Given By

p. rspct/ct memoirs

M3 ^

UNITED STATES TARIFF COMMISSION

SYNTHETIC ORGANIC CHEMICALS

United States Production and Sales, 1965

TC Publication 206

on Public Lib

tntcndent of Documents

JUL 2 11967

>S!TORY

RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION ON SYNTHETIC

ORGANIC CHEMICALS

*Synthetic Organic Chemicals, United States Production and Sales, 1960 (TC Publication 34, 1961) Synthetic Organic Chemicals, United States Production and Sales, 1961 (TC Publication 72, 1962),

$1.25 Synthetic Organic Chemicals, United States Production and Sales, 1962 (TC Publication 114,

1963), $1.50 Synthetic Organic Chemicals, United States Production and Sales, 1963 (TC Publication 143,

1964), $1.50 Synthetic Organic Chemicals, United States Production and Sales, 1964 (TC Publication 167,

1965), $1.25

NOTE. — The report preceded by an asterisk!*) is out of print. The other reports listed may be purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. See inside back cover for additional reports. AH U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in the official depository libraries throughout the United Stales.

UNITED STATES TARIFF COMMISSION

SYNTHETIC ORGANIC CHEMICALS

United States Production and Sales, 1965

UNDER THE PROVISIONS OF SECTION 332 OF THE TARIFF ACT OF 1930, AS AMENDED

U.S. GOVERNMENT PRINTING OFFICE WASHINGTON : 1967

TC Publication 206

UNITED STATES TARIFF COMMISSION

Paul Kaplowitz, Chairman Glenn W. Sutton, Vice Chairman James W. Culliton Dan H. Fenn, Jr. Penelope H. Thunberg

Donn N. Bent, Secretary

Address all communications

UNITED STATES TARIFF COMMISSION

Washington, D.C. 20436

For sale by the Superintendent of Documents, U.S. Government Printing Office Washington, D.C. 20402 - Price $1.00

CONTENTS

Page

Introduction- Summary

Vll

PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS

Tars

Tar crudes '■

Crude products from petroleum and natural gas for chemical conversion \

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS

General

Cyclic intermediates _

Dyes """~-'.~."l"l""l"" 10

Pigments ^

Medicinal chemicals , ,

Flavor and perfume materials ,,

Plastics and resin materials ,□

Rubber -processing chemicals .-,

Elastomers (synthetic rubbers) .,

P lasticize r s *j?

Surface -active agents *i?

Pesticides and other organic agricultural chemicals 52

Miscellaneous chemicals ?f

PART III. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF MANUFACTURERS

Tar crudes , ,

Crude products from petroleum and natural gas for chemical conversion 62

Cyclic intermediates /.

Dyes :::::::::::::::::::::::: %

Pigments -- -- 7

Medicinal chemicals , ,f

Flavor and perfume materials 12q

Plastics and resin materials ,-/.

Rubber -proce s sing chemicals 13R

Elastomers (synthetic rubbers) _ , .-,

Plasticizers ""1 !?,

Surface -active age nts r*f

Pesticides and other organic agricultural chemicals w ,

Miscellaneous chemicals ?f

Directory of manufacturers Jjj^

APPENDIX

U.S. imports of benzenoid intermediates and finished benzenoid products 211

Introduction

This is the forty-ninth annual report of the U.S. Tariff Commission on domestic production and sales of synthetic organic chemicals and the raw materials from which they are made. The report presents statistics for 1965 on production and sales of crude organic chemicals derived from coal, natural gas, and petroleum; of intermediates; and of finished synthetic organic chem- ical products. The finished products are grouped according to their principal use--dyes, syn- thetic organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-processing chemicals, elastomers, plasticizers, surface- active agents, pesti- cides and other organic agricultural chemicals, and miscellaneous chemicals. The use classifi- cations of finished synthetic organic chemicals are based principally on the manufacturers' annual reports to the Tariff Commission; other sources include trade associations, the chemical literature, chemical dictionaries, encyclopedias, and consultants in the chemical industry. With a few exceptions, the report does not cover organic chemicals (such as wood- distillation products essential oils, and naval stores) that are derived from natural (vegetable) sources by simple ex- traction or distillation. The Commission has compiled the statistics given in this report from information supplied by approximately 800 primary manufacturers, listed in part III,

The first section of the report includes the statistics on all products and groups of products for which such information can be published. The second section lists all the chemicals and chemical products on which data are reported and identifies the manufacturers of each. Each reporting company has been assigned an identification symbol consisting of a combination of not more than three capital letters, selected in most instances with the approval of the manu- facturer, and usually bearing some relationship to the company name. The identification symbols are permanent and, except for such changes as may be necessary, will be used in all future re- ports in this series. Like the seven immediately preceding reports, this report includes data on only those individual chemicals for which the volume of production or sales in the year covered exceeded 1,000 pounds or for which the value of sales exceeded $1,000.

The raw materials referred to in this report are obtained from coal, crude petroleum, nat- ural gas, and certain other natural materials, such as vegetable oils, fats, rosin, and grains. Crude organic chemicals are derived from coal by thermal decomposition, from petroleum and natural gas by catalytic cracking and by distillation or absorption, and from other natural sources by fermentation. Production of these crude organic chemicals is the first step in the manufacture of synthetic organic chemicals. From these crudes, intermediates are obtained by synthesis or refining; most of the intermediates are then converted into finished chemical prod- ucts, such as medicinal chemicals, plastics and resin materials, and dyes. More than half of the total production of intermediates is not sold directly to the ultimate consumer, but is used by the producing companies themselves in their manufacturing processes. The statistics given in this report include data for all known domestic producers of the items covered.

In this report the statistics on production of the individual chemicals reported by manufac- turers include the total output of the companies' plants, i.e., the quantities produced for con- sumption within the producing plants, as well as the quantities produced for domestic and foreign sale. The quantities reported as produced, therefore, generally exceed the quantities reported as sold. Some of these differences, however, are attributable to changes in inventories. As speci- fied in the reporting instructions that the Commission sends to manufacturers, and as used in this report, production and sales (unless otherwise specifically indicated) are defined as follows:

Production is the total quantity of a commodity made available by original manufacture only. It is the sum (expressed in terms of 100-percent active ingredient unless otherwise specified) of the quantities of a commodity- -

(1) Produced, separated, and consumed in the same plant or establishment (a commodity

is considered to be separated when it is isolated from the reaction system and/or when it is weighed, analyzed, or otherwise measured). Byproducts and coproducts not classified as waste materials are also included;

(2) Produced and transferred to other plants or establishments of the same firm;

(3) Produced and sold to other firms (including production for others under toll agree-

ments1); and

(4) Produced and held in stock.

A toll agreement is an agreement between two firms, under which one firm furnishes the raw materials and pays the processing costs and the other firm prepares the finished product and returns it to the first firm.

vi INTRODUCTION

Production excludes- -

(1) Purification of a commodity unless specifically requested in the reporting instructions; 2) Intermediate products that are formed in the manufacturing process but are not iso- lated from the reaction system- -that is, not weighed, analyzed, or otherwised meas- ured; and , .

(3) Materials that are used in the process but are recovered for reuse or sale; and waste products that have no economic significance.

Sales are defined as actual sales of commodities by original manufacturers only. Sales include--

(1) Shipments of commodities for domestic use and for export, or segregation in a ware-

house when title has passed to the purchaser in a bonafide sale;

(2) Shipments of a commodity produced by others under toll agreements; and

(3) Shipments to subsidiary or affiliated companies.

Sales exclude- -

(1) All intracompany transfers within a corporate entity;

(2) All sales of purchased commodities; and

(3) All shipments of a commodity produced for others under toll agreements.

The value of a sale is the net selling price, f.o.b. plant or warehouse, or delivered value, whichever represents the normal industry practice.

Data on the chemicals covered in this report are usually given in terms of undiluted mate- rials. Products of 95 percent or more purity are considered to be 100 percent pure. The prin- cipal exceptions are the statistics on dyes and a few solvents, which are reported in terms of commercial concentrations, and the statistics on certain plastics and resins, which are reported on a dry basis. The report specifically notes those products for which the statistics are reported in terms of commercial concentrations. .*.,.., ■ „

The average unit values of sales for groups of products shown in the tables accompanying this report are weighted averages for products which vary widely in unit values and in the quan-

tltieinthiS report, statistics are presented in as great detail as is possible without revealing the operations of individual producers. Statistics for an individual chemical or group of chemicals are not given unless there are three or more producers no one or two of which may be predomi- nant. Moreover, even when there are three or more producers, statistics are not given if there is any possibility that their publication would violate the statutory provisions relating to unlaw- ful disclosure of information accepted in confidence by the Commission.

Statistics on tars and tar crudes include data furnished directly to the Tariff Commission by distillers of coal tar, water-gas tar, and oil-gas tar, and data furnished to the Division of Bitu- minous Coal, U.S. Bureau of Mines, by coke-oven operators. ,,..',-„ j

Statistics on U.S. general imports in 1965 of benzenoid intermediates and finished benzenoid products that entered under schedule 4, parts IB and 1C, of the Tariff Schedules of the United States are given in the appendix. ,

Information on synonymous names of organic chemicals included in this report may be found in the SOCMA Handbook: Commercial Organic Chemical Names, recently published by the Chemical AD- stracts Service of the American Chemical Society, or in the Colour Index (2d edition), published in 1956 by the Society of Dyers and Colourists.

2 Sec. 5, U.S.C. 139b and sec. 18. U.S.C. 1905.

Summary

Combined production of all synthetic organic chemicals, tars, tar crudes, and crude prod- ucts from petroleum and natural gas in 1965 was 151,606 million pounds--an increase of 11.7 percent over the output in 1964 (see table 1). Sales of these materials in 1965, which totaled 80,204 million pounds, valued at $9,898 million, were 10.4 percent larger than in 1964 in terms of quantity and 7.1 percent larger in terms of value. These figures include data on production and sales of chemicals measured at several successive steps in the manufacturing process, and therefore they necessarily contain some duplication.

In 1965, production of all synthetic organic chemicals, including cyclic intermediates and finished chemical products, totaled 88,864 million pounds, or 12.9 percent more than the output in 1964 (see table 1). Production of plastics and resin materials (11,685 million pounds) was 15.7 percent larger in 1965 than in 1964; that of cyclic intermediates (16,865 million pounds) was 13.2 percent larger; that of plasticizers (1,073 million pounds) was 12.8 percent larger; that of dyes (207 million pounds) was 12.4 percent larger; and that of pesticides and other organic agricul- tural chemicals (877 million pounds) was 12.1 percent larger.

The output of most other groups of synthetic organic chemicals also increased in 1965 com- pared with 1964, with miscellaneous chemicals and medicinal chemicals showing increases of more than 10 percent. Production of rubber-processing chemicals (252 million pounds) was 3.3 percent less in 1965 than in 1964. Production and sales statistics for surface-active agents for 1965 are not comparable with those for previous years.

TABLE 1. -- Synthetic organic chemicals and their raw materials: U.S. production and sales, 1964 and 1965

Increase

or decrease (-), 1965

over 19641

Increase, 1965 over 19641

Increase, 1965 over 19641

Grand total2

Tar

Tar crudes

Crude products from petroleum and natural gas

Synthetic organic chemicals, total2

Intermediates

Eyes

Synthetic organic pigments

Medicinal chemicals

Flavor and perfume materials

Plastics and resin materials

Rubber-processing chemicals

ELastomers (synthetic rubbers)

Plasticizers

Surface-active agents

Pesticides and other organic

agricultural chemicals

Miscellaneous chemicals

Million pounds 135,716

Million dollars 9,898

7,629 9,547

78, 678

8,027 10,205

88,864

5.2 6.9

12.9

3,361 6,076

20,465 42,766

3,662 6,332

23,402 46, 807

9.0 4.2

34

131

9,021

14, 896

184

44

144

91

10, 103

261

3,421

951

2,119

783 45,681

16,865

207

48

160

99

11,685

252

3,592

1,073

3,170

877 50,836

(3)

13.2 12.4

9.1 10.7

9.6 15.7 -3.3

5.0 12.8

12.1 11.3

6,470

178 35

119

80

8,727

184 2,958

905 1,900

692 20, 518

7,551

190

38

129

88

10,053

194

3,041

1,022

1,698

764 22,040

(3)

(3)

10.3 7.4

711 264

84 646

84 2,120 123 810 188 350

427 2,651

814

292

94

362

85

2,504

123

843

214

300

497 2,890

6.3 4.1

(3)

(3)

14.5

10.7 11.3

1.5

18.1

.3

4.1 14.4

16.4 9.0

Percentages calculated from figures rounded to thousands.

Because of rounding, figures may not add to the totals shown.

Data for 1965 are not comparable with those for 1964; for details see the appropriate tables.

PART I. PRODUCTION AND SALES OF TARS, TAR CRUDES, AND CRUDES DERIVED FROM PETROLEUM AND NATURAL GAS

Tars

Coal tar is produced chiefly by the steel industry as a byproduct of the manufacture of coke; water-gas tar and oil-gas tar are produced by the fuel-gas industry. Production of coal tar, therefore, depends on the demand for steel; production of water-gas tar and oil-gas tar reflects the consumption of manufactured gas for industrial and household use. Water-gas and oil-gas tars have properties intermediate between those of petroleum asphalts and coal tars. Petroleum asphalts are not usually considered to be raw materials for chemicals.

The quantity of tar produced from coal in the United States in 1 965 was 803 million gallons, or 5.2 percent more than the 763 million gallons produced in 1964. U.S. production of water-gas tar and oil-gas tar was not reported to the Commission for 1964 or 1965; production of these tars amounted to 19 million gallons in 1962, the last year for which production was reported to the Tariff Commission.

Total consumption of tar in 1965 amounted to 766 million gallons, of which 616 million gal- lons was consumed by distillation, 123 million gallons as fuel, and 27 million gallons in mis- cellaneous uses.

TABLE 2. — Tar; U.S. production and consumption, 1964 and 1965

[in thousands of gallons]

PRODUCTION

Coal tar from coke-oven byproduct plants, total1

CONSUMPTION

Total

Tar consumed by distillation, total

Coal tar distilled or topped by coke-oven operators1

Coal tar, water-gas tar, and oil-gas tar distilled by producers and tar

distillers2

Tar consumed chiefly as fuel1

Tar consumed otherwise than by distillation or as fuel, total

Coal tar consumed at coke-oven plants for roads and upkeep1

Coal tar, water-gas tar, and oil-gas tar processed at tar refineries, crude tar consumed for upkeep at such refineries, and tar consumed in making gas and in special- purpose tar blends

762,918

746, 900

765,946

601,753

615,816

293,957

307, 796

127,872

17,275

T7T

16,904

312,079 303,737 122,961 27,169

"371

26,298

1 Reported to the U.S. Bureau of Vines.

2 Reported to U.S. Tariff Commission. Represents tar purchased from companies operating coke ovens and gas-retort plants and distilled by companies operating tar-distillation plants.

Tar Crudes

Tar crudes are obtained from coke-oven gas and by distilling coal tar, water-gas tar, and oil- gas tar. The most important tar crudes are benzene, toluene, xylene, naphthalene, and creosote oil. Some of the products produced from coal tar are identical with those produced from petroleum and natural gas. Data for materials derived from these latter sources are included, for the most part, in or with the statistics for materials derived from coal tar, which are shown in tables 3 and 4A.1

See also table 4B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

2 SYNTHETIC ORGANIC CHEMICALS, 1965

Domestic production of industrial and specification grades of benzene reported by coke-oven operators and petroleum operators2 in 1965 amounted to 827 million gallons-- 13.2 percent more than the 730 million gallons reported for 1964. These statistics include data for benzene pro- duced from light oil and petroleum. Sales of benzene by coke-oven operators and petroleum op- erators in 1965 amounted to 511 million gallons, valued at $123 million, compared with 464 mil- lion gallons, valued at $104 million, in 1964. In 1965 the output of toluene2 (including material produced for use in blending in aviation fuel) amounted to 549 million gallons-- 10.9 percent more than the 495 million gallons reported for 1964. Sales of toluene in 1965 were 325 million gallons, valued at $54 million, compared with 261 million gallons, valued at $44 million, in 1964. The output of xylene2 in 1965 (including that produced for blending in motor fuels) was 340 million gallons, compared with 343 million gallons in 1964. About 98 percent of the 340 million gallons of xylene produced in 1965 was obtained from petroleum sources.

Production of crude naphthalene in 1965 (including 347 million pounds of petroleum-derived naphthalene) amounted to 811 million pounds, compared with 740 million pounds in 1964. In 1965 the output of creosote oil for wood preservation was 124 million gallons (100-percent creosote basis), compared with 113 million gallons in 1964. Production of road tar and tar (crude and re- fined) for other uses in 1965 was 85 million gallons, compared with 76 million gallons in 1964.

TABLE 3. --Tar and tar crudes .■ Summary of U.S. production of specified products, average 1950-54,

annual 1964 and 1965

[Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported]

quantity

Average 1950-54

Increase, or decrease (-)

1965 over 1950-54

1965 over 1964

Tar1

Benzene : 2

Tar distillers3

Coke-oven operators

Petroleum operators

Total -

Toluene:

Tar distillers

Coke-oven operators

Petroleum operators

Total

Xylene:

Tar distillers

Coke-oven operators

Petroleum operators

Total —

Naphthalene, crude:

Solidifying at less than 79° C.5 — Petroleum naphthalene, all grades- Total

,000 gal- ,000 gal- ,000 gal- ,000 gal-

,000 gal- ,000 gal- ,000 gal- ,000 gal-

,000 gal- ,000 gal- ,000 gal- ,000 gal-

,000 lb— ,000 lb— ,000 lb-

Creosote oil (Dead oil)6 1,000

876,070

41,389 163,356 46,635

7,497 32,981 80,725

1,373

9,028

78, 188

8,589 307,537

307,537 109, 946

118, 944 611, 294

802,738

121,917 704, 993

730,238

25,521 469,519

826,910

24,816 524,013

7,119

'336,079

343,198

425,690 314,664

548, 829

6,741 1 333,063

463,980 346, 620

810, 600

-25.4 1,411.7

-24.8 549.1

-25.3 326.0

283.6

163.6 1.0

2.5 15.3 13.2

-.9 -1.0

9.0 10.2 9.5

Includes data for oil-gas, water-gas, and gas-retort tar reported to the American Gas Association for 1950-54 only, and for coal tar reported to the Division of Bituminous Coal, U.S. Bureau of Mines.

2 Includes data for motor-grade benzene in 1950-54. Production in recent years has been negligible.

3 Includes data for benzene produced from imported crude light oil.

* Includes data for material produced for use in blending motor fuels. Statistics are not comparable with monthly figures, which included some o-xylene now shown on table 7A.

5 Figures include production by tar distillers and coke-oven operators and represent combined data for the com- mercial grades of naphthalene to avoid disclosure of the operations of individual companies. Because of conversion between grades, the figures may include some duplication.

6 Includes data for creosote oil produced by tar distillers and coke-oven operators and used only in wood preserv- ing. Data for production of creosote oil in coal-tar solution have been excluded because the figures for 1950-54 are not comparable with the figures for 1964 and 1965. Production figures for 1950-54 are for the distillate sold or consumed as such, and for 1964 and 1965 the production of the distillate is on a 100-percent-creosote basis.

Statistics on production and sales of benzene, toluene, and xylene by tar distillers cannot be shown because publication would reveal the operations of individual companies.

TAR CRUDES TABLE 4A. -- Tar crudes.- U.S. production and sales, 1965

[Listed below are all tar crudes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 4B in pt. Ill lists separately all products for which data on production or sales were reported and iden- tifies the manufacturers reporting to the U.S. Tariff Commission]

of quantity

Quantity

Unit value1

Crude light oil: Coke-oven operators

Intermediate light oil: Coke-oven operators

Light-oil distillates: Benzene, specification and industrial grades,

total2 3 -■

Coke-oven operators

Petroleum operators

Toluene, all grades, total2 3

Coke-oven operators

Petroleum operators

Xylene, total2 3

Coke-oven operators

Petroleum operators

Solvent naphtha, total

Tar distillers

Coke-oven operators

Other light-oil distillates: Coke-oven operators- Naphthalene, crude (tar distillers and coke-oven

operators) , total*

Solidifying at—

Less than 74° C

74° C. to less than 79° C

Crude tar- acid oils:

Tar distillers

Coke-oven operators

Creosote oil (Dead oil) (tar distillers and coke- oven operators) (100$ creosote basis), total5 —

Distillate as such ( 100$ creosote basis)

Creosote content of coal-tar solution (100$

creosote basis)

All other distillate products7

Tar, road, and tar ( crude and refined) for other

uses8

Pitch of tar:

Hard (water softening point above 160° F. )

Other9

1,000 gal- 1,000 gal-

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 lb— 1,000 lb—

1,000 gal- 1,000 gal-

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 gal—

1,000 tons-

1,000 tons-

262,701 4,939

826,910

121,917

704, 993

548,829

24,816

524,013

339,804

6,741

333,063

10,016

4,596

5,420

7,995

463,980

69,537 1,815

510,842

127,449

383,393

324,517

25,087

299,430

201,743

6,913

194,830

7,992

3,41/4

4,578

1,000 dollars 9,441 183

123,282

29,652

93,630

53,882

4,622

49,260

36,734

1,523

35,211

1,622

753

869

448

$0.14 .10

.24 .23 .24 .17 .18 .16 .18 .22 .18 .20 .22 .19 .09

81,856 382, 124

321 28,027

123,602

111,087

12,515

31,445

84,941

916 1,088

76,963

317 28,635

107,452

95,927 11,525

79,818

594 487

1A3 4,365

22,868

19,268 3,600

11,896

22,638 16,753

.20 .31

38.11 34.40

1 Unit value per gallon, or ton, as specified.

2 Data reported by tar distillers are not included because publication would disclose the operations of individual companies. Production of toluene and xylene by tar distillers decreased in 1965, compared with 1964; production of benzene increased. The annual production statistics for petroleum operators on benzene, toluene, and xylene are not comparable with the combined monthly production figures, due to fiscal year revisions.

3 Includes data for material produced for use in blending motor fuels.

* Statistics represent combined data for the commercial grades of naphthalene. Because of conversion of naphtha- lene from one grade to another, the figures may include some duplication.

5 Statistics include only data for creosote oil sold for, or used in, wood preserving. In 1965, production of creosote in coal-tar solution (100$ solution basis) amounted to 21,360 thousand gallons; sales were 19,635 thousand gallons, valued at 3,600 thousand dollars, with a unit value of $0.18 per gallon.

6 Includes value of coal tar used in preparing creosote in coal-tar solution.

7 Includes data for pyridine crude bases, crude cresylic acid, dry distilled tar acid, and neutral oils produced by tar distillers, and for crude sodium phenolate produced by coke-oven operators.

8 Tar (crude and refined) for other uses includes data on tar used for paint, pipe covering, saturating, and other uses.

9 Includes soft and medium pitch of tar (water softening points less than 110° F. , and 110° F. to 160° F. ASTM D61-24), pitch of tar coke, and pitch emulsion.

Note. — Statistics for materials produced in coke and gas- retort ovens are compiled by the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior. Statistics for materials produced in tar and petroleum refineries are compiled by the U.S. Tariff Commission.

4 SYNTHETIC ORGANIC CHEMICALS, 1965

Some of the products included in the statistics in table 4A are derived from other products for which data are also included in the table. The statistics, therefore, involve considerable duplication, and for this reason no group totals or grand totals are given. It is estimated that after duplication has been eliminated insofar as possible the net value of the output of these products and of tar burned as fuel was $500 million in 1965, compared with $460 million in 1964 and $406 million in 1963.

Crude Products From Petroleum and Natural Gas for Chemical Conversion

Crude products that are derived from petroleum and natural gas are related to the inter- mediates and finished products made from such crudes in much the same way that crude prod- ucts derived from the distillation of coal tar are related to their intermediates and finished products. Many of the crude products derived from petroleum are identical with those derived from coal tar (e.g., benzene, toluene, and xylene). Considerable duplication exists in the statis- tics on the production and sales of petroleum crudes because some of these crude chemicals are converted to other crude products derived from petroleum and because data on some pro- duction and sales are reported at successive stages in the conversion processes (see table 5A3). Notwithstanding these duplications, the statistics are sufficiently accurate to indicate trends in the industry and to serve as a basis for general comparison. Many of the crude products for which data are included in the statistics may be used either as fuel or as basic materials from which to derive other chemicals, depending on prevailing economic conditions. In this report, every effort has been made to exclude data on materials that are used as fuel. However, data are included on toluene and xylene which are not used directly as fuel but in blending aviation and motor- grade gasolines.

TABLE ^A..— Crude products from petroleum and natural gas for chemical conversion: U.S. production

and sales, 1965

[Listed below are the crude products from petroleum and natural gas for chemical conversion for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 5B in pt. Ill lists separately all products from petroleum and natural gas for chemical conversion for which data on production or sales were reported and identi- fies the manufacturer of each ]

Production

Quantity

Unit valued-

Grand total

ARQMATICS AND NAPHTHENES2 Total

Alkyl aromatics, distillates, and solvents —

Benzene (1° and 2°), total

Benzene, 1°

Benzene, 2°

Naphthalene, all grades

Naphthenic acids

Toluene, all grades, total

Nitration grade, 1°

Pure commercial grade, 2°

Solvent grade, 90$

All other3 —

Xylenes, mixed, total

3° -

All other3

All other aromatics and naphthenes*

See footnotes at end of table.

1,000 pounds 44,509,671

1,000 pounds 23,402,442

1,000 dollar.

pound

$0,030

214,832

1,878,248 5,202,849

4,139,487 1,063,362

346, 620 24,365

3,809,575

1,877,189 2,829,440

21,873 93,630

.025 .012 .033

269, 845 17,217

10,643 1,805

2,375,829 177,635 124,855

1,131,256

2,401,383

.039 .105

■ 023 .023

503, 673 1,404,723

444,864 1,956,519

100,350

535J25D

969,463

10, 532 35,211

11,625 23,586

.025 TTJ2T .024

See also table 5B, pt, HI, which lists these products alphabetically and identifies the manufacturers.

CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS

TABLE 5A. -

- Crude products from petroleum and natural gas for chemical conversion.- U. S. production and sales, i965--Continued

Unit value1

ALIPHATIC HYDROCARBONS

Total

C2 hydrocarbons, total

Acetylene5

Ethane

Ethylene

C3 hydrocarbons, total

Propane

Propylene

C4 hydrocarbons, total

1,3-Butadiene, grade for rubbers (elastomers)

Butadiene and butylene fractions

n-Butane

1-Butene and 2-butene mixture6

Isobutane

Isobutylene

All other7

C5 hydrocarbons8

All other aliphatic hydrocarbons and derivatives, total.

Alpha olefins9

Diisobutylene (Diisobutene)

Heptenes, mixed

Nonene (Tripropylene)

Polybutene1"

Tetrapropylene--

Hydrocarbon derivatives11

All other12

30,746,281

14,757,498

465,208 1, 546, 660 9,569,885

4,231,286 3,740,835

7,182,182

2,685,359 486, 177 1,879,011 1,067,303 516,726 270,866 276,740

456,523

3,553,702

125,536 33,151 279, 751 244, 257 240,482 462,255 32, 847 2,135,423

663,130 2,714,873

3,135,301 1, 884, 641

4,568,676

1,670,936 102,213 1,022,371 1,080,716 285,391 167, 671 239,378

95,927

115,065 26,689 172,782 161, 009 202, 974 359,033 20,405 636,993

1,000

dollars

489,856

5,781

109,816

29,774 39, 567

237, 143

171,807 4,251 12,295 30,630 3,962 8,448 5,750

2,938 64,837

5,489 1,942 6,483 4,755

12,892 9,102 6,101

18,073

$0,033

.009 .040

.014 .009 .021

.103 .042 .012 .028 .014 .050 .024

.038 .048 .073 .038 .030 .064 .025 .299 .028

Calculated from rounded figures.

2 The chemical raw materials designated as aromatics are in some cases identical with those obtained from the dis- tillation of coal tar. However, the statistics given in the table above relate only to such materials as are derived from petroleum and natural gas. Statistics on aromatic chemicals from all sources are given in table 4A, "Tar Crudes. '

3 Includes toluene and xylene used as solvents, as well as that which is blended in aviation and motor gasolines. * Includes data for 90-percent benzene, crude cresylic acid, sodium cresylate, sodium carbolate and phenate, and

miscellaneous cyclic hydrocarbons.

5 Production figures on acetylene from calcium carbide for chemical synthesis are collected by the U. S. Bureau of the Census.

6 The statistics represent principally the butene content of crude refinery gases from which butadiene is manu- factured.

7 Includes data for 1-butene, 2-butene, mixed butylenes, and mixed olefins.

8 Includes data for isoprene, pentanes, pentenes, and C5 hydrocarbon mixtures.

9 Includes data for the following molecular weight ranges: C6-C7, C8-C10, C1:L-Ci5, Bn^ Ci6-C2o-

10 Includes compounds having a molecular weight of 3,000 or less.

11 Includes data for di-tert-butyldisulfide and miscellaneous mercaptans.

12 Includes data for hexane, heptane, methane, propane-propylene mixture, octanes, 1-dodecene, eicosane, and hydro- carbon mixtures.

The output of crude products derived from petroleum and natural gas as a group amounted to 44,510 million pounds in 1965, or 11.7 percent more than the 39,862 million pounds reported for 1964. The larger output in 1965 is accounted for chiefly by increased production of benzene, toluene, ethylene, and propane. Sales of crude chemicals from petroleum in 1965 were 23,402 million pounds, valued at $705 million, compared with 20,465 million pounds, valued at $619 million, in 1964.

The output of all aromatic and naphthenic products amounted to 13,763 million pounds in 1965, compared with 12,574 million pounds in 1964. Sales in 1965, which amountedto 8,645 million pounds, valued at $215 million, were 1,066 million pounds larger, and valued at $35 mil- lion more, than those in 1964. Naphthalene was produced from petroleum sources in substan- tially greater quantities in 1965 than in 1964. The output of lc and 2° benzene from petroleum

6 SYNTHETIC ORGANIC CHEMICALS, 1965

amounted to 5,203 million pounds in 1965--15.3 percent more than the 4,511 million pounds pro- duced in 1964. The output of toluene in 1965 was 3,810 million pounds-- 11.6 percent more than the 3,413 million pounds produced in 1964. Production of xylene was 2,401 million pounds in 1965, compared with 2,423 million pounds in 1964. These figures include toluene and xylene used in blends in aviation and motor-grade gasolines. The output of naphthenic acids amounted to 24 million pounds in 1965, compared with 30 million pounds produced in 1964.

Production of all aliphatic hydrocarbons and derivatives from petroleum and natural gas was 30,746 million pounds in 1965, compared with 27,288 million pounds in 1964. Sales of these prod- ucts were 14,757 million pounds, valued at $490 million, in 1965, compared with 12,887 million pounds, valued at $439 million, in 1964. The statistics on production of acetylene (table 5 A) in- clude only acetylene produced from natural gas and used as a raw material in the production of other chemicals. Total production of acetylene for chemical synthesis is reported to the U.S. Bureau of the Census. In 1965, production of acetylene from all sources except that produced by railroad shops, shipyards, and small establishments using portable generators, amounted to 1,141 million pounds. Production of ethylene was 9,570 million pounds in 1965, or 10.7 percent more than the 8,641 million pounds produced in 1964. The output of propane and propylene was 7,972 million pounds in 1965--10.3 percent more than the 7,227 million pounds produced in 1964. Production of 1,3 -butadiene, one of the principal ingredients of S-type synthetic rubber, was 2,685 million pounds in 1965, compared with 2,491 million pounds in 1964. The output of 1,3-buta- diene in 1965--7.8 percent more than that in 1964--was the largest on record.

The following tabulation shows the number of companies that reported production of organic chemical crudes in 1965:

Number

of Chemical group companies

Tar crudes 14

Petroleum crudes 72

PART II. PRODUCTION AND SALES OF INTERMEDIATES AND FINISHED SYNTHETIC ORGANIC CHEMICALS, BY GROUPS

General

On the basis of their principal uses, the synthetic organic chemicals covered in this report are classified either as intermediates or as finished products. Finished products, in turn, are grouped as follows: Dyes, synthetic organic pigments, medicinal chemicals, flavor and perfume materials, plastics and resin materials, rubber-processing chemicals, elastomers (synthetic rubbers), plasticizers, surface-active agents, pesticides and other organic agricultural chemi- cals, and miscellaneous synthetic organic chemicals. Most of these groups are further sub- divided, according to chemical classes, into cyclic and acyclic compounds. As most of the in- termediates are used in the manufacture of finished products, aggregate figures that cover both intermediates and finished products necessarily include considerable duplication.

Total production of synthetic organic chemicals (intermediates and finished products com- bined) in 1965 was 88,864 million pounds, or 12.9 percent more than the output of 78,678 million pounds reported for 1964 (see table 6). Sales of synthetic organic chemicals in 1965 amounted to 46,807 million pounds, valued at $9,021 million, compared with 42,766 million pounds, valued at $8,458 million, in 1964. Production of all cyclic products (intermediates and finished products combined) in 1965 totaled 28,229 million pounds, or 10.7 percent more than the 25,506 million pounds produced in 1964. The output of acyclic organic chemicals in 1965 amounted to 60,635 million pounds--14.0 percent more than the 53,172 million pounds reported for 1964.

:

TABLE 6. — Synthetic organic chemicals.- Summary of U.S. production and sales of intermediates and finished products, average 1957-59, annual 1964 and 1965

[Production and sales in thousands of pounds; sales value in thousands of dollars]

Average 1957-59

Increase, or decrease (-)

1965 over 1957-59

1965 over 1964

Organic chemicals, cyclic and acyclic, grand total:

Production

Sales

Sales value

Cyclic, total:

Production

Sales- ---

Sales value —

Acyclic, total:

Production

Sales

Sales value---

1. Inte

Cycli

Production —

Sales

Sales value -

2. Dyes, Cycli

Production —

Sales

Sales value-

3. Synthetic Organic Pigments, Cycli

Production- -

Sales

Sales value -

45,598,853

23,744,812

5 , 743 , 764

14,381,651 8,829,037 2,785,100

31,217,202 14,915,775 2,958,664

7,343,167

2,919,264

481,920

150,830 141,731 182,513

38,603 30,215 58,648

78,677,699

42,766,420

8,457.909

25.505,853 15,241,685 3,890,571

53,171,846 27,524,735 4,567,338

14,895,573

6,470,072

711, 119

184,387 178,273 264,023

44,053 35,081 84,131

88,864,092

46,807,057

9,020,540

28,229,128 16,499, 1B9 3,855,492

60,634,964

30,307,868

5,165,048

16,865,164

7,551,210

814,383

207, 193 189,965 292,284

48,045 38,024 93,635

94.9 97.1 57.0

94.2 103.2 74.6

129.7 158.7 69.0

37.4 34.0 60.1

24.5 25~8 59.7

12.9 9.4

10.7 8.2 -.9

12.4 6.6 10.7

9.1 8.4 11.3

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 6. — Synthetic organic chemicals: Summary of U.S. production and sales of intermediates and finished products, average 1957-59, annual 1964 and 1 965- -Continued

[Production and sales in thousands of pounds; sales value in thousands of dollars]

Average 1957-59

Increase, or decrease (-)

1965 over 1957-59

4. Medicinal Chemicals

Cyclic:

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

5. Flavor and Perfume Materials

Cyclic:

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

6. Plastics and Resin Materials

Cyclic:

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

7. Rubber -Processing Chemicals

Cyclic:

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

«. Elastomers (Synthetic Rubbers)

Cyclic :

Production

Sales

Sales value

Acyclic:

Production

Sales

Sales value

9. Plasticizers

Cyclic:

Production

Sales

Sales value

Acyclic :

Production

Sales

Sales value

See footnote at end of table.

70,654 54,151 535,297

31,592 28,738 35,660

27,312 22,446 33,903

19,033 19,958 21.912

2,278,862

1,900,032

518,501

2,628,779

2,438,853

864,523

159,182 115,704 74,479

29,150 22,127 1/4,289

1,938,732

1,726,757

404,897

521,811 509,262 199,627

348,210

297,423

83,509

118,118 100,984 38,772

97,579

76,946

612,233

46,511 41,732 33,459

49,563 41,235 56,571

41,007 38,802 27, 163

3,915,046

3,256,105

777,342

6,188,018 5,470,616 1,342,942

222,461 161,660 108,656

38,095 22,567 14,371

2,332,436

1,961,181

450,913

1,088,782 996,403 358,989

717,624 689,647 119,565

233,784

215,240

67,903

100,040

72,479

321,158

59,480 56,569 41,011

53,223 44,559 56,800

46,001 43,144 28,180

4,452,975

3,689,722

873,501

7,231,900 6,363,044 1,630,932

211,403 166,21/4 109,204

40,542 27,504 1/4,189

2,300,092

1,897,921

442,722

1,291,562

1,143,242

400,726

798,741 764,736 133,044

274,456 256,887 81,348

i1) (x)

t1)

1A1.7

116.2

28.6

95.4 94.2

175.1 160.9

32.8 43.7 46.6

39.1 24.3

18.6 9.9 9.3

147. 5 124.5 100.7

129.4 157.1 59.3

132.4

154.4 109.8

GENERAL

TABLE 6,-Syntketic organic chemicals: Summary of U.S. production and sales of intermediates and finished products, average 1957-59, annual 1964 and 1965 — Continued

[Production and sales in thousands of pounds; sales value in thousands of dollars]

Average 1957-59

Increase, or decrease (-)

1965 over 1957-59

1965 over 1964

10. Surface-Acti

Cyclic:

Production —

Sales

Sales value- Acyclic :

Production —

Sales

Sales value -

Organ

Cyclic :

Production —

Sales

Sales value -

Acyclic :

Production--

Sales

Sales value-

Agricultu

and Othe il Chemii

-

Cyclic :

Production- Sales

Sales value- Acyclic:

Production —

Sales

Sales value-

852,314 800,432 127.936

502,715 432,135 113,215

440,384 375,627 150,837

105,080 91,938 49,049

733,401 445,252 132,660

27,260,924

11,271,780

1,621,617

1,347,809

1,245,176

165,132

770,879 654,754 185,010

584,698 522,691 316,556

198,051 169,664 110,555

1,114,624 603,618 224,330

44,566,719 19,914,957 2,426,946

1,371,320

877,202

96,153

1,799,158 820,660 204,035

682,671 582,344 377,858

194,526 181,561 119,208

1,138,261 624,813 244,750

49,697,339

21,415,257

2,645,419

55.0 55.0 150.5

85.1 97.5 143.0

55.2 40.3 84.5

82.3

90.0

16.8 11.4 19.4

-1.8 7.0 7.8

2.1 3.5 9.1

11.5 7.5 9.0

1 Data for 1965 are not comparable with those for 1964; for details see the appropriate tables.

The following tabulation shows, by chemical groups, the number of companies that reported production in 1965 of one or more of the chemicals included in the groups listed in table 6:

Number Chemical group oj

comj'atne

Intermediates 213

Dyes 53

Synthetic organic pigments 37

Medicinal chemicals 111

Flavor and perfume materials 55

Plastics and resin materials 320

Numbe r Chemical group of

cvmpanie Rubber-processing chemicals 31

Elastomers (synthetic rubbers) 29

Plasticlzers 58

Surface-active agents 188

Pesticides and other organic agricultural chemicals 85

Miscellaneous chemicals 328

10

SYNTHETIC ORGANIC CHEMICALS, 1965 Cyclic Intermediates

Cyclic intermediates are synthetic organic chemicals derived principally from coal-tar crudes produced by destructive distillation (pyrolysis) of coal and from petroleum and natural gas. Most cyclic intermediates are used in the manufacture of more advanced synthetic organic chemicals and finished products, such as dyes, medicinal chemicals, elastomers (synthetic rubbers), pesticides, and plastics and resin materials. Some intermediates, however, are sold as end products without further processing. For example, refined naphthalene may be used as a raw material in the manufacture of 2-naphthol or of other more advanced intermediates, or it may be packaged and sold as a moth repellent or as a deodorant. In general, the way in which the greater part of the output of a given chemical is consumed determines its use classification in this report. Table 7A gives statistics on production and sales of cyclic intermediates in 1965. Individual statistics given in the table represent more than 85 percent of the total quantity of intermediates produced. Since many of the intermediates included in the statistics represent successive steps in production, the totals necessarily include considerable duplication. In 1965 nearly half of the total output of cyclic intermediates was sold; the rest was consumed chiefly by the producing plants in the manufacture of more advanced intermediates and finished products.

Total production of cyclic intermediates in 1 965 — 1 6,865 million pounds--was the largest on record, and was 13.2 percent larger than the output of 14,896 million pounds reported for 1964. The larger output of cyclic intermediates in 1965 was attributable to increased demand by the chemical products industries, particularly those industries that produce dyes, pesticides, plas- ticizers, and plastics and resin materials. Sales of cyclic intermediates in 1965 amounted to 7,551 million pounds, valued at $814 million, compared with 6,470 million pounds, valued at $711 million, in 1964. In terms of quantity, sales of cyclic intermediates in 1965 were 16.7 percent larger than those in 1964 and in terms of value, 14.5 percent larger.

TABLE 7A. — Cyclic intermediates : U.S. production and sales, 1965

[Listed below are all cyclic intermediates for which any reported data on production or sales may be published.

(Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.; Table 7B in pt. Ill lists alphabetically all cyclic intermediates for which data on production or sales were reported and identifies the manufacturer of each J

Production

Quantity

Unit value1

Total

Acetanilide, tech

H-Acetylsulfanilyl chloride

Alkylbenzenes2

4' -Aminoacetanilide (Acetyl-p-phenylenediaraine)

5-Amino-2-(p-aminoanilino)benzenesulfonic acid

2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid

1-Aminoanthraquinone and salt

2-Aminoanthraquinone and salt

6-Amino-3,4'-azodibenzenesulfonic acid

1 -Amino -4-benzamidoanthraqui none

l-Amino-5-benzamidoanthraquinone

7-(p-Aminobenzamido)-4-hydroxy-2-naphthalenesulfonic acid

2-Amino-p-benzenedisulfonic acid [S03H=l]

l-Amino-4-bromo-9,10-dihydro-9,10-dioxo-2-anthracenesulfonic acid

and sodium salt

l-Amino-2-bromo-4-hydroxyanthraquinone

l-Amino-2-bromo-4-p-toluidinoanthraquinone

l-Amino-5-chloroanthraquinone

o-(3-Amino-4-chlorobenzoyl)benzoic acid

See footnotes at end of table.

1.000 pounds

16,865,164

3,672

3,313

624,894

602

21

47

1,547

1,146

59

95

125

187 204 28 105 116

1.000

pounds

7,551,210

1.000 dollars

814,383

583,634

55,537

1 See also table 7B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, which shows imports of intermediates and related products during 1964 and 1965.

CYCLIC INTERMEDIATES TABLE 7A. — Cyclic intermediates ; U.S. production and sales, 1965 — Continued

Production

Unit value1

3-Amino-5-chloro-2-hydroxybenzenesulfonic acid

2-Amino-5-chloro-p-toluenesulfonic acid [S03H=l]

6-Amino-4-chloro-m-toluenesulfonic acid [S03H>l]

l-Amino-2,4-dibromoanthraquinone

l-Amino-9,10-dihydro-9,10-dioxo-4-p-toluenesulfonamido-2-

anthracenesulfonic acid, sodium salt

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid),

monosodium salt

4-Amino-3-hydroxy-l-naphthalenesulfonie acid (1,2,4-acid)

6-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid),

sodium salt

7-Amino-4-hydroxy-2-naphthalenesulfonic acid (J acid), sodium salt-

N-(4-Aiidno-3-methoxy-l-anthraquinonyl)-p-toluene sulfonamide

4'-Amino-N-methylacetanilide

2-Amino-l,5-naphthalenedisulfonic acid

3-Amino-l,5-naphthalenedisulfonic acid (C acid)

6-Amino-l,3-naphthalenedisulfonie acid (Amino I acid)

7-Amino-l,3-naphthalenedisulfonic acid (Amino G acid)

4-Amino-l-naphthalenesulfonic acid (Naphthionic acid)

5-Amino-2-naphthalenesulfonic acid (1,6-Cleve's acid)

5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed)

6-Amino-2-naphthalenesulfonic acid (Broenner's acid)

8-Amino-l-naphthalenesulfonic acid (Peri acid)

8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid)

8-Amino-2-naphthol

2-Amino-5-nitrobenzenesulfonic acid [S03H=l]

2-Amino-4-nitrophenol

3'-Aminooxanilic acid

p-[(p-Aminophenyl)azo]benzenesulfonic acid

4-Amino-m-toluenesulfonic acid [ S03H=l]

6-Amino-m-toluenesulfonic acid [S03H=1]

5-Amino-2-p-toluidinobenzenesulfonic acid

Aniline (Aniline oil)

7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl J acid)

Anilinomethanesulfonic acid and salt

8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)

o-Anisidine •

o-Anisidinomethanesulfonic acid

Anthranilic acid (o-Aminobenzoic acid)

Anthra[l, 9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone)

N,N'-(l,5-Anthraquinonylene)dianthranilic acid

4',4'"-AzobisL4-biphenylcarboxylic acid]

Benzaldehyde, tech

l-Benzamido-5-chloroanthraquinone

7H-Benz[de]anthracen-7-one ( Benzanthrone )

Benzidine hydrochloride and sulfate

Benzoic acid, tech

o-Benzoylbenzoic acid

[3,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione (Pyrazole- anthrone yellow)

[4,4'-Bi-7H-benz[de]anthracen]-7,7'-dione

l,4-Bis[l-anthraquinonylamino]anthraquinone

4,4'-Bis[dimethylamino]benzophenone (Mlchler's ketone)

3-Bromo-7H-benz [de] anthracen-7-one (3-Bromobenzanthrone)

l-Bromo-4-(methylamino)anthraquinone

p-tert-Butylphenol

1-Chloroanthraquinone

2-Chloroanthraquinone

Chlorobenzene, mono-

o-(p-Chlorobenzoyl)benzoic acid

l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene)

6-Chlorometanilic acid

l-Chloro-2-methylanthraquinone

2-Chloro-4-nitroaniline_ (o-Chloro-p-nitroaniline)

4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline)

1.000 pounds 13 1,585

1,047 370

4,723 1,602

22

60

212

1,187

1,123

145

136

229

135

790

165

65

48

137

19

196

266

207

31

195,547

43

277

417

1,585

347

712

16

26

36

3,979

115

2,256

1,610

16,190

107 239 43

184

1,250

546,292

1,864

8,107

24

140

448

461

1,000 pounds

1,000 dollars

$1.19

2,929 184

2,817

76,277

4,168

1,160 8,461

15,276

82,159

362

1,659

.96

.74

1.60

,959

1,723

1,183 1,522

3,152

5,071 232 277

1.02 .18

.64 .17

See footnotes at end of table.

12 SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE TA.— Cyclic intermediates.- U.S. production and sales , 1965- -Continued

Production

l-Chloro-5-nitroanthraquinone

l-Chloro-8-nitroanthraquinone

l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene ) - l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene ) -

4-Chlora-3-nitrobenzenesulfonamide

2-Chloro-5-nitrobenzenesulfonic acid

4-Chloro-3-nitrobenzenesulf onyl chloride

o-(4-Chloro-3-nitrobenzoyl)benzoic acid

(p-Chlorophenyl)acetonitrile

K -Chlorotoluene (Benzyl chloride)

4-Chloro-o-toluidine [NH2=l] and hydrochloride-- 5-Chloro-o-toluidine [NH2=1] and hydrochloride - -

N-[(5-Chloro-o-tolyl)azo]sarcosine

[(4-Chloro-o-tolyl)thio] acetic acid

Cresols, total3

m-, o-, and p-Cresols

(m,p)-Cresol (from coal tar and petroleum) - (o,m,p)-Cresol4

Cresylic acid, refined, total3

From coal tar

From petroleum

Cumene

Cyclohexane

Cyclohexanol

Cyclohexanone

Cyelohexylamine

1,4-Diaminoanthraquinone

1,5-Diaminoanthraquinone

2,6-Diaminoanthraquinone

l,4-Diamino-2,3-dihydroanthraquinone

4,4'-Diamino-2,2'-stilbenedisulfonic acid

4,5'-Dibenzamido-l,l'-iminodianthraquinone

1,5-Dibenzoylnaphthalene

3,9-Dibromo-7H-benz[de]anthracen-7-one

2,5-Dichloroaniline and hydrochloride [NH2=l]

1,5-Dichloroanthraquinone

o-Dichlorobenzene

p-Dichlorobenzene

3,3'-Dichlorobenzidine base and salts

2 , 5-Dichloro-4- ( 3-methyl-5-oxo-2-pyrazolin-l-yl ) benzenesulf onic

acid-

2,6-Dichloro-4-nltroanillne

l,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene)

2,5-ffl.chlorosulfanilie acid [s03H=l]

p-(Diethylamino)benzaldehyde

N,N-Diethylaniline

9,10-Dihydro-l,4-dihydroxy-9,10-dioxo-2-anthracenesulfonic acid (2-Quinizarinsulfonic acid)

9,10-Dihydro-9,10-dioxo-l,5-anthracenedisulfonic acid and disodium salt

9,10-Dihydro-9,10-dioxo-l,8-anthracenedisulfonic acid,

potassium salt ;

9,10-Dihydro-9,10-dioxo-2,6-anthraeenedisulfonic acid and salt

9,10-Dihydro-9,10-dioxo-l-anthracenesulfonic acid and salt

9,10-Dihydro-5-nitro-9,10-dioxo-l-anthracenesulfonic acid

9,10-Dihydro-l-nltro-9,10-dloxo-2-anthroic acid

1,4-Dihydroxyanthraqulnone (Quinizarin)

1 , 5-Dihydroxyanthraquinone (Anthrarufin)

1,8-Dihydroxyanthraquinone (Qirysazin)

2,6-Dihydroxyanthraquinone (Anthraflavic acid)

l,8-Dihydroxy-4,5-dinitroanthraquinone (4, 5-Dinitrochrysazin )

16,17-Dihydroxyviolanthrone (Dihydroxydibenzanthrone)

l.nnn

pounds

117

56

28,290

109,757

275

89

248

U5

34

62,000

62

507

181

71,168

innn

pounds

10,536

32,533 24,022 14,613

50,890

21,969 28,921

663,009 1,700,245

321,651

13,651

64

64

179

398

4,784

142

231

330

123

199

41,115

65,835

2,677

292 259 705 110 30 1,721

1,226

412 369

3,066 135 29

1,962 233 181 9 461 337

72,019

29,268 27,715 15,036

56,966

21,998

34, <

1,474,742

2,663

12,269

5,528

37,199 66,546 2,331

159 1,732

8,636 3,032 1,949

6,192

2,587 3,605

60,166

679

3,152

1,386

4,239 5,789 2,851

See footnotes at end of table.

CYCLIC INTERMEDIATES TABLE 1A. --Cyclic intermediates.- U.S. production and sales , 1965--Continued

m-Dimethoxybenzene

3,3'-Dimethoxybenzidine

16,17-Dimethoxyviolanthrone

N,N-Dimethylaniline

N,N-Dimethyrbenzylamine

2,2'-Dlmethyl-l,l'-bianthraquinone

N,N-Dimethyl-p-nitrosoaniline

p-(2,4-Dinitroanilino)phenol

2,4-Dinitrophenol, tech

4,4'-Dinitrostirbene-2,2'-disulfonie acid

1,4-Di-p-toluidinoanthraquinone

Divinylbenzene

p-Dodecylphenol

N-Ethylaniline, refined

Ethylbenzene5

N-Ethyl-N-phenylbenzylamine

o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde)

p-Hydrazinobenzenesulfonic acid

p-Hydroxybenzenesulfonic aoid (l-Phenol-4-sulfonic acid)

p-Hydroxybenzoic acid, methyl ester

p-Hydroxybenzoic acid, propyl ester

4-Hydroxymetanilamide

4-Hydroxymetanilic acid

3-Hydroxy-2,7-naphthalenedisulfonic acid, disodium salt- 6-Hydroxy-2-naphthalenesulfonic acid (Schaeffer's acid)

sodium salt

3-Hydroxy-2-naphthoic acid (B.O.N.)

N-(7-Hydroxy-l-naphthyl)acetamide

l,l'-Iminobis ,4-aminoanthraquinone]

1,1' -Iminobis . 5-benzamidoanthraquinone]

7,7'-Iminobis ;4-hydroxy-2-naphthalenesulfonic acid]-

1,1' -Iminobis[4-nitroanthraquinone]

l,l'-Iminodianthraquinone (l,l'-Dianthrimide)

Isocyanic acid derivatives, total

Diphenylmethane 4,4'-diisocyanate (MDI)

Toluene 2,4- and 2,6-diisocyanate (80/20 mixture) All other

4,4'-Isopropylidenediphenol (Bisphenol A)

Isoviolanthrone ( Isodibenzanthrone )

Leuco quinizarin (1,4,9,10-Anthratetrol)-

o-Mercaptobenzoic acid

Metanilic acid (m-Aminobenzenesulfonic acid)

l-(Methylamino)anthraquinone

4,4'-Methylenebis[N,N-dimethylaniline] (Methane base)

4,4-'-Methylenedianiline

p-(3-Methyl-5-oxo-2-pyrazolin-l-yl)benzenesulfonic acid

4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid [so3H=l] ■

3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z)

a-Jfethylstyrene

Naphthalene, solidifying at 79°C. or above, refined from domestic

crude-

1,4,5,8-Naphthalenetetracarboxylic acid

1-Naphthol (a -Naphthol)

Naphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid

p-Nitroaniline

4-Nitro-o-anisidine [NH2=l]

5-Nitro-o-anisidine [NH2=l]

Nitrobenzene

m-Nltrobenzenesulfonic acid and sodium salt

3-Nitro-l,5-naphthalenedisulfonic acid

7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid- p-Nitrophenol and sodium salt

Production

1.000

567

133

11,041

69

90

36

935

6,449

202

2,748

11,021

761

3,022,730

838

271

175

6,310

246

102

119

106

1,715

348 3,951

24 138 45 21 103 145

184,262

4,817

146,578

32,867

97,197

44

88

73,201

17

917

175

1,206

1,086

203

6

281

13,553

4,731 57

1,250

12,478

103

108

280,341

2,293

223

1,084

19,856

Quantity

1.000 pounds

6,003 81

1,762

385 580,332

6,202 256 74

776 205

162,739

Unit value1

138,152 24,587

56,487

59,285

190 536

216 8,480

801 6,883

11,506 2,397

11,273

1,000 dollars

1,296

111

1,403

189 23,614

956 375 164

703 164

61,648

49,024 12,624

11,753 15,064

425 303

353 941

484 2,988

1,051 1,023

4,292

See footnotes at end of table.

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 7A. — Cyclic intermediates : U.S. production and sales , 1965 — Continued

Quantity

Unit

value1

5-Nitro-o-toluenesulf onic acid [ S03H=l] '

3-Nitro-p-toluenesulfonic acid [ S03H=l]

2-Nitro-p-toluidine [NH2=l]

16-Nitroviolanthrone

Nonylphenol

l-[(7-0xo-7H-benz[de] anthracen-3-yl) amino] anthraquinone

l,l'-[(7-0xo-7H-benz[de]anthracen-3,9-ylene)diimino]dianthraquinone

5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester

5-0xo-l-(p-sulfophenyl)-2-pyrazoline-3-carboxylic acid

(Pyrazolone T)

Phenol, grand total3

Natural, total

From coal tar

From petroleum

Synthetic, total

From cumene

Other synthetic

Phenylacetic acid and salts

p-Phenylazoaniline (p-Aminoazobenzene) and hydrochloride

l-Phenyl-l,2-propanedione, 2-oxime (Isonitrosopropiophenone)- Phthalic anhydride

Picolines, total6

2-Picoline (a -Picoline)

Other picolines

Piperidine

Propiophenone

8,16-Pyranthrenedione

2°-Pyridine6

Quinaldine

Salicylaldehyde

Salicylic acid, tech

Styrene, all grades

Terephthalic acid, dimethyl ester

1,4,5,8-Tetrachloroanthraquinone

1,4,5,8-Tetrahydroxyanthraquinone, leuco derivative

Toluene-2,4-diamine (4-m-Tolylenediamine)

o(and p) -Toluenesulfonic acid

4-(o-Tolylazo)-o-toluidine

l,3,3-Trimethyl-A2'a-indolineaeetaldehyde

l,3,3-Trimethyl-2-methyleneindoline

7,7 '-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] (J acid urea) Violanthrone (Dibenzanthrone)

o-Xylene

p-Xylene

Xylenols7

All other cyclic intermediates-

1,000

pounds

8,429

73

1,257

88

61,001

375

637

1,229,113

55,672

41,055

U,617

1,173,441

560,040

613,401

4,056

166

248

608,318

4,779

1,000 pounds

822

22,190

532,704

2,332 2,447

434

533

19

6,488

38

2,540

22,763

2,864,306

544,578

89

127

54,411

5,868

467

141

326

437

569

351,369

396,333

14,585

2,321,922

52,532

36,241

16,291

480,172

224,040

256,132

3,290

336,289 2,493

1,000 dollars

2,424

50,222

812 1,681

5,751

1,839

5,138

1,248,222

218,991

5,183

343,755

375,248

12,440

990,168

47f

3,198

1,690

45,334

20,682

24,652

1,285

28,364 1,011

~278~ 733

3,313

1,879

1,786

95,190

52,474

9,121

32,714

1,478

216,479

.10 .09 .10

.58 1.02

.22

1 Calculated from rounded figures.

Principally straight-chain dodecylbenzene and tridecylbenzene, but includes lesser amounts of branched-chain com- pounds and other alkylbenzenes.

3 Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior, and for tar and petroleum refineries and other producers, reported to the U.S. Tariff Commission.

4 Includes some mixed cresols. Figures include (o,m,p)-eresol from coal tar and from petroleum.

5 Does not include ethylbenzene produced and consumed in continuous-process styrene manufacture.

6 Includes data for coke ovens and gas-retort ovens, reported to the Division of Bituminous Coal, U.S. Bureau of Mines, Department of the Interior, and for tar refineries and other producers, reported to the U.S. Tariff Commission.

7 Includes low- and medium-boiling xylenols and xylenols unclassified as to boiling point.

DYES 15

In 1965, production of ethylbenzene exceeded 3 billion pounds for the first time, reaching 3,023 million pounds. Styrene production in 1965 was 2,864 million pounds, an 11.4-percent in- crease over the 2,571 million pounds reported for 1964. Ethylbenzene is used almost entirely in the manufacture of styrene, which, in turn, is used almost entirely in the manufacture of plastics materials and synthetic rubber. Other intermediates whose production exceeded one billion pounds in 1965 were cyclohexane at 1,700 million pounds, representing a 24.4-percent increase over the 1,367 million pounds reported for 1964, and phenol at 1,229 million pounds, represent- ing a 10.4-percent increase over the 1964 production of 1,113 million pounds. The output of other large-volume intermediates in 1965 compared with production in 1964 was as follows: Cumene, 663 million pounds (20.6 percent larger); phthalic anhydride, 608 million pounds (9.1 percent larger); monochlorobenzene, 546 million pounds, (1.6 percent larger); terephthalic acid, dimethyl ester, 545 million pounds (53.1 percent larger); p-xylene, 396 million pounds (34.0 per- cent larger); and isocyanates, 184 million pounds (33.6 percent larger).

Dyes

Dyes produced in the United States are all derived in whole or in part from cyclic inter- mediates. Approximately two-thirds of the dyes consumed in the United States are used by the textile industry to dye natural and synthetic fibers or fabrics; about one-sixth are used for color- ing paper; and the rest are used chiefly in the production of organic pigments and in the dyeing of leather and plastics. Of the several thousand different synthetic dyes that are known, more than two thousand are manufactured by one or more domestic producers. The large number of dyes results from the many different types of materials to which dyes are applied, the different con- ditions of service for which dyes are required, and the costs that a particular use can bear. Dyes are sold as pastes, powders, lumps, and solutions; concentrations vary from 6 percent to 100 percent. The concentration, form, and purity of a dye are determined largely by the use for which it is intended.

Table 8A2 shows U.S. production and sales of dyes in 1965, total and by individual dyes, using the Colour Index classification and terminology.

Total domestic production of dyes in 1965 amounted to 207 million pounds, or 12.4 percent more than the 184 million pounds in 1964. Sales of dyes in 1965 amounted to 190 million pounds, valued at $292 million, compared with 178 million pounds, valued at $264 million, in 1964. In terms of quantity, sales of dyes in 1965 were 6.6 percent larger than in 1964, and in terms of value, 10.7 percent larger. The average unit value of sales of all dyes in 1965 was $1.54 a pound, compared with $1.48 a pound in 1964.

For many important individual low- and medium-priced dyes for which statistics are given in table 8A, production was larger in 1965 than in 1964. The output of Vat Green 8 was 2.0 mil- lion pounds in 1965, or 78.8 percent more than the 1.1 million pounds produced in 1964; that of Vat Black 25 was 4.5 million pounds, or 44.7 percent more than the 3.1 million pounds produced in 1964. Other important dyes whose output was substantially larger in 1965 than in 1964 were Disperse Yellow 3 (38.3 percent), Vat Green 3 (34.3 percent). Vat Yellow 2 (33.0 percent), Sulfur Black 1 (31.9 percent), Direct Blue 2 (23.0 percent), and Mordant Black 11 (17.4 percent).

On the other hand, the output of a few important dyes was smaller in 1965 than in 1964. Pro- duction of Vat Green 1 was 3.8 million pounds in 1965, or 36.4 percent less than the 5.9 million pounds produced in 1964; that of Leuco Sulfur Black 2 was 2.2 million pounds, or 20.5 percent less than the 2.8 million pounds produced in 1964. The output of Acid Black 1 was 9.7 percent smaller in 1965 than in 1964, and that of Vat Blue 6 was 4.4 percent smaller.

2 See also table 8B, pt. Ill, which lists these products and identifies the manufacturers, and the appendix (table 23), which shows imports of dyes during the years 1964-65.

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 8A. --Benzenoid dyes.- U.S. production and sales , 1965

[Listed below are all benzenoid dyes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 8B in pt. Ill lists all dyes for which data on production or sales were reported and identifies the manufacturer of each]

Dye

Production

Grand total

ACID DYES

Total

Acid yellow dyes, total

Acid Yellow 3

Acid Yellow 11

Acid Yellow 17 ■

Acid Yellow 23

Acid Yellow 36— - —

Acid Yellow 40

Acid Yellow 42

Acid Yellow 44

Acid Yellow 54

Acid Yellow 73

Acid Yellow 99

All other

Acid orange dyes, total

Acid Orange 1

Acid Orange 7

Acid Orange 8

Acid Orange ID

Acid Orange 24

Acid Orange 60

Acid Orange 64

All other

Acid red dyes, total

Acid Red 1

Acid Red 4

Acid Red 1A

Acid Red 18

Acid Red 26

Acid Red 37

Acid Red 73

Acid Red 85

Acid Red 87

Acid Red 88 •

Acid Red 89

Acid Red 99 - ■

Acid Red 114 - ~ •

Acid Red 115

Acid Red 137- — ■

Acid Red 151 •

Acid Red 182

Acid Red 186

All other

Acid violet dyes, total

Acid Violet 1

Acid Violet 3— ■

Acid Violet 7

Acid Violet 12

Acid Violet 49

All other

1,000 pounds 207, 193

20,395

3,375

46 461 387 239 140

89

246

1,633 2,793

77 698 315 265 502 60 50 826

3,489

654 95 100 129 112 40 250 162

173 58

142 118

1,171

67 71

104 73 77

102

1,000 pounds 189,965

1,000 dollars 292,284

18,666

2,961

3T

46

472

334

241

135

52

28

65

72

70

1,415

2,789

T8~ 717 354 294 516 47

2,973

592 114 116 114 110 42 249 160

171 66 39

136

106 41 34

601

58 81

122 62 72

107

39,025

6,743

111

96

1,011

728

361

374

85

82

141

163

157

3,434

4,271

100 672 404 384 693 120 168 1,730

6,022

621

207 159 135 135 126 547 288 183 202

71 397 138

64 429 230 131 103 1,856

944

83

1A2 166 94 160 299

See footnotes at end of table.

DYES

TABLE 8A. --Benzenoid dyes ; U.S. production and sales , 1 965- -Continued

Eye

Quantity

ACID DYES— Continued

Acid blue dyes, total

Acid Blue 7

Acid Blue 9

Acid Blue 25 —

Acid Blue 40

Acid Blue 41

Acid Blue 43

Acid Blue 45

Acid Blue 62

Acid Blue 78

Acid Blue 90

Acid Blue 113

Acid Blue 118

Acid Blue 158 and 158A —

All other

Acid green dyes, total

Acid Green 3

Acid Green 9

Acid Green 12

Acid Green 16

Acid Green 20

Acid Green 25

All other

Acid brown dyes, total

Acid Brown 1A

All other

Acid black dyes, total

Acid Black 1

Acid Black 24

Acid Black 48 — —

Acid Black 107— -

All other

AZOIC DIES AND COMPONENTS

Azoic Compositions

Total

Azoic Yellow 1

Azoic Yellow 3

Azoic Orange 3

Azoic red dyes, total

Azoic Red 1

Azoic Red 2

Azoic Red 6

Azoic Red 16

All other

Azoic Blue 2

Azoic Blue 3

Azoic Brown 9

Azoic black dyes

All other azoic compositions

1,000 pounds 3,695

748 121

212 1,343

1,075

206 25 15 81 38 364 346

306 489

4,679

1,247

1D1

12

289

3,030

2,100

202

67

304

115 1A9 823 218

1,000 pounds 3,275

1,000 dollars

74 24

538

26

39

9

351

188 1,812

179 23 13 65 38 260 312

270 467

4,539

1,178 120 25 187

3,029

2,043

200 64

301 6 87

13 113 146 790 216

9,582

647

59 247 181 1,722 166 257

91 529

424 5,061

2,431

211 101

54 245

73 782 965

1,683

385 1,298

7,349

1,436 210 130 522

5,051

3,968

94 4 91

1,159

348 124 500 17 170

26

185

479

1,403

527

See footnotes at end of table.

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 8A. --Benzenoid dyes.- U.S. production and sales, 1 965- -Continued

Production

Quantity

AZOIC DYES AND COMPONENTS— Continued

Azoic Diazo Components , Bases (Fast Color Bases)

Total- - -

Azoic Diazo Component 4, base

Azoic Diazo Component 9, base

Azoic Diazo Component 10, base

Azoic Diazo Component 12, base

Azoic Diazo Component 13, base

Azoic Diazo Component 32, base

Azoic Diazo Component 48, base

All other azoic diazo components, bases

Azoic Diazo Components , Salts (Fast Color Salts)

Total -

Azoic Diazo Component 1, salt

Azoic Diazo Component 2, salt

Azoic Diazo Component 3, salt

Azoic Diazo Component 5, salt

Azoic Diazo Component 6, salt

Azoic Diazo Component 8, salt

Azoic Diazo Component 9, salt

Azoic Diazo Component ID, salt

Azoic Diazo Component 11, salt

Azoic Diazo Component 12, salt

Azoic Diazo Component 13, salt -r -.

Azoic Diazo Component 28, salt

Azoic Diazo Component 48, salt

Azoic Diazo Component 49, salt

All other azoic diazo components, salts

Azoic Coupling Components (Naphthol AS and Derivatives)

Total

Azoic Coupling Component 2

Azoic Coupling Component 3

Azoic Coupling Component 4

Azoic Coupling Component 5

Azoic Coupling Component 7

Azoic Coupling Component 8

Azoic Coupling Component 11

Azoic Coupling Component 14

Azoic Coupling Component 17

Azoic Coupling Component 18

Azoic Coupling Component 19

Azoic Coupling Component 20

Azoic Coupling Component 21

Azoic Coupling Component 29

All other azoic coupling components

1,000 pounds 1,558

107 54 71 237 377 307

2,835

3,172

1,310

1,000 dollars 2,057

46 224 341 276

2,646

2,429

151 266 429 427 79 623

2,683

296

309

200

357

327

373

40

43

153

123

125

435

384

246

92

89

132

42

72

103

102

111

421

371

254

340

338

364

90

86

96

39

38

110

464

352

495

271

39

14

44

53

23

46

ID

28

791

715

1,454

19

22

21

70

215

141

276

176

817

616

736

7

6

35

137

92

198

112

69

150

32

24

55

481

698

1,577

See footnotes at end of table.

DYES

19

TABLE 8A. — Benzenoid dyes : U.S. production and sales , 1965 — Continued

Eye

Quantity

BASIC DYES

Total -

Basic yellow dyes, total

Basic Yellow 2

Basic Yellow 11

Basic Yellow 13

All other

Basic orange dyes, total

Basic Orange 1

Basic Orange 2

Basic Orange 21

All other

Basic red dyes, total

Basic Red 14-

All other

Basic violet dyes, total

Basic Violet 1

Basic Violet 3

Basic Violet 4

Basic Violet 16

All other

Basic blue dyes, total

Basic Blue 1

Basic Blue 5

Basic Blue 7

Basic Blue 9

Basic Blue 26

All other

Basic Green 1

Basic Green 4

Basic Brown 1

Basic Brown 4

All other basic dyes

DIRECT DYES

Total- - —

Direct yellow dyes, total

Direct Yellow 4

Direct Yellow 5~-

Direct Yellow 6

Direct Yellow 11

Direct Yellow 12

Direct Yellow 26

Direct Yellow 28

Direct Yellow 44

Direct Yellow 50

Direct Yellow 59

Direct Yellow 84

Direct Yellow 105

Direct Yellow 106

All other

1,000 pounds 10,573

1,923

605 482

1,353

339

543 358 113

1,213

436 777

2,991

983

38

130

1,840

1,569

25 22

474

65

983

87 594 254 541

48

36,080

6,719

"463"

75

752

974

388

' 345 403 398 327 467 188 691

1,443

1,000 pounds 9,553

1,794

614 431

333

549

341

94

1,055

351

704

2,750

932 1,129

109 549

128 299

95

584 195 505 48

33,663

6,214

422 105 703 865 393 6 300 395 365 122 398 220 592 1,328

1,000 dollars 23,907

5,419

1,

1,717

326

2,088

2,416

355

646

1,082

333

3,428

1,097 2,331

5,582

1,198

2,045

97

388

1,854

4,154

105

396

699

173

2,781

300 1,506 290 669 143

50,970

10,972

~§97~

302

1,101

979

926

15

568

671

745

183

567

536

1,008

2,474

See footnotes at end of table.

20 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8A. --Benzenoid dyes; U.S. production and sales, 1965 — Continued

Dye

Production

DIRECT DYES— Continued

Direct orange dyes, total

Direct Orange 1

Direct Orange 8

Direct Orange 15

Direct Orange 26

Direct Orange 34

Direct Orange 37

Direct Orange 39

Direct Orange 72

Direct Orange 73

Direct Orange 81

Direct Orange 102

All other

Direct red dyes, total

Direct Red 1

Direct Red 2

Direct Red 4

Direct Red 10

Direct Red 13

Direct Red 16

Direct Red 23

Direct Red 24

Direct Red 26

Direct Red 28

Direct Red 31

Direct Red 37

Direct Red 39

Direct Red 75

Direct Red 79

Direct Red 80

Direct Red 81

Direct Red 83

Direct Red 122

Direct Red 127 and 127A

Direct Red 149— - --

Direct Red 153

All other

Direct violet dyes, total

Direct Violet 1

Direct Violet 9

Direct Violet 51-

All other

Direct blue dyes, total

Direct Blue 1

Direct Blue 2

Direct Blue 6

Direct Blue 8

Direct Blue 14

Direct Blue 15

Direct Blue 22

Direct Blue 24

Direct Blue 25

Direct Blue 71

Direct Blue 76

Direct Blue 78

Direct Blue 80

Direct Blue 86

Direct Blue 98

Direct Blue 120 and 120A

Direct Blue 126

Direct Blue 151

All other

See footnotes at end of table.

1,901

164

201 68 137 63 132 344 34 57 165 500

4,519

275

472

30

20

190

65

259

464

172

198

47

75

72

301 587 385 113

26

699

112 8,141

431

2,248

571

30

129

62

24

43

39

80

574

124

438

1,211

118

178

142

1,699

1,000 pounds 1,829

1,000 dollars 4,044

170 184

121 319 58 57 185 488

4,198

~T7S 463

17 165

64 227 412 178 203

28 284 513 344 115

36

84

7

60

7,81/;

407

2,177

527

43

113

65

22

38

54

86

583

108

404

1,1D3

125

189

175

30

1,565

36 228 222

87 272 153 250 685 231 178 474 1,228

9,102

"359" 803

28 264 124 553 810 451 277

95 219 158

99 684 901 872 179 178

1,661 506

203

48

232

11,437

731

1,928

267

80

102

111

40

53

146

252

1,106

303

650

1,712

235

397

462

40

2,822

DYES TABLE 8A. — Benzenoid dyes • U.S. production and sales, 1965 — Continued

Dye

Quantity

DIRECT DYES— Continued

Direct green dyes, total

Direct Green 1

Direct Green 6

Direct Green 8

Direct Green 12

Direct Green 38

All other

Direct brown dyes, total

Direct Brown 1 and 1A

Direct Brown 2

Direct Brown 6

Direct Brown 31

Direct Brown 74

Direct Bro»n 95

Direct Brown 111

Direct Brown 154

All other

Direct black dyes, total

Direct Black 4

Direct Black 9

Direct Black 19

Direct Black 22

Direct Black 38

Direct Black 51

Direct Black 80

All other .

DISPERSE DYES

Total

Disperse yellow dyes, total

Disperse Yellow 3

Disperse Yellow 5

Disperse Yellow 23

Disperse Yellow 33

Disperse Yellow 34

Disperse Yellow 42

Disperse Yellow 54

All other

Disperse orange dyes, total

Disperse Orange 3

Disperse Orange 5

Disperse Orange 17-

All other

Disperse red dyes, total

Disperse Red 1

Disperse Red 5

Disperse Red 11

Disperse Red 13

Disperse Red 17

Disperse Red 60

All other

Disperse Violet 1

Disperse Violet 4

Disperse Violet 27

1,396

275 456

37 29

1,883

266

200 84

102 56

560

369 246

11,364

234

64

208

903

6,297

56

2,148

1,454

15,514

2,707

1,290 56

229 202 201 185 544

104

98

179

707

2,178

273 112 42 36 127

1,000 pounds 1,1*9

201

471

32

1A 431

1,756

227

184

103

93

62

498

61

322

206

10,541

194

48

224

738

5,833

65

2,087

1,352

13,522

2,484

1,245 44 74 21B 171 189 155 388

801

115 523

1,919

232 69 30 28

124

80

1,356

33 20 161

1.000 dollars 2,610

267

559 41

50 1,693

2,496

T0B~ 283 119 270 93 437 217 313 456

9,803

199 68

322

637 4,487

207 1,850 2,033

32,878

4,822

2,040 150 197 348 295 330 565 897

1,503

159

170 178 996

5,899

379

85

128

38

170

291

4,808

111

58

238

See footnotes at end of table.

22

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 8A. --Benzenoid dyes : U.S. production and sales, 1965- -Continued

Dye

Quantity

DISPERSE DYES— Continued

Disperse "blue dyes, total

Disperse Blue 1

Disperse Blue 3

Disperse Blue 7

Disperse Blue 64

All other

Disperse "black dyes, total

Disperse Black 1

Disperse Black 9

All other

All other disperse dyes

FIBER-REACTIVE DYES

Fiber- reactive dyes, total

Reactive yellow dyes

Reactive red dyes

Reactive blue dyes

All other reactive dyes

FLUORESCENT BRIGHTENING AGENTS

Total- — —

Fluorescent Brightening Agent 9

Fluorescent Brightening Agent 28

All other fluorescent brightening agents

FOOD, DRUG, AND COSMETIC COLORS

Total

Food, Drug, and Cosmetic Dyes

Total

FD&C Blue No. 1

FD&C Red No. 2 —

FDScC Red No. 3 - -

FDScC Red No. 4— —

FDScC Yellow No. 5

FD&C Yellow No. 6-

All other food, drug, and cosmetic dyes

6,296

Drug

nd Cosmetic and Cosm

and Exte ■tic Dyes

jl Drug

348 1,928

319

101

3,600

2,723

344 2,379

361

1,586

631 679

19,420

3,749 1,515 W-, 156

2,923

2,681

Total — -

D&C Red No. 12 — - —

D&C Red No. 19 —

D&C Red No. 21 -

D&C Red No. 36 -

All other drug and cosmetic and external drug and cosmetic dyes

1,000 pounds 5,559

250

1,576

301

1A4

3,288

2,266

275

1,572

419

1,558

271 337 613 337

18,284

3,588 1,568 13,128

2,736

2,493

1,000 dollars 16,700

1,024

2,520

2,041

464

10,651

2,1

336

1,607

945

6,744

1,023 1,223 3,320 1,178

34,516

5,675 2,427 26,414

10,238

8,971

85

52

596

819

820

2,223

111

90

1,278

21

56

241

770

682

2,127

782

700

1,949

93

93

557

1,267

130 31

1,051

See footnotes at end of table.

DYES

23

TABLE 8A.- -Benzenoid dyes.- U.S. production and sales , i365--Continued

Eye

MORDANT DYES

Total— -

Mordant yellow dyes, total

Mordant Yellow 1

Mordant Yellow 8

All other

Mordant orange dyes, total

Mordant Orange 1

All other

Mordant red dyes, total

Mordant Red 7

All other

Mordant blue dyes, total

Mordant Blue 1

All other

Mordant brown dyes, total

Mordant Brown 1

Mordant Brown 40

All other

Mordant black dyes, total

Mordant Black 3

Mordant Black 5

Mordant Black 11

Mordant Black 13

Mordant Black 17

Mordant Black 38

All other

All other mordant dyes

SOLVENT DYES

Total

Solvent yellow dyes, total

Solvent Yellow 2 —

Solvent Yellow 3

Solvent Yellow U

Solvent Yellow 47

All other

Solvent orange dyes, total

Solvent Orange 2

Solvent Orange 3

Solvent Orange 7

All other

Solvent red dyes, total

Solvent Red 24

Solvent Red 26

Solvent Red 49

All other

Solvent violet dyes, total

Solvent Violet 8

All other

Solvent Blue 38

See footnotes at end of table.

Quantity

31 136

117 90

3,715

2,412

61

970

9,837

1,020

38 42

663 30

247

110 244

1,478

362 290 46 780

323 161

4,246

43

12

187

43

101

23 180

3,288

18

19

2,303

25

672

17

234

16

43 42

548 42

220

4

21

116

228

1,362

284 272 40 766

1,000 dollars 5,706

23 336

205 279

169 135

137

58

434

3,582

33 2,311

72 675

52 4W

15,351

543 198

1,004

7

45

164

475

2,640

540

498

258

1,344

982

24

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 8A. — Benzenoid dyes.- U.S. production and sales, 1965 — Continued

Dye

Production

Quantity

SOLVENT DYES — Continued

Solvent green dyes, total

Solvent Green 3

All other

Solvent Drown dyes

All other solvent dyes

SULFUR DYES2

Total

Sulfur Blue 7

Sulfur Blue 11

Sulfur Blue 15

Sulfur Brown ID

Sulfur Black 1

Leuco Sulfur Black 1

Leuco Sulfur Black 2

All other sulfur dyes

VAT DYES

Total

Vat yellow dyes, total

Vat Yellow 2, 8-3/2%

Vat Yellow 4, 12-1/2%

All other

Vat orange dyes, total

Vat Orange 1, 20%

Solubilized Vat Orange 1, 26%

Vat Orange 2, 12%

Vat Orange 3, 13-1/2%

Vat Orange 4, 6%

Vat Orange 5, ]fl%

Solubilized Vat Orange 5, 30%

Vat Orange 7, 11%

Vat Orange 9, 12%

Vat Orange 15, 10%

All other

Vat red dyes, total

Vat Red 1, 13%

Vat Red 13, 11%

Vat Red 15, 10%

Vat Red 32, 20%

All other :

Vat violet dyes, total

Vat Violet 1, 11%

Vat Violet 2, 20%

Vat Violet 9, 12%

Vat Violet 13, 6-1/4%

All other

Vat blue dyes, total

Vat Blue 6, 8-1/3%

Vat Blue 18, 13%-

Vat Blue 20, 14%

All other-

See footnotes at end of table.

5,900

18,648

57,511

4,090

2,373 763 954

2,794

322

110

113 7 312 124 687 493

1,412

651 125 286

310

34

133

421

21,964

3,395

1,433

1,205

15,931

97

360

56

220

86

304

,586

8,270

17,471

52,439

3,897

2,417 675 805

2,463

553

81 163

271 109 564 438

1,143

201 30 265

214

33

391 68

19,924

3,318

1,125

1,073

14,408

9,960

120

130

92

26

26

6

13

47

50

34

1,419

1,160

404

5,827

5,871

2,154

2,207

2,030

800

9,028

8,198

6,437

48,728

5,303

2,126

865

2,312

5,846

1,506

53

509

242 232

795

269

1,362

878

2,436

~K2~ 284 201 131 978

335 490

197

12,659

3,527 1,942 1,450 5,740

DYES

25

TABLE 8A.--Bemenoid dyes.- U.S. production and sales , 1965— Continued

Eye

Production

Quantity

Unit value1

VAT DYES— Continued

Vat green dyes, total

Vat Green 1, 6$

Vat Green 3, 1A#

Solubilized Vat Green 3, 26$

Vat Green 8, 8- 1/2$

Vat Green 9, 12-1/2$

All other

Vat brown dyes, total

Vat Brown 1, 11$

Vat Brown 3, 11$

Vat Brown 5, 13%

All other

Vat black dyes, total

Solubilized Vat Black 1, 27-1/2$

Vat Black 9, 16$ ■

Vat Black 25, 12-1/2$

Vat Black 27, 12-1/2$ - ■

All other

All other dyes3

1.000 11,425

ID, 574

3,755 3,970 16 2,015 1,468 201

5,037

629 1,049

106 3,253

9,793

3,690 3,554 13 1,878 1,297 142

4,726

1,000 dollars

7,379

2,425 2,209 80 1,379 1,057 229

5,618

559

970

115

3,082

8,910

176 4,51/4

747 4,356

296

4 153

4,151 653

3,949

469

887 1,493

177 3,061

7,797

33 354

2,904 792

3,71A

884

pound

$0.70

.66 .62

6.15 .73 .81

1.61

1.19

1.59 1.54 1.54

8.25 2.31

.70 1.21

.94

1.88

1 Calculated from rounded figures.

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of the usual commercial concentration of the C.I. Sulfur dyes.

3 Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

Table 9 summarizes production and sales of dyes in 1965, by class of application. Six classes of dyes grouped by class of application accounted for more than four-fifths of all the dyes produced in 1965. Vat dyes accounted for 27.8 percent of the total; direct dyes, for 17.4 percent; acid dyes, for 9.8 percent; fluorescent brightening agents, for 9.4 percent; sulfur dyes, for 9.0 percent; and disperse dyes, for 7.5 percent. Of the above six classes, the output of disperse dyes was 18. 1 percent larger in 1965 than in 1964; that of fluorescent brightening agents, 16.5 percent larger; and that of both direct and acid dyes, 14. 6 percent larger.

Of the remaining classes, the output of mordant dyes was 4. 7 million pounds in 1965, or 33. 6 percent more than the 3. 6 million pounds in 1964. Production of fast color salts was 32. 7 percent larger in 1965 than in 1964; basic dyes, 15. 5 percent; solvent dyes, 15. 1 percent; and fast color bases, 12.0 percent. On the other hand, the output of fiber- reactive dyes was 3. 3 percent smaller in 1965 than in 1964, and that of azoic coupling components, 1.4 percent smaller.

Table 10 shows production and sales of dyes in 1965, by chemical class. In 1965, three chemical classes of dyes accounted for approximately two-thirds of all the dyes produced: Azo dyes accounted for 32. 1 percent of the total; anthraquinone dyes, for 23. 0 percent; and stilbene dyes, for 10. 3 percent. The output of each of these three classes was larger in 1965 than in 1964: Stilbene dyes were 15.4 percent larger; azo dyes, 14.9 percent larger; and anthraquinone dyes, 14.4 percent larger. Of the remaining chemical classes for which 1964 and 1965 statistics are published, production of most classes was larger in 1965 than in 1964. In terms of value of sales, the most important classes of dyes in 1965 were the azo dyes ($107. 1 million), the anthraquinone dyes ($72.7 million), the stilbene dyes ($33.0 million), and the triarylmethane dyes ($13. 3 million).

26

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 9*--Benzenoid dyes.- U.S. production and sales , by class of application, 1965

Class of application

Total

Acid

Azoic dyes and components:

Azoic compositions

Azoic diazo components, bases (Fast color bases)

Azoic diazo components, salts (Fast color salts)

Azoic coupling components (Naphthol AS and derivatives)

Basic

Direct

Disperse

Fiber-reactive

Fluorescent brightening agents

Food, drug, and cosmetic colors

Mordant

Solvent

Sulfur2

Vat

All other3

1,000 pounds 207,193

20,395

2,100

1,558

2,835

3,172

10,573

36,080

15,514

1,586

19,420

2,923

4,745

9,837

18,648

57,511

296

Quantity

1.000 pounds 189,965

18,666

2,043 1,310 2,646 2,429 9,553 33,663 13,522 1,558 18,284 2,736 4,246 8,930 17,471 52,439 469

1,000 dollars 292,284

39,025

3,968

2,057

2,683

4,669

23,907

50,970

32,878

6,744

34,516

10,238

5,706

15,351

9,960

48,728

884

Unit value1

pound $1.54

2.09

1.94 1.57 1.01 1.92 2.50 1.51 2.43 4.33 1.89 3.74 1.34 1.72 .57 .93 1.88

. I. Solubilized Sulfur dyes are reported in terms of

1 Calculated from rounded figures.

2 Production and sales quantities of C.I. Leuco Sulfur and the usual commercial concentration of the C.I. Sulfur dyes.

3 Includes oxidation bases, ingrain dyes, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

TABLE 10. — Benzenoid dyes.- U.S. production and sales, by chemical class, 1965

Chemical class

Unit value1

Total

Anthr aquinone - -

Azo, total

Monoazo

Disazo

Trisazo

Polyazo

Not specified

Azoic

Cyanine

Indigoid

Ketone imine —

Methine

Nitro

Oxazine

Phthalocyanine -

Quinoline

Stilbene

Sulfur2

Thiazole

Triarylmethane -

Xanthene

All other3

1,000 pounds 207,193

1,000 pounds 189,965

1,000 dollars 292,284

47,674

66,497

42,774

61,737

24,752

19,807

12,155

3,315

6,468

9,754 518

5,740 613

1,343 913 173

2,197

576

21,327

18,648

625

6,690

1,311 22,594

22,390

18,584

11,350

2,937

6,476

8,441

442 5,533

620 1,188

788

179 2,002

507 19,874 17,471

559 5,992

787 21,071

72,664 107,091

43,337 32,631 12,157 4,727 14,239

13,405 1,423 3,304 1,313 4,160 1,438 736 5,0pl 1,664

33,029 9,960 1,113

13,252 3,887

18,794

pound

$1.54

1.73

1.94 1.76 1.07 1.61 2.20

1.59 3.22 .60 2.12 3.50 1.82 4.11 2.52 3.28

2.21 4.94

Calculated from rounded figures.

2 Production and sales quantities of C.I. Leuco Sulfur and C.I. Solubilized Sulfur dyes are reported in terms of the usual commercial concentration of the C.I. Sulfur dyes.

3 Includes acridine, aminoketone, azine, coumarin, hydroxyketone , nitroso, oxidation bases, thiazine, vat sulfur, and miscellaneous dyes. Statistics for these groups of dyes may not be published separately because publication would disclose information received in confidence.

PIGMENTS 27

Pigments

As the terms are used in this report, synthetic organic pigments are toners and lakes derived in whole or in part from benzenoid chemicals and colors. They are used in paints and related products, in printing inks, and in plastics and resin materials.

Statistics on production and sales of all benzenoid pigments in 1965 are given in table 11A. Statistics on sales of a few selected pigments by commercial forms (dry full- strength form, dry extended form, dry dispersions, aqueous dispersions, and flushed colors) are given in table 12. Prior to 1961, statistics for toners included the quantities and values of extenders and diluents. Beginning in 1961, data were collected for both the full-strength and extended toners on a full-strength-toner-content basis. Individual toners and lakes are identified in this report by the names used in the second edition of the Colour Index.

Total production of benzenoid pigments in 1965 was 48. 0 million pounds--9. 1 percent more than the 44. 1 million pounds produced in 1964 and 21.9 percent more than the 39. 4 million pounds produced in 1963. Total sales of benzenoid pigments in 1965 amounted to 38.0 million pounds, valued at $93. 6 million, compared with 35. 1 million pounds, valued at $84. 1 million, in

1964 and 33. 5 million pounds, valued at $79. 6 million, in 1963. In terms of quantity, sales of benzenoid pigments in 1965 were 8.4 percent larger than in 1964 and 13.4 percent larger than in 1963; in terms of value, sales in 1965 were 11. 3 percent larger than in 1964 and 17. 6 percent larger than in 1963.

Production of toners in 1965 amounted to 43.7 million pounds--9.2 percent more than the 40.0 million pounds reported for 1964. Sales in 1965 were 34.1 million pounds, valued at $89.9 million, compared with 31.4 million pounds, valued at $80.9 million, in 1964. Sales in 1965 were thus 8.5 percent larger than those in 1964 in terms of quantity, and 11.1 percent larger in terms of value. The individual toners listed in the report which were produced in the largest quantities in 1965 were Pigment Blue 15, alpha form, 4.5 million pounds; Pigment Green 7, 4.3 million pounds; Pigment Yellow 12, 3.5 million pounds; Pigment Red 49, barium toner, 3.2 million pounds; Pigment Red 48, 2.6 million pounds; Pigment Blue 19, 2.5 million pounds; and Pigment Blue 15, beta form, 2.2 million pounds.

Production of lakes totaled 4.3 million pounds in 1965--8.0 percent more than the 4.0 mil- lion pounds reported for 1964. Sales of lakes in 1965 amounted to 3.9 million pounds, valued at $3.8 million, compared with sales in 1964 of 3.7 million pounds, valued at $3.3 million. Sales in

1965 were thus 7.3 percent larger than those in 1964 in terms of quantity, and 15.3 percent larger in terms of value. Pigment Blue 24, with an output of 2.2 million pounds, was the lake produced in largest quantity in 1965.

For each of 14 selected pigments, or groups of pigments, table 12 gives data on sales by commercial forms. Pigment Yellow 12, Pigment Red 90, and Pigment Blue 19 were sold prin- cipally in the flushed form. The remaining 11 pigments, or groups of pigments, for which statis- tics are published were sold principally in the dry full- strength form. Statistics on sales by commercial forms could not be published for Pigment Red 49, sodium toner, or for Pigment Blue 24 without revealing the operations of individual companies.

3 Sec also table 11B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, which shows imports of benzenoid pigments during the years 1964-G5.

28

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 11 A. --Benzenoid pigments: U.S. production and sales , 1965

[Listed below are all toners and lakes for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 11B in pt. Ill lists all toners and lakes for which data on production or sales were reported and identifies the manufacturer of each]

Pigment

Quantity

Grand total

TONERS Total

Yellow toners, total

Hansa yellows, total

Pigment Yellow 1, C.I. 11 680 —

Pigment Yellow 3, C.I. 11 710

Other Hansa yellows

Benzidine yellows, total

Pigment Yellow 12, C.I. 21 090

Pigment Yellow 13, C.I. 21 100

Pigment Yellow 14, C.I. 21 095

Pigment Yellow 17, C.I. 21 1£>5

Other benzidine yellows

All other

Orange toners, total

Pigment Orange 2, C.I. 12 060

Pigment Orange 5, C.I. 12 075

Pigment Orange 13, C.I. 21 110

Pigment Orange 16, C.I. 21 160

All other

Red and violet toners, total

Naphthol reds, total

Pigment Red 2, C.I. 12 310

Pigment Red 5, C.I. 12 490

Pigment Red 17, C.I. 12 390

Pigment Red IS, C.I. 12 350

Pigment Red 22, C.I. 12 315

Pigment Red 23, C.I. 12 355

Other naphthol reds

Pigment Red 1, C.I. 12 070, dark

Pigment Red 1, C.I. 12 070, light —

Pigment Red 3, C.I. 12 120 - -

Pigment Red 4, C.I. 12 085 -

Pigment Red 6, C.I. 12 090

Pigment Red 38, C.I. 21 120-

Pigment Red 48, C.I. 15 865

Pigment Red 49, C.I. 15 630:

Barium toner

Calcium toner

Sodium toner ,

Pigment Red 52, C.I. 15 860

Pigment Red 53, C.I. 15 585, barium toner- Pigment Red 54, C.I. 14 830, calcium toner- Pigment Red 57, C.I. 15 850, calcium toner- Pigment Red 63, C.I. 15 880

Pigment Red 81, C.I. 45 160, PMA

Pigment Red 81, C.I. 45 160, PTA

Pigment Red 90, C.I. 45 380

Pigment Violet 1, C.I. 45 170, PMA

Pigment Violet 1, C.I. 45 170, PTA

Pigment Violet 3, C.I. 42 535, fugitive

Pigment Violet 3, C.I. 42 535, PMA

Pigment Violet 3, C.I. 42 535, PTA

All other

1,000 pounds 48,045

6,935

1,208 590 170 448

5,509

3,541 316

1,204 223 225 218

860

247 172 212 229

770

94

100

63

12

115

104

282

210

192

1,593

388

73

157

2,627

3,223

1,544

241

1,181

1,924

69

965

323

166

1,291

78

44

432

429

40

2,594

1,000 pounds 38,024

1,000 dollars 93,635

34,105

4,523

386

85

397

3,515

2,063

177

942

152

181

140

700

185

160 181 135

16,720

601 54

97 109 221 152 162 1,250 251

127 2,231

2,941

1,384

268

1,008

1,590

52

853

38

223

133

667

385

378

36

1,870

12,737

2,316

728

196

1,392

8,730

4,503

566

2,184

526

951

1,691

2,745

55

290

520

536

1,344

38,883

2,759. 165 324 172

291 416

1,391 189 199

1,915 351

576 4,068

2,870 1,413

272 1,307 2,038

115

1,272

71

1,359

835 1,239

227

264

578 1,096

147 13,723

See footnotes at end of table.

PIGMENTS

29

TABLE HA. --Benzenoid pigments; U.S. production and sales , 1965 — Continued

Pigment

Unit value1

TON ERS- - Cont inued

Blue toners, total

Pigment Blue 1, C.I. 42 595, PMA

Pigment Blue 1, C.I. 42 595, PTA-

Pigment Blue 2, C.I. 44 045, fugitive, PMA, and PTA-

Pigment Blue 9, C.I. 42 025, PTA

Pigment Blue IA, C.I. 42 600, PMA

Pigment Blue 15, C.I. 74 160, alpha form

Pigment Blue 15, C.I. 74 160, beta form

Pigment Blue 19, C.I. 42 750A

Pigment Blue 22, C.I. 69 810

All other

Green toners, total

Pigment Green 1, C.I. 42 040, PMA

Pigment Green 1, C.I. 42 040, PTA

Pigment Green 2, C.I. 42 040 and 49 005, PMA

Pigment Green 2, C.I. 42 040 and 49 005, PTA

Pigment Green 4, C.I. 42 000, PMA

Pigment Green 4, C.I. 42 000, PTA

Pigment Green 7, C.I. 74 260

Pigment Green 8, C.I. ID 006

All other

Brown toners, total

Pigment Brown 5, C.I. 15 800

All other

Black toners

LAKES

Total- -

Red lakes, total

Pigment Red 60, C.I. 16 105- -

Pigment Red 83, C.I. 58 000

(Acid Red 26), C.I. 16 150

All other

Violet lakes, total

Pigment Violet 5, C.I. 58 055—

All other

Blue lakes, total

Pigment Blue 24, C.I. 42 090

All other

Black lakes: (Natural Black 3), C.I. 75 291

All other lakes2

1,000

pounds

9,997

T7D"

31

18

9

70

4,538

2,239

2,546

376

55

41

7

7

4,252

184

337

164

220

83

623

2,214

2,183

67

853

1,000 pounds

8,239

T50" 22

66

3,464

1,797

2,450

17

240

3,557

2,965 143 333

3,919

958

~178~

70

625

85

1,960

1,928

1,000 dollars 23,603

"750"

123

46

55

522

9,497

5,390

5,661

343

1,216

11,369

249 212

9,270

190

1,301

157 123

1,067

272 248 286 261

1,872

1,852

$2.86

"4T69" 5.59 3.29 6.11 7.91 2.74 3.00 2.31

20.18 5.07

3.20

5.00 5.62 4.88 6.24 4.33 3.50 3.13 1.33 3.91

1.94 4.39

1.11

1.53 3.54

.46 3.07

2.1A

1 Calculated from rounded figures.

2 Includes all brown, green, orange, and yellow lakes, "all other" black lakes, and sales of Natural Black 3.

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edition of the Colour Index.

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic ( including phosphotungstomolybdic) acids, respectively.

30 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 12 — U.S. sales of selected dry full-strength colors, dry extended colors, dry dispersions, aqueous

dispersions, and flushed colors, 1965

Selected pigments by commercial forms

Pigment Yellow 12, C.I. 21 090, total

Dry full-strength toner

Dry extended toner, aqueous dispersions3 and flushed color

Pigment Yellow 13, C.I. 21 100; Pigment Yellow 14, C.I. 21 095; Pigment

Yellow 17, C.I. 21 105; and other benzidine yellows, total

Dry full-strength toner

Dry extended toner and dry dispersions4

Aqueous dispersions3

Flushed color

Pigment Red 3, C.I. 12 120, total

Dry full-strength toner and dry extended toner4

Aqueous dispersions3

Flushed color

Pigment Red 48, C.I. 15 865, total

Dry full-strength toner

Dry extended toner

Dry dispersions and aqueous dispersions Flushed color

Pigment Red 49, C.I. 15 630, barium toner, total -

Dry full-strength toner --- —

Dry extended toner and aqueous dispersions Flushed color

Pigment Red 49, C.I. 15 630, calcium toner, total- Dry full-strength toner and dry dispersions4

Aqueous dispersions3 and flushed color4

Pigment Red 49, C.I. 15 630, sodium toner4

Pigment Red 53, C.I. 15 585, barium toner, total

Dry full-strength toner, dry extended toner, and dry dispersions4 Aqueous dispersions3 and flushed color4

Pigment Red 90, C.I. 45 380, total --

Dry full-strength toner and dry extended toner4- Dry dispersions and flushed color4

Pigment Violet 3, C.I. 42 535, fugitive, . total— - Dry full-strength toner and dry extended toner Flushed color

Pigment Violet 3, C.I. 42 535, permanent (PMA and PTA), total -

Dry full-strength toner

Dry extended toner, dry dispersions and aqueous dispersions Flushed color

Pigment Blue 15, C.I. 74 160, alpha form, total -

Dry full-strength toner

Dry extended toner

Dry dispersions

Aqueous dispersions3

Flushed color

Pigment Blue 15, C.I. 74 160, beta form, total

Dry full-strength toner r-

Dry extended toner, dry dispersions and flushed eolor4- Aqueous dispersions

Pigment Blue 19, C.I. 42 750A, total

Dry full-strength toner and dry extended toner4 Aqueous dispersions3 and flushed color4

See footnotes at end of table.

Qjantity1

1,000 pounds 2,063

608 1,455

1,007

237 163

1,250

740

65

445

2,062

41

2,070

10

861

1,384

1,110 274

1,590

936 654

275 110

222 78 114

3,464

2,036

497

34

721

176

1,797

883 513 401

2,450

207 2,243

1.000 dollars

4,734

1,315 3,419

4,302

3,093 107 596 506

1,986

1,126

108 752

4,083

3,756 83

144 100

2,981

2,019

1,556

1,131 425

1,201 905

1,324

87 1,237

418 162

693 226 338

9,630

5,498 1,618

153 1,892

469

5,392

2,760 1,564 1,068

471 5,190

MEDICINAL CHEMICALS

TABLE 12. --U.S. sales of selected dry full-strength colors, dry extended colors , dry dispersions, aqueous dispersions , and flushed colors, 1965 — Continued

Selected pigments by commercial forms

Quantity1

Unit value2

Pigment Blue 24, C.I. 42 090*

Pigment Green 7, C.I. 74 260, total -

Dry full-strength toner

Dry extended toner

Dry dispersions

Aqueous dispersions3

Flushed color

pounds 1,928

2,965

pound

2,392 9,341

$1.24 3.15

1,345

244

67

985

324

4,314 903 279

2,892 953

3.21 3.70 4.16 2.94 2.94

1 Quantity of the various commercial forms is given in terms of dry full-strength toner (or dry lake) content.

2 Calculated from rounded figures.

3 Includes presscake.

* Separate data on these commercial forms may not be published without revealing the operations of individual com- panies.

Note. —The C.I. (Colour Index) numbers shown in this report are the identifying numbers given in the second edi- tion Of the Colour Index.

The abbreviations FMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic ) acids, respectively.

Medicinal Chemicals

Medicinal chemicals include the medicinal and feed grades of all organic chemicals having therapeutic value, whether obtained by chemical synthesis, by fermentation, by extraction from naturally occurring plant or animal substances, or by refining the technical grade material. They include alkaloids, antibiotics and other anti-infective agents, antihistamines, autonomic drugs, central-nervous-system depressants and stimulants, hormones, vitamins, and other therapeutic agents for human or veterinary use and for animal feed supplements. Statistics on the production of medicinal chemicals are in terms of 100-percent content of the medicinal chemical itself, ex- clusive of all diluents or other materials used in mixing or compounding tablets, solutions, and suspensions for consumer use. Sales include that part of the original production that was sold in bulk and exclude all dosage-form products and other finished pharmaceutical preparations.

Statistics on U.S. production and sales of medicinal chemicals in 1965 are given in table 13A.* Total production of medicinal chemicals in 1965 amounted to 160 million pounds, or 10.7 percent more than the 144 million pounds produced in 1964, and 14.6 percent more than the 139 million pounds produced in 1963. Total sales of medicinal chemicals in 1965 amounted to 129 million pounds, valued at $362 million. These figures represent sales of bulk medicinal chemi- cals only and therefore cannot be compared with sales data for earlier years, which included all antibiotics sold by the primary producers, whether they were sold as medicinal preparations or as bulk materials. Sales of medicinal chemicals in 1965, exclusive of antibiotics, amounted to 125 million pounds, valued at $269 million, compared with sales in 1964 of 113 million pounds, valued at $260 million, and sales in 1963 of 108 million pounds, valued at $251 million. Sales in 1965 of medicinal chemicals other than antibiotics were thus 10.6 percent larger than in 1964 and 15.3 percent larger than in 1963, in terms of quantity, and 3.4 percent larger than in 1964 and 7.1 percent larger than in 1963, in terms of value.

Production of the more important groups of medicinal chemicals in 1965 was as follows: Antibiotics, 7.5 million pounds (14.0 percent larger than in 1964), of which 4.7 million pounds was for medicinal use and 2.8 million pounds was for other uses; anti-infective agents other than an- tibiotics, 27.5 million pounds (5.9 percent larger thanin 1964); central depressants and stimulants, 42.8 million pounds (5.4 percent larger); and vitamins, 16.3 million pounds (15.5 percent larger). Production of some of the more important individual products listed in the report was as follows: Aspirin, 29.1 million pounds (3.1 percent larger than in 1964); salicylic acid, 9.9 million pounds (24.8 percent smaller than in 1964); choline chloride, 31.1 million pounds (23.6 percent larger); methionine and its hydroxy analogue, 10.4 million pounds (72.0 percent larger); ascorbic acid, 7.3 million pounds (19.6 percent larger); piperazine base and salts, 6.5 million pounds (6.3 per- cent smaller); anti-infective sulfonamides, 4.7 million pounds (4.8 percent smaller); vitamin A alcohol and esters, 598 trillion units (3.1 percent smaller); penicillins, 1,343 trillion units (11.7 percent larger); and tetracyclines, 1,157 million grams of antibiotic base.

See also table 13B. pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix which shows imports of coal-tar medicinal chemicals and pharmaceuticals during the years l°64-65.

32

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 13A. --Medicinal chemicals.- U.S. production and sales , 19651

[Listed below are all synthetic organic medicinal chemicals for which any reported data on production or sales may be published. I Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 13B in pt. Ill lists alphabetically all medicinal chemicals for which data on produc- tion or sales were reported and identifies the manufacturer of each]

Quantity

Grand total

Acyclic

Benzenoid3

Cyclic nonbenzenoid^

Antibiotics, total5

For medicinal use, total

Antifungal and antitubercular antibiotics, total

Streptomycin

All other

Bacitracin

Penicillins, total

Penicillin G, potassium

Penicillin G, procaine

All other

All other antibiotics for medicinal use

For other uses, total

Bacitracin

Penicillin G, procaine

All other

Antihistamines, total

Antinauseants

Chlorpheniramine maleate

Pheniramine maleate

Pyrilamine maleate

All other

Anti-infective agents (except antibiotics), total

Antimony, arsenic, and bismuth compounds

Cetylpyridinium chloride

Mercury compounds

5-Nitrofurane, -imidazole, and -thiazole derivatives

Phenolic antiseptics and disinfectants

Piperazine base and salts, total

Piperazine

All other

Quinoline derivatives, total

Diiodohydroxyquin

All other

Sulfonamides, total

Sulfathiazole

All other

Other anti-infective agents, total

Anthelmintic, antifungal, antiprotozoan, and antiviral

agents

Urinary antiseptics

All other

Antineoplastic agents and local anesthetics

Autonomic drugs, total

Parasympatholytic (anticholinergic) agents: Quaternary ammonium compounds (except tropane

derivatives)

Tertiary amines (except tropane derivatives)

Sympathomimetic (adrenergic) agents, total

Epinephrine salts

Isoproterenol salts

Phenylephrine base and salts, total

Phenylephrine hydrochloride

All other

1,000 pounds 159,520

59,480 84,678 15,362 7,455

4,656

1,134

470

664

7

1,749

530

798

421

1,766

2,799

127

707

1,965

380

17 268

27,493

3,035

31

35

502

279

6,513

2,891

3,622

536

19

517

4,728

117

4,611

11,834

696 2,458

2,189

436

(6)

1,000 pounds 129,048

1,000 dollars 362,169

56,569 60,977 11,502 4,

2,397

846

389

457

7

328

1,134

1,689

132

1,557

182 16,887

27

239 4,455

712 3,743

152

152

1,343

72

1,271

10,644

7,729

573

2,342

1,522

302

I6)

41,011

224,159

96,999

93,593

53,713 11,023 3,539 7,484 897

3,343

5,996 32,454 39,880

2,943

36,937

4,745

257 299

4,189 67,581

82 348

428 3,507

789 2,718

495

495

6,265

186

6,079

56,456

46,718

997

8,741

1,724

5,791

810 1,031 3,603

1,767

1,547

220

See footnotes at end of table.

MEDICINAL CHEMICALS TABLE 13A. —Medicinal chemicals.- U.S. production and sales, 19651 --Continued

33

Quantity

Autonomic drugs — Continued

Sympathomimetic (adrenergic) agents — Continued

Phenylpropanolamine hydrochloride

All other

All other autonomic drugs

Cardiovascular agents, total

Vasodilators

All other

Central depressants, total

Analgesics and antipyretics, total

Salicylates, total

Aspirin

All other

All other analgesics and antipyretics

Anticonvulsants, hypnotics, and sedatives, total

Barbiturates, total

Butabarbital

Butabarbital, sodium

Phenobarbital, sodium

All other

All other anticonvulsants, hypnotics, and sedatives7 —

Skeletal muscle relaxants, total

Mephenesin

Succinylcholine chloride

All other

Tranquilizers, total

Meprobamate

Phenothiazine derivatives

All other7

Other central depressants, total8

Ethyl-aorphine hydrochloride

All o^her

Central stimulants, total

Amphetamines, total

Amphetamine, dextroamphetamine and levamphet amine base

and salts, total

Dextroamphetamine sulfate

All other

Methamphetamine base and hydrochloride, total

Methamphetnnri ne (racemic)

Methamphetamine hydrochloride (dextro)

All other

Antidepressants

Caffeine (natural and synthetic)

Other central stimulants

Dermatological agents, total

Allantoin

Bismuth subgallate

Salicylic acid

Other dermatological agents

Expectorants and mucolytic agents

Gastrointestinal agents, total

Choleretics and hydrocholeretics

Choline chloride (all grades)

Methionine and its hydroxy analogue

Other gastrointestinal agents

Hormones and synthetic substitutes, total

Corticosteroids, total

Hydrocortisone

1,000 pounds

39,904

36,320

32,355

29,089

3,266

3,965

1,759

971

31

42

9

889

788

223

162 1,548 1,179

369 54

105 38

2,662 11,255

32 9,866 1,335

1,021

43,183

143

31,146

10,402

1,492

1,381

1,000 pounds

392

34,998

32,859 29,091 26,169 2,922 3,768

527

169 1,361 1,272

(9)

2,938

2,741 101

6,812

5,579 1,233

1,022 44,627

32,459

10,658

1,510

1,000 dollars 1,233 552 347

11,731

11,731 34,739

21,726 17,165 14,380 2,785 4,561

2,128 289

1,839 899

899 5,237 3,344

762

1,131

4,749

82

4,667

10,169

753

471

471 282

5,036 4,380

3,286

2,177 1,109

1,613 19,084

5,423 10,368 3,293

26,893

21,713 2,109

See footnotes at end of table.

34

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 13A. — Medicinal chemicals; U.S. production and sales , 19651 Continued

Quantity

Unit value 2

Hormones and synthetic substitutes—Continued Corticosteroids-- Continued

All other

Estrogens

Synthetic hypoglycemic agents

Other hormones and synthetic substitutes

Renal-acting and edema-reducing agents, total

Mercurial diuretics

Theobromine and theophylline derivatives, total-

Aminophylline

All other

Other renal-acting and edema-reducing agents

Therapeutic nutrients, total

Amino acids and salts, total

Glutamic acid

All other

Calcium gluconate

Other therapeutic nutrients

Vitamins, total

Ascorbic acid and derivatives, total

Ascorbic acid

All other

B-complex vitamins:

Cyanocobalamin (all grades)10

Niacin (all grades)

Niacinamide

Pantothenic acid and derivatives, total

Calcium pantothenate (racemic) (all grades)-

All other

Riboflavin (all grades)

Cholecalciferol (Vitamin D3) 10

Ergocalciferol (Vitamin D2) 10

Menadione

Menadione sodium bisulfite

Vitamin A alcohol and esters, total10

Vitamin A palmitate (feed grade)

All other

Other vitamins

Miscellaneous medicinal chemicals, total11

Anticoagulants

All other

1,000 pounds

27 1,139

205

1,284

101

1,174 3,203

1,927

75

1,852

656

620

16,297

8,629 7,274 1,355

1,828

889

1,610

1,252

358

958

59

77

677

464

213

1,569

463

10 453

1,000 pounds

38

20

337

1,000

dollars

19,604

688

1,189

3,303

7,913

2,374

1,334 56

1,278 524 516

12,028

6,089 4,903 1,186

1,461

858

1,310

1,055

255

599

2

73

613

419

194

1,021

261

28 262

262 7,623

2,842

1,879 345 529

65,366

11,978 9,349 2,629

8,324 1,812 1,754 2,967 1,780 1,187 6,214 520 180

578 17,249 8,642 8,607 13,790

5,099

775 4,324

Per

pound

$515.89

34.40

3.53

1,101.00

42.77

28.00 2.47

2.47 97.73

TT48"

,324.00

1.24

2.04

2.26

1.69

4.65

10.37

260.00

180.00

7.92 28.14 20.63 44.37 13.51

19.54

155.00 16.89

1 The data on production and sales are for bulk medicinal chemicals; they exclude finished preparations and dosage- form products which are manufactured from bulk chemicals. All quantities are given in terms of 100$ active ingredient.

2 Calculated from rounded figures.

3 The term "benzenoid," as used in this report, describes any cyclic medicinal chemical whose molecules contain either a 6-membered carbocyclic ring with conjugated double bonds (e.g., the benzene ring or the quinone ring) or a 6-membered heterocyclic ring with 1 or 2 hetero atoms and conjugated double bonds, except the pyrimidine ring (e.g., the pyridine ring or the pyrazine ring) .

** Includes antibiotics of unknown structure.

MEDICINAL CHEMICALS

35

Footnotes for table 13A — Continued

5 All quantities for antibiotics were reported in terms of grams of antibiotic base or U.S. P. units, but are shown in the table in pounds. Statistics for all individually publishable antibiotics are shown below in terms of kilograms of antibiotic base (Kg.) or billions of U.S. P. units (BU):

Quantity

Bacitracin (BU), total

For medicinal use

For other uses

Neomycin (Kg.), for all uses

Penicillins (BU), total

Penicillin G, potassium, for medicinal use- Penicillin G, procaine, total

For medicinal use

For other uses

Other penicillins, for medicinal use

Streptomycin (Kg.), for medicinal use

Tetracyclines (Kg.), for all uses

3,054

169 2,885

76,332 1,343,126

383,402 689,433 365,587 323,846 270,291

213,242 1,156,705

3,159

169 2,990

31,783 773,372

236,822 482,669

53,881

176,398 472,551

1.000 dollars 3,840

897 2,943

1,831 16,444

3,343 7,105

3,539 29,089

$1,215.57

5,307.69 984.28

14.12 14.72

20.06 61.56

6 Production of epinephrine salts amounted to 374 pounds; sales amounted to 370 pounds.

7 Includes 2 or more of the following 6 drugs which are subject to Federal control under the Drug Abuse Control Act: Chlordiazepoxide hydrochloride, diazepam, ethchlorvynol, ethinamate, glutethimide, and methyprylon. U.S. pro- duction of these 6 drugs amounted to 524 thousand pounds in 1965.

8 Includes production and sales of anesthetics and antitussives; also includes sales of "all other" anticonvul- sants, hypnotics, and sedatives.

9 Sales of ethylmorphine hydrochloride amounted to 450 pounds.

10 The following tabulation shows statistics for vitamins A, Bi2, D2, and D3 in terms of kilograms (Kg.) or bil- lions of U.S. P. units (BU):

Production

Sales

Quantity

Value

Unit value

Cholecalciferol (Vitamin D3) (BU)

20,552 598,264

29,676

660

16,233

541,147

1,000 dollars

520

8,324

180

17,249

$17.52

12,612.12

11.09

31.62

Ergocalciferol (Vitamin D2) (BU)

Vitamin A alcohol and esters (BU), total

382,665 215,599

345,165 195,982

8,642 8,607

25.04 42.96

Includes diagnostic agents, hematological agents, smooth-muscle relaxants, and miscellaneous unclassified me- dicinal chemicals.

36

SYNTHETIC ORGANIC CHEMICALS, 1965

Flavor and Perfume Materials

Flavor and perfume materials are organic chemicals used in the manufacture of foods, beverages, cosmetics, and soaps. Aromatic organic chemicals are utilized to neutralize or to mask unpleasant odors in industrial processes and products as well as in consumer products. Most of them have desirable flavors or odors, and some have the ability to enhance natural flavors when added to certain foods. This report includes data on materials derived from natural products by actual chemical processes and from coal tar; it does not include data on purely natural products, such as floral essences, essential oils, and other materials that are obtained by simple extraction or by distillation from natural plant and animal sources.

The flavor and perfume materials covered in this report are grouped as either cyclic or acyclic materials, according to their chemical structure. Cyclic materials are further classified as (1) benzenoid and naphthalenoid, and (2) terpenoid, heterocyclic, and alicyclic. Statistics on production and sales of flavor and perfume materials in 1965 are given in table 14A.5

Production of flavor and perfume materials in 1965 amounted to 99.2 million pounds--9.6 percent more than the output of 90.6 million pounds in 1964. Sales in 1965 amounted to 87.7 million pounds, valued at $85.0 million, compared with 80.0 million pounds, valued at $83.7 million, in 1964.

Production of cyclic flavor and perfume materials in 1965 amounted to 53.2 million pounds-- 7.4 percent more than the 49.6 million pounds reported for 1964. Sales of cyclic flavor and per- fume materials in 1965 were 44.6 million pounds, valued at $56.8 million, compared with 41.2 million pounds, valued at $56.6 million, in 1964. The individual chemical in the cyclic group that was produced in the greatest volume in 1965 was methyl salicylate (4.7 million pounds). In 1965, production of synthetic sweeteners, as a group, amounted to 12.8 million pounds, representing an increase of only 5.1 percent over production in 1964, compared with an increase in 1964 of 113.7 percent over production in 1963.

The output of acyclic flavor and perfume materials in 1965 amounted to 46.0 million pounds-- 12.2 percent more than the 41.0 million pounds reported for 1964. By far the most important of the acyclic materials in 1965 was monosodium glutamate, a flavor- enhancing chemical, produc- tion of which totaled 43.1 million pounds. Sales of acyclic flavor and perfume materials in 1965 amounted to 43.1 million pounds, valued at $28.2 million, compared with 38.8 million pounds, valued at $27.2 million, in 1964.

TABLE 14A. — Flavor and perfume materials: U.S. production and sales , 1965

[Listed below are all synthetic organic flavor and perfume materials for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be pub- lished or where no data were reported.) Table 1AB in pt. Ill lists alphabetically all flavor and perfume materials for which data on production or sales were reported and identifies the manufacturer of each]

Production

Quantity

Unit value1

Grand total-

99,224

87,703

1,000 dollars 84, 980

Pur pound

$0.96

FLAVOR AND PERFUME MATERIALS, CYCLIC

53,223

44,559

56,800

id and Naphthale

Total-

24,087

22,365

25,307

1.13

4-Allylveratrole (Eugenyl methyl ether) -

Anethole ( p-Propenylanisole)

p-Anisaldehyde ( p-Methoxybenzaldehyde) --

Benzophenone2

Benzyl acetate

Benzyl alcohol2

Benzyl cinnamate

Benzyl propionate

Benzyl salicylate

Cinnamaldehyde

Cinnamyl alcohol

1,904

963

179

1,324

3,955

13 190 908 184

8

22

1,489

1,053

922

1,292

122

122

1,325

534

3,725

1,399

4

U

12

13

182

234

893

633

161

225

2.97

.71

1.40

1.00

.40

.38

3.78

1.11

1.29

.71

1.40

See footnotes at end of table.

5 See also table 14B, pt. Ill, which lists these products alphabetically and identifies the manufacturers, and table 23 in the appendix, which shows imports of benzenoid flavor and perfume materials during the years 1964-65.

FLAVOR AND PERFUME MATERIALS

37

TABLE 14A. -- Flavor and perfume materials; U.S. production and sales , i365--Continued

FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued

Benzenoid and Naphthalenoid— Continued

Eugenol

Isobutyl phenylaoetate (Isobutyl a-toluate)

Isobutyl salicylate

Isoeugenol

Isopentyl salicylate (Amyl salicylate)

p-Isopropyl-a-methylhydrocinnamaldehyde (Cyclamen aldehyde)

Methyl anthranilate

a-Methylcinnamaldehyde

Methyl cinnamate

Methyl salicylate (Synthetic wintergreen oil)

a-Pentylcinnamaldehyde (a-Amylcinnamaldehyde)

Phenethyl acetate

Phenethyl isobutyrate

Phenethyl phenylacetate (Phenethyl a-toluate)

3-Phenyl-l-propanol (Hydrocinnamic alcohol)

All other benzenoid and naphthalenoid materials

Terpenoid, Heterocyclic, and Alicyclic Total

Cedryl acetate

Citral (Geranial)

Citronellol

Citronellyl acetate

Citronellyl formate

Coumarin

Essential oils, chemically modified

Geraniol

Geranyl acetate

Hydroxycitronellal

Ionones

Isobornyl acetate

Menthol, synthetic, tech. and U.S.P

Methylionones

Nerol

Piperonal (Heliotropin)

Rhodinol

Sweeteners, synthetic

Terpineols

Terpinyl acetate

Vetivenyl acetate

All other terpenoid, heterocyclic, and alicyclic materials-

FLAVOR AND PERFUME MATERIALS, ACYCLIC

Total

Allyl hexanoate (Allyl caproate)

Ethyl butyrate

Ethyl nonanoate (Ethyl pelargonate)

Glutamic acid, monosodium salt (Monosodium glutamate)

Isopentyl butyrate (Amyl butyrate)

Isopentyl formate (Amyl formate)

Lauraldehyde (Dodecyl aldehyde) (C12)

All other acyclic materials

1 Calculated from the unrounded figures.

2 Includes some technical grade.

Production

1,000 pounds

4,675 527

8,235

29,136

46,001

57 248

43,121 45

2,528

Quantity

1,000

1,000

pounds

dollars

350

620

17

17

54

49

107

302

409

295

184

512

177

323

11

21

64

126

4,121

1,850

451

624

73

74

6

14

12

39

18

33

7,468

W,867

22,194

125

122

252

171

80

286

555

460

737

29

29

51

25

21

53

1,016

963

2,157

146

136

152

634

602

828

76

67

117

454

386

1,553

262

248

830

942

910

346

381

384

1,357

446

444

1,790

25

15

76

256

272

574

12

11

312

12,841

10,133

8,971

3,418

3,105

920

586

578

329

33

25

565

6,703

3,203

9,237

43,144

58

294

40,366 58

19 2,345

31,493

28,180

216

201

7

25,530

46

2

105

2,073

38

SYNTHETIC ORGANIC CHEMICALS. 1965

Plastics and Resin Materials

Plastics and resin materials are condensation or polymerization products of organic chemi- cals containing necessary fillers, plasticizers, and extenders. At some stage in their manufac- ture they exist in such physical condition that they can be shaped or processed by the application of heat and pressure. Some types of plastics may be molded, cast, or extruded into finished or semifinished forms. Other types are used as adhesives, for the treatment of textiles and paper, and for protective coatings. Still other types of plastics materials may be processed into sheets, rods, and tubes, which are further manufactured into finished articles. Except for vinyl resins, the statistics given in the following tables are based on the total weight of the materials, exclud- ing liquids. Statistics for vinyl resins are given on the basis of resin content.

Statistics on production and sales of plastics and resins in 1965 are given in table 15A6 according to chemical composition and broad end uses. In general, this table follows the outline

TABLE 15A, — Plastics and resin materials ; U.S. production and sales, by chemical classes

and uses, 1965

[Quantities and values are given in terms of the total weight of the materials (dry basis). Listed below are all plastics and resin materials for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 15B in pt. Ill lists all plastics and resin materials for which data on production or sales were reported and identifies the manufacturer of each]

Kind and use

Quantity

Unit value1

Grand total

Plastics and resin materials, benzenoid

Plastics and resin materials, nonbenzenoid

THERMOSETTING RESINS

Total

Alkyd resins, total

Protective coatings:

Phthalic anhydride type, total

Unmodified

Modified

Polybasic acid type

All other uses3

Sales for export

Coumarone-indene and petroleum polymer resins, total- Floor tile

Rubber compounding

All other uses

Sales for export

Epoxy resins:

Unmodified, total

Bonding and adhesives

Protective coatings

Reinforced plastics

All other uses

Sales for export

Modified

Polyester resins,* total

Reinforced plastics:

Sheets, flat and corrugated

All other

Surface coatings

All other uses

Sales for export

1,000 pounds,

11, 684-, 875

4,452,975 7,231,900

3,236,701

639,577

562,618

412,648

149,970

59,365

17,594

324,309

84,727

65,631

173,951

110,663

8,559 398,884

1,000 pounds,

10,052,766

1,000 dollars 2,504,433

3,689,722 6,363,044

2,550,863

873,501 1,630,932

662,392

334,856

88,679

273,148

207,438

65,710

46,701

9,407

5,600

309,494

74,289

63,271

144,623

27,311

105,681 10,124 48,080 17,499 19,224 10,754 2,935

343,605

73,167 54,578 18,589 10,282 3,536 1,694

30,569

58,180

3,390 99,331

32,841

219,725

6,500

75,641

pound

.24 .26

See footnotes at end of table.

6 See also table 15B, pt. Ill, which lists these products according to chemical composition, and identifies the manufacturers.

PLASTICS AND RESIN MATERIALS

TABLE 15A.-- Plastics and resin materials .- U.S. production and sales, by chemical classes and uses, i 965- -Continued

39

Kind and use

THERMOSETTING RESINS— Continued

Phenolic and other tar acid resins, total

Molding materials

Bonding and adhesive resins for—

Laminating

Coated and bonded abrasives

Friction materials

Thermal insulation

Foundry or shell molding

Plywood

Fibrous and granulated wood

All other bonding and adhesive uses

Protective coatings, unmodified and modified--

All other uses

Sales for export

Polyurethane and diisocyanate resins

Rosin modifications, total

Rosin and rosin esters, unmodified (ester gums All other

Urea and melamine resins, total

Textile treating and coating resins

Paper treating and coating resins

Bonding and adhesive resins for —

Laminating

Plywood

Fibrous and granulated wood

All other bonding and adhesive uses

Protective coatings

All other uses (including molding)

Sales for export

All other thermosetting resins6

THERMOPLASTIC RESINS

Total

Cellulose plastics materials, total

Sheets , continuous :

Under 0.003 gage

0.003 gage and over

All other sheets, rods, and tubes

Molding and extrusion materials

Polyamide resins, total '

Nylon type

Non-nylon type

Styrene-type plastics materials:

Production and sales

Used by reporting companies in processing

Sales and use, total

Molding

Textile and paper treating and coating

Emulsion paint

Extrusion

All other uses

Sales for export

Vinyl resins (resin-content basis): Polyvinyl acetate resins:

Production and sales

Used by reporting companies in processing —

See footnotes at end of table.

921,753

274,193

132,732 27,024 32,623

120,626 68,782

117,832 31,815 32,176 34, 8H 49,136

66,209 102,962

Quantity

62,279 40,683

621,179

65,703 50,758

51,764

135,125

117,102

15,138

58,515

127,074

42,606

8,448,174

169,476

24,104

38,342

8,316

98,714

92,076

73,415 18,661

2,033,147

313,160

1,000 pounds,

dry basis'

744,657

246,140

79,109 22,013 28,102 52,576 66,651 110,589 28,051 28,580 24,678 44,164 14,004

55,443

101,249

1,000 dollars 178,799

61,735 39,514

517,698

31,226 20,115

59,571 34,698

34,686 115,162 103,054

15,306

35,373 103,103

16,745

35,245

7,501,903

163,095

24,350

35,945

8,921

93,879

73,383

55,916 17,467

1,836,246

184,245

2,020,491

1,063,005

153,169

43,062

310,986

325,843

124,426

220,354 62,923

11,321 8,794

129,227

Unit value1

pound

22,876

1,842,041

107,825

65,376 54,884 10,492

383,318

67,974

TABLE 15A.--Plastics and resin materials.- U.S. production and sales, by chemical classes and uses, 1965 — Continued

Kind and use

THERMOPLASTIC RES INS --Continued

Vinyl resins (resin-content basis) — Continued Polyvinyl acetate resins — Continued

Sales and use, total

Emulsion paint

Adhesives

Bonding and sizing

All other uses

Sales for export

Polyvinyl chloride and copolymer resins:

Production and sales

Used by reporting companies in processing

Sales and use, total

Calendering:

Film, under 6 mils

Sheet, 6 mils and over

Flooring

Coating, bonding, and adhesives:

Paper and textile coating (including calendering)-

Flooring

Extrusion:

Wire and cable

Garden hose

All other extrusions

Molding:

Records

Slush and rotational molding

All other moldings

All other uses

Sales for export

All other vinyl resins: Production and sales

Polyolefin plastics materials:

Polyethylene, density 0.940 and below:

Production and sales

Used by reporting companies in processing

Sales and use, total

Injection molding

Blow molding

Extrusions:

Film and sheet

Wire and cable coating

Extrusion coating on paper and other substrates —

Pipe

All other extrusions

All other uses

Sales for export

Polyethylene, density over 0.940:

Production and sales

Used by reporting companies in processing

Sales and use, total

Injection molding

Blow molding

Extrusions:

Film and sheet

Wire and cable coating

Pipe

All other extrusions (including extrusion coating

and filament)

All other uses

Sales for export

1,837,467

161,659

Quantity

1,000 pounds ,

basis- 283,277 104,641 111,064 19,856 45,074 2,642

1,715,321

140,337

1,855,658

83,626

250,374 262,282

180,884 68,507

217,214 11,367 254,781

89,552 43,070 30,993 294,913 68,095 9 154,936

262,922

2,046,006

236,885

2,282,891

291,091

40,468

938,193

215,946

282,610

19,381

12,282

179,326

303,594

784,441

649,084

90,835

739,919

130,111

272,769

37,539

22,600

29,759

26,302

133,254

87,585

1,000 dollars

Unit value

$0.17

78,915

344,431

119,861

See footnotes at end of table.

PLASTICS AND RESIN MATERIALS

TABLE 15A. — Plastics and resin materials; U.S. production and sales, by chemical class and uses, 1 965- -Continued

Kind and use

Quantity

Unit value1

THERMOPLASTIC RESINS— Continued

Polyolefin plasties materials — Continued Polypropylene :

Production and sales

Used by reporting companies in processing —

Sales and use, total

Molding

Extrusion

All other uses (including export)

All other thermoplastic resins °

1,000 pounds,

basis2 374,067

419,759

1,000 pounds,

basis2 300,934 75,671 376,605 182,712 135,991 57,902 342,544

1,000 dollars 64,831

312,321

$0.22

1 Calculated from rounded figures.

2 For the purpose of this report, "dry basis" is defined as the total weight of the material, including resin, plasticizers, fillers, extenders, colors and stabilizers, and excluding water, solvents, and other liquid diluents.

3 Includes saturated polyesters for urethanes.

The term "polyester resins" includes unsaturated alkyds copolymerized with a monomer such as styrene, and polyallyl resins such as diallyl phthalate and allyl diglycol carbonate.

5 Includes 448,650 thousand pounds of urea-formaldehyde type, and 172,529 thousand pounds of melamine-formaldehyde type.

6 Includes data for acetone -formaldehyde resins, styrene-alkyd polyesters, toluenesulfonamide resins, silicone resins, and other thermosetting resins, which were produced in small quantities.

Includes straight polystyrene, 728,435 thousand pounds; rubber modified polystyrene, 641,884 thousand pounds; styrene-butadiene copolymers, 253,146 thousand pounds; and all other, including ABS and SAN, 409,682 thousand pounds .

8 Includes 37,373 thousand pounds of polyvinyl alcohol.

Data for intra-company consumption may not be shown separately, and are included with sales at an estimated unit value .

10 Includes data for acrylic, fluorocarbon, polycarbonate, polyoxymethylene, polyterpene, and other thermoplastic resins.

of the Tariff Commission's monthly report on the production and sales of synthetic plastics and resin materials (S. O. C. Series P-65). However, data are included for plastics materials which are not covered in the monthly report and for a number of smaller producers that do not report monthly. The monthly data for 1965, moreover, were returned to the reporting companies for verification or correction. In consequence, many of the figures in the following table are revised from those shown in the monthly release of March 23, 1966, which contained yearend cumulative totals for 1965. The figures in the thermoplastics section of the table under "Used by reporting companies in processing" represent captive use of the materials. The quantities reported under "Sales and use" in this section include data for captive consumption, and for outside sales as defined in the introduction to this volume.

In 1965, total U.S. production of synthetic plastics and resin materials, including cellu- losics, amounted to 11, 685 million pounds, or 15. 7 percent more than the 10, 103 million pounds reported for 1964. Sales of synthetic plastics and resin materials in 1965 amounted to 10, 053 million pounds, valued at $2, 504 million. Production of benzenoid plastics and resin materials in 1965 amounted to 4,453 million pounds, and that of nonbenzenoid materials, to 7, 232 million pounds. These figures compare with production in 1964 of 3, 915 million pounds, and 6, 188 million pounds, respectively. Production of all thermosetting resins in 1965 was 3,237 million pounds, and that of thermoplastic resins was 8,448 million pounds.

In 1965, polyethylene, polystyrene, and polyvinyl chloride resins were the materials produced in the largest volume. The total output of high-density and low-density polyethylene resins in 1965 amounted to 3, 047 million pounds, compared with 2, 613 million pounds in 1964. Sales of polyethylene resins in 1965 were 2, 695 million pounds, valued at $464 million. Produc- tion of styrene-type plastics materials in 1965 was 2, 033 million pounds, compared with 1, 728 million pounds in 1964. Sales of such materials in 1965 were 1, 836 million pounds, valued at $383 million. The output of polyvinyl chloride and copolymer resins in 1965 amounted to 1, 837 million pounds, compared with 1, 637 million pounds in 1964. Sales of polyvinyl chloride resins in 1965 totaled 1, 715 million pounds, valued at $297 million. Other synthetic plastics and resin materials produced in 1965 in large volume were phenolic and other tar acid resins (922 million pounds), alkyd resins (640 million pounds), urea and melamine resins (621 million pounds), polyester resins (399 million pounds), coumarone-indene and petroleum polymer resins (324 million pounds), and polyvinyl acetate resins (313 million pounds).

42

SYNTHETIC ORGANIC CHEMICALS, 1965

Rubber-Processing Chemicals

Rubber-processing chemicals are organic compounds that are added to natural and synthetic rubbers to give them qualities necessary for their conversion into finished rubber goods. In this report, statistics are given for cyclic and acyclic compounds, by use--such as accelerators, antioxidants, and peptizers. Statistics on production and sales of rubber-processing chemicals in 1965 are given in table 16A.7

Production of rubber-processing chemicals as a group in 1965 amounted to 252 million pounds, compared with the 261 million pounds reported for 1964. This apparent decrease in 1965 production was due principally to the reclassification of sodium 2-mercaptobenzothiazole (2- benzothiazolethiol, sodium salt) from rubber-processing chemicals to cyclic intermediates. Sales of rubber-processing chemicals in 1965 amounted to 194 million pounds, valued at $123 million, compared with 184 million pounds, valued at $123 million, in 1964.

TABLE 16A. — Rubber-processing chemicals.- U.S. production and sales , 1965

[Listed below are all rubber-processing chemicals for which any reported data on production or sales may be pub- lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported. ) Table 16B in pt. Ill lists separately all rubber-processing chemicals for which data on production or sales were reported and identifies the manufacturer of each]

Quantity

Unit value1

Grand total

RUBBER-PROCESSING CHEMICALS, CYCLIC Total

Accelerators, activators, and vulcanizing agents, total

Aldehyde-amine reaction products

Dithiocarbamic acid derivatives

Thiazole derivatives, total

N-Cyclohexyl-2-benzothiazolesulfenamide

2,2'-Dithiobis(benzothiazole)

All other

All other accelerators

Antioxidants, antiozonants, and stabilizers, total

Amino antioxidants, antiozonants, and stabilizers, total Aldehyde- and acetone-amine reaction products , total —

Diphenylamine -ace tone condensate

All other

Substituted p-phenylenediamines, total

NjN'-Diphenyl-p-phenylenediamine

All other

Octyldiphenylamine

All other amino antioxidants, antiozonants, and

stabilizers

Phenolic and phosphite antioxidants and stabilizers,

total

Phenol, alkylated

All other phenolic and phosphite antioxidants and

stabilizers

Blowing agents

Peptizers

All other cyclic rubber-processing chemicals, total

N-Nitrosodiphenylamine (retarder)

All other3

See footnotes at end of table.

251,945

193,718

1,000 dollars 123,393

211,403

166,214

109,204

71,279

55,841

32,529

239 59,439 7,228 21,307 30,904 11,601

127,537

97,928

9,374

8,601

773

41,496 1,732

39,764 2,189

44,869

29,609 11,522

18,087

3,425 4,950

4,212

1,086

207

44,077

6,232 10,805 27,040 10,471

99,421

3,224

77,166

7,991

7,414

577

29,538 1,479

28,059 1,982

37,655

22,255 6,693

15,562

3,340 4,404

3,208

971 354 22,907 3,501 5,386 14,020 8,297

67,045

2,254 954

50,380

4,041

3,594

447

27,249 1,335

25,914 1,044

18,046

16,665 3,508

13,157

4,698 2,842

2,090

1,239 851

1.71 .52 .56 .50 .52 .79

.48 .77 .92 .90 .92 .53

.52 .85

1.41 .65

7 See also table 16B, pt. Ill, which lists these products alphabetically and Identifies the manufacturers.

ELASTOMERS (SYNTHETIC RUBBERS) TABLE 16A. — Rubber-processing chemicals .- U.S. production and sales, 1965 — Continued

43

Quantity

Unit value1

RUBBER-PROCESSING CHEMICALS, ACYCLIC

Total

Accelerators, activators, and vulcanizing agents, total

Dithiocarbamic acid derivatives, total*

Dibutyldithiocarbamic acid, zinc salt

Diethyldithiocarbamic acid, zinc salt

Dimethyldithiocarbamic acid, zinc salt

All other

Thiurams, total5

Bis(dimethylthiocarbamoyl) disulfide

Bis(dimethylthiocarbamoyl) sulfide

All other

All other accelerators, activators, and vulcanizing agents

1.000 pounds 40,542

27,504

1.000 dollars 14,189

21,340

Dodecyl mercaptans"

Dimethyldithiocarbamic acid, sodium salt

All other acyclic rubber-processing chemicals7

8,575 1,522 1,262 1,478 4,313 12,379 7,045 1,561 3,773

386

12,551 3,469 3,182

14,144

6,557 1,559 861 1,288 2,849 7,324 4,708 1,338 1,278

263

10,748

2,612

8,834

4,802

1,468

523

570

2,241

3,746

2,036

1,088

622

286

4,218 1,137

.44 .79 .51 .43 .81

.44

1 Calculated from rounded figures.

2 Not comparable with data for previous years owing to reclassification of certain products previously considered to be rubber-processing chemicals.

3 Includes tackifiers and physical-property improvers.

4 Data on dithiocarbamates included in this table are for materials used chiefly in the processing of natural and synthetic rubbers. Data on dithiocarbamates which are used chiefly as fungicides are reported in table 20A, "Pesti- cides and Other Organic Agricultural Chemicals . "

5 Includes data for small amounts of tetramethylthiuram sulfides for uses other than in the processing of natural and synthetic rubbers.

6 Includes some detergent -grade dodecyl mercaptans.

7 Includes blowing agents, polymerization regulators, shortstops, and conditioning and lubricating agents.

The output of cyclic rubber-processing chemicals in 1965 amounted to 211 million pounds. Sales in 1965 were 166 million pounds, valued at $109 million, compared with 162 million pounds, valued at $109 million, in 1964. Of the total output of cyclic rubber-processing chem- icals in 1965, accelerators accounted for 33.7 percent and antioxidants for 60.3 percent. Pro- duction of amino and phenolic and phosphite antioxidants, which amounted to 127. 5 million pounds in 1965, included 97. 9 million pounds of amino compounds and 29. 6 million pounds of phenolic and phosphite compounds. Sales of amino antioxidants in 1965 were 77.2 million pounds, valued at $50.4 million; sales of phenolic and phosphite antioxidants were 22. 3 million pounds, valued at $16. 7 million.

Production of acyclic rubber-processing chemicals in 1965 amounted to 40. 5 million pounds, compared with the 38. 1 million pounds reported for 1964. Sales in 1965 totaled 27. 5 million pounds, valued at $14. 2 million, compared with 22. 6 million pounds, valued at $14.4 million, in 1964. Accelerators, principally dithiocarbamic acid derivatives and tetramethyl- thiuram sulfides, accounted for 52.6 percent of the output of acyclic rubber-processing chemi- cals in 1965. Dodecyl mercaptans accounted for 31.0 percent. Blowing agents, peptizers, modifiers, shortstops, and lubricating and conditioning agents accounted for the remainder of the output in the acyclic group.

Elastomers (Synthetic Rubbers)

The synthetic rubber industry in the United States continued to operate at a high level of capacity in 1965. The styrene-butadiene, or S-type, rubber is a general-purpose material used in the manufacture of tires and other rubber goods, and is the most important type of synthetic rubber, in terms of quantity produced. Several other types of synthetic rubbers are also pro- duced in large volume; among them are the polybutadiene-acrylonitrile type, or N-type, the polybutadiene-isoprene type, or Butyl-type, neoprene, and stereo elastomers.

44 SYNTHETIC ORGANIC CHEMICALS, 1965

The total output of all types of elastomers in the United States in 1965 amounted to 3, 592 mil- lion pounds --somewhat more than the 3,421 million pounds reported for 1964. Sales of elastomers covered in this report amounted to 3, 041 million pounds, valued at $843 million, in 1965, com- pared with 2, 958 million pounds, valued at $810 million, in 1964. Statistics on the production and sales of elastomers are given in table 17A.8

Production of cyclic elastomers, which consisted chiefly of the polybutadiene-styrene type (S-type), amounted to 2,300 million pounds in 1965, compared with 2,332 million pounds in 1964. Sales of these elastomers amounted to 1, 898 million pounds, valued at $443 million, in 1965, com- pared with 1,961 million pounds, valued at $451 million, in 1964. Production of polyurethane type elastomers in 1965 amounted to 9. 0 million pounds.

The output of acyclic elastomers, including N-type, neoprene, Butyl, silicone, and stereo elastomers, amounted to 1,292 million pounds in 1965, compared with the 1, 089 million pounds reported for 1964. Sales of these elastomers amounted to 1, 143 million pounds, valued at $401 million, in 1965, compared with 996 million pounds, valued at $359 million, in 1964. The output of silicone elastomers in 1965 amounted to 10. 9 million pounds, and that of stereo elastomers, to 502 million pounds.

TABLE 17A. — Elastomers (synthetic rubbers) :x U.S. production and sales, 1965

[Listed below are all elastomers (synthetic rubbers) for which reported data on production or sales may be pub- lished. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 17B in pt. Ill lists alphabetically all elastomers for which data on production or sales were reported and identifies the manufacturer of each]

Qjjantity

Unit value2

Grand total

ELASTOMERS, CYCLIC

Total

Polybutadiene-styrene type (S-type)

Polybutadiene-styrene-vinylpyridine type-- Polyurethane type

ELASTOMERS, ACYCLIC

Total

Polybutadiene-acrylonitrile type (N-type)-

Polyisobutylene-isoprene type (Butyl)

Silicone elastomers

Stereo elastomers, total

Stereo polybutadiene

All other stereo elastomers

All other acyclic elastomers

3,591,654

3,041,163

1,000 dollars 843,448

2,271,647 19,402 9,043

4 1,879,568 10,432 7,921

1,143,242

427,741 6,650 8,331

400,726

149, 858 225,392 10, 913

111,695 8,535

410,508

52,812 30,425 91,314

362,278 139,878

287, 090 123,418

62,158 29, 156

$0.28

.23

.64

1.05

The term "elastomers" is defined as substances in bale, crumb, powder, latex, and other crude forms which can be vulcanized or similarly processed into materials that can be stretched at 68° F. to at least twice their original length and, after having been so stretched and the stress removed, will return with force to approximately their original length.

2 Calculated from rounded figures.

3 Elastomer-content basis.

4 Partly estimated.

Note. — Statistics on the production of S-type, cooperation with the U.S. Bureau of the Census.

N-type, Butyl, neoprene, and stereo elastomers were compiled in

8 see also table 17B, pt. m, which lists these products alphabetically and identifies the manufacturers.

PLASTICIZERS

45

Plasticizers

Plasticizers are organic chemicals that are added to synthetic plastics and resin materials to (1) improve workability during fabrication, (2) extend or modify the natural properties of these resins, or (3) develop new improved properties not present in the original resins. Plasticizers re- duce the viscosity of the resins and make it easier to shape and form them at high temperatures and pressures. They also impart flexibility and other desirable properties to the finished product. Statistics on production and sales of plasticizers are given in table 18A.9

TABLE 18A. --Plasticizers:1 U.S. production and sales, 1965

[Listed below are all plasticizers for which reported data may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 18B in pt. Ill lists all plasticizers for which data on production or sales were reported and identifies the manufacturer of each]

Production

Quantity

Unit value3

Grand total

PLASTICIZERS, CYCLIC

Total

Phosphoric acid esters:

Cresyl diphenyl phosphate

Tricresyl phosphate

Phthalic anhydride esters, total

Butyl octyl phthalates ( including butyl 2-ethyLhexyl

phthalate)

Dibutyl phthalates (including diisobutyl phthalate) —

Dicyclohexyl phthalate

Diethyl phthalate

Dihexyl phthalate

Diisodecyl phthalate

Di(2-methoxyethyl) phthalate

Dimethyl phthalate

Dioctyl phthalates, total

Di( 2-ethyLhexyl) phthalate

Diiso-octyl phthalate

Mixed dioctyl phthalates (including dioctyl iso-

phthalates)

Ditrideeyl phthalate

Octyl decyl phthalates (including iso-octyl isodecyl

phthalate)

All other phthalic anhydride esters

Trimellitic acid esters

All other cyclic plasticizers3

PLASTICIZERS, ACYCLIC*

Total- -

Adipic acid esters, total

Di( 2- ethylhexyl) adipate

Diisodecyl adipate

Diiso-octyl adipate ( including di-n-octyl adipate)

Octyl decyl adipate ( including iso-octyl isodecyl

adipate)

All other

See footnotes at end of table.

1 000 pounds 1,073,197

798,741

19, 697 34, 834

678, 679

15,052

20,012

7,719

17,999

1,702

89, 552

10,976

4,408

353, 108

212,360

121,589

19,159

25,416 119, 847

65,531

274,456

47,760

1A,704 9,582 10,912

10,065 2,497

1,000

pounds

1,021,623

764,736

17, 103 37, 627

646,366

14, 934 16,773

12,035

1,489

89,112

8,107

3,937

343,016

211,466

115,945

15,605 13,145

25,856 117,962

1,981 61,659

256,887

42, 950

13,205 8,162

9,978 11, 605

214,392

133,044

4,447 11,338

97,772

1,973 3,1A0

2,181

231

12,523

1,669

786

47, 084

28, 438

16, 255

2,391 2,662

4,41A 21, 109

801 18,686

81,348

11, K5

2,989 2,181

2,335 3,640

See also table 18B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 18A. --plasticizers.-1 U.S. production and sales , 1965 --Continued

Production

Quantity

Unit value2

PLASTICIZERS, ACYCLIC— Continued

Azelaic aeid esters '

Complex linear polyesters and polymeric plasticizers-

Epoxidized esters, total

Epoxidized soya oils

2-Ethylhexyl epoxytallates

Octyl epoxytallates

All other5 -

Glycerol monoricinoleate

Isopropyl myristate

Isopropyl pa Imitate

Oleic acid esters, total

Butyl oleate

Glycerol trioleate (Triolein)

Isopropyl oleate

Methyl oleate

n-Propyl oleate

All other6

Phosphoric acid esters

Sebacic acid esters:

Dibutyl sebacate

Di(2-ethylhexyl) sebacate

Stearic acid esters, total

n- Butyl stearate

All other

Triethylene glycol di(caprylate-caprate)

All other acyclic plasticizers7

13,167 40, 265

75,905

49,484

10,642 15,779

1,473 1,008

9,470

3,106

2,666

168

2,631

698

201

13,851

4,692 5,711

3,848 3,848

1,844 51,614

1,000

pounds 15,092 37,759

81,322

54,158 11,362 9,788 6,014 258 1,397 942

6,689

1,681

2,174

139

1,850

664

181

12,197

3,137 5,509

7,318

3,540 3,778

1,536 40,781

1.000 dollars 4,435 14,746

21,450

14,395 2,420 2,467 2,168

92 626

348

1,443

361 475

379 136

5,323

1,908 2,780

1,749

839 910

503 14, 800

.61 .50

.33 .36

1 Does not include data for clearly defined extenders or secondary plasticizers.

2 Calculated from rounded figures.

3 Includes data for glycol dibenzoates, phosphate esters (including triphenyl phosphate), toluenesulfonamides, tetrahydrofurfuryl oleate, trimellitic acid esters (production only), and other cyclic plasticizers.

4 Dibutyl maleate is now published in table 21A, "Miscellaneous Chemicals."

5 Includes several items that were included in earlier reports in "All other" oleic acid esters.

6 Several items that were included here in earlier reports are now included in "All other" epoxidized esters.

7 Includes data for citric and acetylcitric, lauric, myristic, palmitic, ricinoleic, sebacic, and tartaric acid esters, glycerol and glycol esters of certain fatty acids, glycerol tripropionate, and other acyclic plasticizers.

Note. — The total production and sales statistics are included in this report for some items that are not used exclusively as plasticizers.

Total U.S. production of plasticizers in 1965 amounted to 1, 073 million pounds — representing an increase of 12.8 percent over the output of 951 million pounds reported for 1964. Sales in 1965 of the plasticizers covered by this report amounted to 1, 022 million pounds, valued at $214 mil- lion, compared with 905 million pounds, valued at $187 million, in 1964.

Production of cyclic plasticizers in 1965, which consisted chiefly of the esters of phthalic anhydride and phosphoric acid, amounted to 799 million pounds, compared with 718 million pounds in 1964. Sales of cyclic plasticizers in 1965 amounted to 765 million pounds, valued at $133 mil- lion, compared with 690 million pounds, valued at $120 million, in the previous year.

Production of acyclic plasticizers in 1965 amounted to 274 million pounds, compared with 234 million pounds in 1964. Sales of acyclic plasticizers in 1965 amounted to 257 million pounds, valued at $81 million, compared with 215 million pounds, valued at $68 million, in 1964. Produc- tion of complex linear polyesters in 1965 amounted to 40 million pounds, and that of epoxidized esters, to 76 million pounds. Other products included in the acyclic class are the esters of adipic, azelaic, oleic, sebacic, and stearic acids.

SURFACE-ACTIVE AGENTS

47

Surface-Active Agents

The surface-active agents covered in this report include anhydrous potassium and sodium soaps, synthetic organic detergents, and dispersing, emulsifying, and wetting agents that function in either aqueous or nonaqueous systems. Waxes and plasticizers are not included. The data are reported in terms of 100-percent organic, surface-active ingredient, and thus exclude all inor- ganic salts, water, and other diluents. A major part of the output of surface-active agents is con- sumed in the form of packaged soaps and detergents for household and industrial use. The re- mainder is used as dispersing, emulsifying, foaming, penetrating, and wetting agents in the proc- essing of textiles and leather, in ore flotation and oil-drilling operations, and in the manufacture of agricultural sprays, cosmetics, elastomers, foods, lubricants, paints, pharmaceuticals, and many other products.

Statistics on U.S. production and sales of surface-active agents in 1965 are given in table 19A.10 Total production of surface-active agents in 1965 amounted to 3, 170 million pounds. This

TABLE 19A. — Surface-active agents ; U.S. production and sales, 1965

[Listed below are all surface-active agents for which reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 19B in pt. Ill lists all surface-active agents for which data on production or sales were reported and identifies the manufacturer of each]

Production1

Sales"

Quantity1

Unit value3

Grand total

Amphoteric

Anionic

Cationic

Nonionic

BENZENOID SURFACE-ACTIVE AGENTS

Total -

Not Sulfated or Sulfonated Total

Amides, amines, and quaternary ammonium salts, total —

Benzyldimethyl( mixed alky 1) ammonium chloride

Benzyldimethyloctadecylammonium chloride

Benzyldodecyldimethylammonium chloride

(3,4-Dichlorobenzyl) dodecyldimethylammonium chloride-

( Dodecylbenzyl) trimethylammonium chloride

Heterocyclic compounds, total

l-Benzyl-2-heptadecyl-l-(2-hydroxyethyl)-2-imidazo- linium chloride-;

All other

Oxygen- containing compounds (except heterocyclic)

All other

Carboxylic acid esters and ethers, total

Dinonylphenol, ethoxylated

Dodecylphenol, ethoxylated

Iso-octylphenol, ethoxylated

Nonylphenol, ethoxylated

Phenol, ethoxylated

Other carboxylic acid esters and ethers

Phosphoric and polyphosphorie acid esters, total

Nonylphenol, ethoxylated and phosphated

All other

See footnotes at end of table.

1,000

pounds

3,170,478

5,112

2,358,173

148, 001

659, 192

1,371,320

246,024

8,127

3,859 378 662 46 187 637

53 584 710

232, 610

3, 19,645 1,940 129,394 6,504 71,322

5,287

4,264 1,023

1,000

pounds

1, 697, 862

4,899

1,077,582

123,213

492, 168

877,202

211,969

7,760

3,684 359 662 44 201 608

62

546

651

1,551

200,950

2,613 12,598

120,243

65,496

3,259

2,502 757

1,000 dollars 300, 188

2,940 133,393 50, 542 113,313

96,153

43,327

6,796

2,967 312 533 28 129 654

24

630

869

1,304

35,374

551 1,932

18,887

14,004

1,157

297

.60 .12 .41 .23

1.15

1.33

.84

.21 .36

10 See also table 19B, pt. in, which lists these products alphabetically and identifies the manufacturers.

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 19A. — Surface-active agents.- U.S. production and sales , 1965 — Continued

Chemical

Sales2

Production1

Quantity1 Value

BENZENOID SUHFACE-ACTIVE AGENTS— Continued

Sulfated and Sulfonated

Total

Aliylphenols, ethoxylated and sulfated, total

Nonylphenol, ethoxylated and sulfated, and salts

All other

Benzenesulfonates, total

Benzene-, cumene-, toluene-, and xylenesulfonates, total

Xylenesulfonic acid, ammonium salt

Xylenesulfonic acid, sodium salt

All other

Branched chain alkylbenzenesulf onates , total

Dodecylbenzenesulfonic acid

Dodecylbenzenesulfonic acid, calcium salt

Dodecylbenzenesulfonic acid, isopropylamine salt

Dodecylbenzenesulfonic acid ( mixed alkyl) amine salt

Dodecylbenzenesulfonic acid, sodium salt

Dodecylbenzenesulfonic acid, triethanolamine salt

All other

Straight chain alkylbenzenesulfonates, total

Dodecylbenzenesulfonic acid

Dodecylbenzenesulfonic acid, sodium salt

Dodecylbenzenesulfonic acid, triethanolamine salt

All other .

Lignosulfonates, total

Lignosulfonic acid, calcium salt

Lignosulfonic acid, sodium salt

All other

Naphthalenesulfonates, total

Butylnaphthalenesulfonic acid, sodium salt

Diisopropylnaphthalenesulfonic acid

All other

Other benzenoid surface- active agents, sulfated and

sulfonated*

NONBENZENOID SUHFACE-ACTIVE AGENTS

Total - -

Not Sulfated or Sulfonated

Total5— - —

Amides, amines, and quaternary ammonium salts, total

Amines, amine oxides, and amine salts (except hetero- cyclic), total

Amine salts of fatty acids (anionic)

Amines, not containing oxygen, and salts thereof,

total

Amine salts ( cationic)

Diamines and polyamines, total

N-( 9-0ctadecenyl) trimethylenediamine

N-( Tallow alkyl) trimethylenediamine •

All other

Primary monoamines, total6

(Coconut oil alkyl) amine

Dodecylamine

( Hydrogenated tallow alkyl) amine

Octadecylamine

(Tallow alkyl) amine

All other

1,125,296

16,729

4,329 12,400

643,179

78,458

24,043

21,558

32,857

174, 650

47,441

11, 296

3,722

670

88,424

2,718

20,379

390,071

261,264

1,113

127, 694

288, 165 44,015 115,027

9,626

943

481

8,202

8,555

1,799,158

1,440,633

944

48,478 1,914 8,839 1,201 4, K)l 3,537

24,273 1,544 1,934

13,063

727

4,736

2,269

1,000 pounds 665,233

210,208

74,093 23,456 18, 276 32,361 83, 170 14, 382 8,800 3,814 279 49,069 2,754 4,072 52,945 12,606 37,300

3,039

428,055

269,728 43, 902 114,425

6,780

6,780 20, 190

820, 660

423,098

171,396

59,452 812

43,291 1,861 8,413 1,280 4,003 3,130

21,958 1,299 1,427

13,098

660

3,620

1,854

1,000 dollars 52,826

27, 670

5,153 1,573 1,599 1,981 1/4,645 2,152 2,318 1, 1/42 93 7,409 629 902 7,872 1,799 5,484

589

14,985

6,020 3,391 5,574

2,664

2,664

7,507

204, 035

125,616

61,527

20,300 561

1A, 105

626 2,795

518 1,408

869 6,61/4

610

778 2,992

303 1,065

866

See footnotes at end of table.

SURFACE-ACTIVE AGENTS TABLE 19A. — Surface-active agents; U.S. production and sales , 1 965 --Continued

49

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated— Continued

Amides, amines, and quaternary ammonium salts — Continued Amines, amine oxides, and amine salts ( except heterocyclic) — Continued

Amines, not containing oxygen, and salts thereof — Continued Secondary and tertiary monoamines6

Oxygen-containing amines and amine oxides, total

(Mixed alkyl) amine, ethoxylated

(Tallow aliyl) amine, ethoxylated

All other

Fatty acid - alianolamine condensates, total-

Diethanolamine condensates, total

Capric acid

Coconut oil acids (amine/acid ratio=2/l)

Coconut oil acids (amine/acid ratio=]/l)

Laurie acid

Oleic acid (amine/acid ratio^2/l)

Oleic acid (amine/acid ratio=l/l)

Stearic acid

Tall oil acids

All other

Other alianolamine condensates, total

Coconut oil acids - ethanolamine condensate

Laurie acid - ethanolamine condensate

Laurie acid - isopropanolamine condensate

Stearic acid - ethanolamine condensate ( amine/acid

ratio=l/l)

All other

Fatty acid - diamine and polyamine condensates, total

Oleic acid - diethylenetriamine condensate

Oleic acid - ethylenediamine condensate ( amine/acid ratio=l/2)

All other

Fatty acid - diamine and polyamine condensates,

alioxylated, total

Oleic acid - ethylenediamine condensate,

monoethoxylated

Stearic acid - ethylenediamine condensate,

monoethoxylated

All other

Heterocyclic amines and quaternary ammonium salts, total

Imidazoline derivatives, total

2-HeptadecyI-l-(2-hydroxyethyl) -2- imidazoline

All other

Morpholine, oxazoline, and piperazine derivatives

Quaternary ammonium salts (except heterocyclic), total —

Bis( coconut oil alkyl) dimethylammonium chloride

Bis(hydrogenated tallow a llsyl) dimethylammonium

chloride

Dimethyldioctadecylammonium chloride

Dodecyltrimethylammonium chloride

Oxygen- containing compounds

Other quaternary ammonium salts

N-Substituted amino acids and polypeptides, total

N-Lauroylsarcosine, sodium salt

All other

Other amides, amines, and quaternary ammonium salts,

total

Hydrogenated tallow acids - ethanolamine condensate, ethoxylated

Oleic acid - ethanolamine condensate, ethoxylated

All other

Production1

13,452

2,782

1,086

(7)

85,912

68, U7

96

17, 194

21,526

20,654

1,652

1,262

1,877

470

3,416

17, 765

Quantity1

1,000

pounds

11,059

15,349

2,593

1,051

11,705

58,531

52,493

21,109

1,328 1,231 1,609 204 27,012 6,038 2,312

498

662

672

223

113

113

41

16,492

2,941

1,018

17, 837

17, IK)

6,461

912

767

222

96

98

33

16, 829

16,245

6,206

8,531

5,519

4,597

4,261

3,913

2,476

2,405

357

3,043

2,192

9,173

7,866

3,553

7,112

6,470

2,762

481

473

212

6,631

5,997

2,550

2,061

1,396

791

17, 890

18, 169

6,476

1,334

1,228

695

12,894

13,349

3,106

164

157

86

100

124

143

1,361

1,298

933

2,037

2,013

1,513

5,840

3,569

1,662

2,663

3,177

3,569

1,662

1,180

647

250

277

100

103

108

74

7)

795

473

1,000

dollars

4,070

5,634

1,150

746

3,738

17,831

15,997

5,850

424

415

759

43

8,506

1,834

552

See footnotes at end of table.

50

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 19A. -Surface-active agents; U.S. production and sales, 1 965 --Continued

Production1

Sales2

Quantity1 Value

NONBENZENOID SURFACE-ACTIVE AGENTS--Continued

Not Sulfated or Sulfonated--Continued

Carboxylic acid esters, total

Ethylene glycol and diethylene glycol esters, total—

Diethylene glycol monolaurate

Diethylene glycol mono-oleate

Diethylene glycol monostearate

Ethylene glycol distearate

Ethylene glycol monostearate

All other

Glycerol esters, total

Complex glycerol esters

Glycerol esters of chemically defined acids, total-

Glycerol monolaurate

Glycerol mono-oleate

Glycerol monostearate

All other

Glycerol esters of mixed acids

Polyethylene glycol esters, total

Polyethylene glycol esters of chemically defined

acids, total

Polyethylene glycol dilaurate

Polyethylene glycol dioleate

Polyethylene glycol distearate

Polyethylene glycol monolaurate

Polyethylene glycol mono-oleate

Polyethylene glycol monostearate

All other

Polyethylene glycol esters of mixed acids, total —

Polyethylene glycol ester of castor oil acids

Polyethylene glycol ester of coconut oil acids —

Polyethylene glycol ester of rosin acids

Polyethylene glycol ester of tall oil acids

Polyethylene glycol ester of tallow acids

All other

Polyglycerol esters

Other carboxylic acid esters, total

Anhydrosorbitol tall oil ester

Anhydrosorbitol trioleate

Anhydrosorbitol tristearate

Ethoxylated anhydrosorbitol monolaurate

Ethoxylated anhydrosorbitol mono-oleate

Ethoxylated anhydrosorbitol monopalmitate

Ethoxylated anhydrosorbitol monostearate

Ethoxylated anhydrosorbitol trioleate

Ethoxylated anhydrosorbitol tristearate

1, 2-Propanediol monolaurate

1, 2-Propanediol monostearate

All other

Ethers, total

Castor oil, ethoxylated ■

n-Dodecyl alcohol, ethoxylated

Lanolin, ethoxylated

Mixed linear alcohols, ethoxylated

9-0ctadecenyl alcohol, ethoxylated

n-Octadecyl alcohol, ethoxylated

Tridecyl alcohol, ethoxylated

All other

1,000 pounds 146,815

5,179 519 77 911

2,868 68, 233

4,006

29,399

81

3,481 24,524

1,313 34, 828 24,344

18,464

1,067

3,219

327

4,762

3,205

4,693

1,191

5,880

999

461

435

3,686

140

159

956

48, 103

468

563

375

3,007

4,316

320

2,496

407

775

144

1,122

34, 110

189,975

3,087

631

101, 877

3,438

514

8,029

72,399

1,000 pounds 112,226

1,000 dollars 37,053

4,531

509

58

561

255

653

2,495

59,252

3,012

27,956

57

3,043

23,076

1,780

28,284

15,845

10,567

818

651

282

2,058

2,283

3,686

789

5,278

" 354

"3,243

W-9

1,532

885

31,713

390

64

2,526

3,724

2,238 393

151

1,047

21, 180

117,226

2,619

1,937

268

75,580

2,404

398

7,293

26,727

1,485

156

16

171

76

251

815

15,912

1,325

7,769

21

726

6,495

527

6,818

5,702

4,187 283 242 100 821 888

1,406 447

1,515

594

413

13,541

152

23

1,085

1,592

982 176

61

628

8,842

21,154

SgT

859

87

9,407

1,128

185

1,638

6,969

See footnotes at end of table.

SURFACE-ACTIVE AGENTS TABLE 19A. — Surface-active agents ; U.S. production and sales, 1965-

Chemical

Production-1-

Quantity1

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued Not Sulfated or Sulfonated— Continued

Fatty, rosin, and tall oil acids, potassium and sodium

salts, total8

Coconut oil acids, potassium and sodium salts

Oleic acid, potassium salt

Oleic acid, sodium salt

Stearic acid, potassium and sodium salts

Tall oil acids, potassium and sodium salts, total

Potassium salt

Sodium salt

Tallow acids, sodium salt

All other

Phosphoric and polyphosphoric acid esters, total

2-Ethylhexyl phosphate, sodium salt

2-Ethylhexyl polyphosphate

All other

Sulfated and Sulfonated

Total5

Alcohols, sulfated, total

n-Dodecyl sulfate salts, total

n-Dodecyl sulfate, ammonium salt

n-Dodecyl sulfate, sodium salt

n-Dodecyl sulfate, triethanolamine salt

n-Dodecyl sulfate, all other salts

All other sulfated alcohols

Amides, amines, and quaternary ammonium salts, sulfated

and sulfonated, total

Coconut oil acids - ethanolamine condensate, sulfated,

potassium salt

N-Methyl-N-oleoyltaurine

Quaternary ammonium sulfates

Sulfosuccinamie acid derivatives

All other

Carboxylic acid esters (except natural fats and oils),

sulfated and sulfonated, total

Esters of sulfated oleic acid, total

Isopropyl oleate, sulfated

Propyl oleate, sulfated

All other

Sulfosuccinic acid esters, total

Sulfosuccinic acid, bis (2-ethylhexyl) ester

Sulfosuccinic acid, dihexyl ester

Sulfosuccinic acid, ditridecyl ester, sodium salt

All other

Other carboxylic acid esters, sulfated and sulfonated

Ethers, sulfated and sulfonated, total

n-Dodecyl alcohol, ethoxylated and sulfated, sodium salt All other

Natural fats and oils, sulfated, total

Castor oil, sulfated

Coconut oil, sulfated

Cod oil, sulfated

Grease, other than wool, sulfated

Neat's- foot oil, sulfated

Peanut oil, sulfated

Soybean oil, sulfated

Sperm oil, sulfated

Tallow, sulfated

All other

1,000

3,361

101,505 2,845 2,035 2,265 29, 775 1/4,460 15,315 473,326 286, 610

6,656

249

380

6,027

106, 986

41,899 1,961

15,889 9,712

1A,337 (7)

15,042

30 3,021 8,767 1,760 1,464

3,701 1,094 508 2,099 6,817 4,774

(7)

298 757

2,120 (7)

29,507

5,518 2,758 2,224

659 1,253 1,121

279 6,490 8,272

933

1,000 pounds

1,000 dollars

312 948

14, 916

(7)

5,186

232

380

4,574

116,471

29,644

1,930 12,459 5,467

9,788 14,559

30 2,943 8,559 1,707 1,320

11,343

3,147

550

750

1,847

6,291

4,347

955

305

684

1,905

42,531

1,542 40,989

18,394

3,851

805

1,625

589

1,007 150 3,278 6,061 1,028

154

312

2,117

(7) 3,244

72

105

3,067

35,297

12,922

825 6,233 1,755

4,109

6,727

31

1,458

3,112

986

1,140

5,812

1,013 211 186 616

3,381

2,464 328 187 402

1,418

5,859

499 5,360

3,977

1,228 163 275

136 281

sa

630 947 259

See footnotes at end of table.

52

SYNTHETIC ORGANIC CHEMICALS, 1965 TABLE 19A. --Surface-active agents; U.S. production and sales , 1965 --Continued

Sales 2

Chemical

Production1

Quantity1

Value

Unit value3

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Sulfated and Sulfonated- -Continued

Other nonbenzenoid surface- active agents, sulfated and sulfonated:

1.000

7,206 694

1,000 pounds

(7)

(7)

1,000

dollars

C)

(7)

Per

Nonbenzenoid surface-active agents for which separate data cannot be shown

Total9— - -

251,539

281,091

43,122

$0.15

All quantities are given in terms of 100-percent organic surface-active ingredient.

2 Sales include products sold as bulk surface-active agents only.

3 Calculated from rounded figures.

4 Includes sales of alkylphenols, ethoxylated and sulfated.

5 Total shown includes only those products and groups for which separate data are published below.

6 These products were included in the "Miscellaneous Chemicals" section in previous years.

7 Data are not separately publishable but are included in the total shown below for "Nonbenzenoid surface- active agents for which separate data cannot be shown."

8 Includes production of approximately 884- million pounds not previously reported.

9 Includes production of "all other" oxygen-containing amines and amine oxides, "all other" amides, amines, and quaternary ammonium salts, and "all other" sulfated and sulfonated alcohols, carboxylic acid esters, and ethers; includes sales of "all other" potassium and sodium salts of fatty, rosin, and tall oil acids, and of sulfated oleic acid and sulfated tall oil; also includes production and sales of "all other" nonbenzenoid surface- active agents, not sulfated or sulfonated, and of "all other" nonbenzenoid surface-active agents, sulfated and sulfonated.

total includes data for fatty monoamines, which in previous years were reported in the section on miscellaneous organic chemicals, and for potassium and sodium salts of fatty, rosin, and tall oil acids (soaps), which were for the most part not reported in previous years. U.S. production in 1965, exclusive of materials reported for the first time, amounted to approximately 2,248 mil- lion pounds--6. 1 percent more than the 2, 119 million pounds reported for 1964, and 13. 5 percent more than the 1, 981 million pounds reported for 1963. Sales of bulk surface-active agents in 1965 amounted to 1, 698 million pounds, valued at $300 million. These figures reflect sales of bulk surface-active agents only and cannot be compared with sales data for previous years, which included surface-active agents sold as active ingredients in formulated and packaged products, as well as strictly bulk materials.

Production of anionic surface- active agents in 1965 amounted to 2, 358 million pounds, or 74.4 percent of the total; sales amounted to 1, 078 million pounds, valued at $133 million. Of the anionic products for which individual statistics are shown in the table, those produced inlargest quantity were tallow acids, sodium salt, 473 million pounds; lignosulfonic acid, calcium salt, 288 million pounds; straight chain dodecylbenzenesulfonic acid, sodium salt, 261 million pounds; coconut oil acids, potassium and sodium salts, 102 million pounds; and branched chain dodecyl- benzenesulfonic acid, sodium salt, 88 million pounds.

Production of those surface-active agents which are generally considered to be nonionic amounted to 659 million pounds, or 20.8 percent of the total output for 1965; sales amounted to 492 million pounds, valued at $113 million. The most important nonionic products, in terms of quantity, were nonylphenol, ethoxylated, 129 million pounds, and mixed linear alcohols, ethoxy- lated, 102 million pounds.

Production of cationic materials totaled 148 million pounds, or 4. 7 percent of the total; sales amounted to 123 million pounds, valued at $51 million. Production of amphoteric materials amounted to 5 million pounds, or approximately 0. 2 percent of the total; sales amounted to 5 million pounds, valued at $3 million.

Pesticides and Other Organic Agricultural Chemicals

This section of the report covers pesticides (fungicides, herbicides, insecticides, and rodenticides) and other organic agricultural chemicals, such as plant hormones, seed disinfec- tants, soil conditioners, and soil fumigants. The data are given in terms of 100-percent active material; they thus exclude such materials as diluents, emulsifiers, synergists, and wetting

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

53

agents. Statistics on production and sales of pesticides and other organic agricultural chemicals in 1965 are given in table 20A.

Production of pesticides and other organic agricultural chemicals in 1965 amounted to 877 million pounds—about 12 percent more than the 783 million pounds reported for 1964. Sales in 1965 were 764 million pounds, valued at $497 million, compared with 692 million pounds, valued at $427 million in 1964.

The output of cyclic pesticides and other chemicals included in the cyclic group amounted to 683 million pounds in 1965--about 17 percent more than the 585 million pounds produced in 1964. Sales in 1965 were 582 million pounds, valued at $378 million, compared with 523 million pounds, valued at $317 million, in 1964.

Production of acyclic pesticides and other acyclic organic agricultural chemicals in 1965 amounted to 195 million pounds, compared with the 198 million pounds reported for 1964. Sales in 1965 were 182 million pounds, valued at $119 million, compared with 170 million pounds, valued at $111 million, in 1964. The apparent decrease in production was caused by the transfer of several chlorothiophosphates used as intermediates, to the acyclic miscellaneous chemicals section.

TABLE 20A. — Pesticides and other organic agricultural chemicals .• U.S. production and sales , 1965

[Listed below are all pesticides and other organic agricultural chemicals for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported.) Table 20B in pt. Ill lists all pesticides and other organic agricul- tural chemicals for which data on production or sales were reported and identifies the manufacturer of each ]

Quantity

Unit value1

Grand total

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC

Total- —

Fungicides, total

Mercury fungicides

Naphthenic acid, copper salt

Pentachlorophenol (PCP)

Pentachlorophenol, sodium salt

2,4, 5-Trichlorophenol and salts

All other2 - -

Herbicides and plant hormones, total

2-sec-Butyl-4, 6-dinitrophenol, ammonium salt

Phenoxyacetic acid derivatives:

(2, 4-Dichlorophenoxy) acetic acid (2,4-D)

( 2, 4-Dichlorophenoxy) acetic acid esters and salts,

total

(2, 4-Dichlorophenoxy) acetic acid, n-butyl ester

(2, 4-Dichlorophenoxy) acetic acid, dimethylamine salt

(2, 4-Dichlorophenoxy) acetic acid, ethyl ester

(2, 4-Dichlorophenoxy) acetic acid, iso-octyl ester

(2, 4-Dichlorophenoxy) acetic acid, isopropyl ester

All other

(2,4, 5-Trichlorophenoxy) acetic acid (2,4,5-T)

(2, 4, 5-Trichlorophenoxy) acetic acid esters and salts,

total

(2,4,5-Trichlorophenoxy)acetic acid, n-butyl ester — (2,4, 5-Trichlorophenoxy) acetic acid, iso-octyl ester

All other :

Phenylmereury acetate (PMA)

All other3 - - —

Insecticides and rodenticides, total

Aldrin-toxaphene group4

Hexachlorocyclohexane (Benzene hexachloride) and

lindane5

See footnotes at end of table.

1,000 pounds 877, 197

1,000 pounds 763, 905

1,000 dollars 497,066

682,671

582,344

377, 858

87,378

1,602 3,268 39,965 11,113 12,969 18,461

215,307

73,328

1,367 3,101 33,320 12,646

22,894

142,123

24,208

4,265

902

4,625

2,661

11,755

169,478

63,320

63,360

12,084 13,872

9,580

27, 824 11,601

13,516 6,485 2,292 4,739 588

62, 863

379,986

118, 832

26,049

47,299 10,925 11,435 628 7,948 3,053 13,310

13,176 5,820 2,401 4,955 375

55,168

366,893

110,794 6,948

7,664

21, 179 4,51A 4,743 158 3,007 955 7,802

9,674 3,449 1,831 4,394 2,615 128,275

184, 172

49,644 1,440

■ 33

3.12

.29

.25 .38

.73 .59 .76 .89 6.97 2.33

.50

11

See also table 20B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

54

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 20A. --Pesticides and other organic agricultural chemicals ; U.S. production and sales, 1965 — Continued

Production

Quantity

Unit

value1

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC— Continued Insecticides and rodenticides, total — Continued

Organophosphorus insecticides , total

0, O-Diethyl O-(p-nitrophenyl) phosphorothioate

(Parathion)

0, O-Dimethyl O-(p-nitrophenyl) phosphorothioate

(Methyl parathion)

All other6

l,l,l-Trichloro-2,2-bis(p-ehlorophenyl) -ethane (DDT)

All other7

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, ACYCLIC Total

Fungicides, total

Dime thyldithiocarb ami c acid, ferric salt (Ferbam)

Ethylene bis(dithiocarbamic acid), disodium salt (Nabam)

Ethylene bis(dithiocarbamic acid), zinc salt (Zineb)

All other8

Herbicides and plant hormones, total9

Insecticides, rodenticides, and soil conditioners and

fumigants, total

Bromome thane (Methyl bromide)

l,2-Dibromo-3-chloropropane

Organophosphorus insecticides10

All other insecticides, rodenticides, and soil

conditioners and fumigants11

1,000 pounds 62,029

16,607

29,111

16,311

140,785

58,340

194,526

55,186

14,198

27,440 13,548 141,451 52,514

181,561

1.000 dollars 63,778

10,427

20,662 32,689 20,458 48,852

119,208

36,456

33,014

25,943

2,384 2,489 5,075 26,508

47,617 110,453

14,303 3,433 33,299

59,418

1,745

2,141

4,468

24,660

40,746 107,801

15,127 3,893 30,557

58,224

675

813

2,012

22,443

37,798 55,467

6,605 2,013 39,051

7,798

pound

$1.16

.73

.75

2.41

.14

.93

■ 66 .79

.38 .45

.52 1.28

1 Calculated from rounded figures.

2 Includes captan, dichlone, glyodin, sodium pentaehlorophenate, tri- and tetrachlorophenols, and others.

3 Includes dimethylurea compounds, dinitrophenol compounds, endothal, isopropyl carbanilates (IPC and CIPC), maleic hydrazide, triazines, and others.

* Includes aldrin, chlordane, dieldrin, endrin, heptachlor, terpene polyehlorinates, and toxaphene.

5 Production of gamma isomer content is not publishable because publication would reveal the operations of the individual producers. Sales of gamma isomer content in benzenehexachloride and lindane totaled 2.0 million pounds.

6 Includes carbophenothion, diazinon, other phosphorothioates and phosphorodithioates, and others.

7 Includes DDD, endosulfan, methoxychlor, tetradifon and other chlorinated insecticides, 1-naphtnyl methylcar- bamate, small amounts of rodenticides and insect repellents, hexachlorocyclohexane and lindane (production only), and others.

8 Includes dodine, mercury compounds, maneb, and others.

9 Includes CDAA, methanearsonic acid, disodium salt, thiocarbamate and organophosphorus herbicides, sodium dichloropropionate, sodium TCA, and others.

10 Includes DDVP, ethion, malathion, naled, phorate, TEPP, and others.

11 Includes soil conditioners and fumigants, small quantities of rodenticides, and others.

Miscellaneous Chemicals

As used in this report, the term "miscellaneous chemicals" refers to those synthetic organic products that are not included in the use groups covered in the preceding sections of the report. These miscellaneous chemicals, which account for about three- fifths of the output of all synthetic organic chemicals, include products that are employed in a great variety of uses; the number of chemicals used exclusively for only one purpose is not large. Among the products covered are those used for gasoline and lubricating oil additives, paint driers, photographic chemicals, tanning materials, flotation reagents, refrigerants, textile polymers, sequestering agents, or- ganic fertilizers, antifreeze chemicals, solvents, and acyclic intermediates.

Production of miscellaneous chemicals in 1965 amounted to 50.8 billion pounds, or 11.3 percent more than the output of 45. 7 billion pounds reported for 1964. Sales of miscellaneous chemicals in 1965 amounted to 22. 0 billion pounds, valued at $2. 9 billion, compared with 20. 5 billion pounds, valued at $2. 7 billion, in 1964. Statistics on production and sales of miscellane- ous chemicals in 1965 are given in table 21A.12

" See also table 21B, pt. Ill, which lists these products alphabetically and identifies the manufacturers.

MISCELLANEOUS CHEMICALS 55

TABLE 21A. — Miscellaneous chemicals; U.S. production and sales, 1965

[Listed below are all miscellaneous chemicals for which any reported data on production or sales may be published. (Leaders are used where the reported data are accepted in confidence and may not be published or where no data were reported. ) Table 21B in pt. Ill lists alphabetically all miscellaneous chemicals for which data on produc- tion or sales were reported and identifies the manufacturer of each]

Quantity

Grand total

MISCELLANEOUS CHEMICALS, CYCLIC

Total

Benzoic acid salts: Sodium benzoate, tech. and U.S.P-

Benzoyl peroxide

Cyclopropane

2, 6-Di-tert- butyl- p-cresol:

Food grade

Tech

4- Ethylmorpholine

Flotation reagents

Gasoline additives, total2

N, N'-Di-sec-butyl-p-phenylenediamine

N, N'-Disalicylidene-l, 2-propanediamine

All other

Hexamethylenetetramine, tech

Lubricating oil and grease additives, total

Oil-soluble petroleum sulfonate, barium salt

Oil- soluble petroleum sulfonate, calcium salt

Oil-soluble petroleum sulfonate, sodium salt

All other

Morpholine

Naphthenic acid salts, total3 4

Calcium naphthenate

Cobalt naphthenate

Iron naphthenate

Lead naphthenate

Manganese naphthenate

Zinc naphthenate

All other

Photographic chemicals:

Benzotriazole

p-Diethylaminobenzenediazonium chloride (p-Diazo-N,

N-diethylaniline) - zinc chloride

N, N-Diethyltoluene-2, 5- diamine, monohydrochlori.de

Pinene

Propyl gallate

Tall oil salts, total3

Calcium tallate

Cobalt tallate

Iron tallate

Lead tallate

Manganese tallate

Zinc tallate

All other

Tanning materials, synthetic, total

2-Naphthalenesulfonic acid, formaldehyde condensate

and salts .

All other

See footnotes at end of table.

pounds 50, 835, 600

22,040,070

1,000 dollars 2, 890, 169

1,138,261

9,111

4,835

126

7,298 15,150 1,086 5,828

10,905 2,064

8,841 49,344 354,1

45,963 110, 801

73, 678 124,247

15,831

21,493

1,887 3,364

381 12,796 1,474 1,049

542

127 156

29,852 77

8,679

"785"

2,400

596

3,847

851

26

174

34,225

29,779 4,446

624, 813

7,474

4,734

126

6,761

12,147 974

6,540

2,169

853

3,518

34,318

210, 198

11, 604

47,422 151, 172

W,248

18,756

1,399 2,780

252 11,014 1,159

992 1,160

103 162

23,612

8,153

639 2,441

445 3,609

800 32

187

33,376

28, 902 4,474

244,750

2,216 4,580 1,726

3,836 6,687 1,120

5,697

1,915 1,241 2,541

6,064

50,280

2,820

9,467 37, 993

6,673 6,61A

599

1,909

90

2,602

435

362

617

254 452

3,000 237

2,814

207 1,287 134 893 227 9 57

7, 666

5,392 2,274

56

SYNTHETIC ORGANIC CHEMICALS. 1965 TABLE 21A. — Miscellaneous chemicals; U.S. production and sales , 1965-

Qaantity

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Textile chemicals, other than surface-active agents — All other miscellaneous cyclic chemicals

MISCELLANEOUS CHEMICALS, ACYCLIC

Total

Acetaldehyde

Acetic acid, synthetic, IWf,5

Acetic acid salts, total

Copper acetate

Potassium acetate

Sodium acetate

Zinc acetate

Zirconium acetate

All other

Acetic anhydride, 100$, from all sources

Acetone, total

From cumene

From isopropyl alcohol

All other

Acrylic acid

Acrylonitrile

Adipic acid

Alcohols, monohydrie, unsubstituted, total

Alcohols C9 or lower, total

Butyl alcohols, total

Iso ( Isopropylcarbinol)

Normal ( n-Propylcarbinol)

All other

Ethyl alcohol, synthetic6

2-Ethyl-l-hexanol

Hexyl alcohol

Iso-octyl alcohols

Isopropyl alcohol

Methanol, synthetic

All other

Alcohols C10 or higher, total

Decyl alcohols

1-Hexadecanol (Cetyl alcohol) (95$)

1-Octadecanol (Stearyl alcohol) (95$)

All other -

Amines, total7

Butylamine

Dihutylamine

Diethylamine

Dimethylamine

Ethylamine

Isopropylamine

Methylamine, mono- -

Trimethylamine

All other-

Bis(2-chloroethyl) ether ( Dichlorodiethyl ether) , all

grades

2-Butanone (Methyl ethyl ketone)

2-Butanone oxime

2-Butanone peroxide

Butyl acetates, total

Normal

All other

See footnotes at end of table.

1,000 pounds

2,820 566,587

49,697,339

1,230,310 1,346,683

25,412

200

3,138

16,331

524

182

5,037

1,531,738

1, 124, 097

746, 879 377,218

40, 938 771,622 865,719

8, 295, 247

7,926,726 827,568

428, 807

398,761

2,039,211

293,203

8,335

126, 742

1,537,988

2,868,578

225, 101

368,521

105,942

2,678

259,901

694, 809

1,206 2,409 7,006 50,005 8,329

30,532

14,085

581,237

317,500 2,735 1,676

131,511

86, 116 45,395

1,956 241,070

21,415,257

1,000 dollars 1,923 132,741

2,645,419

101,920 294,468

23,799

206

3,045

15,662

323

4,563

179, 672

296,305

417,691

27, 669

7,594

303,339

69,991

4, 241, 634

4,095,746

391,484

67, 962

291,711

31,811

1,315,353

149,410

2,183

112, 668

581,509

1,395,137

148,002

145,888

68, 280

2,752

6,912

67,944

163,652

1,805 22,918

6,789 26,574

6,316 99,250

1,981

301, 161

2,807

1,622

123,274

80,430 42,844

6,617 19, 883

5,017

127

596

2,398

183

1,713

11, 908

20,964

1,127

2,162

48,354 16,446

266, 120

242, 869 36,041

5,087 27,383

3,571 76, 688 16,337 366 12,852 35, 982 43,881 20,722 23,251

8,024 742

1,202 13,283

49,440

4,080

1,177

3,848

846

38, 6 M

175

32,376 1,704 2,541

11, 817

7,781

4,036

MISCELLANEOUS CHEMICALS TABLE 21A. -- Miscellaneous chemicals.- U.S. production and sales , 1965— Continued

57

Production

Quantity

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

tert- Butyl hydroperoxide

tert- Butyl peroxide (Di-tert-butyl peroxide)

Butyric acid

Caprolactam (Hexahydro-2H-azepin-2-one)

Carbon disulfide

Cellulose esters and ethers, total

Cellulose esters, total

Cellulose acetate

All other

Cellulose ethers, total

Sodium carboxymethylcellulose, 100$

All other

Chloral (Trichloroaeetaldehyde)

Chloroacetic acid, mono-

Chloroacetic acid, methyl ester

2-Chloro-N, N-dimethylethylamine ( Dimethylaminoethyl

chloride) hydrochloride

Decanoyl peroxide

Dibutyl fumarate

Dibutyl maleate

2-Diethylaminoethanol

Diethylene glycol

Dilauryl 3,3'-thiodipropionate

2-Dimethylaminoethanol

Dioctyl maleate

Dipropylene glycol

Erucamide

Ethanolamines, total

2-Aminoethanol (Monoethanolamine)

2,2'-Iminodiethanol (Diethanolamine)

2, 2 ', 2 " -Nitrilotriethanol ( Triethanolamine)

2- Ethoxyethanol (Ethylene glycol monoethyl ether)

2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl

ether) ;

2-[2-(2-Ethoxyethoxy)ethoxy]ethanol (Triethylene glycol

monoethyl ether)

Ethyl acetate, 85$

Ethyl acrylate

Ethylene glycol

Ethylene oxide

Ethyl ether, all grades

2-Ethylhexanoic acid (a-Ethylcaproic acid) salts, total- Calcium 2-ethylhexanoate

Cobalt 2-ethylhexanoate

Lead 2-ethylhexanoate

Manganese 2- ethylhexanoate

Zinc 2-ethylhexanoate

All other

2-Ethyl-l-hexyl acetate

2-Ethyl-l-hexyl acrylate

Formaldehyde, 37$ by weight

Formic acid, 90$-

Formic acid salts

Fu marie acid

Gluconic acid, tech

Gluconic acid, sodium salt, tech

Halogenated hydrocarbons, total

1-Bromobutane (n- Butyl bromide)

Carbon tetrachloride

Chlorinated paraffins

Chlorodifluoromethane

Chloroethane (Ethyl chloride)

Chloroform

Chloromethane (Methyl chloride)

See footnotes at end of table.

1,000 pounds

145 1,011

290,005 756,512

930, 700

839,392 669, 112 170, 280 91,308 48, 770 42, 538

73,502

71,063

585

353

667

6,120

7,513

3,159

158, 746

1,180

1,794

494

33, 904

451

200, 836

67,474 77, 500 55,862

33,733

6,933

114,013

116,796

1, 797, 935

2,189,798

93,164

4,404

604

227

59

276

3,238

25, 200 3, 106, 572 23, 657 30,518 33,749 3,891 8.01A

9,362,119

593, 636 43,750

685,768 152,510 187,549

1,000 pounds

VA

1,020

478

133,612

541, 605

278,425

193,324

193,324 85,101 45,242 39, 859

532

239 651 5,494 5,419 2,589 134, 994 1,168 1,458

30,602 429

155,038

54,108 52,413 48,517

. 46,560

25,467

3,310

100, 197

47,407

1,197,846

255,952

85, 174

3,261

~27T~ 503 178 56 259 1,991

608 20,529 1,189,434 23,241 25,023 31,615 3,501 7,559

4,042,963

1,000 dollars

286

1,672

144

41,900

'21,691

113,408

66,528

66, 528 46,880 19,057 27,823

190

301

897

1,098

1,054

1,122

13,675

1,152

981

3,652 51A

27,708

10,667 8,176 8,865

7,716

4,446

543 10,425 10,901 104,237 25,994 5,429

3,173

A3

509,439 43,635 49,815 273,944 123,320 94,791

110

549

68

27

129

2,290

169 5,752 30, 199 2,993 1,233 5,181 1,135 2,270

458,045

32 37,486 5,698 30, 193 18,576 9,871 6,437

58 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21A. — Miscellaneous chemicals; U.S. production and sales , 1965-

Chemical

Production

Quantity

MISCELLANEOUS CHEMICALS, ACYCLIC--Continued

Halogenated hydrocarbons — Continued

Dichlorodifluorome thane

1, 2-Dichloroethane (Ethylene dichloride)

Dichloromethane (Methylene chloride)

1, 2-Dichloropropane (Propylene dichloride)

Dichlorotetrafluoroethane

Iodomethane (Methyl iodide)

Lauryl chlorides

Tetrachloroethylene (Perchloroethylene)

Trichloroethylene

Trichlorofluoromethane

Vinyl chloride, monomer ( Chloroethylene)

All other

4-Hydroxy-4-methyl-2-pentanone (Diacetone alcohol)

Isoascorbie acid, sodium salt

Isopropyl acetate

Isopropyl ether

Lauroyl chloride

Lauroyl peroxide

Linoleic acid salts, total3

Calcium linoleate

Cobalt linoleate

All other

Lubricating oil additives, total

Phosphorodithioates ( Dithiophosphates)

Sulfurized lard oil

Sulfurized sperm oil

All other

Maleic anhydride

Mercaptoacetic acid ( Thioglycolic acid)

Mercaptoacetic (Thioglycolic) acid derivatives, total

2-Aminoethyl mercaptoacetate (Monoethanolamine

thioglycolate)

Ammonium mercaptoacetate

Iso-oetyl mercaptoacetate

All other

2-Methoxyethanol (Ethylene glycol monomethyl ether)

2-(2-Methoxyethoxy) ethanol (Diethylene glycol monomethyl

ether)

2- [2-(2-Methoxyethoxy) ethoxy] ethanol (Triethylene glycol

monomethyl ether)

Methyl acetate

Methyl ether (Dimethyl ether)

4-Methyl-2-pentanone (Methyl isobutyl ketone)

Nylon, 6 and 6/6 polymer for fiber-

Oleic acid salts, total8

Copper oleate

All other

Oxalic acid

Oxalic acid salts

Palmitic acid salts

Pal ml toy 1 chloride

Pentaerythritol

Pentaerythritol tetranitrate

Phosgene (Carbonyl chloride)

Phosphorus acid esters, not elsewhere specified, total —

Tributyl phosphate

All other

See footnotes at end of table.

271,408

2,455,907

210,830

61,013

21,762

14

911

429,354

434,510

170,461

2,000,000

1, 642, 667

2,835 45,483

9,526 1,333

138

197 124

417, 817

102, 269

2,562

23,668

289,318

128,226

5,904

272 1,599

4,033

73,801

11,416

3,128

8,887

10,393

168, 874

980, 596

282

247

19,573

6,664

758

225

69,338

4,959

284,671

26,988

4,702 22,286

1,000

poi

nds

254, 202

309, 033

194,504

31,122

18,812 9

384, 978 428, 120 153, 953 687,817 485,426

28,004 2,386

38,033 4,199

1,345

467

138

329

184, 798

48, 146

136, 652

94,411 558

5,394

1,729 3,431

66, W7

151,027

20,752 6,803

69,396 2,767

23,445

4,753 18, 692

1,000

dollars

72, 191

13,932

17, 207

729

10, 947

26

32,447 36, 068 31,318 42, 178 92,709

3,574

3,288

4,018

346

1,401

151

26

125

39, 937

11, 968

27, 969

10,976 525

6,982

181

1,254 5,547

11,233

17,944

3,782 1,542

15,415 2,111

9,943

1,883 8,060

59

TABLE 21A. — Miscellaneous chemicals.- U.S. production and sales , 1965— Continued

Quantity

MISCELLANEOUS CHEMICALS, ACXCLIC--Continued

Polyacrylic acid salts

Polyethylene glycol

Polypropoxy ethers, total

Glycerol tri(polyoxypropylene) ether

All other

Polypropylene glycol

Propionic acid

Propionic acid salts:

Calcium propionate

Sodium propionate

Propylene glycol ( 1, 2-Propanediol)

Propylene oxide

Sarcosine and salt

Sequestering agents, total

(Wethylenetrinitrilo)pentaacetic acid, sodium salt-- ( Ethylenedinitrilo) tetraacetic acid ( Ethylenediamine-

tetraacetic acid)

( Ethylenedinitrilo) tetraacetic acid, tetrasodium salt- ( Ethylenedinitrilo) tetraacetic acid, monohydrogen

trisodium salt

(N-Hydroxyethylethylenedinitrilo) triacetic acid,

trisodium salt

All other

Sodium formaldehydesulfoxylate

Sodium methoxide (Sodium methylate)

Sorbitol

Stearand.de ( Octadecanamide)

Stearic acid salts, total9

Aluminum stearates, total

Aluminum distearate

Aluminum monostearate

Aluminum tristearate

Calcium stearate

Lead stearate

Lithium stearate

Magnesium stearate

Zinc stearate

All other

Tallow amide, hydrogenated

Tetraethyllead

Tetramethyllead and tetra(methyl and ethyl) leads

Triethylene glycol

Urea in compounds or mixtures (100$ basis), total

In feed compounds

In liquid fertilizer

In solid fertilizer

All other

See footnotes at end of table.

1,000 pounds 2,492 39, 698

220, 923

161,250 59, 673

94,059 31,870

12,248 4,369

212,756

604, 559

1,698

35,764

Ijf

3,528 19, 985

3,721 6,057

5,466

4,891

62,471

764

37,546

5,469

3,913 895 661 12,674 421 593

2,370 12,020

3,999

686 549, 176 137, 609 50, 667

2,572,923

300, 865

943,218

1,092,818

236, 022

1,000 pounds 3,326 35,129

190,858

134,476 56,382

80,416 16,801

10,398 5,168

188, 933 69, 254

26, 662

1,734

1,914 13,736

3,266 5,430

5,253 4,267 45,525

34,433

5,306

3,797

883

626

12,324

372

522

2,323

12,000

1,586

548, 177 136,038 41, 733

2,466,882

1.000 dollars 4,030 8,571

36,896

25,767 11,129

Li, 085 1,806

1,930

960

19,709

8,298

10, 668

557 999

1,468 2,408

1,266 1,386 10, 001

12,588

305,309

915,203

1,085,567

160, 803

1,931

1,366 341 224

4,188 146 264 888

4,424 747

297,480 78,001 7,024

1 99,587

12,410

36,791

43,399

6,987

60

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21A. — Miscellaneous chemicals: U.S. production and sales , 1965 — Continued

Quantity

Unit value1

MISCELLANEOUS CHMICALS, ACYCLIC— Continued

Vinyl acetate, monomer

Zinc formaldehydesulfoxylate

All other miscellaneous acyclic chemicals

1,000 pounds 511,951 1,490 6,349,894

1,000 pounds 259,099 1,454 1,582,690

1,000 dollars 27, 837 657 443,025

pound

$0.11 .45 .28

1 Calculated from rounded figures.

2 Statistics exclude production and sales of tricresyl phosphate. Statistics on tricresyl phosphate are given in the section "Plasticizers."

3 Quantities are given on the basis of solid naphthenate, tallate, or linoleate content.

* Statistics exclude production and sales of copper naphthenate. Statistics on copper naphthenate are given in the section "Pesticides and Other Organic Agricultural Chemicals."

5 In addition, sales of recovered acetic acid totaled 76,641 thousand pounds, valued at 4,466 thousand dollars.

6 Statistics on production of ethyl alcohol from natural sources by fermentation are issued by the Alcohol Tax Unit, U.S. Internal Revenue Service.

7 Statistics exclude production and sales of fatty amines. Statistics on fatty amines are given in the section "Surface- Active Agents. "

8 Statistics exclude production and sales of potassium and sodium oleates. Statistics on these oleates are in- cluded in the section "Surface- Active Agents."

5 Statistics exclude production and sales of potassium and sodium stearates. Statistics on these stearates are included in the section "Surf ace- Active Agents."

10 Production of urea in primary solution totaled 2,789,089 thousand pounds.

11 Includes estimated values for sales of urea in nitrogen compounds.

The total output of miscellaneous cyclic chemicals in 1965 was 1. 14 billion pounds, or 2. 1 percent more than the output of 1. 11 billion pounds reported for 1964. Sales in 1965 totaled 625 million pounds, valued at $245 million, compared with 604 million pounds, valued at $224 million, in 1964. The most important subgroup of cyclic compounds was the lubricating oil additives, the output of which was 355 million pounds in 1965.

Total production of miscellaneous acyclic chemicals in 1965 was 49. 7 billion pounds--ll. 5 percent more than the output of 44. 6 billion pounds reported for 1964. Sales in 1965 totaled 21.4 billion pounds, valued at $2. 6 billion, compared with 19. 9 billion pounds, valued at $2. 4 billion, in 1964.

Production of alcohols and halogenated hydrocarbons in 1965 each exceeded that of any of the use groups of synthetic organic chemicals except cyclic intermediates and plastics and resin materials. Production of monohydric, unsubstituted alcohols totaled 8.3 billion pounds in 1965, or 4. 5 percent more than in 1964. Alcohols are used as solvents, intermediates, and antifreeze materials, and for other purposes. Production of halogenated hydrocarbons totaled 9.4 billion pounds in 1965, or 15.4 percent more than the 8. 1 billion pounds reported for 1964. Halogenated hydrocarbons are used as solvents, intermediates, refrigerants, and aerosol propellants, and for other purposes.

Individual chemicals the output of which exceeded 1 billion pounds in 1965 were formaldehyde (3. 1 billion pounds, compared with 2. 8 billion pounds in 1964); synthetic methanol (2. 9 billion pounds, compared with 2. 6 billion pounds in 1964); urea (2.6 billion pounds, compared with 2.4 billion pounds); dichloroethane (2. 5 billion pounds, compared with 2. 2 billion pounds); ethylene oxide (2. 2 billion pounds, in each year); ethyl alcohol (2. 04 billion pounds, compared with 2. 07 billion pounds); vinyl chloride (2.0 billion pounds, compared with 1.6 billion pounds); ethylene glycol (1.8 billion pounds, in each year); isopropyl alcohol (1.5 billion pounds, in each year); and acetic anhydride (1. 5 billion pounds, compared with 1.4 billion pounds).

PART IE. ALPHABETICAL LIST OF INDIVIDUAL PRODUCTS, BY GROUPS, AND NAMES OF MANUFACTURERS

This section of the report consists of (1) a series of tables that supplement the statistical information given in parts I and II, and (2) a Directory of Manufacturers. The tables with num- bers that include the letter "B" supplement the tables in part I or part II with numbers that in- clude the letter "A"; for example, table 8B in part III supplements table 8A in part II.

Each table in part III lists alphabetically the individual items in each group for which data on production or sales were reported for 1965. The tables include data on only those chemicals for which the volume of production or sales in 1965 exceeded 1,000 pounds or for which the value of sales exceeded $1,000. Where separate statistics for an item are given in the tables in part I or part II, an asterisk (*) precedes the name of the item in the tables in part III. The manufac- turers of each product are indicated by identification codes which are listed in the Directory of Manufacturers (table 22). A few companies, however, have specifically requested that they not be identified as having produced or sold certain items. These manufacturers are indicated by a small letter "x" in the tables.

Tar Crudes TABLE 4B. — Tar crudes for which U.S. production or sales were reported, identified by manufacturer , 1965

[Tar crudes for which separate statistics are given in table 4A are marked below with an asterisk (*); products not so marked do not appear in table 4A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. Table 22 identifies all U.S. producers of tar crudes (except producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines)]

Manufacturers ' identification codes (according to list in table 22 J1

*Crude light oil

Light-oil distillates:

*Benzene, specification and industrial grades

*Toluene, specification and other grades

*Xylene, all grades

^Solvent naphtha

*A11 other light-oil distillates

Pyridine crude bases

*Naphthalene , crude, solidifying at —

*Less than 74° C

*74° C. to less than 76° C

*76° C. to less than 79° C

Crude tar-acid oils having a tar-acid content of —

5<f> to less than 24$

24$ to 51$

Cresylic acid, crude

*Creosote oil (Dead oil):

^Distillate as such

^Creosote in coal-tar solution

All other distillate products

*Tar, road

*Tar for other uses:

Crude

Refined

Pitch of tar:

Soft and medium (water softening points less than 110° F., and 110° F. to 160° F.)..

*Hard (water softening point above 160° F.)

Pitch-of-tar coke and pitch emulsion

ACY,

KPP.

ACY,

KPP.

ACY,

KPP.

ACY,

KPT,

NEV,

PAI.

ACP,

PAI.

ACP,

KPT.

COP.

KPT.

ACP,

KPT,

PRD,

RIL.

ACP,

RIL.

ACP,

KPT,

RIL.

ACP,

KPT,

PRD.

ACP,

CBT,

COP,

HUS,

KPT,

RIL, WTC

ACP,

JEN,

KPT,

RIL.

ACP,

KPT,

PAI.

ACP,

KPT,

RIL,

WTC.

KPT,

RIL.

ACP,

KPT,

RIL,

RUR.

ACP,

CBT,

COP,

JEN,

KPT,

RIL.

ACP,

COP,

HUS,

KPT,

RIL.

JEN,

RIL.

1 Does not include manufacturers ' identification codes for producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey, Aug. 10, 1966, entitled "Coke Producers in the U.S. in 1965."

2 Crude light oil production and sales of this company are not included with the U.S. Bureau of Mines figures given in table 4A.

61

62

SYNTHETIC ORGANIC CHEMICALS, 1965

Crude Products From Petroleum and Natural Gas for Chemical Conversion

TABLE 5B. — Crude products from petroleum and natural gas for chemical conversion for which U.S. production or sales were reported, identified by manufacturer, 1965

[Crude products from petroleum and natural gas for chemical conversion for which separate statistics are given in table 5A are marked below with an asterisk (*); products not so marked do not appear in table 5A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown be- low are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers ' identification codes (according to list in table 22)

AROMATICS AND NAPHTHENES

*Alkyl aromatics, distillates, and solvents

^Benzene (except motor grade):

*Benzene, 1°

*Benzene, 2°

Cresylic acid, crude

*Naphthalene, all grades

*Naphthenic acids:

Acid number lower than 150

Acid number 150-199

Acid number 200-224

Acid number 225-249

Sodium carbolate and phenate, crude

*Toluene :

^Nitration grade, 1°

*Pure commercial grade, 2°

Solvent grade

All other

*Xylenes, mixed:

Aviation grade

*3°~ —

5°

All other

All other aromatics and naphthenes

ALIPHATIC HYDROCARBONS

Ci hydrocarbon: Methane

*C2 hydrocarbons:

^Acetylene

*Ethane

^Ethylene

C2 and C3 hydrocarbons, mixed

*C3 hydrocarbons:

*Propane

Propane -propylene mixture

*Propylene

*Ci, hydrocarbons:

*1,3-Butadiene, grade for rubbers (elastomers)'

*Butadiene and butylene fractions

ACC, DUP, EN J, FG, GOC, JCC, MOC, MON, CMC, PLC, SHC, SM, SOC, SOG, USI, VPT.

ACU, APR, ASH, ATR, CCP, COR, CSD, DLH, DXS, ENJ, GOC, GRS, MOC, MON, PLC, PRO, RIC, SHO, SKO, SM, SNT, SUN, TOC, TX, VPT.

ACC, AMO, CO, DOW, SHO, SOC, UCC.

ATR, PRD, RIC, SHO.

ASH, COL, MON, SUN, TID.

RIC, SUN, TX. PRD, RIC, SM, SOC, SUN. PRD, RIC, SM, SOC. PRD, RIC, SM, SOC. ATR, GOC, SIN.

ASH, ATR, COR, CSD, DLH, ENJ, GOC, LEN, MOC, MON, PLC, PRO, SHC, SHO, SIN, SNT, SOG, SUN, TOC, TX, UCC, VPT.

DOW, MON, RIC.

CO, FG, SKO.

ACC, CSD, CSO, DXS, ELP, GRS, RIC, SHO, SM, SOC, TOC, TX, VPT.

CSD, CSO, SOG.

ASH, ATR, COR, DLH, MON, PRO, SNT.

SIN, SUN, TX.

AMO, CCP, CSD, ENJ, GRS, LEN, MOC, RIC, SHO, SM, SOC,

SOG, SUN, TOC, VEL, VPT. COR, ELP, ENJ, JCC, LEN, PAS, PLC, SM, SOI.

CCP, MOC, MON, PAN.

ACY, DOW, DUP, MNO, MON, UCC, x.

ACU, CCP, ENJ, MOC, MON, PAN, PLC, SHC, SHO, SM, SOI,

TX, UCC, USI. CCP, DOW, DUP, EKX, ELP, ENJ, GOC, JCC, KPP, MOC, MON,

OMC, PET, PLC, RIC, SHC, SM, SNO, TX, UCC, USI. COR, GYR, MON, PLC.

AMO, ASH, CCP, CSD, DXS, ENJ, GRS, SHM, SHO, SIN, SM, SNT, SOG, SOI,

GOC, TX.

AMO, ASH, CCP, DOW, EKX, ELP, ENJ, PET, PLC, RIC, SHC, SHO, SIN, SM, UCC, UOC.

CPY, DOW, ELP, ENJ, FRS, GGC, ILC,

SHC, SM, SOC, SPI, TID, TUS, UCC.

DOW, GYR, PLC, PTT, SHC, SHO, SIN,

MOC, OMC, SPI, UCC,

GOC, JCC, SOG, SOI..

PAN, PLC, UOC, USI.

MOC, MON, SPI, SUN,

MON, PET, PLC, PTT, SOC.

CRUDE PRODUCTS FROM PETROLEUM AND NATURAL GAS

63

TABLE 5B. —Crude products from petroleum and natural gas for chemical conversion for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

ALIPHATIC HYDROCARBONS— Continued

*C* hydrocarbons — Continued

*n-Butane

1-Butene

2-Butene

*1-Butene and 2-butene mixture

*Isobutane

*Isobutylene

All other

*d hydrocarbons:

Isopentane ( 2-Methylbutane ) ;

Isoprene (2-Methyl-l,3-butadiene)

n-Pentane

All other :

C6 hydrocarbons:

Diisopropyl (2,3-Dimethylbutane)

Hexane

Neohexane (2,2-Dimethylbutane)

All other

C7 hydrocarbons:

n-Heptane

*Heptenes, mixed

All other

Cs hydrocarbons:

*Diisobutylene (Diisobutene)

n-Octane

2,2,4-Trimethylpentane (Iso-octane)

All other

Hydrocarbons, C9 and above:

Eicosane

*Nonene ( Tripropylene )

Pentadecene

*Polybutene

*Tetrapropylene

Tridecene concentrate

Triisobutylene

All other

*Hydrocarbon derivatives :

1-Butanethiol

tert-Butyl mercaptan (2-Methyl-2-propanethiol)

Di-tert-butyl disulfide

Ethyl mercaptan (Ethanethiol)

Isopropyl mercaptan

Methyl mercaptan (Methanethiol)

tert-Octyl mercaptan

n-Propyl mercaptan (1-Propanethiol)

All other '■

*A11 other aliphatic hydrocarbons: Alpha olefins, molecular weight ranges:

C6"C7

C8-C10

C11-C15

Cl6_C20

All other

COR, CSD, DXS, ELP, GRS, MOC, OMC, PAN, PLC, SHO,

SM, SNT, SOC, SOG, SOI, UCC, USI. PLC, PTT. MON, PLC, PTT.

AMD, ENJ, GOC, PLC, PRO, PTT, SHO, SOC, SPI, TX. CCP, DXS, ELP, ENJ, GRS, MOC, OMC, PAN, PLC, SHO,

SOI, UCC, USI. CCP, ENJ, PLC, PRO, PTT, SIN. APR, JCC, MOC, MON, PLC, SM, SOI, UCC, USI.

CCP, CSD, PLC, SHO, SM, SOI, UCC.

ENJ, GYR, SHC.

APR, PLC.

ENJ, GYR, MOC, MON, PAS, PET, PLC, USI.

PLC. ENJ, PLC. APR,

EKX, CSD, PLC.

ATR, ENJ, ENJ. PLC.

ATR. AMO,

PLC, PRO. PLC, SOG.

ENJ, PLC, PRO.

ENJ, GOC, HOU, SIN, SOG, SOI, TID.

ENJ, PTT, TX. PLC.

ATR, CO, ENJ, GOC, PAS, PRO, RIC.

CSD, SOC, SOI. DXS, ENJ, GOC, MOC, PRO, RIC, SNT, SOC, SUN, TX.

ACC

CO,

ENJ.

ATR.

CO, ENJ, GOC, HOU, KEN, PLC, SOC, SUN, TID, UCC, x

PAS. PAS, PAS, CSD, PAS, ACC, PAS, PAS, EKX,

PLC.

PLC.

PAS, SOC, x.

SOC.

PAS.

PLC.

PLC.

PAS, PLC, SOC.

GOC, GYR, PLC, SOC.

ENJ, GOC, SOC.

ENJ, GOC, SOC. GOC.

EKX, SOC.

64

SYNTHETIC ORGANIC CHEMICALS, 1965

Cyclic Intermediates

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Cyclic intermediates for which separate statistics are given in table 7A are marked below with an asterisk (*); cyclic intermediates not so marked do not appear in table 7A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers' identification codes (according to list in table 22)

Aceanthryleno[2, 1-a] aceanthrylene-5, 13-dione

8-Aeetamido-l-(4-acetamido-2-hydroxy-5-nitrophenylazo)- 2-naphthol.

4-Acetamido-2-aminobenzenesulfonic acid

p-Acetamidobenzoic acid

2-Acetamido-3-chloroanthraquinone

*Acetanilide, tech

Acetic acid, phenyl ester

Acetoacetanilide

o-Aeetoacetanisidide

o-Acetoacetotoluidide

2',4'-Acetoacetoxylidide

p-Acetoanisidide

1' -Acetonaphthone

Acetone phenylhydrazone

p-Aeetophenetidide

Acetophenone, tech

p-Acetotoluidide

N-Acetylanthranilic acid

p-Acetylbenzenesulfonamide

p-Acetylbenzenesulfonic acid, sodium salt

p-Acetylbenzenesulfonylurethane

1-(N- Acetyl )methylamino-4-bromo an thraquinone

N-Acetylsulfanilic acid, sodium salt

*N-Acetylsulfanilyl chloride

Adenine

*Alkylbenzenes :

Dodecylbenzene (including tridecylbenzene) :

Straight chain

Other

Other alkylbenzenes:

Straight chain

Other

Alkylphenols, mixed

Alkylpiperazines, mixed

Alkylpyridine

a-dl-5-Allyl-6-imino-l-methyl-5-(l-methyl-2-pentynyl)-

barbituric acid. a-dl-5-Allyl-5-(l-methyl-2-pentynyl)-l-methyl barbi- turic acid. Aminoaceanthryleno [2, 1-a] aceanthrylene-5, 13-dione

*4-'-Aminoacetanilide (Acetyl-p-phenylenediamine)

3'-Aminoacetophenone

*5-Amino-2-(p-aminoanilino)benzenesulfonic acid

l-Amino-4— (3-amino-<t-sulfoanilino)-9, 10-dihydro-9, 10-

dioxo-2-anthracenesulfonic acid. 1- Amino-4- (4-amino-3-sulf oanilino ) -9, 10-dihydro-9, 10-

dioxo-2-anthracenesulfonic acid. 5-Amino-2-anilinobenzenesulfonic acid

*2-(p-Aminoanilino)-5-nitrobenzenesulfonic acid

3-Amino-p-anisanilide

5-Amino-2-o-anisidinobenzenesulfonic acid

*l-Aminoanthraquinone and salt

*2-Aminoanthraquinone and salt

N-(4-Amino-l-anthraquinonyl)anthranilic acid

N-(5-Amino-l-anthraquinonyl)anthranilic acid

N-(8-Amino-l-anthraquinonyl)anthranilic acid

4-Aminoantipyrine

*6-Amino-3,4'-azodibenzenesulfonie acid (C.I. Acid Yellow 9).

8-Aminobenz [a] acridan-12-one

p-Aminobenzamide

*l-Amino-4-benzamidoan thraquinone

*l-Amino-5-benzamidoan thraquinone

ICI. TRC.

G.

DUP.

G.

CTN,

UCC.

FMP,

FMP,

FMP,

FMP,

AAP.

GIV.

DUP.

AAP.

ACP,

ACY.

DUP.

LIL.

LIL.

LIL.

AAP.

ALL.

ACY,

AHA.

EKT, MRK, SAL, SW.

UCC. UCC. UCC. UCC.

CTN, MRK, SAL.

CO, MON, NAC, PLC, SOC, UCC, WCC. ATR, CO, NAC.

CO, SOC.

ATR.

G, 0R0.

HOU.

UCC.

LIL.

LIL.

ICI.

DUP, G, NAC, TRC.

CTN, SDH, SDW.

AAP, CMG, DUP, G, TRC, YAW.

TRC.

TRC.

NAC.

CMG,

PCW.

TRC.

AAP,

ACY,

G.

DUP.

DUP.

SDW.

AAP,

DUP, NAC, TRC.

ACY, DUP, G, ICI, MAY, NAC, TRC. DUP, G, NAC, TRC.

CMG, DUP, NAC, TRC.

NAC.

SDH.

ACY, MAY, NAC, TRC.

G, ICI, NAC, TEC.

CYCLIC INTERMEDIATES

65

TABLE 7B.

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

7-[p-(p-Aminobenzamido)benzamido] -4-hydroxy-2-naphthalene-

sulfonic acid. 7-(m-Aminobenzamido )-4-hydroxy-2-naphthalenesulf onic acid- *7-(p-Aminobenzamido )-4-hydroxy-2-naphthalenesulfonic acid- 7-(p-Aminobenzamido )-5-hydroxy-3-naphthalenesulf onic acid- s'- Aminobenzanilide

4'-Aminobenzanilide

*2-Amino-p-benzenedisulfonic acid [S03H = l]

o-Aminobenzenethiol

2-Aminobenzimidazole

5-Amino-2-benzimidazolinone

p-Aminobenzoic acid, tech

p-Aminobenzoic acid, 2-(diethylamino)ethyl ester (Procaine

p-Aminobenzoic acid, 2-(dimethylamino)ethyl ester

2-Amino-6-benzothiazolecarboxylic acid

2-(m-Aminobenzoyl)-o-acetanisidide

l-Amino-4-bromo-2-chloroanthraquinone

2-Amino-l-bromo-3-chloroanthraquinone

5(and 8)-Amino-8(and 5)-bromo-9, 10-dihydro-9, 10-dioxo- l,6(and l,7)-anthracenedisulfonic acid. *l-Amino-4-bromo-9, 10-dihydro-9, 10-dioxo-2-anthracene- sulfonic acid and sodium salt.

*l-Amino-2-bromo-4-hydroxyanthraquinone

l-Amino-4-bromo-2-methylanthraquinone

*l-Amino-2-bromo-4- p-toluidinoanthraquinone

l-Amino-2-chloroanthraquinone

*l-Amino-5-chloroanthraquinone

l-Amino-8-chloroanthraquinone

2-Amino-l-chloroanthraquinone

2-Amino-3-chloroanthraquinone

4- Amino-6-chloro-m-benzen edisulfonami.de

4- Amino-6-chloro-m-benzenedisulfonamide hydrochloride

5-Amino-2-chlorobenzoic acid

2-Amino-5-chlorobenzophenone

2-Amino-6-chlorobenzothiazole hydrochloride

*o-(3-Amino-4-chlorobenzoyl)benzoic acid

2-Amino-5-chloro-p-cumenesulfonic acid

2-Amino-5-chloro-4-ethylbenzenesulfonic acid

l-Amino-2-chloro-4-hydroxyanthraquinone

*3-Amino-5-chloro-2-hydroxybenzenesulfonic acid

2-Amino-4— chlorophenol

2-Amino-6-chloropyrazine

3-Amino-6-chloropyridazine

*2-Amino-5-chloro-p-toluenesulfonic acid [S03H=1]

*6-Amino-4-chloro-m-toluenesulfonic acid [S03H=1]

2-Amino-p-cresol

*l-Amino-2,4-dibromoanthraquinone

5(and 8)-Amino-6,8(and 5,7)-dibromo-9,10-dihydro-9,10- dioxo-1-anthracenesulfonic acid.

l-Amino-5, 8-dichloroanthraquinone

4'-Amino-2',5/-diethoxybenzanilide

3-Amino-7-(diethylamino)-5-phenylphenazinium chloride

l-Amino-9, 10-dihydro-9, 10-dioxo-2-anthracenesulf onic acid— 5(and 8 )-Amino-9, 10-dihydro-9, 10-dioxo-l-anthracenesulfonic acid. *l-Amino-9, 10-dihydro-9, 10-dioxo-4-p-toluenesulf onamido- 2-anthracenesulfonic acid, sodium salt.

4-Amino-l,3-dihydroxyanthraquinone

5-Amino-4, 5/-dihydroxy-3,4'-[(2-methoxy-5-methyl-p- phenylene)bis(azo)] -di-2,7-naphthalenedisulfonic acid, 5' -benzenesulf onate.

2-Amino-4-(a,a-dimethylbenzyl)phenol

2-Amino-N, N-dimethyl-p-toluenesulfonamide

2-Amino-4, 6-dinitrophenol and salt

3-Amino-4-ethoxyacetanilide

3-Amino-9-ethylcarbazole

p-Amino-N-ethyl-N-1-naphthylbenzamide

Aminoethylpiperazine

l-Amino-4-hydroxyanthraquinone 1

2-Amino-3-hydroxyanthraquinone

5-Amino-4-hydroxy-m-benzenedisulfonic acid

Manufacturers' identification codes (according to list in table 22)

CMG,

DUP.

TRC.

CMG,

DUP,

G, NAC.

VPC.

DUP.

G, TRC.

DUP,

G, NAC, TRC.

FMT.

EK.

DUP.

DUP,

G.

LM.

SDW.

DUP.

G.

AAP.

ICI,

MAY.

TRC.

AAP,

DUP,

G, ICI, NAC, TRC.

AAP,

DUP,

ICC, TRC.

ICI.

G, ICI, TRC.

AAP.

ACT,

DUP,

ICI, MAY, NAC, TRC

DUP,

NAC.

DUP,

G.

G, ICI.

ABB.

ABB.

TRC.

COK,

ICI,

TBK.

DUP.

AAP,

G, ICI.

SW.

ACY,

SW.

AAP.

CMG,

NAC,

TRC.

G, MEE.

ACY.

ACY.

ACY,

HSC,

SW.

ACY,

DUP,

HSC, NAC, SW.

TRC,

X.

AAP,

DUP,

ICC, ICI, NAC, TRC.

ICI.

TRC.

ALL.

DUP.

G.

ICI,

TRC.

AAP,

DUP,

G.

DUP, G.

AAP.

AAP.

G.

UCC.

G.

G, NAC.

TRC.

66

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE IB.-- Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, i965--Continued

l-Amino-4- [(m-2-hydroxyethylsulf onyl )anilino] -9, 10- dihydro- 9, 10-dioxo-2-anthracenesulf onic acid.

l-Amino-4-hydroxy-2-methoxyanthraquinone

4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid, benzene-

sulfonate. 3-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (2R acid),

monosodium salt. 4-Amino-5-hydroxy-l,3-naphthalenedisulfonic acid (Chicago

acid), monosodium salt. *4-Amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H acid),

monosodium salt. *4-Amino-3-hydroxy-l-naphthalenesulfonic acid (1,2,4- acid) — 4-Amino-5-hydroxy-l-naphthalenesulfonie acid (S acid),

sodium salt. *6-Amino-4-hydroxy-2-naphthalenesulfonic acid (Gamma acid),

sodium salt. *7-Amino-4-hydroxy-2-naphthalenesulf onic acid ( J acid ),

sodium salt.

3-Amino-l-hydroxy-2-naphthanilide

3'-Amino-2'-hydroxy-5'-nitroacetanilide

6-Amiiio-5-[ (2-hydroxy-4-nitrophenyl)azo] -2-naphthalene-

sulfonic acid. 2-(2-Amino-5-hydroxy-7-sulfo-l-naphthylazo)-5-nitrobenzoic

acid. l-(6-Anuno-l-hydroxy-3-sulfo-2-naphthylazo)-6-nitro-2-

naphthol-4-sulfonic acid.

5-Aminoisophthalic acid

4-Amino-3- ((3 -methanesulf anamidoethyl )-N, N-diethylaniline

hydrochloride.

3-Amino-4- methoxyacetanilide

*N-(4-Amino-3-methoxy-l-anthraquinonyl)-p-toluenesulfon-

amide.

5-Amino-6-methoxy-2-naphthalenesulfonie acid

m- [(4-Amino-3-methoxyphenyl )azo]benzenesulf onic acid

8-Amino-6-methoxyquinoline

4-[(4-Amino-5-methoxy-o-tolyl)azo]-4-hydroxy-2,7-

naphthalenedisulfonie acid, benzenesulfonate. 3- [(4- Amino-5-rnethoxy-o-tolyl)azo]-l, 5-naphthalenedi- sulf onic acid. 7-[(4-Amino-5-methoxy-o-tolyl)azo] -1,3-naphthalenedi- sulfonic acid.

*4'-Amino-N-methylacetanilide

l-Amino-2-methylanthraquinone

2-Amino-5-(6-methyl-2-benzothiazolyl)benzenesulfonicacid — 4-Amino-4'-(3-methyl-5-oxo-2-pyrazolin-l-yl)-2,2'-stil- benedisulfonic acid.

8-Amino-7-methyl-l-phenazinol (Tolazine base)

8-Amino-7-methyl-2-phenazinol

2-Amino-3-methylpyridine

2-Amino-5-methylpyridine

2-Amino-6-methylpyridine — - —

2-Amino-4-methylpyrimidine (2-Amino-4-methyl-l,3-diazine) —

2-Amino-4-(methylsulfonyl)phenol

2-Amino-5-methyl-l,3,4-thiadiazole

l-Amino-2-methyl-4-p-toluidinoanthraquinone

l-Aminonaphth[2,3-c]acridan-5,8,14-trione

l(and 4)-Aminonaphth[2,3-c] acridan-5,8,14-trione

4-Aminonaphth[2,3-e]acridan-5,8, 14-trione

6-Aminonaphth[ 2, 3-c]acridan-5, 8, 14-trione

*2-Amino-l, 5-naphthalenedisulf onic acid

*3-Amino-l, 5-naphthalenedisulf onic acid (C acid)

3-Andno-2,7-naphthalenedisulfonic acid

4- Amino-1, 5-naphthalenedisulf onic acid

4-Amino-l,6-naphthalenedisulfonic acid

*6-Anri.no-l,3-naphthalenedisulfonic acid (Amino I acid)

*7- Amino-1, 3-naphthalenedisulf onic acid (Amino G acid)

6-Amino-l-naphthalenesulfonamide

l-Amino-2-naphthalenesulfonic acid (o-Naphthionic acid)

2-Amino-l-naphthalenesulfonic acid (Tobias acid)

*4-Amino-l-naphthalenesulfonic acid (Naphthionic acid)

4-Amino-l-naphthalenesulfonic acid, sodium salt

Manufacturers ' identification codes (according to list in table 22)

TRC.

TRC.

DUP, NAC.

DUP, NAC.

DUP, MON, NAC.

ACY, G, NAC, TRC, VPC. NAC.

DUP, G, NAC, TRC.

BKS, CMG, DUP, G, NAC, TRC.

TRC. TRC.

AAP.

AAP, DUP, G.

NAC, TRC. DUP, TRC. SDW.

TRC.

TRC.

CMG,

G, NAC.

DUP,

ICI.

G.

TRC.

NAC.

DUP.

RIL.

RIL.

NEP,

RIL.

ACY.

NAC,

TRC.

ACY.

ICI.

DUP.

NAC.

DUP.

G.

ACY,

SDH,

SW.

G, NAC, TRC.

TRC.

NAC.

DUP.

ACY,

DUP,

G, NAC,

ACY,

DUP,

G, NAC,

VPC.

DUP.

ACY,

HSC,

IMP, SW.

ACY,

DUP,

NAC.

DUP,

NAC.

67

TABLE 7B.

- Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

4(and 5)-Amino-l-naphthalenesulfonic acid

5-Amino-l-naphthalenesulfonic acid (Laurent's acid)

*5-Amino-2-naphthalenesulfonic acid (l,6-Cleve's acid)

*5(and 8)-Amino-2-naphthalenesulfonic acid (Cleve's acid, mixed).

*6-Amino-2-naphthalenesulfonic acid (Broenner's acid)

6(and 7)-Amino-l-naphthalenesulf onic acid

*8-Amino-l-naphthalenesulfonic acid (Peri acid)

*8-Amino-2-naphthalenesulfonic acid (1,7-Cleve's acid)

7-Amino-l,3,6-naphthalenetrisulfonic acid

8-Amino-l,3,6-naphthalenetrisulfonic acid (Koch's acid)

5 (and 8)-Amino-2-naphthol

*8-Amino-2-naphthol

3-Amino-5-(m-nitrobenzamido)-p-toluenesulfonic acid

*2-Amino-5-nitrobenzenesulfonic acid [S03H=l]

4-Amino-3-nitrobenzoic acid

*2-Amino-4-nitrophenol

2-Amino-5-nitrophenol

4-Amino-2-nitrophenol

2-Amino-l-(p-nitrophenyl)-l,3-propanediol

4-Amino-4'-nitro-2,2'-stilbenedisulfonic acid

2-Amino-5-nitrothiazole

*3' -Amlnooxanilic acid

4' -Aminooxanilic acid

3-Amino-2-oxazolidinone

5-Anuno-2-[(2-oxo-5-benzimidazolinyl)amino]benzenesulfonic acid.

p-Aminophenethyl alcohol

5-Amino-2-o-phenetidinobenzenesulfonie acid

o-Aminophenol

p-Aminophenol

m-[ (p-Aminophenyl)azo] benzenesulfonic acid

*p-[ (p-Aminophenyl )azo] benzenesulf onic acid

7-[ (4-Aminophenyl)azo] -1,3-naphthalenedisulfonic acid

5-Anino-8-(phenylazo)-2-naphthol

8-Amino-5-(phenylazo)-2-naphthol

5-[ (p-Aminophenyl )azo] salicylic acid

2-(p-itainophenyl)-6-methylbenzothiazole

2-(p-Jtoiinophenyl )-6-methyl-7-benzothiazolesulf onic acid and salt.

l-(m-Aninophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid

2-JSminopyridine

4-Aminopyridine

2-Aminopyrimidine

5-Jtadnosalicylic acid

N-(4-Amino-3-sulfo-l-anthraquinonyl)anthranilic acid

3 ' - (3-Am.no-4-sulf ophenylsulf amoyl ) -3 " -sulf amoyl-3-

phthalocyaninesulfonic acid, copper derivative. l-Jtaiino-2,3, 6, 7-tetr ahydro-4, 5, 8-trihydroxyanthraquinone---

2-Aminothiazole •

3-itad.no-p-toluamide

5-Amino-o-toluenesulfonanilide

*4-Anino-ni-toluenesulfonic acid [S03HJ.]

*6-Amino-m-toluenesulfonie acid [S03H=1]

*5-Amino-2-p-toluidinobenzenesulfonic acid

3- [(4-Amino-o-tolyl )azo] -1, 5-naphthalenedisulf onic acid

7- [(4-Amino-o-tolyl)azo] -1,3-naphthalenedisulfonic acid

16-Aminoviolan throne

2-Jimino-3,5-xylenesulfonic acid [S03H=1]

5-Anino-2,4-xylenesulfonic acid

*Aniline (Aniline oil)

Aniline hydrochloride

l-Anilino-9, 10-dihydro-9, 10-dioxo-2-anthroic acid

l-Anilino-4-hydroxyanthraquinone

6-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl gamma acid). *7-Anilino-4-hydroxy-2-naphthalenesulfonic acid (Phenyl J acid).

*Anilinomethanesulfonic acid and salt

*8-Anilino-l-naphthalenesulfonic acid (Phenyl peri acid)

m-Anilinophenol

p- Anisic acid

Manufacturers' identification codes (according to list in table 22)

ACY

TRC.

DUP

NAC.

DUP

G, NAC, TRC.

ALL,

DUP, G, NAC.

ALL,

KLS, NAC, SNA, TRC.

VPC

DUP,

NAC, SDC, TRC.

DUP,

G, NAC, TRC.

DUP.

DUP,

NAC.

G.

CMG,

G, TRC, VPC.

G.

ACY,

DUP, G, NAC, TRC.

DUP.

DUP,

G, NAC, TRC.

NAC.

ACY,

VPC.

PD.

G, NAC, TRC.

ACY.

CMG,

DUP, TRC, VPC.

DUP.

NOR.

DUP.

EKT.

NAC.

FMT.

ABB,

DUP, SDC.

AAP,

DUP, TRC.

ACY,

CMG, DUP, G, NAC, TRC

TRC.

ALL.

ALL.

TRC,

VPC.

DUP,

NAC.

DUP,

TRC.

TRC,

VPC.

NEP,

RIL.

RIL.

ACY.

AAP,

TRC.

G.

DUP.

DUP.

ACY,

MRK.

SDH.

G.

ACY,

DUP, G, SNA.

DUP,

HSC, NAC, SW.

DUP,

NAC, TRC.

TRC.

TRC.

ACY,

G.

DUP.

DUP.

ACY,

DOW, DUP, NAC.

ACY.

NAC.

AAP.

DUP,

NAC.

ALT, CMG, DUP, NAC, TRC.

AAP, ACY, DUP, NAC, TRC, VPC. CMG, DUP, NAC, SDC.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B.

■Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 --Continued

Manufacturers' identification cedes (according to list in table 22)

m-Anisidine

*o-Anisidine '—■

p-Anisidine

l-p-Anisidino-4-hydroxyanthraquinone

*o-Anisidinomethanesulfonic acid

2-o-Anisidino-5-nitrobenzenesulfonic acid

p-Anisoin

Anisole, tech

4- (o-Anisylazo)-o-anisidine

Anthracene, refined

*Anthranilic acid (o-Aminobenzoic acid)

*Anthra[l,9-cd]pyrazol-6(2H)-one (Pyrazoleanthrone)

Anthraquinone, 100$

1,1' -[l,5 (and 1, 8)-Anthraquinonylenediamino]bisnaphth- [ 2,3-c]acridan-5,8, 14-trione.

*N, N'-(l,5-Anthraquinonylene)dianthranilic acid

N, N'-(l,5-Anthraquinonylene)dioxamic acid

N,N'-l,5(and l,8)-Anthraquinonylene dioxamic acid

(l-Anthraquinonyl)-l,2-hydrazinedisulfonic acid, disodium salt.

Anthrone

Arsanilic acid and salt, tech

Aryldiamines, mixed

*4',4'"-Azobis[4-biphenylearboxylic acid]

4' , 4' " - Azobis [ N- ( l-ehloro-2-anthraquinonyl )-4-biphenyl- carboxamide] .

Barbituric acid

Barbituric acid, sodium derivative

*Benzaldehyde, tech

4- [(4— Benzamido-l-anthraquinonyl)amino]naphth[2,3-c]- acridan-5, 8, 14-trione.

N-(5-Benzamido-l-anthraquinonyl)-p-toluenesulfonamide

l-Benzamido-4-bromo anthraquinone

l-Benzamido-4- chloroanthraquinone

*l-Benzamido-5-chloroanthraquinone

l-Benzamido-5, 8-dichloroanthraquinone

4-Benzamido-5-hydroxy-2, 7-naphthalenedisulfonic acid

7-Benzamido-4-hydroxy-2-naphthalenesulfonie acid

N-(4-Benzamido-6-methoxy-m-tolyl)-N-(methylazo)glycine

Benzanilide

*7H-Benz[de]anthracen-7-one (Benzanthrone)

Benzeneboronic acid

m-Benzenedisulfonic acid

Benzenesulfonand.de

Benzenesulfonic acid

Benzenesulfonyl chloride

1,2,4, 5-Benzenetetracarboxylic acid

1, 2,4, 5-Benzenetetracarboxylic-l, 2 :4, 5-dianhydride

1,3,5-Benzenetricarboxylic acid

1,2,4-Benzenetricarboxylic acid, 1, 2-anhydride

Benzhydrol ( Diphenylmethanol )

^Benzidine hydrochloride and sulfate

Benzil (Bibenzoyl) ■

Benzilic acid

2-Benzofuranacetonitrile

^Benzoic acid, tech

Benzoic anhydride

Benzoin

Benzonitrile

Benzophenonetetracarboxylic dianhydride

2-Benzothiazolethiol (2-Mercaptobenzothiazole), sodium salt.

Benzo[b]thiophen-3(2H)-one

lH-Benzotriazole

2H-3,l-Benzoxazine-2,4(lH)-dione

2-Benzoxazolinone

Benzoylacetic acid, ethyl ester

*o-Benzoylbenzoic acid

Benzoyl chloride

4-Benzoyl-3-hydroxyphenyl methacrylate

2-Benzoyl-4-sulfobenzoic acid

EK.

AAP,

DUP,

AAP.

AAP,

TRC.

CTN.

DUP,

AAP.

ACP.

DUP,

DUP,

ACY,

DUP.

ALL, DUP, KLS, MON. MON.

DUP, G, NAC, TRC, VPC. GIV, LIL.

LB/1, MEE, NAC. G, TRC. DUP, G, TRC.

DUP, ICI, TRC. G, MEE. G. DUP, G.

ICI.

ABB, FLM.

DA.

DUP, G, TRC.

KF, LIL. ABB, KF. BPC, HN, VEL. DUP.

ICI,

AAP.

DUP,

ACY,

TRC.

TRC.

AAP,

G.

DUP,

AAP,

EDC.

KPT.

NES.

NES,

NES.

DUP.

DUP,

ACC.

ACC.

TBK.

CWN,

LEM.

BPC,

EK.

FRO,

EK.

BPC,

VEL.

GOC.

ACY,

MEE. MEE.

NAC.

DUP, G, ICI, MAY, NAC, TRC.

ACY, ATL, CMG, DUP, G, ICI, MAY, NAC, SDC, TRC.

FIN, LAK, NAC, x.

LEM.

HK, HN, MON, VEL.

LEM.

GYR, MON.

FMP.

ACY, DUP, G, NAC.

HK, HN, VEL.

CYCLIC INTERMEDIATES

69

TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 --Continued

2-Benzoyl-4'-(p-toluenesulfonamido)acetanilide

Benzylamine

4-(Benzylamino)-6-chloro-m-benzenedisulfonic acid

2-(Benzylamino)ethanol

4-Benzyl-6-chloro-3-keto-2-methyl-7-sulf amyl-1, 2, 4-benzyl-

thiadiazine-1, 1-dioxide. 4-Benzyl-6-chloro-3-keto-7-sulf amyl-1, 2, 4-benzylthia- diazine-1, 1-dioxide.

Benzyl disulfide

Benzyl ether (Dibenzyl ether)

5-(Benzylethylamino)-o-toluenesulfonic acid

N-Benzyl-N-ethyl-m-toluidine

4- ( Benzylideneamino ) antipyr ine

4,4'-Benzylidenedi-o-toluidine

Benzylidene phthalide

p-(Benzyloxy)phenol

4- Benzylpiperidine

Benzjl polysulfide

4-Berizylpyridine

Benzyl sulfide

Benzyl trimethylammonium chloride

Benzyltrimethylammonium hydroxide

Benzyl trimethylammonium methoxide

4',4'"-Biacetophenone

M>,3'-Bianthra[l,9-cd]pyrazole]-6,6'-(2H,2'H)dione ( Pyrazoleanthrone yellow).

[3,3'-Bi-7H-benz[de] anthracene] -7,7'-dione

*[4,4'-Bi-7H-benz[de] anthracene] -7, 7 '-dione

[l,l'-Binaphthalene]-8,8'-dicarboxylic acid

Biphenyl

3,3',4,4'-Biphenyltetramine .

2,2',4,4'-Biphenyltetrol

2,2'-Biqiinoline

*1,4-Bis[ 1-anthraquinonylamino] anthraquinone

l,4-Bis[i-anthraquinonylamino] anthraquinone and 1,4-Bis- [ 5-chloro-l-anthraquinonylamino] anthraquinone (mixed ) .

It 5-Bis [1-anthraquinonylamino] anthraquinone >

l,4-Bis(anthraquinonylamino)anthraquinone carbazole

Bis[l-anthraquinonylamino]violanthrene

l,4-Bis[(5-benzamido-l-anthraquinonyl)amino]anthraquinone-—

a2,a6-Bis[5-tert-butyl-6-hydroxy-m-tolyl]mesitol

Bis(chlorosulfonyl)phthalocyaninedisulfonic acid, copper derivative.

4,4'-Bisrdiethylamino]benzhydrol

4,4'-Bis[diethylamino]benzhydrol, 2,6-naphthalenedi-

sulfonate. 4,4'-Bis[diethylamino]benzhydrol salt, 2,7-naphthalenedi- sulfonic acid mixture.

4,4'-Bis[diethylamino]benzophenone (Ethyl ketone base)

4-Bis[ (p-diethylaminophenyl )methyl] -2, 7-naphthalenedi- sulfonic acid, leuco form.

4,4'TBis[dimethylamino]benzhydrol (Michler's hydrol)

*4,4'-Bis[dimethylamino]benzophenone (Michler's ketone)

Bis[p-(dimethylamino)phenyl]methanesulfonic acid and salt —

1, 5-Bis[2,4-dinitrophenoxy]-4,8-dinitroanthraquinone

l,5(and l,8)-Bis[2,4-dinitrophenoxy]-4,8(and 4,5)-dinitro- anthraquinone .

Bis(2,3-epoxycyclopentyl)ether (Epoxide 205)

4,4'-Bis[(p-hydroxyphenyl)azo]-2,2'-stilbenedisulfonic acid (C.I. Direct Yellow 4).

4,4-Bis[p-hydroxyphenyli valeric acid

4,4-Bis(p-methoxyphenyl)-3-hexanone

Bis(2-methyl-l-aziridinyl )phenylphosphine oxide

2,4-Bis(l-methylbutyl)phenol

l,4-Bis[2-(4-methyl-5-phenyloxazolyl)l benzene (Dimethyl- P0P0P).

Bis(o-nitrophenyl)sulfide

m-Bis(m-phenoxyphenoxy)benzene

l,4-Bis[2-(5-phenyloxazolyl)]benzene (P0P0P)

2-Brcanoacetophenone

p-Bromoaniline

p-Bromoanisole~

Manufacturers' identification codes (according to list in table 22)

EK.

ICO, MLS.

ABB.

MLS..

ABB.

ABB.

CCW.

BPC, TBK.

NAC.

DUP, NAC.

SDW.

ACY.

LIL.

EK, ICO.

RIL.

HK.

RIL.

BPC.

MLS.

MLS.

MLS.

DUP.

DUP, G, TRC.

DUP, NAC.

ACY, DUP, ICI, MAY, NAC.

DUP, NAC.

DOW, MON.

AAP.

FMT, IDC.

EK.

ACY, DUP, G, ICI, MAY, NAC.

TRC.

DUP, NAC.

ICI.

G.

ICI.

ACY.

TRC.

DSC, SDH. TRC.

SDH.

DSC, DUP, G, NAC, SDH.

NAC.

DUP.

DUP.

UCC. TRC.

JNS. LIL. ICO. PAS. ARA.

EK. ARA.

EK.

EK, ICO.

70

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B —Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1 965— Continued

*3-Bromo-7H-benz[de]anthracen-7-one (3-Bromobenzanthrone)

Bromobenzene, mono-

p-Bromobenzenesulfonyl chloride

4-Bromobenzophenone

Bromochlorobenzene

o-Bromochlorobenzene

6-Bromo-5-chlorobenzoxazolone

2-Bromo-6-chloro-4-nitroaniline

2-Bromodibenzofuran

2-Bromo-4,6-dinitroaniline

Bromoethylbenzene

2-Bromo-3' -hydroxyacetophenone benzoate

*l-Bromo-4-(methylamino)anthraquinone

6-Bronc-3-methyl-7H-dibenz[f,ij],isoquinoline-2,7(3H)dione--

1-Bromonaphthalene

2-Bromo— 4'-nitroacetophenone

l-[ (9-Bromo-7-oxo-7H-benz [de] anthracen-3-yl )amino] anthra- quinone.

m-Bromophenol

o-Bromophenol

(p-Bromophenyl)acetonitrile

p-Bromophenylhydrazine hydrochloride

2-Broraopyridine

o-Bromotoluene

p- Br omo toluene

a-Bromo toluene

2-Bromo-l,3,5-triethylbenzene

p-Butoxyphenol

4-[3-(p-Butoxyphenoxy)propyl] morpholine

4' -Butoxy-2-piperidinopropiophenone hydrochloride

N-Butylacetanilide

l-(Butylamino)anthraquinone

p-(Butylamino)benzoie acid, ethyl ester

p-Butylaniline

2-tert-Butylanthraquinone

p-tert-Butylbenzaldehyde

n-Butylbenzene

sec-Butylbenzene

tert-Butylbenzene

p-tert-Butylbenzoic acid

o-(p-tert-Butylbenzoyl)benzoic acid

6-tert-Butyl-m-cresol

2-tert-Butyl-p-cresol

2'-tert-Butyl-4',6'-dimethylacetophenone

4-Butyl-a-(dimethylamino)-o-cresol

2-tert- Butyl -4-ethylphenol

^-Butyl-i-methoxymetanilamide

2-tert-Butyl-5-methylanisole

o-sec-Butylphenol

p-sec-Butylphenol

o-tert-Butylphenol

*p-tert-Butylphenol ■

Butylphenols, mixed

p-tert-Butyltoluene

5-tert-Butyl-l,2,3-trimethylbenzene

5-tert-Butyl-m-xylene

6-tert-Butyl-2,4-xylenol

Camphoric acid

Camphoric anhydride

Camphosulfonic acid

Carbamic acid, 2-hydroxy-2-phenylbutyl ester (Hydroxy- phenamate ) .

Carbazole, refined

N, N'-Carbonylbis[4-methoxymetanilic acid]

N, N'-Carbonylbis[4-methoxy-6-nitrometanilic acid]

2,4'-Carbonyldibenzoic acid

5'_(o-Carboxybenzoyl)-2'-chlorooxanilic acid

N- [ (3-Carboxy-4-chlorophenyl )-sulf onyl] anthranilic acid

3-Carboxy-2(and 4)-hydroxybenzenediazonium sulfate

o-[(Carboxymethyl)thio] benzoic acid

[ (o-Carboxyphenyl )thio] ethylmercury

Cedrene

Manufacturers ' identification codes (according to list in table 22)

ACY, DUP, G, ICI, MAY, NAC.

DCW.

EK.

ICO.

DOW.

PIC.

MEE.

AAP.

G.

AAP, TRC.

DOW.

SDH.

AAP, DUP, G, ICI.

AAP.

EK.

G.

BPC.

EK.

FMT, NEP,

EK, RSA.

BPC, PIC.

BPC, EK.

DUP.

ICO.

UCC.

AAP.

ICO.

DUP, UCC.

DUP.

GIV.

PLC.

PLC.

PLC.

SHC.

DUP.

KPT, PED.

ACY.

GIV.

EH.

ACY.

ALL, KLS, PCW.

GIV.

DOW, TNA, UCC.

DOW.

TNA.

DOW, PRD, UCP.

DOW.

GIV, SHC.

GIV.

GIV.

KPT.

FIN, OTC.

FIN.

OTC, FYL.

AHA.

SDC. G.

TRC. NAC-

LIL. GIV.

CYCLIC INTERMEDIATES

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

2'-Chloroacetoacetanilide

2'-Chloroacetophenone

4'-Chloroacetophenone

4'-(Chloroacetyl)acetanilide

m-Chloroaniline

o-Chloroaniline

p-Chloroaniline

2-(o-Chloroanilino)ethanol

3-(o-Chloroanilino)propionitrile

5-Chloro-o-anisidine [NH2 = !] (4-Chloro-o-anisidine [0CH3=1]).

5-Chloro-o-anisidine hydrochloride

4— Chloroanthranilic acid

*l-Chloroanthraquinone

*2-Chloroanthraquinone

N-(5-Chloro-l-anthraquinonyl)-p-toluenesulfonamide

o-Chlorobenzaldehyde

p-Chlorobenzaldehyde

4-(p-Chlorobenzamido)anthraquinone-l, 2-acridone :

Chloro-7H-benz [de] anthracen-7-one ( Chlorobenzanthrone )

*Chlorobenzene, mono-

p-Chlorobenzenesulfinic acid

p-Chlorobenzenesulf on amide

p-Chlorobenzenesulfonic acid

o-Chlorobenzoic acid

p-Chlorobenzoic acid

p-Chlorobenzonitrile

*o-(p-Chlorobenzoyl)benzoie acid

o(and p)-Chlorobenzoyl chloride

p-Chlorobenzoyl chloride

4,4'-(o-Chlorobenzylidene)di-2,5-xylidine

a-(p-Chlorobenzyl)-ct-phenyl-l-pyrrolidine propanol

Chloro(p-chlorophenyl)phenylmethane

Chlorocyclohexane

l-Chloro-2,5-diethoxy-4-nitrobenzene

2-Chloro-N, N-diethyl-4-nitroaniline

2-Chloro-3',4'-dihydroxyacetophenone

2-Chloro-l,4-dihydroxyanthraquinone

N-(3-Chloro-9,10-dihydroxy-2-anthryl)acetamidebis [hydrogen sulfate ].

4'-Chloro-2',5'-dimethoxyacetoaeetanillde

4-Chloro-2, 5-dimethoxy aniline

5-Chloro-2,4-dimethoxy aniline

5-Chloro-4, 7-dimethylbenzo [b] thiophen-3(2H)-one

4-Chloro-N,N-dimethyl-3-ni trobenzenesulfonanti.de

*l-Chloro-2,4-dinitrobenzene (Dinitrochlorobenzene)

l-Chloro-2,4-dinitrobenzene and 2-chloro-l,3-dinitrobenzene mixture.

3-Chloro-4, 6-dinitrobenzenesulf onic acid

4-Chloro-3, 5-dinitrobenzoic acid

3-Chlorodiphenylamine

Chlorodiphenylmethane

a- Chloro-o( and/or p )-dodeeyltoluene [CH3=1]

p-[ (2-Chloroethyl )methylamino]benzaldehyde

Chloroformic acid, benzyl ester

Chloroformic acid, phenyl ester

l-Chloro-4-hydroxyanthraquinone

4-Chloro-5-hydroxy-l, 7-naphthalenedisulf onic acid

5'-Chloro-3-hydroxy-2-naphth-o-anisidide

3-Chloro-4-hydroxyquinoline-3,4-carbonic acid

6-Chloroisatoic anhydride

4-Chloro-N-isopropyl-3-nitrobenzenesulf on amide

4-Chlorometanilic acid

5-Chlorometanilic acid

*6-Chlorometanilic acid

5-Chloro-2-methoxybenzenediazonium chloride

N-[ (5-Chloro-2-methoxyphenyl)azo] sarcosine

*l-Chloro-2-methylanthraquinone

4-(Chloromethyl)-l,2-dimethylbenzene

4-(Chloromethyl)-l,3-dimethylbenzene

l-(Chloromethyl)naphthalene

4-Chloro-N-methyl-3-nitrobenzenesulf on amide

FMP, UCC.

EK.

LIL, NES.

DUP.

DUP, G.

DUP, MON, NAC.

DUP, MON.

EKT.

DUP.

ALL, BUC, KLS.

BUC,

DUP.

ACY,

ACY,

ICI.

HN.

HN.

G.

ACY,

ACS,

TRC.

ACY,

G.

HN.

HN.

EK.

ACY,

HN.

HN.

G.

LIL.

OPC,

ACY.

ALL,

DUP.

AAP,

NAC.

G.

DUP, G, ICI, MAY, NAC. G, NAC, TRC.

DOW, DUP, DVC, GGY, HK, HKD, MON, MTO, OMC, PPG, WOI. NES.

DUP, G, ICI, NAC.

TBK. KMT, G. SDW.

PCW.

PCW.

G, PCW.

NAC.

EKT, G.

AAP, DUP, NAC, SDC.

DUP.

TRC.

G.

SK.

TBK.

0R0.

G, NAC.

RSA.

EK.

ICI.

G.

PCW.

SDH.

MEE.

TRC.

DUP.

NAC.

AAP, DUP, G, SW.

G.

ATL.

AAP, ACY, CMG, G, ICI, NAC, TRC.

BPC.

BPC.

BPC.

TRC.

72

SYNTHETIC ORGANIC CHEMICALS, 1965

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

2- Chloro-5-(N-methylsulfamoyl) sulfanilamide

5-Chloro-2-(N-methylsulfamyl)-<4-sulfamyl-N-benzylaniline

Chloronaphthalen.es

*2-Chloro-<i-nitroaniline (o-Chloro-p-nitroaniline)

*4-Chloro-2-nitroaniline (p-Chloro-o-nitroaniline)

"i-Chloro-2-nitroanisole

*l-Chloro-5-nitroanthraquinone

*l-Chloro-8-nitroanthraquinone

*l-Chloro-2-nitrobenzene (Chloro-o-nitrobenzene)

l-Chloro-2(and 4)-nitrobenzene (Chloronitrobenzenes,

o- and p-). l-Chloro-3-nitrobenzene (Chloro-m-nitrobenzene)

*l-Chloro-4-nitrobenzene (Chloro-p-nitrobenzene)

*4-Chloro-3-nitrobenzenesulfonamide

4-Chloro-3-nitrobenzenesulfonanilide

*2-Chloro-5-nitrobenzenesulfonic acid

2-Chloro-5-nitrobenzenesulfonic acid, sodium salt

4-Chloro-3-nitrobenzenesulfonic acid

*4-Chloro-3-nitrobenzenesulfonyl chloride

2-Chloro-4- nitrobenzoic acid

2-Chloro-5-nitrobenzoic acid

*o-(4--Chloro-3-nitrobenzoyl )benzoic acid

4-Chloro-2-nitrophenol

4-Chloro-3-nitrophenyl methyl sulfone

2-Chloro-<i- nitrotoluene

2-Chloro-6-nitrotoluene

4-Chloro-2-nitrotoluene

4- Chloro-3 -nitrotoluene

m- Chlorophenol

o-Chlorophenol

p- Chlorophenol

2-Chlorophenothiazine

(m-Chlorophenyl)acetonitrile

*(p-Chlorophenyl)acetonitrile

l-(p-Chloro-a-phenylbenzyl)-4-methylpiperazine

4-Chloro-a-phenyl-o-cresol

4-Chlqro-o-phenylenediamine

3-(o-fihlorophenyl)-5-methyl-<i-isoxazolecarbonyl chloride

3-(o-Chlorophenyl )-5-methyl-4- isoxazolecarboxylic acid-

l-(m-phlorophenyl)-3-methyl-2-pyrazolin-5-one

p-Chlprophenyl methyl sulfone

2-Chloro-<4-phenylphenol

1- [4-(p-Chlorophenyl )-3-phenyl-3-butenyl]pyrrolidine hydro- bromide.

4-Chlorophthalic acid

Chlorophthalic anhydride

l-(3-Chloropropyl)-4-methylpiperazine

^-(e-Chloro-S-pyridazinylJsulfanilamide

2-Chloropyridine

dl-2-[p-Chloro-d-(2-pyridyl )benzyl]oxy-N, N-dimethylethyl- amine maleate.

7-Chloro-4-quinolinol

2-(6-Chloro-2-quinoyl)-l,3-indandione

4-Chlororesorcinol

8-Chlorotheophylline

2-Chlorothiaxanthen-9-one

2-Chlorothiophene

m- Chlorotoluene

o-Chlorotoluene

p-Chloro toluene

*a- Chlorotoluene (Benzyl chloride)

Chlorotoluenes, mixed

6-Chloro-m-toluidine

6-Chloro-m-toluidine hydrochloride

3-Chloro-o-toluidine [ NH2 = 1]

*4-Chloro-o-toluidine [ NH2 = 1] and hydrochloride

*5-Chloro-o-toluidine [ NH2 = 1] (4-Chloro-o-toluidine [CH3 = 1]).

*5-Chloro-o-toluidine hydrochloride [ NH2 = 1]

3-Chloro-p-toluidine [NH2= 1]

*N-[(5-Chloro-o-tolyl)azo]sarcosine

G, KPS, KPT.

ACY,

DOW, DUP,

HSC.

AAP,

DOWr DUP,

VPC.

ALL.

ACY,

DUP, MAY,

NAC, TRC.

DUP,

MAY, NAC.

AAP,

DUP, MON,

UPM.

SDC.

DUP,

G, UPM.

AAP,

DUP, MON,

UPM.

AAP,

CMG, DUP,

EKT, ICC, TRC

TRC.

AAP,

CMG, NAC,

TRC.

DUP.

G, NAC, TRC.

AAP,

DUP, EKT.

SAL.

TRC.

AAP,

G, ICI, NAC.

DUP.

TRC.

DUP.

DUP.

BUC,

DUP.

AAP,

BUC.

EK.

DOW,

MON.

DOW,

MON.

SK.

BPC.

ICO,

OPC, TBK.

ABB.

MON.

FMT.

ICO,

OTC.

ICO.

TRC.

TRC.

DOW.

LIL.

SW.

HK.

SK.

ACY.

FMT.

X.

SDW.

DUP.

AAP,

G.

MAL.

KF.

GAM.

BPC,

GRH,

HK, HN,

BPC.

BUC.

BUC.

AAP,

ACY,

PCW.

ATL, DUP,

BUC, SDH.

DUP.

ALL,

ATL,

BUC, G.

CYCLIC INTERMEDIATES

73

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 --Continued

l-(6-Chloro-o-tolyl)-3-methyl-2-pyrazolin-5-one

*[(4-Chloro-o-tolyl)thio]acetic acid

4-Chloro-a,<x,a-trifluoro-3-nitrotoluene

5-Chloro-a,x,a-trifluoro-2-nitrotoluene

p-Chloro-a,a,a-trif luorotoluene

6-Chloro-oc, a,ct-trifluoro-m-toluidine

2-Chloro-l,3,5-trinitrobenzene

Chlorotriphenylmethane

2-Chloro-p-xylene

4-Chloro-2, 5-xylenesulf onyl chloride

4-Chloro-3,5-xylenol

[ (4-Chloro-2,5-xylyl)thio]acetic acid

5<x-Cholestan-3/S-ol

Cholic acid

Cinnamoyl chloride

*Cresols : 1

m-Cresol

o-Cresol:

From coal tar

From petroleum

p-Cresol

Cresols, mixed i1 *(m,p)-Cresol:

From coal tar

From petroleum

*(o,m,p)-Cresol:

From coal tar

From petroleum

2,3-Cresotic acid

*Cresylic acid, refined:1

*From coal tar

*From petroleum

*Cumene

N-(0-Cyanoethyl)-N-(/3-acetoxyethyl)aniline

4-[(2-Cyanoethyl)ethylamino]-o-tolualdehyde

p-[(2-Cyanoethyl)methylamino]benzaldehyde

8-Cyano-l-naphthalenesulfonic acid

*Cyclohexane

1,2-Cyclohexanedicarboxylic acid, diallyl ester

1,4-Cyclohexanedicarboxylic acid, dimethyl ester

1,2-Cyclohexanedicarboxylic anhydride

*Qyclohexanol

*Cyelohexanone

Cyclohexanone oxime

Cyclohexene

4-Cyclohexene-l,2-dicarboximide

4-Cyclohexene-l,2-dicarboxylie anhydride

*Cyclohexylamine

Cyclohexyl-2-propanone

N-Qyclohexyltaurine, sodium salt

Qyclopentanepropionic acid

Cyclopentanol

Qyclopentanone

Qyclopentene

Cyclopentylphenylglycolic acid, methyl ester

Cyclopropylcarbox amide

Cyclopropylcarboxylic acid

p-Cymene

Deoxycholic acid

1,5 (and l,8)-Diacetamidoanthraquinone

3'-[Di(2-acetoxyethyl)amino]-p-acetophenetidide

N, N-Diacetyl-4,4' -diaminobiphenyl

3- (Diallylcarbamoyl )-l, 2, 2-trimethylcyclopentanecarboxylic acid.

N2, N2-W.allylmelamine

*l,4-Diaminoanthraquinone

*1, 5-Diaminoanthraquinone

1,5 (and l,8)-Diaminoanthraquinone

*2, 6-Waminoanthraquinone

3,4-Diaminobenzanilide

2,4-Diaminobenzenesulfonic acid [S03H=l]

See footnote at end of table.

Manufacturers' identification codes (according to list in table 22)

TRC.

ACY,

ALL,

NAC,

POT

AAP,

G, MEE.

MEE.

HK.

AAP.

EK,

PIC.

ARA,

EK.

DUP.

G, NAC.

OTA.

G, NAC.

SDW.

SRL,

WIL.

BPC,

TBK,

X.

KPT,

PRD.

KPT,

PRD.

MER,

NPC,

PRD,

SW.

ACY,

HPC,

SW.

ACP,

KPT,

PRD.

MER,

NPC,

PIT,

PRD.

ACP,

KPT.

NPC, DOW.

PIT,

PRD.

ACP, KPT.

MER, NPC, PIT, PRD, SHO.

ACC, CLK, DOW, GOC, HPC, MON, SHC, SKO, SOC, TX.

EKT.

DUP, G.

DUP, G.

DUP, G.

ASH, CO, CSD, DUP, EK, EKX, ENJ, GOC, GRS, PLC, PRO,

RIC, SOG. ICO.

NAC.

DUP,

MON,

NAC.

DBC,

DUP,

MON, NAC.

NAC,

X.

KF,

PLC.

CHO.

NAC,

PTT.

ABB,

JCC,

MON, PAS, VGC, x.

GIV.

G.

ARA.

ARA,

LIL.

ARA.

PLC.

ARA.

ABB.

ABB.

HNW,

HPC,

NAC.

MRK,

WIL.

AAP.

TRC.

AAP.

WYT.

ACY.

CMG,

DUP,

G, NAC, TRC.

DUP,

MEE,

TRC.

AAP,

G, ICI, TRC.

AAP,

DUP,

G, ICI, NAC, TRC, VPC.

AAP,

DUP.

DUP,

NAC,

TRC.

74

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B. Cyclic intermediates for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

2,5-Diaminobenzenesulfonic acid [S03H=1]

4,4'-Diamino-2,2'-biphenyldisulfonic acid

3,7-Diamino-4, 6-dibenzothiophenedisulfonic acid, 5,5-

dioxide, disodium salt.

1, 5-Diamino-2,6-dibromo-4,8-di-p-toluidinoanthraquinone

l,4-Diamino-2,3-dichloroanthraquinone ■■

*l,4-Diamino-2,3-dihydroanthraquinone

4, 8-Diamino-9, 10-dihydro-l, 5-dihydroxy-9, 10-dioxo-2, 6-

anthracenedisulfonic acid. l,4-Diamino-9, 10-dihydro-9, 10-dioxo-2,3-anthracenedi-

carbonitrile. 1, 4-Diamino-9, 10-dihydro-9, 10-dioxo-2, 3-anthracenedicar-

boximide.

l,5-Diamino-4,8-dihydroxyanthraquinone

l,5(and l,8)-Diamino-4, 8(and 4, 5 )-dihydroxyanthraquinone

4, 5-Diamino-l,8-dihydroxyanthraquinone

3, 6-Diamino-2, 7-dimethylacridine

3, 6-Diamino-2, 7-dimethylacridine sulfate

4,4'-Diaraino-5,5'-dimethyl-2,2' -biphenyldisulfonic acid

l,4-Diamino-5-nitroanthraquinone

4,6-Diamino-5-nitroso-2-phenylpyrimidine

2,4-Diamino-6-phenyl-s-triazine

2, 6-Diaminopyridine

*4,4'-Diamino-2,2'-stilbenedisulfonic acid

l,5-Diamino-2,4,6,8-tetrabromoanthraquinone

2, 5-Diandnotoluene sulfate

4,6-Diamino-m-toluenesulfonic acid [S03H=l]

N-(4,6-Diamino-m-tolyl)-p-benzoquinoneimine

1, 5-Dianilino-9, 10-dihydro-9, 10-dioxo-2, 6-anthraeenedi-

carboxylic acid.

2,4-Dianilino-l-hydroxyanthraquinone

6, 8-Dianilino-l-naphthalenesulf onic acid

Diary lguanidine

p-Diazo-N, N-dimethylaniline-l-amino-8-naphthol-3-sulfonate-

6-sulfonic acid, sodium salt. 5(and 3)-Diazo-6-oxo-l,3(and l,4)-cyclohexadiene-l-car-

boxylic acid.

1,5-Dibenzamidoanthraquinone

6,ll-Dibenzamido-16H-dinaphtho[2,3-aJ2 ',3'-l] -carbazole-

5, 10, 15, 17-tetrone.

*4, 5' -Dibenzamido-1, 1' -iminodianthraquinone

Dibenzo[b,def] chrysene-7, 14-dione

*1, 5-Dibenzoylnaphthalene

N, N'-Dibenzylethylenediamine

N, N'-Dibenzylethylenediamine diacetate

N, N-Dibenzylsulf anilic acid

2,4' -Dibromoacetophenone

*3,9-Dibromo-7H-benz[de]anthracen-7-one

m-Dibromobenzene

p-Dibromobenzene

2, 2' -Dibromobiphenyl

Dibromodibenzo[b,def] chrysene-7, 14-dione

ar-Dibromoethylbenzene

2,6-Dibromo-l, 5-naphthalenediol

2,6-Dibromo-4-nitrophenol

5, 13-Dibromo-8, 16-pyranthrenedione

Dibromoviolan throne

2, 5-Dibutoxy aniline

p-Dibutoxybenzene

l,4-Dibutoxy-2-chloro-5-nitrobenzene

2, 5-Dibutoxy-4-morpholinobenzenediazonium sulfate

4-(2,5-Dibutoxy-4-nitrophenyl)morpholine

2,4-Di-tert-butylphenol

Dibutyltin bis(cyclohexyl maleate)

3,4-Dichloroaniline

*2,5-Dichloroaniline and hydrochloride [NH2"l]

3,4-Dichloroaniline-6-sulfonic acid

3- ( 2, 4-Dichloroanilino )-l- ( 2, 4, 6-trichlorophenyl ) -2-

pyr azolin- 5-one .

*1, 5-Dichloroanthraquinone

1,5 (and 1, 8)-Dichloroanthraquinone

1, 8-Dichloroanthraquinone

TRC.

AAP, ACY, ACY.

ICI.

CMG, DUP. ACY, ATL, TRC.

DUP.

DUP.

DUP, G, ICC, VPC.

DUP.

ICI.

DUP.

DUP.

AAP.

ARA.

RH, VEL. NEP, RIL. ACY, DUP, ICI. EK. NAC. DUP. G, NAC.

DUP, G, HSH, ICC, ICI, MAY, TRC.

G, GGY, NAC, SDH, TRC, VPC.

NAC. DUP. IDC.

G, TRC.

ICI.

ACY, DUP,

G, ICI,

MAY,

NAC,

TRC

ATL, ICI.

ACY, DUP,

G, HST,

ICI,

TRC,

VPC

ICO, WYT.

WYT.

ICI.

DUP, G, MAY, NAC, TRC.

DOW.

EDC.

ICI.

DOW.

EK.

MEE.

DUP,

ICI.

G.

EKT.

ALL.

ALL.

ALL.

ALL.

DOW,

KPT.

X.

DUP,

MON.

AAP,

DUP, KLS, NAC, SDH

SW.

EK.

DUP,

G, ICI, NAC.

DUP,

NAC.

ICI,

TRC.

CYCLIC INTERMEDIATES

75

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 --Continued

Manufacturers1 identification codes (according to list in table 22)

4, 5-Dichloro-l, 8-anthraquinonedisulfonic acid

2, 6-Dichlorobenzaldehyde

2, 6-Dichlorobenzaldehyde oxime

3-(3,4-Dichlorobenzamido)-l-phenyl-2-pyrazolin-5-one

Dichlorobenzan throne

m-Dichlorobenzene

*o-Dichlorobenzene

o(and p)-Diehlorobenzene

*p-Dichlorobenzene

4, 6-Dichloro-m-benzenedisulf on amide

4,6-Dichloro-m-benzenedisulfonyl chloride

*3,3'-Dichlorobenzidine base and salts

2, A— Diehlorobenzoic acid

2, 6-Dichlorobenzonitrile

2,4-Dichlorobenzoyl chloride

2, 5-Dichlorobenzoyl chloride 1

8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo-(3,2-b: 3 ',2'-m)triphenodioxazine.

7 ', 16-Dichloro-6, 15-dihydro-5, 9, 14, 18-anthrazinetetrone

4, 8 ( and 4, 5 )-Dichloro-9, 10-dihydro-9, 10-dioxo-l, 5 ( and l,8)-anthracenedisulfonic acid.

1, 5-Dichloro-4,8-dihydroxyanthraquinone

l,5(and l,8)-Dichloro-4, 8(and 4, 5)-dihydroxyanthraquinone —

6,6'-Diehloro-2,2'-dimethoxybenzidine

4, 5-Dichloro-3,6-dioxo-l,4-cyclohexadiene-l, 2-dicarboni- trile.

Dichlorodiphenylsilane

2',7'-Dichlorofluorescein

2,5-Dichloro-4-hydrazinobenzenesulfonic acid

2- ( 5, 8-Dichloro-l-hydroxy-2-naphthylazo ) -l-phenol-4-sulf on-

amide. N- ( 6, 8-Dichloro-5-hydroxy-l-naphthyl )-p-toluenesulf on amide- s' 14-Dichloroisoviolan throne

*2,5-Dichloro-4-(3-methyl-5-oxo-2-pyrazolin-l-yl)benzene- sulfonic acid. 2,3-Dichloro-6-methylquinoxaline

*2,6-Dichloro-4-nitroaniline

1, 2-Dichloro-4-nitrobenzene

*l,4-Dichloro-2-nitrobenzene (Nitro-p-dichlorobenzene)

2,4-Dichlorophenol

N-[ (2,5-Dichlorophenyl)azo]-N-ethyl-5-sulfoanthranilie acid 3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarbonyl

chloride. 3-(2',6'-Dichlorophenyl)-5-methyl-4-isoxazolecarboxylic acid.

l-(2,5-Dichlorophenyl)-3-triazenecarbonitrile

2,6-Dichloropyrazine

2,5-Dichloro-3,6-di(l-pyrenamino)-p-benzoquinone

3,6-Dichloropyridazine

4,7-Dichloroquinoline'

3, 5-Dichlorosalicylic acid

*2, 5-Dichlorosulf anilic acid [S03H=1]

2, 5-Dichloro-4-sulf obenzenediazonium sulfate

p,oc-Dichlorotoluene

2, 6-Dichlorotoluene

a,a'-Dichloroxylene

2,4-Dichloro-3,5-xylenol

Dicyclodiepoxycarboxylate (l^ioxide 221)

Dicyclohexylamine

Dicyclohexylcarbodiimide

Dicyclopentadiene (includes cyclopentadiene)

Dicyelopentadiene dioxide

2, 5-Diethoxyaniline

2',5'-Diethoxybenzanilide

p-Diethoxybenzene

2, 5-Diethoxy-morpholinobenzenediazonium chloride, zinc chloride.

2',5'-Diethoxy-4'-nitrobenzanilide

l,4-Diethoxy-2-nitrobenzene

4-(2, 5-Diethoxy-4-nitrophenyl )morpholine

«p-(Diethylamino)benzaldehyde

0.

DUP.

OTC.

EK.

ACY.

CPD,

ACS,

GGY,

ACS,

ABB.

EK, G.

CPD, DOW, DUP, DVC, MON, CMC, PPG, SCC, SVT, WOI.

HKD, MTO.

CPD, DOW, DUP, DVC, HK, MON, PPG, SCC, SVT, WOI.

ALL, CWN, IMP, LAK, NAC, UPJ.

AAP,

TRC.

ICI.

G.

DUP.

DUP.

ALL.

ARA.

DCC,

UCS.

EK.

G.

TRC.

EK.

ICI.

ACY,

CMG, DUP, G, KLS, PCW,

X.

AAP,

DUP, EKT, G, MEE, TRC

DUP,

MON.

AAP,

DUP, NAC, PCW, VPC.

DOW,

MON.

G.

ICO,

OTC.

ICO.

G.

ACY.

TRC.

ACY.

SDW.

ICO.

CMG,

DUP, G, VPC.

TRC.

HN.

DUP,

G.

BPC.

OTA.

UCC.

ABB,

MON, VGC.

G.

ENJ,

GOC, UCC.

UCC.

ALL.

ALL.

ALL,

G.

ALL.

ALL.

ALL,

G.

ALL.

DUP,

G, NAC.

76

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B. -Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 --Continued

a_ [(2-Diethylamino) ethyl] -cc-phenylcyclohexanemethanol, hydrochloride .

m- (Diethylamino )phenol ( N, N-Diethyl-3-aminophenol )

3-[(p-Diethylamino)phenylazo]-lH-l,2,4-triazole

3-(Diethylamino)propiophenqne

4-(Diethylamino)-o-tolualdehyde

*N, N-Diethylaniline

N, N-Diethyl-m-anisidine

Diethylbenzene

Diethyl-[3,3'-biantnra[l,9-cd]pyrazole]-6,6 -dione

1, l' -Diethyl-4, 4' -carbocyanine iodide ( Cryptocyanine )

N, N-Diethylcyclohexylamine

a,a'-Diethyl-4,4'-dimethoxystilbene

Nj N-Diethylmetanillc acid

N:L,N1-Diethyl-4-methoxymetanilamide

Diethyl-N-methyl-N-piperazine acetate

N, N-Diethyl-p-nitrosoaniline

N, N-Diethyl-4-nitroso-m-anisidine hydrochloride

N, N-Diethyl-4-nitroso-m-phenetidine

N, N-Di ethyl -p-phenylenediamine

N, N-Diethyl-m-toluidine

6, 15-Dihydro-5, 9, 14, 18-anthrazinetetrone

10,ll-Dihydro-5H-dibenzo[a,d]cyclohepten-5-one

2,3-Dihydro-l,8-dihydroxyanthraquinone

9, 10-Dihydro-l, 5-dihydroxy-4, 8-dinitro-9, 10-dioxo-2, 6-

anthracenedisulfonic acid. *9, 10-Dihydro-l, 4-dihydroxy-9, 10-dioxo-2-anthracenesulfonic

acid (2-Qainizarinsulfonic acid). N-( 5, 13-Dihydro-5, 13-dioxoaceanthryleno[ 2, 1-a] -aceanthry-

len_7-yl)-9,10-dihydro-l-nitro-9,10-dioxo-2-anthr amide.

«9, 10-Dihydro-9, 10-dioxo-l, 5-anthracenedisulf onic acid

*9, 10-Dihydro-9, 10-dioxo-l, 5-ar.thracenedisulf onic acid,

disodium salt. 9, 10-Dihydro-9, 10-dioxo-l, 5 (and 1, 8 )-anthracenedisulf onic

acid and salt.

9, 10-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic acid

*9, lO-Dihydro-9, 10-dioxo-l, 8-anthracenedisulf onic acid,

potassium salt. *9, 10-Dihydro-9,10-dioxo-2,6-anthracenedisulfonic acid and

salt. *9, 10-Dihydro-9, 10-dioxo-l-anthracenesulf onic acid and salt

(Gold salt). 9, 10-Dihydro-9, 10-dioxo-2-anthracenesulfonic acid and salt

(Silver salt).

9, 10-Dihydro-9,10-dioxo-2-anthroic acid

3,4-Dihydro-3,4-dioxo-l-naphthalenesulfonic acid, sodium

salt. 10, ll-Dihydro-5-[3-(methylaminopropyl ) J -5H-dibenzol a,d J- cyclohepten-5-ol. *9, 10-Dihydro-5-nitro-9, 10-dioxo-l-anthracenesulf onic acid— 9,10-Dihydro-5(and 8 )-nitro-9, 10-dioxo-l-anthracenesulf onic

acid. 9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf onic acid— 9, 10-Dihydro-8-nitro-9, 10-dioxo-l-anthracenesulf onic acid, sodium salt.

*9, 10-Dihydro-l-nitro-9, 10-dioxo-2-anthroic acid

l,4-Dihydro-4-oxo-2, 6-pyridinecarboxylic acid

2,3-Dihydro-4H-pyran

*l,4-Dihydroxyanthraquinone (Ouinizarin)

Manufacturers' identification codes (according to list in table 22)

*1, 5-Dihydroxyanthraquinone (Anthraimfin)

1,5 (and 1, 8)-Dihydroxyanthraquinone

*l,8-Dihydroxyanthraquinone (Chrysazin)

*2,6-Dihydroxyanthraquinone (Anthraflavic acid)

2, 5-Dihydroxybenzenesulf onic acid ( tfydroquinone sulfonic acid ) .

2,4-Dihydroxybenzophenone

1, 5-Dihydroxy-4,8-dinitroanthraquinone

l,5(and l,8)-Dihydroxy-4,8(and 4,5)-dinitroanthraquinone-

*l,8-Dihydroxy-4,5-dinitroanthraquinone (4,5-Dinitro- chrysazin).

ACY,

DUP, MON.

TRC.

ACY.

DUP.

ACY,

DSC, DUP, NAC, SDH

DUP.

DOW,

KPP.

G.

EK.

DUP.

LIL.

DUP.

PCW.

ABB.

G.

DUP.

G.

FMT.

DUP.

TRC.

LIL.

DUP.

VPC.

AAP,

HSH, PAT.

ICI,

NAC.

ACY,

DUP, TRC.

DUP,

G, ICI, TRC.

DUP,

TRC.

DUP.

G, ICI, NAC, TRC.

AAP, DUP, G, ICI, NAC, TRC, VPC.

AAR, ACY, DUP, G, ICI, MAY, NAC, TRC.

DUP, NAC.

ACY, NAC.

EK.

DUP, MAY, NAC, TRC.

ICI, TRC.

MAY, NAC. DUP.

DUP, G, NAC, TRC.

SDW.

QKO.

AAP, ACY, CMG, DUP, EKT, G, HSH, ICC, ICI, JTC, MAY,

NAC, TRC.

ACY, CMG, DUP, G, NAC, TRC.

AAP, DUP, TRC.

DUP, G, ICI.

DUP, G, NAC, TRC. NES.

DUP, G.

AAP, ICC, ICI, VPC.

TRC.

DUP, EKT, G, ICC, ICI.

CYCLIC INTERMEDIATES

77

--Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

10, 10'- (Dihydroxyethanediylidene)dian throne

4, 5-Dihydroxy-2,7-naphthalenedisulfonic acid ( Chronotropic acid).

6, 7-Dihydroxy-2-naphthalenesulf onic acid

3, 5-Dihydroxy-2-naphthoic acid

lip .21-Dihydroxypregna-4, 17(20 )-cis-dien-3-one

llp,21-Dihydroxypregna-l,4,17(20)-cis-trien-3-one

4, 5-Dihydroxy-3-(p-sulfophenylazo)-2,7-naphthalenedisul- fonic acid, trisodium salt.

*16,17-Dlhydroxyviolanthrone (Dihydroxydibenzanthrone)

m-Diiodobenzene

2, 5-Diiodobenzoic acid, 2-(2-methoxyethoxy)ethyl ester

3, 5-Diiodo-4-oxo-l(4H)pyridineacetic acid

3, 5-Diiodo-L- tyrosine

N, N '-Diisopropyl-p-phenylenediamine

2, 5-Dimethoxy aniline

l,5(and l,8)-Dimethoxyanthraquinone

2, 5-Dimethoxybenzaldehyde

*m-Dimethoxybenzene

*3,3'-Dimethoxybenzidine

3,3 -Dimethoxybenzidine hydrochloride

2, 4-Dimethoxybenzoie acid

2, 6-Dimethoxybenzoyl chloride

N, N'-[(3,3'-Dimethoxy-4,4'-biphenylylene)bis-(azo)]bis- ( N-methyltaurine ) .

2,5-Dimethoxy-P-methyl-|3-nitrostyrene

N-(3,4-Dimethoxy-a-methylphenethyl)-2-(4-ethoxy-3-methoxy- phenyl )acetamide.

2,5-Dimethoxy-a-methylphenylamine

1,4— Dimethoxy-2-nitrobenzene

2, 5-Dimethoxy-4' -nitrostilbene

3,4-Dimethoxyphenethylamine (Homoveratrylamine)

4-(2',5'-Dimethoxyphenethyl)aniline hydrochloride

N-(3,4-Dimethoxyphenethyl)-2-(3,4-dimethoxyphenyl)-acetamide

3,4-Dimethoxyphenisopropylamine

(3,4-Dimethoxyphenyl)acetic acid

(3,4-Dimethoxyphenyl)acetonitrile

l-(3,4-Dimethoxyphenyl)-2-nitro-l-propene

*16,17-Dimethoxyviolan throne

1, 5-(Dimethylamiho)anthraquinone

m-(Dimethylamino)benzoic acid

a-(Dimethylaraino)-p-cresol

6-Dimethylamino-2- [2-(2, 5-dimethyl-l-phenyl-3-pyrryl)- vinyl]-l-methyl-l-quinolinium methyl sulfate.

6-(Dimethylaminoethyl)-2-methoxy-4-nitrophenol

2-[[ 2-(Dimethylamino)ethyl] -2-thenylamino]-pyridine (non- medicinal grade).

m-(Dimethylamino)phenol

l-(Dimethylamino)phenylbutyTonitrile

N-(p-Dimethylaminophenyl)-l,4-naphthoquinoneimine

*N, N-Dimethylaniline

7, 12-Dimethylbenz[ a] anthracene

3,3'-Dimethylbenzidine (o-Tolidine)

3,3'-Dimethylbenzidine hydrochloride

*N, N-Dimethylbenzylamine

a,a-Dimethylbenzyl hydroperoxide

4-(a,a-Dimethylbenzyl)-2-phenylazophenol

*2, 2'-Dimethyl-l,l'-bianthraquinone

Dimethyl-6, 12-ceroxenol acetate

5,5-Dimethyl-l,3-cyclohexanedione

N, N-Dimethylcyclohexylamine

N,a-Dimethylcyclopentaneethylamine

N, N-Dimethyl-2, 2-diphenylacetamide

2 ' ,T -Dime thy If luor an

5,5-Dimethylhydantoin

2,3-Dimethjrlindole-

2, 5-Dimethyl-4(2 )-morpholinylmethylphenol hydrochloride

*N, N-Dimethyl-p-nitrosoaniline

N, N-Dimethyl-3-nitro-p-toluenesulf on amide

N, N-Dimethyl-p-phenylenediamine

N, N-Dimethyl-p-phenylenediamine hydrochloride

1, 4-Dimethylpiper azine

ICI.

HSH,

NAG.

FMT,

-G, IDC, NAC.

G.

UPJ.

UP J.

EK.

ACY,

DUP,

G, ICI, MAY, NAC.

EK.

SDW.

SDW.

EK.

DUP.

ALL,

EKT,

KLS.

TRC.

CWN.

ACY,

ICO,

TBK.

ALL,

BUC,

CWN, DUP, LAK, SDH

ALL,

CWN.

ACY.

ICO.

ALL,

BUC,

G.

LIL.

x.

LIL.

LIL.

LIL.

LIL.

LIL.

G, ICI, MAY.

AAP.

SDH.

TKL.

MEE. ABB.

ACY,

ICO.

NAC.

ACY,

EK.

CWN,

AAP,

ICO,

ACP.

TRC.

AAP,

WLM.

EKT.

DUP,

LIL.

ARA,

WLM.

GLY.

DUP.

IDC.

ACY,

G.

EKT,

EK.

COK,

DSC, DUP, NAC, SDH.

DUP.

DUP, EK.

MLS, RH.

ACY, CMG, DUP, G, ICI, TRC.

EKT. UPJ.

DUP, NAC. NAC. JCC, SEL.

78

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE IB. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

N-[[ 4- (Dimethylsulf amoyl) -o-tolyl] azo] -N-methyl-5-sulfo- anthranilic acid.

N, N-Dimethylsulf anilic acid

N, N-Dimethyl-p-toluidine

2,4-Dinitroaniline

*p-(2,4-Dinitroanilino)phenol

1, 5(and l,8)-Dinitroanthraquinone

N, N'-(2,4-Dinitro-l,5-anthraquinonylene)dioxamic acid

3',4-Dinitrobenzanilide

m-Dinitrobenzene

2,4-Dinitrobenzenesulfonic acid

3, 5-Dinitrobenzoic acid

3, 5-Dinitrobenzoyl chloride

10,10'-Dinitro[3,3'-bi-7H-benz[de] anthracene] -7, 7 '-dione

Dinitrocaprylphenol

2,4-Dinitrocumene

3,3'-Dinitro-N, N'-diacetylbenzidine

3', 5' -Dinitro-2' -hydroxyacetanilide

l-(3,5-Dinitro-2-hydroxyphenylazo)-2-naphthol

*2,4-Dinitrophenol, tech

(2,4-Dinitrophenyl)hydrazine

3, 5-Dinitrosalicylic acid

*4,4'-Dinitrostilbene-2,2'-disulfonic acid

2,4-Dinitrotoluene

2, 4 (and 2,6)-Dinitrotoluene

3, 5-Dinitro-p-toluenesulf onic acid

2,4-Di-tert-pentylphenol

1, 5-Diphenoxyanthraquinone

1,5 (and 1, 8 ) -Diphenoxyanthr aquinone

1,8-Diphenoxyanthraquinone

Diphenylacetaldehyde

Diphenylacetic acid

Diphenylamine

2, 8-Diphenylanthra [l,2-d: 6, 5-d'] bisthiazole-6, 12-dione

a-d-l,2-Diphenyl-4-dimethylamino-2-hydroxy-3-methylbutane, camphor sulfonate.

N, N'-Diphenylethylenediamine

Diphenylme thane

2-(Diphenylmethoxy)-N, N-dimethylethylamine (Diphenhydra- mine base).

2, 5-Diphenyloxazole

l,3-Diphenyl-l,3-propanedione

1, 3-Diphenyltriazene

2,2'-Dithiodibenzoic acid

*l,4-Di-p-toluidinoanthraquinone

1, 5-Di-p-toluidinoanthr aquinone

1,8-Di-p-toluidinoanthr aquinone

l,4-Di(p-toluidine )-5;8-dihydroxy an thr aquinone

*Divinylbenzene

Dixylylguanidines, mixed

Dodecylbenzene. (See Aliylbenzenes. )

Dodecylbenzyl chloride

Dodecylmethylbenzyl chloride

*p-Dodecylphenol

Bosin (2',4',5',7'-Tetrabromofluorescein)

Epoxycyelohexyladipate (Ipoxide 289)

3-(lpoxyethyl)-7-oxabicyclo[4.1.0]heptane (Epoxide 206)

o-Ethoxybenzoic acid

6-Ethoxy-2-benzothiazolethiol

4- Ethoxy-3-methoxybenzaldehyde

4-Ethoxy-3-methoxybenzyl alcohol

1- (4- Ethoxy-3-methoxybenzyl )-6, 7-dimethoxy-3-methyl- isoquinoline.

(4-Ethoxy-3-methoxyphenyl )acetic acid

2-Ethoxy-l-naphthaldehyde

2-Ethoxynaphthalene

2-Ethoxy-l-naphthoic acid

2-Ethoxy-l-naphthoyl chloride

4-Ethoxy-o-phenylenediamine

3-(Ethylamino)-p-cresol

3-(Ethylamino)-p-toluenesulfonic acid [S03H=1]

*N-Ethylaniline, refined

G.

EK, RSA,

SEL.

AAP, ACT.

DUP, G, NAC.

AAP, ICI,

TRC.

TRC.

DUP.

DUP, NAC.

TRC.

DUP, GAM,

SAL.

EK.

DUP, MAY.

RH.

DUP.

AAP.

TRC.

TRC.

AAP, DUP,

NAC, SDC, VPC.

EK.

EK.

ACT, DUP,

G, GGY, NAC, SDH, TRC

DUP, NAC.

DUP, MOB.

NAC.

PAS.

DUP, ICI,

VPC.

AAP, DUP.

EKT, ICI.

ARA.

ARA, BPC.

ACY, DOW,

DUP, 0R0.

ICI.

LIL.

DOW, RPC.

ARA.

ARA.

ARA.

EK.

NAC.

LIL, MEE.

ATL, CMG,

G, ICI, NAC, TRC, VPC

ICI.

ICI.

ICI.

DOW, FG,

KPP.

ACT.

CO.

x.

G, MON, UCC, x.

ICC.

UCC.

UCC.

ACT.

ARA, DUP.

LIL.

LIL.

LIL.

LIL.

ICO.

ICO, NAC.

ICO.

ICO, OPC.

TRC.

DUP.

DUP.

ACY, DUP,

NAC, SDH.

CYCLIC INTERMEDIATES

79

TABLE 7B.

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

2-(N-Ethylanilino)ethanol

[ 2-( N-Ethylanilino )ethyl] trimethylammonium chloride

3-(N-Ethylanilino)propionitrile

a-(N-Ethylanilino)-m-toluenesulfonic acid

<x-(N-Ethylanilino)-p-toluenesulfonic acid

N-Ethyl-p-anisidine

2-Ethylanthraquinone

*Ethylbenzene

o-(p-Ethylbenzoyl)benzoic acid

Ethylbenzyl chloride

9-EthylcarbazQle

N-Ethyl-N-(2-chloroethyl)aniline

N-Ethyl-1-cyclohexen-l-ylamine

3,3'-Ethylenedioxydiphenol

Ethylenimine

2-[ N-Ethyl-p- [(6-methoxy-2-benzo-thiazolyl)azo]anilino ]- ethanol.

N-Ethyl-1-naphthylamine

9-Ethyl-3-nitrocarbazole

p-Ethylphenol

*N-Ethyl-N-phenylbenzylamine

N-Ethyl-N-phenylbenzylamine sulfonic acid

Ethylphenylmalonic acid, diethyl ester

l-(o-Ethylphenyl)-3-methyl-2-pyrazolin-5-one

5-Ethyl-2-picoline (2-Methyl-5-ethylpyridine) (MKP)

1-Ethylpiperidine

2-Ethylpyridine

N-Ethyl-5-sulfoanthranilic acid

6-Ethyl-l, 2, 3, 4-tetrahydro-l, 1, 4, 4-tetramethylnaphthalene-

N- Ethyl -m-toluidine

N-Ethyl-o-toluidine

2-(N-Ethyl-m-toluidino)ethanol

3-(N-Ethyl-m-toluidino)-l, 2-propanediol

3-(N-Ethyl-m-toluidino)propionitrile

1-Ethynyl-l-eyclohexanol

Fluorescein (3',6'-Dihydroxyfluoran)

l-Fluoro-2, 4-dinitrobenzene

o-Fluorotoluene

4-Formyl-m-benzenedisulfonic acid

m-Formylbenzenesulfonic acid, sodium salt

*o-Formylbenzenesulfonic acid (o-Sulfobenzaldehyde)

Fur an

Furfuryl alcohol

Furfurylamine

Gentisic acid (2,5-Dimethoxybenzoic acid), methyl ester—

Hexachlorobenzene

Hexachlorocyclopentadiene

1, 4, 5, 6, 7, 7-Hexachloro-5-norbornene-2, 3-dicarboxylic acid

Hexachlorophenyl ether

Hexadecachlorophthaloeyanine

Hexa(2-methyl-l-aziridinyl )-l,3, 5-phosphotriazine

Hippuric acid

*p-Hydrazinobenzenesulfonic acid

4-Hydrazino-m-toluenesulfonic acid

Hydroquinone, tech

2'-Hydroxyacetophenone

3'-Hydroxyacetophenone

4'-Hydroxyacetophenone

3 ' -Hydroxyacetophenone benzoate

6'-Hydroxy-m-acetotoluidide

p-Hydroxybenzaldehyde

*p-Hydroxybenzenesulfonic acid

2-Hydroxy-llH-benzo [a]carbazole-3-carboxylic acid

p-Hydroxybenzoic acid

p-Hydroxybenzoic acid, butyl ester

p-Hydroxybenzoic acid, ethyl ester

p-Hydroxybenzoic acid, n-heptyl ester

*p-Hydroxybenzoic acid, methyl ester

*p-Hydroxybenzoic acid, propyl ester

4-Hydroxycoumarin

13b-Hydroxy-2, 8-dimethylnaphtho[3 . 2. 1-kl] xanthen-9(l3bH)- one.

Manufacturers ' identification codes (according to list in table 22)

DUP,

EKT.

DUP.

EKT.

G.

NAC,

SDH, TRC, WJ.

EKT.

G, NAC.

DOW,

ENJ, FG, KPP, KPT

G, NAC.

BPC.

AAP,

ICC.

DUP.

UCC,

x.

IDC.

DOW.

TRC.

DSC,

DUP.

AAP,

ICI.

ACY.

DOT,

NAC, SDH.

VPC.

BPC,

MAL.

TRC.

UCC.

RIL.

RIL.

G.

GIV.

DUP.

DUP.

G.

EKT.

DUP,

EKT, G.

cue,

EKT, NAC.

ICC.

EK.

EK,

PIC.

G, SDH.

G.

G, NAC, SDH, VPC.

DUP.

QKO.

MLS.

ICO.

KPS,

KPT, SCC.

HK,

VEL.

HK.

DOW.

ICC.

ICO.

BPC.

G, STG, WJ.

G.

CRS,

EKT, MAN.

OTC.

SDH.

OTC.

SDH

TRC

DOW

DOW

MON, UPF.

G.

HN,

WSN.

UN,

WSN.

HN,

WSN.

WSN

HN,

ICO, SEL, WSN.

HN,

ICO, WSN.

MON, SHC, SIN, SNT, TOC, UCC.

80

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1 965 --Continued

Manufacturers' identification codes (according to list in table 22)

3-[N-(2-Hydroxyethyl)anilino]propionitrile

N-|3-Ifydroxyethyl-2,4-d ihydroxybenzanri.de

3-Hydroxy-N-(2-hydroxyetnyl)-2-naphthanride

N-t 7-Ifydroxy-8- [2-hydroxy-5-(methylsulf amoylphenyl )azo] -

1-naphthyl] acetanri.de. N-L~7-Hydroxy-8-[(2-hydroxy-5-nitrophenyl)azo]-l-naphthyl]-

acetanride. 7-Hydroxy-8- [[<+'-[ (p-hydroxyphenyl )azo] -4-biphenylyl] azo] -

1, 3-naphthalenedisulfonic acid. 7-Hyd roxy-8-[[ 4' -[ (p-hydroxyphenyl )azo] -3, 3-dime thyl-4- biphenylyl]azo]-l, 3-naphthalenedisulfonic acid.

4-Hydroxy-N1-isopropy lmetanilanri.de

2-Hydroxy-a1, cc3-mesitylenediol

*4-Hydroxymetanilanride

4-ffydroxymetanilanilide

*4-Hydroxymetanilic acid

N-(4-Hydroxymetanilyl)anthranilic acid

4-Hydroxy-l-methycarbostyril

3-Rydroxy-2-methylcinchoninic acid

4-Ifydroxy-N1-methy lmetanilanri.de

N-(Hydroxymethyl)phthalamide

Ifydroxynaphthaldehyde

7-Hydroxy-l-naphthalenecarbamic acid, methyl ester

3-Hydroxy-2,7-naphthalenedisulfonic acid

*3-Hydroxy-2, 7-naphthalenedisulfonic acid, disodium salt

7-Hydroxy-l, 3-naphthalenedisulfonic acid

7-ffydroxy-l, 3-naphthalenedisulfonic acid, dipotassium salt —

7-Rydroxy-l,3-naphthalenedisulfonic acid, disodium salt

4-ifydroxy-2-naphthalenesulfonanri.de

l-Hydroxy-2-naphthalenesulfonic acid, potassium salt

4-Ifydroxy-l-naphthalenesulfonic acid

5-Hydroxy-l-naphthalenesulfonic acid

*6-Ifydroxy-2-naphthalenesulfonic acid

*6-Rydroxy-2-naphthalenesulfonic acid, sodium salt

7-Ifydroxy-2-naphthalenesulfonic acid (Cassella's acid)

8-Hydroxy-l-naphthalenesulfonic acid

8-Hydroxy-l-naphthalenesulfonic acid, Y-sultone

4-Ifydroxy-2-naphthalenesulfonie acid benzenesulfonate, sodium salt.

3-Hydroxy-2-naphthanilide (Naphthol AS)

l-Rydroxy-2-naphthoic acid

l-lfydroxy-2-naphthoic acid, phenyl ester

*3-Ifydroxy-2-naphthoic acid (B.O.N.)

3-lfydroxy-2-naphthoie acid, methyl ester

3-Ifydroxy-2-naphtho-o-toluidide

N-( 2-Ifydroxy- 1-naphthyl Jacetanride

*N-(7-Rydroxy-l-naphthyl)acetamide

l-(2-Ifydroxy-l-naphthylazo)-6-nitro-2 -naphthol -4-sulfonic acid.

N-(7-Ifydroxy-l-naphthyl)benzamide

3'-[(7-Hydroxy-l-naphthyl)carbamoyl]acetanilide

4-Ifydroxy-7-[ p-(p-nitrobenzanri.do )benzamido ]-2-naphthalene-

sulfonic acid. 4-hydroxy-7-(p-nitrobenzamido)-2-naphthalenesulfonic acid —

2-Ifydroxy-5-nitrometanilic acid

l-(2-Hydroxy-4-nitrophenylazo)-2-naphthol

3-Ifydroxy-4-(phenylazo)-2-naphthoic acid

lla-Hydroxypregn-4-ene-3,20-dione

4-Hydroxypropiophenone

a> <x'-[ (a-Hydroxy-p-sulf obenzylidene)bis[ (3-methyl-p- phenylene)(ethylimino)]] di-m-toluenesulfonic acid. 2-Hydroxy-4-sulfo-l-naphthalenediazonium hydroxide, inner salt.

l-Hydroxy-4-p-toluidinoanthraquinone

2-Inridazolidinone modifications

*1, l'-Iminobis[4-aminoan'thraquinone]

1, l'-Iminobis[4-benzamidoanthraquinone]

*1, l'-Iminobis[5-benzamidoanthraquinone]

*7,7'-Iminobis[4-hydroxy-2-naphthalenesulfonic acid]

*1, l/-Iminobis[4-nitroanthraquinone]

*l,l'-Iminodiaiithraquinone (l,l'-Dianthrimide)

DUP, ICC. IDC. IDC. TRC.

TRC.

TRC.

ACY.

CMC,

DUP,

NAC, TRC, VPC.

TRC.

CWN,

DUP,

NAC, TRC.

TRC.

ICC.

DUP,

ICC,

TRC.

TRC.

ACY.

ICO.

TRC.

ATL.

ACY,

G, NAC, TRC, WJ.

DUP,

TRC.

G.

ACY,

NAC.

G.

EK.

DUP,

NAC.

NAC,

TRC.

NAC,

SNA,

TMS.

ACY,

TRC,

WJ.

DUP.

G, VPC.

ACY,

TRC.

G.

ATL,

PCW.

NAC.

EK.

AUG,

DUP,

HN, PCW.

PCW.

ATL,

PCW.

ACY.

CMG,

G, TRC.

TRC.

TRC.

TRC.

DUP.

DUP,

G.

ALL,

G, TRC.

TRC.

ICC.

UPJ.

MLS.

TRC.

ACY.

G, ICI.

RH.

ACY,

CMG,

DUP, G, ICI, MAY, NAC, TRC

ACY,

MAY.

G, ICI, TRC.

CMG,

DUP,

NAC, TRC.

ACY,

DUP,

ICI, MAY, TRC.

ACY,

DUP,

G, ICI, MAY, NAC, TRC.

CYCLIC INTERMEDIATES

TABLE 7B. —Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

1,3-Indandione

Indole-3-acetic acid-

Indole-2,3-dione

1-Iodonaphthalene

Isobutylbenzene

*Isocyanic acid derivatives :

Bitolylene diisocyanate (TODI)

Cyclohexyl isocyanate

Dianisidine diisocyanate (DADI)

3,4-Dichlorophenyl ester

*Diphenylmethane 4,4'-diisocyanate (MDI)

Phenylisocyanate

Polymethylene polypheny lisocyanate

Toluene 2,4-diisocyanate

Toluene 2,4- and 2,6-diisocyanate (65/35 mixture)

*Toluene 2,4- and 2,6-diisocyanate (80/20 mixture)

Other isocyanic acid derivatives

Isonicotinic acid, methyl ester

Isonicotinonitrile

Isooctylphenol

Isophthalic acid (Benzene-l,3-dicarboxylic acid)

Isophthalic acid, diallyl ester

Isophthalic acid, dimethyl ester

Isophthalic acid, diphenyl ester

N-Isopropylaniline

Isopropylbenzyl chloride

4,4'-Isopropylidenebis[2, 6-dibromophenol] (Tetrabromobis-

phenol A). 4,4'-Isopropylidenebis[2,6-dichlorophenol] ( Tetrachloro- bisphenol A).

5,5'-Isopropylidenebis(2-hydroxy-m-xylene-a, a'-diol)

*4,4'-Isopropylidenediphenol (Bisphenol A)

4,4'-Isopropylidenediphenol, ethoxylated

4,4'-Isopropylidenediphenol, propoxylated

o-Isopropylphenol

4-Isopropyl-m-phenylenediamine ■

Isothiocyanic acid, phenyl ester

*Isoviolanthrone (isodibenzanthrone)

*Leuco quinizarin (1,4, 9,10- Anthratetrol)

2,4-Lutidine ■

3,4-Lutidine

Mandelonitrile

*Melamine

dl-p-Mentha-1, 8-diene (Limonene)

p-Mentha-l,4(8)-diene

*o-Mercaptobenzoic acid

Metanilamide

*Metanilic acid (m-Aminobenzenesulfonic acid)

1-Methoxyanthraquinone

4-Methoxymetanilic acid

6-Methoxymetanilic acid

4'-Methoxy-2-(p-methoxyphenyl)acetophenone

4-Methoxy-l-naphthol

N-(2-Methoxy-l-naphthyl)aeetamide

2-Methoxy-4-nitrophenol

6-Methoxy-8-nitroquinoline

m-Methoxyphenol

Methoxyphenylacetic acid

4' -Methoxypropiophenone

6-Methoxytetralone

*1- ( Methylanri no ) anthraquinone

l-(Methylamino)-4-p-toluidinoanthraquinone

N-Methylaniline

2-(N-Methylanilino)ethanol

3-(N-Methylanilino)propionitrile

5-Methyl-o-anisidine [ NH2=l]

m-Methylanisole

N-Methylanthranilic acid

2-Methylanthraquinone

3-Methylbenzo'[f]quinoline

2-Methylbenzothiazole

a-Methylbenzyl alcohol

PIC.

SDW.

NAC.

EK.

PLC.

UPJ.

CWN,

OTC.

CWN,

UPJ.

DUP.

DuT?,

MOB,

NAC, UPJ.

CWN,

MOB,

OTC.

MOB,

UPJ.

DUP,

MOB.

DUP,

MOB,

NAC.

DUP,

MOB,

NAC, CMC, UCC.

DUP,

EK,

MOB, OTC.

RIL.

RIL.

G, PRD.

ACC,

SOC.

FMP.

MTR.

BJL.

ACY,

EKT.

BPC.

DOW.

DVC.

ARK.

DOW,

MON,

SHC, UCP.

APD.

APD.

TNA.

DUP.

TNC.

DUP,

G, MAY.

AAP,

ACY,

BL, EKT, HSH, ICC, NAC, TRC

ACP,

KPT.

RIL.

KF.

ACN,

ACY,

FIS, RCI.

GIV,

HNW.

GIV.

EVN,

LIL,

MED.

CMG,

VPC.

DUP,

NAC,

TRC.

AAP,

G.

ACY,

CMG.

G.

CTN.

SDH.

TRC.

MEE.

GAM.

EK.

SDW.

LIL.

GAM.

AAP,

ACY,

DUP, G, NAC, TRC.

G.

ACY,

DUP.

G.

DUP.

DUP.

GIV.

ICC.

ACY,

NAC.

ACY,

G.

FMT.

UCC.

82

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1 965 --Continued

N-Methylbenzylamine

Methyl benzyl ether

5-(l-Methylbutyl)barbituric acid

3-Methylcholanthrene

Methylcyclohexane

Methylcyclohexenecarboxaldehyde

N-Methylcyclohexylamine

4-Methyl-a,a-diphenyl-l-piperazineethanol dihydrochloride —

N-Methyleneaniline

4,4'-Methylenebis[2-chloroaniline]

4,4'-Methylenebis[N, N-diethylaniline]

*4,4'-Methylenebis[N, N-dimethylaniline] (Methane base)

4,4'-Methylenebis[N, N-dimethyl-3-nitroaniline]

5,5'-Methylenebis[toluene-2,4-diamine]

*4, 4'-Methylenedianiline

5,5'-Methylenedisalicylic acid

5-Methylene-2-norbornene

Methylhydroquinone

6-Methyl-2-(2-methyl-6-quinolyl)-7-benzothiazolesulfonic

acid.

Methylnaphthalene, crude

N-Methyl-4'-nitroacetanilide

N-Methyl-p-nitroaniline

5-Methyl-4-nitro-o-anisidine

4-Methyl-2-nitroanisole

2-Methyl-l-nitroanthraquinone

2-Methyl-5-nitroimidazole

N-Methyl-N-nitroso-p-toluenesulfonamide

Methylnorbornene-2,3-dicarboxylic anhydride, isomers

4-Methyl-7-oxabicyclo[4.1.0]heptane-3-carboxylic acid,

(4-methyl-7-oxabicyclo [4 . 1 . 0] hept-3-yl )methyl ester

(Epoxide 201).

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl)beneenesulfonamide

m-(3-Methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonic acid

*p-(3-Methyl-5-oxo-2-pyrazolin-l-yl )benzenesulfonic acid

3-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-l,5-naphthalenedi-

sulf onic acid . *4-(3-Methyl-5-oxo-2-pyrazolin-l-yl)-m-toluenesulfonic acid

[S03H=1].

2-Methyl-5-phenylbenzoxazole

1-Methyl-l-phenylhydrazine

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid

5-Methyl-3-phenyl-4-isoxazolecarboxylic acid hydrochloride —

*3-Methyl-l-phenyl-2-pyrazolin-5-one (Developer Z)

Methyl phenyl sulfide (Thioanisole)

1-Methylpiperazine

2-Methyl-l-piperidinepropanol

l-Methyl-4-piperidinol

1-Methylpyrrole

*<x-Methylstyrene

N-Methyl-5-sulfoanthranilic acid

2-(Methylsulfonyl)-4-nitroaniline

p-(Methylthio)aniline hydrochloride—

4-(Methylthio)-m-cresol

3-Methylthiophene

p-(Methylthio)phenol

3-Methyl-6-p-toluidino-7H-dibenz[f,ij]isoquinoline-2,7(3H)-

dione.

3-Methyl-l-p-tolyl-2-pyrazolin-5-one

1-Naphthaldehyde

^Naphthalene, solidifying at 79° C. or above (refined flake)

(from domestic crude).

1, 5-Naphthalenediol ( 1, 5-Dihydroxynaphthalene )

1, 5-Naphthalenedisulf onic acid

2,7-Naphthalenedisulfonic acid

1-Naphthalenesulfonic acid

1-Naphthalenesulfonic acid, sodium salt

2-Naphthalenesulfonic acid

2-Naphthalenesulfonic acid, sodium salt

2-Naphthalenesulfonyl chloride

*1, 4, 5,8-Naphthalenetetracarboxylie acid

Manufacturers' identification codes (according to list in table 22)

ICO, MLS.

UCC.

LIL.

EK.

PLC.

UCC.

DUP.

ABB.

DUP.

DUP.

ACY, G.

ACY, DSC, DUP, G, NAC, SDH,

G.

DUP, NAC.

DOW, DUP, NAC.

HN.

DOW.

EKT.

DUP.

KPT, VEL.

G, NAC.

G.

PCW.

DUP.

DUP, G, ICI, TRC.

PDA.

EK.

NAC.

UCC.

CMG, VPC.

G, TRC, VPC.

AAP, ACY, CMG, DUP, G, TRC, VPC.

TRC.

CMG, G, VPC.

EK.

EK.

ICO.

ICO.

DOW, DUP, NAC, SDH, SDW, VPC.

PIT.

UCC.

LIL.

ARA.

DUP.

ACP, CLK, DOW, HPC, SKL.

G.

EKT.

evn.

CRZ. SDW. CRZ.

VPC. COK. KPT, NAC, RIL.

NAC.

AUG, DUP, NAC.

DUP, TRC.

TRC.

ICO, TRC.

ACY, FIN, NAC.

ACY.

DUP.

AAP, G, HST, TRC.

CYCLIC INTERMEDIATES

83

TABLE 7B.

■ Cyclic intermediates for which U. S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

1,3,6-Naphthalenetrisulfonic acid

Naphthalic anhydride

Naphthalimide

2H-Naphth[l,8-cd]isothiazole-3,5-disulfonic acid, 1,1-

dioxide, trisodium salt. 1-Naphthoic acid

*l-Naphthol (cc-Naphthol)

2-Naphthol, tech. (8-Naphthol)

p-Naphtholbenzein

1,4-Naphthoquinone

Naphthostyril

*Naphth[l, 2-d] [l,2,3]oxadiazole-5-sulfonic acid

1-Naphthylamine (a-Naphthylamine)

2-Naphthylamine (B-Naphthylamine)

p- ( 2-Naphthylamino )phenol ( N- (p-Hydroxyphenol ) -2-naphthyl- amine).

cc-Naphthylphenyloxazole

2- ( Naphthylthio ) acetic acid

Nicotinonitrile (3-Cyanopyridine)

Nitro-aceanthra [2, 1-a] aceanthrylene-5, 13-dione

4'-Nitroacetanilide

2'-Nitro-p-acetanisidide

3 ' -Nitro-p-acetanisidide

4'-Nitro-o-acetanisidide

2'-Nitro-p-acetophenetidide

3'-Nitroacetophenone

5'-Nitro-o-aeetotoluidide

m-Nitroaniline

o-Nitroaniline

*p-Nitroaniline

2-Nitro-p-anisidine [NH2=1]

*4-Nitro-o-anisidine [NH2=l]-

*5-Nitro-o-anisidine [NH2=l]-

o-Nitroanisole

p-Nitroaaisole

4-Nitroanthranilic acid

4(and 5)-Nitroarithranilic acid '■

5-Nitroanthranilic acid

1-Nitroanthraquinone

2- (4-Nitro-2-anthraquinonyl )anthra[ 2, 3-d] -oxazole-5, 10- dione.

m-Nitrobenzaldehyde

3'-Nitrobenzanilide

4'-Nitrobenzanilide

*Nitrobenzene

■xm-Nitrobenzenesulfonic acid

*m-Nitrobenzenesulfonic acid, sodium salt

5'-Nitrobenzenesulfono-o-toluidide

m-Nitrobenzenesulfonyl chloride

p-Nitrobehzenesulfonyl chloride

5-Nitro-2-benzimidazolinone

m-Nitrobenzoic acid

m-Nitrobenzoic acid, sodium salt

p-Nitrobenzoic acid

2-(m-Nitrobenzoyl)-o-acetanisidide

m-Nitrobenzoyl chloride

p-Nitrobenzoyl chloride

4' -Nitro-4-biphenylcarboxylie acid

2-Nitro-p-cresol

Nitrocyclohexane

5-Nitro-4,6-diaminopyrimidine

Nitrodiphenylamine

5-Nitro-2-furaldehydesemioxamazone

5-Nitro-2-furanmethanediol, diacetate

5-Nitroisatoic anhydride

5-Nitroisophthalic acid »-

1-Nitronaphthalene '

*3-Nitro-l,5-naphthalenedisulfonic acid

8(and 5)-Nitro-l(and 2)-naphthalenesulfonic acid

4-Nitronaphthalic anhydride

*7(and 8)-Nitronaphth[l,2-d] [l,2,3]oxadiazole-5-sulfonic acid

DUP.

DUP,

G, NAC.

DUP.

COK.

DUP,

NAC,

UCC.

ACY,

NAC,

SW.

EK.

EKT.

DUP,

NAC.

CMG,

G, NAC, TRC, VPC.

DUP,

NAC.

X.

G.

ARA.

ACY.

NEP,

RIL.

ICI.

G, TRC.

DUP,

SDH.

AAP.

DUP.

AAP.

SDH.

DUP.

ACY,

DUP,

TRC.

AAP,

MON.

AAP,

MON,

SDC, UPM.

DUP,

SDH.

AAP,

DUP,

SDH.

ACY,

ALL,

DUP, KLS.

AAP,

DUP,

MON.

DUP.

DUP.

DUP.

MEE,

TRC.

ACY.

G.

NAC,

SDH.

DUP.

G.

ACY,

DUP,

MON, NAC.

ACY,

DUP,

NAC.

AAP,

G, MAY, MON, MRA

RBC.

G.

EK.

DUP.

SDH,

WAY.

WAY.

DUP.

G.

HK.

DUP,

HK.

DUP,

TRC.

SW.

DUP.

KF.

ACY.

NOR.

NOR.

MEE.

G, GAM.

DUP,

NAC.

G, NAC, TRC.

G.

G, NAC.

G, NAC, TRC, VPC.

SYNTHETIC ORGANIC CHEMICALS, 1965

—Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965— Continued

Manufacturers' identification codes (according to list in table 22)

4'-Nitrooxanilic acid

o-Nitrophenol

*p-Nitrophenol ■

*p-Nitrophenol, sodium salt

4' -(p-Nitrophenyl )acetophenone

4-[ (p-Nitrophenyl )azo]-o-anisidine

2-Nitro-p-phenylenediamine

4- Nitro-o-phenylenediamine

(p-Nitrophenyl )hydrazine

(p-Nitrophenyl )hydrazine hydrochloride

2-(p-Nitrophenyl)-2H-naphtho[l,2-d] triazole-6, 8-disulfonic acid.

l-(m-Nitrophenyl)-5-oxo-2-pyrazoline-3-carboxylic acid

3-Nitrophthalic acid

4- Nitrophthalic acid

3-Nitrophthalic anhydride

4-Nitrophthalimide

5-Nitrosalicylaldehyde

3(and 5)-Nitrosalicylic acid

p-Nitrosophenol

[3-Nitrostyrene

4-Nitro-4'-(5-sulfo-2H-naphthol[l,2-d]triazol-2-yl)-2,2'- stilbenedisulfonic acid.

m-Nitrotoluene

o-Nitrotoluene

p-Nitrotoluene

Nitrotoluene mixtures

p-Nitrotoluenesulfonic acid

*3-Nitro-p-toluenesulfonie acid [S03H=l]

*5-Nitro-o-toluenesulfonic acid [S03H=l]

4'-Nitro-p-toluenesulfono-o-toluidide

3-Nitrotoluic acid chloride

3-Nitro-p-toluic acid, methyl ester

*2-Nitro-p-toluidine [NH2=l]

4-Nitro-o-toluidine [NH2=l]

5-Nitro-o-toluidine [NH2=l]

5-Nitro-2-p-toluidinobenzenesulfonic acid

*16-Nitroviolan throne

4-Nitro-m-xylene

Nitroxylenes, mixed

2-tert-Nonyl-p-cresol

Nonyl-dinonylphenol, mixture

*Nonylphenol

5-Norbornene-2,3-dicarboxylic anhydride

Octylphenol

7-0xabicyclo[4.1.0]heptane

Qxalacetic acid, diethyl ester, (p-sulf ophenyl )hydrazone

Oxanilide

*l-[ (7-0xo-7H-benz[de]anthracen-3-yl)amino] anthraquinone

*1, l'-[(7-Oxo-7H-benz[de]anthracen-3,9-ylene)diimino]di- anthr aquinone .

2-Qxocyclohexanecarboxylic acid, ethyl ester

2-0xocyclopentanecarboxylic acid, ethyl ester

5-Qxo-l-phenyl-2-pyrazoline-3-carboxylic acid

*5-0xo-l-phenyl-2-pyrazoline-3-carboxylic acid, ethyl ester — *5-Qxo-l- (p-sulf ophenyl )-2-pyrazoline-3-carboxylic acid ( Pyrazolone T ) .

5-Qxo-l-(p-sulfotolyl)-2-pyrazoline-3-carboxylic acid

4,4'-0xydianiline

4,4'-0xydiphenol

Penicillin, N-ethylpiperidine salt

1, 1, 3,3,5-Pentamethylindan

Pentylnaphthalenes ( Amy lnaph thai enes )

o-Pentylphenol (o-Amylphenol )

p-tert-Pentylphenol

3,4, 9, 10-Perylenetetracarboxylic acid

3,4, 9,10- Perylenetetracarboxylic 3,4:9, 10-diimide

Phenethylamine

Phenethylamine sulfate

o-Phenethylbenzoic acid

o-Phenetidine

p-Phenetidine

DUP.

DUP.

DUP, MON, SDC, UPM.

MON, UPM.

DUP, G.

AAP.

WAT.

DUP, FMT.

EK.

EK.

ACY,

DUP,

NAC.

OWN,

UPJ.

TRC

DUP,

NAC.

DUP,

NAC.

DUP,

NAC.

DUP,

NAC.

GGY.

AAP,

CMG,

G, TRC.

ACY,

DUP,

G, NAC, SDH, TRC.

G.

X.

SDH.

ACY,

DUP,

NAC, SDH, SW.

ABB,

G.

BUC,

DUP,

KLS, PCW.

TRC.

ACY,

ATL,

G, ICI, MAY.

DUP.

DUP,

NAC.

USR.

JCC.

G, JCC, MON, PRD, RH, STP, UCP, USR

NAC.

G, RH.

ARA.

TRC.

WSN.

ACY,

DUP,

G, ICI, MAY, TRC.

ACY,

DUP,

G, ICI, MAY, NAC, TRC.

ARA.

ARA.

NAC.

G, SDW, VPC.

AAP,

G, ICI, VPC.

VPC.

OTC,

X.

EK.

MRK.

GIV.

PAS.

PAS.

PAS,

UCP.

DUP,

G, NAC.

DUP,

G, NAC.

ICO,

MLS.

MLS.

LIL.

MON.

DOW,

MON.

CYCLIC INTERMEDIATES

85

TABLE 7B.

■Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

•Phenol: •Natural :

•From coal tar:1

39° C, m.p

82^-84%

All other

•From petroleum

•Synthetic:

By caustic fusion: U.S.P

From chlorobenzene by liquid -phase hydrolysis: U.S.P

From chlorobenzene by vapor-phase hydrolysis: U.S.P

•From cumene by oxidation: U.S.P

Phenolsulfonaphthalein, sodium salt —

Phenothiazin-2-yl-l-propanone

Fhenoxyacetic acid, sodium salt

2-Phenoxypropanol

2-Phenoxypropionic acid

2-Phenoxypropionyl chloride

•Phenylacetic acid (a-Toluic acid)

Phenylacetic acid, ethyl ester, tech

Phenylacetic acid, methyl ester

•Phenylacetic acid, potassium salt

•Phenylacetic acid, sodium salt

Phenylacetonitrile (a-Tolunitrile)

4'-Phenylacetophenone

Phenylacetyl chloride

2-Phenylanthra[2,3-d] oxazole-5, 10-dione

»p-Phenylazoaniline (C. I. Solvent Yellow 1) and hydrochloride

p-Phenylazoaniline sulfate

4- ( Phenylazo )diphenylamine

4- ( Phenylazo ) -1-naphthylamine

4- ( Phenylazo )-m-phenylenediamine (C.I. Basic Orange 2)

5- ( Phenylazo )salicylic acid

^-Phenyl-l, 2,4-benzenetriamine

l-Phenyl-l,3-butanedione

2-Phenylbutyric acid

a-Phenyl-o-cresol

1-Phenyldecane ( Decylbenzene )

N, N'-p-Phenylenebis[acetamide]

m-Phenylenediamine

o-Phenylenediamine

p-Phenylenediamine

Phenyl ether (Diphenyl oxide)

d-2-Phenylglycine

d-(-)-2-Phenylglycine and derivatives

dl-2-Phenylglycine (racemic )

Phenylglycine, sodium salt

d-(-)-2-Phenylglycyl hydrochloride

5-Phenylhydantoin--

Phenylhydrazine

Phenylhydrazine hydrochloride

2,2'-[(Phenyl)imino]diethanol (N-Phenyldiethanolamine)

3,3'-[(Phenyl)imino]dipropionitrile

Phenylmagnesium bromide

Phenylmalonic acid, diethyl ester

o-Phenylphenol

o-Phenylphenol, chlorinated

o-Phenylphenol, sodium salt

p-Phenylphenol

N-Phenyl-p-phenylenediamine

Phenylphosphinic acid

Phenylphosphonic dichloride

Phenylphosphonothioic dichloride

Phenylphosphonous acid

Phenylphosphonous acid, sodium salt

Phenylphosphorous dichloride

1-Phenylpiperazine "

«1-Phenyl-1, 2-propanedione, 2-oxime

Phenyl-2-propanone

N-3-Phenylpropyl-p-toluidine

See footnote at end of table.

Manufacturers ' identification codes (according to list in table 22)

KPT, PRD.

ACP, KPT.

ACP, KPT.

MER, NPC, PIT, PRD, SW.

MAL,

DOW.

HKD,

ACP,

EK.

WYT.

BPC.

ICO.

ICO.

ICO,

BPC,

BPC.

BPC.

BPC,

BPC,

BPC,

DUP,

ICO.

G.

AAP,

DUP.

EK.

DUP.

DUP.

TRC.

RBC.

EK.

BPC.

RBC.

NAC.

ACY.

ACY,

FMT,

ACY,

DOW.

BPC.

KF.

KF.

NAC,

OTC.

ABB,

DOW.

EK,

AAP,

DUP.

ARA.

BPC.

DOW,

DOW.

DOW.

DOW.

DUP,

SF.

SF.

SF.

RSA. ICC, ORT,

MON, RCI.

CLK, HPC, MON, SHC, SKO, SOC.

OPC.

GIV, MAL, TBK.

OPC, TBK. OPC.

OPC, SDW. G, NES.

ACY, DUP, G, NAC.

DUP, G. NAC. MEE, TRC. BFG.

VPC. DUP, EKT.

NEP, ORT, x. SK.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 7B.

-Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 2365--Continued

Phenyl 2-pyridyl ketone

Phenyl 4- pyridyl ketone

Ehenyl sulfone

l-Fhenyl-2-thiourea

Phloroglueinol

l(2H)-Fhthalazinone

Ehthalic acid

Ehthalic acid, diallyl ester

Ehthalic acid, disodium salt

*Fhthalic anhydride

Ehthalide

Ehthalimide

Ehthalimide, potassium salt

IEhthalocyaninatoC 2-)] copper Ehthalocyaninato(2-)]iron

Ehthalocyaninetetrasulfonyl chloride, copper derivative Ehthaloyl chloride (Ehthalyl chloride)

♦Ficolines:1

*2-Picoline (a-Picoline)

3-Picoline (fi -Picoline)

4-Pieoline (y-Picoline)

Ficoline (3,4-mixture)

Picolinic acid

Picolinonitrile (2-Cyanopyridine)

3-Picolylamine

Picric acid (Trinitrophenol)

2-Pipecoline

4-Pipecoline

Piperazine mixture, crude

*Piperidine

3-Piperidinopropiophenone hydrochloride

Polychlorobiphenyl

Primuline base ■

Primulinesulfonic acid

*Propiophenone

2-Propylpyridine

*8, 16-Pyranthrenedione

Pyridine, refined z1

*2° Pyridine

Other grades

Pyridine hydrochloride

2-Pyridineethanol

3-Pyridinemethanol

Pyridinium bromide perbrond.de

3-Pyridinol

2(lH)-Pyridone

2-Pyrimidinol

2-Pyrrolidinone

3-(l-Pyrrolidinyl)propiophenone hydrochloride

lH-Pyrrolo [2, 3-6] pyridine

*Quinaldine

Quinoline :

1° and 2° Quinoline

Other grades

2,4-Quinolinediol

8-Quinolinol (8-Hydroxyquinoline, tech. )

Quinophthalone (Quinoline yellow, base)

Resorcinol, monoacetate (nonmedicinal grade)

Resorcinol, tech

Resorcinol, mono-fi-hydroxyethyl ether

p-Resorcylaldehyde—

(3-Resorcylic acid

(3-Resorcylic acid, lead salt

*Salicylaldehyde

*Salicylic acid, tech

Salicylic acid, ammonium chromium complex

Salicylic acid, sodium chromium complex

Salicylic acid, sodium salt (crude)

Salicylideneaminoguanidine oleate

Manufacturers ' identification codes (according to list in table 22)

NEP, RIL.

RIL.

NES.

ICO.

MRT.

KPT, NAC, SDH.

EK, KF.

FMP.

INC.

ACP, GRH, HN, KPS, MON, PCC, RCI, SOC, STP, SW, THC,

UCC, WTC. FMT, NAC. DUP, MEE, NAC. EK.

ICC, ICI. DUP. DUP. MON.

ACP, KPT, RIL, UCC.

NEP, RIL.

RIL, UCC.

ACP, KPT.

NEP.

NEP, RIL.

RIL.

DUP, NAC, SDC.

LIL.

RIL.

FLM, JCC, x.

ABB, DUP, RIL.

ACY.

MON.

DUP, NAC.

ATL.

LIL, OPC, TBK.

RIL.

CMG, ICI, TRC.

ACP, KPT, NEP, RIL.

KPT.

EK.

RIL.

RIL.

ARA.

NEP.

FMT.

GGY.

G.

LIL.

SDW.

ACY, DUP, NAC.

ACP, KPT.

EK.

DUP.

GAM.

DUP, NAC.

AAP.

KPT.

BJL.

ACY, ACY. DOW, CFC, TRC. TRC. DOW. DUP.

HN, MTR, RDA. DOW, HN, MON, SDH.

See footnote at end of table.

CYCLIC INTERMEDIATES

87

TABLE 7B. --Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification cede (according to list in table 22)

Sitosterols, nonmedicinal

Sodium phenoxide

*Styrene, all grades

(3-Styrenesulfonic acid, sodium salt

4'-Sulfamoylacetanilide

Sulfanilic acid (p-Aminobenzenesulfonic acid) and salt

4-Sulfoanthranilic acid

«>a-[(p-Sulfobenzylidene)bis[(3-methyl-p-phenylene) (ethyl imino)]] di-m-toluenesulfonic acid.

5-Sulfoisophthalic acid, 1,3-dimethyl ester

3,3'-Sulfonyldianiline

4,4'-Sulfonyldianiline

N, 5'-Sulfonyldianthranilic acid

3,3'-Sulfonyldinitrobenzene

4,4'-Sulf onyldiphenol (4,4 '-Dihydroxydiphenylsulfone)

4-Sulfophthalic acid

Terephthalic acid

Terephthalic acid, dihydrazide

*Terephthalic acid, dimethyl ester

Terephthalic acid, diphenyl ester

Terephthaloyldiacetic acid, diethyl ester

Terphenyl ( Phenylbiphenyl )

1,2,4, 5-Tetraaminobenzene

[4,4', 4", 4'" -Tetr aaminophthalocyaninato ( 2- ) ] copper

3',3",5',5" -Tetrabromophenolphthalein, ethyl ester

Tetrabromophthalic anhydride

Tetrabromo-8, 16-pyranthrenedione

1,3,6, 8-Tetrabromopyrene

*1, 4, 5, 8-Tetrachloroanthraquinone

1,2,4, 5-Tetrachlorobenzene

1, 2, 4, 5-Tetrachloro-3-nitrobenzene

a,a,2,6-Tetrachlorotoluene

Tetrachloroviolan throne

Tetrahydrofuran

Tetrahydro-2-methylfuran

*1,4, 5,8-Tetrahydroxyanthraquinone, leuco derivative

1,4, 5,8-Tetrakis(l-anthraquinonylamino)anthraquinone ( Pentanthr imid e ) .

2-(l,l,3,3-Tetramethylbutyl)-p-cresol

p-(l, l,3,3-Tetramethylbutyl)phenol

3,3 ', 5, 5' -Tetramethyldiphenoquinone

N, N, N', N'-Tetramethyl-p-phenylenediamine dihydrochloride-

[4,4',4",4'"-Tetranitrophthalocyaninato(2-)]copper

1, 1,4,4-Tetraphenylbutadiene

2-(2-Thenylamino)pyridine

3,3'-Thiobis[7H-benz[de]anthracen-7-one]

4,4'-Thiodianiline

6, 6'-Thiodimetanilic acid

2-Thiopheneacetyl chloride ■

2-Thiophenecarbox aldehyde

sym- Thymol

*Toluene-2,4-diamine (4-m-Tolylenediamine)

Toluene-2,4-disulfonic acid

o-Toluenesulfonamide

p-Toluenesulfonamide

*o(and p)-Toluenesulfonic acid

p-Toluenesulfonic acid

Toluenesulfonic acid, aniline salt

p-Toluenesulfonic acid, 2-chloroethyl ester

p-Toluenesulfonic acid, ethyl ester

p-Toluenesulfonic acid, methyl ester

p-Toluenesulfonic acid monohydrate

p-Toluenesulfono-o-toluidide

p-Toluenesulfonyl chloride

m-Toluic acid

o-Toluic acid

p-Toluic acid

m-Toluidine

o-Toluidine

o-Toluidine hydrochloride

UPJ.

DUP.

ACC, CSD, DOW, ELP, FG, KPP, MCB, MON, SHC, SKC, SNT,

UCC. BKL.

ACY, CTN. ACY, CTN, NAC. CMG, TRC. TRC.

RSA. TRC.

G, MON, UPF.

CWN, UPJ.

ACC, DUP, EKT, SOC.

DUP.

ACC, DUP, EKT, HPC.

BJL.

G, PCW.

ARA, MON.

BJL.

DUP.

EK.

MCH.

G, NAC.

G.

DUP, G, ICI, NAC.

DOW, HK.

SDH.

DUP.

G, ICI.

DUP, OKO.

DUP, QKO.

G, ICC, NAC, TRC.

ICI, NAC.

ACY.

G.

DUP.

EK.

DUP.

ARA.

ABB.

DUP,

ACY,

NAC.

LIL.

ABB.

GIV.

ACY,

G.

G, ICI. NAC.

DUP, G, NAC, CMC, SDC, TRC, UCC.

MON.

MON.

MON,

ACY,

NES.

G.

NAC.

ICI.

NES,

G.

MON.

CWL.

CWL.

CWL,

DUP,

DUP,

ACY.

NAC, NES, SW, UPF. TEN.

EK.

NAC.

NAC.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE IB. — Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer, 1 965 --Continued

Manufacturers' identification codes (according to list in table 22)

p-Toluidine

p-Toluidine hydrochloride

N-(p-Toluidine)methyl taurine

Toluidines, mixed

m-Toluidinomethanesulfonie acid

8-p-Toluidino-l-naphthalenesulfonic acid

o-(p-Toluoyl)benzoic acid

N-(p-Tolylazo)sarcosine

*4-(o-Tolylazo)-o-toluidine (C.I. Solvent Yellow 3)

4-(o-Tolylazo)-o-toluidine hydrochloride

1-p-Tolyldodecane

2,2'-(m-Tolylimino)diethanol

N, N, N-Tribenzylamine

1, 2, 3( and 1, 2,4 )-Trichlorobenzene

1, 2,4-Trichlorobenzene

N, 2, 6-Trichloro-p-benzoquinoneimine

1, 2,4-Trichloro-5-nitrobenzene

Trichlorophenylsilane

<x,a,a-Trichlorotoluene (Benzotrichloride)

<x,2,4-Trichlorotoluene

a,2,4(anda,2, 6)-Trichlorotoluene

2,4, 6-Trichloro-s-triazine

1,3,5-Triethylbenzene

N, N, N'-Triethyl-N'-phenylethylenediamine

2-(Trifluoromethyl)phenothiazine

a,a,a_Trifluoro-4-nitro-m-cresol

a,a,a-Trifluoro-m-nitrotoluene

a,a,a-Trifluoro-N-phenyl-m-toluidine (3-(Trifluoromethyl) diphenylamine ) .

<x,a,«-Trifluorotoluene

a,a,a_Trifluoro-m-toluidine

1, 2,4-Trihydroxyanthraquinone

3,4, 5-Trimethoxybenzoic acid

2,4, 5-Trimethylaniline (Pseudocumidine)

1, 2,4-Trimethylbenzene (Pseudocumene)

2,3,3-Trimethyl-3H-indole

*l,3,3-Trimethyl-A2»a-indolineacetaldehyde

*l,3,3-Trimethyl-2-methyleneindoline (Trimethyl base)

Trimethylphenylammonium iodide

«,«', 2-Trimethyl-l,4-piperazinediethanol

2,4, 6-Trimethylpyridine

1,3, 5-Trinitrobenzene

2,4,7-Trinitrofluoren-9-one

2,4, 6-Trinltroresoreinol, lead derivative

Triphenylmethanol

Triphenylsulfonium chloride

a., a.', a." -Tris(dimethylamino)mesitol

Tris(2-methyl-l-aziridinyl)phosphine oxide

2,4,6-Tris(2-methyl-l-aziridinyl)-s-triazine

Tropine

m-Ureidoaniline

*7, 7'-Ureylenebis[4-hydroxy-2-naphthalenesulfonic acid] (J acid urea).

Veratraldehyde (3,4-Dimethoxybenzaldehyde)

Veratryl alcohol (3,4-Dimethoxybenzyl alcohol)

p-Vinylbenzenesulfonic acid, sodium salt

2-Vinylcyclohexene

4-Vinylcyclohexene

2,2 -Vinylenebis[benzimidazole]

5-Vinyl-2-picoline (MVP)

2-Vinylpyridine

4-Vinylpyridine

*Violanthrone (Dibenzanthrone)

Xanthene-9-carboxylic acid

m-}iylene

*o-Xylene

*p-Xylene

Xylenesulfonic acid

2, 5-Xylenesulf onic acid

2,4-Xylenol

Xylenol crystals

DUP,

NAC.

EK.

BUC.

DUP.

TRC,

VPC.

NAC.

ACY,

NAC.

G.

ACY,

ALL,

DUP, G, KLS, NAC, SDH.

G.

X.

EKT.

MLS.

PPG.

DOW,

HK,

SVT.

EK.

PCW.

DCC,

UCS.

HK,

VEL.

HN.

BPC.

ACY,

GGY,

NIL.

DUP.

DUP.

SK.

MEE.

SK.

HK.

MEE.

G.

ICO,

KF.

NAC.

ENJ.

G.

DUP,

G, VPC.

DUP,

G, NAC, VPC.

EK.

WYN.

KPT,

RIL.

EK.

EK.

REM.

EK.

GAM.

RH,

TKL.

ICO.

ICO.

CTN.

ICI.

ACY,

ATL,

BKS, BL, CMG, G, NAC, TRC, VPC.

GIV,

LIL,

SLV.

LIL.

DUP.

UCC.

PLC.

TRC.

PLC.

RIL.

RIL.

ACY,

ATL,

DUP, G, ICI, MAY, TRC.

PLC,

SNT,

SOC.

ASH,

CCP,

COR, CSD, CSO, DLH, ENJ, SIN, SNT, SOC

TOC.

CSD,

ENJ,

SIN, SNT, SOC.

NE3.

EK.

EK.

ACP,

KPT.

CYCLIC INTERMEDIATES

TABLE 7B. — Cyclic intermediates for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

#Jtylenols :

Low b.p

Medium b.p

Not classified as to b.p

)iylidines :

2,4-)fylidine (m-4-Xylidine)-

2, 5-Xylidine (p-Xylidine )

2, 6-Xylidine

Original mixture

4- (2, 4-J!ylylazo ) -o-toluidine— ■ 4- (2, 5-)fylylazo )-o-toluidine-—

4-(Xylylazo)xylidine

4- ( 2, 4-Jiylylazo ) -2, 5-xylidine- All other cyclic intermediates'

NPC,

PIT,

PRD.

KPT,

NPC,

PIT.

KPT,

NPC,

PRD.

DUP,

NAC.

DUP,

NAC.

DUP.

DUP,

NAC.

NAC.

ACY.

ARA, G, HPC, ICC, IDC, LIL, UPJ, VPC, x, x, x.

1 Does not include manufacturers ' identification codes for producers that report to the Division of Bituminous Coal, U.S. Bureau of Mines. These producers are listed in the U.S. Bureau of Mines Mineral Industry Survey Coke Producers in the United States in 1964, May 17, 1965.

90

SYNTHETIC ORGANIC CHEMICALS. 1965

Dyes

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965

[Dyes for which separate statistics are given in table 8A are marked below with an asterisk (*); dyes not so marked do not appear in table 8A because the reported data are accepted in confidence and may not be published. Manufac- turers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Dye

Manufacturers ■ identification codes (according to list in table 22)

ACID DYES

*Acid yellow dyes:

Acid Yellow 1

Acid Yellow 2

*Acid Yellow 3

Acid Yellow 4

Acid Yellow 7

Acid Yellow 9

*Acid Yellow 11

Acid Yellow 14

*Acid Yellow 17

*Acid Yellow 23

Acid Yellow 25 —

Acid Yellow 29

Acid Yellow 34

Acid Yellow 35

*Acid Yellow 36

Acid Yellow 38

*Acid Yellow 40

*Acid Yellow 42

Acid Yellow 43-

*Acid Yellow 44

*Acid Yellow 54

Acid Yellow 59

Acid Yellow 60

Acid Yellow 63

Acid Yellow 65

*Acid Yellow 73

Acid Yellow 76

Acid Yellow 79

Acid Yellow 90

Acid Yellow 95

*Acid Yellow 99

Acid Yellow 113

Acid Yellow 114—

Acid Yellow 121

Acid Yellow 124

Acid Yellow 127— ■

Acid Yellow 128 ■

Acid Yellow 129

Acid Yellow 151

Acid Yellow 152 - ■

Acid Yellow 159

Other acid yellow dyes

*Acid orange dyes:

*Acid Orange 1

Acid Orange 2

Acid Orange 5

Acid Orange 6

*Acid Orange 7

*Acid Orange 8

*Aeid Orange 10

Acid Orange 12

Acid Orange 19

*Acid Orange 24

Acid Orange 28

Acid Orange 31

Acid Orange 34

Acid Orange 45

Acid Orange 49

Acid Orange 50

Acid Orange 51

Acid Orange 52

Acid Orange 56

*Acid Orange 60-

ACY.

DUP.

ACY,

DUP,

NAC.

SDH.

NAC.

ACY.

CMG,

DUP,

VPC.

BDO,

TRC.

ACY,

ATL,

BDO, BKS, CMG, DUP, G,

NAC, PDC, SDH, TRC

VPC.

AAP,

ACY,

G, MRX, NAC, SDH, TRC,

VPC.

G.

G, TRC.

NAC.

VPC.

DUP,

G, NAC, TRC.

NAC.

ACY,

DUP,

G, NAC, TRC, VPC.

AAP,

ACY,

G, VPC.

NAC.

AAP,

G, NAC, VPC.

ACY,

BKS,

CMG, G, NAC, TRC, VPC.

VPC.

NAC.

AAP,

NAC.

TRC.

G, NAC, NYC, SDH.

TRC.

VPC.

NAC.

CMG.

CMG,

G, NAC, TRC, VPC.

TRC.

CMG,

TRC.

G.

BKS,

DUP,

NAC.

TRC.

TRC.

TRC.

ACY,

BKS.

ACY.

TRC.

ACY,

ALT,

CMG, DUP, G, VPC.

ALT,

BKS,

G, NAC.

NAC.

ACY.

NAC.

AAP,

ACY,

ATL, BKS, CPC, G, NAC,

PDC, TRC, YAW.

ACY,

ATL,

BKS, DUP, G, NAC, TRC.

ACY,

ATL,

DUP, G, NAC, TRC, YAW.

NAC.

G.

ACY,

DUP,

G, NAC, TRC, YAW.

NAC.

AAP.

ACY.

NAC,

TRC.

TRC.

AAP.

CMG,

NAC,

TRC.

NAC.

G.

BKS,

CMG,

DUP, G.

DYES

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

Manufacturers' identification codes (according to list in table 22)

ACID DYES- -Continued

*Acid orange dyes — Continued

Acid Orange 62

Acid Orange 63

*Acid Orange 64

Acid Orange 69

Acid Orange 72

Acid Orange 74

Acid Orange 76

Acid Orange 85

Acid Orange 86

Acid Orange 114

Acid Orange 116

Acid Orange 119

Other acid orange dyes

*Aeid red dyes:

*Aeid Red 1

*Acid Red 4

Acid Red 12

*Acid Red 14

Acid Red 17

*Acid Red 18

*Aeid Red 26

Acid Red 27

Acid Red 29

Acid Red 32

Acid Red 33

Acid Red 34

Acid Red 35

*Acid Red 37

Acid Red 42

Acid Red 52

Acid Red 57

Acid Red 60

Acid Red 66

*Acid Red 73

Acid Red 76

Acid Red 80

*Acid Red 85

*Acid Red 87

*Acid Red 88

*Acid Red 89

Acid Red 94

Acid Red 97

*Acid Red 99

Acid Red 100

Acid Red 106 —

Acid Red 113

*Acid Red 114

*Acid Red 115

Acid Red 119

Acid Red 133— —

Acid Red 134

*Acid Red 137

*Acid Red 151

Acid Red 153

Acid Red 167

Acid Red 172

Acid Red 175

Acid Red 178

Acid Red 179

*Acid Red 182

Acid Red 183

Acid Red 184

*Acid Red 186

Acid Red 190

Acid Red 191

Acid Red 194

Acid Red 207

TRC.

G, TRC.

ACY, DUP, NAC.

ACY.

a.

CMG, G, NAC, TRC.

NAC, TRC.

NAC.

NAC, TRC.

ACY.

ATL, TRC.

TRC.

ALT, G, VPC.

AAP, ACY, BDO, BKS, BL, DUP, G, NAC, SDH, TRC, VPC,

YAW. ATL, BDO, CMG, DUP, G, TRC, VPC, YAW. G, NAC.

ATL, BDO, DUP, G, NAC, PDC. ATL, NAC, TRC. ACY, ATL, BDO, G, NAC, TRC. ACY, ATL, CPC, G, NAC. NAC. NAC. G, NAC. NAC, YAW. NAC. AAP, G.

CMG, DUP, G, NAC, TRC. G. G.

TRC. TRC.

AAP, NAC.

ACY, DUP, G, NAC, PSC, TRC. NAC. G, ICI. ACY, ALT, ATL, BKS, CMG, DUP, G, NAC, PDC, TRC, VPC,

YAW. AMS, NYC, SDH.

ACY, ATL, DUP, G, NAC, SDH, TRC, YAW. AAP, G, TRC, VPC. NYC. ATL, G.

BKS, CMG, NAC, TRC, VPC. VPC. YAW. DUP.

ATL, DUP, G. G, NAC, TRC. NAC. G.

TRC.

ATL, DUP, G, NAC, TRC. AAP, ACY, BKS, TRC, YAW. YAW.

NAC, TRC. VPC. DUP. DUP.

CMG, TRC.

ACY, BKS, CMG, DUP, G, NAC. CMG, TRC. TRC.

ACY, BKS, CMG, DUP, G, TRC, VPC. ACY. TRC. TRC. NAC.

92

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Dye

Manufacturers' identification codes (according to list in table 22)

ACID DYES— Continued

*Acid red dyes — Continued

Acid Red 212

Acid Red 213

Acid Red 218—

Acid Red 273

Acid Red 292

Acid Red 299 —

Acid Red 309

Other acid red dyes

*Acid violet dyes:

*Aeid Violet 1

*Acid Violet 3

Acid Violet 6

*Acid Violet 7

Acid Violet 11

*Acid Violet 12

Acid Violet 13 —

Acid Violet 17 -

Acid Violet 29

Acid Violet 34

Acid Violet 41

Acid Violet 43

*Acid Violet 49

Acid Violet 56

Acid Violet 76

Acid Violet 78

Other acid violet dyes

*Acid blue dyes:

Acid Blue 1

*Acid Blue 7

*Aeid Blue 9

Acid Blue 10

Acid Blue 13

Acid Blue 15

Acid Blue 20

Acid Blue 22

Acid Blue 23

*Acid Blue 25

Acid Blue 26

Acid Blue 27

Acid Blue 29

Acid Blue 34

Acid Blue 35

*Acid Blue 40

*Acid Blue 41

*Acid Blue 43

*Acid Blue 45

Acid Blue 47

Acid Blue 48

Acid Blue 58

Acid Blue 59

*Acid Blue 62

Acid Blue 63

Acid Blue 67

Acid Blue 69

Acid Blue 74

*Acid Blue 78

Acid Blud 80

Acid Blue 81

Acid Blue 83

Acid Blue 89— - —

*Acid Blue 90

Acid Blue 92

Acid Blue 93

Acid Blue 102

Acid Blue 104

*Acid Blue 113

*Acid Blue 118

Acid Blue 120 -

TRC.

ALT, ATL, G, TRC, VPC.

G, NAC.

DUP, NAC, TRC, YAW.

BD0, CMG, DUP, G, NAC, TRC, VPC.

DUP, G.

G, SDH.

ICI, NAC. NAC, TRC. G.

DUP, TRC.

NAC, SDH.

G, NAC, SDH. NAC, SDH, VPC.

NAC.

NAC. NYC. TRC. BD0, CMG, DUP, G, NAC, TRC.

G, ICI, NAC. CMG, G, NAC. G, NAC, TRC. CMG, DUP, G, NAC, TRC, VPC.

G, VPC.

NAC.

NAC.

G.

NAC.

G, ICI, NAC, TRC.

TRC.

NAC.

G, NAC, TRC.

NAC,

HSC NAC

TRC. NAC.

BKS, CMG, DUP, G.

G, NAC. NAC.

DYES

93

TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Dye

ACID DYES— Continued

*Acid blue dyes — Continued

Acid Blue 122— -.

Acid Blue 137- -

Acid Blue 145

*Acid Blue 158 and 158A

Acid Blue 165

Acid Blue 179

Acid Blue 203

Acid Blue 230 -

Acid Blue 231

Other acid blue dyes

*Acid green dyes:

Acid Green 1

*Acid Green 3

Acid Green 5

*Aeid Green 9

*Aci'l Green 12

*Acid Green 16

*Acid Green 20

Acid Green 22

*Acid Green 25

Acid Green 35

Acid Green 4-1

Acid Green 44

Acid Green 50

Acid Green 58

Other acid green dyes

*Acid brown dyes:

Acid Brown 1

Acid Brown 6

*Acid Brown 14

Acid Blown 19

Acid Brown 22

Acid Brown 28

Acid Brown 29

Acid Brown 31

Acid Brown 45

Acid Brown 96

Acid Brown 97

Acid Brown 98

Acid Brown 152

Acid Brown 158

Acid Brown 223

Acid Brown 243

Other acid brown dyes

*Acid black dyes:

*Acid Black 1

Acid Black 2

Acid Black 12

Acid Black 16

Acid Black 18

*Acid Black 24

Acid Black 26, 26A, and 26B

Acid Black 29

Acid Black 41

*Acid Black 48

Acid Black 52

Acid Black 53

Acid Black 58

Acid Black 60

Acid Black 92

*Acid Black 107

Acid Black 138 — *•

Other acid black dyes

Manufacturers' identification codes (according to list in table 22)

DUP.

NAC.

DUP.

ACY, BKS,

G, NAC,

TRC, VPC.

DUP.

G.

VPC.

DUP, THC.

TRC.

ACY, ALT,

CMG, DUP, TRC, VPC.

ACY, NAC.

ACY, DUP,

G, NAC,

TRC.

G, NAC.

ACY, DUP,

G, NAC,

VPC.

G, NAC, TRC.

DUP, G, NAC, SDH,

TRC.

ATL, CMG,

DUP, G,

NAC, TRC.

G, NAC.

ATL, CMG,

G, HSH,

ICI, NAC, TRC, VPC

THC.

ICI, VPC.

VPC.

ACY, G.

TRC.

ALT, TRC,

VPC.

G.

G.

AAP, ACY,

DUP, G,

NAC, TRC, YAW.

TRC.

DUP.

TRC.

DUP, NAC.

G.

NAC, TRC.

ACY.

ACY.

ACY, TRC.

G.

G.

G.

G.

ALT, DUP,

G, VPC.

AAP, ACY, ATL, BDO, BKS, DUP, FAB, G, NAC, PDC, TRC YAW. '

ACY, NAC. NAC. NAC. NAC.

CMG, DUP, G, NAC. DUP, NAC, TRC. G, NAC. NAC.

ACY, CMG, DUP, G, ICI, NAC, TRC. G, NAC, TRC. NAC.

NAC, TRC. CMG, TRC. ACY.

G, NAC, TRC. VPC. ALT, DUP, PDC.

94

SYNTHETIC ORGANIC CHEMICALS, 1965

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

AZOIC DYES AND COMPONENTS

Azoic yellow dyes: *Azoic Yellow 1

Azoic Yellow 2

*Azoic Yellow 3

Other azoic yellow dyes

Azoic orange dyes:

*Azoic Orange 3

Azoic Orange 4

Other azoic orange dyes

* Azoic red dyes:

*Azoic Red 1

*Azoie Eed 2

*Azoic Bed 6

Azoic Red 13

Azoic Red 14

Azoic Red 15

•*Azoic Red 16

Azoic Red 73

Azoic Red 74

Other azoic red dyes

Azoic violet dyes:

Azoic Violet 1

Other azoic violet dyes

Azoic blue dyes:

*Azoic Blue 2

*Azoic Blue 3

Azoic Blue 4

Azoic Blue 6

Azoic Blue 7

Other azoic blue dyes

Azoic green dyes:

Azoic Green 1

Other azoic green dyes

Azoic brown dyes:

*Azoic Brown 9

Azoic Brown 10

Azoic Brown 26

Other azoic brown dyes

* Azoic black dyes:

Azoic Black 1

Azoic Black 2

Azoic Black 3

Azoic Black 4

Azoic Black 15

Other azoic black dyes

Other azoic compositions

Azoic Diazo Compo (Fast Color

Azoic

Azoic

Azoic

♦Azoic

Azoic

Azoic

*Azoic

*Azoic

*Azoic

*Azoic

Azoic

Azoic

Azoic

Azoic

*Azoic

Azoic

Azoic

Azoic

Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo

Component Component Component Component Component Component Component Component Component Component Component Component Component Component Component Component Component Component

1, base —

2, base —

3, base —

4, base —

5, base —

8, base —

9, base —

10, base-

12, base-

13, base-

14, base- 20, base- 24, base- 28, base- 32, base- 34, base- 41, base- 46, base-

ALL, ATL, BUC, G.

BUC, G, HST, X.

ATL, G, HST. BUC.

ALL, ATL, BUC, G, x.

VPC.

ALL,

ATL, ALL, G.

ATL, BUC, G, HST, x.

BUC, G, x.

ATL, BUC, G, HST, NAC, VPC, x.

ATL, BUC, G.

ATL, BUC, G. ATL, G, x.

ATL, BUC, G.

ALL, ATL, BUC, G, HST, x.

ATL, G. G.

ATL, G.

VPC.

ATL, BUC,

Qt

HST, VPC

ATL, BUC.

BUC, G.

ATL, BUC,

G>

VPC.

G, HST.

ATL.

ATL.

ALL, ATL,

G.

G, NAC.

ALL, ATL,

Gj

VPC.

SDH. ATL. KLS.

ALL, G, KLS, SDH. G, SDH. DUP.

AAP, DUP, VPC. ALL, AUG, BUC, G, KLS. AUG, KLS, SDH. ALL, AUG, BUC, KLS. AAP. ALL, G. KLS.

ALL, BUC, KLS.

AAP, ATL, BUC, DUP, KLS, SDH. G. G. I ATL.

DYES

95

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Dye

AZOIC DYES AND COMPONENTS- -Continued

Azoic Diazo Components, Bases (Fast Color Bases)— Continued

*Azoic Diazo Component 48, base- Azoic Diazo Component 49, base-

Diazo Components (Fast Color Salt

*Azoic

* Azoic

*Azoic

Azoic

*Azoic

*Azoic

*Azoic

*Azoic

*Azoic

*Azoic

*Azoie

*Azoic

Azoic

Azoic

Azoic

*Azoic

Azoic

Azoic

Azoic

Azoic

Azoic

Azoic

Azoic

Azoic

*Azoic

*Azoic

Azoic

Other

Azoic

*Azoic

*Azoic

*Azoic

*Azoie

*Azoic

* Azoic

Azoic

*Azoic

Azoic

Azoic

*Azoic

Azoic

Azoic

*Azoic

*Azoic

*Azoic

*Azolc

*Azoic

Azoic

Azoic

*Azoic

Azoic

Azoic

Azoic

Azoic

Other

Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo Diazo azoic

Component 1, salt

Component 2, salt

Component 3, salt

Component 4, salt

Component 5, salt

Component 6, salt

Component 8, salt

Component 9, salt

Component 10, salt

Component 11, salt

Component 12, salt

Component 13, salt

Component 14, salt

Component 20, salt

Component 24, salt

Component 28, salt

Component 32, salt

Component 34, salt

Component 35, salt

Component 36, salt

Component 37, salt

Component 41, salt

Component 42, salt

Component 44, salt

Component 48, salt

Component 49, salt

Component 51, salt

diazo components, salts-

Azoic Coupling Components (Naphthol AS and Derivatives)

Coupling Component 1

Coupling Component 2

Coupling Component 3

Coupling Component 4

Coupling Component 5

Coupling Component 7

Coupling Component 8

Coupling Component 10

Coupling Component 11

Coupling Component 12

Coupling Component 13

Coupling Component 14

Coupling Component 15

Coupling Component 16

Coupling Component 17

Coupling Component 18

Coupling Component 19

Coupling Component 20

Coupling Component 21

Coupling Component 23

Coupling Component 24

Coupling Component 29

Coupling Component 34

Coupling Component 35

Coupling Component 36

Coupling Component 43

azoic coupling components

Manufacturers' identification codes (according to list in table 22)

ALL, OWN, DUP, G. KLS.

AAP, ALL, G, SDH.

AUG, BUC, G, KLS.

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC.

ALL.

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC.

AAP, BUC, G, KLS, SDH.

AAP, ALL, AUG, BUC, G, KLS.

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC.

AAP, ALL, BUC, G, KLS, SDH.

AAP, ALL, G, KLS.

AAP, ALL, BUC, G, KLS, SDH.

AAP, ALL, AUG, BUC, G, KLS, SDH, VPC.

AAP.

ALL, G.

BUC.

ALL, AUG, BUC, G, KLS, SDH, VPC.

ALL, BUC, SDH.

G.

G.

AAP, G.

G.

G.

ALL, G, KLS.

G, SDH.

AAP, ALL, G, NAC, SDH.

AAP, BUC, G, KLS.

BUC.

AUG.

AAP, ACY, ATL, BUC, DUP, G, PCW.

AUG, BUC, G, PCW.

ATL, AUG, BUC, G, PCW.

AAP, G, PCW, SDH.

AAP, AUG, BUC, G, PCW.

ATL, G, PCW.

PCW, SDH.

BUC, G, PCW.

BUC, G, PCW.

G.

ATL, BUC, G, NAC, PCW.

ACY, ATL, BUC, PCW.

ACY, ATL, BUC, DUP, G, PCW.

BUC, G, PCW.

ATL, BUC, DUP, G, PCW.

ATL, AUG, BUC, G, PCW.

G, PCW.

G, PCW.

ATL, AUG, BUC, G, PCW.

BUC, G, PCW.

ALL, G, PCW.

G.

ATL, G.

ATL, G, VPC.

96

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Dye

Manufacturers1 identification codes (according to list in table 22)

BASIC DYES

*Basic yellow dyes:

Basic Yellow 1

*Basic Yellow 2

Basic Yellow 5

*Basic Yellow 11

*Basic Yellow 13

Basic Yellow 15

Basic Yellow 16

Basic Yellow 26

Basic Yellow 27

Basic Yellow 28

Basic Yellow 37

Other Basic yellow dyes

*Basic orange dyes:

*Basic Orange 1

*Basic Orange 2

Basic Orange 10

Basic Orange 14

Basic Orange 17

*Basic Orange 21

Basic Orange 22

Basic Orange 24

Basic Orange 25

Basic Orange 26

Basic Orange 31

Other basic orange dyes

*Basic red dyes:

Basic Red 1

Basic Red 2

Basic Red 9

Basic Red 12

Basic Red 13

*Basie Red 14

Basic Red 15

Basic Red 16

Basic Red 17

Basic Red 18

Basic Red 19

Basic Red 20

Basic Red 22

Basic Red 30

Other basic red dyes

*Basic violet dyes:

*Basic Violet 1

Basic Violet 2

*Basic Violet 3

*Basie Violet 4

Basic Violet 7

Basic Violet 10

Basic Violet 13

Basic Violet 14

Basic Violet 15

*Basic Violet 16

Basic Violet 18

Other basic violet dyes

*Basic blue dyes:

*Basic Blue 1

Basic Blue 2

Basic Blue 3

Basic Blue 4

*Basic Blue 5

Basic Blue 6

*Basie Blue 7

*Basic Blue 9

Basic Blue 11

Basic Blue 21

Basic Blue 22

*Basic Blue 26

Basic Blue 27

DUP.

ACY, DUP, NAC.

NAC.

DUP, G, NAC, VPC.

DUP, G, NAC, VPC.

DUP.

DUP.

ACY.

ACY.

VPC.

ACY.

G, DUP.

ACY, DUP, G, NAC.

ACY, DSC, DUP, G, NAC, PDC, PSC, TRC.

VPC.

G.

NAC.

DUP, G, NAC, VPC.

G, NAC.

DUP.

DUP.

DUP.

ACY.

VPC.

DUP,

G.

DUP,

NAC.

DSC,

HSC.

DUP.

G, NAC.

ACY,

DUP,

G,

NAC, VPC.

DUP,

G.

DUP.

DUP.

DUP,

VPC.

DUP.

DUP.

ACY,

TRC.

ACY.

DUP.

ACY,

DSC,

HSC, NAC.

DSC,

NYC.

DSC,

DUP,

G,

NAC, SDH.

DSC,

DUP,

G,

NAC.

G, NAC.

ACY,

DUP,

G.

DSC.

ACY,

DSC.

DUP.

DUP,

G, VPC.

ACY.

DUP.

DSC,

G, NAC,

SDH, VPC.

DSC.

G.

DUP.

DSC,

SDH,

VPC.

ACY,

NAC.

DSC,

DUP,

Gi

SDH.

ACY,

G, NAC,

SDH.

DSC,

DUP,

SDH.

DUP.

DUP,

NAC.

DSC,

DUP,

G,

SDH.

G.

DYES

97

TABLE 8B —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

BASIC DYES- -Continued

♦Basic blue dyes—Continued

Basic Blue 35

Basic Blue 36

Basic Blue 38

Basic Blue 39

Basic Blue 4-1

Basic Blue 54

Other basic blue dyes

Basic green dyes:

♦Basic Green 1

Basic Green 3

♦Basic Green 4

Basic Green 5

Basic brown dyes:

♦Basic Brown 1 — •

Basic Brown 2

*Basic Brown 4

Basic black dyes:

Basic Black 3

Other basic black dyes

DIRECT DYES

♦Direct yellow dyes:

*Direct Yellow 4

*Direct Yellow 5

*Direct Yellow 6

Direct Yellow 7

Direct Yellow 8

Direct Yellow 9

*Direct Yellow 11

*Direet Yellow 12

Direct Yellow 20

Direct Yellow 23

♦Direct Yellow 26

Direct Yellow 27

*Direct Yellow 28

Direct Yellow 29

Direct Yellow 39

*Direct Yellow 44

*Direct Yellow 50

♦Direct Yellow 59

Direct Yellow 62

Direct Yellow 63

♦Direct Yellow 84

Direct Yellow 103

♦Direct Yellow 105

♦Direct Yellow 106

Direct Yellow 107

Direct Yellow 114

Direct Yellow 117

Direct Yellow 118

Direct Yellow 121

Direct Yellow 125

Other direct yellow dyes

♦Direct orange dyes:

♦Direct Orange 1

Direct Orange 6

♦Direct Orange 8

Direct Orange 10

Direct Orange 11

♦Direct Orange 15

♦Direct Orange 26

Direct Orange 29

♦Direct Orange 34

♦Direct Orange 37

Direct Orange 38

♦Direct Orange 39

Direct Orange 40

Manufacturers' identification codes (according to list in table 22)

DUP.

DUP.

ACY, DUP.

DUP.

TRC.

ACY.

ACY, DUP,

G.

ACY, DSC,

DUP, NAC, SDH.

DUP.

ACY, DSC,

DUP, NAC, SDH.

ACY.

ACY, DUP,

G, NAC, TRC.

G, NAC.

ACY, DSC,

DUP, G, NAC, TRC

DSC, DUP.

ACY, DUP, G, NAC, TRC.

ACY, G, NAC.

ACY, DUP, G, NAC, TRC.

ATL.

G, NAC.

DUP.

ACY, DUP, G, NAC, TRC.

BKS, DUP, G, NAC, TRC.

TRC.

DUP.

BKS, BL, DUP.

G.

ATL, DUP, G, NAC, TRC.

DUP, G.

TRC.

ALT, ATL, BKS, BL, DUP, G, NAC, TRC, VPC.

ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC.

ATL, DUP, NAC.

NAC.

DUP.

BKS, G, NAC, TRC.

NAC.

ALT, BKS, TRC.

ALT, BKS, G, TRC.

G.

ACY.

TRC.

ACY, TRC.

TRC.

ACY.

AAP, ALT, ATL, BL, DUP, FAB, VPC.

AAP, BDO, CMG, NAC, VPC.

NAC.

ATL, DUP, G, NAC, TRC.

AAP, NAC.

G.

ACY, DUP, G, NAC, TRC.

ATL, BL, DUP, G, NAC, TRC.

ATL, BKS, TRC.

ACY, CMG, DUP, G, NAC.

ACY, CMG, DUP, G, TRC.

NAC.

ATL, BKS, CMG, DUP, G.

DUP.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. ■

-Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

DIRECT DYES--Continued

*Direct orange dyes — Continued

Direct Orange 48

Direct Orange 55

Direct Orange 59

Direct Orange 61

Direct Orange 67

Direct Orange 70

^Direct Orange 72

*Direct Orange 73

Direct Orange 74

Direct Orange 76

Direct Orange 78

Direct Orange 79

Direct Orange 80

*Direct Orange 81

Direct Orange 83

Direct Orange 88

*Direct Orange 102

Direct Orange 110

Other direct orange dyes

*Direct red dyes:

*Direct Red 1

-"-Direct Red 2

*Direct Red 4

Direct Red 5

*Direct Red 10

*Direct Red 13

*Direet Red 16

Direct Red 20

*Direct Red 23

^Direct Red 24

*Direct Red 26

*Direct Red 28

Direct Red 30

*Direct Red 31

Direct Red 32

*Direct Red 37

*Direct Red 39

Direct Red 46

Direct Red 53

Direct Red 62

Direct Red 72

Direct Red 73 —

*Direet Red 75

Direct Red 76

*Direct Red 79

*Direct Red 80

*Direct Red 81

*Direet Red 83

Direct Red 84

Direct Red 94

Direct Red 95

Direct Red 100

Direct Red 111

Direct Red 117

Direct Red 120

^Direct Red 122

Direct Red 123 —

*Direct Red 127 and 127A

Direct Red 139

Direct Red 148

*Direct Red 149

Direct Red 152

*Direct Red 153

Direct Red 155

Direct Red 209

Other direct red dyes

Manufacturers' identification codes (according to list in table 22)

DUP.

DUP, NAC.

DUP, G.

TRC.

NAC, VPC.

TRC.

ATL, BKS, BL, FAB, NAC, TRC, VPC.

DUP, G, TRC, VPC.

DUP.

DUP.

DUP, VPC.

DUP.

DUP, VPC.

DUP, G, NAC, VPC.

G, NAC.

DUP.

ACT, DUP, G, NAC.

TRC.

ALT, ATL, BL, DUP, G, VPC.

AAP, ATL, DUP, G, NAC, TRC, IAW.

ATL, BKS, DUP, NAC, TRC.

NAC, TRC, VPC.

NAC.

AAP, ACY, ATL, NAC.

AAP, ATL, DUP, G, NAC, TRC, YAW.

AAP, ATL, DUP, G, NAC, TRC.

G, NAC.

ATL, BKS, DUP, FAB, G, NAC, TRC.

AAP, ATL, BKS, BL, FAB, NAC, TRC, VPC.

AAP, ATL, BKS, DUP, G, NAC, TRC, VPC.

ATL, DUP, NAC, TRC.

VPC.

ATL, DUP, G, NAC, TRC.

DUP, NAC.

ACY, ATL, G, NAC, TRC, YAW.

ATL, G, NAC, TRC, YAW.

ATL, TRC.

NAC.

TRC.

G, TRC.

DUP, NAC.

ACY, CMG, DUP, G, NAC, VPC.

G, NAC.

ATL, BKS, CMG, TRC, VPC.

AAP, ATL, BDO, BKS, BL, CMG, DUP, FAB, G, NAC, TRC,

VPC. AAP, ACY, ATL, BDO, BKS, BL, CMG, DUP, G, NAC, TRC,

VPC, YAW. ALT, ATL, BKS, BL, CMG, DUP, FAB, G, NAC, TRC. G, NAC. NAC. VPC. NAC. G, VPC. BL, DUP. VPC. CMG, NAC, TRC, VPC.

DUP,

NAC,

TRC.

VPC.

DUP.

ATL,

CMG,

DUP, G,

NAC

CMG,

DUP,

NAC.

ATL,

CMG,

NAC.

G.

TRC.

ALT,

BL.

DYES

99

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Dye

DIRECT DYES- -Continued

*Direct violet dyes:

♦Direct Violet 1

Direct Violet 7

♦Direct Violet 9

Direct Violet 14

Direct Violet 22

Direct Violet 30

Direct Violet 47

Direct Violet 48

Direct Violet 49

♦Direct Violet 51

Direct Violet 60

Direct Violet 62

Direct Violet 66

Direct Violet 67

Direct Violet 68 —

Other direct violet dyes

*Direct blue dyes:

*Direct Blue 1

*Direct Blue 2

Direct Blue 3

♦Direct Blue 6

♦Direct Blue 8

Direct Blue 10

*Direct Blue 14-

♦Direct Blue 15

Direct Blue 21 -

♦Direct Blue 22

♦Direct Blue 24

♦Direct Blue 25

Direct Blue 26

Direct Blue 27

Direct Blue 55

Direct Blue 67

♦Direct Blue 71

Direct Blue 74

Direct Blue 75

♦Direct Blue 76

♦Direct Blue 78

Direct Blue 79

♦Direct Blue 80

Direct Blue 84

♦Direct Blue 86

Direct Blue 87

Direct Blue 91

♦Direct Blue 98—

Direct Blue 100

Direct Blue 104

♦Direct Blue 120 and 120A

♦Direct Blue 126

Direct Blue 130

Direct Blue 133

Direct Blue 136

Direct Blue 1A3

♦Direct Blue 151

Direct Blue 160

Direct Blue 189

Direct Blue 191

Direct Blue 199

Direct Blue 218

Direct Blue 238

Other direct blue dyes

♦Direct green dyes:

♦Direct Green 1

♦Direct Green 6

♦Direct Green 8

♦Direct Green 12 — ■

Manufacturers' identification codes (according to list in table 22)

AAP, ATL, DUP, NAC.

G, NAC.

ATL, BKS, DUP, G, NAC, TRC.

ATL, NAC.

DUP.

AAP.

DUP, G.

DUP, NAC.

NAC.

ATL, DUP, NAC.

NAC.

ACY.

ATL, TRC.

DUP, NAC.

DUP.

ALT.

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC,

YAW. AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, VPC, YAW. NAC.

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW. ATL, BKS, DUP, G, NAC, TRC, YAW. DUP.

ATL, DUP, NAC, TRC. ATL, DUP, G, NAC, YAW. TRC.

ATL, CMG, DUP, NAC. ATL, BKS, NAC, TRC, YAW. DUP, G, NAC, TRC, YAW. ATL, NAC. DUP. NAC.

ATL, DUP, NAC, TRC. ATL, DUP, G, NAC, TRC. DUP.

TRC.

ALT, ATL, BKS, BL, DUP, G, NAC, TRC, VPC.

ATL, CMG, DUP, G, NAC, TRC.

TRC.

ALT, ATL, BKS, BL, DUP, FAB, G, NAC, TRC.

DUP.

AAP, ACY, ATL, BKS, DUP, FAB, G, ICC, ICI, NAC, SDH, TMS, TRC, VPC.

ICI.

TRC.

ALT, ATL, G, TRC, VPC.

ALT, NAC.

DUP.

ATL, BKS, CMG, DUP, G, NAC, TRC.

BL, DUP, G, NAC, TRC, VPC.

NAC.

G.

G.

DUP.

ATL, NAC, TRC.

TRC.

TRC.

G.

G.

BKS.

ACY.

AAP, ACY, ALT, ATL, BL, DUP, FAB, G, NAC, VPC, YAW.

AAP, ACY, ATL, BKS, DUP, G, NAC, TRC, YAW.

AAP, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW.

ATL, NAC, TRC.

DUP, NAC, TRC.

100

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1 965— Continued

Dye

DIRECT DYES— Continued

*Direet green dyes — Continued

Direct Green 14

Direct Green 15

Direct Green 26

Direct Green 27

Direct Green 28

^Direct Green 38

Direct Green 39

Direct Green 41

Direct Green 45

Direct Green 47

Direct Green 51

Direct Green 69

Other direct green dyes

*Direct brown dyes:

^Direct Brown 1

*Direet Brown 1A

*Direct Brown 2

*Direct Brown 6

Direct Brown 11

Direct Brown 25

Direct Brown 27

Direct Brown 29

*Direct Brown 31

Direct Brown 32

Direct Brown 33

Direct Brown 35

Direct Brown 40

Direct Brown 44-

Direct Brown 48

Direct Brown 59

*Direct Brown 74

*Direet Brown 95

Direct Brown 101

Direct Brown 105

Direct Brown 106

*Direct Brown 111

Direct Brown 112

Direct Brown 125

*Direct Brown 154

Other direct brown dyes

*Direct black dyes:

Direct Black 3

*Direct Black 4

Direct Black 8

^Direct Black 9

Direct Black 17

*Direct Black 19

*Direct Black 22

Direct Black 29

Direct Black 36

Direct Black 37

*Direct Black 38

Direct Black 44

*Direct Black 51

Direct Black 55

Direct Black 56

Direct Black 67

Direct Black 71

Direct Black 74

Direct Black 75

Direct Black 78

*Direct Black 80

Direct Black 109

Direct Black 123

Direct Black 130

Direct Black 190

Other direct black dyes

Manufacturers' identification codes (according to list in table 22)

MAC.

DUP.

TRC.

NAC, TRC.

TRC.

DUP, G, NAC.

G.

DUP.

VPC.

DUP, G.

TRC.

TRC.

ACY, ALT, ATL, BL, DUP.

ACY, ATL, BKS, BL, DUP, FAB, NAC.

G, TRC, YAW.

AAP, ACY, ATL, BKS, BL, DUP, G, NAC, TRC, YAW.

DUP, G, NAC, TRC.

NAC.

DUP, NAC.

G.

NAC.

AAP, ATL, DUP, G, NAC, YAW.

G.

DUP, NAC.

NAC. AAP, DUP.

G, YAW.

AAP.

ACY.

AAP, DUP, NAC.

AAP, ALT, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW.

G.

DUP.

G, NAC.

DUP, G, TRC, VPC.

ATL, NAC.

G.

DUP, G, NAC, TRC, YAW.

ALT, ATL, BL, NAC, TRC, VPC, YAW.

DUP.

ATL, BKS, DUP, G, NAC, TRC, YAW.

TRC, YAW.

BKS, DUP, G, NAC, TRC.

G.

ATL, BKS, G, NAC, TRC, VPC.

AAP, ALT, ATL, BKS, CMG, DUP, G, NAC, TRC, VPC, YAW.

ATL.

AAP.

AAP, DUP.

AAP, ACY, ATL, BKS, BL, DUP, FAB, G, NAC, TRC, YAW.

TRC.

AAP, ATL, DUP, G, NAC, TRC.

DUP.

NAC, TRC.

DUP, NAC, VPC.

ATL, BKS, VPC.

NAC.

G.

BKS, NAC.

AAP, ATL, BKS, BL, FAB, G, NAC, TRC, VPC, YAW.

G.

NAC.

ACY.

BKS.

ACY, ALT, ATL, BL, TRC, YAW.

DYES

101

TABLE 8B.— Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Dye

Manufacturers' identification codes (according to list in table 22)

DISPERSE DYES

•Disperse yellow dyes:

Disperse Yellow 1

Disperse Yellow 2

•Disperse Yellow 3

•Disperse Yellow 5

Disperse Yellow 8

Disperse Yellow 17

•Disperse Yellow 23

Disperse Yellow 31

Disperse Yellow 32

•Disperse Yellow 33

•Disperse Yellow 34

Disperse Yellow 37

•Disperse Yellow 42

Disperse Yellow 50

•Disperse Yellow 54

Disperse Yellow 67

Other disperse yellow dyes

•Disperse orange dyes:

•Disperse Orange 3

•Disperse Orange 5

Disperse Orange 16

•Disperse Orange 17

Disperse Orange 21

Disperse Orange 25

Disperse Orange 26

Disperse Orange 29

Disperse Orange 30

Disperse Orange 38

Disperse Orange 44

Other disperse orange dyes

•Disperse red dyes:

•Disperse Red 1

Disperse Red 4

•Disperse Red 5

Disperse Red 9

•Disperse Red 11

•Disperse Red 13

Disperse Red 15

•Disperse Red 17

Disperse Red 20

Disperse Red 21

Disperse Red 30

Disperse Red 31

Disperse Red 32

Disperse Red 55

Disperse Red 56

Disperse Red 59—

•Disperse Red 60

Disperse Red 61

Disperse Red 65

Disperse Red 66

Disperse Red 73

Disperse Red 78

Disperse Red 96

Other disperse red dyes

Disperse violet dyes: ■ *Disperse Violet 1

•Disperse Violet 4

Disperse Violet 8

Disperse Violet 11

Disperse Violet 14

Disperse Violet 18

Disperse Violet 22

Disperse Violet 26

•Disperse Violet 27

Other disperse violet dyes

•Disperse blue dyes:

•Disperse Blue 1

•Disperse Blue 3

BKS, BL, DUP, EKT, G, HSH, ICC, NAC, SDH, TRC.

EKT, G, ICC.

TRC.

EKT, ICC, NAC, TRC.

EKT, ICC, G. ICC.

DUP. TRC.

DUP, G, ICC, TRC. EKT, G, ICC.

BKS, BL, DUP, EKT, G, HSH, ICC, NAC, TRC. EKT, G.

BKS, EKT, G, HSH, ICC, NAC.

TRC.

EKT, G, ICC.

BKS, BL, DUP, EKT, G, HSH, ICC, NAC, TRC, YAW. TRC.

BKS, EKT, G, HSH, ICC.

DUP, G, TRC. G, ICC. HSH, ICC, NAC.

BKS, DUP, EKT, G, HSH, ICC, TRC.

DUP, VPC. TRC.

DUP, EKT, G, ICC, VPC.

BKS, G, HSH, ICC, TRC. G, ICC.

ACY, BL, DUP. G, ICC.

G, TRC.

BKS, EKT, G, HSH, ICC, TRC.

102

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. Benzenoid dyes for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Dye

Manufacturers' identification codes (according to list in table 22)

DISPERSE DYES — Continued

^Disperse blue dyes — Continued

■^Disperse Blue 7

Disperse Blue 9

Disperse Blue 27

Disperse Blue 35

Disperse Blue 51

Disperse Blue 55

Disperse Blue 59

Disperse Blue 60

Disperse Blue 61

Disperse Blue 62

Disperse Blue 63

^Disperse Blue 64-

Disperse Blue 70

Disperse Blue 71

Disperse Blue 73

Disperse Blue 79

Other disperse blue dyes

Disperse brown dyes:

Disperse Brown 2

Other disperse brown dyes

^Disperse black dyes:

^Disperse Black 1

Disperse Black 2

Disperse Black 6

Disperse Black 7

^Disperse Black 9

Other disperse black dyes

FIBER-REACTIVE DYES

*Reactive yellow dyes:

Reactive Yellow 1

Reactive Yellow 2

Reactive Yellow 3

Reactive Yellow 4

Reactive Yellow 6

Reactive Yellow 7

Reactive Yellow 11

Reactive Yellow 13 <-

Reactive Yellow 14

Reactive Yellow 15

Reactive Yellow 16

Reactive Yellow 17

Reactive Yellow 18 — Reactive Yellow 22- Reactive Yellow 24-

Other reactive yellow dyes

Reactive orange dyeer Reactive Orange 1-

Reactive Orange 2

Reactive Orange 4

Reactive Orange 5- Reactive Orange 7- Reactive Orange 12-

Reactive Orange 13

Reactive Orange 14

Reactive Orange 16

*Reactive red dyes:

Reactive Red 1

Reactive Red 2

Reactive Red 3

Reactive Red 4-

Reactive Red 5

Reactive Red 6

Reactive Red 8

Reactive Red 11

Reactive Red 13

Reactive Red 16

AAP,

EKT, G, ICC, TRC.

G, ICC.

EKT.

ICI.

G.

TRC.

DUP.

DUP.

DUP.

DUP.

DUP.

DUP,

G, TRC.

AAP.

VPC.

TRC.

TRC.

AAP,

BKS, DUP, EKT, G, HSH, ICC, STD, VPC

DUP.

EKT,

G, ICC.

AAP,

BL, DUP, G, TRC.

DUP,

TRC.

AAP,

DUP.

YAW.

AAP,

BL, DUP, EKT, G, NAC.

DUP,

EKT, G, ICC, YAW.

ICI.

TRC.

TRC.

ICI.

TRC.

ICI.

TRC.

HST.

HST.

DUP, HST.

HST.,

HST..

ICI.

ICI.

HST.

DUP, G„ USE.

ICI. TEC. ICI. TRC. DUP. ICI. ICI. ICI. HST.

ICI. ICI. ICI. TRC. ICI. ICI. ICI. ICI. ICI. TRC.

DYES

103

TABLE 8B. -

■Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

FIBER- REACTIVE DYES— Continued

*Reactive red dyes — Continued

Reactive Red 21

Reactive Red 29

Reactive Red 31

Reactive Red 33

Reactive Red 35

Other reactive red dyes

Reactive violet dyes:

Reactive Violet 1

Reactive Violet 2

Reactive Violet 4

Reactive Violet 5

Other reactive violet dyes

*Re active blue dyes:

Reactive Blue 1

Reactive Blue 2

Reactive Blue 3

Reactive Blue 4

Reactive Blue 5

Reactive Blue 7

Reactive Blue 9

Reactive Blue 19

Reactive Blue 21

Reactive Blue 25

Reactive Blue 27

Other reactive blue dyes

Reactive green dyes

Reactive brown dyes:

Reactive Brown 1

Reactive Brown 10

Reactive black dyes:

Reactive Black 1

Reactive Black 5

Reactive Black 9

FLUORESCENT BRIGHTENING AGENTS

Fluorescent Brightening Agent 1

Fluorescent Brightening Agent 6

Fluorescent Brightening Agent 8

♦Fluorescent Brightening Agent 9

Fluorescent Brightening Agent 22

Fluorescent Brightening Agent 24

Fluorescent Brightening Agent 25

♦Fluorescent Brightening Agent 28

Fluorescent Brightening Agent 30

Fluorescent Brightening Agent 33

Fluorescent Brightening Agent 34-

Fluorescent Brightening Agent 37

Fluorescent Brightening Agent 45

Fluorescent Brightening Agent 46

Fluorescent Brightening Agent 49

Fluorescent Brightening Agent 52

Fluorescent Brightening Agent 54

Fluorescent Brightening Agent 59

Fluorescent Brightening Agent 61

Fluorescent Brightening Agent 68

Fluorescent Brightening Agent 71

Fluorescent Brightening Agent 75

Fluorescent Brightening Agent 102

Fluorescent Brightening Agent 108

Fluorescent Brightening Agent 113

Fluorescent Brightening Agent 114

Fluorescent Brightening Agent 125

Fluorescent Brightening Agent 126

Fluorescent Brightening Agent 128

Fluorescent Brightening Agent 130

Fluorescent Brightening Agent 134

Fluorescent Brightening Agent 135

Manufacturers' identification codes (according to list in table 22)

HST. ICI. ICI. ICI. HST. DUP, G.

ICI. TRC. HST. HST. HST.

ICI.

TRC.

ICI.

ICI.

TRC.

TRC.

ICI.

DUP, HST.

DUP, HST.

ICI.

HST.

DUP, G, HST.

HST.

TRC. ICI.

TRC. HST. ICI.

GGY.

ACT.

ACT.

ACY, G, SDH.

GGY.

GGY.

G.

ACY, CCW, DUP, SDH.

G.

G.

DUP.

CIB.

TRC.

GGY.

S.

S.

GGY.

GGY.

ACY.

CCW, G.

ACY, G.

G.

DUP.

G.

VPC.

VPC.

ACY.

SDH.

SDH.

SDH.

CIB.

CIB.

104

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. — Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Dye

Manufacturers ' identification codes (according to list in table 22)

FLUORESCENT BRIGHTENING AGENTS— Continued

Fluorescent Brightening Agent 136

Fluorescent Brightening Agent 139

Fluorescent Brightening Agent 155

Fluorescent Brightening Agent 158

Fluorescent Brightening Agent 159

Fluorescent Brightening Agent 161

Other fluorescent brightening agents

FOOD, DRUG, AND COSMETIC COLORS

Food, Drug, and Cosmetic Dyes

*FD&C Blue No. 1

FD&C Blue No. 2

FD&C Green No. 3

*FD&C Red No. 2

*FD&C Red No. 3

*FD&C Red No. 4

FD&C Violet No. 1

*FD&C Yellow No. 5

*FD&C Yellow No. 6

Other food, drug, and cosmetic dyes

Drug and Cosmetic Dyes

D&C Black No. 1

D&C Blue No. 1

D&C Blue No. 4

D&C Blue No. 6

DM) Blue No. 9

D&C Brown No. 1

D&C Green No. 5

D&C Green No. 6

D&C Green No. 8

D&C Orange No. 4

D&C Orange No. 5

D&C Orange No. 10

D&C Orange No. 17

D&C Red No. 2

D&C Red No. 3

D&C Red No. 6

D&C Red No. 7

D&C Red No. 8

D&C Red No. 9

D&C Red No. 10

D&C Red No. 11

*D&C Red No. 12 —

D&C Red No. 13

D&C Red No. 17

*D&C Red No. 19

*D&C Red No. 21

D&C Red No. 22

D&C Red No. 27

D&C Red No. 28

D&C Red No. 30

D&C Red No. 31 -

D&C Red No. 33

D&C Red No. 34

*D&C Red No. 36

D&C Red No. 37

D&C Red No. 39

D&C Violet No. 2

D&C Yellow No. 5

D&C Yellow No. 6

D&C Yellow No. 8

D&C Yellow No. 10

D&C Yellow No. 11

CIB. CIB. WLM. ACY. ACY. ACY. ACY, CCW, CIB, DUP, G, GGY, S, VPC.

BAT,

KON,

NAC,

SDH,

WJ.

K0N,

NAC,

SDH.

WJ.

BAT,

KON,

NAC,

SDH,

STG, WJ

BAT,

KON,

NAC,

SDH,

STG.

BAT,

KON,

NAC,

SDH,

STG.

BAT,

NAC.

BAT,

KON,

NAC,

SDH,

STG, WJ

BAT,

KON,

NAC,

SDH,

STG, WJ

WJ.

K0N,

YAW.

K0N.

SNA.

K0N,

NAC.

NAC.

NAC.

K0N,

NAC.

NAC.

K0N,

SDH.

K0N,

SNA.

SNA,

TMS.

TMS.

K0N,

SNA.

K0N.

K0N,

TMS.

K0N,

TMS.

K0N,

SNA,

TMS.

K0N,

TMS.

K0N,

SNA,

TMS.

K0N,

SNA.

K0N,

SNA.

K0N,

SNA,

TMS.

SNA,

TMS.

KON,

NAC.

KON,

SNA,

TMS.

KON,

SNA,

TMS.

KON.

TMS.

NAC.

KON.

KON.

KON,

NAC.

KON,

SNA,

TMS.

KON,

SNA,

TMS.

NAC.

SDH.

NAC.

KON,

TMS.

KON.

KON,

NAC,

TMS.

KON,

NAC.

NAC.

DYES

105

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were re, manufacturer, 1 965- -Continued

ported, identified by

Dye

FOOD, DRUG, AND COSMETIC COLORS— Continued Drug and Cosmetic Dyes, External

Ext. D&C Green No. 1~

Ext. DM Orange No. 3-

Ext. DScC Red No. 8

Ext. DScC Red No. 15—

Ext. DScC Violet No. 2-

Ext. DScC Yellow No. 1-

Ext. DScC Yellow No. 5-

Ext. DScC Yellow No. 7-

Ingrain blue dyes: Ingrain Blue 1— Ingrain Blue 3— Ingrain Blue 4 — Ingrain Blue 8 —

*Mordant yellow dyes:

*Mordant Yellow 1

Mordant Yellow 3

Mordant Yellow 5

*Mordant Yellow 8— Mordant Yellow 10— Mordant Yellow 14 — Mordant Yellow 16 — Mordant Yellow 20— Mordant Yellow 26— Mordant Yellow 29— Mordant Yellow 30— Mordant Yellow 36— n-Mordant orange dyes:

*Mordant Orange 1 — Mordant Orange 4 — Mordant Orange 6 — Mordant Orange 8 — Mordant Orange 30— *Mordant red dyes:

Mordant Red 3

Mordant Red 5

Mordant Red 6

*Mordant Red 7

Mordant Red 9

Mordant Red 11

Mordant Red 19——

Mordant Red 59

Mordant Red 64

Mordant violet dyes:

Mordant Violet 5—

Mordant Violet 11-

Mordant Violet 26-

*Mordant blue dyes:

*Mordant Blue 1

Mordant Blue 3

Mordant Blue 7

Mordant Blue 9

Mordant Blue 13

Mordant Blue 19

Mordant green dyes: Mordant Green 11— Mordant Green 36— *Mordant brown dyes:

*Mordant Brown 1

Mordant Brown 12 — Mordant Brown 13 — Mordant Brown 15 — Mordant Brown 17—

INGRAIN DYES

MORDANT DYES

Manufacturers' identification codes (according to list in table 22)

K0N, NAC. K0N, NAC. SNA. K0N. K0N.

K0N, NAC. SNA. K0N.

ICI. ICI. ICI.

ICI.

ATL, G, PDC, TRC.

ATL, NAC.

NAC, TRC.

DUP, NAC, VPC.

DUP.

NAC, TRC.

ACY, NAC.

NAC.

VPC.

G.

TRC, VPC.

PDC.

ACY, G, PDC, TRC.

G, VPC.

ATL, G, TRC.

TRC.

NAC.

ACY, ICI, NAC.

PDC.

G.

ACY, BD0, CMG, G,

NAC,

PDC, TRC, VPC

G, HSH, MRX, NAC.

ACY, NAC.

PDC.

TRC.

PDC.

NAC.

G.

G.

DUP, G, NAC, TRC.

G.

NAC, TRC.

G, NAC.

HSH, NAC.

CMG.

ACY.

NAC, PDC.

CMG, DUP, G, NAC,

TRC,

YAW.

PDC.

NAC.

G.

106

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. Benzenoid dyes for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Dye

MORDANT DYES— Continued

*Mordant brown dyes — Continued

Mordant Brown 18

Mordant Brown 19

Mordant Brown 21

Mordant Brown 33

*Mordant Brown 4-0

Mordant Brown 43

Mordant Brown 50

Mordant Brown 63

Mordant Brown 70

*Mordant black dyes:

Mordant Black 1

^Mordant Black 3

^Mordant Black 5

Mordant Black 7

Mordant Black 8

Mordant Black 9

*Mordant Black 11

*Mordant Black 13

Mordant Black 16

*Mordant Black 17

Mordant Black 19

Mordant Black 26

*Mordant Black 38

OXIDATION BASES

Oxidation Base 8 and 8A

Oxidation Base 21

Oxidation Base 22

Oxidation Base 25

Other oxidation bases

SOLVENT DYES

^Solvent yellow dyes:

Solvent Yellow 1

*Solvent Yellow 2

^Solvent Yellow 3

Solvent Yellow 13

^Solvent Yellow 14

Solvent Yellow 16

Solvent Yellow 19

Solvent Yellow 29

Solvent Yellow 30

Solvent Yellow 33

Solvent Yellow 34

Solvent Yellow 40

Solvent Yellow 42

Solvent Yellow 43

Solvent Yellow 44

Solvent Yellow 45 —

^Solvent Yellow 47

Solvent Yellow 53

Solvent Yellow 56

Solvent Yellow 66

Solvent Yellow 71

Solvent Yellow 72

Other solvent yellow dyes

* Solvent orange dyes:

^Solvent Orange 2

*Solvent Orange 3

Solvent Orange 5

^Solvent Orange 7

Solvent Orange 20

Solvent Orange 23

Solvent Orange 24

Solvent Orange 25

Solvent Orange 31

Manufacturers' identification codes (according to list in table 22)

DUP, NAC.

G.

G, VPC.

DUP, NAC, TRC.

CMG, DUP, G, NAC, VPC, YAW.

G.

TRC.

TRC.

DUP, PDC.

G, NAC, TRC.

G, NAC, TRC.

G, NAC, TRC.

G.

NAC, VPC.

NAC, VPC.

G, NAC, TRC, VPC.

G, HSH, NAC, TRC.

NAC.

ACY, DUP, G, NAC, TRC.

PDC.

TRC.

CMG, G, NAC, VPC.

ACY. PDC. ACY. ACY. ACY.

ACY.

AAP, DUP, FH, G, PAT, PSC.

DUP, FH, G, NAC, PSC.

ACY, G, TRC.

AAP, ACY, DUP, FH, G, NAC, PAT, PSC, SDH.

PAT.

G.

G, NAC.

PSC.

ACY, NAC.

DUP.

NAC.

NAC.

G.

G, NAC.

DUP, NAC.

ACY, DUP, G, NAC.

NAC.

ACY, FH.

NAC.

ACY.

ACY.

ACY, DSC, PAT.

AAP, NAC, PSC.

ACY, DSC, G, NAC.

G.

ACY, ATL, FH, G, NAC, PSC.

ACY, G, NAC.

NAC.

DUP.

ACY, DUP.

NAC.

DYES

107

TABLE 8B -Benzenoid dyes for which U.S. production or sales were reported, identified by lAtsi^ ob. j manufacturer, 1965 —Continued

Dye

SOLVENT DYES— Continued

•Solvent orange dyes— Continued

Solvent Orange 47

Solvent Orange 48

Solvent Orange 51

Other solvent orange dyes

•Solvent red dyes:

Solvent Red 8

Solvent Red 22

•Solvent Red 24

•Solvent Red 26

Solvent Red 27

Solvent Red 33

Solvent Red 34

Solvent Red 35

Solvent Red 36

Solvent Red 40

Solvent Red 41

•Solvent Red 49

Solvent Red 52

Solvent Red 65

Solvent Red 68

Solvent Red 69

Solvent Red 74

Solvent Red 76

Solvent Red 80

Solvent Red 105

Solvent Red 106

Solvent Red 108

Solvent Red 111

Solvent Red 115

Other solvent red dyes

•Solvent violet dyes:

*Solvent Violet 8

Solvent Violet 9

Solvent Violet 13

Solvent Violet 14

Solvent Violet 17

Other solvent violet dyes- Solvent "blue dyes:

Solvent Blue 3

Solvent Blue 4

Solvent Blue 5

Solvent Blue 6

Solvent Blue 7

Solvent Blue 9

Solvent Blue 11

Solvent Blue 12

Solvent Blue 13

Solvent Blue 16

Solvent Blue 30

Solvent Blue 31

Solvent Blue 32

Solvent Blue 36

Solvent Blue 37

•Solvent Blue 38

Solvent Blue 39

Solvent Blue 43

Solvent Blue 58

Solvent Blue 59

Solvent Blue 60

Other solvent blue dyes — •Solvent green dyes:

Solvent Green 1

Solvent Green 2

•Solvent Green 3

Solvent Green 10

Solvent Green 11

Other solvent green dyes-

Manufacturers' identification codes (according to list in table 22)

ACY. ACY. DSC, DUP, PAT.

G.

G.

ACY, DUP, G, PAT, SDH.

AAP, ACY, FH, NAC, PSC.

NAC.

DUP, G.

DUP.

G.

NAC.

G.

DSC.

ACY, DSC, DUP, G.

G, ICI.

NAC.

NAC.

DUP.

NAC.

NAC.

NAC.

ACY.

ACY.

ACY.

ACY.

ACY.

ACY, BKS, DSC, DUP, G, ICI, PAT.

ACY, DSC, NAC.

DSC.

AAP, HSH, ICI.

ICI.

NAC.

DSC, PAT.

SW.

DSC, DUP, SDH.

DSC.

DSC.

ACY, NAC.

G.

G, ICI.

DUP, NAC

ICI.

NAC.

NAC.

NAC.

AAP.

DUP, NAC.

DUP.

ACY, DUP, NAC.

NAC.

NAC.

ACY.

ACY.

ACY.

AAP, ACY, DSC, G, ICI, PAT, SDH.

ACY, DSC, SDH.

AAP, ACY, ATL, CMG, G, HSH, ICI, NAC.

DUP.

DUP.

DSC.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1 965- -Continued

Dye

Manufacturers ' identification codes (according to list in table 22)

SOLVENT DYES--Continued

^Solvent brown dyes:

Solvent Brown 11

Solvent Brown 12

Solvent Brown 17

Solvent Brown 19

Solvent Brown 20

Solvent Brown 21 ■

Solvent Brown 22

Solvent Brown 38

Other solvent brown dyes

Solvent black dyes:

Solvent Black 3

Solvent Black 5

Solvent Black 7

Solvent Black 12

Solvent Black 13

Solvent Black 17

Solvent Black 19

Solvent Black 20

Solvent Black 26

Other solvent black dyes

SULFUR DYES

Sulfur yellow dyes :

Sulfur Yellow 2

Leuco Sulfur Yellow 2

Sulfur Yellow 4

Leuco Sulfur Yellow 4

Leuco Sulfur Yellow 15

Other sulfur yellow dyes

Sulfur red dyes:

Sulfur Red 1

Sulfur Red 6

Sulfur Red 8

Sulfur blue dyes:

*Sulfur Blue 7

Leuco Sulfur Blue 7

Leuco Sulfur Blue 8

Sulfur Blue 9

Leuco Sulfur Blue 9

*Sulfur Blue 11

Leuco Sulfur Blue 11

Sulfur Blue 13

Leuco Sulfur Blue 13

*Sulfur Blue 15

Sulfur Blue 16

Other sulfur blue dyes

Sulfur green dyes:

Sulfur Green 1

Leuco Sulfur Green 1 ; —

Sulfur Green 2

Leuco Sulfur Green 2

Sulfur Green 3

Leuco Sulfur Green 3

Sulfur Green 14

Leuco Sulfur Green 16

Sulfur Green 28

Other sulfur green dyes

Sulfur brown dyes:

Sulfur Brown 3

Leuco Sulfur Brown 3

*Sulfur Brown 10

Leuco Sulfur Brown 10

Sulfur Brown 14

Leuco Sulfur Brown Li

Sulfur Brown 20

Sulfur Brown 21

Sulfur Brown 30

ACY,

DSC,

G.

DUP.

DUP. ACY,

DUP.

NAC.

FH.

DSC.

NAC.

ACY,

DSC,

NAC.

ACY,

DSC,

FH, NAC

NAC.

NAC.

DUP.

G.

NAC.

ACY.

DSC,

DUP.

NAC. ACY, SDC. SDC. ACY. ACY,

ACY,

ACY, DUP.

ACY, ACY, SDC. ACY, SDC. DUP, SDC. NAC. ACY. ACY, ACY. ACY,

NAC. NAC. NAC, SDC. NAC, SDC. DUP. SDC. ACY. AUG,

SDC. SDC. DUP, SDC. ACY. ACY. DUP. DUP. ACY.

AUG, SDC.

NAC. DUP, NAC.

NAC, SDC. NAC, SDC.

NAC. NAC, SDC.

DUP, NAC. SDC.

SDC. SDC.

NAC, SDC.

DYES

109

TABLE 8B.

■ Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer, 1965- -Continued

Dye

Manufacturers' identification codes (according to list in table 22)

SULFUR DYES— Continued

Sulfur brown dyes — Continued

Sulfur Brown 33

Leuco Sulfur Brown 37

Sulfur Brown 39

Sulfur Brown 4-3

Leuco Sulfur Brown 43

Sulfur Brown 44

Leuco Sulfur Brown 44

Sulfur Brown 45

Sulfur Brown 50

Other sulfur brown dyes

Sulfur black dyes:

*Sulfur Black 1 —

*Leuco Sulfur Black 1

Sulfur Black 2

*Leuco Sulfur Black 2

Sulfur Black 6

Leuco Sulfur Black 6

Sulfur Black 10

Leuco Sulfur Black 10

Sulfur Black 11

Leuco Sulfur Black 11

Other sulfur black dyes

VAT DYES

*Vat yellow dyes:

Vat Yellow 1, 12-1/2$ ■

*Vat Yellow 2, 8-l/2$-

Solubilized Vat Yellow 2, 25$

Vat Yellow 3, 12-1/2$-

*Vat Yellow 4, 12-1/2$

Solubilized Vat Yellow 4, 37-1/2$

Vat Yellow 10, 10$

Vat Yellow 13, 6-1/2$

Vat Yellow 1A, 12-1/2$ -—

Vat Yellow 15, 11-1/2$

Vat Yellow 16, 16-2/3$-

Vat Yellow 21, 9-1/2$ -

Vat Yellow 22, 10$

Vat Yellow 27

Vat Yellow 33 -

Vat Yellow 41, 9$

Other vat yellow dyes

*Vat orange dyes:

*Vat Orange 1, 20$

*Solubilized Vat Orange 1, 26$

*Vat Orange 2, 12$

*Vat Orange 3, 13-1/2$-

*Vat Orange 4, 6$

*Vat Orange 5, 10$

*Solubilized Vat Orange 5, 30$

*Vat Orange 7, 11$

*Vat Orange 9, 12$

Vat Orange 11, 6$

*Vat Orange 15, 10$

Vat Orange 23, 17-1/2$

Vat Orange 24

Other vat orange dyes

*Vat red dyes:

*Vat Red 1, 13$

Solubilized Vat Bed 1, 37$

Vat Red 10, 18$

Solubilized Vat Red 10, 31$

Vat Red 12, 8-1/2$

*Vat Red 13, 11$

Vat Red 14, 10$

*Vat Red 15, 10$

Vat Red 16, 11$

ACY. SDC. SDC. NAC. NAC. NAC. NAC. NAC. NAC. ACY, AUG, NAC, SDC.

ACY, DUP, NAC, SDC.

ACY, AUG, NAC, SDC.

ACY, DUP, NAC.

ACY, NAC, SDC.

G.

NAC.

ACY.

ACY, NAC.

SDC.

SDC.

SDC.

NAC.

AAP, DUP, G, ICI, NAC, TRC, VPC.

G, ICI.

DUP.

AAP, ACY, ATL, CMG, G, HST, ICI, VPC.

G, HST, ICI.

G.

ICI.

TRC.

ACY.

DUP.

ATL.

DUP, G.

VPC.

TRC, VPC.

ACY.

MAY, NAC, VPC.

CMG, G, HST, ICI, NAC, TRC, VPC.

G, HST, ICI.

AAP, ACY, CMG, DUP, G, ICI, NAC, TRC.

CMG, DUP, G, HST.

ACY, CMG, DUP.

AAP, ACY, HST.

G, HST, ICI.

G, HST, TRC.

ACY, CMG, DUP, G, ICI, NAC, TRC.

DUP, NAC.

AAP, G, ICI, NAC, TRC, VPC.

ACY, DUP, G.

DUP.

SDC.

AAP, ACY, DUP, HST, ICI.

G, HST, ICI.

G, NAC, TRC.

G.

DUP.

DUP, G, TRC.

G, HST.

G, HST, TRC.

DUP.

no

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 8B. —Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

VAT DYES— Continued

*Vat red dyes — Continued

Vat Red 17, 10$

Vat Red 23 -

Vat Red 29, 18$

*Vat Red 32, 20$

Vat Red 35, 12-1/2$

Vat Red 41, 20$-

Vat Red 44, 17$ —

Vat Red 52, 10$- - -

Vat Red 53, 12$ —

Vat Red 56

Vat Red 62

Other vat red dyes

*Vat violet dyes:

*Vat Violet 1, 11$

Solubilized Vat Violet 1, 26$

*Vat Violet 2, 20$

Vat Violet 3, 15$

*Vat Violet 9, 12$

Vat Violet 12, 10$

*Vat Violet 13, 6-l/*$

Vat Violet 1A, 12-1/2$

Vat Violet 17, 12-1/2$

Other vat violet dyes

*Vat blue dyes:

Vat Blue 1, 20$

Solubilized Vat Blue 1, 25$

Vat Blue 3, 16$

Vat Blue 4, 10$

Vat Blue 5, 16$ -

Solubilized Vat Blue 5, 38$

*Vat Blue 6, 8-1/3$

Solubilized Vat Blue 6, 17-1/2$-

Vat Blue 7, 12-1/2$ -

Solubilized Vat Blue 9, 35$

Vat Blue 12, 6-l/2$-

Vat Blue 14, 8-1/3$

Vat Blue 16, 16$--

*Vat Blue 18, 13$

*Vat Blue 20, 14$

Vat Blue 29— -

Vat Blue 39, 12$

Vat Blue 43

Vat Blue 53

Vat Blue 60

Vat Blue 61, 16$

Other vat blue dyes

*Vat green dyes:

*Vat Green 1, 6$

Solubilized Vat Green 1, 12-3/2$ -

*Vat Green 3, 10$

*Solubilized Vat Green 3, 26$

*Vat Green 8, 8-1/2$

*Vat Green 9, 12-1/2$—

Vat Green 15, 17$ ■

Vat Green 18, 8$-

Vat Green 19, 13$

Vat Green 20, 6$-

Other vat green dyes

*Vat brown dyes:

*Vat Brown 1, 11$

Solubilized Vat Brown 1, 17$

*Vat Brown 3, 11$

*Vat Brown 5, 13$- ■

Vat Brown 6, 17-1/2$

Vat Brown 11, 12$

Vat Brown 12, 12-1/2$

Vat Brown 13, 17$

Vat Brown 14, 12$

Manufacturers' identification codes (according to list in table 22)

G.

DUP.

G, NAC.

DUP, G, NAC.

NAC, TRC.

HST.

TRC.

DUP.

DUP.

ACY.

DUP.

DUP, G, TRC, VPC.

ACY, DUP, G, ICI, MAY, NAC, TRC.

G, ICI.

ACY, G, HST, NAC, VPC.

G, HST, NAC.

DUP, G, ICI, MAY, NAC, TRC.

DUP.

DUP, G, ICI, NAC, TRC.

NAC.

DUP, G, NAC.

NAC.

NAC.

G.

HST.

ACY, DUP, G.

ATL, DUP, HST, NAC, VPC.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

G, HST, ICI.

NAC.

G.

DUP.

DUP, G, NAC, TRC.

ACY, DUP, NAC.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC.

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC.

G.

G.

SDC.

G.

DUP.

DUP.

SDC, x.

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC.

G, HST, ICI.

AAP, ACY, ATL, DUP, G, ICI, MAY, NAC, TRC.

G, HST, ICI.

ATL, DUP, G, ICI, NAC.

ACY, ATL, DUP, G, MAY, NAC, SDC, TRC.

NAC.

DUP.

DUP.

DUP.

G, SDG.

ACY, DUP, G, ICI, MAY, NAC, TRC.

G, ICI.

AAP, ACY, DUP, G, ICI, MAY, NAC, TRC, VPC.

AAP, ACY, G, HST, VPC.

TRC.

MAY, TRC.

DUP, NAC.

MAY.

HST.

DYES

TABLE 8B. --Benzenoid dyes for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Dye

Manufacturers' identification codes (according to list in table 22)

VAT DYES— Continued *Vat brown dyes — Continued

G.

ACT.

AAP.

ICI.

DUP.

G.

TRC.

*Vat black dyes:

ACY.

G.

112

SYNTHETIC ORGANIC CHEMICALS. 1965

Pigments

TABLE 11B. — Benzenoid pigments for which U.S. production or sales were reported, identified

by manufacturer , 1965

[Benzenoid pigments for which separate statistics are given in table 11A are marked below with an asterisk (♦); products not po marked do not appear in table 11A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product ]

Pigment

Manufacturers' identification codes (according to list in table 22)

TONERS ♦Yellow toners: ♦Hans a yellows:

♦Pigment Yellow 1, C.I. 11 680

♦Pigment Yellow 3, C.I. 11 710

Pigment Yellow 4, C.I. 11 665

Pigment Yellow 5, 'C.I. 11 660

Pigment Yellow 6, C.I. 11 670

Pigment Yellow 9, C.I. 11 720

Pigment Yellow 49, C.I. 11 765

Pigment Yellow 65, C.I. 11 74-0

Pigment Yellow 73

Pigment Yellow 74

All other Hansa yellows

♦Benzidine yellows:

♦Pigment Yellow 12, C.I. 21 090

♦Pigment Yellow 13, C.I. 21 100

♦Pigment Yellow 14, C.I. 21 095

♦Pigment Yellow 17, C.I. 21 105

Pigment Yellow 83

All other benzidine yellows

Pigment Yellow 10, C.I. 12 710

Pigment Yellow 18, C.I. 49 005

Pigment Yellow 19

Pigment Yellow 60, C.I. 12 705

Pigment Yellow 62

(Basic Yellow 2), C.I. 41 000, fugitive-

(Vat Yellow 1), C.I. 70 600

(Vat Yellow 20), C.I. 68 420

All other

♦Orange toners:

Pigment Orange 1, C.I. 11 725

♦Pigment Orange 2, C.I. 12 060

♦Pigment Orange 5, C.I. 12 075

Pigment Orange 9

♦Pigment Orange 13, C.I. 21 110

Pigment Orange 15, C.I. 21 130

♦Pigment Orange 16, C.I. 21 160

Pigment Orange 30

(Vat Orange 2), C.I. 59 705

(Vat Orange 3), C.I. 59 300

(Vat Orange 4), C.I. 59 710

(Vat Orange 5), C.I. 73 335

(Vat Orange 7), C.I. 71 105

(Vat Orange 15), C.I. 69 025

All other

♦Red toners: ♦Naphthol reds:

♦Pigment Red 2, C.I. 12 310

♦Pigment Red 5, C.I. 12 490

Pigment Red 7, C.I. 12 420

Pigment Red 9, C.I. 12 460

Pigment Red 10, C.I. 12 440

Pigment Red 13, C.I. 12 395

Pigment Red 14, C.I. 12 380

Pigment Red 15, C.I. 12 465

ACY, AMS, DUP, FCL, G, HSC, HSH, ICI, IMP, K0N, NAC,

PPG, S, SDH, SNA, SW. HSC, HSH, HST, IMP, KCW, K0N, NAC, PPG, S, SNA, SW. NAC, SNA. IMP.

CIK, IMP. SNA. ICI. SW.

NAC, SW. DUP, SW. DUP, HSC, HSH, IMP, KCW, SDH, SNA.

ACY, AMS, DUP, FCL, G, HSC, HSH, ICC, IMP, KON, LVY,

MRX, NAC, S, SDH, SNA, SW. BUC, FCL, G, HSH, HST, ICC, IMP, NAC, ROM, SNA, SW. ACY, AMS, BUC, CPC, DUP, FCL, G, HSC, HSH, HST, ICC,

IMP, KON, MRX, NAC, ROM, S, SDH, SNA, SW, x. ACY, AMS, DUP, FCL, HSC, HSH, HST, ICC, IMP, S, SDH,

SNA, SW. HST, NAC.

BUC, HSH, ICC, IMP, ROM, S, SW. SW. IMP. G. SW. S.

MRX.

NAC, TRC. NAC, TRC. ACY, ICC, IMP, SW.

KCW, NAC.

FCL, IMP, SDH, SW.

ACY, EAK, HSC, IMP, SNA, SW.

DUP.

ACY, AMS, BUC, DUP, G, ICC, IMP, KON, NAC, SNA, SW.

G, NAC.

BUC, DUP, FCL, G, HSH, HST, ICC, IMP, NAC, ROM, SDH,

SNA, SW. SNA, SW. G.

NAC, TRC. NAC. TRO. G, NAC. NAC. HSH, ICC, KON, ROM, SDH.

BUC, EAK, G, HSC, HSH, IMP, KCW, KON, MRX, NAC, S, SDH,

SW. DUP, G, HSH, HST, ICC, ICI, IMP, NAC, ROM, SDH, SNA, SW. ICI, S. IMP. KCW.

IMP, KCW. DUP, NAC. DUP.

See note at end of table for definition of abbreviations.

PIGMENTS

TABLE WB.—Benzenoid pigments for which U.S. production or sales were reported, identified by manufacturer, 1 965— Continued

113

Pigment

TONERS— Continued

♦Red toners — Continued *Naphthol reds --Continued

*Pigment Red 17, C.I. 12 390

♦Pigment Red 18, C.I. 12 350

Pigment Red 19, C.I. 12 400

♦Pigment Red 22, C.I. 12 315

♦Pigment Red 23, C.I. 12 355

Pigment Red 31, C.I. 12 360

All other naphthol reds

♦Pigment Red 1, C.I. 12 070, dark

♦Pigment Red 1, C.I. 12 070, light

*Pigment Red 3, C.I. 12 120

♦Pigment Red 4, C.I. 12 085

Pigment Red 5

♦Pigment Red 6, C.I. 12 090

♦Pigment Red 38, C.I. 21 120

Pigment Red 41, C.I. 21 200

♦Pigment Red 48, C.I. 15 865

Pigment Red 49, C.I. 15 630: *Barium toner

♦Calcium toner

♦Sodium toner

♦Pigment Red 52, C.I. 15 860

♦Pigment Red 53, C.I. 15 585, barium toner- -

Pigment Red 53, C.I. 15 585, sodium toner--

♦Pigment Red 54, C.I. 14 830, calcium toner- Pigment Red 55, C.I. 15 820

♦Pigment Red 57, C.I. 15 850, calcium toner- Pigment Red 58, C.I. 15 825

♦Pigment Red 63, C.I. 15 880

Pigment Red 64, C.I. 15 800

Pigment Red 77, C.I. 15 826

Pigment Red 78

Pigment Red 79, PMA

Pigment Red 81, C.I. 45 160, fugitive

♦Pigment Red 81, C.I. 45 160, PMA.

♦Pigment Red 81, C.I. 45 160, PTA

Pigment Red 87, C.I. 73 310

Pigment Red 88

♦Pigment Red 90, C.I. 45 380

Pigment Red 117, C.I. 15 603

Pigment Red 122

Pigment Red 123

(Vat Red 10), C.I. 67 000

(Vat Red 23)

(Vat Red 29), C.I. 71 140

All other

♦Violet toners:

Pigment Violet 1, C.I. 45 170, fugitive

♦Pigment Violet 1, C.I. 45 170, PMA

♦Pigment Violet 1, C.I. 45 170, PTA

♦Pigment Violet 3, C.I. 42 535, fugitive

♦Pigment Violet 3, C.I. 42 535, PMA

♦Pigment Violet 3, C.I. 42 535, PTA

Pigment Violet 19

Pigment Violet 23

Manufacturers ' identification codes (according to list in table 22)

ACY, BLN, FCL, ICC, IMP, S, SNA, SW.

IMP, NAC, SW.

NAC.

ACY, DUP, FCL, IMP, MRX, NAC, SNA, SW.

ACY, BUC, DUP, FCL, HSC, HSH, ICC, IMP, NAC, ROM, SDH,

SNA. ICC, SNA.

BUC, ICC, IMP, KCW, ROM, SDH, SW, x. ACY, AMS, APC, FCL, HSC, HSH, IMP, K0N, LVY, NAC,

PPG, SDH, SW. ACY, EAK, FCL, HSC, HSH, IMP, KON, PPG, SDH, SW. ACY, APC, BLN, CIK, DUP, EAK, FCL, HSC, HSH, IMP, KCW,

KON, NAC, PPG, SDH, SNA, SW. ACY, AMS, FCL, HSC, HSH, IMP, KON, MRX, SDH, SNA, SW,

UHL. IMP.

DUP, HSC, HSH, KCW, SW. DUP, G, NAC, SNA, SW. G, NAC. ACY, AMS, BLN, DUP, FCL, G, HSC, HSH, ICC, IMP, KON,

LVY, MRX, NAC, S, SNA, SW.

ACY, AMS, CIK, FCL, HSC, HSH, IMP, KON, LVY, PPG, SDH,

SNA, SW, UHL. ACY, AMS, FCL, HSC, IMP, LVY, PPG, SDH, SNA, SW. ACY, AMS, CIK, FCL, HSC, SDH, SW. AMS, FCL, HSC, HSH, IMP, SNA, SW. ACY, AMS, CIK, FCL, HSC, HSH, IMP, KON, LVY, MGR, MRX,

SDH, SNA, SW. KCN.

HSH, IMP, MRX, SDH. DUP, NAC. AMS, BLN, CIK, DUP, FCL, HSC, HSH, IMP, KON, LVY, MGR,

NAC, S, SDH, SNA, SW. DUP, G, IMP.

FCL, HSH, IMP, NAC, SNA, SW. NAC. SW. DUP. G.

BLN, KCW. BLN, CPC, DUP, FCL, G, IMP, KON, LVR, LVY, MGR, MRX,

NYC, S, SNA, SW. ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KCW, KON, MGR,

MRX, S, SDH, SNA. NAC.

NAC, SDH.

AMS, FCL, ICC, IMP, LVR, LVY, NYC, SDH, SNA. SW. NAC. NAC. G, NAC. NAC. NAC. ACY, DUP, G, HAM, HSC, S, SW, TRC.

BLN, UHL.

BLN, G, IMP, LVR, MRX.

ACY, AMS, BLN, DUP, FCL, G, HSC, IMP, KON, MRX, SNA.

ACY, AMS, BLN, HAM, HSC, IMP, LVY, MGE, SDH, UHL.

AMS, BLN, CIK, DUP, EAK, G, HSC, IMP, KON, LVR, LVY,

MGR, MRX, NYC, PPG, SDH, SNA, SW, UHL. ACY, AMS, G, HSC, HSH, IMP, KON, MRX, SNA, SW. DUP, NAC. G, HST, TRC.

See note at end of table for definition of abbreviations.

TABLE 11B.

SYNTHETIC ORGANIC CHEMICALS. 1965

-Benzenoid pigments for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Pigment

TONERS--Ccmtinued

*Violet toners — Continued

(Vat Violet 1), C.I. 60 010

(Vat Violet 2), C.I. 73 385

(Vat Violet 3), C.I. 73 395

All other

♦Blue toners:

♦Pigment Blue 1, C.I. 42 595, PMA

♦Pigment Blue 1, C.I. 42 595, PTA

♦Pigment Blue 2, C.I. 44 045, fugitive

♦Pigment Blue 2, C.I. 44 045, PMA

♦Pigment Blue 2, C.I. 44 045, PTA

Pigment Blue 3, C.I. 42 140, PTA

Pigment Blue 5, C.I. 42 600

Pigment Blue 9, C.I. 42 025, PMA

♦Pigment Blue 9, C.I. 42 025, PTA

Pigment Blue 10, C.I. 44 040, PMA

Pigment Blue 10, C.I. 44 040, PTA

♦Pigment Blue 14, C.I. 42 600, PMA

Pigment Blue 14, C.I. 42 600, PTA

♦Pigment Blue 15, C.I. 74 160, alpha form

♦Pigment Blue 15, C.I. 74 160, beta form

♦Pigment Blue 19, C.I. 42 750A

♦Pigment Blue 22, C.I. 69 810

Pigment Blue 25, C.I. 21 180

(Basic Blue 7), C.I. 42 595, PTA

(Vat Blue 4), C.I. 69 800

(Vat Blue 6), C.I. 69 825

(Vat Blue 14), C.I. 69 810

All other

♦Green toners:

Pigment Green 1, C.I. 42 040, fugitive

♦Pigment Green 1, C.I. 42 040, PMA

♦Pigment Green 1, C.I. 42 040, PTA

♦Pigment Green 2, C.I. 42 040 and 49 005, PMA- ♦Pigment Green 2, C.I. 42 040 and 49 005, PTA-

Pigment Green 4, C.I. 42 000, fugitive

♦Pigment Green 4, C.I. 42 000, PMA

♦Pigment Green 4, C.I. 42 000, PTA

♦Pigment Green 7, C.I. 74 260

♦Pigment Green 8, C.I. 10 006

Pigment Green 10, C.I. 12 775

Pigment Green 36

Pigment Green 38

All other

♦Brown toners :

Pigment Brown 1, C.I. 12 480

Pigment Brown 2, C.I. 12 071

Pigment Brown 3, C.I. 21 010, PMA

♦Pigment Brown 5, C.I. 15 800

(Vat Brown 3), C.I. 69 015

All other

♦Black toners:

Pigment Black 1

Pigment Black 7, C.I. 77 266

All other

LAKES

Yellow lakes:

(Acid Yellow 1), C.I. 10 316

(Acid Yellow 3), C.I. 47 005

(Acid Yellow 11), C.I. 18 820

(Acid Yellow 23), C.I. 19 140

Manufacturers ' identification codes (according to list in table 22)

DUP, ICI, NAC.

NAC.

NAC.

ACY, G, ICC, IMP, ROM.

BLN, DUP, EAK, FCL, G, HSC, IMP, K0N, LVR, LVY, MGR,

MRX, NYC, SDH, SNA, SW, UHL. AMS, G, HAM, IMP, MGR, NAC, SNA, SW, UHL. BLN.

G, IMP, LVR. G, HAM. MGR. G.

MRX, NYC, UHL. BLN, G, IMP, MGR, MRX, SDH. IMP, SDH. IMP.

DUP, G, IMP, NYC. DUP, G, NYC. ACY, DUP, FCL, G, HSC, ICC, ICI, IMP, NAC, SNA, SW,

TMS, TRC. ACY, AMS, DUP, FCL, HSC, IMP, LVY, NAC, SNA, SW, TMS. ACY, AMS, HSC, NYC, SW. DUP, IMP, TRC. DUP, G, ICC, NAC. DUP. G.

ICI, TRC. NAC. G, IMP, MGR, SDH.

BLN, G, IMP, MGR, MRX, NYC, UHL.

BLN, IMP, K0N, S, SDH, SNA.

G, IMP, LVY, MGR, MRX, SDH, UHL.

ACY, AMS, BLN, DUP, IMP, K0N, LVY, MGR, MRX, S, SDH,

UHL. BLN, G, MGR. BLN, G, MGR. ACY, AMS, HAM, IMP. ACY, DUP, FCL, G, HSC, ICC, IMP, NAC, SNA, SW, TMS,

TRC. DUP, G, HSH, IMP, KCW, LVY, SW. DUP, HSC, IMP, SW. ACY, G. NAC. ACY, G, SNA.

ICI.

SDH.

BLN, KCW.

BUC, HSH, ICC, NAC, ROM, SNA.

G, NAC, TRC.

G, ICC, SDH, SW.

SNA. G.

BLN, DUP, G, MGR, UHL.

IMP. IMP. KON. KON, MRX.

See note at end of table for definition of abbreviations.

PIGMENTS

115

TABLE 11B.

■ Benzenoid pigments for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Pigment

Manufacturers ' identification codes (according to list in table 22)

LAKES— Continued

Orange lakes:

Pigment Orange 17, C.I. 15 510

All other

*Red lakes:

♦Pigment Red 60, C.I. 16 105

♦Pigment Red 83, C.I. 58 000

(Acid Red 17), C.I. 16 180

(Acid Red 25), C.I. 16 050

♦ (Acid Red 26), C.I. 16 150

(Acid Red 27)

(Natural Red 4), C.I. 75 470

All other

*Violet lakes:

♦Pigment Violet 5, C.I. 58 055

Pigment Violet 20, C.I. 58 225

(Acid Violet 17), C.I. 42 650

♦Blue lakes:

Pigment Blue 17, C.I. 74 180

♦Pigment Blue 24, C.I. 42 090

(Acid Blue 93), C.I. 42 780

(Acid Blue 104), C.I. 42 735

Green lakes: (Acid Green 3), C.I. 42 085

Brown lakes

Black lakes: ♦(Natural Black 3), C.I. 75 291

CIK, CPC, IMP, KCW, MGR. APC, HAM.

BLN, DUP, HSC, HSH, K0N, MRX, SNA, SW.

HSH, IMP, KON, MRX, SW, UHL.

IMP, KCW.

KON.

CPC, EAK, HAM, IMP, KCW.

KON.

KON.

APC, G, HAM, IMP.

BLN, DUP, HSH, IMP, NAC.

SW.

BLN.

HAM, HSC.

BLN, CPC.

AMS, BLN, ICC, KON, LVY, MGR, SDH.

LVR.

CPC, KCW.

BLN, CPC.

HAM, KON.

CPC, KON, NYC. HAM.

Note. — The C.I. (Colour Index) numbers shown in this report are the identifying codes given in the second edition of the Colour Index.

When the name of a color is enclosed in parentheses, it indicates that this name is that of the dye from which the pigment can be made and that no name for the pigment itself is given in the Colour Index.

The abbreviations PMA and PTA stand for phosphomolybdic and phosphotungstic (including phosphotungstomolybdic ) acids, respectively.

116

SYNTHETIC ORGANIC CHEMICALS, 1965

Medicinal Chemicals

TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Medicinal chemicals for which separate statistics are given in table 13A in pt. II are marked below with an asterisk (*); medicinal chemicals not so marked do not appear in table 13A because the reported data are accepted in con- fidence and may not be published. Manufacturers ' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Chemical

Manufacturers ' identification codes (according to list in table 22)

* Antibiotics :

*For medicinal use:

*Antifungal and antitubercular antibiotics Antifungal antibiotics :

Amphotericin B

Candicidin

Nystatin

Antitubercular antibiotics :

Cycloserine

Dihydrostreptomycin

^Streptomycin

Viomycin

*Bacitracin

*Penicillins :

Ampicillin

Cloxacillln, sodium

Methicillin, sodium

Nafcillin, sodium

Oxacillin, sodium

Penicillin G, benzathine

^Penicillin G, potassium

*Penicillin G, procaine

Penicillin G, sodium

Phenethicillln, potassium

Phenoxymethylpenicill in (Penicillin V) —

Phenoxymethylpenicil 1 in, benzathine

Phenoxymethylpenicillln, hydrabamine

Phenoxymethylpenicillin, potassium

*Other antibiotics for medicinal use:

Cephalothin

Chloramphenicol

Erythromycin

Fumagillin

Gentamycin

Gramicidin

Kanamycin

Lincomycin

Neomycin

Novobiocin

Oleandomycin

Paromomycin

Polymyxin B

Ristocetin

Tetracyclines :

Chlortetracycline

Demethylchlortetracycline

Oxytetracycline

Tetracycline

Thiostrepton

Triacetyloleandomyciii

Tyrothricin

*For other uses:

^Bacitracin

Chlortetracycline

Cycloheximide

Ifygromycin B

Neomycin

Novobiocin

Oxytetracycline

^Penicillin G, procaine,

Streptomycin 1

Tylosin

PEN.

OMS.

COM.

MRK,

OMS,

PFZ.

LIL,

MRK,

OMS,

PFZ.

PFZ.

COM,

PEN,

PFZ,

PMP.

BRS.

BRS.

WYT.

BRS.

PFZ,

WYT.

LIL,

MRK,

OMS,

PFZ,

WYT

LIL,

MRK,

OMS,

PFZ,

WYT

MRK,

OMS,

PFZ.

BRS,

PFZ,

WYT.

LIL.

WYT.

ABB.

ABB,

LIL.

SCH.

BAX,

BRS.

x.

OMS,

MRK,

PFZ.

MRK.

PFZ.

ABB.

ACY. ACY. PFZ. ACY, OMS. PFZ. BAX,

COM, ACY. UP J. LIL. PFZ. UP J. PFZ. LIL, MRK, LIL.

PEN, PFZ, UP J. UP J.

BRS, PFZ, RLS.

PEN.

GPR, PEN, PMP.

MRK, OMS, PFZ, WYT. PFZ.

MEDICINAL CHEMICALS

117

TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

♦Antihistamines : *Antinauseants :

Cyclizine hydrochloride

Dimehhydrinate

Meclizine hydrochloride

Trimethobenzamide hydrochloride

Bromodiphenhydramine hydrochloride

Brompheniramine maleate

Carbinoxamine maleate

Chlorcyclizine hydrochloride

♦Chlorpheniramine maleate

Cyproheptadine hydrochloride

Dexbrompheniramine maleate

Dexchlorpheniramine maleate

Dimethindene maleate

Diphenhydramine hydrochloride

Doxylamine succinate

Methapyrilene fumarate

Methapyrilene hydrochloride

Methapyrilene hydroxybenzoylbenzoate

Phenindamine tartrate

♦Pheniramine maleate

Phenyltoloxamine citrate

♦Pyrilamine maleate

Pyrrobutamine phosphate

Eotoxamine (levo- Carbinoxamine) tartrate

Thenyldiamine hydrochloride

Thonzylamine hydrochloride

Tripelennamine

Tripelennamine citrate

Tripelennamine hydrochloride

Triprolidine hydrochloride

♦Anti-infective agents (except antibiotics): ♦Antimony, arsenic, and bismuth compounds:

Arsanilic acid

Bismuth dipropylacetate

Bismuth sodium triglycollamate

Bismuth subsalicylate

Carbarsone

Glycobiarsol

Ni tars one

Roxarsone

Roxarsone, sodium

Sodium arsanilate

*Cetylpyridinium chloride

♦Mercury compounds :

o-Hydroxyphenylmercuric chloride

Merbromin

Mercuric salicylate

Nitromersol

Phenylmereuric acetate

Phenylmercuric benzoate

Phenylmereuric borate

Phenylmercuric chloride

Phenylmercuric nitrate

Thimerosal

♦5-Nitrofurane, -imidazole, and -thiazole derivatives:

Acinitrazole

2-Amino-5-nitrothiazole

Furazolidone

Metronidazole

Nihydrazone

Ni thiazide

Nitrofurantoin

Nitrofura thiazide

Nitrofurazone

♦Phenolic antiseptics and disinfectants:

Betanaphthol

Bithionol

Resorcinol

Thymol

Thymol iodide

BUR.

SRL.

PFZ.

HOF.

PD.

SCH.

SCH.

ABB,

HEX,

MRK.

SCH.

SCH.

CBP.

ARA,

BKC.

ABB.

ABB.

LIL.

HOF.

HEX,

BRS.

BKL,

LIL.

SCH.

SDW.

NEP.

CBP.

CBP.

CBP.

BUR.

BUR.

LEM, SCH, SK, x.

GAN, PD.

LEM, SCH, x.

HEX, MRK, PYL, RSA.

MAL,

NOR,

PEN.

LIL,

PYL,

RSA,

WHL.

SDW.

SAL.

SAL.

SAL.

SAL,

WHL.

BKL,

FIN,

GAN,

HEX, NEP

MRK.

HYN.

MAL,

MRK.

ABB.

WRC.

MRK,

WRC.

MRK,

WRC.

MRK.

MRK,

WRC.

LIL,

PYL,

SEL.

ACY.

ACY.

NOR.

RDA.

NOR.

MRK.

NOR.

SCH.

NOR.

ACY,

FIN.

SDH.

KPT,

LEM.

GIV.

MAL.

118

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 13B.

■ Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

*Anti-infective agents (except antibiotics) — Continued *Piperazine base and salts :

*Piperazine

Piperazine adipate

Piperazine calcium edetate

Piperazine citrate

Piperazine dihydrochloride

Piperazine hexabydrate

Piperazine hydrochloride

Piperazine phosphate

Piperazine sulfate

Piperazine tartrate

*Quinoline derivatives:

Amodiaquin

Amodiaquin hydrochloride

Chloroquine phosphate

*Diiodohydroxyquin

Hydroxychloroquine sulfate

8-Hydroxy-5-quinolinesulfonic acid

Iodochlorhydroxyquin

Qxyquinoline

Oxyquinoline benzoate

Qxyquinoline citrate

Qxyquinoline potassium sulfate

Qxyquinoline sulfate

Primaquine phosphate

^Sulfonamides :

Acetyl sulfamethoxypyridazine '

Acetyl sulfisoxazole

Azosulf amide .

Dinsed

Mafenide hydrochloride

Phthalylsulfacetamide

Phthalylsulfathiazole

Succinylsulfathiazole

Sulfabenz

Sulfabenzamide

Sulfabenzamide, sodium

Sulfabromomethazine, sodium

Sulfacetamide

Sulfacetamide, sodium

Sulfadiazine

Sulfadiazine, sodium

Sulfadimethoxine

Sulfaethidole

Sulfaguanidine

Sulfamerazine

Sulfamerazine, sodium

Sulfamethazine

Sulfamethizole

Sulfamethoxazole

Sulfamethoxypyridazine

Sulfanilamide

Sulfanitran •

Sulfapyridine

Sulf apy ridine , sodium

Sulfaquinoxaline

*Sulfathiazole

Sulfathiazole, sodium

Sulfisoxazole

*Other anti-infective agents :

*Anthelmintic, antifungal, antiprotozoan, and antiviral agents : Anthelmintic agents :

Cadium anthranilate

Diethylcarbamazine citrate

Gentian violet

Hexylresorcinol

Phenothiazine

Pyrvinium pamoate

Thiabendazole

DOW,

JCC,

UCC.

JCC,

PYL,

RDA.

EN.

BUR,

JCC,

RDA.

DOW,

JCC,

RDA,

WHL.

JCC,

RDA.

DOW,

JCC,

RDA.

BUR,

JCC,

PYL,

RDA, WHL

JCC,

RDA.

RDA.

PD.

PD.

SDW.

LEM,

PYL,

RSA,

SRL.

SDW.

GAM,

MRK.

CBP,

PYL.

GAM,

LEM,

MRK.

GAM,

LEM,

MRK.

GAM.

LEM.

GAM,

LEM,

MRK,

PYL.

PD,

SDW.

ACY.

HOF.

SDW.

SAL.

SDW.

LEM.

MRK.

LEM,

MRK.

SAL.

ACY.

ACY.

MRK.

LEM.

LEM,

SCH.

ACY,

LEM.

ACY.

HOF.

ACY.

ACY,

LEM.

ACY,

LEM.

ACY.

ACY,

LEM.

ACY.

HOF.

ACY.

LEM,

MRK.

SAL.

ACY,

MRK.

ACY.

MRK.

ACY,

LEM,

MRK.

ACY,

MRK.

HOF.

MAL.

ACY.

NAC, SDH.

HEX, MRK.

CLV.

x.

MRK.

MEDICINAL CHEMICALS

TABLE 13B.-- Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

1)9

Manufacturers ' identification codes (according to list in table 22)

*Anti-ihfective agents (except antibiotics) --Continued *Other anti-infective agents — Continued

*Anthelmintic , antifungal, antiprotozoal and antiviral agents — Continued Antifungal agents :

Benzoic acid

Calcium undecylenate

Diamthazole hydrochloride

Fuchsin, basic

p-Hydroxybenzoic acid esters :

Butylparaben

Ethylparaben

Methylparaben

Propylparaben

Salicylanilide

Sodium eaprylate

Sodium undecylenate

Undecylenic acid

Zinc undecylenate

Antiprotozoan agents :

Aklomide

Amprolium

Nitrophenide

Pyrimethamine

Antiviral agent: Amantadine hydrochloride

*Urinary antiseptics :

Ammonium benzoate

Calcium mandelate

Ethoxazene hydrochloride

Mandelic acid

Methenamine

Methenamine acetamidosalicylate

Mathenamine mandelate

Methylene blue

Phenazopyridine hydrochloride

*A11 other:

Acriflavine ^

Acriviolet

Aminacrine

Aminacrine hydrochloride

Antileprotic and antitubercular agents :

Aminosalicylic acid

Calcium aminosalicylate

Isoniazid

Potassium aminosalicylate

Pyrazinamide

Sodium aminosalicylate

Sodium sulfoxone

Benzalkonium chloride

Bromoform

Camphor, monobromated

Cetalkonium chloride

Chloramine T

Chlorobutanol

Iodoform

Magnesium salicylate

Nalidixic acid

Nitromide

Povidone - iodine complex

*Antineoplastic agents and local anesthetics : Antineoplastic agents :

Mercaptopurine

Ure thane

Vinblastine sulfate

Vincristine sulfate

Local anesthetics :

Butacaine sulfate

Butamben picrate

Butyl aminobenzoate (Butamben)

Dibucaine

Dibucaine hydrochloride

MON,

PFZ.

WTL.

HOF.

NAC.

HN,

ICO.

HN.

HN,

ECO, LEM, PYL.

HN,

ICO, LEM, PYL.

LEM.

LEM,

TNC.

BAC.

BAC.

BAC,

LEM, TNC, WTL.

SAL.

MRK.

ACY.

BUR.

x.

GAM,

PEN.

MAL.

KON.

MAL.

HN.

ABB.

LEM,

NEP, PYL, TNC

ACY,

NAC.

HOF,

KON, NEP.

NAC.

NAC.

SDW.

SDW.

MLS.

MLS.

RIL.

MLS.

MRK.

MLS.

ABB.

SDH.

DOW.

MAL,

PEN.

FIN,

SDW.

MON.

BPC,

PD.

MAL,

PEN.

MAL.

SDH,

SDW.

SAL.

C-.

BUR.

BKL,

FMP.

LIL.

LIL.

ABB.

ABB.

ABB,

ICO.

CBP.

CBP.

SYNIHkllC ORGANIC CHEMICALS, 1965

TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported identified bv

manufacturer, 1 965— Continued

"Antineoplastic agents and local anesthetics— Continued Local anesthetics — Continued

Ethyl aminobenzoate (Benzocaine)

Isobutyl aminohenzoate

Lidocaine

Oxethazaine

Phenacaine hydrochloride

Piperocaine hydrochloride

Pramoxine hydrochloride

Procaine

Procaine hydrochloride

Proparacaine hydrochloride

Propyl aminohenzoate

Pyrrocaine hydrochloride

Tetracaine

Tetracaine hydrochloride

"Autonomic drugs :

Ganglionic blocking agent: Tetraethylammonium chloride— Parasympatholytic (anticholinergic) agents: "Quaternary ammonium compounds (except tropane derivatives) :

Ambutonium bromide

Diphemanil methylsulfate

Hexocyclium methylsulfate

Isopropamide iodide

Mepenzolate bromide

Methantheline bromide

Pipenzolate bromide

Pralidoxime chloride

Propantheline bromide

Thihexinol methylbromide

Tridihexethyl iodide •

"Tertiary amines (except tropane derivatives):

Adiphenine hydrochloride

Caramiphen edisylate

Cycrimine hydrochloride

Dicyclomine hydrochloride

Ethopropazine

Orphenadrine citrate

Orphenadrine hydrochloride

Oxyphencyclimine hydrochloride

Piperidolate hydrochloride

Thiphenamil hydrochloride

Trihexyphenidyl hydrochloride

Tropane derivatives :

Anisotropine methylbromide

Benztropine mesylate

Homatropine

Homatropine hydrobromide

Homatropine methylbromide

Parasympathomimetic (cholinergic) agents:

Acetylcholine chloride

Methacholine chloride

Neostigmine bromide

Physostigmine salicylate ;

Pyridostigmine bromide

Sympatholytic (antiadrenergic) agents:

Ergonovine maleate

Hydralazine hydrochloride

Tolazoline hydrochloride

"Sympathomimetic (adrenergic) agents:

Adrenalone

Arterenol hydrochloride (racemic)

Cinnamylephedrine

Cyclopentamine hydrochloride

"Epinephrine salts :

Epinephrine bitartrate (levo)

Epinephrine hydrochloride (racemic)

"Isoproterenol salts :

Isoproterenol hydrochloride

Isoproterenol sulfate

Manufacturers ' identification codes (according to list in table 22)

ABB, LEM.

ICO.

AST, LEM.

WYT.

CAN, SDW.

LIL.

ABB.

ABB.

ABB, LEM.

QMS.

ICO.

EN.

SDW.

ICO, SDW.

ICO.

SCH.

ABB.

SK.

LKL.

SRL.

LKL.

NEP.

SRL.

SCH.

ACY.

CBP.

SK.

LIL.

BKC.

NEP.

RIK.

RIK.

PFZ.

LKL.

x.

ACY, SDW.

CTN, HEX.

CTN.

CTN, EN, HEX.

MRK.

MRK, RSA. HEX. PEN. HOF.

LIL. CBP.

CTN.

SDW. SDW. SDW. LIL.

SDW. DOD, VB.

GAN, SDW. ABB, GAN, SDW.

MEDICINAL CHEMICALS

121

TABLE 13B — Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, i565--Continued

Manufacturers' identification codes (according to list in table 22)

"Autonomic drugs — Continued

"Sympathomimetic (adrenergic) agents — Continued

Levarterenol bi tartrate

dl-Metanephrine hydrochloride

Metaraminol bitartrate

Methoxyphenamine hydrochloride

Naphazoline hydrochloride

dl-Nonnetanephrine hydrochloride

Nylidrin hydrochloride

"Phenylephrine base and salts :

Phenylephrine

Phenylephrine bitartrate

"Phenylephrine hydrochloride

Phenylephrine tannate

"Phenylpropanolamine hydrochloride

Propylhexedrine

Protokylol hydrochloride

Pseudoephedrine hydrochloride

Pseudoephedrine sulfate

Tetrahydrozoline hydrochloride

"Cardiovascular agents : Antihypertensive agents :

Alkavervir

Alseroxylon

Deserpidine

Methyldopa

Pargyline hydrochloride

Reserpine

Bioflavonoids :

Hesperidin

Hesperidin methyl chalcone

Lemon bioflavonoid

Naringin

Rutin

Cardiac drugs:

Calcium camphor sulfonate

Digi toxin

Procainamide hydrochloride

Quinidine gluconate

"Vasodilators :

Clonitrate

Dioxyline phosphate

Ethyl nitrite

Isosorbide dinitrate

Mannitol hexanitrate

Nicotinyl alcohol tartrate

Nitroglycerin

Pentaerythritol tetranitrate

"Central depressants :

"Analgesics and antipyretics: "Salicylates :

Aluminum aspirin

"Aspirin

Ethyl salicylate carbonate

Phenyl salicylate

Potassium salicylate

Salicylamide

Salicylsalicylic acid

Sodium salicylate

Strontium salicylate

"Other analgesics and antipyretics :

Acetaminophen

Acetanilide

p-Aminobenzoic acid and salts:

Aminobenzoic acid

Calcium aminobenzoate

Magnesium aminobenzoate

Potassium aminobenzoate

Sodium aminobenzoate

Anileridine hydrochloride

Calcium succinate

Colchicine

SDW.

SDW.

SDW.

X.

CBP, SDW.

SDW.

X.

CTN, GAN,

SDW.

GAN.

CTN, GAN,

HEX,

SDW.

CTN.

BKL, GAM,

GAN,

ICO, NEP, ORT

HEX, SK.

LKL.

BUR, GAN.

GAN.

PFZ.

PEN, RIK.

RIK.

PEN.

MRK.

ABB.

PEN.

SKG.

SKG.

SKG.

SKG.

PEN.

FIN, PYL.

BUR.

OMS.

HEX.

APD.

LIL.

MAL.

APD.

APD.

HOF.

APD.

APD.

ABB, SCH.

CFC, DOW,

MLS,

MON, NOR, SDG.

PD.

DOW, MAL.

HN, PEN.

CFC, x.

TNC.

DOW, HN.

MAL, TNC.

ATP, MLS,

NEP,

X.

CTN.

LEM.

LEM, x.

LEM.

GAN, LEM.

GAN, LEM.

MRK.

LEM.

PEN.

122

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 13B.

-Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manuf aoturers ' identification codes (according to list in table 22)

^Central depressants — Continued ^Analgesics and antipyretics — Continued

Other analgesics and antipyretics — Continued

Dipyrone

Ethoheptazine citrate

Meperidine hydrochloride

Oxycodone hydrochloride

Oxymorphone hydrochloride

Oxyphenbutazone

Phenacetin

Phenylbutazone

1-Phenylsemicarbazide

Phenyramidol hydrochloride

Propoxyphene hydrochloride

Propoxyphene napsylate

* Anticonvulsants , hypnotics, and sedatives: Anticonvulsants (except barbiturates) :

Aminoglutethimide

Diphenylhydantoin

Diphenylhydantoin, sodium

Ethosuximide

Ethotoin

Methsuximide

Paramethadione

Phenacemide

Phensuximide

Trimethadione

*Barbiturates :

5-Allyl-5-(2-cyclopenten-l-yl)barbituric acid

Amobarbital

Amobarbital, sodium

Barbital

Barbital, sodium

*Butabarbital

*Butabarbital, sodium

Butalbital

Butalbital, sodium

Cyclobarbital, calcium

Hexobarbital

Mephobarbital

Methohexital, sodium

Pentobarbital

Pentobarbital, sodium

Phenobarbital

*Phenobarbital, sodium

Secobarbital

Secobarbital, sodium

Talbutal

Thiamylal, sodium

Thiopental, sodium

Vinbarbital

Hypnotics and sedatives (except barbiturates):

Acetylcarbromal

Carbromal

Ethchlorvynol

Ethinamate

Glutethimide

Methyprylon

*Skeletal muscle relaxants :

Carisoprodol

Chlorphenesin carbamate

Chlorzoxazone

*Mephenesin

Mephenesin carbamate

Phenaglycodol

Styramate

*Succinylcholine chloride

Tubocurarine

^Tranquilizers :

Azacyclonol hydrochloride

Buclizine hydrochloride

Chlordiazepoxide hydrochloride

SDW.

WYT.

SDW,

EN.

EN.

GGY.

DOW,

GGY.

RSA.

OTC.

LIL.

LIL.

CBP. PD.

ABB.

PD.

ABB.

GAN.

LIL.

GAN,

GAN.

GAN.

ABB,

ABB,

GAN.

GAN.

SDW.

GAN,

SDW.

LIL.

ABB,

ABB,

BPC,

BPC,

GAN.

GAN,

SDW.

PD.

ABB.

MLS. MLS, ABB. LIL. CBP. HOF.

UPJ. OTC. BKL, OMS. LIL. AEP. ABB, ABB,

BKC. PFZ. HOF.

BPC, GAN. BPC, GAN.

BPC, GAN. BPC, GAN. GAN, MAL. GAN, MAL, SDW.

LIL.

HEX, OMS.

BUR, SDW. OMS.

MEDICINAL CHEMICALS

123

TABLE 13B.

-Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Manufacturers' identification codes (according to list in table 22)

♦Central depressants — Continued ♦Tranquilizers — Continued

Chlormezanone

Chlorprothixene

Diazepam

Ethoxybutamoxane hydrochloride

Hydroxyphenamate

Hydroxyzine hydrochloride

Hydroxyzine pamoate

Mebutamate

Mephenoxalone

♦Meprobamate

Methaqualone

Oxazepam

*Phenothiazine derivatives :

Carphenazine maleate

Chlorpromazine hydrochloride

Fluphenazine hydrochloride

Mepazine hydrochloride

Perphenazine

Prochlorperazine maleate

Promazine hydrochloride

Promethazine hydrochloride

Trifluoperazine hydrochloride

Triflupromazine hydrochloride

Tybamate

*Other central depressants : Anesthetics :

Tribromoethanol

Vinyl ether

Antitussives:

Benzonatate

Carbetapentane citrate

Dextromethorphan hydrobromide

Dimethoxanate hydrochloride

*Ethylmorphine hydrochloride

Hydrocodone bitartrate

♦Central stimulants : * Amphetamines :

♦Amphetamine, dextroamphetamine and levamphetamine base and salts :

Amphetamine (racemic)

Amphetamine hydrochloride (racemic)

Amphetamine sulfate (racemic)

Dextroamphetamine

Dextroamphetamine carboxymethylcellulose

Dextroamphetamine hydrochloride

♦Dextroamphetamine sulfate

Dextroamphetamine tannate

Levamphetamine succinate

♦Methamphetamine base and hydrochloride:

Methamphetamine (dextro)

Methamphetamine (levo)

♦Methamphetamine (racemic)

♦Methamphetamine hydrochloride (dextro)

Methamphetamine hydrochloride (racemic)

♦Antidepressants :

Amitriptyline

Desipramine hydrochloride

Isocarboxazid

Nialamide

Nortriptyline

Phenelzine sulfate

♦Caffeine :

Natural

Synthetic

♦Other central stimulants:

Benzphetamine hydrochloride

Caffeine, citrated

Caffeine sodium benzoate

Chlorphentermine hydrochloride

Diethylpropion hydrochloride

SDW.

HOF.

HOF.

LIL.

ARP.

PFZ.

PFZ.

x.

ACY.

ABB, BKL, PEN, TBK.

HEX, x.

WYT.

WYT.

SK.

0M3, SCH.

NEP.

SCH.

SK.

WYT.

WYT.

SK.

CMS.

PEN, x.

SDW. MRK.

CBP. PFZ. HOF. x.

MAL, MRK, PEN. EN, MAL, MRK.

HEX,

ORT.

HEX.

AM,

HEX,

SK.

HEX.

ARN.

ARN,

HEX.

ARN,

HEX,

SK.

ARN.

ARN.

HEX.

ABB.

ARN,

HEX,

OTC.

ABB,

ARN,

GAN, HEX

ARN,

CAN,

HEX.

MRK.

GGY,

LKL.

HOF.

PFZ.

LIL.

NEP.

GNF,

MYW.

MON,

PFZ.

x.

MAL,

MRK.

MAL.

NEP.

BKC,

x.

124

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1965 — Continued

Manuf aeturers ' identification codes (according to list in table 22)

*Central stimulants — Continued

"Other central stimulants — Continued

Nikethamide

Phendimetrazine tartrate

Phenmetrazine hydrochloride

Phentermine

Sodium succinate

"Dermatological agents :

"Allantoin

"Bismuth subgallate

*Salicylic acid

■"Other dermatological agents :

Aluminum phenolsulfonate

Ammonium phenolsulfonate

Dipropylene glycol salicylate

Glycol salicylate

Homomenthyl salicylate

p-Methoxycinnamie acid, 2-ethoxyethyl ester

Podophyllum resin

Scarlet red

Sodium phenolsulfonate

Zinc phenolsulfonate

■"■Expectorants and mucolytic agents:

Ethylenediamine dihydriodide

Glyceryl guaiacolate

Guaiacol

Iodinated glycerol

Lobeline sulfate

Terpin hydrate

Thonzonium bromide

"Gastrointestinal agents :

"Choleretics and hydrocholeretics :

Bile acids, oxidized

Dehydrocholic acid

Florantyrone

Iron bile salts

Qx bile extract

Sodium dehydrocholate

Tocamphyl

"Choline chloride (all grades):

Feed grade

Medicinal grade

Technical grade

"Methionine and its hydroxy analogue :

Methionine (feed grade)

Methionine (medicinal grade)

Methionine, hydroxy analogue, calcium salt-- "Other gastrointestinal agents :

Betaine base

Betaine hydrate

Betaine hydrochloride

Calcium polycarbophil

Choline bicarbonate

Choline bi tartrate

Choline citrate (Tricholine citrate)

Choline dihydrogen citrate

Dihydroxy aluminum aminoacetate

Magnesium citrate

Pectin

Phenolphthalein

Phenolphthalein, yellow

Sitosterols

Sodium carboxymethylcellulose

Sodium tartrate

"Hormones and synthetic substitutes : "Corticosteroids :

Betamethasone

Betamethasone acetate

Betamethasone phosphate

Cortisone

Cortisone acetate

Dexamethasone

GGY.

HEX.

MAL.

CTN,

FIN, HFT.

BKC,

MAL, PEN.

DOW,

HN, M)N, SDH.

MAL.

SAL.

SBC.

RDA.

ICO.

GIV.

ABB,

PEN.

NAC.

MAL,

SAL.

MAL.

BKC,

PYL, WHL.

BKL,

GAM, ICO, OTC, x

HN,

M)N.

X, X

ABB.

LEM,

PEN.

NEP.

SRL,

WIL.

WIL.

SRL.

LIL.

COM,

DLI,

HFT, TMH

CFC,

HFT.

G, RH.

DOW.

DOW,

LEM.

DUP,

MON.

HFT,

MAL.

HFT.

HFT.

WLI.

COM.

ACY,

CFC,

HFT.

ACY,

CFC,

HFT.

ACY,

CFC,

HFT.

CHT.

MAL.

SKG-

MON.

WLI.

UPJ.

CBP.

MAL.

SCH.

SCH.

SCH.

MRK.

MRK,

SCH,

UPJ.

MRK,

SCH.

MEDICINAL CHEMICALS

125

TABLE 13B. — Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Hormones and synthetic substitutes — Continued * Corticosteroids — Continued

Dexamethasone acetate

Dexamethasone phosphate

Dichlorisone acetate

Fludrocortisone acetate

Fluorometholone

Fluprednisolone

Hydrocortamate hydrochloride

^Hydrocortisone

Hydrocortisone acetate

Hydrocortisone phosphate

Indomethacin

Methylprednisolone

Prednisolone

Prednisolone acetate

Prednisone

Triamcinolone

*Estr:>gens:

ChLorotrianisene

Dienestrol diacetate

Diethylstilbestrol

Natural estrogenic substances

Piperazine estrone sulfate

*Synthetic hypoglycemic agents :

Aeetohexamide

Chlorpropamide

Phenformin hydrochloride

Tolazamide

Tolbutamide

«Othef hormones and synthetic substitutes: Androgens :

Fluoxymesterone

Testosterone cypionate

Antithyroid agents :

Jfetliimazole

Propylthiouracil

Thiouracil

Progestogens :

Medroxyprogesterone acetate

Norethynodrel

Progesterone

All other:

Corticotropin (ACTH) (pituitary)

Insulin (pancreas)

*Renal-acting and edema-reducing agents : *Mercurial diuretics:

Meralluride

Mersalyl acid

Sodium mercaptomerin

Sodium mercurophylline

^Theobromine and theophylline derivatives :

Ambuphylline

*Aminophylline

Aminophylline sodium biphosphate

Oxtriphylline

Theobromine sodium salicylate

Theophylline magnesium

Theophylline monoethanolamine

Theophylline sodium acetate

*Other renal-acting and edema-reducing agents :

Acetazolamide

Benzothiadiazine derivatives :

Bendroflumethiazide

Benzthiazide

Chlorothiazide

Cyclothiazide

Flumethiazide

Hydrochlorothiazide

Hydroflumethiazide

Manufacturers ' identification codes (according to list in table 22)

SCH. MRK. SCH. UP J. UP J. UP J. PFZ. MRK, MRK, MRK. MRK. UPJ. MRK, SCH, MRK, ACY,

BKC. SCH. CTN, ORG. ABB.

LIL. PEZ.

HST, x.

PFZ, UPJ. PFZ, UPJ.

SCH, UPJ. UPJ.

SCH, UPJ. OMS.

UPJ. UPJ.

LIL. PYL. ACY.

ARP, ARP,

LKL. SDW. WYT. FIN.

GAN. GAN, GAN. NEP. CLC. MAL. LIL. MAL.

ACY.

OMS. PFZ. MRK. LIL. OMS. ABB, OMS.

ORG, WIL. LIL.

LEM, SRL.

CBP, MRK.

126

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 13B.

-Medicinal chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

*Renal-acting and edema-reducing agents — Continued

*Other renal-acting and edema-reducing agents — Continued Benzothiadiazine derivatives — Continued

Polythiazide

Trichlorme thiazide

Chlorthalidone

Dichlorphenamide

Probenecid

Spironolactone

Triamterene

*Therapeutic nutrients : *Amino acids and salts :

Acetyltryptophane

Aminoacetic acid (glycine)

Amino acid mixtures

Arginine glutamate

Aspartic acid and salts :

Aspartic acid

Magnesium aspartate

Potassium aspartate

Beta-alanine

Glutamic acid and salts :

Ammonium glutamate

Calcium gluxamate

^Glutamic acid

Glutamic acid hydrochloride

Potassium glutamate

lysine (feed grade)

lysine hydrochloride

dl- Phenylalanine

dl- Tryptophane

*Caleium gluconate

«Other therapeutic nutrients :

Calcium glucoheptonate

Calcium lactophosphate

Calcium levulinate

Calcium phytate

Copper gluconate

Ferrous gluconate

Fructose

Lecithin

Liver concentrate

Liver, desiccated

Magnesium gluconate

Manganese gluconate

Potassium gluconate

Sodium glycerophosphate

*Vitamins :

*Ascorbic acid and derivatives :

* Ascorbic acid

Ascorbyl palmitate

Calcium ascorbate

Sodium ascorbate

B-complex vitamins : *Cyanocobalamin (all grades):

Feed grade

Medicinal grade

U.S. P. crystalline

*Niacin (all grades):

Feed grade

Medicinal grade

^Niacinamide

*Pantothenic acid and derivatives:

Calcium pantothenate (dextro)

*Calcium pantothenate (racemic) (all grades):

Feed grade

Medicinal grade

Calcium pantothenate (racemic) - calcium chloride

complex. Dexpanthenol

PFZ.

SCH.

GGY. MRK.

MRK. SRL.

SK.

SDW.

BPC,

DOW.

ABB,

CUT,

STA.

ABB.

HEX,

NAC.

WIT.

WYT.

BFG,

NOP.

IMC.

LEM.

IMC,

LEM,

PFZ.

IMC,

LEM.

IMC,

LEM,

PFZ.

MRK.

MRK.

SDW.

SDW.

MAL,

PFZ,

WHL.

PFN.

MAL.

SEL.

STA.

PFZ.

PFZ,

SDW.

DLL

ARP.

WIL.

WIL.

PFZ.

PFZ.

PFZ.

SEL.

HOF,

MRK,

PFZ.

PFZ.

PFZ.

HOF,

MRK,

PFZ.

GPR,

MRK,

PMP.

IMC,

MRK.

MRK.

ABB,

CKL,

MRK, NEP, RIL

MRK,

NOP,

RIL, SCR.

MRK,

NEP,

PD, RIL, SCR.

DLI, MRK, x.

CKL, FLM, HFT, NOP.

NOP.

NOP.

MEDICINAL CHEMICALS

127

TABLE 13B. —Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

*Vitamins — Continued

B-ooraplex vitamins — Continued •Pantothenic acid and derivatives — Continued

Panthenol (racemic)

Sodium pantothenate

*Ribof lavin ( all grades ) :

Feed grade

Medicinal grade

•Cholecalciferol (Vitamin D3)

•Ergocalciferol (Vitamin D2)

*Menadione

•Menadione sodium bisulfite

•Vitamin A alcohol and esters :

Vitamin A acetate (feed grade)

Vitamin A acetate (medicinal grade)

Vitamin A alcohol

Vitamin A natural esters

•Vitamin A palmitate (feed grade)

Vitamin A palmitate (medicinal grade)

Other vitamins :

d-Alpha tocopherol

dl-Alpha tocopherol

d-Alpha tocopheryl acetate

dl-Alpha tocopheryl acetate

d-Alpha tocopheryl acid succinate

Beta-carotene (Provitamin A)

Biotin

Cyanocobalamin with intrinsic factor concentrate-

Folic acid

Inositol

Magnesium nicotinate

Niacinamide hydrochloride

Phytonadione

Pyridoxine

Riboflavin-5-phosphate, sodium

Sodium nicotinate

Thiamine hydrochloride

Thiamine mononitrate

•Miscellaneous medicinal chemicals : Diagnostic agents :

Roentgenographs contrast media:

Acetrizoate, sodium

Diatrizoate, meglumine

Diatrizoate, sodium

Diprotrizoate, sodium

Iodihippurate, sodium

Iodopyracet

Iopanoic acid

Iophendylate

Iothalamate, meglumine

Iothalamate, sodium

Methiodal, sodium

Other diagnostic agents :

Galactose (liver function test)

Indocyanine green (cardiac output test)

Metyrapone (pituitary function test)

Hematological agents: •Anticoagulants :

Ammonium heparin

Anisindione

Bishydroxycoumarin

Phenindione

Potassium heparin

Sodium heparin

Sodium warfarin

Other hematological agents :

Aminocaproic acid

Cellulose, oxidized

Dextran (plasma expander)

Smooth muscle relaxants :

Alverine

Alverine citrate

Manufacturers ' identification codes (according to list in table 22)

HOF. PD.

COM, GPR, HOF, MRK, PMP.

HOF, MRK.

CW, DLI, NOP, VTM.

CW, DLI, SCR, VTM.

ABB, HET, HFT, WHL.

ABB, HET, HFT, WHL.

HOF.

CW, HOF, PFZ.

CW, HOF.

CW.

EK, HOF, PFZ.

EK, HOF, PFZ.

CW, EK.

HOF.

CW, EK.

HOF.

CW, EK, HOF.

HOF.

HOF.

WIL.

ACT.

STA.

NEP.

NEP.

MRK.

HOF, MRK.

HOF.

MRK, NEP.

HOF, MRK.

HOF, MRK.

MAL.

SDW.

SDW.

MAL.

MAL.

SDW.

SDW.

x.

MAL.

MAL.

SDW.

WIL.

SCH.

ABB, FIN.

CTN, GAN, WIL.

WIL.

ABB, RIK.

EN.

ACT. EKT. PHR.

CTN. CTN.

128

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 13B.— Medicinal chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1965 — Continued

Chemical

Manufacturers ' identification codes (according to list in table 22)

^Miscellaneous medicinal chemicals—Continued anooth muscle relaxants — Continued

era.

LIL.

ICO. ABB, PEN.

Other miscellaneous medicinal chemicals :

PEN.

ttydrastme hydrocnior de

FLAVOR AND PERFUME MATERIALS

129

Flavor and Perfume Materials

TABLE 14B. — Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer, 1965

[ Flavor and perfume materials for which separate statistics are given in table 14A are marked below with an asterisk (*); those not so marked do not appear in table 14A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Material

Manufacturers' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC

Benzenoid and Naphthalenoid

2 '-Acetonaphthone (Methyl fi-naphthyl ketone)

Aeetophenone

7-Acetyl-6-ethyl-l,l,4,4-tetramethyl-l,2,3,4-tetrahydro- naphthalene .

p-Allylanisole

Allyl phenoxyacetate

*4-Allylveratrole (Eugenyl methyl ether)

p-tert-Amylcyclohexanone

*Anethole (p-Propenylanisole)

p-Anisaldehyde (p-Methoxybenzaldehyde) ■

Anisole (Methyl phenyl ether)

Anisyl acetate

Anisyl alcohol

*Benzophenone

*Benzyl acetate

*Benzyl alcohol

Benzyl behzoate

Benzyl butyrate

*Benzyl cinnamate

Benzyl ether

Benzyl formate

Benzyl glyceryl acetal

Benzyl isobutyrate

Benzyl isoeugenyl ether

Benzyl isopentyl ether

Benzyl phenylacetate (Benzyl a-toluate)

*Benzyl propionate

*Benzyl salicylate

a -Bromostyrene

4' -tert-Butyl-2 ', 6' -dimethyl-3 ' , 5 '-dinitroacetophenone

(Musk ketone ) . 6-tert-Butyl-3-methyl-2,4-dinitroanisole (Musk ambrette)-- p-tert -Butyl-a -methylhydrocinnamaldehyde ( a-Methyl-f! - ( p-

tert -butylpheny 1 ) propionaldehyde ) . 5-tert-Butyl-l,2,3-trimethyl-4.,6-dinitrobenzene (5-tert- Butyl-4, 6-dinitrohemi mellitene ) .

5-tert-Butyl-2,4,6-trinitro-m-xylene (Musk xylol)

Carvacrol (2-p-Cymenol)

*Cinnamaldehyde

Cinnamic acid

Cinnamyl acetate

*Cinnamyl alcohol

Cinnamyl anthranilate

Cinnamyl cinnamate

Cinnamyl formate

Cinnamyl isovalerate

Cinnamyl propionate

trans-Decahydro-2-naphthol

p ,<* -Dimethylbenzyl alcohol (p-Methylphenylmethylcarbinol)-

ajx -Dimethylphenethyl acetate

<x,a -Dimethylphenethyl alcohol

ccyx -Dimethyl -3-phenyl-l-propanol

4,6-Dinitro-l,l,3,3,5-pentamethylindan

Diphenylmethane

l,3-Diphenyl-2-propanone (Dibenzyl ketone)

l-Ethoxy-2-hydroxy-4-propenylbenzene

2-Ethoxynaphthalene (Ethyl p-naphthyl ether)

Ethyl anisate

Ethyl anthranilate

Ethyl benzoate

FB, GIV, TBK. GIV, TBK. GIV.

GIV.

GIV.

FB, GIV, ICO.

IFF.

ARZ, GLD, HNW, HPC.

GIV, OPC, SHL, TBK, UNG.

GIV.

GIV, TBK.

GIV, TBK.

G, GIV, ICO, NEO, TBK.

GIV, OPC, SHL, TBK, TNP.

BPC, GIV, OPC, SHL, TBK, TNP.

MON, TBK, TNP.

FB, GIV, TBK.

FB, GIV, ICO, TBK.

OPC, SHL, TNP.

TBK.

GIV.

TBK.

GIV, TBK.

GIV.

GIV, TBK.

FB, GIV, TBK.

GIV, ICO, OPC, TBK, UNG.

TBK.

GIV, TBK.

GIV. GIV.

GIV.

GIV.

GIV.

FB, OPC, TBK.

BPC, ICC.

FB, GIV, TBK.

FB, GIV, NEO, TBK.

FEL, GIV, RT.

TBK.

TBK.

TBK.

GIV, TBK.

IFF.

GIV, TBK.

GIV, IFF.

GIV, IFF.

IFF.

GIV.

TBK.

GIV, TBK.

SHL.

GIV.

ICO.

FB.

TBK.

130

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 14B.

-Flavor and perfume materials for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Manufacturers ' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued

Pen

id and haphthalenoid--Continued

Ethyl cinnamate

Ethyl a,|3-epoxy-(j-methylhydrocinnamate

Ethyl eugenol

2-Ethylhexyl salicylate

Ethyl phenylacetate

Ethyl 3-phenylglycidate

Ethyl salicylate

Ethylvanillin

*Eugenol

Eugenol acetate

Hexylcinnamaldehyde

Hydratropaldehyde (x -Phenylpropionaldehyde )

Hydratropaldehyde, dimethyl acetal

Hydrocinnamaldehyde (p -Phenylpropionaldehyde)

Hydroxycitronellal methyl anthranilate

2-Hydroxypropyl p -N , N -bis ( 2 -hydroxypropyl ) aminobenzoate •

Isobutyl cinnamate

*Isobutyl phenylacetate (Isobutyl a-toluate)

*Isobutyl salicylate

*Isoeugenol

Isoeugenyl acetate

*Isopentyl salicylate (Amyl salicylate)

p-Isopropylbenzaldehyde ( Cumaldehyde )

p-Isopropylcyclohexanol

*p-Isopropyl-a-methylhydrocinnamaldehyde ( Cyclamen aldehyde ) .

4' -Methoxyacetophenone

2-Methoxynaphthalene (Methyl p -naphthyl ether)

4-(a-Methoxyphenyl)butanone

l-(p-Methoxyphenyl)-l-pentene-3-one

4' -Methylacetophenone (Methyl p-tolyl ketone)

Methyl anisate

p-Methylanisole (p-Cresyl methyl ether)

*Methyl anthranilate

Methyl benzoate

p-Methylbenzyl acetate

a-Methylbenzyl acetate

a-Methylbenzyl alcohol (Methylphenyl carbinol)

*a-Methylcinnamaldehyde

*Methyl cinnamate

4-Methyl-7-ethoxy coumarin

p-Methyl hydratropic aldehyde

Methyl N-methylanthranilate (Dimethyl anthranilate)

Methyl phenylacetate (Methyl o-toluate)

*Methyl salicylate (Synthetic wintergreen oil)

*a-Pentylcinnamaldehyde (a -Amylcinnamaldehyde)

*Phenethyl acetate

Phenethyl alcohol

Phenethyl formate

*Phenethyl isobutyrate

Phenethyl isovalerate

*Phenethyl phenylacetate (Phenethyl a-toluate)

Phenethyl propionate

Phenethyl salicylate

2-Phenoxyethyl isobutyrate

Phenylacetaldehyde (a-Tolualdehyde)

Phenylacetaldehyde, dimethyl acetal

Phenylacetaldehyde, ethylene acetal

o-Phenylanisole (2-Methoxybiphenyl)

4-Phenyl-3-buten-2-one

Phenyl ethyl acetal

Phenylethyl tiglate

*3-Phenyl-l-propanol (Hydrocinnamic alcohol)

3-Phenyl-l-propyl acetate

5-Propenyl-2-ethoxyphenol (Propenylguaethol)

4- Propenylveratrole (Isoeugenyl methyl ether)

p-Propylanisole

TBK. TBK.

ICO. TBK.

GIV,

GIV,

ICO.

FEL,

GIV.

GIV,

TBK.

MON, RDA.

FB, GIV, ICO, LUE, NEO, PEN, RT, TBK, UNG, VLY.

GIV.

GIV,

GIV,

GIV,

GIV.

GIV.

SHL.

TBK.

FB,

FB,

GIV,

TBK.

FB,

GIV.

GIV.

GIV,

IFF, TBK.

IFF.

IFF.

GIV, TBK. GIV, TBK. SHL, TBK, VLY.

GIV, ICO, OPC, SHL, TBK. OPC, RDA.

GIV, ICO.

GIV.

TBK.

GIV.

TBK.

ICO.

GIV;

FB,

HN.

ICO.

FB, GIV, VLY.

TBK.

FB,

FB,

GIV,

GIV,

GIV.

GIV.

CFC

FB,

GIV.

GIV.

IFF

GIV,

FB,

FB,

GIV,

NEO,

GIV.

GIVj

GIV,

GIV.

GIV.

FB.

GIV.

FB.

FB,

FB,

ICO.

GIV,

GIV.

OPC. GIV, MEE, OPC, SHL, UNG.

GIV, TBK, VLY. ICO, TBK.

OPC, TBK, D0W;

GIV, IFF. IFF, TBK. IFF,

GIV.

GIV,

TBK. TBK. TBK. TBK.

HN, MON, PEN. IFF, NEO, RDA, TBK, VLY. NEO. OPC.

TBK.

IFF, TBK.

GIV, TBK. GIV.

ICO, TBK.

FLAVOR AND PERFUME MATERIALS

131

TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer , 2965--Continued

Manufacturers ' identification codes (according to list in table 22)

FLAVOR AND PERFUME MATERIALS, CYCLIC— Continued Benzenoid and Naphthalenoid— Continued

n-Propyl phenethyl acetal

p-Tolualdehyde (p-Methylbenzaldehyde)

p-Tolyl acetate (p-Cresyl acetate)

p-Tolyl phenylacetate (p-Cresyl a-toluate)

a-(Trichloromethyl)benzyl acetate (Rosetone)

Trimethyltetrahydrobenzylidene acetone

Vanillin

All other

Terpenoid, Heterocyclic, and Alicyclic

Allyl eyclohexyl propionate

Allyl ionone

Amyris acetate

Bornyl acetate

4-tert-Butyleyclohexanol

4-tert-Butylcyclohexyl acetate

Cadinene

Carvone (Carvol)

Caryophyllene

Cedranone

Cedrenol

Cedrol

*Cedryl acetate

*Citral (Geranial)

Citral dimethyl acetal

Citronellal

*Citronellol

*Citronellyl acetate

Citronellyl butyrate

*Citronellyl formate

Citronellyl isobutyrate

Citronellyl oxyacetaldehyde

Citronellyl propionate

*Coumarin

Cyclohexadecanolide

Cyclohexylcyclohexanone :

Cyclopentanone

Dihydrogeraniol

Dihydroterpinyl acetate

^Essential oils, chemically modified:

Citronella oil, acetylated

Clove leaf oil terpenes

Ethyl oxyhydrate

Gualacwood acetate

Lavandin, acetylated

Oil clove stem, acetylated

Sassafras oil, hydrogenated

Other

a-Furfural mercaptan

*Geraniol

Geranoxy acetaldehyde

*Geranyl acetate

Geranyl benzoate

Geranyl butyrate

Geranyl formate

Geranyl isobutyrate

Geranyl isovalerate

Geranyl phenylacetate (Geranyl a-toluate)

2-Hexyl-2-cyclopenten-l-one

Hydrocoumarin (3,4— Dihydrocoumarin)

*Hydroxyeitronellal

Hydroxycitronellal, dimethyl acetal

4-(4-Hydroxy-4-methylpentyl)-3-eyelohexene-l-carboxalde-

hyde. Indole

GIV.

HN.

GIV, IFF.

GIV.

ICO, TBK.

TBK.

MON, SLV.

FB, GIV, IFF, PFW, FDA, SHL.

GIV.

GIV,

GIV,

FEL.

IFF.

DOW,

FB.

FB,

FB,

TBK

GIV

GIV

GIV

FB,

GIV

FB,

FB,

GIV

GIV

FB,

GIV,

IFF.

GIV,

DOW,

IFF.

GIV.

AHA.

ICO.

GIV.

CP,

SHL.

FEL,

FB,

FEL.

FB.

GIV.

BPC.

RT.

FB,

IFF.

FEL.

GIV,

GIV,

GIVl

IFF.

FB.

GIV.

IFF.

GIV.

giv!

GIV!

iff!

IFF. TBK.

FRM, OPC. GIV.

IFF, TBK.

IFF, NEO, TBK, UNG. FEL, GIV, LUE, MYW, NEO, RT, TBK.

GIV, IFF, TBK.

GIV, GLD, IFF, NEO, TBK, VLY. IFF, TBK, VLY.

GIV, IFF, TBK, VLY. IFF, TBK.

i, NEO, RDA, TBK.

FLO, LUE, VND. GIV, TBK. GIV, UNG.

FEL, GIV, GLD, IFF, NEO, TBK, UNG, VLY. GIV, IFF, TBK, VLY.

TBK.

IFF, TBK, VLY.

ICO.

GLD, IFF, OPC, TBK, VLY.

OPC, TBK.

DOW, GIV.

132

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 14B. --Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer , 1 965 --Continued

Material

FLAVOR AND PERFUME MATERIALS, CYCLIC--Continued Terpenoid, Heterocyclic, and Alicyclic--Continued

*Ionones :

a-Ionone

(3-Ionone

Ionone (a- andp-)

Isoborneol (Isobornyl alcohol)

*Isobornyl acetate

Isobutylquinoline

Isomenthone

Isopropylquinoline

Isopulegol

Isosafrole

Laevo carveol

d-Limonene

Llnalool

Linalyl acetate

Linalyl anthranllate

Linalyl isobutyrate

Linalyl propionate

l,l-p-Menthen-6-yl-l-propanone

*Menthol, synthetic:

Tech

U.S.P

Menthone

Menthyl acetate

6-Methylcoumarin

*Methylionones :

Methyl-a-ionone

Methyl-fJ-ionone

Methylionone (a- and fj-)

Methyl-Y -ionone

Methyl-5-ionone

*Nerol

Nerol, acetate

Nopyl acetate

Phellandrene

*Piperonal (Heliotropin)

Piperonal, sodium bisulfite complex

Piperonal terpenes

Pseudolinalyl acetate (Myrcenyl acetate, principally) -

*Rhodinol

Rhodinyl acetate

Safrole

Santalol

Santalyl acetate

♦Sweeteners , synthetic :

Cyclohexanesulfamic acid

Cyclohexanesulfamic acid, calcium salt

Cyclohexanesulfamic acid, sodium salt

Saccharin

Saccharin, calcium salt

Saccharin, sodium salt

All other

*Terpineols:

a-Terpineol

P-Terpineol

Terpineol (a- andg-)

Terpinol hydrate (Terpin hydrate ) , tech

*Terpinyl acetate

Terpinyl propionate

Tetrahydro alloocimenol

3,5,5-Trimethylcyclohexanol

Vertofix (Acetyl cedrene, principally)

Vetivenol

*Vetivenyl acetate

All other

Manufacturers ' identification codes (according to list in table 22)

GIV, IFF, LUE, MYW, TBK.

MYW, TBK.

GIV, LUE, MYW, NEO.

RDA.

FB, GIV, OPC, RDA.

IFF.

FB, GIV, TBK.

FMT.

GIV, TBK.

GIV.

FB.

RT, SKG.

FB, FEL, GIV, GLD, HOF, LUE, NEO, SHL, TBK, UNG.

DOW, FB, GIV, GLD, HOF, LUE, SHL, UNG.

FMT.

GIV, TBK.

FB, GIV.

GIV.

GIV, ICO, NEO. GIV, HNW, NEO. GIV, HNW, NEO. FB, GIV. GIV.

GIV, IFF, MYW.

IFF, NEO.

GIV, LUE, MYW, VLY.

TBK.

TBK.

FB, GIV, GLD, IFF, TBK, VLY.

FB, GIV.

MYW, SHL, TBK, VLY.

GIV, ICO.

GIV, SHL, TBK.

SHL.

SHL.

IFF.

FB, FEL, GIV, IFF, LUE, NEO, SHL.

FB, GIV, IFF.

GIV.

GIV, IFF.

GIV.

ABB, NRS.

ABB, CYC, DRW, MDN, NRS, PBY, PFZ, UNS.

ABB, DRW, MON, NRS, PBY, PFZ, UNS.

MEE, M3N, NRS.

MEE, MON, NRS, PBY.

MEE, MON, NRS.

VLY.

GLD, HNW, HPC.

HNW.

GIV, NEO.

HPC.

GIV, NEO, OPC, RDA, TBK, UNG.

GIV, TBK.

IFF.

ICO.

IFF.

GIV, TBK.

FB, GIV, IFF, NEO, TBK.

FB, GIV, IFF, OPC, RDA, TBK.

FLAVOR AND PERFUME MATERIALS 133

TABLE 14B. -- Flavor and perfume materials for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

FLAVOR AND PERFUME MATERIALS, ACYCLIC

Acetyl butyryl

Acetyl isovaleryl

Acetyl propionyl

Allyl heptanoate (Allyl enanthate)

*Allyl hexanoate (Allyl caproate)

Allyl isothiocyanate (Synthetic mustard oil)

Allyl sulfide (Diallyl sulfide)

Amyl propionate

Butyl butyrate

Butyl isovalerate

Butyroyl butyl lactate

Decanal ( Capraldehyde ) (C10)

Diallyl disulfide

Diethyl sebacate (Ethyl sebacate)

Diethyl succinate

Diethyl tridecanedioate (Ethylene brassylate)

2,6-Dimethyl-5-hepten-l-al

3,6-Dimethyl-3-oetanol

3,7-Dimethyl-l-octanol

3,7-Dimethyl-3-octanol

Dimethyl succinate

Ethylamyl ketone

Ethyl butyrate

Ethyl decanoate

Ethylene brassylate

Ethyl heptanoate (Ethyl enanthate)

Ethyl hexanoate (Ethyl caproate)

Ethyl isovalerate

Ethyl laurate

Ethyl levulinate

*Ethyl nonanoate (Ethyl pelargonate)

Ethyl octanoate (Ethyl caprylate)

^Glutamic acid, monosodium salt (Monosodium glutamate

Heptanal (Enanthaldehyde) (C7)

Heptyl alcohol (Heptanol)

cis-3-Hexen-l-ol

cis-3-Hexyn-l-ol

3-Hydroxy-2-butanone (Acetoin)

4-Hydroxynonanoic acid, y-lactone (y-Nonalactone) —

4-Hydroxyoctanoic acid, y-lactone (y -Octalactone )

4-Hydroxyundecanoic acid, y-lactone (y -Undecalactone

*Isopentyl butyrate (Amyl butyrate)

*Isopentyl formate (Amyl formate)

Isopentyl heptanoate (Amyl caproate)

Isopentyl isovalerate (Amyl isovalerate)

*Lauraldehyde (Dodecyl aldehyde) (Ci2)

6-Methyl-5-hepten-2-one

Methyl isovalerate-

Methyl-p -methylthiopropionate

Methyl -2-nonenoate

Methylolmethylhexyl ketone

2-Methylundecanal ( 2-Methylnonylacetaldehyde )

Myristic aldehyde

Nonanal (Pelargonaldehyde) (C9)

Nonanediol monoacetate

Nonyl acetate

Nonynol acetate, isomeric (Tepyl acetate)

Octanal (Caprylaldehyde) (Cb)

n-Octyl acetate

n-Octyl formate ■

n-Octyl isobutyrate

Omega decenol

2,6,10-Trimethyl-9-undeeen-l-ol

Undecanal (Hendecanaldehyde) (Cn)

2-Undecanone (Methyl nonyl ketone)

Undecenal (Hendecenaldehyde)

10-Undecen-l-ol

Valerolactone

All other

Manufacturers' identific<.ion codes (according to list in table 22)

FB,

rBK.

DOW,

FB,

GIV, UNG.

ICO,

MRT.

RT.

GIV.

OPC,

TBK.

TBK.

ICO.

GIV,

IFF,

TBK.

RT.

FEL,

TBK.

ICO,

TBK,

UCC.

RDA.

GIV.

cue.

GIV,

TBK.

GIV.

ICO.

GIV.

FB,

NW, RT, TBK.

TBK.

VLY.

FB,

FEL,

TBK.

FB,

NW.

FB,

TBK.

FB,

TBK.

FMT.

FB,

FEL,

GIV, TBK.

FB,

TBK.

COM,

GRW

ITC, IMC, MRK.

BAC.

BAC

UCC

X.

X.

FMT.

GIV

TBK

GIV

TBK

FB,

GIV.

FB,

GIV,

NW, RT, TBK.

FEL

RT,

TBK.

FEL

TBK

FB,

TBK.

GIV

IFF

TBK.

GIV.

FB.

RT.

GIV

GIV

GIV

TBK

GIV

GIV

GIV

TBK

IFF

GIV

IFF

FB,

TBK.

FB.

FB,

TBK.

IFF

GIV

GIV

IFF

, TBK.

GIV

GIV

GIV

GIV

FB,

GIV,

IFF, OPC, RT, SHL

SYNTHETIC ORGANIC CHEMICALS, 1965

Plastics and Resin Materials

TABLE 15B.— plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer , 1965

[Plastics and resin materials for which separate statistics are given in table 15A are marked below with an asterisk (*); chemicals not so marked do not appear in table 15A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Material and use

Manufacturers' identification codes (according to list in table 22)

THERMOSETTING RESINS

*Alkyd resins:

Protective coatings: *Phthalic anhydride type-

*Polybasic acid type

*A11 other uses

*Coumarone-indene and petroleum polymer resins

*Floor tile

*Rubber compounding

*A11 other uses

Epoxy resins:

Unmodified:

^Bonding and adhesives

^Protective coatings

^Reinforced plastics

*A11 other uses

*Modified

*Polyester resins:

Reinforced plastics: *Sheets, flat and corrugated

*A11 other

^Surface coatings

*A11 other uses

Silicone resins

*Phenolic and other tar acid resins ^Molding materials

Bonding and adhesive resins for- *Laminating

*Coated and bonded abrasives —

*Friction materials

^Thermal insulation

^Foundry or shell molding

*Plywood

*Fibrous and granulated wood —

AAI, ACP, ACY, ADM, APT, APV, BAL, BEN, BOY, BRU, CEL, CIK, CM, COM, CPV, DAV, DEG, DSO, DUN, DUP, EW, FAR, FBR, FCD, FLW, FOC, FRE, FSH, GEI, GIL, GLD, GRG, GRV, HAN, HPC, HRS, ICF, JOB, JWL, KEL, KMC, KMP, KPS, KYN, MCC, MID, NCI, NPV, NTL, 0R0, OSB, PER, PFP, PPG, PRT, RCI, RED, REL, RH, RMC, SCF, SCN, SED, SIP, SM, SRR, SVC, SW, SYV, TV, VTV, WAS, WPC, x.

ACP, ACY, APV, BEN, BRU, CGL, CM, COM, CPV, DSO, DUN, DUP, EW, FBR, FCD, FOC, GEI, GLD, GRV, HPC, ICF, KPS, MCC, MID, NCI, NON, NPV, OBS, 0R0, OSB, PPG, PRT, RED, REL, RH, RMC, SCN, SHA, SM, SRR, TV, VTV.

ACP, ACY, AMR, CGL, CIK, DUP, GLD, HPC, HYC, JSC, KMP, MMM, MOB, NOP, ORO, QCP, RCI, RH, SCN, SIP, SM.

ACC, ACP, NEV, NSP, PAI, VEL. ACC, ACP, KPI, NEV, NSP, PAI, VEL, WTC. ACC, ACP, ADM, CM, DSO, DUP, ENJ, ICF, MCA, NEV, NPV, NSP, PAI, PPG, RCM, VEL, VTV.

CBA, CEL, DOW, SHC, UCP.

CBA, CEL, DOW, RCI, SHC, UCP.

CBA, CEL, DOW, RCI, SHC, UCP.

CBA, CEL, DOW, RCI, SHC, UCP.

ACP, ADM, BEN, CM, DSO, FAR, FMC, GLD, HAN, HAP, ICF,

IOC, KPT, MID, MNP, MRB, NON, ORO, OSB, PPG, PYR,

REZ, RMC, SCN, SM, VTV, WAS.

ACY, ADM, APD, DA, EW, FRE, GLD, HKD, ICF, LAS, MFG,

ORO, PPG, RCI, RH, SIC, USR. AAI, ACP, ACY, ADM, CAP, CPV, DA, DSO, FRE, GLD, GRV,

HKD, ICF, IPC, KPS, LAS, MFG, MRO, PLU, PPG, RCI,

SW, USR. ACP, ACY, APD, COM, CPV, DA, FCD, GLD, GYR, ICF, MCC,

ORO, PPG, SW, USR. ACP, ACR, ACY, AMR, APD, DA, DAV, DSO, EKT, EPC, EW,

FMC, FRE, GEI, GLD, GNT, GRG, GYR, HKD, LAS, OCF,

PLU, PPG, RCI, RH, SCN, SW, USR, UTR, VAL. ACP, BOR, DCC, GLD, SPD, UCS.

FRL, GE, HER, HKD, HVG, IRC, MON, MRB, PLS, RCI, RGC, SYR, UCP, VAR, VSV.

ACP, AMR, BOR, CAT, CBR, CD, DRL, EW, FOM, GE, HKD,

IRI, MCA, MON, NPI, NPP, NTC, NVF, PGU, PYZ, RCD,

RCI, SCN, SPL, SYR, TAY, TKL, UCP, VAR. AMR, EME, BOR, CAT, CBM, CBR, HKD, MMM, MON, PYZ, SCN,

SYR, UCP, VAR. ABS, BME, BOR, FRL, GE, HKD, PYZ, SCN, SYR, SYV, UCP,

VAR, VSV, x. ACP, AMR, CAT, GE, HKD, ICF, MON, NPI, OCF, PYZ, RCI,

SYV, UCP. ACP, ACR, ARM, BOR, GE, HKD, MON, NPI, PYZ, RCI, SCN,

UCP, UNO, VAR, WOD. AMR, BOR, CAT, CBC, CBD, HPC, MON, PGU, PYZ, RCI, RH,

SIM, WCA, WOD, WRD. AMR, BOR, CBC, CBD, HKD, ICF, MCA, MON, NPI, PYZ, RCI,

SIM, UCP.

PLASTICS AND RESIN MATERIALS

135

TABLE 15B. --Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer, 1965- -Continued

Material and use

THERMOSETTING KESINS--Continued

*Phenolic and other tar acid resins— Continued Bonding and adhesive resins for — Continued *A11 other bonding and adhesive uses

*Proteotive coatings

*A11 other uses

*Polyurethane and diisocyanate resins

♦Rosin modifications:

♦Rosin and rosin esters, unmodified (ester gums, ♦All other

Styrene and alkyd polyesters

♦Urea and melamine resins:

*Textile treating and coating resins

♦Paper treating and coating resins

Molding materials

Bonding and adhesive resins for—

♦Laminating

♦Plywood

♦Fibrous and granulated wood

♦All other bonding and adhesive uses

♦Protective coatings

All other uses

All other thermosetting resins

THERMOPLASTIC RESINS Acrylic resins

♦Cellulose plastics materials: Sheets , continuous : ♦Under 0.003 gage

♦0.003 gage and over

♦All other sheets, rods, and tubes

♦Molding and extrusion materials

♦Polyamide resins:

♦Nylon type

♦Non-nylon type

♦Styrene type plastics materials:

♦Molding

♦Textile and paper treating and coating-

♦Emulsion paint

♦Extrusion

♦All other uses

Manufacturers' identification codes (according to list in table 22)

ACP, AMR, BME, B0R, CAT, GE, HKD, IRI, KPT, M0N, MRB, PYZ, RPC, SCN, SHA, SNC, SYR, UCP, USR, VAR.

ADM, AMR, BOR, CIK, CPV, DS0, EW, FAR, FCD, FRE, GE, GEI, GLD, GRG, GRV, HAN, HER, HKD, ICF, INL, KRM, MID, M0N, NCI, NPI, 0R0, PFP, PYZ, RCI, RH, RMC, SCN, SHA, SM, SNC, SW, SYR, UCP, VAR, VTV, WAS.

ACP, ACR, AMR, BOR, CAT, EW, GEN, HER, HKD, IOC, IRC, KND, MMM, MON, MRB, PLS, PYR, PYZ, RCI, REZ, RGC, RH, SCN, SNC, UCP, USR, VAR, VSV, x.

ACB, ADM, ARK, BFG, BKL, CDM, DUP, FAR, GPM, HAP, HOU, IPI, MCC, MID, NOP, NPV, PEL, PFP, PYR, QUN, SCN, TRN, UPC, UPJ.

ADM, APV, CBY, DPP, FAR, FCD, FRP, HPC, KRM, MCC, SRR. ADM, APV, CBY, DPP, FAR, FCD, FLW, FRP, HPC, KRM, MCC,

RH, SCF, SRR. ADM, DEG, MCC.

ACY, APX, BOR, BPY, CAT, CCT, CIB, CRC, DAN, DEP, DUP, ECC, HNC, HRT, JSC, MON, MRA, ONX, PC, QCP, RCI, RH, ROC, RPC, S, SBC, SEY, SNW, STC, SYN, TV, USO, WON.

ACY, AMR, BME, BOR, CBD, CBR, DEP, DUP, HPC, MMM, MON, RCI, RH, SIM, x.

ACP, ACY, AV, BOR, CAP, EFH, GDN, PMC.

ACY, BOR, CAT, FOM, GE, MON, NPP, NTC, PGU, PPL.

ACY, BGC, BOR, CAT, CBC, CBD, HPC, MON, NPI, NTC, PGU,

RCI, REN, RH, SAC, SIM, SOR, WOD, WRD. ACY, AMR, BOR, CED, IPR, MON, NTC, PGU, RCI, SOR, SWP,

SYV, UPL. ACP, ACY, BOR, GLD, MON, OCF, RCI, UNO. ACP, ACY, AMR, BOR, CEL, CPV, DUP, GRV, HAN, KPS, MID,

MON, OXR, PPG, RCI, REL, RH, SCN, SW. ACP, ACY, AMR, AV, BOR, CAT, CMP, DUP, ECC, FRP, GEO,

HPC, MMM, MON, RCI, RH, VAL, VAR, WIC. ACP, ACY, ADM, DEG, GGY, HPC, HVG, JNS, MCC, MON, NPV,

OCF, RCD, SNW, UBS, UNO, WTC.

AGO, ACY, CAT, CEL, CIB, CMG, DUP, FLH, GLC, GLX, HCO, JNS, JSC, PII, PPG, QUN, RH, RPC, SAR, SEY, USP, VPC, WIC.

CEL, DUP, EKT, MON.

CEL, DOW, EKT, MPP, NIX, PDJ, SPY.

CEL, MPP, NIX, PDJ, RPI, RSB, SPY.

CEL, DOW, EKT, MON, PMA, RSB.

ALF, DUP, FG, POL, SPN.

AMR, BCM, EMR, GNM, HN, JNS, KRM, SNW.

ACP, BFG, BKC, BPL, CSD, DOW, DSO, FBF, FG, FIR, GOR,

GRP, GYR, KPP, MCB, MON, MPL, PLA, RCC, SHC, SOL,

TIC, UCP, USR. BOR, DOW, FIR, GNT, GRD, GYR, ILC, KPP, MON, MRT, USR,

WAS, WIC. BOR, DOW, DSO, DUP, FIR, GLD, GNT, GRD, GYR, KPP, JSC,

MON, USR. ASP, BFG, CSD, DOW, KPP, MCB, MON, PMA, RCC, UCP, USR. ACC, ACP, BCN, BFG, BKC, BOR, CSD, DOW, DSO, DUP, FIR,

G, GNT, GRD, GYR, IOC, JNS, JSC, KPP, MCB, MON, MRT,

ONX, PAI, POL, PVI, RCC, RH, SEK, SEP, SHC, SPI, UBS,

UCP, UNC, USR, WAS, WIC.

136

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 15B Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Material and use

Manufacturers ' identification codes (according to list in table 22)

THERM3PLASTIC RESINS--Continued

Vinyl resins: ♦Polyvinyl acetate resins:

♦Emulsion paint

♦Adhesives

♦Bonding and sizing

♦All other uses

♦Polyvinyl chloride and copolymer resins:

♦Film, under 6 mils

♦Sheet, 6 mils and over

♦Flooring

♦Paper and textile coating

Extrusion: ♦Wire and cable

♦Garden hose

♦All other extrusions

Molding: ♦Records

♦Slush and rotational molding

♦All other moldings

♦All other uses

♦All other vinyl resins

Polyolefin plastics materials: ♦Polyethylene, density 0.940 and below:

♦Injection molding

♦Blow molding

Extrusion: ♦Film and sheet

♦Wire and cable coating

♦Extrusion coating on paper and other substrates-

♦Pipe

♦All other extrusions

♦All other uses ■

♦Polyethylene, density over 0.940:

♦Injection molding

♦Blow molding

Extrusion: ♦Film and sheet

♦Wire and cable coating

♦Pipe

♦All other extrusions

♦All other uses

ACP, AIR, AML, APV, BOR, BOY, CAT, CEL, COM, DAV, DSO, DUP, FAR, FLH, GLC, GLD, GRD, HAM, JNT, KMC, KMP, MCC, MON, NPV, NSC, RCI, REL, SED, SPC, UCP, WAS, x.

ACP, AML, AIR, BOR, CAT, CEL, DUP, FC, FLH, GLC, GRD, HNC, JNT, JSC, MON, MRN, NSC, NTC, PII, PPG, RCI, SEY, SH, SYR, UCP, WIC.

AIR, AML, CEL, .CST, DUP, GLC, GRD, MON, PII, QCP, RPC, SEY, WIC.

AIR, AML, BOR, CEL, CIK, DAN, DUP, FLH, GLC, GRD, HRT, JSC, MON, NSC, OCF, PPG, PVI, RCI, RPC, SCO, UCP, x.

ATU, BFG, BOR, CRY, DOW, FIR, GNT, GYR, MON, PNT, THC,

UCP, x. AME, ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, GNT, GYR,

MON, PNT, THC, UCP, USR, x. AME, BFG, BOR, CRY, CUC, DA, ESC, FIR, GNT, GYR, MON,

THC, UCP, USR, x. ATU, BFG, BOR, CRY, DA, ESC, MON, ONX, THC, UCP, USR, x.

ATU, BFG, BOR, CRY, DA, DOW, FIR, MON, PNT, THC, UCP,

USR. ATU, BFG, BOR, DA, DOW, FIR, MON. BFG, BOR, CRY, DA, DOW, ESC, FIR, GNT, GYR, LAS, MON,

THC, UCP, USR.

BFG, BOR, CRY, CUC, DA, KYS, MON, PLA, PNT, THC, UCP,

USR. BFG, BOR, CRY, DA, ESC, FIR, MON, UCP, USR. ATU, BFG, BOR, CRY, DA, DOW, ESC, FIR, GYR, LAS, MON,

PYR, THE, UCP. ATU, BFG, BOR, CBR, CMG, CRY, CUC, DA, DOW, ESC, FIR,

GNT, GRA, GYR, MON, NSC, PNT, PYR, THC, UCP, USR, x. ADM, AIR, BEN, BOR, DOW, DUP, FC, FCD, G, GLD, GRD,

HOU, MCC, MON, NSC, RMC, RPC, SW, UCP.

ACP, CEL, DOW, DUP, EKX, KPP, MON,

UCP, USI. ACP, DOW, DUP, EKX, KPP, MON, PLC,

ACP, ALO, CEL, DOW, DUP, EKX, KPP,

SPN, UCP, USI. DOW, DUP, EKX, KPP, MON, PLC, SHC, ACP, CEL, DOW, DUP, EKX, KPP, MON,

UCP, USI. CEL, DUP, EKX, KPP, PLC, SPN, UCP, ACP, DOW, DUP, EKX, GRP, KPP, PLC, ACP, CEL, DOW, DUP, EKX, KPP, MON,

UCP, USI.

ACP, CEL, DOW, DUP, EKX, HPC, KPP,

USI. ACP, CEL, DOW, DUP, EKX, GGC, HPC,

UCP, USI.

ACP, CEL, DOW, DUP, EKX, GGC, HPC,

USI. ACP, CEL, DUP, EKX, HPC, PLC, UCP. ACP, CEL, DUP, EKX, GGC, HPC, KPP, ACP, CEL, DOW, DUP, EKX, GGC, HPC,

USI. ACP, CEL, DOW, DUP, EKX, GGC, HPC,

UCP, USI.

PLC, RCC, SHC, SPN,

RCC, SHC, UCP, USI.

MON, PLC, RCC, SHC,

SPN, UCP, USI.

PLC, RCC, SHC, SPN,

USI.

UCP, USI.

PLC, RCC, SHC, SPN,

PLC, RCC, SHC, UCP,

KPP, MON, PLC, SHC,

KPP, PLC, SHC, UCP,

PLC, SHC, UCP. KPP, PLC, SHC, UCP,

KPP, MON, PLC, RCC,

PLASTICS AND RESIN MATERIALS

137

TABLE 15B. —Plastics and resin materials for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Material and use

Manufacturers1 identification codes (according to list in table 22)

THERMOPLASTIC RESINS— Continued

Polyolefin plastics materials—Continued ^Polypropylene :

UCP, USI. ACP, ALO, AVS, EKX, ENJ, HPC, PLC, UCP.

UCP, USI. ACG, ACP, CBY, CIB, DEP, DUP, GE, HPC, JSC, KRM, MID, MMM, MOB, MRA, RPC, SBC, SCN, SEY, SNW, VSV, WIC.

SYNTHETIC ORGANIC CHEMICALS, 1965

Rubber- Processing Chemicals

TABLE 16B. --Rubber- processing chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Rubber-processing chemicals for which separate statistics are given in table 16A are marked below with an asterisk (*); chemicals not so marked do not appear in table 16A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers' identification codes ( according to list in table 22)

RUBBER-PROCESSING CHEMICALS, CYCLIC

^Accelerators, activators, and vulcanizing agents: *Aldehyde-amine reaction products:

Acetaldehyde- aniline condensate

n-Butyraldehyde- aniline condensate

Butyraldehyde-butylideneaniline condensate

a-Ethyl-fS-propylacrylanilide

Heptaldehyde- aniline condensate

Triethyltrimethylenetriamine

*Dithiocarbamic acid derivatives:

Dibenzyldithiocarbamic acid, sodium salt

Dibenzyldithiocarbamic acid, zinc salt

Dibutyldithiocarbamic acid, N,N-dimethylcyclohexylamine

salt.

Dibutyldithiocarbamic acid, diphenylguanidine salt

Dimethylethylene diphenyldithiocarbamic acid, lead salt

2,4-Dinixrophenyl dimethyldithiocarbamate

Piperidinecarbodithioic acid, piperidinium- potassium

salts, mixed. Guanidines:

Dicatechol borate, di-o-tolylguanidine salt

1, 3-Diphenylguanidine

Diphenylguanidine phthalate

1, 3-Di-o-tolylguanidine

1, 2,3-Triphenylguanidine

*Thiazole derivatives:

2-Benzothiazyl N,N-diethylthiocarbamoyl sulfide

1, 3-Eis(2-benzothiazolylmercaptomethyl)urea

N-tert-Buty 1-2- benzothiazolesulf enamide

*N-Cyelohexyl-2-benzothiazolesulf enamide

N, N-Diisopropyl-2-be nzothiazolesulfenand.de

N-(2, 6-Dimethy-lmorpholino) -2-ben£othiazolesulf enamide —

*2,2'-Dithiobis(benzothiazole)

2-Mercaptobenzothiazole

2-Mercaptobenzothiazole, zinc chloride

2-Mercaptobenzothiazole, zinc salt

4-Morpholi nyl-2-benzothiazyl disulfide

N-0xydiethylene-2-benzothiazolesulf enamide

Thiazoline-2- thiol

All other cyclic accelerators, activators, and vulcanizing

agents:

p-Benzoquinonedioxime

Bis( p- aminocyclohexyl) methane carbamate

Bis( 2, 6-dimethylmorpholinothiocarbonyl) sulfide

Dibenzoyl-p-quinonedioxime •

Dibenzylamine

N, N'-Dicinnamylidene-l, 6-hexanediamine

Di-N,N'-pentamethylenethiuram tetrasulfide

^■i'-Dithiodimorpholine

2-Imidazoline-2-thiol

m-Phenylenebismaleimide

Poly-p-dinitrosobenzene

Styrene polysulfide

Tetrahydro-4,4,6-trimethyl-2( lH)-pyrimidinethione

*Antioxidants, antiozonants, and stabilizers:

*Amino antioxidants, antiozonants, and stabilizers: *Aldehyde- and acetone-amine reaction products:

Acetaldehyde- aniline hydrochloride condensate

Aldol-cc-naphthylamine condensate

Butyraldehyde- aniline condensate

*Diphenylamine- acetone condensate

Phenyl-2-naphthylamine-acetone condensate

USR.

DUP, MAN, RCD, USR.

MON.

CCO.

USR.

USR.

USR. USR. MON.

CCO. CCO. USR. DUP.

DUP. ACY. MON.

ACY, DUP. NAC.

PAS. MON. MON. ACY, ACY. MON. ACY, ACY, DUP. ACY, GYR. ACY, ACY.

BFG, MON, USR.

BFG, GYR, MON, USR. BFG, GYR, MON, USR.

GYR, USR. MON.

CTA, DUP.

DUP.

DUP.

CTA, USR.

MLS, USR.

DUP.

DUP, VNC.

MON.

DUP, RBC.

DUP.

DUP.

TKL.

VNC.

USR.

BFG.

DUP.

ACY, BFG, DUP, USR.

USR.

RUBBER-PROCESSING CHEMICALS

139

TABLE 16B.— Rubber-processing chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965— Continued

Manufacturers1 identification codes (according to list in table 22)

RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued

•Antioxidants, antlozonants, and stabilizers — Continued •Amino antioxidants, antiozonants, and stabilizers — Continued •Substituted p-phenylenediamines:

N, N'-Bis( l-ethyl-3-methylpentyl) -p-phenylenediamine-

N, N'-Bis( l-methyljtieptyl) -p-phenylenediamine

N-see-Butyl-N'-phenyl-p-phenylenedlamine

N-Cyclohexyl-N '-phenyl- p-phenylenediamine

Diary larylenediamines, mixed

N,N'-Di-2-naphthyl- p-phenylenediamine

•N,N'-Diphenyl- p-phenylenediamine

N-Isopropyl-N '-phenyl- p-phenylenediamine

N-(l-MethyLheptyl)-N' -phenyl- p-phenylenediamine

All other p-phenylenediamines

Other amino antioxidants, antiozonants, and stabi- lizers:

p-Anilinophenol

l,2-Dihydro-6-dodecyl-2,2,4-trimethylquinoline

l,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline

l,2-Dihydro-2, 2,4- trimethylquino line

4,4'-Dimethoxydiphenylamine

4,4'-Dioetyldiphenylamine

N,N'-Diphenylethylenediamine

N, N'-Diphenyl-l,3-propanediamine

N, N'-Di-o-tolylethylenediamine

p- Isopropoxydiphenylamine

4,4'-Methylenedianiline

*Octyldiphenylamine

Octyldiphenylamine mixture (mono-, nonyl-, and di-)>

N-Phenyl-1-naphthylamine

N-Phenyl-2-naphthylamine

Tetramethyldiphenylethylenediamine

p-(p-Toluenesulfonamido)diphenylamine

•Phenolic and phosphite antioxidants and stabilizers: Phosphites:

Nonyl phenyl phosphites, mixed

Polyphenolie phosphite, polyaliylated

Polyphenolics ( including bisphenols) :

4,4'-Butylidenebis(6-tert-butyl-m-cresol)

2,5-Di-(l,l-dimethylpropyl)hydroquinone

2, 2'-Methylenebis(6-tert-butyl-p-cresol)

2,2'-Methylenebis(6-tert-butyl-4-ethylphenol)

2,2'-Methylenebis(6-tert-octyl-p-cresol)

2,2'-Thiobis(4, 6-di-sec-amylphenol)

4,4'-Thiobis(6-tert-butyl-m-cresol)

1, l,3-Tri(2-methyl-4-hydroxy-5-tert-butylphenyl)- butane. Other phenolic antioxidants and stabilizers:

p-Benzyloxyphenol

N-Butyroyl-p-aminophenol

o-Cresol, alkylated

N-Lauroyl-p-aminophenol

•Phenol, alkylated

Phenol, hindered

Phenol, styrenated

N-Stearoyl-p-aminophenol

Xylenol, alkylated

•Blowing agents:

N,N'-Dimethyl-N,N'-dinitrosoterephthalamide

Dinitrosopentamethylenetetramine

p,p'-Oxybis(benzenesulfonhydrazide)

•Peptizers:

Alkylated o-thiocresol

Alkylated thiophenol, zinc salt

Aryl mercaptans

2-Benzamidothiophene, zinc salt

2',2'"-Dithiobis(benzanilide)

Dixylyl disulfides, mixed

2-Naphthalene thiol

EKT,

MON,

UPM.

BFG,

EKT,

MON,

UPM.

USR.

USR.

GYR.

BFG.

BFG,

DUP,

USR.

MON,

USR.

UPM.

EKT,

MON.

BFG.

MON.

MON.

BFG,

MON.

DUP.

BFG.

CCO,

X, X

CCO.

CCO.

BFG.

USR.

ACY,

NPI,

PAS,

USR.

BFG.

DUP.

BFG,

DUP.

USR. BFG.

MON.

MON.

ACY, CAT.

ACY.

ACY.

MON.

MON.

ICI.

BFG.

MLS.

PIT.

MLS.

ACY, BFG, CCO, GYR, PAS, PIT, USR.

DUP, GYR, PIT.

BFG, GYR.

MLS.

PIT.

DUP.

DUP, NPI. USR.

PIT.

PIT.

PIT.

ACY.

ACY.

DUP, PIT.

DUP.

140

TABLE 16B.

SYNTHETIC ORGANIC CHEMICALS, 1965

—Rubber-processing chemicals for which U.S. production or sales were reported identified by manufacturer, 1 965- -Continued

RUBBER-PROCESSING CHEMICALS, CYCLIC— Continued

♦Peptizers — Continued

Pentachlorobenzene thiol

Pentachlorobenzenethiol, zinc salt

Thioeresol

Thiophenol ( Benzenethiol)

Xylenethiol

Other cyclic rubber-processing chemicals:

p-tert-Amylphenol sulfide ( taclcifier)

Dicresyl disulfide

N,4-Dinitroso-N-methylaniline ( physical- property improver) . ♦N-Nitrosodiphenylamine ( retarder)

RUBBER-PROCESSING CHEMICALS, ACYCLIC

♦Accelerators, activators, and vulcanizing agents: ♦Dithiocarbamic acid derivatives:

Dibutyldithiocarbamic acid, potassium salt

Dibutyldithiocarbamic acid, sodium salt

♦Dibutyldithiocarbamic acid, zinc salt

Diethyldithiocarbamic acid, cadmium salt

Diethyldithiocarbamic acid, selenium salt

Diethyldithiocarbamic acid, sodium salt

Diethyldithiocarbamic acid,

♦Diethyldithiocarbamic acid, Dimethyldithiocarbamic acid, Dimethyldithiocarbamic acid, Dimethyldithiocarbamic acid, Dimethyldithiocarbamic acid, Dimethyldithiocarbamic acid, sodium salt and sodium polysulfide.

♦Dimethyldithiocarbamic acid, zinc salt

All other

♦Thiurams :

Bis( dibutylthiocarbamoyl) sulfide

Bis( diethylthiocarbamoyl) disulfide

♦Bis( dimethylthiocarbamoyl) disulfide

Bis( dimethylthiocarbamoyl) disulfide and 2-mercapto- benzothiazole, mixed.

*Bis( dimethylthiocarbamoyl) sulfide

Bis( ethylmethylthiocarbamoyl) sulfide

Thiuram blend

Xanthates and sulfides:

Di-n-butylxantho disulfide

Diisopropylxantho disulfide

Zinc dibutyl xanthate

All other acyclic accelerators, activators, and vulcan- izing agents:

n-Butyraldehyde-butylamine condensate

Pi- n- butyls mmonium oleate

N, N'-Dibutyldithioadipamide

3- Ethyl- 1, 1-dimethy 1-2- thiourea

Ethylenediamine carbamate

Polyoxyalkalenetetrasulfide

1,1,3-Trimethy 1-2- thiourea-

tellurium salt- zinc salt

bismuth salt- copper salt

lead salt

selenium salt-

Manufacturers' identification codes (according to list in table 22)

DUP. DUP. PIT. PIT. DUP.

PAS. USR. CTA, MON.

BFG, CTA, GYR, USR.

PAS, USR, VNC.

DUP, PAS, REC, USR, VNC.

PAS, USR.

GYR, PAS, RBC, USR, VNC.

VNC. DUP, ALC, VNC. VNC. ALC, VNC. ALC, VNC. VNC. VNC. VNC. BFG,

ALC, DUP, FMN, GYR, PAS, RBC, USR, WRC. PAS.

USR.

DUP, GYR, PAS, VNC.

BFG, DUP, GNT, GYR, PAS, RBC, USR, VNC.

VNC.

DUP, GYR, USR.

VNC.

DUP.

USR. BFG. USR.

DUP. DUP. DUP. VNC. DUP. TKL. VNC.

RUBBER-PROCESSING CHEMICALS

141

TABLE 16B. — Rubber-processing chemicals for which U.S. production or sales were reported, identified by

manufacturer, 2S65--Contlnued

Chemical

Manufacturers' identification codes ( according to list in table 22)

RUBBER-PROCESSING CHEMICALS, ACYCLIC— Continued Blowing agents:

SW.

DUP. DUP. DUP.

PAS, PLC.

Conditioning and lubricating agents:

Methyl stearyl-10-sulfonic acid, sodium salt

Mono- and dialkyl phosphate ammonium salts, mixed

Polymerization regulators:

Shortstops:

Dimethyldithiocarbamic acid, potassium salt

Other acyclic rubber-processing chemicals:

Zinc laurate (activator, physical- property improver)

GYR, PAS, USR.

ALC, BFG, DUP, GYR, PAS.

USR.

SYNTHETIC ORGANIC CHEMICALS, 1965

Elastomers (Synthetic Rubbers)

TABLE 17B.-- Elastomers (synthetic rubbers) for which U.S. production or sales were reported, identified by

manufacturer , 1965

[Elastomers (synthetic rubbers) for which separate statistics are given in table 17A are marked below with an as- terisk (*); products not so marked do not appear in table 17A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Product

Manufacturers ' identification codes (according to list in table 22)

ELASTOMERS, CYCLIC

ASY, BFG, CPY, FIR, FRS, GGC, GNT, GYR, ILC, MCB, PLC,

RUB, SHC, TUS, URC, USR, WIC. ASY, BFG, FIR, FRS, GNT, GYR, PLC, USR, WIC. ACY, BFG, DUP, GNT, MOB, PRC, TKL, USR.

ACY, BFG, TKL.

TKL.

BFG, FRS, GYR, TKL, TUS.

BFG, FRS, GYR, ILC, MCB, USR.

DUP.

CBN, ENJ.

GYR, HPC.

DCC, SPD, UCS.

ASY, BAR, DUP, ENJ, FRS, GGC, GNT, GYR, PLC, SHC, TUS.

DUP, x.

ELASTOMERS, ACYCLIC

*Polyisobutylene-isoprene type (Butyl)

<3+

Plasticizers

TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Plasticizers for which separate statistics are given in table 18A are marked below with an asterisk (*); products not so marked do not appear in table 18A because the reported data are accepted in confidence and may not be pub- lished. Manufacturers' identification codes shown below are taken from table 22]

Manufacturers' identification codes (according to list in table 22)

PLASTICIZERS, CYCLIC

Coumarone-indene plasticizer

N-Cyclohexyl-p-toluenesulfonamide

Diethylene glycol dibenzoate

Di-tert-octyldiphenyl oxide

Dipropanediol dibenzoate

N-Ethyl-p-toluenesulfonamide

Isopropylidenediphenoxypropanol

Naphthalene, alkylated

Phosphoric acid esters:

*Cresyl diphenyl phosphate

Dibutyl phenyl phosphate

Diphenyl mono-o-xenyl phosphate

Diphenyl octyl phosphate

Methyl diphenyl phosphate

*Tricresyl phosphate

Triphenyl phosphate

All other phosphoric acid esters

*Phthalic anhydride esters:

Alkyl benzyl phthalates

Butyl benzyl phthalate

Butyl cyclohexyl phthalate

Butyl decyl phthalate

*Butyl 2-ethylhexyl phthalate

n-Butyl isodecyl phthalate

*Butyl octyl phthalate

Butyl phthalyl butyl glycolate

Di(2-butoxyethyl) phthalate

*Dibutyl phthalate

*Dicyelohexyl phthalate

*Diethyl phthalate

*Dihexyl phthalate

Diisobutyl phthalate

*Diisodecyl phthalate

»Di(2-methoxyethyl) phthalate

Dimethyl cyclohexyl phthalate

Dimethyl isophthalate

*Dimethyl phthalate

Dinonyl phthalate

*Dioctyl phthalates:

Dicapryl phthalate

Di(ethylhexyl)isophthalate

*Di(2-ethyLhexyl) phthalate

*Diiso-octyl phthalate

Di-n-octyl phthalate

*Mixed dioctyl phthalates

Diphenyl phthalate

*Ditridecyl phthalate

2-EthyLhexyl isodecyl phthalate

Ethyl (and methyl) phthalyl ethyl glycolate

Glycol phthalic esters

Hexyl n-decyl phthalate

Hexyl isodecyl phthalate

Hydrogenated castor oil phthalate

Isodecyl tridecyl phthalate

*0ctyl decyl phthalates:

Iso-octyl isodecyl phthalate

n-Octyl n-decyl phthalate

All other phthalic anhydride esters

NEV.

MON.

VEL.

DOW.

VEL.

MON.

DOW.

ACC.

FMP,

MON, MTR, SF, SM.

MON.

DOW.

MON.

FMP,

MON.

FMP,

MON, MTR, SF.

DOW,

EK, MON, SF.

SF.

MON.

GRH,

MON.

ACP.

ACP,

PCC.

ACP,

MON, UCC.

GRH,

UCC.

GRH,

PCC, RCI, RUB.

MON.

FMP,

WM.

ACP,

COM, DUP, EKT, ENJ, GRH,

HAL,

LAS,

MON,

PCC,

PFZ

RCI, RUB, SW, UCC, WTH.

ACP,

DUP, FMP, MON, PFZ.

DUP,

EKT, KF, MON, PFZ.

ACP,

ENJ, GRH, LEH, THC.

EKT,

UCC.

ACP,

BFG, EKT, ENJ, GRH, MON,

PCC,

PFZ,

RCI,

RUB,

THC

UCC, WTH.

DUP,

EKT, FMP, RCI, SF.

DUP.

PFZ.

ACP,

EKT, KF, MON, PFZ.

RCI.

ACP, GRH, WTH.

UCC.

ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB,

THC, UCC, WTH. ACP, BFG, EKT, ENJ, GRH, LEH, MON, PCC, PFZ, RCI, RUB,

THC, UCC. ADM.

ACP, GRH, UCC, WTH. MON.

ACP, ENJ, GRH, MON, PCC, PFZ, RCI, RUB, THC, UCC. UCC. MON.

ARG, HPC. ACP, UCC. PFZ. DUP. THC. ,

ACP, PCC.

ACP, GRH, HPC, MON, PCC, PFZ, RCI, RUB, THC, UCC.

FMP, LEH, MON, PCC, UCC.

144

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 18B. — Plasticizers for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

PLASTICIZERS, CYCLIC— Continued

Polyethylene glycol dibenzoate

Tetrahydrofurfuryl oleate

Toluenesulfonamide, o-, p- mixtures

Triethylene glycol dibenzoate

*Trimellitic acid esters

All other cyclic plasticizers

PLASTICIZERS, ACYCLIC

*Adipic acid esters:

Di(2-(2-butoxyethoxy)ethyl) adipate

*Di ( 2-ethylhexyl ) adipate

Diisobutyl adipate

*Diisodecyl adipate

*Diiso-octyl adipate

Dinonyl adipate

Di-n-octyl adipate

Di-tridecyl adipate

Iso-octyl isodecyl adipate

*Octyl decyl adipate

Polyethylene glycol adipate

All other adipic acid esters

*Azelaic acid esters:

Di ( 2-ethyLhexyl ) azelate

Di-n-hexyl azelate

Diisobutyl azelate

Diiso-octyl azelate

Dioctyl azelate

All other azelaic acid esters

Citric and acetylcitric acid esters

^Complex linear polyesters and polymeric plasticizers-

Di(2-(2-butoxyethoxy)ethyl)methane

Diethylene glycol dinonanoate

Diiso-octyl diglycolate

*Epoxidized esters:

Butyl epoxydioleate

Butyl epoxytallate

Epoxidized linseed oils

*Epoxidized soya oils

*2-Ethylhexyl epoxytallates

Octyl epoxystearates

*Octyl epoxytallates

All other epoxidized esters

Glycerol pelargonate

Glyceryl tributyrate and tripropionate

Glycol pelargonate

Isodecyl maleate

Isodecyl nonanoate (Isodecyl pelargonate)

Laurie acid esters

Myristic acid esters:

Butyl myristate

*Isopropyl myristate

*01eic acid esters:

*Butyl oleate

^Glycerol trioleate (Triolein)

*Isopropyl oleate

*Methyl oleate

*n-Propyl oleate

*A11 other oleic acid esters

Palmitic acid esters:

Isobutyl palmitate

*Isopropyl palmitate

2-Methoxyethyl palmitate

All other palmitic acid esters

^Phosphoric acid esters:

Tri(2-butoxyethyl) phosphate

Tri(2-chloroethyl) phosphate

Triethyl phosphate

VEL.

CCW, EMR.

ACY, MON.

VEL.

PCC, PFZ, RUB.

CCW, EKT, MON, NEV, WTH.

TKL.

FMP, EKT, FMP, ACP, GRH, THC. ACP. LEH. BFG, ACP, PFZ. ACP, ARC, EKX, PCC, PFZ, VND.

LEH, MON, PCC, RCI, RH, RUB, THC, UCC, WTH. GRH, HAL, RCI.

EKT, GRH, LEH, MON, PCG, RCI, RH, RUB, THC, UCC, WTH. LEH, PCC, RCI, RH, RUB, WTH.

NOP, RCI.

GRH, MON, PCC, RCI, RH, RUB, THC, TKL, UCC.

DUP, EKT, EMR, PFZ, RCI, RH, RUB, THC, UCC.

UCC.

HAL, RCI.

EMR, PFZ.

PFZ.

ACP, EMR, PFZ.

PFZ.

ADM, EKT, EMR, GLY, HAL, LEH, MON, PFZ, RH, RUB, WM,

WTH. GRD.

EMR, RUB. CCA, FMP.

THC.

SWT.

ARG, BAC, RCI, RH, SWT, THC, UCC.

BAC, UCC.

RH, THC, UCC. RH.

ADM. ADM, ADM, ADM, ADM, ARG. ARG, EMR, EMR. EKT. EMR. LEH. EMR. HAL.

ARC, ICI.

ARC, ICI, NOP, PRP.

ARC, HAL, ICI, LAS, NOP, SWT, WM, WTH.

DRW, EMR, SWT, WM.

ARC, ICI, WM.

CHL, EMR, ICI, NOP, SWT.

CHL, EMR, WM.

ARC, DRW, HAL.

ARC, EKT.

ARC, EMR, ICI, PRP, WM.

EKT.

EKT, RUB.

FMP, MON, SF, WES.

UCC.

EKT.

PLASTICIZERS

145

TABLE 18B. --Plasticizers for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

PLASTICIZERS, ACYCLIC— Continued

•Phosphoric acid esters — Continued

Trioctyl phosphate

All other phosphoric acid esters

Ricinoleic and acetylricinoleic acid esters:

n-Butyl acetylricinoleate

Butyl ricinoleate

•Glycerol monorieinoleate

Glyceryl tri( acetylricinoleate)

Methyl ricinoleate

All other ricinoleic and acetylricinoleic acid esters

Sebacic acid esters:

Dibutoxyethyl sebacate

*Dibutyl sebacate

*Di(2-ethylhexyl) sebacate

All other sebacic acid esters

•Stearic acid esters:

Butoxyethyl stearate

*n-Butyl stearate

Glycerol triacetyl stearate

Glycerol tristearate

Methoxyethyl stearate

Methyl diohlorostearate

Methyl pentachlorostearate

Methyl stearate

All other stearic acid esters

Sucrose acetate isobutyrate

Tetraethylene glycol di(2-ethylhexanoate)

*Triethylene glycol di(caprylate-caprate)

Triethylene glycol di-2-ethylbutyrate

Methylene glycol di(2-ethylisohexoate)

Trimethyl pentanediol diisobutyrate

All other acyclic plasticizers

Manufacturers ' identification codes (according to List in table 22)

FMP, UCC.

SM.

BAC, WTH.

BAC, RCI.

BAC, GLY, HAL, NOP.

BAC.

BAC.

ARC, BAC, RCI.

RCI.

EKT, GRH, HAL, PFZ, RCI, RH, WTH.

GRD, GRH, HAL, PCC, RCI, RH, HUB, WTH.

ARC, LEH, NOP, PCC, RCI, RH, HOB.

ARC.

ARC,

BAC.

DRW.

ARC.

HK.

HK.

CHL.

ARC,

EKT.

UCC.

DRW,

UCC.

EKT.

EKX.

ARC,

CHL, EMR, HAL, ICI, LAS, SCP, SWT, WTH.

FMP, HPC, PRP, RCI, RH, Hi. FOR, HAL, RUB.

EMR, HAL, HPC, LEH, PFZ, RH, RUB, TKL, UCC, WM.

SYNTHETIC ORGANIC CHEMICALS, 1965

Surface-Active Agents

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Surface-active agents for which separate statistics are given in table 19A are marked below with an asterisk (*); products not so marked do not appear in table 19A because the reported data are accepted in confidence and may not be published. Manufacturers ' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Manufacturers ' identification codes (according to list in table 22)

BENZENOID SURFACE-ACTIVE AGENTS

Not Sulfated or Sulfonated

*Amides, amines, and quaternary ammonium salts:

*Benzyldimethyl(mixed alkyl) ammonium chloride

*Benzyldimethyloctadeey lammonium chloride

*Benzyldodeeyldimethylammonium chloride

*( 3, 4^ Dichlorobenzyl)dodecyldimethy lammonium chloride

*(Dodecylbenzyl)trimethylammonium chloride

^Heterocyclic compounds :

l-Benzyl-2-( coconut oil alkyl)-l-(2-hydroxyethyl)-2- imidazolinium chloride. *l-Benzyl-2-heptadecyl-l-( 2-hydroxyethyl) -2-imidazo- linium chloride. l-Benzyl-l-(2-hydroxyethyl)-2-nor(tall oil alkyl)-2- imidazolinium chloride.

l-Benzyl-2-picolinium bromide

1-Benzylpyridinium chloride

2-Dodecylisoquinolinium bromide

1-Dodecylpyridinium chloride

2-(2-Lauroyloxyethyl)carbamoyl-l-methylpyridinium

chloride. l-Methyl-2- ( 2-stearoyloxyethyl) carbamoylpyridinium chloride. *Oxygen- containing compounds (except heterocyclic): Benzylbis ( 2-hydroxyethyl ) ( 2-stearamidomethoxyethyl) -

ammonium chloride. Benzyl( coconut oil alkyl )bis ( 2-hydroxyethyl )a,mmonium

chloride . Benzyl( coconut oil amidopropyl ) dime thy lammonium

chloride. Benzyl( ethoxylated coconut oil alkyl )dimethy lammonium

chloride. ( Ethoxybenzyl ) dimethyl ( oc tylphenoxy ) ammonium chloride — (Ethoxybenzyl) dime thyl(octyltolyloxy) ammonium chloride-

N- ( 2-Hydroxyethyl ) -1, 2-diphenylethylenediami ne

o-Isopropoxyphenyl N-methylcarbamate

(Tridecylbenzyl)diethyl( 2-hydroxyethyl) ammonium chloride. *A11 other:

Benzylbis (hydrogenated tallow alkyl )methy lammonium chloride.

Benzyl( coconut oil alkyl) dime thy lammonium chloride

Benzyldimethyltetradecy lammonium chloride

Benzylhexadecyldimethy lammonium chloride

Benzyl( hydrogenated tallow alkyl ) dime thy lammonium chloride.

Benzyl( soybean oil alkyl) dimethy lammonium chloride

Benzyltrimethy lammonium chloride

(Dodecylbenzyl) dimethy loctadecy lammonium chloride

(Dodecylbenzyl)triethylammonium chloride

( Dodecylmethylbenzy 1 ) trimethy lammonium chloride

(Ethylbenzyl)dimethyl(mixed alkyl) ammonium chloride

*Carboxylic acid esters and ethers :

*Dinonylphenol, ethoxylated

*Dodecylphenol, ethoxylated

*Iso-octylphenol, ethoxylated

*Nonylphenol, ethoxylated

*Phenol, ethoxylated

AAC, BC, BRD, CUL, FIN, ONX, PCS, PG, RH, RTF, TXT,

VAC, WSN. APX, ONX, PCS, RET, WSN. DEP, FIN, ONX, SDH, WSN. CUL, FIN, ONX, VAC, WSN. BC, CUL, NLC, RCD, WTC.

NLC.

PCS, TXT,

UVC

NLC.

FIN.

DEP.

CUL, ONX.

BC, HK.

WTC.

WTC.

CIB.

CIB.

TXT.

G.

RH. RH. APX.

TXT.

BC, CRT. SNW, WSN. ONX, RH. TXT.

TXT.

COM.

AML.

PC.

RH.

ONX.

G, JCC, STP.

G, MON, PCS, UCC.

APX, CIB, DRW, NOP, CMC.

APD, CIB, CLY, DOW, DRW, G, HFC, JCC, MON, NLC, CMC,

PCS, RH, RTF, STP, UCC. APD, G, JCC, NOP, UCC.

SURFACE-ACTIVE AGENTS

147

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

BENZENOID SURFACE- ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated--Continucd

*Carboxylic acid esters and ethers — Continued *Other earboxylic acid esters and ethers : Alkylphenol - formaldehyde, alkoxylated :

(Mixed aliyl) phenol - formaldehyde, aLkoxylated

Nonylphenol - formaldehyde, alkoxylated

tert-Octylphenol - formaldehyde, ethoxylated

Pentylphenol - formaldehyde, alkoxylated

Diisobutylphenol, ethoxylated

(Mixed alkyl)phenol, ethoxylated

(Mixed alkyljphenol, ethoxylated, butyl ether

(Mixed aliyl)phenoxypoly(ethyleneoxy) ethyl chloride

Nonylphenol, ethoxylated and propoxylated

Nonylphenoxypoly(ethyleneoxy) ethyl iodide

n-Octylphenol, ethoxylated

Pentylphenol, ethoxylated

Phthalic acid, octadecyl ester, potassium salt

Tetradecylphenol, ethoxylated

Tridecylphenol, ethoxylated

Xylenol, ethoxylated

All other

*Phosphoric and polyphosphoric acid esters :

Dinonylphenol, ethoxylated and phosphated

Hexylphenol, ethoxylated and phosphated

*Nonylphenol, ethoxylated and phosphated

Nonylphenol, ethoxylated and phosphated, barium salt

Octylphenol, ethoxylated and phosphated

Octylphenol, ethoxylated and phosphated, magnesium salt- Phenol, ethoxylated and phosphated

Sulfated and Sulfonated

*ALkylphenols, ethoxylated and sulfated:

Dodecylphenol, ethoxylated and sulfated

Dodecylphenol, ethoxylated and sulfated, potassium salt-

(Mixed alkyl)phenol, ethoxylated and sulfated

»Nonylphenol, ethoxylated and sulfated, and salts:

Nonylphenol, ethoxylated and sulfated

Nonylphenol, ethoxylated and sulfated, ammonium salt —

Nonylphenol, ethoxylated and sulfated, sodium salt

Nonylphenol, ethoxylated and sulfated, triethanolamine salt.

n-Octylphenol, ethoxylated and sulfated

*Benzenesulfonates :

*Benzene-, cumene-, toluene-, and xylenesulfonates :

Benzenesulfonic acid, sodium salt

Cumenesulfonic acid, ammonium salt

2,4- Dinitrobenzenesulfonic acid, sodium salt

Ethylene glycol dibenzenesulfonate

Toluenesulfonic acid

p-Toluenesulfonic acid, hexadecyltrimethylammonium salt.

Toluenesolfonic acid, potassium salt

Toluenesulfonic acid, sodium salt

*Xylenesulfonic acid, ammonium salt

Xylenesulfonie acid, potassium salt

*Xylenesulfonic acid, sodium salt

^Branched chain alkylbenzenesulf onates :

Decylbenzenesulfonic acid, sodium salt

Didodecylbenzenesulfonic acid

Didodecylbenzenesulfonic acid, sodium salt

*Dodecylbenzenesulfonic acid

Dodecylbenzenesulfonic acid, ammonium salt

Dodecylbenzenesulfonie acid, butylamine salt

^Dodecylbenzenesulfonic acid, calcium salt

Dodecylbenzenesulfonic acid, diethanolamine con- densate, fatty acid monoester. Dodecylbenzenesulfonic acid, diethanolamine salt

NLC, RTF.

RTF.

SDW.

RTF.

G, RH.

G, PCS.

RH.

G.

STP.

G.

ICI.

RTF.

CIB.

0R0.

PCS.

NLC.

RH.

RZL.

G, NLC, RTF, RZL, SEY, TCC, TCI, TXT, WAY, WSN, WTC.

G.

RH.

G, LEV, TCI.

STP.

G.

CRT, G, OMC, WTC.

CIB, MYW, RCD, STP, TXT.

STP.

RH, TXT.

NES, UPF.

STP.

NES.

NES.

RCD.

FIN.

MTW, NES, RCD, STP, WTC.

CO, NES, PIL, RCD, STP, WTC.

ATR, CO, NES, RCD, STP, WTC.

MTW, NES, STP.

ATR, CO, MYW, NES, PIL, RCD, STP, WTC.

MON.

CO. CO. ARD, CO, CRT, LEV, MON, NAC, PIL, RCD, RTF, SEY, STP,

TCI, TDC, TEN, TXT, WTC. ARL. WTC.

APD, CO, NLC, RCD, RH, RTF, SMC, STP, WTC. MAH.

PCS, VAL, WON.

148

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Chemical

BENZENOID SURFACE- ACTIVE AGENTS- -Continued

Sulfated and Sulfonated--Continuei

*Benzenesulf onates — Continued

*Branehed chain aliylbenzenesulfonates--Continued

Dodecylbenzenesulfonie acid, ethylenediamine salt

Dodecylbenzenesulfonic acid, isopropanolamine salt

*Dodeeylbenzenesulfonic acid, isopropylamine salt

*Dodeeylbenzenesulfonic acid, (mixed aliyl) amine salt

Dodecylbenzenesulfonie acid, potassium salt

Dodecylbenzenesulfonic acid, propoxylated ethylene- diamine salt.

^Dodecylbenzenesulfonic acid, sodium salt

Dodecylbenzenesulfonie acid, strontium salt

^Dodecylbenzenesulfonic acid, triethanolamine salt

Nonylbenzenesulfonic acid, sodium salt

Pentadeeylbenzenesulfonic acid, potassium salt

Pentadecylbenzenesulfonic acid, sodium salt

Pentylbenzenesulfonic acid, sodium salt

Tridecylbenzenesulfonie acid

Tridecylbenzenesulfonic acid, ammonium salt

Tridecylbenzenesulfonie acid, sodium salt

*Straight chain alkylbenzenesulfonates :

^Dodecylbenzenesulfonie acid

Dodecylbenzenesulfonie acid, ammonium salt

Dodecylbenzenesulfonic acid, isopropylamine salt

*Dodecylbenzenesulfonie acid, sodium salt

^Dodecylbenzenesulfonic acid, triethanolamine salt

Tridecylbenzenesulfonic acid

Tridecylbenzenesulfonic acid, sodium salt

*Lignosulf onates :

Lignosulfonic acid, aluminum salt

Lignosulfonic acid, ammonium salt

*Lignosulfonie acid, calcium salt

Lignosulfonic acid, chromium salt

Lignosulfonic acid, iron salt

Lignosulfonic acid, magnesium salt

^Lignosulfonic acid, sodium salt

*Naphthalenesulf onates :

Benzylnaphthalenesulfonic acid

Butylnaphthalenesulfonic acid

*Butylnaphthalenesulfonic acid, sodium salt

DibutyLnaphthalenesulfonic acid

Didodecylnaphthalenesul fonic acid, sodium salt

*Diisopropylnaphthalenesn1 fonie acid

Diisopropylnaphthalenesulfonic acid, sodium salt

Dipentylnaphthalenesulfonic acid

Dipentylnaphthalenesulfonic acid, ammonium salt

Dipentylnaphthalenesulfonic acid, (mixed aliyl) amine salt

Isopropylnaphthalenesul fonic acid

Methylenebis(2-naphthalenesulfonic acid)

6,6'-Methylenebis(2-naphthalenesulfonic acid), calcium salt.

MethyLnaphthalenesulfonic acid, sodium salt

JfethylnonyLnaphthalenesulfonic acid, sodium salt

Tetrahydronaphthalenesulfonic acid, sodium salt

Other benzenoid surface-active agents, sulfated and sulfonated :

ButyLhydroxybiphenylsulfonic acid

Dodecyldiphenyloxidedisulfonic acid, sodium salt

HpptnHppyliTigt.hylbgngiiiririg'an'liTipgiilfnrnp acid, Sodium

salt. n-Octylphenol, ethoxylated and sulfonated

Petroleumsulfonic acid, water soluble (acid layer), sodium salt.

5-Sulfophthalic acid, diaDsyl ester, potassium salt

Trichlorophenol sulfate, ethanolamine salt

Manufacturers ' identification codes (according to list in table 22)

APD.

SMC.

APD, AHD, RCD, RTF, SNW, STP, WTC.

PCS, RTF, STP, WTC.

VAL.

PCS.

AAC, APX, ARD, ARL, ATR, CO, CP, CRT, DEP, EFH, EMK, HLI, HRT, ICI, LEV, MON, NAC, NOP, PG, PIL, RCD, SEY, STP, SWT, TEN, TXT, WIC, WON, WTC.

RTF.

AML, ARD, ARL, ATR, CRT, HLI, NAC, PCS, PEK, PIL, RCD, RTF, SOS, STP, SWT, TXT, VAC, WON, WTC.

WTC.

STP.

CP.

MON.

RCD.

RCD.

CP, TXT, WTC.

ARD, CO, HLI, LEV, NAC, PIL, PRX, RCD, RTF, RZL, STP,

TCI, TXT. CTL, TXT. CTL, RCD. ARD, ATR, CO, CP, CTL, LEV, NAC, PG, PIL, PRX, RCD,

STP, SWT, TXT, UNP. ARD, ATR, CTL, NAC, RCD, RZL, STP, SWT, TXT. RCD. BLA, CP, PRX, RCD, TXT, UCC.

MAR.

CRZ.

CRZ,

CWP, LKY,

LPC, MAR, PSP

MAR,

PSP.

CRZ,

PSP.

LPC,

MAR.

CRZ,

CWP, MAR,

WVA.

G.

SCP.

CLD,

CMG, GGY,

PFZ.

G, MRA, S.

PFZ.

DUP,

G, GRD, NAC.

G, PFZ.

GGY.

NLC.

NLC.

DUP,

NOP, ONX.

DUP.

DUP.

UDI.

UDI.

DUP.

ICO,

RBC.

DOW.

CIB.

SIN, SON.

SURFACE-ACTIVE AGENTS

149

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Manufacturers ' identification codes (according to list in table 22)

NONBENZENOID SURFACE-ACTIVE AGENTS Not Sulfated or Sulfonated

*Amides, amines, and quaternary ammonium salts:

*Amines, amine oxides, and amine salts (except hetero- cyclic) : *Amine salts of fatty acids (anionic):

Coconut oil acids, triethanolamine salt

Oleic acid, diethylamine salt

Oleic acid, N-(tallow allsyl ) trimethylenedianri ne salt.

Oleic acid, triethanolamine salt

Stearic acid, N,N,N',N'-tetrakis(2-hydroxyethyl)- ethylenediamine salt.

Stearic acid, triethanolamine salt

^Amines, not containing oxygen, and salts thereof: "Amine salts ( cationic ) :

(Coconut oil allsyl) amine acetate

N-( Coconut oil allsyl) trimethylenediamine acetate---

( Hydrogenated tallow aliyl)amine acetate

(9-0ctadecenyl) amine acetate

Octadecylamine acetate

Octylamine acetate

(Soybean oil allsyl) amine acetate

(Tallow aliyl)amine acetate

N-(Tallow alkyl) trimethylenedianri ne acetate

N-(Tallow aliyl)trimethylenediamine naphthenate

"Diamines and polyamines :

N-( Coconut oil alliyl ) trimethylenedianri ne

N-(Mixed allsyl) polyethylenepolyamine

*N-(9-0ctadecenyl)trimethylenediamine

N-(Soybean oil allsyl) trimethylenediamine

N-( Tallow allsyl )dipropylenetriamine

*N-( Tallow allsyl) trimethylenediamine

"Primary monoamines :

*( Coconut oil aliyl)amine

(Cottonseed oil allsyl) amine

"Dodecylamine 7

Hexadecylamine

*( Hydrogenated tallow aliyl)amine

(Mixed allsyl) amine

9-0ctadecenylami ne

Octadecylamine

Octylamine

(Soybean oil alkyl) amine

(Tall oil aliyl)amine

*( Tallow allsyl) amine

"Secondary and tertiary monoamines :

Bis(coconut oil allsyl)amine

Bis ( hydrogenated tallow allsyl)amine

N, N-Dimethyl( coconut oil aliyl)amine

N, N-Dimethyldodecylamine

N, N- Dime thy lhexadecylamine

N,N-Dimethyl(hydrogenated tallow aliyl)amine

N,N-Dimethyl(inixed alily)amine

N, N-Dimethyloctadecylami ne

N,N-Dimethyl( soybean oil allsyl) amine

N, N-Dimethyltetradecylami ne

N-Methylbis( coconut oil alkyl)amine

N-Methy Ibis ( hydrogenated tallow allsyl) amine

N-Methyldioctadecylamine

Tridodeeylami ne

Trioctylamine

Tris( hydrogenated tallow alkyl)amine

"Oxygen- containing amines and ami ne oxides :

N, N-Bis ( 2-hydroxyethyl ) dodecylami ne

N,N-Bis(2-hydroxyethyl)octadecylamine

N, N-Bis (2-hydroxyethyl) octylamine

N, N-Bis (2-hydroxyethyl) (tallow aliyl)amine

N,N-Bis(2-hydroxyethyl)(tallow allsyl) amine acetate—

WTC.

FOR.

DOM,

HAL,

TCC,

TXT.

ICI.

AML,

GLY,

TCC.

ADM,

ARC,

FOR.

ARC.

ADM,

ARC.

GNM.

ACY,

ARC.

ARC.

ARC.

ADM,

ARC,

FOR,

GNM.

ARC,

FOR.

APD,

FOR.

ARC,

FOR,

GNM.

CCW.

ARC,

FOR,

GNM.

ARC.

GNM.

ARC,

FOR,

GNM.

ADM,

ARC,

CGL,

FOR, GNM.

FOR.

ADM,

ARC,

FOR,

GNM.

ADM,

ARC,

FOR.

ADM,

ARC,

CGL,

FOR, GNM, HUM, VGC

GNM.

ARC,

FOR,

GNM.

ADM,

ARC,

FOR,

GNM.

ARC,

RH,

UCC.

ARC,

CGL.

FOR,

GNM.

ADM,

ARC,

CGL,

FOR, GNM, HUM.

ARC,

FOR.

ARC.

PG.

BC.

ARC,

BC.

ARC.

BRD,

PG,

SDH,

X.

ARC,

BC,

PG.

ARC.

ARC,

BC.

FOR,

GNM.

ARC,

FOR,

GNM.

FOR.

GNM.

GNM.

GNM.

FIN.

FIN.

FIN.

FIN.

PG.

150

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B -Surface-active agents for which U.S. production or sales were reported, identified by lAtf^c i»d. j manufacturer, 1 965— Continued

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued Not Sulfated or Sulfonated- -Continued

*Amides, amines, and quaternaiy ammonium salts— Continued *Amines, amine oxides, and amine salts (except hetero- cyclic)— Continued *Oxygen-containing amines and amine oxides— Continued

(Coconut oil alkyl)amine, ethoxylated

(Coconut oil alkyl)amine, ethoxylated, acetate

Hexadecyldimethylamine oxide

( Hydrogenated tallow alkyl)amine, ethoxylated—--— N-(2-Hydroxyethyl)-N,N',N'-tris(2-hydroxypropyl)- ethylenediamine .

3-Lauramido-N, N-dimethylpropylamine oxide

*(Mixed alkyl)amine, ethoxylated

Octadecylamine, ethoxylated

Poly ethy lenepolyamine , alkoxylated

Rosin amine, ethoxylated

(Soybean oil aliyl) amine, ethoxylated

*(Tallow alkyl)amine, ethoxylated

N-(Tallow aliyljtrimethylenediamine, ethoxylated— - N, N, N', N '-Tetrakis( 2-hydroxyethyl)ethylenediamine-- N, N, N ' , N '-Tetrakis ( 2-hydroxypropyl) ethylene- diamine, propoxylated and ethoxylated.

Triethanolamine, ethoxylated

All other

*Fatty acid - alkanolamine condensates : *Diethanolamine condensates :

*Capric acid

Castor oil acids

*Coconut oil acids (amine/acid ratio=2/l)

Manufacturers' identification codes (according to list in table 22)

*Coconut oil acids (amine/acid ratio=l/l)-

Coconut oil acids (all other ratios)

Coconut oil and tallow acids (amine/acid ratio=2/l) — *Laurie acid

Laurie and myristic acids

Linoleic acid

Mixed fatty acids

*01eic acid (amine/acid ratio=2/l)- *01eic acid (amine/acid ratio=l/l)-

Palmitic acid

Pelargonic acid

♦Stearic acid

*Tall oil acids

Tallow acids

♦Other alkanolamine condensates :

*Coeonut oil acids - ethanolamine condensate

Coconut oil acids - isopropanolamine condensate

♦Laurie acid - ethanolamine condensate

♦Laurie acid - isopropanolamine condensate

Laurie and myristic acids - isopropanolamine condensate .

Myristic acid - ethanolamine condensate

Myristic acid - isopropanolamine condensate

Oleic acid - ethanolamine condensate

isopropanolamine condensate

ethanolamine condensate (amine/acid

Oleic acid ♦Stearic acid

ratio=l/l) . Stearic acid

ratio=l/2). All other

APD, ARC, NLC, VAC.

RPC.

ONX.

CIB, TCH, VAC.

NLC.

SNW.

APD, CIB, G, NOP, RH.

ARC, ICI.

NLC.

HPC, PCS, RTF.

ARC, VAC.

ADM, ARC, CIB, DUP.

ARC.

NLC.

WYN.

JCC.

GGY, PCS, RZL.

PCS, VAL.

AML, ARD, BSC, CIB, CLI, CRT, CTL, DEP, DRW, EFH, HLI,

HRT, JOR, KNP, LEV, LUR, MOA, NOP, ONX, PC, PCS, PNX,

RCD, RZL, SBC, SEY, STP, SWT, TCC, TXC, UNN, UVC,

VAC, VND, WIC, WTC. APX, ARD, ARL, CLI, CTL, DRW, EMK, GGY, HLI, MOA, MRV,

NOP, ONX, PCS, PEK, QCP, RCD, RTF, RZL, SBC, SEY,

STP, TXT, VAC. JRG, PCS. PG. ARD, CLI, CTL, HLI, MOA, ONX, PCS, PG, RCD, RTF, RZL,

SBC, STP, TXT, WON, WTC. CLI. VND.

BSC, HLI, STP, WTC.

CCW, CLI, HLI, MRA, ONX, SEY, STP, UVC, VAC, WTC. CUL, GGY, NOP, PCS, SBC, SCP, SEY, SWT, TCC, TXT, VAC. CMG. EMR. AML, BSC, CLI, DEP, EMR, GGY, GLY, JOR, MRA, NOP, ONX,

RPC, SCO, SEY, TXC, UVC, VAL, WTC. EFH, MRA, MRV, UVC, WTC. PCS, RPC.

ethanolamine condensate (amine/acid

APX, CCL, CTL, HRT, MOA,

LEV, STP.

CTL, PCS, TXT, WTC.

ARD, CLI, MOA, PCS, WTC.

TXT.

WTC. ARD. ARD. WTC. ARC, ARD, MOA, VND, WTC.

GLY, WTC.

CLI, GLY.

PCS, PG, STP, TXT, UVC, VND.

SURFACE-ACTIVE AGENTS

151

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated— Continued

*Amides, amines, and quaternary ammonium salts — Continued *Fatty acid - diamine and polyamine condensates : Adipic and stearic acids - diethylenetriamine condensate.

Coconut oil acids - diethylenetriamine condensate

Coconut oil acids - N, N-dimethyltrimethylenediamine condensate.

Mixed fatty acid - polyaliylenepolyamine condensate

Oleic acid - (2-aminoethyl)piperazine condensate

*01eie acid - diethylenetriamine condensate

Oleic acid - diethylenetriamine condensate, acetic

acid salt. Oleic acid - N, N-dimethyltrimethylenediamine conden- sate. Oleic acid - N, N-dimethyltrimethylenediamine conden- sate, caproic acid salt. *01eie acid - ethylenediamine condensate (amine/acid ratio=l/2).

Pelargonic acid - tetraethylenepentamine condensate

Stearic acid - diethylenetriamine condensate

Stearic acid - N,N-diethylethylenediamine condensate

Stearic acid - N,N'-diethylethylenediamine condensate ( amine/acid ratio=l/2 ) .

Stearic acid - dipropylenetriamine condensate

Stearic acid - ethylenediamine condensate (amine/acid ratio=l/2).

Stearic acid - tetraethylenepentamine condensate

Tall oil acids - diethylenetriamine condensate

All other

*Fatty acid - diamine and polyamine condensates, alkoxy- lated: Coconut oil acids - diethylenetriamine condensate,

polyethoxylated . Coconut oil acids - ethylenediamine condensate, mono-

ethoxylated. Mixed fatty acids - alkylenediamine condensate, poly- ethoxylated. *01eic acid - ethylenediamine condensate, monoethoxy- lated. Palm oil acids - ethylenediamine condensate, mono-

ethoxylated. Stearic acid - diethylenetriamine condensate, poly- ethoxylated . *Stearic acid - ethylenediamine condensate, mono- ethoxylated . Stearic acid - ethylenediamine condensate, poly- ethoxylated. ^Heterocyclic amines and quaternary ammonium salts : * Imidazoline derivatives :

l-(2-Aminoethyl)-2-heptadecyl-2-imidazoline

l-(2-Aminoethyl)-2-(mixed al)syl)-2-imidazoline

l-(2-Aminoethyl)-2-nor(tall oil aliyl)-2-imidazoline- l,l-Bis(carboxymethyl)-2-undecyl-2-imidazolinium

chloride, disodium salt. 1, 1-Bis( carboxymethyl) -2-undecyl-2-imidazolinium

hydroxide, disodium salt. 1- Carboxymethyl-2-heptadecyl-l- ( 2-hydroxyethyl) -2- imidazolinium hydroxide, sodium derivative, sodium salt. l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2-

imidazolinium chloride, sodium salt. l-Carboxymethyl-l-( 2-hydroxyethyl) -2-nonyl-2-

imidazolinium hydroxide, sodium derivative, sodium salt. l-Carboxymethyl-l-( 2-hydroxyethyl) -2-undecyl-2-

imidazolinium hydroxide, sodium derivative, sodium salt.

APX, JRG,

NOP. TXT.

NLC. PCS. APD, PCS.

HDG,

PCS,

TXT.

CCW,

SNW.

RCD.

CCW,

GLY,

HDG.

ICI. APX, CBP. SNW.

CRT,

DEP,

HRT,

ONX,

QCP, S.

JOR. CCW,

CTN,

GLY,

ICI,

NOP.

ICI, NCW. EMR,

ONX. TXT,

VAL,

VND,

WM.

TCC.

NOP,

RFC.

NLC.

CLD,

DEX,

NOP,

SOC,

TNA.

APX.

TCC.

AML,

CLD,

CMG,

CST,

DEP,

DEX, ICI, MRA, NOP, S, SNW

APD,

TCC.

TXT. RTF. NLC. PCS.

PCS. MIR.

152

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Chemical

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated--Continued *Amides, amines, and quaternary ammonium salts — Continued heterocyclic amines and quaternary ammonium salts — Con. "Imidazoline derivatives — Continued

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2-

imidazolinium bromide. 2-(8-Heptadeeenyl)-l-(2-hydroxyethyl)-2-imidazoline-

2-(8-Heptadecenyl)-2-imidazoline

*2-Heptadecyl-l-(2-bydroxyethyl)-2-imidazoline

2-Heptadecyl-2-imidazoline

l-(2-Hjrdroxyetnyl)-2-nonyl-2-imidazoline

l-(2-Ifydroxyetnyl)-2-nor( coconut oil alkyl ^-imid- azoline. l_(2-[tydroxyethyl)-2-nor(tall oil aliyl) -2-imid-

azoline. l-(2-Ifydroxyethyl)-2-tridecyl-2-imidazolinium chlo- ride.

l-(2-Ifydroxyetbyl)-2-undecyl-2-imidazoline

2-(ll-Ifydroxy-8-heptadecenyl)-2-imidazoline

Rosinpolyamidoimidazoline

3- [2- (2-Undecyl-2-imidazolin-l-yl)ethoxy] propionic acid. *Mbrpholine, oxazoline, and piperazine derivatives:

N-Dodeeylmorpholine

2-( 8-Heptadecenyl ) -4,4-bis ( hydroxymethyl) -2-oxazo-

line. 2-(8-Heptadecenyl)-4-hydroxymethyl-4-methyl-2-oxazo

line.

N-Hexadecylmorpholine

Mixed fatty piperazines

N-(Soybean oil aliy 1 )morpholine

"Quaternary ammonium salts (except heterocyclic):

*Bis(coconut oil alkyljdimethylammonium chloride

*Bis(hydrogenated tallow alkyl)dimethylammonium chlo- ride.

*Dimethyldioctadecylammonium chloride

*Dodecyltrimethylammonium chloride

"Oxygen-containing compounds:

Bis(2-hydroxyethyl, ethoxylated)methyl(9-octa-

decenyl)ammonium chloride. Bis( 2-hydroxyethyl, ethoxylated)methyloctadecyl-

ammonium chloride.

N-(3-Coconut oil amidopropyl)betaine

(Coconut oil alkyl)betaine

(Coconut oil alkyl)bis(2-hydroxyethyl, ethoxylated)

methylammonium chloride.

C-Decylbetaine

C-Dodecylbetaine

N-Dodecylbetaine

C-Hexadecylbetaine

(2-Ifydroxyethyl)dimethyl(stearamidopropyl) ammonium

dihydrogen phosphate. ( 2-Hydroxyethyl) dimethyl( stearamidopropyl) ammonium

nitrate. 2-}fydroxytrimethylenebis[( coconut oil aHsyl)di-

methylammonium chloride] .

Mixed fatty betaines

C-Octadecylbetaine .

Triethyl(octadecyloxymethyl) ammonium chloride

Other quaternary ammonium salts :

(Coconut oil aliyl)trimethylammonium chloride

Didodecyldimethylammonium bromide

Dimethylbis( soybean oil aliyl) ammonium chloride

Dodecyltrimethylammonium bromide

Ethyldimethyl(9-octadecenyl) ammonium bromide

Ethyldimethyl( soybean oil alkyl) ammonium bromide — Ethylhexadecyldimethylammonium bromide

Manufacturers' identification codes (according to list in table 22)

NLC, PCS, UVC.

HDG, MOA, ONX, RZL, TXT.

GGY,

PCS,

UVC.

GRD.

UVC.

UVC.

BC.

COM,

UVC.

COM,

UVC.

APD.

TXT.

APD.

ARC,

FOR,

GNM,

VAC.

ADM,

ARC,

FOR,

GNM, VAC

FOR,

GNM,

PC.

ARC,

FOR,

GNM.

RCD. CUL. ARC, VAC.

DUP. DUP. RCD. DUP. ACY.

ACY.

TXT. DUP. DAN.

ARC, GNM.

ONX.

ARC.

DUP.

ONX.

BC.

FIN.

SURFACE-ACTIVE AGENTS

153

TABLE 19B. —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965— Continued

Manufacturers' identification codes (according to list in table 22)

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated— Continued

•Amides, amines, and quaternary ammonium salts — Continued •Quaternary ammonium salts (except heterocyclic) — Con. •Other quaternary ammonium salts — Continued

Hexadecyltrimethylammonium bromide

Hexadecyltrimethylammonium chloride

Hexadecyltrimethylammonium stearate

( Hydrogenated tallow aliyl )trime thy lammonium chlo- ride.

Methyltriocty lammonium chloride

lfethyltris( mixed aliyl) ammonium chloride

N, N, N ' , N' , N' -Pentamethyl-N- ( tallow aliyl) trimethyl- enebis [ammonium chloride].

Trimethyl(mixed aliyl) ammonium chloride

Trimetbyloctadecylammonium chloride

Trimethyl( soybean oil aliyl) ammonium chloride

Trimethyl( tallow aliyl) ammonium chloride

All other

•N-Substituted amino acids and polypeptides :

N-[ 2-( Carboxymethylamino) ethyl] -N-( 2-hydroxyethyl) - coconut oil amide, sodium salt.

N-( Coconut oil acyl)sarcosine

N-( Coconut oil acyl)sarcosine, sodium salt

N-( Coconut oil aliyl) -|3 -alanine

N-Dodecyl-3-iminodipropionic acid

N-Dodecyl-3- inn nodipropionic acid, sodium salt

N-(2-Hydroxyethyl)-N-(2-lauramidoethyl)-|3-alanine

N-(2-Hydroxyethyl)-N-(2-stearamidoethyl)glycine

N-Lauroylpolypeptide

*N-Iauroylsarcosine, sodium salt

N-Oleoylpolypeptide

N-Oleoylpolypeptide, sodium salt

N-Oleoylsarcosine, sodium salt

Polypeptide

N-Stearoylsarcosine, sodium salt

N-( Tallow aliyl) -3-i" mi nodipropionic acid, sodium salt •Other amides, amines, and quaternary ammonium salts: N, N-Bis( 2-hydroxyethyl) -2- ( stearamidomethoxy ) ethyl-

amine. N, N-Bis( 2-hydroxyethyl) -2-( stearamidomethoxy ) ethyl-

amine - melamine ether condensate. Bis [octadecenyloxypolyethylene glycol] ester of 1,6-

hexamethylenedicarbamic acid. Coconut oil acids - ethanolamine condensate, ethoxy-

lated. Coconut oil acids - isopropanolamine condensate, ethoxylated and propoxylated. •Hydrogenated tallow acids - ethanolamine condensate, ethoxylated.

•Oleic acid - ethanolamine condensate, ethoxylated

Oleic acid - methanolamine condensate, ethoxylated

Stearic acid - N- ( 2-eyanoethyl ) diethylenetriami ne

condensate (amine/acid ratio=l/2). Tall oil acids - ethanolamine condensate, ethoxylated- •Carboxylic acid esters :

•Ethylene glycol and diethylene glycol esters :

Diethylene glycol distearate

methylene glycol monoester of coconut oil acids

Diethylene glycol monoester of tallow acids

•Diethylene glycol monolaurate

•Diethylene glycol mono-oleate

Diethylene glycol monoricinoleate

•Diethylene glycol monostearate

Diethylene glycol sesquilaurate

Diethylene glycol sesquioleate

Diethylene glycol sesquistearate

Diethylene glycol tall oil ester

DUP,

FIN, I CI.

ARC.

FIN.

ARC,

FOR.

GNM.

VAC.

ARC,

GNM.

GNM.

ARC,

GNM.

ARC,

FOR.

ARC,

FOR, GNM.

CGL.

TCC.

GGY.

HMP.

GNM.

GNM.

GNM.

UVC.

G.

MYW.

CP,

GGY, HMP, ONX.

MYW.

I1C.

G, GGY.

MYW.

GGY.

GNM.

CIB.

CIB.

CIB.

DRW,

STP.

STP.

ARC,

DRW, NOP.

ARC,

DRW, G.

G.

CIB.

JCC.

ARC.

DRW.

DRW.

ARC,

CCW, DRW, EMR,

GLY,

HAL,

HDG,

KAL,

NOP,

WTC

ARC,

HAL, WTC.

GLY.

AML,

ARC, CCW, CLI,

HAL,

NOP,

PCS,

QCP,

SEY,

UVC

VAL, VND, WTC.

GLY.

^

GLY.

GLY,

WM.

HDG,

QCP, WTC.

154

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued

Not Sulfated or Sulfonated--Continued

♦Carboxylic acid esters — Continued ♦Ethylene glycol and diethylene glycol esters — Continued

♦Ethylene glycol distearate

Ethylene glycol mono-oleate

♦Ethylene glycol monostearate

Ethylene glycol sesquistearate

♦Glycerol esters :

♦Complex glycerol esters :

Glycerol diacetyl tartrate monostearate

Glycerol lactate palmitate

Glycerol lactate stearate

Glycerol maleate mono-oleate

Glycerol monoester, acetylated

Glycerol mono-oleate, acetylated

♦Glycerol esters of chemically defined acids :

Glycerol dioleate

Glycerol distearate

Glycerol monocaprylate

♦Glycerol monolaurate

♦Glycerol mono-oleate

Glycerol monoricinoleate

♦Glycerol monostearate

♦Glycerol esters of mixed acids :

Glycerol diester of lard acids

Glycerol monoester of coconut oil acids

Glycerol monoester of cottonseed oil acids

Glycerol monoester of hydrogenated cottonseed oil

acids. Glycerol monoester of hydrogenated soybean oil acids

Glycerol monoester of lard acids

Glycerol monoester of mixed fatty acids

Glycerol monoester of peanut oil acids

Glycerol sesquiester of mixed fatty acids

♦Polyethylene glycol esters :

♦Polyethylene glycol esters of chemically defined acids :

♦Polyethylene glycol dilaurate

♦Polyethylene glycol dioleate

♦Polyethylene glycol distearate

Polyethylene glycol methylcarbitol maleate

♦Polyethylene glycol monolaurate

♦Polyethylene glycol mono-oleate

Polyethylene glycol monopalmitate

Polyethylene glycol monoricinoleate

♦Polyethylene glycol monostearate r

Polyethylene glycol pelargonate

Polyethylene glycol sesquioleate

♦Polyethylene glycol esters of mixed acids :

♦Polyethylene glycol ester of castor oil acids

♦Polyethylene glycol ester of coconut oil acids

♦Polyethylene glycol ester of rosin acids

♦Polyethylene glycol ester of tall oil acids

♦Polyethylene glycol ester of tallow acids

Polyethylene glycol monoester of soybean oil acids- All other

ARC, EMR, HAL, HDG.

PCS.

ARC, CCW, CLI, EFH, GLY, HAL, HDG, KNP, VND, WM.

WM.

DRW, PCS, WTC. DRW, GLD. APD, GLD. NOP, WTC.

EK.

ARC, HAL.

APX, ARC, PCS.

ARC.

ARC, GLX, HAL, KNP.

APD, ARC, CCW, DRW, EFH, EK, EMR, GLY, HAL, HDG, SWT,

WM. CCW. ARC, CCW, CHL, CRT, DRW, EK, EMR, GLY, HAL, HDG, JRG.

LUR, MRA, NOP, NW, PCS, PG, SNW, SWT, TCC, UVC, VND.

WM, WTC, x.

PCS.

DRW, GLY, HDG, SWT, WM.

DRW, EK, PCS.

LEV.

DRW.

EK, GLD, PCS.

EFH, EK, GLD, HDG, LEV, SWT, WTC.

DRW.

APD.

ARC, DEX, EFH, GLY, HAL, HDG, JOR, NOP, PCS, WM. ARC, CLD, EFH, GGY, GLY, HAL, HDG, NOP, PCS, RZL, SM,

UVC, VND. ARC, GLY, HAL, HDG, PCS, QCP. CCA. AAC, ARC, BSC, CCA, DEX, DRW, GGY, GLY, HAL, HDG, JOR,

KNP, NOP, PCS, SYC, TCH, TXT, UVC, WM. AAC, ARC, CCA, CLD, CRC, CRT, DEX, DRW, EMR, G, GGY,

GLY, HAL, HDG, I CI, NOP, ONX, PCS, SM, SWT, SYC, TCH,

UVC, VAC, WM, WTC. APD.

AAC, ARC, BAC, NOP. AML, APD, ARC, CRT, DEP, DEX, DRW, EMR, G, GGY, GLY,

HAL, HDG, ICI, KNP, NOP, ONX, PC, PCS, PD, RH, TCC,

TCH, VND, WTC. EMR. PCS.

G, GGY, GLY, HAL, NOP, WTC.

ARC, ARL, DRW, EMR, GLY, NOP, ONX, PG, VND.

APD, HPC, NLC, CJCP.

AML, APD, APX, ARC, DRW, GLY, HDG, MON, NOP, RTF, SOS,

TCH, WTC. DRW, ONX, SOS. DRW. GLY, PCS, SYC.

SURFACE-ACTIVE AGENTS

155

TABLE 19B —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued Not Sulfated or Sulfonated--Co.nti.nued

*Carboxylic acid esters — Continued *Polyglycerol esters :

Polyglyeerol distearate

Polyglyeerol lactate oleate

Polyglyeerol monoester of cottonseed oil acids

Polyglyeerol oleate

Other carboxylic acid esters: Anhydrosorbitol esters :

Arihydrosorbitol dioleate

Anhydrosorbitol mixed fatty acid ester

Arihydrosorbitol monolaurate

Anhydrosorbitol mono-oleate

Anhydrosorbitol monopalmitate

Anhydrosorbitol monostearate

Anhydrosorbitol sesquioleate

^Anhydrosorbitol tall oil ester

Anhydrosorbitol tetrastearate

^Anhydrosorbitol trioleate

Anhydrosorbitol triricinoleate

*Anhydrosorbitol tristearate

Ethoxylated anhydrosorbitol esters :

Ethoxylated anhydrosorbitol castor oil ester

*Ethoxylated anhydrosorbitol monolaurate

*Ethoxylated anhydrosorbitol mono-oleate

*Ethoxylated anhydrosorbitol monopalmitate

*Ethoxylated anhydrosorbitol monostearate

Ethoxylated anhydrosorbitol tall oil ester

*Ethoxylated anhydrosorbitol trioleate

^■Ethoxylated anhydrosorbitol tristearate

Ethoxylated sorbitol esters :

Ethoxylated sorbitol beeswax ester

Ethoxylated sorbitol distearate

Ethoxylated sorbitol hexaoleate

Ethoxylated sorbitol hexa(tall oil) ester

Ethoxylated sorbitol lanolin ester

Ethoxylated sorbitol mono-oleate

Ethoxylated sorbitol oleate stearate

Ethoxylated sorbitol pentalaurate

Ethoxylated sorbitol pentaoleate, acetylated

Ethoxylated sorbitol penta(tall oil) ester

Ethoxylated sorbitol tetra(laurate, oleate)

Ethoxylated sorbitol tetra(tall oil) ester

All other:

Anhydrosorbitol glycerol monolaurate

Calcium stearolactate

Coconut oil acids, ethoxylated methanol ester

Diisobutylene maleate

Ethoxylated glucose oleate

Ethoxylated glycerol mono- and diester of mixed fatty acid.

Ethoxylated 1,2-propanediol stearate

Methyl glucoside laurate

Methyl glucoside oleate

Pentaerythritol distearate

Polyalkylene glycol diglycolate

Polyalkylene glycol dimaleate

Polyaliylene glycol naphthenate

1,2-Propanediol distearate

1,3-Propanediol monoester of coconut oil acids--

*l,2-Propanediol monolaurate

1,2-Propanediol mono-oleate

»l,2-Propanediol monostearate

Propylene glycol monoesters

Sucrose esters of fatty acids

*Ethers :

*Castor oil, ethoxylated

n-Decyl alcohol, ethoxylated

Manufacturers ' identification codes (according to list in table 22)

PCS. DEW. DRW. DRW, HDG, VND, WTC.

APD.

GLY.

AAC, APD, GLY, HDG, PCS.

AAC, APD, DRW, GLY, HDG, PCS.

APD, GLY, PCS.

AAC, APD, DRW, GLY, HDG, PCS.

GLY.

APD, GLY, HDG, RTF.

APD.

AAC, APD, GLY, HDG, PCS.

APD.

APD, DRW, GLY, HDG, PCS.

APD.

AAC, APD, DRW, GLY, HDG, PCS, TCH.

AAC, APD, ARC, DRW, GLY, HDG, PCS, TCH.

AAC, APD, GLY, TCH.

AAC, APD, DRW, GLY, HDG, PCS, TCH.

APD, RTF, TCH.

AAC, APD, GLY, TCH.

AAC, APD, DRW, GLY, PCS, TCH.

APD. APD. APD. APD. APD. APD. APD. APD. APD. APD. APD. APD.

APD.

GLY.

DRW, JOR.

RH.

APD.

APD.

APD.

HDG.

HDG.

VAL.

NLC, RTF.

NLC.

APD.

HAL, PCS.

DRW.

ARC, HAL, SBC, WM.

ARC, HAL.

APD, ARC, CCW, EK, GLY, HAL, HDG,

GLD.

SUG.

JRG, PCS, PG, WTC.

AAC, APD, BAC, DRW, ICI, G, ICI, PCS.

NLC, NOP, PCS, RTF, TCH, VAC.

156

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

NONBENZENOID SURFACE-ACTIVE AGENTS- -Continued

Not Sulfated or Sulfonated--Cor\tinued

*Ethers — Continued

n-Decyl and n-octyl alcohols, ethoxylated

Deoyloxypoly(ethyleneoxy) ethyl chloride

*n-Dodecyl alcohol, ethoxylated

Glucose, ethoxylated

n-Hexadecyl alcohol, ethoxylated

Hydrogenated castor oil, ethoxylated

*Lanolin, ethoxylated

»Mixed linear alcohols, ethoxylated

Mixed linear alcohols, ethoxylated and propoxylated—

*9-0ctadecenyl alcohol, ethoxylated

*n-Octadecyl alcohol, ethoxylated

Polyethylene glycol tert-dodecyl thioether

Poly(mixed ethylene, propylene) glycol

Polypropylene glycol, ethoxylated

Ricinoleyl alcohol, propoxylated and ethoxylated

Rosin alcohol, ethoxylated

Sorbitol, ethoxylated

Sperm oil alcohol, ethoxylated

Tallow alcohol, ethoxylated

*Tridecyl alcohol, ethoxylated

Tridecyl alcohol, propoxylated and ethoxylated

Trimethylheptanol, ethoxylated

Trimethylnonyl alcohol, ethoxylated

Trimethylolpropane, alioxylated

All other

*Fatty, rosin, and tall oil acids, potassium and sodium salts :

Castor oil acids, potassium salt

Castor oil acids, sodium salt

*Coconut oil acids, potassium and sodium salts:

Potassium salt

Sodium salt

Corn oil acids, potassium salt

Corn oil acids, sodium salt

Laurie acid, potassium salt

Mixed vegetable fatty acids, potassium salt

Oleic acid, potassium salt

*01eic acid, sodium salt

Olive oil acids, sodium salt

Palm oil acids, sodium salt

Peanut oil acids, potassium salt

Rosin acids, potassium salt

Rosin acids, sodium salt

Soybean oil acids, potassium salt

♦Stearic acid, potassium and sodium salts:

Potassium salt

Sodium salt

*Tall oil acids, potassium and sodium salts:

*Tall oil acids, potassium salt

*Tall oil acids, sodium salt

Tallow acids, potassium salt

*Tallow acids, sodium salt

All other

♦Phosphoric and polyphosphoric acid esters :

Decyl, dodecyl, and octyl phosphate, morpholine salt

Decyl and octyl phosphate

Decyl polyphosphate, triethanolamine salt

Dodecyl alcohol, ethoxylated and phosphated

2-Ethylhexanol, ethoxylated and phosphated

*2-EtnyLhexyl phosphate, sodium salt

*2-Ethylhexyl polyphosphate

2-Ethylhexyl polyphosphate, sodium salt

Manufacturers ' identification codes (according to list in table 22)

G.

AAC, APD, DRW, DUP, GLY, JCC, NAC, OMC, PCS, UCC.

RH.

ADM, APD, CIB, ICI.

APD, VAC.

AAC, APD, DRW, VAC.

CO, G, JCC, MON, NLC, RH, RTF, SHC, STP, TCH, UCC,

WYN. STP.

AAC, ADM, APD, CIB, DUP, G, ICI, NOP, TCH, VAC. AAC, APD, CIB, DUP, HDG. MON.

nic, ucc, vac.

nlc, wyn.

PCS. HPC. VAC. DUP. ADM. AAC, APD, DRW, EFH, G, ICI, JCC, MON, NLC, CMC, PCS,

RTF, TCH, UCC. JCC, PCS. PCS. UCC. RTF. JCC, UCC, VAC, VPC.

BAC, SEA. MRV.

CP, JRG, LUR, PCH, PG, SWT.

CON, CP, JRG, LEV, PG, PRX.

ARL, PCH.

LUR.

BSC, DRW, NOP, USR, VAL.

AML, ARL, PCH, SWT.

AML, BSC, CCL, CIB, CPY, DAN, GYR, NOP, QCP, S, SHP,

USR, WIC, WTC, x.

LEV, LUR, MRV, NOP, SEA, SWT, USR, WTC, x. LUR. LUR.

KAL, SLC.

ASY, FRS, HPC.

ASY, CRT, HPC, MRA, PLC, PRX, QCP.

CON, DRW.

GYR, WTC.

GYR, LEV, MAL, NOP, WTC.

ASY, BSC, CON, DRW, FRS, GYR, HPC, LUR, PNX, QCP, TXT,

USR, VAL.

CPY, GYR, HPC, PCS, PRX, QCP, UNP.

ASY, CPY, GYR, PG, SWT.

ASP, CON, CP, FRS, GYR, JRG, LEV, LUR, NOP, PG, PLC,

PRX, QCP, SWT. SLC.

DUP.

UVC.

RCD.

G.

WAY.

RZL, SEY, UCC, UVC.

SEY, TCI, UVC.

SF.

SURFACE-ACTIVE AGENTS

157

TABLE 19B.

-Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers' identification codes (according to list in table 22)

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued

Not Sulfated or Su(/onated--Continued

*Phosphoric and poljrphosphoric acid esters — Continued

Hexyl polyphosphate, potassium salt

Mixed aliyl phosphate, diethanolamine salt

Mixed linear alcohols, ethoxylated and phosphated

Mixed mono- and dialiyl phosphate

Mixed mono- and dioctyl phosphate

Mixed mono- and dioctyl phosphate, potassium salt

9-0ctadecenyl alcohol, ethoxylated and phospnated

9-0etadecenyl phosphate

Octadecyl phosphate, triethanolamine salt

Octyl phosphate, allsylamine salt

Octyl phosphate, ethoxylated

Oct;,! polyphosphate

Octyl polyphosphate, potassium salt

Odyl polyphosphate, sodium salt

Trideeyl alcohol, ethoxylated and phosphated

Tris(castor oil alkyl) phosphate

All other

Other nonbenzenoid surface-active agents, not sulfated or

sulfonated :

n-Decyl alcohol, ethoxylated and carbonated

3,5-Dimethyl-l-hexyn-3-ol

3,6-Dimethyl-4-octyne-3,6-diol

2,4.,7,9-Tetramethyl-5-decyne-4,7-diol

Trideeyl alcohol, ethoxylated and carbonated, sodium

salt. All other

Sulfated and Sulfonated

*Alcohols , sulfated :

*n-Dodecyl sulfate salts :

n-Dodecyl sulfate, 2-amino-2-methylpropanol salt

*n-Dodeeyl sulfate, ammonium salt

n-Dodecyl sulfate, diethanolamine salt

n-Dodecyl sulfate, N,N-diethylcyclohexylamine salt

n-Dodecyl sulfate, isopropanolamine salt

n-Dodecyl sulfate, magnesium salt

n-Dodecyl sulfate, potassium salt

*n-Dodecyl sulfate, sodium salt

*n-Dodecyl sulfate, triethanolamine salt

*A11 other sulfated alcohols :

sec-Aliyl sulfate, ammonium salt

Branched hexadecyl sulfate, sodium salt

Coconut oil and sperm oil aliyl sulfate, sodium salt-

Decyl and octyl sulfate, sodium salt

n-Decyl sulfate, sodium salt

n-Deeyl sulfate, triethanolamine salt

3, 9-Diethyl-6- trideeyl sulfate

2-Ethylhexyl sulfate, sodium salt

7-Ethyl-2-methyl-4-undecyl sulfate

n-Hexadecyl sulfate

Hexyl sulfate, potassium salt

Nonyl sulfate

n-Oetadecyl sulfate

n-Octadecyl sulfate, sodium salt

n-Octadecyl sulfate, triethanolamine salt

n-Octyl sulfate, sodium salt

n-Tetradeeyl sulfate, sodium salt

Trideeyl sulfate, sodium salt

»Amides, amines, and quaternary ammonium salts, sulfated and sulfonated: Fatty aeid - alkanolamine condensates, sulfated: *Coeonut oil acids - ethanolamine condensate, sulfated.

potassium salt. Coconut oil acids - isopropanolamine condensate,

sulfated, sodium salt.

CST, DEX.

DUP.

G.

CST, DUP.

DUP.

DUP.

G.

DUP.

RCD.

DUP, TXT.

DUP.

BCN, DEX, TXT.

x.

SF.

G, LUR.

GLY.

NLC, SF, WTC.

G.

cue. cue. cue. s.

G, GLY, STC.

DUP.

AAC, CTL, DUP, ONX, PCS, RCD, STP, TXT.

AAC, CUL, DUP, HLI, JRG, ONX, RCD, STP.

DUP.

JRG, PCS.

AAC, HLI, STP.

HLI, PG, RCD.

AAC, CUL, DUP, HLI, JRG, LAK, MYW, ONX, PCI, PCS, PG,

RCD, RET, STP, TXT. AAC, CTL, CUL, DUP, HLI, MYW, ONX, PCS, PG, RCD, RET,

STP, TXT.

ucc.

APX.

DUP.

PCS.

CTL,

DUP,

ONX, PCS.

DUP.

UCC.

AAC,

UCC,

WTC.

UCC.

AAC,

DUP.

DEX.

TEN.

DUP,

EMK.

ONX,

PG.

DUP.

DUP,

PCS.

ONX,

AAC,

DUP.

DEX, APX.

EMK,

HRT, ONX.

158

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B -Surface-active agents for which U.S. production or sales were reported, identified by 1AJJL manufacturer, 1965— Continued

Chemical

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Sulfated and Sulfonated— Continued *Amides, amines, and quaternary ammonium salts, sulfated and sulfonated— Continued Fatty acid - alkanolamine condensates, sulfated— Con.

Oleic acid - ethanolamine condensate, sulfated

Stearic acid, diethanolamine condensate, methyl

sulfate . ♦Quaternary ammonium sulfates :

(2-Aminoethyl)ethyl(hydrogenated tallow alkyl)(2-

hydroxyethy 1 ) ammonium ethyl sulfate. Bis(hydrogenated tallow alkyl)dimethylammonium

methyl sulfate.

Dimethyldioctadecylammonium methyl sulfate

Ethyldimethyl(mixed aliyl) ammonium ethyl sulfate

l-Ethyl-2-(8-heptadecenyl)-l-(2-hydroxyethyl)-2-

imidazolinium ethyl sulfate.

N-Ethyl-N-hexadecylmorpholinium ethyl sulfate

N-Ethyl-N-( soybean oil al!syl)morpholinium ethyl

sulfate . 2-Heptadecyl-l-(2-stearamidoethyl)-2-imidazolinium

methyl sulfate. (3-Lauramidopropyl)trimethylammonium methyl sulfate —

Mixed fatty sulfobetaines

Trimethyl(3-oleamidopropyl)ammonium methyl sulfate

*Sulfosuccinamic acid derivatives :

N-(l,2-Dicarboxyethyl)-N-octadecylsulfosuecinamic

acid, tetrasodium salt. N- ( 2-Hydroxyethyl) -N- ( tallow allsyl) sulf osuccinamide—

N-Octadecylsulfosuccinamide, disodium salt

N-(Oleoyloxyisopropyl) sulf osuccinamide

Taurine derivatives :

N-Cyclohexyl-N-palmitoyltaurine

N-Methyl-N-( coconut oil acyl)taurine

*N-Methyl-N-oleoyltaurine

N-Methyl-N-paljnitoyltaurine

N-Methyl-N-(tall oil acyl)taurine, sodium salt

N-Methyl-N-( tallow acyl) taurine

Other amides, amines, and quaternary ammonium salts, sulfated and sulfonated: N-( 2-Hydroxyethyl) -N,N',N'-tris(2-hydroxypropyl)-

ethylenediamine, distearate methyl sulfate. Laurie acid, 2-sulfoacetamidoethyl ester, potassium salt.

N-(Mixed alkyl sulfonyl)glycine, sodium salt

Mixed primary amines, ethoxylated and sulfated

Oleic acid - ethylenediamine condensate, propoxylated

and sulfated, sodium salt. Stearic acid - ethylenediamine condensate, mono-

ethoxylated, ethyl sulfate. Tall oil acids - polyallsylenepolyamine condensate,

sulfated. N, N, N' , N ' - Tetrakis ( 2-hydroxypropyl ) ethylenediamine dioleate methyl sulfate. ♦Carboxylic acid esters (except natural fats and oils), sulfated and sulfonated: ♦Esters of sulfated oleic acid:

2-Butoxyethyl oleate, sulfated

Butyl oleate, sulfated

Ethyl oleate, sulfated

Glycerol trioleate, sulfated

*Isopropyl oleate, sulfated

Methyl oleate, sulfated

♦Propyl oleate, sulfated

♦Sulfosuccinic acid esters:

Sulfosuccinic acid, bis(2,6-dimethyl-4-heptyl)ester, sodium salt. ♦Sulfosuccinic acid, bis (2-ethylhexyl) ester

Manufacturers ' identification codes (according to list in table 22)

SCP. DUP.

ONX. JOR. APD.

APD.

APD.

ACY. TXT. CIB.

SCP. ACY. WTC.

CRC, CRT, DEP, DRW, G, HRT, MRA, NOP, PCI. G.

S.

ICI, ONX, PC.

G, KAL.

MRV, SCP.

BRY, DEX, EMR, HRT, ICI, LEA, LUR.

ICI.

ACY, BSC, EFH, MRV.

G.

ACY, CRC, CRT, CST, DAN, EFH, EMK, GGY, HRT, ICI, MRA, PC, SBC.

SURFACE-ACTIVE AGENTS

159

TABLE 19B —Surface-active agents for which U.S. production or sales were reported, identified by manufacturer, 1965— Continued

Chemical

NONBENZENOID SURFACE-ACTIVE AGENTS— Continued

Sulfated and Sulfo

ed--Conlinued

*Carboxylic acid esters (except natural fats and oils), sulfated and sulfonated— Continued *Sulfosuccinie acid esters— Continued

Sulfosuccinic acid, bis(tallow monoglyceride)ester

*Sulfosuccinic acid, dihexyl ester

Sulfosuccinic acid, dioctyl ester, sodium salt

Sulfosuccinic acid, dipentyl ester, sodium salt

*Sulfosuccinic acid, ditridecyl ester, sodium salt

Other carboxylic acid esters, sulfated and sulfonated:

Coconut oil isethionate

Coconut oil isethionate, sodium salt

Dodecyl sulfoacetate

Glycerol mono( coconut oil)ester, sulfated, ammonium

salt. Glycerol mono(coconut oil)ester, sulfated, sodium salt.

Glycerol monostearate sulfoacetate

2-Lauroyloxy-l-propanesulfonic acid

All other

*Ethers, sulfated and sulfonated:

n-Dodecyl alcohol, ethoxylated and sulfated, ammonium salt. *n-Dodecyl alcohol, ethoxylated and sulfated, sodium salt. n-Dodecyl alcohol, ethoxylated and sulfated, tri-

ethanolamine salt. Dodecyl and tetradecyl alcohols, ethoxylated and

sulfated, ammonium salt. Dodecyl and tetradecyl alcohols, ethoxylated and sulfated, potassium salt.

2-Hexyloxypropyl sulfate, sodium salt

Mixed linear alcohols, ethoxylated and sulfated

Mixed linear alcohols, ethoxylated and sulfated,

ammonium salt. Mixed linear alcohols, ethoxylated and sulfated,

potassium salt. Mixed linear alcohols, ethoxylated and sulfated, sodium salt.

Sperm oil alcohol, ethoxylated and sulfated

Tridecyl alcohol, ethoxylated and sulfated, sodium salt- All other

^Natural fats and oils, sulfated:

*Castor oil, sulfated

Manufacturers ' identification codes (according to list in table 22)

*Coconut oil, sulfated

*Cod oil, sulfated

Cottonseed oil, sulfated

*Grease, other than wool, sulfated-

Herring oil, sulfated

Lard, sulfated

Mixed fish oils, sulfated

Mixed vegetable oils, sulfated

Mustard seed oil, sulfated

*Neat's-foot oil, sulfated

*Peanut oil, sulfated

Rice-bran oil, sulfated

^Soybean oil, sulfated

*Sperm oil, sulfated

ACY.

ACY, MOA, SNW, TCI.

ACT.

ACY, MOA, WTC.

DRW. G, LEV. NAC. CP.

AAC, CP.

WTC. SDH. EMR.

AAC, LAK, ONX, RCD.

AAC, DUP, ONX, PCS, RCD, RET, STP.

PG.

LEV, TXT.

CO, G, SHC. NLC, STP.

*Tallow, sulfated-

Whale oil, sulfated-

DUP.

AAC, ARL, RCD.

APX, PG.

AAE, ACT, ACY, G, HRT, ICI, ONX, PC, PCI,

ACY, MRD, NOP,

ACT, CRT, DRW,

NOP, RTC.

CRT, NOP, SEA,

WHI.

WAW.

AML, SCO.

LEA.

LUR, NOP.

ACT, CRT, KAL,

ACY, CRT, ICI,

EFH, KNG, LUR,

APX, CRT, DRW,

ACT, CLD, CRT, RTC, S, SEA,

ACT, ACY, BRY, NOP, ONX, PC

KNG.

AML, APX, BRY, BSC, CRT, DEX, DRW, DUP, KAL, KNG, LEA, LUR, MRA, MRD, MRV, NOP,

S, SCO, SCP, SEA, SLC, WHI, WHW. RTC, SEA, WHW. MRD, NOP, S, SEA, WAW, WHI, WHW.

WHI, WHW.

LUR, MRD, NOP, PC, SEA, WHI, WHW.

LEA, LUR, NOP, SCP, SLC, SOS. NOP.

HRT, KAL, LEA, MRD, NOP, ONX.

DRW, HRT, KAL, KNG, LEA, MRD, NOP, ONX,

WAW, WHI, WHW.

DRW, EFH, ICI, KAL, LEA, LUR, MRA, MRD, PCI, SCP, SEY, SID, SNW, SOS, WHI.

160

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 19B. — Surface-active agents for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

NONBENZENOID SURFACE- ACTIVE AGENTS— Continued

Sulfated and Su!/onated--Continued

Other nonbenzenoid surface-active agents, sulfated and sulfonated :

Acetyloleic acid, sulfated

Mixed alkanesulfonic acids

Mixed alkanesulfonic acids, sodium salt

*01eic acid, sulfated

Oleostearin, sulfated

Ricinoleic acid, sulfated

a-Sulfostearic acid

*Tall oil, sulfated

DUP. VPC. DUP. ACT, ACT, CRT, DEX, DRW, EMR, G, LEA, LUR, MRV, NOP,

PCI, SCO, TEN, WHI, WHW. SEA. NOP. RCD. ACT, APX, CRT, ICI, NOP, SEA, WHI, WHW.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

Pesticides and Other Organic Agricultural Chemicals

TABLE 20B. --Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965

[Pesticides and other organic agricultural chemicals for which separate statistics are given in table 20A are marked below with an asterisk (*); products not so marked do not appear in table 20A because the reported data are ac- cepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Chemical

Manufacturers' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC

^Fungicides:

2,6-Bis(dimethylaminomethyl)eyclohexanone

2-sec-Butyl-4, 6-dinitrophenyl-3, 3-dimethylacrylate ( Binapacryl) .

5-Chloro-2-mereaptobenzothiazole, laurylpyridium salt

2,4-Dichloro-6-o-ehloroanilino-s-triazine

l,4-Dichloro-2,5-dimethoxybenzene

2,3-Dichloro-l,4- naphthoquinone (Diehlone)

Diphenylammonium propionate

3,3'-Ethylenebis(tetrahydro-4,6-dimethyl-2H-l,3,5,5- thiadiazine-2-thione) .

2-Heptadecyl-2-imidazoline acetate (Glyodin)

2-Mereaptobenzothiazole, monoethanolamine salt

*Mereury fungicides:

2-Chloro-4-(hydroxymercuri)phenol

Chloromethoxypropylmercuric acetate

N-(Ethylmercuri)-p-toluenesulfonanilide

4-(Hydroxymercuri)-2-nitrophenol

8-(Methylmercurioxy)quinoline

2-(Phenylmercuriamino) ethyl acetate

Phenylmercurlammonium acetate

N-Phenylmereuriformamide

Phenylmercury hydroxide

Phenylmercury lactate

Phenylmercury naphthenate

Phenylmercury oleate

Phenylmercury propionate

Tris(2-hydroxyethyl) (phenylmercuri) ammonium lactate

2-( 1-Methylheptyl) -4, 6-dinitrophenyl crotonate

*Naphthenic acid, copper salt

Pentachloronitrobenzene

*Pentachlorophenol (PCP)

*Pentachlorophenol, sodium salt

8-Quinolinol (8-Hydroxyquinoline), copper salt

Tetrachloro-p-benzoquinone (Chloranil)

2,3,4,6-Tetrachlorophenol

Tetrahydro-3,5-dimethyl-2H,l,3,5-thiadiazine-2-thione

N- ( Trichloromethylthio) -4-cyclohexene-l, 2-dicarboximide ( Captan) .

N-( Trichloromethylthio) phthalimide (Folpet)

*2,4,5-Trichlorophenol

*2,4,5-Triehlorophenol, ethanolamine salt

*2,4,5-Triehlorophenol, sodium salt

2,4,6-Trichlorophenol

All other cyclic fungicides

*Herbicides and plant hormones:

5-Bromo-3-sec-butyl-7-methyluracil

l-Butyl-3-(3,4-dichlorophenyl) -1-methylurea ( Neburon)

2-sec-Butyl-4,6-dinitrophenol (DNBP)

*2-sec-Butyl-4, 6-dinitrophenol, ammonium salt

2-sec-Butyl-4,6-dinitrophenol, triethanolamine salt

N-Butyl-N-ethyl-a,a,a,-trifluoro-2,6-dinitro-p-toluidine (Benefin).

2-Chloro-4,6-bis(ethylamino)-s-triazine (Simazine)

2-Chloro-4,6-bis(isopropylamino)-s-triazine (Propazine)-

4-Chloro-2-butynyl m-chlorocarbanilate (Barban)

2-Chloro-4-ethylamino-6-isopropylamino-s-triazine

( Atrazine) . N-(3-Chloro-4-methylphenyl) -2-methylpentanamide ( Solan) - 3-(p-Chlorophenyl) -1, 1-dimethylurea (Monuron)

MRK. FMN, FMP.

VNC. CHG.

DUP. USR. MRK. DUP.

UCC. VNC.

DUP.

TRO.

DUP.

DUP.

MRK.

CLY.

TRO.

VIN.

MRK.

WRC.

MRK.

CLY, HNX, MRK, TRO.

MRK.

CLY.

RH.

CCA, FER, HNX, MCI, MLD, SHP, SM, SOC, SRR, TGL, TRO,

WTC. MON, OMC.

BXT, DOW, FRO, MON, RCI, SFD. DOW, MON, RCI, SFD. GAM, HNX, MRK. USR. DOW.

CLY, MRK, SF, WRC. CHO.

CHO.

DA, DOW, HK.

G.

DA, DOW.

DOW.

CWN, DUP.

DUP.

DUP.

CIS, DOW, FMN, TNA.

CIS, DOW, FMN.

CIS, DOW, FMN.

LIL.

GGY. GGY. SPN. GGY.

FMN. DUP.

162

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 20B. •

-Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC--Continued

^Herbicides and plant hormones — Continued

3-(p-Chlorophenyl)-l, 1-dimethylurea trichloroacetate

2,5-Dichloro-3-aminobenzoic acid, ammonium salt

3,6-Diehloro-2-anisic acid

2-(2,4-Dichlorophenoxy)ethanol sulfate, sodium salt

3-(3,4-Dichlorophenyl)-l, 1-dimethylurea (Diuron)

3-(3,4-Dichlorophenyl) -1-methoxy-l-methylurea ( Linuron) -

2,4-Dichlorophenyl-4-nitrophenyl ether

3,4-Dichloropropionanilide

l,2-Dihydro-3,6-pyridazinedione (Maleic hydrazide)

N,N-Dimethyl-2,2-diphenylacetamide (Diphenamide)

l,l-Dimethyl-3-phenylurea (Fenuron)

l,l-Dimethyl-3-phenylurea trichloroacetate

Dimethyl tetrachloroterephthalate

4,6-Dinitro-o-eresol (DNOC)

4,6-Dinitro-o-cresol, sodium salt

2, 6-Dinitro-N, N-di-n-propyl-ct,a, a-trif luoro-p- toluidine ( Trif luralin) .

Diphenylacetonitrile

Gibberellic acid

3-(Hexahydro-4,7-methanoindan-5-yl)-l, 1-dimethylurea ( Norea) .

Indolebutyric acid

Isopropyl carbanilate (Isopropyl N-phenylearbamate)

(IPC). Isopropyl 3-chlorocarbanilate (Isopropyl N-(3-chloro-

phenyl) carbamate) (CIPC). N-( 2-Mercaptoethyl) benzenesulf onamide S- ( 0, 0-diisopropyl phosphorodithioate) (Betasan).

l-(2-Methyl-cyclohexyl)-3-phenylurea (Siduron)

1-Naphthaleneacetic acid and derivatives:

1-Naphthaleneacetamide

1-Naphthaleneacetic acid

1-Naphthaleneacetic acid, methyl ester

1-Naphthaleneacetic acid, sodium salt

N-1-Naphthylphthalamic acid (NPA)

7-0xabicyclo[2.2.1]heptane-2,3-dicarboxylic acid,

disodium salt (Endothal). Phenoxyacetic acid derivatives:

(4-Chloro-o-tolyloxy) acetic acid (MCPA)

(4-Chloro-o-tolyloxy) acetic acid, potassium salt

♦(2, 4-Dichlorophenoxy) acetic acid (2,4-D)

*( 2, 4-Dichlorophenoxy) acetic acid esters and salts: ( 2, 4-Dichlorophenoxy) acetic acid, 2-butoxyethyl

ester. (2, 4-Dichlorophenoxy) acetic acid, butoxypolypropyl- eneglycol ester.

*(2, 4-Dichlorophenoxy) acetic acid, n-butyl ester

(2, 4-Dichlorophenoxy) acetic acid, sec-butyl ester

*(2,4-Dichlorophenoxy)acetic acid, dimethylamine salt (2, 4-Diehlorophenoxy) acetic acid, ethanolamine and isopropanolamine salt.

*(2, 4-Dichlorophenoxy) acetic acid, ethyl ester

(2, 4-Dichlorophenoxy) acetic acid, 2-ethylhexyl ester

*(2, 4-Dichlorophenoxy) acetic acid, iso-octyl ester

*( 2, 4-Dichlorophenoxy) acetic acid, isopropyl ester

(2, 4-Dichlorophenoxy) acetic acid, lithium salt

(2,4-Diehlorophenoxy)acetic acid, sodium salt

All other (2, 4-Dichlorophenoxy) acetic acid esters and salts.

*(2, 4, 5-Triehlorophenoxy) acetic acid (2,4,5-T)

*(2, 4, 5-Trichlorophenoxy) acetic acid esters and salts:

(2,4,5-Trichlorophenoxy)acetic acid, amyl ester

(2,4,5-Triehlorophenoxy)aeetic acid, 2-butoxyethyl

ester. (2,4,5-Trichlorophenoxy) acetic acid, butoxypoly- propyleneglycol ester. *(2, 4, 5-Trichlorophenoxy) acetic acid, n-butyl ester— (2,4,5-Trichlorophenoxy)acetie acid, sec-butyl ester

Manufacturers' identification codes (according to list in table 22)

ACG.

G.

VEL.

G.

DUP.

DUP.

RH.

MON, RH.

ACY, USR.

LIL, x.

DUP.

ACG.

DA.

CIS, FMN.

CIS, FMN.

LIL.

LIL.

ABB, MRK. HPC.

ARA. PPG.

PPG.

SF.

DUP.

AMC.

AMC, COK. AMC.

AMC, BKL. USR. PAS.

CHC, CLY, DOW, RIV.

GTH.

CHC, DA, DOW, HPC, MON.

AMC.

DOW.

AMC, DA, DOW, HPC, IMR, MON, RIV, TMH.

CHC, MON.

ALC, AMC, CHC, DA, DOW, HPC, RIV, TMH.

DOW.

AMC, DOW,

MON.

DA, HPC.

CHC, DOW,

MON, RIV, TMH.

AMC, CHC,

DA, DOW, HPC, MON,

RIV

GTH.

DOW.

CWN, HPC.

DA, DOW,

HPC, MON.

HPC.

AMC.

DOW.

DA, DOW,

HPC, MON, RIV.

MON.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

TABLE 20B. — Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC— Continued

^Herbicides and plant hormones — Continued Phenoxyacetic acid derivatives — Continued *(2,4,5-Trichlorophenoxy)acetic acid esters and salts — Continued (2,4,5-Trichlorophenoxy)acetie acid, 2-ethyLhexyl ester. *(2, 4, 5-Trichlorophenoxy) acetic acid, iso-octyl ester (2,4,5-Triehlorophenoxy)acetic acid, isopropyl ester (2, 4, 5-Trichlorophenoxy) acetic acid, triethylamine salt.

*Phenylmercury acetate (PMA)

Polychloro-tetrahydro-methanoindene ( Polychlorodicyclo- pentadiene) isomers.

N-Tolylphthalamic acid

Tributyl(2,4-dichlorobenzyl)phosphonium chloride

2-(2,4,5-Trichlorophenoxy)proplonic acid (Silvex) '■

2-(2,4,5-Trichlorophenoxy)propionic acid, 2-ethyLhexyl ester.

Tris [2- ( 2, 4-dichlorophenoxy) ethyl] phosphite (2,4-DEP)

All other cyclic herbicides and plant hormones

Insect attractants: 2,4-Bis( isopropylamino) -6-methoxy-s-triazine

( Prometone ) . tert-Butyl 4(and 5)-chloro-2-methylcyclohexane-

carboxylate. 2-Ethylamino-4-isopropylamino-6-methylmercapto-s- triazine (Ametryne). ^-Insecticides:

Allethrin (Allyl homolog of Cinerin I)

Benzyl thiocyanate

Chlorinated insecticides: *Aldrin-toxaphene group:

Heptachloro-tetrahydro-methanoindene ( Heptachlor )

Hexachloro-epoxy-octahydro-endo, endo-dimethano-

naphthalene ( Endrin) . Hexachloro-epoxy-octahydro-endo, exo-dimethano-

naphthalene (Dieldrin). Hexachloro-hexahydro- endo, exo-dimethanonaphthalene (Aldrin) .

Octachloro-tetrahydro-methanoindan (Chlordan)

Terpene polychlorinates

Toxaphene (Chlorinated camphene)

l,l-Bis(p-chlorophenyl)-2-nitrobutane

1, l-Bis(p-chlorophenyl)-2-nitropropane

2-(p-tert-Butylphenoxy)isopropyl-2'-chloroethyl

sulfite . 2-(p-tert-Butylphenoxy)-l-methyletnyl 2- ehloroethyl sulfite.

p-Chlorophenyl p-chlorobenzenesulfonate (Ovex)

p-Chlorophenyl 2,4,5-trichlorophenyl sulfone

4,4'-Dichlorobenzilate

l,l-Dichloro-2,2-bis(p-chlorophenyl)ethane (DDD) (TDE)

1, l-Dichloro-2,2-bis(p-ethylphenyl) ethane

4,4'-Dichloro-a-(trichloromethyl)benzhydrol

*Hexachlorocyelohexane (Benzene hexachloride)

*Hexachlorocyclohexane, 100$ y-isomer (Lindane)

Hexachloro-hexahydro-methano-benzodioxathiepinoxide (Endosulfan).

*1, l,l-Trichloro-2,2-bis(p-chlorophenyl)ethane (DDT)

1, 1, l-Trichloro-2, 2-bis (p-methoxyphenyl) ethane (Methoxychlor) .

All other chlorinated insecticides

N, N-Diethyltoluanu.de

Isobornyl thiocyanatoacetate

1-Naphthyl methylcarbamate

*Organophosphorus insecticides:

4-tert-Butyl-2-chlorophenyl methyl methylphosphor-

amidate. 3-Chloro-7-hydroxy-4-methylcoumarin 0, 0-diethyl phos- phorothioate .

DA,

HPC.

CIS,

DOW, MON, HIV, TMH.

DA.

DOW,

HPC, RIV.

BKM,

CLY, MRK, TRO, WRC.

VEL.

USR.

SM.

DOW,

HPC, RIV.

HPC.

USR.

HPC,

LIL.

GGY.

TBK.

GGY.

BPC.

HK.

VEL.

SHC,

VEL.

SHC.

SHC.

VEL.

HN.

HPC.

COM.

COM.

USR.

USR.

AMP,

CIS, DOW.

FMN,

FMP.

GGY.

ACG,

RH.

RH.

RH.

DA,

fRO, HK, PPG.

HK.

HK.

ACG,

DA, GGY, LEB, MTO, OMC

CHF,

DUP.

LIL,

SHC.

HPC,

PFZ.

CIS,

HPC.

UCC.

DOW.

CHG.

164

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 20B.

-Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers ' identification codes (according to list in table 22)

PESTICIDES AMD OTHER ORGANIC AGRICULTURAL CHEMICALS, CYCLIC— Continued

^Insecticides- -Continued

*Organophosphorus insecticides — Continued

S-(p-Chlorophenylthio)methyl 0, O-diethyl phosphoro-

dithioate ( Carbophenothion) . 0, 0-Diethyl 0-(2-isopropyl-4-methyl-6-pyrimidinyl) phosphorothioate (Diazinon). *0, 0-Diethyl O-(p-nitrophenyl) phosphorothioate ( Parathion) . 0,0-Dimethyl 0- [4-(methylthio)-m-tolyl] phosphoro- thioate. *0, 0-Dimethyl 0- ( p-nitrophenyl) phosphorothioate (Methyl parathion) . 0, 0-Dimethyl S-(4-oxo-l,2,3-benzotriazin-3(4H) -

ylmethyl) phosphorodithioate. 0, 0-Dimethyl 0-(2,4,5-trichlorophenyl) phosphoro- thioate (Ronnel).

p-Dioxane-2,3-diyl ethyl phosphorodithioate

0-Ethyl 0-(p-nitrophenyl)phenyl phosphonothioate

a-Methylbenzyl 3-hydroxy-cis-crotonate, dimethyl phos phate ester.

All other organophosphorus insecticides

Nematocides:

0-2,4-Dichlorophenyl 0, 0-diethyl phosphorothioate

0, 0-Diethyl 0-2-pyrazinyl phosphorothioate (Thionozin)— *Rodenticides:

3-(Acetonylbenzyl)-4-hydroxycoumarin

2-Isovaleryl-l,3-indandione, calcium salt

2-Pivaloyl-l,3-indandione

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, ACYCLIC

*Fungicides:

Bis-1,4— bromoacetoxy-2-butene

Cadmium succinate

l-Chloro-2-nitropropane (Korax)

Disodium cyanodithioimidocarbonate

Dithiocarbamic acid fungicides:

*Dimethyldithiocarbamic acid, ferric salt (Ferbam)

Dimethyldithiocarbamic acid, manganese salt

Ethylene bis(dithiocarbamic acid), diammonium salt

^Ethylene bis(dithiocarbamic acid), disodium salt ( Nabam) . Ethylene bis( dithiocarbamic acid), manganese salt (Maneb). ^Ethylene bis( dithiocarbamic acid), zinc salt (Zineb)--

Polyethylenethiuram disulfide (PETD)

All other dithiocarbamic acid fungicides

Dodecylguanidine acetate (Dodine)

Mercury fungicides:

3-Ethyl(mercuritnio)-l,2-propanediol

Ethylmercury acetate

Ethylmercury chloride

Ethylmercury phosphate

3-Methyl(mercurithio)-l,2-propanediol

Methylmercury acetate

Methylmercury hydroxide

Methylmercury nitrile

All other mercury fungicides

All other acyclic fungicides

*Herbicides and plant hormones:

Cacodylic acid

2-Chloroallyl diethyldithiocarbamate (CDEC)

N,N-Diallyl-2-chloroacetamide (CDAA)

2,3-Dichloroallyl diisopropylthiocarbamate

2,2-Dichloropropionic acid, sodium salt

Diethyl dithiobis(thionoformate)

S-Ethyl dipropylthiocarbamate (EPTC)

Hexachloroacetone

SF.

GGY.

ACY, AMP, M0N, SF, SHC.

CHG.

AMP, M0N, SF, SHC.

CHG.

DOW.

HPC.

SF.

SHC.

SF.

SM. ACY.

PEN. MOT. MOT, PIC.

VI N.

MAL.

FMN, FMP. BKM.

DUP, FMN, RBC, WRC.

FMN.

CIS, RBC.

CIS, DUP, FMN, RBC, RH.

CIS, DUP, RH.

CIS, DUP, FMN, RH.

FMN.

VNC.

ACY.

DUP. DUP. DUP. DUP. DUP. DUP. MRT. WRC. MAL. LIL, MLD, SHC.

ASL.

M0N.

M0N.

M0N.

DOW.

RBC.

SF.

ACG.

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS

165

TABLE 20B. ■

-Pesticides and other organic agricultural chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued -^

Manufacturers' identification codes (according to list in table 22)

PESTICIDES AND OTHER ORGANIC AGRICULTURAL CHEMICALS, ACYCLIC- - Continued

*Herbicides and plant hormones — Continued

Methanearsonic acid, disodium salt

Methanearsonic acid, dodecyl- and oetylammonium salts —

S- Propyl butylethylthiocarbamate

S,S,S-Tributyl phosphorotrithioate

Tributyl phosphorotrithioite

Trichloroacetic acid, sodium salt (TCA)

2,3,3-Trichloroallyl diisopropylthiocarbamate

All other acyclic herbicides and plant hormones

^Insecticides:

2-(2-Butoxyethoxy) ethyl thiocyanate

Butoxypolypropylene glycol (Fly repellent)

Metaldehyde

*Organophosphorus insecticides:

Bis(dialkoxyphosphinothioyl) disulfides

S-[l,2-Bis(ethoxycarbonyl)ethyl] 0,0-dimethyl phos-

phorodithioate (Malathion). l,2-Dibromo-2,2-dichloroethyl dimethyl phosphate (Naled).

2,2-Dichlorovinyl dimethyl phosphate (DDVP)

0,0- Diethyl S-[2-(ethylthio)ethyl] phosphorodithioate- 0,0-Diethyl 0-[2-(ethylthio)ethyl] phosphorothioate--- 0,0-Diethyl S-[2-(ethylthio) ethyl] phosphorothioate— 0,0-Diethyl S-[ (ethylthio)methyl] phosphorodithioate— Dimethyl 3-hydroxycrotonate, dimethyl phosphate ester- 0,0- Dimethyl S-(N-methylcarbamoy Methyl) phosphorodi- thioate (Dimethoate) .

Ethyl methylene phosphorodithioate (Ethion)

Ethyl pyrophosphate (Tetraethyl pyrophosphate) (TEPP)- S-2-(Ethylsulfinyl) ethyl 0,0-dimethyl phosphoro- dithioate. Methyl 3-hydroxycrotonate, dimethyl phosphate ester—-

All other organophosphorus insecticides

2-Thiocyanatoethyl laurate

*Rodenticides: Sodium fluoroacetate

*Soil conditioners:

Polyacrylonitrile, hydrolyzed, sodium salt

All other soil conditioners

*Soil fumigants:

*Bromomethane (Methyl bromide)

Chloropicrin (Trichloronitromethane)

*l,2-Dibromo-3-chloropropane

1,3-Dichloropropene

1,3-Dichloropropene, 1, 2-dichloropropane

N-Methyldithiocarbamic acid, sodium salt

All other soil fumigants

ASL,

CLY, VI N

CLY,

VIN.

SF.

CHG.

SM.

DOW.

MON.

SF,

USR.

RH.

UCC.

COM.

FMN.

ACY.

SHC.

SHC.

CHG.

CHG.

CHG.

ACY.

SHC.

ACY.

FMN,

FMP.

ALC,

AMP, OTH.

CHG.

SHC.

AMP,

SHC.

AMP,

DOW, FRO,

GTL,

MCH

DOW, AMP,

IMC. DOW, SHC.

DOW.

DOW,

SHC.

DUP,

RH, SF.

SYNTHETIC ORGANIC CHEMICALS. 1963

Miscellaneous Chemicals

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965

[Miscellaneous chemicals for which separate statistics are given in table 21A are marked with an asterisk (*); chemicals not so marked do not appear in table 21A because the reported data are accepted in confidence and may not be published. Manufacturers' identification codes shown below are taken from table 22. An x signifies that the manufacturer did not consent to his identification with the designated product]

Chemical

Manufacturers ' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC

6-Aeetoxy-2, 4- dimethyl- m-dioxane

Adenosine phosphates

2-Aminobenzothiazole

3-Amino-4-bromobenzotrifluoride

l-(2-Aminoethyl)piperazine

l-(3-Aminopropyl)morpholine

Anisaldehyde bisulfite

Arylalkyl phosphites

Aziranephosphine oxide

Barium octylphenate

Benzoic acid salts:

Barium benzoate

Cadmium benzoate

Cobalt benzoate

*Sodium benzoate, tech

*Sodium benzoate, U.S.P

Zinc benzoate

p-Benzoquinone (p-Quinone)

Benzothiazole

* Benzoyl peroxide

Biological stains

Bis(2,4-dichlorobenzoyl) peroxide

Boron fluoride-phenol complex

3-Bromo-4-chlorobenzotrifluoride

a- [2-(2-Butoxyethoxy) ethoxy] -4,5-methylenedioxy-2-propyl-

toluene (Piperonyl but oxide).

Butyl benzoate

p-tert-Butylbenzoic acid, barium bis-salt

2( and 3)-tert-Butyl-4— methoxyphenol

p-tert-Butyl-ci-methylcinnamaldehyde

tert-Butyl peroxybenzoate

4-tert-Butylphenyl salicylate

4-tert-Butylpyrocatechol

Camphene

Catecholdisulfonic acid, disodium salt

Catecholdisulfonic acid, sodium salt

Centralite- 1 ( N, N '-Diethyl-N, N'-diphenylurea)

Chemical indicators

Chemical reagents

Chloramine B (Sodium derivative of N-chlorobenzenesulfon-

amide) .

Chlorinated terphenyls

l-(3-Chloroallyl)-3,5,7-triaza-l-azon iaadamantane

chloride.

4-Chloro-3-cyanobenzotrifluoride

5-Chloro-2-hydroxybenzophenone

Chlorophyllin, sodium- potassium- copper

Cobalt phthalocyaninedisulfonic acid

Cumene hydroperoxide

Cyanuric acid

Cyclohexanone peroxide

Cyclohexene-1, 2-dicarboxylic acid ( Tetrahydrophthalic

acid) disubstituted, polyester salts: Barium and

cadmium salts.

1,4-Cyclohexylenedimethanol

^Cyclopropane

Cytidine and derivatives

Decahydronaphthalene ( Decalin)

Decyl diphenyl phosphite

Dehydroacetic acid, sodium salt

2,5-Di-tert-amylhydroquinone

GIV. PLB.

FMT. PIC. JCC. JCC. GIV. WES. CEM. CCA.

CCW.

CCW.

SHP.

HN.

HK, HN, MON, PFZ, VEL.

CCW.

EKT.

ACY.

AZT,

HLC,

CAD.

ACG.

PIC.

FMN,

FRO,

CCA.

EKT.

GIV.

WTL.

DOW.

BKL,

GLD,

ICO.

SDW.

OTC,

EK,

ACG,

NES.

CAD, NOC, OXY, RCI, SDH, UPR, WTL. NAC.

DOW. HPC.

PAS. HLC, LAM, NAC. CLB, EK, GFS, HLC, NAC, PIC.

KPS, KPT. DOW.

PIC.

DOW.

KCH.

NAC.

HPC.

FMB.

NOC, WTL.

RCI.

EKT.

MAL, OH, OMS, TAE.

PLB.

DUP.

HK.

GAN.

EKT.

MISCELLANEOUS CHEMICALS

167

TABLE 21B.

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1 965- -Continued

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

l,4-Diazabicyclo[2.2.2]oetane (Triethylenediajnine)

Diazodinitrophenol

2,4-Dibenzoylresorcinol

2,4-Di-tert-butyl-p-cresol

2,6-Di-tert-butyl-p-cresol:

*Food grade

*Tech

2,5-Di-tert-butylhydroquinone

1, l-Diehloro-2-( o- chlorophenyl) -2-( p- chloropheny 1) ethane—

l,3-Dichloro-5,5-dimethylhydantoin

Dichloro-s-triazine-2,4, 6( 1H,3H,5H) trione (Dichloroiso-

cyanuric acid) . Dichloro-s- triazine-2, 4, 6( LH,3H,5H) trione, potassium salt-

Diehloro-s- triazine-2, 4, 6( 1H,3H,5H) trione, sodium salt

Dicyclohexylammonium nitrite

Dicyclopentadienyliron

Didecyl phenyl phosphite

Digitonin

2,2'-Dihydroxy-4, 4'-dimethoxybenzophenone

2, 6-Dihydroxyisonicotinic acid (2,6-Dihydroxy-4-carboxy- pyridine) .

2, 2'-Dihydroxy—4- methoxybenzophenone

2,2'-Dihydroxy-4-(octadecyloxy)benzophenone

3, 5-Diiodosalicylie acid

Diisopropylbenzene hydroperoxide, mixed isomers

Diisopropyl-m, p-cresols

Diisopropyl-m, p-cresols, mixed

p-Dimethoxybenzene (Dimethyl ether of hydroquinone)

2, 5-Dimethyl-2, 5-di( peroxyphenyl) hexane

2,5-DimethyLhexane-2,5-diperoxybenzoate

2,6-Dimethylmorpholine

4,4-Dinitrocarbanilide-4,6-dimethyl-2-pyrimidinol

Dioxane ( 1, 4-Diethylene oxide)

2,5-Diphenyl-p-benzoquinone

Diphenyl phosphite

4-(Dodecyloxy)-2-hydroxybenzophenone

Enzymes: Hydro lytic:

Amylases--

Proteases

Other

Nonhydro lytic

Other

1, 2-Epoxy-3-phenoxypropane (Glycidyl phenyl ether)

6-Ethoxy-m-anol (Propenylmethylguaethol)

Ethylglucosyl p- aminobenzoate

2-EthyLhexyl octylphenyl phosphite

Ethyl hydrocaffeate

*4-Ethylmorpholine

Fenchone

*Flotation reagents:

Dicresylphosphorodithioic acid ( Dicresylthiophosphoric acid) .

Dicresylphosphorodithioic acid, ammonium salt

Dicresylphosphorodithioic acid, sodium salt

2,2'-Dimethylthiocarbanilide (Di-o-tolylthiourea)

Rosin amines

Thiocarbanilide ( Diphenylthiourea)

Fluorinated benzenoid chemicals

o-Fluorobenzoic acid

4-Fluoro-2-methylaniline

5-Fluoro-2-nitrotoluene

Furan derivatives:

2-Furaldehyde (Furfural)

Tetrahydrofurfuryl alcohol

Gallic acid, all grades

*Gasoline additives:

N, N'-Bis( 1, 4-dimethylpentyl)-p-phenylenediamine

2, 6-Di-tert-butylphenol

*N, N'-Di-sec- butyl- p-phenylenedlamine

HOU. HPC. DOW. PRD.

CAT, EKT, HPC, KPT, SHC.

CAT, EKT, HPC, KPT, SHC.

EKT.

ALD, EDC.

GLY.

MON.

FMB, MON.

FMB, WON.

CMC.

TNA.

HK.

PEN.

G.

EK.

ACY.

ACY.

MRT.

HPC.

GIV.

GIV.

ASL, EKT, G, ICO.

WTL.

UPR.

DOW.

MRK.

DOW, UCC.

EKT.

HK.

DUP, EKT.

CRN, OMS, PMP, RH, WBC.

PMP, RH, WBC. WBC.

MLS, WBC.

BAX,

BAX,

RH,

FMO,

PLB.

SHC.

ICO.

VND.

SM.

ICO.

BC, C

HNW.

ACY.

ACY.

KCU.

DUP, RBC. HPC.

ACY, NAC. PIC. PIC. PIC. PIC.

QKO. CjKO.

MAL.

EKT. TNA. DUP, EKT, UPM.

168

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 21B -Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965— Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Gasoline additives — Continued

N,N'-Diisopropyl-p-phenylenediamine

*N,N'-Disalicylidene-l,2-propanediamine

Methylcyelopentadienylmanganese triearbonyl

2,2'-Thiobis[6-tert-butyl-4-methylphenol]

All other

Glyceryl p- aminobenzoate

Guanosine phosphates

Heterocyclic compounds

5, 6,7, 8, 9, 9-Hexachloro-l, 2,3, 4, 4a, 5, 8, 8a-oetahydro- 5,8-methano-2,3-naphthalic anhydride (Cloran).

Hexa(2-methylaziridinyl)-l,3,5-phosphotriazine

*Hexamethylenetetramine, tech

Hydrocinnamic acid

o-(2-Hydroxy-p-anisoyl) benzoic acid

N-(2-Hydroxyethyl)gentisamide

Hydroxyethylpiperazine

2-Hydroxy-4-methoxybenzophenone

2-Hydroxy-4-methoxy-5-sulfobenzophenone trihydrate-

Hydroxymethyl-5,5-dimethylhydantoin

2-Hydroxymethyl-5-norbornene

2-(2'-Hydroxy-5'-methylphenyl)benzotriazole

2-Hydroxy-4-n-octoxybenzophenone

Hydroxyphenylbenzotriazole derivative

2-(2-Hydroxyphenyl) -4(3) -quinazo lone

l-Hydroxy-2-pyridine (Omadine)

2-Imidazolidinethione ( l,3-Ethylene-2-thiourea)

Inosine and phosphates

Isoamyl p-dimethylaminobenzoate

Isocyanurie acid

Isocyanuric acid, sodium salt (Sodium isocyanurate)

Isophorone

Isopropyl-o-cresol p-Isopropyl-a- methylc innamaldehyde- Isosorbid Ketene, dimer- *Lubricating oil and grease additives:

Chlorosulfurized and sulfurized compounds: Alicyclic compounds, sulfurized- Heterocyclic compounds, sulfurized Liquid disulfide-

Tall oil ester, sulfurized

Terpenes, sulfurized

Oil- soluble petroleum sulfonates:

Oil-soluble petroleum sulfonate, ammonium salt

Oil-soluble petroleum sulfonate, barium salt

*Oil-soluble petroleum sulfonate, calcium salt

xOil-soluble petroleum sulfonate, sodium salt

All other

Phenol salts:

Barium salt of dodecylphenol

Barium salt of nonylphenol

Calcium salt of octylphenol- formaldehyde

Calcium salt of polypropylphenol

All other phenol salts

All other

p-Menthane

8-p-Menthyl hydroperoxide

4-Methallylbenzenesulfonic acid

Methoxybenzyl alcohol

p-Methoxybenzylidenemalonic acid, dimethyl ester

4-Methoxyphenol

N-Methylanthranilic acid

2-Methylaziridine

2,2'-Methylenebis[4-chlorophenol] ( Dichlorophene)

4,4'-Methylenebis[2,6-di-tert-butylpheno]]

Methylenebis[5,5-dimethylhydantoin]

2,2'-Methylenebis[3,4,6-trichlorophenol] ( Hexachlorophene) 2,2'-Methylenedi-p-cresol ( Bis( 5-methyl-2-hydroxyphenyl) methane) .

DUP, EKT.

D0P, EKT, SM, TX, UPM.

TNA.

CAT.

EKT, TNA, UPM.

TOD.

PLB.

ALD.

WSN.

ICO.

BOR, DUP, HKD, HMP, HN, FLS, UCP.

ICO.

ACY.

ICO.

JCC.

ACY, G.

ACY.

GLY.

ICO.

GGY.

ACY.

GGY.

LUB, MON, 0R0, SIN, x.

LUB, MON, 0R0, SIN, SM, TNA, TX, X.

SIN.

CO, LUB, SON, TX, X.

CO, LUB, 0R0, SHO, SON, X.

ENJ, MOR, NOP, PAR, SHO, SOC, SOI, SON, TX.

CO.

TX.

CCA.

SHC.

0R0.

ENJ,

ENJ,

HPC.

HNW,

CCW.

ICO.

ACY.

ASL,

GIV.

ICO.

GIV.

SHC.

GLY.

GIV.

GIV.

MISCELLANEOUS CHEMICALS

169

TABLE 21B.-- Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1965 — Continued

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Methyl gallate

Methylglucoside

■i-Methylmorpholine

5-Methyl-5-norbornene-2,3-dicarboxylic anhydride (Methyl- bicyclo[2.2.l]hept-5-ene-2,3-dicarboxylic anhydride).

Methyl phenyl phosphates

l-Methyl-2-pyrrolidone, monomer

*Morpholine

Morpholine salt of p- toluenesulf onic acid

*Naphthenic acid salts:

Aluminum naphthenate

Barium naphthenate

Cadmium naphthenate

*Calcium naphthenate

Cobalt lead manganese naphthenate

*Cobalt naphthenate

*Iron naphthenate

Lead manganese naphthenate

*Lead naphthenate

Lithium naphthenate

^Manganese naphthenate

Nickel naphthenate

Rare earths naphthenate

Sodium naphthenate

Strontium naphthenate

*Zinc naphthenate

o-Nitrobenzoic acid and sodium salt

5-Norbornene-2-methylacrylate ( Bicyclo[2.2. l]hept-5-ene- 2-aerylate) .

l-0ctadecenyl-2-naphthenyltetrahydropyrimidine

Octylphenyl acid phosphate

Organic mercury compounds:

Phenyl mercuric borate

Pyridyl mercuric acetate

1, 10-Phenanthroline

Phenolthiosulfonic acid

2-Phenoxyethanol (Ethylene glycol monophenyl ether)

2-(2-Phenoxyethoxy)ethanol (Diethylene glycol phenyl ether) .

2,2'-(p-Phenylene)diethanol

m-Phenyleneisophthalamide

Phenyl hydrogen phosphate -

Phenyltrimethylammonium chloride

Photographic chemicals:

N-(o-Acetamidophenethyl)-l- hydroxy- 2- naphthamide

2-(4-Amino-N-ethyl-m-toluidino) ethyl sulfate

4-Amino-6-methylguaiacol (2-Methyl-6-methoxy-4-amino- phenol hydrochloride) .

3-Amino-l,2,4-triazole (5-Amino-l,3,4-triazole)

*Benzotriazole

p-Benzylaminophenol hydrochloride

Catechol (Pyrocatechin)

3-Chloro-4-diethylaminobenzenediazonium chloride ( p- Diazo-2-ehlpro-N, N-diethylaniline) - zinc chloride. 2-Chloro-N, N- diethyl- p-phenylenediamine hydrochloride—

2,4-Diaminophenol dihydrochloride (Amidol)

N-(4-Diazo-2,5-dibutoxyphenyl) morpholine, zinc chloride

salt. N-(4-Diazo-2, 5-diethoxyphenyl) morpholine, zinc chloride salt.

4— Diazo-1-morpholine benzene

2,5-Diethoxy-4-morphinyldiazonium chloride - zinc chloride double salt.

Manufacturers' identification codes (according to list in table 22)

HSH. CRN. JCC, UCC.

ICO.

TNA.

G.

DOW, JCC, UCC.

AMB.

HSH, WIC.

CCA, QCP.

CCA.

CCA, FER, HNX, HSH, MCI, MLD, MR, SHP, SM, SOC, SRR,

SW, TRO, WTC. HNX, HSH, SW. CCA, CCC, FER, HNX, HSH, MCI, MLD, MON, MR, SHP, SM,

SOC, SRR, SW, TRO, WTC. CCA, HNX, HSH, MCI, MLD, SOC, TRO, WTC. CCA. CCA, CCC, CCW, FER, HNX, HSH, MCI, MLD, MR, SHP, SM,

SOC, SRR, SW, TRO, WTC. CCA. CCA, CCC, FER, HNX, HSH, MLD, SHP, SM, SOC, SRR, SW,

TRO, WTC. CCA.

CCA, HNX. CCA. CCA. CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SOC, SRR, SW,

TRO, WTC. WAY. ICO.

SM. SM.

WRC.

MAL.

COK.

G.

DOW, JCC.

DOW.

SM. BKL.

EKT. EKT.

FMT.

EK, FMT, MEE, MRT.

EK.

KPT.

IDC. VPC. IDC.

FMT. G.

170

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , iS65--Continued

MISCELLANEOUS CHMICALS, CYCLIC--Continued

Photographic chemicals — Continued *p-Diethylaminobenzenediazonium chloride (p-Diazo-N, N- diethylaniline) - zinc chloride. p-Diethylaminobenzenediazonium ( p-Diazo-N, N- diethy lani- line) fluoroborate.

N, N-Diethyl-p-phenylenediamine hydrochloride

*N, N-Diethyltoluene-2. 5- diamine, monohydrochloride

2.5-Dihydroxy-p-benzenedisulfonic acid, dipotassium salt

2,5-Dihydroxybenzenesulfonic acid

2, 7-Dihydroxy-3, 6- naphthalene sulfonate

p-Dimethylaminobenzenediazonium chloride ( p-Diazo-N, N-

dimethylaniline) - zinc chloride. <i-(2',6'-Dimethylmorpholinyl)benzenediazonium chloride - zinc chloride.

p-Diphenylaminediazonium sulfate

p-(N-Ethylbenzimido)benzenediazonium chloride (p-Diazo-

N-henzyl-N-ethylaniline) - zinc chloride. p-[ Ethyl( 2-hydroxyethyl) amino] benzenediazonium chloride (p-Diazo-N-ethyl-N-hydroxyethylaniline) - zinc chlo- ride.

N-Ethyl-N-hydroxyethyl-p-phenylenediamine sulfate

N-Ethyl-N-(p-methanesulfonamidoethyl)toluene-2,5-diamine sulfate.

Hydroquinone ( Hydroquinol)

p-[( 2-Hydroxyethyl) methylamino]benzenediazonium chloride ( p-Diazo-N- hydroxyethyl-N-methylaniline) - zinc chloride. 1- Hydroxy- N-( 2-hydroxyethyl) -2-naphthamide (2,3-Oxynaph- thoic-mono-ethanolamide) .

l-(3-Hydroxyphenyl)urea

4-Methoxy-l-naphthol

p-Methylaminophenol sulfate (Metol)

5-Methylbenzotriazole

2-Methylbenzoxazole

4-Methyl-l-phenyl-3-pyrazolidinone

4-Morpholinylbenzenediazonium chloride - zinc chloride salt.

4-Morpholinylbenzenediazonium fluoroborate

6-Nitrobenzimidazole

Octylphenyl salicylate

Phenylmercaptotetrazole

Phenyl-5-mercaptotetrazole

l-Phenyl-3-pyrazolidinone

4-Phenylpyrocatechol

2-Eesorcylic monoethanolamide

4,4'-Thiodiresorcinol (Diresorcyl sulfide)

l-( 2, 4, 6-Trichlorophenyl) -3-( 4-nitroanilino) -2-pyraz- olin-5-one.

All other

Phthalic acid, lead salt, dibasic

*Pinene

Poly-4-( 2-acryloxy ethoxy) -2-hydroxybenzophenone

Polyethylene terephthalate

Poly-2-hydroxy-4-methacryloxybenzophenone

Polyvinyl phthalate

*Propyl gallate

Pyrogallol (Pyrogallic acid)

Resorcinol monobenzoate

Rosin acid salts:

Aluminum resinate

Calcium resinate

Copper resinate

Iron resinate

Lead resinate

Manganese resinate

Zinc resinate

All other

Salicylanilide

Salicyclic acid, lead salt

Silicones

Manufacturers' identification codes ( according to list in table 22)

FMT, G, IDC, MRT. IDC.

EKT, PMT. HCT, FMT, IDC.

FMT. FMT, IDC.

FMT. FMT, MRT.

FMT, IDC.

IDC. EKT.

EKT. FMT, IDC.

FMT, IDC. x.

IK. EK.

FMT. WAY. IDC.

IDC.

EK, FMT.

EKT.

TNC.

FMT.

GGY, WAY.

x.

FMT.

HCC.

EKT.

EK, EKT, FMT.

NTL.

CBY, GLD, HNW, HPC.

ACY.

DUP, EK.

DUP.

EK.

EKT, HN, HSH.

MAL.

HCT.

JMS.

JMS, SW.

JMS.

HSH, JMS.

JMS, MCI.

JMS.

JMS, SW.

JMS.

DUP, FIN, MEE, PCW.

NTL.

DCC.

MISCELLANEOUS CHEMICALS

171

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1965 — Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, CYCLIC— Continued

Sodium cresoxide (Cresylic acid, sodium salt)

Sodium ferric ethylenediamine di-o-hydroxyphenylacetate —

Sucrose benzoate

Sulfosalicylic acid

Tall oil fatty acid chloride

*Tall oil salts (Linoleic- rosin acid salts):

Barium zinc tallate

*Calcium tallate

*Cobalt tallate

Copper tallate

*Iron tallate

Lead manganese tallate

*Lead tallate

^Manganese tallate

*Zine tallate

Tannic acid

*Tanning materials, synthetic:

Hydroxytoluenesulfonlc acid, formaldehyde condensate ( Cresol- formaldehyde sulfonate), sodium salt. *2-Naphthalenesulfonie acid, formaldehyde condensate and salts. 1-Pheno 1-2- sulfonic acid, formaldehyde condensate (Phenol- formaldehyde, sulfonated) .

1-Pheno 1-4- sulfonic acid, formaldehyde condensate

Styrene maleic anhydride interpolymer, partial sodium

salt. Sulfonyldiphenolsulfonic acid, formaldehyde condensate--

All other

Tetra(n- butyl) ammonium picrate

3,3',4,4'-Tetrachlorophenylurea

1,2,3,4-Tetrahydronaphthalene (Tetralin)

Tetrahydrothiophene

Tetramethylaminoethylpiperazine

Tetraphenyltin

*Textile chemicals, other than surface-active agents: 1, 3-Bis( hydroxymethyl) -2- imidazolidone ( Dimethylol ethylene urea) .

N',N'-Diphenyl-l,2-propanediamine

l-[ ( Octadecyloxy) methyl] pyridinium chloride

Phenol, sulfurated

Tetrahydro-3, 5-bis( methoxymethyl) -4H- 1, 3, 5-oxadiazin-4- one ( 1, 3- Bis( methoxymethyl) uron) .

2,2',4,4'-Tetrahydroxybenzophenone

All other

2,2'-Thiobis[4-ehlorophenol]

2,2'-Thiobis[4, 6-dichlorophenol]

[ 2,2'-Thiobis(4-octylphenolate)] -n-butylamine nickel

o-Toluidine formaldehyde hydrochloride

Triallyl cyanurate

Triaryl phosphites

3,4',5-Tribromosalieylanilide

3,4',5-Tribromosalicylanilide and dibromosalicylanilide mixtures.

3,4,4'-Triehlorocarbanilide _ —

Trichloromelamine

l,3,5-Triehloro-s-triazine-2,4,6(lH,3H,5H)trione (Tri- chloroisocyanuric acid) .

Tri-(m, p)-cresyl borate

p-Trifluoromethylbenzonitrile

s-Trioxane

Triphenyl phosphite

Triphenylphosphorus

Triphenyltin acetate

Triphenyltin chloride

Tris( 1-aziridinyl) phospnine oxide

2, 4, 6-Tris( 2-hydroxy-4-octyloxyphenyl) -s-triazine

Uridine derivatives

l-Vinyl-2-pyrrolidinone, monomer and polymer

l-Vinyl-2-pyrrolidinone - vinyl acetate copolymer

DEX, GOC. GGY. VEL.

MON, MRK. G.

HSH.

CCA, HNX, HSH, MCI, MLD, TRO, VITC.

CCA, CCC, FER, HNX, MCI, MLD, SHP, SRR, TRO, WTC.

MCI, MLD, SHP, SRR.

CCA, MCA, MCI, MLD, SRR, WTC.

HSH, MCI.

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SM, SRR, TRO,

WTC.

CCA, CCC, FER, HNX, HSH, MCI, MLD, SHP, SRR, TRO, WTC.

CCA, HSH, MCI.

HSH, MAL.

GGY.

AKS, GRD, NOP, NYC, RH.

NAC, NOP, RH.

AKS. DUP.

G.

GGY.

MED.

OTC.

DUP.

0R0, PAS.

JCC.

x.

ACY, AKS.

SNW. DUP.

AKS,

x, x.

GIV.

MON,

SDH.

ACY.

RBC.

ACY.

WES.

DOW,

FIN, MEE, TRO

FIN.

MON.

WTH.

FMB,

MON.

USB.

PIC.

CEL.

HK,

MON.

PLB. G.

G.

172

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B.

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers1 identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC

*Acetaldehyde

Acetamide

Acetamidine hydrochloride

Aeetamidoethanol ( N-Acetylethanolamine)

*Acetic acid, synthetic, 100$

*Acetic acid salts:

Aluminum acetate

Aluminum subacetate

Ammonium acetate

Barium acetate

Cadmium acetate

Calcium acetate

Chromium acetate

Cobalt acetate

*Copper acetate

Lead acetate

Lead subacetate

Lead tetraacetate

Magnesium acetate

Manganese acetate

Mercuric acetate

Methylmercury acetate

Nickel acetate

*Potassium acetate

Silver acetate

*Sodium acetate

Sodium diacetate

Strontium acetate

Uranyl acetate

*Zine acetate

* Zirconium acetate

*Acetie anhydride, 100$:

From acetaldehyde

From acetic aeid_, other than recovered, by the vapor- phase process. From acetic acid, recovered, by the vapor-phase process-

From ethylene

Acetin:

Mono-

Tri -

Acetoacetamidoacetamide

*Acetone:

*From cumene

*From isopropyl alcohol

*A11 other

Acetone, dimethyl acetal (2,2-Dimethoxypropane)

Acetone semicarbazone

Acetonitrile

Acetyl chloride

Acetyl peroxide

Aconitic acid

Acrolein ( Acrylaldehyde)

*Acrylic acid

Acrylic monomers

*Aerylonitrile

*Adipic acid

Adiponitrile

*Alcohols, monohydric, unsubstituted: *Alcohols C9 or lower:

Allyl alcohol

Amyl alcohols: Unmixed:

2»Methyl-2-butanol (tert-Amyl alcohol)

3-Methylbutanol

1-Pentanol

2-Pentanol

3-Pentanol

Mixed:

Fusel oil, refined

Other than fusel oil

CEL,

COM,

DIX,

DUP,

EKT,

HPC, MON, PUB, SHC, UCC

ACG.

MRK.

RBC.

CEL,

EKT,

HPC,

PUB,

SNC,

UCC.

ACY,

UCC.

MAL.

ACG,

BKC,

MAL,

WSN.

ACG,

BKC,

MAL.

MAL,

SHP.

ACG,

BKC,

MAL,

WSN.

ACY.

BKC,

HSH,

SHP.

ACG,

BKC,

UCC

ACG,

BKC,

MAL,

SRR,

sw.

ACG,

BKC,

MAL.

ABA.

ACG,

BKC.

HSH,

SHP.

BKC,

MAL.

DUP.

BKC,

HSH,

SHP.

ACG,

BKC,

CWL,

MAL,

UCC,

WSN.

MAL.

ACG,

BKC,

CEL,

DAN,

EKT,

MAL, UCC, WSN.

UCC.

BKC.

BKC.

ACG,

BKC,

HSH,

MAL,

SNW,

UCC.

HSH,

NTL,

SNW.

HPC.

CEL,

EST.

CEL.

UCC.

ARC,

HAL.

EKT,

WM.

RBC.

ACP,

CLK,

HPC,

MON,

SHC,

SKO, SOC.

EKT,

EN J,

SHC,

UCC.

CEL,

DIX,

HPC,

TBK.

DOW.

NOR.

EKX,

SOH,

UCC.

TBK.

WTL.

PCW.

SHC,

UCC.

BFG,

CEL,

DBC,

MMM,

UCC.

BH.

ACY,

BFG,

DUP,

MON,

SOH,

UCC.

CEL,

DUP,

MON,

NAC,

RH.

DUP,

MON.

DOW,

OMC,

SHC.

PAS,

UCC.

UCC.

TBK,

UCC.

UCC.

EK.

PUB.

CEL,

PAS,

UCC.

MISCELLANEOUS CHEMICALS

173

TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965— Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

*Aleohols, monohydric, unsubstituted — Continued *Alcohols C9 or lower — Continued *Butyl alcohols: Primary:

*Iso ( Isopropylcarbinol)

*Normal ( n-Propylcarbinol)

Secondary (Methylethylcarbinol)

Tertiary (Triinethylcarbinol)

Mixed

*Ethyl alcohol, synthetic

2-Ethyl-l-butanol (sec-Hexyl alcohol)

*2- Ethyl- 1-hexanol

2-Ethyl-4-methyl-l-pentanol

4- Ethyl- l-octyn-3-ol

Heptyl alcohol

*Hexyl alcohol

3-Hexyne-2-ol

*Iso-octyl alcohols

*Isopropyl alcohol

^Methanol, synthetic

2-Methyl-3-buten-2-ol

2-Methyl-3-butyn-2-ol

4~Methyl-2-pentanol ( 1-Methylisobutylcarbinol)

3-Methyl-l-pentyn-3-ol (Methylparafynol)

1-Octanol ■

2-0ctanol

Octanols, other

Propyl alcohol (Propanol)

2-Propyn-l-ol

All other

*Alcohols C10 or higher:

*Deeyl alcohols

3,9-Diethyl-6-tridecanol

Dodecyl alcohol (Lauryl alcohol) (95$)

7-Ethyl-2-methyl-4-hendecanol

*l-Hexadeeanol (Cetyl alcohol) (95<f)

*l-0ctadecanol (Stearyl alcohol) (95%)

cis-9-0ctadecen-l-ol (Oleyl alcohol)

Tallow alcohol

Tetradecanol

1-Tridecanol

Tridecanol mixed isomers

2, 6, 8-Trimethyl-4-nonanol

All other

Aldol (Acetaldol)

ALkane and aliene hydrocarbons

Aliyl and aliylene hydrocarbons

Aliyl sulfides, mixed

l-Allyl-3-( 2-hydroxyethyl) -2-thiourea ( N-p-Hydroxyethyl- N'-allylthiourea) .

Allyl isocyanate

Allyl isothiocyanate, nonflavoring grade

Allyl methacrylate

Allyl nitrile (Allyl cyanide)

l-(Allyloxy)-2,3-epoxypropane (Allyl glycidyl ether)

3-(Allyloxy)-l,2-propanediol (AlLyl glyceryl ether)

Aluminum isopropoxide (Aluminum isopropylate)

Amidinourea (Guanylurea) phosphate and sulfate

*Amines:

*Butylamine

tert-Butylamine

n-Butylethylamine

Butylmethylamine

Diallylamine

*Dibutylamine

Dibutylmethylamine (Methylbutylbutylamine)

*Diethylamine ■

Diethylamine hydrochloride

Diethylaminopropylamine

Manufacturers' identification codes (according to list in table 22)

CEL, DBC

EKX,

ENJ, SHC, UCC.

CEL, CO,

DBC,

EKX, ENJ, SHC, UCC.

ENJ, SHC

SHC.

CEL, DBC,

EKX.

CEL, DUP,

EKX,

ENJ, HPC, PSP, SHC, UCC, USI.

UCC.

CEL, EKX,

ENJ,

SHC, UCC.

EKX.

cue.

EKX.

EKX, ENJ,

UCC.

LIL.

EKX, ENJ,

GOC,

HOU, 0X0, TID, UCC.

ENJ, SHC,

TBK,

UCC.

ACN, BOR,

CEL,

COM, DUP, ESC, GYR, HPC, WON, RH, SPN

UCC.

cue.

cue.

SHC, UCC.

cue.

DUP.

PG, RH, WTH.

IFF.

CEL, UCC.

G.

CEL, CO,

PG, TNA.

DUP, ENJ,

GOC,

HOU, 0X0, PG, TBK, TID, TNK, UCC.

UCC.

DUP, PG,

RH.

UCC.

ADM, DUP,

ENJ,

GIV, PG, RH.

ADM, DUP,

PG,

RH.

ADM, DUP.

ADM.

PG.

ENJ, GOC.

UCC.

UCC.

ADM, CO,

EKX,

PG, RH, SHC, TNA.

UCC.

HMY.

ADM, GOC.

OHO.

FMT, IDC.

CTN.

ICO.

SAR.

KF.

SHC.

SHC.

CHT, SFA.

ACY.

EKT, PAS,

UCC,

VGC.

»N, RH.

PAS.

PAS.

SHC.

'AS, UCC,

VGC.

UCC.

DUP, PAS,

UCC,

VGC.

174

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B.

--Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer, 1965 — Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

*Amines — Continued

Diethylenetriamine

N, N-Diethylethylenediamine

N jN1 -Diethyl- 1, 4- pentanediamine (Novoldiamine)

N, N-Diethyl-l,3-propanediamine

Diisobutylamine

Diisopropylamine

*Dimethy lamine

Dimethylamine hydrochloride

Dimethylamine sulfate

Dime thy land nopropy lamine

Dipentylamine (Diamylamine)

Dipropy lamine

Dipropylenetriamine

*Ethy lamine

Ethylenediamine

Ethylenediamine sulfate

n-Heptylamine

1, 6-Hexanediamine ( Hexamethylenediamine)

N-Hexylamine

3,3'-Iminobispropylamine

Isobuty lamine

*Isopropy lamine

Methy lamine hydrochloride

*Methylamine, mono-

N-Methylethylenediamine

N-Methyl-l,3-propanediamine

Methyltriethylenediamine

Pentaethylenehexamine

Pentylamine (Mono amy lamine)

1, 2-Propanediamine (Propylenediamine)

1, 3-Propanediamine

Propylamine

Tetraethylenepentamine

N,N,N',N'-Tetramethyl-l,3-butanediamine

Tetramethylethylenediamine

Tributy lamine

Triethylamine

Triethylenetetramine

*Trimethy lamine

Tripenty lamine

All other

2-Amino-l-butanol

1-Aminoethanol (Acetaldehyde ammonia)

Aminoethoxyethanol

2-( 2-Aminoethylamino) ethanol ( Aminoethylethanolamine)

2-Aminoethyl vinyl ether

Aminoguanidine bicarbonate

2- Amino-2- ( hydroxymethyl) - 1, 3-propanediol ( Tris( hydroxy- methyl) aminomethane) .

2-Amino-2-methyl-l-propanol hydrochloride — —

2-Amino-l-propanol

3-Amino-l-propanol

Amyl acetates, 90$:

Amyl acetate (n-Pentyl acetate)

Isopentyl acetate ( Isoamyl acetate)

Mixed

Azelaic acid

1, l'-Azobisformamide ( Azodicarbonamide)

2,2'-Azobis(2-methylpropionamidine) hydrochloride

Behenamide (Docosanamide)

Behenic acid

Bis(2-butoxyethyl) ether (Diethylene glycol di-n- butyl ether) .

Bis( 2-chloroethoxy) methane ( Dichloroetnylformal)

*Bis(2-chloroethyl) ether ( Dichlorodiethyl ether)

Bis(2-ehloroethyl) and bis(2-chloro-l-methylethyl) ethers

mixed. Bis( chloromethyl) ether

Manufacturers' identification codes ( according to list in table 22)

DOW,

JCC,

UCC.

ALB,

COK.

SDH.

JCC.

PAS.

PAS,

UCC,

VGC.

COM,

DUP,

PAS, RH.

GAM,

TNC.

RH.

UCC.

PAS,

VGC.

PAS,

UCC.

UCC.

ESC,

PAS,

UCC, VGC.

DOW,

JCC,

UCC.

EK.

ALB.

CEL,

DUP,

MON.

VGC.

JCC,

UCC.

PAS,

VGC.

ESC,

PAS,

UCC.

RBC.

COM,

DUP,

ESC, g, p;

ALB.

ALB.

JCC.

DOW.

EK,

3AS.

JCC,

UCC.

UCC.

PAS,

UCC.

DOW,

UCC.

UCC.

RH.

PAS,

VGC.

PAS,

UCC.

ccw,

DOW,

UCC.

COM,

DUP,

PAS, RH.

PAS.

ALB,

DUP,

ONX, UCC.

COM.

PAS.

JCC.

DOW,

JCC,

UCC.

MEE,

RH.

TBJ.

COM.

SNW.

LIL.

UCC.

PUB,

TBK.

FB,

NW.

CEL,

PAS,

UCC.

EMR.

FMT,

NPI,

USR.

X.

HUM.

ADM.

DOW,

UCC.

TKL.

DOW

JCC

CMC, UCC.

WYN.

MISCELLANEOUS CHEMICALS

175

TABLE 21B.-

-Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965- -Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Bis(2-chloro-l-methylethyl) ether ( Dichloroisopropyl

ether) . Bis(2-ethoxyethyl) ether (Di ethylene glycol diethyl ether) Bis(hydroxyethyl) ether butynediol

1, 3-Bis( hydroxymethyl) urea ( Dimethylolurea)

Bis[2-(2-methoxyethoxy)ethyl] ether ( Tetraethylene glycol

dimethyl ether) . Bis(2-methoxyethyl) ether (Diethylene glycol dimethyl ether) .

Bis( tributyltin) oxide

Biuret

Boron organic compounds:

Boron fluoride ethyl ether complex

Boron trifluoride monoethylamine complex

tert-Butylaminoborane

Triethylborane

Triethyl borate

Trimethoxyboroxine

Trimethylaminoborane

All other

N-Bromoaeetamide

fj-Bromopropionic acid

1, 2(and l,3)-Butanediol (Butylene glycol)

1,4-Butanediol

2,3-Butanediol (2,3-Butylene glycol)

2,3-Butanedione 2-oxime

1,2,4-Butanetriol

*2-Butanone (Methyl ethyl ketone)

Butanone mixture

*2-Butanone oxime

*2-Butanone peroxide

2-Butene-l,4-diol

l-Butoxy-2,3-epoxypropane (Butyl glycidyl ether)

2-Butoxyethanol (Ethylene glycol monobutyl ether)

2-(2-Butoxyethoxy)ethanol (Diethylene glycol monobutyl

ether) . 2-[2-(2-Butoxyethoxy)ethoxy] ethanol (Triethylene glycol monobutyl ether) .

2-(2-Butoxyethoxy) ethyl acetate

l-Butoxyethoxy-2-propanol

2-Butoxyethyl acetate

*Butyl acetates:

Iso

*Normal

Secondary

Tertiary

Mixed

Butyl aery late

Butylene oxide

Butyl ether (Di-n-butyl ether)

Butylethylthiourea

*tert- Butyl hydroperoxide

2,2'-(Butylimino)diethanol (N,N-Bis(2-hydroxyethyl)butyl- amine) .

Butyl isocyanate *

Butyl lactate

n-Butyllithium

sec-Butyllithium

Butyl maleate, mono-

Butyl oxalate partial ester

*tert-Butyl peroxide (Di-tert- butyl peroxide)

tert- Butyl peroxyacetate

tert- Butyl peroxyisobutyrate

tert-Butyl peroxyisopropyl carbonate

tert- Butyl peroxypivalate

Butyl vinyl ether

1-Butyne ( Ethylacetylene)

2-Butyne-l,4-diol

Butyraldehyde

Butyraldehyde oxime

DOW.

ucc.

G.

DEC, GLY, x.

ASL.

ASL, OMC.

CCW, x. SW.

ACG.

ACG.

CAL.

CAL, TNA.

USB.

CAL.

CAL.

CAL, SFA, USB.

ARA.

ABB.

CEL.

EK.

G.

CEL,

CEL.

ALB,

AZT,

G.

DOW,

JCC,

JCC,

DIX, ENJ, SHC, SPI, UCC.

CCA, MID, NAC, TED. CAD, NOC, RIC, UPR, WTL.

SHC.

OMC, SHC, UCC.

OMC, SHC, UCC.

DOW, OMC, UCC.

UCC. UCC. UCC.

CEL,

CEL,

EK,

ENJ.

CEL.

CEL,

DOW,

UCC.

PAS.

AZT,

PAS.

CTN, COM, FTE. FIE. RUB. DUP. AZT, WTL. WTL. PPG. WTL. UCC.

cue.

G.

CEL, NAC.

EKT, UCC.

EKT, ENJ, PUB, UCC. ENJ, HPC, PUB, SHC.

DBC, UCC. UCC.

CAD, UPR, WTL.

UPJ. CWN, UPC.

CAD, SHC, UPR, WTL.

HOC, UCC.

176

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B -Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Chemical

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

*Butyric acid

Butyric anhydride

Butyrolactone

Butyronitrile

Butyryl chloride

*Caprolactam (Hexahydro-2H-azepin-2-one)

Capro lactone

*Carbon disulfide

^Cellulose esters:

^Cellulose acetate

Cellulose acetate butyrate

Cellulose acetate propionate

Cellulose propionate

Nitrocellulose (Cellulose nitrate)

^Cellulose ethers:

Ethylcellulose

Ethylhydroxyethylcellulose

Hydroxyethylcellulose

Methylcellulose

*Sodium carboxymethylcellulose, 100%

Sodium carboxymethylhydroxyethylcellulose

Cetyl chloride

Cetyl lactate

*Chloral ( Trichloroacetaldehyde)

Chloroacetamide

*Chloroacetic acid, mono-

Chloroacetic acid, mono-, derivatives:

Butyl chloroacetate

Ethyl chloroacetate

2-Ethylhexyl chloroacetate

*Methyl chloroacetate

Sodium chloroacetate

Chloroacetonitrile

Chloroacetyl chloride

P-Chloroallyl-N-methylamine

Chlorocholine chloride ~~

2-Chloro-l, 1-dimethoxyethane (Dimethyl chloroacetal) - *2-Chloro-N, N-dimethylethylamine ( Dimethylaminoethyl chloride) hydrochloride.

2-Chloro-N,N-dimethylpropylamine

3-Chloro-N, N-dimethylpropylamine hydrochloride

2-Chloroethanol (Ethylene chlorohydrin)

2-Chloroethylamine

2-Chloroethyl chloroformate

2-Chloroethyl vinyl ether

Chloromethyl methyl ether -■

l-Chloro-l-penten-3-one (p-Chloro vinyl ethyl ketone)- 3-Chloro-l,2-propanediol (Glycerol a-chlorohydrin)---

l-Chloro-2-propanone ( Chloroacetone)

N-Chlorosuccinimide ( Succinichlorimide)

2-Chlorotriethylamine hydrochloride

Chlorotrlmethylsilane

Choline base

Citric acid

Citric acid salts:

Ammonium citrate

Calcium citrate

Ferric ammonium citrate

Ferric citrate

Ferrous calcium citrate

Potassium citrate

Sodium citrate

All other

Coconitrile

Coconut oil amide

Cottonseed oil acids, ammonium salt

Cottonseed oil nitrile

Creatine and creatinine

Crotonaldehyde

Manufacturers' identification codes ( according to list in table 22)

CEL, EKT, UCC. EKT, UCC.

DBC, DUP, NAC.

UCC.

ACG, BKT, FMB, PAS, PPG, SF.

AV, CEL, DUP, EKT.

EKT.

EKT.

CEL.

DUP, HPC.

DOW,

HPC.

HPC.

HPC,

UCC.

DOW.

BUK,

DUP, HPC, KON, WYM.

HPC.

BC.

VND.

DA, FMB, GGY, MTO.

BPC,

DOW.

BUK,

DA, DOW, HPC, MON.

MON.

DOW,

KF, WON.

MON.

BPC,

DOW, KF.

DOW.

BPC.

DOW,

DUP.

LIL.

ACY.

LIL.

ABB,

GAM, HEX, MCH, NES, PAS

SK.

MCH.

CMC,

UCC.

ICI.

CTN.

UCC.

HK,

X.

ABB.

EVN,

ICO, OTC.

EK,

MRK.

ARA,

NAC.

MCH,

PAS, X.

DCC.

EH.

MLS,

PFZ.

MAL,

PFZ.

PFZ.

MAL,

PFZ.

MAL.

X.

MLS

PFZ.

MLS

PFZ.

MLS

FOR,

ARC

CRT, PG.

GLY

FOR

PFN

CEL

EKT, UCC.

MISCELLANEOUS CHEMICALS

177

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Chemical

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Crotonic acid (2-Butenoic acid)

Crotononitrile

2-Cyanoacetamide

Cyanoacethydrazide

Cyanoacetic acid

Cyanogen bromide

3-Cyanopropylamine

1, 10-Decanediol

Decanoyl chloride

*Decanoyl peroxide

Dialdehyde starch

Diallylcyanamide

Diallyl maleate

1, 2-Dibutoxyethane (Ethylene glycol di-n- butyl ether) -

2-Dibutylaminoethanol

*Dibutyl fumarate

*Dibutyl maleate

1, 3-Dibuty 1-2- thiourea

Dibutyltin compounds:

Dibutylmethoxytin (Dibutyltin methoxide)

Dibutyltin bis( lauryl mercaptide)

Dibutyltin dichloride

Dibutyltin dilaurate

Dibutyltin maleate

Dibutyltin mercaptopropionate

Dibutyltin oxide

All other

Dichloroacetaldehyde

Dichloroacetic acid

2,2-Dichloro-l, 1-difluoroethyl methyl ether

Dichlorodimethylsilane

Dichloromethylsilane

Dichloromethylvinylsilane

l,3-Dichloro-2-propanol

Dicyanobutene

Diethyl allyl( 1-methylbutyl) malonate

Diethylaluminum chloride

Diethylaluminum iodide

Diethylaminoethanethiol

*2-Diethylaminoethanol

2-(2-Diethylaminoethoxy) ethanol

2-Diethylaminoethyl methacrylate

Diethylaminopropionamide

Diethyl sec-butylethylmalonate

Diethyl butylmalonate

Diethyl sec- butylmalonate

Diethylcarbamoyl chloride

Diethyl carbonate (Ethyl carbonate)

Diethyl diethylmalonate (Diethyl malonic ester)

*Diethylene glycol

Diethylene glycol, borated

Diethylene glycol chloroformate

Diethyl ( ethoxymethylene) malonate

Diethyl ethylisopentylmalonate

Diethyl ethylmalonate (Ethyl malonic ester)

Diethyl ethyl( 1-methylbutyl) malonate

Diethyl ethyl(3-methylbutyl) malonate

Diethyl ethyl( 1-methylpropyl) malonate

Di-2- ethyl- 1-hexyl fumarate

Di-2- ethyl- 1-hexyl maleate

Diethylhydroxylamine

N, N-Diethylhydroxylamine sulfate

Diethyl maleate

Diethyl malonate (Malonic ester)

Diethyl ( 1-methylbutyl) malonate

Diethyl (3-methylbutyl) malonate

Diethyl ( 1-methylpropyl) malonate

Diethyl oxalate (Ethyl oxalate)

Diethyl phosphorochloridothioate —

EEC.

KF.

KF.

KF.

KF.

ffl.

EKT.

NEP.

TBK, UCC.

CAD, UPR, WTL.

MLS.

ACY.

FMP.

DOW.

AAC, PAS.

MON, PCC, PFZ, RCI, RUB.

CUC, DUP, GRH, MON, PCC, RCI, RUB.

PAS, RBC.

CCA. x.

CCW, x.

CCA, x.

CCA, x.

CCA, x.

PAS, UCC.

FMP.

CAU, DIX, DOW, G, HCH, JCC, CMC, UCC, WYN.

ABB,

GAM

CTN

BPC

ACN

GLY.

PPG,

KF.

LIL.

BPC, LIL.

ABB, BPC.

BPC.

BPC.

RUB.

RUB.

PAS.

EK.

ACY, ICO, UCC.

ABB, KF, LIL.

ABB, BPC, LIL.

BPC.

BPC.

FMP.

MON, SF.

l,3-Diethyl-2- thiourea | pas, RBC

178

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965— Continued

Chemical

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Diethylzinc

Diglycolio acid

Dihexyl fumarate

Dihydropseudoionone

2,4-Dihydroxy-3,3-dimethylbutyric acid, Y- lactone (Panto- lactone) .

l,3-Dihydroxy-2-propanone (Dihydroxy acetone)

Diisobutylaluminum chloride

Diisobutylaluminum hydride

Diisononyl maleate

Diiso-octyl fumarate

2-Diisopropylaminoethanol ( N, N-Diisopropylethanolamine) —

Diisopropylammonium nitrite

Diisopropylcarbodiimide

Diisopropyl peroxydicarbonate ( Isopropyl percarbonate)

1,3-Diisopropy 1-2- thiourea

*Dilauryl 3,3'-thiodipropionate (Didodecyl thiodipropio- nate) .

Dimethoxyethane ( Ethylene glycol dimethyl ether)

N,N-Dimethylacetamide

N, N-Dimethylacetoaeetamide

*2-Dimethylaminoethanol

Dimethylaminoethyl methaerylate

Dime thy lamino-2-propanol

3-Dimethylaminopropionitrile

N-(3-Dimethylaniinopropyl)oleamide

Dimethylcarbamoyl chloride

Dimethyl carbonate

2, 5-Dimethyl-2, 5-di( tert-butylperoxy) hexane

2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3

N, N-Dimethylformamide

2, 6-Dimethyl-4-heptanol ( Diisobutylcarbinol)

2,5-Dimethyl-2,5-hexanediol

2,5-Dimethylhexane-2,5-diperoctoate

2, 5-Dimethyl-3-hexyne-2, 5-diol

1, 1-Dimethylhydrazine

Dimethyl malonate

Di(4-methyl-2-pentyl) maleate

0, 0-Dimethyl phosphorochloridothioate

2,2-Dimethyl-l,3-propanediol (Neopentyl glycol)

Dimethylthiophosphoryl chloride

Dioctanoyl peroxide (Capryloyl peroxide)

Dioctyl fumarate

*Dioctyl maleate

*Dipropylene glycol

Distearyl 3,3'-thiodipropionate

Dithiobis( stearylpropionate) (Distearyl dithiodipropio- nate) .

2,5-Dithiobiurea

Dithiooxamide

Ditridecyl maleate

n-Dodecane

Dodecenylsuccinie anhydride

tert-Dodecyldisuccinamide

n-Eicosane

Epichlorohydrin

*Erucamide

Ethanedithiol

* Ethanolamines :

*2-Aminoethanol (Monoethanolamine)

*2,2'-Iminodiethanol (Diethanolamine)

*2,2',2"-Nitrilotriethanol (Triethanolamine)

Ethanolamine hydrochloride

Ethanolamine sulfate

Ethanolamine sulfite

Ethanolamine trihydrochloride

*2-Ethoxyethanol (Ethylene glycol monoethyl ether)

*2-(2-Ethoxyethoxy)ethanol (Diethylene glycol monoethyl ether) .

Manufacturers' identification codes ( according to list in table 22)

TNA.

DUP. FB. GIV. CKL.

BAX, PFZ.

TSA.

TSA.

RUB.

HUB.

PAS, UCC.

CMC.

G.

PPG.

G.

ACY, CCW, EVN, HAB.

ASL. DUP, EKT. AAC, AAC. COM, ACY. DUP. OTC. CTN. WTL. WTL. DUP. UCC.

cue.

UPR. CUC. FMP. KF.

MON.

JCC, PAS, RH, UCC.

UCC.

RUB.

MON,

SF.

EKX.

TBK.

CEM.

MON.

CRT,

MON,

PCC,

RCI.

CEL,

DOW,

JCC,

OMC, UCC, WYN

ACY,

CCW,

EVN.

EVM.

ACY.

MAL.

RUB.

HMY.

HMY,

MON,

NAC.

SM.

HMY.

DOW,

SHC,

UCC.

ADM,

ARC,

FIN,

HUM.

RBC.

ACN,

DOW,

JCC,

UCC.

ACN,

DOW,

JCC,

UCC.

ACN,

DOW,

JCC,

UCC.

WSN.

EVN.

SUM.

TNC.

DOW,

JCC,

OMC,

UCC.

DOW,

JCC,

OMC,

UCC.

MISCELLANEOUS CHEMICALS

179

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

*2-[2-(2-Ethoxyethoxy) ethoxy] ethanol (Triethylene glycol monoethyl ether) .

2-(2-Ethoxyethoxy) ethyl acetate

2-Ethoxyethyl acetate

Ethoxymethylene malononitrile

Ethoxypropanol

3-Ethoxypropionitrile

1- Ethoxy- 1,3, 3- trimethoxypropane

Ethyl acetamidocyanoacetate

Ethyl acetamidomalonate

*Ethyl acetate, 85$

Ethyl acetoacetate

*Ethyl aery late

Ethyl allyl-( l-methyl-2-pentyl) cyanoacetate

Ethylaluminum dichloride

Ethylaluminum sesquichloride

2-Ethylaminoethanol ( Ethylmonoethanolamine)

2-Ethylbutyraldehyde

2- Ethylbutyric acid (Diethylacetic acid)

Ethyl carbamate

Ethyl carbodiimide

Ethyl chloroformate

Ethyl 3-( ehloroformyl) propionate (fj-Carbethoxypropionyl chloride) .

Ethyl cyanoacetate

Ethylene, from ethyl alcohol

Ethylene carbonate

Ethylenediamine, propoxylated

* Ethylene glycol

Ethylene glycol diacetate

Ethylene glycol dimethacrylate

* Ethylene oxide

Ethylene trithiocarbonate

*Ethyl ether:

Absolute

Tech

U.S.P, - —

Ethylethoxymethylene cyanoacetate

Ethyl formate

2- Ethylhexanal (a-Ethylcaproaldehyde)

2-Ethyl-l,3-hexanediol

2- Ethylhexanoic acid (x-Ethylcaproic acid)

*2- Ethylhexanoic acid (a-Ethylcaproic acid) salts:

Aluminum 2-ethylhexanoate

Barium 2-ethylhexanoate

Cadmium 2-ethylhexanoate

^Calcium 2-ethylliexanoate

*Cobalt 2-ethylhexanoate

Copper 2-ethylhexanoate

Dibutyltin di-2-ethylhexanoate

Iron 2-ethylhexanoate

*Lead 2-ethylhexanoate

*Manganese 2-ethylhexanoate

Nickel 2-ethylhexanoate

Potassium 2-ethylhexanoate

Rare earths 2-ethylhexanoate

Stannous 2-ethylhexanoate

Strontium 2-ethylhexanoate

*Zinc 2-ethylhexanoate

Zirconium 2-ethylhexanoate

*2-Ethyl-l-hexyl acetate

*2-Ethyl-l-hexyl acrylate

2-Ethylhexyl cyanoacetate

2-Ethylhexyl methaerylate

Ethyl 2-hydroxy-3-methylbutyrate ( Ethyl a-hydroxyiso-

valerate) . 2- Ethyl-2- ( hydroxymethyl) - 1, 3- propanediol ( Trimethylol-

propane) . 2- Ethyl-2- ( hydroxymethyl) - 1, 3-propanediol allyl ethers—

DOW,

OMC,

UCC.

UCC.

DOW,

EKT,

UCC.

KF.

UCC.

ACY.

KF.

SDW.

SDW.

CEL,

EKT,

ENJ, HPC, MON, PUB, UCC

EXT,

FMP,

UCC.

CEL,

DBC,

RH, UCC.

LIL.

TNA,

TSA.

TNA,

TSA.

PAS.

UCC.

UCC.

EKL,

FMP.

OTC.

CTN,

FMP.

ABB.

KF.

OH.

DOW, JCC, UCC.

PCS.

ACN, APD, CAU, CEL, DOW, DUP, G, HCH, JCC, OMC, UCC,

WYN. UCC. SAR.

ACN, CAU, DOW, G, HCH, JCC, OMC, SNO, UCC, WYN. EVN.

MAL.

ENJ, HPC, UCC, USI.

MAL, OMS.

KF.

COM, FB.

EKX, UCC.

UCC.

EKT, UCC.

WTC.

CCA.

CCA,

CCA,

CCA,

CCA,

x.

CCA.

CCA,

CCA,

MCI.

CCA.

CCA.

WTC,

CCA.

CCA,

CCA,

CEL,

CEL,

G.

CEL. CEL.

FER, HNX, HSH, MCI, MLD, SRR, SW, WTC. FES, HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. MLD, SRR.

HNX, HSH, MCI, MLD, SHP, SRR, SW, WTC. HNX, MCI, MLD, SHP, SRR.

HNX, HSH, MCI, SRR, SYP, WTC.

HNX, WTC.

EKT, UCC.

DBC, UCC.

180

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Ethylidine diacetate

2, 2 '-( Ethylindno) diethanol ( N-Ethyldiethanolamine) —

2-( Ethylmercapto) ethanol

Ethylmereuric chloride

Ethyl ( l-methyl-2-pentyl) eyanoacetate

Ethyl propionate

Ethyl silicate (Tetraethoxysilane)

Ethyl sulfate (Diethyl sulfate)

Ethyl vinyl ether

Fats and oils, chemically modified:

Lard oil, nitrated

Vegetable oils, brominated

Other

Fatty acids, chemically modified:

cc-Bromo( lauric-stearic) acids

Castor oil fatty acids, dehydrated-

All other

Fatty acid esters, not included with plasticizers or surface- active agents:

Ethyl stearate

Hexadecyl stearate

Isopropyl linoleate

Isopropyl myristate

Isopropyl oleate

Methyl ester of coconut oil

Methyl esters of tallow

Methyl 12-hydroxystearat*-~—

Methyl stearate

All other

Fish oil fatty acid amide

Flotation reagents: Phosphorodithioates ( Dithiophosphates) :

Potassium dihexyl phosphorodithioate

Sodium di-sec-butyl diethyl phosphorodithioate —

Sodium di-see-butyl phosphorodithioate

Sodium diethyl phosphorodithioate

Sodium dihexyl phosphorodithioate

Sodium diisopropyl phosphorodithioate

Other

Xanthates:

Potassium n-butylxanthate

Potassium ethylxanthate

Potassium hexylxanthate

Potassium isopropylxanthate

Potassium pentylxanthates

Potassium sec-pentylxanthate

Sodium n-butylxanthate

Sodium sec-butyLxanthate

Sodium ethylxanthate

Sodium isobutylxanthate ;

Sodium isopropylxanthate

All other

^Formaldehyde, 37$ by weight

Formajrd.de

Formamidine disulfide dihydrochloride

*Formic acid, 90$

*Formic acid salts:

Aluminum formate

Ammonium formate

Calcium formate

Chromic formate

Chromium formate

Copper formate

Lead formate

Nickel formate

Potassium formate

Sodium formate, refined

Sodium formate, tech

Thallous formate — - —

CEL.

ucc.

PAS.

LIL.

LIL.

FB, NW, TBK.

MTR, SFA, UCC

UCC.

UCC.

SM. DOM. CHL, x.

DUP. BAC. ABB, RH, RT, x.

ICO. ARC, VND. TBK. CRT. STP. BFR, BAC. ICO. DRW, ADM.

EWR, ICI, PCS, PG, RT.

ACY. ACY. ACY. ACY. ACY. ACY. ACY.

USR.

ACY, DOW.

DOW.

DOW.

ACY, DOW.

DOW.

KCC, USR.

ACY, DOW.

ACY, DOW.

DOW.

ACY, DOW.

ACY, DOW.

ACN, BOR, CBC, CEL, COM, DUP, G, HKD, HN, HPC, ICI,

MON, RCI, RH, SPN, TRJ, UCP. DUP. WAY. DUP, HN, SF, SNC, UCC.

SF, SNW, UCC.

ACG, WSN.

TRJ.

G.

NAC.

CTN.

NTL.

HSH.

TNC.

ACG, BKC, SF.

HN, HPC.

EK.

MISCELLANEOUS CHEMICALS

131

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, iS65--Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

*Fumaric acid

Fumaric acid, lead salt

Geranyl crotonate

Glucoheptono lactone

^Gluconic acid, tech

Gluconic acid, ammonium salt

^Gluconic acid, sodium salt, tech

Glucono-delta- lactone

Glutaraldehyde

Glutaraldehyde bis[ sodium bisulfite]

Glutaric anhydride

Glycerol, synthetic

Glycidol (2,3-Epoxy-l-propanol)

Glycine (Aminoacetic acid), tech

Glycine, cupric salt

Glycine ethyl ester hydrochloride

Glycine, potassium and sodium salts

Glycol adipate

Glycolic acid ( Hydroxyacetic acid)

Glycolic acid salts:

Aluminum glycolate

Sodium glycolate

Glycolonitrile

Glyoxal

Guanidine hydrochloride

4-Guanyl-l-isonitrosoguanyl-l-tetrazene

*Halogenated hydrocarbons:

*l-Bromobutane (n-Butyl bromide)

2-Bromobutane (sec-Butyl bromide)

Bromochlorome thane

l-Bromo-3-ehloropropane (Trimethylenechloro bromide)

2-Bromo-2-chloro-l, 1, 1-trifluoroethane

1-Bromodecane

1-Bromododecane

Bromoethane (Ethyl bromide)

1-Bromohexadecane (Cetyl bromide)

1-Bromohexane (n-Hexyl bromide)

l-Bromo-2-methylbutane

l-Bromo-3-methyTbutane

1-Bromo-octadecane

1-Bromopentane (n-Amyl bromide)

2-Bromopentane ( 1-Methylbutyl bromide)

1- Bromopropane (n-Propyl bromide)

2- Bromopropane (isopropyl bromide)

2-Bromopropene

3-Bromopropene (Allyl bromide)

3-Bromopropyne

Bromotrifluoromethane

*Carbon tetrachloride

^Chlorinated paraffins:

Less than 35$ chlorine

355&-64# chlorine

6556 or more chlorine

1-Chloro butane (n- Butyl chloride)

2-Chlorobutane (sec-Butyl chloride)

1-Chloro-l, 1-difluoroethane

*Chlorodifluoromethane

*Chloroethane (Ethyl chloride):

Tech

U.S.P

*Chloroform:

Tech

U.S.P

2-Chloro-3-hexyne

*Chloromethane (Methyl chloride):

Crude

Refined (refrigerant grade)

2-Chloro-2-methylpropane ( tert- Butyl chloride)

3-Chloro-2-methylpropene (Methallyl chloride)

Chloropentafluoroethane

HN, MON, NAC, PCC, PFZ, PTT, SOC, STP.

NTL.

FB.

PFN.

CWL, DLI, IBI, PFZ.

PFZ.

CWL,

DLI,

UCC.

IDC, RZL.

UCC.

APD, DOW, SHC.

DIX, OTC.

BPC, CHT.

DLI, IBI, PFZ, PMP. PFZ.

CIB.

MED,

TNC.

ACY.

UCC.

ACY.

REM.

ABB,

BPC, DOW, MCH

ABB,

BPC.

DOW.

DOW,

MCH.

ICI.

G.

DUP.

DOW,

MCH.

EK.

BPC.

LIL.

BPC,

LIL.

DUP,

G.

BPC,

EK, OPC.

ABB,

BPC, LIL.

DOW,

EK.

BPC.

CLB.

DOW.

DUP.

ACG, ACS, DA, DOW, FMB, FRO, PPG, SF.

HK.

CCH, DA, DVC, HK, HPC, KPS, KPT, WOI.

DA, DVC, WOI.

PUB, UCC.

ICO, PLC.

ACG, DUP.

ACG, DUP, KAI, PAS, UCC.

AME, DOW, DUP, HPC, TNA, USI.

DOW, SHC.

ACS, DA, DOW, DUP, FRO, SF.

ACS, DA, DOW.

LIL.

DCC, DOW, TNA.

ACS, ANM, DOW, DUP, FRO.

EK.

FMP.

DUP.

182

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 21B -Miscellaneous chemicals for which US production or sales were reported, identified by 1Abbfi 'S1B• manufacturer, 1965— Continued

Chemical

MISCELLANEOUS CHIMICALS, ACYCLIC— Continued

*Halogenated hydrocarbons—Continued

2-Chloropropane (Isopropyl chloride) -----

3-Chloropropene (Allyl chloride)

Chlorotrifluoroethylene (Trifluorovinyl chloride)-—

Chlorotrif luoroethylene, polymerized

Chlorotrifluoromethane "'

1, 2-Dibromo-l, 1-dichloroethane

Dibromodifluoromethane

1, 2-Dibromoethane (Ethylene dibromide)

Dibromomethane (Methylene bromide) ■-

1, 2-Dibromo-l, 1, 2, 2-tetrafluoroethane—

Dichlorobutadiene "

1,4-Dichlorobutene

*Dichlorodifluoromethane ■

*1, 2-Dichloroethane (Ethylene dichloride)

*Dichloromethane (Methylene chloride)

Dichloropentanes, mixed isomers

*1, 2-Dichloropropane (Propylene dichloride)

2,3-Dichloropropane

*Dichlorotetrafluoroethane

1, 1-Dif luoroethane

Difluorotetrachloroethane

Diiodomethane (Methylene iodide)

Hexachloroethane

Hexafluoro-2-propane

Hexafluoropropylene, monomer—'-

Hexamethylene dibronn.de "

Iodoethane (Ethyl iodide), tech

Iodoform (Triiodomethane)

*Iodomethane (Methyl iodide)

1-Iodoperfluorohexane

*Lauryl chlorides ""'

Octafluorocyclobutane """"""

1, 1,2,2-Tetrabromoethane (Acetylene tetrabromide) —

Tetrabromomethane " ""

1,1,2,2-Tetrachloroethane (Acetylene tetrachloride) -

*Tetrachloroethylene (Perchloroethylene)

Tetrafluoroethylene, monomer

Tetrafluoroethylene, polymer

Tetrafluoromethane

Xt i, l-Trichloroethane (Methyl chloroform)

l' 1, 2-Trichloroethane (Vinyl trichloride)

*Trichloroethylene " ""'

*Trichlorofluoromethane

1,2,3-Trichloropropane

1, 2, 3-Triehloropropene

Trichlorotrif luoroethane

*Vinyl chloride, monomer ( Chloroethylene)

Vinyl fluoride "~ T"

Vinylidene chloride, monomer ( 1, 1-Dichloroethylene) -

VInylidene fluoride- All other-

2-Heptanone (Methyl amyl ketone)

Hexadecane

n-Hexadecenyl succinic anhydride

n-Hexadecyl disulfide

Hexadecyl nitrile

Hexamethylenediammonium adipate

1,6-Hexanediol

Hexanediol bischloroformate

2, 5-Hexanedione ( Acetonylacetone)

1, 2, 6-Hexanetriol

1,2,6-Hexanetriol octoate

Hexanoic acid (Caproic acid)

2-[ 2- ( Hexyloxy) ethoxy] ethanol

Hydracrylonitrile (Ethylene cyanohydrin) -

Hydrazine and salts

2-Hydrazinoethanol

Hydroxyethyl carbamate

Hydroxyethyl methacrylate

Manufacturers' identification codes (according to list in table 22)

DOW.

DOW, SHC.

ACG, MMM.

HK, MM.

ACG, DUP, PAS.

DOW.

DOW.

DOW, ETD, HCH, MCH.

DOW.

DUP.

DUP.

DUP.

ACG DUP, KAI, PAS, UCC.

m^, DA, DOW, DUP, JCC, MON, OMC, PPG, TNA, UCC, WYN.

ACS, DA, DOW, DUP, FRO, SF.

PAS.

DOW, JCC, UCC.

DOW, UCC, WYN.

ACG, DUP, PAS, UCC.

ACG, DUP.

DUP.

NTB, SDW.

NES.

DUP.

DUP.

CLB.

EK, FMT.

NTB.

CLB, EK, FMT, RSA.

x.

BC, HK, SDH.

DUP.

DOW.

DOW.

DUP, PPG.

DA, DOW, DUP, FRO) HK, PPG, SF, TTX.

DUP.

DUP.

DUP.

DOW, PPG, TNA.

DOW, UCC.

DOW, DUP, HK, PPG, TTX.

ACG, DUP, KAI, PAS, UCC.

DOW, SHC.

DOW.

ACS^ AME^ BFG' CUCJ DA, DOW, GNT, GYR, MNO, MON, TNA,

UCC. x.

DOW, TMC, TNA. x.

DUP, EK, KPS, KPT. UCC. HMY. HMY. PAS. FOR.

CEL, MON. CEL. PPG.

ACI, RBC. UCC. ARC. FB. UCC. UCC.

FMT, OMC. NOR. JCC. AAC, JCC.

MISCELLANEOUS CHEMICALS

183

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1 965- -Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

2-( Hydroxymethyl) -2-methyl-l, 3-propanediol ( Trimethylol

ethane) . 2-( Hydroxymethyl) -2-nitro-l, 3-propanediol ( Tris( hydroxy- methyl) nitromethane) . N-( Hydroxymethyl) octadecanamide ( N-Hydroxyroethylsteara- mide) .

*4-Hydroxy-4-methyl-2-pentanone (Diaoetone alcohol)

Hydroxyneopentyl hydroxypivalate

Hydroxypropyl methacrylate

Iodoaoetio acid, sodium salt

Iodomethylmercury iodide

Isethionic acid (2-Hydroxyethanesulfonic acid)

Isoascorbic acid

*Isoascorbic acid, sodium salt

Isobutoxyethanol

l-Isobutoxy-2-propanol (Propylene glycol isobutyl ether) -

Isobutyl acrylate

Isobutyl isobutyrate

Isobutyraldehyde

Isobutyric acid and anhydride

Isobutyronitrile

Isodecaldehyde, mixed isomers

Isodecanoic acid, mixed isomers

Isodecyl acrylate •

Iso-octanoic acid

Isopentyl ether (Isoamyl ether)

Isoprenylaluminum

Isopropanolamines:

l-Amino-2-propanol ( Monoisopropanolamine)

1, l/-Iminodi-2-propanol ( Diisopropanolamine)

1, 1', 1" -Nitrilotri-2-propanol ( Triisopropanolamine)

*Isopropyl acetate

2-Isopropylaminoethanol

Isopropyl chloroformate

*Isopropyl ether

Isovaleric anhydride

Isovalerone (Diisobutyl ketone)

Itaconic acid (Methylenesuecinic acid)

Lactic acid, K)0#:

Edible

Technical

Lactic acid salts:

Aluminum lactate

Aluminum sodium chlorohydroxylactate

Aluminum sodium lactate

Calcium lactate

Sodium lactate

Lactic anhydride

Lactide (3,6-Dimethyl-2,5-p-dioxanedione)

Lactonitrile

Laurie acid salts

Lauronitrile

Lauroyl bromide

*Lauroyl chloride

*Lauroyl peroxide

Lauryl lactate

Levulinic acid

*Linoleic acid salts:

*Calcium linoleate

»Cobalt linoleate

Copper linoleate

Iron linoleate

Lead linoleate-

Lead manganese linoleate

Manganese linoleate

Manufacturers' identification codes ( according to list in table 22)

CEL, SHC, UCC.

EKT.

JCC.

BSA.

NTB.

G.

MRK, PFZ.

BAX, MRK, PFZ.

UCC.

DOW.

DBC.

EKX.

EKX, UCC.

EKT, UCC.

ESX.

UCC.

UCC.

UCC.

UCC.

GIV.

TSA.

DOW, UCC.

DOW, UCC.

DOW, UCC.

EKT, ENJ, HPC, UCC.

PAS.

CTN, PPG.

ENJ, SHC, UCC.

ICO.

EKT, UCC.

PFZ.

CLN, DUP, MON.

CLN, MON.

TNC.

REH.

REH.

SHF.

PFN.

FB.

CLN.

MON.

BCN, CCW, SYP.

FOR.

DOW.

CAD, G, ONX, TBK, THC, UPR, WTL

AZT, CAD, UPR, WTL.

VND.

CRZ.

CCA, LEF, SHP, SRR.

HSH, SHP, SRR.

WTC.

HSH.

SHP, SRR.

SDH, SRR.

SHP, SRR.

184

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B-— Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1965 — Continued

MISCELLANEOUS CHEMICALS, ACYCLIC--Continued

^Lubricating oil additives:

Chloronaphtha xanthate

Chlorosulfurized hydrocarbon

Chlorosulfurized lard oil--

Chlorosulfurized sperm oil

Oxidized hydrocarbons

*Phosphorodithioates ( Dithiophosphates) :

2-Pinene phosphorodithioate

Zinc di( butylhexyl) phosphorodithioate

Zinc dihexyl phosphorodithioate

Zinc diisopropylhexyl phosphorodithioate

Zinc diisopropyl phosphorodithioate

All other

Sulfurized butenes

*Sulfurized lard oil

Sulfurized methyl oleate

*Sulfurized sperm oil

All other

Magnesium methylate

Maleic acid

Maleic acid, tribasic lead salt

*Maleic anhydride

Malic acid

Malonic acid

Malonic acid salts

Malononitrile

Maltol (Hydroxy methyl pyrone)

Mannitol

*Mercaptoacetic acid ( Thioglycolic acid)

*Mercaptoacetie acid (Thioglycolic acid) derivatives: *2-Aminoethyl mercaptoacetate (Monoethanolamine thio- glycolate) .

*.jr-jonium mercaptoacetate (Ammonium thioglycolate)

Antimony mercaptoacetate

Calcium mercaptoacetate

Dibutyltin bis( iso-octylmercaptoacetate)

Dibutyltin mercaptoacetate

*Iso-octyl mercaptoacetate

Potassium mercaptoacetate

Sodium mercaptoacetate

3-Mercapto-l, 2-propanediol ( Thioglycerol)

|3-Mercaptopropionic acid

Mercaptosuccinic acid (Thiomalic acid)

Metal soaps of oxidized hydrocarbons

Methacrylamide

Methacrylate copolymers

Methacrylate monomers, above methyl

Methacrylic acid ;

Methacrylic acid esters, other

MethalLylidene diacetate

Methanesulfanol

Methanesulfonic acid

*2-Methoxyethanol ( Ethylene glycol monomethyl ether)

*2-(2-Methoxyethoxy)ethanol (Diethylene glycol monomethyl

ether) . *2-[2-(2-Methoxyethoxy)ethoxy]ethanol (Triethylene glycol monomethyl ether) . 2-(2-Methoxyethoxy)ethyl 2-methoxyethyl ether (Triethylene glycol dimethyl ether) .

2-Methoxyethyl acetate

4-Methoxy-4-methyl-2-pentanol

4-Methoxy-4-methyl-2-pentanone

Methoxypolyethylene glycol

l-Methoxy-2-propanol

3-Methoxypropanol

3-(3-Methoxypropoxy)propanol (Dipropylene glycol methyl

ether) . 3-[3-(3-Methoxypropoxy)propoxy] propanol (Tripropylene

glycol methyl ether) . 3-Methoxypropylamine

Manufacturers' identification codes (according to list in table 22)

MON. EN J. CCW.

ccw.

ALX.

TX.

0R0.

MON.

TX.

SIN.

ENJ,

LUB.

CCW,

SIN.

CCW,

CCW,

MKT,

NAC,

NTL.

HN,

EX,

KF.

LUB, MON, SIN.

GOC, NLC, SIN.

LUB, QCP, SIN, SOI, x.

ENJ, HK, LUB, MON, 0R0, SIN, SOI, x.

SFA.

PFN.

KPS, MON, NAC, PCC, PTT, RCI. NAC, PFN.

EK, GIV.

KF.

APD.

EVN,

HAB,

RET.

EVN,

HAB,

RET.

EVN,

HAB,

RET,

TNI.

CCA.

EVN.

X.

CCA.

CCW,

EVN,

HAB.

EVN.

EVN.

EVN.

EVN.

EVN.

ALX.

RH,

X.

X.

DUP.

DUP,

RH.

SAR.

UCC.

PAS.

PAS.

DOW,

JCC,

OMC,

UCC.

DOW,

JCC,

OMC,

UCC.

DOW,

CMC,

UCC.

ASL.

UCC.

SHC.

SHC.

UCC.

DOW,

SHC.

UCC.

DOW,

UCC.

EXT, JCC.

MISCELLANEOUS CHEMICALS

185

TABLE 21B.- -Miscellaneous chemicals for which U.S. production or sales were reported identified by

manufacturer, 1 965- -Continued

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

Methoxytriethyleneglycol acetate

*Methyl acetate

Methyl acetoacetate

Methyl acrylate, monomer

Methylal ( Dimethoxymethane)

Methylaluminum sesquichloride

2-Methylaminoethanol ( N-Methylethanolamine)

Methyl borate

3-Methyl-2-butenoic acid

2-Methyl-l-buten-3-yne ( Isopropenylacetylene)

Methyl butynoxyethanol

Methyl carbamate

Methyl chloroformate

Methyl cyanoacetate

Methyl 2-cyanoacrylate

Methyl dichloroacetate

Methyl disulfide (Dimethyl disulfide)

N, N'-Methylenebisacrylamide

N,N '-Methylenebisoctadecanand.de ■

*Metnyl ether (Dimethyl ether)

Methyl formate

N-Methylglucamine

Methylglycerol

5-Methyl-2-hexanone (Methyl isoamyl ketone)

2,2'-(Methylimino)diethanol (Methyl diethanolamine) -

Methyl isocyanate

2-Methyllactie acid (a-Hydroxyisobutyric acid)

2-Methyllactonitrile (Acetone cyanohydrin)

Methylmagnesium bromide

Methylmagnesium chloride

Methyl methacrylate, monomer

2-Methyl-2-nitro-l,3-propanediol

2-Methyl-2-nitro-l-propanol

2-Methyl-2,4-pentanediol (Hexylene glycol)

*4-Methyl-2-pentanone (Methyl isobutyl ketone)

4-Methyl-2-pentanone oxime ( Methylisobutyl ketoxime)

4-Methyl-3-penten-2-one (Mesityl oxide)

4-Methyl-2-pentyl acetate

Methylpolyethanolamine

2-Methyl-2-propyl- 1, 3-propanediol

Methylpseudoionone

Methyl sulfate (Dimethyl sulfate)

Methyl sulfide (Dimethyl sulfide)

Methyl sulfone

Methyl sulfoxide (Dimethyl sulfoxide)

N-Methyltaurine

N-Methyltaurine, sodium salt

N-Methylurea

2-Methylvaleraldehyde ( 2-Methylpentaldehyde)

2-Methylvaleric acid

Methyl vinyl acetate

Methyl vinyl ether

Mucochloric acid (2,3-Diehloro-3-formylacrylie acid)

Myrcene (7-Methyl-3-methylene-l, 6-octadiene)

Myristoyl chloride

Myristyl lactate

2-Nitro-l-butanol

Nitroethane

Nitromethane

1-Nitropropane

2-Nitropropane

1, 9-Nonanediol

Nonanoic acid (Pelargonic acid)

Nonanoic acids, cobalt salts

Nonenylsuceinic anhydride

Nylon, heteropolyamide polymer

*Nylon, 6 and 6/6 polymer for fiber

Nylon, sebacamide polymer

1-Octadecene

RBC.

BOH, EK, MON, UCC.

EKT, UCC.

CEL, DBC, RH.

CEL.

TNA.

UCC.

MHI, SFA.

UCC.

CUC.

cue.

BKL, MP.

CTN.

KF.

EKT.

KF, PD.

CRZ.

ACY.

ARC.

COM, DUP, UCC.

DUP.

DUP.

APD.

EKT, UCC.

UCC.

CTN, OTC.

EK.

ACY, x, x.

ARA.

ARA, x.

ACY, DUP, RH.

COM.

COM.

CEL, EKT, SHC, UCC.

EKT, ENJ, SHC, UCC.

ALB.

SHC.

PUB, SHC, UCC.

G.

ABB, DUP, ICO.

GIV.

DUP.

CRZ, PAS.

CRZ.

CRZ.

G.

TNA.

LIL.

UCC.

UCC.

UCC.

G, UCC.

EKT.

IFF.

BC.

VND.

COM.

COM.

COM.

COM.

COM.

ADM.

EMR.

MID.

HMY.

DUP.

DUP, MON, NAC.

DUP.

HMY.

186

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B. — Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1 965- -Continued

Manufacturers' identification code ( according to list in table 22)

MISCELLANEOUS CHEMICALS, AC YCLIC-- Continued

Octadecyl isocyanate

n-Octadecyl mereaptan

Octadecyl mercaptopropionate

1-Octanethiol (n-Octyl mereaptan)

Octanoic acid (Caprylic acid) salts:

Aluminum octanoate

Barium octanoate

Cadmium octanoate

Stannous octanoate

Zinc octanoate

2-0etanone (Hexyl methyl ketone)

3-0ctanone (Amyl ethyl ketone)

Octanoyl chloride

l-Octene

l(and 2)-0ctene

2-0ctene

Octenylsuccinic anhydride

Octyltins

Oleamide (Oetadecene amide)

Oleamides, mixed

*01eie acid salts:

Aluminum oleate

Ammonium oleate -

Barium zinc oleate

*Copper oleate

Lead oleate

Stannous oleate

Oleonitrile

Oleoyl chloride

Oleoylhydroxamic acid

Oleylpalmitamide

*0xalic acid

*Oxalic acid salts:

Ammonium oxalate

Calcium oxalate

Ferric ammonium oxalate

Ferric oxalate

Ferric sodium oxalate

Ferrous oxalate

Potassium binoxalate

Potassium oxalate

Sodium binoxalate

Sodium oxalate

Oxidized hydrocarbon mixtures, other than lubricating oil additives. *Palmitic acid salts:

Aluminum palmitate

Zinc palmitate

*Pa1nritoyl chloride

Paraformaldehyde

Paraldehyde (Paracetaldehyde)

*Pentaerythritol

Pentaerythritol caprylate

Pentaerythritol pelargonate

*Pentaerythritol tetranitrate

2, 4-Pentanedione ( Acetylacetone)

2,4-Pentanedione, metallic complexes:

Ferric

Other

2-Pentanone (Methyl propyl ketone)

3-Pentanone (Diethyl ketone)

Pentyl nitrate (Amyl nitrate)

Peroxyacetic acid

^Phosgene (Carbonyl chloride)

•^Phosphorus acid esters, not elsewhere specified (See also Plasticizers, Surface-active agents, Pesticides, Flo- tation reagents, and Lubricating oil additives) :

Bis(2-ethylhexyl) hydrogen phosphate-

Bis(2-ethylhexyl) hydrogen phosphite

CWN,

ICO

MOB.

HMY.

EVN.

PAS.

NOP.

CCW.

CCW.

CCW.

BKC.

EKT,

TBK,

WTH.

AHA.

HK,

UPR.

ADM.

WTH.

mix.

HMY.

x.

ADM,

ARC,

FIN, HUM.

FIN.

WTC.

BCN,

MCI.

WTC.

MLD,

SHP,

WTC.

SHP.

CCW,

X.

ARC,

FOR.

DEP,

G, TBK.

WAY.

FIN.

ACG,

MAL,

PFZ, SF.

ACG,

BKC,

PFZ.

SF.

PFZ.

PFZ.

PFZ.

BKL.

BKC.

ACG,

BKC,

PFZ.

SF.

ACG,

BKC,

MAL, SF.

ALX.

ACY,

NOP,

WTC.

ACY,

NOP,

WTC.

G, HAL, OPC, THK.

CEL,

HN,

3PC.

UCC.

CEL,

COM,

DCI, HN, HPC, RCI, TRJ.

DEW.

DRW.

DUP,

HPC,

TRJ.

UCC.

MAK.

MAK.

UCC.

DUP,

HEX.

TNA.

FMB.

CTN,

DUP,

MOB, NAC, CMC, OTC, PPG, UCC,

UPJ, VDM.

MISCELLANEOUS CHEMICALS

187

TABLE 21B. --Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1 965- -Continued

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

^Phosphorus acid esters, not elsewhere specified (See also Plastieizers, Surface-active agents, Pesticides, Flo- tation reagents, and Lubricating oil additives) — Continued

Butyl phosphates (mono- and di-)

Chloropropyl phosphorothioate

Dibutyl butylphosphonate

Dibutyl hydrogen phosphite

Didodecyl hydrogen phosphate

Diethyl ethylphosphonate

Diethyl hydrogen phosphite

Diisopropyl hydrogen phosphite

Dimethyl hydrogen phosphite

Dimethyl methylphosphonate

Dioctyl hydrogen phosphate

Dioctyl hydrogen phosphite

Dipentaerythritol phosphite

. 2-Ethylhexyl phosphates (mono- and di-)

Ethyl phosphates (mono- and di-)

Iso-octyl hydrogen phosphate

Isopentyl octyl hydrogen phosphate

Methyl dihydrogen phosphate

Methyl phosphates (mono- and di-)

Pentyl phosphates (Mono- and diamyl phosphates)

*Tributyl phosphate

Tributyl phosphite

Tridecyl phosphite

Triethyl phosphite

Triiso-octyl phosphite

Triisopropyl phosphite

Trimethyl phosphate

Trimethyl phosphite

Tris(2-chloroethyl) phosphite

Tris(2,3-dibromopropyl) phosphate

Tris(2-ethylhexyl) phosphite

Tris( octadecyl) phosphite

All other

Pine oil, synthetic

Polyaerylamide

Polyacrylic acid

*Polyacrylic acid salts:

Ammonium polyacrylate

Sodium polyacrylate

All other

Polyacrylonitrile

Polybutylene glycol

Polychlorinated propyl ether

Polyethoxyethylglycerol

Polyethoxyethylsorbitol

■^Polyethylene glycol

Polyethylene glycol dimethacrylate

Polyethylene imine

Polyethylene polysulfide

Polyglycerol " "_

Polyglycols, ethylene glycol and glycol ethers, mixtures-

Polymethacrylic acid esters

*Polypropoxy ethers:

*Glycerol tri( polyoxypropylene) ether

Polypropoxysorbitol

Other

^Polypropylene glycol

Polytetramethylene glycol ether

Propanone peroxide (Acetone peroxide)

|3-Propiolactone

Propionaldehyde

^Propionic acid

Propionic acid salts:

*Calcium propionate

*Sodium propionate

Zinc propionate

Manufacturers' identification codes (according to list in table 22)

SF, SM.

TNA.

SM.

SM.

DUP.

SM.

SM.

SM.

SM.

SM.

DUP, SF.

HK.

HK.

SF.

SF, SM.

SM.

SM.

HK.

SF, SM.

SF.

COM, FMP, SF, TXT.

SM.

HK.

SM.

SM.

SM.

TNA.

SM.

SM.

MCH.

HK.

SM.

DUP, MON, SF, SM, x.

CBY.

ACY.

BFG, NOP, RH.

BFG.

ALC, BFG, JOR, RH.

BFG.

DUP.

NIC.

JCC.

GLY.

APD, GLY, TCH.

ACN, DOW, DUP, G, JCC, CMC, UCC, WYN.

SAR.

cm.

BFG. DRW. DOW. DUP.

JCC, OMC, UCC, WYN.

APD.

ACS, APD, WYN.

DOW, JCC, NLC, OMC, UCC, WYN.

x.

SDH.

CEL.

EKX, UCC.

CEL, COM, EKT, UCC.

CEL, HFT, PFZ, UCC, WSN. CEL, PFZ, UCC, WSN. BKC.

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B.— Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer , 1 965— Continued

MISCELLANEOUS CHMICALS, ACYCLIC— Continued

Propionic anhydride

Propionyl chloride

Propionyl peroxide

Propyl acetate

Propylene carbonate

^Propylene glycol ( 1,2-Propanediol)

Propylene glycol, mixed ethers

^Propylene oxide

n-Propyl isocyanate

Propyl nitrate

Propyne (Methylacetylene)

Pseudoionone

Pyruvaldehyde

Quaternary ammonium compounds (butyl and lower)

Rare sugars

Ricinolamide

Ricinoleic acid salts:

Calcium ricinoleate

Lithium ricinoleate

*Sarcosine ( N-Methylaminoacetic acid)

*Sarcosine, sodium salt

Sebacic acid

Semicarbazide base and hydrochloride

^Sequestering agents:

(Diethylenetrinitrilo)pentaacetic acid

(Diethylenetrinitrilo)pentaacetic acid, monosodium hydrogen ferric salt.

*(Diethylenetrinitrilo)pentaaeetie acid, sodium salt

N, N-Dihydroxyethylglycine, sodium salt

*( Ethylenedinitrilo) tetraacetic acid ( Ethylenediamine- tetraacetic acid) .

( Ethylenedinitrilo) tetraacetic acid, diammonium salt

( Ethylenedinitrilo) tetraacetic acid, dipotassium salt

( Ethylenedinitrilo) tetraacetic acid, disodium salt

( Ethylenedinitrilo) tetraacetic acid, disodium calcium

salt. ( Ethylenedinitrilo) tetraacetic acid, disodium copper

salt. ( Ethylenedinitrilo) tetraacetic acid, disodium zinc salt, diiydrate.

( Ethylenedinitrilo) tetraacetic acid, manganese salt

*( Ethylenedinitrilo) tetraacetic acid, monohydrogen tri- sodium salt. ( Ethylenedinitrilo) tetraacetic acid, monosodium iron

salt. ( Ethylenedinitrilo) tetraacetic acid, tetrapotassium salt

*( Ethylenedinitrilo) tetraacetic acid, tetrasodium salt

Hexahydroxyheptanoic acid, s6dium salt

(N-Hydroxyethylethylenedinitrilo)triacetic acid

(N-Hydroxyethylethylenedinitrilo) triacetic acid, iron sodium salt. *(N-Hydroxyethylethylenedinitrilo) triacetic acid, tri- sodium salt. ( N-Hydroxyethylethylenedinitrilo) triacetic acid, other salts.

Nitrilotriacetic acid, trisodium salt

Sodium salt of sugar acids

Silicones

Sodium ethoxide

Sodium ethyl oxalacetate *

Sodium formaldehydebisulfite

*Sodium formaldehydesulfoxylate

*Sodium methoxide (Sodium methylate)

Sodium polypectate

Sodium sorbitol borate

Sorbic acid (2,4-Hexadienoic acid), and potassium and sodium salts.

^Sorbitol

Soya nitrile

*Stearamide ( Octadecanamide)

Manufacturers' identification codes (according to list in table 22)

CEL, ABB, WTL. CEL, DOW, APD, DOW. CEL, CWN, TNA.

cue.

GIV. UCC. EDC, PFN. TKL.

BAC. BAC. ATL, GGY.

WTH, FMT.

HMP. GGY.

CWL, CWL,

DOW,

DOW. EK. DOW, DOW,

GGY.

GGY. GGY,

GGY,

GGY. CRT, PCW. GGY. DOW.

EKT, UCC. EK, TBK.

EKT, PUB, UCC.

JCC.

CEL, DOW, DUP, JCC, OMC, UCC, WYN.

DOW, JCC, OMC, UCC, WYN. OTC.

EK, PAS, RSA.

G, HMP, VPC.

DOW, GGY, HMP, RPC, TCC. DOW, HMP, MOA. GGY, HMP, MOA.

EK, GGY, HMP, RPC. GGY.

HMP, NOP. HMP, RPC.

CWL, DOW, GGY, HMP, HRT, IBI, RPC, TCC.

CRT, CWL, DOW, HMP, IBI, MOA, RPC, TCC.

HMP.

GGY, HMP.

PFN.

DCC, ORO, UCS.

FMP.

FMP.

EK, IDC.

HSH, NOP, RH, ROY.

BFR, DA, DUP, HSH, KF, OMC,

RBC,

SFA.

SKG.

APD.

UCC.

APD, BRD, MRK, PFZ.

CGI.

ADM, ARC, DUP, FIN, HUM.

MISCELLANEOUS CHEMICALS

189

TABLE 21B. —Miscellaneous chemicals for which U.S. production or sales were reported, identified by

manufacturer, 1 965- -Continued

Manufacturers' identification codes (according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC— Continued

♦Stearic acid salts: ♦Aluminum stearates:

♦Aluminum distearate

♦Aluminum monostearate

♦Aluminum tristearate

Ammonium stearate

Barium stearate

Cadmium stearate

♦Calcium stearate

Cobalt stearate

Copper stearate

Ferric and ferrous stearates

♦Lead stearate

Lead stearate, dibasic

♦Lithium stearate

♦Magnesium stearate

Ma nganese stearate

Nickel stearate

♦Zinc stearate

All other

Stearonitrile (Octadecanenitrile)

Stearoyl chloride

Stearyl-2- lactic acid

Succinic acid

Succinic anhydride

Succinimide

Succinonitrile

Succinyl peroxide

Sucrose octaacetate

♦Tallow umide, hydrogenated

Tallow fatty acyl chloride

Tallow litrile

Tallow nitrile, hydrogenated

Tartaric acid salts:

Antimony potassium tartrate

Potassium bitartrate

Potassium sodium tartrate

Sodium bitartrate

All other

Tetrabutyltin

Tetrabutyl titanate

n-Tetradecane

1, 1,3,3-Tetraethoxypropane

Tetraethylene glycol

Tetraethylene glycol dimethacrylate

♦Tetraethyllead

Tetrahydropseudoionone

Tetrahydroxysuccinic acid ( Dioxytartaric acid)

Tetrakis( hydroxymethyl) phosphonium chloride

N, N, N', N'-Tetrakis( 2-hydroxypropyl) ethylenediamine-

1, 1,3,3-Tetramethoxypropane-

♦Tetramethyl( and ethyl) lead

Tetramethylguanidine

♦Tetramethyllead

Tetramethylurea

Tetraoctyl orthosilicate

Tetrapropenylsuccinic acid

Thioacetamide

Thioacetic acid

2,2'-Thiodiethanol ( Thiodiethylene glycol)

3,3'-Thiodipropionates, other

3,3'-Thiodipropionic acid

Thiodipropionic acid, cobalt salt

3,3'-Thiodipropionitrile

Thiolactic acid

Thiosemicarbazide

Titanic acid esters

Tributylphosphine

ACY, JTC, LEF, MAL, NOC, NOP, PHP, SYP, WTC.

LEF, MAL, NOC, NOP, SYP, WTC.

ACY, LEF, MAL, NOC, NOP, PBP, SYP.

LEF, NOP, WTC.

LEF, NOC, NOP, PHP, SYP, WTC.

NOP, PHP, SYP, WTC.

ACY, HNX, JTC, LEF, MAL, NOC, NOP, PHP, SYP, WTC.

WTC.

NOC.

MCI, WTC.

HSH, LEF, NOP, NTL, PRP, WTC.

NOC, NOP, NTL.

FTE, LEF, NOP, PRP, SYP, WTC.

ACY, JTC, LEF, MAL, NOC, NOP, PRP, SYP, WTC.

NOC.

WTC.

ACY, BCN, CCA, HNX, JTC, LEF, MAL, NOC, NOP, PRP, SYP,

TNC, WTC. APD. FOR. G, TBK.

RKC, NAC.

NAC.

NAC.

NAC, RSA.

WTL.

PD, UCC.

ADM, ARC,

CGL, CRT, HUM.

G.

FOR.

FOR.

PF2.

ATC.

PFZ.

PFZ.

BKC.

X.

DUP.

HMY.

KF.

DOW, UCC.

SAR.

DUP, HCH,

TNA.

GIV.

ACY.

HK.

WYN.

KF.

DUP, TNA.

ACY.

DUP, HCH,

NLC, TNA.

OTC.

MON.

X.

BKC, EK.

EVN.

UCC.

ttAB.

CCW, EVN.

CCW.

ACY, HAB.

EVN.

ACY, FMT.

DUP.

CCW.

190

SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 21B.-

- Miscellaneous chemicals for which U.S. production or sales were reported, identified by manufacturer , 1965 — Continued

Manufacturers' identification codes ( according to list in table 22)

MISCELLANEOUS CHEMICALS, ACYCLIC--Continued

Tributyltin chloride

Trichloroacetic acid

Trichloroacetyl chloride

(Trichloromethyl)phosphonic acid

Trichloropropylsilane

Trichlorovinylsilane

Tridecyl mercaptan

Triethylaluminum

*Triethylene glycol

Triethylene glycol dimethacrylate

Triethyl orthoacetate

Triethyl orthofonnate

Triethyl orthopropionate

Trifluoroaeetic anhydride

Tri(hexylene glycol) biborate

Triisobutylaluminum

Triisodecyl orthofonnate »

Trimethoxyboroxine

T rime thy laluminum

2, 6, 8-Trimethyl-4-nonanone

Trimethyl orthoformate

2,2,4-Trimethyl-l,3-pentanediol

2,2,4-Trimethyl-l,3-pentanediol monoisobutyrate

Tri-n-octyl phosphine oxide

Tri-n-propy laluminum

Tripropylene glycol

*Urea in compounds or mixtures, 100$ basis:

*In feed compounds

*In liquid fertilizer

*In solid fertilizer

In plastics

All other

Urea peroxide

Urea urethane copolymer

Valeraldehyde

Valeric acid

*Vinyl acetate, monomer

*Zine formaldenydesulfoxylate

DOW.

EK.

DCC.

DCC.

DCC.

PAS.

TNA,

ACN,

SAH.

EK,

KF.

KF.

EK.

USB.

TNA,

KF.

SFA.

TNA.

UCC.

KF.

EKX.

EKX.

EK.

TNA,

DOW,

CAU, DOW, G, HCH, JCC, OMC, UCC. KF.

TSA. UCC.

ACN, DUP, GCC, JDC, MON, MSC, SHC, SOH.

ACN, CFA, DUP, ESC, FCA, GCC, HKY, HPC, KET, MON,

NIT, SHC, SNI, SOH, SPN, x.

ACN, DUP, GCC, HPC, JDC, MON, MSC, SHC, SNO, SOH,

DUP, MON.

ACN, DUP, HPC, MON, SNO, SOH. FMB. DUP. UCC. UCC.

BOR, CEL, CUC, DUP, MON, NSC, UCC.

NOP, RH, ROY.

MSC, SPN.

DIRECTORY OF MANUFACTURERS

Directory of Manufacturers

The Directory of Manufacturers lists the companies that report their production of synthetic organic chemicals to the U.S. Tariff Commission. The name of each manufacturer is preceded by an alphabetical identification symbol. These identification symbols consist of not more than three capital letters, and usually bear a relation to the company name.

For 1965, the Directory of Manufacturers lists approximately 800 primary manufacturers (see table 22). Some of the companies that report production of synthetic organic chemicals do not sell the materials, but consume their entire output in further manufacturing.

The Directory of Manufacturers lists the reporting companies in two ways: Section 1 lists them in alphabetical order by identification symbols; section 2 lists the reporting companies in alphabetical order by company name, and gives the corresponding identification symbol and the company address. Company divisions are usually listed under the parent company's name.

TABLE 22.-- Synthetic organic chemicals; Directory of manufacturers , 1965

SECTION 1. ALPHABETICAL DIRECTORY BY CODE [Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission for 1965 are listed below in the order of their identification codes as used in tables m pt. III. Sec. 2 of this table lists these manufacturers alphabetically and gives their office addresses J

Name of company

AAC AAE AAI AAP ABB ABS

ACB ACC ACG ACI ACN ACO ACP ACR ACS ACT ACU

ACY ADM AKS ALB ALC ALD ALF ALL ALO ALT

ALX AMB AMC AME AML AMD AMP AMR AMS

ANM APC APD APR APT APV APX ARA ARC

Alcolac Chemical Corp.

American Aniline & Extract Co., Inc.

American Alkyd Industries

American Aniline Products, Inc.

Abbott Laboratories

American Brake Shoe Co., American Brakeblok

Div. Allied Chemical Corp., Barrett Div. Amoco Chemicals Corp.

Allied Chemical Corp., General Chemical Div. Aceto Industrial Chemical Corp. Allied Chemical Corp., Nitrogen Div. Acralite Co., Inc.

Allied Chemical Corp., Plastics Div. Acme Resin Corp.

Allied Chemical Corp., Solvay Process Div. Arthur C. Trask Co. Allied Chemical Corp., Union Texas Petroleum

Div. American Cyanamid Co. Archer-Daniels-Midland Co. Arkansas Co., Inc. Ames Laboratories, Inc. Alco Chemical Corp. Aldrich Chemical Co., Inc.

Allied Chemical Corp., Fibers Div.

Alliance Color & Chemical Co.

Alamo Industries, Inc.

Crompton & Knowles Corp., Althouse Chemical Co. Div.

Alox Corp.

American Bio-Synthetics Corp.

Amchem Products, Inc.

American Chemical Corp.

Amalgamated Chemical Corp.

American Oil Co. (Texas)

American Potash Sc Chemical Corp.

Pacific Resins & Chemical Co.

Martin-Marietta Corp. , Ridgway Color & Chemical Div.

Ancon Chemical Co.

Appleton Coated Paper Co.

Atlas Chemical Industries, Inc., Chemicals Div,

Atlas Processing Co.

American Petrochemical Corp.

Armstrong Paint & Varnish Works, Inc.

Apex Chemical Co., Inc.

Syntex Corp., Arapahoe Chemicals Div.

Armour Industrial Chemical Co.

Name of company

ARD

ARG

ARK

ARL

ARM

ARN

ARP

ARZ

ASH

ASL

AST

ASY

ATC

ATL

ATP

ATR

ATU

AUG

AV

AVS

AZT

BAC

BAL

BAR

BAT

BAX

BC

BCM

BCN

BDO

BEN

BFG

BFR

BJL

BKC

BKL

BKM

BKS

BKT

BL

BLA

BLN

BLS

BME

BOR

BOY

BPC

Ardmore Chemical Co.

Argus Chemical Corp.

Armstrong Cork Co.

Arol Chemical Products Co.

Armour Agricultural Chemical Co.

Arenol Chemical Corp.

Armour Pharmaceutical Co.

Arizona Chemical Co.

Ashland Oil & Refining Co.

Ansul Chemical Co.

Astra Pharmaceutical Products, Inc.

American Synthetic Rubber Corp.

American Tartars Corp.

Atlantic Chemical Corp.

Atco Chemical- Industrial Products, Inc.

Atlantic Refining Co.

Atlantic Tubing & Rubber Co.

Augusta Chemical Co.

FMC Corp., American Viscose Div.

Avisun Corp.

Aztec Chemicals, Inc.

Baker Castor Oil Co.

Baltimore Paint & Chemical Corp.

American Rubber & Chemical Co.

Crompton & Knowles Corp., Bates Div.

Baxter Laboratories, Inc.

Barlow Chemical Corp.

Belding Chemical Industries

Lehn & Fink Products Corp., Beacon Div.

Benzenoid Organics, Inc.

Bennett ' s

B. F. Goodrich Co., B. F. Goodrich Chemical Co. Div.

Branehflower Co.

Burdick & Jackson Laboratories, Inc.

J. T. Baker Chemical Co.

Millmaster Onyx Corp., Millmaster Chemical Div.,

Berkeley Chemical Dept. Buckman Laboratories, Inc.

Tenneco Chemicals, Inc. , Berkshire Color Div. J. T. Baker Chemical Co., Taylor Div. Belle Chemical Co., Inc. Winn-Dixie Stores, Inc. Brooklyn Color Works, Inc. Beech-Nut Life Savers, Inc. Bendix Corp., Marshall- Eclipse Div. Borden Co., Borden Chemical Co. Div. Walter N. Boysen Co. Benzol Products Co.

192 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22..-- Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued

Code

Name of company

Code

Name of company

BPL

Brand Plastics Co.

COR

Commonwealth Oil Refining Co., Inc.

BRD

Baird Chemical Industries, Inc.

CP

Colgate-Palmolive Co.

BRS

Bristol-Meyers Co., Bristol Laboratories Div.

CPC

Childs Pulp Colors, Inc.

BRU

M. A. Bruder & Sons, Inc.

CPD

Chemical Products Corp.

BRY

Bryant Chemical Corp.

CPV

■ Cook Paint & Varnish Co.

BSC

Burkart-Schier Chemical Co.

CPY

Copolymer Rubber & Chemical Corp.

BUC

Blackman-Uhler Chemical Co.

CRC

Crown Chemical Corp.

BUK

Buckeye Cellulose Corp.

CRN

Corn Products Co.

BUR

Burroughs- Wellcome & Co. (U.S.A.), Inc.

CRS

Carus Chemical Co., Inc.

BXT

J. H. Baxter & Co.

CRT CRY

Crest Chemical Corp.

Tenneco Manufacturing Co. , Tenneco Plastics Div.

CAD

Cadet Chemical Corp.

CRZ

Crown Zellerbach Corp., Chemical Products Div.

CAL

Callery Chemical Co.

CSD

Cosden Oil & Chemical Co.

CAP

Cap- Roc, Inc., Capital Plastics Div.

CSO

Cities Service Oil Co.

CAT

Catalin Corp. of America

CST

Charles S. Tanner Co.

CAU

Calcasieu Chemical Corp.

CTA

Conestoga Chemical Corp.

CBA

Ciba Corp., Ciba Products Co.

CTL

Continental Chemical Co.

CBC

Georgia-Pacific Corp., Coos Bay Div.

CTN

Chemetron Corp., Chemetron Chemicals, Organic

CBD

Chembond Corp.

Chemical Dept.

CBM

Carborundum Co. , Coated Abrasives Div.

cue

Cumberland Chemical Corp., Subsidiary of Air

CBN

Columbian Carbon Co.

Reduction Co., Inc.

CBP

Ciba Corp., Ciba Pharmaceutical Co. Div.

CUL

Culver Chemical Co.

CBR

Colab Resin Corp.

CUT

Cutter Laboratories, Inc.

CBT

Samuel Cabot, Inc.

CW

General Mills, Inc., Chemical Div.

CBY

Crosby Chemicals, Inc.

CWL

Cowles Chemical Co.

CCA

Carlisle Chemical Works, Inc., Advance Div.

OWN

Upjohn Co., Carwin Organic Chemicals

CCC

Chase Chemical Corp.

CWP

Consolidated Papers, Inc.

CCH

Pearsall Chemical Co.

CYC

Cyclamate Corp. of America

•

CCI

Checkmate Chemicals, Inc.

CCL

Charlotte Chemical Laboratories

DA

Diamond Alkali Co., and Western Div.

CCO

Chemico, Inc.

DAN

Dan River Mills, Inc.

CCP

Crown Central Petroleum Corp.

DAV

Conchemco, Inc., H. B. Davis Co. Div.

CCW

Carlisle Chemical Works, Inc.

DBC

Dow Badische Chemical Co.

CD

Budd Co., Polychem Div.

DCC

Dow Corning Corp.

CEL

Celanese Corp. of America:

DCI

Delaware Chemicals, Inc.

Celanese Chemical Co. Div.

DEG

Degen Oil & Chemical Co.

Celanese Coatings Co.

DEP

DePaul Chemical Co., Inc.

Celanese Plastics Co. Fibers Co. Div.

DEX DIX

Dexter Chemical Corp. Dixie Chemical Co.

CEM

Chemirad Corp.

DLH

Hess Oil & Chemical Corp.

CFA

Cooperative Farm Chemicals Association

DLI

Dawe's Laboratories, Inc.

CFC

Rexall Chemical Co. - Kearny

DOD

Donald A. Dodd

CGL

Cargill, Inc.

DOM

Dominion Products, Inc.

CHC

Chipman Chemical Co. , Inc.

DOW

Dow Chemical Co.

CHF

Chemical Formulators, Inc.

DPP

Dixie Pine Products Co., Inc.

CHG

Chemagro Corp.

DRL

Caradco, Inc., Durel Div.

CHL

Chemol, Inc.

DRW

Drew Chemical Corp.

Dye Specialties, Inc.

DeSoto Chemical Coatings, Inc.

CHO CHT

Stauf fer Chemical Co. , Calhio Chemicals Div. Chattanooga Medicine Co. , Chattem Chemicals Div.

DSC DSO

DUN

Frank W. Dunne Co.

CIB

Ciba Chemical & Dye Co.

DUP

E. I. duPont de Nemours & Co., Inc.

CIK

Tenneco Chemicals, Inc., Ca]/lnk Div.

DVC

Dover Chemical Co.

CIS CKL

Chemical Insecticide Corp. Chemlek Laboratories, Inc.

DXS

Sunray DX Oil Co.

CLB

Columbia Organic Chemicals Co., Inc.

CLC

Charles L. Huisking & Co., Inc., Clintbrook

EAK

J. S. & W. R. EaMns, Inc.

Chemical Co. Div.

ECC

Eastern Color & Chemical Co.

CLD

Colloids, Inc.

EDO

Edcan Laboratories

CLI

Clintwood Chemical Co.

EFH

E. F. Houghton & Co.

CLK

Clark Oil & Refining Corp.

EK

Eastman Kodak Co.

CLN

Standard Brands, Inc., Clinton Corn Processing

EKT

Eastman Kodak Co., Tennessee Eastman Co. Div.

Co. Div.

EKX

Eastman Kodak Co., Texas Eastman Co. Div.

CLV

Clover Chemical Co.

ELP

El Paso Natural Gas Products Co.

CLY

W. A. Cleary Corp.

EMK

Emkay Chemical Co.

CM

Carpenter-Morton Co.

EMR

Emery Industries, Inc.

CMG

Nyanza, Inc.

EN

Endo Laboratories, Inc.

CMP

Commercial Products Co., Inc.

ENJ

Enjay Chemical Co.

CO

Continental Oil Co.

EPC

Epoxylite Corp.

COK

Cockerille Chemicals, Inc.

ESC

Escambia Chemical Corp.

COL

Collier Carbon & Chemical Corp.

ETD

Ethyl-Dow Chemical Co.

COM

Commercial Solvents Corp.

EVN

Evans Chemetics, Inc.

CON

Concord Chemical Co., Inc.

EW

Westinghouse Electric Corp., Insulating Materials

COP

Coopers Creek Chemical Corp.

Div.

DIRECTORY OF MANUFACTURERS TABLE 22, — Synthetic organic chemicals: Directory of manufacturers , 1965 — Continued

193

Code

Name of company

Code

Name of company

FAB

Fabricolor Manufacturing Corp.

GRV

Guardsman Chemical Coatings, Inc.

FAR

Fa mow, Inc.

GRW

Great Western Sugar Co.

FB

Frltzsche Bros., Inc.

GTH

Guth Chemical Co.

FBF

Fiberfil, Inc.

GTL

Great Lakes Chemical Corp.

FBR

Fibreboard Paper Products Corp.

GYR

Goodyear Tire & Rubber Co.

FC

Franklin Chemical Co.

FCA

Farmers Chemical Association, Inc.

HAB

Halby Products Co., Inc.

FCD

France, Campbell & Darling, Inc.

HAL

C. P. Hall Co. of Illinois

FCL

Federal Color Laboratories, Inc.

HAM

Hampden Color & Chemical Co.

FEL

Felton Chemical Co., Inc.

HAN

Hanna Paint Manufacturing Co., Inc.

FER

Ferro Corp., Ferro Chemical Div.

HAP

Applied Plastics Co., Inc.

FG

Foster Grant Co., Inc.

HCH

Houston Chemical Corp.

FH

Foster-Heaton Co.

HCO

Hamilton Chemical Corp.

FIN

Fine Organics, Inc.

HDG

Hodag Chemical Corp.

FIR

Firestone Tire & Rubber Co., Firestone

HER

Heresite & Chemical Corp.

Plastics Co. Div.

HET

Heterochemical Corp.

FIS

Fisher Melamine Corp.

HEX

Hexagon Laboratories, Inc.

FLH

H. B. Fuller Co.

HFT

Hoffman-Taff, Inc.

FLM

Fleming Laboratories, Inc.

HK

Hooker Chemical Corp.

FLO

Florasynth Laboratories, Inc.

HKD

Hooker Chemical Corp., Durez Plastics Div.

FLW

W. P. Fuller Paint Co.

HKY

Hawkeye Chemical Co.

FMB

FMC Corp., Inorganic Chemicals Div.

HLC

Hartman-Leddon Co.

FMN

FMC Corp., Niagara Chemical Div.

HLI

Haag Laboratories, Inc.

FMO

Fermco Laboratories, Inc.

HMP

W. R. Grace & Co., Hampshire Chemical Div.

FMP

FMC Corp., Organic Chemicals Div.

HMY

Humphrey Chemical Corp.

FMT

Fairmount Chemical Co., Inc.

HN

Tenneco Chemicals, Inc.

FOC

Farac Oil & Chemical Co.

HNC

H & N Chemical Co.

POM

Formica Corp.

HNW

Tenneco Chemicals, Inc., Newport Div.

FOR

Foremost Chemical Products Co.

HNX

Tenneco Chemicals, Inc., Nuodex Div.

FRE

Freeman Chemical Corp.

HOF

Hoffmann-LaRoche, Inc.

FRL

Firestone Tire & Rubber Co., Firestone Rubber

HOU

Air Products & Chemicals, Inc., Houdry Process

& Latex Products Co. Div.

& Chemical Co. Div.

FRM

Farmer's Chemical Co.

HPC

Hercules Powder Co . , Inc .

FRO

Vulcan Materials Co., Frontier Chemical Co.

HRS

Grow Chemical Corp., Harris Paint Co. Div.

Div.

HRT

Hart Products Corp.

FRP

Filtered Rosin Products Co.

HSC

Holland-Suco Color Co.

FRS

Firestone Tire & Rubber Co., Firestone

HSH

Harshaw Chemical Co.

Synthetic Rubber & Latex Co. Div.

HST

American Hoechst Corp.

FSH

Frisch & Co. , Inc.

HUM

National Dairy Products Corp., Humko Products

FTE

Foote Mineral Co.

Chemical Div.

HUS

Husky-Dominion Briquets

G

General Aniline & Film Corp. , Dyestuff &

HVG

Haveg Industries, Inc., Resin & Compound Div.

Chemical Div.

HYC

Hysol Corp.

GAM

Gamma Chemical Corp.

HYN

Hynson, Westcott & Dunning, Inc.

GAN

Gane's Chemical Works, Inc.

GCC

W. R. Grace & Co. , Nitrogen Products Div.

IBI

Industrial Biochemicals

GDN

Lancaster Chemical Corp., Gordon Chemicals

ICC

Interchemical Corp., Color & Chemicals Div.

Co. Div.

ICF

Interchemical Corp., Finishes Div.

GE

General Electric Co., Chemical Materials Dept.

ICI

I.C.I. (Organics), Inc.

GEI

General Electric Co., Insulating Materials

ICO

Interchemical Corp., Organic Chemicals Dept.

Dept.

IDC

Industrial Dyestuff Co.

GEO

Geolina Business, Inc.

IFF

International Flavors & Fragrances, Inc.

GFS

G. Frederick Smith Chemical Co.

ILC

International Latex Corp.

GGC

Goodrich-Gulf Chemicals, Inc.

IMC

International Minerals & Chemical Corp.

GGY

Geigy Chemical Corp.

IMP

Hercules Powder Co., Inc., Imperial Color &

GIL

Gilman Paint & Varnish Co.

Chemical Dept.

GIV

Givaudan Corp.

LMR

Imperial Chemical Co., Inc.

GLC

General Latex & Chemical Corp.

INL

Inland Steel Container Co.

GLD

Glidden Co., Durkee Famous Foods Div.

IOC

Ritter-Pfaudler Corp., Ionac Chemical Co. Div.

GLX

Glasflex, Inc.

IPC

Interplastic Corp., Commercial Resins Div.

GLY

Glyco Chemicals, Inc.

IPI

Isocyanate Products, Inc.

GNF

General Foods Corp., Maxwell House Div.

IPR

Inter-Pacific Resins, Inc.

GNM

General Mills, Inc.

IRC

IRC, Inc.

GNT

General Tire & Rubber Co., Chemical Div.

IRI

Ironsides Resins, Inc.

GOC

Gulf Oil Corp.

GOR

Gordon Chemical Co., Inc.

JCC

Jefferson Chemical Co., Inc.

GPM

General Plastics Manufacturing Co.

JDC

Nipak, Inc.

GPR

Grain Processing Corp.

JEN

Jennison-Wright Corp.

GRA

Great American Plastics Co.

JMS

J. Meyer & Sons, Inc.

GRD

W. R. Grace & Co., Dewey & Almy Chemical Div.

JNS

S. C. Johnson & Son, Inc.

GRG

P. D. George Co.

JNT

Jennat Corp.

GRH

W. R. Grace & Co., Hatco Chemical Div.

JOB

Jones-Blair Paint Co.

GRS

Pontiac Refining Corp.

JOR

Jordan Chemical Co.

194 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22.- -Synthetic organic chemicals: Directory of manufacturers , i365--Continued

Code

Name of company

Code

Name of company

JRG

Andrew Jergens Co.

MLS

Miles Laboratories, Inc., Miles Chemical Co. Div.

JSC

Jersey State Chemical Co.

MMM

Minnesota Mining & Manufacturing Co.

JTC

Joseph Turner & Co.

MNO

Monochem, Inc.

JWL

Jewel Paint & Varnish Co.

MNP

Minnesota Paints, Inc.

MOA

Mona Industries, Inc.

KAI

Kaiser Aluminum & Chemical Corp.

MOB

Mobay Chemical Co.

KAL

Kali Manufacturing Co.

MOC

Marathon Oil Co., Texas Refining Div.

KCC

Kennecott Copper Corp., Chino Mines Div.

MON

Monsanto Co.

KCH

Keystone Chemurgic Corp.

MOR

Mineral Oil Refining Co.

KCU

Kennecott Copper Corp., Utah Copper Div.

MOT

Motomco, Inc.

KCW

Keystone Color Works, Inc.

MPL

Massachusetts Plastics, Div. of Rexall Chemical Group

KEL

Kelly-Pickering Chemical Corp.

MPP

Midwest Plastic Products Co.

KM

Kendall Refining Co.

MR

Benjamin Moore & Co.

KET

Ketona Chemical Corp.

MRA

Metro-Atlantic, Inc.

KF

Kay- Fries Chemicals, Inc.

MRB

Marblette Corp.

KLS

Kilsdonk Chemical Corp.

MRD

Marden-Wild Corp.

KMC

Kohler-McLister Paint Co.

MRK

Merck & Co., Inc., and Metalsalts Corp.

KMP

Kelly-Moore Paint Co.

MRN

International Latex & Chemical Corp, Paisley

KND

Knoedler Chemical Co.

Products Div.

KNG

Far- Best Corp., 0. L. King Div.

MRO

W. R. Grace & Co., Marco Chemical Div.

KNP

Knapp Products, Inc.

MRT

Morton Salt Co., Morton Chemical Co. Div.

KON

H. Kohnstamm & Co., Inc.

MRV

Marlowe-Van Loan Corp.

KPI

Kenrich Petrochemicals, Inc.

MRX

Max Marx Color & Chemical Co.

KPP

Sinclair-Koppers Co.

MSC

Mississippi Chemical Corp.

KPS

Koppers Pittsburgh Co.

MTO

Montrose Chemical Corp. of California

KPT

Koppers Co., Inc., Tar & Chemical Div.

MTR

Baldwin-Montrose Chemical Co., Inc., Montrose

KRM

Lawter Chemicals, Inc., Krumbhaar Resin Div.

Chemical Div.

KYN

Kyanize Paints, Inc.

MYW

Stepan Chemical Co., Maywood Div.

KYS

Keysor Chemical Co.

NAC

Allied Chemical Corp. , National Aniline Div.

LAK

Lakeway Chemical Co.

NCI

Union Bag-Camp Paper Corp., Nelio Chemical Div.

LAM

LaMotte Chemical Products Co.

NCW

Nostrip Chemical Works, Inc.

LAS

Lasco Industries, Inc.

NEO

Norda Essential Oil & Chemical Co., Inc.

LEA

Leatex Chemical Co.

NEP

Nepera Chemical Co., Inc.

LEB

Lebanon Chemical Corp.

NES

Nease Chemical Co., Inc.

LEF

Leffingwell Chemical Co.

NEV

Neville Chemical Co.

LEH

Lehigh Chemical Co.

NIL

Nilok Chemicals, Inc.

LEM

B. L. Lemke & Co., Inc.

NIT

Nitrin, Inc.

LEN

Leonard Refineries, Inc.

NIX

Tenneco Chemicals, Inc., Nixon- Baldwin Div.

LEV

Lever Brothers Co.

NLC

Nalco Chemical Co.

LIL

Eli Lilly & Co.

NOC

Norac Co., Inc.

LKL

Lakeside Laboratories, Div. of Colgate-

NON

A. P. Nonweiler Co.

Palmolive Co.

NOP

Nopco Chemical Co., Inc.

LKY

St. Regis Paper Co., Lake States Yeast &

NOR

Norwich Pharmacal Co.

Chemical Div.

NPC

Northwest Petrochemical Corp.

LMI

North American Chemical Co.

NPI

National PoLychemicals, Inc.

LPC

Lignin Products Co.

NPP

National Plastic Products Co., Inc.

LUB

Lubrizol Corp.

NPV

Norris Paint & Varnish Co.

LUE

George Lueders & Co.

NRS

Norse Chemical Corp.

LUR

Laurel Soap Manufacturing Co.

NSC

National Starch & Chemical Corp.

LVR

C. Lever Co., Inc.

NSP

Alabama Binder & Chemical Corp.

LVY

Fred'k H. Levey Co., Inc.

NTB

National Biochemical Co.

NTC

National Casein Co.

MAH

Maher Color & Chemical Co.

NTL

National Lead Co.

MAK

MacKenzie Chemical Works, Inc.

NVF

N.V.F. Co.

MAL

Mallinckrodt Chemical Works

NVT

Novamont Corp.

MAN

Manganese Chemical Corp.

NW

Northwestern Chemical Co.

MAR

American Can Co., Marathon Div.

NYC

New York Color & Chemical Corp., Subsidiary of

MAY

Otto B. May, Inc.

Tenneco Chemicals, Inc.

MCA

Masonite Corp. , Alpine Chemical Div.

MCB

Borg- Warner Corp., Maroon Chemical Div.

OCF

Owens- Corning Fiberglas Corp.

MCC

McCloskey Varnish Co.

OH

Air Reduction Co., Inc., Ohio Chemical & Surgical

MCH

Michigan Chemical Corp.

Equipment Co. Div.

MCI

Mooney Chemical Corp.

OMC

Olin Mathieson Chemical Corp. and Agricultural Div.

MED

Medical Chemicals Corp.

OMS

E. R. Squibb & Sons Div. of Olin Mathieson Chemical

MEE

Maumee Chemical Co.

Corp.

MER

Jefferson Lake Sulphur Co. , Chemical Div.

ONX

Millmaster Onyx Corp. , Onyx Chemical Co. Div.

MET

M &. T Chemicals, Inc.

OPC

Orbis Products Corp.

MFG

Molded Fiber Glass Body Co., Resin Div.

ORG

Organics, Inc.

MGR

Magruder Color Co., Inc.

0R0

Chevron Chemical Co., Oronite Div.

MHI

Ventron Corp., Metal Hydrides Div.

ORT

Roehr Chemicals, Inc.

MID

Midland Industrial Finishes Co.

OSB

C. J. Osborn Co.

MIR

Miranol Chemical Co., Inc.

OTA

Ottawa Chemical Co.

MLD

Metalead Products Corp. 1

OTC

Ott Chemical Co.

DIRECTORY OF MANUFACTURERS TABLE 22, — Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued

195

Code

Name of company

Code

Name of company

OTH

Chevron Chemical Co. , Ortho Div.

RCD

Richardson Co.

0X0

Oxo Chemicals Co.

RCI

Reichhold Chemicals, Inc.

OXR

Onyx Oils & Resins, Inc.

RDA

Rhodia, Inc.

OXY

Millmaster Onyx Corp. , Oxy Chemical Div.

RED

Red Spot Paint & Varnish Co., Inc.

REH

Reheis Chemical Co. , Div. of Armour Pharmaceutical Co.

PAI

Pennsylvania Industrial Chemical Corp.

REL

Reliance Universal, Inc.

PAN

Pan American Petroleum Corp.

REM

Remington Arms Co., Inc.

PAR

Pennsylvania Refining Co.

REN

Renroh Resins

PAS

Pennsalt Chemicals Corp.

RET

Rayette, Inc.

PAT

Patent Chemicals, Inc.

REZ

Rezolin, Inc.

PBY

Pillsbury Co., Chemical Div.

RGC

Rogers Corp.

PC

Proctor Chemical Co., Inc.

RH

Rohm & Haas Co.

PCC

USS Chemicals Div. of U.S. Steel Corp.

RIC

Richfield Oil Corp.

PCH

Peerless Chemical Co.

RIK

Riker Laboratories Div. of Rexall Drug & Chemical Co.

PCI

Pioneer Chemical Works, Inc.

RIL

Reilly Tar & Chemical Corp.

PCS

Emery Industries, Inc., Western Div.

RIV

Riverdale Chemical Co.

PCW

Pfister Chemical Works

RLS

Rachelle Laboratories, Inc.

PD

Parke, Davis & Co.

RMC

Rinshed-Mason Co.

PDC

Berncolors-Poughkeepsie, Inc.

ROC

Rock Hill Printing & Finishing Co.

PDJ

Joseph Davis Plastics Co.

ROM

Roma Chemical Corp.

PEK

Peck's Products Co.

ROY

Royce Chemical Co.

PEL

Pelron Corp.

RPC

Refined Products Co.

PEN

S. B. Penick & Co.

RPI

Rowland Products, Inc.

PER

Perry & Derrick Co.

RSA

R.S.A. Corp.

PET

Petroleum Chemicals, Inc.

RSB

Rosenberg Bros. & Co.

PFN

Pfanstiehl Laboratories, Inc.

RT

F. Ritter & Co.

PFP

Phe Ian- Faust Paint Manufacturing Co.,

RTC

Ritter Chemical Co., Inc.

Phelan's Resins & Plastics Div.

RTF

Retzloff Chemical Co.

PFW

Polak's Frutal Works

RUB

Hooker Chemical Corp., RC Div.

PFZ

Chas. Pfizer & Co., Inc.

RUR

Ruberoid Co.

PG

Procter & Gamble Co., Procter & Gamble Manufacturing Co. Div.

RZL

Rozilda Laboratories, Inc.

PGU

Gulf Oil Corp., Chemical Div., Perkins Glue

S

Sandoz, Inc., Dyestuff Div., Pigments Dept.

Branch

SAC

Southeastern Adhesives Co.

PHR

Pharmachem Corp.

SAL

Salsbury Laboratories

PIC

Pierce Organics, Inc.

SAR

Sartomer Resins, Inc.

PII

Polymer Industries, Inc.

SBC

Scher Bros., Inc.

PIL

Pilot Chemical Co.

sec

Standard Chlorine Chemical Co., Inc.

PIT

Pitt-Consol Chemical Co.

SCF

Schaefer Varnish Co., Inc.

PLA

Richardson Co., Richardson Polymers Div.

SCH

Schering Corp.

PLB

P-L Biochemicals, Inc.

SCN

Schenectady Chemicals, Inc.

PLC

Phillips Petroleum Co.

SCO

Scholler Bros., Inc.

PLS

Plastics Engineering Co.

SCP

Standard Chemical Products, Inc.

PLU

Plumb Chemical Corp.

SCR

R. P. Scherer Corp.

PMA

Plastics Materials, Inc.

SDC

Martin-Marietta Corp., Southern Dyestuff Co. Div.

PMC

Plastics Manufacturing Co.

SDG

Sterling Drug, Inc., Glenbrook Laboratories Div.

PMP

Premier Malt Products, Inc.

SDH

Sterling Drug, Inc., Hilton-Davis Chemical Co. Div.

PNT

Pantasote Co.

SDW

Sterling Drug, Inc., Winthrop Laboratories Div.

PNX

Phoenix Oil Co.

SEA

Seaboard Chemicals, Inc.

POL

Polymer Corp.

SED

Seidlitz Paint & Varnish Co.

PPG

Pittsburgh Plate Glass Co.

SEK

Sekisui Plastics Corp.

PPL

Pioneer Plastics Corp., Chemical Div.

SEL

Selney Co., Inc.

PRO

Products Research & Chemical Corp.

SEP

Southeast Polymers, Inc.

PRD

Productol Chemical Co., Inc.

SEY

Seydel-Woolley & Co. , Inc.

PRO

Pure Oil Co.

SF

Stauffer Chemical Co., Industrial Chemical Div.

PRP

S. B. Penick & Co., Parsons-Plymouth Div.

SFA

Stauffer Chemical Co., Specialty Chemical Div.

PRT

Pratt & Lambert, Inc.

SFD

Sonford Chemical Co.

PRX

Purex Corp., Ltd.

SH

Stein, Hall & Co., Inc.

PSC

Passaic Color & Chemical Co.

SHA

Shanco Plastics & Chemicals, Inc.

PSP

Georgia-Pacific Corp., Puget Sound Div.

SHC

Shell Oil Co., Shell Chemical Co. Div.

PTT

Petro-Tex Chemical Corp.

SHF

National Dairy Products Corp., Sheffield Chemical

PUB

Publicker Industries, Inc.

Co. Div.

PVI

Polyvinyl Chemicals, Inc.

SHL

Shulton, Inc.

PYL

Polychemical Laboratories, Inc.

SHM

Shamrock Oil & Gas Corp.

PYR

Poly Resins

SHO

Shell Oil Co.

PYZ

Polyrez Co., Inc.

SHP

Shepherd Chemical Co.

SIC

Vistron Corp., Silmar Div.

QCP

Quaker Chemical Corp.

SID

George F. Siddall Co., Inc.

QKO

Quaker Oats Co.

SIM

Simpson Timber Co.

QUN

K. J. Quinn & Co., Inc.

SIN

Sinclair Refining Co.

SIO

Standard Oil Co. of Ohio

RAB

Raybestos-Manhattan, Inc., Raybestos Div.

SIP

James P. Sipe & Co.

RBC

Roberts Chemicals, Inc.

SK

Smith, Kline & French Laboratories

RCC

Rexall Chemical Co.

SKC

Sinclair Koppers Chemical Co.

196 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers, 1965 — Continued

Code

Name of company

Code

Name of company

SKG

Sunkist Growers, Inc.

TRN

Trancoa Chemical Corp.

SKO

Skelly Oil Co.

TRO

Troy Chemical Co.

SLC

Soluol Chemical Co., Inc.

TSA

Texas ALkyls, Inc.

SLV

Sterling Drug, Inc., Salvo Chemical Div.

TTX

Detrex Chemical Industries, Inc.

SM

Socony Mobil Oil Co., Inc.:

TUS

Texas-U.S. Chemical Co.

Mobil Chemical Co. Div.

TV

Tousey Varnish Co.

Mobil Oil Co. Div.

TX

Texaco, Inc.

SMC

Stamford Chemical Co.

TXC

Tex Chem Co.

SNA

Sun Chemical Corp., Pigments Div.

TXT

Textilana Corp.

SNC

Sonoco Products Co.

SNI

Southern Nitrogen Co., Inc.

UBS

A. E. Staley Manufacturing Co., UBS Chemical

SNO

SunOlin Chemical Co.

Co. Div.

SNT

Suntide Refining Co.

UCC

Union Carbide Corp., Chemicals Div.

SNW

Sun Chemical Corp., Chemical Products Div.

UCP

Union Carbide Corp., Plastics Div.

SOC

Standard Oil Co. of California, Chevron

ucs

Union Carbide Corp., Silicones Div.

Chemical Co.

UDI

Universal Detergents, Inc. & Petrochemicals

Co.

SOG

Signal Oil & Gas Co. , Houston Div.

UHL

Paul Uhlich & Co., Inc.

SOH

Sohio Chemical Co. & Solar Nitrogen

UNC

United Cork Companies

Chemicals, Inc.

UNG

Ungerer & Co.

SOI

American Oil Co. (Maryland)

UNN

United Chemical Corp. of Norwood

SOL

Solar Chemical Corp.

UNO

United Oil Manufacturing Co.

SON

Witco Chemical Co., Inc., Sonneborn Div.

UNP

United Chemical Products Corp.

SOR

Thomason Industries, Inc., Southern Resin Div.

UNS

Union Starch & Refining Co., Inc.

SOS

Southern Sizing Co.

UOC

Union Oil Co. of California

SPC

Sinclair Paint Co.

UPF

United States Pipe & Foundry Co.

SPD

General Electric Co., Silicone Products Dept.

UPJ

Upjohn Co.

SPI

Sinclair Petrochemicals, Inc.

UPL

United States Plywood Corp., California Div

,

SPL

Spaulding Fibre Co., Inc.

Shasta Operations

SPN

Gulf Oil Corp., Chemicals Dept.

UPM

Universal Oil Products Co.

SPY

Standard Pyroxoloid Corp.

UPR

U.S. Peroxygen Corp.

SRL

G. D. Searle & Co.

URC

United Carbon Co.

SRR

Stresen-Reuter, Inc.

USB

U.S. Borax Research Corp.

STA

A. E. Staley Manufacturing Co.

USI

National Distillers & Chemical Corp. :

STC

Sou-Tex Chemical Co., Inc.

A-B Chemical Corp. Div.

STG

Stange Co.

National Petro Chemical Corp. Div.

STP

Stepan Chemical Co., Industrial Chemicals

U.S. Industrial Chemicals Co. Div.

Div., Millsdale Works

USO

U.S. Oil Co.

SUG

Sucro-Chemical Div. of Colonial Sugars Co.

USP

U.S. Plastic & Chemical Corp.

SUM

Summit Chemical Products Corp.

USR

United States Rubber Co., Chemical Div.

SUN

Sun Oil Co.

UTR

Utah Resin Co., Inc.

SVC

Sullivan Varnish Co.

UVC

Universal Chemicals Corp.

SVT

Solvent Chemical Co., Inc.

SW

Sherwin-Williams Co.

VAC

Varney Chemical Corp.

SWP

Souhegan Wood Products, Inc.

VAL

Valchem

swr

Swift & Co.

VAR

Reichhold Chemicals, Inc., Varcum Chemical Div.

SYC

Synthetic Chemicals, Inc.

VB

Vermi lye- Bell

SYN

Synthron, Inc.

VDM

Van De Mark Chemical Co.

SYP

Synthetic Products Co.

VEL

Velsicol Chemical Corp.

SYR

Syneo Resins, Inc.

VGC

Virginia Chemicals, Inc.

SYV

Synvar Corp.

VIN VLY

Vineland Chemical Co. Chem-Fleur, Inc.

TAE

Chemtron Corp. , National Cylinder Gas Div.

VNC

Vanderbllt Chemical Corp.

TAY

Taylor Corp.

VND

Van Dyk & Co., Inc.

TBK

Universal Oil Products Co., Chemical Div.

VPC

Verona-Pharma Chemical Corp.

TCC

Tanatex Chemical Corp.

VPT

Viekers Refining Co., Inc.

TCH

Trylon Chemical Corp.

VSV

Valentine Sugars, Inc., Valite Div.

TCI

Texize Chemicals, Inc.

VTM

Vitamins, Inc.

TDC

Diversey Corp.

VTV

Vita-Var Corp., Div. of Textron Industries,

Inc.

TEN

Tennessee Copper Co.

TGL

Triangle Chemical Co.

WAS

Washburn-Purex Co.

THC

Thompson Chemical Co.

WAW

W. A. Wood Co.

TIC

Ticonderoga Chemical Corp.

WAY

Philip A. Hunt Chemical Corp., Way land Chemical Div.

TID

Tidewater Oil Co.

WBC

Worthington Biochemical Corp.

TKL

Thiokol Chemical Corp.

WBG

White & Bagley Co.

TMC

Tenneco Manufacturing Co.

WCA

West Coast Adhesives Co.

TMH

Thompson- Hayward Chemical Co.

WCC

Witfield Chemical Corp.

TMS

Sterling Drug, Inc., Thomasset Colors Div.

WES

Weston Chemical Corp.

TNA

Ethyl Corp.

WHI

White 8c Hodges, Inc.

TNC

Tennant Development Corp., Chemical Div.

WHL

Whitmoyer Laboratories, Inc.

TNI

Gillette Chemical Co.

WHW

Whittemore- Wright Co., Inc.

TOC

Tenneco Oil Co.

WIC

Wica Chemicals, Inc.

TRC

Toms River Chemical Corp.

WIL

Wilson 8c Co., Inc., Wilson Laboratories Div

TRJ

Trojan Powder Co.

WJ

Warner-Jenkinson Manufacturing Co.

DIRECTORY OF MANUFACTURERS TABLE 11. — Synthetic organic chemicals; Directory of manufacturers, 1965 — Continued

197

Code

Name of company

Code

Name of company

WLI

White Laboratories, Inc.

WTC

Witco Chemical Co. , Inc.

WLM

Wilmot 8c Cassidy, Inc.

WTH

Wallace & Tiernan, Inc., Harchejn Div.

WM

Wilson & Co., Inc., Wilson-Martin Di v.

WTL

Wallace 8c Tiernan, Inc., Lucidol Div.

TOD

Wood Chemicals, Inc.

WVA

West Virginia Pulp 8c Paper Co.,

TOI

Neville Chemical Co., Chlorinated

Polychemicals Div.

Products Div.

WYN

Wyandotte Chemicals Corp.

TON

Woonsocket Color & Chemical Co.

WYT

American Home Products Corp., lyeth Laboratories,

WRC

Wood Ridge Chemical Corp.

Inc. Div.

WRD

Weyerhaeuser Co., Wood Products Div.

WSN

Washine Chemical Corp.

YAW

Young Aniline Works, Inc.

198

SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued

SECTION 2. ALPHABETICAL DIRECTORY BY COMPANY

[Names of synthetic organic chemical manufacturers that reported production or sales to the U.S. Tariff Commission for 1965 are listed below alphabetically, together with their identification codes as used in tables in pt. III. Sec. 1 of this table lists these manufacturers in the order of their identification codes]

Name of company

Office address

Abbott Laboratories

Aceto Industrial Chemical Corp

Acme Resin Corp

Acralite. Co. , Inc

Air Products & Chemicals, Inc., Houdry Process

& Chemical Co. Div. Air Reduction Co., Inc., Ohio Chemical & Surgical Equipment Co. Div.

Alabama Binder & Chemical Corp

Alamo Industries, Inc

Alco Chemical Corp

Alcolac Chemical Corp

Aldrich Chemical Co., Inc

Alliance Color & Chemical Co

Allied Chemical Corp.:

Barrett Div

Fibers Div

General Chemical Div

National Aniline Div

Nitrogen Div

Solvay Process Div

Union Texas Petroleum Div

Alox Corp

Amalgamated Chemical Corp

Amchem Products, Inc

American Alkyd Industries

American Aniline & Extract Co., Inc

American Aniline Products, Inc

American Bio-Synthetics Corp

American Brake Shoe Co., American Brakeblok Div —

American Can Co., Marathon Div —

American Chemical Corp

American Cyanamid Co

American Hoechst Corp

American Home Products Corp., Wyeth Laboratories, Inc. Div.

American Oil Co. (Maryland)

American Oil Co. (Texas) ;

American Petrochemical Corp

American Potash & Chemical Corp

American Synthetic Rubber Corp

American Rubber & Chemical Co

American Tartars Corp

Ames Laboratories, Inc

Amoco Chemicals Corp

Ancon Chemical Co

Ansul Chemical Co

Apex Chemical Co., Inc

Appleton Coated Paper Co

Applied Plastics Co., Inc ■

Archer-Daniels-Midland Co

Ardmore Chemical Co

Arenol Chemical Corp

Argus Chemical Corp

Arizona Chemical Co

Arkansas Co., Inc

Armour Agricultural Chemical Co

Armour Industrial Chemical Co

Armour Pharmaceutical Co ■

Armstrong Cork Co

Armstrong Paint & Varnish Works, Inc

Arol Chemical Products Co

Ashland Oil & Refining Co

Astra Pharmaceutical Products, Inc

Atco Chemical- Industrial Products, Inc

14th St. and Sheridan Rd., N. Chicago, IL 60664.

126-02 Northern Blvd., Flushing, New York, NY 11363.

1401 Circle Ave., Forest Park, IL 60130.

59 Kent St., Brooklyn, NY 11222.

Widener Bldg., 1339 Chestnut St., Philadelphia, PA 19107.

1400 E. Washington Ave., Madison, WI 53701.

P.O. Box 3179, Tuscaloosa, AL 35401.

Ervin Bldg., 4037 Independence Blvd., Charlotte, NC 28205.

Trenton Ave. and William St., Philadelphia, PA 19134.

3440 Fairfield Rd., Baltimore, MD 21226.

2371 N. 30th St., Milwaukee, WI 53210.

P.O. Box 326, Ridgefield, NJ 07657.

40 Rector St., New York, NY 10006.

1450 Broadway, New York, NY 10018.

P.0'. Box 70, Morristown, NJ 07960.

40 Rector St., New York, NY 10006.

P.O. Drawer 61, Hopewell, VA 23860.

P.O. Box 365, Morristown, NJ 07960, and 225 Allwood Rd.,

Clifton, NJ 07015. P.O. Box 271, Syracuse, NY 13201. P.O. Box 2120, Houston, TX 77001. 3943 Buffalo Ave., Niagara Falls, NY 14302. Ontario and Rorer Sts., Philadelphia, PA 19134. Brookside Ave., Ambler, PA 19002. Broad and 14th Sts., Carlstadt, NJ 07072. Venango and F Sts., Philadelphia, PA 19134. P.O. Box 2086, Paterson, NJ 07509. 710 W. National Ave., Milwaukee, WI 53204. 900 W. Maple Rd., Troy, MI 48012. Neenah, WI 54957.

P.O. Box 9247, Long Beach, CA 90810. Berdan Ave., Wayne, NJ 07470.

129 Quidnick St., W. Warwick, NJ 02893. P.O. Box 8299, Philadelphia, PA 19101.

910 S. Michigan Ave., Chicago, IL 60680.

910 S. Michigan Ave., Chicago, IL 60680.

3134 California St., N.E., Minneapolis, MN 55418.

3000 W. 6th St., Los Angeles, CA 90054.

P.O. Box 360, Louisville, KY 40201.

P.O. Box 1034, Louisville, KY 40201.

420 Lexington Ave . , New York, NY 10017.

200 Rock Lane, Milford, CT 06460.

130 E. Randolph Dr., Chicago, IL 60601. 1 Stanton St., Marinette, WI 54143.

1 Stanton St., Marinette, WI 54143.

200 S. 1st St., Elizabethport, NJ 07206.

825 E. Wisconsin Ave., Appleton, WI 54910.

130 Perm St., El Segundo, CA 90246.

500 Investors Bldg., Minneapolis, MN 55440.

840 Valley Brook Ave., Lyndhurst, NJ 07071.

40-33 23d St., Long Island City, NY 11101.

633 Court St., Brooklyn, NY 11231.

Ill W. 50th St., New York, NY 10020.

185 Foundry St., P.O. Box 210, Newark, NJ 07101.

P.O. Box 1685, Atlanta, GA 30301.

P.O. Box 1805, Chicago, IL 60609.

P.O. Box 511, Kankakee, IL 60901.

W. Liberty St., Lancaster, PA 17604.

1330 S. Kilbourn Ave., Chicago, IL 60623.

371 Wayne St., Jersey City, NJ 07302.

1401 Winchester Ave., Ashland, KY 41101. 7 Neponset St., Worcester, MA 01606.

93 Main St., Franklin, NJ 07416.

DIRECTORY OF MANUFACTURERS TABLE 22.-- Synthetic organic chemicals : Directory of manufacturers , 1 965— Continued

199

ATL ATR ATU APD APR AUG AVS AZT

BRD BAC BKC BKT MTR

BAL

BC

BXT

BAX

BLS

BCM

BL

BME

BEN

BDO

BPC

PDC

BUC

BOR

MCB

BOY

BFR

BPL

BBS

BLN

BRU

BRY

BUK

BKM

CD

BJL

BSC

BUR

CBT CAD CAU CAL CAP DRL CBM CGL

CCW

CCA

CM

CRS

CAT

CEL

CCL CCC CHT CCI CHG CBD

CTN TAE VLY

Name of company

Atlantic Chemical Corp

Atlantic Refining Co

Atlantic Tubing & Rubber Co

Atlas Chemical Industries, Inc.

Atlas Processing Co

Augusta Chemical Co

Avisun Corp

Aztec Chemicals, Inc

Chemicals Div —

Baird Chemical Industries, Inc

Baker Castor Oil Co

J. T. Baker Chemical Co

Taylor Div

Baldwin-Montrose Chemical Co., Inc., Montros Chemical Div.

Baltimore Paint & Chemical Corp

Barlow Chemical Corp

J. H. Baxter & Co

Baxter Laboratories, Inc

Beech-Nut Life Savers, Inc

Belding Chemical Industries

Belle Chemical Co., Inc

Bendix Corp., Marshall-Eclipse Div

Bennett's

Benzenoid Organics, Inc

Benzol Products Co

Berncolors-Poughkeepsie, Inc

Blackman-Uhler Chemical Co

Borden Co., Borden Chemical Co. Div

Borg-Warner Corp., Marbon Chemical Div

Walter N. Boysen Co

Branchf lower Co

Brand Plastics Co

Bristol-Meyers Co., Bristol Laboratories Div

Brooklyn Color Works, Inc

M. A. Bruder & Sons, Inc

Bryant Chemical Corp

Buckeye Cellulose Corp

Buckman Laboratories, Inc

Budd Co., Polychem Div

Burdick & Jackson Laboratories, Inc

Burkart-Schier Chemical Co-

Burroughs-Wellcome & Co. (U.S.A.), Inc

Samuel Cabot, Inc

Cadet Chemical Corp

Calcasieu Chemical Corp

Callery Chemical Co

Cap-Roc, Inc., Capital Plastics Div

Caradco, Inc., Durel Div

Carborundum Co., Coated Abrasives Div- Cargill, Inc

Carlisle Chemical Works, Inc

Advance Div

Carpenter-Morton Co

Carus Chemical Co., Inc

Catalin Corp. of America

Celanese Corp. of America:

Celanese Chemical Co. Div

Celanese Coatings Co

Celanese Plastics Co

Fibers Co. Div

Charlotte Chemical Laboratories

Chase Chemical Corp

Chattanooga Medicine Co., Chattem Chemicals Div-

Checkmate Chemicals, Inc

Chemagro Corp

Chembond Corp

Chemetron Corp.:

Chemetron Chemicals, Organic Chemical Dept

National Cylinder Gas Div

Chem-Fleur, Inc

Office address

P.O. Box 216, Nutley, NJ 07110.

260 S. Broad St., Philadelphia, PA 19101.

Mill St., Cranston, RI 02905.

New Murphy Rd. and Concord Pike, Wilmington, DE 19899.

P.O. Box 1786, 3546 Midway St., Shreveport, LA 71102.

P.O. Box 660, Augusta, GA 30903.

P.O. Box 312, New Castle, DE 19720.

P.O. Box 756, Elyria, OH 44035.

185 Madison Ave., New York, NY 10016. 40 Avenue A, Bayonne, NJ 07002. 600 N. Broad St., Phillipsburg, NJ 08865. 600 N. Broad St., Phillipsburg, NJ 08865. 100 Lister Ave., Newark, NJ 07105.

2325 Hollins Ferry Rd., Baltimore, MD 21230.

Barlow Lane, Ossining, NY 10562.

120 Montgomery St., San Francisco, CA 94104.

6301 N. Lincoln Ave., Morton Grove,- IL 60053.

Canajoharie, NY 13317.

1407 Broadway, New York, NY 10018.

P.O. Box 848, Lowell, NC 28089.

P.O. Box 238, Troy, NY 12180.

65 W. 1st S., Salt Lake City, UT 84110.

P.O. Box 177, Attleboro, MA 02703.

237 South St., Newark, NJ 07114.

77 N. Water St., Poughkeepsie, NY 12602.

P.O. Box 1869, Spartanburg, SC 29301.

350 Madison Ave., New York, NY 10017. P.O. Box 68, Washington, WV 26181.

1001 42d St., Oakland, CA 94608.

4501 Shilshole St. NW., Seattle, WA 98103.

130 E. Randolph Dr., Chicago, IL 60601.

P.O. Box 657, Syracuse, NY 13201.

681 Morgan Ave., Brooklyn, NY 11222.

52d St.. and Grays Ave., Philadelphia, PA 19143.

6 North St., N. Quincy, MA 02171.

2899 Jackson Ave., Memphis, TN 38108.

1256 N. McLean Blvd., Memphis, TN 38108.

70 S. Chapel St., Newark, DE 19711.

1953 S. Harvey St., Muskegon, MI 49442.

1228 Chestnut St., Chattanooga, TN 37402.

1 Scarsdale Rd., Tuckahoe, NY 10707.

246 Summer St., Boston, MA 02210.

2153 Lockport-Olcott Rd., Burt, NY 14028.

P.O. Box 1522, Lake Charles, LA 70601.

Callery, PA 16024.

250 Mill St., Rochester, NY 14614.

1098 Jackson St., Dubuque, IA 52000.

P.O. Box 477, Niagara Falls, NY 14302.

Room 2008, 3 Penn Center Plaza, Philadelphia, PA 19102,

and Cargill Bldg., Minneapolis, MN 55402. West St., Reading, OH 45215. 500 Jersey Ave., New Brunswick, NJ 08903. 376 W. 3d St., Everett, MA 02149. 1375 8th St., LaSalle, IL 61301. 1 Park Ave., New York, NY 10016.

522 5th Ave., New York, NY 10036.

1481 S. 11th St., Louisville, KY 40208.

744 Broad St., Newark, NJ 07102.

P.O. Box 1414, Charlotte, NC 28201.

P.O. Box 948, 5046 Old Pineville Rd., Charlotte, NC 28201.

3527 Smallman St., Pittsburgh, PA 15201.

1717 W. 38th St., Chattanooga, TN 37409.

P.O. Box 2164, Greenville, SC 29602.

P.O. Box 4913, Station "F", Kansas City, M0 64120.

P.O. Box 270, Springfield, OR 97477.

201 E. 42d St., New York, NY 10017.

840 N. Michigan Ave., Chicago, IL 60611.

200 Pulaski St., Newark, NJ 07105.

20o SYNTHETIC ORGANIC CHEMICALS. 1965

TABLE 22.— Synthetic organic chemicals.- Directory of manufacturers , 1 965— Continued

Name of company

Chemical Formulators, Inc

Chemical Insecticide Corp

Chemical Products Corp

Chemico, Inc

Chemirad Corp

Chemlek Laboratories, Inc

Chemol, Inc

Chevron Chemical Co.:

Oronite Div

Ortho Div

Childs Pulp Colors, Inc

Chipman Chemical Co., Inc

Ciba Chemical & Dye Co

Ciba Corp.:

Ciba Pharmaceutical Co. Div

Ciba Products Co

Cities Service Oil Co

Clark Oil & Refining Corp

W. A. Cleary Corp

Clintwood Chemical Co

Clover Chemical Co

Cockerille Chemicals, Inc

Colab Resin Corp

Colgate-Palmolive Co

Collier Carbon & Chemical Corp

Colloids, Inc

Columbian Carbon Co

Columbia Organic Chemicals Co., Inc

Commercial Products Co., Inc

Commercial Solvents Corp

Commonwealth Oil Refining Co., Inc

Conchemco, Inc., H. B. Davis Co. Div

Concord Chemical Co., Inc

Conestoga Chemical Corp

Consolidated Papers, Inc

Continental Chemical Co

Continental Oil Co

Cook Paint & Varnish Co

Cooperative Farm Chemicals Association

Coopers Creek Chemical Corp

Copolymer Rubber & Chemical Corp

Corn Products Co

Cosden Oil & Chemical Co

Cowles Chemical Co

Crest Chemical Corp

Crompton & Knowles Corp . :

Althouse Chemical Co. Div

Bates Div

Crosby Chemicals, Inc

Crown Central Petroleum Corp

Crown Chemical Corp

Crown Zellerbaeh Corp., Chemical Products Div

Culver Chemical Co

Cumberland Chemical Corp., Subsidiary of Air Reduction Co., Inc.

Cutter Laboratories, Inc

Cyclamate Corp. of America

Office address

Dan River Mills, Inc

Joseph Davis Plastics Co

Dawe's Laboratories, Inc

Degen Oil & Chemical Co

Delaware Chemicals, Inc

DePaul Chemical Co., Inc

DeSoto Chemical Coatings, Inc — Detrex Chemical Industries, Inc-

Dexter Chemical Corp

Diamond Alkali Co

Western Div

Diversey Corp

Dixie Chemical Co-

Dixie Pine Products Co., Inc

Donald A. Dodd

P.O. Box 26, Nitro, WV 25143.

20 Whitman Ave., Metuchen, NJ 08840.

P.O. Box 449, Cartersville, GA 30120.

2508 E. Bailey Rd., Cuyahoga Falls, OH 44221.

P.O. Box 187 (Ryders Lane), E. Brunswick. NJ 08816.

4040 W. 123d St., Alsip, IL 60658.

P.O. Box 3227, Greensboro, NC 27402.

200 Bush St., San Francisco, CA 94120.

940 Hensley, Richmond, CA 94800.

43 Summit St., Brooklyn, NY 11231.

P.O. Box 2009, 297 Jersey Ave., New Brunswick, NJ 08903.

Route 208, Fair Lawn, NJ 07410.

556 Morris Ave., Summit, NJ 07901.

556 Morris Ave., Summit, NJ 07901.

P.O. Box 300, Tulsa, OK 74102.

131st St. and Kedzie Ave., Blue Island, IL 60406.

P.O. Box 749, New Brunswick, NJ 08903.

1 N. LaSalle St., Chicago, IL 60602.

360 Regis Ave., Pittsburgh, PA 15236.

Greenwood, VA 22943.

Main St., Tewksbury, MA 01876.

300 Park Ave., New York, NY 10022.

714 W. Olympic Blvd., Los Angeles, CA 90015.

394 Frelinghuysen Ave., Newark, NJ 07114.

380 Madison Ave., New York, NY 10017.

912 Drake St., Columbia, SC 29205.

117 Ethel Ave., Hawthorne, NJ 07641.

260 Madison Ave., New York, NY 10016.

P.O. Box 4423, San Juan, PR 00905.

Bayard and Severn Sts . , Baltimore, MD 21230.

205 S. 2d St., Camden, NJ 08103.

Wilmington Industrial Park, Wilmington, DE 19801.

Wisconsin Rapids, WI 54494.

270 Clifton Blvd., Clifton, NJ 07015.

9 Rockefeller Plaza, New York, NY 10020.

P.O. Box 389, N. Kansas City, M0 64141.

P.O. Box 308, Lawrence, KS 66044.

River Rd., W. Conshohocken, PA 19428.

P.O. Box 2591, Baton Rouge, LA 70821.

717 5th Ave., New York, NY 10022.

P.O. Box 1311, Big Spring, TX 70721.

12000 Shaker Blvd., Cleveland, OH 44120.

225 Emmet St., Newark, NJ 07114.

500 Pear St., Reading, PA 19603. Scottdale Rd., Lansdowne, PA 19050. P.O. Drawer 460, Picayune, MS 39466. P.O. Box 1168. Baltimore, MD 21203. 12 Dudley St., Providence, RI 02901. Camas, WA 98607.

1502 N. 25th St., Melrose Park, IL 60160. 150 E. 42d St., New York, NY 10017.

4th and Parker Sts., Berkeley, CA 94710. 100 Lister Ave., Newark, NJ 07105.

Danville, VA 24540.

450 Schuyler Ave., Kearny, NJ 07032.

4800 S. Richmond St., Chicago, IL 60632.

200 Kellogg St., Jersey City, NJ 07305.

726 King St., Wilmington, DE 19801.

44-27 Purvis St., Long Island City, NY 11101.

1700 S. Mt. Prospect Ave., Des Plaines, IL 60018.

14331 Woodrow Wilson, Detroit, MI 48232.

845 Edgewater Rd., Bronx, NY 10474.

300 Union Commerce Bldg., Cleveland, OH 44114.

300 Union Commerce Bldg., Cleveland, OH 44114.

212 W. Monroe St., Chicago, IL 60606.

P.O. Box 13410, Houston, TX 77019.

P.O. Box 470, Hattiesburg, MS 39401.

8002 53d Ave. W., Everett, WA 98202.

DOM DVC DBC DOW DCC DRW DUN DUP DSC

DIRECTORY OF MANUFACTURERS 201

TABLE 22.-- Synthetic organic chemicals.- Directory of manufacturers , 1965 --Continued

Name of company

Inc-

Dominion Products,

Dover Chemical Co

Dow Badische Chemical Co

Dow Chemical Co

Dow Corning Corp

Drew Chemical Corp-

Frank W. Dunne Co

E. I. duPont de Nemours & Co., Inc- Dye Specialties, Inc

J. S. & W. R. Eakins, Inc

Eastern Color & Chemical Co

Eastman Kodak Co

Tennessee Eastman Co. Div

Texas Eastman Co. Div

Edcan Laboratories

El Paso Natural Gas Products Co- Emery Industries, Inc

Western Div

Emkay Chemical Co

Endo Laboratories, Inc

Enjay Chemical Co

Epoxylite Corp

Escambia Chemical Corp

Ethyl Corp

Ethyl-Dow Chemical Co

Evans Chemetics, Inc

FMC Corp . :

American Viscose Div

Inorganic Chemicals Div-

Niagara Chemical Div— Organic Chemicals Div-

Fabrieolor Manufacturing Corp

Fairmount Chemical Co., Inc

Farac Oil & Chemical Co

Far-Best Corp., 0. L. King Div

Farmers Chemical Association, Inc

Farmer's Chemical Co

Farnow, Inc

Federal Color Laboratories

Felton Chemical Co.,, Inc

Fermco Laboratories, Inc

Ferro Corp., Ferro Chemical Div

Fiberfil, Inc

Fibreboard Paper Products Corp

Filtered Rosin Products Co

Fine Organics, Inc

Firestone Tire & Rubber Co.:

Firestone Plastics Co. Div

Firestone Rubber & Latex Products Co. Div— Firestone Synthetic Rubber & Latex Co. Div-

Fisher Melamine Corp

Fleming Laboratories, Inc

Florasynth Laboratories, Inc

Foote Mineral Co

Foremost Chemical Products Co

Formica Corp

Foster Grant Co., Inc

Foster-Heaton Co

France, Campbell & Darling, Inc

Franklin Chemical Co

Freeman Chemical Corp

Frisch & Co., Inc

Fritzsche Bros., Inc

H. B. Fuller Co

W. P. Fuller Paint Co

Office address

882 3d Ave., Brooklyn, NY 11232. 15th and Davis Sts., Dover, OH 44622. P.O. Box 875, Freeport, TX 77541. Main St., Midland, MI 48640. P.O. Box 592, Midland, MI 48641. 416 Division St., Boonton, NJ 07005. 1007 41st St., Oakland, CA 94608. DuPont Bldg., Wilmington, DE 19898. 26 Journal Sq., Jersey City, N J 07306.

55 Berry St., Brooklyn, NY 11211.

35 Livingston St., Providence, RI 02904.

343 State St., Rochester, NY 14650.

P.O. Box 511, Kingsport, TN 37662.

P.O. Box 2068, Longview, TX 75603.

10 Pine St., S. Norwalk, CT 06856.

P.O. Box 3986, Odessa, TX 79760.

4300 Carew Tower, Cincinnati, OH 45202.

8733 S. Dice Rd., Santa Fe Springs, CA 90670.

319 2d St., Elizabeth, NJ 07206.

1000 Stewart Ave., Garden City, NY 11533.

60 W. 49th St., New York, NY 10020.

P.O. Box 3397, 1428 N. Tyler Ave., S. El Monte, CA 91733.

P.O. Box 467, Pensacola, FL 32502.

100 Park Ave., New York, NY 10017.

Midland, MI 48640.

250 E. 43d St., New York, NY 10017.

1617 John F. Kennedy Blvd., Philadelphia, PA 19103. Sawyer Ave. and River Rd., Tonawanda, NY 14207, and 633

3d Ave., New York, NY 10017. 100 Niagara St., Middleport, NY 14105. 1701 Patapsco Dr., Baltimore, MD 21226, and 633 3d Ave.

New York, NY 10017. 24-1/2 Van Houten St., Paterson, NJ 07505. 117 Blanchard St., Newark, NJ 07105. 147th St. and Indiana Ave., Chicago, IL 60627. 640 Gilman St., Berkeley, CA 94710. P.O. Box 67, Tyner, TN 37392. P.O. Box 591, Kalamazoo, MI 49005. 77 Jacobus Ave., S. Kearny, NJ 07032. 4526 Chickering Ave . , Cincinnati, OH 45232. 599 Johnson Ave., Brooklyn, NY 11237. 4941 S. Racine Ave., Chicago, IL 60609. P.O. Box 349, Bedford, OH 44014. 1701 N. Heidelbach Ave., Evansville, IN 47717. 1550 Powell St., Emeryville, CA 94608. P.O. Box 349, Baxley, GA 31513. 205 Main St., Lodi, NJ 07644.

P.O. Box 699, Pottstown, PA 19464.

1 Firestone Ave., Fall River, MA 02722.

381 W. Wilbeth Rd., Akron, OH 44301.

90 Park Ave., New York, NY 10016.

P.O. Box 10372, 2205 Thrift Rd., charlotte, NC 28201.

900 Van Nest Ave., Bronx, NY 10462.

Route 100, Exton, PA 19341.

P.O. Box 599, Oakland, CA 94604.

Berdan Ave., Wayne, NJ 07470.

289 N. Main St., Leominster, MA 01453.

16 E. 5th St., Paterson, NJ 07524.

N. Michigan Ave., Kenilworth, NJ 07033.

2020 Bruck St., Columbus, OH 43207.

222 E. Main St., Port Washington, WI 53074.

88 E. 11th St., Paterson, NJ 07524.

76 9th Ave., New York, NY 10011.

1150 Eustis St., St. Paul, MN 55108.

450 E. Grand Ave., S. San Francisco, CA 94080.

Gamma Chemical Corp 355 Lexingtorl Ave-) New York m 10017.

Cane s Chemical Works, Inc 535 5th Ave., New York, NY 10017

Geigy Chemical Corp | p.0. box 430, Yonkers, NY 10704.

202 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. Synthetic organic chemicals.- Directory of manufacturers , 1965 — Continued

Name of company

Office address

General Aniline & Film Corp., Dyestuff &

Chemical Div. General Electric Co.:

Chemical Materials Dept

Insulating Materials Dept

Silicone Products Dept

General Foods Corp., Maxwell House Div

General Latex & Chemical Corp

General Mills, Inc

Chemical Div

General Plastics Manufacturing Co

General Tire & Rubber Co., Chemical Div

Geolina Business, Inc

P. D. George Co

Georgia-Pacific Corp.:

Coos Bay Div

Puget Sound Div

Gillette Chemical Co

Gilman Paint & Varnish Co

Givaudan Corp

Glasflex, Inc-r

Glidden Co

Durkee Famous Foods Div

Glyco Chemicals, Inc

B. F. Goodrich Co., B. F. Goodrich Chemical Co Div.

Goodrich-Gulf Chemicals, Inc

Goodyear Tire & Rubber Co

Gordon Chemical Co., Inc

W. R. Grace & Co.:

Dewey & Almy Chemical Div

Hampshire Chemical Div

Hatco Chemical Div

Marco Chemical Div

Nitrogen Products Div

Grain Processing Corp

Great American Plastics Co

Great Lakes Chemical Corp

Great Western Sugar Co

Grow Chemical Corp., Harris Paint Co. Div

Guardsman Chemical Coatings, Inc

Gulf Oil Corp

Chemicals Dept

Perkins Glue Branch

Guth Chemical Co

H & N Chemical Co

Haag Laboratories, Inc

Halby Products Co., Inc

C. P. Hall Co. of Illinois

Hamilton Chemical Corp

Hampden Color & Chemical Co

Hanna Paint Manufacturing Co., Inc

Harshaw Chemical Co

Hartman-Leddon Co

Hart Products Corp

Haveg Industries, Inc., Kesin & Compound Div— ■

Hawkeye Chemical Co

Hercules Powder Co., Inc

Imperial Color & Chemical Dept

Heresite & Chemical Co

Hess Oil & Chemical Corp

Heterochemical Corp

Hexagon Laboratories, Inc

Hodag Chemical Corp

Hoffmann-LaRoche, Inc

Hoffman-Taff, Inc

Holland-Suco Color Co

Hooker Chemical Corp

Durez Plastics Div

RC Div

E. F. Houghton & Co

P.O. Box 12, Linden, NJ 07036.

1 Plastics Ave., Pittsfield, MA 01203. 1 Campbell Rd., Schenectady, NY 12306. Waterford, NY 12188. 1125 Hudson St., Hoboken, NJ 07030. 666 Main St., Cambridge, MA 02139. S. Kensington Rd., Kankakee, IL 60901. Quimby St., Ossining, NY 10562. 3481 S. 35th St., Tacoma, WA 98409. 1708 Englewood Ave., Akron, OH 44309. P.O. Box 1557, Savannah, GA 31402. 5200 N. 2d St., St. Louis, M0 63147.

P.O. Box 869, Coos Bay, OR 97420.

300 Laurel St., Bellingham, WA 98225.

P.O. Box 362, N. Chicago, IL 60064.

W. 8th and Pine Sts., Chattanooga, TN 37401.

125 Delawanna Ave., Delawanna, NJ 07014.

Stirling, NJ 07980.

900 Union Commerce Bldg., Cleveland, OH 44115.

2333 Logan Blvd., Chicago, IL 60647.

417 5th Ave., New York, NY 10016.

3135 Euclid Ave., Cleveland, OH 44137.

1717 E. 9th St., Cleveland, OH 44114. 1144 E. Market St., Akron, OH 44316. 88 Webster St., Worcester, MA 01603.

62 Whittemore Ave., Cambridge, MA 02140.

Poisson Ave., Nashua, NH 03060.

King George Post Rd., P.O. Box 27, Fords, NJ 08863.

1711 W. Elizabeth Ave., Linden, NJ 07036.

P.O. Box 277, 147 Jefferson Ave., Memphis, TN 38101.

1600 Oregon St., Muscatine, IA 52761.

85 Water St., Fitchburg, MA 21420.

P.O. Box 2200, Highway 52 N.W., West Lafayette, IN 47906.

P.O. Box 5308, Terminal Annex, Denver, CO 80217.

1010-26 N. 19th St., Tampa, FA 33601.

1350 Steele Ave. SW., Grand Rapids, MI 49502.

P.O. Drawer 2100, Houston, TX 77001.

610 Dwight Bldg., Kansas City, M0 64105.

632 Cannon Ave., Lansdale, PA 19446.

332 S. Center St., Hillside, IL 60162.

Maltese Dr., Totowa, NJ 07512.

14010 S. Seeley, Blue Island, IL 60406.

P.O. Box 366, Wilmington, DE 19899.

5245 W. 73d St., Chicago, IL 60638.

45 Andrews St., Lowell, MA 01853.

5 Albany St., Springfield, MA 01101.

1313 Windsor Ave., Columbus, OH 43216.

1945 E. 97th St., Cleveland, OH 44106.

60th St. and Woodland Ave., Philadelphia, PA 19143.

1440 Broadway, New York, NY 10018.

900 Greenbank Rd., Wilmington, DE 19808.

P.O. Box 899, Clinton, IA 52733.

Hercules Tower, 910 Market St., Wilmington, DE 19899.

P.O. "Box 231, Glens Falls, NY 12803.

822 S. 14th St., Manitowoc, WI 54220.

State St., Perth Amboy, NJ 08861.

Ill E. Hawthorne Ave., Valley Stream, NY 11582.

3536 Peartree Ave., Bronx, NY 10469.

7247 N. Central Park Ave., Skokie, IL 60076.

324 Kingsland Rd., Nutley, NJ 07110.

P.O. Box 1246 SSS, Springfield, M0 65805.

P.O. Box 2166, 24th St. and 5th Ave., Huntington,

WV 25722. Buffalo Ave. and 47th St., Niagara Falls, NY 14302. Walck Rd., N. Tonawanda, NY 14121. New South Rd., Hicksville, L.I., NY 11802. 303 W. Lehigh Ave., Philadelphia, PA 19133.

DIRECTORY OF MANUFACTURERS TABLE 22.— Synthetic organic chemicals.- Directory of manufacturers, 1965— Continued

203

Name of company

Houston Chemical Corp

Charles L. Huisking & Co., Inc., Clintbrook

Chemical Co. Div.

Humphrey Chemical Co

Philip A. Hunt Chemical Corp., Wayland Chemical

Div.

Husky-Dominion Briquets

Hynson, Westcott & Dunning, Inc

Hysol Corp

LAK LAM GDN

LAS LUR

I.C.I. (Organics), Inc

IRC, Inc

Imperial Chemical Co., Inc

Industrial Biochemicals

Industrial Dyestuff Co

Inland Steel Container Co

Interchemical Corp. :

Color & Chemicals Div

Finishes Div

Organic Chemicals Dept

International Flavors & Fragrances, Inc

International Latex Corp

International Latex & Chemical Corp., Paisley Products Div.

International Minerals & Chemical Corp

Inter-Pacific Resins, Inc

Interplastic Corp., Commercial Resins Div

Ironsides Resins, Inc

Isocyanate Products, Inc

Jefferson Chemical Co., Inc

Jefferson Lake Sulphur Co., Chemical Div-

Jennat Corp

Jennison-Wright Corp

Andrew Jergens Co

Jersey State Chemical Co

Jewel Paint & Varnish Co

S. C. Johnson & Son, Inc

Jones-Blair Paint Co

Jordan Chemical Co

Kaiser Aluminum & Chemical Corp-

Kali Manufacturing Co

Kay-Fries Chemicals, Inc

Kelly-Moore Paint Co

Kelly-Pickering Chemical Corp—

Kendall Refining Co

Kennecott Copper Corp. :

Chino Mines Div

Utah Copper Div

Kenrich Petrochemicals, Inc

Ketona Chemical Corp

Keysor Chemical Co

Keystone Chemurgic Corp

Keystone Color Works, Inc

Kilsdonk Chemical Corp

Office address

Knapp Products, Inc

Knoedler Chemical Co

Kohler-McLister Paint Co

H. Kohnstamm & Co., Inc

Koppers Co., Inc., Tar & Chemical Div-

Koppers Pittsburgh Co

Kyanize Paints, Inc

Lakeside Laboratories, Div. of Colgate-Palmolive

Co.

Lakeway Chemical Co

LaMotte Chemical Products Co

Lancaster Chemical Corp., Gordon Chemicals Co.

Div.

Lasco Industries, Inc

Laurel Soap Manufacturing Co

Lawter Chemicals, Inc., Krumbhaar Resin Div

200 Madison Ave., New York, NY 10016. 417 5th Ave., New York, NY 10016.

Devine St., North Haven, CT 06473. P.O. Box 63, Lincoln, RI 02865.

P.O. Box 380, Cody, WY 82414.

Charles and Chase Sts., Baltimore, MD 21201.

1100 Seneca Ave., Olean, NY 14760.

55 Canal St., Providence, RI 02901.

401 N. Broad St., Philadelphia, PA 19108.

W. 6th and Grass Sts., Shenandoah, IA 51601.

Edison Industrial Center, Edison, NJ 08817.

P.O. Box 4249, Massasoit Ave., E. Providence, RI 02914.

6532 S. Menard Ave., Chicago, IL 60638.

150 Wagaraw Rd., Hawthorne, NJ 07506.

1255 Broad St., Clifton, NJ 07015.

P.O. Box 8, Route 17, Carlstadt, NJ 07072.

521 W. 57th St., New York, NY 10019.

Playtex Park, Dover, DE 19901.

1770 Canalport Ave., Chicago, IL 60616.

5401 Old Orchard Rd., Skokie, IL 60078.

P.O. Box 445, 1602 N. 18th St., Sweet Home, OR 97386.

2015 N.E. Broadway St., Minneapolis, MN 55413.

270 W. Mound St., P.O. Box 1999, Columbus, OH 43216.

900 Wilmington Rd., New Castle, DE 19720..

P.O. Box 53300, Houston, TX 77052.

1914 Haden Rd., Houston, TX 77015.

137 W. 168th St., Gardena, CA 90247.

P.O. Box 4187, Station E, Toledo, OH 43609.

2535 Spring Grove Ave., Cincinnati, OH 45214.

59 Lee Ave., Haledon, NJ 07508.

345 N. Western Ave., Chicago, IL 60612.

1525 Howe St., Racine, WI 53403.

6969 Denton Dr., Dallas, TX 75235.

Barclay Bldg., 1 Belmont Ave., Bala Cynwyd, PA 19004.

P.O. Box 337, Gramercy, LA 70052. 427 E. Mayer St., Philadelphia, PA 19125. 360 Lexington Ave., New York, NY 10017. 1015 Commercial St., San Carlos, CA 94070. 956 Bransten Rd., San Carlos, CA 94070. 77 N. Kendall Ave., Bradford, PA 16701.

Hurley, NM 88043.

P.O. Box 11299, Salt Lake City, UT 84111.

Foot of E. 22d St., Bayonne, NJ 07002.

P.O. Box 6565, Tarrant Branch, Birmingham, AL 35217.

26000 Bouquet Canyon Rd., Saugus, CA 91350.

R.D. 2, Bethlehem, PA 18017.

151 W. Gay Ave., York, PA 17403.

c/o Pfister Chemical Works, P.O. Box 326, Ridgefield, NJ

07657. 180 Hamilton Ave., Lodi, NJ 07644. 651 High St., Lancaster, PA 17604. P.O. Box 546, 1201 Osage St., Denver, CO 80201. 161 Avenue of the Americas, New York, NY 10013. Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. Koppers Bldg., 430 7th Ave., Pittsburgh, PA 15219. 2d and Boston Sts., Everett, MA 02149.

1707 E. North Ave., Milwaukee, WI 53201.

5025 Evanston Ave., Muskegon, MI 49443.

Chestertown, MD 21620.

500 A St., Wilmington, DE 19801.

1561 Chapin Rd., Montebello, CA 90640.

Thompson and Tioga Sts., Philadelphia, PA 19134.

3550 Touhy Ave., Chicago, IL 60645.

204 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. — Synthetic organic chemicals ; Directory of manufacturers , 1965 — Continued

Name of company

Leatex Chemical Co

Lebanon Chemical Corp

Leffingwell Chemical Co

Lehigh Chemical Co

Lehn & Fink Products Corp., Beacon Div

B. L. Lemke & Co., Inc

Leonard Refineries, Inc

Lever Brothers Co

C. Lever Co., Inc

Fred'k H. Levey Co., Inc

Lignin Products Co

ELi Lilly & Co

Lubrizol Corp

George Lueders & Co

M & T Chemicals, Inc

MacKenzie Chemical Works, Inc

Magruder Color Co., Inc

Maher Color & Chemical Co

Mallinckrodt Chemical Works

Manganese Chemical Corp

Marathon Oil Co., Texas Refining Div

Marblette Corp

Marden-Wild Corp

Marlowe-Van Loan Corp

Martin-Marietta Corp. :

Ridgway Color & Chemical Div

Southern Dyestuff Co. Div

Max Marx Color & Chemical Co

Masonite Corp., Alpine Chemical Div

Massachusetts Plastics, Div. of Rexall Chemical Group.

Maumee Chemical Co

Otto B. May, Inc

McCloskey Varnish Co

Medical Chemicals Corp

Merck & Co., Inc

Metalsalts Corp

Metalead Products Corp

Metro- Atlantic, Inc

J. Meyer & Sons, Inc

Michigan Chemical Corp

Midland Industrial Finishes Co

Midwest Plastic Products Co

Miles Laboratories, Inc., Miles Chemical Co. Div Millmaster Onyx Corp. :

Millmaster Chemical Div., Berkeley Chemical Dept.

Onyx Chemical Co. Div

Oxy Chemical Div

Mineral Oil Refining Co

Minnesota Mining & Manufacturing Co

Minnesota Paints, Inc

Miranol Chemical Co., Inc

Mississippi Chemical Corp

Mobay Chemical Co

Molded Fiber Glass Body Co., Resin Div

Mona Industries, Inc

Monochem, Inc

Monsanto Co. :

Bircham Bend Plant ■

Chemstrand Co. Div

Chocolate Bayou Plant

Gering Plastics Dept

Organic Chemical Div

Plastics Div

Western Div

Montrose Chemical Corp. of California

Mooney Chemical Corp

Benjamin Moore & Co

Morton Salt Co., Morton Chemical Co. Div

Motomco, Inc

Office address

2722 N. Hancock St., Philadelphia, PA 19133.

P.O. Box 180, Lebanon, PA 17042.

P.O. Box 1187, Perry Annex, Whittier, CA 90604.

P.O. Box 120, Chestertown, MD 21620.

33 Richdale Ave., Cambridge, MA 02140.

199 Main St., Lodi, NJ 07644.

E. Superior St., Alma, MI 48801.

390 Park Ave., New York, NY 10022.

Howard and Huntington Sts., Philadelphia, PA 19133.

380 Madison Ave., New York NY 10017.

P.O. Box 960, Erie, PA 16512.

740 S. Alabama St., Indianapolis, IN 46206.

29400 Lakeland Blvd., Wickliffe, OH 44092.

427 Washington St., New York, NY 10013.

Woodbridge Rd. and Randolph Ave., Rahway, NJ 07065.

1 Cordello Ave., Central Islip, L. I., NY 11722.

2385 Richmond Terrace, Staten Island, NY 10302.

1700 N. ELston Ave., Chicago, IL 60622.

P.O. Box 5439, St. Louis, M0 63160.

711 Pittman Rd., Baltimore, MD 21236.

P.O. Box 1191, Texas City, TX 77591.

37-31 30th St., Long Island City, NY 11101.

500 Columbia St., Somerville, MA 02143.

1508 Joshua Circle, High Point, NC 27261.

75 Front St., Ridgway, PA 15853. P.O. Box 10098, Charlotte, NC 28201. 192 Coit St., Irvington, NJ 07111. P.O. Box 2392, Gulf port, MS 39503. West Ave., Ludlow, MA 01056.

1310 Expressway Dr., Toledo, OH 43608. 52 Amsterdam St., Newark, NJ 07105. 7600 State Rd., Philadelphia, PA 19136. 4541 W. Grand Ave., Chicago, IL 60639. 126 E. Lincoln Ave., Rahway, NJ 07065.

200 Wagaraw Rd., Hawthorne, NJ 07507-

P.O. Box 11005, 2901 Park Blvd., Palo Alto, CA 94306.

1027 Smith St., Centerdale, RI 02911.

4321 N. 4th St., Philadelphia, PA 19140.

500 N. Bankson St., St. Louis, MI 48880.

P.O. Box 620, E. Water St., Waukegan, IL 60086.

3251 Chicago Rd., Steger, IL 64075.

1127 Myrtle St., Elkhart, IN 46514.

99 Park Ave., New York, NY 10016.

Warren and Morris Sts., Jersey City, NJ 07302.

P.O. Box 28, Hackettstown, NJ 07840.

4401 Park Ave., Dickinson, TX 77539.

2501 Hudson Rd., St. Paul, MN 55119.

1101 S. 3d St., Minneapolis, MN 55415.

277 Coit St., Irvington, NJ 07111-

P.O. Box 388, Yazoo City, MS 39194.

Penn Lincoln Parkway, W. Pittsburgh, PA 15205.

4601 Benefit Ave., Ashtabula, OH 44004.

65 E. 23d St., Paterson, NJ 07524.

P.O. Box 433, Geismar, LA 70734.

190 Grochmal Ave., Indian Orchard, MA 01051.

350 5th Ave., New York, NY 10001.

P.O. Box 711, Alvin, TX 77511.

200 N. 7th St., Kenilworth, NJ 07033.

800 N. Lindbergh Blvd., St. Louis, M0 63166.

730 Worcester St., Springfield, MA 01101; P.O. Box 1311,

Texas City, TX 77591; and River Rd., Addyston, OH 45001. 9229 E. Marginal Way S., Seattle, WA 98108. 500 S. Virgil Ave., Los Angeles, CA 90005. 2301 Scranton Rd., Cleveland, OH 44113. 548 5th Ave., New York, NY 10036. 110 N. Wacker Dr., Chicago, IL 60606. 89 Terminal Ave., Clark, NJ 07066.

DIRECTORY OF MANUFACTURERS TABLE 22. -Synthetic organic chemicals.- Directory of manufacturers , 1 965 --Continued

205

NVF NLC NTB NTC

HUM SHF USI

NTL NPP NPI NSC NES NEP NOT WOI NYC

NIL JDC NIT NON NOP NOC

NEC-

NPV

NRS

LMI

NW

NPC

NOR

NCW

NVT

CMG

OXR OPC ORG OSB OTA OTC OCF 0X0

PLB

AMR

PAN

PNT

PD

PSC

PAT

CCH

PEK

PCH

PEL

PEN

PRP

PAS

PAI

PAR

PER

PET

PTT

PFN

PCW

PFZ

PHR

Name of company

N.V.F. Co

Nalco Chemical Co

National Biochemical Co

National Casein Co

National Dairy Products Corp.:

Humko Products Chemical Div

Sheffield Chemical Co. Div

National Distillers & Chemical Corp. :

A-B Chemical Corp. Div

National Petro Chemical Corp. Div

U.S. Industrial Chemicals Co. Div

National Lead Co

National Plastic Products Co., Inc

National Polychemicals, Inc

National Starch & Chemical Corp

Nease Chemical Co., Inc

Nepera Chemical Co., Inc

Neville Chemical Co

Chlorinated Products Div

New York Color & Chemical Corp., Subsidiary of Tenneco Chemicals, Inc..

Nilok Chemicals, Inc

Nipak, Inc

Nitrin, Inc

A. P. Nonweiler Co

Nopco Chemical Co., Inc

Norac Co., Inc

Norda Essential Oil & Chemical Co.

Norris Paint & Varnish Co

Norse Chemical Corp

North American Chemical Co

Northwestern Chemical Co

Northwest Petrochemical Corp

Norwich Pharmacal Co

Nostrip Chemical Works, Inc

Novamont Corp

Nyanza, Inc

Inc-

Olin Mathieson Chemical Corp-

Agricultural Div

Onyx Oils & Resins, Inc

Orbis Products Corp

Organics, Inc

C. J. Osborn Co

Ottawa Chemical Co

Ott Chemical Co

Owens-Corning Fiberglas Corp- Oxo Chemicals Co

P-L Biochemioals, Inc

Pacific Resins & Chemical Co

Pan American Petroleum Corp

Pantasote Co

Parke, Davis & Co

Passaic Color & Chemical Co

Patent Chemicals, Inc

Pearsall Chemical Co

Peck's Products Co

Peerless Chemical Co ;

Pelron Corp

S. B. Penick & Co

Parsons-Plymouth Div

Pennsalt Chemicals Corp

Pennsylvania Industrial Chemical Corp-

Pennsylvania Refining Co

Perry & Derrick Co

Petroleum Chemicals, Inc

Petro-Tex Chemical Corp

Pfanstiehl Laboratories, Inc

Pfister Chemical Works

Chas. Pfizer & Co., Inc

Pharmachem Corp

Office address

Maryland Ave. and Beech St., Wilmington, DE 19899. 6216 W. 66th PI., Chicago, IL 60638. 3127 W. Lake St., Chicago, IL 60612. 601 W. 80th St., Chicago, IL 60620.

P.O. P.O.

Box 398, Memphis, TN 38101. Box 630, Norwich, NY 13815.

99 Park Ave., New York, NY 10016.

99 Park Ave., New York, NY 10016.

99 Park Ave., New York, NY 10016.

Ill Broadway, New York, NY 10006.

Odenton, MD 21113.

51 Eames St., Wilmington, MA 01887.

750 3d Ave., New York, NY 10017.

P.O. Box 221, State College, PA 16801.

Route 17 and Averill Ave., Harriman, NY 10926.

Neville Island P.O., Pittsburgh, PA 15225.

Neville Island P.O., Pittsburgh, PA 15225.

374 Main St., Belleville, NJ 07109.

Mill St. and N. Transit, Lockport, NY 14094.

301 S. Howard St., Dallas, TX 75221.

P.O. Box 233, Cordova, IL 61242.

P.O. Box 1007, Oshkosh, WI 54901.

60 Park PI., Newark, NJ 07101.

405 S. Motor Ave., Azusa, CA 91703, and 169 Millbank St.

Lodi, NJ 07644. 475 10th Ave., New York, NY 10001. 1710 Front St. NE., Salem, OR 97303. 2121 Norse Ave., Cudahy, WI 53110. 19 S. Canal St., Lawrence, MA 01843. 120 N. Aurora St., W. Chicago, IL 60185. P.O. Box 99, Anacortes, WA 98221. 17 Eaton Ave., Norwich, NY 13815. 182 Liberty Ave., Jamaica, NY 11433. P.O. Box 189, Kenova, WV 25530. Magunco Rd., P.O. Box 349, Ashland, MA 01721.

445 W. 59th St., New York, NY 10019. P.O. Box 991, Little Rock, AR 72203. 95 Broad St., New York, NY 10004. 475 10th Ave., New York, NY 10018. 1724 Greenleaf Ave., Chicago, IL 60628. 1301 W. Blancke St., Linden, NJ 07036. 700 N. Wheeling St., Toledo, OH 43605. 500 Agard Rd., Muskegon, MI 49945. National Bank Bldg., Toledo, OH 43614. 2100 Grant Bldg., Pittsburgh, PA 15219.

1037 W. McKinley Ave., Milwaukee, WI 53205.

3400 13th Ave. SW., Seattle, WA 98134.

P.O. Box 591, Tulsa, OK 74102.

26 Jefferson St., Passaic, NJ 07056.

Foot of Jos. Campau, Detroit, MI 48232.

28-36 Paterson St., Paterson, NJ 07501.

335 McLean Blvd., Paterson, NJ 07504.

P.O. Box 108, Phillipsburg, NJ 08865.

P.O. Box 14508, St. Louis, M0 63178.

3850 Oakman Blvd., Detroit, MI 48204.

7847 W. 47th St., Lyons, IL 60534.

100 Church St., New York, NY 10008.

100 Church St., New York, NY 10008.

3 Penn Center, Philadelphia, PA 19102.

120 State St., P.O. Box 240, Clairton, PA 15025.

Union Bank Bldg., Butler, PA 16001.

2510 Highland Ave., Norwood, OH 45212.

P.O. Box 1522, Lake Charles, LA 70601.

P.O. Box 2584, Houston, TX 77001.

1219 Glen Rock Ave., Waukegan, IL 60086.

P.O. Box 326, Ridgefield, NJ 07657.

235 E. 42d St., New York, NY 10017.

Broad and Wood Sts., Bethlehem, PA 18015.

206 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. — Synthetic organic chemicals; Directory of manufacturers , 1965 — Continued

Name of company

Office address

RGC RH

Phelan-Faust Paint Manufacturing Co., Phelan's Resins & Plastics Div.

Phillips Petroleum Co

Phoenix Oil Co

Pierce Organies, Inc

Pillsbury Co., Chemical Div

Pilot Chemical Co

Pioneer Chemical Works, Inc

Pioneer Plastics Corp., Chemical Div

Pitt-Consol Chemical Co

Pittsburgh Plate Glass Co

Plastics Engineering Co

Plastics Manufacturing Co

Plastics Materials, Inc

Plumb Chemical Corp

Polak's Frutal Works

Polychemical Laboratories, Inc

Polymer Corp

Polymer Industries, Inc

Poly Resins

Polyrez Co., Inc

Polyvinyl Chemicals, Inc

Pontiac Refining Corp

Pratt & Lambert, Inc

Premier Malt Products, Inc

Procter & Gamble Co., Procter & Gamble Manufac- turing Co. Div.

Proctor Chemical Co., Inc

Productol Chemical Co., Inc

Products Research & Chemical Corp

Publicker Industries, Inc

Pure Oil Co

Purex Corp., Ltd

Quaker Chemical Corp

Quaker Oats Co

K. J. Quinn&Co., Inc

R.S.A. Corp

Rachelle Laboratories, Inc

Raybestos-Manhattan, Inc., Raybestos Div

Rayette, Inc

Red Spot Paint & Varnish Co., Inc

Refined Products Co ■

Reheis Chemical Co., Div. of Armour Pharma- ceutical Co.

Reichhold Chemicals, Inc

Varcum Chemical Div

Reilly Tar & Chemical Corp

Reliance Universal, Inc

Remington Arms Co., Inc

Renroh Resins

Retzloff Chemical Co

Rexall Chemical Co

Rexall Chemical Co. - Kearny

Rezolin, Inc

Rhodia, Inc

Richardson Co

Richardson Polymers Div

Richfield Oil Corp

Riker Laboratories, Div. of Rexall Drug &

Chemical Co.

Rinshed-Mason Co

F. Ritter & Co

Ritter Chemical Co., Inc

Ritter Pfaudler Corp., Ionac Chemical Co. Div--

Riverdale Chemical Co

Roberts Chemicals, Inc

Rock Hill Printing & Finishing Co

Roehr Chemicals, Inc

Rogers Corp

Rohm & Haas Co

Oak St. and Buff Rd., P.O. Box 189, Burlington, IA 52602.

Bartlesville, OK 74003.

9505 Cassius Ave., Cleveland, OH 44-105.

P.O. Box 98, Rockford, IL 61105.

1152 Pillsbury Bldg., Minneapolis, MN 55402.

11756 Burke St., Santa Fe Springs, CA 90670.

940 N. Delaware Ave., Philadelphia, PA 19123.

Pionite Rd., Auburn, ME 04210.

191 Doremus Ave., Newark, NJ 07105.

I Gateway Center, Pittsburgh, PA 15222. 1607 Geele Ave., Sheboygan, WT 53082. 2700 S. Westmoreland, Dallas, TX 75224. New South Rd., Hicksville, NY 11801. 4837 James St., Philadelphia, PA 19137. 33 Sprague Ave., Middletown, NY 10940. 490 Hunts Point Ave., New York, NY 10059. 2120 Fairmont Ave., Reading, PA 19603. Viaduct Rd., Springdale, CT 06879. 11655 Wicks St., Sun Valley, CA 91352. P.O. Box 320, Woodbury, NJ 08096.

26 Howley St., Peabody, MA 01960.

P.O. Box 1581, Corpus Christi, TX 78403.

75 Tonawanda St., Buffalo, NY 14207.

917 W. Juneau Ave., Milwaukee, WI 53201.

Ivorydale Technical Center, Rm. 2S25, Cincinnati,

OH 45217. P.O. Box 399, Salisbury, NC 28144. 615 S. Flower St., Los Angeles, CA 90017. 2919 Empire Ave., Burbank, CA 91504. 1429 Walnut St., Philadelphia, PA 19102. 200 E. Gulf Rd., Palatine, IL 60067. 5101 Clark Ave., Lakewood, CA 90712.

Elm, Lime, and Sandy Sts., Conshohocken, PA 19428. Merchandise Mart Plaza, Chicago, IL 60654. 195 Canal St., Maiden, MA 02148.

690 Saw Mill River Rd., Ardsley, NY 10502.

P.O. Box 9095, 700 Henry Ford Ave., Long Beach, CA 90810.

75 E. Main St., Stratford, CT 06601.

261 E. 5th St., St. Paul, MN 55101.

110 Main St., Evansville, IN 47708.

624 Schuyler Ave., Lyndhurst, NJ 07071.

325 Snyder Ave., Berkeley Heights, NJ 07922.

525 N. Broadway, White Plains, NY 10602. Niagara Falls, NY 14302.

II S. Meridan St., Indianapolis, IN 46204.

4730 Crittenden Dr., P.O. Box 21067, Louisville, KY

40221, and 6901 Cavalcade, Houston, TX 77001. 939 Barnum Ave., Bridgeport, CT 06602. P.O. Box 1191, New Bern, NC 28560. P.O. Box 45296, Houston, TX 77045. 8480 Beverly Blvd., Los Angeles, CA 90048. 1106 Harrison Ave., Kearny, NJ 07029. 1651 18th St., Santa Monica, CA 90404. 600 Madison Ave., New York, NY 10022. 27th Ave. and Lake St., Melrose Park, IL 60160. 345 Morgan Lane, West Haven, CT 06516. 555 S. Flower St., Los Angeles, CA 90054. 19901 Nordhoff St., Northridge, CA 91326.

5935 Milford Ave., Detroit, MI 48210.

4001 Goodwin Ave., Los Angeles, CA 90039.

403 W. Main St., Amsterdam, NY 12010.

Birmingham, NJ 08011.

220 E. 17th St., Chicago Heights, IL 60411.

P.O. Box 546, Nitro, WV 25143.

Rock Hill, SC 29730.

52-20 37th St., Long Island City, NY 11101.

Main St., Rogers, CT 06263.

222 W. Washington Sq., Philadelphia, PA 19105.

DIRECTORY OF MANUFACTURERS TABLE 22. — Synthetic organic chemicals.- Directory of manufacturers , 1965— Continued

207

Name of company

Roma Chemical Corp

Rosenberg Bros. & Co

Rowland Products, Inc

Royce Chemical Co

Rozilda Laboratories, Inc

Ruberoid Co

St. Regis Paper Co., Lake States Yeast & Chemical Div.

Salsbury Laboratories

Sandoz, Inc

Dyestuff Div., Pigment Dept

Sartomer Resins, Inc

Schaefer Varnish Co., Inc

Schenectady Chemicals, Inc

Scher Bros., Inc

R. P. Scherer Corp

Schering Corp

Scholler Bros., Inc

Seaboard Chemicals, Inc

G. D. Searle & Co

Seidlitz Paint & Varnish Co

Sekisui Plastics Corp

Selney Co., Inc

Seydel-Woolley & Co., Inc

Shamrock Oil & Gas Corp

Shanco Plastics & Chemicals, Inc

Shell Oil Co

Shell Chemical Co. Div

Shepherd Chemical Co

Sherwin-Williams Co

Shulton, Inc

George F. Siddall Co., Inc

Signal Oil & Gas Co., Houston Div

Simpson Timber Co

Sinclair Koppers Chemical Co

Sinclair-Koppers Co

Sinclair Paint Co

Sinclair Petrochemicals, Inc

Sinclair Refining Co

James B. Sipe & Co

Skelly Oil Co

G. Frederick Smith Chemical Co

Smith, Kline & French Laboratories

Socony Mobil Oil Co., Inc.:

Mobil Chemical Co. Div

Mobil Oil Co. Div

Sohio Chemical Co. & Solar Nitrogen Chemicals,

Inc.

Solar Chemical Corp

Soluol Chemical Co., Inc

Solvent Chemical Co., Inc

Sonford Chemical Co

Sonoco Products Co

Souhegan Wood Products, Inc

Sou-Tex Chemical Co., Inc

Southeastern Mhesives Co

Southeast Polymers, Inc

Southern Nitrogen Co,, Inc

Southern Sizing Co

Spaulding Fibre Co., Inc

E. R. Squibb & Sons Div. of Olin Mathieson

Chemical Corp. A. E. Staley Manufacturing Co

UBS Chemical Co. Div

Stamford Chemical Co

Standard Brands, Inc., Clinton Corn Processing

Co. Div.

Standard Chemical Products, Inc

Standard Chlorine Chemical Co., Inc

Standard Oil Co. of California, Chevron

Chemical Co.

Office address

900 Passaic Ave., E. Newark, NJ 07029. 100 Landing Ave., Smithtown, NY 11787. 34 Fairview Lane, Kensington, CT 06037. Carlton Hill P.O., E. Rutherford, NJ 07073. 814 Madison St., Hoboken, NJ 07030. S. Bound Brook, NJ 08880.

603 W. Davenport St., Rhinelander, WI 54501.

500 Gilbert St., Charles City, IA 50616.

P.O. Box 357, Fair Lawn, NJ 07410.

61-63 Van Dam St., New York, NY 10013.

P.O. Box 56, Essington, PA 19029.

1350 S. 15th St., Louisville, KY 40210.

Congress St. and 10th Ave., Schenectady, NY 12301.

P.O. Box 538, Allwood Station, Clifton, NJ 07012.

9425 Grinnell Ave., Detroit, MI 48213.

1011 Morris Ave., Union, NJ 07083.

Collins and Westmoreland Sts., Philadelphia, PA 19134.

30 Foster St., Salem, MA 01970.

P.O. Box 5110, Chicago, IL 60680.

18th and Garfield Sts., Kansas City, M0 64141.

666 Dietrich Ave., Hazelton, PA 18201.

65 9th St., Bldg. 15, Brooklyn, NY 11215.

748 Rice St. NW., Atlanta, GA 30318.

P.O. Box 631, Amarillo, TX 79105.

2716 Kenmore Ave., Tonawanda, NY 14150.

113 W. 52d St., New York, NY 10019.

113 W. 52d St., New York, NY 10019.

2803 Highland Ave., Cincinnati, OH 45212.

101 Prospect Ave. NW., Cleveland, OH 44101.

697 Route 46, Clifton, NJ 07015.

P.O. Box 925, Spartanburg, SC 29301.

P.O. Box 5008, Harrisburg Station, Houston, TX 77012.

2301 N. Columbia Blvd., Portland, OR 97217.

P.O. Box 5536, Houston, TX 77012.

900 Koppers Bldg., Pittsburgh, PA 15219.

3960 E. Washington Blvd., Los Angeles, CA 90023.

600 5th Ave., New York, NY 10020.

600 5th Ave., New York, NY 10020.

P.O. Box 8010, Pittsburgh, PA 15216.

P.O. Box 1650, Tulsa, OK 74102.

867 McKinley Ave . , Columbus , OH 43223 .

1500 Spring Garden St., Philadelphia, PA 19101.

150 E. 42d St., New York, NY 10017.

612 S. Flower St., Los Angeles, CA 90054, and P.O.

Box 3311, Beaumont, TX 77704. 621 Republic Bldg., Cleveland, OH 44115.

Solar Park, Leominster, MA 01453.

Green Hill and Market Sts., W. Warwick, RI 02893.

341 Commercial St., Maiden, MA 02148.

412 Main St., Houston, TX 77002.

Harts ville, SC 29550.

Wilton, NH 03086.

E. Catawba Ave., Mount Holly, NC 28120.

P.O. Box 791, Lenoir, NC 28645.

P.O. Box 309, Chattanooga, TN 37401.

P.O. Box 246, Savannah, GA 31402.

P.O. Box 391, East Point, GA 30044.

310 Wheeler St., Tonawanda, NY 14150.

745 5th Ave., New York, NY 10022.

N. 22d and Eldorado Sts., Decatur, IL 62525.

491 Main St., Cambridge, MA 02142.

45 Jefferson St., P.O. Box 1131, Stamford, CT 06940.

1251 Beaver Channel Parkway, Clinton, IA 52733.

1301 Jefferson St., Hoboken, NJ 07030. 1015 Belleville Turnpike, Kearny, NJ 07032. 200 Bush St., San Francisco, CA 94120.

208 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. — Synthetic organic chemicals .- Directory of manufacturers , 1 965 --Continued

Name of company

Standard Oil Co. of Ohio

Standard Pyroxoloid Corp

Stange Co

Stauf f er Chemical Co . :

Calhio Chemicals Div

Industrial Chemical Div

Specialty Chemical Div

Stein, Hall & Co., Inc

Stepan Chemical Co.:

Industrial Chemicals Div. , Millsdale Works—

Maywood Div

Sterling Drug, Inc.:

Glenbrook Laboratories Div

Hilton-Davis Chemical Co. Div

Salvo Chemical Div

Thomasset Colors Div

Winthrop Laboratories Div

Stresen-Reuter, Inc

Sucro-Chemical Div. of Colonial Sugars Co

Sullivan Varnish Co

Summit Chemical Products Corp

Sun Chemical Corp., Chemical Products Div

Sun Chemical Corp-, Pigments Div

Sunkist Growers, Inc ' —

Sun Oil Co

SunOlin Chemical Co

Sunray DX Oil Co

Suntide Refining Co

Swift & Co

Synco Resins, Inc

Syntex Corp., Arapahoe Chemicals Div

Synthetic Chemicals, Inc

Synthetic Products Co

Synthron, Inc

Synvar Corp

Tanatex Chemical Corp

Charles S. Tanner Co

Taylor Corp

Tennant Development Corp., Chemical Div

Tenneco Chemicals, Inc

Berkshire Color Div

Cal/Ink Div

Newport Div

Nixon-Baldwin Div

Nuodex Div

Tenneco Manufacturing Co

Tenneco Plastics Div

Tenneco Oil Co

Tennessee Copper Co

Texaco, Inc •

Texas Alkyls, Inc

Texas-U.S. Chemical Co

Tex Chem Co

Texize Chemicals, Inc

Textilana Corp

Thiokol Chemical Corp

Thomason Industries, Inc., Southern Resin Div

Thompson Chemical Co

Thompson-Hayward Chemical Co --

Ticonderoga Chemical Corp

Tidewater Oil Co

Toms River Chemical Corp

Tousey Varnish Co

Trancoa Chemical Corp

Arthur C. Trask Co

Triangle Chemical Co

Trojan Powder Co

Troy Chemical Co

Trylon Chemical Corp

Joseph Turner & Co

Office address

Midland Bldg., Cleveland, OH 44115. 85 Pleasant St., Leominster, MA 01453. 342 N. Western Ave., Chicago, IL 60612.

380 Madison Ave., New York, NY 10017. 380 Madison Ave., New York, NY 10017. 380 Madison Ave., New York, NY 10017. 605 3d Ave., New York, NY 10016.

Elwood, IL 60421. 100 W. Hunter Ave.

Maywood, NJ 07607.

90 Park Ave., New York, NY 10016.

2235 Langdon Farm Rd., Cincinnati, OH 45237.

Military Rd., Rothschild, WI 54474.

120 Lister Ave., Newark, NJ 07105.

90 Park Ave., New York, NY 10016.

400 W. Roosevelt Ave., Bensenville, IL 60106.

P.O. Drawer G, Gramercy, LA 70052.

410 N. Hart St., Chicago, IL 60622.

11 William St., Belleville, NJ 07109.

Wood River Junction, RI 02894.

441 Tompkins Ave., Staten Island, NY 10305.

720 E. Sunkist St., Ontario, CA 91764.

1608 Walnut St., Philadelphia, PA 19103.

P.O. Box F, Claymont, DE 19703.

P.O. Box 2039, Tulsa, OK 74102.

P.O. Box 2608, Corpus Christi, TX 78403.

115 W. Jackson Blvd., Chicago, IL 60604.

32 Henry St., Bethel, CT 06801.

2855 Walnut St., Boulder, CO 80301.

335 McLean Blvd., Paterson, NJ 07504.

1636 Wayside Rd., Cleveland, OH 44112.

Ryan Ave., Ashton, RI 02805.

726 King St., Wilmington, DE 19801.

P.O. Box 388, Lyndhurst, NJ 07071.

450 Furman Hall Rd., Greensville, SC 29608.

Valley Forge, PA 19481.

100 Park Ave., New York, NY 10017.

300 E. 42d St., New York, NY 10017.

12th and Bern Sts., Reading, PA 19604.

711 Camelia St., Berkeley, CA 94710.

P.O. Box 911, Pensacola, FA 32502.

Nixon, NJ 08818.

1 Virginia St., Newark, NJ 07207.

P.O. Box 2511, Houston, TX 77001.

P.O. Box 38, East Brunswick, NJ 08816.

P.O. Box 2511, Houston, TX 77001.

Copperhill, TN 37317.

P.O. Box 52332, Houston, TX 77052.

P.O. Box 600, Deer Park, TX 77536.

P.O. Box 667, Port Neches, TX 77651.

20-21 Wagaraw Rd., Fair Lawn, NJ 07410.

P.O. Box 368, Greenville, SC 29602.

12607 Cerise Ave., Hawthorne, CA 90250.

P.O. Box 27, Bristol, PA 19007.

P.O. Drawer 1600, Fayetteville, NC 28301.

90 Mendor Ave., Pawtucket, RI 02862.

5200 Speaker Rd., Kansas City, KA 66106.

Marguerite Ave., Leominster, MA 01453.

Delaware City, DE 19706.

Route 37, P.O. Box 71, Toms River, NJ 08753.

135 W. Lake St., North Lake, IL 60164.

312-326 Ash St., Reading, MA 01867.

327 S. LaSalle St., Chicago, IL 60604.

206 Lower Elm St., P.O. Box 4528, Macon, GA 31208.

17 N. 7th St., Allentown, PA 18105.

338 Wilson Ave., Newark, NJ 07105.

P.O. Box 5101, Station B, Greenville, SC 29606.

P.O. Box 88, Ridgefield, NJ 07451.

DIRECTORY OF MANUFACTURERS TABLE 22. -Synthetic organic chemicals.- Directory of manufacturers , 1965— Continued

209

Name of company

Office address

USS Chemicals Div. of U.S. Steel Corp

Paul Uhlich & Co., Inc

Ungerer & Co

Union Bag-Camp Paper Corp., Nelio Chemical Div-- Union Carbide Corp.:

Chemicals Div

Plastics Div

Silicones Div

Union Oil Co. of California

Union Starch & Refining Co., Inc

United Carbon Co

United Chemical Corp. of Norwood

United Chemical Products Corp

United Cork Companies

United Oil Manufacturing Co

U.S. Borax Research Corp

U.S. Oil Co

U.S. Peroxygen Corp

United States Pipe & Foundry Co

U.S. Plastic & Chemical Corp

United States Plywood Corp., California Div., Shasta Operations.

United States Rubber Co., Chemical Div

Universal Chemicals Corp

Universal Detergents, Inc. & Petrochemicals Co--

Universal Oil Products Co

Chemical Div

Upjohn Co

Carwin Organic Chemicals

Utah Resin Co., Inc

Valchem

Valentine Sugars, Inc., Valite Div-

Van De Mark Chemical Co

Vanderbilt Chemical Corp

Van Dyk & Co., Inc

Varney Chemical Corp

Velsicol Chemical Corp

Ventron Corp., Metal Hydrides Div

Vermi lye-Bell

Verona-Pharma Chemical Corp

Vickers Refining Co., Inc

Vineland Chemical Co

Virginia Chemicals, Inc

Vistron Corp., Silmar Div

Vitamins, Inc

Vita-Var Corp., Div. of Textron Industries, Inc- Vulcan Materials Co., Frontier Chemical Co. Div-

Wallace & Tiernan, Inc.:

Harchem Div

Lucidol Div

Warner-Jenkinson Manufacturing Co

Washburn-Purex Co

Washine Chemical Corp

West Coast Adhesives Co

Westinghouse Electric Corp., Insulating

Materials Div.

Weston Chemical Corp

West Virginia Pulp & Paper Co., Polychemicals

Div.

Weyerhaeuser Co., Wood Products Div

White & Bagley Co

White & Hodges, Inc

White Laboratories, Inc

Whitmoyer Laboratories, Inc

Whittemore -Wright Co., Inc

Wica Chemicals, Inc

Wilmot & Cassidy, Inc

Rm. 2104, Grant Bldg., Pittsburgh, PA 15219. 90 West St., New York, NY 10006. 161 Avenue of the Americas, New York, NY 10013. P.O. Box 6170, Jacksonville, FA 32205.

270 Park Ave., New York, NY 10017.

270 Park Ave . , New York, NY 10017.

270 Park Ave., New York, NY 10017.

461 S. Boylston St., Los Angeles, CA 90017.

301 Washington St., Columbus, IK 47201.

P.O. Box 149, Baytown, TX 77520.

P.O. Box 327, Endicott St., Norwood, MA 02062.

York and Colgate Sts . , Jersey City, NJ 07302 .

50 Central Ave., Kearny, NJ 07032.

2d and Cascade Sts., Erie, PA 16512.

3075 Wilshire Blvd., Los Angeles, CA 90005.

P.O. Box 4228, E. Providence, RI 02914.

850 Morton Ave., Richmond, CA 94804.

3300 1st Ave. N., Birmingham, AL 35202.

122 E. Railroad Ave., W. Haverstraw, NY 10993.

P.O. Box 1688, Redding, CA 96002.

Naugatuck, CT 06771.

1224 Mundon Rd., P.O. Box 1224, Ashtos, RI 02865.

1825 E. Spring St., Long Beach, CA 90806.

30 Algonquin Rd., Des Plaines, IL 60018.

State Highway 17, E. Rutherford, NJ 07073.

7000 Portage Rd., Kalamazoo, MI 49001.

Sackett Point Rd., North Haven, CT 06473.

604-605 Kearns Bldg., Salt Lake City, UT 84101.

1407 Broadway, New York, NY 10018.

726 Whitney Bldg., New Orleans, LA 70130.

N. Transit Rd., Lockport, NY 14094.

33 Winfield St., E. Norwalk, CT 06855.

11 William St., Belleville, NJ 07109.

2001 Afton Rd., Janesville, WI 53545.

330 E. Ohio St., Chicago, IL 60611 and 4902 Central Ave.

Chattanooga, TN 37410. 12-24 Congress St., Beverly, MA 01915. 21707 Bothell Way, Bothell, WA 98011. P.O. Box 385, Union, NJ 07083. P.O. Box 2240, Wichita, KS 67201. W. Wheat Rd., Vineland, NJ 08360. West Norfolk, VA 23703.

12335 S. Van Ness Ave., Hawthorne, CA 90250. 809 W. 58th St., Chicago, IL 60621. 177 Oakwood Ave., Orange, NJ 07050. P.O. Box 545, Wichita, KS 67201.

25 Main St., Belleville, NJ 07109. 1740 Military Rd., Buffalo, NY 14240. 2526 Baldwin St., St. Louis, 113 63106. 2244 Elston Ave., Chicago, IL 60614. 165 Main St., Lodi, NJ 07644. 11104 NW. Front Ave., Portland, OR 97231. Trafford, PA 15085.

104 E. 40th St., Suite 107, New York, NY 10016. P.O. Box 5207, N. Charleston, SC 29406.

118 S. Palmetto St., MarshfieM, WI 54449. P.O. Box 1171, Worcester, MA 01601. 576 Lawrence St., Lowell, MA 01852. Galloping Hill Rd., Kenilworth, NJ 07033. P.O. Box 97, Myerstown, PA 17067. 62 Alford St., Boston, MA 02129. P.O. Box 506, Charlotte, NC 28201. 108 Provost St., Brooklyn, NY 11222.

210 SYNTHETIC ORGANIC CHEMICALS, 1965

TABLE 22. — Synthetic organic chemicals: Directory of manufacturers , 1965 — Continued

Code

Name of company

Office address

WIL

WM

BLA

WTC

SON

WCC

WAW

WOD

WRC

WON

WBC

WYN

YAW

Wilson & Co., Inc. :

4-221 S. Western Blvd., Chicago, IL 60609.

Snyder Ave. and Swanson St., Philadelphia, PA 19148.

5050 Edgewood Ct., P.O. Box B, Jacksonville, FA 52203.

P.O. Box 305, Paramus, NJ 07652.

277 Park Ave., New York, NY 10017.

555 S. Flower St., Los Angeles, CA 90017.

108 Spring St., Everett, MA 02149.

P.O. Box 3545, Eugene, OR 97402.

Park PI. E., Wood Ridge, NJ 07075.

176 Sunnyside Ave., Woonsocket, RI 02895.

Route 9, Freehold, NJ 07728.

1609 Biddle Ave., Wyandotte, MI 48192.

2731 Boston St., Baltimore, MD 21224.

Witco Chemical Co., Inc

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W. A. Wood Co

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Woonsocket Color & Chemical Co

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Young Aniline Works, Inc

APPENDIX

U.S. Imports of Benzenoid Intermediates and Finished Benzenoid Products

Table 23 summarizes, for 1964 and 1965, U.S. imports of benzenoid chemicals and products entered under the Tariff Schedules of the United States (TSUS), schedule 4, part 1, subparts B and C. The data, which were obtained by analyzing invoices covering imports through all U.S. customs districts, are given in detail in a separate report of the Tariff Commission.1

In 1965, general imports of benzenoid intermediates entered under schedule 4, part IB, comprised 642 items with a total weight of 38.0 million pounds and an invoice value of $19.5 million. In 1964, imports consisted of 651 items with a total weight of 18.8 million pounds and an invoice value of $14.4 million. About half of the benzenoid chemicals and products imported in 1965 were declared to be "competitive" (duty based on "American selling price"). In 1965, imports of these products from Canada amounted to 34 percent of the total; imports from that country amounted to 13 million pounds, compared with 2.0 million pounds in 1964. In 1965, im- ports from Italy amounted to 8.1 million pounds, compared with 1.6 million pounds in 1964. Im- ports from West Germany amounted to 7.2 million pounds, compared with 7.6 million pounds in 1964. Imports from Japan totaled 3.3 million pounds in 1965, compared with 2.2 million pounds in 1964; and imports from the United Kingdom amounted to 2.2 million pounds in both 1965 and 1964. In 1965, sizable quantities of intermediates were also imported from Switzerland (1.6 mil- lion pounds), France (1.2 million pounds), and Sweden (0.8 million pounds).

TABLE 23. — Benzenoid intermediates and finished benzenoid products ; U.S. general imports,

classified by use, 1964 and 1965

Quantity

Invoice value

Invoice

value

Intermediates1

Finished benzenoid products, total

Dyes, total

Acid

Azoic dyes

Azoic components:

Fast color bases

Fast color salts

Naphthol AS and its derivatives- Basic

Direct

Disperse

Fiber-reactive

Fluorescent brightening agents

Mordant

Solvent ■.

Sulfur

Vat

All other

Benzenoid pigments (toners and lakes)

Medicinals and pharmaceuticals

Flavor and perfume materials

All other

1,000 pounds 18,789

23,682

10,096

2,093

14

311

113

901

1,018

1,015

900

416

151

292

128

11

1.000 dollars 14,410

34,670

16,261

1,000 pounds 37,975

31,941

2,713 2 20 684 3,127 1,613 8,162

1,128 9,764 2,311 5,206

12,276

1,808

22

416

185

1,093

1,227

931

1,880

652

229

221

168

37

3,374

2 33

797

3,408

1,908

13,552

1,000 dollars

19,483

45,425

20,505

1,510

12,551

2,522

8,337

1 Includes small quantities of rubber-processing chemicals.

2 Includes ingrain dyes.

3 Includes organic pesticides and agricultural chemicals, plasticizers, surface -active agents, and textile assistants.

Source: Compiled from the records of the U.S. Bureau of Customs.

1 Imports of Benzenoid Chemicals and Products, 1965, TC Publication 183, 1966 [processed].

211

212 SYNTHETIC ORGANIC CHEMICALS, 1965

The most important intermediates imported in 1965 were adipic acid, polyalkylbenzene, p-nitrotoluene, 3-hydroxy- 2-naphthoic acid (B. O. N. )> cyclohexanone, acetoacetanilide, Gamma acid, anthraquinone, 2-(morpholinothio)benzothiazole, and sodium naphthionate. In 1965, imports of adipic acid amounted to 13. 7 million pounds, compared with 1. 9 million pounds in 1964, and came almost entirely from Canada. Imports of polyalkylbenzene in 1965 totaled 6. 1 million pounds, compared with 725,000 pounds in 1964, and all came from Italy. In 1965, imports of p-nitrotoluene, which came principally from Sweden and Germany, totaled 922, 000 pounds; im- ports of B.O.N. , which came from Italy, West Germany, and Japan, totaled 873,000 pounds; imports of cyclohexanone (699, 000 pounds) all came from Italy; imports of acetoacetanilide (679, 000 pounds) came principally from Switzerland; imports of Gamma acid (595, 000 pounds) came from Japan, West Germany, and Italy; imports of anthraquinone (468,000 pounds) came from the United Kingdom, Japan, and West Germany; imports of 2-(morpholinothio)benzothiazole (415, 000 pounds) all came from the United Kingdom; and imports of sodium naphthionate (326, 000 pounds) all came from Japan.

Imports in 1965 of all finished benzenoid chemicals and products that are dutiable under part 1C comprised Z, 223 items, with a total weight of 31.9 million pounds and an invoice value of $45.4 million. In 1964, imports consisted of 2, 292 items, with a total weight of 23. 7 million pounds and an invoice value of $34. 7 million. In 1965, benzenoid dyes were the most important group of finished benzenoid products imported. Imports of dyes amounted to $20. 5 million (invoice value), or 45.2 percent of the value of all imports under part 1C. In 1964, imports of dyes amounted to $16. 3 million (invoice value), or 47. 0 percent of the value of all imports under part 1C.

Imports of medicinals and pharmaceuticals were the next most important group of products entered under part 1C in 1965. In 1965, imports of medicinals and pharmaceuticals were valued at $12. 6 million (invoice value), or 27. 8 percent of total imports under part 1C. In 1964, imports of medicinals and pharmaceuticals were valued at $9. 8 million, or 28. 2 percent of total imports under part 1C. In 1965, imports of benzenoid pigments (toners and lakes) were valued at $1. 5 million, compared with $1. 1 million in 1964. Imports of benzenoid flavor and perfume materials in 1965 ($2. 5 million) we re 8 percent more than in 1964. Imports in 1965 of other benzenoid products entered under part 1C (chiefly synthetic resins and pesticides) were valued at $8. 3 million, compared with $5. 2 million in 1964.

REPORTS OF THE UNITED STATES TARIFF COMMISSION ON THE OPERATION OF THE TRADE AGREEMENTS PROGRAM

*Operation of the Trade Agreements Program, June 1934 to April 1948 (Rept. No. 160, 2d ser., 1949) : Part I. Summary

Part II. History of the Trade Agreements Program Part III. Trade-Agreement Concessions Granted by the United States Part IV. Trade- Agreement Concessions Obtained by the United States Part V. Effects of the Trade Agreements Program on United States Trade

*Operation of the Trade Agreements Program : Second Report, April 1948-March 1949 (Rept. No.

163, 2d ser., 1950)

*Operation of the Trade Agreements Program : Third Report, April 1949-June 1950 (Rept. No. 172,

2d ser., 1951) *Operation of the Trade Agreements Program : Fourth Report, July 1950-June 1951 (Rept. No. 174,

2d ser., 1952) *Operation of the Trade Agreements Program: Fifth Report, July 1951-June 1952 (Rept. No. 191,

2d ser., 1954) *Operation of the Trade Agreements Program: Sixth Report, July 1952- June 1953 (Rept. No. 193,

2d ser., 1954) *Operation of the Trade Agreements Program : Seventh Report, July 1953- June 1954 (Rept. No. 195,

2d ser., 1955) *Operation of the Trade Agreements Program: Eighth Report, July 1954-June 1955 (Rept. No. 197,

2d ser., 1956) *Operation of the Trade Agreements Program : Ninth Report, July 1955-June 1956 (Rept. No. 199,

2d ser., 1957) ♦Operation of the Trade Agreements Program: 10th Report, July 1956-June 1957 (Rept. No. 202,

2d ser., 1959) ♦Operation of the Trade Agreements Program: 11th Report, July 1957- June 1958 (Rept. No. 204,

2d ser., 1959) ♦Operation of the Trade Agreements Program : 12th Report, July 1958-June 1959 (TC Publication

9, 1961) ♦Operation of the Trade Agreements Program : 13th Report, July 1959-June 1960 (TC Publication

51, 1962) Operation of the Trade Agreements Program: 14th Report, July 1960-June 1962 (TC Publication

120, 1964), 350 Operation of the Trade Agreements Program : 15th Report, July 1962-June 1963 (TC Publication

147, 1965), 350 Operation of the Trade Agreements Program : 16th Report, July 1963-June 1964 (TC Publication

164, 1966), 300

NOTE.— The reports preceded by an asterisk (*) are out of print. Those followed by a price may be purchased from the Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. See inside front cover for additional reports. All U.S. Tariff Commission reports reproduced by the Government Printing Office may be consulted in the official depository libraries throughout the United States.

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