data and the wide discrepancies between the results obtained by different observers induced Kopp to undertake the determina- tion of the boiling-points of various compounds, and, later, their molecular volumes at a series of temperatures, and it is interesting to note the comparative crudeness of his first attempts and the increasing attention which he paid to the purification of his compounds and to the elimination of thermometric and other errors, He first examined three pairs of esters in order to find whether isomeric compounds have really the same boiling-points. But he employed only calcium chloride as a dehydrating agent, and this would remove neither water nor the alcohol com- pletely; he was much troubled by the ‘ bumping’ of the liquids, and the tempera- tures he actually observed—with the thermometer bulb in the liquid—fluctuated considerably, and he could onlv, in most cases, take the lowest temperature observed as the most probable boiling-point. By so doing, and by making a fairly liberal allowance for residual errors, Kopp arrived at the erroneous conclusion TRANSACTIONS OF SECTION B. 489 that the boiling-points of isomers were the same in the three cases examined, and therefore, probably, in all cases. The boiling-point of methyl alcohol was of great interest to Kopp, because, taking that of ethyl alcohol—about which there was general agreement—as correct, it should, according to his law, be 78°—19°=59°, while the temperatures actually observed varied from 60° to 66°. Kopp prepared a specimen of methy} alcohol, and found that it boiled at about 65°; but he had more faith in his law than in his experimental result, and he concluded that the methods of determining boiling-points were not sufficiently accurate to give results correct to within even 1° or 2°. In 1854 he discussed the corrections which should be applied to thermometer readings, giving a table of corrections for the unheated column of mercury, and adopting the value 27 mm. per degree as the value of = for all substances, in order to reduce the observed boiling-point to that at normal pressure. He pointed out, also, that the height of the barometer should be reduced to 0° C. Taking advantage of Delff’s improved method of preparing and purifying methyl alcohol, Kopp made a fresh specimen from methyl oxalate and dried it with lime; but while Delff observed the boiling-point to be 60°, Kopp obtained the value 65°°2—65°'8. He was still, however, inclined to think that, owing to bumping, the observed boiling-point was too high and that the true temperature should be about 60°. Meanwhile, in 1847 Kopp had examined sixteen liquids, including water, two alcohols, three fatty acids, and seven esters, and in 1854, as a result of his further determinations, he was able to compare the boiling-points—and also the molecular volumes—of a large number of substances, most of which were either alcohols, acids, or esters, and he at first adhered to his previous value of 19° for the rise of boiling- point due to the addition of CH,. Later in the same year, however, taking a wider survey and including hydrocarbons and their halogen derivatives, ethers, sulphides, and other compounds, he was obliged to admit that tbe difference is in some cases higher, in others lower, than 19°, but he still regarded these cases merely as exceptions to the law. In 1867 Kopp admitted that isomeric aromatic hydrocarbons have not always the same boiling-point, and that the difference for an addition of CH, was not always 19°; but he still believed that the difference for CH, was constant in any really homologous series—for example, 20°°5 for homologues of toluene, 18°°5 for those of xylene, and 16°5 for those of trimethyl- benzene. He also recognised the fact that isomeric alcohols have widely different boiling-points. Kopp published no later papers on the boiling-points of organic compounds, although he dealt fully with the question of molecular volumes in his final com- munication in 1889. Asa pioneer, Kopp had very great difficulties to contend against when he began his researches ; data were scanty and far from accurate, and the substances which could be most easily obtained and, it was thought, readily purified were, unfortunately, those which were the least likely to lead to normal generalisations. Water, the alcohols, and the organic acids all contain a hydroxyl group, and we now know that the physical properties of these substances are abnormal in nearly all respects, owing, probably to the fact that their molecules tend to associate together ; moreover, the esters, which are formed by the interaction of acids and alcohols, do not behave quite normally, and there is probably molecular association, though to a much smaller extent than with the hydroxyl compounds. There can be little doubt that if Kopp had been able, in the first place, to obtain a considerable number of pure substances of normal behaviour, such as the paraffins or their halogen derivatives, he would not have been led to the erroneous conclusions which he defended with such vigour for so many years. If we take the normal paraffins as the simplest class of organic compounds, we find that, instead of the boiling-points rising by equal intervals as the series is ascended, the rise, which is very large for the lowest numbers, becomes. smaller and smaller as the molecular weight increases. This fact is, of course, now well 4.90 REPORT—1904, known, and various formule have been suggested to reproduce these boiling- points. Thus Walker has proposed the formula T=aM”, where T is the boiling. point on the absolute scale of temperature, M is the molecular weight, and a and 6 are constants. Ramage has this year suggested that this formula applies only to the CH, chain linkage, and that the influence of the terminal hydrogen atoms is considerable in the case of the lowest members, but diminishes as the chain lengthens, and becomes eventually either constant or negligible. In other words, the lower members of the series cannot be regarded as truly homologous, and that is a point which is, I think, important to bear in mind. Ramage suggests a new formula, T= a[M(1—2-")]}, where a is Walker’s constant, 37:3775, and 7 is the number of carbon atoms in the molecule. He assumes, however, a constant difference for CH, in the case of the alcohols, the aldehydes, and the ketones, but I doubt whether the boiling-points of the last two classes of compounds are yet sufficiently well established to allow of any certain conclusions being drawn from them. I am inclined to think that it may be useful to regard the value of A (the rise of B.P. for an increment of CH,) as being mainly a function of the absolute tem- perature, and I would provisionally suggest the formula A = sonar where A is the difference between the boiling-point, T, of any paraffin and that of its next higher homologue. Taking the boiling-point of methane as 106°-75 abs., the values for the higher members agree better with the observed temperatures than those given by Ramage’s formula, as will be seen by the table below :— Boiling-point (abs. temp.) a sceeani Calculated. | ne Calculated. Bere Ramage | Young | A CH 1083 | 105°7 —26 | 106°75 | = = 1:55 OH, - 180-0 1773 Joo 27% | 1777 —2°3 OjHy. 228°0 231:9 | +39 229°85 + 1:85 C,H,, 274-0 275'6 Pa sth 6 aces 272°6 —14 C,H, 309°3 | 312-2 | ‘+2°9 309-4 +01 Cane 341-95 343°9 +1:95 341°95 0 C,H,, 8714 372°3 +0°9 3713 | —O1 C,Hie 398°6 398°3 -03 398-1 | —O5 C,H, 422°5 422°5 0 422°85 + 0°35 Ohales 4460 4452 —0°8 445°85 — 015 C,H, 467°0 466°8 —0:2 467°35 + 0°35 C,.Ho, 487°5 487°3 —0:2 487°65 +015 ChE. 507:0 507-0 0 506°8 —0'2 Ole e, 5255 526°0 +0°5 5250 —0°5 Cie 543°5 544°2 +07 542°3 —12 Cry 560°5 561°9 +14 558°85 —1°65 CirHg, 576:0 5790 +30 574-7 —13 OF ‘ si 590°0 595°7 +57 589°9 —01 C,H yo m : 603-0 611°9 +89 604°5 +15 I do not wish, however, to lay much stress on the actual form of the equation, or on the particular values of the constants; the chief point I wish to call atten- tion to is that A may be regarded as a function of the temperature. Suppose that we replace a terminal atom of hydrogen in each normal paraffin by chlorine, so as to form the homologous series of primary alkyl chlorides. The boiling-points of these chlorides are much higher, and the differences, A, are much smaller than for the corresponding paraffins, but the gradual fa}l in the values of A as the series is ascended is unmistakable. The same remarks apply to the bromides and iodides, the boiling-points being still higher and the values of A smaller, But the point of chief interest appears to me to be this: if the values of A for TRANSACTIONS OF SECTION B. 491 the halogen derivatives are plotted against the absolute temperatures, the points for the most part fall near the curve constructed for the paraffins, and represented by the formula A= dears The first value of A is decidedly low in each case T 0:0148./T (average deviation from curve 2°-7); the later ones are rather high in nearly every case (average deviation 0°86). Similar results are in general obtained with other homologous series of compounds in which molecular association is not believed to occur, but, as will be seen from the following table, the deviations from the normal paraffin curve are greater in the case of those series the lower members of which, according to Ramsay and Shields, are characterised by mole- cular association. In the great majority of cases the deviations are greatest for the lowest members of a series, the calculated values of A being almost invariably higher than the observed, and this may perhaps be explained in the manner suggested by Ramage. I have, therefore, divided each series into two groups, the first ending and the second beginning with the lowest member of the series which contains a CH, group linked to two carbon atoms. Thus, of the alkyl chlorides, the first group contains CH,Cl, CH,CH,Cl, and CH; —CH, — CH,Cl, and the second group begins with propyl chloride, so that all its members contain one or more C—CH,—-C roups. - Tk the case of the ethers, esters, and other compounds which contain two alkyl radicals, a series is regarded as homologous when one radical remains unaltered and the other increases by stages of CH,. The variable radical only is considered in dividing the series into the two groups; thus, although propionic acid contains a ©—CH,—C group, it remains unchanged in the propionic esters, the first group of which consists of methyl, ethyl, and propyl propionate, the second beginning with the last-named ester. Lower Members Higher Members Group Number | Mean Difference} Number | Mean Difference of Values) calculated— of Values calculated — of A observed | of A observed ° | ° Alkyl chlorides 2 + 2°70 5 —1:04 » bromides 2 + 1:12 5 = 1°25 3, iodides . 2 + 0°52 3 —1-0 Tsoparafiins — _— 2 +0°57 Toluene, &c. 1 +0°45 3 + 0°63 o-Xylene, &e. . 1 +671 1 —0°5 m-Xylene, &c.. 1 +4252 1 +407? p-Xylene, &c.. 3 Nya gill —0715 1 +0°65 Diethyl benzene, &c. . -f = — i — 0:05 Olefines H,C = CHR ; Mile ss — | 3 —2°351 $s RHC=CHR' . : — — hie te +0°5? Polymethylenes . 2 Lo — 2 —3'85 2 Ethers A - : aoe. | +82 13 +112 Aldehydes 2 +2°0 4 +13 Hydrosulphides 2 + 3°55 1 -0°5 Amines = ; 5 : 2 + 8:2 4 +17 Esters. i : < tal hee ot +492 67 +1:53 Associating Substances. ie) ° Cyanides . . 1 + 12°65 4 +2°9 Nitro-methane, &c.. 2 +111 ] +3°85 Ketones . 1 + 62 3 + 2.85 Fatty acids 2 + 5:87 7 +1:58 2 + 12°87 5 +65'24 » alcohols ‘4,92 REPORT—1904. Of the seventeen series of non-associating substances there are only five for which the mean difference between the calculated and observed values of A for the higher members exceeds 1°°5. 1. The m-xylene series. Here there is only one value, which, I think, is doubtful. 2. The olefines, H,C=CHR. Here two of the three individual differences are less than 1°5; the temperatures are all below 0° and are somewhat uncertain. 3. The polymethylenes. The difference for pentamethylene and hexamethy- lene differs by less than 1° from the calculated value. The B.P. of heptamethy- lene appears very doubtful. 4, The amines. Ditferences somewhat erratic ; three within 1°:5 and two within 0°5. Octylamine and nonylamine clearly incorrect and not included. 5. The esters. Although Ramsay and Shields include these substances as non-associating, there is, I think, reason to suspect slight association. It will be seen that the differences are greater for associating than for non- associating substances ; also that they are greatest for the alcohols and least for the acids, although the factor of association is very high for both these series. In order to arrive at an explanation of these facts the effect of replacing hydrogen by chlorine may first be considered. The boiling-point of hydrogen chloride is not yet known accurately, but it must be about —80°. Thus, by replacing an atom of hydrogen in the hydrogen molecule by chlorine the boiling-point is raised from 20°-4 abs. to about 193° abs., or about 173°. On replacing an atom of hydrogen in methane by chlorine the rise of boiling-point is from 108°'8 to 249°3, or 141°. Ascending the series of paraffins the rise of boiling-point due to the replacement of hydrogen by chlorine diminishes rapidly at first, and then more slowly, being only 58°-5 in the case of octane. Thus the influence of the chlorine atom becomes relatively smaller as the formula weight of the alkyl group increases. Consider, now, the effect of replacing a hydrogen atom by a hydroxyl group. In the formation of water from hydrogen gas the boiling-point is raised no less than 352°°6, from 20°4 abs. to 373° abs., or in the ratio of 1 : 18°38; in the case of methane the rise is 221°8, from 108°'3 to 337°7, or in the ratio of 1: 3:12; with octane the rise is 65°-4, from 398°'6 to 464°; and with hexdecane itis only 56°°5, from 560°'5 to 617°, the ratio being 1 : 1:10. It will be seen that in the case of hydrogen the influence of the hydroxyl is enormously greater, and in the case of methane very much greater, than that of chlorine in raising the boiling-point, but that on ascending the series of paraflins to octane the influence of the hydroxyl group diminishes until it 1s little greater than that of the chlorine atom, and if is quite probable that with hexdecane it would be somewhat less. This is, no doubt, to be explained by the fact that the molecules of water and of the lower alcohols are highly associated in the liquid, but not in the gaseous state, and therefore, in order to vaporise the liquids, this molecular attraction must be overcome, and the temperature must therefore be raised. The molecular association diminishes, however, as the series of alcohols is ascended, and is probably slight in the case of octyl alcohol. If so, it would appear that the effect of the hydroxyl group—apart from association— in raising the boiling-point is not very different from, and is probably somewhat less than, that of the chlorine atom, and that the difference between the boiling-points of the lower alcohols and of the corresponding chlorides is entirely due to molecular association in the liquid state. With the acids there is association in the gaseous as well as the Jiquid state, and since, according to the tables given by Ramsay and Shields, the factor of association for a liquid fatty acid at its boiling-point is rarely greater, and in most cases is somewhat smaller, than for the corresponding liquid alcohol, the molecular attraction to be overcome on vaporisation must be considerably less for the acid than for the corresponding alcohol, and the resulting rise of boiling-point above the normal value must be less. An explanation of the very low values of A for the alcohols and the moderately low values for the acids is thus afforded. It would take up far too much time and space to give full details of the boiling-points of all the compounds considered, with the observed and calculated values of A; but it may, I think, be stated that tie difference between the boiling- TRANSACTIONS OF SECTION B. 4.93 vint of any non-associating organic compound which contains at least one —CH,—C group, and that of its next higher homologue (at any rate up to tem- peratures of about 300° C.), may be calculated with an error rarely exceeding 1°5 14486 ToousyT seems also to be applicable to any ester which contains at least five atoms of carbon in the variable alkyl or acyl group (the mean error for 40 values of A is +0°-93), and with smaller error when the number of carbon atoms is still larger ;! it is probably also applicable to the higher fatty acids, cyanides, ketones, and nitro-compounds. and generally under 1°, by means of the formula A= The formula Comparison of Molecular Volumes. The fundamental idea on which both Kopp and Schréder based their methods of calculating the molecular volumes of organic compounds from the atomic volumes of the component elements was the constancy of the increase in molecular volume for each addition of CH,. With regard to this point the question was greatly discussed whether the comparison should be made at the same temperature, say 0°C., or at the boiling-points of the compounds under the same pressure. Later, when Van der Waals brought forward his conception of corresponding states, it was thought probable that the comparison should be made at cor- responding or equal reduced temperatures ; that is to say, at temperatures which bear the same ratio to the critical temperatures. If the generalisations of Van der Waals were strictly true, the boiling-points under corresponding pressures would be corresponding temperatures, but that is not usually the case. The com- arison may, therefore, be made either at equal reduced temperatures or at the foititig points under equal reduced pressures ; or, lastly, it may he made at the critical points themselves, and, thanks to the law of Cailletet and Mathias, the critical volumes can be ascertained with a great degree of accuracy. In order to find whether the difference in molecular volume for each addition of CH, is really constant it is best to examine such perfectly normal substances as the paraffins, and the data for four consecutive members of the series—n-pen- tane, n-hexane, n-heptane, and -octane—are fortunately available. In the table below the molecular volumes and the differences, A, for an addition of CH, are given under the following conditions ; 9— A. At O°C, B. At the respective boiling-points under | atm. pressure. C. At equal reduced temperatures (0°6396). D. At the respective boiling-points under equal reduced pressures (0-022 11). E. At the respective critical points. | A B C D | E Paraffin —| Nise —= - M.Vol| A |M.Vol| A M.Vol| A M.Vol) A M.Vol| a | | n-Pentane 111°33 | ‘117°80 | 116-13 116-13 309-3 | 15-44 22-13 | 20°09 | 21-06 568 | n-Hexane |126°77 139°93 136:22 137:19 (3661 15°69 22-63 20°18 21-49 | 60-2 n-Heptane 142-46 162°56 156-40 158°68 426°3 | 15-88 23°70 20°54 21:83 | 62°6 n-Octane (158-34 186:26 176-94 180°51 488-9 | ‘ Thus the observed B.P. of »-hexyl formate is 153°-6, and the value of A calculated from the formula is 22°8, giving 176°-4 as the B.P. of the next higher homologue, This agrees very well with the observed B.P. of n-heptyl formate, 176°-7, but not with that of n-hexyl acetate, 169°-2. Again, the observed B.P. of methyl caproate (hexoate) is 149°6, and the calculated value of A is 23°-0, giving 172°6 as the B.P. of the next homologue. The observed B.P. of methyl cenanthylate (heptoate) is 172°-1, but that of ethyl caproate is only 166°-6. * The atomic weights [C=11:97, H=1] employed in the original papers are retained, 494, REPORT—1904, It will be seen that in every case there is a decided rise in the value of A as the series is ascended, but that the rise is relatively smallest when the comparison is made at the particular reduced temperature chosen. At higher reduced tempe- ratures, however, it would be relatively much greater, since it is very marked at the critical point, where the reduced temperature =1. The rise is also compara- tively small at the common temperature 0°, but the comparison would not be satisfactory if a higher common temperature, say 150°, were chosen, because the coefficients of expansion differ considerably: at 150° the values of A would be 8 75, 13:45, and 15°38 respectively. In the case of nine of the lower esters the values of A are by no means con- stant, whether the comparison be made at 0°, at the boiling-point, or at the critical point, The eleven values of A vary in the three methods between 16:34 and 18°21, 20:84 and 23°42, 54:3 and 61-7 respectively; but there is not a regular rise with increase of molecular weight. Both Kopp and Schroder compared the molecular volumes of compounds at their boiling-points under normal pressure, but they deduced quite different values for the atomic volumes of carbon and hydrogen; it is clear, however, that as A varies considerably no values whatever for C and H could give accurate results, even in the case of true homologues. Traube makes the comparison at a common temperature, usually 15°, and takes into consideration both the actual volumes of the molecules and the co-volume, which he assumes to have the same value, 24:5 (1+ at), where a= 1/273, for all substances. He calculates definite values for the atomic volumes of C and H. at a given temperature; thus, at 15°,C=9°9 and H=3:1, or CH,=16:1, so that here again the difference for CH, at a given temperature should be constant, It does not appear to me that the problem has yet been completely solved, although Trauhe’s method of calculation generally gives much better results than those of Kopp and Schroder. Comparison of Boiling-points at a Series of Equal Pressures, The results of this comparison are often exceedingly simple if the two sub- stances compared are very closely related, and if there is no molecular association in either case. Taking, for example, chlorobenzene and bromobenzene, it is found that the ratio of the boiling-points (on the absolute scale of temperature) under equal pressures is constant whatever the pressure may be, or 1, _ Ts. 1.0590. T; Ts A similar result is obtained with the other halogen derivatives of benzene, with ethyl bromide and ethyl iodide, with ethyl acetate and propyl acetate, and some other pairs of esters; but in some cases of close relationship—for example, with ethyl formate and ethyl acetate—the ratio is not quite constant, and the formula becomes a= a5 + ¢e(T,—T’,), where c has a very low value [0:0000417 for these two esters. When there is no close relationship, but the molecules are not associated, the value of ¢ is usually larger—for example, 0:0001185 for carbon disulphide and ethy! bromide. Lastly, when there is no close relationship and the molecules of one or both substances are associated, the formula = = = +ce(T;—T’;) may no longer hold, B B and a third term may be required, thus: = = = + ¢e(T, —T’,)+d(Ts—T’,)?; or, B B in any case, the value of ¢ becomes much higher, as with benzene and ethyl alcohol [¢ = 0:0008030] or sulphur and carbon disulphide [¢ = 0:0006845]. TRANSACTIONS OF SECTION B. 495 Behaviour of Liquids when Mixed together. There are three points to consider when two liquids are brought together— (1) their miscibility, whether infinite, partial, or inappreciable; (2) the relative volumes of the mixture and of the components ; (8) the heat evolved or absorbed. Liquids which are classed as non-miscible rarely, if ever, bear any close chemical relationship. Thus water is practically non-miscible with all hydro- carbons and with their halogen and many other derivatives; again, mercury, so far as I mow, is not miscible with any liquid compound, organic or inorganic. It is true that the higher aliphatic alcohols are almost insoluble in water, although there may be said to be some chemical relationship between them, inasmuch as an alcohol may be regarded as an alkyl derivative of water. But the alcohols may also be looked upon as hydroxyl derivatives of the hydrocarbons, and, the higher the formula weight of the alkyl group, the greater is its influence, rela- tively to that of the hydroxyl, on the properties of the alcohol. Thus, while the lower alcohols show considerable resemblance to water—for example, in their behaviour with dehydrating agents, such as sodium, phosphoric anhydride, or lime, and in their power of uniting with metallic salts to form crystalline alco- holates corresponding to the hydrates—this resemblance diminishes as we ascend the series, and is generally not observable with the higher members. On the other hand, the higher the molecular weight of the alcohol the closer is its resemblance to the hydrocarbon from which it is derived. This, as already mentioned, is well shown by the diminishing difference between the boiling-points of the aleohol and paraffin as the series is ascended; it may also be noted that methane was long classed as a permanent gas, while methyl alcohol is a liquid ; whereas both hexdecane (C,,H;,) and cetyl alcohol (C,,H,,0H) are solids, the former melting at 18° and the latter at 50°, It may, in fact, I think, be stated that the chemical relationship between water and methyl alcohol is fairly close, while that between water and cetyl alcohol is very distant. So, also, two adjacent members of a homologous series, such as methyl and ethyl alcohol, are more closely related than two members of widely different molecular weight, such as methyl and cetyl alcohol. Adopting this view, it is, I believe, safe to state that liquids which are chemically closely related to each other are invariably miscible in all proportions. As regards the relative volumes of a mixture and of its components at the same temperature, it is well known that inequality is the rule and equality the exception; and, further, that contraction is more frequently observed than expansion on admixture. So far, however, as experimental evidence is available, it appears that when the liquids are very closely related to each other the change of volume is exceedingly small. For example, with ethyl acetate and propionate in equimolecular proportions, + 0-015 per cent.; toluene and ethyl benzene, — 0-034 per cent.; 2-hexane and n-octane, — 0:053 per cent.; methyl and ethyl alcohol, + 0:004 per cent.; chlorobenzene and bromobenzene, no change. When the relationship is less close the changes are usually, but not invariably, larger, and are in some cases positive, in others negative ; and it is rarely possible, in the present state of our knowledge, to predict from the nature of the sub- stances—unless one is basic and the other acidic in character—whether contraction or expansion is to be expected. Thus, when methyl alcohol is mixed with water considerable contraction occurs, although the relationship is less close than between methyl and ethyl alcohol, which expand to a minute extent on mixing. All we can say with regard to the alcohols is that, the higher the molecular weight—or, if isomeric alcohols are included, the higher the boiling-point—the smaller, as a rule, is the contraction on mixing with water. Very similar remarks apply to the heat changes which occur on mixing liquids. It appears that in the case of very closely related substances these changes are exceedingly small, or negligible, as is indicated by the very minute change of temperature which has been observed, thus: ethyl acetate and propionate, — 0°-02; toluene and ethyl benzene, + 0°05; n-hexane and n-octane, + 0°06; methyl and ethyl alcohol, — 0°:10; chlorobenzene and bromobenzene, 0°00, 4.96 REPORT—1904. It might be expected that in the case of less closely related substances con- traction would be accompanied by evolution of heat and expansion by absorption of heat, but this is by no means invariably the case; for example, on mixing 40 gram-molecules of propyl alcohol with 60 gram-molecules of water there is a contraction of 1:42 per cent., but a fall of 1°15 in temperature was observed. Taking the alcohols as a group, it is found that, the higher the boiling-point, the smaller is the heat evolution or the greater the absorption on admixture with water. Properties of Mixtures. The behaviour of two non-miscible liquids when heated together is well known, and I need only refer to the fact that the vapour pressure is equal to the sum of the vapour pressures of the pure components at the same tem- perature; that the boiling-point is the temperature at which the sum of the vapour pressures of the components is equal to the pressure under which the liquid is being distilled, provided that evaporation is taking place freely and the vapour is not mixed with air; and, lastly, that the composition of the vapour is independent of that of the liquid (so long as both components are present in sufficient quantity), and is expressed by the equation = ~ a Us BU, and «2, are the relative weights of the two components in the vapour, P, and P® their vapour pressures at the observed boiling-point, and D, and D, their vapour densities. The vapour pressure, boiling-point, and vapour composition, then, can be calculated for non-miscible liquids, and it has been stated that such liquids have never any close chemical relationship, and are usually not related at all. On the other hand, it has been mentioned that when the chemical relationship is very close the liquids are invariably miscible in all proportions, and that there is very little, if any, volume or heat change on admixture. So, also, the vapour pressure and boiling-point of a mixture of closely related liquids are easily ascertained from those of the pure components, and the com- position of the vapour bears a simple relation to that of the liquid. The vapour pressure of the mixture is given, at any rate with a very close approach to accuracy, by the equation P = mP, + es ait) Pp where P, Py, and P, are the vapour pressures of the mixture and of the components, A and B, at the observed boiling-point, and m is the molecular percentage of A. Van der Waals concluded from theoretical considerations that this relation should be true when the critical pressures are equal and the molecular attractions agree with the formula proposed by Galitzine and by D. Berthelot, a,..= 4/4;'@2, where a,., represents the attraction of the unlike molecules and a, and a, the respective attractions of the like molecules. That is certainly the case with chlorobenzene and bromobenzene, which, as already mentioned, show no heat or volume change on admixture, for the maximum difference between the observed and calculated pressure in three experiments was less than 0°1 per cent. But the relation is, at any rate, very nearly true for closely related substances when the critical pressures are not equal, for in the case of methyl and ethyl alcohol the difference between the observed and calculated pressure was within the limits of experimental error, and with four other pairs of closely related substances the greatest mean difference (for three readings each) was only 0°6 per cent. It is not, however, as Speyers suggested, true for all non-associated substances, whether closely related or not; indeed, chemical relationship seems to be much more important than the state of molecular aggregation, for the relation is true for methyl and ethyl alcohol, while it is altogether untrue for benzene and hexane. The boiling-point of a mixture of closely related liquids may be ascertained from the vapour pressures of the components, but not so simply as in the case of non-miscible liquids, because the boiling-point depends on the composition of the liquid, » Where 2, TRANSACTIONS OF SECTION B. 4.97 In erder to calculate the boiling-points of all mixtures of two closely related _ liquids under normal pressure we should require to know the vapour pressure of each substance at temperatures between their respective boiling-points under that pressure. Thus, chloroform boils at 132°0, and bromobenzene at 156°-1, and we must be able to ascertain the vapour pressure of each substance between 132° and 156°. The percentage molecular composition of mixtures which exert a vapour pres- sure of 760 mm. must then be calculated at a series of temperatures—say every two 2) degrees—between these limits by means of the formula m=100. aes , where, in this case, P = 760. aa Py Lastly, the molecular percentages of A, so calculated, must be mapped against the temperatures, and the curve drawn through the points will give us the required relation between boiling-point and molecular composition under normal pressure. In the case of six pairs of closely related liquids the greatest difference between the observed temperature and that read from the curve constructed as described was 0°27. For liquids which are not closely related the differences are usually much greater, and particular mixtures of constant (minimum or maximum) boiling-poirt are not unfrequently met with, especially when the molecules of one or both substances are associated in the liquid state. The formula for the composition of the vapour from a mixed liquid suggested independently by Berthelot and by Wanklyn, ts. WiPAD, tz _W5P3Ds and P,,, D, and D,, have the same meaning asin the equation for non-miscible liquids, and W, and W, are the relative weights of the two components in the liquid mixture), was shown by F. D. Brown to be incorrect, and he proposed the simpler (where 2, and zs, Ps Va = A formula, lee ow, The subject was investigated mathematically by Duhem and by Margules, and experimentally and mathematically by Lehfeldt and by Zawidski, The two last- named observers deduced workable formule from the fundamental equation of Duhem and Margules, and it is noticeable that both Lehfeldt’s and Zawidski’s formule, in their simplest form, become identical with Brown’s. Zawidski’s, how- where ¢ is a constant which does not differ greatly from a B ever, assumes the form “t= P. F Ww: This formula is certainly not, as a rule, “B B B true for mixtures of liquids which are not closely related; but, on the other hand, in the very few cases examined the equation “*=c . ws = a B mP, + (100—m)P® 100 appears to hold for those mixtures for which the equation P = is true; that is to say, generally, for closely related liquids, The question, however, whether c= ™ is an open one; but it is interesting to B remark that if this equality holds it should be possible in many cases to calculate the vapour pressure at any temperature, the boiling-point under any pressure, and the composition of the vapour, of any mixture of two very closely related liquids, if the boiling-point of one of them under any one pressure, and the vapour pressures of the other within sufficiently wide limits of temperature, are known. For the boiling-points on the absolute scale of the two liquids at the same pressure bear a constant ratio to each other, or = = = ; hence the vapour pressures or boiling- B B points of one substance can be calculated if those of the other are known. Again, from the vapour pressures of the pure substances we can calculate the vapour pres- sures and the boiling-points of all mixtures; and, lastly, if c= Pp” we can make use B of Brown’s formula, “* = as to calculate the composition of the vapour from 1904. KK 498 REPORT—-1904. all mixtures without carrying out special experiments to find the value of ec. Itis, therefore, a matter of considerable interest to ascertain whether c is really equal to Pa mP, + (100—m)Ps 100 cation of Brown’s formula, or that of Lehfeldt, or of Zawidski, must be employed to calculate the vapour composition, and the constants for those formule must first be determined experimentally. Other physical properties, such as the refractive power of mixtures, might be considered, but I will only refer to the critical temperature and pressure. In 1882 Pawlewski stated that the critical temperature of a mixture could be calculated m6, + (100 — m)6z 100 : is the percentage by weight of A; and G. C. Schmidt, in 1891, carried out experi- ments to test the correctness of the statement, purposely choosing substances of widely different physical properties. The differences between the calculated and observed temperatures were not, as arule, very great, rarely exceeding 4°, and Schmidt considered that they might, to some extent, be accounted for by partial decomposition of one or other component. Such determinations are, however, liable to serious errors. It is exceedingly difficult to filla tube with the required amount of a liquid mixture of known composition quite free from air, and, although the composition of the very small amount of liquid employed might be determined after the experiment from its specific refractive power, it would be necessary to know the specific refractive powers of the two components and of mixtures of them. Schmidt does not state how he prepared his mixtures and determined their composition. Again, when a liquid mixture is heated in a sealed tube, fractionation goes on, so that the more volatile component tends to accumulate in the upper part of the tube, leaving the less volatile component in excess below, and unless a stirring arrangement, such as that devised by Kuenen, is employed, many hours would elapse before complete admixture by diffusion took place at the critical point. By far the most important and accurate experiments on this subject have been carried out by past or present pupils of Professor Kamerlingh Onnes, notably by Professor Kuenen; and it is quite certain that the formula of Pawlewski cannot be generally true for mixed liquids, for, just as we may have mixtures of minimum or maximum boiling-point, so also, as Kuenen has shown, mixtures of minimum or maximum critical temperature may exist, Thus the critical temperature of carbon dioxide is 31°1, and of ethane, 32°:0, but that of a mixture containing 30 molecules per cent. of carbon dioxide is 18°8. The question remains, however, whether some such law as that proposed by Pawlewski may not hold good for closely related substances. In certain cases, when the relationship is very close (for example, C,H,Cland C,H,Br), the critical pressures are equal, or very nearly so, and it seems probable that the critical pressure would be the same for any mixture as for the components. Such a case as this would be likely to give the simplest possible relation between the critical temperatures of a mixture and those of its com- ponents ; and although the critical temperatures of these substances are incon- veniently high, there are, no doubt, others which might be employed—perhaps etbyl chloride and bromide, or possibly carbon dioxide and carbon disulphide. I imagine, however, that Pawlewski’s formula would be more likely to hold if m represented the moleculur percentage, and not the percentage by weight of A. In the case of homologous compounds, paraffins, ethers, esters, and so on, the critical pressures are not equal, and it would be necessary to find whether the mPa + (100 —m)Px 100 (where m is the molecular percentage of A), and also whether any such simple formula is applicable to the critical temperatures. Kuenen has made some observations with mixtures of ethane and butane con- taining 2°5 and 5 molecules per cent. of butane, and at the conclusion of his paper When the equation P = does not hold good, a modifi- from those of the components by the formula 6= where m critical pressures of mixtures are represented by the formula P = TRANSACTIONS OF SECTION B. 499 he says: ‘If there was a simple law connecting the critical constants of mixtures with those of the constituents, we might calculate the constants for the second substance [those of the first being known]. But such is not the case. Pawlewski’s law that the critical temperature is proportional to the composition, expressed in weight units, is very inaccurate, the deviations being sometimes considerable in both directions.’ It would, I think, be of great interest if Professor Kuenen could find time to carry out further experiments with mixtures of ethane and butane in order to settle this point, or, perhaps, with n-hexane and n-octane, both of which can be more easily obtained in a pure state. From what has been said it may be concluded that, in order to ascertain the normal behaviour of pure substances under different conditions, or to find the simplest relations between the boiling-points, molecular volumes, or other physical constants of a series of substances, or, again, to ascertain the normal behaviour of substances when mixed together, and the properties of the mixtures as compared with those of the components, it is undoubtedly advisable—at first, at any rate— to confine our attention to substances of which the molecules show no signs of association in either the gaseous or liquid state. In the case of mixtures it is also best to begin with substances which are chemically closely related to each other. The following Papers and Report were read :— 1. The Relation between the Crystalline and the Amorphous States as disclosed by the Surface Flow of Solids. By G. T. Brizpy, In former papers the phenomena observed in connection with the flow of solids have been fully described, and in the most recent of these the results of the observations have been applied to the study of the hard and soft states in metals. The purpose of the present paper is to direct attention to the very general character of the relations which have been found to exist between the amorphous and the crystalline states. Observations on flow in crystalline substances are described and illustrated by photo-micrographs. By the use of etching in stages the successive layers of a polished or disturbed surface are disclosed, from the smooth vitreous surface, through a granular layer, to the undisturbed crystalline body beneath. The demonstration that the polish of a lens of rock crystal has resulted from the formation of a flowed layer of amorphous phase on its surface suggests that no crystalline substance is too hard to yield to the mechanical flowing action. The passage of the amorphous back to the crystalline state by the agency of heat is discussed, and attention is directed to the important bearing of the fact that this transformation occurs at a definite temperature, on the behaviour of solids at ordinary atmospheric temperatures. It is suggested that as the stability point of ice is probably a long way below the freezing point, the amorphous phase can only have a transient existence at ordinary atmospheric temperatures; while at the lower range of winter temperatures within the Arctic Circle, the amorphous phase, once formed, may be stable and permanent. The grinding of crystalline substances to powder does not simply consist in their reduction to finer and finer crystalline fragments, but it involves the transfor- mation of at any rate a part of the substance into the amorphous condition. When crystalline powders are formed into cakes by pressure the cementing material is the amorphous phase which results from flow. In metals, and probably in most other solids, the physical and other properties of the two phases are so distinct that it is not difficult to determine the transition temperature or stability point in the transformation A > C. * _ From the existence of a definite stability point it is argued that not only must all crystalline substances be capable of existing in the amorphous as well as in the crystalline state, but that, by purely mechanical means, it is possible to transform them into this state. EK2 500 REPORT—1904. These observations, and the conclusions to which they have led, have a very direct: bearing on the flow of rocks. The recognition of the transformation from crystalline to amorphous through an intermediate mobile phase, for the first time supplies an explanation of why flow which has been started by stresses can cease while the disturbing stresses are still maintained. 2. The Action of certain Gases on Glass in the Neighbourhood of Hot Metals. By G. T. Beivpy. In a former paper (‘ British Association Report, 1903’) the formation of halos of decomposed glass around pieces of metal placed on glass plates and heated in a muffle to which the products of combustion had access was described. Further experiments and observations have been made to ascertain (1) To what chemical agent is the decomposition of the glass due? and (2) What is the cause of the localisation of this decomposition in the immediate neighbourhood of the hot metal as shown in the formation of halos and images ? By passing various gases over heated glass slips on which pieces of metal foil were placed, it was found that the most active agents in the decomposition of the glass were sulphur dioxide, air, and water vapour. The decomposition products of the glass were ascertained to be sodium or potassium sulphate and silica. In the original experiments, in which the products of combustion had access to the muffle, the source of the SO, was the trace of sulphur compounds in the coal gas used for heating. The actual attack on the glass is made by sulphur trioxide formed by the oxidation of the SO,,. The dull white film frequently seen on the outside of tubes or other glass vessels which have been heated in a gas furnace or muflle is no doubt due to the decomposition of the glass by the combustion gases, The second question, as to the cause of the localisation of the decomposition, cannot be answered so conclusively as the first. The active agent being SO,, the suggestion naturally occurs that its formation from SO, and air is accelerated by the presence of the hot metal, which acts as a catalyte. The question was discussed whether in this case the combination of these gases takes place on the surface of the metal or whether it takes place to some extent in the surrounding atmosphere. The appearances suggest that the agent which caused the decomposition had been in the form of a detinite cloud of particles shot out from the metal surface rather than in the form of widely diffused molecules of SO, in a very large volume of air. While no traces of metal could be detected in the halos or images, it does not seem necessary to suppose that the particles thrown off by the metal must be either visible or ponderable in order that they may produce very powerful effects. It cannot be claimed that these observations give a final answer to the second question proposed ; but they certainly do not give a final negative to the sugges- tion that some part of the effect may be due to the slow disintegration of the metal. 3. On the Formation of Salts in Solutions, especially amongst Tautomeric Compounds. By Professor J. W. Bruny. 4, Methods of Investigating Alloys, illustrated from the Copper-Tin Series. By C. T, Heycock, /.A.S., and F. H. NEvitie, “2.8. TRANSACTIONS OF SECTION B, 501 5, Hexachlor-a-Picoline and its Derivatives. By W. J. Seti, IA., F.R.S, With the object of assisting in the orientation of some of the lower chloro and other derivatives of pyridine it was thought advisable to study the action of chlorine on the hydrochlorides of various methylpyridines. The substance employed to begin with was a-picoline after purification of its double salt with mercuric chloride. The chief solid product of the chlorination of a-picoline is a white crystalline substance having the formula C,HC1,N, and which readily gives trichlorpicolinie acid on heating with 80 per cent. sulphuric acid; it therefore contains the fully chlorinated methyl group CCl,, which, as usual, breaks down to COOH with elimination of HCI. Trichlorpicolinic acid when distilled with glycerine is readily resolved into a trichlorpyridine (m.p. 72-8°), first obtained by Keiser, and described by him as the hydrochlorate of a dichloropyridine, but since shown by Sell and Dootson to be a trichlorpyridine. The positions of the chlorine atoms in this compound are unknown, but various considerations lead to the supposition that they occupy the positions 3, 4, 5. i To prove that this is so, recourse was had to the synthesis from the trichlor- picolinic acid of a compound whose constitution is established. Such a substance is 2-amino-3, 4, 5-chlorpyridine. The trichlorpicolinic acid was converted into the amide, and this into the amino derivative by the Hofmann reaction, On comparison the aminotrichlorpyridine was found to be identical with the 2-amino-3, 4, 5-trichlorpyridine obtained from other sources, 6. The Change of Conductivity in Solutions during Chemical Reactions. By P. V. Bevan, JA. The experiments described in this paper were made to determine, if possible, the part played by the hydrogen ions of the acid used in the inversion of cane sugar. The object was to attack the problem of catalytic action by applying the Kohlrausch method of determining the conductivity of the solution. It seemed certain that, the action being conditioned by the presence of the hydrogen ions, their capacity as carriers of the current must be affected, and so it was thought that some light might be thrown on the actual mechanism of the action. If the resistance of a solution of cane sugar with a small percentage of hydrochloric acid be obtained at various stages of the inversion, a change of resistance, which may amount to 10 or more per cent. of the initial resistance, occurs during the inversion. Two factors which contribute to this change are the loss of water during the inversion and the change of the ionic viscosity of the solution conse- quent on the transition from the cane to the inverted sugar. The results so far obtained have not enabled me to discriminate between the various causes pro- ducing the total effect. Another series of experiments was made determining the conductivity of solutions containing a constant quantity of sugar per volume but a varying amount of acid. On plotting the concentration (HCl) and_ specific molecular conductivity one obtains a curve, which at concentrations down to about ‘005 normal is a straight line parallel to the concentration axis, but for concentrations lower than this the curve drops towards the concentration axis ; the specific molecular conductivity decreasing at a concentration of ‘0002 norma), there are indications that the curve becomes again parallel to the axis of concen- tration, At this small concentration, however, the observations so far made are not very consistent, and at present stress is not laid on this point. The experiments show in this way an effect on the molecular conductivity, which can be explained by supposing the H-ions are loaded up, forming the centre of a group consisting of one or more sugar molecules and one or more water molecules. This kind of group need not be considered as a stable compound, but may be merely in a state where it can split easily into water and cane sugar again, or in some cases 502, REPORT—1904. into the invert sugars. At higher concentrations than the value at which the specific molecular conductivity becomes constant the proportion of H-ions loaded in this way is small at any particular time; hence we see that we may explain on these lines the influence of concentration of the sugar on the rate of inversion. Further experiments are in progress, and it is hoped that experiments on the actual velocity of the ions in the inversion with dilute acid may lead to some definite results. 7. On Double Acetylides. ty Major A. FE. Epwarns and Professor W. R. Hopaxryson, Ph. D. The authors have investigated the action of acetylene on a number of salts with a view to obtaining an explosive of a sufficiently safe nature to be used for military purposes, and referred in this paper to some silver compounds which they have obtained. The acetylene employed was purified as well as possible from sulphur and phosphorus compounds, and was then brought in contact with silver salts in solution or suspended in boiling water, In some cases the gas was passed for some days continuously through the water containing the suspended salts. A number of organic salts, such as silver acetate, benzoate, and butyrate, yield the same acetylide as that obtained from neutral or faintly alkaline silver nitrate solution. A solution of silver nitrate in nitric acid of 1°3 sp. gr. did not give this particular acetylide, but one containing nitric acid as nitrate. Solutions of silver salts in potassium cyanide or in thiosulphate are quite unaffected by acetylene, but pure thiocyanate suspended in water is acted upon; the product in this case is explosive, and contains both sulphur and cyanogen, but was not obtained in a pure state. The following compounds have been obtained in a definite form, analysed and examined as to their sensitiveness to percussion and heat. From a boiling solution of silver bichromate acetylene precipitates an orange- red salt of the composition (Ag,OC,H,,Ag,CrO,), whilst chromic acid is liberated. When dry, this substance is very sensitive to friction, and explodes violently at 157°C. Corresponding compounds are formed from silver sulphate, selenate, tungstate, and molybdate; they are all much less sensitive than the chromic acid compound, and explode much more feebly. Compounds from the phosphate and vanadate were obtained with difficulty, and no satisfactory analyses were made; they explode in a very feeble but peculiar manner. 8. On some Reactions between Ammonium Salts and iletuls. By Professor W. R. Hopexinson, Ph.D., and Artnur H. Coorer. As far back as 1879 a note was published by one of us on the action of aluminium on ammonium chloride, and we have recently continued the investiga- tions of the behaviour of ammonium salts generally towards metals. Ammonium nitrate, either in aqueous solution or in a fused state, acts very vigorously on some metals, There is a notable difference, as a rule, between the fused salt and its aqueous solution in regard to rate of action on the more common metals; but in the case of the metal cadmium there is little difference perceptible between the rate of action of an aqueous solution and the melted salt. Cadmium placed in an ice- cold saturated solution of ammonium nitrate rapidly dissolves without evolution of gas. The liquid becomes alkaline from presence of a little free ammonia; the solution gives off nitrogen only when heated to 100°, when the cadmium ceases to dissolve and some remains in excess. The solution contains a little free ammonia, and apparently the nitrite of cadmium and ammonium. This is, at any rate, indicated by the fact that every trace of cadmium can be precipitated from this solution by passing through it a stream of carbon dioxide at the ordinary temperature, The solution contains mainly ammonium nitrite. TRANSACTIONS OF SECTION B. 503 Zine and magnesium act in a similar mamner, but, owing to the formation of somewhat insoluble double ammonium compounds, not to the same extent or with the rapidity observed with cadmium. Aluminium, iron, mercury, and silver are unaffected by an aqueous solution of the salt, but nickel, copper, and lead are slightly active. Lead becomes coated with a somewhat insoluble nitrite. Melted ammonium nitrite has no action on iron, mercury, or aluminium, and, in fact, these metals are quite unaffected when the salt is heated with them so strongly as to decompose with formation of red fumes; under these conditions silver is slightly attacked. Approximately it may be stated that when the salt is just fused the following metals are acted upon at rates about in the order given: cadmium, magnesium, zine, copper, nickel, lead, bismuth. The mechanism of the reaction as regards cadmium and fused ammonium nitrate seems to be that first a little ammonia is split off and then a metallic nitrate formed. This, however, involves the expulsion of hydrogen, which in turn reduces the nitrate of the metal to nitrite, which immediately reacts with the ammonium salt in the usual manner, liberating nitrogen. Weighed quantities of metals have been allowed to act upon ammonium nitrate in a vacuum-tube maintained at the melting-point of the salt. In the cases of cadmium and copper the gas collected was pure nitrogen; with cadmium the amount of nitrogen collected falls a little short of 4 atoms of nitrogen to 1 atom of metal; with copper it is nearly 3 atoms of nilrogen to 2 atoms of the metal. The amount of ammonia liberated in the first phase of the reaction may have something to do with this deficit of nitrogen, but we are unable to explain it fully at present. Powdered cadmium dissolves in a solution of aniline nitrate, and if the temperature be maintained below 10° no appreciable evolution of gas occurs, and a considerable yield of diazoaminobenzene is obtained. The course of the reaction is very similar to that with the ammonium salt, a little aniline being liberated in the first instance. 9. Report on the Study of Hydio-aromatic Substances.— See Reports, p. 60. 10. The Constitution of Nickel Carbonyl. By H. O. Jones, M.D., D.Se. The study of the chemical reaction of nickel carbonyl, first undertaken in association with Professor Sir James Dewar, has been continued and extended. Nickel carbonyl reacts readily with hydroxylamine in alcohol solution to give a bluish violet-coloured gum which solidifies on standing in a desiccator, is insoluble to all solvents, and is decomposed by water and acids and on heating to 100° C; The action of water and of heat on the compound gives rise to new com- pounds similar in appearance to the original substance, and which react with acids, giving nickel and hydroxylamine salts and carbon dioxide. These compounds have not been obtained pure enough to give analytical results of any value, but the ratio Ni : NH,OH in the original compound is found to be 1 : 4-5, and is probably 1 : 4. Hydrazine hydrate reacts in a similar way, and gives a blue-violet solid com- pound. The formation of these substances shows that nickel carbonyl can react as a ketonic compound. Nickel carbonyl reacts with the alkyl magnesium iodide compounds of Grignard, in some eases violently, to produce dark-coloured oily and solid sub- stances, which contain nickel, magnesium, and iodine, and are decomposed by acids, yielding a mixture of compounds. The product obtained from several aliphatic iodides has been examined, but no pure compound has hitherto been isolated and identified. Some of the compounds produced react with sodium bisulphite, hydroxylamine, and substituted hydrazines, and are very probably ketonic. The product of the action of phenyl magnesium iodide on nickel carbonyl : 504 REPORT—1904. when treated with acids gave rise to a mixture which was found to consist chiefly of diphenyl and benzoin. The former is very readily produced from phenyl magnesium iodide, and is frequently observed among the products of its reactions. ee eter of benzoin has an important bearing on the constitution of nickel carbonyl, All the reactions of nickel carbonyl which have been described previously can be equally well explained by means of either of the two formulz G2 “9 CO—CO 7 =C=0 : Ni G=0Q and NiC | which have been proposed; but benzoin could be produced in a much simpler way from a compound with the second formula, Its production may therefore be regarded as evidence in favour of this, The following suggestion as to the course of the reaction is to be regarded as purely tentative : — C,H, OMgI a /o—CO eK ZOMel Ni | + 4C,H—Mg—I > Ni | CO.H, CO—CO C—C/C,H, we \OMel C,f, OMel ; | H,O and acid C,H; JOH 2C,H,—CHOH A C_c/oH ck a 00 ei NiK |\C.Hs + nickel salt, C—C/C,H /\._ Soil '6**5 OH The product C,H, >C—OH C,H; >C—OH is supposed to undergo molecular transformation into benzoin, 11. A Suggested Explanation of the Phenomena of Opalescence observed in the Neighbourhood of Critical States, By F. G. Donnan. It has been frequently observed (Guthrie, Rothmund, Friedlinder, Kono- walow) that a mixture of two liquids becomes opalescent before the temperature is reached at which definite separation into two phases occurs. Similarly, a mixture of two partially miscible liquids remains opalescent at temperatures beyond that corresponding to the disappearance of the meniscus. Apparently analogous phenomena have been noticed in the case of one-component liquid-vapour systems, especially by Wesendonck and Teichner. The latter has observed the existence of permanent opalescent states in the case of carbon tetrachloride at temperatures several degrees higher than the critical. These phenomena, so far as they refer to mixtures of liquids, have been studied by Konowalow, who considers that they are due to a partial separation into two phases, occurring round dust-nuclei acting as centres of disturbance. Konowalow shows that such a disturbance of equilibrium in the otherwise homogeneous liquid will, in the neighbourhood of the critical solution temperature, involve only a slight expenditure of work owing to . the small change of vapour-pressure with composition under these conditions, TRANSACTIONS OF SECTION B. 505 The author suggests another explanation, which involves the following suppc- sitions :— (a) Below the critical temperature the interfacial tension between the two phases is positive for all values of the radius of curvature. (6) At the critical temperature the interfacial tension becomes zero for all ordinary curvatures, but remains positive for very small values of the radius of curvature. It will be seen that this assumption involves the furthér one, that at the temperature of disappearance of the meniscus at a bounding surface of ordinary curvature (critical temperature) the two phases do not become identical. (c) At temperatures slightly above the critical the interfacial tension is still positive for very small radii of curvature, but negative for all ordinary curvatures. (d) At still higher temperatures the interfacial tension becomes negative for all curvatures, These assumptions carry with them the main assumption that the interfacial tension between two liquid phases increases in general with diminution of the radius of curvature of the bounding surface. This increase, however, need not extend to the very smallest values of the radius of curvature. It is also neces- sary to suppose that the curve connecting interfacial tension with radius of curva- ture of the bounding interface suffers a shift towards the region of negative values of the interfacial tension as the temperature rises, Granting these assumptions, the existence of permanent opalescent states above the ordinary critical point follows at once. For it can be shown that the con- ditions specified, for example, under (c) would produce a system in which one phase would be distributed throughout the other in a state of very fine sub- division. If the particles are small enough, such a system would not present a milky appearance, but would doubtless be opalescent. An interesting question concerning the nature of the critical state is thus raised—namely, as to whether there is not sufficient experimental evidence to justify the belief that the passage of systems through critical states is insufficiently described by the simple theory of Andrews? That is the wider question at issue. The particular form of explanation suggested in the present paper also raises the question as to whether the observed phenomena may not admit of interpretation by taking into consideration the operation of capillary forces ? These points seem worthy of discussion, especially in relation to the theories of ‘ gaseous’ and ‘ liquid’ molecules—‘ Gasonen ’ and ‘ Fluidonen’ devised in recent years by de Heen, Traube, and others. The present communication has arisen out of a correspondence on the subject with Professor van’t Hoff, to whom the main idea is due. FRIDAY, AUGUST 19. The following Papers and Report were read :— 1. On Crystal Structure and its Relation to Chemical Constitution, By Professor Paut Grotu. The molecular hypothesis assumes that in solid bodies the molecular move- ments occur about certain equilibrium positions which can only be altered by the operation of external forces. In crystalline bodies the spacial arrangement of these equilibrium positions must consequently be a regular one. The possible kinds of crystal structure—that is, the kinds of regular arrange- ment cf congruent molecules—were first discussed by Bravais, who described fourteen such kinds of structure and distinguished them as ‘ space lattices.’ Bravais’s theory, however, only explains seven kinds of symmetry which possess the properties of crystal symmetry, and the incompleteness of his work reposes on the introduction of an unnecessary assumption, namely, that the molecules occupy parallel positions. Sohncke discarded this assumption in attacking the problem, 506 REPORT—1904. -gnd merely sought for those arrangements of congruent molecules in which the arrangement of parts is the same about every molecule; he thus arrived at sixty-five regular ‘point systems.’ By the discovery of these, most, though not quite all, of the symmetrical relationships of the properties of crystals became explicable. Sohncke further developed his theory of crystal structure by intro- ducing the assumption that two or more regular point systems, consisting of different kinds of molecules, may be interlaced or supposed to interpenetrate in such a way that equilibrium results. This, however, is only possible when the different point systems possess the same ‘coincidence movements’ (Deckschie- bungen)—that is to say, when they are built up from space lattices of identical dimensions. This form of the theory is also deducible from the theory of regular point systems if the different individual atoms constituting the molecule are con- sidered in place of the centres of gravity of the molecules; each set of analogous atoms then form a regular point system, and, by the interlacing of the several systems, a compound system is obtained consisting of as many component systems as there are kinds of atoms in the chemical molecule. This, the most general theory of crystal structure, may be summarised by the following definition. A erystal—considered as indefinitely extended—consists of » interpenetrating recular- point systems, each of which is formed from similar atoms ; each of these point systems is built up from a number of interpenetrating space lattices, each of the latter being formed from similar atoms occupying parallel positions. All the space lattices of the combined system are geometrically identical or are charac- terised by the same elementary parallelepipedon. In this form the theory is capable of elucidating all the observed regularities of crystal structure, and it is unnecessary to assume the operation of any ‘molecular forces’ in addition to the forces which act upon the atoms themselves. No diffi- culties now arise in ascribing to the atoms the power of assuming a definite orientation, since, according to J. J. Thomson, the atoms are not mere points, but highly complex structures. If acrystal is built up of but one kind of atom it consists of a crystalline element, and is produced from but one kind of regular-point system the properties of which depend upon the forces exercised upon each cther by the similar atoms involved, In the case of a chemical compound, however, there must be just as many regular-point systems in the combined system as there are kinds of atoms in the chemical molecule, and the arrangement of the combined system must correspond with the equilibrium of the forces with which similar and dissimilar atoms act upon each other. On solution, melting, or evaporation of the crystal the combined system separates into its component and freely moving molecules, and the relative posi- tions in space of the point systems or space lattices, composed from the several kinds of atoms, must therefore be such as to correspond with the arrangement of the atoms in the chemical molecule. The difference between the crystalline and the amorphous state thus consists in that in the latter the chemical molecules have a mutually independent existence, whilst in the crystal the idea attached to the term molecule is different, the molecule being regarded only as a group or assemblage of atoms belonging to several interpenetrating point systems. Such an assemblage can under certain conditions be quite an arbitrary one; thus, the structure of crystalline sodium chloride—making the simplest conceivable assumption—consists of a cubic space lattice of sodium atoms and a similar space lattice of chlorine atoms, the latter atoms occupying the mean points in the lattice of sodium atoms. It is obviously a matter of quite arbitrary choice with which of the neighbouring sodium atoms a particular chlorine atom will remain combined as a molecule of sodium chloride when the mole- cules of the latter separate during the passage into the amorphous state by melting, solution, &e. The same considerations naturally hold when, instead of two simple space lattices, two regular-point systems consisting of chlorine and sodium atoms are imagined to coalesce. In this case any multiple of the complex NaCl may be regarded as the ‘ molecule,’ and thus has arisen the failure of all attempts hitherto made to determine the molecular magnitudes of crystalline bodies, TRANSACTIONS OF SECTION B, 507 In order to ascertain the crystal structure of a substance with any degree of probability the most complete possible knowledge is required concerning it, such as of its optical properties, its cohesion relationships, the orientation of its different solubility directions (etch figures), and more especially the knowledge of its crystalline form under the most widely differing conditions of formation. If the product of only one crystallisation is examined, the possibility is incurred that the crystals so produced exhibit casual forms developed under quite special conditions of growth; and only by investigating many different crystallisations separated from different solvents under different conditions of temperature, &c., does it become possible to recognise those faces the development of which is most favoured during growth or, what is the same thing, to learn which planes are parallel to the greatest density of structure. Ifthese planes are taken as the elementary faces, it is always found, not only that they are identical with the cleavage plane, with the most stable plane of twinning, &c., but also that the other forms present on the crystal assume the simplest indices. The greater the number of forms observed upon the crystals, so much the greater is the probability of being able to choose the correct elements for the crystal, because the faces most likely to be favoured during the growth of the crystal are those the indices of which are composed of the simplest numbers. Jlaving found the correct elements of the crystal, it is a simple matter of calculation to ascertain the ratio of the three parameters and the angles of the elementary parallelepipedon upon which the structure of the crystal is built up, and which is therefore a prime characteristic of the structure. Since the equilibrium in a crystal structure is dependent on the conditions of movement of the component atoms, the stability of the equilibrium must alter with the temperature; and since each form of structure may possess several stable equilibrium positions of different degrees of stability, it follows that a particular crystal structure will assume the most stable of the possible kinds of equilibrium only within a certain range of temperature, constant pressure being assumed. Outside these limits other kinds of arrangement will be in more stable equilibrium, and on exceeding the limits a discontinuous change of all the physical properties of the body will occur—that is to say, a change into another modification of different crystal structure will ensue. Polymorphism, the property of existing in different crystalline phases, must be distinguished from polysymmetry, or the power possessed by pseudosymmetrical crystals of forming apparently simple crystals of higher symmetry by repeated twinning. Amongst the latter the change into the form of true higher symmetry can indeed take place at a specific temperature, but the change is not accompanied by a discontinuous change in the density and the specific heat. Amongst the truly polymorphous bodies, however, even when the crystalline forms of the several modifications exhibit a certain similarity, so great a dissimilarity still exists between them in physical and erystallographical respects that the various modifications must be referred to quite ditterent elementary parallelepipeda. A difference in the crystal structure is thus introduced, and this may arise from the regular point systems, which compose the combined system, consisting each of one or of several space lattices. On comparing the polymorphous relationships of two different but chemically similar substances it 1s found that the temperature (or pressure) limits of the stability of the several modifications are not the same—thus, considering analogous chloro-, bromo-, and iodo-compounds, it is often observed that the temperatures of change for the chloro- and bromo-compounds are lower than for the iodo-com- pound, just as is often the case with the melting-points of such analogous sub- stances. As a result totally different polymorphous modifications of the various members of analogous series exist at one and the same temperature. The foregoing leads to the definite conclusion that the relationships between the crystal structures of two chemically related substances can only be recognised if their corresponding modifications are available for comparison; every chemico- erystallographical comparison of two or more substances must therefore be based upon a study of the polymorphism relationships. If the existence of correspond- ing modifications is established by such a study, the further complete investiga- tion of these forms leads to the determination of the most probable values of the 508 REPORT—1904, dimensions of the elementary parallelepipeda of the crystal structure; by taking the planes of the elementary parallelepipedon as the basis for assigning symbols to the crystal faces, the so-called ‘elements’ of the crystal give immediately the angles, a, 8, and y, and the relative lengths a: 6 : ¢ of the sides of the elementary parallelepipedon, The elements of the two comparable substances being 1, a: b,: ¢, and a,, B,, y; Zs, Ae 3 by > Cy aNd Gy) Boy Yos the comparison of the two sets of elements, if all the other necessary conditions are fulfilled, permits the determination of the alteration which ensues in the structure of the crystal 1, if it be converted by substitution into the substance of crystal form 2, This alteration may be regarded as a ‘ homogeneous deformation’ of the parallelepipedon, because a homogeneous edifice—the crystal structure of form 1 becomes thereby converted into another homogeneous edifice—the crystal structure of the crystal of modification 2. The character of this deformation cannot be recognised through the comparison of the axial ratios of the two sub- stances if these are stated in the ordinary way, but can only be ascertained if the axial ratios are expressed in terms of the same unit. For this purpose an exact determination of the specific gravity of the two substances is made and the ‘equivalent volume’ calculated therefrom; the dimensions (parameters) of the elementary parallelepipeda can then be at once referred to the same unit, namely, to the side of a cubic elementary parallelepipedon of a substance of which the molecular weight is equal to the density (equivalent density —1). Such comparable parameters are termed the ‘ topical axial ratios,’ and are described as x, y, and o. The comparison of the following substances may be quoted as a simple example. Ammonium iodide erystallises in hexahedra and exhibits a perfect cleavage parallel to {100}, so that its crystal structure is undoubtedly hexahedral or cubic. Tetramethylammonium iodide crystallises in the tetragonal system and shows per- fect cleavages parallel to {100} and {001}; its most probable crystal structure therefore differs from that of ammonium iodide only in the ratio of the axes a and c, The direction in which the crystal structure has been altered by the sub- stitution of 4H by 4CH, is seen by a comparison of the topical axial rativs; as the following table shows, the principal axis c has undergone no noteworthy change, but the parameter of the two axes a and d is much greater in the methylated com- pound. Tetraethylammonium iodide is similarly tetragonal and exhibits a regular increase of the parameter of the two equal axes in the same direction ; the increase in the equivalent volume is also quite regular during the transition from 4H to 40H, to 4C,H;. On further attempting to lengthen the dimension a and 6, by exchanging 4C,H, for 4C,H.,, a quite different deformation comes into play. Asa result of this » and increase, and y decreases. NH, N(CH;),I_ = N(C,H;),I N(C,H,)4I 05'9. Equivalent volume 57°51 108°70 162-91 255°95 = 3:860 5°319 6:648 6-093 v= 3 860 5-319 6648 7851 w= 3-860 3 842 3°686 4:933 The so-called morphotropic relationships between numerous organic substances which have been brought to light during many years past consist mainly in the observation that the substitution of H by CH,, NO,, OH, &c., gives rise in many cases to but partial changes in the crystalline form. In order, however, to deter- mine the direction of deformation, as has been done above for the alkylated ammonium iodides, all the substances must be studied in accordance with the principles laid down above, and their specific gravities determined; further, in cases in which no morphotropic relationships can be traced it must be ascertained whether the substances compared are not different—non-corresponding—modifica- tions. Regularities from which conclusions can be drawn concerning the position of the atoms or atomic groups in the crystal structure can only be traced as a result of this kind of complete investigation of long series of chemically related TRANSACTIONS OF SECTION B. 509 compounds, ‘That such conclusions can be drawn is evident from the above example. The only study of related substances which satisfies all the requirements noted above is to be found in the brilliant work of Tutton on_the sulphates and selenates; this relates to the comparatively small changes which result from the replacement of K by Cs, Rb and NH, in so-called ‘isomorphous compounds.’ In spite of the smallness of the changes produced, Tutton has been able to establish definite relationships between the atomic weight of the metal concerned and the crystal structure, and his work therefore stands as a sample of the way in which chemico- crystallographical investigations must in the future be carried out for the purpose of determining the mutual relationship of the crystal structure and the chemical substance. As is well known, isomorphous substances possess the power of forming homogeneous mixtures, and, since in these mixtures the properties continuously change with the composition, they have been described as ‘ solid solutions.’ Such a miscibility often exists, however, within certain limits between substances possessing totally different crystal structures, so that the solidification curves of the molten mixtures of such substances show just the same relationships as if the mixtures had been made from two truly isomorphous materials. It is therefore incorrect to conclude that two substances are isomorphous from an examination of the melting and solidification curves of their mixtures. Ouly those substances which exhibit corresponding crystal structures as a result of their chemical analogy can be regarded as isomorphous; mixed solutions of two such substances may be caused to deposit apparently homogeneous crystals in which the atoms of one element are partially replaced by atoms of another without overthrowing the equilibrium of the crystalline structure. ‘The preserva- tion of the equilibrium will clearly be the more easy the less the differences between the forces determining the crystal structure in the two isomorphous substances, and the less therefore also the difference between the two crystal structures. The properties of the mixture must be immediately deducible additively from those of the components ; thus, for instance, each component must preserve its individual specific gravity in the mixture, as has been shown by the careful investigations of Retgers to be the case. Lastly, the facts which Kipping and Pope have brought to light in connection with optically active and racemic compounds can be brought into unison with the above discussion on crystal structure. The crystal structure of a racemic com- pound contains a regular-point system of carbon atoms, one half of which is the mirror image of the other half—the other atoms present in the compound form point systems similarly arranged and constituted—whilst the pseudoracemic substances stand to the active components in the same relation as polysymmetric substances. The object of the author is to state clearly the point of view in accordance with which previous investigations must be developed in order that generally applicable conclusions can be deduced therefrom. 2. On Dynamic Isomerism. By T. M. Lowry, D.Sc.—See Reports, p. 193. 3. The Constitution of Phthalein Salts. By Professor Ricuarp Meyer, The author gave an account of his experimental work on the constitution of phthalein salts at the last Versammlung deutscher Naturforscher und Aerzte at Cassel.! Phenolphthalein itself is colourless and is generally regarded as a lactone, whilst the quinonoid formula is assigned to its red alkali salts by the majority of ' Ber. d. deutsch. Chem, Ges., 36, 2949 (1903). 510 REPORT—1904. chemists. J luorescein, being coloured both in the free state and in the form of salts, is regarded as being quinonoid either when free or combined. Quinolphthalein (I), the constitution of which has been confirmed by work dene in the author’s laboratory, does not come into quite the same category, and its red alkali salts must be supposed to possess a meta-quinonoid constitution (II or III). C,4,.CO 44 C,H,.COOH | +N e 7 ~ Haw a 4 x FO ae ue A ye \ou Ho % D\ \ Neo | I | | Lae | aos IRIN 29 fade \ iL ARTO Se a —y \Y my, or Nid wy O O Metaquinones being at present unknown, further work on the above substances was desirable, and the author and his assistant, Mr. O. Sprengler, have therefore studied the ethers and oximes of phenol- and quinol-phthalein, preparing these substances in alkaline solution; the results of this work point to the lactonic formula of the alkali salts as being correct, both in the case of quinolphthalein and of phenolphthalein. They drew attention recently to the fact that the anilides of the phthaleins dissolve in alkali without giving rise to coloration; if these anilides have the same constitution as the phthaleins themselves, this dis- tinction might arise from a difference in basicity. They therefore endeavoured to ascertain the equivalents of these substances. A measured volume of standard caustic-soda solution was treated for two hours at the ordinary temperature with an excess of phenolphthalein; in a second and a third experiment quinolphthalein and phenolphthalein anilide were subjected to similar treatment. The undis- solved residue was filtered off and washed, the filtrate being then precipitated with dilute sulphuric acid; the precipitates were filtered, washed, dried, and weighed. The results agreed with the formulee— C,,H,,0,Nay, O,,H,,0,Na,, and C,,H,,0,(NC,H,)Na,. Thus all three compounds behave alike as dibasic acids, and from this point of view no difference is traceable between the anilide and the free phthaleins; the anilide is, however, more feebly acidic than the phthaleins, being precipitated by the latter from its alkaline solution. These experiments have some bearing on those described recently by A. G. Green and A. G. Perkin; but the results of these investigators differ from the present because they worked under different conditions. The authors have made many attempts, under varied conditions, to obtain a quinonoid ether of phenol- or quinol-phthalein, employing methyl iodide and methyl sulphate both in aqueous and alcoholic solutions, and using an excess of alkali and also of sodium methoxide. In each case the same di-ethers as before TRANSACTIONS OF SECTION RB. 511 were obtained ; they are colourless, and doubtless possess a lactonic constitution. Only when the neutral sodium salts of the two phthaleins are treated two new compounds are formed, in addition to the well-known di-ethers. These substances proved to be the mono-ethers, C,,H,,0,,0CH, and C,,H,,0,OCH,, and are not carboxylic but hydroxylic ethers; they could not be saponified, and on further treatment with alkyl salts yielded the lactonic ethers, They do not decompose sodium carbonate, and hence do not contain a free carboxyl group; moreover, they are colourless, and are doubtless of lactonic constitution, just as are the di-ethers. They form, however, red salts, the constitution of which is open to discussion. The quinonoid formulz of the phthaleins indicate the presence of one carboxyl and one phenolic hydroxyl group in the molecule, whilst, according to the lactonic formula, two phenolic hydroxyl groups are present. The etherification conditions of carboxylic acids and phenols were therefore studied, as it appeared of prime importance to ascertain whether the carboxyl group can be esterified under the conditions prevailing in the present experiments—namely, in neutral or alkaline solution. The following facts were established as the result of numerous experi- ments, carried out under a great variety of conditions. Phenol is always converted into its ethers by means of alkyl halogen salts and by methyl sulphate, whether the solution be alkaline or neutral, or even acid; the only point of difference is in the yield obtained. Benzoic acid, however, can only be esterified in acid or neutral solutions, but not in alkaline ones, whether alkyl halogen salts or methyl sulphate is used. It would seem difficult to reconcile the above results with the quinonoid formula of the phthalein salts; the difticulty involved in the assumption of the quinonoid theory is also felt by A. G. Green and A. G. Perkin, and they attempt to overcome it by assuming the intermediate formation of the carbinol salt. This view would indicate that the red solution contains, in addition to the quinonoid salt, a certain proportion of carbinol salt, from which latter the lactonic ethers are produced; and that during the course of the reaction the quinonoid salt is progressively converted into carbinol salt, in accordance with the law of mass action, until the change has become complete. The carbinol salt could only be formed by opening the ring, and this could only take place whilst working in presence of excess of alkali; since, however, the author has obtained the same Jactonic di-ethers in neutral solution, the opening of the lactonic ring in this case would appear to be impossible. The advocates of the quinonoid theory point to analogies between phenol- phthalein and fluorescein, but the author is of opinion that it would be very difficult to find, in one group of chemically related compounds, two substances more dis- similar than are phenolphthalein and fluorescein. Thus, for instance, R. Nietzki and P. Schroeter obtained one lactonic and three quinonoid ethers by the * alkylation of fluorescein, whilst the salts of phenol- and quinol-phthalein never yielded quinonoid derivatives under the most varied conditions of working. The quinonoid ethers of tetrabromophenolphthalein, discovered by R. Nietzki and E. Burckhardt, have no bearing on this question, because they have not been pre- pared from the phthalein salts. It would be preferable to try to express the different behaviour of fluorescein and phenolphthalein by the aid of chemical formule rather than to insist on a similarity which is not warranted by the facts. One serious difficulty arises in connection with the colour of the alkali salts: Ostwald assumes that the red colour is due to the phthalein ions, whilst the undissociated molecules are colourless. If, however, the ions are coloured, they should contain a chromophoric group, such as is present in undissociated coloured molecules; the lactonic formula does not indicate the presence in the molecule of such a chromophoric group. At the same time, it must be agreed that, however valuable the theory of chromophors has proved as a means of characterisation and classification of colouring matters, it is not sufficiently comprehensive to include all coloured organic compounds. It does not include the quinolphthaleins (and orcinphthalein), dibenzalacetone, and other colourless substances which form deeply coloured addition compounds with mineral acids. Adolf Baeyer introduced the a]2 REPORT—1904. term ‘halochromy’ as descriptive of this phenomenon, and it does not seem im~ possible that the colour of phthalein salts is due to a kind of halochromy. The author is continuing his work in another direction, and hopes to obtain further evidence bearing on this question. 4, Studies in the Dynamic Isomerism of a- and (3-Crotonic Acids. Y By R. 8S. Morrewt and E. K. Hanson. 5. Mesoxalic Semialdehyde. By Henry J. Horstman Fenton, 7.2.8. Mesoxalic semialdehyde (COOIL—CO—CHO), it has been previously shown,! can be obtained by the oxidation of dihydroxymaleic acid with ferric salts at about 40°. This method is not altogether satisfactory, owing to the difficulty of removing the iron salts, and it is now found that the oxidation may advanta- geously be effected by means of mercuric chloride. In this case the mercury separates almost quantitatively as calomel, and any traces remaining may be removed by hydrogen sulphide. The properties of this semialdehyde are being further studied, and appear to be of considerable interest. It is evident that the aldehyde hydrate COOH—-CO—CH(OH), may be regarded as a tautomeric form of the missing trihydroxyacrylic acid, COOH—C(OH=C(OH),, and the latter should, by condensation with two molecules of urea, yield uric acid. If a solution of mesoxalic semialdehyde is mixed with urea and heated, together with dilute hydrochloric acid, a large yield of a very sparingly soluble crystalline substance is obtained which, by its properties and composition, proves to be glycouril, C,H,N,O,. This compound was originally obtained by reduction of allantoin, and afterwards from glyoxal and urea, It is evident, therefore, that a molecule of carbon dioxide splits off in tbe reaction above described ; later experiments appear to indicate, however, that hy modifying the conditions this loss may be prevented, in which case it is hoped that uric acid itself may be obtained. Although the properties of glycouril have been carefully studied by various authors, the following very striking colour-reaction appears to have been over- looked: the substance is evaporated to dryness with strong nitric acid on a water bath and the white residue dissolved in caustic soda; a faint blue violet colour here results, and now, on addition of sodium hypochlorite, a very brilliant purple colour is obtained, 6. Note on the Influence of Radium Radiations on Atmospheric Oxidation in presence of Iron. By Henry J. Horstman Fenton, 7.2.5, It has been pointed out by the author in previous communications? that the oxidation of certain hydroxy-compounds, such as tartaric acid or glycol in presence of iron, may be brought about by atmospheric oxygen in presence of sunlight, and that the products are the same as those obtained when hydrogen dioxide is employed as oxidizing agent. It is now found that the influence of yadiations from radium bromide may, in certain cases, produce effects similar in this respect to those obtained by exposure to sunlight. A solution of tartaric acid, for example, containing a small quantity of ferrous tartrate, was divided into two parts and kept in the dark in presence of air, one of the tubes being placed directly over a specimen of radium bromide. On testing the solutions after a day or two with phenylhydrazine acetate a very striking difference was observed in the results, the exposed solution giving a comparatively copious precipitate of Nastvogel’s osazone. 1 Fenton and Ryffel, Trans. Chem. Soc., 1902. 2 British Association Report, 1895 and 1898. TRANSACTIONS OF SECTION B. 513 7. A Colour Reaction for Methylfurfural and its Derivatives. By H. J. H. Fenton, £.2.S., and J. P. Mituineton, B.A. When bromo-methylfurfural is heated with dimethylaniline and a de-hydrat- ing agent, such as phosphorus oxychloride, zine chloride, or dry oxalic acid, an intensely blue-coloured compound is obtained, This reaction is extremely sensi- tive, and is given by bromo-, chloro-, iodo-, or acetoxy-methylfurfural, and by methylfurfural itself, but not by the condensation products previously described.! Asa dye the blue colour appears to be very permanent in the dark, but slowly fades in sunlight. 8. A Reaction for Keto-hexoses. By Henry J. Horstman Fenton, F.R.S. By oxidation of levulose, cane sugar, inulin, or sorbose in presence of ferrous iron at about 90°-100°, and heating the resulting solution with phenylhydrazine- p-sulphonic acid, a compound is obtained which dyes silk a rich brownish pink colour, which is remarkably stable and permanent. This reaction appears to be especially characteristic of keto-hexoses or substances which yield them on hydrolysis, and is given by dextrose, milk sugar, maltose or starch only to a limited extent, or not at all. 9. On the Energy of Water and Steam at High Temperatures. By Professor C. Dieterict. The author has devised a method for determining the specific heat of water at temperatures up to 300°C. The water is enclosed in quartz tubes, which are sufficiently strong to withstand the pressure of steam—namely, about 100 atmo- spheres at 300° C.—and the determinations are made with the aid of the ice calorimeter. The results obtained may be expressed by the formula e = 1:0160 — 0:0,6057¢ + 0:0,430222, in which the specific heat, ¢, is given as a function of the temperature. The formula holds between 50° and 300’ C., but does not hold below 50° C., because at such low temperatures the point of maximum specific heat first observed by Rowland occurs. The observations made with water completely enclosed in a tube give the difference between the energy of the liquid water at ¢° C. and that of the water at 0° C. Since the heat of evaporation is known or calculable, this quantity, diminished by the external work, gives the energy difference between saturated steam and liquid water at ¢° C. Very careful observations have been published by Sir W. Ramsay and Professor 8. Young (‘ Phil. Trans.,’ 1891) on the pressure of unsaturated steam between 140° and 270°; and since the relation between energy change and volume at constant temperature is given by the equation A Gy Ov/T Or] v of the mechanical theory of heat, the change of energy of superheated steam depends only on the pressure, and can be calculated from the author's present observations. It is, therefore, possible to calculate the energy isothermals and to draw the isothermal lines for water. After applying the most accurate methods of calculation possible to the new observations, the author draws the following conclusions :— At about 200° C. the specific heat of superheated steam at constant volume is 0°5, and is practically independent of the volume if the latter is much greater - 1 Fenton and Gostling, Zrans. Chem. Soc., 1899, 423, and 1901, 807. 1904. LL 514 REPORT—1904. than the saturation volume. As, however, the volume diminishes to the volume of saturation, the specific heat increases to about 0-7. The specific heat at con- stant pressure, C,, similarly varies from 0°6 to 0°8. Further, in the well-known equation of state of Van der Waals RT p+ — Pp Tr — 3? the cohesion pressure, 7, cannot be taken as = but is such a function of v and v T that it has a considerable value for large volumes at low temperatures, and for small volumes at higher temperatures. 10. On the Specific Heat of Gases at High Temperatures. By Professor H. B. Dixon, F.B.S. 1l. The Oxidation of Carbohydrates by Hydrogen Peroxide in presence of Ferrous Sulphate. By R.S. Morreri and A, E. BELiars. 12. Report on Wave-length Tables of the Spectra of the Elements and Compounds.—See Reports, p. 66. MONDAY, AUGUST 22. The following Papers were read :— 1. Sur la photographie des spectres détincelle directe des minéraux sulfurés. Par le Comte A. DE Gramont, D. és Sc.Ph. J’ai repris, avec l’aide des procédés photographiques, des recherches que j’avais poursuivies autrefois sur les spectres des minéraux ou des produits métallurgiques bons conducteurs, entre deux fragments desquels jaillit ]’étincelle d’une ou plu- sieurs bouteilles de Leyde alimentées par une bobine de Rhumkorff. J’avais établi ainsi! que l’étincelle condensée dissocie les composés en donnant des spectres de lignes trés vives oii chaque corps est représenté par les raies carac- téristiques de son spectre individuel. Les corps conducteurs, ou seulement volati- lisables dans l’étincelle, se comportent donc spectroscopiquement, comme on l’avait auparavant constaté pour les alliages métalliques, mais ils donnent en plus les spectres de lignes des métalloides. Etudiant ensuite les principaux sulfures métal- liques minéraux, j’avais donné les longueurs d’onde de leurs raies, et notamment de celles qui caractérisent le soufre dans leurs spectres visibles. Mais les raies les plus sensibles 4 I’ceil ne sont pas, comme on le sait depuis longtemps, celles qui impressionnent le mieux la plaque photographique. Aussi ai-je repris photo- graphiquement la recherche du spectre du soufre dans les sulfures, en superposant sur un méme cliché le spectre du minéral étudié, galéne PbS, ou argyrose Ag?S, avec celui d’un tube de Pliicker chauffé, contenant du soufre en vapeurs; les raies données par le tube se trouvent ainsi sur le prolongement des raies correspon- dantes du sulfure minéral. Deux séries de clichés ont été prises: (1°) avec un spectrographe a partie optique toute en quartz, prisme Cornu (droit et gauche) et lentilles non achromatiques de 40 cm. de foyer; on avait ainsi tout le spectre 1 Comptes Rendus des Séances de VAcadémie des Sciences de Paris, 2 Juillet 1894, 8 Juillet 1895; Bulletin de la Société Francaise de Minéralogie, 1895; et vol. i. de V’ Analyse spectrale directe de Minéraux (Librairie Béranger, Paris, 1895). TRANSACTIONS OF SECTION B. 515 photographiable ; (2°) avec deux prismes en flint lourd et un objectif achromatique de 35 cm. de foyer; on obtenait ainsi avec une dispersion suffisante la partie com- prise entre Ad0Oup et AZ50up. L’étincelle était fournie par une bobine de Rhumkorff donnant de 8 4 5 cm. d’étincelle, chargeant un condensateur formé de deux, trois, ou quatre jarres de Leyde dont chaque armature offrait environ 12 décimétres carrés de surface, et une capacité de 0:0043 microfarad par jarre. Les minéraux étudiés en petits fragments, comme ceux des essais au chalumeau, étaient maintenus 4 une distance d’un millimétre environ par des pinces & bout de platine. Il est utile de ménager, dans le circuit de décharge des jarres, une coupure a écarte- ment variable, afin de régler le potentiel de I’étincelle sans augmenter I’6cartement des minéraux dont le spectre est photographié. L’introduction d’une trés faible self-induction (0# 00008 Henry, environ) élimine le spectre de l’air, mais affaiblit beaucoup le spectre du soufre, qu'il est avantageux de renforcer en augmentant la condensation jusqu’d trois ou quatre jarres. Dans une étude spéciale de l’action de la self-induction sur les spectres de dissociation des composés' j'ai d’ailleurs étudié les conditions de disparition des spectres des métalloides. Dans l’observation visuelle du spectre les groupes de raies du soufre les plus caractéristiques sont situés dans le vert: a (5665 & 5509); 8 (5475 a 5429); y (5248; 5320); §(5213; 5201), la raie 8 (5453) étant la derniére 4 disparaitre et la plus sensible. Il n’en est plus de méme avec le procédé photographique, & cause de la limite dimpressionnabilité des plaques au gélatino-bromure. Les groupes les plus carac- téristiques ont varié, et se trouvent alors dans le bleu, l’indigo et surtout dans le violet. L’emploi de systémes optiques en flint est tout indiqué, l’absorption de cette substance pour les rayons plus réfrangibles que \350up ne présentant pas d’in- conyénient dans ce cas, et sa forte dispersion permettant de résoudre plus facile- ment qu’avec le quartz ou le spath les groupes de raies multiples mais non trés réfrangibles qui décélent le plus nettement le soufre. Voici le tableau de ces raies photographiées avec un tube 4 soufre d’abord, puis avec la galéne et avec l'argy- rose. Je donne ici les valeurs de MM. Eder et Valenta pour les longueurs d’onde des raies. Mes déterminations concordaient avec les leurs 4 deux unités prises du cinquiéme chiffre, mais les intensités relatives des lignes dans la partie la plus réfrangible, qui ne figure pas ici, étaient notablement différentes, et je me propose de reprendre l’examen de cette question dans un travail ultérieur. Sn 4812-0 4354-7 4189-9 3933°6 S@ 47164 4332°9 41745 45526 4294°6 Sp 4162°9 3919°5 Su 4525-1 Gq | £2851 "| 41533 4483°5 4267-2 4145°3 3497°4 4464-2 4253°8 4142-4 4362°6 Toutes ces raies sont d’intensité notable. Les groupes les plus caractéristiques et les plus sensibles sont Sz et surtout Sp. 2. Quelques observations sur le groupement des raies du spectre du silicium d’apres Veffet de la self-induction, et sur leur présence dans les spectres stellaires. Parle Comte A. Dp Gramont, D, és Se.Ph. Dans une courte note? présentée l’an dernier au meeting de la British Associa- tion, 4 Southport, j’ai donné les premiers résultats de mes recherches sur la compa- raison entre les raies du spectre d’étincelle du silicium qui résistent ou disparaissent sous l’action de la self-induction, et les raies correspondantes des spectres stellaires, ' Comptes Rendus de l Académie des Sciences de Paris, 5 et 26 Mai 1902. 2 «Sur le spectre de self-induction du silicium et ses comparaisons astro- nomiques,’ rectifier la faute d’impression suivante: dans le doublet 3 lire 5979 au lieu de 5879. D’autre part de nouvelles mesures photographiques m’ont permis de donner des mesures plus précises du doublet 7. LL2 fr 516 REPORT—1904. J’ai repris récemment ce travail avec un prisme composé de Rutherford et un objectif de 45 cm. de foyer, et je voudrais ajouter ici les résultats que j’ai obtenus et comparés avec le groupement des raies du silicium tel que Sir Norman Lockyer le fait @aprés des températures supposées croissantes de I. a LV.' Lockyer. Groupes thermiques. A, de Gramont. Classification basée sur l’effet de la self-induction. Iv ice ries i ) Disparaissant avec le spectre de lair et 3 4116-4 41166 A? sous l’action d’une trés faible self- 4103-5 A? induction. 0#-00009. 4552°8 4552°3 iil. ers Sid {ase Trés affaiblies avec la self précédente, dis- 3807-5 paraissent pour une self-induction de Sin [3r360 (;1'00060. 38791°5 3853°9 3854-2 sBe7 ® 138502 Les derniéres 4 disparaitre pour une ; at self-induction voisine de 0*-00620. 14 41281 gig {4128°2 lalated (41310 5042°0 5057°0 I paint Sig 3905-7 ) * (4103°2 Résistent 4 une self-induction de prés - (5044:0 de 0#-03000 sans étre affaiblies. SiY 1 5058-7 Les lignes du groupe IV., qui d’aprés Sir Norman Lockyer indiqueraient une température excessive, ont toujours, sur mes clichés, accompagné les raies de V’air et disparu avec elles. Elles coincident avec des lignes de Voxygéne ou del’azote, mesurées par Neovius, Exner et Kaschek, ou Hemsalech. Ces deux gaz ont @ailleurs été reconnus dans plusieurs étoiles d’Orion et dans B Crucis,’ ou l’on rencontre aussi les raies du silicium. Je crois done que les raies du groupe IV. pourraient appartenir 4 lair, de méme que la raie 41035 du groupe I., qui serait différente de 4103-10 signalée par Rowland dans le spectre solaire et dans le spectre d’arc du silicium. Le groupe III. devrait comprendre le triplet Siy qui accompagne Sid dans « Canis Majoris et dans plusieurs étoiles d’Orion, et qui disparait dans les mémes conditions. Il faudrait, au contraire, retirer du groupe II. le doublet vert Siy qui résiste absoliiment 4 la plus forte self-induction dont j’aie disposé—ce sont des raies de basse température, et elles devraient étre rangées dans le groupe I. avec la ligne Sig, (8905-7), commune a l’are et a 1’étincelle, et qui se voit dans le spectre solaire. Pour les longueurs d’ondes des lignes des spectres d’étoiles que j’ai identifiées avec celles du silicium, je m’en suis rapporté aux nombres donnés dans les publica- tions de MacClean, de Lockyer, de J. Lunt, et surtout de Miss Maury: ‘Spectra of Bright Stars.’* Ce dernier mémoire contient une table des ‘Orion lines’ trouvées dans les groupes IVII. de sa classification stellaire; parmi les raies qui y figurent j’ai trouvé, en sus des raies de l’hydrogéne et de V’hélium, la lupart des raies du silicium que je viens de donner ci-dessus, et notamment Sid, ic, Si¢,, Sin (8791). On y voit aussi celles du groupe de raies IV. de Lockyer, que je suppose dues & l’azote et & l’oxygéne. 1 Proce. of the Roy. Soc., vol. \xvii. 1901, p. 403. 2 MacClean, Spectra of Southern Stars, London, 1898; and Comparative Stellar Spectra, Phil. Trans. 1898. 8 Roy. Soe. Prov. 1901, vol. lxvii. p. 403. 4 Ann of the Astr. Obs. of Harvard College, vol. xxviii. TRANSACTIONS OF SECTION B. 517 En comparant les raies du silicium avec leurs correspondants dans les spectres stellaires, et en observant la répartition de celles-ci suivant les grandes classes d’étoiles des quatre types de Secchi, nous obtiendrons les conclusions suivantes : 1°, Seules les étoiles de la premiére classe (& hydrogéne et 4 hélium) montrent les raies du silicium que supprime la self-induction. Les étoiles & hélium, par exemple celles d’Orion ou ¢ Canis Majoris, réputées les plus chaudes, donnent avec intensité les raies qui disparaissent les premiéres: Sid, Sij. Au contraire, les étoiles 4 hydrogéne, comme Sirius, et celles qui se rapprochent du type solaire, comme Procyon, donnent surtout Sie, Si¢,, qui disparaissent les derniéres par Vaccroissement de la self. Deneb (a Cygni), qui parait étre &4 un stage inter- médiaire, montre simultanément ces différentes raies propres & chacune des deux catégories d’étoiles. 2°, Les étoiles de la seconde classe, du type solaire, montrent les raies spéciales aVarc, y compris ¢, qui résiste 4 la self, et se voit aussi dans le ‘ flash spectrum’ des éclipses. II serait intéressant de rechercher si quelques-unes des étoiles de cette classe ne donnent pas aussi les doublets persistants, Sia et Siy. 3°. Les étoiles des troisiéme et quatriéme classes, 4 spectres de bandes et réputées de température peu élevée, n’ont pas montré de raies du silicium. En admettant, done, ce qui est de toute vraisemblance, que l’action de la self- induction fait disparaitre les raies de haute température, en laissant subsister seulement celles de l’auréole de 1’étincelle, on voit que la répartition des raies du silicium dans les étoiles vient confirmer les classifications basées sur les tempéra- tures relatives attribuées 4 celles-ci. 3. Changes produced by the /3-rays. By Sir WituiaM Ramsay, &.C.B., LBS. 4. The Stereochemistry of Nitrogen. By H. O. Jonus, W.A., D.Sc. See Reports, p. 169. 5. On the Pentavalent Nitrogen Atom. By Professor Ossian ASCHAN. The author has previously (‘Zeits. f. physik. Chem.,’ 46, 1903, 293) expressed the view, which is in accordance with that of van’t Hoff (‘Die Lagerung der Atome im Raume,’ 2te Aufl., 1894, 136), that the valency directions of the pentavalent nitrogen atom are arranged as in the appended figure :— Fig. 1, ad ich Cc Qa » 6 e By the addition of trimethylene bromide, CH,Br.CH,.CH,Br, to ethyl- enedipiperidide, C,H,,N.CH,.CH,.NO,H,,, and of ethylene bromide to trime- 10. 518 REPORT—1904. thylenedipiperidide, C,H,,N .CH,.CH,.CH,.NC,H,,, the author bas obtained two stereoisomeric compounds having the constitution, , Br Br GS ie bias peach NOH, CH, .CH,7 Soup gr which he was unable to resolve into optically active components by the aid of Pope’s method with d-camphorsulphonice acid. Both compounds would therefore seem to possess symmetrical configurations, and this is only possible if the above conception of the arrangement of the valency directions of the pentavalent nitrogen atom is correct. Since the attempts at resolution were carried out in aqueous solution and as possibly the d-camphorsulphonic acid is not capable of effecting an easy separation of the stereoisomerides, the two ethylenetrimethylenedipiperidide dibromides were caused to react with silver d-bromocamphorsulphonate in absolute methyl alcoholic solution. Both gave highly crystalline ethylenetrimethylenedipiperidide d-bromo- camphorsulphonates which were separated by crystallisation into four and three fractions respectively, the fractions being then converted into the difficultly soluble iodide by precipitation with potassium iodide, The samples of iodide from the first and last fractions were then immediately examined polarimetrically, but were found to be optically inactive. The author finds in these results a confirmation of his previously expressed views on the configuration of ammonium compounds, and notes also that this view possesses the greatest probability on grounds of a mechanico-chemical nature. 6. Zhe Asymmetric Nitrogen Atom. By Professor E, WEDEKIND. In 1899 I succeeded in preparing isomeric series of salts of phenylmethyl- allylbenzylammoniumhydroxide by different methods ; since then many attempts have been made to find analogous cases of isomerism among other asymmetric ammonium salts, and so to explain the nature of this peculiar phenomenon. I have already published the results of numerous experiments made with cyclic quaternary salts of tetrahydroquinoline and isoquinoline, and with methylethyl- phenylallylammoniumhydroxide, and now describe the results of experiments carried out with the toluidines, to see if these bases behave like aniline. The asymmetric salts of para-toluidine can be made by three methods. In spite of analogous constitution, they behave very differently from the corresponding compounds in the aniline series. Firstly, the iodides (CH,.C,H,) (C,H) (C,H,) (CH,) N.L prepared by three different methods, were at once obtained crystalline, and showed chemical and crystallographical identity. The iodide and bromide are not isomorphous; the crystals of the former are rhombic, of the latter monoclinic. Still more remarkable was the difference in the case of the homologous benzyl salt (C,H,*CH,) (C,H,) (C,H,) (CH,) N.I. Identical salts were obtained by all three methods. On the other hand, there is here a case of dimorphism; the crystals are triclinic, but show different angles. One form crystallises from alcohol, the other from water. The iodide and bromide, however, are not isomor- phous; and the crystals of the latter show hemihedral faces. Different relations were observed in the ortho-toluidine series. The tertiary bases showed but little tendency to combine with the alkyliodides (this is due to the sterochemical hindrance of the methyl] group in the ortho-position). The salts obtained with benzyl and allyliodide were amorphous. By the use of methyl iodide crystals were obtained ; the quantity, however, was too small to allow of chemical and crystallo- graphical examination. The properties of the latter salt seem to show that there is here a second case of the new nitrogen isomerisin. Since the preparation of optically active nitrogen compounds the question has TRANSACTIONS. OF SECTION B. 519 remained undecided whether every difference in the groups attached to the nitrogen atom was sufficient to cause activity. Contrary to expectation, I have been unable to obtain optically active forms of the asymmetric salts of the above-mentioned paratoluidine series. The failure was probably due to unfavourable solubility conditions, and also to a tendency to autoracemisation. The latter phenomenon was observed by Pope and by myself in the case of the active a-phenylmethyl- allylbenzylammonium iodide. This phenomenon was formerly explained by assuming the dissociation of the salt into benzyl iodide and allylmethylaniline, according to the equation :— (C,H) (C;H,). (CH,)N (C,H,)I @ C,H, (C,;H;) (CH,)N + C,H, I. That is to say, by the easy passage, under certain conditions, of pentavalent into bivalent nitrogen, and the consequent destruction of space asymmetry, and, therefore, also of optical activity. Asa matter of fact, the iodide is largely dissociated in boiling chloroform solution. Whether this is also the case in chloroform solution at ordinary temperature could not then be decided. H.O. Jones, however, by using Barger’s microscopic method for determining molecular weights, was able to show that such salts possess normal molecular weights in chloroform solution at ordinary temperature. The explanation of the mechanism of autoracemisation in the case of the active asymmetric ammonium salts becomes, therefore, as difficult as that of the spontaneous racemisation of the active esters of brom-fatty acids, unless it is assumed that the degree of dissociation at any instant is at ordinary temperatures so small as to escape measurement by the methods employed. This small amount of dissociated material would on recombination form the racemic salt. In the next instant another small quantity of the active salt would be dis- sociated and racemised, and so on until the whole mass was racemised. It is evident that, in spite of this process, an approximately normal molecular weight might be found. The velocity of the change—that is to say, the amount of active salt dissociated in the unit of time—depends upon the strength and duration of the light falling on the solution, and also on the temperature. I am at present engaged in the measurement of the velocity of autoracemisation under various conditions, in the hope of elucidating this problem. The important question whether all asymmetric ammonium salts, independent of difference in groups, could be obtained in active forms has at last beeu answered. Jones, after failing to obtain ammonium salts of the type N.a.a.b.c.X., and also cyclic salts in active forms, succeeded in resolving the phenylethylmethylbenzyl- ammonium base at almost the same time. I prepared the iodide and the dextro- camphorsulphonate of the same base, and succeeded in resolving the latter by a single recrystallisation from methyl formate ([m{, of the dextro-phenylbenzyl- ethylmethy] d-camphorsulphonate= +69°). By employing the same useful solvent I have also recently been able to resolve the homologous propylphenylbenzyl- methylammoniumhydroxide. The d-camphorsulphonate of the dextro base forms transparent rhombohedra, which attain a diameter of one or more centimetres. The highest rotatory power hitherto observed is [M] p= +62°. The iodide pre- pared from the camphorsulphonate was active. Activity did not result when acetone or acetic ether was employed. I am at present working on the resolution of the homologous isobutyl base. The problem of resolving salts containing two asymmetric nitrogen atoms appeared particularly interesting.' For this purpose I have converted ethylene dikairolinium iodide * into the di-dextro-camphorsulphonate. CH,—CH, CH,—CH, / >C.H, x H, N OS HG, Pat hee el ope. | CH, SO,.C,,H,,0 OH, SO,.C,,H,,0: 1 O. Aschan, Zeitachr. f. physikal. Chemie, 46, 312 ff. 2 BE. Wedekind, Ber. d. deutsch. Chem. Ges. 36, 3796. 520 REPORT—1904. The single fractions showed the same specific rotatory power and a molecular rotation of + 105°to 104°. The di-d-brom-camphorsulphonate crystallises remark- ably well, and seems to offer a better chance of resolution. The acetic ester of kairolinium d-camphorsulphonate ([a]>=11'7°) has not. been obtained in active forms either by Jones or myself. The problem of examining the so-called inactive isomers of asymmetric nitrogen offers great difficulties. Anyone who has examined so great aseries of asymmetric systems for isomers without success as I have, will understand me when I call the single case of isomerism in the series of benzylallylphenylmethylammonium salts (which I discovered several years ago) ‘remarkable,’ and to a certain extent a ‘puzzle.’ Kipping and Aschan have both taken exception to this expression. I think, however, that everyone will agree with me that the extraordinary rarity of such isomers—predicted by most theories—is most striking, especially as in the observed case the isomers possess about equal stability. Since then I have found a new case in the series of asymmetric ortho-tolyl-ammonium salts, but on account of experimental difficulties 1 have not been able to establish it with absolute certainty. Since among the homologues of the asymmetric aniline salt, with this exception, no isomers have been found, I have commenced experimenting with the asymmetric phenetidine and anisidine bases.!_ Paraphenetylbenzylallylmethylam- monium iodide (and the corresponding d-camphorsulphonate) are beautifully crystallised salts when made by the combination of allyl or benzyl iodide with the corresponding tertiary bases. The third method—addition of methyl iodide to benzylallyl-p-phenetidine—leads to an amorphous salt, Experiments are already in progress to prove if this is really a case of isomerism. O. Aschan has recently discovered a new case of isomerism in the series of the diacid ammonium salts which differ in solubility. At the time of his publication I was working on the ethylene bases of the tetrahydrozsoquinoline series. I therefore tried whether the above-named bases, which in contradistinction to the piperidine derivatives are quite unsymmetrical, possess analogous powers of reaction. The reaction between trimethylene bromide and ethylene di-tetrahydro- erengnee takes place almost quantitatively at 100° C. The equation pro- ably is :— CH, H,C OH, H,C N—CH,—CH,—N CH, H,C + Br. CH, . CH,. CH, Br CH, H,C CH, H,C u ee 7 OCH N- SN se. \ oth otte Jy OH, ff Br BY According to this, the salt, which is rather easily soluble in water, would contain a seven-atom heterocyclicsystem. The prospects of successfully preparing this system by the second method are not good, since, according to my experience, 1 T intend to try to resolve the fatty asymmetric base of Le Bel, N(CH;)(C,H;) C,H,)(@.C,H,)OH by the new method. TRANSACTIONS OF SECTION B. 521 ethylene bromide seldom reacts with tertiary bases in the normal manner, Iso- kairolin itself with ethylene bromide gives almost exclusively the salt : — CH, CH, Br “___0H,.CH,.Br CH, CH, It has not yet been found possible to bring the Br in the —CH,Br group into reaction with a second molecule of isokairolin. I do not consider that our present knowledge is sufficient for successful theoretical speculation on the configuration and isomerism relations of the pentavalent nitrogen atom. This, however, is certain, viz.: in active ammonium salts the tetra-atomic radical N.a. b.c. d.,the centre of activity, must possess tetrahedric grouping. This radical occurs in solution as the free active cation. The fifth valency, which is not always satisfied, cannot—apart from other grounds— possess equal value. I picture it in a rectilinear lengthening of a tetraheder axis, as the following sketch shows :— This configuration is that proposed long ago by van't Hoff, and since then revived by Aschan. The latter has also deduced the inactive isomers (prepared by Le Bel, Kipping, Aschan, and Wedekind) from this scheme. In my opinion, the change of places of the different radicals, or, still more, the lack of change of places of the different radicals (appearance of isomerism), is so little understand- able that even with the help of this model we cannot as yet form any clear ideas of the intramolecular reactions among the ammonium salts. I incline more and more to the opinion that, in the case of nitrogen which shows such different behaviour, one must discard the idea of a fixed valency. The theories which Werner has developed for carbon may be useful here. They allow, too, of an explanation of autoracemisation without the assumption of dissociation. Let us consider affinity as a force acting uniformly from the nitrogen atom, considered as a sphere, towards the surface. Then we can imagine the five radicals fixed as five ‘ valency positions’ on the surface of the sphere. Four of these could take up a tetrahedral grouping, if in this position the greatest exchange of affinity took place. Now, the intra-molecular movements of the radicals in substituted ammonium salts are particularly evident. This is proved by the tendency towards change of place. These movements appear, then, as pendulum-like oscillations about the valency position, and are increased by rise of temperature, by the action of sunlight, and by other unknown causes, until, finally, a change of place occurs, just as Werner assumes in the case of compounds containing asymmetric carbon. (Explanation of autoracemisation of brom-succinic acid.) I do not consider it, however, impossible that the five radicals would cause a different grouping of the valency positions, when the force acting between them is of a different nature. Such groupings are perhaps the pyramid formula, or the double tetrahedron of Willgerodt. The latter might occur when two negative radicals are combined with a tertiary amine. The attractions and repulsions 522 REPORT—1904. between the radicals would now be quite different from those in the normal ammonium type. The configuration set forth by the double tetrahedron is the labile one, and a tendency therefore exists for it to go over into the stable ammonium form (tetrahedron or pyramid), one of the negative radicals being replaced by hydrogen or alkyl. I think that such pictures are useful in helping us to understand the easy change of position of the radicals in quaternary ammonium salts. Further, the complex behaviour of pentavalent nitrogen becomes thereby more easily explicable. 7. On the Products obtained by the Action of Vertiary Bases on some Acid Chlorides. By Professor E. WEDEKIND. The author has previously shown (‘Annalen,’ 318, 99; 323, 257) that, in spite of the violent reaction which occurs between the chlorides of powerful acids and strong tertiary bases, no quaternary salt of the type /CO.R oa \Cl is produced, but that the hydrochloride of the tertiary amine, H Cl is obtained in quantitative yield. his fact is in so far of importance in connec- tion with the stereochemistry of nitrogen as it indicates the reluctance of the trivalent nitrogen atom to take up two acidic or negative groups; the trivalent nitrogen atom exhibits a kind of striving to assume the most stable condition, that, namely, of which ammonium chloride is the type. The question at once arises, in connection with the above reaction, as to what becomes of the residue of the acid chloride molecule; the solution of this problem presented extraordinary experimental difficulties, but its study has led to the dis- covery of several interesting facts, which may here be briefly mentioned. The author has already shown that by the action of acetyl chloride on triethylamine, pyridine, &c., dehydracetic acid is produced (‘Annalen,’ 323, 247); in this reaction four molecules of each component take part, in accordance with the equation 4CH,.COCI + 4N(C,H,), = 4N(C,H,),1Cl + 0,H,0,(4C,H,0); but when the acetic chloride is replaced by propionyl, phenylacetic or hydro- cinnamic chloride, products are obtained which have only three times the molecular weight of the hypothetical substance which must be supposed to be first formed by the splitting off of hydrogen chloride from the one molecule of the acid chloride. Thus the condensation product from propionic chloride, CH,.CH,.CO.Cl, has the empirical formula C,H,,0, or 3(C,H,O), and that from phenylacetic chloride, C,H,.CH,.CO.Cl, corresponds to the formula C,,H,,0, or 3(C,H,0). The latter substance proved to be fairly easily obtainable, and the first suppo- sition that it might be a phloroglucinol derivative—the symmetrical triphenyl- phloroglucinol-—was found untenable, because the material can under no con- ditions be reduced to triphenylbenzene, and is relatively very stable even in alkaline solutions. The new compound shows simultaneously the behaviour of a lactone, a monoketone, and a primary alcohol; thus it gives with soda a monosodio- derivative, with hydroxylamine a monoxime, with acetic chloride a monoacetyl compound, and with benzoyl chloride a monobenzoyl derivative. On treating it with ammonia under pressure it yields a very stable pyridine derivative, and this reaction shows it to be a simple homologue of pyronone (the previously known rae compounds contain, like dehydracetic acid, a carboxyl group in the side chain). R,N 1 On heating with alkalies it yields analogous products of hydrolysis to the symmetrical trialkylphloroglucinols. TRANSACTIONS OF SECTION B. 523 The mechanism of the reaction by which the substance is formed (compare J.N. Collie, ‘Trans. Chem, Soc.,’ 77,971) would seem to be that three molecules of the acid chloride first condense with evolution of two molecules of hydrogen chloride, yielding the chloride of an ay-diketonic acid in accordance with the fol- lowing scheme: C,H,.CH,.COCI + C,H,.CH,.C0.Cl + 0,H,.CH,.COCl> C,H,.CH,.CO.CH.CO.CH.CO.C1 | C,H; C,H; This hypothetical chloride then undergoes total or partial conversion into an enolic form, from which, by subsequent loss of hydrogen chloride, in which the hydroxyl group is involved, the closed pyronone ring is formed : C,H; C,H; GEOR, | ->C,H,.CH,.C=C—CO—CH~0,H,.CH,.C=C—CO—CH | | | | OH C1CO = 0 Since this pyronone derivative differs from those previously studied, in that it gives an oxime as well as a monobenzoyl derivative, it must be regarded as tautomeric in that it can assume the above ketonic form as well as the following enolic or hydroxylactonic constitution : OH | 0,H,—0—C=C'0,H, I | C,H,.CH,—C—O—CO The latter formula naturally gives rise to the acidic derivatives. ‘The remark- able power which the carbonyl group in the closed ring possesses of reacting with hydroxylamine must be attributed to the multiplication of unsaturated groups in the molecule—namely, to the presence of two phenyl groups and two double bonds in the closed chain. As was to be expected from the known behaviour of pyrone or pyronone compounds, the action of ammonia gives benzyldiphenyldihydroxypyridine : OH | C,H,.C—O=C.0,H, I | C,H,.CH,.C_N=C.OH Lastly, it may be mentioned that the author has made a remarkable observa- tion upon the interaction of isobutyric chloride with tertiary amines; in this reaction an extremely volatile substance crystallising in colourless needles and having an odour of menthol and camphor is obtained. This product is formed by the condensation of only two molecules of the acid chloride, and is not a pyronone derivative but a diketone ; it is in all probability a tetramethylene derivative, from which the author hopes to prepare the parent hydrocarbon. 8. Sur les Manganates et les Permanganates. Par Dr. A. Erarp. Le permanganate de potassium est parfaitement connu, mais le manganate vert est, je crois, considéré comme une masse fondue trés riche en potasse. Cependant, Mitscherlich a décrit et mesuré des cristaux de MnO*K?. Il ne semble pas qu’on les ait préparés depuis. Mon but n’est pas de signaler ce sel, connuautrefois, mais de décrire ses relations avec le permanganate. Quand du permanganate cristallisé 524 REPORT—1904. est dissous et chauffé avec un fort excés de potasse concentrée, il arrive un moment ot la coloration rouge passe au vert; en méme temps il se dégage de Yoxygéne trés abondamment et il se dépose des cristaux verts de MnO‘K? qu’on a le temps de laver avec de la potasse froide, de l’alcool absolu et de I’éther. Ces cristaux verts, dissous dans l’eau et traités par un courant d’air, absorbent Voxygéne a froid ; la liqueur devient rouge et il se dépose des cristaux de perman- gvanate MnO‘*K. Les deux réactions successives s’écrivent donc: (1) 2MnO'K +2KOH =2Mn0‘K?+ H20+0 (2) 2MnO‘K? + H?0 +0 =2MnO‘K + 2KOH, Ce sont ces deux formules qui me paraissent nouvelles, sauferreur. Tlles ex- pliquent les apparences souvent controversées du caméléon minéral. L’oxygéne qui est dans l’eau aérée oxyde le manganate vert. I] n’y a ni équilibre chimique spécial ni influence de l’acide carbonique ni dépdt de bioxyde de manganése. 9. On the Bearing of the Colour Phenomena presented by Radium Compounds. By Witt1am AcKRoyp, Madame Curie early observed that radium salts are white like barium salts when first prepared, but that they gradually become coloured.’ I have associated this colour-change with the reception of external radiant energy and the con- sequent increase of radio-activity.” What I take to be confirmation of this view has been obtained in following the history of a radium bromide tube. The salt was nearly white when purchased, and in a month or two it became tawny-yellow or orange; its powers of absorption had visibly increased, and its power of exciting fluorescence in barium platino-cyanide was concurrently quadrupled. These facts may be thus diagrammatically represented :— Colour-change and increase of absorption. Seral White, yellow, orange, tawny-orange. —> Increase of radio-activity. This readiness on the part of radium compounds to become coloured under the influence of external radiations may be regarded as an effort to conform to the constitutive-colour law ;* moreover, it is highly probable that the colour-change is effected by a minimum expenditure of energy, as in the case of other end members of vertical groups of the periodie classification of the elements. This tendency I have experimentally demonstrated in the case of chlorides of alkali metals.* But while we may regard this colour-change as being slowly effected by external radiations, the comparatively sudden application of sensible heat has a very different effect. In July 1903 I strongly heated tawny-orange radium bromide, expecting to see it change in this order—red, brown, black-like mercuric oxide and other colour-changing bodies. Instead, the seething substance reverted at once to white. The colour behaviour of the radium bromide when heated is evidently anomalous like that of some other compounds of extreme members of vertical periodic groups; as, for example, mercuric iodide. Its powers of absorption are visibly lessened, and, as is now well known, the radio-active properties of the residue are also lessened. The increase in the radio-activity of the expelled emanation is another phenomenon, and probably the joint produce of radium rays and heat. Analogous effects are produced by radium rays and heat on halides of 1 Thesis on Radio-active Substances, p. 30. London: Chem. News Office. 2 Lancet, Nov. 21, 1903, p. 1464. % B.A, Report, 1903, and Chem. News, 1903, 88, 217. 4 Journ. Chem. Soc., 1904, 85, 815. TRANSACTIONS OF SECTION B. 525 the alkali metals.!_ Cesium chloride was exposed to radium rays for half an hour at 16° C.; the radium compound was then removed and the temperature of the cesium salt was raised to 37° C. The phosphorescence was now markedly increased by the rise of temperature. May we not, then, suppose that the bodies occluded in radium compounds have radio-activity conferred on them while there, and that this radio-activity is increased by the heat which is necessary for their expulsion ? Crucial tests of the validity of this energy-transformation theory appear to be presented in the following additional facts. If water be admitted to the contents of a radium bromide tube its phosphorescence is practically undiminished.” Rutherford has studied the matter quantitatively, and finds that solution of a solid radium compound to a thousand times its volume does not appreciably affect its radio-activity, which he has attempted to explain on the atomic disintegration theory.? I have, however, pointed out that under such conditions there is approxi- mate constancy of absorption of external radiant energy which ought to result ina like constancy of radio-activity.* Again, the 60 per cent. difference of heat emission in the Curie-Laborde and Curie-Dewar estimations appears to receive a rational explanation from this point of view. At normal temperature the output of heat from a radium compound was found to be of the order of 100 calories per gram of radium per hour, while at the temperature of boiling oxygen it was only 38 calories. Now a colour-changing substance, whilst passing from normal temperature towards the region of absolute zero, becomes white, or, in other words, lessens its capability of absorbing external radiant energy; and it is now suggested that probably to this cause is to be attributed the low numbers obtained by Professors Curie and Sir J. Dewar at the temperature of boiling oxygen. 10. Pseudomorphosis in Organic Persulphates. Sy Professor R. WoLFFENSTEIN. 1l. A New Theory of the Periodic Law. Ly Professor G. J. Stokes, M.A. Many mathematical and physical interpretations of the Periodic Law have been suggested. That of the author, based on a logical analysis due to De Morgan, offers itself as more than an illustration—as a method by which chemical facts may be deductively re-discovered. It has been shown by De Morgan that between any two things x and y there are only a definite number of logical relations possible. If we take the diagrams by which these are represented and arrange the elements under them, it is shown that a number of qualitative facts in chemistry may be deductively arrived at. TUESDAY, AUGUST 23. The following Papers were read :— 1. On the Velocity of Osmosis and on Solubility : a Contribution to the Theory of Narcosis. By Professor I. TRAvuBE. Upon the results of a series of investigations, by plasmolytic methods, of the velocity of the osmosis of chemical compounds into the protoplast, Overton bases the theory that the magnitude of the distribution coefficient between such sub- stances as fat, cholesterins, and lecithins on the one hand, and water on the other, ! Journ. Chem. Soc. 1904, 85, 816. 2 Chem. News, 1903, 88, 206. 3 Nature, 1904, 69, 222. 4 Tbid., 1904, 69, 295. 526 REPORT—1904. determines the velocity of the osmosis. He assumes that in the first instance a dissolution takes place in the fatty substance of the membrane at a velocity pro- portional to this coefficient, and that thereupon the substance passes on from the membrane to the interior of the cell. Moreover, Overton, and independently Hans Meyer, point out that all the reliable narcotics, anaesthetics, and antipyretics belong to the class of rapidly diffusing substances, and hence they deduce the theory that the efficacy of a narcotic depends principally on its lipoid solubility. These theories, however, in so far as they concern osmotic velocity, are erroneous, The author's investigations on the constants of capillarity of substances, especially solutions, have led to the result that the greater the osmotic velocity of a substance soluble in water, the more this substance reduces the constant of capillarity of water, whilst substances which cannot penetrate membranes (with regard to which the membranes are semipermeable) raise this constant. Among hundreds of com- pounds examined plasmolytically by Overton, and asto capillarity by the author, there is not one case in which capillary and osmotic phenomena do not correspond. It is evident that osmotic velocity and surface tension run parallel. Hence the difference of the surface tensions—or of the internal pressures—is the motive force in osmotic phenomena ; it is to this difference that osmotic pressure is due. The theory here stated leads to a new conception of the phenomena of diffusion and solution. Suppose that an aqueous solution of a salt is brought into contact with pure water. According to the prevalent theory the salt particles or the ions, in virtue of their ‘ osmotic pressure,’ migrate into the pure solvent, but according to the author’s view it is the pure solvent which, in virtue of its low surface ten- sion, migrates into the salt solution. Again, let two liquids capable of dissolving in each other be brought in contact, or let a solid be in contact with a pure sol- vent, then the solution tension will depend chiefly on the difference between the surface tensions. Irom this we may expect that when a liquid or solid substance dissolves in a solvent the surface tension of the solution will never fall below that of the dissolving substance, and if the surface tensions of solution and dissolving substance be equa), the solution will be saturated. The surface tension of a saturated solution is i maximo as low as that of the dissolved substance, consequently the latter value determines the shape of the curve of the surface tension of solutions. From the author’s former investigations he deduced the law that equal equiva- lents of substances belonging to homologous series, which exercise a strong influ- ence on capillarity (ordinary alcohols, fatty acids, esters, &c.), lower the capillary height of water in the proportion 1:3:37:3° . . . If three mols. of methyl alcohol reduce the surface tension of water as much as one mol. of ethyl alcohol, the con- clusion is justified that the tendency to increase the surface tension of water is three times less in the case of methyl alcohol than in the case of its nearest homo- logue. Hence the tendency of methyl alcohol to separate from the solution may be considered as three times less than the corresponding tendency of ethyl alcohol, or, in other words, the solution tension of substances belonging to homologous series, which exercise a strong influence on capillarity, increases with increasing molecular weight in the proportion 1:3:3?: 3°... Ifa layer of a liquid insoluble in water, say benzene, he placed upon an aqueous solution of different alcohols, esters, &c., the amount of dissolved substance of which this liquid will deprive the water will be greater in exact proportion as the solution tension is less, Dis- tribution coefficients and solution tension—and hence also surface tension and osmotic velocity—are therefore proportional magnitudes in first approximation. Thus Overton’s theory is erroneous in as far as it represents penetration into the cell as depending on the degree of lipoid solubility, for dissolution of the dis- solved substance in the lipoids certainly does not take place. The motive force is the surface tension. Overton and Meyer have pointed cut that the efficacious narcotics, anaesthetics, and antipyretics all belong to those compounds which pene- trate their membranes rapidly, Rapid penetration into the cell seems to be the most essential condition for enabling a narcotic to exercise its effect on the interior of certain cells. Thus narcotics which differ materially in their chemical compo- sition may possibly exercise their action in different cells, and this action may vary considerably even when exerted on one and the same species of cell, But if TRANSACTIONS OF SECTION B. 527 narcotising substances of the same homologwus series, such as the ordinary alcohols or the esters, be considered, we are brought to the conclusions that the cells acted on are all of the same species, that the action in the interior of the cell only differs in degree, and finally that this difference depends essentially and solely on the velocity with which the homologous substances penetrate into the cells. Now this velocity has been shown to be proportional to the depression of the surface tension of water by the dissolved substances, and hence we cannot but conclude that the same law holds good for the narcotic action of homologous substances as has been proved to be valid for surface tension, and approximately so for the distribution coefficient. 2. The Action of Organic Bases on Olefinie Ketonic Compounds. By Dr. 8. Runemann and E. R. Watson. The authors have continued their investigation ' of the behaviour of unsaturated ketonic compounds, especially of benzylideneacetylacetone, towards organic bases, and have isolated several additive compounds which are thus formed, e.g., with m-toluidine, p-toluidine, m-chloroaniline, p-chloraniline, and B-naphthylamine. These substances on heating suffer the following decomposition : C,H,.CH(NHR).CH(COCH,), = C,H,.CH : NR + CH,(CO.CH,),. In some cases the additive compounds cannot be isolated, because they are decomposed at once, according to the above equation. Of interest is the fact that neither o-toluidine nor a-naphthylamine combines additively with benzylidene- acetylacetone. Ortho-substituted benzenoid bases, therefore, seem not to react with the diketone. This conclusion is supported by the fact that piperidine readily forms an additive product with benzylideneacetylacetone, but tetrahydroquinoline does not. The study of piperidobenzylacetylacetone, C,H,.CH(N.O,H,,).CH(COCH,),, has proved of the greatest interest as throwing light on the catalytic action of piperidine and other secondary bases in the condensation of aldehydes and ketones, which have been elaborated by Knoevenagel and his pupils. The authors arrive at the view that, taking the formation of benzylidenebisacetylacetone as example, the reaction is to be expressed thus: (1) C,H,.CH : C(CO.CH,), + O,H, NH = C,H,.CH(N.C,H,,).CH(CO.CH,),. (2) C,H,C (N.C, H,,).CH(CO.CH,), + CH,(CO.CH,), = C,H, CH[CH(CO.CH,),],. The observation of Knoevenagel and Faber,’ that ethyl benzylideneacetoacetate in the presence of diethylamine yields ethyl benzylidenebisacetoacetate, has also found a ready explanation. The fact that piperidobenzylacetylacetone on treat- ment with water yields benzaldehyde and henzylidenebisacetylacetone indicates that the formation of the latter substance is preceded by the production of an additive compound of the unsaturated ketone with the base. 3. The Union of Hydrogen and Oxygen in contact with a Hot Surface. By Wiuutam A. Bont and Ricnharp ‘V. WHEELER. The authors have investigated the rate of formation of water when electrolytic gas, or electrolytic gas diluted with an excess of either hydrogen or oxygen, is circulated at a uniform speed over a porous surface, either of porcelain or magnesia, heated to 430° in the combustion tube of the ‘circulation apparatus’ described in our paper on the Slow Oxidation of Methane (‘Trans. Chem. Roe. 1903, 88, 1074). The steam was condensed each time the gases left the combustion tube, so that its rate of formation was indicated by the pressure-fall in the apparatus. The experimental conditions were such that chemical change was exclusively ' Cf. Trans, Chem. Soc., 1904, 85, 466. 2 Ber., 31, 2773. 528 REPORT—1904. confined to the layer of gas immediately in contact with the hot surface, and we therefore measured the rate of change in a heterogeneous system. Our results may be summarised as follows :— 1. With normal electrolytic gas the velocity of steam formation is always directly proportional to the pressure of the ‘dry’ gas in the apparatus. In other words, the velocity of chemical change is in no way determined by the ‘ order’ of the reaction. : 2. With excess of either hydrogen or oxygen the velocity of steam formation depends mainly, if not entirely, on the pressure of the hydrogen in the apparatus. } 3. The catalysing power of the surface is always stimulated by previous exposure to hydrogen at 430°. Previous exposure of the surface to oxygen at the same temperature has the opposite effect. 4. The catalysing power of the surface is not affected by previous exposure to hydrogen at a red heat, followed by continued exhaustion at the same temperature. This proves that the stimulating effect of hydrogen at 43U° is not attributable to a chemical reduction of the catalysing material. 5. At a red heat porous porcelain has the power of absorbing considerable quantities of hydrogen, of which only a part is yielded up on continuous exhaustion at the ordinary temperature. 6, The results are substantially the same, whether the catalysing surface be acid or basic in character. The experiments indicate that the velocity of steam formation depends on an association of the hydrogen with the catalysing surface. 4, The Decomposition and Synthesis of Ammonia. Sy Epvcar Puinie Perman, D.Se. it is well known that on heating ammonia a large proportion of it is decom- posed, and it has been assumed by many chemists that the mixture then comes into chemical equilibrium. Some experiments recently carried out by Mr. G, A.S. Atkinson and myself appear to disprove the existence of any equilibrium in the case, Decomposition of Ammonia by Heat. In a recent communication! it was shown, from observations on the rate of decomposition of ammonia heated in a porcelain globe, that there is no equilibrium until complete (or nearly complete) decomposition has taken place. Direct Synthesis of Ammonia by Heat. In order to solve the question of equilibrium it was thought better to attempt to reach the equilibrium point (if one exists) by synthesis. A mixture of nitrogen and hydrogen (1:3) was passed slowly through a red-hot glass tube into dilute acid; on making the solution alkaline and testing for ammonia by Nessler’s solu- tion no trace was found. The result was similar when the tube was packed with broken porcelain. If, however, the mixture was passed over red-hot iron (and many other metals), or over asbestos, pumice, or clay tobacco-pipe stems, traces of ammonia were formed. These last-named substances contain iron, and it is concluded that there is no combination of the nitrogen and hydrogen unless some catalysing agent is present. Decomposition and Synthesis of Ammonia by Electricity. On sparking a mixture of nitrogen and hydrogen traces of ammonia were formed, and the gases came into equilibrium in about halfan hour. Approxi- mately the same equilibrium point was reached on decomposing ammonia by sparking, but when the volume was kept constant many hours’ sparking were required to reach that point. ! Proc, Roy. Soc., 1904, 74, 110. TRANSACTIONS OF SECTION B. 529 5. On Active Chlorine. By C. H. Burcess and D. L. Cuapman. The theory which postulates the formation of an unstable additive compound in the preliminary stages of chemical change has of late received considerable attention and support. It is claimed for this theory that it readily accounts for the remarkable influence of water vapour on the rate of chemical change, and also for the initial inert period which can be observed when a mixture such as hydrogen and chlorine is exposed to light. The theory in question cannot, in the opinion of the authors, be accepted as a complete explanation of the latter phenomenon, the chief objection to it being grounded upon certain quantitative results connected with the induction period with mixtures of carbon monoxide and chlorine and hydrogen and chlorine. In addition to carrying out work which has led to the above-mentioned conclusion, the authors have discovered several new facts of practical importance connected with the subject, which are briefly described below. It is well known that hydrogen and chlorine inclosed in a Bunsen and Roscoe’s actinometer over water do not immediately combine at their maximum rate when exposed to light. In repeating this experiment of Bunsen and Roscoe it was found that, even after the maximum rate of combination had been reached, a fresh period of induction resulted on shaking the contents of the actinometer bulb. The period of induction produced in this way was not so long as the first period with the fresh gases. On again shaking the actinometer another induction period was observed still shorter than the second. By constantly repeating this operation and re-exposing to light, the contents of the actinometer were at last brought into such a condition that no fresh induction period resulted on shaking. The experiment shows clearly enough that not only does a fresh mixture of hydrogen and chlorine on exposure to light change its condition in such a manner as to be ready to enter into combination, but that the aqueous solution of chlorine also alters, and ultimately becomes incapable of absorbing the activity of the mixed gases. Since the aqueous solution contains a considerable quantity of chlorine and very little hydrogen, it seemed probable that the change is mainly in the moist chlorine. This was made the subject of a series of experiments. At first we were able to observe only a slight difference, somewhat similar to that noticed by Bevan in the behaviour of the insolated and uninsolated chlorine when mixed with hydrogen and exposed to light ; but it was afterwards shown that, if proper precautions are taken to keep the chlorine in its active condition during admixture with hydrogen, combination occurs promptly on exposure to light. In accounting for the in- duction period the main fact to be taken into consideration is, therefore, the condition of the chlorine. Our attention was next turned towards the discovery of all the possible methods of rendering chlorine gas and also its aqueous solution active. It was shown that chlorine gas becomes active when heated to 100° C. and then cooled, and also when it is acted upon by the silent discharge. An aqueous solution of chlorine can be rendered active, ¢.e., incapable of absorbing the activity from active oxy-hydrogen gas, (1) by the action of light, (2) by contact with active chlorine gas, (3) by heating at a temperature of 100° C., and then allowing to cool. The ability to remove the activity from chlorine is possessed in a much more marked degree by saline solutions and by acids than by pure water. A solution of chlorine which has once been rendered active does not become inactive when the chlorine is removed in a vacuum. It can, however, be rendered inactive by dissolving in it certain salts such as crystallised barium chloride and fused calcium chloride. The foregoing observation suggested the possibility of preparing crystallised barium chloride both in an active and an inactive condition, and the following experiment showed that this could be done. An aqueous solu- tion of barium chloride was rendered active by constantly shaking with chlorine in daylight ; the chlorine was then removed in a vacuum, and the water distilled off in vacuo. The crystals thus obtained were dissolved in water which had been made active by contact with active chlorine. Another solution was made 1904, MM 530 REPORT—1904. by dissolving ordinary barium chloride crystals in a sample of the same water, and the two solutions were tested in two similar actinometers. The difference in the induction periods was so marked as to leave no doubt that soluble solids cau be rendered active. Preliminary experiments on the rate of decay of activity have shown that aqueous solutions retain their activity for a considerable period of time even when a current of air is passed through them. Barium chloride crystals, however, rapidly become inactive when they are exposed to the air for a few hours. It has also been observed that exposure of barium chloride to the action of radium rays does not render the salt active towards chlerine. Besides establishing the above facts, the work, as mentioned above, includes comparative measurements of the induction period and of the sensitiveness of mixtures of hydrogen and chlorine, which appear to throw doubt on theories based on the assumption of the preliminary formation of additive compounds, which are formed and decomposed in conformity with the law of mass action. The relation of the above facts to cloud formation has also been studied, but we have been unable to obtain any evidence of the formation of any intermediate substances in this way. It has been incidentally observed that the presence of air does not prolong the induction period, although the sensitiveness of the mixture is thereby enormously reduced, 6. Exhibition of Effects produced by precipitating Silver Chromate in Gelatine. By Professor I. TRAUBE. 7. Exhibition of Photographs of Sections of an Australian Siderite, By Professor A. Liversipae, /.R.S. 8. Ueber Isocystein (Isothioserin). By Professor 8. GABRIEL. 9. Saponarin, a Glucoside coloured Blue by Iodine. By G. Barcer. The substance known to botanists as ‘ soluble starch’ and occurring in the leaf epidermis of a number of plants has been isolated from Saponaria officinalis at the suggestion of Professor L. Errera, of Brussels; it is a glucoside, and has been named saponarin. The substance is obtained pure in the shape of minute needles by a special method of crystallisation from mixtures of pyridine and water, Saponarin is insoluble in water and all ordinary organic solvents, but readily soluble in dilute alkalies and in pyridine; it melts at 231° with decomposition. The solution in alkalies is intensely yellow, and when acidified the substance remains for a long time in a state of pseudo-solution ; in this condition it gives an intense blue or violet coloration with iodine dissolved in potassium iodide solution. The air-dried crystals of saponarin lose water when heated or when left in vacuo over sulphuric acid, The dried substance is extremely hygroscopic, and, if left in the balance case for au hour or so, takes up quantitatively the water it had previously given off. For combustion it was dried in vacuo till of constant weight, and the boat containing it was then placed in a stoppered weighing tube. The mean of five analyses of the substance dried in this way gave C = 5375 %.H = 516 % For the molecular weight determination pyridine was the only available solvent. The microscopic method was the most convenient, and gave the following result: A. solution of +299 gram in 2:96 grams of pyridine was isotonic with a benzil solution of :23 mole. Hence M = 436. TRANSACTIONS OF SECTION B. 531 The two possible formule for saponarin are: C,,H..0,, requiring C = 53°52, H = 5:21, M = 426 Ca), OC = oe do, FE = 6:15, M468 Of these, the second is considered the more probable, but a definite choice can- not be made till the decomposition products of the substance have been studied more fully. On boiling saponarin with mineral acids it is hydrolysed, and a yellow solution is formed, from which glucose was separated as phenyl gluco- sazone. Unless the solution be dilute, a second product of hydrolysis separates as a thick yellow oil, which has not yet been obtained crystalline. The name saponaretin is suggested for it, and it isscarcely soluble in water, but dissolves in alkalies and in pyridine ; it closely resembles the parent substance, but does not give the reaction with iodine. From dilute solutions saponaretin separates in the solid state, either amorphous or in the form of imperfect whetstone-shaped crystals. It has not yet been obtained quite pure, but seems to be mixed with another substance which crystallises from alcohol in glistening plates. The formula of the latter substance has not been definitely fixed owing to want of material, but it seems to be a hydrate of saponaretin. Saponaretin is in all probability closely allied to the flavones. When fused with potash it yields p-oxybenzoic acid, and a red solution which gives the phloroglucin reaction with pinewood. Phloroglucin itself could, however, not be isolated. The blue substance formed from iodine and saponarin exhibits a close analogy with that formed from iodine and starch. Its composition varies considerably, and it is another example of the absorption of iodine by a substance in pseudo- solution, The blue substance has been obtained in the crystalline state, but must nevertheless be regarded as a mixture and not as a chemical compound. 10, The Vapour Density of Hydrazine Hydrate. By Dr. A. Scort, FBS. 11. The Combining Volumes of Carbon Monouide and Oxygen. By Dr. A. Scorr, LBS. 12. The Action of Heat on Oxalates. By Dr. A. Scorr, F.RS, 13. Some Alkyl Derivatives of Sulphur, Selenium, and V'ellurion. By Dr. A. Scort, RS. 14. On the Presence of Arsenic in the Body and its Secretion by the Kidneys. By W. Tuomson, RSE. 15. On New Low-temperature Phenomena and their Scientific Applications. By Professor Sir Jamus Dewar, JR. MM? 532 REPORT—1904. Sscrion C.—GEOLOGY. PRESIDENT OF THE SECTION—AUBREY StTRAHAN, M.A., F.R.S. THURSDAY, AUGUST 18. The President delivered the following Address :— [PLATE VIII.] Ir is forty-two years since the British Association last met in Cambridge, and we may turn with no little interest to the record of what was taking place at a date when the science of Geology was still in its infancy, and in a University where its promise of development was first recognised. Dr. John Woodward, the founder of the Woodwardian Chair, had been dead 176 years, but his bequest to the University had not long begun to bear fruit, for the determination to house suit- ably the collection of fossils and to provide for the reading of a systematic course of lectures was not arrived at till 1818. In that year Adam Sedgwick, on his appointment to the Woodwardian Chair, began a series of investigations into the geology of this country, which made one of the most memorable epoclis in the history of British Geology. At the Cambridge meeting of 1862 he had therefore held the professorship for forty-four years, a period sufficient to spread his reputa- tion throughout the civilised world as one of the pioneers of geological science. Towards the close of his life Sedgwick gave expression to the objects which he had had in view when he accepted a professorship in a science to which he had not hitherto specially devoted his attention. ‘There were three prominent hopes,’ he writes, ‘which possessed my heart in the earliest days of my Professorship. First, that I might be enabled to bring together a Collection worthy of the University, and illustrative of all the departments of the Science it was my duty to study and to teach. Secondly, that a Geological Museum might be built by the University, amply capable of containing its future Collections; and lastly, that I might bring together a Class of Students who would listen to my teaching, support me by their sympathy, and help me by the labour of their hands.’ We, visiting the scene of his labours more than thirty years after he wrote these words, witness the realisation of Sedgwick’s hopes. The collection is not only worthy of the University, but has become one of the finest in the kingdom, It is housed in this magnificent memorial to the name of Sedgwick, on the completion of which I offer for myself, and I trust I may do so on behalf of this Section also, hearty congratulations to the Woodwardian Professor and his staff. Finally, I may remind you that at this moment the Directorship of the Geological Survey and the Presidential Chair of the Geological Society are held by Cambridge men; that the sister University has not disdained to borrow from the same source; and lastly, that it is upon Cambridge chiefly that we have learned to depend for recruit- ing the ranks of the Geological Survey, as proofs that Cambridge has maintained her place among the foremost of the British schools of Geology. ‘hough he had taken a leading part at former meetings of the Association, Sedgwick’s advanced age in 1862 necessitated rest, and this Section was deprived TRANSACTIONS OF SECTION C. 533 to a great extent of the charm of his presence. It benefited, however, in the fact that the Presidential Chair was occupied by one of his most distinguished pupils, Jukes was one of those men the extent of whose knowledge is not readily fathomed. It has been my experience, and probably that of many others in this room, to find that some conclusion, formed after prolonged labour and perhaps fondly imagined to be new, has been arrived at years before by one of the old geologists. Such will be the experience of the man who follows Jukes’ footsteps. Turning to his Address given to this Section in 1862, we find much of what is now written about earth-movement and earth-sculpture forestalled by him, with this difference, however, that whereas the custom is growing of using a phraseo- logy which may sometimes be useful, but is generally far from euphonious, and not always intelligible, he states his arguments in plain, forcible English. It may raise a smile to find that Jukes thought it necessary in 1862 to combat the view that deep and narrow valleys had originated as fissures in the crust of the earth, and that the Straits of Dover must have been formed in this way, because the strata correspond on its two sides. But we shall do well to remember that the smile will be at the public opinion of that day, and not at Jukes himself, In no branch of Geology have our views changed more than in the recognition of the potency of the agents of denudation. In 1862 it was necessary to present preliminary arguments and to draw inferences which in 1904 may be taken as ranted, : The evidences of the prodigious movements to which strata have been sub- jected, and of the extent to which denudation has ensued, cannot fail to strike the most superficial observer. Both mountain and plain present in varying degree proof that sheets of sedimentary material originally horizontal are now folded and fractured. But after a momentary interest aroused by some example more striking than usual, glimpsed, it may be, from a train-window, the subject is probably dismissed with an impression that such phenomena are due to cataclysms of a past geological age, and have little concern for the present inhabitants of the globe. These stupendous disturbances, it might be argued, can only have taken place under conditions different from those which prevail now. We are familiar with moun- tain-ranges in which their effects are conspicuous ; we have carried railways over or through them and have been troubled by no cataclysmic movements of the strata. Apparently the rocks have been fixed in their plicated condition, and are liable to no further disturbance. Parts of the world, it is true, are subject to earthquakes accompanied by fissuring and slight displacement of the crust, but not even in earthquake regions can we point to an example of such thrusting and folding of the strata being actually in progress as have taken place in the past. Nor, again, can volcanic activity be appealed to, for some of the most highly disturbed regions are devoid of igneous rocks, Volcanic eruptions are more probably the effect than the cause of the disturbances of the crust. Nowhere in the world therefore, it will be said, can we see strata undergoing such violent treatment as they have experienced in the past. How, then, can we dispute the inference that the forces by which the folding was produced have ceased to operate ? Before accepting a conclusion which would amount to admitting that the globe is moribund and that the forces by which land has been differentiated from sea have ceased to act, we shall do well to look more closely into the history of the earth-movements to which any particular region has been subjected. The investi- gation is one which calls for the most intimate knowledge of the geological structure, and, as time will admit of my dealing with a small area only, I shall confine my observations to England and Wales, selecting such facts as have been established beyond dispute. ; . At the outset of the investigation we find reason to conclude that the move- ments, so far as any one region is concerned, have been intermittent. Evidence of this fact is furnished wherever any considerable part of the geological column is laid open to view. Sheets of sediment, aggregating perhaps thousands of feet in thickness, have been laid down in conformable sequence, all bearing evidence of having been deposited in shallow seas, The inference is inevitable that that period of sedimentation was a period of uninterrupted subsidence. But aooner or 534 REPORT—1904. later every such period came to an end. Compression and upheaval took the place of subsidence, and the strata lately deposited were plicated and brought within the reach of denudation. [Illustrations of the recurrence of these move- ments abound, and I need dwell no further upon them than to remark that movements of subsidence and upheaval may be seen to have alternated wherever opportunity is afforded for observation. On extending our observations we are led to infer that the movements of the crust were developed regionally, not universally. The areas of subsidence, for example, evidenced by the marine formations, had their limits, though those limits did not coincide with the shores of existing seas, nor has reason been found to believe that the proportion of land to sea has varied greatly in past times. The limits of the area affected by any one movement of upheaval are more difficult to determine, but the effects were manifested in the crumpling up of comparatively narrow belts of country, and are easy of recognition. Further than this, we ascertain that the movements of one region were not necessarily contemporaneous with those of adjoining regions. The forces operat- ing upon the crust of the earth came into activity in different places at different times, and, while some continental tracts have been but little disturbed from early geological times, there are parts of the globe which have been the scene, so to speak, of almost ceaseless strife. Among the latter we may include the British Isles. These are commonplaces of Geology, and I mention them merely to emphasise the fact that the geological structure of these islands is the result of movement superimposed upon movement. Obviously, therefore, in order to gain a com- prehensive view of the operations which were in progress in any one region during any one epoch, we have to find some means of distinguishing the movements of that epoch and of eliminating all which preceded or followed it. This, briefly, is the problem which has engaged the attention of geologists for many years past, and upon which I propose to touch. The determination of the age of a disturbance is seldom easy, and among the older Paleozoic rocks is often impossible; but at the close of the Carboniferous period, during the great continental epoch which led to and followed upon the de- position of the Coal Measures, there came into action a set of movements of elevation and compression, which generally can be distinguished both from those which preceded them and from those which have been superimposed upon them. The distinction depends upon the determination of the age of the rocks affected by the movements. For example, a movement by which the latest Carboniferous rocks have been tilted from their original horizontal position is obviously post-Carboni- ferous. On the other hand, if Permian rocks lie undisturbed upon those tilted Carboniferous rocks it is equally obvious that the movement was pre-Permian. Now it happens that earth-movements of the date alluded to were particularly active in the British Isles, and played an important part in shaping the platform on which the Permian and later rocks were laid down. Though they have been more completely explored than others in the working of coal, their further investigation is of the greatest economic importance. I have attempted, therefore, briefly to sketch out the principal lines along which earth-movements of that age came into operation in England, premising, however, that by Permian I mean the Magnesian Limestone series, and not the ‘ Permian of Salopian type,’ which is now known to be partly of Triassic but principally of Carboniferous age. In the course of the investigation we shall find reason to conclude that several at least of the movements followed old axes of disturbance, lines of weakness dating from an early period in the history of the habitable globe; and, again, that some of the latest disturbances of which we have cognisance were but renewals of movement along the same general lines. One of the most clearly proved examples of pre-Permian faulting in the Car- boniferous rocks occurs in the Whitehaven Coalfield. The fault forms the south- eastern limit of the Coal Measures, and has been precisely located for a distance cf six miles. In its course towards the south-west it passes under five outliers of Permian rocks, and finally is lost to sight under the Permian and Trias of St. Bees. 35 or TRANSACTIONS OF SECTION C. The dislocation in the Carboniferous rocks amounts to about 400 yards, but the Permian rocks have not been even cracked; though broken and displaced by numerous faults of later date, they pass undisturbed over this great dislocation, the movement along it obviously having ceased before they were deposited. This fault forms part of the upheaval which brought the older rocks of Cumberland and Westmoreland to the surface, and in that sense it may be said to form the north-western frontier of the Lake District. On the north-eastern side also of the Lake District the Permian rocks rest upon uptilted Carboniferous strata, but the axis of upheaval runs in a north-north- westerly direction and defines what we may regard as the north-eastern frontier, Along this frontier much movement has taken place in post-Permian times, but the unconformable relations of the Permian and Carboniferous rocks enable us to distinguish that part of the tilting which intervened between the two periods. On the south-eastern frontier also the Carboniferous rocks had been upheaved and de- nuded before the Permian sandstones were laid down. A huge fault, along which Carboniferous rocks have been jammed from the east in a multitude of plications against Silurian, runs from Kirkby Stephen by Dent to Kirkby Lonsdale, and thence trends south-eastwards by Settle. It is highly probable, though it has not been proved, that this fault is of pre-Permian age. That the Pendle axis which upheaves the Lower Carboniferous rocks between Settle and Burnley is pre-Permian is placed beyond doubt by the fact that an outlier of Permian rests upon the denuded crest of the anticline near Clitheroe. The south-western frontier is defined by a still more marked unconformable overlap by the Permian strata, which here pass over the edges of the lowest members of the Carboniferous series and come to rest upon the Lake District rocks. We have thus defined the sides of an oblong tract which was upheaved in the period we are considering. The older rocks forming the northern part of that tract had already had imposed upon them a dominant north-easterly strike by a pre-Carboniferous movement of great energy. As a result also of that and other movements they had been subjected to vast denudation, not only in the Lake Dis- trict, but throughout the North-west of England generally. But while it is doubt- ful whether any of the physical features then produced have survived, it seems to be beyond dispute that it was in consequence of the pre-Permian movements that the older rocks of the Lake District were freed from their Carboniferous covering, and that to this extent the district may be said to haye been blocked out in pre- Permian times. The detailed sculpturing resulted from later movements, with which we are not now concerned. During this same period there rose into relief that part of the Pennine axis which runs between [ancashire and Yorkshire. The doming up of the Lower Car- boniferous rocks and the wildness of the moorlands which characterise their outcrops have impressed all who have had occasion to cross from the one populous coalfield to the other, and have gained the name of the ‘backbone of England’ for this anticlinal axis. Whether, however, it can be regarded as one axis or as the result of several movements is doubtful, but not material for our present pur- pose. Regarded as a geological structure it isnot continuous with that part of the Pennine axis which runs along the north-eastern frontier of the Lake District. Passing westwards from the Pennine axis we cross the deep and broad Triassic basin of Cheshire, which may be regarded as the complement of the dome of eleva- tion of Derbyshire. To the west of this, again, we reach a part of North Wales which was more or less shaped out by the earth-movements which came into action between the Carboniferous and Permian periods. Two leading faults traverse the district. The one runs in a north-north-westerly direction across Denbighshire and introduces that little bit of ‘Cheshire in Wales’ known as the Vale of Clwyd. Though there has been some later movement along this fault, it was in the main pre-Triassic, which statement, in view of the perfect conformity between the Per- mian and Trias, amounts to saying that it was pre-Permian. The other passes across Wales in a north-easterly direction along the Dee Valley at Bala, and reaches the Triassic basin between Chester and Wrexham. The date of this fault bas not been worked out in detail, but the fact that it is associated with a pre-'riassi¢ anticline, 536 REPORT—1904. where it reaches the Triassic margin, proves that it is in part at least of pre-Triassic age. In Anglesey also there has been strong post-Carboniferous folding in the same N.E.-S.W. direction. It is to be noticed, further, that the Carboniferous rocks maintain their characters to their margins on the flanks of the Clwydian Hills and other ranges of Silurian rocks in North Wales. Both along the coast, and even in a little outlier preserved near Corwen by an accident of faulting, they show a persistence of type and of detail in sequence which could hardly have been maintained had the Silurian uplands existed in Carboniferous times. Theinference that the uplands of Denbighshire and Flintshire are the result of post-Carboniferous upheaval is strengthened by the fact that the Carboniferous rocks reposing on their flanks are tilted at an angle which would carry them over their tops. This part of North Wales, therefore, presents a history corresponding in its main events with that of the Lake District. It had undergone elevation and denudation in pre-Carboniferous times on a scale so vast that rocks showing slaty cleavage and other indications of deep-seated metamorphism had been laid bare. But in both cases it was in consequence of the post-Carboniferous movements that the leading physical features as they exist to-day began to take shape. In both these regions pre-Carboniferous movements had been extremely active. For example, an axis of compression and upheaval ranges from N.E. to §.W., involving the Lake District, the Isle of Man, and Anglesey. It belongs to the Caledonian system of disturbances which is developed on a large scale further north, and which sufficed here to cause slaty cleavage and presumably the extrusion of the Shap granite. I mention this pre-Carboniferous axis to point out that it offers an explanation of the direction taken by the post-Carboniferous disturbances of Whitehaven, Pendle, Anglesey, and possibly Bala. With the exception of the last-named they lie well within the region affected, and alone among the post-Carboniferous axes take that particular direction. The Pennine axis ends as a physical feature in South Derbyshire and North Staffordshire on the margin of a deep channel filled with Triassic marl, which extends westwards from Nottingham into Shropshire. In this part of England there springs into existence a remarkable series of disturbances tending to radiate southwards. The westernmost of these is the great fault which forms the western boundary of the North Staffordshire Coalfield. Recent work by Mr. W. Gibson has shown that the vertical displacement of the Coal Measures amounts to no Jess than 900 yards, but that it is far less, though recognisable, in the Trias, proving that the disturbance was in the main pre-Triassic. The fault ranges from Macclesfield in a south-south-westerly direction, is lost to view under the Trias near Market Drayton, but is recognisable further on in the great dislocation which passes along the western side of the Wrekin, and thence through Central Shropshire by Church Stretton to Presteign in Radnorshire, and thence into Brecknock. The second is the Apedale Fault of the North Staffordshire Coalfield. In work- ing the coal this disturbance has been found to possess the structure of a broken monocline, a fold with fracture such as may be regarded as an early stage in the formation of an overthrust from the east. It runs through the coalfield in a direction slightly east of south, and then passing under the Trias of Stafford ranges for Wolverhampton and Stourbridge. This fault is mainly pre-Triassic, but what Mr. Gibson believes to be a continuation of it, following the same direction as far south as Hanbury, certainly effects a great movement in the Trias. The third disturbance runs on the east of the Forest of Wyre Coalfield in a direction a little west of south. Here, as I learn from Mr. T. C. Cantrill, the thrust from the east is obvious, for Old Red Sandstone has been pushed from that direction against and even over Coal Measures, while the strata have been forced up into a vertical position for some miles. In South Staffordshire all the Carboniferous rocks, including the ‘Salopian Permian,’ are involved in this and the previously Span: movement, proving that both disturbances were of post-Carboniferous ate. Traced southwards, this disturbed belt leads to Abberley, and there connects itself with the well-known Malvernian axis, The broken belt known by that TRANSACTIONS OF SECTION C. 587 name runs north and south, and may be followed almost continuously from Worcestershire to Bristol. It presents evidence of having been a line of weakness through a large part of the world’s history, as shown by Professor Groom, and of having yielded repeatedly to earth-stresses; but there is seldom difficulty in dis- tinguishing the movements which were effected during the period under considera- tion. For example, near and south of Abberley the Coal Measures are clearly involved in a thrust from the east, which was sufficiently energetic to turn over a great belt of Old Red Sandstone and other rocks beyond verticality for some miles. Further south, again, among repeated proofs of the ridging up of the old axis in several pre-Carboniferous periods, we find evidence of post-Carboniferous elevation along the same general line. Throughout this same region there has been also post-Triassic dislocation, which, however, is on a comparatively small scale. That the Carboniferous rocks were greatly disturbed before the Trias was laid down is proved by the great unconformity between the two formations. The Malvernian axis continues southwards by Newent, but perhaps with diminishing intensity, On its west side a broad syncline rolls in the tract of Jarboniferous rocks which underlies the Forest of Dean. The syncline trends north and south, and is shown to be of pre-Triassic age by the fact that the Triassic strata on the banks of the Severn do not share in the synclinal structure. Here we must leave the Malvernian axis for the present. The fourth disturbance ranges along the Lickey Hills, which, diminutive as they are, tell a story of great geological significance. They range in a south- south-easterly direction, and in the fact that they are formed of extremely ancient rocks furnish evidence of immense upheaval. From the relations of these ancient formations to one another we may gather also that the upheaval was due to a recurrence of movement along the same axis at more than one geological date, but at the same time we find no difficulty in distinguishing that part of the movement which took place between Carboniferous and Triassic times, for the Coal Measures are tilted up on end along the flanks of the axis, while the Trias passes hori- zontally over all the tilted rocks. A clue to the southward extension of the axis under the Secondary rocks is furnished by some faulting as far as Redditch, here also there having been a renewal of movement on a small scale in post-Triassic times. The fifth disturbance runs through Warwickshire and includes the low ridge of ancient rocks which ranges through Atherstone and Nuneaton in a south-easterly direction. About fifteen miles to the north-east Archean rocks form the parallel ridge or series of ridges of Charnwood Forest, while the intervening space 1s over- spread by Trias, resting partly on Carboniferous and partly on older strata. The structure of the Carboniferous and older strata is dominated by what is known as the Charnian movement, which includes disturbances of several ages ranging in a south-easterly direction. That part of the movement which was post-Carboniferous is identifiable by the fact that Coal Measures are tilted on either side of the ridges of old rocks. They once overspread both ridges, but were removed by denudation as a consequence of upheaval before the Trias was deposited. It has been found also in working the coal, as I am informed by Mr. Strangways, that there are large faults having the south-eastward or Charnian direction which shift the Coal Measures, but do not break through the overlying Trias, The evidence, therefore, of a great Charnian movement having taken place during the period under considera- tion is conclusive. The disturbance ranges as a whole in the direction of Be auton, where in fact borings have reached the Charnwood rocks at no great epth. The five great disturbances which I have briefly indicated tend to converge northwards, but their exact connection with the Pennine axisis not known. What may be only a part of that axis trends for Charnwood through a tract of Lower Carboniferous rocks exposed at Melbourne, between the Yorkshire and Leicester- shire Coalfields, but the Triassic channel I have already mentioned intervenes, and the structure of the rocks underlying the red marl is unknown. The channel itself appears to be of Triassic age, for not only is the depth of mar! in it suggestive of its haying been a strait in the Triassic waters but its northern margin has been 538 REPORT —1904. found by Mr. Gibson to coincide with, and perhaps to have been determined by, faults known to be mainly of pre-Triassic age. One of these, with a downthrow of 400 yards to the south, runs from Trentham through Longton, and south of Cheadle, while another ranges from near Nottingham to the north of Derby. We come now to the south-west of England, where we find striking proofs of a still more energetic movement than any yet mentioned having intervened between the Carboniferous and Triassic periods. The central part of the Armorican axis, as it has been called, after the ancient name of Brittany, trends nearly east and west, and keeps to the south of our South Coast ; but we have opportunities in Deyon and Cornwall of seeing some of the stupendous effects produced along its northern side. A belt of country measuring some 130 miles in width has been completely buckled up. Slaty cleavage was superimposed upon the intricate folds into which the strata were being thrown, while after or towards the close of these phenomena granite was extruded at several points along the belt of dis- turbance, a little north, however, of the line alonz which the oldest rocks were brought up to the surface. In Devon the Culm-measures are fully involved in the movement, but on the other hand the Permian strata, while containing fragments of the cleaved and metamorphosed rocks, are themselves wholly free from such structures. The age of the folding, cleavage, and extrusion of the granite is thus definitely fixed as having been subsequent to the deposition of the Culm-measures, but previous to that of the Permian rocks, But we may fix the age still more closely. A broad syncline of Carboniferous rocks traverses Mid-Devon, and is succeeded northwards by an anticline and by an extrusion of granite at Lundy Island, the age of which, however, has not yet been definitely ascertained. Still further north in a series of folds and overthrusts which traverse the southern margin of South Wales we can recognise the last effects of the great Devonshire movement at a distance of not less than 130 miles from the central axis, the ground-swell, so to speak, subsiding as it receded from the distant storm-area. Here the higher Carboniferous rocks are involved, and thus prove that this part at least of the Armorican disturbance was of post- Carboniferous age. In Dorset, Somerset, and Gloucestershire the Paleeozoic rocks pass eastwards under Secondary formations, and are seen no more in the South of England. That the disturbance continues, however, is inferred from the fact that it has been traced across a large part of the continent of Europe in the one direction and across the South of Ireland in the other. The determination of its position there- fore, and especially of the effects of its intersection with the Midland disturbances, is of the greatest importance in view of the possible occurrence of concealed coal- fields under the Secondary rocks. One such intersection is open to observation. The Malvern and Devonshire disturbances intersect in Somerset. On investi- gating their behaviour as they approach we may notice in the first place that the subsidiary axes which form the northernmost part of the Devonshire disturbance in South Wales die away one after the other towards the east. Thus an east and west disturbance at Llanelly runs a few miles and disappears. ‘The more important Pontypridd anticline, which traverses the centre of the coalfield, fades away near Caerphilly, while the coalfield itself terminates a little further east, its place on the same line of Jatitude being taken by the Usk anticline, which trends southwards and south-westwards. So far it might be inferred that the east and west folds die away on approaching the north and south Malvernian axis. But the Cardiff anticline, which lies south of and was more energetic than those mentioned, crosses the Bristol Channel and, emerging on the other side in a com- plicated region near Clevedon and Portishead, passes to the north of Bristol and holds its course right across the coalfield at Mangotsfield. The coalfield, howeyer, lies in what is part of the Malvernian disturbance, for it occupies a syncline running north and south along the west side of the main axis of upheaval. Though the interruption is local and the strata recover their north and south strike to the south of it, yet the east and west axis obviously holds its course right through the Malvernian structure. Still further south in the direction in which the east and west movements TRANSACTIONS OF SECTION C. 539 eet increase in energy a series of sharp folds is well displayed in the coast of outh Wales and in an island in the Bristol Channel, ranging for that part of the east and west disturbance which is known as the Mendip axis. Thisname has been applied to a series of short anticlines which are arranged en échelon along a line ranging east-south-east, but each of which runs east and west. Among them we may distinguish the Blackdown anticline, the Priddy anticline, the Penhill anticline, north of Wells, and the Downhead anticline, north of Shepton Mallet. With one exception they all die out eastwards after a course of two to ten miles, but the Downhead anticline holds its course into the Malvernian disturbance, the two engaging in a prodigious mé/ée south of Radstock. From that much shattered region the Downhead anticline emerges, but the Malvernian axis is seen no more, and, so far as can be judged under the blanket of Secondary rocks, comes to an end. Mention has been made of the fact that many of the subsidiary east and west folds die away on approaching the Malvernian axis. In a general way we may attribute their disappearance to the influence of the north and south movement, for it is commonly to be observed in these great belts of disturbance that they are composed of a number of parallel anticlines or elongated domes of upheaval, con- stantly replacing one another ; it is a common feature also that these subsidiary folds replace one another not exactly in the direction in which they point, but that they lie en échelon along a line slightly oblique to it. The behaviour of the South Wales and Mendip folds is in accordance with these observations, and may be taken to indicate that the effects of the east and west disturbance reached further north in South Wales than they did in Somerset, or, in other words, that they failed to penetrate as far into the region where north and south movements were in progress as in the region where there were no movements of that direction. The fact that the east and west folds keep their course across the north and south wherever the two actually meet comes out prominently, and supports the inference that they dominate the structure of the Palzeozoic rocks which lie hidden beneath the Secondary rocks of the south and south-east of England. Somewhere under this blanket of later formations the east and west axis presumably intersects the other disturbances which traverse the Midlands. To ascertain where and how the intersections take place will he going far towards locating any concealed coal- fields which may exist ; but the knowledge can be obtained only by boring, anc the number of such explorations as yet made is wholly insufficient. The majority have been made in search of water, and have been stopped as soon as a supply was secured. Near Northampton the older rocks were reached at a small depth on what is believed to be the underground continuation of the Charnian axis, and a boring at Bletchley traversed what is thought to have been a great boulder of Charnian rock, suggesting that the axis is not far off; but with these exceptions the counties of Oxford, Buckingham, Bedford, Huntingdon, Cambridge, and Norfolk are unknown ground. Yet under these counties the axes must run if they keep their course. Where exposed at the surface each post-Carboniferous syncline between two axes contains a coalfield. It remains to future exploration to ascertain whether similar conditions hold good under the Oolitic and Cretaceous areas of Central England. In speaking of the north and south disturbances I have in more than one case stated that the post-Carboniferous movement was but a renewal of activity along an old line of disturbance. The fact is proved by the unconformities visible among the pre-Carboniferous rocks, and it is important for the reason that the geography of this part of the globe at the commencement of the Carboniferous period had been determined by these movements. It has long been known, for example, that the parts of the counties of Stafford, Warwick, and Leicester traversed by the axes of upheaval were not submerged till late in the Carboniferous period. On the other hand, some of the area lying immediately west of the Malvernian axis was submerged at an earlier date, as is shown by the existence of Carboniferous Limestone at Cleobury Mortimer and, in greater development, in the Forest of Dean. The borings near Northampton also proved the presence of Carboniferous Limestone, a fact which is in favour of the occurrence of concealed coalfields, in so far as it indicates that the wMole Carboniferous series may have once existed there. 54.0 REPORT—1904. It is remarkable that none of the borings in the South and East of England have touched Carboniferous Limestone, all having passed into older or newer rocks, The existence of that formation is neither proved nor disproved. The determination of the age of these disturbances and a discussion of the pre-Carboniferous geography may seem at first sight to be only of scientific interest, but that problems of great economic importance are involved has been shown recently. It has long been known that the principal coal-seam of South Stafford- shire deteriorates westwards as it approaches the pre-Carboniferous ridge evidenced in the neighbourhood of Wyre Forest. There seemed, however, to be no theo- retical reasons why it should not keep its characters on either side of the fault which forms the western boundary of the South Staffordshire Coalfield, inasmuch as that fault came into existence after the deposition of the Coal Measures. A shaft recently sunk has proved the correctness of the inference. The seam has been found to be well developed to the west of the fault, and a considerable addition has been made to our productive coalfields. So much has been written about the range of the Devonshire disturbance under the South of England that I shall add no more than a brief comment on some of the evidence on which reliance has been placed. We have seen that there has been some post-Triassic movement along old lines of disturbance in North Wales and the Midlands and along the Malvern axis. It is suggestive therefore to find that in the region which we believe to be underlain by the east and west disturbance east and west folding forms the dominant structure of the Secondary and Tertiary rocks. The anticlines of the Vales of Pewsey and Wardour, the London syncline, the Wealden anticline, the Hampshire syncline, and the anticline of the Isles of Wight and Purbeck, not only lie in the range of the axis, but show an increas- ing intensity southwards, towards what we may suppose to have been the most active part of that axis. A similar structure prevails in the Oolitic rocks also. They too had been thrown into east and west folds before the Cretaceous period, and this earlier set of movements also grew in intensity towards the south. It would seem, then, at first sight that the structure of the later rocks gives an easy clue to the structure of the older rocks buried beneath them. This is by no means the case. That the movements manifested in the Oolitic and Cretaceous rocks followed the same general line as the older movement admits of little doubt, but that the later structures correspond in detail with the earlier is improbable. A brief examination of the region where the Carboniferous rocks disappear under the Secondary formations will give the grounds for this statement. There we find that the Trias passes over the complicated flexures of the Mendip axis in undulations so gentle as to prove that those flexures had been completed before it was deposited. Nor again do the members of the Oolitic group of the rocks cropping out in succession further east show any such folds as those visible in the Carboniferous, and it is not till we have passed over a considerable tract of Secondary rocks in which there are no signs of east and west folding that we reach the anticlines of the Vales of Pewsey and Wardour. Nor can we then fit these folds in the Cretaceous formation on to any visible axes in the Carboniferous rocks. Under these circumstances it would be unjust to suppose that such synclines and anticlines as those of the London and Hampshire basins, or of the Weald, coincide with previously formed synclines and anticlines in the older rocks. They give a clue to the position of the old axis, but not necessarily to the details of its structure. Yet it is upon the determination of the position of the older anticlines and synclines, and of their intersection with the north and south disturbances, that: we must depend for locating concealed coalfields. So far but little has been done in the forty-eight years since the question was first mooted by Godwin-Austen, The existence of a coalfield in Kent has been proved, and what appears to be a prolongation of a disturbance from the Pas de Calais along the south-western side of it. The other borings which have reached the Paleozoic floor round London and at Harwich have thrown but little light on the details of its structure. By far the greater part of the ground remains yet to be explored. In this brief review of the earth-movements of on’e-period, as manifested in one , 1904. ] [Puate VIII. | OF POST-C eee / 2 | rs, &c. of post- Carboniferous | hown thus :— | re shown thus:- | re shown thus :— 55 4 SPOTTISWOODE & CF LIP LITH. LONDON Il lus British Association, 74th Report, Cambridge, 1904.] (Prare VIII. MAP OF POST-CARBONIFEROUS AND PRE-PERMIAN EARTH-MOVEMENTS. By A. Strahan, MA, FR.S. ~ Be The position of faults, anticlines, &€. of post-Corboniferous and pre-Permian date are shown thus.— ————_—__ When hypothetical thus:— Synclines of the same age are shown thus. eceosccsoesoe Post-Permian anticlines &c.a°¢ shown thus — ARLISLE Maryport | Whitehovenp Barnard Castle St Bees’ °Kendol Mire 20 CLANCASTER Sse ykeighlay B QFORD HUDDERSFII Penistone’ 51 LIVERPOO WERryELn || ) “Chesterfield! Ceebury WIRE erin FOR) READING No rt MAIDSTONE & dicing Cj 'U/LDFORD| od inbridge (Alton — Horsham A , rMmor/ Can Wardodre e«saLiSBYRY “Haslemere we Vie 7 Carboni feroys) axis le Presta aah —— Se bore alewes jostings = CHICHES: Ridgeway Purb VY, --- SCALE English Miles 69/4= One Degree, 5. 60 ] TRANSACTIONS OF SECTION C. 541 small part of the globe, we have found reason to conclude that they were the result of compression and upheaval; that the crust yielded to the compression by overthrusting and buckling along certain belts; that these belts in the North of England and the Midlands ran for the most part north and south, diverging, how- ever, to the south-west and to the south-east, while in the South of England they took an east and west direction and concentrated themselves along a belt of country which presents the phenomena of crushing on a stupendous scale. We have onshed in two cases the flanks of a mountain-range—the Caledonian, which was built and ruined before the Carboniferous period ; the Armorican, which was built after that period, and which, though it has stirred so recently as the late Tertiary period, and so energetically as to initiate the physical features and river-system of the South of England, yet expended the greater part of its energy before the Permian period. Lastly, we have found evidence, in the majority of cases, that the disturbances were but renewals of movement along lines of weakness long before established, and that in several cases there has been further renewal along the same lines during successive periods later than the one we have considered. With such a history before us, and with the knowledge that mountain-ranges have been built in other parts of the world by the upheaval of strata of almost recent date, we have more cause to wonder that the internal forces have left this quarter of the globe alone for so long, than reason to believe that they have ceased to exist. Changes of level, however, have taken place in comparatively recent times, and are now in progress. Though almost imperceptibly slow, they serve to remind us that a giant lies sleeping under our feet who has stretched his limbs in the past, and will stretch them again in the future. Nor in view of the fact that the structures I have described have only been revealed by the denudation of vast masses of strata does it seem unreasonable to suppose that they are deep-seated phenomena. The slow changes of level may be the outward manifestation of more complicated movements being in progress at a depth. It is interesting to speculate on what appearance the globe would have presented had it not been enveloped in an atmosphere and covered for the most part with water. Owing to those circumstances it possesses the power of healing old wounds and burying old scars. In their absence we may suppose that the belts of crushing and buckling would have given rise to ridges growing in size at every renewal of movement, for they would have been neither levelled by denudation nor smoothed over by sedimentation. This globe, we may suppose, would have appeared to the inhabitants of another planet as being encompassed in a network, and we are prompted to ask whether our astronomers can distinguish in any other planet markings that may be attributable to this cause. I must remind you, however, how much more remains to be done than J have been able to touch upon to-day. The map represents one episode only in a long series of events, and a series of such maps would be required to illustrate the first appearance of lines of weakness in the earth’s crust, the subsequent renewals of movement along those lines, and the formation of new lines in successive geological periods. With the case thus set out we shall be justified in appealing to the physicists for an - explanation of the restlessness of this globe. The following Papers and Report were read :— 1, The Geology of Cambridgeshire. By J. E. Marr, Sc.D., 7.RB.S. The main physical features of the county are the Chalk uplands of the south- eastern and southern part, the curious plateau on the west, the Cam Valley between them, and the fenland of the north. Of Jurassic rocks, the Oxford Clay is not well exposed save near Whittlesea. The Corallian rocks are of considerable interest. Two types occur—the Ampthill Clay facies of the western outcrop and the Calcareous facies of the Upware Inlier. The Elsworth rock forms the base of the deposits of each of these types, and its relationship to the members of the Calcareous facies is a subject still under discus- 542 REPORT—1904. sion. The Upper and Lower Kimmeridge Clay are found at Ely and in the neigh- bourhood of that city. Of Cretaceous rocks the Lower Greensand is well seen near Gamlingay. The old phosphate workings of Wicken are now closed. The Gault is seen in many exposures. Most of the sections exhibit Lower Gault, but Mr. Fearnsides has recently detected the Upper Gault in the Barnwell brick-pit. The basal member of the Chalk, the well-known Cambridge Greensand phosphatic seam, lies uncon- formably upon the Gault. It is succeeded by various divisions of the Chalk up to the zone of Micraster. The glacial deposits consist chiefly of the chalky boulder clay ; the great boulder at Ely is of interest. The Pleistocene gravels include the plateau gravels on the chalk hills and the well-known mammaliferous gravels forming terraces on the valley-sides. The March marine gravels are usually correlated with the gravels of one of these terraces. Alluvium is found on the valley-bottoms, and in the fenland peat occurs with intercalated patches of Scrobicularia clay. The peat contains the fauna of Neolithic and later times. 2. The Great Eastern Glacier. By F. W. Harmer. This name is proposed for the great ice-stream, the moraine of which, the chalky Boulder Clay, covers an area of more than 5,000 square miles in the East of England, frequently attaining a thickness of more than 100 feet. As far back as 1858, Trimmer, a pioneer in glacial investigation, had pointed out that the county of Norfolk had been twice invaded by ice, first from the North Sea and then from the west, the resulting detritus in the one case being characterised by igneous blocks, some of them of Scandinavian origin; and in the other by a predominance of Jurassic material. The first invasion is represented by the Cromer Till and the contorted Drift of the Norfolk coast; the second, which does not occur in north-east Norfolk, by the chalky Boulder Clay, the subject of the present paper. The region covered by the latter deposit, which extends over a great part of the eastern counties of England, has a palmate outline, its lobes, which radiate from the great depression of the Lincolnshire and Cambridgeshire Fens, being of unequal length, The latter region was not only the centre whence the chalky Boulder Clay was distributed, but also the quarry out of which was excavated the enormous mass of Jurassic material forming to a great extent the matrix of this deposit. The present physiographical features cf the East of England closely resemble those which obtained in glacial times, the Drift deposits not only covering the plateaux between the valleys in which the rivers of the district now run, but descending into them, sometimes to below sea level. Hence by the study of the existing contours, aided by that of well-borings, it is possible to obtain a general - idea of the preglacial topography by which the movements of the ice must have been influenced. Although the erratics of the chalky Boulder Clay are more or less of a similar character over a wide area, indicating that it was distributed from a common centre, its predominant character varies in different districts, in accordance with that of the strata over which the ice moved. The matrix of the Boulder Clay of south Norfolk and north Suffolk, for example, has been largely derived from the Kimmeridge Clay. Over this region, which formed in glacial times a shallow trough running east and west, corresponding with the present depression of the basins of the Little Ouse and the Waveney, as well-as with the gap in the Chalk escarpment between Swaffham and Newmarket, the ice evidently poured in great: volume, planing down the surface of the Chalk and carrying its Kimmeridgian material fifty miles to the east from its original source in the Fen basin. On the other hand, although the Fen ice was sufliciently thick to enable it to overflow TRANSACTIONS OF SECILION C. 543 the Chalk hills between Newmarket and Royston, it only travelled thence to the south-east for about half that distance. In this region the Boulder Clay is chalky near the escarpment, while beyond the outcrop of the London Clay it is mainly composed of detritus from that formation. oo. ; Along the basin of the Ouse, where its matrix is largely Oxfordian, the ice to which it was due advanced much further, to Buckingham and beyond, as it also did along that of the Nene, in the direction of Northampton. On the contrary, the high land near the head waters of the Welland obstructed the ice-tlow, so that but little Boulder Clay seems to have found its way into the area comprised in sheet 53 of the Ordnance map. ‘The greater part of sheet 63, however, is covered by it, and it there reaches an elevation of 730 feet above the sea level. Much of the Boulder Olay of this region, in the author’s opinion, was due to the ice-stream of the Trent Valley having been piled up upon the high land to the east of Leicester by the pressure of ice descending from the Pennines. It seems probable that the whole of the low-lying region between the Lincoln- shire Wolds and the Pennines was filled with ice during the period of maximum glaciation. It is not physically possible that any considerable thickness of ice could have existed on one side only of the Lincolnshire ridge, which does not often exceed an elevation of about 200 feet above the lower ground adjoining it. The author hopes to make the ultimate source of the chalky Boulder Clay ice the subject of a future paper. The prevalence of Carboniferous dédris in the East Anglian region seems to indicate, however, that a part of it at least was of Pennine origin ; another part may have been due to an overflow from the North Sea across the lowest part of the Chalk Wolds, and the ice may also have been reinforced by the abundant precipitation to which this district was subject during the Glacial period ; the moisture-bearing cyclonic disturbances from the Atlantic, to which the enormous accumulation of ice in the Baltic region was due, must have passed near the eastern counties of England. There is no evidence to show that any considerable amount of ice entered East Anglia through the Wash gap, all the facts known to the author appearing to point in an opposite direction. 3. On a Great Depth of Drift in the Valley of the Stour. By W. Wuiraker, /.2.S. Several cases of great irregularities in the thickness of the Drift have been shown by borings in Suffolk, where the existence of deep channels filled with Drift has been practically proved, as also in the neighbouring counties of Essex and Norfolk. In some cases these channels cannot be shown on the map, the Glacial Drift being hidden by deposits of later age, and this is markedly the case in the upper part of the valley of the Cam, where at one place (Newport) the Drift has been pierced to the depth of 340 feet: without reaching the bottom. In Suffolk the greatest amount of Drift recorded is at Brettenham Park, where apparently a thickness of 312 feet has been found. But this and all other records in Kast Anglia are now put into the shade by the result of a boring near Glems- ford railway station. This is ata low level in the valley of the Stour, in the tract formed by the sand and gravel that crops out from beneath the Boulder Clay of the higher ground. Here one would have expected, perhaps, some 50 feet of Drift; but certainly not more than 100. No less than 477 feet have been passed through, before reaching the Chalk. The gravel and sand that form the surface reached to a depth of 51 feet, as might have been expected; but then the unexpected occurred, no Jess than 228 feet of boulder clay (partly sandy) having been found, with a mass of sand and clayey sand beneath. We seem here then again to have evidence of a very deep Drift-filled channel. A well in the village, at a higher level, has reached Chalk after passing through 120 feet of Drift; so the channel does not reach far northward, nor does it reach to Foxearth, in Essex, about a mile to the south, where there is a still less thickness of Drift. As to its direction or extent, however, we can say little as yet. 544 REPORT—1904. One may add that a boring (? unfinished) in Euston Park has proved over 150 feet of Drift, at a spot where no Drift is shown on the map. This may be simply a huge pipe. 4. Well-sections in Cambridgeshire. By W. Wurraxer, IRS. See Reports, p. 266. 5. Note on a Small Anticline in the Great Oolite Series at Clapham, north of Bedford! By Horace B. Woopwarp, /.2.S. Attention was drawn to a gravel-pit between Oakley and Clapham, in which a small anticline of the Great Oolite had been abruptly encountered amidst the regularly stratified river-deposits. The trend of the fold was N.N.W. and S8.E., and therefore contrary to that of the minor undulations which affect the Oolitic rocks of the district, and which serve to counteract the general dip of these strata between Sharnbrook and Bedford. Prior to the opening of the pit there was no surface-indication of the disturbed rocks, but the arch was coated with Great Oolite clay which had superficially been disarranged and mixed with gravel. There was no evidence to connect the disturbance with glacial action, nor was there any direct evidence against such a supposition. The Oolitic strata may have been planed down prior to or during the period of maximum glaciation, when the boulder clay, which crowns the adjacent plateau, was laid down. ‘The erosion of the softer strata flanking the arch of Great Oolite limestone may have been due to the actiun of the river, the harder rocks having stood up as a low ridge until levelled up by the accumulation of the valley deposits. A portion of a molar of Elephas primigenius was obtained from the gravel; also a somewhat decomposed block of rhomb- porphyry, evidently derived from the boulder clay. The occurrence of this Scandinavian rock was of interest, as, according to Professor P. I’. Kendall, it had not been previously found south of Norfolk.’ 6. Recent Coast Erosion in Suffolk—Dunwich to Covehithe. By JouN SPILLER. This communication brings up to date the record of losses on the Suffoll coast, and continues the Report presented at the Ipswich meeting, 1895, of which details were published in the ‘Geological Magazine’ for January 1896, Since that time scarcely a year has passed without the winter gales and high tides doing mischief at one or more points of the coast embraced within the limits above specified ; but whilst Lowestoft and Pakefield, Covehithe, and Easton have all suffered very con- siderably, the cliffs at Dunwich, until quite recently, remained almost unaffected. The losses may be summed up as follows :— Dunwich. All Saints’ Church Ruins and Graveyard.—The 43 feet of land reported by Mr. Whitaker, September 1880,3 became 25 feet by Mr. Teall’s measurement in 1902. Now this has all gone and about 6 feet of northern buttress and east end of the Church have dropped into the sea, Total loss, 31 feet in two years. Footpath at Temple Hill.—Mr. Whitaker says, ‘40 yards outside the wood.’ Mr. Teall in 1902 made it 38 yards. It is now diminished to 59 feet. Actual loss, therefore, 55 feet in two years. The cliffs extending away north and south 1 Printed in full in the Geological Magazine, Decade V., vol. i. pp. 439-441. 2 See Eighth Report of Committee on Erratic Blocks, Rep. Brit. Assoc. for 1903. 3 See Memoir of the Geological Survey, Southwold and the Suffolk Coast, hy W. Whitaker, F.R.S., p. 48. TRANSACTIONS OF SECTION C, 545 have lost more than this, except at Misner. The lifeboat at the Coastguard Station cannot be used at present, for the shingle beach is gone and the boathouse perched on a terrace. Ordinary tides reach the foot of the cliffs, and further losses may be expected. Walberswick, _ The high shingle beach is cut back all the way from Dunwich to the mouth ot the river Blyth, Southwold. As the result of lengthening the old North Pier at the harbour a good deal of sand and shingle has been thrown up, but not enough to replace that lost in front of the lifeboat house, which is now practically useless and embanked for further protection. It has been suggested that another 50 feet might be added on to the Pier, and that the old jetty near the centre cliff should be reconstructed. The timber breastwork in front of the town has stood well since it has been continued to Buss Creek and strengthened at critical points by double piling. The new pier, 880 feet long, erected by the Coast Development Company at the North Cliff has acted like a groyne, and vastly increased the beach on both sides of it, so that the Bathing Station, threatened with destruction in 1895, is better than ever. Easton. The low land extending from Buss Oreek to the southern slope of Easton Cliff remains as before, protected by a huge bank of shingle, but from this point onward to the Broad great losses have occurred. The site of the gun battery is buried out at sea, and the powder magazine behind it now left in ruins on the shore, 50 feet outside the present edge of cliff. The rifle range has been shortened by 100 yards and a new butt constructed, so that the total loss may be estimated at 350 feet since 1895. The effect of this demolition is to bring Covehithe Ness into view, whereas it was formerly invisible from Southwold. Another necessary con- sequence is that the coast line, straight in-the Ordnance map, has once more become curved inwards, corresponding with the original Sole Bay. The seam of shelly crag at the foot of Easton high cliff was uncovered a year ago for the length of 40 yards, but is now entirely hidden by masses fallen from the cliff. The measures of loss (nine years) are as follows :— Easton Cliff, southern end . 5 . 350 feet. Roadway, Easton Bavents . : ny LODE ss Easton high cliff . - A . seep CU sy Covehithe. Beyond Easton Broad the cliffs leading to Covehithe are constantly presenting new faces with bright yellow and pink colouring, suggestive of Alum Bay. The losses would probably have been greater but for ledges of hard sand rock, pro- jecting out some 12 to 15 feet and acting as benches for the support of the upper strata. At Covehithe roadway frequent measurements have been taken since 1895, showing gradual diminution in length from 62 yards to a remnant of 19 yards, Total loss in nine years = 129 feet. 7. Report on the Fossiliferous Drift Deposits at Kirmington, Lincolnshire, éc.—See Reports, p. 272, 1904. NN 546 REPORT—1904. FRIDAY, AUGUST 19. The following Papers and Reports were read :— 1. On the Structure of the Silurian Ophiurid Lapworthura Miltoni. By Professor W. J. Sotias, /.R.S. The structure of the arms and jaws of this fossil were described from informa- tion obtained by a study of serial sections, and reconstructions built up from these were exhibited before the Section. 2. The Base-line of the Carboniferous System round Edinburgh. By B. N. Peacu, LL.D., P.RS., and J. Horne, LL.D., FBS. In the last edition of the Geological Survey map embracing the Edinburgh district (Sheet 32), published in 1892, strata of Upper Old Red Sandstone age are represented as occupying the area that stretches southwards from the Castle by Morningside and Newington to the Lower Old Red Sandstone volcanic rocks of the Blackford Hill and Braid Hills. The rocks consist of conglomerates, red sand- stones, marls, and cornstones. The correlation of these strata with the Upper Old Red Sandstone was based, not on fossil evidence, but partly on their lithological characters, and partly on the fact that along their eastern margin they pass con- formably upwards into the Cementstone group of the Carboniferous system. The Cementstone group as developed in the Edinburgh district consists of grey, green, and red mudstones, and shales with cementstone bands, occasional sandstones, and rarely some thin seams of dark carbonaceous shales yielding plants, ostracods, and Paleoniscid fish-scales of undoubted Carboniferous type. In the last edition of the Edinburgh sheets all the beds between the Castle and the voleanic rocks of Arthur’s Seat were included in the Calciferous Sandstone series. Our colleague, Mr. Goodchild, however, suggested that the sandstone underlying the dolerite sill of Salisbury Crags is of Upper Old Red Sandstone age in virtue of the cornstone associated with it, which in the Edinburgh district 1s characteristic of that formation. During the revision of the Carboniferous area round the city, Dr. Peach recently detected minute fragments of fishes in this sandstone where it is exposed at the side of the Queen’s Drive. These were ex- amined by Dr. Traquair, who considered them to be fragments of dendrodont (Holoptyehian) teeth, though not specifically determinable. Permission having been granted by H.M. Office of Works in Scotland to charge the rock exposure with dynamite, a mass of material was set free, which, when broken up by the fossil collectors, Messrs. MacOonochie and Tait, yielded conclusive fossil evidence. After examination Dr. Traquair determined a number of specimens of teeth and scales which undoubtedly belong to the genus Holoptychius, a characteristic Upper Old Red Sandstone form. Accepting this determination, it is obvious that the cementstones to the west must be faulted down against the Upper Old Red Sand- stone of Salisbury Crags. Attention was next directed to the Craigmillar sandstones lying to the north of Arthur’s Seat, and hitherto grouped with the Carboniferous formation by the Geological Survey. Mr. Tait here obtained a number of very fragmentary fish- remains, one of which, according to Dr. Traquair, is an unmistakable fragment of a scale of Holoptychius. Therecan be no doubt, therefore, that the Craigmillar sandstones are also of Upper Old Red Sandstone age, At Raeburn’s Brewery, not tar trom Duddingston Station, they are overlatd by dark shales and sandstones, “with a thin eoaly seam full of plant remains of Carboniferous type. Thereatter a special examination was made of the sections north and south of the Warklaw Hill, four miles south-west of Edinburgh, which is formed of Lower Old Red Sandstone volcanic rocks, where conglomerates, pebbly sandstones and corn- stones rest unconformably on that platform, and are overlaid by the Cementstone croup. After careful searching by Mr. Tait, fish fragments were found which Dr. TRANSACTIONS OF SECTION ©, 5A7 Traquair considers fragmentary and indecisive. No undoubted Holoptychian remains were obtained. Those that have recognisable affinities are of Dipnoi and Rhizodontide, and might be either of Upper Old Red or Carboniferous age. Notwithstanding the indefinite fossil evidence, it is highly probable that the con- glomerates, pebbly grits, and cornstones of Clubbiedean and Torduff are the equivalents of the sandstones and grits of Craigmillar and Salisbury Crags. This discovery seems to us of special interest and importance, because (1) it is the first record of undoubted Upper Old Red Sandstone fish remains in the Edin- burgh district ; (2) it defines more precisely the area occupied by this formation round the city—.a point of practical importance, as these sandstones are the source of the water supply for the local brewing industry; (3) it raises the question whether the base-line of the Carboniferous system throughout Scotland should not be drawn where the Ballagan type of the Cementstone group first appears. 3. Note on the Fish-remains recently collected by the Geological Survey of Scotland at Salisbury Crags, Craigmillar, Clubbiedean Reservoir, and Torduff Reservoir, in the Edinburgh District. By Dr. R. H.Traquatr, FRS. The fish-remains from the sandstones of all these localities are very fragmentary, but from the Salisbury Crags sandstone portions of teeth of dendrodont, that is, Holoptychian fishes, are distinctly recognisable, and a piece of a scale was referable . to Holoptychius nobilissimus, a characteristic Upper Old Red Sandstone fish. Among the fish-remains from Craigmillar, a portion of a scale also with the sculpture of Holoptychius nobilissimus has been found, The remains from Clubbiedean and Torduff Reservoirs are still more fragmen- tary, and of the fragments none distinctly referable to Holoptychius have been as yet detected. Fragments referable to Rhizodont and Dipnoan fishes are present, but not generically or specifically identifiable, and it is therefore impossible to say whether they are of Upper Old Red or of Carboniferous age. 4, On the Fauna of the Upper Old Red Sandstone of the Moray Firth Area. By Dr. R. H. Traquair, F.R.S. The fish fauna of the Upper Old Red Sandstone of Britain is better developed in the Moray Firth area than in any other. There are twenty-two determinable species, of which four are noted in this paper as new. Of the genera, the most noteworthy and characteristic are Psammosteus, Asterolepis, Bothriolepis, and Holoptychius. In this region we have evidence of three successive zones of fish life in the Upper Old Red— 1, That of the Nairn sandstone, being apparently the lowest, and characterised by Psammosteus tesselatus, Asterolepis maxima, and Holoptychius decoratus. 2. That of the Alves beds, including the well-known Scat Craig deposit, and characterised by Psammosteus Taylori, Bothriolepis major, and Sauripterus crassidens. Holoptychius giganteus and H., nobilissimus are also common, 3. That of the Rosebrae beds, apparently the highest of the Upper Old Red of the district. Holoptychius giganteus and H, nobilissimus are equally common in these sandstones and in the nnderlying Alves beds. Bothriolepis major is also found, but of comparatively small size, but there is a complete absence of the venus Psamimosteus. The presence of Phyllolepis concentrica, Glyplopomus minor, and Phaneropleuron Anderson/ turnishes, however, au interesting correlation with the uppermost Old Red beds of Dura Den, in Fiteshire. The author expressed his great indebtedness to Mr, W. Taylor, of Lianbryde, near Elgin, for furnishing him with most valuable material for prosecuting these researches into the fauna of the Upper Old Red Sandstone of the North of Scotland. NNQ kK 548 REPORT—1904. 5. Note on Lower Cretaceous Phosphatic Beds and their Fauna, By G. W. Lampiuen. It has been customary to regard the fossils more or less imperfectly preserved in the condition of phosphatic casts in different parts of the English Lower Cretaceous series as derivative from the Jurassic rocks. In previous papers the writer has brought forward evidence to show that the fauna of such beds at Speeton and in Lincolnshire is not derivative, but occurs at its proper horizon and, so far as it goes, indicates the life of the period. Personal investigation of the localities, and of the fossils obtained from the ‘coprolite beds’ at Upware, Potton, and Brickhill, has led him to conclude that in these deposits also the greater part of the so-called derivatives are really of Lower Cretaceous age. Thus one of the most abundant phosphatic fossils of these places is the ammonite, usually fragmentary, which has habitually been named Amm. biplea, but belongs in almost every case to one or another of several allied species of Lower Cretaceous Olcostephani. Most of the lamellibranchs can likewise be best matched by Lower Cretaceous forms; and there are good grounds for suspecting that many of the saurian- and fish-remains from the above-mentioned places and from the Faringdon ‘Sponge Gravels,’ which have been classed as Jurassic, are true Lower Cretaceous forms. It is acknowledged that the presence of transported pebbles of older rocks in the deposits at Upware, Potton, and Faringdon renders the occurrence of deriva- tive fossils at these places more probable than in the case of the Speeton and Lincolnshire ‘ coprolite beds’; and in the collections examined a few specimens were noticed that seem to have been washed from older rocks. But the writer believes that these instances are exceptional, and he urges that no fossil should be set down as derivative unless the evidence is conclusive, as much confusion has arisen through the unquestioning adoption of the hypothesis of derivation. While there is still much to be learnt as to the physical conditions requisite for the concretion of phosphatic nodules and for their segregation into bands, it seems clear that an important determinative was the existence of submarine currents occasionally impinging upon the sea-floor with sufficient strength to sweep away the matrix in which the nodules had been formed, so that there was a gradual accumulation of the partially eroded nodular residues. Such residues, though of inconsiderable thickness, may represent a long period of submarine con- ditions, The term ‘aggregate deposits’ has been suggested by J. F. Blake for beds of this character. 6. On Marine Fossils from the Ironstone of Shotover Hill, near Oaford. By G. W. Lampiueu. (Communicated by permission of the Director of the Geological Survey.) _ The presence of casts of marine fossils, including Trigonia, Perna, and Modiola, in an ironstone rock on Shotover Hill resembling in appearance that which contains the Lower Oretaceous freshwater fossils, Unio, Cyrena, and Paludina, has long been known, but the horizon at which these marine fossils occur has not hitherto been ascertained. The writer found that these marine forms occur at the base of the Ironsand series, in a rock which appears originally to have been a sandy limestone, now converted, sometimes wholly and sometimes partly, into an ironstone by the replacement of the lime by iron. In other parts of the outcrop the limestone has been silicified, and the fossils are then almost entirely obliterated. From its position and fossils it is concluded that this rock belongs to the Port- landian series, and represents a portion of the Upper Portland stone, converted to its ee state through the infiltration of ferruginous waters from the overlying ironsands. TRANSACTIONS OF SECTION ©. 549 7. On the Fossil Plants of the Upper Culm Measures of Devon. By EH, A. NEwett Arser, Jf. A. The Upper Culm Measures form by far the largest portion of the Carboni- ferous sequence in Devon and the adjacent counties. Fossil plant remains are abundant in these beds, but their preservation is rarely sufficiently good to permit of even generic determination. A number of well-preserved specimens have, how- ever, recently been obtained from the one horizon in which coal or ‘culm’ occurs in these beds in the Bideford district. They include Calamites undulatus, Calamo- cladus charefornus, Alethopteris lonchitica, A. Serli, Neuropteris obliqua, Sigillaria tessellata, and many others. Neuropteris Schlehani and Megalopteris (F)sp. are also recorded from Britain for the first time. This flora confirms the previous conclusions with regard to the Upper Car- boniferous age of these beds, and indicates that the coal-bearing beds of the Bideford district are the equivalents of the Middle Coal Measures elsewhere in Britain—a higher horizon than has previously been assigned to these beds. 8. On Derived Plant Petrifactions from Devonshire. By HK. A, Newent Arser, Jf.A. Some interesting plant petrifactions in which the structure has been to some extent preserved by means of a mineral agent have recently been discovered in the higher beds of the Upper Culm Measures (Upper Carboniferous) in Western Devon. Although the preservation is not sufficiently good to render this dis- covery of any botanical importance, the manner in which the fossils occur is interesting from a geological point of view. The plant remains consist of small rolled fragments of stems, of an inch or less in length, arranged without order in a fine-grained sandstone. They are in all probability derived from some pre- existing beds, and are not contemporaneous with the sandstone in which they are found. Such derived plant remains are very rare, if not unknown, from the Paleozoic rocks. 9. Report on the Fauna and Flora of the Trias of the British Isles. See Reports, p. 275. 10. On Lootprints of Small Fossil Reptiles from the Upper Karroo Rocks of Cape Colony. By Professor H. G. Sunny, /.R.S. The author recognised a slab of fine-grained sandstone in the Paleontological collection of the University of Munich, which contains impressions of the feet of three kinds of reptiles and also preserves casts of small phalangeal bones terminated by compressed claws. This was collected about 1880, near Middleburg, together with a small Theriodont skull allied to Hyorhynchus. The surface of the slab appears to show faint ripple marks, an inch or two apart. The larger footprints cross these markings at an angle of about 45°. The prints are in relief; indicate a pentadactylate animal, with the fore and hind feet of nearly equal size. The digits are widely spread, stout, and terminate bluntly, without any indication of claws. The palmar surface is most convex towards the first digit, and there is a convexity under each metacarpal and metatarsal bone. The point is less deep towards the outer side, so that the outermost digit appears to be exceptionally slender. The width of the hand is about one inch, and the length did not exceed one inch and a half; at the carpal border the width is eight-tenths of an inch. There appear to be four bones in the distal-tarsal row. The hinder tarsal border is formed of three convex curves, which appear to indicate the three bones in the proximal tarsal row. There is a slight impression of the tail, showing a fine granular skin ornament, arranged quincuncially. In size the digits are not unlike those of Mesosaurus, though in the shorter 550 REPOR?—1904. metapodial bones they are more like Procolophon. ‘Their generic relation is not determined. Two other animals of smaller size are indicated on the same slab. Both have the digits parallel, and apparently four in number, like some from the Trias of Cheshire. ; A cast of this slab was made by the late Professor v. Zittel. and given to the author for description and presentation to the British Museum. This is the first record of footprints in the Karroo rocks, 11. Report on Life Zones in the British Carboniferous Rocks,—See Reports, p. 226, be MONDAY, AUGUST 2 The following Papers were read :— 1, Discussion on the Nature and Origin of Earth Movements. i, Introduction, By AuBRey STRAHAN, M.A., F.R.S. The subject proposed for discussion is the nature and origin of those move- ments of the earth’s crust which have manifested themselves in the fracturing, overthrusting, and folding of strata. These movements have been in operation from the earliest to the latest geological periods; and, though they have been intermittent so far as any one region is concerned, there is reason to believe that they have been more or less continuously in action throughout the world as a whole. Their operation, in fact, is essential to the existence of a land surface, for in their absence all rocks projecting above the sea would be worn away, and the globe would become enveloped in one continuous ocean. Notwithstanding these facts, and though they have been the object of pro- longed study, no theory as to the cause of the movements has commanded universal acceptance. Without attempting to enter in detail into the various theories which have been advanced, I will merely point out, for the purposes of the present discussion, that, while some hold that the shrinking of the globe by cooling and the efforts of the crust to adapt itself to the shrinking interior are the prime causes, others maintain that the scale on which folding and overthrusting in the crust have taken place is out of all proportion to the shrinking that can be attributed to such a cause. Earth movements may be divided into two principal classes—namely, move- ments of expansion, which are evidenced in normal faulting; and movements of compression, such as are indicated by the buckling, overthrusting, and shearing of strata, by the superinduced structures of cleavage and schistosity, and by the extrusion of granitic rocks and metamorphism. All these phenomena have been made the subject of special study, and I believe that no better opportunity could be found than a meeting of this Section for comparing the views of specialists upon them, and for ascertaining how far those views point to a general agreement as to the causes of the earth movements upon which these phenomena are attendant, ii, Contribution by Dr. Joun Horne, F.R.S. The Earth Movements in the North-West Highlands. The nature of the earth movements in the North-West Highlands in post- Cambrian time was illustrated by a series of horizontal sections across the belt of complication, that stretches from the north coast of Sutherland to Sleat, in Skye. TRANSACTIONS OF SECTION C. tapi It was shown that, though the sections vary indefinitely along this belt, there aie certain features characteristic of different stages of the movements which con- stitute well-marked types. In the strip that generally intervenes between the undisturbed area to the west and the powerful thrusts to the east, the geological structures may be arranged in two groups: 1. The strata are thrown into a series of inverted folds accompanied by reversed faults or thrusts, which dip in one general direction towards the E.S.E.; this type is well represented in the region of Eriboll and in the mountainous district south of Loch Maree. 2. Without incipient folding, the strata are repeated by a series of minor thrusts or reversed faults which lie at an oblique angle to the major thrust-planes, and dip in the direction from which the pressure came—that is, from the E.S.E. This type is admirably displayed in Glen Coul, in Glen Dhu, and on the hill slopes N.N.W. of Inchnadamph, in Suther- landshire. It sometimes happens, however, that the structures characteristic of this stage of the movements are buried underneath the materials driven westwards by the powerful thrusts ; but wherever denudation has laid bare the reduplication of the strata in advance of the great displacements, these structures are found. The features characteristic of the more powerful thrusts may also be arranged in two groups. In the first, masses of Lewisian gneiss, Torridon sandstone, and Cambrian rocks are made to override the underlying piled-up strata, and in some cases to overlap other thrusts to the west. Owing to the movements of the strata from east to west, and also to the friction along the plane of the thrust, the strata fold over and curve under the Lewisian gneiss, thus producing inversion of the beds. These features are exemplified in the Eriboll region, in Assynt, and in the Loch Maree district, by the Arnabol, Glen Coul, Ben More, and Kishorn Thrusts. The materials brought forward by these displacements can be referred to different types of Lewisian gneiss occurring to the west, and to the respective sub-divisions of the Torridonian and Cambrian systems. In the second group, which is represented solely by the Moine Thrust, the Eastern Schists, composed of quartz-schists, mica-schists, and muscoyite-biotite schists, with lenticular masses of acid and basic gneisses of Archzean type, are driven westwards, and in some cases overlap all major and minor thrusts till they rest directly on the comparatively undisturbed Cambrian strata, The planes of the major or powerful thrusts along which the materials have been driven are usually inclined to the E.S.E. at low angles, but in some cases they are folded, and, more rarely, are almost vertical. One of the distinctive features of the major thrust-planes is, that their outcrops resemble the boundary lines between unconformable formations, because (1) there is a complete discordance between the strata lying above and below the planes of disruption; (2) each successive thrust may be overlapped in turn by the higher one. By means of denudation, outliers of the materials lying above the thrust-planes are formed, of which excellent examples occur near Inchnadamph, in Assynt, and to the south of Loch Maree. iii. Contribution by J. J, H. Tratt, M.A., F.B.S, Effects of Earth Movements on Rocks, The effects of earth movements on rocks may be either local or regional. Local effects are confined to the immediate neighbourhood of dislocations ; regional effects are observable over areas that may be measured in tens, hundreds, or even thousands of square miles. Fault-breccias and mylonites may be cited as well-known examples of local effects, the former being especially characteristic of normal faults and the latter of thrust-planes. In the majority of cases fault-breccias and mylonites are formed at the expense of the adjacent rocks, but this is not always the case. Vein-stones have not infrequently been deposited in cracks and fissures along which movement has taken place, Some of the tin lodes of Cornwall, for example, give evidence of 552 REPORT—1904. two or more periods of infiltration, followed by movements which have broken up the previously deposited material, consisting of quartz, tourmaline, and tin- stone. In the cases above referred to the evidence of the mechanical fracture of the rocks and of their constituent minerals is obvious, but in those which have now to be considered such evidence is rare or altogether absent. The Lewisian gneiss of Scotland is traversed by alarge number of basic dykes. Both gneiss and dykes are crossed by shear-zones in which the rocks have been deformed and in which the structure and, to some extent, the mineralogical com- position of the original rocks have been changed. The basic dykes have become hornblende schists and the gneiss a hornblende granulite. Both rocks are now in the condition of holocrystalline schists, and although traces of mechanical fracture may sometimes be seen in the transitional forms, they are as a rule conspicuous by their absence, and are not found in the finished product. The essential difference between fault-breccias and mylonites, on the one hand, and the holocrystalline schists of the shear-zones on the other, is that evidence of mechanical fracture, both of the rocks and of their mineral constituents, is abundant in the former and rare or absent in the latter. This difference is pro- bably due to the fact that the deformation in the case of the shear-zones took place under a greater load and at a higher temperature. The breadth of many of the typical shear-zones is only a few yards, but wider belts of country composed of similar rocks—hornblende schists and granulitic gaeisses—occur, so that the consideration of these shear-zones helps to bridge over the gap between the two classes of effects—the local and the regional. Regional effects are well illustrated by the phenomena of slaty cleavage, which is due to the mechanical deformation of extensive tracts of country. Sharpe and Darwin associated the foliation of crystalline schists with slaty cleavage, an association which appears to be justifiable, although the case as stated by them requires some modification. Much remains to be done before the problem of the origin of the crystalline schists is solyed, but a few points of considerable import- ance have been definitely established. Taking the Highlands of Scotland as an example, the foliated crystalline rocks of that region are, as a rule, easily separable into two distinct classes—those of igneous and those of sedimentary origin. In dealing with foliated igneous rocks there is, in many cases, a doubt as to whether the foliation may not date from the time of intrusion and be of the nature of original fluxion; but when a granitic mass, its apophyses and the metamorphosed sediments on its margin have a common foliation, and the apophyses are foliated transversely to their width, and not parallel to their margins, we are compelled to assume that the foliation has been produced by earth movements operating after intrusion, consolidation, and contact-metamorphism. This is the case, for example, with the Carn Chivinneag mass in Eastern Ross, which has recently been investigated by Mr, Clough. Crystalline schists of sedimentary origin also form large tracts in the Highlands. They probably belong to more than one formation, and certainly include repre- sentatives of arenaceous, argillaceous, and calcareous types. To what extent the present condition of these crystalline schists is to be attributed to earth movements is more or less an open question. That they have been powerfully affected by such movements is often clearly proved by their disposition, by the presence of recog- nisable folds, and by the flattening or elongation of the clastic grains and pebbles in the coarser-grained sediments. If foliation be taken to include both parallel banding and the disposition of minerals with their longer axes in one definite direction, it is probable that in general the former is evidence of original stratifi- cation, although the thickness of a band, as we now see it, may be different from its original thickness, and the latter is the result of earth movement. It appears, therefore, that the secondary foliation of igneous rocks and a part ! There is also a third class of mixed rocks, due to the impregnation of sedi mentary with igneous material, but this class is relatively unimportant. TRANSACTIONS OF SECTION C. 553 of the foliation of the crystalline schists of sedimentary origin must be attributed to earth movements and associated with the phenomena of slaty cleavage. The Rey. Osmonp FisHEeR made the following communication :— L used to think that the corrugations of the earth’s crust were due to compres- sion through the shrinking of the interior. To judge of the sufficiency of this cause the first thing to be done is to seek a measure of the compression, and then to compare the result of the effects of cooling with the actual amount of compression. The most satisfactory measure appears to be the thickness of the layer which the corrugations would form if levelled down. The question then becomes a question of how much. In 1863 Lord Kelvin (then Sir W. Thomson) formulated a law of secular cooling upon the hypothesis that the interior is solid. Adopting a probable value for the contraction of rocks in cooling, I calculated the thickness of the layer which would be produced by the corrugations resulting, and found it far short of that which the existing inequalities would form if levelled down. Mr. Mellard Reade and Dr. Davison subsequently discovered the existence of a level of no strain within the crust, and this greatly reduces the possible amount of corrugations. The conclusion at which I arrived was that, on the hypothesis of a solid globe, secular contraction through cooling would not account for the corrugations. : Numerous phenomena suggest to the vulcanologist that the substratum is a liquid magma holding water-gas in solution. The free yielding of the substratum is also testified by the phenomena of isostacy. I have therefore endeavoured to estimate the amount of corrugations which would be produced by a cooling globe also on this hypothesis. But although they would be slightly greater than in the case of a solid globe, they still fall far short of those actually existing. I there- fore argue that the corrugations of the crust are not due to the shrinking of the peer away from the cooled crust, whether we regard the interior as solid or iquid. My own view of this vexed question, which is based on the considerations given below, is that the substratum is affected by convection currents, and that these ascend beneath the oceans, and flowing horizontally towards and beneath the continents, and descending beneath mountain chains, are the cause of the compression of the crust, and other disturbances, of which we are in search. It is, in the first. place, necessary to combat the dictum of leading physicists that the interior of the earth is solid. It has been asserted that unless the earth is extremely rigid bodily tides would be produced, and that there would be no rise and fall of the water relatively to the land. Ifthe earth was a smooth spheroid, covered with a uniformly deep ocean, this would, no doubt, be true; but as matters stand the tides of short period are affected by local irregularities, known as the establishment of the port. If the substratum of the crust is liquid, isostacy requires large protuberances of its underside, which would cause irregularities in the tides in the magma analogous to those in the ocean; and unless these agree in time, in height, and in place with the water tides, the latter will not be obscured by them, and may even be augmented. | Of tides of long period the fortnightly is the most important, but I think I have shown in the Appendix to my ‘ Physics of the Earth’s Crust’ that it had not been proved by fifteen years of observation that any such tide existed,! which would be an argument in favour of the liquidity of the interior. The peculiarities of the transmission of earthquake waves to great distances through the body of the earth have been appealed to as proving to all ‘except some geologists’ that the earth is solid.» The disturbance first arrives as a series of minute tremors. These have been considered to be waves of compression. They are soon followed by somewhat larger disturbances, which have been con- sidered to be waves of distortion. Since waves of distortion could not be propagated in a liquid, it is maintained that the earth is hereby proved to be solid. In reply to this argument, I have shown that if a liquid magma holds gas 1 Page 34, Nae 2 Darwin's Tides, p. 236, ~ 554 REPORT—1904. in solution two types of waves will be propagated through it, with different velocities. Tremors will first arrive, due to the compressibility of the magma, and subsequently waves, caused by the extrusion of gaseous vesicles, due to the changes of pressure. If my argument is valid, that for solidity loses its force." I will now give my reasons for thinking that the substratum, if a liquid, is not a still liquid, but is affected by convection currents. Availing myself of Sir Arthur Riicker’s observed values of the melting- temperature and specific heat of Rowley rag, I have calculated that if the substratum of the crust be a still liquid, the thickness of the crust comes out 22 miles, and the corresponding time since it began to solidify about eight million years. This is a much shorter time than geologists would admit. This result proves that the substratum is not a still liquid, and must, therefore, be affected by convection currents, bringing up heat from below and delaying the thickening of the crust. The existence of convection currents being thus, as I submit, established, I will add my reason for believing that they ascend beneath the oceans, By a somewhat complicated calculation, which, although assailed by Mr. Blake,’ has been ably defended by Mr. Brill,® I have, I think, proved that the substratum beneath the ocean is less dense than beneath the land. This shows that the upward currents are beneath the ocean. I have at the same time proved that the sub-oceanic crust does not reach quite so deep down as the continental crust, and thet its upper layer is thin and very dense; from which I infer that it consists of basic lava flows, the oxydation of which would afford the red clay which covers the bottom of the deeper oceans, These convection currents, ascending beneath the ocean, and then flowing horizontally towards and beneath the continents till they descend, are, in my opinion, the cause of the compression of the continental crust. At the request of the President, Professor T, McKunny Hueuss explained the position and arrangement of the specimens exhibited in the museum in illustration of the subject under discussion, They were, as far as possible, arranged to show the ‘nature’ of earth move- ment and the relation between superinduced structures, which might suggest their ‘origin.’ Great continental folds, and local readjustments in connection with them, may be exemplified even in small specimens. From these we should infer, as we should also from observations over large areas, that faults and folds were generally due to movements in relief of lateral pressure, while faults due to the dropping of the marginal portion of uplifted and exposed areas are com- paratively rare. What the nature of the movement will be in various regions would largely depend upon the character of the rocks affected. Heim had estimated the probable breadth of the Alps if the strata were pulled out flat. Similar calculations had been made among the folded mountain ranges of America ; but, as our specimens show, all rocks were not susceptible of the same kind of compression. One rock had gained in vertical thickness at the expense of horizontal extension by molecular rearrangement of the particles, which had, or could assume, a flattened form at right angles to the direction of the pressure. Another rock which would not yield to this kind of readjustment must fold; but faults and crumplings occur along belts, and are in easement or relief of strain along lines of less resistance during movements of uplift and depression. In the production of folding without fracture time is an element, and tempera- ture must be taken into account. When the rocks do break, earthquakes record the rent, and volcanic phenomena follow the relief of pressure on the superheated rocks. If we could explain the great epeirogenic movements by a shrinking of the interior and a tangential pinching of the hardened outside crust, we should establish a vera causa which would involve the crumplings along limited belts, where vertical expansion was produced in compensation for horizontal extension. Nature is full of automatic compensations and conflicting forces, and in this. dis- 1 Proceedings of Cambridge Phil, Soc., vol. xii., 1904. 2 Phil, Mag., 1894. 5 Phil, Mag., 1895, TRANSACTIONS OF SECTION C. eves cussion we must not forget the transference of large portions of the earth’s crust from one region to another. Fifteen thousand feet of rocky material taken off a continent and thrown down on its margin must produce an appreciable disturb- ance, as we see on a small scale when a solid stratum is remoyed from above a shale or a mountain side, in a tunnel or in a quarry. The removal of blankets of sediment from one area and the heaping on of corresponding layers elsewhere must affect the transmission of heat and its many consequences. We must remember the different volume of rocks in a molten and solid state, and the tremendous power of crystallisation and chemical reacticns. We must be careful not to think that we can explain the working of a clock when we have given a numerical estimate of the strength of the spring, without taking account of the controlling influence of the pendulum, Professor Sotias remarked that Mr. Horne in his closing words had suggested the question which was most open to discussion, 7.e., How far could the hypothesis of a cooling globe be shown to explain the phenomena of disturbance in the super- ficial structure of the earth’s crust? It was difficult to enter upon this inquiry without making some assumption as to the internal state and constitution of our planet. Professor Arrhenius regarded the interior as consisting of gas at a temperature above its critical point, but under a pressure which rendered it highly incompressible. Such a conception would afford the geologist a general contrac- tion sufficient to meet all his needs. The Rev. O, Fisher, as the result of his investigations, had been led to regard the interior as fluid, but thought that even so the contraction resulting from cooling would be inadequate to account for the inequalities of the surface. While Mr. Davison, reasoning from Lord Kelvin’s hypothesis of a solid earth, was led to an opposite result. But however authori- ties might differ as to the amount, none would deny that some contraction would follow trom the secular cooling of the globe, and it was of interest to inquire by what kind of machinery this would act to produce mountain folds, with their associated thrust-planes and volcanic and seismic disturbances. It must be care- fully borne in mind that folding is confined to comparatively narrow belts of the earth’s surface, extensive masses of sediment remaining comparatively undisturbed in approximately horizontal platforms ; that these belts occur near the margin, or the once existent margin, of the ocean, and that they are comparatively super- ficial, the causes which gave rise to them being deeper seated. If we consider the relative level of the continents and ocean-floor, we find the latter lies at an average depth of some two miles below the former, yet the continents appeared to be self- supporting. Wherever great folded ranges are in existence, however, we have evidence of a previous slow subsidence of the sea-floor bordering the land, a sub- sidence which, with lapse of time, had in many cases amounted to five or six miles. When the present difference in level between continent and ocean-floor had undergone so great an increase as this, it was doubtful whether the continent would continue to sustain itself, and if it gave way it would slide towards the ecean. Consideration of the distribution of pressure and isogeotherms below the crust suggested the possible existence of a zone of solid material near its critical fusion point, the slope of which might be seawards, and might lead to the formation of gently inclined glide planes. The movement of the continental mass would then give rise to compression, folding, and overthrusting of the marginal sediments, as well as accompanying seismic and volcanic action. The limited distribution of folded belts could be thus accounted for; but it might still be urged that the contraction due to cooling was inadequate to explain the subsidence on which this theory was based. There was, however, another cause to which attention might be directed, viz., a slow deformation accompanying a loss of rotational velocity. Mr. Jeans had shown that the original form of the earth; subsequent to the origin of the moon, was probably pear-shaped, and this figure, of which some vestiges still remain, would determine the primitive distribution of land and sea. As rotational velocity diminished, the form would approximate more and more to that of an oblate spheroid, and the oblate spheroid would become more spherical; in the course of these changes the Pacific belt of continents would be produced, and the 556 REPOR1—1904. mountain ranges of the ancient Thetis. Contraction and this deformation acting together might be found to supply the explanation required. A decisive solution, however, could hardly be looked for at present ; many physical data, especially the value of the coefficient of expansion for solid bodies near their critical fusion point, were not sufficiently known, and great authorities were ranged on opposite sides ; at the same time, investigators like Joly and Barus were making important addi- tions to our knowledge, and further advances might he hopefully looked for in the near future. Professor J. F. Brake considered it more important to determine, in the first instance, the proximate causes of earth movements rather than the ultimate causes, which must be more or less speculative. Thus the thrust-planes of the N.-W. Highlands had inclinations pretty uniformly bringing upwards the overthrust materials, only the small minor thrusts bending down towards the end, as though they were locally stopped in their motion. This motion was from the east, where there existed a broad area of crystalline rock. These indications suggested the former existence of a mountainous region in this direction, which had afterwards sunk by its own weight and forced out the strata to the west, carrying with it portions of its own base, the yielding of which was the immediate cause of the motion. This, however, involved no important folding, and thus supported rather the ideas of Professor Rothpletz than those of Professor Heim. Folding, in fact, had, in the speaker’s opinion, been much exaggerated; there was plenty of it, but too wide effects had been attributed to it. ‘The speaker had never seen ‘isoclinal’ strata in the sense often implied, and never hoped to, for such folding was physically impossible, involving as it did the absolute destruction of the central layers. At most the structure might be called p/estoclinal; and in this case the centre of the fold should always be somewhere recognisable, as it occurred throughout. If no indication could be found it argued that a fold was absent. There were also local causes of folding, of which an instance was quoted in the valley crossed by the excavation for dams made in carrying out the Derwent Valley water-scheme. Here the two sides of the valley showed uniform horizontal strata in the bedded Pendleside series ; but where the stream was crossed a sharp uplift on both sides was seen in the section, while the underlying strata were said to be still undis- turbed ; thus indicating that the cause of the uplift originated at the stream, and was probably the relief from local pressure dug to the excavation of the valley, and might be called, therefore, a kind of earth-creep. Professor A. Rorupnetz said: I have had much pleasure in listening to the clear exposition that Mr. Horne has given us of the overthrusts and earth-crush movements in the Scottish Highlands, and in seeing the great importance given to these subjects by this meeting. It is more than twenty-five years ago that I had the first opportunity of studying an overthrust. At that time nobody cared for such things, and the text-books of geology hardly recognised the word at all. The next overthrust I found in the Alps twenty years ago, but I had to defend it against almost everyone. So you may understand my delight when I came to the meeting of this Association at Nottingham, and had the good fortune to find there those geologists who had worked out so carefully the overthrusts of the Highlands, and to accompany them into that district. But now opinions have changed so entirely that nobody in this room will be found to deny the existence of overthrusts. Although I have now worked twenty-five years at the subject I am still very doubtful about overthrusts, because we do not yet know many of their essential features. How, for instance, do these wide and long overthrust-planes come to an end laterally? That we cannot see in the Highlands; but in the Alps I have found two great overthrust-planes which strike from §. toN. at a place where the strike of the folds is E. to W. So the shortening in one direction took place by folding, while the shortening in a direction at right angles to that was by over- thrust. Following those overthrust-planes to the north and south, we see that before reaching the boundaries of the Alps they simultaneously and suddenly turn east- ward and lose their horizontal character, They become longitudinal and more or TRANSACTIONS OF SECTION C. 5517) less vertical fault-planes, which we may follow to the east end of the Alps. So they enclose an enormous mass of mountains, which have moved from E. to W. along these longitudinal fault-planes like a car on the rails. Now, are the particular features of these Alpine overthrusts of general application? It may beso or not. Nothing but further field-work can clear up this point. Of course the forces which made these overthrusts must have been enormous, and there is naturally a great tendency to attempt to calculate their origin. Field geologists are not so well fitted for doing this, because they have too great a knowledge of detail, and are too much puzzled by what they have not yet fully elaborated. It is easier for those who are mainly occupied in working at theory and who are not disturbed by detail. They can more readily accept the simple assumptions which are wanted for mathematical analysis. We have just seen, however, that in theory, too, there are many difficulties and much difference of opinion; and so I do not think that questions of the nature and origin of overthrusts will be solved so quickly as Professor Sollas hopes and anticipates. Professor Boyp Dawxrns called attention to the foldings and faults caused by the relaxation of pressure at the bottom of valleys carved out of the elastic shales and thin sandstones of the Yoredale and Millstone Grit rocks, which he had observed in the upper valleys of the Derwent and of the Don during the construc- tion of reservoirs. ‘lhe folded and faulted strata extend to a depth of from 40 to 120 feet from the surface, and rest on undisturbed shales and sandstones. They are due to the lateral pressure of the sides acting on the valley, from which the counterpoise of rock has been denuded away, and are analogous to the ‘ creeps’ in coal-workings. We must, therefore, add the relaxation of pressure to the causes of folding and faulting recognised in geological theory. Professor Joun Minne remarked that the number of worlds which had been invented by geologists, physicists, and others exceeded the number which they had heard about in their youth. New worlds had even been invented whilst he had been in the room, and to them he ventured to add another—a world that would meet the requirements of the seismologist. The world which they required was one which would convey earthquake waves with a velocity which was nearly uniform along chords corresponding to arcs greater than 30°. In other words, a fairly homogeneous nucleus was required, and this nucleus should have a ‘rigidity about twice that of steel. Such a world would not be far removed from the one suggested by Wiechert, which was in agreement with the require- ments of astronomy and geodesy. In other respects it resembled the world of Arrhenius, Professor Percy F, Kenpatt said that he had no intention of discussing the general question of the causes of earth movements, but merely desired to make one observation upon the remarks of Professor Sollas, who had pointed out that the continental margins were the seat of the most important mountain-making movements. Upon the hypothesis that there was a critical zone at which temperature would impart a viscosity to rocks, he thought the sub-oceanic margins might, for another reason than that suggested by Professor Sollas, be the regions where the yielding of the crust would take place. The accumulation of a great thickness of sediment, such as took place in proxi- mity to coast-lines in a sinking area, would have the effect of producing a rise of the ge-isotherms and of the critical zone. If, then, a movement of accommodation were initiated, there would he above the critical zone a region of relative weak- ness, where the new-formed and imperfectly consolidated sediments constituted perhaps two or three miles of the superincumbent crust, while the continental mass would be relatively stiffer. The yielding and crumpling would, theretore, be localised in this belt. 558 REPORT—1904, 2, Hvidence in the Secondary Rocks of Persistent Movement in the Charnian Range. By Professor Percy F, KenpAtt. 3. Rwver-capture in the Don System. By Rev. W. Lower Carter, IA. The river Don has a remarkable semicircular course. Rising in the Middle Grits west of Dunford Bridge at 1,500 feet above O.D., it flows eastwards to Peni- stone (700’), where it makes a bend to the south-east, quickly deepens its valley to 500’, and at Wortley breaks through the great watershed (1,000’) of the Greno- side and Wharncliffe grits. It then receives the Little Don, the Ewden, and the Loxley, on its right bank, and falls into the valley of the Sheaf at Sheffield (150’). The Don then makes a rectangular bend to the north-east, following the old valley of the Sheaf to Conisborough, receiving the Rother on its right bank at Rother- ham (87’) and the Dearne on its left bank at Denaby (45’). It then traverses the Maguesian Limestone escarpment in a fine gorge and continues past Doncaster in a north-easterly direction to Thorne, where it bends northwards towards the Aire, which it formerly entered at Snaith. It has, however, been artificially diverted by the Dutch river to the Ouse at Goole. The history of the present river course is presumed to have commenced when the Pennine anticlinal rose from the Cretaceous sea, and the original consequent streams commenced to run down the dip-slope of the Chalk. Slack Beck (Broad- stone Dyke), which is diverted south-east at Ingberchworth by a tributary of the Don, is considered to be the head-stream of the brook that runsby Cawthorne, only a narrow dip in the watershed dividing them. The Don at Penistone (700’) faces a watershed of 700 feet, which forms a dip between Hoyland Swaine (900’) and Thurgoland (810’). Immediately beyond this watershed are the head- waters of the Dove, flowing eastward in direct continuation of the course of the Don above Penistone. The Dove is thus considered to be the beheaded remnant of the Don. The southerly bend of the Don and the cutting of the Wharncliffe gorge are explained as due to river-capture by a feeder of the Sheaf. This Wharncliffe stream, with a rapid fall to the Sheaf, was able to capture successively the Loxley, the Ewden, and the Little Don, and then the watershed at Wortley was attacked by a branch of this stream, and on the other side by a feeder of the Don, As the watershed was cut through, the Wharncliffe stream, by reason of its steeper fall, captured the Wortley feeder of the Don and then the Don itself. The Dearne.—At a very early date the Bretton stream must have been captured by the Darton feeder of the Cawthorne stream, as it flows straight at the Woolley Edge escarpment (527’), and therefore must have been captured before the land was reduced to this level. The Dearne flows eastwards, by Barnsley to Cudworth Common, where it males a rectangular bend southwards, and cutting through the Upper Chevet Rock (225’) at Darfield, enters the old valley of the Dove (100). This gorge at Darfield proves the extension of the 225-foot contour eastwards, towards Hickleton, forming the watershed between the Dearne and the Dove, and there is an old river valley at Frickley (200’) between Clayton and Hickleton, which was probably the original course of the Dearne, which flowed through Hampole gorge into the central plain. The Darfield gorge is a case of river- capture by a feeder of the Dove. The Dove itself had probably been captured by the Sheat at a period hefore the present level of the Magnesian Limestone esearp- ment was reached bv denudation. The Rother.—Vhe original cousequents of the Rother are Shire Brook, the Moss, and the Stayeley stream. The Shire and Moss probably coalesced and formed the head-waters of the Ryton. The two gorges (530’) uniting at Kiveton are plainly traceable, and have subsequently been used, in all probability, as a channel of glacial overflow, The Moss must have captured the Staveley stream before it was itself captured by the Rother. The whole inner Don system is thus explainable by a series of riyer-captures, TRANSACTIONS OF SECTION C. o09 due to the deep cutting of its valley by the Sheaf, and its resulting predominant power in capturing consequent streams north and south. The northward bend of the Don, after its entrance into the central plain, is due to river-capture by a feeder of the Aire. The course of the old Don river from Thorne, along the north side of Hatfield Chase to Adlingfleet, on the Trent, is clearly traceable, and may have been one of the previous channels of the whole river. 4, On the Elephant Trench at Dewlish, Dorset: Was it a Pitfall? By Rev. O. Fisner, JA. The author refers to papers upon the trench at Dewlish, by the late Mr. Mansel- Pleydell,! Mr. Clement Reid,’ and himeelf.* After describing the course of the excavations made by Mr. Pleydell in 1889, he points out the apparent impossi- bility of accounting for the formation of such a trench by natural agency, and for its containing the remains of so many elephants. He then refers to the present practice of taking elephants in pitfalls by the natives of Africa, and suggests that the trench at Dewlish was artificially dug for a similar purpose. The species of eiephant found here being Z. meridionalis, the author refers to flints, considered to have been worked, being procured from the ‘forest bed’ of Cromer, where they are associated with this early species of elephant, and alludes briefly to some of the geological questions involved. 5. Wotes on the Glaciation of Holyhead Mountain. By Epvwarp GREENLY. The glaciation of Holyhead Mountain is of considerable interest on account of its position far out in the Irish Sea Basin. Its northern and eastern slopes are strongly rubbed and rounded, and striated in a general N.E.-S.W. direction, with local deflections. Striz cross the very summit, 721 ft. above the sea, running 8. 40° W. This direction agrees with that of the general glaciation of Anglesey. A strong feature traverses the mountain from N. to 8. facing W., and forms also the line of great sea cliffs near the North Stack. The edge of the crag is polished, and, in spite of being sheltered by a steep rocky brow rising some 50 or 100 ft. behind it to the east, is traversed by striz from N.E. to S.W. Examples are also given of undercut furrows, and of glaciation of overhanging surfaces. The mountain is very bare of drift, but a little till occurs in hollows. At the summit are abundant fragments of the green mica schists of the neighbourhood of the town, which do not occur 7m sttw at a higher level than 200 or 220 ft. These have, therefore, been raised some 500 ft. above their source. The phenomena, when all are considered, appear to the author to be ascrib- able, with probability, to land ice. Finally, there are some ill-defined mounds, composed of local débris, which appear to be moraines, as if small local glaciers had gathered here for some time, in spite of the moderate elevation. 8 Report on the Brratic Blocks of the British sles —See Reports, p. 237 ' broc. Lorset Nut. Hist. and Antiy. Field Club, 1889, vil. ; 1893, xiv. * Geol. Survey : Mem. on the Country round Dorchester, 1899. * Q.S.G@US., 1888, xliv. 818, 560 REPORT—1904. TUESDAY, AUGUST 23. The following Papers and Reports were read :— 1. On the Origin of the Great Iron-ore Deposits of Lapland. By Dr. Heice BackstR6m. The great ore sheet of Kirunavara-Luossavara occurs between old lava streams and volcanic conglomerates, in other words between rocks formed by volcanic action at the surface. It seems to mark an interval between two separate eruptions or eruptive periods, as the rocks on both sides are different, although showing a distinct consanguinity. The ore bed is older than the overlying quartz porphyry, while at the same time it is younger than the underlying syenite porphyries. The underlying porphyries show characteristic evidence of a hydro- chemical or pneumatolytic action, which has left no similar traces on the overlying porphyries, and must therefore have occurred in the interval during which the ore was formed. From these facts we may presume that the magnetite-apatite sheet was formed by the voleanic activity which produced the overlying as well as the underlying rocks, and that the hydrochemical or pneumatolytic transformation of the under- lying porphyries was effected by the same agents which brought the iron and phosphorus up to the surface of the earth. The Ekstrémsberg ore-field, situated about twenty miles west of Kirunavara, ranks as the third of the great Lapland iron mountains; the probable quantity of ore has been estimated by the author at one hundred million tons. The ore is partly magnetite, partly hematite, with 63 per cent. Fe, 1°25 per cent. P, on the average. The surrounding rock is a quartz porphyry, but with potash instead of soda as the dominant alkali, the same variety occurring on both sides of the ore sheet. In the ore-field of Mertainen, situated eighteen miles south-east of Kirunavara, the ore is magnetite without apatite, but the quantities of rich ore present are compara- tively small, the principal part of the ore-field being occupied by ore breccias or mixtures of porphyritic and ore material. The original rock of the district is a syenite porphyry. In the ore-field this is penetrated by veins of magnetite with biotite, hornblende, and titanite. These minerals, and especially the magnetite, also occur, filling amygdules, This penetration of the original rock by magnetite in those places where it was most favourable for penetration, resulted in the formation of the ore breccias, in which the ore, so to say, has eaten away most of the porphyritic material. An intense transformation of the porphyry has gone on hand-in-hand with this infiltration of the ore material. Of the original pheno- erysts of the dark minerals not even pseudomorphs are found; the biotite and hornblende present are of secondary formation. The plagioclase is very often partly transformed into biotite or titanite, but still more often into scapolite, which latter transformation is of very great interest when the transformation of plagio- clase into scapolite along the apatite veins occurring in gabbros is remembered. That the iron ore of Mertainen, occurring to a great extent as veins and ore breccias and accompanied by such transformations of the surrounding rock, should be of pneumatolytic origin, seems very probable. But the author thinks this theory must be adopted also for the great masses of Kirunavara-Luossavara and Ekstrémsberg, closely connected as they are with voleanic rocks. Hence these iron-ore deposits have probably got their material from below through volcanic emanations belonging to the last phase of the volcanic activity (or to an interval in the activity, as in Kirunavara), emanations of iron, phosphorus, or titanium compounds, essentially chlorides and fluorides, in the form of gases or superheated solutions, which on reaching the surface regions were decomposed by the water and the silicates with which they came in contact. This theory may appear rash, especially when applied to such enormous masses as the Kirunavara-Luossavara magnetite-apatite sheet, but it seems to the author to be only an extension of the generally accepted theory of the origin of the con- tact deposits. In both cases the material has come with the eruptive rock from TRANSACTIONS OF SECTION C. 561 below, although in one case the ore has been deposited along the margins of an intrusive rock, and in the other case at the surface or in the regions near the surface. 2. Exhibition of Specimens of Tertiary Plutonic Rocks (including Gneisses) Jrom the Isle of Rum. By Atrrep Harker, I.A., F.B.S. (By permission of the Director of the Geological Survey.) Of the plutonic rocks of Tertiary age, which make up about one half of Rum, the ultrabasic group is the most important. It includes various peridotites, some essentially of olivine, but others containing pyroxenes, and especially anorthite. A noteworthy amount of lime and alumina, giving rise to anorthite, is indeed a special characteristic of the group. Equally striking is a tendency to separation of the more peridotic and the more felspathic portions of the magma, usually with a stratiform disposition. With bands of true peridotite alternate others of allivalite, a rock consisting of anorthite (predominant) and olivine, and even containing seams of pure anorthite rock. Another peculiar type, styled harrisite, is composed essentially of olivine (predominant) and anorthite, the olivine occurring here as large lustrous black crystals, with good cleavage. Later than all these rocks, and intruded beneath them, comes the ewcrite group, which shows less variety. The rocks are usually somewhat rich in olivine; much of the pyroxene is hypersthene, and the felspar is near anorthite. Still later comes the granite group, mostly hornblendic and often with granophyric structures. The acid magma has entered into peculiarly intimate relations with the eucrite, not only metamorphosing and impregnating that rock, but enclosing and partially incorporating portions of it, large and small. The enclosed portions, in a half-digested state, have been streaked out by movement, and there has arisen a group of well-banded gneisses, closely resembling the Lewisian of the North- western Highlands. These Tertiary gneisses are all of the nature of hybrid and composite rocks, of which the contributing elements are the eucrite and the granite, and their genesis can be traced step by step in the field. 3. The Lava-Domes of the Eifel. By Eywarp GREENLY. Associated with those cones and craters of the Hifel which are so remarkably preserved, and have suffered so little from denudation, are many bosses and domes of massive igneous rock, particularly of phonolite. If these are the denuded necks or stumps of volcanoes, they must be far older than the cones and craters. It is suggested, however, that they may be really contemporaneous, and have originated in the same way as the recent lava-pyramid of Mt. Pelée. This suggestion is supported by considerations connected with the distribution of the Trass; and by comparison with some other domical and pyramidal masses, 4. Report on Geological Photographs.—See Reports, p. 242. 5. Coneretions as the Result of Crystallisation. By Professor H. A. Mimrs, £25. In the gold districts of the Urals decomposed crystals of iron pyrites are not uncommon, which when sawn in half are found to contain a nucleus of gold; fresh crystals from the same localities are auriferous, but have the gold uniformly distri- buted. Similar nuclei are found in decomposed aikinite (a sulpho-bismuthite of lead and copper) at Beresoysk, but here the nucleus of gold is, like the crystal of aikinite, rod-shaped. In both cases the metal has become concentrated during the “Soar rm of the mineral in which it was contained, . Qa0 562 REPORT—1904. It is well known that crystallisation may result in a concentration of material, as when the small crystals in a solution become redissolved and reappear as a large crystal, That the concentrating agency in the case of the decomposed pyrites may have been crystallisation is suggested by the fact that the nucleus has crystal facets. Other examples of the attractive force exerted during the growth of crystals are afforded by such things as gypsum growing in clay, where, as was pointed out by Bunsen, the force does work and thrusts up the clay, often in considerable masses. Again, Klocke found that an alum crystal during growth may raise itself in the solution. If this attractive force exists it should also manifest itself in a concentration of the material in the neighbourhood of a growing crystal, and this the author has found to be the case. By means of total internal reflection he has determined the index of refraction, and hence the composition, of the solution in contact with growing crystals of alum and other substances, aud has always found the solution to be supersaturated. The author suggests that in cases where no other explanation is forthcoming a sufficient cause for concretionary growth may be found in the attractive action of growing crystals. Marcasite, hematite, barytes, and many other concretions, are really crystalline in structure; and Liversidge has shown that gold nuggets are always so. 6. Basic Patches in the Granite of Mount Sorrel, Leicestershire. By R. H. Rasrart, B.A. Dark-coloured patches are very abundant, and may be divided into three types :— (1) Small black or grey angular patches, without porphyritie felspars. (2) Larger ovoid patches of a brown colour, with pink porphyritic felspars, (3) Black patches showing banding and Jit-par-lit injection by the granite. Type (1) consists of felspars and hornblende with a little quartz. Small erystals of plagioclase and hornblende are enclosed in poecilitic fashion by large plates of orthoclase. The second type is very similar microscopically, but quartz is more abundant, The large felspars are often much corroded. Both types are almost free from biotite, although in the normal granite it is the dominant melanocratic mineral. There is abundant sphene, of a peculiar habit, often moulded on the felspars, with an approach to ophitic structure. These patches show a great resemblance to many metamorphosed basic igneous rocks, and attention is called to the resemblance between them and the early stages of the alteration of the Scourie Dyke, described by Mr. Teall.’ It is con- cluded that they are fragments of basic rocks caught up by the granite magma during intrusion. A specimen of the banded type consists of brown biotite and magnetite, enclosed poecilitically by plates of perthite, microcline, or orthoclase, It is very like many metamorphosed slates, and is probably a fragment of a sedimentary rock, This type is rare. 7. On the Different Modifications of Zircon. By L. J. Spencer, M.A. Some very irregularly developed crystals of zircon from the gem-washings of the Balangoda district in Ceylon were found to have characters differing widely from those of zircons of more common occurrence. Although of low specific gravity (4:0), they are not increased in density when strongly ignited, as are many 1 0.I.GS., 1885, p. 133. TRANSACTIONS OF SECTION C. 563 zircons of specific gravity below 4:7. They further differ from ordinary zircon in their very feeble, or absence of, birefringence. The crystals are dark brown in colour and almost opaque, but after ignition they are bright green and quite transparent. While some of the crystals consist wholly of zircon of this type, others contain an intergrowth of a second kind, which may be present in greater or less amount. The latter has a higher specific gravity, and increases in density when ignited ; it is optically biaxial with very strong birefringence. A section cut perpendicular to the principal axis of such a compound crystal shows, when moved across the micro- scope-stage in convergent polarised light, a gradual transition from a biaxial to a uniaxial figure, the coloured rings at the same time moving outwards and becominy further apart owing to the diminution in the strength of the double refraction, which is positive throughout ; finally, when the rings have all moved out of the field of view, the black cross also disappears and the corresponding portion of the section is optically isotropic. The mean refractive index has about the same value in all portions of the section. Zircon of the first type has been previously described by Professor A. H. Church (1875), and by Dr. S. Stevanovié (1903), and from the researches of these and other authors it would seem that there are, at least, three modifications of zircon, viz. :— a. Those of specific gravity 4:0, which do not increase in density when ignited, 8. Those of specific gravity 4°7, also not increased in density when ignited, y- An unstable form of specific gravity about 4°38, which when ignited is increased in density to 4:7. That these different kinds are often intergrown in the same crystal is shown by the frequent occurrence of zonal structures in zircon, and further by the behaviour of the crystals when heated. A crystal consisting of an intergrowth of a-zircon and y-zircon will be increased in density on ignition, but not to the higher limit of 4-7; on the other hand, an intergrowth of @-zircon and y-zircon will reach the higher limit when ignited. In crystalline form and chemical composition (as far as could be determined by qualitative tests), a-zircon and @-zircon are identical, and these appear to be also the same for y-zircon. 8. A Preliminary Description of Three New Minerals and some Curious Crystals of Blende from the Lengenbach Quarry, Binnenthal. By R. H. Sotty, 1.4. The author dealt with three new minerals, whose composition has not yet been determined, for two of which he proposed the names Lengenbachite and Marrite. He also described crystals of blende having a brilliant grey metallic coating on their surfaces and resembling galena or tetrahedrite. 9. On the Granite from Gready, near Luaxullian, in Cornwall, and its Inclusions. By Professor Kart Busz. In 1880 J. A. Phillips published in the ‘ Quarterly Journal of the Geological Society’ a description of the granite from Gready, in the parish of Luxullian, in Cornwall, and the concretionary patches contained in it. This granite he describes as sometimes containing dark-coloured patches of irregular shape, firmly embedded in the rock, and exhibiting distinct and sharply defined outlines. On examination he found them to be composed of the same minerals as the enclosing granite, and consequently considered them to be abnormal arrangements of the minerals constituting the granite itself, and essentially consisting of a fine-grained variety of the granite in which they occur. A few years ago I happened to visit the same locality. The granite is still 002 564 REPORT—1904. extensively worked in large quarries for building material, and on that account I was able to collect a number of suitable specimens for investigation. The granite itself is of much interest on account of the presence of several constituents which rarely occur in this kind of rock. It exhibits on the whole a uniform medium-grained structure, but is in some parts porphyritically de- veloped, and contains large well-defined crystals of white orthoclase; it is also traversed by pegmatitic veins, which contain much tourmaline and apatite, while mica disappears. When examined under the microscope, thin sections of this granite are observed to be composed of the following constituents: Quartz, orthoclase, oligo- clase, albite, white and brown mica, tourmaline, apatite, zircon, magnetite, fluorite, andalusite, cordierite, and chlorite—the last-named as a decomposition product. Further constituents, occurring only in cavities in the pegmatitic veins, are lepidolite and gilbertite. Quartz occurs in the usual form of grains or granular aggregates, and contains numerous liquid inclusions, some of them show- ing a crystal of salt. The orthoclase is of a pure white colour; its phenocrysts are of considerable size, being sometimes about 4 inches long and 2} inches wide. They are Carlsbad twins, and occasioually two such crystals form penetration twins of cruciform type, similar to the pseudomorphs of cassiterite after orthoclase, which are well known from Cornwall, the twinning plane being probably a face of the pyramid P (i11). Under the microscope the ortioclase is seen to be more or less decomposed, passing into a kaolin-like substance. It contains a great number of inclusions: numerous flakes of black mica can be observed macruscopically, which generally accumulate in the centre of the crystals or are arranged in layers parallel to their faces. White mica also is very abundant, and occurs in micropoikilitie inter- growth with the orthoclase, forming sponge-like aggregates; there can be no question about this mica being a primary constituent and contemporaneous with the orthoclase in which it is embedded. Microperthitic intergrowth of orthoclase and albite is very common; and it may be mentioned here that albite frequently envelops the orthoclase crystals, which occur well crystallised in cavities of the rock. There is also a fair amount of plagioclase present ; its colour differs somewhat from that of orthoclase, being yellowish white. Under the microscope it exhibits, as a rule, a better state of preservation ; the sections are perfectly transparent, and contain but few inclusions and alteration products. ‘Twin lamellation is well marked, and the optical properties are those of oligoclase. Brown and white mica both occur abundantly. The former contains numerous small crystals of zircon, which are always surrounded by pleochroic halos, whereas the white mica is almost free from inclusions, Parallel intergrowth of the two is very common ; the brown mica is often seen to pass into green chlorite; the white mica is often twinned according to the common law; the composition plane being sometimes the twin plane itself, in which case a twinned flake shows different optical orientation in different parts of the basal plane, and the interference-figures appear disturbed. It has been suggested that in tourmaline-bearing granite the tourmaline may have been produced through the action of vapours containing boric acid on mica, and that in this way it replaces the mica. It seems as though our granite con- firms this view. Tourmaline is a never-failing constituent of the rock throughout, and although it does not occur very abundantly, yet one or more grains of it can be detected in every thin section. The pegmatitic veins of the granite, however, contain a great quantity of tourmaline, and it occurs in large crystals and erystal- line aggregates of radiating structure; the prisms reach a length of 10-12 em. ; biotite and muscovite, on the other hand, are very rare. Of great interest is the parallel intergrowth of biotite and tourmaline; it sometimes appears as if the tourmaline intrudes into the mica, and the pleochroic halos surrounding the inclusions in the latter are sometimes half situated in the mica and half in tourmaline. This intergrowth has not been observed with tourmaline and the white mica. The colour of the tourmaline in thin section is brown, or seldom blue, both colours also appearing on the same crystal; zonal structure is very conspicuous in most crystals, .“ TRANSACTIONS OF SECTION C. 565 Apatite is very abundant, occurring in small crystals or grains in the ordinary granite, or in larger masses intergrown with tourmaline in the pegmatitic veins, and is here of a pale sky-blue colour. In many of the cavities it is well crystallised, and forms shining, perfectly transparent pale-blue crystals of a size up to $ cm. diameter. Very remarkable is the occurrence of andalusite and cordierite as constituents of this granite, both of them being rare. The former occurs in grains or aggregates of grains, which very distinctly exhibit the characteristic pleochroism of andalusite, pink and colourless. Cordierite may easily be taken for quartz, being colourless in thin sections, and exhibiting no distinct cleavage traces. There are, however, several characteristic properties, which also facilitate the identification of this mineral in the present case—firstly, the twinning, resulting through penetration of three individuals in the formation of a pseudo-hexagonal crystal ; secondly, the pleochroic halos of yellow colour, which cannot occur in quartz ; and, thirdly, the decomposition products, consisting of felty aggregates of micaceous or serpentine- like minerals. In some cases the crystals are entirely altered into decomposition products. The concretionary patches contained in the granite consist of a fine-grained rock of bjack colour, and show quite irregular but sharply defined outlines. Numerous small shiny flakes on the fresh surface indicate that mica is a pre- dominant constituent. Under the microscope the rock is seen to consist essentially of quartz, cordierite, and biotite; accessory constituents are a few crystals of magnetite and small crystals or grains of zircon, generally embedded in cordierite and surrounded by a pleochroic halo, which by its deep yellow colour contrasts very strongly with the colourless cordierite. There is no felspar of any kind, and the rock is precisely equivalent to the cordierite-hornfels known from many zones of contact with granite. It is therefore evident that these inclusions cannot be regarded as products of differentiation of the granitic magma, but as fragments of sedimentary rocks altered by the influence of the eruptive mass. 10. Report on the Movements of Underground Waters of North-west Yorkshire-—See Reports, p. 225. WEDNESDAY, AUGUST 24. The following Papers and Reports were read :— 1. Exhibition of a Model of the Cleveland Area, showing Glacier Lakes. By Professor Percy F. Krenpatu. 2. The Glaciation of .the Don and Dearne Valleys. By Rev. W. Lower Carrer, WA. In studying the geological history of the rivers of the Don system, my attention was specially directed to the evidences of glacial action in the area, with the object of ascertaining whether glaciation had anything to do with the interesting diver- sions of the Don, Dearne, and Dove. Certain valleys in the area, also, attracted my attention as possessing abnormal features with respect to the present drainage of the district, and I began to inquire what their relations might be to an altered system of drainage during the Glacial Period. The present paper is an attempt to piece together the scattered glacial evidence, and to ascertain the effect that the advance of a glacier from the north and north-east would have on the drainage ot this district, and how far the present valleys would help to explain the water-flow under such conditions. 566 REPORT—1904, i. The Glacial Deposits of the Don System. These are fragmentary and scattered, and probably but relics of considerable deposits of drift. here are two considerable areas covered with true boulder clay in this district—one at Staincross, Carlton, and Royston, near Barnsley, and the other at Balby, near Doncaster—each filling a small valley which, since the Glacial Period, has been slightly removed from the line of direct drainage, and hence has escaped denudation. The Staincross boulder clay, as described in the ‘Memoir on the Yorkshire Coal Field, consists of two beds of stiff unstratified till, separated by a thin seam of warp and sand, the lower containing only boulders of Carboniferous sand- stone and limestone, chert, and a blue, close-grained trap. The upper bed is more sandy, and on the surface have been found many erratics, including a large shap granite (25 cwt.), Armboth felsite, Threlkeld quartz porphyry, andesitic ash, rhyolite, &c. These beds fill a hollow cut out of the Woolley Edge Rock; the junction is much shattered and smashed, and large blocks of the sandstone are embedded in the clay. The Yorkshire Boulder Committee report that the country to the north and east of this patch is covered with erratics, and similar boulder clays are found at Burton Grange, near Barnsley, and at Ardsley, on the opposite side of the river Dearne. Mr, Walter Hemingway, of Barnsley, has recently traced two tongues of this drift into the valley of the Dearne, and has recorded a section of contorted shale with pockets of erratics from the excavation for the Barnsley gasometer. The Balby boulder clay occupies an area of about five acres in extent. It occupies part of a small valley in the Magnesian Limestone, which previously was filled with Bunter sandstone. In three large pits a magnificent section of 40 feet of stiff till is shown which has yielded many erratics, including a shap granite (2 cwt.), andesites and andesitic breccias, Eskdale granite, St. John’s Vale quartz porphyry, Carboniferous limestone, chert, Millstone grit, &c. The Bunter sand- stone on which this till is seen to rest has been scooped out to form a clean, level floor, without any sand or gravel intervening under the clay. In the excavations for the workhouse a section of this till showed masses of Bunter sandstone torn off and embedded in the till. About halfway along the arc joining Staincross and Balby is another patch of boulder clay at Adwick-on-Dearne, containing Carboniferous sandstone, quartzite, felstone, and encrinital chert. Close to this patch was found a third boulder of shap granite (15 cwt.). Contiguous to this zone are several patches of gravel containing Carboniferous sandstone with quartzite and chert, and a boulder of ganister (of Leeds type) lies on the summit of Wombwell Hill. Beyond and to the south of this zone are several scattered patches of drift. At Barbot Hall, about one mile north of Rotherham, is a little hill covered with clay containing pebbles of quartz, sandstone, Carboniferous limestone, and Oolitic rocks. At Masbrough sand and gravel are found containing pebbles of Carboniferous sandstone and quartz rock, and at Sitwell Vale, one and a quarter mile south of Rotherham, is a clay with pebbles and boulders of Carboniferous sandstone. Near Hooton Roberts are three or four patches of gravel containing Carboniferous sandstone, with quartz, quartzite, and black chert. At the western entrance of the gorge of the Don, at Conisborough, a bed of boulder clay (about 15 feet thick) is shown at the Ashfield Brick Works (225 feet above O.D.), including Lake Country andesites, Carboniferous limestone, a talcose schist with garnets, and other rocks, About the same level, on the opposite side of the gorge, at Cadeby, is a patch of drift with Carboniferous lime- stone blocks. Mr. H. H. Corbett, of Doncaster, has also kindly told me of a section of boulder clay recently exposed in the valley between the railway station and Oonisborough Castle. At Sprotborough and Cusworth, on the north side of the gorge of the Don, are patches of drifted sand and pebbles, and from the fields have been ploughed up small boulders of diorite, basalt, mountain limestone, ganister, and quartz porphyry. At Hexthorpe Flats, near Doncaster, striated Carboniferous limestone with encrinites has been found, and between Hexthorpe TRANSACTIONS OF SECTION C. 567 and Balby the ground is covered with drifted pebbles and fragments of limestone. The Magnesian limestone escarpment south of Conisborough is strewed for some miles with patches of drifted pebbles, of quartz, sandstone, and Trias. This evidence points to glaciation from the north and north-east by two move- ments of ice. ‘Two distinct tills, separated by warp and pockets of sand, are found at Staincross, the lower with Carboniferous boulders and the upper with Lake Country rocks. The drift patches are also of two kinds, one set being of a specially Carboniferous type, and the other rich in Lake Country rocks. It is the latter type that forms the Conisborough and Balby clays. In the Balby pits there is also found a large percentage of Middle Coal Measure material, which forms a perplex- ing mixture to explain. The author suggests that there was a double glaciation of this area early in the Glacial Period, first by Pennine ice, and secondly by the Tees glacier. It seems probable that at the commencement of the Glacial Period, before the Trish Sea was filled with ice, the Pennine Chain was an area of great snowfall, and extensive glaciers were formed in the valleys of Western Yorkshire. These glaciers would probably send down considerable streams of ice into the central plain, laden with Mountain and Yoredale limestones, cherts, ganisters, and Carboniferous sandstones. As the Glacial Period advanced the pressure of the Norwegian ice forced the Tees glacier into the Vale of York, and this in its turn would push back the Pennine ice into the lowlands of Airedale and over the low watershed between the Aire and Don, inside the Magnesian limestone escarp- ment, where it spreads out westwards and southwards as far as Staincross, Rotherham, and Conisborough. This seems to have been the line of farthest extent of this glacier, which, though it interfered for a time with the drainage of the Don, does not appear to have passed through the gorge at Conishorough. The country south of Frickley has undergone extensive denudation since the cutting of the Darfield gorge, and it seems probable that this was effected by this ice, and, on its northward retreat, by the deflected drainage of the Aire and Calder, which, as its course eastwards would still be blocked by the advancing Tees glacier, would find a ready route of flow through Frickley gorge. Thus a large quantity of Middle Coal Measures material must have been carried through the Conis- borough gorge into the plain at Doncaster, and would probably be suitably situated for the second glacier to carry forward to Balby. As it has been suggested that this material might be due to a glacier moving down the valley of the Sheaf from Dore and Totley, this question has been carefully considered. The geological surveyors do not record any drift in the valley of the Sheaf, and a careful search of the 6-inch contour maps has not disclosed any valleys which could have carried off the drainage of the upper Don if it had been obstructed by such a glacier at Sheflield. It is therefore concluded that no glacier capable of advancing to Conisborough was formed in the valley of the Sheaf. The retreat of the first glacier may have been due to a lessening of the snowfall on the Pennine watershed, owing to the shifting of the area of greatest precipitation to the west of the Pennine Chain as the Irish Sea became filled with ice. The evidence, then, points to a second invasion of the Don and Dearne Valleys by ice, the stream this time coming principally from the Tees. This glacier, which had advanced down the central plain, was now, by the retreat of the Pennine ice, enabled to push over the Aire-Don watershed and Magnesian lime- stoneescarpment. Westwards it abutted against the high land of Woolley Edge, and sent down a lobe of ice at Staincross and Monk Bretton into the valley of the Dearne. This second glacier does not, however, seem to have advanced far south of the Barnsley-Adwick-Conisborough curve, and laid down the upper clay of Staincross, the shap granites of Royston and Adwick, and the numerous Lake Country erratics of the district to the north and east of the Dearne. This glacier seems to haye advanced over the Magnesian limestone with a south-westerly movement, gradually closing the gorge of the Don and carrying the material of denuded Bunter and limestone beds over the escarpment to the south of Conis- borough, of which the pebble drifts are the relics. This movement does not appear to have extended much farther southwards, as 568 REPORT—1904. the Kiveton gorge seems to have presented a clear course for the overflow of the lake formed by the damming back of the drainage. The second glacier appears to have retreated north of the Aire before the overflows at the head of Calderdale were in full swing. The Don and Dearne valleys were, therefore, in all probability, clear of ice during the later part of the Glacial Period, and have been subjected to enormous denudation, both during the Glacial Period and since, which has cleared away the bulk of the boulder clay and only left relics of previously widespread deposits. ii. Glacial Lakes and Overflow Valleys. Such a series of glacier movements as has just been indicated would divert the normal drainage of the district and produce lakes in the valleys thus dammed up, The boulder clay at Ashfield’s Pit, and near the railway station at Conisborough, and at Cadeby, on the opposite side of the Don, shows that this gorge must have been filled with ice up to the 225-foot contour. The scattered patches of drift from Edlington to Clifton and Braithwell, reaching up to 400 feet, indicate that the gorge was entirely closed above the 350-foot contour. This is the general height of the Midland watershed of the Don system, and is only broken through at one point south of Conisborough, the Kiveton Valley (330 feet), near the middle of which one of the sources of the river Ryton takes its rise. These considerations warrant one in assuming the existence of a great glacial lake, rising to the level of the 330-foot contour to the west and south, and dammed back by ice from Jonisborough to Barnsley, This lake would overflow by the Kiveton gorge towards Worksop. One cannot expect to find abundant evidences of lake deposits in an area which has suffered so severely by denudation as this; but the geological surveyors map from 4 feet to 9 feet of brick earth and clay resting on gravel at Parkgate, and from 3 feet to 7 feet of brick earth near Wombwell. These indicate a lake both in the Don and Dearne Valleys, covering up the old river gravels. Following this line of argument, and taking the various patches of drift as the relics of moraines, and therefore as indications of periods of rest in glacial movement, I have attempted to map out the lakes that would be produced at the different positions of the ice-front, and have examined the watersheds to see if overflow channels existed such as would be necessary to drain such lakes. The whole has been plotted out on the 6-inch contoured maps, by which the results have heen carefully tested, and a series of lakes made out discharging successively over cols from 175 feet to 335 feet above O.D. These overflow valleys are not of the type so characteristic of Cleveland and the Cheviots. The long period of sub- aérial denudation to which they have been subjected has worn back their sides so that they are now V-shaped, but they are streamless either in whole or in part, and often the nearest streams cut across their ends. In spite of this weathering back there has probably been little alteration of their level, and their present levels may be taken approximately as those of the Glacial Period. Some of them are strike-valleys formed by the denudation of the shales between the outcrop of a bed of Carboniferous sandstone and the dip slope of a lower grit. The objections against such valleys as overflows have been carefully considered, but as the movement of the ice seems to have brought its margin parallel to the general strike of the Coal Measures of this area, it is natural that the deflected drainage should sometimes escape by such routes. In consider- ing the course of the first glacier, it seems probable that it would dam up the Dearne at Ardsley and form a lake overflowing by the Stairfoot Valley at 175 feet. A forward movement would carry it to the Wombwell ridge, and the overflow would be by the Wombwell and Swinton strike-valleys. Further south the ice would probably abut against the projecting spur of the 350-foot contour west of Rawmarsh, and hence would form a lake about that level stretching up to Elsecar, Cawthorne, and Bretton. In searching the watershed for a possible overflow for such a lake, a narrow cut through the 350-foot contour was found at the head of the Wentworth Woodhouse Valley, sloping back to the 400-foot contour on each hand, and with a little stream running across each end at right angles to the TRANSACTIONS OF SECTION C. 569 direction of the col. By this valley at 335 feet the Elsecar lake would be dis- charged into a smaller lake held up by the ice in the Wentworth Woodhouse Valley. When the ice laid down the Masbrough and Sitwell Vale patches of drift, the Rother Valley would be blocked, and the glacial drainage would be discharged round the lobe of ice by channels at Greasborough and Sitwell Vale at 275 feet, and thence into the Don by the Hooton Roberts Valley (180 feet). REPORT—1904. same plot, the lowest percentage of dry matter was only 10°7, and the highest 19:7, the ratio being 100: 184. In three other varieties the ratios came out 100 : 183; 100: 184; 100 : 179. The sugar and nitrogen vary still more widely. In 100 individual roots of one variety, grown side by side on the same plot, the following were the limits :— Ratio. Highest percentage of sugar eee BILL OV 100 : 190 Lowest percentage of sugar So Lid | ’ y 5 Highest percentage of nitrogen . "25 | 100 : 280 Lowest percentage of nitrogen. 094 ° i ‘ : Throughout the examination of the individual roots careful records have been kept of the shape, size and colour of each root which has been sampled and exa- mined. Shape and colour do not appear to be in any way correlated with any peculiarity of chemical composition, As regards size, a mixed sample from fifty large roots is certain to contain a lower percentage of dry matter and sugar than a mixed sample from fifty small roots of the same variety grown under identical conditions, but there is nothing like inverse proportionality between size of root and percentage of dry matter. Among the 1,000 roots examined many large ones have been found containing high percentages of dry matter, and vice versa. By saving such Jarge roots with high percentages of dry matter for seed-mothers it should be possible to improve the race. Again, there appears to be no definite correlation between percentages of dry matter, sugar, and proteid and non-proteid nitrogen. Hach appears to vary inde- pendently of the rest. It should therefore be possible, by continuously selecting as seed-mothers roots of definite composition, to change the composition of the race in any desired direction. Experiments of this kind are already in progress on the University Farm. MONDAY, AUGUST 22. The following Papers were read :— 1. On the Forms of Stems of Plants. By Lorp Avesury, D.C.L., FBS. Some plants have round stems, some square, some triangular, some pentagonal. No doubt there are reasons for these and other forms, but the author found no explanation in botanical works, It is, of course, important for plants, as for architects, to obtain the greatest strength with the least expenditure of material. To do this it is necessary that the plant should be equally liable to rupture at every point when the strain is equal. If not, it is obvious that a certain amount of material may be removed from the strongest part without increasing the danger of rupture. If the stem of a plant, or any other pillar, is affected by pressure—say of wind—one side will be extended and the other compressed, while between them will be a neutral axis, and both extension and compression will be greatest along the surface farthest from the neutral axis. It follows, therefore, that the strongest form is where the material is collected as far as possible from the neutral axis. The two bars cannot, however, be entirely separate, and must therefore be connected by a bar or bars. This is the origin of the well-known girder (fig. 1). If the forces to be resisted act in two directions at right angles to one another, two girders must be combined, one at right angles to the other. It the forces act in all directions, a circular series of girders will be required, as Schwendener and others have pointed out. This is the case in the stems of trees, where the woody fibres form a ring, only separated in places by what are aoe as the ‘medullary’ rays. ‘This is the reason for the prevalent round form of stems. The question then arises, Why is this form not universal? As regards plants having quadrangular stems, it may be pointed out that when the leaves were TRANSACTIONS OF SECTION K. 813 in opposite pairs, each pair at right angles to those above and below, as, for instance, in the dead nettle, the strain of the wind would be mainly in two directions, and the ‘double girder’ (fig. 2) would be the best form. Ifso we should expect to find quadrangular stems associated with opposite leaves. The author then took the British flora, and showed that plants with quadrangular stems always have opposite leaves, and that plants with opposite leaves have generally, though with exceptions, quadrangular stems. The reasons for these exceptions were then considered. Passing to triangular stems, it was pointed out that they might be accounted for by the same considerations. Many Monocotyledons, but not all, have the leaves in threes. Sedges, for instance, all have more or less triangular stems, while in Fig, 1. Fig. 2. grasses they are round. Now, sedges have leaves in threes, while in grasses they are distichous, z.e. in two rows or ranks, In plants with pentagonal stems the same relation prevails. The bramble, for instance, has a stem more or less pentagonal, and the leaves are in whorls of fives, a character, as he incidentally observed, which throws light on the number of petals and sepals. The petals represent a whorl of leaves, and asarule, when the whorl consists of five leaves, the flower has five petals and five sepals; while when the leaves are opposite a whorl would consist of four leaves, as, for instance, in veronica, where also there are four petals. Thus, then, the author finally remarked, plants have worked out for themselves, millions of years ago, principles of construction so as to secure the greatest strength with the least expenditure of materials, which have been gradually pupled to the construction of buildings by the skill and science of our architects and engineers, 2. On Recent Researches on Parasitic Fungi. By Professor H. Marsuati Warp, /.2.S. 3. On the Vegetative Life of some Uridiner. By Professor Jako Eriksson. 4. On the Development of the Aicidium of Uromyces Pox, and on the Life- History of Puccinia Malvacearum. By V. H. Burackman and Miss Hexen C, I. Fraser. TUESDAY, AUGUST 23. The following Papers were read :— 1. Sunshine and CO,-Assimilation : an Account of Experimental Researches. By Dr. F, F. Buackman and Miss Marrnaet. 814 REPORT—1904. 2. Struggle for Pre-eminence and Inhibitory Stimuli in Plants. By Professor L. Errera. Vegetable physiology, like animal physiology, presents a great number of cases of suspensory stimuli, or inhibitory phenomena: arrest of growth of the fructiferous filament of Phycomyces during the formation of the sporangium ; influence of wounds on the growth, and irritability of certain organs (traumatic shock) ; retarding effect of light on elongation, &c. It is also in this way that the influ- ence exercised by the apex of many plants on the subjacent ramifications with which it finds itself in some way struggling for pre-eminence can best be understood. The apex of Picea excelsa, for instance, hinders the side-branches from rising geotropically. If one suppresses it, or if it is notably weakened, a conflict for supremacy obtains between the branches themselves; generally one of the branches nearest the summit, or the strongest among equidistant ones, prevails and forms a new summit. The apex continues to make itself felt even after the removal of a ring of bark; its action then probably proceeds through the living cells of the pith and the medullary rays. On the other hand, in the Arauwcarias (where the regeneration of the summit is effected hy new buds, and not by the rising of already developed branches) the action of the apex is conducted by the bark, and an annular incision is equivalent to cutting off the top. Several arguments can be quoted to support the existence of inhibitory stimuli emanating from the apex, and the production of ‘suckers’ (gourmands) and of ‘witches’ brooms’ can be connected with it. 3. On the Proteases of Plants. By Professor 8. H. Vinks, 7.2.5. As the result of observations made in the course of the last three years, of which accounts have been published from time to time in the ‘ Annals of Botany,’ I have demonstrated the very general occurrence of proteases in all parts of lants. c With regard to the nature of the proteases, it has been ascertained, in the first place by means of the tryptophane-reaction, that their action is peptolytic—that is, that they decompose peptones and albumoses into non-proteid substances such as leucin, tyrosin, and other amido-acids. In no case was peptonisation observed without peptolysis; whence it follows that the proteases are not of the nature of pepsin, but rather correspond to either the trypsin or the erepsin of the animal body. It has been found that in certain cases the juices or extracts of plants can peptonise fibrin, indicating the presence of a tryptic protease; but more com- monly they do not possess this capacity, The following are instances of the peptonisation of fibrin :— Pine-apple (juice); papain (solution); nepenthes (pitcher-liquid); yeast (extract); mushroom (extract); cucumber (juice) ; melon (juice); wheat-germ (extract); asparagus (juice); Phytolacca decandra (extract of leaves); fig (extract of leaves). It may be inferred that a tryptic protease is present in these plants. It is not necessary to give a list of cases in which peptolysis of albumoses and peptones (as contained in the commercial preparation known as Witte-peptone) has been observed; it appears that the juice or watery extract of almost any part of any plant can effect this process. Although fibrin is not digested in these cases, yet any proteid matter naturally present in the juice or extract is digested (autolysis). Hence it may be inferred that an ereptic protease is present. I have found in the yeast and the mushroom that both a tryptic and an ereptic protease are present; no doubt other cases of such an association of proteases, analogous to that of the ‘trypsin’ of animals, remain to be discovered. It may be stated generally that these proteases are most active at the natural degree of acidity of the juices or extracts, TRANSACTIONS OF SECTION K. 815 It is, however, quite possible that the protease here described as ‘ tryptic’ may be found to be a mixture of erepsin with a pepsin. 4, Sexuality in Zygospore Formation. By Dr, A, F, BuaKESLEE. 1, The production of zygospores in the Mucorinew is conditioned primarily by the inherent nature of the individual species, and only secondarily by external factors. 2, According to their method of zygospore formation, the Mucorinee may be divided into two main groups, which have been termed respectively homothallic and heterothallic. 3. In the homothallic group, comprising the minority of the species, zygo- spores are developed from branches of the same thallus or mycelium, and can be obtained from the sowing of a single spore. 4. In the heterothallic group, comprising probably a large majority of the species, zygospores are developed from branches which necessarily belong to thalli or mycelia diverse in character, and can never be obtained from the sowing of a single spore. 5. These sexual strains in an individual species show in general a more or less marked differentiation in vegetative luxuriance, and the more or less luxuriant may be appropriately designated by the use of (+) and (—) signs respectively. G. In heterothallic species, strains have been found which from their failure to react with (+) and (—) strains of the same form have been called ‘neutral,’ and a similar neutrality may be induced by cultivation under adverse conditions, 7. In all species of both groups in which the process of conjugation has been carefully followed, the swollen portions (progametes) from which the gametes are cut off do not grow toward each other, as currently believed, but arise from the stimulus of contact between more or less differentiated hyphae (zygophores), and are from the outset always normally adherent. 8. In some species the zygophores have been demonstrated to be mutually attractive (zygotactic). 9. In the heterogamic subdivision of the homothallic group a distinct and constant differentiation exists between the zygophoric hyphz and the gametes derived from them, but in the remaining homothallic forms and in all hetero- thallic forms no such differentiation is apparent. 10, A process of imperfect hybridisation will occur between unlike strains of different heterothallic species in the same or even in different genera, or between a homothallic form and both strains of a heterothallic species, 11. By taking advantage of this character it has been possible to group together in two opposite series the strains of all the heterothallic forms under cultivation. 12. When thus grouped the (—), or less luxuriant strains, will be in one series, while the (+), or more luxuriant, will be in the other. 13. From the foregoing observations it may be concluded :— (a) That the formation of zygospores is a sexual process ; (b) That the mycelium of a homothallic species is bisexual ; (c) While the mycelium of a heterothallic species is unisexual ; (d) And, further, that in the (+) and (—) series of the heterothallic group are represented the two sexes. 5. Some General Results on the Localisation of Alkaloids in Plants. By Professor L. ERRERA. Microchemistry does not claim in any way to supplant chemistry. Its great value consists in permitting an approach to problems unattainable by ordinary analytical methods, and in accomplishing for physiological (and also for petrographic) 816 REPORT—1904. chemistry the work of penetration and localisation which the microscope performs for structure. For a long time botanical microchemistry has dealt with a limited number of bodies and reactions: cellulose, starch, reducing sugars, inulin, proteid matters, asparagin, tannins, silica, and calcium compounds. Gradually a series of interest- ing bodies have been added to the original scanty list, such as sulphur, glycogen, salts of iron and other bases, alkaloids, myrosine, certain glycosids, prussic acid, &c. Although a few valuable preliminary researches had already appeared, a more methodical attempt to localise, in the various tissues, the important group of alkaloids was made in a paper I published in 1887 in collaboration with two of my pupils, Dr. Maistriau and the lamented Dr. Clautriau. We used a great number of general as well as special reagents of the different alkaloids which we examined, for the sake of their mutual control. In consequence of the fact that many alkaloids are closely related to proteids, a great analogy exists in the action of many general reagents on both classes of compounds. This is, of course, a serious difficulty in microchemical determinations. But an alcoholic solution of tartaric acid separates clearly the two groups, dissolving the former from the cells and leaving the latter undissolved, and this method has always given very good results. Similar lines of investigation have been followed with success within the last eighteen years by a number of my pupils and by many other observers, principally in Holland and Sweden, but also in France, Germany, and Italy. The more important conclusions arrived at by these researches (which must, of course, be conducted critically) might be summarised as follows :— (1) The qualitative and to some extent the quantitative distribution of alka- loids (especially those belonging to the pyridic series) can be determined micro- chemically in the various organs of plants with perfect certainty. (2) In living cells the alkaloids are eliminated from the protoplasm and gather in the vacuole. It is only in cells which have lost all their liquid contents (as in ripe seeds) or in dead cells that they accumulate in the protoplasm or the cell-wall. (8) The alkaloids are generally localised : (a) In very active tissues: chiefly in the neighbourhood of growing points (a little behind the initial cells), in the ovules, &c. ; (6) In the epidermis, the epidermic hairs, often also in the sub-epidermic layers of vegetative organs, as well as the outer layers of fruits and seeds; (ce) Round the fibro-vascular bundles, in certain of their phloem-elements and in the neighbourhood of the pericycle ; (d) In the phellogen and the youngest cork-cells (either normal or consecutive to traumatism) ; (e) In the laticiferous or similar elements, when present. (4) By means of the microchemical tests many new alkaloid-plants have been discovered, the result being afterwards confirmed by the usual chemical methods, e.g. certain Orchidacese (where alkaloids were formerly quite unknown), Amaryl- lidaceze, Papaveracese, Ranunculacee, Solanacez, &c. (5) Although the investigation of animal tissues is particularly delicate, obser- vations (yet unpublished) show that even here a microchemical identification of organic bases is sometimes possible—for instance, in Salamandra, (6) Granting that the physiology of alkaloids is far from settled, I think a critical study of their topography as well as their behaviour in germination, growth, etiolation, maturation of seeds, &c., supports the view that they are waste-products, resulting from the catabolism of cytoplasm, and secondarily utilised for defence against animals. A few grams of an alkaloid constitute a protection not less efficient than the strongest spines. The diminution of the proportion of alkaloids in a given plant is often wrongly interpreted as a proof of their direct consumption as plastic material, But the TRANSACTIONS -OF SECTION K, 817 decrease may be only apparent—for example, when, the alkaloids remaining unchanged, the amount of other substances becomes greater. Secondly, the fact that a body disappears from the plant does not demonstrate that it has been used as food : it may have been eliminated in a volatile state or otherwise transformed, Thirdly, it must not be forgotten that the percentage of nitrogen in alkaloids is generally very small, so that they would be a very poor nitrogen-store. Even in the case of caffeine, which is exceptionally rich in nitrogen, numerous experiments of Clautriau, confirmed afterwards by Suzuki, lead to the conclusion that it is not a plastic substance. This, nevertheless, does not exclude the possibility of certain products of the splitting-up of the alkaloid molecule being ulteriorly resumed by anabolism, just as the essentially catabolic CO, formed in respiration can serve to regenerate starch in the green cell. 6. Lhe Discovery of a New Alkaloid in Strychnos Nuw Vomica. By Dr. J. P. Lorsy. While experimenting on the physiological significance of the alkaloid in the leaves of cinchona, I found that both brucine and strychnine could be made to disappear, which led me to believe that the Jeaves were entirely devoid of alkaloid at the end of the experiment. Closer investigation showed, however, that an alkaloid remained, and this alkaloid proved to be a new one, entirely unknown at the time, in strychnos. It was later, at my request, isolated, analysed, and de- scribed by Dr. Boorsma. 7. On the Significance of the so-called Anti-ferment Reaction in Geotropi- iy cally Stimulated Roots. Ly Professor F. Czapux. Up to the present time we have had only one method of deciding whether or no a plant perceives a stimulus of orientation, namely, the method of observing the presence or absence of a reflex reaction, The fact that no reaction occurs may depend either on the stimulus not being perceived, or on the reaction being absent though the stimulus is perceived. In 1897 the author discovered qualitative chemical differences between stimulated and unstimulated root-tips. More recently he has shown that in geotropism (and other tropisms) the oxidation of aromatic amidic acids is checked, especially in the metabolism of tyrosin. This leads to an accumulation of homogentisinic acid, a substance having a well-marked power of reducing silver solutions. This checking action is caused by the formation of an anti-enzyme, which retards the action of the oxydase on the homogentisinic acid. By autolytic experiments which permit the control of the decrease of the reducing power this ‘ anti-ferment’ reaction can easily be established. The reaction in question takes place within 5-6 minutes after the roots have been placed horizontally, and can be applied to the investigation of a number of questions; for instance, the localisation of geotropic sensibility in the root-tip, the behaviour of roots on the klinostat, the relation between geotropic activity and the angle at which the organ is placed. It has been conclusively proved that the anti-ferment reaction is not produced by any general disturbance of normal metabolism, such as is due to poison, mechanical injury, electrical influence, tem- perature, or light. The anti-ferment reaction only occurs in consequence of perception of stimuli of orientation, and can be used, to the best advantage, to find out whether or no roots or other organs perceive such a stimulus in certain contro- yersial cases. WEDNESDAY, AUGUST 24. The following Papers were read :— 1. A Measurement of the Great Swamp Cypress at Santa Maria del Tule, Mexico. By Aurrep P. Maupstay. 1904. 3G 818 REPORT—1904. 2. Oxidising Enzymes and Katalases in Plants. Ly Professor R. Cuovat. 3. On the Pollination of Gymnosperms. By Professor K, Fusu. 4. The Dissemination and Germination of Arceuthobium occidentale. Ly Dr. Guorce J. Peirce, As is well known, the fruits of Arceuthobiwn explode, discharging the ‘seed’ to a distance often of 25 feet. ‘The conditions for developing the greatest explosive force are (1) an abundance of water in the soil and the host-plant, a species of pine, and (2) moist air. The structure of the fruit is such that it will withstand great internal pressure, and when the fruit finally breaks at the base, the force which stretched the walls of the fruit and compressed the ‘seed’ is applied against and violently expels the ‘seed.’ The force develops mainly in consequence of the absorption of water by the gelatinous walls of the cells in certain layers in the fruit. Germination can take place upon anything, but moist air and moderate warmth are essential. The roots of the seedlings are markedly negatively phototropic. Unless the forward growth of the root be stopped by some obstacle, the root does not attach itself and form a holdfast. Only on rough bark, never on leaves or smooth parts of the bark, is germination followed by attachment and penetration into the host. ‘lhe haustorium, after penetrating into the cortex, sends out slender branches penetrating the medullary rays and attaching themselves to the tracheids of the host. Meantime buds develop on the mass of parasitic cells in the cortex of the host, and these quickly grow out into branches which at first vegetate and later flower. There is perfect connection between the xylem elements in the bundles of host and parasite. Between the phloem clements of host and parasite parenchymatous cells intervene, as is the case in other green parasites. 5, On the Transpiration Stream vi Smali Plants. Ly Dr, Ovrvo V, DarsisHiRe. 6, Ona Brilliant Pigment appearing after Injury ww Species of Jacobinia (N.0. Acanthacew). By J. Parwin, ALA, Shoots of certain species of Jacobinia,' when bruised and extracted with water, yield a beautiful purplish liquid. Liebmann discovered these species while travel- ling in Ceutral America about half a century ago, and found the Indians using them for dyeing purposes. ‘Thomas,* while in Mexico, submitted the colouring principle cf Jacobinia Mohintli to a brief examination. Since then these plants seem to have received no further investigation, and their peculiarity is apparently little known to botanists. ‘The object of the present paper is to direct attention to this conspicuous example of pigment-formation, and to give a few details con- cerning the chromogen and the colouring matter resulting from it. The author hopes to make a full investigation later. So far the observations have been made on the two very similar species, Jacobinia tinctoria and Jacobinia Mohintli. The peculiar behaviour of the former plant was brought to the writer’s notice, when in Ceylon, by Mr. Willis, the Director of the Royal Botanic Gardens, Peradeniya. The pigment does not exist as such in the living plant, but appears only on death. Leaves, however, killed by boiling water remain green and do not darken. 1 Jacobinia tinctoria, J. Mohintli, J. mcana, J. neglecta, and J. verrucosa, 2 Journ, de Pharm. et de Chimie, 1866, sev. iv. t. iii. p. 251. rt ee TRANSACTIONS OF SECTION K. 819 Hence the pigment most likely arises through enzymic action. Slight alkalinity hastens its appearance. Oxygen is also necessary for its formation. It is readily soluble in water and gives a fluorescent solution, purple to violet by transmitted and blood-red by reflected light. A trace of acid robs the solution of most of its colour. The original tint reappears on neutralisation. Alkali turns it bluer, and if strong changes it to green, eventually destroying it. Light does not alter it. All parts of the plant except the flower can produce the pigment. Such a reducing agent as stannous chloride decolorises an aqueous solution of the pigment. Micro-organisms can also readily bleach it, when oxygen is excluded. On allowing air to enter, the original colour at once returns. The whole phenomenon bears some resemblance to the way in which indigo arises in plant-tissues. The chromogen of Jacobinia is probably a glucoside. In the living cell this substance and its enzyme may be differently situated, perhaps one in the protoplasm and the other in the sap. On the destruction of the cell the two come in contact. ‘he first result is the formation of a colourless body. Then this through the oxygen of the air, possibly assisted by an oxidase, is changed into the pigment. This behaviour of Jacobinia is perhaps only a striking instance of a common feature of plant-juices, viz., their tendency to darken on exposure to the air. 7. Saponarin (‘Soluble Starch’). By Guorcu Barger. Dissolved in the cell-sap of the leaf epidermis of a number of plants there occurs a substance which is coloured blue by a solution of iodine in potassium iodide. This so-called ‘soluble starch * was first observed in 1857. Sanio found it in the leaf epidermis of Gagea lutea, and Schenk in that of three species of Ornithogalum. Similar observations were afterwards made by Trécul, Nigeli, and Kraus. The last important paper was by the Swiss botanist Dufour, in 1886; he found the substance in about twenty different plants, and investigated its physio- logical importance. The first (and unpublished) attempt to isolate the substance was made by the late G. Clautriau. Later, when the author was his successor as assistant to Professor L. Errera at the Brussels Botanical Institute, the latter suggested a renewed investigation of the substance. Fairly large quantities of the chemically pure substance have been isolated from the leaves of Saponaria officinalis, L. It has accordingly been called Saponarin; it may or may not be identical with the ‘soluble starch’ of all the other plants. Saponarin is a glucoside; it crystallises in small needles, and its probable formula is C,,H,,O0,,, On hydrolysis it yields glucose and a substance which is closely related to the class of bodies known as flavones. Flavone derivatives are widely distributed in plants, either as such or combined with sugar, as glucosides. Their physiological function is doubtful ; perhaps they are merely waste products. For the detection of saponarin under the microscope the following reactions cau be applied to sections or to strips of the epidermis :— 1, With iodine and potassium iodide the whole of the cell-sap is coloured uniformly blue or violet, and the substance which issues from injured cells pro- duces the same colour outside these cells. On warming, the colour disappears ; it reappears on cooling outside the cells. 2. Dilute alkalis and alkaline carbonates, as well as strong hydrochloric or sulphuric acid, produce an intense golden-yellow colour, first inside the cells con- taining saponarin, and then outside, 3. Ferric chlovide produces a reddish-brown colour in these cells ; sometimes the colour is green or violet, owing to the simultaneous presence of tannins. These micro-chemical reactions of saponarin were used in the investigation of its physiological importance, but no very definite results were arrived at. 8G 2 820 REPORT—1904. Dufour’s observation was confirmed that the substance does not disappear if the plant is kept in the dark. In etiolated shoots, grown entirely in the dark from a rhizome, the substance is not formed, but it appears when these shoots are transferred to the light, even after they have been cut off from the rhizome and placed in water. Saponarin is therefore produced by the leaves themselves, and only when these are kept in the light. No enzyme could be found capable of hydrolysing the glucoside, and Professor Beyerinck, of Delft, was kind enough to inform the author that he could not split it with bacteria. From the way in which the substance disappears in Hordeum and Bryonia after the death of the plant, it seems nevertheless likely that an enzyme exists capable of hydrolysing the glucoside. Nothing is known about the way in which saponarin is useful to the plant. Professor Errera has suggested that as it is only found in the epidermis it might act as a deterrent to animals, after the manner of many alkaloids. The substance is, however, physio'ogically inactive. Pfeffer has suggested that aromatic substances combine with sugar to form substances which diosmose with difficulty, and so to store up a greater supply of sugar than would be otherwise possible. In this connection it may be observed that saponarin does not truly dissolve in water, but only forms a suspension like starch, so that it does not raise the osmotic pressure of the cell-sap in which it occurs. 8. On the Centrosome of the Hepaticw. By K. Miyuxen, M.A., Ph.D. The present communication is a part of my uncompleted study on the spermato- genesis of the Hepatic. The study was originally started with the cbject of repeating the recent remarkable observations of Ikeno on Merchantia polymorpha, and was afterwards extended to Fegatella conica, Pellia epiphylla, Makinoa crispa, and a species of Aneura. When the nuclear division is about to take place the nucleus assumes a more or less elliptical shape, and two cytoplasmic radiations or asters are seen at opposite poles of the nucleus. In the centre of the aster no distinct hody corresponding to the centrosome was observed. When the spindle is formed the aster entirely disappears, and no structure which might be taken for a centrosome was seen at the spindle pole. I also failed to see, either in the resting stage or in the dividing nucleus of the young antheridium, the structure corresponding to the centrosome of Ikeno. Only, in the last division in the antheridium of Merchantia and Fegatella 1 found a deeply staining body at each pole of the spindle, as figured by Ikeno, Although I have not studied the further behaviour of this body in the develop- ment of the spermatozoid, there can be little doubt that it will take part in the formation of cilia as [keno described, and may properly be called a blepharoplast. On the other hand, at the spindle pole of the last division of Makinoa I was able to recognise neither centrosome nor blepharoplast. However, I often observed two granular bodies, nearly opposite to each other, at some distance from each pole of the spindle. In the spermatid I often observed a deeply staining spherical body in the cytoplasm, which is very probably a blepharoplast. The identity of these two structures is very probable, although it has not been conclusively proved. The presence of centrosome in the flowering plants and ferns seems to have been almost conclusively dis,roved by the careful researches of cytologists during the last ten years. On the other hand, it is still generally believed that in the Bryophytes and Thallophytes centrosome does exist. But my present study seems to show that there is no true centrosome, at least in the Hepatic, agreeing with the recent investigation of Gregoire in Pellia. The centrosome hitherto reported in the cells of the Hepatic is nothing but a centre of cytoplasmic radiations. TRANSACTIONS OF SECTION K. 821 9, Further Cultural Experiments with ‘ Biologic Forms’ of the Erysiphacee. By Ernest 8. Satmon, £.L.S. In a recent paper! the author described a method of culture by means of which the conidia of ‘biologic forms’ of Erysiphe Graminis, DC., can be induced to infect leaves of host-species which normally are immune to their attacks. In this method of culture the vitality of the inoculated leaf was affected by cutting oS piece of its tissue, or by injuring the leaf by touching it with a red-hot nife. In the present paper further methods are described by which the same result can be obtained. A preliminary series of experiments proved that the ascospores of a ‘ biologic form’ are able, in the same manner as the conidia, to infect leaves injured by the removal of a piece of the leaf-tissue, although quite unable to cause any infection of the uninjured leaf of the species used. An extensive series of experiments was then made in which the leaf previous to inoculation had been injured in one of the following ways: By pricking with a pin, by stamping out a circular piece of the leaf with a cork-borer, by allowing slugs to eat away portions of the leaf, by pressure with weights, or by nipping the leaf with a pair of forceps, Leaves injured by the action of narcotics and heat were also used, the leaf previous to inoculation being exposed to ether, chloroform, or alcohol vapour, or immersed in a mixture of alcohol and water, or heated gradually in water to 49°:5 or 50° C. The results of the experiments carried out prove that not only mechanical injuries, such as wounds from cuts, bruises, attacks of slugs, &e., but also injuries due to the action of narcotics and heat, cause a leaf to become susceptible to a ‘biologic form’ of a fungus to which it is normally immune. Attention is directed to the fact that these cases of the loss of immunity brought about by causes which affect the vitality of the leaf find their exact parallel in the recorded instances of induced susceptibility in animals to certain diseases caused by bacilli. To describe cases where a form of a fungus which is specialised to certain host-plants and confined to them under normal circumstances proves able to infect injured parts of a strange host the author proposes the terms wvenoparasite and wenoparasitism. The terms may be used also in the cases where fungi which live usually as saprophytes prove able to infect injured parts of living plants. In the case of the specialised fungus, when on its proper host, the terms @coparasite and. ecoparasitism are proposed. A series of experiments was carried out with the object of ascertaining the infection-powers of the conidia of the first generation produced on barley-leaves inoculated—after having been rendered susceptible by the action of ether, or alcohol, or heat—with conidia taken from wheat. In the sixteen cases the conidia produced on such treated barley-leaves proved, when sown simultaneously on normal leaves of barley and wheat, totally unable to cause any infection on the barley, while causing in every case full, and usually virulent, infection on the wheat. In order to see if any subsequent variation would occur in the infection- powers of the conidia of the fungus produced on the treated barley-leaves, conidia of the successive generations produced on wheat, up to the sixteenth generation, were cultivated. In every case the conidia proved able to infect fully leaves of wheat, while never producing any sign of infection on barley. These experiments demonstrate the fact that the infection-powers of a ‘ biologic form’ are not altered by its residence for one generation on a strange host-plant treated in the manner described, and give also some evidence in favour of the idea of the hereditary nature of the infection-powers of certain ‘ biologic forms.’ \ Phil. Trans., vol, exevii. 1904, pp. 107-122. 822 REPORT—1904. 10. The Inheritance of Susceptibility and Immunity to the Attacks of Yellow Rust. By R. H. Birren, J.A. Evidence was brought forward to show that the liability to certain diseases is inherited, and the results of crossing together races of wheat relatively immune and highly susceptible to the attacks of Puccinia glumarum were described in detail. It appears that susceptibility is dominant over immunity in the hybrid, whilst in the second and third generations the immune, or recessive, forms are found in approximately the Mendelian ratio of 1 to 3. 1). Infection Experiments with various Uredinee. By Miss C. M, Gipson, The following list summarises the results of successful and doubtful cases of the entry of the stomata by the germ tubes of the spores employed :— Result Spores Species of Fungus from Host Uredospores | Uredo chrysanthemi Chrysanthe- | R. ficaria | Enter freely MUM | | Alcidiospores | Phragmidium rose- | Rosa i ; alpine AMecidiospores | Uromyces Pow Ranunculus a | 3 TEPens Aicidiospores Peidium Buniti | Bunium re | Negative? Alexuosum | AXicidiospores Puceinia Poarum Tussilago | Caltha Enter freely Sarfara palustris Uredospores Tromyces geranii Geranium 9 ¥ pyrenaicum Aicidiospores Puccinia Menthe Mentha as Enter not very freely | Uredospores Puceinia hieracii Carduus ? Caltha | Enter freely | | Jicidiospores Phragmidium Poterium iy 2 or 3 doubt- sanguisorbe sanquisorba ful entries Uredospores Puceinia glumarum Triticum 3 1 certain vulgare entry From the above results it is evident— 1, That the germ tubes from the spores of any uredine may enter almost any lant. ‘ 2, That the attractive substance causing entry is not specialised in each species, but is something common to all plants. 3. That the entrance of the stoma by any germ tube cannot be taken as an index of the infective capacity of that germ tube. The paper also dealt with some experiments on chrysanthemum rust and time experiments on the germinating power of uredo- and :cidio-spores. 12. On the Normal [Histology of the Uredo of Puccinia glumarum. By T. B. P. Evans, 13. Pineapple Galls of the Spruce. By E. R. Burpon, B.A. The galls are caused by the hibernating generation of certain aphid belonging to the genus Chermes. a In the autumn a Chermes larva drives its long proboscis into the stem of the ee TRANSACTIONS OF SECTION K. 823 spruce, just below a winter bud or into the bud itself, and thus anchored passes into a hibernating condition. The tip of the proboscis lies in the neighbourhood of the cambium. In the spring the insect awakens, commences to suck, undergoes three eedyses, and then lays a great number of eggs. It probably injects an irritant into the bud, which is forced into precocious growth, and by the time the bud-scales are thrown off the rudimentary shoot has become enormously swollen and stunted. The swelling proceeds outwards through the cortex into the bases of the young needles, and takes place in such a manner that the spaces in the axils of the needles become converted into chambers. Into the chambers the young larve make their way, and there remain until the gall is ripe, when the chambers open and the inhabitants emerge as winged insects, which carry the infection to other trees. In the early stages the chlorophyll, tannin, resin, resin canals, and secretory cells of every description disappear within the gall area, which consists entirely of enormously swollen parenchymatous cells. After the shoot emerges from the bud-seales and becomes exposed to light these all reappear, though in abnormal situations. Starch is found in great abundance round the periphery of the gall area, and it is suggested that it may be the ultimate product of the disintegration of the tannin. The nuclei of the galled cells also become enlarged, and the chromatin network becomes aggregated into numerous wart-like nucleoli. The mitotic figures are of Ma usual somatic type, and no indication of heterotypical mitoses has yet been ound. The later stages of the gall are still under examination. The complicated life-cycle of the insect and the connection between it and the well-known larch-blight will be shown by means of a table thrown on to the screen. The pests may he got rid of by washing hoth spruces and larches with a paraffin wash during the winter. 14. The History and Distribution of Catesby’s Pitcher Plant (Sarracen Catesbei). Py Professor Joun M. MACFARLANE. 15. Observations on Two Species of Alpine Rose and their supposed Hybrids. By Professor Joun M. MACFARLANE. 16. Exhibition of a Bigenerie Hybrid between Gymnadenia and Nigritella. By Professor Jonn M. MAcrARLANR. 17. The Destruction of Wooden Paving Blocks by the Fungus Lentinus lepideus, /’r. 2y A. H. Reaiwatp Butier, D.Sc, Ph.D. The destruction of a great many paving blocks, made of pine- or fir-wood, in the city of Birmingham is being brought about by Lentinus lepideus, a fungus belonging to the Agaricini, Considerable repairs to the pavement are thereby necessitated. Single blocks, or small groups of blocks, at intervals in the streets go completely rotten, so that one can break up the wood with the fingers. The streets affected become unduly bumpy. In wet weather water collects above places where rotten blocks are, 824, REPORT—1904. A number of rotting blocks, obtained from time to time from the streets, were placed in a large damp-chamber. In the course of a few weeks fruit-bodies of Lentinus lepideus appeared upon them. The spores remain unchanged in distilled water and tap-water, but germinate readily in Pasteur’s Fluid and in beef-gelatine. They also germinate in decoctions of horse-dung and of pine-wood. The pavement is probably infected by spores after the blocks have been laid down. ‘The mycelium of the fungus often grows from a rotten block to the neighbouring sound ones. No fruit-bodies are produced in the streets, owing to the traffic. The wood is rotted by Lentinus /epideus in very much the same manner as by the Dry Rot Fungus (Merudius lacrimans), It becomes red and is spongy when wet. It shrinks and cracks considerably on drying, and is then very brittle. Cellulose is removed from the cell-walls. Hadromal and a red friable substance are left - behind. The paving blocs, used in the pavements referred to, were dipped in creosote before use. Had they been fully impregnated with that substance, the ravages of Lentinus lepideus or any other wood-destroying fungus would have been prevented. 18. The Reactions of the Frivit-bodies of Lentinus lepideus, /r., to External Stimuli. By A. WW. Reetwwatp Buiter, D.Se., Ph.D. The fruit-bodies of Lentinus lepideus were grown upon rotting paving blocks, taken from the streets of Birmingham. The fungus belongs to the Agaricini. The papille, from which the fruit-bodies arise, are not somatotropic, so far as the surface of the wooden substratum is concerned, but grow out perpendicularly to the surface of the mycelial layer on which they develop. Their formation takes place equally well in light or darkness. Before the development of the pileus, the stipe is perfectly indifferent to geotropic stimuli. In the absence of light it is rectipetal, and in its presence positively heliotropic. In the absence of light the stipe may continue to grow for weeks or months, and may attain a length of 17 centimetres, but no signs of a pileus make their appearance. The development of the pileus depends on the presence of sufficient illumination. Grown in the dark, therefore, the fruit-bodies are all monstrous and abortive. While the pileus is developing, the stipe alters its reactions to external stimuli. It becomes negatively geotropic and ceases to be heliotropic. The pileus is sometimes developed unequally in fruit-bodies with oblique stipes. The longest gills are always formed on the lower side of the stipe. The inequality of development is induced by the stimulus of gravity. The gills begin their development in such manner as to become perpendicular to the surface of the pileus, from which they are formed. They are never helio- tropic, but they become positively geotropic. Fruit-bodies grown in darkness or weak light are prone to branching, and often become grotesque. Branching may be due to internal causes or to injury of young pilei. It may be shown that the reactions of the fruit-bodies to external stimuli, as described above, are admirably adapted for the economical distribution of the spores. 19. The Structure of the Ascocarp in the Genus Monascus. By B. T. P. Barker, J/.A. Since the publication of the author's earlier paper on this subject Ikeno and Dangeard have published accounts of the structure of the ascocarp of Monascus purpureus, and the latter also describes the ‘ Samsu’ fungus, which he has named TRANSACTIONS OF SECTION K, 825 Monascus Barkeri. He agrees with the author that the fructification is not an invested sporangium, but an ascocarp containing numerous small asci, but differs as to the sexual nature cf the archicarp, and affirms that a layer of nutritive hyphe surrounds the asci in the place of the enlarged central cell. Ikeno, on the other hand, disputes the presence of asci, and declares that spore-formation takes place in an enlarged sporangium-like central cell by the massing together and subsequent division of dense portions of its protoplasm. The author has made a fresh examination of both species, confirms his previous results for M. Barkeri, and finds that M. purpureus yields corresponding results, the only points of difference being the formation of a basal cell in the ascogonium in many instances and the production of a more vivid red pigment in the case of the latter species. Fusion between the antheridial branch and the ascogonium occurs before the division of the ascogonium, but nuclear fusion at this stage has not been observed with certainty, although pairs of nuclei have been frequently found. The central cell swells considerably, and eventually almost completely encircles the ascogenous hyphe which originate from it. The cells of the ascogenous hyph are often multinucleate, in which case the nuclei are usually paired, but in many instances they are binucleate. The asci appear to be developed from the sub-terminal binucleate cells of branches of these hyphe, the nuclei fusing and the fusion nucleus then dividing to form eight daughter- nuclei, which become the nuclei of the spores. The spores are formed in the manner described by Harper for other Ascomycetes. By repeated cultivation of M. purpureus in beer-wort at 34° C.a variety was isolated which produced conidia only, although normally ascocarps are also formed. 20. Further Observations on the Ascocarp of Ryparobius. By B. T. P. Barker, JA. In an earlier paper on this subject it was shown that the archicarp of a species of Ryparobius therein described possessed the characters of the archicarp of Thelebolus, as described by Brefeld, and differed from those of other species of Ryparobius, as figured by Zukal. Recently in some old cultures archicarps were found which, while retaining the typical structure in essentials, varied from the usual type as to the position and the manner of development, and resembled in many respects the type described by Zukal. Further details have also been obtained concerning the cytology of the ascocarp at various stages of its develop- ment. Both the antheridial branch and the ascogonium are uninucleate when first formed ; but subsequent nuclear division occurs in each organ near the time of fusion. The fusion takes place at the point of contact of these structures, this usually being at or near their apices. Probably a nucleus passes from the former to the latter at this period, and shortly afterwards walls are formed in both, so that the resulting cells are uninucleate, with the exception of the subterminal cell of the ascogonium, which is sometimes found to contain two nuclei close together. Investing hyphe then develop and encircle the ascogonium, which enlarges considerably and for a short period consists of a row of several uninucleate cells. These are later found in a binucleate, or occasionally a quadrinucleate, condition. From them ascogenous hyphse arise, and the asci are formed from their binucleate subterminal cells. The two nuclei in these fuse together, and the fusion nucleus enlarges to an enormous extent, keeping pace with the growth of the ascus. The nucleolus now becomes a most striking structure, considerably larger than the vegetative nuclei, and containing apparently almost the whole of the chromatin of the nucleus, so that the nuclear body resembles alarge vacuole. Nuclear division then takes place, the nucleolus giving up chromatin and showing very distinct signs of a reticulated structure. The number of chromosomes is probably not less than eight. Successive divisions take place very rapidly, and when sixty-four nuclei are formed they become regularly grouped in dense granular protoplasm around the periphery of the ascus. Other series of divisions now usually occur, 826 REPORT— 1904. and eventually uninucleate spores are formed, these being ovoid pointed bodies, arranged at the time of their first appearance with their long axes parallel to the radii of the ascus. The protoplasm passes through a series of characteristic changes during the development of the ascus, and the whole process of spore formation seems to be intermediate between the typical methods in sporangia and ascl, 21, Some Features in the Development of the Geoglossacere, By Dr, Extas J, Duranp. TRANSACTIONS OF SECTION L. 827 Sretion L.—EDUCATIONAL SCIENCE. PRESIDENT oF THE Srction—The Right Rey. the Lord Bisnop oF Hererorp, D.D., LL.D. THURSDAY, AUGUST 18. The President delivered the following Address :-— I am moved to begin this address with a word of personal apology, the strongest feeling in my mind, as I rise to deliver it, being that in the fitness of things some one of the many distinguished representatives of education in this University would have been the natural occupant of this chair on the present oceasion ; and for my own part I could hardly have brought myself to accept the invitation with which I have been honoured had I not been led to understand that on occasions of this kind it is preferred by the members of the University visited that some one from the outside should be invited as I have heen. Thus I have accepted, not without hesitation and misgiving, but with the more gratitude, as feeling that I am here because of the wish of the Cambridge authorities to have some one connected with the University of Oxford, and I desire that the grateful acknowledgment of this courtesy and kindness should be my first word as President of the Educational Section. The inclusion of Education among the various sections of this Association for the Advancement of Science is sufficient evidence that a new educational era has beeun in this country. Whatever may be the defects of our educational system or want of system, whatever changes may be necessary to bring it, in the current phrase, up to date, the days of unthinking tradition are over. Scientific method is entering on its inheritance, and it has begun to include the field of education along with other fields of life and thought within the sphere of its influence. And scientific minds are asking on every side of us what is the end of true education, and are we on the right way to it ? Mee education, almost insuperably difficult in practice, has been often defined in words, Plato told us long ago how it is music for the soul and gymnastic for the body, both intended for the benefit of the soul, how it is a life-long process, how good manners are a branch of it and poetry its principal part, though the poets are but poor educators, how great is the importance of good surroundings, how the young should be reared in wholesome pastures and be late learners of evil, if they must learn it at all, how nothing mean or vile should meet the eye or strike the ear of the young, how in infancy education should be through pleasurable interest, how dangerous it is when ill directed, how it is not so much a process of acquisition as the use of powers already existing in us, not the filling of a vessel, but turning the eye of the soul towards the light, how it aims at ideals and is intended to promote virtue, and is the first and fairest of all things. Tn this description, I take it, we most of us agree, though some of Plato’s views 828 REPORT— 1904. would doubtless elicit differences of opinion amongst us, as, for instance, that education ought not to be compulsory, or that it should be the same for women as for men. One of his statements may be soothing to our English self-complacency, for, as is the habit of idealists in every age, he says that even in Athens they care nothing for educational training, one of the most brilliant of their younger statesmen plead- ing that it does not matter, because others are as ignorant as he. Or again, our own Milton sums it up in fewer words, but very impressively, when he says true education fits a man to perform justly, skilfully, and magnani- mously all the offices, both private and public, of peace and war. It is a noble aim which he thus sets before us, to make our sons skilful, just, magnanimous, and every description of aims and methods can be little more than an expansion of it. Of the importance of right aims and ideals there can, as Plato reminded us, be no question, because of the danger of ill-directed aims, and the lasting nature of early impressions. ; What we learnt at school, when all the world was young to us, whether we learnt it with weariness or pain, or under happier influences with a quickening pulse and the glow of enjoyment, passed into the blood, as Stevenson said some- where, and became native in the memory. True education, then, as we all acknowledge, aims at cultivating the highest and most efficient type of personality, men not only appropriately and technically equipped for their professional business, but men endowed with the best gifts and inspired with high purposes, men who desire to follow the more excellent ways and to lead others in them, who love knowledge, truth, freedom, justice, in all the relations of life, whether individual or social, men marked by sense of duty and moral thoughtfulness, public spirit, and strength of character. Such an education is the true basis of individual and national welfare, and experience has abundantly shown how necessary this is to save men from distorted views of history, from wrong conceptions of patriotism and public duty, from mistaken aims and disastrous policy. Thus, for instance, a good and true education shows us that the true basis of life is moral and economic and not military, and the true aim of both individuals and nations is knowledge, justice, freedom, peace, magnanimity, and not pride, ageoression, force, or greed. Scientific consideration of our subject will of course dea] largely with such details as the relative claims of the humanist and the realist, subjects and methods of instruction, the correlation of different grades of education, the adaptation of this or that system to special needs, and so forth; but through all this these fundamental requirements of the true education, as placarded before us by Plato or by Milton, must always hold the chief place, and all others must be kept in due and conscious subordination to these. This very obvious remark calls for repetition, as we are so apt to lose sight of ideals amidst the dust of controversy about details or methods or practical needs. How, then, does our English education stand when thus considered? And what signs are there in our life of our having fallen short or fallen behind, or missed the best that was possible in our circumstances ? It may, I venture to think, be fairly said that to a reflective observer, various things are patent which seem to make it expedient that the subject of education should have its place in the proceedings of a scientific association like this, although there may be difference of opinion as to how it should be handled there. In saying this I have to admit that some educational reformers seem to have doubts as to the propriety of its inclusicn in your programme. The element of personality is so pre-eminently vital in all education that some men say it cannot be treated as wholly scientific in the ordinary sense, and that there is serious risk in subjecting it too rigidly to the methods of investigation which naturally hold the field in the main departments of this Association, and that men who are wholly accustomed to such methods are not the best equipped, for dealing with the problems involved in the education of the young. TRANSACTIONS OF SECTION L. 829 If I endeavour ina few paragraphs to express what, so far as I understand it, is the ground of this fear in the minds of some thoughtful objectors, I trust I may not be thought to be wasting your time. This Section is still in its swaddling-clothes. It has to justify its existence in the coming years. It is therefore of moment that it should be started on its course of early growth as free as may be from prejudice and with the sympathy and support of all who, whatever be their views as humanists or realists, as men of letters or men of science, as teachers of religion or men of practical affairs, desire to see the education of the young in our country advancing and expanding on the best lines. On this account the misgivings or warnings of every thoughtful critic deserve our attention and may be helpful. In what I am saying it will be understood, I hope, that I am not expressing views of my own, but endeavouring to act as the recording instrument, a very inadequate and old-fashioned instrument, of views which come to me from one quarter and another. The inclusion of the study of education by the British Association for the Advancement of Science among its subjects of investigation is, they say, not alto- gether free from risk. If you treat education too exclusively according to the analytic naturalistic methods of scientific men you incur the danger of unfitting teachers for the best part of their work, which depends on the inspiring influence of personal ideals breathing through all their lessons, on a vivid sense of the subtle element of per- sonality in the pupil, and on their responsible exercise of the power of their own personality. In giving the scientifically educated teacher the analytic knowledge of the dissecting chamber you may possibly rob him of the magnetic power of personal sympathy and influence. In this sense, at all events, you must not dehumanise him, The most eminent psychologists, the critics tell us, are beginning to recog- nise the danger, and they bid the educator beware of science which has a great deal to say about mental processes but takes too little account of the emotions and the will, and seems inclined to forget that men are personalities and not plants or trees or machines, and that boys will be boys. The combination of a living and fruitful experience, these critics assert, with systematic organised scientific methods and processes is more difficult in educa- tion than in any other realm of knowledge, because the data are so complicated and so subtle and elusive. Hence, they say to me quite frankly, the risk of failure to do much that will be of real value in your Educational Section. In particular I have the impression that they set no great store by presidential addresses, although the address to which you are now listening has at least one merit, that it has no claim to be technically scientific, but is wholly based, so far as any positive conclusions or recommendations are concerned, on practical personal observation and experience. This section, say the critics, will do its best work by seeking first of all to determine and to set forth: (1) What field is to be covered when education is to be treated as a scientific study, and what are the limits of the field, taking care to give due regard to right ideals of moral and social progress as a primary part of the whole. (2) What methods of investigation are appropriate and what are inappropriate to the study of education. Such are some of the warnings with which we are asked to begin our discus- sions. The critics ask the men of science to remember that they are leaving their accustomed field of purely natural phenomena, and entering a field of inves- tigation which is largely, if not mainly, social, political, religious, moral, and lends itself only in a limited degree to those problems which men whose sphere is natural science are more accustomed to handle, 830 REPORT—1904. These are some of the criticisms which, as men of science, you have to meet, and I may safely leave them to your tender mercies. For myself my attitude in the whole matter must of necessity be a humble one. For many years of my life I was a teacher, but entirely untrained, or rather self-taught, that is to say, relying for my instruction and guidance entirely on my own reading, observation, experience, and practice, I belong to the pre-scientific age of Englishmen engaged in education, I grew up to my profession anyhow, like so many others; and now for some years I have ceased even to teach, and so even as an untrained teacher I am out of date. It is due to this audience and to my subject that I should say thus much. It is my appeal for your kind indulgence. As regards the critics whose views I have endeavoured to express, I may say at once that I do not go with them, because I am profoundly convinced that our ‘nglish education needs the influence of more light and more thought from every quarter, and especially from those who are familiar with scientific methods. ‘Blessed are they that sow beside all waters,’ Moreover, I hail the application of scientific intelligence and scientific methods to this subject, because, looking back, I am profoundly conscious that I should have done my own educational work far less imperfectly if in my youth I had undergone any rational scientific illuminating preparation for it. In such a process I should have lost no personal gift or aptitude that I possessed, and I should have gained some early knowledge and confidence and power which would have saved me much discomfort and anxiety and some mistakes and failures, and would have saved my pupils some loss and possibly some distress. When I turn with these thoughts in my mind and look out over the field of Inelish life I see very strong and valid reasons why our education, its merits, its defects, its methods and results, should be seriously considered here, as also in very different assemblies elsewhere. Above all, the persistently traditional and unscientific spirit that still pervades so much of it from top to bottom, its lack of reasoned reflection, demands our special attention. ‘The want of the idea of science, that is of systematic knowledge,’ said Matthew Arnold, ‘is, as I have said again and again, the capital want at this moment of Inglish education and English life. Our civil organisation (including our educa- tion) still remains what time and chance have made it.’ This was written about thirty-six years ago, and it is, to say the least, a sur- prising thing that in an age of unusually rapid scientific development it should be, in the main, still so true, as it undoubtedly is, of a great part of our English educational system, _ There is the lack of any systematic preparation for the business of teaching which still prevails throughout our middle and upper-class education, although here in Cambridge and in Oxford some excellent pioneer work is being done in the training of teachers. There is the general lack of interest in education which is still so noticeable in a great deal of English society of all grades, the spirit of indifference to it, and even the tendency to depreciate the intellectual life. There is the excessive influence of tradition and routine on our great schools and universities, and in some quarters an inert or suspicious conservatism. There is throughout our middle-class education a state bordering on chaos, a country largely unexplored, a mixture of things good and bad, involving a vast amount of wasted opportunity and undeveloped faculty. Even in elementary education, which has received the largest share of public attention, there is much that needs to be done in a more thoughtful and scientific spirit. ; Party politics have to be eliminated as far as possible, especially ecclesiastical politics. TRANSACTIONS OF SECTION L. 831 The fitness of a great deal of the teaching to the special needs and require- ments of the children has to be considered afresh. The tendency to overlook the interests and the attainments of each individual child has to be checked, The wastefulness of our absurdly truncated system of elementary education stopping abruptly at about twelve years of age and then leaving the children to drift away into au unexplored educational wilderness has to be superseded by some rational system of continuation classes made obligatory. ‘Truly the harvest is a plenteous one for those who desire to uplift our English life by helping forward the best modes of educating the rising generation in a scientific, or, in other words, a wise, intelligent, and large-minded spirit. Much, it is true, has been done in almost every part of the educational field during the last half-century, but not nearly so much as ardent friends of education anticipated forty years ago. I have already quoted some significant words from Mr. Arnold’s illuminating Report on the Schools and Universities of the Continent as he saw them thirty- seven years ago, If that report had been turned to immediate practical account at the time, if some English statesman, like William von Humboldt, had been enabled with a free hand to take up and give effect to Mr. Arnold’s chief suggestions, as Humboldt and his colleagues gave effect to their ideas in Prussia in the years 1808 onwards, the advantage to our country to-day would have been incalculable. In our insular disregard or depreciation of intellectual and scientific forces actually working in other countries, we have undoubtedly wasted some of that time and tide in human affairs which do not wait for cither men or nations. But, putting regrets aside and turning to some of the practical problems that seem to confront us to-day, I venture to put before you for consideration such cursory and unsystematic observations or suggestions as my personal experience has led me to believe to be of practical importance. Jor more than this I have no qualification. In the first place, the growth of crowded city populations and the conditions under which multitudes have for at least two generations been growing up and passing their lives in our great cities have set us face to face with the very serious preliminary problem of physical health. If our physical manhood decays all else is endangered, so that the first business of the educator is to look well to the conditions of a healthy life from infancy upwards. Hence the great educational importance of the petition presented by 14,718 medical practitioners, including the heads of the profession, to the central educa- tional authorities of the United Kingdom. This petition opens with these impressive words :— ‘Having constantly before us the serious physical and moral conditions of degeneracy and disease resulting from the neglect and infraction of the elementary laws of hygiene, we venture to urge the Central Educational Authorities of the United Kingdom (the Board of Nducation of England and Wales, the Scotch Education Department, the Commissioners of National Kducation in Ireland and the Inter- mediate Hducation Board of Ireland) to consider whether it would not be possible to include in the curricula of the Public Elementary Schools, and to encourage in the Secondary ‘Schools, such teaching as may, without developing any tendency to dwell on what is unwholesome, lead all the children to appreciate at their true value healthful bodily conditions as regards cleanliness, pure air, food, drink, &c. In making this request we are well aware that at the present time pupils may receive teaching on the laws of health, by means of subjects almost invariably placed upon the Optional Code. By this method effective instruction is given to a small proportion of the pupils only. ‘This does not appear to us to be adequate. We believe that it should be compulsory and be given at a much earlier age than at present.’ And it concludes as follows :— ‘In many English-speaking countries, definite attempts are being made to train 832 REPORT—1904. the rising generation to appreciate from childhood the nature of those influences which injure physical and mental health. Having regard to the fact that much of the degeneracy, disease, and accident with which medical men are called upon to deal, is directly or indirectly due to the use of alcohol, and that a widespread ignorance prevails concerning not only the nature and properties of this substance but also its effects on the body and the mind, we would urge the Board of Hduca- tion of England and Wales, the Scotch Education Department and the Irish Education Authorities to include in the simple hygienic teaching which we desire, elementary instruction at an early age on the nature and effects of alcohol. We gladly recognise (1) the value of the teaching on this subject given in some schools in Ireland and in a proportion of the schools of Great Britain, by means of reading primers, moral-instruction talks, &c., and (2) the excellence of the occasional temperance lessons provided in certain schools by voluntary organisa- tions ; but until the four Central Educational Authorities of the United Kingdom include this subject as part of the system of National Education, it appears to us that the mass of the pupils must fail as at present to receive that systematic teaching of hygiene and of the nature and effects of alcohol which alone we con- sider adequate to meet the national need. Finally, we would venture to urge the necessity of ensuring that the training of all teachers shall include adequate instruction in these subjects.’ This petition, coming, as it does, with all the weight of the medical profession, as the expression of their experience and convictions, is, to my mind, one of the most important educational documents which have been published in our time, and it can hardly be disregarded without incurring the charge of folly. It may be worth while to set it for a moment side by side with the fashionable cult of athleticism, as bringing into relief our curiously unscientific inconsistency in such matters. On the one hand, in our absent-minded way, we have allowed these genera- tions of town-dwellers, to say nothing of rural villagers, to grow up and live under insanitary conditions which inevitably produce a physically degenerate, enfeebled, and neurotic race of men and women. On the other hand, in the upper and middle classes, we have been sedulously cultivating the taste for physical exercises, outdoor life, athletics, and sport, think- ing nothing of such importance as the development of the body, admiring nothing so much as bodily prowess; carrying all this to such an extent that a natural and wholesome use of athletic exercise has been fostered into a sort of fashionable athleticism, with all its parasitic professionalism, possessing both soul and body. And the result has been curiously significant ; at one end of the scale neglect of the rudiments of sanitation, the loss of the corpus sanum, at the other end the idol worship of athleticism, the depreciation of the intellectual life, and the loss of the mens sana. Are we not then in some danger of drifting into the ways of the Greeks, not in their best days but in their decadence, and of the Romans under the demoralising influences of the Empire ? The Greeks, as we are constantly reminded, in the great period of their creative influence, found nothing so absorbing as the things of the mind; a pre-eminent characteristic of their life was their love of knowledge, their fine curiosity, their enjoyment of the things of the imagination and of thought. It has been noted that what specially conciliated an Athenian voter was the gift of a theatre ticket; and this is a very instructive and significant fact when we bear in mind that the theatre was the great teacher of religion, morals, poetry, patriotism, all in one; that it combined the influences of Westminster Abbey, the plays of Shakespeare, and the heroic achievements of the race; whereas to an ordinary English voter these things are too often only as caviare to the general. Tf so, our education has before it the task of doing what can be done to alter this; and from the Greeks we may derive both lessons and warnings. It was in the days when this decadence was beginning that their excessive admiration of the professional athlete, what we might call their athletic craze, called forth the bitter jibes of Euripides, and his impressive warnings and exhortations to admire TRANSACTIONS OF SECTION L. 833 and to crown with their highest honours, not those who happened to be swiftest of foot or strongest in the wrestling bout, but the man of sound mind, wise and just, who does most to guide others in the more excellent ways, and to uplift the life of his community : GoTis Hyetra TOAEL Kddducra, copper kai Sixatos dv avnp. Here we have a warning by no means inappropriate to our own life and its tendencies. It is, indeed, high time to bring serious and, let us say, scientific thought to bear upon the whole matter. As I look with such thoughts in my mind over those portions of the educa- tional field with which I have been personally familiar, I note various things which seem to call for both consideration and action. Taking first the elementary school, it is to be noted that our system does too little to draw out and stimulate the faculties or to form the tastes of each individual child. Classes are still in many cases far too large. The system of block grants, being inadequately safeguarded or supplemented by inducements to individual children to apply and prepare for certificates of merit or proficiency, however attractive it may be to inspectors and teachers, needs to be very carefully watched in the interests of individual children. The individual child requires the hope and stimulus of some personal recognition or distinction, if its faculties are to be fully roused and its tastes properly cultivated. Moreover, the aid of scientific thought and experience is needed to bring both the subjects and methods of instruction into closer and more vital relationship with the environment of the children and with their practical requirements, and more weight has to be given to specific ethical teaching, that moral and spiritual training day by day, which has for its end the development and strengthening of character, and taste, and issues in conduct, which is the greater part of life. And seeing that it is of the essence of any rational or scientific system to avoid needless waste, it is time that our elementary education should no longer be left in its absurdly truncated condition, which allows a child’s education to be stopped abruptly and finally at or about the age of twelve, when in the nature of things it should be only beginning. As things are at present, just when the parent of the upper classes is anxiously considering what school will be the best for his son, a vast number of the children of the poorer classes are left by the State to drift out into a wilderness where all things are forgotten. In this connection, however, it is due to the Board of Education that we take note of the reminders lately issued in the Introduction to the New Code and the memorandum prefixed to the Regulations for the Training of Teachers. This Introduction to the Code reminds every parent, school-manager, and teacher, very emphatically, that the purpose of the school is to form and strengthen the character and to develop the intelligence of the children, to fit them both practically and intellectually for the work of life, to send them forth with good and healthy tastes and the desire to know, with habits of observation and clear reasoning, with a living interest in great deeds and great men, and some familiarity with, at all events, some portion of the literature and history of their country ; and this being so, the special charge and duty of their teachers is by the spirit of their discipline and of their teaching, by their personal example and influence, to foster in the children, as they grow up in their hands, habits of industry, self-control, endurance, perseverance, courage, to teach them reverence for things and persons good or great, to inspire them with love of duty, love of purity, love of justice and of truth, unselfishness, generosity, public spirit, and so not merely to reach their full development as individuals, but also to become upright and useful members of the community in which they live and worthy sons and daughters of the community to which they belong. Hardly less valuable, as a contribution to education which shall be more thoughtful than hitherto, is the memorandum prefixed to the new Regulations lor the Training of Teachers. 1904. 3H 834 REPORT—1904. I confine myself to one significant quotation from this valuable document : ‘Much of the instruction which is given in all subjects must necessarily be founded upon the statements and the experience of other persons; but every education which deserves to be called complete must include some training of the student in those systematic methods of inquiry which are necessary for any assured advance in knowledge, and which are the most truly educative of all mental processes. ‘Tf this scientific spirit is to find its right expression in the teaching given in elementary schools it must be made to imbue the whole study of the intending teacher during his course in the Training College. It must not he confined to any one branch of the curriculum. It is true that, partly as the result of tradition and partly from other reasons, the term “scientific method” has come to be associated more particularly with the study of natural phenomena. But as a matter of fact, scientific method is of equal importance, and is indeed of ancient application, in the fields of history, literature, language, and philosophy ; and wherever knowledge of these has made advance, it may be discerned that the essential processes of scientific inquiry have been employed. When Matthew Arnold declared in 1868 that the want of the idea of science, of systematic know- ledge, was the capital want of English education and of English life, he was thinking of science as a method and not as a prescribed portion or subject of a curriculum. It cannot be doubted that this want has been seriously prevalent in a large portion of the education and training hitherto provided for elementary school teachers.’ We might, indeed, widen the scope of these observations and say that this want of regard for scientific method has been and is a prevalent want in almost every department and grade of English education. These unaccustomed utterances from Whitehall may very well prove memor- able in the history of English education, as the words of William von Humboldt, quoted by Matthew Arnold, are so memorable in connection with the education of Germany: ‘The thing is not to let the schools and universities go on in a drowsy and impotent routine; the thing is to raise the culture of the nation ever higher and higher by their means.’ Passing from the sphere of the elementary schools to that of secondary educa- tion, we enter on a sphere in which there is much greater need of careful study and the guidance of those who know. Our secondary education has by the Act of 1902 been handed over very largely to county councils, excellent but heterogeneous bodies, and for the most part not only ignorant of educational needs, methods, and possibilities, but quite un- accustomed to their practical consideration—altogether unprepared and untrained for the responsible work now thrown upon them, and hampered by their besetting fear of the ratepayers. Add to these difficulties the prejudice, so common in the ordinary English mind, against what is known as the ‘expert,’ that is, the man who knows trom experience, and is therefore likely to be earnest for improvement, and to believe that wise educational expenditure will repay itself, and you see how manifold are the obstacles in the way of immediate progress. These county authorities need first of all to be themselves instructed and persuaded as to the right subjects for their schools, the co-ordination or proportion of subjects in any scheme to be encouraged, the methods of instruction, the sort of teachers to be appointed, the wisdom of spending public money on good education, as exemplified in other countries, like Germany, Switzerland, the United States, Denmark. Our local authorities feel and recognise that something is needed, but very often they seem to be like children erying in the dark. From lack of educational know- ledge and educational experience they do not always know the difference between the right and the wrong method, or between the good and the bad school. In our rural districts at all events it may be said further that one of our first needs is to persuade the local authorities by some convincing proof that expendi- TRANSACTIONS OF SECTION L. 835 ture on popular education higher than elementary is a wise economy, and that their bread cast on educational waters will come back to them, not after many days, but very soon and in their own homes. Thus my observation has led me to the conclusion that by way of preliminary to progress our new educational authorities need instruction or persuasion as to the importance of a sufficient provision for really good secondary education; and it would greatly expedite progress if the Government could and would offer more liberal secondary education grants to be earned by efficient schools, and initial grants towards buildings and scientific equipment, to be met by contributions from local rates or other local sources, public or private. Many persons and localities would be ready to tax themselves with the view of securing a Treasury grant not available without such taxation. Meanwhile the wheels of our local educational chariots are tarrying on every side so far as higher education, whether general or technical, is concerned. It would also stimulate our local educational authorities if they could be more fully informed as to the practical advantages which have been derived from a practical system of popular education in such a country as the United States of America; and still more if they had set plainly before them the wonderful results derived by a poor country like Denmark during the last twenty-five years, and in the face of every disadvantage, from the system of education initiated by Bishop Grundtvig and taken up by the Government. And the need of our middle classes, especially that of the farmer and trades- men classes, is very pressing. A great deal of the education they receive is given in schools of which the public know very little, whether as regards qualifications of the staff—moral and intellectual—equipment, or methods of teaching, or even sanitary arrangements ; and it is to be feared that much of this education would on inquiry be found to be very poor, if judged by any reasonable standard of modern requirements. When we pass to the class of schools generally spoken of as public schools, those that look to the ancient Universities as the goal of their best pupils, we enter on another very interesting and important field of study. But for the beginning of our investigation we have to go behind these schools to the preparatory schvol, which has now assumed a definite place in secondary education, and therefore calls for serious attention. Some of these schools are very good, so far as the conditions under which they work admit of excellence ; in others there is, it is to be feared, much room for improvement. And such schools are now so largely used by parents that their condition becomes a matter of vital importance, as a boy’s progress and prospects, his moral and intellectual future, are very frequently determined for good or ill by his experience in the preparatory school, by the bent which has there been given to his morals, tastes, ambitions, by the fostering of his intellectual gifts or the failure to foster them. In the course of my own experience I have known many boys whose prospects in life were spoilt by their unhappy beginnings in some preparatory school, and who consequently entered their public school foredoomed to failure. These schools are in most cases private-adventure schools, conducted for private gain. Their staff consists very often of young men untrained for the work of education, and sometimes underpaid. They are subject to no public inspection or examination ; in fact, the general public have no knowledge of their condition. Seeing how grave are the considerations involved, I hold it to be one of the things needed for the general improvement of our secondary education that every private school, of whatever kind, should be liable to public inspection and public report thereon ; that a licence should be required for every such school ; and that the staff and their qualifications, and the remuneration given to each of them, the sanitary condition, suitability, and educational equipment of the premises, should all be considered in connection with the giving or withholding of a licence. As regards the curriculum of the schools preparatory to the public schools, the subjects taught, and the proportion of time allotted to each, it has to be borne in mind that they are nct free agents. In this respect they are dependent on the 3H 2 836 REPORT—1904. requirements of the entrance examination at the public schools which they supply ; just as those schools in their turn are dependent on the requirements of the university to which they send. their pupils. Thus, when we come to confer with the authorities of the public schools, our first inquiry is whether their entrance examination is such as to conduce to the best system of education from infancy upwards. Believing, as [ do, that there is room for improvement, I would ask them to consider and come to a general agreement as to the subjects on which special stress should be laid. What place, for instance, is occupied in the Eton entrance examination by such subjects as English language and literature, English com- position, spelling, handwriting, and reading aloud? What weight is given to elementary drawing, or to an elementary knowledge of natural phenomena, so as to encourage in the preparatory school an interest in the mineral, vegetable, and animal world around us, and to stimulate in early years the habit of observation, and to impress the difference between eyes and no eyes ? Such subjects as these, it is now generally recognised, ought to be given a foremost place and equal weight with the modicum of arithmetic, French, and ancient languages, which have hitherto, as a rule, formed the staple of this entrance examination, and have consequently given an unnatural twist to the earlier education of our boys. As regards the public schools themselves, if we consider them critically— though, on the other hand, I trust, by no means forgetting their many and great excellencies—the points that invite attention would seem to be such as the following :— There is undoubtedly a great deal of waste in these schools owing to the poor teaching of untrained masters, who in some cases cannot even maintain reasonable discipline, and in many more have no real knowledge or mastery of the best methods of teaching their subject, be it linguistic, or historical, or literary, or scientific, and have not acquired that first gift of an efficient teacher, the art of interesting their pupils and drawing out their faculties and their tastes. It would, therefore, be reasonable, as it would certainly be stimulative and advantageous, to require that all masters should be bound to go through some system of well-considered and serious preparation or training for the teacher's work, or at the least a probationary period. It should, I venture to think, be made a rule that no master could be placed on the permanent staff until he was certified and registered as having fully satisfied this requirement and given proof of his efficiency. And here I would venture to point out to existing masters and mistresses in the leading schools how great a service they may do to the cause of good education if they themselves apply to be registered, Seeing the advantages which registration is destined to bring to our secondary education by winnowing out inefficient teachers and otherwise, the higher members of the profession may fairly be expected to give their personal adhesion to it as a part of their duty to their profession. We might almost say to them nodlesse oblige. Again, it must, I fear, be admitted that one of the chief defects in our public school education is still to be found in over-attention to memory work, and in the comparative failure to develop powers of thought, taste, and interest in the things of the mind. And even in the teaching of languages attention has been too exclusively devoted to mere questions of grammar, as if to learn the language were an end in itself, whereas, in the words of Matthew Arnold, ‘the true aim of schools and instruction is to develop the powers of our mind and to give us access to vital knowledge.’ For this end, as he reminds us, the philological or grammatical discipline should be more consciously and systematically combined with the matter to which it is ancillary, the end should be kept in view; whereas nine out of ten of our public-school boys seem never to get through the grammatical vestibule at all; TRANSACTIONS OF SECTION L. 837 and yet we agree that ‘no preliminary discipline should be pressed at the risk of keeping minds from getting at the main matter, a knowledge of themselves and the world.’ This also was written by Mr. Arnold thirty-six years ago, and thoughtful critics are still repeating, and with some reason, that the majority of boys who grow up in our public schools seem hardly to have received an adequate training for many of the higher duties of life. We hear much more than formerly about the public schools being the best training-place for good citizenship. Therefore, say the critics, it is reasonable to inquire how far their educational system, their ideals, their traditions, their fashions, and the pervading spirit of their life fit the mass of their pupils intel- lectually and otherwise for the duties of citizenship, and for grappling in the right spirit with the problems that will confront them. ‘ Any careful observer,’ says one of these writers, himself a loyal public-school man, and intimately acquainted with school life, ‘any careful observer, who has studied the political moods and opinions of the middle classes in this country during the past few years, can hardly have failed to notice two obviously decisive influences : an ignorance of modern history and a want of imagination. For both of these defects the public schools must bear their full share of blame. ‘It may be doubted whether any other nation teaches even its own history so little and so badly.’ The result is that ‘to the average public-school and university man the foreign intelligence in his daily paper is of less interest than the county cricket; and though events of far-reaching importance may be happening almost under his eyes he is in the dark as to their significance.’ ‘ As regards the duties and aims of citizenship in all the various affairs of his own country, political, social, economic, he goes out from his school almost wholly uninstructed by the lessons of history, or by any study of the life and the needs of our own times. Again, as it is urged, the lack of imagination is hardly less dangerous to us than lack of instruction in the lessons of history and the social conditions and needs amongst which we have to live and work. No doubt the gift of imagination is a natural gift,—it cannot be created. But, given the thing in the germ, it can be stimulated and developed, or starved, stunted, or even crushed out. No system of education that neglects it is even safe. For, without it, principle becomes bigotry and zeal persecution. It is conscientiousness divorced from imagination that produces Robespierres. Now, it is precisely here that we should expect the public schools to be most helpful, for it is through literature that the faculty is most obviously cultivated, and they all profess to give some- thing of a literary training. But though the intention is excellent the performance is often terribly meagre.’ Whatever may be thought of such criticisms as these, which come from within our public-school life, it is, I imagine, generally agreed by those who know both our national needs and the work and influence of our public schools, that there is much room for improvement in regard to methods of teaching, the cultivation of intellectual interests and tastes, and the stimulating habits of thought in the majority of their pupils. In close connection with these considerations there are two questions of practical importance which deserve a prominent place in any study of our public-school education. The first of these is whether it is good for all boys alike to continue their life at school, especially at a boarding school, up to the age of eighteen or nineteen ; and the other is whether more encouragement and pains should not be given to developing the best type of day school, or, to put it somewhat differently, whether the barrack life of the boarding school has not, through fashionable drift and class prejudice, become too predominant a part of our English education at the expense of the home life with all its finer educational influences. As regards the first of these questions, it will be remembered that Dr. Arnold considered it a matter of vital importance to expedite the growth of a boy from the childish age to that of a man. In other words, the boy should not be left to grow through the years of critical change from fourteen to nineteen without special regard to his growth in 838 REPORT—1904, intellectual taste and moral purpose and thoughtfulness. His education during these critical years should be such as to rouse in him the higher ambitions of a responsible manhood. Does, then, the actual life of a public school really conduce to this early development in the majority of cases P My own experience has led me to the conclusion that it cannot be confidently held to do so. The boys in any of our public schools may be said to fall into two classes— those who in due course reach the sixth form, and during their progress through lower forms have an ambition to reach it; and, on the other hand, a numerous class who do not expect to rise to the sixth, don’t care about it, and never exert themselves to reach it. For the first class, I doubt if any more effective preparation for life has been devised than that of our best English schools; but the case of the second class is somewhat different. Many of these come to the end of their school time with their intellectual facul- ties and tastes and their sense of responsibility as men to a great extent undeveloped. From sixteen to eighteen or nineteen their thoughts, interests, and ambitions have been largely centred in their games and their out-of-school life, with the natural results that their strongest tastes in after life are for amusement and sport. 3 Some of these boys, after loitering at school to the age of eighteen or nineteen, go to the University as passmen, some begin their preparation for the work of a doctor or a solicitor, and many go straight from school into City life as men of business ; and nearly all of them suffer from the lack of intellectual and moral stimulus during these later years of their school life. Now many of these boys could without difficulty pass the entrance examina- tion to the University at sixteen or seventeen, if well and carefully taught ; and 1 have long held the view that such boys would greatly benefit by going to Oxford or Cambridge at the age of seventeen, or even sixteen, if suitable arrangements could be made. It was with this conviction in my mind that I published a scheme showing how this experiment might be tried about twenty years ago. The interval has confirmed me in the opinion that it would be a distinct gain to many boys to take advantage of such a scheme if made available. They would go out into the world from the University at the age of twenty far better equipped and prepared for life, both as regards knowledge and interests, tastes, and character, than by going straight from school at nineteen. And looking to my own University of Oxford, I see no reason why such younger students should not be safely received. There are at least three Colleges in that University which would find it easy to adapt their arrangements so as to secure this. Each of these Colleges has a hall in connection with it, well suited for the residence of a college tutor who might have special charge of these younger students, residing in the hall during their first year with somewhat stricter rules as to ordinary discipline and liberty, but in all other respects exactly on a par with the senior undergraduate members of the College. On the subject of the day school, as compared with the boarding school, a subject which has not hitherto received the attention it deserves, I may venture to repeat here what in substance I have said on other occasions. Many parents are so situated that they have no choice in the matter; but ta the educational inquirer it is a question of much interest and importance. The boarding school is admitted to excel in turning out strong, self-reliant, sociable, practical men of affairs, men who have learnt by early experience not to think or make too much of small injustices, to rough it, if need be, with equani- mity and cheerfulness, and to count it a man’s part to endure hardness in a manly spirit. It is a fine type of character which is thus produced, at its best; but the best is not always seen in the result, and the system too often produces an undue deference to public opinion, a spirit of moral compromise, and a loss of TRANSACTIONS OF SECTION L. 839 moral enthusiasm. The human soul in its finer parts is a very sensitive thing, and I do not think the barrack life of an average boarding school is always the most favourable for its healthy growth. As I look back over the school days of my own pupils I feel that those of them had, on the whole, the best education who grew up as day boys in good homes at Clifton College. There they enjoyed all the advantages of the cultivated home, which I need not here enumerate, and at the same time, through the arrangements we made for them, all the best elements in the life of a great boarding school. In the upper school of 500 boys, we had about 160 day boys living at easy distances from the school. These boys were divided into two houses—North Town and South ‘Town—about eighty boys in each house, and they were treated for school purposes just as if they were living together in a boarding house. They were under the same rules as boarders in regard to hours of locking up, or the bounds beyond which they might not go without a note from their parents giving express leave. Their names were printed in a house list, a master was appointed as their tutor, whose duty it was to look to their educational needs and progress, to their reports and conduct, just as if they had been boarders and he their house master. Each house had its own room or library on the College premises, with books of reference, and so forth, for spare hours, and took its part with the boarding houses, and held its own in all school affairs, games, and other competitions. And my experience of this system compared with others has led me to the conclusion that the form of education which may on the whole claim to be the best is that of a well-organised day school, in which it is clearly understood to be the duty of the masters to give their life to the boys in school and out of school, just as if they were at a boarding school, and in which the boys are distributed into houses for school purposes, just asif they were living in a boarding house. Under such a system they get the best of both worlds, home and school. From the public school we pass naturally to the Universities, and the first question that meets us is the influence they exercise on school education, through their requirements on admission or matriculation and the bestowal of their endowments and other prizes. On this part of my subject I have seen no reason to alter or modify what I said at Glasgow three years ago, and therefore I merely enumerate and emphasise the suggestions which I put forward on that occasion for the improvement of educa- tion both at school and college. I hold that it would be equivalent to pouring a new stream of intellectual influence through our secondary education if Oxford and Cambridge were to agree on some such requirements as the following :— 1. In the matriculation examination (a) candidates to be free to offer some adequate equivalent in place of Greek. (6) An elementary knowledge of some branch of natural science, and of one modern language to be required of all candidates. (c) A knowledge of some period of English history and literature also to be required of every candidate, and ability to write English to be tested. (d) The examination in Latin and any other foreign language to include questions on the subject-matter of any prepared books offered, some ques- tions oe history and literature, and translation of easy passages not previously repared. Y (e) Marks of distinction should be given for work of superior merit in any branch of this examination, as, indeed, of every pass examination conducted by the University. Candidates should not be excluded from residence before passing this examina- tion, nor should they be required to pass in all subjects at the same time; but the completion of this examination would be the necessary preliminary to entry for any other examination required for a degree. 2. On the question of endowments and the minimising of waste in the adminis- 840 REPORT—1904, tration of them there is much to be said, and I would suggest for considera- tion: (1) That, as a rule, open scholarships and exhibitions might be reduced to free tuition, free rooms, and free dinners in hall, or thereabouts. (2) That every holder of an open scholarship or exhibition, whose cireumstances were such that he needed augmentation, should, on application, receive such augmentation as the College authorities considered sufficient. (3) That care should be taken to discourage premature specialisation at school. For this end it should be required that no scholar should enjoy the emoluments of his scholarship until he had passed the matriculation examination described above; and a fair proportion of scholarships should be awarded for excellence in a combination of subjects. The Universities might also do good service in the way of stimulating secondary education, if some small proportion of their entrance scholarships were distributed over the country as county scholarships, on condition that the county contributed an equal amount in every case. In this way some equivalent for the endowments, so cynically confiscated by the Education Act of 1902, might be recovered and used for the benefit of poor and meritorious students. Other reforms, which would, as I believe, be productive of valuable results, are the requiring from every candidate for a degree a knowledge of some portion of our own literature and history, and the encouragement of intellectual interests and ambitions by abolishing all purely pass examinations. A pass examination, in which the candidates are invited simply to aim at a minimum of knowledge or attainment, is hardly worthy of a university. The opportunity of winning some mark of distinction in this or that portion of what is now a pass examination would frequently rouse some latent ambition in an idle man, and transform the whole spirit of his work. Thus a modest reform of this kind might be of great practical benefit to the nation by helping in its degree to intellectualise the life of a great many of our young men, and draw out unsuspected interests, faculties, and tastes. My observations have run to such a length that I must, perforce, conclude, leaving untouched other aspects of University education and training, whether in the old or the new universities, as also the whole subject of the higher education of women, and its proper relationship to traditional systems of instruction and study, framed and intended for men. And my last word is a word of practical inquiry. How is this Section to be made of most value as an instrument of educational progress ? I leave the answer to this question to those more competent to give it, merely putting on record my own feeling that it may do a valuable service and supply one of our special educational needs, if the working committee of the Section, enlarged by the addition of various representative persons, makes it a duty to collect and publish year by year in succession a series of papers, the best that can be written by recognised authorities, on the chief branches of our English education, dwelling on its immediate and pressing needs, and how best to supply them. To do this the Committee should set to work systematically, commencing in October with monthly meetings, and formulating, without delay, the scheme or series of papers to be prepared and presented to the next meeting of the Association. The following Papers were read :— 1. The Present Hducational Position of Logic and Psychology. By Miss E, E. C. Jonus. _ There are several reasons for paying special attention at present to the teach- ing of logic and psychology : (a) Some knowledge of these subjects is part of the qualification for getting on to the new Teachers’ Register, 4 TRANSACTIONS OF SECTION L. 841 (6) Secondary teachers are now called upon to undergo training, and some logic and psychology are required for the teachers’ training examinations. (c) There is a widespread movement towards bringing the standard of religious knowledge up to the level ordinarily required in other departments. (d) There are signs of a widening interest in philosophical questions. It is very necessary that those who take up logic and psychology as a stepping- stone to the profession of teaching should give to those subjects serious and well-directed study, and should have genuine interest in them and some grasp of their scope and meaning. It is likewise desirable that students of religious doctrine, or of the great questions of philosophy, should bring to their study an equipment of logical method and psychological knowledge. At the same time, it will not be disputed that at present these requirements are not, and perhaps hardly can be, adequately met. My aim here is briefly to draw attention to this state of things—to the facts that, on the one hand, from various causes, logical and psychological studies hold a position of great and growing importance in English thought and educa- tion, while, on the other hand, to some extent at least, the quality, quantity, and organisation of the instruction supplied leaves much to be desired ; and to point out that, consequently, the practical treatment of these subjects calls for special recognition and careful attention from educationists. 2. Comparison of the Intellectual Power of the Two Sexes. by Dr. J. DE Korésy. The material of the following statistics is drawn from observations made during the last twenty-seven years in the schools of Buda Pest, where, since 1873, a special report on the progress of each pupil has to be sent to the author’s office. These individual reports (amounting latterly to 60,000 per annum) represent together 808,350 cases; they relate at first to the elementary schools (ages six to twelve years) only ; later they include the higher elementary schools (‘ citizen schools,’ ten to sixteen years), and in the last years the grammar schools also. (1) General Progress in the Elementary Schools ; twenty-seven years’ Observations. The test applied is the number of children who have to repeat their year’s work instead of passing on to the next standard. Of 412,758 boys and 350,582 girls, 69,422 boys (16°8 per cent.) and 54,391 girls (15:8 per cent.) repeated their work. These figures show a slight superiority on the part of the girls. If we observe the divergence standard by standard, we see that the boys and girls are nearly level at first, but that the advantage of the latter increases with age, Percentage repeating the Number of Girls to Standard cae Work 7 100 Boys Boys Girls 16 22°5 22:2 99 II. | 16°6 15:4 . 93 Iii. 16°3 13°8 84 IV. 12:2 9°2 75 v. | 9°8 56 BT VI. | 4-7 27 58 (2) Special Progress in the Fourth Standard of the Elementary Schools (172,477 cases). The frequency of the best marks (‘very good’ and ‘ good’) was— Boys Girls In Mother-tongue . . 23°6 per cent. 32:3 per cent. In Arithmetic ; . 28:0 “ a73 gy In Geography 3 s 22 RP), 36:9 yy 842 REPORT—1904. (8) Progress in the Higher Elementary Schools. (a) Of 14,201 boys and 20,588 girls, 840 boys (6-2 per cent.) and 450 girls (2:2 per cent.) had to repeat their work. (6) By standards :— Percentage repeating their Number of Girls to Bede Year’s Work 100 Boys Boys Girls I. 11:0 a1 28 1B 4°8 2°7 57 II. 4:6 18 35 TV. 30 0°6 20 Average ‘ : 6:2 gb! 22 35 (c) Frequency of the best marks in the Fourth Standard :— Boys Girls In Mother-tongue . . 16°7 per cent. 44-6 per cent. » German 5 - = 412-2 + BO2 yas, », History 5 ; .. 20°9 + ATS » Arithmetic . : ANOS 2% 3 35:3, The superiority of girls is really puzzling here, especially in arithmetic. In this division, however, there are difficulties, for the female group is more selected than the male; for the boys who follow the higher elementary classes, instead of entering secondary schools, are from a class less gifted than the ordinary, while the contrary is the case with the girls. This disturbing cause exercises greater influence in the grammar school, as only the most talented and most ambitious girls enter the Latin schools. Besides this the system of teaching and examination is more favourable to the girls.!_ Thus the elementary schools furnish the most reliable measure, especially where their attendance is, as in Hungary, compulsory. Conclusion. The results are all in favour of the female sex, but relate only to children. Since not only in sciences, but also in poetry and (with exception of the stage) in arts, the great work of human progress has been accomplished by the male sex, one is obliged to suppose that with the age of ripening the feminine intellect develops itself more slowly than the masculine, 3. The Teaching of Experimental Science in the Secondary Schools of Ireland. By the Right Rev. Gzratp Motuoy, D.D., D.Sc, The education given in the secondary schools of Ireland is controlled and guided, in large measure, by a body of Commissioners known as the Intermediate Education Board. This Board was constituted by Act of Parliament in 1878, and administers a fund of about 90,000. a year. For many years this fund was distributed on the results of examination alone; and the programme of the Board was not favourable to the study of experimental science in the schools. But in the year 1900 the Board was empowered, under a new Act, to supplement examina- tion by inspection, and, in the distribution of grants, takes account of the results of inspection as well as the results of examination. ‘ At the examination, which takes place at the end of the grammar school course, there were rejected (1900-03) 494 young men—22°4 per cent. 22 girls —10°3 4 TRANSACTIONS OF SECTION L. 845 This change led to an important reform, in which the Board has been greatly aided by the co-operation of the Department of Agriculture and Technical Instruc- tion, To this Department was transferred, in 1901, the administration of the Parliamentary vote for science and art in Ireland, which had been previously administered from South Kensington. As the Intermediate Board and the Department were dealing with practically the same schools, it was agreed to adopt a common programme in science subjects, and to carry out a common system of examination and inspection. The programme adopted under this arrangement, which includes two years of a preliminary course and two years more of advanced teaching in various special subjects, is fully set out in the paper. It involved, in effect, an entirely new departure in the teaching of experimental science in Ireland; substituting, to a large extent, practical work in the laboratory for the study of books, and testing the efficiency of schools by actual inspection of the work done, as well as by written papers. One of the chief difficulties encountered in the introduction of this new system was to provide a supply of competent teachers. This task was taken up by the Department, as the training of teachers does not fall within the functions of the Intermediate Board. The plan adopted was twofold. First, summer classes for teachers were held at various centres; and teachers who attend these classes, and afterwards satisfy the examiners, obtain provisional certificates to teach the course in which they have been so trained. This is only a temporary expedient, intended to meet the urgent need of the moment. But as the permanent element in their scheme the Department propose to grant the ‘Irish Teacher's Science Certificate’ to all students who pass through a three years’ course, prescribed for the purpose, in the Royal College of Science, Dublin. They will also recognise as qualitied teachers students who have followed a similar course in any university or technical college, and who haye obtained the corre- sponding degree or diploma. The next difficulty was the want of laboratories and laboratory equipment. This difficulty has been met by the cordial and very remarkable co-operation of the schools and the local authorities with the efforts made by the Department and the Intermediate Education Board. The Department designed plans to suit the circumstances of each particular school, and prescribed the necessary apparatus to be provided. Then loans were advanced by the Intermediate Board, and grants were made by the Department to help the schools to meet the cost of building and equipment, ‘The county and borough councils also lent their aid in many cases, by allocating to the same purpose a portion of the funds placed at their disposal for technical education. The result has been that 214 schools are now provided with all that is needed for the two years’ instruction of the preliminary course; and many of these are further provided with the equipment prescribed for one or more years of the special courses, The new system now embraces all the secondary schools of the country, about 250 in number, with a school population of about 20,000 pupils. Of these 20,000 pupils, somewhat more than 9,000 were under instruction in the preliminary course during the school year 1903-4, and about 1,500 in one or more of the special subjects. This represents a very satisfactory progress, in what is practically a new line of study, within the short period of four years. It is encouraging to hear that the subject of experimental science, taught on the new lines, is popular both with teachers and pupils. I am informed that a large number of pupils have developed quite a remarkable taste for laboratory work, and that many who had been regarded as dull and inert in other studies, have shown themselves alert and bright in this new field of nature knowledge that has been opened to them. 844, REPORT—1904. FRIDAY, AUGUST 19. The following Papers and Report were read :— 1. Specialisation in Science Teaching in Secondary Schools. By J. H. Lronarp, B.Sc. While it is admitted that too early a specialisation is an evil, indications are not wanting which show that the efficiency of science teaching in schools is itself threatened with a particular kind of specialism. A sketch was given of the broad lines which school science teaching may be supposed to follow, emphasis being laid upon its practical nature and the mental training involved. In contrast to this, certain cases were cited where mechanics is studied in some detail before any attention is paid to such branches of physics as optics, electricity, and magnetism. In other cases, again, experiments in titration are performed before sufficient progress has been made in elementary chemistry. Botany and physiography meet with no recognition in such schools. It was maintained that such instances as these exemplify what may be termed ‘specialisation’ for want of a better word, ze, one study is accorded undue prominence, It was shown that the effects of such ‘ specialism’ are bad, since the school time is not proportionately allotted—e.., the omission of botany—while the effect on the scholars themselves, so far as can be judged, is to weary them instead of maintaining their interest. 2. Short Description of ‘ Realistic Arithmetic.’ By Lieut.-Colonel G. Macxintay, late R.A. This apparatus consists of a series of blocks of different sizes, each approxi- mately of the proportions of an ordinary brick, threaded on cords for convenience of manipulation. The exact proportions of each block are such that ten of one size placed together exactly make the figure of one of the next larger blocks, and all the blocks are similar figures. No other proportions except those adopted in ‘Realistic Arithmetic’ (in which the lengths of edges always increase by the factor 1889. {Harrison, J.C. Oxford House, Castle-road, Scarborough. 1858. *Harrison, J. Park, M.A. 22 Connaught-street, Hyde Park, W. 1892. tHarrison, JoHN (Local Sec. 1892). Rockville, Napier-road, Edinburgh. 1870. {HARRIson, yee F.R.C.S. (Local See. 1870). 6 Lower Berkeley-street, Portman-square, W. 46 LIST OF MEMBERS. Year of Election. 1853. 1892. 1895. 1901. 1886. 1885. 1876. 1905. 1875. 1893. 1897. 1871 1896. 1886. 1887. 1897. 1898. 1885. 1862. 1884. 1893. 1903. 1903. 1904. 1875. 1903. 1889. 1903. 1893. 1904. 1904. 1887. 1872. 1864. 1897. 1889. 1887. 1890. 1861. 1885. 1891. 1900. 1908. 1894. 1896. 1896. 1873. 1898, tHarrison, Robert. 386 George-street, Hull. tHarrison, Rey. S. N. Ramsey, Isle of Man. tHarrison, Thomas. 48 High-street, Ipswich. *Harrison, W. E. 15 Lansdowne-road, Handsworth, Staffordshire. {Harrison, W. Jerome, F.G.S. Board School, Icknield-street, Bir- mingham, tHart, Colonel C. J. (Local Sec. 1886.) Highfield Gate, Edgbaston, Birmingham. *Hart, Thomas. Brooklands, Blackburn. *Hart, Thomas Clifford. Brooklands, Blackburn. tHart, W. E. Kilderry, near Londonderry. *Harrianp, E. Srpney, F.S.A. Highgarth, Gloucester. tHartley, E.G.S. Wheaton Astley Hall, Stafford. *Hartiey, Water Nos, D.Sc., F.R.S., F.R.S.E., F.C.S. (Pres. B, 1903), Professor of Chemistry in the Royal College of Science, Dublin. 386 Waterloo-road, Dublin. {Hartley, W. P., J.P. Aintree, Liverpool. *Hartoa, Professor M. M., D.Sc. Queen’s College, Cork. t{Hartoe, P.J., B.Sc. University of London, South Kensington, S. W. tHarvey, Arthur. Rosedale, Toronto, Canada. tHarvey, Eddie. 10 The Paragon, Clifton, Bristol. § Harvie-Brown, J. A. Dunipace, Larbert, N.B. *Harwood, John. Woodside Mills, Bolton-le-Moors. {Haslam, Rev. George, M.A. Trinity College, Toronto, Canada. §Haslam, Lewis. 44 Evelyn-gardens, 8.W. *Hastie, Miss J. A. Care of Messrs. Street & Co., 30 Cornhill, I..C, §Hastie, William. 20 Elswick-row, Newcastle-on-Tyne. §Hastings,G. 15 Oak-lane, Bradford, Yorkshire. *Hastines, G. W. (Pres. F,1880.) Chapel House, Chipping Norton. §Hastings, W.G. W. Chapel House, Chipping Norton. {Hatch, F. H., Ph.D., F.G.S. 28 Jermyn-street, S.W. {Hathaway, Herbert G. 45 High-street, Bridgnorth, Salop. tHatton, John L. 8. People’s Palace, Mile End-road, E. *Haughton, W. T. H. The Highlands, Great Barford, St. Neots. §Havyilland, Hugh de. Eton College, Windsor. *Hawkins, William. Earlston House, Broughton Park, Manchester. *Hawkshaw, Henry Paul. 58 Jermyn-street, St. James’s, S.W. *HawksHaw, JoHN CrarxkeE, M.A., M.Inst.C.E., F.G.S. (Council 1881-87.) 22 Down-street, W., and 33 Great George- street, S. W. §Hawxstey, Cuartes, M.Inst.C.E. (Pres. G, 1903; Council, 1902— .) 30 Great George-street, S.W. tHaworth, George C. Ordsal, Salford. *Haworth, Jesse. Woodside, Bowdon, Cheshire. {Hawtin, J. N. Sturdie House, Roundhay-road, Leeds. *Hay, Admiral the Right Hon. Sir Joun C. D., Bart., G.C.B., D.C.L., F.R.S. 108 St. George’s-square, S. W. *Haycrarr, JoHN Berry, M.D., B.Se., F.R.S.E., Professor of Physiology in University College, Cardiff. . tHayde, Rev. J. St. Peter's, Cardiff. - §Hayden, H. H., B.A., F.G.S. Geological Survey, Calcutta, India. *Haydock, Arthur. 197 Preston New-road, Blackburn. {tHayes, Edward Harold. 5 Rawlinson-road, Oxford. tHayes, Rev. F.C. The Rectory, Raheny, Dublin. tHayes, William. Fernyhurst, Rathgar, Dublin. *Hayes, Rey. William A., M.A. Dromore, Co. Down, Ireland. tHayman, C. A. Kingston Villa, Richmond Hill, Clifton, Bristol, LIST OF MEMBERS. 47 Bisetion. 1903. {Hayward Joseph William, M.Se. 29 Bishop’s-mansions, Fulham, 1896, “Beyzond Lieut.-Colonel A. G. Rearsby, Merrilocks-road, Blundell- sands. 1879. *Hazelhurst, George S. The Grange, Roclferry. 1883. tHeadley, Frederick Halcombe. Manor House, Petersham, S.W. 1883. tHeadley, Mrs. Marian. Manor House, Petersham, S.W. 1883. {Headley, Rev. Tanfield George. Manor House, Petersham, S.W. 1883. {Heape, Charles. Tovrak, Oxton, Cheshire. 1883. {Heape, Joseph R. Glebe House, Rochdale. 1882. *Heape, Walter, M.A. Heyroun, Chaucer-road, Cambridge. 1877. tHearder, Henry Pollington. Westwell-street, Plymouth. 1877. tHearder, William Keep. 195 Union-street, Plymouth. 1898. sient. ome Arthur J., B.A., F.G.S. 71 St. Michael’s-hill, Redland, ristol. 1902. {Heath, J. W. Royal Institution, Albemarle-street, W. 1898. {Hratu, R.S., M.A., D.Sc. The University, Birmingham. 1884, {Heath, Thomas, B.A. Royal Observatory, Edinburgh. 1902. §Heathorn, Captain T. B., R.A. 10 Wilton-place, Knightsbridge,S.W. 1883. tHeaton, Charles. Marlborough House, Hesketh Park, Southport. 1892. *Heaton, Witt1am H., M.A. (Local Sec. 1893), Professor of Physics in University College, Nottingham. 1889, *Heaviside, Arthur West. 7 Grafton-road, Whitley, Newcastle-upon- Tyne. 1888. *Heawood, Edward, M.A. 38 Underhill-road, Lordship-lane, S.E. 1888. *Heawood, Percy J., Lecturer in Mathematics in Durham University. 41 Old Elvet, Durham. 1855. tHecror, Sir James, K.C.M.G., M.D., F.R.S., F.G.S., Director of the Geological Survey of New Zealand. Wellington, New Zealand. 1887. *Hepees, Kintivewortu, M.Inst.C.E. 10 Cranley-place, South Kensington, S.W. 1881. *Herz-Suaw, H. 8., LL.D., F.R.S., M.Inst.C.E. 27 Ullet-road, Liverpool. 1901. *Heller, W. M., B.Sc. 18 Belgrave-square, Monkstown, Co. Dublin. 1887. §Hembry, Frederick William, F.R.M.S, Langford, Sidcup, Kent. 1897. §Hemming, G. W., K.C. 2 Earl’s Court-square, 8. W. 1899, §Hemsalech, G. A., D.Sc. The Owens College, Manchester. 1873. *Henderson, A. L. Westmoor Hall, Brimsdown, Middlesex. 1883, {Henderson, Mrs. A. L. Westmoor Hall, Brimsdown, Middlesex. 1901. 1891. 1892. 1880. 1896. 1904, 1873. 1892. 1855. 1890. 1890. tHenderson, Rev. Andrew, LL.D. Castle Head, Paisley. *Henverson, G. G., D.Sc., M.A., F.LC., Professor of Chemistry in the Glasgow and West of Scotland Technical College. 204 George-street, Glasgow. t Henderson, John. 3 St. Catherine-place, Grange, Edinburgh. *Henderson, Rear-Adwiral W. H.,R.N. Royal Dockyard, Devonport. { Henderson, W. Saville, B.Sc. Beech Hill, Fairfield, Liverpool, *Hendrick, James. Marischal College, Aberdeen. *Hewrici, Oraus M. F. E., Ph.D., F.R.S. (Pres. A, 1883; Council, 1883-89), Professor of Mechanics and Mathematics in the City and Guilds of London Institute, Central Institution, Exhibition- road, S.W. 34 Clarendon-road, Notting Hill, W. t{Hepsurn, Davin, M.D., F.R.S.E., Professor of Anatomy in Uni- versity College, Cardiff. *Hepbum, J. Gotch, LL.B, F.C.S. Oakfield Cottage, Dartford Heath, Kent. tHepper, J. 43 Cardigan-road, Headingley, Leeds, tHepworth, Joseph. 25 Wellington-street, Leeds. 48 LIST OF MEMBERS. _ Year of Election. 1904, 1892. 1902. 1887. 1893. 1875. 1891. 1871. 1874. 1900. 1900. 1903. 1895. 1894. 1894. 1896. 1908. 1903. 1898, 1883. 1882. 18838. 1866. 1897, 1901. 1879. 1886. 1887. 1888. 1898. 1877. 1886. 1884. 1887. 1864, 1891. 1885. 1903. 1881. §Hepworth, Commander M. W. C., R.N.R., C.B. Meteorological Office, Victoria-street, S.W. *HeRBERTSON, ANDREW J., Ph.D., F.R.S.E., F.R.G.S. 4 Broad- street, Oxford. {Herdman, G. W., B.Sc., Assoc.M.Inst.C.E. 2 Fyfield-road, Enfield. *HEeRDMAN, WILLIAM A., D.Sc., F.R.S., F.R.S.E., F.L.S. (GEnerat Srecrerary, 1903— ; Pres. D, 1895; Council, 1894-1900; Local Sec. 1896), Professor of Natural History in the University of Liverpool. Croxteth Lodge, Sefton Park, Liverpool. *Herdman, Mrs, Croxteth Lodge, Sefton Park, Liverpool. {HereErorD, The Right Rev. Jonn Prrcrtvat, D.D., LL.D., Lord Bishop of. (Pres. L, 1904.) The Palace, Hereford. tHern, S. South Chiff, Marine Parade, Penarth. *HERSCHEL, ALEXANDER S., M.A., D.C.L., F.R.S., F.R.A.S., Honorary Professor of Physics and Experimental Philosophy in the Uni- versity of Durham. Observatory House, Slough, Bucks. §HerscHrz, Colonel Jonny, R.E., F.R.S., F.R.A.S. Observatory House, Slough, Bucks. : *Herschel, J.C. W. Littlemore, Oxford. tHerschel, Sir W. J., Bart. Littlemore, Oxford. *HesxerH, Cuartes H. B., M.A. The Rookery, North Meols, Southport. §Hesketh, James. Scarisbrick Avenue-buildings, 107 Lord-street, Southport. {Hewetson, G. H. (Local Sec. 1896.) 89 Henley-road, Ipswich. tHewins, W. A.S., M.A., F.S.S., Professor of Political Economy in King’s College, Strand, W.C. §Hewitt, David Basil. Oakleigh, Northwich, Cheshire. tHewitt, E.G. W. 87 Princess-road, Moss Side, Manchester. tHewitt, John Theodore, M.A., D.Se., Ph.D. 8 Montpellier-road, Twickenham. tHewitt, Thomas P. Eccleston Park, Prescot, Lancashire. tHewson, Thomas. Junior Constitutional Club, Piccadilly, W. *Heycock, Ouartes T., M.A., F.R.S. King’s College, Cambridge. tHeyes, Rev. John Frederick, M.A., F.R.G.S8. 27 Arkwright-street, Bolton. *Heymann, Albert. West Bridgford, Nottinghamshire. tHeys, Thomas. 180 King-street West, Toronto, Canada. *Heys, Z. John. Stonehouse, Barrhead, N.B. tHeywood, Sir A. Percival, Bart. Duffield Bank, Derby. {Hrywoop, Henry, J.P. Witla Court, near Cardiff. tHeywood, Robert. Mayfield, Victoria Park, Manchester. {Hichens, James Harvey, M.A. The School House, Wolverhampton. tHicks, Henry B. 44 Pembroke-road, Clifton, Bristol. §Hicks, Professor W. M., M.A., D.Sc., F.R.S. (Pres. A, 1895), Principal of University College, Sheffield. Dunheved, Endcliffe- crescent, Sheffield. tHicks, Mrs. W. M. Dunheved, Endcliffe-crescent, Sheffield. tHickson, Joseph. 272 Mountain-street, Montreal, Canada. *Hicxson, Sypney J., M.A., D.Sc., F.R.S. (Pres. D, 1903), Professor of Zoology in Victoria University, Manchester. *Hiern, W. P., M.A., F.R.S. The Castle, Barnstaple. {Hices, Henry, LL.B., F.S.S. (Pres. F, 1899; Council 1904.) H.M. Treasury, Whitehall, 8. W. *Hitt, Avexanper, M.A., M.D. Downing College, Cambridge. *Hill, Arthur W. King’s College, Cambridge. “Hitz, Rey. Epwin,M.A. The Rectory, Cockfield, Bury St. Edmunds. LIST OF MEMBERS, 49 Year of Election. 1887. {Hill,G. H., M.Inst.C.f., F.G.8. Albert-chambers, Albert-square, Manchester. 1884. {Hill, Rev. James Edgar, M.A., B.D. 2488 St. Catherine-street, Montreal, Canada. 1886. {Hroz, M. J. M., M.A., D.Se., F’.R.S., Professor of Pure Mathematics in University College, W.C. 1885. *Hill, Sidney. Langford House, Langford, Bristol. 1898, *Hill, Thomas Sidney. Langford House, Langford, Bristol. 1888. {Hill, William. Hitchin, Herts. 1876. THill, William HI. Barlanark, Shettleston, N.B. 1885, *HintuHousr, WittaM, M.A., I’.L.8., Professor of Botany in the University of Birmingham, 16 Duchess-road, Edebaston, Bir- mincham. 1886. §Hillier, Rev. E. J. Cardington Vicarage, near Bedford. 1887. {Hilton, Edwin. Oak Bank, Fallowtield, Manchester. 1903. “Hilton, Harold. Bryn Teg-terrace, Bangor, North Wales. 1903. §Hinp, Dr. WHertton, F.G.S. Roxeth House, Stoke-on-Trent. 1870. {Uinpz, G. J., Ph.D., F.RS., F.G.8. Ivythorn, Avondale-road, South Croydon, Surrey. 1883. *Hindle, James Henry. 8 Cobham-street, Accrington. 1888. *Hindmarsh, William Thomas, F.L.S. Alnbank, Alnwick. 1898. §Hinds, Henry. 57 Queen-street, Ramsgate. 1886. {Hingley, Sir Benjamin, Bart. Hatherton Lodge, Cradley, Wor- cestershire. 1881. {Hingston, J.T. Clifton, York. 1884. {Hineston, Sir WitttAmM Hates, M.D., D.C.L. 37 Union-avenue, Montreal, Canada. 1900. §Hinks, Arthur R., M.A. 10 ILuntingdon-road, Cambridge. 1903. *Hinmers, Edward. Glentwood, South Down-drive, Hale, Cheshire. 1884. {Hirschfilder,C. A. Toronto, Canada. 1899, §Hobday, Henry. Hazelwood, Crabble Hill, Dover. 1887, *Hobson, Bernard, M.Sc., F.G.S. Thornton, Didsbury, near Man- chester. 1883. {Hobson, Mrs. Carey. 5 Beaumont-crescent, West Kensington, W. 1883. {Hobson, Rev. E. W. 55 Albert-road, Southport. 1904. § Hobson, Ernest William, Sc.D., F.R.S, The Gables, Mount Pleasant, Cambridge. 1877. {Hodge, Rev. John Mackey, M.A. 58 Tavistock-place, Plymouth, 1876. {Ifodges, Frederick W. Queen’s College, Belfast. 1863. *lopexsn, Tomas, B.A.,D.C.L. Benwell Dene, Newcastle-upon-Tyne. 1887. *Hodgkinson, Alexander, M.B., B.Sc., Lecturer on Laryngology at Owens College, Manchester. 18 St. John-street, Manchester. 1896. {Hodgkinson, Arnold, 22 Park-road, Southport. 1880. §Hodekinson, W. R. Eaton, Ph.D., F.RS.E., F.G.8S, Professor of Chemistry and Physics in the Royal Artillery College, Woolwich. 18 Glenluce-road, Blackheath, S.1. 1884. {Hodgezon, Jonathan. Montreal, Canada. 1862. {Hodgson It. W. 7 Sandhill, Nowcastle-upon-Tyne. 1898. tHodgson, T. V. Municipal Musenm and yer Gallery, Plymouth. 1896. {Hodyson, Dr. William, J.P. Helensville, Crewe. 1904. §Hlodson, F. Bedale’s School, Petersfield, Hampshire. 1904. §Hogarth, D. G., M.A. Chapel Meadow, Forest Ruw, Sussex. 1894. t{Hogg, A. F., M.A. 153 Victoria-road, Darlington. 1894. tHolah, Ernest. 6 Crown-court, Uheapside, E.C. 1883. tHolden, James. 12 Park-avenue, Southport. 1883. tHolden, John J, 75 Albert-road, Southport. 1884. tHolden, Mrs, Mary E. Dunham Ladies’ College, Quebec, Cana la, 1904, D 50 LIST OF MEMBERS. Year of Election. 1887. 1896. 1900. 1887. 1891. 1904. 19038. 1896. 1898, 1889. 1886. 1883. 1883. 1866. 1892. 1882. 1903. 1896. 1897. 1875. 1904, 1847, 1892. 1865. 1877. 1904, 1901. 1884. 1882. 1871. 1858. 1891. 1898. 1885, 1903. 1902. 1875. 1884. 1887. 1893. 1884. 1899, 1859. 1896, *Holder, Henry William, M.A. Sheet, near Petersfield. tHolder, Thomas. 2 Tithebarn-street, Liverpool. §Hoxpica, Colonel Sir THomas H., R.E., K.C.B., K.0.LE., F.R.G.S. (Pres. E, 1902.) 41 Courtfield-road, S.W. “Holdsworth, C.J. Sunnyside, Wilmslow, Cheshire. tHolgate, Benjamin, F.G.S. The Briers, North Park-avenue, Roundbay, Leeds. §Holland, Charles E. 9 Downing-place, Cambridge’ §Holland, J. L., B.A. 72 Kingsley Park-terrace, Northampton. {Holland, Mrs. Lowfields House, Hooton, Cheshire. tHolland, Thomas H., F.R.S., F.C.S. Geological Survey Office, Calcutta. tHollander, Bernard, M.D. King’s College, Strand, W.C. tHolliday, J. R. 101 Harborne-road, Birmingham. {Hollingsworth, Dr. T.S. Elford Lodge, Spring Grove, Isleworth. *Holmes, Mrs. Basil. 5 Freeland-road, Haling, Middlesex, W. *Holmes, Charles. 24 Aberdare-gardens, West Hampstead, N.W. tHolmes, Matthew. Netherby, Lenzie, Scotland. *Hotmps, Toomas Vincent, F.G.8. 28 Croom’s-hill, Greenwich, S.E, *Holt, Alfred, jun., J.P, Crofton, Aigburth, Liverpool. tHolt, William Henry. 11 Ashyille-road, Birkenhead, tHolterman, R. F. Brantford, Ontario, Canada. *Hood, John. Chesterton, Cirencester. §Hooke, Rev. D. Burford. Bonchurch Lodge, Barnet. tHooxer, Sir Jossrn Darron, G.C.S.1., C.B., M.D., D.C.L., LL.D., F.R.S., F.LS., F.G.S., F.R.G.S. (Presrpent, 1868; Pres. E, 1881; Council 1866-67.) The Camp, Sunningdale, Berkshire. tHooxsr, Ruervatp H., M.A. 3 Gray’s Inn-place, W.C. *Hooper, John P. Deepdene, Streatham Common, 8S. W. *Hooper, Rev. Samuel F., M.A. Lydlinch Rectory, Sturminster Newton, Dorset. §Hopewell-Smith, A., M.R.C.S. 37 Park-street, Grosvenor-square, S.W *Hopkinson, Bertram, M.A. Holmwood, Wimbledon. *Hopxinson, CHARLES (Local Sec. 1887). The Limes, Didsbury, near Manchester. ; *Hopkinson, Edward, M.A., D.Sc. Ferns, Alderley Edge, Cheshire. *Hopxrnson, Jonny, Assoc.M.Inst.C.E., F.L.S., F.G.S., F.R.Met.Soc. 84 New Bond-street, W.; and Weetwood, Watford. tHopkinson, Joseph, jun. Britannia Works, Huddersfield. tHorder, T. Garrett. 10 Windsor-place, Cardiff. *Hornby, R., M.A. Haileybury College, Hertford. tHorne, Jonny, LL.D., F.R.S., F.R.S.E., F.G.S. (Pres. C, 1901.) Geological Survey Office, Sheriff Court-buildings, Edinburgh. §Horne, William, F.G.S. Leyburn, Yorkshire. tHorner, John. Chelsea, Antrim-road, Belfast. ; *Horniman, F. J., M.P., F.R.G.S., F.L.S. Falmouth House, 20 Hyde Park-terrace, W. *Horsfall, Richard. Stoodley House, Halifax. tHorsfall, T. C. Swanscoe Park, near Macclesfield. *Horstey, Sir Vicror A. T., BSc. F.R.S., F.R.C.S. (Council, 1893-98.) 25 Cayendish-square, W. *Hotblack. G.S. Brundall, Norwich. tHotblack, J.T. 45 Newmarket-road, Norwich. tHough, Joseph, M.A., F.R.A.S. Codsall Wood, Wolverhampton, "Hough, 8. 8., F,R.S. Royal Observatory, Cape Town, , LIST OF MEMBERS. 5] Year of Election. 1886. tHoughton, I. T.S., M.A., F.G.S. 183 Hagley-road, Edgbaston, Birmingham. 1887. {Houldsworth, Sir W. H., Bart., M.P. 85 Grosyenor-place, §.W. 1896. tHoult, J. South Castle-street, Liverpool. 1884. tHouston, William. Legislative Library, Toronto, Canada, 1883. *Hovenden, Frederick, F.L.S., F.G.S. Glenlea, Thurlow Park-road, 1893. 1883, 1887. 1899. 1901. 1903. 1886. 1876. 1899. 1889. 1857. 1898. 1891. 1886. 1901. 1884. 1865, 1863. 1883. 1883. 1887, 1903. 1888, 1898, 1867. 1858, 1887. 1883. 1871. 1887. 1896. 1891. 1868. 1891. 1867. West Dulwich, 8.E. tHoward, F. T., M.A., F.G.S. The Cottage, Poynton, Stockport. tHoward, James Fielden, M.D., M.R.C.S. Sandyeroft, Shaw. *Howard, 8.8. 58 Albemarle-road, Beckenham, Kent. §Howard-Hayward, H. 16 Blakesley-avenue, Kaling, W. §Howarth, E. Public Museum, Weston Park, Sheffield. *Howarth, James H., F.G.8. Somersley, Rawson-avenue, Ialifax. {Howatt, David. 3 Birmingham-road, Dudley. tHowatt, James. 146 Buchanan-street, Glasgow. tHowden, Ian D.C. 6 Cambridge-terrace, Dover. {Howden, Robert, M.B., Professor of Anatomy in the University of Durham College of Medicine. Neweastle-upon-Tyne. {Howoll, Henry H., F.G.S. 13 Cobden-crescent, Edinburgh. tHowell, J. H. 104 Pembroke-road, Clifton, Bristol. tHowell, Rev. William Charles, M.A. Holy Trinity Parsonage, High Cross, Tottenham, N. t{Howss, G. B., LLD., D.Sc, F.RS, F.LS. (Pres. D, 1902; Council, 1902-04), Professor of Zoology in the Royal College of Science, South Kensington, 8. W. t{Howie, Robert Y. 3 Greenlaw-avenue, Paisley. {Howland, Edward P.,M.D. 211 414-street, Washington, U.S.A. *How tert, Rev. Freverick, F.R.A.S. 7 Prince’s-buildings, Clifton, Bristol. tHoworrz, Sir II. H., K.C.LE., D.C.L., F.R.S., F.S.A. 30 Colling- ham-place, Cromwell-road, S.W. {Howorth, John, J.P. Springbank, Burnley, Lancashire. tHoyle, James. Blackburn. §Hoyix, WittiaM E., M.A.,D.Se. Victoria University, Manchester. §Hiibner, Julius. Ash Villa, Cheadle Hulme, Cheshire. {Hudd, Alfred E., F.S.A. Clinton House, Pembroke-road, Clifton, Bristol. §Hupiestoy, W. H., M.A., F.RS., F.G.S. (Pres. C, 1898.) 8 Stanhope-gardens, 8. W. *Houpsoyn, Witttam H. H., M.A. 15 Altenberg-gardens, Clapham Common, S.W. *Hucerns, Sir Writuam, K.C.B., D.C.L. Oxon., LL.D. Camb., Pres.R.S., F.R.A.S. (Presrpent, 1891; Council, 1868-74, 1876-84.) 90 Upper Tulse-hill, S.W. tHughes, E.G. 4 Roman-place, Higher Broughton, Manchester {Hughes, Miss E. P. Cambridge Teachers’ College, Cambridge. *Hughes, George Pringle, J.P. Middleton Hall, Wooler, Northum- berland. tHughes, John Taylor. Thorleymoor, Ashley-road, Altrincham. tHughes, John W. New Heys, Allerton, Liverpool. tHughes, Thomas, F.C.S. 31 Loudoun-square, Cardiff. §Hueuss, T. M‘K., M.A., F.R.S., F.G.S., Woodwardian Profersor of Geology in the University of Cambridge. (Council, 1878-86.) Ravensworth, Brooklands-avenue, Cambridge. tHughes, Rey. W. Hawker. Jesus College, Oxford. tHurt, Epwarp, M.A., LL.D., F.R.S., F.G.S. (Pres. C., 1874.) 14 Stanley-gardens, Notting Hill, W. D2 62 LIST OF MEMBERS. Year of Election. 1903. {Hulton, Campbell G. Palace Hotel, Southport. 1897. tHume, J.G., M.A., Ph.D. 650 Church-street, Toronto, Canada, 1901. {Hume, John H. Toronto, Canada; and 63 Bridgegate, Irvine. 1890. {Humphrey, Frank W. 68 Prince’s-gate, 8. W. 1904. *Humphreys, Alexander C., Sc.D., LL.D., President of the Stevens Institute of Technolozy, Hoboken, New Jersey, U.S.A. 1880, tHumphreys, Noel A., F.S.S. Ravenhurst, Hook, Kingston-on- Thames. 1877. *Hunt, Arravr Roors, M.A., F.G.S8. Southwood, Torquay. 1891. *Hunt, Cecil Arthur. Southwood, Torquay. 1886. {Hunt, Charles. The Gas Works, Windsor-street, Birmingham. 1891. tHunt, D. de Vere, M.D. Aubrey House, Cathedral-road, Cardiff. 1875. *Hunt, William. North Cote, Westbury-on-Trym, Bristol. 1881. tHunter, F. W. Newbottle, Fence Houses, Co. Durham. 1889. tHunter, Mrs. F. W. Newbottle, Fence Houses, Co. Durham. 1901. t{Hunter, G. M., Assoe.M.Inst.C.E. Newyards, Maybole, N.B. 1881. tHunter, Rev. John. University-gardens, Glasgow. 1901. *Hunter, William. Evirallan, Stirling. 1879. t{Huntineton, A.K.,F.C.S., Professor of Metallurgy in King’s College, W.C 1885. tHuntly, The Most Hon, the Marquess of. Aboyne Castle, Aber- deenshire. 1863. {Huntsman, Benjamin. West Retford Hall, Retford. 1898. tHurle, J. Cooke. Southfield House, Brislington, Bristol. 1903. §Hurst, Charles C., F.L.S. Burbage, Hinckley. 1832. *Hurst, Walter, B.Sc. Kirkgate, Tadcaster, Yorkshire. 1861. *Hurst, A eae John. Drumaness, Ballynahinch, Co. Down, Treland. 1894, *Hurcuinson, A., M.A., Ph.D. (Local Sec. 1904.) Pembroke College, Cambridge. 1903. §Hutchinson, Rev. H. N. 94 Fellows-road, N. W. Hutton, Crompton. Harescombe Grange, Stroud, Gloucestershire, 1864 *Hutton, Darnton. 14 Cumberland-terrace, Regent’s Park, N.W. 1887. *iLutton, J. Arthur. The Woodlands, Alderley Edge, Cheshire. 1901. *Hutton, R.8., M.Sc. The Victoria University, Manchester. 1883. Hyde, George H. 23 Arbour-street, Southport. 1871, *Hyett, Francis A. Painswick House, Painswick, Stroud, Glouces- tershire. 190u., *Hyndman, H. H. Francis. Physical Laboratory, Leiden, Nether- lands. 1902. {Hyndman, Hugh. Crosshill, Windsor-avenue, Belfast. 1883. §Idris, T. H. W. 110 Pratt-street, Camden Town, N.W. Ihne, William, Ph.D. Heidelberg. 1884, *Iles, George. 5 Brunswick-street, Montreal, Canada. 1885. tim Thurn, Everard F., C.B.,C.M.G. Colombo, Ceylon. 1888. *Ince, Surgeon-Lieut.-Col. John, M.D. Montague House, Swanley, Keni. 1858. {Ingham, Henry. Wortley, near Leeds. 1893. tIngle, Herbert. Pool, Leeds. 1901. {Ineis, Jouyn, LL.D. 4 Prince’s-terrace, Dowanhill, Glasgow. 1891. {Ingram, Lieut.-Colonel C. W. Bradford-place, Penarth. 1852, t{Ineram, J. K., LL.D., M.R.1LA. (Pres. F. 1878), Senior Lecturer in the University of Dublin. 2 Wellington-road, Dublin. 1885. tIngram, William, M.A. Gamrie, Banff, LIST OF MEMBERS, 53 Year of Election. 1898. {Inskip, James. Clifton Park, Clifton, Bristol. 1901. *Ionides, Stephen A. 23 Second-avenue, Hove, Brighton. 1892. {Irvine, James. Devonshire-road, Birkenhead. 1882, 1903. 1859. 1876, 1901. 1883. 1903. 1874. 1883. 1885, 1899. 1866, 1897, 1898. 1869, 1887, 1874. 1891. 189]. 1891. 1860. 1886. 1891. 1896. 1904. 1858. 1896. 1884. 1881. 1885, 1859. 1889, 1896. 1905. 1870. 1904. 1904. 1891. 1897. 1894. 1875. 1880, §Irvine, Rey. A., B.A., D.Sc. Hockerill Vicarage, Bishop’s Stort- tord, Herts. firving, W. B. 27 Park-road, Southport. {Jack, John, M.A. Belhelvie-by-Whitecairns, Aberdeenshire. *Jack, Witt1aM, LL.D., Professor of Mathematics in the University of Glasgow. 10 The College, Glasgow. §Jacks, William, LL.D. Crosslet, Dumbartonshire. *JAckson, Professor A. II., B.Sc. 849 Collins-street, Melbourne, Australia, §Jackson, C.S. 96 Herbeit-road, Woolwich, S.E. *Jackson, Frederick Arthur, Penalya Ranche, Millarville, Alberta, Calgary, N.W.T., Canada, *Jackson, F. J, 35 Leyland-road, Southport. tJackson, Mrs. F. J. 35 Leyland-road, Southport. {Jackson, Geoffrey A. 351 Harrington-gardens, Kensington, S.W. tJackson, H. W., F.R.A.S. 67 Upgate, Louth, Lincolnshire. §Jackson, James, F.R.Met.Soc. Seabank, Girvan, N.B. *Jackson, Sir John. 51 Victoria-street, S.W. §Jackson, Moses, J.P. The Orchards, Whitchurch, Hants, §Jacobson, Nathaniel. Olive Mount, Cheetham Hill-road, Man- chester. *Jaffe, John, Villa Jaffe, 388 Prom. des Anglais, Nice, France. tJames, Arthur P. Grove House, Park-grove, Cardiff. *James, Charles Henry, J.P. 64 Park-place, Cardiff. *James, Charles Russell. 6 Raymond-buildings, Gray’s Inn, W.C. tJames, Edward H. Woodside, Plymouth. tJames, Frank. Portland House, Aldridge, near Wailsall. {James, Ivor. University College, Cardiff. {James,O.S. 192 Jarvis-street, Toronto, Canada. §James, Thomas Campbell. 4 Belmont-terrace, Llanelly. tJames, William C, Woodside, Plymouth. *Jameson, H. Lyster, M.A., Ph.D. Technical College, Derby. f{Jameson, W. C. 48 Baker-street, Portman-square, W. tJamieson, Andrew, Principal of the College of Science and Arts, Glasgow. tJamieson, Thomas. 175 Union-street, Aberdeen. *Jamieson, Thomas F,, LL.D., F.G.S. Ellon, Aberdeenshire. *Jarp, F. R., M.A., Ph.D., LL.D., F.R.S. (Pres. B, 1898), Pro- fessor of Chemistry in the University of Aberdeen. *Jarmay, Gustav. Hartford Lodge, Hartford, Cheshire. tJarrarr, J. Exngst. (Local See. 1903.) 10 Cambridge-road, Southport. {Jarrold, John James. London-street, Norwich. *Jeans, J. H. Trinity College, Cambridge. §Jebb, Sir R. C., Litt. D., M.P., Professor of Greek in the University of Cambridge. Springfield, Cambridge. fJefferies, Henry. Plas Newydd, Park-road, Penarth. {Jeffrey, KE. C., B.A. The University, Toronto, Canada. jJelly, Dr. W. Aveleanas, 11, Valencia, Spain. {Jenkins, Major-General J. J. 16 St. James’s-square, 8. W. *JENKINS, Sir Jonn Jonxs. The Grange, Swansea, 64 LIST OF MEMBERS, Year of Election. 1903. §Jenkinson, J. W. The Museum, Oxford. 1904. §Jenkinson, W. W. 6 Moorgate-street, E.C. 1852. {Jennings, Francis M., M.R.LA. Brown-street, Cork. 1893. §Jennings, G. HE. Glen Helen, Narborough-road, Leicester. 1897. {Jennings, W. T., M.Inst.CE. Molson’s Bank Buildings, Toronto, Canada. 1899, {Jepson, Thomas. Evington, Northumberland-street, Higher Brough- ton, Manchester. 1887, {Jervis-Smitu, Rev. F. J., M.A.,T.R.S. Trinity College, Oxford. Jessop, William. Overton Hall, Ashover, Chesterfield. 1889. jJevons, F. B., M.A. The Castle, Durham. 1900, *Jevons, H. Stanley. 19 Chesterfield-gardens, Hampstead, N.W. 1884, {Jewell, Lieutenant Theo. F. Torpedo Station, Newport, Rhode Island, U.S.A. 1884. jJohns, Thomas W. Yarmouth, Nova Scotia, Canada. 1884, tJounson, ALEXANDER, M.A., LL.D., Professor of Mathematics in McGill University, Montreal, 5 Prince of Wales-terrace, Mont- real, Canada. 1883. tJohnson, Miss Alice. Llandaff House, Cambridge, 1865. *Johnson, G. J. 36 Waterloo-street, Birmingham. 1888. {Johnson, J.G. Southwood Court, Highgate, N. 1881. {Johnson, Sir Samuel George. Municipal Offices, Nottingham. 1890, *Jounson, Tuomas, D.Sc., F'.L.S., Professor of Botany in the Royal College of Science, Dublin. 1902. *Johnson, Rev. W., B.A., B.Sc. Archbishop Holgate’s Grammar School, York. 1898. *Johnson, W. Claude, M.Inst.C.E. The Dignaries, Blackheath, S.E. 1887. tJuhbnson, W. H. Woodleigh, Altrincham, Cheshire. 1883. tJohnson, W. H. F. Llandaff House, Cambridge. 1861. {Johnson, William Beckett. Woodlands Bank, near Altrincham, Cheshire. 1899. tJohnston, Colonel Duncan A., C.B., R.E. Ordnance Survey, South- ampton. 1888. ican, Sir H. H., G.C.M.G., K.C.B., F-.R.G.S. Queen Anne’s- mansions, 8S. W. 1884. tJohnston, John L. 27 St. Peter-street, Montreal, Canada. 1883 j{Johuston,Thomas. Broomsleigh, Seal, Sevenoaks. 1884. {Johnston, Walter R. Fort Qu’Appelle, N.W. Territory, Canada. 1884, *Johnston, W. H. County Offices, Preston, Lancashire. 1885. {Jounston-Lavis, H. J., M.D., F.G.S. Beaulieu, Alpes Maritimes, France, 1886, {Johnstone, G. H. Northampton-street, Birmingham. 1871. {Jotxy, Wint1aM, F.RS.E., F.G.S. Blantyre Lodge, Blantyre, N.B. 1888. {Jolly, W. C. Home Lea, Lansdowne, Bath. 1896. *Jory, Cuartes JAsper, M.A., D.Sc, F.R.S., F.R.A.S., Royal Astronomer of Ireland and Andrews’ Professor of Astronomy in the University of Dublin. The Observatory, Dunsink, Co. Dublin. 1888. {Jory, Joun, M.A., D.Sc., F.R.S., F.G.S., Professor of Geology and Mineralogy in the University of Dublin. Geological Depart- ment, Trinity College, Dublin. 1898. tJones, Sir Alfred L., K.C.M.G. Care of Messrs, Elder, Dempster, & Co., Liverpool. 1887. tJones, D. E., B.Sc., H.M. Inspector of Schools. Science and Art Department, South Kensington, S.W. 1904. §Jones, Miss E, Constance. Girton College, Cambridge. LIST OF MEMBERS, 55 Yenr of Election. 1890. §JonEs, Rev. Epwarp, F.G.S. Primrose Cottage, Embsay, Slopton. 1896. {Jones, E. Taylor, D.Sc. University College, Bangor. 1903. 1887, 1891, 1883. 1908. 1895. 1877. 1901. 1902. 1873. 1880. 1860. 1896. 1883. 1875. 1884. 1891. 1891. 1879. 1890. 1872. 1883. 1886. 1891. 1870. 1903. 1894, 1883. 1888, 1904, 1875. 1886. 1894, 1878. 1884, 1864, 1902, 1885. 1847, §Jones, Evan. Ty-Mawr, Aberdare. fJones, Francis, F.R.S.E., F.C.S, Beaufort House, Alexandra Park, Manchester. *Jonus, Rey. G. Harrwett, M.A. Nutfield Rectory, Redhill, Surrey. *Jones, George Oliver, M.A. Inchyra House, 21 Cambridge-road, Waterloo, Liverpool. *Jonges, H. O., M.A. Clare College, Cambridge. tJones, Harry, Engineer’s Office, Great Eastern Railway, Ipswich. tJones, Henry C., F.C.S. Royal College of Science, South Kensing- ton, S.W. §Jones, R. E., J.P. Oakley Grange, Shrewsbury. tJones, R. M., M.A. Royal Academical Institution, Belfast. tJones, Theodore B. 1 Finsbury-cireus, E.C. {Jones, Thomas. 15 Gower-street, Swansea. tJonzs, Toomas Rurerrt, F.R.S., F.G.S. (Pres. C, 1891.) 17 Par- *son’s Green, Fulham, 8. W. {Jores, W. Hope Bank, Lancaster-road, Pendleton, Manchester. tJones, William. Elsinore, Birkdale, Southport. *Jose, J. EH. 49 Whitechapel, Liverpool. tJoseph, J. H. 738 Dorchester-street, Montreal, Canada. {Jotham, F. H. Penarth. fJotham, T. W. Penylan, Cardiff. +Jowitt, A. Scotia Works, Sheffield. {Jowitt, Benson R. Elmhurst, Newton-road, Leeds. {Joy, Algernon. Junior United Service Club, St. James’s, 8, W. {Joyce, Rev. A. G., B.A. St. John’s Croft, Winchester, tJoyce, The Hon. Mrs. St. John’s Croft, Winchester. tJoynes, John J. Great Western Colliery, near Coleford, Gloucester- shire. tJupp, Joun Westey, C.B., LL.D., F.R.S., F.G.S. (Pres. C, 1885: Council, 1886-92), Professor of Geology in the Royal College of Science, London. 22 Cumberland-road, Kew. §Julian, Henry Forbes. Redholme, Braddon’s Hill-road, Torquay. §Julian, Mrs. Forbes. Redholme, Braddon’s Hill-road, Torquay. tJustice, Philip Middleton. 14 Southampton-buildings, Chancery- lane, W.C. {Kapp, Gisbert, M.Inst.C.E., M.Inst.E.E. 3 Lindenallee, Westend, Berlin. §Kayser, Professor H. The University, Bonn, Germany. tKeeling, George William. Tuthill, Lydney. {Keen, Arthur, J.P. Sandyford, Augustus-road, Birmingham. {Keightley, Rev. G. W. Great Stambridge Rectory, Rochford, Essex. *Kelland, W. H. 80 Lothian-road, S. W. {Kelloge, J. H., M.D. Battle Creek, Michigan, U.S.A. *Kelly, W. M., M.D. Ferring, near Worthing. *Kelly, William J., J.P. 25 Oxford-street, Belfast. §Kettiz, J. Scorr, LL.D., Sec. R.G.8., F.S.S. (Pres. E, 1897 ; Council, 1898-1904.) 1 Savile-row, W. *Kervin, The Right Hon. Lord, G.C.V.O., M.A., LL.D., D.C.L., E.R.S., F.R.S.E., F.R.A.S. (Presipent, 1871; Pres. A, 1852, 1867, 1876, 1881, 1884.) Netherhall, Largs, Ayrshire; and 15 Eaton-place, 8. W. 56 Year of LIST OF MEMBERS. Election. 1877. 1887. 1898. 1884, 1890. 1891. 1875. 1897. 1884. 1876, 1884, 1884. 1886, 1893. 1901. 1886. 1857. 1876. 1881. 1884. 1883. 1901. 1892. 1889, 1887. 1869, 1869. 1903, 18838. 1902. 1876. 1886. 1897. 1901. 1885. 1896. 1890. 1878. 1860. 1875. 1888. 1888. 1875. *Kelvin, Lady. Netherhall, Largs, Ayrshire; and 15 Eaton-place, Swe tKemp, Harry. 55 Wilbraham-road, Chorlton-cum-Hardy, Man- chester. *Kemp, John T., M.A. 4 Cotham-grove, Bristol. {Kemper, Andrew C. ., A.M., M.D. 101 Broadway, Cincinnati, U.S.A. JKempson, Augustus. Jildare, 17 Arundel-road, Eastbourne. §Kenpatt, Pprcy I, .G.8., Professor of Geology in the Univer- sity of Leeds. j{Kenyepy, Ee W., LL.D., F.R.S., M.Inst.C.E. (Pres. G 1894.) 1 Queen Amne-street, Cavendish-square, We §Kennedy, George, M.A., LL.D. Crown Lands Department, Toronto, Canada. {Kennedy, George T., M.A., I.G.S, Professor of Chemistry and Geology in King’s College, Windsor, Nova Scotia, Canada. {Kennedy, Ilugh. 20 Mirkland-street, Glasgow. {Kennedy, John. 115 University: -street, Montreal, Canada. tKennedy, William. Hamilton, ‘Ontario, C Canada. fKenrick, George Hamilton. Ww hetstone, Somerset-road, Edgbaston, Birmingham. §Kenr, A. If. Sranzpy, M.A., F.L.S., F.G.8., Professor of Physio- logy in University College, Bristol. {Kent, G. 16 Premier-road, ‘Nottingham. §KENWARD, JAMEs, F.S.A. 43 Streatham Iligh-road, 5. W. *Ker, André Allen Murray. Newbliss House, Newbliss, Ireland. {Ker, William. 1 Windsoyr-terrace West, Glasgow. {Kermopr, Puitre M.C. Claughbane, Ramsey, Isle of Man. {KXerr, James, M.D. Winnipeg, Canada. }iurr, Rev. Jonny, LL.D., F.RS. Free Church Training College, 113 Hill-street, Glasgow. {Kerr, John G., LL.D. 15 India-street, Glaszow. { Kerr, J. Granam, M.A., Professor of Natural Ilistory in the Uni- versity, Glasgow. {Kerry, W. H. R. The Sycamores, Windermere. {Kershaw, James. Holly House, Bury New-road, Manchester. *Kesselmeyer, Charles Augustus. Rose Villa, Vale-road, Bowdon, Cheshire. *Kesselmeyer, William Johannes, Elysée Villa, Manchester-road, Altrincham, Cheshire. §Kewley, James. King William’s College, Isle of Man. *Keynes, J. N., M.A., D.Sc., F.S.S. 6 Harvey-road, Cambridge. §Kidd, George. Junmurry, Co. Antrim. }IXidston, J. B. 50 West Regent-street, Glasgow. §Kapston, Robert, F.R.S., F.RS.E., F.G.8. 12 Clarendon-place, Stirling. {Kiekelly, Dr. John, LL.D. 46 Upper Mount-street, Dublin. *Kiep, J. N. 4 Hughenden-drive, Nelvinside, Glasgow. *Kilgour, Alexander. JLoirston House, Cove, near Aberdeen. *Killey, George Deane. Bentuther, 11 Victoria-road, Waterlco, Liverpool. §Kamumuins, C. W., M.A., D.Sc. Dame Armstrong House, Harrow. tKinahan, Sir Edward Hudson, Bart. 11 Merrion-square North, Dublin. tKiwawan, G. Henry, M.R.I.A. Dublin. *Kincu, Epwarp, F. GS. Royal Agricultural College, Cirencester. {King, Austin J. Winsley Hill, Limpley Stoke, Bath. *King, E. Powell. Wainsford, Lymington, Hants. *King, F. Ambrose. Avonside, Clifton, Bristol. LIST OF MEMBERS. 57 Year of Wlection. 1899, jIine, Sir Georex, K.C.ILE., PRS. (Pres. K, 1899). Care of Messrs. Grindlay & Co., 55 Pavliament-street, S.W. 1871. *King, Rev. Herbert Poole. The Rectory, Stourton, Bath. 1855. {King, James. Levernholme, Hurlet, Glasgow. 1888. *King, John Godwin. Stonelands, West Hoathly. 1870. tKing, John Thomson, 4 Clayton-square, Liverpool. 1883. *King, Joseph. Sandhouse, Witley, Godalming. 1860. *King, Mervyn Kersteman. Mercbants’ Hall, Bristol. 1875. *King, Percy L. 2 Worcester-avenue, Clifton, Bristol. 1901. ting, Robert. Levernholme, Nitshill, Glasgow. 1870. tKing, William, M.Inst.C.E. 5 Beach Lawn, Waterloo, Liverpool. 1903. §Kingsford, H. S., B.A. Anthropological Institute, 3 IJanover- square, W. 1897. {Kingsmill, Nichol. Toronto, Canada. 1875. t{Kinezerr, Cnartes T., F.C.S. Elmstead Knoll, Chislehurst. 1867. tKinloch, Colonel. Kirriemuir, Logie, Scotland. 1892, ¢Kinnear, The Hon. Lord, F.R.S.E. 2 Moray-place, Edinburgh. 1900, tKirrtne, Professor F. Srantey, D.Se., Ph.D., F.RS, University College, Nottingham. 1899. *Kirby, Miss C. F. 74 Kensington Park-road, W. 1870. { Kitchener, Frank E. Newcastle, Staffordshire. 1904. §Kitson, Arthur. 209 Gloucester-terrace, Iyde Park, W. 1890, *Kitson, Sir James, Bart., M.P. Gledhow Hall, Leeds. 1901. §Kitto, Edward. The Observatory, Falmouth. 1886. {Klein, Rev. L. M. de Beaumont, DSc, F.L.S. 6 Gloucester- terrace, Regent’s Park, N. W. 1886, {Knight, J. McK., F.G.8. Bushwood, Wanstead, Issex. 1898, {Knocker, Sir E. Woxtastoy, K.C.B. (Local See. 1899.) Castle Hill House, Dover. 1888. {Knorr, Professor Carcitn G., D.Se., F.RS.E. 42 Upper Gray- street, Ediiburgh. 1887. *Knott, Herbert. Aingarth, Stalybridge, Cheshire. 1887. *Knott, John F. Oak Hill, Windermere. 1874, {Knowles, William James. Flixton-place, Ballymena, Co, Antrim. 1908. {Knowlson, J. F. 26 Part-street, Southport. 1297. {Knowlton, W. H. 36 King-street East, Toronto, Canada, 1876. {Knox, David N., M.A., M.B. 24 Elmbank-crescent, Glasgow. 1902. {Kwox, R. Kytn, LL.D. 1 College-gardens, Belfast. 1875, *Knubley, Rev. b. P., M.A. Steeple Ashton Vicarage, Trowbridge. 1883. jKnubley, Mrs. Steeple Ashton Vicarage, Trowbridge. 1892. t{Koun, Cuartes A.. Ph.D. Sir John Cass Technical Institute, Jewry-street, Aldgate, F.C. 1898. ¢{Krauss, A. Hawthornden, Priory-road, Clifton, Bristol. 1890, *Krauss, John Samuel, B.A. Stonycroft, Knutsford-road, Wilmslow, Cheshire. 1901. tKuenen, Professor J. P., Ph.D. University College, Dundee. 1888. *Kunz, G.F., M.A., Ph.D. Care of Messrs. Tiffany & Co., 11 Union- square, New York City, U.S.A. 1870. {Kynaston, Josiah W.,F.C.5S. 3 Qak-terrace, Beech-street, Liverpool. 1885. *Laing, J. Gerard. 5 Pump-court, Temple, E.C. 1897. {Laind, Professor G. J. Wesley College, Winnipeg, Canada. 1904, §Lake, Philip. St. John’s, College, Cambridge. 1877. tLake, W.C., M.D. Teignmouth. 1904, §Lamb, ©. G. Ely Villa, Glisson-road, Cambridge, 58 Year LIST OF MEMBERS, of Election. 1889 1887. 1887. 1896, 1895. 1908. 1884. 1893. iteyAls 1886. 1904, 1883. 1859. 1898. 1886. 1870, 1865. 1880, 1884. 1878. 1885. 1887. 1881, 1883. 1896. 1870. 1900. 1870. 1891. 1892. 1888. 1883. 1870. 1884. 1870, 1881. 1900. 1889, 1885. . *Lamb, Edmund, M.A. Borden Wood, Liphook, Hants. t{Lams, Horace, M.A., LL.D., D.Sc., F.R.S. (Pres. A, 1904), Pro- fessor of Pure Mathematics in the Victoria University, Manchester, 6 Wilbraham-road, Fallowfield, Manchester. {Lamb, James. WKenwood, Bowdon, Cheshire. tLambert, Frederick Samuel. Balgowan, Newland, Lincoln. Lambert, J. W., J.P. Lenton Firs, Nottingham. tLambert, Joseph. 9 Westmoreland-road, Southport. {Lamborn, Robert H. Montreal, Canada, *LampLucH, G. W., F.G.S. 13 Beaconsfield-road, St. Albans. tLancaster, Edward. Karesforth Hall, Barnsley, Yorkshire. {Lancaster, W. J., F.G.S. Colmore-row, Birmingham, §Landor, A. TH. Savage, F.R.G.S. Care of Messrs. Grindlay & Co., 55 Parliament-street, 5. W. tLang, Rey. Gavin. Mayfield, Inverness. fLang, Rev. John Marshall, D.D. The University, Aberdeen, *Lang, William H. 10 Jedburgh-gardens, Kelvinside, Glasgow. *Lanetey, J. N., M.A., D.Sc., F.R.S. (Pres. I, 1899; Council, 1904— ), Professor of Physiology in the University of Cam- bridge. Trinity College, Cambridge. {Langton, Charles. Barkhill, Aigburth, Liverpool. tLanxester, IX. Ray, M.A., LL.D., F.R.S. (Pres. D, 1883; Council 1889-90, 1894-95, 1900-02), Director of the Natural History Museum, Cromwell-road, 8. W. *LANSDELL, Rev. Hryry, D.D., F.R.A.S.,F.R.G.S, Morden College, Blackheath, London, 8.E. §Lanza, Professor G. Massachusetts Institute of Technology, Boston, tLapper, E., M.D. 61 Harcourt-street, Dublin. tLapwortn, Cartes, LL.D., F.R.S., F.G.S. (Pres. C, 1892), Professor of Geology and Physiography in the University of Birmingham, 48 Frederick-road, Edgbaston, Birmingham, tLarmor, Alexander. Craglands, Helen’s Bay, Co. Down. {Larmor, Josnry, M.A., D.Sc., Sec.R.S. (Pres. A, 1900), Lucasian Professor of Mathematics in the University of Cambridge. St. John’s College, Cambridge. § Lascelles, B. P., M.A. Longridge, Harrow. *Last, William J. South Kensington Museum, London, 8.W. *LatHam, Barpwin, M.Inst.C.E., I°.G.S. 7 Westminster-chambers, ‘Westminster, 8. W. tLauder, Alexander, Lecturer in Agricultural Chemistry in the Edin- burgh and East of Scotland College of Agriculture, Edinburgh. tLaughton, John Knox, M.A., F.R.G.S. 5 Pepys-road, Wimbledon, Surrey. tLaurie, A. P. Heriot Watt College, Edinburgh, , tLavrre, Matcorm, B.A., D.Sc., F.L.8., Professor of Zoology in St. Mungo’s College, Glasgow. tLaurie, Colonel R. P., C.B. 79 Farringdon-street, E.C. tLaurie, Major-General. Oakfield, Nova Scotia, Canada. *Law, Channell. Ilsham Dene, Torquay. tLaw, Robert, F.G.S. Fennyroyd Hall, Hipperholme, near Halifax, Yorkshire. {Lawrence, Hdward. Aigburth, Liverpool. tLawrence, Rey. F., B.A. The Vicarage, Westow, York. tLawrence, W. Trevor, Ph.D. 57 Prince’s-gate, S.W. §Laws, W. G., M.Inst.C.E. 95 Osborne-road, Newcastle-upon-Tyne. tLawson, James, 8 Church-street, Huntly, N.B, LIST OF MEMBERS. 59 Year of Election. 1888. §Layard, Miss Nina F, Rookwood, Tonnereau-road, Ipswich. 1856. 1883. 1875. 1894, 1884. 1901. 1884, 1904. 1884. 1872. 1884, 1895. 1898. 1896. 1891. 1894. 1884. 1896. 1892, 1886. 1859. 1896. 1889. 1881. 1872. 1869. 1892. 1868. 1856. 1891. 1903. 1859. 1882. tLea, Henry. 38 Bennett’s-bill, Birmingham, *Leach, Charles Catterall. Seghill, Northumberland. tLeach, Colonel Sir G., K.C.B., R.E. 6 Wetherby-gardens, S.W. *Leany, A. H., M.A., Professor of Mathematics in University College, Sheffield. 92 Ashdell-road, Sheffield. *Leahy, John White, J.P. South Hill, Killarney, Treland. *Lean, George, B.Sc. 15 Park-terrace, Glasgow. tLearmont, Joseph B. 120 Mackay-street, Montreal, Canada. *Leathem, J.G. St. John’s College, Cambridge. *Leavitt, Erasmus Darwin. 2 Central-square, Cambridgeport, Mas- sachusetts, U.S.A. {Lesovr, G. A., M.A., F.G.S., Professor of Geology in the Durham College of Science, Newcastle-on-Tyne. tLeckie, R.G. Springhill, Cumberland County, Nova Scotia, Canada. *Ledger, Rev. Edmund. Protea, Doods-road, Reigate. tLue, Artur, J.P. (Local Sec. 1898). 10 Berkeley-square, Clifton, Bristol. §Lee, Rev. H. J. Barton. 35 Cross Park-terrace, Heayitree, Exeter. {Lee, Mark. The Cedars, Llandaff-road, Cardiff. *Lee, Mrs. W. Ashdown House, Forest Row, Sussex. *Leech, Sir Bosdin T. Oak Mount, Timperley, Cheshire, *Leech, Lady. Oak Mount, Timperley, Cheshire. *Lres, Cuartes H., D.Se. 42 Lorne-grove, Fallowfield, Man- chester. *Lees, Lawrence W. Old Ivy House, Tettenhall, Wolverhampton {Lees, William, M.A. 12 Morningside-place, Edinburgh. tLees, William. 10 Norfolk-street, Manchester. *Leese, Joseph. 8 Lord-street West, Southport. *Leeson, John Rudd, M.D., O.M., F.LS., F.G.8. Clifden House, Twickenham, Middlesex. {Lx Frvvrr, J. E. (Local Sec. 1882). Southampton. {Lzrrvre, The Right Hon. G. SHaw, F.R.S. (Pres. F, 1879; Council 1878-80.) 18 Bryanston-square, W. tLe Grice, A. J. Trereife, Penzance. {Lenretpr, Rosert A. 56 Norfolk-square, W. {Lercesrer, The Right Hon. the Earl of, K.G. Holkham, Norfolk. tLxren, The Right Hon. Lord. Stoneleigh Abbey, Kenilworth, tLeigh, W. W. Treharris, R.S.O., Glamorganshire. §Leighton, G. R., M.D., F.R.S.E., Professor of Pathology in the Royal Veterinary College, Edinburgh. tLeith, Alexander. Glenkindie, Inverkindie, N.B. §Lemon, James, M.Inst.C.E., F.G.8. Lansdowne House, South- ampton. . *Lempfort, R. G. K., M.A. Meteorological Office, 63 Victoria-street, fo) S.W. tLeng, Sir John, M.P. ‘Advertiser’ Office, Dundee. tLennon, Rev. Francis. The College, Maynooth, Ireland. 2, tLennox, R.N. Rosebank, Hammersmith, W. *Leon, John T. Elmwood, Grove-road, Southsea. {Lronarp, Hueu, M.R.LA, 24 Mount Merrion-avenue, Blackrock, Co. Dublin. §Leonard, J. H., B.Sc. 2 Carlingford-road, Hampstead, N.W. §Lepper, Alfred William. 6 Trinity College, Dublin. t+Lesage, Louis. City Hall, Montreal, Canada. *Lester, Joseph Henry. Royal Exchange, Manchester. {Lester, Thomas. Fir Bank, Penrith. 60 LIST OF MEMBERS. Year of Klection. 1904. 1900. 1894. 1896. 1887. 1890. 1893. 1879. 1870. 1891. 1891. 1899. 1904. 1897. 1891), 1891. 1891. 1884. 1503. 1878. 1871. 1904. 1898, 1883. 1896. 1888. 1861, “Le Sueur, H. R., D.Se. Chemical Laboratory, St, Thomas’s Hos- pital, S.E. {Letts, Professor IE. A., D.Sc., F.R.S.E. Queen’s College, Bel- fast. tLeudesdorf, Charles. Pembroke College, Oxford. {Lever, W. H. Port Sunlight, Cheshire. *Levinstein, Ivan. Hawkesmoor, Fallowfield, Manchester. {Levy, J.H. 11 Abbeville-road, Clapham Park, S8.W. *Lewes, Vivian B., F.C.S., Professor of Chemistry in the Royal Naval College, Greenwich, S.E. {Lewin, Colonel, F.R.G.S. Garden Corner House, Chelsea Embank- ment, 8. W. {Lewts, Atrrep Lionet. 54 Highbury-hill, N. {Lewis, D., J.P. 44 Park-place, Cardiff. § Lewis, Professor D. Morgan, M.A. University College, Aberystwyth. {Lewis, Professor KE. P. University of California, Berkeley, U.S.A. §Lewis, Hugh. Glanafrau, Newton, Montgomeryshire. {Lewis, Rev. J. Pitt, M.A. Rossin House, Toronto, Canada. tLewis, Thomas. 9 Hubert-terrace, Dover. tLewis, W. 22 Duke-street, Cardiff. {Lewis, W. Henry. Bryn Rhos, Llanishen, Cardiff. *Lewis, Sir W. T., Bart. The Mardy, Aberdare. §Lewkowitsch, Dr. J. 71 Priory-road, N.W. {Lincolne, William. Ely, Cambridgeshire. fLindsay, Rev. T. M., M.A., D.D. Free Church College, Glas- gow. §Link, Charles W. Eversley, Chichester-road, Croydon. {Lippincott, R. C. Cann. Over Court, Almondsbury, near Bristol. { Lisle, H. Claud. Nantwich. *ListeR, The Right Hon. Lord, F.R.C.S., D.C.L., D.Se, F.R.S. (PRestDENT, 1896.) 12 Park-crescent, Portland-place, W. {Lister, J. J., M.A., F.R.S. Leytonstone, Essex, N.E. *Liveine, G. D., M.A., F.R.S, (Pres. B, 1882; Council 1888-95 ; Local Sec. 1862), Professor of Chemistry in the University of Cambridge. Newnham, Cambridge. . “Liversiper, ARcuIBALD, M.A., F.R.S., F.C.S., F.G.S., F.B.GS., Professor of Chemistry in the University of Sydney, N.S.W. . §Llewellyn, van. Working Men’s Institute and Hall, Blaenavon. . TLLEWELYN, Sir Joun T. D., Bart., M.P. Penllegare, Swansea. . §Lloyd, Godfrey I. H. Grindleford, near Sheffield. . {Lloyd, J. Henry. Ferndale, Carpenter-road, Edgbaston, Bir- mingham. . *Luoyn, R. J., M.A., D.Litt., F.R.S.E 49a Grove-street, Liverpool. » {Lloyd, Samuel. Farm, Sparkbrook, Birmingham. . *Lloyd, Wilson, F.R.G.S. Park Lane House, Wednesbury. . §Lloyd-Verney, J. Hi. 14 Hinde-street, Manchester-square, W. . *Lonpiey, J. Logan, F.G.S., F.R.G.S. 36 Palace-street, Bucking- ham Gate, S.W. . §Locu, C.8., B.A. 15a Buckingham-street, W.C, . §Lock, Rev. J. B. Herschel House, Cambridge. . *Locke, John. 144 St. Olaf’s-road, Fulham, 8.W, . {Lockhart, Robert Arthur, 10 Polwarth-terrace, Edinburgh. . {Lockyenr, Sir J. Norman, K.C.B., LL.D., F.R.S. (PRESIDENT, 1903 ; Council 1871-76, 1901-02.) 16 Penywern-road, 8. W. 2. *Lockyer, Lady. 16 Penywern-road, S.W. . §Lockyrr, W. J. S., Ph.D. 16 Penywern-road, 8.W. . *Lopen, AtrreD, M.A. The Croft, Peperharow-road, Godalming. LIST OF MEMBERS. 61 Year of Election. 1875. 1894. 1889. 1896. 1899. 1902. 1903. 1876. 1885. 1883. 18838. 1904. 1866. 1901. 1898. 1901. 1875. 1872. 1881. 1899. 1883. 1894. 1889. 1903. 1897. 1883. 1896. 1887. 1886, 1876, 1883. 1904, 1875. 1885. 1891. 1885. 1892. 1886. 1894, 19038. 1881. 1881. 1870. 1889. 1901. 1878. 1889. 1891. 1881. *Lonag, Sir Ontver J., D.Se., LL.D., F.R.S. (Pres. A, 1891; Council, 1891-97, 1899-1908), Principal of the University of Birmingham. *Lodge, Oliver W. F. 225 Hagley-road, Birmingham. tLogan, William. Langley Park, Durham. §Lomas, J., F.G.S. 13 Moss-grove, Birkenhead. §Loneq, Emile. 6 Rue de la Plaine, Laon, Aisne, France. {LonponpERRY, The Marquess of, K.G., H.M. Lieutenant of the City of Belfast. Londonderry House, Park-lane, W. §Long, Frederick. The Close, Norwich. tLong, H. A. Brisbane, Queensland. *Long, William. Thelwall Heys, near Warrington. {Long, Mrs. Thelwall Heys, near Warrington. {Long, Miss. Thelwall Heys,near Warrington. *Longden, J. A., M.Inst.C.K. Stanton-by-Dale, near Nottingham. tLongdon, Frederick. Osmaston-road, Derby. tLonge, Francis D. ‘The Alders, Marina, Lowestoft. *Longfield, Miss Gertrude. High Halstow Rectory, Rochester. *Longstaff, Frederick V., F.R.G.S. _Ridgelands, Wimbledon, Surrey. *Longstaff, George Blundell, M.A., M.D., 1.C.8., F.S.5. Highlands, Putney Heath, S.W. *Longstaff, Llewellyn Wood, F.R.G.S. Ridgelands, Wimbledon, Surrey. *Longstatiy Mr. Ll. W. Ridgelands, Wimbledon, Surrey. *Longstaff, Tom G., B.A., F.R.Met.Soc. Ridgelands, Wimbledon, Surrey. *Longton, £. J., M.D. Brown House, Blawith, vid Ulverston. tLord, Edwin C. E., Ph.D. 247 Washington-street, Brooklyn, U.S.A. tLord, Sir Riley. 75 Pilgrim-street, Newcastle-upon-Tyne. tLoton, John, M.A. 23 Hawkshead-street, Southport. tLoupon, Jams, LL.D., President of the University of Toronto, Canada. *Louis, D. A., F.C.S. 77 Shirland-gardens, W. §Louis, Henry, M.A., Professor of Mining in the Durham College of Science, Newcastle-on-Tyne. *Love, A. E. H., M.A., D.Sc., F.R.S., Professor of Natural Philosophy in the University of Oxford. 84St.Margaret’s-road, Oxford, *Love, E. F. J., M.A. The University, Melbourne, Australia. *Love, James, I’.R.A.S., F.G.S., F.Z.S. 33 Clanricarde-gardens, W. {Love, James Allen. 8 Eastbourne-road West, Southport. *Love, J. B. Outlands, Devonport. *Lovett, W. Jesse. Panton House, Panton-road, Hoole, Chester. §Lowdell, Sydney Poole. Baldwin’s Hill, East Grinstead, Sussex. §Lowdon, John. St. Hilda's, Barry, Glamorgan, *Lowe, Arthur C. W. Gosfield Hall, Halstead, Essex. tLowe, D. T. Heriot’s Hospital, Mdinburgh. *Lowe, John Landor, B.Sc., M.Inst.C.E. Spondon, Derbyshire. tLowenthal, Miss Nellie. 60 New North-road, Hudderstield. *Lowry, Dr. T. Mariry. 44 Blenheim-crescent, W. tLubbock, Arthur Rolfe, High Elms, Farnborough, R.S.O., Kent. {Lubbock, John B. 14 Berkeley-street, W. tLubbock, Montague, M.D. 19 Grosvenor-street, W. tLucas, John. 1 Carlton-terrace, Low Fell, Gateshead. *(ucas, Keith. Greenhall, Forest Row, Sussex. tLucas, Joseph. Tooting Graveney, 5.W. tLuckley, George. The Grove, Jesmond, Neweastle-upon-Tyne. *Lucovich, Count A. Tyn-y-pare, Whitchurch, near Carditf. {Luden, C.M. 4 Bootham-terrace, York. 62 LIST OF MEMBERS, Year of Election. 1866, 1873. 1850. 1892. 1853. 1883. 1874. 1900. 1864. 1898. 1903. 1871. 1899. 1884. 1884. 1874. 1885. 1896, 1862. 1868. 1878. 1904. 1896. 1897. 1896. 1879. 18835. 1883. 1866. 1896. { 1896. 1904. 1896. 1884. 1902. 1886, 1887. 1884. 1904. 1876. 1902. 1868. *Lund, Charles. Ilkley, Yorkshire. {Lund, Joseph. Ilkley, Yorkshire. *Lundie, Cornelius. 32 Newport-road, Cardiff. tLunn, Robert. Geological Survey Office, Sheriff Court-buildings Edinburgh. Pe {Lunn, William Joseph, M.D. 25 Charlotte-street, Hull. *Lupton, Arnold, M.Inst.C.E., F.G.S. 6 De Grey-road, Leeds. *Lupton, Sypnpy, M.A. (Local Sec. 1890.) 102 Park-street Grosvenor-square, W. ‘ {Lupron, Writram C. Bradford. *Lutley, John. Brockhampton Park, Worcester. §Luxmoore, Dr. C. M._ University College, Reading. §Lyddon, Krnest [1. Lisvane, near Carditt. {Lyell, Sir Leonard, Bart., F.G.S. 48 Eaton-place, S.W. tLyle, Professor Thomas R. The University, Melbourne. {Lyman, A. Clarence. 84 Victoria-street, Montreal, Canada, tLyman, 1. H. 74 McTavish-street, Montreal, Canada. tLynam, James. Ballinasloe, Ireland. tLyon, Alexander, jun. 52 Carden-place, Aberdeen. {Lyster, A. G. Dockyard, Coburg Dock, Liverpool. *Lyrn, Ff, Maxwett, M.A., F.C.S, GO Iinborough-road, 8. W. {MACALISTIER, ALEXANDER, M.A., M.D., F.R.S. (Pres. H, 1892; Council, 1901— ), Professor of Anatomy in the University of Oambridge. Torrisdale, Cambridge. csr ie Donatp, M.A.,M.D., B.Sc. St. John’s College, Cam- ridge. §Macalister, Miss M. A. M. Torrisdale, Cambridge. {Macalister, R. A. S. 2 Gordon-street, W.C. t{McAllister, Samuel. 99 Wilcox-street, Toronto, Canada. §Macattum, Professor A. B., Ph.D. (Local Sec, 1897.) 59 St. George-street, Toronto, Canada. Te cecesicdahe James J., F.L.S. Lukesland, Ivybridge, South eyon, {MacAndrew, Mrs. J. J. Lukesland, [vybridge, South Devon. §MacAndrew, William. Westwood House, near Colchester. *M‘Arthur, Alexander. 79 Holland-park, W. McArthur, Charles. Villa Marina, New Brighton, Cheshire, *Macaulay, F.S., M.A. 19 Dewhurst-road, W, *Macaulay, W. H. King’s College, Cambridge. {MacBrrpe, Professor E. W., M.A. MeGill University, Montreal Canada. . {McCabe, T., Chief Examiner of Patents. Patent Office, Ottawa -Canada. : : *Maccall, W. T., M.Sc. 225 Burrage-road, Plumstead. {MacCarthy, Rev. E. F. M., M.A. 93 Hagley-road, Birmingham. *McCarthy, James. Care of Sir Sherston Baker, Bart., 18 Cavendish- road, Regent’s Park, N.W. *McCarthy, J. J., M.D. 83 Wellington-road, Dublin. § McClean, Frank Kennedy. Rusthall House, Tunbridge Wells. *M‘Cretiann, A.S. 4 Crown-gardens, Dowanhill, Glasgow. {McClelland, J. A., M.A., Professor of Physics in University Col- lege, Dublin. {M‘Crrvrock, Admiral Sir Francs L., R.N., K.C.B., FBS. F.R.G.S, United Service Club, Pall Mall, S,W, } LIST OF MEMBERS. 63 Year of Election. 1878. *M‘Comas, Henry. Pembroke House, Pembroke-road, Dublin. 1901. *MacConkey, Alfred. Lister Institute of Preventive Medicine, Chelsea-gardens, 8. W. 1901. {MacCormae, J. M., M.D. 31 Victoria-place, Belfast. 1892, *McCowan, John, M.A., D.Sc. Henderson-street, Bridge of Allan, N.B. 1892. tMcCrae, George. 3 Dick-place, Edinburgh. 1901. ¢{McOrae, John, Ph.D. 7 Kirklee-gardens, Glasgow. 1904, §McCulloch, Major T., R.A. 68 Victoria-street, S.W. 1899. {McDiarmid, Jabez. ‘lhe Elms, Stanmore, Middlesex. 1904, §Macdonald, H. M., M.A., F.R.S. Clare College, Cambridge. 1900, t{MacDonald, J. R. 3 Lincoln’s Inn-fields, W.C. 1890. *MacDonald, Mrs. J. R. 3 Lincoln’s Inn-fields, W.C. 1886. t{McDonald, John Allen. Hillsboro’ House, Derby. 1884, {MacDonald, Kenneth. Town Hall, Inverness. 1884. *McDonald, Sir W. C. 891 Sherbrooke-street, Montreal, Canada. 1884, {MacDonnell, Mrs. F. H. 1483 St. Catherine-street, Montreal, Canada. 1897. }McEwen, William C. 9 South Charlotte-street, Edinburgh. 1902. tMacfadyen, Allan, M.D., B.Sc. Lister Institute of Preventive Medicine, Chelsea-gardens, 8. W. 1881. {Macfarlane, Alexander, D.Sc., F.R.S.E., Professor of Physics in the University of Texas. Austin, Texas, U.S.A. j 1885, {Macfarlane, J. M., D.Sc., F.R.S.E., Professor of Biology in the University of Pennsylvania, Lansdowne, Delaware Co., Penn- sylvania, U.S.A. 1897. t{McFarlane, Murray, M.D. 32 Carlton-street, Toronto, Canada. 1879. tMacfarlane, Walter, jun. 12 Lynedoch-crescent, Glasgow. 1901. tMacfee, John. Marguerite, Blackhall, Paisley. 1897. {McGaw, Thomas, Queen’s Hotel, Toronto, Canada. 1888. t{MacGeorge, James. 7 Stonor-road, Kensington, W. 1884, tMacGillivray, James. 42 Cathcart-street, Montreal, Canada. 1884, {MacGoun, Archibald, jun., B.A., B.C.L. Dunayon, Westmount, Montreal, Canada. 1884, *MacGrecor, James Gorpon, M.A., D.Se., P.R.S., F.RS.E., Professor of Natural Philosophy in the University of Edinburgh, 1885. {M‘Gregor-Robertson, J., M.A., M.B. 26 Buckingham-terrace, Glasgow. 1902. {MclIlroy, Archibald. Glenvale, Drumbo, Lisburn, Ireland. 1867. *McInrosn W. C., M.D., LL.D., F.B.S., F.R.S.E., F.L.S. (Pres. D, 1835), Professor of Natural History in the University of St. Andrews. 2 Abbotsford-crescent, St. Andrews, N.B. 1883. [Mack, Isaac A. Trinity-road, Bootle. 1884. §MacKay, A. H., B.Sc., LL.D., Superintendent of Education. Education Office, Halifax, Nova Scotia, Canada. 1885. §Macxay, Jonn Yur, M.D., LL.D., Principal of and Professor of Anatomy in University College, Dundee. 1897. {McKay, T. W.G., M.D. Oshawa, Ontario, Canada. 1896. *McKechnie, Duncan. Eccleston Grange, Prescot. 1873. {McKxrnprick, Joun G., M.D., LL.D., F.B.S., F.R.S.E. (Pres: I, 1901; Council, 1903- _), Professor of Physiology in the Uni- versity of Glasgow. 2 Buckingham-terrace, Glasgow. 1897. tMcKenzie, John J. 61 Madison-avenue, Toronto, Canada. 1884. {MacKenzie, Stephen, M.D. 18 Cavendish-square, W. 1884. {McKenzie, Thomas, B.A. School of Science, Toronto, Canada. 1901. *Mackenzie, Thomas Brown. Calder View, Motherwell. 1883. {Mackeson, Henry. Hythe, Kent. 1872. *Mackey, J, A, 175 Grange-road, 8.I. 64 LIST OF MEMBERS. Year of Election. 1867. {Macxiz, SAmMugeL Josery. 17 Howley-place, W. 1901. §Mackie, William, M.D. 15 North-street, lgin, 1887. {Macxinppr, H. J.. M.A., F.R.G.S. (Pres. HE, 1895; Council, 1904- .) London School of Mconomics, Clare Market, W.C. 1891. {Mackintosh, A.C. 88 Plymouth-road, Penarth. 1892. {Maclagan, Philip R. D. St. Catherine's, Liberton, Midlothian. 1892. {Maclagan, Rk. Craig, M.D., I.R.S.E. 5 Coates-crescent, Edin- burgh, 1885. *M‘Larey, The Hon, Lord, I’.R.S.E., F.R.A.S. 46 Moray-place, Edinburgh. 1894. *McLaren, Mrs, E. L. Colby, M.B., Ch.B. 4 Duke-street, Edin- burgh, 1897, tMacLaren, J. F. 3880 Victoria-street, Toronto, Canada. 1901. {Maclaren, J. Malcolm. 62 Sydney-street, South Kensington, S.W. ttt tt tt 3. tMacLaren, Walter 5. B. Newington House, Edinburgh. . [MacLaren, Rev. Wm, DD. 57 St. George-street, Toronto, Canada. . {Maclay, James. 38 Woodlands-terrace, Glasgow. . {Maclay, William. Thornwood, Langside, Glascow. . §McLean, Angus, B.Sc. Ascog, Meikleriggs, Paisley. 2. *Mactpan, Macnus, M.A., D.Sc. F.R.S.E. (Local Sec. 1901), Professor of Electrical Engineering, Technical College, Glasgow. . {McLennan, Frank. 317 Drummond-street, Montreal, Canada, . {McLennan, Hugh. 317 Drummond-street, Montreal, Canada. . (McLennan, John. Lancaster, Ontario, Canada. . §McLeop, Hurzrrr, F.R.S. (Pres. B, 1892; Council, 1885-90). 9 Coverdale, Richmond, Surrey. . {Macleod, W. Bowman. 16 George-square, Edinburgh. . {MacManon, Major Poercy A., R.A., D.Sc, F.R.S. (Guenurat Srcretary, 1902- ; Pres. A, 1901; Council, 1893-1902 ) Queen Anne’s-mansions, Westminster, S.W. 2. {McMordie, Robert J. Cabin Hill, Knock, Co. Down, . {MeMurrick, J. Playfair. University of Michigan, Ann Arbor, Michigan, U.S.A. . {M‘Neill, John. Balhousie House, Perth. . {Macnie, George. 59 Bolton-street, Dublin. . {Maconochie, A. W. Care of Messrs. Maconochie Bros., Lowes- toft. . {Macpherson, J. 44 Frederick-street, Edinburgh. MacRitchie, David. 4 Archibald-place, Edinburgh. McWeeney, HE. J.. M.D. 84 Stephen’s-green, Dublin. McWhirter, William. 9 Walworth-terrace, Glasgow. Macy, Jesse. Grinnell, Iowa, U.S.A. Madden, W.H. Marlborough College, Wilts. Magill, R., M.A., Ph.D. The Manse, Maghera, Co. Derry. Magnay, I’. A. Drayton, near Norwich. Macenuts, Sir Putrir, B.Sc. 16 Gloucester-terrace, Hyde Park, W. * . t{Maguire, Thomas Philip. Eastfield, Lodge-lane, Liverpool. 2. t{Mahon, J. LL. 2 May-street, Drumcondra, Dublin. . {Mahony, W. A. 34 College-green, Dublin. . {Mainprice, W.S. Longcroft, Altrincham, Cheshire. . §Maitland, Miss Agnes C. Somerville College, Oxford. 3. tMaitland, P. C. 136 Great Portland-street, W. . {Makarius, Saleem. ‘Al Mokattam,’ Cairo. . t Malcolm, Lieut.-Colonel, R.E. 72 Nunthorpe-road, York. . {Matter, Joan Wittram, Ph.D., M.D., I.R.S., F.C.8., Professor of Chemistry in the University of Virginia, Alhemar’e Co., U.S.A. LIST OF MEMBERS. 65 Year of Election. 1896. 1897. 1887, 1903. 1901. 1888. 1894. 1888. 1891. 1887. 1902. 1870. 1898, 1900. 1887. 1883. 1887, 1864, 1863. 1888, 1888, 1881. 1993. 1887. 1884. 1892. 1883. 1887. 1864. 1889. 1904. 1892. 1890. 1901. 1886. 1849. 1865. 1899. 1891. 1887. 1884. 1889, 1865. 190 *Manbré, Alexandre, 15 Alexandra-drive, Liverpool. tMancs, Sir H.C. 32 Earl’s Court-square, 8. W. {MancuestER, The Right Rev. the Lord Bishop of, D.D. Bishop's Court, Manchester. §Manifold, C. C. 16 St. James’s-square, S.W. {Mann, John, jun., M.A. 137 West George-street, Glasgow. {Mann, W. J. Rodney House, Trowbridge. {Manning, Percy, M.A., F.S.A. Watford, Herts. {MansereH, James, M.Inst.C.E., F.RS, F.G.S. 5 Victoria-street Westminster, 8. W. : tManuel, James. 175 Newport-road, Cardiff. labeee Henry Colley, M.D., F.S.A. Portesham, Dorchester, Dorset- shire. *Marchant, Dr. EZ. W. University College, Liverpool. {Marcoartu, His Excellency Don Arturo de. Madrid. *Mardon, Heber. 2 Litfield-place, Clifton, Bristol. tMargerison, Samuel. Calverley Lodge, near Leeds. }{Margetson, J. Charles. The Rocks, Limpley, Stoke. {Marginson, James Fleetwood. The Mount, Fleetwood, Lancashire, {Markham, Christopher A., F.R.Met.Soc. Spratton, Northampton. tMarxuam, Sir Crewents R., K.C.B., F.R.S., Pres.R.G.S., I'.S.A, (Pres. 2, 1879; Council 1893-96), 21 Kecleston-square, S. W. tMarley, John. Mining Office, Darlington. tMarling, W. J. Stanley Park, Stroud, Gloucestershire. {Marling, Lady. Stanley Park, Stroud, Gloucestershire. *Marr, J. E., M.A., D.Sc, F.RS., F.G.S. (Pres, C, 1896 ; Council 1896-1902). St. John’s College, Cambridge. §Marriott, William. Royal Meteorological Society, 70 Victoria- street, S.W. { Marsden, Benjamin. Westleigh, Heaton Mersey, Manchester. *Marsden, Samuel. 1015 North Leflingwell-avenue, St. Louis, Missouri, U.S.A. *Marsden-Smedley, J. B. Lea Green, Cromford, Derbyshire, *Marsh, Henry. 72 Wellington-street, Leeds. {Marsh, J. E., M.A. The Museum, Oxford. {Marsh, Thomas Edward Miller. 387 Grosvenor-place, Bath. *MarsHAaLt, ALFRED, M.A., LL.D., D.Sc. (Pres. F, 1890), Professor of Political Keonomy in the University of Cambridge, Balliol Croft, Madingley-road, Cambridge. §Marshall, I’. H. A., D.Sc., F.R.S, University of Ndinburgh. tMarshall, Hugh, D.Sc., F.RS., F.R.S.E. 12 Lonsdale-terrace, Edinburgh. tMarshall, John. Derwent Island, Keswick. §Marshall, Robert. 97 Wellington-street, Glasgow. *MARsHALL, WILLIAM Baytzy, M.Inst.C.E. Richmond Iill, Edgbas- ton, Birmingham. *MarsHatt, Wittiam P., M.Inst.C.E, Richmond Hill, Edgbaston, Birmingham, {Marren, Epwarp Brnpon. Pedmore, near Stourbridge, §Martin, Miss A. M. Park View, 32 Bayham-road, Sevenoaks. *Martin, Edward P., J.P. The Hill, Abergavenny, Monmouthshire, *Martin, Rev. H.A. Grosvenor Club, Grosvenor-crescent, S. W. capsid N. H., J.P., F.L.8. Ravenswood, Low Fell, Gateshead-on- ne. *Martin, Thomas Henry, Assoc.M.Inst.C.2, Northdene, Now Barnet, Herts, tMartineau, R. F, 18 Highfield-road, Edghaston, Birmingham, 4, E 66 LIST OF MEMBERS. Year of Election. 1883. t{Marwick, Sir J. D., LL.D., F.R.S.E. (Local Sec. 1871, 1876, 1901.) Glasgow. 1891. {Marychurch, J.G. 46 Park-street, Cardiff. 1873. *Masuam, Lord. Swinton Park, Swinton. 1847, {Masxenyne, Nuvit Story, M.A., D.Sc., F.R.S., F.G.S. (Council 1874-80). Basset Down House, Swindon. 1886. {Mason, Hon. J. EK. Fiji. 1893. *Mason, Thomas. Endersleigh, Alexandra Park, Nottingham. 1891. *Massey, William H., M.Inst.C.E. Twyford, R.S.O., Berkshire. 1885. {Masson, Orme, D.Sc. F.R.S. University of Melbourne, Victoria, Australia. 1898. tMasterman, A. T. University of St. Andrews, N.B. 1901. *Mather, G. R. Boxlea, Wellingborough. 1883. {Mather, Robert V. Birkdale Lodge, Birkdale, Southport. 1887. *Mather, Sir William, M.Inst.C.E. Salford Iron Works, Man- chester. @ 1890, {Mathers, J. S. 1 Hanover-square, Leeds. 1865. {Mathews, C. E. Waterloo-street, Birmingham. 1898, {Mathews, E. R. Norris. Cotham-road, Cotham, Bristol. 1894, {Maruews, G. B., M.A., F.R.S, St. John’s College, Cambridge. 1889, {Mathews, John Hitchcock. 1 Queen’s-gardens, Hyde Park, W. 1881. {Mathwin, Henry, B.A. 26 Oxtord-road, Birkdale, Southport. 1883. {Mathwin, Mrs. H. 26 Oxford-voad, Birkdale, Southport. 1902. {Matley, C. A. 90 St. Lawrence-road, Clontarf, Dublin. 1904. *Matthaei, Miss G. L. C. Newnham College, Cambridge. 1904. §Matthews, D. J. The Laboratory. Citadel Hill, Plymouth. 1868. {Matthews, F.C. Mandre Works, Driffield, Yorkshire. 1899. {Marrurws, WittiAm, C.M.G., M.Inst.C.E. 9 Victoria-street, S.W. 1893. {Mavor, Professor James. University of Toronto, Canada. 1865, *Maw, Guores, F.L.S., F.G.S., F.S.A. Benthall, Kenley, Surrey. 1894. §Maxim, Sir Hiram 8, 18 Queen’s Gate-place, Kensington, 8. W. 1908. {Maxwell, J. M. 387 Ash-street, Southport. *Maxwell, Robert Perceval. Finnebrogue, Downpatrick. 1901. *May, W. Page, M.D., B.Sc. 9 Manchester-square, W. 1884. *Maybury, A. C., D.Sc. 8 Heathcote-street, W.C. 1878, *Mayne, Thomas. 33 Castle-street, Dublin. 1904, §Mayo, Rev. J.. LL.D. 6 Warkworth-terrace, Cambridge. 1871. {Meikle, James, F.S.S. 6 St. Andrew’s-square, Edinburgh. 1879. §Meiklejohn, John W.S., M.D. 105 Holland-road, W. 1887. {Meischke-Smith, W. Rivala Lumpore, Salengore, StraitsSettlements. 1881. *Mrtpora, Rapwakt, F.R.S., F.R.A.S., F.C.S., F.IC. (Pres. B, 1895 ; Council 1892-99), Professor of Chemistry in the Finsbury Technical College, City and Guilds of London Institute. 6 Bruns- wick-square, W.C. 1883, {Mellis, Rev. James. 23 Part-street, Southport. 1879. *Mellish, Henry. Hodsock Priory, Worksop. 1866. {Mzxtxo, Rey. J. M., M.A., F.G.S. Cliff Hill, Warwick. 1883. {Mello, Mrs. J. M. Cliff Hill, Warwick. 1896. §Mellor,G. H. Weston, Blundellsands, Liverpool. 1881. §Melrose, James. Clifton Croft, York. 1887. tMelvill, J. Cosmo, M.A. Kersal Cottage, Prestwich, Manchester. 1863. {Melvin, Alexander. 42 Buccleuch-place, Edinburgh. 1901. {Mennell, F. P. 8 Addison-road, W. t 1862. Mavaatly Henry T. St. Dunstan’s-buildings, Great Tower-street, 1879. {Merrvate, Joun Herman, M.A. (Local Sec. 1889). Togeton Hall, Acklington. LIST OF MEMBERS. 67 Yeat ot flection. 1899. 1880. 1899. 1889. 1863. 1896. 1869. 1903. 1866. 1865. 1881. 1893. 1881. 1904. 1804. 1889, 1886. 1881. 1885. 1889, 1895. 1888. 1885. 1886, 1895. 1834, 1876. 1897. 1902. 1904. 1883. 1880. 1902. 18865. 1882, 1903. 1885. 1898. 1882. 1880. 1859. *Merrett; William H, WHatherley, Grosvenor-roud, Wallington, Surrey. Merry, Alfred 8. Bryn Heulog, Sketty, near Swansea, {Merryweather, J.C. 4 Whitehall-court, S.W. *Merz, John Theodore. The Quarries, Neweastle-upon-T yne. tMessent, P. T. 4 Northumberland-terrace, Tynemouth. {Metzler, W. I., Professor of Mathematics in Syracuse University Syracuse, New York, U.S.A. fMratz, Louis C., F.R.S., F.L.S., F.G.S. (Pres. D, 1897; Local Sec. 1890), Professor of Biology in the University of Leeds. Richmond-mount, Headivgley, Leeds. tMicklethwait, Miss F.G. Queen’s College, Galway. {Middlemore, Thomas. Holloway Head, Birminghum. {Middlemore, William. Edgbaston, Birmingham. “Middlesbrough, The Right Rey. Richard Lacy, D.D., Bishop of. Middlesbrough. tMiddleton, A. 25 Lister-gate, Nottingham. oe R. Morton, F.LS., F.Z.5. 46 Windsor-road, Ealing, y : §Middleton, T. H., M.A., Professor of Agriculture in the University of Cambridge. South House, Barton-road, Cambridge. i *Mirrs, H. A., M.A., F.R.S., F.G.S., Professor of Mineralogy in the University of Oxford. Magdalen College, Oxford. r {Milburn, John D. Queen-street, Newcastle-upon-Tyne. {Miles, Charles Albert. Buenos Ayres. {Mizes, Morris (Local Sec. 1882). Warbourne, Hill-lane, South- ampton. §Mitt, Hueu Ronert, D.Sc., LL.D., F.R.S.E., F.R.G.S. (Pres. E, 1901.) 62 Camden-square, N.W. *Millar, Robert Cockburn. 80 York-place, Edinburgh. Millar, Thomas, M.A., LL.D., F.R.S.E. Perth. }Miller, Henry, M.Inst.C.E. Bosmere House, N orwich-road, Ipswich. {Miller, J. Bruce. Rubislaw Den North, Aberdeen. tMiller, John. 9 Rubislaw-terrace, Aberdeen. tMiller, Rey. John, B.D. The College, Weymouth. {Miller, Thomas, M.Inst.C.E. 9 Thoroughtare, Ipswich. {Miller, T. F., B.Ap.Sc. Napanee, Ontario, Canada. {Miller, Thomas Paterson. Cairns, Cambuslang, N.B. fMiller, Willet G., Professor of Geology in Queen’s University, Kingston, Ontario, Canada. i tMillin, 8S. T, Sheridan Lodge, Helen’s Bay, Co. Down. §Millis, C. T. Hollydene, Wimbledon Park-road, Wimbledon. *Miiis Epuunp J., D.Sc., F.R.S., F.C.S, 64 Twyford-avenue, West Acton, W. JMills, Mansfeldt H., M.Inst.C.E., F.G.S. Sherwood Hall, Mans- field. }Mills, W. Sloan, M.A. Vine Cottage, Donaghmore, Newry. tMilne, Alexander D. 40 Aibyn-place, Aberdeen. *MitnB, Jon, F.R.S., F.G.S, Shide Hill House, Shide, Isle of Wight. *Milne, R. M. Royal Military Academy, Woolwich. tMilne, William. 40 Albyn-place, Aberdeen. *Milner, S. Roslington, D.Sc. University College, Sheffield. }Milnes, Alfred, M.A., F.S.S. 22a Goldhurst-terrace, South Ilamp- stead, N.W. t¢Mincuin, G. M., M.A., F.R.S., Professor of Mathematics in the Royal Indian Engineering College, Cooper's Hill, Surrey. {Mitchell, Alexander, M.D, Old Rain, Aberdeen. H2 68 LIST OF MEMBERS. Year of Election. 1901. 1883, 1883. 1901. 1885. 1895. 1885. 1883. 1877. 1884. 1900. 1887. 1891. 1882. 1892. 1872. 1872. 1896. 1894. 1890. 1901. 1896. 1891. 1901. 1881. 1895. 1873. 1891. 1896. 1902. 1887. 1902. 1882. 1901. 1892. 1889. 1893. 1891. 1883. 1889. 1896. 1881. 1883, 1892. 1883, *Mitchell, Andrew Acworth. 7 IHuntly-gardens, Glasgow. {Mitchell, Charles T., M.A. 41 Addison-gardens North, Kensington, W t{Mitchell, Mrs. Charles T, 41 Addison-gardens North, Kensington, W. *Mitchell, G. A. 5 West Regent-street, Glasgow. {Mitchell, P. Chalmers, M.A., D.Sc ,Sec.Z.S. 3 Hanover-square, W. *Moat, William, M.A. Johnson Hall, Eccleshall, Staffordshire. | {Moffat, William. 7 Queen’s-gardens, Aberdeen. tMollison, W. L., M.A. Clare College, Cambridge. *Molloy, Right Rev. Gerald, D.D. 86 Stephen’s-green, Dublin. t{Monaghan, Patrick. Halifax (Box 317), Nova Scotia, Canada. §Monckton, H. W., F.L.S., F.G.S. 3 Harcourt-buildings, Temple, E.O. *Monp, Lupwie, Ph D., D.Sc., F.R.S., F.C.S. (Pres. B, 1896.) 20 Ayenue-road, Regent's Park, N.W. *Mond, Robert Ludwig, M.A., F.R.S.E., F.G.S. 20 Avenue-road, Regent’s Park, N.W. *Montagu, Sir Samuel, Bart., M.P. 12 Kensington Palace-gardens, W. {Montgomery, Very Rev. J. F. 17 Athole-crescent, Edinburgh. {Montgomery, R. Mortimer. 3 Porchester-place, Edgware-road, W. t{Moon, W., LL.D. 104 Queen’s-road, Brighton. tMoore, A. W., M.A. Woodbourne House, Douglas, Isle of Man. §Moore, Harold E, Oaklands, The Avenue, Beckenham, Kent. {Moore, Major, R.E. School of Military Engineering, Chatham. *Moore, Robert T. 142 St. Vincent-street, Glasgow. *Mordey, W. M. 82 Victoria-street, S.W. tMorel, P. Lavernock House, near Cardiff. *Moreno, Francisco P. La Plata Museum, Argentina. t{Morean, Atrrep. 50 West Bay-street, Jacksonville, Florida, U.S.A {Moraay, C. Lroyn, F.R.S., F.G.S., Principal of University College, Bristol. 16 Canynge-road, Clifton, Bristol. {Morgan, Edward Delmar, F.R.G.S. 15 Roland-gardens, South Kensington, 8. W. tMorgan, F. Forest Lodge, Ruspidge, Gloucestershire. §Morgan, George. 21 Upper Parliament-street, Liverpool. tMorean, Gitpert T., D.Sc. F.1.C. Royal College of Science, S.W. {Morgan, John Gray, 88 Lloyd-street, Manchester. *Morgan, Septimus Vaughan. 387 Harrington-gardens, S.W. {Morgan, Thomas, J.P, Cross House, Southampton, *Morison, James. Perth. {Morison, John, M.D., F.G.S. _ Victoria-street, St. Albans, §Morison, J. Rutherford, M.D. 14 Saville-row, Newcastle-upon- Tyne. tMorland, John, J.P. Glastonbury. {Morley, H. The Gas Works, Cardiff. *Moriey, Henry Forsrur, M.A., D.Sc., F.C.S. 5 Lyndhurst-road, Hampstead, N.W. {Mortry, The Right Hon. Jony, M.A. LL.D. MP. PRS. Flowermead, Wimbledon Park, Surrey. tMorrell, R. S. Caius College, Cambridge. tMorrell, W. W. York City end County Bank, York. {Morris, C. 8. Millbrook Iron Works, Landore, South Wales. si Sir Danret, K.0.M.G., M.A., D.Se., F.L.8, Barbados, West ndies, Morris, George Lockwood. Millbrook Iron Works, Swansea. 1 g' ? LIST OF MEMBERS. 69 Year of Election. 1880. 1896. 1874, 1899. 1865. 1869. 1858. 1887. 1886. 1896, 1878. 1876, 1892, 1878. 1892. 1866. 1878. 1863. 1877. 1899. 1887. 1888. 1884, 1884, 1899. 1894. 1902. 1874, 1904, 1872. 1876. 1902. 1884. 1880. 1904, 1897. 1398. 1901. 1904, 1876. 1901. 1898. §Morris, James. 6 Windsor-street, Uplands, Swansea. *Morris, J. T. 13 Somers-place, W. {Morrison, G. James, M.Inst.C.E. 7 The Sanctuary, Westminster, S.W. §Morrow, Captain Joun, M.Se. 19 LElliston-road, Redland, Bristol. {Mortimer, J. R. St. John’s-villas, Driffield. {tMortimer, William. . Bedford-circus, Exeter. *Morton, Henry Josrrm. 2 Westbourne-villas, Scarborough, tMorton, Percy, M.A. Llltyd House, Brecon, South Wales. *Morton, P. F. 15 Ashley-place, Westminster, S.W. *Morton, Wittiam B., M.A., Professor of Natural Philosophy in Queen’s College, Belfast. *Moss, Jonn Francis, I'.R.G.S. (Local Sec. 1879.) Beechwood, Brincliffe, Sheffield. §Moss, Ricuarp Jackson, F.I.C., M.R.I.A. Royal Dublin Society, and St. Aubyn’s, Ballybrack, Co, Dublin. {Mossman, R. C., F.R.S.E. 10 Blacket-place, idinburgh. {Mossman, William. St. Hilda’s, Frizinghall, Bradford. *Mostyn, S. G., M.A., M.B. Health Office, South Shields. tMort, Freprrick T., .R.G.S. Crescent House, Leicester. *Moutron, J. Frercuer, M.A., K.C., M.P., F.R.S, 57 Onslow- square, S.W. t{Mounsey, Edward. Sunderland. t{Mount-Epecumse, The Right Hon. the Earl of, D.C.L. Mount- Edgcumbe, Devonport. §Mowll, Martyn. Chaldercot, Leyburne-road, Dover. {Moxon, Thomas B. County Bank, Manchester. tMoyle, R. E., M.A., F.C.S. Heightley, Chudleigh, Devon. {Moyse, C. E., B.A., Professor of English Language and Literature in McGill College, Montreal. 802 Sherbrooke-street, Montreal, Canada. {Moyse, Charles E. 802 Sherbrooke-street, Montreal, Canada. *Mutl, Herbert B. Geological Survey Office, Edinburgh. t{Mugliston, Rev. J.. M.A. Newick House, Cheltenham, §Muir, Arthur H.,C.A. 2 Wellington-place, Belfast. tMurr, M. M. Parrison, M.A. Gonville and Caius College, Cam- bridge. §Muir, William. Collector's Office, Custom House, I.C, *MurrgHEaD, ALEXANDER, D.Sc., F.R.S., F.C.S, 12 Carteret-street, Queen Anne’s-gate, Westminster, S.W. *Muirhead, Robert Franklin, M.A., D.Sc. 24 Kersland-street, Hillhead, Glasgow. {Mullan, James. Castlerock, Co. Derry. *Mitier, Hvco, Ph.D., F.R.S., F.C.S. 18 Park-square Fast, Regent’s Park, N.W. tMuller, Hugo M. 1 Griinanger-gasse, Vienna. §Mullinger, J. Bass, M.A. St. John’s College, Cambridge. t¢Mullins, W. E. Hampstead, N.W. {Mumford, C. E. Bury St. Edmunds. *Munby, Alan E. 7 Chalcot-crescent, Primrose Hill, N.W. Munby, Arthur Joseph. 6 Fig Tree-court, Temple, E.C. §Munro, A. Queen’s Colleze, Cambridge. t¢Munro, Donald, M.D., F.C.S. The University, Glasgow. tMunro, Donald, M.D., J.P. Wheatholm, Pollokshaws, Glasgow. tMunro, John, Professor of Mechanical Engineering in the Merchant Venturers’ Technical College, Bristol. 70 LIST OF MEMBERS, Year of Election. 1883. 1855. 1890, 1889. 1884. 1887. 1891. 1884. 1884, 1903. 1872. 1892. 1863, 1897. 1870. 1902. 1902. 1890. 1886. 1892. 1890. 1876, 1872. 1887. 1896. 1887. 1883. 1837. 1855. 1897. 1898. 1866. 1839. 1885. 1901. 1886, 1901. 1889. 1860. 1892. 1867. 1887. *Munro, Roperr, M.A., M.D. (Pres. H, 1893). 48 Manor-place, Edinburgh. {Murdoch, James Barclay. Capelrig, Mearns, Renfrewshire. {Murphy, A. J. Preston House, Leeds. tMurphy, James, M.A., M.D. Holly House, Sunderland. §Murphy, Patrick. Marcus-square, Newry, Ireland. tMurray, A. Hazeldean, Kersal, Manchester. {Murray, G. R. M., F.RS., F.RS.E., F.L.S. British Museum (Natural History), South Kensington, 8. W. {Murray, Sir Joun, K.C.B., LL.D., D.Sc., Ph.D., F.R.S., F.R.S.E. (Pres. E, 1899.) Challenger Lodge, Wardie, Edinburgh. {Murray, J. Clark, LL.D. 111 McKay-street, Montreal, Canada, {Murray, J. D. Rowbottom-square, Wigan. tMurray, J. Jardine, F.R.C.S.E. 99 Montpellier-road, Brighton. {Murray, T.S. 1 Nelson-street, Dundee. tMurray, William, M.D. 9 Ellison-place, Neweastle-on-Tyne. tMusgrave, James, M.D. 511 Bloor-street West, Toronto, Canada, *Muspratt, Edward Knowles, Seaforth Hall, near Liverpooi. {Myddleton, Alfred. 62 Duncairn-street, Belfast. *Myers, Charles S., M.A., M.D. 62 Holland-park, W. *Myres, Joun L., M.A., F.S.A, 1 Norham-gardens, Oxford. {Nacen, D. H., M.A. (Local See. 1894.) Trinity College, Oxford. *Nairn, Sir Michael B., Bart. Kirkcaldy, N.B. §Nalder, Francis Henrv. 34 Queen-street, E.C, {Napier, James S. 9 Woodside-place, Glasgow. {Narrs, Admiral Sir G. S., K.C.B., RN., F.RS., F.R.G.S. 11 Claremont-road, Surbiton. tNason, Professor Henry B., Ph.D. Troy, New York, U.S.A, tNeal, James K., U.S. Consul. 26 Chapel-street, Liverpool, §Neild, Charles. 19 Chapel-walks, Manchester. *Neild, Theodore, B.A. The Vista, Leominster. {Neill, Robert, jun. Beech Mount, Higher Broughton, Manchester. tNeilson, Walter. 172 West George-street, Glasgow. tNesbitt, Beattie S. A., M.D. 71 Grosvenor-street, Toronto, Canada. §Nevill, Rey. J. H. N., M.A. The Vicarage, Stoke Gabriel, South Devon. *Nevill, The Right Rey. Samuel Tarratt, D.D., F.L.S., Bishop of Dunedin, New Zealand. §Nevitte, I. H., M.A., F.R.S. Sidney College, Cambridge. *Newall, IT. Frank, M.A., F.R.S., F.R,A.S. Madingley Rise, Cam- bridge. §Newbigin, Miss Marion, D.Se. 1 Greenbank-road, Morningside, Edinburgh. tNewbolt, F. G. Oakley Lodge, Weybridge, Surrey. {Newman, F. H. ‘Tullie House, Carlisle. ioe A, Hi. L., B.A. 88 Green-street, Bethnal Green, *Newron, ALrred, M.A., F.R.G., F.L.S. (Pres, D, 1887; Council 1875-82), Professor of Zoology and Comparative Anatomy in the University of Cambridge. Magdalene College, Cambridge. LOS, E, T., F.R.S., F.G.S. Geological Museum, Jermyn-street, 2 Wis {Nicholl, Thomas. Dundee. *Nicholson, John Carr, J.P, Moorfield House, Headingley, Leeds, Year of LIST OF MEMBERS, 71 Election. 1884, 1883. 1887. 1895. 1887 1901. 1885. 1896. 1878. 1877. 1863. 1879. 1887. 1863. 1888. 1865, 1872. 1883. 1886. 1894. 1903, 1896, 1898, 1878. 1885. 1858. 1894. 1902. 1896. 1885. 1876. 1885. 1859, 1884, 1881. 1896, 1892. {Nicuotsoy, Josnrm S., M.A., D.Sc. (Pres. F, 1893), Professor of Political Economy in the University of Edinburgh, Eden Lodge, Newbattle-terrace, Edinburgh, { Nicholson, Richard, J.P. Whinfield, Hesketh Parl, Southport, tNicholson, Robert H. Bourchier. 21 Albion-street, Hull, tNickolls, John B., F.C.S. The Laboratory, Guernsey. {Nickson, William. Shelton, Sibson-road, Sale, Manchester, tNrcon, James, City Chamberlain. Glasgow. {Nicol, W. W. J., D.8c., F.R.S.E. 15 Blacket-place, Edinburgh. {Nisbet, J. Tawse. 175 Lodge-lane, Liverpool. {Niven, Coaries, M.A., F.R.S., F.R.A.S., Professor of Natural Philosophy in the University of Aberdecn. 6 Chanonry, Old Aberdeen. tNiven, Professor James, M.A, King’s College, Abérdeen. *Nosie, Sir ANDREW, Bart., K.C.B., D.Sc., F.R.S., F.R.A.S., F.C.S, (Pres. G, 1890; Council, 1903- ; Local Sec. 1863.) Elswick Works, and Jesmond Dene House, Newcastle-upon-Tyne, tNoble, T.S. Lendal, York. {Nodal, John H. The Grange, Heaton Moor, near Stockport. §Norman, Rev. Canon ALFRED Mrrte, M.A., D.C.L., LL.D., F.3.S., F.L.S. The Red House, Berkhamsted. t{Norman, George. 12 Brock-street, Bath. {Norris, Ricuarp, M.D. 2 Walsall-road, Birchfield, Birmingham. tNorris, Thomas George. Gorphwysfa, Llanrwst, North Wales. *Norris, William G. Dale House, Coalbrookdale, R.S.O., Shropshire. Norton, The Right Hon. Lord, K.C.M.G. 35 Eaton-place, 5.W.; and Hamshall, Birmingham. tNorton, Lady. 85 Eaton-place,S.W.; and Hamshall, Birmingham. §Norcurt, S. A., LL.M., B.A., B.Sc. (Local Sec, 1895.) Constitution Hill, Ipswich. {Noton, John, 45 Part-street, Southport. Nowell, John. Farnley Wood, near Huddersfield. tNugent, the Right Rey. Monsignor, Harewood House, Formby, Lancashire, *O’Brien, Neville Forth. Queen Anne’s-mansions, 8.W. {O’Conor Don, The. Clonalis, Castlerea, Ireland. tOdgers, William Blake, M.A., LL.D. 4 Elm-court, Temple, E.C. *Optine, WittraM, M.B., F.R.S., V.P.C.S. (Pres. B, 1864; Coun- cil 1865-70), Waynflete Professor of Chemistry in the Univer- sity of Oxford. 15 Norham-gardens, Oxford. §Ogden, James. Kilner Deyne, Rochdale. §Ogden, James Neal. Claremont, Heaton Chapel, Stockport. tOgden, Thomas. 4 Prince’s-avenue, Liverpool. tOgilvie, Alexander, LL.D. Gordon’s College, Aberdeen. {Ogilvie, Campbell P. Sizewell House, Leiston, Suffolk. tOeitviz, F. Grant, M.A., B.Se., F.R.S.E. (Local Sec. 1892.) Board of Education, 8.W. tOgilvy, Rev. C. W. Norman. Baldan House, Dundee. *Ogle, William, M.D., M.A. The Elms, Duffield-road, Derby. {O’Halloran, J. S.,C.M.G. Royal Colonial Institute, Northumber- land-avyenue, W.C. fOldfield, Joseph, Lendal, York. fOldham, G. 8S. Town Hall, Birkenhead, fOrpnam, H. Yurn, M.A., F.R.G.S., Lecturer in Geography in the University of Cambridge. MKing’s College, Cambridge, 72 LIST OF MEMBERS. Year of Election. 1885. {Oldham, John. River Plate Telegraph Company, Monte Video. 1893. *OrpHAm, R. D., F.G.S., Geological Survey of India. Care of Messrs, H.S. King & Co., 9 Pall Mall, 8.W. 1868, {OniveR, Danter, LL.D.,F.R.S., F.L.S., Emeritus Professor of Botany in University College, London. 10 Kew Gardens-road, Kew, Surrey. 1887. {OLIVER, in W., D.Se., F.L.S., Professor of Botany in University College, London. 2 The Vale, Chelsea, S.W. 1883. §Oliver, Samuel A. Bellingham House, Wigan, Lancashire. 1889, §Oliver, Professor T., M.D. 7 Ellison-place, Newcastle-upon-Tyne. 1882, §Olsen, O. T., F.L.S., F.R.G.S. 116 St. Andrew’s-terrace, Grimsby. 1880. *Ommanney, Rey. i. A. St. Michael’s and All Angels, Portsea, Hants. 1902. {O’Neill, Henry, M.D. 6 College-square East, Belfast. 1902, {O’Neill, James, M.A. 5 College-square Kast, Belfast. 1872. {Onslow, D. Robert. New University Club, St. James's, 8.W. 1883. {Oppert, Gustav, Professor of Sanskrit in the University of Berlin 1902. {O’Reilly, Patrick Joseph. 7 North Earl-street, Dublin. 1899, {Orling, Axel. Moorgate Station-chambers, E.C, 1858. {Ormerod, T. T. Brighouse, near Halifax. 1883. {Orpen, Miss. St. Leonard’s, Kilkenny, Co. Dublin. 1884, *Orpen, Lieut.-Colonel R, T., R.E. Monksgrange, Enniscorthy, Co. Wexford. 1884, *Orpen, Rey. T. H., M.A. Binnbrooke, Cambridge. 1901. §Orr, Alexander Stewart. Care of Messrs. Marsland, Price, & Co., Nesbit-road, Mazagon, Bombay, India, 1904. *Orton, K. J. P., M.A., Ph.D., Professor of Chemistry in University College, Bangor. 1899. {Osborn, Dr. F. A. The Chalet, Dover. 1897. {Osborne, James K. 40 St. Joseph-street, Toronto, Canada. 1901. {Osborne, W. A., D.Sc. University College, W.C. 1887. §O'Shea, L. T., B.Se. University College, Sheffield. 1897. {Osler, I. B., M.P. Rosedale, ‘Toronto, Canada, 1865. *Osler, Henry F. Coppy Hill, Linthurst, near Bromsgrove, Birmingham. 1884, {Oster, WitrtAM, M.D., LL.D., F.RS., Regius Professor of Medicine in the University of Oxford. 1884. { O'Sullivan, James, F.C.S. 71 Spring Terrace-road, Burton-on-Trent, 1882. *Oswald, T, R. Castle Hall, Milford Haven. 1881. *Ottewell, Alfred D, 14 Mill Hill-road, Derby. 1896, {Oulton, W. Hillside, Gateacre, Liverpool. 1882. {Owen, Rev. C. M., M.A. St. George’s, Edgbaston, Birmingham, 1903. *Owen, Edwin, M.A. ‘Terra Nova, Birkdale, Lancashire. 1889. *Owen, Alderman If. C. Compton, Wolverhampton. 1896. §Owen, Peter. The Elms, Capenhurst, Chester. 1903. *Page, Miss Ellen Iva. Turret House, Felpham, Sussex. 1889, tPage, Dr. F, i Saville-place, Newcastle-upon-Tyne. 1883. {Page, George W. Fakenham, Norfolk. 1883. {Page, Joseph Edward. 12 Saunders-street, Southport, 1894, {Paget, Octavius. 158 Fenchurch-street, E.C. 1898. {Paget, The Right Hon. Sir R. H., Bart. Cranmore Hall, Shepton Mallet. 1875. {Paine, William Henry, M.D. Stroud, Gloucestershire. 1870, *Paterave, Rovert Harry Ineus, F.R.S., F.S.8. (Pres. F, 1883.) Belton, Great Yarmouth, LIST OF MEMBERS. 73° Year of Election. 1896, {Pallis, Alexander. Tatoi, Aigburth-drive, Liverpool. 1889, {Patmer, Sir Cuartes Mark, Bart., M.P. Grinkle Park, York- shire, 1878. *Palmer, Joseph Edward. Rose Lawn, Ballybracl, Co. Dublin. 1866. §Palmer, William. Waverley House, Waverley-street, Nottingham. 1886. {Panton, George A., F.R.S.E. 73 Westfield-road, Edgbaston, Birmingham, 1883, {Park, Mrs. Wigan. 1880, *Parke, George Henry, F.L.S., F.G.8. St. John’s, Wakefield, York- shire. 1904. §Parxker, KE, H., M.A. Thorneycreek, Herschel-road, Cambridge. 1898. {Parker, G., M.D. 14 Pembroke-road, Clifton, Bristol. 1903. §Parker, Rey. J. Dunne, LL.D., D.C.L., V.R.A.S. Bennington House, vii Stevenage, Hertfordshire. 1886, {Parker, Lawley. Chad Lodge, Edgbaston, Birmingham. 1899, {Parker, Mark. 30 Upper Fant-road, Maidstone. 1891, {Parker, Witt1am Newton, Ph.D., F.Z.S., Professor of Biology in University College, Cardiff. 1899. *Parkin, John. Blaithwaite, Carlisle. 1879. *Parkin, William. The Mount, Sheffield. 1887. {Parkinson, James. Greystones, Langho, Blackburn. 1859. {Parkinson, Robert, Ph.D. Yewbarrow House, Grange-over-Sands. 1903. §Parry, Joseph, M.Inst.C.E. Woodbury, Waterloo-road, Liverpool. 1883. {Parson, T. Cooke, M.R.C.S. Atherston House, Clifton, Bristol. 1878. {Parsons, Hon. C. A., C.B., M.A., D.Sc, F.R.S., M.Inst.C.E. (Pres. G, 1904.) | Holeyn Hall, Wylam-on-Tyne. 1904. § Parsons, Professor F. G. St. Thomas’s Hospital, 8.E. 1898. *Partridge, Miss Josephine M. 15 Grosvenor-crescent, 8.W. 1898. {Pass, Alfred C. Clifton Down, Bristol. 1887. {ParErson, A. M., M.D., Professor of Anatomy in the University of Liverpool. 1897. {Paterson, John A. 23 Walmer-road, Toronto, Canada. 1896. {Paton, A. A. Greenbank-drive, Wavertree, Liverpool. 1897. {Paton, D. Noél, M.D. 22 Vorrest-road, Edinburgh, 1883. *Paton, Rey. Henry, M.A. 120 Volwarth-terrace, Edinburgh. 1884. *Paton, Hugh. Box 2400, Montreal, Canada, 1902. { Patterson, Robert, F'.Z.S., M.R.I.A. “Ivy Dene, Malone Park, Belfast. 1876. {Patterson, T. L. Maybank, Greenock. 1874. {Patterson, W. IL, M.R.I.A. 26 Hich-street, Belfast. 1863, {Partinson, Jonn, F'.C.S. 75 The Side, Newcastle-upon-Tyne. 1879, *Patzer, F, R. Clayton Lodge, Newcastle, Staffordshire. 1883, {Paul, George. 10 St. Mary’s-avenue, Harrogate. 1892. {Paul, J. Balfour. 80 Heriot-row, Edinburgh. 1863. [Pavy, FrepericK WILLIAM, M.D., F.R.S. 35 Grosvenor-street, W. 1887. *Paxman, James. Stisted Hall, near Braintree, Essex. 1887. *Payne, Miss Edith Annie. Hatchlands, Cuckfield, Ilayward’s Heath. 1881. {Payne, J. Buxton. 15 Mosley-street, Newcastle-upon-Tyne. 1877. *Payne, J. C. Charles, J.P. Albion-place, The Plains, Belfast. 1881. {Payne, Mrs. Albion-place, The Plains, Belfast. 1866, {Payne, Joseph F., M.D. 78 Wimpole-street, W. 1888. *Paynter, J. B. Iendford Manor House, Yeovil. 1886. {Payton, Henry. Wellington-road, Birmingham. 1876. {Peace,G. H. Monton Grange, Eccles, near Manchester. 1879. {Peace, William K. Moor Lodge, Sheffield. 1885. {Peaca, B.N., F.1.S., F.RS.E., F.G.S. Geological Survey Office, Edinburgh. 1875, {Peacock,Thomas Francis, 12 South-square, Gray’s Inn, WC, 74 LIST OF MEMBERS. Year of Election. 1886. *Pearce, Mrs. Horace, Orsett House, Birmingham-road, Kidder- minster, 1886. tPearsall, Howard D. 19 Willow-road, Pmt gns Se NW 1883. {Pearson, Arthur A. Colonial Office, S. W. 1891. {Pearson, B. Dowlais Hotel, Carditt. 1893, *Pearson, Charles E. Hillcrest, Lowdham, Nottinghamshire. 1898. §Pearson, George. Bank-chambers, Baldwin-street, Bristol. 1883. {Pearson, Miss Helen E. Oakhurst, Birkdale, Southport, 1881. {Pearson, John. Glentworth House, The Mount, York, 1883. {Pearson, Mrs. Glentworth House, The Mount, York. 1892. {Pearson, J. M. John Dickie-street, Kilmarnock, 1904. §Pearson, Karl, M.A., F.R.S., Professor of Applied Nisihometee in University College, London, W.C. 1881. {Pearson, Richard. 57 Bootham, York, 1889, {Pease, Howard. Enfield Lodge, Benwell, Newcastle-upon-Tyne. Peckitt, Henry. Carlton Husthwaite, Thirsk, Yorkshire. 1855. *PeckoverR, ALEXANDER, LL.D., F.S.A., F.L.S., F.R.G.S. Bank House, Wisbech, Cambridgeshire. 1888. {Peckover, Miss Alexandrina. Bank House, Wisbech, Cambridgeshire. 1885. { Peddie, W ‘aliam, D.Se., F.RSF. 2 Camer on parks, Edinburgh, 1884, {Peebles, W. EX, 9 North Frederick-street, Dublin, 1878. *Peek, William. Summerslea, Lingfield, Surrey. 1901, *Peel, Hon. William, M.P. 13 King's Bench-walk, Temple, F.C, 1878. {Pemberton, Charles Seaton. 44 Lincoln’s Inn-fields, W.C. 1887. {PenpLEBURY, Wrtttam IL, M.A., F.0.8. (Local Sec, 1899,) Woodford House, Mountfields, Shrewsbury. 1894. §Pengelly, Miss. Lamorna, Torquay. 1897. {PenHALLow, Professor D, P,, M.A. McGill University, Montreal, Canada. 1896. {Pennant, P. P. Nantlys, St. Asaph. 1898. {Pentecost, Rev. Harold, M.A. The School, Giggleswick, Yorkshire, 1889. {Percival, Archibald Stanley, M.A., M.B. 16 Ellison-place, New- castle-upon-Tyne, 1898. {Percival, Francis W., M.A., F.R.G.S. 2 Southwick-place, W. 1895. {Percival, John, M.A., Professor of Botany in the South-Eastern Agricultural College, Wye, Kent. *Perigal, Frederick. Chalcots, Lower Kingswood, Reigate. 1804, Perkin, A. G., F.R.S., F.RS.E., F.C.S., F.LC. 8 Montpelier- terrace, Hyde Park, Leeds. 1902. §Perkin, F. Mollwo, Ph.D. The Firs, Hengrave-road, Honor Oak Park, S.E. 1868. *Prrxin, Wrtttam Henry, Ph.D., LL.D.,D.Sc., F.R.S., F.C.S. (Pres. B, 1876; Council 1880-86), The Chestnuts, Sudbury, Harrow, Middlesex. 1884, {PerKin, WitttaM Henry, jun., LL.D., Ph.D., F.R.S., F.R.S.E. (Pres. B, 1900; Council 1901— ), Professor of Organic Chemistry in the Owens College, Manchester. Fairview, Wilbraham-road, Fallowfield, Manchester. 1864. *Perkins, V. R. Wotton-under-Edge, Gloucestershire. 1898. *Perman, E. P., D.Sc. University College, Cardiff. 1885, {Perrin, Miss Emily. 31 St John’s Wood Park, N.W, 1886. {Perrin, Henry 8. 31 St. John’s Wood Park, N.W. 1886. {Perrin, Mrs. 31 St. John’s Wood Park, N.W. 1874. *PErny, Joun, M. ae D.Se., F.R.S. (GunERAL TREASURER, 1904- ; Pres. G, 1902 ; Council 1901-04), Professor of Mechanics and Mathematics in the Royal College of Science, 8. W, 1883, {Perry, Russell R, 34 Duke-street, Brighton, LIST OF MEMBERS. 75 Year of Election, 1904, *Pertz, Miss D. F. M. 2 Cranmer-road, Cambridge. 1900. §Petavel, J. E. The Owens College, Manchester. 1897. {Peters, Dr. George A. 171 College-street, Toronto, Canada. 1898. {Pethick, William. Woodside, Stoke Bishop, Bristol. 1901. {Pethybridge, G. H. Museum of Science and Art, Dublin. 1883. {Petric, Miss Isabella. Stone Hill, Rochdale. 1895. {Prrriz, W. M. Frinpers, D.C.L., F.R.S. (Pres. H, 1895), Professor of Egyptology in University College, W.C. 1871. *Peyton, John KE. H., F.R.A.S., F.G.S. 13 Fourth-avenue, Hove, Brighton. 1886. {Phelps, Major-General A. 23 Augustus-road, Edgbaston, Birming- am. 1863, *PuEnfé, Joun Samvet, LL.D.,F.S.A., F.G.S., F.R.G.S. 5 Carlton terrace, Oakley-street, S.W. 1896, {Philip, George, jun. Weldon, Bidston, Cheshire. 1903. {Philip, James C. 20 Westfield-terrace, Aberdeen. 1892. {Philip, R. W. M.D. 4 Melville-crescent, Edinburgh. 1870. {Philip, T. D. 51 South Castle-street, Liverpool. 1853. *Philips, Rev. Edward. Hollington, Uttoxeter, Staffordshire. 1853. *Philips, Herbert. The Oak House, Macclesfield. 1877. §Philips, T, Wishart. Elizabeth Lodge, Crescent-road, South Woodford, Essex. 1863, {Philipson, Sir G. H. 7 Eldon-square, Newcastle-upon-Tyne, 1883. {Phillips, Arthur G. 20 Canning-street, Liverpool. 1899. *Phillips, Charles E. S. Castle House, Shooter's Hill, Kent. 1894. {Phillips, Staff-Commander E. C. D., R.N., F.R.G.S. 14 Hargreaves- buildings, Chapel-street, Liverpool. 1887. { Phillips, H. Harcourt, F.C.S. 183 Moss-lane East, Manchester. 1902. {Phillips, J. St. J., BE. 64 Royal-avenue, Belfast. 1890, {Phillips R. W., M.A., D.Se., Professor of Biology in University College, Bangor. 1883. {Phillips,S. Rees. Wonford House, Exeter. 1881. tPhillips, William. 9 Bootham-terrace, York. 1898. {Philps, Captain Lambe. 7 Royal-terrace, Weston-super-Mare, 1884, *Pickard, Rev. H. Adair, M.A. Airedale, Oxford. 1883, “Pickard, Joseph William. Oatlands, Lancaster. 1901. §Pickard, Robert H., D.Se, Isca, Merlin-road, Blackburn. 1894. {Pickarp-Camprines, Rey. O., M.A., F.R.S. Bloxworth Rectory, Wareham. 1885. *Prckerinc, Spencer P. U., M.A., F.R.S. Harpenden, Herts. 1884. *Pickett, Thomas E., M.D. Maysville, Mason Co., Kentucky, U.S.A. 1888, *Pidgeon, W. R. 42 Porchester-square, W. 1865. {Pixz, L.OwEn. 4a Marlborough-gate, Hyde Park, W. 1873. {Pike, W. H., M.A., Ph.D. Toronto, Canada. 1896. *Pilkington, A.C. Rocklands, Rainhill, Lancashire. 1896, *Pilling, William. Rosario, Heene-road, West Worthing. 1877. {Pim, Joseph T. Greenbank, Monkstown, Co. Dublin. 1868, { Pinder, T. R. St. Andrew's, Norwich. 1887. {Pitkin, James. 56 Red Lion-street, Clerkenwell, E.C, 1876, {Pitman, John. Redclift Hill, Bristol. , 1883, { Pitt, George Newton, M.A., M.D, 24 St. Thomas-street, Borough, SL. 1883. {Pitt, Sydney. 16 St. Andrew’s-street, Hoiborn-circus, E.C. 1893, *Pitt, WattTErR, M.Inst.0.E. South Stoke House, near Bath. 1900, *Platts, Walter. Fairmount, Bingley. 1898, {Playne, H.C, 28 College-road, Clifton, Bristol. 1893, {Plowright, Henry J, Ashdown House, Fawley, near Southampton, 76 Year of Election. 1897. 1898. 1899. 1857. 1900. 1881. 1888. 1896. 1904, 1898. 1896. 1862. 1891, 1900, 1892, 1868, 1901. 1883. 1883. 1887. 1883, 1886, 1898. 1873. 1887. 1883. 1894. 1875. 1887. 1867. 1883. 1884. 1869. 1888. 1904, 1892. LIST OF MEMBERS, ° {Plummer, J. H. Bank of Commerce, Toronto, Canada. §Plummer, W. E., M.A., F.R.A.S. The Observatory, Bidston, . Birkenhead. {Plumptre, Fitzwalter. Goodnestone, Dover. tPlunkett, Thomas. Ballybrophy House, Borris-in-Ossory, Queen’s Co., Ireland. *Pocklington, H. Cabourn. 41 Virginia-road, Leeds. §Pocklington, Henry. 20 Park-row, Leeds. { Pocock, Rev. Francis. 4 Brunswick-place, Bath, {Pollard, James. High Down, Hitchin, Herts. : §Pollard, William, 12 Aberdare-gardens, Hampstead, N.W. {PozLeN, Rev. G. C. H., F.G.S. Stonyhurst College, Blackburn, *Pollex, Albert. Tenby House, Egerton Park, Rockferry. *Polwhele, Thomas Roxburgh, M.A., F.G.S8. Poliwiele: Truro, Cornwall. }Pomeroy, Captain Ralph. 201 Newport-road, Cardiff. §Porr, W. J., F.R.S., Professor of Chemistry in the Municipal School of Technology, Manchester. 16 Hope-street, Higher Broughton, Manchester. {Popplewell, W. C., M.Sc., Assoc.M.Inst.C.E. The Yew, Marple, near Stockport. {Porrat, Sir Wynpmam §., Bart. Malshanger, Basingstoke. §Porter, Alfred W., B.Sc. 87 Parliament Hill-mansions, Lissenden- gardens, N.W. *Porter, Rev. C. T., LL.D., D.D. All Saints’ Vicarage, Southport. }Postgate, Professor J. P., M.A. University College, Gower-street, W.C. { Potter, Edmund P. Hollinhurst, Bolton. {Potter, M. C., M.A., I°.L.S., Professor of Botany in the College of Science, Newcastle-upon-Tyne. 14 Highbury, Newcastle-upon- ne. nace. Epwarp B., M.A., F.R.S., F.L.S., F.G.S., F.Z.S. (Pres. D 1896; Council 1895-1901), Professor of Zoology in the Univer- sity of Oxford. Wykeham House, Banbury-road, Oxford. *Poulton, Edward Palmer. Wykeham House, Banbury-road, Oxford. *Powell, Sir Francis 8., Bart., M.P., F.R.G.S8. Horton Old Tall, Yorkshire ; and 1 Cambridge- “square, MZ *Powell, Horatio Gibbs, F.R.G.S. Wood Villa, Tettenhall Wood, : Wolverhampton. {Powell, John. Brynmill-crescent, Swansea. *Powell, Sir Richard Douglas, Bart., M.D. 62 Wimpole-street, Cavendish-square, W. {Powell, William Augustus Frederick. Norland House, Clifton, : Bristol. §Pownall, George H. 20 Birchin-lane, I.C. tPowrie, James. Reswallie, Forfar. {Porntine, J. Il., D.Sc., ERS. (Pres. A, 1899), Professor of Physics in the University of Birmingham, 10 Ampton-road, Edgbaston, Birmingham. *Prankerd, A. A., D.C.L. 66 Banbury-road, Oxford. *PREECE, Sir WILLIAM Henry, K.C.B., F.R.S., M.Inst.C.E. (Pres. G, 1888 ; Council 1888-95, 1896-1902.) Gothic Lodge, Wimbledon Common, Surrey; and 8 Queen Anne’s-gate, S.W. *Preece, W. Llewellyn. Bryn Helen, Woodborough-road, Putney, - S.W §Prentice, Mrs. Manning. Thelema, Felixstowe. §Prentice, Thomas, Willow Park, Greenock, Year of LIST OF MEMBERS, 77 Election. 1889. 1894, 18938. 1884, 1903, 1888. 1875. 1891. 1897. 1897. 1892. 1889. 1876. 1888. 1881. 1863. 1884. 1879. 1872. 1871. 1873. 1867. 1883. 1891. 1903. 1874, 1866, 1878. 1884. 1860. 1898. 1883. 1883, 1868. 1879. 1893, 1894, 1870, §Preston, Alfred Eley, M.Inst.C.., F.G.S. 14 The Exchange, Brad- ford, Yorkshire. tPreston, Arthur E. Piccadilly, Abingdon, Berkshire. *Preston, Martin Inett. 48 Ropewalk, Nottingham. *Prevost, Major L. de T., 2nd Battalion Argyll and Sutherland Highlanders. §Price, Edward E, Oaklands, Oaklands-road, Bromley, Kent. Price, J.T. Neath Abbey, Glamorganshive. }Pricr, L. L. F. R., M.A., F.S.S. (Pres. I, 1895; Council, 1893- 1904.) Oriel College, Oxford. *Price, Rees. 163 Bath-street, Glasgow. tPrice, William. 40 Park-place, Cardiff. : *Price, W. A., M.A, The Mill House, Broomfield, Chelmsford. {Primrose, Dr, Alexander. 196 Simcoe-street, Toronto, Canada. {Prince, Professor Edward E., B.A. Ottawa, Canada. *Pritchard, Eric Law, M.D., M.R.C.S. 70 Fairhazel-gardens, South Hampstead, N.W. *PritcHARD, Urnan, M.D., F.R.C.S. 26 Wimpole-street, W. {Probyn, Leslie C. 79 Onslow-square, 5. W. §Procter, John William. Ashcroft, York. tProctor, R. 8. Grey-street, Newcastle-upon-Tyne. Proctor, William. Elmhurst, Higher Erith-road, Torquay. *Proudfoot, Alexander, M.D. 100 State-street, Chicago, U.S.A. *Prouse, Oswald Milton, F.G.S. Alvington, Ilfracombe. *Pryor, M. Robert. Weston Park, Stevenage, Herts. *Puckle, Rey. T. J.. Chestnut House, Huntingdon-road, Cambridge. tPullan, Lawrence. Bridge of Allan, N.B. *Pullar, Sir Robert, F.R.S.E. Tayside, Perth. *Pullar, Rufus D., F.C.S. Brahan, Perth. tPullen, W. W. F. University College, Cardiff. §Pullen-Burry, Miss. Care of Mrs. Kilyington, Coniston, Avondale- road, South Croydon. . §PumpHrey, Wittiam. (Local Sec. 1888.) 2 Oakland-road, Red- land, Bristol. . §Punnett, R. C. Caius College, Cambridge. . ¢Purpre, Taomas, B.Sc., Ph.D., F.R.S., Professor of Chemistry in the University of St. Andrews. 14 South-street, St. Andrews, N.B. . {Purey-Cust, Very Rey. Arthur Percival, M.A., Dean of York. The Deanery, York. {Porser, Frepertck, M.A. Rathmines Castle, Dublin. {Pursmr, Professor Joun, M.A., LL.D., M.R.DLA. (Pres. A, 1902.) Rathmines Castle, Dublin. tPurser, John Mallet. 3 Wilton-terrace, Dublin. *Purves, W. Laidlaw. 20 ee Oxford-street, W. *Pusey, S. E. B. Bouverie. Pusey House, Faringdon. *Pye, Miss E. St. Mary’s Hall, Rochester. §Pye-Smith, Arnold. Willesley, Park Hill Rise, Croydon. tPye-Smith, Mrs, Willesley, Park Hill Rise, Oroydon. {Pyz-Suiru, P. H., M.D.,F.R.S. 48 Brook-sireet, W.; and Guy’s Hospital, 8.1. tPye-Smith, R. J. 350 Glossop-road, Sheffield. tQuick, James, University College, Bristol. tQuick, Professor W. J, University of Missouri, Columbia, U.S.A, tRabbits, W. T. 6 Cadogan-gardens, 8,W, 28 LIST OF MEMBERS. Year of Election: 1855. 1887. 1898. 1896. 1894. 1863, 1884, 1884. 1861. 1885, 1889. 1876, 1883. 1869. 1901, 1868. 1893. 1863. 1861. 1889. 1903. 1864. 1892. 1874. 1889. 1870. 1887. 1868. 1895. 1883. 1897. 1896. 1902. 1870. 1884. 1899. 1852. 1892, 1889. 1889. 1890, *Radstock, The Right Hon. Lord. Mayfield, Woolston, Southampton. *Ragdale, John Rowland. The Beeches, Stand, near Manchester. *Raisin, Miss Catherine A.; D.Sc. Bedford College, York-place, Baker-street, W. *RamaGeE, Huen. The Technical Institute, Norwich. *RampauT, ARTHUR A., M.A., D.Sc., F.R.S., F.R.A.S., M.R.LA. Radcliffe Observatory, Oxford. tRamsay, ALEXANDER. 2 Cowper-road, Acton, Middlesex, W. tRamsay, George G., LL.D., Professor of Humanity in the University of Glasgow. 6 The College, Glasgow. tRamsay, Mrs. G.G. 6 The College, Glasgow. tRamsay, John. Kildalton, Argyllshire. tRamsay, Major. Straloch, N.B. {Ramsay, Major R.G. W. Bonnyrizg, Edinburgh. *Ramsay, Sir Witx1am, K.C.B., Ph.D., F.R.S. (Pres. B, 1897 ; Council 1891-98), Professor of Chemistry in University College, London. 19 Chester-terrace, Regent’s Park, N.W. tRamsay, Lady. 19 Chester-terrace, Regent’s Park, N.W. *Rance, H. W. Henniker, LL.D. 10 Castletown-road, W. {Rankin, James, M.A., B.Sc. The University, Glasgow. *Ransom, Edwin, F.R.G.S. 24 Ashburnham-road, Bedford. tRansom, W. B., M.D. The Pavement, Nottingham. }Ransom, Witi1amM Henry, M.D.,F.R.S. The Pavement, Nottingham. {Ransome, ArtHuR, M.A., M.D., F.R.S. (Local Sec. 1861.) Sunnyhurst, Deane Park, Bournemouth. Ransome, Thomas. Hest Bank, near Lancaster. tRapkin, J. B. Thrale Hall, Streatham, 8.W. Rashleigh, Jonathan. 8 Cumberland-terrace, Regent’s Park, N.W. §Rastall, R. H. Christ’s College, Cambridge. tRate, Rev. John, M.A. Fairfield, East Twickenham. *Rathbone, Miss May. Backwood, Neston, Cheshire. tRavenster, E. G., F.R.G.S., F.S.S. (Pres. E, 1891.) 2 York- mansions, Battersea Park, S.W. tRawlings, Edward. Richmond House, Wimbledon Common, Surrey. tRawlins, G. W. ‘The Hollies, Rainhill, Liverpool. tRawson, Harry. Earlswood, Hllesmere Park, Eccles, Manchester. *RayteicH, The Right Hon. Lord, M.A., D.C.L., LI..D., F.R.S., T.R.A.S., F.R.G.S. (Presiprnt, 1884; Trusrep,1883-— ; Pres. A, 1882; Council, 1878-83), Professor of Natural Philosophy in the Royal Institution. Terling Place, Witham, Essex. {Raynbird, Hugh, jun. Garrison Gateway Cottage, Old Basing, Basingstoke. *Rayne, Charles A., M.D.. M.R.C.S. St. Mary’s Gate, Lancaster. *Rayner, Edwin Hartree, M.A. 19 Tiviot Dale, Stockport. *Reap, Cuarnes H.,F.S.A. (Pres. H, 1899). British Museum, W.C. tReade, R. H. Wilmount, Dunmurry. {Reapz, Toomas Metrarp, F.G.S. Blundellsands, Liverpool. §Readman, J. B., D.Se., F.R.S.E. 4 Lindsay-place, Edinburgh. tReaster, James William. 68 Linden-grove, Nunhead, S.E. *Reprurn, Professor Prrer, M.D. (Pres. D, 1874.) 4 Lower- crescent, Belfast. tRedgrave, Gilbert R., Assoc.Inst.C.H. The Elms, Westgate-road, Beckenham, Kent. tRedmayne, J M. Harewood, Gateshead. tRedmayne, Norman. 26 Grey-street, Newcastle-upon-Tyne. *Redwood, Loverton, F.R.S.E., F.C.S. Wadham Lodge, Wadham- gardens, N.W. LIST OF MEMBERS. 9 Year of Election. 1861. 1889. 1891. 1894, 1891. 1888. 13875. 1897. 1903. 1901. 1904. 1881 1883. 1903. 1892. 1889. 1901. 1876. 1901. 1904. 1897. 1892. 1887. 1893. 1875. 1863. 1894, 1891. 1903. 1885. 1889, 1904. 1883. 1871. 1900, 1870. 1896. 1877. 1890. 1884, 1899, 1877. 1891. 1891. 1889, tRexp, Sr Epwarp James, K.0.B., F.R.S. Broadway-chambets, Westminster, 8. W. tReed, Rev. George. Bellingham Vicarage, Bardon Mill, Carlisle, *Reed, Thomas A. Bute Docks, Cardiff. *Rees, Edmund 8.G. Dunscar, Oaken, near Wolverhampton. *Rees, I. Treharne, M.Inst.C.E, Blaenypant, near Newport, Mon- mouthshire. tRees, W. L. 11 North-crescent, Bedford-square, W.C. TRees-Mogge, W. Wooldridge. Cholwell House, near Bristol. tReeve, Richard A. 22 Shuter-street, Toronto, Canada. §Reeves, HE. A., F.R.G.S. 1 Savile-row, W. *Reid, Andrew T 10 Woodside-terrace, Glasgow. §Reid, Arthur H. P.O. Box 120, Cape Town. §Reid, Arthur 8., M.A., F.G.S. Trinity College, Glenalmond, N.B. *REID, CLEMENT, F'.R.S., F.L.S., F.G.S. 28 Jermyn-street, S.W. *Reid, Mrs. E. M., B.Sc. 36 Sarre-read, West Hampstead, N.W. tRerp, E. Waymourn, B.A., M.B., F.R.S., Professor of Physiology in University College, Dundee. tReid, G., Belgian Consul. Leazes House, Newcastle-upon-Tyne. *Reid, Hugh. Belmont, Springburn, Glasgow. tReid, James. 10 Woodside-terrace, Glasgow. tReid, John. 7 Park-terrace, Glascow. §Reid, P. J. German Cottage, Marske-by-the-Sea. §Reid, T. Whitehead, M.D. St. George’s House, Canterbury. tReid, Thomas. University College, Dundee. *Reid, Walter Francis. Fieldside, Addlestone, Surrey. tReinach, Baron Albert von. Frankfort s. M., Prussia. tRetnotp, A. W., M.A., F.R.S. (Council 1890-95), Professor of Physics in the Royal Naval College, Greenwich, S.E. tRenats, E. ‘ Nottingham Express’ Office, Nottingham. tRenpatt, Rey. G. H., M.A., Litt.D. Charterhouse, Godalming. *Rendell, Rev. James Robson, B.A. Whinside, Whalley-road, Accrington. §Renpie, Dr. A. B, M.A., F.L.S. 47 Wimbledon Park-road, ‘Wimbledon. tRennett, Dr. 12 Golden-square, Aberdeen, *Rennie, George B. 20 Lowndes-street, S.W. §RevneRT, THEODORE, M.Inst.CE. (Vicse-Presiprnt, 1905.) P.O. Box 92, Johannesbure. *Reynolds, A. H. Bank House, 135 Lord-street, Southport. {Rrynoxps, James Emerson, M.D., D.Sc., F.R.S., Pres.C.S8., M.R.LA. (Pres. B, 1893; Council 1893-99). 29 Campden Hill-court, W. *Reynolds, Miss K. M. 4 Colinette-road, Putney, S.W. *Reynoips, Osporne, M.A., LL.D., F.R.S., M.Inst.C.E. (Pres. G, 1887), Professor of Engineering in the Owens College, Man- chester. 19 Lady Barn-road, Fallowfield, Manchester. t{Rhodes, Albert. Fieldhurst, Liversidge, Yorkshire. *Rhodes, John. 360 Blackburn-road, Accrington, Lancashire. tRhodes, J. M., MD. Ivy Lodge, Didsbury. tRhodes, Lieut.-Colonel William. Quebec, Canada. *Ruys, Professor Joun, D.Sc. (Pres. H, 1900). Jesus College, Oxford. *Riccardi, Dr. Paul, Secretary of the Society of Naturalists. Riva Muro, 14, Modena, Italy. fRichards, D. 1 St. Andrew’s-crescent, Cardiff. tRichards, H. M. 1 St. Andrew’s-crescent, Cardiff. cao, Professor T. W., Ph.D. Cambridge, Massachusetts, 80 LIST OF MEMBERS, Year of Election. 1869. 1882. 1884. 1889. 1884. 1896. 1901. 1870. 1889. 1876. 1891. 1891. 1886. 1883. 1902. 1894. 1861. 1881. 183. 1892. 1892. 1889. 1903. 1900. 1898. 1902. 1887. 1859. 1881. 1879. 1879. 1896. 1904. 1883. 1884. 1883. 1883. 1897. 1897. 1901. 1892. 1886. 1898. 1861. 19038, 1897. 1887, *Richardson, Charles. 8 Cholmley-villas, Long Ditton, Surrey, {Richardson, Rev. George, M.A. Walcote, Winchester. *Richardson, George Straker. Isthmian Club, Piccadilly, W. tRichardson, Hugh, M.A. Bootham School, York. *Richardson, J. Clarke. Derwen Fawr, Swansea. *Richardson, Nelson Moore, B.A., F.E.S. Montevideo, Chickerell, near Weymouth. *Richardson, Owen Willans. Trinity College, Cambridge. tRichardson, Ralph, F.R.S.E. 10 Magdala-place, Kdinburgh. {Richardson, Thomas, J.P. 7 Windsor-terrace, Newcastle-vpon-Tyne. §Richardson, William Haden, City Glass Works, Glasgow, =~ {Riches, Carlton H. 21 Dumfries-place, Cardiff. §Riches, T. Harry. 8 Park-grove, Cardiff. tRichmond, Robert. Heathwood, Leighton Buzzard. *RIDEAL, SAMUEL, D.Sc., F'.C.S. 28 Victoria-street, S.W. §Ridgeway, William, M.A., Professor of Archeology in the Uni- versity of Cambridge. Ten Ditton, Cambridge. §Riptey, i. P., F.G.S. (Local See. 1895.) Burwood, Westerfield- road, Ipswich. {Ridley, John. 19 Belsize-park, [ampstead, N.W. *Rige, Arthur. 15 Westbourne Park-villas, W. *Riae, Epwarp, M.A. Royal Mint, FE. {Rintoul, D., M.A. Clifton College, Bristol. *Rrron, The Most Hon. the Marquess of, K.G., G.C.S.1., C.1E., DG Ly TE Bant ayes nie ee ek ka lan aaa S.W. Ritchie, R. Peel, M.D., F.R.S.E, 1 Melville-crescent, Edinburgh. {Ritson, U. A. 1 Jesmond-gardens, Newcastle-upon-Tyne. *Rivers, W. H. R., M.D, St. John’s College, Cambridge. {Rixon, F. W., B.Sc. 79 Green-lane, Heywood, Lancashire, §Robb, Alfred A. Lisnabreeny House, Belfast. *Roberts, Bruno. 30 St. George’s-square, Regent’s Park, N. W. *Roberts, Evan. 30 St. George’s-square, Regent’s Park, N.W. tRoberts, George Christopher. Hull. {Roberts, R. D., M.A., D.Sc., F.G.S. 4 Regent-street, Cambridge. tRoberts, Samuel, M.P. The Towers, Sheffield. {Roberts, Samuel, jun, The Towers, Sheffield. §Roberts, Thomas J. 33 Serpentine-road, Liscard, Cheshire. *Robertson, Miss Agnes. 9 Klsworthy-terrace, Primrose Hill, N.W. tRobertson, Alexander. Montreal, Canada. { Robertson, E. Stanley, M.A. 43 Waterloo-road, Dublin, tRobertson, George H. Plas Newydd, Llangollen. {Robertson, Mrs. George H. Plas Newydd, Llangollen. §Roprrtson, Sir Grorcr 8., K.C.S.1. (Pres. EB, 1900.) 1 Pump- court, Temple, H.C. §Robertson, Professor J. W. Department of Agriculture, Ottawa, Canada. *Robertson, Robert, B.Sc., M.Inst.C.E, 154 West George-street, Glasgow. tRobertson, W. W. 3 Parliament-square, Edinburgh, *Robinson, C. R. 27 Elvetham-road, Birmingham. §Robinson, Charles E., M.Inst.C.E, Holm Cross, Ashburton, South Devon. tRobinson, Enoch, Dukinfield, Ashton-under-Lyne. §Robinson, G. H. 1 Weld-road, Southport. }Robinson, Haynes, St. Giles’s Plain, Norwich. §Robinson, Henry, M.Inst.C.E, 18 Victoria-street, 8, W, LIST OF MEMBERS. 81 Year of Election. 1902. 1902. 1901. 1878. 1895. 1876. 1899. 1887. 1881. 1875. 1884. 1901. 1865. 1904. 1904. 1891. 1888. 1870. 1872. 1890. 1896. 1896. 1885, 1885. 1866. 1898. 1890. 1883. 1882. 1884. 1889. 1897. 1876, 1891. 1881. 1855, 1883. 1894, 1900. 1885. 1887. 1859. 1902. 1901. {Robinson, Herbert C. Holmfield, Aigburth, Liverpool. {Robinson, James, M.A., I.R.G.S. Dulwich College, Dulwich, 8.E. §Robinson, John, M.Inst.C.E. 8 Vicarage-terrace, Kendal. tRobinson, John L. 198 Great Brunswick-street, Dublin. *Robinson, Joseph Johnson. 8 Trafalgar-road, Birkdale, Southport. {Robinson, M. lv. 6 Park-circus, Glasgow. *Robinson, Mark, M.Inst.C.E. 9 Belsize-crove, N.W. {Robinson, Richard. Belltield Mill, Rochdale. {Robinson, Richard Atkinson. 195 Brompton-road, S.W. *Robinson, Robert, M.Inst.C.. Beechwood, Darlington. {Robinson, Stillman. Columbus, Ohio, U.S.A. {Robinson, T, Eaton. 33 Cecil-street West, Glasgow. {Robinson, T. W. U. Houghton-le-Spring, Durham. §Robinson, Theodore R. 25 Campden Hill-gardens, W. §Robinson, W. H. MLtibblesdale, Cardiff-road, Llandaff. {Robinson, William, M.Inst.C.E., Professor of Engineering in Uni- versity College, Nottingham. {Robottom, Arthur. 3 St. Alban’s-villas, Highgate-road, N.W. *Robson, E. R. Palace Chambers, 9 Bridge-street, Westminster, S.W. *Robson, William. 5 Gillsland-road, Merchiston, Edinburgh. {Rochester, The Right Rey. EH. 8. Talbot, D.D., Lord Bishop of. Kennington Park, 8.E. { Rock, W. H. 73 Park-road East, Birkenhead. tRodger, Alexander M. The Museum, Tay Street, Perth. *Rodger, Edward. 1 Olairmont-gardens, Glasgow. *Rodriguez, Epifanio. New Adelphi Chambers, 6 Robert-street, Adelphi, W.C, {Roe, Sir Thomas. Grovye-villas, Litchurch. {RoeErs, Bertram, M.D. (Local Sec. 1898.) 11 York-place, Clifton, Bristol. *Rogers, L. J., M.A., Professor of Mathematics in the University of Leeds. 15 Regent Park-avenue, Leeds. fRogers, Major R. Alma House, Cheltenham. § Rogers, Rev. Canon Saltren, M.A. 15 Somerset-place, Bath. *Rogers, Walter. Hill House, St. Leonard’s, {Rogerson, John. Croxdale Hall, Durham. tRogerson, John. Barrie, Ontario, Canada, tRoxuit, Sir A. K., M.P., B.A., LL.D., D.C.L., F.R.A.S., Hon, Fellow K.C.L. 45 Belgrave-square, S.W. {Rénnfeldt, W, 43 Park-place, Cardiff, *Roper, W. O. Beechfield, Yealand Conyers, Carnforth. *Roscor, Sir Henry Enrretp, B.A., Ph.D., LL.D., D.C.L., F.R.S. (PRESIDENT, 1887; Pres. B, 1870, 1884; Council 1874-81 ; Local See, 1861.) 10 Bramham-gardens, 8. W. *Rose, J. Holland, Litt.D. 11 Endlesham-road, Balham, S.W. *Rose, T. K., D.Sc, Chemist and Assayer to the Royal Mint. Royal Mint, E. {Rosenhain, Walter, B.A. 185 Monument-road, Edgbaston, Bir- mingham. tRoss, Alexander. Riverfield, Inverness. {Ross, Edward. Marple, Cheshire. *Ross, Rey. James Coulman. Wadworth Hall, Doncaster. §Ross, John Callender. 46 Holland-street, Campden Hill, W. }Ross, Major Ronaxp, O.B., F.R.S., Professor of Tropical Medicine and Parasitology in the University of Liverpool, 36 Bentley- road, Liverpool, 1904, ¥ 82 LIST OF MEMBERS, istion. 1869. *Rossr, The Right Hon. the Earl of, K.P., B.A., D.C.L., LL.D., ERAS., F.R.A.S., M.R.LA. Birr Castle, Parsonstown, Ireland. 1891. *Roth, H. Ling. 32 Prescot-street, Halifax, Yorkshire. 1893. {Rothera, G. B. Sherwood Rise, Nottingham. 1865. *Rothera, George Bell. Hazlewood, Forest-grove, Nottingham. 1901. *Rottenburg, Paul, LL.D. Care of Messrs. Leister, Bock, & Co., 1899 1884 1901 1861 1885. 1903. 1877. 1890. 1881. 1881. 1876, 1885. 1899. 1875. 1892. 1869. 1901. 1904. 1896. 1887. 1904, 1889. 1875. 1884. 1890. 1885, 1852. 1876. 1886. 1852. 1886. 1897. 1891. 1887. 1889. 1897. 1898. 1865, 1903. Glasgow. *Round, J. C., M.R.C.S. 19 Crescent-road, Sydenham Hill, S.E. *Rouse, M.L. Hollybank, Hayne-road, Beckenham. tRouse, W. H. D. Perse School, Cambridge. tRourn, Epwarp J., M.A., D.Sc, F.R.S., F.R.A.S., F.G.S. St. Peter’s College, Cambridge. tRowan, Frederick John. 134 St. Vincent-street, Glaszow. *Rowe, Arthur W., M.B., F.G.8. 1 Cecil-street, Margate. tRowg, J. Brooxina, F.L.S., F.S.A. 16 Lockyer-street, Plymouth. tRowley, Walter, F.S.A. Alderhill, Meanwood, Leeds. *Rowntree, Joun 8. Mount-villas, York. *Rowntree, Joseph. 88 St. Mary’s, York. {Roxburgh, John. 7 Royal Bank-terrace, Glasgow. {Roy, John. 83 Belvidere-street, Aberdeen. {Rubie, G.S. Belgrave House, Follestone-road, Dover. *Rucker, Sir A, W., M.A., D.Sc., F.R.S., Principal of the University of London. (PRrusipenr, 1901; Trusrer, 1898- ; GENERAL TREASURER, 1891-98; Pres. A, 1894; Council 1888-91.) 19 Gledbow-gardens, South Kensington, 8. W. §Riicker, Mrs. Levetleigh, Dane-road, St. Leonards-on-Sea. §Rupter, Ff. W., F.G.S. 18 St. George’s-road, Kilburn, N. W. *Rudorf, C. C. G., Ph.D., B.Sc. 26 Weston-park, Crouch End, N, §Ruhemann, Dr. 8. 3 Selwyn-gardens, Cambridge. *Rundell, T. W., F'.R.Met.Soc. 25 Castle-street, Liverpool. {Ruscoe, John. Ferndale, Gee Cross, near Manchester. §Russell, E. J., D.Se., Professor of Chemistry in the South-Eastern Agricultural College, Wye, Kent. {Russell; The Right Hon. Earl. Amberley Cottage, Maidenhead. *Russell, The Hon. F. A. R. Dunrozel, Haslemere. { Russell, George. 13 Church-road, Upper Norwood, S.L. Russell, John. 39 Mountjoy-square, Dublin. tRussell, Sir J, A., LL.D. Woodville, Canaan-lane, Edinburgh, *Russell, J. W. 131 Woodstock-road, Oxford. *Russell, Norman Scott. Arts Club, Dover-street, W. {Russell, Robert, F.G.8. 1 Sea View, St. Bees, Carnforth. {Russell, Thomas H. 3 Newhall-street, Birmingham. *Russett, Wittram J., Ph.D., F.R.S., V.P.C.S. (Pres. B, 1873; Council 1873-80). 34 Upper Hamilton-terrace, St. John’s ‘Wood, N.W. {Rust, Arthur. Eversleigh, Leicester, {Rutherford, A. Toronto, Canada. a tRutherford, George. Dulwich House, Pencisely-road, Cardiff. . {Rutherford, Wiliam. 7 Vine-grove, Chapman-street, Hulme, Mans chester. {Ryder, W. J. H. 52 Jesmond-road, Newcastle-upon-Tyne. {Ryerson, G.8., M.D. Toronto, Canada. §Ryland, C.J. Southerndon House, Clifton, Bristol. tRyland, Thomas. The Redlands, Erdington, Birmingham. {Sadler, M. E., LL.D., Professor of TEducation in the Victoria University, Manchester. LIST OF MEMBERS, 83 Year of Election. 1883. 1871, 1903. 1881. 1873. 1904, 1887. 1861. 1901, 1894, 1883. 1893, 1872, 1883. 1896. 1896. 1892. 1903. 1886, 1896, 1896. 1901. 1886. 1886, 1900, 1868. 1886. 1903. 1881. 1883, 1846. 1884. 1891. 1887. 1883. 1885. 1901. 1887. 1884, 1883. 1903. 1903, 1879, 1888, {Sadler, Robert. 7 Lulworth-road, Birkdale, Southport. {Sadler, Samuel Champernowne. 186 Aldersgate-street, E.C. §Sagar, J. The Poplars, Savile Park, Halifax. {Salkeld, William. 4 Paradise-terrace, Darlington. *Salomons, Sir David, Bart., F.G.S. Broomhill, Tunbridge Wells. §Salter, A. E., D.Se., F.G.S. 20 Shell-road, Loampit Hill, Lewis- ham, S.E. tSamson, C. L. Carmona, Kersal, Manchester. *Samson, Henry. 6 St. Peter’s-square, Manchester. §Samuel, John S., J.P., F.R.S.E. City Chambers, Glasgow. {Samuetson, The Right Hon. Sir Bernwarp, Bart., F.RS., M.Inst.C.E. 56 Prince’s-gate, S.W. tSanderson, Surgeon-General Alfred. East India United Service Club, St. James’s-square, 8. W. {Sanderson, F. W., M.A. The School, Oundle. §SanpErson, Sir J. S. Burpon, Bart., M.D., D.Se., LL.D., D.C.L., F.R.S., F.R.S.E. (Presipent, 1893; Pres. D, 1889; Council 1877-84). 64 Banbury-road, Oxford. tSanderson, Lady Burdon. 64 Banbury-road, Oxford. Sandes, Thomas, A.B. Sallow Glin, Tarbert, Co. Kerry. §Saner, John Arthur, Assoc.M.Inst.C.E. Highfield, Northwich, tSaner, Mrs. Highfield, Northwich. §Sang, William D. Tylehurst, Kirkcaldy, Fife. tSankey, Captain H. R., R.E, Bawmore, Bilton, Rugby. §Sankey, Percy E. 44 Russell-square, W.C. *Sargant, Miss Ethel. Quarry Hill, Reigate. {Sargant, W. L. Quarry Hill, Reigate. tSarruf, N. Y. ‘Al Mokattam,’ Cairo. tSauborn, John Wentworth. Albion, New York, U.S.A. {Saundby, Robert, M.D. 834 Edmund-street, Birmingham, *Saunder, S. A. Fir Holt, Crowthorne, Berks. {Saunders, A., M.Inst.C.E. King’s Lynn. {Saunders, C. T. Temple-row, Birmingham. *Saunders, Miss E. R. Newnham College, Cambridge. tSaunpers, Howarp, F.L.S., F.Z.S. 7 Radnor-place, W- {Saunders, Rev. J. C. Cambridge. {Saunpers, Tretawnry W.,F.R.G.S. 8 Elmfield-on-the-Knowles, Newton Abbot, Devon. {Saunpprs, Dr. Witt1AM. Experimental Farm, Ottawa, Canada. jSaunders, W. H. R. Llanishen, Cardiff. tSavage, Rey. Canon KE. B., M.A., F.S.A. St. Thomas’ Vicarage, Douglas, Isle of Man. {Savage, W. W. 109 St. James’s-street, Brighton. {Savery, G. M., M.A. The College, Harrogate. {Sawers, W. D. 1 Athole Gardens-place, Glasgow. §Saycge, Rev. A. H., M.A., D.D. (Pres. H, 1887), Professor of Assyriolory in the University of Oxford. Queen’s College, Oxford, jSayre, Robert H. Bethlehem, Pennsylvania, U.S.A. *Scarborough, George. Whinney Field, Halifax, Yorkshire. §Scarisprick, Sir Cuartes, J.P, Scarisbrick Lodge, Southport. {Scarisbrick, Lady. Scarisbrick Lodge, Southport. *Scudrmr, I, A., LL.D., F.R.S., M.R.C.S. (Gen. Sec. 1895-1900; Pres. I, 1894; Council 1887-93), Professor of Physiology in the University of Edinburgh. *Scuarrr, Ropert F’., Ph.D., B.Se., Keeper of the Natural History Department, Museum of Science and Art, Dublin. F2 84 Year of LIST OF MEMBERS. Election. 1880. 1892. 1887. 1883. 1885. 1878. 1847, 1883, 1867. 188]. 1878. 1881. 1889, 1885. 1857. 1884, 1902. 1895. 1883. 1895. 1890. 1859. 1880, 1861. 1891. 1893. 1855, 1879. 1904, 1904. 1897. 1885. 1888, 1888, 1901, 1870. 1892, *Schemmann, Louis Carl. Hamburg. (Care of Messrs, Allen Everitt & Sons, Birmingham.) tSchloss, David F. 1 Knaresborough-place, S.W. tSchofield, T. Thornfield, Talbot-road, Old Trafford, Manchester. tSchofield, William. Alma-road, Birkdale, Southport. §Scholes, L. Arneliffe, Trinity-road, Sale, Cheshire. *ScuustErR, Arruur, Ph.D., F.R.S., F.R.A.S. (Pres. A, 1892; Council 1887-93), Professor of Physics in the Victoria Univer- sity, Manchester. Kent House, Victoria Park, Manchester. *Scnater, Puri Loriey, M.A., Ph.D., F.RS., F.LS., F.G.S., F.R.G.S., F.Z.S. (GpNERAL SECRETARY 1876-81; Pres. D, 1875; Council 1864-67, 1872-75) Odiham Priory, Winchfield. *Scrarer, W. Luriry, M.A., F.Z.8, South African Museum, Cape Town. {Scorr, ALEXANDER. Clydesdale Bank, Dundee. *Scorr, ALEXANDER, M.A., D.Se., F.R.S., Sec.C.S. Royal Institu- tion, Albemarle-street, W. *Scott, Arthur William, M.A., Professor of Mathematics and Natural Science in St. Dayid’s College, Lampeter. {Scott, Miss Charlotte Angas, D.Sc. Bryn Mawr College, Pennsyl- vania, U.S.A. *Scort, D. H., M.A., Ph.D., F.R.S., F.L.S. (GQpnerat SEcRETARY, 1900-03 ; Pres. K, 1896.) The Old Palace, Richmond, Surrey. tScott, George Jamieson. Bayview House, Aberdeen, *Scorr, Rosrrt If., M.A., D.Sc, F.RS., F.R.Met.S. 6 Elm Park- gardens, S.W. *Scott, Sydney C. 28 The Avenue, Gipsy Hill, S.E. §Scott, William R. The University, St. Andrew’s, Scotland. {Scott-Elliot, Professor G. I*., M.A., B.Se., F.L.8. Ainslea, Scots- tounhill, Glasgow. tSerivener, Mrs. Haglis Tlouse, Wendover. §Scull, Miss I. M. L. The Pines, 10 Langland-gardens, Hamp- stead, N.W. *Searle, G. F.C., M.A. Wyncote, Hills-road, Cambridge. tSeaton, John Love. The Park, Hull. {Sepewicx, Apam, M.A.,F.R.S. (Pres. D, 1899.) 4 Cranmer-read, Cambridge. *SEELEY, Harry Govirr, F.RS., F.LS., F.G.S., F.R.G.S., F.Z.S., Professor of Geology in King’s College, Londen. 25 Palace Gardens-terrace, Kensington, W. {Selby, Arthur L., M.A., Assistant Professor of Physics in University College, Cardiff. {Setny-Biecr, L., A., M.A. Charity Commission, Whitehall, S.W. {Selieman, H. L. 27 St. Vincent-place, Glasgow. }Selim, Adolphus, 21 Mincing-lane, E.C. §Sell, W. J. 19 Lensfield-road, Cambridge. §Sella, Professor Alfonso. Istituto Fisico, Rome. {Selous, F. C., F.R.G.S. Alpine Lodge, Worplesden, Surrey. jSemple, Dr. A. United Service Club, Edinburgh. *SENIER, ALFRED, M.D., Ph.D., F.C.S., Professor of Chemistry in Queen’s College, Galway. *Sennetr, ALFRED R., A.M.Inst.C.E. 304 King’s-road, Chelsea, S.W. {Service, Robert. Janefield Park, Maxwelltown, Dumfries, *Sephton, Rey. J. 90 Huskisson-street, Liverpool. {Seton, Miss Jane, 37 Candlemaker-row, Edinburgh. Year LIST OF MEMBERS. 85 of Election. 1895. *Seton-Karr, If. W. 51 Lingfield-road, Witibledon; Survey. 1892. *Sewaxp, A.C., M.A. F.RS., F.G.S. (Pres, K,1903; Council, 1901; 1891. 1868, 1904. 13899, 1891, 1888. 1904, 1902. 1867. 1881, 1878. 1904. 1886, 1904, 1883. 1904, 1870. 1896. Local Sec. 1904.) Westfield, Huntingdon-road, Cambridge. {Seward, Edwin. 55 Newport-road, Cardiff. {Sewell, Philip E. Catton, Norwich. §Sewell, R, B, Seymour, Christ’s College, Cambridge. . §Seymour, Henry J., B.A., F.G.S. St. Peter's, Ailesbury-road; Dublin. {Shackell, E. W. 191 Newport-road, Cardiff. {Shackles, Charles F. Hornsea, near Hull. §Shackleton, Ernest H. Royal Scottish Geographical Society, Edinburgh. es, The Right Hon, the Earl of, D.L. Belfast Castle, Belfast. {Shanks, James. Dens Iron Works, Arbroath, N.B. {Shann, George, M.D. Petergate, York. {Smarr,, Davin, M.A., M.B., F.R.S., F.L.S. Museum of Zoology, Cambridge. §Sharp, Mrs. E. M. Drumna House, Whetstone, N. {Sharp, T. B. French Walls, Birmingham. §Sharp, Walter. Drumna House, Whetstone, N. {Sharples, Charles H. 7 Fishergate, Preston. §Sharples, George. 181 Great Cheetham-street West, Higher Broughton, Manchester. {Shaw, Duncan. Cordova, Spain. {Shaw, Frank, Ellerslie, Aigburth-drive, Liverpool, 1870. {Shaw, John. 21 St. James’s-road, Liverpool. 1891. 1889. 1883. 1883. 1904. 1903. 1891, 1878. {Shaw, Joseph. 1 Temple-gardens, F.C. *Shaw, Mrs. M. 8., B.Sc. Sydenham Damard Rectory, Tavistock. *Suaw, W.N., M.A., D.Sc., F.R.S. (Council 1895-1900, 1904-.) Meteorological Office, Victoria-street, S.W. {Shaw, Mrs. W. N. 10 Moreton-gardens, South Kensingten, S.W. §Shaw-Phillips, Miss. 19 Camden-crescent, Bath. §Shaw-Phillips, T., J.P. 19 Camden-crescent, Bath. {Sheen, Dr. Alfred. 23 Newport-road, Cardiff. Shelford, Sir William, K.C.M.G., M.Inst.C.E. 35a Great George- street, S.W. 1865. {Shenstone, Frederick S. Sutton Hall, Barcombe, Lewes. 1881. 1885. {Suenstonz, W. A., F.R.S, Clifton College, Bristol. {Shepherd, Rey. Alexander. Ecclesmechen, Uphall, Edinburgh. 1890. {Shepherd, J. 80 Prince of Wales-mansions, Battersea, S.W. 1883. 1900. 1883. 1883, 1883. 1896. 1888. 1886. 1892, 19Ci. 1902. 1883. {Shepherd, James, Birkdale, Southport. §Sheppard, Thomas, F.G.S. The Municipal Museum, Hull. {Sherlock, David. Rahan Lodge, Tullamore, Dublin. {Sherlock, Mrs, David. Rahan Lodge, Tullamore, Dublin. {Sherlock, Rey. Edgar, Bentham Rectory, vid Lancaster. §SHerrineron, C. 8, M.D, IRS. (Pres. I, 1904), Professor of Physiology in the University of Liverpool. 16 Grove-park, Liverpool. *Shickle, Rev. C. W., M.A., F.S.A. St. John’s Hospital, Bath {Shield, Arthur H. 35a Great George-street, S.W. {Shields, John, D.Se., Ph.D. Dolphingston, Tranent, Scotland tShields, Thomas, M.A., B.Sc. Englefield Green, Surrey. ; *Shillington, T. Foulkes, J.P. Dromart, Antrim-road, Belfast. *Shillitoe, Buxton, F.R.C.S. 2 Frederick-place, Old Jewry, E.C. 1887. *Sairtey, Artuur FE., M.A.,F.R.S. (Council 1904- .) Christ’s College, Cambridge. 86 LIST OF MEMBERS. Year of Election. 1889, {Shipley, J. A. D. Saltwell Park, Gateshead. 1885, {Shirras,G. F. 16 Carden-place, Aberdeen. 1883. {Shone, Isaac. Pentrefelin House, Wrexham. 1870. *SHoorsren, J. N., B.A., M.Inst.C.E. 47 Victoria-street, 8. W. 1888. {Shoppee, C. H. 22 John-street, Bedford-row, W.C. 1897. {Suorn, Dr. Lewis E. St. John’s College, Cambridge. 1875. {Suorzn, Tomas W., F.G.S. 157 Bedford-hill, Balham, S.W. 1882, {Suorn, T. W., M.D., B.Sc., Lecturer on Comparative Anatomy at St. Bartholomew's Hospital. Heathfield, Alleyn Park, Dul- wich, S.E. 1901. §Short, Peter M., B.Sc. 1 Holmdene-ayenue, Herne Hill, 8.E. 1897. {Shortt, Professor Adam, M.A. Queen’s University, Kingston, Ontario, Canada. 1904. *Shrubsall, F. C., M.A., M.D. Brompton Hospital, 8.W. 1889, {Sibley, Walter K., B.A., M.B. 8 Duke Street-mansions, Grosvenor- square, W. 1883. {Sibly, Miss Martha Agnes, Flook House, Taunton. 1902. {Siddons, A. W. Harrow-on-the-Hill, Middlesex. 1883, *Sidebotham, Edward John. Erlesdene, Bowdon, Cheshire. 1877. *Sidebotham, Joseph Watson. Merlewood, Bowdon, Cheshire. Sidney, M. J. I’. Cowpen, Neweastle-upon-Tyne. 1883. *Sidebotham, James Nasmyth. Parkfield, Altrincham, Cheshire. 1873. *Srmmens, ALEXANDER, M.Inst.C.E, 12 Queen Anne’s-gate, S.W. 1903, *Silberrad, Dr. Oswald, Experimental Ustablishment, Royal Arsenal, Woolwich. 1859. {Sim, John. Hardgate, Aberdeen. 1871. {Sime, James. Craigmount House, Grange, Edinburgh. 1898, {Simmons, Henry. Kingsland House, Whiteladies-road, Cliftun, Bristol. : 1862, {Simms, James. 138 Fleet-street, I.C. 1874. {Simms, William. Upper Queen-street, Belfast. 1876. {Simon, Frederick. 24 Sutherland-gardens, W. 1901. {Simpson, Rey. A., B.Se., F.G.8. 28 Myrtle-park, Crossbill, Glasgow. 1871. *Srmpson, ALEXANDER R., M.D., Professor of Midwifery in the Uni- versity of Edinburgh. 52 Queen-street, Edinburgh, 1887. {Simpson, F. Estacion Central, Buenos Ayres. 1863. {Simpson, J. B., F.G.8. Hedgefield House, Blaydon-on-Tyne, 1901. *Simpson, J. Y., M.A., D.Sc., F.R.S.E. 52 Queen-street, Edinburgh. 1894. §Simpson, Thomas, I’.R.G.S, Fennymere, Castle Bar, Ealing, W. 1883. {Simpson, Walter M. 7 York-road, Birkdale, Southport, 1896. *Simpson, W., F.G.S, Catteral Hall, Settle, Yorkshire. 1887. {Sinelair, Dr. 268 Oxford-street, Manchester, 1874. {Srncrarr, Right Hon. Tomas (Local See, 1874). Dunedin, Belfast. 1897. {Sinnott, James, Bank of England-chambers,12 Broad-street, Bristol. 1864. *Sircar, The Hon. Mahendra Lal, M.D., O.I.E, 51 Sankaritola, Cal- cutta. 1892, {Sisley, Richard, M.D. 1 Park-row, S.W. 1902. §Skeffington, J. B., M.A., LL.D. Waterford, 1883, {Skillicorne, W. N. 9 Queen’s-parade, Cheltenham. 1885, {Skinner, Provost. Inverurie, N.B. 1898, §SKINNER, Sipney, M.A. (Local Sec. 1904.) South-\Western Polytechnic, Manresa-road, Chelsea, S.W 1889, §Siater, Matthew B., F.L.S. Malton, Yorkshire, 1877. lesan, Leys Philip, L.Th., F.R.A.S, 65 Pembroke-road, Clifton, ristol, , 1891. §Slocombe, James, Redland House, Fitzalan, Cardiff. Year of LIST OF MEMBERS. 87 Election. 1849, 1887. 1887, 1903. 1904. 1889, 1902. 1898. 1876. 1877. 1890. 1876. 1867. 1892. 1897. 1901. 1874, 1887. 1873. 1887. 1889, 1886, 1886. 1886. 1900. 1886, 1892, 1897. 1901, 1866, 1885, 1897. 1860. 1903. 1870, 1889, 1888. 1876. 1902. 1901. 1885. 1903. 1883. 1885. {Sloper, George Elgar. Devizes. §Small, Evan W., M.A., B.Sc., F.G.S. The Mount, Radbourne-street, Derby. §Small, William. Lincoln-circus, The Park, Nottingham. *Smallman, Raleigh 8. Wressil Lodge, Wimbledon Common, §Smart, Edward. Benview, Craigie, Perth, N.B. *Smart, Professor William, LL.D. (Pres. F, 1904.) Nunholme, Dowanhill, Glasgow, §Smedley, Miss Ida. 11 Mecklenburgh-square, W.C. {Smeeth, W. F., M.A., F.G.8. Mysore, India. {Smellie, Thomas D. 213 St. Vincent-street, Glasgow. tSmelt, Rev. Maurice Allen, M.A., F.R.A.S. Heath Lodge, Chel- tenham. {Smethurst, Charles. Palace House, Harpurhey, Manchester. {Smieton, James, Panmure Villa, Broughty lerry, Dundee. {Smieton, Thomas A. Panmure Villa, Broughty Ferry, Dundee. {Smith, Alexander, B.Sc., Ph.D., F.R.S.E. The University, Chicago Illinois, U.S.A. {Smith, Andrew, Principal of the Veterinary College, Toronto, Canada, *Smith, Miss Annie Lorrain. 20 Talgarth-road, West Kensington, W. *Smith, Benjamin Leigh, F.R.G.S. Oxford and Cambridge Club, Pall Mall, 5. W. {Smith, Bryce. Rye Bank, Chorlton-cum-Hardy, Manchester. {Smith, C. Sidney College, Cambridge. *Smith, Charles. 759 Rochdale-road, Manchester. *Smith, Professor C. Michie, B.Sc., F.R.S.E., F.R.A.S, The Ob- servatory, Kodaikanal, South India. {Smith, Edwin. 33 Wheeley’s-road, Edgbaston, Birmingham. *Smith, Mrs. Emma. Hencotes House, Hexham. {Smith, KE. Fisher, J.P. The Priory, Dudley. §Smith, E. J. Grange House, Westgate Hill, Bradford. {Smith, E. 0. Council House, Birmingham. {Smith, E. Wythe. 66 College-street, Chelsea, S.W. {Smith, Sir Frank, 54 King-street East, Toronto, Canada. §Smith, F. B. Care of A. Croxton Smith, Esq., Burlington House, Wandle-road, Upper Tooting, 8. W. *Smith, F.C. Bank, Nottingham. {Smith, Rev. G. A., M.A. 22 Sardinia-terrace, Glasgow. {Smith, G. Elliot, M.D. St. John’s College, Cambridge. *Smith, Heywood, M.A.,M.D. 25 Welbeck-street, Cavendish-square, W, *Smith, H. B. Lees. 16 Park-terrace, Oxford. {Smith, H. L. Crabwali Hall, Cheshire. *Smith, H. Llewellyn, C.B., B.A., B.Sc., F.S.8. 49 St. George’s- square, S.W. {Smith, H. W. Owens College, Manchester. *Smith, J. Guthrie. 5 Kirklee-gardens, Kelvinside, Glasgow. ; {Smith, J. Lorrain, M.D., Professor of Pathology in the Victoria University, Manchester. {Saara, Right Hon. J. Parker, M.P. Jordanhill, Glasgow. {Smith, Rev. James, B.D. Manse of Newhills, N.B. §Smith, James, Pinewood, Crathes, Aberdeen. : Smith, John Peter George. Sweyney Cliff, Coalport, Iron Bridge, Shropshire. pa {Smith, M. Holroyd. Royal Insurance-buildings, Crossley-street, Halifax. {Suuru, Ropert H., Assoc.M.Inst.C.E, Ellerslie, Sutton, Surrey. - 88 LIST OF MEMBERS. Year of Election. 1873. 1867. 1894. 1892. 1885, 1896, 1852. 1876, 1885. 1885. 1883. 1882. 1874. 1857. 1888. 1889, 1898. 1879, 1892. 1900. 1859, 1879. 1901. 1888. 1903. 1886. 1903. 1865, 1883. 1890. 1893. 1887. 1884. 1889. 1864, 1894, 1864, 1864. 1854, 1883. 1897. 1888, 1897. 1903, 1883. {Smith, Sir Swire. Lowfield, Keighley, Yorkshire. Smith, Thomas. Poole Park Works, Dundee. §Smith, T. Walrond. Care of Frank Henderson, Esq., 25 Pearfield- road, Forest Hill, 8.14. {Smith, Walter A. 120 Princes-street, Edinburgh. *Smith, Watson, 54 Upper Park-road, Haverstock Hill, N.W. *Smith, Rev. W. Hodson. Newquay, Cornwall. {Smith, William, Eglinton Engine Works, Glasgow, {Smith, William, 12 Woodside-place, Glasgow. {Smirmects, Arruur, B.Se., F.R.S, (Local Sec. 1890), Professor of Chemistry in the University of Leeds, Smithson, Edward Walter. 13 Lendal, York, {Smithson, Mrs. 15 Lendal, York. {Smithson, T, Spencer, Facit, Rochdale. tSmoothy, Frederick. Bocking, Essex. *Smyro, Jonny, M.A., F.C.S., F.R.M.S., M.Inst.C.1.1 Milltown, Banbridge, Ireland. *Snare, H. Lioyp, D.Sc., Ph.D. Balholm, Lathom-road, Southport. {Snell, W. Ii. Lancaster Lodge, Amersham-road, Putney, 8. W. {Snook, Miss L. B. V. 13 Clare-road, Cotham, Bristol. *Sottas, W. J., M.A., D.Sc., F.RBS., I.R.S.E., F.G.S. (Pres. C, 1900 ; Council 1900-03), Professor of Geology in the University of Oxford. 173 Woodstock-road, Oxford. *SOMERVAIL, ALEXANDER. ‘The Museum, Torquay. *SoMERVILLE, W., D.Sc. Board of Agriculture, Whitehall, 8. W. *Sorsy, H. Crirron, LL.D., F.R.S., F.G.S. (Pres. C, 1880; Council 1879-86 ; Local Sec. 1879). Broomfield, Sheftield. *Sorby, Thomas W. Storthfield, Ranmoor, Sheffield. }Sorley, Robert, The Firs, Partickill, Glasgow. {Sortey, Professor W. R., M.A. Trinity College, Cambridge. {Soulby, R. M. Sea Holm, Westbourne-road, Birkdale, Lancashire. {Southall, Alfred. Carrick House, Richmond Hill-road, Birmingham. §Southall, Henry T, The Graig, Ross, Herefordshire. *Southall, John Tertius. Parktields, Ross, Herefordshire. {Spanton, William Dunnett, F.R.C.S, Chatterley Ilouse, Hanley, Staffordshire, {Spark, F. R. 29 Hyde-terrace, Leeds. *Speak, John, Kirton Grange, Kirton, near Boston. {Spencer, F. M. Fernhill, Knutsford. {Spencer, John, M.Inst.M.E, Globe Tube Works, Wednesbury, *Spencer, John. Newbiggin House, Kenton, Newcastle-upon-Tyne. *Spicer, Henry, B.A., F.L.S., F.G.8. 14 Aberdeen-park, High- buy, N. {Spiers, A. H. Gresham’s School, Holt, Norfolk. *Srinier, JouHn, F.C.S. 2 St. Mary’s-road, Canonbury, N. *Spottiswoode, W. Hugh, F.C.S. 107 Sloane-street, 8. W. *SpracuE, Tuomas Bonn, M.A., LL.D. VRS LE, 29 Buckingham- terrace, Edinburgh. {Spratling, W. J., B.Sc., F.G.S8, Maythorpe, 74 Wickham-road, Brockley, 8.15. §Squire, W. Stevens, Ph.D, Clarendon House, 30 St. John’s Wood Park, N.W. *Stacy, J. Sargeant. 164 Shoreditch, E.C. {Stafford, Joseph. Morrisburg, Outario, Canada. §Stallworthy, Rey. George B. The Manse, Hindhead, Haslemere, Surrey. “Stanford, Edward, F.R.G.S. 12-14 Long-acre, W.C. LIST OF MEMBERS. §9 Year of Election. 1881. 1883. 1894. 1900. 1899. 1876. 1899. 1898. 1894. 1873. 1900. 1881. 1881. 1884, 1892. 1896, 1891. 1884. 1884. 1884, 1902. 1901, 1901. 1880, 1900. 1892. 1863. 1890. 1885. 1864, 1892. 1885. 1886. 1875. 1901. 1892. 1901, 1901, 1901. 1867. 1876. 1867. 1904. “Stanley, William Ford, F.G.S, Cumberlow, South Norwood, S.E. {Stanley, Mrs. Cumberlow, South Norwood, 8.1. “STANSFIELD, ALFRED, D.Sc. McGill University, Montreal, Canada *Stansfield, H., B.Sc. Municipal Technical School, Blackburn. {Srarrine, Li. H., M.D, F.R.S., Professor of Physiology in University College, London, W.C, {Starling, John Henry, F.C.S. 32 Craven-street, Strand, W.C. §Statham, William, The Redings, Totteridge, Herts. tStather, J. W., F.G.S. 16 Louis-street, Hull. Staveley, T. K. Ripon, Yorkshire. {Stavert, Rev. W. J., M.A. Burnsall Rectory, Skipton-in-Craven. Yorkshire. *Stead, Charles. Red Barns, Freshfield, Liverpool. *Stead, J, E., F.R.S. Laboratory and Assay Ottice, Middlesbrough. {Stead, W. H. Orchard-place, Blackwall, I. {Stead, Mrs. W. H. Orchard-place, Blackwall, E. {Stearns, Sergeant P, U.S. Consul-General, Montreal, Canada. *Sresbine, Rey. Thomas R.R., M.A., F.R.S, Ephraim Lodge, The Common, Tunbridge Wells. : *Stebbing, W. P. D., F.G.S. 169 Gloucester-terrace, W. {Steeds, A. P. 15 St. Helen’s-road, Swansea. {Stephen, George. 140 Drummond-street, Montreal, Canada. {Stephen, Mrs. George. 140 Drummond-street, Montreal, Canada. *Stephens, W. Hudson. Low-Ville, Lewis County, New York, ULS.A. §Stepkenson, G. Cuilin, Glasneyin, Dublin, {Steven, William, 420 Sauchieball-street, Glasgow. {Steven, Mrs. W, 420 Sauchiehall-street, Glasgow. *Stevens, J. Edward, LL.B. Le Mayals, Blackpill, R.S.O. {Srkvens, Freperick (Local Sec. 1900.) Town Clerk's Office, Bradford. {Stevenson, D. A,, B.Sc., F.R.S.E., M.Inst.C.E. 84 George-street, Edinburgh. *Strevrenson, James C., M.P. Eltham Court, Eltham, Kent. *Steward, Rey. Charles J., F.R.M.S, The Cedars, Anglesea-road, Ipswich. *Stewart, Rev. Alexander, M.D., LL.D. Murtle, Aberdeen. {Srewart, Cuartes, M.A., F.R.S., F.L.S., Hunterian Professor of Anatomy and Conservator of the Museum, Royal College of Surgeons, Lincoln’s Inn-fields, W.C. {Stewart, C. Hunter. 3 Carlton-terrace, Edinburgh. {Stewart, David. Banchory House, Aberdeen. *Stewart, Duncan. 14 Windsor-terrace West, Kelvinside, Glasgow. *Stewart, James, B.A., F.R.C.P.Ed. Dunmurry, Sneyd Park, near Clifton, Gloucestershire. *Stewart, John Joseph, M.A., B.Sc. 85 Stow Park-ayenue, New- port, Monmouthshire. {Stewart, Samuel. Knocknairn, Bagston, Greenock. §Stewart, Thomas. St, George’s-chambers, Cape Town. {Stewart, Walter, M.A., D.Sc, Gartsherrie, Coatbridge. {Stewart, William. Violet Grove House, St. George’s-road, Glasgow. {Stirling, Dr. D. Perth. {Srretine, Witr1aM, M.D., D.Se., F.R.S.E., Professor of Physiology in the Owens College, Manchester. *Stirrup, Mark, F.G.S. Stamford-road, Bowdon, Cheshire, §Stobbs, J. T. Dunelm, Basford Park, Stoke-on-Trent. 90 LIST OF MEMBERS. Year of Election. 1901, 1865. 1890, 1885. 1898, 1898, 1887. 1899. 1886. 1886. 1874, 1876, 1857. 1895, 1878. 1861, 1903. 1883. 1887. 1884, 1888. 1874, 1871. 1881, 1863. 1882. 1881. 1889. 1879. 1884, 1883. 1898. 1887. 1887. 1876. 1872. 1884, 1892. 1896, 1885. 1897. 1879. 1891. gach ae Somerset House, Garelochhead, Dumbartonshire, *Stock, A Tosoph S. St. Mildred’s, Walmer. {Stockdale, R, The Grammar School, Leeds. *Stocker, W.N., M.A. Brasenose College, Oxford. tStoddart, I’, Wallis, F.1.C. Grafton Lodge, Sneyd Park, Bristol. *Stokes, Professor George J., M.A. Riversdale, Sunday’s Well, Cork. {Stone, E. D., F.C.S. Rose Lea, Alderley Edge, Cheshire, *Stone, Rev. F. J. Radley College, Abingdon. {Stone, Sir J. Benjamin, M.P. The Grange, Erdington, Birmingham, {Stone, J. H. Grosvenor-road, Handsworth, Birmingham. {Stone, J. Harris, M.A., FL. s, F.C.S. 3 Dr. Johnson’ s-buildings, Temple, 1.C. {Stone, Octavius C., F.R.G.8. Rothbury House, Westclifl-gardens, Bournemouth. {Sroney, Brypon B., LL.D., F.R.S., M.Inst.C.E., M.R.LA., Engineer of the Port of Dublin. 14 Elgin-road, Dublin. *Stoney, Miss Edith A. 30 Ledbury-road, ’ Bayswater. We *Stoney, G. Gerald. Oakley, Heaton-road, Newcastle-upon-Tyue. *Srongy, GroreE Jonnstone, M.A., D.Sc. JE. R.S.,M.R.LA. (Pres. A, 1897.) 30 Ledbury-road, Bayswater, W. *Stopes, Miss Marie, Ph.D., B.Sc. 25 Denning-road, Hampstead, N.W {Stopes, Mrs, 25 Denning-road, Hampstead, N.W. *Storey, H. L. Bailrigg, Lancaster. {Storrs, George H. Gorse Hall, Stalybridge. *Stothert, Perey K. Woodley Grange, Bradford-on-Avon, Wilts. { Stott, William. Scar Bottom, Greetland, near Halifax, Yorkshire. *SrracuEy, Lieut.-General Sir Ricwarp, RE., G.C.S.1., LL.D., FRS., F.R.GS., F.LS., F.G.S. (Pres. i, 1875 ; "Council, 1871-75.) 69 Lancaster-gate, Hyde Park, W. {Srrawan, Avsprey, M.A., F.RS., F.G.S. (Pres. C, 1904.) Geo-~ logical Museum, Jermyn-street, 8. W. {Straker, John. Wellington House, Durham. {Strange, Rey. Canon Cresswell, M.A. The College, Worcester. {Srraneways, C, Fox, F.G.S. Geological Museum, Jermyn-street, S.W {Streatfeild, H.8., F.G.8. | Ryhope, near Sunderland. {Strickland, Sir Charles W., Bart., K.C.B. Hildenley-road, Malton. {Stringham, Irving. The University, Berkeley, California, U.S.A. §Strong, aged i, M.D. Colonnade House, The Steyne, Worthing. *Strong, W. M. 8 Champion-park, Denmark Hill, 8.E. *Stroud, H., M.A., D.Se., Professor of Physics in the College of Science, Newecastle-upon-Tyne. *Srroup, WiniiAM, D.Sc., Professor of Physics in the University of Leeds. *Stuart, Charles Maddock, M.A. St. Dunstan’s College, Catford, S.E. *Stuart, Rey. Edward A.,M.A. 5 Prince’s-square, W. {Stuart, Dr. W. Theophilus. 183 Spadina-avenue, Toronto, Canada. {Stuart-Gray, Hon. Morton, M.A.,I'.G.S. 2 Belford-park, Edinburgh. {Stubbs, Miss. Torrisholme, Aigburth-drive, Sefton Pat Liverpool. {Stump, EdwardC. 16 Herbert-street, Moss Side, Manchester. {Stupart, R. F. The Observatory, Toronto, Canada. *Styring, Robert. Brinkcliffe Tower, Sheffield. *Sudborough, Professor J. J., Ph.D., D.Sc. University College of Wales, Aberystwyth. LIST OF MEMBERS. 91 Year of Hiection. 1902. §Sully, H. J. Avalon House, Priory-road, Clifton, Bristol. 1898. §Sully, T. N. Avalon House, Priory-road, Clifton, Bristol. 1884, {Sumner, George. 107 Stanley-street, Montreal, Canada, 1887. *Sumpner, W. E., D.Sc. Technical School, Suffolk-street, Birming- ham. 1883. {Sutcliffe, J. 8., J.P. Beech House, Bacup. 1873. {Sutcliffe, Robert. Idle, near Leeds. 1863. {Sutherland, Benjamin John. Thurso House, Newcastle-upon- Tyne. 1886. {Suthier leat Hugh. Winnipeg, Manitoba, Canada. 1892. {Sutherland, James B, 10 Windsor-street, Mdinburgh. 1884. {Sutherland, J.C. Richmond, Quebec, Canada. 1863. {Surron, Francois, F.C.S. Bank Plain, Norwich. 1889. {Sutton, William. LEsbank, Jesmond, Newcastle-upon-Tyne. 1891. {Swainson, George, F.L.S. North Drive, St. Anne’s-on-Sea, Lan- cashire. 1903. §Swallow, Rev. R. D., M.A. Chigwell School, Essex. 1881. §Swan, Sir Jossrpn Witson, M.A., D.Sce., F.R.S, 58 Holland-park, W. 1897. {Swanston, William, F.G.S. Mount Golly er Factory, Belfast. 1879. tSwanwick, Frederick. Whittington, Chesterfield. 1887. §Swrypurne, Jaws, M.Inst.C.E. 82 Victoria-street, S.W. 1870, *Swinburne, Sir John, Bart. Capheaton Hall, Newcastle-upon- Tyne. 1887. *Swindells, Rupert, F.R.G.S. 22 Oxford-road, Birkdale, Southport. 1890. {SwinHog, Colonel C., F.L.S. Avenue House, Oxford. 1873. {Sykes, Benjamin Clifford, M.D. St. John’s House, Cleckheaton. . 1895. {Sykes, HE. R. 3 Gray’s Inn-place, W.C. 1902. *Sykes, Miss Ella C. Elcombs, Lyndhurst, Hampshire. 1887. *Sykes, George H., M.A.,M.Inst.C.1., F.S.A, Glencoe, 64 Elmbourne- road, Tooting Common, 8. W. 1896. *Sykes, Mark L., F.R.M.S. Kensington House, Pensford, near Bristol. 1902. *Sykes, Major P. Molesworth, C.M.G. Elcombs, Lyndhurst, Hampshire. 1893. {Symes, Rev. J. E., M.A. 70 aa ee Nottingham. 1870. {Symzs, RIcHARD. Guascorr, M.A., F.G.S , Geological Survey of Scotland. Sheriff Court-buildings, Edinburgh. 1903. §Symington, Howard W. Brooklands, Market Harborough. 1885. {Symineron, Jonunson, M.D., F.R.S., F.R.S.E. (Pres. H, 1903), Professor of Anatomy in Queen’s College, Belfast. 1886, {Symons, W. H., M.D. (Brux.), M.R.C.P., F.C. Guildhall, Bath. 1896, {Tabor, J. M. Holmwood, Harringay Park, Crouch End, N, 1898, {Tagart, Francis. 199 Queen’s-gate, 5. W, 1865, {Tailyour, Colonel Renny, R.E, Newmanswalls, Montrose, Forfar- shire. 1894, {Takakusu, Jyun, B.A. 17 Worcester-terrace, Oxford. 1904. §Tallack, H. T. Clovelly, Birdhurst-road, South Croydon, 1903. TW, Ellen G. 48 Campden House Court, Gloucester- wal 1890. §TANNER, HL. W. Luoyp, D.Se., F.R.S. (Local See. 1891), Professor of Mathematics and Astronomy in University College, Cardiff. 1897. {Tanner, Professor J. H. Ithaca, New York, U.S.A. 1892. *Tansley, Arthur G., M.A., F.L.S. University College, W.C. 1883. *Tapscott, R. Lethbridge, F, R.A.S. 62 Croxteth-road, Liverpool. 1878. {Tarrry,Hven. Dublin. 1861. *Tarratt, Henry W. Broadhayes, Dean Park, Bournemouth. 92 LIST OF MEMBERS. Year of Election. 1893. 1902. 1901. 188, 1887. 1898, 1887. 1881. 1884. 1882, 1860. 188], 1865. 1899. 1884. 1900, 1887. 1883. 1901, 1903. 1895, 1893. 1894, 1901. 1858. 1885, 1898, 1879, 1889. 1882, 1896. 1892. 1883, 1883. 1882, 1889. {Tate, George, Ph.D. College of Chemistry, Duke-street, Liverpool. {Tate, Miss. Rantalard, Whitehouse, Belfast. {Taylor, Benson, 22 Hayburn-crescent, Partick, Glasgow. *Taylor, Rev. Charles, D.D. St. John’s Lodge, Cambridge. {Taylor,G. H. Holly House, 235 Eccles New-road, Salford. {Taylor, Lieut.-Colonel G. L. Le M. 6 College-lawn, Cheltenham. {Taylor, George Spratt. 13 Queen’s-terrace, St. John’s Wood, N.W. *Taylor, H. A. 69 Addison-road, Kensington, W. *Taytor, H. M., M.A., F.R.S. Trinity Colleze, Cambridge. *Taylor, Herbert Owen, M.D. Oxford-street, Nottingham. *Taylor, John, M.Inst.C.E., F.G.S. G Queen Street-place, E.C. “Taylor, John Francis. Holly Bank House, York. {Taylor, Joseph. 99 Constitution-hill, Birmingham, [Taylor, Robert H., Assoc.M.Inst.C.I. 5 Maison Dieu-road, Dover. *Taylor, Miss S. Oak House, Shaw, near Oldham. tTaylor, T. H. Yorkshire College, Leeds. {Taylor, Tom. Grove House, Sale, Manchester. { Taylor, William, M.D. 21 Crockherbtown, Cardiff. §Taylor, William. 57 Sparkenhoe-street, Leicester. {(‘Taylor, William, 61 Cambridge-road, Southport. {Taylor, W. A., M.A., F.R.S.E. Royal Scottish Geographical Society, Edinburgh. { Taylor, W. FF. Bhootan, Whitehorse-road, Croydon, Surrey. *Taylor, W. W., M.A. 30 Banbury-road, Oxford. *Teacher, John H., M.B. 32 Kingsborough-gardens, Glascow. {Teatzr, Tuomas Pripvern, M.A., F.R.S. 88 Cookridge-street, Leeds, {Teatt, J. J. H., M.A., FBS. F.G.S.. (Pres. C, 1893; Council 1894-1900), Director of the Geological Survey of the United Kingdom. 89 Thurlow Park-road, West Dulwich, 8.1. §Tebb, Robert Palmer. Inderfield, Chislehurst, Kent. {Temple, Lieutenant G. T., R.N., F.R.G.S. The Nash, near Worcester. {Tennant, James. Saltwell, Gateshead. {Terrill, William. 42 St. George’s-terrace, Swansea. *Terry, Rev. T. R., M.A., F.R.A.S. The Rectory, East Isley, New- bury, Berkshire. *Tesla, Nikola. 45 West 27th-street, New York, U.S.A. {Tetley, C. F. The Brewery, Leeds. {Tetley, Mrs. C. F. The Brewery, Leeds. *THann, GEorcE Dancer, Professor of Anatomy in University College, London, W.C. {Thetford, The Right Rev. A. T. Lloyd, D.D., Bishop of. North Creake Rectory, Fakenham, Norfolk. . {Tutsenron-Dygr, Sir W. T., K.C.M.G., O.1.E., M.A., B.Se., Ph.D., LL.D., F.R.S., F.L.8. (Pres. D, 1888; Pres. K, 1895; Council 1885-89, 1895-1900.) Royal Gardens, Kew. {Thom, Robert Wilson, Lark Hill, Chorley, Lancashire. {Thomas, Alfred, M.P. Pen-y-lan, Cardiff. {Thomas, A. Garrod, M.D., J.P. Clytha Park, Newport, Mon- moutbshire. *Thomas, Miss Olara. Penurrig, Builth. tThomas, Edward. 282 Bute-street, Cardiff. {Thomas, FE. Franklin. Dan-y-Bryn, Radyr, near Cardiff. §Thomas, Miss Ethel N, 8 Downe-mansions, Gondar-gardens, West Hampstead, N.W. {Thomas, H. D. Fore-street, Exeter. {tThomas, Herbert. Ivor House, Redland, Bristol. LIST OF MEMBERS. 93 Year of Election, 1881. 1869. 1880. 1899. 1902. 1904. 1883. 1898. 1883, 1886. 1904. 1886. 1875. 1891. 1883. 1891. 1882, 1888. 1885. 1896, 1883. 1891. 1904, 1893. 1883. 1891. 1891. 1897. 1891, 1861. 1876, 1883. 1876. 1883. 1896. 1896. 1867. 1894, 1889. 1891. 1896. 1890, 1883. 1871, {THomas, J. Brount. Southampton. {Thomas, J. Henwood, F.R.G.S. 86 Breakspears-road, Brockley, S.E, *Thomas, Joseph William, F.C.S. Overdale, Shortlands, Kent, *Thomas, Mrs. J. W. Overdale, Shortlands, Kent. §Thomas, Miss M. B. 200 Bristol-road, Birmingham. §Thomas, Northcote W. 7 Coptic-street, W.C, {Thomas, Thomas H. 45 The Walk, Carditf. {Thomas, Rev. U. Bristol School Board, Guildhall, Bristol {Thomas, William. Lan, Swansea. {Thomas, William. 109 Tettenhall-road, Wolverhampton. §Thomas William. Bryn-heulog, Merthyr-Tydfil. {Thomason, Yeoville. 9 Observatory-gardens, Kensington, W. {Thompson, Arthur. 12 St. Nicholas-street, Hereford. *Thompson, Beeby, F.C.S., F.G.S. 67 Victoria-road, Northampton. Thompson, Miss C. i. Heald Bank, Bowdon, Manchester. Thompson, Charles F. Penhill Close, near Cardiff. {Thompson, Charles O, Terre Haute, Indiana, U.S.A, *Thompson, Claude M., M.A., Professor of Chemistry in University College, Cardiff. {Taompson, D’Arcy W., B.A., C.B., Professor of Zoology in Univer- sity College, Dundee. *Thompson, Edward P. Paulsmoss, Whitchurch, Salop. *Thompson, Francis. Lynton, Haling Park-road, Croydon, {Thompson, G. Carslake. Park-road, Penarth. *Thompson, G. R., B.Se., Professor of Mining in the University of Leeds. *Thompson, Harry J., M.Inst.C.E., Madras. Care of Messrs, Grindlay . & Co., Parliament-street, S.W. “Thompson, Henry G., M.D. 86 Lower Addiscombe-road, Croydon, {Thompson, Herbert M. Whitley Batch, Llandaff, {Thompson, H. Wolcott. 9 Park-place, Cardiff. {Thompson, J. Barclay. 37 St. Giles’s, Oxford. {Thompson, J. Tatham, M.B. 23 Charles-street, Carditt. *THompson, JosePH. Riversdale, Wilmslow, Cheshire. *Thompson, Richard. Dringcote, The Mount, York. {Thompson, Richard. Bramley Mead, Whalley, Lancashire. {THompson, Sirvanus Puitiirs, B.A., D.Se., F.R.S., F.R.A,S, (Council 1897-99), Principal and Professor of Physics in the City and Guilds of London Technical College, Finsbury, F.C. *Thompson, T. H. Oldfield Lodge, Gray-road, Bowdon, Cheshire. *THompson, W. H., M.D., D.Sc., King’s Professor of Institutes of Medicine (Physiology) in Trinity College, Dublin. 14 Hatch- street, Dublin, {Thompson, W. P, 6 Lord-street, Liverpool. {Thoms, William. Magdalen-yard-road, Dundee. {THomson, Artur, M.A., M.D., Professor of Human Anatomy in the University of Oxford. Exeter College, Oxford. *Thomson, James, M.A, 22 Wentworth-place, Newcastle-upon-Tyne. {Thomson, John. 70a Grosyenor-street, W. { Thomson, John. 3 Derwent-square, Stonycroft, Liverpool. {THomson, Professor J. ARTHUR, M.A., F.R.S.E. Castleton House, Old Aberdeen. jTuomson, J. J., M.A., D.Sc., F.R.S. (Pres. A, 1896; Council 1893-95), Professor of Experimental Physics in the University of Cambridge. Trinity College, Cambridge. *Tuomson, Joun Mittar, LL.D., F.R.S. (Council 1895-1901), Pro- fessor of Chemistry in King’sCollege, London, 85 Addison-rd., W. 94 LIST OF MEMBERS, Year of Election. 1902. {Thomson, J. Stuart. Marine Biological Laboratory, Plymouth. 1901. §Thomson, Dr. J. T. Kilpatrick. 148 Norfolk-street, Glasgow. 1874, —, Wun, F.R.S.E., F.C.S. Royal Institution, Man- chester. 1880. §Thomson, William J. Ghyllbank, St. Helens. 1897. {Thorburn, James, M.D. Toronto, Canada. 1871. ¢{Thornburn, Rey. David, M.A, 1 John’s-place, Leith. 1887. {Thornton, John. 3 Park-street, Bolton. 1898. eee W.M. The Durham College of Science, Newcastle-on- e. 1902. Thonmyatottl Sir John I., F.R.S., M.Inst.C.E, Eyot Villa, Chis- wick Mall, W. 1883. {Thorowgood, Samuel. Castle-square, Brighton. 1903. §Thorp, Edward. 87 Southbank-road, Southport. 1881. {Thorp, Fielden. Blossom-street, York. 1881. *Thorp, Josiah. 37 Pleasant-street, New Brighton, Cheshire, 1898. §Thorp, Thomas. Moss Bank, Whitefield, Manchester. 1898. {Thorpe, Jocelyn Field, Ph.D. Owens College, Manchester. 1871. {Tuorrz, T. I., C.B., Ph.D., LL.D., F.R.S., F.R.S.E., V.P.O.S. (Pres. B, 1890; Council 1886-92), Principal of the Government Laboratories, Clement’s Inn-passage, W.C. 1883. §Threlfall, Henry Singleton, J.P. 1 London-street, Southport, 1899, §THRELFALL, RicwarD, M.A., F.R.S. 80 George-road, Edgbaston, Birmingham. 1896. §Thrift, William Edward, M.A., Professor of Natural and Experi- mental Philosophy in the University of Dublin. 80 Grosyenor- square, Rathmines, Dublin. 1868, {Tuurimer, General Sir H. E. L., R.A., OS.1, F.RS., F.R.G.S, Tudor. House, Richmond Green, Surrey. 1889. {Thys, Captain Albert. 9 Rue Briderode, Brussels. 1870, {Tichborne, Charles R. C., LL.D., F.C.S., M.R.L.A. Apotheearies’ Hall of Ireland, Dublin. 1873. *TrppEMAN, R. H., M.A., F.G.S. 175 Banbury-road, Oxford. 1874, {Trupen, Witriam A., D.Sc., F.R.S., Treas.C.S. (Pres. B, 1888, Council 1898-1904), Professor of Chemistry in the Royal College of Science, London. The Oaks, Northwood, Middlesex. 1883, {Tillyard, A. I.,M.A. Fordfield, Cambridge. 1883. {Tillyard, Mrs. Fordfield, Cambridge. 1896. §Timmis, Thomas Sutton. Cleveley, Allerton, Liverpool. 1899, {Tims, = W. Marett, B.A., M.D., F.L.S. 10 Bateman-street, Cam- bridge. 1902. §Tipper, Charles J. R., B.Sc. 21 Greenside, Kendal. 1900. §Tocher, J. F., F.C. 5 Chapel-street, Peterhead, N.B. 1876. {Todd, Rev. Dr. Tudor Hall, Forest Hill, 8.E. 1891. {Todd, Richard Rees. Portuguese Consulate, Cardiff. -1897. {Todhunter, James. 85 Wellesley-street, Toronto, Canada. 1889, §Toll, John M. 49 Newsham-drive, Liverpool. 1857. t{Tombe, Rey. Canon. Glenealy, Co. Wicklow. 1888. {Tomkins, Rev. Henry George. Park Lodge, Weston-super-Mare. 1896. { Toms, Frederick. 1 Ambleside-avenue, Streatham, S.W, 1887. {Tonge, James, F.G.S. 24 Hampton-road, Southport. 1865. { Tonks, Edmund, B.C.L. Packwood Grange, Knowle, Warwickshire. 1873. *Tookey, Charles, F.C.S. Portland Hotel, Great Portland-street, W. 1875. {Torr, Charles Hawley. St. Alban’s Tower, Mansfield-road, Sher- wood, Nottingham. 1884, *Torrance, Rev. Robert, D.D. Guelph, Ontario, Canada, 1873. {Townend, W. H. Heaton Hall, Bradford, Yorkshire. LIST OF MEMBERS, 95 Year of Election. 1875, 1901. 1876. 1883. 1870. 1868, 1902. 1891, 1884. 1868, 1891. 1887. 1903. 1889. 1884. 1879. 1871. 1860. 1902. 1884, 1885, 1891, 1887, 1898. 1885. 1847, 1888. 1871. 18838. 1392. 1855, 1901. 1901. 1893. 1894, 1886, 1863. 1893, 1890 {Townsend, Charles. St. Mary’s, Stoke Bishop, Bristol. fTownsend, J. S. E., M.A., F.R.S., Professor of Physies in the University of Oxford. New College, Oxford, *Tratt, J. W. H., M.A., M.D., F.RS., F.L.S., Regius Professor of Botany in the University of Aberdeen, tTramt, A., M.D., LL.D., Provost of Trinity College, Dublin. Ballylough, Bushmills, Ireland. tTrarnt, Wittam