y 4 ns ; tape 2 MV's ty f ir we 4 + and ‘Proceedings OF ane D it RBELAAST iF ‘ “ : | Natural History and Philosophical Society th FOR THE i SESSION. 1917-1918. a eA Oy "BELFAST: | ie -MAYNE, BOYD & SON, LTD.. 2 CORPORATION STREET (PRINTERS: TO THE QUEEN’ $ UNIVERSITY). ° PG 2M ASagtens > a Py eA i : } 2G gin vA een oa mes i | wer aye og 7 a AO ak x ¥ ! sy QD lee ————— ———= | |S > SSS ~ - . =— 4d) | = [————_ eennnnmemnenemmeeenemenen =) i ( y ‘Ai, ep y > : é : : 7 A 7 Pig), chee are i } ay ae: “s / y ‘ . 44 a Ath i ’ Bs pe: "ar, tt ae ‘ 1 ae , > 4 ly. y ey ~~ a -. is J Report and Proceedings py | Natura! History and Philosophical Society | BELFAST: MAYNE, BOYD & SON, LTD., 2CORPORATION STREET (PRINTERS TO THE QUEEN’S UNIVERSITY). 1919. Belfast Natural History and Philosophical Society. ——_ :0 : —— ESTABEISGIED 1821- —— :0:—— CONSTITUTION. The membership of the Society consists of Shareholders, Members under the new scheme authorized by the Society, Annual Subscribers (Associates), Ifonorary Members and Honorary Associates. A holder of one share pays an annual contribution of ten shillings ; a holder of two shares (in one certificate) an annual contribution of five shillings ; while a holder of three or more Shares (in one certificate) is exempt from annual payments. Shares on which the annual paymentt as above are in arrear are liable to forfeiture. The Council retain the right to decline to ‘consolidate two or more share certificates into one certificate. Members under the new scheme are elected by the Council, pay ten shillings per annum subscription, and have the right to vote on all questions not affecting the ownership of the property of the Society. Annual subscribers (Associates) pay £1 ls. Od. (one guinea‘, due Ist November in each year in advance. A General Meeting of Shareholders in the Museum is held annually in May or June, or as soon thereafter as convenient, to receive the Report of the Council and the statement of Accounts for the preceding year, to elect members of Council, to replace those retiring by rotation or for other reasons, and to transact any other business incidental to an annual meeting. The Council elect, from among their own number, a President and other officers of the Society. Each member has the right of personal attendance at the ordinary lectures of the Society, and has the privilege of introducing two friends for admission to such. The Session for lectures extends from November to May. Any further information required may be obtained from the Honorary Secretary. CONTENTS. The Fixation of Nitrogen and its Application to the Industrial Development of Ireland—Professor William Caldwell, M.A., SOeID eos I ssle(Cs The Giant’s Ring-—H. C. Lawlor, M.R.I.A. The Folk-Lore of North of Ireland Place Names—Sir John Byers, M.A., M.D. The Psychology of Telephony—John Lee, M.A. Discontinuity in the Phenomena of Radiation—James Rice, M.A. Annual Report Treasurer’s Account Exchanges Office-Bearers and List of Shareholders and Members t NATURAL HISTORY cigs 29° 30° 43. 81 85 86. 88. BELFAST Aw LRA La dTSEORY Pee hI MOSOPHICAE SOCIETY. SESSION 1917-18. 11th December, 1917. “THE FIXATION OF NITROGEN AND ITS APPLICATION TO THE INDUSTRIAL DEVELOPMENT OF IRELAND.” By Proressor WILLIAM CALDWELL, M.A., Sc.D., F.I.C. (Abstract). Dr. Caldwell described, besides other methods, the method of obtaining nitrogen from liquid air, and in this connection recalled the work of Dr. Thomas Andrews, formerly Professor of Chemistry in Queen’s College, Belfast, and the work of Lord Kelvin and Joule in defining the principles on which the liquefaction of gases is based. It was pointed out that we require unlimited quantities of nitrogenous compounds, not alone for use as artificial fertilizers, but for use in the manufacture of explosives. The supplies of the naturally occurring nitrates are decreasing rapidly, therefore we shall have to adopt some method of fixation of nitrogen to replace the natural supplies. Germany’s preparations for war were based on the establishment of huge chemical industries, and the foresight of Germany saved that country from defeat after the blockade of Germany became strict. We may likewise build up industries with peaceful objects in view, to replenish our unproductive soil and to intensify our agricultural pursuits, a 6 Professor William Caldwell on In olden times natural manures were sufficient to feed the lands with the requisite nitrogen to be converted into nitrates, previous to absorption and assimilation by the plants and vegetables. Now we must procure artifical fertilizers. One of these artificial fertilizers is procured from the gas works. The coal is destructively distilled and the ammonia evolved is absorbed and converted into ammonium sulphate. But the production of ammonium sulphate in the whole world is relatively a small amount. It was only one million tons in 1910—an amount quite insufficient to meet the demands of agriculture. We must have recourse to Chili saltpetre, a naturally occurring sodium nitrate found on the plains of Chili. For ages the nitrogen of the atmosphere has been absorbed by the soil, and the nitrifying organisms convert it into nitrates. In 1830 only 935 tons of saltpetre were used from this source, whilst in 1912 2,500,000 tons were used, and 75% of these imported nitrates were used as artificial fertilizers. In a short space of time, however, these sources of supply will have vanished, and therefore we must apply our scientific knowledge to make good the deficiency. Let us see what methods we may adopt. Plants, belonging to the Leguminosae order, have their roots covered with nodules, which are vast collections of nitrifying organisms, which possess the power of using the free nitrogen of the air and assimilating it in their tissues. At the ordinary temperature without any extraordinary phenomenon these organisms are secreting and storing vast supplies of nitrogen for their own use. Yet these organisms which flourish on the roots of leguminous plants are not specific. They may be cultivated and used by other plants. Land barren and poor in quality may be inoculated with these organisms and made rich and fertile for the production of foodstuffs. But there is another and more prolific method of fixing the nitrogen of the air. The method was suggested by Sir William Crookes at a conversazione of the Royal Society in 1898, ~T The Fixation of Nitrogen _ There exists in the atmosphere, according to a rough approximation, 4,000 billion tons of nitrogen. Over every square yard there are about seven tons of nitrogen. Over every square mile of the earth’s surface we have as much free nitrogen which, if converted into nitrates, would manure the lands of the world for a very prolonged period. Crookes demonstrated the fixation of this free nitrogen by passing electric sparks through air enclosed in a specially constructed globe, and showed that the nitrogen was burned and thus converted into oxides of nitrogen which, when absorbed by water or alkali, yielded acids or salts in nitrogen, products ready for use as fertilizers. Crookes pointed out that the experiment might be made the basis of a huge industry destined to solve the great food problem of the world. A few years later the first successful nitrate factory was established by Professor Birkeland and Dr. Eyde at Notodden, where the artificial production of nitrates is carried out on an extensive scale. Here an alternating current of 3,000—5,000 volts is used, and a powerful electric are is formed between two copper electrodes placed in a stream of air. The electrodes are hollow to permit them being kept cool by a constant stream of cold water. The terminals are placed about.4 to $ inch apart. The are is deflected at right angles to the direction of the electrodes by means of a powerful electro-magnet, placed in such a way that the terminals of the copper electrodes are in the middle of the magnetic field. A great roaring disc of flame immensely hot forms between the electrodes. The gases from the flame are pumped off and yield according to the method of absorption either alkali salts or calcium salts. The calcium salts may be applied directly, without purification, to the soil as a fertilizer. There is another important method called the Haber process, which has been adopted in countries where water power can be easily obtained When a mixture of nitrogen and hydrogen is subjected to sparks from an induction coil combination takes 8 Professor Wiliam Caldwell on place with the formation of ammonia. But the yield of ammonia under these conditions is very small. It has, however, been found that if a mixture of nitrogen and hydrogen be passed over a catalyser—in this case finely divided osium or uranium— heated to a definite temperature, the two gases readily unite and ammonia may be separated in quantities sufficiently large to prove a commercial success. In 1913 Germany spent £2,000,000 on works to secure the production of ammonia on an enormous scale by this process. . The nitrogen is obtained from liquid air, and the hydrogen may be obtained by several interesting methods. Hydrogen may be prepared very cheaply by the electrolysis of a solution of potas- sium carbonate or of a solution of caustic potash at a temperature of 60°C. The cost is reduced by making use of the oxygen which is evolved at the same time. A second method is to use water gas and to pass it at the required temperature through eauzes composed of catalytic metals, iron, nickel or platinum. The mixture of gases necessary for the production of ammonia may be also obtained from air and steam. The mixture is deprived of oxygen by passing it over heated copper, and then over heated iron to decompose the steam. The oxides of the metals are in turn reduced, and may be used again and again. Ammonia may also be made from the nitrides—compounds of nitrogen with metals. The process has been developed by Serpek, who uses aluminium nitride, and subsequently decomposes the nitride with the production of ammonia, and aluminium is obtained as a bye-product. The process might be developed in the North of Ireland, where Bauxite, a naturally occurring hydrated alumina, is found in County Antrim. Again, the carbides, for example calcium carbide, absorbs nitrogen and forms cyanamide. This substance may be used direct as a fertilizer, or it may be decomposed and ammonia obtained under certain conditions. The cyanamide industry-is being developed on a large scale in Germany, France, Italy, Norway, Japan and America, The Fixation of Nitrogen 9 The fixation of nitrogen may be made by (1) electrical methods or by (2) chemical methods, and although the electrical method, such as the Birkeland Eyde process, requires about 30 times more energy than the chemical method, e.g., the direct synthetical. method, yet from the economic standpoint it is not certain that the chemical methods are the better ; for, from the point of view of capital expenditure, the are processes have a good deal in their favour. Mr. Kilburn Scott has been working on this problem in this country for some years past, and he has devised a special electric furnace for the production of nitric acid, which differs from those used on the continent for the same purpose, in that it is a self- contained three phase unit. The furnace is filled with three triangular metal electrodes. The arcs are struck between the electrodes where they are near together at the bottom, and they are spread out in flames by the flow of air. When the air comes in contact with the rapidly rotating triple are flames, combination between the nitrogen and the oxygen take place with the formation of nitric oxide. The nitric oxide must be cooled as rapidly as possible, and to facilitate this an arrangement is fitted to the furnace to absorb the heat from the hot gases. And as the hot gases pass away they are used to heat the incoming air. The normal yield of nitric acid is about 50 gms per kw. hr, and with the three phase furnace the yield has been raised to about 66 gms per kw. hr. The other part of the process is similar to what I have described under the Birkeland Eyde system. Dr. Maxted, on the other hand, favours the method of the direct synthesis of ammonia and its subsequent oxidation to nitric acid, and he estimates that the cost in that case cannot be more than £15 per ton. And he states that so far as power and raw material are concerned the formation of ammonia by direct synthesis is a process more than twice as efficient as the cyanamide process and more than six times as efficient as the arc process. The direct synthesis of ammonia with the subsequent oxidation to nitric acid is by far the most economical means of 10 Professor William Caldwell on effecting the fixation of atmospheric nitrogen. With us in Ireland the product is required as a fertilizer, and in this case it would obviate any risks of loss by accidents to the ships, and indeed it would save much shipping which could be diverted to other uses. We have had to rely on our Navy and its command of the seas for the importation of all our supplies of nitrate of soda, the raw material required to make explosives. On the other hand, the Central Powers have been cut off from external supplies, and have had therefore to develop. their internal resources, which they have done to an enormous extent, and if it had not been for this marvellous developmant of chemistry, Germany would have been defeated three years ago. Since the beginning of 1915 a Committee has been appointed in England to consider these different schemes, and latterly after more than a couple of years, a report has been issued and the Government has made some important recommendations, and some real work has been begun. To help those who wish to make individual efforts the Government will readily place all their knowledge at their disposal. Some new work has likewise been done on the syuthesis of ammonia, and a catalyser has been used which gives excellent results. Now what can we do in Ireland. Have we any means of providing cheap power? In the first place one should perhaps say that any waste from the gas works, or gas coke furnaces, or blast furnaces should be prevented, because we are just able to obtain about 1/10th of the amount of ammonium sulphate we should obtain if waste was entirely prevented. It is not a dream to assert that the power is at our doors. If we want water power then on the Bann we have two water- falls—one at Portna and the other at Mavanagher. They might be used without any very extensive hydraulic work, and would produce between them about 600 H.P. The falls are not high— from 1lft. to 16ft.—but then we must remember that the falls at Reinfelden and Schaffhausen are not any higher. ‘These small The Fixation of Nitrogen Ui: falls on the Bann might be used for the Haber process which requires only a moderate expenditure of power. Nor can the day be far distant when we shall harness the waters of the Shannon, and for Ulster the waters of Lough Erne will one day be con- veyed by canal and pipe to some power station for distribution for different purposes for many miles around the province. Again we have other sources of power, and if these can be developed, then Ireland will benefit to a very great extent. Ireland is mainly an agricultural country, and if we could have cheap fertilizers our agricultural pursuits would develop enormously. We are a poor people, and the land is cultivated in a poor fashion. In Germany four or five times the manure we use 1s put into the soil, with the result that their crops in the past have been more prolific. For the source of cheap power we turn to peat. The peat itself is a source of nitrogen, and when the peat is carbonized the nitrogen present can be recovered as ammonia, and in view of the enormous peat moors which exist in the world the reserve stock of nitrogen is very great. In Russia there is no less than 95,000,000 acres, in Finland 185 million acres, and in Ireland 1/7th of the whole country—about 2? million of acres is bog or peat land. Hence the combustion of the peat itself will produce huge quantities of ammonia sulphate, but the combustion from the peat will also give us a power gas, which can be used for industrial purposes or for the purpose of synthesizing ammunia itself, by the use of atmospheric nitrogen. The problem has been solved elsewhere. The peat gas is produced and utilized, and the ammonia obtained as a bye-product. At Osnabriick, in Germany, the peat gas is used by a central electrical power station, and ylelds 3,000 H.P., whilst the reclaimed moorland can be used for agricultural purposes. Therefore, a practical use for the peat in this country is to convert it into gaseous fuel in suitable gas producers. In this way you obtain the combustible gases, ammonia, and some other important bye-products. There is a plant of this type in use at Portadown belonging to the firm i2 Professor Caldwell—The Fixation of Nitrogen of Hamilton Robb, Ltd. This installation is, it seems, very satisfactory, and effects a considerable saving in the coal bill. The bye-products are allowed to go to waste ; nevertheless, it is a commercial success. Recently plants have been devised to recover the nitrogen as ammonium sulphate while the gas is used to drive gas engines, which drive alternate current generators. In. another such plant in Italy a total power capacity of over 3,000 H.P. has been obtained, and the gas engines are coupled to alternators. The current transmitted at a tension of 30,000 volts is distributed over an area of 25 miles radius. Therefore, what one would naturally suggest is the establishment of a producer plant at or near the bog land itself, the conversion of the mechanical power into electricity, and the transmission of the energy at high pressure to the point where it is wanted. This method of using the peat, and the recovery of the land. for agricnitural purposes, may be combined with some of the methods for preparing or synthesizing ammonia or nitric acid, by the use of atmospheric nitrogen. Our fertilizers will be produced in abundance, our lands will yield accordingly, and our people may have such prosperity as a result of the enterprise, as to cast discontent aside and become as happy, as contented, as enter- prising as our fellow-countrymen in the North of Ireland. Sth January, 1918. THE GIANT’S RING. By Mr. H. C. Lawtor, M.R.I.A. The Giant’s Ring, situated in the townland of Ballynahatty and adjoining those of Edenderry and Ballylesson, some four miles south-west from Belfast, may well be classed among the most remarkable earthworks in Ireland. It is somewhat smaller than Tara or Emmania, covering some ten acres, but it is dis- tinguished by containing a very fine Cromlech almost in the centre, a feature which makes it, I think, almost unique in monuments of the sort. Mr. Borlase states that another example of a Vallum or Rath surrounding a Dolmen is that of Leacht an Seail in County Kilkenny, but im this case the ring has been levelled. Another individual peculiarity of the Giant’s Ring is that whereas in all other cases that have come to my knowledge the mounds or walls of ring forts or raths have always been formed by heaping up the soil dug from a surrounding trench ; in this instance there is no foss round the Vallum, and no sign that there ever was one. ‘The question naturally arises, where then was the vast quantity of material necessary to build the mound got from? I shall refer to this interesting question later. Unlike Tara, Emmania or Newgrange, the Giant’s Ring is completely without a vestige of written history. The complete removal from the whole district of all trace of the old inhabitants, through English and Scottish plantations, has also removed any oral traditions that might have been handed down concerning it. The names of the townlands in which it lies or which it touches, Ballynahatty, Edenderry and Ballylesson, convey no hint. True, Dr. O'Donovan suggested that Ballynahatty might resolve itself into Bally n’ait tigh or the ““Townland of the site of the House,” 14 Mr. HI. C. Lawlor on or that it was in prehistoric times the residence of a Sept called O’Hatty. Ballylesson in its present form is, merely the townland of the small lis or fort. This cannot apply to the Giant’s Ring. Two other suggested interpretations of Ballylesson have been put forth: one that it is a contraction of Bally-lis-owen or the townland of the lis of Owen; the other that the ‘an’ or ‘on’ terminating the word Ballylesson is a modern contraction from the old Irish Oenach or festival with games, and that the -uame means the “ place of enclosure of the games.” This trans- lation is very tempting, but unfortunately does not lend itself to gaelic etymology. The form of the name of this townland in the 17th century inquisitions was Ballynalissan. We may assume that the Bally is comparatively modern, say mediaeval, but un- fortunately we cannot up to the present trace any earlier reference to the place in ancient literature. If it is referred to, as 1t may be, it is by some name that has not yet been identified as apply- ing to it. The townland of Edenderry, “The slope of the oak trees,” touches on the Ring on the south side. The oak tree has always been associated with Druidical worship. Some sixty years ago a few stunted oaks still remained on the Giant’s Ring, and it is quite possible that they were the descendants of an ancient grove of oaks connected with Druidical ceremonial. The Vallum is divided by seven depressions into seven arcs. That these are part of the original design there can be little doubt. Mr. Borlase in his description of the Ring refers to this fact, and points out that similar: depressions or gaps are a notable feature in certain very similar and even larger prehistoric enclosures in Ohio, known as the “Mound builder’s works.” It is curious that from one spot only outside the Ring can a view be had of the inside; this is a certain point ona ridge about 100 yards from the vallum on the north side, and on the spot is an old thorn bush known locally as the fairy thorn. It lies N.E. of the cromlech. The fascinating mystery of this ancient monument has for The Giant's Ring 15 generations excited the curiosity of many people of historic and antiquarian tastes. Within the last few years it has been placed under the guardianship of H.M. Office of Works, who have ample powers to protect it from destruction. In the early part of last year I had an interview with the Board, and laid before them the fact that a number of local gentlemen would be willing to provide the funds necessary to investigate and excavate the Ring if the Board would give them permission. They advised us to form a local committee who would be responsible for the proper carrying out of the work under their supervision, and guarantee that no injury would be done to the structure, and that everything would be left as we found it, and that any antiquarian remains found would be handed to the local Museum. The necessary preliminaries having been satisfactorily arranged, a liberal sum was contributed towards the expenses, and work was commenced on Monday, the 10th September. I have to acknowledge the kindness of Mr. Gray and Mr. Thompson, the tenants in possession of the Ring, for their permission to make the excavations, and for their help in many ways in forwarding the work. The vast extent of the Ring of course prevented any thought of excavating it all over, so we decided to sink trenches radiating from a small circle round the cromlech. In dry weather in certain places in the Ring the grass dries up and yellows in patches, suggesting the presence underneath of stone slabs or hollow cavities as the cause. Several of these were noticeable in a line running east of the cromlech, so we began the first radial trench, No. 1 in the plan, to cut through some of these patches. We found the undisturbed till to lie evenly 15 to 18 inches under the surface, being of the glacial deposit common in the whole basin of the lower Lagan. The yellow patches were not caused by slabs of stone as we thought possible, but merely by some extra porous spots in the gravelly nature of ‘the till. We extended this trench to the inner edge of the Vallum, but nothing in the way of. archaeological remains rewarded our 16 Mr. H. C. Lawlor on search. The trench was accordingly filled in and carefully resodded. ‘The same negative result awarded our excavations of trenches 2 to 6, the only noteworthy feature being that while the depth of the undisturbed till below the grass was mostly 15 to 18 inches, at the cutside end, as we approached the vallum the surface of the till descended somewhat steeply. Thus the surface of the till underneath the soft top soil of the surface of the whole enclosure resembles the shape of an inverted saucer, of which the centre is some 10 feet higher than the edges. The depth of the soft top soil at the outer edges increases to from five to six feet deep, so that the visible surface also has the inverted saucer shape, although to a much less extent. The circular trench round the cromlech was dug so as to approach the latter not nearer than 20 feet. In it nothing of interest was found, and all were filled in and _ resodded. Our object in sinking the circular trench so far from the cromlech was to avoid any possibility of loosening the fuunda- tions of the great stones. ‘This caution was necessary, as had there been any previous disturbance of the firm till in the immediate vicinity of the stones, such as the presence of a cist or urn chamber, there would have been some danger in excavating to any depth too close to the stones. As the work proceeded, however, it became evident that there was little danger. as the upright stones are well and truly set on the hard till, and no cist or chambers exist round the outside of the monument. We sank narrow trenches radiating inwards from the circular trench with- out finding anything of note, except at one point only. In the trench north-east of the cromlech we found at 15° down, spread on the hard till, a layer of brown black sooty remains of fire. » We followed it until it disappeared, exhibiting the fact that it only extended some three feet in diameter, with a depth of only about one inch. The fire remains were evidently extremely ancient, as it required a glass to see that they contained fragments of burned wood. No remains of bone could be detected in the black soil, but a stone hammer, the only implement or fragment The Giant’s Ring ys of implement or utensil discovered in our researches, lay in the fire remains. In all our investigations we found no single vestige of pottery, no pieces of worked flint or shaped stone, only this one elongated oval stone chipped at each end by hammering some object. The accompanying larger scale plan of the immediate vicinity GIANTS RING. Cc? DOWN. Plan shewing Irenchey_excavated eases — Vis ve / jo if ey | == Se a \ ‘ oN = \ \\ < PN NN of the cromlech shows the position of the stones as they remain to-day, and also the places where we excavated. It is of import- ance to draw a distinction between the stones that are set on the 18 Mr. H. C. Lawlor on hard till and those that lie only on the surface. The original supporting stones are all set on the hard till. One very large stone stands upright, leaning against the main structure on the north side, but it is not set on the till. There can therefore be no doubt that it was originally a second top stone of the crom- lech itself, fallen down through original faulty erection, or more probably by the action of modern destructive hands. The earliest known description of this cromlech is that in Harris’ County Dowa, published in 1744. If his description is correct, the monument has suffered much since then. He says : alt consists of one huge upper stone, almost round, 7ft. lin. by 6ft. Llins. ; two ranges of rude pillars support it, each consisting of seven, and round it at about 4 feet distant are several fixed stones not above two feet high.” The possibility of the correctness of Harris’ account has been called in question by a writer in the Dublin Penny Journal as long ago as 1834. Mr. Borlase thinks that Harris’ account was probably correct, and that the outer ring has been removed for building stone. The removal of these seven stones of the outer ring might account for the fall of the second top stone now lying on its edge on the surface of the top ground; but Harris men- tions only one top stone, the one that still remains in its place. It rests actually on three stones, not on seven, though there are seven upright stones besides the fallen top stone. The ~ several fixed stones” (now two in number) “ not above two feet high at about four feet distance” are still there. Now the nearest one of these to the uprights of the cromlech is only 2ft. 6in. there- from, whereas Harris says 4 feet from the alleged outer row of seven stones. Had there been such second or outer row of seven stones they would actually have touched this smaller stone, not been 4 feet from it as Harris states. Had builders come to quarry stones for their work from the cromlech it is inconceivable that they would not have first taken these two comparatively small outlying stones which could be easily lifted; as the monument now stands, and as it appears to have stood in Duberdieu’s time, The Giant's Ring 19 and I think probably in Harris’ time, it consists of one top stone in position, one top stone fallen and seven upright stones, besides the two outside disconnected stones, or eleven stones inall. Mr. Borlase says “there appear to have been two covering stones, one of which has fallen owing to the removal of the side ones.” Yet Harris in 1744 says there was only one top stone, although he says the alleged side stones were then in position. So that in this detail Mr. Borlase seems to contradict himself. On the whole I think the evidence tends to prove that Harris’ account is inaccurate, and that the cromlech remains almost in its original form, except that even prior to Harris’ day one of the top stones had slipped down to its present position from the top of the three upright stones it lies between, which would still support it if raised up. Having closed up and re-sodded all the excavations near the outside of the cromlech, we proceeded to sink a narrow shaft under the cromlech itself. This excavation proved that we had been forestalled by someone who unfortunately never seems to have placed his discoveries on record. The soil was quite loose, and at nearly four feet down were fragments of modern lemonade and porter bottles. Every spade full of soil taken out was care- fully examined. A few fragments of burned human _ bones occasionally appeared, not a teacup full in all. Whether the previous explorer had found an urn containing bones, or merely found burned bones buried in soil, there was nothing to indicate. Not a fragment of pottery was forthcoming. Had the previous investigator found an urn full of bones and taken it away, why would bones be found through the loose soil? On the other hand, if he had found merely bones buried in soil, he may have removed a portion of them, and what we found were the remainder, reduced in quantity by decay more rapid after his turning them up. I have made enquiries in every direction I can think of as to the existence of an urn from this site, either im museums or private collections, but can find no trace of such. There may have been one, but from my experience gained in the 20 Mr. H.C. Lalor on investigation of the Cairn Grannia at Mallusk, I am of opinion that the interment in this dolmen was one of incinerated remains in the soil under the cromlech without an urn. In the Cairn Grannia there are nine distinct cromlechs joined together in a line. In each one examined the burial was of incinerated remains in the soil ; two urn burials were found, but they were evidently of later date and not under distinct cromlechs. As I have mentioned, the Giant’s Ring cromlech is not in the geometrical centre of the Giant’s Ring, but some eight or ten yards to the south-east of that point. We ascertained by accurate measure- ments the exact centre of the ring, and sank a circular pit five yards in diameter there. The hard till was 15 to 18 inches beneath the surface, and this excavation was entirely negative in results. We also dug several other pits where we thought slight hollows or dry patches existed, but had no better results. Our original intention had been to continue the sinking of these radiating trenches all the way round from the cromlech, but as the results obtained in the excavations already made were so completely negative, we decided to discontinue further ex- cavations in this direction. In all we had excavated nearly 600 yards of trenches of an average depth of about 18 inches down to the undisturbed till. With the exception of the remains of a small fire and a stone hammer lying a few feet north-east of the cromlech, not a single thing was found in excavating outside the cromlech to indicate that the site had ever been occupied in any way by man. It may be urged that our actual excavations only covered, in all, some 400 square yards out of a surface of some 10 acres, and that we might easily have missed valuable discoveries ; which may be perfectly true. The final excavation we made was to cut a trench two-thirds across the mound itself down to the original ground level, some 15 feet in depth and 4 feet wide. The accompanying section of the mound, kindly prepared by Messrs. Fennell & Clarke, admirably shows the dimensions. The : as 2 * 5 TH E S, eS e226 0G 400 Scait tt contd ete eects aes eee The Giant's Ring Pil material of which the mound is made is chiefly small roundish boulders covered with an outside layer of earth and sods. A certain amount of earth has filtered down from the outside among these stones, and in places among boulders were pockets of earth. The boulders were of the glacial deposit type characteristic of the locality. It is, however, a remarkable fact that we found no large stones ; all were small stones of which an ordinary man could easily carry one or two in his hands from some distance. Now, had this circular mound been made by removing the top of a knoll in the centre, large stones would have been plenty, as we found numerous large stones in course of our excavations, and they are of frequent occurrence in all these glacial deposits in the immediate neighbourhood. One is therefore forced to the con- clusion that the material from which the mound was built was carried by the hands of a large number of workers from the country round, and that the almost flat or slightly convex enclosure is in its original shape. It would be futile to conjecture now who were the builders; were they bands of slaves owned by the surviving relatives of the great and important person buried in the cromlech? or were they voluntary tribesmen who, out of respect to the memory of the deceased, continued to carry stones to cast them on the mound as they passed until it gradually assumed its vast propor- tions? I rather think the latter is the more probable, as had slaves been employed, they would not likely have heaped up only small stones; again, the ancient Irish custom of passers-by throwing a stone on the cairn of some deceased chief or king is well known. The division of the mound into seven distinct ares or sections may also suggest that the work was done by seven separate tribes owing allegiance to the deceased. The measure- mentsof these arcs might accordingly be anindication of therelative sizes of such tribes, and it may be of interest to record the length of the sections. The following are the measurements, com- mencing with the section to the left of the entrance, and measured b 22 Mr. H. C. Lawlor on along the top of the ridge :—259 ft. ; 250 ft.; 382 ft.; 387 ft.; 427 ft.; 170 ft.; 205 it. ; total, 2,080 feet. The measurements of the enclosure to the bottom of the inside of the mound are east and west 599 feet, north and south 588 feet. The average width of the mound at the base is about 80 feet, so that it will be seen the Ring is almost, though not quite circular, with a diameter over all of about 250 yards. I have referred to the great depth of the soft top soil cover- ing the hard boulder clay immediately inside the mound. This is carefully shown in the sectional diagram, and proves that originally the mound was at one time considerably higher, a great deal of soft mould having been worn down by weather and spread over the ground at the bottom. It is noteworthy that in the immediate vicinity of the Giant’s Ring numerous antiquarian remains have from time to time been found. Thanks to the painstaking work of the late ~ Mr. McAdam, editor of the original Ulster Journalof Archaeology, and the late Mr. Getty, an account of these, so far as they could ascertain particulars in the year 1855, was published in that Journal.* Fortunately the farm immediately to the north side of the Ring was then in possession of the late Mr. David Bodel, representative of a family who had been in continuous occupation of the farm for at least three or four generations. Mr. David Bodel aud his father before him took an intelligent interest in such matters, and although in agricultural improvements to their farm they had destroyed many ancient monuments, Mr. Bodel was able to supply Mr. McAdam with a pretty full description of such of these monuments as he had either seen or found himself, or his father had described to him. One of these was discovered by Mr. Bodel in 1855, and I take the following from Mr. McAdam’s article. This ancient sepulchral Chamber lies almost due N.W. of the Giant’s Ring, about 4/500 yards distant, in a small plantation of Scotch fir at the west end of the farm house. ‘The floor of the Chamber * Vol. iii, p. 358 et. seq. The Giant's Ring 23 is about five feet below the surface of the ground, and is three feet high in the centre. The depth of the top of the roofing stones below the surface is 18 inches. In the Chamber when found were four urns containing burned bones, besides a number of skulls and other bones, human and otherwise, some burned and some not. The urns were too fragile to preserve ; the bones were removed by Mr. Grattan for examination. After examination the Chamber was carefully closed up, and remains, I believe, still intact. Of the other remains of which Mr. Bodel supplied a description, I shall quote from Mr. McAdam’s article. “In addition to the facts observed upon the present occasion, it may be well to record, upon the testimony of Mr. Bodel, that the field in which this discovery was made forms part of a farm held by him and his family for several generations ; and that, on various occasions, he and his pre- decessors have discovered throughout the same piece of ground indications of extensive interments ; vast quantities of human bones have been turned up by the plough, both in his own time and that of his father, especially in the vicinity of the present dwelling-house. In the boundary fence of the field, facing the Giant’s Ring, is an enormous stone which he suspects to be a Cromlech, and intends to have uncovered. Very near this spot there were taken up in the field, a little below the surface, many cartloads of human bones, but without there being any mound or mark to distinguish the place. On the site of the dwelling-house itself, which is not many perches distant, was a mound, which on being removed at the time of building the house, disclosed several short stone coffins or cists containing earthen urns and burnt bones. In several parts of the same field similar cists were found subsequently, all formed of stone slabs, and having a slab at the bottom and one as a lid’ These in most cases contained urns. The coffins were all shorter than a man, In one of the urns was found a skull by Mr Myr. H. C. Lawlor on Bodel himself; in each of two others bones and a stone implement. One of the implements was minutely described by Mr. Bodel as a black stone 6 inches long, knobbed at each end and hollowed between, with a small hole passing through the centre of the intermediate stem. The other was a yellow stone tapering at each end, almost resembling in size and shape a gimlet head, and pierced in like manner at the centre with a small hole. In another urn, along with the usual burnt bones, were two flint arrow heads. Occasionally stone axes have been found in the field. At one extremity of it, furthest from the house, there was a spot several perches in extent, on which the vegetation was observed to be always bad. On digging it up it was found, for several feet deep, to consist of a peculiar dark-coloured and soapy mould, and intermixed with it were observed a number of red stones, presenting the appearance of having been discoloured by strong heat. Near this spot was a small mound, somewhat elevated ; and about fifty or sixty years ago (i.e., about the year 1800), Mr. Bodel’s father, having an idea that he might find something valuable within it determined to open it. On removing the earth a little he came to some large blocks of stone standing upright, and was then fully persuaded that his hopes would be realised. He therefore removed the entire mound, and found it to contain three very large stones placed on end and sloping towards each other at the top. On examining underneath this enclosure he found an urn.and a quantity of small bones, but nothing further. In the same part of the field were found four rings made of a black light substance, like jet, the largest about four inches in diameter, and the other three smaller, in regular succession, the whole of them fitting exactly one within the other, so that when thus placed they presented the appearance of a circular grooved disk. In one part of the field Mr. Bodel pointed out a spot where a pillar stone was buried some years ago in clearing The Giant's Ring 25 the ground. Some coffins and urns, exactly similar to those in Mr. Bodel’s field, were found at different times in the adjoining lands held by Mr. George Thomson, Mr. McKeown, and Mr. Frederick Russell; and there was at least one artificial Chamber discovered resembling the one now described.” In Arthur Young’s “ Tour in Ireland,” published in 1780, the author refers to a mound close to the Giant’s Ring, in which had been found on its removal vast quantities of human bones. He does not indicate how long before he wrote, this discovery had been made ; he may refer to the mound which had occupied the site of the farm house mentioned by Mr. Bodel, or possibly yet another sepulchral mound. Father O’Laverty in his “ Down and Connor” * refers to a funereal mound in the grounds of Eden- derry House, lying south-west of the Ring, in which Urns have been found. It is worthy of note that in these various accounts of past discoveries in this district, particularly in Mr. Bodel’s graphic narrative, while many funereal urns, wholesale internments in mounds, various stone implements and other remains have been found, not a single instance is recorded of the discovery of ancient bronze or other metal. Bearing upon Harris’ statement that in his day, 1744, the cromlech had two rings of seven stones each, or 14 stones in all supporting the top stone, it is important that Mr. Bodel, who was able to describe to Mr. McAdam in 1855 so much of what had happened to the various ancient monuments in the locality for three or four generations, probably back to Harris’ time, makes no reference to the removal of any stones from the cromlech ; it is inconceivable that Mr. McAdam and Mr. Getty should not have made enquiries from Mr. Bodel on this point, and recorded anything he had to say. During our investigations, which extended over a week, we had the benefit of the presence and advice of several distinguished * Vol, ii, p. 240. 26 Mr. H. C. Lawlor on archaeologists, of whom I may mention Professor R. A. S. MacAlister, Mr. Andrew Robinson, of H.M. Board of Works, Canon Lett and others. Professor MacAlister has been good enough to write the following on the result of the investigation :— NoTE By PRoFessor R. A. 8S. MACALISTER, M.A., D.LITT., F.S.A. “That no antiquities of any kind were discovered in the Giant’s Ring is not surprising, having regard to the probable nature of the Monument. Indeed, from one point of view the negative result is not unsatisfactory, as it is an indication that the study of this and analogous monuments, after many and devious experi- ments, has at last settled down on proper critical lines. That the monument was primarily sepulchral may be taken for granted ; also that it belongs to the Dolmen building period. That is to say, it dates from the time of the overlap between the stone age and the bronze age, though probably a little nearer in date to the former than to the latter period, i.e., early in the time of overlap. ; There is no doubt that the stone monument in the centre of the ring was erected over the sepulchre itself, the structure being designed, like all dolmens, after the model of a house. It is, indeed, the “ eternal house” provided for the use of the soul, in which food and the offerings could be provided from time to time. The stratum of burning found in-a patch immediately to the north-east of the Dolmen, may possibly mark the site of a dwel- ling, perhaps the actual dwelling of the deceased, though this of course can only be a matter of conjecture. The mound of earth and stone surrounding the Dolmen (1) is undoubtedly connected with it, (2) is not the rampart of a residential enclosure, for in that case pottery and other signs of | occupation would have been found within it. The total absence of any such objects, and the absence af any signs of disturbance of the soil for graves or any other purpose (excepting recent tillage) is an indication that the enclosure within the mound was The Giant's Ring i) ~I not only not occupied, but was actually avoided. We are in the presence of a religious taboo of some kind. It is not difficult to guess the reason of this taboo. The ground surrounding the Dolmen is sacred to the spirit of the _ dead person ; no unauthorized intruder dare tread upon it. At the same time the fence protects the living, preventing the ghost from breaking bounds and coming out to injure them in any way. Modern savage life presents analogies with both these forms of belief. The modern superstitions connecting fairies with ring-forts of this kind are survivals of this dread. Some of the so-called ring-forts are probably at least primarily, sepulchral ; and fear of the ghost, degenerated in more modern times to fear of the fairies, has prevented intruders from trespassing upon them even to our day. ‘These sepulchral ring-forts (if I may use this not very scientific expression for convenience) are essentially of the same type of monument as the Giant’s Ring, differing only in their inferior size. ‘The unusual size of the Giant’s Ring may be confidently taken as an indication of the great and important rank which the person commemorated by it held among his contemporaries. He was most likely deified after his death ; and the tradition of horse races and other games held in the Ring till modern times may well go back to the games and processions that we may presume were held there periodically in his honour. In this connection it is worth noticing that to the north of the Ring is a ridge from the highest poimt of which (and from nowhere else in the immediate neighbourhood) a view of the interior of the Ring can be obtained. On this view point stands a thorn tree, suggestively called the fairy thorn, though the ridge in question, I am satisfied, is quite natural. That the exact nature of the interment was not discovered in the recent excava- tion can be sufficiently explained by previous looting. Such a monument as this would be sure to attract the attention of treasure seekers as soon as the dread of the Ghost had ceased to influence the population. 28 Mr. H. C. Lawlor on The Giant’s Ring Like Stonehenge, the tomb sanctuary became the centre of a bronze Age cemetery, the graves of which were scattered around, but not inside the Ring. The nearest analogy to the Giant’s Ring burial that I can quote, in Ireland, is the Bronze Age Sepulchre excavated a few years ago at Longstone Fort, Furness, near Naas, County Kildare.* There was at this place an earthen ring similar to that surround- ing the Giant’s Ring Dolmen ; at its centre was a subterranean cist burial, marked by a tall standing stone. Traces of extensive burning were found around the cist: these the explorers interpreted as the marks of a peat fire, probably lit for a beacon to summon the clans to the burial of the chieftain. The excavation has thus proved that the Giant’s Ring was a tabooed grave sanctuary, into which intruders were not admitted (except perhaps on the occasion of games or other religious celebrations) ; sacred to the spirit of some great chief, medicine-man, or other notable functionary, of the end of the Stone or beginning of the Bronze Age (say very roughly, about 2,000 z.c.). The gigantic nature of the structure makes it certain that the deceased was a personage of outstanding im- portance ; and suggests the probability that the work was carried out to his own plans and during his lifetime, though this again is naturally conjecture only. But it is not unlikely that he might compel his followers to erect the structure under his own superintendence in order the more to impress his own importance upon them. * Proceedings Royal Irish Academy, vol. xxx sec. C. p. 351. 12th February, 1918. THE FOLK-LORE OF NORTH OF IRELAND PLACE NAMES. By Sir JoHn Byers, M.A., M.D. (Abstract. ) After pointing out the importance of the study of place- names, not merely as to their origin, but also in regard to the curious sayings, homely proverbs, and rustic rhymes associated with them, Sir John Byers said certain broad principles might be laid down to form a guide in their investigation :— First—Many place-names are not only very ancient, but also remarkably permanent. Second—Place-names, in their origin, are, as a rule, simple, and show sympathy with nature. Third—Place names are often primarily most utilitarian, except in the case of religion and superstition. Fourth—In the history of almost all countries, and especially so in the case of the northern parts of Ireland, various bodies of people—colonists and conquerors—came at different times, each speaking a mother-tongue of their own. Now, not only did these invaders bring place-names peculiar to themselves, but they also adopted and often altered others already existing. Fufth—Place-names are, in many cases, compounds made up of a substantive or generic term, and a correlative, indicating some attributive quality. In pronunciation, the stress or emphasis almost invariably remains on the qualitative syllable, and this, in English place-names, usually precedes the other, while, on the contrary, in Celtic words, the qualitative usually follows the substantive. Sir John Byers illustrated each of these principles by humerous examples, and gave a selection of proverbs, sayings, and rhymes associated with a large number of North of Ireland place-names. 12th March, 1918. THE PSYCHOLOGY OF TELEPHONY. By Mr. rasta M.A. (Abstract. The true student is always working at experimental psychology. The working of the human mind is the most en- trancing subject, and wherever we are we can watch its operations. The waiter in Mr. Bernard Shaw’s early comedy asked us all to watch the working of the barrister’s brain. But not only barristers have brains, and the true experimentalist will wish to gather his data from a wider field. He will be interested in the human mind normally, so to speak. He will watch carefully when any factor comes into the normal life which will enable him to study the human mind afresh. Now I am about to claim that the telephone is such a factor. It will be my effort to show that some of the fundamental problems of psychology are capable of fresh consideration by reason of the data which the use of the telephone has placed at our disposal. For the telephone was something more than a new instrument of communication ; it was a revolutionary change in our method of communication ; the telegraph was less revolutionary. The written message still obtained, not essentially different from the written message which we put carefully in an envelope. It was more brief, more blunt. It eschewed the pretty politenesses of the ready letter writer, the “kind regards,” the “ Yours faithfully,” the “best love to all,” and “hope to find you well as it leaves me at present.” It went to the point without fuss or flummery. But the telephone wrought a revolution. It brought us back to the courtesies of speech ; it threw the cumbrous art of handw™ting overboard. It called on us to face each other direct ana without inter- mediary, and so it affected our mental relationship. Deep called The Psychology of Telephony 31 directly unto deep. And so it came about that the rector of a distant Yorkshire village, what time he spent his leisure making the telephone into a practicable means of day-by-day communica- tion, really wrought more wisely than he knew. He really set out to put the human mind to a severe test, for the human mind had grown accustomed to the written word as its means of com- munication, and not readily, as I hope you will see, did it fit itself into the new conditions. Telephony is only at the begin- ning, we have heard again and again, but I think it is nearer the truth to say that the human mind in its appreciation of the differences which have been wrought by telephony is only at the beginning. To begin with, we have not grasped the central fact that the telephone annihilates distance. Whatever may be our explana- tion and our theory of the Kantian categories of time and space, the fact remains that the telephone illustrates how deeply the framework of space is upon our minds. It is shown in the first place by the way we bawl into a telephone. That comes from the idea that the persons to whom we are speaking is far away. We shout as if we were shouting at them across a valley. The fact is that the people are very near to us. They are so near, in fact, that in auditory efficiency they are only a few feet. This is proved by the use of the telephone for persons with inefficient hearing, where the telephone actually is only a few feet distant. But our mental framework is such that we cannot bring ourselves to realize that the telephone has annihilated distance, that it has broken down all walls and barriers, that it has given us a whispering nearness to the person to whom we are speaking. Which of us, using the telephone, realizes for 2 moment that our lips are to our friend’s ear? That puts in a phrase the fact that we have but little conception of what the telephone has done in the annihilation of space. Now let us examine the content of this conservative psychology. In the first place the phraseology which we use is based on the emphasis of distance. It is as though we thought 32 Mr. John Lee on we are still speaking with two tin cans and a drum of parchment, now shouting at the parchment and now turning our mouths away and shouting through the pure air, “Could you hear that Bill?” The favourite phrase is“ Are you there?” It is an emphasis of distance, a puerile phrase, an indication of vacuity of mind, for indeed we should shudder if the answer “No!” came along. The word “Hello!” which is regarded with disfavour nowadays, took its origin in the convenient shout which made the hills resound. We need other phrases, but much more than that we need the psychological realization that the person to whom we are speakingisclose by. Until we get this psychological realization we shall never use the telephone efficiently. , No matter how Science may improve it, no matter how clearly and distinctly the newer receiver may give us the distant voice, so long as we have the framework of distance and of wonder as the primary outfit of our minds, just so long shall we shout “Hello!” and “Are you there?” and so long will the telephone continue to be a tin can and a parchment diaphragm. * This conception of distance vanishes from the mind of the expert. I could show you a group of ladies speaking with infinite ease from London to all the great towns of the country. They pass from the Brighton subscriber to the Liverpool subscriber with infinite ease. They speak in a soft, subdued voice, a trained voice, as if they realized the new intimacy. They are not overwhelmed with the wonder of the thing ; they are taught to harness the lightning and not to shudder at it. They will say “Liverpool” with a rising inflexion, which meaus “ Please tell me, Liverpool, if you are within earshot ;” they will reply “Liverpool” with a falling inflexion which says: “I am in attendance ; I am Liverpool and not Newcastle-on-Tyne”; but it does not say or suggest “I am at Liverpool, two hundred miles away.” ‘That intimate and trusting use of the telephone needs to be cultivated and then the telephone will be really useful, but it is not done in a generation. The framework of mind to which we have grown accustomed is not readily changed. ‘The The Psychology of Telephony 33 psychology of adaptation to habit throws its tyranny over us and holds that tyranny fast for many a generation. This is why we use stilted speech and why we shrink from intimacy. We speak in the mode of the writer rather than in the natural mode of the speaker. We labour under the burden of distance, which is always present with us, and we speak on the telephone, as Queen Victoria said of Mr. Gladstone, just as if we were addressing a public meeting. The personal nature of a telephone conversation has not yet been grasped. Of this fact we can see various evidences. The telephone is used outrageously in the drama. The speakers bellow through the instrument, and their conversation is a repetition of what the other fellow says:— Mayfair 1861, that you Jimmie? Oh, you are going to catch the 12-30 to Bournemouth, are you? Ah, it will be a very pleasant day. Yes, I like the Royal Hotel, too.” ‘There is a typical stage conversation It includes what Jimmie said and no more. In fact it is designed to convey what Jimmie said and nothing else. It is the crudest of stage conventions. But it is having one more influence in robbing the telephone of its intimacy. After seeing a telephone play who would trust the instrument with any secret at all? What may thus be said of the drama can be said with redoubled energy of the Kinema. Watch the Kinema actress seize the telephone! Watch her as she brings it to her mouth! You can literally see her shouting into it. If ever there is a time when one rejoices at the silence of the Kinema it is when the telephone is in evidence. Indeed the telephone and its particular utility in disseminating sound has become the very warp and woot of the Kinemadrama. And that is not the function of the telephone at all. It is the most secret of methods of communication. To-day between 10 a.m. and 11 am. there were some 20,000 conversations in Belfast They were intimate and secret The operators do not listen to them ; they have something else to do, for the operator’s work is so scientifically scheduled that she connects some 240 calls in the hour, and you will at once see that she has little chance of 34 Mr. John Lee on listening, and if she had a chance the one thing she would have no taste for would be to listen. It is safer to speak on the telephone than to speak in a tramcar; it is safer to speak on the telephone than to write. Yet none of us really comprehend the fact. I am assured that love-making on the telephone is only indulged by rare souls who have learned to trust the instrument. I heard a story some years ago of a man who was known by all the public (including the telephone staff) to be appallingly in love with his wife; it was in the earlier days. An operator found him speaking to his wife; the temptation was too great and she listened, alas! ‘‘ And besides,” he said, “I think I saw a cobweb over the middle of the sideboard. Id sack her, if I were you.” It was unpoetic; it cured the operator of listening. But if you want evidence on this heading come with me to the realm of fiction. English fiction makes a good deal of the love interest. Yet you never can find an instance of a love scene on the telephone. The young couple will speak by telephone, but it is a chastened and restrained conversation. I saw a novel last year which handled the situation in this somewhat crude fashion : “Molly!” “Yes, dear.” “Did you get my letter?” “Yes, what a lovely letter!” ‘‘ Which part did you like best?” “Oh, the last paragraph, it was lovely!” “Ill write again to-night.” ““ Will you say it all over again?” “Yes, dear.” “That will be lovely.” Personally, I do not believe that such a conversation ever took place; I doubt if any self-respecting telephone would stand it. But it throws a light on telephone psychology. The writer of that novel was perfectly certain that on the telephone you could only hint at what you intended to say, and that the real declaration of one’s inner feelings must be under a sealed cover. I shall come back to this aspect of the question later, but this timidity is all a part of the one fundamental characteristic of our use of the telephone—we have not realized that it annihilates distances—we have not realized its beautiful intimacy. Space is part of the framework of our minds, except The Psychology of Telephony 35 when dissolved by the faculty of sight. Some telephone _ philosophers think that we shall never be rid of the disability until seeing by telephone (so to speak) becomes an accomplished fact ; just as we read in that ancient classic, the Book of Job, “LT have heard of thee by the hearing of the ear, but now mine eye seeth thee.” Something has been done in that direction, but not yet is it part of the interchange of communication, and I am afraid that it is not likely to be. We shall have to modify our telephone psychology without the aid of sight, and it will be a good discipline for us. Much the same might be said as regards time. For some mysterious reasons, which I cannot explain, time is always erratic on the telephone. I have had respectable citizens, even ministers of religion, tell me in days gone by that the operator kept them waiting ten minutes. In one case it was a bishop, usually harmless, kindly disposed, and a lover of his kind. He had waited 35 seconds for an answer—too long, we admit, but his conception of the period was amazing. I tried him with my official stop watch, and I asked him to guess the length of certain periods of time both with the telephone in his hand and without the telephone. His guess was wonderfully accurate without the telephone, but with the telephone invariably he quadrupled the time once it got beyond ten seconds. Other citizens are affected in the other direction. They ask for a number; the operator picks up a peg and taps the terminal and finds the number engaged. She conveys the information to the caller. Of course she is quick ; she is trained to be quick ; we know to the decimal of a second how long it takes her to perform the operation. But I am constantly told that she never tries at all, that she just says number engaged” out of spite or negligence. And this summary reflection on her honour is always based on the pre- sumption that the interval of time is not sufficient. Now it may as well be said that with the telephone in one’s hand the estimate of the lapse of small periods of time is invariably aberrant. Why it should be so I do not know, but I have tried my own estimate 36 Mr. John Lee on again and again and have found it hopelessly wrong. Certainly I am not ready to condemn an operator merely on my own conception of the passage of time ; nor am I prepared to pit my conjecture of the passage of time against that of the various appliances given to the operator for making the record, appliances which both indicate the time and check the record. There are circumstances in which three minutes seems to be a desperately short period ; I expect the young man and maiden, to whose conversation I have already alluded, would think it had only lasted seconds when, in truth, it ran into tens of minutes. Other types of conversation seem to be prolonged. But the telephone machine is ruthless. Three minutes in its eyes are three single minutes. The operator who asks you to have another call has no interest whatever in cutting you short. She herself has her observers. She is doing her duty under the eyes of strict supervision. She is not knitting, even in days when all the rest of the world is knitting. She is not reading novelettes. She is not talking to her young man, that phantom young man of the subscriber’s fancy, for to her the telephone is a professional thing, and even when all the rest of the world does its love- making by telephone she will scorn to do so. For to her it is unpoetic, her bread and butter, her craft. To the rest of the world it isan embroidery on life ; to her it is life itself. It has modified her conception of space and time in that it has made them real and accurate, the things-in-themselves. The rest of the world are only in process of having its conceptions modified. Psychologically she is in advance of her time. There are other characteristics. It is strange how numbers are affected by the telepbone. New limitations of memory are revealed. The transposition of digits follow broadly certain well- known laws. A subscriber will look at the directory and pick out a umber, say 3547. This is a difficult number to remember in the brief period which elapses from the printed page to the telephone. Why? Because the human mind yearns to give the figures in sequence, and it will give them in sequence unless it is The Psychology of Telephony 37 watched. So that 3547 becomes 3457 in, as we may say, the twinkling of an eye. You will agree that there are certain numhers which will not stick in your memory. There are many instances where subscribers are frequently unable to remember their own numbers. The introduction of the “double” was a help. 3, double 5, 7 is an easy number to remember, for this reason. No doubt some of you have felt aggrieved when we introduced “O” (Oh!) instead of “0” (nought), yet we had a reason on our side. It is much easier to articulate “Oh” than “nought”; it is especially to be appreciated in respect of “double oh” ; it is a clearer demarcation from 9. A telephone company in the middle West of America once proposed the substitution of “cinq” for “five,” in order to avoid the old confusion between “9” and “5.” That was an heroic sugges- tion. We have to get over it by teaching the staff the careful articulation of “ five ”—rather long—and “nine,” crisp and sharp. You will notice, though it is uot so striking in Belfast as else- where, because it is nearer the normal in speech, that our operators roll their r’s, that they say “sev—en,” that they pro- nounce the consonants clearly ; of course they repeat back the figures, as a safeguard, rather differently from the way in which the subscriber has passed them. All this, you say, has nothing to do with psychology ; it is a mere matter of articulation. But it has a great deal to do with psychology. Do not forget that the telephone is a metallic instrument. It makes its speech by the vibration of a metallic diaphragm. Compare this to the beautiful flexibility of the human instrument and you will realise that the telephone is at a great disadvantage. Moreover there are some sounds which it is said the telephone does not carry at all, such as sibilants. Now here comes in psychology. The telephone auditor, in listening to the sounds which reach his ear has to build them up into the likeness of speech which reaches his ear direct and without the interposition of a metallic diaphragm. There are therefore two arts involved.’ There is the art of telephone speech, which has acquired by a process c 38 Mr. John Lee on largely subconscious the method of masking those sounds which are less efficiently carried by the metallic medium and of slightly emphasizing those sounds which are definitely and clearly carried by the medium. There is also the art of telephone hearing by which one learns to rely on the clearer consonants and to fit in the sounds which come less definitely. So it comes about that the person who hears most efficiently on the telephone is not the person whose hearing is most acute, but he who has reasonably good hearing and who also has the quasi-musical gift of building sounds into sound phrases, “out of three sounds he makes,” as Browning says, “not a fourth sound but a star.” Everyone is not equally successful with telephone speech, but it is true that far more persons are successful with telephone speech than with telephone hearing. Having said this by way of fundamental, I have to point out that there are further subtleties. In some extraordinary way not yet explicable there are certain sympathies which we have to take into account. Certain speakers appeal to certain hearers. Certain methods of articulation seem to suit certain psychological tendencies in piecing together the sounds which do come and the sounds which do not come. I have known cases where speakers whom I should expect to be per- fectly clear on the telephone do not produce this effect at the distant end. Also I have known cases where men whose hearing is thought to be imperfect have shown astonishing skill in being able to interpret methods of articulation which do not suit the metallic medium of the telephone. The fact is that the telephone does not seem to us to be mechanical. We have forgotten that it can only apply the transmission of sounds to human use by means of a mechanical medium. There is a great religious leader who is said to be buried with a telephone in his coffin, readily joined up, to be used in emergencies. That was a profound compliment to the telephone. For that religious leader always asserted the purely spiritual nature of the resurrection, and in doing so he forgot that by installing a telephone he was insisting upon a mechanical means of transition, The Psychology of Telephony 39 But something more than the voice is carried. Mechanical though the instrument is yet it does convey a conception of character. There are some, though very few, well-authenticated cases of “ falling in love,” that emotional crisis of which psycho- logists have given so many and so varied explanations, over the telephone, without any personal or direct acquaintance. The New York Telephone Company tells its operators that the culti- vation of a soft voice is a sure way to matrimony and points boldly to statistics which proves the thesis quite as readily as they prove anything else. But it is not the soft voice which alone, to use a colloquialism, “does the trick.” There is some intangible method or inexplicable method of conveying the sense of character by telephone. The subscriber sometimes lays down his telephone, smiles benignly, and says “ That is a real, nice girl.” Of course she is. But why does he sayso? He knows nothing of the colour of her hair, the poise of her head, the slow graceful carriage of her body, all so dear to the novelist who describes in his own way the motions of love. She has spoken courteously to him—perhaps to the extent of half-a-dozen words, and at once he makes up his mind that if the worst comes to the worst he will take her as a daughter-in-law. He sums up her charac- ter in a twinkling, without a shadow of doubt, not caring how she behaves to her brother, what her ideals are for the future govern- ment of the world, or how she could make a currant cake, in days, that is, when there were currants. I believe that the arrival of our young women as telephonists in France had a marked influence. Crusty generals adopted almost tender addresses ; weather-beaten colonels found the telephone suddenly efficient ; subalterns developed new chivalrous instincts. They could not help it, for courtesy and determination to help are infectious. Indeed I could go farther. The telephone reveals character in an amazing way. Ordinary interchange of speech often hides our motives. “ We say unkind things in a kind way.” But the telephone brings out the hidden springs. John Smith, whom you know as a decent citizen, cordial and reasonably kindly, is 40) _ Mr. John Lee on known to be a brute on the telephone. Not that he changes his spots like the leopard, but that the telephone reveals the spots. There is something to be said, therefore, for the Cupid-blind method of making perfect marriages, not in Heaven, but by the telephone. Only those who do it must trust the telephone abso- lutely and, as I have shown, it is not easy. For the average man or woman amongst us the telephone will be an enemy to love- making. It will reveal that skeleton in the cupboard of our characters which, at any cost, must remain hidden. The tele- phone is the Mother Hubbard who goes to the cupboard and finds not merely a bone but the complete skeleton. There is room yet for a vast amount of research on this subject. Not indeed that those of us who have spent years of our lives associated with telephone practice have ignored the subject. But for the true investigation the student will need a considerable knowledge of the mechanics of voice production and of the science of acoustics. Even so, he will be imperfectly equipped unless he has some acquaintance with the modern developments of psychology. For some of the margin of these studies belongs to psychology. You will readily understand now how strange errors occur in telephone speech. There have been instances where whole phrases have been imagined, to use the popular phrase. It is as if the sub-conscious mind, in building up the material which I have indicated, was sometimes urged forward to operate beyond its proper limits. And other senses come into play. I once knew a telephonist who, whenever she had the task of controlling a certain circuit, always declared that she could smell the chemicals, which were notably allowed to escape in the town at the other end. The remedy was simple. A telephonist who had never been in that town was altogether unaware of the smell. Indeed we have found that the active co-operation of the sub-conscious mind in telephone operating has produced the most curious results. It has not the check which vision places upon it, and in some temperaments has heen rather inclined to lead to difficulties. But you must remember The Psychology of Telephony 4] that in saying this we are dealing with a twilight realm. The simple fact is that clear enunciation of consonants reduces this twilight realm to very small dimensions. The experienced auditor, using reasonable care, reduces the possibility of error to almost a negligible degree. In that division of the Head Post Office where telegrams are accepted by telephone—the most severe ordeal to which the telephone is subjected—there is a singularly small proportion of error. Of course we take special pains and it is a subject which is always being studied, but in the main it is true to say that the errors are no more numerous than in the case of telegraphs proper. And it has long been known that even in respect of telegraph symbols, clear and definite though they appear to be, psychological factors have their place in the accuracy of signalling and receiving. The new science of experimental psychology is making big demands upon us to-day. Even vast wars are influenced by psychological means: the temperament of nations is regarded as a proper field for the operation of suggestion, and it looks as if the might of arms were within the influence of psychology to some extent which we cannot estimate. From great things we come to small, and I claim that if we are to use the telephone efficiently we cannot despise the close study of these psychological factors. If we kept some sort of open mind on the subject, some sort of tolerant expectation of more light, we should be less prone, at times, to lose our tempers and less prone to blame a body of women who are rendering the public really faithful and zealous service. For the greatest beauty of the telephone lies in the fact that it makes a corporate demand. The best telephone in the world cannot give an efficient service to the man who does not speak clearly to the middle of the diaphragm and does not strive to gather together all the elements of sound which go to make up the speech which is destined for him. The psychology of the telephone is the psychology of mutual dependence. It affects us far more than we suppose. It modifies our speech > it quickens and enlightens our hearing ; it sharpens that sub-conscious mind 42 Mr. John Lee on The Psychology of Telephony which works ever on our behalf. It shows us that evidence which we take to be certain is not always positive ; it warns us that sometimes we err in that unconsciously we have made a a mental contribution to contributory facts as they seem objectively to be. It is a check against over-confidence, a guide- post against assertiveness, a builder of character in that we learn the lowliness of the human unit and his dependence upon factors the existence of which he has scorned. ‘Thus I claim for tele- phony a creditable position in the world of psychological practice- Not yet has it come into its own. Only for some 30 years has it affected on any considerable plane our day-by-day lives. But when the day comes, as come it may soon, for the telephone to be extended so as to fulfil more nearly its proper function, we shall realise how great has been its kingdom over the human mind, for in that day the kingdom of the human mind will have its true place among the realms of earth, its true dignity in the league of nations. 9th April, 1918. DISCONTINUITY IN THE PHENOMENA OF RADIATION. By Mr. James Rick, M.A. The idea of continuity has been of supreme importance in the development of all departments of Science. Let us be clear at the outset as to What this idea implies. It certainly does not preclude the possibility of swdden changes, 1.e., changes in the properties of bodies taking place at rates which are to be regarded as very much greater than the normal values for such rates. To take a simple example, the impact of two billiard balls offers an illustration of the fact that a change may be sudden without being discontinuous ; for we have no reason to suppose that the laws of motion, to which the balls are subject at the other periods of their motion, are inoperative during the brief interval when they are in contact and their surfaces are being progressively strained from their normal shapes and restored to it. A dis- continuity in a natural occurrence implies the existence of a period of time, long or short, in which laws, previously assumed to be of a general character, are found to fail and cease to explain the occurrence in a manner consistent with established principles. It is in the realm of Biology that the notion of continuity has made its most sigual contribution to the advaucement of science. The assumption of the evolutionary growth of all living forms from protoplasm without the intervention of “special creations” is the most striking example of the application of the principle of continuity to which one can direct the attention of a general audience. Yet even in this department of science pheno- mena in which discontinuities appear to be present have been plentiful ; so much so that the particular theory of variation of species which is associated with the name of Darwin has had to 44 _ Mr. James Rice on be modified and extended in the constant endeavour to obtain a principle wide enough to bridge the gaps which constantly come into view with our increasing knowledge. The part which continuity has played in the development of Mathematics and Physics is not so well known, but students of those subjects can bear testimony to the fact that without it their present position would not have been attained The calculus is the very embodiment of mathematical continuity, and it is in the realm of the so-called “continuous functions” that it has given the most striking examples of its power. The belief that all physical and chemical phenomena are but continuous transformations of energy from one form to another, which could ultimately be explained by the laws of Dynamics, has had a pro- found effect on the minds of all physicists and chemists. But the struggle between discontinuity and continuity is making itself felt here in a manner too marked to ignore. The desire to found his subject on a vigorous and unassailable basis has of late driven the mathematician from those elegant applications and developments of mathematical analysis with which all mathe- matical students are so familiar, to the close and careful scrutiny of his methods and assumptions and the thorough study of those discontinuities and singularities in mathematical functions which his predecessors used to pass by with airy indifference. In Physics we are faced with difficulties of a like nature. By reason of the refinements of modern experimental methods older theories of radiation and the heat content of bodies have been found wanting. Where we previously pictured an output of energy in a continuous and orderly fashion, we have now apparently to postulate something of a catastrophic nature, a discontinuous emission of energy, whose essentially disturbing feature is not so much its suddenness, as our inability to fit it into the scheme of laws and equations which have hitherto served to summarise our knowledge in this branch of science. The solution of this diffi- culty will, it is expected, provide us with the key to several other ditfieulties still preventing an advance in this subject. Discontinuity in the Phenomena of Radiation 45 It is to this particular difficulty that I wish to direct your attention this evening, and to make the matter as intelligible as possible to the non-physicists among you, I must recapitulate certain facts and definitions; and in this recapitulation the exigencies of time prevent me paying too much attention to the historical and logical order of the development of the ideas presented. The nineteenth century witnessed the foundation of the energy principle. In a limited form conservation of energy may be said to date back to Galileo, and Newton made a clear state- ment of it for a restricted range of phenomena ; but it is on the work of Carnot, Joule, Clausius, Rankine, Thomson and Helm- holtz that its acceptance in the widest sense reposes to-day. That form of energy which we most readily apprehend is the energy of moving matter—so-called kinetic energy—and the mathematical physicist demonstrates for us how it is to be measured, viz., by multiplying half the mass of the body by the square of the velocity, and, if need be, by certain numerical factors also, according to the particular units in which we desire to express the result—ergs, joules, foot-pounds, etc. Another form’of energy possessed by matter is that known as energy of position or energy of configuration. A body possesses this by reason of its occupying a position of advantage with respect to other matter in the universe which is exerting force on it, or by reason of the fact that it is strained from what may be called its natural shape or configuration. Such energy is generally re- ferred to as “ potential” ; for if the body leaves its position of advantage or returns towards its natural shape it does so with increasing movement, i.e., with gradual increase of kinetic energy, so that this acquired energy of motion may be said to be latent or potential in the matter as it was originally situated or strained. The important feature about the possession of this type of energy is that it depends upon the action on the body, by other matter, of forces which arise solely from the position of the body or from elastic stresses set up in the body by its deformation—forces and 46 _ Mr. James Rice on stresses which are quite independent of the body’s state of motion, and which exist whether it is at rest at or in motion through the position or configuration considered. Once more the mathematician teaches us how to measure the amount of potential energy which a body in one position possesses in excess of what it possesses in another, viz., by the mechanical work of the forces as the body passes from the first—and more advantageous— and less advantageous—position. The formulae obtained vary with the nature of the forces involved and the particular laws which connect the magnitude of the forces with the relative position of the body. In one very important case, the energy of a raised mass, the measure is obtained by multiplying the weight by the height, and perhaps by a numerical factor suitable to a special unit of energy. In position to the second another case, the energy of a stretched string, the result depends on the tension and the elongation of the string—half their pro- duct giving the energy of strain. It used to be urged against the workings of the scientific mind that it sought to give a “mechanical” explanation to the universe and to life itself—the implication being that in so doing it affected to regard living matter as a “dead machine,” an automaton without emotions or feelings. The implication was, of course, false, but the original statement contained an element of truth in so far as there has always been on the part of the scientist an effort to explain all physical and chemical changes in terms of movement of matter, especially matter in the molecular, atomic or subatomic form; such movement being always subject to the dynamical laws, which were first propounded clearly by Newton, and whose consequences were fully worked out by the great mathematicians of the 18th and early 19th century. One of the deductions from these laws establishes the existence of an exact equivalence between the two forms of energy just dealt with, whenever the forces involved are of a conservative nature—in practice this would exclude the action of forces arising from friction and percussion. Whenever the Discontinuity in the Phenomena of Radiation 47 body loses energy of motion under these restricted conditions, it gains energy of position and vice-versd, or at all events this conservation can be demonstrated for a system of bodies which, while mutually acting and reacting on one another, are freed from external influence. For many years, the view that heat was a material substance, barred the natural extension of this deduction to the view which regards the molecules and atoms of a body as a system of bodies, themselves subject to dynamical laws, and consequently brings their relative motions and positions within the scope of the energy principle. With the gradual abandonment of the belief in the material nature of heat, came the conviction that heat was but the energy of molecular agitation. This, at all events, was a tenable and highly plausible hypothesis, and permitted a great extension of the energy principle on the assumption that all intermolecular forces, such as cohesion and those developed during friction or impact were subject to Newton’s laws. That was the state of affairs when in 1840 Joule began his famous experiments on the equivalence between heat developed by friction and the mechanical work expended in maintaining the motion of the rubbing bodies. The positive results of Joule’s work and that of his successors constitute one of the finest achievements of the 19th century. After that first step other developments followed rapidly. Not only can matter in its molecular and atomic form possess energy of motion; it can also possess potential energy. Energy of strain becomes resolved into the mutual energy of position of the individual molecules separated as they are from one another in their vibrational movement against their mutual attractions. The absorption by a liquid of latent heat as it is converted into vapour is but the conversion of kinetic energy of the molecules of the fluid into potential energy as those molecules escape from the liquid, and not only rise against gravity but also separate considerably trom one another against the mutual attractions which hold them together in the condensed form. ‘The electric energy of the materials of a voltaic cell, the chemical energies of various 48 Mr. James Rice on substances which enter into combination with one another are also examples of molecular potential energy, and all are capable of being converted into molecular kinetic energy-—it is this con- version we are dealing with when we speak of heat of reaction, combination, combustion, and so on. Indeed we measure such energies by the amounts of heat procurable by their conversion under well-defined conditions. The work of Joule and _ his followers has given us, as it were, a currency in which we can measure any amount of energy and in any form, just as in the world of economics we measure the value of all commodities in terms of one commodity—money. All forms of energy are ultimately measurable in terms of heat energy, although in actual experience we may measure an amount of energy in terms of an energy which is not thermal but one whose value in thermal units is known. We have by no means exhausted all our stores of energy in the short statement just made. Energy, for instance, reaches us from the sun in a form whose importance is manifest to all. It is established beyond doubt that it requires some time to reach us—about 8 minutes in fact. It is decidedly inconvenient for us to conceive a quantity of energy leaving the sun at an instant and turning up on the earth’s surface 8 minutes later, if we can- not make it give some account of itself in the meanwhile. We absolutely refuse to believe that it is non-existent in the interim. There is no material substance in the intervening space to attach it to; so we invent one, put the energy into it, and call it radiant energy. A very arbitrary act, no doubt, and many scientists, even the great Newton himself, had serious doubts about it. Yet the “proof of pudding, etc.” Its justification lies in the coordination of our knowledge thereby effected, a coor. dination whose completeness can only be appreciated by those engaged in the study of physical science. To the physicist, indeed, it is not a question of the existence of the ethereal medium ; his difficulty lies in its nature ; his doubts are centred around the properties he is to aseribe to it. Discontinuity in the Phenomena of Radiation 49 For many years some of the best brains in Europe struggled to show that there was, for instance, no essential differeuce between the transmission of a beam of light through the ether, the trans- mission of an earthquake shock through the earth, and the transmission of a wave through water. But it was just on the nice combination in the ether of the property of rigidity possessed by an elastic solid like the earth with the property of fluidity possessed by water, that full success was wanting. There came a second phase when Clarke Maxwell, abandoning attempts to explain the physical properties of the ether in terms of those of matter, essentially reversed the problem, and began the modern attempt to found an electrical theory of matter by pointing out the similarity of light waves to the electrical waves with which we girdle the earth to-day—although Maxwell himself did not live to see his prediction of the existence of these waves actually verified. Tremendous success followed on this suggestion ; it proved a landmark in the history of Physics; but like all great advances, it brought its own difficulties, and those difficulties have accumulated until to-day it would appear that we are awaiting the advent of another genius, a Newton or a Maxwell, to usher us into a third phase. The trouble is, to put the matter in a crude way, that the ether, so far from being a substance whose existence is in doubt, has acquired such enormous importance that we are hard put to it to explain why it does not possess all the energy in the universe, and why matter, as we appreciate it by our senses, possesses any at all and is not in reality the dead and inert thing so scorned by a former generation of anti scientific speculators. To appreciate the nature of the present impasse, I must ask you to follow me into some considerations of a rather special nature, concerned with the manner in which the _ physicist measures radiant energy and in what particulars he distinguishes one quality of radiation from another. ‘To be sure, in the eye one has an instrument in some slight degree suitable for that purpose—but one too crude and too limited in its range to be of 50 Mr. James Rice on much scientific value. For one thing, the eye is quite incapable of distinguishing between two radiations producing the same colour sensation, which a modern spectrometer will resolve with the greatest ease ; for another, as is well known, the particular qualities of radiant energy which are capable of affecting the retina constitute a very narrow range of the totality of ethereal vibrations. We can probably approach the question in hand by con- sidering a wave motion in a medium where we can follow the occurrences with great ease. Picture a small needle with its point just touching the surface of a pool of water, and compelled by some mechanism to oscillate up and down; a disturbance is created in the water, and alternate crests and troughs travel out with a definite speed from the centre of disturbance. There are obviously three quantities of immediate importance; one is the frequency of oscillation of the needle or disturbing mechanism, i.e., the number of vibrations executed per second ; the second is the wave length of the train of waves sent out—that is, the distance from crest to crest, or trough to trough, or, in general, between two successive rings of water in the same phase of motion ; the third is the speed at which the rings travel out. Of course, when we speak of the rings travelling out, we are refer- ring to an outward movement , not of the water itself, but of a particular form or configuration of the water. As far as the water is concerned, each drop of it is rising and falling like the needle point, and with the same frequency. Very little experi- menting is needed to prove to us that the more frequent the oscillations of the needle the shorter is the wave-length of the ripples. Indeed, a little thought shows that the two are very simply connected, that in fact the wave-length is the distance which the disturbance advances outwards while the needle executes one complete up and down oscillation, so that the wave- length is determined by a division of the speed of the ripple movement by the frequency of the needle’s oscillation. It is clear that for such simple and almost ideal wave motions as these Discontinuity in the Phenomena of Radiation ou one important distinguishing factor is wave-length, or its equiva- lent, frequency. Another feature is the amplitude of the oscillation of the wave particles, i.e., the extent of movement between the highest and lowest point. This diminishes, no doubt, as we recede from the needle, but at any one defined spot it depends on the amplitude of movement of the needle, and may be inereased or decreased by variation of the extent of the needle’s oscillation. So we naturally discriminate between two ripple-trains by the details—wave length (or frequency) and amplitude. The water is, morever, the receptacle of energy which is being imparted to it by the vibrating mechanism of the needle, and which we readily apprehend as existing in one of the two most familiar forms, kinetic energy or potential energy. At places where the water is momentarily at its undisturbed level, the energy is entirely that of motion ; for there each particle is passing through its mean position, upward or downward, with its greatest speed. At the trough or crest the energy of each particle is for the instant all potential, since in the former case the pressure of the surrounding elevated water gives an excess of upward force which will presently impart kinetic energy to the drop against downward-acting gravity, while at the crest the conditions are reversed, but with the same result—possession of potential energy. At other phases of motion the energy is partly kinetic and partly potential. But whatever the form it takes, the existence of an energy in the water, which has _ been “emitted ” by the mechanism controlling the needle, is obvious. I have chosen this very simple and commonplace example of wave-motion, because its very simplicity exhibits all the essentials for a general grasp of radiation problems ; it is, in fact, a case of actual radiation in the wide sense in which that word is used to-day. Allow me to make a little further use of it, in order to show you how physicists measure the wave-lengths of those ethereal vibrations which possess the simple qualities which we have attributed to the ripples. In the case of the ripples them- selves the measurement of the wave-length would appear to be a 52 | Mr. James Rice on simple matter of a ruler. It is nothing so easy. I should not envy the man who essayed to measure the wave-length of a train of moving ripples to an accuracy of, say, one per cent., with nothing but a foot-rule for apparatus. And yet the measurement has in it simplifying elements absent from the corresponding pro- blem for light waves. The medium, water, appeals directly to our senses; its oscillations, which are of course not merely surface phenomena, are all the more easily observed by the fact that there is a surface whose changes of form disclose to us the underlying movements. Further, even in the case of the tiniest ripples, the wave-lengths are enormous compared with those of light. However, if you look at this slide*, it may help you to obtain a sufficient idea of the means adopted by the physicist for attacking this problem. This picture is an instantaneous photo- graph of the surface of a shallow dish of water which is being disturbed by the oscillations of two needles, both vibrating with equal periods, and each one exciting a ring-shaped train of ripples whose wave lengths are equal. The apparatus employed in the production of this picture is called a ripple-tank, and requires the nicest adjustment between the mechanism actuating the needles, which is an electrically driven tuning fork, and the photographic apparatus, which is in reality a scientific adaptation of the cine- matograph camera. ‘The picture shows you an instantaneous view of the surface of the water. What you observe is that along a series of radial lines or channels, diverging from a spot between the needles, the water is absolutely undisturbed, while along the intervening radial channels you have the water surface corrugated in crests and troughs, The photograph shows you that as a matter of fact along certain paths there is no energy of vibration transmitted at all; the two wave-trains are said to interfere along such lines. Along the intervening paths the wave-trains reinforce one another, and all the energy emitted by the vibrating mechanism is directed along these channels. The reason for this Pg. -o co. “peesgeresp nse: Be Soe Sue Rome Gia Sd Discontinuity in the Phenomena of Radiation 53 state of affairs may be gathered from the next slide”, which presents to you a diagram illustrating by thick and dotted lines the crests and troughs of each wave-train as they would be situated at a definite moment, were the other train absent. Where crest cuts crest, or trough cuts trough you would expect reinforced oscillation, and you will notice that such intersections do actually lie on radial lines ; while where crest cuts trough you would expect interference and absence of energy flow, and such intersections, once more, lie on radial lines, which separate the previous set of lines. Furthermore, you will experience no difficulty, I presume, in appreciating the fact that if the frequency of the oscillation of the needles were increased the channels of energy flow would be more numerous and more closely packed ; their angular separation would be less, for with increased fre- quency the common wave length of each train would be decreased, the thick and dotted circles of the second slide would be more numerous, and the lines of intersections, therefore, more numerous as well. Indeed, there is a very simple relation which connects the wave-length of each ripple-train with the separation of the lines of energy flow when the distance separating the needles is known, and by its aid wave-length could be calculated if other and more direct methods were not available. One limiting condition must be observed before we leave this illustration ; the frequency of the oscillation must neither be so great nor so small as to make the wave-length too small a fraction or too great a multiple of the distance apart of the needles. In the first case the channels of flow would be so numerous and closely packed as practically to obliterate the intervening quiescent avenues, while in the second they might not exist at all. In applying this method to the problem of light radiation, we naturally ask are there sources of light which send out ethereal vibrations of such a simple character as that possessed by our ripples, having the necessary uniformity of wave-length baie Us (cay 54 -Mr. James Rice on along the whole train; and also can we obtain two or more sources of such light as nicely adjusted in phase to one another as the needles of a ripple-tank. The answer is in the affirmative. The light emitted from incandescent sodium, lithium, strontium, to choose a few familiar substances, the light emitted from tubes containing traces of any gas and electrically excited by a coil possesses in a high degree those elements of simplicity required. From such sources we can obtain beams of almost homogeneous or “ monochromatic ” light, i.e., light of definite wave length or frequency. Square across the path of such a beam we can put what is called a grating, consisting of a series of fine, equally spaced, parallel lines ruled by a diamond point on a piece of glass. Such lines serve to scatter and absorb some of the luminous energy of the advancing beam; the remainder of the energy will emerge through the clear pieces of glass between the lines—the spaces as they are called. These spaces, as a matter of fact, serve as sources of light possessing that nice adjustment of phase which was postulated above as an experimental necessity. Instead of two such sources only, we generally have several thousands. The essentials of the occurrence are, however, still preserved ; it is found that the light energy is directed not merely along its original direction, but also along several other well defined directions. The slide shows you a crude picture of some of the energy being directed along one direction ; it is collected by the lens and focussed to a fine line. The slide shows you only one of these lines corresponding to one direction of energy flow. There are in general several such line images, and their distance apart serves to determine the angular separation of the various paths of the energy, and this, as you will remember, determines the wave length. once we know the distance apart of the successive spaces of the grating. In actual practice the line image is projected on the vertical cross wire in a telescope eye-piece, which permits of a very fine adjustment of the telescope and a very precise determination of the divergence of each energy stream from the original direction of the light. As Discontinuity in the Phenomena of Radiation 5D already indicated in the ripple-tank photograph the wave length of the light must be comparable with the distance separating the successive spaces of the grating for the experiment to succeed. Fourtnately the skill of such physicists as the late Professor Rowland, of Baltimore, has placed at our disposal gratings with as many as 14,000 lines to the inch, and also photographic copies of these. Such fineness of ruling is absolutely necessary for accurate work on light. The wave length of any homogeneous light is so small compared with our usual standards of measure- ment that we find it convenient to introduce two new units of length into use, viz., the millionth part of a metre, i.e., the thousandth of a millimetre, which is called a micron, and the thousandth part of this length called a millimicron. Rowland’s gratings have their spaces separated by distances of the order 2 to 3 microns, the separation being known from the mechanical means by which the ruling was carried out. The results of measurements with such gratings and other apparatus designed for similar purposes is to prove that when we analyse the white light of the sun or electric arc into a spectrum band on a screen by prism or grating the light which illuminates the extreme red end of the band has a wave-length of -8 micron approximately, while the light illuminating the other, the violet, end is about -4 micron in wave length. To indicate the precision of measurement possible in spectrometric work, it is known that the yellow light emitted from incandescent sodium vapour is composed of two homogeneous qualities, one having a wave length -5890 micron and the other -5896 micron, a difference in wave length of but -6 millimicron. This excessive shortness of wave length carries with it as its natural counterpart an extreme rapidity of vibration on the part of the mechanism inside the atoms of the radiating, luminous material, and also on the part of the ethereal medium through which the light is transmitted. These frequencies can be calculated very easily from the known speed of light through the ether, which is 300 millions of metres per second. For extreme violet light it turns out to be about 56 ‘Mr. James Rice on 750 billions of vibrations per second, and for extreme red light about half of this number. (Billion is taken to mean 10” or one million millions). We are able to do more than measure the wave-length of a stream of radiation ; we can also measure the amount of energy which is carried per second across any section of its path. To do this the cross-wire of the telescope in the spectrometer is re- placed by an extremely thin strip of some metal coated with a highly absorbent material such as lamp black. The energy of the concentrated stream from the grating is converted into the universal currency for measuring energy, viz., heat, in the strip. The strip itself forms part of an extremely sensitive mechanism in which an electric current is generated by the heat thus developed, this current being measurable by a delicate mirror galvanometer. The sensitiveness of such “radiomicrometers” is such that a rise of one millionth of a degree in the temperature _of the strip is observable with accuracy. The possibility of using such radiomicrometers 1s of extreme importance ; for, as is well known, there exist radiations which do not affect the retina. Our only direct experience of them is the sensation of glow when we stand before a fire or hold our hand near a hot kettle, ete. Such radiations are poured forth in profusion from all bodies, hot or cold; only at the extreme zero of temperature, the so-called absolute zero, would any body cease to radiate. This fact generally eludes us because of our lack of direct sensation in many cases, although we occasionally experi- ence one result of it, viz., the chilly sensation near a very cold body, arising from the condition that we are radiating more to that body than it is radiating in return to us, involving a net loss of energy on our part. At all events their existence is undoubted. They can be directed from bodies, luminous or not, to a grating ; the diffracted streams from the grating can be detected by means of a radiomicrometer, and measured both as regards wave-length and intensity. The photographic plate is also an extremely use- ful appliance in radiometric work ; the camera can replace the Discontinuity in the Phenomena of Radiation 57 telescope of the ordinary spectrometer, and the position of the dark lines and bands on the developed plate give the necessary data for measuring the direction of the diffracted streams of radiation which produced this effect on the negative. The amount of chemical action at each line on the negative, estimated by the depth of tone, indicates the intensity of the stream of radiation. With the specially sensitized plates available to-day, the range of radiation over which the photographic plate can be used is very wide, but it is for those qualities of radiation which are shorter in wave-length than the extreme violet of the visible spectrum, the so-called actinic, photographic or ultra-violet rays, that it has been mainly employed. My remarks so far have been based more or less on the assumption that ideal radiations of precise and definite wave- length exist and are detactable. I must qualify that stalement somewhat. As already stated, there are certain luminous bodies, such as the incandescent alkali earths, or electrically excited gases, which emit radiations approximating to the ideal torm ; but even in such cases, what we actually detect is a stream of radiation with wave-length between certain limits, restricted, no doubt, but still not absolutely identical. The reason for this is not merely the finite dimensions of our receiving and detecting apparatus ; it lies in the very nature of matter itself. But apart from such radiations as are approximately monochromatic or homogeneous, we have in the sun, the flame of a candle, the incandescent metal filament or mantle, the electric arc, and so on a whole series of bodies which are pouring forth radiations which are the very opposite of homogeneous. Even the tumbled surface of a choppy sea can only give an imperfect analogy to the com- plexity of ethereal vibration which must be set up by the presence of an ordinary incandescent solid. Yet the grating and radio- meter can evolve order out of that seeming chaos and discover uniformity of behaviour. The grating will analyse a stream of such heterogeneous radiation into component streams, each stream having its own narrow limits of wave-length or frequency, and 58 Mr. James Rice on each producing on the radiometer (if set in the correct position to receive it) an effect denoting the intensity in which it existed in the original heterogeneous stream. We can say that these quasi- heterogeneous streams existed in the original one, just in the same sense that we say that the violet, blue, green, yellow and red of the spectrum existed in the original beam of sunlight before it was analysed by prism or grating. By these means physicists have actually been able to isolate from radiant energy emitted by various light sources, radiations extending as far into the ultra- violet as -06 micron, and as far into the infra-red as 300 microns, or -3 millimetre, which correspond to limits of frequency of about 5,000 billions per sec. and 1 billion per sec respectively. It will be, of course, readily grasped that the dimensions of the gratings used for such extremes must be varied with the qualities measured ; for the spacing of the grating must always bear a close relation to the wave-length measured. This range of wave-length by no means completes the picture—far from it. The absorbing powers which the materials of our apparatus possess for all qualities of radiation, and for some qualities in a very high degree, prevent us at present extending research in the immediate neighbourhood of the limits mentioned. But that radiations of longer and shorter wave length exist there is absolutely no doubt. The ethereal waves of wireless telegraphy are extreme examples of long wave-length. The huge antennae employed to-day emit radiations whose wave- lengths attain in some cases to 3 kilometres, corresponding to a frequency as low as 100,000 per see. When Hertz first isolated electrical waves in 1887 and verified Maxwell's prediction, he worked with waves about 60 cms. long, small enough compared with those that flash our messages across the oceans, but enormously long compared even with the longest of the so-called infra-red waves detected from ordinary sources of light. But just as some workers, by increasing the size of the emitting apparatus, have produced electrical waves of great wave-length for purposes of communication, others by diminishing the size have sought to Discontinuity in the Phenomena of Radiation 59 bridge the gap that separates the early Hertzian waves from the long infra-red waves and have so far succeeded as to reach a wave-length of 6 mms. The accompanying slide* will give you some idea of radiations which have actually been detected and measured by the variety of means at our disposal, except that the dark portion indicating the gap between infra-red and electrical should be actually smaller owing to work carried out since this diagram was constructed. Further, a remarkable series of researches carried out since 1912 have suddenly opened up a new field of knowledge at the other extreme of the complete radiation range. This refers to the nature of the X-rays. It had long been suspected that they were ethereal vibrations with the same elements of undulatory motion in them as in ordinary light waves; it was also known that if this view as to their nature were correct, their wave-lengths must be very short compared even with the 60 millimicrons or -06 micron of the extreme ultra-violet so far attained. This inference has been fully justified. Taking up an observation, first announced by Professor Laue of Zurich, Professor Bragg of London and his son, together with the late Henry Moseley of Manchester University, published a series of researches opening up a new avenue of knowledge whose possibilities we are just beginning to realize. Sufficient to say, that they have demonstrated beyond doubt the ethereal nature of the X-rays. From the heterogeneous stream of X-ray radiation emitted by any bulb, it is possible to isolate and measure the wave-lengths of individual, almost homegeneous, streams. It is possible also, by varying the metal of the anticathode and by using a high enough voltage, to make a bulb emit practically nothing but an extremely homogeneous radiation, characteristic of the particular metal used and closely analogous to the kind of radiation emitted, say, by incandescent sodium except for the much shorter wave-length. The natural unit of length for these waves turns out to be the millimicron, or even ‘1 of it, the so-called Angstrom unit. Thus, for instance, * Hig. 3. 60 My. James Rice on anticathodes of the heavy metals, such as platinum, palladium, rhodium, tungsten can be made to emit radiations with wave- lengths equal to about half of an Angstrom unit, or -05 millimicron. Lighter metals radiate with wave-lengths somewhat longer, for example about -15 millimicron for copper. Before leaving this explanatory portion of my lecture, I ought to mention that we cannot escape the conclusion that those oscil- lations which we can excite in material bodies by hammering, bending, etc., and which give rise to aerial vibrations producing the sensation of sound, also give rise to ethereal vibrations, which, however, would be in the main of excessive wave-length and of the feeblest intensity. Also all that oscillatory motion in the molecules which we call the heat-motion must give rise to ethereal vibrations, even when the body is not luminous ; in fact such vibrations do constitute some part of the infra-red vibrations, The shortest qualities of the infra-red, however, together with the luminous ultra-violet waves originate from mechanisms within the - atom, no doubt the rings of electrons, constituting the “ planets ” of the “solar system ” to which now-a-days we liken the structure of the atom. In X-rays we are doubtless receiving intimations of violent changes going on in the very interior of the atom itself, its ianermost rings of electrons, perhaps even in its very nucleus, that positively electrified core which seems to hold the negative electrons in their orbits against centrifugal action and mutual repulsion. What picture does all this give us of the condition of the ether with which we have had perforce to fill our universe. One whose very complexity it seems hopeless to analyse, compared to which the most violently agitated water surface seems simplicity itself. Yet that hopelessness is not justified: In the grating and radiometer we have means of analysis which have brought us considerable knowledge, and the past history of science fully supports the view that out of all the seeming disorder the mind of man will evolve order. Indeed he has already made a good start, but one serious difficulty confronts him. Discontinuity in the Phenomena of Radiation 61 Let us return to the analogy of the water surface. Suppose our pool or tank of water has not merely one or two needles touching it, but millions. Conceive each one to be oscillating up and down as before, with all varieties of frequency and form of vibration, The surface of the water will present at any instant a form which must be the synthesis of all the individual move- ments which would exist alone were all needles but one at rest. In the same sense as we say that there are red, green and blue in the white sunlight, so we can say that there are in the complex motion of the water surface all the individual wave motions emitted by each needle, and a natural question presents itself—— can we from the actual wave surface determine the wave length and intensity of each individual train? Well that problem certainly meets too many mathematical obstacles to be soluble in any but a few limited cases. But another consideration equally interesting crops up. Supposing we have some knowledge of the movement of the needles, not necessarily a detailed one, but something about their average behaviour, should we not then be able to infer something about the resultant movement of the water surface, again not detailed knowledge necessarily, but behaviour on the average? Now turn from this two-dimensional picture : think of the three-dimensional ether aud the analogues of our needle-points, viz., the molecules, atoms and electrons of matter, all in excessively rapid movement in it and all exciting ethereal radiations whose frequencies and intensities are depend- ent on these movements. To narrow down our problem to quite manageable dimensions, let us abstract ourselves from open space where we meet with bodies with all varieties of temperature. This is a perfectly legitimate procedure in investigating the elements of a problem. Let us think of this room—with our- selves removed from it, as causing too much disturbance—having walls, ceiling, floor, etc., all at one temperature, and quite imper- vious to all radiation from external sources ; whether we leave the air in it or not does not matter. The enclosed ether is excited by radiations proceeding in all directions, emitted by the 62 Myr. James Rice on walls, each train, as it reaches the wall again, being in part reflected and in part absorbed only to be emitted once more. No we do know something about the molecular movements in a piece of matter at a given temperature, not detailed knowledge concerning any individual molecule to be sure, but knowledge concerning average behaviour. From that knowledge we can infer certain results concerning the movement of the ether in our “constant temperature enclosure.” Furthermore, it is possible to test these inferences, and unfortunately while some of them are verified, one very important one is absolutely at variance with the facts. To show you where the contradiction arises, I must necessarily try to explain to you what is the kind of knowledge we have about molecular and atomic motion. To do so, I take the simplest instance possible, molecular motion in a body of gas, where the molecules spend the greater part of time practically free from each other’s influence or that of the molecules in the sides of the enclosing vessel. The whole theory of such molecular motion has been very thoroughly worked out and can be found in books on the Dynamical Theory of Gases; the results obtained are numerous and in many cases capable of verification ; in fact few single bodies of scientific knowledge can show such a strong chain of influence and verification. One of these results refers to the average energy possessed by any individual molecule of the gas when its temperature is definite. At any instant among the enormous numbers of molecules present—and you must remember we are dealing with numbers of the order 30 trillions per cubic centimetre for a gas at atmospheric pressure— as many are travelling within any well-defined limits of direction as within any other similarly defined limits. Otherwise we would be having the gas pressing in one direction more than another. ‘That is, there are no privileged directions of motion. At a given temperature there is one privileged speed ; i.e., there are more molecules with speeds varying by not more than say 1 metre per second from this speed than there are molecules Discontinwty in the Phenomena of Radiation 63 varying by the same amount from any other speed. In fact more than 60 per cent. of the molecules have at a given instant speeds between one-half and twice this speed, and less than 1 per cent have velocities more than two anda half times it. For air in normal conditions it is about 460 metres per sec. Of course any one definite molecule will probably assume in its career the most various speeds, but the actual number within defined limits of velocity remains practically unchanged. Further the average kinetic energy of a molecule, that is the total kinetic energy divided by the number of molecules is a definite quantity, which depends on the temperature in a very simple way ; it is simply proportional to the temperature, provided we measure this not from the arbitrary zeros of the usnal scales but from the absolute zero. Of course this average kinetic energy per molecule is a very small amount of energy indeed, even at very high temperatures, on account of the excessively small mass of the molecule. It can be obtained by multiplying the absolute temperature of the gas by a fractional number which is nearly 200 trillionths (i.e., 2x 10~'°), the units of energy being those suitable to the C.G.S. system, viz., ergs. To avoid repeating this extremely small number too much let us indicate it by a letter, say a, and refer to the average molecular kinetic energy of a gas at temperature T on the absolute scale as a T ergs. The application of the same mathematical methods which have proved so successful in the case of gases, to the case of solid bodies is naturally attended with more difficulty, and the positive results are much fewer. As regards the energy of each molecule, however, a result, which is an extension of that for the gas, can be obtained with a considerable weight of evidence in its favour on the basis of ordinary dynamics. It is known as the Theorem of the Equipartition of Energy. Returning to the case of the gas for a moment, the mathematical analysis only considers the energy possessed by the molecule by reason of its general trans- latory motion, with no reference whatever to any internal energy 64 Mr. James Rice on which the molecule may possess by reason of the relative motion of its parts to each other, i.e., its atoms, or even the electrons within the atoms. Considered in that restricted light the mole- cule has, as we say, three degrees of freedom, i.e., the most general translatory movement can be compounded of three partial movements in three defined directions, say, back to front, side to side, and up and down; this is a natural sort of division in view of the three dimensional nature of our space. We also say that for each degree of freedom the molecule possesses an amount of energy il 3 aT ergs giving the total, a T ergs, as before for the three degrees of freedom. Now, when we go inside the molecule, as it were, we per- ceive the existence of other degrees of freedom. To a huge celestial intelligent being our solar system would be as one body travelling through space with apparently three degrees of freedom. To us, however, it appears as a number of discrete bodies with many degrees of freedom quite independent of its own present motion towards the costellation Hercules. Similarly the com- plexity of the structure of the molecule yields many more degrees of freedom than the three referred to, and the accom panying movements and vibrations must involve the possession of kinetic energy over and above the energy of translation. The theorem of Equipartition states that in so far as such movements can be affected by conditions which alter temperature, the a T ergs of kinetic energy for each such degree of freedom. I have put in a pro- visional clause, you will observe. On the grounds of pure Dynamics it should not be necessary to insert it ; the movements in question should be affected by changes of temperature. But that is the trouble, as we shall see. This enumeration of the average energy of the molecule is not exhaustive ; it refers solely molecule, on the average, should possess Discontinuity in the Phenomena of Radiation 65 to kinetic energy. The very existence of these intermolecular vibrations of necessity postulates the existence of mutually restraining forces on the various parts of the molecule, and such forces involve the possession by the molecule of a certain amount of internal potential energy. Further, if the molecule constitutes part of a solid body there will be restraining forces of cohesion on the molecule as a whole involving possession of still more potential energy. Under certain rather restrictive conditions, but, nevertheless, conditions which are of considerable import- ance in practice, we can say that each molecule, in addition to the total kinetic energy referred to, possesses on the average an amount . a T ergs of potential energy for each degree of freedom of motion which involves vibratory movement. I must ask you to bear in mind the fact that these are statements about average values of energy. They are entirely statistical. The behaviour of any individual molecule is much too complex an affair to follow. In any case it probably passes through the most varied conditions in any finite period of time. Further, this equal partitioning of the energy among the various degrees of freedom is a result depend- ent on the complete truth of the dynamical principles as laid down by Newton and extended by Lagrange and Hamilton. Now let us turn to the behaviour of the ether which is situated within our enclosure where the walls are at a constant temperature. The trains of radiation passing through it involve periodic changes at every point of this ether. The old view, so skilfully developed by Young Fresnel, Green, MacCullagh, Lord Kelvin was that this periodic change is actually a vibratory movement of the ether, which is pictured as a material combining properties of rigidity, incompressibility and fluidity in a fashion hard to reconcile with our preconceived notions based as they are on the actual properties of matter as we directly apprehend it, Maxwell, taking up the ideas of Faraday and putting an 66 Mr. James Rice on elegant mathematical dress upon them, turned away somewhat from such hard and fast physical ideas of radiation. Instead he developed a system of equations based essentially on electro- magnetism, which he claimed had to be satisfied by the particular physical property in the ether whose periodic variation accom- panies the trausmission of energy through space. Despite this fact, his methods are quite consistent with the notion that a finite body of the ether can possess degrees of freedom, and that the average energy of any volume of the ether can be calculated in a manner analogous to the calculations carried out for ordinary matter. Furthermore his equations, whose importance in the Physics of the last fifty years cannot be overestimated, are based on the truth of Newtonian Dynamics, and ultimately involve an equipartitioning of energy among the various degrees of freedom of the ether just as the Lagrange-Hamilton equations involve it for the molecules of matter. The idea of degrees of freedom is difficult enough for the non-mathematician to grasp in the case even of such a tangible thing as solid matter. In the case of the ether it appears very elusive indeed. It will perhaps be best to illustrate by the older view of ethereal movement ; at all events the conclusions are consistent with those developed by means of Maxwell’s equations. Consider a string stretched between two points. Such a string is capable of many ways of simple vibration, several of which I illustrate by these drawings on the board. First, it may vibrate as a whole between the indicated forms; then it may vibrate in two halves with the middle point always at rest. It is known that the frequency of vibration of any point on the string is in the latter case double what it is in the former, i.e., double the fundamental frequency. Then it may vibrate in three different segments, with two “nodes,” and a frequency three times the fundamental; and so on. Theoretically there is no limit to this exact division of the string into so many parts with an accompanying simple type of vibration, if we regard the string as a perfectly continuous piece of matter. If, however, we regard it, as we must do on the Led Discontinuity in the Phenomena of Radiation 67 molecular hypothesis, as a group of discrete particles, there is an upper limit to the number of such types of motion, viz., the number of particles itself. Be that as it may, we have the concept of a string which may vibrate in certain simple fundamental ways with frequencies which progress in the ratio of the whole numbers. Thus if the fundamental vibration has a frequency f times per sec, the others are 2f, 3/, 4f, etc. up to the limit prescribed by the structure of the string. Any vibration of the string, however complex its nature, can be considered as the sum of a number of their simple vibrations, each one with an appropriate amplitude or intensity. Hence these simple types of vibration constitute the “degrees of freedom” of the string, and you will observe that there are exactly n degrees of freedom whose frequencies are not greater than n times that of the fundamental, that is, the number below a certain frequency is proportional to that frequency. Now let us make a further step. Consider a stretched skin in the form of a square, instead of a string ; it has also certain simple types of vibration which may be roughly considered as a blend of those belonging to all the strings which we could cut out of the skin by lines parallel to one pair of sides with those belonging to strings cut out by lines parallel to the other pair. This blending makes the total number of such simple types, i.e., of degrees of freedom, whose frequencies are not greater than a certain frequency to be proportional to the square of that frequency. Finally, if we consider a cubical lump of elastic material, its fundamental mode of vibration and all the simple types constituting its “overtones” are a blend of three sets of linear types, and it appears that the number of all the simple types whose frequencies are not greater than a given frequency is proportional to the cube of that frequency. Now, it . is this lump of elastic material which we are to take as our model of the ether. The finite volume of ether enclosed within the constant temperature walls is at any moment in a definite state of agitation following on the transmission of vibrations through it from the walls of the enclosure. This state of agitation is the 68 Mr. James Rice on sum of an enormous number of simple vibrations, each one of which corresponds to one degree of freedom of this volume of ether. Owing to the uncontrolled motions of the molecules of the walls and their internal parts, the motion of the ether is just as uncontrolled. The actual state of one tiny portion of it at a defined instant is as unpredictable as that of a single molecule, but the energy of the whole should be given by the principle of equipartition, 1.e., for every degree of freedom there should be energy of radiation always present of amount ; 9 —a T ergs » d 1 where T is the temperature of the enclosure, 3 4 T ergs being bie 1 : the average kinetic energy per degree of freedom and 3 T being the average potential energy. Now, as I have stated above, the number of degrees of freedom, or simple types of vibration possible for the ether in the enclosure is first of all proportional to the volume, as one would expect, and then to the cube of the highest frequency possible. The question naturally arises—is there any highest frequency? If the ether is to be regarded as an absolutely continuous medium, there is not; and this leads to the conclusion that the number of degrees of freedom of the ether is genuinely infinite, not merely enormously large like that of the walls of the enclosure ; and this means that in the steady state corresponding to a definite temperature while there would be a finite amount of energy in the walls, there would be an infinite amount in the enclosed ether, a statement which really means that the only possible steady condition would be one in which all the energy would be in the ether and none in the walls, which would therefore be at absolute zero. But let us waive this difficulty ; yet we are not freed from anomalies. Let us put an upper limit to the types of vibration which the ether may have. Experiment has shewn that the ether, even if it has a structure, is nothing like as coarse-grained Discontinuity in the Phenomena of Radiation 69 as ordinary matter. The frequencies corresponding to X-rays are of the order 3 trillions per sec. To avoid much use of algebraic symbols let me make use of graphical methods. The curve which I draw on the board is to be interpreted thus. Lengths along the horizontal axis are to be considered as proportional to frequencies, so that a point on this axis indicates a definite frequency. ‘The lines drawn up from two such points enclose with the axis and the curve a quasi-rectangu- lar area. Now the curve is so drawn that this area is propor- tional to the number of degrees of freedom in, say, 1 ¢.c. of the ether whose frequencies lie between the limits indicated by the two points. The area bounded by the curve and the axis up to a particular vertical line is proportional to the cube of the length along the axis up to this line, which agrees with the rule concerning the number of degrees of freedom of the ether mentioned above. The curve as a matter of fact is a very well-known one, being a parabola. If we are then to partition the energy of the ether in a constant temperature — enclosure equally between all the degrees of freedom, it follows that the quasi-rectangular strips may be taken to be also propor- tional to the amount of energy in the ether corresponding to vibrations with frequencies between the limits indicated by the two points ; and the whole energy in the ether is to be propor- tional to the whole area under the curve up to the point corresponding to the maximum frequency possible if we choose to impose such a limit which, as I have stated, must be in the trillions at least. Well, this conclusion is absolutely contradicted by facts. It is possible to determine what is the partitioning of the energy among the frequencies. A hollow vessel is maintained at a steady temperature (by electric heating if the temperature is very high). A small hole is opened in its wall, which permits some of the radiation to emerge. This radiation is a fair sample of that existing inside the vessel and can be analysed in the usual way. It is known that this radiatiou, “full radiation” as it is called, is independent of the material of the walls so long as these e 70 _ Mr. James Rice on are not perfectly reflecting for any qualities of radiation, a con- clusion which can be arrived at theoretically, and is substantiated by experiment. The results of the analysis of such full radiation and the amount of energy within defined limits of frequency or wave-length are indicated in the slide* which give curves for a SPECTRAL ENERGY Curves oF FuLL RADIATION. (Lummer and Pringsheim). Fig. 4. variety of temperatures, the horizontal lengths being taken as proportional to wave-length, instead of frequency. When drawn so as to make the horizontal lengths proportional to frequency, * Fig, 4, Discontinuity in the Phenomena of Radiation 71 any one of these curves takes the form which I put on the board* AIN3NDIB4 JO JONVH LINN Y3d ADHINT 4 FREQUENCY PQ beside the original parabola. The discrepancy between theory and experiment could not be more forcibly illustrated. Instead of the greater part of the energy residing in vibrations of very high frequency, it is largely concentrated in vibrations around a certain mean frequency, this mean frequency changing to a higher value, with, of course, a shorter wave-length, as the temperature of the enclosure rises. To emphasise the point still further, let me show you the energy curves of the radiation from the sun (freed from the absorption of the solar and terrestrial atmos- pheres), the electric arc, and a gas flame, all sources which approximate closely to the condition of “full radiators.” The same type of curve with its maximum peak appears just as in the previous slide. Let me also give one numerical illustration which can be deduced from such curves. A mass of iron at the freezing point of water is situated inside an enclosure whose walls are = hign Oy -~I bo ' Mr. James Rice on perfectly impervious to radiation. According to the theoretical results the iron ought to lose energy continually until its tem- perature became practically absolute zero, and the whole energy of the system had passed into the surrounding ether, and was contained almost entirely in those vibrations of the ether which were of the very highest frequency. So far from this actually happening, the experimental evidences indicates with some certainty that a steady state is rapidly reached in which the density of the energy in the ether is about 40 millionths of an erg per c.c., while that in the iron is about 8,000 million ergs per c.c. Actually all the energy, with an infinitesimal exception, resides in the comparatively few degrees of freedom of the iron, while the enormously greater nnmber of degrees of freedom of the ether are almost devoid of energy. Nothing further from equipartition between the matter and the ether could hardly be imagined. Here then we are faced with a serious discrepancy. It is not the only one. There is another one concerned with the division of the energy between the degrees of freedom of the matter itself, and there are some concerned with such points as the electrical and thermal conductivities of the metals. Time does not permit me to enter into any account of these, but this much may be said ; if we can find the key to the first riddle it will in all probability give us the answers to the others. It is the master problem, the interaction between ether and matter. To sum up the situation as it presents itself to us, we see that the application of Newtonian Dynamics, as embodied in Maxwell’s equations, to the interaction between matter and the ether (the latter being regarded as a continuous medium, or at least one with an excessively fine structure) leads to a partition of energy between the ether and the matter in a constant temperature enclosure, and also a partition of the energy in the ether itself among its various simple types of vibration, which is wholly at variance with experimental observation. Nothing could be further from equipartition than the state graphically represented on the slides just shown, oo Discontinuity in the Phenomena of Radiation To meet this difficulty two courses seem immediately possible, one is to abandon the principle of equipartition, but still retain the classical dynamical principles and discover the flaws in the chain of inference which leads from the latter to the former. Such a course is perfectly logical, and finds favour among the older and more conservative of physicists. But on the whole, opinion seems to be turning generally to a more drastic solution, to a denial of the complete validity of Newtonian Dynamics itself. It must be confessed that it is not only on these matters that the foundations of classical dynamics have shown signs of being no longer able to support the superstructure of our knowledge, and of requiring something broader still to rest on. It isnot surprising that in this particular difficulty attempts are being made to arrive at a set of principles of wider application than any contemplated by Newton or his immediate followers. To the treatment of the movements of our solar system and of bodies of ordinary dimensions on the earth’s surface, the Newtonian dynamics has shewn itself admirably adapted, although there are one or two minute discrepancies which have obstinately resisted explanation. When we pass into the region of molecular, atomic and electronic motion and the transference of energy from such exiguous bodies to the ether, we are dealing with orders of mag nitude far removed from those contemplated in gravitational theory. Bodies of excessively minute dimensions but possessed of enormous speeds are our material. The 30 kilometres per second or so of our earth’s motion round the sun is a very snail’s pace compared to the speed of electronic movement with which we are now-a-days familiar, attaining in some cases almost to the speed of light, 300,000 kilometres per second. ‘There is little to marvel at, if it should turn out that we want new laws to co-ordinate the new knowledge in regions so remote from our customary perceptions, laws to which Newton’s principles consti- tute an excellent approximation under the conditions for which they were designed. 74 Mr. James Rice on Unfortunately, in this direction, little has been attained so far. If we are to rebuild, we are still awaiting our Newton. Into the mass of conflicting material one tentative principle has been thrust. It is little more than a new proposal as to the partitioning of energy, with but a small physical basis for its support. Yet its undoubted success in calculating the partition- ing of energy leads one to believe that it will perhaps one day occupy a position of some importance in the new structure which has to be raised. I will treat it first as a mere principle of partitioning, and then say a few words as to the manner in which its originator, Professor Planck, of Berlin, and his school seek to justify it. Return to the two diagrams. ‘The parabola representing the partitioning of energy on the older assumptions and the peaked curve representing the actual facts. Hach curve is supposed to be drawn for a definite temperature, 7. Professor Planck’s first step was the discovery of the relation between these two curves and of a mathematically elegant expression for it. ‘Take two near points P and Q on the frequency axis ; they represent two definite frequencies separated by a small range of frequency: the amount of energy in unit volume of the ether corresponding to the types of vibration between these two frequencies would be represented by the narrow quasi-rectangle PQBA on the equi- partition basis; it is actually represented by PQDC. Now it appears that the ratio between AP and CP can be expressed by a simple formula depending on the value of the temperature 7, and the value of the frequency represented by the point P ; let us call that vibrations per second, which of course corresponds to a wave-length obtained by dividing the speed of light by n. The expression for the ratio further involves the constant a already used (with a value close to 200 billionths, you will remember), and a new universal constant, “ Planck’s constant,” with a value about 6,500 quintillionths (6-5 x 1077’), The extreme importance of this new constant for purposes of cal- culation is undoubted. There must be some physical basis for it, Discontinuity in the Phenomena of Radiation =I though what it is forms a matter rather of speculation than of sure knowledge at present. But I will come to that in a moment. To proceed. With this set of symbols, two of them absolute universal constants, two of them standing for measures of definite physical properties, let us calculate the number : 8hn/2aT where hf stands for Planck’s constant. Call this calculated number 7. This number 7 has, of course, a definite value for each point P on the frequency axis, so long as we are considering a definite pair of curves corresponding to a definite temperature. Now, Planck has pointed out that the ratio AP to CP is equal to the sum of the series 147/2477/6 +7°/24 + 74/120 + etc. ad infin. That is not the most elegant way of putting this ratio. Those of you who have some knowledge of mathematical functions will recognize this series as (e” —1)/r Where e is Naperian base of logarithms. Of course the ratio varies as we pass along the corve, for r is a different number at different parts of the curve. This is a new principle of partition. It has been discovered that its applicability is not confined to partition of energy in the ether alone. Indeed it is its application to the distribution of heat energy among the types of vibration of solid bodies that has constituted one of its triumphs, and first brought it seriously into consideration. To state it once more—when apportioning vibrational energy among the degrees of freedom of any substance, ethereal or material, at a definite temperature, one first of all estimates the amount to be assigned to each narrow frequency range by the equipartition principle and then divides the result by the expression. . (e” —1)/r where 7 is the frequency temperature number calculated as above. 76 Mi. James Rice on It appears that if m is small enough or T large enough, the value of ris so small that the divisor given above is little different from unity and so for high temperatures or frequencies of vibration not too great the equipartition principle nearly holds ; but at low temperatures or high frequencies it is utterly at variance with the facts. This in itself is but one way of saying that, under certain restricted conditions, Newtonian dynamics is an excellent approximation to truth. It remains for me to give you a brief statement of the manner in which Planck endeavours to justify this partitioning of the energy. He does so by introducing the hypotheses of dis- continuous or spasmodic radiation. Now, this hypothesis can flnd no secure position in the general framework of electro- magnetic theory as built on Maxwell’s Equations. According to modern views as to the structure of the atom, there is no doubt that the electrons of the atom are the sources of all those high frequency radiations for which the principle of equipartition proves such a failure. The result of applying orthodox theory to the actions between electrons and the ether is to demonstrate that ‘electrons cannot radiate energy if they are at rest or in uniform motion. They must be moving with velocities variable either in speed or direction, or both. Now, such variable motion is an obvious feature of rotation in the quasi-planetary orbits around the atomic nucleus ; it is also a feature of electron motion when they are ejected from the atom by the action of ultraviolet light or X-rays. At all events, according to classical theory, electrons whirling in their atomic orbits should be continuously radiating energy. This constitutes something of a difficulty, for such continuous radiation of energy must mean a gradual con- tracting of the orbit and a gradual absorption of all the electrons mto the necleus with a consequent change in the properties of the atom which is certainly not justified by facts. The ordinary phenomena of magnetism, and the action of magnetic fields on sources of monochromatic light give powerful evidence of the permanent and undiminished intensity of such electronic whirls Discontinuity in the Phenomena of Radiation 77 in all atoms, and this permanency is hard to reconcile with the gradual loss of energy by the electron deduced by theory. True the full force of the argument can be somewhat abated by pos- tulating that there are a considerable number of electrons in any one orbit following each other round in a stable ring ; for under such circumstances it appears that the rate of radiation is greatly reduced. Planck’s hypothesis is this. He assumes that there are electrons in the atom—‘ resonators” he calls them—which oscillate without radiating in this continuous way. He also assumes, to take his later views, that these resonators can absorb energy in a continuous manner from the energy of the surround- ing ether by reason of the electrical forces inherent in all radiant energy according to the electro-magnetic theory of light. Such absorption without emission could not go an for ever. Radiation from the resonator must occur some time or other. Planck postulates that this emission instead of being continuous is jerky or spasmodic. He assumes that there are certain critical stages in this loading up of energy when the resonator may suddenly put out its whole content of energy in one rapid rush as it were. These critical stages occur when the resonator possesses exactly a definite multiple of a definite “quantum” of energy. It is in the amount of this quantum that Planck’s h constant makes its appearance. The resonator will, of course, have a definite frequency—n per second, let us say; the quantum of energy for this resonator is hn erg. Suppose we conceive the resonator devoid of energy, it begins absorbing from the surrounding ethereal energy; presently it is loaded up with a value hn, it may radiate then; it cannot do so before that moment (according to Planck) ; it may fail to radiate at this moment; it then keeps on absorbing until it attains an energy 2 hn; it cannot emit in the interval, but it may radiate at this moment; again if it fails to do so it keeps on absorbing and cannot radiate until its energy reaches 3 hn, and so on. Radiation can only occur at certain well-defined and discrete 78 Myr. James Rice on states ; the chance of the resonator emitting at the energy hn is greater than its chance of passing this critical state and radiating at the energy 2 hn, and so on. Planck assumes a certain law of chance for the attainment of these successive stages which is plausible enough ; but one point must be most strongly emphasized ; for it is vital in his reasoning. At whatever multiple of the quantum radiation occurs, the whole amount pours out suddenly ; nothing can check or prevent this total radiation. Here is the very essence of the discontinuity. The particular form of the hypothesis which I have outlined above is not the only one possible, in fact it is not quite the form first propounded by Planck himself. Also other workers have abandoned the particular radiating mechanism postulated by Planck, viz., the resonator, and employed the ordinary orbital whirls of electrons. But all have to assume somewhere or other this feature of discontinuous emission of energy from whatever radiating mechanism they employ. It is possible to do without discontinuous absorption, but discontinuous emission there must be and in amounts which must be multiples of the quantum of energy corresponding to the frequency of the mechanism. Perhaps you may think that because of the extreme smallness (compared to our customary standards) of a quantum of energy even for very high frequencies (an amount equal to about six billionths of an erg [6 x 107] for a frequency of 1,000 billions [10°], that discontinuous outputs in such exiguous quantities would practically amount to continuity. Such a view cannot be maintained. It must be remembered that the scale of dimensions we are dealing with here is quite distinct from that of daily phenomena which appeal directly to our senses. It is all a matter of comparison, and the quantum which I have just mentioned is certainly 100 times as great as the average heat energy of a molecule at normal temperatures, and it is this latter amount which is the natural quantity of energy for us to consider when we are concerned with the comparative largeness or small- ness of the amount of energy which is converted from one form Discontinuity in the Phenomena of Radiatiou 79 to another in these small scale phenomena. Besides, as I indi- eated at the beginning of this paper, it is not in the magnitude of the phenomena nor in its extreme brevity that the discontinuity arises. In order to obtain by logical reasoning Planck’s partition of the energy, which is undoubtedly extremely near to the truth, and avoid equipartition, which is certainly far from it, we are bound to assume some hypothesis concerning the radiation of energy for which we have no basis in our fundamental principles. It seems necessary to postulate a picture of the atom structure such as the following. Around the positively charged nucleus of the atom we have negative electrons rotating in orbits. On the older views the positions of these orbits could change con- tinuously as the electrons gained or lost energy in a continuous manner. On the new idea, we must consider the possible orbits as discrete and well separated from one another. While an electron moves in one of these stable paths, its motion can be calculated by the orthodox dynamical rules; thus for a single electron whirling round a single nucleus (the usual view of the hydrogen atom), any of these paths would be the usual planetary ellipse. While in this path the energy of the electron remains constant ; there is no radiation of energy and no absorption. Some critical condition arises due to external influences and the electron leaps suddenly from one orbit to another. As the energies of the electron in two orbits are different, the electron must part with or absorb some energy in the transit, the amount being quite definite and determined by the particular two stable orbits considered. This amount is emitted or absorbed as vibrational energy of a definite frequency, and here the significance of Planck’s constant comes in, for the frequency of the radiation emitted or absorbed must be such that when multiplied by this constant the result is the amount of energy in question. This is a view of atom-structure which is receiving considerablé attention of late. You will see that it postulates both discontinuous absorption and emission. Planck, himself, being reluctant to abandon any more than was necessary of the older theory contented himself with developing a theory of “resonators ” 80 Discontinuity in the Phenomena of Radiation which could absorb continuously and radiate discontinuously. The truth is that there is at present little to choose between the two views. It should be remarked that the former view could be pushed still further and interpreted as the result of the fact that there was an atomicity in energy itself, a speculation that has been more or less implicit in the recent work of some of the English school of Physicists, notably Sir J. J. Thomson. How- ever, there does not appear to be any phenomena yet which actually compel us to adopt such a revolutionary view ; but it is doubtful if we will be able to escape from some form or other of Planck’s hypothesis. In itself it may turn out to be only one result of a new scheme of dynamics, of which we are now getting the first inklings in the case of these small scale vibratory occurrences. The key-note of the new mechanics is discontinuity. ee 2 a | | JOSH AURROREEP ah etas - Jldd | [dad d oof J CURGEREARER BERS : Hoig fo Bota COS Ae - ay ] : 28 cat —_set WS: a BR opos # Serene eR nes ssssssssssss?/ssssrSss0"5055—r at ie ; & SOlnL& Ey cone oni | eee pens ie x EN 4o44 So =) O p| Playocr |p eile: : Blige | Has o ca | || Sosroon4 i, | ang LS TE eae PLL on “SaueV OF “TL ANGHIS “Sauov ot -] AAAHIS! [ See p 19. A War Memorial for Belfast. 15 housing, good, bad and indifferent, could easily have beenzadded to: but the principle involved is the vital point, and this principle can hardly be better stated than in Mr. Raymond Unwin’s diagram, Fic. 18, in which we can read very plainly the reason why the official improvements made just before the war are so very little in advance of the slums which they replaced. Cost. At this stage, it may well be asked, how is all this going to be paid for? Obviously, it would be a very costly business. I take it that the expense would be borne partly by the State, partly by the Municipality, partly by private enter- prise. As regards the State, already a huge scheme of national Housing is afoot in Parliament, involving the erection of anything up to a_million new houses. Belfast will, of course, have its share of these. As regards private enterprise, the evils we hope to cure have been so largely the result of uncontrolled private enterprise that our aim will probably be to supervise its activities and check its natural lust after cheap buildings and high rents, rather than to hand over another generation of our people. to a fresh group of jerry-builders. But as regards the Municipality, there is one surprising and hopeful possibility. City develop- ment, on the lines here indicated, could, to a very large extent, be made to pay for itself, asswmning that the City will adopt a very broad and far-seeing policy. The essential point of this policy is that the City should own, or control the ownership of, all the unoccupied building land which could possibly be utilised for thirty or forty years ahead. The manner of obtaining such ownership or control would be to buy—or take options to buy—at the official figures which are now recorded in connection with the Land Values Taxation clauses of the 1909 Budget. If necessary, compulsory powers, to acquire land and options at these prices, would not be hard to obtain from Parlia- ment. Let the City begin to buy up its own edges and outskirts, at least 1,000 acres to start with, and let it obtain options over other portions, so large that come what may, it will never be possible for private speculators to stop or check the development 16 A War Memorial for Belfast. of the city by withholding land from the market for the higher values which they might obtain after a few years. Having bought a suitable strip, let the City lease it for building, under careful supervision, in accordance with the City Plan. Intelligent planning, on modern lines, will prevent waste of capital expenditure in a multitude of ways; and the public ownership of the ground will enable rents to be fixed at a figure which will not be inflated by private profiteering. Within these limitations, it seems to me that private enterprise would still have enormous scope for all the energy it is capable of exerting. In private enterprise, I include Co-Partnership groups, and Building Societies, as well as private firms and individuals. As regards possible alternatives, direct State building and ownership appear to me to be out of the question: it is physically impossible for the Board of Works to do it, and I have not the least expectation that Parliament intends to do anything of the sort. Municipal building and ownership of the actual houses themselves might appear more likely, but here again, I do not believe that our Corporation is likely at present to take over the building trade of the city as a going concern and run it from Done- gall Square,—as well as a big rent-agency department. The plan which has been officially adumbrated seems to be for the State to lend very large sums of money to local authorities at a low rate of interest ; and that, in turn, local authorities should lend the same money to large numbers of property owners. I have only this comment: unless the State insists upon a proper city plan, properly supervised, upon the general lines indicated in this essay, we are likely to find that, after the lapse of a few years, (1) the property-owners have got most of the cash, (2) the city owns neither the land nor the houses, and (3) the tenants are paying high rents for houses little if anything better than they are occupying to-day. My claim has been that, to a very large extent, we could make city development pay for itself. But it is only fair to my own suggestions to observe that there must necessarily be some A War Memorial for Belfast. 17 portions of a broad scheme that, taken separately, could not be, directly, a paying proposition in the strictly financial sense. No amount of financial genius will extract a profit-rent out of a child’s allotment garden! But surely, this War has taught us that “money” and “wealth” are not identical terms? Shall citizens of Belfast not learn to take more of their municipal dividend in terms of health and happiness for our youngsters, in opportunities for activity in mind and body for people who have nothing to-day outside the narrow grind of their working lives ? God knows, the world has paid enough since August, 1914, for pure destruction, in order that life and freedom may be preserved : may we not, as part of our War Memorial, spend a small fraction more upon construction, so that, in our own times, we may see the growth and liberty again at work ? CONCLUSION. Our War Memorial shall thus be no mere carven stone upon a pedestal : it shall be at once a tribute and an inspiration: a tribute to those who have fought for our freedom, and an inspiration to us to use our freedom to nobler ends. It may be that, in days far ahead, men shall learn here of the Great War, not as we have learned of past wars in our school-books, but by themselves living in the realization of our War Memorial ideas. Is this too much to hope for? Rather may we not say that we shall not have justified all the heroism of our men these four years past, if we do not see to it that these dreams shall begin to come true, in our own day, and by our own effort? The gallantry of Thiepval has already given to July Ist a new significance, a new historic orientation. Shall we not also give a new meaning to our old city motto—Pro Tanto Quid Retribuamus ? “For so much, what shall we give in return?” What shall we give? I say we shall give to them and to their children a new city, a new hope for the days to come. “ats AND. PHILOSOPHICAL SOCIETY. ’. _ PROCEEDINGS, = SS SESSION 1918-1919. % re SS No. 2. as = : : = f = =e F % ee an oe z = LYMARTIN CHURCH RUINS | THER RATH OF DREEN, = > ; te im he ~~ — p r. = a ~ . BELFAST: — ee ee aon ‘BOYD & SON, ETD); AE ee orurate STREET {eo ‘ Ber ee J 1919. : - ¥ é r < i us a ; “CHURCHYA -AND oTim FY TO e e oes: SCALE TIN BALLY MAR RATH AT DREEN NEAR CULLYBACKEY. (SCs Se ee > anivck eee ae = PLAN . i yi 1 SECTICN OF SOUTERRAN CD ee as : SBAVEYED BY WC LAWLOR corsa = BALLYMARTIN CHURCH RUINS, AND THE RATH OF DREEN. Papers read on the 10th December, 1918, at the Annual Meeting of the Archcological Section, By Mr. H. C. Lawtor, M.R&.I1.A. BALLYMARTIN CHURCH RUINS. The ancient Church and Churchyard of Ballymartin he in a picturesque little glen on the north side of the Ballymartin river exactly a mile and a quarter east of Templepatrick (see O.S. Map, sheet 51). The Church, the orientation of which is nearly due east and west, is about 30 yards from the stream, on a slightly raised knoll, while on the east, north and west can be traced a now grass grown, but marshy channel, which shows that it was once an island church. It is rectangular, measuring internally 51 by 17 feet. In the immediate neighbourhood are several objects of archaeological interest. Leading due north from what was once the little lakelet in which the island stood, is an ancient paved road traceable for.several hundred yards until it is lost in a plantation. Just above where the stream once widened out into the lakelet is an old ford or row of stepping stones, at a short distance from which on the south side of the river is an ancient well, at one time a Holy Well.* Opposite the Church on the other side of the river is the entrance to the Souterrain, the investigation of which is described in the Report of this Society for 1917. 170 yards east of the cave, surmounting a steep cliff overhanging the river, is a small rath much obliterated by tillage. The churchyard lies south and east of the church, * For traditions respecting this well, see Ordnance Survey memoirs quoted in O’Laverty’s Down and Connor, Vol. I1I., pp. 17-18, 2 Ballymartin Church Ruins and contains many rugged graves, some of which are marked by rough uninscribed stones. The site of the church and church- yard has never been tilled, but the remains of the walls were barely distinguishable, being overgrown with grass and brambles. The investigation of this ruin was carried out at various dates during the summer of 1917, as opportunity and weather permitted, and in all some 10 days were spent on the work. I had the assistance of two steady labouring men, and during the progress of the investigation it was visited by Professor Macalister, Mr. Andrew Robinson, of the Board of Works, Canon Carmody and Mr. R. M. Young, whose valuable advice and information I wish to acknowledge. Our first undertaking was to clear out the whole interior of the church, which was filled to a depth of from two to five feet with the fallen debris of the walls. The removal of this brought us down to the original floor level, which was covered with the remains of burned matter, and at the same time exposed the types of the masonry of what still remains of the walls. The original stone work apparently had not been built in sunk trenches, as the foundations were on the level of the charred surface of the earth floor. The masonry itself was of two distinct types, dry or clay built and mortar built. In removing the debris, all stones showing cutting were carefully laid to one side and will be described separately. We worked down from the eastern gable, lifting the stones and debris to the outside. About nine feet from the gable was a large recumbent pillar stone about 4 feet long, lying east and west and equidistant from the side walls. It was impossible to tell whether this stone was originally partly sunk in the floor or lying on the surface or erect. Beneath it we found in the soil two skeletons buried in a sitting position facing east. As we proceeded westward we found human bones at various depths in the debris, showing that interments had taken place long after the church had become a ruin. At the extreme west end under the last of the debris we Ballymartin Church Ruins 2 found a deep deposit of what is usually described as of the kitchen midden type. It consisted of wood fire remains contain ing numerous bones of animals and broken pottery. There were also hnman bones in places, evidently the remains of one or more bodies that had been interred at a period much later than the date of the kitchen midden. We also found one stone of a large quern here. The midden remains were from 6 to 18 inches deep, and extended considerably below the level of the bottom of the foundations of the wall and the floor level of the Church, but not under the wall; they were piled against the inside of the wall, thus proving that they were deposited subsequent to the building. The masonry of the walls is to a considerable extent dry built, with earth between the stones, indicating a very early date. It is very dangerous to come to dogmatic conclusions as to the age of early stone built churches. Petrie discusses the subject very fully in his “ Ecclesiastical Architecture of Ireland Anterior to the Anglo Norman Invasion,” and O’Hanlon, in his “ Life of St. Malachy,” refers to the matter in some detail without arriving at any definite conclusion. Generally speaking, I think it may be assumed that, except in the larger and more important ecclesiastical centres, the great majority of churches in Ireland prior to the teuth or eleventh century were wooden structures. If we assign the original date of Ballymartin stone ,church approximately to the tenth century, we are probably fairly cor- rect. ‘That it was the successor of a more ancient church or even pagan place of worship is not improbable from the discovery of the two bodies buried, facing east, in a sitting position, under the pillar stone. From the crudeness of some of the pottery found in the priest’s kitchen, I can hardly think the date of the stone ehurch can be very much later than the approximate date I suggest. Many of the stones show evidence of having endured extreme heat, while the charred remains over the floor level’ prove that the church was, at least once, burned. The absence of any sign of fragments of slates or tiles proves that it was roofed with 4 Bailymartin Church Ruins thatch. Of the carved stones, some were rough hewn basalt, while a number were of smooth magnesian limestone, of which so much was used by the Normans in the building of the churches of St. Nicholas, Carrickfergus, and the old church at Holywood, and taken from a now exhausted quarry at Cultra. The basalt carvings were all fire marked, while the lime- stone were not, from which it may be assumed that the ancient native lrish Church was burned, and that it was restored and partly built during the Norman occupation. It was probably at this restoration the walls were patched and partly rebuilt with mortared masonry, and the limestone jambs inset. The western end of the south wall, for about twelve feet from its junction with the gable, was entirely gone, but there was one stone in position where the remaining portion of this wall terminates, which was evidently the bottom stone of the east jamb of the entrance door ; the Ordnance Survey memoir referred to above and quoted by O’Laverty, mentions that the door was in the north wall, but this is quite wrong, as no gap occurs In any part of the walls except at the western end of the south wall. The accompanying rough sketches show cxamples of the only carved stones found ; they all appear to be portions of the jambs and mullions of windows, but no fragments of glass were found in the excavations. Of the considerable deposit of kitchen midden remains found at the west end of the church floor, a detailed account may be given. The half quern of Scrabo freestone was practically per- fect, measuring 18” in diameter. Of the other half we found two fragments among the debris of building material, but not in the kitchen midden remains; they were of Tardree rhyolite. I assume that the two fragments were of the half quern that had been originally mated with the other half found in the kitehen midden, but of course there is no proof of this. The pottery remains are of much interest. There were not found sufficient fragments of any one vessel to effect recon- struction. There appear to be pieces of six vessels, four show Ballymartin Church Rians 5 ornamentation by scores or dents, one, a thin unsooted vessel, evidently a milk bowl, had a smoothing surface paste, and one was wheel turned, and elaborately ornamented both inside the lip and outside. The last mentioned is of particular interest owing to its minute resemblance to portions of a vessel found in 1897 by Mr. R. M. Young, in a sandhill settlement near Groomsport* 1 and 2—-Scrabo freestone, not apparently damaged by fire. 3 and 4— Basalt, much burned. there were several examples of 4. 5—Cultra Limestone, undamaged by fire, there were several of these, and one base of a small window of same. * Illustrated and described in the Ulster Journal of Archaeology, 2nd series, vol. iv., p. 46. 6 Ballymartin Church Ruins and also to a portion of a vessel found in the Rath of Dreen, Parish of Ahoghill, in our investigations this year, to which I will refer in a subsequent paper. The exact resemblance of these three vessels to each other in shape, decoration, finish and material seems sutticient to prove that they are approximately contemporaneous. The finding of fragments of a pot of this particular pattern within a church building of about the tenth century confirms the conclusion arrived at with regard to the date of the pottery of this precise type, 11 my papers on pre- historic dwelling places in the Reports of this Society for 1916 and 1917. We found one piece of pottery, evidently the bottom of a vessel, showing signs of glaze of mediaeval type, but un- fortunately I cannot be certain where exactly it was found. I thought at first these kitchen midden remains were those left by the original artizans who built the church, but Professor Macalister informs me that many instances have been noted in early churches where the priest lived in the west end of the church, and that this is an example of a priest’s kitchen. Of the history of Ballymartin Church we have practically no certain knowledge. The reference to “the church of the old town” in the taxation roll of 1307, as Dr. Reeves thought, applies to it; no other mention of it appears in any available record until about 1600, when it is referred to as “ the church of Bally- martin in ruin.”* From various sources we know that for over a century after the wars of John de Courey. the Normans were firmly settled in Co. Antrim, but especially in the fertile district, now known as the valley of the Six mile Water, but anciently as the Tuath of Magh Linn or Moylinne. Prior to the Norman invasion much of this territory was the home of the clan O’Flynn. When the Norman occupation was effected, it was parcelled out among the followers of De Courey. The Savages obtained the lands round Donegore and Rathmore, the townland of Ballysavage perpetuating *See Reeves, Ecclesiastical Antiquities, p. 66. Ballymartin Church Ruins 7 their memory. The Mandevilles held sway east of Templepatrick, while the Logans were settled in a large territory with the present Ballyclare as its centre. The names of a few modern townlands and parishes seem to be all that remain to us of the Norman conquest of this part of Ulster. After the desolation of all this district by Edward Bruce between 1315 and 1318, and the internal dissentions culminating in the murder of the Earl of Ulster in 1333 by the Logan faction, the O’Neills found the conquest of central and south Antrim and north Down an easy matter; by 1360 they had practically subdued or driven out the native O’Flynns of Ui Tuirtri, whom the Normans appear to have allowed to remain in possession of a portion of their lands, and during the century and a half that followed, all the Norman settlers in the southern half of Co. Antrim, excepting Carrickfergus, and in north Down, were similarly dispersed or exterminated. Ballymartin, with Ballysavage, Ballyrobert, Ballywalter and a few other townlands, granges and parishes, perpetuate in their names heroes of the Norman occupation. Ballymartin derives from Martin de Mandeville, who flourished about the end of the 13th century ; Ballysavage from one of the Savages, what particular member of the family we cannot say; but the Savages were one of the most important of the Co. Antrim Norman settlers. Ballyrobert perpetuates the memory of Robert de Logan, a contemporary of Martin de Mandeville; Ballywalter was once known as Walter de Logan’s town, or Loganstown, otherwise Vill de Walter de Logan. Walter de Logan was also a contemporary of Martin de Mandeville and Robert de Logan, and it is reasonable to assume that these and other townland names of Norman derivation date from a general adjustment of the earldom of Ulster carried out by the great Richard de Burgh, Earl of Ulster, about the year 1305*. It is S *See Orpen, ‘‘ The Earldom of Ulster,” Journals of the RS.A.L., vol, xliii., pp. 30—46, and 133—143, and xlv., pp. 123—142. 8 ' The Rath of Dreen interesting to note that of all the great Norman families settled in County Antrim after the wars of de Courcy only one withstood the reconquest by the Irish O’Neills, and the later English and Scottish Chichesters, Hamiltons, and other Elizabethan ad- venturers: I refer to the grant of the Glynns to the Bissets. They, through their descendants, the MacDonnells, still remain, Earls of Antrim, in the proud position of the only Co. Antrim family of the Norman conquest of Ulster surviving in their original lands. THE RATH OF DREEN, PARISH OF AHOGHILI. The townland of Dreen (the blackthorn) lies between the villages of Cullybackey and Ahoghill, the Rath being one mile S.S.W. of the former, but in the Parish of the latter name. The Rath where our investigations took place may be seen on the O.S. 6” Map, Sheet 32, a little to the left of, a point 12 inches due south of the letter “C” in the townland named Cardonaghy. There is another Rath a few hundred yards to the east of that of Dreen, but it is in the townland of Cardonaghy. The Rath of Dreen is of the usual shape, but rather larger than the majority, the airlis or flat enclosure being 110 feet in diameter. The circular vallum is built of the soil extracted from the surrounding trench, and the height from the bottom of the trench to the top of the vallum is about 17 feet. The airlis is not raised above the level of the surrounding fields. As is usually the case the Rath is built on a slight slope, which facilitated the drainage of the enclosed dwellings. Almost in the centre of the airlis, outlined in the grass were traceable two contiguous circular hut sites, each about 15 feet in diameter, slightly raised above the level of the immediately surrounding ground ; to the east up against the inner side of the vallum is a cloghan, or earth house of one chamber as shown in The Rath of Dreen 9 the plan. This is built in the style of the ordinary souterrain, but is almost completely above the ground level, with soil heaped over it, a rather unusual form of construction. At some time a gap was made in the vallum on the east side, and the soil thereby removed was thrown into the trench to make an easy entrance for cattle. I fancy that in doing this a second chamber of fhe earth house was destroyed, as the foundation of the eastern side wall seems to extend somewhat in that direction. The proprietor of the farm, Mr. W. J. Kernoghan, gave his consent to, and otherwise assisted in the investigation of the Rath, and we spent Easter Monday and the two following days at the work, with five men. We first dug a trench round the outside of the vallum in the hope of finding the midden where refuse might have been thrown out from the dwellings inside. The depth of the peaty mud however we found to be from four to five feet, and as. we dug, water gathered in the excavations, compelling us to abandon the search in the trench. We then put some of the men to remove the sods carefully from the hut sites, while the others dug trenches at regular intervals over the airlis. Except at one spot near the southern end of the gap, where we found some coarse pottery, all the archaeological remains were found in the hut sites. In these, immediately beneath the sods, the earth was black and sooty, containing numerous fragments of burned sticks and bones of animals, a few pieces of iron, too corroded to enable us to form any idea of their purpose, three stone axes and a con- siderable number of fragments of pottery. All were lying on or between a fairly regularly constructed series of hearths made with ordinary large flat-topped field stones. A few fragments of flint were turned up, but none of these seemed to belong to even the crude type of implement generally described .as “worked flints.” The utility of the iron fragments being so hopelessly unrecognisable, we are confined to the pottery and the stone axes in our theoretical deductions as to the age of the hut sites. 10 The Rath of Dreen The greater part of the pottery was of the crude class to which in former papers I have given the name “ Souterrain type,” purely hand made, without ornamentation, not made on the potters’ wheel, not finished with any surface paste, but evidently baked in intense heat, and differing in this respect from the cinenary urn or bronze age pottery, which displays less evidence of fusion by great heat. There were fragments of a large number of different vessels, but out of the whole collection we were only able to reconstruct, almost completely, one, and partially another. Both of these were in the loose black soil of the hut sites. The first of these is a cup or tumbler, without any sign of soot; it is crudely ~-JHONi "YOIUBLNI see! Se x 4 ad ¥3 a =e. = iz << obs SS Sk es ZB zz ei bie: ALG BFL NO1L93S ie The Rath of Dreen ornamented by the potter with dents made by his finger or thumb nails. It is circular, but not wheel-turned, and measures 35 x 32. The other vessel is a cooking pot, and is heavily sooted inside and outside. It is wheel-turned and bears a remarkable resemblance in shape, decoration and material to Mr. Young’s find in the Sandhill near Groomsport, and_ the fragments already described as having been found in the priest’s kitchen of Ballymartin Church. These three pots are so similar in general form and in every important detail, that one is compelled to conclude that they are approximately of the same period. From deductions arrived at with regard to pottery in my papers on pre-historic Dwelling Places of Man, in the reports of the Society for 1916 and 1917, I placed the date of this class of of vessel later than that of the Souterrain type, probably the 9th to the 11th century. The finding of a portion of an almost exactly similar vessel in Ballymartin Church Priest’s kitchen curiously confirms the deductions arrived at in these articles. The deposit of refuse, ete., on the hut sides was not at all deep, perhaps ten or twelve inches, including the hearth stones. From this we must conclude either that the house refuse was systematically cleared away by the dwellers, or that the place had not been occupied as a dwelling for a long period. In many lake dwellings hearth sites are found superimposed one upon another, in layers representing many successive periods, showing long continuous occupation ; this was not the case here however, and while some of the coarse pottery was found down on the hard till and round the bottom of the stones, most of it was in the soft upper level of the black soil. ° This applies in particular to the drinking cup, the wheel turned pot, the three stone axes, and the irou fragments, which were all found within a radius of a few feet, about the centre of the western hut side. We must conclude that all these articles were in use by the last occupiers of the hut. It will doubtless be said that this is impossible, and that The Rath of Dreen 13 stone axes could not belong to the late iron age settlement ; but facts are before us. In this connection I may recall that in two of our excavations recorded in detail in the Reports of this Society for the years 1916 and 1917, stone axes were found in immediate association with late iron age remains. I refer to one found in the souterrain at Donegore, and two, of which one was quite perfect and the other a fragment, found in the Ballykennedy Iron Foundry remains. They are illustrated and described in the Report for 1916. Of the three found together at the Rath of Dreen, a detailed description may be of interest. No. 1 is a stone axe of the small thick oval section type. When left by the hut dwellers where we subsequently found it, it had ceased to be of use for its original purpose; the cutting edge is completely worn or chipped away, but the top end bears unmistakable evidence of its having descended to the purpose of an ordinary hammer. The difference of the appearance of the chipped surface of the cutting end and the top is very marked, and may represent a difference in age of an indefinite period. This axe, though in use by the hut dwellers as a hammer, may have been, as an axe, hundreds of years old at the time. Not so, I think, Nos. 2 and 3. They are both of the thin flattish type which some theorists regard as the predecessors of copper and bronze axes of similar shape and the models on which they were designed ; they believe therefore that they are what they call late stone or early Bronze Age, say 1800 to 1000 B.C. No. 2 has a few small chips off the cutting edge. No. 3 is absolutely perfect and presumably unused, as was the very simillar - axe found at Ballykennedy. It is probable therefore that No. 2 is the axe which was in actual use when hut dwellers left the hut, and No. 3 a spare tool in reserve. Ina recent very interesting paper by Mr. E. C. R. Armstrong, in the Proceedings of the Royal Irish Academy, dealing with “Associated finds of stone celts in Ireland” he deals with a great number of Stone Celts found at various times and places in groups of two or more, now in the Academy’s Museum, It is S IS —— = i (NCHES The Rath of Dreen 15 nothing short of calamitous that in not a single instance that I can find has any record been preserved by the past curators as to the actual associations and surroundings in which the axes were found. “Found ina lake,” “ina bog,” “in a field whilst digging” are examples of all the information now forthcoming. In the now considerable number of excavations carried out by this Society during the past four years, I have endeavoured to chronicle in the most minute detail every material fact in connection with the excavation and the circumstances and positions in which remains were found. Without such details, any mere collection of specimens of prehistoric implements is robbed of much of its instructive value ; and consequently the deductions arrived at from their inspection are liable to error. We have now three instances in which we have found stone axes in actual and contemporary association with what are generally known as the late Iron Age remains. These are :— lst. The Donegore souterrain, where one stone axe was found of the rather rough thick type; Wilde in his Catalogue of the Museum of the Royal Irish Academy records the reported find in apparently the same cave of another axe and some arrow heads “now lost, and a portion of a vessel richly ornamented with inscribed scoring, now in the Academy’s collection”; he does not say, however, whether the vessel is a cooking pot or not, or if turned on a wheel; I regret I have not yet had an opportunity of inspecting this in the Museum. Our finds in the Donegore souterrain have been recorded in the Report for 1916, and I have endeavoured to show that the age of the building of these dwellings was between the 6th and the &th centuries. 2nd. The Ballykennedy Foundry where one perfect and one fragmentary axe were found among the remains of many articles of iron and glass.* * In my account of this investigation in the 1916 Report I mentioned a piece of Bronze slag found close to a small crucible, which seemed to fit it ; subsequent examination proves that what from its greenness I took to be bronze slag is actually impure glass, which if purified, is the same type of glass of which the dumb-bell bead found close by consists, 16 The Rath of Dreen 3. The Rath of Dreen just described, where three axes were found, apparently just as left by the last occupier of the hut. These three finds of stone axes in close association with Iron age remains seems strongly to suggest that these implements continued to be both manufactured and used to a very much later date than that usually assigned to them. We concluded our excavations by clearing out the floor of the earth house or cloghan. ‘This search was quite unproductive of results, no fragments of pottery or even charcoal being found. I have to thank Mr. Sidney Stendall for his admirable etchings of the pottery and stone axes. _ : = i ; s N L: HISTORY. AND. PHILOSOPHICAL ‘SOCIETY. — 9 ; PROCEEDINGS ie ae SESSION 1918-1919. aie | — Nee cS oe 3. WITH NOTES on “oe : . “ORESTRY AND AFFORESTATION, = BY ARTHUR DEANE, . ~ QURATOR, “BELFAST MUNICIPAL MUSEUM. 3 : fs . - : i é a ie Se BELFAST: Se ge = PRINTERS 0 ‘THE ae S) UNIVERSITY). V7 ae oe Petes pa | oe pee ra é pa aise #3 Ske iss Prpeetn er tgs he ae gs Se ee LE 7 é * 7 . A Mes ae BE ee es Sy 2 yi a at > Paes ‘sg aseg "1 “017 BJadOA jo ygAoaz Ysoag @ £Q peovi[ded pue pelt AT[vngusas o10M pue ‘potted Arp & SULMp payslanopy 89019 ety, “Wagyu AON ur Sog uo Ve auld syooy WWW ‘HOTA “f M 29904d Proceedings of the Belfast Natural History and Philosophical Society, 1918-1919. 11th March, 1919. TREES—THE CHARACTERS, STRUCTURE, AND PROPERTIES OF WOOD, WITH NOTES ON FORESTRY AND: AFFORESTATION. Illustrated by Specimens and Lantern Slides. By ARTHUR DEANE, Curator, Belfast Municipal Museum. (Abstract.) One of the many things the war has done for us is to raise our regard for timber. Its cheapness and plentifulness in past years rather blinded us to its value. It has taken the war with its resultant forest destruction and transport problems to open our eyes to the necessity of considering our timber supply in the future in a very different manner from what we have done in the past. In 1913 Russia supplied us with almost half our total imports of timber, followed by supplies from Sweden, France, and Canada, and there will be a great demand for timber from the allies for reconstruction purposes, while our enemies will have an accumulated timber wealth. We are not likely to return to pre-war conditions, and we cannot afford to rely upon the possible excess of timber from foreign countries for our industries. In Ireland alone there will be an increased consumption of timber for many years to come, and yet there is no reason why the country should not, in the future, be largely self-supporting in this direction, even if new wood using industries spring up, which is probable if areas become afforested. But if forestry in Ireland is to be successful, it must, from the initial stages, be attempted on sound business and scientific principles with a long look ahead policy, and approached with such patriotism that the generations 36 Mr. Arthur Deane on to come will never have to rely on foreign timber for structural purposes. Afforestation in the United Kingdom is no new idea. It was advocated for many years before the war by pioneers in forestry like Sir Wm. Schlich, the late Prof. W. R. Fisher, Mr. A. C. Forbes, and many others. Had they been listened to, British Forests would have been producing to-day a much larger yield. We are fortunate in having in Ireland under the Depart- ment of Agriculture, Mr. Forbes, who was a Member of the Forestry Sub-Committee appointed by the Ministry of Recon- struction. Just before the war the total yield in the United Kingdom was less than 15 cubic feet per acre per annum, but under a proper forest policy it would have yielded about three times that amount. This small percentage in British woodlands is partly due to their being too open and the soil covered with injurious surface growth, and if these woodlands are to yield a ereater return and a better product in a shorter time, they must, like the continental forests, be placed under proper scientific planning and economic management and not left to Nature. Arboriculture is the art of growing trees singly, or in groups, to preserve them for aesthetic purposes; direct financial gain is not considered. Apart from their ornamental effect, trees make the air fitter to breathe by taking from it the impure carbon dioxide and increasing the supply of oxygen, and for this reason they should be planted more than they are in congested neigh- bourhoods of towns. Many of our city trees show signs of having been placed on a very meagre ration, which does not agree with them. The very tips of tree roots are in direct communication with the uppermost leaves of the foliage, and if roots do not get sufficient air to breathe, they cannot perform their proper functions and lead a healthy life. They need, too, an occasional pick-me-up in the form of nitrate, potash, and phosphate, especially the first-named, for they have not the fallen leaves to keep the soil in condition as in a forest. Many of them badly need serious. surgical operations, which should be performed Trees—The Character, Structure, &c. 3F during the autumn and winter months, so that the antiseptic applied may soak into the wounds, this it fails to do if applied in spring or summer. Sylviculture deals with the growth of trees in dense masses in order to produce timber of high technical quality for knotty or crooked trees cannot produce good timber. The trained forester knows that tall cylindrical trees, comparatively free from knots, can only be obtained in dense forests. | Under such a condition the lower branches are prevented from thriving, and so the size and number of knots are reduced when the timber is cut into boards. It is the dense type of woods we want to see in Ireland, not the open woods for sporting purposes as in the past. Sometimes trees are grown in pure forests, consisting of one species only, or in mixed woods of two or more species which is more complex. Although trees must have a certain amount of light, they differ in their requirements. The forester takes advantage of this, and divides trees into light-demanding species and shade-hbearing species, and mixes accordingly, as for instance, Oak with Beech, Larch with Beech or Silver Fir, Scots Pine with Spruce, according to the soil and climate. Mixed woods should always contain shade-bearing species which protect the soil and kill out weeds; especially is this necessary on thin exposed or peaty soils, or places swept by winds. It is interesting to note that those trees having a smooth thin bark are usually shade enduring species, as is the case with Beech, Hornbeam, Spruce, and Silver Fir, while those species that early in life acquire a rough bark are usually light demanding, such as Oak, Pine, Ash, Sycamore, Poplar, Alder, and Willows. The great difference between the Ireland of to-day and the Ireland before the Christian era lies in the amount of forest. Although good progress has been made in afforestation in Ireland under the Department of Agriculture, she is, comparatively speaking, a woodless country now, and yet, Ireland is by nature an ideal country and well adapted with her temperate and humid climate for growing timber trees. Instead of producing 38 Mr. Arthur Deane on the highest percentage for Europe as she should, she produces the smallest. Her hillsides become denuded by water carrying away a rich burden of soil, choking up rivers and, in some places, making the lowland soil so boggy as to he unsuitable for agriculture. Where bogs have encroached, after cutting the turf, the stumps of ancient trees are sometimes found in situ standing like small monuments as if to remind us that Ireland was formerly full of timber (see frontispiece). In fact, we have shown in such a bog an excellent example that where a forest had existed and had not been replaced, a change to an inferior soil and climate resulted. It is for this reason that we must not suppose that these tree-remains give us an indication as to what trees should now be grown upon such sites. Before a peat bog can be made to support tree growth, it must be drained, and especially should this be done with live peat in order to destroy the surface vegetation. The fibrous covering must also be completely broken up, or better, removed for a depth of 3 or 4 feet so that the roots may dip into the soil and the new surface weathered. On such a site one would not expect to grow large timber, but poles for fencing and pit props. Soil should be regarded as the greatest natural economic endowment of a country ; it is the primary source of wealth. Our very existence depends upon it and yet the loss of soil capital by water attrition is enormous. Why should this perpetual waste of soil from hillsides go on when there is such a demand for softwoods which will grow in Iveland and yield a quick and profitable return if carried out on a large scale? On better soils trees such as Oak, Ash and Chestnut might be grown. Trees are soil builders and soil binders. Their root range is far and wide, and they act as wedges cleaving the rocky substratum into the hollows. of which water percolates, carrying with it the soil particles. The fallen leaves would create a modification in the soil, which would be shaded and protected from wind, sun, and surface growth by the continuous canopy formed by Trees—The Character, Structure, &c. 3 te} the foliage of the trees. ‘The importance of maintaining a dense eanopy above and a suitable forest floor below cannot be too strongly insisted upon. grain produced by broad and crowded Rays. & 3. LIME (Tilia) Silver- grain. produced by fine Rays. Photo: J. A. S. STENDALL. Fic. 1. Radial or quarter-cut boards, showing silver-grain. The horizontal lines clearly shown in Nos. 1 and 2 are Ring-boundaries. Page 53. vesnvin X 1g o8eg *(peonped &yysys) *pooM jo sodA} Yueteyrp sutrmoys °% “ory TIVINALS “S "yf 2 9304g (esnsjopnasd) 3Niq NODSYO-"poOoM snoiod -uON (Snd4end) HVO DOOM Snood -38uly aa a ar POOM er) 2 B5© AQUIUAS — a be mas 1 2a poom Z Suiads (x1yeS) MONNIM -"poom snoji0od-esnjsia 7 2”? gs Wales n 2 S = = ae oe g 2 = W) rb) Tyee W) = g Mes oaks ‘he ae : QO So 00 S c 00 = col 8 é¢ i oleae Dos i 74 a NAY) © a 3 3 =) a = eG S c I 3 Ors Ww nce > a 5 . S. STENDALL. adek J Photo: 3 5) th Flecks, page i Ie . ~ Trees—The Character, Structure, &c. Dil ends knocked out, and usually having on their walls bordered pits and reticulated thickenings. A vessel, then, is a cell fusion, while a tracheid is a cell. They may range from the diameter of a pin, as in Oak, down to those too small to he seen with the naked eye, as in Willow. Hardwoods on this account are some- times called “ porous woods,” while softwoods having no vessels are frequently called “non-porous woods.” Among the hardwoods, those forming a prominent porous ring are sometimes described as “Ring porous woods” such as Oak, Chestnut, and Elm, while those examples where the pores are more or less evenly distributed throughout the entire ring are frequently described as “ Diffuse porous woods” such as Birch, Hornbeam, Alder, Poplar, and Willow. The rings are best defined in ring-porous woods and non-porous woods. (Fig. 2). Tyloses.—These are ingrowths of cells adjoining the pore (vessel) of some hardwoods or a resin pore of some softwoods, or more rarely in the tracheids of such hardwoods as sweet gum. (Liquidamber styraciflua). These cells make their invasion by pushing their way through the pits or unthickened portions of the walls into the cavity. They contain protoplasm and in some cases nuclei, and may divide and completely plug up the lumina of the elements which they invade, forming partition walls at irregular intervals throughout the entire length of the tube. Tyloses occur in many woods, sometimes few and sometimes in abundance. We have examples in some Oaks, Sycamore, Robinia, and Snakewood (Brosimum aubletti). Inthe last named the tyloses become thickened and converted into stone cells. Tyloses originate under various conditions, but are more usually found in connection with the transition of the sapwood into heartwood, especially in those woods with large pores, rendering the heartwood impervious to water. They are also produced in the pores of wood wherever local injury takes place, as in cut branches, and they develop in the cementing tissue during the progress of engrafting. ‘ Snow points out that air can be readily blown through 52 Mr. Arthur Deane on several feet of Red Oak, even if unseasoned, because tyloses are not present in the pores, but a pressure of 100 lbs. per square inch is sometimes insufficient to force air through a single inch of unseasoned White Oak, because the pores of this species contain abundant tyloses. They thus tend to retard the introduction of foreign fluids such as antiseptics. Wood Fibres.—These are thread-like cells, not unlike tracheids in outline, but usually longer and with much thicker walls, which is a characteristic feature. Sometimes they are so thick as to show hardly any cell cavity, and they are devoid of the characteristic bordered pits of the tracheids of softwoods, the pits being small and slit-like. They are not found in soft- woods, but they form the principal structure in hardwoods. These fibres contribute largely to the strength and hardness of hardwoods, and the more they predominate the better. According to K.-C. Jeffrey a peculiar kind of fibre is found in some Oaks and in some leguminous woods, caused by the inner wall of the fibre becoming mucilaginous. Woods having mucilaginous fibres are stated to be of special value in cabinet work on account of their relative immunity from shrinking and swelling, while the numerous mucilaginous fibres composing the woods of False Acacia (Robinia Pseudacacia) make the wood very suitable for trenails in the construction of wooden ships, as they neither swell unduly in water nor shrink in the sun. Wood Cells (Wood parenchyma). These are much more abundant in hardwoods than in softwoods Sometimes they are scattered in characteristic fashion among the wood-fibres and are usually lighter in colour than the surrounding tissue. They often adjoin the vessels and become a useful aid in identifying timbers. In the Oak they form radial lines in the summer wood (Fig. 2), while in the Elm they surround the pores to form tangential lines. In Corkwoods, such as Balsa wood (Ochroma Lagopus) exhibited, the wood consists in a large part of wood cells. The wood cell tissue of the sapwood is used during the resting season as a storehouse for reserve food material such as starch. Trees—The Character, Structure, &c. 53 Pith Flecks.—Peculiar patches which have a_ pathologic origin are sometimes found in wood, and usually appear coloured and well defined on the cross cut section of logs, or on tangential boards. In Hornbeam and Cherry they are inconspicuous, owing to the colour of the wood. They frequently occur in Willow, Poplar, Alder, Birch, Lime, and many trees belonging to the Rosaceew, They are the burrows caused by the larvae of a dipterous insect (7ipula) feeding upon the cambium during the growing season, and afterwards becoming occluded with wound tissue of a soft cellular nature. (Fig. 3). SURFACES OF TIMBER. In cutting timber there are three surfaces or exposures, and in order to understand the structure of timber, it is important to study the three planes of section: (Fig. 4) (1) the transverse or cross cut section, i.e. at right angles to the long axis; on this surface the annual layers appear as concentric rings and the rays as long lines as it shows the latter in longitudinal view from above or below: (2) the radial cut or quarter-sawed timber, ie. cut towards the centre of the log parallel with the rays: the rings then appear as vertical lines, and crossing these at right angles are the wood rays displaying their longitudinal view from the side to form flat expanded surfaces known as silver grain in large rayed woods: (Fig. 5) (3) the tangential surface or slab cut, which is parallel to the bark and at right angles to the rays. Here the rays are not conspicuous, but under a lens appear as short pointed streaks distributed irregularly among the other tissue, this is a very important surface, however, when studying timber, because we get some idea as to the height and breadth of rays as we view them in transverse section. The rings appear on this surface as ellipses or hyperbolas in the centre and open stripes at the side. To grasp this, one must remember that the rings are hollow cones nested one within another, 54 Mr. Arthur Deane on Boards cut with the rays (i.e. radial or quartered) are stronger and less liable to warp and split than those cut across the rays (tangential) which form the ordinary boards, Tangential cuts may, however, present a pleasing appearance as in Elms. It is important to note, as the late Thomas Laslett has pomted out, that in tangential boards there is an outside and inside to every board, and especially should this be noted in floor boards with the strain of traffic. These should be laid so as to expose the youngest or outermost rings ; otherwise if laid with the older or innermost rings exposed they will shell out, forming hollows in the boards. In other words the convex side should be upper- most. TIMBER versus METAL. From the earliest times wood has been used in construction, and for making implements and utensils wherever it grew, at first by primitive stone tools; but later, with metal tools, wood was more extensively used, and to-day, with the advance of civilization, it is the most widely used material in spite of its replacement to some extent by iron and stone in buildings. Timber used in construction has many advantages over metal. Advantages :— 1. One great feature is that wood, being an organic structure, can be reproduced. The cutting of forests has advanced at a greater rate than they have been regenerated, yet, under a well conducted forest management, forests could be made to yield indefinitely. With inorganic materials such as metal and stone, the more extensively they are utilised, the quicker the supply becomes exhausted with no opportunity to replace them. © 2. Timber is stronger than is generally supposed. In tensile strength (resistance to a pull lengthwise of the grain) a bar of hickory exceeds a similar bar of iron or steel of the same weight and height. A 10 ft, bean; of hard a) e el Trees—The Character, Structure, &c. 55 pine requires considerably more load to bend it by one inch than a similar bar of iron of the same weight and length. Timber can stand a far greater distorsion than metal without losing its power to regain its original position. In this way timber gives a warning before reaching breaking point. In many eases of damage or fracture it is easier to replace, and it can be shaped and reshaped with greater ease than metals. 12” wooden beams, though combustible, require a good deal of heat to destroy them, because the surface becomes charred and protects the inner portion. ‘Timber beams will often remain in position, after a fire, and carry 2 load, while iron and steel under the same heat would twist out of shape and fall. Timber does not corrode like metal. It lasts longer, even without paint, in exposed situations. With metal, access to moist air must be prevented. Impurities in iron cause brittleness and weakness. ‘Timber continually under water lasts longer than iron or steel. Timber is a poor conductor of heat and electricity ; it is pleasant to touch, is more artistic, and has a beauty absent in metal, and has none of the injurious effects of iron and steel. Pieces of wood may be strongly glued together. Metals, on the other hand, would require welding or soldering. By too frequent reheating and forging, wrought iron is weakened. Certain timbers may be used for casks, remaining un- affected, and imparting no disagreeable flavour to their liquid contents, where metals would be objectionable or even poisonous. The elasticity of certain woods renders them superior to any metal for the resonant parts of musical instruments, 56 My. Arthur Deane on So far, we have been considering the advantages of wood over metal. We must not, however, overlook some of the disadvantages. Disadvantages :— 1. Wood cannot be melted or cast. Rods, or thin sheets of wood, however, can be bent when steamed, and when reduced to pulp can be moulded into almost any shape. 2. It shrinks and expands with variations of moisture a good deal more than metal under ordinary variations of temperature. S . Being more easily crushed than iron, it is not so well suited for bearing the greatest weight or for resisting heavy blows. . For commercial buildings greater strength is obtained in steel, less depth of girder is required, and thus a gain in height. Sir T. G. Jackson, R.A., in his book “Reason in Archi- tecture,’ 1906, p. 171, says: “Iron construction is really still in an experimental stage; we do not yet know how it will © NS stand the test of time. Meanwhile, all experience hitherto tends to show that an Architect who wishes his building to go down to posterity will do wisely to let iron play as small a part as possible in his construction. It has been prophesied that 30 years hence no one will employ iron in his buildings, at all events, as the main element in their fabric. The failure of a single tie-rod seems to have been the cause of the collapse of the roof at Charing Cross Station, and it is certain that no monster roof of that kind will ever be put up again. To say vothing of great railways and other engineering works, it is disquieting to think of the miles and miles of streets in London and other towns where the whole of the upper storeys rest on girders accessible to atmospheric changes, liable to rust and fatigue and possible injury by vibration, which no one can examine and which cannot be repainted.” It would be interesting to know the opinions of our local architects and civil engineers seeing it is 12 years since these Trees—-The Character, Structure, &c. 57 remarks were published. Perhaps the best conclusion is a happy combination of both, because the properties of one so largely supplement those of the other. NAMES OF TIMBERS. The multiplicity of common and trade names of timbers is so bewildering and misleading that one is forced to wonder why Architects and others, whose duty it is to draw up specifications, do not recognize the importance of botanical names in order that the timber wanted may be properly defined and many difficulties avoided ; especially is this important now that new kinds of timbers may be used in place of others. ‘Timbers from different countries frequently go under different names, making it appear that they are more numerous than is actually the case, and often they are brought from afar because the same species nearer at _hand is not recognized by its local name. Moreover popular and native names may in the course of time disappear and be replaced by others. What we call Pitchpine (Pinus palustris) has something like 30 common names, and in America is usually called Longleaf or Georgian Pine, their pitchpine being Pinus rigida, an inferior species. Weymouth Pine (P. strobus) is known on our market as Yellow Pine, but is called in America White Pine. The wood of Douglas Fir, (Pseudo-tsuga Douglasiz) if wide-ringed, is usually reddish and is known as “ red-fir” and “ oregon pine,” and the popular belief is that these timbers come from different species of trees whereas the two grades are obtained from the same species. Intermediate grades are also common. “Southern Pine” of the United States includes three species. An Architect specifying for Southern Pine may be supplied with any or all of the pines in question. The name “Mahogany” is not now confined, as it originally was, to a single species, (Swietenia Mahagont) but to a number of timbers from many different genera and species of trees which differ widely in anatomical structure. Some 70 kinds of timber 58 Mr. Arthur Deane on are sold under the name of Mahogany. A good paper on the recognition of some of the different kinds of Mahoganies, by Dr. Dixon of Trinity College, which he read before the Royal Dublin Society, was published in December last. Dr. Dixon describes some 45 kinds of “Mahogany” which he had the opportunity of examining. The paper is illustrated by excellent photographs, the tangential sections being particularly valuable in displaying the area occupied by the rays in the different woods. Enough has been said to show that common names are confusing, which makes it very possible to substitute timber of poor quality for better timber. This leads to the necessity of a reliable means of recognizing commercial woods. The wood design produced by the cambium when viewed in the three directions offers the most reliable means for the identification of timbers, although there are accessory characters such as colour, taste, odour, bark (if present), which may be helpful in conjunction with structural characters. Even structural character does not always render identification easy between related species, as in Oaks. Although an Oak wood is perhaps the easiest to identify, yet it is one of the most complicated as regards its structure, while softwoods, although much simpler in structure, are more difficult to identify than hardwoods, and frequently require the aid of the microscope for decision. In attempting the identification of wood, one should not forget the observations of many good workers, and particularly the labours of H. Nérdlinger, R. B. Hough, J. S. Gamble, F.R.S., on Indian Timbers ; the late Professor Marshall Ward, F.R.S., and Herbert Stone. Many attempts have been made to establish keys to “run down” timbers, but these generally deal with only certain woods. Mr. Herbert Stone, the author of an- excellent book—*‘ The Timbers of Commerce and their identification,” and other works, who has examined mauy thousands of timbers, has devoted much time and thought to the construction of a key. An interesting account of Mr. Stone’s suggestions for such a key will be found Trees—The Character, Structure, &c. 59 in a discussion on a paper on ~ Wood: its identification and mechanical properties,” by W. H. Barling, which appears in the Aeronautical Journal for May, 1918. Anyone wishing to take up the study of the identification of timbers will find in the Museum many examples to commence with. We have Ceylon timbers presented to this Society by Sir James Emerson Tennant, British Guiana timbers in the Grainger collection, Canadian and Australian timbers, and Queensland and other timbers given by Mr. Herbert Stone of the Forestry School at Cambridge. BIBLIOGRAPHY. The following books and pamphlets will be found very useful to those who wish to expand their knowledge on the points. raised in the lecture. All of them will be found in the Reference Department, Public Library, and the writer is indebted to the Authors of many of those mentioned. Forestry and Afforestation. Commercial Forestry, Ministry of Reconstruction. 1919. Forestry Sub-Committee: Final Report. Ministry of Recon- struction. 1918. Forbes, A. C. ... The Development of British For- estry. 1910. Graves, Henry 8S. ... The place of Forestry among Natural Sciences. Journal Washing- ton Academy of Science, vol. 5, 1915. Schlich, Sir Wm. .... Manual of Forestry, 5 vols. Stebbing, E. P. ... Forestry asa Career. The World’s Work, February, 1918. do. ... Afforestation and National Economy- The World’s Work, Septem- ber, 1918. 60 Mr. Arthur Deane on The following in the Journal of Department of Agriculture and Technical Instruction, Ireland :— Forbes, A. C. Henry, A. do. Barling, W. H. Baterden, J. R. Brown, H. P. Dixon, H. H. Groom, Percy Hanausek, T. F. Jeffrey, E. C. Koehler, Arthur Production and Value of Irish Timber. 1915. Profitable Trees. 1913. The Artificial Production of Vigorous iiregs, 91914 Avondale Forestry Station. 1907. Forestry : six articles. 1906. National Importance of Forestry. 1905. Position of Larch in Irish Forestry. 1907. Tree growth on Bog Land. 1910. Wood Structure, ete. Timber: its identification and mechan- ical properties. The Aero- nautical Journal. 1918. Timber. 1908. Pith-ray flecks in wood. U.S. Dept. of Agriculture. 1913. Mahogany and the recognition of some of the different kinds by their microscopic characters. Royal Dublin Society, 1918. Trees and their life histories. 1907. The Microscopy of Technical Pro- ducts. 1907. The Anatomy of Woody Plants. 1917. | Guidebook for the identification of woods used for ties and timbers. U.S. Depart. of Agriculture. 1917. Trees—The Character, Structure, &c. 61 Sargent, F. L. ... Plants and their uses. 1914. Snow, C. H. ... Wood and other organic structural materials. 1917, Stone, H. .... The timbers of commerce and their identification. 1904, = 7 Dai a7 Mi — a * Lith January, 1919. FRONTIERS OF FRANCE. By Pror. GRANVILLE A. J. COLE, F.R.S., M.R.IA. (Abstract by the Lecturer.) Ancient Gaul, the predecessor of France, received its civilization from the spreading Roman Empire, and in turn impressed that civilisation, and a speech of Latin origin, on the Franks and Goths who seized upon the Roman lands. The Goths sided with the Romans against the barbarous Huns, and the dwellers in Gaul did much to maintain the traditions of law and order transmitted to them by Roman rule. The divisions of- western Europe in the middle ages led to the struggle between a growing kingdom of France on the one hand and the English and the Burgundians on the other. The frontiers of France as we now know them were the dream of the young peasant girl, Jeanne d’Arc. In her 19th year, by faith and devotion to a visionary cause, deserted by her king and martyred by the English, she had laid the foundations of a united France. The Phocaeans brought Greek civilization to Massala (Marseilles) in 600 B.c., and this harbour on the Mediterranean frontier remained the great port of entry for the Romans. The Rhone valley west of it gave easy access to the interior, and to-day Marseilles is the link between Paris and the colomial lands of France in northern Africa. From it the French have taken up the mantle of imperial Rome, and their heroic actions on the Meuse and on the Somme have been discussed on the steps of Tunisian mosques and supported by Moslem volunteers. The rampart of the Pyrenees forms a highly effective and natural frontier between France and the Iberian block, and checked in critical centuries the progress of the Moorish Cali- 64 Professor Granville A. J. Cole on phates. From its western end the great confluent delta of the Garonne and its tributaries spreads northwards, forming the level country of the Landes, margined by sand-dunes and swept by the Atlantic winds. This ocean frontier was known to the Phoenicians, and it is said that the first knowledge of letters reached Gaul through the estuary of the Seine. ‘The bleak promontory of Brittany, which gave so many seamen to the navies of France, is part of “Armorican” Europe, a folded mass far older than the Paris Basin, the Pyrenees, or the Alps ; it is repeated in Cornwall and southern Ireland, and can be traced through the Ardennes and eastward far across the Rhine. The special “narrow sea” of the old writers, the link . between the North Sea and the English Channel, completes the sea-frontier of England, but has allowed of frequent rivalry between dwellers on the opposing shores. Across it the Nor- mans converted England into “the most successful colony of France,” while their anglicized descendants made frequent raids upon what they claimed as their rightful soil in Picardy. The holding of Calais by those who held the port of Dover was long regarded as essential to England’s safety. A permanent and warm alliance with France offers a far better guarantee at the present day. Eastward from the narrow sea, the northern frontier runs across the level lands of Flanders, where natural boundaries are hard to find. Here nation has warred with nation for supremacy in western Europe, and the open Nether- lands have been again and again overrun in struggles with which they had no immediate concern. It is no accident that the invaders of France in 1914, and the victorious allies marching northward in the autumn of 1918, traversed the ground of Conde’s, Marlborough’s, and Wellington’s campaigns. The frontier is far better defined when we reach the Armorican ridge of the Ardennes, which leads us eastward to the Rhine-trough. The mass of the Vosges forms a natural rim to France above the Rhine, though the river itself must be accepted as the actual frontier of Alsace. This country, Frontiers of France 65 formerly divided among small states and German _ bishoprics, was annexed to France at the close of the thirty years’ war, and by the wise treatment of 200 years became thoroughly French in spirit. The language was not interfered with in the German-speaking districts, and it was Alsatian-Strassburg in 1792 that Rouget de Il’Isle, a young captain of Engineers, composed and sang for the first time verses that he called “A song of the Army of the Rhine.” ‘That army had flung back the coalised Prussians and Austrians to the natural edge of France, and the song, renamed the Marseillaise, remains the anthem of the great French Republic. France in 1870 paid the price of a rash attempt to cross the Rhine in arms, and the frontier was broken by the counter- onslaught of Bavarians and Prussians, who swept their opponents into Metz and northward along the Meuse vale to Sedan, where the second French empire fell, five weeks after the opening of the war. ‘The new frontier that was exacted by the victors in 1871 was determined strategically, and was designed to secure the iron mines of Lorraine as well as to keep back France from contact with the Rhine. From unconquered Belfort, the Juras provide a region very difficult to traverse, where the valleys run south-westward, parallel with the axes of folding in the range ; and then we reach, ranging from Mont Blane to the Mediterranean, the unrivalled frontier of the Alps. The nature of the superb but little visited region of Haute Savoie and Dauphiné may be illustrated by the traverse of seventy miles from Grenoble across the Lantaret Pass, and through the frontier-fortress of Briangon to the wall of Italy at Mont-Genevre. Right down to the Maritime Alps, equal difficulties must be encountered by an invader, and Charles V. lost two armies in his attempts across the hills on Toulon. Again, in 1707, Prince Eugene and the Duc de Savoie lost 10,000 men before Toulon and in their enforced retreat. At Nice and Monte Carlo, the range is cut across by the sea, so that the road and 66 Prof. Granville A. J. Cole on Frontiers of France railway into Italy have to find what space they can and often: tunnel through projecting spurs. The Alsatian frontier on the Rhine has now been recovered for the French. The desecrated northern frontier has been crossed by the armies of the H’ntente at the final collapse of terrorism after four years of devastating war. The vigour of the French defence is typified for us by the stand on the Meuse at Verdun and in the trenches across the open plateaus consecrated by the home of Jeanne the Maid. It may he illustrated in a concrete form by the chase of the Zeppelins from Paris southward on October 20th, 1917, when four of the invading airships were brought down between Lunéville and the cluse of Sisteron, kept by the vigilance of defensive aircraft from escaping into German lands. France has held her frontiers as she held them once before at Valmy and Jémappes, and it was with a wise fore- knowledge that M. Driver in 1917 named his fine bust of the Republic, worn by conflict but confident of right, La Republique de la Victorve. eport and Proceedings — | BELFAST 7 rs ‘Natural History and Philosophical saciety ty 7 Ne Beat, he K “ \ _ FOR THE ‘SESSION 1919-20. SN Oy 4 Alege Es AUS ~ : BELFAST». A E, BOYD & SON, LED 2 CORPORATION STREET _ (PRINTERS TO THE QUEEN’S UNIVERSITY). " \ ' hd . i j 1921. Heport and Proceedings SEAS | Natural History and Philosophical society FOR THE SESSION 1919-20. i al aac — >.> ¢ aia) USE ae © Sy eee bow aU, BELFAST : MAYNE, BOYD & SON, LTD., 2 CORPORATION STREET (PRINTERS TO THE QUEEN’S UNIVERSITY). 1921. * 3 bith ol NATURAL HISTORY ANP EILOSOPHICAL-SOGIETY. Officers and Council of Management for 1919-20. President : Pror. GREGG WILSON, o.8.£., M.A., D.SC., PH.D., M.R.I.A. Vice=Presidents : Str CHARLES BRETT. S. W. ALLWORTHY, M.A., M.D., F.C.S. PROF. JAMES A. LINDSAY, m.a., F.R.C.P. ROBERT M. YOUNG, M.a., M.R.I.A., J.P. J. M. FINNEGAN, ».4., B.Sc. WILLIAM SWANSTON, F.«c.s. tbon. Treasuret : HENRY RIDDELL, M.&., u.1.M.5. thon. Librarian : ROBERT M. YOUNG, M.aA., M.R.1.A., J.P. ‘tbon. Secretary : ARTHUR DEANE. Council : W. B. BURROWES. K. J. ELLIOTT. H. C. LAWLOR, M.R.1. A. WILLIAM SWANSTON, F.a.s. ProFEssor GREGG WILSON, p.sc., M.R.1.A. JOHN M. FINNEGAN, B.a., B.sc. Proressor J. A. LINDSAY, m.a., F.R.0.P. HENRY RIDDELL, m.&., M.1.M.£. ROBERT M. YOUNG, M.4., M.R.1.A., J.P. PrRoFEssor W. ST. CLAIR SYMMERS, m.x. Str CHARLES BRETT. ~*Sir JOHN BYERS, m.4., M.D., M.A.O. S. W. ALLWORTHY, .a., M.D., F.C.8. WILLIAM FAREN. ARTHUR DEANE. *Died September 20, 1920. Retire 1920. Retire 1921. Retire 1922. TF —eeeee Belfast Natural History and Philosophical Society. O ESTABLISHED. 1621. ) CONSTITUTION. The membership of the Society consists of Shareholders, Members under the new scheme authorized by the Society, Annual Subscribers (Associates), Honorary Members and Honorary Associates. A holder of one share pays an annual contribution of ten shillings ; « holder of two shares (in one certificate) an annual contribution of five shillings ; while a holder of three or more shares (in one certificate) is exempt from annual payments. Shares on which the annual payments as above are in arrear are liable to forfeiture. The Council retain the right to decline to consolidate two or more share certificates iuto one certificate. Members under the new Scheme are elected by the Council, pay ten shillings per annum subscription, and have the right to vote on all questions not affecting the ownership of the property of the Society. Annual Subscribers (Associates) pay £1 Is. Od. (one guinea), due Ist November each year in advance. A general meeting of Shareholders and Members is held annually in May or June, or as soon thereafter as convenient, to receive the Report of the Council and the Statement of Accounts for the preceding year, to elect members of Council, to replace those retiring by rotation or for other reasons, and to transact any other business incidental to an Annual Meeting. The Council elect from among their own number a President and other officers of the Society. Each member has the right of personal attendance at the Ordinary lectures of the Society, and has the privilege of introducing two friends for admission to such. The Session for lectures extends from November to May. Any further information required may be obtained from the Honorary Secretary at :—The Museum, College Square North, Belfast. Proceedings of the Belfast Natural History and Philosophical Society, 1918-1919. 12th November, 1918. IRISH WOODS AND FORKSTS. Illustrated by Lantern Slides. By Proressor AUGUSTINE Henry, M.A., Professor of Forestry, Royal College of Science, Dublin. Professor Henry, in the course of his address, which was illustrated by many beautiful views, described how trees growing on bog-land had been killed by the change of climate which the country had experienced some 3,000 years ago, and how the bog had since grown above their roots to a considerable depth which explained the presence of tree stumps and roots being found twenty or more feet below the bog surface. The lecturer emphasised the very great repressive effect of wind on the growth of trees, and showed how important was the proper selection, not only of sites for tree planting for timber purposes, but the species of trees best suited to resist wind in exposed situations. A brief historical account was given of some of the more famous woods—principally Oak woods—in the North of Ireland, including the historic “derry,” which was cut down to build the City of Londonderry. The forests along the Lagan Valley and in the lower Mourne district were also dealt with. In conclusion, the Professor said “the reafforestation of those parts of Ireland which were suitable for the purpose should be approached in a systematic way, otherwise attempts of this kind would be of little practical good.” At the close a vote of thanks to Professor Henry was passed by acclamation, 68 26th Mebruary, 1919. “THE STORY OF PORCELAIN.” By Mr. CHARLES EK. WHITE. In the course of an interesting address, Mr. White pointed out that commercial cumpetition had always tended towards deterioration in the artistic merits of porcelain ; the cheapening of prices resulting from this competition, and the cutting down of wages had often made it impossible for an artist to put his soul into the work. This had helped to bring about the deterioration in style and the introduction of transfer printing on porcelain. Several lantern slides were shown of Belleek porcelain, in which the effect of temperament and national characteristics were displayed. In addition to a full series of slides Mr. White illustrated his remarks by beautiful specimens of the potter’s art. A hearty vote of thanks was accorded the lecturer on the motion of Mr. H. C. Lawlor, seconded by Mr. R. 8S. Lepper. 69 Sth April, 1919. “THE ROMANCE OF TUBERCULOSIS.” By Dr. ANDREW TRIMBLE, D.P.H., Chief Tuberculosis Officer, Belfast. Professor W. St. Clair Symmers presided, and_ briefly introduced the lecturer, remarking that tuberculosis was the most dreadful of all human diseases, and he trusted that one of the results of the lecture would be to reawaken in Belfast that keen interest which they had in the disease some few years ago ; he was perfectly certain that the campaign to which he referred did an untold amount of good. Dr. Trimble said he had noticed that the history of a scoundrel was always much more interesting to the bulk of man- kind than the history of a saint. If he was correct !n his observation, then the subject of tuberculosis should be of thrilling interest, for tuberculosis might well be called the diabolus amongst the demons of disease—the scoundrel amongst the scourges of humanity. It was hoary with age, and yet had all the energy of youth. It attacked the prince in his palace, and the peasant in his hovel—but preferred the peasant as the easier prey. It neither pitied the young nor honoured the aged, although it preferred to wait till its victim had come to maturity, and, just at the moment when life was inviting and hopes were high, it dashed the cup of youth in pieces to the ground. It attacked the animal as well as man. It settled in every tissue of the body, although it preferred the more delicate and vital parts. It attacked the strong as well as the weak, but preferred the weak. It observed the lifeboat rule, “Women and children first,” with an irony that was sardonic. It gave the flush of health to its victim at the moment when it was about to push him over into the grave, and instead of warning its victim of his 70 Dr. Andrew Trimble on impending doom, it blinded his eyes to his true condition and gave him the false hope of betterment and life. And all that it did in a manner so wholesale and sweeping thatit killed annually in the Empire more victims than we lost each year since the greatest war in history began, and wounded twice as many people as were wounded in warfare. ‘To be specific, more than 60,000 people died annually in the United Kingdom, while it was com- puted that there were at least seven actively tubercular subjects to each one who died, or more than 400,000. The history of tuberculosis was not a chapter in the history of medicine : it was part and parcel of history itself. Though the recorded historical observation and tabulation of symptoms began about the time of Hippocrates, it was obvious that symptoms of tuberculosis must have been observed long before, for there was no reason to doubt that the bacillus showed its activities almost at the dawn of civiliza- tion. Proceeding, the lecturer sketched the history of the study tuberculosis in a most interesting manner, dwelling particularly upon the work of Anenbrugger, Laennec, Jean Antoine Villemin, Cohnheim, and Koch. The final discovery, by the last-named— the cause of tuberclosis—-said the lecturer, was not less epoch- making, or less important to humanity, than was the discovery by Columbus of America. Let them turn now to the tubercle bacillus, and hear what he had to say for himself. He had called him a scoundrel, but if he were a criminal being tried at the bar of humanity, he would have aright to say what he could for himself. If they gave him that opportunity, he fancied this was something like what the bacillus would say in his defence :— “You have accused me of being the cause of much suffering, and of innumerable deaths ; of having slain without pity the young and the old from time immemorial. But I would remind you that in that respect I have done no more than you yourselves— the lords of creation—have been doing for the past four and a half years. If I reproduce myself to the damage of my host, I would like you to remember that it was not I who put myself in the position of doing this injury. I can neither walk, swim, nor The Romance of Tuberculosis. (U3) fly, and if I find myself in the body of either man or animal I must have been blown there by the wind, or introduced by the careless and filthy habits of the individual. For the rest, I have but obeyed the law of nature, that the fittest survives. But allow me to point out to you that the death of my host, far from being my object, is to me an unmitigated calamity. For, being buried with him in the earth, I soon follow him into decay for want of warmth and food. I have my place in nature, as you have yours, and if you will not compel me to enter your bodies, I am content to remain outside, fulfilling my function in some other fashion. But after examining all the facts, can you say I have been an unmitigated evil? I have altered the destiny of many an individual. I have had an effect, not always for the worse, but often for the better, on art, music, and literature. I have called out and developed tender sympathies and loving devotion that otherwise might have lain dormant, and if now you understand that I am an accompaniment of poverty, crowded housing, careless and dirty persenal habits, and of Cain-like indifference to brotherly feelings, and if, understanding this, you recognize the necessity for more and better food, for decent housing accommodation, for parental solicitude for little children, for personal cleanliness, and if, realizing this necessity, you are resolved to remedy these evil conditions so far as lies in your power, you will at one stroke have removed the opportunity of which I—with a horde of other evil spirits of infectious diseases —have taken advantage, and you will at the same time have laid the foundation of a happier and healthier humanity.” The lecturer went on to say that he thought the jury, having heard such a speech, would bring in a verdict of “guilty, but with extenuating circumstances.” It might be well, however, to take the admonition of the bacillus to heart, and to put his suggestions into practice. He had mentioned in his speech a circumstance that had not:commonly been noted—that of the effect which he had had upon the arts and literature. Might he (Dr. Trimble) say at once that he believed there was a great deal of 72, Dr. Andrew Trimble on The Romance of Tuberculosis. truth in what he had said. The tubercle bacillus was a traitor in that he had not failed to attack royalty—our own Richard III. apparently suffered from tuberculosis of the spine. Again he hesitated not to strike down the little Dauphin of France, “the king who never reigned.” Amongst artists, he laid his hand on Watteau and Sebastian Le Sage. Amongst poets, he shortened the lives of Henry K. White, Keats, Elizabeth Barrett Browning, Sidney Lanier, Henley, and Francis Thomp- son, while it was on account of tuberculosis that Shelley made the journey to Italy, where he was destined to meet with so tragic a death. He stilled the notes of Henry Purcell, Paganini, Chopin, and Weber. Amongst preachers, he carried off George Herbert, and attempted, but failed, to carry off John Wesley. Even famous soldiers fell in combat with him, for he sent to an early grave one of Napoleon’s most famous Generals—Hoche. Historians had bowed before his ravages; Green died at 46 dictating the end of his English History from his death-bed, and Smollett fell before him. Novelists had succumbed to his blows, two of the Brontes and Robert Louis Stevenson being amongst his victims. Litterateurs such as Thoreau, John Addington Symonds, and Heinrich Heine fell in the unequal contest with him. Wits like Artemus Ward and Tom Hood made the world laugh while they were dying from his assaults, nor must they forget the wisdom, so akin to wit, of A4sop, nor the wit, so akin to wisdom, of our own Mr. Punch—the modern Punchinello. Finally, it was the tubercle bacillus that drove Cecil John Rhodes to seek for health in South Afriea, and, incidentally, to lay the foundations of an empire. Noseriousattempt had yet been made to assess the influence of disease on intellectual workmanship. The tubercle bacillus undoubtedly had ou more than one occasion altered the course of destiny—had been, indeed, destiny itself. Questions were asked and answered, and at the close a vote of thanks was heartily accorded Dr. Trimble, on the proposition of Professor Symmers, who expressed the hope that the doctor would give an address in the near future on the work upon which he was engaged in Belfast. ANNUAL MEETING. SESSION 1918—1919 Held in the Museum, College Square North, on Tuesday evening, 11th November, 1919, at eight o'clock. On the motion of Mr. H. C. Lawlor, the chair was taken by Professor Gregg Wilson. The Chairman referred in feeling terms to the death of Mr. John Horner. On the motion of the Chairman, seconded by Councillor Henry Riddell, the following resolution was passed in silence :— “That this Annual Meeting record its sense of the great loss the Society has sustained by the death of Mr. John Horner, which took place on the 25th November, 1919. Mr. Horner was an active member since the year 1887, and took a keen interest in all that pertained to the welfare of the Society. He served as Honorary Treasurer from 1904 to 1911, and at the time of his death was a Vice-President and Honorary Librarian.” The Honorary Secretary was instructed to forward a copy of this Resolution to Mrs. Horner and to convey to her the Society’s sincere sympathy in her sad bereavement. COUNCIL'S REPORT. The following report of the Council for the year was sub- mitted by the Hon. Secretary (Mr. J. M. Finnegan) and adopted :— The Council of the Society desires to submit its report of the working of the Society during the past session. Six ordinary meetings have been held, and it is glad to say that the lecture 74 Annual Meeting. on each occasion was well attended. The list of the lectures and lecturers is as follows :— 1918. Ist. Nov. 12th. — “Irish Woods and Forests.” By Professor Henry, M.A., Professor of Forestry, Royal College of Science, Dublin. 2nd. Dec. 10th. ‘A War Memorial for Belfast.” By Mr. Alec Wilson, M.R.LA. 1919. OrGe eam bathe “Frontiers of France.” By Professor Grenville A. Cole, F.R.S., of the Royal College of Science, Dublin. 4th. Feb. 25th. “The Story of Porcelain.” By Mr. Charles EK. White. 5th. March 11th. Trees: the character, structure, and properties of wood. By Mr. Arthur Deane, Curator Municipal Art Gallery and Museum, Belfast. 6th. April 8th. “The Romance of Tuberculosis.” By Dr. Andrew Trimble, D.P.H., J.P., Chief Tuberculosis Officer, Belfast. All the lectures were well illustrated by lantern slides, and, in some instances, further illustration was obtained from specimens. PROCEEDINGS. A new departure has been made in regard to papers intended for publication : instead of waiting until the end of the session and printing in the Proceedings, papers intended for publication are sent to the printers as soon as possible after the lectures have been given, in order that printed copies may be put into the hands of members at an earlier date. The Council hope, that in future, all lecturers will assist in this new arrangement by Annual Meeting. 15 handing their papers to the Hon. Secretary without delay, so that they may be submitted to the Publication Sub-Commmittee at once. A certain number of the printed papers will be hound as Transactions for distribution. ARCHAEOLOGICAL SECTION. The Archaeological Section which was formed during the session 1917-18 under the chairmanship of Sir Charles Brett, appears to justify its existence. A separate report of its activities will be submitted to the Sectional Annual Meeting by the Hon. Secretary of the Section, Mr. H. C. Lawlor, during the present month. (See pp. 77—86.) Hon. SECRETARY’S RESIGNATION. Your Council is sorry to have to report that Mr. J. M. Finnegan, B.A., B.Sc., who has served the Society as Hon. Sec. since 1912, has resigned, and that Mr. J. W. Storey, B.A., who has acted as Assistant Secretary, has also resigned, having been appointed as Secretary in Ireland of the National Society for the Prevention of Cruelty to Children. Your Council has already recorded on the minutes its thanks to these gentlemen for their services. Hon. TREASURER’S STATEMENT. Mr. Riddell, the Hon. Treasurer, will submit his Statement of Accounts. He has had some heavy expenditure to meet owing to the appearance of dry-rot and insect attack in the upper part of the building. Your Council feels that as long as Mr. Riddell continues to be Hon. Treasurer the financial interests of the Society will be carefully watched, 76 Annual Meeting. EXCHANGES. Your Council continues to receive publications from leading Institutions and Societies in exchange for this Society’s Proceedings, many of those received being of great importance. A list appears on pages 89 to 91. CouNCcIL’s THANKS. The Council wish to place on record its thanks to the Press for the full reports of the Society’s work from time to time. The Council’s thanks are also due to the Lecturers for their assistance during the session. ELECTION. Three members of the Council retire from office, all of whom are eligible for re-election, and the meeting will be asked to fill the vacancies, as well as that caused by the lamented death of Mr. Horner already referred to by the President. TREASURER’S STATEMENT. Mr. Henry Riddell, Hon. Treasurer, presented the financial statement, which showed a reduction of £86 in the adverse balance, not including £21 deposited with the Treasurer by the Archaeological Section. He thought that in the present year they would be able to wipe out completely their debt, and urged upon all members to make an effort to increase the membership under the new subscription scheme. ELECTION OF COUNCIL FOR 1919-1920. Moved by Couucillor Henry Riddell, seconded by Mr. J. M. Finnegan :— Resolved ;—That the three retiring members of the Council, Annual Meeting. 77 namely, Sir John Byers, Dr. Allworthy, and Mr. William Faren, be re-elected, and that the names of Sir Charles Brett and Mr. Arthur Deane be added to the list. Subsequently a meeting of the new Council was held, to elect officers for the ensuing year. These, together with the new Council, will be found on page 92. ARCHAEOLOGICAL SECTION. ANNUAL MEETING. The third General Meeting of the Section was held in the Museum on Wednesday, November 26th, at 3-30 p.m. In the unavoidable absence of the Chairman, Sir Charles Brett, the chair was occupied by Mr. R. M. Young, M.A., M.R.I.A. The Hon. Treasurer (Councillor Henry Riddell. M.E.), re- ported that at the close of the session he had funds in hand amounting to almost £64 ; about £6 was due to be paid, and the subscriptions due for the new session and subsidy from the parent society would bring the amount available for the work of the Section during the coming session to about £90. The Hon. Secretary of the Section (Mr. H. C. Lawlor, M.R.I.A.) reported that from various causes three members of the Section had resigned, and one, the late and much lamented Mr. John Horner, had died; four new members had _ joined, leaving the membership of the Section at 69. He expressed regret that during the past session a more general interest in the objects of the Archaeological Section had not been shown, and that no applications for grants in aid of research had been made by members or others since last meeting. He read an account of the investigation of the crannog at Ballygolan (adjoining the Bellevue Gardens, Antrim Road, Belfast), and of some megalithic monuments in the sandhills at Portrush. (For details see pp. 71—86.) Mr. W. A, Green exhibited some interesting pottery frag- 78 Annual Meeting. ments, bones, and rude flint implements found by him in a newly discovered sandhill settlement at Portrush. The office-bearers for the new session were elected as follows :— Chairman, Sir Charles Brett. Hon. Treasurer, Mr. Henry Riddell, M.E., M.I.M.E. Hon. Secretary. Mr. Henry C. Lawlor, M.R.I.A. Executive Committee, in addition to the foregoing (ex- officio) Professor Gregg Wilson, D.Sc., Mr. Arthur Deane ; (elected) Mr. R. S. Lepper, M.A., F.R.Hist. Soc, Mr. Alec Wilson, J.P., M.R.LA., Mr. W. B. Burrowes, Mr. T. Edens Osborne, Mr. John seein the Rev. William Adams, He Mr. Fergus Greeves, Mr. Robert May. The Hon. Secretary of the Section, Mr. H. C. Lawlor, read the following reports :— I.—INVESTIGATION OF CRANNOG IN THE TOWNLAND OF BALLYGOLAN. At the extreme north-west corner of the townland of Ballygolan (the place of the forked streamlet) is a saucer shaped, somewhat marshy hollow in which rises a prolific spring. A channel cut to carry away the water from the spring has drained the hollow where once was a deep lake. A natural ridge of eravel soil retained the water of the lake on its eastern side, while on its western side the steep slopes of the Cavehill and Colin Ward begin to rise. The farm in which the site of this ancient lake is situated is now known as Hazelwood and is bounded on its eastern side by the Antrim Road and on its northern side by the Bellevue Gardens. A little to the east of the centre of the hollow is a circular knoll some four feet higher than the surrounding ground, seventy across at its base, sixty at the summit. -The knoll is flat topped, and no foss or vallum surround it as in the great majority of raths, Wid LN ‘oy “NW IOSAIIVG dv SONNYYD JO NOILISG aft Sh 31vIS wey: fA AL 7S “es DBT Gas e 7 = Lo Lo W/V y 7 ; 7s (2 gs dd 77 " 4 oh ’ Le HX SGT AUF | C=, A sr ; ep FY REX Wy ELS Ws yon fii” SARIN Va Ne Ys / oy ¢ WINS PLAN NEF? LP APILA UA gl Y/ Tet 4 2 Si poy Y is J hth = hs : a i aS fe Mr, - UD f= 2 : - ayy =: ; q g 5 WA Ma ZAP % zs ln KUTLESS, Z ! a eed MOY VLTTIN! ~ t LS NLL PRN PDN IRATE Tr mS» / L ri 1, bide Ya Sy pom 2 wf) Vy Wf y n “Hi / Ze Lj (tig y Uy / Z ty yf Z Ls Ls Y Y GY LM) i Wy CZ “Lig Wy YY We elites) Y, pa ats Bo aaa Cones Rate OPEL) Y BOS AP ra) 20 pie een Le cae BOER ite . on pee . OME at je) WY Wy MALY NV, Wy eis Lp MW} oa pr fil GE Ty at “S341G HivwaH O3SS0cWINaaGNS 80 Annual Meeting. The present proprietor of Hazelwood—Mr. Read, readily gave his consent to the investigation of the mound, which was carried out during Easter week of this year. I had the assistance of five men the first day and three the two following days. We decided first to search for the remains of a refuse deposit or kitchen midden outside the mound, and with this object in view dug a deep trench round the base of the mound, examining carefully all the soil thrown out. It is of ordinary peat. At a depth of six feet we had to suspend operations in this direction owing to the inflow of water, but we probed down the soft bottom of the trench with crowbars, and found that the peat extended down at least four feet further, so that the growth of peat is not less than, and probably more than, ten feet. In probing we did not come to hard till, so that the original depth of the lake was not ascertained. The section of the trench showed that the mound had been built after the usual manner of early lake dwellings. Asa foundation, large logs and branches of trees were laid down, weighted down by stones and soil. When the pile had been thus raised above the water level, it became a habitable island. The timber branches upon which the crannog was built are quite rotten and of a soft sponge like texture : they consisted of hazel, birch, oak and fir. I saw no sign of upright stakes surrounding the mound as are usually found in lake dwellings; the branches and logs on which the island was built seem to have been thrown down horizontally in haphazard fashion. In the circular trench we found no remains of implements or utensils ; as we could not dig deeper than six feet on account of the inflow of water, we filled in the trench and re-sodded it. We next proceeded to cut sectional trenches and pits in the mound itself. The upper surface of the island is composed of clay soil of a depth of about three feet or more in places. Near the centre of the island we came upon three distinct hearths, one above the other, with clay intervening. It is evident these represent three periods, and that the lowest hearth represents Annual Meeting. 81 the earliest period of occupation. As the foundations of the island rotted and sank, the inhabitants found it necessary to build the island higher by adding another course of clay, with new hearths on top of the older. Ata later period, a further sinking of the foundation made another floor necessary, apparently the last one in the history of the lake dwelling. Ashes, burned fragments of wood and bones, were numerous in the immediate vicinity of the three hearths, and here and at the various places where we excavated were found a considerable number of fragments of broken pottery cooking vessels. It is worthy of remark that these pottery fragments were all found fairly near the surface, not at the level of the lowest stratum of occupation. The pottery is all of that distinct type which I have in former papers described as souterrain pottery, and not of the type usually found in crannogs. None of it showed signs of having been turned on a wheel, though some of it had thumbnail ornamentation. A few years ago Mr. F. J. Bigger made some slight excava- tions in the form of small trenches in this crannog, and found some small fragments of the same pots, which he presented to the City Museum. These and what we found are exhibited together. Mr. Bigger, in a short account of his investigation (published in the Ulster Journal of Archaeology, 2nd Series, Vol, VII, p. 195) states that he also found a “ Danes pipe” which, with the pottery fragments, he had presented to the Public Museum. The records of the City Museum show that the pottery was given, but no pipe, and [ am inclined to be sceptical about the latter. Mr. Bigger makes the extraordinary error of describing this crannog as a Dun. In our investigation we found no implements or fragments of metal of any sort, and no flints; we found a stone implement, a flat oval, measuring 53" x 44” x 2”, slightly hollowed in the centre of each face and chipped at the edges. I cannot suggest for what purpose this implement served. From conclusions arrived at in former papers in investi- 82 Annual Meeting. | gations in connection with souterrains, I think we may be safe in dating the pottery about the fifth or sixth century, and that the upper floor or stratum of the crannog is of this date; no evidence was forthcoming as to the possible age of the lower strata or of the original date of the construction of the island. Our investigations were not by any means exhaustive, and a further and more complete examination might produce interesting results. Il—SOME MEGALITHIC MONUMENTS IN THE . PORTRUSH SANDHILLS. Some years ago my friend, the late Mr W. H. Patterson, wrote me when I was staying in Portrush asking me to inspect a megalithic monument of the type usually called a Giant’s Grave, situated at a spot he described in the Sandhills, but which was not marked in the Ordnance Survey Map. I proceeded to the place indicated, but could find no trace of the object of my search. Enquiry from some of the golf green attendants, however, elucidated the reason of my want of success, When the golf course was being made some thirty years ago, the giant’s grave was found to be an impediment in laying out one of the greens, and the committee ordered its destruction. The larger stones were blasted in pieces and carted into Portrush for building purposes, and the smaller ones covered over to level up the surface of the green. My informant told me he had been one of the men employed to carry out the work. I reported the matter to Mr. Patterson, who replied saying that fortunately he had preserved a carefully made plan, drawn to scale, of the grave as it was when he visited it many years before. He sent me the plan with a pencil sketch, asking me to lay them before this society to be recorded, if possible, in one of our publi- cations. I now have pleasure in placing Mr. Patterson’s plan and sketch before the archaeological section in the hope that his request may be acceeded to. (Sketch No. 1). \ i\Y\ QN \ WS Sy PLAN of Meeauituic Monument in Portrusn Sanponis, Co. Antrim. « N° 1) THe LATE W.H. Patterson. MRA. Sy FROM ROvCHnH SKETCH MADE 84 Annual Meeting. As accurately as I can ascertain the position of the grave on the ordnance map, it should have been placed at a point 13° W.N.W. of the letter B in the name of the townland of Bally- craig Lower, on sheet No. 6, County Antrim. Last summer, when again visiting Portrush, I was pointed out by a resident, Mr. Gaston, of The Warren House, another somewhat similar though smaller monument at a point on the map approximately 24” north of the second A in the same townland name. The stones of which I show aroughly measured plan (No. 2) are in a low lying part of the sandhills on a grass covered knoll about 3 feet higher than the immediately surround- ing ground. With one exception the stones, of which there were 18, did not present any notable features, being ordinary basalt field stones of no great size; the one exception being an elongated rough pillar stone, in one side of which is a round cup-shaped hole about two inches across and 14” deep. I could not decide if this hole was artificial or the work of nature. With the aid of three men, Mr. Gaston and I made con- siderable excavations in the knoll. We found that its foundation rested on an old raised beach of white limestone gravel, into which we penetrated some depth. Atno point in our excavations did we find any trace of burned wood, bones or other remains which would indicate that the knoll had ever been used either as a place of burial or human occupation. With our knowledge of the shifting nature of sand in these hills, it seems most extraordinary that the stones were all at the surface, none being entirely buried. ‘This fact would seem to suggest that the stones could not have lain there for the number of years usually attributed to monuments of the type to which this one has the appearance of belonging. While not prepared to assert positively that the stones are, or are not the remains of a monument of great antiquity, as they are locally regarded, I think it right to suggest that they may have been placed there in comparatively modern times as a base Pian or Mecautuic Monument S ANOWILLS , SCALE Kea 147. in Poatrusy Co. AnTRIN’. (wea) 86 Annual Meeting. on which to lay boards or branches of trees on which one or more hay stacks might have been piled. Ata point, which on the map would be approximately one inch north of the letter J in the same townland name of Ballycraig Lower, I found on an eminence on the east bank of a small stream which flows and eventually sinks into the sandhills, another knoll through the surface of which appear the tops of several apparently large stones. With the negative results of the foregoing investigation in mind, I did not feel warranted in making excavations on the spot, but I wish to take the present opportunity of placing on record the existence of these three monuments of antiquity in case others should like to pursue their examination more fully. oo+tr0 0000 gr 6 gr 6 Tee © 0% Il Fe ° ge oa or 11 S61% °° nooott MODHM +A H 6161 ‘19q0190 jo Avp y16 7oPAy NN AI VV "109.1109 SI JUNODDW SUIOS910} ayy ywyI Ajtq199 T Hw MOWDHOMNO ‘ e SalIejJoIo9Sg JULISISSY “HAD aAVHOSIG ap) ‘op ‘suoidiiosqng Surjsa][o9 ** "929 ‘sasImeig Jo souvuajuivyyy ‘* 6161 Ysnsny jo € L ol€¥ ‘TeI0T, yuLg 0} ysaraquy took sasuedx@ Uones10[dxq ae) suvday sey 2ey PNY yoog enbayd ‘O29 ‘SUIOJUe'T I QI gg oe s9injoa'T Jo sasuedxy —: 714 ‘sjuawAeg 1ayj0o Ag ‘* ¢ aSvlliey pur ssxysog ‘ JUuaWasIyIaApy ‘‘ Arsuoneyg puy sunuug ‘ 0} SODUBMO][YW—Seejes ‘ SOxey, pue sajeyy “uayy ** fe) om yunosoy 4svy Jed sv sonejeg Aq ‘6161 ‘aunt 410g Papua sad ay] {JaJ90S peojydosojiyd puke AsOjsip] [einer Iselag 88F Avp 4siz “4200 Suyunooy “TTAACIN AUNHH “40UdI20D) “ONOOA “W LYAIOU "WUTODDW 90.1) v ST 9AOQE 91 IwYy Ayrq199 aM “Iq ‘soueleg 19N ** 9So[9 Joqje UMLIp SanbayD pypPy aso[o 1alye syusUISpo'T ssa7T 616r ‘ounf yf ‘yoog yueg 10d ‘sourleg 6x61 ‘Ajnf ysx€ uo JUNODDW IsuleSe souvpeq Lb-gc61 ‘uvo'T 18 \\ "]U99 jad S 4S YIOA Semmjuaqaq “jueo sed «F “SSHILTANOUS AO LSIT we ae ve oe ‘og Sutuutdg xvi q sjuoy ‘ spuepiarq ‘ suoidiiosqng oy, “HOUVHO AOI oy} JO SsJunoD9y 1G aud, 'S88I ‘SLOV (GNV1Eal) SLNAWMOGNA TYNOLLVONGA OLF OL 9 GLF e9 ° Ayjel00g yueIeg Jo spunj Ul soured ‘ce "* WOO’ SuIZ@eT JO JUS 2 ' ‘oy Buquiig ‘09 7 psog ‘ousey Ome: oe yoog eqnuryyy O10" Za Ayowog quereg woaz Apisqug ve peg pur durqzg reqqny 0 LEO -. °° qunooov s,1vah 4Se] oa (Ne oe aeyF qIpne saved OM, Oe fe alba +f " suoiqdriiosqng—6I6l “ Ow “y “soap ‘sdure4g OL ZL BF © Aqoroog jworydosopiyg pwe £10481 Hf SF GL-SIGI PU® SI-LIGI SUOM2TTOD Jo JSOO—GIGT ‘ouns TeINyeN ASBjfog Jo spuny ur sourpeg—si6l ‘ounce ‘NOILOAS IVOIDOTOAVHDYUV ‘olor ‘y30e ANAL OL LNNODDV AANLIGNAdXH ANV HWOONI ‘MOJJ[OJ MOU YOIYM JOJ JUNOIIE 91B1eda|S ‘UOTJIIG [BIIFZOJOIaeYIIY BY} JO Sasuadxa puw SUOIJGIJOSQNS 9YyJ Sapnjoul j] “psvOg JUSWIUIIAOD [89077 ay} Aq pagiioseid Wao} ay} UI SI ased Surpaceid uo uaals AJII90S [eoydosoyjyd puv A1O}SI] [BINJeA] JSBJJ9G FY} JO JuNOIIR SY] EXCHANGES. AUCKLAND—Annual Report of the Auckland Institute and Museum. 1918-19. BARCELONA—Publications of Barcelona Museum. BELFAST—Proceedings of the Belfast Naturalists’ Field Club. 1948-19. BERGEN (NorwaAy)—Publications of the Bergen Museum. BIRMINGHAM—Proceedings of the Birmingham Natural History and Philosophical Society. 1918. BrighHTtoN—Annual Report of the Brighton and Hove Natural History and Philosophical Society. 1918. CatcutraA—Bibliography of Indian Geology. Part I and II. Records of the Geological Survey of India. Report of the Progress of Agriculture in India. 1917-18. Campripur (U.S.A.)—Bulletin of the Cambridge Museum of Comparative Zoology. CAMBRIDGE— Proceedings of the Cambridge Philosophical Society. EDINBURGH—Proceedings of the Royal Society of Edinburgh. 1917-18. Transactions and Proceedings of the Botanical Society of Edinburgh. %) ” ” # Notes from the Royal Botanic Gardens, Hdinburgh. Essex—tThe Essex Naturalist. Vols. VIIJ.—XIX. Haimrax—Proceedings and Transactions of the Nova Scotian Institute of Science. INDIANA—-Proceedings of the Indiana Academy of Sciences, 1916-17. Lima (PERU)—Boletin del Cuerpo de de Ingenieros de Minas del Peru. LonpoN—British Museum, Economic Publications, 90 EHxchanges. LoNDON—Quarterly Journal of the Royal Microscopic Society. He Memoirs of the Royal Astronomical Society. e; Quarterly Journal of the Geological Society. i Report of the British Association. 1918. LOoUSANNE—Bulletin de la Societe Vaudoise des Sciences Naturelles. MASSACHUSETTS—Bulletin of the Museum of Comparative Zoology. MELBOURNE—Proceedings of the Royal Society of Victoria. Mextco—Anales del Instituto Geologico de Mexico. New Haven—Transactions of the Connecticut Academy of Art and Sciences. 1917. New OrLEANS—Sixth Biennial Report of the Board of Curators of the Louisiana State Museum. 1917-18. New YorK—The Geographical Review. Monthly. NotrrincGHAM—Annual Reports, Nottingham Naturalists’ Society, 1913-1918. Oxn10— Bibliographical Contributions from the Lloyd Library. . The Ohio Journal of Science. Orrawa—Memoirs of the Canadian Geological Survey. Memoirs of the Geological Survey of Canada, De- partment of Mines. PHILADELPHIA— Proceedings of the Academy of Natural Sciences of Philadelphia. A Proceedings of the American Philosophical Society. Pusa (InprA)—Scientific Reports of the Agricultural Research Institute. 1916-17. Rio de JANEIRO—Report of the National Museum of Brazil. SAN FRANcISCO—Proceedings of the California Academy of Science. STAVANGER (Norway)—Report of the Stavanger Museum. 1917. STIRLING—-Transactions of the Stirling Natural History and Archaeological Society. 1914-1919. St. Lours—Public Library Monthly Bulletin, be) Exchanges. 91 St. LEoNARDS—Report of the Hastings and St. Leonards Natural History Society. 1917-18. Torquay—Journal of Torquay Natural History Society. TorRoNTO—Transactions of the Royal Canadian Institute. UpsALA—Bulletin of the Geological Institution of Upsala University. W ASHINGTON—Annual Report of the Smithsonian Institution. Annual Report of the United States National Museum. Bulletins of the Bureau of American Ethnology. Bulletins of the Smithsonian Institution. Contributions from the United States National Herbarium. Proceedings of the United States National Museum. Smithsonian Institution Miscellaneous Collections. Year Book of the United States Department of Agriculture. 1918. 92 BELFAST NATURAL HISTORY AND PHILOSOPHICAL SCGLzike Officer's and Council of Management for 1919-20. President : Pror. GREGG WILSON, m.a., D.Sc., PH.D., M.R.LA. Vice=Presidents : Sir CHARLES BRETT. ALDERMAN 8. W. ALLWORTHY, M.4., M.D.,. F.G.S. PROF. JAMES A. LINDSAY, m.a., F.R.c.P. ROBERT M. YOUNG, M.a., M.R.1.A., J.P. J. M. FINNEGAN, B.A., B.Sc. WILLIAM SWANSTON, rf.«.s. bon. Treasurer: CounciLtoR HENRY RIDDELL, M.f£., M.1.M.E. fbon. Librarian : ROBERT M. YOUNG, M.A., M.B.1.A., J.P. on. Secretary : ARTHUR DEANE. Council : W. B. BURROWKES. E. J. ELLIOTT. H. C. LAWLOR, m.R.1.A. WILLIAM SWANSTON, r.a.s. ProFESSOR GREGG WILSON, p.sc., M.R.1.4. JOHN M. FINNEGAN, B.A., B.Sc. Prorsssor J. A. LINDSAY, M.a., F.R.0.P. CouncILLoR HENRY RIDDELL, m.£., M.1.M.2. ROBERT M. YOUNG, M.A., M.R.1.A. Proressor W. ST. CLAIR SYMMERS, m.s. Str CHARLES BRETT. Sir JOHN BYERS, m.A., M.D., M.A.O. ALDERMAN 8. W. ALLWORTHY, m.a., M.D., F.C.8. WILLIAM FAREN. ARTHUR DEANE. : | | Retire 1920. Retire 1921 Retire 1922. 93 SHAREHOLDERS AND MEMBERS. [* Denotes Holders of three or more Shares. | la sf Members of Archaeological Section. | aAcheson, F. W., Cloneevin, Dundalk aAdams, Rev. Wm. A., The Manse, Antrim. * Alexander, Francis, B.£., Belfast Alderdice, W. W., 9 Malone Park, do. Allworthy, S. W., m.p., Manor House, Antrim Road, do. * Anderson, John, J.P., F.G.S. (Representatives of), Holywood, Co. Down aAnderson, Frank, Tavanagh Weaving Company, Ltd., Portadown aAndrews, M. C., F.R.G.S., F.R.8.G.8., 17 University Square, Belfast aArmstrong, E. C. R., M.R.1.4., National Museum, Dublin Andrew, John J., L.D.S., R.¢.S.Eng., 23 University Square, Belfast aAndrews, Miss Elizabeth, 12 College Gardens, do. Armstrong, William, Thronemount, do. aAtkinson, Arthur S., Dromana, Knockdene Park, do. Baird, Major William, Royal Avenue, do. Bigger, Francis J., M.R.1.A., Ardrigh, Antrim Road, do. aBlackwood, W. B., Ebony Grange, Deramore ParkS., do. aBlake, R. F., F.1.c., 4 Knock Road, do. Boyd, Thornton, Blackstaff Spinning Company, do. *Boyd, J. St. Clair, M.D. (Representatives of), do. Boyd, John, San Remo, Holland Park, Neill’s Hill, do. Brandon, H. B., J.p., Rosemount House, Antrim Road, do. aBrett, Sir Charles H., Gretton Villa, South, Malone Road, do. aBrett, Rev. Canon, M.A., Montrose, Fortwilliam Park, do. aBristow, James R., M.A., Prospect, Dunmurry Bristow, John, 9 Wellington Place, Belfast aBurrowes, W. B., Ballynafeigh House, Ravenhill Road, do. Byers, Prof. Sir John W., M.A., M.D., Lower Crescent, do. *Brown, George B., Lisnamaul, Ormeau Road, do, 94 Shareholders and Members Campbell, A. A., Drumnaferrie, Rosetta Park, Belfast *Campbell, Miss Anna (Representatives of), do. Campbell, John, Innishowen, Donegall Park, do. aCarmody, Rev. Canon, M.A., The Rectory, Lisburn Carr, A. H. R., 224 Donegall Place, Belfast aCarter, C. S., 29 Cedar Avenue, do. aCarter, H. R., 19 Mountcharles, do. *Charley, Phineas H., Mornington Park, Bangor, Co. Down *Christen, Mrs. Rodolphe, St. Imier, Brig of Cairn, Ballater, N.B. Clark, Sir George S., Bart., D.u., Dunlambert, Belfast Clarke, E. H., Notting Hill, do. Crawford, Sir William, J.p., Mount Randall do. Corbett, Miss K. M., Ardsallagh, Derryvolgie Avenue, do. Combe, Barbour & Co., Ltd., do. aCunningham, Right Hon. S., Fern Hill, Ballygomartin Road, do. Davies, A. C., Lenaderg House, Banbridge, Co. Down aDeane, Arthur, Municpal Art Gallery and Museum, Royal Avenue Belfast *Deramore, Lord, D.L. Dixon, Professor, M.A., SC.D., F.R.S., St. Ives, Bladon Drive, Belfast *Donegall, Marquis of (Representatives of), do. *Downshire, Marquis of, The Castle, Hillsborough, Co. Down Duffin, Adam, LL.D., J.p., Dunowen, Cliftonville, Belfast Dunleath, Lord, Ballywalter Park, Ballywalter, Co. Down Ewart, G. Herbert, M.A., J.p., Firmount, Antrim Road, Belfast Ewart, Fred W., M.A., B.L., Derryvolgie, Lisburn Ewart, Sir Win. Quartus, Bart., M.A., J.P., D.L. (Representatives of), Glenmachan House, Belfast Elhott, E. J.. The Towers, Donegall Park Avenue, do. aFaren, William, 454 Waring Street, do. Shareholders and Members 95 *Fenton, Francis G., Paris aFerguson, G. W., 6.E., J.P., Carnamenagh, Antrim Road, Belfast Finlay, Fred W., Mrs., Wolfhill House, Ligoniel, Belfast Finlay, Robert H. F., 66 Eglantine Avenue, do. Finnegan, John M., B.A., B.SC., 23 Botanic Avenue, do. aFrazer, Kenneth W., Hillmount, Cullybackey Fulton, G. F., Arlington, Windsor Avenue, Belfast Gamble, James, Broadway Damask Co., Ltd., do. *Getty, Edmund (Representatives of), do. Gibson, Andrew, F.R.S.A.1., Fairfield, Lansdowne Road, do. Gibson, W. K., 16 Chichester Street, do. Gordon, Malcolm, Dunarnon, University Road, do. aGreen, W. A., 4 Salisbury Avenue, do. aGreeves, F. M., Garranard, Strandtown aGreeves, Joseph M., Bernagh, Circular Road, do. aGreeves, Arthur, Altona, do. aGreeves, John Theo., Nendrum, Knock aGreeves, W. Leopold, Rockfield, Dundonald *Hall, Frederick H., Waterford Hamilton, Rev. Thomas; D.D., LuL.D., Vice-Chancellor, Queen’s University, Belfast *Hamilton, Hill, J.P. (Representatives of), do. Harland, Capt. W.. 38 Chester Ter., Chester Sq., London, S.W. aHenry, Professor R. M., M.A., M.R.1.A., Crosshill, Windsor Avenue North, Belfast aHenry, T. W., Greenbank, Mountpleasant, do. Herdman, E. C., Carricklee House, Strakane Herdman, F. S., Antrim Road, Belfast. *Herdman, Robert Ernest, J.P., Merrouhurst, Craigavad, Co. Down aHewton, John, M.P.s.1., Ava Buildings, 315 Ormeau Rd., Belfast Heyn, James A. M., Head Line Buildings, do. aHill, Dr., 46 Pound Street, Larne 96 Shareholders and Members Hind, John, jun., 22 Cliftonville Road, Belfast aHyde, James J., 36 Bedford Street, do. aHogg, A. R., 10 Thorndale Avenue, do. Hodges, Miss, 12 Trebovir Road, Earlscourt, London, 8.W., 5 Horner, John (Representatives of), Drum-na-Coll, Antrim Road, Belfast *Houston, John Blakiston, D.L., J.P., Orangefield, do. *Hnghes, Edwin (Representatives of), Craigavad, Co. Down Hunter, William, J.P., Fortwilliam Villas, Belfast Jaffe, Sir Otto, J.p., LL.D., Kin Edar, Strandtown, do. aJaffe, W., 10 Donegall Square South, do. Johnston, Samuel A., J.p., Dalriada, Whiteabbey, Co. Antrim aJury, P. M., Brooklands, Dunmurry *Kinghan, John R,, Windsor Avenue (Representatives of), Belfast Kyle, Robert Alexander, 15 Wellington Park, do. Laird, Professor J., 4 Cranmore Gardens, do. Larmor, Sir Joseph, M.A., D.SC., LL.D., F.R.A.S., SEC. R.S., St. John’s College, Cambridge aLawlor, H. C., M.R.1.4., 8 Windsor Avenue, Belfast aLepper, R. S., M.A., F.R.AIST.S., Elsinore, Carnalea, Co. Down aLett, Rev. Canon, M.R.1.A., Aghaderg Glebe, Lough- brickland, do. Lindsay, Professor James A., M.A., M.D., Queen’s Elms, Belfast aLindsay, W. A., M.p., Tyrone House, do. aLoewenthal, John, Lennoxvale, Malone Road, do. *Macrory, A. J. (Representatives of), do. Magill, John E., Eversley, Whitehead aMackie, James, J.P., Hazelbank, . Whitehouse Malcolm, Bowman, M.1.C.E., M.1.M.E., Inver, Ashley Park, Antrim Road, Belfast Maxton, James, M.I.N.A., M.I.MAR.E., 6 Kirkliston Drive, Bloomfield, do, Shareholders and Members 97 aMay, Robert, 40 Hopefield Avenue, Belfast Mayes, William, 12 Deramore Park South, do. Metcalfe, A. W., Hawthornden House, Hawthornden Rd. do. Milligan, A., 4 Cooke Street, do. Mitchell, Robert A., LL.B., T.c.D., Marmount, Strandtown, do. aMontgomery, Miss E., 26 College Green, do. aMontgomery, H. C., Ballyholme House, Bangor, Co. Down aMontgomery, H. H., 17 Malone Park, Belfast Moore, James, J.P., Finaghy House, Dunmurry Morton, Professor W. B., M.A., Glencarse, Nottinghill, Belfast Muir, A. H., 7 Donegall Square West, do. Mullan, William, Lindisfarne, Marlborough Park, do. *Murphy, Isaac James (Representatives of), Armagh *Murphy, Joseph John (Representatives of), Belfast *Musgrave, Henry, D.L., Drumelass, Malone, do. aMacalister, Professor, R.A.S., D.LITT., M.A., 18 Mount Eden Road, Donnybrook, Dublin McBride, A. H., Ormeau Avenue, Belfast *McCalmont, Robert (Representatives of), London *McCammon, Thos. P. (Representatives of), Plaisted, Woodville, Holywood, County Down. aMcCoy, B., 84 Smithfield Belfast MacColl, Hector, 4 Kirkliston Drive, Bloomfield, do. *McCracken, Francis (Representatives of), aMacready, H. L., 104 Myrtlefield Park, do. aMcGowan, Thomas, 73 Ann Street, Belfast Macllwaine, Dr. John E., 26 College Gardens, do. McKisack, H. L., M.p., Chlorine Place, do. *MacLaine, Alexander, J.P., Queen’s Elms (Representatives of), do. McLaughlin, W. H., D.L., J.P., Macedon, Belfast MacKenzie, Dr. W. G., 6 University Square, do. aMcMeekin, Adam, J.P., Cogry House, Doagh McNeill, George, 12 Deramore Park, Belfast *O’Rorke, Mrs., Tudor Park, Holywood, County Down 98 Shareholders and M. embers Orr, Hugh L., 17 Garfield Street (Representatives of), Belfast aQOsborne, T. Edens, Wellington Place, do. Patterson, Edward Ferrar, 17 Talbot Street, do. Patterson, Mrs. David C., Glenard, Holywood, County Down Patterson, John F., 2 Mountcharles, Belfast Patterson, Robert, M.R.1.A., F.Z.S., M.B.0.U., Glenbank, Holywood Patterson, William H. F., Auburn, Warren Road, Donaghadee Pim, E. W. (the late), Ivy Lodge, Knockbreda Park, Belfast aRiddell, Henry, M.E., M.I.M.E., 64 Great Victoria Street, do. aRoden, Countess of, Tullymore Park, Newcastle, County Down Sefton, Burton, 20 Bedford Street, Belfast Sinclair, Prof. Thomas, M.D., F.R.¢.S., Eng., University Sq , do. aSinclair, Thomas, J.P., Castle Lane, do. Sinclair, John, Mount Donard, Windsor Park, do. aSkillen, Joseph, The Lisnagarvey Linen Co., Lisburn Steen, William, B.L., Roseberry, Marlborough Park, Belfast aStevenson, John, Coolavon, Malone Road, do. Stirling, James H., Ardanreagh, Windsor Avenue, do. aSteel, Samuel, Millbrook, Larne aStendall, Sidney, Museum, College Square North, Belfast Stelfox, Arthur W., A.R.1.B.4., Ballymagee, Bangor, Co. Down Swanston, William, F.G.s., Farm Hill, Dunmurry aSymmers, Professor W. St. Clair, Queen’s University, Belfast aTaylor, James, 6 Royal Avenue - : do. *Tennent, Robert (Representative of), Rushpark, do. *Tennent, Robert James (Representative of), Rushpark, do. aThompson, Edward, Prospect Mills, _ do. Thompson, John, J.p., Mounteollyer, Malone Road, do. Torrens, Mrs. S. (c/o T. H. Torrens, Edenmore), Whiteabbey *Turnley, Francis, Drumnasole, Carnlough aWalker, Franklin M., Mount Royal,: Whitehead Shareholders and Members 99 *Webb, Richard (Representative of), Knock, Belfast aWhite, J. C., Right Hon., J.p., Lord Mayor of Belfast, Craigavad Whitla, Prof. Sir William, M.P., M.D., J.P., Lennoxvale, Belfast Wilson, Prof. Gregg, M.A., PH.D., D.SC., M.R.I.A., Queen’s Uuiversity, do. aWilson, Fergus 8., Crofton Hall, Holywood aWilson, George, 17 Bedford Street, Belfast a* Wilson, Alec., J.P., M.R.1.A., Croglin, Ballyaughlis, Co. Down *Wilson, W. Percival (Representative of), Belfast *Wolff, G. W. (Representatives of), do. Workman, Francis, The Moat, Strandtown, do. Workman, John, J.p., Lismore, Windsor Avenue do. Workman, Rev. Robert, m.A., Crusheen, Cadogan Park, do. *Workman, T. (Representative of), Workman, W., 8 Corporation Street, Belfast Wright, Joseph, F.c.s., 10 May Street, do. a*Young, Robert Magill, M.A., J.P., M.R.1.A4; Rathvarna, do. HONORARY ASSOCIATES. Foster, Nevin H., M.R.1.A., F.L.S., Hillsborough, County Down Swanston, William, F.c.s., Farm Hill, Dunmurry Wright, Joseph, F.c.s., May Street, Belfast ANNUAL SUBSCRIBERS OF TWO GUINEAS. Belfast Banking Company, Ltd., Belfast - Northern Banking Company, Ltd., do. Ulster Bank, Ltd., do. [The Hon. Secretary will be obliged by shareholders and members notifying him in the event of change of address, or those whose names are incorrectly set out. Address:—The Museum, College Square North, Belfast. | BRITISH rs KEE tTKA Mi US. UM ' ve ¥ rey VM 7 uf i i men Bs ae 5 9 ees “PROCEEDINGS, acs SESSION 1919- 1920. - Lth and 12th November, 1919. -Nowri OF IRELAND DURING THE eS CLACIAL PERIOD. RTHUR R DWERRYHOUSE, DSc, M RIA, PGS, : ee - Lectur er im Geology, aus University Belfast. ueTeATIONS | IN THE FOREIGN EXcHGES ROFESSOR F. T. LLOYD-DODD, M.A, D.So. — of Commer ce Depar ie Municipal Technical Institute, Belfast. . .* me \} BELFAST: Fone Proceedings of the Belfast Natural History and Philosophical Society 1919-1920 (1). 11th November, 1919. Councillor HENRY Ripper, M.E., M.I.M.E., in the Chair. THE NORTH OF IRELAND DURING THE GLACIAL PERIOD. By ARTHUR R. DwerRRyYHOUSE, D.Sc., M.R.I.A., F.G.S., Lecturer in Geology, Queen's University, Belfast. (Abstract). The subject was introduced by a description of the traces left by the passage of ice-sheets over a country. The scratches and grooves impressed upon rock surfaces were illustrated and their importance as records of the direction of movement was discussed. The deposits formed by glaciers next received attention, and these were divided into (a) Boulder Clay, an unstratified clay with striated stones, many foreign to the district in which they now rest; and (b) stratified clays, sands and gravels accumulated by the action of the running water associated with ice. ‘The Boulder Clay occurs either in sheets of irregular thickness or in slightly elongated ridges with smooth contours, such as those which are so common in County Down, and known as drumlins. The stratified clays are lake deposits formed in standing water near the ice-margin, and the sands and gravels consist of coarse materials, lying in sheets or fans, accumulated under somewhat similar conditions, or in long tortuous ridges, called Eskers, the product of streams of water flowing in tunnels in or beneath the ice. Accumulations of clay, stones and sand which are formed along the margins of an icelobe, are known as moraines and serve to indicate the limits of the ice at its maximum extension and at various stages of its retreat. The stones which are carried by the ice for long distances from the parent rock are called Erratics, and serve to indicate 2 Arthur R. Dwerryhouse on the main direction of ice flow. These are extremely plentiful over the district under consideration, and several, including the Clogh More near Rostrevor, were shown upon the screen. Attention was next directed to the effect of ice-sheets upon the ordinary drainage of the country, and it was shown that the advance of a glacier might interrupt the normal flow of rivers and cause them to form lakes, which, by their overflow, might cut channels or gorges in the rocks.. When the ice had retreated and the lakes been drained, these gorges were left as permanent records of the levels of the water, and consequently of the former position of the ice-front. In certain cases the overflow stream remained in the temporary channel after the retreat of the ice, thus producing a permanent diversion of the drainage. Examples of this were cited in the case of the Bush River and the streams in Glen Aan and Glen Dun, all in County Antrim. The lecturer then described his investigations of the glaciation of the North of Ireland and first referred to the distribution of © erratics as being the most trustworthy indication of the direction of ice movement. In every assemblage of erratics there were always some of which the origin was difficult or impossible to determine, but there were usually others with such striking characters that they could be identified readily. The most useful of these in the district under consideration were the fine-grained granite of Ailsa Craig in the Firth of Clyde, and the granites and pyroxenic rocks of an area extending from Slieve Gallion in County Tyrone to the neighbourhood of Omagh, while in the immediate neighbourhood of Belfast, the rhyolites which occur at Tardree and at several other places on the Antrim Plateau, were of considerable use. Some of the more important deposits of Glacial age and the drainage channels and lake-terraces of the district were then described and their bearing on the glaciation of the country was explained. The North of Ireland during the Glacial Period. 3 The conclusions at which the lecturer had arrived as the result of his work in the North of Ireland were as follow :— (a) The district was first glaciated by ice which came down the Firth of Clyde from the Scottish Highlands, over-rode the whole of the Counties of Antrim and Down, extended at least as far inland as the south-west corner of Lough Neagh, and passed over the Mourne and Carlingford Mountains and so into the Irish Sea. (b) At a slightly later stage ice from the mountainous regions to the west and north of Lough Neagh advanced into the lowlands bringing with it boulders of the granites and pyroxenic rocks of the Sheve Gallion area, and gradually pushing back the Scottish ice. The western ice-sheet passed south eastward across the head of the Belfast valley by way of Moira and Hillsborough, and so out to sea at Newcastle. It formed a continuous sheet away to the south-west as far as the central plain of Ireland. A portion of the western ice also flowed into Lough Neagh and thence northwards by way of the valley of the Lower Bann as far as Coleraine, but it did not reach the eastern shore of Lough Neagh except in the extreme South, being held u) by the Scottish ice, which though in retreat still occupied that part of the area in sufficient force to hold up the flow from the West. It would thus appear that the Scottish and Western ice- sheets were to some extent contemporaneous, and that no lengthy period elapsed between the two glaciations, as has been held by some geologists. The lecture was illustrated by lantern-slides, maps and relief models of the Belfast District, and the lecturer answered ‘several interesting questions put by members of the audience. The meeting terminated with a hearty vote of thanks to the lecturer. 21st November, 1919. The President, Professor GREGG WILSON, in the Chair. FLUCTUATIONS IN THE FOREIGN EXCHANGES. By Professor F. T. LLoyp-Dopp, M.A., D.Sc. Head of Commerce Department, Municipal Technical Institute, Belfast. To the ordinary individual the term “ Foreign Exchanges,” if it conveys any impression at all, merely brings to mind mystic columns of figures which appear periodically in the morning newspaper. If his curiosity is still unsatisfied, he may turn up the reference in the Encyclopaedia Britanica where it is defined as “The system by which commercial nations discharge their debt to each other.” Having read that, he feels that he knows all that is worth knowing on the subject. There is, however, a great deal more in it than that! Foreign Exchange is admittedly a complex subject, and on the surface is full of appalling pitfalls and intricacies to the unwary. Once one has delved beneath the surface, he finds it an absorbing and fascinating study. For those who have not either time or inclination to study the subject deeply, it is possible, with little difficulty, to grasp the principle on which foreign exchange is based, so as to take an intelligent interest in exchange fluctua- tions. Stated briefiy, foreign exchange is the buying and selling of the money of other countries. From our point of view, foreign exchange is the business of exchanging foreign money into English money ; and we would naturally expect that the exchange would be carried out at a fixed ratio of so many dollars or franes for a sovereign. But this is by no means the case. Money is a com- modity, and like other commodities is subject to the law of supply and demand. If there is a large supply of foreign money for sale, with a small demand, the price goes down. Ifon the other hand there is a small supply and a large demand, the price rises, 6 F. T. Lloyd-Dodd on It is necessary for us to grasp, therefore, two things—(1) the degree of intrinsic value that lies behind the currencies of different countries ; and (2) the causes of the fluctuations in the demand and supply of foreign money, which result in the fluctations of the Foreign Exchanges. With regard to the first, we find on examination that we can group the currencies of the commercial countries of the world into five classes :— . 1. Under the English system money carries the right of being immediately turned into gold. Inthe United Kingdom sovereigns are legal tender up to any amount, as are also Bank of England notes. Bank of Ireland notes are legal tender in Ireland only. Silver and copper are only token money, silver being legal tender up to 40/- and copper up to 1/-.. If a Bank of England note is presented to that Bank, it cannot meet it with another note, but must pay sovereigns against it. So that normally all the money we use, except our small change, consists either of gold or of paper that can be unquestionably turned into gold. I used the word normally because the use of Currency Notes as a temporary war measure is a deviation from the usual system. 2. In the second class we may place the currencies of the so-called gold standard countries, under which money can be converted into gold when it is convenient to the Central banks of these countries. German currency is an example of this class. In theory the notes of the Reichsbank can be turned into gold on demand. In practice they cannot except when it is convenient to Germany. In France the Bank of France can meet its notes in five frane pieces. In the United States “gold certificates ” can be turned into gold, but there is an enormous amount of American paper money which does not possess this right, while silver dollars are legal tender up to any amount. The American banks keep the gold certificates in hand as far as possible, and meet demands on them in other forms of legal tender. So that if it does not suit the convenience of American bankers to permit gold to leave the country, they can practically refuse it, and still meet their legal obligations, Fluctuations in the Foreign Exchanges. rf 3. Thirdly, there are certain countries such as India, Japan, Mexico, Brazil, and the Argentine, which have a semi-gold standard They will issue silver or paper currency against gold, but have no obligations to convert the silver or paper currency into gold on demand. Such countries usually take measures to keep the exchange value of their currency at or near the legal ratio. Thus India maintains balances in London, so that the Jovernment can supply English money, when the demand for it in India becomes so great, as to depress the purchasing power of the rupee to too great an extent. 4. Fourthly, there are the few silver standard countries of which China is the only important example, and lastly, 5. There are the few purely paper money countries where gold is simply dealt with as ordinary merchandise, and always stands at a premium. We see then that the intrinsic value behind the currencies of different countries varies considerably. Gold is the international medium of exchange—acceptable everywhere—and while the notes of a country are perfectly serviceable in that country, they are useless for international trade. It is for this reason that the gold-backing of a country’s currency has such an important influence on its foreign exchange. Having considered thus briefly the money of different countries, which is the subject matter of the Foreign Exchanges, we must now see how demand for the money of one country arises in another. A claim for money between nations arises in exactly the same way as between individuals. An individual may be regarded as exporting the services, which he renders, in his business or profession, and for which he is paid in money. He imports the food, shelter, clothing, amusements, and all the luxuries and necessaries of life which he enjoys, and pays for them by cheque or cash. At the end of the year, if he has kept careful accounts, he can see what he has received, how he has spent it, and the exact amount of his balance, or overdraft, as the case may be, i.e) F. T. Lloyd-Dodd on The matter is more complicated in the case of nations. In any individual pair of trading nations, there are at any time hundreds of individuals buying and selling commodities and services, which it is difficult to record. It is this very difficulty of tracing the exchange of goods and services which is part of the fascination of the study of foreign exchange. The most carefully compiled records of a nation’s income and expenditure always leaves a margin of what must be, at the best, estimated statistics. The monthly returns of the Board of Trade give us the figures of our exports and imports, and these figures, though as accurate as they possibly can be made, yet for various causes leave a margin of error. These figures, in hundreds of thousands, for 1913. were :— 1913. Food, Drink Raw Manufactured & Tobaeco Material Articles Imports -26) 23902 2,818 1,930 Exports OF 326 699 4,114 Taking the totals, and allowing for the re-export of foreign and colonial produce, we find that for that year our imports, which are much larger in the case of England than in that of any other country, exceeded our exports by £133,900,000. This huge excess of imports is at first sight alarming. It forms what the older economists would have called an adverse balance of trade, and in their view would indicate that the country was rapidly approaching bankruptcy. Two explanations at once present themselves. In 1913, we either received goods worth roughly 134 millions more in value than the goods we gave in exchange—the difference being clear profit—or we paid for the difference in gold. The first explanation, if true, would be very comforting, but unfortunately the other countries have not con- spired to kill us with kindness and to give us £134,000,000 worth of goods for nothing. Nor did we pay this difference in gold, for the Board of Trade returns show that we imported rather more bullion than we exported. B88 69.94) eats be ooeamiee or 1918. Imports: ... “572,71 458,9 PHO Ze! Pol iss \ . Exports... 12.1 60.8) 407 Gane ieee The contrast between the figures is striking. While our imports in 1918 are almost double the amount of those of 1913, our exports under every heading have decreased. Making allowance for the re-export of foreign and colonial produce, the net result is that while in 1913 our imports exceeded our exports by £133,9 millions, in 1918 the excess of imports was £790 millions. We saw that in 1913 the excess of imports of £1339 millions, represented interest due upon our foreign investments, Fluctuations in the Foreign Exchanges. 19 and payments for our invisible exports in the services of our ships and banks. During the war the greater part of our invest- ments have been sold, and owing to the disorganised state of international trade the return for the Banking services greatly reduced. How then are we paying for that £790 millions worth of excess of imports? A large part of it still represents payment for the services of our ships, for though the tonnage is greatly reduced, the freights are much higher. But what about the enor- mous balance still unaccounted for? Our expenditure has exceeded our income, and for a nation, as for an individual, that is a serious matter. We have sold our securities abroad, and we are now mortgaging our capital assets to pay for imports which we cannot pay in exports. Worse still, we have raised enormous sums in the United States and in neutral countries on Treasury Bills and other short-dated securities. In the case of an individual we would call them I.0.U.’s, but in National affairs the other term sounds better, though they amount to the same thing. The money raised in this way has been used by the Government to pay for the goods it has bought in the United States and elsewhere, or it has been lent to the banks which have re-lent it to importers. In short, the excess of imports has been paid for by borrowed money. We have, of course, lent large sums to our Allies and to the Dominions ; but while many of their debts to us are likely to prove “bad debts” our debts to others must be made good. In any case, we have borrowed abroad much more than we have lent, and there is a considerable balance of foreign debt against us. We have changed from the position of a Creditor nation to that of a Debtor, and it is only now when the exchanges are set free to work on normal lines that we are beginning to feel the serious effects. Up to March last the Exchanges were regulated by our Government so as to prevent them moving against us. During the war we made heavy purchases of war material and supplies from the United States and other countries, so that, on balance, we were their debtors. As a result, the foreign exchanges would move against us, and so, to prevent this the exchanges 20 F.T. Lloyd-Dodd on Fluctuations in the Foreign Exchanges. were artifically supported. Several agencies were employed for this purpose. 1. Imports were restricted—partly it is true from shortage of tonnage—but also to reduce the amount owing by us to other countries. 2. Exports were encouraged in order to increase the amount owing to us. As this did not prove sufficient, the next step was 3. To raise loans abroad. At first sight it seems strange that when the exchange is going against us and because we are debtors, we try to remedy it by getting further into debt. But when we floated a loan, say in the United States, the U.S. became our debtor until the loan had been paid over, and in this way the balance was temporarily put in our favour. 4. Lastly the Government took over large amounts of foreign securities owned and held in this country, and employed them to create credits abroad, thus lessening the balance of indebtedness. By these means the exchanges were prevented from moving too much against us during the war. But in March last this regulation came to an end, and we are now beginning to see where we stand. ‘The position is a serious one. We are in the same case as an individual living beyond his income, and the remedy is the same—Spend less and earn more. We are a debtor nation and no juggling with figures can alter the fact. The situation is so grave that it calls for all-round sacrifice. It calls upon us for a rigid reduction of consumption, especially of luxuries, thus setting goods and labour free for the export trade. It calls on us to go on saving every penny, and thus to cheapen the supply of capital needed for industry ; and it calls on everyone engaged industrially to increase production to the last ounce in his power and thus make a direct-contribution to the liberation of the nation from its load of debt. Professor Meredith, Queen’s University; Mr. R. G. Geale, the City Accountant; and Mr. A. H. Muir spoke to the lecture, and the proceedings concluded with a vote of thanks to the lecturer, AND HILOSOPHICAL. SOCIETY. PROCEEDINGS, SESSION 1919- 1920. No. 2. 11th December, 1919, and 10th February, 1920. , BY me ‘KILLEN MACBETH, .M. A.D. Sc, FLC, M.R.LA. BELFAST: iN BOYD & SON, LTD., 2. CORPORATION STREET a TERS £Q! THE QUEEN'S UNIVERSITY). Proceedings of the Belfast Natural History and Philosophical Society, 1919-20. 11th December, 1919. Professor GREGG WILSON, President of the Society, in the Chair. THE DYEING OF PURPLE IN ANCIENT ISRAEL. By Rev. Isaac HeErzoca, M.A., D.Lit., Chief Rabbi of Dublin. (Abstract.) Varied as are the meanings of the term purple in modern usage, to the student of antiquity the word denotes a cloth dyed with a colouring matter furnished by certain marine snails. And the tinting of cloth by means of marine animal pigment is still practised, albeit in a crude, primitive form, by the natives of certain coasts of Central America. Our principal authorities as to the species of marine snail anciently employed in purple-dyeing are Aristotle and Pliny, but their statements leave much to be desired. Aristotle, in the fifth book of his History of Animals (chap. 15), states that it is the genus zopdipa (Purpura) which furnishes the pigment for the ' dyeing of purple. In close association with the Purpurae Aris- totle also gives some account of a genus called xijpvé (Keryx) without, however, distinctly referring to its employment in the dyeing of purple. Pliny, on the other hand, speaks of two genera utilised for the manufacture of purple, namely, Purpura and Buccinum. It is assumed by all writers on the subject, at least as far as my research has extended, that the Heryx of Aristotle and the Buccinum of Pliny are identical; but in my work on Tekelet, still awaiting publication, I have shown that there is very serious ground for questioning the identification. Modern research on this subject began with the identification by Guillaume Rondelet (d. 1556), Professor at Montpellier, . of the Purpura of Pliny with the species now termed Murex 22 Rev. Isaac Herzog on brandaris ; and the chain of inquiries has been practically continuous down to the present day. ‘To William Cole, an Englishman, belongs the credit of having for the first time after the total extinction of purple-dyeing, re-discovered (1681) the remarkable properties of susceptibility to light, and of colour- progression under its action, possessed by the fluids secreted by certain molluscs. W. R. Wilde, an Irishman, made a substantial contribution towards the solution of our problem by his discovery of huge deposits of shells of Murex trunculus on the shore of ancient Tyre, the home of purple-dyeing. Special mention must also be made of the striking researches of Lacaze-Duthiers. His “Mémoire sur la Pourpre” (1857), narrates his experiments on the secretions of Murex trunculus, M. brandaris, M. erinaceus, Purpura hemastoma and P. lapillus, and sheds a flood of light on the statements contained in Aristotle and Pliny. The net result of the study of the classical texts, combined with archeological discoveries and scientific experiments, has been the establishing, beyond a shadow of doubt, that at least the following species were anciently employed in the manufacture of purple:—Murex brandars, M. trunculus, and Purpura heemastoma. Purple in the Bible and in Talmudic literature is mentioned under two designations, tekelet and argaman. While argaman is generally explained as red or violet-red purple, there is less consensus among translators with regard to tekelet, but the prevailing view is that, contrary to the traditional interpretation, it denotes not a dark pure blue, but rather a dark violet, inclining to blue. In my work on Tekelet, however, I have shown, I believe conclusively, that if not actually so in the strictly scientific sense, the tekelet-colour did not, at all events, appreciablg differ from a dark pure blue, the nuance assigned to it by tradition. It is generally assumed that both tekelet and argaman are varieties of purple, or in other words, of stuff dyed with sea-snail pigment. That argaman was of this nature is attested by the Septuagint, the oldest translation of the Bible, The Dyeing of Purple in Aucient Israel 23 Wherever argaman occurs in the Bible it is rendered by rop¢ipa or one of its derivatives; and zopdvpa without a qualifying epithet means, of course, purple dyed with the pigment of sea- snails. Tekelet is rendered in the Septuagint by takivOos, a designation which does not necessarily imply that the dye is of molluscan origin. Philo and Josephus, moreover, while expressly mentioning the conchylian origin of the dyestuff used for argaman, are silent in regard to the source of the pigment producing tekelet. ‘Talmudic tradition, however, fills the gap. A Talmudic text, going back in all probability to a time when the Second Temple was still in existence, dispels all doubt on the matter by declaring that tekelet used for ritual purposes must be of conchylian origin. The Talmud, moreover, contains a description of the species used for dyeing tekelet, and also an account of the actual process of dyeing tekelet for the “fringes”? (Numbers xv). The exact determination of the species used in ancient Israel for the dyeing of tekelet and argaman, and particularly the former, is a task fraught with almost insuperable difficulties. Various suggestions have been made, but it has fallen to the lot of Dr. Alexander Dedekind, keeper of the Museum of Egyptian Antiquities in Vienna, to press Lacaze-Duthiers’ far-reaching results into the service of Semitic archeology. He maintains that Lacaze-Duthiers’ researches have once for all furnished the clue to the identification of tekelet and argaman respectively. In the fourth book of his Beitrige zur Purpurkunde (p. 226) he gives the following classification :— Purpura lapillus f belong to the tekelet variety Murex erinaceus \ of purple, i.e., violet or blue Murex trunculus | purple. ( belong tothe argamanvariety of purple, i.e., red or scarlet - purple. He regards Murex trunculus as the tekelet species, but also names M. ervnaceus as a possible identification, though in view Murex brandaris Purpura hemastoma | 24 Rev. Isaac Herzog on of the minuteness of the dye-secretion in that species its employ- ment for dyeing was unlikely. His omission of Purpura lapillus is probably due to the fact that this species is not found in the Mediterranean. The identification adopted by Dedekind, be it carefully noted, is based solely on the tradition of the tekelet nuance: it does not take into account the description of the tekelet species as given in the Talmud, and as reproduced by Maimonides, the greatest authority of Post-Talmudic Judaism. And if we are to choose between the three species known to have been employed in Phoenician purple-dyeing (M. trunculus, M. brandaris, and P. hemastoma) there can be little hesitation so far as tekelet is concerned. Murex trunculus is the likeliest of the three; but there is the possibility that tekelet was produced from an altogether different species. The description given in the Talmud of the tekelet species runs as follows :— (a) Its body (i.e., the colour of its body or shell) is like unto the sea; (b) its shape is like unto a fish ; and (c) it comes up once in seventy years, and with its blood tekelet is dyed, and therefore it is very dear.” (Menahet, 44a). Another ancient text (Baraita a’Sisit) offers a variant reading: “ What is Hilazon® like unto? Its shape is like unto that of a fish, and its body (i.e., the colour of body or shell) is like unto the sky, and it only comes up once in seven years ; therefore it is very dear.” Which species of marine snail satisfies the description thus recorded in the Talmud and the Baraita a’Sisit ? Before we attempt to answer the question it is essential to ascertain the import of the three elements constituting the description in the Talmud. (a) This presents no difficulty. It refers to a deep blue or deep violet blue resembling the colour of the Mediterranean or of the clear cloudless Palestinian sky in bright sunshine. *Hilazon in general means a shell-snail. In this instance it means the particular species furnishing the ‘ekelet dye. The Dyeing of Purple m Ancient Israel 25 (b) The second element offers considerable difficulty. From the sporadic allusions to the nature and characteristics of fishes it is exceedingly difficult to evolve a clear idea of the type “ dag” (fish) in the Talmudic conception, though one gains the impres- sion that it does not materially differ from the modern conception of the term fish. Seeing, however, that on the one hand the Gastropoda and Cephalopoda are probably included in the term “dag” as used by Maimonides, and that the tekelet species is described by him as “dag,” we are led to think that the characteristic (6) in the Talmud description does not exclude these classes of marine snails. (c) The last point in the description also offers certain diffi- culties. Science knows nothing of a comet-like septuagenarian appearance of any of the denizens of the sea. In reality, how- ever, ounce in seventy years” is a hyperbolic expression. It amounts to saying that the species is caught at long intervals of time. Murex trunculus fails to satisfy characteristics (a) and (c) of the Talmud. A_ serious difficulty in the way of the identification with Murex trunculus is also offered by the fact that the dye furnished by the latter is of a fugitive nature, while tekelet, as we know from the Talmud, was exceedingly fast. This difficulty can partly be met by the consideration that the tekelet dye used to be mixed with certain drugs, not specified in the Talmud. They may have served as stiptics for the purpose of endowing the colour with the quality of durability and fastness, but I do not think this very probable. If for the present all hope is to be abandoned of rediscover- ing the tekelet species among the members of the genera Murex and Purpura, it might not be amiss to look for the same within the confines of the genus Janthina. ‘The two species of this genus that live in the Mediterranean are J. pallida, Harvey, and J. prolongata, Blainville. These furnish a blue colouring fluid playing into violet. They live in the high seas, at the surface, and their colour is of a beautiful violet blue, which might easily 26 Rev. Isaac Herzog on be confounded with the colour of the sea. Lastly they, like a great many pelagic animals, abound for some years to an enormous extent, whereas in the preceding period they had been rare or even extremely rare. ; Mention may also be made of the fact that the dye-secretion of Janthina is fairly abundant in quantity : in J. prolongata the secretion, in fact, amounts toan ounce. This tends to corroborate the identification with the tekelet species; for while in the classical authors the extreme expensiveness of purple is attributed to the minuteness of the purpurigenic matter in the animal, in the Talmud the preciousness of tekelet is ascribed solely to the rare appearance of the species. Pending further research which, let us hope, will one day be undertaken along the Palestinian and Syrian coasts by specialists from the future Hebrew University of Jerusalem, the suggested identitication with Janthina pallida and J. prolongata is, I venture to say, deserving of serious examination. THE PROCESS OF DYEING. No other material but wool was admissible for tekelet, argaman, and tolat shani (scarlet) of a sacerdotal and ritual character, and for the tekelet of the fringes. In Greek and Latin authors ropdipa, Purpura and their derivatives stand for woollen or silken stuff dyed with purple pigment. Silk purple was probably not unknown in Pheenicia and Palestine, but in the Temple*its use was excluded by tradition. There can be but little doubt that purple dyeing in its early stages was confined to wool. Silk purple being a later extension of the industry, naturally failed to gain admission into the sanctuary or the ritual. , The wool was dyed in its raw state, the spinning, weaving, &e., forming subsequent processes. This is apparent from certain stray allusions in the Talmud, and is also corroborated by classical authority in regard to the manufacture of purple. (Compare also The Dyeing of Purple in Ancient Israel 20 Exodus XX XV, 23 with v. 25). No account of the mode of dyeing has been preserved by Jewish tradition in connection with argaman. Tekelet, however, has fared better, though the account given in the Talmud by R. Samuel bar Judah leaves much to be desired. “Abayi” records the Talmud, said to R. Samuel bar Judah,—“ Now about this tekelet—how do you dye it?” He said to him, “ We take the blood of the hilazon (i.e., the dye secretion of the tekelet species) and drugs (Sanmanim), put them into a kettle, boil the mixture, and then take out something of the liquid in an egg-shell, and test the sample with a bit of soft wool.* We then throw away that ege-shell and burn that sample of wool.” No particulars are given of the “drugs” employed together with the dye-secretion of the tekelet species. Commentators differ. The Tosaphists, the French school of Talmudial exegesis, remark that “it is very strange that extraneous matter should have been mixed with the tekelet dye,” “but perhaps,” they add, “it was the combination of the tekelet pigment with these drugs that constituted the tekelet dye.” Rashi, the foremost commentator of the Talmud, would seem to hold that the drugs in question were simply mordants used for fixing the colour in the fibre, and had nothing to do with the production of the colour itself. An earlier authority, Samuel ben Hofni, principal of the Academy at Sura, Babylonia (d. 1034) would seem to be of a contrary opinion. In a treatise extant as a unique manuscript at the library of Petrograd he asserts:— the information has been handed down to us that tekelet was dyed with the blood of an aguine (marine) animal called hilazon mixed with another (substance).” This rather gives the impression that the sammanim or drugs formed an essential part of the dye, assisting in the production of the requisite colour. Appearances in the Talmud, I feel, point in the opposite direction. The absence of all specification of the drugs in question, tends to indicate that the latter stuffs were not essential to the production of the colour. * Cf. Pliny, IX, 38. 28 Rev. Isaac Herzog on This is really the opinion of Maimonides, the greatest codifier of Jewish law and ritual. In reproducing the Talmudic account of the dyeing of tekelet, he states: “The wool is soaked in chalk and washed until it is clean, and then boiled with ahla and the like, as is the practice of the dyers, in order to prepare the wool for absorbing the colour. The blood of the hilazon is then put into the vat (kettle) together with drugs such as kimonia (cimolia),* as is usual in dveing; the liquid having been raised to a boiling heat, the wool is immersed therein, remaining in that condition until it has the colour of the sky, and this is the tekelet used for the fringes.” TESTS FoR DETECTING FRAUDULENT IMITATIONS OF 'TEKELET. Imitations of purple with vegetable dye-stuff are referred to in Pliny, Vitruvius and other non-Jewish sources. I cannot, however, recall any reference to testsin Greek and Latin authors. For tekelet the Talmud records two testing processes : one due to R. Isaac V. R. Jehudah, the other to R. Avira in whose name it was reported by R. Ada. In the first case a sample of the wool in question was allowed to soak overnight in a mixture of alumine, fenugrec juice and urine forty days old (or - according to a variant reading urine of a forty days’ old child). If the colour remained unimpaired, the tekelet was proved genuine. The other test consisted in putting some of the wool into an overfermented dough made of barley flour, and baking the dough. If after the baking operation was over, the sample on being taken out showed a change for the better in the quality of the colour, the wool would be pronounced genuine tekelet ; if for the worse, it would be rejected. The tekelet imitations were usually made with indigo, which being fast to light and washing, could not be easily detected as a fraud. In test (1) we miss an indication of the proportions in *Cimolia is a cleaning substance, a reference to which is often made in Pliny (XX., 81, etc). The Dyeing of Purple in Ancient Israel 29 which the several constituents are to be mixed. What is the value of these tests from the chemical point of view ? Professor Green, Professor of Tinctorial Chemistry at the University of Leeds, in reply to this and other questions” states :— “Tt would seem clear from the quotation given that the tests prescribed have the object of ascertaining whether the dye is easily reduced” (hydrogenated). Indigo is more readily hydro- genated and removed from the fibre in the form of its leuco compound than is the brominated indigo (of which the purple probably chiefly consists). In both cases the action probably depends on the evolution of the hydrogen by the fermenting organic matter. 2°. It seems likely that tekelet was faster than indigo. 3°. Indigo like all vat dyes is very fast to soap. In pale and medium shades it is not very fast to light, in which respect it 1s surpassed by brominated indigos. 4°. Brominated indigos are all brighter in shade than indigo itself. 5°. All vat dyes are fixed on the fibre by oxydation. In the bath the dye is not present as such but as a soluble leuco or hydro compound. If the oxydation on the fibre is not complete, the dye will be easily removed by washing.” THE USES OF PURPLE IN ANCIENT ISRAEL. Allusions to the secular uses of tekelet and argaman are very few. Neither ever appears in connection with the royal apparel of Jewish Kings in Biblical times. In Canticles the seat of Solomon’s palanquin is spoken of as being made of argaman. The virtuous woman is depicted as clothing herself in shesh and argaman. Tekelet is conspicuous by its absence. The ritual uses of tekelet are two-fold, (I) for sacerdotal and cultual purposes, (II) for the sisit or fringes. (See Exodus XXV, etc., etc., and Numbers XV.) Tekelet appears as occupy- ing a somewhat higher position than argaman in the ladder of sanctity. The account of the First Temple in 1 Kings, 5-7, which of course is very far from complete, omits all mention of textiles. * Dated July 29, 1913. 30 Rev. Isaac Herzog on The parallel passages in Chronicles refer to tekelet and argaman, but in very general terms. Ezekiel’s sketch of the Future Temple contains no allusion to tekelet and argaman. In the Second Temple tekelet and argaman were, we know, used not only for the High Priest’s garments, in accordance with Pentateuchal prescriptions, but also for the thirteen veils hung at the gates. The ritual use of tekelet for the sisit or the fringes survived the Temple by several centuries. _ The law of sisit (the fringes) occurs twice in the Pentateuch Numbers XV, 37-41, and Deuteronomy XXII, 12. The symbolic significance of tekelet is, I think, quite clear from the text of the Pentateuch itself. The tekelet resembling the sky-colour is to remind one of heaven, and so raise his feelings and thoughts to higher planes. This is, in fact, the traditional view of the significance of tekelet. Though the rite of sisit is still observed, to some extent, by professedly orthodox Jews, and in a smail measure even by reformers, tekelet has long ceased to form part of the sisit. THE ToTAL EXTINCTION OF TEKELET. Tradition singles out the territory of Zebulun, which, as we know, adjoined Phoenicia, as the centre of purple manufacture in Palestine. This is significant in view of what we otherwise know of Phoenicia as a principal centre of the purple industry. A Talmudic tradition states in connection with Jeremiah, LII, 16 that Nebuzradan left some of the poorest people of the land to engage in the fishing of the purple-snails on the coast extending from the ladder of Tyre to Haifa.. This would point to that stretch of territory as the home of Jewish purple-manufacture in ancient Palestine. The Hittite City Luz (Judges I, 26) is referred to in the Talmud as pre-eminent in the manufacture of tekelet. The reference may well be to a city in the vicinity of the Syrian The Dyeing of Purple in Ancient Israel 31 coast belonging to the great Hittite Empire in Northern Syria. In view of the tradition crediting Phoenicia with the invention of purple-dyeing, and of the high esteem in which Tyrian purple was universally held in antiquity,* it is rather startling to find Ezekiel (X XVII, 7) referring to the Isles (or coast lands) of Elisha as furnishing Tyre with tekelet and argaman. This sounds like bringing coals to Newcastle. Where are those isles or coast lands of Elisha 2 I am inclined to agree with Professor Sayce (Hasting’s Dictionary of the Bible, S.V. Elisha) that Elisha adjoined the Mediterranean coast land. It may very well have been a Phoenician settlement, which would seem to have excelled about the time of Ezekiel, in the manufacture of purple. It would thus appear that the universally renowned Tyrian pre-eminence in purple production is subsequent to Ezekiel (died about 571 B.C.). A classical source? names Sarepta, Caesarea, Neapolis and Lydda as cities supplying purple, thus indicating that the industry covered an area comprising the coasts of Syro-Phoenicia, Galileo, Samaria and Judaea. Migdal-Sabaja in the neighbourhood of Lydda (Lud) would seem to have contained an important purple market. The question in how far the manufacture of tekelet in particular may have been affected by the imperial edicts issued from time to time concerning the fabrication of purple, its sale and use, is discussed at considerable length in my work on tekelet. For centuries after the destruction of the Second Temple extra-Palestinian Jewry was wont to procure tekelet for the “fringes” from the Jewish dye-houses in the Holy Land. There is a record of the importation of ritual tekelet into Babylonia about 506 c.E. It may safely be asserted that at the time of the completion of the Babylonian Talmud (c.¥. 570) tekelet still continued in practice for the sisit or fringes. On the other hand in the Sheltot d’ Rabbi-Ahai, a ritual work * (Cf. for instance, Strabo, XVI, 11). Tt Geog. Gr. Minores, IT 5-13, 29. 32 Rev. Isaac Herzog on composed in Palestine about 760 c.&., all mention of tekelet is omitted. The disappearance of tekelet from the Jewish ritual thus falls between the final redaction of the Talmud (c.&. 570) and the composition of the Sheltot (c.n. 760). The Arab conquest of Palestine about the year 638 entailed the total destruction of the purple dye-houses administered by the imperial officials. t The final extinction of tekelet would also seem to have been one of the effects of the Arab conquest. The great Jewish traveller, Benjamin of Tudela (C. 1160), makes mention of the dyeing of red-purple on the Tyrian Coast. It would thus appear that the industry revived some time after the Arab occupation. The interval must have been a fairly long one, seeing that the Jews who in Benjamin’s time played an important part in the industrial life of Tyre* had made no attempt to resuscitate the dyeing of tekelet for ritual purposes ; the chain of tradition must have been too long broken. The art of purple-dyeing in general, which, dating from hoary antiquity—the mention of tekelet and argaman in the Cuneiform texts occurs already about 1600 B.c.—passed through a long and checkered career, finally becoming extinct, at least in the Old World, on the fall of Coustantinople, May 29th, 1453. It is worthy of note that the remarkable researches carried out by Gentile inquirers from William Cole to Lacaze-Duthiers found no echo in Jewish circles. It was not until 1887, some 28 years after Lacaze-Duthiers’ famous experiments that an attempt was made by a certain Rabbi, Gershon Enoch Leiner, of Radzin, Poland, to restore ritual tekelet in Israel. He carried out investigations along the Adriatic coast, and eventually arrived at the conclusion that the tekelet species was identical with Sepia officinalis. In 1888 he established a factory for ritual tekelet in Radzin, dying a few years afterwards. The tSee Amati, De Restitution Purposes. *See Benjamin of Tudela’s Itinerary, cd. Asher, pp, 29-30. The Dyeing of Purple in Ancient Israel 33 dye-house founded by him was still in existence about the time of the outbreak of the Great War. The tekelet of Radzin has * failed to obtain general acceptance, and its use is confined to a small circle of a few thousand families, consisting of admirers of the late Rabbi Leiner and of his son and successor. That his identification of the tekelet species is entirely erroneous is conclusively shown in my work on Tekelet. At the conclusion of the lecture the sincere thanks of the audience was conveyed to Dr. Herzog by the Chairman. 10th February, 1920. Professor GREGG WILSON, President of the Society, in the Chair. CATALYSIS OR THE SPEEDING-UP OF CHEMICAL REACTIONS. By A;. Kitten Macpetu, M-A., D:Sc., F.1.C., MR DAS ire: ( Abstract.) Para 1. The word catalysis 1s an unusual one and is doubtless unfamiliar to many, so at the outset a little space may profitably be devoted to an explanation of its meaning and application. It is derived from the Greek and means to wnloosen. The term is now reserved for the description of those cases in which the pro- eress of a chemical reaction is accelerated by the addition of a small amount of another substance, which is itself unchanged at the end of the reaction ; this may with some justification be regarded as an unloosening of chemical forces through the agency of the added material. The influencing agent is called a catalyst. A particular case will help to make the matter clear. A mixture of dry hydrogen and oxygen may be kept for a long time without any apparent union of the gases (to form water) taking place. The mixture may even be heated considerably without any appreciable combination resulting. If, however, a piece of clean platinum foil is added to the gaseous mixture the reaction immediately commences and sometimes proceeds with such vigour that the platinum becomes red hot and an explosion occurs. ‘This isan example of the catalytic effect of platinum—a normally slow reaction being accelerated by its presence whilst the catalyst itself undergoes no change. Catalysis or the Speeding-up of Chemical Reactions 35 A good mechanical analogy is found in the case of a weight moving down an inclined plane. If the angle is gradually increased the plane is ultimately sufficiently tilted for the weight to start off and move slowly down the plane. Such motion may be regarded as representing a chemical reaction normally proceeding with small velocity. If the plane is now smeared with oil—the tilt remaining unaltered—it is found that the weight moves with a much greater velocity than in the preceding case. So we have the analogy to the increase in the rate of a chemical reaction by the addition of traces of a foreign substance. In the case of the weight moving down the plane it is evident that the oil cannot affect the actual force causing the weight to slide down the plane. It does, however, alter the resistance to the motion by decreasing the friction and so the velocity of the weight is increased, Force Resistance since Velocity = In the same way a catalyst cannot be regarded as increasing the actual chemical affinities in a reaction but merely as acting in some way to decrease the resistance. Many examples of catalytic action are known, but at this stage we may refer to two common cases. Potassium chlorate on being heated decomposes and gives off oxygen. If a little manganese dioxide is added to another quantity of the chlorate it is found that on heating, the oxygen is liberated much more rapidly and at a much lower temperature than in the first experiment. The manganese dioxide, moreover, may be recovered unchanged at the end of the reaction. Again, if a solution containing oxalic acid is heated with some nitric acid, little decomposition occurs. If a trace of a’ manganous salt is added the reaction proceeds briskly and the oxalic acid is broken down into carbonic acid gas. In these examples we see two criteria for catalysis, namely, (1) a catalyst can assist the course of a chemical reaction and itself remain unchanged and (2) a small 36 A. Killen Macbeth on amount of the catalyst is sufficient to effect the reaction between large amounts of the reagents. Before passing from the inclined plane analogy attention may be called to a further point. We can conceive the case of the plane being tilted to an angle much greater than that required to set the weight in motion. But if the weight is held by a clip it will not move until such an obstacle is removed. We find a parallel to this in what are known as “ trigger” reactions: and just as no amount of oil will start the movement of the weight when it is held up by an obstacle, so trigger reactions are not recognised as catalytic phenomena. Examples of trigger reaction are found in the super-heating of water out of contact with dust and air and the crystallisation of supersaturated solutions. There is, therefore, an additional criterion for catalysis that is generally advocated, namely, that (3) a catalyst only affects reactions that are normally proceeding at a slow rate—in many cases at an immeasurably slow rate. Substances which may act catalytically. In the early days of the subject it was thought that catalysis was the exception rather than the rule, but with increasing experiment the observations quickly reversed the belief and it would now appear that there are few reactions incapable of being materially assisted by the introduction of a suitable catalyst. The substances which act as catalysts range from the commonest to the rarest—from water to osmium, platinum, ete. .Water, indeed, is a very general catalyst, bringing about the interaction of many gases that would not react if perfectly dry. For example, if sulphuretted hydrogen (dried by its passage over calcium chloride) is passed into a flask along with sulphur dioxide (dried by sulphuric acid) no reaction occurs : on adding a little water to the flask the gases immediately interact and sulphur is deposited. Again, carbon monoxide burns to carbonic acid gas, uniting with the oxygen of the air: but a jet of the dry gas will not burn in dry air. These are particular examples illustrating the catalytic action of water, Catalysis or the Speeding-up of Chemical Reaction 37 Of the metals, platinum and nickel are the most effective catalysts, and their efficiency is greatly increased as their fineness of division increases. Thus colloidal platinum and _ platinum black are incomparably more effective than platinum wire or platinum foil. Theories of catalytic action.—Many views have been pre- sented to account for the action of catalysts, and of these two deserve mention. The first—which may be regarded as the chemical view—supposes the catalyst to form transitional chemical compounds. Here the catalyst acts as a kind of middle- man, inducing reaction between the two main reagents. ‘The hypothesis may best be supported by reference to the reaction of sulphur dioxide with oxygen to form sulphur trioxide. This addition takes place but slowly in the absence of a catalyst. In the presence of a trace of nitrogen peroxide the difficulties disappear and the reaction proceeds quickly. This is explained by the nitrogen peroxide first parting with some of its oxygen to the sulphur dioxide to convert it into the trioxide. The resulting nitric oxide quickly takes up oxygen and is again converted into the peroxide, which is available for further reaction with sulphur dioxide. Thus a small amount of nitrogen peroxide is sufficient to bring about the union of large amounts of sulphur dioxide and oxygen. The transition of the catalyst into a lower oxide during the course of the reaction supports the view of catalytic action mentioned above. There are many cases in which the intermediate compound view is untenable, notably in reactions which are accelerated by catalysts such as platinum or other finely divided metals. In such cases it is assumed that the catalytic power of the substance is connected with some physical property. The chief property that has been emphasised is that known as adsorption. Most substances have the power of condensing other compounds on their surface, and this is known as adsorption. Charcoal, for example, can take up about 170 volumes of ammonia gas; it can also remove substances from solution, as is seen in the case of the 38 A. Killen Macbeth on filtration of coloured solutions through layers of charcoal. This is purely a surface effect, and when it is recollected how large a surface is presented by the finely divided or colloidal metals, ‘the probability of adsorption as a factor in catalysis is apparent. It has been calculated that if a sphere of gold with a radius of 1 m/m (about the size of a lead shot) were broken down into the colloidal state the particles would present a surface of nearly 1,000 sq. feet. On the adsorption view the reacting substances are condensed on the surface of the catalyst, and so are brought more closely together. There is therefore a greater chance of their reacting : and so the velocity of the reaction is increased. These are the outstanding views that have been presented to account for the action of catalysts in speeding-up chemical re- actions. Whether they are a correct representation of the state of affairs matters but little, as the application of catalysis to commercial operations is fortunately not dependent on such explanations. So without further enquiry we may proceed to examine some of the outstanding uses of catalysts in industrial processes. Part II. THE CATALYSIS OF COMMERCIAL CHEMICAL PROCESSES. In introducing the second part of the subject, we may first look at a particular case illustrating the effective application of catalysis to a commercial problem. In the manufacture of carbonate of soda (washing soda) from cominon salt, two great difficulties were encountered in connection with bye-products formed during the process. In the first place large amounts of hydrochloric acid were produced during the course of manufac- ture, and as there was no great demand for this, it was allowed to escape into the air through tall chimneys. The acid which thus escaped was carried down by rains and had a very harmful effect on the vegetation of the surrounding country. This and other public inconveniences gave rise to widespread grievance, and the manufacturers were compelled to dispose of Catalysis or the Speeding-up of Chemical Reactions 39 the acid otherwise. They made use of the great solubility of the acid in water, and discharged it into neighbouring streams: but the streams so polluted were the cause of the destruction of fish, and in consequence this practice also had to be abandoned. After some study of the question it was found that if the hydrochloric acid fumes were mixed with air, and passed over heated bricks which had previously been moistened with a solution of cuprous chloride, a reaction took place, and chlorine was produced. The chlorine was absorbed by lime, yielding bleaching powder, for which there was a brisk demand. Thus by the catalytic action of cuprous chloride, a bye-product which had previously not only been a loss but also a nuisance to the manufacturers, was trans- formed into a valuable compound which proved a very welcome source of revenue to the companies. The second bye-product in the process was a substance known as ‘ black ash,’ consisting largely of calcium sulphide. For this there was no demand, and it was therefore tipped-up outside the works. In course of time mountains of this waste material had accumulated and proved a vexatious question to the manu- facturers, not only on account of the space it occupied, but also because of the offensive smell. It was found that the calcium sulphide could be made to yield its sulphur in a very pure state, and as this was a good marketable substance the question of the profitable disposal of the black ash was settled. The calcium sulphide is decomposed by carbonic acid gas, yielding calcium carbonate (chalk) and sulphuretted hydrogen : the latter is con- verted by the catalytic action of iron oxide into sulphur and steam when a mixture of it and air is passed through a kiln packed with iron oxide. Thus the discovery of suitable catalysts gave a new lease of life to the Leblanc alkali process and enabled it to compete successfully with newer rivals. Sulphuric Acid Manufacture.—In the further study of the bearing of catalysis on manufacturing questions the difficulty is not one of dearth of material, but is rather a question of making a judicious selection that may prove both interesting and instruc- 40 A. Killen Macbeth on tive. A prior place may be given to the process of acid manufacture. It has been said that the wealth of a nation may be gauged by studying its consumption of sulphuric acid. This acid is extensively employed in manufacturing operations and so the quantity used gives an indication of the commercial activities of a nation. The acid results from a solution of sulphur trioxide in water. When sulphur (or an ore containing a high percentage of sulphur) is burnt in air, a gas known as sulphur dioxide is obtained. This unites with oxygen to form the trioxide. The manufacture of sulphuric acid therefore centres round the question of an effeetive process for combining sulphur dioxide with atmospheric oxygen. This is brought about by two processes, both of which involve the use of a catalyst. The Chamber Process depends on the catalytic power of nitrogen peroxide which has already been referred to. The Contact Process rests on the action of various agents, which promote the union of the gases when the mixture is passed over layers of the catalyst. Iron oxide is found to induce a sixty per cent. union of sulphur dioxide and oxygen if the temperature is about 600°C. Asbestos impregnated with a solution of platinic chloride (known as platinised asbestos) is a much more effective, but more expensive, agent. An interesting point may be noted in this connection. If the gaseous mixture contains certain impurities— notably arsenic—the efficiency of the catalyst rapidly decreases and in time its power disappears completely. This is referred to as poisoning of the catalyst and is a point which demands much attention in all catalytic processes. The Nitrogen Question—The. next operation which may be described deals with the manufacture of ammonia and nitric acid. It has been said that the fate of-a nation probably rests on two simple compounds of nitrogen—ammonia and nitric acid. This seems a very remarkable statement and deserves examination. Taking a wide view of the matter we might say that the three chief factors in a nation’s life are her commerce, her armaments and her food production. Without her commerce she must Catalysis or the Speeding up of Chemical Reactions 41 decline; without her armaments her defensive and offensive powers vanish; and without suflicient foodstuffs her population cannot carry on the necessarily unequal contest. In all three of these we find ammonia and nitric acid, but especially the latter, play an important part. Nitric acid is extensively used in industries, such as the manufacture of dyestuffs and other chemical products. All explosives are derived from it or its salts. Food production is also intimately connected with it. In this connection we must briefly examine our needs. The animal body is largely composed of proteins which in the wear and tear of daily life are undergoing incessant wastage and so stand in need of continuous repair. The proteins are largely com- posed of combined nitrogen, so animal diet must include a fair amount of nitrogenous material. Animals are unable to make use of free nitrogen, such as might be obtained from the air we breathe ; in addition animals are unable to assimilate simple compounds of nitrogen, such as nitrates or ammonium salts. The nitrogen diet must be composed of organic compounds already built up to the protein stage by plants or derived from other animals. It is thus evident that animals are ultimately dependent on the plant world for their supplies of nitrogen. Plants can take in nitrates from the soil and convert them into vegetable proteins, such as gluten of wheat. Now there are not great amounts of nitrates in the soil. Some compounds containing nitrogen are present in the humus of the soil; others are carried down by rains. Plants are, therefore, mainly dependent for their supplies of nitrogen on the humus of the soil, which results from the residues of preceding crops and the introduction of animal manures. There is a profit and loss account on the farm, and so the land gets exhausted. There is a steady drain ou the farm, the crops produced being diverted to the centres of keenest demand ; and so most of the foodstuffs raised, instead of being consumed on the farm, are sent to the cities. Stock raised is also sold off. So it is evident that there is a steady export of nitrogenous com- 42 A. Killen Macbeth on pounds which necessarily exhausts the soil. To carry the story on, it need but be stated that the nitrogenous compounds sent into the city for consumption ultimately find their way in sewage to the sea, and so are lost. . The researches of Lawes and Gilbert and other agricultural chemists showed that the application of nitrate of soda or sul- phate of ammonia greatly increased the yields of crops. The practice so introduced was greatly extended, and an enormous demand grew up for these artificial fertilisers. The chief source of sulphate of ammonia is the bye-product produced in the gas works throughout the country, and this is very limited. The chief source of nitrates was the nitre beds in Chili where sodium nitrate deposits were found. The amount of sulphate of ammonia is small, and it was found that the demand on the Chili beds was so great that calculations predicted that they would be exhausted in the year 1923. Considerations of this nature gave rise to what was known as the nitrogen question ; and Sir William Crooks, speaking at the British Association at Bristol in 1898, for reasons such as we have hinted at above, said: “England and all civilised nations stand in deadly peril of not having enough to eat. As mouths multiply food resources dwindle.” And further he added: “I hope to point a way out of this colossal dilemma. It is the chemist who must come to the rescue of the threatened communities. It is through the laboratory that starvation may ultimately be turned into plenty.” : Efforts then were made to prepare nitrates and other com- pounds of nitrogen on a commercial scale. In the atmosphere there are practically unlimited amounts of nitrogen ; but nitrogen is a very sluggish element, combining but slowly with most other elements. It can be made to unite with oxygen under the in- fluence of electrical discharge, but this is not a catalytic process, and so does not concern us here. It can, moreover, be made to combine with hydrogen by the influence of certain metals, and this forms the basis of the Haber process for producing ammonia. Catalysis or the Speeding-up of Chemical Reactions 43 Nitrogen obtained from air is mixed with hydrogen and forced at a pressure of some 200 atmospheres (3,000lb. per sq. inch) over heated osmium or other catalyst. Ammonia is produced, which is condensed by means of a freezing mixture, and collects in a special receiver. The process is very efficient, and other cheaper catalysts may be substituted instead of osmium, which is very expensive. Iron, it would seem, acts as a very suitable catalyst. A very old experiment—shown to illustrate the oxidation of ammonia to nitric acid—consists in bubbling oxygen through a moderately strong solution of ammonia and introducing a heated spiral of platinum wire into the vapour. The platinum con- tinues to glow, and white fumes of ammonium nitrate are formed, due to the oxidation of some of the ammonia vapour. After many years Ostwald gave a modern application to this experi- ment, and built up the commercial process for preparing nitric acid by the oxidation of ammonia. Platinum acts as a catalyst in the process, and a mixture of air and ammonia is passed rapidly over a layer of half an inch of the catalyst heated to 300°C. The velocity of the mixture must be great, as otherwise the process is not effective. Stoneware vessels are used in the manufacture, as the hot nitric acid would attack any metal with great vigour. By methods such as we have outlined atmospheric nitrogen is converted at a reasonable cost into ammonia and nitric acid : and the Nitrogen Question is thus solved. Hardening of Oils. Another application of catalytic action which in recent times has become important deals with the hardening or hydrogenation of oils. Most vegetable oils are fluid or semi-fluid under ordinary conditions. Such oils are of much less value than hard fats, as they are not suitable for commercial processes such ‘as the manufacture of margarine, candles or soap. On examining these vegetable oils it is found that they differ from the fats in having a lower hydrogen content. They are unsaturated, and are capable of taking up additional hydrogen atoms. The problem of converting an oil into a more valuable fat therefore centres round the most effective way of causing it 44 “A. Killen Macbeth on to add on further hydrogen atoms. Finely divided metals prove to be effective catalysts, and finely’ divided nickel is a most effective agent. The general method now practised is to pass steam over hot coke. Water gas—which is a mixture of hydro- gen and carbon monoxide—is formed. The water gas is then passed over nickel heated to about 100°C., and the carbon monoxide reacts with the nickel, giving a volatile compound known as nickel carbonyl, which, together with the hydrogen, is passed into the hot oil. The nickel carbonyl is decomposed, giving off carbon monoxide again and depositing nickel in a very fine state of division. This finely divided nickel acts as the catalyst causing the hydrogen to combine with the oil. By this method an oil may be hardened to any desired degree. Oils so hardened are employed in the manufacture of soap and candles ; they are also largely used in the manufacture of margarine. In this latter connection it is interesting to point out that traces of nickel remain in the hardened oils, and might have a harmful effect if the oils are used for human consumption. No limit to the permissible amount present has yet been fixed, but actual experiments have been conducted with a view to examining the effects of nickel compounds on health. As much as half a gram of nickel oxide has been given daily in a diet without ill-effects, 99-8 per cent. of the metal being rapidly excreted : and hardened oils contain very much less nickel than this, in fact, about one hundreth of this quantity per pound. Synthetic Rubber. Since the introduction of the pneumatic tyre the demand for rubber has gone forward by leaps and bounds. The supply is derived from the sap exuded from the barks of certain trees in the rubber plantations of Ceylon, Java and elsewhere. It is not surprising that efforts were made to produce rubber synthetically—that is, to prepare it by purely manufacturing processes from simpler substances. Rubber, on being decomposed by heat gives, amongst other products, a liquid called isoprene. ‘This liquid is also obtained from other sources, notably turpentine. Sir William Tilden made a comprehensive Catalysis or the Speeding-up of Chemical Reactions 45 study of isoprene and established its structure. In the course of a paper read at Birmingham in 1893 he said: “I was surprised a few weeks ago at finding the contents of the bottles containing isoprene from turpentine entirely changed in appearance. In place of a limpid, colourless liquid, the bottles contained a dense syrup in which were floating several large masses of solid of a yellowish colour. Upon examination this turned out to be india- Up Der . 6s. ‘i This then represents the first artificial production of rubbers Efforts were made to accelerate the polymerisation of isoprene to rubber and many agents were found to promote the change. In 1910 Matthews discovered that sodium had a very pronounced catalytic effect and by varying the conditions the change could be completed in a few hours or a few days. The condensation of isoprene to form rubber can therefore be accomplished and the next step in the process to make it a commercial proposition is to ensure large supplies of isoprene at a low cost. Turpentine is out of the question, not only on account of its price, but also because only very limited amounts of it are available. A fermentation process was devised whereby starch, obtained from potatoes or grain, could be converted into fusel oil, consisting largely of butyl aleohol. This, by the action of hydrochloric acid and the subsequent action of chlorine, is converted into a dichloro-derivative, and when the latter is passed over heated lime it is broken down into butadiene—a substance which resembles isoprene in its main chemical properties. By the agency of sodium the butadiene is polymerised to form an artificial rubber. It was claimed that rubber could be produced by this method at a cost (pre-war) of about sixpence a pound. It is too early yet to give a pronounced opinion about the process, but it seems to have great possibilities. The scarcity of rubber in Ger- many during the war might perhaps be taken as an adverse criticism of the manufacture of artificial rubber, or of the value of the rubber so produced. 46 A. Killen Macbeth on Parr. “Il: NATURAL CATALYSTS OR ENZYMES. Having examined the behaviour of catalysts and reviewed some cases of the application of catalysis in manufacturing operations, association of ideas carries one on to ask the question, Are any substances found in nature which function, or can function, as catalysts? Many substances are found elaborated in the presence of living organisms which assist definite chemical reactions occurring in the animal body, and doubtless also effect the changes that take place during the plant growth. Grain is largely made up of starch, but there is also present a substance known as diastase. The diastase can be developed by moistening the grain and allowing it to sprout. If the grain is subsequently crushed and allowed to stand in contact with water the diastase assists the breakdown of the starch into sugars. This is known as hydrolysis, water being added on to the starch, thereby converting it into sugar. This conversion of starch into sugar does not ordinarily take place, but it may be brought about in the laboratory by boiling the starch for some time with dilute sulphuric acid: the acid acts as a catalyst, inducing the addition of water. We are, therefore, brought face to face in these changes with the great contrast between the violent action of an inorganic catalyst and the quiet, steady working of the natural ferment, diastase. Another example of natural ferments——or enzymes as they are called—is seen in the case of almonds. Almonds, when freshly ground, do not possess their characteristic odour. ‘This, however, develops in the course of time and is due to the chemical change brought about by the enzyme emulsim which is present. From the almonds a substance known as amygdalin can be extracted which, when moistened and treated with emulsin, breaks down into sugar (glucose), prussic acid and oil of bitter almonds (benzaldehyde) to which is due the characteristic smell. Catalysis or the Speeding-up of Chemical Reactions 47 Another good example of enzyme action is found in the case of the extraction of indigo from the indigo-plant. This plant contains a compound izndican which is a combination of the active principle of indigo with glucose. On steeping the plant in tepid water for 12-15 hours an enzyme acts on the indican and the indigo principle passes into solution from which it subsequently settles out on oxidation by atmospheric oxygen. In the case of the animal organism enzymes are found to be very abundant. These natural catalysts have each a specific action. ‘One set assists a particular reaction, another induces a different chemical change, and others accomplish hydrolysis of different types. In the saliva, for instance, an enzyme ptyalin is found which acts on starch to break it down into sugars. In the stomach pepsin is present which acts in the acid solution of the gastric juice to break down proteins into simpler bodies. In the alkaline pancreatic juice another enzyme trypsin occurs, which also acts on proteins. Fat-splitting enzymes are also present. So the work of the digestion and assimilation of food goes on, being accomplished by the agency of these catalytic compounds. Attention might again be drawn to the gentle way in which the enzymes bring about the chemical changes for which they are responsible. ] = aan vee S| == ( L _ ‘ ‘ } 5 eS At i 7 * N i] y - = f t ba ij 1 Ht rs, i ‘y iv 1 } : pi i . i 2 ; , — 4 ‘ > ra i @ — 3 4 a fi a » ites! i, y td 1 : i " * ie ai ‘ae ! / LJ a i ey be a in : 19 1 ‘ 1 va | im a . rf iy i I : meh i Ferra A . : 3 \ Vt - ile if r , ’ a ¥ ‘> 8 ret - PROCEEDINGS, : Nos i : REPORTS. nae BELFAST: f PON INUAL WEE Ee PING: 9077 SE SSlOny 1919-20. The Annual Meeting of the Society was held in the Museum, College Square North, on Tuesday evening, November 9th, 1920, the President, Professor Gregg Wilson, O.B.E., M.A., D.Se., presiding. The Hon. Secretary submitted the following report :— The Council has pleasure in submitting its report for the 99th Session. Seven lectures have been given during the year. The list of the lectures and lecturers is as follows :— O19. lst November. Jn Musewmn, College Square North. “The North of Ireland during the Glacial Period,” by Dr. A. R. Dwerryhouse, M.R.LA., Lecturer in Geology, Queen’s University, Belfast. 2ist November. In Musewm, College Square North. “Fluctuations in the Foreign Exchanges,” by Professor F. T. Lloyd-Dodd, M.A., D.Sc., Head of the Commerce Department, Municipal Technical Institute, Belfast. llth December. In Museum, College Square North. “The Dyeing of Purple in Ancient Israel,” by Rey. Isaac Herzog, M.A., D'Litt., Chief Rabbi of Dublin, 98 Annual Meeting. 1920 13th January. In Museum, College Square North. “The Great Chemist, Joseph Black, his Belfast friends and family connections,” by Mr. Henry Riddell, M.E., M.I.M.E., Hon. Treasurer of the Society. 10th February. In Queen's University. “Catalysis, or the Speeding up of Chemical Reactions,” by Dr. 8S. Killen Macbeth, M.A., F.1.C., M.R.I.A., Lecturer on Organic Chemistry, (Jueen’s University. 12th “March. In Queen’s University. “The Use of Colloids in Disease,” by Mr. Alfred B. Searle, of Sheffield. 25th March. In Wellington Hall, Y.M.C.A. ‘A Naturalist’s Wanderings in Nyasaland,” by Professor Robert Newstead, F.R.S., Professor of Entomology in the Liverpool School of Tropical Medicine. Where possible, the lectures were illustrated by Lantern and Microscopic Slides, Specimens and Experiments. CounNcIU’s THANKS. The Council tenders its thanks to the Vice-Chancellor of Queen’s University (The Rev. T. Hamilton, M.A., D.D., LL.D.), for his continued interest and for the facilities which he so willingly affords by granting accommodation in the University for lectures requiring apparatus and experiments. The Council also desires to express its best thanks to the local Press for the reports of the various meetings, and to the Lecturers for their assistance during the session. Annual Meeting. 99 New MEMBERS. Some sixty new members have joined the Society, either during the year or for the coming session. The Council wishes to thank Mr. Thomas Edens Osborne for his efforts in bringing into the Society, under the new subscription scheme, a number of townsmen having interests in science, art or literature. DEATHS. The Council has to record, with regret, the death of four members: Mr. Blakiston-Houston, D.L., of Orangefield, formerly Member of Parliament for North Down, on February 27th, 1920, at the age of 90 years ; Mr. Hector MacColl, who died on April 22nd, 1920; Mr. W. H. McLaughlin, D.L., J.P., of Macedon, who died on July 18th last; and Sir John Byers, a _ past President (1908-1911) of the Society, who died as recently as September 20th last. Sir John took a warm interest in all that pertained to its welfare. He delivered six lectures before your Society, dealing with Ulster dialects and folk-lore. His first lecture was given in 1905, and his last in 1918. IrtsH Mss. A grant of £15 Os. Od. has been paid to Miss Madelaine Dempsey for cataloguing the Irish MSS. in the possession of the Society. The manuscripts referred to were deposited on loan on 18th December last, in the Reference Department of the Central Public Library, where they have been much utilised by students. ARCHAEOLOGICAL SECTION. The Archaeological Section, which is now entering its fourth year of existence, under the chairmanship of Sir Charles Brett, continues to justify its formation. Extensive excavations were made during the summer at the Mound at Downpatrick, and in Rathkeltchar, and a report of these investigations will be read by 100 Annual Meeting. the Honorary ‘Secretary, Mr. H. C. Lawlor, M.R.I.A., at the annual meeting of the Section to be held towards the end of the month. The membership is considerably increased, now num- bering over eighty. Hon. TREASURER’S STATEMENT. Mr. Riddell, the Hon. Treasurer, will submit the financial statement, which has been passed by the Local Government Board Auditor. It will be seen that the debt brought about by the repairs, due to dry rot in the upper part of the building, has been wiped out. EXCHANGES. Your Council still continues to receive, in exchange for this Society's proceedings, a number of publications, both home and foreign, from kindred Societies and Institutions, many of them being of great interest and importance. A list of these will be attached to the Society’s report (see pages 123—125). PROCEEDINGS. The method recently adopted of printing the papers periodic- ally has been continued during the year. Copies of these are bound up at the end of the year, as Transactions of the Society tor Exchange. ELECTION OF COUNCIL. In accordance with the constitution of the Society, the five following members retire by rotation from the Council :—-Messrs. W. B. Burrowes, E. J. Elliott, H. C. Lawlor, William Swanston, and Professor Gregg Wilson, all of whom are eligible for re- election, and the meeting will be asked to fill the vacancies, and to co-opt a member in place of Sir John Byers, deceased. The Hon, Treasurer (Mr. Henry Riddell), when submitting Annual Meeting. 101 his Statement of Accounts said he would like to draw attention to the fact that the Accounts were presented in the form pre- scribed by the Local Government Board, and that they include of ' course the finances of the Archaeological Section, which possesses a credit balance of considerable amount, thus rendering the ordinary balance of the Society apparently more favourable than in reality. It has also to he said that the Society’s Printers have this Session furnished no account, which will be fairly large, so that if this account had been included there would have been still a debit balance against the Society. Considering, however, the very heavy expeuse due to the extensive repairs of the build- ings a year or two ago, the present condition of the finances must be considered very favourable. A copy of the Archaeological Section Account will be found on page 122. ADOPTION OF REPORTS. The President (Prof. Gregg Wilson), in moving the adoption of the reports, said that although they were commencing their hundredth year they were showing no signs of decay, but on the contrary were in a healthy flourishing condition. They could congratulate themselves on the fact that they had a good session, and at the same time congratulate themselves and more especially Mr. Deane, on the fact that they were likely to have a more successful session this year. He was delighted to know of the success of the Archaeological section, which was making a great effort to acquire the Knowles collection of antiquities. The amount of money required was rather overwhelming, but the section was going at it with vigour. Mr. Henry Riddell seconded, and the reports were adopted. THE Late Sir JoHN Byers, M.A., M.D., M.A.O. The President said in view of the very special interest Sir John Byers took in the society and the great help he was to it, 102 Annual Meeting. it was only right that they should pass a vote of condolence to be sent to Lady Byers and family. Ever since he (Professor Gregg Wilson) came to Queen’s, Professor Byers was a prominent member of the society, and was always interested in its doings. He moved the following resolution :— “That at this first meeting assembled since the death of Sir John Byers on 20th September, 1920, we desire to place on record our sense of the great loss the society has sustained by his death. Sir John took a deep interest in all that pertained to the welfare of the society and, during his Presidency (1908-11), the transfer of the society's museum collection to the Corporation was completed. That a copy of the foregoing resolution be forwarded to Lady Byers by the hon. secretary, and that he convey to her the society’s sincere sympathy.” Mr. J. M. Finnegan, B.A., B.Se., seconded the motion which was passed in silence, the members standing. LIFE MEMBERSHIP. The Hon. Secretary read letter dated 11th October, 1920, from Mr, Thomas Edens Osborne, suggesting the propriety of creating Lite Members and after some discussion it was decided to leave the matter in the hands of the Council for the coming Session, to deal with. ELECTION OF COUNCIL MEMBERS. The following five members .of Council, who retired by rotation, were re-elected on the motion of Mr. William Faren, seconded by Mr. T. Edens Osborne—Messrs. W. B. Burrowes, E. J. Elliott, H. C. Lawlor, William Swanston, and Professor Gregg Wilson. Mr. Deane moved the co-option of Mr. T. Edens Osborne on the Council in place of the late Sir John Byers, and the motion, Annual Meeting. 103 which was heartily passed, was seconded by Mr. H. C. Lawlor M.R.1.A. In moving a vote of thanks to Professor Gregg Wilson for his services during the past year Mr. Henry Riddell said he wanted to emphasise the intimate connection between that society and (Queen's University. ‘They numbered amongst their membership some of the most famous men who were also connected with the University—men whose names were known wherever the English language was spoken. ‘Their lectures were open to the public on application to the hon. secretary or members, and the society was most anxious to accommodate the Workers’ Educational Associa- tion, for which personally he had the highest admiration. One of the leading workers in that association was always a lecturer in Queen’s University, and that made a practical connection between the two. Councillor E. J. Elliott seconded the motion, which was passed with cordiality, and acknowledged by Professor Gregg Wilson. At a subsequent meeting of the New Council the Officers were elected for the 100th Session. These together with the Members of Council will be found on page 126. ARCHAEOLOGICAL SECTION. ANNUAL MEETING. The fourth Annual General Meeting of the Section was held on Wednesday, November 24th, at 4-15 p.m., at 8 Windsor Avenue, Belfast, the residence of Mr. and Mrs. Lawlor, who very kindly entertained the large attendance of members to tea. The chair was occupied by Sir Charles Brett, who referred to the gratifying increase in the membership of the Section, which now consisted of 82. He also expressed gratification at the increased interest that had been manifested in the work of the 104 Annual Meeting. Section during the past season. He regretted the unavoidable absence of the Hon. Treasurer, Mr. Henry Riddell, M.E., and some other members, who had sent apologies. Mr. T. Edens Osborne, acting for Mr. Riddell, read the Treasurer’s report which stated that after all expenses had been met, and the remainder of the annual subscriptions had been paid, he estimated that there would be a balance of about £75 available for the work of the Section during the coming year. The Hon. Secretary, Mr. H. C. Lawlor, M.R.I.A., read his report. There had been three meetings of the Executive Com- mittee held since last annual meeting. Only one application for a grant had been received, namely, one for the purpose of excavation in the Mound of Downpatrick, towards which £50 had been voted: the actual cost had been about £42. A large number of members had been present during these excavations, which had taken place in July, and to a small extent in October. The Executive Committee had taken an active and important step towards securing for the Belfast Municipal Museum the world-famed collection of Irish antiquities of Mr. W. J. Knowles, M.R.I.A., of Ballymena. Owing to his advanced age, Mr. Knowles had come to a decision to realize this collection, and the Executive Committee have only given practical effect to the general feeling that this magnificent collection should not be allowed to leave the home of its creation. The Committee had taken the initial steps towards raising a sum sufficient to acquire the collection for Belfast, or at least preventing it being scattered by auction. The Hon. Secretary could not at this early stage— the circular explaining the matter having only been issued a few days—make any forecast as to the success of the effort. The election of Office-bearers for the ensuing year was then proceeded with, with the following results :— Chairman, Sir Charles Brett. Hon. Treasurer, Mr. Henry Riddell, M.E. Hon. Secretary, Mr. H. C. Lawlor, M.R.I.A. Kixecutive Committee, in addition to the above, (ex-ofticio) ? Annual Meeting. 105 Professor Gregg Wilson, D.Se., M.R.I.A., Mr. Arthur Deane ; (elected) Mr. R. S. Lepper, M.A., F.R.Hist.Soc., Mr. Alex: ° Wilson, J.P., M.R.I.A., Mr. Thomas Edens Osborne, Mr. W. B, Burrowes, The Rev. William Adams, M.A., The Rev. Canon Carmody, M.A., Mr. Fergus Greeves. The Hon. Secretary (Mr. H. C. Lawlor, M.R.1.A.) read a report upon the investigations at the Mound of Downpatrick and Rathkeltchar, already referred to, and exhibited a number of articles of great antiquarian interest discovered therein. (See pel 0a— 120). EXCAVATIONS AT THE MOUND, AND ON THE SITE OF RATHKELTCHAR, DOWNPATRICK. About a quarter of a mile to the N. of the Cathedral of Down lies the remarkable fortified hill, to-which only in recent years, the name “Rath Keltchar” or ‘“ Dunkeltair” has erroneously been applied. It will not be without interest if I briefly trace backwards in chronological order references to this mound, showing what I may call the gradual growth of this misnomer. In an admirable and instructive little book called “The Official Guide to County Down and the Mourne Mountains” by Mr. R. Ll. Praeger, it is stated that the place is referred to as early as the year B.C. 1030, in its early form Aircealtair or Aras Cealtair, the habitation of Celtchar : but a few lines further on it states that Celtchar, or Celtchar of the battles, as he was called, was one of the heroes of the Red Branch of Ulster, and a companion of Conor McNessa, King of Ulster. Now Conor MeNessa lived in the first century, A.D, so that there seems to be some confusion among the authorities as to the real origin of the name. This remarkable confusion occurs, though not in quite so pronounced a manner, in Father O’Laverty’s “ Diocese of Down and Connor” (vol. 1, pp. 266-7). Reeves also attributes the name to Celtchar of the battles, 106 Annual Meeting. but fails to explain the name as having appeared in the form of Aircealtair in 1030, B.C. (Annals F.M.). Reeves, so far as I can find, seems to have been the first writer who actually states that the Mound of Downpatrick was the Rath of Celtchar (Keclesiastical Antiquities p. 142). Comparing the several editions of the ordnance maps, the recent editions print the name Rathkeltchar as applying to the mound ; the edition of 1857 calls it “Mount,” while that of 1834, the first, merely marks it “ Fort.” The Act of Parliament of 1882, dealing with the establish- ment of the county councils, gives the council of Down power to preserve as an Ancient Monument Dunkeltair, referring to the mound. Lewis, in his topographical Dictionary, 1837, merely refers to the mound as “the ancient doon or fort, near the church founded by St. Patrick”; he does not associate it with Dunlethglas or Rathkeltchar, from which it seems evident the confusion had not arisen in his time. Going further back to Harris, who wrote in 1747, no sign of the confusion can be found in his account; but perhaps the clearest evidence of rather more ancient times as to the real nature of the mound can be found in an estate map drawn out in the year 1729, where the mound is marked, as then known, “The English Mount,” and in the inquisition of 1662, where it is recorded that Thomas Cromwell, Earl of Ardglass, had been seized at the time of his death in 1650, of, inter alia, “ Hoggs Island, Le Roundmount als Donecoscue, Courtground, &e. . . all in-or near Down.”* There can be no doubt that the English Mount, Le Round- mount, otherwise Donecoscue, in or near Down, applies to the Mound as it was familiarly known in the years 1729 and 1662 respectively. In the earlier date the Norman-French name still adhered, evidently transcribed by a clerk with no accurate *Orpen ; Journal of the R.S.A.I., vol. xxxvii (1907), ‘‘ Norman Motes in Ireland.” Annual Meeting. 107 acquaintance with the ancient spellings ; butit is easy to interpret his meaning as the Round Mound, otherwise Dun de Courey, or de Courcy’s Fort. I can find no further direct reference to the Mound of Downpatrick until we get back to the entries in The Annals of the year 1177. In the Four Masters the following occurs :— “An army was led by John de Courey and the Knights into Dalaradia and to Dundaleathghlas; they slew Donnell, the grandson of Cathasach (this is possibly a mistake, or another name for McDunlevy), Lord of Dalaradia. Dundaleathghlas was plundered and destroyed by John and the Knights who came in his army. A castle was erected by them there, out of which they defeated the Ulidians twice, We.” The annals of Innis- fallen, however, give us more particulars of this castle of de Courey. They record: “John de Courcy on this occasion erected a strong fort of stones and clay at Down, and drew a ditch or wall from sea to sea.”* This account exactly describes the mound as it was before the flood gates at the mouth of the Quoile were erected, when the sea came round three sides of the mound ; the existing outer trench and vallum exactly correspond with “a ditch or wall from sea to sea,” while the inner trench and motte and bailey are clearly the “strong fort of stones and clay.” In the following notes I adopt the terms ‘motte’ and ‘bailey,’ following the lines laid down by Mrs. Armitage in her ‘Early Norman Castles of the British Isles.” A motte is still the French word meaning a lump or ball of earth. . In Doomsday it is used to designate the mound which was always a feature of an early Norman castle, and on which a wooden tower or bretasch was built. These mottes were usually atone side of and within a circular or oval enclosure, leaving the remainder of the enclosure crescent-shaped, as in the present instance. This flat crescent-shaped enclosure was called the bailey, and corresponded *Annals F. M., O'Donovan ; anno 1177, note k. 108 Annual Meeting. to the courtyard of later castles. In some cases, as in Dromore, the bailey wasa rectangular entrenchment with the motte outside and detached. The motte was usually built of the clay or rock excavated from a circular trench of which it became the centre. Thus the word motte or mote, latterly spelled phonetically m-o-a-t, became applicable to either a circular trench or foss, or the enclosed mound made from the soil extracted therefrom, or to the two combined. Mrs. Armitage restores the original meaning of motte, a lump of earth or artificial mound: while the moat is now more generally accepted as the trench, either full of water or dry, surrounding a habitation, such as a moated grange. The bailey or courtyard corresponds to the Irish bawn. The name is still well preserved in the Old Bailey of London, originally a courtyard of a Norman fortification. It seems to be also analogous to the Irish bally, now loosely translated as a town or townland, but really seeming to mean a populated centre or assembly of dwellings. The accounts of the events immediately following the erection of this castle differ in the various annals and the account of Giraldus Cambrensis; but one thing seems to be clear, that de Courcy having once entrenched himself here, “ dug himself in,” as the modern phrase is, used this fort as his rallying point. He may have suffered the defeats referred to in the annals of Innis- fallen, but in the end he undoubtedly conquered Dalaradia, at first fortifying the mound as an impregnable fortification on which to fall back. This does not at all imply that his army stayed here continuously ; the Four Masters and Giraldus clearly convey that he was continuously on the move, raiding here and there, gradually increasing his hold on Down and Antrim, until finally he had the whole in subjection and “ encastellated,” as Giraldus relates. One thing seems to loom out clear from all accounts : de Courcy set out from Dublin with a force of a few hundred knights and well armed foot soldiers ; in four days they arrived at Downpatrick, which, all unprepared, they captured at once, erecting immediately “the strong fort of stones and clay, en- Annual Meeting. 109 trenched from sea to sea.” How long or how continuously they camped here, or how soon their headquarters were removed to the stone and lime built fortifications in the centre of the present town, the documentary evidences forthcoming do not say ; tradition indicates that de Courey built four strong stone towers joined by curtain walls, one of these towers only now surviving, in the tower of the parish church ; another stood on the site now occupied by the post-office ; the two others, long since pulled down, would, with the curtain walls, have formed a large square with a strong tower at each angle. The plan and section drawn out by Mr. Stendall, the former from the O.S. map, the latter from my measurements taken in conjunction with the map, will give an idea of the mound as it now stands. I have made a dotted line on the plan showing roughly where the tidal waters came to before the Quoile flood gates were made, as the place was in de Courcy’s time. From these the importance of the particulars mentioned in the annals of Innisfallen will be apparent. The use of “the wall and ditch from sea to sea” will become evident especially to those who have studied the place in situ, bearing in mind the ancient level of the water. It must be remembered that the Normans under de Courcy were well armed, mail clad soldiers, expert in deadly archery, while the Irish used no armour and were ignorant of the use of the bow and arrow in warfare. The absolute impregnability of of the fort under these circumstances can be imagined. To this impregnability of the mound, scarped and countersearped and surrounded on all sides by deep water, is probably due to the ultimate conquest by de Courey and his knights, of the whole of Dalaradia. In accordance with the resolution of the Executive Committee passed on 20th June, 1920, I made arrangements for excavations to be conducted in the mound. Through the active interest of Dr, T. M. Tate and Mr. 8, R. Hastings of Downpatrick, a local ore 4 XN x we ‘ 1 pe ‘ a Bs As Ae Ay %, A ae Mp iyrrn bey fenih Te a, Oy TAL a, Oo \ “SQ veel earn 7 5 Sih My hee ~ j > SS "UU yyy, 3 My ay ty oss Se CMY 4 Wy ih WY “ths oO = < Vy WY ; oe = oe S WLESER > z= = MUG ECG ~ >, 2 “> SS es 1, ne SS ~ = "Ge = se oe Se awe = ~—e l ea a Bie =) =i YE Of wx = Dee xs y Sie tas ff a Se 23 tt, fe Se 2G % ie = \ \ == SS sah ZZ “ Yyys\\ \\ =~ SN Nee oO ae $agar% \\s ~) ESOS on sy > é We oe’ 4 \ x \ 1 ~ gles " ‘ youd LS iia! x PATTY ATTY AVY UNANS QQ aes y Gu, Mp eny any \ ' will v4 \\ a 7a TS Wy . Wi tea Jv ui Qa cee Li pv desig dber ATCA SANYSANAAS \\ \ Ww A LOLA POCO OLR) \\5 \ \\ ‘ en! w 41 GLY LTTE LS ee 6 i of = ah yale ek x ~ Ue M Sait Y & t o) i os 4 74 we 7 Se) is OF ak O E w 9 = =< @) (a ao 7 xe S3LYIION) 3JNIND Q31.100 YUN@INOD DVWNIDISO et'ceve NO1L93S WMODYGIWINMOG 40 GNNOW JHL 12 Annual Meeting. committee was formed; the landlord, Lord Dunleath, gave his consent and that of the occupying tenant was also readily given. Through this local committee a band of ten able labouring men was engaged for the investigation, and work was started on the 13th July. Deeming the motte to have probably been the centre of activity of the fort when in occupation, we detailed four men to excavate a trench three feet wide round the crescent- shaped toy; the other six men were set to work digging a trench in the bottom of the inner fosse which surrounds the motte. When these excavations were completed, aud the trenches filled in and resodded, we put six men to the work of sinking pits in the bailey, and four to excavating in the neighbourhood of what was evidently a landing stage or pier on the north side when the water was at its old level. In the bailey nowhere were there the smallest indications of irregularities on the surface to indicate where hut-sites might have been ; so the pits were made at random, some close to the motte, others near the enclosing vallum. In all places the finds were few and disappointing. The total of our finds here are displayed. It is worthy of note that notwithstanding that the sides of the motte and the trench surrounding it are exceedingly steep, the topsoil lying on the bottom of the fosse 1s in no place more than twelve to eighteen inches deep, showing that centuries of rain and weather have not obliterated the original shape of the fort to any appreciable extent. In the bailey the topsoil averaged about eighteen inches ; it was of the ordinary brown earth usual in the district, and was to all intents and purposes virgin soil, probably never tilled. At some fairly recent date it has been top-dressed, to improve the grass, and we found fragments of pottery, &c., from an ordinary modern midden or farm-yard manure heap. Such we cast aside, and the collection displayed represents all the finds exclusive of these. On the top of the motte only a few much corroded small iron nails were turned up. In the surrounding trench were found a few pieces of late mediaeval, or even seventeenth century glass, an Annual Meeting. 113 antiquated iron horse shoe, some fragments of pottery of uncertain age, a few bones of large animals’ and horses’ teeth, the bowl and part of the stem of a pipe of early 17th century. In the bailey, where we excavated extensively, a few fragments of pottery and a few iron nails were found. At the boat quay, where we searched carefully for a refuse heap or dumping ground for waste from the cam}, we found nothing but a few large nails and frag- ments of comparatively modern bricks and a few bits of coal. It is very remarkable that in all our excavations, either on the motte, in the trench surrounding it, or in the bailey, we found not the slightest trace of hearths, chareoal, charred wood, or soot; evidences of continued occupation were everywhere conspicuously absent. With regard to the various articles collected during our excavations, the few iron remains convey no indication as to age, nor can we, I think, derive any information from the bones and horses’ teeth ; the glass is comparatively modern ; there remain only the pottery fragments. I sent these to the South Ken- sington Museum for expert opinion, and had a courteous reply saying that the curator considered it advisable to obtain the opinion of the Department of Mediaeval Antiquities, British Museum, and that he had forwarded the collection to them. Mr. Dalton later reported that in the collection which he had examined none of the pieces seemed of earlier date than, at most, early 17th century. I then forwarded the collection to the National Museum in Dublin, where they were carefully examined by our distinguished member, Mr. E. C. R. Armstrong, and Mr. Dudley Westropp, whose report in every respect and quite independently, confirmed that of the Department of Mediaeval Antiquities of the British Museum. The natural deduction from the foregoing must be that the mound, fortified-as it is, was never occupied to any extent by dwellers. The few articles discovered may indicate that for a brief period it may have been occupied, possibly as a camp, in the 114 Annual Meeting. 17th century ; it may have been temporarily used during the rebellion of 1641; whocan say? But why did we find absolutely nothing to show ancient occupation, early mediaeval, Celtic or prehistoric? Not a trace of a hearth, not a fragment of burned wood, soot, or ash, not a flint-flake or stone weapon 2 -Rathkeltchar, or as it was better known, Dundalethghlas, has been a populous centre for probably 3,000 years. Our excavations in the Mound prove that it at least is not the site of an ancient settlement, and therefore cannot be Rathkeltchar, if other proof were needed. However, those who have read Mr. Goddard H. Orpen’s article above referred to, and Mrs. Armitages’ “ Early Norman Castles in the British Isles,” will have already been convinced, without our investigations, that the Mound of Downpatrick is not Rathkeltchar. It may be asked, if this is de Courcy’s castle, why did our investigations discover no relics contemporary with his time? I think a remarkable feature in the motte helps to answer this: it was never even completed. The completed Norman motte was always a platform capable of holding a bretasch or wooden tower. In the Mound of Down- patrick the motte was only half made when work was suspended, leaving no place on which the bretasch could have stood. Extracts from the several annals throw some hint as to the probably very short occupation of the mound by de Courcy. On his sudden arrival at Down, McDunlevy fled, leaving the town to be plundered by the invaders ; the Irish chief hastened towards Armagh to seek ior aid, and shortly returned with an army, estimated by some at as high as 10,000 men, including many clergy with sacred relics ; that a battle was fought in the marshes near the town, and the Irish army disastrously defeated and dispersed, the sacred relics captured, and the clergy and many others taken prisoners, seems to be well founded. This story has been discredited and attributed to an exaggeration of Giraldus Cambrensis. I can see no reason to doubt its accuracy : the fact that the battle was fought in the marshes clearly indicates that the Irish army attacked de Courcy in his fortress, where, armed Annual Meeting. 15 as his comparatively few followers were, with the deadly bow and arrow, and clad in mail, of which the Irish had neither, he could have defeated twice as many. There seems to be no reason to think that de Courcy used the Mound for any length of time ; in the interval between the flight of McDunlevy and his return, the natural place for de Courcy and his followers to camp was the deserted town round the church; on the return of McDunlevy with the army, de Courcy shut himself up in his fort, around the land side of which the battle took place. After the battle, the defeat of the Irish was so complete that probably de Courcy had no further immediate need for the fort, never finished it in detail, and had leisure to pursue adventures elsewhere. McDunlevy seems to have been forced to make the best of a bad situation, and made peace with de Courcy, as we find indica- tions a little later that he was in alliance with the latter in some of his raids. It is probable that it was during the period after the battle and during the peace with McDunlevy that de Courcy erected the stone castle in the centre of the town, of which the one corner tower, traditionally attributed to him, still remains. Some three miles almost due south of Downpatrick is Castlescreen, also built by de Courcy prior to 1180. It is of almost the same design as the Mound of Down, with motte and bailey, but completed ; the oval platform of the motte measures 90 x 27’; it is smaller than the Mound. About a quarter of a mile to the east of it is the stump of a stone tower of very early masonry, apparently the gate tower.of a later Norman castle, where the stone tower takes the place of the early motte and bretasch. During the progress of the excavations in the Mound I took the opportunity of examining the site of the Cathedral of Down and the surrounding ground. I was much struck with the black appear- ance of the earth everywhere near the cathedral, contrasting so strikingly with the natural virgin soil found on the Mound; it seems to be thoroughly permeated with soot and small fragments of charred wood, in many places intermixed with bones. This 116 Annual Meeting. black soil extended not only in the immediate vicinity of the cathedral but over the fields to the south-west, west and north- west, and to the plantation on the slope to the south of the churchyard. In the field south-west of the cathedral, beyond the new churchyard extension, can still be seen remains of the old cireular vallum, of which the apparent centre seems to have been near the tower of the present cathedral. This vallum is not apparent in the field to the north of this one, but can be indistinctly traced in the next field, lying N.-E. of the cathedral. Due east of the cathedral a broad roadway has been made by filling up the valley with a raised embankment ; to the S.-E. of this, and south of the churchyard, lies the old plantation, separated from the churchyard by a massive wall, built, according to local tradition, during the restoration of the cathedral in 1790 from stones removed from the old ruins. It is quite impossible now to trace the remains of the ancient vallum anywhere except in the field to the S.-W. and to a slight extent to the N.-E. ; but enough remains to show that a vallum at one time existed round the summit of the hill, with a centre somewhere near the present tower, having a radius of between four and five hundred feet. ‘This would indicate an ancient rath with the unusually large diameter of something like three hundred yards. I learned from local enquiries that a few years ago, 1913 or 1914, I believe, immediately to the north of the present cathedral enclosure Mr. Martin, the lessee of the ground, removed a slight hill in the construction of a tennis ground, removing in the process some- thing lke an average depth of from 6 to 8 feet over an area of about three-quarters of an acre. At the time the tennis ground was being made, the County Council were engaged in raising the level of the Ballydougan Road, and arranged with Mr. Martin to remove the excavated soil to assist in constructing the necessary embankment through the marsh. During the process of the excavation, unfortunately, no detailed accounts of the many “finds” that were made were taken, and probably much that might have been of supreme interest has been hopelessly lost, Annual Meeting. Le However, Mr. S. R. Hastings, Dr. T. M. Tate, and others, fortunately succeeded in preserving some of the finds, and a few items are in the possession of the cathedral verger and in the garden of Mr. Harley, which lies close to the cathedral on the N.-W. side. Mr. Hastings kindly supplied me with some notes of what he knew of the excavation, and collected together for exhibition such of the portable finds as he could now bring together. ‘To enable us to have the account more comprehensive, we deemed it advisable to make some slight experimental excavations to find out if the foss S.-W. of the cathedral were ancient, or merely composed of refuse from the old cathedral ruin, as some supposed it to be, and also to examine more minutely the black soil, and obtain some knowledge of its nature and extent. I was not able except on one afternoon to superin- tend this work myself, but Mr. Hastings did so during several days in October, as weather permitted and as he could get the necessary labour. Ina most valuable Historical Sketch of the Cathedral of Down, published in 1904 by “The Down Recorder,” and edited by Mr. Edward Parkinson, is a conjectural sketch of the original plan of the 13th century Benedictine Abbey of Downpatrick, by Mr. J.-J. Phillips, architect. It will be of much interest to contemplate the vast extent of ground covered by the Benedictine Monastry and Church, of which only the chancel is now remain- ing, forming the existing cathedral, the tower being new. The foundation is ascribed to John de Courcy, during the quarter of a century he held sway in Downpatrick. It existed with fluctuating prosperity for some 350 years, from about 1188 to 1538 ; in the latter year it was absolutely destroyed by the English, whether by Lord Leonard Gray or Thomas Cromwell, Earl of Ardglass, matters little. The excavation of 1913-14, when the tennis ground was made, was on the place marked “chapter house ” ‘and part of “the cloisters.” The results that can now be gathered of the excavation of 118 Annual Meeting. 1913-14 together with those of our slight excavation are of immense interest. The hillock where is now the tennis ground, was composed, as to its upper layer, of refuse cast up from the ruins of the Benedictine Abbey cleared in restoring the old chancel to make the present cathedral. Many carvings in Serabo and Dundonald sandstone and in Castleespie limestone were found ; these comprise bases and capitals of pillars, mullions, &e ; half of a piscina and various fragments of carved work. Most of these are to be seen in Mr. Harley’s garden adjoining the cathedral. In this level of the hill were also found many flooring tiles of apparently early 13th century, a number of which are on exhibition. The designs are interesting, some being purely Celtic in idea; others are early Norman. The lion rampant facing either to the dexter or sinister is much in evidence. Beneath the level of the deposit of building refuse the workers came upon the foundations of the walls of the chapter house, and it is a remarkable tribute to the accuracy of Mr. Philip’s conjectural plan, that this wall was found within 6 inches of the position conjectured by him. Beneath the apparent level of the chapter house floor, immense quantities of bones, mostly, if not all, human were removed, showing that a very ancient cemetery nad existed here prior to the erection of the Abbey. How ancient was this cemetery, cannot of course be accurately conjectured, but that it went far back into Pagan times was proved by the discovery of three circular drybuilt graves measuring about 5 feet deep, by 3’ 6” wide, containing skeletons buried in a sitting position with the knees drawn up to the level of the chest. A number of bronze rings were found in or near these graves, but their exact position unfortunately was not noted down. In the tennis ground excavation no fragments of domestic.or other pottery except the tiles from the Abbey debris are recorded to have been found. In the experimental trench beginning to the east side of Hogg Island lane, and at about a right angle thereto, much of great interest was found. At the upper end the debris resembled what had been found on the surface layer of the tennis ground Annual Meeting. 119 site, comprising flooring tiles, roofing tiles and roofing slates from the old Abbey. With these were mixed bones and horns of domestic animals, including boars, deer and fowl, with broken pottery of the ordinary domestic, apparently mediaeval, type. As the trench proceeded further away from the lane, the Abbey debris seemed to stop; the soil was everywhere permeated with soot and decayed vegetable matter, and very black; the depth of the black soil varied from about three feet to, at places, five or six feet or more, resting on the gravel subsoil in the neighbourhood. About 40 feet from the lane the trench cut through what appeared to be superimposed hearths showing two layers of soot or fire remains. These were traced laterally for a few feet, exposing fragments of pottery cooking vessels and several pieces of broken quern stones. The pottery of which specimens are shown is of the crude hand-made class to which I have applied the name “ souterrain type”; it is the class of which about 90 per cent. of the souterrain pottery consists, and dates probably between the 4th and 8th centuries. One or two fragments of early wheel-turned pottery were also found in the black soil, but not in the hearth sites ; these I believe to be of 8th to 10th century. Among the other interesting items found were two remarkable stones: one is a quartz nodule perforated by five circular polished holes; of its use I can form no con- jecture. The other is an artificially rounded stone of about 2” diameter. This is one of the hurling stones used by the Irish in warfare in the 12th century in place of the bow and arrow. Of these stones Giraldus Cambrensis says: “ Handstones (Lapides pugillares), when other weapons fail, they hurl more dexterously than any other nation, soas to inflict great loss on their enemies.” O’Curry, in his “Manners and Customs ” (Vol. ii, p. 263), says that the Irish of this period retained these stones in the hollow of their shields for use when required. The experimental excavation of the trenches just referred to was made in the latter half of October ; the weather was broken and the days getting very short, so we deemed it wiser to dis- 120 Annual Meeting. continue further work and report the result of what we had found to the Archaeological Section for future consideration. In conclusion I would say that from historical records coupled with what has been found by excavations, certain facts are established, which facts I may tabulate as follows :— 1. The hill on which the cathedral is situated has been a place of almost constant human occupation for at least 2,000 years. 2. It has through time been subjected to important alter- ations in its contour on at least four occasions, namely :— a. The enclosure of the Rath by a vallum of which traces still remain ; date unknown. b. The levelling of a vast area of the top for the erection of the great Benedictine Abbey, about the year 1188, when much soil was removed from the site and apparently cast over the side of the hill. c. The clearing of the debris of the Benedictine Abbey for the creation of the present cathedral in 1790: this debris was scattered in various places near the cathedral raising the ground considerably where it was dumped. d. The levelling of the tennis ground on the north side of the cathedral, when about 8 feet was cut off an area of about three-quarters of an acre. The soil removed in this operation was used for raising the level of the Ballydougan Road. 3. As the hill now exists, excavations prove that its summit and to some extent its sides constitute a veritable midden of refuse of all ages from the late bronze or early iron age to the present date. 4. The hill is undoubtedly the site of the ancient Rath- keltchar, Araskeltchair, Dunkeltchair, otherwise Dunleathghlas or Dundaleathghlass. 5. The Mound is actually the entrenchment or castle made by John de Courcy in 1177 and should not be confused with Rathkeltchar. “Opp ‘OZGT “4susny jo Avp UIST ‘NNATA “V °V *WOaLdOD SLYMMODIOYW SULOSIAOZ 99 Fey AJ1LQA99 T dy} puL AJaLVOg JUaIv_ IYY JO SJUNODDY ayy JO BTOYA 9} Sopnyout oT ‘0261 ‘A[nE JO Avp STE “0aO Bununooy "TTACCIY AUNAH OUMUH ONNOA W LUALOU “‘qQUNODDV Iq & SI IAOG’ Oy YY AFI9.109 9A, *ATa}wAVAaS SMOT[OF UOIJO9G 9y4 JO Wnoddy oY, “WoIvag [vol Sopoovyo.Iy “plvogé QUSUTULIAAOH [vooTT ay} AQ padinbad WLMOF 9Y9 UL PAYSTUANJ St UNODOW SIL OL 9 966F [230,L OL 9 966 ‘T8I0.L 6 4 TS van 0 &1 & quNOD.VV JO aSo[o 19qye pespoT ZB FL GS spurt s $10: HO BUIgUNO: wy UL aURlTV_ G LT TL ‘s ae ; ‘on ‘sodvqsod % OL PE SUISTFLVAPV 8 6 IP apes i) @ @ sosivyO yueg g OF 0 : yoog snbeyD OG e 9 20 sis d0UBINSUT 0 21¢ SMUBMOI[Y S19i4oo'T € ¢ coe P-RZGL ‘UOT, IBAA “Juan tad g 0 a ji a $2. mys ary OF seplls pure sue UeT A = PARTE ANS Pee ; aia SuOTeAtoxT] 0 0 OOF “OD SulUUIdY xV[yq 9S YAO A Ssaangueqed ‘jus Jed fF 0 0 GI SSIN MEI SUMNSOlVyVH ‘SSULLIMNOUS HO LST OR ia: re 90, FpPUYy —: “ZILA ‘squeulkeg 13ay9O “* 08 ¢ — -————. 0 0 & SOLIVCS is 0-8) 2c ae ah 2 popunjoy XB, FUOOUT & O FE : SOXVL pure soqey ‘quay ‘‘ ® @ Wye . élo Se squay | Il GL 6 : ‘oN ‘Sosttdig JO svUvUOQUIVy ** OL 6L 12 or a8 o9 - vie spueplaiqd ‘ L OL 88H he qunoooy se ted sv avuvyeg Aq 0 6L ZLIx "° ee Be Bie me SuOIndLiosqns OF WOUV HOSIC OUV HO ¢ AD ‘O@6I “‘oune yjog papua sBad ay} AJIII0S peotydosojid pue AsOJSI] [84nJeN) SBIJag ay} so JuNODIy "SSSI ‘LOV (GNV1Sal) SLNAWMOGNY TWNOILVONGHA OJ 1G au *IAOQ*S UBALS JUEUIOZLYS ey} Ul esuvyo snolses AuB ssnvd You [ILM pu ‘aduey you ‘TaA9MOY ‘ale syUNoUIe oy,f, “AqQeT00g jusIed oYy 07 poYstuaNy syUNOID VW WOT poyesaises Useq oA YOu dABY UOIZOIG [BoIBoToavYyory ey} Jo JTeYaq uO epeut syueuAed oWOG—‘ALON a ES PP TO SET I SI I EI OL St 101s OL SI LOLs OL OL €6 °° Ajeato0g anew jo spury v UL soURTeg as () Gir ter 28 Ajooog yuereg wo1y Apisqnyg a (Del eG ee _ SUOTFBAVOXT as (i) ea Ree “* suorgdrsosqny [Buozoeg S (ie 4 (7 aia Areiqry Jo yuay = 020: (G4 ies sivak OMG ‘paMmo][e 4se10,UT— ‘OZBI ‘oune (ie hes (ye) ee sesuedxy JIpny palyy-eucd “s OL SI g97 Ayo1oog querivg YyALM sourreg— 6161 ‘Aine 0 61 If “* sdweqg pur uorpe[[opD Jo sosuedxy—ozel ‘eune ‘qunowy HONATAAS ULC UL: AAO LIGNA dT Xa ‘NOILOAS TWOIDOTOAVHDAV ‘02616161 ~ALAIDOS TVOIHdOSOTIHd GNV AUOLSIH TWAUNLVN LSVATAG FHL WLIM LNIOJOV NI 123 EXCHANGES. AUCKLAND—Annual Report of the Auckland Institute and Museum, 1919-20. BASEL (Switzerland)—-Verhandlungen der Naturforchenden Ge- sellschaft in Basel, 1918-19. BELFAST—Proceedings of the Belfast Naturalists’ Field Club, 1919-20. BerGEN (Norway)—Publications of the Bergen Museum. BIRMINGHAM—Proceedings of the Birmingham Natural History and Philosophical Society, 1919-20. CaLcutTtA—Memoirs of the Geological Survey of India. Hs Records of the Geological Survey of India. a Report of the Progress of Agriculture in India, 1918-19. CAMBRIDGE (U.s.A.)—Bulletins of the Cambridge Museum of Comparative Zoology. CAMBRIDGE—Proceedings of the Cambridge Philosophical Society. DuBLIN—Economic Proceedings of the Royal Dublin Society. EASTBOURNE—Transactions and Journal of the Hastbourne Natural History Club, 1914-19. EDINBURGH—Proceedings of the Royal Physical Society. Re Proceedings of the Royal Society of Edinburgh, 1918-19. * Transactions and Proceedings of the Botanical Society of Edinburgh. Essex—The Essex Naturalist. Vol. XIX, Parts 2 and 3. GLascow—Proceedings of the Royal Philosophical Society of Glasgow, 1917-18. - Transactions of the Geological Society of Glasgow, 1917-18. / GoTEBorG (Sweden)—Proceedings of the Societas Scientiarum et Litterarum Gotoburgensis, 1911-17. 124 Exchanges. HatrrAx—Proceedings and Transactions of the Nova Scotian Institute of Science. HuLL—scientific and Field Naturalists’ Club. Vol. 1V—part V. InpDIANA—Proceedings of the Indiana Academy of Sciences, 1916-17. Lima (Peru)—Boletin del Cuerpo de de Ingenieros de Minas del Peru. LonbDON— British Museum, Economic Publications. -" ~ Quarterly Journal of the Royal Microscopic Society. n Memoirs of the Royal Astronomical Society. ae Proceedings of the Royal Institute of Great Britain. f Quarterly Journal of the Geological Society. . Report of the British Association, 1918. LOUSANNE—Bulletin de la Societe Vaudoise des Sciences Naturelles. Mapras—Report of the Government Museum of Madras, 1918-19. Matnx—Bulletins of the Maine Agricultural Experiment Station. MANCHESTER—-Journal of the Manchester Geographical Society MELBOURNE—Proceedings of the Royal Society of Victoria. Merxitco— => = os ag eta ids Ct Uae iE ee a gg bah any Soe ‘ FOR THE 4 ete ht ee SESSION 1920-21. MAG MOR e eS December, an ae 47-6 = The yearly average being 74:69 ,, Needless to state this list cannot be regarded as complete ; for doubtless many casuals may have visited the district unnoted. As an instance of this may be cited the observation of an Oyster- catcher—a bird one would not expect here—and it was a mere matter of luck that the writer in passing Munroe’s Dam chanced to see it. However, this paper may be taken as a basis to which future workers in detailed ornithological distribution may add. The measurements of eggs cited are the greatest length aud greatest breadth of the egg and are stated in millimetres. The weights—in grammes—of full eggs are those of fresh eggs, it being recognised that eggs lose some 15/ in.weight during the process of incubation. Measurements and weights are given only for eggs taken in the district. tS to Nevin H. Foster on ANNOTATED LIST OF THE BIRDS OF HILLSBOROUGH. The order and nomenclature here adopted is that of the B.O.U. List, 2nd Edition, 1916. Order PASSERIFORMES. Family CORVIDA. [Corvus corax. Linné. Raven. Local tradition asserts that the Raven formerly bred in Hillsborough Park, but no reference to this can be found in any authoritative work. It is possible that this statement should be referable to the following species, | Corvus cornix Linné. Hoovrpn Crow. Thompson states* that grey crows bred on a wooded islet in Lough Aghery. This may be taken as authentic, but for many years past this bird has not been seen in the district. Corvus monedula Linné. Jackvaw. Resident and common, usually breeding in disused chimneys, but often in trees, particularly those clothed with ivy. Numbers formerly bred in rabbit holes in Hillsborough Park.t Average size of eggs 34°39 x 25°66 mm. ; average weight of full eggs 11°91 gr, of empty shells °8 gr. Corvus frugilegus Zzuné. Rook. ‘Resident and common. Several rookeries occur in the district, the largest of which contains annually about 120 nests. Average size of eggs 39°29 x 2797 mm. ; average weight of full eggs 16°07 gr., of empty shells 1045 gr. Pica pica (Linné). Macrin. This bird was first observed in lreland towards the end of the 17th century but is now resident all through the country as obtains in this district. The nest is usually placed in the upper part of a tall tree but the bird also utilises high Whitethorn (Crategus Oxyacantha) hedges. From such a situation a nest now in the Belfast Municipal Museum was obtained. When fresh taken this nest weighed over 70 lbs. Average size of eggs 33°53 x 23°62 mm. ; average weight of full eggs 9°76 gr., of empty shells “5958 gr. : Garrulus garrulus hibernicus. Witherby & Hartert. Inisn Jay. The Jay can only be regarded as an occasional wanderer to the district. A pair was observed in the Demesne about 1900, and a single bird in the same place in December, 1907. * Nat. Mist. of Iveland, Vol. U1, p. 146. + Nat. Hist. of Ireland, Vol. 1, p. 324. The Birds of Hillsborough 23 Family STURNID 4%. Sturnus vulgaris Linné. STar ine. Resident and numerous, but becoming less so in the Autumn and Winter months. At this season it is probable that many of our Starlings betake themselves to the sea coast, for at this time countless nnmbers may be seen each evening at sunset coming in to roost on the Technical Institute and Assembly’s Buildings, Belfast. Average size of eggs 28°79 x 21°34 mm. ; average weight of full eggs 7 gr., of empty shells 497 gr. Pastor roseus (Linné). Ross-coLourED Pastor. The only recorded instance of this species in the district is one shot here in July, 1836.* {A GoLpEN ORIOLE (Oriolus oriolus (22772) ) was said to have been seen about 2 miles north of the village in September, 1911. ] Family FRINGILLID 2. Chloris chloris (Linné). GRreenFincn. The Greentinch (locally called Green Linnet) is resident and numerous, packing into large flocks in Autumn. Average size of eggs 20°13 x 13°88 mm.; average weight of full eggs 1°94 gr., of empty shells ‘1019 gr. Coccothraustes coccothraustes (Linné). Hawrincn. Thompson statest that a very fine specimen was shot near Hills- borough about the year 1829. One said to have been shot in Park about 1899. Rev. Allan Ellison, when here on a visit in July, 1905, thought he detected a pair flying overhead. Carduelis carduelis britannica (Hartert). GoLDFINCH. Formerly common, this bird has now become very rare. In 1901 Mr. R. J. Pack Beresford released 24 birds obtained from Co. Carlow, but this did not seem to have any appreciable effect on the population. In May, 1905, a nest of this species was found in a high beech hedge, from which the young were duly reared. Spinus spinus (Linné). Siskin. Resident in the district in small numbers, but the local population is augmented in Winter by flocks of migratory birds. The nests, so far as discovered, are always placed far out on a branch of Douglas Spruce and at a high elevation. Passer domesticus (Linné). Housn-Sparrow. Resident and abundant. As obtains elsewhere, the nests are of two kinds (a) a domed structure among the finer branches of the upper part of a tree, or (b) a cup-shaped nest in a hole in a tree or building or in the thatch of houses. Average size of eggs 21°22 x 15°02 mm.; average weight of full eggs 2°635 gr., of empty shells *1712 gr. * Nat. Hist. of Ireland, Vol. I, p. 296. + Nat. Hist. of Ireland, Vol. I, p. 259. 94 Nevin H. Foster on Fringilla celebs Linné. CuHarrincu. Resident and probably the most abundant of our small birds, whose song may be heard from the middle of February till about the end of June. A specimen almost pure white in colour was shot a short distance from the village a few years ago. Average size of eggs 18°98 x 14°12 mm. ; average weight of full eggs 2°024 gr., of empty shells *1211 gr. Fringilla montifringilla Zinné. Brampuine. An irregular Winter visitant—a few probably visiting the district nearly each year, when they may be found consorting with Chaffinches generally in the neighbourhood of beech trees. Acanthis cannabina (Linné). Linnev. A not numerous resident. Average size of eggs 18°23 x 13°49 mm. ; average weight of full eggs 1°667 gr., of empty shells ‘08 gr. Acanthis linaria cabaret (7. L. S. Miller). Lrsser REDPOLL. Resident in considerable numbers. A seasonal movement is observable, most of these birds deserting the higher parts of the district in Autumn and spending the Winter in the lower lying portions. Average size of eggs 16°16 x 12°22 mm. ; average weight of full eggs 1°289 gr., of empty shells 0643 gr. Acanthis flavirostris (ZLinné). Twrrr. Resident in small numbers but usually keeping to the higher lying portions of the district, 7.¢., Drumlough Moss, where it breeds among the ling (Calluna vulgaris). Average size of eggs 17°1 x 13°24 mm. ; average weight of full eggs 1°396 gr., of empty shells ‘0833 gr. Pyrrhula pyrrhula pileata MacGillivray. British BULLFINCH. A not uncommon resident, doing a considerable amount of damage to the buds of fruit trees in Spring but later destroying seeds of noxious weeds. Average size of eggs 18°66 x 13°55 mm. ; average weight of full eggs 1°813 gr., of empty shells ‘118 gr. Loxia curvirostra Linné. CrossBiLu. Thompson records* this bird from Hillsborough Park in January and February, 1838. It is probable that Crossbills bred here in 1901 as a small party was observed for several months in the early Summer frequenting a plantation of Douglas Spruces in the Park. A flock of about a dozen was seen feeding on the seeds of the Douglas Spruce in July, 1909, and Crossbills were noted several times in the succeeding Autumn and Winter. It appears to be here as elsewhere in Ireland a somewhat erratic visitant. [On the evening of 12th June, 1920, and on the following morning a bird was observed feeding among potatoes, &c., in some of the gardens at the south end of the village. The writer had only a momentary vision of it, but others saw it for longer or shorter periods. The bird appears to have been the DominicaAN CarpDINAL, Paroaria larvata Boddaert, a native of Brazil, which is imported in considerable numbers to this country and kept in confinement, from which undoubtedly this bird had escaped. It is the ‘* Pope” of dealers. ] * Nat. Hist. of Ireland, Vol. I, p. 278. The Birds of Hillsborough. 25 Emberiza calandra Linné. Corn-Buntina. Resident in small numbers and very locally distributed in the neighbourhood. Average size of eggs 22°72 x 16°54 mm. ; average weight of full eggs 3°175 gr., of empty shells "194 gr. Emberiza citrinella Zinné. Yrrtow Hammnr. Resident and common. Average size of eggs 20°34 x 15°78 mm. ; average weight of full eggs 2°702 gr., of empty shells "1581 gr, Emberiza scheeniclus Linné. Reen-Buntinu. Resident and common. Forsaking its Summer habitat—marshes and rushy meadows—it frequents stubble and potato fields in Winter, and may frequently be seen following the plough. The Cuckoo frequently utilises the nest of this species for the depositing of its egg. Average size of eggs 19°14 x 14°28 mm. ; average weight of full eggs 2°102 gr., of empty shells ‘1211 gr. Family ALAUDID. Alauda arvensis Linné. Sky-Lark. Resident and common, particularly in the lower-lying portions of the district. The song may be heard as early as January, and in the early season it is frequently uttered whilst the bird is on the ground. In 1920 nany were heard singing on the afternoon of 10th October. Average size of eggs 24°5 x 17°07 mm. ; average weight of full eggs 3°618 gr., of empty shells ‘22 gr. Family MOTACILLID%. Motacilla lugubris Z'emminck. Prep Wacratt. This bird is said to be less numerous in the district than obtained formerly. During the Winter months one can scarce fail to see one or a pair in the village street, but by March they change their habitat. 070Uq ‘ANSUWA( HOAOMOASTTIIT “ISHN NO MON GITAA WIVWNGT ‘16-0261 ‘AJoWOg [vorydosopiy_ pur ALOgSIFT [BVANIVN ISeI[OR. The Birds of Hillsborough. 33 Cygnus cygnus (/717¢). Wuoorrr Swan. Thompson states* that Wild Swans have occurred at Lough Aghery and Hillsborough Park but as at that time the difference between the W hooper and Bewick’s Swan does not appear to have been appreciated it is doubtful to which species these records should be relegated. However on lst December, 1912, tive birds were noted on Hillsborough Park Lake which were undoubtedly Whooper Swans. Cygnus bewicki Yarre//. Brwick’s Sway. In December, 1919, a mature female with two inmature birds of this species came to McKee’s Dam. The mature bird was shot a few days afterwards, but the two cygnets remained for about a fortnight, when they took their departure. Cygnus olor (Gmelin). Mute Swan. Scarce a lake or pond in the district does not provide habitat and breeding place for a pair of these birds in a truly feral condition. On Lough Aghery, which is a mile in length, 2 or 3 pairs nest, but on this lake in Winter it is not unusual to observe as many as 100 of these birds. Average size of eggs 107°62 x 73-36 mm. ; average weight of full eggs 315.636 gr., of empty shells 38°943 gr. Anas boschas Zzuné. Wr.p Duck or Mauuarp. The Mallard is resident and nests in the district in fair numbers. In Winter large flocks of immigrant birds swell the local population. Thompson records} a nest of this species in Hillsborough Park, formed in the old nest of a Magpie about 40 feet from the ground ina Silver Fir tree. This nest contained 15 eggs, and he was of opinion that the young birds had been successfully brought out. Average size of eggs 56°82 x 41°33 mm. ; average weight of full eggs 50°273 gr., of empty shells 4°783 or. Querquedula crecca (/2nné). Common Trt. Resident and breeding in small numbers. Mareca penelope (2772). Wicnon. From 1905 till 1909 numbers of this species frequented the lakes in the Park and Demesne throughout the Winter, but before and since this period they have not been observed. A male in fine plumage was seen on “The Cuts” by the side of the railway a little over a mile from Hills- borough on 21st May, 1906. Dafila acuta (Zine). PrINTAIL. A female of this species was observed on the lake in the Demesne on Ist February, 1909, but on the following day it had disappeared. * Nat. Hist. of Ireland, Vol. III, pp. 9 and 20, + Nat, Hist, of Ireland, Vol, ITI, p. 76, 34 Nevin H. Foster on Nyroca ferina (Zz). PocHarp. A few of these birds spend the Winter on the lakes in the district. Nyroca fuligula (Zzvné). Turrep Duck. Frequents the lakes annually in Winter in larger numbers than the preceeding species. Glaucion clangula (Zzné). GoLDEN-EYE. All through the month of June, 1916, a female or inmature bird of this species (probably a cripple) frequented the lake in the Demesne. During December, 1918, and January, 1919, a pair were seen on the lake in the Park. Order ARDEIFORMES. Family ARDE1DAi. Ardea cinerea Ziuné. Heron. This bird which formerly bred in the district has now apparently ceased to do so. It is common, however, except perhaps in the nesting season. ‘Thompson states! that the heronry in Hillsborough Park contained about 50 nests and it still nested these up to about 1900. The same author tells us* on the authority of Rev. J. Dubourdieu that up till about 1803 Herons nested on the ground in an island in Lough Aghery. It may be stated that the usual nesting site of this species is high up on tall trees. Its local name is ‘‘ Heron-Cran” or ‘‘Cran.” A nest seen in May, 1920, on a tree in one of the islands in Lough Aghery from which evidently young had been hatched is doubtless referable to this species. Order CHARADRIIFORMES. Family CHARADRIIDA Scolopax rusticola Zzz2é Woopcock. The Woodcock has been known to breed in Hillsborough Park since 1844 and still nests there in considerable numbers. In Winter many immigrant birds inhabit the district. Size of eggs 43°51 x 33°49 mm. ; average weight of full eggs 25°157 gr., of empty shells 1°4 gr. Gallinago gallinago (Zzzne). Common SNIPE. A common breeding species, nesting as a rule in comparatively dry situations, 7.e., in rushy meadows or bracken-clad uplands. Average size of eggs 39°81 x 27°69 mm. ; average weight of full eggs 14°477 gr., of empty shells ‘8357 gr. Limnocryptes gallinula (/zc). Jack SNIPE. A regular Winter visitant, as obtains elsewhere in the British Islands. Nat. Hist. of Ireland, Vol. 1, p. 141. 2 Ibid, p. 146. Belfast Natural History and Philosophical Society, 1920-21. - Was x Re”, Woopcock on Nest, Hittsporoucn Park. G. G. McCready. Photo : The Birds of Hillsborough. 35 Totanus totanus (Zinné). RepsHanK. The Redshank nests in small numbers in meadows adjacent to Lough Aghery, and occurs in the lower-lying northern portion of the district oceasionally in Winter. Average size of eggs 46°41 x 31°75 mm. ; average weight of full eggs 22°612 gr., of empty shells 1°23 gr. Totanus hypoleucus (Z2é). Common SANppieEr. A regular Spring migrant, arriving about the Ist of May, and nesting in small numbers. Average size of eggs 37°85 x 26°67 mm. ; average weight of full eggs 13°258 gr., of emipty shells °58 er. Numenius arquata (Z7vn2é). CuRLEW. The Curlew’s whistle as it flies overhead has been here noted in every month of the year except January. It is also not uncommonly seen feed- ing in the fields. Charadrius apricarius Ziuné. GoipEN Plover. A regular Winter visitant in small numbers, usually consorting with flocks of Lapwings. Vanellus vanellus (Z27¢). Larwina. The Lapwing, Peewit or Green Plover, is a resident'and numerous species breeding both in the higher southern and lower-lying northern parts of the district, but in Winter for the most part forsaking the former regions. Average size of eggs 47°19 x 32°97 mm. ; average weight of full eggs 25°819 gr., of empty shells 1°478 er. Hzematopus ostralegus Ziuné. OysTeR-CATCHER. An unexpected incident was the sight of an Oyster-catcher at Munroe’s Dam on 26th June, 1919, where also a few days previously a Redshank had been observed. ‘This bird nests at Lough Neagh, and it may well be that the one seen was on passage from thence to the sea coast. Order LARIFORMES. Family LARIDD. Larus canus Linxwé. Common GULL. A regular Winter visitant (October till May), feeding in the fields and often following the plough, but has also been observed in July and August. Larus argentatus Pontoppidan. HeERRING-GULL. The Herring-Gull has been seen in every month of the year but is much more numerous in Winter. The majority of the birds frequenting the district are in immature plumage. Larus fuscus affinis Reinhardt. Brirish Lesser BLACK-BACKED GULL. A single bird of this species seen in 1903 constitutes the only record for the district. This is somewhat strange as this bird may constantly be observed at Lough Neagh only some 10 miles distant. 36 Nevin H. Foster on Larus ridibundus JZzuré. Buack-HEADED GUEL. The Black-headed Gull may be seen in the district the year round and in Winter in large numbers. Thompson states* that about the year 1803 a number of these birds took possession of an islet in Lough Aghery as a breeding place and drove out the Herons and nested for several years afterwards to the number of many hundreds, their nests almost covering the whole islet. This apparently continued till about 1832 when they were in their turn evicted, it is said, by the persecution of Hooded Crows. In July, 1905, the Rev. Allan Ellison and the writer found on the Willow trees overhangiug the water of Hillsborough Park Lake about 20 nests built of sticks and placed on the branches usually about a foot above the surface but some almost touching the water, which they believed belonged to this species. Certainly at the time there were about 100 Black-headed Gulls about the lake, the majority of which were birds of the year. The gamekeeper informed us that two pairs had nested there the previous year. Since then they have not bred there. Sterna hirundo Zizxé. Common TERN. A pair, sometimes three, of these birds usually frequent Hillsborough Park from May till July, and may occasionally be seen at this season on some of the ponds in the district. These do not appear to be breeding birds as no nest could be found, nor were any immature birds ever seen. Order PROCELLARIIFORMES. Family THALASSIDROMID. Thalassidroma pelagica (Zzzé). Srorm-PErTRet. Thompson records} that after a hurricane on 7th January, 1839, two of these birds were found dead near the Castle, Lisburn. Oceanodroma leucorrhoa Salvin. LeEAcH’s PETREL. For the inclusion of this species we are indebted to Thompson, who Statest that in the Winter of 1831 a specimen was found dead—but in excellent condition and plumage—near Lisburn. [It may here be stated that the second example found in Ireland of the American Wilson’s Petrel, Oceanites oceanicus (Kuhl), was taken alive after the great storm of September, 1891, near Dunmurry, only a little more than two miles outside our district. | Order PODICIPIDIFORMES. Family PODICIPID Ad. Podiceps cristatus (Ziuné). Great Crestep GREBE. To the district we can only regard this bird as a Summer visitant, though Thompson says§ that a pair of them remained on the lake in Hills- * Nat. Hist. of Ireland, Vol. Il, p. 146. +t Nat. Hist. of Ireland, Vol. Il, p. 428. { Nat. Hist. of Ireland, Vol. 111, p. 415. § Nat. Wist. of Ireland, Vol. i, p. 175, The Birds of Hillsborough. 37 borough Park during the Winter of 1847-48. Usually arriving in March, it has been known to nest on Hillsborough Park Lake, Lough Aghery and McKee’s Dam. It appears probable that in some years it does not visit the district. Average size of eggs 51°33 x 34°5 mm. ; average weight of full eggs 32°14 er., of empty shells 3°375 gr. Podiceps fluviatilis Tunstall. Lirrne GREBE. A common resident, only leaving the district when severe frosts cover its haunts with ice. It is locally known as the ‘‘ Diver.” Average size of eggs 38°58 x 25°78 mm. ; average weight of full eggs 13°063 gr., of empty shells 1°1917 gr. Order RALLIFORMES. Family RALLID 2. Rallus aquaticus Zizné. Warrr-Ratn. A resident in considerable numbers, though seldom observed owing to its skulking habits. The nest of this species is well concealed and is almost invariably placed among wet surroundings. In December, 1908, and again in February and November, 1909, the unusual sight was witnessed of one of these birds perching in a Willow tree growing at the margin of the lake in Hillsborough Park. Average size of eggs 35°28 x 25°93 mm. ; average weight of full eggs 12°408 er., of empty shells 9122 or. Crex Crex (/zuné). Corn-Crakk or Lanp-Ratn. A common Spring migrant arriving about the middle of April (earliest 14th April, in 1918). A specimen of this species was shot near Hills- borough on 20th February, 1905, and is in the writer’s possession. Average size of eggs 36°86 x 26°47 mm. ; average weight of full eggs 13°539 gr., of empty shells “834 gr. Gallinula chloropus (Zz). Moor-Hey. Resident and very common. Locally known by the more appropriate name of “‘ Water-Hen.” Although its usual nesting place is on the ground, or in vegetation growiug in or extending over and close to the water, its nest has more than once been seen here in a high hedge or in an Alder tree at an elevation of about 15 feet. Average size of eggs 44°04 x 31°22 mm. ; average weight of full eggs 23°085 gr., of empty shells 1°9447 gr. Fulica atra Linné. Coor. Usually called ‘“‘Bald Coot” this bird is resident and eommon. Average size of eggs 51°94 x 36°04 mm.; average weight of full eggs 39°8795 gr., of empty shells 3°4 gr. 38 Nevin H. Foster on Order COLUMBIFORMES. Family COLUMBID i. Columba cenas Liuné. Srock-Dove. vesident in small numbers. Average size of eggs 36 x 28°6 mm. ; average weight of full eggs 17°142 gr., of empty shells 1°25 gr. Columba palumbus Z7zzzé. Rixe-DovE or Woop-PiGcEon. Resident and common. In some Winters large flocks of immigrant birds frequent the district. Average size of eggs 39°78 x 28°65 mm. ; average weight of full eggs 18°13 gr., of empty shells 1°261 gr. Streptopelia turtur (Zévné). Turrin-Dovn. A specimen (in the writer’s possession) was shot about 2 miles from Hillsborough on 24th May, 1904. On dissection it proved to bea female ‘with eggs in the ovary. Order GALLIFORMES. Family PHASIANIDAL. Phasianus colchicus Zzzné. Pupasant. The Pheasant is listed as P. colchicus, though since the introduction of the Chinese Ring-necked, P. torquatus, into the British Islands, about a century ago, these species have been bred together, and being perfectly fertile ante se, it is evident that the present race is mongrel. It may be stated that there is no mention of the Pheasant in Ireland before 1589. In pre-war times large numbers of Pheasants were artifically hatched in Hillsborough Park, but numbers bred naturally in the Park and in the adjoining fields. Not infrequently a blue egg may be found in a nest of | normally-coloured eggs. Average size of egg, 43°74 x 36°17 mm. ; average weight of full eggs 31°095 gr., of empty shells 3°05 gr. [For many years a few Golden Pheasants, Thaumalea pieta, existed in a semi-feral condition in Hillsborough Park. Since about 1910 they have disappeared, but at present there are in aviaries in the district examples of this species, and also of the following :—Lady Amherst’s 7. amherstie ; P. versicolor ; Elliott’s Phasianus elliotti; Reeve’s P. reevesii; Silver HLuplocomus nycthemerus; Swinhoe’s #. swinhoit; Mantchurian Kared, Crossoptilon mantchurinum ; and Impyean or Monal, Lopophorus impey- anus ; some of which have bred in captivity here. It is hardly probable that any of these birds may escape and become acclimatised natives of the country. Should such occur the future historian may have the opportunity of including their names in the local avifauna. ] Perdix perdix (Zzzné). PARTRIDGE, Formerly not uncommon, it is probable the Partridge does not now inhabit the district. The last known nest was in 1904. Coturnix coturnix (Zzzze). QUAIL. Resident and common up till about 1870 the Quail or ‘‘ Wet-my-foot ” can now only be regarded as an irregular Summer visitant. For several years its presence had not been detected, but in 1896 its distinctive call was heard. In 1904 it appeared in considerable numbers, and since it has occasionally visited us. Average size of eggs 31°71 x 23°84 mm. ; average weight of empty egg-shells ‘8286 gr. _ PROCEEDINGS, c= 100TH SESSION 1920-1921. ; No. + = COURSE OF —— ‘LECTURES Of CHEMICAL STAN DPOINT.. _BY PROFESSOR A. Aoi STEWART, D.Sc. “aie PERCEPTION OF THE INVISIBLE, pes 1 BYE BEATTY, M.A., D.So. A COURSE ¢ OF FOUR LECTURES. ON ae Proceedings of the Belfast’ Natural History and Philosophical Society, 1920-1921. 19th and 26th November, 2rd and 10th December, 1920 PROFESSOR GREGG WILSON, PRESIDENT OF THE SOCIETY, IN THE CHAIR. A CouRSE OF FOUR LECTURES ON THE GROUNDWORK OF THE UNIVERSE FROM A CHEMICAL STANDPOINT, By Proressor A. W. Stewart, D.Sc., Professor of Chemistry, Queen’s University, Belfast. In CHEMICAL LECTURE THEATRE, QUEEN’S. UNIVERSITY. I.—THE FOUNDATION STONES OF MATTER. One of the common actions of the human mind is the search for intrinsic resemblances between things which on the surface exhibit differences in character. ‘Thus the chemist seeks to identify common characteristics in a group of materials, each of which differs from the others in its surface appearance. The great aim of the chemist is simplification, the breaking up of matter into forms which cannot be further decomposed. Thus water can be decomposed into two gases, oxygen and hydrogen, and neither of these gases has been further decomposed, so they are called “Elements,” and to-day we recognise ninety-two such “Chemical Elements” as capable of existence. These elements are built up of particles called atoms, almost indefinitely small, the atoms in any one element being all alike in chemical properties; but the different chemical elements vary because of the different characters of the atoms from which they are formed. Since these atoms are material bodies, they must have definite 49 A. W. Stewart on masses and occupy definite volumes, so that we speak of the ‘atomic weight” and the “atomic volume” of an element. In 1815 Prout suggested that the atoms of all elements are built up from those of hydrogen, which is the lightest known body. For almost a century Prout’s views were rejected by the scientific world, but recent work tends to establish this hypothesis upon a more solid basis. Towards the classification of these ninety-two elements the earliest definite work was due to the English chemist, Newlands, while at a later date, and apparently independently, Mendeléef and Lothar Meyer developed the system into its present form. Suppose that the elements are arranged in ascending order of the weights of their atoms, and that alongside the names of the elements we place first the nature of the element and second the number of hydrogen atoms which one atom of the element will combine with or will displace from combination. We then get the following arrangement :— TABLE I, Number of Hydrogen Atomic Weight Atoms combined with correct to the Element. Nature of Element. or displaced by one nearest unit. atom of the element. 4 *Helium Inert gas 0 7 **Tithium Light soft metal 1 9 ***Beryllium Heavier tough metal 2 el Boron Non-metal 3 12 Carbon Non-metal 4 14 Nitrogen Gas, not reactive 3 16 Oxygen Gas, reactive 2 1S Fluorine Gas, very reactive i 20 *Neon Inert gas like helium 0 23 ** Sodium Metal like lithium i 24 ***Maenesium Metal like beryllium 2 An examination of the above Table brings to light a certain order in the arrangement. Thus helium, the first element, has properties similar to those of the ninth element, neon ; the second The Groundwork of the Universe, &c. 43 element, lithium, shows an analogy with the tenth element, sodium ; whilst the third and eleventh elements, beryllium and magnesium, also show a close resemblance in properties. (The similar elements are indicated by one, two and three asterisks). Thus we can say that every eighth element in the series will have similar chemical properties, and that by such an arrangement we obtain a regular periodicity. The same type of element recurs at regular intervals in the series as in the notes of the musical scale, from which analogy Newlands called his system the ‘* Law of Octaves.” A further periodicity is seen in the number of hydrogen atoms which one atom of an element will displace from combination, the figures rising regularly from zero to four and thence falling as regularly again to begin a new series with another zero. The following Table shows the system of classification now adopted :— ‘sotqaadoad [ROW [VdI1}UApT IAB] TOLYA JO [TV ‘wntuyo.e -OIpel pus ‘1 Y-UINTURAN “tUNLOT}-OIpRl SUMITOL StuNnLIoTy :dnoas oy} syueseadesr tuntaoyy snyy, ‘sedoyost jo duoas yore Fo sroquam ay [1% epujour 07 aovds yonut 003 Kdnos0 ppnoa 41 se ‘oTquy, ey} Jo Javed aamoy oy] Ut sovjd Yova 10F UMOYS SI JOU eAtqovoIpeaA oUO KTACG, “QUIJONY YIM SUOTL UOLYROYISSLO S}L OF PRET FYSLUU YONA poonppe Noeq savy suosved YSnoY} ‘tuniygl] eoqe peov]d souttzoruos st TOT A ‘uasoapAy 0} pausisse usaq svy uorgtsod ON ‘sOze aI} JO SIYSIomM aavyed oyZ ATozvartxoadde or1d saurvu oy} dopun sssquuu oyy, _—F @ 8EG 4 V G&G 4 9GG GCG = = — — UNIURAQ Z—XQ| wanoyqy) unmpoy! wnipey — UOLNT 0806 G LOG 0 V0G 9006 G LOI — umniuopog | ygnusiq | prey wniyyeqy, | fanosapy | ploy 6 C61 T1661 6061 OFST Gist erie LET S'GEL G OSI ways, = warply TUNIS) -— uayssung, | wnzeqguey, | ¢90d9 HLYVd Sava AHL) = wuniieg | wniseseg| uousy 6941 CLE GO0GI L Sit STII Pell 6°LOT aurpoy =| umes, |Auowmuy | ary, tunipuy = | warped | aeaqtis L901 6 GUI L101 96 1 cis) 9°06 L’88 9°18 G°g8 6°GS wMIpryed = warpoyyy,— wanuayyNy — |unuepysopy fmiquinjog} tuntaoarz | wnt 4 | wus | wurpiqny | uojd&axyy 6°6L G'6L OGL Gol 6°69 VS9 91S9 auiuoarg =| wmiuaTag otuasay — fluntueiudey| MTR) — | OUT saddog L’8S 06S 8'°G¢ 6 FS O'GS 01S LSP LPP 0'OT 168 66E [PON qBqOD uoay jaseursuryy| weimoayy} warpeur, | wniuegip | warpuesg| umrore9 | wurssejog | uotay GGe 0'CE OTE £86 T'Lz 6G 0°&¢ G06 dULIOTYO anyding = |snaoydsoyg) uooipig § ftuntotwnpy|untseasepy}| uinrpog uoaN 061 09T OFFI OGI OTL 16 69 OFT ation iy uaBAxQ uasoaqginy | uoqaed uoiog =| wuqpsaog | wayyy | wniyay TIA TULA TA “A “AI Ti ut 1 0 NOU) taowy AOU) adn0u') anor) IN0Uy) In0ury anouy dou ‘SENGNGIG HHL JO INGNMONVULY OIGOMAd AH, Tl WIavi, The Groundwork of the Universe, &c. 45 Hydrogen has been omitted from the table on account of the difficulty in placing it properly. From its chemical properties it should be situated above lithium, but for physical reasons it seems allied to fluorine at the other end of the line. The table is so arranged that the vertical columns contain those elements which show a family resemblance to each other in their properties. Thus the inert gases are ranged together, and in the next column we find lithium, sodium, potassium, rubidium and caesium showing close family likenesses, while with them are copper, silver and gold which have many chemical characteristics in common with the other five. This periodicity is also found in the volumes of the atoms. The curve at the end of this section shows a regular periodicity in volume and in other physical properties, when arranged in the same order as in the Table. From this arrangement we get the conception of an ‘atomic order” in which hydrogen is the first element, helium the second, lithium the third, and so on to uranium, which is the ninety- second. The place which the element occupies is called its atomic number. When the rays from the cathode of a Crookes’ vacuum tube are allowed to fall upon a specimen of an element, an X-ray is produced, and the wave-length of this ray is characteristic of the: element. Moseley has shown that the wave-length is reciprocally proportional to A(V—1)*, in which A is a constant and N the atomic number of the element used. We can thus calculate the atomic number of the element and establish its place in the periodic system by this measurement alone. If from a complete series of such measurements we find any blanks in our table, we are able to say where the corresponding unknown elements will take their places when actually discovered. Moseley found there were five blanks upon the roll: (1) between molybdenum and Ruthenium; (2) between tungsten and osmium; (3) between polonium and niton; (4) between niton and radium; (5) one in the rare earth group, which is not shown in Table II. When 46 A. W. Stewart on this result is compared with Mendeléef’s table it is seen that blanks were actually left by Mendeléef at these very points. Thus two lines of evidence, chemical and physical, indicate that there are still tive elements to be discovered. In support of such forecasts we know that in 1871 scandium, gallium and germanium were unknown, but Mendeléef, from the gaps in his table, predicted the fact of their existence and even their very properties with amazing certitude. TABLE III. Prediction (1871). Properties of Germanium (1886). Atomic Weight = 72. Atomic Weight = 72:5. Grey Metal, hard to fuse. Grey Metal, fuses 900°c. Specitic Gravity = 5-5. Sp. G. =5:469. Density of Oxide = 4:7. Density of Oxide = 4-703. Volatile liquid Chloride, boiling Chloride is a volatile liquid, at 90°C. with density of 1-9 boiling at 86°C. density 1-887. Easily forms volatile Fluoride. Fluoride volatile. Thus from consideration of his periodic table Mendeléef was able to predicate the existence of an unknown element and even to forecast its properties with wonderful accuracy. He was equally successful with the other two elements, scandium and gallium. These examples show the extreme importance of the classification in the Periodic Table. The actual causes of these variations are not yet known, but in the future we may learn something of the laws which have been thus revealed. [To indicate the resemblances between members of the same group of elements many experiments were shown, among them vacuum tubes of the rare gases, tints imparted to a Bunsen flame by the presence of lithium and its congeners, while other resemblances were illustrated by the formation and non-formation of precipitates on the addition of certain reagents. | HIG. REFRACTN Soon 10 ad oe ~~ pe M.P. aBo .. BEG WE 8S G [Se eae ag a | ; : y { Me Am } \ ! \ iz / \ ri \ ¥) ' y | / \ = : ! 1 S 1 | \ S j sf ! 1 ; \ A | | : ; \ : \ ® i \ NX ! S Bi Th : NY UX> X ih (Col Salts : 8| 82 83 84 85 86 87 88 89 90 91 92 tydroxides clectro ne wale Sih Se NY) SRA a, eae See oe Low Malleable Brittle Malleable Brittle Malleable Brittle Malleable Brit tle Malleable Malleable Bri ttle Malleable Malleable e 2 Brittle Malleable MP.apove 1000°Abs. = s WP.eeLowi000°Abs. 3 ———_——————— —SSSSS==== Se = _ a | ————— | — — From “Recent Advances in Physical and Inorganio Chemistry,” by Professor A, W. Stewart, DS Col Salts be 70 60 y N 50 N 40 30F \ = 20 8 K X 10 0 Coloured Salts Coloured Salts Coloured Salts Col Salts: Coloured Salts bese | _—— los sere! NOMIC NUMBERS 123456789101 2 8 4 & [6 17 16 19 2021 22 2 2% 25 26 27 26 29 30 3) 32 33 34 35 36 37 38 39 40 41 42 43.44 45 46 47 48 49 50 SI S253 S455 56 ST S859 60 Gl 62 63 GF 65 66 67 68 69 70 7] 72 73 74 TS 16 77 7879 BIN 82 83 8 8S 86 87 6B 89 90 91 92 = = —_- =z == SS EEE a ool 7 both acid and alkali ma ZEEE [iscscocevesorasecsscsisissesssert) [oss) The Groundwork of the Universe, &c. 47 I.—THE RISE OF RADIO-ACTIVITY. The beginnings of the science of radio-activity must be dated from 1879, when Sir William Crookes published the results of his investigations upon the passage of an electric discharge through highly evacuated tubes. Previous to this time it was known that a spark passed between two electrodes at atmospheric pressure became broadened out into a columnar formas the pressure became reduced, so that when a discharge was passed between the electrodes of a tube containing a gas at a moderately low pressure, the whole tube glowed brilliantly. Crookes showed that when the evacuation is carried to a very high degree and only a very slight amount of residual gas remains in the tube, the glow vanishes and the interior of the tube becomes almost non-luminous. At the same time a green fluorescent light makes its appearance on the glass of the tube opposite the cathode. Certain “rays” originate at the cathode, leave its surface at right angles and travel in straight lines through the tube until they impinge upon the glass, the green fluorescence occurring at the points of impact. The following evidence determines the character of these rays. They leave the cathode only on the side nearest the positive electrode, and do not spread in all directions like the radiations froma heated body. If an aluminium cross be interposed in the path of the “rays” a shadow of the cross is thrown on the patch of green fluorescence, showing that the “rays” are either vibrations like light or are streams of particles. If a tiny windmill be placed in the path of the “rays” it spins with great velocity, in a manner not to be explained by “light pressure,” but easily understood if there be a stream of particles. But the “rays” can be deviated from their straight path by means of a magnet or an electric field, which indicates that they are jets of particles each carrying an electric charge. These charges are negative when examined by an electroscope. Finally, investigation shows that these particles have, almost 48 A. W. Stewart on certainly, a mass seventeen hundred times smaller than a hydrogen atom, and that they are really corpuscles of negative electricity which we call electrons. But another set of phenomena has been observed in the Crookes’ tube. If the cathode be pierced with a series of apertures, a second set of “rays” makes its appearance, travelling in the direction opposite to that of the cathode rays. These are shown to be — streams of the molecules of the gas in the tube, each carrying one or more positive charges, being named for this reason “ Positive Rays.” In the dark they can be seen as faint pencils of light traversing the tube. There is still a third type of “ray” observable, the X-rays. These are rays of light of extremely short, wave length, related to ordinary light as a note in the treble of a piano is to a note in the bass. They are produced by the impact of electrons upon matter, and in the Crookes’ tube they originate where the cathode rays strike the glass of the tube. They have the power _ of making the air through which they pass a good conductor of electricity. Both Dr. R. Beattie and Dr. P. T. Crymble, of the Queen’s University, have made valuable contributions to our knowledge in this sphere, the one in pure Physics, the other in the applica tion to medical and surgical problems. In 1896, the French scientist, Becquerel, was struck by the resemblance of the green fluoresence of Crookes’ tubes to the fluoresence of certain salts of uranium, and it occurred to him that these salts might be emitting ‘X-rays. We know now that his analogy was erroneous ; but when he tested these salts by the photographic method, he found that there actually was an emission of X-rays. This discovery by Becquerel opened up an entirely new field of research, lying within the borders of both Chemistry and Physics ; and at once there was a rapid extension of our knowledge. Other elements, such as thorium, were found to be radio-active, this being easily demonstrated by laying a 49 The Groundwork of the Universe, &c. SQOHLVD As0NTZId SAVY BAILISOd SAVY JGOHLVDS SAVY -X - 50 — A. W. Stewart on broken fragment of an incandescent mantle, containing oxide of thorium, upon a photographic plate and leaving it in the dark for a week, On development the plate will show the reticulations of the mantle. Soon the new element actinium was discovered, and Mme. and M. Curie isolated the salts of radium from pitch- blende. After months of laborious work it was shown that radium was chemically closely related to barium, since it was extremely difficult to separate these two elements, though it was com- paratively easy to isolate the radium-barium group from all the other elements in pitch-blende. Some idea of the labour involved may be got from the fact that from one ton of the material less than the thirtieth of an ounce of very impure radium salt was obtained. The chemical resemblance between radium and _ barium shows they belong to the same group in the Periodic System, and itis seen that radium les just below barium in Group II of this classification. The other radio-active elements have positions in the table between lead and uranium, so that their atomic weights are all high. Potassium and rubidium form exceptions, and investigation in their case is still incomplete. It is found that radium compounds have properties different from those of other elements. They break up water just as electricity does ; their temperature is always slightly higher than that of their surroundings ; they colour glass vessels in which they are kept, and they give off the “rays” which are called Becquerel rays. Finally, radium salts emit a radio-active gas, niton, which will be dealt with in the next lecture. A simple experiment shows that no less that three types of “ray” are emitted by radio-active materials. A sample of a radio-active salt is allowed to radiate upon an electroscope, and the rapidity of discharge of the electroscope is observed. If, now, a sheet of cigarette paper is wrapped about the salt, and the observation repeated, it is found that there is a marked diminution in the rate of discharge. Thus a fraction of the The Groundwork of the Universe, &c. il “rays” has been trapped and prevented from reaching the electroscope. Ifa second sheet of paper is added, it is found that the rate of discharge is unaltered, so it appears that the first sheet of paper screened out entirely some constituent parts of the “rays,” and that the part passing the paper penetrates a second sheet just as easily as the first. Thin lead foil causes stoppage of much of the radiation which passed the paper, but a second thin sheet has no further action. A heavy lead block, however, cuts off all the “rays.” Thus there are three constituents: one which passes the paper but not the lead foil, one which is stopped by the heavy lead block after passing through the lead foil, and finally those “rays” which failed to pass through even the paper. The component stopped by thin paper is called the Alpha- ray, that stopped by lead foil after passing through the paper, the Beta-ray, whilst the most penetrating component is the Gamma-ray. To put the matter in the form of a diagram we have some- thing like Fig. II as a representation of the experimental results. TISSUE PAPER. LEAD FOIL. LEAD BLOCK D > g ce) > a es < nm wo fe) c be) 0 m A. W. Stewart on or bo When a magnetic field is applied to a thin pencil of the Becquerel rays the pencil is split up into three different sprays as shown in Fig. III. J -rays &- rays B-rays LEAD PLATE RADIOACTIVE SOURCE The Gamma-rays are almost unaffected by the magnetic field ; the Alpha-rays are slightly deviated, while the Beta-rays are more strongly affected. The Alpha rays are deflected on to the right, the Beta to the left of the original direction, which the Gamma-rays continue to pursue, unaffected by the magnetic field. The Groundwork of the Universe, &c. 5p Recall now the three types of ray from the Crookes’ tube, the Cathode-ray, the Positive-ray, and the X-ray. Each of these has the same qualities as one of the constituents of the Becquerel rays, corresponding as below :— Zecquerel Rays. Crookes’ Tubes. Alpha-rays, Positive-rays, Beta-rays, Cathode-rays, Gamma-rays, X-rays. The Alpha-rays are atoms of helium, each atom carrying two charges of positive electricity; the Beta-rays are streams of negative electrons, while the Gamma-rays are really X rays having a penetrating power far in excess of any we can_ produce arti- ficially. Some idea of the enormous velocities of emission may be got from the following figures :— Alpha particles vet 20,000 miles per second. Beta KS eM Ash FORO OEs ge 5 Light MOLSGOOO'' ef A little reflection will suggest the reason of the phenomena observed in radio-active centres. The Alpha particle, ejected from the radio-active atom ata very high velocity soon strikes some heavier matter in the form of atoms in the radio-active mass and heat is thus generated, so that these helium atoms will tend to raise the temperature of the material with which they collide, and keep it permanently above that of surrounding bodies. Again, radio- active materials eject showers of electrons travelling much faster than the Alpha particles. When these strike matter they generate X-rays, as the cathode stream of a Crookes’ tube did at its point of contact with the glass, so that there is a complete parallel between the action of the Becquerel rays and that of the Crookes’ tube. To sum up the properties exhibited by the Becquerel rays as a whole—They have the power of ionizing gases and making 54 A. W. Stewart on them conduct electricity readily ; they produce photographic effects upon sensitive plates, even through cardboard ; they cause zine sulphide to glow strongly, as is seen in the ordinary luminous watch or compass ; they colour glass violet or brown according to its chemical composition, and they have a powerful disintegrating action on vital tissue. This last property is utilized in radium therapy, which is successful in the case of rodent ulcer and similar diseases. The radio-active material, usually the gas iiton, is enclosed in a tiny tube within a silver sheath and introduced into the wound. The violent action of the rays destroys the diseased tissue, and it is possible for fresh healthy tissue to grow in its place. There is another property of radium which requires atten- tion. The radium atoms are constantly breaking up, so that, although radium is an “ element,” it is not a permanent body. Half disappears in 1,350 years, so that in 2,700 years only one- fourth will be present, and in another 1,350 years only one- eighth. If, then, there is now in existence one gramme of radium, and if it be the descendant of a pre-existing mass, this mass, no longer than 140,000 years ago, must have been as large as the earth, a conclusion which all the facts of geology show to be absurd. It must therefore be assumed that radium has a parent, from which it is being continually derived. Just as the gas niton is a descendant of radium, so is radium itself a product of ionium, which is in turn descended from yet another elementary form of matter. Thus a certain family relationship among the radio-active elements can be traced, which will be dealt with in the next lecture. In conclusion, it seems worth while to draw attention to the immense practical benefits which have followed the investigations in this one field of research, investigations which have their origin in University laboratories, and which were undertaken only from a pure love of knowledge for its own sake. The Groundwork of the Universe, &c. 55 The discovery of the X-rays, with all their modern applica- tious to medical and surgical problems, arose directly from Sir William Crookes’ desire to know what results follow from the evacuation of tubes to a higher degree than had ever been tried before. The whole investigation of radium therapy arose from Becquerel’s study of the uranium salts, again a problem of a purely scientific nature, seeming then to have no practical bearing. The self-luminous compass, serving to guide our airmen in their night flying, and to permit our battleships to cruise in the darkness without showing a light, was the result of Sir William Crookes’ invention of the spinthariscope, designed to make visible the impact of the alpha particles by their action on zine sulphide. The search of knowledge for its own sake and without ulterior motives actually lays the foundation for the most unexpected and valuable practical applications. | No applied chemist would ever have dreamed of searching for a radio-active material before Becquerel’s discovery, nor would he have thought of devising an apparatus by means of which the bones of the living hand could be examined, until the X-rays were actually discovered in a laboratory. The words of Huxley are true to day as when spoken, “I would make accessible the highest and most complete training the country could afford. Whatever might be the cost, depend upon it the investment would be a good one. I weigh my words when I say that, if the nation could purchase a potential Watt, or Davy, or Faraday, at a cost of a hundred thousand pounds down, he would be dirt cheap at the money. It is a mere commonplace and every day piece of knowledge that what these three men did has produced untold millions of wealth, in the narrowest economical use of the word.” With this in view it is right to acknowledge with gratitude the generosity of Mr. F. A. Heron, who has presented to the Queen’s University a most munificent gift for the proper equipment of a department for Physical Chemistry, and has thus enabled the University to furnish Ulster students with a training in this 56 A. W. Stewart on most important branch which will allow them to compete on even terms with graduates from other Universities. It is especially appropriate that the Heron gift should have been devoted to a branch of Chemistry with which the name of Belfast is connected. through the fame of Andrews. II.—THE TRANSMUTATION OF THE ELEMENTS AND KINDRED PROBLEMS. In the first of this series of lectures, it was tacitly assumed that what we call “chemical elements” are forms of matter which exist unchanged through their history and which are not capable of decomposition into simpler materials. With the second lecture in the course, following the historical development of the subject, it was found necessary to modify this view in order to bring it into line witb modern work on the radioactive elements: for these forms of matter have been found to disintegrate spontaneously into simpler substances, though the experimental resources at our disposal fail to initiate such decompositions among the non- radioactive elements or even to influence the rate at which the radioactive elements disintegrate. In the present lecture, the subject will be brought up to date and the discoveries of the past year will be described, which show that even this voluntary break-down of certain elements is possible at the present time. But before entering upon this field, it may be well to go back to the beginning of the century, when Sir William Crookes was investigating the radioactive properties of the element uranium. Crookes found that a certain specimen of uranium showed marked radioactive character ; but when he applied the processes of chemical analysis to it, he was able to separate it into two parts. The one portion showed strong beta-ray activity (like the parent specimen) ; but the second portion exhibited no beta-ray activity whatever. After being left aside for some months, however, the non-active specimen was found to have acquired radioactive pro- The Groundwork of the Universe, &c. 57 perties and to display considerable beta-ray activity. These results are expressed in the following scheme :— ORIGINAL — URANIUM.” (Gives off B-rays) | | URANIUM-1 URANIUM-X, (Emits no B-rays) (Emits B-rays) On standing \ URANIUM-Xy (Emits B-rays) There is nothing abnormal in the separation of “ uranium ” into two fractions, one of which is radioactive whilst the other is inactive ; for the radioactive material might be there as an impurity in the original mass of “uranium.” What ds extra- ordinary is the fact that after all the racioactive impurity is removed, the remaining inactive material gradually becomes again radioactive. This is practically parallel to the complete removal of silver from a lead-silver alloy and the slow reappear- ance of silver after a time in the carefully purified lead. It can be accounted for only by assuming that the substance uranium-1 is breaking up and giving rise to a new element, uranium-X,, which possesses beta-ray activity. The phenomena mentioned in the last lecture in connection with radium throw further ight upon the matter. Radium, it was found, gave off continually a gas, niton, which has radio- active properties different from those of radium itself. Here, obviously, since both radium and niton are known to be ele- mentary forms of matter, we have the case of one element giving birth to another ; and the older idea of the permanence of the elements has received a severe shock. When the chemical properties of niton were investigated by Sir Ernest Rutherford and Mr, Soddy, it was found that they 58 A, W. Stewart on formed an,exact parallel to those of the inert gases of the atmos- phere discovered by Sir William Ramsay. Niton refuses to com- bine with any other element, even when heated to a red heat in the presence of reactive metals. It thus shows itself akin to argon and its congeners of the Zero Group in the Periodic Table. But while thus chemically inert, niton is very powerfully radioactive. When it is dissolved in water, it decomposes the liquid into oxygen and hydrogen, just as the electrodes of a battery do. It sends out a very intense stream of alpha-particles, with all the properties which such emitted particles ordinanly display. It affects a charged electroscope when brought near to it ; and it causes a fluorescent screen to glow brightly when the gas is blown across the surface. In order to handle niton, special precautions had to be taken. In the course of the fundamental experiments of Sir William Ramsay and Mr. Soddy, the largest volume of niton obtainable was about 0-000,000,32 cubie inches; and the manipulation of this tiny bulk of gas was extremely difficult. In order to trans- fer the niton from vessel to vessel, it was necessary to mix the radioactive gas with a large bulk of air and then drive the mixture from its reservoir to the place where it was required. In this way the loss of a fraction of a cubic inch of the mixture only represented the mislaying of an immeasurably small quantity of niton. Sir William Ramsay, however, actually manipulated pure niton, unmixed with air. Working merely with the almost in- visible volume mentioned above, he and Dr. Whytlaw-Gray were able to liquify and solidify niton, determine its critical temperature and pressure, and study its behaviour under the microscope as it passed from state to state. In order to fix definitely the place of niton in the Periodic Table, it was necessary to determine its atomic weight ; and the only way in which that could be done was by the determination of the gaseous density of the element-——i.e., by weighing a known volume of the gas. The experimental difficulties in the way of The Groundwork of the Universe, &c. ag this were so great that it was generally assumed to be an impossible task ; but Sir William Ramsay and Dr. Whytlaw-Gray were not deterred by this idea: and they proceeded to construct a “microbalance” capable of weighing the extremely small quantity of niton available. This balance, when eventually con- structed (from quartz fibres) was so delicate that it turned with the weight of 0-000,000,04 ounces. Its construction marks the high-water mark of accuracy in weighing ever successfully per- formed. Of course, no weights could be prepared of sufficient refinement to use on a balance of this accuracy ; but Sir William Ramsay overcame this difficulty by utilising as his weight a glass tube filled with air at ordinary pressure, and by making his balance-case air-tight and capable of evacuation. When the air in the balance-case was at ordinary pressure, obviously the air in the “weight” had no effect ; but when the air was pumped out of the balance-case then the “weight” depressed the beam, because the air inside the glass “ weight ” was no longer equi- poised with the air outside the “weight.” Thus by measuring the pressure of the air in the balance-case, it was possible to calculate the exact “ weight” of the glass tube, plus the air inside it. By means of this balance the exact weight of the tiny quantity of available niton was ascertained ; and when its atomic weight was calculated froin this it was found that the atom of niton was 222 times heavier than a hydrogen atom—a figure which brings niton into the bottom of the inert gas column of the Periodic Table. It will be noticed that the word Niton has the same ter- mination as most of the other elements of the group. The name was given to it because of its luminosity. In the dark a tube of niton glows with a greenish-white lustre; and on this account Ramsay called it Niton—the shining one. It was originally termed “radium emanation.” The decay of the element niton is extremely rapid. In ninety-four hours half of it disintegrates, no matter what quantity we start with at first, In the next ninety-four huurs it falls again 60 A. W. Stewart on to half its quantity. Thus, if at the start there were sixteen grammes of niton present, the following figures give the amounts remaining in existence after various periods :— Start baie 16 grammes. After 94 hours a 8 grammes. After 188 hours 7 4 grammes. After 282 hours sa 2 grammes. After 376 hours ie 1 gramme. It is now necessary to deal with the work of Sir William Ramsay and Mr. Soddy upon niton. Hitherto, though the change of one element into another had been well-established—as has been described above—both the parent and the descendant ele- ments had belonged to the radioactive group, which at that time were regarded as forming a class apart from the ordinary chemical elements. Sir William Ramsay and Mr. Soddy, however, brought the matter into a new orientation by proving that niton, in the course of its disintegration, produced a perfectly well-known element, helium. This formed the first link connecting the radio-elements with the common non-radioactive series of ele- mentary materials known to chemists. Suppose that we had, enclosed in a glass tube, some niton, and that we were able to measure the pressure of the gas within the tube from day to day. ‘This was actually done by Sir William Ramsay and Mr. Soddy ; and, somewhat to their astonish. ment, they found that the pressure diminished as time passed. Finally, on examining the spectrum of the contents of the tube, they observed that the niton spectrum had disappeared completely, and had been replaced by that of helium. Further investigation shows that the walls of the tube have acyuired radioactive properties. That these properties are due to a solid deposited on the glass can be proved in various ways. For example, if the glass be scraped with a metal point, the metal in turn acquires the power of discharging an electroscope ; or again, by means of acids it is possible to dissolye from the glass The Groundwork of the Universe, &c. 61 some material which displays radioactivity. Thus niton clearly disintegrates and gives rise to some solid material, Radium A, which is also radioactive like its parent. The next question which arises concerns the helium found in the tube. Where does it come from? To discover this we must go back to the alpha-particles which form part of the Becquerel rays. These alpha-particles are helium atoms carrying two charges of positive electricity ; and since niton shows very strong alpha-ray activity, it is not hard to deduce that the helium found in the tube by Ramsay and Soddy was simply a collection of the helium atoms ejected from the niton in the course of its disin- tegration. Thus we may symbolise the break-down of radium and its descendants in the following way :— TABLE III. Solid RADIUM > HELIUM Gas Atomic Weight Atomic Weight 226 4 t Gas NITON > HELIUM Gas Atomic Weight Atomic Weight 999 4 od hed ead Solid RADIUM-A Atomic Weight 218 Thus the atom of radium, in disintegration, gives rise to an atom of helium and an atom of niton ; and the atom of niton is four units lighter than the radium atom, since the remainder of the weight of the radium appears in the helium atom, with atomic weight 4. In turn, the niton atom throws off four units of weight in the guise of a helium atom and the remainder of the exploded atom is the atom of radium-A, with atomic weight 218. The diagram above gives us the idea of a “ radioactive series,” that is, a series of elements each of which is born from one heavier than itself, and may give rise in its turn to some 62 A. W. Stewart on lighter element. Originally three of these series were assumed to exist, one starting from uranium, another from the element actinium, aud a third from thorium; but recent work by Pro- fessor Soddy has proved that there are only two, since actinium itself is a descendant of radium. The following Table IV shows the relations of the radio- elements, and gives some idea of the number of these unstable materials now known :— TABLE LY. THE RADIOACTIVE SERIES OF ELEMENTS. I.—TuHrE THORIUM SERIES. Atomic Average Rays Klement Weight Life Emitted Thorium 252 2-6 + 10'° years a Mesothorium-1 228 7:9 years B Mesothorium-2 228 8-9 hours B Radiothorium 228 2-91 years Thorium-X 224 5-25 days Thorium emanation 220 78 seconds 0. Thorium-A 216 0-2 seconds a. Thorium-B 212 15-4 hours B Thorium-C 212 87 minutes a and Thorium -C! ate) 10-1" seconds a. Thorium-D 208 4-5 minutes B End-product 208 Permanent No rays Norr.—Thorium D and Thorium C! are both disintegration products of Thorium-C which decomposes in two different ways. Il.—TuHrE URrANIUM-RADIUM SERIES. Atomic Average Rays Element Weight Life Kmitted Uranium-1 238 8 x 10° years a. Uranium-X, 234 35°5 days B Uranium X, 234 1:65 minutes B Uranium-2 234 3x 10° years a. The Groundwork of the Universe, &c. 63 Atomic Average Rays Hlement Weight Life Kmitted Tonium 230 2 x 10° years a Radium 226 2,440 years “ Niton 222 94 hours a Radium-A 218 4:3 minutes ‘pi tl Radium-B 214 38:5 minutes B Radium-C 214 28-1 minutes a and B At this point a branching occurs in the series. Radium-C disintegrates by two different processes, yielding respectively Radium-C' and Radium-C2. Each of these then disintegrates as shown below. Radium-C! 214 107° seconds a. Radium-D 210 24 years B Radium-E 210 7:20 days B Radium-F 210 196 days a. End-product 206 Stable No rays Radium-C, 210 1:9 minutes B End-product 210 Stable No rays II].—TuHE URaANiIUM-ACTINIUM SERIES. Average Rays Element Life Emitted Uranium-Y 2-2 days B Uranium-Z (Eka-tantalum) q a. Actinium 5,000 years B Radioactinium 28:1 days a. Actinium-X 16-4 days a. Actinium emanation 5:6 seconds Actinium-A 0-003 seconds a Actinium-B 52-1 minutes B Actinium-C 3:1 minutes a. Actinium-D 6-83 minutes _ B End-product Stable No rays Norre.—Uranium-Y is believed to be derived fram Uranium-1, but the exact connection has not yet been traced. The atomic weights in the actinium series have not been determined up to the present. 64 ‘A. W. Stewart on The actual positions of all these elements in the Periodic System were established for the most part by the work of Dr. Fleck, who carried out the most extensive investigation in this difficult region of the subject. Some idea of the complexity of the problem solved by him may be gained from the fact that certain of the elements which he examined fall to half their original quantity in an extremely short time. A gramme of radium-A, for example, will leave only half a gramme unde- composed after four minutes and twenty seconds. Thus Dr. Fleck had not only to cope with the normal difficulties of assigning to an element its proper position in the Table but in addition he had to work with the greatest rapidity if any measurable quantity of his material was to be left intact at the end of his experiments. On the basis of Dr. Fleck’s results, which were obtained in Soddy’s laboratory, Prof. Soddy put forward the generalization now known as Soddy’s Law ; but before the enunciation of this is given it may be best to examine a simple case which is already familiar to us. Radium belongs to Group II of the Periodic Table. In disintegrating, it ejects an alpha-particle and is converted into niton, which occupies a position in the Zero Group of the Table. Further, since the ejection of the helium atom entails the loss of four units of atomic weight, niton is four units lighter than radium. Thus in the case of what is called an “ alpha-ray change” the descendant element occupies a position in the column next-but-one to the left of the parent ; and the atom of the clescendant is four units lighter than that of the parent element. On the other hand, when an element changes into another by the ejection of an election (Beta-ray change), the descendant occupies a position one column to the right of the parent. The italicized text above gives the Soddy Law, which governs the character of the relations between the parent element and its descendant as far as the Periodic Table is concerned, The Groundwork of the Universe, &c. 65 Professor Soddy, however, was not content merely with the enunciation of this Law. He proceeded, as Mendeléef had done, to predict certain results which must follow if his views were correct ; and the fulfilment of his prediction has marked almost as great a stride forward in our knowledge of the atom as that which the Russian chemist made in connection with the relations between the elements. The stable product which finally results from the radioactive disintegration of uranium is a material having all the chemical properties of lead. The end-product of the thorium series is also chemically indistinguishable from lead. Now, in order to attain the stage of lead, as Professor Soddy pointed out, uranium has to eject eight alpha-particles ; whilst thorium yields lead by the ejection of six alpha-particles. Since each alpha-particle is a helium atom with an atomic weight of four, it is evident that the lead from uranium will have an atomic weight thirty-two units lower than that of uranium ; whilst the lead from thorium will have an atomic weight twenty-four units less than that of thorium itself :— Atomic Weight Atomic Weight 238-2 URANIUM THORIUM 232-4 Loss of Loss of —32 units eight atoms six atoms of helium of helium — 24 units | | 206:2 LEAD LEAD 208-4 oo Chemically indistinguishable. The Atomic Weight of natural Lead is 207-1. Basing himself upon these facts, Professor Soddy predicted that although the lead obtained from uranium and that produced by the disintegration of thorium were chemically identical with each other, their atomic weights would be different: that of the uranium derivative being 206-2 ; whilst that of lead from thorium would be 208-4. This prediction has been tested with every 66 A. W. Stewart on refinement of experimental skill by numerous workers ; and it has been proved to be correct. It is evident that this work of Professor Soddy’s re- volutionises our previous ideas of the elements. Hitherto it has been assumed that all the atoms of an element were identical with each other in every respect; but it is now conclusively established that two atoms, each of which has all the chemical properties of lead and each of which emits the same spectrum, have weights differing from each other by about one per cent. Since the two varieties of lead have identical chemical properties, they must both be placed in the same square in the Periodic Table ; and elements such as these are termed by Professor Soddy “isotopic elements ” from isos= equal and topos =a place. The two varieties of lead are said to be isotopes of each other. Thus These isotopes, in some cases, are found to have different radioactive properties, though chemically they are inseparable from each other. Thus thorium is inseparable from uranium — X4 by any chemical means; but when the two are examined by radioactivity tests it is found that uranium — X, loses half its activity in thirty-five and a half days, whereas thorium requires many millions of years to decay to the same extent. The recent work of Dr. Aston has shown that isotopy is not confined to the radioactive series of elements; for even such common elements as chlorine are found to be made up of mixtures of atoms of different weights though they are all endowed with identical chemical properties. Professor Soddy having thus established the existence of isotopy, it was my good fortune to call attention to the second half of the generalization upon which the modern classification of atoms is based. When a radioactive element parts with an electron in the beta-ray change, its atomic weight is unaltered, since in comparison with atomic weights, the mass of an electron is negligible. None the less, the loss of this electron produces a complete change in the chemical properties of the material. Evidently then, there may be two atoms of equal weights but The Groundwork of the Universe, &c. 67 with entirely different chemical properties. To such atoms, I gave the name isobares, from isos = equal and baros = weight. To illustrate the question of isobarism, the following data will be sufficient :— B-ray B-ray Mesothorium-1 ——— Mesothorium-2 —— Radiothorium Change Change AtomicWeight = 228 AtomicWeight = 228 AtomicWeight = 228 Number of Hydrogen atoms displaced by one Element atom of element. resembles. Mesothorium-1 2 Barium Mesothorium-2 3 Lanthanum Radiothorium 4 Cerium From the foregoing, the following possibilities are evident :— Two elements having identical chemical properties are zsotopiec. Two elements having different chemical properties are heterotopic. Two elements having identical atomic weights are zsobarie. Two elements having different atomic weights are heterobaric. By taking all the possible combinations of these in turn, the Soddy-Stewart classification of atoms is obtained :-— Atomic Weights Chemical Properties Isobaric Isotopes Same Same Isobaric Heterotopes Same Different Heterobaric Isotopes Different Same Heterobaric Heterotopes Different Different Thus by means of this system we are able to define the relations between any two atoms, whether they are of the same elemental character or not and whether their weights are identical or different. Leaving the work of the laboratory, it may be well to turn next to phenomena upon a far vaster scale. The resources of energy which the chemist and physicist have at their disposal are limited both in quantity and in intensity ; and it is necessary to examine certain astronomical evidence in order to gain a further knowledge of the behaviour of elementary matter under extreme 68 - A. W. Stewart on conditions. The views which are about to be described are due to Sir Norman Lockyer; and although they are not accepted m toto by the scientific world, they probably contain more than a grain of truth. When investigating the emission spectra of metals, Lockyer found that the character of the spectrum emitted by an element depended to a large extent upon the temperature at which the metal was examined. Thus in a gas-flame having a temperature of a few hundred degrees, a certain metal gave a characteristic spectrum; in the electric are, at a temperature of 3000°C, a different spectrum was exhibited by the same metal; whilst, finally, in the electric spark, which is supposed to have a temperature of sume 12000°C., the metal shows yet another type of spectrum. Lockyer’s examination of star spectra suggested to him that among the stars there are bodies at all sorts of different temperatures ; and he began to classify the stellar species into groups according to this property. At first sight it might appear to be impossible to determine which of two stars was the hotter; but the matter is not so difficult as it might seem at first sight. A simple example will make the matter clearer. Suppose that the complete spectrum were spread out by a prism as shown below :— Heat Rays—ReED—ORANGE— YELLOW—GREEN— BLUE— InpIGOo —VIOLET—ULTRA-VIOLET. Now assume that a piece of metal, such as a poker, is gradually heated. In the first place, it begins to emit heat rays while still remaining black to our eye. Next, it gradually turns red, showing that the red part of the spectrum is being radiated from it. With a further increase of temperature, its colour becomes lighter, because it is now radiating orange as well as red rays. A higher temperature makes it glow bright red, for at this stage it is throwing out every variety of ray from the heat-rays down to yellow ; and the joint action of all these produces on our eye the sensation of bright-red. Finally, if we still further raise the poker’s temperature, it The Groundwork of the Universe, &c. 69 becomes white-hot, which implies that it is radiating all the vibrations from the slow heat-rays up to the rapid waves of the violet. Clearly from this example it is evident that the relative temperatures of two pieces of heated iron can be gauged by the length of continuous spectrum which they emit: the further this spectrum extends towards the violet, the hotter the material must be. By an examination of the stellar spectra, Lockyer was thus able to catalogue the stars into various groups, the members of each group having approximately the same temperature. Basing his views upon this experimental evidence, Lockyer put forward what is known as his Meteoritic Hypothesis of stellar evolution. He assumed as a beginning, a swarm of cold meteorites travelling through empty space. As time passes, gravitation will act upon this swarm, gradually drawing the meteors nearer and nearer together; and the result of this process will be a series of collisions between the flying bodies and the consequent generation of heat. Imagine this process continued for a considerable period, and it is obvious that in the next stage of evolution we should find all the meteorites agglomerated together into a loose mass with a moderately high temperature. Still the force of gravity would act upon the material, tending to condense the mass more and more; and with the increasing condensation and consequent increase in the number of impacts between the particles, the temperature would continue to increase until finally the whole of the material would be a flaming mass of gas. At this point, it has reached its highest temperature ; and its subsequent history will be one of radiation and cooling. Slowly it falls in temperature, passing successively but in the inverse order through all the temperatures through which it travelled on the up-grade ; until finally it is reduced to a cold globe, a dead star. After classifying the stars according to his results, Lockyer found that in the dull, red stars, most of the ordinary metals were present (as was proved by means of the spectroscope) in the 70 . A. W. Stewart on same state as in the electric are and in addition there were signs of the presence of carbon. In the next hotter stars, no carbon was detected, but most of the metals were spectroscopically recognisable as being in the same condition as in the electric spark. In the next set, of still higher temperature, many of the metals were absent and the two elements hydrogen and helium appeared in considerable strength. Finally, im the hottest, gaseous stars, no metallic traces are found ; hydrogen and helium were strongly marked and in addition there were lines in the spectra which correspond to no elements known upon the surface of the earth. Lockyer symbolised this somewhat after the following fashion : i GASEOUS STARS. (Eydrogen, helium and unknown elements). 7 + HIGH TEMPERATURE HIGH TEMPERATURE ze o STARS STARS Z, < (Few Metals present) (Few Metals present) : oa IN V Fe B MEDIUM TEMPERATURE MEDIUM TEMPERATURE fe = STARS STARS 'S) = (Metalsin “spark” state; (Metals in “spark” state; : a No Carbon present) No Carbon present) 5 N\ V a = LOW TEMPERATURE LOW TEMPERATURE SS STARS STARS (Metals in “are” state; (Metals in “arc” state: Carbon present) ~ Carbon present) IN — Y COLD METKORS COLD STARS Y Thus according to Lockyer’s hypothesis, the stars present us with a picture of the evolution of the elements. At first there are the cold meteors, having a composition very like that of the Karth, ‘Then, with rise in temperature, due to inter-collisions The Groundwork of the Universe, &c. Aa between the bodies, a star is formed which contains most of the ordinary elements at a temperature somewhere between that of the electric are and the electric spark. A further continuance of the evolutionary process yields stars of a temperature at least as high as that of the electric spark ; and in the hotter stars of this group carbon apparently ceases to be capable of existence, since it vanishes from the spectra. : fraction —— should vary as the sine of the angle, unless other. D The Evectness of Plants. 101 factors are also acting. The same explanation may be applied to the angles of stem-branches and of leaves. This extension of the theory was taken up by Miss Lynn and the writer’. The angles, lengths and distances were measured in various plants. The results for root branches of the pea, and for the stem branches of privet, cherry laurel, dock, yellow cress and horse-tails were found to be in accordance with the theory, when an allowance of 10° on either side of the theoretical angle was made. Considering that many other as yet unanalysed factors may act in the growth of such branches, a deviation of ten degrees in either direction is quite a moderate ‘experimental error” on the part of the geotropic orientating mechanism. ‘The data for leaves were not so satisfactory, and the regular action of other factors was indicated. This was explained when Dr. Harold Wager informed us that from some unknown cause” young leaves grow more on their under sides and old leaves grow more on their upper sides. When these interfering effects are eliminated by taking the angle as 90° less the angle of the leaf with the vertical, the data for leaves are in as complete accord with the theory of the angle of balance as are those for stem and root- branches. Leaves and the branches of stems and roots may, therefore, be said to be spread out primarily by the balancing action which the leakage from the main stem has upon the effects of the action currents in the lateral organs. How LEAVES ORIGINATE. Up to the present there has been no detailed theory for the origin of leaves but, with the new insight into what is occurring in the stem apex, it should be possible to obtain some idea of how leaves happen to develop at the apex of the stem. The following 1 See the “‘ New Phytologist,” Vol. XIX, p. 209. 1920. 2 This cause very probably is the effect of light on photosynthesis and the carbon dioxide balance in upper and lower sides of the leaf. 102 - James Small on suggestions have been put forward tentatively’, as a working hypothesis which may open up this particular field to experimental investigations. Any apical meristem is considered as generating an electric current. The apical meristem of the stem produces a sym- metrically flowing “normal polarity current” as previously described. The primordial knob which develops into a leaf starts as a slight more or less hemispherical swelling near the stem apex ; then it develops a meristematic region and grows out to form a leaf. ‘The young leaves developed in this way overlap the comparatively small apex of the main axis of the stem. The electric fields of the currents produced by the growing points (meristems) of the leaves and of the stem may be compared with the magnetic fields of magnets. The electric field of the stem current is small, compared with that of the larger leaf current. The stem is represented by a small cylindrical magnet placed vertically, and the leaf is represented by the opposite pole of a large bar magnet placed horizontally. If the combined magnetic fields are investigated by means of iron filings, when the large magnet is set close to the top (opposite pole) of the smaller magnet, a small neutral area will be found to be induced on the side of the “axis” opposite to the large magnet. Now, if normal polarity of growth is due to the normal polarity current, the cells in this neutral area will be freed from that influence and will grow in all directions. Such growth would give rise to the first stage of the leaf as a primordial knob. When growth advanced further and a meristem developed, an electric current and its electric field would result. Meanwhile the first leaf would be carried away from the stem apex by the elongation of the stem, and the new leaf (originated by the effect of the electric field of the first leaf on the normal polarity current at the stem apex) would be left to help in the development of the primordial knob of a third leaf, and so on. . 1 New Phytologist. Vol. XIX, p. 210. 1920. The Erectness of Plants. 103 An interesting case is that of opposite pairs of leaves, which may be imitated with two large horizontal bar magnets placed very close to the top of a small vertical cylindrical magnet, as shown in the demonstration experiment on the table. In this case the mutual effect of the two equal large fields and the smaller field is the production of two equal small neutral areas at right angles to the bar magnets. These areas in the plant would become prim- ordial knobs at the stem apex, and a pair of leaves at right angles to the first pair would result. This is a very common case in the Dicotyledons, but very rare amongst the Monocotyledons, and the first pair of leaves may be taken as the seed-leaves or cotyledons. SoME PRACTICAL APPLICATIONS. The great outstanding practical application of these purely scientific facts and theories occurs in the “ earthing-up” of potatoes. ‘The potato tuber is a stem structure, a swelling at the end of a lateral branch which is induced to grow downwards in the soil by covering the main stem with earth above the level of the buds in the axils of the lower leaves. When the stem is covered with earth the stomata cannot act efficiently as passages for the respiratory carbon dioxide, and that gas is not used up in photosynthesis because of the absence of light. The farmer and the gardener, therefore, have been carrying on this particular experimental reversal of geotropic curvature in the stem every year in the “ earthing-up” of their potatoes. A minority opinion in the past has been expressed against “earthing-up ” as a method of increasing the production of tubers, but with the new scientific basis for this process there can be no doubt that, within certain limits, more earthing-up means more potatoes. Enough green foliage must be left above ground to produce the starch for filling the tubers ; but in Forfarshire, at any rate, those farmers who earth-up their potatoes, not only once but twice or more, get the heavier crops. A comparatively small amount of foliage seems to be sufficient to produce all the starch that is required. 104 James Small on Apart from this very extensive and important economic: application of the effect of carbon dioxide on the direction of growth, there are numerous other lines of scientific and economic investigation in which the fact that the root is relatively acid while the stem is relatively alkaline, has been overlooked. The: new evidence for the verity of this phenomena may prove of great. value in directing the attention of investigators to its obvious. results in experimental and observational work. For example, it is well known that only a few plants are able to grow in distinctly acid media, such as sphagnum bogs and sphagnum peat; similarly a few other plants show a very decided preference for chalky soils. The continued existence of both classes obviously depends upon special relations between the reaction of the soil and the reaction of the roots of the plants. Two interesting cases of the influence of “ reaction” on the: growth of the plant occur in the maize and the bean. The ordinary maize is yellow, but varieties are sold which are white,. e.g., Sutton’s White Horse-tooth Maize. The colour is due to a substance which becomes intensely yellow with ammonia vapour and is changed to a colourless product by acids. The yellow maize is yellow because it is, as a whole, relatively alkaline ; while the white maize is white because it is in the same way relatively acid. Keeping in mind that the root is acid, it is interesting to note that, while in yellow maize the main root aborts when it is not more than two millimetres long, the white (acidic) maize produces a main root several inches long. A similar phenomen occurs in the bean. Broad beans with green seed-coats give straighter longer main roots on first ger- minating than do those with brown seed-coats. Such seedlings. as the former naturally stand a better chance of successful growth into mature plants. Now, the green bean is acid and the brown bean is relatively alkaline. The colouring matter can be ex- tracted ; it is green in acids but turns brown in alkaline media. The Erectness of Plants. 105 A FURTHER EXTENSION OF THE THEORY. An obvious corollary to the theory as outlined above is that the sign of the electric charge on the particles which form the outermost layer of the cytoplasm depends upon the concentration of acids near that membrane. Not only the sign but also the density’ of the charge (7.e., the degree of polarisation or electrifi- cation) will be affected by the varying amounts of acid or alkali present. This corollary forms the basis of the theory of heliotropism outlined above (p. 98). Since the density of the charge on the membrane largely governs the degree of permeability and, there- fore, of turgor and growth, it has very important bearings also upon the influence of the acidity or alkalinity of the medium upon disinfection, plant diseases, infection of plants or animals by fungi or bacteria, the cultivation of bacteria, the long recognised effects of acids and alkalies upon both plants and animals and upon protoplasm in general. The concentration of carbon dioxide governs not only the erectness of plants but also very probably their resistance or susceptibility to disease, their rate of growth, their storage of starch and a multitude of other phenomena in the details of the “living” of these organisms. EXPLANATION OF PLATES. PLATE I. V.—Coated with vaseline. UV.—Unvaselined. Fic. 1.—Bean seedling showing retardation of growth in the dark with seedlings vaselined (V.) as compared with others left unvaselined (UFW.). Fia. 2.—Maize seedlings showing reversal of gravity curvature in one (V.), and recovery from this effect in another (V!.), after being vaselined and kept in the dark for several days. Fic. 3.—Vaselined maize seedlings several days after being placed horizontally in the dark. Three show downward curvature, three are erect, and four or five are nearly horizontal. Fic. 4.—Vaselined maize seedlings after similar treatment ; the one-which is curved down recovered on being placed in sunlight. 1See my ‘Text Book of Botany,” foot-note, pp. 353-4, 106 Explanation of Plates. Fic. 5.—Antirrhinum seedlings after treatment. The control (U.V.) curved up. The lowest vaselined plant turned up at first and then curved downwards. Fic. 6.—Ivy-leaved Pelargonium after treatment. In the control (U.V.) the stem and young leaves curved up. In one of the vaselined piants (V!.) both young leaves and the stem curved downwards. Fic. 7.—Two stems of the same species showing downward curves after _ treatment. Fic, 8.—Stem apex of the plant in figure 6 (V.!"). Experiments by Miss M. W. Rea. PLATE II. Fic. 9.—Seedling of Cerastium after treatment. The control (U.V.) was an older plant. The lower two vaselined plants show downward curves. Photographed in the erect position in order to show the turgidity of the curves. Fra. 10.—A similar plant after treatment. Photographed erect. Fras, 11-14,—Reversal of gravity-curvature in sunflower seedlings placed in 13 to 16 per cent. carbon dioxide and recovery of normal cur- vature. Hxperiments by Miss M. J. Lynn. Fie. 11.—Reversed curvature of six seedling stems in carbon dioxide, Fic. 12.—Recovered normal curvature in the same seedlings after the carbon dioxide had been removed. Reversed curvature in eight out of nine seedling stems in carbon dioxide. Fic. 13. Fie. 14.—Recovered normal curvature in the same seedlings after removal from the jar into fresh air. PLAT: Ut. Fie. 15.—One plant of Anthemis sp. with one branch vaselined and show- ing reversed curvature, the other unvaselined showing normal curvature and elongation. Experiment by Miss M. W. Rea. Fics. 16-20.—Reversal of gravity curves and light curves in carbon dioxide, and recovery of both normal curvatures. Experiment by Miss I. Finnegan. Fic, 16.—Sunflower seedlings in carbon dioxide growing away from light and downwards. Fic, 17.—The same plants after removal to fresh air, showing recovery of normal response to gravity in one seedling. : Fira. 18.—The same a day later, showing recovery of normal gravity- curvature in both seedlings. Fir. 19.—The same a few more days later, showing recovery of normal light-curvature in both seedlings. The same still later. ato b reversed heliotropism ; b to c re- versed geotrepism ; c to d recovered normal geotropism ; d to e recovered normal heliotropism. In one seedling the recovered light-curve is in the new growth (d to e); in the other it is in the older part of the stem (d! to e!), Bre. 20; FIG. ! Pate I. FIG, a NATURAL | HISTORY. PLATE II. TS sh NATURAL HISTORY. | Pate Iii Lariat earls fo EES 25 NATURAL | { HISTORY. j SION 1920-1921. cae DR. THOMAS ANDREWS: E GREAT CHEMIST AND PHYSICIST. BY HENRY RIDDELL, M.E., M.LMxcw.E. —s B.A nee: ra 4 o- ie LTD, 2C ORPOR ATION STR oe ea * : “ee ie } E* oe : & a \ - THOMAS ANDREWS, M.D., M.R.I.A. rom a Photograph presented to the Society by Mrs. Andrews in 1888, Proceedings of Belfast Natural History and Philosophical Society, 1920-1921 8th March, 1921. In CuemicaL Lecture THEATRE, QUEEN’S UNIVERSITY. The President, PRorESSoR GREGG WILSON, in the Chair. Dr. THOMAS ANDREWS: THE GREAT CHEMIST AND PHYSICIST, By Henry Rippeii, M.E., M.I.M.E Hon. Treasurer of Society. (Abstract. ) [Some apparatus used by Dr. Andrews for his famous experiments were on exhibition in the lecture room. ] It is right at times for the people of a nation, the citizens of any town, and the members of a Society like ours, to look back _ upon their history and bethink themselves of the men who have gone before them, to use as the text for their meditations those words from Kcclesiasticus, “ Let us praise famous men and the fathers who begot us.” And there is no time more suitable to us for such a purpose than this, the Centenary Year of our Society, and so the Council have arranged to publish a memorial volume, in which will be found complete lists of our members, with short biographies of the best known men, and a statement of the great work they have done for their generation and for the world. And we have a right to be proud of such men, for example, as John Templeton, William Thomson, Robert Patterson, Wyville Thomson, R. O. Cunningham and others in the study of Natural History, John Purser, Peter Guthrie Tait, James Thomson and Joseph D. Everett, in the realms of Physical and Mathematical Science, while the name of Thomas Andrews stands out upon our roll, the great investigator in Chemical Physics. 108 Henry Riddell on It is therefore at the request of the Council of the Society that I have this evening to give you an account, necessarily imperfect, of Dr. Andrews and his work. There are many reasons for our interest in Andrews. He was a fellow townsman, a prominent and greatly respected member of our Society, of which he was President 1854—1856, and a scientific investigator whose name and work are known wherever Science is esteemed. ‘To me he was the valued and venerated teacher for whom I had unbounded admiration and affection. And not least upon our list, by his kind and generous heart, his care for the feelings and interest of others, and his sincere and upright life, he earned the grand title of an honourable and Christian gentleman. Thomas Andrews was born on 19th December, 1813, at 3 Donegall Square South, and lived there as a boy and as a man until his transfer to the building erected for him in this College grounds in 1845. In those days the square around the Old Linen Hall was almost wholly residential. Next door to the Andrews family for years dwelt Mr. Bristow, a well-known solicitor of the town, the Bristow name being still familiar in Belfast and on the roll of our Society. Other residents there were Charles Lanyon, the Architect of this College, and a member of our Society, John Workman, whose descendants to the third and fourth generation are now among our members, and John Sinclair, of the firm of J. & T. Sinclair, a name best remembered among us in the person of the late Right Hon. Thomas Sinclair, a dis- tinguished Graduate of this College and a man much loved and respected in the City of Belfast. The Andrews family, then as now, were closely connected with the mercantile life of the town, and are to-day represented by the Flax Spinners of Comber and the Flour Millers of Belfast, while the name of Michael Andrews, of Ardoyne, ‘is ever famous in the history of the Linen Trade, in which the family is still concerned. Thomas Andrews’ grandfather, Michael Andrews, was the eldest son of John Andrews of Comber, and his father, also Thomas, was in business in Belfast as a linen merchant, Dr. Thomas Andrews: The Great Chemist 109 having his office in Thompson’s Court, off Donegall Street, while Michael Andrews, of Ardoyne, had his residence at 72 Donegall Street and his office in York Lane. The boy Thomas was sent to school first to the old Belfast Academy in Donegall Street, but was soon transferred to the Academical Institution, in which from 1835 to 1845 he was to be the Professor of Chemistry in its Collegiate department. He did much of his important work while in this post, and before he left it in 1845 to join the organizing staff of the projected Queen’s College, or rather the Northern College as it was first called, his name was known over all Kurope. He wasa diligent pupil, paying especial attention to French and having a liking for Chemistry. He left school before he was fifteen to join his father’s business, but his heart was not in the work and discussions took place regarding his future. A family friend at that time was Doctor James McDonnell, who was a man of mark and influence in Belfast. He belonged to the famous Antrim family, and was educated by that remarkable teacher David Manson, graduated in Edinburgh in 1784 at the age of twenty-two, and started practice in Belfast, where he soon became one of the leading Physicians. He was the originator of the old Belfast Literary Society and one of the founders of the Linen Hall Library. He was greatly esteemed by our Society, and belonging to it there is a fine bust of the Doctor, still among our collection of pictures, books and manuscripts, a collection which is exceedingly valuable and ought to be available for study in any New Museum to be erected by the City. His graduation thesis was on the treatment of those apparently drowned and he was bold enough to suggest the transfusion of blood as a last resort. Between this man and the school-boy fifty years younger a curious companionship arose more like that between equals in age and acquirements than between persons so different in years. He advised that the youth should be educated for the medical pro- fession, taking care in the course of this education that the subjects studied should be such as would be of service to him, if later on his duty or inclination should call him to commercial life, 110 Henry Riddell on Andrews then was sent to Glasgow to study Chemistry undér Dr. Thomas Thomson, who had established there the first school of Practical Chemistry in Great Britain. In Glasgow Andrews worked hard, and received at the end of the session certificates of diligence and ability in both Chemistry and Natural Philosophy. It was this year that was published his first scientific paper, from.a boy of fifteen, in the Phil. Magazine, the subject being certain peculiarities of the blow-pipe flame. ~ He did not seem satisfied with his outlook at Glasgow and it was later arranged that next year he should go to Paris to try entering one of the laboratories there, to get a wider view of his favourite study. It was in this year, 1830, that appeared his first paper on a truly Chemical Subject, “The Separation of Baryta or Strontia when in Union with Lime,” a paper which gave promise of the care for detail and accuracy which was always characteristic of his work. In the Autumn of 1830 Andrews sailed from Dublin for Bordeaux with some letters of introduction, intending to make a somewhat extended tour before reaching Paris, where he had determined to study. It was a bold step for a boy not yet seventeen. Trance was just emerging from the revolution which had placed Louis Phillippe on the throne as a constitutional Monarch, and the effects were so feared that travellers were few, there being only twelve on the boat in which he sailed. By a singular piece of good fortune his diary of this trip has survived the ninety years, and you will forgive me, I hope, if I quote some passages to show the power of thought and expression rare in a boy so young. He describes his journey up the river to Bordeaux— On leaving Poliae (where the Customs Officers had boarded the ship), the banks of the river present a lively and picturesque appearance. Vines, with occasional meadows are the only crops cultivated. Approaching Bordeaux the view gains in richness and variety. Country villas surrounded by clusters of trees appear, and on passing the mound, the shipping and the town burst suddenly into view. ‘The appearance of the town is rather engaging. It is built of a coarse siliceous sandstone Dr. Thomas Andrews: The Great Chemist 111 which is obtained from the right bank of the river. Some of the buildings, such as the Theatre, are in the highest state of external beauty, and there is a very extensive Place in which some rows of trees are planted.” He describes the company in his hotel, “where politics were discussed with the utmost eagerness.” ‘“ At the table d’hote where I dined was a lady who had arrived from Paris wearing a tri-coloured ribbon. She took the lead in every conversation, was, in fact, the orator of the party. Nothing ean exceed the interest the French have taken in their Revolution. They can speak of nothing else. If the conversation passes for a moment to any other subject of local or personal interest, it soon returns to the detail of the events in Paris. The same actions are related over and over again, and followed by the same exclamations of wonder and delight. Every article in the constitution is received with a unanimous and cordial assent. C'est bien cela! C’est bien cela! is repeated after every clause and re-echoed by every voice. There is no diversity of opinion on any point. Had each individual framed a code himself he could not have been better satisfied with it. Such are the French people. Scarce half a century ago they submitted without a murmur to the most despotic of governments and tyrannical of priesthoods. They admired their Government; they adored their King; they loved their Church. Suddenly a wonderful revolution took place in their government and in their religion, and they regarded with equal veneration the new idol they had set up. It, in turn, soon passed away—a reign of confusion and terror succeeded, till a military despot seized the reins of the Kingdom. The nation bowed before his feet, and, dazzled by the splendour of his victories, regarded him in the light of a God. A foreign force drove the usurper from the external throne in France, but he still retained his dominion over their hearts. This dynasty has now been expelled—for ever? The nation has had its own election and what has been its choice? Not its much vaunted Republic, nor still less its military despotism. It has formed a limited Monarchy such as that of England, but 112 _ Henry Riddell on it has abolished an established Church and retained the Monarch in faster bonds. Its new Constitution is looked upon as a chef douvre of perfection, as forming a guarantee against every danger, as ensuring to them an ever during liberty. May they enjoy it as they deserve it. Their laws are good but will they be fulfilled? Were a second Buonaparte to arrive, could he not, taking advantage of the natural vivacity of the nation, trample on their newly acquired rights and set up a new subject for their admiration?” I am inclined to think you will agree that a boy of sixteen shows here a graphic power of expression and an insight far beyond his years. Continuing his tour he passed through the mountainous Auvergne region, giving close study to the geological formations and collecting specimens which he catalogues and names. As showing the terms of the friendship between him and Dr. McDonnell I shall quote one or two letters of the Doctor’s which have survived till to-day. The good Doctor had been studying many subjects in which he was interested and refers to experiments in which Andrews had shared. He had been investigating the proportion of CO, in atmospheric air, and had been taking samples upon the hills round Belfast. He had been studying the geology of County Antrim and County Down, and experimenting on the effect of altitude on the pulse and respiration. We find him putting a number of geological questions to Andrews on his journey through Auvergne, and he goes on— “IT much wish to know whether Chemistry furnishes any plain or simple criterion by which to distinguish Trapps from all other rocks except Lava, and again another difference between Lava and Trapp? Is there any chalk or Lias or Mulatto in Auvergne ? and, if dykes cutting them, change the lime into marble or render it phosphorescent? Any red flints or gypsum? and how situated with regard to the Trapp? Whether the Trapp lies horizontal or vertical ?—Is the outline of the mountains like or unlike ours?” In another letter, sent by the hand of a friend, he opens very characteristically “My dear Thomas, finding that this costs me nothing I must write, though I have nothing of moment to say.” Dr. Thomas Andrews : The Great Chemist 113 He repeats his question as to the chemical distinction between Trapp and other rocks, making the interesting point, that, for want of such a criterion he finds Playfair and Allan placing the Portrush Ammonites as being found in Siliceous slates while Dr. Richardson and hundreds of others called it Siliceous Trapp or Basalt. He gives him numerous commissions to haunt the bookstalls looking for volumes which are wanting in certain series in the Doctor’s library, and we form an idea of the amazing variety of the literary and scientific interests of McDonnell. He finishes by discoursing upon the effect of altitude on the heart and the rate of respiration and urges Andrews if ever he should gain access to Gay Lussac, to ask him to describe his sensations during his famous balloon ascent of 22,000 feet. I cannot take time to quote further from this most interesting correspondence, but we must wonder greatly when we think it is addressed to a boy wanting some months of seventeen. After his arrival in Paris Andrews presented his letters, and was very kindly received by some of the great scientists then in the city. It was vacation time and none of the regular schools were open, but he entered some classes specially intended for students remaining in Paris at such a season, and congratulated himself that he was using his time to so much advantage. He ultimately succeeded in gaining admission to the laboratory of M. Dumas, and ever after retained the friendship of this great man. Unfortunately a severe illness compelled him to leave France earlier than he had intended, and on his return to Ireland he entered Dublin as a medical student. While there he con- tinued his great interest in Chemistry and laboured diligently in his preparation for his profession. During his student days he published a remarkable paper on the “ Chemical Changes in the blood of Cholera patients,” gaining his material during the great epidemic which broke over Belfast in 1832. He completed his medical course in Edinburgh where he took his-degree, obtaining the diploma of the Royal College of Surgeons in April, 1835, and his M.D. in the August of the same year. It was immediately 114 Henry Riddell on after obtaining his degree that he joined our society, on the register of which for 1835 he appears as Thomas Andrews, M.D. He was not yet twenty-two years old, but had been already offered the position of Chemistry professor by both the great Dublin schools of medicine. He was not long in Belfast before he was appointed the first professor of Chemistry in the newly established Medical College in the Academical Institution, which teaching he combined with a growing private practice, and in spite of the claims of both upon his time, managed, as I have already said, to do much splendid work. It is almost forgotten now that there ever was such a collegiate department in the Institution, as it was closed when the Queen’s College was opened in 1849. The year after his appointment in Belfast he spent a vacation in Paris, renewing his acquaintance with M. Dumas, and making that of M. Chevreul, M. Berthier, and M. Gay Lussac. In this visit he had much pleasure in the company of the great physicist Thomas Graham, and the latter was the means of introducing Andrews to the notice of many of the men who made Paris of the day so famous. To Graham he owed also his introduction to Faraday, beginning a very close friendship which ended only with Faraday’s death. Andrews had even thus early begun his series of experiments on the electrical relations of elementseand compounds, and took the opportunity of this visit to purchase some of the latest and most accurate instruments. Reeognition soon came to him. In 1839 he was elected « Member of the Royal Irish Academy, and he was one of the original members of the Chemical Society in 1841. It was in 1842 that he married, his wife being a grand-daughter of Adam Johnston of Glynn, who was Andrews’ own great grand- father. I am glad to remind you that among our members the family of my old master is still well represented, and we all know Miss E. Andrews as an active investigator into the antiquities and folk lore of our Province. Andrews received the Royal Medal in 1844 for one of his investigations upon the heat developed in chemical combination. In 1845 he was invited to offer himself for the vacant chair of Dr. Thomas Andrews: The Great Chemist 115 Chemistry in King’s College, London, but declined. The new Colleges in Ireland were about to be launched, and it was clear that Andrews was the man marked out as necessary, and this same year he was appointed Vice-President in order that by his knowledge and common sense he should help to direct the course and arrange the details of the new scheme. When the time arrived for the appointment to the professorships, Andrews naturally received that of Chemistry. In 1849, the birth year of the University, he was elected to a Fellowship of the Royal Society, and it was in this year began that period of earnest and inspiring teaching which so many of his old pupils remember with gratitude and admiration. From this time his life flowed on, devoted to his students and his researches. I need offer no proofs of the estimation in which Andrews was held all over the world. Many degrees and honours were showered upon him; the thirty years passed rapidly by and the burden of approaching old age began to be felt, so that in 1879 he resigned and for six years lived in retirement in Fortwilliam Park until his death in 1885. Perhaps this is the time to say something of my own memories of the great teacher. I was much past ordinary student age when I entered the Engineering School, having already completed two technical apprenticeships. Before I entered Queen’s College I had twice listened to Andrews lecturing to the members of this society. The first lecture was fifty-one years ago upon his own great work on the continuity of the liquid and gaseous state, and was a revelation of the extreme clearness of expression and power of forcing an audience to be interested and eager to hear what he was saying. I remember a remark made by the then President of the society, Joseph John Murphy, of which I shall speak when explaining this great research. The second lecture was a beautifully illustrated and clear discourse on the then recently invented Gramme ring, and its uses in electro-generating machinery. It drove me to study Faraday, for which I am for ever grateful. It followed therefore that I had some idea of the man I was going to learn from, but I had not formed the full 116 Henry Riddell on knowledge of his kind heart or of his eagerness to help a willing student. It was his habit, after every lecture, to remain for a short time at the table to auswer any questions students might come to ask him, and I always took advantage of this opportunity. In my time his lectures were models of what was needed. Thorough, in that they dealt with every essential, but not redundant, beautifully clear and illustrated with well chosen experiments always thoroughly prepared and always successful. ' He suffered somewhat from the kindness of his heart in that he was never able to show that outward sternness which is so needful to keep discipline in a class of youths. There was in my time no general teaching of Practical Chemistry. The accommodation for laboratory work was so scanty that it was necessary to select the few pupils by examination, there being also a possibility of obtaining admission by payment of a heavy fee, which I do not remember to have been much availed of. In this laboratory work I learned to know Andrews thoroughly and to have a great regard and affection for him. He never spent more than a few minutes at a time in our laboratory, but it was the frequent visits which I was allowed to make to his own room in which lay the charm and the delight of my time there. He used often to call me up to help him to set up some piece of apparatus, and I have always been sure he never needed the assistance he called for, that it was his plan to help a man he knew to be anxious to learn. I had many interesting and enlightening conversations with him. I remember on one occasion a whole morning spent in his room discussing his work and some chemical problems. I asked him if he accepted the idea that all elements had atomic weights with simple numerical relation to that of Hydrogen. He said that this could not be unreservedly accepted, as accurate determinations did not support it. At the same time he thought there was evidence that some intimate connection existed. ‘‘ We physicists,” he said, I quote the word as illustrating his position, “ We physicists look to the future to show that all the elements are built up from the same primordial OO ——— a Mi taifor ve ee ev at ae hs Dr. Thomas Andrews: The Great Chemist Diy substance, matter or otherwise.” He thought that the atomic weights might not represent an exact measure of this primordial substance, but only some ratio to it, constant for each element. That they might be affected by the interference of some form of energy. ‘These were only speculations and must be left to the future to prove or disprove. He thought it possible that all chemical action was dependent on electrical forces, but in what way he saw no method of discovering. Of course all his answers were coloured by the nature of my questions, and he smilingly assured me that these odd speculations did not form any hypothesis which he could use in lecturing. JI sometimes wonder what the Doctor would have thought of the modern theories which have been so rapidly developed in Physical Chemistry, the present conception of the atom and the molecule, the almost certain knowledge that several editions of the same element may be found, alike in chemical actions but differing in atomic weights, and the suggestion that the known figures are but means between these differing varieties. _ Dr. Andrews told me that, from his point of view, he saw no reason to say that transmutation of the elements was impossible ; ~ its difficulty must be measured by. the constant failure of all attempts. If ever it be found possible to realize the aim of the old alchemists by manufacturing gold he had the idea that it would be too costly for use. I should like to have him watch the transformation of the Radium relatives and to see his own researches followed up, to the extent they have reached to-day. We ought not to forget that Pneumatic Chemistry had its origin in Britain and that the greatest advances had been made there. Faraday began an enquiry which Andrews continued, and in which he may be said to have determined the laws. In later years Rayleigh, Ramsey and others have made advances almost incredible in amount in the discovery of new gaseous elements, and _we are proud to remember that the main work in this branch of Physical Chemistry has been done by our fellow countrymen. On Andrews’ retirement in 1879, his fellow townsmen 118 Henry Riddell on honoured him by instituting the Andrews Studentship in Chemistry, and by presenting his portrait to the University, where it hangs in the Examination Hall. At his death he was mourned as a great teacher and asa good and kindly man, for whose life his country was grateful, and for his death sorrowed deeply. It is impossible to deal at all fully with his many investigations and I shall only mention a few. In 1841 he began to publish a great series of researches on the heat developed in chemical combination, and it may be remembered that in 1840 Hess published the results of a number of experiments on the same subject. It is singular how often we find a series of investigations proceeding in one country, and at the same time, quite independently, somewhere far away another man has chosen to follow the same research, and publication is almost simultaneous. Andrews’ experiments were perhaps more accurate in results and more numerous than those of Hess, but both deserve honour for their work. It was a favourite subject with Andrews, and he continued to work occasionally on it for many years, while for the time between 1841 and 1849 it formed almost his only research. It is characteristic of the man that he best loved to seek the inner secrets of a chemical law from the point of view of energy, and it is interesting to note that all through the great series of experiments he seems to take for granted the law of conservation of energy, not definitely framed for some years later. He looked upon it as self-evident that a compound which gave out heat during combination, should take up precisely the same amount when its bonds were released, and that the thermal properties of a body were not dependent upon its history, but that the energy of combination in a compound was the same no matter how many transformations it had passed through or what path these followed. He was the author of the report on this subject to the British Association of 1849, in which a comprehensive survey was made of the then state of our knowledge. ‘Towards the end of this period belongs a research on Dr. Thomas Andrews : The Great Chemist 119 the question of latent heat in many substances. Joseph Black first brought this doctrine into use, and it must be remembered that it is very closely connected with the ideas raised by the investigations into heat of chemical combination. It differs by being concerned only with the physical change of a substance. Black showed for example, that it required a large quantity of the entity called heat to cause the melting of ice, but this heat could not be perceived by the thermometer, as it had disappeared in the change of physical state. In like manner heat was required to convert the water into steam, and again the thermometer gave no indication of its presence, as the steam was at precisely the same temperature as the water from which it was being formed. In all such changes of state heat is either absorbed or given out ; the quantities are perfectly measurable and are fixed, being always the same for the same change of condition. “It is also the fact that the amount of heat required to raise the temperature of a substance, water for example, through some range between fixed limits, is always the same for the same substance under the same conditions and is proportional of course to the mass of substance dealt with. This is the specific heat of the substance, and the unit used is generally the quantity of heat required to raise one gramme through one degree C, from a fixed temperature. For fifty years it was believed that Regnault was right in his hypothesis that the specific heat of water was almost constant between 0° and 100°C, between freezing and boiling point, and all Andrews’ experiments were made with this idea in view. In 1879 Rowland discovered the most unexpected fact that, instead of a constant, or a very slight but steady increase in the specific heat, the measure at.35° was almost one per cent. less than at 5°C. In the light of these results all Andrews’ determinations need to be recalculated, as his values are given in terms of the mean between 0° and 100°, while his measurements were made at temperatures at which the specific heat is now known to be above the mean. I may illustrate this by his figures for water vapour. He published in 1847 a series of eight experiments on water 120 Henry Riddell on vapour, One succession of three by a method which he believed would give values too high in amount, and five by another method which he was equally certain would give a figure too low. If we take the mean of those due to the first method and also of the five in the second series and use half the sum of these as the most probable value due to his experiments we find the resulting figure to be 537°, which means that the amount of heat required to convert say one pound of water at 100° into steam also at 100° is the same as would suffice to raise 5-37 pounds of water through the whole range between 0° and 100°C. But these figures are calculated on the understanding that the mean specific heat was constant. When they are recalculated in the light of modern knowledge, and of the most accurate experiments now on record, the figure of 537° becomes 538:3°, and we note also that the most modern value chosen for this quantity is 539-3°, arising out of experiments conducted with all the refinements of electric methods by which temperature can be measured to about one-thousandth of a degree. When Dr. Andrews made his experiments it was necessary to read the mercury thermometer to less than one one-hundredth of a degree to measure the variation between 538°- and 539:3°. I should next mention the series of experiments on Ozone, and here a short introduction is necessary. It had been noticed that a body having peculiar odour was formed under the following different circumstances, and that in each case its properties appeared to be similar :— 1. Passing electric sparks through air. 2. When water is decomposed by the electric current this — substance appears at the positive pole along with oxygen. 3. By the slow oxidation of Phosphorous in air at ordinary temperatures. For a long time the composition was uncertain, and it required experiment to determine if the same substance was formed in each of these cases. It was believed by many chemists that the substance obtained Dr. Thomas Andrews : The Great Chemist On! from the electrolysis of water contained hydrogen. Other scientists believed it to be composed wholly of oxygen. It was soon shown, however, that pure and dry oxygen could be partially converted into ozone by passing through it an electric spark. It was also noticed that in the formation of ozone in oxygen the volume was reduced, and it was argued that ozone was an altered or allotropic form of oxygen, having a density greater than the parent gas. Andrews’ experiments were undertaken to settle this question and he succeeded in proving that, no matter in what way Ozone was prepared, it was always the same body, with the same properties, and that that obtained from the electrolysis of water did not contain Hydrogen as had been supposed. It was found that Oxygen could only be partiaily changed into Ozone by the action of the spark, but it was also discovered that certain reagents seemed to absorb the Ozone when the combination took place, and that by continuing the process and absorbing the Ozone as formed, the whole of the Oxygen could thus be ultimately transformed. It was soon apparent that the amount: of Ozone destroyed, as was supposed, by the chemical reagent used, and accounted for by its increase in weight corresponded approximately to the reduction in volume of the oxygen when the spark was passed through it. It was then necessary to investigate the matter further and discover the density of the allotropic modi- fication of oxygen which he had proved to be formed. In 1857 the first account of the experiments undertaken in conjunction with P. G. Tait, then Professor of Mathematics in Belfast and a member of our society, appeared, and was followed by publication of a further series in 1859 and 1860. Never was Andrews’ unrivalled accuracy in experiment better shown than in this series, which ran up against a stone wall by suggesting an infinite density for Ozone. It is true that the two experimenters saw another solution to the difficulty, which was really the true solution, but which was named only to be rejected as too improbable. Soret later proved that the density of Ozone was one and a half times that of Oxygen, and that the solution rejected by Andrews and Tait was the true one, 122 Henry Riddell on The experimenters attempted to discover the density of Ozone when mixed with Oxygen on the assumption that the molecule was completely broken up and the resulting oxygen combined with the reagent employed. They weighed the reagent and found the volume of oxygen it had seized and then found that no volume whatever had been lost from the gas under consideration. Of course if a definite weight of any substance has no volume whatever its density must be infinite, yet the very accuracy of the experiment is seen in the fact that absolutely no change in the volume could be discovered. If we represent Ozone by the formula ane which is possible since the discovery of quadrivalency in Oxygen, we see at once what occurs. When the outer atom is removed from the molecule it will of course be in a very active condition and will be totally absorbed, while the remaining two atoms keep the molecular form, becoming bivalent. As the molecule in both cases has the volume of two atoms of Oxygen there will be no change whatever due to the tearing away of the loosely bound atom. A rather interesting memory is connected with these Ozone investigations. When the paper was submitted for the Royal Society in 1860 it was handed to two referees for report. The curious result of the calculations seems to have raised doubt as to the accuracy of the experiments, but it is rather odd that I have found in Sir George Stokes’ correspondence with Andrews, the statement that one of the referees still clung to the view that Ozone was a compound of Oxygen and Hydrogen, though all who read Andrews’ first paper with attention will admit that he completely disproves this idea. Stokes was a firm and good friend to Ur. Andrews, and of course well known as a scientific investigator himself, but perhaps even better in his official position in regard to the Royal Society, of which he was secretary for so many years, and afterwards president. George Gabriel- Stokes was a Sligo man, and was senior wrangler and first Smith’s Prizeman in 1841, He was one of our really great mathematical Dr. Thomas Andrews: The Great Chemist 128 physicists and deserves to be remembered on the roll of our countrymen. The only other research of Professor Andrews’ which I shall mention is his great investigation which resulted in the Bakerian lectures of 1869 and 1876, on the “Continuity of the Liquid and Gaseous States.” A hundred years ago Caignard de La Tour heated a number of volatile liquids in sealed tubes, and noticed that, at a temperature which seemed fixed for each liquid, the meniscus of the surface gradually flattened out, and then, somewhat suddenly, the tube became filled with homogeneous matter. In 1826 Faraday succeeded in liquifying Chlorine, rather unexpectedly it must be admitted. He was then assistant to Davy, and was ex- perimenting at his desire on several substances. He had sealed into a bent glass tube a small quantity of Hydrate of Chlorine Crystals, which are formed by exposing moist Chlorine gas to a temperature of 0°C. You will remember that it was Davy who proved that Chlorine was an element. When Faraday gently heated the crystals in one end of the bent tube some drops of an oily looking yellow liquid condensed in the other, the cool end. Of course the generation of the chlorine had greatly increased the pressure in the tube and caused partial liquefaction. There is a pleasant story to the effect that Dr. Paris entered the laboratory while this experiment was in progress, and after seeing the yellow drops scolded the worker for his carelessness in allowing the materials to be contaminated. Faraday answered nothing at the time, but the next morning Dr. Paris received a short letter reading — “Your oily drops were nothing but Liquid Chlorine.” MICHAEL FARADAY. In these experiments Faraday succeeded in liquefying a number of gases. He returned to the subject in 1845, when, by the joint application of pressure and cold he effected the liquefaction of a further number. He published the opinion that 124 Henry Riddell on the liquefaction of any gas was only a question of sufficient pressure and sufficient cold, and that there existed for each gas a temperature above which pressure alone, no matter how great, would not produce liquefaction. Faraday was one of the most intimate friends Andrews possessed. He was the son of a black- smith and was both a scholar and a gentleman, though there is rather a malicious story as to Lady Davy and him. He accompanied Davy to Paris as his assistant, and in an emergency undertook to act as his valet. The French scientists were not long in discovering the nature of the young man they met, and placed him at dinner with Sir Humphry and his wife. It is said that Lady Davy was highly indignant that a servant should have such a position, and other arrangements had to be made for the rest of the visit. It was about 1860 that Dr. Andrews began the experiments, which first took the form of an inquiry into the effect on various gases of combined pressure and cold. In this inquiry he used pressures as great as 500 atmospheres and a degree of cold approaching — 110°C. Later on he devoted himself to an investi- gation of Carbon Dioxide, Carbonic Acid as it was then always called, with the view of discovering some law which might be connected with liquefaction generally, and in this he was eminently successful. The apparatus used is shown in the engraving, fig. I. It con- sists essentially of two metallic tubes, to the upper flanges of which elass tubes can be connected. The two metallic tubes are in full communication at the bottom and are filled with water, so that the pressure in both will be alike, whatever its value. The tubes are of cold drawn copper, and the general arrangement is easily understood from the drawing. In my day at Queen’s, Andrews was engaged in repeating and varying the experiments described in his Bakerian lecture of 1876, and at this time had improved the apparatus, by somewhat increasing the diameter of the metal tubes, and inserting the lower ends of the glass tubes into small glass reservoirs of mercury resting on ledges within the metallic igi: Dr. Thomas Andrews: The Great Chemist 125 portions. The glass tubes were mounted in an ingenious way. An enlarged conical portion was formed near the junction of the two diameters, the lower ends of the tubes being comparatively large in diameter while the upper portions were of capillary dimensions. The lower mouth of the metallic flange was cone SRE a Fig. I.—Apparatus arranged for compression of COz. shaped, fitting pretty well the cone on the glass tube. About the conical part of the glass tube and a short distance below it was wrapped a fine thread coated with shoemaker’s wax. When the joint was to be made the metallic portion was warmed and the glass tubes pressed firmly into place and held until cool, This joint stood quite perfectly and gave no trouble, 126 Henry Riddell on The screws shown on the lower part were passed through leather washers steeped in vacno in melted lard, and they also acted so perfectly that I have known the apparatus undisturbed under pressure for weeks and at the end reading identically as before the stoppage, when reduced for temperature and barometer. Of course the forcing in of the screws raised the pressure, two being used to increase the range. A stream of puritied Carbonic Acid was passed through the tube for some hours and the capillary end sealed by heat while the lower ‘portion was in the small reservoir approaching the surface of the mercury. A stream of the gas was continued past the open end for some time after sealing and then the tube was passed beneath the surface of the mercury, enclosing a measured volume of the gas, under barometer pressure and temperature carefully recorded. ‘The volume of the tubes and the variations of internal diameter were very carefully measured by weighing mercury contents and by the usual calibrating method of passing a known quantity of mercury along tho tube and noting the variation in the length oceupied. The result could be relied upon to about one part ina million. The volume of the gas was so calculated that the mercury began to show in the capillary part of the tube at a pressure of about forty atmospheres. Arrangements are shown in the drawing by which the required temperature could be maintained surrounding the tube with the Carbon Dioxide, while the air-tube, well screened from the heat of its neighbour, could be kept at the temperature chosen as the standard for the manometer. The results of the experiments are shown in the diagram (fig. II), and can only be described briefly. It was found that, below a certain temperature, the carbonic acid behaved as a partially saturated vapour, and that on adding pressure the compression at first proceeded in a way somewhat resembling that in a perfect gas, in which, so long as the tem- perature remains unchanged, the product of pressure by volume is constant, and a curve corresponding thereto would be an hyperbola. In the figure the curves show the actual relations Dr. Thomas Andrews: The Great Chemist Oe discovered between volume and pressure, the gas being compressed at a constant temperature in each case. It is seen that within certain limits of pressure the curve in each case resembles an hyperbola, but that below the curve of Pressures in Atmospheres i Zero Line for volumes 2.40 220 200 1a0 160 140 120 100 80 690 40 20 2 Scale of Volumes iow lilt The undulating dotted lines show Jamies Thomson’s theoretical isothermals for 13°°] and 21°'5, 128 Henry Riddell on about 30°C, there is in each case a point at which the volume lessens as the screws are forced into the liquid in the reservoir tubes, while the pressure does not increase until a certain volume is reached at which this action ceases, and the pressure abruptly starts again to rise. ‘The first point marks the beginning of the change into the liquid condition, while the second marks the completion of the change, when the gas is all liquefied, and the increasing pressure is only accompanied by such reduction of volume as corresponds with the gradual compression of the liquid ‘thus formed. If the CO, were quite pure the line showing the process of liquefaction would be truly horizontal, but it proved to be impossible to remove the last vestige of air from the tubes, and it was found that from one five-hundredth to one thousandth part of the volume consisted of air, which is not liquefied under the conditions of the experiment, so that the line has a slight upward tendency corresponding to the increased pressure required to reduce the volnme of the air itself. It will be noticed that, as’ the temperature is greater, this horizontal line in the isothermal curve becomes shorter, so that at a temperature approximative to 30°C., it becomes infinitely short : and at this point the curve has a point of inflexion. This is a critical point of liquefaction, and the particular temperature belonging to this isothermal line is called the critical tempera- ture. It was defined by Andrews as that temperature below which liquefaction visibly oecurs, and above which no pressure, however great, will cause a partial liquefaction, or at which the liquid can exist in presence of the gas He pointed out that the passage from the gaseous to the liquid condition may be made absolutely continuous, and for this reason chose as a title for his statement of results “The Continuity of the Liquid and Gaseous States.” eae . ee The critical temperature is often defined as that tem- perature above which no pressure, however great, will cause liquefaction to take place.” Dr. Thomas Andrews ; The Great Chemist 129 It does not seem that this is a logical statement, nor did Dr. Andrews ever teach in this form. It does not seem possible to show that liquefaction has not taken place when the gas has been sufficiently compressed above the critical temperature. It seems better to define the critical temperature as that above which any conversion of gas to liquid takes place with perfect continuity. We may, however, frame a definition for “ point of lique- faction” by referring to the isothermal curves. In every isothermal below the critical temperature there is a point of the curve in which the diagram shows a break in the nature of the line. This corresponds to the point at which liquefaction is taking place, at which the pressure remains constant while the volume decreases rapidly. If we accept the theoretical curves due to James Thomson—explained before our Society fifty years ago, and shown in figure I[—there are two points on each of these curves at which the tangents are horizontal. These are points of liquefaction or the converse action. Between these points the substance is unstable. It may exist in either state, but tends very strongly to the condition usually apparent at the corres- ponding pressure. On the isothermal belonging to the critical temperature there is a point at which the two tangents coincide, and this becomes a point of inflexion and the critical points, the tangent becoming horizontal and also cutting the curve. To put:the result into mathematical language any tangent to Seay hg ‘ ‘ ; the curve at which Ste: marks a point of liquefaction, while dv 2 at a critical point we have also = ==) The isothermal curve is therefore one of the third degree, and many equations have been framed to express this, some of which will be referred to later. * These experiments and conclusions of Professor Andrews form a great part of the foundation of the art of refrigeration, 130 Henry Riddell on One of the greatest of the French inventors in this development of industry says—‘“This remarkable scientific man very wisely turned his attention to a simpler problem, that of the liquefaction of Carbonic Acid. with a view to investigating its characteristics. From this investigation. was destined to be born the general theory of liquefaction and the ideas, more than ever prevalent at the present time, on the Continuity of the Liquid and Gaseous States.” On hearing Andrews’ paper shortly after the delivery of the Bakerian lecture of 1869, the then President of our Society, Joseph John Murphy, offered a suggestion for the calculation of the critical temperature of water, rather interesting under the circumstances. He argued that clearly the critical temperature was that at which the latent heat of conversion to vapour vanished. “if, then, we accept Reynault’s equation,” said Mr. Murphy, “throwing it into the form—Latent Heat = 606-5 — -695t, when the latent heat vanishes we have -695t=606-5, or t=873°C.” Of course this temperature is far too high, but the error was in the equation and not in the method suggested. Reynault’s equation gave fair values at moderate temperatures between 100° and 200°, but the equation representing the facts has a factor € = -) where v=volume in liquid form and V volume of same quantity in vapour, both taken at the temperature ¢ At 100° the term v v has a value of about 0:0006, so that G = =) is very nearly unity. At 200° the value of = is roughly 0-009, so that it is rapidly increasing yet still nearly negligible. Ata temperature v V about 374° v becomes equal to V, and the Latent Heat becomes zero. Thanks to the introduction of quartz tubes the critical point of water is measured fairly easily. In 1876 Dr. Andrews, in his second Bakerian lecture, gave of about 250° the value of has risen to about 0-025, while Dr. Thomas Andrews: The Great Chemist 131 an account of many experiments, the bearing of which was not immediately perceived. In comparing the behaviour of CO, at various temperatures and pressures, he deduced several laws connecting the different isothermals, but it is impossible to give any detailed account of the investigations. It is of interest, however, to consider one of the suggested laws and to connect it with some others offered by such men as Rankine and Van der Waal. His experiments showed that, for a great part of the range, the isothermal curves of the vapour approximately answered the equation C=V(1-—Vp), where V is the volume, p the pressure, and Ca constant. A perfect gas being represented by Vp =constant, this equation of Andrews showed the departure of the vapour from the ideal. If two such equations on the same isothermal curve, in the form eee 1— V, P, and Bes =1-V,P,, Vy V, Pee Oa at 2 be subtracted, the result is —--~~=V,P.—V,P,. If the alge fe equation be assumed true for the gas from a very low to a moderate pressure, then we may take P, as very low, and C : consequently 7, may be supposed to vanish as P. becomes 2 4 A : (Cs ; indefinitely small, leaving the form pr — VP, where R is the ideal VP when P becomes very small. This then appears to be the true form of Andrews’ equation, and if the proper corrections are made for the presence of air, &c., it represents the true facts within reasonable limits of pressure. It may obviously be thrown 2 C : my? into the form R= V (P +72) For very high pressures this is obviously untrue. It becomes necessary to have a factor which vanishes when FP is infinite, and this is found by writing (V — a) instead of V as the factor outside the bracket, when a must be the limit of volume of the gas as P becomes very great, This then gives Van der Waals’ equation (V-—a) (P+) With 132 Henry Riddell on proper values for a and C this equation gives a very good approximation to the experimental results, as long as the gaseous condition is plainly present, but at very high pressures a small error in a or V introduces so great a change in the results that it is useless under such circumstances. mai van the relation between two points on the same isothermal, if P, is - Again, in the equation - = V, P.— V, P,, representing unity, and by the conditions of the experiments V, also unity, mY the equation becomes 7 1+C—VP, but comparing this with previous results it is plain that 1+ C is sensibly equal to R, as already defined, and an equation resembling Rankine’s simple aC ‘ =P. form appears poe Again, this represeuts the results better if the first term be aoa where a has the value already mentioned. -Thus Rankine’s, Van der Waals’, and also Clausius’ equations are very closely related to this simple approximation due to Andrews. The connection between different temperatures was also investi- gated, and valuable results obtained. In his later experiments upon the behaviour of mixed gases under changes of temperature assumed as and pressure, some results were obtained, the value of which was not apparent until the liquefaction of air became an economic SUCCESS. It is impossible to follow Andrews’ work further in such a sketch as this. It is well, however, to remind the reader of the very remarkable anticipation of the results of the experiment on the critical condition, which is found in the hypothesis framed by Mendeleéff at the very time Andrews was completing his experi- mental work. He predicates a condition in which, by combination of temperature and pressure, a vapour becomes of the same density as its liquid under the same circumstances, and concludes Dr. Thomas Andrews: The Great Chemist Les that, at this point, which he calls the absolute boiling point, the latent heat becomes zero. I should like to say a few words about the services of Dr. Andrews in another than the scientific side of his work. He was the leading spirit in the foundation of the Queen’s University of Ireland. It is not generally understood that the first idea of the Government was to establish three Colleges in Ireland for the general education in Arts of the middle classes, without the purpose of forming them into a University. There was not, apparently, any intention of providing professional edu- cation in such subjects as Medicine and Engineering. Dr. Kane in his report seems to have taken this for granted, but Dr. Andrews vigorously combated this view. I have the rough draft of a memorandum in his hand-writing, in which he urges that the Government must take up the work of framing a University, as the Colleges could never be maintained in a working condition unless this were done. He also argues that the neglect of the special education required for those proceeding to qualify for the professions will drive large numbers of the possible students to other centres of learning, and that it will be impossible to fill the class-rooms with those anxious only to obtain an education in the usual Arts courses. He sketches an arrangement for a Medical School, almost completely agreeing with that provided later when the College was opened, and suggests that, on the provision of such facilities, the Medical School then in operation in the Royal Academical Institution should be discontinued, and the Institution should completely revert to its original purpose of providing a first-rate secondary education for the youth of the middle class inhabitants. Dr. Andrews always remained greatly interested in educational schemes, and published a most interesting and powerful pamphlet, entitled “Studium Generale,” explaining his views, which have since come to fruition, at least to a large extent, in the Queen’s University of Belfast. 134 : Henry Riddell on The following is a list of the papers contributed to our Society by Dr. Andrews, and will be interesting to our members :— 6th April, 1836.—Construction of electro magnets. 4th October, 1837.—HElectrical conduction. ‘ 17th January, 1838.—llame and the oxy-hydrogen blow-pipe. 6th February, 1840.—-Some recent applications of galvanism to the arts. ' 3ist March, 1841.—Radiant heat. 10th March, 1842.—On the subject of heat. 15th February, 1848.—On the heat of combination. 3lst January, 1844. 23rd April, 1845.—Some recent discoveries in organic chemistry. 13th May, 1846.—An account of Dr. Faraday’s recent discoveries in magnetism. 4th November, 1846.—The heat developed in combustion and other cases of chemical action. On animal heat. 30th December, 1846.—The construction and method of using certain meteorological instruments. 16th April, 1851.—(1) On certain applications of polarised light to chemical analysis; (2) on the presence of magnesia in magnetic iron Ore. 17th December, 1851.—On the spheroidal condition of bodies. 9th March, 1853.—Communication on the construetion and use of certain meteorological instruments and results obtained during the previous two years at Queen’s College. 8th March, 1854.—Composition and properties of ozone. 15th November, 1854.—Photography. 18th March, 1857.—Preparation and properties of aluminium. 4th November, 1857.—The manufacture of stearic acid and other analogous bodies employed for illuminating purposes. 19th January, 1859.—The metals of the alkalies and alkaline earth. 7th March, 1860.—Recent researches regarding the properties of some of the chemical elements. 2nd May, 1866.—Spectrum analysis. 8th April, 1868.—Atmospheric ozone. | 17th February, 1869.—The mechanical analysis of rocks. 23rd February, 1870.—The continuity of the liquid and gaseous states of matter. 3rd March, 1875.—The analysis of the Ballynahinch water. 17th March, 1875.—EHlectro-magnetic machines and the recent im- provements on them by M. Gramme. Dr. Thomas Andrews: The Great Chemist 135 It is interesting to note, that in 1902, thirty-two years after Dr. Andrews’ paper in 1870 ‘‘ The liquefication of gases and the continuity of state,” was the subject of an address at the Belfast meeting of the British Association by the then President, Sir James Dewar. As an appendix to one of his lectures before the Royal Society, Dr. Andrews printed for the first, and possibly the only time, several letters from M. Lavoisier to Dr. Joseph Black. To render these letters more generally accessible they are reprinted here. The reader is referred to p. 49, Proceedings of Society, 1919-20; for some account of Black and his Belfast connections. LETTERS FROM M. LAVOISIER TO DR. BLACK. Paris le 19 Septembre, 1789. MonsiEuR,—C’est un membre de lacadémie Royale des Sciences de Paris qui vous écrit a titre de Confrere: c’est un des plus zélés admirateurs de la profondeur de votre génie et des importantes révolutions que vos découvertes ont occasionées dans les Sciences, qui profite, pour avoir Vhonneur de vous écrire, de l’oceasion de M. de Boullogne qui va finir son éducation 4 Edimbourg. Permettez-moi de vous le recommander. I] joint 4 @heureuses dispositions un grand désir de s’instruire et il regarde comme un grand bonheur pour lui d’avoir une occasion pour se présenter & vous. Il a bien voulu, Monsieur, se charger de vous remettre un exemplaire d’un ouvrage que je viens de publier: vous y trouverez une partie des idées dont vous avez jetté le premier germe: si vous avez la bonté de donner quelques instants a sa lecture, vous y trouverez le développement d’une Doctrine nouvelle que je crois plus simple et plus d’accord avec les faits que celle du Phlogistique. Ce n’est au surplus qu’en tremblant que je le soumets au premier de mes juges et a celui dont j’ambitionnerais le plus le suffrage. J’ai Vhonneur d’étre trés-respectueusement, Monsieur, Votre trés-humble et trés-obéissant Serviteur, 136 Henry Riddell on Paris, 24 Juillet, 1790. MownstEvuR,—J’apprends avec une joye inexprimable que vous voulez bien attacher quelque mérite aux idées que j'ai professé le premier contre la doctrine du phlogistique. Plus confiant dans vos idées que dans les miennes propres, accoutumé d vous regarder comme mon maitre, j’étois en défiance contre moi-méme tant que je me suis écarté sans votre aveu de la route que vous avez si glorieusement suivie. Votre approbation, Monsieur, dissipe mes inquictudes et me donne un nouveau courage. Cette Lettre, Monsieur, vous sera remise par M. Terray intendant de Lyon neveu du Ministre des finances de ce méme nom et mon parent; il conduit 4. Kdimbourg son fils, jeune homme d’espérance et destiné a posséder une grande fortune, pour y finir son éducation et suivre les leeons des professeurs célébres de Vuniversité d’Edimbourg. Permettez-moi, Monsieur, de vous le recommander. L’intérét que vous voudrez bien prendre ad lui sera un premier titre qui lannoncera d’une manicre avantageuse et j’ai lieu de croire qu il ne se rendra pas indigne de vos bontés. Je ne serai pas content jusqu’a ce que les circonstances me permettent de vous aller porter moi-méme le témoignage de mon admiration et de me ranger au nombre de vos disciples. La révolution qui sopere en France devant naturellement rendre inutile une partie de ceux attachés 4 Vancienne administration, il est possible que je jouisse de plus de liberté; et le premier usage que j’en ferai sera de voyager ev de voyager surtout en Angleterre et & Edimbourg pour vous y voir, pour vous y entendre et profiter de vos lumiéres et de vos conseils. J’ai commencé un grand nombre d’ouvrages et de travaux et j/aspire dun Etat de tranquillité qui me permette d’y mettre la derniére main. Jai Vhonneur d’étre trés-respectueusement. Monsieur, Votre trés-humble et trés- obéissant serviteur. AW v : M. Black, de Vacadémie des sciences, Dr. Thomas Andrews : The Great Chemist 13% Paris, le 19 Novembre, 1790. M. Terray, Monsieur, m’a remis, en arrivant a Paris la lettre que vous m’avez fait Vhonneur de nvécrire le 24 Octobre ; il ne pouvait me faire un présent qui me fit plus agréable. J’ai cru que vous ne désapprouveriez pas que je la communiquasse 4 l’ Académie des Sciences ; elle n’a pas moins admire l’élégance du style que la profondeur de philosophie et la candeur qui regne dans votre lettre, et elle a méme désiré qu'elle fit déposée dans ses registres ; mais je n’y ai consenti, qu’a condition qu'il m’en serait remis une copie certifi¢e du secrétaire. J’ai une autre grace 4 vous demander, mais sur laquelle je dois attendre votre aveu; c’est de vouloir bien me permettre d’en publier la traduction dans les Annales de Chimie. M. Gillan a été témoin, depuis son séjour 4a Paris, de quelques expériences que j’ai faites sur la respiration et il a bien voulu y concourir. Nous nous sommes assurés des faits suivans : 1°. La quantité @air vital ou gaz oxigéne qu’un homme en repos et jeun consomme, ou plutot convertit en air fixe ou acide carbonique, pendant une heure est de 1200 pouces cubiques de France environ, quand il est placé dans une température de 26 degrés. 2°. Cette quantité s’éleve 4 1400 pouces, dans les mémes circonstances, si la personne est placée dans une température de 12 degrés seulement. 3°. La quantité de gaz oxigéne consommée, ou convertie en acide carbonique, augmente pendant le tems de la digestion et s’éléve A 1800 ou 1900 pouces. 4°. Par le mouvement et l’exercice on la porte jusqu’’A 4000 pouces par heure et méme davantage. 5°. La chaleur animale est constaniment la méme, dans tous ces cas. 6°. Les animaux peuvent vivre dans ce lair vital ou gaz oxigéne, qui ne se renouvelle pas, aussi longtems que l’on le juge 4 propos, pourvu qu’on ait soin d’absorber, par de Valcali caustique en liqueur, le gaz acide earbonique, & mesure qwil se forme; en sorte que ce gaz n’a pas besoin, comme on le croyait, pour ¢tre salubre et propre a la respiration d’étre mélangé avec une certaine portion de gaz azote ou Mophete. 7. Les animaux ne paroissent pas souffrir dans un mélange de 15 parties de gaz azote et d’une partie de gaz oxigéne, pourvu qu’on ait de méme la précaution d’absorber le gaz acide carbonique, par le moyen de Valeali caustique, 4 mesure qu'il est formé. 8°. La consommation du gaz oxigéne et sa conversion en acide carbonique est la méme dans le gaz oxigéne pur et dans le gaz oxigéne mélé de gaz azote, en sorte que la respiration n’est nullement accélérée en raison de la pureté de Vair. 138 Henry Riddell on Dr. T. Andrews: The Great Chemist 9°. Les animaux vivent assez longtems dans un mélange de deux parties de gaz inflammable et d’une de gaz oxigene. 10°. Le gaz azote ne sert absolument a rien dans l’acte de la respiration et il ressort du poumon en méme quantité et qualité qwil y est entré. 11°. Lorsque par l’exercice et le mouvement on augmente la con- sommation de gaz oxigéne dans le poumon, la circulation s’accélére ; ce dont il est facile de s’assurer par le battement du poulx: et en général lorsque la personne respire sans se géner, la quantité de gaz oxigéne con- sommée est proportionnelle a augmentation du nombre des pulsations multiplié par le nombre des inspirations. Tl est bien juste, Monsieur, que vous soyez un des premiers informés des progrés qui se font dans une carriére que vous avez ouverte, et dans laquelle nous nous regardons tous comme vos disciples. Nous suivons les mémes expériences, et j’aurai lhonneur de vous faire part de mes découvertes ultérieures. J’ai VPhonneur d’étre avec un respectueux attachement, Monsieur, Votre trés-humble et trés-obéissant Serviteur, OW ’ BELFAST ; NATURAL HISTORY AND PHILOSOPHICAL SOCIETY. PROCEEDINGS, SESSION 1920-1921. No. 4. ABSTRACTS OF LECTURES, ANNUAL REPORTS. coe LIST OF MEMBERS, &c. BELFAST : MAYNE, BOYD & SON, LTD., 2CORPORATION STREET (PRINTERS TO THE QUEEN’S UNIVERSITY). & : : 1922. Proceedings of the Belfast Natural History and Philosophical Society, 1920-1921. 11th January, 1921. Professor GREGG WILSON, President of the Society, in the Chair. Pueiic LECTURE IN ASSEMBLY MINoR HALL, entitled : THE WONDERLAND OF THE WASPS. By Joun J. Warp, F.E.S. (Abstract.) In introducing his subject the lecturer referred to certain wasp mimics, insects masquerading as wasps, and deriving pro- tection from their black and yellow covering and wasp-like appearance ; and in this connection showed slides of the wasp beetle, hover fly, and the lunar hornet moth. The life story of the latter insect was told in detail and illustrated by means of wonderful photographs, and incidentally introduced a parasitic enemy—the long-tailed ichneumon wasp. The wasps were divided into two great classes, namely, the Solitary and the Social species. Then came _ astonishing revelations of the life histories of various solitary species, almost unbelievable wonders observed by the lecturer were demonstrated on the screen by means of his instructive photographs. The life story of the Mud Wasp (Odynerus antilope), Mr. Ward stated, had taken him seven years to work out in detail. The little wasp appeared for only about three weeks during the month of June, building its nesting cells on a flat brick wall, preferably that of a newly-built house. The cells were constructed with a kind of cement, which the wasp manufactured by scraping a piece of sandstone with its mandibles and then mixing the sand grains so obtained with saliva. When a cell was made the wasp then stored it with live caterpillars, which it captured, and, with 140 John J. Ward on the skill of an experienced surgeon, stung so as to paralyze, but not to kill. After each caterpillar was in this manner placed under an anesthetic, it was then carried by the wasp to the cell and there stored, from eight to sixteen of them, packed like sardines ina box. ‘The wasp then deposited an egg in the cell and. sealed it up. In that way it provided its offspring with fresh meat. The whole development of the wasp grub was shown from the egg stage until it completed its metamorphoses and appeared as a fully-developed wasp. Details were also revealed of the natural enemies of the mud wasp, one of which was the common blue tit, and particularly interesting were the gorgeously-coloured cuckoo wasps, which came and deposited their eggs in the cells of the mud wasp before they were sealed up. . Leaving the solitary species, the lecturer then dealt with the social species, which included the common wasp. These con- sisted of tree wasps and ground wasps. The former built their nests in trees in the open sunlight, and the latter below ground in darkness. After describing the anatomy of the mouth parts of the common wasp, and also that of its stinging organs, the nests of tree wasps were described. The final part of the lecture was devoted to the complete story of the building of the nest of the common ground wasp, from the time when the queen leaves her hibernating place at the beginning of May and commences to build a new wasp city at the end of a mouse run of the previous summer. ‘The queen wasp was shown with the little nest she had constructed quite unaided. It was no larger than a five- shilling piece, but after her first offspring appeared it soon grew apace, and eventually became as big as a four-pound loaf. Mr. Ward displayed astonishing photographs showing the combs of the nest with their hosts of worker wasps carrying on their functions. At this stage the queen wasp had nothing todo but deposit eggs in the thousands of cells being made by the workers. The latter carry on all the work of the nest, building, feeding and tending the young wasp grubs, excavating the soil, The Wonderland of the Wasps 141 etc. Eventually the queen wasp became the mother of from 20,000 to 60,000 wasps. As autumn approached, dome-shaped cells appeared, and from these emerged the young queens and their suitors, the males, to carry on the generations for the next year. Photographs showed the wasps biting their way out of the cells as they matured, and the cells being cleaned and pre- pared almost immediately for another egg to be placed in them by the queen, for they could be used three times during one summer. One slide displayed a comb containing over 4,000 cells, which used three times would represent 12,000 wasps, and the nest often contained ten combs, although not all so large as that one. At the first signs of wintry weather the worker wasps quickly perished, and the nest soon became a complete ruin, only the young queens could live through the winter, each surviving one would then become the mother of a new wasp colony the following year. At the conclusion of the lecture the Chairman said while there would be no formal vote of thanks, he would ask the audience to express their appreciation of the brilliant and most fascinating lecture they had just listened to. He thought the interest with which the lecture had been followed had been felt by the lecturer throughout the evening, and that was the best thanks they could give to him. 142 25th January, 1921. Professor GREGG WILSON, President of the Society, in the Chair. IN Museum, CoLLEGE SQuARE NORTH. “ART AND WORKMANSHIP.” By Ivor Beaumont, A.R.C.A., M.S.A., F.RS.A., F.I.B.D. Head Master, School of Art, Municipal College of Technology, Belfast. (Abstract.) Mr. Beaumont said, broadly speaking, art was connected with all the works of man which were primarily meant to satisfy the aesthetic instinct. The craving for beauty and harmony was inherent in all human beings. By Works of Art he did not mean only those things which appeal to the eye and touch ; in the term “ Art” he included all manifestations which arose out of and tended towards the satisfying of man’s desire for beauty and harmony. Art was therefore rarely divorced from industry ; art was indispensable in life, and it should have an important place in the course of general education. In conclusion, Mr. Beaumont said it should never be forgotten that Schools of Art were provided for the industries and not the industries for the Schools of Art. Once they got that fact fixed in their minds, they would take care that the training given in the Schools of Art was thoroughly practical, and that students were properly itted to take their place in the industries which they intended to enter. The lecture was illustrated with a beautiful series of lantern slides, and at the close a hearty vote of thanks was passed to the lecturer, 143 8th February, 19217. The President, Professor GREGG WILSON, in the Chair. In Musrum, CoLLeEGE SQuARE Nortu. THE DECORTICATION OF FIBROUS PLANTS, WITH SPECIAL REFERENCE TO FLAX RETTING AND SCUTCHING. By H.R. CARTER: (Abstract. ) Mr. Carter, in the course of his remarks, said that it has been aptly stated that “the Great War was won by Belfast wings,’ the Ulster capital providing the bulk of the aeroplane linen. The cultivation, retting, scutching, and spinning of flax was one of Ulster’s greatest industries. Mr. Carter divided vegetable fibres into three classes namely, those obtained from the bark of the plants, such as flax, true hemp, jute and ramie ; those derived from the more or less fleshy leaves, or from the part of the plant enclosed by the bark, including Sisal, New Zealand hemp, and other hard cordage fibres ; and thirdly, fibres derived from the seed pods of which the principal are cotton and coir. Of these three classes, only the first two require processes of decortication, and of course the treatment of the flax plant is that of special interest in Ireland. The lecturer displayed excellent lantern illustrations of the various processes in connection with the treatment of this fibre, laying special stress upon the highly scientific methods of growing and preparation of the fibre in vogue in the valley of the river Lys in Belgium. From this district is derived the best and finest quality of flax fibre in the world, and he emphasised the ‘ 144 H.R. Carter on The Decortication of Fibrous Plants importance to Ireland of these methods being more fully adopted in this country. Irish flax, if properly treated agriculturally, is quite equal to that grown in Belgium or Holland; lax and unscientific methods of growing, retting, scutching and general handling, however, reduce its market value considerably as com- pared with the product of Belgium and Holland. A vote of thanks to the lecturer brought an interesting address to a conclusion. ANNUAL MEETING. VOC Se SSlON,, Toe2Ore The Annual Meeting of the Shareholders and Members was held in the Museum, College Square North, on the 21st November, 1921. Professor Gregg Wilson, O.B.E., M.A., D.Sc., Ph.D., President, occupied the Chair, and among those present were :—Sir Charles Brett, LL.D.; Alderman S. T. Mercier, J.P.; Messrs. H. C. Lawlor, M.R.I.A.; William Faren, Godfrey Ferguson, J.P.; W. B. Burroughs, T. Edens-Osborne, W. M. Crawford, Victor Salter, and Arthur Deane, Hon. Secretary. Apologies for absence were announced from Sir Frederick Moneypenny, C.B.E., C.V.O.; Dr. S.. W. Allworthy, M.A., F.G.S.; Dr. Gawin Orr, Councillor E. J. Elliott, Mr. R. M. Young, M.A., M.R.I.A.; Mr. Henry Riddell, M.E., M.I.Mech.E. ; Mr. J. M. Finnegan, B.A., B.Sc., and Mr. Alexander Milligan. The Chairman called upon the Hon. Secretary to read the notice convening the meeting, and also the Annual Report of the Council, which was as follows :— The Council has pleasure in presenting to Shareholders and Members of the Society the Annual Report and Statement of Receipts and Expenditure for the 100th Session of the Society. OBITUARY. It is with deep regret the Council records the loss by death of Mr. Burton Sefton, Mr. James Moore, and the Rev. Canon H. W. Lett, M.R.I.A. Mr. James Moore was. a member of an old merchant family in Belfast. Every one knows the old- fashioned front of the warehouse in Donegall Place, about the 146 Annual Meeting only one in that thoroughfare which has remained unchanged for more than sixty years. Mr. Moore was a member of our Society for many years He was a kindly-hearted and courteous gentle- man, and his loss will be greatly felt. Canon Lett’s death leaves a gap inthe ranks of Northern Naturalists. He devoted con- siderable time to the study of the lower Irish Cryptogams and to Irish Archaeology, both prehistoric and ecclesiastical. He was born at Hillsborough on the 4th December, 1836, and died at Aghaderg on the 26th December, 1920, at the age of 84. Mr. Burton Sefton was one of the members who joined the Society through the new scheme of membership. He took a great interest in our proceedings, and died in August last. MEMBERSHIP. The total number of Shareholders and Members at the end of session was 291. Your Council has had under consideration the propriety of creating life members on the basis of one pay- ment, but it was decided to postpone further consideration of this proposal for one year. Your Council has observed with great satisfaction that our oldest member, namely, Sir Charles Brett, has had conferred upon him the LL.D. degree, Honoris Causd, of the Queen’s Uni- versity, Belfast, and that the Vice-Chancellor of the University (The Right Hon. the Rev. Thomas Hamilton, M.A., D.D., LL.D.), another old member of the Society, has been appointed a member of His Majesty’s Privy Council in Ireland. LECTU RES. Your Council records with pleasure that the Programme of Lectures arranged for the 100th Session was the best in the history of the Society. The Council feels that the Society is worthily fulfilling the wishes of the early members in the efforts. Annual Meeting 147 made to-day to diffuse useful knowledge among the citizens by means of popular addresses and short courses of lectures. It is interesting to note that arrangements for short courses were com- menced as early as 1837, when Dr. James Drummond Marshall delivered a course of twelve lectures on “ Birds: their classifica- tion, geographical distribution, and habits.” A good deal of original work was brought before the Society by some of the lecturers. The Council would like to point out that the publication of a programme does not in any sense preclude the reading of original papers, which may be submitted to the Council during the session. A list of the lectures delivered during the period covered by this report will be found in Appendix, p. 158. COUNCIL'S THANKS. The Council is again indebted to the Vice-Chancellor of Queen’s University (The Right Hon. the Rev. Thomas Hamilton) for granting your Society accommodation in the University. On this occasion two courses were delivered by two University Professors, namely, Professor A. W. Stewart and Professor James Small. To these gentlemen the Council tenders, on behalf of the Society, its sincere thanks for the continued co-operation between the University and our Society. As far back as 1858 Dr. Thomas Andrews, F.R.S., M.R.I.A., Professor of Chemistry, and Vice-President of Queen’s College, delivered a course of six lectures on Chemistry in the Chemical Lecture Theatre at Queen’s College, under the auspices of the Society. - The Council also desires to express its best thanks for the assistance rendered by the other lecturers during the session, and to the local Press for the full reports of the various meetings. 148 Annual Meeting CENTENARY VOLUME. Your Council has had under consideration the compilation of a Centenary Volume, giving a history of the Society, with a series of memoirs of the distinguished men connected with the Society in the past. This work is well in hand, and the Council hopes to publish this volume during the present session. EXCHANGES. Your Council continues to receive in exchange various publications, both home and foreign, from kindred societies, many of which are of great importance. The Council regrets, how- ever, to report that the American Geographical Society has intimated that it proposes to limit its exchange list to those publications which are distinctly geographical in character. Application for back numbers of our Proceedings have been received from the following :— The Brooklyn Museum. New York Public Library. New York Academy of Science. Museum of Comparative Zoology, Cambridge, Mass. United States Department of Agriculture. Department of Agriculture, Canada. The Patent Office Library, London. A number of publications were also received from the Com- mittee of the Ulster Fisheries and Biology Association on the winding-up of the Association. ARCHAEOLOGICAL SECTION. A separate report of the Archaeological Section will be submitted to the members by. its Hon. Secretary, Mr. H. C. Lawlor, M.R.I.A., at the Annual Meeting of the Section, which is to be held on Monday, the 28th instant. Annual Meeting - 2a ELECTION OF COUNCIL. In accordance with the constitution of the Society, the five following members retire by rotation from the Council :— Mr. J. M. Finnegan, Mr. Henry Riddell, Mr. R. M. Young, Pro- fessor Lindsay, and Professor Symmers. The two last named are ineligible for re-election. ° HON. TREASURER’S STATEMENT. The Hon. Treasurer (Mr. Henry Riddell) is unable to be with us this afternoon owing to an unfortunate accident which occurred to him some weeks ago, and which necessitated an operation.. The Council is glad to report that he has made satisfactory progress, and hopes to be among us again soon. He has laid upon the table the Statement of Accounts which has been passed by the Local Government Board Auditor, and which will appear on p. 160 of the. printed report, and submits a report which will be read to the meeting. : LOYAL ADDRESS. Your Council, on behalf of the Society, submitted a loyal and dutiful address on the occasion of the visit of Their Most Gracious Majesties King George V. and Queen Mary, to open the Parliament of Northern Ireland, on the 22nd June, 1921. The time at the disposal of their Majesties, however, was not sufficient to allow of a personal presentation of the address, but it was duly acknowledged later by Lord Stamfordham, Private Secretary to His Majesty. HON. TREASURER’S REPORT For YEAR ENDING JUNE 30TH, 1921. Both the Society and the Section for Archaeological Study are to be congratulated on a year of considerable progress. 150 Annual Meeting The joint subscriptions for the year amount to One Hundred and Fifty-Four Pounds Seventeen Shillings, being an increase upon the previous year of almost thirty-five per cent. It will be seen, when the Balance Sheet is sent out to the Members, that the expenditure during the past year exceeded the income by over. One Hundred Pounds, and the Local Government Board Auditor, in his report, calls attention to this fact. It will be remembered, however, that attention was called last year to the fact that the balance-sheet then presented gave - too favourable an impression of the finances, owing to the fact that the printers had not furnished their accounts for a great part of the Session, and that the Archaeological Section had on deposit with the parent Society a sum of Ninety-three Pounds. The printed accounts appear in the present statement, and the balance of the Archaeological Section is now reduced to about Seventy Pounds. Every care and foresight is exercised with regard to the finances, and the members may be assured that nothing is spent which cannot be afforded. The cost of printing has been exceedingly heavy, but of course may be expected to fall with the decreasing cost of production. It is felt that neither the Council nor the members of the Society would urge any curtailment of the reports of proceedings, unless such were absolutely necessary. Very many of our members cannot attend the meetings, and the Proceedings form the only connection they can have with the Society. It is evident also, from the frequent demands from outside bodies, that they arouse much interest. They are also the source of exchanges of the most extraordinary value, which will in the future form an important library. ADOPTION OF REPORTS. The Chairman, in moving the adoption of the Reports, said the Society had had a very busy year, and had very large audiences at all their meetings, some of which were as interesting Annual Meeting 151 as any he had ever attended in Belfast. He hoped in the future they would manage to keep the Society as active as it had been recently. In regard to finances, while they were not in funds, they were rapidly coming to the day when they would have a little money to spare as they used to have. They were much indebted to their Hon. Treasurer (Mr. Henry Riddell) for the care he had taken to keep them as far as possible in good financial position, which was a very important matter in these days. In conclusion, the Chairman spoke of the valuable work of Mr. Riddell and the Hon. Secretary on behalf of the Society, and especially in con- nection with the Centenary Volume Alderman S. T. Mercier, in seconding the resolution, said he had the pleasure of attending many of the lectures, and had found them most helpful and beneficial. If they found the Society was getting into financial difficulties, he suggested that a small fee should be charged for admission to the lectures, which at present were free. VOTE OF THANKS TO PRESIDENT. Mr. H. C. Lawlor, M.R.LA., moved a vote of thanks to the outgoing President (Professor Gregg Wilson) for his valuable services during the past two years. The Society, he said, would always remember with pleasure Professor Wilson’s term of office. This was seconded by Sir Charles Brett, IL.D., who also spoke in appreciative terms of Professor Wilson’s services, and this was very heartily adopted. On the motion of Mr. T. Edens Osborne, seconded by Mr. Godfrey Ferguson, it was unanimously agreed that the Hon. Secretary should convey to Mr. Henry Riddell the feelings of the members present in that they were gratified to know that he was recovering from his recent accident, and that they express to him the hope that he would soon be among them again, 152 Annual Meeting ELECTION OF COUNCIL MEMBERS. Messrs. J. M. Finnegan, Henry Riddell, and R. M. Young were re-elected Members of the Council for three years. retiring in 1924; together with Professor Morton and Professor A. W. Stewart. The new Council held a meeting after the conclusion of the Annual Meeting, when the office-bearers were elected for the Session 1921-22. These, together with the Council of Manage- ment, will be found on page 162. ARCHAEOLOGICAL SECTION. ANNUAL MEETING. The Fifth Annual Meeting of the Section was held in the Old Museum on Monday, the 28th November, at 3-45 p.m., Sir Charles Brett, LL.D., in the chair. The minutes of the previous Annual Meeting were read and confirmed. In the unavoidable absence of the Hon. Treasurer, Mr. Henry Riddell, through indisposition, the financial report was read by the Hon. Secretary of the Section. The balance- sheet, made up to June 30th, is given on page 161, showing a balance to credit of the Section at that date of £70 lls. 4d. To this must be added a little over £30 arising from current year’s subscriptions and subsidy from the parent Society, less a few outstanding accounts, leaving slightly over £100 in hand, avail- for the work of the coming season. The Hon. Secretary of the Section read a report on the work of the Section during the past year. In the early part of the season he had issued to all the members and some others likely to be interested, invitations to suggest subjects for investigation, under the auspices of the Section. The replies to this circular were gratifying, and were laid before a meeting of the Executive Annual Meeting Be Committee on June 16th—Sir Charles Brett presiding. Sixteen monuments of archaeological interest were .recommended for investigation by the Section, mostly by members, and a few by non-members. These were carefully considered, and all recorded in the minutes for future reference. Out of the sixteen the following were selected as being of most importance :—- 1. The ecclesiastical remains on Mahee Island, anciently Nendrum, in Strangford Lough. Further excavations in Rathkeltchar in the field north and north-east of the Cathedral. The Castle and Abbey site of Portmuck, Islandmagee. The Stone circle at Kilmakee, Templepatrick. The Cromlec at Shieve na Griddle in Lecale. Harryville Moat, Ballymena. Lo eee The Committee considered that the proper execution of the investigation and preservation of the remains at Mahee Island would entail greater expenditure of money than the funds at their disposal permitted, and this work was deferred. With regard to Rathkeltchar, it was considered by a majority that further investigation would fortify the conclusions arrived at from last year’s investigations, and a grant of £30 was voted towards the object, the Hon. Secretary being instructed to communicate with the Downpatrick members who had helped in this work last year, and to arrange, if possible, for this work to be carried out in the July holidays. It was considered that this grant depleted the sum at the disposal of the Section sufficiently for the time, and that the remaining selected subjects for investigation be let lie in abeyance for future consideration. A further meeting of the Executive Committee was held on the 27th July,—Sir Charles Brett presiding. The Hon. Secre- tary stated that arrangements had been practically completed for the work at Rathkeltchar to be carried out during the July holidays, when owing to the drought then prevailing, and the consequent shortage of grass, the tenant of the grazing, at the 154 Annual Meeting last moment, withheld his permission to carry out the work, which had therefore been abandoned for the present. The Executive Committee then allotted the following grants for three of the other objects considered at the meeting in June 16th :-— To Major Thompson, D.S.O., for the investigation of the Castle and Abbey Site of Portmuck, Islandmagee— oF To the Rev. William Adams, M.A., for the investigation of Kilmakee Stone Circle—£15. To Colonel Berry, M.R.I.A., for the investigation of the Cromlec at Slieve na Griddle—£5. Owing to various unforseen circumstances, none of these grants had been taken advantage of, and while it was to be regretted that no actual excavation work had been carried out during the year, it was satisfactory that consequently the funds available for future work were so much greater. ANCIENT GRAVE AT CREA, KILLYLEAGH.—In April the Hon. Secretary received a communication from Mr. James Heron, D.L., of Tullyverey, Killyleagh, to the effect that a remarkable prehistoric grave had been discovered in a rath in the townland of Crea, on the farm of Mr. Boyd, and requesting him to inspect the same, and record the find in the Society’s reports. He accordingly visited the site in company with Mr. Heron and Mr. Boyd. The rath, if it is one, is of somewhat unusual formation. It is situated on the summit of a small hill in the middle of a field. It is from 8’ to 12’ high above the somewhat uneven contour of the ground ; it is flat on top with no rampart, and no surround- ing trench or vallum : the diameter measured (on the top) about 27 paces. Mr. Boyd, to cover a bare spot in his field, had removed a few cart loads of soil from the side of the rath or mound. In doing so, he removed a flat stone which had been placed on its edge. The removal of this stone disclosed the end of a stone- lined grave, measuring 5’ 8” long, by 14” wide, and 11” high, Annual Meeting 155 internal measurement. The grave lay due East and West; lying within were the remains of a skeleton, which he raked out and buried a few feet from the grave. No relics of any kind® were found with the remains. The grave was of a class exactly similar to those so fre- quently found in the Abbey field at Portmuck, and at Gransha, Islandmagee, in which coins of the first Edwards were found, that it is possible that it dates as late as between the 12th and 14th centuries ; it may be earlier, but from its orientation and similarity to graves known to be mediaeval, it may be regarded as certainly not pre-Christian. The flat top of the mound was under cultivation, and a very careful search of the surface showed no sign of pottery or charcoal remains. This tends to indicate that the mound is not, correctly speaking, a rath, but a burial monument in which most probably other graves still exist. BALLYLOUGH CRANNOG.—As requested by the Committee, the Hon. Secretary, by arrangement with, and by kind permission of Colonel Traill, D.L., visited this site in August. The various annals and other records make frequent mention of Ballylough, otherwise Loughtown. During the Norman occupation it was held under the Earldom of Ulster by the Savages, who with their neighbours, the de Mandevilles, were the chief holders of land in the Route. Ata later date the annais refer to these lands as being in the possession of the family of McQuillan, which is almost undoubtedly a corruption of the Irish MacUghlin (son of little Hugh) derived from a Hugh de Mandeville. It is probable that the de Mandevilles combined the Savage estate with their own by intermarriage, but no positive evidence is as yet forth- coming. Several mentions occur showing that in the 16th century the McQuillans lived in a crannog at Ballylough, where also a castle of apparently this period was built, the piel tower of which still remains. Early in the 17th century, some time after the expulsion of the McQuillans by the McDonnells, this property was held under the Earls of Antrim by a branch of the Stuarts 156 Annual Meeting of Ballintoy, who in turn sold it to a cadet of the old Fifeshire family of Traill of Blebo in Fife, the present owners. Colonel Traill’s grandfather conceived the idea of draining the lake by cutting a deep channel from it to the river Bush. In cutting this trench a considerable number of relics were found, including a large oak corracle, mediaeval pottery, a beautiful chain of silver filagree beads, and near the castle a number of coins of the 15th and 16th centuries. A few of these relics remain at Ballylough, but the exact site of the crannog is uncertain. The site of the old lake and its immediate surroundings are so overgrown with trees and brambles that it is difficult to get any clear view of the general contour. So far as tradition relates, the corracle and pottery were found at a spot where there is no apparent evidence of a crannog having existed, and so far as ean be seen, on what was near the edge of the lake. There is a circular entrenched group of trees known as “the decoy plantation,” which would have been surrounded by the lake, and which has, taken in con- junction with the surroundings, every appearance of a crannog, and it is most probable that it is here that the crannog site remains undisturbed. However, it is all so overgrown with trees and undergrowth that its investigation seems practically im- possible. Sir Charles Brett referred in sympathetic terms to the accident that had befallen the recently-appointed President of the Society, Mr. Henry Riddell, M.I.Mech.E., but rejoiced to say that he was rapidly returning to his normal health and vigour. He regretted that circumstances over which the Section had no control had prevented any important investigations being carried out during the year, but referred with pleasure to the increase in the membership of the Section, to within a very few of 100 members, and of the satisfactory state of the funds. He hoped that during the coming year the Archaeological Section would continue to give a good account of itself. Canon Carmody made an eloquent appeal to the meeting on behalf of the investigation and preservation of the Celtic Annual Meeting ayy) ecclesiastical remains on Mahee Island, upon the history of which the late Bishop Reeves had thrown so much light. He admitted that to carry out the work in a proper manner a considerable sum of money would be necessary, but he thought that the funds at the disposal of the Section could not be better spent. Mr. W. B. Burrowes heartily supported Canon Carmody’s appeal. He said that if more money were required than the Section could afford, he was certain that the amount could easily be raised by subscription, and on his suggestion, the question was referred to the Executive Committee for consideration. The election of office-bearers for the year was proceeded with, with the following results :— Chairman, Sir Charles Brett, LL.D. Hon. Treasurer, Mr. Henry Riddell, M.E. (President of the Soeiety). Hon. Secretary, Mr. H. C. Lawlor, M.R.LA. Executive Committee :—Sir Charles Brett, LL.D.; Mr. Henry Riddell, M.E. (ex-officio); Mr. H. C. Lawlor, M.R.LA ; Mr. Arthur Deane, M.R.LA. (ex-officio) ; Rev. Canon Carmody, M.A. ; Mr. H. R. Lepper, M.A., F.R.Hist.S. ; Mr. Thomas Edens Osborne, F.R.S.A.I.; Mr. W. B. Burrowes, F.R.S.A.I.; Mr. Fergus Greeves, Rev. William Adams, M.A.; Mr. Alec Wilson, J.P., M.R.I.A.; Mr. Godfrey Ferguson, J.P., C.E. 158 1920. 5th October. 9th November. 19th November. 26th November. 3rd December. 10th December. 14th December. 1921. 11th January. 14th January. Last of Lectures APPENDIX LIST. OF LECTURES. In Assembly Minor Hall. “Many Inventions: a Study in Natural His- tory,” by Professor J. Arthur Thomson, M.A., LL.D., F.RB.S.E. In Museum, College Square. “The Trend of Evolutionary Thought,” by Professor Gregg Wilson, O.B.E., M.A, D.Se., Ph.D., M.R.LA. In Queen’s University. ‘The Foundation Stones of Matter,” by Professor A. W. Stewart, M.A., D.Se. In Queen's Unwwersity. “The Rise of Radioactivity,” by Professor A. W. Stewart, M.A., D.Se. In Queen's Umversity. “The Transmutation of the Elements and Kindred Problems,” by Professor A. W. Stewart, M.A., D.Sc. In Queen's University. “Some Problems of Food and Power,” by Professor A. W. Stewart, M.A., D.Sc. In Museum, College Square. “The Birds of Hillsborough,” by Mr. Nevin EL-Foster, F.L:S., V.R.1.A.. MBO, In Assembly Minor Hall. “The Wonderland of the Wasps,” by Mr. John J. Ward, F.E.S. In Queen's University. “The Wanderings of the Groundsel,” by Professor James Small, D.Sc., Ph.C., F.L.S, 25th January. 28th January. 4th February. 8th February. llth and 25th February. 8th March. List of Lectures 159 In Museum, College Square. “Art and Workmanship,’ by Mr. Ivor Beaumont, A.R.C.A., M.S.A. In Queen’s University. “The Erectness of Plants,’ by Professor James Small. In Queen’s University. “The Perception of the Invisible.” by Mr. R. T. Beatty, M.A., D Se. In Museum, College Square. “The Decortication of Fibrous Plants, with special reference to Flax Retting and Scutching,’” by Mr. H. R. Carter. In Queen’s University. “The Erectness of Plants” (continued). By Professor James Small. 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