Given By

V. 5. 5UFT. OF E>OaTMENTS

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1

UNITED STATES TARIFF COMMISSION

SYNTHETIC

ORGANIC CHEMICALS

United States Production and Sales, 1964

TC Publication 167

Boston Public Library

■superintendent of Docl'.p .-ifs

FEB 1

RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON SYNTHETIC

ORGANIC CHEMICALS

*Synthetic Organic Chemicals, United States Production and Sales, 1959 (Rept. No. 206, 2d ser.,

1960) *Synthetic Organic Chemicals, United States Production and Sales, 1960 (TC Publication 34, 1961) Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 1962),

$1.25 Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114, 1963),

$1.50 Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143, 1964), $1.50

NOTE. ^The reports preceded by an asterisk (*) are out of print. The other reports listed may be purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20402. Seeinside back cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in the official depository libraries throughout the United States.

UNITED STATES TARIFF COMMISSION

SYNTHETIC ORGANIC CHEMICALS

United States Production and Sales, 1964

UNDER THE PROVISIONS OF SECTION 332 OF THE TARIFF ACT OF 1930, AS AMENDED

U.S. GOVERNMENT PRINTING OFFICE WASHINGTON : 1965

TC Publication 167

UNITED STATES TARIFF COMMISSION

Joseph E. Talbot Glenn W. Sutton James W. Culliton Dan H. Fenn, Jr. Penelope H. Thunberg

Donn N. Bent, Secretary

Address all communications

UNITED STATES TARIFF COMMISSION

Washington, D.C. 20436

For sale by the Superintendent of Documents, Government Printing Office Washington, D.C, 20402 - Price $1.25

CONTENTS

Page

Introduction- Summary

PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS

Tars 1

Tar crudes 1

Crude products from petroleunn and natural gas for chemical conversion 4

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS

General '

Cyclic§ intermediates 10

Dyes 14

Pigments 26

Medicinal chemicals 31

Flavor and perfume materials 36

Plastics and resin materials 38

Rubber -processing chemicals 42

Elastomers (synthetic rubbers) 43

Plastic izers 44

Surface -active agents 46

Pesticides and other organic agricultural chemicals 52

Miscellaneous chemicals 53

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF MANUFACTURERS

Tar crudes 61

Crude products from petroleum and natural gas for chemical conversion 62

Cyclic intermediates 64

Dyes 91

Pigments 116

Medicinal chemicals 120

Flavor and perfume materials 138

Plastics and resin materials 144

Rubber -processing chemicals 148

Elastomers (synthetic rubbers) 152

Plasticizers 153

Surface -active agents 156

Pesticides and other organic agricultural chemicals 172

Miscellaneous chemicals 178

Directory of manufacturers 207

APPENDIXES

A. U.S. imports of benzenoid intermediates and finished benzenoid products 227

B. List of Colour Index and common names for synthetic organic pigments (toners and lakes) 229

C. Employment in the synthetic organic chemicals industry, 1964 (original manufacturers

only) - --- 230

Introduction

This is the forty-eighth annual report of the U.S. Tariff Commission on domestic production and sales of synthetic organic chemicals and the raw materials from which they are made. The report presents statistics for 1964 on production and sales of crude organic chemicals derived from coal, natural gas, and petroleum; of intermediates; and of finished synthetic organic chemi- cal products. The finished products are grouped according to their principal use- -dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin ma- terials, rubber-processing chemicals, elastomers, plasticizers, surface-active agents, pesti- cides and other organic agricultural chemicals, and miscellaneous chemicals. The use classifi- cations of finished synthetic organic chemicals are based principally on the nnanufacturers ' annual reports to the Tariff Commission; other sources include trade associations, the chemical litera- ture, chemical dictionaries, encyclopedias, and consultants in the chemical industry. With a few exceptions, the report does not cover organic chemicals (such as wood-distillation products, essential oils, and naval stores) that are derived from natural (vegetable) sources by simple extraction or distillation. The Commission has compiled the statistics given in this report from information supplied by the 800 primary manufacturers listed in part III.

The first section of the report includes the statistics on all products and groups of products which conform to the general rules of publishability. The second section lists all the chemicals and chenaical products on which data are reported and identifies the manufacturers of each. Each reporting company has been assigned an identification symbol consisting of a combination of not more than three capital letters, selected in most instances with the approval of the manufac- turer, and usually bearing some relationship to the company name. The identification symbols are permanent and, except for such changes as may be necessary, will be used in all future re- ports in this series. Like the six immediately preceding reports, this report includes data on only those individual chemicals for which the volume of production or sales in the year covered exceeded 1, 000 pounds or for which the value of sales exceeded $1, 000.

The raw materials referred to in this report are obtained from coal, crude petroleum, natural gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. Crude organic chemicals are derived from coal by thermal decomposition, from petroleum and natural gas by catalytic cracking and by distillation or absorption, and from other natural sources by fer- mentation. Production of these crude organic chemicals is the first step in the manufacture of synthetic organic chemicals. From these crudes, intermediates are obtained by synthesis or re- fining; most of the intermediates are then converted into finished chemical products, such as medicinal chemicals, plastics and resin materials, and dyes. More than half ot the total produc- tion of intermediates is not sold directly to the ultimate consumer, but is used by the producing companies themselves in their manufacturing processes. The statistics given in this report in- clude data for all known domestic producers of the items covered and are therefore virtually complete.

In this report the statistics on production of the individual chemicals reported by manufac- turers include the total output of the companies' plants, i. e. , the quantities produced for con- sumption within the producing plants, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, therefore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to changes in inventories. As specified in the reporting instructions that the Commission sends to manufacturers, and as used in this report, production and sales (unless otherwise specifically indicated) are defined as follows:

Production is the total quantity of a commodity made available by original manufacture only. It is the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of the quantities of a commodity- -

(1) Produced, separated, and consumed in the same plant or establishment (a connmodity

is considered to be separated when it is isolated from the reaction system and/or when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts not classified as waste materials are also included;

(2) Produced and transferred to other plants or establishments of the same firm;

(3) Produced and sold to other firms (including production for others under toll agree-

ments-'-); and

(4) Produced and held in stock.

A toll agreement is an agreement between two firms, under which one firm furnishes the raw materials and pays the processing costs and the other firm prepares the finished product and returns it to the first firm.

vi INTRODUCTION

Production excludes--

(1) Purification of a commodity unless specifically requested in the reporting instructions;

(2) Intermediate products that are formed in the manufacturing process but are not iso-

lated from the reaction system--that is, not weighed, analyzed, or otherwise measured; and

(3) Materials that are used in the process but are recovered for reuse or sale; and waste

products that have no economic significance.

Sales are defined as actual sales of commodities by original manuiactwreTS only. Sales include--

(1) Shipments of commodities for donnestic use and for export, or segregation in a ware-

house when title has passed to the purchaser in a bonafide sale;

(2) Shipments of a commodity produced 6y oiAers under toll agreements; and

(3) Shipments to subsidiary or affiliated companies.

Sales exclude--

(1) All intracompany transfers within a corporate entity;

(2) All sales of purchased commodities; and

(3) All shipments of a commodity produced for others under toll agreements.

The value of a sale is the net selling price, f. o. b. plant or warehouse, or delivered value, whichever represents the normal industry practice.

Data on the chenaicals covered in this report are usually given in terms of undiluted mate- rials. Products of 95 percent or more purity are considered to be 100 percent pure. The principal exceptions ai;e the statistics on dyes and a few solvents, which are reported in terms of commer- cial concentrations; the statistics on certain plastics and resins, which are reported on a dry basis; and the data on sales of antibiotics, which are reported on the basis of specific conditions mentioned in the section on medicinal chemicals. The report specifically notes those products for which the statistics are reported in terms of commercial concentrations.

The average unit values of sales for groups of products shown in the tables accompanying this report are weighted averages for products which vary widely in unit values and in the quan- tities sold.

In this report, statistics are presented in as great detail as is possible without revealing the operations of individual producers. Statistics for an individual chemical or group of chemicals are not given unless there are three or more producers no one or two of which may be predomi- nant. Moreover, even when there are three or more producers, statistics are not given if there is any possibility that their publication would violate the statutory provisions relating to unlaw- ful disclosure of information accepted in confidence by the Commission. 2

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bituminous Coal, U.S. Bureau of Mines, by coke-oven operators.

Statistics on U. S. general imports in 1964 of benzenoid intermediates and finished benzenoid products that entered under schedule 4, parts IB and IC, of the Tariff Schedules of the United States are given in appendix A. Appendix B is a cross-reference list of the Colour Index and com- mon names of synthetic organic pigments. Appendix C presents the results of a one-time survey on employment in the synthetic organic chemical industry made at the request of the Special Representative for Trade Negotiations. Statistics are given on total employment, employnnent by States, and by product groups, in 1964.

The Glossary of Synonymous Names of Cyclic Intermediates, which appeared as appendix B in previous reports, has been deleted from this report. Information formerly included in the glossary may now be found in the more comprehensive SOCMA Handbook: Commercial Organic Chemical Names, recently published by the Chemical Abstracts Service of the American Chemical Society, or in the Colour Index (2d edition), published in 1956 by the Society of Dyers and Colourists.

2 Sec. 5, U.S.C. 139b and sec. 18, U.S.C. 1905.

Summary

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude products from petroleum and natural gas in 1964 was 135, 716 million pounds--an increase of 12. 2 percent over the output in 1963 (see table 1). Sales of these materials in 1964, which totaled 72, 668 mil- lion pounds, valued at $9, 242 million, were 13. 7 percent larger than in 1963 in terms of quantity and 8. 5 percent larger in terms of value. These figures include data on production and sales of chemicals measured at several successive steps in the manufacturing process, and therefore they necessarily contain some duplication.

In 1964, production of all synthetic organic chemicals, including cyclic intermediates and finished chemical products, totaled 78, 678 million pounds, or 11.8 percent more than the output in 1963. Production of flavor and perfume materials (91 million pounds) was 22. 8 percent larger in 1964 than in 1963; that of cyclic intermediates (14,896 million pounds) was 16.7 percent larger; that of plasticizers (951 million pounds) was 14. 0 percent larger; and that of plastics and resin materials (10, 103 million pounds) was 12. 6 percent larger.

The output of most of the other groups of synthetic organic chemicals also increased in 1964 compared with 1963. Production of synthetic organic pigments (44 million pounds) was 11.8 percent greater; that of rubber-processing chemicals (261 million pounds) was 11.5 percent greater; that of miscellaneous organic chemicals (45,681 million pounds) was 11. 0 percent greater; that of elastomers (3,421 million pounds) was 7.4 percent greater; that of surface- active agents (2, 119 million pounds) was 7. 0 percent greater; that of medicinal chemicals (144 million pounds) was 3. 5 percent greater; and that of pesticides and other organic agricultural chemicals (783 million pounds) was 2.5 percent greater. The apparent decline of 9. 6 percent in the production of dyes is the result of a change in the method of reporting data on certain dyes. Therefore, the figures on production (184 million pounds) and on the quantity of sales (178 mil- lion pounds) are not comparable with those for previous years. The value of sales of dyes ($264 million) in 1964 was 10. 2 percent higher than in 1963.

TABLE 1. Synthetic organic chemicals and their raw materials: U.S. production and sales, 1963 and 1964

Increase

or

decrease

(-), 1964

over

1963^

Quanti ty

Increase

or

decrease

(-), 1964

over

1963^

Increase or

decrease

(-), 1964

over

1963^

Grand total

Tar

Tar crudes

Crude products from petroleum and natural gas

Synthetic organic chemicals, total- Intermediates

Dyes

Synthetic organic pigments

Medicinal chemicals

Flavor and perfume materials

Plastics and resin materials

Rubber-processing chemicals

Elastomers (synthetic rubbers)

Plasticizers

Surface -active agents

Pesticides and other organic

agricultural chemicals

Miscellaneous chemicals

120,928

135,716

Million poands 63,898

Million pounds 72,668

Million dollars 8,517

9,242

6,719 8,745

35,121 70,343

7,629 9,547

39,862 78,678

13.6 9.0

11.8

2,907 5,485

18,460 37,046

3,361 6,076

20,465 42,766

15.6 10.8

32

119

7,793

34 131

619 8,458

12,768

204

39

139

74

8,968

234

3,185

835

1,981

763 41,153

14,896

184

44

144

91

10,a03

261

3,421

951

2,119

783

45, e

16.7 -9.6 11.8

3.5 22.8 12.6 11.5

7.4 14.0

7.0

2.5

11.0

5,429

187 34

114

67

7,516

177 2,836

750 1,790

651 17,495

6,470

178 35

119

80

8,727

184 2,958

905 1,900

692 20,518

19.2 -4.6 4.6 4.2 19.4 16.1 4.0 4.3 20.7 6.2

6.3 17.3

643

240

80

639

77

2,003

119

767

168

325

369 2,363

711 264

84 646

84 2,120 123 810 188 350

427 2,651

10.8 9.9

8.5

10.6 10.2 5.7 1.0 8.2 5.8 3.7 5.6 11.5

44.2 12.2

■"• Percentages calculated from figures rounded to thousands.

PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS

Tars

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars have properties intermediate between those of petroleum asphalts and coal tars. Petroleum asphalts are not usually considered to be raw materials for chemicals.

The quantity of tar produced from coal in the United States in 1964 was 763 million gallons, or 13. 6 percent more than the 672 million gallons produced in 1963. U. S. production of water- gas tar and oil-gas tar was not reported to the Commission for 1963 or 1964; production of these tars amounted to 19 million gallons in 1962, the last year for which production was reported to the Tariff Connmission.

Total consumption of tar in 1964 amounted to 747 million gallons, of which 602 million gal- lons was consumed by distillation, 128 million gallons as fuel, and 17 nnillion gallons in miscel- laneous uses.

TABLE 2.

Tar: U.S. production and consumption, 1963 and 1964

[in thousands of gallons]

PRODUCTION

Coal tar from coke-oven byproduct plants"''

CONSUMPTION Total

Tar consumed by distillation, total

Coal tar distilled or topped by coke-oven operators^

Coal tar, water-gas tar, and oil-gas tar distilled by producers and tar distillers^

Tar consumed chiefly as fuel'"'

Tar consumed otherwise than by distillation or as fuel, total

Coal tar consumed at coke-oven plants for roads and upkeep''"

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar consumed for upkeep at such refineries, and tar consumed in making gas and in special-purpose tar blends

671,876

691,509

762,918

7'i6,900

573,096

289,569 283,527 91,313 27,100

601,753

55§"

26,542

293,957 307,796 127,872 17,275

371

16,9(X

Reported to the U.S. Bureau of Mines.

Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort plants and distilled by companies operating tar -distillation plants.

Tar Crudes

Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and oil-gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, and creosote oil. Some of the products produced from coal tar are identical with those produced from petroleunn and natural gas. Data for materials derived from these latter sources are included, for the most part, in or with the statistics for materials derived from coal tar, which are shown in tables 3 and 4A.-'-

^ See also table 4B, pt. m, which lists these pio ducts alphabetically and identifies the manufactuieis.

2 SYNTHETIC ORGANIC CHEMICALS, 1964

Domestic production of industrial and specification grades of benzene reported by coke-oven operators and petroleum operators^ in 1964 amounted to 730 million gallons--12.8 percent more than the 647 million gallons reported for 1963. These statistics include data for benzene pro- duced from light oil and petroleum. Sales of benzene by coke-oven operators and petroleum operators in 1964 amounted to 464 million gallons, valued at $104 million, compared with 421 million gallons, valuea at $96 million, in 1963. In 1964 the output of toluene2 (including material produced for use in blending in aviation fuel) amounted to 495 million gaIlons--21. 9 percent more than the 406 million gallons reported for 1963. Sales of toluene in 1964 were 261 million gallons, valued at $44 million, compared with 207 million gallons, valued at $35 million, in 1963. The output of xylene^ in 1964 (including that produced for blending in motor fuels) was 343 million gallons, compared with 335 million gallons in 1963. About 98 percent of the 343 million gallons of xylene produced in 1964 was obtained from petroleum sources.

Production of crude naphthalene in 1964 (including 315 million pounds of petroleum-derived naphthalene) amounted to 740 million pounds, compared with 627 million pounds in 1963. Sales of coal-tar-derived naphthalene^ in 1964 were 234 million pounds, valued at $6 million, com- pared with 209 million pounds, valued at $7 million, in 1963. In 1964 the output of creosote oil for wood preservation was 113 million gallons (100-percent creosote basis), compared with 98 million gallons in 1963. Production of road tar in 1964 was 56 million gallons, compared with 58 million gallons in 1963.

TABLE 3 —Tar and tar crudes- Summary of U.S. production of specified products, average 1950-54,

annual 1963 and 1964

[ Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported]

Tar^

Benzene : ^

Tar distillers^

Coke-oven operators

Petroleum operators

Total

Toluene :

Tar distillers

Coke-oven operators

Petroleum operators

Total

Xylene :

Tar distillers

Coke-oven operators

Petroleum operators

Total

Naphthalene, crude:

Solidifying at less than 79° C.^

Petroleum naphthalene, all grades -

Total

Creosote oil (Dead oil)^ 1,000 gal

Unit

of

quantity

1,000 gal-

1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal-

1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal-

1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal-

1,000 Ib-- 1,000 lb 1,000 lb-

Average 1950-5A

876,070

41,389 163,356 46,635

251,380

7,497 32,981 3,725

121,203

1,373 9,028 78,188

88,589 307,537

307,537 109,946

671,876

9,098 112,427 525,889

647,414

3,204

25,794

377,205

406,203

509

6,888

327,460

334,857

338,715 288,240

626,955

87,894

762,918

118,944 611,294

730,238

25,521 469,519

495,040

7,119 336,079

343,198

425,690 314,664

740,354 102,114

Increase, or decrease (-)

1964 over 1950-54

-27.2 1,210.8

-22.6 481.6

-21.2 329.8

287.4 38.4

140.7 -7.1

1964 over 1963

-1.1 24.5 21.9

3.4 2.6 2.5

25.7 9.2

18.1

^ Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1950-54 only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines.

2 Includes data for motor-grade benzene in 1950-54. Production in 1964 by coke-oven operators was 864 thousand gallons, with sales of 864 thousand gallons, valued at 197 thousand dollars.

^ Includes data for benzene produced from imported crude light oil.

'• Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly figures, which included some o-xylene now shown in table 7A.

5 Figures include production by tar distillers and coke-oven operators and represent combined data for the com- mercial grades of naphthalene to avoid disclosure of the operations of individual companies. Because of conversion between grades, the figures may include some duplication.

^ Includes data for creosote oil produced by tar distillers and coke-oven operators and used only m wood preserv- ing. Data for production of creosote oil in coal-tar solution have been excluded because the figures for 1950-54 are not comparable with the figures for 1963 and 1964. Production figures for 1950-54 are for the distillate sold or consumed as such; and, for 1963 and 1964, the production of the distillate is on a 100-percent-oreosote basis.

2 Statistics on production and sales of benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal the operations of individual companies,

3 For sales of petroleum-derived naphthalene, see table 5A,

TAR CRUDES

TABLE 4A. Tar crudes.- U.S. production and sales, 1964

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table "iB in pt. Ill lists separately all products for which data on production or sales were reported and iden- tifies the manufacturers reporting to the U.S. Tariff Commission]

Sales

Quantity

Unit value-"-

Crude light oil: Coke-oven operators

Intermediate light oil: Coke-oven operators

Light-oil distillates:

Benzene, specification and industrial grades, total^

Coke-oven operators

Petroleum operators

Toluene, all grades, total^ ^

Coke-oven operators

Petroleimi operators

Xylene, total^ 3

Coke-oven operators

Petroleum operators

Solvent naphtha: Coke-oven operators^

Other light-oil distillates, total

Tar distillers

Coke-oven operators*

Pyridine crude bases (dry basis)

Naphthalene, crude (tar distillers and coke-oven

operators), total'

Solidifying at

Less than 74° C

74° C. to less than 79° C

Crude tar-acid oils:

Tar distillers

Coke-oven operators

Creosote oil (Dead oil) (tar distillers and coke-oven

operators) (100^ creosote basis), total^

Distillate as such (100^ creosote basis)

Creosote content of coal-tar solution (100^

creosote basis)

All other distillate products^

Tar, road

Tar (crude and refined) for other uses'

Pitch of tar:

Hard (water softening point above 160° F. )

Other^°

1,000 gal- 1,000 gal-

1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal- 1,000 gal-

1,000 Ib-

1,000 Ib- 1,000 Ib-

1,000 gal- 1,000 gal-

1,000 gal— 1,000 gal—

1,000 gal—

1,000 gal— 1,000 gal— 1,000 gal—

1,000 tons- 1,000 tons-

248,669 5,392

730,238

118,944

611,294

495,040

25,521

469,519

343,198

7,119

336,079

4,484

9,101

464

425,690

53,702 2,185

464,032

119,070

344,962

260,796

25,530

235,266

153,927

7,135

146,792

4,193

8,721

3,004

5,717

234,362

1,000 dollars 6,709 224

104,182

25,263

78,919

43,524

4,729

38,795

28,455

1,617

26,838

839

1,002

378

624

6,237

78, 179 347,511

328 24,893

113,272

70,804 163,558

317 24,145

98,007

102,114 11,158

55,696 19,968

87,310

10,697

14, 617 54,879 18,950

701 418

1,350 4,887

139 3,749

21,014

17,701

' 3,313

2,550 7,549 3,743

27,600 16,085

.20

■' .31

.17 .14 .20

39.37 38.48

■'- Unit value per gallon, pound, or ton, as specified.

^ Data reported by tar distillers are not included because publication would disclose the operations of individual companies. Production of benzene, toluene, and solvent naphtha by tar distillers decreased in 1964, compared with 1963; production of xylene increased. The annual production statistics for petroleum operators on benzene, toluene, and xylene are not comparable with the combined monthly production figures, due to fiscal year revisions.

^ Includes data for material produced for use in blending motor fuels.

* Production reported by coke-oven operators Includes 864 thousand gallons of motor-grade benzene, sales of which were 864 thousand gallons, valued at 197 thousand dollars.

' Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naph-tha- lene from one grade to another, the figures may include some duplication.

* Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1964, production of creosote in coal-tar solution (1005^ solution basis) amounted to 19,291 thousand gallons; sales were 17,444 thousand gallons, valued at 3,313 thousand dollars, with a unit value of $0.19 per gallon.

' Includes value of coal tar used in preparing creosote in coal-tar solution.

* Includes data for crude cresylic acid, dry distilled tar acid, and neutral oils produced by tar distillers, and for crude sodium phenolate produced by coke-oven operators.

' Includes data for tar used for paint, pipe covering, satiiratlng, and other uses. ■^° Includes soft and medium pitch of tar (water softening points less than 110° F. , and 110° F. to 160° F. ASIM D61-24), pitch of tar coke, and pitch emulsion.

Note. Statistics for materials produced in coke and gas-retort ovens are compiled by -the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum re- fineries are compiled by the U.S. Tariff Commission.

4 SYNTHETIC ORGANIC CHEMICALS, 1964

Some of the products included in the statistics in table 4A are derived from other products for which data are also included in the table. The statistics, therefore, involve considerable duplication, and for this reason no group totals or grand totals are given. After duplication has been eliminated insofar as possible, it is estimated that the net value of the output of these products and of tar burned as fuel was $460 million in 1964, compared with $406 million in 1963 and $423 million in 1962.

Crude Products from Petroleum and Natural Gas for Chemical Conversion

Crude products that are derived from petroleum and natural gas are related to the interme- diates and finished products made from such crudes in much the same way that crude products derived from the distillation of coal tar are related to their intermediates and finished products. Many of the crude products derived from petroleum are identical with those derived from coal tar (e. g. , benzene, toluene, and xylene). Considerable duplication exists in the statistics on the production and sales of petroleum crudes because some of these crude chemicals are con- verted to other crude products derived from petroleum and because data on some production and sales are reported at successive stages in the conversion processes (see table 5A*). Notwith- standing these duplications, the statistics are sufficiently accurate to indicate trends in the in- dustry and to serve as a basis for general comparison. Many of the crude products for which data are included in the statistics may be used either as fuel or as basic materials from which to derive other chemicals, depending on prevailing economic conditions. In this report, every effort has been made to exclude data on materials that are used as fuel. However, data are included on toluene and xylene which are not used directly as fuel but in blending aviation and motor- grade gasolines.

TABLE 5A.-- Crude products from petroleum and natural gas for chemical conversion: U.S. production

and sales, 1964

[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from petroleum and natxiral gas for chemical conversion for which data on production or sales were reported and iden- tifies the manufacturer of each]

Production

Sales

Qiiantity

Value Unit value^

Grand total

AROMATICS AND NAPHTHENES^ Total

Alkyl aromaticE, distillates, and solvents

Benzene (1° and 2°), total- Benzene,

Benzene,

1,000

pounds

39,862,500

1,000

pounds

20,465,279

1.000 dollars 618,971

Per pound

$0,030

12,574,423

7,578,662

180,150

1,658,622 4,511,350

1,935,826 2,545,820

22,155 78,919

.011 .031

Cresylic acid, crude

Naphthalene, all grades-

Naphthenic acids, total- Acid No. 150-199

All other

3,616,761 894,589

37,655 314,664

30,482

235,419 14,625

9,961 1,412

5,399 25,083

4,122 10, 503

Toluene, all grades, total- Nitration grade,

Pure commercial grade, All other^

Xylenes, mixed, total -

-

All other^

2,290,312 163,401 959,691

2,423,129

All other aromatlcs and naphthenes*- See footnotes at end of table.

364,797 2,058,332

185,117

1,377,294

333,089

1,058,371

415 997

38,795

31,976

6,819

26,838

237,310 821,061

78,218

6,617 20,221

2,070

.097 .101 .095

.023 .023

.025 .028 .025

4 See also table 5B, p. III, which lists these products alphabetically and identifies the manufacturers.

CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS

TABLE 5A.

-Crude products prom petroleum and natural gas for chemical conversion: U.S. production and sales, i 964 --Continued

Quantity

Unit value -^

ALIPHATIC HyDROCARBONS

Total-

C2 hydrocarbons, total

Acetylene'

Ethane

Ethylene

C3 hydrocarbons J total

Propane

Propylene

C^ hydrocarbons, total

1,3-Butadiene, grade for rubbers (elastomers)

Butadiene and butylene fractions

n-Butane

1-Butene and 2-butene mixture^

Isobutane

Isobutylene

All other''

C5 hydrocarbons, total

Isoprene (2-lfethyl-3-butadiene)

All other^

All other aliphatic hydrocarbons and derivatives, total-

Diisobutylene (Diisobutene)

n-Heptane

Heptenes, ■mixed

Hexane

Nonene ( Tripropylene)

Polybutene'

Tetrapropylene

Ifydrocarbon derivatives •'-°

All other^^

1,000

pounds

27,288,077

10,2^8,95^

437,190 1,170,562 8,641,202

7,227,166

3,656,661 3,570,505

6,671,545

2,491,C

305,092 1,700,843 1,175,713 552,766 220,467 225,578

477,941

81,423

396,518

2,662,471

21,474

66,395

254,143

130,192

161,544

124,954

432,839

29,262

1,441,668

1,000

pounds

12,886,617

2,795,106

34,198 383,540 2,377,368

4,085,337

2,624,874 1,460,463

4,164,309

1,508,684 68,961 927,488

1,039,428 328,306 130,134 161,308

79,847

1,762,018 22,113

140,561

143,166

343,891

17,109

1,095,178

1,000 dollars 438,821

3,475

3,172

110,792

56,548

24,548 32,000

214,454

157,260 1,571 10,737 31,140 4,204 5,898 3,64^

3,360

47,020

1,386

5,328

4,292

9,479 5,821 20,714

pound

$0,034

.102 .008 .047

.014 .009 .022

.051 .104 .023 .012 .030 .013 .045 .022

.063

.038

.030

.028 .340 .019

^ Calculated from rounded figures.

^ The chemical raw materials designated as aromatios are in some cases identical with those obtained from the dis- tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes."

^ Includes toluene and xylene used as solvents, as well as that which is blended In aviation and motor gasolines.

* Includes data for 90-percent benzene, sodium cresylate, sodium oarbolate and phenate, and miscellaneous cyclic hydrocarbons .

' Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U.S. Bureau of the Census.

* The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- factured.

"^ Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins.

^ Includes data for pentanes, pentenes, and C5 hydrocarbon mixtures.

' Includes compounds having a molecular weight of 3,000 or less. Includes data for di-tert-butyldisulfide and miscellaneous mercaptans.

■'■•'■ Includes data for alpha olefins, methane, propane -propylene mixture, octanes, 1-dodecene, eicosane, and hydro- carbon mixtures.

The output of crude products derived from petroleum and natural gas as a group amounted to 39, 862 million pounds in 1964, or 13. 5 percent more than the 35, 121 million pounds reported for 1963. The larger output in 1964 is accounted for chiefly by increased production of benzene, toluene, ethylene, and propylene. Sales of crude chemicals from petroleum in 1964 were 20,465 million pounds, valued at $619 million, compared with 18, 460 million pounds, valued at $573 million, in 1963.

The output of all aromatic and naphthenic products amounted to 12, 574 million pounds in 1964, compared with 11,292 million pounds in 1963. Sales in 1964, which amounted to 7, 579 million pounds, valued at $180 million, were 733 million pounds larger, and valued at $16 mil- lion more, than those in 1963. Naphthalene was produced from petroleum sources in substan- tially greater quantities in 1964 than in 1963. The output of and benzene from petroleum amounted to 4, 511 million pounds in 1964- -16. 2 percent more than the 3, 881 million pounds produced in 1963. The output of toluene in 1964 was 3,413 million pounds--24. 5 percent more

^ SYNTHETIC ORGANIC CHEMICALS, )964

than the 2, 742 million pounds produced in 1963. Production of xylene was 2,423 million pounds in 1964, compared with 2, 361 million pounds in 1963. These figures include toluene and xylene used in blends in aviation and motor- grade gasolines. The output of naphthenic acids amounted to 30 million pounds in 1964, comipared with 25 million pounds produced in 1963. Production of cresylic acid in 1964--38 million pounds--was 19. 8 percent more than in 1963.

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 27,288 million pounds in 1964, compared with 23,829 million pounds in 1963. Sales of these prod- ucts were 12, 887 million pounds, valued at $439 million, in 1964, compared with 11, 614 million pounds, valued at $410 million, in 1963. The statistics on production of acetylene (table 5A) in- clude only acetylene produced from natural gas and used as a raw material in the production of other chemical. Total production of acetylene for chemical synthesis is reported to the U.S. Bureau of the Census. In 1964, production of acetylene from all sources except that produced by railroad shops, shipyards, and small establishments using portable generators, amounted to 1,051 million pounds . Production of ethylene was 8, 641 million pounds in 1964, or 14.9 percent more than the 7, 518 nnillion pounds produced in 1963. The output of propane and propylene was 7, 227 million pounds in 1964-- 25. 6 percent more than the 5, 756 million pounds produced in 1963. Production of 1 , 3-butadiene, one of the principal ingredients of S-type synthetic rubber, was 2,491 million pounds in 1964, compared with 2, 324 million pounds in 1963. The output of 1 , 3-butadiene in 1 964-- 7. 2 percent more than that in 196 3 --was the largest on record.

The following tabulation shows the number of companies that reported production of organic

chemical crudes in 1964: ,, ,

number

of Chemical group companies

Tar crudes 14

Petroleum crudes 74

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS

General

On the basis of their principal uses, the synthetic organic chemicals covered in this report are classified either as intermediates or as finished products. Finished products, in turn, are grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic rubbers), plasticizers, surface-active agents, pesticides and other organic agricultural chemi- cals and miscellaneous synthetic organic chemicals. Most of these groups are further subdi- vided according to chemical classes, into cyclic and acyclic compounds. As most of the inter- mediates are used in the manufacture of finished products, aggregate figures that cover both intermediates and finished products necessarily include considerable duplication.

Total production of synthetic organic chemicals (intermediates and finished products com- bined) in 1964 was 78, 678 million pounds, or 11.8 percent more than the output of 70, 343 million pounds reported for 1963 (see table 6). Sales of synthetic organic chemicals in 1964 amounted to 42 766 million pounds, valued at $8, 458 million, compared with 37, 046 million pounds, valued at $7 793 million, in 1963. Production of all cyclic products (intermediates and finished products combined) in 1964 totaled 25, 506 million pounds, or 13.4 percent more than the 22, 490 million pounds produced in 1963. The output of acyclic organic chemicals in 1964 amounted to 53, 172 million pounds-- 11. 1 percent more than the 47, 853 million pounds reported for 1963.

TABLE 6. Synthetic organic chemicals; Summary of U.S. production and sales of intermediates and finished products, average 1957-59, annual 1963 and 1964

[ Production and sales in thousands of pounds; sales value in thousands of dollars ]

Average 1957-59

Increase, or decrease (-)

1964 over 1957-59

1964 over 1963

Organic chemicals, cyclic and acyclic, grand total:

Production .

Sales

Sales value

Cyclic, total:

Production

Sales

Sales value

Acyclic, total:

Production

Sales r

Sales value

I. Intermediates, Cyclic

Production

Sales

Sales value

2. Dyes, Cyclic

Production

Sales

Sales value

3. Synthetic Organic Pigments, Cyclic

Production

Sales

Sales value

45,598,853

23,744,812

5,743,764

14,381,651 8,829,037 2,785,100

31,217,202 14,915,775 2,958,664

7,343,167

2,919,264

481,920

150,830 141,731 182,513

38,603 30,218 58,648

70,343,302

37,046,363

7,793,226

22,490,017 13,477,603 3,631,620

47,853,285 23,568,760 4,161,606

12,768,168

5,428,713

642,884

204,046 186,951 239,676

39,399 33,534 79,600

78,677,699

42,766,420

8,457,909

25,505,853 15,241,685 3,890,571

53,171,846 27,524,735 4,567,338

14,895,573

6,470,072

711,119

184,387 178,273 264,023

44,053 35,081 84,131

80.1 47.2

77.3 72.6 39.7

70.3 84.5 54.4

102.8 121.6 47.6

22.2 25.8 44.6

14.1 16.1 43.4

11.8 15.4

13.4 13.1

11.1 16.8 9.7

16.7 19.2 10.6

-9.6 -4.6 10.2

11.8 4.6 5.7

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 6.— Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished products, average 1957-59, annual 1963 and 1964 --Continued

[Production and sales in thousands of pounds; sales value in thousands of dollars]

^. Medicinal Chemicals

Cyclic:

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

5. Flavor and Perfume Maten

Cyclic :

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

6. Plastics and Resin Mater

Cyclic :

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

7. Rubber -Processing Chemic

Cyclic:

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

(Synthetic Rubbers)

Cyclic:

Production--

Sales

Sales value- Acyclic :

Production

Sales

Sales value-

Cyclic:

Production

Sales

Sales value -

Acyclic:

Production

Sales

Sales value-

Average 1957-59

70,654

54,151

535,297

31,592 28,738 35,660

27,312 22,446 33,903

19,033 19,958 21,912

2,278,862

1,900,032

518,501

2,628,779

2,438,853

864,523

159,182 115,704 74,479

29,150 22,127 14,289

1,938,732

1,726,757

404,897

521,811 509,262 199,627

348,210

297,423

83,509

118,118 100, 984 38,772

94,125 73,606 605,080

45,071 40,314 33,875

41,338 34,671 51,446

32,430 32,343 25,940

3,489,361

2,886,387

736,760

5,479,112 4,629,750 1,266,359

199,282 152,835 101,757

34,350 24,367 16,906

2,174,183

1,925,751

434,474

1,010,731 910,544 332,457

621,687 557,979 103,000

212,837 191,771 65,181

97,579

76,946

612,233

46,511 41,732 33,459

49,563 41,235 56,571

41,007 38,802 27, 163

3,915,046

3,256,105

777,342

6,188,018 5,470,616 1,342,942

222,461 161,660 108,656

38,095 22,567 14,371

2,332,436

1,961,181

450,913

1,088,782 996,403 358,989

717,624 689,647 119,565

233,784

215,240

67,903

Increase, or decrease (-)

1964 over 1957-59

81.5 83.7 66.9

115.4 94.4

71.8 71.4 49.9

135.4 125.3

39.8 39.7

20.3 13.6 11.4

108.6 95.6 79.8

31.9 43.2

97.9 113.1 75.1

GENERAL

TABLE 6. Synthetic organic chemicals : Summary of U.S. production and sales of intermediates and finished

products, average 1957-59, annual 1963 and 1964 --Continued

[Production and sales in thousands of pounds; sales value in thousands of dollars]

Average 1957-59

Increase, or decrease (-)

1964. over 1957-59

1964 over 1963

10. Surface-Active Agent!

Cyclic :

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

11. Pesticides and Other Organic Agricultural Chemicc Cyclic:

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

11. Miscellaneous Chemicals

Cyclic:

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

852,314 800,432 127,936

502,715 432,135 113,215

440,384 375,627 150,837

105,080 91,938 49,049

733,401 445,252 132,660

27,260,924

11,271,780

1,621,617

1,308,791

1,222,238

159,963

671, 867 567,445 165,011

597,072 498,082 286,045

166,405 153,389 83,095

952,565 476,856 190, 935

40,200,482 17,018,837 2,172,782

1,347,809

1,245,176

165,132

770, 879 654,754 185,010

584,698 522,691 316,556

198,051 169,664 110,555

1,114,624 603,618 224,330

44,566,719 19,914,957 2,426,946

51.5 63.4

32.8 39.2 109.9

84.5 125.4

3.0 1.9 3.2

4.9 10.7

19.0 10.6

10.9 17.0 11.7

The following tabulation shows, by chemical groups, the number of companies that reported production in 1964 of one or more of the chemicals included in the groups listed in table 6:

number Chemical group of

companies

Intermediates 203

Dyes . 51

Synthetic organic pigments 39

Medicinal chemicals 114

Flavor and perfume materials 53

Plastics and resin materials 337

Numbe r Chemical group of

companies Rubber-processing chemicals 33

Elastomers (synthetic rubbers) . 30

Plasticlzers 61

Surface-active agents 182

Pesticides and other organic agricultural chemicals 86

Miscellaneous chemicals 325

10

SYNTHETIC ORGANIC CHEMICALS, 1964

Cyclic Intermediates

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic chennicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold as end products without further processing. For example, refined naphthalene may be used as a raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it may be packaged and sold as a moth repellent or as a deodorant. In general, the way in which the greater part of the output of a given chemical is consumed determiines its use classification in this report. Table TA"*" gives statistics on production and sales of cyclic intermediates in 1964. Individual statistics given in the table represent more than 85 percent of the total quantity of intermediates produced. Since many of the intermediates included in the statistics represent successive steps in production, the totals necessarily include considerable duplication. In 1964 about two-fifths of the total output of cyclic intermediates ^vas sold; the rest was consumed chiefly by the producing plants in the manufacture of more advanced intermediates and finished products.

Total production of cyclic intermediates in 1964--14, 896 million pounds--was the largest on record, and was 16.7 percent larger than the output of 12, 768 million pounds reported for 1963. The larger output of cyclic intermediates in 1964 was attributable to increased demand by a number of industries that consume large quantities of intermediates, particularly those indus- tries that produce dyes, plastics and resin materials, and plasticizers. Sales of cyclic interme- diates in 1964 amounted to 6,470 million pounds, valued at $711 million, compared with 5,429 million pounds, valued at $643 million, in 1963. In terms of quantity, sales of cyclic interme- diates in 1964 were 19.2 percent larger than those in 1963 and in terms of value, 10. 6 percent larger.

TABLE 7A. Cyclic intermediates : U.S. production and sales, 1964

[Listed telow are all cyclic intermediates for which any reported data on production or sales may be published.

( Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 7B in pt. Ill lists alphabetically all cyclic Intermediates for which data on production or sales were reported and identifies the manufacturer of each]

Production

Quantity

Unit value"""

Total

Acetanilide, tech

4-'-Aminoacetanilide ( Acetyl -p-phenylenediamlne)

5-Amlno-2-(p-aminoanillno)benzenesulfonlc acid

2-(p-Amlnoanilino) -5-nitrobenzenesulf onic acid

1-Aminoanthraquinone and salt

2 -Aminoanthraquinone and salt

S-Amino-SjV -azodi(benzenesulfonic acid)

1-Amino-A-benzamidoanthraquinone

l-Amino-5-benzamidoanthraquinone

6-(p-Aminobenzamldo) -l-naphthol-3 -sulfonic acid

2-Amlno-p-benzenedlsulfonic acid [ S03H=1]

l-Amino-4-bromo-2-anthraquinonesulfonio acid and sodium salt-

l-Amino-2-bromo-4--hydroxyanthraquinone

l-Amino-5-chloroanthraqulnone

2-Amlno-3-chloroanthraquinone

o-( 3 -Amino -4 -chlorobenzoyl) benzoic acid

6-Amlno-4—chloro-l-phenol-2 -sulfonic acid

6-Amino-4— chloro-m-toluenesulfonlo acid [S03H=l]

See footnotes at end of table.

1,000

pounds

l^i, 895,573

1,000

pounds

6,470,072

1,000 dollars 711,119

Per pound

3,905

'i75

15

33

1,152

965

60

75

104

38

21

253

113

86

48

106

1,305 164

341 255

.26

1.55

See also table 7B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and appendix A, wlucn snows imports of intermediates and related products during 1963 and 1964.

CYCLIC INTERMEDIATES

TABLE lA.— Cyclic intermediates.- U.S. production and sales , 2564— Continued

Production

Quantity

Unit value-'-

2-Amno-5-ohloro-p-toluenesulfQnio acid [S03H=1]

l-Amino-2,'i-dibromoanthraquinone

4.'-Amino-N-methylacetanilide

2-Ajiiino-l,5-naphthalenedisulfoniG acid

3-Ajnino-l,5-naphthalenedisulfonic acid (Cassella acid)

6-Ainino-l,3-naphthalenedisulfonio acid (Amino I acid)

2-Aiiiino-l-naphthalenesulfonic acid (Tobias acid)

5-Amino-2-naphthalenesuli'onic acid (1,6-Cleve's acid)

5(and 8) -Ainino-2-naphthalenesulfonio acid (Cleve's acid, mixed)--

6-Amino-2-naphthalenesuli'onic acid (Broenner's acid)

8-Ajiiino-l-naphthalenesulfonic acid (Peri acid)

8-Amino-2-naphthalenesulfonic acid (l,7-Cleve's acid)

8-Amino-2-naphthol

8-Amino-l-naphthol-3,6-disulfonio acid (H acid), monosodium salt-

l-Amino-2-naphthol-<4-sulfonic acid (1,2,'i-acid)

6-Amino-l-naphthol-3-sulfonic acid (J acid), sodium salt

7-Amino-l-naphthol-3-sulfonic acid (Gamma acid), sodium salt

2-Amino-5-nitrobenzenesulfonic acid rS03H=l]

2 -Aminos -nitrophenol

2 -Amino-l-phenol-4 -sulfonamide

2 -Amino-1-phenol-^ -sulfonic acid

p-(p-Aminophenylazo)ben2,enesulfonlc acid

4-Amino-m-toluenesulfom.o acid [S03H=1]

5-Amino-m-tQluenesulfonic acid rS03H=l]

16-Aminoviolanthrone

2-Amlno-3,5-xylenesulfonic acid [S03H=1]

Aniline (Aniline oil)

Anilinomethanesulfonio acid and salt

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)

6-Anilino-l-naphthol-3-sulfonic acid (Phenyl J acid)

o-Anisidine

o-Anisidinomethanesulfonic acid

Anthra[l,9]pyrazol-6(2H)-one (Pyrazoleant'hrone)

Anthraquinone , 100^

1,5-Anthraquinonedisulfonic acid

IjS-Anthraquinonedisulfonic acid, potassium salt

2,6-Anthraquinonedisulfonic acid and salt

1-Anthraquinonesulfonic acid and salt

Anthraruf in (l,5-Dihydroxyanthraquinone)

Benzaldehyde, tech

l-Benzamido-5-chloroanthraqulnone

7H-Benz[de ]anthracen-7-one^ (Benzanthrone)

Benzidine hydrochloride and sulfate

Benzoic acid, tech

o-Benzoylbenzoic acid

3,3'-Bianthra[l,9]pyrazole-6,6'-(2H,2'H)dione ( Pyrazoleanthrone

yellow)

[■4j4'-Bi-7H-benz[de]anthracen]-7,7'-dione

[ ljl'-Binaphthalene]-8,8'-dicarboxylic acid

l,4-Bis[l-anthraquinonylamino] anthraquinone 7-

"+,4' -Bis [dimethylaminojbenzophenone (Michler's ketone)

3-Bromo-7H-benz[de] anthracen-7-one ( Bromobenzanthrone )

o-sec-Butylphenol

Camphoric acid

1-Chloroanthraquinone

2-Chloroanthraquinone

Chlorobenzene , mono-

o-(p-Chlorobenzoyl)benzoic acid

l-Chloro-2,<4-dinitrobenzene (Dinitroohlorobenzene)

6-Chlorometanilic acid

l-Chloro-2-methylanthraquinone

2-Chloro-4.-nitroaniline (o-Chloro-p-nitroaniline)

l-Chloro-5-nitro anthraquinone

l-Chloro-8-nitro anthraquinone

l-Chloro-2-nitrobenzene (Chloro-o -nitrobenzene)

l-Chloro-3 -nitrobenzene (Chloro-m-nitrobenzene)

l-Chloro-4 -nitrobenzene (Chloro-p-nitrobenzene)

See footnotes at end of table.

1,000

pounds

1,334

245

14

85

241

1,168

4,506

149

303

90

476

224

59

3,506

1,151

596

578

36

98

62

100

205

223

280

21

69

169,909

242

364

66

1,672

372

30

2,760

261

312

271

2,691

255

3,338

109

1,987

1,369

15,864

5,786

19

145

1,093

10

197

1,010

537,500

1,633

8,193

24

215

301

103

46

20,088

8,063

86,902

i.ono

founds

1,000 dollars

pound

3,615

64

893

7,998

1,452

109

906

1,392

1.70 1.01

,238 252

.89 .07

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 7A.-- Cyclic intermediates: U.S. production and sales , i564— Continued

Qaantity Value

Unit value "^

4-Chloro-3-nltrobenzenesulfonaiiilde

"i-Chloro-S-nitrobenzenesulfonyl chloride

o-(4-Chloro-3-nitrobenzoyl) benzoic acid

'4-Chloro-2-nitrotoluene

a -Chlorotoluene (Benzyl chloride)

5-Chloro-o-toluidine [NH2=l] and hydrochloride

Cresols, total^

m-, 0-, and p-Cresols

(m,p)-Cresol (from coal tar and petroleum)

(o,m,p)-Cresol^

Cresylio acid, refined, total^

From coal tar

From petroleum

Cumene

Cyclohexane

Cyclohexanol

Cyclohexanone

l,<i-Diaminoanthraquinone

1,5-Diaminoanthraquinone

2,6-Diaminoanthraquinone

■4,4' -Diamino-2,2' -biphenyldisulfonic acid

■4,4' -Diamino-2, 2'-stilbenedisull"onic acid

4,5' -Dibenzamido-1,1' -iminodianthraquinone

1,5-Dibenzoylnaphthalene

3,9-Dibromo-7H-benz[de ]anthraoen-7-one

2,5-Dichloroaniline and hydrochloride [NH2=l]

1,8-Dichloroanthraquinone

o-Dichlorobenzene

o(and p) -Dichlorobenzene

p-Dichlorobenzene

3,3'-Dichlorobenzidine base and salts

2,5 -Dichloro^ -( 3 -methyl-5 -oxo-2 -pyrazolin-l-yl) benzenesulf onic acid

2,6-Dichloro-4-nitroaniline

l,4-Dichloro-2 -nitrobenzene (Nitro-p-diohlorobenzene)

2,5-Dichlorosulfanilio acid [S03H=l]

p-Diethylaminobenz aldehyde

N,N-Diethylanlline

l,5-Dihydroxy-4,8-dinitroanthraquinone

l,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitroohrysazin)

16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone)

3 j3^ -Dimethoxybenzidine

N,N-Dimethylaniline

N,N-Dime thy Ibenzy lamina

2, 2 '-Dime thy 1-1,1' -bianthraquinone

N,N-Dime thy 1-p-nitrosoani line

p-( 2, 4-Dinitroanilino) phenol

2,4-Dinitrophenol, tech

4,4'-Dinitro-2,2'-stilbenedisulfonio acid

Dlphenylacetic acid

l,4-Di(p-toluidino)anthraquinone

Dodecylbenzene*

Dodecylphenol

N-Ethylaniline, refined

Ethylbenzene

N-Ethyl-N-phenylbenzylamine

2-Ethyl-2-phenylraalonic acid, diethyl ester

3-(N-Ethyl-m-toluidino)propionitrlle

o-Formylbenzenesulfonic acid (o-Sulf obenzaldehyde)

p-Hydrazinobenzenesulf onic acid

p-Hydroxybenzoic acid, methyl ester

p-Hydroxybenzoic acid, propyl ester

l,l'-Iminobis[4-aminoanthraquinone]

l,l'-Iminobis[5-benzamidoanthraquinone]

6,6'-Iminobis[l-naphthol-3-sulfonic acid]

1.000 pounds 258 235 93 396 52,408 657

62,467

1,000 pounds

8,471 159

26,147 24,445 11,875

22,208 41,482

549,841 1,367,142

116

4

2,882

129

183

224

138

77

52,308

12,997

63,154

2,345

313

225

417

102

26

1,480

137

186

448

776

10,855

78

118

89

33

1,037

4,159

7

162

413,972

25,783

409

2,953,879

493

259

61

239

153

255

1,064

20 200

1,000 dollars

1,551 218

135 247 569

679 721

865 901 895

295 184

1.48 2.30

See footnotes at end of table.

CYCLIC INTERMEDIATES

TABLE 7A. Cyclic intermediates: U.S. production and sales , 1964 Continued

Quantity

Unit value ■*■

1, l'-Iininobis[4-nitroanthraquinone]

1, I'-Iminodianthraquinone (Dianthrimide)

Isooyanio acid derivatives, total

Diphenylmethane -ij^'-diisocyanate (MDI)

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture)

All other

'i,'i'-Isopropylidenediphenol (Bisphenol A)

Isoviolanthrone (Isodibenzanthrone)

Leuco-l,<4-diamnoanthraquinone

Leuco quinizarin ( 1,4,9, 10-Antliratetrol)

Leuco tetrahydroxyanthraquinone

Iifelamine

o-kfercaptotenzoio acid

1-lfethylaminoanthraquinone

<i,'i'-Methylenebis[N,N-dlethylaniline]

4,'i'-Methylenebls[N,N-dimethylaniline] (ifethane base)

2-Iifethyl-l-nitroanthraquinone

p-(3-Methyl-5-oxo-2-pyTazolln-l-yl)benzenesuli'onie acid

3-Methyl-l -phenyl -2 -pyrazolin-5-one (Developer Z)

ct-lfethylstyrene

1,5-Naphthalenedisulfonic acid

2,7-Naphthalenedisuli'onic acid

1,4,5,8-Naphthalenetetraoarboxylic acid

1-Naphthol (a-Naphthol)

2-Naphthol-3,6-disuironic acid, disodium salt

2-Naphthol-6-sulfonic acid (Sehaeffer's acid) and sodium salt

Naphth[l,2] oxadiazole-5-suLfonio acid

2-(Naphthylthio) acetic acid

p-Nitroaniline

4-Nitro-o-anisidine [ NH2=1]

5-Nitro-o-aiiisidine [nH2=1]

l-Nitro-2-anthraquinoneoarboxylic acid

5-Nitro-l-anthraquinonesulfonic acid

5(and 8) -Nitro-l-anthraquinonesulfonic acid

Nitrobenzene

m-Nitrobenzenesulfonic acid and sodium salt

m-Nitrobenzoio acid and sodlvim salt

3-Nitro-l,5-naphthalenedisulfonio acid

7(aiid 8) -Nitronaphth[ 1, 2] oxadiazole-5-sulfonic acid

p-Nitrophenol

5-Nitro-o-toluenesulfonic acid [ SO H=l]

5-Nltro-o-toluidine [NH2=l]

2-Nitro-p-toluidine [NH2=1]

16 -Nitroviolanthrone

Nonylphenol :

l-(7-0xo-7H-benz[de]anthracen-3-ylaraino)anthraquinone

1,1' -(7-0xo-7H-benz[de]anthracen-3,9-ylenedilmino)dianthraquinone- 5-0xo-l-(p-suLfophenyl) -2-pyrazoline-3-carboxylic acid

(Pyrazolone T)

Phenol, grand total^

Natural, total

From coal tar

From petroleum

Synthetic, total

From cumene

Other synthetic

l-Phenol-4 -sulfonic acid

Phenylacetic acid, potassium salt

Phenylaoetonitrlle (a -Tolunitrile)

p-Phenylazoaniline (p-Aminoazobenzene) and hydrochloride

2, 2' - ( Phenylimino )diethanol ( Phenyldiethanolamine )

l(2H)-Phthalazlnone

Phthalic anhydride

1,000 pounds

137,960

3,899 113,627 20,434

92,948 40 332

13 227

59

1,340

108

125

279

14,112

62 111

2,059 366

10,890

73

331

37

116

25

239,216

3,090

255

207

758

18,935

6,680

358

941

69

60,585

181

447

1,113,056

50,287

35,639

14,648

1,062,769

443,872

618,897

6,646

1,414

1,740

133

545

135

557,517

1,000 pounds

1,000 dollars

2,600

107,265

16,654

41,146

25,246

54

38

15

439

199

239

135 283,736

902 676 621

66 355

579

716

699 2,271

47,735

5,054

3,470

1,584

42,681

18,149

24,532

966 526 369

659 27,605

See footnotes at end of table.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE tA. --Cyclic intermediates: U.S. production and sales , 1964--Contirme(i

Production

Quantity

Unit value '■

2-Piooline (a-Pieoline) ^

Piperidine

Propiophenone

Pyranthrone

Pyridine'

CJuinaldine

Quinizarin

2-Quinizarinsulfonie acid

Salicylaldehyde

Salicylic acid, tech

Styrene, all grades

Terephthalic acid, dimethyl ester

Ij'ijSjS-Tetrachloroanthraquinone

o(and p) -Toluenesulf onic acid

o-(p-Toluoyl) benzoic acid

i-Co-Tolylazo) -o-toluidine

l,3,3-Trimethyl-A^»"-indolineacetaldehyde

l,3,3-Trimethyl-2-methyleneindoline

6,6'-Ureylenebis[ l-naphthol-3-sulfonic acid] (j acid urea)

Violanthrone (Dibenzanthrone)

o-Xylene

p-Xylene

Xylenols, medium b.p

All other cyclic intermediates

1.000 pounds

3,297

^01

587

20

5,503

33

1,411

2,156

20,769

,571,395

355,587

34

4,348

318

443

89

185

258

436

336,557

295,730

5,930

,173,805

1,000

pounds

1,042 256

74

18

2,055

3,199

1,368,179

1,000 dollars

81

39

2,249

1,095

110,845

4,306

306,049

313,019

6,058

1,165,579

8,087

26,978

656

244,919

pound

$0.36 1.18

.21

■'■ Calculated from rounded figures.

^ Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior, and for tar and petroleum refineries and other producers, reported to the U.S. Tariff Commission.

■^ Includes some mixed cresols. Figures include (o,m,p)-cresol from coal tar and from petroleum.

* Includes branched- and straight-chain dodeoylbenzene and tridecylbenzene.

' Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commission.

In 1964, production of two intermediates amounted to over 2 billion pounds each. The output of ethylbehzene totaled 2, 954 million pounds (20. 5 percent more than in 1963) and that of styrene, 2, 571 million pounds (19.4 percent more than in 1963). Ethylbenzene is used almost entirely in the manufacture of styrene, which, in turn, is used almost entirely in the manufacture of plas- tics materials and synthetic rubber. The output of other large-volume intermediates in 1964 compared with production in 1963 was as follows: Cyclohexane, 26. 7 percent larger; phenol, 18.9 percent larger; and phthalic anhydride, 21.6 percent larger. Production of cumene and monochlorobenzene was larger by 26. 9 percent and 3. 6 percent, respectively, in 1964 than in 1963. Production of dodeoylbenzene (including tridecylbenzene) in 1964 was 15. 5 percent smaller than that in 1963. The output of terephthalic acid, dim:ethyl ester amounted to 356 million pounds in 1964, representing an increase of 7.4 percent over the 331 million pounds pro- duced in 1963. Production of orthoxylene amounted to 337 million pounds in 1964, compared with 304 million pounds in 1963--representing an increase of 10. 8 percent.

Dyes

Dyes produced in the United States are all derived in whole or in part from cyclic interme- diates. About three-fourths of the dyes consumed in the United States are used by the textile industry to dye natural and synthetic fibers or fabrics; the rest are used chiefly by the industries that produce organic pignnents, paper, and leather. Of the several thousand different synthetic dyes that are known, more than two thousand are manufactured by one or more domestic pro- ducers. The large number of dyes results from the many different types of materials to which dyes are applied, the different conditions of service for which dyes are required, and the costs that a particular use can bear. Dyes are sold as pastes, powders, lumps, and solutions; concen- trations vary from 6 percent to 100 percent. The concentration, form, and purity of a dye are determined largely by the use for which it is intended.

DYES

15

Table 8A^ shows U.S. production and sales of dyes in 1964, total and by individual dyes, using the Colour Index classification and terminology (which was used for the first time in the Commission's 1958 report).

Total domestic production of dyes in 1964 amounted to 184 million pounds, while sales amounted to 178 million pounds, valued at $264 million. The value of dyes sold in 1964 was 10 percent larger than that in 1963. Statistics on the quantity of dyes produced and sold in 1964 are not comparable with those for 1963 because of a change in the method of reporting sulfur dyes. Data on production and sales of two forms of sulfur dyes, the solubilized and leuco forms, were reported in commercial concentrations in 1963; these same dyes were reported on a more con- centrated active ingredient basis in 1964.

For many important individual low- and medium-priced dyes, for which statistics are given in table 8A, production was larger in 1964 than in 1963. The output of Direct Black 38 was 6. 3 million pounds in 1964, or 5.0 percent more than the 6.0 million pounds produced in 1963; that of Vat Green 1 was 5. 9 million pounds, or 19. V percent more than the 4. 9 million pounds pro- duced in 1963. Other important dyes whose output was substantially larger in 1964 than in 1963 were Disperse Black 9 (53.8 percent). Disperse Yellow 3 (41.4 percent). Direct Blue 86 (22.5 percent), and Vat Blue 6 (10. 6 percent).

TABLE 8A. Benzenoid dyes: U.S. production and sales, 1964

[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies the manufacturer of each]

Dye

Quantity

Unit value''"

Grand total

ACID DYES

Total

Acid yellow dyes, total

Acid Yellow 3

Acid Yellow 11

Acid Yellow 17

Acid Yellow 23

Acid Yellow 36

Acid Yellow 40

Acid Yellow 4-2

Acid Yellow 44

Acid Yellow 54

Acid Yellow 73

Acid Yellow 99

All other

Acid orange dyes, total

Acid Orange 1

Acid Orange 7

Acid Orange 8

Acid Orange 10

Acid Orange 24

Acid Orange 60

Acid Orange 74

All other

Acid red dyes, total

Acid Red 1

Acid Red 4

1,000 pounds

184,387

17,794

2,766

482 385 196

219

83

1,151

2,687

38 763 354 319 479

456 143

1,000 pounds

178,273

17,090

2,481

28

53

445

280

212

82

35

22

57

59

82

1,126

2,511

684 306 319 457 32

2,600

496 147

1,000 dollars

264,023

35,812

5,556

84

109

972

592

315

223

62

71

123

136

185

2,684

3,735

121 600 355 409 610 83 100 1,457

5,281

557 266

pound

$1.48

2.10

2.24 3.00 2.06 2.18 2.11 1.49 2.72 1.77 3.23 2.16 2.31 2.26 2.38

1.49 3.10

1.16 1.28 1.33 2.59 2.22 2.32

2.03

See footnotes at end of table.

"^ See also table 8B, pt. Ill, which lists these products and identifies the manufacturers, and appendix A (table 23), which shows imports of dyes during the years 1963-64.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE QA.-- Benzenoid dyes: U.S. production and sales , 1964 Continued

E)ye

Production

aantlty Value

ACID DY£S--Continued

Acid red dyes--Continued

Acid Red lA

Acid Red 18

Acid Red 26

Acid Red 37

Acid Red 73

Acid Red 85

Acid Red 87

Acid Red 88

Acid Red 89

Acid Red 99

Acid Red 115

Acid Red 137-

Acid Red 151

Acid Red 182

Acid Red 186

All other

Acid violet dyes, total

Acid Violet 1

Acid Violet 3

Acid Violet 7

Acid Violet 12

Acid Violet 17

Acid Violet 43

All other

Acid blue dyes, total

Acid Blue 7

Acid Blue 9

Acid Blue 25

Acid Blue 40

Acid Blue 41

Acid Blue 43

Acid Blue 45

Acid Blue 78

Acid Blue 113 -

Acid Blue 158 and 158A

All other

Acid green dyes, total

Acid Green 3

Acid Green 9

Acid Green 12

Acid Green 16

Acid Green 20

Acid Green 22

Acid Green 25

All other

Acid brown dyes, total

Acid Brown 14

All other

Acid black dyes, total

Acid Black 1

Acid Black 24

Acid Black 48

Acid Black 52

Acid Black 107

All other

1,000 pounds

188 150 465 163

29 135

20 119

104 101

3,369

566 99

1,492

157 289

274 410

4,104

1,381

92

33

438

84

2,076

1,000

pounds

1,000 dollars

82 120

49

57 190 163

83 136

39

18 128 55 33

3,234

82 474 110

347

210

1,243

169 18 13

113 32 64

177

186

261 439

1,499 128 27

2,661

118 137

57 155 427 276 161 194

66

29 405 119 101

53 2,160

745

144 115

30 148

20 220

228 586 593 64 260 172

1,918 338 482 479

4,770

2,210

196 79

135 649 598

373 1,258

1,723 228 148

246 4,419

See footnotes at end of table.

DYES

TABLE 8A. —Benzenoid dyes : U.S. production and sales , i56-^— Continued

Oye

Quantity Value

AZOIC DYES AND COMPONENTS

Azoic Conipositions

Total

Azoic Yellow 1

Azoic Yellow 2

Azoic Orange 3

Azoic red dyes, total

Azoic Red 1

Azoic Red 2

Azoic Red 6

Azoic Red 16

All other

Azoic Blue 2

Azoic Blue 3

Azoic Brown 9

Azoic black dyes

All other azoic compositions

Azoic Diazo Components, Bases (Fast Color Bases)

Total

Azoic Diazo Component 4, base

Azoic Diazo Component 9, base

Azoic Diazo Component 12, base

Azoic Diazo Component 32, base

Azoic Diazo Component A-8, base

All other azoic diazo components, bases

Azoic Diazo Components, Salts (Fast Color Salts)

Total

Azoic Diazo Component 1, salt

Azoic Diazo Component 3, salt

Azoic Diazo Component 5, salt

Azoic Diazo Component 6, salt

Azoic Diazo Component 8, salt

Azoic Diazo Component 9, salt

Azoic Diazo Component 10, salt

Azoic Diazo Component 11, salt

Azoic Diazo Component 12, salt

Azoic Diazo Component 13, salt

Azoic Diazo Component 28, salt

Azoic Diazo Component 32, salt

Azoic Diazo Component 36, salt

Azoic Diazo Component 48, salt

Azoic Diazo Component 49, salt

All other azoic diazo components, salts

Azoic Coupling Components (Naphthol AS and Derivatives)

Total

Azoic Coupling Component, 2

Azoic Coupling Component 3

1.000 pounds 2,041

187 78

302

7

85

155 685 277

1,391

31

267 266

2,137

3,218

1,000 pounds 1,707

1,000 dollars

44

172 9

71

9

83

114

677

287

1,272

33 52 266 258 35 628

1,973

2,447

3,441

73 83 849

261 110 291 24 163

17

141

363

1,304

611

1,984

42

43

350

419

61

1,069

2,028

14

13

19

290

266

179

105

111

136

15

16

17

44

49

49

222

235

153

20

13

20

38

36

60

129

139

151

419

414

290

180

181

210

201

57

63

73

132

36

36

39

31

34

101

393

300

409

4,696

227 18

197 17

See footnotes at end of table.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8A.-- Benzenoid dyes.- U.S. production and sales, i 564 --Continued

Dye

Quantity Value

AZOIC DYES AND COMPONENTS— Continued

Azoic Coupling Component s (Naphthol AS and Derivatives) -ContxxwieA

Azoic Coupling Component 4

Azoic Coupling Component 7

Azoic Coupling Component 1<+

Azoic Coupling Component 17

Azoic Coupling Component 18

Azoic Coupling Component 19

Azoic Coupling Component 20

Azoic Coupling Component 21

Azoic Coupling Component 29

All other azoic coupling components

BASIC DYES

Total

Basic Yellow 2

Basic Yellow 11

Basic Yellow 13

Basic orange dyes, total

Basic Orange 1

Basic Orange 2

Basic Orange 21

All other

Basic red dyes, total

Basic Red 2

Basic Red K

All other

Basic violet dyes, total

Basic Violet 1

Basic Violet 3

Basic Violet 4-

Basic Violet 14-

Basic Violet 16

All other

Basic blue dyes, total

Basic Blue 1

Basic Blue 7

Basic Blue 9

Basic Blue 26

All other

Basic Green 1

Basic Green 4

Basic Brown 1

Basic Brown 4

All other basic dyes

DIRECT DYES

Total

Direct yellow dyes, total

Direct Yellow 4

Direct Yellow 5

Direct Yellow 6

Direct Yellow 11

1,000 pounds

1,041 148 203

744

106 79 28

624

9,154

714

332

56

1,330

294 581 367

176 317 546

2,650

914 1,056 42 116 104 418

1,201

123 403

90 489 240 605 408

31,490

5,752

414 145 783 871

7 775 103 160 658 14

8,553

768 337 49

1,141

276

482

304

79

166 313 454

2,605

865 1,120 44 81 98

397

18 106 307

85 509 219 609 314

31,939

5,548

410 123 737

15

1,415

219

313

782

67 176 139

53 1,261

20,878

1,570

1,353

172

2,116

297 580 955 284

477

941

1,731

5,277

1,112

2,034

125

290

353

1,363

3,292

82

354

716

188

1,952

273

1,334

317

808

1,217

46,807

10,021

866

351

1,202

981

See footnotes at end of table.

DYES

19

TABLE 8A. Benzenoid dyes : U.S. production and sales, 1964—Contm\ied

Dye

DIRECT DYES- -Continued

Direct yellow dyes Continued

Direct Yellow 12

Direct Yellow 26

Direct Yellow 28

Direct Yellow 29

Direct Yellow 44

Direct Yellow 50

Direct Yellow 59

Direct Yellow 84

All other

Direct orange dyes, total

Direct Orange 1

Direct Orange 8

Direct Orange 15

Direct Orange 26

Direct Orange 34

Direct Orange 37

Direct Orange 39

Direct Orange 72

Direct Orange 73

Direct Orange 81

Direct Orange 102

All other

Direct red dyes, total

Direct Red 1

Direct Red 2

Direct Red 4

Direct Red 10

Direct Red 13

Direct Red 16

Direct Red 23

Direct Red 24

Direct Red 26

Direct Red 28

Direct Red 31

Direct Red 37

Direct Red 39

Direct Red 75

Direct Red 79

Direct Red 80

Direct fled 81

Direct Red 83

Direct Red 149

Direct Red 152

All other

Direct violet dyes, total

Direct Violet 1

Direct Violet 9

Direct Violet 48

All other

Direct blue dyes, total

Direct Blue 1

Direct Blue 2

Direct Blue 6

Direct Blue 8

Direct Blue 14

Direct Blue 15

Direct Blue 22

Direct Blue 24

Sales

Production

Quantity

Value

Unit value^

1,000 pounds

368

8

262

122

401

331

45

172

1,830

1,726

1,000 pounds

292

6

279

98

378

349

50

211

1,807

1,834

1,000 dollars

700

17

551

148

646

664

75

309

3,511

4,002

Per pound

$2.40 2.83

1.97

1.51

1.71

1.90

1.50

1.46

1.94

2.18

21 143 129 47 97 56 98 248 19 49 164 655

3,291

14

135

161

62

97

60

100

285

31

36

166

687

3,400

33 204 201 127 233 145 208 598 126 110 446 1,571

7,220

2.36

1.51

1.25

2.05

2.40

2.42

2.08

2.10

4.06

3.06

2.69

2.29

2.12

175

381

30

18

69

34

265

326

130

200

36

58

61

37

197

427

291

128

14

414

253

167

402

31

19

84

56

297

346

113

177

31

67

65

33

201

444

293

105

13

5

451

194

261

709

85

32

138

104

656

640

295

235

126

172

189

111

482

812

751

165

44

25

1,188

570

1.56

1.76

2.74

1.68

1.64

1.86

2.21

1.85

2.61

1.33

4.06

2.57

2.91

3.36

2.40

1.83

2.56

1.57

3.38

5.00

2.63

2.94

16 174 34 29

7,049

15 118 30

31

7,186

33 282 118 137

10,076

2.20

2.39

3.93

4.42

1.40

417

1,828

522

55

96

41

404 1,977

523 55

123 48 20 44-

710 1,659 271 103 104 79 34 57

1 76

.84

.52

1.87

.85

1.65

1.70

1.30

See footnotes at end of table.

20

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8A. Benzenoid dyes : U.S. production and sales, 1964 Continued

Efire

Production

Quantity

DIRECT DYES— Continued

Direct blue dyes Continued

Direct Blue 25

Direct Blue 26

Direct Blue 67

Direct Blue 71

Direct Blue 76

Direct Blue 78

Direct Blue 80

Direct Blue 86

Direct Blue 98

Direct Blue 120 and 120A

Direct Blue 126

Direct Blue 151

All other

Direct green dyes, total

Direct Green 1

Direct Green 6

Direct Green 8

Direct Green 12

Direct Green 38

All other

Direct brown dyes, total

Direct Brown 1 and lA

Direct Brown 2

Direct Brown 6

Direct Brown 31

Direct Brown 74

Direct Brown 95

Direct Brown 111

Direct Brown IS^-

All other

Direct black dyes, total

Direct Black A

Direct Black 9

Direct Black 19

Direct Black 22

Direct Black 37

Direct Black 38

Direct Black 51

Direct Black 80

All other

DISPERSE DYES

Total

Disperse yellow dyes, total

Disperse Yellow 1

Disperse Yellow 3

Disperse Yellow 5

Disperse Yellow 23

Disperse Yellow 33

Disperse Yellow 37

Disperse Yellow 54

All other

Disperse orange dyes, total

Disperse Orange 3

Disperse Orange 5

Disperse Orange 17

All other

See footnotes at end of table.

1,000 pounds

33

62 622

83

431

1,186

155

91 185

1,171

1,140

230 424 48

1,910

378 157 97 116

184 230

10,369

271

52

224

690

6,338 118

1,883 793

13,132

2,126 23

234 103 207 557

1.000 pounds

1.000 dollars

606 107 448

1,182 1A7 116 158 28

1,013

1,046

159 401 37 17 11 421

1,989

426

200

81

96

52

696

37

194

207

10,742

174 678

297

61

238

648

13

6,615

113

2,005

752

11,993

60 226

98 155 506

119 511

164 9 138 223 861 302 722

1,850

271

240

391

36

1,852

2,466

200

458

48

17

40

1,703

2,569

424 295

89 270

86 543 133 248 481

334

543

17

5,155

328

1,836

1,289

28,032

4,030 50

1,438 214 167 358 198 564

1,041

1,434 168 152 145 969

DYES

TABLE SA.—Benzenoid dyes: U.S. production and sales , 1964— Continued

Dye

DISPERSE DYES- -Continued

Disperse red dyes, total

Disperse Red 1

Disperse Red 5

Disperse Red 11

Disperse Red 13

Disperse Red 17

Disperse Red 60

All other

Disperse violet dyes, total

Disperse Violet 1

All other

Disperse blue dyes, total

Disperse Blue 1

Disperse Blue 3

Disperse Blue 7

Disperse Blue 64

All other

Disperse trown dyes

Disperse black dyes, total

Disperse Black 1

Disperse Black 9

All other

FIBER-REACTIVE DYES

Fiber-reactive dyes, total

Reactive yellow dyes

Reactive blue dyes—

All other reactive dyes

FLUORESCENT BRIGHTENING AGENTS

Total

Fluorescent Brightening Agent 68

All other fluorescent brightening agents

FOOD, DRUG, AND COSMETIC COLORS

Total

Food, Drug, and Cosmetic Dyes

Total

FD&C Blue No. 1

FE&C Red No. 2 -

FDSiC Red No. 3

FDScC Red No. 4

FE&C Yellow No. 5

FSScC Yellow No. 6

All other food, drug, and cosmetic dyes

Drug and Cosmetic and External Drug and Cosmetic Dyes

Total-

DiC Red No. 7

DScC Red No. 19— -

See footnotes at end of table.

Production

1,000 pounds 1,620

211 63 64

189

59

1,034

38 331

5,056

306

1,741

252

179

2,578

131

2,863

2,122 399

1,640

Quantity

243 683 714

16,675

31 16,644

2,909

2,710

65 786

49 277 700 659 174

1,000 pounds

227 35 42 13

123 73

998

30 285

4,790

311

1,565

271

2,643

140

2,465

1,000 dollars

332

1,744

389

1,526

225 621 680

15,673

33 15,640

2,846

2,630

58 785

43 324 644 595 181

4,679

352 46 218 19 145 259 3,640

817

117 700

13,831

1,285 2,563 1,702

8,281

227

3,014

392

1,879

743

6,261

851 3,019 2,391

27,802

354 27,448

9,970

638 2,220

720 1,620 2,135 1,768

869

1,099

22

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8A. Benzenoid dyes : U.S. production and sales , 1964 Continued

Dye

Production

Quantity Value

FOOD, DRUG, AND COSMETIC COLORS- -Continued

Drug and Cos and Cosm.

c and Extei Dyes--Cont

nal Dr .nued

1,000 pounds

D«tC Red No. 21

E&C Red No. 36

All other drug and cosmetic and external drug and cosmetic dyes

MORDANT DYES

Total

Mordant yellow dyes, total

Mordant Yellow 1

Mordant Yellow 8

Mordant Yellow 16

All other

Mordant orange dyes, total

Mordant Orange 1

Mordant Orange 6

All other

Mordant red dyes, total

Mordant Red 7

All other

Mordant blue dyes, total

Mordant Blue 1

All other

Mordant brown dyes, total

Mordant Brown 1

Mordant Brown 33

Mordant Brown 40

All other

fcfardant black dyes, total

Mordant Black 3

Mordant Black 11

Ifcirdant Black 13

Mordant Black 17

Mordant Black 38

All other

All other mordant dyes

SOLVENT DYES

Total

Solvent yellow dyes, total

Solvent Yellow 2

Solvent Yellow 3

Solvent Yellow 14

Solvent Yellow 47

All other

Solvent orange dyes, total

Solvent Orange 3

Solvent Orange 7

All other

3,551

10 159

2,736

2,054 409 273

8,547

45 747

41 262

121 225

1.000 dollars

3,976

3,164

20 2,273

7,974

38 516

108 220

140 30

4,995

138 232

182 139

33 483

3,138

25

1,968

111

522

41 471

36

13,380

1,816

49

59

512

184

1,012

671

37 165 469

See footnotes at end of table.

DYES TABLE 8A. Benzenoid dyes : U.S. production and sales , 1964 Continued

23

Dye

Production

CJuantity

SOLVENT DYES— Continued

Solvent red dyes, total

Solvent Red 24

Solvent Red 26

Solvent Red 49

All other

Solvent violet dyes, total

Solvent Violet 8

All other

Solvent green dyes, total

Solvent Green 3

All other

Solvent brown dyes

All other solvent dyes

SULFUR DYES^

Total

Sulfur Blue 7

Leuco Sulfur Blue 7

Sulfur Blue 11

Sulfur Brown 10

Sulfur Black 1

Leuco Sulfur Black 2

All other sulfur dyes

VAT DYES

Total

Vat yellow dyes, total

Vat Yellow 2, 8-I/25S

Vat Yellow 4, 12-l/2?t-

All other

Vat orange dyes, total

Vat Orange 1, 20^S

Solubllized Vat Orange 1, 26$

Vat Orange 2, 12^

Vat Orange 4, 6f-

Vat Orange 5, 105^

Solubilized Vat Orange 5, SOjt

Vat Orange 7, II56

Vat Orange 9, 12^4

Vat Orange 15, 10^

All other

Vat red dyes, total

Vat Red 1, 13%

Solubilized Vat Red 1, 375^

Vat Red 13, 11^6

Vat Red 15, lOf

Vat Red 32, 20;^

All other

Vat violet dyes, total

Vat Violet 1, 1156

Vat Violet 2, 205^

Vat Violet 9, 125^

Vat Violet 13, 6-1/4^6

All other

See footnotes at end of table.

1,192

293

300

20

579

163

146 47

5,055

17,776

52,518

3,394

1,784

764

846

2,296

485 8 300

6 207 101 471 656

1,126

"52S"

100 171

283 36

308 156

1.000 pounds

1,000 dollars

1,140

295

257

21

567

318 148

60 4,987

17,268

121

123

639

21

16

47

50

1,076

1,188

2,776

2,452

13,096

13,439

51, 699

3,431

1,884 735 812

2,077

373

12

263

93

119

4

225

106

464

418

1,056

501

234 29 82

380 82

2,215

530

450

136

1,099

950

472 478

252 175

227 7,074

9,798

19

35

407

974

8,260

46, 162

4,641

1,637

835

2,169

4,729

1,060 88 550 258 170 42 591 255 980 735

783 38 263 172 127 923

1,578

287 473 245

24

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 8A. Benzenoid dyes: U.S. production and sales, 1964 Continued

r>ye

Production

Sales

Quantity

Unit value^

VAT DYES— Continued

Vat blue dyes, total

Vat Blue 4, 10$

Vat Blue 6, 8-I/356

Solubilized Vat Blue 6, 17-1/2^-

Vat Blue 18, 135^

Vat Blue 20, W?^

All other

1,000 pounds 20,894

1,000 pounds 20,519

Vat green dyes, total

Vat Green 1, 656

Vat Green 3, 10^ -

Solubilized Vat Green 3, 265^-

Vat Green 8, 8-l/2?6 -

Vat Green 9, I2-I/256-

All other

74

3,550

31

960

1,152 15,127

11,378

Vat brown dyes, total- Vat Brown 1, lljS

Vat Brown 3, lljt

Vat Brown 5, 13$

All other

5,902 2,955

17 1,127 1,302

75

5,063

66

3,353

39

1,034

992

15,035

11,436

1,000 dollars 11,969

3.58

148 3,457

244 1,655 1,097 5,368

7,916

2.24 1.03 6.26 1.60 1.11 .36

Vat black dyes, total

Vat Black 9, 16?^

Vat Black 25, 12-1/2$-- Vat Black 27, 12 -1/2 ?^- All other

1,018 990 144

2,911

7,584

5,599 2,959

1,347

1,444

87

4,632

All other dyes-^

las'

3,120

966

3,390

41A

964

891

100

2,677

7,741

3,325 2,092

966

1,275

258

6,325

1.37

123 3,313

909 3,396

337

1,735

1,422

145

3,023

6,698

1.80 1.60 1.45 1.13

.87

295 2,364 1,059 2,980

878

2.40

.71

1.16

■'■ Calculated from rounded figures.

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of the usual commercial concentration of the C.I. Sulfur dyes.

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

On the other hand, the output of a few important dyes was smaller in 1964 than in 1963. Pro- duction of Vat Green 3 was 3. 0 nnillion pounds in 1964, or 7. 9 percent less than the 3. 2 million pounds produced in 1963; that of Mordant Black 11 was 2. 1 million pounds, or 14. 8 percent less than the 2.4 million pounds produced in 1963. The output of Vat Green 9 was 24.4 percent smaller in 1964 than in 1963; that of Vat Green 8 was 20. 8 percent smaller; and that of Acid Black 1 was 19.9 percent smaller.

Table 9 summarizes production and sales of dyes in 1964, by class of application. Five classes of dyes grouped by class of application accounted for 74 percent of the total output of dyes in 1964. Vat dyes accounted for 28. 5 percent of the total; direct dyes, for 17. 1 percent; acid dyes, for 9. 6 percent; sulfur dyes, for 9. 6 percent; and fluorescent brightening agents, for 9. 1 percent. Of the above five classes, the output for acid and vat dyes remained about the same in 1964 as in 1963. The output of direct dyes was 10. 9 percent larger in 1964 than in 1963. Sta- tistics on sulfur dyes and fluorescent brightening agents were not published separately for 1963.

Of the remaining classes, the output of fiber- reactive dyes was 1. 6 million pounds in 1964, or 44. 9 percent more than the 1. 1 million pounds in 1963. Production of food, drug, and cos- metic colors was 21.0 percent larger in 1964 than in 1963; disperse dyes, 16.0 percent larger; solvent dyes, 11.7 percent larger; and basic dyes, 4.6 percent larger. On the other hand, the output of mordant dyes was 12. 5 percent smaller in 1964 than in 1963, and that of azoic dyes and components, 1.0 percent smaller.

Table 10 shows production and sales of dyes in 1964, by chemical class. In 1964, three chemical classes of dyes accounted for approximately two-thirds of all the dyes produced: Azo dyes accounted for 31. 4 percent of the total; anthraquinone dyes, for 22. 6 percent; and stilbene dyes, for 10. 0 percent. The output of each of these three classes was larger in 1964 than in 1963; Stilbene dyes were 16. 0 percent larger; azo dyes, 8. 5 percent larger; and anthraquinone dyes, 1.8 percent larger. Of the remaining chemical classes for which 1963 and 1964 statistics are published, production of eight classes was larger in 1964 than in 1963. No comparable sta- tistics for 1963 were published on the following classes of dyes: Cyanine, indigoid, and sulfur. In terms of value of sales, the most important classes of dyes in 1964 were the azo dyes ($96. 6 million), the anthraquinone dyes ($66.9 million), the stilbene dyes ($29.2 million), and the tri- arylmethane dyes ($12.7 million).

DYES

25

TABLE 9. Benzenoid dyes : U.S. production arid sales , by class of application, 1964

Class of application

Total

Acid

Azoic dyes and components:

Azoic compositions

Azoic dlazo components, bases (Fast color bases)

Azoic dlazo components j salts (Fast color salts)

Azoic coupling con?!onents (Naphthol AS and derivatives)

Basic

Direct

Disperse

Fiber-reaotlve

Fluorescent brightening agents

Food, drug, and cosmetic colors

Mordant

Solvent

Sulfur^

Vat

All other^—

Production

1,000 pounds l8<i.,387

Quantity

1,000 pounds 178,273

17,090

1,707

1,272

1,973

2,447

8,553

31,939

11,993

1,526

15,673

2,846

3,976

7,974

17,268

51,699

337

1,000 dollars 264,023

35,812

3,441

1,984

2,028

4,696

20,878

46,807

28,032

6,261

27,802

11,069

4,995

13,380

9,798

46,162

878

Unit value'"'

md $1.48

2.10

2.02 1.56 1.03 1.92 2.44 1.47 2.34 4.10 1.77 3.89 1.26 1.68 .57

Calculated from rounded figures.

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in temiB of the usual commercial concentration of the C.I. Sulfur dyes.

^ Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

TABLE 10.— Benzenoid dyes: U.S. production and sales , by chemical class, 1964

Chemical class

Total

Anthraquinone—

Azo, total

Manoazo

Disazo

Trisazo

Polyazo

Not specified-

Azoic

Cyanine

Indigoid

Ketone imine

Methine

Nitro

Oxazine

Phthalooyanine-

Quinoline

Stilbene

Sulfur^

Thlazole

Triarylmethane-

Xanthene

All other^

Production

Sales J

Unit 5

Quantity

Value

value

1,000

1,000

1,000

Per

pounds

pounds

dollars

pound

184,387

178,273

264,023

$1.48

41,661

40,675

66,889

1.64

57,897

57,367

96,579

1.68

21,084

19,932

38,522

1.93

16,873

17,278

28,867

1.67

11,883

12,303

12,730

1.03

2,344

2,218

3,819

1.72

5,713

5,636

12,641

2.24

8,787

7,399

12,149

1.64

373

362

1,113

3.07

5,729

6,144

3,302

.54

731

782

1,614

2.06

1,074

974

3,367

3.46

720

679

1,258

1.85

172

144

601

4.17

1,987

1,868

4,800

2.57

637

519

1,658

3.19

18,488

17,640

29,166

1.65

17,776

17,268

9,798

.57

462

480

1,043

2.17

5,607

5,312

12,682

2.39

1,312

737

3,473

4.71

20,974

19,923

14,531

.73

1

Calculated from rounded figures.

^ Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of the usual commercial concentration of the C.I. Siilfur dyes.

' Includes aoridine, amlnoketone, azine, coumarin, hydroxylcetone, nltroso, oxidation bases, thiazine, vat sulfur, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

26 SYNTHETIC ORGANIC CHEMICALS, 1964

Pigments

As the terms are used in this report, synthetic organic pigments are toners and lakes de- rived in whole or in part from benzenoid chemicals and colors. They are used in paints and related products, in printing inks, and in plastics and resin materials.

Statistics on production and sales of all benzenoid pigments in 1964 are given in table llA.^ Statistics on sales of a few selected pigments by connmercial forms (dry full-strength form, dry extended fornn, dry dispersions, aqueous dispersions, and flushed colors) are given in table 12. Prior to 1961, statistics for toners included the quantities and values of extenders and diluents. Beginning in 1961, data were collected for both the full- strength and extended toners on a full- strength-toner- content basis. Individual toners and lakes are identified in this report by the names used in the second edition of the Colour Index rather than by their common names.'*

Total production of benzenoid pigments in 1964 was 44. 1 million pounds--ll. 8 percent more than the 39.4 million pounds produced in 1963 and 18. 6 percent more than the 37. 2 million pounds produced in 1962. Total sales of benzenoid pigments in 1964 amounted to 35. 1 million pounds, valued at $84. 1 million, compared with 33. 5 million pounds, valued at $79. 6 million, in 1963 and 31. 6 million pounds, valued at $74. 3 million, in 1962. In terms of quantity, sales of benzenoid pignnents in 1964 were 4. 6 percent larger than in 1963 and 11.0 percent larger than in 1962; in terms of value, sales in 1964 were 5. 7 percent larger than in 1963 and 13.2 percent larger than in 1962.

Production of toners in 1964 amounted to 40. 0 million pounds--12. 6 percent more than the 35.6 million pounds reported for 1963. Sales in 1964 were 31.4 million pounds, valued at $80.9 million, compared with 30. 1 million pounds, valued at $76. 2 million, in 1963. Sales in 1964 were thus 4.4 percent larger than those in 1963 in terms of quantity, and 6. 2 percent larger in terms of value. Production of red toners in 1964 amounted to 17. 8 million pounds, or 44. 5 per- cent of the total output of toners. The individual toners listed in the report ■which were produced in the largest quantities in 1964 were Pigment Green 7, 4. 0 million pounds; Pigment Blue 15, alpha form, 3. 9 million pounds; Pigment Yellow 12, 3. 2 million pounds; Pigment Red 49, bar- ium toner, 3. 1 million pounds; and Pigment Blue 19, 3.0 million pounds.

Production of lakes totaled 4. 0 million pounds in 1964--4. 8 percent more than the 3. 8 mil- lion pounds reported for 1963. Sales of lakes in 1964 amounted to 3. 7 million pounds, valued at $3. 3 million, compared with sales in 1963 of 3.4 million pounds, valued at $3.4 million. Sales in 1964 were thus 6. 8 percent larger than those in 1963 in terms of quantity, but 5. 1 percent smaller in terms of value. Pigment Blue 24, with an output of 2.0 million pounds, was the lake produced in largest quantity in 1964.

For each of 14 selected pigments, or groups of pigments, the Commission's report gives figures on sales by commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 19 were sold principally in the flushed form. The rennaining 11 pigments, or groups of pigments, for which statistics are published were sold principally in the dry full- strength form. Statistics on sales by commercial forms could not be published for Pigment Red 49, sodium toner and Pigment Blue 24 without revealing the operations of individual companies.

^ See also table IIB, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in appendix which shows imports of benzenoid pigments during the years 1963-64,

■♦See appendix C, which lists the common names of all the pigments mentioned in this report.

PIGMENTS

27

TABLE llA.—Benzenoid pigments : U.S. production and sales , 1964

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table IIB in pt. Ill lists all toners and lakes for which data on production or sales were reported and identifies the manufacturer of each]

Pigment

Grand total

TONERS

Total

Yellow toners, total

Hansa yellows, total

Pigment Yellow 1, C.I. 11 680

Pigment Yellow 3, C.I. 11 710 -

Other Hansa yellows

Benzidine yellows, total

Pigment Yellow 12, C.I. 21 090

Pigment Yellow 13, G.I. 21 100

Pigment Yellow 1-4, G.I. 21 095

Pigment Yellow 17, C.I. 21 105

Other benzidine yellows

All other

Orange toners, total

Pigment Orange 2, C.I. 12 060

Pigment Orange 5, C.I. 12 075

Pigment Orange 13, C.I. 21 110

Pigment Orange 16, C.I. 21 160

All other

Red toners, total

Naphthol reds, total

Pigment Red 2, C.I. 12 310

Pigment Red 5, C.I. 12 A90

Pigment Red 13, C.I. 12 395

Pigment Red 17, G.I. 12 390

Pigment Red 18, C.I. 12 350

Pigment Red 22, G.I. 12 315

Pigment Red 23, C.I. 12 355

Other naphthol reds

Pigment Red 1, C.I. 12 070, dark

Pigment Red 1, G.I. 12 070, light

Pigment Red 3, C.I. 12 120

Pigment Red 4, C.I. 12 085

Pigment Red 38, C.I. 21 120

Pigment Red 48, G.I. 15 865

Pigment Red 49, C.l. 15 630:

Barium toner

Calcium toner

Sodium toner

Pigment Red 52, G.I. 15 860

Pigment Red 53, C.I. 15 585, barium toner-. Pigment Red 57, G.I. 15 850, calcium toner.

Pigment Red 63, C.I. 15 880

Pigment Red 81, C.I. 45 160, PMA

Pigment Red 81, C.I. 45 160, PTA

Pigment Red 90, C.I. 45 380

All other

Violet toners, total

Pigment Violet 1, G.I. 45 170, BIA

Pigment Violet 1, C.I. 45 170, PTA

Pigment Violet 3, C.I. 42 535, fugitive- Pigment Violet 3, C.I. 42 535, PMA

Pigment Violet 3, C.I. 42 535, PTA—

All other

See footnotes at end of table.

1,000 pounds

44,053

40,028

5,958

1,152 540 128

484 4,642 3,180 195 978 176 113 164

768

206 155 179 192

17,817

11 98 123 291 198 241

1,913 372 144

2,365

3,058

1,425

240

910

1,884

937

41

228

131

1,243

1,696

1,077

(iiantlty

444

359

30

143

1,000 pounds

35,081

925

401

88

436

2,931

1,791

116

793

130

101

97

651

161

. 145

152

193

14,949

605 51

86 117 194 171 198

1,395 259 131

2,076

2,926

1,349 282 828

1,534 836 32 169 128 595

1,435

1,015

1.000 dollars

84,131

424 333

),870

10,583

2,437

748

208

1,481

6,994

3,900

375

1,889

436

394

1,152

2,814

255

487

418

1,654

31,964

2,665

159

385

20

235

252 431

1,183 212 239

2,155 362 594

3,881

2,844 1,375

291 1,232 1,934 1,259 67 1,059

818 1,109 9,868

3,673

172 239 624 982 129 1,527

28

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE llA. Benzenoid pigments : U.S. production and sales , 1964 Continued

Pigment

Quantity

Unit value •'■

TONEES--Continued

Blue toners, total

Pigment Blue 1, C.I. 42 595, MA

Pigment Blue 1, C.I. <i2 595, PTA

Pigment Blue 9, C.I. 42 025, FMA

Pigment Blue 9, C.I. 42 025, PTA

Pigment Blue U, C.I. 42 600, PMA

Pigment Blue 15, C.I. 74 160, alpha form

Pigment Blue 15, c!l. 74 160, beta foim

Pigment Blue 19, C.I. 42 750A

Pigment Blue 25, C.I. 21 180

All other

Green toners, total

Pigment Green 1, C.I. 42 040, BJA

Pigment Green 1, C.I. 42 040, PTA

Pigment Green 2, C.I. 42 040 and 49 005, IMA- Pigment Green 2, C.I. 42 040 and 49 005, PTA-

Pigment Green 4, C.I. 42 000, PTA

Pigment Green 7, C.I. 74 260

Pigment Green 8, C.I. 10 006

All other

Brown toners, total

Pigment Brown 5, C.I. 15 800

All other

Blaot toners

LAKES

Total

Red lakes, total

Pigment Red 60, C.I. 16 105

Pigment Red 83, C.I. 58 000

(Acid Red 26), C.I. 16 150

All other

Violet lakes, total

Pigment Violet 5, C.I. 58 055

All other

Blue lakes, total

Pigment Blue 24, C.I. 42 090

All other

Black lakes: (Natural Black 3), C.I. 75 291

All other lakes^

10

56

3,864

2,007

3,033

142

202

4,581

4,004 174 282

4,025

113 78

575 94

2,058

,026 32

1.000

1,000

pounds

dollars

7,460

21.229

142

672

30

152

3

12

8

50

57

511

3,149

8,417

1,577

4,596

2,235

5,342

3,169

11

6

50

37

6

2,760

145

154

74

3,653

110 74

575 89

1,690

1,660

10,170

60

37

230

236

21

8,292

187

1,107

82

183

3,261

195 249 255 152

1,586

67 466

$2.85

5.45 6.17

3.58 1.78

1-00

1.77 3.36

2.30 1.50

1.02 .50

^ Calculated from rounded figures.

^ Includes all brown, green, orange, and yellow lakes and all other black lakes.

Note. —The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edition of the Colour Index,

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) acids, respectively.

PIGMENTS

29

TABLE 12.-

■U.S. sales of selected dp full-strength colors, dry extended colors dry dispersions aqueous dispersions, and flushed colors, 1964

Selected pigments by commercial forms

Quantity^

Unit value ^

Pigment Yellow 12, C.I. 21 090, total

Dry full-strength toner

Dry extended toner, aqueous dispersions^ and flushed color''

Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment

Yellow 17, C.I. 21 105; and other "benzidine yellows, total

Dry full-strength toner

Diy extended toner and dry dispersions''

Aqueous dispersions-'

Flushed color

Pigment Red 3, C.I. 12 120, total- -

Dry full-strength toner and diy extended toner''- Aqueous dispersions^

Flushed color

Pigment Red 48, C.I. 15 865, total

Dry full-strength toner

Dry extended toner

Dry dispersions

Aqueous dispersions-' and flushed color*

Pigment Red 49, C.I. 15 630, barium toner, total- Dry full-strength toner

Diy dispersions and aqueous dispersions-' "^

Flushed color

Pigment Red 49, C.I. 15 630, calcium toner, total- Dry full-strength toner and dry dispersions'*

Aqueous dispersions^ and flushed color*

Pigment Red 49, C.I. 15 630, sodium toner'*-

Pigment Red 53, C.I. 15 585, barium toner, total-

Diy full-strength toner

Flushed color

Pigment Red 90, C.I. 45 380, total

Dry full-strength toner and dry extended toner'' Flushed color

Pigment Violet 3, C.I. 42 535, fugitive, total

Diy full-strength toner and dry extended toner''- Flushed color

Pigment Violet 3, C.I. 42 535, permanent (PMA and PTA), total

Diy full-strength toner

Diy extended toner, dry dispersions and aqueous dispersions ^ *- Flushed color

Pigment Blue 15, C.I. 74 160, alpha form, total- Diy full-strength toner

Dry extended toner

Dry dispersions

Aqueous dispersions^

Flushed color

Pigment Blue 15, C.I. 74 160, beta form, total- Dry full-strength toner

Dry extended toner and diy dispersions''

Aqueous dispersions^

Flushed color

Pigment Blue 19, C.I. 42 750A, total

Dry full- strength toner and diy extended toner ''- Aqueoiis dispersions^ and flushed color''

1,000 pounds

1,791

607 1,184

1,140

83 112

145

1,395

863

57

475

2,076

1,932 37 28 79

2,926

2,072

1,349

1,108 241

1,534

958 576

53

542

279 145

3,149

1,756

447

80

714

152

1,577

863

36

402

276

2,235

454 1,781

1.000 dollars

4,102

1,314 2,788

3,169

2,207 196 298 468

2,212

1,332

97

783

3,915

3,626

75

60

154

2,992

2,016

5

971

1,454

1,127 327

2,003

1,205 798

114 1,095

409 220

610 226 291

8,588

4,527 1,560

178 1,924

399

4,594

2,749 127

1,090 628

5,430

1,097 4,333

See footnotes at end of table.

30

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 12. U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, aqueous dispersions, and flushed colors, 1964 Continued

Selected pigments by commercial forms

Quantity"""

Unit value ^

Pigment Blue 2^, C.I. ^2 090*

Pigment Green 7, C.I. 74 260, total-

Diy full-strength toner

Dry extended toner

Dry dispersions

Aqueous dispersions-

Flushed color

1.000 pounds

1,660

2,760

1,000 dollars

1,7-40 258 130 MA 168

8,529

5,235 924 482

1,459 429

$1.18 3.09

3.01 3.58

""" Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content. ^ Calculated from rounded figures. ^ Includes presscake.

'' Separate data on these commercial forms may not be published without revealing the operations of individual companies.

Note. Kie C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edition of the Colour Index.

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic) acids, respectively.

MEDICINAL CHEMICALS 31

Medicinal Chemicals

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having therapeutic Value, whether obtained by chemical synthesis, by fermentation, by extraction from naturally occurring plant or animal substances, or by refining the technical grade material. They include alkaloids, antibiotics and other anti- infective agents, antihistamines, autonomic drugs, central-nervous-system depressants and stimulants, hormones, vitamins, and other therapeutic agents for human or veterinary use and for animal feed supplements.

Statistics on the production of medicinal chemicals are in terms of 100-percent content of the medicinal chemical itself, exclusive of all diluents or other materials used in mixing or compounding tablets, solutions, and suspensions for consumer use. Except for antibiotics, the statistics on sales include only that part of the original (primary) production that was sold in undiluted or uncompounded form. Sales of antibiotics include all sales by the primary producers, both diluted and undiluted, in bulk or in dosage forms.

Statistics on U. S. production and sales of medicinal chemicals in 1964 are given in table 13A.^ Total production of medicinal chemicals in 1964 amounted to 144 million pounds, or 3. 5 percent more than the 139 million pounds produced in 1963, and 13.1 percent more than the 127 nnillion pounds produced in 1962. Total sales of medicinal chemicals in 1964 amounted to 119 million pounds, valued at $646 nnillion, compared with sales in 1963 of 114 million pounds, valued at $639 million, and sales in 1962 of 104 million pounds, valued at $601 million. Sales in 1964 were thus 4. 2 percent larger than in 1963 and 14. 5 percent larger than in 1962 in terms of quantity, and 1. 0 percent larger than in 1963 and 7. 5 percent larger than in 1962 in terms of value.

Since 1962, the data published on medicinal chemicals have been divided into antibiotics and benzenoid and nonbenzenoid groups, instead of into cyclic and acyclic groups as in previous years. Totals for the cyclic and acyclic groups are shown in this report, however, in order to permit comparison of the statistics for 1964 with those for the years prior to 1962. Production of cyclic medicinal chemicals in 1964 amounted to 98 million pounds, or 3. 7 percent more than the output of 94 million pounds reported for 1963. Sales of cyclic medicinals in 1964 amounted to 77 million pounds, valued at $612 million, compared with sales in 1963 of 74 million pounds, valued at $605 million. Production of acyclic medicinals in 1964 amounted to 47 million pounds, or 3. 2 percent more than the output of 45 million pounds reported for 1963. Sales of acyclic medicinals in 1964 amounted to 42 million pounds, valued at $33 million, compared with sales in 1963 of 40 nnillion pounds, valued at $34 million.

Production of antibiotics for all uses in 1964 amounted to 6. 5 million pounds, of which 3. 9 million pounds was for human or veterinary use and 2. 6 million pounds was for animal feed supplements, food preservation, and crop spraying. Sales amounted to 5.7 million pounds, valued at $386 million. The most important antibiotics, in terms of value, were the penicillin salts and tetracycline. Production of penicillin salts for all uses amounted to 1,202 trillion U. S. P. units; sales totaled 965 trillion U. S. P. units, valued at $86 million. Production of tetra- cycline for human or veterinary use amounted to 176 million grams of activity; sales totaled 152 nnillion grams of activity, valued at $55 million.

Production of benzenoid nnedicinals in 1964 amounted to 78 million pounds; sales totaled 61 million pounds, valued at $162 nnillion. The benzenoid nnedicinal chennicals that Tvere produced in largest quantity in 1964 were aspirin, 28. 2 million pounds; salicylic acid, 13. 1 million pounds; and the anti- infective sulfonamides, 5. 0 million pounds.

Production of nonbenzenoid medicinals in 1964 amounted to 60 million pounds; sales to- taled 52 million pounds, valued at $98 million. The most important nonbenzenoid nnedicinal chennicals, in terms of quantity, were choline chloride, production of which amounted to 25. 2 million pounds, piperazine and salts, 7. 0 million pounds, and methionine and its hydroxy ana- logue, 6. 0 million pounds.

Production of all vitamins, both benzenoid and nonbenzenoid, amounted to 14. 1 million pounds in 1964; sales amounted to 10. 6 million pounds, valued at $60. 6 million. The most im- portant vitamins, in ternns of value, were vitamins A, Bj, B12, and C. Production of vitamin A alcohol and esters announted to 618 trillion U. S. P. units; sales totaled 470 trillion U. S. P. units, valued at $19.7 million. Production of vitamin B2 (riboflavin) amounted to 662,000 pounds; sales totaled 701,000 pounds, valued at $6.4 million. Sales of vitamin B12 (cyanoco- balannin) announted to 398,000 grams, valued at $6.9 million. Production of vitamin C (ascor- bic acid) and derivatives amounted to 7.4 million pounds; sales totaled 5.3 million pounds, valued at $10. 3 million.

5 See also table 13B, pt. lU, which lists these products alphabetically and identifies the manufacturers, and table 23 in appendix A, which shows imports of coal-tar medicinal chemicals and pharmaceuticals during the years 1963-64.

32

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13A. Medicinal chemicals: U.S. production and sales , 1964

[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may be

published. (Leaders are used where the reported data are accepted in confidence and may not be published or where

no data were reported.) Table 13B in pt. Ill lists alphabetically all medicinal chemicals for which data on pro- duction or sales were reported and identifies the manufacturer of each]

Production

Sales'^

Quantity

Grand total

Cyclic'^

Acyclic*^

MEDICINAL CHEMICALS, AOTIBIOTICS^

Total

For human or veterinary use, total

Bacitracin

Dihydrostreptomyoin

Neomycin

Penicillins, total

Penicillin G, potassium

Penicillin G, procaine

Penicillin G, other

Phenethicillin and potassium salt

All other penicillins

Tetracycline

All other^

For animal feed supplements, food preservation, and crop

spraying, total

Bacitracin --

Penicillin G, procaine

All other^ - -

MEDICINAL CHEMICALS, BENZENOID''

Total

Alkaloids, except those affecting the autonomic or central nervous system

Antihistamines, total

Antinauseants

2-[p-Chloro-a -(2-dimethylaminoethyl)benzyl] pyridine

(Chlorpheniramine) maleate

2-[a-(2-Dimethylaminoethyl)benzyl] -pyridine (Pheniramine)

maleate

2- [ ( 2-Dimethylami noethyl ) (p-methoxybenzyl)amino]pyridine

(Pyrilamine) maleate

All other

Anti-infective agents, total

Antimony, arsenic, bismuth, and mercury compounds*

1-Hexadecylpyridinium (Cetylpyridinium) chloride

Phenolic antiseptics and disinfectants

Quinoline derivatives, total

5-Chloro-7-iodo-8-qulnolinol (lodochlorhydroxyquin)

5,7-Diiodo-8-quinolinol (Diiodohydroxyquin)

8-Quinolinol (Oxyquinoline) benzoate

8-Quinolinol (Oxyquinoline) sulfate

All other

Sulfonamides, total

Sulfathlazole

All other

Other anti-Infective agents, total

Anthelmintic, antifungal, and antlprotozoan agents

All other' -

Autonomic drugs, total

Parasympatholytic (anticholinergic) agents

1,000 pounds 1^4,090

97,579 46,511

6,540

3,913

92

1,569

505

799

54

14

197

388

1,857

2,627

565 1,904

77,557

17,736

2,937

10

157

320

11

21

10 275 4,964 144 4,820 9,345 7,229 2,119

338

i.OOO pounds

118,678

76,946 41,732

5,729

3,235

436

70

1,215

413

623

31

12

136

336

1,173

2,494

136

515

1,843

61,344

20 167

150 10,887

136 227

225 1,476

111 1,365 9,048 6,616 2,432

230

2r

1,000 dollars

645,692

612,233 33,459

385,910

328,445

1,128

6,306

5,069

82,389

18,411

12,204

10,972

3,954

36,848

54,570

178,983

57,465

3^< 3,659 50,717

162,067

656 4.810

269 269

4,272 60,669

299 2,905

2,897

6,783 291

6,492 50,682 45,179

5,503

4,815

See footnotes at end of table.

MEDICINAL CHEMICALS TABLE ISA.— Medicinal chemicals: U.S. production and sales , i 564— Continued

33

Production'''

Quantity

MEDICKWl CHEMICALS, BENZENOID'— Continued

Autonomic drugs Continued

Sympathomimetic (adrenergic) agents, total

Epinephrine

a-(lEopropylamlnomethyl)protocatechuyl alcohol

(Isoproterenol)

Norephedrine (Phenylpropanolamine) hydrochloride

Phenylephrine hydrochloride

All other

All other autonomic drugs

Benzothiadiazine derivatives

Bismuth subgallate

Central depressants, total

Dihydrocodeinone (Hydrocodone) bitartrate

5-Ethyl-5-phenylbarbituric acid (Phenobarbital)

5-Ethyl-5-phenylbarbituric acid, sodium derivative

p-Hydroxyacetanilide (Acetaminophen)

Salicylates, total

Aspirin

Sodium salicylate

All other

Skeletal muscle relaxants and tranq\iilizers , total

Phenothiazine derivatives

3-o-Tolyloxy-l,2-propanediol (Mephenesin)

All other

All other central depressants

Central stimulants, total

Amphetamines, total

Anjjhetamine, dextroamphetamine, and levamphetamine

base and salts

Methamphetamine base and hydrochloride

Antidepressants

All other central stimulants

Guaiacol glyceryl ether

Salicylic acid

Synthetic hypoglycemic agents

Vitamins, total

Ba (Riboflavin) (All grades)

Bi2 (Cyanocobalamin) (All grades) ■'■■'■

Niacin (Nicotinic acid) (All grades)

Niacinamide (Nicotinamide)

All other

All other benzenoid medioinals^^

MEDICINAL CHEMICALS, NONBENZENOID^^

Total

Anti-infective agents, total

Caprylates and undecylenates

Derivatives of 5-nitrofurane, 5-nitroimidazole, and 5-

nitrothiazole

Halogen coii5)ounds

Plperazine and salts, total

Piperazine

Piperazine hydrochloride

Piperazine phosphate

All other

All other anti-infective agents

1.000 pounds

(10)

35,«^69

242

8

1,060

30,935

28,221

2,714 400

338 2,823

41 70

32 13,127 1,010

1,549 802 429

5,782

59,993

8,219

1,000 pounds

(10)

1,000 dollars

140 40

31,883

1,037

27,712

24,864

465

2,383

162

3

159 2,674

35 10,587

2,911

701

1

1,218

757

234

4,394

51,605

5,935

397

619

547

5,684

140

6,950

4,774

3,831

2,631

917

854

417

413

459

196

191

154

3,706

3,253

2,364

93

217

566

29 1,038 1,596

6,777 95

33,445

203

759

36

1,357

16,323

13,560

337

2,426

5,533

158

5,375 9,234

5,504

2,690 2,298

113 4,143

21,747

6,383 6,852 1,505 1,369 5,638

19,293

97,715

10,583

See footnotes at end of table.

34

SYNTHETIC ORGANIC CHEMICALS, '964 TABLE 12 A. --Medicinal chemicals.- U.S. production and sales , 7564— Continued

Production

Quantity Value

MEDICINAL CHEMICALS, NONBENZENOID^^--Continued

Autonomic drugs

Central depressants and stimulants, total

Barbiturates, total

S-seo-Butyl-S-ethylbarbituric acid (Butabarbital) and

sodium derivative

5-Ethyl- 5- (1-methylbutyl) barbituric acid (Pentobar- bital)

All other

Caffeine (natural and synthetic)

2-Methyl-2-propyl-l,3-propanediol dicarbamate

(Meprobamate)

Succinylcholine chloride

All other central depressants and stimulants

Digestants and lipotropic agents, total

Betaine base, hydrate, and hydrochloride

Bile acids and salts

Choline salts:

Choline bitartrate

Choline chloride (All grades)

Choline dihydrogen citrate

Tricholine citrate

Methionine and hydroxy analogue

All other digestants and lipotropic agents

Hormones, total

Hydrocortisone alcohol and acetate

Prednisone

All other

Theobromine and theophylline derivatives

Therapeutic nutrients, total

Amino acids, total

Amino acid mixtures

Aspartic acid and salts

Glutamic acid

All other

Calcium gluconate

All other therapeutic nutrients

5-Ureidohydantoin (Allantoin)

Vitamins, total

Ascorbic acid and derivatives, total

Ascorbic acid

All other

Pantothenic acid and derivatives, total

dl-Calcium pantothenate

All other

Vitamin A alcohol and esters, total^"''

Vitamin A palmitate (medicinal grade)

All other

Vitamin D; (Ergooalciferol )■'■■'•

All other vitamins''"'^

All other nonbenzenoid medicinal chemicals''''^

pounds

529 2,791

1,173

8

428

31,787

44 117

208 25,194

6,049 104

1,739 23 37 81 1,598 652 371

1,000 pounds

1,000 dollars

155 2,441

902

154

30,654

210

24,3U

64

18

5,860

188

30

2,612

1,663

58

1,605

575

374

17

7,718

1,604

358

50 1,196 4,260

2,430

1,224

12,705

197 5,042

6,203 1,183

19,850

2,800

17,050

192

3,196

2,407

2,313 367 422

38,831

7,409

5

,348

10,329

6,080

4

,405

8,291

1,329

943

2,038

1,711

1

,208

3,017

1,359

986

1,893

352

222

1,124

694

533

19,700

211

172

6,787

483

361

12,913

1

1

325

848

628

5,460

1,522

2,757

See footnotes on following page.

MEDICINAL CHEMICALS

35

Footnotes for table 13A

■'• The data on production are those for medicinal chemicals In bulk; they do not include finished preparations, such as tablets, capsules, and ampoules, which are manufactured from bulk chemicals.

^ Except for antibiotics, sales include only that part of the original production which is sold in undiluted or uncompounded form, including that sold in bulk and that sold in packages (tablets, ampoules, etc.). Sales of anti- biotics include all forms (both undiluted or uncompounded and diluted or compounded), including that sold in bulk and that sold in packages.

^ Calculated from rounded figures.

^ Since 1962, medicinal chemicals have been divided into antibiotics, benzenoid, and nonbenzenoid groups, instead of into cyclic and acyclic groups, as in previous reports. Totals for the cyclic and acyclic groups are shown in this report in order to facilitate comparison of the statistics for 196^ with those for the years prior to 1962.

^ For statistical purposes, reported quantities of antibiotics have been converted from grams of activity or U.S. P. units to pounds by means of the following conversion factors: Procaine penicillin G, A53.6 million units=l pound; penicillin V salts, 768.9 million unlts=l pound; other penicillin salts and hygromycin B, 756 million units= 1 pound; bacitracin, 22.7 million unlts=l pound; polymyxin B, 2,812.3 million units=l pound; all other antibiotics, 453.6 grams of aotivlty=l pound. Statiistics for all individually publishable antibiotics are given in the following tabulation in terms of 'million U.S. P. units (MU), billion U.S. P. units (BU), or kilograms of activity (Kg.):

Antibiotic

Production

Sales (bulk and dosage forms)

ftiantity

Bacitracin (MU), total

For human or veterinary use- For other uses

3,728,231

3,217,150

1,000 dollars

4,235

$1.32

Dihydrostreptomycin, for human or veterinary use (Kg. )

Neomycin, for human or veterinary use (Kg.)--

Penioillin salts (BU), total

dl-a-Phenoxyethyl penicillin (Phenethicillln) and potassium salt, for human or veterinary use

Potassium penicillin G, for human or veterinary

use

Procaine penicillin G, total

For human or veterinary use

For other uses

Other penicillin G salts, for human or veteri- nary use

Other penicillin salts, for human or veteri- nary use

Streptomycin, for all uses (Kg.)

Tetracycline, for human or veterinary use (Kg. )

150,095 3,578,136

41,763 1,202,328

119, 140 3,098,010

197,692 31,798

964,857

1,128 3,107

6,306

5,069

86,048

9.47 1.00

31.90 159.41

89.18

10,723

381,729 618,575 362,115 256,460

40,905

150,396

280,995 176,269

9,197

312,057 516,097 282,738 233,359

23,441

104,065

259,378

152,154

3,954

18,411 15,863 12,204 3,659

10,972

36,848

7,543 54,570

429.92

59.00 30.74 43.16 15.68

468.07

29.08 358.65

^ Includes streptomycin, for which separate statistics cannot be published by use category, because publication would reveal the operations of individual companies. Statistics for streptomycin are given in tenns of kilograms in footnote 5.

' The term "benzenoid, " as used in this report, describes any cyclic medicinal chemical, other than antibiotics, whose molecule contains any one or more of the following types of rings : 6-membered carbocyclic rings with conju- gated double bonds, e.g., the benzene ring or the quinone ring; 6-membered heterocyclic rings with 1 hetero atom and conjugated double bonds, e.g., the pyridine rings; or 6-membered heterocyclic rings with 2 hetero atoms and conju- gated double bonds, except the pyrimidine ring, e.g., the pyrazine ring or the pyridazine ring.

Production of all antimony, arsenic, and bismuth compounds, both benzenoid and nonbenzenoid. Including bismuth subgallate, amounted to 2,918,000 pounds. Production of all mercury compounds, both benzenoid and nonbenzenoid, amounted to 51,000 pounds.

' Includes sales of antimony, arsenic, bismuth, and mercury compounds and of 1-hexadecylpyridinium chloride.

Production of epinephrine amounted to 266 pounds; sales amounted to 258 pounds.

■'■■'■ For statistical purposes, reported quantities of vitamins A, Bi2j ^z> and Dj have been converted from grams or U.S. P. units to pounds by means of the following conversion factors: Vitamin A acetate, 1.307 billion units = 1 pound; vitamin A alcohol, 1.510 billion units=l pound; vitamin A natural esters, 1.080 billion units=l pound; vita- min A palmitate, 0.816 billion units=l pound; vitamin B^j' ^53.6 grams=l pound; vitamins D^ and D^, 18.14 billion units=l pound. Statistics for these vitamins (except vitamin D3, for which reported statistics cannot be published because publication would reveal the operations of individual companies) are given in the following tabulation in terms of grams or U.S. P. units:

Unit of quantity

Sales

Vitamin A, total

Palmitate, except feed grade

All other

Vitamin B12

Vitamin Da

Billion units

Grams

Billion units

617,508

172,232 445,276

22,398

140,734

329,309

397,876

19,674

1.000 dollar 19.700

6,787 12,913

6,852 325

$41.91

48.23 39.21 17.22 16.52

^^ Includes production of benzothiadiazine derivatives and sales of synthetic hypoglycemic agents.

■"■ The tenn "nonbenzenoid, " as used in this report, describes any cyclic or acyclic medicinal chemical, other than antibiotics, whose molecule does not contain any of the types of rings described in footnote 7 above. All acyclic compounds and any cyclic compound whose molecule contains only one or more of the following types of rings are clas- sified as "nonbenzenoid": FUlly or partially reduced rings, e.g., the piperidine ring or the cyclohexadiene ring; rings with more or less than 6 members, e.g., the Imidazole ring or the azepine ring; heterocyclic rings with more than 2 hetero atoms, e.g., the triazine ring; or the pyrimidine ring.

■■■* Includes production of hydrocortisone alcohol and acetate and "all other" hormones and sales of autonomic drugs.

36

SYNTHETIC ORGANIC CHEMICALS, 1964 Flavor and Perfume Materials

Flavor and perfume materials are organic chemicals that are used in the manufacture of foods, beverages, cosmetics, and soaps, and to disguise unpleasant odors in industrial prod- ucts. Most of them have desirable flavors or odors, and some have the quality of enhancing natural flavors when added to certain foods. This report includes data on materials derived from natural products by actual chemical processes and from coal tar; it does not include data on purely natural products, such as floral essences, essential oils, and other materials that are obtained by simple extraction or by distillation from natural vegetable and animal sources.

The flavor and perfume materials covered in this report are grouped as either cyclic or acyclic materials, according to their chemical structure. Cyclic materials are further classi- fied as (1) benzenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Statistics on production and sales of flavor and perfume materials in 1964 are given in table 14A.^

Production of flavor and perfume materials in 1964 amounted to 90. 6 million pounds--22. 8 percent more than the output of 73. 8 million pounds in 1963. Sales in 1964 amounted to 80. 0 million pounds, valued at $83. 7_ million, compared with 67. 0 million pounds, valued at $77. 4 million, in 1963.

Production of cyclic flavor and perfume materials in 1964 amounted to 49. 6 million pounds-- 19. 9 percent more than the 41. 3 million pounds reported for 1963. Sales of cyclic fla- vor and perfume materials in 1964 were 41. 2 million pounds, valued at $56. 6 million, compared with 34. 7 million pounds, valued at $51. 4 million, in 1963. The individual chemical in the cyclic group that was produced in the greatest volume in 1964 was methyl salicylate (3. 8 million pounds). Production of synthetic sweeteners, as a group, amounted to 12. 2 million pounds, rep- resenting an increase of 113.7 percent over the quantity produced in 1963.

The output of acyclic flavor and perfume materials in 1964 amounted to 41.0 million pounds--26.4 percent more than the 32. 4 million pounds reported for 1963. By far the most im- portant of the acyclic materials in 1964 was monosodium glutamate, a flavor-enhancing product, production of which totaled 38. 6 million pounds. Sales of acyclic flavor and perfume materials in 1964 amounted to 38. 8 million pounds, valued at $27. 2 million, compared with 32. 3 million pounds, valued at $25. 9 million, in 1963.

TABLE 14A. Flavor and perfume materials: U.S. production and sales , 1964

[Listed beloi? are all synthetic organic flavor and perfume materials for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be piib- lished or where no data were reported.) Table 14-B in pt. Ill lists alphabetically all flavor and perfume materials for which data on production or sales were reported and identifies the manufacturer of each]

Quantity

Unit value^

Grand total

FLAVOR AND PERFUME MATERIAI5, CYCLIC Total

Benzenoid and Naphthalenoid Total -

■i-Allylveratrole (Eagenyl methyl ether)

Anethole (p-Propenylanlsole)

p-Anlsaldehyde (p-Methoxybenzaldehyde)

Benzophenone^

Benzyl acetate

Benzyl alcohol^

Benzyl cinnamate

Benzyl ether

Benzyl propionate

Benzyl salicylate

Cinnamaldehyde

Clnnamyl alcohol

a,oi-Dimethylphenethyl acetate

Eogenol

Isobutyl phenylacetate (Isobutyl a-toluate)

Isobutyl salicylate

Isoeugenol

See footnotes at end of table.

1,000 pounds

90,570

80,037

1,000 dollars

83,73A

Per pound

$1.05

'^9,563

41,235

56,571

21,054

20, U7

24,547

1.22

18

1,576

699

264

1,116

3,373

3

103

13

222

804

209

26

274

19

46

95

11

1,438

766

278

1,202

2,970

4

102

12

203

605

153

34

1,102

1,105

252

506

1,159

13

19

13

272

411

213

100

534

19

45

267

2.97

.76

1.44

.91

.42

.39

3.57

.19

1.14

1.34

.68

1.39

4.56

2.02

.90

1.01

2.88

See also table 14B, pt. Ill, which lists these products alphabetically and Identifies the manufacturers, and table 23 in appendix A, which

shows imports of benzenoid flavor and perfume materials during the years 1963-64.

FLAVOR AND PERFUME MATERIALS TABLE lAA. Flavor and perfume materials: U.S. production and sales , 1964 --Continued

37

FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued

Bemenoid and JVopht/iaieno id- -Continued

Isopentyl salicylate (Amyl salicylate)

"4 ' -Methoxyacetophenone

Methyl anthranilate

a-Wethylcinnamaldehyde

Methyl salicylate (gynthetio wlntergreen oil)

a-Pentyloinnamaldehyde (a -, Amylcinnamaldehyde )

Phenethyl isotutyrate

Phenethyl phenylacetate (Phenethyl a-toluate)

3- Phenyl- 1-propanol (Kbrdrocinnajiiie alcohol)

4-Propenylveratrole (Isoeugenyl methyl ether)

All other benzenoid and naphthalenoid materials

Terpenoid, Heterocyclic, and Alicyclic

Total

Cedryl acetate

Citral (Geranlal)

Citronellol

Citronellyl acetate

Cltronellyl formate

Coumarin

Essential oils, chemically modified

Geraniol

Geranyl acetate

Geranyl formate

Hydrocoumarin (3,4- Dihydrocoumarin)

H^roxycitronellal

lonones

Isobomyl acetate

linalyl acetate

Msnthol, synthetic, tech. and U.S.P

Msnthone

Methylionones , total

a,p, Y, find 6, individually

a and P , mixed

Nerol

Piperonal (Heliotropin)

Rhodinol

Sweeteners, synthetic

Terpineols

Terpinyl acetate

Vetivenyl acetate

All other terpenoid, heterocyclic, and alicyclic materials

FLAVOR AND PERFUME MATERIAI£, ACYCLIC

Total

Allyl hexanoate (Allyl oaproate)

Decanal ( Capraldehyde ) (Cio)

Ethyl butyrate

Ethyl hexanoate (Ethyl oaproate)

Ethyl nonanoate (Ethyl pelargonate)

Glutamic acid, monosodium salt (Itonosodlum glutamate)

4-I^roxyundecanoic acid, Y-lactone (Y-Undeoalactone)

Isopentyl butyrate (knyl butyrate)

Laiiraldehyde (Dodecyl aldehyde) (Cia)

All other acyclic materials

410

412

14

3,784

433

7,103

28,509

112

218

675

31

20

1,030

118

845

78

10

26

556

206

1,373

659

289

Quantity

363 113

210

10

12,215

3,532

641

19

5,160

41,007

46 13 310 3 3 38,632 5 57

1,938

1,000 pounds

3,738 4A4

7,224

21,088

107

63

448

23

20

1,000

117

557

68

9

23

538

161

1,330

407

280

7

444

1,000 dollars

355 89

252

11

8,658

3,607

677

18

2,256

38,802

47

13

237

36,630

4

47

18

1,804

263

18

258

2,006

610

15

29 15,222

32,024

229

248

821

42

60

2,464

160

852

123

25

96

2,469

645

528

1,286

983

17

1,929

Unit value-"-

1,496 433

40

506

293

9,721

901

317

1,007

6,262

27,163

174

50

165

3

4

24,843

24

37

105

1,758

^ Calo\ila-ted from the unrounded figures. ^ Includes some technical grade.

38

SYNTHETIC ORGANIC CHEMICALS, 1964 Plastics and Resin Materials

Plastics and resin materials are condensation or polymerization products of organic chem- icals containing necessary fillers, plasticizers, and extenders. At some stage in their manufac- ture they exist in such physical condition that they can be shaped or processed by the application of heat and pressure. Some types of plastics may be molded, cast, or extruded into finished or semifinished forms. Other types are used as adhesives, for the treatment of textiles and paper, and for protective coatings. Still other types of plastics materials may be processed into sheets, rods, and tubes, which are further manufactured into finished articles. Except for vinyl resins, the statistics given in the following tables are based on the total weight of the materials, exclud- ing liquids. Statistics for vinyl resins are given on the basis of resin content.

Statistics on production and sales of plastics and resins in 1964 are given in table 15A' ac- cording to chemical composition and broad end uses. In general, this table follows the outline of the Tariff Commission's monthly report on the production and sales of synthetic plastics and resin materials (S. O. C. Series P-64). However, data are included for plastics materials which are not covered in the monthly report and for a number of smaller producers that do not report

TABLE 15A. --Plastics and resin materials: U.S. production and sales, by chemical classes

and uses, 1964

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all plastics and resin materials for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 15B in pt. Ill lists all plastics and resin materials for ,which data on production or sales were reported and identifies the manufacturer of each]

Kind and use

Sales

Quantity

Unit value

Grand total-

1,000 pounds, dry basis ^

10,103,06<i

1,000 pounds, 8,726,721

1.000 dollars

2,120,28-;

Plastics and resin materials, benzenoid

Plastics and resin materials, nonbenzenoid-

THERMOSETTING RESINS

Total-

3,915,046 6,188,018

2,954,795

3,256,105 5,470,616

2,343,943

777,342 1,342,942

618,213

Alkyd resins, total

Protective coatings :

Phthalic anhydride type, total- Unmodified

Modified

Polybasic acid type

All other uses^

Sales for export

593,627

309,696

80,621

Coumarone-indene and petroleum polymer resins, total- Floor tile

Rubber compounding

All other uses

Sales for export

Epoxy resins :

Unmodified, total

Bonding and adhesives

Protective coatings

Reinforced plastics

All other uses

Sales for export

Itidified

524,942

387,520

137,422

55,716

12,969

354,349

Polyester resins,* total

Reinforced plastics :

Sheets, flat and corrugated- All other

Surface coatings

All other uses

Sales for export

Silicone resins

91,556

57,431 205,362

96,204

8,941 316,628

254,618

194,959

59,659

43,597

7,905

3,576

328,311

66,949

49,300

17,649

9,417

2,686

1,569

33,269

80,031

55,615

165,071

27,594

95,923 12,569 42,328 13,322 16,109 11,595 4,936

276,282

3,278 84,556

10,981

33,231 168,670

2,377 62,314

9,690

10,051

22,963

See footnotes at end of table.

^ See also table 15B, pt. III, which lists these products according to chemical composition, and identifies the manufacturers.

PLASTICS AND RESIN MATERIALS

TABLE 15A.-- Plastics and resin materials.- U.S. production and sales, by chemical classes and uses, 2 964 --Continued

39

Kind and use

Production

Quantity

Unit value"''

THERmSETTING RESINS— Continued

Phenolic and other tar acid resins, total

Molding materials

Bonding and adhesive resins for

Laminating

Coated and bonded abrasives

Friction materials

Thermal insulation

Foundry or shell molding

Plywood

Fibrous and granulated wood

All other bonding and adhesive uses

Protective coatings, immodifled and modified

All other uses

Sales for export

Polyurethane and diisooyanate resins

Rosin modifications, total

Rosin and rosin esters, unmodified (ester gums) All other

Urea and melamine resins, total

Textile treating and coating resins

Paper treating and coating resins

Bonding and adhesive resins for

Laminating

Plywood

Fibrous and granulated wood

All other bonding and adhesive uses

Protective coatings

All other uses (including molding)

Sales for export

All other thermosetting resins*

THERMDPLASTIC RESINS

Total -

Cellulose plastics materials, total

Sheets, continuous:

Under 0.003 gage

0.003 gage and over

All other sheets, rods, and tubes

Jtolding and extrusion materials

Polyamide resins''

Styrene type plastics materials :

Production and sales

Used by reporting companies in processing

Sales and use, total

Jfclding

Textile and paper treating and coating

Bmilsion paint

Extrusion

All other uses

Sales for export

Vinyl resins (resin content basis): Polyvinyl acetate resins:

Production and sales

Used by reporting oon^ianies in processing

Sales and use, total

Smilsion paint

See footnotes at end of table.

1,000 pounds,

832, 5.40

247,326

113, S-W 21,701 31,584

107,141 53,799 99,073 28,546 40,469 32,271 56,786

35,634 119,492

74,284 45,208

570,274

56,107 48,355

57,605 116,607 84,665 17,820 56,882 132,233

16,125

7,148,269

161,281

17,927

39,692

4,609

99,053

75,597

1,727,864

282,307

1,000 pounds , dry basis^ 685 , 169

1,000 dollars 166,002

Per

pound

225,351

66,612 18,038 29,376 47,992 53,551 89,683 27,806 36,591 23,427 50,436 16,306

31,066

71,437 43,556

473,827

18,100 22,521

13,401 9,120

49,079 33,801

37,683 100,407 72,267 16,068 35,735 111,238 17,549

13,689

6,382,778

5,140

1,502,071

156,991

17,739

38,207

6,222

94,823

58,408

1,559,534 128,265

1,687,799 843,117 128,698 39,704 229,585 282,399 164,296

228,233 51,416

279,649 96,760

107,170

54,115 333,927

66,497

40 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 15 A. --Plastics and resin materials: U.S. production and sales , by chemical classes and uses, 1964 Continued

Kind and use

- Continued

THERMOPLASTIC RESINS--Continued

Vinyl resins (resin content basis) Continued Polyvinyl acetate resins Continued

Used by reporting companies in processing Sales and use--Continued

Adhesives

Bonding and sizing

All other uses

Sales for export

Polyvinyl chloride and copolymer resins :

Production and sales

Used by reporting companies in processing

Sales and use, total

Calendering :

Film, under 6 mils

Sheet, 6 mils and over

Flooring

Coating, bonding, and adhesives :

Paper and textile coating (including calendering

Flooring

Extrusion:

Wire and cable

Garden hose

All other extrusions

Molding :

Records

Sliish and rotational molding

All other moldings

All other uses

Sales for export

All other vinyl resins :

Production and sales

Used by reporting companies in processing

Sales and use, total

Polyolef in plastics materials :

Polyethylene, density C.g-iO and below:

Production and sales

Used by reporting companies in processing

Sales and use, total

Injection molding

Blow molding

Extrusions :

Film and sheet

Wire and cable coating

Extrusion coating on paper and other substrates- Pipe

All other extrusions

All other uses

Sales for export

Polyethylene, density over C.g^VO:

Production and sales

Used by reporting companies in processing

Sales and use, total

Injection molding

Blow molding

Extrusions :

Film and sheet

Wire and cable coating

Pipe

All other extrusions (including extrusion coating

and filament)

All other uses

Sales for export

1,636,891

Quantity

147,629

1,955,095

658,320

dry

basis'

100,868

17,927

60,505

3,589

1,373,740

273,569

1,647,309

79,449 248,993 243,657

155,773 62,972

195, 4S5

13,806

190,095

74,703 39,185 24,293 249,026 69,872

96,836 44,427 141,263

1,930,267 170,387

2,100,654

257,436

38,585

745,365 194,317 255,288 25,172 14,541 198,867 371,083

550,472 55,449 605,921 100,144 238,870

24,959 20,294 21,417

21,524 114,890 63,823

1.000 dollars

240,056

Unit value

pound

60,857

320,752

113,948

See footnotes at end of table.

PLASTICS AND RESIN MATERIALS

TABLE 15A.— Plastics and resin materials.- U.S. production and sales, by chemical classes and uses, 7554 --Continued

Kind and use

Quantity

Unit value-"-

THERMDPLASTIC RESINS--Continued

Polyolefin plastics materials Continued Polypropylene :

Production and sales

Used by reporting companies in processing- Sales and use, total

Molding

Extrusion

All other uses (including export)

All other thermoplastic resins'"-'^

dry ba

dry

270, 176

233,109

unds.

1,000

basis'

dollars

225,712

5^,823

35,156

260,868

108, "iSS

113,5^3

38,870

202,585

1-49,926

pourid

.74

■"- Calculated from rounded figures.

^ For the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents. ^ Includes saturated polyesters for urethanes.

* The term "polyester resins" includes unsaturated aliyds oopolymerized with a monomer such as styrene, and polyallyl resins such as diallyl phthalate and allyl diglycol carbonate.

' Includes 418,314 thousand pounds of urea- formaldehyde type, and 151,960 thousand pounds of melamine-formalde- hyde type.

^ Includes data for acetone-formaldehyde resins, styrene-alkyd polyesters, toluenesulfonamide resins, and other thermosetting resins, which were produced in small quantities.

'' Includes both nylon and non-nylon types.

* Includes straight polystyrene, 592,151 thousand pounds; rubber modified polystyrene, 683,850 thousand pounds; styrene-butadiene copolymers, 188,161 thousand pounds; and all other, including ABS and SAN, 263,702 thousand pounds .

' Includes 32,382 thousand pounds of polyvinyl alcohol.

■'-° Includes data for acrylic, fluorocarbon, polycarbonate, polyoxymethylene, polyterpene, and other thermoplastic resins.

monthly. The monthly data for 1964, moreover, -were returned to the reporting companies for verification or correction. In consequence, many of the figures in the following table are revised from those sho-wn in the monthly release of March 23, 1965, which contained yearend cumulative totals for 1964. The figures in the thermoplastics section of the table under "Used by reporting companies in processing" represent captive use of the materials. The quantities reported under "Sales and use" in this section include data for captive consumption, and for outside sales as defined in the introduction to this volume.

In 1964, total U.S. production of synthetic plastics and resin materials, including cellu- losics, amounted to 10, 103 million pounds, or 12. 6 percent more than the 8, 968 million pounds reported for 1963. Sales of synthetic plastics and resin materials in 1964 amounted to 8, 727 mil- lion pounds, valued at $2, 120 million. Production of benzenoid plastics and resin materials in 1964 amounted to 3, 915 million pounds, and that of nonbenzenoid materials, to 6, 188 million pounds. These figures connpare with production in 1963 of 3, 489 million pounds, and 5, 479 mil- lion pounds, respectively. Production of all thermosetting resins in 1964 was 2, 955 million pounds, and that of thermoplastic resins was 7, 148 million pounds.

In 1964, polyethylene, polystyrene, and polyvinyl chloride resins were the materials pro- duced in the largest volume. The total output of high-density and low-density polyethylene resins in 1964 amounted to 2, 613 million pounds, compared with 2, 270 nmillion pounds in 1963. Sales of polyethylene resins in 1964 were 2,481 million pounds, valued at $435 million. Production of styrene type plastics materials in 1964 was 1, 728 million pounds, compared with 1, 494 million pounds in 1963. Sales of such materials in 1964 were 1, 560 million pounds, valued at $334 mil- lion. The output of polyvinyl chloride and copolymer resins in 1964 amounted to 1, 637 million pounds, compared with 1, 386 million pounds in 1963. Sales of polyvinyl chloride resins in 1964 totaled 1, 374 million pounds, valued at $240 million. Other synthetic plastics and resin materials produced in 1964 in large volume were phenolic and other tar acid resins (833 million pounds), alkyd resins (594 million pounds), urea and melamine resins (570 million pounds), coumarone- indene and petroleum polymer resins (354 million pounds), polyester resins (317 million pounds), and polyvinyl acetate resins (282 million pounds).

42

SYNTHETIC ORGANIC CHEMICALS, '964 Rubber-Processing Chemicals

Rubber-processing chemicals are organic compounds that are added to natural and synthetic rubbers to give them qualities necessary for their conversion into finished rubber goods. In this report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, antioxidants, and peptizers. Statistics on production and sales of rubber-processing chemicals in 1964 are given in table 16A.^

Production of rubber-processing chemicals as a group in 1964 amounted to 261 million pounds, or 11.5 percent more than the 234 million pounds reported for 1963. The larger total output of rubber-processing chemicals in 1964 is attributable principally to increased produc- tion of antioxidants and thiazole accelerators. Sales of rubber-processing chemicals in 1964 amounted to 184 million pounds, valued at $123 million, compared with 177 naillion pounds, valued at $119 million, in 1963.

TABLE 16A. Rubber-processing chemicals: U.S. production and sales , 1964

[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- lished. (Leaders are used where the reported data are accepted in confidence and may not be published "or where no data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on production or sales were reported and identifies the manufacturer of each]

Quantity

Unit value ^

Grand total

RUBBER- PROCESSING CHBJICAIS, CYCLIC

Total -

Accelerators, total

Aldehyde-amines

Dithiooarbamic acid derivatives

Thiazole derivatives, total

N-Cyolohexyl-2-benzothlazolesulfenamide--

2,2'-Dithlobis{benzothiazole)

2-Mercaptobenzothiazole

All other^

All other accelerators

Amino and hydroxy compounds, total-'

Amino compounds, total

N, N'-Diphenyl-p-phenylenediamine

All other

Itydroxy compounds, total

Phenol, alkylated

All other

N-Nitrosodiphenylamine -—

Peptizers

All other cyclic rubber-processing chemicals*

RUBBER- PROCESSING CHEMICALS, ACYCLIC

Total

Accelerators, total

Dithiooarbamic acid derivatives, total^

Wbutyldithiooarbamlo acid, sodium salt

Dibutyldithiocarbamic acid, zinc salt

Diethyldithiocarbamic acid, zinc salt

Dimethyldithiocarbamic acid, potassium salt-

Dimethyldithiocarbamic acid, sodium salt

Dimethyldithiocarbamic acid, zinc salt

All other

pounds 260,556

222,4.61

87,295

1,983

270

75,015

10,100

21,045

7,972 35,898 10,027

105,357

85,406 1,609

83,797

19,951 9,312

10,639

3,089

5,003

21,717

38,095

25,255

13,003 974

1,424

1,058 298

6,618 955

1,676

184,227

53,317

1,382

204

42,220

5,652 10,316

5,018 21,234

9,511

82,382

67,950 1,587 66,363 14,432 4,904 9,528

2,164 4,631 19,166

22,567

13,431

7,277

1,119 704

'2,484

903

2,067

123,027

108,656

31,493

1,463 333

22,222 3,564 5,247 1,937

11,474 7,475

59,984

46,707 1,406

45,301

13,277 2,623

10,654

1,173 3,101 12,905

14,371

10,369

5,802

1,249 570

947

757

2,279

.67

.59 1.06 1.63 .53 .63 .51 .39 .54

.73 .69

.92 .53 L.12

.64-

.77

1.12 .81

.38

.84

1.10

See footnotes at end of table.

'See also table 16B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

ELASTOMERS (SYNTHETIC RUBBERS) TABLE 16A. Rubber-processing chemicals: U.S. production and sales, 1964 Continued

43

Production

ijiantity

Unit value ■"■

RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued

Accelerators Continued

Thiurams, total^

Bis (dime thy lthiocartiainoyl)disulfide

Bis(dimethylthlocarbaiiioyl)sulfide

All other

All other accelerators

1,000 pounds

1,000 pounds

pound

Dodeoyl mercaptans

All other acyclic rubber-processing chemicals''

11,896

11,896 356

10,2^9 2,591

5,934

4,132

1,071

731

220

8,129 1,007

4,337

2,651

1,141

545

230

3,489 513

1.07

.75

1.05

""" Calculated from rounded figures.

^ Includes small quantities produced and sold for uses other than rubber processing.

^ Data on production and sales of aldehyde and acetone amine antioxidants are included below in "All other cyclic rubber-processing chemicals . "

* Includes aldehyde and acetone amines, blowing agents, inhibitors, modifiers, stabilizers, and taekifiers.

^ Data on dithiocarbamates Included in this table are for materials used chiefly in the processing of natural and synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are reported in table 20A "Pesti- cides and Other Organic Agricultural Chemicals."

^ Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural and synthetic rubbers.

' Includes blowing agents, peptizers, modifiers, and conditioning and lubricating agents.

The output of cyclic rubber-processing chemicals in 1964 amounted to 222 million pounds, or 11. 6 percent more than the 199 million pounds reported for 1963. Sales in 1964 were 162 million pounds, valued at $109 million, compared with 153 million pounds, valued at $102 million, in 1963. Of the total output of cyclic rubber-processing chemicals in 1964, accelerators accounted for 39.2 percent and amino and hydroxy antioxidants, for 47. 4 percent. Production of amino and hydroxy antioxidants, which amounted to 105.4 million pounds in 1964, included 85.4 million pounds of amino compounds and 20. 0 nnillion pounds of hydroxy compounds. In 1963 the output of amino antioxidants amounted to 79. 2 million pounds and that of hydroxy antioxidants, to 17. 0 million pounds. Sales of amino antioxidants in 1964 were 68. 0 million pounds, valued at $46. 7 million; sales of hydroxy antioxidants were 14.4 million pounds, valued at $13. 3 million.

Production of acyclic rubber-processing chemicals in 1964 amounted to 38. 1 million pounds, compared with the 34. 4 million pounds reported for 1963. Sales in 1964 totaled 22. 6 million pounds, valued at $14. 4 million, compared with 24. 4 million pounds, valued at $16. 9 million, in

1963. Accelerators, principally dithiocarbamic acid derivatives and tetramethylthiuram sulfides, accounted for 66. 3 percent of the output of acyclic rubber-processing chemicals in 1964. Dodecyl mercaptans, together with blowing agents, peptizers, modifiers, and lubricating and conditioning agents, accounted for the remainder of the output in the acyclic group.

Elastomers (Synthetic Rubbers)

The synthetic rubber industry in the United States continued to operate at a high level of capacity in 1964. The styrene-butadiene, or S-type, rubber is a general- purpose material used in the manufacture of tires and other rubber goods, and is the most important type of synthetic rubber, in terms of quantity produced. Several other types of synthetic rubbers are also pro- duced in large volume; among them are the polybutadiene-acrylonitrile type, or N-type, the polybutadiene-isoprene type, or Butyl-type, neoprene, and stereo elastomers.

The total output of all types of elastomers in the United States in 1964 amounted to 3,421 million pounds-- somewhat more than the 3, 185 million pounds reported for 1963. Sales of elastomers covered in this report amounted to 2, 958 million pounds, valued at $810 million, in

1964, compared with 2, 836 million pounds, valued at $767 million, in 1963. Statistics on the production and sales of elastomers are given in table 17 A. 5

See also table 173, pt. ni, which lists these products alphabetically and identifies the manufacturers.

SYNTHETIC ORGANIC CHEMICALS, 1964

polyurethane type elastomers in 1964 amounted to 7. 3 nnillion pounds.

TABLE 17A. --Elastomers (synthetic rubbers):'' U.S. production and sales, 1964

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 17B in pt. Ill lists alphabetically all elastomers for which data on production or sales were reported and identifies the manufacturer of each]

Quantity

Unit value^

Grand total

ELASTOMERS, CYCLIC Total

Polybutadiene-styrene type (S-type)

Polybutadiene-styrene-vinylpyridine type- Polyurethane type

ELASTOMERS, ACYCLIC

Total

Polybutadiene-acrylonitrile type (N-type)

Polychloroprene type (Neoprene)

Poljrisobutylene-isoprene type (Butyl)

Silicone elastomers

Stereo elastomers

All other acyclic elastomers^

Sj^i^ais

1,000 pounds^ 2,957,58^

1,000 dollars 809, 902

2,332,436

1,961,181

450,913

2,306,065 19,075 7,296

1,088,782

1,944,595 10,520 6,066

996,403

437, 616 6,868 6,429

358,989

117,443 316,040 221,558 8,276 364,826 60,639

102,439

6,286 285,230 602,448

49,161

23,714

65,430

220,684

.23

.36 .48

3.77 .23 .37

"'" The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original length and, after having been so stretched and the stress removed, will return with force to approximately their original length.

^ Calculated from rounded figures.

^ Elastomer-content basis.

* Partly estimated.

' Includes data for the production and sales of polyalkalene sulfide, and polylsobutylene elastomers, and natiiral rubber modifications; and for sales of neoprene and Butyl elastomers.

Note. Statistics on the production of S-type, N-type, Butyl, neoprene, and stereo elastomers were compiled in cooperation with the U.S. Bureau of the Census.

The output of acyclic elastomers, including N-type, neoprene, Butyl, silicone, and stereo elastomers, amounted to 1,089 million pounds in 1964, compared with the 1,011 million pounds reported for 1963. Sales of these elastomers amounted to 996 million pounds, valued at $359 million, in 1964, compared with 911 million pounds, valued at $332 million, in 1963. The out- put of silicone elastomers in 1964 amounted to 8. 3 million pounds, and that of stereo elas- tomers, to 365 million pounds.

Plasticizers

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials to (1) improve workability during fabrication, (2) extend or modify the natural properties of these resins, or (3) develop new improved properties not present in the original resins. Plasticizers reduce the viscosity of the resins and make it easier to shape and form them at high tempera- tures and pressures. They also impart flexibility and other desirable properties to the finished product. Statistics on production and sales of plasticizers are given in table 18A."''°

^^ See also table 18B, pt. III, which lists these products alphabetically and identifies the manufacturers.

PIASTICIZERS 45

TABLE 18A. --Plasticizers:^ U.S. production and sales. 1964

[Listed below are all plastloizers for which reported data may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 18B in pt. Ill lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of each]

Quantity

Grand total

PLASTICIZERS, CYCLIC

Total—

Phosphoric acid esters :

Cresyl diphenyl phosphate^

Tricresyl phosphate-'

Triphenyl phosphate

Phthalic anhydride esters, total

Butyl octyl phthalate

Di butyl phthalate

Dicyolohexyl phthalate

Diethyl phthalate

Dihexyl phthalate

Diisodecyl phthalate

Di(2-methoxyethyl) phthalate

Dimethyl phthalate

Diootyl phthalates, total

Di(2-ethylhexyl) phthalate

Diiso-octyl and mixed dioctyl phthalates

Ditridecyl phthalate

Octyl deoyl phthalates

All other phthalic anhydride esters

Trimellitic acid esters

All other cyclic plasticizers'^

PLASTICIZERS, ACYCLIC'

Total

Adipic acid esters, total

Di(2-(2-butoxyethoxy) ethyl) adipate

Di(2-ethylhexyl) adipate

Diisobutyl adipate

Diisodecyl adipate

Diiso-octyl adipate

Octyl decyl adipate

All other

Azelaic acid esters

Complex linear polyesters and polymeric plasticizers

Epoxidized esters, total

Epoxidized soya oils

Octyl epoxy tallates

All other

Glycerol monoricinoleate

Isopropyl myristate

Isopropyl palmltate

1,000 pounds 951,408

717,624

16,061

32,419

8,982

601,403

12,422

18,228

6,730

15,058

713

77,963

8,939

4,253

323,619

188,761

134,858

11,528

21,475

100,475

1,140 57,619

233,784

36,143

957 6,053

730

8,051

5,862

10,280

4,210

13,359 43,272

58,020

38,455

17,007 2,558

423 2,682 1,316

1.000 pounds 904,887

1.000 dollars 187,468

689,647

119,565

L3,855

30,123

1,970

16,595 14,902

9,975

776

73,521

5,964

3,978

326,626

196,105

130,521

11,072

24,185

102,512

1,335 52,258

215,240

33,040

913 6,117

786 6,974

10,156 8,094

12,972 40,626

62,993

43,522 16,833 2,638

170 2,598 1,377

3,488

8,027

708

91,775

2,365 2,889

1,936

143

10,934

1,143

841

45,907

27,847

18,060

2,387

4,164 19,066

579 14,988

67,903

8,527

360 1,494

244 2,067

2,700 1,662

3,966 16,316

15,346

10,265 4,004 1,077

904 448

See footnotes at end of table.

46 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 18A. --Plasticizers-' U.S. production and sales, i 964 --Continued

Chemical

Production

Quantity

Unit value ^

PLASTICIZERS, ACYCLIC— Continued

Oleic acid esters, total

Butyl oleate

Glycerol trioleate (Triolein)

Isopropyl oleate

tethyl oleate

n-Propyl oleate

All other

1,000

1,000 8,046

1,000 dollars

1,947

Phosphoric acid esters

Sebacic acid esters:

Dibutyl sebacate

Di(2-ethylhex3rl) sebaoate-

Stearic acid esters, total-

n-Butyl stearate

All other

2,769 3,767

281 1,708

801 2,121

11,731

4,521 7,547

7,399

1,792 2,506

633

3,115

8,211

2,759 7,703

6,957

All other acyclic plasticizers"

3,019 4,380

35,924

2,823

4,134

27,788

~3ST 521

116

927

1,693 4,034

1,718

1,038 9,703

■'■ Does not include data for clearly defined extenders or secondary plasticizers.

^ Calculated from rounded figures.

^ Includes material produced for use as motor-fuel additive.

* Includes data for toluenesulfonamides, tetrahydrofurfuryl oleate, and other cyclic plasticizers. ' Dibutyl maleate is now published in table 22A, "Miscellaneous Chemicals."

* Includes data for citric and aoetylcitric, lauric, myristic, palmitic, ricinoleic, sebacic, and tartaric acid esters, glycerol and glycol esters of certain fatty acids, glycerol tri propionate, and other acyclic plasticizers.

Total U.S. production of plasticizers in 1964 amounted to 951 million pounds-- representing an increase of 14.0 percent over the output of 835 million pounds reported for 1963. Sales in 1964 of the plasticizers covered by this report amounted to 905 million pounds, valued at $187 million, compared with 750 million pounds, valued at $168 million, in 1963.

Production of cyclic plasticizers in 1964, which consisted chiefly of the esters of phthalic anhydride and phosphoric acid, amounted to 718 million pounds, compared with 622 million pounds in 1963. Sales of cyclic plasticizers in 1964 amounted to 690 million pounds, valued at $120 million, compared with 558 million pounds, valued at $103 million, in the previous year.

Production of acyclic plasticizers in 1964 amounted to 234 million pounds, compared with 213 million pounds in 1963. Sales of acyclic plasticizers in 1964 amounted to 215 million pounds, valued at $68 million, compared with 192 million pounds, valued at $65 million, in 1963. Pro- duction of complex linear polyesters in 1964 amounted to 43 million pounds, and that of epoxi- dized esters, to 58 million pounds. Other products included in the acyclic class are the esters of adipic, azelaic, oleic, sebacic, and stearic acids.

Surface-Active Agents

The surface-active agents covered in this report include synthetic organic detergents and wetting, emulsifying, and dispersing agents that function in either aqueous or nonaqueous sys- tems. Soaps, waxes, and plasticizers are not included. The data are reported in terms of 100- percent organic, surface-active ingredients, and thus exclude all inorganic salts, water, and other diluents. Originally developed as soap substitutes for the textile industry, surface-active agents have proved valuable in many other applications. A major part of the output of surface- active agents is consumed in the form of packaged household and industrial detergents. The rennainder is used as wetting, dispersing, penetrating, and emulsifying agents in the processing of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of paints, agricultural sprays, lubricants, cosmetics, foods, pharmaceuticals, and many other products.

Statistics on U.S. production and sales of surface- active agents in 1964 are given in table igA.-"-^ Total production of surface-active agents in 1964 amounted to 2, 119 million pounds--?. 0 percent more than the 1, 981 million pounds produced in 1963, and 8. 7 percent more than the 1, 949 million pounds produced in 1962. Sales in 1964 totaled 1, 900 million pounds, valued at

11 See also table 19B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

SURFACE-ACTIVE AGENTS

47

$350 million, compared with 1,790 million pounds, valued at $325 million, in 1963, and 1,758 million pounds, valued at $317 million, in 1962. Sales in 1964 were thus 6.2 percent larger than in 1963 and 8. 0 percent larger than in 1962 in terms of quantity, and 7. 7 percent larger than in 1963 and 10. 4 percent larger than in 1962 in terms of value.

Production of anionic materials in 1964 amounted to 1,434 million pounds, or 67. 7 percent of total production; sales of anionic materials were 1, 365 million pounds, valued at $196 mil- lion. Production of those surface- active agents which are generally considered nonionic amounted to 581 million pounds, or 27.4 percent of the total; sales were 434 million pounds, valued at $108 million. Production of cationic materials amounted to 98 million pounds, or 4. 6 percent of the total; sales totaled 96 million pounds, valued at $43 million. Production of amphoteric mate- rials amounted to 4, 6 million pounds, or approximately 0. 2 percent of the total; sales totaled 4. 5 million pounds, valued at $2. 8 million.

TABLE 19 A.— Surface -active agents: U.S. production and sales, 1964

[Listed below are all surface-active agents for which reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were reported and identifies the manufacturer of each]

Production'''

Quantity-''

Unit value ^

Grand total

Amphoteric

Anionic

Cationic

Nonionic

BENZENOID SURFACE-ACTIVE AGENTS

Total

Not Sulfated or Sulfonated

Total

Amides, amines, and quaternary ammonium salts, total

Benzyl( coconut oil alkyl)dimethylammonium chloride

Benzyldimethyl(mixed aliyl) ammonium chloride

Benzyldimethylootadeoylammonivun chloride

Benzyldodecyldimethylammonium chloride

(3,4— Dichlorobenzyl)dodeoyldimethylammonlum chloride

(Dodecylbenzyl)trimethylammonium chloride

Heterocyclic compounds

Oxygen- containing' compounds

All other

Carboxylic acid esters and ethers, total

Dodecylphenol, ethoxylated

Iso-octylphenol, ethoxylated

Nonylphenol, ethoxylated

Phenol, ethoxylated

Other carboxylic acid esters and ethers

Phosphoric and polyphosphoric acid esters and salts, 'to'tal

Nonyl and dinonylphenol, ethoxylated and phosphated

All ether

Sulfated and Sulfonated Total

Alkylphenols, ethoxylated and sulfated, total

Nonylphenol, ethoxylated and sulfated

All other

See footnotes at end of table.

2,118,688

<i,562

1,434,399

98,348

581,379

1,347,809

273,786

8,018

3,548 309 789 31 158 696 706

1,723

263,545

52,483

1,676

132,778

4,027

72,581

2,223

2,045 178

1,074,023

40,579

20,213 20,366

1,899,930

4,536

1,365,424

95,518

434,452

1,245,176

209,146

7,602

56

3,468

286

747

30

149

475

694

1,697

199,570

22,680

114,822

2,774

59,294

1,974

1,799 175

1,036,030

20,079

i,000 dollars

350,142

2,755 196,092 43,228 108,067

165,132

46,006

7,217

47 3,166 260 651 37 113 563 923 1,457

38,062

6,394

18, 198

620

12,850

662 65

119,126

4,253

pound

.61 .14 .45 .25

.22

.95

.84

.91

.91

.87

1.23

.76

1.19

1.33

.86

.19 .28

.16 .22 .22

.37 .37 .37

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 19A.--Surface-active agents: U.S. production and sales , i564--Continued

Production^

Sales

Quantity^

BENZENOID SURFACE-ACTIVE AGENTS- -Continued Sulfated and Sulfonated Continued

Benzenesulfonates, total

Benzene-, toluene-, and xylenesulfonates :

Toluenesulfonio acid, sodium salt

}fylenesulfonio acid, anmonium salt

i^lene sulfonic acid, potassium salt

^lenesulfonic acid, sodium salt

Branched chain dodeeyl- and tridecylbenzenesulfonates,

total

Dodecylhenzenesulfonic acid--

Dodecylbenzenesulfonlo acid, ammonium salt

Dodecylbenzenesulfonic acid, calcium salt

Dodecylbenzenesulfonic acid, diethanolamine salt

Dodecylbenzenesulfonic acid, isopropylamine salt

Dodecylbenzenesulfonic acid, (mixed alkyl) -amine salt-

Dodecylbenzenesulfonlc acid, sodium salt

Dodecylbenzenesulfonic aoid, triethanolamine salt

Tridecylbenzenesulfonic acid, sodium salt

All other

Straight chain dodeeyl- and tridecylbenzenesulfonates :

Dodecylbenzenesulfonic acid

Dodecylbenzenesulfonic aoid, sodium salt

Dodecylbenzenesulfonic aoid, triethanolamine salt

All other benzenesulfonates-'

lignosulfonates, total

lignosulfonio acid, calcium salt

All other

Naphthalenesulfonates, total

Diisopropylnaphthalenesulfonio aoid

Isopropylnaphthalenesulfonio aoid

All other

Other benzenoid surface -active agents, sulfated and

sulfonated

NONEENZENOID SURFACE-ACTIVE AGENTS

Total

Not Sulfated or Sulfonated

Total

Amides, amines, and quaternary ammonium salts, total

Acyclic quaternary ammonium salts, total

Bis(hydrogenated tallow alkyl) dimethylaramonium

chloride

Hexadeoyltrimethylammonium salts

All other

Amine acetates, total

( i^drogenated tallow aliyl) amine acetate

All other

Amine salts, anionic, total

Oleic acid, triethanolamine salt

All other

Amines, alkoxylated, total

(Mixed alkyl)amine, ethoxylated

(Tallow alkyl)amine, ethoxylated

All other

Fatty acid - alianolamine condensates, total

Diethanolamine condensates, total

Castor oil acids - diethanolamine condensate

1,000 pounds 590, 670

9,253 I8,<i59

1,4.98 23,612

445,453

61,219

8,177

9,932

184

3,907

388

320,020

3,204

30,911

7,511

3,834

48,886

127

39,548

426,788

325,574 101,214

9,634

333

427

8,874

6,352

770,879

461, 149

162,816

17,610

13,223

410

3,977

1,585

444

1,141

694

74

620

11, 852

2,383

691

8,778

71,293

54,499

1,000 pounds 575, 756

9,209 18,549

20,970

436,787 59,844

5,501

187

3,611

349

324,658

3,176

27, 884

11,577

1,213 49,079

39,949

412,943

311,843 101, 100

5,521

223 5,298

* 21,731

366,605

156,104

20,048

15,798

434

3,816

1,865

1,865

559

17

542

11,421

2,157

658

8,606

67,340

51,102

12

1,000 dollars 90,497

721 1,441

2,042

73,655 14,295

1,719

72

1,122

102

47,867

939

5,278

2,261

267 5,517

6,854

14,762

10,130 4,632

2,289

120 2,169

* 7,325

185,010

120, 802

61,992

6,746

3,909 440

2,397 587

587

344

8

336

4,925

982

550

3,393

19,846

15,366

7

See footnotes at end of table.

SURFACE-ACTIVE AGENTS TABLE \QA.- -Surface -active agents: U.S. production and sales , i 964 --Continued

49

Production"""

Quantity""

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sal fonated— Continued

i^jnides, ajidnes, and quaternary ammonium salts Continued Fatty aoid - alkanolamine condensates Continued Diethanolamine condensates Continued

Coconut oil acids - diethanolamine condensates :

(Amine/acid ratio=2/l)

(Amine/aoid ratio=l/l)

Laurlo acid - diethanolamine condensate

Oleic acid - diethanolamine condensates :

(Amine/acid ratio=2/l)

(Amine/acid ratio=l/l)

Stearic acid - diethanolamine condensate

Tall oil acids - diethanolamine condensate

Other diethanolamine condensates

Other alianolamine condensates, total

Laurie aoid - isopropanolamine condensate

Stearic acid - ethanolamine condensates

All other

Fatty acid - polyamine condensates, total

Oleic acid - dlethylenetriamlne condensate

Stearic aoid - dlethylenetriamlne condensate

All other

Fatty acid - polyamine condensates, ethoxylated, total Oleic aoid - ethylenedlamine condensate, monoethoxy-

lated

Stearic acid - ethylenedlamine condensate, mono-

ethoxylated

All other

Heterocyclic compounds, total

2-Heptadeoyl-l-(2-hydroxyethyl)-2-imldazoline

Hosinpolyamldoimldazollne

All other

N-Substituted amino acids and polypeptides

Other amides, amines, and quaternary ammonium salts,

total

N-(Coconut oil alkyl)-l,3-propylenediamine

N-(9-0ctadecenyl)-l,3-propylenediamlne

N- (Tallow alkyl)-l,3-propylenediamine

All other

Carboxylic acid esters, total

Ethylene glycol and dlethylene glycol esters, total

methylene glycol dl- and sesquistearate

Dlethylene glycol monolaurate

methylene glycol mono-oleate

methylene glycol monostearate

Ethylene glycol distearate

Ethylene glycol monostearate

All other

Glycerol esters, total

Complex glycerol esters'

Glycerol esters of chemically defined fatty acids,

total

Glycerol mono-oleate

Glycerol monostearate

All other

Glycerol esters of mixed fatty acids, total

Glycerol monoester of coconut oil acids

Glycerol monoester of cottonseed oil acids

All other

Polyethylene glycol esters, total

Polyethylene glycol esters of chemically defined fatty

acids, total

Polyethylene glycol dilaurate

Polyethylene glycol dioleate

Polyethylene glycol distearate

13,858 16,712 16, 194-

1,298

1,097

1,9U

334

3,092

16,794

1,394

269

15,131

16, 877

1,216

905

14,756

6,109

3,357

2,517 235

7,443 123 208

7,112

4,974

24,379

989

1,400

3,720

18,270

132,281

5,347 285 536 132

1,025 212 888

2,269 67,083

4,700

21,613 940

20,246 427

40,770

361

1,455

38,954

21,169

15,323

596

2,774

322

1,000 dollars

11,850 15,973 16,789

937 1,084 1,931

2,526 16,238

249 15,989 15,378

749 14,629 4,281

1,532

2,749

.6,683

120

6,563 4,350

24,179 1,084 1,194 3,837

18,064

102,689

4,904 262 559 126 828 213 776

2,140 56,936

2,754

20,217 905

18,923 389

33,965 4^9

33,516 14,157

9,218 590 611 276

4,196 4,541 4,701

224 396 726

575 4,480

95 4,385 5,494

469 5,025 3,476

1,650 1,826 3,362

3,296 7,293

9,919 832

471 1,762 6,854

33,516

1,525

73

172

30

209

73

320

648

15,336

1,192

6,239 314

5,797 128

7,905 117

7,788 4,911

3,491 ^13 214 103

See footnotes at end of table.

50 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19A. —Surface -active agents.- U.S. production and sales , J964-

Chemical

Production"""

Quantity^

NONBENZENOID SURFACE-ACTIVE AGENTS--Continued Not Sulfaled or Sulfonated-Continued

Carboxylio acid esters Continued

Polyethylene glycol esters Continued

Polyethylene glycol esters of chemically defined fatty acids Continued

Polyethylene glycol monolaurate

Polyethylene glycol mono-oleate

Polyethylene glycol monostearate

All other

Polyethylene glycol esters of mixed fatty acids,

total

Polyethylene glycol coconut oil ester

Polyethylene glycol rosin ester

Polyethylene glycol tall oil ester

All other

Other carboxylic acid esters, total

Anhydrosorbitol tall oil ester

Ethoxylated anhydrosorbitol monolaurate

Ethoxylated anliydrosorbitol raono-oleate

Ethoxylated anhydrosorbitol monostearate

Ethoxylated anhydrosorbitol trioleate

Ethoxylated anhydrosorbitol tristearate

1, 2-Propanediol monolaurate

1,2-Propanediol monostearate

All other

Ethers, total

Castor oil, ethoxylated

n-Dodecyl alcohol, ethoxylated

Mixed primary straight chain alcohols, ethoxylated

9-Ootadeoenyl alcohol, ethoxylated

Tridecyl alcohol, ethoxylated

All other

Fatty acids, potassium and sodium salts:

Coconut oil acids, potassium and sodium salts

Laurie acid, potassium salt

Mixed vegetable fatty acids, potassium salt

Oleic acid, potassium salt

Oleic acid, sodium salt

Rosin acids, sodium salt

Stearic acid, sodium salt

Tall oil acids, potassium salt

Tall oil acids, sodium salt

Phosphoric and polyphosphoric acid esters, total

Alcohols, phosphated and polyphosphated, total

2-Ethylhexyl phosphate, sodium salt

Mixed mono- and diaUcyl phosphate

Octyl polyphosphate

All other

Other phosphoric and polyphosphoric acid esters

Other nonbenzenoid surface-active agents, not sulfated or sulfonated^

Sulfated and Sulfonated Total— - -

Dicarboxylio acid amides, sulfated and sulfonated

Dicarboxylic acid esters, sulfated and sulfonated, total

Sulfosuooinic acid, bis(2-ethylhexyl)ester

Jill other

1,000

pounds

3,887

2,64A

4,611

489

5,846 350

3,596

1,900

38,682

401

2,600

3,446

1,970

430

708

174

1,042

27,911

119,474

2,593

43,947

17, 974

2,934

7,524

39,502

289

102

494

863

1,034

90

1,841

6,379

97

JlA

3,862

229

324

112

3,197

1,028

30,499

309,730

1,492 5,427

1,000

pounds

2,111

1,987

3,398

245

4,939

274

671

2,929

1,065

26,692

2,482

3,135

1,906

415

987

179

847

16,741

63,139

2,131 1,930

15,233 1,966 6,994

34, 885

287

100

487

708

1,011

90

1,865

6,375

81

3,665

2,651

201

276

112

2,062

1,014

30,004

288, 149

1,521 5,515

1,000 dollars

833

771

1,276

81

1,420

86

213

670

451

11,744

1,065

1,372

832

184

415

68

270

7,538

15,495

756

900

2,237

942

1,546

9,114

107 215 188 21 947 1,090

1,807

63

215

44

1,485

683

4,661

64,208

3,993 1,434

3,880 1,635

935 2,592

1,780 812

See footnotes at end of table.

SURFACE-ACTIVE AGENTS 51

TABLE 19A. Surface-active agents: U.S. production and sales, 1964 Continued

Production''"

Sales

Quantity^

Unit value ^

NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued

Sulfated and Sulfonated- -Continued

n-Dodeoyl sulfate salts, total

n-Dodecyl sulfate, aminonium salt

n-Dodecyl sulfate, sodium salt

n-Dodeoyl sulfate, triethanolamine salt- All other

1,000 pounds ■41,097

1,000 dollars

36,704

Fats, oils, and waxes, sulfated and sulfonated, total- Castor oil, sulfonated

Coconut oil, sulfonated

Cod oil, sulfonated

Grease, other than wool, sulfonated

Neat's-foot oil, sulfonated

Peanut oil, sulfonated

Rice-bran oil, sulfonated

Soybean oil, sulfonated

Sperm oil, sulfonated

Tall oil, sulfonated

Tallow, sulfonated

All other

ijS-ig

12,777 10,018 16,-453

31,692

1,836 10,948

8,584 15,336

19,522

12,028

Other nonbenzenoid surface-active agents, sulfated and

sulfonated, total

Butyl sulfo-oleate

Coconut oil acids - ethanolamlne condensate, sulfated,

potassium salt

n-Dodeoyl alcohol, ethoxylated and sulfated, sodium salt

Isopropyl sulfo-oleate

N-lfethyl-N-oleoyltaurine

Oleic acid, sulfonated

Propyl sulfo-oleate

All other'

8,119 1,686 2,222

660 1,166 1,309

187

2U 6,948

714 7,312 1,155

230,022

3,799 813

1,702 625 491

1,183

196 4,152

5,383 1,178

224, 887

921 5,724 1,928 3,455

4,193

.50 .52

1,195 171 265 98 107 309

71 795

853 329

44,460

.36 .19

.16 .28

1,564

45

579

1,123

2,780

4,837

810

218,284

1,499

45

413

665

2,763

3,607

719

215,176

357

48 255 194 1,473 849 184 41, 100

""■ All quantities are given in terms of 100-percent organic surface-active ingredient.

^ Calculated from rounded figures.

-^ Includes sales of xylenesulfonio acid, potassium salt, and of straight chain dodeoylbenzenesulfonic acid, tri- ethanolamine salt; also includes production and sales of "All other" benzene-, toluene-, and xylenesulfonates, of "All other" straight chain dodecyl- and tridecylbenzenesulfonates, and of all branched chain alkylbenzenesulfonates other than dodecyl- and tridecylbenzenesulfonates.

'• Includes sales of "All other" alkylphenols, ethoxylated and sulfated.

' E.g., glycerol lactate palmitate and glycerol diacetyltartrate monostearate.

^ Includes production and sales of "All other" fatty acids, potassium and sodium salts.

'' Includes alcohols, alkanes, amines, ethers, fatty acids, fatty acid amides, fatty acid esters, and quaternary ammonium compounds, sulfated and sulfonated.

Production of benzenoid surface- active agents in 1964 amounted to 1,348 million pounds, or 3. 0 percent more than the 1,309 million pounds reported for 1963. Sales of benzenoid surface- active agents in 1964 totaled 1,245 million pounds, valued at $165 million, compared with sales in 1963 of 1,222 million pounds, valued at $160 million. Of the benzenoid surface- active agents for which individual statistics are shown in the table, those produced in largest quantity were lignosulfonic acid, calcium salt, 326 million pounds; branched chain dodecylbenzenesulfonic acid, sodium salt, 320 million pounds; nonylphenol, ethoxylated, 133 million pounds; branched chain dodecylbenzenesulfonic acid, 61 million pounds; dodecylphenol, ethoxylated, 52 million pounds; and straight chain dodecylbenzenesulfonic acid, sodium salt, 49 million pounds.

Production of nonbenzenoid surface- active agents in 1964 amounted to 771 million pounds, or 14. 7 percent more than the 672 million pounds reported for 1963. Sales of nonbenzenoid surface-active agents in 1964 totaled 655 million pounds, valued at $185 million, compared with the 567 million pounds, valued at $165 million, reported for 1963. Of the nonbenzenoid surface- active agents for which individual statistics are shown in the table, those produced in largest quantity were n-dodecyl alcohol, ethoxylated, 49 million pounds; glycerol monostearate, 20 million pounds; coconut oil acids - diethanolamine condensate (amine/acid ratio=l/l), 17 nnil- lion pounds; and lauric acid - diethanolamine condensate, 16 million pounds.

52

SYNTHETIC ORGANIC CHEMICALS, 1964 Pesticides and Other Organic Agricultural Chemicals

This section of the report covers pesticides (fungicides, herbicides, insecticides, and rodenticides) and other organic agricultural chemicals, such as plant hormones, seed disin- fectants, soil conditioners, and soil fumigants. The data are given in terms of 100-percent active material; they thus exclude such materials as diluents, emulsifiers, synergists, and wetting agents. Statistics on production and sales of pesticides and other organic agricultural chemicals in 1964 are given in table 20A.12

Production of pesticides and other organic agricultural chemicals in 1964 amounted to 783 million pounds--about 2 percent more than the 763 million pounds reported for 1963. Sales in 1964 were 692 million pounds, valued at $427 million, compared with 651 million pounds, valued at $369 million, in 1963.

The output of cyclic pesticides and other chemicals included in the cyclic group amounted to 585 million pounds in 1964--about 2 percent less than the 597 million pounds produced in 1963.

TABLE 20A. Pesticides and other organic agricultural chemicals : U.S. production and sales, 1964

[listed below are all pesticides and other organic agricultural chemicals for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 20B in pt. Ill lists all pesticides and other organic agricul- tural chemicals for which data on production or sales were reported and identifies the manufacturer of each]

Sales

Qaantity

Unit value ^

Grand total

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC

Total

Fungicides, total

Ifercury fungicides

Naphthenic acid, copper salt

Pentachlorophenol (PCP)

2,4-,5-Trichlorophenol and salts

All other^

Herbicides and plant hormones, total

2-sec-Butyl-4,6-dinitrophenol (DNBP)

2-seo-Butyl-4-,6-dinitrophenol, ammonium salt

Phenoxyacetic acid derivatives:

(2,A-Dichlorophenoxy)acetic acid (2,4-D)

(2,4-Dichlorophenoxy)aoetic acid esters and salts, total

( 2, 'i-Dichlorophenoxy) acetic acid, n-butyl ester

( 2, 4--Dichlorophenoxy) acetic acid, dimethylamine salt-

(2, li-Dichlorophenoxy) acetic acid, ethyl ester

( 2, -i-Diohlorophenoxy) acetic acid, iso-octyl ester

( 2, 4-Dichlorophenoxy) acetic acid, isopropyl ester

All other

(2,<i,5-Trichlorophenoxy)aoetic acid (2,4,5-1)

(2,4,5-Trichlorophenoxy)acetic acid esters and salts,

total

(2,'i,5-Trichlorophenoxy) acetic acid, n-butyl ester

(2,4., 5-Trlohlorophenoxy) acetic acid, Iso-ootyl ester- (2,'i,5-Trichlorophenoxy)acetic acid, triethylamine

salt

All other

Phenylmercury acetate (PMA)

All other^

Insecticides and rodenticides, total

Aldrin-toxaphene group*

Hexaohlorocyclohexane (Benzene hexachloride ) and lindane'

Organophosphorus insecticides, total

0,0-Diethyl O-(p-nitrophenyl) phosphorothioate

(Parathlon)

0,0-Dlmethyl O-(p-nitrophenyl) phosphorothioate

(Methyl parathion)

All other^

l,l,l-Trichloro-2,2-bis(p-chlorophenyl) -ethane (DDT)

All other''

See footnotes at end of table.

1,000 pounds 782,749

692,355

1,000 dollars 427,111

584,698

522,691

316,556

3,774

1,138

1,897

36,901

13,662

27,176

186,344

63,115

1,132

1,860

29,236

30,887 117,!

21,415

4,146 55

53,714

54,366

7,242

14,091

607

6,159

4,508

21,759

11,434

12,963 1,754 3,699

361

7,149

495

49,171

317,580

105,296

39,661

12,768

18,640

8,253

123,709

48,914

2,691 52

25,006 40,262 5,766 9,618 749 6,010

18,119 3,729

6,895

551

2,933

414

2,997

468

38,765

341,708

3,164

540

5,005

12,706 124,611

105,551 11,765 42,769

10,338

21,713

10,718

129,373

52,250

1,497 108

7,573 15,827 2,498 4,094 194 2,414

6,627 3,174

5,056

439

2,514

410

1,693

2,248

89,128

170,530

1,934 51,527

7,349

16,431 27,747 18,993 47,141

1 2 See also table 20B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

MISCELLANEOUS CHEMICALS 53

TABLE 20A. Pesticides and other organic agricultural chemicals: U.S. production and sales, 1964 Continued

Quantity

Unit value ^

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, ACYCLIC

Total

Fungicides, total

Dimethyldithiooartamio acid, ferric salt (Ferbam)

Ethylene bis(dit)iiooarbamio acid), disodium salt (Nabam)

Ethylene bis(dithiooarbaniio acid), zinc salt (Zineb)

All other^

Herbicides and plant hormones, total

Methanearsonio acid, disodiiim salt

All other'

Insecticides, rodenticides, and soil conditioners and

fumigants, total

Bromomethane (ifethyl bromide)

l,2-Dibromo-3-chloropropane

Organophosphorus insecticides, total

Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)-

All other

All other insecticides, rodenticides, and soil condi- tioners and fumigants-'''''

1,000 pounds

198,051

pounds 169,664

1.000 dollars

110,555

31,929

1,838

2,251

6,664

21,176

40,042

32,441

24,050

2,167 37,875

126,080

1,863 2,238 4,039 24,301

34,159

2,667 31,492

103,064

735

859

1,780

20,676

38,839

.38 .44 .85

16,994

5,314

41,501

669

40,832

62,271

16,042 3,910 30,486 538 29,948

52,626

1,128 37,711

47,666

.42 1.20

.46

6,712 1,756

31,839 450

31,389

7,359

.42 .45

1.04 .84

1.05

.14

■'■ Calculated from rounded figures.

^ Includes captan, dlohlone, glyodin,. sodium pentachlorophenate, tri- and tetrachlorophenols , and others.

^ Includes dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl carbanilates (IPC and CIPC), maleio hydrazide, triazines, and others.

* Includes aldrin, ohlordane, dieldrin, endrln, heptachlor, and toxaphene.

' Production of gamma isomer content is not publishable because publication would reveal the operations of the Individual producers. Sales of gamma isomer content In benzenehexachlorlde and lindane totaled 3.2 million pounds.

^ Includes carbophenothlon, diazlhon, other phosphorothioates and phosphorodithloates, and others.

■^ Includes DDD, endosulfan, methoxychlor, tetradifon and other chlorinated Insecticides, 1-naphthyl methyl- carbamate, small amounts of rodenticides and Insect repellents, hexachlorocyolohexane and lindane (production only), and others.

^ Includes dodlne, mercury compounds, maneb, and others.

' Includes CDAA, thiocarbamate and organophosphorus herbicides, sodium dichloropropionate, sodium TCA, and others. ■^° Includes DD'VP, ethlon, malathion, naled, phorate, and others. ^^ Includes soil conditioners and fumigants, small quantities of rodenticides, and others.

Sales in 1964 were 523 million pounds, valued at $317 million, compared with 498 million pounds, valued at $286 m^illion, in 1963. The chemical in this group which was produced in the greatest quantity in 1964--as in eachyear since it was first separately reported in 1944--was the insecti- cide DDT. The output of this product in 1964 amounted to 124 million pounds, compared with 179 million pounds in 1963. The sharp decline in the production of DDT in 1964 was due in part to the large inventory carried over from the preceding year and in part to a sharp decrease in exports.

Production of acyclic pesticides and other acyclic organic agricultural chemicals in 1964 amounted to 198 million pounds--about 19 percent more than the 166 million pounds reported for 1963. Sales in 1964 were 170 million pounds, valued at $111 million, compared with 153 million pounds, valued at $8 3 million in 1963.

Miscellaneous Chemicals As used in this report, the term "miscellaneous chemicals" refers to those s-ynthetic organic products that are not included in the use groups covered in the preceding sections of the report. These miscellaneous chemiicals, which account for about three-fifths of the output of all synthetic organic chemicals, include products that are employed in a great variety of uses; the number of chemicals used exclusively for only one purpose is not large. Among the products covered are those used for gasoline and lubricating oil additives, paint driers, photographic chemicals, tanning materials, flotation reagents, refrigerants, textile polymers, sequestering agents, organic fertilizers, antifreeze chemicals, solvents, and acyclic intermediates.

Production of miscellaneous chemicals in 1964 amounted to 45. 7 billion pounds, or 11.0 percent more than the output of 41. 2 billion pounds reported for 1963. Sales of mis,cellaneous chemicals in 1964 amounted to 20. 5 billion pounds, valued at $2.7 billion, compared with 17. 5 billion pounds, valued at $2.4 billion, in 1963. Statistics on production and sales of miscel- laneous chemicals in 1964 are given in table 21A.-'-3

13 See also table 21 B, pt. III, which lists these products alphabetically and Identifies the manufacturers.

54

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 2i.A.— Miscellaneous chemicals.- U.S. production and sales, 1964

rusted below are all miscellaneous chemicals for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on produc- tion or sales were reported and identifies the manufacturer of each]

Grand total

MISCELLANEOUS CHEMICALS, CYCLIC

Total

Benzoic acid salts: Sodium benzoate, tech. and U.S.P

Benzoyl peroxide

Butyl benzoate

Cyclopropane

2,6-Di-tert-butyl-p-cresol:

Food grade

Tech

Ethylmorpholine

Flotation reagents

Gasoline additives, total^

N,N-Di-sec-butyl-p-phenylenediamine

N,N'-Disalioylidene-l,2-propanediamine

All other

Hexamethylenetetramine , tech

Lubricating oil and grease additives, total

Oil soluble petroleum sulfonate, barium salt

Oil soluble petroleum sulfonate, calcium salt

Oil soluble petroleum sulfonate, sodium salt

All other

Morpholine

Naphthenic acid salts, total^ *

Calcium naphthenate

Cobalt naphthenate

Iron naphthenate

Lead naphthenate

Manganese naphthenate

Zinc naphthenate

All other

Photographic chemicals:

Benzotrlazole

p-Diethylamlnobenzenediazonium chloride (p-Diazo-N,N-

diethylaniline) - zinc chloride

p-Dimethylaminobenzenediazonium chloride (p-Diazo-N,N

dimethylaniline) - zinc chloride

Pinene

Tall oil salts, total^

Calcium tallate

Cobalt tallate

Iron tallate

Lesid tallate

Manganese tallate

Zinc tallate

All other

See footnotes at end of table.

1,000 pounds

45,681,3»;3

1,1U,624

5,6U

5,022

577

163

4,316

15,537

879

4,523

11,333

1,403 9,930

42,776 466,691

34,847 156,041 127,430 148,373

15,102

20,427

1,383 3,122

161

12,903

1,323

1,069

466

20

119

63

9,007

704 2,391

519 4,262

899 58

174

Qaantity

20,518,575

603,618

5,110 4,832

4,063

12,822

870

6,633

2,441

915

3,277

28,755

276,352

83,628

68,396

124,328

12,638

18,784

1,231

2,521

137

12,305

1,250

906

434

10,042

589 2,337

479 3,494

862 36

167

1,000 dollars 2,651,276

224,330

1,497 4,558

2,271

2,381 7,044 1,011

6,110

2,133 1,610 2,367

5,241

58,132

16,518 10,420 31,194

6,114

6,012

549

1,637

48

2,709

473

337

259

84 247

1,398 2,729

191

1,242

127

859

247

11

52

MISCELLANEOUS CHEMICALS TABLE 21A. Miscellaneous chemicals.- U.S. production and sales , 1964 Continued

55

Production

CJuantity

Unit value ■"•

MISCELIANEOUS CHEMICAI£, CYCLIC— Continued

Tanning materials, synthetic, total

2-Naphthalenesulfonic acid, formaldehyde condensate and

salts

l-Phenol-2-sulfonio acid, formaldehyde condensate

(Phenol-formaldehyde, sulfonated)

All other

Textile chemicals, other than surface-active agents

All other miscellaneous cyclic chemicals

MISCELLANEOUS CHEMICAI£, ACYCLIC

Total

Acetaldehyde

Acetic acid, synthetic, 100^

Acetic acid salts, total

Copper acetate

Potassium acetate

Sodium acetate

Zinc acetate

All other .

Acetic anhydride, IOO5J, from all sources

Acetone, total

From isopropyl alcohol

All other

Acrylic acid

Acrylonitrile

Adipic acid

Alcohols, monohydrio, unsubstituted, total

Alcohols Cg or lower, total

Amyl alcohols

Butyl alcohols, total

Normal (n-Propyloarbinol)

All other

Ethyl alcohol, synthetic^

Hexyl alcohol

Iso-octyl alcohols

Isopropyl alcohol

Methanol, synthetic

All other

Alcohols Cio or higher, total

Deoyl alcohols

Dodecyl alcohol (Lauryl alcohol) (955^)

1-Hexadecanol (Cetyl alcohol) (955^)

1-Octadecanol (Stearyl alcohol) (955^)

All other

Amines, total

Coconut oil amine

Diethylamine

Dlmethylamine

Isopropylamlne

Methylamlne, mono-

Octadecylamine

Oleylamlne

Tallow amine

Tallow amine, hydrogenated

Trimethylamine

All other

1,000 pounds 34)001

29,871

3,318 812

1,928 476,526

44,566,719

1,058,013 1,099,986

23,154

171 2,853 14,649

5,481

1,399,203

1,054,756

761,154 293,602

32,532 594,177

7,936,892

7,567,198

32,179

799,219

388,540

410,679

2,071,116

5,208

142,042

1,503,957

2,631,657

381,820

369,694

64,720

16,672

1,777

286,525

611,134

1,157

8,260

54,129

7,729

18,003

749

931

3,153

9,951

12,129

494,943

i ,000 dollars

6,616

28,086

3,024 1,065

1,14^ 181,152

19,914,957

4,991

994 631

700 122,185

2,426,946

100,466 234,477

17,596

6,613 17,025

132 2,974

322

14,168

672,093

450,771 221,322

4,369

311,147

60,830

4,165,648

160 3,194

31,997

22,879 9,118

1,471 48,808 14,810

261,812

4,011,240

22,080

399,164

288,133

111,031

1,163,477

128,256 538,651 1,497,380 262,232 154,408 50,431

1,837

5,321

96,819

183,344

986

30,865

18,091

830

650

2,858

9,572

5,381

114,111

236,818

3,007

38,305

28,789

9,516

73,325

14)972 33,541 42,683 30,985 24,994 5,719

496

889

17,890

57,419

505 6,038

2,971 383 274 877

2,636

829

42,906

56

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 21A. Miscellaneous chemicals.- U.S. production arid sales , 1964-

-Continued

Chemical

MISCELLANEOUS CHEMICALS, ACyCLIC--Continued

Amjrl acetates, 905t

Bis(2-chloroethyl) ether (Dichlorodiethyl ether), all

grades

2-Butaiione (Methyl ethyl ketone)

2-Butanone oxime

2-Butanone peroxide

Butyl acetates, total

Normal

All other

tert-Butyl hydroperoxide

tert-Butyl peroxide (Di-tert-butyl peroxide)

Butyric acid

Caprolactam (Hexahydro-2H-azepin-2-one)

Carbon disulfide

Cellulose ethers, total

Sodium carboxymethylcellulose, lOOjt

All other

Chloral (Trichloroacetaldehyde )

Chloroaoetic acid, mono-

Chloroacetic acid, ethyl ester

2-Chloro-N,N-dimethylethylamine (Dimethylaminoethyl

chloride) hydrochloride

2-Chlorotriethylamine hydrochloride

Decanoyl peroxide

Dibutyl fumarate

Dibutyl maleate

2-Dlethylaminoethanol

Diethylene glycol

Diethyl malonate (Malonic ester)

Dllauryl 3,3'-thiodipropionate

2-Diinethylaminoethanol

Dioctyl maleate

Dipropylene glycol

Dodeoenylsuceinic anhydride

Epichlorohydrin

Erucamide

Ethanolamines , total

2-Aminoethanol (Monoethanolamine )

2,2'-Iminodiethanol (Diethanolamine)

2,2',2"-Nitrilotriethanol (Triethanolamine)

2-Ethoxyethanol (Ethylene glycol monoethyl ether)

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl

ether)

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol

monoethyl ether)

Ethyl acetate, 8556

Ethyl acetoacetate

Ethyl acrylate

Ethylene glycol

Ethylene oxide

Ethyl ether, all grades

Ethyl formate

2-Ethylhexanoio acid (o -Ethylcaproic acid) salts, total'

Calcium 2-ethylhexanoate

Cotalt 2-ethylhexanoate

Lead 2-ethylhexanoate

Manganese 2-ethylhexanoate

Zinc 2-ethylhexanoate

See footnotes at end of table.

Production

8,664

88,934 2,760 1,486

77,782 38,811

130 1,074

245,688 668,780

44,930 40,875

57,614

60,511

1,734

314 5,143 6,052

151,475

937

1,257

165

27,101

968

173,937

60,286 65,521 48,130

36,294

8,277

117,746

980

90,831

1,814,600

2,163,035

87,807

Quantity

773 274

7,106

8,832

276,416

2,675

1,448

112,822

75,047 37,775

633

121,777 601,201

79,294

42,454 36,840

40

288

4,630

3,653

2,240

125,051

607

905

947

25,225 830

32,045 429

14^,107

48,225 49,043 46,839

47,216

29,154

1,378

101,212

799

36,177

1,202,562

198,209

79,680

168

2,966

143 638 227

1,000 dollars 1,193

165

31,157

2,009

2,492

11,539

7,804 3,735

249 1,531

151 41,065 24,191

43,521

18,712 24,809

49 423 984 791 1,054 13,818 4A2 895 664

3,158 390

7,165 503

26,728

9,770 8,165 8,793

7,740

5,056

228

10,366

348

9,737

110,085

20,502

5,353

56

649 96 28

102

MISCELLANEOUS CHEMICALS TABLE 21A. Miscellaneous chemicals: U.S. production and sales , 1964-

57

Quantity-

Unit value -"^

MISCELLAHEOUS CHEMICAIS, ACYCLIC— Continued

2-Ethylhexanoio acid (a-Ethyloaproio acid) salts Continued All other

2-Ethyl-l-hexyl acrylate

Ethyl propionate

Ethyl silicate (Tetraethoxysilane)

Formaldehyde (3795 by weight)

Fonnio acid, 905&-

Formic acid salts

Fumario acid

Gluconic acid, tech

Gluconic acid, sodium salt, tech

Halogenated hydrocarbons, total

1-Bromobutane (n-Butyl bromide)

Carbon tetrachloride

Chlorinated paraffins, total

355^64 i^ chlorine

All other

Chlorodifluorome thane

Chloroethane (Ethyl chloride)

Chloroform

Chloromethane (Methyl chloride)

Diohlorodifluoromethane

1,2-Dichloroethane (Ethylene diohloride)

Diohloromethane (Methylene chloride)

1,2-Dlchloropropaiie (Propylene diohloride)

Dichlorotetrafluoroethane

lodomethane (Methyl iodide)

Tetraohloroethylene (Perohloroethylene)

Triohloroethylene

Trichlorofluoromethane

Vinyl chloride, monomer ( Chloroethylene )

All other

Isoascorbic acid, sodium salt

Isopropyl acetate

Isopropyl ether

Lactic acid, lOOjt

Lauroyl chloride

Lauroyl peroxide ^

Linoleic acid salts, total^

Calcium linoleate

Cobalt linoleate

All other '■

Lubricating oil additives, total

Phosphorodithioates (Dithiophosphates )

Sulfurized sperm oil

All other

Maleic anhydride

Meroaptoacetic (Thioglycolio) acid derivatives, total— 2-Aminoethyl mercaptoacetate (Monoethanolamine

thioglyoolate)

Ammonium mercaptoacetate

All other

2-Methoxyethanol (Ethylene glycol monoethyl ether)

2-(2-Methoxyethoxy)ethaiiol (Diethylene glycol monoethyl ether)

See footnotes at end of table.

1,000 pounds

3,011

22,590

24

4,871

2,839,884

19,396

30,572

30,145

3,503

8,904

8,116,012

4J 535,891 39,887 29,664 10,223

666,111

119,210

134,011

227,873

2,199,378

179,602

58,489

13,401

20

365,729

370,465

148,498

1,614,981

1,442,423

2,631 38,048

9,353 1,427

128 231 183

380,686

101,928

23,484

255,274

118,109

4,671

225 1,723 2,723

73,376

11,022

1,000 pounds 1,724

20,464

3^924

1,067,340

18,769

23,629 3,269 7,530

3,704,041

464,547

43,380

252,660

98,104

67,199

226,327

445,508

156,693

32,294

12,629

10

335,619

370,076

139,367

597,124

462,504

2,363 33,559 2,970 8,069

1,397

523

133 390 165,733

53,282

112,451

67,792

4,180

4,180 61,819 3,764

1,000 do I lars 2,062

6,521

"l,577 27,973 2,597

3,844 1,110 2,285

417,943

33,719

27,093

18,322

8,199

5,233

65,680

•20,671

14,020

816

7,020

30

31,704

32,122

28,504

37,895

86,915

3,141

3,717

246

2,956

1,687

182

28

154

34,511

13,492 21,019 8,271 5,709

5,709

10,757

656

58 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21A. Miscellaneous chemicals: U.S. production and sales , 1964 Continued

MISCELLANEOUS CHEMICALS, AOfCLir^-Continued

2-[2-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol

monoraethyl ether)

Methyl acetate

4-Methyl-2-pentanone (Methyl isobutyl ketone)

Oleic acid salts, total'

Copper oleate

All other

Oxalic acid

Oxalic acid salts

Palmitic acid salts, total

Aluminum palmitate

Zinc palmitate

Palmitoyl chloride

Pentaerythritol

Pentaerythritol tetranitrate

Phosgene (Carbonyl chloride)

Phosphorus acid esters, not elsewhere specified

Polyethylene glycol

Polypropoxy ethers, total

Glycerol tri(polyoxypropylene) ether

All other

Polypropylene glycol

Propionic acid

Propionic acid salts :

Calcium propionate

Sodium propionate

Propylene glycol (1,2-Propanediol)

Propylene oxide

Saroosine and salt

Sequestering agents, total

(Diethylenetrinitrilo)pentaacetic acid, sodium salt

N,N-Dihydroxyethylglycine, sodium salt

(Ethylenedinitrilo)tetraacetic acid (Ethylenediamine-

tetraaoetic acid)

(Ethylenedinitrilo)tetraacetic acid, disodium salt

(Ethylenedinitrilo)tetraacetic acid, tetrasodium salt-- (N-Hydroxyethylethylenedinitrilo)triacetic acid,

trisodium salt

All other

Sodium formaldehydesulfoxylate

Sodium methoxide (Sodium methylate)

Stearic acid salts, total*

Aluminum stearates, total

Aluminum distearate

Aluminum monostearate

Aluminum tristearate

Calcium stearate

Lead stearate

Lithium stearate

Magnesium stearate

See footnotes at end of table.

8,897 158,607

52 287

22,935 4,677

159

137

69,296

4,776

244,965

9,749

39,120

173,224

117,120 56,104

95,987 39,117

11,404

5,357

236,357

569,060

1,566

34,883

1,541 150

5,706

680

19,010

3,294 4,502

4,673 5,440

31,884

5,0l4

3,639

855

520

11,046

411

339

1,326

1,000 pounds

343

134,822

327

1,000 dollars

35

19,655 4,469

64,208 2,668

3,308 33,650

157,167

110,347 46,820

11,572

211,454 60,319

23,839

1,300 124

2,968 11,755

2,814 4,878

4,778 5,240

29,906

4,630

3,334

816

480

10,427

359

361

1,367

17,131

14 266

2,778 1,238

15,517 2,108

4,184 8,220

31,841

21,775 10,066

1,302

22,593 7,583

9,031

411 84

1,108 4,196

1,320 1,912

1,032 1,604

10,830

1,716 1,236 310 170 2,951 140 184 531

MISCELLANEOUS CHEMICALS TABLE 21A. —Miscellaneous chemicals.- U.S. production and sales , 1964— Continued

59

MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued

Stearic acid salts Continued

Zino stearate

All other

Tallow amide, hydrogenated

Tetraethyllead

Triethylene glycol

Urea in compounds or mixtures (IOO5S "basis), total-—

In feed compounds

In liquid fertilizer

In solid fertilizer

All other

Vinyl acetate, monomer

Zinc formaldehydesulfoxylate

All other miscellaneous acyclic chemicals

1,000 pounds

9,982 3,766

824 586,956 44,539

2,419,764

238,872

869,879

1,092,287

218,726

440,331

1,380

7,543,372

Quantity

9,880 2,882

796 571,565 35,610

2,296,736

257,925

838,043

1,058,971

141,797

217,310

1,405

1,813,971

3,948 1,360

298

304,715

6,137

° 97,813

11,325

37,441

42,826

6,221

24,731

631

486,933

Unit value ■"■

Calculated from rounded figures.

= Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given in the section "Plasticizers." ■' r r s " j-"

^ ftuantities are given on the basis of solid naphthenate, tallate, or linoleate content.

Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in the section "Pesticides and Other Organic Agricultural Chemicals." e =

6 J? f?'3"i°n. sales of recovered acetic acid totaled 70,784 thousand pounds, valued at 3,992 thousand dollars. T, .* o^ i"! °" production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax Unit, U.S. Internal Revenue Service.

_ ■^ Statistics exclude production and sales of potassium and sodium oleate. Statistics on these oleates are included m the section "Surface-Active Agents."

_ Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are included m the section "Surface-Active Agents."

^^Production of urea in primary solution totaled 2,487,279 thousand pounds. Includes estimated values for sales of urea in nitrogen compounds.

60 SYNTHETIC ORGANIC CHEMICALS, 1964

The total output of miscellaneous cyclic chemicals in 1964 was 1. 1 billion pounds, or 17. 0 percent more than the output of 95 3 million pounds reported for 1963. Sales in 1964 totaled 604 million pounds, valued at $224 million, compared with 477 nnillion pounds, valued at $191 mil- lion, in 1963. The most important subgroup of cyclic compounds was the lubricating oil addi- tives, the output of which was 467 million pounds in 1964.

Total production of miscellaneous acyclic chemicals in 1964 was 44. 6 billion pounds-- 10. 9 percent more than the output of 40.2 billion pounds reported for 1963. Sales in 1964 totaled 19. 9 billion pounds, valued at $2. 4 billion, compared with 17. 0 billion pounds, valued at $2. 2 billion, in 1963.

Production of alcohols and halogenated hydrocarbons in 1964 each exceeded that of any of the use groups of synthetic organic chemicals except cyclic intermediates and plastics and resin materials. Production of monohydric, unsubstituted alcohols totaled 7. 9 billion pounds in 1964, about 10. 8 percent more than in 1963. Alcohols are used as solvents, intermediates, and anti- freeze materials, and for other purposes. Production of halogenated hydrocarbons totaled 8. 1 billion pounds in 1964, or 12. 9 percent more than the 7. 2 billion pounds reported for 1963. Halogenated hydrocarbons are used as solvents, intermediates, refrigerants, and aerosol propellants, and for other purposes.

Individual chemicals the output of which exceeded 1 billion pounds in 1964 were formalde- hyde (2. 8 billion pounds, compared with 2. 5 billion pounds in 1963); synthetic nnethanol (2. 6 billion pounds, compared with 2. 3 billion pounds); urea (2.4 billion pounds, compared with 2. 2 billion pounds); ethylene oxide (2. 2 billion pounds, compared with 1. 9 billion pounds); dichloro- ethane (2. 2 billion pounds, connpared with 1. 8 billion pounds); ethyl alcohol (2. 1 billion pounds, compared with 2. 0 billion pounds); ethylene glycol (1. 8 billion pounds, compared with 1. 7 billion pounds); vinyl chloride (1.6 billion pounds, compared with 1.4 billion pounds); isopropyl alcohol (1. 5 billion pounds in each year); and acetic anhydride (1. 4 billion pounds, compared with 1. 3 billion pounds).

PARTm.

ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF MANUFACTURERS

This section of the report consists of (1) a series of tables that supplement the statistical information given in parts I and II, and (Z) a Directory of Manufacturers. The tables with num- bers that include the letter "B" supplement the tables in part I or part II with numbers that in- clude the letter "A"; for example, table 8B in part III supplements table 8A in part II.

Each table in part III lists alphabetically the individual items in each group for which data on production or sales were reported for 1964. The tables include data on only those chemicals for which the volume of production or sales in 1964 exceeded 1, 000 pounds or for which the value of sales exceeded $1, 000. Where separate statistics for an item are given in the tables in part I or part n, an asterisk (=!=) precedes the name of the item in the tables in part III. The manufacturers of each product are indicated by identification codes which are listed in the Directory of Manu- facturers (table 22). A few companies, however, have specifically requested that they not be identified as having produced or sold certain items. These manufacturers are indicated by a small letter "x" in the tables.

Tar Crudes TABLE 4B. Tar crudes for which U.S. production or sales were reported, identified by manufacturer, 1964

[Tar crudes for which separate statistics are given in table Ak are marked below with an asterisk (**); products not so marked do not appear in table "iA because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)]

Manufacturers ' identification codes (according to list in table 22)^

*Crude light oil

Light-oil distillates :

*Benzene, specification and industrial grades

»Toluene, specification and other grades

*}^lene, all grades

^Solvent naphtha

»A11 other light-oil distillates

•^Pyridine crude bases

♦Naphthalene, crude, solidifying at

*Less than 74° C

*'7^" C. to less than 76° C

»76° C. to less than 79° C

Crude tar-acid oils having a tar-acid content of

»55fc to less than 245t-

*2A$ to 515^

Cresylic acid, crude

*Creosote oil (Dead oil) :

♦Distillate as such

♦Creosote in coal-tar solution

All other distillate products

♦Tar, road

♦Tar for other uses:

Crude

Refined

Pitch of tar: ♦Soft and medium (water softening points less than 110° F., and 110° F. to 160° F.).

♦Hard (water softening point above 160° F.)

Pitch-of-tar coke and pitch emulsion

CBT. ■=

ACY, KPP.

ACT, KPP.

ACT, KPP.

ACT, KPT, NEV, PAI.

ACP, NEV, PAI.

ACP, KPT.

COP, NEV.

KPT.

ACP, KPT, PRD, RIL.

ACP, RIL.

ACP, KPT, RIL.

ACP, KPT, PHD.

ACP, ACT, CBT, COP, KPT, RIL, WTC.

ACP, HUS, JEN, KPT, RIL.

ACP, KPT, NEV, PAI.

ACP, KPT, RIL, WTC.

KPT, RIL.

ACP, KPT, RIL, RUR.

ACP, CBT, COP, JEM, KPT, RIL.

ACP, COP, KPT, RIL.

JEN, RIL.

Does not include manvif acturers ' identification codes for producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, May 17, 1965, entitled "Coke Producers in the U.S. in 1964-."

^ Crude light oil production and sales of this company are not included with the U.S. Bureau of Mnes figures given in table 4A.

61

62

SYNTHETIC ORGANIC CHEMICALS, 1964

Crude Products From Petroleum and Natural Gas for Chemical Conversion

TABLE 5B. Crude products from petroleum and natural gas for chemical conversion for which U.S. production

or sales were reported, identified by manufacturer, 1964

[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in table 5A are marked below with an asterisk ( *) ; products not so marked do not appear in table 5A because the reported data are accepted in confidence and may not be published. Jifanufacturers ' identification codes shown be- low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers' identification codes (according to list in table 22)

AROMATICS AND NAPHTHENES

*Alkyl aromatics, distillates, and solvents

^Benzene (except motor grade) :

^Benzene,

»Benzene,

*Cresylic acid, crude

*Naphthalene , all grades

*Naphthenic acids :

Acid number lower than 150

*Acid number 150-199

Acid number 200-224

Acid number 225-24-9

Sodiiim carbolate and phenate, crude

*Toluene :

■^Nitration grade,

*Pure commercial grade,

Solvent grade

All other

»}(ylenes , mixed :

Aviation grade

*3°

All other

All other aromatics and naphthenes

ALIPHATIC HYDROCARBONS

Ci hydrocarbon: Methane

»C2 hydrocarbons :

*Aoetylene

»Ethane

^Ethylene

C2 and C3 hydrocarbons, mixed

*C3 hydrocarbons:

*Propane

Propane-propylene mixture

^Propylene

*Ci. hydrocarbons :

*1,3-Butadiene, grade for rubbers (elastomers)-

^Butadiene and butylene fractions

ACC, DUP, ELP, ENJ, FG, GOC, JCC, MOC, MON, OMC, PLC, SM, SOG, USI, VPT, WTN.

APR, ASH, ATR, CCP, CSD, DLH, DXS, ELP, ENJ, GOC, GRS, M3C, MON, PLC, PRO, RIC, SHO, SM, SNT, SOG, SUN, TOC, TX, VPT.

Aid, CO, DOW, SHO, SKO, SOC, UCC.

ATR, PRD, RIC, SHO, SOI.

ASH, COL, CSO, MON, SUN, TID.

RIC, SUN, TX.

PRO, RIC, SM, SOC, SUN.

PRO, RIC, SM, SOC.

NOP, PRO, RIC, SM, SOC.

ATR, GOC, SIN.

ASH, ATR, CSD, DLH, ENJ, GOC, GRS, LEN, MOC, MON, PLC, PRO, RIC, SHC, SHO, SIN, SNT, SOG, SUN, TOC, TX, UCC, VPT.

DOW, M3N, RIC.

CO, FG.

CSD, DXS, ELP, GRS, RIC, SHO, SM, SOC, SUN, TOC, TX, VEL.

CSD, CSO, SOG.

ASH, ATR, DLH, MON, PRO, SNT.

MOC, SIN.

AMD, CCP, CSD, ENJ, GRS, LEN, MON, RIC, SHO, SM, SOC,

SUN, TOC, TX, VPT. ACC, ELP, ENJ, JCC, LEN, PAS, PLC, SM.

CCP, MOC, PAN.

ACY, DOW, DUP, MNO, MON, UCC, X.

ACU, CCP, ENJ, MOC, MON, PAN, SHC, SHO, SM, SOI, TX,

UCC, USI. CCP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, M3C, MON,

OMC, PET, PLC, RIC, SHC, SM, SNO, TX, UCC, USI. GYR, PLC, SM.

ASH, CCP, CSD, DXS, ENJ, GRS, MOC, OMC, PAN, PLC, SHO, SIN, SM, SNT, SOG, SOI, SPI, UCC, UOC, USI.

GOC, TX.

ASH, CCP, DOW, EKX, ELP, ENJ, GOC, JCC, MOC, MON, PET, PLC, RIC, SHC, SHO, SIN, SIO, SM, SOG, SOI, SPI, SUN, UCC, UOC.

CPY, DOW, ELP, ENJ, FRS, GGC, ILC,

SHC, SM, SOC, SPI, TID, TUS, UCC. DOW, GYR, PLC, SHC, SHO, SIN, SOC.

i, PET, PLC, PIT,

CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS

63

TABLE 5B. Crude products from petroleum and natural gas for chemical conversion for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

ALIPHATIC HTOROCABBONS— Continued

*Ci, hydrocarbons Continued

*n-Butane

1-Butene

2-Butene

*1-Butene and 2-butene mixture

»Isobutane

»Isobutylene

All other

*C5 hydrocarbons :

Isopentane ( 2-Methy Ibutane )

*Isoprene (2-Methyl-l,3-butadiene)

n-Pentane

All other

Ce hydrocarbons:

Diisopropyl (2, 3-Dimethy Ibutane)

*Hexane

Neohexane ( 2, 2-Dimethy Ibutane)

All other

C7 hydrocarbons:

*n-Heptane

»Heptenes, mixed

All other

Cs hydrocarbons :

*Diisobutylene (Diisobutene)

n-Octane

2,2,4-Trlmethylpentane (iso-octane)

All other

Hydrocarbons, C9 and above:

1-Dodecene

Eicosane

»Nonene (Tripropylene)

Pentadecene

*Polybutene

»Tetrapropylene

Trideoene concentrate

Triisobutylene

All other

■^Hydrocarbon derivatives:

1-Butanethiol

tert-Butyl mercaptan ( 2-Methy 1-2-propanethiol)

Di-tert-butyl disulfide

tert-Dodecyl mercaptan

Ethyl mercaptan (Ethanethiol)

Isopropyl mercaptan

Methyl mercaptan (Methanethiol)

tert-Ootyl mercaptan

n-Propyl mercaptan (l-Propanethiol)

All other

All other aliphatic hydrocarbons: Alpha olefins, molecular weight ranges:

C6-C7 '

Cg-Cio

C11-C15—

C16-C20

All other

PLC, PRO. SIN, SOG, TID.

CCP, CSD, DX3, SM, SNT, SOC,

PLC, PTT, SPI.

MON, PLC, PTT.

AMO, CCP, ENJ, SOI, SPI, TX,

CCP, DXS, EIP, USI.

CCP, ENJ, PRO,

APR, JCC, MON,

CCP, CSD, ENJ,

ENJ, am, PLC,

APR, PLC.

ENJ, GYR, MOC,

PLC.

ENJ, PLC, PRO,

PLC.

APR, PLC.

CSD, EKX, ENJ, ENJ, GOC, HOU, PLC.

ATR, PTT, TX. ENJ, PLC. PLC. PLC.

CO.

ATR.

AMO, ATR, ENJ,

CO.

CSD, SOC, SOI.

DXS, ENJ, GOC,

ENJ.

ATR.

ENJ, GOC, HOU,

PAS.

PAS, PLC.

PLC.

PAS.

CSD, PAS, SOC.

PAS, SOC.

ACC, PAS.

PAS, PLC.

PAS.

EKX, PAS, PLC,

ATR, GOC, GYR, PLC, SOC.

ATR, ENJ, GOC, SOC.

ENJ, GOC, SOC.

ENJ.

EKX, GOC, SOC.

ELP, MOC, OMG, PAN, PLC, SHM, SHO, SOI, UCC, USI.

GOC, MOC, PLC, PRO, PTT, SHO, SOC, MOC, OMG, PAN, PLC, SHO, SOI, UCC,

PTT, SIN.

PLC, SM, SOI, UCC, USI.

PLC, SHO, SM, SOI, UCC. SHC.

MON, PAS, PET, PLC, SHC, USI.

GOC, PAS, PRO, RIC, SUN.

MOC, PRO, RIC, SNT, SOC, SUN, TX.

KEN, PLC, SOC, TID, UCC, x.

64

SYNTHETIC ORGANIC CHEMICALS, 1964 Cyclic Intermediates

TABLE 7B.

Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964

fCyolio intermediates for which separate statistics are given in table 7A are marked below with an asterisk (*); cyclic intermediates not so marked do not appear in table 7A because the reported data are accepted in confi- dence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers' identification codes (according to list in table 22)

Aoeanthryleno[2,l-a]aceanthrylene-5,13-dione

8-Acetamido-l-('i-acetamido-2-hydroxy-5-nitrophenylazo)- 2-naphthol.

3-Acetamido-6-aminobenzenesulfonic acid

5-Acetamido-2-aminobenzenesulfonic acid

3-(2-Acetamido-A-aminophenylazo)-l,5-naphthalenedi- sulfonlc acid.

p-Acetamidobenzoic acid

2-Aoetamido-3-chloroanthraqulnone

*Acetanilide, tech

Acetoacetanilide

o-Acetoacetanisidide

o-Acetoacetotoluidide

Acetoacetoxylidide

I'-Acetonaphthone

Acetone phenylhydrazone

Acetophenone, tech

p-Acetotoluidide

N-Acetylanthranilic acid

p-Acetylbenzene sulfonamide

p-Acetylbenzenesulfonic acid, sodium salt

p-Acetylbenzenesulfony lure thane

N'^-Acetylsulfamethoxypyridazine

N-Acetylsulfanilyl chloride

Adenine

Alkylbenzene

Alkylphenol, mixed

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)-

barbituric acid. Aioinoaceanthryleno[2,l-a]aoeanthrylene-5,13-dione

*4' -Aminoacetanillde ( Acetyl-p-phenylenediamine)

3'-Aminoacetophenone

*5-Amino-2-(p-aminoanilino)benzenesulfonlc acid

l-Amino-'i-(3-amino-'4-sulfoanilino)-2-anthraqulnonesul-

fonic acid. l-Amlno-4-('i-amino-3-sulfoanilino)-2-anthraquinonesul-

fonic acid. 5-Amino-2-anilinobenzenesulfonio acid

*2-(p-Aminoanllino)-5-nitrobenzenesulfonic acid

3-Amino-p-anisanilide

5-Amino-2-o-anisidinobenzenesulfonic acid

*l-Aminoanthraquinone and salt

*2-Aminoanthraquinone and salt

l-Amino-2-anthraquinonecarboxylic acid

l-Amino-2-anthraqulnonesulfonlc acid

5(and 8)-Amino-l-anthraquinonesulfonic acid

N-(4-Amino-l-anthraquinonyl)anthranilic acid

N-(5-Amino-l-anthraqulnonyl)anthranilic acid

l-Amino-N^-anthraquinonyl-2-anthraquinonecarboxamide 4-Aminoantipyrine

*6-Amino-3,4-' -azodi(benzenesulfom.c acid)

8-Aminobenz[a]acridin-7(12H)-one

^l-Amino-'i-benzamidoanthraquinone

*l-Amino-5-benzamidoanthraquinone

ICI. TRC.

DUP.

G, ICI.

CTN,

EKT,

MRK, SAL, SW.

FMP,

UCC.

FMP,

UCC.

FMP,

UCC.

FMP.

GIV.

DUP.

ACP,

UCC.

ACY.

DUP.

LIL.

LIL.

LIL.

ACY.

ACY,

CTN,

MRK,

AHA.

ATR,

MON,

UCC.

G.

LIL.

ICI.

DUP,

G, NAC, TRC.

SDH.

om.

G, TRC, YAW.

TRC.

TRC.

NAC.

CMC,

DUP,

TRC, VPC.

PCW.

TRC.

AAP,

ACY,

DUP, G, ICI, MAY, NAC, TRC

ACY,

DUP,

G, NAC, TRC.

DUP.

G.

ICI.

G.

DUP.

G.

SDW.

AAP,

CM3,

DUP, G, NAC, TRC.

NAC.

ACY,

MAY,

NAC, TRC.

G, ICI, NAC, TRC.

CYCLIC INTERMEDIATES

65

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

6- [p-( p-Ajninobenzamido) benzamido] -l-naphthol-3-sulfonic acid.

i<6-(p-Amlnobenzaiiiido) -l-naphthol-3 -sulfonic acid

3' -Aminobenzanilide

A' -Aminobenzanilide

»2-Amlno-p-benzenedisulfonio acid [S03H=l]

o-Amlnobenzenethiol

2-Aininobenz imidazole

5-Amino-2(3H) -benzimidazolone

p-Aminobenzoic acid, tech

p-Aminobenzoic acid, diethylami noethyl ester (Procaine)

2-Aiiiino-6-benzothiazoleoarboxylic acid

l-Amino-2-bromo-4-('i' -aminoanilino)anthraquinone-5(and 8)-

sulfonic acid. 5(and 8) -Amino-8( and 5) -bromo-l,6(and 1,7) -anthraquinone- disulTonio acid.

*l-Amino-4-bromo-2-anthraquinonesulfonic acid and sodium salt.

l-Amino-4-bromo(benzamdo)anthraquinone

2-Amino-l-bromo-3-chloroanthraquinone

»l-Amino-2-bromo-<i-hydroxyanthraquinone

l-Amino-4-bromo-2-methylanthraquinone

l-Amino-2-bromo-4-(p-toluidino)anthraquinone

l-Amino-2-chloroanthraqulnone

»l-Amino-5-chloroanthraquinone

l-Amino-8-chloroanthraquinone

2-Amino-l-chloroanthraquinone

»2-Amino-3-chloroanthraquinone

A-Amino-6-chloro-m-benzenedisulfonamide

4-Amino-6-chloro-m-benzenedisulfonamide hydrochloride

2-Amlno-5-chlorobenzophenone

2-Amino-6-chlorobenzothlazole hydrochloride

«o-(3-Amino-4-ohlorobenzoyl) benzoic acid

2-Amino-5-ohloro-p-c\imenesulfonic acid

2-Amino-5-ohloro-4-ethylbenzenesulfonic acid

l-Amino-2-chloro-4-hydroxyanthraquinone

2-Amlno-4-ohloro-6-nitrophenol

2-Amino-4-chlorophenol

«6-Amino-4-chloro-l-phenol-2 -sulfonic acid

2-Amino-6-chloropyrazine

3-Amino-6-chloropyridazine

«6-Amino-<*-chloro-m-toluenesulfonic acid [S03H=l]

»2-Amiuo-5-chloro-p-toluenesulfonic acid [S(iH=l]

2-Amino-p-cresol

»l-Amino-2,'4-dibromoanthraquinone

l-Amino-2,4— dibromoanthraquinone-5(and 8) -sulfonic acid—

<i'-Amino-2',5'-diethoxybenzanilide

5-Amino-2-(2,3-dihydro-2-oxobenzimidazol-5-ylamino) - benzenesulfonic acid.

4--Amino-l,3-dihydroxyanthraquinone

2-Amino-4-( dime thy Ibenzyl) phenol

3-Amino-9-ethylcarbazole

p-Amino-N-ethyl-N-l-naphthylbenzamide

2-Aiiilno-N-ethyl-5-nltrobenzenesulfonanilide

Aminoethylpiperazine

l-Amino-4-hydroxyanthraquinone

2-Amino-3-hydroxyanthraqulnone

DUP.

DUP, G, NAC, TRC, VPC.

DUP.

0, TRC.

DUP, G, NAC, TRC.

GAM.

EK.

DUP.

DUP, G.

SDW.

DUP.

ICI.

TRC.

AAP, DUP, G, ICI, NAC, TRC.

AAP.

ICI, MAY.

AAP, DUP, ICC, TRC.

ICI.

G, ICI.

AAP.

ACY, DUP, ICI, MAY, NAC, TRC.

DUP, NAC.

DUP, G.

G, ICI, MAY.

ABB.

ABB.

ICI.

DUP.

AAP, G, ICI, MAY.

SW.

ACY.

AAP.

CMG.

G, MEE, NAC.

CMl, NAC, TRC.

ACY.

ACY.

ACY, DUP, HSC, NAC, SW.

ACY, HSC, SW.

TRC.

AAP, DUP, G, ICI, NAC, TRC.

ICI.

G.

DUP.

G, TRC. TRC. AAP. G. G.

UCC. AAP, G. G, NAC.

66

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B -Cyclic intermediates for which U.S. production or sales were reported, identified by lAauc. ID. y manufacturer, 1 964 Continued

8- K-( 8-Aiiiino-l-hydroxy-3,6-disuLfo-2-naphthylazo) -5- methoxy-o-tolylazo]-l-naphthol-3,6-disulfonic acid,

benzenesuLfonate. l-Amlno-i-[in-(2-hydroxyethylsulfonyl)anilinoJ-2-anthra-

quinonesulfonio acid. 3'-Amino-2'-hydroxy-5'-nitroacetaiillide

2-( 2-Aiiiino-5-hydroxy-7-sulf o-1-naphthylazo) -5-nitro-

benzoic acid. l-(6-Amino-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2-

naphthol-4--suLfonio acid.

S-Amlnoisophthalic acid

2-Aiiiino-N-isopropyl-l-phenol^-suironainide

4-Ainino-3-(|3-methanesuLfanaiiiidoethyl)-N,N-diethylaniline

hydrochloride . N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesuiron-

ajmide. 5-Amino-6-methoxy-2-naphthalenesulfonic acid

m-("i-Aniino-3-methoxyphenylazo)benzenesulfonic acid

8-Ainino-6-methoxyquinoline

l-Amino-2-methoxy-4-(p-toluenesulfonainldo)anthraquinone

3-(4-Amino-5-methoxy-o-tQlylazo)-l,5-naphthalenedisulfonic

acid. 7-(4-Amino-5-methoxy-o-tolylazo)-l,3-naphthalenedisulfonic

acid. . ,„

8-('!K-Amino-5-methoxy-o-tolylazo)-l-naphthol-3,6-disulfonic

acid, benzenesuLfonate.

*4'-Aiiiino-N-methylacetanilide

l-Aniino-2-methylanthraquinone

2-Amino-5-(6-methyl-2-benzothiazolyl)benzenesulfonic acid— A-Mino-4'-(3-methyl-5-oxo-2-pyTazolin-l-yl)-2,2'-stilbene-

disulfonic acid.

2-Aiiiino-5-methylpyridine

2-Ainino-6-metl:^lpyTidine 7 "

2-Ainino-4-methylpyTimidine (2-Amino-4.-methyldiazine)

2-Amino^-Cmethylsulfonyl) phenol

2-Aiiiino-5-methyl-l,3,A-thiadiazole

l-Amlno-2-methyl-A-(p-toluidino)anthraquinone

l-Aminonaphth[2,3-c]aoridan-5,8,14-trione

4-AiBinonaphth[2,3-c]acridan-5,8,lA-trione

6-Aminonaphth[2,3-c]acridan-5,8,li(13H)trione

*2-Aiiiino-l,5-naphthalenedisulfonic acid

»3-Aiiiino-l,5-naphthalenedisuironic acid (Cassella acid)

3-Amno-2,7-naphthalenedisulfonio acid

4-Ainino-l,5-naphthalenedisuironic acid

'i-Amlno-l,6-naphthalenedisulfonic acid

*6-Ainino-l,3-naphthalenedisulfonic acid (Amino I acid)

7-Aniino-l,3-naphthalenedisulfonic acid (Amino G acid)

l-Amino-2-naphthalenesulfonic acid (o-Naphthionlo acid)

*2-Amlno-l-naphthalenesuli'onic acid (Tobias acid)

4(and 5)-Aim.no-l-naphthalenesulfonio acid

5-Amino-l-naphthalenesulfonic acid (Laurent's acid)

*5-Aniino-2-naphthalenesulfonlc acid (l,6-01eve's acid)

*5(and 8) -Aiiiino-2-naphthalenesulf onio acid (Cleve's acid, mixed) .

*6-Amino-2-naphthalenesulfonic acid (Broenner's acid)

»8-Amlno-l-naphthalenesulfonio acid (Peri acid)

*8-Amlno-2-naphthalenesulfonic acid (l,7-Cleve's acid)

7-Amino-l,3,6-naphthalenetrisulfonic acid

8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid)

Manufacturers' identification codes (according to list in table 22)

TRC. TRC.

G.

TRC.

EKT.

DUP.

NAC, TRC. DUP, TRC. SDW. AAP, G. TRC.

TRC.

CM3,

G, NAC.

DUP,

ICI.

G.

TRC.

RIL.

NEP,

RIL.

ACY.

NAC,

TRC.

ACY.

ICI.

DUP.

DUP.

G.

ACY,

SDH,

SW.

G, NAC, TRC.

TRC.

NAC.

DUP.

ACY,

DUP,

G, NAC, TRC.

ACY,

DUP,

G, NAC, TRC

DUP.

ACY,

HSC,

IMP, SW.

ACY,

TRC.

DUP.

ALL,

DUP,

G, NAC, TRC

ALL,

DUP,

G, NAC, TRC

KLS

NAC,

SNA.

DUP,

NAC,

SDC, TRC.

ALL

DUP,

G, NAC, TRC

DUP

DUP

NAC.

CYCLIC INTERMEDIATES

67

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

4--Amino-l,3,5-naphthalenetrisulfonio acid, 4,5-sultam,

trlsodium salt. 8- Amino-l- naphthoic acid

5-Amino-l-naphthol

5 (and 8)-Amino-2-naphthol

»8-Amino-2-naphthol

8-JSniino-l-naphthol-3,6-diEulfonio acid, benzenesulfonate- 7-Amino-l-naphthol-3,6-disulfonic acid (2R acid), mono- sodium salt. *8-Amino-l-naphthol-3,6-disulfonic acid (H acid), mono- sodium salt. 8-Anino-l-naphthol-5,7-disulfonic acid (Chicago acid) (2S acid), monosodium salt.

»l-Aiiino-2-naphthol-4-sulfonic acid (1,2,4-acid)

*6-Aiiino-l-naphthol-3-sulfonic acid (J acid), sodium salt- *7- Amino- l-naphthol-3-sulfonic acid (Gamma acid), sodium salt. 8-Amino-l-naphthol-5-sulfonic acid (S acid), sodium salt-

3-Jtoiino-5-(m-nitrobenzamido)-p-toluenesulfonic acid

*2-Mino-5-nltrotienzenesulfonic acid[S03H=l]

4-Amino-3-nitrobenzoic acid

*2- Amino— 4-nitrophenol

2-Amino-5-nitrophenol

4--Amino-2-nitrophenol

i -2- Amino-l- (p-nitrophenyl)-l,3-propanediol

4-Amino-4-'-nitro-2,2'-stil'benedisulfonic acid

2-Amino-5-nitrothiazole

3'-Aminooxanilic acid

4' -Aminooxanilio acid

3-Amino-2-oxazolidlnone

p-Aminophenethyl alcohol

5-Amino-2-o-phenetidinobenzenesulfonio acid, sodium salt-

o-Aminophenol

p-Aminophenol

*2-Amino-l-phenol-4-sulfonamide

2-Amino-l-phenol-4-sulfonanilide

*2 -Amino- l-phenol-4-sulfonic acid

m-(p-Aminophenylazo)benzenesulfonio acid

*p-(p-Aminophenylazo)benzenesulfonic acid

7-(4-Aminophenylazo)-l,3-naphthalenedisulfonic acid

5-(p-Aminophenylazo) salicylic acid

2-(p-Aminophenyl)-6-methylbenzothiazole

2-(p-Aminophenyl) -6-methyl-7-benzothiazolesulfonic acid and salt.

l-(m-Aminophenyl) -5-oxo-2-pyrazoline-3-carboxylio acid

2-Aminopyridine

4-Aminopyridine

2-Aminopyrimidine

3-Aminoquinoline

5-Aminosalicylio acid

N-(4-Amino-3-sulfo,anthraqulnonyl) anthranilio acid

3'-(3-Amino-4-sulfophenylsulfamoyl)-3"-sulfamoyl-3- phthalocyaninesulfonic acid, copper derivative.

2-Aminothiazole

3-Amino-p-toluamide

l-Amino-4- (p- toluene sulfonamido) -2- anthraquinonesulf onic

acid. l-Amlno-4-(p-toluenesulfonamido)-2-anthraquinone sulfonic

acid, sodium salt. 5-Amino-o-toluenesulfonanilide

Manufacturers' identification codes (according to list in table 22)

G.

NAG

G.

ALL,

CMG

DUP, G, TRC, VPC

TRC.

DUP,

NAC.

DUP,

MON,

NAC.

DUP,

NAC.

ACY,

G, NAC, TRC, VPC.

CMG,

DUP,

G, NAC, TRC.

DUP,

G, NAC, TRC.

NAG.

G.

ACY,

DUP,

G, NAC, TRC.

DUP.

DUP,

G, NAC, TRC.

NAC.

ACY.

PD.

DUP,

NAC,

TRC.

ACY,

EKT.

CMG.

DUP.

NOR.

EKT.

NAC.

FMT.

ABB,

DUP,

SDC.

CMG,

DUP,

NAC, TRC, VPC.

TRC.

AAP,

CWN,

DUP, NAC, TRC.

AAP,

TRC.

ACY,

CMG,

DUP, G, NAC, TRC.

TRC.

VPC.

DUP,

NAC.

DUP,

TRC.

VPC.

NEP,

RIL.

RIL.

ACY.

EK.

AAP,

TRC.

G.

DUP.

ACY,

MRK.

SDH.

AAP.

DUP, G.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE IB. -Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i964~Continued

Chemical

*4-Andno-m-toluenesulfonie aoid[S03H=l] -----

»6-Amino-m-toluenesulfoiiio acid [S03H=1]

5-Amino-2-(p-toluidino)benzenesulfonic acid

m-(4-Amino-3-tolylazo)'benzenesulfonio acid

3- (4-Amino-o-tolylazo) -1, 5-naphthalenedisulf onic acid

A-U-Amino-m-tolylazoi-m-toluenesulfonic acid

*16-Aininoviolaiithrone

»2-Amino-3,5-xylenesiilfonio acid [S03H=1J

5-Ajm.no-2,4-xylenesulfonic acid -•

<;-Amino-2,6-xylenol

■^Aniline (Aniline oil) "'

Aniline hydrochloride ~

l-Anilino-2-anthraquinonecar"boxylic acid

*Anilinomethanesulfonic acid and salt ---

*8-Anilino-l-naphthalenesulfonlc acid (Phenyl pen aoidj

«6-Anilino-l-naphthol-3-sulfonio acid (Phenyl J acid)

7-Anilino-l-naphthol-3-sulfonic acid (Phenyl gamma acid

Anisic acid

o-Anisic acid

m-Anisidine

*o-Anisidine

p-Anisidine

l-p-Anisidino-A-hydroxyanthraquinone

«o-Anisidinomethanesulfonio acid

2-o-Anisidlno-5-nitrobenzenesulfonic acid

p-Anisoin

Anisole, tech

Anthracene, refined "

Anthraflavic acid (2,6-Dihydroxyanthraq\u.none) --

Anthranilic acid (o-Aminobenzoic acid)

*Anthra[l,9]pyrazol-6(2H)-one (Pyrazoleanthrone)

*Anthraquinone , 100^

2-Anthraquinonecar'boxylio acid

*1, 5-Anthraquinonedisulf onic acid

1,5-Anthraquinonedisulfonic acid, disodium salt

1 5(and 1,8)-Anthraquinonedisulfonio acid and salt

1,8-Anthraquinonedisulfonic acid

»l,8-Anthraq\iinonedisulfonic acid, potassium salt

*2,6-Anthraquinonedisulfonic acid and salt

*l-Anthraquinonesulfonic acid and salt

2-Anthraquinonesulfonic acid and salt (Silver salt)

l,l'-[l,5(!"i<J 1,8) -Anthr aqulnonylenediamino] bisnaphth- ' [2,3-c] aoridan-5,8,U-trione.

N,N'-(1,5-Anthraqulnonylene)dianthranilio acid

N,N '-(l,5-Anthraquinonylene)dioxamic acid

l-(l-Anthraquinonyl) -1,2-hydrazinedisulf onic acid, disodium salt.

*Anthrarufin (1,5-Dihydroxyanthraquinone)-

Anthrone

Arsanilio acid and salt, tech

4', 4' ' '-Azobis [4-biphenylcarboxylic acid]

Barbituric acid

Barbituric acid, sodium derivative :

«Benzaldehyde , tech -

4-(4-Benzamido-l-anthraquinonylamino)naphth [2,3-oJ -

acridan-5 ,8, K-trione . N-(5-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide-

l-Benzamido-4-chloroanthraquinone

*l-Benzamido-5-chloroanthraquinone

Manufacturers' identification codes (according to list in table 22)

ACY, DUP, G, SDH, SNA.

DUP, HSC, MAC, SW.

DUP, MAC, TRC.

TRC.

TRC.

MAC.

ACY, G, TRC.

DUP, NAC, SDH, STG, WJ.

DUP.

UPJ, X.

ACY, DOW, DUP, NAC.

ACY.

NAC.

AAP, ACY, DUP, NAC, TRC.

CMG, DUP, NAC, SDC.

ALT, CMG, DUP, G, NAC, TRC.

DUP, G, NAC.

HN, ICO.

ACY.

EK.

AAP, ALL, DUP, KIS, MON.

DUP, HON.

AAP.

AAP, DUP, G, NAC, TRC, VPC.

TRC.

CTN.

DUP, LIL.

ACP.

DUP, G, TRC.

DUP, LEM, MKE, NAC.

DUP, G, TRC.

ACY, DUP, G, TRC.

ACY, NAC.

ACY, DUP, ICI, TRC.

DUP, G, TRC.

DUP, TRC.

DUP.

G, ICI, TRC.

AAP, DUP, G, ICI, NAC, TRC, VPC.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

DUP, NAC.

DUP.

DUP, ICI. G, MEE, TRC. DUP, G.

ACY, CMG, DUP, G, NAC, TRC.

ICI.

ABB.

DUP, G, TRC.

KF, LIL.

ABB, KF.

BPC, HN, TNP.

DUP.

ICI.

DUP, G.

ACY, DUP, G, ICI, MAY, NAC, TRC.

CYCLIC INTERMEDIATES

69

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

l-(4-Benzamido-2,5-diethoxjrphenyl)-3-methyl-3-(2-sulfo-

ethyl) triazene. [ 3- (4-Benzaniido-6-methoxy-ni-tolyl ) -l-methyltriazen-3-yl] - acetic acid.

8-Benzamido-l-naphthol-3,5-disulfonic acid

3-Benzamido-l-naphthol-3-sulfonic acid

Benzanilide

*7H-Benz [de] anthraoen-7-one ( Benzanthrone )

Benzeneboronic acid

m-Benzenedisulfonic acid

Benzenesulfonamide

Benzenesulfonic acid

Benzenesulfonio acid, 2-propyn-l-ol ester

Benzenesulfonyl chloride "

1,2,4— Benzenetrioarboxy lie acid, 1,2-anhydride

Benzhydrol (Diphenylmethanol)

Benzidine base

^Benzidine hydrochloride and sulfate

Benzil (Bibenzoyl)

Benzilic acid

2-Benzofuranacetonitrile

^Benzoic acid, tech

Benzoic anhydride

Benzoin

Benzonitrile

Benzophenonetetracarboxylic dianhydride

Benzo[b] thiophen-3(2H)-one

IH-Benzotriazole

Benzoylacetio acid, ethyl ester

»o-Benzoylbenzoic acid

Benzoyl chloride

'i-Benzoyl-3-hydroxyphenyl methacrylate

2-Benzoyl-'4-sulfobenzoic acid

2-Benzoyl-4' -(p-toluenesulfonanildo)acetanilide

Benzylamine

dl-Benzyl-2-aid.no-l-propanol

<+-Benzyl-6-chloro-3-keto-2-methyl-7-sulfamyl-l,2,4-benzyl-

thiadiazine-1, 1-dioxide . 4-Benzyl-6-chloro-3-keto-7-sulfamyl-l,2,4-benzylthia- diazine-1, 1-dioxide.

Benzyl disulfide

Benzylethanolamine

Benzyl ether (Dibenzyl ether)

4-(N-Benzyl-N-ethylamino)-o-toluenesulfonio acid

N-Benzyl-N-ethyl-m-toluidine

Benzylidene phthalide

4- Benzylidineiminoantipyrine

p-(Benzyloxy)phenol

Benzyl polysulfide

Benzyltrimethylammonium hydroxide

Benzyltrimethylammonium methoxide

*3,3'-Bianthra[l,9]pyrazole-6,6'-(2H,2'H)dione (Fyrazole- anthrone yellow) . [3,3'-Bi-7H-benz[de] anthracen] -7,7' -dione

*[4,4'-Bl-7H-benz[de] anthracen] -7,7' -dione

endo-cis-Bicyolo[2.2.1]hept-5-ene-2,3-dloarboxyllc anhydride .

*[1,1' -Binaphthalene]-8,8'-dicarboxyllc acid

Biphenyl

2,2',4,4'-Biphenyltetrol

Manufacturers ' identification codes (according to list in table 22)

ACY, ATL, CMG, DUP, G, ICI, MAY, NAG, SDC, TEC.

G.

TRC TRC DUP

AAP;

EDO- KPT NES, EK, ABB, NES. ACC. ARAj MAC, OWN, HN,

BPG;

EK.

ACC;

EK.

BPC,

TNP,

GOG.

G.

MEE.

FMP.

ACY,

HK,

X.

DUP.

EK.

ICO,

LIL.

ABB.

ABB.

GCW.

MLS.

BPC, TBK.

NAC.

DUP, NAC.

LIL.

SDW.

EK.

HK.

MLS.

MLS.

DUP, G, TRC.

DUP.

ACY, DUP, ICI, MAY.

MAC.

DUP, G, NAC. DOW, MON. IDC.

FIN, LAK, NAC, X.

LEM. LEM.

FRO, HK, HN, MON, TNP.

HN.

DUP, G, NAC. HN, TNP.

70

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers' Identification codes (according to list in table 22)

2,2' -Biquinoline

»l,4--Bis[l-anthraquinonylamino]anthraquinone

Iji-Bis [l-anthraquinonylamino] anthraquinone and

1,4— Bis [ 5 -chloro-l-anthraquinonylamino] anthraquinone

(mixed) .

1,5-Bis [1-anthraqulnonylamino] anthraquinone

Bis[l-anthraquinonylamlno] violanthrene

a^,a^ -Bis[5-tert-butyl-6-hydroxy-ra-tolyl] mesitol

N,N' -Bis[l-chloro-2-anthraquinonyl] -4' ,4" ' -azol)is-[4-bi-

phenylcarboxamlde] . Bis(chloro sulf onyl)phthalocyaninedisulfonic acid, copper

derivative .

4,4' -Bis[diethylamino]benzhydrol

4,4' -Bis[diethylamino]benzhydrol, 2,6-naphthalene-

disulfonate. 4,4' -Bis [diethylamino]benzhydrol salt, 2,7-naphthalene-

disulfonic acid mixture.

4,4' -Bis[diethylamino]benzophenone (Ethyl ketone base)

4-Bis [ ( p -die thy laminophenyl) methyl ] -2 , 7-naphthalene -

disulfonic acid, leuco form.

4,4' -Bis[dimethylamino] benzhydrol (Michler's hydrol)

*4,4' -Bis[dimethylamino] benzophenone (Michler's ketone)

Bis[p-dimethylaminophenyl]methanesulfonic acid and salt l,5(and 1,8) -Bis[2,4-dinitrophenoxy ]-4,8(and 4,5)-di-

nitroanthraquinone . 4,4' -Bis[p-hydroxyphenylazo]-2,2' -stilbenedisulfonic acid-

4,4' -Bis[p-hydroxyphenyl]valeric acid

2,4-Bis(methylsulfamyl)-5-chloroaniline

Bis (o-nitrophenyl) sulf ide

m-Bis(m-phenoxyphenoxy) benzene

2-Bromoaoetophenone

p-Bromoaniline

4-Bromoanlsole

*3-Bromo-7H-benz[de]anthracen-7-one (Bromobenzanthrone)

Bromobenzene , mono-

p-Bromobenzenesulf onyl chloride

Bromobenzoic acid

o-Bromobenzoic acid

4 -Bromobenzophenone

6-Bromo-5-chlorobenzoxazolone

2 -Bromo-6-chloro-4-nitro aniline

Bromocyclopentane

2-Bromodibenzofuran

2-Bromo -4, 6-dinitro aniline

Bromoethylbenzene

2-Bromo-3'-hydroxyacetophenone, benzoate

l-Bromo-4-(N-methylacetamido) anthraquinone

l-Bromo-4-me thy laminoanthraqui none

6-Bromo-3-methyl-7H-dibenz[f ,ij] isoquinQline-2,7(3H) -

dione.

1-Bromonaphthalene

4-Bromonaphthalic anhydride

l-(9-Bromo-7-oxo-7H-benz[de] anthracen-3-ylamino) anthra- quinone .

p-Bromophenol

(p-Bromophenyl)aoetonitrile

(p-Bromophenyl) hydrazine hydrochloride

2-Bromopyridine

ACY, DUP, G, MAY, NAC, TRC. TRC.

DUP, NAC.

DUP, TRC.

SDH. TRC.

SDH.

DUP, G, NAC, SDH.

NAC.

DUP.

TRC. JNS.

ICO, OPC.

ACY, DUP, G, MAY.

DOW.

EK.

RSA.

EK.

ICO.

MEE.

AAP.

UL.

G.

TRC.

DOW.

SDH.

G.

AAP, DUP, G.

G.

CYCLIC INTERMEDIATES

■Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , i 554— Continued

a-Bromotoluene

p-Bromotoluene

l-Bromo-2,'i,6-triethylbenzene

p-Butoxyphenol

<i-[3-(p-Butoxyphenoxy)propyl] morpholine

4-'-Butoxy-2-piperidinopropiophenone hydrochloride

p-n-Butylaminobenzolc acid, ethyl ester

p-Butylaniline

2-tert-Butylanthraquinone

p-tert-Butyltenzaldehyde

n-Butylbenzene

seo-Butylbenzene

tert-Butylbenzene

p-tert-Butylbenzoio acid

o-(p-tert-Butylbenzoyl)benzoic acid

6-Butyl-m-cresol [OH=l]

6-tert-Butyl-m-cresol

2-tert-Butyl-p-cresol

2' -tert-Butyl-4-' ,6'-dimethylacetophenone

2-tert-Butyl-4-ethylphenol

N'-Butyl-'i-methoxymetanilamide

N'''-Butyl-4--methoxymetam.lamide

2-tert-Butyl-5-methylamsole

»o-seo-Butylphenol

p-seo-Butylphenol

o-tert-Butylphenol

p-tert-Butylphenol

Butylphenols, mixed

p-tert-Butyltoluene

5-tert-Butyl-l,2,3-triinethylbenzene

5-tert-Butyl-m- xylene

6-tert-Butyl-2,4-xylenol

Butyrophenone

^Camphoric acid

Camphoric anhydride

Camphosulfonic acid

Carbazole, refined

Carbonic acid, diphenyl ester

1- (4- Carbonyl-o- anisyl) -3-methyl-3- ( 2-sulf oethyl) triazene-

2,4- '-Carbonyldibenzoic acid

6(and 2 ) - Carboxybenzene-2 ( and <V)-diazo-l-oxide

5 -(o-Carboxybenzoyl)-2-ohlorooxanilic acid

3-Carboxy-2(and 4)-hydroxybenzenediazonium sulfate

3-(Carboxymethyl-3-methyl)-l-p-tolyltriazene

o-(Carboxymethylthlo)benzoio acid

5-(o-Carboxyphenylsulfamoyl)anthranilic acid

[ (o-Carboxyphenyl)thio]ethylmercury

3-(2-Carboxy-4-sulfophenyl)-l-(2,5-dichlorophenyl)-

3-ethyltriazene. 3-(2-Carboxy-<t-Eulfophenyl)-l-(5-dimethylsulfamoyl-o-

tolyl) -3-methyltriazene. 3-(2-Carboxy-4-sulfophenyl)-3-ethyl-l-(5-nitro-o-aniEyl)- triazene.

Cedrene

Chelidamic acid

Chlorendic acid

2'-Chloroacetoacetanilide

ci-Chloroacetophenone

2'-Chloroacetophenone

3'-Chloroacetophenone

4' -Chloroacetophenone

4' -(Chloroaoetyl)acetanilide

m-Chloroaniline

o-Chloroaniline

p-Chloroaniline

Marnif acturers ' identification codes (according to list In table 22)

BPC,

EK.

BPC.

DUP.

ABB.

ABB.

ICO.

ICO.

DUP.

DUP.

GIV.

PLC.

PLC.

PLC.

SHC.

DUP.

KPT.

PIT.

ACY.

GIV.

ACY.

KLS.

G.

GIV.

DOW,

PRD,

TNA.

DOW.

TNA.

DOW,

KPT,

PRD, UCP

DOW.

GIV,

SHC.

GIV.

GIV,

x.

KPT,

PIT.

TBK.

FIN,

OTC,

PYL.

FIN,

OTC.

OTC,

PYL.

SDC.

BKL.

G.

ACY. DUP.

G, NAC.

TRC. LIL.

G.

G.

GIV.

SDW.

HK.

FMP, UCC.

EK.

EK.

RBC.

LIL.

DUP.

DUP, G.

DUP, MON.

DUP, MON.

72 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , i 564— Continued

2-(Chloroamllno)ethanol

3-(o-Chloroaiiilino)propionitrile

5-CM.oro-o-anisidlne [NH2=l] (4-Chloro-o-amsidlne

[0CH3=l] ) .

5-Chloro-o-£misldine hydrochloride

/i-Chloroanthranillo acid

*l-Chloroanthraquinone

*2-Chloroanthraquinone

m-Chlorobenzaldehyde

o-Chlorohenzaldehyde

p-Chlorobenzaldehyde """

Chloro-7H-benz[ de ] anthrao en-7-one ( Chlorobenzanthrone )

*Chlorobenzene , mono-

l-Chlorobenzene-4-niethylsulfone

4-Chlorobenzenesulfinic acid

p-Chlorobenzenesulfonamide

l-(4-Chlorobenzhydrol)-4-methylpiperazine

o-Chlorobenzoic acid

5-Chloro-2-benzoxazolinone

»o-(p-Chlorobenzoyl)benzoic acid

o-(p-Chlorobenzoyl) chloride

p-Chlorobenzoyl chloride

4,<i'-(o-Chlorobenzylidene)di-2,5-xylidine

Chloro-(p-chlorophenyl)phenylmethaiie

Chlorocyolohexane

2-Chloro-l,4-dibutoxy-5-nitrobenzene

2-Chloro-l,A-diethoxy-5-nitrobenzene

2-Chloro-N,N-diethyl-4-nitroamllne

N- (3-Chloro-9 ,10-dihydroxy-2-aiithryl) acetamide-bis [ acid sulfate] .

A' -Chloro-2' ,5' -dimethoxyaoetoacetanilide

4-Chloro-2,5-dimethoxyamline

5-Chloro-2,4-dimethoxy aniline

4-Chloro-N,N-diinethyl-3-nitrobenzenesulfonamide

5-Chloro-4,7-dimethyl-3(2H)-thiaiiaphthenone

»l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene )

l-Chloro-2,4-diiiitrobenzene and 2-chloro-l,3-dim.tro- benzene mixtiire.

3-Chloro-4,6-dinitrobenzenesulfonio acid

3-Chlorodiphenylainine

Chlorodiphenylmethane

a-Chloro-o(aiid/or p ) -dodeoyltoluene [CH3=l]

4-[(2-Chloroethyl)ethylamino]-o-tolualdehyde

p- [(2-Chloroethyl)methylaiiiino]benzaldehyde

2-Chloro-N-ethyl-5-nitrobenzenesulfonanilide

Chloroformio acid, benzyl ester

Chloroformlc acid, phenyl ester

4-Chloro-3-hydrazinobenzenesulfonic acid

l-Chloro-4-hydroxyaiithraquinone

5'-Chloro-3-hydroxy-2-naphthol-o-anlsidide

3-Chloro-4-hydroxyquinoline-3,4-carbonio acid

6-Chloroisatoic anhydride

o-Chloro-a-[ (isopropylamino) methyl] benzyl alcohol hydrochloride .

4-Chloro-N-isopropyl-3-nitrobenzenesulfonamide

5-Chlorometanilio acid

»6-Chlorometanilic acid

5-Chloro-2-methoxybenzenediazonium chloride

Manufacturers' identification codes (according to list in table 22)

EKT. DUP. BUG, KI£.

DUP.

ACT, DUP, G, ICI, MA.Y, NAG, TRC.

ACY, G, NAG, TRC.

RSA.

HN, NAG, SDH.

HN.

AGY, DUP.

AGS, DOW, DUP, GGY, HK, HKD, M3N, IfTO, QMC, PPG.

TRG.

TRC.

ACY.

ABB.

HN, SDH.

AGY, DUP, G, IGI, NAG.

HN.

HN.

G.

OPG, TBK.

ACY.

FMT.

FMT, G.

DUP.

PCW.

PGW.

ALL, PCW.

EEC, G.

NAG.

AAP, DUP, NAG,

DUP.

TRG. SK. TBK. ORO.

G.

RSA.

EK.

G.

ICI.

PGW.

SDH.

MEE.

LIL.

TRG. NAG. AAP, DUP,

CYCLIC INTERMEDIATES

73

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964— Continued

ilamifacturers ' identif loatlon codes (according to list in table 22)

N-(5-Chloro-2-methoxyphenylazo)saroosine

»l-Chloro-2-methylanthraquinone

6-Chloro-2-methyl-7-ohlorosulfamoyl-2H-l,2,4-benzo- tM.adiazin-3(4H)-one, 1,1-dioxide.

l-(Chloromethyl)-2,'i-dimethylbenzene

A-(Chloromethyl)-l,2-dimetl^lbenzene

S-Chloro-l-methylisatoic anhydride

6-Chloro-2-methyl-7- (N-methylsulf amoyl) -2H-l,2,<i-benzo- thiadiazin-3(4H)-one, 1,1-dioxide.

a-Chloromethylnaphthalene

<i-Chloro-3-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- sulfonic acid.

2-Chloro-5- ( N-methylsulf amoyl)sulf anllami de

5-Chloro-2- ( n-methyl ) -sulf ainyl-4-sulf amyl-n-benzylaniline-

Chloronaphthalenes

»2-Chloro-4-nitroaniline (o-Chloro-p-nitroaniline)

4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline)

*l-Chloro-5-nitroanthraquinane

»l-Chloro-8-nitroaiithraquinone

*l-Cliloro-2-nitrobenzene ( Chloro-o-nitrobenzene )

l-Cliloro-2(and 4-) -nitrobenzene (Chloronitrobenzenes, o- and p-) .

*l-Chloro-3-m.trobenzene (Chloro-ra-nitrobenzene)

*l-Cliloro-4-nitrobenzene ( Chloro-p-nitrobenzene )

*4-Chloro-3-nitrobenzenesulf onaTni de

<i-Chloro-3-nitrobenzenesulfouaiiilide

2-Chloro-5-m.trobenzenesulfonio acid

2-Chloro-5-nitrobenzenesulfonic acid, sodium salt

4— Cliloro-3-nitrobenzenesulfonic acid

■>«4-Chloro-3-nitrobenzenesulfonyl chloride

2-Chloro-4— nitrobenzoic acid

2-Chloro-5-nitrobenzoic acid

*o-('i— Chloro-3-m.trobenzoyl)benzoic acid

4-Chloro-2-nitrophenol

'i-Chloro-6-nitro-l-phenol-2-sulfonic acid

4-Chloro-3-nitrophenyl methyl sulfone

2-Chloro-4-nitrotoluene

2-Chloro-6-nitrotoluene

»4-Chloro-2-nitrotoluene

4-Chloro-3-nitrotoluene

m-Chlorophenol

o-Chlorophenol

p-Chlorophenol

2-Chlorophenothiazine

p-Chlorophenylacetonitrile

4— Chloro-(x -phenyl-o-cresol

4- Chloro-o-phenylenediamine

3-(o-Chlorophenyl)-5-methyl-4-isoxazole carbonyl chloride

3-(o-Chlorophenyl) -5-methyl-4-isoxazolecaj:"boxylic acid

l-(m-Chlorophenyl)-3-methyl-2-pyrazolin-5-one

2-Chloro-4-phenylphenol

p-Chlorophenyl-2-pyridyl carbinol

4-Chlorophthalic acid

Chlorophthalic anhydride

l-(3-Chloropropyl)-4-methylpiperazine

N'''-(6-Chloro-3-pyTidazinyl)sulfanilamide

AAP,

ACY,

CMG, G, ICI, NAG, TRC

ABB.

BPC.

BPC.

MEE.

ABB.

BPC.

DUP,

G.

ABB.

ABB.

G, KPT.

ACY,

DOW,

DUP, HSG.

DOW,

DUP,

VPC.

ACY,

DUP,

MAY, NAG, TRC.

DUP,

MAY,

NAG.

AAP,

DUP,

MON, UPM.

AAP,

SDC.

DUP,

G, MDN, UPM.

AAP,

DUP,

MDN, UPM.

AAP,

DUP,

EKT, G, ICG, TRC.

TRC.

CMG,

MAC.

DUP,

G.

G, HAG.

AAP,

DUP,

EKT.

SAL.

TRC.

AAP,

G, ICI, MAC.

DUP,

MEE.

TRC.

TRC.

DUP.

DUP.

AAP,

BUG,

DUP.

AAP,

BUG.

EK.

DOW,

MDN.

DOW,

ION.

SK.

ICO,

TBK.

mn.

mr.

ICO.

ICO.

TRC.

DOW.

RIL.

DUP,

SW.

HK.

SK.

ACY.

74

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B -Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i 564— Continued

2-Chloropyridine """^

2-Chloroquinlzarin

7-Chloro-'i-quinollnol

4— Chlororesorcinol

2-Chloro-5-sulfamoylbenzoic acid

8-Chlorotheophylline

2-Chlorothiaxanthenone

2-Chlorothiophene

m-Chlorotoluene

o-Chlorotoluene

p- Chlorotoluene

*o-Chlorotoluene (Benzyl chloride)

l-Chloro-S-p-toluenesulfonamidoanthraqulnone

6-Chloro-m-toluldlne

3-Chloro-o-toluidine [NH2=1]

4-Chloro-o-toluidine [NH2=l] an<i l^'^^°°h^°='^'^?::'"""';""::T *5-Chloro-o-toluldlne [NH2=l] (-V-Chloro-o-toluidme [CH3=1] )

*5-Chloro-o-toluidine hydrochloride [NH2=1] """

3-Chloro-p-toluidine [NH2=1]

N-(5-Chloro-o-tolylazo)sarcoslne

Chloro-p-tolylmercury

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one

l-(5-Chloro-o-tolyl)-l-tetrazene

(4-Chloro-o-tolylthio) acetic acid

3-Chloro-a ,a ," -trlf luoro-6-nitrotoluene

4.-Chloro-a,a,a-trlfluoro-3-nitrotoluene

p-Chloro-a,a,a-trifluorotoluene

2-Chloro-l,3,5-trinitrQbenzene

Chlorotriphenylmethane

a-Chloro-p-xylene

2-Chloro-p-xylene

A-Chloro-2,5-xylenesulfonyl chloride

4-Chloro-3,5-xylenol

6-Chloro-3,'i-xylylmethylcarbainate

4-Chloro-2,5-xylylthioacetic acid

Cholic acid

Chrysazin (1,8-Dihydroxyanthraquinone)

Cinnamoyl chloride

s-Collidine (2,4,6-Trimethylpyridine)

*Cresols:-'-

m-Cresol

o-Cresol:

From coal tar

From petroleum

p-Cresol

Cresols, mixed: ■"■ *(m,p)-Cresol:

From coal tar

From petroleum

*(o,m,p)-Cresol:

From coal tar

From petroleum

2,3-Cresotic acid

»Cresylic acid, refined: ■"■

*From coal tar

*From petroleum

See footnote at end of table.

Manufacturers ' identification codes (according to list in table 22)

FMI,

NEP.

iSR.

SDW.

AAP,

G.

TRC.

MAL.

KF.

am.

HK.

HN.

HN.

BPC,

HK, HN, MON, TNP.

ICI.

BUG.

DUP.

AAP,

PCW.

AAP,

BUG,

DUP, NAC, SDH

ATL,

AUG,

BUG, KLS, SDH

DUP.

ATL,

BUG,

G.

EK.

TRC.

G.

NAG.

MEE.

G.

HK.

EK.

EK.

BFG.

DUP.

G, NAG.

OTA.

UPJ.

NAG.

SRL,

WIL.

DUP,

G.

TBK,

X.

KPT,

NAG,

RIL.

KPT.

KPT,

PRD.

MER,

NPC,

PRD, SW.

ACY,

HPC,

SW.

AGP,

KPT,

PIT, PRD.

MER,

NPC,

PRD.

AGP

KPT.

PIT

PRD.

DOW

AGP, KPT, PRD.

MER, NPC, PIT, PRD, SHO, SM.

CYCLIC INTERMEDIATES

75

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers' identification codes (according to list in table 22)

Cryptocyanine

*Cuinene

2-[p-(2-Cyanoacetiiiiido) phenyl] -6-methyl-7-benzothiazole- sulfonic acid.

N-(P-Cyanoethyl) -N-(P-aoetoxyethyl) aniline

4--[(2-Cyanoethyl)ethylamino]-o-tolualdehyde

p-[(2-Cyanoethyl)methylamino]benzaldehyde

8-Cyano-l-naphthalenesulfonic acid

Cyanuric chloride

*Cyclohexane

1,4--Cyolohexanedicarboxylic acid, dimethyl ester

1,2-Cyclohexanedicarboxylic anhydride

1,2-Cyclohexanedione

*Cyclohexanol

*Cyclohexanone

Cyolohexanone oxime

Cyclohexene

4--Cyolohexene-l,2-dicarboxiiiiide

4-Cyolohexene-lj2-dicarboxylic anhydride

Cyolohexylamine

p-Cyelohexyloxy benzoic acid

Cyolohexyl-2-propanone

N-Cyclohexyltaurate, sodium salt

Cyclopentanepropionic acid

Cyclopentanol

Cyclopentene

(2-Cyclopenten-l-yl) -2-propanone

Cyolopentylphenylglycolic acid, methyl ester

p-Cymene

Cytosine arabinoside hydrochloride

Decylbenzene

Decylphenol

Dehydroaoetic acid, sodium salt

Desoxycholic acid

l,5(and 1,8) -Diacetamidoanthraquinone

3'-[Di(2-acetoxyethyl)-aminQ]-p-acetophenetidide

<+,4'-Diaoetylamino-3,3'-dinitrobiphenyl

N,N-Diaoetyl-4,4' -diaminobiphenyl

N,N-Diallyloamphoramic acid

N^,N^-Diallylmelamine

«1,4— Diaminoanthraquinone

*l,5-Diaminoanthraquinone

l,5(and 1,8) -Diaminoanthraquinone

*2,6-Diaminoanthraquinone

l,4-Diamino-2,3-anthraquinonedicarbom.trile

l,"i-Diamino-2,3-anthraquinonedicarboximide

4,8-Diaininoanthrarufin

3,3'-Diaminobenzanilide

3,4--DiaMnobenzanilide

2,4-Diaminobenzenesulf onic acid [S03H=l]

2,5-Diaminobenzenesulfonic acid [s03H=l]

*4,4'-Diamino-2,2'-biphenyldisulfom.o acid ■■

3,7-Diaminodibenzothiophenedisulfonic acid, 5,5-dioxide, disodium salt.

Diamlnodibromodi-p-toluidinoanthraquinone

l,4-Diamino-2,3-dichloroanthraquinone

l,5-Diamino-4,8-dihydroxyanthraquinone

l,5(and l,8)-Diamino-4-,8Cand 4-,5)-dihydroxyaiithraquinone

4,5-Diamino-l,8-dihydroxyanthraquinone

4, 8-Diamino-l,5-dihydroxy-2,6-anthraquinonedisulf onic acid 4,4'-Diamino-3,3' -dimethyltriphenylmethane

ACC, ACP, CLK, DOW, GOG, HPC, PLC, SHC, SKO, SOG, TX. DUP.

EKT.

DUP, G.

DUP, G.

DUP, G.

AGY, GGY, NIL.

CO, DUP, GOG, PLC, PRO, SOG.

X.

NAC.

RSA.

DUP, MON, NAC.

DBC, DUP, MON, NAC.

NAC, X.

KF, PLC.

CHO.

NAC, PTT.

ABB, JCC, PAS, VGC, X.

LIL.

GIV, TBK.

G.

AHA.

LIL.

PLC.

LIL.

AHA.

HNW, HPC, NAC.

UP J.

NAC.

G.

GAN.

WIL.

AAP.

TRC.

AAP.

AAP.

wn.

AGY.

CMl, DUP, G, NAC, TRC.

DUP, G, TRC.

AAP, TRC.

AAP, DUP, G, NAC, TRC, VPC.

DUP.

DUP.

G, ICC.

AAP.

AAP.

DUP, NAC, TRC.

TRC.

AAP, ACY, NAC.

AGY.

ICI.

cue, DUP.

VPC.

DUP.

ICI.

TRC.

ACY.

76

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B.

- Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i554~Continued

l,4-Dlamino-5-nitroanthraquinone

2,'i-Dlaiiiino-6-phenyl-s-triazine

2,6-Dlainlnopyridine

Mj-i'-Diamino-aja' -stilbenedisulfonlc acid

Diaminotetrabromoanthraqulnone

4.,6-Diamino-m-toluenesulfomc acid [SOjHil]

3,5-Diainino-p-toluenesulfonic acid [S03H=1]

Di-tert-amylphenoxyacetyl chloride

1, 5-Diaiiilino-2,5-aiithraquinonedicarboxylic acid

o-Dianisidine

N-(o-Dianisidine)methyltaurine

l,2-Dianthroiiyl-l,2-ethanediol

Diary Iguanidine

p- Di azo- N, N- dime thy lani line- 1- aniino-8-naphthol-3- sulfonate-6-sulfonic acid, sodium salt.

1,5-Dibenzaiiiidoanthraquinone

4,9-Dibenzamido-3' ,4' ,6' ,7' -diphthaloyloarbazole

*i,5'-Dibenzaiiiido-l,l'-iminodlanthraquinone

5,5'-Dibenzamido-l,l' ,4,l"-trianthrimide

2-Dibenzofuranol

Dibenzothiophene

«l,5-Dibenzoylnaphthalene

1' ,2', 6', 7' -Dibenzpyrene-7,14— quinone

NjN'-Dibenzylethylenediamine

N,,N'-Dibenzylethylenediamine diacetate

N, N-Dibenzylsulf anilic acid

2,4'-Dibromoacetophenone

*3,9-Dibroino-7H-benz[de] anthraoen-7-one

m-Dibromobenzene

p-Dibromobenzene

2,2'-Dibromobipheiiyl

Dibromodibenzo[b,def ]chrysene-7,14-dione

ar-Dibromoethylbenzene

2,6-Dibromo-l,5-naphthalenediol

Dibromo-8, 15-pyraiithrenedione

X,Y-Dibromothianthrene

Dibromoviolanthrone

2, 5-Dibutoxy aniline

2,6-Di-tert-butyl-4-nonylphenol

2,4-Di-tert-butylphenol

2,4-Dichloroanlline

3,4-Dichloroaniline

*2,5-Dichloroaniline and hydrochloride [nH2=1J

3,4-Dichloroanlline-6-sulfonic acid

3.(2,4-Dichloroanilino)-l-(2,4,6-triohlorophenyl)-2- pyr azolin-5 - one .

1, 5-Dichloroanthraqulnone

1,5 (and l,8)-Dichloroanthraquinone

*l,8-Dichloroanthraquinone

4,5-Dlchloro-l,8-anthraquinonediEulfonio acid

2,2'-Dichloroazobenzene

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin-5-one

Dichlorobenzanthrone

m-Dichlorobenzene

*o-Dichlorobenzene

*o(and p)-Diohlorobenzene

*p-Dichlorobenzene

4,6-Diohloro-m-benzenedlsulfonamlde

4,6-Dichloro-m-benzenedisulfonyl chloride

*3,3'-Dichlorobenzidine base and salts

2,4-Diohlorobenzoic acid

2,6-Dlchlorobenzonitrile

2,5-Diohloro-3,6-bis(9-ethyloarbazol-3-ylaniino)-p-benzo-

quincne . 8, 18-Diohloro-5, 15-diethyl-5, 15-dihydrodllndolo- (3,2-b:3' ,2'-m)triphenodioxazine.

2,5-Diohloro-3,6-dihydroxy-p-benzoquinone

4,5-Diohloro-3,6-dioxo-l,4-cyclohexadiene-l,2-dicar-

bonitrile. 4,5-Dlchloro-3,6-dioxocyolohexene-l,2-dicarbonitrile

Manufacturers' identification codes (according to list in table 22)

RH, TNP.

NEP, RIL.

ACY, DUP, G, MAC, SDH, TRC, VPC.

ICI. MAC.

G, NAC.

LAK.

BUG.

ICI.

DUP.

IDC.

G, TRC.

ICI.

ACY, DUP, G, ICI, MAY, NAC, TRC.

ICI.

G, HST, ICI, TRC, VPC.

EK, EVN.

ACY, DUP,

ATL, ICI.

WYT.

WYT.

ICI.

EK.

DUP, G, MAY, NAC, TRC.

EK.

DOW.

EDC.

ICI.

DOW.

EK.

DUP.

TRC.

G.

EKT.

G.

DOW.

EK.

DUP, MON.

AAP, DUP, KLS, NAC, SDH.

SW.

EK.

DUP, ICI, NAC.

DUP, NAC.

G, ICI, TRC.

G.

DUP.

EK.

ACY.

EK, WOI, X.

ACS, CPD, DCW, DUP, DVC, MON, CMC, PPG, SCC, SVT, WOI.

GGY, HKD, MTO.

ACS, CPD, DOW, DUP, DVC, HK, MON, PPG, SCC, SVT, WOI.

ABB.

ABB.

ALL, OWN, IMP, LAK, NAC.

HN.

AAP, TRC.

EK.

CYCLIC INTERMEDIATES

77

TABLE 1^.— Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 7564— Continued

Manufacturers' identification codes (according to list in tatle 22)

Diohlorodiphenylsilane

Diohlorodiphenyl sulfone

2' ,7'-Dichlorofluorescein

2,5-Dichloro-'i-hydrazinoben2;enesulfonio acid

2-(5,8-Dichlcro-l-hydroxy-2-naphthylazo)-l-phenol-4- suifonamlde .

7,16-Dichloroindanthrene

Dichloroisoviolanthrone

»2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)'benzene- sulfonic acid. Dichloromethylphenol

*2,6-Dichloro-4— nltroaniline

l,2-Dichloro-4-nitrobenzene

*l,4-Dichloro-2-nitrobenzene (Nitro-p-diohlorobenzene )

2,4-Dichlorophenol

l-(2,5-Dichlorophenyl)-3-triazene-car'bonitrile

2,6-Dichloropyrazine

3,6-DichloropyTldazine

4,7-Dichloroquinollne

3,5-Dichlorosalicylic acid

*2,5-Diohlorosulfanilic acid [S03H=1]

2,5-Dichloro-4-sulfobenzenediazoniuin sulfate

a,a-Dichlorotoluene (Benzal chloride)

p,a-Diohlorotoluene

2,4-Dichloro-5-(p-toluenesulfonaniido)-l-naphthol

2,<i-Dichloro-3,5-xylenol

Dicyclohexylamine

Dicyclohexylcarbodiimlde

Dicyclopentadiene and cyclopentadiene

Dioyclopentadiene dioxide

2,4-Di(l,l-dijiiethylpropyl)phenol (Di-tert-amylphenol)

2,5-Diethoxyaniline

2 ',5 '-Diethoxybenzanilide

p-Diethoxybenzene

2,5'-Diethoxy-4' -nitrobenzanilide

l,4-Diethoxy-2-nitrobenzene

*p-Dlethylaminobenzaldehyde

a- ( 2-Diethylaminoethyl) -a-phenylcyclohexanemethanol, hydrochloride .

m-Diethylami nophenol ( N, N-Diethyl-3-aiiiinophenol)

3-(p-Diethylaminophenylazo)-lH-ly2,4.-triazole

3-Diethylmm" nopropiophenone

4-Diethylainino-o-tolualdehyde

*N,N-Diethylaniline

N,N-Diethyl-m-anisidine

Diethylbenzene

N, N-Diethyloyclohexylamine

N.N-Diethylmetanilic acid

N ,>}■'■ -Diethyl-4-methoxyinetanilaiiiide

N,N-Diethyl-l-naphthylamine

N,N-Dlethyl-p-nitrosoaniline

N,N-Diethyl-4-nitroso-ni-anisidine hydrochloride

N,N-Diethyl-4-nitroso-m-phenetidine

N,N-Diethyl-m-phenetidine

Diethyl terephthaloyldiacetate

N,N-Diethyl-m-toluidine

6,15-Dihydro-5,9,14,18-anthrazinetetrone

10, ll-Dihydro-5H-dibenzo [a, d] cyeloljepten-5-one

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid, sodium salt.

3,4-Di}-vc.o-6-methoxy-l(2H)-naphthalenone

10,ll-Dihydro-5-[3-(methylamino)propyl] -5H-dibenzo [a,d] - cyclohepten- 5-ol .

2,3-Dihydro-4H-pyran

1,4-Diliydroxyanthraquinone

1,5 (and l,8)-Dihydroxyanthra(iiilnone

2,5-Dihydroxybenzenesulfonlc acid

3,4-Dihydroxybenzoic acid (Protocatechuic acid)

4,4'-Dihydroxy-3,3'-dimethylbiphenyl

Dec. NES.

ICI. ICI.

ACY, CMG, DUP, G, KI£, TEC, VPC.

EKT.

AAP,

DUP,

AAP,

DOW,

G.

ACY.

ACY.

SDW.

ICO.

CMG,

TEC.

MAC.

HN.

EK.

OTA.

ABB,

G.

ENJ,

UCC.

PAS.

ALL.

G.

G.

G.

G.

DUP,

ACY.

DUP, EKT, G, MEE, PCW, TEC.

MON.

DUP, MAC, VPC.

MON.

DUP, G, VPC.

VGC. UCC.

G, MAC.

ACY, DUP, MON.

TRC.

ACY.

DUP.

ACY, nSC, DUP, NAC, SDH.

DUP.

DOW, KPP.

DUP.

DUP.

G, PCW.

DUP.

G.

DUP.

G.

G.

G.

DUP.

TRC.

LIL.

EK.

GAM. LIL.

QKO.

DUP.

DUP, NAC, SDH.

NES.

AMB.

EK.

78

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1964- -Continued

Manufacturers' identification codes (according to list in table 22)

Dihydroxydinitroanthraquinone

*l,5-Dlhydroxy-4,8-dlnitroanthraqulnone

*l,8-Dlhydroxy-4,5-dinitroanthraquinone (4, 5-Dinitro-

chrysazin). l,5-Dlhydroxy-4,8-dlnitro-2,6-anthraqulnonedisulfonio acid- l,8-Dihydroxy-4,5-dinitro-2,6-anthraquinonedlsulfonic aoid- 4,5-DihydrQxy-2,7-naphthalenedlsulfonic acid ( Chromotropic acid) .

6,7-Dihydroxy-2-naphthalenesulfonic acid

3 J 5-Dihydroxy-2 -naphthoic acid

ll|3,21-Dihydroxypregna-4,17(20)-cis-dien-3-one

ll/3,21-Dlhydroxypregna-l,4,17(20)-cis-trien-3-one

4,5 -Dihydroxy-3 -( p-sulf ophenylazo) -2,7-naphthalene - disulfonic acid, trisodium salt.

*16,17-Dihydroxyviolanthrone (Dihydroxydihenzanthrone)

m-Diiodohenzene

2,5-Diiodobenzoic acid

3,5-Diiodo-L-tyrosine

NjN'-Diisopropyl-p-phenylenediamine

2,5-Dlmethoxyaniline

l,5(and 1,8) -Dlmethoxyanthraqulnone

m-Dimethoxybenzene

p-Dimethoxybenzene

*3,3' -Dimethoxybenzidine

3,3' -Dimethoxybenzidine hydrochloride

2,4-Dljnethoxybenzoic acid

l,l-(3,3 '-Dimethoxy-4,4 '-biphenylene)bis [3-methyl-3-(2- sulf oethyl) triazene] .

1, 4 -Dimethoxy-2 -nitrobenzene

2,5-Dimethoxy-4' -nitrostilbene

3,4-Dimethoxyphenethylamlne (Homoveratrylamine)

4-(2',5'-Dimethoxyphenethyl)aniline hydrochloride

N-(3,4-Dimethoxyphenethyl)-2-(o-nitrophenyl)acetamide

( 3, 4-Dimethoxyphenyl) acetic acid

(3,4-Dimethoxyphenyl)acetonltrile

16,17-Dimethoxyviolanthrone

m-Dimethylaminobenzoic acid

a-Dimethylamino-o-cresol

6 -Dime thy lamlno-2-( 2-( 2 , 5 -dimethyl-l-phenyl-3 -pyrryl) - vinyl) -l-methyl-l-quinolinivuD methyl sulfate .

6-(Dliiiethylaiiiinoethyl) -2-methoxy-4-nitrophenol

Dimethylamlnoethyl-4-methylpiperazine

o-( 2 -Dimethylamlnoethyl) phenol

2-[ ( 2-Diiiiethylaminoethyl) thenylamino] pyridine (non- medicinal grade) .

a, a', a"-tris(Dimethylamiuo)mesitol

o-(Dlmethylamlnomethyl) -p-butylphenol

m-Dimethylaminophenol

N-( p-Dimethylaminophenyl) -1,4-naphthoquinoneimine

»N,N-Dimethylaniline

7,12-Dimethylbenz [a] anthracene

*N,N-DimethylbenzylaJilne

a, a'-Dimethylbenzyl hydroperoxide

4-(a,a-Diniethylbenzyl)-2-phenylazophenol

*2,2' -Dimethyl-1,1' -bianthraquinone

2,4-Di( 1-me thy Ibutyl) phenol

5,5-Dimethyl-l,3-cyclohexanedione

N,N-Dimethylcyclohexylamine

N, N-Dimethyl-2 , 2 -diphenylacetnml de

2 ',7' -Dimethylfluoran

Dimethylhydantoin

2,6-Dijiiethylhydroqulnone

2,8-Dimethyl-13P-hydroxy-9(l3P)-oeroxenone

2,3-DimetlQflindole

2,5-Dimethyl-^(2) -morpholinylmethylphenol, hydrochloride

*N,N-Dimethyl-p-nitrosoaniline

N,N-Dimethyl-p-phenylenediamine

N,N-Dimethyl-p-phenylenediamine hydrochloride

Dlmethylplperazine

1,4-Dimethylpiperazine

DUP.

G, ICI, TRC, VPC.

DUP, EKT, G, ICI, MAC.

VPC. DUP. HSH, MAC.

FMT, G, IDC, NAC.

G.

UP J.

UP J.

EK.

ACY, DUP, G, ICI, MAY, NAC.

EK.

RSA.

EK.

DUP.

EKT, KIS.

TRC.

ACY, ICO.

G, ICO.

ALL, CWN, DUP, SDH.

CWN.

ACY.

EKT. UP J. LIL. UP J.

X.

LIL. LIL.

ICI, MAY. SDH. TKL.

NAC.

DEC, DUP, NAC, SDH.

MIS, X.

MEE. UCC.

TKL.

RH.

ACY,

NAC.

ACY,

EK.

ICO,

ACP.

TRC.

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC.

PAS.

EKT.

DUP, EKT.

UPJ.

WIM.

GLY.

UPJ.

WIM.

DUP.

IDC.

ACY, DUP, G, NAC.

EKT, NAC.

EK.

WYN.

JCC, SEL.

CYCLIC INTERMEDIATES

79

TABLE IB.— Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i 964— Continued

p-(l,l-Dimethylpropyl)phenol

N, N-Dimethylsulf anilio aoid

Dimethyl-p-toluldine

N,N-Dimethyl-p-toluidine

2,4-Dinitroaniline

*p-(2,4-Dinltroanilino)phenol

lj5(and l,8)-DinltroanthTaqulnone

2j4-Dinitro-N,N'-(l,5-anthraqulnonylene)dioxamlo acid

3,4-'-Dinitrobenzanilide

m-Di nitrobenzene

2,4-Dinltrobenzenesulfonlo acid

3,5-Dinitrobenzoio acid

3,5-Dinitrobenzoyl chloride

ninitro(3,3'-bi-7H-benz[de]anthracen)-7,7'-dione-

2 , 4— Dinitrocumene

l-(3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol

*2,4-Dinitrophenol, tech

2,4-nlnitrophenylhydrazine

3,5-Dinitrosalicylic acid

*'i-,<i'-Dinitro-2,2' -stilbenedisulfonio acid

2,4-Dinitrotoluene

2,4(and 2,6)-Dinitrotoluene

3,5-Dinitro-p-toluenesulfonic acid

1,5-Diphenoxyanthraquinone

1,5 (and l,8)-Diphenoxyanthraquinone

1, 8-Diphenoxyanthraquinone

*Diphenylacetic acid

Diphenylaeetone

Diphenylamine

6,8-Diphenylamlno-l-naphthalenesulfonic aoid

2,8-Dlphenylanthra[l,2-d:5,6-d']bisthiazole-6,12-dione

a-d-l,2-M.phenyl-4-diinethylaiiiino-2-hydroxy-3-methylbutane, camphor sulfonate.

N,N' -Diphenylethylenediamine

l,3-Diphenyl-l,3-propanedione

1,3-Diphenyltriazene

2, 4-Disulforiyl-5-chloro-(N-benzyl) -aniline

2,5-nithiobl\n-ea

Dithiodibenzoic aoid

2,2'-Dithiodibenzoic aoid

*1, 4-Di(p-toluidino)anthraquinone

1, 5-Di(p-toluidino)anthraquinone

l,8-Di(p-toluldino)anthraquinone

l,4-ni(p-toluidino)-5,8-dihydroxyanthraquinone

Divinylbenzene

Edxylylethane

Dixylylguanidine

Dodeoylaniline

*Dodecylbenzene (including trideoylbenzene ) :

Straight-chain

Other

Dodecylmethylbenzene

Dodecylmethylbenzyl chloride

Dodecylnitrobenzene

*Dodeoylphenol

o- Ethoxybenzoic acid

(o-Ethoxybenzoyl)aoetonitrile

6-Ethoxy-2-mercaptobenzothiazole

2-Ethoxynaphthalene

2-Ethoxy-l-naphthoyl chloride

■4-Ethoxy-o-phenylenediamine

3-Ethylamino-p-cresol

Manufacturers' identification codes (according to list in table 22)

PAS, UCP.

SEL.

AAP, ACY.

DUP, G, NAC.

AAP, TRC.

TRC.

AAP.

DUP, NAC.

TRC.

DUP, GAM,

SAL, SDH.

EK.

DUP, MAY.

DUP.

TRC.

AAP, DUP,

NAC, SDC.

EK.

EK.

ACY, DUP,

G, NAC, SDH, TRC

DUP, NAC.

DUP, MOB.

G.

ICI, VPC.

AAP, DUP.

EKT, G, ICI.

ARA, BPC,

LIL.

TBK.

ACY, DOW,

DUP.

NAC.

ICI.

LIL.

DOW, RPC.

EK.

NAC.

ABB.

ACY.

MEE.

LIL.

ATL, CMG,

G, ICI, NAC, TRC,

ICI.

ICI.

ICI.

DOW, FG, KPP.

GOC.

ACY.

MON.

CO.

ATR, CO, MON, NAC, SOC.

X.

X.

MON.

G, MON, X

ACY.

ACY.

ARA, DUP.

ICO, NAC.

ICO, OPC.

TRC. DUP.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE TB.-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i 564 —Continued

3-Ethylaim.no-p-toluenesulfoiiic acid [S03H=lJ »N-Ethylaiallne, refined

2-(N-Ethylanilino)ethanol 7-—

[ 2-(N-Ethylanilino)ethyl] trimethylaimiionium chlonde- (N-Ethylaiillino)propionltrile

a-(N-Ethylaniltno)-m-toluenesiilfonlc acid

a-(N-Ethylaiilltno)-p-toluenesulfonio acid

N-Ethyl-p-anisidine

N-Ethylanthranilic acid

2-Ethylaiit)iraquinone

*Ethylbenzene

(MEP)-

o-(p-Etliylbenzoyl)benzoic acid

Etl^rlbenzyl chloride

N-Ethyl-N-(2-chloroetliyl) aniline 7 J-—

l-Ethyl-7-methyl-l,8-naphtl)yridln-4-one-3-carboxylio acid—

N-Ethyl-l-naphthylamlne

9-Ethyl-3-nitrocarbazole

p-Ethylphenol

»N-Etl^l-N-phenylbenzylamine

»2-Ethyl-2-phenylmalonic acid, diethyl ester-^ 5-Ethyl-2-picollne (2-Methyl-5-ethylpyridine

1-Ethylpiperidine

N-Ethyl-5-sulfoanthranillo acid 7

6-Ethyl-l,l,'4,4-tetramethyl-l,2,3,4-tetrahydronaphthalene-

N-Ethyl-m-toluidine

N-Ethyl-o-toluidine

3-(N-Ethyl-m-toluidino)-l,2-propanediol

»3-(N-Ethyl-m-toluidino)propionitrile

1-Ethynylcyclohexanol ~_

o-Fluoroaniline

l-Fluoro-2,4-dinitrobenzene

o-Fluorotoluene

A-Fonnyl-m-benzenedisulfonic acid 7

»o-Foniiylbenzenesulfonic acid (o-Sulfobenzaldehyde)

m-Formylbenzenesulfonio acid, sodium salt

Furan

Furfuryl alcohol

Hexachlorobenzene

Hexachlorocyclopentadiene

Hexachlorophenyl ether

N-Hexadeoylmorpholine

2 2' ,U,U' ,6,6' -Hexanitrodiphenylamlne

Hippurlo acid

«p-Hydrazinobenzenesulfonio acid

3-Hydrazino-5-nitro-p-toluenesulfonic acid [S03H=1J

Hydroquinone , tech

2' -Hydroxyacetophenone

3' -Hydroxyaoetophenone

"i' -Hydroxyacetophenone

3 '-Hydroxyaoetophenone benzoate

6'-Hydroxy-m-aoetotoluidide

1-Hydroxyanthraqulnone

p-HydToxybenzaldehyde

2-Hydroxy-llH-benzo [a] carbazole-3-oarboxylic acid

p-I^roxybenzoic acid

p-Hydroxybenzoio acid, butyl ester

p-Hydroxybenzolc acid, ethyl ester

«p-Hydroxybenzoio acid, methyl ester

»p-Hydroxybenzolc acid, propyl ester

Manufacturers' identification codes (according to list in table 22)

DUP.

ACY, DUP, NAG, SDH.

DUP, EKT, G.

DUP.

EKT.

ICC, NAG, SDH, THC, WJ.

EKT.

G, SDH.

NAC.

DOW, ENJ, FG, KPP, KPT,

MON

TOO, UCC.

NAC.

BPC.

DUP.

SDH.

DSC, DUP.

TRC.

ACY.

DUP, NAC, SDH.

BPC, MAL, VPC.

UCC.

RIL.

SDH.

GIV.

DUP.

DUP.

EKT.

DUP, EKT, G.

EKT, NAC.

NEP.

EK.

EK.

G.

G, NAC, SDH, VPC.

G.

DUP.

QKO.

KPT, sec

HK, VEL.

D01».

APD.

EK.

BPC.

ACY, G, STG, WJ.

G.

CRS, EKT.

arc

SDH.

OTC.

SDH.

TRC.

AAP.

DOW.

G.

HN.

HN, WSN.

HN, ICO, WSN.

HN, ICO, LEM, WSN.

HH, ICO, LEM, WSN.

SHC, SIN, SKC, SNT,

CYCLIC INTERMEDIATES

TABLE 7B. -- Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in tatle 22)

6' -Itydroxy-m-benzotoluidide

o-(p-Ifydroxybenzoyl)benzoie acid

A-Ify'droxycoumarin

'4-I^roxy-N-'-,N-'--diinethylmetanilandde

3-(N-2-I^droxyethylam.lino)propionitrile

N-P-Hrdroxyethyl-2,4-dihydroxybenzamide

3-l^droxy-N-2-hydroxyethyl-2-naphthaiTn'de

6'-Hydroxy-5 '- (2-hydroxy-5-nitrophenylazo)-in-aoetotoluidide N-[ 7-}^droxy-8-( 2-hydroxy-5-nitrophenylazo ) -1 -naphthyl] - aoetamide.

ifydroxyisophthalio acid

2-Hydroxy-C"'',a^-mesitylenediol

2-Itrdroxy-3-methylcinchoninic acid

3-Hydroxy-2-methylcinchoninlc acid

N-I^dro3(ymethylphthalamide

V-Ifydroxy-l-naphthalenecarbamic acid, methyl ester

l-l^droxy-2-naphthalenesulfonio acid, potassium salt

3-}fcrdroxy-2-naphthanilide (Naphthol AS)

1-Itydroxy -2 -naphthoic acid

2-ffydroxy-l -naphthoic acid

3 -Ify-droxy -2 -naphthoic acid (B.O.N.)

3 -Ilydroxy-2 -naphthoic acid, methyl ester

l-Hydroxy-2-naphthoio acid, phenyl ester

3-Hydroxy-2-naphtho-o-toluidide

N-(7-Itydroxy-l-naphthyl)acetamide

l-(2-Ifydroxy-l-naphthylazo)-6-nitro-2 -naphthol -4-sulfonio acid.

N-(7-Hydroxynaphthyl)benz amide

3'-[(7-Hydroxy-l-naphthyl)carbamoyl]acetaiiilide

l-(2-Ifydroxy-4-nitrophenylazo) -2 -naphthol

^-Hydroxypropiophenone

2-I^droxy-4— sulfo-1-naphthalenediazonimn hydroxide, inner salt.

l-}trdroxy-4--(p-toluidino)anthraquinone

2-Tmidazolidinone modifications

»l,l' -Iminobis[4-aminoanthraquinone]

1,1' -Iminobis /--benzamldoanthraquinone]

5-benzamidoanthraquinone]

l-naphthol-3-sulfonic acid]

A-nitroanthraquinone]

*l,l'-Iiziinodianthraquinone ( Dianthrimide )

2,2' -Tmi nodipyridine

1,3-Indandione

1-Iodonaphthalene

Isatin

Isatoic anhydride

*Isooyanio acid derivatives:

Bitolylene diisocyanate (TODI)

Dianisidine diisocyanate (DADI)

3-,4— Diohlorophenyli"sooyanate

*Diphenylmethane 4-,A' -diisocyanate (MDI)

Phenylisocyanate

Polyisocyanates (complex)

Polymethylene polyphenylisocyanate

Toluene 2,4-diisocyanate

Toluene 2,A- and 2,6-diisocyanate (65/35 mixture)

*Toluene 2,4- and 2,6-diisocyanate (80/20 mixture)

Other isocyanio acid derivatives

Isonicotinic acid, methyl ester

Isonicotinonitrile

Isonitrosopropiophenone

»1,1' -Iminobis »6,6'-Iminobis *l,l'-Iminobis

TRC.

LIL.

ABB.

G.

ICC.

IDC.

X.

TRC.

TRC.

SDH.

ACY.

G.

DUP,

TRC.

ACY.

TRC.

EK.

ATI,

PCW.

NAC.

BL.

AUG,

DUP,

HN, PCW.

PCW.

EK.

ACY,

ATL.

CMG,

TRC.

TRC.

TRC.

TRC.

TRC.

MLS.

ACY.

ICI.

RH.

ACY,

CMG,

DUP, G, ICI, MAY, NAC, TRC

ACY,

MAY.

G, ICI, TRC.

DUP,

G, NAC, TRC.

ACY,

DUP,

ICI, MAY, TRC.

ACY,

DUP,

G, ICI, MAY, NAC, TRC.

RIL.

PIC.

EK.

NAC.

MEE.

CWN.

CWN.

DUP.

CWN,

DUP,

MOB, NAC.

CWN.

MOB.

CWN.

DUP.

DUP,

NAC.

DUP,

MOB,

NAC.

CWN,

MOB,

UCC, UPC.

RIL.

RIL.

ICO,

NEP.

82

TABLE 7B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 2564— Continued

Isoootylphenol "" '"^ '_

Isophorone "7 T"7"

Isophthalic acid (1,3-Benzenedlcarboxylic acid) -—

Isophthallc acid, dimethyl ester

Isophthalic acid, diphenyl ester -

Isophthalonitrile "

N-Isopropylaniline

p-Isopropylbenzoic acid "

5,5'-Isopropylidenebis(2-hydroxy-ni-xylene-a,a'-diol)

*<i,4'-Isopropylidenediphenol (Bisphenol A)

4 4'-Isopropylidenediphenol, ethoxylated

i.',A' -Isopropylidenediphenol, propoxylated

o-Isopropylphenol

<V-Isopropyl-m-phenylenediajiiine

Isothiooyanic acid, phenyl ester

*Isoviolanthrone (Isodibenzanthrone)

*Leuco-l,4-diaiiiinoanthraquinone

*Leuco quinizarin (1,4,9,10-Anthratetrol)

»Leuco tetrahydroxyanthraquinone

2,4-Lutidine

3,'4-Lutidine

Mandelonitrile

*Melaniine

dl-p-Mentha-l,8-diene (Limonene)

p-Mentha-l,'i(8)-diene

p-Mentha-l,8-diene ^

*o-Mercaptot)enzoic acid

Metanilamide "

Metanilic acid (m-Amlnobenzenesulfonic aoid)

1-Methoxyanthraquinone

4-Methoxymetanilic aoid

4'-Methoxy-2-(p-methoxypheiiyl)acetophenone

N-(2-Methoxy-l-naphthyl)acetamide

2-Methoxy-4-nitrophenol

p-Methoxyphenylaoetic acid ''"^"s

S-Methoxy-m-phenylenediamine (m-Diaminoanisole)

crude

Me thoxypropi ophenone

i-l-Methylaminoanthraqulnone

l-Methylaiiiino-<i-(p-toluidino)anthraquinone

N-Me thy lani line

2-(N-Methylanilino)ethanol

3-(N-Methylanilino)propionitrile

5-Methyl-o-anisidine [NH2=1]

m-Methylanlsole

N-Methylanthranilic acid

2-Methylanthraquinone """"

1- ( 3-Methyl-2-anthraquinonylamino ) -5- (7-oxo-7H-benz [dej -

anthracen-3-ylamino) anthraquinone .

3-Methylbenzo [f]quinoline

2-Methylbenzothiazole

N-Me thy Ibenzylamine

Methyl benzyl ether

3-Methylcholanthrene

Methylcyclohexane

N-Methylcyclohexylamine

-i-Methyl-a ,a-diphenyl-l-piperazineethanol dihydrochloride-

N-Methyleneaniline

4.,4'-Methylenebls[2-chloroaniline]

iH 4'-Methylenebls[N,N-diethylaniline]

*4,4'-Methylenebis[N,N-dimethylaniline] (Methane base)

4,4'-Methylenebis[N,N-dimethyl-3-nitroaniline]

5,5'-Methylenebis[toluene-2,4-diaiiiine]

Methylenedianiline

Methylenedisalicylic acid

5-Methylene-2-norbornene

l-Methylindole-3-carboxaldehyde

Manufacturers ' identification codes (according to list in table 22)

G.

UCC.

ACC, SOC.

MTR.

BJL.

X.

ACY, EKT.

EK.

ARK.

DOW, MON, SHC, UCP.

APD.

APD.

TNA.

DUP.

TNC.

ACY, DUP, G, MAY.

ACY, ATL, DUP, G, ICC, ICI, MAY, TRC.

AAP, ACY, EKT, HSH, ICC, MAC.

G, ICC, TRC.

ACP, KPT.

RIL.

KF.

ACN, ACY, RCI.

HNW.

GIV.

GIV.

EVN, LIL, MED.

CMG, VPC.

DUP, NAG, TRC.

G.

G.

CTN.

TRC.

MEE.

TBK.

AAP.

LIL.

AAP, ACY, DUP, G, ICI, MAC.

G, ICI.

ACY, DUP, MAC.

G.

DUP.

DUP.

GIV.

ICC.

ACY, MAC.

DUP.

ACY, G.

FMI.

ABB, MLS.

UCC.

EK.

DOW, PLC.

DUP.

DUP.

DUP.

DUP,

ACY,

G.

NAC.

DOW,

HN.

DOW.

G.

G, SDH, TRC.

DSC, DUP, G, MAC, SDH, x.

CYCLIC INTERMEDIATES

83

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

Jfethyl-N-methyl-N-piperazine acetate

6-Jfethyl-2- ( 2-methyl-6-quinolyl ) -7-"benzothlazolesulf onio acid.

Methylnaphthalene, crude

1-Jfethylnaphthalene

N-Methyl-4'-nitroacetanilide

N-lfethyl-p-nltroaniline

5-Methyl-4— nitro-o-anisidine

4-Methyl-2-nitroanisole

*2-Methyl-l-nitroanthraquinone

2-Methyl-5-nitro imidazole

N-Methyl-N-nitroso-p-toluenesulfonamide

Methylnorbomene-2,3-dicarboxylic anhydride, isomers

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzene sulfonamide

p-(3-Methyl-5-oxopyrazolin-l-yl)benzenesulfonic acid

m-(3-^fethyl-5-oxo-2-pyTazolin-l-yl)benzenesulfonio acid

*p-(3-lfetliyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid 3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedisul-

fonic acid. 4-- ( 3-Methyl-5-oxo-2-pyrazolin-l-yl ) -m- toluenesulf onic acid [ S03H=1] .

2-Wtethyl-5-phenylbenzoxazole

1-Methyl-l-phenylhydrazine

5-Jfethyl-3-phenyl-<i-isoxazolecarboxylic acid

5-Metliyl-3-phenyl-4-isoxazolecarboxylic acid hydrochlo- ride.

*3-tfethyl-l-phenyl-2-pyrazolin-5-one (Developer Z)

N-lfethylpiperazine

3-(a-Methylpiperidino)propaiiol--

16a-Methyl-l,,4,9( 11) pregnatriene-17a-21-diol-3,20-dione, 21-ethyl carbonate.

Ifethylpropylcarbinylbarbituric acid-

Ifethylpyrazine

1-Msthylpyrrole

*a-Hfethylstyrene

N-Msthyl-5-sulfoanthranilic acid

2-Methylsulfonyl-'i-nitroaniline

Methyl 2-thlenyl ketone

p-Methylthioaniline hydrochloride

<i-(tfethylthio)-in-oresol

p-(Methylthio)phenol

3-lfethyl-6-(p-toluidino)-7H-dibenz [f , ij Jisoqiiinoline- 2,7(3H)-dione.

3-Methyl-l-(p-tolyl)-2-pyrazolin-5-one

6 '-Methyl-A'-p-tolylsulfonamido-m-benzanisidide

Morpholino propylchloride

Naphthalene, solidifying at 79° C. or above (refined flake) (from domestic crude).

1, 3-Naphthalenediol

1, 5-Naphthalenediol ( 1, 5-Dihydroxynaphthalene )

*l,5-Naphthalenedisulfonio acid

*2,7-Naphthalenedisulfonic acid

l-Naphthalenesulfonic acid

1-Naphthalenesulfonic acid, sodium salt

2-Naphthalenesulfonio acid

2-Naphthalenesulfonic acid, sodium salt

2-Naphthalenesulfonyl chloride

*1,4, 5,8-Naphthalenetetraoarboxylio acid

1,3,6-Naphthalenetrisulfonio acid

Naphthalic anhydride

Naphthallmide

Naphthionic acid (4-Jtaiino-l-naphthalenesulfonio acid)

Naphthionio acid, sodium salt

»l-Naphthol (a-Naphthol)

2-Naphthol, tech. (|3-Naphthol)

p-Naphtholbenzein '

2-Naphthol-3,6-disulfonic acid (R acid)

*2-Naphthol-3,6-disulfonio acid, disodium salt

2-Naphthol-6, 8-disulf onic acid (G acid)

ABB.

DUP.

KPT,

VEL.

RIL.

G, NAC.

EK,

G.

Few.

DUP.

DUP,

G, ICI, NAC.

RDA.

EK.

NAC.

CMG,

VPC.

KLS.

G, TRC.

AAP,

ACY, CMG, DUP, G, TRC, VPC

TRC.

CMG,

G, TRC.

EK.

EK.

ICO,

X.

ICO.

DOW,

DUP, NAC, SDH, SDW, VPC.

UCC.

LIL.

SCH.

LIL.

WYN,

DUP.

ACP,

CLK, DOW, HPC.

G.

EKT.

GAM.

EVH.

CRZ.

CRZ.

ICI.

VPC.

NAC.

ABB.

KPT,

RIL.

EK.

NAC.

G, MAC, TRC.

DUP,

NAC, TRC.

TRC.

TRC.

ACY,

NAC.

ACY.

DUP.

G, HST, TRC.

G.

DUP.

DUP,

NAC.

ACY,

DUP.

DUP,

NAC.

DUP,

NAC, UCC, UCP.

ACY,

MAC, SW.

EK.

ATL.

ACY,

G, NAC, TRC, WJ.

DUP,

TRC.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

2-Naphthol-6,8-disulfonlc acid, dipotassium salt

2-Naphthol-6,8-disulfonlc acid, disodlum salt

l-Naphthol-3-sulfonainide

l-Naphthol-A-sulfonic acid (Nevile & Winther's acid)

l-Naphthol-5-sulfonic acid

l-Naphthol-8-sulfonic acid

»2-Naphthol-6-sulfonic acid (Schaeffer's acid)

*2-Naphthol-6-sulfonic acid, sodium salt

2-Naphthol-7-sulfonic acid

l-Naphthol-3-sulfonic acid, benzenesulfonate, sodium salt-

l-Naphthol-8-sulfonio acid sultone (1,8-Naphthosultone)

l,"i-Naphthoquinone

Naphthostyril

»Naphth[l,2]oxadiazole-5-sulfonio acid

1-Naphthylamine (a -Naphthylamine )

l-(2-Naphthylamino)anthraqulnonecarboxylic acid

*2-(Naphthylthio) acetic acid

Nlootinonitrile (3-Cyanopyridine)

Nitro-aceanthra[2,l-a] aceanthrylene-5,13-dione

3' -Nitroacetanilide

4' -Nitroaoetanilide

<4'-Nitro-o-acetanisidide

2-Nitro-p-acetanisidide

3 ' -Nitroaoetophenone

5' -Nitro-o-acetotoluidide

m-Nitroanlline

o-Nitroaniline

*p-Nitroaniline

3-Nitro-p-anisamide

*<i--Nitro-o-aiiisidine [rH2=1]

»5-Nitro-o-anisidine [nH2=i]

2-Nitro-p-anisidine [NH2=1]

o-Nitroanisole

p-Nitroanisole

4-Nitroanthranllic acid

S-Nitroanthranilic acid

1-Nitroanthraquinone

1' -Nitroaiithraquinone-2' -carboxyaminoaceanthra [2,1-^ - aceanthrylene-5,13-dione .

»l-Nitro-2-aiithraquinonecarboxylic acid

*5-Nitro-l-anthraquinonesulfonic acid

»5(and 8)-Nitro-l-anthraquinonesulfonic acid

S-Nitro-l-anthraquinonesulfonio acid

8-Nitro-l-anthraquinonesulfonic acid, sodlimi salt

2-(4-Nitro-2-anthraqulnonyl)anthra[2,3]oxazole-5,10-dione-

m-Nitrobenzaldehyde

6-(p-Nitrobenzamido)-l-naphthol-3-sulfonio acid

3'-Nitrobenzanilide

4'-Nltrobenzanilide

*Nitrobenzene

3-Nitrobenzenesulfonanilide

*m-Nitrobenzenesulfonic acid

*m-Nitrobenzenesulfonio acid, sodium salt-

m-Nitrobenzenesulfonyl chloride

p-Nitrobenzenesulfonyl chloride

5-Nitro-2(3H)-benzimidazolone

ACY,

NAC.

G.

ATL,

DUP,

NAC.

NAC.

G, VPC.

NAC,

SNA,

TMS.

ACY,

TRC,

WJ.

DUP.

G.

ACY,

TRC.

EKT.

DUP,

NAC.

CMG,

G, NAC, TRC, VPC

DUP,

NAC.

TRC.

AAP,

ACY,

VPC.

KEP,

RIL.

ICI.

G.

G, TRC.

DUP.

DUP,

SDH.

SDH.

DUP.

ACY,

DUP.

AAP,

MDN.

AAP,

M3N,

SDC,

UPM.

X.

AAP,

DUP,

SDH.

ACY,

AUG,

DUP,

KLS.

DUP,

SDH.

DUP,

MON.

DUP.

DUP.

TRC.

ACY.

ICI.

DUP,

G, MAY, NAC, TRC

DUP,

NAC,

TRC.

ICI,

NAC,

TRC.

NAC.

DUP,

TRC.

G, NAC.

SDH.

DUP,

G.

DUP.

G, TRC.

ACY,

DUP,

G, MDN, NAC

G.

ACY,

DUP,

NAC.

AAP,

G, MAY, MON, MRA

ACY.

DUP, G.

CYCLIC INTERMEDIATES

85

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i5«— Continued

*m-Nitrobenzoio acid

*m-Nitrobenzoic acid^ sodium salt

p-Nitrobenzoio acid

p-Nitrobenzoio acid, ethyl ester

p-Nitrobenzoic acid, propyl ester

m-Nitrobenzoyl chloride

p-Nitrobenzoyl chloride

<♦' -Nitro-4-bipheiiylcarboxylic acid

2-Nitro-p-cresol

Nitrooyclohexane

Nitrodiphenylamine

5-Nitro-2-furaldehydediacetate

5-Nitro-2-furaldehyde semioxamazide

4-Nitro-6-(5-hydroxy-3-inethyl-l-phenyl-<i-pyrazolylazo) l-phenol-2-sulfonic acid.

5-Nitroisophthalic acid

1-Nitronaphthalene

*3-Nitro-l,5-naphthalenedisulfonic acid

8(and 5) -Nitro-l(aiid 2) -naphthalenesulfonio acid

4.-Nitronaphthalic anhydride

*7(and 8) -Nitronaphth[l,2]oxadiazole-5-sulfoiiio acid

p-Nitrophenethyl acetate

Nitrophenethyl alcohol

o-Nitrophenol

»p-Nitrophenol

p-Nitrophenol, sodium salt

4'-(p-Nitrophenyl)acetophenone

4-Nitro-o-phenylenediamine

(p-Nitrophenyl) hydrazine

(p-Nitrophenyl) hydrazine hydrochloride

2-(p-Nitrophenyl) -(2H) -naphtho[l,2-d]triazole-6,8-

disulfonic acid. l-(m-Nitrophenyl) -5-oxo-2-pyrazoline-3-carboxylic acid

o-Nitrophenyl phenyl sulfone

"i-Nitrophthalic acid

3-Nitrophthalic anhydride

^-Nitrophthalimide

l-Nitropyrene

5-Nitro-4,6-pyrimidinediol

5-Nitrosalicylaldehyde

3(arid 5) -Nitrosalicylic acid

p-Nitrosophenol

p-Nitrostyrene

2-U-(4-Nitro-2-sulfostyTyl) -3-sulf ophenyl] -2H-naphtho. [l,2]triazole-5-suli'onlc acid.

m-Nitrotoluene

o-Nitrotoluene

p-Nitrotoluene

Nitrotoluene mixtures

»5-Nitro-o-toluenesulfonic acid [S03H=l]

3-Nitro-p-toluenesuli'onic acid [S03H=l]

'i'-Nitro-p-toluenesulfono-o-toluidide

3-Nitrotoluic acid chloride

3-Nitro-p-toluic acid, methyl ester

4-Nitro-o-toluidine [nH2=1]

*5-Nitro-o-toluidine [nH2=1]

»2-Nitro-p-toluidine [ NH2=l]

5-Nitro-2-p-toluidinobenzenesulfonic acid

*16-Nitroviolanthrone _.

4--Nitro-m-xylene

Nitroxylenes, mixed

Manufacturers' identification codes (according to list in table 22)

HK,

SDH,

WAY.

WAY.

DUP.

ICO.

ICO.

HK.

DUP,

HK.

DUP,

TRC

SW.

X.

ACY.

NOR.

NOR.

TRC.

G, GAM.

DUP,

NAC

G, NAC, TRC.

G.

G.

G, NAC, TRC, VPC.

EKT.

EKT.

DUP.

DUP,

MON,

SDC, UPM

MON,

UPM.

DUP,

G.

DUP,

FMT.

EK.

DUP.

TRC.

KF.

EK.

G.

ACY,

DUP,

NAC.

CWN.

TRC.

DUP.

DUP,

NAC.

DUP,

NAC.

DUP,

NAC.

ACY,

DUP,

G, NAC, SDH, TRC.

AAP,

CIC.

G.

X.

SDH.

DUP,

G.

DUP,

KLS,

SDH.

AAP,

ACY,

DUP, NAC, SDH, SW

TRC.

ACY,

ATL,

G, MAY, TRC.

DUP.

DUP,

NAC.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

2-tert-Nonyl-p-cresol

Nonyl-dinonylphenol, mixture

*Nonylphenol

Ctetylphenol

7-CR;abicyclo[ 4. 1.0] heptane

Qxanilide

*l-(7-0xo-7H-benz[de] anthracen-3-ylamino)anthraquinone

*l,l' -(7-CKo-7H-benz [de] anthracen-3j 9-ylenediimino )- di anthraquinone .

2-Oxocyolohexanecarboxylic acid, ethyl ester

5-CKo-l-phenyl-2-pyrazoline-3-carboxylic acid

5-Qxo-l-phenyl-2-pyraaoline-3-oarboxylic acid, ethyl ester- *5-CKo-l-(p-sulfophenyl) -2-pyrazoline-3-carboxylic acid ( Pyrazolone T ) .

5-0xo-l-(p-sulfotolyl)-2-pyTazoline-3-carboxylic acid

Oxydianiline

"4, 4' -Oxydianiline

4,4' -CKydiphenol

Penicillin, N-ethylpiperidine salt

Pentadecyltoluene

1,1,3,3,5-Pentamethylindan

Pentylnaphthalenes ( Aniylnaphthalenes )

o-Pentylphenol (o-Amylphenol)

3,4,9,10-Perylenetetracarboxylio acid

3,4,9,10-Perylenetetracarboxylic diimide

Phenacetyl chloride

P- Phenethylamine

(j-Phenethylamine sulfate

o-Phenethylbenzoic acid

o-Phenetidine

p-Phenetidine

•x-Phenol : *Natural :

^From coal tar : -^

39° C, m.p

82^-84 5t

All other

*-Froni petroleum

^Synthetic :

By caustic fusion: U.S.P

From ohlorobenzene by liquid -phase hydrolysis: U.S.P

From chlorobenzene by vapor-phase hydrolysis: U.S.P

*From cumene by oxidation: U.S.P

Phenolsulfonaphthalein, sodium salt

»l-Phenol-4-sulfonic acid

Phenoxypropanol

2-Phenoxypropionic acid

a-Phenoxypropionyl chloride

Phenylacetic acid (a-Toluic acid)

Phenylacetic acid, ethyl ester, tech

*Phenylacetic acid, potassium salt

Phenylacetic acid, sodium salt

*Phenylaoetonitrile (a -Tolunitrile)

4' -Phenylacetophenone

2-Phenylanthr[2,3]oxazole-5,10-dione

*p-Phenylazoaniline (p-Jlminoazobenzene) and hydrochloride

4-Hienylazodiphenylamine

4-Phenylazo-l-naphthylamine

5-Phenylazosalicylic acid

N-'--Phenyl-l,2,4-benzenetriamine

l-Phenyl-l,3-butanedione

2-HienylbutyTic acid

USR.

JCC.

G, JCC, MON, RH, UCP, USR.

G, PRD, RH.

ARA.

WSN.

ACY,

DUP,

G, ICI, TRC.

ACY,

DUP,

G, ICI, MAY, NAC, TRC.

ARA.

NAC,

SDW.

0, VPC.

AAP,

G, ICI, VPC.

VPC.

ore.

X.

EK.

MEK.

CO.

GIV.

PAS.

PAS.

DUP,

G.

DUP,

NAC.

ICO.

MLS.

MLS.

LIL.

MON.

DOW,

MON.

KPT,

PRD.

ACP,

KPT.

ACP,

KPT,

PRD.

MER,

NPC,

PIT, PRD, SW.

MAL,

MON,

RCI.

DOW.

HKD,

UCP.

ACP,

CLK,

HPC, MON, SHC, SKO, SOC, UCC

EK.

DOW,

MON,

UPF.

ICO.

ICO.

ICO.

BPC,

GIV,

TBK.

BPC,

MAL.

BPC,

OPC,

TBK.

BPC.

BPC,

OPC,

SDW, TBK.

DUP,

NES.

G.

AAP,

ACY,

DUP, G, NAC.

EK.

DUP.

TRC.

RBC.

See footnote at end of table.

CYCLIC INTERMEDIATES

87

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964— Contiimed

a-Phenyl-o-cresol

N.N' -p-Phenylenebis[acetamide]

m-Phenylenediamine

o-Phenylenediamine

p-Phenylenediamine

Phenyl ether (Diphenyl oxide)

Phenylglycine

D(-)-2-Phenylglyclne

D(-)Phenylglycine and derivatives

Phenylglycine, sodium salt

D(-)-2-Phenylglycyl chloride hydrochloride

5-PhenyLhydantoin

Phenylhydrazine

Phenylhydrazine hydrochloride

*2,2' -(Phenylimino)diethanol (Phenyldiethanolamine)

3,3' -(Phenylimino)dipropiom.trile

Phenylmalonic acid, diethyl ester

o-Phenylphenol

o-Phenylphenol, chlorinated

o-Phenylphenol, sodium salt

p-Phenylphenol

N-Phenyl-p-phenylenediamine

Phenylphosphonous acid

Phenylphosphonous acid, sodium salt

Phenylpiperazine

l-Phenyl-l,2-propanedione, 2-oxime

Phenyl-2-propanone

N-3-Phenylpropyl-p-toluidine

Phenyl 2-pyridyl ketone

Phenyl sulfone

o-(Phenylsulfonyl) aniline

Phenylthioacetic acid

l-Phenyl-2-thiourea

Phenylimdecanoic acid

Phloroglucinol

Phthalazinone

*l(2H)-Phthalazinone

Phthalio acid

Phthalio acid, disodium salt

*Phthalic anhydride

Phthalide

Phthalimide

Phthalocyaninato(2-)iron

[Phthalooyanine( 2-)] copper

Phthalocyaninedisulfonic acid, copper derivative

Phthalocyaninetetrasulfonyl chloride, copper derivative-

Phthaloyl chloride (Phthalyl chloride)

Picollnes ; ■"•

«2-Piooline (tx-Picoline)

3-Picoline (p -Picoline)

4-Piooline (Y -Picoline)

Picoline (3,4--mixture)

Picolinic acid

3-Picolylamine

Picramio acid and salt

Picric acid (Trinitrophenol)

2-Pipecoline

Piperazine mixture, crude

»Piperidine

3-Piperidinopropiophenone hydrochloride

Polychlorobiphenyl

Polydodecylhenzene

Polyethylbenzene (8O5S Diethylbenzene)

Primuline base

Primulinesulfonio acid

See footnote at end of table.

Manufacturers' identification codes (according to list in table 22)

RBC.

ACY.

ACY, DUP, G, NAC.

FMT, MEE, TRC.

BFG.

ACY, DOW.

KF.

ore.

KF.

MAC.

OTC.

ABB, X.

DOW.

EK, VPC.

AAP, DUP, EKT, G.

DUP.

BPC.

DOW, RCI.

DOW.

DOW.

DOW.

DUP, USR.

VIC.

VIC.

RSA.

BKL.

ORT, SK.

EK.

RIL.

NES.

G.

EVN.

EK.

EK.

MRT.

AAP.

KPT, NAC, SDH.

EK, KF.

TNG.

AGP, GHH, HN, KPS, M3N, PCC, RCI, SOC, SW, THC, UCC,

WTC. FMT, NAC.

DUP, MEE, NAC, SFA. DUP. ICI. ICI. DUP. MDN.

ACP, KPT, RIL, UCC.

RIL.

RIL, UCC.

ACP, KPT.

NEP.

RIL.

DUP.

DUP, NAC, SDC.

LIL.

JCC.

ABB, DUP, MRK, RIL.

AGY.

MON.

CO.

UCC.

DUP, NAC.

ATL.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 7B.

. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers' identification codes (according to list in table 22)

*Propiophenone

Propylbenzene

2-PropylpyTidine

»Fyranthrone

1-Fyrene amine

lyridine, refined :■"■

»2° IVridine

Other grades

2,5-IVridinedicarboxylic acid

lyridine hydrochloride

3-Fyridlneniethanol

3-Fyridinol

2(lH)-Pyridone

4-, 6-Pyrimidinedlol

2-iyriiiiidinol

Fyromellitio acid

I^romellltic dlanhydrlde

2-Pyrrolidinone

3-(l-Pyrrolidlnyl)propiophenone hydrochloride

*Quinaldine

*Quinizarin

*2-Quinizarinsulfonic acid

Quinoline :

and Quinoline

Other grades

2,4-(Jiinolinediol

8-Quinolinol (8-}fydroxyquinoline, tech.)

Quinophthalone

Quinothalone (Quinoline yellow, base)

Resorcinol, monoacetate (nonmedicinal grade)

Resorcinol, tech

P-Resorcylaldehyde

P-Resoroyllo acid

(j -Resorcylic acid, lead salt

*Salioylaldehyde

Salicylanilide

*Salicylic acid, tech

Salicylic acid, ammonium chromium complex

Salicylic acid, sodium salt (crude)

Salicylideneaminoguanldine oleate

Sodium phenoxide

Styphnic acid, lead salt

*StyTene, all grades

p-Styrenesulfonic acid, sodium salt

i,' -Sulfamoylacetanilide

5-Sulfamoylanthranilio acid

Sulfanllic acid (p-Aminobenzenesulfonio acid) and salt-

■4-Sulfoanthranilio acid

5-Sulfoanthranilic acid

o-Sulfobenzoio, cyclic anhydride

5-Sulfoisophthalic acid, dimethyl ester

4,4' -Sulfonyldiphenol (4,4' -Dihydroxydiphenylsulfone) -■

4-Sulfophthalic acid

Terephthalic acid

*Terephthalic acid, dimethyl ester-

Terephthaloyldiacetic acid, diethyl ester

Terphenyl (Phenylbiphenyl)

[4,4',i" ,4'" -Tetraaminophthalocyaninato(2-)] copper—

Tetrabromobisphenol A

Tetrabromophenolphthaleln, ethyl ester

Tetrabromophthallc anhydride

Tetrabromo-8,16-pyranthrenedione

LIL,

OPC,

TBK.

EK.

RIL.

CMC,

ICI,

TRC.

TRC.

ACP,

KPT,

RIL.

KPT.

RIL.

EK.

RIL.

NEP.

FMT.

KF.

GGY.

DUP.

DUP,

HEX.

G.

LIL.

ACY,

DUP,

NAG.

AAP,

ACY,

CMG, DUP, EKT, HSH, ICC, ICI, JTC, MAY,

NAG, TRC.

G, HSH, NAG, PAT.

AGP,

KPT.

EK.

DUP.

GAM.

DUP.

NAG.

AAP.

KPT.

EK,

G.

ACY,

KPT.

ACY.

DOW,

HN,

MTR.

PCW.

CFC,

DOW,

HN, MON, SDH.

TRG.

DOW.

DUP.

DUP,

FIN.

RIM.

AGG,

CSD,

DOW, ELP, FG, KPP, MCB, MON, SHC, SKG,

SNT, UGG.

BKL.

ACY,

CTN.

TRG.

ACY,

CTN,

NAG.

CMG.

ICI.

EK.

X.

MON,

UPF.

GWN.

ACC,

DUP,

SOG.

AGG,

DUP,

EKT, HPC.

PGW.

MON.

DUP.

DOW.

EK.

MGH.

G, NAG.

See footnote at end of table.

CYCLIC INTERMEDIATES

89

TABLE IB. Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

1,3,6,8-Tetrabromopyrene

*l,4-,5,8-Tetrachloroanthraquinone

l,2,<i,5-Tetraohlorobenzene

Tetraohloronitrobenzene

a,a,2,6-Tetraohlorotoluene

Tetrachloroviolanthrone

Tetrahydrofuran

1,4,5,8-Tetrahydroxyaiithraquinone

l,4-,5,8-Tetrald.s[ l',l" ,1"' ,1"" -anthraquinonylamino]-- anthr aquinone ( Pentanthrimide ) .

2-(l,l,3,3-Tetramethyl'butyl)-p-cresol

p-(l,lj3,3-TetramethyllDutyl)phenol

N,N,N ' ,N '-Tetramethyl-p-phenylenediamine dihydroohloride-

[4-,4',4",'4"'-Tetramtrophthalooyanlnato(2-)]copper

2- ( 2 -Thenylamino) pyridine

Thianthrene-XjY-dicartoxylic aoid

Thianthrene-XjY-dinitrile

Thioanisole

2-Thiobarbituric acid

3,3'-Thio'bis[7H-benz[de] anthracen-7-one]

4,4-'-Thiodianiline

6,6 '-Thiodimetanilic aoid

Thiolbenzoic acid

2-Thiophenecarboxaldeliyde

sym-Thymol

o-Tolidine

2,2 '-o-Tolidinedisulfonio acid

o-Tolidine hydrochloride

Toluenediamine

Toluene-2,4-diaTiiine (4-m-Tolylenediaiiiine)

Toluene-3,4-diaiiiine

Toluene-2,5-diaiin.ne sulfate

Toluene-2,'i-disulfonic acid

o-Toluenesulfonamide

p-Toluenesulfonamide

»o(and p ) -Toluenesulf onic acid

p-Toluenesulfonic acid

Toluenesulfonio acid, aniline salt

p-Toluenesiilfonio acid, 2-chloroethyl ester

p-Toluenesulfonic acid, ethyl ester

p-Toluenesulfonic acid, methyl ester

p-Toluenesulfonic acid monohydrate

p-Toluenesulfonyl chloride

p-Toluhydroquinone (Methylhydroquinone)

m-Toluio aoid

o-Toluic aoid

p-Toluic acid

m-Toluidine

o-Toluldine

o-Toluidine hydrochloride

p-Toluldine

N-(p-Toluidine)methyltaurine '■

Toluldines, mixed

2-o-Toluidlnoethanol

N-(2-(m-Toluidino)ethyl)suocinimide

m-Toluidinomethanesulfonio acid

o-Toluidinomethanesulfonio aoid

8-(p-Toluidino) -1-naphthalenesulfonio acid

*o-(p-Toluoyl)benzoic acid ->

*<i-(o-Tolylazo)-o-toluidlne

4-(o-Tolylazo)-o-toluidine hydrochloride

2,2 '-(m-Tolylimlno)diethanol

3,4',5-Tribromosalioylanilide

l,2,3(and 1,2,4) -Trichlorobenzene

1,2,4-Trichlorobenzene

Manufacturers' identification codes (according to list in table 22)

DUP,

G, ICI,

NAC.

DOW,

HK.

SDH.

DUP.

ICI.

DUP,

0^0

NAC.

ICI,

NAC

ACY.

G.

EK.

DUP.

ABB.

TRC.

TRC.

PIT.

EK.

ACY,

DUP

G.

ACY.

NAC.

EVN.

ABB.

GIV.

CWH,

DUP

LAK

AAP.

AAP,

DUP

EK.

OMC.

ACY,

BL,

DUP,

G, NAC, SDC, TRC.

X.

EK.

G.

MQN.

MON.

CTN,

MDN

NAC

, NES, SW, UPF.

ACY,

TN,

UPF.

NES.

G.

NAC.

ICI.

CTN,

NES.

MDN.

EKT.

CWL.

CWL.

CWL.

DUP,

NAC.

DUP,

NAC.

ACY,

EK.

DUP,

NAC.

BUG.

DUP.

EKT.

EKT.

TRC.

TRC.

NAC.

ACY,

DUP,

NAC

ACY,

DUP,

G, KLS, NAC, SDH, TRC

G.

EKT,

G.

DOW,

MEE.

PPG.

DOW,

HK,

SVT.

90

SYNTHETIC ORGANIC CHEMICALS. 1964

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

N, 2,6-Triohloro-p-benzoquinoneimine

l,2,4-Trichloro-5-nitrobenzene

Trichlorophenylsilane

a,aja-Ti-ichlorotoluene (Benzotri chloride)

ctjaj'i-Trichlorotoluene

ct ,2,4- (and a,2,6)-Trichlorotoluene

C( ,3j4— Trichlorotoluene

IjSjS-Triethylbenzene

3-Trifluoromethyldiphenylaiiiine

2-Trifluoromethylphenothiazine

a,a,a-Trlfluoro-4-nitro-m-cresol

a,o ja-Trifluoro-m-nitrotoluene

a^a^a-Trifluorotoluene

a,a,a-Trifluoro-m-toluidine

1,2,4-Trihydroxyanthraquinone

2,3,5-Triiodobenzoic acid

3,'4,5-Trimethoxybenzoic acid

2,4,5-Trimethylaniline (Pseudocumidine)

1,2,4- Trimethylbenzene (Pseudocuraene)

2,3,3-Trimethy-3H-indole

*l,3,3-Trimethyl-A^j^-indolineacetaldehyde

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)'

Trimethylphenylammonium iodide

a, a',2-Trimethyl-l,4-piperazine diethanol

1,3,5-Trinitrobenzene

2,4,6-Trinitrobenzoic acid

2,4,7-Trinitrofluorenone-9-one

Triphenylmethanol

2,4,6-Tris [dimethylaminomethyl] phenol

Tropine

m-Ureidoaniline

*6,6'-Ureylenebis[l-naphthol-3-sulfonic acid] (J acid urea) .

Veratraldehyde (3,4-Dimethoxybenzaldehyde)

p-Vinylbenzenesulfonic acid, sodium salt

2-Vinylcyclohexene

4-Vinylcyclohexene

2,2'-Vinylenebis[benzimidazole]

5-Vinyl-2-picoline (MVP)

2-Vinylpyridine

4-Vinylpyridine

*Violanthrone (Dibenzanthrone)

9-Xanthenecarboxylio acid

m-}(ylene

*o-Xylene

*p-Xylene

m-Xylene-a,a' -diamine

Xylenesulfonic acid

2,5-Xylenesulfonic acid

}(ylenol crystals

Xylenols :

Low b.p

^Medium b.p

Not classified as to b.p

Xylldines:

2,4-Xylidine (m-4-Xylidine)

2,5-Xylidine (p-Xylidine)

Original mixture

4-(2,4-Xylylazo)-o-toluidine

4-(2,5-Xylylazo) -o-toluidine

4-(Xylylazo)xylldine

4-(2,4-Xylylazo)-2,5-xylidine

All other cyclic intermediates

ALL, PCW.

Dec, UCS.

HK, HN, TNP.

HN.

BPC.

HN.

DUP.

SK.

SK.

MEE.

MEE.

HK.

MEE.

G.

EK.

ICO.

NAG.

ENJ, PLC.

G.

DUP, G, VPC.

DUP, G, VPC.

EK.

WYN.

EK.

EK.

EK.

EK.

RH.

CTN.

ICI.

ACY, ATL, CMG,

G, NAC, TRC, VPC.

GIV, LIL, SLV.

DUP.

UCC.

PLC.

TRC.

PLC.

RIL.

RIL.

ACY, ATL, DUP,

G, ICI, MAY, TRC.

MAL.

PLC, SNT, see.

ASH, CCP, CSD,

CSC, DLH, ENJ, MON, PLC, SIN, SNT

SOC, TOC.

CSD, ENJ, SIN,

SNT, SOC.

X.

NES.

EK.

ACP, KPT.

NPC, PIT, PRD.

KPT, NPC, PIT,

PRD.

KPT, NPC, PHD.

DUP, MAC.

DUP, NAC.

DUP, NAC.

NAC.

ACY, NAC.

CCW, G, HPC, ICC, LIL, UPJ, x, x, x.

■■■ Does not include manufacturers ' identification codes for producers that report to the Division of Bitiminous Coal, U.S. BiJreau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers in the United States in 196/,, May 17, 1965.

DYES Dyes

TABLE SB.— Benzenoid dyes for which U.S. production or sales were reported identified by manufacturer, 1964 '

[Ayes for which separate statistics are given in table 8A are marked below with an asterisk (*); dyes not so marked do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manufac- turers' Identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Dye

ACID DYES

*Acid yellow dyes:

Acid Yellow 1

Acid Yellow 2

*Acid Yellow 3

Acid Yellow 4-

Acid Yellow 7

Acid Yellow 9

*Acid Yellow 11

Acid Yellow 1^

*Acid Yellow 17

»Acid Yellow 23—

Acid Yellow 25

Acid Yellow 29

Acid Yellow 34

*Acid Yellow 36

Acid Yellow 38

*Acid Yellow 4-0

*Acid Yellow 42

*Acid Yellow 44

»Aoid Yellow 54

Acid Yellow 59

Acid Yellow 60

Acid Yellow 63

Acid Yellow 65

*Aeid Yellow 73

Acid Yellow 76

Acid Yellow 90

Acid Yellow 95

*Aoid Yellow 99

Acid Yellow 114

Acid Yellow 121

Acid Yellow 124

Acid Yellow 127

Acid Yellow 128

Acid Yellow 129

Acid Yellow 151-

Acid Yellow 152

Acid Yellow 159—

Other acid yellow dyes

*Acid orange dyes:

*Aoid Orange 1

Acid Orange 2

Acid Orange 5

Acid Orange 6

*Acid Orange 7

*Acid Orange 8

«-Acid Orange 10

Acid Orange 12

Acid Orange 19

Manufacturers' identification codes (according to list in table 22)

ACY.

DUP.

ACY, DUP, NAG.

SDH.

NAC.

ACY.

CMG, DUP, VPC.

THC.

ACY, ATL, BKS, CMG, DUP, G, NAC, PBC, SDH, TRC, VPC.

AAP, ACY, G, MRX, NAC, SDH, TRC, VPC.

G.

G, TRC.

NAC.

DUP, G, NAC, TRC.

NAC.

ACY, DUP, G, NAC, TRC, VPC.

AAP, ACY, G, VPC.

AAP, G, NAC, VPC.

ACY, BKS, CMG, G, NAC, TRC, VPC.

VPC.

NAC.

AAP, NAC.

TRC.

G, NAC, NYC, SDH.

TRC.

NAC.

CM}.

CMG, G, NAC, TRC, VPC.

CMG, TRC.

G.

DUP, NAC.

TRC.

TRC.

TRC.

ACY.

ACY.

TRC.

ACY, ALT, CMG, DUP, VPC.

ALT, BKS, G, NAC.

NAC.

ACY.

NAC.

AAP, ACY, ATL, BKS, CPC, G, NAC, PDC, TRC, YAW.

ACY, AIL, BKS, DUP, G, NAC, IRC.

ACY, ATL, DUP, G, NAC, TRC, VPC, YAW.

NAC.

G.

92

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8B.

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Dye

ACID DYES- -Continued

»Acld orange dyes Continued

»Acld Orange 24

Acid Orange 28

Acid Orange 31

Acid Orange 32

Acid Orange 34

Acid Orange 45

Acid Orange 49

Acid Orange 51

Acid Orange 52

Acid Orange 56

»Acid Orange 60

Acid Orange 62

Acid Orange 63

Acid Orange 64

Acid Orange 69

Acid Orange 72

*Acid Orange 74

Acid Orange 76

Acid Orange 85

Acid Orange 86

Acid Orange 114

Acid Orange 116

Acid Orange 119

Other acid orange dyes

*Acid red dyes:

»Acid Red 1

»Acid Red 4

Acid Red 12

*Acid Red 14

Acid Red 17

»Acid Red 18

Acid Red 25

»Acid Red 26

Acid Red 27

Acid Red 29

Acid Red 32

Acid Red 33

Acid Red 34

Acid Red 35

*Acid Red 37

Acid Red 42

Acid Red 52 -•

Acid Red 57

Acid Red 60

Acid Red 66

»Acid Red 73

Acid Red 76

Acid Red 80

*Acid Red 85

»Acid Red 87

*Acid Red 88

*Acid Red 89

Acid Red 92

Acid Red 94

Acid Red 97

»Acid Red 99

Acid Red 100

Acid Red 106

Acid Red 109

Acid Red 113 -

Manufacturers' identification codes (according to list in table 22)

AAP, ACY,

DUP, G,

NAC.

AAP.

AAP.

ACY.

NAC, TRC.

TRC.

CMG, NAC,

TRC.

NAC.

G.

CMG, DUP,

G.

TRC.

G, TRC.

ACY, DUP,

NAC.

ACY.

G.

CMG, G, NAC, TRC

NAC, TRC.

NAC.

NAC, TRC.

ACY.

BKS, TRC.

TRC.

ALT, VPC.

NAC, TRC, YAW.

AAP, ACY, BKS, DUP, G, NAC, SDH, TRC, VPC, YAW.

ATL, CMG, DUP, G, TRC, VPC, YAW.

G, NAC, TRC.

ATL, DUP, G, NAC, PDC.

ATL, NAC, TRC, YAW.

ACY, ATL, DUP, G, NAC, TRC.

TRC.

ACY, ATL, CPC, G, NAC.

NAC.

NAC.

G, NAC.

NAC, YAW.

DUP, NAC.

AAP, G.

BNS, CMG, DUP, G, NAC, TRC.

G.

G.

TRC.

TRC.

AAP, NAC.

ACY, DUP, G, NAC, TRC.

NAC.

G, ICI.

ACY, ALT, ATL, BKS, CMG, DUP, G, NAC, PDC, TRC, VPC,

YAW. AMS, NYC, SDH.

ACY, ATL, DUP, G, NAC, SDH, TRC, YAW. AAP, G, TRC, VPC. NYC, SDH. NYC. ATL, G.

CMG, NAC, TRC, VPC. VPC. YAW. VPC. DUP.

DYES

TABLE 8B. —Bemenoid dyes for which U.S. production or sales were reported identified by manufacturer, 1964— Continued

93

Dye

ACID DYES--Continued

*Aoid red dyes Continued

Acid Red lU

»Acid Red 115

Aoid Red 119

Acid Red 133

Acid Red 134

»Acld Red 137

»Aoid Red 151

Aoid Red 153

Acid Red 167

Acid Red 172

Acid Red 175

Acid Red 178

Aoid Red 179

*Aoid Red 182—

Acid Red 183

Aoid Red 184-

»Acid Red 186

Acid Red 190— -

Aoid Red 191

Aoid Red 194—

Acid Red 207—

Aoid Red 212

Acid Red 213

Acid Red 218

Aoid Red 273

Acid Red 292

Acid Red 299—

Aoid Red 309—

Other aoid red dyes

*Acid violet dyes :

*Acid Violet 1

*Aold Violet 3—

Acid Violet 6

*Aoid Violet 7

Aoid Violet 11

*Aoid Violet 12

Aoid Violet 13

Acid Violet 14

*Acid Violet 17

Aoid Violet 21

Aoid Violet 29

Aoid Violet 34

Acid Violet 41

*Aoid Violet 43

Acid Violet 49

Acid Violet 56

Acid Violet 58-;

Acid Violet 76

Acid Violet 78

Other acid violet dyes *Acid blue dyes:

Aoid Blue 1

»Acid Blue 7

*Acid Blue 9

Aoid Blue 10

Acid Blue 13

Aoid Blue 15

Aoid Blue 20

Acid Blue 22

Aoid Blue 23

»Aoid Blue 25

Acid Blue 26

Acid Blue 27

Manufacturers ' identification codes (according to list in table 22)

ATL, DUP, G.

G, NAG, TRC.

NAC.

G.

TRC.

ACY, DUP, G, NAC, TRC.

AAP, ACY, BKS, THG, YAW.

YAW.

BKS, NAC, TRC.

VPC.

DUP.

DUP.

CMG.

ACY, BKS, CMG, DUP, G, NAC.

CMG, TRC.

TRC.

ACY, BKS, CMG, DUP, G, TRC, VPC.

ACY.

TRC.

TRC.

NAC.

TRC.

TRC.

NAC.

G.

ACY.

TRC.

TRC.

ACY, ALT, ATL, TRC, VPC.

CMS, G, NAC.

ACY, DUP, NAC, TRC, YAW.

NAC.

AAP, CMG, DUP, G, NAC, THC, VPC.

G.

CMG, DUP, G.

DUP.

THC.

DUP, G, SDH, TRC.

DUP.

HSH.

ICI, NAC.

CMG.

DUP, HSH, ICI.

ACY, NAC.

CMG, G.

G.

NAC.

NAC.

ALT, DUP, TRC.

G, NAC, SDH.

ACY, G, NAC, SDH, VPC.

G, NAC, SDH, VPC.

AAP, NAC.

DUP.

DUP, G.

ACY, NAC.

ACY, NYC.

NAC, TRC.

ATL, CMG, DUP, G, NAC, TRC.

NAC.

CMC, G.

94

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8B.

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Rye

ACID DYES- -Continued

*-Acid blue dyes Continued

Acid Blue 29

Acid Blue 34

Acid Blue 35

*Acid Blue 40

*Acld Blue 4-1

*Acid Blue 43

-fAcid Blue 45

Acid Blue 47

Acid Blue 48

Acid Blue 58

Acid Blue 59

Acid Blue 62

Acid Blue 63

Acid Blue 67

Acid Blue 69

Acid Blue 74

*Acid Blue 78

Acid Blue 80

Acid Blue 81

Acid Blue S3

Acid Blue 89

Acid Blue 90

Acid Blue 92

Acid Blue 93

Acid Blue 102

Acid Blue 104

*Acid Blue 113

Acid Blue 118

Acid Blue 120

Acid Blue 122 -

Acid Blue 137

Acid Blue 145

*Aeid Blue 158 and 158A

Acid Blue 165

Acid Blue 179

Acid Blue 230

Aold Blue 231

Other acid blue dyes

«Aoid green dyes :

Acid Green 1

»Acid Green 3

Acid Green 5

*Acld Green 9

*Acid Green 12

»Aoid Green 16

*Acid Green 20

*Acid Green 22

»Aoid Green 25

Acid Green 35

Acid Green 41

Acid Green 44

Acid Green 50

Acid Green 58

Other acid green dyes

ifAold brown dyes :

Acid Brown 1

Acid Brown 2

Acid Brown 6

Manufacturers ' identification codes (according to list in table 22)

YAW.

NAC.

NAC.

ATL,

G, ICI, NAC, TRC.

CMG,

G, NAC.

ACY,

G, NAC, TRC.

ACY,

CMG, DUP, G, NAC, TRC, VPC.

DUP,

ICI.

HSG.

DUP.

NAC.

G, VPC.

CMG,

NAC.

CMG,

NAC.

DUP,

G.

DUP,

NAC.

DUP,

G, ICI, NAC, TRC.

NAC,

TRC.

ICI.

G.

NAC.

G, NAC, TRC.

NAC.

HSC.

NAC,

TRC.

DUP,

G, NAC.

CMG,

DUP, G.

BKS,

G, NAC.

BKS,

G, NAC.

DUP.

NAC.

DUP.

ACY,

BKS, G, NAC, TRC, VPC.

DUP.

G.

TRC.

TRC.

ACY,

ALT, CMG, DUP, TRC, VPC.

ACY,

NAC.

ACY,

DUP, G, NAC, TRC, VPC.

G.

ACY, DUP, G, NAC, VPC.

G, NAC, TRC.

DUP, G, NAC, SDH, TRC.

CMG, DUP, G, NAC, TRC.

G, HSH, NAC.

AAP, ATL, CMG, G, ICI, NAC, TRC, VPC.

TRC.

ICI, VPC.

VPC.

ACY, G, VPC.

TRC.

ALT, TRC, VPC.

CM3, G.

AAP.

G.

DYES

95

TABLE BB.--Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i564-- Continued

Dye

ACID DYES— Continued

*Aoid brown dyes Continued

«Acid Brown lA

Acid Brown 19

Acid Brown 22

Acid Brown 28

Acid Brown 29

Acid Brown 31

Acid Brown A5

Acid Brown 96

Acid Brown 97

Acid Brown 98

Acid Brown 152

Acid Brown 158

Acid Brown 223

Acid Brown 243

Other acid brown dyes

*Acid black dyes:

»Aoid Black 1

Acid Black 2

Acid Black 12

Acid Black 16

Acid Black 18

*Acid Black 24

Acid Black 26, 26A, and 26B

Acid Black 29

Acid Black 41

*Acid Black 48

»Acld Black 52

Acid Black 53

Acid Black 58

Acid Black 60

Acid Black 92

*Acid Black 107

Acid Black 138

Other acid black dyes

AZOIC DYES AND COMPONENTS Azoic Compositions

Azoic yellow dyes:

*Azoio Yellow 1

*Azoic Yellow 2

Azoic Yellow 3

Azoic orange dyes:

*Azoic Orange 3

Azoic Orange 4

*Azoic red dyes:

»Azoic Red 1

*Azoic Red 2

*Azoic Red 6

Azoic Red 13

Azoic Red 14

Azoic Red 15

*Azoio Red 16

Manufacturers' identification codes (according to list in table 22)

ACY, DUP, G, NAC, TRC, YAW.

AAP,

TRC.

DUP.

TRC.

DUP, NAC.

G.

TRC.

ACY.

ACY.

ACY, TRC.

G.

G.

G.

G.

ALT, DUP, G, VPC

AAP, ACY, ATL, BKS, CMG, DUP, FAB, G, NAC, PDC, TRC,

YAW. ACY, NAC. NAC. NAC'. NAC.

CMG, DUP, G, NAC. DUP, NAC, TRC. G, NAC. G, NAC.

ACY, CMG, DUP, G, ICI, NAC, TRC. G, NAC, TRC. CMG, NAC. CMG, NAC, TRC. TRC. ACY.

G, NAC, TRC. VPC. ALT, BL, DUP, PDC.

ALL, ATL, BUG, G, HST, VPC. ALL, BUC, HST, x. ATL, BUC, G.

ALL,

ATL,

BUC,

G,

VPC,

X.

G.

ALL,

ATL,

BUC,

G,

HST,

X.

ALL,

ATL,

BUC,

G,

X.

ALL,

ATL,

BUC,

G,

HST,

VPC, X

G.

G.

G.

ATL,

BUC,

G.

96

TABLE 8B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Cye

AZOIC DYES AND COMPONENTS- -Continued

Azoic Compositions— Contiuued

»Azoio red dyes Continued

Azoic Red 73

Azoic Red lA

Other azoic red dyes

Azoic violet dyes:

Azoic Violet 1

Other azoic violet dyes

Azoic "blue dyes:

»Azoic Blue 2

*Azoic Blue 3

Azoic Blue 4-

Azoic Blue 6

Azoic Blue 7

Other azoic blue dyes

Azoic green dyes:

Azoic Green 1

Other azoic green dyes

Azoic brown dyes:

*Azoic Brown 9

Azoic Brown 10

Azoic Brown 26

Other azoic brown dyes

»Azoic black dyes:

Azoic Black 1

Azoic Black 2

Azoic Black <>

Azoic Black 15

Other azoic black dyes

Other azoic compositions

Azoic Diazo Components, Bases (Fast Color Bases)

Component 1, base Component 2, base Component 3, base Component 4, base Component 5, base Component 8, base--- Component 9, base Component 10, base-- Component 11, base-- Component 12, base-- Component 13, base-- Component 14-, base-- Component 20, base-- Component 24-, base-- Component 28, base-- Component 32, base-- Component 3A, base-- Component ■41, base-- Component 42, base- Component "W-, base-- Component A6, base- Component 48, base- Component 49, base- Component 121, base

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

*Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

» Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

»Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

»Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

*Azoic

Diazo

Azoic

Diazo

Azoic

Diazo

Manufacturers' identification codes (according to list in table 22)

ATL, BUC, G, VFC, x.

ATL, G, X. G.

ATL, BUC, G.

ALL, ATL, BUC,

G.

ATL, G.

G.

G, VPC.

G, HST,

ATL, G. VPC.

ATL, BUC, G, HST, VPC, x.

BUC.

G.

BUC, G, VPC, X.

G, HST.

BUC.

ALL, ATL, G.

G.

ATL, G, VPC.

ALL.

SDH.

AAP, ATL.

AAP, KLS, SDH.

ALL, G, KLS, NAC, SDH.

G, SDH.

DUP, NAC.

AAP, DUP, VPC.

BUC, G, KLS.

BUC.

AAP, ALL, AUG, KLS, SDH.

AAP, ALL, AUG, KLS, SDH.

AAP.

ALL, G.

KLS.

ALL, KLS, SDH.

AAP, ALL, ATL, AUG, BUC, DUP, KLS, SDH.

G.

ALL, G.

ALL.

AAP.

ATL.

ALL, CWN, DUP, G.

KLS.

PCW.

DYES

97

TABLE 8B.-

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Eye

AZOIC DYES AND COMPONENTS- - Ctontinued

Azoic Diazo Components, Salts (Fast Color Salts)

»Azoio Diazo Component 1, salt

Azoic Diazo Component 2, salt

**Azoic Diazo Component 3, salt

Azoic Diazo Component 4, salt

»Azoio Diazo Component 5, salt

■''Azoio Diazo Component 6, salt

*Azoic Diazo Component 8, salt

*fAzoio Diazo Component 9, salt

*Azoio Diazo Component 10, salt

«Azoio Wazo Component 11, salt

*Azoic Diazo Component 12, salt

*Azoic Diazo Component 13, salt

Azoic Diazo Component 14, salt

Azoic Diazo Component 20, salt

*Azoic Diazo Component 28, salt

»Azoic Diazo Component 32, salt

Azoic Diazo Component 34, salt

Azoic Diazo Component 35, salt

*Azoic Diazo Component 36, salt

Azoic Diazo Component 37, salt

Azoic Diazo Component 41, salt

Azoic Diazo Component 42, salt

Azoic Diazo Component 44, salt

»Azoic Diazo Component 48, salt

»Azoic Diazo Component 49, salt

Azoic Diazo Component 121, salt

Other azoic diazo components, salts

Azoic Coupling Components (Naphthol AS and Derivatives)

Azoic Coupling Component 1

»Azoio Coupling Component 2

*Azoic Coupling Component 3

»Azoic Coupling Con^ionent 4

Azoic Coupling Component 5

*Azolc Coupling Component 7

Azoic Coupling Component 8

Azoic Coupling Component 10

Azoic Coupling Component 11

Azoic Coupling Component 12

Azoic Coupling Component 13

»Azoic Coupling Component 14

Azoic Coupling Component 15

Azoic Coupling Component 16

*Azoic Coupling Component 17

*Azoic Coupling Component 18

*Azoic Coupling Component 19

■KAzoic Coupling Component 20

wAzoic Coupling Component 21

Azoic Coupling Component 23

Azoic Coupling Component 24

*Azoic Coupling Component 29

Azoic Coupling Component 34

Azoic Coupling Component 35

Manufacturers ' identification codes (according to list in table 22)

AAP,

AUG, G, KLS, SDH.

ALL,

BUC, KLS.

AAP,

ALL, AUG,

BUC, G,

KLS,

NAC,

SDH,

VPC

ALL,

AUG, DUP.

AAP,

AUG, BUC,

G, KLS,

SDH,

VPC.

AAP,

G, KLS, SDH.

AAP,

ALL, AUG,

BUC, G,

KLS.

AAP,

ALL, AUG,

BUC, G,

KLS,

NAC,

SDH,

VPC

AUG,

BUC, G, KIS.

AAP,

G, KLS.

AAP,

ALL, AUG,

BUC, G,

KLS,

SDH.

AAP,

ALL, AUG,

BUC, G,

KLS,

NAC,

SDH,

VPC

AAP.

ALL,

G.

ALL,

AUG, BUC,

G, KLS,

SDH,

VPC.

ALL,

AUG, BUC,

KLS, SDH.

G.

G.

AAP,

G, NAC.

G.

ALL,

G.

ALL,

G, KLS.

G.

AAP,

ALL, G, KLS, NAC,

SDH.

AAP,

BUC, G, KLS.

BUC.

ATL, AUG.

ACY, ATL, BUC, DUP, G, NAC, PCW.

BUC, G, PCW.

ATL, BUC, G.

AAP, G.

AAP, AUG, G, PCW.

ATL, G, PCW.

PCW, SDH.

BUC, G, PCW.

ALL, BUC, G, PCW.

ALL, G.

ALL, ATL, BUC, G, PCW.

ACY, ALL, ATL, BUC, DUP, PCW.

ACY, ATL, BUC, DUP, G, PCW.

AAP, BUC, G, PCW.

ALL, ATL, BUC, DUP, G, PCW.

ATL, BUC, PCW.

G, PCW.

ATL, BUC, G, PCW. BUC, G, PCW. ALL, G, PCW.

98

TABLE 8B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i 564 Continued

AZOIC DYES AND COh/IPONENTS-- Continued

Azoic Coupling Components (Naphlkol AS and Denvativesj-CtrntinuBd

Azoic Coupling Component 36

Azoic Coupling Component 43

Other azoic coupling components

Basic yellow dyes :

Basic Yellow 1

*Basic Yellow 2

Basic Yellow 5

*Basic Yellow 11

*Basic Yellow 13

Basic Yellow 15

Basic Yellow 26

Basic Yellow 27

Basic Yellow 28

Cither basic yellow dyes *Basic orange dyes :

*Basic Orange 1

»Basic Orange 2

Basic Orange 10

Basic Orange 14

Basic Orange 17

ifBasic Orange 21

Basic Orange 22

Basic Orange 24

Basic Orange 25

Basic Orange 26

Basic Orange 31

*BaEic red dyes:

Basic Bed 1

*Basio Red 2

Basic Red 9

Basic Red 12

Basic Red 13

*Basic Red 14

Basic Red 15

Basic Red 16

Basic Red 17

Basic Red 18

Basic Red 19

Basic Red 20

Basic Red 22

Basic Red 30

»Basic violet dyes :

**Basic Violet 1

Basic Violet 2

ifBasic Violet 3

*Basic Violet 4

Basic Violet 7

Basic Violet 10

Basic Violet 13

*Basic Violet 14

Basic Violet 15

*Basic Violet 16

Basic Violet 18

Other basic violet dyes-

li'lanuf aoturers ' identification codes (according to list in table 22)

AIL, G. ATL, G, VPC.

DUP.

ACY, DUP, NAG.

NAG.

DUP, G, NAG, VPC.

DUP, G, NAG.

DUP.

ACY.

ACY.

VPC.

G, DUP.

ACY, DUP, G, NAG.

ACY, DSC, DUP, G, NAG, PDG, TRC.

VPC.

G.

NAC.

DUP, G, NAC, VPC.

G, NAC.

DUP.

DUP.

DUP.

ACY.

DUP, G.

DUP, G, NAC.

DSC, HSC.

DUP.

G, NAC.

ACY, DUP, G, NAC, VPC.

DUP, G.

DUP.

DUP.

DUP.

DUP.

DUP.

ACY, TRC.

ACY.

ACY, DSC, HSC, NAC.

ACY, NYC.

DSC, DUP, G, NAG, SDH.

DSC, DUP, G, NAG.

G, NAG.

ACY, DUP, G.

DSC.

ACY, DSC, NYC.

DUP.

DUP, G, VPC.

ACY.

DUP, G.

TABLE 8B.-

DYES

-Benzerwid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

99

BASIC DYES— Continued

*Basio blue dyes:

»Basic Blue 1

Basic Blue 3

Basic Blue 4

Basic Blue 5

Basic Blue 6

*Basic Blue 7

»Basio Blue 9

Basic Blue 11

Basic Blue 21

Basic Blue 22

*Basic Blue 26

Basic Blue 35

Basic Blue 36

Basic Blue 38

Basic Blue 39

Basic Blue 54

Other basic blue dyes

Basic green dyes:

«Basic Green 1

Basic Green 3

*Basic Green 4

Basic Green 5

Other basic green dyes

Basic brown dyes :

*Basic Brown 1

Basic Brown 2

*Basic Brown 4

Basic black dyes:

Basic Black 3

Other basic black dyes

DIRECT DYES

^Direct yellow dyes:

«Direot Yellow 4

^Direct Yellow 5

*Direct Yellow 6

Direct Yellow 7

Direct Yellow 8

Direct Yellow 9

*Direct Yellow 11

«Direct Yellow 12

Direct Yellow 19

Direct Yellow 20

Direct Yellow 23

*Direct Yellow 26

Direct Yellow 27

^Direct Yellow 28

^Direct Yellow 29

Direct Yellow 39

*Direct Yellow 44

*Direct Yellow 50

*Direct Yellow 59

Direct Yellow 63

Direct Yellow 81

*Direct Yellow 84

Direct Yellow 103 .

Manufacturers' identification codes (according to list in table 22)

DSC, G, NAC, SDH.

G.

DUP.

DSC, SDH.

ACY, NAG.

DSC, DUP, G, MAC, SDH.

ACY, G, NAC, SDH.

ESC, DUP, SDH.

DUP.

DUP, NAC.

DSC, DUP, G, NAC, SDH.

DUP.

DUP.

ACY, DUP.

DUP.

ACY.

ACY, G.

ACY, DSC, DUP, NAC, SDH.

DUP.

ACY, DSC, NAC, SDH.

ACY.

DUP.

ACY, DUP, G, NAC, TRC.

G, NAC.

ACY, DUP, G, NAC, TRC.

G. DUP.

ACY, DUP, G, NAC, TRC.

ACY, BL, G, NAC.

ACY, DUP, G, NAC, TRC.

ATI.

G, NAC.

DUP.

ACY, DUP, G, NAC, TRC.

BKS, DUP, G, NAC, TRC.

TRC.

TRC.

DUP.

ALT, BKS, DUP.

G.

ATL, DUP, G, NAC, TRC,

ATL, DUP, G.

TRC.

ALT, ATL, BKS, DUP, G, NAC, TRC, VPC.

AIL, BKS, BL, DUP, G, NAC, TRC, VPC.

ATL, DUP, NAC.

DUP.

BKS, TRC.

G, NAC, TRC.

NAC.

100

TABLE 8B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

DIRECT DYES— Continued

»Direot yellow dyes Continued

Direct Yellow 105

Direct Yellow 106

Direct Yellow 107

Direct Yellow IW

Direct Yellow 117

Direct Yellow 118

Direct Yellow 121

Direct Yellow 125

Other direct yellow dyes

»Direct orange dyes:

^Direct Orange 1

Direct Orange 6

*Direct Orange 8

Direct Orange 10

Direct Orange 11

*Direct Orange 15

»Direct Orange 26

Direct Orange 29

»Direct Orange 34

*Direct Orange 37

Direct Orange 38

*Direct Orange 39

Direct Orange 40

Direct Orange 48

Direct Orange 55

Direct Orange 59

Direct Orange 61

Direct Orange 67

Direct Orange 70

^Direct Orange 72

♦Direct Orange 73

Direct Orange 74

Direct Orange 76

Direct Orange 78

Direct Orange 79

Direct Orange 80

♦Direct Orange 81

Direct Orange 83

Direct Orange 88

♦Direct Orange 102

Direct Orange 105

Direct Orange 110

Other direct orange dyes

♦Direct red dyes:

♦Direct Red 1

♦Direct Red 2

♦Direct Red 4

Direct Red 5

Direct Red 7

♦Direct Red 10

♦Direct Red 13

♦Direct Red 16 -•

Direct Red 20

♦Direct Red 23

♦Direct Red 24

♦Direct Red 26

♦Direct Red 28

Direct Red 30

♦Direct Red 31

Direct Red 32

TRC.

BKS,

TRC.

G.

ACY.

TRC.

ACY,

TRC.

TRC.

ACY.

ALT,

ATL,

BL,

DUP, FAB, G, VPC.

AAP,

CMG,

NAC

VPC.

NAC.

ATL,

DUP,

G,

■lAC, TRC.

AAP,

NAC.

G.

ACY,

DUP,

G,

\IAC, TRC.

ATL,

CMG,

DUP

G, NAC, TEC.

ATL,

BKS,

TRC

ACY,

ATL,

CMG

DUP, G, NAC.

ACY,

CMG,

DUP

G, TRC.

NAC.

ATL,

BKS,

CMG

DUP, G.

DUP.

DUP.

DUP,

NAC.

DUP,

G.

TRC.

NAC,

VPC.

TRC.

ACY,

AIL,

BKS

, BL, FAB, NAC, TRC, VPC

DUP,

G, TRC,

VPC.

DUP.

DUP.

DUP,

VPC.

DUP.

DUP,

VPC.

DUP,

G, NAC,

VPC.

G, NAC.

DUP.

ACY,

DUP,

G,

NAC.

BKS.

TRC.

ALT,

ATL,

BL,

DUP, G, VPC.

AAP, ATL, DUP, G, NAC, TRC, YAW.

ATL, BKS, DUP, NAC, TRC.

NAC, TRC, VPC.

NAC.

DUP.

AAP, ACY, ATL, NAC.

AAP, AIL, DUP, G, NAC, TRC, YAW.

ATL, DUP, G, NAC, TRC.

G, NAC.

ATL, BKS, CMG, DUP, FAB, G, NAC, TRC, VPC.

AAP, ATL, BKS, BL, FAB, NAC, TRC, VPC.

ATL, BKS, CMG, DUP, G, NAC, TRC, VPC.

ATL, DUP, NAC, TRC.

VPC.

ATL, DUP, G, NAC.

DUP, NAC.

DYES

101

Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

DIRECT DYES--Continued

»Direot red dyes Continued

*Direot Red 37

^Direct Red 39

Direct Red 4-6

Direct Red 53

Direct Red 62

Direct Red 72

Direct Red 73

»Direct Red 75

Direct Red 76

^Direct Red 79

«Direct Red 80

*Direct Red 81

*Direct Red 83

Direct Red 84

Direct Red 94

Direct Red 95

Direct Red 100

Direct Red 111

Direct Red 117

Direct Red 122

Direct Red 123

Direct Red 127 and 127A

Direct Red 139

Direct Red 148

^Direct Red 149

*Direot Red 152

Direct Red 153

Direct Red 155

Direct Red 209

Other direct red dyes

*Direct violet dyes:

^Direct Violet 1

Direct Violet 7

»Direct Violet 9

Direct Violet 14

Direct Violet 22

Direct Violet 30

Direct Violet 47

»Direct Violet 48

Direct Violet 49

Direct Violet 51

Direct Violet 60

Direct Violet 67

Direct Violet 68

Other direct violet dyes

*Direct blue dyes:

*Direct Blue 1

*Direct Blue 2

*Direct Blue 6

*Dlrect Blue 8

Direct Blue 10

^Direct Blue 14

»Direct Blue 15

Direct Blue 21

^Direct Blue 22

»Direct Blue 24

»Direct Blue 25

Manufacturers' identification codes (according to list in table 22)

ACY, ATL, G, NAC, TRC, YAW.

ATL, G, NAC, TRC, YAW.

ATL, TRC.

NAC.

ATL, TRC.

G, TRC.

DUP, NAC.

ACY, DUP, G, NAC, VPC.

G, NAC.

ATL, BKS, CKi, NAC, TRC, VPC.

AAP, ATL, BKS, BL, CM), DUP, FAB, G, NAC, TRC, VPC.

AAP, ACY, ALT, ATL, BKS, BL, CMG, DUP, G, NAC, THC,

VPC, YAW. ALT, ATL, BKS, CMG, DUP, NAC, TRC, VPC. G, NAC, TRC. NAC. VPC. NAC. G.

BL, DUP.

cm, G, TRC, VPC. G.

CMG, DUP, TRC. VPC. DUP.

ATL, CMG, DUP, G, NAC, TRC. CMG, DUP, NAC. NAC. G.

TRC. ALT, BL, DUP, TRC.

AAP, ATL, DUP, NAC.

G, NAC.

ATL, BKS, DUP, G, NAC, TRC.

ATL, NAC.

DUP.

AAP.

DUP, G.

DUP, NAC, TRC.

NAC.

DUP, NAC.

NAC.

DUP, NAC.

DUP.

ALT.

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, THC, VPC,

YAW.

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC, YAW.

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW.

ATL, BKS, DUP, G, NAC, TRC. DUP.

ATL, DUP, NAC, TRC.

ATL, DUP, G, NAC, YAW. TRC.

ATL, CM}, DUP, NAC.

BKS, NAC, TRC, YAW. DUP, G, NAC, TRC, YAW.

102

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8-B.—Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i 564— Continued

Dye

DIRECT DYiS Continued

^Direct blue dyes--

*Direot Blue 26-

Direct Blue 27-'

Direct Blue 55-

Direct Blue 66-

*Direct Blue 67-

wDlrect Blue 71-

Direct Blue 74-

Direct Blue 75-

*nirect Blue 76-

*Direct Blue 78-

Direct Blue 79-

*Direot Blue 80-

Direct Blue 84-

»Direot Blue 86-

Mreot Blue 87

Direct Blue 91

^Direct Blue 98

Direct Blue 100—

Direct Blue 104

♦Direct Blue 120 and 120A-

*Direct Blue 126

ELreet Blue 127

Direct Blue 130

Direct Blue 133

Direct Blue 136

Direct Blue 143

♦Direct Blue 151

Direct Blue 160

Direct Blue 180

Direct Blue 189

Direct Blue 191

Direct Blue 199

Direct Blue 238

Other direct blue dyes ♦Direct green dyes:

♦Direct Green 1

♦Direct Green 6

♦Direct Green 8

♦Direct Green 12

Direct Green 14

Direct Green 15

Direct Green 26

Direct Green 27

Direct Green 28

♦Direct Green 38

Direct Green 39

Direct Green 41

Direct Green 45

Direct Green 47

Other direct green dyes- ♦Dlrect brown dyes :

♦Direct Brown 1

♦Direct Brown lA

♦Direct Brown 2

♦Direct Brown 6

Direct Brown 11

Direct Brown 21

Direct Brown 25

Manufacturers ' identification codes (according to list in table 22)

ATL,

DUP,

G, NAC.

DUP.

NAG.

DUP.

ATL,

DUP,

NAC, TRC.

ATL,

DUP,

G, NAC, TRC.

DUP.

TRC.

ATT,,

BKS,

BL, DUP, G, NAC, TRC, VPC.

ATL,

CMG,

DUP, G, NAC, TRC.

TRC.

ALT,

ATL,

BKS, DUP, FAB, G, NAC, STD,

TRC.

DUP.

AAP,

ACY,

ATL, BKS, CMG, DUP, FAB, G,

ICC, ICI, NAC

SDH, TMS, TRC, VPC.

ICI.

TRC.

AAP,

ALT,

ATL, G, ICC, TRC, VPC.

ALT,

NAC.

DUP.

ATL,

BKS,

DUP, G, TRC.

BL,

DUP,

G, NAC, TRC, VPC.

G.

NAC.

G.

G.

DUP.

AIL,

DUP

NAC, TRC.

TRC.

CMG,

NAC

TRC.

TRC.

AAP,

G.

G.

ACY

ALT

ATL

BL, DUP, FAB, G, NAC, VPC.

AAP, ACY, ATL, BKS, DUP, G, NAC, TRC, YAW.

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW.

ATL, NAC, TRC, YAW.

DUP, NAC, TRC.

NAC.

DUP.

NAC, TRC.

NAC, TRC.

TRC.

DUP, G, NAC.

G.

DUP.

VPC.

DUP, G.

ACY, ALT, ATL, BL, DUP.

ACY, ATL, BKS, BL, DUP, FAB, NAC.

G, TRC, YAW.

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW.

DUP, G, NAC, TRC.

NAC.

DUP.

DUP, NAC.

DYES

TABLE 8B. Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

103

Eye

Manufacturers ' identification codes (according to list in table 22)

DIRECT DYES— Continued

»Direct brown dyes Continued

Direct Brown 27

Direct Brown 29

*Direot Brown 31

Direct Brown 32

nlreot Brown 33

Mrect Brown 35

Direct Brown 'tO

Direct Brown 44

Direct Brown iS

Direct Brown 59

*Direct Brown 74

»Direot Brown 95

Direct Brown 101

Direct Brown 105

Direct Brown 106

♦Direct Brown 111

Direct Brown 112

Direct Brown 125

♦Direct Brown 154

Other direct brown dyes

♦Direct black dyes:

Direct Black 3

♦Direct Black 4

Direct Black 8

♦Direct Black 9

Direct Black 17

♦Direct Black 19

♦Direct Black 22

Direct Black 29

Direct Black 36

♦Direct Black 37

♦Direct Black 38

Direct Black 44

♦Direct Black 51

Direct Black 55

Direct Black 56

Direct Black 61

Direct Black 67

Direct Black 71

Direct Black 74

Direct Black 75

Direct Black 78

♦Direct Black 80

Direct Black 109

Direct Black 130

Other direct black dyes

DISPERSE DYES

♦Disperse yellow dyes:

♦Disperse Yellow 1

Disperse Yellow 2

♦Disperse Yellow 3

♦Disperse Yellow 5

Disperse Yellow 8

Disperse Yellow 17

♦Disperse Yellow 23

Disperse Yellow 31

Disperse Yellow 32

G.

NAC.

AAP, ATL, DUP, G, NAC, YAW.

G.

DUP, NAC.

NAC.

AAP.

G, YAW.

AAP.

ACY.

AAP, DUP, NAC.

AAP, ALT, ATL, BKS, DUP, G, NAC, TRC, YAW.

G.

DUP.

G, NAC.

DUP, G, TRC, VPC.

NAC.

G.

DUP, G, TRC, YAW.

ALT, BL, NAC, TRC, VPC, YAW.

DUP.

ATL, BKS, DUP, G, NAC, TRC, YAW.

TRC, YAW.

BKS, DUP, G, NAC, TRC.

G, NAC, TRC.

ATL, BKS, G, NAC, TRC, VPC.

AAP, ALT, ATL, BKS, CMG, DUP, G, NAC, TRC, VPC, YAW.

ATL.

AAP.

AAP, DUP, NAC.

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW.

TRC.

AAP, ATL, DUP, G, NAC, TRC.

DUP.

NAC, TRC.

TRC.

DUP, NAC.

AIL, VPC.

NAC.

G.

BKS, NAC.

AAP, ATL, BKS, BL, FAB, G, NAC, TRC, VPC, YAW.

G.

ACY.

ACY, ALT, ATL, VPC, YAW.

DUP, G, ICC.

DUP.

AAP, BL, DUP, EKT, G, HSH, ICC, NAC, SDH, STD, TRC.

EKT, G, ICC, STD.

DUP, TRC.

AAP.

DUP, EKT, ICC.

G.

DUP.

104

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8B -Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i 564 —Continued

DISPERSE DYES—Continued

♦Disperse yellow dyes Continued

♦Disperse Yellow 33

Disperse Yellow 34

♦Disperse Yellow 37

Disperse Yellow 42

Disperse Yellow 50

♦Disperse Yellow 54

Disperse Yellow 67

Other disperse yellow dyes

♦Disperse orange dyes:

♦Disperse Orange 3

♦Disperse Orange 5

Disperse Orange 16

♦Disperse Orange 17

Disperse Orange 21

Disperse Orange 25

Disperse Orange 26

Disperse Orange 29

Disperse Orange 30

Disperse Orange 38

Disperse Orange 44-

Other disperse orange dyes

♦Disperse red dyes:

♦Disperse Red 1

Disperse Red 4

♦Disperse Red 5

Disperse Red 7

Disperse Red 9

♦Disperse Red 11

♦Disperse Red 13

Disperse Red 15

♦Disperse Red 17

Disperse Red 20

Disperse Red 21

Disperse Red 30

Disperse Red 31

Disperse Red 32

Disperse Red 53

Disperse Red 55

Disperse Red 56

Disperse Red 59

♦Disperse Red 60

Disperse Red 61

Disperse Red 65

Disperse Red 66

Disperse Red 73

Disperse Red 96

Other disperse red dyes

♦Disperse violet dyes:

♦Disperse Violet 1

Disperse Violet 4

Disperse Violet 8

Disperse Violet 11

Disperse Violet 14

Disperse Violet 17

Disperse Violet 18

Disperse Violet 22

Disperse Violet 26

Disperse Violet 27

Other disperse violet dyes ♦Disperse blue dyes:

♦Disperse Blue 1

♦Disperse Blue 3

Manufacturers' identification codes (according to list in tahle 22)

AAP, EKT, ICC.

AAP, EKT, ICC.

AAP, EKT, ICC.

DUP, TEC.

TRC.

AAP, DUP, G, ICC, TRC.

DUP.

DUP, EKI, G.

AAP, DUP, EKT, G, ICC, NAC, STD, TRC.

AAP, EKT, G.

AAP.

AAP, EKI, G, HSH, ICC, NAC, STD.

TRC.

DUP.

DUP.

AAP.

TRC.

TRC.

DUP.

DUP, EKT, G, ICC, TRC.

AAP, DUP, EKT, G, ICC, NAC, STD, TRC, YAW.

G, TRC.

AAP, EKI, G, HSH, ICC, STD.

AAP.

DUP.

AAP, DUP, G, TRC.

DUP, G, ICC.

G, HSH, ICC, NAC.

AAP, DUP, EKT, G, HSH, ICC, STD, TRC.

NAC.

EKT.

EKI, TRC.

ICC.

G.

TRC.

TRC.

DUP.

DUP, G.

AAP, DUP, VPC.

DUP.

DUP.

AAP.

TRC.

ACY.

DUP, EKT, G, ICC, TRC, VPC.

AAP, DUP, G, ICC, STD, TRC.

AAP, G, ICC.

G.

EKI, NAC.

DUP.

ACY.

DUP.

G.

DUP.

AAP, BL, DUP, G.

EKT, ICC.

AAP, G, TRC. AAP, EKT, G, ICC,

NAC, STD, TRC.

DYES

105

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Dye

DISPERSE DYES^-Continued

*Dlsperee blue dyes Continued

^Disperse Blue 7

Disperse Blue 8

Disperse Blue 9

Disperse Blue 27

Disperse Blue 35

Disperse Blue 41

Disperse Blue 51

Disperse Blue 55

Disperse Blue 59

Disperse Blue 60

Disperse Blue 61

Disperse Blue 62

Disperse Blue 63

»Dlsperse Blue 64

Disperse Blue 67

Disperse Blue 70

Disperse Blue 71

Disperse Blue 73

Disperse Blue 79

Other disperse blue dyes

»Dlsperse brown dyes:

Disperse Broim 2

Other disperse brown dyes

*Disperse black dyes:

«Dlsperse Black 1

Disperse Black 2

Disperse Black 6

Disperse Black 7

*Disperse Black 9

Other disperse black dyes

FIBER-REACTIVE DYES

^Reactive yellow dyes:

Reactive Yellow 1

Reactive Yellow 2

Reactive Yellow 3

Reactive Yellow 4

Reactive Yellow 6

Reactive Yellow 7

Reactive Yellow 15

Reactive Yellow 18

Reactive Yellow 22

Other reactive yellow dyes

Reactive orange dyes:

Reactive Orange 1

Reactive Orange 2

Reactive Orange 4

Reactive Orange 5

Reactive Orange 7

Reactive Orange 12

Reactive Orange 13

Reactive Orange 14

Other reactive orange dyes

Reactive red dyes:

Reactive Red 1

Reactive Red 2

Reactive Red 3

Reactive Red 4

Reactive Red 5

Reactive Red 8

Reactive Red 11

Reactive Red 13

Reactive Red 16

Reactive Red 29

Reactive Red 31

Reactive Red 33

Other reactive red dyes

Manufacturers' identification codes (according to list in table 22)

EKT, G,

HSH,

ICC, TRC.

DUP.

G, ICC.

EKT.

G.

NAC.

G.

TRC.

DUP.

DUP.

DUP.

DUP.

DUP.

DUP, G,

TRC.

DUP.

AAP.

VPC.

TRC.

TRC.

EKT, G,

ICC,

STD.

DUP, G.

EKT, IOC

AAP, BL,

DUP

G, TRC.

DUP, TRC

DUP.

YAW.

AAP, BL,

DUP

EKT, G, KLS, NAC

DUP, EKT

, G,

ICC, YAW.

ICI. TRC. TRC. ICI. TRC. ICI. DUP. ICI. ICI. G, HST.

ICI. TRC. ICI. TRC. DUP. ICI. ICI. ICI. HST.

ICI. ICI. ICI. TRC. ICI. ICI. ICI. ICI. TRC. ICI. ICI. ICI. DUP, G, HST.

106

TABLE 8B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i 964— Continued

FIBEH-REACTIVE DYES— Continued

Reactive violet dyes:

Reactive Violet 1

Reactive Violet 2

Other reactive violet dyes- *Reactive blue dyes:

Reactive Blue 1

Reactive Blue 2

Reactive Blue 3

Reactive Blue 4

Reactive Blue 5

Reactive Blue 7

Reactive Blue 9

Reactive Blue 19

Reactive Blue 25

Other reactive blue dyes---

Reactive green dyes

Reactive brown dyes:

Reactive Brown 1

Reactive Brown 10

Reactive black dyes:

Reactive Black 1

Reactive Black 9

Other reactive black dyes-'

FLUORESCENT BRIGHTENING AGENTS

Fluorescent Brightening Agent 1

Fluorescent Brightening Agent 6

Fluorescent Brightening Agent 8

Fluorescent Brightening Agent 9

Fluorescent Brightening Agent 22

Fluorescent Brightening Agent 24-

Fluorescent Brightening Agent 25

Fluorescent Brightening Agent 28

Fluorescent Brightening Agent 30

Fluorescent Brightening Agent 33

Fluorescent Brightening Agent 34

Fluorescent Brightening Agent 37

Fluorescent Brightening Agent 45

Fluorescent Brightening Agent 46

Fluorescent Brightening Agent 49

Fluorescent Brightening Agent 52

Fluorescent Brightening Agent 61

Fluorescent Brightening Agent 66

^Fluorescent Brightening Agent 68

Fluorescent Brightening Agent 71

Fluorescent Brightening Agent 75

Fluorescent Brightening Agent 102

Fluorescent Brightening Agent 108

Fluorescent Brightening Agent 113

Fluorescent Brightening Agent 114

Fluorescent Brightening Agent 125

Fluorescent Brightening Agent 134

Fluorescent Brightening Agent 135

Fluorescent Brightening Agent 136

Fluorescent Brightening Agent 139

Fluorescent Brightening Agent 155

Fluorescent Brightening Agent 159

Fluorescent Brightening Agent 161

Other fluorescent brightening agents-

Manufacturers' identification codes (according to list in table 22)

ICI. TRC. HST.

ICI.

TRC.

ICI.

ICI.

TRC.

TRC.

ICI.

DUP.

ICI.

DUPj G, HST.

HST.

TRC. ICI.

TRC. ICI. HST.

GGX.

ACY.

ACY.

ACY, G.

GGY.

GGY.

G.

ACY, DUP.

G.

G.

DUP.

CIB.

TRC.

GGY.

S.

S.

ACY.

SDH.

CCW, G, SDH.

ACY, G.

G.

DUP.

G.

VPC.

VPC.

ACY.

CIB.

CIB.

CIB.

CIB.

WLM.

ACY.

ACY.

ACY, CCW, CIB, DUP, G, GGY, S, VPC.

DYES

107

TABLE 8B.-

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 7564--Continued

FOOD, DRUG, AND COSMETIC COLORS Food, Drug, and Cosmetic Dyes

»FDaC Blue No. 1

FD&C Blue No. 2

FD&C Green No. 1

FD&C Green No. 3

»FD&C Red No. 2

*FD&C Red No. 3

*FD&C Red No. -4

FD&C Violet No. 1

*FD&C Yellow No. 5

*FD&C Yellow No. 6

Other food, drug, and cosmetic dyes- Drug and Cos

Dye.

D&C Black No. 1

D&C Blue No. 6

D&C Blue No. 9

D&C Brown No. 1

D&C Green No. 5

D&C Green No. 6

D&C Green No. 8

D&C Orange No. 4-

D&C Orange No. 5

D&C Orange No. 10

D&C Orange No. 14-

D&C Orange No. 17

D&C Red No. 2

D&C Red No. 3

D&C Red No. 6

*D&C Red No. 7

D&C Red No. 8

D&C Red No. 9

D&C Red No. 10

D&C Red No. 11

E&C Red No. 12

E&C Red No. 13

D&C Red No. 17—

*D&C Red No. 19

*D&C Red No. 21

D&C Red No. 22

D&C Red No. 27

D&C Red No. 28

D&C Red No. 30

D&C Red No. 31

D&C Red No. 33

D&C Red No. 34

*D&C Red No. 36 ^

D&C Red No. 37

D&C Red No. 39

D&C Violet No. 2

D&C Yellow No. 5

Manufacturers ' identification codes (according to list in table 22)

BAT

KON

NAC,

SDH,

WJ.

KON

NAC

SDH.

NAC

WJ.

BAT

KON

NAC,

SDH,

STG,

WJ

BAT

KON

NAC,

SDH,

STG.

BAT

KON

NAC,

SDH,

STG,

WJ

NAC

BAT

KON

NAC,

SDH,

STG,

WJ

BAT,

KON

NAC,

SDH,

STG,

WJ

KON,

WJ.

KON,

NAC.

KON,

NAC.

NAC.

NAC.

KON,

NAC.

KON,

NAC.

KON,

SDH.

KON,

SNA.

KON,

SNA,

TMS.

TMS.

TMS.

KON,

SNA.

KON.

KON,

T^B.

SNA,

TMS.

KON,

SNA,

TMS.

TMS.

KON,

SNA,

TMS.

KON,

SNA.

KON,

SNA.

KON,

SNA,

TMS.

KON,

SNA,

TMS.

KON,

NAC.

KON,

SNA,

IMS.

KON,

SNA,

TWB.

KON.

KON,

SDH,

TMS.

NAC,

TMS.

KON.

KON.

KON,

NAC.

KON,

TMS.

KON,

SNA,

TMS.

NAC.

SDH.

NAC.

TMS.

108

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i 964— Continued

FOOD, DRUG, AND COSMETIC COLORS— Continued Drug and Cosmetic Dyes--Continued

D&C Yellow No. 7

D&C Yellow No. 8

D&C Yellow No. 10

D&C Yellow No. 11

Drug and Cosmetic Dyes, External

Ext. D&C Blue No. 1

Ext. D&C Green No. 1

Ext. D&C Orange No. 3

Ext. D&C Red No. 8

Ext. D&C Red No. U

Ext. D&C Red No. 15

Ext. D&C Violet No. 2

Ext, D&C Yellow No. 1

Ext. D&C Yellow No. 5

Ext. D&C Yellow No. 7

INGRAIN DYES

Ingrain blue dyes:

Ingrain Blue 1

Ingrain Blue 3

Ingrain Blue A

Ingrain green dye: Ingrain Green 2

^DRDANT DYES

*Mbrdant yellow dyes:

*Mordant Yellow 1

Mordant Yellow 3

Mordant Yellow 5

^Mordant Yellow 8

Mordant Yellow 10

Mordant Yellow U

■xMordant Yellow 16

Mordant Yellow 20

Mordant Yellow 26

Mordant Yellow 29

Mordant Yellow 30

Mordant Yellow 36

^Mordant orange dyes:

ifMordant Orange 1

Mordant Orange A

^Mordant Orange 6

Mordant Orange 8

Mordant Orange 30

XMordant red dyes :

Mordant Red 3

Mordant Red 5

Mordant Red 6

^Mordant Red 7

Mordant Red 9 '■

Manufacturers' identification codes (according to list in table 22)

KON,

TMS.

KON,

NAC, TMS

KON,

NAC.

NAC.

NAC.

NAC.

KON,

NAC.

SNA.

NAC.

KON,

NAC.

KON.

KON,

NAC.

SNA.

KON.

ICI. ICI. ICI. ICI.

ATL, G, PDC, TRC.

ATL, NAC.

NAC, TRC.

DUP, G, NAC, VPC.

DUP.

NAC, TRC.

ACY, DUP, NAC.

NAC.

NAC, VPC.

G.

TRC, VPC.

PDC.

ACY, G, PDC, TRC, VPC.

G, VPC.

ATL, G, TRC.

NAC, TRC.

NAC.

ACY, NAC.

NAC.

G.

ACY, CMG, G, NAC, TRC, VPC.

G, MRX, NAC.

DYES

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported identified by manufacturer, 7964— Continued

109

I3ye

Manufacturers' identification codes (according to list in table 22)

MORDANT DYES— Continued

«}tordant red dyes Continued

Mordant Red 11

Mordant Red 36

Ifordant Red 59

Mordant violet dyes:

Mordant Violet 5

Mordant Violet 11

Mordant Violet 26

^Mordant blue dyes:

«M3rdant Blue 1

Mordant Blue 3

Mordant Blue 7

Mordant Blue 9

Mordant Blue 13

Mordant Blue 19

Mordant green dyes:

Mordant Green 9

Mordant Green 11

Mordant Green 36

MDrdant Green 4-7

*MDrdant brown dyes:

*Mbrdant Broim 1

Mordant Brown 12

Mordant Brown 13

Mordant Brown 15

Mordant Brown 17

Ifordant Brown 18

Mordant Brown 19

Mordant Brown 21

*Mordant Brown 33

■xMordant Brown 4-0

Mordant Brown 43

Mordant Brown 50

Mordant Brown 63

Mordant Brown 70

Mordant Brown 78

^Mordant black dyes:

Mordant Black 1

^ftfordant Black 3

Mordant Black 5

Mordant Black 7

Mordant Black 8

Mordant Black 9

«Mordant Black 11

<<Mordant Black 13

Mordant Black 16

»Mbrdant Black 17

Mordant Black 19

Mordant Black 26

^Mordant Black 38

Other mordant black dyes

OXIDATION BASES

Oxidation Base 8 and SA.

Oxidation Base 21

Oxidation Base 22

Oxidation Base 25

Other oxidation bases

ACY, NAC.

TRC.

TRC.

NAC.

G.

G.

AAP, DUP, G, NAC, TRC.

G, NAC.

TRC.

G, NAC.

HSH, NAC.

CMG.

NAC. ACY. PDC. NAC.

cm, DUP, G, NAC, TRC, YAW.

PDC.

NAC.

DUP, NAC.

G.

G, VPC.

DUP, MAC, TRC.

CMG, DUP, G, NAC, VPC.

G.

TRC.

TRC.

DUP, PDC.

CM}.

G, NAC.

G, NAC, TRC.

NAC, TRC.

G.

VPC.

NAC, VPC.

G, NAC, TRC, VPC.

G, HSH, NAC, TRC.

NAC.

ACY, DUP, G, NAC, TRC.

PDC.

TRC.

CM}, DUP, NAC, TRC, VPC.

VPC.

ACY. PDC. ACY. ACY. ACY.

110

TABLE 8B.-

SYNTHETIC ORGANIC CHEMICALS, 1964

Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 —Continued

Dye

SOLVENT DYES

^Solvent yellow dyes:

Solvent Yellow 1

^Solvent Yellow 2

^Solvent Yellow 3

Solvent Yellow 8

Solvent Yellow 13

♦Solvent Yellow 14-

Solvent Yellow 16

Solvent Yellow 19

Solvent Yellow 29

Solvent Yellow 33

Solvent Yellow 34

Solvent Yellow 40

Solvent Yellow 4-2

Solvent Yellow 43

Solvent Yellow 4^

Solvent Yellow 45

♦Solvent Yellow 47

Solvent Yellow 53

Solvent Yellow 56

Solvent Yellow 66

Solvent Yellow 71

Solvent Yellow 72

Other solvent yellow dyes- ♦Solvent orange dyes:

Solvent Orange 2

♦Solvent Orange 3

Solvent Orange 5

♦Solvent Orange 7

Solvent Orange 20

Solvent Orange 23

Solvent Orange 24

Solvent Orange 25

Solvent Orange 31

Solvent Orange 47

Solvent Orange 48

Solvent Orange 51

Other solvent orange dyes- ♦Solvent red dyes:

Solvent Red 8

Solvent Red 22

♦Solvent Red 24

♦Solvent Red 26

Solvent Red 27

Solvent Red 33

Solvent Red 34

Solvent Red 35

Solvent Red 40

Solvent Red 41

♦Solvent Red 49

Solvent Red 52

Solvent Red 63

Solvent Red 65

Solvent Red 68

Solvent Red 69

Solvent Red 74

Solvent Red 76

Solvent Red 80

Solvent Red 105

Solvent Red 108

Solvent Red 111

Solvent Red 115

Other solvent red dyes

Manufacturers' identification codes (according to list in table 22)

ACY.

AAP, AIL, DUP, FH, G.

AAP, DUP, FH, a, NAC, SDH.

PAT.

ACY, G, TRG.

AAP, ACY, ATL, DUP, FH, G, NAC, PAT, SDH.

PAT.

G.

G, NAC.

ACY, NAC.

DUP.

NAC.

NAC.

G.

G, NAC.

DUP, NAC.

ACY, DUP, G, NAC.

NAC.

ACY, FH.

NAC.

ACY.

ACY.

ACY, DSC.

AAP.

ACY, DSC, G, NAC.

G, TRC.

ACY, ATL, FH, G, NAC.

ACY, G, NAC, TRC.

NAC.

DUP.

ACY, DUP.

NAC.

FH.

ACY.

ACY.

DSC, DUP, PAT.

G.

G.

ACY, DUP, G, NAC, PAT, SDH.

AAP, ACY, FH, NAC.

NAC.

DUP.

DUP.

G.

G.

DSC.

ACY, DUP, G.

G, ICI.

NAC.

NAC.

NAC.

DUP.

NAC.

NAC.

ACY, NAC.

ACY.

ACY.

ACY.

ACY.

ACY, DSC, DUP, ICI, PAT.

DYES

TABLE 8B. —Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Pye

SOLVENT DYES— Continued

*Solvent violet dyes :

Solvent Violet 7

^Solvent Violet 8 .

Solvent Violet 9

Solvent Violet 13

Solvent Violet U

Solvent Violet 17

Other solvent violet dyes

Solvent blue dyes :

Solvent Blue 3

Solvent Blue A

Solvent Blue 5

Solvent Blue 6

Solvent Blue 7

Solvent Blue 9

Solvent Blue 11

Solvent Blue 12

Solvent Blue 16

Solvent Blue 30

Solvent Blue 31

Solvent Blue 32

Solvent Blue 33

Solvent Blue 36

Solvent Blue 37

Solvent Blue 38

Solvent Blue 39

Solvent Blue .43

Solvent Blue 58

Solvent Blue 59

Solvent Blue 60

Other solvent blue dyes

»Solvent green dyes:

Solvent Green 1

Solvent Green 2

*Solvent Green 3

Solvent Green 10

Solvent Green 11

Other solvent green dyes

»Solvent brown dyes:

Solvent Brown 11

Solvent Brown 12

Solvent Brown 17

Solvent Brown 19

Solvent Brown 20

Solvent Brown 21

Solvent Brown 38

Other solvent brown dyes

Solvent black dyes :

Solvent Black 3-

Solvent Black 5

Solvent Black 7

Solvent Black 12

Solvent Black 13

Solvent Black 17

Solvent Black 19

Solvent Black 20

Solvent Black 26

Other solvent black dyes

Manufacturers ' identification codes (according to list in table 22)

ACT,

DSC

NAC.

DSC.

AAP,

HSH,

ICI.

ICI.

NAC.

DSC,

PAT.

SW.

DSC,

DUP,

SDH.

DSC.

DSC.

ACY,

NAC.

G.

G, ICI.

DUP,

NAC.

NAC.

NAC.

NAC.

AAP.

G.

DUP,

NAC.

DUP.

ACY,

CMl,

DUP, NAC.

NAC.

NAC.

ACY.

ACY.

ACY.

AAP,

DSC,

G, ICI, PAT, SDH

ACY,

DSC,

SDH.

AAP, ACY, AIL, CIG, G, HSH, ICI, NAC.

DUP.

DUP.

DSC, NAC.

G.

ACY, G. DUP. DUP.

ACY, DUP. NAC. ACY. ACY, DSC.

NAC.

ACY, NAC.

ACY, FH, NAC.

NAC.

NAC.

DUP.

G.

NAC.

ACY.

DSC, DUP.

TABLE 8B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

SULFUR DYES

Sulfur yellow dyes:

Sulfur Yellow 2

Leuoo Sulfur Yellow 2

Sulfur Yellow 4

Leuco Sulfur Yellow 4

Leuoo Sulfur Yellow 15

Other sulfur yellow dyes

Sulfur red dyes:

Sulfur Red 1

Leuco Sulfur Red 1

Sulfur Red 6

Sulfur Red 8

Sulfur blue dyes:

»Sulfur Blue 7

*Leuco Sulfur Blue 7

Leuoo Sulfur Blue 8

Sulfur Blue 9

Leuoo Sulfur Blue 9

»Sulfur Blue 11

Sulfur Blue 13

Leuoo Sulfur Blue 13

Sulfur Blue 15

Sulfur Blue 16

Other sulfur blue dyes

Sulfur green dyes:

Sulfur Green 1

Sulfur Green 2

Leuoo Sulfur Green 2

Solubilized Sulfur Green 2

Sulfur Green 3

Leuoo Sulfur Green 3

Sulfur Green 8

Sulfur Green 11

Sulfiir Green 14

Leuoo Sulfur Green 16

Other sulfur green dyes

Sulfur brown dyes:

Sulfur Brown 3

Leuoo Sulfur Brown 3

Solubilized Sulfur Brown 3

»Sulfur Brown 10

Leuoo Sulfur Brown 10

Solubilized Sulfur Brown 10

Sulfur Brown 14

Leuoo Sulfur Brown 14

Sulfur Brown 20

Sulfur Brown 30

Sulfur Brown 33

Leuoo Sulfur Brown 37

Sulfur Brown 39

Sulfur Brown 40

Sulfur Brown 43

Sulfur Brown 44

Leuoo Sulfur Brown 44

Sulfur Brown 45

Sulfur Brown 50

Sulfur Brown 76

Other sulfur brown dyes

Manuf aoturers ' identification codes (according to list in table 22)

NAC.

ACY, NAC.

AUG, DUP,

SDC.

SDG.

ACY.

ACY, SDC

DUP, NAC.

NAC.

ACY, DUP,

NAC.

DUP.

ACY, DUP,

NAC, SDC

ACY, NAC,

SDC.

SDC.

ACY, NAC.

SDC.

DUP, NAC,

SDC.

ACY, NAC.

ACY.

ACY, DUP,

NAC.

ACY, NAC.

ACY, SDC.

NAC.

DUP, NAC,

SDC.

SDC.

SDH.

NAC, SDC.

SDC.

AUG.

DUP.

DUP.

SDC.

SDC.

SDC.

SDC.

AUG.

DUP, NAC

SDC.

NAC, SDC

AUG.

ACY, AUG

ACY.

DUP.

ACY.

ACY.

SDC.

DUP, SDC

DUP.

NAC.

NAC.

NAC.

NAC.

NAC.

ACY.

ACY, NAC

, SDC.

DYES

113

TABLE 8B.-

-Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

I^e

SULFUR DYES— Continued

Sulfur black dyes:

»Sulfur Black 1

Leuco Sulfur Black 1

Sulfur Black 2

»Leuco Sulfur Black 2

Sulfur Black 6

Leuco Sulfur Black 6

Sulfur Black 10

Leuco Sulfur Black 10

Sulfur Black 11

Leuco Sulfur Black 11

Other sulfur black dyes

VAT DYES

*Vat yellow dyes:

Vat Yellow 1, 12-1/2?J

»Vat Yellow 2, 8-1/2^^

Solubllized Vat Yellow 2, 2ii

Vat Yellow 3, 12-1/2^6

»Vat Yellow 4, 12-l/25t

Solubllized Vat Yellow 4-, 37-1/25^

Vat Yellow 10, lO^fr-

Vat Yellow 13, t-l/Z'i,

Vat Yellow U, 12-'L/2i

Vat Yellow 15, 11-1/2^^

Vat Yellow 16, 16-2/35^

Vat Yellow 20

Vat Yellow 21, 9-1/2$

Vat Yellow 22, 1.0$

Vat Yellow 27

Vat Yellow 28, 10$

Vat Yellow 33

Vat Yellow 34, 8-1/25^

Vat Yellow 41, 9$

Other vat yellow dyes

*Vat orange dyes:

»Vat Orange 1, 205t

»Solubilized Vat Orange 1, 26$

»Vat Orange 2, 125^

Vat Orange 3, 13-1/2$

»Vat Orange 4, 6$

*Vat Orange 5, lOjt

»Solubilized Vat Orange 5, 305^

»Vat Orange 7, lli^

»Vat Orange 9, 12?^

Vat Orange 11, 6$

»Vat Orange 15, IO56

Vat Orange 23, 17-l/25(

Vat Orange 24

Other vat orange dyes

*Vat red dyes:

»Vat Red 1, 13$

»Solubilized Vat Red 1, 375S

Vat Red 10, I856

Solubllized Vat Red 10, 315t

Vat Red 12, 8-l/25t

»Vat Red 13, lljt

Manufacturers' identification codes (according to list in table 22)

DUP,

NAC,

SDC

ACY,

NAC,

SDC

ACY,

DUP,

NAC

ACY,

NAC,

SDC

G.

NAC.

ACY,

DUP.

ACY,

NAC.

a, SDC.

SDC.

SDC.

NAC.

AAP, ATL, DUP, G, ICI, NAC, TRC, VPC.

G, ICI.

DUP.

AAP, ACY, AIL, CMG, G, HST, ICI, TRC, VPC.

G, HST, ICI.

G.

ICI.

TRC.

ACY.

DUP.

G.

ATL, DUP.

DUP, G.

VPC.

NAC.

ICI, TRC.

DUP.

ACY.

MAY, NAC, VPC.

CMG, G, HST, ICI, NAC, TRC, VPC.

G, HST, ICI.

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC.

CMG, DUP, G.

ACY, CMG, DUP, NAC.

AAP, ACY, DUP, HST.

G, HST, ICI.

G, HST, TRC.

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC.

DUP, NAC.

AAP, ACY, G, ICI, NAC, TRC, VPC.

ACY, DUP.

DUP.

G, SDC.

AAP, ACY, DUP, HST.

G, HST, ICI.

G, NAC, TRC.

G.

DUP.

DUP, G, NAC, TRC.

114 SYNTHETIC ORGANIC CHEMICALS. 1964

TABLE 8B. -Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

VAT DYES Continued

2656—

*Vat red dyes Continued

"Vat Red U, 105t

*Vat Red 15, lO^i

Vat Red 16, 115^

Vat Red 17, 105^

Vat Red 23

Vat Red 29, I856

»Vat Red 32, 20^

Vat Red 35, I2-I/25S

Vat Red 44, 175t

Vat Red 52, IO56

Vat Red 53, 12^

Vat Red 56

Vat Red 62

Other vat red dyes

*Vat violet dyes:

»Vat Violet 1, 115^-

Solubilized Vat Violet

*Vat Violet 2, 20^

Vat Violet 3, XSfl,

Solubilized Vat Violet 3, 43^

*Vat Violet 9, 12^—

Vat Violet 12, IO5S

*Vat Violet 13, 6-1/4^6

Vat Violet 14, 12-1/2^6

Vat Violet 17, I2-I/256

Other vat violet dyes

Wat "blue dyes:

Vat Blue 1, 20?^

Solubilized Vat Blue 1, 25?^

Vat Blue 3, I656

*Vat Blue 4, lOjt

Vat Blue 5, 16i

Solubilized Vat Blue 5, 3856

Wat Blue 6, 8-1/35^

*Solubilized Vat Blue 6, 17-1/2^

Vat Blue 7, 12-l/2^i

Solubilized Vat Blue 9, 35^

Vat Blue 12, 6-I/256

Vat Blue 14, 8-1/35^ -

Vat Blue 16, 16^^

*Vat Blue 18, 135^

*Vat Blue 20, 14^6

Vat Blue 29 -

Vat Blue 39, 12^6

Vat Blue 43

Vat Blue 53

Vat Blue 60

Vat Blue 61, I656

Other vat blue dyes

Wat green dyes:

Wat Green 1, 65S

Solubilized Vat Green 1, 12-1/2^-

Wat Green 3, lOjt

»Solubilized Vat Green 3, 2656

Wat Green 8, 8-l/2';t

Wat Green 9, I2-I/256

Vat Green 15, 175^—

Manufacturers' identification codes (according to list in table 22)

G, HST.

G, HST, TRC.

DUP.

G.

DUP.

G, NAG.

DUP, G, MAC.

NAC, TRC.

TRC.

DUP.

DUP.

ACY.

DUP.

DUP, G, TRC, VPC.

ACY, DUP, G, ICI, MAY, NAC, TRC.

G, ICI.

ACY, G, HST, NAC.

G, HST, NAC.

G.

DUP, G, ICI, MAY, NAC.

DUP.

CMG, DUP, G, ICI, NAC, TRC.

DUP, NAC.

DUP, G, NAC.

NAC.

DUP, NAC.

G.

HST.

ACY, DUP, G.

ATL, DUP, HST, NAC, VPC.

G, HST.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC.

G, HST, ICI.

NAC.

G.

DUP.

DUP, G, NAC, TRC.

ACY, DUP, NAC.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

AAP, ACY, AIL, DUP, G, ICI, MAY, NAC, TRC.

G.

G.

SDC.

G.

DUP.

DUP.

G, SDC, X.

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC.

G, HST, ICI.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

G, HST, ICI.

DUP, G, ICI, NAC.

ACY, ATL, DUP, G, MAY, NAC, SDC, TRC.

NAC.

DYES

115

TABLE 8B. Bemenoid dyes for which U.S. production or sales were reported, identified by manufacturer, i564— Continued

Dye

VAT DYES—Continued

*Vat green dyes Continued

Vat Green 18, B$

Vat Green 20, e^

Other vat green dyes

*Vat bromn dyes;

*Vat Brown 1, 11$

Solubllized Vat Brown 1, 17i6

»Vat Brown 3, 115t

«Vat Brown 5, 13^6

Vat Brown 6, 17-l/25t

Vat Brown 11, 12ifr

Vat Brown 12, 12-l/2?6

Vat Brown 13, 1756

Vat Brown 14, 125^

Vat Brown 20, IO-I/256

Vat Brown 25, II-I/256

Vat Brown 29, 13;^-

Vat Brown 31, 28$

Vat Brown 38, 20i6-

Vat Brown 40, I456

Vat Brown 57

Other vat brown dyes

Wat black dyes:

Solubllized Vat Black 1, 27-1/2!^

*Vat Black 9, I656

Vat Black 11, 17-l/25t

Vat Black 13, XU$

Vat Black' 14, ll-l/2i6

Vat Black 15

Vat Black 18, 15-l/2;6-

Vat Black 21, 18-l/25t

Vat Black 22, 195t

*Vat Black 25, 12-1/25^

Wat Black 27, 12-1/2;^-

Vat Black 34, 16$

Vat Black 36-

Vat Black 38

Vat Black 52

Other vat black dyes

All other dyes

Manufacturers' identification codes (according to list in table 22)

DUP. DUP. SDC.

ACY, DUP, G, ICI, MAY, NAC, TRC.

G, ICI.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC.

AAP, ACY, G, HST, NAC, VPC.

TRC.

MAY, TRC.

DUP, NAC.

MAY.

HST.

DUP, G, NAC.

G.

ACY.

AAP.

ICI.

DUP.

TRC.

DUP, G, NAC, SDC, VPC.

G, HST, ICI.

G, NAC, TRC.

ACY.

DUP, NAC.

DUP.

AAP.

G, NAC.

ACY.

ACY, TRC.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

AAP, ACY, CMG, DUP, G, ICI, MAY, NAC, TRC.

ICI.

DUP.

G.

ACY.

DUP, G, NAC, SDC, TRC.

ACY, FH, PAT, VPC.

1)6

SYNTHETIC ORGANIC CHEMICALS, 1964

Pigments

TABLE IIB. Benzenoid pigments for which U.S. production or sales were reported, identified

by manufacturer, 1964

[Benzenoid pigments for which separate statistics are given in table llA are marked below with an asterisk (»); products not so marked do not appear in table llA because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Pigment

Manufacturers ' identification codes (according to list in table 22)

TONERS

*Yellow toners: »Hansa yellows:

♦Pigment Yellow 1, C.I. 11 680

»Pigment Yellow 3, C.I. 11 710

Pigment Yellow 4, C.I. 11 665

Pigment Yellow 5, C.I. 11 660

Pigment Yellow 6, C.I. 11 670

Pigment Yellow 9, C.I. 11 720

Pigment Yellow 49, C.I. 11 765

Pigment Yellow 60

Pigment Yellow 73

Pigment Yellow 74

All other Hansa yellows

♦Benzidine yellows:

♦Pigment Yellow 12, C.I. 21 090

♦Pigment Yellow 13, C.I. 21 100

♦Pigment Yellow 14, C.I. 21 095

♦Pigment Yellow 17, C.I. 21 105

Pigment Yellow 65, C.I. 11 740

Pigment Yellow 83

All other benzidine yellows

Pigment Yellow 18, C.I. 49 005

(Basic Yellow 2), C.I. 41 000, fugitive

(Vat Yellow 1), C.I. 70 600

(Vat Yellow 20), C.I. 68 420

All other

♦Orange toners:

Pigment Orange 1, C.I. 11 725

♦Pigment Orange 2, C.I. 12 060

♦Pigment Orange 5, C.I. 12 075

Pigment Orange 9

♦Pigment Orange 13, C.I. 21 110

Pigment Orange 15, C.I. 21 130

♦Pigment Orange 16, C.I. 21 160

Pigment Orange 30

(Vat Orange 3), C.I. 59 300 --

(Vat Orange 4), C.I. 59 710

(Vat Orange 7), C.I. 71 105

(Vat Orange 15), C.I. 69 025—- -

All other

♦Red toners: ♦Naphthol reds:

♦Pigment Red 2, C.I. 12 310

♦Pigment Red 5, C.I. 12 490

Pigment Red 7, C.I. 12 420

Pigment Red 9, C.I. 12 460

Pigment Red 10, C.I. 12 440

♦Pigment Red 13, C.I. 12 395

ACY, AMS, CIK, DUP, FCL, G, HAR, HSC, HSH, ICI, IMP,

KON, PPG, S, SDH, SNA, SW, WDC. HAR, HSC, HSH, HST, IMP, KCW, KON, S, SW, WDC. HAR, HSH, SNA. HSH, IMP. CIK, IMP. SNA. ICI. SW.

HAR, SW. DUP, SW. DUP, HSC, IMP, KCW, SDH, SNA, WDC.

ACY, AMS, DUP, FCL, G, HAR, HSC, HSH, HST, ICC, IMP,

KON, LVY, MRX, S, SDH, SNA, SW, WDC. FCL, G, HAR, HST, ICC, IMP, ROM, SNA, SW. ACY, AMS, BUC, CPC, DUP, FCL, G, HAR, HSC, HSH, HST,

ICC, IMP, KON, MRX, ROM, S, SDH, SNA, SW, x. ACY, AMS, DUP, HST, ICC, IMP, SDH, SNA, SW. SW. HAR.

HSH, HST, ICC, IMP, ROM, S, SW. IMP. MRX, S. HAR, TRC. HAR. ACY, HSH, ICC, S, SW.

HAR, KCW, SNA.

FCL, HSC, IMP, SDH, SW.

ACY, HSC, IMP, SNA, SW.

DUP.

ACY, AMS, BUC, G, HAR, ICC, ICI, IMP, KON, S, SNA, SW.

G, HAR.

BUC, DUP, FCL, G, HAR, HST, ICC, IMP, ROM, SDH, SNA,

SW. SW.

HAR, TRC. HAR. G, HAR. HAR. ICC, KON, ROM, SDH, SNA, SW.

EAK, G, HAR, HSC, IMP, KCW, KON, MRX, SDH, SW.

DUP, G, HAR, HST, ICC, ICI, IMP, ROM, S, SDH, SNA, SW.

ICI, S,

IMP.

KCW.

HAR, IMP, KCW.

See note at end of table for definition of abbreviations.

PIGMENTS

117

TABLE IIB. —Bemenoid pigments for which U.S. production or sales were reported, identified by manufacturer, iS64- -Continued

Pigment

TONERS— Continued

»Red toners Continued »Naphthol reds Continued

Pigment Red li, C.I. 12 380

Pigment Red 15, C.I. 12 ^65

»Pigment Red 17, C.I. 12 390

^Pigment Red 18, C.I. 12 350

Pigment Red 19, C.I. 12 400

»Pigment Red 22, C.I. 12 315

^Pigment Red 23, C.I. 12 355

Pigment Red 31, C.I. 12 360

All other naphthol reds

*Pigment Red 1, C.I. 12 070, dark

^Pigment Red 1, C.I. 12 070, light

^Pigment Red 3, C.I. 12 120

^Pigment Red 4, C.I. 12 085

Pigment Red 5

Pigment Red 6, C.I. 12 090

»Pigment Red 38, C.I. 21 120

Pigment Red 41, C.I. 21 200

*Pigment Red 48, C.I. 15 865

Pigment Red 49, C.I. 15 630: *Barium toner

*Caloium toner

*Sodium toner

♦Pigment Red 52, C.I. 15 860

♦Pigment Red 53, C.I. 15 585, barium toner- Pigment Red 54, C.I. 14 830, calcixun toner- Pigment Red 55, C.I. 15 820

♦Pigment Red 57, C.I. 15 850, calcium toner- Pigment Red 58, C.I. 15 825

♦Pigment Red 63, C.I. 15 880

Pigment Red 64, C.I. 15 800

Pigment Red 77, C.I. 15 826

Pigment Red 78

Pigment Red 81, C.I. 45 160, fugitive

♦Pigment Red 81, C.I. 45 160, PMA.

♦Pigment Red 81, C.I. 45 160, PTA

Pigment Red 87, C.I. 73 310

Pigment Red 88

♦Pigment Red 90, C.I. 45 380

Pigment Red 117, C.I. 15 603

Pigment Red 122

Manufacturers' identification codes (according to list in table 22)

DUP.

DUP.

ACY, BLN, FCL, ICC, IMP, S, SNA, SW.

HAR, HSH, IMP, SW.

HAR.

ACY, DUP, FCL, HAR, IMP, MRX, SNA, SW.

ACY, BUG, DUP, FCL, HAR, HSC, ICC, IMP, S, SDH, SNA,

SW. SNA, SW.

BUC, ICC, IMP, KCW, ROM, S, SDH, SW. ACY, AMS, APC, FCL, HAR, HSC, HSH, IMP, KON, LVY,

PPG, SNA, SW, WDC. ACY, APC, CIK, EAK, FCL, HSC, HSH, IMP, KON, PPG, SDH,

SW. ACY, APC, BLN, CIK, DUP, EAK, FCL, HAR, HSC, HSH,

IMP, KCW, KON, PPG, SDH, SNA, SW, UHL, WDC. ACY, AMS, FCL, G, HSC, IMP, KON, MRX, SDH, SNA, SW,

WDC. IMP.

DUP, HSC, SW.

DUP, G, HAR, ICC, SNA, SW. G, HAR. ACY, AMS, BLN, DUP, FCL, G, HAR, HSC, HSH, IMP, KON,

LVY, MRX, S, SNA, SW, WDC.

ACY, AMS, CIK, FCL, HSC, IMP, LVY, SDH, SNA, SW, UHL,

WDC. ACY, AMS, EAK, FCL, HSC, IMP, LVY, PPG, SDH, SNA, SW. ACY, AMS, CIK, FCL, HSC, SDH, SW. AMS, FCL, HSC, HSH, IMP, SNA, SW. ACY, ADC, AMS, CIK, FCL, HSC, IMP, KON, LVY, MRX,

SDH, SNA, SW, WDC. IMP, MRX, SDH. DUP, HAR. ADC, AMS, BLN, CIK, DUP, FCL, HAR, HSC, HSH, IMP,

KON, LVY, SDH, SNA, SW, WDC. DUP, G, IMP.

FCL, HAR, HSH, IMP, SNA, SW. HAH. SW. DUP.

BLN, KCW, SNA. BLN, CPC, DUP, FCL, G, IMP, KON, LVR, LVY, MGR, MRX,

NYC, SNA. ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KCW, KON, MGR,

MRX, S, SDH, SNA. HAR. HAR. ACY, AlB, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA,

WDC. SW. HAR.

See note at end of table for definition of abbreviations.

118

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE IIB.—Benzenoid pigments for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Pigment

TONERS— Continued

»Red toners Continued

Pigment Red 123

(Vat Red 10), C.I. 67 000

(Vat Red 23)

(Vat Red 29), C.I. 71 140

All other

*Violet toners:

Pigment Violet 1, C.I. 45 170, fugitive

*Pigment Violet 1, C.I. 45 170, PMA.

«Pigment Violet 1, C.I. 45 170, PTA

^Pigment Violet 3, C.I. 42 535, fugitive

^Pigment Violet 3, C.I. 42 535, PMA

^Pigment Violet 3, C.I. 42 535, PTA

Pigment Violet 19

Pigment Violet 23

(Vat Violet 1), C.I. 60 010

(Vat Violet 2), C.I. 73 385-

(Vat Violet 3), C.I. 73 395

(Vat Violet 23)

All other

*Blue toners:

♦Pigment Blue 1, C.I. 42 595, PMA

♦Pigment Blue 1, C.I. 42 595, PTA

Pigment Blue 2, C.I. 44 045, fugitive

Pigment Blue 2, C.I. 44 045, PMA

Pigment Blue 2, C.I. 44 045, PTA

Pigment Blue 3, C.I. 42 140, PMA

Pigment Blue 3, C.I. 42 140, PTA

Pigment Blue 5, C.I. 42 600

♦Pigment Blue 9, C.I. 42 025, PMA

♦Pigment Blue 9, C.I. 42 025, PTA

Pigment Blue 10, C.I. 44 040, PMA

Pigment Blue 10, C.I. 44 040, PTA—

♦Pigment Blue 14, C.I. 42 600, PMA

Pigment Blue U, C.I. 42 600, PTA

♦Pigment Blue 15, C.I. 74 160, alpha form

♦Pigment Blue 15, C.I. 74 160, beta form

♦Pigment Blue 19, C.I. 42 750A

Pigment Blue 22, C.I. 69 810

♦Pigment Blue 25, C.I. 21 180 -

(Basic Blue 7), C.I. 42 595, PTA

(Vat Blue 4), C.I. 69 800

(Vat Blue 6), C.I. 69 825

(Vat Blue 14), C.I. 69 810

All other

♦Green toners:

♦Pigment Green 1, C.I. 42 040, PMA

♦Pigment Green 1, C.I. 42 040, PTA

♦Pigment Green 2, C.I. 42 040 and 49 005, PMA- ♦Pigment Green 2, C.I. 42 040 and 49 005, PTA-

Pigment Green 4, C.I. 42 000, fugitive

Pigment Green 4, C.I. 42 000, PMA

♦Pigment Green 4, C.I. 42 000, PTA

♦Pigment Green 7, C.I. 74 260

Manufacturers ' identification codes (according to list in table 22)

HAR. HAR. HAR. HAR. DUP, G, HAM, HSC, SW, TRC, x.

BLN, UHL.

BLN, G, IMP, LVR, MRX.

ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KON, MRX, S,

SNA. ACY, ADC, AMS, BLN, HSC, IMP, LVY, MGR, SDH, UHL. ADC, AMS, BLN, CIK, DUP, EAK, G, HSC, IMP, KON, LVE,

LVY, MGR, MRX, NYC, PPG, SDH, SNA, SW, UHL. ACY, AMS, G, IMP, KON, MRX, SNA, SW. HAR. G.

DUP. HAR. HAR. TRC. ACY, HST, ICC, ROM.

ADC, BLN, DUP, EAK, FCL, G, HSC, IMP, KON, LVR, LVY,

MGR, MRX, NYC, SDH, SNA, SW, UHL. AMS, G, HAM, HAR, IMP, MGR, SNA, SW, UHL. BLN.

CIK, G, LVR. G, HAM, WS.. MGR. MGR. G.

LVR, MRX, NYC, UHL. BLN, G, IMP, M3R, MRX, SDH. IMP, SDH. IMP.

DUP, G, IMP, NYC. DUP, G, NYC. ACY, DUP, G, HAR, HSC, ICC, ICI, IMP, SNA, SW, TMS,

TRC. ACY, DUP, FCL, HSC, IMP, KON, LVY, SNA, SUC, SW, TMS,

TRC. ACY, AMS, HSC, NYC, SW. DUP, IMP. DUP, G, HAR, ICC. DUP. G.

ICI, TRC. HAR, TRC. ICC, IMP, M5R, S, SDH.

BLN, G, IMP, MGR, MRX, SNA, UHL.

BLN, IMP, MIR, S, SDH.

ADC, G, IMP, LVY, MiR, MRX, S, SDH, UHL.

ACY, AJ/B, BLN, DUP, IMP, KON, LVY, MjR, MRX, S, SDH,

UHL. BLN, G. ADC, BLN.

ACY, AMS, HAM, MGR. ACY, DUP, FCL, G, HAR, HSC, IMP, SNA, SW, TMS, TRC.

See note at end of table for definition of abbreviations.

PIGMENTS

119

TABLE IIB.

-Benzenotd pigments for which U.S. production or sales were reported, identified by manufacturer, i 564- -Continued

Pigment

TONERS— Continued

«<}reen toners Continued

♦Pigment Green 8, C.I. 10 006

Pigment Green 10, C.I. 12 775

Pigment Green 36

Pigment Green 38

All other

*Brown toners:

Pigment Brown 1, C.I. 12 4-80

Pigment Brown 2, C.I. 12 071

Pigment Brown 3, C.I. 21 010, PMA.

♦Pigment Brown 5, C.I. 15 800

(Vat Brown 3), C.I. 69 015

All other

*Blaok toners:

Pigment Black 1

All other

Manufacturers' identification codes (according to list in table 22)

Yellow lakes:

(Acid Yellow 1), C.I. 10 316

(Acid Yellow 3), C.I. 4-7 005

(Acid Yellow 23), C.I. 19 14-0

All other

Orange lakes:

Pigment Orange 17, C.I. 15 510

All other

♦Red lakes:

♦Pigment Red 60, C.I. 16 105

♦Pigment Red 83, C.I. 58 000

(Acid Red 17), C.I. 16 180

(Acid Red 25), C.I. 16 050

♦(Acid Red 26), C.I. 16 150

(Acid Red 27}

(Natural Red 4), C.I. 75 470

(Natural Red 24), C.I. 75 280

All other

♦Violet lakes:

♦Pigment Violet 5, C.I. 58 055

Pigment Violet 20, C.I. 58 225

(Acid Violet 17), C.I. 42 650

All other

♦Blue lakes:

Pigment Blue 17, C.I. 74 180

♦Pigment Blue 24, C.I. 42 090

(Acid Blue 93), C.I. 42 780

(Acid Blue 104), C.I. 42 735

Green lakes: (Acid Green 3), C.I. 42 085-

Brown lakes -r

Black lakes:

♦(Natural Black 3), C.I, 75 291

All other

DUP, G, HSH, KCW, LVY, SW.

DUP.

G.

HAR.

ACY.

ICI.

SDH.

BLN, KCW.

BUC, HAR, ROM, SNA.

G, HAR.

ICC, SDH, SW.

SNA.

BLN, DUP, G, MGR, SNA, SW, UHL.

IMP. IMP. KON, IMP.

CIK,

HAM.

BLN, IMP, IMP, KON. CPC, KON. KON. IMP. APC,

BLN, SW. BLN. HAM,

BLN, ADC, LVR. CPC, BLN, HAM,

CPC, HAM.

Mffi, MRX.

CPC, IMP, KCW, MGR.

DUP, HSH, KON, MRX, SNA, SW. KON, MRX, SW, UHL. KCW, WDC.

EAK, HAM, IMP, KCW, UHL.

G, HAM, IMP. DUP, HAR, IMP.

CPC.

AMS, BLN, CIK, ICC, KON, LVY, MGR, SDH.

KCW. CPC. KON.

KON, NYC.

of^the'co'w Ind« ^^'°"'" ^""^"^ numbers shown in this report are the identifying codes given in the second edition

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the pigment can be made and that no name for the pigment Itself is given in the Colour Index

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic)

120

SYNTHETIC ORGANIC CHEMICALS, 1964

Medicinal Chemicals

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964

[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk (*); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- fidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product ]

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHIMICALS, ANTIBIOTICS

^Antibiotics for human or veterinary use :

Amphotericin B

■^Bacitracin

Cephalothin, sodium

Chloramphenicol

Chlortetracycline

Cycloserine

Dactinomycin

Demethylchlortetracycline

^Dihydrostreptomycin

Erythromycin

Fumagillin

Gentamicin

Gramicidin

Kanamycin

Lincoraycin

*Neomycin

Novobiocin

Nystatin

Oleandomycin

Oxytetracycline

Paromomycin

■^Penicillins :

Ampicillin

Cloxacillin, sodium

Methioillin, sodium

Nafcillin, sodium

Oxacillin, sodium

♦Penicillin G, potassium

♦Penicillin G, procaine

♦Penicillin G, other:

Penicillin G, benzathine

Penicillin G, sodium

Penicillin 0, chloroprocaine

Penicillin 0, sodium

Penicillin V

Penicillin V, benzathine

Penicillin V, hydrabamine

Penicillin V, potassium

♦Phenethicillin and potassium salt:

Phenethicillin

Phenethicillin, potassium

Polymyicin B

Ristocetin

Streptomycin

♦Tetracycline

Thiostrepton

Triacetyloleandomycin

Tyrothricin

Vancomycin

Viomycin

♦Antibiotics for animal feed supplements, food preserva- tion, and crop spraying;

♦Bacitracin

Chlortetracycline

ffygromycin B

Oxytetracycline

♦Penicillin G, procaine

Streptomycin

I^losin

PFZ, MP, X.

CMS, PFZ. LIL.

CMS, PEN, PFZ, UPJ. UPJ.

CMS.

CCM,

LIL.

PD.

ACY.

CCM.

MRK.

ACY.

MRK,

ABB,

ABB.

SCH.

BAX,

BRS.

X.

ACY, MRK, QMS. PFZ. PFZ. MRK.

BRS.

BRS.

BRS.

WYT.

BRS.

LIL, MRK, CMS, PFZ, WYT.

ABB, LIL, MRK, CMS, PFZ, WYT.

PFZ, WYT.

MRK, OMS, PFZ.

UPJ.

UPJ.

LIL.

WYT.

ABB.

ABB, LIL.

CMS, PFZ.

BRS, WYT.

PFZ.

ABB.

LIL, MRK, CMS, PFZ.

ACY, BRS, PFZ, RLS.

CMS.

PFZ.

BAX, PEN.

LIL.

PFZ.

COM, DLI, GPR, PMP, x.

ACY.

LIL.

PFZ.

LIL, MRK, am, PFZ, WYT.

MRK, PFZ.

LIL.

MEDICINAL CHEMICALS

121

TABLE 13B.

Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, i 964 --Continued

MEDICINAL CHEMICALS, BENZENOID

^Alkaloids, except those affecting the autonomic or central nervous system: Berberine hydrochloride

Ergonovine maleate

Hydrastine

Ifydrastine hydrochloride

Lobeline sulfate

Papaverine hydrochloride, synthetic

Quinidine gluconate

Qainidine sulfate

Eauwolfia serpentina fraction (Alseroxylon)

Resoinnamine

Reserpine

Theobromine sodium salicylate

Vinblastine sulfate

^Antihistamines : *Antinauseants :

N-Benzhydryl-N-'--methylpiperazine (Cyclizine) base and hydrochloride.

2-(Benzhydryloxy)-N, N-dimethylethylamine 8-chloro- theophyllinate (Dlmenhydrinate).

l-(p-Chlorobenzhydryl)-<i-(3-methylbenzyl)piperazine (Meclizine) dihydrochloride .

4-(2-Dimethylamlnoethoxy)-N-(3,4,5-trimethoxybenzoyl)- benzylamine (Trimethobenzamide) hydrochloride. 2-(Benzhydryloxy)-N, N-dimethylethylamine (Diphenhydra- mine) hydrochloride. 2 -[ Benzyl ( 2-dimethylaminoettiyl ) amino] pyridine ( Tri -

pelenamine ) . 2-[Benzyl(2-dimethylaminoethyl)amino]pyridine (Tri-

pelenamine) citrate. 2-[ Benzyl( 2-dimethylaminoethyl )amino]pyridine ( Tri-

pelenamine) hydrochloride. 2-[ p-Bromo-a- ( 2-dimethylaminoethyl )benzyl] pyridine

(Brompheniramine) maleate. d-2-[ p-Bromo-a-(2-dimethylaminoethyl )benzyl] pyridine

( Dexbrompheniramine ) maleate .

Bromodiphenhydramine hydrochloride

l-(4-Chlorobenzhydryl)^-methylpiperazine ( Chlor-

cyclizine ) hydrochloride . 2-[p-Chloro-a-(2-dimethylaminoethoxy)benzyl] pyridine

( Carbinoxamine ) . l-2-[p -Chloro-a - ( 2 -dimethylaminoethoxy )benzyl] pyridine

(Rotoxamine). *2-[p-Chloro-a-(2-dlmethylaminoethyl)benzyl] pyridine

( Chlorpheniramine ) maleate . d-2-[p-Chloro-a-( 2-dimethylaminoethyl )benzyl] pyridine

( Dexchlorpheniramine ) maleate . l-(p-Chlorophenyl)-2-phenyl-4-pyrrolidyl-l-butene

( lyrrobutamine ) diphosphate and hydrochloride. 4-(5H-Dibenzo [a,d]eyclohepten-5-ylidene)-l-methyl-

piperidine ( Cyproheptadine } . 2-[a -(2-Dimethylaminoethoxy)-a-methylbenzyl] pyridine

(Doxylamine) succinate.

Manufacturers' identification codes (according to list in table 22)

PEN. LIL. PEN. PEN. ABB. LIL. HEX. HEX. RIK. CEP. PEN. CLC. LIL.

PD.

ABB, BUR.

HEX, LEM, PYL, SCH, SK, x.

SCH.

122

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B.

-Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

MEDICINAL CHEJAICALS, BENZENOID— Continued

»Antiliistamines Continued

*2-[a-(2-Diiiiethylaminoethyl)"benzyl] pyridine ( Phenir amine ) maleate. 2-[l-[2-(2-Dimethylaiiiinoethyl)inden-3-yl]ethyl] pyridine (Dimethindene) maleate. *2 - [ ( 2 -Dime thy laminoe thyl ) ( p -me thoxybenzyl ) amino J pyr id ine (lyrilamine) maleate. 2-[ ( 2-Dimethylaminoethyl ) (p-me thoxybenzyl ) amino] pyr-

imidine ( Thonzylamine ) l^rdroohloride . 2 - [ ( 2 -Dime thy laminoe thyl ) -2 -thenylamino] pyridine

(Methapyrilene) fumarate. 2-L (2-Dimethylaminoethyl )-2-thenylamino] pyridine

(Methapyrilene) hydrochloride. 2-[ (2-Dimethylaminoethyl) -2-thenylamino] pyridine

(Methapyrilene) o-(p-hydroxybenzoyl)'benzoate. 2 - [ (2-Dimethylaminoethyl ) -3 -thenylamino] pyridine

( Thenyldi amine ) hydrochloride . N,N-Dimethyl-2-[(a-phenyl-o-tolyl)oxy]ethylamine (Phenyl-

toloxamine) dihydrogen citrate. 2,3,4,9-Tetrahydro-2-methyl-9-phenyl-lH-indeno[2,l-o]- pyridine ( Phenindamine ) hydrogen tartrate. *Anti-infective agents :

*Antimony, arsenic, bismuth, and mercury compounds: Antimony, arsenic, and bismuth compounds:

N-Acetyl-4-hydroxy-m-arsanilic acid (Acetarsone)

Arsanilic acid

Arsanilic acid, sodium salt

Bismuth subsalicylate

N-Carbamoylarsanilic acid (Carbarsone)

2-( 2-Hydroxy-3 , 5 -disulXophenoxy) -1,3 , 2-benzodioxa- stibole-i,6-disulfonic acid, tetrasodium salt ( Stibophen ) .

'i-Hydroxy-3-nitrobenzenearsonic acid

4-Ifydroxy-3-nitrobenzenearsonic acid, sodium salt

p-Nitrobenzenearsonic acid

1,2,5,6-Tetrahydro-l-methylniootinic acid, methyl ester, N-acetyl-4-hydroxy-m-arsanilate (Drocarbil) Mercury compounds :

o-Chloromercuriphenol ( o-Ifydroxyphenylmercuric

chloride ) . Dibromohydroxymercurifluorescein, sodium salt (Mer-

bromin ) . Ethylmercurithiosalicylic acid, sodium salt

(Thimerosal). 6-(Hydroxymercuri)-5-nitro-o-cresol, inner salt (Nitromersol).

Mercuric salicylate

Phenylmerouric acetate

Phenylmerouric benzoate

Phenylmercuric borate

Phenylmerouric nitrate

»l-Hexadeoylpyridinium (Cetylpyridinium) chloride

*Phenolic antiseptics and disinfectants:

Chlorothymol

2-Naphthol ( |3-Naphthol)'

Resoroinol

Resorcinol monoacetate

Thymol

Thymol iodide

Manufacturers ' identification codes (according to list in table 22)

HEX,

SCH, X.

CBP.

HEX,

MRK, PYl,

RSA

NEP.

ABB.

ABB.

LIL.

SDW.

BRS.

HOF.

SDW.

SAL,

WHL.

SAL,

WHL.

MAL,

NOR,

PEN.

LIL,

PYL,

RSA, WHL.

SDW.

SAL.

SAL.

SAL.

SDW.

MTL.

HYN.

LIL,

PYL.

ABB.

MAL,

MTL.

WRC.

MTL,

WRC.

MTL,

WRC.

MTL,

WRC.

BKL,

FIN,

CAN, HEX

OPC.

ACY.

LEM.

KPT.

GIV.

MAL.

MEDICINAL CHEMICALS

123

TABLE 13B.

-Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, i964— Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHIMICALS, BENZENOID— Continued

*Anti -infective agents Continued *Quinoline derivatives :

8-[(4-Amino-l-methylbutyl) amino] -6-methoxyquinoline

( Primaquine ) . 8-[ ('i-Amino-l-methylbutyl )amino] -6-methoxyquinollne

( Primaquine ) diphosphate . 7-Chloro-4-(4-diethylaTm"no-l-methylbutylamino)quin-

oline ( Chloroquine ) . 7-Chloro-4-(4-[ethyl(2-hydroxyethyl)amino] -1-methyl-

butylamino)quinoline (hydroxychloroquine) sulfate.

*5-Chloro-7-iodo-8-quinolinol ( lodochlorhydroxyquin)

'i-(7-Chloro-4-quinolylamino)-a-diethylamino-o-cresol

(Amodiaquin). 4-(7-Chloro^-quinolylainino)-a-diethylamino-o-cresol

(Amodiaquin) hydrochloride.

»5,7-Diiodo-8-quinolinol (Diiodohydroxyquin)

8-Ifydroxyquinoline-5-sulfonic acid

8-l3uinolinol ( Qxyquinoline )

*8-Quinolinol (Qxyquinoline) benzoate

8-Quinolinol (Qxyquinoline) citrate

8-Q(iinolinol (Qxyquinoline) potassium sulfate

»8-Quinolinol (Qxyquinoline) sulfate

*Sulf onamides :

6-Acetamido-4-hydroxy-3-(<t-sulf amoylphenylazo) -2,7-

naphthalenedisulfonio acid, disodium salt (Azo-

sulfamide). N-'--Acetyl -N^- ( 3,4-dlmethyl-5 -isoxazolyl )sulf anilamide

( Acetylsulf isoxazole ) .

N^-Acetylsulfamethoxypyridazine

- 4'-(Acetylsulfamoyl)phthalanilio acid (Phthalyl-

sulf acetamlde ) .

N*-Benzylsulfanilamide

N,N'-Bis(3-nitrobenzenesulfonyl)ethylenediamine

N^- ( 6-Chloro-2 -pyrazinyl ) sulfanilamide ( Sulf achloro-

pyrazine), sodium derivative. N-'--(2,6-Dimethoxy-4-pyrimidinyl)sulfanilamide (Sulfa-

dimethoxine ) . N-'--(3,4-Dimethyl-5-isoxazolyl) sulfanilamide (Sulf isoxa- zole) . N^-(5-Ethyl-l,3,4-thiadiazol-2-yl)sulfanilamide (Sulfa-

ethidole). N-'--( 5 -Methyl-3-isoxazolyl) sulfanilamide (Sulfamethoxa- zole ) . N^-(5-Methyl-3,4-thiadiazol-2-yl)sulfanilamide (Sulfa-

methizole ) . 4' - ( p -Ni trophenyls ulf amoyl ) aeetanilide (Sulfanitran)—

p-Nitrosulfathiazole

Succinylsulfathiazole

Sulfabromomettiazine, sodium

Sulfanilamide

Sulfanilanilide

N-Sulfanilylacetamide (Sulfacetamide)

N-Sulfanilylacetamide, sodium derivative

N-Sulfanilylbenzajnide ( Sulf abenzamide )

N-Sulfanilylbenzamide, sodium derivative

Sulfadiazine

Sulfadiazine, sodium

SDW.

PD.

SDW.

SDW.

CBP, MTL, PYl. PD.

PD.

LEM, PYL, PSA, SHI.

MTL.

GAM, LEM, MTL.

GAM, LEM, MTL.

GAM.

LEM.

GAM, LEM, MTL, PYL.

SDW.

ACY. LEM.

SDW.

SAL. ACY.

HQF.

HOP.

ACY.

SAL.

SDW.

LEM, MRK.

MRK.

MRK.

LEM, SAL.

LEM, SCH.

LEM, SCH.

ACY.

ACY.

ACY, LEM.

ACY.

124

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B -Mediciml chemicals for which U.S. production or sales were reported, identified hy lABLii!- iJo. manufacturer, i 964 —Continued

Chemical

MEDICIKAL CHEMICALS, BENZENOID— Continued

»Anti -infective agents— Continued ^Sulfonamides Continued

Sulfaguanidlne " ""

Sulfamerazine

Sulfamerazine, sodium 'J'S"

Sulfamethazine

Sulfamethoxypyridazine 'J^

Sulfapyridine "

Sulfapyridine, sodium

Sulfaqulnoxallne

*Sulfathiazole " "'

Sulfathiazole, sodium ''"/TllZ'V-,

<i'-(2-Thlazolylsulfajiioyl)phthalanilic acid (Phthalyl-

sulf athiazole ) . *Other antl -Infective agents:

^Anthelmintic, antifungal, and antiprotozoan agents : l-[ ('i-Amino-2-propyl-5-pyrlmidlnyl)methyl] -2- pioollnium chloride hydrochloride (Amprolium).

Anthranlllc acid, cadmium salt

Benzoic acid "

Bis(3-nltrophenyl) disulfide ( Nitrophenide )

2-Chloro^-nitrohenzamlde (Aklomlde)

2,4-Diamlno-5-(p-ohlorophenyl)-6-ethylpyrlmldine

( I^lmethamine ) . 6-(2-Diethylaminoethoxy)-2-dimethylaminobenzo- thiazole ( Diamthazole ) dlhydrochloride.

Fuchsin, basic "

Gentian violet (Methylrosanlllne chloride)

Hexylresorclnol

p-Ifydroxybenzolc acid esters :

n-Butyl p-hydroxybenzoate

Ethyl p-hydroxybenzoate

Methyl p-hydroxybenzoate

Propyl p-hydroxybenzoate

Phenothlazine

P5mrinlum pamoate "

2-(4-Thiazolyl)benzimldazole (Thiabendazole)

*A11 other anti-infective agents:

Acriflavine

Aeri violet

Aminosalicylic acid and salts:

4-Amlnosallcylic acid

Calcium ^-aminosalicylate

Potassium ^-aminosalicylate

Sodium -^-aminosalicylate

Ammonium benzoate

Calcium mandelate 7

N-Chloro-p-toluenesulfonamide, sodium derivative

(Chloramine T). wj™

2,4-Dlamino-4'-ethoxyazobenzene (Ethoxazene) nyaro-

chlorlde. .

2, 6-Dlamlno-3-phenylazopyrldlne ( Phenazopyridme )

hydrochloride .

3j5-Dlnltrobenzamide 7

l-Ethyl-l,4-dlhydro-7-methyl-4-oxo-l,8-naphthyri-

dine-3-carboxylic (Nalidixic) aold. Hexamethylenetetramlne (Methenamine) mandelate

Manufacturers' Identification codes (according to list in table 22)

ACY, LEM.

ACY, LEM.

ACY.

ACY, LEM.

ACY.

ACY, MRK.

ACY.

MRK.

ACY, LEM, MRK.

ACY, MRK.

LEM, MRK.

MRK.

MAL.

MON, PFZ. ACY. SAL. BUR.

HOP.

NAC.

NAC, SDH. HEX, MRK.

HN, ICO. HN.

HN, ICO, LEM, FYL. HN, ICO, LEM, PYL. CLV.

NAC. NAC.

MLS. MLS. MLS. MLS. PEN. MAL. MON.

KON.

HOF, KON, NEP.

SAL. SDW.

LEM, NEP, PYL, TNC.

MEDICINAL CHEMICALS

125

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, iderdified by

manufacturer, i 564- -Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHmiCALS, BENZENOID— Continued

*Anti -infective agents Continued

mother anti-infective agents —Continued

*A11 other anti -infective agents Continued

Isonicotinic acid hydrazide- (Isoniazid)

Magnesium salicylate

Mandelic acid

Methylene blue

Fyrazine-2-oarboxamide ( I^azinainide )

[ Sulf onylbis (p -phenyleneimino ) ] dimethanesulf inic acid (Sulfoxone), discdium salt.

3,4',5-Tribromosalioylanilide (Tribromsalan)

^Autonomic drugs :

*ParaEymatholytic (anticholinergic) agents:

Anisotropine methyl bromide

(3 -Carbamoyl -3, 3-diphenylpropyl)diisopropy Imethyl-

ammonium ( Isopropamide ) iodide. (3 -Carbamoyl -3, 3-diphenylpropyl) ethyldimethyl-

aramonlum (Ambutonium) bromide. l-Cyclohexyl-3-diethylamino-l-phenyl-l-propanol

ethiodide ( Tridihexethyl iodide). <i-(P -Cyolohexyl-g -hydroxyphenethyl ) -1, 1-dimethyl-

piperazinium (Hexccyclium) methyl sulfate. a-Cyclohexyl-a-phenyl-1-piperidinepropanol (Tri- hexyphenidyl ) . a-Cyolohexyl-a-phenyl-1-piperidinepropanol (Tri- hexyphenidyl ) hydrochloride . P-Diethylaminoethyl diphenylthioaoetate ( Thiphenamil )

hydrochloride . 10-(2-Diethylaminopropyl)phenothiazine (Bthopropazine)- Diethyl(2-hydroxyethyl)methylammonium bromide,

xanthene-9-carboxylate (Methantheline bromide). 4- ( Dimethylami no ) -2, 2 -diphenylvaleramide (Aminopenta-

mide) sulfate. N, N-Dimethyl-2-( o-methyl-a-phenylbenzyloxy) ethylamine

(Orphenadrine) citrate. N,N-Dimethyl-2-( o-methyl-a-phenylbenzyloxy) ethylamine

( Orphenadrine ) hydrochloride . N,N-Dimethyl-4-piperidylidene-l,l-diphenylme thane

(Diphemanil) methyl sulfate. Diphenylaoetyldiethylaminoethanol (Adiphenine) hydro- chloride . N- Ethyl -3-piperidyl benzilate methobromide (Pipenzo-

late bromide). N-Ethyl -3-piperidyl diphenylacetate ( Piperidolate )

hydrochloride . Fluorene-9-carboxylio acid, 2-(diethylamino)ethyl

ester (Pava trine) hydrochloride.

Homatropine

Homatropine hydrobromide

Homatropine methyl bromide

4-Ifydroxy-l,l-dimethylpiperidinium methyl sulfate,

3-methyl-2-phenylvalerate ( Pentapiperide methyl

sulfate). (2-Hydroxyethyl)diisopropylmethylammonium bromide,

xanthene-9-carboxylate (Propantheline bromide). N-Methyl -3-piperidyl benzilate methobromide (Mepenzo-

late bromide ) .

RIL. MAI. MAL. ACY, NAC.

MRK. ABB.

TRO.

SK.

ICO.

ACY.

ABB.

SDW.

ACY.

X.

NEP. SRL.

ICO.

RIK.

RIK.

SCH.

CBP.

LKL.

LKl.

SRL.

CTN, HEX.

CTN.

CTN, EN, HEX.

SRL. LKL.

126

SYNTHETIC ORGANIC CHEMICALS. 1964

TABLE 13B.

. Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

MEDICINAL CHEMICAIS, BENZENOID— Continued

^Autonomic drugs Continued

^Parasympatholytic (anticholinergic) agents --Continued l-Phenylcyclohexaneglycolio acid, ( 1,4,5, 6-tetrahydro- l-methyl-2-pyTimidinyl)inethyl ester (Oxyphen- cyclimine) hydrochloride. 1-Phenylcyolopentaneoarboxylio acid, 2-diethylamino-

ethyl ester ( Caramiphen) ethanedisulf onate . Tropine benzhydryl ether methanesulf onate (Benztropine mesylate ) . ^-Sympathomimetic (adrenergic) agents:

i_3,<i_DihydroxyTiorephedrine (Nordefrin) hydrochloride—

*Epinephrine

l-(p-Hydroxyphenyl) -2-(l-niethyl-3-phenylpropylamine) - propanol (Nylidrin) hydrochloride. »a-(lsopropylaminomethyl)protocatechuyl alcohol (Iso- proterenol ) . o-Methoxy-N,a-diinethylphenethylamine (Methoxyphena-

mine) hydrochloride. a-(l-Methylaminoethyl)benzyl alcohol ( Pseudoephedrine )

hydrochloride . a-(l-Methylaminoethyl)ben2yl alcohol (Pseudoephedrine)

sulfate. a-[([x-Methyl-3,4-methylenedioxyphenethylamino)- methyl]protocatechuyl alcohol ( Protoltylol ) hydro- chloride .

^Norephedrine (Phenylpropanolamine) hydrochloride

1 -Phenylephrine base

^Phenylephrine hydrochloride

2-(l,2,3,4-Tetrahydro-l-naphthyl)-2-imidazoline ( Tetrahydrozoline ) hydrochloride . *111 other autonomic drugs :

2-Benz;yl-2-imidazoline (Tolazoline) hydrochloride

1-Hydrazinophthalazine (Ifydralazine) hydrochloride

3-Ifydroxy-l-methylpyridinium bromide, dimethyl- carbamate (I^idostigmine bromide).

Neostigmine bromide

Physostigmine

*Benzothiadiazine derivatives :

3-Benzyl-3,'4-dihydro-6-(trifluoromethyl)-2H-l,2,4-benzo- thiadiazine-7-sulfonamlde 1,1-dioxide (Bendroflu-

me thiazide). 3-Benzylthlomethyl-6-chloro-2H-l,2,'i-benzothladia-

zine-7 -sulfonamide 1,1-dioxide (Benzthiazlde). 6-Chloro-2H-l, 2, •i-benzothiadiazine-7 -sulfonamide 1,1- dioxide (Chlorothiazide). 6-Chloro-2-chloromethyl-3,<i-dihydro-2-methyl-2H-l,2,'4-

benzothiadiazine-7-sulfonamide 1,1-dioxide (Methy-

clo thiazide ) . 6-Chloro-3-dichloromethyl-3,'i-dihydro-2H-l,2,4-benzo-

thiadiazine-7-sulfonamide 1,1-dioxide (Trichlor-

methiazide). 6-Chloro-3,4-dihydro-2H-l,2,4-benzothiadiazine-7-sul-

fonamide 1,1-dioxide (Ifydrochlorothiazide). 6-Chloro-3, 4-dihydro-2 -methyl -3-(2, 2, 2-trif luoroethyl-

thiomethyl)-2H-l, 2, 4-benzothladiazine-7 -sulfonamide

1,1-dioxide (Polythiazide). 6-Chloro-3,4.-dihydro-3-(5-norbomen-2-yl)-2H-l,2,4-ben-

zothiadiazine-7 -sulfonamide 1,1-dioxide (Cyclo-

thiazide).

Manufacturers' identification codes (according to list in table 22)

SDW.

DQD, SDW, VB.

ABB, CTN, GAH.

BUR, CAN. CAN.

BKL, GAM, CAN, HEX, ICO, NEP, ORT.

CTN, GAN.

CTN, GAN, SDW. PFZ.

CTN. GBP.

HOF.

HEX. PEN.

CMS.

MRK. ABB.

SCH.

ABB, CBP, MRK. PFZ.

LIL.

MEDICINAL CHEMICALS

127

TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHIMICAIS, BENZENOID— Continued

*Benzothiadiazine derivatives Continued

3,4-Dihydro-6-(trifluoromethyl)-2H-l,2,'^-'benzothia-

diazine-V-sulfonamide 1,1-dioxide (Hydroflumethiazide). 6-(Trifluoromethyl)-2H-l,2,'i-benzothiadiazine-7-sulfon- andde 1,1-dioxide (Flume thiazide).

*Bismuth subgallate

^Central depressants :

*Dihydrooodeinone (Hydrooodone) bitartrate

*5-Ethyl-5-phenylbarbituric acid (phenobarbital)

*5-Ethyl-5-phenylbarbituric acid, sodium derivative

*p-Ifydroxyacetanilide (Acetaminophen)

^-Salicylates :

Aluminum aspirin

*Aspirin

Ethyl salicylate carbonate

Glycol monosalicylate

Phenyl salicylate (Salol)

Potassium salicylate

Salicylamide

Salicylsalicylic acid

*Sodium salicylate

Strontium salicylate

^Skeletal muscle relaxants and tranquilizers: *Phenothiazine derivatives :

2-Chloro-10-(3-dimethylaminopropyl)phenothiazine

( Chlorpromazlne ) hydrochloride . 2-Chloro-10-[3-(l-methyl-4-piperazinyl)propyl] -

phenothiazine (Prochlorperazine) dimaleate. 2-Chloro-10-[3-(l-methyl-4-piperazinyl)propyl] -

phenothiazine (Prochlorperazine) ethanedisulfonate. 'i-[3-(2-Chlorophenothiazin-10-yl)propyl]-l-piper-

azineethanol ( Perphenazine ) . 10-(2-DiinethylaTninopropyl)phenothiazine (Prometh- azine) hydrochloride. 10 - ( 3 -Dimethylrimi nopropyl )phenothiazine ( Promazine )

hydrochloride . 10 - ( 3 -Dimethylaminopropyl ) -2 - ( trif luoromethyl ) - phenothiazine (Triflupromazine) hydrochloride. 1- [ 10- ( 3 -[<+-( 2 -Hydroxyethyl ) -1-piperazinyl] propyl ) - phenothiazin-2-yl] -1-propanone ( Cairphenazine ) base and maleate. 10-[(l-Methyl-3-piperidyl)methyl]phenothiazine

(Mepazine) hydrochloride hydrate. 4-(3-[ 2- ( Trif luoromethyl )phenothiazin-10-yl] propyl ) - 1-piperazineethanol ( Fluphenazine ) dihydro- ohloride.

*3-o-Tolyloxy-l,2-propanediol (Mephenesin)

*A11 other skeletal muscle relaxants and tranquilizers : 2-(Butylaminomethyl)-8-ethoxy-l,4-benzodioxane

( Ethoxybutamoxane ) hydrochloride , l-(p-tert-Butylbenzyl)-4-(p-chloro-a-phenylbenzyl)-

piperazine (Buclizine) dihydrochloride. Carbamic acid, 2-hydroxy-2-phenylbutyl ester

( ^ydroxyphenamate ) . Carbamic acid, 2-hydroxy-2-phenylethyl ester ( Styramate ) .

BKC, MAI, PEN.

EN, MAL, MRK,

PEN.

BPC, GAN, MAL,

SDW.

BPC, GAH, MAL,

SDW.

ABB, ATP, MLS,

NEP.

ABB, SCH.

CFC, DOW, MI5,

MON, NOR, SDG

PD.

EDA.

DOW, MAL, PEN.

HST, PEN.

CFC, X.

TNC.

DOW, HN, MON.

MAL, TNC.

SK.

SK.

SK.

SCH.

WYT.

WYT.

CMS, SK.

wn.

NEP. CMS, SCH.

BKL, HEX, QMS.

LIL.

PFZ.

AHP.

ARP.

128 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B. -Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, i 564— Continued

MEDICINAL CHEMICALS, BE^EENOID— Continued

K-Central depressants Continued

*Skeletal muscle relaxants and tranquilizers— Continued *A11 other skeletal muscle relaxants and tranquilizers— Continued l-(p-Chlorobenzhydryl )-A-[2-{2 -hydroxyethoxy) ethylj -

piperazine (hydroxyzine) dihydrochloride . l-(p-Chlorobenzhydryl) -A-i 2-( 2-hydroxyethoxy) ethyl] -

piperazine (Hydroxyzine) pamoate. 7-Chloro-l,3-dihydro-l-metl:^l-5-phenyl-2H-l,4-t)enzo-

diazepin-2-one- (Diazepam). Y

trans-2-Chloro-N,';N-dimethylthioxanthene-A^' -propyl- amine (Chlorprothlxene). 7-Chloro-2-methylamino-5-phenyl-3H-l,'4-benzodi-

azepine-4-oxide ( Chlordiazepoxide ) hydrochloride. 2-(p-Chlorophenyl)-3-methyl-2,3-butaiiediol (Phena-

glycodol ) . 2 - ( 4-Chlorophenyl ) tetr ahydro -3 -methyl -4H-1, 3 -thiazin-

<i-one 1,1-dioxide ( Ghlormezanone ) . 5 - ( o-Methoxyphenoxymethyl ) -2 -oxazolidinone (Mephen-

oxalone ) . 2-Jfethyl-3-o-tolyl-'i ( 3H) -quinazolinone ( Methaqualone ) a-(4-Piperidyl)benzhydrol (Azacyclonol) hydro- chloride. 3-o-Tolyloxy-l,2-propajiediol 1-carbamate (Mephenesin carbamate).

Tubocurarine

*A11 other central depressants :

Acetanilide

Aoetophenetidin (Phenacetin)

p-Aminobenzoic acid and salts :

p-Aminobenzoic acid

Calcium p-aminobenzoate

Magnesium p-aminobenzoate

Potassium p-aminobenzoate

Sodium p-aminobenzoate

l-(p-Aminophenethyl)-'i-phenylisonipecotic acid, ethyl

ester (Anileridine) dihydrochloride. 2-(p-Aminophenyl) -2-ethylglutarimide (Aminoglutethi-

mide. <i-Butyl-2-p-hydroxyphenyl-l-phenyl-3,5-pyrazolidine-

d ione ( Oxyphenbutazone ) .

Colchicine

Dihydrohydroxycodeinone (Cixycodone) hydrochloride

a-d-4-Dlmethylamino-l,2-diphenyl-3-methyl-2-propoxy-

butane (Propoxyphene) hydrochloride. ( [ (2,3-Dimethyl-5-oxo-l-phenyl-3-py^azolin-'i-yl)- methyl]-amino)methanesulfonio acid, sodium salt

(Dipyrone).

N,2-Dimethyl-2-phenylsucoinimide (Ifethsuximide )

5,5-Di^henylhydantoin

5, 5-Diphenylhydantoln, sodium salt

5-Ethyl-l-methyl-5-phenylbarblturle acid (Mepho-

barbital) .

Ethyl l-methyl-4-phenylisonipecotate (Meperidine)

Ethylmorphlne hydrochloride

5-Ethyl-5-phenylbarblturic acid (Phenobarbital),

calcium derivative.

2-Ethyl-2-phenylglutarlmide ( Glutethimide )

3-Ethyl-5-phenyIhydantoin (Ethotoin )

Hexahydro-l-methyl-4-phenylazepine-4-carboxyllc acid,

ethyl ester ( Ethoheptazine ) citrate.

Manufacturers' identification codes (according to list in table 22)

PFZ.

PFZ.

HOF.

HOF.

HOF.

LIL.

SDW.

ACY.

HEX. BKC.

CMS.

ABB, CMS.

CTN. DOW, MON.

LEM. LEM. LEM.

CAN, LEM. CAN, LEM. MEK.

CBP.

GGY.

PEN.

EN.

LIL.

SDW, WYT. MAL, MRK. CAN.

CBP. ABB. WYT.

MEDICINAL CHEMICALS

129

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHEMICALS, BENZENOID— Continued

♦Central depressants Continued

*A11 other central depressants Continued

lodoantipyrine (lodopyrine)

d-3-Methoxy-N-methylmorphinan (Dextromethoiphan) hydro- bromide. oj-MethoxypolyCethyleneoxy) ethyl p-butylaminobenzoate ( Benzonatate ) ,

N-Methyl-2-phenylsuccinimide ( Phensuximide )

10-Hienothiazineoarboxylio acid, 2-(2-diinethylamino- ethoxy)ethyl ester (Dimethoxanate) hydrochloride.

Fhenylacetylurea ( Phenacemide )

1-Phenylcyclopentaneoarboxylic acid, 2-(2-diethylaiiu.no-

ethoxy)ethyl ester ( Carbetapentane ) citrate. a-(2-iyridylajninomethyl)benzyl alcohol ( Phenyramidol ) hydrochloride . ♦Central stimulants : ♦Amphetamines :

♦Amphetamine, dextroamphetamine, and levan^hetamine base and salts :

d-a-Methylphenethylamine (Dextroamphetamine) base

d-a-Methylphenethylamine, carboxymethylcellulose salt

d-a-Methylphenethylamine hydrochloride

d-a-Methylphenethylamine phosphate

d-a-Methylphenethylamine sulfate

d-a-Metl^rlphenethylamine tannate .

dl-a-Methylphenethylamlne (Amphetamine) base

dl-a-Methylphenethylamine hydrochloride

dl-a-Methylphenethylamine sulfate

2 -a-Methylphenethylamine ( Levamphetamine ) succinate ♦Methamphetamine base and hydrochloride :

d-N,a-Dimethylphenethylamine (Methamphetamine) hydro- chloride. dl-N,a-Dimethylphenethylamine (Methamphetamine) base- dl-N,a -Dimethylphenethylamine (Methamphetamine )

hydrochloride. Z -N,a -Dimethylphenethylamine (Methamphetamine) base ♦Antidepressants :

l-[2-(Benzylcarbamoyl)ethyl]-2-isonicotinoylhydrazine

( Nialamide ) . 10,11-Dihydro-N, N-dimethyl-5H-dibenzo[a,d] cycloheptene-

45, Y -propylamine ( Amitriptyline ) . 10,ll-Dihydro-N-methyl-5H-dibenzo[a,d]cyoloheptene- A 5, Y -propylamine (Nortriptyline).

Phenethylhydrazlne (Phenelzine) sulfate

trans-2-Phenylcyclopropylamine (Tranylcypromine) sulfate ♦All other central stimulants :

d-N-Benzyl-N,a -dimethylphenethylamine (Benzphetamine ) hydrochloride .

Caffeine sodium benzoate

p-Chloro-a ,a-dimethylphenethylamine ( Chlorphentermine ) hydrochloride .

Diethylaminopropiophenone (Diethylpropion)

2-(Dlmethylamino)ethanol, p-acetamidobenzoic acid salt (Deanol acetamidobenzoate ) .

a , a -Dimethylphenethylamine ( Phentermine )

3,'4-Dimethyl-2-phenylmorpholine ( Phendimetrazine )

3-Methyl-2-phenylmorpholine ( Phenmetrazine ) hydro- chloride . Nikethamide

MAL. HOF.

CBP. PD.

ABB. PFZ.

HEX.

arc.

HEX.

ore.

HEX,

SK.

OTC.

HEX,

ORT.

HEX.

HEX,

SK.

OTC.

ABB,

GAN, HEX

HEX,

OTC.

GAN,

HEX.

ABB.

PFZ.

MRK.

LIL.

NEP.

GAN, MAL. NEP.

BKC, GAN. RIK.

HEX.

x.

GGY.

CBP.

130

SYNTHETIC ORGANIC CHEMICALS. 1964

TABLE 13B.-

Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, i564 --Continued

MEDICINAL CHEMICALS, BENZENOID--Continued

*Guaiaool glyceryl ether

*Salioylio aold

*Synthetlo hypoglycemic agents :

1- [(p-Acetylphenyl )sulfonyl] -3-oyclohexylurea ( Aceto- hexamide ) .

l-Butyl-S-p-tolylsulConylurea (Tolbutamide)

l-(p-Chlorobenzenesulfoiiyl)-3-propylurea (Chlorpropamide) l-(Hexahydro-l-azepinyl)-3-p-tolylsulfonylurea (Tolaz- amide).

l-Phenethylbiguanide (Phenformin) hydrochloride

*Vitajnins :

«B2 (Riboflavin):

For animal and poultry consumption

For human consumption

""B 12 ( Cyanocobalamin ) :

Feed grade

Pharmaceutical

U.S. P. Crystalline

■x-Niacin (Nicotinic acid):

Feed grade

Medicinal grade

*Niaoinamide (Nicotinamide )

»A11 other vitamins :

Folic acid

Magnesium nicotinate

Menadione

Menadione sodium bisulfite

2-Methyl-3-phytyl-l,4-naphthoquinone ( Phytonadione )

Nicotinamide hydrochloride

I^idoxine

Riboflavin-5' -phosphate, monosodium salt

Sodium nicotinate

a -Tocopherol

a -Tocopherol acetate

*A11 other benzenoid medioinals : Amino acids :

dl-Acetyltryptophane

dl-Phenylalanine

dl-Tryptophane

p-A[iiino-N-(2-diethylaminoethyl)benzamide (Procainamide) hydrochloride .

Benzaldehyde

3 -(4-Chloro-3 -sulf amoylphenyl ) -3 -hydroxyphthalimidine

( Chlorthalidone ) . 'i,5-Dichloro-m-benzenedisulfonamide (Dichlorphenamide) l,l-Dichloro-2-(o-chlorophenyl)-2-(p-chlorophenyl)ethane- l -3-(3,4-Dlhydroxyphenyl)-2-methylalanine (Methyldopa)--- 6,7-Dimethoxy-l-(4-ethoxy-3-methoxybenzyl)-3-methyl-

quinoline (Dioxyline) phosphate. p,a-Dimethylben2yl camphorate, diethanolamine salt (Tooamphyl).

p-(Di-n-propylsulfamoyl)benzoic acid (Probenecid)

Estrogens :

3,4-Bis(p-hydroxyphenyl)-2,4-hexadiene (Dienestrol)

diacetate. «,£(' -Diethyl-Aj^'-stilbenediol (Diethylstllbestrol) --■ Estrogenic substance

Manufacturers' identification codes (according to list in table 22)

BKL, GAN, HEX, ICO, OTC. DOW, HN, HST, MON, SDH.

HST, X. PFZ. UP J.

GPR, HOF, MRK, IMP. HOF, MRK.

GPR, MRK, FMP. IMC, MRK. MRK.

ABB, CKL, MRK, NEP, RIL. MRK, NOP, PD, RIL, SCR. MRK, NEP, PD, RIL, SCR.

ACY.

NEP.

ABB, HET, HFT.

ABB, HET, WHL.

MRK.

NEP.

HOF, MRK.

HOF.

MRK, NEP.

CW, HOF.

HOF.

SDW. SDW. SDW. OMS.

GGY.

MRK. EDC. MRK. LIL.

MRK. SCH.

CTN, LIL. ORG.

MEDICINAL CHEMICALS

131

TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHEMICALS, BENZENOID— Continued

*A11 other benzenoid medicinals Continued

N-Ethyl-3,3' -diphenyldipropylamine

N-Ethyl-3,3' -diphenyldipropylamine citrate

N-Ethyl-3,3' -diphenyldipropylamine hydrochloride

2-Formyl-l-methylpyridinium chloride, oxime (Pralidoxime chloride ) .

Guaiacol, liquid and crystalline

Hesperidin methyl chalcone

Indocyanine green

Local anesthetics :

Benzocaine (Ethyl p-aminobenzoate)

2-Butoxy-N-(2-diethylajiiinoethyl)cinchoninamide (Di-

bucaine). <+- [3- (p-Butoxyphenoxy )propyl] morpholine ( Pramoxine ) hydrochloride .

n-Butyl p-aminobenzoate (Butesin)

Di(n-butyl p-ajninobenzoate) trinitrophenol (Butesin piorate).

a-Diethylaniino-2,6-acetcxylidide (lidooaine)

2-Diethylajiiincethyl '4-amino-2-propoxybenzoate (Propoxy-

caine ) . p-Ethoxybenzoic acid, 2-(diethylamino)ethyl ester

(Parethoxycaine) hydrochloride. 2,2' -(2-lfydroxyethylimino )bis [n- (a , a-dimethylphenethyl) N-methylacetamide] (Oxethazaine) .

Isobutyl p-aminobenzoate (Cyoloform)

2-Methyl-l-piperidinepropanol benzoate (Plperocaine )

hydrochloride . 3-(2-Methyl-l-piperidyl)propyl p-oyolohexyloxybenzoate

( Cyclomethycaine ) . Phenacaine [(Di-p-ethoxyphenyl)acetamidine] hydro- chloride.

Procaine base (2-Diethylaininoethyl p-aminobenzoate)

Procaine hydrochloride

Propyl p-amincbenzoate

l-iyrrolidineaceto-2',5'-xylidide (lyrrocaine) hydro- chloride . Tetracaine (2-Diinethylaininoethyl p-butylaminobenzoate) base.

Tetracaine hydrochloride

2-(p-Methoxyphenyl)-l,3-indandione (Anisindione )

2-Methyl-l, 2-di-3-pyridyl-l-propanone (Metyrapone )

3,3' -Methylenebis(4-hydroxycouniarin) (Bishydroxycoumarin) N-Methyl-N-(2-propynyl)benzylamlne (Pargyline) hydro- chloride .

Phenolphthalein

Phenolphthalein, yellow

Phenolsulf onic acid salts :

Aluminum phenolsulf onate

Ammonium phenolsulf onate

Sodium phenolsulf onate

Zinc phenolsulf onate

2-Phenyl-l,3-indandione ( Phenindione )

Podophyllum resin

2-iyridinemethanol (Nicotinyl alcohol) tartrate

Roentgenographic contrast media:

3-Acetamido-2,4, 6-triiodobenzoio acid and sodium salt

(Sodium acetrizoate). 3-(3-Amino-2,'i,6-triiodophenyl)-2-ethylpropicnic acid (lopanoic acid).

CTN. CTN. CTN. NEP.

HN, MON. SKG.

ABB, Lai. CBP.

AST. SDW.

ICO.

WYT.

ICO. LIL.

LIL.

SDW.

ABB.

ABB, LEM. ICO. EN.

ICO.

ICO, SDW. SCH. CBP. ABB, FIN.

WLI.

MAL.

SAL.

MAL, SAL.

MAL.

CTN, GAN.

ABB.

HOF.

MAL.

SDW.

)32 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1 964 - -C ontinued

MEDICINAL CHEMICALS, BENZENOID— Continued

*A11 other benzenoid medicinals Continued Roentgenographio contrast media Continued

3,5-Diacetamido-2,'4,6-triiodobenzoio acid, N-methyl

gluoamine salt (Meglumine diatrizoate ) . 3,5-Diacetamido-2,'i,6-triiodobenzcic acid, sodium salt

(Sodium diatrizoate). 3,5-Dipropionamido-2,'4,6-triiodobenzoic acid and sodium salt (Sodium diprotrizoate).

Ethyl (iodophenyl)hendecanoate ( lophendylate )

Meglumine iothalamate

Sodium o-iodohippurate dihydrate

Sodium iothalamate

Rutin

Scarlet red

Sodium benzoate

8-Sucoinoylfluoranthene ( Florantyrone )

Sunscreens :

Dipropylene glycol salicylate

homo-Menthyl salicylate

p-Methoxyoinnamic acid, benzyl ester

p-Methoxycinnamic acid, 2-ethoxyethyl ester

2,4,7-Triamino-6-phenylpteridine (Triamterene)

MEDICINAL CHEMICAIS, NONBENZENOID

*Anti-infective agents :

»Caprylates and undecylenates :

Calcium undecylenate

Sodium caprylate

Sodium undecylenate

Undecylenic acid

Zinc undecylenate

»Derivatives of 5-nitrofurane, 5-nitroimidazole, and 5-nitrothiazole :

2-Acetamido-5-nitrothiazole ( Acini trazole)

2-Amino-5-nitrothiazole

l-Ethyl-3-(5-nltro-2-thiazolyl)urea (Ni thiazide)

l-(2-}fydroxyethyl)-2-methyl-5-nitroimidazole (Metro- nidazole).

5-Nitro-2-furaldehyde aoetylhydrazone ( Nihydrazone )

5-Nitro-2-furaldehyde semicarbazone (Nitrofurazone)

N-(5-Nitro-2-furfurylidene)-l-aminohydantoin (Nitro- furantoin ) . 3-( 5-Nitro-2-furfurylideneamino)-2-oxazolidinone ( Fura- zolidone). »Halogen compounds :

Bromocamphor, mono-

Bromoform (Tribromome thane)

Chlorobutanol (tert-Triohlorobutyl alcohol)

Iodoform

l-Vinyl-2-pyrrolidinone iodine complex polymer (Povidone - iodine complex). *Piperazine and salts ;

*Piperazine

Piperazine adipate

Piperazine calcium edetate

Piperazine citrate

Piperazine dihydrochloride

Manufacturers' identification codes ( according to list in table 22 )

SDW. SDW. MAL.

MAI. MAI. MAL. PEN. NAC. PFZ. SRL.

SBC. ICO. CIV. GIV.

WTL. INC. BAC. BAC. BAC, LEM, MCO, TNC, WTL.

ACY. ACY.

MRK.

NOR. NOR. NOR.

MAL,

PEN.

DOW.

BPC, MAL,

PD. PEN.

G.

DOW,

JCC,

UCC, X.

JCC,

PYL,

RDA.

EN.

JCC,

RDA.

DOW,

JCC,

PYL, RDA,

WHL

MEDICINAL CHEMICALS

133

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

MEDICINAL CHMICALS, NOMBENZENOID— Continued

»Anti -infective agents Continued *Piperazine and salts Continued

Piperazine hexahydrate

*Piperazine hydrochloride

*Piperazine phosphate

Piperazine sulfate

Piperazine tartrate

All other

*A11 other anti-infective agents ;

l-Mamantanamine (Amantadine) hydrochloride

l-Diethyloarhamoyl-4-methylpiperazine (Diethyl- carhamazine) dihydrogen citrate.

Hexamethylenetetrajnine (Methenamine)

p-(Hydroxymethoxy)trioarballylic acid, Y-lactone, hexamethylenetetramine salt (Citramin).

4,5-Imidazoledioarboxamide ( Glyoarbylamide )

2-Propylvaleric acid and bismuth salt

Sodium bismuth triglycollamate

*Aatonomic drugs :

Acetylcholine chloride

Acetyl -P-methyloholine (Methacholine) chloride

l-Cyclopentyl-2-methylpropylajnine ( Cyclopentamine ) hydro- chloride . Diethylaminocarbethoxybicyolohexyl (Dicyclomine) hydro- chloride. Diethyl ( 2 -hydroxyethyl)methylaiiimoniujii bromide, a-cyclo-

pentyl-2-thiopheneglycolate (Penthienate bromide). N, a-Dimethyloyclohexaneethylamine (l-Cyclohexyl-2-methyl-

aminopropane ) ( Propylhexedrine ) . Hexamethylenebis(trimethylajnmonlum chloride) (Hexa-

methoniujn chloride). trans-['i-(l^droxydi-2-thienylmethyl)oyolohexyl]trimethyl- ammonium bromide (Thihexinol methylbromide).

Tetraethylaranonium chloride

^Central depressants and stimulants : *Barbiturates :

5-ALlyl-5-sec-butylbarbituric acid (Talbutal)

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid and salt- 5-Allyl-5-isobutylbarbituric (Allylbarbituric) acid

and salt. 5-Allyl-5-(l-methylbutyl)barbiturio acid (Secobarbital)

and salt. 5-Allyl-5-(l-methylbutyl)-5-thiobarbituric acid (Thia-

ncrlal), sodium derivative. dl-5-Allyl-l-methyl-5 -( l-methyl-2-pentynyl )barbituric acid (Methohexital), sodium derivative.

*5-seo-Butyl-5-ethylbarbituric acid (Butabarbital)

*5-sec-Butyl-5-ethylbarbituric acid, sodium derivative 5-(l-Cyolohexen-l-yl)-l,5-dimethylbarbiturio acid

( Hexobarbital ) . 5-(l-Cyolohexen-l-yl)-l, 5-dimethylbarbiturlc acid,

sodium derivative. 5-(l-Cyclohexen-l-yl)-5-ethylbarbiturio acid (Cyclo- barbital) and salt.

5,5-Diethylbarbituric acid (Barbital)

5,5-Diethylbarbiturio acid, sodium derivative

5,5-Diethyl-l-methylbarbituric acid (Metharbital)

JCC, RDA.

DOW, JCC, RDA.

BUR, JCC, PYL, RDA, WHL.

JCC, RDA.

PYL, RDA.

PYL.

HN. SDW.

MRK.

MRK, RSA. LIL.

BKC.

SDW.

SK.

RSA.

SCH.

RSA.

SDW. GAN. GAN.

ABB, BPC, GAN. ABB, BPC, GAN. GAN.

SDW.

GAN, SDW.

GAN. GAN. ABB.

134

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B -Medicinal chemicals for which U.S. production or sales were reported, identified by iAai.li. loD. manufacturer, 1964— Continued

MEDICINAL CHEMICALS, NONBENZENOID— Continued

^Central depressants and stimulants Continued i^Barbiturates Continued

S-Ethyl-S-isoamylbarbituric acid (Amobarbital), sodium

derivative. 5-Ethyl-5-(l-inethyl-l-butenyl)barbiturio aoid (Vin- barbital ) . *5-Ethyl-5-(l-methylbutyl)barbituric aoid (Pento- barbital). 5-Ethyl-5-(l-methylbutyl)barbituric acid, sodium de- rivative. 5-Ethyl-5-(l-methylbutyl)-2-thiobarbitiiric acid (Thio- pental) and sodium derivative. 5-Ethyl-5-n-pentylbarbituric aoid, sodium derivative *Caf f eine :

Natural

Synthetic

*2-Methyl-2-propyl-l,3-propanediol dicarbamate (Mepro- bamate ) .

»Suooinylcholine chloride

*A11 other central depressants and stimulants :

Acetylcarbromal [ l-Aoetyl-3-(2-bromo-2-ethylbutyryl)- urea].

Bis(2,2,2-trifluoroethyl)ether (Flurothyl)

2-sec-Butyl-2-methyl-l, 3 -propanediol dicarbamate

(Mebutamate). N-Butyl-2-methyl-2-propyl-l,3-propanediol dicarbamate (Tybamate).

Caffeine citrate

Calcimn succinate

Carbromal (Bromodiethylacetylcarbamide )

p-Chlorovinylethylethynyloarbinol (Ethchlorvynol)

3,3-Diethyl-5-methyl-2,'4-piperidinedione (Methyprylon)-

2-(Dimethylamino)ethanol (Deanol) bitartrate

Divinyl ether

2-Ethyl-ois-orotonylurea (Eotylurea)

5-Ethyl-3,5-dimethyl-2,'i-oxazolidinedione ( Parametha- dione ) .

2-Ethyl-2-methylsuooinimide (Ethosuximide)

Ethynylcyclohexyl carbamate (Ethinamate)

N-Isopropyl -2 -methyl -2 -propyl -1,3-propanediol dicar- bamate (Carisoprodol).

Sodium hydroxydione succinate

Sodium succinate

2,2,2-Tribromoethanol

3,5,5-Trimethyl-2,4-oxazolidinedione (Trlmethadione) *Digestants and lipotropic agents :

»Betaine base, hydrate, and hydrochloride:

Betaine base

Betaine hydrate

Betaine hydrochloride

»Bile acids and salts :

Bile acids, oxidized

Dehydrocholic acid

Dehydrocholic acid, sodium salt

Iron bile salts

Oxbile extract

^Choline bitartrate

Manufacturers' identification codes (according to list in table 22)

BPC, GAN, LIL.

GAN.

ABB, BPC, GAN.

ABB, BPC, GAN.

GNF, luffW. MON, PFZ. ABB, BKL, ICO, PEN, x.

ABB, BUR, SDW.

MLS.

TBK.

X, X.

MAL, MRK. LEM, PEN. MLS, PD.

MRK. MLS.

PFZ. PEN. SDW. ABB.

MAL. HFT. HFT, LEM, INC.

MRK, SRL, WIL.

WIL.

WIL.

LIL.

ABB.

ACY, CFC, HFT.

MEDICINAL CHEMICALS

135

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

MEDICINAL CHIMICALS, NONBENZENOID— Continued

*Digestants and lipotropic agents Continued ^Choline chloride :

Feed grade

Medicinal grade

Technical grade

^Choline dihydrogen citrate

'•Methionine and hydroxy analogue :

Methionine, feed grade

dl-Methionine, medicinal grade

Methionine, hydroxy analogue

»Trioholine citrate

*A11 other digestants and lipotropic agents :

Acetylmethionine

Choline bicarbonate

Sitosterols

*Hormones :

Corticotropin

Dexamethasone

Dexamethasone acetate

Dexamethasone 21 -phosphate

9,lip-Dichloro-17,21-dihydroxypregna-l,4.-diene-3,20-

dione (Dichlorisone) 21-aoetate. 17a-Ethynyl-17P-hydroxy-5(lO)-estrene-3-one (Norethyno- drel).

9c4-Fluorohydrooortisone acetate (Fludrocortisone)

Fluorometholone

9-Fluoro-llfi,17,21-trihydroxy-16j3-methylpregna-l,4-diene 3,20-dione (Betamethasone).

Fluoxymesterone

Fluprednisolone

*Hirdrocortisone alcohol and acetate

hydrocortisone dlethylaminoaoetate ( Ifydrocortamate ) hydrochloride .

Ifydrocortisone phosphate

J.7-Ifydroxy-ll-dehydrooortioosterone (Cortisone) and

acetate. 17-^ydroxypregna-4-ene-3,20-dione (Ifydroxyprogesterone)-

lla-Hydroxyprogesterone

Insulin (salt cake)

Medroxyprogesterone acetate

17 -Methyl -5a-androstano[3,2-c] pyrazole-17/3-ol (Stano- zolol ) .

Methylprednisolone

Prednisolone

*Prednlsone

Progesterone

Triamcinolone

^Theobromine and theophylline derivatives :

Theobromine, sodium acetate

Theophylline aminoisobutanol (Ambuphylllne)

Theophylline cholinate (Oxtriphylline)

Theophylline ethylenediamine (Aninophylline)

Theophylline ethylenediamine, sodium biphosphate

Theophylline monethanolamine

^Therapeutic nutrients : *Amino acids ;

|S -Alanine

*Amino acid mixtures

Manufacturers' identification codes (according to list -in table 22)

CCM,

HFT.

CFC,

HFT.

DLI,

RH.

ACY,

CFC,

HFT

DOW.

DOW,

LEM.

DUP,

MON.

ACY,

CFC,

HFT

DOW.

CCM,

HFT.

HP J.

AHP,

ORG,

WIL

MHK,

SCH.

SCH.

MRK.

SCH.

SRL.

UPJ.

UP J.

SCH.

UPJ.

UPJ.

MRK,

PFZ,

UPJ

PFZ.

MRK.

MRK,

UPJ.

SCH.

UPJ.

ARP.

X.

SDW.

UPJ.

MRK,

SCH,

UPJ.

MRK,

SCH,

UPJ.

X.

ACY,

OMS.

MAL.

GAN.

NEP.

GAN,

LIM,

SRL.

GAN.

LIL.

BFG,

NOP.

ABB,

CUT,

STA.

136

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 13B -Mediciml chemicals for which U.S. production or sales were reported, identified by TABLh, iJhi. ivjeui^c manufacturer, i 564 -Continued

Chemical

MEDICINAL CIDMICALS, NONBENZENOID— Continued

x-Therapeutio nutrients— Continued *Amino acids Continued *Aspartic acid and salts :

dl-Aspartic acid

Magnesium hydrogen aspartate

Potassium hydrogen aspartate

Glutamic acid and salts :

^♦Glutaniic acid

Glutamic acid, calcium salt

Glutamic acid hydrochloride

Glutamic acid, monoammonium salt

Glutamic acid, monopotassium salt

Glycine (Aminoaoetic acid)

lysine, feed grade

lysine hydrochloride

*Calcium gluconate

*A11 other therapeutic nutrients:

Calcium glucoheptonate

Calcium glycerophosphate

Calcium lactophosphate

Calcium levulinate

Calcium phytate

Copper gluconate

Fructose (Levulose)

Iron (ferrous) gluconate

Lecithin, purified

Magnesium gluconate

Manganese gluconate

Potassium gluconate

Sodium glycerophosphate

*5-Ureidohydantoin (Allantoin)

^Vitamins :

*Ascorbio acid and derivatives :

*Ascorbic acid

Ascorbic acid, calcium salt

Ascorbic acid, sodium salt

Ascorbyl palmitate

^Pantothenic acid and derivatives:

d-Calcium pantothenate

»dl-Calcium pantothenate:

Feed grade

Medicinal grade

dl-Caldium pantothenate, calcium chloride complex-

d-Pantothenyl alcohol (Dexpanthenol)

dl-Pantothenyl alcohol (Panthenol)

Sodium pantothenate

*Vitajiiin A alcohol and esters :

Vitamin A acetate (feed grade)

Vitamin A acetate (medicinal grade)

Vitamin A alcohol

Vitamin A natural esters

Vitamin A palmitate (feed grade)

»Vitamin A palmitate (medicinal grade)

*Vitamin Da (Ergocalciferol)

*A11 other vitamins :

Biotin

P -Carotene

Inositol

Thiamin hydrochloride

Thiamin mononitrate

Vitamin D3 ( Cholecalcif erol )

Manufacturers' identification codes (according to list in table 22)

HE}{, MAC.

WYT.

WYT.

MC,

LIM,

PFZ.

LEM.

IMC,

LEM.

IMC.

IMC,

LEM,

PFZ.

BPC,

DOW.

MRK.

MRK.

MAL,

PFZ,

WHL.

PFN.

SEL.

MAI.

SEL.

STA.

PFZ.

DLL

PFZ.

ARP.

PFZ.

PFZ.

PFZ.

SEL.

CTN,

FIN,

HFT.

HOF,

MRK,

PFZ.

PFZ.

HOF,

MRK,

PFZ.

PFZ.

ACY,

DLI,

MRK, X.

NOP.

ABB,

CKL,

HFT, MRK, NOP

NOP.

HOF.

HOF.

PD.

HOF

HOF

PFZ

CW,

HOF.

CW.

EK,

HOF.

n.

HOF,

PFZ.

DLI

NOP

SCR, VTM.

HOF

HOF

STA

HOF

, MRK

HOF

, MRK

DLI

, VTM

MEDICINAL CHEMICALS

137

TABLE 13B. Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MEDICINAL CHEMICALS, NONBENZENOID— Continued

*A11 other nonbenzenoid meaioinal chemicals :

5-Aoetamido-l,3,'i-thiadiazole-2-sulfonajnide (Acetazol-

amide). 2-(2-Aminoethyl)-2-thiopseudourea dihydrobromide (AET)—

6-Aminohexanoic (Aminooaproic) acid

Calcium camphosulfonate

Cellulose, oxidized

Dextran

Digitoxin

3,5-Dliodo-4-pyridone-N-aoetio acid, diethanolajnine salt

( lodopyracet ) .

Ethyl carbamate (Urethane)

Ethylenediamine dihydriodide

Ethyl nitrite

Galactose

Gitalin

Glyceryl trinitrate

Heparin, sodium

17-}fydroxy-7a-meroapto-3-oxo-17a-pregn-4-ene-21-carbox-

ylic acid, Y -lactone, 7-acetate (Spironolactone). 2-Iodoethyl-l,3-dioxolane-4-methanol (lodinated glycerol

lodomethanesulfonic acid (Methiodal), sodium salt

Isosorbide dinitrate

Magnesium citrate

6-Mercaptopurine

Mercury compounds :

N-[3-(Carboxymethylthiomercuri)-2-methoxypropyl] -a- oamphoramic acid, disodium salt (Mercaptomerin, sodium).

[ 3 - ( Chloromercur i ) -2 -methoxypropyl] urea ( Chlormero - drin) .

N- [ 3 - ( ^droxymercuri ) -2 -me thoxypropyl] -a -c amphor ami c acid, sodium salt and theophylline (Mercurophylline, sodium).

l-[3-(Hydroxymercuri) -2 -methoxypropyl] -3-succinylurea and theophylline (Meralluride ) .

l-Methylimidazole-2-thiol (Methimazole )

Polyacrylic acid ( Polyearbophil )

Polyaorylic acid, calcium salt

6-Propyl-2-thiouracil

Sodium carboxymethylcellulose (medicinal grade)

Sodium tartrate

Sulfosuccinic acid, bis(2-ethylhexyl)ester, sodium salt

(Dioctyl sodium sulfosuccinate).

Terpinol hydrate

Veratrum viride (Alltavervir)

ACY.

SBR.

ACY.

FIN, PYL.

EKT.

PHR.

BUR.

SDW.

FMP.

PYL, TOL. MAL. PFN. PEN. APD.

ABB, RIK. SRL.

SDW. APD. MAL. BUR.

WYT.

LKL. FIN.

LKL.

LIL. WLI. WLI. PYL. CBP. MAL. ACY.

LEM, PEN. PEN, RIK.

138

SYNTHETIC ORGANIC CHEMICALS, 1964

Flavor and Perfume Materials

TABLE 14B.

-Flavor and perfume materials for which U.S. production or sales were reported, identified by manufacturer , 1964

[Flavor and perfume materials for which separate statistics are given in tatle 14A are marked below with an asterisk (»); those not so marked do not appear in table WA because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers ' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC

Benzenoid and ^aphthalenoid

2'-Aoetonaphthone (Methyl P-naphthyl ketone)

Acetophenone

7-Acetyl-6-ethyl-l,l,4,4-tetramethyl-l,2,3,4-tetrahydro- naphthalene .

p-Allylanlsole

Allyl phenoxyacetate

»4-Allylveratrole (Eugenyl methyl ether)

p-tert-Amylcyclohexanone

*Anethole (p-Propenylanisole)

*p-Anisaldehyde (p-Methoxybenzaldehyde )

Anisole (Methyl phenyl ether)

Anisyl acetate

Anisyl alcohol

^Benzophenone

*Benzyl acetate

*Benzyl alcohol

Benzyl benzoate

Benzyl butyrate

^Benzyl cinnamate

*Benzyl ether

Benzyl formate

Benzyl glyceryl acetal

Benzylidene acetone

Benzyl isoeugenyl ether

Benzyl isopentyl ether

Benzyl phenylacetate (Benzyl a-toluate)

*Benzyl propionate

^Benzyl salicylate

a-Bromostyrene

4- ' -tert-Butyl-2' , 6' -dimethyl -3 ' , 5 ' -dinitroaoetophenone

(Musk ketone ). 6-tert-Butyl-3-methyl-2,'i-dinitroanisole (Musk ambrette)-- p-tert-Butyl-a-methylhydroclnnamaldehyde (a-Methyl-p-(p-

tert-butylphenyl )propionaldehyde ). 5-tert-Butyl-l,2,3-trimethyl-4-,6-dlnitrobenzene (5-tert- Butyl-'t, 6-dlnitrohemimellitene ) .

5-tert-Butyl-2,<i,6-trinitro-m-xylene (Musk xylol)

Carvacrol (2-p-Cymenol )

*Cinnamaldehyde

Cinnamlc acid

Cinnamyl acetate

*Cinnaiiiyl alcohol

Cinnamyl anthranllate

Cinnamyl cinnamate

Cinnamyl formate

Cinnamyl isovalerate

Cinnamyl propionate

trans -Decahydro-2-naphthol

p,a-Dimethylbenzyl alcohol (p-Methylphenylmethylcarbinol)-

*fa,a-Dimethylphenethyl acetate

a,a-Dimethylphenethyl alcohol

a,a-Dimethyl-3-phenyl-l-propanol

GIV,

TBK.

GIV,

TBK.

GIV.

GIV.

GIV.

FB,

GIV,

ICO,

TBK.

IFF.

AHZ,

GLD,

HNW,

HPC,

UNG.

GIV,

ICO,

OPC,

TBK,

UNG.

GIV.

GIV,

TBK.

GIV,

TBK.

G, GIV, ICO, NEO, TBK.

GIV,

OPC,

RDA

SHL,

TBK, TNP

BPC,

GIV,

OPC,

SHL,

TBK, TNP

MON,

TBK,

TNP.

FB,

TBK.

GIV,

ICO,

TBK

OPC,

SHL,

TNP

TBK.

GIV.

FB.

GIV,

TBK.

GIV.

MYW,

TBK.

FB,

GIV,

TBK.

GIV,

OPC,

TBK,

UNG.

TBK.

GIV.

GIV.

GIV,

TBK

GIV.

GIV.

GTV.

FB,

OPC,

TBK.

BPC

FB,

GIV,

TBK.

FB,

GIV,

NEO,

TBK.

FEL

GIV,

RT.

TBK

TBK

TBK

GIV

IFF

GIV

GIV

IFF

RDA

TBK.

IFF

IFF,

TBK

FLAVOR AND PERFUME MATERIALS

139

TABLE 14B.-Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer, 1964 --Continued

Manufacturers ' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued

Benzenoid and I^aphthalenoid- -Contliaied

4-,6-Dinitro-l,l,3,3,5-pentamethyllndan

Diphenylme thane

l,3-Diphenyl-2-propanone (Dibenzyl ketone)

6-Ethoxy-m-anol (Propenyl methylguaethol)

2-Ethoxynaphthalene (Ethyl p-naphthyl ether)

Ethyl anisate

Ethyl anthranilate

Ethyl benzoate

Ethyl cinnamate

Ethyl a,p-epoxy-p-niethyUiydrocinnamate

2-Ethylhexyl salicylate

Ethyl 3-phenylglycidate

Ethylvanillin

»Eugenol

Eugenol acetate

Geranyl benzoate

Hexylcinnamaldehyde

Ifydratropaldehyde (a-Phenylpropionaldehyde)

I^dratropaldel^rde, dimethyl acetal

Hy-drocinnamaldehyde (3-Phenylpropionaldehyde)

Iftrdroxycitronellal methyl anthranilate

2-Hydroxypropyl p-N, N-bis ( 2-hydroxypropyl) aminobenzoate

Isobutyl cinnamate

wisobutyl phenylacetate (Isobutyl a-toluate)--

»Isobutyl salicylate

*Isoeugenol

Isoeugenyl acetate

*Isopentyl salicylate (Amy! salicylate)

p-Isopropylbenzaldehyde ( Cumaldehyde )

p-Isopropylcyclohexanol

p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen aldehyde ) .

p-Isopropyl-a-methylhydrooinnamyl alcohol

Laevo carveol

*4-' -Methoxyacetophenone

2-Methoxynaphthalene (Methyl p-naphthyl ether)

4-ta-Methoxyphenyl)butanone

l-(p-Methoxyphenyl)-l-pentene-3-one

"i'-Methylacetophenone (Methyl p-tolyl ketone)

Methyl anisate

p-Methylanisole (p-Cresyl methyl ether)

«Methyl anthranilate

Methyl benzoate

a-Methylbenzyl acetate

p-Methylbenzyl acetate

*a-Methyloinnamaldehyde

Methyl cinnamate

4- Methyl-7-ethoxy coumarin

p-Methyl hydratropic aldehyde

Methyl N-methylanthranilate (Dimethyl anthranilate)

Methyl phenylacetate (Methyl a-toluate)

Methyl phenylcarbinol acetate

*Methyl salicylate (Synthetic wintergreen oil)

*a-Pentylcinnamaldehyde (a-Amylcinnamaldehyde)

Phenethyl acetate

Phenethyl alcohol

Phenethyl formate

*Phenethyl isobutyrate

Phenethyl isovalerate

Phenethyl methacrylate

*Phenethyl phenylacetate (Phenethyl a-toluate)

Phenethyl propionate

Phenethyl salicylate

2-Phenoxyethyl isobutyrate I tBK

Phenylacetaldehyde (a-Tclualdehyde) | GIV, TBK.

GIV.

TBK.

GIV.

SHL.

GIV, TBK.

ICO.

FB, PMT.

TBK.

GIV, TBK.

GIV, TBK.

FEL.

GIV, TBK.

MON, RDA.

FB, GIV, ICO, LUE, NEO, PEN, RT, SHL, TBK, UNG, VLY.

GIV.

GIV.

GIV, IFF, TBK.

GIV, IFF.

GIV, IFF.

TBK.

GIV.

SHL.

TBK.

FB, GIV, MYW, TBK.

FB, GIV, TBK.

FB, GIV, NEO, SHL, TBK, VLY.

TBK.

FB, GIV, ICO, OPC, RDA, TBK, UNG.

GIV.

GIV.

GIV, OPC, RDA.

GIV.

FB.

GIV, ICO, OPC.

GIV, TBK.

TBK.

GIV.

TBK.

ICO.

GIV, TBK.

DOW, FB, GIV, MEE, OPC, SHL, UNG.

HN.

GIV, TBK.

ICO, IFF.

FB, GIV, VLY.

FB, ICO, TBK.

GIV.

GIV.

GIV.

GIV, TBK.

VLY.

CFC, DOW, HN, MON, x.

FB, GIV, IFF, NEO, RDA, TBK, VLY.

GIV, IFF.

GIV, IFF, OPC.

IFF.

GIV, IFF, TBK.

FB, GIV.

IFF.

GIV, IFF, TBK.

IFF.

IFF, TBK.

140

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE UB. -Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

FLAVOR AND PERFUME MATERIALS, nYCLIC— Continued

Bemenoid and Naphthalenoid— Continued

Phenylacetaldehyde, dimethyl aoetal

Phenylacetaldehyde, ethylene acetal

o-Phenylanlsole (2-Methoxybiphenyl)

Phenylethyl tiglate

*3-Phenyl-l-propanol (Hydrocinnamlc alcohol)

3-Phenyl-l-propyl acetate

5-Propenyl-2-ethoxyphenol (Propenylguaethol)

M-Propenylveratrole (Isoeugenyl methyl ether)

p-Propylanisole

n-Propyl phenethyl acetal

Styrolyl acetate

l,2,3,6-Tetrahydro-2,3,5-trimethylbenzaldehyde

p-Tolualdehyde (p-Methylbenzaldehyde)

p-Tolyl acetate (p-Cresyl acetate)

p-Tolyl isobutyrate (p-Cresyl isobutyrate)

p-Tolyl phenylacetate (p-Cresyl a-toluate)

a-(Trlchloromethyl)benzyl acetate (Rosetone)

p-o,a-Trimethylphenethyl alcohol

Trimethyltetrahydrobenzylidene acetone

Vanillin

All other

Terpenoid, Heterocyclic, and Alicyclic

Allyl cyclohexyl propionate

Allyl lonone ■"

An^rris acetate

Bornyl acetate

<V-tert-Butylcyclohexanol

4-tert-Butylcyclohexyl acetate

Cadinene

Carvone (Carvol)

Caryophyllene

Cedranone

Cedrenol

Cedrol

*Cedryl acetate

»Cltral (Geranlal)

Cltral dimethyl acetal

Cltronellal

*Citronellol

*Citronellyl acetate

Cltronellyl butyrate

»Gitronellyl formate

Cltronellyl Isobutyrate

Cltronellyl oxyaoetaldehyde

Cltronellyl propionate

*Coumarin

Cyclohexadecanollde

Cyclohexylcyclohexanone

Cyclopentanone

Dihydrogeraniol

Dlhydronordicyolopentadienyl acetate

Dihydroterpinyl acetate

^Essential oils, chemically modified:

Cedarwood, terpeneless

Cltronella oil, acetone condensation product

Citronella oil, aoetylated

Clove leaf oil terpenes

Ethyl oxyhydrate

Gualacwood acetate

Hexene-2-al-l

Lavandln, acetylated

Oil clove stem, acetylated

Sassafras oil, hydrogenated

a- Furfural mercaptan

Manufacturers ' identification codes (according to list in table 22)

GIV,

TBK.

GIV.

GIV.

FB.

FB,

GIV, OPC, TBK

GIV.

ICO.

GIV,

ICO, TBK.

GIV.

GIV.

FB.

IFF.

GIV,

HN.

GIV,

IFF.

IFF.

GIV,

TBK.

GIV,

ICO, TBK.

IFF.

TBK.

MON,

SLV.

PFW.

GIV.

GIV,

IFF.

GIV,

TBK.

FEL.

IFF.

DOW,

IFF.

FB.

FB,

J-RM,

OPC.

FB,

GIV.

TBK.

GIV.

GIV,

IFF

NEO,

TBK.

GIV,

IFF

NEO,

TBK

UNG.

FB,

FEL,

GIV,

LUl,

MYW, NEO, RT, TBK, UNG

GIV.

FB,

GIV,

IFF,

TBK.

FB,

GIV,

GLD,

IFF,

NEO, OPC, TBK, VLY.

GIV,

IFF

TBK,

VLY

GIV.

FB,

GIV,

IFF,

TBK.

GIV,

IFF

TBK

IFF,

TBK

IFF.

DOW,

MON

NEO

RDA

TBK.

IFF.

GIV.

AEA

ICO

GIV

GIV

TBK

CP.

IFF

SHL

FEL

FLO

LUE

RT,

VND.

FB,

GIV,

TBK.

OPC

FEL

IFF

, UNG

FB.

GIV

RT.

FLAVOR AND PERFUME MATERIALS

141

TABLE 14B.

-Flavor and perfume materials for which U.S. production or sales were reported, identified by manufacturer, i 564 Continued

Manufactiirers ' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued Terpenoid, Heterocyclic, and Alicyclic--Continiied

*Cieraiiiol

Geranoxy acetaldehyde

«Geranyl acetate

Geranyl butyrate

»Geraiiyl formate

Geranyl isobutyrate

Geranyl isovalerate .

Geranyl phenylaoetate (Geranyl a-toluate)

2-Hexyl-2-cyolopenten-l-one

»Hydrocoumarin (3,4-DihydroeoiimRrin)

*I^droxycitronellal-

li^droxycitronellal, dimethyl acetal

4-(4-Iftrdroxy-4-methylpentyl)-3-eyclohexene-l-carboxalde hyde.

Indole

»Ionones :

a-Ionone

P-Ionone

lonone (a- and p-)

Isobomeol (Isobomyl alcohol)

*Isobomyl acetate

Isobutylquinoline

Isomenthone

Isopropylgiiinoline

Isopulegol

Is OS af role

d-Hmonene

Linalool

*Linalyl acetate

Linalyl anthranilate

Linalyl cinnamate

Linalyl isobutyrate

Linalyl propionate

»MBnthol, synthetic :

Tech

U.S.P

*Menthone

Menthyl acetate

6-Methylcoumarin

*Methylionones :

<<Methyl-a-ionone

*Methyl-P-ionone

*lfethylionone (a- and fi-)

*Methyl-Y-ionone

«Jfethyl-5-ionone

»Nerol

Nopyl acetate

Phellandrene

»Piperonal (Heliotropin)

Piperonal, sodium bisulfite complex

Piperonal terpenes

Pseudolinalyl acetate (J^cenyl acetate, principally)

»Ehodinol

Rhodinyl acetate

Rhodinyl formate

Safrole

Santalol

Santalyl acetate

FB, IFF. FEL, GIV. GIV, IFF. FB. GIV, IFF. GIV, GIV, GIV, IFF.

GIV,

MYW,

GIV,

RDA.

FB,

FMT,

GIV,

FMT.

GIV.

GIV.

RT,

FB,

DOW,

FW.

TBK.

GIV,

GIV.

GIV,

GIV,

GIV,

FB,

GIV.

GIV,

TBK.

GIV,

TBK.

TBK.

GLD,

MYW,

ICO.

GIV,

SHL.

SHL.

IFF.

FB,

GIV,

GIV.

GIV.

GIV,

GIV.

FEL, GIV, GLD, IFF, MYW, NEO, TBK, UNG, VLY.

GIV, IFF, NEO, TBK, UNG, VLY.

TBK, VLY.

TBK.

ICO, OPC, TBK.

GLD, IFF, OPC, TBK, VLY.

TBK.

IFF, MYW, TBK. NEO, TBK. LHE, MYW, TBK.

GIV, OPC, RDA, TBK, UNG. IFF. TBK.

FEL, GIV, GLD, HOF, LUE, NEO, SHL, TBK, UNG. FB, GIV, GLD, HOF, LUE, SHL, TBK, UNG.

ICO, NEO. GLD, H^W, NEO. HNW, NEO. GIV.

IFF, MYW, NEO.

LUE, MYW, TBK, UNG, VLY.

IFF, TBK, VLY. SHL, VLY.

3, SHL, TBK.

FEL, GIV, IFF, LUE, NEO, SHL, VLY. IFF.

142

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 14B —Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued

Terpenoid, Heterocyclic, and Alicyclic--CGntinue6

^Sweeteners , synthetic :

Cyclamic acid

Cyclohexanesulfamic acid

CyclohexanesuLfamic acid, calciimi salt

Cyclohexanesulfamic acid, sodium salt

Saccharin

Saccharin, calcium salt

Saccharin, sodium salt

All other

*Terpineols:

ar-Terpineol

p-Terpineol

Terpineol (a- andg-)

Terpinol hydrate (Terpin hydrate), tech

■J^Terpinyl acetate

Terpinyl propionate

Tetrahydro alloocimenol

3,5,5-Trimethylcyclohexanol

Vertofix (Acetyl cedrene, principally)

Vetivenol

wVetivenyl acetate

All other

FLAVOR AND PERFUME MATERIALS, ACYCLIC

Allyl heptanoate (Allyl enanthate)

*Allyl hexanoate (Allyl caproate)

Allyl isothiocyanate (Synthetic mustard oil)

Allyl sulfide (Diallyl sulfide)

Amyl propionate

Butyl butyrate

Butyl isovalerate

Butyrone (Di-n-propyl ketone)

Butyroyl butyl lactate

*Decanal ( Capraldehyde ) (Cio)

Diallyl disulfide

Diethyl sebacate (Ethyl sebacate)

Diethyl succinate

Diethyl trideoanedioate (Ethylene brassylate)

2,6-Dimethyl-5-hepten-l-al

3,5-Dimethyl-3-octanol

3,7-Dimetl:^l-l-octanol

3,7-Diraethyl-3-octanol

Dimethyl succinate

*Ethyl butyrate

Ethyl decanoate

Etl^rlene brassylate

Ethyl heptanoate (Ethyl enanthate)

»Ethyl hexanoate (Ethyl caproate)

Ethyl isovalerate

Ethyl laurate

Ethyl levulinate

•»Ethyl nonanoate (Ethyl pelargonate)

Ethyl octanoate (Ethyl caprylate)

»GHutamic acid, monosodium salt (Monosodium glutamate)—

Heptanal (Enanthaldehyde) (C7)

Heptyl alcohol (Heptanol)

Heptyl ether (Enanthic ether"!

cis-3-Hexen-l-ol

Hexyl octanoate (Hexyl caprylate)

cis-3-Hexyn-l-ol

3-Hydroxy-2-butanone (Acetoin)

Manufacturers' identification codes (according to list in table 22)

MRS.

ABB.

ABB, DRW, NRS, PBY, PFZ.

ABB, NRS, PBY, PFZ, UNS.

MEE, MON, NRS.

MEE, MON, NRS, PBY.

MEE, MON, NRS.

VLY.

GLD. HNW, HPC.

HNW.

GIV, NEO.

HPC.

GIV, HNW, OPC, RDA,

TBK, UNG

GIV, TBK.

IFF.

ICO.

IFF.

GIV, TBK.

GIV, IFF, NEO, TBK,

UNG.

FB, OPC, TBK.

DOW, TBK.

DOW, FB, GIV, TBK,

UNG.

ICO, MRT.

DOW, RT.

GIV.

TBK.

TBK.

TBK.

ICO.

GIV, IFF, OPC, TBK

RT.

FEL, TBK.

UCC.

RDA.

GIV.

AIR.

GIV, TBK.

GIV.

ICO.

FB, NW, RT, TBK.

TBK.

VLY.

FEL, TBK.

FB, NW, TBK.

FB, TBK.

FB.

FMT.

FB, FEL, TBK.

FB.

COM, GRW, HPC, DjIC

, MRK.

BAC.

BAC, UCC.

TBK.

FLAVOR AND PERFUME MATERIALS

143

TABLE 14B. —Flavor and perfume materials for which U.S. production or sales were reported identified by

manufacturer, 1964- - Continued

FLAVOR AND PERFUME MATERIALS, ACYCLIC— Continued

"i-Hydroxynonanoic acid, y-lactone (y-Nonalactone)

4-Hydroxyoctanoio acid, y-lactone (Y-Octalaotone)

*4-Hydroxyundecanoic acid, y-lactone (Y-Undeoalactone)-

*Isopentyl butyrate (Amyl butyrate)

Isopentyl formate (Amy! formate)

Isopentyl geranate

Isopentyl heptanoate (Amyl caproate)

Isopentyl isovalerate (Amyl isovalerate)

*Lauraldehyde (Dodeoyl aldehyde) (C12)

6-Methyl-5-hepten-2-one

Methyl isovalerate

Methyl-P-methylthiopropionate

Methyl-3-thiopropionaldehyde

2-Methylundecanal (2-Methylnonylaoetaldehyde)

IVJyristic aldehyde

Nonanal (Pelargonaldehyde) (C9)

Nonanediol monoacetate

Nonanol

Nonyl acetate

Nonynol acetate, isomeric (Tepyl acetate)

Ootanal ( Caprylaldehyde ) (Cg)

n-Ootyl acetate

n-Ootyl isobutyrate

Omega decenol

n-Propyl acetal

d-Pulegone

Tepyl acetate

2,6,10-Triinethyl-9-undecen-l-ol

Undecanal (Hendecanaldehyde) (Cn)

2-Undecanone (Methyl nonyl ketone)

Undecenal (Hendecenaldehyde)

10-Undecen-l-ol

Valerolactone

All other

Manufacturers ' identification codes (according to list in table 22)

GIV

TBK.

GVl

TBK

FB,

GIV,

TBK.

FB,

GIV,

ICO, NW, RT, TBK

FEL

TBK.

FB.

FEL

FB,

TBK.

GIV

IFF,

TBK.

GIV.

FB.

RT.

RT.

GIV,

TBK.

GIV.

GIV,

TBK.

GIV.

TBK.

TBK.

IFF.

GIV,

IFF,

OPC, TBK.

FB,

TBK.

FB,

ICO.

IFF.

GIV.

GIV.

TBK.

GIV.

GIV,

IFF,

TBK.

GIV.

GIV,

TBK.

GIV.

GIV.

GIV,

SHL.

144

SYNTHETIC ORGANIC CHEMICALS, 1964

Plastics and Resin Materials

TABLE 15B. Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer , 1964

[Plastics and resin materials for which separate statistics are given in table 15A are maxked below with an asterisk ( «) ; chemicals not so marked do not appear in table 15A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Material and use

Manufacturers ' identification codes (according to list in table 22)

THEEMOSETTING RESINS

»Alkyd resins :

Protective coatings : »Phthalic anhydride type-

*Polybasio acid type-

*A11 other uses

«Coumarone-indene and petroleum polymer resins ;

*Floor tile

*Eubber compounding

*A11 other uses

Epoxy resins :

*lftraiodif led :

■^Bonding and adheslves

^Protective coatings

*Reinforoed plastics

»A11 other uses

*MDdified

*Polyester resins :

Reinforced plastics : *Sheets, flat and corrvigated

*A11 other

»Surface coatings

*A11 other uses

^Silicone resins

*Phenolic and other tar acid resins ♦Molding materials

Bonding and adhesive resins for-- ♦Laminating

♦Coated and bonded abrasives

♦Friction materials

AAI, ACP, ACY, ADM, AMF, APV, ARD, BAL, BEN, BOY, BRU, CGL, CIK, CM, COM, CPV, DAV, DBG, DSO, DUN, DUP, EW, FAR, FBR, FCD, FLW, FOC, FRE, FSH, GEI, GIL, GLD, GRV, HAN, HPC, HRS, ICF, JAM, JOB, JOD, JWL, KEL, KMC, KMP, KPS, KYN, LON, MCC, MID, MNP, MR, NCI, NPV, NTL, ORO, OSB, PER, PFP, PPG, PRT, RCI, RED, REL, RH, RMC, SCF, SCN, SED, SIP, SPP, SRR, SVC, SW, SYV, TV, VTV, WAS, WPC.

ACP, AMF, APT, APV, ARD, BEN, CGL, CM, COM, CPV, DSO, DUN, DUP, EW, FAR, FBR, FCD, FLW, FOC, FSH, GEI, GLD, GRG, GRV, HPC, ICF, LON, MID, NCI, NON, NPV, ORO, OSB, PPG, PRT, RCI, RED, REL, RH, RMC, SHA, SPP, SRR, TV, VTV.

ACP, ACY, AMR, CIK, DUP, FAR, FLW, GLD, HPC, JSC, KPS, MCC, MMM, MOB, NOP, ORO, PPG, QCP, RCI, RH, SIP, SNW.

ACC, ACP, NEV, NSP, PAI, VEL.

ACC, ACP, NEV, NSP, PAI, VEL, WTC.

ACC, ACP, CM, DSO, DUP, ENJ, ICF, MCA, NEV, PAI, PPG, VEL, X.

CBA, DOW, JOD, SHC, UCP.

CBA, DOW, JOD, RCI, SHC, UCP.

CBA, DOW, RCI, SHC, UCP.

CBA, DOW, SHC, UCP.

ACP, AMF, BEN, DSO, FMP, GLD, HAP, ICF, ISO, KPI, KPT,

LEF, MID, MNP, MRB, NON, ORO, OSB, PPG, PYR, REZ,

RMC, SPP, SRR, WAS.

ACP, ACY, ADM, DA, EW, FRE, GLD, HKD, ICF, LAS, MFG,

ORO, PPG, RCI, RH, SW, USR. AAI, ACP, ACY, ADM, APD, CAP, CPV, DA, DSO, FRE, GLD,

GRV, HKD, ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG,

RCI, SIC, SPP, SW, USR. ACP, ACY, APD, COM, CPV, DA, GLD, GYR, ICF, PPG, SW,

USR. ACP, ACR, ACY, AMR, APD, DA, DAV, DSO, EKT, EPC, EW,

FMP, FRE, GEI, GLD, GNT, GRG, GYR, HKD, HYC, LAS, MID,

OCF, PLU, PPG, RCI, RH, SCN, SW, USR, UTR, VAL. ACP, BOR, DCC, GLD, SPD, UCS.

ACP, BOR, DUH, FRL, GE, HER, HKD, HVG, IRC, MRB, PLS, RCI, RGC, SYR, UCP, VAR, VSV.

ACP, AMR, BOR, CAT, CBR, CD, DRL, EW, FOM, GE, HKD, IRI, MCA, MON, NPI, NPP, NTC, NVF, PGU, PYZ, RCD, RCI, SCN, SPL, SYR, TAY, TKL, UCP, VAR.

BME, BOR, CAT, CBM, CBR, HKD, MMM, MON, PYZ, SYR, UCP, VAR.

ABS, BME, BOR, FRL, GE, HKD, MON, PYZ, RAB, SCN, SYR, SYV, UCP, VAR.

I

PLASTICS AND RESIN MATERIALS

145

TABLE 15B»- Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Material and use

Manufacturers' identification codes (according to list in table 22)

THERMOSETTING RESINS— Continued

»Phenolio and other tar acid resins Continued Bonding and adhesive resins for Continued ^Thermal insulation

♦Foundry or shell molding

♦Plywood

♦Fibrous and granulated wood

*A11 other bonding and adhesive uses

♦Protective coatings

♦All other uses

♦Polyurethane and diisocyanate resins

♦Rosin modifications:

♦Rosin and rosin esters, unmodified (ester gums)

♦All other

Styrene and aliyd polyesters

♦Urea and melamine resins:

♦Textile treating and coating resins

♦Paper treating and coating resins

Ifclding materials

Bonding and adhesive resins for

♦Laminating

♦Plywood

♦Fibrous and granulated wood

♦All other bonding and adhesive uses

♦Protective coatings

All other uses

All other thermosetting resins

THERMDPLASTIC RESINS

Acrylic resins-

♦Cellulose plastics materials: Sheets, continuous:

♦Under 0.003 gage

♦0.003 gage and over

♦All other sheets, rods, and tubes -

♦Molding and extrusion materials

♦Polyamide resins

ACP, AMR, CAT, GE, HKD, ICF, MON, QCF, PYZ, RCI, SYV,

UCP. ACP, ACR, ARM, BOR, GE, HKD, MON, PYZ, RCI, SCN, UCP,

UNO, VAR, WOD. ACP, AMR, BGC, BOR, CAT, CBC, CBD, DA, MON, PGU, PYZ,

RCI, RH, SIM, WCA, WRD. AMR, BOR, CBD, HKD, MCA, MON, PYZ, RCI, SIM, UCP. ACP, AMR, BME, BOR, CAT, GE, HKD, IRI, KPT, MON, MRB,

NPI, PYZ, RPC, SCN, SHA, SNC, SPP, SYR, UCP, USR,

VAR. ACP, ADM, AMF, AMR, CIK, CPV, DSO, EW, FCD, PRE, GE,

GEI, GRG, GRV, HER, HKD, ICF, INL, KRM, MD, MON,

NCI, ORO, OXR, PFP, PYZ, RCI, RH, RMC, SCN, SHA, SNC,

SW, UCP, VAR, WAS. ACP, ACR, AMR, BOR, CAT, EW, FRL, GEI, HER, HKD, IOC,

IRC, KND, MMM, MON, MRB, NPI, PLS, PYR, PYZ, RAB,

RCI, REZ, RGC, RH, SCN, SNC, UCP, USR, VAR, VSV. ACB, ADM, APV, ARK, BFG, BKL, DUP, GPM, HOU, IPI, MCC,

MID, NOP, NPV, PEL, PFP, QUN, RCI, SCN, SW, TRN, UPC.

ADM, APV, CBY, DPP, FAR, FCD, FRP, HPC, KRM, MCC, RCI,

RH, SRR. ADM, APV, CBY, CPT, DPP, FAR, FCD, FLW, FRP, HPC, JNS,

KRM, MCC, RCI, SCF, SRR. ADM, DEG, FLW, RCI.

ACY, APX, BRY, CAT, CIB, CKM, CRC, DAN, DEP, DUP, ECC, HNC, HRT, JSC, MON, MRA, ONX, PC, QCP, RCI, RH, RPC, RTX, S, SBC, SEY, SNW, SYN, TV, USO, VAL, WIC, x.

ACY, AMR, BME, BOR, CBD, CBR, DEP, DUP, HPC, MMM, MON, RCI, RH, X.

ACP, ACY, BOR, CAP, FMP, GDN, PMC.

ACY, BOR, CAT, FOM, GE, MON, NPP, NTC, PGU, PPL, SAC. ACY, BGC, BOR, CAT, CBC, CBD, MON, NPI, NTC, PGU, RCI,

RH, SAC, SIM, SOR, WRD. ACY, BGC, BOR, IPR, MON, NTC, PGU, RCI, SAC, SOR, SYV,

UPL, WOD. ACP, ACY, AMR, BOR, GEO, MON, RCI, SWP, TXT, UNO. ACP, ACY, APV, CPV, DUP, FRP, GLD, GRV, JOD, KPS, MON,

OXR, PPG, RCI, REL, RH, SW. ACP, ACY, AMR, BOR, CMP, DUP, EFH, FMP, GEO, GGY, HPC,

HID, MMM, MON, RCI, RH, STC, SWR, VAL, VAR, WON. ACP, ACY, CEM, G, GGY, HPC, HVG, JNS, MON, SNW, SWR,

UNO, WTC, X.

AGO, ACY, CAT, CIB, CMG, DUP, FLH, GLC, GLX, HCO, JNS, JSC, PII, PPG, QUN, RCI, RH, RPC, SAR, SEY, USP, VAL, VPC, WIC.

CEL, DOW, DUP, EKT.

CEL, DOW, EKT, MON, MPP, NIX, PDJ, SPY.

CEL, MPP, NIX, PDJ, R5B, SPY.

CEL, DOW, EKT, MON, PMA, RPI, RSB.

ALF, BCM, DUP, EMR, FG, GNM, HN, JNS, KRM, POL, SNWj SPN.

146

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 15B. Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer , 1964 Continued

Material and use

Manufacturers' identification codes (according to list in table 22)

THERMOPLASTIC RESINS--Continued

*Styrene type plastics materials:

«Mblding

*Textile and paper treating and coating

♦Emulsion paint

♦Extrusion

*A11 other uses

Vinyl resins: ♦Polyvinyl acetate resins:

♦Emulsion paint

♦Adhesives

♦Bonding and sizing

♦All other uses

♦Polyvinyl chloride and copolymer resins:

♦Film, under 6 mils

♦Sheet, 6 mils and over

♦Flooring

♦Paper and textile coating

Extrusion: ♦Wire and cable

♦Garden hose

♦All other extrusions

Molding : ♦Records

♦Slush and rotational molding

♦All other moldings

♦All other uses

♦All other vinyl resins

Polyolefin plastics materials: ♦Polyethylene, density 0.940 and below:

♦Injection molding

♦Blow molding

Extrusions: ♦Film and sheet

♦Wire and cable coating

♦Extrusion coating on paper and other substrates-

BFG, BKC, BPL, CSD, DOW, FBF, FG, FIR, GOR, GRP, GYR, KPP, MON, MPL, PLA, RCC, SHC, SOL, TIC, UCP, USR, x.

BOR, DOW, FIR, FLH, GNT, GYR, ILC, KPP, MON, MET, USR, WAS, WIC.

BOR, DOW, FIR, GLD, GNT, GYR, KPP, MON, USR.

BFG, BKC, CSD, DOW, FIR, GRP, KPP, MON, PMA, RCC, UCP, USR, X.

ACC, ARD, BCN, BFG, BOR, CSD, DOW, DSO, DUP, FIR, GNT, GRD, GRP, GYR, ICG, JNS, KPP, MON, MRT, ONX, PAI, POL, PVI, RCC, RH, SEK, SHC, SPI, UBS, UCP, UNC, USR, WAS, WIC, X.

ACP, AIR, AML, APV, BAL, BEN, BOR, CEL, DAV, DSO, DUP, FAR, FLH, GLD, GRD, HAN, JOD, KMC, KMP, MCC, MR, NPV, NSC, PPG, RCI, REL, SED, SPC, SRC, SW, UCP, WAS, WIC.

ACP, AIR, BAL, BOR, CEL, DUP, FC, FLH, GLC, GRD, HNC, MRN, NSC, NTC, PII, RCI, SH, SRC, SYR, UCP, WIC.

AIR, AML, CAT, CEL, GST, DUP, GLC, GRD, PII, QCP, RFC, SEY, SRC, WIC.

AML, BAL, BLS, BOH, CEL, DAN, DUP, FC, GRD, HET, JNT, JSC, NEP, NSC, OCF, HPC, SCO, SED, SRC, UCP, WIC.

ATU, BFG, BOR, CRY, DOW, ESC, FCP, FIR, GNT, GYR, MON,

PNT, THC, UCP. ATU, BFG, BOR, CHY, DA, DOW, ESC, FCP, FIR, GNT, GYR,

MON, PNT, THC, UCP, USR. AME, BFG, BOR, CRY, CUC, DA, ESC, FCP, FIR, GNT, GYR,

KYS, MON, THC, UCP, USR. ATU, BFG, BOR, CRY, DA, DOW, ESC, FCP, MON, ONX, PNT,

UCP, USR.

BFG, BOR, CRY, DA, DOW, ESC, FIR, MON, PNT, THC, UCP,

USR. ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, MON, THC. BFG, BOR, CRY, DA, DOW, ESC, FCP, FIR, GNT, GYR, LAS,

MON, THC, UCP, USR.

BFG, BOR, CRY, CUC, DA, ESC, KYS, MON, PNT, THC, UCP,

USR.

BFG, BOR, CRY, DA, ESC, FIR, MON, UCP, USR.

ATU, BFG, BOR, CRY, DA, DOW, ESC, GYR, MON, UCP.

ATU, BFG, BOR, CBR, CRY, CUC, DA, DOW, ESC, FCP, FIR,

GNT, GRA, GYR, MON, PNT, PYR, UCP, USR.

ADM, AIR, BOR, BOY, DOW, DSO, DUP, FC, G, JOD, MCC,

NSC, SNW, SRC, SW, UCP.

CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC,

SPN, UCP, USI. CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN,

UCP, USI.

CEL, DOW, DUP, EKX, ENJ, GRP, KPP, MON, PLC, RCC, SHC,

SPN, UCP, USI, X. CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, SHC, SPN, UCP,

USI. CEL, DOW, DUP, EKX, GRP, KPP, MON, PLC, RCC, SHC, SPN,

UCP, USI.

PLASTICS AND RESIN MATERIALS

147

TABLE 15B. Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer, ^964 Continued

Material and use

Manufacturers' identification codes (according to list in table 22)

THERMOPLASTIC RESINS— Continued

Polyolefin plastics materials Continued ^Polyethylene, density 0.94-0 and below Continued Extrusions Continued »Plpe

*A11 other extrusions

*A11 other uses

*Polyethylene, density over 0.940:

*Injeotion molding

»Blow molding

Extrusions: *Film and sheet

*Wire and cable coating

*Pipe

*A11 other extrusions

*A11 other uses

^Polypropylene :

^Molding

^Extrusion

*A11 other uses

All other thermoplastic resins

CEL, DOW, DUP, EKX, GRP, KPP,

USI. DOW, DUP, EKX, GRP, KPP, PLC, ACP, CEL, DOW, DUP, EKX, ENJ,

SHC, SPN, UCP, USI.

CEL, DOW, DUP, EKX, GRP, HPC,

USI. CEL, DOW, DUP, EKX, GGC, GRP,

UCP, USI.

CEL, DOW, DUP, EKX, GGC, GRP,

USI.

CEL, DUP, EKX, GGC, GRP, HPC,

ACP, CEL, DUP, EKX, GGC, GRP,

CEL, DOW, DUP, EKX, GGC, GRP,

USI.

ACP, CEL, DOW, DUP, EKX, GGC,

RCC, UCP, USI.

AVS, DOW, EKX, ENJ, GRP, HPC, SPN, UCP, USI.

AVS, EKX, ENJ, GRP, HPC, ORO,

AVS, DOW, EKX, ENJ, GRP, HPC, USI, X.

ACG, AGO, ACP, ACY, CAT, CBY, FLH, GE, GLC, GLX, HCO, JNS, PAI, PII, PPG, QUN, RCI, RH, SNW, USP, VAL, VPC, WIC.

UCP. GRP,

KPP, HPC,

PLC, SHC, SPN, UCP,

KPP, MON, PLC, RCC,

PLC, RCC, SHC, UCP,

KPP, MON, PLC, SHC,

HPC, KPP, PLC, SHC, UCP,

PLC,

UCP,

USI.

HPC,

KPP,

PLC,

SHC,

UCP.

HPC,

KPP,

PLC,

SHC,

UCP,

GRP,

HPC,

KPP,

MON,

PLC,

NVT,

ORO,

PLC,

RCC,

SHC,

PLC,

SHC,

UCP,

USI,

X.

ORO,

PLC,

RCC,

SHC,

UCP,

CIB,

CMG,

DEP,

DUP,

ECC,

JSC

, KRK

MCC

, MMM

, MOB

RFC

, SAR

SBC

, SCN

SEZ

148

SYNTHETIC ORGANIC CHEMICALS, 1964

Rubber- Processing Chemicals

TABLE 16B. Rubber-processing chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964

Rubber-processing chendoals for which separate statistics are given in table 16A are marked below with an asterisk (*); chendoals not so marlr.d io not appear in table 16A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Chemical

Manufacturers ' identification codes (according to list in table 22)

RUBBER-PROCESSING CHMECALS, CYCLIC

^Accelerators : «Aldehyde- amines :

Acetaldehyde-aniline

n-Butyraldehyde-aniline

Butyraldehyde-butylidene-aniline

<i,4'-Dithiodimorpholine

a-Ethyl-P-propylacrylanilide

Heptaldehyde- aniline

Triethyltrime thy lenetri amine

p-Benzoquinone dioxime

Dibenzoyl-p-quinonedioxime

Dibenzylamine

Di-N-pentamethylenethiuram tetrasulfide

*Dithiocarbamlc acid derivatives :

Dibenzyldithiocarbamio acid, sodium salt

Dibenzyldithiooarbamio acid, zinc salt

Dibutyldithiooarbamic acid, N, N-dimethylcyclohexyl- amine salt.

Dibutyldithiocarbamlo acid, diphenylguanidine salt

Dimethylethylene diphenyldithiooarbamic acid, lead salt

2,'i-Dinitrophenyl dlmethyldithiocarbamate

Piperidinecarbodithioie acid, piperidinium-potassium salts . Guanidines :

Dicatechol borate, di-o-tolylguanidine salt

Diphenylguanidine

Diphenylguanidine phthalate

Di-o-tolylguanidine

1,2,3-Triphenylguanidine

2-Imidazoline-2-thlol

Poly-p-dinitrosobenzene

»Thiazole derivatives :

2-Benzothiazyl N, N-diethylthiooarbamoyl sulfide

l,3-Bis(2-benzothiazolylmercaptomethyl)urea

N-tert-Butyl-2-benzothiazolesulfenamide

*N-Cyclohexyl-2-benzothiazolesulfenamide

N, N-Diisopropyl-2-benzothiazolesulfenamlde

N-(2,6-Dimethylmorpholino)-2-benzothiazolesulfenamide

*2,2'-Dithiobis(benzothiazole)

*2-Msrcaptobenzothiazole

2-lfcrcaptobenzothiazole, sodium salt

2-lfercaptobenzothiazole, zinc chloride

2-Meroaptobenzothiazole, zinc salt

4-te)rpholinyl-2-benzothiazyl disulfide

N-Oxydiethylene-2-benzothiazolesulfenamide

Thiazoline-2-thiol

All other cyclic accelerators

Antioxidants :

Aldehyde- and acetone-amines:

Acetaldehyde-aniline hydrochloride

Aldol-a-naphthylamine condensate

Diphenylamine-aoetone

Hienyl-2-naphthylamine-aoetone

USE.

DUP,

USR.

MON.

MON.

ceo.

USR.

USR.

CTA,

DUP.

OTA,

USR.

MLS,

USR.

DUP,

TOC.

USR.

USR.

MON.

ceo.

COO.

USR.

DUP.

DUP.

ACY.

MON.

ACY,

DUP.

NAC.

DUP,

RBC.

DUP.

PAS.

MON.

MON.

ACY,

BFG,

MON,

USR.

ACY.

MON.

ACY,

BFG,

GYR,

MON, USR

ACY,

BFG,

GYR,

MON, USR

ACY,

GYR,

MON.

DUP.

ACY,

GYR,

USR.

GYR.

ACY,

MON.

ACY.

DUP,

VNC.

USR.

BFG,

CLY.

ACY,

BFG,

USR.

USR.

RUBBER-PROCESSING CHEMICALS

149

TABLE 16B. -- Rubber-processing chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1964 Continued

Manufacturers' identification codes (according to list in table 22)

RUBBER- PROCESSING CHEMICALS, Of CLIC— Continued

Antioxidants Continued *Amino and hydroxy compounds ; *Amino compounds :

p-Anilinophenol

N-sec-Butyl-N' -phenyl -p-phenylenediamine

N-Butyroyl-p-aminophenol

N-Qyolohexyl-N'-phenyl-p-phenylenediamine

Dlarylaiylene diamines, mixed

N, N '-Di( l-ethyl-3-methylpentyl) -p-phenylenediamine

l,2-Dihydro-6-dodeoyl-2,2,'4-trimethylquinoline

l,2-Dihydro-6-ethoxy-2,2,<»-trimetliylqulnoline

l,2-Dihydro-2,2,4-trimethylquinoline

PjP'-Diiiethoxydiphenylamine

N, N'-Di(l-me thy Iheptyl) -p-phenylenediamine

N,N'-Di-2-naphthyl-p-phenylenediamine

A, A' -Diocty Idiphenylami ne

N,N'-Di-2-octyl-p-phenylenediamine

N,N'-Diphenylethylenediamine

*N,N'-Diphenyl-p-phenylenediamine

N, N'-Diphenyl-l,3-propanediamine

N,N'-Dl-o-tolylethylenediamine

p-Isopropoxydiphenylamine

N-Isopropyl-N'-phenyl-p-phenylenediamine

4,4'-Methylenedianiline

N-(l-Methylheptyl)-N '-phenyl-p-phenylenediamine

Ootyldiphenylamine

Ootyldiphenylamine mixture (mono-, nonyl-, and di-) -

N-Hienyl-1-naphthylamine

N-Hienyl-2-naphthylamine

p-(p-Toluenesulfonamido)diphenylamine

All other amino antioxidants

*Hydroxy compounds :

p-Benzyloxyphenol

4,4'-Butylidenehis(6-tert-butyl-m-cresol)

2,5-Di(l, l-dimethylpropyl)hydroquinone

N-Lauroyl-p-aminophenol

2,2'-Methylenebis(6-tert-butyl-p-cresol)

2,2'-Methylenebis(6-tert-butyl-4--ethylphenol)

2,2'-Methylenebis(6-tert-octyl-p-cresol)

»Phenol, allsylated

Phenol, hindered

Phenol, styrenated

Polyphenolic phosphite, polyaliylated

N-Stearoyl-p-aminophenol

A, A' -Thiobis(6-tert-butyl-m-oresol)

2,2'-Thiobis(4,6-di-sec-amylphenol)

l,l,3-Tri(2-methyl-4— hydroxy-5-tert-butylphenyl)butane Blowing agents :

N,N'-Dimethyl-N, N'-dinitrosoterephthalamide

DinitroEopentamethylenetetramine

p,p' -Oxybis(benzenesuli'onhydrazide)

Inhibitors, modifiers, and stabilizers:

Alkylated o-oresol

Dioresyl disulfide

Nj't-Dinitroso-N-methylaniline

*N-Nitrosodiphenylamine

Nonylphenylphosphites, mixed

BFG.

USE.

MLS.

USE.

GYR.

EKT,

MON,

UPM.

MON.

MON.

BFG,

MON.

DUP.

EKT,

MON,

UPM.

BFG.

BFG.

BFG.

ceo.

NOP,

X.

BFG,

DUP,

USR.

ceo.

ceo.

BFG.

MON,

USR.

USR.

UPM.

ACY,

PAS,

USR.

BFG.

DUP.

BFG,

DUP.

USR.

EKT,

NOP,

X.

BFG.

M3N.

M3N.

MLS.

ACY,

CAT.

ACY.

ACY.

ACY,

BFG,

eeO, GYR, PAS,

PIT, USR

DUP,

GYR,

PIT.

BFG,

GYR.

BFG.

MLS.

MON.

MON.

ICI.

DUP.

DUP,

NPI.

USR.

PIT.

USR.

CTA,

MON.

BFG,

CTA,

GYR, USR.

USR.

150

TABLE 16B.

SYNTHETIC ORGANIC CHEMICALS, 1964

-Rubber -processing chemicals for which U.S. production or sales were reported, identified by manufacturer, i 964 --Continued

RUBBER-PROCESSING CHEMCAIS, CYCLIC— Continued

^Peptizers:

Aryl mercaptans

Z-Benzamidothlophene, zinc salt

2' 2 ' ' '-Dithlo'bis(tienzaiiilide)

Dlxylyl disulfides, mixed

2 -Naphthalene thiol

Pentachlorobenzenethiol

Pentaohlorobenzenethiol, zinc salt

Thlocresol

Thiophenol

Xylenethiol

Tackifiers: p-tert-Amylphenol sulflde-

RUBBER-PROCESSING CHHECAIS, ACYCLIC

^Accelerators :

n-Butyraldehyde-butylamlne

Di-n-butylammonium oleate

*Dithiocarhamic acid derivatives:

Dibutyldithiocarbamio acid, potassium salt

*Dibutyldithiooarhainic acid, sodium salt

■x-Dibutyldithiocarbamic acid, zinc salt

Diethyldithiocarbamic acid, cadmium salt and bis(dlethylthiocarbamoyl) disulfide mixture.

Diethyldithiocarbamic acid, selenium salt

Diethyldithiocarbamic acid, sodium salt

Diethyldithiocarbamic acid, tellurium salt

♦Diethyldithiocarbamic acid, zinc salt

Dimethyldithiocarbamic acid, bismuth salt

Dimethyldithiocarbamic acid, copper salt

Dimethyldithiocarbamic acid, lead salt

♦Dimethyldithiocarbamic acid, potassium salt

Dimethyldithiocarbamic acid, selenium salt

♦Dimethyldithiocarbamic acid, sodium salt

Dimethyldithiocarbamic acid, sodium salt and, sodium polysuLf ide .

♦Dimethyldithiocarbamic acid, zinc salt

All other

♦Thiurams :

Bis(dibutylthiocarbamoyl) sulfide

Bis(diethylthiocarbamoyl) disulfide--

♦Bis(dimethylthiocarbamoyl) disulfide

♦Bis (dime thy Ithiocarbamoyl) sulfide

BisCethylJuethylthioearbamoyl) sulfide

Thiuram blend

Xanthates and sulfides:

Di-n-butylxantho disulfide

Di-isopropylxantho disulfide

Zinc dibutylxanthate

All other acyclic accelerators:

3-Ethyl-l,l-dimethyl-2-thiourea

Ethylenediamine carbamate

Polyoxyaliylene tetrasulfide

l,l,3-Trimethyl-2-thiourea

Blowing agents:

Urea-biuret mixture

All other blowing agents

Manufacturers' identification codes (according to list in table 22)

PIT.

ACY.

ACY.

DUP, PIT.

DUP.

DUP.

DUP.

PIT.

PIT.

DUP.

PAS.

DUP. DUP.

VWG. DUP, ALC, VNC.

PAS, USR, VNC.

DUP, GYR, PAS, RBC, USR, VNC.

PAS.

GYR, RBC, USR, VNC.

VNC.

ALC,

VNC.

ALC,

VNC.

VNC.

VNC.

GYR, PAS, USR.

VNC.

ALC,

BFG,

ALC, PAS.

USR. DUP, BFG, DUP, VNC. DUP,

USR. BFG. USR.

VNC, DUP. TKL. VNC.

sw.

DUP.

BFG, DUP, GYR, PAS, USR. GNT.

DUP, FMN, GYR, PAS, RBC, USR, WRC.

GYR, PAS.

DUP, GNT, GYR, PAS, RBC, USR, VNC.

GYR, USR.

RUBBER-PROCESSING CHEMICALS

151

TABLE 16B.-

Rubber -processing chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

RUBBER- PROCESSING CHMICALS, ACYCLIC- -Continued

Conditioning and lubricating agents :

Ifethyl stearyl-10-sulfonio acid, sodium salt

ttono- and diaUsyl acid phosphates, mixed

Ifono- and dialkyl phosphate ammonium salts, mixed

Peptizers and modifiers :

Alkyl mercaptans, mixed

»Dodecyl mercaptans

Tetradecyl mercaptan

Zinc laurate

All other

DUP. DUP. DUP.

PAS, PLC.

HK, PAS, PLC.

PAS.

USE.

ACY, TKL, USR.

152

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 17B.

Elastomers (Synthetic Rubbers)

-Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by manufacturer, 1964

[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- terisk (*); products not so marked do not appear in table 17A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Product

Manufacturers ' identification codes (according to list in table 22)

ELASTOMEES, CYCLIC

ASY, BFG, CPY, FIR, FHS, GGC, GNT, GYR, ILC, MCB,

PLC, RUB, SEP, SHC, TOS, URC, USR, WIG. BFG, FIR, FRS, GNT, GYR, PLC, USR. ACY, BFG, DUP, GNT, MDB, ORU, PRC, TKL, USR.

ELASTOMERS, ACYCLIC

»Polybutadiene-aorylonitrile type (N-type)

BFG, FRS, GYR, ILC, USR, WIC.

DUP.

CBN, EN J.

GYR, HPC.

DCC, SPD, UCS.

ASY, DUP, ENJ, FRS, GGC, GNT, GYR, PLC, SHC, TUS.

DUP, ENJ, X.

Reaction products of natural rubber

^-Silicone elastomers

PLASTICIZERS

153

Plasticizers

TABLE 18B.— Plasticizers for which U.S. production or sales were reported, identified by

manufacturer, 1964

[Plasticizers for which separate statistics are given in table ISA are marked below with an asterisk (»); products not so marked do not appear in table 18A because the reported data are accepted in confidence and may not be pub- lished. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manu- facturer did not consent to his identification with the designated product]

PLASTICIZEHS, CYCLIC

Coumarone-indene plasticizer

N-Cyclohexyl-p-toluenesulfonamide--

Diethylene glycol dibenzoate

Di-tert-octylphenyl ether

Diphenyl cyclohexane, o-, m-, p- --

Dipropanediol dibenzoate

N-Ethyl-p-toluenesulfonamide

Isopropylidenediphenoxypropanol

Naphthalene, alkylated

Phosphoric acid esters:

*Cresyl diphenyl phosphate

Dibutyl phenyl phosphate

Diphenyl mono-o-xenyl phosphate

Diphenyl octyl phosphate

tfethyl diphenyl phosphate

*Tricresyl phosphate

*Triphenyl phosphate

All other phosphoric acid esters- »Phthallc anhydride esters:

Alkyl benzyl phthalates

Butyl benzyl phthalate

Butyl cyclohexyl phthalate

Butyl deoyl phthalate

Butyl 2-ethyl hexyl phthalate

n-Butyl isodecyl phthalate

»Batyl octyl phthalate

Butyl phthalyl butyl glycolate

Di(2-butoxyethyl) phthalate

*Dibutyl phthalate

Dioarbitol phthalate

*Dlcyolohexyl phthalate

Diethylene glycol phthalate- *Diethyl phthalate

*Dlhexyl phthalate

Diisobutyl phthalate

*Diisodeoyl phthalate

*Di(2-methoxyethyl) phthalate-- Dimethyl cyclohexyl phthalate-

Dimethyl Isophthalate

*Dlmethyl phthalate

Dinonyl phthalate

*Dioctyl phthalates:

Dioapryl phthalate

Di ( ethylhexyl ) Isophthalate - - »Di(2-ethylhexyl) phthalate—

*Diiso-octyl and mixed dioctyl phthalates-

Manuf acturers ' identification codes (according to list in table 22)

Di-n-ootyl phthalate

All other dioctyl phthalates

Diphenyl isophthalate

Diphenyl phthalate

*Ditridecyl phthalate

2-(Ethyl hexyl) isodecyl phthalate

Ethyl (and methyl) phthalyl ethyl glycolate

Glycol phthalate fatty acid esters

Glycol phthalic esters

Hexyl isodecyl phthalate

Hexyl Iso-octyl phthalate

Hydrogenated castor oil phthalate I DUP,

Octyl deoyl fatty acid phthalates | PFZ.

NEV. MON. TNP. DOW. MON. TNP. MON. DOW. ACC.

CEL, FMP, MON, MTR, SF, SPP.

MON.

DOW.

MON.

FMP, MON.

CEL, FMP,. FRO, MON, MTR, SF.

CEL, DOW, EK, MON, SF.

SF.

MON.

GRH, MON.

ACP.

ACP, PCC.

ACP, MON, PFZ, UCC.

GRH, PCC, THC.

GRH, PCC, RCI, RUB.

MON.

FMP, GRH, KES, WM.

ACP, AIR, COM, DUP, EKT, GED, GRH, HAL, LAS, MON, PCC,

PFZ, RCI, RUB, SW, WTH, UCC. FMP.

ACP, DUP, FMP, MON, PFZ. ARK.

DUP, EKT, KF, MON, PFZ. ACP, CCA, ENJ, GRH. EKT, MON. ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB,

THC, UCC, WTH. CEL, DUP, EKT, FMP, RCI, SF. DUP. PFZ.

ACP, EKT, FRO, KF, MON. RCI.

GRH, WTH.

UCC.

ACP, BFG, EKT, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, SH,

THC, UCC, WTH. ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB,

THC, UCC. ADM.

EKT, THC. BJL. MON.

ACP, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, THC, UCC.

UCC.

MON.

HPC.

ARG, UCC.

PFZ.

PFZ.

154

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 18B. Plasticizers for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers' Identification codes (according to list in table 22)

PLASTICIZERS, CYCLIC— Continued

*Phthalic anhydride esters Continued *Octyl deoyl phthalates:

Iso-octyl isodecyl phthalate

n-Octyl n-decyl phthalate

All other phthalic anhydride esters

Polyethylene glycol dibenzoate

Tetrahydrofurfuryl oleate

Toluenesulfonamide, o-, p- mixtures

Triethylene glycol dibenzoate

»Trimellitic acid esters

All other cyclic plasticizers

PLASTICIZERS, ACYCLIC

»Adipio acid esters:

*Di(2-(2-butoxyethoxy)ethyl) adipate

*Di(2-et±iylhexyl) adipate

»Dlisobutyl adipate

*Diisodeoyl adipate

*Diiso-octyl adipate

Iso-octyl isodecyl adipate

*Octyl decyl adipate

All other adipic acid esters

*Azelaic acid esters:

Di(2-ethylhexyl) azelate

Dllsobutyl azelate

Diiso-octyl azelate

All other azelaic acid esters

Citric and acetylcitrio acid esters

«Complex linear polyesters and polymeric plasticizers-

Di(2-(2-buto}(yethoxy)ethyl)me thane

Diethylene glycol dinonanoate

Diiso-octyl diglycolate

*Epoxidized esters:

Butyl epoxytallate

*Epoxidized soya oils

2-Ethylhexyl epoxytallates

Ootyl epoxystearates

*Octyl epoxytallates

All other epoxidized esters

Glycerol pelargonate

Glyceryl tributyrate and tripropionate

Glycol pelargonate

Isodecyl nonanoate (Isodecyl pelargonate)

Laurie acid esters

J/(yristic acid esters:

Butyl myristate

*Isopropyl myristate

*01eic acid esters:

*Butyl oleate

*Glycerol trioleate (triolein)

*Isopropyl oleate

»Methyl oleate

»n- Propyl oleate

*A11 other oleic acid esters

Palmitic acid esters:

*Isopropyl palmitate

All other palmitic acid esters

♦Phosphoric acid esters:

Tri(2-butoxyethyl) phosphate

Triethyl phosphate

Triootyl phosphate

All other phosphoric acid esters

ACP, PCC, PFZ.

ACP, GRH, HPC, MON, PCC, PFZ, RCI, RUB, THC, UCC.

ERG, MP, PCC, PFZ, UCC.

TNP.

CCW, EMR.

ACY, MON.

TNP.

ACC, PCC, PFZ, RUB.

CCW, EKT, WTH.

CCW, EUP, GRH, PCC, TKL.

EKT, HAL, MON, PCC, PFZ, RCI, RUB, THC, UCC, WTH.

FMP, GRH, HAL, PCC, RCI, WTH.

ACP, EKT, GRH, LEH, MON, PCC, PFZ, RCI, RH, RUB, THC,

UCC.

GRH, HAL, LEH, PCC, RCI, RH, RUB.

BFG, GRH, MON, PCC, RCI.

ACP, GRH, LEH, PCC, RCI, RUB, THC, TKL, UCC.

ACP, EKX, KES, LEH, PCC, PFZ, THC.

DUP, EKT, EMR, PFZ, RCI, RUB, UCC.

HAL, RCI.

EMR, MON.

ACP, EMR, PFZ.

ADM, EKT, WM, WTC GRD.

EMR, RUB.

CCA, FMP.

LEH, PFZ, UCC.

EMR, GLY, HAL, HPC, LEH, MON, PFZ, EH, RUB,

ADM.

ADM, ARG, ADM, UCC. ARG.

ARG, CCW, ADM, BAC, EMR. EKT. EMR.

EMR, LEH. HAL.

ICI, KES. DRW, EMR,

CCW, RCI, EH, SWT, THC, UCC.

RH, THC, UCC.

EMR, RCI, RH, SWT, THC.

ICI, KES, NOP, PCS, PEP.

CIN, DRW,

HAL, EMR,

ICI, SWT,

KES, WM.

LAS,

NOP,

RUB,

SWT,

WM,

WTH.

CRT,

ICI,

KES,

WM.

EMR,

ICI,

NOP,

SWT.

CHL,

EMR,

WM.

HAL,

ICI,

KES,

RH.

DRW,

EMR,

ICI,

KES,

PRP,

WM.

DRW,

EKT,

KES,

RUB.

FMP.

EKT.

UCC.

VC.

PLASTICIZERS

155

TABLE ISB.—Plasticizers for which U.S. production or sales were reported, identified by manufacturer, i 56^ --Continued

PLASTICIZEES, ACYCLIC— Continued

Polyethylene glycol di-2-ethylhexanoate

Rlclnolelo and acetylriclnoleio aoid esters:

^Glycerol monoricinoleate

All other rlolnolelc and aoetylricinoleio aoid esters- Sebaoio aoid esters:

*Di butyl sebacate

*Di(2-ethylhexyl) sebacate

All other sebaoic acid esters

^Stearic aoid esters:

*n- Butyl stearate

All other stearic aoid esters

Sucrose acetate isobutyrate

Triethylene glycol di(eaprylate-caprate)

Triethylene glycol di-2-ethylbutyrate

All other acyclic plastioizers

Manufacturers' identification codes (according to list in table 22)

BAG, GLY, HAL, NOP.

BAG, KES, RCI, WTH.

£KT, GRH, HAL, PFZ, RCI, RH, WTH.

GRD, GRH, HAL, PCC, PFZ, RCI, RH, RUB, WIH.

KES, LEH, NOP, PCC, RCI, RH, RUB.

EMR, HAL, IGI, KES, LAS, RUB, SCP, SWT, WTH.

BAG, CHL, DRW, IMP, HK, HPC, IGI, ICO, KES, RCI, EH,

WM. EKT.

DRW, FOR, HAL, RUB. UCC.

DRW, EKT, EKX, EMR, HAL, IGI, JNS, KES, LEH, PFZ, EH,

RUB, TKL, UCC, x.

156

SYNTHETIC ORGANIC CHEMICALS, 1964

Surface-Active Agents

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1964

[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (»); products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers ' identification codes

Chemical

(according to list in table 22)

BENZENOID SUHFACE-ACTIVE AGENTS

Not Sulfated or Sulfonated

*Amides, amines, and quaternary ammonium salts:

*Benzyl( coconut oil alkyl) dimethylamTnonium chloride

BC,

CRT, FIN, TXT.

*Benzyldimethyl( mixed aliyl) ammonium chloride

BC,

CUL, FIN, ONX, PCS, RH, TXT, VAC.

»Benzyldimethylootadecylammonium chloride

ONX,

PCS, RET, WSN.

*Benzyldodecyldimethylaramonium chloride

DEP,

ONX, SDH, WSN.

*(3,4-Diohlorobenzyl)dodecyldimethylammonium chloride

ONX,

VAC, WSN.

«(Dodecylbenzyl)trimethylaramonium chloride

BC,

CUL, ROD, VIS, WSN, WTC.

^Heterocyclic compounds:

l-Benzyl-2-( coconut oil aliyl) -l-(2-hydroxyethyl) -2-

NLC.

imidazolinlum chloride.

l-Benzyl-2-heptadecyl-l-( 2-hydroxyethyl) -2-imidazo-

PCS,

uvc.

linium chloride.

l-Benzyl-l-(2-hydroxyethyl)-2-(tall oil alkyl)-2-

NLC.

imidazolinium chloride.

l-Benzyl-3-methyl-2-undecylimidazoliuin bromide

LIL.

l-Benzyl-2-picolinium bromide

FIN.

2-Dodecylisoquinolinium bromide

ONX.

l-Dodeoylpyridinium chloride

BC,

HK.

2-(2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium

WTC.

chloride .

l-Kfethyl-2-( 2-stearoyloxyethyl) carbamoylpyridinium

WTC.

chloride .

«Oxygen-containing compounds:

Benzylbis (2-hydroxyethyl) (2 -stearamidomethoxyethyl) -

CIB.

ammonium chloride.

Benzyl( oocoamido ethyl)dimethylamraonium chloride

TXT.

Benzyl( coconut oil alkyl)bis(2-hydroxyethyl) ammonium

CIB.

chloride .

Benzyl( ethoxylated coconut oil alkyl) dimethylammonium

G.

chloride .

( Ethoxybenzyl)dimethyl(octylphenoxy) ammonium ohloride--

RH.

(Ethoxybenzyl)dimethyl(octyltolyloxy) ammonium chloride-

RH.

APX.

rj- ^ ^— nyaroxyeTinyx^ Xj.c— uipneny-Le itjiy^eiiecxriiiu xie

(Tridecylbenzyl)diethyl( 2-hydroxyethyl) ammonium

ORO.

chloride .

»A11 other:

Benzyldimethyltetradecylammonium chloride

SNW,

WSN.

Benzylhexadecyldlmethylammonium chloride

FIN,

ONX, RH, SDW.

Benzyl(hydrogenated tallow aliyl) dimethylammonium

ARC,

GNM, ONX, PCS.

chloride .

Benzyltrimethylammonium chloride

COM.

(Dodecylbenzyl)dimethyloctadecylammonium chloride

AML.

(Dodecylbenzyl)triethylammonium chloride

PC.

( Dodecy Imethylbenzyl) trimethylammonium chloride

RH.

(Ethylbenzyl)dimethyl(mixed aliyl) ammonium chloride

ONX.

*Carboxylio acid esters and ethers:

*Dodecylphenol, ethoxylated

G, MON, PCS, UCC.

APX,

CIB, DRW, NOP, OMC.

*iso— oc^yxpnenox, exnoxyxaxeo

APD, CIB, DOW, DRW, G, HPC, JCC, MON, OMC, PCS, RTF, STP, UCC, VIS.

RH

,

»Phenol, ethoxylated

APD,

CLY, G, JCC, NOP, UCC.

SURFACE-ACTIVE AGENTS

157

TABLE 19B.

--Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, i564--Continued

Manufacturers' identification codes (according to list in table 22)

BENZENOID SUHFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated— Continued

*Carboxyllo acid esters and ethers Continued *Other oarboxylic acid esters and ethers: Aliylphenol - formaldehyde, alioxylated :

(Mixed alkyl)phenol - formaldehyde, aUtoxylated

Nonylphenol - formaldehyde, alkoxylated

t-Ootylphenol - formaldehyde, ethoxylated

Pentylphenol - formaldehyde, alioxylated

Diisobutylphenol, ethoxylated

Dinonylphenol, ethoxylated

(Mixed aliyl) phenol, ethoxylated

(Mixed aliyl) phenol, ethoxylated, butyl ether

Nonylphenoxypoly ( ethyleneoxy) ethyl iodide

n-Octylphenol, ethoxylated

Phthalic acid, octadeoyl ester, potassium salt

Tetradeoylphenol, ethoxylated

Tridecylphenol, ethoxylated

Xylenol, ethoxylated

All other

*Phosphoric and polyphosphoric acid esters and salts: »Nonyl- and dinonylphenol, ethoxylated and phosphated:

Dinonylphenol, ethoxylated and phosphated

Nonylphenol, ethoxylated and phosphated

Nonylphenol, ethoxylated and phosphated, barixjm salt- Other phosphoric and polyphosphoric acid esters and salts:

Dodeoylphenol, ethoxylated and phosphated

Octylphenol, ethoxylated and phosphated, magnesium

salt. Phenol, ethoxylated and phosphated

Sulfated and Sulfonated

*Alkylphenols, ethoxylated and sulfated:

Dodecylphenol, ethoxylated and sulfated

(Mixed aliyl) phenol, ethoxylated and sulfated

*Nonylphenol, ethoxylated and sulfated

Nonylphenol, ethoxylated and sulfated, ammonium salt Nonylphenol, ethoxylated and sulfated, triethanolamlne salt.

n-Ootylphenol, ethoxylated and sulfated

»Benzenesulf onates :

Benzene-, toluene-, and xylenesulf onates :

Benzenesulfonio acid, sodium salt

2,4--Dinitrobenzenesulfom.c acid, sodium salt

Ethylene glycol dibenzenesulfonate

p-Toluenesulfonio acid, hexadecyltrimethylammonium salt.

Toluenesulfonio acid, potassium salt

»Toluenesulfonlc acid, sodium salt

»}iylenesulfonio acid, ammonium salt

*Xylenesulfonic acid, potassium salt

^Xylenesulfonic acid, sodium salt

^Branched chain dodecyl- and trideoylbenzenesulf onates : *Dodecylbenzenesulfonic acid

RTF, VIS.

RTF.

SDW.

RTF.

0, BE.

a, JCC, STP.

G, PCS, STP.

RH.

G.

ICI.

CIB.

ORO.

PCS.

VIS.

RH.

CIN, G, RZL, SEY, TCC, TXT, UVC, WAY, WTC.

TCI. SMC.

G, LEV, STP.

G.

CRT, G, OMC, STP, TXT, WTC.

CIB, MYW.

NES, UPF. NES. NES. FIN.

MYW, NES, RCD, STP, WTC.

CO, NES, PIL, RCD, STP, WTC.

CO, NES, RCD, STP, WTC.

MYW, NES, STP, WTC.

ATR, CO, MYW, NES, PIL, RCD, STP, WTC.

ARD, CIN, CO, CRT, HU, LEV, MON, MYW, NAC, PCI, PIL, PRX, RCD, SEY, STP, TCI, TDC, TN, TXT, WON, WTC.

158

TABLE 19B.

SYNTHETIC ORGANIC CHEMICALS, 1964

- Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers ' identification codes

Chemical

(according to list in table 22)

BENZENOID SURFACE -ACTIVE AGENTS —Continued

Sulfated and Sui/ona terf—Contlnued

»Benzenesulf onates —Continued

*Branohed chain dodeoyl- and trideoylbenzenesulfonates--

Continued

*Dodecylbenzenesu3-fonic acid, ammonium salt

ARL,

CTL, MYW, PRX, RCD, TXT.

*Dodecylbenzenesulfonic acid, calcium salt

APD,

RCD, RH, SMD, STP, VIS, WTC.

»Dodecylbenzenesulfonic acid, diethanolamine salt

PCS,

VAL, WON.

*Dodecylbenzenesulfonic acid, isopropylamine salt

APD,

ARD, CIN, CTL, RCD, SNW, STP, WTC.

»Dodecylbenzeuesulfonic acid, (mixed aliyl) amine salt

PCS,

STP, TXT, WTC.

*Dodeoylbenzenesulfonic acid, sodium salt

AAC,

ARD, ARL, ATR, CO, CP, CTL, DEP, EFH, EMK, HLI,

HRT, ICI, LEV, MON, NAC, NOP, PCI, PG, PIL, PfiX,

RCD, SEY, SIP, SWT, TN, TXT, VAL, WIC, WTC.

^Dodecylbenzenesulfonio acid,' triethanolamine salt

ML,

APX, ARD, ARL, ATR, CIN, CO, CTL, HLI, NAC, PCS,

PEK, PIL, RCD, RZL, SOS, STP, SWT, TXT, VAC, WTC.

*Tridecylbenzenesulfonlc acid, sodium salt

BLA,

CO, CP, PRX, RCD, TXT, WTC.

*Other branched chain dodecyl- and tridecylbenzene-

sulf onates:

Dodecylbenzenesulfonic acid, butylamine salt

WTC.

Dodecylbenzenesulfonic acid, diethanolamine

MAH.

condensate, fatty acid monoester.

Dodecylbenzenesulfonic acid, ethylenediamine salt

APD.

Dodecylbenzenesulfonic acid, isopropanolamine salt

SMC,

WON.

Dodecylbenzenesulfonic acid, potassium salt

VAL.

Dodecylbenzenesulfonic acid, propoxylated ethylene -

PCS.

diamine salt.

Tridecylbenzenesulfonic acid, ammonium salt

PRX,

TXT.

Straight chain dodecyl- and tridecylbenzenesulf onates :

*Dodecylbenzenesuli'onic acid

ARD,

HLI, LEV, MON, NAC, PIL, RCD, RZL, TCI.

»Dodecylbenzenesuli'onic acid, sodium salt

ATR,

CP, LEV, MON, PG, PIL, PRX, RCD, UNP.

■"■Dodecylbenzenesulfonic acid, triethanolamine salt

ATR,

RZL, TXT.

Tridecylbenzenesulfonic acid, sodium salt

CP,

NAC.

Other benzenesulf onates :

MON.

uecyiDenzenesun onic acj.a, soaium fadxu

CO.

uiuOaecyiDenzenesuii onic acia

Nonylbenzenesulfonic acid, sodium salt

WTC.

Pentadecylbenzenesulfonic acid, sodium salt

CP.

Pentylbenzenesulf onic acid, sodium salt

MON.

All other

SWT.

■flignosulf onates ;

lignosulfonic acid, aluminum salt

MAR.

lignosulfonic acid, ammonium salt

CRZ.

^lignosulfonic acid, calcium salt

CRZ,

CWP, INP, LKY, LPC, MAR, PSP.

Lignosulfonic acid, chromium salt

MAR.

Lignosulfonic acid, iron salt

CRZ.

Lignosulfonic acid, magnesium salt

LPC,

MAR.

Lignosulfonic acid, sodium salt

CRZ,

CWP, INP, MAR, WVA.

■"■Naphthalenesulf onates :

G.

Deniyjjidpiiijiiciienebujj. uiu-c city j.q

Butylnaphthalenesulfonic acid

SCP.

Butylnaphthalenesulfonic acid, sodium salt

CLD,

CMG, GGY, PFZ.

Di butylnaphthalenesulfonic acid

G, MRA, S.

Didodecylnaphthalenesulfonic acid, sodium salt

PFZ.

*Diisopropylnaphthalenesulf onic acid

DUP,

G, GRD.

DiisopropylnaphthalenesulTonic acid, sodium salt

G, PFZ.

Dipentylnaphthalenesulf onic acid

GGY.

DipentyLnaphthalenesulfonic acid, ammonium salt

VIS.

»IsopropylnaphthalenesuLfonic acid

DUP,

NAC, NOP, ONX.

SURFACE-ACTIVE AGENTS

159

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers' identification codes (according to list in table 22)

BENZENOID SUHFACE-ACTIVE AGENTS— Continued

Sulfated and Sulfonated- -ContimieA

^Naphthalene sulfonates Continued

Methylenebis(2-naphthalenesulf onic acid)

6,6'-Methylene'bis(2-naphthalenesulfonic acid), calcium salt.

Methylnaphthalenesulfonlc acid, sodium salt

Methylnonylnaphthalenesulfonlo acid, sodium salt

Tetrahydronaphthalenesulfonlc acid, sodium salt

ifOther benzenoid surface-active agents:

Butylhydroxyblphenylsulfonlc acid

Dodecyldiphenyloxidedlsulfonlc acid, sodium salt

Heptadecylmethylbenzlmidazollnesulf onlc acid, sodium salt

n-Octylphenol, ethoxylated and sulfonated

Petroleumsulfoulc acid, water soluble (acid layer),

sodium salt. Trlchlorophenol sulfate, ethanolamlne salt

NONBENZENOID SURFACE-ACTIVE AGENTS

Not Sulfated or Sulfonated

^Amides, amines, and quaternary ammonium salts: *Acycllc quaternary ammonium salts:

*Bis ( hydrogenated tallow aliyl) dime thy lammonium

chloride . *Hexadecyltrimethylammonium salts :

Hexadecyltrimethylammonium bromide

Hexadecyltrimethylammonlum chloride

Hexadecyltrimethylammonium stearate

mother acyclic quaternary ammonium salts: Alkylethyldimethylammonium salts ;

Ethyldlmethyl(9-octadeoenyl) ammonium bromide

Ethyldimethyl( soybean oil alkyl) ammonium bromide

Ethylhexadecyldlmethylammonlum bromide

Aliyltrimethylammonlum salts:

(Coconut oil alkyl) trlmethylammonium chloride

Dodecyltrimethylammonlum bromide

Dodecyltrimethylammonium chloride

(Hydrogenated tallow alley 1) trlmethylammonium chloride .

Trlmethyl( mixed aliyl) ammonium chloride

Trlmethyloctadecylammonlum chloride

Trlmethyl( soybean oil aliyl) ammonium chloride

Trlmethyl( tallow alkyl) ammonium chloride

Trimethyl(tetradecyl) ammonium bromide

Dialiyldlmethylammonium salts:

Bls( coconut oil alkyl) dimethylammonium chloride

Dldodecyldimethylammonium bromide

Dimethyldioctadecylammonliim chloride

Oxygen-containing compounds:

( Carboxyraethyl) ( coconut oil amldopropyl) dimethyl- ammonium chloride, sodium salt,

(Coconut oil alkyl) betalne

(Coconut oil alkyl) bis(2-hydroxyethyl, ethoxy- lated) methylammonium chloride. Deeylbetalne

DUP. DUP.

UDI. UDI. DUP.

ICO, RBC.

DOW.

CIB.

RH.

SIN, SON.

G.

ADM, ARC, FOR, GNM, VAC.

DUP,

FIN, ICI

ARC,

WSN.

FIN.

ONX.

BC.

FIN.

ARC,

GNM.

DUP.

ARC.

ARC.

GNM.

ARC.

ARC.

ARC,

GNM.

FIN.

ARC,

GNM.

ONX.

PG.

JRG.

CUL.

ABC,

VAC.

160

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, iSSi— Continued

Manufacturers ' identification codes (according to list in table 22)

NONBENZENOID SURFACE-ACnVE AGENTS— Continued Not Sulfated or Sulfonated— Continuea

♦Amides, amines, and quaternary ammonium salts Continued *Acyclio quaternary ammonliim salts Continued

*Other acyclic quaternary ammonium salts Continued Oxygen-containing compounds Continued

Hexadeoylbetaine

( 2-Hydroxyethyl) dimethyl( stearamidopropyl) -

ammonium dihydrogen phosphate. ( 2-Hydroxyethyl) dimethyl( stearamidopropyl) -

ammonium nitrate. 2-Hydroxy-l,3-propylenebis [(coconut oil allqrl)- dlmethylaramonium chloride] .

Mixed fatty betaines

Octadecylbetalne

Trlethyloctadecyloxymethylammonium chloride

Trlaliylmethylammonium salts:

Methyltrioctylammonium chloride

lfethyltrls(mixed alkyl) ammonium chloride

*Amine acetates;

(Coconut oil alkyl)amine acetate

(Coconut oil alkyl) amine, ethoxylated, acetate

*(Hydrogenated tallow aUtyl) ami ne acetate

(9-Octadecenyl) amine acetate

Octadecylamine acetate

Octylamine acetate

(Tallow alkyl) amine acetate

N-( Tallow alkyl) diethanolamine acetate

*Amine salts, anionic:

Oleic acid, diethylamine salt

»01eic acid, triethanolamine salt

Rosin acids, triethanolamine salt

Stearic acid, N,N,N ',N'-tetrakis(2-hydroxyethyl)ethyl- enediamlne salt.

Stearic acid, triethanolamine salt

All other

»Amlnes , alioxylated :

N,N-Bis(2-hydroxyethyl)dodecylamine

N,N-Bis(2-hydroxyethyl) octadecylamine

N,N-Bis(2-hydroxyethyl) -2-(stearamidomethoxy)ethyl-

amlne. N,N-Bis(2-hydroxyetbyl)-2-(stearamidomethoxy)ethyl- amlne - raelamine ether condensate.

N,N-Bls(2-hydroxyethyl) (tallow alkyl amine)

(Coconut oil alkyl) amine, ethoxylated

(Hydrogenated tallow aLkyl)amine, ethoxylated

N-( 2-Hydroxyethyl) -N,N',N'-tris( 2-hydroxypropyl)ethyl- enedlaim'ne.

»(Mixed alkyl) amine, ethoxylated

(9-Octadecenyl) amine, ethoxylated

Octadecylamine, ethoxylated

Polyethylenepolyamlne, alkoxylated

Rosin amine, ethoxylated

(Soybean oil alkyl) amine, ethoxylated

»( Tallow aliyl) amine, ethoxylated

N-( Tallow alkyl) -1,3-propylenedlamine, ethoxylated

N,N,N',N'-TetraJils(2-hydroxyethyl)ethylenediamine

DUP.

ACY.

ACY.

CIB.

TXT.

DUP.

DAK.

GNM.

ADM,

VAC.

ADM,

ARC.

RPC.

ADM,

ARC,

GIN,

WAY.

GNM.

ACY,

ARC.

ARC.

ADM,

ARC,

GNM.

PG.

WTC.

DOM,

H.U,,

NOP,

TCC.

RTF.

ICI.

AML,

TCC.

PCS.

FIN.

FIN.

CIB.

CIB.

FIN.

APD,

ARC,

VAC,

VIS.

CIB,

TCH.

VIS.

APD,

CIB,

G, NOP, RH

ARC,

PCS.

ARC,

ICI.

VIS.

HPC,

PCS,

RTF,

VIS.

ARC,

VAC.

ADM,

ARC,

CIB,

DUP..

ARC.

VIS.

SURFACE-ACTIVE AGENTS

TABLE 19B. Surface-active agents for which U.S. production or sales were reported identified by manufacturer, 1964— Continued

161

NONBENZENOID SUHFACE-ACTIVE AGENTS— Continued Not Sulfated or Sulfonated— Continued

*Amides, amines, and quaternary ammonium salts Continued *Amines, alkoxylated Continued

N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediaim.ne, propoxylated and ethoxylated.

Triethanolamine, ethoxylated

*Fatty acid - aUcanolamine condensates: *Dlethanolamine condensates :

Caprio acid - diethanolamine condensate

»Castor oil acids - diethanolamine condensate

Coconut oil acids - diethanolamine condensates: »(Amine/acid ratio = 2/1)

»(Amine/aold ratio = l/l)

All other ratios

*Lauric acid - diethanolamine condensate

linoleic acid - diethanolamine condensate

Hyrlstio acid - diethanolamine condensate

Oleic acid - diethanolamine condensates:

*(-Amlne/aoid ratio = 2/1)

»(Amine/acld ratio = l/l)

»Steario acid - diethanolamine condensate

»Tall oil acids - diethanolamine condensate

Tallow acids - diethanolamine condensate

Other diethanolamine condensates

Other alianolamine condensates:

Coconut oil acids - ethanolamine condensate

Coconut oil acids - isopropanolamine condensate

Laurie acid - ethanolamine condensate

*Lauric acid - isopropanolamine condensate

Myrlstic acid - ethanolamine condensate

Ifcrristic acid - isopropanolamine condensate

Oleic acid - ethanolamine condensate

Oleic acid - Isopropanolamine condensate

^Stearic acid - ethanolamine condensates:

(Amiue/acid ratio = l/l)

(Amine/acid ratio = 1/2)

All other ratios

All other fatty acid - aUcanolamine condensates

*Fatty acid - polyamine condensates:

Adipic and stearic acids - diethylenetriamine condensate.

Coconut oil acids - diethylenetriamine condensate

Coconut oil acids - N,N-dimethyl-l,3-propylenediamine condensate .

Coconut oil acids - propylenediamine condensate

Mixed fatty acids - polyaliylenepolyamine condensate

Oleic acid - aminoethylpiperazine condensate

*01eic acid - diethylenetriamine condensate

Oleic acid - diethylenetriamine condensate, acetic

acid salt. Oleic acid - N,N-dimethyl-l,3-propylenediamine condensate.

Manufacturers' identification codes (according to list in table 22)

WYN. JCC.

GGY, ONX, PCS, RZL. PCS, VAL, VND.

AML, ARD, BSC, CIB, CIN, CLI, CRT, CTL, DEP, DRW, EFH, HLI, HRT, JOR, KNP, LEV, LUR, MDA, NOP, ONX, PC, PCS PC, PNX, RCD, RZL, SBC, SEY, SWT, TCC, TXC, TXT, UNN UVC, VAC, VAL, VND, WTC.

APX, ARD, ARL, CLI, CTL, DRW, EMK, GGY, HLI, MDA, MRV NOP, ONX, PCS, PEK, QCP, SBC, SEY, STP, TXT, VAC.

JRG, PCS.

ARD, CLI, CTL, HLI, ICI, MOA, ONX, PCS, PC, RZL, SBC TXT, WON, WTC.

VND.

CLI.

CCW, CLI, HLI, MRA, ONX, SEY, STP, WTC.

CUL, GGY, NOP, SBC, SCP, SEY, STP, SWT, TXT.

AML, APX, ARD, BSC, CLI, DEP, EMR, GGY, GLY, JOR, MRA,

NOP, ONX, RPC, SCO, SEY, TXC, UVC, VAL, WTC.

EFH, MRA, MRV, SEY, WTC. PCS, PG, RPC.

BSC, HLI, RCD, WTC,

APX, CCL, HRT, MOA, PCS, PG, RCD, TXT, VND, WIC WTC.

LEV, STP, TXT. '

RCD, WTC.

ARC, ARD, CLI, MOA, PCS, TXT, WTC.

WTC.

ARD, TXT.

ARD.

WTC.

ARD, CIN, KES, MOA, STP, VND.

GLY, WTC. CLI.

CLI, GLY.

APX.

APX, NOP, SEY. JHG.

TXT.

VIS.

PCS.

HDG, PCS, SEY.

PCS, UVC.

CCW, SNW.

162

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B.-

- Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, i564 —Continued

Manufacturers' identification codes

Chemical

(according to list in table 22)

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated— Continued

^Amides, amines, and quaternary anmioniuni salts Continued

*Fatty acid - polyamine condensates Continued

Oleic acid - ethylenedi amine condensate (amine/acid

ccw.

GLY,

HDG.

ratio = 1/2) .

Pelargonic acid - tetraethylenepentamine condensate

ICI.

»Stearic acid - diethylenetrlamine condensate

APX,

CRT,

CST,

DEP, HRT, ONX, QCP, S.

Stearic acid - N^N-diethylethylenediamine condensate

CBP.

Stearic acid - N,N'-diethylethylenedianiine condensate

SNW.

( amine/acid ratio = l/2) .

Stearic acid - dipropylenetriamlne condensate

JOR.

Stearic acid - ethylenediamine condensate (amine/acid

CCW,

GLY,

ICI.

ratio = 1/2) .

Stearic acid - tetraethylenepentamine condensate

ICI,

ONX.

Tall oil acids - diethylenetrlamine condensate

NCW.

Tall oil acids - polyamine condensate

TXT.

AIT nthea-p .

EMR

VAL,

VND,

WM.

iixj. ubiiei

*Fatty acid - polyamine condensates, ethoxylated:

Coconut oil acids - diethylenetrlamine condensate.

TCC.

polyethoxylated .

Coconut oil acids - ethylenediamine condensate, mono-

NOP,

RFC.

ethoxylated.

Mixed fatty acids - aUkylenedi amine condensate, poly-

VIS.

ethoxylated .

*01elc acid - ethylenediamine condensate, monoethoxy-

CID,

GST,

DEX,

NOP, SOC, TNA.

lated.

Palm oil acids - ethylenediamine condensate, mono-

APX.

ethoxylated .

Stearic acid - diethylenetrlamine condensate, poly-

TCC.

ethoxylated .

Stearic acid - ethylenediamine condensate, diethoxy-

TCC.

lated.

^Stearic acid - ethylenediamine condensate, monoethoxy-

AML,

CLD,

CST,

DEP, DEX, ICI, MRA, NOP, S, SNW.

lated.

Stearic acid - ethylenediamine condensate, polyethoxy-

APD,

GLY,

TCC.

lated.

^Heterocyclic compounds :

Imidazole derivatives:

l-(2-Aminoethyl)-2-(tall oil alkyl) -2-lmldazoline

NLC.

1, 1-Bis( carboxymethyl) -2-undeoyl-2-imidazolinium

PCS.

chloride, dlsodium salt.

l,l-Bis( carboxymethyl) -2-undecyl-2-lmidazolinium

MIR.

hydroxide, disodium salt.

l-Carboxymethyl-2-heptadecyl-l-(2-hydroxyethyl) -2-

MIR.

imidazolinium hydroxide, sodium derivative, sodium salt. l-Carboxymethyl-l-(2-hydroxyethyl) -2-nonyl-2-imidazo-

PCS.

linium chloride, sodium salt.

MIR.

linium hydroxide, sodium derivative, sodium salt.

l-Carboxymethyl-l-( 2-hydroxyethyl) -2-undecyl-2-

WR.

imidazoliniiim hydroxide, sodium derivative, sodium salt. l-Ethyl-2-(8-heptadeoenyl) -l-( 2-hydroxyethyl) -2-

BC.

imidazolinivim bromide.

2-(8-Heptadecenyl) -l-( 2-hydroxyethyl) -2-imidazoline

GGY,

NLC,

PCS,

UVC.

»2 -Heptadecyl-l-( 2 -hydroxyethyl) -2-imidazoline

GGY,

HDG,

ONX,

UVC.

SURFACE-ACTIVE AGENTS

163

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 7564— Continued

Manufacturers' identification codes (according to list in tatle 22)

NONBENZENOID SURFACE-ACnVE AGENIS— Continued

Not Sulfated or Sulfonated— Continued

*Amides, amines, and quaternary ammonium salts Continued ■^Heterocyclic compounds Continued Imidazole derivatives Continued

2-Heptadecyl-2-imidazoline

l-(2-ffydroxyetl]yl)-2-nonyl-2-imidazoline

l-(2-Hydroxyethyl)-2-(tall oil alkyl)-2-imldazoline- l-(2-Ifydroxyethyl)-2-tridecyl-2-imida2olinium chloride.

l-(2-Ifydroxyethyl)-2-undecyl-2-imidazoline

2- (Mixed aliyl)-2-imidazoline

*Rosinpolyamidoimidazoline

Oxazole derivatives :

2- ( 8-Heptadecenyl) -4, <4-bis ( hydroxymethyl) -2-

oxazoline. 2-(8-Heptadeoenyl)-'t-hydroxymethyl-4-methyl-2- oxazoline. *N-Substltuted amino acids and polypeptides:

N-[ 2-( Carboxymethylamino) ethyl J -N-( 2-hydroxyethyl) - coconut oil amide, sodium salt.

N-( Coconut oil acyl)sarcosine

N-( Coconut oil aliyl) -p-alanlne

N-Dodeoyl-3-iminodipropionic acid

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine

N-Lauroylpolypeptide

N-Lauroylsarcosine, sodium salt

N-Oleoylpolypeptide

N-Oleoylsarcoslne, sodium salt

Polypeptide

N-Stearoylsarcosine, sodiimi salt

N-(Tallow alkyl) -3-iminodipropionic acid, sodium salt- *Other amides, amines, and quaternary ammonium salts: Fatty acid - aUcanolamine condensates, ethoxylated: Hydrogenated tallow acids - ethanolamine condensate, ethoxylated.

Oleic acid - ethanolamine condensate, ethoxylated

Oleic acid - methanolamine condensate, ethoxylated Tall oil acids - ethanolamine condensate, ethoxy- lated. All other amides, amines, and quaternary ammonium salts :

*N-(Goconut oil aliyl)-l,3-propylenediamine

(Cottonseed oil alkyl) amine

N-Dodecyldiethylenetri amine

N-(Mixed alkyl)polyethylenfipolyamine

*N-(9-0etadecenyl) -1,3-propylenedlamine

N-(Soybean oil aliyl) -1,3-propylenediamlne

Stearic acid - N-(2-cyanoethyl)diethylenetrlamine condensate (amine/acid ratio = 1/2) .

*N-( Tallow alkyl) -1,3-propylenediamine

All other

*Carboxyllc acid esters:

^Ethylene glycol and diethylene glycol esters: *Diethylene glycol di- and sesquistearate:

Diethylene glycol distearate

Diethylene glycol sesquistearate

*Diethylene glycol monolaurate

^-Diethylene glycol mono-oleate

*Diethylene glycol monostearate

RZL,

SCO.

PCS.

NLC.

GGY.

GGY,

UVC.

TXT.

GRD,

PCS,

UVC

COM.

COM,

UVC.

GGY.

GNM.

G^M.

G.

MYW.

CP, GGY, HMP, ONX.

MYW.

G, GGY.

MYW.

GGY.

GNM.

ARC, G.

ARC,

FOR, GNM.

GNM.

FIN.

CCW.

ARC,

FOR, GNM.

ARC.

CIB.

ARC,

FOR, GNM.

CIB,

G, ONX, X

KES.

GLY, WM.

CCW, DRW, EMR, GLY, HAL, HDG, KAL, KES, NOP, WTC.

HAL, KES, WTC.

CCW, CIN, CLI, HAL, KES, NOP, PCS, QCP, VAl, VHD, WTC.

164 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Chemical

NONBENZENOID SUHFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sui/ona ted— Continued

«Cartoxyllc acid esters Continued

»Ethylene glycol and diethylene glycol esters— Continued

♦Ethylene glycol distearate

♦Ethylene glycol monostearate

♦Other ethylene glycol and diethylene glycol esters:

Diethylene glycol mono( coconut oil) ester

Diethylene glycol monorioinoleate

Diethylene glycol sesquilaurate

Diethylene glycol sesquioleate

Diethylene glycol tall oil ester

Ethylene glycol mono-oleate

Ethylene glycol sesquistearate

♦Glycerol esters:

♦Complex glycerol esters:

Glycerol diacetyltartrate mono-oleate

Glycerol diacetyltartrate monostearate

Glycerol lactate laurate

Glycerol lactate palmitate

Glycerol lactate stearate

Glycerol maleate mono-oleate

Glycerol mono-oleate, aoetylated

All other

♦Glycerol esters of chemically defined fatty acids:

Glycerol dioleate

Glycerol distearate

Glycerol monooaprylate

Glycerol monolaurate

♦Glycerol mono-oleate

Glycerol monorioinoleate

♦Glycerol monostearate

♦Glycerol esters of mixed fatty acids:

Glycerol diester of lard

♦Glycerol monoester of coconut oil acids

♦Glycerol monoester of cottonseed oil acids

Glycerol monoester of hydrogenated cottonseed oil

acids. Glycerol monoester of hydrogenated soybean oil acids

Glycerol monoester of lard

Glycerol monoester of peanut oil acids

All other

♦Polyethylene glycol esters:

♦Polyethylene glycol esters of chemically defined fatty acids:

♦Polyethylene glycol dilaurate

♦Polyethylene glycol dioleate

♦Polyethylene glycol distearate

Polyethylene glycol methylcarbitol maleate

♦Polyethylene glycol monolaurate

Manufacturers' identification codes (according to list in table 22)

EMR, HAL, HDG, KES.

CCW, CLI, DRW, EFH, GLY, HAL, HDG, KES, KNP, PCS, TOD,

WM.

DRW.

GLY.

GLY.

GLY.

HDG,

QOP,

SEY, WTC

EFH.

WM.

DRW.

DRW,

PCS,

WTC.

APD.

DRW,

GLD.

APD,

GLD.

NOP,

WTC.

EK.

HAL, KES.

APX, KES, PCS.

KES.

GLY, KES, KNP.

APD, CCW, DRW, EFH, EK, EMR, GLY, HAL, HDG, KES, SWT,

VND, WM. CCW. CCW, CHL, CRT, DRW, EK, EMR, GLY, HAL, HDG, JRG, KES,

LUR, MRA, NOP, NW, PCS, PG, SNW, SWT, TCC, VND, WM,

WTC, X.

DRW, GLY, HAL, HDG, SWT, WM.

DRW, EK, GLD, PCS.

LEV.

DRW.

EK, GLD.

DRW.

APD, EFH, EK, GLD, GLY, HDG, LEV, PCS, SWT, WTC.

DEX, EFH, GLY, HDG, JOR, KES, PCS, UVC, WM.

CLD, EFH, GGY, GLY, HAL, HDG, KES, NOP, PCS, SPP, UVC,

VND, WM.

GLY, HAL, KES, PCS, QCP. CCA.

AAC, ARC, BSC, CCA, DEX, DRW, GGY, GLY, HAL, ICI, JOR,

KES, KNP, NOP, SYC, TCH, UVC.

SURFACE-ACTIVE AGENTS

165

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 7564— Continued

Chsfflica.!

Manufacturers '

identification codes

(ac

cording tc

list in table 22)

NONBENZENOID SURFACE -ACTIVE AGENTS— Continued

Wot Sulfated or Sul fona ted- -Continued

*Carboxylic acid esters Continued

*Polyethylene glycol esters— Continued

^Polyethylene glycol esters of chemically defined

fatty acids— Continued

^Polyethylene glycol mono-oleate

AAC,

ARC,

CCA,

CLD,

CRC,

CRT, DEX, DRW, EMR, G, GGY,

GLY, HAL, ICI, KES, NOP, ONX, PCS, QCP, SPP.'SWT,'

SYC, TCH, UVC, VAC, WW

, WTC.

Polyethylene glycol monopalraitate

APD.

Polyethylene glycol monoricinoleate

AAC, AML,

HAL, APD,

KES, ARC,

NOP. CCW,

^Polyethylene glycol monostearate

CIN,

CRT, DEP, DEX, DRW, G, GGY.

GLY, HAL, HDG, ICI, JOR, KES, KNP, NOP, ONX,' PC,

PCS, PD

, RH,

TCC,

TCH,

UVC, VND, WTC.

*Polyethylene glycol esters of mixed fatty acids:

Polyethylene glycol castor oil ester

G, GGY, GLY, NOP, UVC, WTC.

*Polyethylene glycol coconut oil ester

APX,

ARL,

GLY,

HAL,

NOP,

PCS, PG, VND.

^Polyethylene glycol rosin ester

APD,

HPC,

QCP,

VIS.

*PolyetlQrlene glycol tall oil ester

AML,

APD,

APX,

ARC,

DRW,

GLY. HAL. HDG, KES, MCN, NOP,

OMC, PCS, SOS, TCH, UVC, WTC.

Polyethylene glycol tallow ester

ONX,

SOS.

All other

GLY,

HDG,

PCS,

SYC.

*Other oarhoxylic acid esters:

Anhydrosorbitol esters :

Anhydrosorbitol dioleate

APD.

Anhydrosorbitol mixed fatty acid ester

GLY.

Anhydrosorbitol monolaurate

AAC,

APD,

GLY,

HDG,

PCS.

Anhydrosorbitol mono-oleate

AAC,

APD,

DRW,

GLY,

HDG,

PCS.

AnlQfdrosorbitol monopalmitate

AAC,

APD,

GLY.

Anhydrosorbitol monostearate

AAC, GLY.

APD,

DRW,

GLY,

HDG,

PCS.

Anhydrosorbitol sesquioleate

^Anhydrosorbitol tall oil ester

APD,

GLY,

HDG.

Anhydrosorbitol tetrastearate

AAC,

APD.

Anhydrosorbitol trioleate

AAC,

APD,

GLY.

Anhydrosorbitol tristearate

APD,

GLY.

Ethoxylated anhydrosorbitol esters:

Ethoxylated anhydrosorbitol castor oil ester

APD.

*Ethoxylated anhydrosorbitol monolaurate

AAC, AAC,

APD,

APD,

DRW, DRW,

GLY, GLY,

HDG, HDG,

PCS, TCH. PCS, TCH.

*Ethoxylated anhydrosorbitol mono-oleate

Ethoxylated anhydrosorbitol monopalmitate

AAC, AAC, APD,

APD, APD, TCH.

GLY, DRW,

TCH. GLY,

^Ethoxylated anhydrosorbitol monostearate

HDG,

PCS, TCH.

Ethoxylated anhydrosorbitol tall oil ester

^Ethoxylated anhydrosorbitol trioleate

AAC, AAC,

APD, APD,

GLY, DRW,

TCH. GLY,

*Ethoxylated anhydrosorbitol tristearate—-

PCS,

TCH.

Ethoxylated sorbitol esters:

Ethoxylated sorbitol beeswax ester

APD.

Ethoxylated sorbitol distearate

APD.

Ethoxylated sorbitol hexaoleate

APD.

Ethoxylated sorbitol hexa(tall oil)ester

APD.

Ethoxylated sorbitol lanolin ester -^

APD.

Ethoxylated sorbitol mono-oleate

APD.

Ethoxylated sorbitol oleate stearate

APD.

Ethoxylated sorbitol pentalaurate

APD.

Ethoxylated sorbitol pentaoleate, acetylated

APD.

Ethoxylated sorbitol penta(tall oil) ester

APD.

Ethoxylated sorbitol tetra( laur ate , oleate)

APD.

Ethoxylated sorbitol tetra(tall oil)ester

APD.

166

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

NONBENZENOID SURFACE -ACTIVE AGENTS- -Continued

Not Sulfated or Siilfonated--Continued

»Carboxylio acid esters Continued

*Other oarboxylio acid esters Continued All other carboxylic acid esters:

Anhydrosorbitol glycerol monolaurate

Calcium stearolactate

Coconut oil acids, ethoxylated methanol ester

Diisobutylene maleate

Ethoxylated glycerol mono- and diester of mixed fatty acids.

Ethoxylated 1,2-propanediol mono-oleate

Ethoxylated 1,2-propanediol stearate

Mannitol dioleate, propoxylated

Methyl glucoside laurate

Methyl glucoside oleate

Pentaerythritol distearate

Polyaliylene glycol adipate

PolyaUjylene glycol diglycolate

PolyaUjylene glycol dimaleate

Polyaliylene glycol naphthenate

Polyglycerol lactate oleate

Polyglycerol raonoester of cottonseed oil acids—

Polyglycerol oleate

Polyglycerol stearate

1,2-Propanediol distearate

1,3-Propanediol mono( coconut oil) ester

*1, 2 -Propanediol monolaurate

1,2 -Propanediol mono-oleate

*l,2-Propanediol monostearate

Propylene glycol mono esters

Sucrose esters of fatty acids

All other

*Ethers:

*Castor oil, ethoxylated

Coconut oil alcohols, ethoxylated

n-Decyl alcohol, ethoxylated

n-Decyl alcohol, ethoxylated and chlorinated

*n-Dodecyl alcohol, ethoxylated

n-Hexadecyl alcohol, ethoxylated

Hydrogenated castor oil, ethoxj'lated

Iso-octyl alcohol, ethoxylated

Lanolin, ethoxylated

*Mixed primary straight chain alcohols, ethoxylated-

*9-0ctadeoenyl alcohol, ethoxylated

n-Ootadecyl alcohol, ethoxylated

Polyethylene glycol tert-dodecyl thioether

Poly(mlxed ethylene, propylene) glycol

Polypropylene glycol, ethoxylated

Rosin alcohol, ethoxylated

Sorbitol, alkoxylated

Soybean oil, ethoxylated

Sperm oil alcohol, ethoxylated

Tallow alcohol, ethoxylated

2,4,7,9-Tetramethyl-5-decyne-4.,7-diol, ethoxylated- »Tridecyl alcohol, ethoxylated

Manufacturers ' Identification codes (according to list in table 22)

APD.

GLY.

JOR.

RH.

APD.

APD. APD. APD. HDG. HDG. VAL. PFZ. VIS. VIS. APD. DRW. DRW. DRW, PCS. PCS. DRW. HAL, KES. APD, GLD. SUG. WM.

KES, SBC, WM.

CCW, EK, GLY, HAL, HDG, JRG, EES, PCS, PG, WTC.

AAC, APD, BAG, DRW, ICI, NOP, PCS, RTF, TCH, VAC, VIS. G.

G, ICI, PCS. G.

AAC, APD, DRW, G, GLY, JCC, NAC, CMC, PCS, UCC. ADM, APD, CIB, ICI. AAC, APD. G.

APD.

CO, JCC, RH, RTF, TCH, VIS, WW. AAC, ADM, APD, CIB, DUP, G, ICI, NOP, TCH. ACC, APD, CIB. MON, PAS. UCC, VIS. PCS, VIS, WYN. HPC. VAC. CGL. DUP. G.

AIR.

AAC, APD, DRW, EFH, G, ICI, JCC, MON, OMC, PCS, RTF, TCH, UCC, VIS.

TABLE 19B.-

SURFACE-ACTIVE AGENTS

-Surface-active agents for which U.S. production or sales were manufacturer, i564— Continued

167

reported, identified by

NONBENZENOID SURFACE -ACTIVE AGENIB— Continued Not Sulfated or Sulfonated--Continued

(•■Ethers —Continued

Tridecyl alcohol, ethoxylated and carbonated, sodium salt.

Tridecyl alcohol, ethoxylated and chlorinated

Tridecyl alcohol, propoxylated and ethoxylated

Trimethylheptanol, ethoxylated

Trimethylnonyl alcohol, ethoxylated

Trimethylolpropane , alioxylated

All other

Fatty acids, potassium and sodium salts:

Castor oil acids, potassium salt

Castor oil acids, sodium salt

»Coconut oil acids, potassium and sodium salts:

Coconut oil acids, potassium salt

Coconut oil acids, sodium salt

Corn oil acids, potassium salt

Com oil acids, sodium salt

*Lauric acid, potassium salt

*Mixed vegetable fatty acids, potassium salt

*01eiG acid, potassium salt

*01eic acid, sodium salt

Olive oil acids, sodium salt

Palm oil acids, sodium salt

Peanut oil acids, potassliim salt

*Rosin acids, sodiiim salt

Soybean oil acids, potassium salt

Stearic acid, potassium salt

*Stearic acid, sodium salt

»Tall oil acids, potassium salt

*Tall oil acids, sodium salt

Tallow acids, potassium salt

Tallow acids, sodium salt

All other

*Phosphorlc and polyphosphorlc acid esters; ^Alcohols, phosphated and polyphosphated:

Deoyl, octyl phosphate

Decyl phosphate, ethanolamine salt

Decyl polyphosphate, sodium salt

*2-Ethylhexyl phosphate, sodium salt

2-Ethylhexyl polyphosphate

Hexyl polyphosphate, potassium salt

Mixed aliyl phosphate, diethanolamlne salt

Mixed decyl, dodecyl, and octyl phosphate, morpholine salt.

*Mixed mono- and dialiyl phosphate

9-Octadecenyl phosphate

Ootadecyl phosphate, ethanolamine salt

Octyl phosphate, aliylamine salt

*Octyl polyphosphate

Octyl polyphosphate, potassium salt

Octyl polyphosphate, sodium salt

Tri(castor oil alkyl) phosphate

Tri(mixed alkyl) phosphate

*Other phosphoric and polyphosphorlc acid esters:

Dodecyl alcohol, ethoxylated and phosphated

Dodecyl alcohol, ethoxylated and polyphosphated

Manufacturers' identification codes (according to list in table 22)

S.

G.

JCC, PCS.

PCS.

UCC.

RTF.

JCC, VPC.

BAG, SEA. MRV, SEA.

ARL, CON. PCH. LUR. BSC, AMI, AML, LUR, LUR. LUR. KAL, CRT, CON, VAL. LEV, BSC, DEX, SWT. CON, SLC,

LUR, PCH, SWT.

DRW, NOP, VAL.

ARL, PCH, SWT.

BSC, CIB, DAN, DEX, EFH, NOP,

MRV, NOP, SEA, SWT, WTC, x.

P, S, SHP, WTC, X.

SLC.

MRA, QCP. DRW.

MAL, NOP, SLC, WTC.

CIN, CON, DRW, LUR, PNX, QCP, VAL.

PCS, QCP, UNP.

LUR, NOP, QCP, SWT. VAL.

UVC.

RCD.

SEY.

SEY, TCI, UCC, UVC.

UVC.

CST, DEX.

DUP.

DUP.

CST, DUP, UVC.

DUP.

RCD.

DUP, TXT.

BCN, DEX, TXT.

X.

VIC. GLY. VIC.

168

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, i 564 --Continued

Manufacturers ' identification codes (according to list in table 22)

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued Not Sulfated or Sulfonated- -Continued

*Phosphoric and polyphosphoric acid esters Continued »Other phosphoric and polyphosphoric acid esters Con.

2-Ethylhexanol, ethoxylated and phosphated

Mixed primary straight chain alcohols, ethoxylated and phosphated .

9-Octadecenyl alcohol, ethoxylated and phosphated

Ootyl phosphate, ethoxylated

Propylene glycol, propoxylated and phosphated

Tridecyl alcohol, ethoxylated and phosphated

All other

Other nonbenzenoid surface-active agents, not sulfated or sulfonated :

3,5-Dimethyl-l-hexyn-3-ol

3,6-Dimethyl-"+-octyne-3,6-diol

2,<i,7,9-Tetramethyl-5-deoyne-4.,7-diol

All other

Sulfated and Sulfonated

»Dicarboxylic acid amides, sulfated and sulfonated:

N-(l,2-Dicarboxyethyl) -N-octadecylsulfosuooinamic acid, tetrasodiujn salt.

N-(2-Hydroxyethyl)-N-( tallow aliyl) suLfosuooinamide

N-OctadecylsulXosuccinamide, disodium salt

N-(01eoyloxyisopropyl)sulfosuocinamide

*Dicarboxylic acid esters, sulfated and sulfonated:

*Sulfosucoinio acid, bis(2-ethylhexyl;ester

Sulfosuocinic acid, bis(tallow monoglyceride) ester

Sulfosuccinic acid, dihexyl ester

Sulfosuccinic acid, dioctyl ester, sodium salt

Sulfosuccinic acid, dipentyl ester, sodium salt

Sulfosuocinic acid, ditrideoyl ester, sodium salt

All other

«ii-Dodecyl sulfate salts:

n-Dodecyl sulfate, 2 -ami no -2 -me t hy Ipropanol salt

*n-Dodecyl sulfate, ammonium salt

n-Dodecyl sulfate, diethanolamine salt

n-Dodecyl sulfate, N,N-diethylcyclohexylamine salt

n-Dodecyl sulfate, isopropanolamine salt

n-Dodecyl sulfate, magnesium salt

n-Dodeeyl sulfate, potassium salt

»n-Dodecyl sulfate, sodium salt

*n-Dodecyl sulfate, triethanolamine salt

*Fats, oils, and waxes, sulfated and sulfonated:

*Castor oil, sulfonated

*Coconut oil, sulfonated

*Cod oil, sulfonated

Cottonseed oil, sulfonated

^Grease, other than wool, sulfonated

DUP.

APD.

G, LUH.

VIC, WTC.

AIR.

AIB.

AIR.

GLY, JCC, LMI,

STC

SCP. ACY. WTC.

ACY, CIN, CRC, CRT, CST, DAN, EFH, EMK, GGY, HRT, ICI ,

MOA, MRA, PC, SBC, TCI. ACY.

ACY, MDA. RH. ACY.

ACY, MOA, WTC. G.

DUP.

AAC, DUP, ONX, PCS, STP.

AAC, CUL, DUP, HLI, JRG, ONX, STP.

DUP.

JRG, PCS.

AAC, HLI.

HLI, PG.

AAC, DUP, HLI, JRG, MYW, ONX, PCI, PCS, PG, RCD, RET,

STP, TXT. AAC, CUL, DUP, HLI, MYW, ONX, PCS, PG, RCD, RET, STP,

TXT.

AAE, ACT, ACY, AML, APX, BAO, BRY, BSC, CRT, DEX, DRW,

DUP, EFH, G, HRT, ICI, KAL, KNG, LEA, LUR, MRA, MRD, MRV, NOP, ONX, PC, PCI, S, SCO, SCP, SEA, SLC, WHI, WHW.

ACY, BAO, MRD, NOP, RTC, SEA, WHW.

ACT, BAO, CRT, DRW, LEA, MRD, NOP, S, SEA, WAW, WHI, WHW.

NOP, RTC.

CRT, NOP, SEA, WHI, WHW.

SURFACE-ACTIVE AGENTS

169

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, i56<?— Continued

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued Sulfated and Sulfonated— eontiimed

*Fats, oils, and waxes, sulfated and sulfonated Continued

Lard, sulfonated

Mixed fish oils, sulfonated

Mixed vegetable oils, sulfonated

Mustard seed oil, sulfonated

*Neat's-foot oil, sulfonated

Oleostearin, sulfonated

»Peanut oil, sulfonated

Red fish oil, sulfonated

«Rice-bran oil, sulfonated

^Soybean oil, sulfonated

»Sperm oil, sulfonated

*Tall oil, sulfonated

»Tallow, sulfonated

Whale oil, sulfonated

All other

*Other nonbenzenoid surface-active agents, sulfated and sulfonated: Alcohols, except dodecyl, sulfated and sulfonated:

Branched hexadeoyl sulfate, sodium salt

n-Decyl sulfate, sodium salt

n-Decyl sulfate, triethanolamine salt

3,9-Diethyl-6-trideeyl sulfate

2-Ethylhexyl sulfate, sodium salt

7-Ethyl-2 -methyl -4— undecyl sulfate

n-Hexadecyl sulfate

Hexyl sulfate, potassium salt

Mixed coconut oil alkyl and sperm oil aliyl sulfate, sodium salt.

Nonyl sulfate

n-Octadecyl sulfate ^

n-Ootadecyl sulfate, sodium salt

n-Octadecyl sulfate, triethanolamine salt

n-Octyl sulfate, sodium salt

n-Tetradecyl sulfate, sodium salt

Tridecyl sulfate, sodium salt

Alianes, sulfated and sulfonated:

Mixed alianesulfonic acids

Mixed alkanesulfonic acids, sodium salt— r

Amines, fatty acid amides, and quaternary ammonium

salts, sulfated and sulfonated:

Fatty acid - alianolamine condensates, sulfated:

*Coconut oil acids - ethanolamine condensate,

sulfated, potassium salt.

Coconut oil acids - ethanolamine condensate,

sulfated, sodium salt. Laurie acid - isopropanolamine condensate, sulfated- Neat's-foot oil acids - ethanolamine condensate, sulfated, ammonium salt.

Oleic acid - ethanolamine condensate, sulfated

Stearic acid - diethanolamine condensate, methyl

sulfate . All other

Manufacturers' identification codes (according to list in table 22)

WAW.

AMI, EFH, SCO.

LEA.

LUR, NOP.

ACT, BAO, CRT, KAL, LUR, MRD, NOP, PC, SEA, WHW.

SEA.

ACY, CRT, ICI, LEA, LUR, NOP, SCP, SEY, SLC, SOS.

WHI.

HRT, KNG, LUR, NOP-^

APX, CRT, DRW, HRT, KAL, LEA, MRD, ONX.

ACT, BAO, CLD, CRT, DRW, HRT, KAL, KNG, LEA, MRD,

NOP, ONX, RTC, S, SEA, WHI, WHW. ACy, APX, BAO, CRT, ICI, QCP, SEA, WHW. ACT, ACY, BRY, DRW, EFH, ICI, KAL, LEA, LUR, MRA, MRD,

NOP, ONX, PC, PCI, SCP, SID, SOS, SNW, WHI. KNG. EFH.

APX.

DUP,

ONX,

PCS.

DUP.

UCC.

AAC,

UCC,

WTC.

UCC.

AAC,

DUP.

DEX.

DUP.

TN.

DUP,

EMK,

PG.

ONX.

DUP.

DUP,

PCS.

ONX.

AAC.

VPC.

DUP,

WSN.

DEX,

EMK,

HRT, ONX

DEP.

PCS.

APX.

SCP.

DUP.

170

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

NONBENZENOID SURFACE-ACTIVE AGENTS -Continued

Sulfated <md'Sulfonated--ContinuBd

*Other nonbenzenoid surfaoe-aotive agents, sulfated and sulfonated --Continued Amines, fatty acid amides, and quaternary ammonium salts, sulfated and sulfonated--Continued Quaternary ammonium salts, sulfated and sulfonated:

N-Aliyl dimethyl ethyl ammonium ethyl sulfate

(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2-

hydroxy ethyl) ammonium ethyl sulfate. Bis(hydrogenated tallow alkyl)dimethylammonium methylsulf ate .

Dlmethyldloctadeoylammonlum methyl sulfate

l-Ethyl-2-(8-heptadeoenyl) -l-(2-hydroxyethyl) -2- Imidazollnlum ethyl sulfate.

N-Ethyl-N-hexadecylmorpholinium ethyl sulfate

N-Ethyl-N-( soybean oil alkyl) morpholinium ethyl

sulfate. 2-Heptadecyl-l-(2-stearamidoethyl)-2-lmadazollnium

methyl sulfate. (3-Lauramidopropyl)trlmethylammonlum methyl sulfate-

Mlxed aliyl sulfobetalnes

Trlmethyl(3-oleamldopropyl) ammonium methyl sulfate- Taurine derivatives:

N-Cyclohexyl-N-palmitoyltaurine

N-Methyl-N-( coconut oil aoyl) taurine

«-N-lfethyl-N-oleoyltaurlne

N-Metl^l-N-palmltoyltaurine

N-Methyl-N-(tall oil aoyl) taurine, sodium salt

N-Methyl-N-( tallow acyl) taurine

Other amines, fatty acid amides, and quaternary ammonium salts, sulfated and sulfonated: N-( 2-Hydroxyethyl) -N, N ' , N' -tris ( 2-hydroxypropyl) -

ethylenediaraine , distearate methyl sulfate. Laurie acid, 2-sulfoaoetamidoethyl ester, potassium salt.

N-(Mixed alkyl sulfonyl) glycine, sodium salt

Mixed primary amines, ethoxylated and sulfated

Oleic acid - ethylenedlamine condensate, propoxy-

lated and sulfated, sodium salt. Stearic acid - ethylenedlamine condensate, mono-

ethoxylated, ethyl sulfate. Tall oil acids - polyalkylenepolyamine condensate,

sulfated. N, N, N ', N ' -Tetraiis ( 2-hydroxypropyl) ethylenedlamine dioleate methyl sulfate. Ethers, sulfated and sulfonated:

n-Dodecyl alcohol, ethoxylated and sulfated, ammonium salt. »n-Dodecyl alcohol, ethoxylated and sulfated, sodium salt. n-Dodecyl alcohol, ethoxylated and sulfated, trl- ethanolamine salt.

Hexyloxypropyl sulfate, sodium salt

Mixed primary straight chain alcohols, ethoxylated

and sulfated. Mixed primary straight chain alcohols, ethoxylated

and sulfated, ammonium salt. Sperm oil alcohol, ethoxylated and sulfated

Manufacturers ' identification codes (according to list in table 22)

JOR. LUR.

ONX. APD.

APD. APD.

ACY. TXT. CIB.

ORG, CRT, DEP, DRW, G, HRT, MRA, NOP, VAL.

AAC, DUP, ONX, PCS, RCD, RET, TXT.

PG.

SURFACE-ACTIVE AGENTS

TABLE 19B.— Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1964— Continued

171

NONBENZENOID SURFACE-ACTIVE AGENTS —Continued Sulfated and 5ui/onaf ec/--Continued

*Other nonbenzenoid surface-active agents, sulfated and sulfonated Continued Ethers, sulfated and sulfonated Continued

Tridecyl alcohol, ethoxylated and sulfated, ammonium

salt. Tridecyl alcohol, ethoxylated and sulfated, sodium salt.

All other

Fatty acids, sulfated and sulfonated:

Acetyloleic acid, sulfonated

*01eic acid, sulfonated

Rioinoleic acid, sulfonated

Fatty acid esters, sulfated and sulfonated:

2-Butoxyethyl sulfo-oleate

*Butyl sulfo-oleate

Butyl sulforicinoleate

Coconut oil isethionate

Coconut oil isethionate, sodium salt

Dodeoyl sulfoacetate

Ethyl sulfo-oleate

Glycerol mono( coconut oil) ester, sulfated, ammonium

salt. Glycerol mono( coconut oil) ester, sulfated, sodium salt.

Glycerol monostearate sulfoacetate

Glycerol tri( sulfo-oleate)

*Isopropyl sulfo-oleate

2-Lauroyloxy-l-propanesulfonic acid

Methyl sulfo-oleate

^Propyl sulfo-oleate

All other

Manufacturers' identification codes (according to list in table 22)

LEV.

AAC, ARL, RCD.

APX, PG.

DUP.

ACT, ACY, BRY, CRT, DRW, EMR, G, ICI, LEA, LUR, MRV,

NOP, PCI, QCP, SCO, TN, WHl, WHW. NOP.

AML, CIN, ICI, NOP, ONX, PC.

NOP.

DRW.

G, LEV.

NAC.

G, KAL.

CP.

CP.

WTC.

ACT, MRV, SCP.

BRY, DEX, EMR, HRT, ICI, LEA, LUR.

SDH.

ICI.

ACY, BSC, CHL, EFH, MRV, WM.

EMR.

172

SYNTHETIC ORGANIC CHEMICALS, 1964

Pesticides and Other Organic Agricultural Chemicals

TABLE 20B. Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer , 1964

[Pesticides and other organic agricultural chemicals for which separate statistics are given in table 20A are marked below with an asterisk (»); products not so marked do not appear in table 20A because the reported data are ac- cepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers ' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, OrCLIC

^Fungicides :

2,6-Bis(dimethylaminomethyl)cyclohexanone

5-Chloro-2-mercaptobenzothiazole, lauiylpyridium salt

2,<V-Dichloro-6-o-chloroanilino-s-triazine

2,3-Dichloro-l,<*-naphthoquinone (Dichlone)

Diphenylammonium propionate

3,3' -Ethylenebis ( tetrahydro-^ , 6-dimethyl-2H-l, 3,5,5- thiadiazine-2-thione) .

2-Heptadecyl-2-imidazoline acetate (Glyodin)

2-Mercaptobenzothiazole, monoethanolamine salt

*Mercury fungicides :

2-Chloro-4-(hydroxymercuri)phenol

Chloromethoxypropylmercuric acetate

N-(Ethylmercuri)-p-toluenesulfonanilide

1,4,5,6 , 7, 7-Hexachloro-N- ( ethylmercuri ) -5-norbomene- 2, 3-dicarboximide.

'i-(^ydroxymercuri)-2-nitrophenol

8-(Methylmercurioxy)quinoline

2 - ( Phenylmercuriamino ) ethyl acetate

Phenylmercuriammonium acetate

N-Phenylmercuriformamide

Phenylmercury hydroxide

Phenylmercury lactate

Phenylmercury naphthenate

Phenylmercury oleate

Phenylmercury propionate

Tris(2-hydroxyethyl) (phenylmercuri)aiiimoniuin lactate

2-(l-Methylheptyl)-4,6-dinitrophenyl crotonate

»Naphthenic acid, copper salt

Pentachloronitrobenzene

*Pentachlorophenol (PCP)

Pentachlorophenol, sodium salt

8-Quinolinol (8-Hjrdroxyquinoline), copper salt

Tetrachloro-p-benzoquinone ( Chloranil)

2,3,4,6-Tetrachlorophenol

Tetrahydro-3,5-dimethyl-2H, l,3,5-thiadiazine-2-thione

N- ( Trichloromethylthio ) -<4-cyclohexene-l, 2-dicarboximide (Captan) .

N-( Trichloromethylthio )phthalimide (Folpet)

*2,4,5-Trichlorophenol

■t2,'4,5-Trichlorophenol, ethanolamine salt

»2,4,5-Trichlorophenol, sodium salt

2,4,6-Trichlorophenol

^Herbicides and plant hormones :

5-Bromo-3-sec-butyl-6-methyluracil

5-Bromo-3-isopropyl-6-methyluracil

l-Butyl-3-(3,4-dichlorophenyl)-l-methylurea (Neburon)

*2-sec-Butyl-4,6-dinitrophenol (DNBP)

*2-sec-Butyl-4,6-dinitrophenol, ammonium salt

2-seo-Butyl-4,6-dinitrophenol, triethanolamine salt

2-sec-Butyl-4,6-dinitrophenyl-3,3-dime thy lacry late

2-sec-Butyl-4,6-dinitrophenyl-3-methyl-2-butenoate (Binapacryl).

2-Chloro-4, 6-biE(ethylamino)-s-trlazine (Simazine)

4-Chloro-2-butynyl m-chlorocarbanilate (Barban)

2-Chloro-4-ethylamino-6-isopropylamino-s-triazine

( Atrazine ) . N- ( 3- Chloro-4-methylphenyl ) -2-methylpentanamide ( Solan ) -

MTL. VNC. CHG. USR. MTL. DUP.

UCC. VNC.

DUP. TRC. DUP. RBC.

DUP.

MTL.

CLY.

GUA,

VIN.

WRC.

WflC.

MTL.

CLY,

MTL.

CLY.

RH.

CCA,

MON,

BXT,

DOW,

GAM,

USR.

DOW.

CLY,

CHO.

HNX, MTL, TRO, TOC.

FER, HNX, MCI, MLD, SM, SOC, SRR, TGL, TRO, WTC.

CMC.

DOW, FRO, ION, RCI.

M3N, RCI.

HNX, MTL.

MTL, SF.

CHO.

DA, DOW, HK.

G.

DOW.

DOW.

DUP.

DUP.

DUP.

CIS, DOW, FMN, TNA.

CIS, DOW, FMN.

CIS, DOW, FMN.

FMP.

FMN.

GGY. SPN. GGY.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

173

TABLE 20B. Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC- -Continued

*Herbioides and plant hormones Continued

3-(p-Chlorophenyl)-l, 1-dlmethylurea (Mjnuron)

3-(p-Chlorophenyl)-l, 1-dimethylurea triohloroacetate

Chlorophenyl-N-methylcarbamate

2,5-Dichloro-3-aiiilnobenzoic acid, ainmonlum salt

3,6-Dichloro-2-anisio acid

2,5-Dlohloro-3-nitrobenzoic acid

2-(2,4-Diohlorophenoxy)ethanol sulfate, sodium salt

3- (3, ■4-Dichlorophenyl)-l, 1-dimethylurea (Dluron)

N-(3,4-Diohlorophenyl) methaorylamide (Dicryl)

3-(3,4-Dichlorophenyl)-l-methoxy-l-methylurea ( linuron)-

2,4-Dichlorophenyl-4-nitrophenyl ether

3,4-Dichloropropionanilide

l,2-Dihydro-3,6;pyTidazinedione (Maleic hydrazide)

N,N- Dimethyl -2, 2-diphenylacetamlde ( Diphenamide )

1, l-Dimethyl-3-phenylurea (Fenuron)

1, l-Dimethyl-3-phenylurea trichloroaoetate

Dimethyl tetraohloroterephthalate

4,6-Dlnitro-o-oresol (DNOC)

<i,6-Dlnitro-o-cresol, sodium salt

Dlphenylacetonitrile

N, N-Dipropyl-2,6-dinltro-'i-trifluoromethyl aniline

Gibberellic acid

3- ( Hexahydro-4-, 7-methanoindan-5-yl) - 1, 1-dimethylurea (Norea).

Indolebutyric acid

Isopropyl oarbanilate (Isopropyl N-phenyloarbamate )

(IPC). Isopropyl 3-chlorocarbanilate (Isopropyl N-(3-ohloro-

phenyl) carbamate) (CIPC). 1-Naphthaleneacetlc acid and derivatives :

1-Naphthaleneacetamide

1-Naphthaleneaoetic acid

1-Naphthaleneacetic acid, methyl ester

1-Naphthaleneacetio acid, sodium salt

2-Naphthyloxyacetic acid

2-Naphthyloxyaoetic acid, sodium salt

N-1-Naphthylphthalamic acid (NPA)

7-Q)cabicyclo[2.2.1]heptane-2,3-dicarboxylio acid,

disodium salt ( Qidothal) . Ehenoxyacetic acid derivatives:

(4-Chloro-o-tolyloxy)acetic acid (MCPA)

(4-Chloro-o-tolyloxy)acetic acid, potassium salt

*(2,'4-Dichlorophenoxy)acetic acid (2,4-D)

»( 2, A-Dichlorophenoxy) acetic acid esters and salts: ( 2, "i-Dlchlorophenoxy) acetic acid, 2-butoxyethyl

ester. (2,<i-Dichlorophenoxy)acetic acid, butoxypolypropyl- eneglycol ester.

»(2,4-Diohlorophenoxy)acetic acid, n-butyl ester

(2,4-Dlchlorophenoxy)acetic acid, sec-butyl ester

«{2,4-Dichlorophenoxy)aoetic acid, dimethylamine salt (2,4-Dichlorophenoxy)acetic acid, ethanolamlne and isopropanolamine salt.

»(2,4-Dichlorophenoxy)acetic acid, ethyl ester

( 2, 'i-Diohlorophenoxy) acetic acid, 2-ethylhexyl ester

»(2,4-Dlchlorophenoxy)acetio acid, iso-octyl ester

*{2,'4-Dlchlorophenoxy)acetic acid, isopropyl ester

(2,A-Dlchlorophenoxy)aoetio acid, lithium salt

(2,4— Dlchlorophenoxy) acetic acid, sodium salt

All other (2,'i-Dichlorophenoxy)acetio acid esters and salts.

DUP. ACG.

X.

G.

VEL.

G.

G.

DUP.

FMN.

DUP.

X.

MON, X.

ACY, USR.

LIL.

DUP.

ACG.

DA.

CIS, FMN.

CIS, FMN.

LIL.

X.

ABB, MRK. HPC.

AHA. PPG.

AMC.

AMC,

COK.

AMC.

AMC,

BKL.

BKL.

BKL.

USR.

PAS.

CHC,

DOW.

GTH.

CHC,

DA, DOW,

HPC,

MON

AMC,

DA,

DOW, HPC, IMR, MON,

RIV.

CHC.

ALC,

AMC,

CHC, DA, DOW, HPC,

RIV, TMH

CHC,

DOW.

AMC,

DOW,

MON.

DA,

HPC.

CHC,

DOW,

MON, RIV, TMH.

AMC,

CHC,

DA, DOW, HPC, MON,

RIV.

GTH.

DOW.

CWN.

174

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 20B.-

Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, i 964- -Continued

PESTICIDES AM) OTHER ORGANIC AGRICULTURAL CHEMICAI£, CYCLIC--Continueci

*Herbicldes and plant hormones Continued Phenoxyacetio acid derivatives--Contlnued

4_(2,<i-Dichlorophenoxy)butyric acid, dimethylamine salt.

»(2,4,5-Triclilorophenoxy)aoetic acid (2,4,5-T)

*(2,'4,5-Trichloroplienoxy)aoetic acid esters and salts:

(2,4,5-Triohlorophenoxy)aoetio acid, amyl ester

(2,4,5-Trlchlorophenoxy)aoetio acid, 2-butoxyethyl

ester. (2,4,5-Triohlorophenoxy)acetic acid, butoxypoly- propyleneglycol ester. *(2,4,5-TricW.orophenoxy)acetic acid, n-butyl ester— (2,'i,5-Triohlorophenoxy)acetio acid, sec-butyl ester (2,4,5-Trichlorophenoxy)aoetic acid, 2-ethylliexyl ester. *(2,4,5-Trichlorophenoxy)acetic acid, iso-octyl ester (2,'i,5-Triohlorophenoxy)acetio acid, isopropyl ester *(2,4,5-Triohlorophenoxy)aoetic acid, triethylamine salt.

All other phenoxyacetic acid derivatives

*Phenylmercury acetate (PMA)

Polyehloro-tetrahydro-methanoindene (Polychlorodicyclo- pentadiene) isomers.

N-Tolylphthalamic acid

Tributyl(2,4-dichlorobenzyl)phosphonium chloride

2-(2,'4,5-Trichlorophenoxy)propionic acid (Silvex)

2-(2,4,5-Triohlorophenoxy)propionic acid, 2-ethylhexyl

ester. 2-(2,4-,5-Trichlorophenoxy)propionic acid, triethenol- amine salt.

Tris[2-(2,4-diohlorophenoxy)ethyl]phosphite (2,4-DEP)

All other cyclic herbicides and plant hormones

Insect attractants:

4-(p-Acetoxyphenyl)-2-butanone

tert-Butyl 4(and 5)-chloro-2-methylcyclohexane- carboxylate . ^Insecticides :

Allethrin (Allyl homolog of Cinerin I)

Benzyl thiocyanate

Chlorinated insecticides : *Aldrin-toxaphene group :

Heptachloro-tetrahydro-methanoindene (Heptachlor)

Hexachloro-epoxy-octahydro-endo, endo-dimethano-

naphthalene (Endrin) . Hexachloro-epoxy-octaliydro-endo, exo-dimethano-

naphthalene (Dieldrin) . Hexachloro-hexahydro-endo, exo-dimethanonaphthalene (Aldrin) .

Octahydro-tetrahydro-methanoindan (Chlordan)

Terpene polychlorinates

Toxaphene (Chlorinated caraphene)

l,l-Bis(p-chlorophei]yl)-2-nitrobutane

l,l-Bis(p-chlorophenyl)-2-nltropropane

2-(p-tert-Butylphenoxy) -1-methylethyl 2-chloroethyl sulfite.

p-Chlorophenyl p-ohlorobenzenesulfonate (Ovex)

p-Chlorophenyl 2,4,5-triohlorophenyl sulfone

4,4'-Dichlorobenzilate

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane (DDD) (TDE)

l,l-Dichloro-2,2-bis(p-ethylphenyl) ethane

4,4'-Dichloro-a-(trichloromethyl)benzhydrol

*Hexaohlorocyclohexane (Benzene hexaohloride )

*Hexachlorocyclohexane , 100^ y-isomer (Lindane)

Hexaohloro-hexahydro-methano-benzodloxathiepinoxide (Endosulfan).

Manufacturers ' identification codes (according to list in table 22)

DA, DOW, HPC, ION.

HPC. AMC.

DA,

MON.

DA,

DOW, DA, CIS,

TMH. BKM, VEL.

USR. VC. DOW, HPC.

USR. ARA,

TBK. TBK.

DOW, HPC, ION, RIV.

HPC.

, MON, RIV, TMH.

MDN.

, DOW, HPC, RIV.

CLY, GUA, MIL, TRO, WRC.

DUP, HPC, SF.

VEL. SHC, VEL.

VEL. HN. HPC. COM.

COM. USR.

CIS, DOW.

FMN, FMP.

GGY.

ACG, RH.

RH.

RH.

DA, FRO, HK, PPG.

HK.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

175

TABLE 20B.

-Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC— Continued

^Insecticides Continued

♦Chlorinated insecticides Continued

»l,l,l-Triohloro-2,2-bis(p-chlorophenyl)ethane (DDT)

l,l,l-Trichloro-2,2-bis(p-methoxyphenyl)ethane ( Ifethoxychlor ) .

All other chlorinated insecticides

N,N-Diethyltoluaniide

Isohomyl thiocyanatoacetate

1-Naphthyl methylcarhamate

*Organophosphorus insecticides :

A-tert-Butyl-2-chlorophenyl methyl methylphosphor-

amidate . 2-Chloro-l-(2,'l-diohlorophenyl)viiiyl diethyl phosphate 0-(3-Chloro-'4-niethyl-2-oxo-2H-l-benzopyran-7-yl) 0,0-

diethyl phosphorothioate . S-(p-Chlorophenylthio)methyl 0,0-diethyl phosphoro-

dithioate (Carbophenothion). 0,0- Diethyl 0-(2-isopropyl-4-methyl-6-pyrimldinyl phosphorothioate (Diazinon). *O,0-Diethyl O-(p-nitrophenyl) phosphorothioate (Parathion) . 0,0-Dliiiethyl 0-[4-(methylthio)-ni-tolyl] phosphoro- thioate . 0,0- Dimethyl O-(p-nitrophenyl) phosphorothioate (Methyl parathion). 0,0-nimethyl S-(4-oxo-l,2,3-benzotriazin-3(4H)-

ylmethyl) phosphorodithloate . 0,0-IlLmethyl 0-(2,4,5-trichlorophenyl) phosphoro- thioate (Ronnel).

p-Dioxane-2,3-diyl ethyl phosphorodithloate

0-Ethyl O-(p-nitrophenyl) phenylphosphonothioate

a-Methylbenzyl 3-hydroxycrotonate, dimethyl phosphate ester.

All other organophosphorus insecticides

Nematocides: 0-2,'4-Dlchlorophenyl 0,0-diethyl phosphoro- thioate . *iiDdenticides :

3-(Aoetonylbenzyl)-<t-hydro2ycoumarin

2-Isovaleiyl-l, 3-indandione, calcium salt

2-Plvaloyl-l,3-indandione

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, ACYCLIC

♦Fungicides :

Bis-l,4-bromoacetoxy-2-butene

Bis(trichloromethyl)sulfone

Cadmium succinate

l-Chloro-2-nitropropane (Korax)

3,3-Diacetoxypropene-l

Disodium oyanodlthioimldocarbonate

Dithiocarbamic acid fungicides :

♦Dimethyldithiocarbamlo acid, ferric salt (Ferbam)

Dimethyldithiocarbamic acid, manganese salt

Ethylene bis(dithiocarbaniic acid), diammonium salt

♦Ethylene bis(dithiocarbaiiiic acid), disodium salt ( Nabam) .

DA, GGY, LEB, MTO, CMC, RBC.

USR. PFZ. CIS, HPC.

ACG, DUP.

LIL, HPC, BKC, UCC.

DOW.

SHC. CHG.

SF.

GGY.

ACY, AMP, MON, SHC, VIC.

CHG.

AMP, MON, SHC, VIC.

CHG.

DOW.

HPC. VIC. SHC.

ABB, PEN. MOT. MOT, PIC.

VIN.

SF.

MAL.

FMN.

SHC.

BKM.

DUP, FMN, RBC, WRC.

FMN.

CIS, RBC.

CIS, DUP, FMN, RBC, RH.

176

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 20B.

Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, i 564 —Continued

PESTICIDES ANB OTHER ORQAHIC AGRICULTURAL CHEMICALS, ACYCLIC— Continued

» Fungicides-- Continued

Dithiocarbamic acid fungicides— Continued

Ethylene bis( dithiocarbamic acid), manganese salt (Maneb). ^Ethylene bls{ dithiocarbamic acid), zinc salt (.ZinebJ

Polyethylenethiuram disulfide (PETD)

Dodeoylguanidlne acetate (Dodine)

Mercury fungicides :

3-Ethyl(mercurithlo)-l,2-propanediol

Ethylmercury acetate

Ethy Mercury chloride

Ethylmercury phosphate

Ifydroxyethylmercury acetate

3-Methyl(mercurlthio)-l,2-propaiiediol

Methylmercury acetate

Methylmeroury hydroxide

Methylmercury nitrile

All other acyclic fungicides

^Herbicides and plant hormones :

Cacodylic acid

2-Chloroallyl diethyldithiocarbamate (CDEC)

N,N-Diallyl-2-chloroacetamde (CDAA)

2,3-Dichloroallyl diisopropylthiocarbamate

2,2-Dichloropropionic acid, sodium salt

Diethyl dithiobis(thionoformate)

S-Ethyl dipropylthiocarbamate (EPTC)

Hexachloroacetone

»Methanearsonic acid, disodium salt

Methanearsonic acid, dodecyl- and octylaramonium salts

Methanearsonic acid, monosodium salt

Methanearsonic acid, sodium salt

S- Propyl butylethylthlocarbamate

S,S,S-Tributyl phosphorotrithioate

Tributyl phosphorotrithioite

Trichloroacetic acid, sodiiim salt (TCA)

2,3,3-Trlchloroallyl diisopropylthiocarbamate

All other acyclic herbicides and plant hormones

*Insectioides :

2-(2-Butoxyethoxy)ethyl thiooyanate

Butoxypolypropylene glycol (Fly repellent)

Metaldehyde

»Organophosphorus insecticides:

Bis(dialkoxyphosphinothioyl) disulfides

S-[l,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos-

phorodithioate (Malathlon). l,2-Dibromo-2,2-diohloroethyl dimethyl phosphate (Naled).

2,2-Dichlorovinyl dimethyl phosphate (DDVP)

0,0- Diethyl S- [2- ( ethylthio ) ethyl] phosphorodlthioate- 0,0-Diethyl 0-[2-(ethylthio)ethyl1 phosphorothioate— - 0,0-Diethyl S- [2- ( ethylthio ) ethyl] phosphorothioate- -- 0,0-Diethyl S-[( ethylthio )methyl] phosphorodithioate--

0,0- Diethyl phosphorochloridothioate

Diethyl phosphorochloridothionate

Dimethyl 3-hydroxycrotonate, dimethyl phosphate ester- 0,0- Dimethyl phosphorochloridothioate

Ifenufacturers ' identification codes (according to list in table 22)

CIS, DUP, RH.

CIS, DUP, FMN, RH.

FMN.

ACT.

DUP. DUP. DUP. DUP. WHC. DUP. DUP. MRT. WRC. MLD.

ASL. MON. MON.

DOW.

RBC.

SF.

ACG.

ASL,

CLY,

ASL.

VIN.

SF.

CHG.

VC.

DOW.

MON.

LIL,

UCC. COM.

FMN. ACY.

SHC. CHG. CHG. CHG. ACY. MON. VIC. SHC. MDN.

CLY, VIN. VIN.

SF, UCC, USR, VIN.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

177

TABLE 20B.

-Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, i564--Continued

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICAI^, ACYCLIC— Continued

*Inseotioides Continued

*Organophosphorus insecticides Continued

Dimethyl phosphorochloridothionate

Ethyl methylene phosphorodithioate (Ethion)

»Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP) S-2-(Ethylsulfinyl)ethyl 0,0-dimethyl phosphoro- dithioate . Methyl 3-hydroxycrotonate, dimethyl phosphate ester---

All other organophosphorus insecticides

2-Thiooyanatoethyl laurate

■xRodentioides: Sodium fluoroaoetate

*Soil conditioners: Polyacrylonitrile, hydrolyzed, sodium

salt. *Soil fumigants:

*Bromomethane (Methyl bromide)

Chloropiorin (Trichloronitromethane)

*l,2-Dibromo-3-chloropropane

1,3-Dichloropropene

1,3-Dichloropropene, 1,2-dichloropropane

N-Methyldithiooarhamic acid, sodium salt

Manufacturers' identification codes (according to list in table 22)

VIC.

FMNj EMP. ALC, AMP, OTH. CHG.

SHC. ACY.

X.

RBC. ACY.

AMP, DOW, FRO, GTL, MCH.

DOW, IMC.

AMP, DOW, SHC.

DOW.

DOW, SHC.

DUP, SF, X.

178

SYNTHETIC ORGANIC CHEMICALS, 1964

Miscellaneous Chemicals

TABLE 21B.-

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer , 1964

[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (■•*); chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. Jto x signifies that the manufacturer did not consent to his identification with the designated product]

Chemical

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC

6-Acetoxy-2,4-dimethyl-m-dioxane

Adenine

Adenosine derivatives

Alkylpiperazine quaternary ammonium compounds

2-Aminobenzothiazole

l-(2-Aminoethyl)piperazine

Aminopropylmorpholine

Aryldiamines, mixed

Barium octylphenate

Benzoic acid salts:

Aluminum benzoate

Ammonium benzoate

Bari\mi benzoate

Cadmium benzoate

Calcium benzoate

*Sodium benzoate, tech

*Sodium benzoate, U. S.P

Zinc benzoate

All other

p-Benzoquinone (p-Quinone)

Benzothiazole

^Benzoyl peroxide

Benzoylresorcinol

Bibenzyl (Dibenzyl)

Biological stains

2,6-Bis(C5-C2o alkyl)-p-cresol

Bis(2,'4-dichlorobenzoyl) peroxide

Bis[l-(2-methyl)aziridinyl]phenyl phosphine oxide

1,'4-Bis[ 2- (A-me thy 1-5-phenyloxazolyl)] benzene

l,'4-Bis[2-(5-phenyloxazolyl)] benzene

Boron fluoride-phenol complex

a-[2-(2-Butoxyethoxy)ethoxy] -4,5-methylenedioxy-2-propyl- toluene (Piperonyl butoxide) .

*Butyl benzoate

p-tert-Butylbenzoic acid, barium bis-salt

(n-Butylcyclopentadienyl-cyclopentadienyl) iron

2(and 3)-tert-Butyl-i-methoxyphenol

p-tert-Butyl-a-methylcinnamaldehyde

tert-Butyl peroxybenzoate

4-tert-Butylpyrocatechol

Camphene

d-Camphor-p-sulfonic acid

Catecholdisulfonio acid, disodium salt

Cellulose acetate phthalate

Centralite-1 (N, N'-Diethyl-N, N'-diphenylurea)

Chemical indicators

Chemical reagents

Chloramine B (, Sodium derivative of N-chlorobenzenesulfon- amide) .

Chlorinated terphenyls

o-Chlorobenzylidenemalononitrile

Chlorophyllin, sodium-potassium-copper

Cobalt phthalocyaninedisulfonic acid

Copper phthalocyaninedisulfonic acid

Cumene hydroperoxide

Cyanuric acid

Cyolohexanone peroxide

GIV.

KF.

PLB, SBR.

HOU.

FMT.

JCC.

JCC.

DA.

CCA.

GAM. CCW. CCW. QIC.

HN.

HK, HN, MON, TNP.

CCW.

PLB.

EKT.

ACY.

AZT, CAD, NOC, OXY, RCI, SDH, UPR, WTL.

BKL, G.

GIV.

HLC, NAC.

EKT.

CAD, OXY.

ICO.

ARA.

ARA.

ACG.

FMN, FMP.

CIN, CCA. ARA. EKT, GIV. WTL. BKL, GLD, ARA. ICO.

X.

OTC, EK, ACG, NES.

FRO, TNP.

DOW. HPG.

PAS. HLC, LAM, NAC. EK, GFS, HLC, LAM, NAC, PIC.

KPT. GAM. KCH. NAC. NAC. HPC. FMB. NOC, UPR, WTL.

MISCELLANEOUS CHEMICALS

TABLE 21B. -Miscellaneous chemicals for which U.S. production or sales were reported identified bv

manufacturer, i 564 —Continued '

179

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Cyclohexene-l,2-dioarboxyliG acid (Tetrahydrophthalio acid) disubstituted, polyester salts: Barium and cadmlu salts .

1,4-Cyclohexylenedimethanol

^Cyclopropane

Cytidine and derivatives

Decahydronaphthalene (Decalin)

Decyl diphenyl phosphite

2,5-Di-tert-ainylhydroquinone

l,4-Diazabicyclo[2.2.2] octane ( Triethylenediamine )

Diazodinitrophenol

l,3-Dibromo-5,5-dimethylhydantoin

3,5-nibrofflo(and 3j4',5-tribroino)salicylanilide

4',5-Dibroiiio(and 3,4',5-tribromo)salicylic acid

2, 6-Di-tert-butyl-p-eresol :

*Food grade

«Tech -.VSSS.".

2,5-Di-tert-butylhydroquinone .

ZjS-Di-tert-butylquinone

Dibutyltinbis(cyolohexyl maleate)

2j 6-Dichlorobenzaldehyde oxime

l,3-Diohloro-5,5-dimethylhydantoin

Dichloro-s-triazine-2, 4, 6( IH, 3H, 5H) trione ( niohloroiso-

cyanuric acid) . nichloro-s-triazine-2,4,6(lH,3H,5H)trione, potassium salt-

nlohloro-s-triazine-2,4,6(lH,3H,5H)trione, sodium salt

Dioyclohexylammonium nitrite

Mcyclopentadienyloobalt

Dicyclopeutadienyliron

Dideoyl phenyl phosphite

Digitonin

2,2'-Dihydroxy-<i,4.'-dimethoxybenzophenone

2,6-mhydroxylsonicotinic acid (2,6-Dihydroxy-4-carboxy- pyridine ) .

2>2'-Dihydroxy-4-methoxybenzophenone

2)2'-nihydroxy-4-(ootadecyloxy)benzophenone

3,4-Dihydroxyphenylacetic acid

3,5-Diiodosalicyllc acid

Misopropylbenzene hydroperoxide, mixed isomers

Dilsopropyl-m,p-oresols ;

Diisopropyl-m,p-cresols, mixed

p-Dimethoxybenzene (Dimethyl ether of hydroquinone )

2,5-Dimethyl-2,5-di(peroxyphenyl)hexane

2,5-Dimethylhexane-2,5-di(peroxybenzoate)

DLmethyljnorpholine

4,4-mnitrocarbanilide-4,6-diiiiethyl-2-pyrimldinol

rdoxane (1,4- methylene oxide)

2,5-ia.phenyl-p-benzoquinone

M-phenyloxazole

Diphenyl phosphite

l>3-Ei--o-tolylthlourea

4-Dodeeyloxy-2-hydroxybenzophenone

Hizymes :

l^rolytic :

Amylases

Proteases

Other I.IIII

Nonhydrolytio

Other IIIIIIII.

l,2-Epoxy-3-phenoxypropane (Glyoidyl phenyl ether)

6-Ethoxy-m-anol (Propenylmethylguaethol)

5-Ethyl-10,10-diphenylphenylphenazasiline

Ethylenediaminebis[o-hydroxyphenylacetio acid], monosodium

ferric salt.

Ethylglucosyl p-aminobenzoate

2-Ethylhexyl oetylphenyl phosphite

2-Ethylhexyl salicylate

2-Ethylhexyl tallate

Ethyl hydrocaffeate

*Ethylmorpholine

Fenchone

Manufacturers ' identification codes (according to list in table 22)

EKT.

MAL, OH, OMS, TAE.

PLB, SBR.

DUP.

HK.

EKT.

HOU.

HPC.

AHA.

FIN.

FIN.

CAT, EKT, HPC, KPT, SHC. CAT, EKT, HPC, KPT, PIT, SHC. EKT. EKT.

X.

ore.

GLY.

FMB, MON.

FMB, MON.

EMB.

OMC.

AHA.

ARA, TNA.

HK.

PEN.

G.

EK.

ACY. ACY.

LIL.

MRT.

HPC.

GIV.

GIV.

ASL, ICO.

WTL.

UPR.

DOW.

MRK.

DOW, UCC.

EKT.

ARA.

HK.

PBC.

EKT.

BAX, CRN, OMS, PMP, RH, WBC.

BAX, PMP, RH, WBC.

RH, WBC.

MO, MLS, WBC.

PLB.

SHC.

ICO.

MRK.

GGY.

VND.

VC.

ICO.

UCC.

ICO.

BC, JCC, UCC.

HNW.

180

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.-

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964— Continued

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICAI£, CYCLIC— Continued

*Flotation reagents:

BenzoyIthiono-1-ethylpropyl carbamate (Benzamate)

Dioresylphosphorodithioic acid (Dioresylthiophosphorio acid) .

Dioresylphosphorodithioic acid, ammonium salt

Dioresylphosphorodithioic acid, sodium salt

2,2'-Dimethylthiooarbanilide (Di-o-tolylthiourea)

Rosin amines

Thiocarbanilide (Diphenyl thiourea)

Furan derivatives:

2-Furaldehyde (Furfural)

Tetraliydrofurfuryl alcohol

Gallic acid, all grades

gasoline additives:

N,N'-Bis(l,4— dimethylpentyl)-p-phenylenediamine

2,6-Di-tert-butylphenol

*N,N'-Di-sec-butyl-p-phenylenedi amine

N,N'-Diisopropyl-p-phenylenediamine

Di(nonylphenol) salt of triethylenetetramine

*N,N'-Disalioylidene-l,2-propanediamine

Methylcyolopentadienylmanganese trioarbonyl

2,2'-Thiobis [6-tert-butyl-4-methylphenol]

All other

Glyceryl p-amlnobenzoate

Guanosine phosphates

Hesperidin

Hexa(2-methylaziridinyl)-l,3,5-phosphotriazine

*Hexamethylenetetr amine , tech

Humic acids, sodium salts

Hydrocinnamio acid

o-(2-Hydroxy-p-anisoyl)benzoic acid

N-(2-Hydroxyethyl)gentisamide

2-Hydroxy-'i-methoxybenzophenone

2-Hydroxy-4-methoxy-5-sulfobenzophenone trihydrate

Hydroxymethyl-5,5-dimethylhydantoin

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole

2-Hydroxy-4— n-octoxybenzophenone

2-(2-Hydroxyphenyl)-4(3)-quinazolone

l-Hydroxy-2-pyridine (Omadine)

2-Imidazolidinethione (l,3-Ethylene-2-thiourea)

Inosine and phosphates

Isoamyl p-dlmethylaminobenzoate

Isocyanuric acid

Isocyanuric acid, sodium salt (Sodium isocyanurate)

Isopropyl-o-cresol

Isopropyl-p-cresol

p-Isopropyl-a-methylcinnamaldehyde

Isopropyl tallate

Isosorbide

Ketene, dimer

Laurylmorpholine

Lemon biflavonoid

*Lubricating oil and grease additives:

Chlorosulfurized and sulfurized compounds:

Alicycllc compounds, sulfurized

Heterocyclic compounds, sulfurized

Liquid disulfide

Tall oil ester, sulfurized

Terpenes, sulfurized

Oil-soluble petroleum sulfonates:

Oil-soluble petroleum sulfonate, ammonium salt

*Oil-soluble petroleum sulfonate, barium salt

*Oil-soluble petroleum sulfonate, calcium salt

*Oil-soluble petroleum sulfonate, sodium salt

All other

Phenol salts:

Bariimi salt of dodecylphenol

Barium salt of nonylphenol

Calcium salt of ootylphenol-formaldehyde

DOW. ACY.

ACY. KCU.

ACY, DUP. HFC. ACY, NAC.

QKO. QKO. MAL.

EKT.

TNA.

DUP, EKT, UPM.

DUP, EKT.

SPP.

DUP,

TNA.

CAT.

EKT, UPM.

VND.

PLB, SBR.

SKG.

ICO.

EKT, SOI, SPP, TNA, TX, UPM.

NLC. ICO. ACY. ICO. ACY. ACY. GLY. GGY. ACY.

X.

OMC.

PAS.

PLB,

VND.

MON.

FMB.

CP.

GIV.

GIV.

DEX.

APD.

EKT.

BC.

SKG.

G, SOI. ORO.

LUB. LUB.

DUP, HKD, HMP, HN, PLS, UCP.

SIN.

ATR, LUB, TX, WTC.

LUB, ORO, SHO, SOI, SON, WTC, x.

ENJ, MDR, NOP, PAR, SHO, SOC, SOI, SON, TX, WTC.

CO.

TX.

CCA.

SHC.

MISCELLANEOUS CHEMICALS

181

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MISCELLAMEOUS CHEMICALS, CYCLIC— Continued

*Lubrioating oil and grease additives Continued

Phenol salts Continued

Calcium salt of polypropylphenol

All other phenol salts

All other

p-Menthane

8-p-Menthyl hydroperoxide

•4-Methoxyphenol

N-Methylanthranilic acid

2-Methylaziridine

Methylcentralite (N,N'-Diinethyloarbanilide)

2,2'-Methylenebis ["4-ohlorophenol] ( Diohlorophene )

4,4'-Methylenebis [2,6-di-tert-butylphenol]

Msthylenebls[5,5-dimethylhydantoin]

2,2' -Methylenebis[ 3, <i, 6-triohlorophenoll ( Hexaohlorophene 2,2'-lfethylenedi-p-cresol (Bis(5-methyl-2-hydroxyphenyl)

methane ) .

Methylglucoside

"i-Methylmorpholine

lfethylnorbomene-2,3-dioarboxylic anhydride (Methylbi-

oyolo-(2.2.1)heptene-2,3-carboxyllo anhydride).

Methyl phenyl phosphates

5-Methyl-5-n-propyl-in-dioxan-2-one

l-Methyl-2-pyrrolidone, monomer

»Morpholine

Mbrpholine salt of p-toluenesulfonic acid

*Naphthenic acid salts:

Aluminum naphthenate

Barium naphthenate

Cadmium naphthenate

»Caloium naphthenate

Cobalt lead manganese naphthenate

»Cobalt naphthenate

*Iron naphthenate

Lead manganese naphthenate

»Iiead naphthenate

Lithium naphthenate

*Manganese naphthenate

Nickel naphthenate

Rare earths naphthenate

Sodium naphthenate

Strontium naphthenate

*Zinc naphthenate

o-Nitrobenzoic acid and sodium salt

5-Norbomene-2-methanol (Bicyclo [2.2.1] hept-5-ene-2-

methanol) and acrylate ester. Ootylphenyl acid phosphate

LUB, MDN, OHO, SIN, x.

LUB, MDN, ORO, SIN, SPP, TNA, TX.

OKD.

ENJ,

ENJ,

HPC.

HNW, HPC.

ASL, EKT, ICO.

GIV.

ICO.

OTC.

GIV.

SHC.

GLY.

GIV.

GIV.

CRN.

JCC, UCC. ICO.

DOW, JCC, UCC. AMB.

HSH, WTC. CCA, QCP. CCA, HSH. CCA, FER, HNX, HSH, MCI, MLD, MR, SHP, SOC, SPP, SRR,

SW, TRO, WTC. HNX, HSH. CCA, CCC, FER, HNX, HSH, MCI, MLD, MON, MR, SHP, SOC,

SPP, SRR, SW, TRO, WTC. CCA, HNX, HSH, MCI, MLD, SOC, WTC. CCA. CCA, CCC, CCW, FER, HNX, HSH, MCI, MLD, MR, QCP, SHP,

SOC, SPP, SHE, SW, TRO, WTC. CCA. CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SPP, SRR,

SW, TRO, WTC. CCA.

CCA, HNX. CCA. CCA. CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SRR, SW,

TRO, WTC. WAY. ICO.

VC.

182

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

IQSCEIiANEOUS CHEMICALS, CYCLIC— Continued

Organic mercury compounds:

Phenyl mercuric borate

Pyridyl mercuric acetate

Pentachloronitrobenzene

Pentaerythrityl tetra( diphenyl phosphite)

o-Phenanthroline

Phenolthiosulfonic acid

2-Phenoxyethanol (Ethylene glycol monophenyl ether)

2-(2-Phenoxyethoxy)ethanol (Diethylene glj-col phenyl ether) .

2-Phenoxy-l-propanol

Phenyl acid phosphate

Phenyl benzoate

2j2'-(p-Phenylene)diethanol

Phenyltrimethylammonium chloride

Photographic chemicals:

N-(o-Aoetamidophenethyl)-l-hydroxy-2-naphthamide

2-(<i-Jtaiino-N-ethyl-in-toluidino) ethyl sulfate

^-Mino-6-methylguaiacol (2-Methyl-6-methoxy-'i-amino- phenol hydrochloride).

3-Amino-l,2,'i-triazole (5-Amino-l,3,4-triazole)

»Benzotriazole

p-Benzylaminophenol hydrochloride

2,2','V,'4'-Biphenyltetrol

Catechol (Pyrocatechin)

3-Chloro-<i-diethylaminobenzenediazonium chloride

(p-Dlazo-2-chloro-N,N-diethylaniline) - zinc chloride.

2,4-Diaminophenol dihydrochloride (Amidol)

N-(A-Diazo-2,5-dibutoxyphenyl)morpholine

N-('4-Diazo-2,5-diethoxyphenyl)morpholine

4-Diazo-l-morpholine benzene

2,5-Diethoxy-4-morphinyldiazonium chloride - zinc chloride . *p-Diethylaminobenzenediazonium chloride (p-Diazo-N, N- diethylanlline) - zinc chloride. p-Diethylaminobenzenediazonium (p-Diazo-N, N-diethyl- aniline) f luorobor ate .

N, N-Diethyl-p-phenylenediamine hydrochloride

N,N-Dlethyltoluene-2,5-diamine, monohydrochloride

2,5-Dihydroxy-p-benzenedisulfonio acid, dipotassium salt

2,5-Dihydroxybenzenesulfonic acid

2,7-Dihydroxy-3,6-naphthalene sulfonate

»p-Dlniethylaminobenzenediazonium chloride (p-Diazo- N,N-dimethylaniline) - zinc chloride. 4-(2',6'-Dimethylmorpholinyl)benzenediazonium chloride - zinc chloride.

p-Diphenylaminediazonium sulfate

p-(N-Ethylbenzimldo)benzenediazonium chloride (p-Diazo-

N-benzyl-N-ethylaniline) - zinc chloride. p-[Ethyl(2-hydr6xyethyl) amino] benzenediazonium chloride (p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc chlo- ride.

N-Ethyl-N-hydroxyethyl-p-phenylenediamlne sulfate

N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5-di amine sulfate .

Hydroquinone (Hydroquinol)

p- [(2-Iferdroxyethyl)methylamino] benzenediazonium chloride (p-Diazo-N-hydroxyethyl-N-methylaniline) - zinc chloride . 3-Ifydroxy-N-(2-hydroxyethyl)-2-naphthamide (p-Oxynaph-

thoicmonoethanolamlde) . N-(p-Hydroxyphenyl) glycine

WRC.

MAI.

OTC.

HK.

COK.

G.

DOW, JCC.

DOW.

ICO.

VC.

CIN.

EKT.

BKL.

EKT. EKT.

FMT.

EK, FMT, MEE, MRT.

EK.

FMT.

KPT.

FMT.

VPC. IDC. IDC. FMT. G.

FMT, G, IDCj MRT.

IDC.

EKT, FMT. EKT, FMT.

X.

EK.

FMT.

FMT, G, IDC.

FMT. FMT, MRT.

FMT, IDC.

IDC.

EKT.

EKT. FMT, IDC.

FMT. IDC.

MISCELLANEOUS CHEMICALS

183

TABLE 21B.-

- Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer , 1964 Continued

Manufacturers ' Identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Photographic chemicals Continued

l-(3-I^droxyphenyl)urea

4— Methoxy-1-naphthol

p-Methylaminophenol sulfate (Jfetol)

S-lfethylbenzotriazole

•4-M)rpholinylbenzenediazonium chloride - zinc chloride salt.

"i-MDrpholinylbenzenediazonium fluoroborate

6-Nitrobenzimldazole

Octylphenyl salicylate

Phenyljnercaptotetrazole

l-Phenyl-3-pyTazolidinone

4- Phenylpyrooatechol

2-Resorcylic monoethanolamide

ij'i'-Thiodlresoroinol (Diresorcyl sulfide)

l-(2,'i,6-Triohlorophenyl)-3-('i-nitroanillno)-2-pyraz- olln-5-one.

All other

Phthalio acid, lead salt, dibasic

*Plnene

Polyethylene terephthalate

Poly-2-hydroxy-4.-inethacryloxybenzophenone

Polyvinyl phthalate

Propyl gallate

i^ogallol (I^ogallio acid)

Eesorcinol monobenzoate

Ribonucleic acid and derivatives

Rosin acid salts :

Aluminum resinate

Calcium resinate

Copper resinate

Iron resinate

Lead resinate

Manganese resinate

Zinc resinate

Salicylanillde

Salicylic acid, lead salt

Silicones

Sodium oresoxide (Cresylio acid, sodium salt)

Sucrose benzoate

Sulfosalicylic acid

Tall oil fatty acid chloride-

*Tall oil salts ( linolelc-rosin acid salts):

*Calcium tallate

*Cobalt tallate

Copper tallate

*Iron tallate

Lead manganese tallate

*Lead tallate

*<Manganese tallate

Zinc glyceryl tallate

ifZino tallate

Tannic acid

EK,

FMT.

IDC.

IDC.

EK,

FMT.

EKT.

TNC.

GGY,

WAY.

X.

FMT.

BKC.

EKT.

EK,

EKT, FMT, G.

NTL.

CBY,

GID, HNW, HPC

DUP.

DUP.

EK.

EKT,

HN, HSH.

MAL.

EKT.

SBR.

JMS.

JMS,

SW.

JMS.

HSH,

JMS.

JMS,

MCI.

JMS.

JMS,

SW.

DUP,

FIN, MEE.

NTL.

DCC.

DEX,

GOC.

TNP.

MON,

MRK.

CCA, HNX, HSH, MCI, MLD, TRO, WTC.

CCA, CCC, FER, HNX, MCI, MLD, SHP, SRR, TRO, WTC.

CCA, MCI, MLD, SHP, SRR.

CCA, MCA, MCI, MLD, SRR, WTC.

HSH, MCI.

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SPP, SRR, TRO,

WTC. CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC. CCA.

CCA, HSH, MCI. HSH, MAL.

184

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.-Miscellaneou^ chemicals for which U.S. production or sales were reported, identified by manufacturer, i 964— Continued

Chemical

mSCELLANEOUS CHE1CCAI5, CYCLIC— Continued

wTarniing materials, synthetic:

Hydroxytoluenesulfonio acid, formaldehyde condensate (Cresol-formaldehyde sulfonate), sodium salt. »2-Naphthalenesulfonic acid, formaldehyde condensate and

salts. ^ .

*l-Phenol-2-sulfonic acid, formaldehyde condensate (Phenol-formaldehyde, sulfonated). Styrene malelc anhydride Interpolymer, partial sodium

Sulfonyldiphenolsulfonlc acid, formaldehyde condensate- All other " '

Tetra(n-butyl) ammonium picrate

1,2,3,4-Tetrahydxonaphthalene (Tetralln)

Tetrahydrothiophene '2".

Tetraphenyltin "

^<Textile chemicals, other than surface-active agents: l,3-Bis(hydroxymethyl)-2-imidazolidone (Dlmethylol

ethylene urea).

N',N'-Diphenyl-l,2-propaiiediamlne

1- ICOctadecyloxyimethyl] pyridinlum chloride

Phenol, Eulfurated '7"T""J"'

Tetrahydro-3,5-bis(methoxymethyl)-4H-l,3,5-oxadiazin-<;-

one.

2,2' ,4,'i' -Tetrahydroxybenzophenone

2-Thenoyltrifluoroacetone

2,2'-ThiobiB[4-ohlorophenol]

2,2'-Thlohis[4,6-dlchlorophenolJ

[ 2,2'-Thiobis(4-octylphenolate)] -n-butylamlne nickel

Thymidine and phosphates

o-Toluidine-formaldehyde hydrochloride

o-Tolylbiguanlde

3,4' ,5-Tribromosallcylanilide

3,4,4' -Triohlorooarbanlllde

Triohloromelamine """7 '"'

l,3,5-Trichloro-s-trlazlne-2,4,6(lH,3H,5H)trione (Trl-

ohloroisocyanuric acid) . Tri-(m,p)-creByl borate

Triethanolamlne salicylate

s-Trioxane

Trlphenyl phosphite

Triphenylphosphorus

Triphenyltln hydroxide

Tris(l-azirldinyl)phoEphlne oxide

2,4,6-Tris(2-hydroxy-4-ootyloxyphenyl)-s-triazine

Tris[l-(2-methylaziridinyl)]phosphine oxide—

Tris(2-methylazirldtnyl)-l,3,5-trlazine-

Uridine and derivatives

l-VInyl-2-pyrrolldlnone, monomer and polymer

l-Vinyl-2-pyrrolldinone - vinyl acetate copolymer

MISCELLANEOUS CHEMICALS, ACYCLIC

Aoetacetamidoacetamide

»Acetaldehyde

Aoetamide

Acetamidine hydrochloride

2-Acetamldoethanol (N-Acetylethanolamlne) - *Acetio acid, synthetic, 100^

Manuf actiirers ' identification codes (according to list in table 22)

AKS, GRD, NOP, NYC, RH. MAC, NOP, RH.

G.

MS. MED. DUP. ORO, PAS.

ACY, AKS, X.

SNW. DUP. G. DEX.

G.

CLE.

GIV.

MDN, SDH.

ACY.

SBR.

HBC.

MON.

FIN.

MON.

IIVTH.

FMB, M)N.

USB. ICO. CEL. HK, MON.

CEM.

X.

ICO.

ICO.

PLB, SBR.

G.

G.

RBC.

BFG, CEL, COM, DUP, EKT, HPC, MDN, PUB, SHC, UCC.

ACG. MRK. RBC. CEL, EKT, HPC, PUB, UCC.

MISCELLANEOUS CHEMICALS

185

TABLE 21B.

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964— Continued

MISCELLANEOUS CHE\aCAI£, ACYCLIC— Continued

»Aoetic acid salts :

Aluminum acetate

Alujninum subacetate

Ammonium acetate

Barium acetate

Cadmium acetate

Calcium acetate

Chromium acetate

Cobalt acetate

*Copper acetate

Lead acetate

Lead subacetate

Lead tetraacetate

Magnesium acetate

Manganese acetate

Mercuric acetate

Methylmercuiy acetate

Nickel acetate ,

*Potassiimi acetate

Silver acetate

»Sodiijm acetate

Sodium diacetate

Strontium acetate

Uranyl acetate

»Zinc acetate

Zirconium acetate

*Aoetic anhydride, IOO56:

From acetaldehyde

From acetic acid, other than recovered, by the vapor -

phase process. From acetic acid, recovered, by the vapor-phase process

From ethylene

Acetin :

Ifono

Tri

*Acetone :

From cumene

*From isopropyl alcohol

All other

Acetone, dimethyl acetal (2,2-Dimethoxypropaiione)

Acetone semicarbazone

Acetonitrile

Acetyl chloride

Acetyl peroxide

Aconitlc acid

Acrolein (Acrylaldehyde)

^Acrylic acid

Acrylic monomers

*Acrylonitrile

*Adlpic acid

Adiponitrile

Adipoyl chloride

*Alcohols, monohydric, unsubstituted : *Alcohols C9 or lower:

Allyl alcohol

Manufacturers ' identification codes (according to list in table 22)

AQf

UCC.

MAL

ACG

BKC

MAL

WSN

ACG

BKC

MAL

HSH

MAL.

ACG

BKC,

MAL

WSN.

ACY.

BKC,

HSH,

SHP.

ACG,

BKC,

UCC.

ACG,

BKC,

MAL,

SRR,

SW.

ACG,

BKC,

MAL.

AHA.

ACG,

BKC.

HSH,

SHP.

BKC,

MAL.

DUP.

BKC,

HSH,

SHP.

ACG,

BKC,

CWL,

MAL,

ncc

WSN.

MAL.

ACG,

BKC,

CEL,

DAN,

EKT

MAL, UCC

UCC,

WSN.

BKC.

BKC.

ACG,

BKC,

HSH,

MAL,

SNW,

UCC.

NTL,

SNW.

HPC.

CEL,

EKT.

CEL.

UCC.

KES.

EKT,

WM.

ACP,

CLK,

HPC,

MON,

SHC,

SKO, SOC.

EKT,

EN J,

SHC,

UCC.

CEL,

HPC.

DOW.

NOR.

EKX,

UCC.

TBK.

WTL.

PCW.

SHC,

UCC.

BFG,

CEL,

DBC,

MMM,

RH,

UCC.

RH.

ACY,

BFG,

DUP,

MON,

SOH,

UCC.

DUP,

MDN,

NAC,

RH.

DUP,

MON.

TBK.

DOW,

SHC.

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLiE 21B. -- Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

»AlcoholE, monohydric, unsubstltuted Continued *AloolioIs C9 or lower Continued *Amyl alcohols: Unmixed :

a-Methyl-a-tutanol (tert-Amyl alcohol)

1-Pentanol

2-Pentanol

3-Pentanol

Mixed:

Fusel oil, refined

(Jther than fusel oil:

Primary mixed

Secondary mixed

Other

*Butyl alcohols: Primary:

Iso { Isopropylcarbinol)

^Normal (n- Propylcarbinol)

Secondary (Methylethyloarbinol)

Tertiary ( Trimethylcarbinol)

Mixed

*Ethyl alcohol, synthetic

2-Ethyl-l-butanol (sec-Hexyl alcohol)

2-Ethyl-l-hexanol

2-Ethyl-4-methyl-l-pentanol

4-Ethyl-l-octyn-3-ol

»Hexyl alcohol

l-Hexyn-3-ol

*Iso-octyl alcohols

*Isopropyl alcohol

»Methanol, synthetic

2-Methyl-3-buten-2-ol

2-Methyl-3-butyn-2-ol - -

4-fcfethyl-2-pentanol ( 1-Methylisobutylcarbinol)

3-Methyl-l-pentyn-3-ol (Methylparafynol)

1-Octanol

2-Octanol

Pinacolyl alcohol (3,3-Dimethyl-2-butanol)

Propyl alcohol (Propanol)

2-Propyn-l-ol

All other

*Aloohols Cio or higher:

»Decyl alcohols

3,9-Diethyl-6-tridecanol

»Dodecyl alcohol (Lauryl alcohol) (95^)

7-Ethyl-2-methyl-4-hendecanol

*l-Hexadecanol (Cetyl alcohol) (95^)

»1-Octadecanol (Stearyl alcohol) (955t)

cis-9-Octadecen-l-ol (Oleyl alcohol)

Tallow alcohol

1-Tridecanol

2,6,8-Trimethyl-4-nonanol

All other

Aldol (Acetaldol)

Aliyl and aliylene hydrocarbons

Aliyl mercaptoacetic acid

Aliyl sulfides, mixed

Manufacturers' identification codes (according to list in table 22)

PAS, UCC. PAS, UCC. UCC. EK.

PUB.

PAS. PAS. CEL,

PAS, UCC.

USI.

CEL, DBC, EKX, ENJ, SHC, UCC.

CEL, CO, DBC, EKX, ENJ, SHC, UCC.

ENJ, SHC.

SHC.

CEL, DBC, EKX.

DUP, EKX, ENJ, HPC, PSP, SHC, UCC,

UCC.

CEL, EKX, ENJ, SHC, UCC.

EKX.

AIR.

EKX, ENJ, UCC.

AIR.

EKX, ENJ, GOC, HOU, 0X0, SOI, TID, UCC.

ENJ, SHC, UCC.

"' ', MON, HH, SPN,

ACN, BOR, CEL, COM,

DUP, ESC, GH

UCC.

AIR.

AIR.

ENJ, SHC, UCC.

AIR.

DUP.

PG, RH, WIH.

KF.

CEL, UCC.

G.

CEL, EKX.

DUP, ENJ, GOC, HOU,

PG, TID, UCC

UCC.

DUP, PG, RH.

UCC.

ADM, DUP, ENJ, GIV,

RH.

ADM, DUP, PG, RH.

ADM, DUP.

ADM.

ENJ, GOC.

UCC.

CO, PG, RH.

UCC.

ADM, GOC, HMf.

ENJ.

ORO.

miscellaneous! chemicals

187

TABLE 21B.

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, iS64 --Continued

Manufacturers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

l-Allyl-3-(2-hydroxyethyl)-2-thiourea (N-|3-Hydroxyethyl- N'-allyl thiourea) .

Allyl isocyanate

Allyl isothiooyanate, nonflavoring grade

Allyl methacrylate

Allyl nitrile (Allyl cyanide)

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)

3-(Allyloxy)-l,2-propanediol (Allyl glyceryl ether)

2-Allyl-4-pentenoic acid (Diallylacetic acid)

Allylpseudoionone

Aluminum isopropoxide (Aluminum isopropylate)

Amidinourea (Guanylurea) phosphate and sulfate

*Amines :

Butylamine

tert-Butylamine

Butylethylamine

Butylmethylainine

Cetyl dimethylamine

*Coconut oil amine

Cottonseed oil amines

Diallylamine

Dibutylamine

«Diethylamine

Diethylamine hydrochloride

2,2'-Diethyldihexylamine

Diethylenetriamine

N.N-Diethylethylenediamine

N ,N-'--Diethyl-l,4-pentaiiediamine ( Novoldiamine )

N,N-Diethyl-l,3-propaiiediamine

Diisobutylamine

Diisopropylamine

Dilaurylamine

*Dimethylamine

Dimethylamine hydrochloride

Dimethylamine sulfate

Dimethylmyrystylamine

N,N-Dimethyloctadecylamine (Stearyldimethylamine)

N,N-Dimethyl-l,3-propanediamine

Dipentylamine (Diamylamine)

Dipropylamine

Dipropylenetriamine

Dodeoylamine

Ethylamine

Ethylenediamlne

Ethylenediamine dihydrochloride

Ethylenediamlne sulfate

Hexadecylamine

1,6-Hexanedlamlne (Hexamethylenediamine)

3,3'-Iminobispropylamine

Isobutylamlne

*Isopropylamine

Lauryl dimethylamine

Methylamine hydrochloride

*Methylamine , mono-

Methyltriethylenedi amine

*Octadeoylamine

Octylamlne

^Oleylamine

Pentylamine (Monoamylamine )

Primary allsylamines , mixed

1,2-Propanediamine (Propylenediamine)

1,3-Propanediamine

Propylamine

Soybean oil amine

Tall oil amine

*Tallow amine

Tallow amine, dihydrogenated

*Tallow amine, hydrogenated

FMI, IDC.

CTN.

ICO.

SAH.

KF, RBC.

DOW, SHC

SHC.

X.

GIV.

CHT.

ACY.

EKT, PAS,

UCC

MDN, RH.

PAS, UCC.

PAS.

EC.

ADM, ARC,

CGL

FOR

GNM.

FOR.

SHC.

PAS, UCC.

DUP, PAS,

UCC

X,

VGC.

DOW, UCC.

COK.

SDH.

UCC.

PAS.

PAS, UCC.

GNM.

COM, DUP,

PAS,

RH.

ICO, TNC.

RH.

BC.

ARC.

JCC, UCC.

PAS.

PAS, UCC.

UCC.

ARC, FOR,

GNM.

ESC, PAS,

UCC.

DOW, JCC,

UCC.

BKC.

EK.

ADM, ARC.

DUP, MON.

JCC, UCC.

PAS.

ESC, PAS,

UCC,

VGC.

BC.

RBC.

COM, DUP,

ESC,

PAS,

RH.

JCC.

ADM, ARC,

CGL,

FOR,

GNM.

ADM, ARC,

RH,

UCC.

ARC, CGL,

FOR,

GNM.

ALB, EK,

PAS.

RH.

UCC.

UCC.

PAS, UCC.

ARC, CGL.

CGL, GNM.

ADM, ARC,

CGL,

FOR,

GNM.

ARC, FOR.

ADM, ARC,

CGL,

FOR,

GNM, HUM

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.- Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

^aSCELLANEOUS CHEMICALS, ACYCLIC— Continued

•Amines Continued

Tallow methylamlnes, dihydrogenated

Tetraethylenepentamine

N,N,N',N'-Tetraiiiethyl-l,3-"butaiiedlaiiiine

Tetramethylethylenediajnlne

Tributylamine

Tricaprylylamine

Tridodecylamine

Triethylamine

Triethylenetetramine

Trimethylainlne

Tripentylamine-

All other

2-Aiiiino-l-butaiiol

l-Aminoethanol ( Aeetaldehyde ammonia)

Aminoethoxyethanol

Aminoethoxypropylsilane

2- ( 2-Aminoethylamino) ethanol ( Aminoethylethanolamine )

2-Amlno-2-ethyl-l,3-propanediol

2-Aminoethyl vinyl ether

Aminoguanidine bicarbonate

2-Amino-2-(hydroxymethyl)-l,3-propanediol (Tris(hydroxy- methyl ) aminome thane ) .

2-Amino-2-methyl-l,3-propanediol

2-Amino-2-methyl-l-propanol

2-Aiiiino-2-methyl-l-propanol hydrochloride

*Amyl acetates, 90?t:

Aiiyl acetate (n-Pentyl acetate)

Isopentyl acetate (Isoamyl acetate)

Mixed

Azelaic acid

1,1' -AzobisfortDamide ( Azodicarbonamide )

2 , 2' -Azobis [2-methylpropionitrile] ( a , a' -Azodiisobutyro- nitrile).

Behenamide (Docosanainide)

Behenic acid

Bis[2-(2-butoxyethoxy)ethyl] ether ( Tetraethylene glycol

dibutyl ether) . Bis(2-butoxyethyl) ether (Diethylene glycol di-n-butyl ether).

Bis(2-chloroethoxy)methane ( Dichloroethylf ormal )

*Bis(2-ohloroethyl) ether ( Dichlorodiethyl ether)

Bls(2-chloro-l-methylethyl) ether (Dichloroisopropyl ether).

Bis(2,6-dimethyl-'i-heptyl) maleate

Bis(2-ethoxyethyl) ether (Diethylene glycol diethyl ether) .

Bis(hydroxyethyl) ether butynediol

l,3-Bis(hydroxymethyl)urea (Dimethylolurea)

Bis [2-(2-methoxyethoxy) ethyl] ether (Tetraethylene

glycol dimethyl ether) . Bis(2-metho3cyethyl) ether (Diethylene glycol dimethyl ether) .

Bis(perfluoroall!yl) phosphate diethanolamine salt

Bis(tributyltin) oxide

Biuret

Boron organic compounds:

Boron alcoholate

Boron fluoride ethyl ether complex

Boron trifluoride monoethylamine complex

Triethylborane

Manufacturers' identification codes ( according to list in table 22)

ARC,

FOR.

DOW,

UCC.

UCC.

RH.

PAS.

GNM.

GNM.

PAS,

UCC.

CCW,

DOW,

UCC.

COM,

DUP,

PAS,

RH.

PAS.

ALB,

ARC,

BRD,

CGL, DUP,

COM.

PAS.

JCC.

UCS.

DOW,

UCC.

COM.

MEE.

TRI.

COM.

COM.

COM.

SNW.

PUB,

TBK.

FB,

NW.

CEL,

PAS,

UCC.

EMR.

FMT,

NPI,

USE.

DUP.

HUM.

ADM.

RBC.

DOW,

UCC.

TKL

DOW

JCC

OMC

UCC, WYN

DOW

WYN

DEX, GLY, ASL.

SW.

SFA. ACG. ACG. CAL, TNA.

MISCELLANEOUS CHEMICALS

189

TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1 964 ~ C ontinue d

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Boron organic compounds Continued

Triethyl borate

Trimethoxyboroxine

All other

N-Bromoaoetamide

2-Bromo-N, N-dimethylethylamine ( Dimethylaminoethyl bromide) hydrobromide.

N-Bromosuoolnimide (Succinibromimide)

l,2(and l,3)-Butanediol (Butylene glycol)

l,<t-Butanediol

2,3-Butanedione 2-oxime

1,2,'4-Butanetriol

*2-Butanone (Methyl ethyl ketone)

Butanone mixture

*2-Butanone oxlme

*2-Butanone peroxide

2-Butene-l,<;-diol

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether)

2-Butoxyethanol (Ethylene glycol monobutyl ether)

2-(2-Butoxyethoxy)ethanol (Methylene glycol monobutyl

ether) . 2-[2-(2-Butoxyethoxy)ethoxy]ethanol (Triethylene glycol monobutyl ether).

2-(2-Butoxyethoxy)ethyl acetate

l-Butoxyethoxy-2-propanol

2-Butoxyethyl acetate

*Butyl acetates :

Iso ^^

^Normal

Secondary

Tertiary

Mixed

Butyl acrylate

Butylene oxide

Butyl ether (Di-n-butyl ether)

Butylethylthiourea

»tert-Butyl hydroperoxide

2,2' -(Butyllmino)diethanol (N,N-Bis(2-hydroxyethyl)butyl- amine).

Butyl lactate

n-Butyllithium

Butyl maleate, mono-

*tert-Butyl peroxide (Di-tert-butyl peroxide)

tert- Butyl peroxyacetate

tert-Butyl peroxylsobutyrate

tert-Butyl peroxypivalate

Butyl vinyl ether

1-Butyne ( Ethylacetylene )

2-Butyne-l,'i-diol

Butyraldehyde

Butyraldel^rde oxime

*Butyric acid

Butyric anhydride

Butyrolactone

Butyronitrile

Butyxyl chloride

*Caprolactam (Hexahydro-2H-azepin-2-one)

Caprolactone

*Carbon disulfide

Manufacturers ' Identification codes (according to list in table 22)

USB.

CAL.

CAL,

USB.

ARA.

BKL.

ARA.

CEL.

G.

EK.

G.

EN J,

SHC,

SPI,

UCC.

CEL.

ALB,

CCA,

MLD,

NAC,

TRO.

CAD,

NOC,

RCI,

UPR,

WTL.

G.

DOW,

SHC.

JCC,

QMC,

UCC.

JCC,

OMC,

UCC.

DOW,

CMC.

UCC.

UCC.

UCC.

CEL,

EKT,

ENJ,

PAS,

UCC.

CEL,

EKT,

ENJ,

PUB,

UCC.

EN J,

HPC,

PUB,

SHC.

ENJ.

CEL.

CEL,

DBC,

UCC.

DOW,

UCC.

UCC.

PAS.

AZT,

CAD,

UPR,

WTL.

PAS.

COM,

CWN,

UPC.

FTE.

RUB.

AZT,

CAD,

RCI,

SHC,

UPR, WTL.

WTL.

WTL.

WTL.

UCC.

AIR.

G.

CEL,

EKX,

UCC.

NAC.

CEL,

EKT,

UCC.

EKT,

UCC.

G.

EKX,

UCC.

HK.

DEC,

DUP,

NAC.

UCC.

ACG,

BKT,

EMB,

OLH,

PAS, PPG, SF

190 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, i 964- -Continued

Manufacturers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Cellulose esters:

Cellulose acetate butjrrate

Cellulose acetate propionate

Nitrocellulose (Cellulose nitrate)

^Cellulose ethers:

Ethyloellulose

Ethylhydroxyethylcellulose

Hydroxyethylcellulose

Methyloellulose

*Sodium carboxymethyloellulose, IOO56

Sodium carboxymethylhydroxyethylcellulose

Cetyl chloride

Cetyl lactate

*Chloral (Triohloroaoetaldehyde)

Chloroacetamide

*Chloroaoetic acid, mono-

Chloroacetic acid, mono-, derivatives:

Butyl chloroacetate

*Ethyl chloroacetate

Methyl chloroacetate

Sodium chloroacetate

Chloroaoetonitrile

Chloroacetyl chloride

Chlorocholine chloride

2-Chloro-l,l-dimethoxyethane (Dimethyl chloroacetal)

*2-Chloro-N,N-dimethylethylamine (Dimethylaminoethyl chloride) hydrochloride.

2-Chloro-N,N-dimethylpropylamine

2-Chloro-N,N-dlmethylpropylamine hydrochloride

3-Chloro-N,N-dimethylpropylamine hydrochloride

Chlorodimethylvinylsilane

2-Chloroethanol (Ethylene ohlorohydrin)

2-(2-Chloroethoxy)ethyl 2-chloroethyl ether (Triethylene glycol dichloride) .

2-Chloroethylamine

2-Chloroethyl vinyl ether

4— Chloro-3-hydroxybutyronitrile

Chloromaleic anhydride

P-Chloro-N-methylallylamine

Chloromethyl methyl ether

l-Chloro-l-penten-3-one (P-Chlorovlnyl ethyl ketone)

3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin)

l-Chloro-2-propanone (Chloroacetone)

N-Chlorosucoinimide (Succinichloriiolde)

*2-Chlorotriethylamlne hydrochloride

Chlorotrimethylsilane

Citric acid

Citric acid salts:

Ammonium citrate

Barium citrate

Calcium citrate

Ferric ammonium citrate

Ferric citrate

Ferrous calcium citrate

Potassium citrate

Sodium citrate

All other

EKT.

EKT.

DUP,

HPC.

DOW,

HPC.

HPC.

HFC,

UCC.

DOW.

BUK,

DUP, HPC,

KON, WYN.

HPC.

BC.

VND.

DA,

FMB, GGY,

MTO.

BPC,

DOW.

BUK,

DOW, HPC,

MDN.

MON.

DOW,

KF, MON.

BPC,

DOW, KF.

DOW.

BPC.

DOW,

DUP.

Acy.

LIL.

ABB,

GAM, HEX,

MCH, NES, PAS

SK.

NES.

MCH.

DCC.

CMC,

UCC.

UCC.

ICI.

UCC.

X.

RBC.

LIL.

HK,

X.

ABB.

BKL,

ICO, ore.

EK,

MRK.

NAC.

HEX,

MCH, NES,

PAS, X.

DCC,

UCS.

MLS,

PFZ.

MAL,

PFZ.

SW.

PFZ.

MAL,

PFZ.

MAL.

X.

MLS,

PFZ.

MLS,

PFZ.

MLS.

MISCELLANEOUS CHEMICALS

191

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 7564— Continued

Manuf aoti^rers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued

Coconitrile

Coconut oil amide

Cottonseed oil acids^ ammonium salt

Cottonseed oil nitrile

Creatine and creatinine

Crotonaldehyde

Crotonic acid (2-Butenoic acid)

Crotononitrile

2-Cyanoacetamide

Cyanoaoethydrazide

Cyanoaoetio acid

Cyanogen bromide

3-Cyanopropylamine

1,10-Deoanediol

Decanoyl chloride

*Decaiioyl peroxide

Dialdehyde starch

Diallylcyanamide

1,2-Dibutoxyethane (Ethylene glycol di-n-butyl ether).

2-Dibutylaminoethanol

»Dibutyl fumarate

*Dibutyl maleate

1,3-Di butyl -2-thioiirea

Dibutyltin compoiinds :

Dibutylmethoxytin (Dibutyltin methoxide)

Dibutyltin bis(lauryl mercaptide)

Dibutyltin dichloride

Dibutyltin dilaurate

Dibutyltin maleate

Dibutyltin mercaptopropionate

Dibutyltin oxide

All other

Dichloroacetaldehyde

Dichloroaoetic acid

2,2-Dichloro-l,l-diflviciroethyl methyl ether

Dichlorodimethylsllane

Dichlorohydrogenmethylsllane

Dichloromethylsilane

Diohloromethylvinylsilane r

l,3-Dichloro-2-propanol

2,3-Dichloro-l-propanol

Dicyanobutene

Diethoxydimethylsilane

Diethyl acetylsuccinate

Diethyl allyl(l-methylbutyl)malonate

Diethylaluminim chloride

Diethylaluminiim iodide

*2-Diethylaminoethanol

2-(2-Diethylaminoethoxy)ethanol

2-Diethylaminoethyl methacrylate

Diethylaminopropionamide

Diethyl sec-butylethylmalonate

Diethyl butylmalonate

Diethyl sec -butylmalonate

Diethylcarbamoyl chloride

Diethyl carbonate (Ethyl carbonate)

Diethyl diethylmalonate (Diethyl malonio ester)

*Diethylene glycol

Diethylene glycol, borated

FOR.

ARC,

CRT,

KES,

PC.

GLY.

FOR.

PFN.

CEL,

EKT,

UCC.

EKT.

KF.

KF.

KF.

KF.

EK.

EKT.

NEP.

TBK.

CAD,

UPR,

WTL.

MLS.

ACY.

DOW.

AAC,

PAS.

MON,

PCC,

PFZ,

RCI,

RUB.

AIR,

DUP,

MON,

PCC,

RCI, RUB

PAS,

RBC.

CCA.

X.

CCW,

X.

CCA,

X.

CCA,

GRH,

X.

CCA,

X.

FMB.

KF.

DOW.

DCC, UCS.

UCS.

DCC.

DCC.

EK.

UCC.

X.

UCS.

BPC.

HPC.

TNA, TSA.

TSA.

AAC, PAS, UCC.

PAS.

DUP.

BPC.

ABB.

GAM.

CTN, FMP.

BPC, LIL.

ACN, CAU, DOW, G, HCH, JCC,

GLY.

:, UCC, WYN.

192

SYNTHETIC ORGANIC CHEMICALS, )964

TABLE 21B.-MiscelUineous chemicals for which U.S. production or sales were reported, identified by lABi^£- iii-D. manufacturer, 1964— Contvmed

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICAIS, ACYCLIC— Continued

Diethylene gljcol chloroformate

Diethyl (ethoxymethylene)malonate

Diethyl ethylisopentylmalonate

Diethyl ethylmalonate (Ethyl malonic ester)

Diethyl ethyl(l-methylbutyl)malonate

Diethyl ethyl(l-methylpropyl)malonate

Dl-2-ethyl-l-hexyl fumarate

Di-2-ethyl-l-hexyl maleate

N, N-Diethylnydroxylamine sulfate

Diethyl maleate

^Diethyl malonate (Malonic ester)

Diethyl ( 1-methylbutyl) malonate

Diethyl (3-metlQrlbutyl) malonate

Diethyl methylmalonate

Diethyl (l-methylpropyl)malonate

Diethyl oxalate (Ethyl oxalate)

Diethyl succinate

Diethylthiophosphoryl chloride

l,3-Diethyl-2-thiourea

Diethylzino

Diglycolic acid

Dihexyl fumarate

Dihydropseudoionone ""

l,3-Dihydroxy-2-propanone (Dihydroxy acetone )-

Diisobutylaluminum

Diisobutylaluminum chloride

Diisononyl maleate-

Diisopropyl adipate "T'li," i ~'\

2-Diisopropylaminoethaiiol ( N, N-Diisopropylethanolamine) -

Diisopropylaninionium nitrite-

Diisopropylcarbodiimide

0 0-Diisopropyl dithiobis(thioformate) ----

Diisopropyl peroxydi carbonate (Isopropyl percarbonate)-

l,3-Diisopropyl-2-thiourea "'7'.'Z'. '■"

*Dilauryl 3,3'-thiodipropionate (Didodecyl thiodipropio-

nate) . ^ , j.%, \

Dlmethoxyethane (Ethylene glycol dimethyl ether) -—

N, N-Dimethylacetamide

N, N-Dimethylacetoacetamlde

*2-Dimethylaminoethanol

Dimethylamino-2-propanol

3-Dimethylaminopropionitrile

N-(3-Dimethylajninopropyl)oleamide

Dimethylcarbamoyl chloride

Dimethyl carbonate

2 5-Dimethyl-2,5-di(tert-butylperoxy)hexane

2^5-Dimethyl-2,5-di(tert-butylperoxy)hexyBe-3— --— --

N, N-Dimethylf ormamide ^"

Dlmethylglyoxime T"''r

2,6-Dimethyl-4-heptanol (Diisobutylcarbmol)

2',5-Dimethyl-2,5-hexanediol "--■

2,5-Dimethyl-3-hexyne-2,5-diol --"- --'

1, 1-DimethyIhydrazine ""

Dimethyl malonate _"

2,3-Dimethylpentaldehyde J"

Di(4-methyl-2-pentyl) maleate

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol)—

Dimethyltin dichloride

1,3-Dimethylurea-

Diootanoyl peroxide (Caprylyl peroxide) -

Dioctyl fumarate

PPG.

KF.

LIL.

LIL.

ABB, BPC.

BPC.

RUB.

CIN, RUB.

EK.

ACY, ICO, UCC.

ABB, KF, LIL.

ABB, BPC, LIL.

BPC.

BPC.

BPC.

FMP.

ICO. ACY.

PAS, RBC.

TNA.

DUP.

FB.

GIV.

BAX, PFZ.

TSA.

ISA.

RUB.

VND.

PAS, UCC.

OMC.

G.

DUP.

PPG.

G, PAS.

ACY, CCW, EVN, HAB.

ASL, OMC.

DUP.

EKT.

AAC, PAS, RH, UCC.

COM, PAS.

ACY.

DUP.

GAM, OTC.

FMP.

WTL.

WTL.

DUP.

EK.

UCC.

AIR.

AIR.

FMP.

KF.

UCC.

RUB.

EEC.

MISCELLANEOUS CHEMICALS

193

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported identified by

manufacturer, i£>fri— Continued

MrSCELLANEOUS CHEMICALS, ACYCLIC— Continued

*Diootyl maleate

l,3-Diootyl-2-thiourea

*Dipropylene glycol

Dlstearyl 3,3'-thiodipropionate

Dithiooxamide

Ditridecyl maleate

n-Dodeoane

»Dodecenylsuooinio anhyriride

n-Eicosane

*Epichlorohydrin

»Eruoajnide

Enioio acid

Ethanedithiol

*Ethanolamines :

*2-Aminoethanol ( Jtonoethanolamine )

*2,2'-Iininodiethanol (Diethanolamine)

*2,2' ,2" -Nltrilotriethanol ( Triethanolamine )

Ethanolamine hydrochloride

Ethanolamine sulfite

*2-Ethoxyethanol (Ethylene glycol monoethyl ether)

*2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl

ether) . »2-[2-(2-Ethoxyethoxy)ethoxy]ethaiiol (Triethylene glycol monoethyl ether).

2-(2-Ethoxyethoxy)ethyl acetate

2-Ethoxyethyl acetate

Ethoxymethylene malononitrlle

3-Ethoxypropionitrile

1-Ethoxy-l, 3,3-trimethoxypropane

»Ethyl acetate, S5$

*Ethyl acetoaoetate

*Ethyl aery late

Ethylali imi num dichloride

Ethylaluminum sesquichloride

2-Ethylaminoethanol (Ethylmonoethanolamine)

2-Ethylbutyraldehyde

2-EthylbutyTic acid (Diethylacetic acid)

Ethyl carbamate

Ethyl carbethoxyacetimidate

Ethyl carbodiimide

Ethyl <i-chlorobutyrate

Ethyl chloroformate

Ethyl 3-(chlorofonnyl)propionate (p-Carbethoxypropionyl chloride ) .

Ethyl cyanoacetate

Ethylene, from ethyl alcohol

Ethylene carbonate

*Ethylene glycol

Ethylene glycol diacetate

Ethylene glycol dimercaptoacetate

Ethylene glycol dimethaorylate

«Ethylene oxide

*Ethyl ether:

Absolute

Tech

U.S.P

*Ethyl formate

2-EthyIhexanal (a-Ethyloaproaldehyde)

2-Etliyl-l,3-hexanediol

2-Ethylhexanoic acid (a-Ethyloaproic acid)

Manufacturers ' identification codea (according to list in table 22)

CRT

ION

PCC

RUB.

PAS

CEL

DOW

JCC

OMC,

UCC

CCW

MAL.

^

RUB.

HMf.

HMf

MON,

NAG.

HMI.

DOW,

SHC,

UCC.

ADM,

FIN,

HUM.

ADM.

RBC.

ACN,

DOW,

JCC,

UCC.

ACN,

DOW,

JCC,

UCC.

ACN,

DOW,

JCC,

UCC.

WSN.

EVN,

SUM.

DOW,

JCC,

OMC,

UCC.

DOW,

OMC,

UCC.

DOW,

OMC,

UCC.

UCC.

EKT,

UCC.

KF.

ACT.

KF.

CEL,

EKT,

EN J,

HPC,

PUB,

SRC, UCC.

EKT,

FMP,

UCC.

CEL,

DEC,

RH,

UCC.

TNA,

TSA.

TNA,

TSA.

PAS.

UCC.

UCC.

BKL,

FMP.

KF.

OTC.

ABB.

FMP.

ABB.

KF.

OH.

DOW,

JCC.

ACN,

APD,

CAU,

CEL,

DOW.

DUP, G, GOC, HCH, JCC, OMC

UCC, WYN.

UCC.

EVN.

SAR.

ACN,

CAU,

DOW,

G, HCH, JCC, OMC, SNO, UCC, WYN.

MAL.

EN J, MAL,

HPC, OMS.

UCC,

USI.

COM,

FB, TBK, UCC.

EKX,

UCC.

UCC.

EKT,

UCC.

194

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.- Miscellaneous chemicals for which U.S. production or sales were reported, identified by lAtsL,Ji ^iD. manufacturer, 1964— Continued

MISCELLANEOUS CHMICALS, ACYCLIC— Continued

*2-Ethylhexanoic aoid (a-Ethylcaproic acid) salts:

Aluminum 2-ethyLhexanoate

Barium 2-ethylhexanoate

Cadmium 2-ethylhexanoate

*Calcium 2-ethylhexanoate

*Cobalt 2-ethylhexanoate

Copper 2-ethylhexanoate

Dibutyltin di-2-ethylliexanoate -■

Iron 2-ethylhexanoate ^

*Ijsad 2-ethylhexanoate "'

^Manganese 2-ethylhexanoate

Nickel 2-ethylhexanoate

Potassium 2-ethylhexanoate

Rare earths 2-ethylhexanoate

Stannous 2-ethylhexanoate

Strontium 2-ethylhexanoate

*Zinc 2-ethylhexanoate

Ziroonivmi 2-ethylhexanoate

All other

2-Ethyl-l-hexyl acetate

*2-Ethyl-l-hexyl aery late

2-Bthylhexyl cyanoacetate

2-EthyUiexyl methacrylate

2-Ethyl-2-(hydroxymethyl)-l,3-propanediol (Trimethylol-

propane). 2-Ethyl-2-(hydroxymethyl)-l,3-propanediol allyl ethers

Ethylidine diacetate

Ethyl isocyanate

2-( Ethylmercapto)ethanol

Ethylmerciirio chloride "

Ethyl 2-methyllaotate (Ethyl a-hydroxyisobutyrate)

Ethyl (I-methyl-2-pentynyl) cyanoacetate

*Bthyl propionate

*Ethyl silicate (Tetraethoxysilane)

Ethyl sulfate (Diethyl sulfate)

N-Ethylurea """

Ethyl vinyl ether

Fats and oils, chemically modified:

lard oil, nitrated

Vegetable oils, brominated

Other

Fatty acids, chemically modified:

a-Bromo(lauric-steaTic) acids

Castor oil fatty acids, dehydrated

All other

Fatty acid esters, not included with plasticizers or surface-active agents:

Deoyl oleate

Ethyl stearate

Isopropyl linoleate

Isopropyl palmyristate

Methyl esters of tallow

All other

Fish oil fatty aoid amide

Flotation reagents:

Isopropyl ethylthionocarbamate

Phosphorodithioates (Dithiophosphates) :

Potassivun dihexyl phosphorodithioate

Sodium di-sec-butyl diethyl phosphorodithioate

Manufacturers ' identification codes (according to list in table 22)

WTC. CCA. CCA.

CCA, FER, ma, HSH, MCI, MLD, SRR, SW, mC. CCA, FER, HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. CCA, SRR.

CCA,

HNX,

HSH, MCI,

MLD, NTL, SHP, SRR, SW, WTC

CCA,

HNX,

MCI, MLD,

SHP, SKR.

MCI.

CCA.

CCA.

WTC,

X.

OCA.

CCA,

HNX,

HSH, MCI,

SRR, WTC, X.

CCA,

HNX,

WTC.

SW.

GEL,

EKT,

UCC.

CEL,

DBC,

RH, UCC.

KF.

DUP.

CEL.

CEL.

CEL.

ore.

PAS.

LIL.

RH.

LIL.

FB,

NW, TBK.

MIR,

SEA,

UCC.

UCC.

MED.

UCC.

SPP.

DOM,

RT.

CHL.

DUP.

BAC.

ABB,

RH,

HI.

VND.

ICO.

VND

PCS

BFR,

CHL

ADM

EMR

, EMJ, PG,

RT, X.

ADM

DOW

Acy

Acy

TABLE 21B.

MISCELLANEOUS CHEMICALS

-Miscellaneo^ chemicals for which U.S. production or sales were reported, identified by manufacturer, 7564— Continued ' '""'"■'J '■^" °y

195

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Flotation reagents Continued

Phosphorodithioates (Dithiophospiiates) Continued

Sodium di-seo-butyl phosphorodlthioate

Sodiiim diethyl phosphorodithioate

Sodium dihexyl phosphorodithioate

Sodium diisopropyl phosphorodithioate

Other

Xanthates :

Potassiiom n-butylxanthate

Potassium ethylxanthate

Potassium hexylxanthate

Potassium isopropylxanthate

Potassium pentylxanthates

Potassium sec-pentylxanthate

Sodium n-butylxanthate

Sodium sec-butylxanthate

Sodium ethylxanthate

Sodium isobutylxanthate

Sodium isopropylxanthate

Ail other

^Formaldehyde, 37^ by weight

Formamide

*Formic acid, 9Q<jo

*Formio acid salts:

Aluminum formate

Ammonium formate

Calcium formate

Chromic formate

Copper formate

Lead formate

Nickel formate

Potassium formate

Sodium foimate, refined

Sodium formate, tech

Thallous formate

Fumarate polymer

*Fumaric acid

Geranyl orotonate

^■Gluconic acid, tech

Gluconic acid, ammonium salt

^Gluconic acid, sodium salt, tech

Glucono-delta-laotone

Glucosamine hydrochloride

Glucose pentaacetate

Glutar aldehyde

Glutaraldehyde bis(potassium metabi sulfite)

Glutaraldehyde bis [sodium bisulfite]

Glutaric acid

Glycerol, synthetic

Glycidol (2,3-Epoxy-l-propaiiol)

Glycine (Aminoacetic acid), tech

Glycine, cupric salt

Glycine ethyl ester hydrochloride

Glycolic acid (Hydroxy acetic acid)

Glyoolio acid salts;

Aluminum glycolate

Sodium glycolate

Glycolonitrile

Glyoxal

Guanidine hydrochloride

4-Guaiiyl-l-isonitrosoguanyl-l-tetrazene

Manufacturers ' identification codes (according to list in table 22)

ACY. ACY. ACY. ACY. ACY.

USE.

ACY, DOW.

DOW.

DOW.

ACY, DOW.

DOW.

KCC, USE.

ACY, DOW,

ACY, DOW.

DOW.

ACY, DOW.

ACY.

ACN, BOH, CBC, CEL, COM, DUP, HKD, HN, HPC, MON, HCI,

RH, SPN, THJ, UCP. DUP. DUP, HN, VIC.

SNW, UCC, VIC.

ACG, WSN.

THJ.

G.

GTN.

NTL.

HSH.

TNC.

ACG, BKC.

DCI, HN, HPC.

EK.

EN J.

HN, MON, NAC, NTL, PCC, PFZ, PIT, SOC.

FB.

CWL, DLI, IBl, PFZ.

PFZ.

CWL, DLI, IBI, PFZ.

DLI, PFZ.

PFZ.

BKL.

UCC.

RZL.

IDC, HZL.

MON.

APD, DOW, EH, SHC, UCC.

OTC.

BPC.

BPC.

BPC.

DUP.

CIB.

MED, TNC.

ACY.

UCC.

ACY.

REM.

196

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.-

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

MSCELLAMEOUS CHEMICALS, ACYCLIC— Continued

»Halogenated hydrocartons:

«l-Bramobutane (n-Butyl bromide)

2-Bromobutaiie (seo-Butyl bromide)

Bromochloromethane

l-Bromo-3-chloropropane (Trimethyleneohlorobromide)

2-Bromo-2-chloro-l,l,l-trifluoroethane

Bromoethane (Ethyl bromide)

1-Bromohexadeoane (Cetyl bromide)

l-Bromohexane (n-Hexyl bromide)

l-Bromo-2-methylbutane

l-Brofflo-3-methylbutane

1-Bromo-octadecane

l-Bromopentane (n-Amyl bromide)

2-Bromopentaiie (l-Methylbutyl bromide)

1-Bromopropane (n-Propyl bromide)

3-Broraopropene (Allyl bromide)

3-Bromopropyne

Bromotrifluoromethane

*Carbon tetrachloride

^Chlorinated paraffins:

Less than 355^ chlorine

*35^64-5S chlorine

65?J or more chlorine

1-Chlorobutane (n-Butyl chloride)

2-Chlorobutane (sec-Butyl chloride)

l-Chloro-l,l-difluoroethane

*Chlorodifluoromethane

«Chloroethane (Ethyl chloride) :

Tech

U.S.P

*Chloroform:

Tech

U.S.P

2-Chloro-3-hexyne

*Chloromethane (Methyl chloride) :

Crude

Refined (refrigerant grade)

2-Chloro-2-methylpropane (tert-Butyl chloride)

3-Chloro-2-methylpropene (Methallyl chloride)

Chloropentafluoroethane

Chloropentanes , mixed isomers

2-Chloropropane (Isopropyl chloride)

3-Chloropropene (Allyl chloride)

Chlorotrifluoroethylene (Trifluorovinyl chloride)--

Chlorotr if luoroethylene , polymerized

Chlorotrifluoromethane

l,2-Dibromo-l,l-dichloroethane

Dibromodifluoromethane

1,2-Dibromoethane (Ethylene dibromide)

Dibromomethane (Methylene bromide)

1,3-Dibromopropane

l,2-Dibromo-l,l,2,2-tetrafluoroethane

Dichlorobutadiene

1,4-Dichlorobutene

*Dichlorodifluoromethane

*l,2-Dichloroethane (Ethylene diohloride)

Manufacturers' identification codes (according to list in table 22)

ABB, BPC, DOW, MCH.

ABB, BPC.

DOW.

DOW, MCH.

ICI.

DOW, MCH.

EK.

BPC.

LIL.

BPC.

DUP, G.

CLB, EK.

ABB, BPC, LIL.

BPC, EK.

CLB, DOW.

G.

DUP.

ACG, ACS, DA, DOW, FMB, FRO, PPG, SF.

HK.

CCH, DA, DVC, HK, HPC, KPT, WOI.

DA, DVC, WOI.

PUB, UCC.

ICO, PLC.

ACG, DUP.

ACG, DUP, KAI, PAS, UCC.

AME, DOW, DUP, HPC, TNA, USI. DOW, SHC.

ACS, DA, DOW, DUP, FRO, SF.

ACS, DA, DOW.

LIL.

ANM, DOW, TNA.

ACS, DA, DCC, DOW, DUP, FRO.

DUP, EK, RBC.

FMP.

DUP.

PAS.

DOW.

DOW, SHC.

ACG, MMM.

HK, MMM.

ACG, DUP, PAS.

DOW.

DOW.

AMP, DOW, ETD, HCH, MCH.

DOW.

EK.

DUP.

DUP.

DUP, RBC.

ACG, DUP, KAI, PAS, UCC.

AME, DA, DOW, DUP, JCC, M3N,

OMC, PPG, TMA, UCC, WYN.

MISCELLANEOUS CHEMICALS

197

TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, i 564— Continued

MISCELLANEOUS CHEMICAIS, ACtCLIC—Continued

♦Halogenated hydrooartons Continued

*Diohloromethane (Methylene chloride)

Diohloropentanes , mixed isomers

*1,2-Diohloropropaiie (Propylene diohloride)

2,3-Diohloropropene

*Diohlorotetrafluoroethane

Ijl-Difluoroethane

Difluorotetrachloroethane

Diiodomethane (Methylene iodide)

Hexaohloroe thane

Hexafluoropropylene, monomer

lodoethane (Ethyl iodide), teoh

*Iodomethane (Methyl iodide)

lodotrifluoromethane

1,1,2,2-Tetrabromoethane (Acetylene tetrahromide)

Tetrabromomethane

1,1,2,2-Tetrachloroethane (Acetylene tetrachloride)--

*Tetrachloroethylene (Perohloroethylene)

Tetrafluoroethylene, monomer

Tetrafluoroethylene, polymer

Tetrafluoromethane

1,1,1-Trichloroethane (Methyl chloroform)

1,1,2-Trichloroethane (Vinyl trichloride)

*Trichloroethylene

*Triohlorofluoromethane

1,2,3-Trichloropropane

1,2,3-Trichloropropene

Triohlorotrifluoroethane

»Vinyl chloride, monomer ( Chloroethylene )

Vinyl fluoride

Vinylidene chloride, monomer (1,1-Dichloroethylene)—

Vinylidene fluoride

All other

Heptaf luorobutanol

2-Heptanone (Methyl amyl ketone)

3-Heptanone (Ethyl butyl ketone)

Heptanoyl chloride

9H-Hexadecaf luorononanoic acid, ammonium salt

Hexadecane

Hexadecenyl succinic anhydride

n-Hexadecyl disulfide

Hexa(2-ethylbutoxy)disiloxane

Hexamethylenediamlne dicarbamate

Hexamethylenediammonium adipate

Hexamethylene diisocyanate

2,5-Hexanedione (Aoetony lace tone)

1,2,6-Hexanetriol

1,2,6-Hexanetriol ootoate

Hexanoio acid (Caproic acid)

Hexyl acetate

2-[2-(Hexyloxy)ethoxy]ethanol

Hydracrylonltrile (Ethylene cyanohydrin)

Ifydrazine and salts

2-Hydrazinoethanol

Hydrocarbon polymer

N-[ 3-(Hydroxymercuri) -2-methoxypropyl]carbamoylsuc-

cinamic acid (Methoxyoximercuripropylsuccinyl urea) . 2-(Hydroxymethyl) -2-methyl-l,3-propanediol ( Trimethylol

ethane) . 2-(Hydroxymethyl)-2-nitro-l,3-propanediol ( Tris( hydroxy

methyl) nitromethane) . N-( Ifydroxymethyl) octadeeanamide ( N-Hydroxymethylsteara- mlde) .

Manufacturers ' identification codes (according to list in table 22)

ACS

DA,

DOW,

DUP,

FRO,

SF.

PAS

DOW

JCC

UCC

, WYN

DOW

ACQ

DUP

PAS

ACQ

DUP

DUP

NTB

SDW

X.

NES

DUP.

EK,

FMT.

CLE

EK,

FMT,

NTB,

RSA.

CLB.

DOW.

DOW.

DUP,

PPG.

DA,

DOW,

DUP,

FRO,

HK, PPG, SF, TTX.

DUP.

DUP.

DUP.

DOW,

PPG,

TNA

DOW,

TNA,

UCC

DOW,

DUP,

HK,

PPG,

TTX.

ACQ,

DUP,

KAI

PAS

UCC

DOW,

SHC.

DOW.

ACQ,

DUP,

PAS.

ACS,

AME,

BFG

BOR

cue

DA, DOW, GNT, GYR, MNO, MON

TNA, UCC.

X.

DOW,

TNA.

X.

DUP,

KPT,

SDH.

CLB.

UCC.

UCC.

EK.

DUP.

ma.

HMY.

PAS.

UCC.

BKL.

MON.

OTC.

RBC.

UCC.

KES.

FB, TpK.

ENJ.

UCC.

UCC.

FMT,

QMC.

NOH.

ENJ.

LKL.

198

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

MISCELLANEOUS CHEMICALS, ACYCLIC- -Continued

4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol)

(ffydroxyniethyl)urea (Methylol-urea)

Hydroxypropyl methacrylate

3,3'-Iininodiproplonitrile

lodoacetic acid, sodium salt

lodomethylmercury Iodide

Isethlonic acid (2-Itsrdroxyethanesulfonlc acid)

Isoascorblc acid

*Isoascort)ic acid, sodium salt

Isobutoxyethanol

Isobutyl aciylate

Isobutyl isobutyrate

Isobutyl vinyl etber

Isobutyraldehyde

Isobutyrle acid and anhydride

Isobutyronltrlle

Isodeoaldehyde, mixed isomers

Isodeeanoic acid, mixed Isomers

Isodecyl aery late

Iso-octanoic acid, mixed Isomers

Isopentanoio acid

Isopentyl ether (Isoamyl ether)

Isoprenylalumlnum

Isopropanolamines :

l-Amino-2-propanol (Mbnoisopropanolamine)

1,1' -Iminodi-2-propanol (Diisopropanolamine)

1,1' ,1" -Nitrilotri-2-propanol (Triisopropanolamli

*Isopropyl acetate

2- IsopropylRTTii noethanol

Isopropyl ohloroformate

*Isopropyl ether

Isopropyl isocyanate

Isovalerone (Diisobutyl ketone)

Itaconic acid (Methylenesuccinic acid)

o-Ketoglutario acid

*Lactic acid, 100^:

Edible

Medicinal-

Technical

Lactic acid salts :

Aluminum lactate

Aluminum sodium_ chlorohydroxylactate

Aluminum sodium lactate

Calcium lactate

Sodium lactate

Lactic anhydride

Lactide (3,6-Dimethyl-2,5-p-dioxanedlone)

Lactonitrile

Laurie acid salts

Lauronitrile

Lauroyl bromide

*Lauroyl chloride

*Lauroyl peroxide

Lauryl lactate

Levulinic acid

*Linoleic acid salts :

^-Calcium linoleate

^Cobalt linoleate

Copper linoleate

Iron linoleate

Lead linoleate

Manufacturers ' identification codes (according to list in table 22)

CEL, LIL,

SHC,

UCC.

DUP.

JCC.

ACY.

RSA.

NTB.

G.

MRK, PFZ.

BAX, MRK,

PFZ.

UCC.

DBC.

EKX.

G, UCC.

EKX, UCC.

EKT.

EKX.

UCC.

UCC.

UCC.

UCC.

UCC.

GIV.

ISA.

DOW, UCC.

DOW, UCC.

DOW, UCC.

EKT, EN J,

HPC,

UCC.

PAS.

CTN, PPG.

EN J, SHC,

UCC.

OTC.

EKT, UCC.

PFZ.

PIC.

CLN, DUP,

MON.

DUP.

CLN, DUP,

MON.

TNC.

REH.

REH.

SHF.

PEN.

FB.

CLN.

MON.

CCW.

FOR.

DOW.

BC, G, HK

, MON

, TBK

AZT, CAD,

UPR,

WTL.

VND.

CRZ.

CCA, LEF,

SHP,

SRR.

HSH, SEP,

SRR.

WTC.

HSH.

SHP, SRR.

MISCELLANEOUS CHEMICALS

199

TABLE 21.B. -Miscellaneous chemicals for which U.S. production or sales were reported identified bv

manufacturer, 1964— Continued r , j y

MISCELLANEOUS CHEKQCALS, ACYCLIC— Continued

*Llnoleio acid salts Continued

Lead manganese linoleate

Manganese linoleate

»Iubricating oil additives:

Chloronaphtha xanthate

Chlorosulfurized hydrocarbon

Chlorosulfurized lard oil

Chlorosulfurized sperm oil

High-molecular-weight liydrooarbons and their phosphorus derivatives.

Oxidized hydrocarbons

*Phosphorodithioates (Dithiophosphates) :

Barium aliyl phosphorodithioates

Zinc aliyl phosphorodithioates

Zinc di(butylhexyl) phosphorodithioate

Zinc dihexyl phosphorodithioate

Zinc hexyl isopropyl phosphorodithioate

All other

SuLfurized butenes

Sulfurized lard oil

Sulfurized methyl oleate

*Sulfurized sperm oil

Tetradecyl selenide

All other

Magnesium metiiylate

Maleic acid

Maleic acid, tribasic lead salt

*Maleic anhydride

Malic acid

Malonio acid

Malonic acid salts

Malononitrile

Mamiitol

Mannitol hexanitrate

Mercaptoaoetic acid ( Thioglycolic acid)

»lferoaptoaoetic acid (Thioglycolic acid) derivatives: »2-Aminoethyl mercaptoacetate (MDnoethanolamine thio- glycolate ) .

*Ammonium mercaptoacetate (Ammonium thioglycolate)

Antimony mercaptoacetate

Calcium mercaptoacetate

Dibutyltin bis(iso-octylmeroaptoaoetate)

Dibutyltin mercaptoacetate

Iso-octyl mercaptoacetate

Ifethyl mercaptoacetate

Octadecyl mercaptoacetate

Potassium mercaptoacetate

Sodium mercaptoacetate

3-Iiferoapto-l,2-propanediol (Thioglycerol)

/3-lfercaptopropionic acid

Mercaptosuccinic acid (Thiomalic acid)

Ifetal soaps of oxidized hydrocarbons

Methacrylamide

Jfethaorylate copolymers

Ifethacrylate monomers, above methyl

Ifethacrylic acid

Manufacturers ' identification codes (according to list in table 22)

SDH

SRR.

SHP

SRR.

MON

ENJ

CCW

ccw

SOI

ALX

LUB.

ENJ,

LUB.

ORO.

MON,

SIN.

TX.

ACY,

LUB, MON

SIN, TX.

LUB.

ccw.

GOC, SIN

SOI.

SIN.

ccw.

LUB, QCP,

SIN, SOI, X.

ORO.

CCW,

ENJ, HK,

LUB, MON, ORO,

MET,

SFA.

NAC,

PFN.

NTL.

HN,

KPS, MON,

NAC, PCC, PTT,

EK„

^AC, PFN.

KF.

EK,

3IV.

KF.

APD.

APD.

EVN,

HAB, RET.

EVN,

HAB, RET.

EVN,

HAB, RET,

TNI.

CCA.

Era.

X.

CCA.

CCW,

Era.

Era.

e™.

Era.

Era.

Era.

ETO.

Era.

ALX.

RH, X

X.

DUP,

SAR.

DUP,

RH.

200

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1964 Continued

MISCELLANEOU:. CHEMICALS, ACYCLIC— Continued

Iifethaoryloyl chloride

tfethalylldene .iacetate

Jfcthanesulfonlo acid

»2-Msthoxyethanol (Ethylene glycol monoethyl ether)

*2-(2-hfethoxyethoxy)ethanol (Diethylene glycol monoethyl

ether) . »2-[2-(2-lfethoxyethoxy)ethoxy]ethanol (Triethylene glycol monomethyl ether). 2-(2-hfethoxyethoxy)ethyl 2-methoxyethyl ether (Triethylene glycol dimethyl ether).

2-Methoxyethyl acetate

2-Methoxyethylainine

'i-lfethoxy-<i-methyl-2-peutanol

4-Methoxy-<i-methyl-2-pentanone

Jfcthoxypolyethylene glycol

l-Methoxy-2-propanol

3-hfethoxypropionitrile

3-(3-Methoxypropoxy)propanol (Dipropylene glycol methyl

ether) . 3-[3-(3-lfethoxypropoxy)propoxy]propanol ( Tripropylene glycol methyl ether).

3-Methoxypropylamine

Ifethoxytriethyleneglycol acetate

*Jfethyl acetate

Jfethyl acetoacetate

Metlyrl acrylate, monomer

Methylal ( Dimethoxymethane )

Ifethylaluminum sesquichloride

2-lfethylaminoethanol (N-Methylethanolamine)

Methyl borate

3-I*thyl-2-butenoie acid

2-Methyl-l-buten-3-yne ( Isopropenylacetylene )

2-Methyl-2-(sec-butyl)-l,3-propanediol

lifethyl butynoxyethancl

Methyl carbamate

Ifethyl chloroformate

Methyl oyanoacetate

Methyl 2-oyanoacrylate

Methyl diohloroacetate

Methyl disulfide (Dimethyl disulfide)

NjN'-Jfethylenebisacrylamide

N, N' -Ifethylenebisoctadecanamlde

Ifethyl ether (Dimethyl ether)

Ifethyl formate

N-Jfethylglucamine

Methylglyoerol

5-Methyl-2-hexanone (Methyl isoamyl ketone)

2,2'-(Methylimino)diethanol (hfethyl diethanolamine)

Ifethyl isocyanate

2-Methyllactic acid (a-Hydroxyisobutyrio acid)

2-Methyllactonltrile (Acetone cyanohydrin)

Methylmagnesium bromide

Methylmagnesiiom chloride

Methyl methacrylate, monomer

7-Kfethyl-3-methylene-l,6-ootadiene (h/tyrcene)

2-Msthyl-2-nitro-l,3-propanediol

2-^fethyl-2-nitro-l-p^opanol

2-MBthyl-2,'i-pentanediol (Hexylene glycol)

*4-lfethyl-2-pentanone (tfethyl isobutyl ketone)

4-Afcthyl-2-pentanone oxime (Methylisobutyl ketoxime)

4-lfethyl-3-penten-2-one (^fesityl oxide)

4^-Methyl-2-pentyl acetate

Methylpolyethanolamine

Manufacturers ' Identification codes (according to list in table 22)

DUP.

UCC.

EK, PAS.

DOW, JCC,

OMC,

UCC.

DOW, JCC,

OMC,

UCC.

DOW, CMC,

UCC.

ASL.

UCC.

JCC, WYN.

SHC.

SHC.

JCC, UCC.

DOW, SHC.

ACY.

DOW.

DOW.

DUP, EKT,

JCC.

RBC.

BOR, EK,

GRD,

SRC, UCC.

EKT, UCC.

CEL, DEC,

RH.

CEL.

TNA.

UCC.

MHI, SFA.

UCC.

AIR.

BKL.

AIR.

BKL.

CTN.

KF.

EKT.

KF, PD.

CRZ.

ACY.

ARC.

COM, DUP.

DUP.

ABB, DUP.

APD.

EKT, UCC.

DOW, UCC.

CTN, OTC.

EK.

RH, x.

ARA.

ARA.

ACY, DUP,

RH,

USP.

IFF.

COM.

COM.

CEL, EKT,

ICO

SHC, UCC

EKT, ENJ,

SHC

UCC.

ALB.

SHC, UCC

PUB, SHC,

UCC

MISCELLANEOUS CHEMICALS

201

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, i564~ Continued

Manufacturers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICAI£, ACYCLIC— Continued

2-Methyl-2-propyl-l,3-propanediol

2-lfethyl-2-n-propyl-l,3-propanediol monocarbamate

Methylpseudoionone

Methyl sulfate (Dimethyl sulfate)

Methyl sulfide (Dimethyl sulfide)

Methyl sulfone

^fethyl sulfoxide (Dimethyl sulfoxide)

N-Jfethyltaurine

N-Jfethyltaurine, sodium salt

2-Methylvaleraldehyde (2-Methylpentaldehyde)

2-Methylvaleric acid

Methyl vinyl ether

Micochlorio acid (2,3-Dlchloro-3-fonnylaciylic acid)

Ifyristoyl chloride

Ifyristoyl lactate

Naringin

Neodecanoic acid ( Trialiylaoetic acid) salts

Nitriminobispropionic acid

2-Nitro-l-butanol

Nitroethane

Nitromethane

1-Nitropropane

2-Nitropropane

Nonanoic acid (Pelargonic acid)

Nonenylsuccinio anhydride

Nylon

1-Octadeoene

Octadecyl isocyanate

Octadecyl mercaptopropionate

Octadecyl vinyl ether

1-Octanethiol (n-Octyl meroaptan)

Octanoic acid (Caprylic acid) salts:

Aluminum octanoate

Barium octanoate

Cadmium octanoate

Zinc octanoate

2-Octanone (Hexyl methyl ketone)

Octanoyl chloride

1-Octene

l(and 2)-0ctene

2-Octene

Ootenylsuocinio anhydride

Octyltins

Oleamide (Octadecene amide)

Oleic acid salts:

Aluminum oleate

Ammonium oleate

Barium zinc oleate

*Copper oleate

Lead oleate

Stannous oleate

Oleonitrile

Oleoyl chloride

Oleylpalmitamide

*Qxalic acid

Oxalic acid salts :

Ammonium oxalate

Calcium oxalate

Copper oxalate

Ferric ammonium oxalate

Ferric oxalate

Ferric sodium oxalate

Ferrous oxalate

Potassium binoxalate

ABB, BKL, DUP, ICO.

X.

GIV.

DUP.

CR2, PAS.

CRZ.

CRZ.

G.

TNA.

UCC.

UCC.

G, UCC.

EKT.

BC, X.

TOD.

SKG.

MCI, MLD.

ACY.

COM.

COM.

COM.

COM.

COM.

EMR.

HMY.

DUP, MDN.

HMY.

CWN, ICO, MDB.

ETO.

G.

PAS.

NOP.

CCW.

CCVf.

BKC.

EKT, TBK, WTH.

HK, TBK.

ADM.

WTH.

HMY.

HMY.

X.

ADM, ARC, FIN, HUM.

WTC. MCI. HSH, LEF, SHP. CCW, ARC, CRT, FIN. ACG,

WTC.

MLD, SHP, WTC.

FOR. DEP, G.

HK, MAL, PF2, VIC.

ACG, BKC, PFZ.

VIC.

TNC.

PFZ.

PFZ.

PFZ.

BKL.

BKC.

202

SYNTHETIC ORGANIC CHEMICALS, )964

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, i 964 Continued

Chemical

MISCELLANEOUS CHEMICALS, ACYCLIC--Continued

*Oxalio acid salts--Continued

Potassium oxalate

Sodium binoxalate

Sodium oxalate ~~

Oxidized hydrooarton mixtures, other than lubricating oil additives. *Palmitic acid salts :

*Aluminum palmitate

*Zinc palmitate

*Palmitoyl chloride

Pantolaotone

Paraformaldehyde

Paraldehyde (Paracetaldehyde)

*Pentaerythritol

Pentaerithritol caprylate

Pentaerythritol, di- and other

Pentaerythritol, di- and tri-

Pentaerythritol pelargonate

*Pentaerythritol tetranitrate

Pentafluoropropanol

2,4--Pentanedione ( Acety lacetone )

2,4-Fentanedione, metallic complexes:

Cobalt

Ferric

Other

2-Pentanone (Methyl propyl ketone)

3-Pentanone (Diethyl ketone)

Pentyl nitrate (An^rl nitrate)

Perchloromethanethiol (Perchloromethyl mercaptan)

Peroxyacetic acid

*Phosgene (Carbonyl chloride)

♦Phosphorus acid esters, not elsewhere specified {See also Plastioizers, Surface-Active Agents, Pesticides, Flo- tation reagents, and Lubricating oil additives):

Bis(2-chloroethyl) vlnylphosphonate

Bis(2-ethylhexyl) hydrogen phosphate

Bis(2-ethylhexyl) hydrogen phosphite

Butyl phosphates (mono- and di-)

Chloropropyl phosphorothloate

Dibutyl butylphosphonate

Dibutyl hydrogen phosphite

Didodecyl hydrogen phosphate

Diethyl hydrogen phosphite

Dimethyl hydrogen phosphite

Dimethyl methylphosphonate

Dioctyl hydrogen phosphate

Dioctyl hydrogen phosphite

2-Ethylhexyl phosphates (mono- and di-)

Ethyl phosphates (mono- and di-)

Iso-oetyl hydrogen phosphate

Isopentyl ootyl hydrogen phosphate

Lauryl dihydrogen phosphate

Methyl phosphates (mono- and di-)

Pentyl phosphates (Mono- and diainyl phosphates)

Tributyl phosphate

Tributyl phosphite

Tridecyl phosphite

Triethyl phosphite

Triiso-octyl phosphite

Trimethyl phosphate

Trimethyl phosphite

Tris(2-chloroethyl) phosphate

Tris(2-chloroethyl) phosphite

Tris(2,3-dibromopropyl) phosphate

Tris(2-ethylhexyl) phosphite

Tris(octadecyl) phosphite

All other

Manufacturers ' identification codes (according to list in table 22)

ACG, BKC, PFZ.

VIC.

ACG, BKC, MAL, VIC.

ALX.

ACY, NOP, WTC.

ACY, NOP, WTC.

G, HAL, OPC, TBK.

CKL, NOP.

CEL, HN.

UCC.

COM, DCI, HN, HPC, RCI, TRJ.

DRW.

HPC.

HPC.

DRW.

APD, DUP, HPC, TRJ.

CLB.

UCC.

MLD.

MAK.

MAK.

UCC.

DUP.

TNA.

CHO.

FMB.

CTN, DUP, EKT, GE, MOB, NAC, OMC, PPG, SF, UCC, UPJ,

VDM.

VIC.

UCC.

VC.

VIC.

TNA.

VC.

VC.

DUP.

VC.

VC.

VC.

VIC.

HK.

VIC.

VIC.

VC.

VC.

VIC.

HK, VIC.

VIC.

CEL, COM.

VC.

HK.

VC.

VC.

TNA.

VC.

CEL, ENJ.

VC.

DUP, MCH.

HK, VC.

VC.

CEL, DUP, ENJ, MON, VC.

MISCELLANEOUS CHEMICALS

203

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1964 Continued

Manufacturers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued

Pine oil, synthetic

Polyacrylamide

Polyacrylic acid

Polyacrylic acid salts:

immonium polyaciylate

Sodium polyaorylate

All other

Polyacrylonitrile

Polyohlorinated propyl ether

Polyethoxyethylglycerol

Polyethoxyethylsorbltol

♦Polyethylene glycol

Polyethylene glycol dimethaorylate

Polyethylene polysulfide

Polygalacturonic acid

Polyglycols, ethylene glycol and glycol ethers, mixtures

Polyisobutyl succinic anhydride

Polymethaorylic acid esters

Polymethacrylic acid, sodium salt

Polymethyl vinyl ether

*Polypropoxy ethers :

glycerol tri(polyoxypropylene) ether

Polyp ropoxysorbitol

Other

♦Polypropylene glycol

Polytetramethylene glycol ether

Propanedithlol

Propanone peroxide (Acetone peroxide)

|3-Propiolactone

Propionaldehyde

♦Propionic acid

Propionic acid salts r

♦Calcium propionate

♦Sodium propionate

Propionic anhydride

Propionyl peroxide

2-[2-(Propo2y)ethoxy]ethanDl (Diethyleneglycol monopropyl ether).

Propyl acetate

Propylene carbonate

♦Propylene glycol (1,2-Propanediol)

Propylene glycol, mixed ethers

n- Propyl isooyanate

Propyl nitrate

2-Propylvaleric acid (Dl-nr-propylacetic acid)-

Propyne ( Methylacetylene )

Pseudoionone

Pyruvaldehyde

Quaternary ammonium- compounds (butyl and lower)-

Rare sugars

RicinoLamide

Hicinoleic acid salts:

Barium ricinoleate

Calcium ricinoleate

lithium ricinoleate

♦Sarcosine ( N-lfethylaminoacetio acid)

♦Sarcosine, sodium salt

CBY.

ACY,

NLC.

BFG,

NOP,

RH.

BFG.

AlC,

BFG,

JOR, RH.

BFG.

DUP.

JCC.

GLY.

APD,

GLY,

TCH.

ACN,

DOW,

DUP, G, JCC, OMC, UCC, WYN.

SAH.

BFG.

SKG.

DRW,

OMC.

DOW.

EN J.

DUP.

GRD.

G.

JCC,

OMC,

UCC, WYN.

APD.

ACS,

APD,

UCC, WYN.

DOW,

JCC,

UCC, VIS,

WYN.

X.

RBC.

SDH.

CEL.

EKX,

UCC.

CEL,

COM,

DUP, EKT,

UCC.

CEL,

DUP,

HFT, PFZ,

UCC, WSN.

CEL,

DUP,

PFZ, UCC,

WSN.

BKC.

CEL,

EKT,

UCC.

ABB,

TBK.

WTL.

UCC.

CEL,

EKT,

ENJ, PUB,

UCC.

DOW,

JCC.

APD,

CEL,

DOW, DUP,

JCC, OMC, UCC, WYN

DOW.

CEL,

DOW,

JCC, OMC,

UCC, WYN.

CWN,

UPC.

TNA.

X.

AIR.

GIV.

UCC.

ASL,

EK,

PAS, RSA.

PEN.

TKL.

BAG.

BAG.

BAG.

ATL,

G, HMP, VPC.

GGY. WTH,

X.

204

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 21B. Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Manufacturers' identification codes (according to list in table 22)

MISCELIANEOUS CHEMICALS, ACYCLIC— Continued

Sebacoyl chloride

Semicarbazide base and hydrochloride

*Sequestering agents:

(Diethylenetrinltrilo)pentaacetic acid

(Diethylenetrinitrllo)pentaacetio acid, monosodium hydrogen ferric salt.

*(Diethylenetrinitrilo)pentaacetic acid, sodium salt

*N,N-Dihydroxyethylglycine, sodium salt

*(Ethylenedinitrilo)tetraacetio acid (Ethylenediamine- tetraacetic acid),

(Ethylenedinitrilo)tetraacetlc acid, diammonium salt

(Ethylenedinitrilo)tetraacetiG acid, dipotasslum salt

*(Ethylenedinitrilo)tetraacetio acid, disodium salt

(Ethylenedinltrilo)tetraaoetic acid, disodium calcium

salt. (Ethylenedinitrilo)tetraacetic acid, disodium copper

salt. (Ethylenedinitrilo)tetraaoetic acid, disodium zinc salt, dihydrate .

(Ethylenedlnitrilo)tetraacetio acid, manganese salt

(Ethylenedinitrilo)tetraaoetic acid, monohydrogen

trisodium salt. (Ethylenedinitrilo)tetraaoetic acid, monosodium iron

salt. (Ethylenedinitrilo)tetraaoetic acid, tetrapotassiimi salt

*(Etlyrlenedlnitrilo)tetraacetic acid, tetrasodium salt

Hexahydroxyheptanoic acid, sodium salt

(N-Hydroxyethylethylenedinitrilo)trlacetic acid

(N-Hydroxyethy letter lenedinitrilo)triacetic acid, iron sodium salt. *(N-Hydroxyethylethylenedinitrilo ) triacetic acid , trisodium salt. (N-Hydroxyethylethylenedlnltrilo)triacetic acid, other salts.

Nitrilotriacetic acid, tripotassiinn salt

Nitrilotriacetic acid, trisodium salt

All other

Silicones

Sodium ethoxide

Sodium ethyl oxalaeetate

Sodium formaldehydebisulfite

»Sodium formaldehydesulfoxylate

^Sodium methoxlde (Sodium methylate)

Sodium polypectate

Sodium sorbitol borate

Sorbaldehyde (Hexadienal)

Sorbic acid (2,4-Hexadienoic acid), and potassiim and sodiimi salts.

Sorbitol

Stearamide (Octadecane amide)

^Stearic acid salts: »Aluminum stearates:

*Aluminuiii distearate

»Aliminum monostearate

^Aluminum tristearate

Ammonium stearate

Barium stearate

Cadmium stearate

■sfCaloium stearate

Cobalt stearate

EK, ' FMT.

HMP. GGY.

DOW, DOW, DOW,

DOW. EK. DOW, DOW,

GGY. GGY,

GGY. CRT, PCW. GGY. DOW.

GGY, HMP, RPC, TCC.

HMP, MDA.

GGY, HMP, MDA, VIC.

EK, GGY, HMP, RPC. GGY.

HMP.

GGY, HMP, RPC.

CWL, DOW, G, GGY, HMP, HRT, IBI, NOP, RPC, TCC.

CRT, CWL, DOW, GGY, HMP, IBI, ^DA, RPC, TCC.

HMP.

GGY.

GGY, HMP, PEN.

DCC, ORO.

fMP.

FMP.

EK, IDC.

NOP, RH, ROY.

BRF, DA, DUP, HSH, KF,

OMC,

RBC,

SFA

SKG.

APD.

UCC.

UCC.

APD, BRD, MRK.

AIM, DUP, FIN, HUM.

ACY, JTC, LEF, MAL, MCO, NOP, PRP, SYP, WTC.

ACY, LEF, MAL, MCO, NOP, SYP, WTC.

ACY, LEF, MAL, MCO, NOP, PRP, SYP.

DEX, NOP, WTC.

LEF, MCO, NOP, PRP, SYP, WTC.

NOP, PRP, SYP, WTC.

ACY, HNX, JTC, LEF, MAL, MCO, NOP, PRP, SYP, WTC.

WTC.

MISCELLAtslEOUS CHEMICALS

205

TABLE 21B.-

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1964 Continued

Chemical

MISCELLANEOUS CHEMICAI5, ACYCLIC— Continued

^<Steario acid salts Continued

Copper stearate

Ferric and ferrous stearates

*Lead stearate

Lead stearate, dibasic

wLithium stearate

■xMagnesium stearate

Nickel stearate

*Zinc stearate

All other

Stearonitrile (Ootadecanenitrile)

Stearoyl chloride

Stearyl-2-lactic acid

Succinic acid

Succinic acid, calcium salt

Succinic acid, sodium salt

Succinic anhydride

Succinimide

Suocinonitrile

Suocinyl peroxide

Sucrose octa-acetate

*Tallow amide, hydrogenated

Tallow fatty acyl chloride

Tallow nitrile

Tallow nitrile, hydrogenated

Tartaric acid salts:

Antimony potassium tartrate

Potassiimi bitartrate

Potassium sodium tartrate

Sodium bitartrate

All other

Tetrabutylphosphonium hydroxide

n-Tetradecane

1,1,3,3-Tetraethoxypropane

Tetra(2-ethylbutyl) ortho-silicate

Tetraethylene glycol

Tetraethylene glycol dimethacrylate

*Tetraethyllead

Tetrahydropseudoionone

Tetrahydroxysuccinio acid (Dioxytartaric acid)

TetraMs ( hydr oxymethyl ) phosphonium chloride

N,N,N',N'-Tetrald.s(2-hydroxypropyl)ethylenediamine—

1,1,3,3-Tetramethoxypropane

Tetramethyl(and ethyl) lead

Tetramethylguanldine

Tetramethyllead

Tetraoctyl orthosilicate

Tetrapropenylsuccinio acid

Thioacetamide

Thioaoetic acid

2,2'-Thiodiethanol (Thiodiethylene glycol)

3,3' -Thiodipropionic acid

3,3' -Thlodipropionitrlle

Thiosemioarbazide

Titanic acid esters

Triacetoxyvinylsilane

Tributylphosphine

Tributyltin chloride

Trichloroacetic acid

Trichloroacetyl chloride

Trichloroethylsilane (Ethyl silicone trichloride)

Trichloromethylsilane

Trichloropentylsilane

Trichloropropylsilane

Triohlorovinylsilane

Manufacturers' Identification codes (according to list in table 22)

MCO,

WTC.

MCI

WTC.

HSH

LEF,

NOP,

NTL,

PRP,

WTC.

MCO

NOP,

NTL.

FIE

LEF,

NOP,

PRP,

SYP,

WTC.

ACY

JTC,

MAL,

MCO,

NOP,

PRP,

SYP,

WTC.

WTC.

ACY,

BCN,

CCA,

HNX,

JTC,

LEF,

MAL,

MCO, NOP, PRP, SYP

WTC.

APD.

FOR.

G.

X.

BKC,

M3N,

NAC.

OTC.

MAL.

NAG.

MAC.

ACY,

RSA.

ICO,

WTL.

PD,

UCC.

ADM,

ARC,

CRT,

HUM.

G.

FOR,

GNM.

FOR.

PFZ.

ATC.

PFZ.

PFZ.

BKC.

RSA.

HMY.

KF.

UCC.

DOW,

UCC.

SAR.

DUP,

HCH,

TNA.

GIV.

ACY.

HK.

WYN.

KF.

DUP.

ACY.

DUP,

NLF,

TRA.

MON.

X.

BKC.

e™.

UCC.

CCW,

ETO.

ACY,

HAB.

ACY,

FMT.

DUP.

DCC.

CCW,

COK,

X.

X.

DOW.

EK.

UCS.

DCC.

UCS.

DCC.

DCC,

UCS.

-

206

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 2i.B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, i 964— Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Triethoxyvinylsilane

Triethylaluminum

*Triethylene glycol

Trlethylene glycol dlmethaorylate

Triethyl orthoacetate

Triethyl orthoformate

Trietl^rl orthopropionate

Trifluoroacetaldehyde

Trifluoroacetio anhydride

Tri(hexylene glycol) biborate

Triisobutylaluminum

Triisodecyl orthoformate

Trimethoxyboroxine

Trlmethylaluminum

Trimethylamine-sulfur trioxide

2,6,8-Triinethyl-4-nonanone

Trlmethyl orthoformate

2,2,'i-Trimethyl-l,3-pentanediol

2,2,4-Triiiiethyl-l,3-pentanediol monoisobutyrate

Trimethylpentanol

Tripropylalumimim

Tripropylene glycol

2-Undecanone

*Urea in compounds or mixtures, 100^:

»In feed compounds

*In liquid fertilizer

*In solid fertilizer

In plastics

All other

Urea peroxide

Urea urethane copolymer

Valeraldehyde

Valeric acid

*Vinyl acetate, monomer

Vinyl crotonate

*Zinc formaldehydesulfoxylate

Manufacturers ' identification codes (according to list in table 22)

UCS.

TNA, TSA.

ACN, CAU, DOW, G, HCH, JCC, OMC, UCC.

SAR.

KF.

KF.

KF.

CLB.

EK.

USB.

TNA, TSA.

KF.

SFA.

TNA.

HEX.

UCC.

KF.

EKX.

EKX.

EKX.

TNA, TSA.

DOW, UCC.

TBK.

ACN, DUP, GCC, JDC, MON, MSC, SHC, SOH.

ACN, AHM, CFA, CO, DUP, ESC, FCA, GCC, HEC, HPC, JDC,

KET, MON, MSC, NIT, SHC, SNI, SOH, SPN. ACN, DUP, GCC, HPC, JDC, MON, MSC, SHC, SNO, SOH, SPN. DUP, MON.

ACN, DUP, HPC, MON, SHC, SOH. FMB. DUP. UCC. UCC.

AIR, BOR, CEL, DUP, MON, NSC, UCC. BKL. NOP, RH, ROY.

DIRECTORY OF MANUFACTURERS

207

Directory of Manufacturers

The Directory of Manufacturers lists the companies that report their production of synthetic organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded by an alphabetical identification symbol. These identification symbols consist of not more than three capital letters, and usually bear a relation to the company name.

For 1964, the Directory of Manufacturers lists 800 primary manufacturers (see table 22). Some of the companies that report production of synthetic organic chemicals do not sell the materials, but consume their entire output in further manufacturing.

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists them in alphabetical order by identification symbols; section 2 lists the reporting companies in alphabetical order by company name, and gives the corresponding identification symbol and the company address. Company divisions are usually listed under the parent company's name.

TABLE 22, Synthetic organic chemicals: Directory of manufacturers , 1964

SECTION 1. ALPHABETICAL DIRECTORY BX CODE

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission for 1964 are listed below in the order of their identification codes as used intables in pt. III. Sec. 2 of this table lists these manufacturers alphabetically and gives their office address]

Code

Name of company

Code

Name of company

AAC

Aloolac Chemical Corp.

APX

Apex Chemical Co., Inc.

AAE

American Aniline & Extract Co . , Inc .

AHA

Arapahoe Chemicals, Inc.

AAI

American Alkyd Industries

ARC

Armour & Co., Armour Industrial Chemical Co. Div.

AAP

American Aniline Products, Inc.

AHD

Ardmore Chemical Co.

ABB

Abbott Laboratories

ARC

Argus Chemical Corp.

ABS

American Bralce Shoe Co., American Brakeblok Div.

ARK

Armstrong Cork Co.

ACB

Allied Chemical Corp. , Barrett Div.

ARL

Arol Chemical Products Co.

ACC

Amoco Chemicals Corp.

ARM

Armour Agricultural Chemical Co.

ACQ

Allied Chemical Corp., General Chemical Div.

ARO

Mobil Finishes Co., Inc., Arco Div.

ACN

Allied Chemical Corp. , Nitrogen Div.

ARP

Armour Pharmaceutical Co.

ACO

Aerallte Co., Inc.

ARZ

Arizona Chemical Co.

ACP

Allied Chemical Corp., Plastics Div.

ASH

Ashland Oil & Refining Co.

ACR

Acme Resin Corp.

ASL

Ansiil Chemical Co.

ACS

Allied Chemical Corp., Solvay Process Div.

AST

Astra Pharmaceutical Products, Inc.

ACT

Arthur C. Trask Co.

ASY

American Synthetic Rubber Corp.

ACU

Allied Chemical Corp., Union Texas Petroleum

ATC

American Tartars Corp.

Div.

ATL

Atlantic Chemical Corp.

ACY

American Cyanamid Co.

ATP

Atco Chemical- Industrial Products, Inc.

ADC

Ad-Co Color Corp.

ATR

Atlantic Refining Co.

ADM

Archer-Daniels -Midland Co.

ATU

Atlantic Tubing & Rubber Co.

AIR

Air Reduction Co., Inc., Air Reduction Chemical

AUG

Augusta Chemical Co.

& Carbide Co. Div.

AV

FMC Corp., American Viscose Div.

AKS

Arkansas Co., Inc.

ATC

Avisun Corp.

ALB

Ames Laboratories, Inc.

AZT

Aztec Chemicals, Inc.

ALC

Alco Chemical Corp.

ALD

Aldrlch Chemical Co., Inc.

BAC

Baker Castor Oil Co.

ALF

Allied Chemical Corp., Fibers Div.

BAL

Baltimore Paint & Chemical Corp.

ALL

Alliance Color & Chemical Co.

BAO

Bayoil Co., Inc.

ALO

Alamo Polymer Corp.

BAT

Bates Chemical Co.

ALT

Cronipton & Khowles Corp., Althouse Chemical Co.

BAX

Baxter Laboratories, Inc.

Div.

BC

Barlow Chemical Corp.

ALX

Alox Corp.

BCM

Beldlng Chemical Industries

AMB

American Bio-Synthetics Corp.

BCN

Beacon Chemical Industries, Inc.

AMC

Amohem Products, Inc.

BEN

Bennett ' s

AME

American Chemical Corp.

BFG

B. F. Goodrich Co., B. F. Goodrich Chemical Co. Div.

AMF

Mobil Finishes Co., Inc., Ferbert-Schomdorfer

BFR

Branchf lower Co.

Div.

BGC

Balfour Chemicals, Inc.

AML

Amalgamated Chemical Corp.

BJL

Burdlck & Jackson Laboratories, Inc.

AMD

American Oil Co. (Texas)

BKC

J. T. Baker Chemical Co.

AMP

American Potash & Chemical Corp.

BKL

Millmaster Onyx Corp., Berkeley Chemical Dept.

AMR

Pacific Resins & Chemical Co.

BKM

BncVman TjihnTstnTlps, Tnn .

AMS

Martin-Marietta Corp., Ridgway Color & Chemical

BKS

Berkshire Color & Chemical Co.

Div.

BKT

J. T. Baker Chemical Co., Taylor Div.

ANM

Ancon Chemical Co.

BL

Belle Chemical Co., Inc.

APC

Apple ton Coated Paper Co.

BLA

Blue Arrow, Inc.

APD

Atlas ChemicsLl Industries, Inc., Chemicals Div.

BLN

Brooklyn Color Works, Inc,

APR

Atlas Processing Co.

BLS

Beech-Nut Life Savers, Inc.

APT

American Petrochemical Corp.

BME

Bendix Corp., Marshall-Eclipse Div.

APV

Armstrong Paint & Varnish Works, Inc.

BOR

Borden Co., Borden Chemical Co. Div.

208 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22. —Synthetic organic chemicals: Directory of manufacturers , 1964 Continued

Name of company

Walter N. Boysen Co.

Benzol Products Co.

Brand Plastics Co.

Baird Chemical Industries, Inc.

Bristol-Meyers Co., Bristol Laboratories Div.

M. A. Bruder & Sons, Inc.

Bryant Chemical Corp.

Burkart-Schier Chemical Co.

Blaciman-Uhler Chemical Co.

Buckeye Cellulose Corp.

Burroughs -Wellcome & Co. (U.S.A.), Inc.

J. H. Baxter & Co.

Cadet Chemical Coi-p.

Callery Chemical Co.

Cap-Roc, Inc., Capital Plastics Div.

Catalin Corp. of America

Calcasieu Chemical Corp.

Ciba Corp., Ciba Products Co.

Georgia-Pacific Corp., Coos Bay Div.

Central Processing Co.

Carborundum Co., Coated Abrasives Div.

Columbian Carbon Co., Pigments & Elastomers

Div. Ciba Corp., Ciba Pharmaceutical Co. Div. Colab Resin Corp. Samuel Cabot, Inc. Crosby Chemicals, Inc.

Carlisle Chemical Works, Inc., Advance Div. Chase Chemical Corp. Pearsall Chemical Co. Checkmate Chemicals, Inc. Charlotte Chemical Laboratories Chemioo, Inc.

Crown Central Petroleum Corp. Carlisle Chemical Works, Inc. Budd Co., Polychem Div. Celanese Corp. of America:

Celanese Chemical Co. Div.

Celanese Plastics Co. Div. Chemirad Corp.

Cooperative Farm Chemicals Association Rexall Chemical Co. - Kearny Cargill, Inc.

Chipman Chemical Co., Inc. Chemagro Corp. Chemol, Inc.

Stauffer Chemical Co., Calhio Chemicals Div. Chattanooga Medicine Co., Chattem Chemicals

Div. Ciba Chemical & Dye Co. Cal/Ink Co., Inc. Cindet Chemicals, Inc. Chemical Insecticide Corp. Chemlek Laboratories, Inc. Columbia Organic Chemicals Co., Inc. Charles L. Huisking & Co., Inc., Clintbrook

Chemical Co. Div. Colloids, Inc. Clintwood Chemical Co. Clark Oil & Refining Corp. Standard Brands, Inc., Clinton Com Processing

Co. Div. Clover Chemical Co. W. A. Cleary Corp. Carpenter-Morton Co. Nyanza, Inc.

Commercial Products Co., Inc. Continental Oil Co. Cockerille Chemicals, Inc. Collier Carbon & Chemical Corp. Commercial Solvents Corp. Concord Chemical Co., Inc.

COP

CP

CPC

CPD

CPT

CPV

CPY

CRC

CRN

CRS

CRT

CRY

CRZ

CSD

CSO

CST

CTA

CTL

CTN

cue

CUL

CUT

CW

CWL

CWN

CWP

DA

DAN

DAV

DBC

DCC

DCI

DEG

DEP

DEX

DLH

DLI

DOD

DOM

DOW

DPP

DRL

DRW

DSC

DSO

DUN

DUP

DUR

DVC

IX/S

EAK

ECC

EDO

EFH

EK

EKT

EKX

ELP

EMK

EMR

EN

ENJ

EPC

ESC

ETD

EVN

EW

FAB FAR

Name of conpany

Coopers Creek Chemical Corp.

Colgate-Palmolive Co.

Childs Pulp Colors, Inc.

Chemical Products Corp.

Consolidated Paint Co.

Cook Paint & Varnish Co.

Copolymer Rubber & Chemical Corp.

Crown Chemical Corp.

Com Products Co.

Carus Chemical Co., Inc.

Crest Chemical Corp.

Tenneco Manufacturing Co., Tenneco Plastics Div.

Crown Zellerbach Corp., Chemical Products Div.

Cosden Oil & Chemical Co.

Cities Service Oil Co.

Charles S. Tanner Co.

Conestoga Chemical Corp.

Continental Chemical Co.

Chemetron Corp., Chemetron Chemicals, Organic

Chemical Dept. Cumberland Chemical Corp. Culver Chemical Co. Cutter Laboratories, Inc. General Mills, Inc., Chemical Div. Cowles Chemical Co. Upjohn Co., Carwin Co. Div. Consolidated Papers, Inc.

Diamond Alkali Co., and Western Div.

Dan River Mills, Inc.

Conchemco, Inc., H. B. Davis Co, Div.

Dow Badische Chemical Co.

Dow Coming Corp.

Delaware Chemicals, Inc.

Degen Oil & Chemical Co.

DePaul Chemical Co., Inc.

Dexter Chemical Corp.

Hess Oil & Chemical Corp.

Dawe's Laboratories, Inc.

Donald A. Dodd

Dominion Products, Inc.

Dow Chemical Co.

Dixie Pine Products Co., Inc.

Caradco, Inc., Durel Div.

Drew Chemical Corp.

Dye Specialties, Inc.

DeSoto Chemical Coatings, Inc.

Frank W. Dunne Co.

E. I. duPont de Nemours & Co., Inc.

Duraphene Corp.

Dover Chemical Co.

Sunray DX Oil Co.

J. S. & W. R. EaMns, Inc.

Eastern Color & Chemical Co.

Edoan Laboratories

E. F. Houghton S; Co.

Eastman Kodak Co.

Eastman Kodak Co., Tennessee Eastman Co. Div.

Eastman Kodak Co., Texas Eastman Co. Div.

El Paso Natural Gas Products Co.

Emkay Chemical Co.

Emery Industries, Inc.

Endo Laboratories, Inc.

Enjay Chemical Co., Div. of Humble Oil & Refining Co.

Epoxylite Corp.

Escambia Chemical Corp.

Ethyl-Dow Chemical Co.

Evans Chemetics, Inc.

Westinghouse Electric Corp., Wicarta Div.

Fabricolor Manufacturing Corp. Famow, Inc.

DIRECTORY OF MANUFACTURERS 209

TABLE 22. —Synthetic organic chemicals.- Directory of manufacturers , 2964— Continued

FB

FBF

FBR

FC

FCA

FCD

FCL

FCP

FEL

FEE

FG

FH

FIN

FIR

Name of company

Fritzsohe Bros., Inc.

FlberfU, Inc.

Fibreboard Paper Products Corp.

Franliin Chemical Co.

Farmers Chemical Association, Inc.

France, Canipbell & Darling, Inc.

Federal Color Laboratories, Inc.

J. P. Frank Chemical & Plastic Corp.

Felton Chemical Co., Inc.

Ferro Corp., Ferro Chemical Div.

Foster Grant Co., Inc.

Foster-Heaton Co.

Fine Organios, Inc.

Firestone Tire & Rubber Co., Firestone

Plastics Co. Div. H. B. Fuller Co.

Florasynth Laboratories, Inc.

W. P. Fuller Paint Co.

FMC Corp., Inorganic Chemicals Div.

FMC Corp., Niagara Chemical Div.

Fermoo Laboratories, Inc.

FMC Corp., Organic Chemicals Div.

Fairmount Chemical Co., Inc.

Farac Oil & Chemical Co.

Formica Corp.

Foremost Chemical Products Co.

Freeman Chemical Corp.

Firestone Tire & Rubber Co., Firestone

Rubber & Latex Products Co. Div. Farmers' Chemical Co. Vulcan Materials Co., Frontier Chemical Co.

Div, Filtered Rosin Products Co. Firestone Tire & Rubber Co., Firestone

Synthetic Rubber & Latex Co. Div. Frisch & Co., Inc. Foote Mineral Co.

General Aniline & Film Corp.

Gamma Chemical Corp.

Gane's Chemical Works, Inc.

W. H. Grace & Co., Nitrogen Products Div.

Lancaster Chemical Corp., Gordon Chemicals Co Div.

General Electric Co., Chemical Materials Dept.

General Electric Co. , Insulating Materials Dept.

Geolina Business, Inc.

G. Frederick Smith Chemical Co.

Goodrich-Gulf Chemicals, Inc.

Geigy Chemical Corp.

Gilman Paint & Vamish Co.

Givaudan Corp.

General Latex & Chemical Corp.

Glidden Co.

Glasflex, Inc.

Glyco Chemicals, Inc.

General Foods Corp., Maxwell House Div.

General Mills, Inc.

General Tire & Rubber Co., Chemical Div.

Gulf Oil Corp.

Gordon Chemical Co., Inc.

General Plastics Manufacturing Co.

Grain Processing Corp.

Great American Chemical Corp.

W. R. Grace & Co., Dewey & Almy Chemical Div.

P. D. George Co.

W. R. Grace & Co., Hatco Chemical Div.

W. R. Grace & Co., Polymer Chemicals Div.

Pontiac Refining Corp.

Guardsman Chemical Coatings, Inc.

Great Western Sugar Co.

Guth Chemical Co.

Code

GTL GUA GYR

HAB HAL HAM HAN HAP HAR

HCH

HCO

HDG

HER

HET

HEX

HFT

HK

HKD

HKT

HLC

HLI

HMP

ma

HN

HNC

HNW

HNX

HOF

HOU

HPC HRS HRT HSC HSH HST HUM

HUS HVG HYC HYN

IBI ICC ICF ICI ICO IDC IFF ILC IMC IMP IMR INL INP IOC IPC

IPI

IPR IRC IRI ISO

JAM JCC JDC JEN JMS JNS JNT JOB

Name of company

Great Lakes Chemical Corp. Guard Chemical Co., Inc. Goodyear Tire & Rubber Co.

Halby Products Co., Inc.

C. P. Hall Co. of Illinois

Hampden Color & Chemical Co.

Hanna Paint Manufacturing Co., Inc.

Applied Plastics Co., Inc.

Allied Chemical Corp., National Aniline Div.,

Harmon Color Works Houston Chemical Corp. Hamilton Chemical Corp. Hodag Chemical Corp. Heresite & Chemical Corp. Heteroohemlcal Corp. Hexagon Laboratories, Inc. Hoffman-Taff, Inc. Hooker Chemical Corp.

Hooker Chemical Corp., Durez Plastics Div. Hawkeye Chemical Co. Hartman-Leddon Co. Haag Laboratories, Inc. Hampshire Chemical Corp. Humphrey Chemical Corp. Tenneco Chemicals, Inc. H & N Chemical Co.

Tenneco Chemicals, Inc., Newport Div. Tenneco Chemicals, Inc., Nuodex Div. Hoffmann-LaRoche, Inc. Air Products & Chemicals, Inc., Houdry Process

& Chemical Co. Div. Hercules Powder Co. Bernz-o-Matio, Harris Paint Co. Div. Hart Products Corp. Holland-Suoo Color Co. Harshaw Chemical Co. Hoechst Chemical Corp. National Dairy Products Corp., Humko Products

Chemical Div. Husky-Dominion Briquets

Haveg Industries, Inc., Resin & Compound Div. Hysol Corp. Hynson, Westoott & Dunning, Inc.

Industrial Bioohemicals

Interohemical Corp., Color & Chemicals Div.

Interchemioal Corp., Finishes Div.

I.C.I. (Organios), Inc.

Interchemical Corp.,. Organic Chemicals Dept.

Industrial Dyestuff Co.

International Flavors & Fragrances, Inc.

International Latex Corp.

International Minerals & Chemical Corp.

Hercules Powder Co., Imperial Color & Chemical Dept.

Imperial Chemical Co., Inc.

Inland Steel Container Co.

International Paper Co.

Pfaiidler Permutlt, Inc., lonao Chemical Co. Div.

Interplastio Corp., Commercial Resins Div.

Isooyanate Products, Inc.

Inter-Pacific Resins, Inc.

International Resistance Co.

Ironsides Resins, Inc.

Isoohem Resins Co.

Jamestown Paint & Vamish Co.

Jefferson Chemical Co., Inc.

John Deere Chemical Co.

Jennison-Wright Corp.

J. Meyer & Sons, Inc.

S. C. Johnson & Son, Inc.

Jennat Corp.

Jones -Blair Paint Co.

210 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22. Synthetic organic chemicals: Directory of manufacturers , 1964 Continued

Code

Name of company

Code

Name of company

JOD

Devoe & Reynolds Co., Inc., Jones-Dabney Dlv.

MET

M & T Chemicals, Inc.

JOR

W. H. & F. Jordan, Jr. Manufacturing Co.,

MFC

Molded Fiber Glass Body Co., Resin Div.

Inc.

MGR

Magruder Color Co., Inc.

JRG

Andrew Jergens Co.

MHI

Metal Hydrides, Inc.

JSC

Jersey State Chemical Co.

MID

Midland Industrial Finishes Co.

JTC

Joseph Turner & Co.

MIR

Miranol Chemical Co., Inc.

JWL

Jewel Paint & Varnish Co.

MLD

Metalead Products Corp.

MLS

Miles Laboratories, Inc., Miles Chemical Co. Div.

KAI

Kaiser Aluminum & Chemical Corp.

MMM

Minnesota Mining & Manufactijring Co.

KAl

Kali Manufacturing Co.

MNO

Monochem, Inc.

KCC

Kenneeott Copper Corp., Chino Mines Div.

MNP

Minnesota Paints, Inc.

KCH

Keystone Cheraurgic Corp.

MOA

Mona Industries, Inc.

KCU

Kenneeott Copper Corp., Utah Copper Div.

MOB

Mobay Chemical Co.

KCW

Keystone Color Works, Inc.

MOC

Marathon Oil Co., Texas Refining Div.

KEL

Kelly-Piokering Chemical Corp.

MON

Monsanto Co.

KEN

Kendall Refining Co.

MOR

Mineral Oil Refining Co.

KES

Armour Industrial Chemical Co., Kessler

MOT

Motomco, Inc.

Chemical Dlv.

MPL

Massachusetts Plastic Corp.

KET

Ketona Chemical Corp.

MPP

Midwest Plastic Products Co.

KF

Kay-Fries Chemicals, Inc.

MR

Benjamin Moore & Co.

KLS

Kilsdohk Chemical Corp.

MRA

Metro-Atlantic, Inc.

KMC

Kohler-McLister Paint Co.

MRS

Marble tte Corp.

KMP

Kelly-Moore Paint Co.

MRD

Marden-Wild Corp.

KND

Knoedler Chemical Co.

MRK

Merck & Co., Inc.

KNG

Far-Best Corp., 0. L. King Div.

MRN

Morningstar Paisley, Inc.

KHP

Knapp Products, Inc.

MRO

Marco Chemical Corp.

KON

H. Kohnstamm & Co., Inc.

MRT

Morton Salt Co., Morton Chemical Co. Div.

KPI

Kenrich Petrochemicals, Inc.

MRV

Marlowe-Van Loan Corp.

KPP

Koppers Co., Inc., Plastics Div.

MRX

Max Marx Color & Chemical Co.

KPS

Koppers Pittsburgh Co.

MSC

Mississippi Chemical Corp.

KPT

Koppers Co., Inc., Tar & Chemical Div.

MIL

Metals alts Corp.

KRM

Lawter Chemicals, Inc., Krumbhaar Resin Div.

MIO

Montrose Chemical Corp. of California

KYN

Kyanize Paints, Inc.

MTR

Baldwin-Montrose Chemical Co., Inc., Montrose

KYS

Keysor Chemical Co.

Chemical Div.

MYW

Stepan Chemical Co., Maywood Dlv.

LAK

Lakeway Chemical Co.

LAM

LaMotte Chemical Products Co.

NAC

Allied Chemical Corp., National Aniline Div.

LAS

Lasco Industries, Inc.

NCI

Union Bag-Camp Paper Corp., Nelio Chemical Div.

LEA

Leatex Chemical Co.

NOW

Nostrip Chemical Works, Inc.

LEB

Lebanon Chemical Corp.

NED

Norda Essential Oil & Chemical Co., Inc.

LEF

Leffingwell Chemical Co.

NEP

Nepera Chemical Co., Inc.

LEH

Lehigh Chemical Co.

NES

Nease Chemical Co., Inc.

LEM

B. L. Lemke & Co., Inc.

NEV

Neville Chemical Co.

LEN

Leonard Refineries, Inc.

NIL

Nilok Chemicals, Inc.

LEV

Lever Brothers Co.

NIT

Nitrin, Inc.

LIL

Eli Lilly & Co.

NIX

Nixon-Baldwin Chemicals, Inc.

LKL

Lakeside Laboratories, Div. of Colgate-

NLC

Nalco Chemical Co.

Palmolive Co.

NLF

Nalco Chemical Co., Freeport Div.

LKY

St. Regis Paper Co., Lake States Yeast &

NOC

Norac Co., Inc.

Chemical Div.

NON

A. P. Nonweiler Co.

LMI

Lawrence Mills, Inc.

NOP

Nopco Chemical Co., Inc.

LON

Mobil Finishes Co . , Inc . , American-Marietta

NOR

Norwich Pharmacal Co.

Paint Div.

NPC

Northwest Petrochemical Corp.

LPC

Lignin Products Co.

NPI

National Polychemicals, Inc.

LUB

Lubrizol Corp.

NPP

National Plastic Products Co., Inc.

LUE

George Lueders & Co.

NPV

Norris Paint & Varnish Co.

LUH

Laurel Soap Manufacturing Co.

NRS

Norse Chemical Corp.

LVR

C . Lever Co . , Inc .

NSC

National Starch & Chemical Corp.

LVY

Fred'k H. Levey Co., Inc.

NSP

Alabama Binder & Chemical Coit>.

NTB

National Biochemical Co.

MAH

Maher Color & Chemical Co.

NTC

National Casein Co.

MAK

MaoKenzie Chemical Works, Inc.

NTL

National Lead Co.

MAL

Mallinckrodt Chemical Works

NVF

National Vulcanized Fibre Co.

MAR

American Can Co., Marathon Div.

NVT

Novamont Corp.

MAY

Otto B. May, Inc.

NW

Northwestern Chemical Co.

MCA

Masonite Corp., Alpine Chemical Div.

NYC

American Dyewood Co., Inc., New York Color &

MCB

Borg-Wamer Corp., Marbon Chemical Div.

Chemical Co. Div.

MCC

McCloskey Varnish Co.

MCH

Michigan Chemical Corp.

OCF

Owens -Coming Fiberglas Corp.

MCI

Mooney Chemical Corp.

OH

Air Reduction Co., Inc., Ohio Chemical & Surgical

MCO

Mathe Chemical Co.

Equipment Co. Div.

MED

Medical Chemicals Corp.

OLH

Old Hickory Chemical Co.

MEE

Maumee Chemical Co.

OMC

Olin Mathieson Chemical Corp.

MER

Jefferson Lake Sulphin? Co., Chemical Div.

OMS

Olin Mathieson Chemical Corp., E.R. Squibb & Sons Div.

DIRECTORY OF MANUFACTURERS TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1964 Continued

Name of company

Name of company

Millmaster Onyx Corp., Onyx Chemloal Co. Div.

Orbis Products Corp.

Organics, Inc.

California Chemical Co., Oronite Div.

Roehr Chemicals, Inc.

Eagle-Picher Co., Ohio Rubber Co. Div.

C. J. Osborn Co.

Ottawa Chemical Co.

Ott Chemical Co.

California Chemloal Co., Ortho Div.

Oxo Chemicals Co.

Onyx Oils & Resins, Inc.

Oxy Chemical Co.

Pennsylvania Indiistrial Chemical Corp.

Pan American Petroleum Corp.

Pennsylvania Refining Co.

Pennsalt Chemicals Corp.

Patent Chemicals, Inc.

Pillsbury Co., Chemical Div.

Proctor Chemical Co., Inc.

Pittsburgh Chemical Co., Div. of U.S. Steel Co.

Peerless Chemical Co.

Pioneer Chemical Works, Inc.

Emery Industries, Inc., Western Div.

Pfister Chemical Works

Park, Davis & Co.

Bemoolors-Poughkeepsie, Inc.

Joseph Davis Plastics Co.

Peck's Products Co.

Pelron Corp.

S. B. Penick & Co.

Perry & Derrick Co.

Petroleum Chemicals, Inc.

Pfanstiehl Laboratories, Inc.

Phelan-Faust Paint Manufacturing Co.

Polak's Frutal Works

Chas. Pfizer & Co., Inc.

Procter & Gamble Co., Procter & Gamble Manu- facturing Co. Div.

Gulf Oil Corp., Spencer Chemical Div., Perkins Glue Branch

Pharmachem Corp.

Pierce Chemical Co.

Polymer Industries, Inc.

Pilot Chemical Co.

Pitt-Consol Chemloal Co.

Richardson Co., Richardson Polymers Div.

P-L Biochemicals, Inc.

Phillips Petroleum Co.

Plastics Engineering Co.

Plumb Chemical Corp.

Plastics Materials, Inc.

Plastics Manufacturing Co.

Premier Malt Products, Inc.

Pantasote Co.

Phoenix Oil Co.

Polymer Corp.

Pittsburgh Plate Glass Co.

Pioneer Plastics Corp.

Products Research Co.

Productol Chemical Co.

Pure Oil Co.

S. B. Penick & Co., Parsons -Plymouth Div.

Pratt & Lambert, Inc.

Purex Corp . , Ltd .

Georgia-Pacific Corp., Puget Sound Div.

Petro-Tex Chemloal Corp.

Publioker Industries, Inc.

Polyvinyl Chemicals, Inc.

Polyohemioal Laboratories, Inc.

Poly Resins

Polyrez Co., Inc.

QCP QKO

auN

RAB RBC RCC RCD HCI RDA RED REH

REL

REM

RET

REZ

RGC

RH

RIC

RIK

RIL

RIV

RLS

RMC

ROC

ROM

ROY

RFC

RPI

RSA

BSE

RT

RTC

RTF

RTX

RUB

RUR

R2X

SAC SAL SAR SBC SBR

sec

SCF

SCH

SON

SCO

SCP

SCR

SDC

SDG

SDH

SDW

SEA

SED

SEK

SEL

SEP

SEY

SF

SFA

SH

SHA

SHC

SHF

SHL SHM SHO SHP

Quaker Chemical Corp.

Quaker Oats Co.

K. J. Quinn & Co., Inc.

Raybestos-Manhattan, Inc., Raybestos Div.

Roberts Chemicals, Inc.

Rexall Chemical Co.

Richardson Co.

Reiohhold Chemicals, Inc.

Rhodia, Inc.

Red Spot Paint & Varnish Co., Inc.

Rebels Chemical Co., Div. of Armour Pharmaceutical

Co. Reliance Universal, Inc. Remington Arras Co . , Inc . Rayette , Inc . Rezolin, Inc. Rogers Corp. Rohm & Haas Co. Richfield Oil Corp. Riker Laboratories, Inc. Reilly Tar & Chemical Corp. River dale Chemical Co. Rachel Laboratories Rinshed-Mason Co.

Rook Hill Printing & Finishing Co. Roma Chemical Corp. Royoe Chemical Co. Refined Products Co. Rowland Products, Inc. R. S. A. Corp. Rosenberg Bros. & Co. F. Hitter & Co. Hitter Chemical Co., Inc. Retzloff Chemical Co. Riegel Textile Corp. Rubber Corp. of America Ruberoid Co. Rozilda Laboratories, Inc.

Sandoz, Inc.

Southeastern Adhesives Co.

Dr. Salsbury's Laboratories

Sartomer Resins, Inc.

Scher Bros . , Inc .

Schwarz BioResearoh, Inc.

Standard Chlorine Chemical Co., Inc.

Schaefer Varnish Co., Inc.

Sobering Corp.

Schenectady Chemicals, Inc.

Soholler Bros., Inc.

Standard Chemical Products, Inc.

H. P. Soberer Corp.

Martin-Marietta Corp

Sterling Drug, Inc.,

Sterling Drug, Inc.,

Sterling Drug, Inc.,

Seaboard Chemicals, Inc

Seidlitz Paint & Varnish Co.

Sekisui Plastics Corp.

Selney Co., Inc.

Southeast Polymers, Inc.

Seydel-Woolley & Co., Inc.

Stauffer Chemical Co., Industrial Chemloal Div.

Staiiffer Chemical Co., Anderson Chemloal Co. Div.

Stein, Hall & Co., Inc.

Shanco Plastics & Chemicals, Inc.

Shell Oil Co., Shell Chemical Co. Div.

National Dairy Products Corp . , Sheffield Chemical

Co. Div. Shulton, Inc., Fine Chemioals Div. Shamrock Oil & Gas Corp. Shell Oil Co. Shepherd Chemical Co.

, Southern Dyestuff Co. Div. Glenbrook Laboratories Div. Hilton-Davis Chemical Co. Div. Winthrop Laboratories Div.

212

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , 1964— Conthived

Name of company

Silmax Chemical Corp. George F. Siddall Co., Inc. Simpson Timber Co. Sinclair Refining Co. Standard Oil Co. of Ohio James P. Sipe & Co. Smith, Kline & French Laboratories Sinclair Koppers Chemical Co. SunJd-St Growers, Inc. Skelly Oil Co. Soluol Chemical Co., Inc. Sterling Drug, Inc., Salvo Chemical Div. Socony Mobil Oil Co., Inc.: Mobil Chemical Co. Div. Mobil Oil Co. Div. Stamford Chemical Co. Ansbaoher-Siegle Corp., Div. of Sun Chemical

Corp. Sonooo Products Co. Southern Nitrogen Co., Inc. SunOlin Chemical Co. Suntide Refining Co.

Sun Chemical Corp., Warwick Chemical Co. Div. Standard Oil Co. of California, California

Chemical Co. Div. Signal Oil & Gas Co., Houston Div. Sohio Chemical Co., Agent: Sohio Petroleum Co. Solar Nitrogen Chemicals, Inc. American Oil Co. (Maryland)

Solar Chemical Corp.

Witco Chemical Co., Inc., Sonneborn Div.

Thomason Industries, Inc., Southern Resin Div.

Southern Sizing Co.

Sinclair Paint Co.

General Electric Co., Silicone Products Dept,

Sinclair Petrochemicals, Inc.

Spaulding Fibre Co., Inc.

Gulf Oil Corp., Spencer Chemical Div.

Socony Paint Products Co.

Standard Pyroxoloid Corp.

Shawinigan Resins Corp.

G. D. Searle & Co.

Fred'k A. Stresen-Reuter, Inc.

A. E. Staley Manufacturing Co.

Sou-Tex Chemical Co., Inc.

Standard Dyestuff Corp.

Stange Co.

Stepan Chemical Co.

Sucro-Chemical Div. of Colonial Sugars Co.

Summit Chemical Products Corp.

Sun Oil Co.

Sullivan Varnish Co.

Solvent Chemical Co., Inc.

Sherwin-Williams Co.

Soiihegan Wood Products, Inc.

Switzer Bros., Inc.

Swift & Co.

Synthetic Chemicals, Inc.

Synthron, Inc .

Synthetic Products Co.

Synoo Resins, Inc.

Synvar Corp.

Thomas A. Edison Industries, McGraw-Edison

Co., Medical Gas Div. Taylor Corp. Universal Oil Products Co., Trubek Chemical

Co. Div. Tanatex Chemical Corp. Trylon Chemical Corp. Texlze Chemicals, Inc. Diversey Corp.

Name of company

TEN

TGL

THC

TIC

TID

TKL

TMH

TMS

TNA

TNC

TNI

TNP

TOG

TRC

TRJ

TRN

TRO

TSA

TTX

TUS

TV

TX

TXC

TXT

UCC UCP UCS UDI UHL UNC UNG UNN UNO UNP UNS UOC UPC UPF UPJ UPl

UPM UPR URC USB USI

USD USP USR UTR UVC

VAC

VAL

VAR

VB

VC

VDM VEL VGC VIC VIN VIS VLY VNC VND VPC

Tennessee Copper Co.

Triangle Chemical Co.

Thompson Chemical Co.

Tioonderoga Chemical Corp.

Tidewater Oil Co.

Thiokol Chemical Corp.

Thompson-Hayward Chemical Co.

Sterling Drug, Inc., Thomasset Colors Div.

Ethyl Corp.

Tennant Development Corp., Chemical Div.

Toni Co.

Velsicol Chemical Corp., Tensyn Div.

Tenneco Oil Co.

Toms River Chemical Corp.

Trojan Powder Co.

Trancoa Chemical Corp.

Troy Chemical Go.

Texas Alky Is, Inc.

Detrex Chemical Industries, Inc.

Texas-U.S. Chemical Co.

Tousey Varnish Co.

Texaco, Inc.

Tex Chem Co.

Textilana Corp.

A. E. Staley Manufacturing Co., UBS Chemical

Co. Div. Union Carbide Corp., Chemicals Div. Union Carbide Corp., Plastics Div. Union Carbide Coirp., Silicones Div. Universal Detergents, Inc. & Petrochemicals Co. Paul Uhlich & Co., Inc. United Cork Companies Ungerer & Co.

United Chemical Corp. of Norwood United Oil Manufacturing Co. United Chemical Products Corp. Union Starch & Refining Co., Inc. Union Oil Co. of California Upjohn Co., Polymer Chemicals Div. United States Pipe & Foundry Co. Upjohn Co. United States Plywood Corp., California Div.,

Shasta Operations Universal Oil Products Co. U.S. Peroxygen Corp. United Carbon Co. U.S. Borax Research Corp. National Distillers & Chemical Corp.:

A-B Chemical Corp. Div.

National Petro Chemical Corp. Div.

U.S. Industrial Chemicals Co. Div. U.S. Oil Co.

U.S. Plastic & Chemical Corp. Naugatuok Chemical Div. of U.S. Rubber Co. Utah Resin Co., Inc. Universal Chemicals Corp.

Vamey Chemical Co.

Valchem

Reichhold Chemicals, Inc., Varcum Chemical Div.

Verml lye-Bell

Socony Mobil Oil Co., Inc., Virginia-Carolina

Chemical Co. Div. Van De Mark Chemical Co. Velsicol Chemical Corp. Virginia Chemicals, Inc.

Stauf fer Chemical Co. , Victor Chemical Works Div. Vineland Chemical Co. Nalco Chemical Co., Visco Div. Chem-Fleur, Inc. Vanderbilt Chemical Corp. Van Dyk & Co., Inc. Verona-Pharma Chemical Corp.

DIRECTORY OF MANUFACTURERS TABLE 22. Synthetic organic chemicals: Directory of manufacturers , 1964 Continued

213

Code

Name of company

Code

Name of company

VPT

Vickers Refining Co., Inc.

WLI

White Laboratories, Inc.

VSV

Valentine Sugars, Inc., Valite Div.

WLM

Wilmot & Cassidy, Inc.

VTM

Vitamins , Inc .

WM

Wilson & Co., Inc., Wilson-Martin Div.

VTV

Vita-Var Corp., Div. of Textron Industries,

WOD

Wood Chemicals, Inc.

Inc.

WOI

Neville Chemical Co. , Chlorinated Products Div.

WON

Woonsocket Color & Chemical Co.

WAS

Washtum-Purex Co.

WPC

Warren Paint & Color Co.

WAW

W. A. Wood Co.

WRC

Wood Ridge Chemical Corp.

WAY

Philip A. Hunt Chemical Corp., Way land Chem-

WRD

Weyerhaeuser Co., Wood Products Div.

ical Div.

WSN

Washine Chemical Corp.

WBC

Worthlngton Biochemical Corp.

WTC

Witco Chemical Co., Inc.

WBQ

White & Bagley Co.

WTH

Wallace & Tieman, Inc., Harchem Div.

WCA

West Coast Adhesives Co.

WTL

Wallace & Tieman, Inc., Lucidol Div.

WDC

Western Diy Color Co.

WVA

West Virginia Pulp & Paper Co. , Polychemioals

WHI

White & Hodges, Inc.

Div.

WHl

Whitmoyer Laboratories, Inc.

WYN

Wyandotte Chemicals Corp.

WHW

Whltteraore -Wright Co., Inc.

WYT

American Home Products Corp., Wyeth Laboratories,

WIC

Wica Chemicals, Inc.

Inc. Div.

WIL

Wilson & Co., Inc., Wilson Laboratories Div.

WJ

Wamer-Jenkinson Manufacturing Co.

YAW

Young Aniline Works, Inc.

2,4 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , 1964— Contmued

SECTION 2. ALPHABETICAL DIRECTORY BY COMPANY

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Connnission for 1964 are listed below alphabetically, together with their identification codes as used in tables in pt. III. Sec. 1 of this table lists these manufacturers in the order of their identification codes]

ARD AHG ARZ AKS ARM

ARC KES AEP

Name of company

Abbott Laboratories

Acme Resin Corp

Acralite Co., Inc

Ad-Co Color Corp

Air Products & Chemicals, Inc., Houdry Process

& Chemical Co. Div. Air Reduction Co., Inc.;

Air Reduction Chemical & Carbide Co. Div

Ohio Chemical & Surgical E^iuipment Co. Div

Alabama Binder & Chemical Corp

Alamo Polymer Corp

Alco Chemical Corp

Alcolac Chemical Corp

Aldrich Chemical Co., Inc

Alliance Color & Chemical Co

Allied Chemical Corp.:

Barrett Div

Fibers Div

General Chemical Div

National Aniline Div

Harmon Color Works

Nitrogen Div

Plastics Div

Solvay Process Div

Union Texas Petroleum Div

Alox Corp

Amalgamated Chemical Corp

Amchem Products, Inc

American Alkyd Industries

American Aniline & Extract Co., Inc

American Aniline Products, Inc

American Bio-Synthetics Corp

American Brake Shoe Co., American Brakeblok Div--

American Can Co., Marathon Div

American Chemical Corp

American Cyanamid Co

American I^ewood Co., Inc., New York Color &

Chemical Co. Div. American Home Products Corp., Wyeth Laboratories, Inc. Div.

American Oil Co. (Maryland)

American Oil Co. (Texas)

American Petrochemical Corp

American Potash S; Chemical Corp

American Synthetic Rubber Corp

American Tartars Corp

Ames Laboratories, Inc

Amoco Chemicals Corp

Ancon Chemical Co

Ansbacher-Siegle Corp., Div. of Sun Chemical Corp-

Ansul Chemical Co

J^ex Chemical Co., Inc

Appleton Coated Paper Co

Applied Plastics Co., Inc

Arapahoe Chemicals, Inc

Archer- Daniels-Midland Co

Office address

Ardmore Chemical Co

Argus Chemical Corp

Arizona Chemical Co

Arkansas Co., Inc

Armour Agricultural Chemical Co

Armour & Co. :

Armour Industrial Chemical Co. Dlv-

Kessler Chemical Div

Armour Pharmaceutical Co

Uth St. and Sheridan Rd., N. Chicago, 111. 60664.

UOl Circle Ave., Forest Park, 111. 60130.

59 Kent St., Brooklyn, N.Y. 11222.

66 Lister Ave., Newark, N.J. 07105.

Widener Bldg., 1339 Chestnut St., Philadelphia, Pa. 19107.

150 E. A-2d St., New York, N.Y. 10017.

UOO E. Washington Ave., Madison, Wis. 53701.

P.O. Box 3179, Tuscaloosa, Ala. 35404.

Phillips Bldg., 16th Fl., Bartlesville, Okla. 74004.

Trenton Ave. and William St., Philadelphia, Pa. 19134.

3440 Fairfield Rd., Baltimore, m. 21226.

2371 N. 30th St., Milwaukee, Wis. 53210.

33 Avenue P, Newark, N.J. 07105.

40 Rector St., New York, N.Y. 10006.

40 Rector St., New York, N.Y. 10006.

P.O. Box 70, Morristo'.vn, N.J. 07960.

40 Rector St., New York, N.Y. 10006.

40 Rector St., New York, N.Y. 10006.

P.O. Drawer 61, Hopewell, Va. 23860.

P.O. Box 365, Morristown, N.J. 07960.

P.O. Box 271, Syracuse, N.Y. 13201.

P.O. Box 2120, Houston, Tex. 77001.

3943 Buffalo Ave., Niagara Falls, N.Y. 14302.

Ontario and Rorer Sts., Philadelphia, Pa. 19134.

Brookside Ave., Ambler, Pa. 19002;

Broad and Uth Sts., Carlstadt, N.J.

Venango and F Sts., Philadelphia, Pa.

P.O. Box 2086, Paterson, N.J. 07509.

710 W. National Ave., Milwaukee, Wis.

900 W. Maple Rd., Troy, Mich. 48012.

Neenah, Wis. 54957.

P.O. Box 9247, Long Beach, Calif. 90810.

Berdan Ave., Wayne, N.J. 07470.

374 Main St., Belleville, N.J. 07109.

07072. 19134.

53204.

P.O. Box 8299, Philadelphia, Pa. 19101.

910 S. Michigan Ave., Chicago, 111. 60680.

910 S. Michigan Ave., Chicago, 111. 60680.

3134 California St., N.E., Minneapolis, Minn. 55418.

3000 W. 6th St., Los Angeles, Calif. 90054.

P.O. Box 360, Louisville, Ky. 40201.

420 Lexington Ave., New York, N.Y. 10017.

200 Rock Lane, Milford, Conn. 06463.

130 E. Randolph Dr., Chicago, 111. 60601.

P.O. Drawer 37, Westlake, La. 70669.

441 Tompkins Ave., Staten Island, N.Y. 10305.

1 Stanton St., Marinette, Wis. 54143.

200 S. 1st St., Elizabethport, N.J. 07206.

825 E. Wisconsin Ave., i^pleton, Wis. 54910.

130 Penn St. , El Segundo, Calif. 90246.

2855 Walnut St., Boulder, Colo. 80301.

733 Marquette Ave., P.O. Box 532, Minneapolis, Minn.

55440. 840 Valley Brook Ave., I^mdhurst, N.J. 07071. 633 Court St., Brooklyn, N.Y. 11231. Ill W. 50th St., New York, N.Y. 10020. 185 Foundry St., P.O. Box 210, Newark, N.J. 07101. P.O. Box 1685, Atlanta, Ga. 30301.

110 H. Waoker Dr., Chicago, 111. 60606.

State Rd. and Cottman Ave., Philadelphia, Pa. 19135.

P.O. Box 511, Kankakee, 111. 60901.

DIRECTORY OF MANUFACTURERS TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , i5« —Continued

215

Name of company

Armstrong Cork Co

Armstrong Paint & Varnish Works, Inc

Arol Chemical Products Co

Aishland Oil & Refining Co

Astra Pharmaceutical Products, Inc

Atco Chemical- Industrial Products, Inc

Atlantic Chemical Corp

Atlantic Refining Co

Atlantic Tubing & Rubber Co

Atlas Chemical Industries, Inc., Chemicals Dlv-

Atlas Processing Co

Augusta Chemical Co

Avisun Corp

Aztec Chemicals, Inc

Baird Chemical Industries, Inc

Baker Castor Oil Co

J. T. Baker Chemical Co

Taylor Div

Baldwin-Montrose Chemical Co., Inc., Montrose Chemical Div.

Balfour Chemicals, Inc

Baltimore Paint & Chemical Corp

Barlow Chemical Corp

Bates Chemical Co

J. H. Baxter & Co

Baxter Laboratories, Inc

Bayoil Co., Inc

Beacon Chemical Industries, Inc

Beech-Nut Life Savers, Inc

Belding Chemical Industries

Belle Chemical Co., Inc

Bendix Corp., Marshall-Eclipse Div

Bennett 's- Benzol Products Co- Berkshire Color & Chemical Co- Bernoolors-Poughkeepsle, Ino- Bernz-o-Matic, Harris Paint Co. Div- Blackman-Uhler Chemical Co- Blue Arrow, Inc-

Borden Co., Borden Chemical Co. Div- Borg-Warner Corp., Marbon Chemical Div- Walter N. Boysen Co- Branchflower Co- Brand Plastics Co

Bristol-Meyers Co., Bristol Laboratories Div— -

Brooklyn Color Works, Inc

M. A. Bruder & Sons, Inc

Bryant Chemical Corp

Buckeye Cellulose Corp

Buckman Laboratories, Inc

Budd Co., Polychem Div

Burdlck & Jackson Laboratories, Inc

Burkart-Schier Chemical Co

Burroughs-Wellcome & Co. (U.S.A.), Inc

Samuel Cabot, Ino

Cadet Chemical Corp

Calcasieu Chemical Corp

California Chemical Co. :

Oronite Div

Ortho Div

Cal/Ink Co., Inc

Gallery Chemical Co

Cap-Roc, Inc., Capital Plastics Div

Caradco, Inc., Dure 1 Div

Carborundum Co., Coated Abrasives Div- Cargill, Ino

Carlisle Chemical Works, Inc-

Advance Div

I Carpenter-lforton Co

Office address

W. Liberty St., Lancaster, Pa. 176CK.

1330 S. Kilbourn Ave., Chicago, 111. 60623.

371 Wayne St., Jersey City, N.J. 07302.

UOl Winchester Ave., Ashland, Ky. 41101.

7 Neponset St., Worcester, Mass. 01606.

1259 Route 46, Parsippany, N.J. 07054-.

P.O. Box 216, Nutley, N.J. 07110.

260 S. Broad St., Philadelphia, Pa. 19101.

Mill St., Cranston, R.I. 02905.

New Mirphy Rd. and Concord Pike, Wilmington, Del. 19899.

P.O. Box 1786, Shreveport, La. 71102.

P.O. Box 660, Augusta, Ga. 30903.

P.O. Box 312, New Castle, Del. 19720.

P.O. Box 756, Elyria, Ohio 44036.

185 Madison Ave., New York, N.Y. 10016. 40 Avenue A, Bayonne, N.J. 07002. 600 N. Broad St., Phillipsburg, N.J. 08865. 600 N. Broad St., Phillipsburg, N.J. 08865. 100 Lister Ave., Newark, N.J. 07105.

1754 Thome Rd., Tacoma, Wash. 98421.

2325 Hollins Ferry Rd., Baltimore, Mi. 21230.

Barlow Lane, Ossining, N.Y. 10562.

Scottdale Rd. , Lansdowne, Pa. 19050.

120 Montgomery St., San Francisco, Calif. 94104.

6301 N. Lincoln Ave., Morton Grove, 111. 60053.

2 Union St., Peabody, Mass. 01961.

33 Richdale Ave., Cambridge, Mass. 02140.

Canajoharle, N.Y. 13317.

1407 Broadway, New York, N.Y. 10018.

P.O. Box 848, Lowell, N.C. 28089.

P.O. Box 238, Troy, N.Y. 12180.

65 W. 1st S., Salt Lake City, Utah 84110.

237 South St., Newark, N.J. 07114.

12th and Bern Sts., Reading, Pa. 19603.

45 Taylor Ave., Poughkeepsie, N.Y. 12602.

1026 N. 19th St., Tampa, Fla. 33601.

P.O. Box 1869, Spartanburg, S.C. 29301.

P.O. Box B, Jacksonville, Fla. 32203.

350 Madison Ave., New York, N.Y. 10017.

P.O. Box 68, Washington, W. Va. 26181.

1001 42d Sts., Oakland, Calif. 94608.

4501 Shilshole St. NW. , Seattle, Wash. 98107.

8400 Willow Springs Rd., Willow Springs, 111. 60480.

P.O. Box 657, Syracuse, N.Y. 13201.

681 Morgan Ave., Brooklyn, N.Y. 11222.

52d St. and Grays Ave., Philadelphia, Pa. 19143.

6 North St., N. Quincy, Mass. 02171.

2899 Jackson Ave., Memphis, Tenn. 38108.

1256 N. McLean Blvd., Memphis, Tenn. 38108.

70 S. Chapel St., Newark, Del. 19711.

1953 S. Harvey St., ^4iskegon, MLch. 49442.

1228 Chestnut St., Chattanooga, Tenn. 37402.

1 Scarsdale Rd., Tuckahoe, N.Y. 10707.

246 Summer St., Boston, Mass. 02210.

2153 Lookport-Oloott Rd., Burt, N.Y. 14028.

P.O. Box 1522, Lake Charles, La. 70604.

200 Bush St., San Francisco, Calif. 94120.

Lucas and Ortho Way, Richmond, Calif. 94800.

711 Camelia St., Berkeley, Calif. 94710.

Gallery, Pa. 16024.

250 Mill St., Rochester, N.Y. 14614.

1098 Jackson St., Dubuque, Iowa 52001.

P.O. Box 477, Niagara Falls, N.Y. 14302.

Room 2008, 3 Penn Center Plaza, Philadelphia, Pa. 19102,

and Cargill Bldg., Minneapolis, Minn. 55402. West St., Reading, Ohio 45215. 500 Jersey Ave., New Brunswick, N.J. 08903. 376 3d St., Everett, Mass. 02149.

216 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 2Z.—Synthetic organic chemicals: Directory of manufacturers , i 564 —Continued

Name of company

CES CAT

CEL

CBD CCL CCC CHT CCI CHG CTN

VLY CIS CPD

ceo

CEM CKL CHL CPC CHC CIB

CBP

CBA

CIN

CSO

CLK

CLY

CLI

CLV

COK

CBR

CP

COL

CLD

CBN

CLE

CMP

COM

DAV

CON

CTA

CPT

CWP

CTL

CO

CPV

CFA

COP

CPY

CRN

CSD

CWL

CRT

ALT

CBY CCP CHC CRZ CUL

cue

CUT

DAN PDJ DLI

Carus Chemical Co., Ino

Catalln Corp. of America

Celanese Corp. of America:

Celanese Chemical Co. Div

Celanese Plastics Co. Div

Central Processing Co

Charlotte Chemical Laboratories

Chase Chemical Corp

Chattanooga Medicine Co., Chattem Chemicals Div

Checlsmate Chemicals, Ino

Chemagro Corp

Chemetron Corp., Chemetron Chemicals, Organic Chemical Dept.

Chem-Fleur, Inc

Chemical Insecticide Corp

Chemical Products Corp

Chemico, Inc

Chemirad Corp

Chemlek Laboratories, Ino

Chemol, Ino

Chllds Pulp Colors, Ino

Chipman Chemical Co., Ino

Ciba Chemical & Dye Co

Ciba Corp . :

Ciba Pharmaceutical Co. Div

Ciba Products Co

Cindet Chemicals, Ino

Cities Service Oil Co

Clari: Oil & Refining Corp

W. A. Cleary Corp

Clintwood Chemical Co

Clover Chemical Co

Cockerille Ghemioals, Ino

Colab Resin Corp

Colgate-Palmolive Co

Collier Carbon & Chemical Corp

Colloids, Ino

Columbian Carbon Co., Pigments & Elastomers Div

Columbia Organic Chemicals Co., Ino

Commercial Products Co., Inc

Commercial Solvents Corp

Conchemco, Inc., H. B. Davis Co. Div

Concord Chemical Co., Ino

Conestoga Chemical Corp

Consolidated Paint Co

Consolidated Papers, Inc

Continental Chemical Co

Continental Oil Co

Cook Paint & Varnish Co

Cooperative Farm Chemicals Association

Coopers Creek Chemical Corp

Copolymer Rubber & Chemical Corp

Corn Products Co

Cosden Oil & Chemical Co

Cowles Chemical Co

Crest Chemical Corp

Crompton & Knowles Corp., Althouse Chemical Co. Div.

Crosby Chemicals, Ino

Croim Central Petroleum Corp

Crown Chemical Corp

Crovm Zellerbaoh Corp., Chemical Products Div~

Culver Chemical Co

Cumberland Chemical Corp

Cutter Laboratories, Ino

Office address

Mo. 64120.

Dan River Mills, Ino

Joseph Davis Plastics Co- Dawe's Laboratories, Inc-

1375 8th St., LaSalle, 111. 61301. 1 Park Ave., New York, N.Y. 10016.

522 5th Ave., New York, N.Y. 10036. 744 Broad St., Newark, N.J. 07102. P.O. Box 270, Springfield, Oreg. 97477. P.O. Box 948, Charlotte, N.C. 28201. 3527 Smallman St., Pittsburgh, Pa. 15201. 1717 W. 38th St., Chattanooga, Tenn. 37409 P.O. Box 2164, Greenville, S.C. 29602. P.O. Box 4913, Station "F", Kansas City, 386 Park Ave. S., New York, N.Y. 10016.

200 Pulaski St., Newark, N.J. 07105.

30 Whitman Ave., Metuchen, N.J. 08840.

P.O. Box 815, Cartersvllle, Ga. 30120.

2508 E. Bailey Rd., Cuyahoga Falls, Ohio 44221.

P.O. Box 187 (Ryders Lane), E. Brunswick, N.J. 08816.

4040 W. 123d St., Alsip, 111. 60658.

P.O. Box 3227, Greensboro, N.C. 27402.

43 Summit St., Brooklyn, N.Y. 11231.

1801 Murchlson Dr., Burlingame, Calif. 94011.

Route 208, Fair Lawn, N.J. 07410.

556 Morris Ave., Summit, N.J. 07901.

556 Morris Ave., Summit, N.J. 07901.

P.O. Box 907, Greensboro, N.C. 27402.

P.O. Box 300, Tulsa, Okla. 74101.

131st St. and Kedzie Ave., Blue Island, 111. 60406.

P.O. Box 749, New Brimswiok, N.J. 08903.

1 N. LaSalle St., Chicago, 111. 60602.

360 Regis Ave., Pittsburgh, Pa. 15236.

Greenwood, Va. 22943.

Main St., Tewksbury, Mass. 01876.

300 Park Ave., New York, N.Y. 10022.

714 W. Olympic Blvd., Los Angeles, Calif. 90015.

394 Frelinghuysen Ave., Newark, N.J. 07114.

380 Madison Ave., New York, N.Y. 10017.

912 Drake St., Columbia, S.C. 29205.

117 Ethel Ave., Hawthorne, N.J. 07641.

260 Madison Ave., New York, N.Y. 10016.

Bayard and Severn Sts., Baltimore, Md. 21230.

205 S. 2d St., Camden, N.J. 08103.

Wilmington Industrial Park, Wilmington, Del. 19801.

3101 E. nth St., Los Angeles, Calif. 90023.

Wisconsin Rapids, Wis. 54494.

270 Clifton Blvd., Clifton, N.J. 07015.

1300 Main, Houston, Tex. 77001.

P.O. Box 389, N. Kansas City, Mo. 64141.

P.O. Box 80, Lawrence, Kans. 66044.

River Rd., W. Conshohocken, Pa. 19428.

P.O. Box 2591, Baton Rouge, La. 70821.

717 5th Ave., New York, N.Y. 10022.

P.O. Box 1311, Big Spring, Tex. 79721.

12000 Shaker Blvd., Cleveland, Ohio 44120.

235 Emmet St., Newark, N.J. 07114.

500 Pear St., Reading, Pa. 19603.

P.O. Drawer 460, Picayune, Miss. 39466.

P.O. Box 1168, Baltimore, Md. 21203.

12 Dudley St., Providence, R.I. 02901.

Camas, Wash. 98607.

1502 N. 25th St., Melrose Park, ,111. 60160.

150 E. 42d St., New York, N.Y. 10017.

4th and Parker Sts., Berkeley, Calif. 94710.

Danville, Va. 24540.

450 Schuyler Ave., Kearny, N.J. 07032.

4800 S. Richmond St., Chicago, 111. 60632.

JDC DEG DCI DEP DSO TTX JOD DEX

DIRECTORY OF MANUFACTURERS TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1 964— Continued

217

Name of company

John Deere Chemloal Co

Degen Oil & Chemical Co

Delaware Chemicals, Ino

DePaul Chemical Co., Inc

DeSoto Chemical Coatings, Inc

Detrex Chemical Industries, Inc

Devoe & Reynolds Co., Inc., Jones-Dabney Div-

Dexter Chemical Corp

Diamond Alltali Co

Western Div

Diversey Corp

Dixie Pine Products Co., Inc

Donald A. Dodd

Dominion Products, Ino

Dover Chemical Co

Dow Badisohe Chemical Co

Dow Chemical Co

Dow Corning Corp

Drew Chemical Corp

Frank W. Dunne Co

E. I. duPont de Nemours & Co., Inc

Duraphene Corp

Dye Specialties, Inc

Eagle-Pioher Co., Ohio Ruhber Co. Div

J. S. & W. R, EaMns, Ino

Eastern Color & Chemical Co

Eastman Kodak Co

Tennessee Eastman Co. Div

Texas Eastman Co. Div

Edcan Laboratories

Thomas A. Edison Industries, MoGraw-Edison Co.

Medical Gas Div.

El Paso Natural Gas Products Co

Emery Industries, Inc

Western Div

Emkay Chemical Co

Endo Laboratories, Inc

Enjay Chemical Co., Div. of Humble Oil &

Refining Co. Epoxylite Corp

Escambia Chemical Corp- Ethyl Corp

Ethyl -Dow Chemical Co Evans Chemetics, Inc

Fabricolor Manufacturing Corp

Fairmount Chemical Co., Inc

Farac Oil & Chemical Co

Far-Best Corp., 0. L. King Div

Farmers Chemical Association, Inc

Farmers' Chemical Co

Farnow, Inc

Federal Color Laboratories

Felton Chemical Co., Inc

Fermoo Laboratories, Inc

Ferro Corp., Ferro Chemical Div

Fiberfll, Inc

Fibreboard Paper Products Corp

Filtered Rosin Products Co

Fine Organios, Ino

Firestone Tire & Rubber Co.:

Firestone Plastics Co. Div

Firestone Rubber & Latex Products Co. Div

Firestone Synthetic Rubber & Latex Co. Div—

Florasynth Laboratories, Ino

EMC Corp.:

American Viscose Div

Office address

P.O. Box 1736, Tulsa, Olcla. 74101.

200 Kellogg St., Jersey City, N.J. 07305.

726 King St., Wilmington, Del. 19801.

44-27 Purvis St., Long Island City, N.Y. 11101.

1700 S. Mt. Prospect Ave., Des Plalnes, 111. 60018.

P.O. Box 501, Detroit, Mich. 48232.

1481 S. 11th St., Louisville, Ky. 40208.

845 Edgewater Rd., Bronx, N.Y. 10474.

300 Union Commerce Bldg., Cleveland, Ohio 44114.

300 Union Commerce Bldg., Cleveland, Ohio 44114,

212 W. Monroe St., Chicago, 111. 60606.

P.O. Box 470, Hattiesburg, Miss. 39402.

8002 53d Ave. W., Everett, Wash. 98202.

882 3d Ave., Brooiayn, N.Y. 11232.

15th and Davis Sts., Dover, Ohio 44622.

P.O. Box 875, Freeport, Tex. 77541.

Main St., Midland, Mich. 48640.

P.O. Box 592, Midland, Mioh. 48641.

416 Division St., Boonton, N.J. 07005,

1007 41st St., Oakland, Calif. 94608.

1007 Market St., Wilmington, Del. 19898.

Route 14, Sterling, Conn. 06377.

26 Journal Sq., Jersey City, N,J. 07306.

Ben Hur Ave., Willoughby, Ohio 44094, 55 Berry St., Brooklyn, N.Y. 11211. P.O. Box 6161, Providence, R.I. 02904. 343 State St., Rochester, N.Y. 14650. P.O. Box 511, Kingsport, Tenn. 37662. P.O. Box 2068, Longview, Tex. 75$03. 10 Pine St., S. Norwalk, Conn. 06856. Stuyvesant Falls, N.Y. 12174.

P.O. Box 3986, Odessa, Tex. 79760.

4300 Carew Tower, Cincinnati, Ohio 45202.

8733 S. Dice Rd., Santa Fe Springs, Calif. 90670.

319 2d St., Elizabeth, N.J. 07206.

1000 Stewart Ave., Garden City, N.Y. 11533.

60 W. 49th St., New York, N.Y. 10020,

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, Calif.

91733. P.O. Box 467, Pensaoola, Fla. 32502. 100 Park Ave., New York, N.Y. 10017, Midland, Mich. 48640. 250 E. 43d St., New York, N.Y. 10017.

24-1/2 Van Houten St., Paterson, N,J, 07505.

117 Blanchard St., Newark, N.J. 07105.

147th St. and Indiana Ave., Chicago, 111. 60627.

640 Gilman St., Berkeley, Calif. 94710.

P.O. Box 67, Tyner, Tenn. 37392.

P.O. Box 591, Kalamazoo, Mich. 49005.

77 Jacobus Ave., S. Kearny, N.J. 07032.

4526 Chickering Ave., Cincinnati, Ohio 45232.

599 Johnson Ave., Brooklyn, N.Y. 11237.

4941 S. Racine Ave., Chicago, 111. 60609.

P.O. Box 349, Bedford, Ohio 44014.

1701 N. Heidelbaoh ;ive., Evansville, Ind. 47711.

1550 Powell St., Emeryville, Calif. 94608.

P.O. Box 349, Baxley, Ga. 31513.

205 Main St., Lodi, N.J. 07644.

P.O. Box 699, Pottstown, Pa. 19464. 1 Firestone Ave,, Fall River, Mass. 02722. 381 W. Wilbeth Rd., Akron, Ohio 44301. 900 Van Nest Ave., Bronx, N.Y. 10462.

1617 John F. Kennedy Blvd., Philadelphia, Pa. 19103.

218 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22. —Synthetic organic chemicals.- Directory of manufacturers , 1964 --Continued

Name of company

FMC Corp. Continued

Inorganic Chemicals Div

Niagara Chemical Div

Organic Chemicals Div

Foote Mineral Co

Foremost Chemical Products Co

Formica Corp

Foster Grant Co., Inc

Foster- Heaton Co

France, Campbell & Darling, Inc

J. P. Frank Chemical Sc Plastic Corp

Franklin Chemical Co

Freeman Chemical Corp

Frisch & Co., Inc

Fritzsche Bros., Inc

H. B. Fuller Co

W. P. Fuller Paint Co

Gamma Chemical Corp --

Gane's Chemical Works, Inc

Geigy Chemical Corp

General Aniline S: Film Corp

General Electric Co.:

Chemical Materials Dept

Insulating Materials Dept

Silicone Products Dept

General Foods Corp., Maxwell House Div

General Latex & Chemical Corp

General Mills, Inc

Chemical Div

General Plastics Manufacturing Co

General Tire & Rubber Co., Chemical Div

Geolina Business, Inc

P. D. George Co

Georgia-Pacific Corp.:

Coos Bay Div

Puget Sound Div

Gilman Paint & Varnish Co

Givaudan Corp

Glasflex, Inc

Glidden Co

Glyco Chemicals, Inc

B. F. Goodrich Co., B. F. Goodrich Chemical Co Div.

Goodrich-Gulf Chemicals, Inc

Goodyear Tire & Rubber Co

Gordon Chemical Co., Inc

W. R. Grace & Co.:

Dewey & Almy Chemical Div

Hatco Chemical Div

Nitrogen Products Div

Polymer Chemicals Div

Grain Processing Corp

Great American Chemical Corp

Great Lakes Chemical Corp

Great Western Sugar Co

Guard Chemical Co., Inc

Guardsman Chemical Coatings, Inc

Gulf Oil Corp

Spencer Chemical Div

Perkins Glue Branch

Guth Chemical Co

H & N Chemical Co

Haag Laboratories, Inc

Halby Products Co., Inc

C. P. Hall Co. of Illinois

Hamilton Chemical Corp

Office address

Sawyer Ave. and River Rd., Tonawanda, N.Y. K207, and 633

3d Ave., New York, N.Y. 10017. 100 Niagara St., Middleport, N.Y. UIOS. P.O. Box 1616, Baltimore, m. 21203. Route 100, Exton, Pa. 1934-1. P.O. Box 599, Oakland, Calif. 94604. 4614 Spring Grove Ave., Cincinnati, Ohio 45232. 289 N. Main St., Leominster, Mass. 01453. 16 E. 5th St., Paterson, N.J. 07524. N. Michigan Ave., Kenilworth, N.J. 07033. 5410 Avenue U, Brooklyn, N.Y. 11234. 2020 Bruck St., Columbus, Ohio 43207. 222 E. Main St., Port Washington, Wis. 53074. 88 E. 11th St., Paterson, N.J. 07509. 76 9th Ave., New York, N.Y. lOOll. 1150 Eustis St., St. Paul, Minn. 55108. 450 E. Grand Ave. , S. San Francisco, Calif. 94080.

355 Lexington Ave., New York, N.Y. 10017. 535 5th Ave., New York, N.Y. 10017. P.O. Box 430, Yonkers, N.Y. 10704. P.O. Box 12, Linden, N.J. 07036.

1 Plastics Ave., Pittsfield, Mass. 01203. 1 Campbell Rd., Schenectady, N.Y. 12306. Waterford, N.Y. 12188. 1125 Hudson St., Hoboken, N.J. 07030. 666 Main St., Cambridge, Mass. 02139. S. Kensington Rd. , Kankaiee, 111. 60901. Quimby St., Ossining, N.Y. 10562. 3481 S. 35th St., Taooma, Wash. 98409. 1708 Englewood Ave., Akron, Ohio 44309. P.O. Box 1557, Savannah, Ga. 31402. 5200 N. 2d St., St. Louis, Mo. 63147.

P.O. Box 869, Coos Bay, Oreg. 97420.

300 Laurel St., Bellingham, Wash. 98225.

W. 8th and Pine Sts., Chattanooga, Tenn. 37401.

109-201 Delawanna Ave., Delawanna, N.J. 07014.

Stirling, N.J. 07980.

900 Union Commerce Bldg. , Cleveland, Ohio 44115.

417 5th Ave., New York, N.Y. 10016.

3135 Euclid Ave., Cleveland, Ohio 44115.

1717 E. 9th St., Cleveland, Ohio 44114. 1144 E. Market St. , Akron, Ohio 44316. 88 Webster St., Worcester, Mass. 01603.

62 Whittemore Ave., Cambridge, Mass. 02140.

King George Post Rd., P.O. Box 27, Fords, N.J. 08863.

P.O. Box 277, ttJmphis, Tenn. 38101.

225 Allwood Rd., Clifton, N.J. 07015.

1600 Oregon St. , Muscatine, Iowa 52761.

650 Water St., Fitchburg, Mass. 21420.

2024 Filer City Rd., Filer City, Mich. 49634.

P.O. Box 5308, Terminal Annex, Denver, Colo. 80217.

N. Water St., Ossining, N.Y. 10563.

1350 Steele Ave. SW., Grand Rapids, Mich. 49502.

P.O. Drawer 2100, Houston, Tex. 77001.

610 Dwight Bldg., Kansas City, Mo. 64105.

632 Cannon Ave., Lansdale, Pa. 19446.

1455 W. Congress Pkwy., Chicago, 111. 60607.

Maltese Dr., Totowa, N.J. 07512. 14010 S. Seeley, Blue Island, 111. 60406. P.O. Box 366, Wilmington, Del. 19899. 5245 W. 73d St., Chicago, 111. 60638. 45 Andrews St., Lowell, Mass. 01853.

DIRECTORY OF MANUFACTURERS TABLE 22. Synthetic organic chemicals: Directory of manufacturers , 1964 --Continued

219

Name of company

Hampden Color S: Chemical Co

Hampshire Chemical Corp

Haima Paint Manufacturing Co., Ino

Harshaw Chemical Co

Hartman-Leddon Co

Hart Products Corp

Haveg Industries, Inc., Resin & Compound Div

Hawkeye Chemical Co

Hercules Powder Co

Imperial Color & Chemical Dept

Heresite & Chemical Co

Hess Oil & Chemical Corp

Heterochemical Corp

Hexagon laboratories, Inc

Hodag Chemical Corp

Hoechst Chemical Corp

Hoffmann-LaRoche, Inc

Hoffman-Taff, Inc

Holland-Suco Color Co

Hooker Chemical Corp

Durez Plastics Div

E. F. Houghton & Co

Houston Chemical Corp

Charles L. Huisking & Co., Inc., Clintbrook

Chemical Co. Div.

Humphrey Chemical Co

Philip A. Hunt Chemical Corp., Wayland Chemical

Div.

Husky -Dominion Briquets

I^son, Westcott & Dunning, Inc

f^sol Corp

I.C.I. (Organlcs), Inc

Imperial Chemical Co., Ino

Industrial Biooheralcals

Industrial Dyestuff Co

Inland Steel Container Co

Interchemlcal Corp. :

Color & Chemicals Div

Finishes Div

Organic Chemicals Dept

International Flavors & Fragrances, Inc

International latex Corp

International Minerals & Chemical Corp

International Paper Co

International Resistance Co

Inter-Pacific Resins, Inc

Interplastic Corp., Commercial Resins Div

Ironsides Resins, Inc

Isochem Resins Co

Isooyanate Products, Inc

Office address

KAI

KAl

KF

KMP

KEL

Jamestown Paint &. Varnish Co

Jefferson Chemical Co., Ino

Jefferson Lake Sulphur Co., Chemical Div-

Jennat Corp

Jennison-Wright Corp

Andrew Jergens Co

Jersey State Chemical Co

Jewel Paint & Varnish Co

S. C. Johnson & Son, Inc

Jones-Blair Paint Co

W. H. & F. Jordan, Jr. Manufacturing Co.,

Kaiser Aluminum & Chemical Corp-

Kali Manufacturing Co

Kay-Fries Chemicals, Ino

Kelly-Moore Paint Co

Kelly-Pickering Chemical Corp— -

5 Albany St., Springfield, Mass. 01101.

PoissonAve., Nashua, N. H. 03060.

1313 Windsor Ave., Columbus, Ohio 43211.

1945 E. 97th St., Cleveland, Ohio 44106.

60th St. and Woodland Ave., Philadelphia, Pa. 19143.

1440 Broadway, New York, N.Y. 10018.

900 Greenbank Rd., Wilmington, Del. 19808.

P.O. Box 899, Clinton, Iowa 52733.

Hercules Tower, 910 Market St., Wilmington, Del. 19899.

P.O. Box 231, Glens Falls, N.Y. 12803.

822 S. 14th St., Manitowoc, Wis. 54221.

State St., Perth Amboy, N.J. 08861.

Ill E. Hawthorne Ave., Valley Stream, N.Y. 11582.

3536 Peartree Ave., Bronx, N.Y. 10469.

7247 N. Central Park Ave., Skokie, 111. 60076.

129 Quidnlck St., W. Warwick, R.I. 02893.

324 Kingsland Rd., Nutley, N.J. 07110.

P.O. Box 1246 SSS, Springfield, Mo. 65805.

471 Howard Ave., Holland, Mich. 49424.

Buffalo Ave. and 47th St., Niagara Falls, N.Y. 14302.

Walck Rd., N. Tonawanda, N.Y. 14121.

303 W. Lehigh Ave., Philadelphia, Pa. 19133.

200 Madison Ave., New York, N.Y. 10016.

417 5th Ave., New York, N.Y. 10016.

Devine St., North Haven, Conn. 06473. Industrial Circle, Lincoln, R.I. 02865.

P.O. Box 380, Cody, Wyo. 82414.

Charles and Chase Sts., Baltimore, IJH. 21201.

1100 Seneca Ave., Olean, N.Y. 14761.

55 Canal St., Providence, R.I. 02901.

W. 6th and Grass Sts., Shenandoah, Iowa 51601.

Edison Industrial Center, Edison, N.J. 08817.

Dexter Rd., E. Providence, R.I. 02914.

6532 S. Menard Ave., Chicago, 111. 60638.

150 Wagaraw Rd., Hawthorne, N.J. 07506.

1255 Broad St., Clifton, N.J. 07015.

P.O. Box 8, Route 17, Carlstadt, N.J. 07072.

521 W. 57th St., New York, N.Y. 10019.

Playtex Park, Dover, Del. 19901.

5401 Old Orchard Rd., Skokie, 111. 60078.

220 E. 42d St., New York, N.Y. 10017.

401 N. Broad St., Philadelphia, Pa. 19108.

P.O. Box 445, Sweet Home, Oreg. 97386.

102 W. Fairfield Ave., St. Paul, Minn. 55107.

270 W. Mound St., Columbus, Ohio 43215.

Cook St., Unoom, R.I. 02865.

900 Wilmington Rd., New Castle, Del. 19720.

108 Main St., Jamestown, Pa. 16134.

P.O. Box 53300, Houston, Tex. 77052.

1914 Haden Rd., Houston, Tex. 77015.

137 W. 168th St., Gardena, Calif. 90247.

P.O. Box 4187, Station E, Toledo, Ohio 43609.

2535 Spring Grove Ave., Cincinnati, Ohio 45214.

59 Lee Ave., Haledon, N.J. 07508.

345 N. Western Ave., Chicago, 111. 60612.

1525 Howe St., Racine, Wis. 53403.

6969 Denton Dr., Dallas, Tex. 75235.

Barclay Bldg., 1 Belmont Ave., Bala Cynwyd, Pa. 19004.

P.O. Box 337, Gramercy, La. 70052. 427 E. Mayer St., Philadelphia, Pa. 19125. 360 Lexington Ave., New York, N.Y. 10017. 1015 Commercial St., San Carlos, Calif. 94070. 956 Bransten Rd., San Carlos, Calif. 94070.

220

SYNTHETIC ORGANIC CHEMICALS, 1964 TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1964— Continued

Name of compaiiy

Office address

Kendall Refining Co

Kennecott Copper Corp. :

Chino Mines Div

Utah Copper Div

Kenrioh Petrochemicals, Inc

Ketona Chemical Corp

Keysor Chemical Co

Keystone Chemurgio Corp

Keystone Color Works, Inc

Kilsdoni Chemical Corp

Koapp Products, Inc

Knoedler Chemical Co

Kohler-McLister Paint Co

H. Kohnstanm & Co., Ino

Koppers Co., Inc.:

Plasties Div

Tar & Chemical Div

Koppers Pittsburgh Co

Kyanize Paints, Ino

lalsBSide laboratories, Div. of Colgate- Palmolive Co.

Lakeway Chemical Co

LaMotte Chemical Products Co

Lancaster Chemical Corp., Gordon Chemicals Co Div.

Lasco Industries, Inc

Laurel Soap Manufacturing Co

Lawrence Mills, Inc

Lawter Chemicals, Inc., Krumbhaar Resin Div

Leatex Chemical Co

Lebanon Chemical Corp

Leffingwell Chemical Co

Lehigh Chemical Co

B. L. Lemke & Co., Inc

Leonard Refineries, Inc

Lever Brothers Co

C. Lever Co., Inc

Fred'k H. Levey Co., Ino

Lignin Products Co

Eli Ully & Co

Lubrizol Corp

George Lueders & Co

M & T Chemicals, Ino

MaoKenzie Chemical Works, Ino

Magruder Color Co., Inc

Maher Color & Chemical Co

Mallinokrodt Chemical Works

Marathon Oil Co., Texas Refining Div

Marblette Corp

Marco Chemical Corp

Marden-Wild Corp

Marlowe-Van Loan Corp

Martin-Marietta Corp. ;

Ridgway Color & Chemical Div

Southern Dyestuff Co. Div

Max Marx Color & Chemical Co

Masonite Corp., Alpine Chemical Div

Massachusetts Plastic Corp

Mathe Chemical Co

Maumee Chemical Co

Otto B. May, Inc

McCloskey Varnish Co

Medical Chemicals Corp

Merck & Co., Inc

Metalead Products Corp

Itetal Hydrides, Inc

Metalsalts Corp

Metro-Atlantic, Ino

1177 Kendall Ave., Bradford, Pa. 16701.

Hurley, N. Mex. 850^3.

P.O. Box 1650, Salt Lake City, Utah 84110.

Foot of E. 22d St., Bayonne, N.J. 07002.

P.O. Box 6565, Tarrant Branch, Birmingham, Ala. 35217.

26000 Bouquet Canyon Rd., Saugus, Calif. 91350.

R.D. #2, Bethlehem, Pa. 18017.

151 W. Gay Ave., York, Pa. 17403.

c/o Pfister Chemical Works, Ridgefield, N.J. 07657.

180 Hamilton Ave., Lodi, N.J. 07644.

651 High St., Lancaster, Pa. 17604.

P.O. Box 546, Denver, Colo. 80201.

161 Avenue of the Americas, New York, N.Y. 10013.

Koppers Bldg., Pittsburgh, Pa. 15219. Koppers Bldg., Pittsburgh, Pa. 15219. Koppers Bldg., Pittsburgh, Pa. 15219. 2d and Boston Sts., Everett, Mass. 02149.

1707 E. North Ave., Milwaukee, Wis. 53201.

5025 Evanston Ave., Muskegon, Mich. 49443.

Chestertown, Md. 21620.

Broad and 13th Sts., Carlstadt, N.J. 07071.

1561 Chapin Rd., Montebello, Calif. 90640.

Thompson and Tioga Sts., Philadelphia, Pa. 19134.

19 S. Canal St., Lawrence, Mass. 01843.

3550 Touhy Ave., Chicago, 111. 60645.

2722 N. Hancock St., Philadelphia, Pa. 19133.

P.O. Box 693, Lebanon, Pa. 17042.

P.O. Box 1187, Perry Annex, Whittier, Calif. 90604.

P.O. Box 120, Chestertown, Md. 21620.

199 Main St., Lodi, N.J. 07644.

E. Superior St., Alma, Mich. 48801.

390 Park Ave., New York, N.Y. 10022.

Howard and Huntington Sts., Philadelphia, Pa. 19133.

380 Madison Ave., New York, N.Y. 10017.

P.O. Box 960, Erie, Pa. 16512.

740 S. Alabama St., Indianapolis, Ind. 46206.

29400 Lakeland Blvd., Wiokliffe, Ohio 44-092.

427 Washington St., New York, N.Y. 10013.

Woodbridge Rd. and Randolph Ave., Rahway, N.J. 07065.

1 Cordello Ave., Central Islip, L. I., N.Y. 11722.

2385 Richmond Terrace, Staten Island, N.Y. 10302.

1700 N. Elston Ave., Chicago, 111. 60622.

P.O. Box 5439, St. Louis, Mb. 63160.

P.O. Box 1191, Texas City, Tex. 77591.

37-31 30th St., Long Island City, N.Y. 11101.

1711 W. Elizabeth Ave., Linden, N.J. 07036.

500 Columbia St., Somerville, Mass. 02143.

1508 Joshua Circle, High Point, N.C. 27261.

75 Front St., Ridgway, Pa. 15853.

P.O. Box 10098, Charlotte, N.C. 28201.

192 Coit St., Irvington, N.J. 07111.

P.O. Box 2392, Gulf port. Miss. 39503.

West Ave., Ludlow, Mass. 01056.

169 Milbank St., Lodi, N.J. 07644.

1310 Expressway Dr., Toledo, Ohio 43608.

52 Amsterdam St., Newark, N.J. 07105.

7600 State Rd., Philadelphia, Pa. 19136.

4122 W. Grand Ave., Chicago, 111. 60639.

126 E. Lincoln Ave., Rahway, N.J. 07065.

P.O. Box 11005, 2901 Park Blvd., Palo Alto, Calif. 94

12-24 Congress St., Beverly, Mass. 01915.

200 Wagaraw Rd., Hawthorne, N.J. 07507. 2072 Smith St., Centerdale, R.I. 02911.

DIRECTORY OF MANUFACTURERS 221

TABLE 22. -Synthetic organic chemicals: Directory of manufacturers , i564— Continued

Name of company

J. Meyer & Sons, Inc

Michigan Chemical Corp

Midland Industrial Finishes Co

Midwest Plastic Products Co

Miles Laboratories, Inc., Miles Chemical Co. Div Millmaster Onyx Corp. :

Berkeley Chemical Dept

Onyx Chemical Co. Div

Mineral Oil Refining Co

Minnesota Mining & Manufacturing Co

Minnesota Paints, Ino

Miranol Chemical Co., Inc

Mississippi Chemical Corp

Mobay Chemical Co

Mobil Finishes Co., Inc.:

Aneri can- Marietta Paint Div

Arco Div

Ferbert-Schorndorfer Div

Molded Fiber Glass Body Co. , Resin Div

Mona Industries, Inc

Monochem, Inc

Monsanto Co. :

Chemstrand Co. Div

Chocolate Bayou Plant

Gering Plastics Dept

Organic Chemical Div

Plastics Div

Western Div

Montrose Chemical Corp. of California

Mooney Chemical Corp

Benjamin Moore & Co

Morningstar Paisley, Inc

Morton Salt Co., Morton Chemical Co. Div- Motomoo, Inc

Nalco Chemical Co

Freeport Div

Visco Div

National Biochemical Co

National Casein Co

National Dairy Products Corp. :

Humio Products Chemical Div

Sheffield Chemical Co. Div

National Distillers & Chemical Corp. :

A-B Chemical Corp. Div

National Petro Chemical Corp. Div

U.S. Industrial Chemicals Co. Div

National Lead Co

National Plastic Products Co., Ino

National Polychemicals, Inc

National Starch & Chemical Corp

National Vulcanized Fibre Co

Naugatuck Chemical Div. of U.S. Rubber Co-

Nease Chemical Co., Inc

Nepera Chemical Co., Inc

Neville Chemical Co

Chlorinated Products Div

Nilok Chemicals, Inc

Nitrin, Inc

Nixon-Baldwin Chemicals, Inc

A. P. Nonweiler Co

Nopco Chemical Co., Ino

Norac Co., Ino

Norda Essential Oil & Chemical Co. , Inc---

Norris Paint & Varnish Co

Norse Chemical Corp

Northwestern Chemical Co

Office address

-1321 N. ith St., Philadelphia, Pa. 19140.

500 N. Bankson St., St. Louis, Mich. 48880.

P.O. Box 620, E. Water St., Waukegan, 111. 60086.

3251 Chicago Rd., Steger, 111. 64075.

1127 Myrtle St., Elkhart, Ind. 46514.

99 Park Ave., New York, N.Y. 10016.

190 Warren St., Jersey City, N.J. 07302.

4401 Park Ave., Dickinson, Tex. 77539.

2501 Hudson Rd., St. Paul, Minn. 55119.

1101 S. 3d St., Minneapolis, Minn. 55415.

277 Coit St., Irvington, N.J. 07111.

P.O. Box 388, Yazoo City, Miss. 39194.

Penn Lincoln Parkway, W. Pittsburgh, Pa. 15205.

1630 West Hill St., Louisville, Ky. 40210. 7301 Bessemer Ave., Cleveland, Ohio 44127. 12815 Elrawood Ave., Cleveland, Ohio 44111. 4501 Benefit Ave., Ashtabula, Ohio 44004. 65 E. 23d St., Paterson, N.J. 07524. P.O. Box 488, Geismar, La. 70734.

350 5th Ave., New York, N.Y. 10001.

P.O. Box 711, Alvin, Tex. 77511.

N. 7th St. and Monroe Ave., Kenilworth, N.J. 07033.

800 N. Lindbergh Blvd., St. Louis, Mo. 63166.

812 Monsanto Ave., Springfield, Mass. 01102; P.O. Box- 1311,

Texas City, Tex. 77591; and River Ed., Addyston, Ohio

45001. 9229 E. Marginal Way S. , Seattle, Wash. 98108. 500 S. Virgil Ave., Los Angeles, Calif. 90005. 2303 Scranton Rd., Cleveland, Ohio 44113. 548 5th Ave., New York, N.Y. 10036. 1770 Canalport Ave., Chicago, 111. 60616.

110 N. Waoker Dr., Chicago, 111. 60606. 89 Terminal Ave., Clark, N.J. 07066.

6216 W. 66th Place, Chicago, 111. 60638. 6216 W. 66th Place, Chicago, 111. 60638. P.O. Box 87, Sugar Land, Tex. 77478. 3127 W. Lake St., Chicago, 111. 60612. 601 W. 80th St., Chicago, 111. 60620.

P.O. Box 398, Hfemphis, Tenn. 38101. P.O. Box 630, Norwich, N.Y. 13815.

99 Park Ave., New York, N.Y. 10016.

99 Park Ave., New York, N.Y. 10016.

99 Park Ave., New York, N.Y. 10016.

111 Broadway, New York, N.Y. 10006. Odenton, Vd. 21113.

51 Eames St., Wilmington, Mass. 01887.

750 3d Ave., New York, N.Y. 10017.

Maryland Ave. and Beech St., Wilmington, Del. 19899.

Naugatuck, Conn. 06771.

P.O. Box 221, State College, Pa. 16801.

Route 17 and Averill Ave., Harriman, N.Y. 10926.

Neville Island P.O., Pittsburgh, Pa. 15225.

Neville Island P.O., Pittsburgh, Pa. 15225.

Mill St. and N. Transit, Lookport, N.Y. 14094.

P.O. Box 233, Cordova, 111. 61242.

Nixon, N.J. 08818.

P.O. Box 1007, Oshkosh, Wis. 54902.

60 Park PI., Newark, N.J. 07101.

405 S. Motor Ave., Azusa, Calif. 91703.

475 10th Ave., New York, N.Y. 10001.

1710 Front St. NE. , Salem, Oreg. 97303.

2121 Norse Ave., Cudahy, Wis. 53110.

120 N. Aurora St., W. Chicago, 111. 60185.

222 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22.— Synthetic organic chemicals: Directory of manufacturers , i564— Continued

NPC NOR NOW NVT

CMC CMS OXR OPC OEG OSB

cyiA

OTC OCF 0X0 OXY

PLB

iiMR

PAM

PNT

PD

PAT

CCH

PEK

PCH

PEL

PEN

PRP

PAS

PAI

PAR

PER

PET

PTT

PEN

IOC

PCW

PFZ

PHR

PFP

PLC PNX PIC PBY PIL PCI PPL PIT PCC PPG PIS PMC

aiA

PLU PFW PYL POL PI I PYR PYZ PVI GRS PRT PMP PG

Name of company

Northwest Petrochemical Corp-

Norwich Pharmacal Co

Nostrip Chemical Works, Inc--

Novamont Corp

Nyanza, Inc

Old Hickory Chemical Co-

Office address

Olin Mathieson Chemical Corp-

E. R. Squibb & Sons Div

Onyx Oils & Resins, Ino

Orbis Products Corp

Organics, Inc

C. J. Osbom Co

Ottawa Chemical Co

Ott Chemical Co

Owens-Corning Fiberglas Corp-

Oxo Chemicals Co

Oxy Chemical Co

Div-

P-L Biochemicals, Inc

Pacific Resins & Chemical Co

Pan American Petroleum Corp

Pantasote Co

Parke, Davis & Co

Patent Chemicals, Inc

Pearsall Chemical Co

Peck's Products Co

Peerless Chemical Co

Pelron Corp

S. B. Peniok & Co

Parsons-Plymouth Div

Pennsalt Chemicals Corp

Pennsylvania Industrial Chemical Corp

Pennsylvania Refining Co

Perry & Derrick Co

Petroleum Chemicals, Ino

Petro-Tex Chemical Corp

Pfanstiehl Laboratories, Ino

Pfaudler Permutit, Inc., lonao Chemical Co,

Pfister Chemical Works

Chas. Pfizer & Co., Inc

Pharmachem Corp

Phelan-Faust Paint Manufacturing Co

Phelan's Resins & Plastics Div

Phillips Petroleum Co

Phoenix Oil Co

Pierce Chemical Co

Pillsbury Co., Chemical Div

Pilot Chemical Co

Pioneer Chemical Works, Ino

Pioneer Plastics Corp

Pitt-Consol Chemical Co

Pittsburgh Chemical Co., Div. of U.S. Steel Co-'

Pittsburgh Plate Glass Co

Plastics Engineering Co ^^

Plastics Manufacturing Co

Plastics Materials, Inc

Plumb Chemical Corp

Polak's Frutal Works

Polychemioal Laboratories, Ino

Polymer Corp

Polymer Industries, Inc

Poly Resins

Polyrez Co., Inc

Polyvinyl Chemicals, Inc

Pontiao Refining Corp

Pratt & Lambert, Ino

Premier Malt Products, Inc

Procter & Gamble Co., Procter & Gamble Manu- facturing Co. Div.

P.O. Box 99, Anaoortes, Wash. 98221. 17 Eaton Ave., Norwich, N.Y. 13815. 182 Liberty Ave., Jamaica, N.Y. 11412. P.O. Box 189, Kenova, W. Va. 25530. Magunco Rd., Ashland, Mass. 01721.

c/o Stauffer Chemical Co., 380 Madison Ave.,

New York, N.Y. 10017. AA5 W. 59th St., New York, N.Y. 10019. 460 Park Ave., New York, N.Y. 10022. 95 Broad St., New York, N.Y. 10004. 475 10th Ave., New York, N.Y. 10018. 1724 Greenleaf Ave., Chicago, 111. 60628. 1301 W. Blancke St., Linden, N.J. 07036. 700 N. Wheeling St., Toledo, Ohio 43605. 500 Agard Rd., Muskegon, Mich. 49945. National Bank Bldg., Toledo, Ohio 43614. 130 E. Randolph Dr., Chicago, 111. 60601. P.O. Box 28, Hackettstown, N.J. 07840.

1037 W. McKinley Ave., Milwaukee, Wis. 53205.

3400 13th Ave. SW. , Seattle, Wash. 98134.

P.O. Box 591, Tulsa, Okla. 74102.

26 Jefferson St., Passaic, N.J. 07056.

Foot of Jos. Campau, Detroit, Mich. 48232.

335 McLean Blvd., Paterson, N.J. 07504.

P.O. Box 108, Phillipsburg, N.J. 08865.

P.O. Box 14508, St. Louis, Mo. 63178.

3850 Oatanan Blvd., Detroit, Mich. 48204.

7847 W. 47th St., ^yons, 111. 60534.

100 Church St., New York, N.Y. 10008.

100 Church St., New York, N.Y. 10008.

3 Penn Center, Philadelphia, Pa. 19102.

120 State St., P.O. Box 240, Clairton, Pa. 15025.

Union Bank Bldg., Butler, Pa. 16001.

2510 Highland Ave., Norwood, Ohio 45212.

P.O. Box 1522, Lake Charles, La. 70604.

P.O. Box 2584, Houston, Tex. 77001.

1219 Glen Rook Ave., Waukegan, 111. 60086.

Birmingham, N.J. 08011.

Linden Ave., Ridgefield, N.J. 07657.

235 E. 42d St., New York, N.Y. 10017.

Broad and Wood Sts., Bethlehem, Pa. 18015.

932 Loughborough Ave., St. Louis, Mo. 63111.

Oak St. and Buff Rd., Burlington, Iowa 52602.

Bartlesville, Okla. 74004.

9505 Cassius Ave., Cleveland, Ohio 44105.

P.O. Box 117, Rockford, 111. 61105.

1152 Pillsbury St., Minneapolis, Minn. 55402.

11756 Burke St., Santa Fe Springs, Calif. 90670.

940 N. Delaware Ave., Philadelphia, Pa. 19123.

Pioneer Ave . , Sanf ord , Maine 04073 .

191 Doremus Ave., Newark, N.J. 07105.

Grant Bldg., Pittsburgh, Pa. 15219.

1 Gateway Center, Pittsburgh, Pa. 15222.

1607 Geele Ave., Sheboygan, Wis. 53082.

2700 S. Westmoreland, Dallas, Tex. 75224.

New South Rd., Hicksville, N.Y. 11801.

4837 James St., Philadelphia, Pa. 19137.

33 Sprague Ave., Middletown, N.Y. 10941.

490 Hunts Point Ave., New York, N.Y. 10059.

2120 Fairmont Ave., Reading, Pa. 19603.

Viaduct Rd., Springdale, Conn. 06879.

11655 Wicks St., Sun Valley, Calif. 91352.

P.O. Box 320, Woodbury, N.J. 08096.

26 Howley St., Peabody, Mass. 01961.

P.O. Box 1581, Corpus Christi, Tex. 78403.

75 Tonawanda St., Buffalo, N.Y. 14207.

917 W. Juneau Ave., Milwaukee, Wis. 53201.

Ivorydale Technical Center, Cincinnati, Qhio 45217.

PRD PRC PUB PRO PKX

RSA ELS

RAB RET RED RPC REH

RCI VAE RIL REL

REM

RTF

RCC

CFC

EEZ

RDA

RCD

PIA

RIC

RTX

RIK

RMC

RT

RTC

RIV

RBC

ROC

ORT

RGC

RSB RPI ROY RZL RUB RUR

SAL S

SAR SCF SON SBC SCR SCH SCO SBR SEA SRL SED

DIRECTORY OF MANUFACTURERS TABLE 22. —Synthetic organic chemicals: Directory of manufacturers , 1964— Continued

223

Name of company

Proctor Chemical Co., Inc-

Productol Chemical Co

Products Research Co

Publicker Industries, Inc-

Pure Oil Co

Purex Corp., Ltd

Quaker Chemical Corp

Quaker Oats Co

K. J. Quinn & Co., Inc-

R. S. A. Corp

Rachel Laboratorles-

Rayhestos-Manhattan, Inc., Raybestos Div

Rayette, Inc

Red Spot Paint & Varnish Co., Inc

Refined Products Co

Rehels Chemical Co., Dlv. of Armour Pharma- ceutical Co.

Relchhold Chemicals, Inc

Varcum Chemical Dlv

Rellly Tar & Chemical Corp

Reliance Universal, Inc

Remington Arms Co., Inc

Retzloff Chemical Co

Rexall Chemical Co

Rexall Chemical Co. - Kearny

Rezolin, Inc

Rhodia, Inc

Richardson Co

Richardson Polymers Div

Richfield Oil Corp

Riegel Textile Corp

Hiker Laboratories, Inc

Rinshed-Mason Co

F. Ritter & Co

Ritter Chemical Co., Inc

Rlverdale Chemical Co

Roberts Chemicals, Inc

Rock Hill Printing & Finishing Co-

Roehr Chemicals, Inc

Rogers Corp

Rohm & Haas Co

Roma Chemical Corp

Rosenberg Bros. & Co

Rowland Products, Inc

Royce Chemical Co

Rozilda Laboratories, Inc

Rubber Corp. of America

Ruberoid Co

St. Regis Paper Co

Chemical Dlv. Dr. Salsbury's Laboratories— Sandoz, Inc

Dyestuff Div., Pigment Dept

Sartomer Resins, Inc

Schaefer Vamlsh Co., Inc

Schenectady Chemicals, Inc

ScherBros., Inc

R. P. Scherer Corp

Schering Corp

Scholler Bros., Inc

Schwarz BioResearch, Inc

Seaboard Chemicals, Inc

G. D. Searle & Co

Seidlitz Paint & Vamish Co

Lake States Yeast &

Office address

P.O. Box 399, Salisbury, N.C. 28144.. 615 S. Flower St., Los Angeles, Calif. 90017. 2919 Empire Ave., Burbank, Calif. 91504. 1429 Walnut St., Philadelphia, Pa. 19102. 20C E. Gulf Rd., Palatine, 111. 60067. 5101 Clark Ave., Lakewood, Calif. 90712.

Elm, Lime, and Sandy Sts . , Conshohocken, Pa. 19428. Merchandise Mart Plaza, Chicago, 111. 60654. 195 Canal St., Maiden, Mass. 02148.

690 Saw Mill River Rd., Ardsley, N.Y. 10502.

P.O. Box 9095, 700 Henry Ford Ave., Long Beach, Calif.

90810. 75 E. Main St., Stratford, Conn. 06601. 261 E. 5th St., St. Paul, Minn. 55101. 110 Main St., Evansville, Ind. 47711. 624 Schuyler Ave., Lyndhurst, N.J. 07071. 325 Snyder Ave., Berkeley Heights, N.J. 07922.

525 N. Broadway, White Plains, N.Y. 10602.

Niagara Falls, N.Y. 14302.

1615 Merchants Bank Bldg., Indianapolis, Ind. 46204.

4730 Crittenden Dr., Louisville, Ky. 40221, and P.O. E

1113, Houston, Tex. 77001. 939 Bamum Ave., Bridgeport, Conn. 06602. P.O. Box 45296, Houston, Tex. 77045. 8480 Beverly Blvd., Los Angeles, Calif. 90054. 1106 Harrison Ave., Kearny, N.J. 07029. 1651 18th St., Santa Monica, Calif. 90404. 60 E. 56th St., New York, N.Y. 08901. 27th Ave. and Lake St., Melrose Park, 111. 60160. 345 Morgan Lane, West Haven, Conn. 06516. 555 S. Flower St., Los Angeles, Calif. 90054. 260 Madison Ave., New York, N.Y. 10016. 19901 Nordhoff St., Northridge, Calif. 91326. 5935 Milford Ave., Detroit, Mich. 48210. 4001 Goodwin Ave., Los Angeles, Calif. 90039. 403 W. Main St., Amsterdam, N.Y. 12011. 220 E. 17th St., Chicago Heights, 111. 60411. P.O. Box 546, Nltro, W. Va. 25143. Rock Hill, S.C. 29731.

52-20 37th St., Long Island City, N.Y. 11101. Main St., Rogers, Conn. 06263. 222 W. Washington Sq., Philadelphia, Pa. 19105. 900 Passaic Ave., E. Newark, N.J. 07029. 100 Landing Ave., Smithtown, N.Y. 11787. Fairview Lane, Kensington, Conn. 06037. Carlton Hill P.O., E. Rutherford, N.J. 07073. 814 Madison St., Hoboken, N.J. 07030. New South Rd., Hicksville, N.Y. 11802. S. Bound Brook, N.J. 08880.

603 W. Davenport St., Rhlnelander, Wis. 54501.

500 Gilbert St., Charles City, Iowa 50616.

P.O. Box 357, Fair Lawn, N.J. 07410.

61-63 Van Dam St., New York, N.Y. 10013.

P.O. Box 56, Essington, Pa. 19029.

15th and Magnolia Sts., Louisville, Ky. 40210.

Congress St. and 10th Ave., Schenectady, N.Y. 12301.

P.O. Box 538, Allwood Station, Clifton, N.J. 0701?^.

9425 Grinnell Ave., Detroit, Mich. 48213.

1011 Morris Ave., Union, N.J. 07083.

Collins and Westmoreland Sts., Philadelphia, Pa. 1913

Mountain View Ave., Orangeburg, N.Y. 10962.

30 Foster St., Salem, Mass. 01971.

P.O. Box 5110, Chicago, 111. 60680.

18th and Garfield Sts., Kansas City, Mo. 64141.

224 SYNTHETIC ORGANIC CHEMICALS. 1964

TABLE 22. Synthetic organic chemicals: Directory of manufacturers , i 964- -Continued

Name of company

Office address

Seklsui Plastics Corp

SeLney Co., Inc

Seydel-Woolley & Co., Inc

Shamrock Oil & Gas Corp

Shanco Plastics & Chemicals, Inc

Shawinigan Resins Corp

Shell Oil Co

Shell Chemical Co. Div

Shepherd Chemical Co

Sherwin-Williams Co

Shulton, Inc., Fine Chemicals Div

George F. Siddall Co., Inc

Signal Oil & Gas Co., Houston Div

Silmar Chemical Corp

Simpson Timber Co

Sinclair Koppers Chemical Co

Sinclair Paint Co

Sinclair Petrochemicals, Inc

Sinclair Refining Co

James B. Sipe & Co

Skelly Oil Co

G. Frederick Smith Chemical Co

Smith, Kline & French Laboratories

Socony Mobil Oil Co., Inc. :

Mobil Chemical Co. Div

Mobil Oil Co. EtLv

Virginia- Carolina Chemical Co. Div

Socony Paint Products Co

Sohio Chemical Co., Agent:

SoMo Petroleum Co

Solar Nitrogen Chemicals, Inc

Solar Chemical Corp

Soluol Chemical Co., Inc

Solvent Chemical Co., Inc

Sonoco Products Co

Souhegan Wood Products, Inc

Sou- Tex Chemical Co., Inc

Southeastern Adhesives Co

Southeast Polymers, Inc

Southern Nitrogen Co., Inc

Southern Sizing Co

Spaulding Fibre Co., Inc

A. E. Staley Ifenufacturing Co

UBS Chemical Co. Div

Stamford Chemical Co

Standard Brands , Inc . , Clinton Com Processing Co. Div.

Standard Chemical Products, Inc

Standard Chlorine Chemical Co., Inc

Standard Eyestuff Corp

Standard Oil Co. of California, California Chemical Co. Div.

Standard Oil Co. of Ohio

Standard Pyroxoloid Corp

Stange Co

Stauffer Chemical Co. ;

Anderson Chemical Co. Div

Calhio Chemicals Div

Industrial Chemical Div

Victor Chemical Works Div

Stein, Hall & Co., Inc

Stepan Chemical Co

Maywood Div

Sterling Drug, Inc.:

Glenbrook Laboratories Div

Hilton-Davis Chemical Co. Div

Salvo Chemical Div

Thomasset Colors Div

Winthrop Laboratories Div

666 Dietrich Ave., Hazelton, Pa. 18201.

65 9th St. Bldg. 15, Brooklyn, N.X. 11215.

748 Rice St. NW. , Atlanta, Ga. 30318.

P.O. Box 631, Amarillo, Tex. 79105.

2716 Kenmore Ave., Tonawanda, N.Y. 1<H50.

6M- Monsanto Ave., Springfield. Mass. 01101.

50 W. 50th St., New York, N.Y. 10020.

110 W. 51st St., New York, N.Y. 10020.

2803 Highland Ave., Cincinnati, Ohio ■i5212.

101 Prospect Ave. NW. , Cleveland, Ohio 44101.

697 Route 46, Clifton, N.J. 07015.

P.O. Box 925, Spartanburg, S.C. 29301.

P.O. Box 5008, Harrisburg Station, Houston, Tex. 77012.

12335 S. Van Ness Ave., Hawthorne, Calif. 90250.

2301 N. Columbia Blvd., Portland, Oreg. 97217.

P.O. Box 5536, Houston, Tex. 77012.

3960 E. Washington Blvd., Los Angeles, Calif. 90023.

600 5th Ave., New York, N.Y. 10020.

600 5th Ave., New York, N.Y. 10020.

P.O. Box 8010, Pittsburgh, Pa. 15216.

P.O. Box 1650, Tulsa, Okla. 74102.

867 McKinley Ave., Columbus, Ohio 43223.

1500 Spring Garden St., Philadelphia, Pa. 19101.

150 E. 42d St., New York, N.Y. 612 S. Flower St., Los Angeles. P.O. Box 3311, Beaumont, Tex. 401 E. Main St., Richmond, Va. Ifetuchen, N.J. 08840.

10017.

Calif. 90054, and

77704. 23208.

621 Republic Bldg., Cleveland, Ohio 44115.

621 Republic Bldg., Cleveland, Ohio 44115.

36 Ifonument Sq., Leominster, Mass. 01453.

Green Hill and Market Sts., W. Warwick, R.I. 02893.

341 Commercial St., Maiden, Ifess. 02148. Hartsville, S.C. 29550.

Wilton, N.H. 03086.

E. Catawba Ave., Atount Holly, N. C. 28120.

P.O. Box 791, Lenoir, N. C. 28645.

P.O. Box 309, Chattanooga, Tenn. 37401.

P.O. Box 246, Savannah, Ga. 31402.

P.O. Box 391, East Point, Ga. 30044.

310 Wheeler St., Tonawanda, N.Y. 14152.

N. 22d and Eldorado Sts., Decatur, 111. 62525.

491 Main St., Cambridge, Mass. 02142.

45 Jefferson St., P.O. Box 1131, Stamford, Conn. 06940

Clinton, Iowa 52733.

1301 Jefferson St., Hoboken, N.J. 07030. 1015 Belleville Turnpike, Kearny, N.J. 07032. 19 E. 5th St., Paterson, N.J. 07524. 200 Bush St., San Francisco, Calif. 94120.

Midland Bldg., Cleveland, OMo 44115.

85 Pleasant St., Leominster, Mass. 01453.

342 N. Western Ave., Chicago, 111. 60612.

380 Madison Ave., New York, N.Y. 10017. 380 Madison Ave., New York, N.Y. 10017. 380 fedison Ave., New York, N.Y. 10017. 380 Madison Ave., New York, N.Y. 10017. 605 3d Ave., New York, N.Y. 10016. R.R. No. 1, Elwood, 111. 60421. 100 W. Hunter Ave., Maywood, N.J. 07607.

90 Park Ave., New York, N.Y. 10016.

2235 Langdon Farm fid., Cincinnati, Ohio 45237.

Military Rd., Rothschild, Wis. 54474.

120 Lister Ave., Newark, N.J. 07105.

90 Park Ave., New York, N.Y. 10016.

SRR SUG SVC SUM SNW SKG SUN SNO DXS SNT SWT SWR SYR SYC SYP SYN SYV

TCC

CST

TAY

TNC

HN

HNW

HNX

CRY

TOC

TEN

TX

TSA

TUS

TXC

TCI

TXT

TKL

SOR

THC

TMH

TIC

TID

TRC

TNI

TV

TRN

ACT

TGL

TRJ

TRO

TCH

JTC

UHL UNG NCI

UCC UCP UCS UOC UNS URC UNN UNP UNO UNO USB USO

DIRECTORY OF MANUFACTURERS TABLE 22. —Synthetic organic chemicals : Directory of manufacturers , 1964— Continued

225

Name of company

Fred'k A. Stresen-Reuter, Ino

Sucro-Chenloal Div. of Colonial Sugars Co

Sullivan Varnish Co

Summit Chemical Products Corp

Sun Chemical Corp., Warwick Chemical Co. Div-

Surikist Growers, Inc

Sun Oil Co

SunOlin Chemical Co

Sunray DX Oil Co

Suntide Refining Co

Swift & Co

Switzer Bros., Ino

Synco Resins, Inc

Synthetic Chemicals, Inc

Synthetic Products Co

Synthron, Inc

Synvar Corp

Office address

Tanatex Chemical Corp

Charles S. Tanner Co

Taylor Corp

Tennant Development Corp., Chemical Div

Tenneco Chemicals, Inc

Newport Div

Nuodex Div

Tenneco Manufacturing Co., Tenneco Plastics Dlv-

Tenneoo Oil Co

Tennessee Copper Co

Texaco, Inc

Texas Alkyls, Inc

Texas-U.S. Chemical Co

Tex Chem Co

Texlze Chemicals, Inc

Textllana Corp

Thiokol Chemical Corp

Thomason Industries, Inc., Southern Resin Div— -

Thompson Chemical Co

Thompson-Hayward Chemical Co

Ticonderoga Chemical Corp

Tidewater Oil Co

Toms River Chemical Corp

Toni Co

Tousey Varnish Co

Trancoa Chemical Corp

Arthur C. Trask Co

Triangle Chemical Co

Trojan Powder Co

Troy Chemical Co

Trylon Chemical Corp

Joseph Turner & Co

Ine-

Paul Uhllch & Co,

Ungerer & Co

Union Bag- Camp Paper Corp Union Carbide Corp.:

Chemicals Div

Plastics Div

Silicones Div

Union Oil Co. of California

Union Starch & Refining Co., Inc

United Carbon Co

United Chemical Corp. of Norwood

United Chemical Products Corp

United Cork Companies

United Oil Manufacturing Co

U.S. Borax Research Corp

U.S. Oil Co

Nelio Chemical Dlv-

400 W. Roosevelt Ave., Bensenvllle, 111. 60106.

P.O. Drawer G, Gramercy, La. 70052.

"ilO N. Hart St., Chicago, 111. 60622.

11 William St., Belleville, N.J. 07109.

Wood River Junction, R.I. 02894.

707 W. 5th St., Los Angeles, Calif. 90054.

1608 Walnut St., Philadelphia, Pa. 19103.

P.O. Box F, Claymont, Del. 19703.

P.O. Box 2039, Tulsa, Okla. 74102.

P.O. Box 658, Corpus Christ!, Tex. 78403.

115 W. Jackson Blvd., Chicago, 111. 60604.

4732 St. Clair Ave., Cleveland, Ohio 44103.

30 Henry St. , Bethel, Conn. 06801.

335 McLean Blvd., Paterson, N.J. 07504.

1636 Wayside Rd., Cleveland, Ohio 44112.

Ryan Ave., Ashton, R.I. 02805.

726 King St., Wilmington, Del. 19801.

P.O. Box 388, liyndhurst, N.J. 07071.

250 S. Water St. , Providence, R. I. 02901.

Valley Forge, Pa. 19481.

100 Park Ave., New York, N.Y. 10017.

300 E. 42d St., New York, N.Y. 10017.

P.O. Box 911, Pensacola, Fla. 32501.

830 Magnolia Ave., Elizabeth, N.J. 07114.

P.O. Box 38, East Brunswick, N.J. 08816.

P.O. Box 2511, Houston, Tex. 77001.

Copperhlll, Tenn. 37317.

P.O. Box 52332, Houston, Tex. 77052.

P.O. Box 988, Pasadena, Tex. 77501.

P.O. Box 667, Port Neches, Tex. 77651.

20-21 Wagaraw Rd., Fair Lawn, N.J. 07410.

P.O. Box 368, Greenville, S.C. 29602.

12607 Cerise Ave., Hawthorne, Calif. 90250.

P.O. Box 27, Bristol) Pa. 19007.

P.O. Box 352, Fayettevllle, N.C. 28302.

90 Mendor Ave., Pawtuoket, R.I. 02852.

P.O. Box 768, Kansas City, Mo. 64141.

P.O. Box 11, Leominster, Mass. 01453.

Delaware City, Del. 19706.

P.O. Box 71, Toms River, N.J. 08753.

456 Merchandise Mart, Chicago, 111. 60654.

135 W. Lake St., North Lake, 111. 60164.

312 Ash St., Reading, Mass. 01867.

327 S. LaSalle St., Chicago, 111. 60604.

P.O. Box 4528, Macon, Ga. 31208.

17 N. 7th St., Allentown, Pa. 18105.

338 Wilson Ave., Newark, N.J. 07105.

P.O. Box 5101, Station B, Greenville, S.C. 29606.

P.O. Box 88, Rldgefield, N.J. 07451.

90 West St., New York, N.Y. 10006.

161 Avenue of the Americas, New York, N.Y. 10013.

P.O. Box 6170, Jacksonville, Fla. 32205.

270 Park Ave., New York, N.Y. 10017.

270 Park Ave., New York, N.Y. 10017.

270 Park Ave., New York, N.Y. 10017.

461 S. Boylston St., Los Angeles, Calif. 90017.

301 Washington St., Columbus, Ind. 47201.

P.O. Box 149, Baytown, Tex. 77520.

P.O. Box 327, Endlcott St., Norwood, Mass. 02062.

York and Colgate Sts., Jersey City, N.J. 07302.

50 Central Ave., Kearny, N.J. 07032.

2d and Cascade Sts., Erie, Pa. 16512.

3075 Wllshlre Blvd., Los Angeles, Calif. 90005.

P.O. Box 4228, E. Providence, R.I. 02914.

226 SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 22. Synethic organic chemicals.- Directory of manufacturers , i564— Continued

Name of company

U.S. Peroxygen Corp.

United States Pipe & Foundry Co

U.S. Plastic & Chemical Corp

United States Plywood Corp., California Div.,

Shasta Operations.

Universal Chemicals Corp

Universal Detergents, Inc. & Petrochemicals Co- Universal Oil Products Co

Trubek Chemical Co. Div

Upjohn Co

Carwin Co. Div

Polymer Chemicals Div

Utah Resin Co., Inc

Valchem

Valentine Sugars, Inc., Valite Div

Van De Mark Chemical Co

Vanderbilt Chemical Corp

Van Dyk & Co., Inc

Vamey Chemical Co

Velsicol Chemical Corp

Tensyn Div

Vermi lye-Bell

Verona-Pharma Chemical Corp

Vickers Refining Co., Inc

Vineland Chemical Co

Virginia Chemicals, Inc

Vitamins, Inc

Vita-Var Corp., Div. of Textron Industries, Inc- Vulcan Materials Co., Frontier Chemical Co. Div-

Wallaoe & Tieman, Inc. :

Harohem Div

Lucidol Div

Wamer-Jenkinson Manufacturing Co

Warren Paint & Color Co

Washhum-Purei Co '

Washine Chemical Corp

West Coast Adhesives Co

Western Dry Color Co

Westinghouse Electric Corp., Micarta Div

West Virginia Pulp & Paper Co., Polychemicals Div.

Weyerhaeuser Co., Wood Products Div

■White & Bagley Co

White & Hodges, Inc

White Laboratories, Inc

Whitmoyer Laboratories, Inc

Whittemore-Wright Co. Inc

Wica Chemicals, Inc

Wilmot & Cassidy, Inc

Wilson & Co., Inc. :

Wilson Laboratories Div

Wilson-Martin Div

Witco Chemical Co., Inc

Sonnebom Div

W. A. Wood Co

Wood Chemicals, Inc

Wood Ridge Chemical Corp

Woonsocket Color & Chemical Co

Worthington Biochemical Corp

Wyandotte Chemicals Corp

Young Aniline Works, Inc

Office address

850 Morton Ave., Richmond, Calif. 9480^.

3300 1st Ave. N. , Birmingham, Ala. 35202.

122 E. Railroad Ave., W. Haverstraw, N.Y. 10927.

P.O. Box 1688, Redding, Calif. 96002.

1224 ttrndon Rd., P.O. Box 1224, Ashton, R.I. 028£ 1825 E. Spring St., Long Beach, Calif. 90806. 30 Algonquin fid., Des Plaines, 111. 60018. State Highway 17, E. Rutherford, N.J. 07073. 7000 Portage Rd., Kalamazoo, Mich. 49001. Stiles Lane, North Haven, Conn. 06473. Battle Ground Rd., Houston, Tex. 77001. 418 Keams Bldg., Salt Lake City, Utah 84101.

1407 Broadway, New York, N.Y. 10018.

726 Whitney Bldg., New Orleans, La. 70130.

N. Transit Rd., Lockport, N.Y. 14094.

33 Winfield St., E. Norwalk, Conn. 06855.

11 William St., Belleville, N.J. 07109.

2001 Afton Rd., Janesville, Wis, 53545.

330 E. Ohio St., Chicago, 111. 60611.

4902 Central Ave., Chattanooga, Tenn. 37410.

21707 Bothell Way, Bothell, Wash. 98011.

P.O. Box 385, Union, N.J. 07083.

P.O. Box 2240, Wichita, Kans. 67201.

W. Wheat Rd., Vineland, N.J. 08360.

West Norfolk, Va. 23703.

809 W. 58th St., Chicago, 111. 60621.

177 Oakwood Ave., Orange, N.J. 07050.

P.O. Box 545, Wichita, Kans. 67201.

25 Main St., Belleville, N.J. 07109.

1740 Military Rd., Buffalo, N.Y. 14240.

2526 Baldwin St., St. Louis, Mo. 63106.

P.O. Box 1307, Nashville, Tenn. 37202.

2244 Elston Ave., Chicago, 111. 60614.

165 Main St., Lodi, H.J. 07644.

11104 NW. Front Ave., Portland, Oreg. 97231.

600 W. 52d St., Chicago, 111. 60609.

Trafford, Pa. 15085.

P.O. Box 5207, N. Charleston, S.C. 29406.

118 S. Palmetto St., Marshfield, Wis. 54449. P.O. Box 1171, Worcester, Mass. 01601. 576 Lawrence St., Lowell, Mass. 01852. Galloping Hill Rd., Kenilworth, N.J. 07033. 19 N. Railroad St., %erstown. Pa. 17067. 62 Alford St., Boston, Mass. 02129. P.O. Box 506, Charlotte, N.C. 28201. 108 Provost St., Brooklyn, N.Y. 11222.

4221 S. Western Blvd., Chicago, 111. 60609.

Snyder Ave. and Swanson St., Philadelphia, Pa. 19148.

P.O. Box 305, Paramus, N.J. 07652.

277 Park Ave., New York, N.Y. 10017.

108 Spring St., Everett, Mass. 02149.

P.O. Box 3545, Eugene, Oreg. 97401.

Park PI. E., Wood Ridge, N.J. 07075.

176 Sunnyside Ave., Woonsocket, R.I. 02895.

Freehold, N.J. 07728.

1609 Biddle Ave., Vfyandotte, Mich. 48193.

2731 Boston St., Baltimore, m. 21224.

APPENDIXES

A. U. S. Imports of Benzenoid Intermediates and Finished Benzenoid Products

Table 23 summarizes, for 1963 and 1964, U.S. imports of benzenoid chemicals and products entered in 1963 under paragraphs 27 and 28 of the Tariff Act of 1930-'- and entered in 1964 under the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B and C. The data, which were obtained by analyzing invoices covering imports through all U.S. customs districts, are given in detail in 5. separate report of the Tariff Commission. 2

In 1964, general imports of benzenoid intermediates entered under schedule 4, part IB, com- prised 651 items with a total weight of 18. 8 million pounds, and an invoice value of $14. 4 million. In 1963, imports consisted of 778 items with a total weight of 25. 2 million pounds, valued at $12. 6 million. About half of the benzenoid intermediates imported in 1964 were declared to be competitive (duty based on "American selling price"). In terms of quantity, about 40 percent of the total imports of these products in 1964 came from West Germany; imports from that country amounted to 7. 6 million pounds in 1964, compared with 8.3 million pounds in 1963. In 1964, imports from the United Kingdom amounted to 2. 2 million pounds , compared with 2. 5 million

TABLE 23.

. Benzenoid intermediates and finished benzenoid products : U.S. general imports, classified by use, 1963 and 1964

Quantity

Invoice value

Quantity

Invoice value

Intermediates""" '

Finished benzenoid products, total

Dyes, total

Acid

Azoic dyes

Azoic components :

Fast color "bases

Fast color salts

Naphthol AS and its derivatives- Basic

Direct

Disperse

Fiber-reactive

Fluorescent brightening agents

Ingrain

ttordant

Solvent

Sulfur

Vat

All other

Benzenoid pigments (toners and lakes)

Medicinals and pharmaceuticals

Flavor and perfume materials

All other

25,249 20,109

8,917

1,712

13

169

118

1,00A

456

950

454-

395

82

5

232

112

29

3,163

23

363

2,961

1,957

5,911

1,000 dollars 12,617

^ 30,992

1,000 pounds 18,789

23,682

10,096 2,093

14

311 113 901 1,018 1,015 900 416 151

292

128

11

2,713

3 20

684

3,127

1,613

8,162

1,000 dollars

14,410 34,670

16,261

^ Includes small quantities of rubber-processing chemicals.

^ Revised to include azoic dye components, formerly classified as inteimediates. ^ Includes ingrain dyes.

* Revised to include organic pesticides and agricultural chemicals, plasticlzers, surface-active agents, and textile assistants, formerly classified as intennediates .

Source: Compiled from the records of the U.S. Bureau of Customs.

The import statistics for 1963 have been revised to account for the transfer of such commodities as fast color bases, fast color salts, n^hthol AS and derivatives, pesticides, and textile assistants to schedule 4,pt. IC, TSUS.

^Imports of Benzenoid Chemicals and Products, 1964, TC Publication 159, 1965 [processed].

227

228 SYNTHETIC ORGANIC CHEMICALS, 1964

pounds in 1963. Imports from Japan amounted to 2.2 million pounds, compared with 2. 1 million pounds in 1963. Imports from Canada totaled 2.0 million pounds in 1964, compared with 7.3 mil- lion pounds in 1963; and imports from Italy amounted to 1 . 6 million pounds in 1964, compared with 2.4 million pounds in 1963. In 1964, sizable quantities of intermediates also were imported from France (1,049,000 pounds), Switzerland (1,043,000 pounds), Sweden (629,000 pounds), and the Netherlands (254,000 pounds). Smaller quantities came from Belgium (120,000 pounds), and Czechoslovakia (55,000 pounds).

The most important intermediates imported in 1964 were adipic acid; refined anthracene; p-nitrotoluene; 1 , 6-hexanediamine; polyalkylbenzene; cyclohexane sulfamic acid, calcium salt; acetoacetanilide; 3-hydroxy-2-naphthoic acid (B.O. N. ); and p-toluenesulfonamide. In 1964, imports of adipic acid, which amounted to 1 . 9 million pounds, were principally from Canada; imports of refined anthracene, which totaled 900, 000 pounds, all came from West Germany; imports of p-nitrotoluene, which came from Sweden and West Germany, totaled 748, 000 pounds; imports of

1, 6-hexanediamine, which came from France, Italy, and West Germany, amounted to 741, 000 pounds; imports of polyalkylbenzene (725, 000 pounds) all came from Italy; imports of cyclohexane- sulfamic acid, calcium salt (714,000 pounds), all came from Japan; and imports of acetoacet- anilide, which came from the United Kingdom, Switzerland, West Germany, and Japan, amounted to 599,000 pounds. Among the other important individual chemicals imported, imports of 3- hydroxy-2-naphthoic acid (B.O.N.) came from Italy, Japan, and West Germany; p-toluene- sulfonamide came principally from Japan.

Imports in 1964 of all finished benzenoid products that are dutiable under part IC comprised

2, 292 listed items, with a total weight of 23. 7 million pounds and an invoice value of $34. 7 mil- lion. In 1963, imports consisted of 2, 005 items, with a total weight of 20. 1 million pounds and an invoice value of $31. 0 million. Imports of dyes in 1964 amounted to $16. 3 million (invoice value), or 46. 9 percent of the value of all imports under part IC. In 1963, imports of dyes amounted to $12. 6 million (invoice value), or 40. 5 percent of the value of all imports under part IC.

Imports of medicinals and pharmaceuticals, the next most important group of products entered under part IC in 1964, were about 4 percent less in that year than in 1963 and 1962. In 1964, imports of medicinals and pharmaceuticals were valued at $9. 8 million (invoice value), or 28. 2 percent of the total value of imports under part IC. In 1963, imports of medicinals and pharmaceuticals were valued at $10. 2 million, or 38 percent of the total value of imports under part IC. In 1964, imports of benzenoid pigments (toners and lakes) were valued at $1, 128, 000, compared with $616, 000 in 1963. Imports of benzenoid flavor and perfume materials in 1964 ($2. 3 million) were 19 percent less than in 1963 ($2. 9 million). In 1964, imports of other benze- noid products entered under part IC (chiefly synthetic resins and pesticides) were valued at $5. 2 million, compared with $4.8 million (revised) in 1963.

APPENDIX B

229

List of Colour Index and Common Names for Synthetic Organic Pigments (Toners and Lakes)

In the Commission's reports for 1957 and earlier years, individual toners and lakes were identified by the names by which they were most commonly known in the literature and in the trade. In the reports for 1958 and the years since, they have been identified by the names used in the second edition of the Colour Index.

The following list of all Colour Index names which appear in tables 1 lA and 12 of this report is appended for quick reference. The list gives the common names (and coupling components, in the case of azo pigments) for each Colour Index pigment listed.

Synthetic organic pigments: List of Colour Index and common names

Colour Index name

Common name

Pigment

Yellow 1

Hansa Yellow G (2-nitro-p-toluidine and aoetoaoetanilide) .

Pigment

Yellow 3

Hansa Yellow lOG (<i-chloro-2-nitroaniline and o-ohloroacetoaoetanilide).

Pigment

Yellow 12—

Benzidine Yellow (3,3 '-dlohlorobenzidine and aoetoacetanilide) .

Pigment

Yellow 13

Benzidine Yellow (3,3 '-dlchlorobenzidine and 2,4-acetoacetoxylidide) .

Pigment

Yellow U-

Benzidine Yellow (3,3 '-dichlorobenzldine and o-aoetoacetotoluidide).

Pigment

Yellow 17

Benzidine Yellow (3,3 '-dichlorobenzidine and o-aoetoacetanisidide) .

Pigment Orange 5

Dinltroaniline Orange (2,4.-dinitroaniline and 2-naphthol) .

Pigment Orange 13

Benzidine Orange (3,3 '-dlohlorobenzidine and 3-methyl-l-phenyl-2-pyrazolin-5-one).

Pigment Orange 16

Dianlsidine Orange (o-dianisidine and acetoaoetanilide) .

Pigment

Red 1

Para Red (p-nitroaniline and 2-naphthol) .

Pigment

Red 2

Naphthol Red (2,5-dichloroaniline and Naphthol AS).

Pigment

Red 3

Toluidine Red (2-nitro-p-toluidine and 2-naphthol),

Pigment Pigment

Chlorinated Para Red (2-chloro-4-nitroaniline and 2-naphthol). Naphthol Red (N^,N^-diethyl-4-methoxymetanilamide and Naphthol AS-ITR).

Red 5

Pigment

Red 13 -

Naphthol Red (2-nitro-p-toluidine and Naphthol AS-D) .

Pigment

Red 17

Naphthol Red (5-nitro-o- toluidine and Naphthol AS-D).

Pigment

Red 18

Toluidine Maroon (2-nitro-p-toluidine and Naphthol AS-BS).

Pigment

Red 22

Naphthol Red (5-nitro-o- toluidine and Naphthol AS).

Pigment

Red 23

Naphthol Red (5-nitro-o-anisidine and Naphthol AS-BS).

Pigment

Red 38

Pyrazolone Red (3,3 '-dlohlorobenzidine and 5-oxo-l-phenyl-2-pyrazoline-3-oarboxylio acid, ethyl ester) .

Pigment

Permanent Red 2B (6-amino-4-chloro-m-toluenesulfonio acid and 3-hydroxy-2-naphthoio

acid) . Lithol Red R (2-amino-l-naphthalenesulfonic acid and 2-naphthol).

Pigment

Pigment

Red 52

Lithol Red 2G''- (2-amino-5-chloro-p-toluenesulfonic acid and 3-hydroxy-2-naphthoic

acid) . Red Lake C (2-amino-5-chloro-p-toluenesulfonio acid and 2-naphthol).

Pigment

Red 53-

Pigment

Red 54

Helio Bordeaux BL ( 1-naphthylamine and l-naphthol-5-sulfonio acid).

Pigment

Red 57

Lithol Rubine B (6-amino-m-toluenesulfonic acid and 3-hydroxy-2-naphthoic acid).

Pigment

Red 60

Pigment Scarlet 3B (anthranilic acid and 2-naphthol-3,6-disulfonlc acid).

Pigment

Red 63

BON Maroon (2-amino-l-naphthalenesulfonlc acid and 3-hydroxy-2-naphthoio acid).

Pigment

Red 81

Rhodamine 6G.

Pigment

Red 83

Alizarin Red B.

Pigment

Red 90

Bromo Acid; Eosin.

(Acid Red 26)

Scarlet 2R (2,4-xylidine and 2-naphthol-3,6-disulfonic acid).

Pigment

Violet 1

Rhodamine E.

Pigment

Violet 3

Methyl Violet B.

Pigment Pigment

Helio Fast Rubine 431. Victoria Pure Blue BO.

Blue 1

Pigment

Blue 2

Victoria Blue B.

Pigment

Blue 9

Setoglauoine .

Pigment

Blue lA

Ethyl Violet.

Pigment

Blue 15

Phthalocyanine Blue.

Pigment

Blue 19

Aliali Blue.

Pigment

Blue 24

Peacock Blue Late.

Pigment

Blue 25—

Dianlsidine Blue (o-dianisidine and Naphthol AS).

Pigment

Green 1

Brilliant Green.

Pigment

Green 2

Brilliant Green and Thioflavine.

Pigment Pigment

Malachite Green. Phthalocyanine Green.

Pigment Green B.

Bismarck Brown R (toluene-2,4-diamine). Logwood Black.

^ Lithol Red 2G has become generally accepted as the name for Pigment Red 52, although the 2d edition of the Colo Index lists this name for Pigment Red 69.

Note. When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the pigment can be made and that no name for the pigment itself is given in the Colour Index.

230 SYNTHETIC ORGANIC CHEMICALS, 1964

C. Employment in the Synthetic Organic Chemicals Industry, 1964 (Original Manufacturers Only)

At the request of the Special Representative for Trade Negotiations, the Tariff Commission conducted a one-time survey of original manufacturers in the synthetic organic chemicals industry to obtain employment data by product groups, by plants, for 1964. The survey also included pro- ducers of crude products from coal tar, petroleum, and natural gas. Figures in table 24 show employment as of December 31, 1964, or the pay period nearest the end of 1964.

There were 275,299 persons employed in the production and sales of synthetic organic chem- icals, including crudes, in December 1964; 262,261 were employed in the synthetic organic chemicals industry and 13, 038 in the tar crudes and petroleum crudes industries. Employment data were submitted by 696 companies, operating 1, 156 plants, out of a total of 803 companies that reported production and sales datatothe Commission for 1964. The companies which reported employment accounted for 92.4 percent of the 1964 production of synthetic organic chemicals, for 99. 1 percent of production of tar crudes, and for 96i 6 percent of the production of crude products from petroleum and natural gas. For the most part, ^the chemical companies which did not report employment are relatively small in size; a few large, integrated companies also did not report. Production by these large companies, however, amounted to only a small part of total U.S. production of synthetic organic chemicals.

No attempt was made to collect separate data on production workers. Supervisory employees and research or sales personnel located at the plants are included in the figures on plant employ- ment. Therefore, the figures on employment at plants shown in table 24 cannot be used to deter- mine the number of production workers in the industry.

Coverage of the industry, by product groups, is also given in table 24. The percent of the industry covered is based on the production accounted for by those companies reporting employ- ment in each respective product group. The reporting companies accounted for more than 85 per- cent of production in 1964 in 13 of the 15 product groups. Companies reporting employment in two product groups--elastomer s and miscellaneous cyclic chemicals --accounted for less than 71 percent of production in each group in 1964. (See table 24. )

Employment in December 1964 in the synthetic organic chemicals industry, by States having three or more plants, is given in table 25. Similar data on employment in the tar crudes and petroleum crudes industries cannot be published without disclosing the operations of individual companies .

Total employment of 1, 087 in the tar crudes industry was reported by plants in the following States: Alabama, California, Illinois, Maryland, Massachusetts, Michigan, New Jersey, New York, Ohio, Pennsylvania, Texas, and Wyoming.

Employment in the petroleum crudes industry, Twhich amounted to 11, 951 in December 1964, was reported by plants located in California, Connecticut, Delaware, Illinois, Indiana, Kansas, Kentucky, Louisiana, Massachusetts, Michigan, Mississippi, New Jersey, New York, Ohio, Oklahoma, Pennsylvania, South Carolina, Texas, and West Virginia.

APPENDIX C

231

TABLE 2A. Synthetic organic chemicals industry, including crudes : Employment as of Dec. 31, 1964, or pay period nearest end of 1964

Product group

Grand total

Tar and tar crudes

Crude products from petroleum^ total

A. Aromatios and naphthenes

B. Aliphatic hydrocarbons

Synthetic organic chemicals, total

Benzenoid, jnodified benzenoid, and benzenoid raw

materials

Other

Cyclic intermediates, total

A. Benzenoid

B. Other

Dyes

Synthetic organic pigments

Medicinal chemicals, total

A. Benzenoid

B. Other

Flavor and perfume materials, iiotal-

A. Benzenoid and modified benzenoid

B. Other

Plastics and resin materials, total

A. Benzenoid

B. Other

Rubber-processing chemicals, total

A. Benzenoid

B. Other

Elastomers, total

A. Benzenoid

B. Other

Plastioizers, total

A. Benzenoid

B. Other

Surf ace -active agents, total

A. Benzenoid

B. Other

Pesticides, total

A. Benzenoid

B. Other

Miscellaneous cyclic chemicals, total

A. Benzenoid

B. Other

Miscellaneous aoyclio chemicals, total

A. From benzenoid raw materials

B. Other

Other synthetic organic chemicals, total**

A. Benzenoid

Total employment-'-

275,299

2,920 9,031

262,261

115,611 146,650

21,625

20,294-

1,331

9,347

3,873

30,842

14,989

15,853

2,533

1,223

1,310

68,648

29,708

38,940

3,618

2,199

1,419

14,306

4,097

10,209

3,811

1,928

1,883

13,932

6,796

7,136

7,459

2,874

4,585

7,334

3,751

3,583

68,035

13,217

54,818

6,898

1,315

5,583

Percent of industry

99.1 96.6

99.8 99.0 92.5

65.8 93.6 93.8

Distribution of employment

At plants

214,777

2,211 7,997

203,609

89, 937 113,672

16,843

15,815

1,028

7,064

3,308

19,497

9,365

10,132

2,220

1,055

1,165

54,735

23,995

30,740

2,784

1,590

1,194

12,283

3,448

8,835

3,001

1,572

1,429

11,870

5,651

6,219

5,192

2,018

3,174

6,060

3,209

2,851

53,324

10,771

42,553

5,428

1,076

4,352

At other locations'

Bnployment at those locations -where the same persons handle more than a single product group was allocated be- tween the applicable products by the reporting congsany.

^ Coverage shown is based on the production accounted for by those companies reporting eraplo3nnent in each respec- tive product group.

^ Includes employees engaged in sales, research, administration, etc.

Production and sales of chemicals reported in this group were transferred to the appropriate product groups shown above. Bnployment figures, however, were not allocated. ' Not available.

232

SYNTHETIC ORGANIC CHEMICALS, 1964

TABLE 25. Synthetic organic chemicals industry: Employment by States, as of Dec. 31, 1964, or pay period nearest end of 1964

Number

employed

Number eii5)loyed

New Jersey

Texas

New York

West Virginia Pennsylvania

Michigan

Ohio

Tennessee

Illinois

California

Louisiana

Kentucky

Massachusetts

Virginia

Connecticut

South Carolina- Missouri

North Carolina-

29,675

26,236

18,376

13,330

13,111

12,915

9,571

8,510

8,333

6,738

5,877

5,589

5,243

5,000

4,031

3,819

3,545

3,077

Alabama

Indiana

Delaware

Rhode Island

Wisconsin

Kansas

Georgia

Maryland

Colorado

Mississippi

Washington

Iowa

All other States^

Total employment at plants - finployment at other than plant

locations -

Grand total-

2,592

2,521

1,947

945

917

839

812

743

567

539

522

337

7.352

203,609 58,652

262,261

■'■ All States listed have 3 or more producing plants. Qnployment is distributed among the plants in such a manner as not to disclose individual company operations.

^ Includes Arkansas, Florida, Maine, Minnesota, Montana, Nebraska, Nevada, New Hampshire, New Mexico, Oklahoma, Oregon, and Utah.

»U. S. GOVERNMENT PRINTING OFFICE: 1965 O - 796-332

REPORTS OF THE UNITED STATES TARIFF COMMISSION ON THE OPERATION OF THE

TRADE AGREEMENTS PROGRAM

♦Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949) : Part I. Summary

Part II. History of the Trade Agreements Program Part III. Trade-Agreement Concessions Granted by the United States Part IV. Trade-Agreement Concessions Obtained by the United States Part V. Effects of the Trade Agreements Program on United States Trade ♦Operation of the Trade Agreements Program: Second Report, April 1948-March 1949 (Rept. No.

163, 2d ser., 1950) ♦Operation of the Trade Agreements Program: Third Report, April 1949-June 1950 (Rept. No. 172,

2d ser., 1951) ♦Operation of the Trade Agreements Program: Fourth Report, Jidy 1950-June 1951 (Rept. No. 174,

2d ser., 1952) ♦Operation of the Trade Agreements Program: Fifth Report, July 1951- June 1952 (Rept. No. 191,

2d ser., 1954) ♦Operation of the Trade Agreements Program: Sixth Report, July 1952- June 1953 (Rept. No. 193,

2d ser., 1954) ♦Operation of the Trade Agreements Program: Seventh Report, July 1953- June 1954 (Rept. No.

195, 2d ser., 1955) ♦Operation of the Trade Agreements Program: Eighth Report, July 1954r-June 1955 (Rept. No.

197, 2d ser., 1956) ♦Operation of the Trade Agreements Program: Ninth Report, July 1955-June 1956 (Rept. No. 199,

2d ser., 1957) ♦Operation of the Trade Agreements Program: 10th Report, July 1956- June 1957 (Rept. No. 202,

2d ser., 1959) ♦Operation of the Trade Agreements Program: 11th Report, July 1957- June 1958 (Rept. No. 204, 2d

ser., 1959) ♦Operation of the Trade Agreements Program : 12th Report, July 1958- June 1959 (TC Publication

9, 1961) ♦Operation of the Trade Agreements Program : 13th Report, July 1959-June 1960 (TC Publication

51, 1962) Operation of the Trade Agreements Program : 14th Report, July 1960-June 1962 (TC Publication

120, 1964), B5i Operation of the Trade Agreements Program : 15th Report, July 1962- June 1963 (TC Publication 147, 1965), 35^

NOTE. The reports preceded by an asterisk (*) are out of print. Those followed by a price may be purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C., 20402. See inside front cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in the official depository libraries throughout the United States.

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