*1 ii ■■i^j!>«tv;^ < ^ o • CO U- — o z CO >- < C/) z _i a: o CO u — > hO o 1- o -1 : 3 o - o •» > n uj J >- CL -J CO 1- CO H O _1 CO J> co> > o -M CO — < O NJ o 3: < — Q- U) X o < — M < CO— I -J oj U > CD < CB < O -J CO O LU < q3 -I V CO -1 ic: — o o < — _I CT) TRAVELS ^^^^ IN THE TWO SICILIES, AKO SOME PARTS OIF THE APENNINES. Tranflated frdhi the Original Italian of the ABBE LAZZARO SPALLANZANI, ■^nefeffor- Royal of Natural Hiftory in the Univerfity of Pavia, an4 Superintendant of the Imperial Mufeum in that City j Fellow of the R.oyal Society of London ; and Member of the Academies of Pruffia, Stockholm, Gotiingen, Turin, Padua, &c. &c. In four volumes. — with eleven plates. VOL. III. LONDON: PRINTED FOR G. G. AND J. ROBINSOs!> PATERNOSTE R-R O \V, 1798, CONTENTS OF THE THIRD VOLUME. Fiagc Chap. XVL — ObSERFJTIONS made in the Interior Parts of Li' pari^ and fever al of its Mountains I Chap. XVII. — Felicuda — — 90 Chap. XVIII. — Alicuda — — 124 Chap. XIX. — Ohfervations which have an immediate Relation with the Volcani%ation of the Eolian Ifles — Enquiries relative to the Origin of Bafaltes — • — 152 Chap. IV cotjtents. Page Chap. XX. — DigreJJhn relative to the different Volcanic Producfions ef the Euganean Mountains — . — 216 Rejle^ions and Corollaries — — ^o i Chap, XXI. — ILxperimental Efiqtiiries relative to the Nature of the Gafis ofVolcanos, and the Caufes of their Eruptions — — — 317 Chap. XXII. — Difcovery that various volcanic ProduBs contain Muriatic Acid — Enquiry how this Acid has been produced y and mixed with them ' — — — 386' TRAVELS TRAVELS IN THE TWO SICILIES, Sec. CHAP. XVI. LIPARI. PART THE SECOND. OBSERVATIONS MADE IN THE INTERIOR PARTS OF LIPARI, AND SEVERAL OF ITS MOUNTAINS. Extremely irregular appearance ftf this ijland — No charaBerifed crater d'lfcover-' able in it — ConjeBiire that the Monte San Angeloy and the Monte ddla Guardia^ the VOL. III. B higheji ( 2 ) h'lghejl mountains in Lipart, were prO" duced by two dij}'m& volcanos — Effloref" cences of muriate of ammoniac (fal ammO' niac) in two caverns near the plain called La Valle — Curious volcanic breccia — 'The volcanic tufa which^ on one fide^ covers the whole mountain of the celebrated Stoves (or vapour baths) ofLipari^ has every ap^ pearance of having beeft an earthy cur' rent ; and is remarkable for containing true Ugfieous coal — Conje&ural enquiries into the origin of this — The road that leads from the town to the floves formed^ in a great meafure^ of tufa corroded by the rain-water '-^Various bodies obfervable within this corroded tufa — Detached pieces of enamel^ which include many fmall bulbous bodies that appear to be ^gartiets — Camparifon between thefe and the garnets of Vefuvius — E?iamel of the Liparefe garnets^ which has for its bafe ihe horn-ftone — Detached lavas in the road leading to the Jloves — Volcanic chry^ ■Coliies in a lava with a horn-Jione bafe — Thefe chryfolites compared with thofe of 4 ILtna — ( 3 ) Etna^^Large pieces of red porphyry which do not fee fn to have fuffered fifion — None ofthefe bodies difpofed in currents ; "whence it is probable that they have been throivn into the air by fome volcano — A fpaciouS plain of tufa rendered cultivable^ fituatcd beyotid the Monte della Stufe, ivhich affords numerous pieces of the fneji and purejl glafs found in Lipari — Local ori^ gin of this glafs — Bed of pumices on the ebctejffve current of tufa before men- tioned— Stoves of Lipari defcribed — Re- mains of confagrations of fulphur under" them^ and in their envirojis — Prodigious number of lavas decompofed by the a£iion of fulphur eons acid vapours — Oxyde of pure iron depoftted on fome of thefe lavas '—Variety of colours which they preferit to the eye — Their decompofition ufually in the inverfe proportion of the depth of their majfes — Widen freed from the decompoft" tion which renders it difficult to afcertain their nature^ they are ufually found of a petrofiliceous bafe — This decompoftion an ohjlacle to their fufton in the Jurnace-^^ B 3 Expli* ( 4 ) Kxpl'icatioti of the caufe of this change — Sulphates of Ihne^ var'ioifly coloured^ and adhering to the decompofed lavas — Iroji^ oxydated^ and modifcd in various manners y the caife of the dijferent colours of the decompofed lavas ^ andfulphates of lime — Difcovery of fever al amorphous and cryf- tallifed zeolites ?iear the ftoves — J^Uy 'which they form ivith mineral acids — ILmit bright fafoes ivhen on the point of meltings and fwell confiderahly on their aEiual fufion — 'Terms of co7nparifon be tween thefe %eoUtts and thofe of other countries — Their produSiion not by the dry but the humid ivay — Though the zeolites of fever al volcanized countries are probably formed within the fea^ this does not feem to be the origin of thofe of Lipari — ///- fiances of zeolites produced in frefJj water — Springs of hot water "which fupply the baths of Lipari — Another prodigious accu - mulation of decompofed lavas ^ and fid- phures of lime^ on the fouthern fide of the if and — Perhaps there is no volcanizedcomi- try in Europe where the fulphur eons fnnes iffuing ( s ) ijfii'mg from fuhterranean conf,agrations are fo extenfive as at Llpari — Vitrifications of CampoBiaiico^ and the Monte delLi Cafag- 7ia^ 'which are found attached to thofe of the Monte dellc Stufe^ the Monte San An-- gelo, and other places — Proofs that aimofi two-thirds of Lipari, which tfland is iiine^ teen miles and a hj.lf in circumference^ are compofed of vitr if cations — "The mate?'ials of which this ifland is compofed^ prin- cipally derived from the petroflex^ fi^^' fpars in the mafsy and horn-fones, in part fimply ffed by fubterraneous combufionsy and in a fill greater part vitrified- — Not- withfanding the immenfe accu?nulations of this vitrifcation^ an extraordinary intenfity of heat not neceffary to be fuppofed— An exception in the pumices orighiating from granite — Few notices left us by ancient authors relative to the fres of Lipari ; though we hnois) from indubitable au- thorities^ that both the if and and the city exifed before the Trojan war — "No erup- tion in this ifland defcribed by Hifory — Feeble fres, vifible by night, alone ob- B 3 ferved ( 6 ) ferved in ancient times — This ijland^ the produce offuhterraneaii conflagration, had arrived at its greatefl dimenfwns^ before it was noticed by any writer* X O acquire a juft knowledge of the in- terior part of a mountainous vulcanized country, the beft method, as it appears to me, is firft to afcend the higheft mountain, and, after having examined the fummit, to turn the eye downward, and obferve the chain of fmaller nnountains that furround it. We may thus, at one glance, difcover the form of thefe inferior mountains, their in- terchangeable connection, and the relations which they bear to each other, and to the pri- mary mountain, with other important ob- jedls, which, had we firft afcended one of the Jower eminences, we fhould not have been able to afcertain with equal precifion and clearnefs. After, therefore, having made refearches, with the grcateft diligence, around the fhore of JLiparlj when I proceeded, according to jny ( 7 ) my original intention, to explore, likewife, the Internal parts of the Ifland ; I, firft, af- Cended to the fummit of the Monte San Angelo, fituated to the north of the city of LIpari ; this being the higheft mountain in the ifland. Here the whole of the ifland prefented itfelf, at once, to my view, and I could perceive that, far from having a coni- cal figure, fuch as Is that of Stromboli, and in a certain manner of Vulcano, it is compofed of groups of broken and half- deftroyed mountains, confufedly heaped to- gether; which give it a moft irregular appearance. It is evident that the volcanic fires have raged in many places, and that, from their too great proximity to each other, they have not been able to form thofe diftind: cones which are fo obfervable in Vefuvius and on Etna. But the matters ejeded by the fuperior volcanos, pouring upon thofe which iflued from the lower, have produced in every part confu- fion and diforder. From the fummit of Etna we may difcover a multitude of fub- jacent craters, well charaderifed ; but from B 4 that ( 8 ) t"hat of San Angel o I could not perceive one. There are, indeed, many openings and hollows to be feen, which once, per- haps, were fiery mouths ; but none of thefe cavities have at prefent the figure of an inverted tunnel, pofTibly becaufe they have been in part filled up and deftroyed by fub- fequent eruptions, or by time. M. Dolomieu obferved at the fummit of this mountain a circular plain, furrounded by eminences fhelving towards the infide, which he imagined might be the remains of an ancient crater. This conjedlure, after a careful examination of the fpot, does not appear to me improbable. The fame natu- ralifl likewife fuppofes that this mountain, the height of which is nearly a mile above the fea, was the firft that was formed in the ifland, through which the volcano burfl forth, and which ferved as a bafe and fup- port for the other mountains that were thrown up afterv/ards. This opinion is extremely plaufible ; but the fad: may like- wife be, in my opinion, that this mountain, at ( 9 ) at the time of its produdion, or very foon. afterwards, had for its companion the Monte della Guardia, which looks towards the fouth, and of which I have before fpoken ; both becaufe the latter is feparated from the former, and becaufe it is little in- ferior to it in height. From the ideas fug- geited by a view of the places themfelves, I conceive it not improbable that thefe two mountains, which rife fo much higher than the reft, have been produced by two dif- tind volcanos, and were the firft that emerged from the fca, forming then two fmall iflands, which afterwards, enlarging their bafe, united into one ; for it is well known that other volcanic iHands originally confifted of feveral parts, wduch afterwards were joined. To thefe two mountains fubfequent eruptions made new additions, until at length the whole of the iiland of Lipari was produced, which, from the ero- iion of the rains and the fea, is now cer- ■'tainly lefs than it once was. From Monte San Angelo, I pafled to the Monte ( 10 ) Monte (iella Guardia, which on the fide to- wards the fea prefents only fteep and rug- ged precipices of lava, and, confequently, is deprived of all vegetation and verdure j but on the land fide, which is oppolite in one part to the city, it is formed with gentle de- clivities, and covered with vineyards ; for, as its foil is tufaceous, it lefs refifts cultiva- tion than any other volcanic product. While ftanding on the fummit I was ftill more confirmed in the opinion, that this mountain is not an accefTary to, or prolon- gation of, that of San Angelo ; but that it forms a whole of itfelf, and may be called primary equally with the other, from the diftance between them, and the wide valley, running from eafl to weft, by which they are feparated. Having vifited thefe two mountains, which are the loftieft in the ifland, I pro- ceeded next to examine the lefler emic nences, and found additional confirmation of what I have already obferved ; I mean, that thefe eminences have entirely loft the true { " ) true form of volcanic craters, fo much have the matters ejected from them interfeded each other, and confufedly intermixed. The long and unkriown feries of years that has elapfed fince thefe eruptions, muft, no doubt, have contributed to increafe the con- fufion. Excepting, therefore, fome few flat places, and practicable declivities, which the inhabitants have rendered cultivable by great labour, Lipari is a ruinous pile of horrid precipices, rugged cliffs, and enor-» mous mafles ; and there is no fummlt, or projecting part of a mountain, which does not exhibit manifeft indications of its fu- ture fall and deftrudion. The materials of which thefe ruins are formed are pumices, enamels, and glafles, which I ihall not de« fcribe, becaufe they are partly the fame, and partly extremely analogous to thofe of which I have already given the defcription. Some of the natives, by the accounts they gave me, excited my curiofity to vilit a ca- vern fituated in a fniall plain called La Valle, about a quarter of a mik to the weft of ( 12 ) of the city. This cavern has its mouth In a rock of decompofed lava, and a man may walk Into it to the diftance of fifty paces. Its fides are covered with efflorefcences of muriate of ammoniac, as were, likewife, thofe of another fmaller cavern In the fame rock. This fait muft have been formed by fublimation, having been reduced to va- pour by fubterraneous fires, and thus at- tached itfelf to the fides of thefe two ca- verns, as it is found attached in many other volcanic places ; but of thefe fires and am- moniacal vapours no traces whatever now exift. In this fliort excurfion I found by the way a volcanic breccia, which, on account of the heterogeneous fubftances it contained, it would be improper to pafs without notice. It is found in large ifolated pieces, but I was unable to difcover from what vein it derived its origin. Its principal fubftance is an earthy lava, of a blueifli grey, a coarfe grain, and little hardnefs. In this were in- clofed the following bodies : Firrt, ( 13 ) Firft, fragments of two kinds of lava ; the one black, of a fcaly fradure, and which moved the magnetic needle at tlie diftance of two lines : the other of a grey ground, a very rough furface, an unequal frad:ure, which gave fparks with fteel, and contained fmall plates of feltfpar. Both were of the horn-ftone bafe, and emitted a ftrong argil- laceous odour. Secondly, feveral pieces of vitreous lava, of a very beautiful colour, between a green and a blue : by its fmoothnefs, clear frac- ture, its afped:, and want of hardnefs, it re- fembles the pitch-ftone, or pitch-blende. Thirdly, numerous fmall pieces of a ci- nereous compact pumice. Fourthlyj pieces of a whitillx feml-tranf- parent glafs. Fifthly, fmall pieces of a colourlefs glafs, refembling in tranfparency factitious glafs. The largefl piece was fourteen lines in length, ( '4 ) length, and eight in breadth, and wasj like the others, buried in the breccia. Thefe five fpecies of volcanic produdions were certainly not natural to the fubftance of the lava ; for their fradures and angles are very vifible, and by carefully breaking the lava they may be extracted entire. We muft therefore conclude that they were ab- forbed and inclofed in the lava when it was in motion, and thus were confolidated into one body. In making thefe obfervations a doubt fuggefted itfelf. Though to the naked eye, and likewife to the touch, the vitreous lava appears perfedly fmooth, yet, when viewed with a lens of a ftrong magnifying power, its furface appeared full of very minute fif- fures. At leaft, if this was not obfervable in all, it was in feveral pieces of both thefe kinds of glafs, I therefore conjectured, that when thefe fubftances were in an ignited ftate, a current of water might have paiTed over them j or that they fuddenly came in conta^ ( «5 ) contad with the cold air j unlefs we rather choofe to fuppofe that thefe fiflures were produced, when thefe vitreous bodies, in a frigid ftate, were fuddenly enveloped in the fiery torrent. But the celebrated Stoves of Lipari appear to be the objed which moft excites the curiofity of travellers ; I could not, there- fore, omit to vifit them. I muft, however, confefs, that the road which led to them afforded me more inftrudive obje(^s than the ftoves themfelves. Thefe ftoves He to the weft of the city, at the diftance of four miles, and fomewhat beyond the fummit of a mountain, w^hich, after thofe of San Angelo and della Guar- dia, is one of the higheft in the ifland. The road I went was that which leads immedi- ately from the city to the ftoves, and the only one which can be travelled without great difficulty. It is in a great degree the ^ork of rain waters, which have made a deep excavation in an immenfe mafs of tufa. ( i6 ) tufa. In more than one place, in this work i . I have fpoken of volcanic tufas, but almoft always incidentally. The prefent fpecies of this fubftance requires to be treated of fome- what more at length. At the beginning of this work, when fpeaking of the volcanic tufas of Pofilipo, I faid, and endeavoured to prove, that it was probable they were formed by ilimy eruptions ; though I would not deny that afhes, fand, and other fubtile matters ejected by volcanos, and penetrated either by the rain-waters or thofe of the fea when they covered the bafes of the burning moun- tains, have been confolidated into fome tufas*. The tufa of Lipari, of which I now fpeak, has every appearance of having been, an earthy current. It begins at about a hun- dred paces from the city, and continues, without interruption, to beyond the fum- mit of the Monte della Stufe, or Mountain of the Stoves. This mountdn, like mofl of the others, varies confiderably in its dif- » See Chap. II. ferent ( I? ) ferent parts, in one place prefentlng gentle declivities, and in another fteep and rugged defcents ; here plains nearly level, and there precipices almoft perpendicular. The tufa with which it is covered, takes exad:ly the fame courfe ; and fometimes curves, and, as it were, waves on the furface : nor does it in the lead differ in its finuofities and wind- ings, from the moft completely chara([le- rifed currents of lava, which it likewife re- fembles by being difpofed in beds lying one over the other, as appears in thofe places which have been moft corroded by the rain. I therefore was of opinion, that this tufa had been a ftream, if I may ufe the ex- preffion, of flimy fubftances, that had flow- ed down the mountain ; as examples are not wanting of fimilar eruptions, produced in the humid way, in the mountains Vefu- vius, Etna, and Hecla. But here a difficulty prefented itfelf in oppofuion to this hypothecs. Had this part of the mountain been inundated by a torrent of water ifluing from the earth, VOL. III. C when ( IS ) 'when its violence had ceafed, the more heavy bodies mufl have fubfided to the bottom in obedience to the law of gravity, the lefs heavy have remained above them, and the lighteft have occupied the higheft place; which, however, is not the fad:, fmce, as we fhall fee, at a fmall depth within the tufa, are found large mafles of lavas, enamels, and glafles. But it does not ap~ pear to me improbable that thefe mafles may have been thrown out from fome burning mouth, after the hardening of the tufa, within which they have not penetrated deep. Not only the pbfition and winding eourfe of this tufa over the back and fides of the mountain fufficiently prove that it once flowed : its very nature is a ftrong confir- mation of this fad. It is not an aggrega- tion of aflies and fand ; a mixture of frag- ments of Ihoerls, feltfpars, and lavas de- compofed, and rendered earthy, and faften- ed together by the adion of the water, be- coming fo hard as to be cut into pieces pro- per ( 19 ) per for building, as is the cafe with many other tufas ; but it is merely an argillaceous earth, refembling, from its foftnefs, the hardened mud of rivers. Its colour is a dull grey, its ftru6ture fomevvhat granular, and fo yielding that it may be crumbled and pulverized between the fingers. It is light, adheres flightly to the infide of the lip, emits a feeble argillaceous odour, and, w-hen immerfed in wacer, greedily imbibes it in every part. In the furnace it firft acquired a reddifh brown colour, and afterwards the black co- lour of iron. It became fo hard that it gave fparks with fteel, without, however, vitrifying, except that its furface affumed a kind of vitreous varnifli. The depth of this tufa is different in different parts of the mountain. In fome places it is feveral feet deep, in others but a few, and in others there is fo great a quan- tity of it that, notwithilanding the excava- tions made in it by the rains, I was unable C2 . t© ( 20 ) to afcertain Its depth. But in every place where I could difcover the bottom, I oh- ' ferved that it reded on a bed of pumices, partly pulverized, and partly in detached pieces approaching to the globofe form. They belong to the clafs of the lighteft of thefe fubftances. It appear?, therefore, in- dubitable that thefe pumices had been thrown out of the burning mouth of fome volcano, before the flowing of the tufaceous current. This tufa prefented a very unexpected phenomenon. On breaking it, its fradures exhibited frnall black particles, which were diftinClly recognized to be true coal, from t their blacknefs, lightnefs, drynefs, the faci- lity with which they broke, and their fmall degree of hardnefs. Some of them, like- wife, when expofed to fire in the open air, fumed, and became red hot ; others emitted a little flame. The latter had not been perfed.ly reduced to coal, as the fibrous parts of the wood were Itill to be feen. Thefe coals were fmall cylinders from two or ( 21 ) or three lines in length to twelve or four- teen, and of proportional thicknefs. They appeared to Iiave appertained to branches of trees or fhrubs 5 they are buried in the tuf^ at various depths, and are found, though thinly fcattered, through its whole extent. This fad:, never before, to my knowledge, obferved by others in volcanic tufas, might induce us to imagine that the two methods, the humid and the dry, had here been com- bined ; and that the watery Hime, when it flowed down the mountain, had been pene-^ trated by the fire in fuch a manner that it had inflamed, and converted into coal, the vegetables it met with in its way. This ex-- planation is certainly not free from diffi- culties, as the reader, no doubt, already perceives ; it thereiore may appear more probable that the earthy inundation had involved, and carried with itfelf, thefe car- bonaceous fubftances, which exifled pre- vious to its eruption, and which derived their origin from a fhower of ignited matter leaving burned, but not entirely confumed, C 3 thQ ( 22 ) ~ the few plants which feebly vegetated on the declivities of the mountain. It has been already faid, that the rapid defcent of the rain-v/aters on that part of the mountain which leads to the ftoves, has corroded the tufa to a great depth ; and it is in the middle of thefe corrofions that we meet with various volcanic bodies, which, together with others lying in the public road, merit well to be defcribed. Firft, we find pieces of enamel of every fize, which, though they are fmooth with- out, when broken, have, within, an angular fradure. Their colour is a pale blue, they have no great brilliancy, nor are they very hard, as they fly in pieces when flruck againft the fteel. The caufe of the want of hardnefs in this enamel, may be afcribed to the filTures, of which it is full ; and thefe, perhaps, are to be attributed to the pieces of enamel being red-hot when they fell into the tufa not yet dry. The felt- fpars it contains have the fame cracks, and probably from the fame caufe. In ( n ) In the fame places is found another kind of enamel containing a great number of fmall bodies, which 1 will not abfolutely affirm to be garnets, becaufe 1 was not able to analyze them in the humid way ; but their external charadters, together with the proofs furnilhed by the dry way, almoft induce me to conclude them fuch. In all my volcanic refearches I have never met with any fimilar. In general they have a bulbous figure, and are of a blackifh colour, which in fome inclines to a red. Their furface is fmooth and fhining, their recent fradures lamellar, perfectly vitreous, and will cut glafs. The largeft are about three lines and a half in thicknefs, and are opake ; the fmalleft, about the third part of a line, and are femi-tranfparent. They give fparks with fteel, and melt in the furnace into- a black and fcoriaceous enamel. Thefe cha- raders, taken together, certainly give them a great refemblance to garnets : I fhall not therefore hefitate to clafs them with that fpecies of ftone ; as their not being cryftalr lized is of little importance, fmce we know that there are alfo amorphous garnets. C 4 While ( H ) While employed ia the examination of thefe ftones, I refolved to compare tliem with the Veruvian garnets j tor, in myexcur- fion to that volcano, I had colledled feveral different fpecies of them on Monte Somma, which is the ancient Vefuvius. I made le- veral experiments on four of thefe, of which the following is the refult. The firft fpecies is found in a lava with a horn-flone bafe, of a yellowifh grey colour, an unequal furface, and of a confiftence little different from earthy, from the great alteration it has undergone ; not, as far as appears, from fulphureous exhalations, but from the acftion of the atmofphere. The garnets it contains have likewife fuffered injury, having loft a part of their native luftre, and being eafily broken or crumbled to pieces from the multitude of minute fif- fures and cracks in them. They, however, retain fomewhat of the vitreous chara<51:er. Their colour is between a vvhite and a grey. At firft view their figi-ire appears peife^lly globular ; but on extrading them from the lloncj their matrix, (which may eafily be done,) ( 25 ) done,) and attentively examining them, they are found to have facets, though it is not poffible to afcertain the number of them, as piany of the angles have been defaced by time. I Ihall only obferve, that having broken one of thefe garnets into two equal parts, the perimeter of each half was o£tagonal. This fradture at the fame time fhewed the texture of the garnet, which is compofed of very thin circular leaves. Thefe garnets are of different lizes, from four lines and a half to one fixth of a line. The furnace reduces the matrix-lava to a compadl enamel of the colour of pitch ; but it leaves the garnets untouched, which only become fomewhat whiter, more vitre- ous, and more hard. The blacknefs of the enamel being a contrafh to the whitenefs of the garnets, a great number of the latter be- come confpicuous, which before were not vifible in the lava; and, notwithftanding their extreme minutenefs, they remain un- injured by the fire. The ( 26 ) The garnets of the fecond fpecics are contained in a lava which has for its bafe a foft horn-ftone. They are larger than the former, and entirely opake. They are white as fnow, and more brilliant in their fractures than the preceding. Many of them are of a round figure, and manifeftly (hew a cryftal- lization in various facets ; which, however, it is impoffible to number, as they break in pieces if we attempt to extrad: them from the lava. Many others of them are of very irregular forms. Several of this fecond fpecies of garnets inclofe within them fmall prifmatic fhoerls, of the colour and luftre of afphaltum, which probably pre-exifled completely formed, and were taken into the moifture from which the garnet derived its origin. Thefe garnets are, llkewife, infufible in the furnace, though the lava is converted into a porous fcoria. The third kind is ftrongly infixed In a heavy ( 27 ) heavy lava, which alfo has for its bafe the ' horn-ftone, is of an iron-bl;ick, compad:, but not fufficiently hard to give fparks with fteel. The garnets, which are of a yellow- iih white colour, and fome of them four lines in diameter, for the moft part have clefts or fiflures, but in fuch a manner that in the recent fradlures the furface refembles around polypetalous flower. The furnace melted the lava, but not the garnets, which only acquired the red colour of copper. The garnets of the fourth and laft fpecies have four-and-twenty facets, and are femi- tranfparent, white, and vitreous. Their ma- trix is a compadl lava of a horn-ftone bafe, which emits an argillaceous odour. In the the furnace it changes into a black ena- mellar product, but the garnets remain un- touched. On comparing thefe refults with others before detailed, we fhall find that the ftruc- ture { 28 ) ture of the Vefuvian garnets, (o far as it is vU treous and lamellar, is fimilar to that of thofe of Lipari j but that, when expofed to the fire, a difference is found between thefe two fiones, the one eafily melting in the furnace, and the other proving refradtory. Finding, therefore, that thefe four fpecies of garnets were infufible in the furnace, though continued in it for feveral days, I had recourfe to oxygenous gas (or dephlo- gifticated air}, by the adion of which they all melted, though flov ly. When the ma- trix lava flowed like common glafs, the fmali pieces of garnet within it remained unchanged ; but at length fufed, though without incorporating with the lava, fo a3 to form a homogeneous whole. Thofe chemifts and naturalifts, who, be- fore me, have made experiments with fire on the Vefuvian garnets, have defcribed re- fuks fimilar to thofe I obferved. Bergmann fays thefe garnets melt with the blow- pipe alone, but a vehement fire is necef- fary. ( «9 ) fary *. Sauflure tells us, that a fpotted lava (lave a ocil de perdr'ix) which he found on Monte Somma, acquh-ed, after fufion, a black vitrified ground, but that the polyhedrous grains of this lava remained unchanged in the moft violent fire ; and by polyhedrous grains it is evident that he means what I and others have called garnets f . With refpe^fi to the adion of oxygenous gas upon them, we may refer to Ehrmann, in his work on the Air of Fire. " The white opake garnet of " Vefuvius," fays this writer, " differs from " garnets properly fo called, in this, that it " melts with extreme difficulty (with the " affiflance of oxygenous gas is here to be " underftood), and at length, after continual " ebullition, becomes a mafs perfedly fimi- " lar to quartz, even in its fradure, and " which crackles in like manner between " the teeth." This kind of ebullition I have obferved in the four varieties of garnets above men- * De ProducElis Vulcanlcis. t Voyage dans les Alpes, Tom. I. doned, { 30 ) tioncd, when they were in a ftate of fufion* The firfl: and third, likewife, produced two finall mafles refembling quartz, but thofe of the fecond and fourth variety were fpongy. It is very poiTibU that this author only made his experiments on one fpecies. Some learned naturalifts are of opinion that the garnets of Vefuvius are improperly fo denominated ; firft, becaufe they con- tain no iron ; fecondly, becaufe they fufe with difficulty ; and, thirdly, becaufe they differ in the proportionate qualities of their conftituent parts from thofe of true garnets. Thefe reafons, hov/ever, do not appear to me fufficient to exclude them from being clatled with this kind of ftones. It is true, that iron is ufually contained in garnets; but it is not elTential to them ; as has been obferved by Bergmann, who, in tranfparent garnets, found only y^ parts of this metal. The abfence of iron, probably, therefore, renders them fo difficult to fufe. With re- fped: to their conftituent parts, the Swedifli chemift (Bergmann) has obferved, that the principal ( 3' ) principal of thefe is filex, the next alumine, and that which is lead of all in quantity, lime. This analyfis agrees with that made by Achard on fome of the pureft Bohemian garnets ; and fuch a proportion of the con- flituent principles is fufhciently fuitable to that of the garnets of Vefuvius, in which Berg- mann found about ^^ parts of filex, 39 of alumine, and 6 of lime. And though the proportion of the filex to the alumine is not entirely the fame in both thefe ftones, the difference is not fo great,, in my opinion, as to induce us to confider them as two diftind fpecies ; as will appear by compar- ing the numbers ^^ and 39, which exprefs the quantities of filex and alumine in the Vefuvian garnets, with the numbers 48 and 30, denoting thofe of the fame two earths, in the Bohemian garnets, analyzed by the before-cited chemift of Berlin (Achard). To return for a moment to the garnets of Lipari: thefe do notfo tenacioufly adhere to their bafe as we almoft always find the felt- fpars and fhoerls ; but, like other garnets, are z mpl anted C 32 } Implanted in it in fuch a manner that they may be eafily detached without breaking, leaving the exa6t impreffion of their figure in the enamel. This enamel, which is compa61:, heavy, and of a grey cinereous colour, is found in detached pieces, both in the road and in the tufa ; and is the firft production which prefents itfelf, after leav- ing the city to proceed towards the ftoves. Continuing our journey ftill further along this road, we find in it, and likewife within the tufa, very curious mixtures of a white argillaceous earth and black enamel ; both of which are fo mingled and kneaded toge- ther, that we can fcarcely find a quantity of this earth of the fize of a pea, which does not contain feveral particles of this enamel ; and very few, indeed, are the pieces of enamel that contain none of this earth. It has an earthy odour, and adheres to the tongue. In the fame fituations where this peculiar mixture is found, we likewife meet with an enamel containing garnets, fimilar to thofe above ( r. ) above-mentioned, but larger, and more ap- proaching to a globular figure. It is re- markable that this enamel, in fome places, forms one whole with fome pieces of lava of a horn-ftone bafe, which alfo contains garnets. I {hall briefly diftinguifh four fpecies of lava, each of a horn-ftone bafe, which are met with, in detached pieces, on the road to the Stoves. The firft has a fibrous fraGure, the colour of iron, fome appearance of porofity, fuiE- cient hardnefs to give fparks with fteel, and the power to move the magnetic needle at the diftance of a line and a quarter. It emits an earthy odour, and contains felt- fpars. The fecond is of a black-grey colour, and, though compact, rather foft. Almoft one half of it confiftsof rhomboidal felt- fpars. VOL. III. D The ( 34 ) The third only differs from the feconcJ by being fomewhat more compaift, harder, and containing fewer feltfpars. The fourth, which in folidity, weight, and hardnefs, exceeds the three preceding, has a black ferrugineous colotrc, an earthy -fradure, adheres llightly to the tongue, and emits the ufual argillaceous odour. It moves the magnetic needle at the diftance of half a line. AH thefc four kinds of lavas are change ) under certain angles, their colours become much more lively and bright. Many of them- are amorphous, butfome are quadran- gular prifms. Their furface, In the fradtures, fhlnes with a glafly brilliancy, and is fome- times fmooth, and fometlmes rough, accord- ing as the plates of which the chryfolites are compofed may have been broken. The fmall fragments of them are angular and femi-tranfparent. Thefe chryfolites give fparks with fteel, and cut glafs nearly like rock- cry ftal. The largeft are not lefs than three lines and a half in length, but the fmalleft can fcarcely be difcerned by the naked eye. They are fo firmly Infixed in the lava, that only fragments of them can be detached. The fire of the furnace, and that of the blow-pipe, not only will not fufe thefe mi- nute Hones, but are unable to injure them either in their^colours or texture. Oxyge- nous gas (dephlogifllcated air) alone dlfco- lours them, and melts them into a globule, of a white colour, but without brilliancy. Though ( 31 ) Though it was not known till the pre- fent time that Lipari afforded volcanic chry- folites, they had been before found in other volcanized countries, as in Vivarais and Ve- lay, by M, Faujas, and on Mount Etna by M. Dolomieu. But on comparing their chry- folites with mine, I find certain differences and refeaiblances, which it will be proper to enumerate. The chryfolitcs obferved and defcribed by M. Faujas, when examined with the lens, are found to be compofed of an aggre- gate of arenaceous grains, more or lefs fine, and more or lefs adherent ; fcabrous, irre- gular, and fometimes forming crufts and fmail fandy fcales ; but, for the mod part, having the appearance of angular fragments united by infertion into each other. The chyfolites of Lipari have nothing of this nature in their ftrudure. I broke fe- veral of them, and examined their frag- ments with the microfcope -, but they never appeared to me granular, but always fmooth D 3 and ( 38 ) and glaiTy. The moft minute parts of thefc chryfolites exhibited the fame afped: they prefented when whole. I muft not omit to mention another dif* ference of importance, which is, that the chryfolites of Lipari are only a few lines i^ length, whereas thofe defcribed by M. Eau- jas are fometimes feveral pounds in weight, They agree, however, with mine in their infufibility in an extremely adive fire ; for thofe on which he made his experiments refilled the fire of common furnaces, how- ever violent and continued it might be, an4 could not be reduced to a ftate of fufion bu^ by the aid of oxygenous gas. The colours of both are fcmetlmes the fame. 1 fay fometimes, for M. Faujas in- forms us, that feveral of his chryfolites were only of one colour i a green, or topaz-yel-r low. The traits of refemblance and difference between ( 39 ) between the Liparefe and Etnean chryfo- lites will be feen by comparing the defcrip- tion I have given of the former with what M. Dolomieu fays of the latter, in the work I have frequently cited. He tells us, that fome of the chryfolites he found there are amorphous, others cryftallized in tetra- gonal or hexagonal prifms, fometimes with an hexagonal pyramid ; that their fracture is partly concholdal, and partly lamellar; that they are harder than quartz ; that they are more or lefs tranfparent ; that their co- lour is a greenifli yellow, with various tinges, and that they are fufible in a ftrong fire. He does not give their fize, but they cannot be large ; both becaufe he calls them grains^ and becaufe thofe which I obferved in fome lavas of Etna were very minute. I have defignedly called the chryfolites of Lipari, volcajiic chryfolites, not merely be- caufe they are found within a lava, but to preferve a diftindion between them and the gem of that name ; fmce I know that fome refpedable authors are of opinion, that the D 4 volcanic ( 4° ) volcanic ftones which, from their greenifh yellow colour, and other circumftances, re- femble that gem, and therefore are called chryfolltes by the Volcanifts, differ from them entirely in their component parts, and feveral of their external characters. To this opinion I can make no objedicn, though, in defcriblng thefe ftones, I have adopted the name by which they are ufual- ly known. It mud be obferved, however, that fome of their properties fhew they can- .not be clafied as fhoerls, among which fome naturalifts generally place the chryfolites of volcanos. It remains like wife to fpeak of a ftone which was the laft of the produds that of- fered themfelves to my obfervation, as I proceeded along the declivity of the moun- tain leading to the Stoves. This ftone is a porphyry, the bafe of which is the petrofilex, containing feltfpars with feveral faces, and brilliant in the frac- tures, and blackifh irregular fhoerls. The bafe ( 41 ) bafe has the red colour of brick. It is found in detached mafTes, fome of which weigh feveral thoufand pounds. It is corn- pad:, and fcaly in the fractures. The pieces broken from it are irregular ; the tlitnnell are tranfparent at the edges ; and they give fparks moderately with fteel. The colour of the bafe has given the feltfpars a reddiih tinge, as we fee in certain oriental porphy- ries. But has this porphyry fufFered fufion, or is it in its natural ftate, and, at mofl, cal- cined when it was ejeded by the volcano ? I cannot pretend pofitively to decide ; but I incline to the latter opinion more than to the former, fmce an alteration is vifible, even in the internal parts, which appears to be the effedt of a true calcination. In the furnace, the fubftance of this rock becomes foft, but does not fufe : the felt- fpars remain unchanged, but the fhocrls are vitrified. The ( 42 ) The fpacious and deep excavations made in the tufa by the rain-water, and which extend from the bottom of the mountain to the fummit, afforded me an opportunity to difcover and examine the ftony fub- ftances I have defcribed ; for it was only in thofe excavations that they were vifible : in every other part nothing appeared but the naked fuperficial cruft of the tufa. None of thefe fubftances are dlfpofed in currents; they are all detached ; and thus render it probable that they fell into the tufa after having been thrown up into the air in vol- canic ejedions. When "we have reached the fummit of the mountain, an ample plain opens, formed of the fame tufa, but become earthy, in which corn is fown, and a few vineyards are planted. Here we find numerous pieces of a fhining glafs, which is femi- tranfparent, of a blackilh colour, and fome of the fineft and pureft to be found in Li- pari. As I wiflied to difcover the origin of this fubiUnce, 1 caufed the place where it is founcj ( 43 ) found to be dug into. The tufiiceous earth is there about three or four feet deep. The pumices lie immediately under it, and among them this glafs is found, in confiderable quantities. It has probably been turned up, and brought to the furface, by the plough, pr other fimilar inftruments ufed to prepare the earth for fowing with corrj. Beyond this plain there Is a gentle de« fcent of about two 'hundred feet in length, at the end of which are the Stoves. What- ever prepofTeffion in their favour the travel- ler may have conceived from hearing fo much of them, he lofes it the moment he fees them. They form a group of four or five caves, more like to the dens of bears than the habitations of men ; and which exhibit much lefs of art than the edifices framed by the beaver. Every cave has an opening at the bottom, through which the warm and humid vapours enter, and ano- ther in the top through which they pafs out, I entered one of thefe, but was unable tP remairx long in it, l^fs from, the heat, for the ( 44 ) the thermometer ftood at only 48 j degrees, than from I know not what of a fufFocating nature which the air had in it. Thefe Stoves now retain Httle more than their name, and are nearly deferted. In facft, though they ftill retained their virtue, and were efficacious in the cure of various dif- orders, how would it be poffible to make ufe of them, when they are deftitute of every convenience necefiary to that pur- pofe ? When M. Dolomieu vifited them, the "whole ground on which they ftand was pe- netrated with hot vapours, which, under the form of a thick fmoke, iffued from fmall apertures of about an inch, or two inches, in diameter. When I was there, circum- ftances were much changed, as ufually hapr pens in volcanos, where the prefence of fire manifefts itfelf fometimes more and fome*- times lefs. There was then only one aper- ture, of about an inch in diameter, from ■which, from time to time, iflued a thin flream of fmoke, with a ftrong fulphureous 4 fmello ( 45 ) fmeii, Having enlarged this aperture, I found it furrounded by a fraall quantity of foft fulphures of iron (pyrites) generated by the union of iron and fulphur. The Ab- bate Trovatini, vvdiom I have cited m ano- ther place, likewife attefts, that, at certain times, feveral ftreams of fmoke afcended round the Stoves ; and I fhall add, that, be- fides the ftrong fmell of fulphur, which I perceived on approaching the place, the ground became hot, and the fetor increafed, on digging to about the depth of a foot : from which it may be concluded, that un- der the Stoves and the ground adjacent, fome remains of fulphureous conflagration ftill continue*. The Stoves, and the warm baths, * It has been (liewn, in Chap. XIII, that the decompo- (itions of different products of Stromboli and Vulcano do not derive their origin from the muriatic acid, to which, according to M. Sage, the principal alterations of volcanic fubftances are to be afcribed, but to fulphu- reous-acid exhalations. The decompofitions in the environs of the Stoves of Llpari, I am of opinion, with M. Dolomieu, are to be attributed to the fame caufe, the exiftence of which is fufficiently proved by the re- mains ( 45 ) baths, of which we ihall fpeak below, ard the only places in the whole illand where any figns are to be found of as yet unex« tinguifhed volcanos* M. Dolomieii, after having defcribed the Stoves of Lipari, proceeds to fpeak of the alterations caufed by the fulphureous-acid vapours on the lavas of this place, remark- ing that all of them, befides having become fofter and lighter, have loft their primitive colour, and affumed a w^hite tinge, mixed with yellow, red, violet, and other colours, which the oxides of Iron ufually produce. He obferves likewife, that they are coated ■with a thick cruft of fulphates of lime (fele- pite or gypfum), which fulphates penetrate likewife to the internal parts, and that fome lavas are covered with that kind of iron ore which is called filmy (f^ingofa) or bog ore. He then very ingenioufly explains in what manner, by means of a combination of the mrnns of fulphureous fumes, and the quantity of ful- phates of lime, which I fliall prcfently have occafion to tlefcribc. fulphuric C 47 ) fulphurlc acid with diiFerent earth?, the lavas have become lighter and varioufly coloured. As I vifited the Stoves three feveral times, and examined wqth great attention the lavas that had fuffered alteration by the adlion of the fulphureous acid, I am enabled to add, to the obfervations already given, fome others which I believe to be new, and which I fhall here briefly ftate. It was an obje61: equally important and curious to afcertain to w^hat kinds of lavas ftill remaining in the ilate in which they were left by the fire, thofe belong which we now fee decompofed by acids ; and as the obfervations I had made at Solfatara di Poz- zuolo and other places, had taught me that the decompofition diminilhes, the deeper it enters into the fubftance, I conceived that the moft proper means to obtain this know- ledge would be, to break fragments of the lava, and examine the internal parts, to find how far the decompofition had penetrated. The ( 48 ) The greater part of the decompofed latas of the Monte delle Stufe are, externally, of a reddifh white ; and fome are of a black- ifh colour. I firft examined the latter ; and prefenting their furface to the full light of the fun, I difcovered fomething of a brilliant appearance which invited me to examine it with the lens. It proved an aggregate of innumerable globules of hsematitic iron, which beautifully cover the furface of thefe lavas, I detached a confiderable number of thefe globules, and found that on trituration they afTumed a red colour, which is the property of the dark haematites. This was, there- fore, a pure martial oxide, depofited here, and formed into globules ; and under that aggregate lay another oxide of red, but earthy iron. The lava ftill deeper was of a white colour, interfered with parallel ftreaks of a reddifh black, or lightly fhaded with a yellowifh tinge. Thefe lavas are foft, light, and compact : they { 49 ) they adhere to the tongue, have the confifl* ence of clay, but do not emit its odour. They feem to be fimple lavas, no extra- neous bodies appearing in them. . It is ob- fervable that every fracture is conch oidal ; and that, when ftruck, they caufe a found fimilar to that of fome kinds of petrofilex ; which has induced me to fufpedt they belong to that fpecies of ftone : a fufpicion which is confirmed by examining deeper within the fradtures ; fmce at the depth of two feet, or thereabouts, a grey colour takes place of the white, and the other external appearances diminifh ; the lavas begin to aflume a fili- ceous afped,and give a few i^arks withfteel. Still deeper we perceive without the leaft doubt that thefe lavas have a petrofiliceous bafe, and contain a few {hoerls, which do not appear in the decompofed parts, probably becaufe they are themfelves decompofed. Thefe obfervations, which were made on fome lavas of a black colour on the furface, are likewife true of feveral others, which, externally, are of a reddifh white. The ap- V0L» in. E pearances ( 5* ) pearances in them are, elTentlally, the fame. The red colour in the internal parts infenfi- bly vanifhes ; the grey by degrees fucceeds the white, which, ftill deeper, acquires a luftre, the lava at the fame time becoming harder, and at length diftindly exhibiting all the chara^ers of the petrofilex. One of thefe lavas, ftreaked with white and a clear red like that of the peach- flower, is fpotted on the furface with points almoft pulverulent* Thefe are decompofed feltfpars, though they ftill retain a refidue of cryftallization. This lava has been more changed by the acids than the others, being ibfter, and even pulverable ;. though at the depth of two feet it is hard, heavy, of a bkck-grey colour, evidently has a petrofili- eeous bafe, and contains feltfpars which are perfedly entire. In deicribing the varioufly decompol^d- lavas of Solfatara, we have feen that felt- fpars are a kind of ftones which ftrongly refift the adtion of acids. It frequently 7 happensy { 5' ) happens, that their hafe is completely decompofed, while they are fcarcely in the leaft changed. As, therefore, ia th^ prefent lava, the fekfpars are decompofed equally with their bafe, we muft be con- vinced that the ftrength of thefe acids muft have been very great* In general, thefe lavas at their furface are foft, like doughy and almoft faponaceous; characters th^- ufually accompany thefe decompofitionsh -'^ * We muft not omit toWQtke'a lava oif the breccia kind, the bafe df whichis likewife petrofilex, and in which the action of the- acids has extended only tO' the depth of a few inches. This bafe, even near the fur- face, has not entirely loft its natural colour, refembling that of iron, and in it are incor- porated irregular fmall mafles of whitened and pulverulent lava. Thefe, therefore, have yielded more to the decompofition than the bafe that contains them. -At a -greater depth we find them unaltered 3 -and they are then only fragments of^kva bf ^ horn-ftone bafe. ' <'^iJjI:,i bnh ^o-iun^^ E 3 Though ( 52 ) Though many of the lavas of the Stoves of Lipari have fuffered by the fulphureous- acid vapours, there are fome that are entire- ly unchanged. I Ihall only defcribe one, which is fo well prelerved that it appears to have: been produced but yefterday by the volcanic gulph. If we fcale the furface of it, where it projeds in large mafles from the earth, it appears of a dark iron colour, has an eJvtremely, compad grain, and a con- choidal fradure. The fcales at the edges are fharp and -.cutting, and give very lively fparks with fteel. It is one of the heavieft lind hardeft among the lavas, and puts the magnetic needle in motion at two lines diftance. It has for its bafe the petrofilex, containing very brilliant feltfpar needles. This, lava, therefore, has not been- in the leaft affeded by thefe acids, not, probably, becaufe it was able to rtfift their ftrength, but becaufe it was not expofed to their ac- 4f^ : bThe places under which the confla- grations,pf. a volcano bun-, have,.numerous apertures and hfTures through which iflfue r!^uorri fuiphureous ( 53 ) fulphureous fumes; and when lavas are fituated around or within there, they will be more or lefs afFeded by them. But in the fame tradis of ground there are more places than one impenetrable to thefe fumes, and there, in confequence, the lavas fuffer no other alterations than thofe produced by time. Thefe interrupted exhalations of ful- phureous vapours I have obferved at Vefu-» vine, Etna, and Stromboli, and have noticed them before in my accounts of thefe vol- canos. It is only to be remarked that, at the Stoves of Lipari, the quantity of decom- pofed lavas being very great, and extending for the moft part to a great depth, the ful- phureous-acid vapours muft have there if» fued in extraordinary abundance, and at the fame time have been of long duration. The intenfity of them, and their confequently greater efficacy, might, indeed, have fup- plied the place of long continuance ; for I have obferved, that when the lava of Vefu* vius flowed before my eyes, and feveral of its lateral branches had ceafed to move, two of thefe, which had been penetrated E a by ( 54 ) by a thick clou'd of the fumes nfiul there, were already half decompofed, though they were evidently parts of that ciiTfent wMch, but a few months before, had been difgorged Jjy the fide of the jnountainv ^ Laftly, ac- cording to the different qualities of th« lavas, arid as they may be ."compofed more or lefs of calcareous, argillaceous, or martial principles, all combinable with fulphureous acidS) a greater of • kfe deGohlpolltioa will be produced* ^ -I J-!03oo i ty:dhi\ - The different degrees' of d^eompofition in lavas render them fometimes more, and fbthetimes lefs fufceplible of fufi^n in the furnaee. The parts notydecbinpofed will fufe. A beginiiing decompofidbft renders them ftubborn, andy whtii 4t is complete, they entirely refift the fire. TheCaufe of thefe differences appears to. me fufficiently evident. The more earths are pure the more they refifh fufion. All thofe hitherto known are.infufible, except in .very violent ^res. Their mixture facilitates their fufion, as they thus become a reciprocal flux j and ( 5S ) we know that fufion readily follows, when filex, alumine, and lime are mixed in the proportion of 3, i and i. There was no lava on which I made experiments, in which I did not find thefe three kinds of earth ; and though they might' not be combined exadtly in this proportion, their combi- nation was yet fuch as to render almoft every lava fufible in the furnace. The lime, which, in the dry way, ads as a flux to the filex, is in a great degree diminifhed in the decompofition of lavas, forming fulphate of lime by its intimate union with the ful- phuric acid ; and hence we have one im- pediment to the fufibility of thefe lavas. The diminution of the alumine, arifing from its combination with the abovementioned acid forming fulphate of alumine, which is afterwards detached and carried away by the rains ••'", will likewife be another obllacle; * To prevent any ambiguity, it may be proper to re- peat what 1 have faid in Chap. II, that the pretended tranfmutation of filex, or any other earth, into argil- laceous earth, in the decompofition of lavas, has no exiftence ; fince, in this c^ie, that earth likewife is di- miniflied, from the caufes alleged above. E 4 to ( 56 ) to which we may add a third, which is the lofs of the iron, Ukewile an aid to fufion, ' Thefe fulphates, which for the inofl: part accompany lav.as, prefent a pleafmg fpec-» tacle to the naturalift. Their colours are infinitely varied. Thofe which are moft prominent to the eye, are the rofe colour, violet, and orange, and they are the more confpicuous becaufe they are generally placed on a white ground. I have obferved three kinds of fulphate of lime, independent of feveral varieties which I omit. The firft is compofed of thin plates, parallel to each other, clofely united, brilliant, compad, and opake. They form ftrata or beds of diiferent thicknefs, fometimes more than a foot, and thefe ftrata are eafily detached from the lavas to which they adhere. The fecond fpecies is filamentous, having either parallel or ftellated filaments, in which Jatter cafe tl,e filaments form a kind of py-? ramids, which have their apices in one 6 commo?! ( 57 ) common centre, and their bafes at tlie cir- cumference. We find fome very large, pieces of this kind, formed by the aggrega- tion of thefe pyramids. The third fpecies is compofed of thin and (hining plates, fomewhat elaftic, tranCr parent, very foft, and forms the indeter- minate cryftallization of fulphate of lime called fpecular ftone; but this fpecies is rare, and its cryftals are always very fmalL In thefe cafes the determinate and primitive eryftallization of this neutral earthy fait is always wanting. It is therefore evident that this variety of colours, fuch as yellow, red, or violet, ex- hibited by the decompofed lavas, is a con* fequence of the iron pre-exifting in them ; which being, if not decompofed, at leafl greatly altered, by the fulphureous acids, is varioufly modified, and aflumes this diver- fity of hues. The fame caufe operates, in like manner, on the fulphates of lime, form- ed by the combination of the fulphuric acid with ( i8 ) with the lime, which is laid open by the deftrudion of the adhefion of the confti- tuent principles of the lavas, and varioiifly coloured by the oxydated metal. The white colour of -the decompofed lavas, then, it is evident, is produced by the lofs of their iron ; which agrees perfectly with experi- ence, fmce, where the decompofition has taken place, the lavas are incapable of moving the magnetic needle, whereas they conftantly produce motion in it, fome at the diftance of two lines, and fome at more or lefs, in the parts not decompofed. I fhall conclude my obfervations on the produ<^ions of the Stoves of Lipari, with fome interefting remarks relative to feve-- ral different fpecles of zeolites, which I dif- covered in their vicinity. I fhall defcribe them feparately with their matrices. - Eirfl fpecies. The matrix containing this zeolite is a lava of a horn-ftone bafe, of a dark- brown colour, granular in the frac- tures^: and which fcarcely gives fparks with fteel* ( 59 ) fteel. It (hews no indication of having fufFered by the fulphureous acids. It is full of fmall long cavities, all in one diredtion, and which probably were produced when the lava was in a fluid flate. It is in thefe cavities that this fpecies of zeclite is found. At firft view it appears rather tobe a ftalac- dcal calcedony, having the form of aclufter of grapes. It is of a white pearl colour, inclining to a light blue, and gives fome fparks with fteel. It has a filiceous fradlure, and a degree of tranfparency. Three pro- perties, however, efpecially charadterife it ; iirfl, that it forms a jelly with mineral acids; fecondly, that it flaflies or blazes at the mg- ment of fufion ; and, thirdly, that it bub- bles, and as it were boils, when in fudon: and though neither of thefe charaders ex- clufively appertain to the zeolite, all the three together fufficiently fix the nature of this ftone, which muft be referred to the clafs of amorphous zeolites. The clufter- ing grains may be extraded entire, as they attach to the lava but in a few points. The largeft extend to five lines in length, by two or ( 60 ) or three in breadth. The figure which I have called cluflering, is the moft ufual in this fpecies of zeolite ; though fome arc only oblopg globules, of the fame fize with that of the fmall cavities which contain them. They are, however, by no means found in every cavity ; for, out of a hun- dred of thefe cavities, ninety contained no zeolite. This fpecies is contaminated with a pulverulent, orange- coloured oxyde of iron. The blow-pipe with difficulty melted it j and feveral feconds were required for its I complete liquefadion, even with the aid of II oxygenous gas. It then changed into a fnowy-white enamtl, full of bubbles. It has a lucid brightnefs when it begins to melt, and boils and bubbles up when ia actual fufion. Second fpecies. This is found in fome pieces of the former lava, but its charaders are different from thofe of the pr-eceding fpecies. It coats over many of the cavities before C 61 ) before mentioned with a thin cruft, thii& forming geodes, which, however, are not cryftallized internally. This zeoUte, which incUnes to a white colour, is more tranfpa- rent than the other, and, from its harJnels, cuts glafsj almoft like rock cryftal. The mineral acids have no effedt upon it, not even when pulverifed, though they convert the former fpecies into a kind of jelly. When melted with the aid of oxygenous gas, it emits a thin brilliant blaze, and is changed, with ebullition, into a vitreous and white globule. It Is not unufual to find within thefe zeolitic geodes, plates of very tranfparent fulphate of lime. A hundred grains of this, pulverifed, were put into fix hundred of diftilled boiling water. A folution was obtained, and the oxalic acid precipitated the lime. Third fpecies. This confifts of ovoid globules, externally dirty, from an earthy coating, but which internally are extremely white. t 6^ ) white. In the fractures we perceive that they confift of a number of opake groups of fibres, ftriated, filky, and (hining, which diverge from the centre to the circumference of the globules, and thus form fo many in- verted cones. Thefe globules, fome of which are more than four lines in diameter, Jjerfedly fill the cavities of an argillaceous, light, extremely friable lava of a deep grey colour. Every cavity, however, does not contain a zeolite of this conformation : in fome we ftnd zeolitic ftones with feveral facets, but fo confufed that the precife con- figuration of the cryftals cannot be diftin* guiftied. On attentive examination, they evidently appear to be formed of th« fame zeolitic fubftance, which, when it occupied the whole fpace of the cavity, took the con- formation of thofe fibrous groups that have externally a globofe figure ; but when a part of this fpace remained empty, it cryftallized more or iefs. Thefe zeolitic ftones always have" in the middle a fmall empty fpace, where they are cryftallized, forming a num- ber of very minute geodes. The I ( 63 ) The blow-pipe prefently melts this third fpecies, and with ebullition ; a phofphoref- cence precedes the fufion, and the pearly globule which is the refult, is a femitranf- parent glafs, abounding in bubbles. If this globule be broken, which requires rather a fmart blow, the fharp angles of the frag- ments will cut deep into glafs. This zeolite, foon after it has been put into acids, attaches to the fides of the con- taining vefTel in the form of a cruft, which cruft prefently refolves itfelf into a tranfpa- rent tremulous jelly, fimilar to that of harti^ horn. Fourth fpecies. The lava which contains this zeolite is of a horn-ftone bafe, and forms two fpecies, at leaft two varieties ; the one of which is granular, rough to the touch, and extremely friable ; the other has a kind of foftnefs, a fine grain, and greater folidity. In colour, however, which is a grey, and in their argillaceous odour, both thefe varieties agree. ( S4 ) agree. This lava contains a multitude of zeolitiG globules, from half a line to an inch in diameter. On breaking them, a Vacuity is found within them, thus forming geodes of a cryftallization more ot lefs perfects Wherever the zeolitic fiibftance ha^ been too confined in the cavity of the lava, the cryf- tallization is extremely imperfect, in con- fequence of the prifms being half-formed and confufedly intermingled ; but where that fubftance had a larger fpace to develop it- felf ia, the prifms are no longer fo indif- tin£t ; many of them, at leaft, are found to incline to a tetrahedral figure ; and where the cavities of the lava have afforded a ftill greater fpace to the zeolitic matter, it has cryftallized in tetrahedral prifms, of a dif- tin(fi conformation. Every prifm has there- fore four faces diftindly feparated. In fome few places thefe prifms are terminated by a tetrahedral pyramid. Many of them are of a milky whitenefs, and thefe are femi- tranfparentj but others have a tranfparency almoft equal to that of quartzofe cryftals, A fmgle i ( 65 ) A lingle cavity fometimes contains feveral fcores of fuch prifms, while another fhall contain but very few. The blow- pipe eafily melts thefe geodes with the ufual phenomena of ebullition and phofphorefcence, and the glafs which is the refult of the fufiori is fimilar to that of the zeolite of the third fpecies. A fimilar jelly is likewife produced from it, and wuth equal promptnefs, in acids, except that it has a lefs degree of vifcofity. Fifth and fixth fpecies. Thefe two fpecies of zeolites are contained within an argilla- ceous lava, of a dark-grey colour, light, and of an earthy confiftence : they both merit to be diftindly defcribed. The firft fpecies confills of a great number of fmall fpheses, white as fnow, each occupying a cavity in the lava, and varying in fize, the fmalleft being fcarcely one third of a line in diame- ter, and the largeft more than three lines. The furface of thefe fmall fpheres is not fmooth, but fomewhat rough, from an in- VOL. Ill, F finity { 66 ) finity of points which, viewed through the lens, are difcovered to be fo many minute tetrahedral prifms, diftindly defined. On breaking the fpheres we perceive that the prifms arc continued within them, and, be- coming thinner, proceed to the centre ; or, to fpeak more properly, we find that the fpheres are only the refult of a number of prifms joined together length wife. The portion of the prifms that is immerfed within the fpheres is opake ; but that part which projects out has a degree of tranf- parency. It is to be obferved, that though the greater number of thefe minute fpheres are perfedly folid, many of them have a round vacuity at the centre, fometimes ex- tending to one tenth part of the whole fphere. This zeolite Is the fofteft of all the fpecies hitherto enumerated, and may be fcraped or cut with a knife. The fixth, and laft, fpecies is one of the moft beautiful zeolites hitherto difcovered by ( 67 ) by naturallfts. It confifts of minute cry- ftals, extremely clear and bright, which, having facets in every part, vividlyrefled: the light, and fparkle like fo many diamonds. Thefe are very numerous in the cavities of the fame lava ; but are unequally diftributed, as fome cavities contain but one of thefe cryftals, while others have two, and others three, though the latter are rare. The largeft do not exceed a line, and the moft minute are fcarcely a quarter of a line. While they remain in the lava, it is not eafy to examine them as might be wi(hed ; but many of them may be extracted without injury, and viewed, in every part, with the lens, at leifure. We then perceive that thefe zeolites, where they reft on the lava, are flat ; but in their upper part incline to a globofe figure ; and that, there, their cryftallization is apparent : that the ifolated cryftals, I mean thofe which in their formation grew without attaching to the other cryftals, have eighteen facets, for the moft part pentago- nal, or tetragonal, but never triangular : that thefe ifolated cryftals are extremely rare; the greater number being aggregated^ that F 2 is. ( 68 ) is, confufedly heaped upon each other lU their formation : that, lafily, though many of them may compare in clearnefs with the pureft rock cryftal, they are yet inferior in, hardnelis, as they with difficulty cut glafs. I at firfl fufpeded that thefe zeoUtes were a fimple modification of the fifth fpecies, which, wherever it had a free fpace, had formed itfelf into thefe brilliant cryflals, either ifolated or aggregate. But this con- jecture was not confirmed by obfervation. It frequently happens that the white minute fpheres which form the fifth fpecies, occupy enly one half, or even lefs, of the contain- ing cavities, without ever taking the form of the fixth fpecies ; but it is conflantly to be obferved that the tetrahedral prifms pro- jed: farther beyond the convexity of the fpheres, and have a greater tranfparency. They muft therefore be confidered as two diflindt fpecies. » This difference is filll more confirmed by the action of fire and acids. The latter do not a<^, at lead fenfibly, on the fixth fpecies, though ( 69 ) though they reduce the fifth to gelatinous flakes or tufts. The fire of the furnace, in half an hour, converts the cryftals of the fixth fpecies into globules of extremely tranfparent glafs ; whereas it only foftens, in that time, the minute fpheres of th^ fifth, which require a fire of much longer con- tinuance for their complete liquefa] £v w)70i. Horn. Odyff". Lib. X. Kai ixiv Twv utOfXsaSa ttc'aiv y.ai cxixara xa>-a. I7.10V, A^ynav T£ v£aj, nai vofov A;^«iS)V. Ibid. the ( ^1 ) the poet the ufual licence of poetry, it Is ftiil moft certain that he could not have named this ifland, and the city it contained, unlefs they exifted at the time he wrote his poem, fmce which nearly three thoufand years have now elapfed. But if we confult other ancient and credible writers, we fliall find that before Eohis, Liparus reigned in this ifland, which from him took its name, being before called Mdogonis^ or, according to others, Meligunu, Another obfervatlon, likewife, here natu- rally prefents itfelf. An ifland formed by. depofltions, and the fubfequent retiring of waters, may, in a fliort time, be cultivated and inhabited ; but it is not fo with one that is produced by fubterraneous eruptions, where the decompofltion of volcanized mat-, ters is necefl^ary; that is to fay, a far longer time. If, therefore, LIpari had inhabitants and cities, and was a cultivated country before the deftrudion of Troy; it is evident that it muft have exifled many ages prior to that event. G 4 From ( 88 ) From the time, however, that mention Is firft made of this ifland in hiftory to the prefent day, we may confider it as certain that no true eruption, or current of lava, has taken place in it ; as, otherwife, it is probable fome memorial would have been prefer ved of it, as well as of thofe of Stromboli and Vulcano. Arlftctle, indeed, mentions the fires burning in Lipari, but adds they were only vilible by night ■'''; and the writers who followed him fay nothing more. I hence infer that this ifland had attained its full formation and fize, before it was known to men, which was not the cafe with Stromboli and Vulcano. I muft not omit another obfervation. Many of the lavas of Lipari ftill fcarcely exhibit the lead fign of alteration, efpecially the vitreous, the enamels, and the glafTes ; though it is evident, from what has been faid above, that thefe bodies muft have exilled above three thoufand years. We hence perceive what * Kai TO EV 7r) Aiaa^a ^s 7iv^ (pavi^ov xai (p?\oyuO£g, cu fitv rfXEfcci;, a'h.>.a vvhlcg fxovov Hana9ai T^zyirai- In Mirandis. an ( 89 ) an adamantine temperament, if I may ufe the expreffion, the fire can beflow on vari- ous fubftances, fince they can thus refift the influence of the feafons and of time. "When I prove the antiquity of Lipari by the authority of Homer, I do not mean to confider the other neighbouring iflands as of pofterior date. I am Hkewife well con- vinced, by the teftimony of hiftory, that, except Vulcanello, they were all in exiftence in the time of that poet, who probably docs not mention the other Eolian ifles becaufe Lipari was the largeft, the moft fruitful, and moft generally known, as being the refidence and feat Qf government of king Eolus, CHAP. ( 9^ ) CHAP. XVIL FELICUD A. Two bays i?i this ijland capable of receiving fmall vejfels — The prodiidfs fou?id there by the author^ fiifficiently prove it volcanic — Circuit of it by fea — Prifmatic lavas fall- ing into the fea — Spacious cavern hollowed in one of thcfe lavas — Enquiries relative to its origin — Curious alternation offiratas of tufa and lava — Other prifmatic lavas along the fjorc — Obfervations relative to them — Excuffion into the interior part of the if and — A mountain^ near the centre^ higher than the refy on vohich is difcover- able the crater of an ancicfit volcano^ to which y probably, Fe lieu da oives its origin ■ — ConjeElures that another f mailer volcano exifedat thefummit of a lower moimtain — ISlo other perceivable fgns of volcanic mouths throughout the w^hole if and — ^alitics of the lavas forming the inte- rior ( 9' ) rior part of Felicnda — GhiJJ'cs, pnmkes^ iufas^ and pu%%olanas fcattered over the ijlatid — Fu%%olanas and pumices employed by the inhabit a7its ofFelicuda in hull ding — ■ The fuhjlances of ivbich the ifland is com- pofed entirely volcanic ^ except a piece of granite^ vohich appears to be natural — Reflexions on this rock. r yet remains to fpeak of Felicuda and Alicuda, the two extreme iflands of thofe of Lipari towards the weft ; and I fliall the more willingly undertake the defcription of them, as they have not, to my knowledge, been vifited, at leaft defcribed, by^any other naturalift ; M. Dolomieu, who was moft capable of examining them, having only feen them at a diftance, as to have touched at them would have led him too far from his intended route. On the 7th of Odober, in the morning, I fet fail from Lipari for Felicuda, diftant from the former illand twenty-three miles, and ( r- ) and arrived there in four hours. This illand is not provided with a port; but it has two bays, one on the fouth, and the other on the north-eaft fide, fufficient for the re- ception of.fmall veiTels, and fo fituated, that though the wind fliould render the entrance into one of them difFicult, it will be eafy to get into the other : both of them are like- wife kifhciently fheltered by a mountain. I landed in the bay on the north-eaft fide, and, in the flrft place, applied myfelf to difcover of what materials the illand was formed ; and foon difcovered inconteftable proofs that it is truly volcanic. Not only is the fhore of this bay lined with lava; but, having in the courfe of the day proceeded farther up on the fouth-eaft fide of the iiland, I found among the earth of fome fields a confiderable quantity of pumices, glafles, and enamels, which produds I fliall feparately defcribe when I come to treat of the internal part of the ifland. Being thus fully convinced of the ancient exiftence ( y3 ) exiftence of fire in this iflaiid, I determined, the next day, to make the circuit and ex- amine the fhores of it, in the fame manner as I had proceeded in the other iilands. Felicuda is nine miks in circumference, I began the circuit of it hj examining the lavas that border the fmall bay which I entered. Thefe have for their bafe the feltfpar, v^^hich is of a fcaly confiftence, a light grey colour, not very compact, but giving a few fparks v^ith ft eel and attrading the magnetic needle. Within its fubftance are included needles of black and fibrous fhoerl, and fmall pieces of feltfpar, which are eaiily diftinguilhable from the 'bafe by their whitenefs, femitranfparence and luftre. A part of the fhores of the bay are com- pofed of this lava with deep fiflures running lengthwife, as we fee in many other lavas. A number of round vacuities are likewife obfervable in it. They are of confiderable depth, and give it the appearance of a honey- comb. I rather incline to afcribe them to the adion of elaftic gafeous fub- ftances. ( 94 ) ilances, vvhcn the lava was In a ilate of fufion, than to corrofions produced by the influence of the atmofphere or any external agent. It is certain that the air of the Tea will greatly corrode many foffil fubftances fituated in its vicinity J and I have witnelTed extraordinary effects from its adion on many low rocks, on the fhore of the Me- diterranean, near Genoa, and efpecially at Porto Venere, the Golfo della Spezia, and at Lerici. I have alfo frequently obferved the external part of many towers and maritime buildings very much injured on that fide which fronts the water. The city of Commachio in the territory of Fer- rara, perhaps, furnifhes fome of the moil complete examples of fuch effedls. it is lituated in the midft of fait lakes; and its porticos and edifices are lo much corroded and damaged by the air, that they are ob- liged to undergo periodical repairs at the end of no very long time, as I obferved with furprife during a fhort ft ay which I made there in Odober 1792. The fea air, how- ever, does not ad thus on every foliil fubftance indif- ( 95 ) indifFerently, but, with refped: to flones, feems principally to attack the carbonates of lime ; though not all of thefe, as appears from the hard Iftrian marble with which the fuperb palaces and fumptuous edifices of Venice are built, and which remains unin- jured for a long feries of years. I likewife obferve that volcanic ftony fubilances are little, or not at all, injured by the air of the fea; and I am the more confirmed in my opinion that the incavations in the litoral lava of which I am now fpeaking muft be attributed to the a(flion of aeriform gafes, and not to that of the fea air, from obferving the fame, likewife, in the feltfpar, a ftone much lefs liable to this kind of alteration than many others. After having made thefe obfervationS) T left the bay, and began to coaft the iHand towards the left, on the northern fide. I had fcarcely proceeded one hundred and ^fty paces when I met with a rock of lava, about thirty feet high, and equally broad, lifing almoft perpendicularly from the water. This ( 96 ) This rock prefented a novelty I had riot be- fore obferved in the Eolian illes. This was a number of prifms into which the lava divided before it plunged into the lea. The im- portance of this objedt induced me to bring my boat clofe under the rock, that I might make the neceflary obfervations with more certainty and fecurity. About twelve feet above the level of the fea, the rock is fmooth, and prefents an equal furface ; but, lo me what lower, it begins to be furrowed with narrow longi- tudinal excavations, which defeend to the edge of the water, and form prifms with three unequal fides, the fide behind remain- ing attached to the rock, or, to fpeak more properly, forming one continued whole with it. Thefe prifms" continue to preferve their form under the vx^ater, of which I haid Indubitable proof. The fea, though then calm, had a flight roughnefs towards the rock, to allay which I poured into it fome olive oil, which I always carried with me in thefe excurfions to calm the leiTer waves of the ( 97 ) the fea, and thus enable myfelf to perceive fubaqueous bodies at a certain depth as cir- cumrtances might require. By thefe means I difcovered that the prifms were immerfed in the fea to the depth of fome feet. The breadth of fome of the prifms was a foot and a half, but that of others lefs. This prifmatic lava merits to be very ac- curately defcribed, fmce, in profecuting my voyage along the fhore of Felicuda, I met with it in feveral other places, and fhall again have occafion to mention it. Its bafe is a horn-ftone of the black colour of iron, and fo compact that the fmalleft bubble is not perceivable in it; it muft, therefore, be claffed among the heavy lavas. The edges of the thinned flakes of it are tranfparent, and give fparks with fteel. Its fragments are amorphous, and receive a polilh, but without luftre. It attrads the masfnetic o needle at about the diftance of three lines. The powder of this lava is cinerltious, and impalpable, and attaches to the finger. In VQL, III. H it ( 98 ) it are contained various grains of amorphous fbltfpar, and a greater number of fmall, long, rhomboidal fhoerls. The product of this lava in the furnace is a hard enamel, of the colour of pitch, and full of bubbles. The feltfpars it contains remain refradtory. It is to be remarked, that this enamel does not lofe the magnetic virtue. The place where this rock hangs over the fea is called Fila di Sacca. Beyond it the fhore of the ifland, M^hich continues to have a fteep defcent into the fea, offers only common lavas, except one fpecies which has fome rude appearance of prifms, that affume a more diftin(^ form near the furface of the water. Still farther, at a place called Saccagne^ a number of fmall rocks rife above the furface of the water; one of which is called // Perciato^ becaufe it is perforated in the mid- dle, and the opening is wide enough to admit ( 99 ) admit fmall veflels to pafs through. The forms of prifms are diftindly difcernible in thefe rocks. At the dlftance of fifty paces farther, a fpacious cavern opens in the lava of the (here ; an obje£l highly interefling and beautiful in the eyes of the volcanift. It is called the Grotta del Bove Marino (or Grotto of the Sea-ox), perhaps becaufe it was once the retreat of fome phoca or feal, as in the Lipari iflands, and many other places, the phocsE are called fea- calves. The mouth of this cavern, in the upper part, is oval, and is fixty feet in breadth, and above forty in height. The mouth opens into a kind of porch, which leads into a fpacious hall two hundred feet long, or nearly, one hundred and twenty broad, and fixty-five high. This hall terminates the cavern. The fea enters it ; and as its force is broken by the narrownefs of the entrance, fmall barks when furprlfed by a ftorm may there find fhelter. H 2 Some ( lOO ) Some may pertaps wifh to enquire, whe- tlier the roof of this cavern prefents any of thofe ftaladical concretions which are obfervable in many other excavations in mountainous countries. No fuch concre- tions are to be feen ; the ftone of which it is formed being evidently not of an aqueous but an igneous origin, that is, a lava diftin- guifhed by the following charaders. Its bafe is fhoerl in the mafs ; it is mo- derately porous, and therefore rather light ; but gives fparks with fteel. It is unequal in the fradtures, has a fomewhat argillaceous odour, and attracts the magnetic needle at the diftance of half a line. It is of a grey colour; but interfperfed with white, fhin- ing, rhomboldal feltfpars. Their fplendour is diminifhed in the furnace ; but their whitenefs appears heightened from the black colour acquired by the enamel produced by the fufion of the lava, which is opake and extremely full of bubbles. The fufion, in- ftead of diminifhing or deftroying, rather increafes its magnetifm. This ( 10. ) This lava, which forms the large cavern, defcends ahnoft perpendicularly into the fea, and there affumes the form of prifms, but larger than thofe before defcribed. It is worthy of remark, that thefe prifms, though in their lower part they fmk deep into the water, do not rife above it, in their upper, more than eight or nine feet. But in what manner are w^e to explain the origin of this cavern ? How great muft have been the violence of the waves of the fea, to form by flow corrofion fo vaft an excavation within this mafs of lava ! To this caufe I cannot confent to afcribe it; principally for this reafon, among others that might be adduced, but which I omit for brevity, that no fooner has the water entered the mouth of the cavern but it lofes all its force ; befides that the hardnefs of this lava is fuch, that it does not eafily yield to the ftroke of the waves. I incline rather to think it the effed of the adion of the gafes in the lava at the time it was in a ftate of fluidity ; as we have examples at Etna of H 3 caverns ( I02 ) caverns incomparably deeper produced by a fimilar caufe. Immediately beyond the Grotta del Bove Marino, we meet with a mixture of tufa and lava, which merits fome attention from the curious alternation of its ftrata. They are found on a high precpice which defcends into the Tea, the fur-ace of which is covered with a tufaceous foil, refting on a bed of lava, above another of tufa, and fo fuc- ceflively, that in a rent made in the pre^ cipice by the waters we may number eleven ftrata or beds of tufa, and as many of inter* pofed lava. It appears, therefore, that the fire and water, by their repeated adlion, have produced this mixture of lavas and tufas. The lava of^ the eleven beds is of the fame kind, that is, of a horn-ftone bafe, and containing, as ufual, (hoerls and feltfpars. It has an earthy afped, a blackifh colour, and a ftrong argillaceous odour. It moves the magnetic needle at the diftance of two lines, ( 103 ) lines, and the enamel into which It is changed in the furnace has the opacity and blacknefs of pitch, and its magnetifm is greater than that of the lava before fufion. The beds of tufa, llkewlfe, do not eflen- tially differ from each other. They are an ill-kneaded mixture of lumps of argillaceous earth, more or lefs tindured with yellow oxyde of iron, which earth is eafily pulve- rable. With it are mixed numerous fhoeils, that from the foftnefs of the bafe may be feparated entire, which they fcarcely ever can be in the lava. Notwithftanding, how- ever, the facility with which they may be detached, it is difficult to determine their cryftallization, not merely from their ex- treme minute nefs, for fome of them are two lines In length, but from their being fcarcely ever found fmgJe, almoft every one being a group of aggregated {hoerls. When one, however, is found fmgle and detached, it appears to be an hexagonal prifra terminated by two trihedral pyramids. They are black, fliining in the recent fradures, and are fome- H 4 what ( l with the following remarks : Fir ft. Thefe prifms have never more than three faces, one of which always remains adherent to the lava. Secondly. Their diredion is never ob- lique, or tranfverfe ; but, without excep- tion, perpendicular to the fea. Thirdly. They are not articulated, as they have been obferved to be in fome volcanic countries, efpecially on Mount Etna, but form one continued line. Fourthly. In their lower extremity they defcend within the water, and, in their upper, rife fome feet above the level of the f£4* Fifihly. Thefe prifmatic lavas have for their bafe, either the horn-ftone or flioerl in the mafs, I ihall ( lo6 ) I fhall now proceed to defcrlbe the ob- jeds which appeared to merit notice in the interior part of Felicuda. This ifland, when feen from the fea, at a little diftance, has the appearance of a number of mountains heaped together ; one of which, fituated in the centre, is much higher than the reft, rifing, perhaps, half a mile above the level of the fea. After having examined the bafe or fliore of the ifland, 1 proceeded, there- fore, to the fummit of this mountain, taking my way towards the eaft, as, on that fide, the road is leaft difficult. The afcent is not one of the moft fatiguing; for though we meet with fteep precipices in fome parts of it, they are prefently fucceeded by gentle declivities, which relieve wearinefs and re- ftore ftrength. When I had reached the fummit of th^ central mountain, I perceived that it inclofed a capacious hollow called Fo[[d delle Felcl (the ditch of fern) becaufe it formerly was overgrown with that plant j though when I was there it had been all rooted up, with the ( I07 ) the intention of fowing corn the next fprlng. This hollow is about half a mile in circuit, the fides approach as they de* fcend, and its depth is not more than forty feet. Thefe circumftances fufficiently prove that this was the ancient crater of the vol- cano ; and that, perhaps, or rather without doubt, this was the firft, which, by its eructations, contributed to the formation of Felicuda. It is likewife to be obferved, that the ex- ternal part of this crater correfponds to the internal ; that it is a truncated cone ; that its lavas, parting as from a centre, have di- verged like rays down the fides of the mountain, while thofe on the fide towards the north-weft have poured rapidly into the fea. The propofal to fow corn in this hol- low argues that it muft be earthy, as it really is. It is formed of a half pulverulent tufa, under which, however, the lava is difcoverable. Three ridges rife on this mountain, one of ( >o8 ) qf which defcends to the fouth ; and, at about half way up, joins another mountain. The fecond of thefe ridges has its direction to the eaft, and the third to the weft. From this fummit I had a complete view of Fdi- cuda, and looked round me with attention to fee if I could difcover the figns of any other crater. 1 thought I could difcern the veftiges of one to the fouth-eaft, and, after- wards, repairing to the foot, was more con- firmed in my opinion. I found a hill, about half as hio;h as the mountain already defcribed, and about two miles in circuit. It is ifolated on every fide, and has the figure of a broken cone, truncated at the top, where it finks into a cavity growing nar- rower towards the bottom, which appears to be the relics of an ancient crater. Scat- tered pieces of various lavas, half-buried in an earthy tufa, occupy the cavity of this hill, and its external fides are formed of a number of currents of lavas. Except thefe two craters, of the laft of which I have expreifed myfelf with fome doubt, ( 109 ) doubt, I know not of any throughout the whole ifland ; as I fhall not venture pod- tively to confider as fuch a number of cavi- ties, hollows and caverns which we meet with in various places, fuch appearances not being fufEclent to chara^fterife a volcanic mouth. The principal lavas of the fhore of Feli- cuda have already been defcribed fmgly : it is now neceffary to fpecify thofe which form the internal and more elevated parts of the ifland. Thefe, as far as I was able to difco- ver, during the ftay of five days which I made there, may be reduced to three kinds, if we omit thofe which are merely va- rieties. The bafe of the firft is a horn-ftone of a colour between a black and a grey, of a frac- ture evidently brilliant, without any appear- ance of pores, and which gives fparks copi- oufly with fteel. The pieces into which it breaks have no determinate form, do not refufe a tolerable polifli, and move the mag- netic ( "0 ) iietic needle at the diftance of a line afid three-fourths. Minute grains of quartz, nu* merous fcales of feltfpar, and extremely fmall and brilliant needles of fhoerl are incorpo- rated in this lava. The furnace fufes the fhoerls,but not the quartz, and the feltfpars; and the lava is changed into a black, frothy, and opakc enamel. This lava extremely refembles the prlf- matic lava defcribed above ; though it has not that regular configuration. The lava of the fecond fpecies is likewife of the horn-ftone bafe ; not very hard nor heavy ; of a cinereous and earthy afpe<£t, without pores, attaches flightly to the infide of the lip, and emits an argillaceous odour. The fhoerls it contains are rhomboidal, fcaly, and of a violet colour. In the furnace it is only foftened ; and the (hoerls remain entire, < The ( "I ) The third fpecles has for its bafe, fhoerl in the mafs. It is black, without pores, ra- ther heavy, and of a granular fradure. The heterogeneous floncs, which arc mixed with the fubftance of this lava_ are of three kinds : fmali irregular quartzofe par- ticles, which, from their whitenefs, are mod confpicuous ; a few minute feltfpars ; and numerous rhomboidal fhoerls, of a dark violet colour, and remarkable for their fize, fome of them extending-to feven lines. The feltfpars and quartzofe grains are refradory in the furnace; though their bafe is eafily fufible, and produces a fhining, opake, and porous enamel. The internal part of the ifland, as far, at leaft, as appears from the furface, is com- pofed of thefe three lavas and their varieties; which lavas form currents, that, from their great antiquity, do not exhibit thofe tu- mours, wavings, and inequalities, which are obfervable in recent lavas, or thofe of a mo- derate ( 112 ) derate age. The fame antiquity is, likc-a wife, probably the reafon, why in Felicuda we do not find fcori^e, or fcoriaceous lavas ; thefe, ufually, from their flight and feeble texture, and from their lying on the furface of the current, being the firft which are altered and deftroyed. When treating of Lipari, I remarked the great effeds which have been produced on the products of that ifland by the fulphu- reous-acid exhalations. The contrary is to be obferved of Felicuda, there not being a fmgle lava which exhibits the leaft fign of their influence; though they all bear the marks of the injuries of time and of the at- mofphere. So much have I found them changed, efpecially near the furface, that had I not broken up the lavas to the depth of fome feet, a pradice to which I had ac* cuftomed myfelf in thefe refearches, I fliould freouently have taken the fame lava for others fpecifically different. Having thus defcribed the different kinds of ( "3 ) of lavas cf this ifland, it will now be proper to proceed to treat of the other volcanic fubftances it contain*?. Among thefe are the tufas, which are found in great abun- dance in other parts of the ifland befide thofe above defcribed. In general they are pulverulent, light, fpungy, of an argilla- ceous nature, and greedily imbibe water. The places in which they are found, are the only parts of the ifland which the inhabit- ants can render productive by cultivation. It is among the tufas that we difcover glafles and pumices. We will treat of thefe two fubftances feparately, beginning with the firft. I have already faid, that I had fcarc ely landed in Felicuda before I difcovered feve- ral pieces of volcanic glafs. In my fubfe- quent refearches, I afterwards difcovered that this glafs was not found among the la- vas, but in the cultivated earth of the fields. The peafants of thofe parts confirmed the truth of this obfervation, and, finding I was VOL. III. I in ( 114 ) in feareh of this fubftance, brought me more of it than was neceffary, which they cot- leded in the fields where they worked. As I was not, however, perfedtly fatished with this firft obfervation, I dired:ed them to dig a deep trench in one of the fields which mod abounded in fpecimens of this fub- ftance, with a view to try if I could dif- cover a vein, thefe being only detached pieces. The trench they dug was eight feet deep, and five in breadth. For the depth of two feet I found only a tufaceous earth, containing fome of thefe vitreous pieces. At a greater depth the virgin tufa- appeared,, untouched by the ploughfhare, or any ruftic infirument. This tufa likewife furniflied a fimilar glafs, but always in detached pieces^ nor was any difference perceivable in the nature of thefe products, on continuing the refearch to the bottom of the trench, where the tufa was ftill found* It appears, therefore, that the glafs in tlie ploughed fields had its feat in the tufa ; though it cannot be affirmed with certainty, that ( "5 ) that it was thrown out from the mouth of the volcano in the fame ftate in which it is now feen ; fince it is only found in plates or flakes, and with thofe points and (harp angles, thofc cutting edges and waving ftreaks, which we obferve in glafs, whether volcanic or fad:itious, when it has been broken and^ divided into fragments by a hammer, or other heavy body. We muft therefore conclade, that after the fubterra- nean conflagrations had reduced the ftony fubftance to glafs, this glafs has been thus broken and fhivered by fome convulfion of the earth, or by fome violent and tumultu- ary agent. The larger pieces are about five inches and a half over, and two in thicknefs. Many of them are not inferior in clearnefs and brilliancy to the fineft and brighteft glades of Liipari ; others are lefs tranfparenr, and of a cinerltious, or grey, colourj while others are almoft entirely opake; and'thefe approach nearer to the nature of enamels than to that of glalTes. They are all, how- I 3 ever, ( ir6 ) ever, extremely compa£l, and will readily give fparks with ileel, and cut common ar- tificial glafs. Several of thefe pieces con- tain within them fmalt white particles, whicb have been obferved and defcribed in many of the glaiTes of Lipari, which particles in- dicate that the glafs containing them is not fo perfedlly vitrified as the reft. We alfo find pieces, though they are rare, the one half of which is a very black glafs, and the other a fimple lava. The lava, which thus^ forms a whole with the glafs, is of a cineri- tions colour, and, as appears from fome analyfes which I have made of it, is of a petrsfilkeous bafe. Tills glafs, like other volcanic glafles,. changes in the furnace into a vitreous froth. It now remains to fpeak of the pumices,, which are likewife enveloped in thefe tufas.- Thefe never form laree maOes, but are al- ways found in detached pieces, of rather a- imall iize, the largeft rarely exceeding the bignefs of the clofed hand. In general they are ( i'7 ) are. more plentiful than the glafles, and among the tufas of uncultivated places, it is only nece^ary to remove the furface to find them by hundreds. During my ftay at Fe- •iicuda I refided in a place called La Valle della Chiefa (the Valley of the Church), This is a fmall plain, on the eaft fide of the ifland, in which ftand the parfonage-houfe and the church, two indifferent buildings, .Suitable to the poverty of the country. This place, as like wife a fpacious declivity -to the ^outh, abounded with pumices, both on the furface of the tufas, and below the furfaccj wherever they were dug into. Thefe pumices are of two kinds ; the one cellular, extremely friable, fibrous, and 'tt'hich float on the water; and the other compad:, heavy, without pores, and of a fmooth fradure 9 but which yet polfefs all the true charaders of pumice. Some are of a reddifli colour, ;Qthers yellowifh, and many afh-grey. Ail are plentifully fur- iiifhed with extremely brilliant vitreous felt- ipar-fcales. Ij la ( «>8 ) In my obfervations on the pumices of Vulcano I have remarked, that inilead of fwelling in the furnace, and being tranf- formed into an ebullient product, as is al- mod always the cafe with glaffes and comr pad: enamels, they become of lefs bulk, lofe their pores, if they had any before, or, at leaft, contra.ii zipoTayopevofjitvuv vnTuv 'sr^jj^of tj (paai In Mirandis. + 'EpixHcra-a, fna ruv AioT^a vno-icv, utto (pi/7a hu'^h/ji.bvti. !iSk7.rA7ui» Lib, VL palm^ ( IJ' ) palm-tree, nor is there one to be found in any of the Eolian ifles. But neither the above-cited authors, nor any other ancient writers, make the leaft mention of any conflagrations in thefe two iilands ; probably becaufe, though, in their time, StromboU, Vulcano, and even Lipari threw out fire, Felicuda and Alicuda, as we have feen was the cafe with Didyma and Euonimus, were entirely extinguiOied. L 4 CHAP. { ^52 ) CHAP. XIX. OBSERVATIONS WHICH HAVE AN IMME- DIATE RELATION WITH THE VOLGA- NIZATION OF THE EOLIAN ISLES ENQUIRIES RELATIVE TO THE ORIGIN OF BASALTES. Methods and injlruments proper to ra'ife Jlojiy bodies from the bottom of the fea fiirroiind- ing the Eolian ifes — The bottom of the channels between Vidcano^ Ltpari^ and Sa- line, entirely volcafiic — The faine obferva- hie of the roots of the Eolian ifes beloiv the water — Gravel and volcafiic find in the channel that divides Panaria fom Lipari~The rocks in the middle of the channels between Saline and Felictida, and between Felicuda and Alicuda, analogous to thofe of the fame ifands, but, probably, priniordial — Dec five proofs deduced from thefe obfervations, that ihefooerls and cry f talU%ed fcltfpars of the lavas have not been ( ^S3 ) heen taken tip by them zvhen in a fiuid Jiatc^ iior formed within them at the time of their congelation — Confrmatlon of thefe proofs — 'The Eollan If es placed hi a dlredl line from eafi to ijoefi — A fimllar direction ohfervable In fome ifands and volcanic monntalns in other countries — Not Impro- bable that all the eight Eollan Ifes were formed at the fame tlme^ and perhaps very fiiddenly^ ivlth refped^ at leaf^ to their frf rudiments — -Explanation of the caufe ijuhy ifands and burnwg mountains are fmetlmes produced dlfpofed in a right line — Materials of the Eollan Ifles^for the mof part^ porphyrltlc — Analyfis made by the author^ proving that the red Egyptian porphyries have not for their bafe the pe- troflcXy but rather the hornfone — En- quiry whether the vltrif cations found In fuch prodigious quantities at Vulcano and Llpai'l^ are found in fimllar quantities in any other volcanic countries — Uncertainty of this from the "want of accurate miner a- logical defcrlptlons of the greater part of vokanos — The accounts given of thein nfually ( '54 ) ufuaJly general and wonderful^ but little injlnicl'ive — Volcanic glafs found in Ice- land^ but by no means in ftifficient quantities to form mountains — No notices of vitrifi- cations in the volcanos of the iflands of Ferro, nor in thofs of Norway and Lap- lafid — Little or no glafs in the volcanized countries of Ger7nany and Hungary — Nor in the extinguifjed volcanos of France — The quantity of vitrif cations at Vefuvius, and fever al other parts of the Neapolitan territory^ more cojfiderable— Scarcely any at Mount Etna, or the volcaitic mountains cf Padua — A more extenfive trad of pU" mices found perhaps in 7io part of Europe than in the ifland of Santorine — This ijland^ hotvever, affords no glafs — Great fcarcity of vitrif cations in the three other quarters of the globe— Concluf on : that Vulcano and Lipari offer a greater abund- ance of glaffes than any other volcanized part of the world ; but that Santorine ex- ceeds them in the quantity of pumices — Enquiries relative to this fcarcity of vitri- fications in volcanos^ whether hur'niv.g or extinEl ( 155 ) ixthiB — // feems to proceed lefs from iht • quality of the fones a^ed on by the vol- fame fire^ than from the i?teficacy of that agent to produce vitrif cation — A fnccef- fively fro7iger degree of heat reqnifite for a fione to pafs from the fate of lava into pumice^ and from that of pumice into per- J'eEi glafs — Elucidation of the caufc why fome volcanos produce pumices^ but not glaffes — The formation , of pumices hitherto not attainable in our furnaces — Blacli the natural colour of pumices ^ which are ren^ dered white by external caufes, Enquiries relative to bafaltes — Thefe origi-- nate i?i the hiunid 'way^ vohen the voord bafalt is underfood in the fenfe in which it was tfed by ihe ancients — ^ he columnar fones which^ from their prifnatic conf- guration^ refemble the bafaltes of the an^ (ients^ originate according to circumfances in the humid or the dry way. — F roofs of their origin in the dry way in Vulcano and FcUcuda — Nature^ in the fofil king^ dom^ produces cryfals as well by the dry 4 'ZC'iTJ ( 156 ) iJDay as by the humid — This exemplijied in the generation of hafaltes — An ahufe of analogy to conclude from it one common origin of bafaltes — When examined de- tached^ they frequently hear no peculiar chara&er of their origin, ivhich mufl be determined from local circumfaiices — jE";/- quiry ivhether bafaltiform lavas have be- come fuch by a fudden coridenfation ivithin the fea — Proofs which fhew, fi^fl-i tk^^ maity bafaltiform lavas have affumed this fymmetrical co?fguratio7t on coagulation in the waters cf the fea ; fecondly, that in others it has taken place only by congelation in the air ; thirdly, that very numerous lavas have proved refraElory to this fgure, both within the fea and in the air — The property of affuming a prifmatic figure ap- pears, in many lavas, not to depend on their being of a particular fpecies, nor on their compacinefs and foUdity, but on extrinfic atid adventitious circumfances — Thefe cir^ currfances indicated, ivith an explanation in 'what manner, according to their pre- fence or abfence, lavas frequently offume a prfmatic ( ^57 ) prifmatic form in the aiVy while others remain irregular within the fea, X HE form, fize, and ftrudure of the Eoiian ifles, the different materials of which they are compofed, and the primordial rocks from which thefe are derived ; the fires which ftill burn in fome, and the pheno- mena and changes which accompany them ; with the comparifon between the prefent conflagrations and thofe of ancient times, conftitute the principal objeds to be confi- dered in writing the volcanic hiftory of fiich a country. And though we have al- ready employed nine chapters on thefe fub- jeds, we conceive the candid reader will not accufe us of extreme prolixity ; both becaufe we have had to treat of {^nqw. iflands, and becaufe our object was to write the I.ithology of this ancient and celebrated country. The prefent chapter, we flatter ourfelves, will, in like manner, be ac- ceptable to the enquiring naturalift, as it contains various obfervations and reflec- tions tions which have a diredt and immediate relation to the deflagrations of the Eolian illes. We have already obferved and defcribed thefe iflands from the fammit to the bafe, which buries itfelf in the waters of the fea. But it was impofiible to examine their internal part in the fame manner as the external ; though the importance of fuch an examination merited that every ef- fort in our power (hould be exerted to ef- fed it. It would be equally interefting and initructive to afcertain the nature of the bottom in thole tra-ilis of fea which fur- round thefe illands, and feparate them one from the other. 1 iball, therefore, here relate whit I obferved with refped to this fubject, and defcribe the methods and inftru^ ments to which I had recourfe to make my obfervations. Where the depth was not great, I found extremely ufeful the large tongs, mentioned by ( 159 ) by Donatl *, furnifhed with (Irong pincers, iixed to one or more bars, which by means of a rope may be clofed or opened at plea- fure, and thus take hold of and bring up any fubftances fromthe bottom. But where the water was deep, I found it more con- venient to employ one of thofe nets which fifhermen ufe to envelop, and tear from the rocks, coral and other fubaqueous bodies. Thefe nets I eafily procured, as coral is fifhed up on thefe coafts ; of which fifliery I fhall treat further in a fubfequent part of this work. Employing, therefore, thefe two inftru- ments, the follow^ing was the refult of my obfervations, which were not made on pieces that lay detached on the bottom, but on fiich as formed a continued whole with it, as was evident from, the recent appear- ance of the fractures where they were broken off. * Saggio fopra la Storia naturale del Mare Adrlatico — Eflay on the Natural Hiftory of the Adriatic Sea. la ( . i6o ) In the channels which divide VuIcanO from Lipari, and Lipari from Saline, the bottom is entirely volcanic, and affords pro- du61:s of the fame fpecles with the two iliores. The fame is obfervable of the foot of the iflands, which foot in fome fituations defcends perpendicularly ; but in others has a confiderable declivity, and thus enlarges the circuit of the ifland. The pieces of lava which I was here able to detach, did not differ from thofe of the fhore, which 1 have already defcribed. But at a greater diftance between illand and ifland this was not the cafe. I made my experiments in three different places. The firil was between Lipari and Panaria ; but here, the water being very deep, I did not fucceed in my attempts to bring up any ftony body from the bed of the fea, but only teflaceous and cruflaceous animals alive or dead, enveloped in fand and gravel, and forming a fpecies of cruft more or lefs thick. The fand and gravel, it is tobe obferved, were volcanic. The ( i6i ) The fecond place in which I made this experiment was between Saline and Felicu- da, and the third between Fellcuda and Aiicuda, in both inftances, at the point of greateft diftance, as nearly as the eye could meafure, between the two iilands. In each of thefe fituations, befides drawing up from the bottom portions of the before-mentioned cruft, I like wife obtained feveral ftony frag- ments, which, from the great force it re- quired to feparate them, and the recent ap- pearance of their fractures, evidently had an immediate communication with the folid and rocky bottom. The whole number of thefe fragments, great and fmall, was ele- ven ; of which four were brought up be- tween Felicuda and Aiicuda, and feven be- tween Saline and Felicuda. The bafe of five * of them was a petrofilex almoft opake, affording fparks wiih fteel, compadt, of a grain a litde fcaly, but fine ; the colour * The author muft here have committed fome mif- take, as he, immediately before, faid the whole number of pieces was eleven, and now mentions ^ve and feven. T. VOL. III. M of ( l62 ) of two of thefe pieces was a light'ifli blue, and that of the three others a grey. The bafe of the feven other pieces was a dark- gi'een horn-ftone moderately hard. None of them differed in their bafe, and fhoerla- ceous and feltfpathofe cryftallizations, from feveral volcanic lavas of the Eolian ifles. Thefe eleven pieces, however, excited in me a ftrong fufpicion that the rocks from which they were detached had not been expofed to the allien of fire. The parti- cles of the petrofilex in them were more clofely united, had greater hardnefs, and a more filiceous appearance, than in the fame ftone of thofe illands which has been fub- jeded to fufion. In like manner, the lavas of a horn-ftone bafe ufually have fomewhat of a fibrous nature, and a thinnefs in their texture which is not feen in the ftone of the fame kind. Thefe two rocks, therefore, appeared to me to be in their natural ftate. I .confider thefe experiments as very in- ftrudive with regard to the origin and formation ( >63 ) formation of thefe iflands. We may con- clude from them : Firft, That the part of the iflands which is buried under the waters of the fea, has fuffered the adlion of the fire in the fame manner with that which is ex- pofed to the eye of the obferver. Second- ly, That Vulcano, Lipari, and Saline form one continued group of volcanized fub- ftances, which, at firft, might probably have one common central conflagration, that, di- viding into three branches, and affording a pafTage to three diftindt mouths, gave birth to three iflands, which conflagration, by fubaltern and fucceffive ramifications, and ejedions of new matters, afterwards in- creafed in extent. No fenfible remains, in- deed, of fuch a fire are at prefent difcover- able in the internal parts of SaUne, nor are any phferva-ble in Lipari, its whole effi- cacy appearing to be confined to Vulcano. Thirdly, That Alicuda, Felicuda, and Saline do not appear to have any volcanic commu- nication with each other, at leaft in the parts that form the bed of the fea, which feparates thefe three iflands from each other ; M 2 lince ( '64 ) fince thofe parts, as far as the eye can per- ceive, fliew no figns of the adion of fire. Fourthly, That thefe three Ifiands, and per- haps hkevvife Stromboli, are fituated in the vicinity of analogous but primitive rocks* The perfedl refemblance of the fhoerls and feltfpars in thefe rocks, both in thofe that have fuflered change from the fire and thofe that have not, is a demonftration that thefe cryftallizations have not been taken up by the lavas when they flowed in currents, nor formed in them at the time of their congelation. From the very beginning of this work, I have adduced fads of the fame nature, which I have the fatisfa£lion to confirm by the prefent ; and which become of the greater importance, as I have lately read that a naturaUft of eminence inclines to be- lieve that the fhoerls of lavas are formed when the latter ccndenfe and become cold, becaufe then the homogeneous molecules feparate from the heterogeneous, and unite by affinity in fmall cryftallized mafles. This ( i^S ) This ingenious theory is not only contra- dided by the obfervation made above, but ap- pears to me not to accord with the ufual ope- rations of Nature. Were it well founded, I can perceive no reafon why the fhoerls in lavas fhould not re-appear after they have been fufed within them in the furnace, and, being removed into a cold place, have acquired their former hardnefs. But though I made experiments with fire on fome thoufands of pieces of lava, not one of them re-produced its fhoerls, though many were continued a long time in a ftate of fufion, and afterwards fufFered quietly and flowly to cool and confolidate ; v;hich two circumftances are known to favour the formation of cryftallizations. Shoerls were, indeed, fometimes found in the lavas, after fufion, when cooled and hardened ; but thefe had proved refradory to the fire ; as appear- ed on expofmg them again to the furnace detached from the lava. The eleven pieces of primordial rock M 3 broken ( i66 ) broken from the bottom, exhibited in the furnace the f^jme changes with their conge- nerous lavas expofed to the fame fire : the feltfpars, however, remained refractory. The Lipari iflands extend in a right line from eaft to weft the diftance of about fifty- miles, except that Vulcano makes a fmall angle. Strombcli is the firft to the eaft, and Aiicuda the laft to the weft. This is not the only inftance of volcanos having produced iflands, or rather mountains, ar- ranged in a rectilinear diredion. We find an example of this in the Moluccas, which are the produce of fubterranean fires, and placed one beyond the other in a right line, When, in 1707, a new iftand was thrown up by a fubmarine volcano, in the Archipelago, near San:orine, other fmall iflands arofe from the fea near it, to the number of fe- venteen, in a right line, forming, as it were, a long chain of black and dark rocks, which vifibly increafed in dimenfions and height, and, approaching each other, at length united. ( '67 ) united, and, joining that which firft arofe from the water, formed one fmgle illand*. Another memorable inftance of this di- reftion of volcanic mountains (for illands are in fad only mountains buried in part under water) is the, produdion of feven lefTer mountains by the eruption of Vefu- vius in 1760 ; the account of the formation of v/hlch, as it may throw fome light on that of the Eolian ifles, I fhall here give, from the accurate relation of ProfefTor Bot- tis, an ocular witnefs. After repeated concuflions of the earth, which were felt fifteen miles round Vefu- vius, the fides of the fiery mountain opened in the territory of the Torre del Greco, and fifteen volcanos appeared, eight of which were foon after covered by a torrent of lava, which ra(hed from one of them ; the other feven remaining entire, and incefiantly ejed- ing from their mouths vaft quantities of ig- * Vallifneri Opcr. fol. t. i\, M 4 nitedl { i68 ) nited fubftaiices, which falling almoft per-^ pendicularly around the volcanos, produced, in the fhort fpace of ten days, feven fmall mountains, of various heights, difpofed in a right line. During thefe ejedions, the noife which accompanied them fometimes refem- bled that of violent thunder, and at others the difcharge of a number of cannons. Se- veral of the burning ftones, even the largefl, were thrown to the height of nine hundred and fixty feet, and fome fell at a confider- able diftance from the mouth whence they were thrown. Thefe erudtations ihook all the neighbouring country, and the roarings of the mountain were dreadful to the inha- bitants. After the tenth day, the eruptions ceafed, and the newly-formed mountains, gradually cooling, permitted a nearer ap- proach ; when fome were found to have at their fummit a cavity refembling an invert- ed funnel, and others a fimple hollow, of greater or lefs depth. The produdion of the Eolian ifles being anterior to the records of hiftory, we know not ( i69 ) not whether this took place at one time, or in different periods. The relation, however, juft cited, of the origin of the feven Vefu- vjan mountains clearly proves the poffibility of their being produced at the fame time. It alfo proves, that the whole eight might be formed in no long fpace of time, with refpeG: at lead to their firft rudiments, it having been feen that thev have received fucceffive additions. We alfo evidently perceive, that the in- flammable fubftances generative of the Mo- luccas in Afia, of the chain of iflands at San- torine, of the Vefavian mountains above defcribed, and of the Eolian ifles, have formed a dired: fubterranean zone incompa- rably longer than broad. This phenome- non may be explained by recurring to the clefts and fiflures perpendicular to the hori- zon, exifting in many places w^ithin the earth, as well in foft fubftances as in the more durable and folid ; within which clefts fliould fubftances proper for the produdion of ( ^jo ) of volcanos be found in abundance, and be- come inflamed, in feparate heaps, burning mountains would arife, in a diredt line, and more or lefs large, according to the quantity of the ejeded matters. From the particular defcriptions of the iflands of Lipari, we Jiave feen that the combuftible fubftances which have produced them have fometimes been contained within granite, as at Panaria and Bafiluzzo, but for the moft part within rocks which have for their bafe the petrofilex, the horn-ftone, and the fcltfpar. It likewife appears, from the obfervations made at Stromboli, that, even there, thefe burning fubftances have their feat in the horn-ftone rock, though, from the fize of the ifland they have produced, they muft undoubtedly be buried at an im- menfe depth. If we would fimplify the fads relative to the materials of ail thefe illands, we (hall find that they are for the greater part porphyritic ; as are likewife foine of thofe fubmarine trads, apparently not <*a. ( 171 ) not touched by the fire, and placed among them ; as has been fhewn above *. When I compared the effeds of the fur- nace on volcanized porphyritic rocks with thofe it produces on the natural, I men- tioned fome red Egyptian porphyries, the bafe of which I believed to be horn-ftone, rather than petrofilex, relying on the ana- lyfes of Bayen, as related by Delametherie, of an Egyptian porphyry of the fame co- lour, and fimilar to thofe on which I made my experiments f. But not having then been able to analyfe them, from want of time, I determined to do it afterwards, and give an account of the refult, in another part of this work, when I fhould again have occafion to fpeak of this fpecies of volcanic reck. I fhall here give this analyfis, which affords a confirmation that the bafe of thefe porphyries is not petrofilex, as they contain magnefia, which is not found in that flone. * See the Note at page 82, Chap. XI, in wliich I have fpoken of the efTential characlers of porphyry, t See Chap. XI. Z From ( 172 ) From this circumftance, and the nature of their conftituent principles, their bafe ought rather to be called a horn-ftone, of the na- ture of which it at lead participates. This analytical obfervation is likewife here very opportune, as it is an additional proof that I have properly called porphyritic the lavas with a horn-ftone bafe, and containing felt- fpars, which are fo numerous in thefe iflands. The red Egyptian porphyries which I analyfed are of two fpecies ; the firft has been defcribed at page ii8 of Vol. JI. : the fecond differs only in its colour being of a lefs lively red, and in the abundance of its feltfpars. It is evident, that to render this experiment accurate, the fubftance of thefe two ftones fhould be firft freed from the Ihoerls and feltfpars which they con- tain. Firjl Specks. Sllex, fomewhat reddifh, - 80 Alumine - - - 7 Lime - - "3 Magnefia { V3 ) Magnefia 2 Iron ' - . 6 Second Species. Silex - 8i Alumine - n Lime - 4 Magnefia 2 Iron - 4i Befides the porphyritic lavas with which the Eolian ifles abound, we have feen that they contain great quantities of tufas ; and thatStromboU is diftinguiihed from the other iflands not only by its volcano, but by the beautiful fpecular iron it affords ; and Lipari by its chryfolites and zeolites, but ftill more by the prodigious quantities of pumices and glaifes which it contains. I cannot, indeed, refled: on thofe enormous mafles of vitrifica- tions, without renewed wonder ; which has been ftill more increafed by the difcovery, by means of the forceps and coral net, that thefe vitrifications are continued from Li- pari, till they join thofe of Vulcano, v/hich. ( '74 ) on the north and north-eaft fide abounds in pumices, enamels, and glafles. The vitre- ous fubftances,- therefore, of this ifland, and thofe of Lipari, which, as has been faid, oc- cupy about two-thirds of the latter, compofe an accumulation of glafs, not lefs than fif- teen miles in circuit. It is impofTible to at- tend to this flupendous phenomenon with- out feeling our curiofity excited to know whether it be peculiar to thefe iflands, or found likewife in other volcanized countries. But fatisfa£loriIy to anfwer fuch a queftion, it would be requifite that we fhould be ac- quainted with the volcanic mineralogy of all the volcanos in the world ; not only thofe at prefent burning, but thofe extinguiilied, which are infinitely more numerous ; in the fame manner as we are with that of Viva- rais and Velay, the iflands of Ponza, Vefu- vius, Etna, the Eolian ifles, and the moun- tains of Old-Brifach, by the labours of Fau- jas, Gioeni, Dolomieu, Dietrich, and myfelf. Of fuch a mineralogy, how^ever, we are entirely deftitute. The greater part of thofe who, either by chance, or from curiofity, ~ - have { '75 ) have viewed burning volcanos, have only defcribed in their relations the moft com- mon and general phenomena, lefs adapted to increafe the knowledge than to amufe the imagination of their readers, and excite their wonder Shocks and undulations of the earth — the fea in commotion, and raging without a tempeft ; here retiring and leav- ing its ftiores dry, and there inundating vaft tracts of land — fubterranean thunders, and roarings in the air above — the fun difappear- ing in thick darknefs at noon — whirhvinds of fmoke, afhes, and flame, burfting from the yawning gulf — burning ftones hurled towards heaven, and falling in a fiery hail — torrents and rivers of liquid lava, fulphur, and bitumen, pouring down on the valleys below, and carrying terror, defolation, and death — iflands, now fuddenly produced by fubmarine eructations, and now torn from their foundations, and fwallowed up by earthquakes thefe compofe the ufual de- fcrlptions of volcanos, which, though they may not be ufelefs when the fads are faith- fully ftated, and not magnifred by the ima- gination ( i7« ) ginadon of the narrator; yet they common- ly v*^ant one eflential requlfite ; that is, li- thological deicriptions of the bodies ejeded by thefe burning mountains. As glafs and pumices, however, are known even to thofe who are unacquainted with this part of na- tural fciencc, we may, with certainty, or, at leaft, with the ftrongell probabihty, con- elude, that they are produced by the volca- nos in the defcriptions of which we find them exprefsly mentioned as making a part of the ejedled matters, and that they are not produced when not mentioned. Thus in Iceland, the greater part of which ifland is only an accumulation of volcanos either ex- tindt or adive, it is certain, from the ac- counts of travellers, that numerous glafTes ace found, to which the name of Icelandic agate has improperly been given, only be- caufe they have the luftre and beauty of that ftone. The prefent eruptions of this ifland, likewife, not unfrequently contain pumices ; but no perfon has ever afTerted that there are entire mountains of thefe ftones, or of glafles. S The ( 1/7 ) The Iflands of Ferro are confidered as volcanic, and produce the famous zeolites, mixed, as it is faid, with lava ; but as yet we know nothing more of them. The minute account of each of thefe feventeen illand^, publiflied by Jacobfon Debes, in which no mention is made of the vitrifications, authorizes us to conclude they do not exift there. Norway and Lapland have their volcanos, which from time to time burft forth in fearful eruptions, according to the accounts of Pennant and others, who, however, give us no further information. Leaving thefe cold regions, and pafling to Germany and Hungary, we find fome trads of thefe countries that have like- wife been fubjeded to fubterranean confla- grations, which, however, have produced no vitrifications, or fcarcely any. " I have fought in vain the black agate of Iceland, and the true pumice," fays the above-cited Baron Dietrich, in his long and circumftan- VOL, III. N tial ( 178 ) ilai Memoir relative to the volcanos near Old-Brifach, t Proceeding to a milder cliniate, and ap- proaching nearer to our own country, we find that the extlnft volcanos of France af- ford no pumices or glalTes ; which affertion I can make on the authcrity of M. FaujaSy who has written fo well concerning them, than which one more unqueftionable cannot be adduced. It is not the fame with Italy ; the coiin- -try in which fire has principally extended its empire. The Neapolitan territory pe- culiarly abounds in pumices, enamels, and glalTes, as appears in the iflands of Ponza, at Herculaneum, Pompeii, Mifeno, Monte Nuovo, the Rock of Burnt Stones, Proci- da, Ifchia, and the valley of Metelona *. Even in our times Vefuvius has ejected fimilar bodies ; but, with refpedt to Etna, its fires rarely produce the fllghteft vitri- fication, ' * Sec Chaps. IV, V, VI. The ( ^79 ) The only place in Europe, which, in the abiindiince of its pumices, can equal, or perhaps furpafs Lipari, is the ifland of San- torine. On this fubjedt we may confalt Thevenot and Tournefort, two intelligent travellers, who at different periods examined this ifland, which has not hitherto, to my knowledge, been conlidered by volcanifts in this point of view. The former, who vifited Santorine in 1655, obferves, that " many of the inha- bitants live in caves, made under the earth, which is extremely light, and eafily dug into, as it confifts entirely of pumices." He afterwards relates a fad:, which has a particular relation to our prefent fubjed:, fince it teaches us in what manner thefe light flones may be thrown up, immediately by the fea, in volcanic eruptions. His ac- count is as follows : " About eighteen years ago, oh a Sunday ^' night, a violent noife began to be heard *' in the port of Santorine, which was like- N 2 ** wife ( i8o ) " wile heard even to Chios, dlftant more *' 'than two hundred miles, and was tliought " to be occafioned by the Venetian fleet *' having engaged the Turks ; in confe- " quence of which great numbers of people *' got upon the higheil places early in the '* morning, to be fpectators of the battle ; " and I remember the Reverend Father *' Bernardo, a venerable man, perfeclly de- " ferving credit, told me he was one among *' the number of thofe who were fo de- *' ceived, imagining they heard a violent *' cannonade. They could however fee no- '• thing. In fad:, this noife was caufed by " a fire kindled in the earth, under the har- *■ hour, the effect of which w^as, that from " the morning to the evening a vaft quan- *' tity of pumices role from the bottom of " the fea, with fuch violence and noife as to *' refemble repeated difcharges of cannon, *' and fo infedled the air that feveral perfons *' died at Santorine, and many loft their '' fight, which they did not recover till ^' fome days after. This infedion extended " as far as the noife which had preceded it had " been ( >8i ) *' been heard j fince not only in this illand, ** but at Chios and Smyrna, all the filver " became red, whether kept in coffers or " in the pocket ; and the religious who re- *' Tided there told me that all their chalices " became red. After fome days the infec- " tion ceafed, and the filver returned to its " former colour. " The pumices which were thrown up *' covered the Archipelago in fuch a man- " ner, that, for fome time, when certain " winds prevailed, the harbours were i^o '* blocked with them, that not even the ** fmalleft veflels could get out till a way *' was made for them by removing the " pumices v^ith long poles, and they are " ftill feen fcattered over the whole Medi- *' terranean, though in a fmall quantity *.'* Tournef(pit, after having remarked from Herodotus that Santorine was once called KaA/.i7-;i or " the moft beautiful ifland," adds, that " its ancient inhabitants would * Voyages de INI. de Thevenot, Prem. Part. N 3 " not ( l82 ) " not at prefent know it, fmce it is covered *' with pumices, or, more properly, is a " mine of thofe ftones, which may be cut " into great fquare blocks, as other ftones *' are cut in the quarries *." According to this traveller and to The- venot, Santorine is thirty- fix miles in cir- cuit ; v/hence it appears what a prodigious accumulation of pumices there muft be in this illand and the adjacent fea. It merits notice, however, that neither thefe two travellers, nor others who have written of Santorine, make the leaft mention of glaifes of any kind ; we may therefore venture to affirm that the fubterraneous fires have, there, never produced them. If from Europe we pafs to the three other quarters of the globe, we fhall find in each a great number of volcanos, which it w^ould be fuperfluous to enumerate par- ticularly, fuch an enumeration having al- * Voyage du Levant. ready ( i83 ) ready been made by Faujas, BufFon and others. I fliall only mention thofe which afford prodii<5ts that have relation to our prefent fubjeiSt. We read that the iiland of Ternate, in Afia, throws out a confiderable quantity of pumices, as does, likev/ife, one of the nu- merous volcanos of Kamfchatka. As to thofe of Africa, we have but very imperfecl accounts of them, with the fingle exception of the peak of Teneriffe, one of the loftiefl: of volcanos ; which, with refpe(ft to its fituation, height, form, and crater, and the hot fumes which iffue from it, has been accurately defcribed by the Chevalier Borda. But it were to be wi{hed that we had a more complete defcription of the, materials of which it is compofed ; as the French traveller only tells us that they are ^' fand, black and red calcined Itones, pu- •^ mices, and flints of different kinds *." '•■^ Voyage en diverfes Parties de FEurope. N4 It ( J84 ) It admits of no doubt that the highefl mountains of America, as Chimboraco, Col- topaxi, Sangai, Pichencha, &c. form a chain of burning volcanos, the largeft exifting in nature. We are indebted for the accounts we have of them to M. Bouguer ; but thefe are fuch as only tend flrongly to excite our curiofity without gratifj^ing it. With refped: to what relates to our prefent en- quiry, we only learn from this writer, that " fome mountains in the vicinity of Quito " are compofed entirely, to a great depth, " of fcorise, pumices, and fragments of " burnt ftones of every fize *." As to volcanic glaffes, he does not make the flight- eft mention of them ; though it is well known that the famous gallinaceous ftone, which is univerfdly acknowledged to be a moft beautiful American volcanic glafs, of a black colour, is found in Peru, and that, according to M. Godin, there is a mine of it, feveral days journey from Quito. * Acad. Royale des Sciences, J 7 44. If ( '85 ) If we now confider thofe parts of thefc imperfecl accounts which relate to glaffes and pumices, we fhall find, with refpedl to the former, that the much greater part of volcanos produce none, and that thofe which do produce them, as in the Neapoli- tan territory, Iceland, and Peru, are by no means to be compared in this refpe£t with Lipari and Vulcano. The fame may be aflerted of Alicuda and Felicuda, the glafles of which, though abundant in many parts of thofe illands, are only found in flakes and fragments. Thefe obfervations might like- wife be applied to the pumices, did not the immenfe quantity of them in the ifland of Santorine equal, if not exceed, that of the two Eoljan iflands above mentioned. If we confider the volcanos known to us under one general point of view, we fiiall find that, though they have changed into lavas an infinity of rocks, by which they have produced mountains and iflands very confiderable both in number and dimen- fi ons, it is very rarely that they vitrify the 7 fubftances ( i86 ) fubftances expofed to their fires. Reflect-' ing on the immenfe quantities of vitrifica- tions at Vulcano and Lipari, which are almoft all derived from feltfpars and petro- filex, the idea fuggefted irfelf to mv mind, whether fo great an abundance in thefe two places, and fo great a fcarcity in others, might not be attributed to thefe ftones be- ing here extremely abundant, and very rare elfevvhere. But this fuppofition does not accord v/ith fa£t ; as we have (e^n. in many other volcanic tradts, which I have defcribed, and fhall defcribe when I come to fpeak of the Euganean mountains, that both thefe ftones may be changed into lava without that lava exhibiting the fiighteft appearance of glafs. On the other hand we have fliown, that, befides feitfpar and petrofilex, many pumices have for their bafe the horn- ftone and afbeilus, and many granite, as M. Dolomieu has obferved. I am, there- fore, of opinion that the caufe which has produced them lliould rather be fought in the volcanic fire, which rarely has fufficient a6:ivity to vitrify the ftones and rocks on which ( i87 } which it exerts Its power ; though I grant that the petrofiiex and feltfpar are more adapted to this vitrification than other flones. To produce a lava, a certain de- gree of heat Is neceffary ; and a ftill greater to convert it into pumice. The lavas, at leaft thofe of the compad; fpecies, ufually preferve the grain, hardnefs, and fometimes the weight and colour of the primordial rock ; but the greater part of thefe external qualities difappear in the pumice, from the ftronger adlion of the fire. This muft operate ilill more in glafs, in which the ho- mogeneity and finenefs of the pafte efface every trace of its primitive texture. Thefe gradual tranfitions of lava into pumice, and pumice into glafs, I have feve- ral times obferved, and indeed have already defcribed, in the fame volcanic piece. It has alfo been obferved, that a lava frequent- ly paffes immediately into perfed; glafs, which muft be caufed by a fudden heat, greater than that required to change it into pumice. This theory fatisfadorily explains why C «8S ) wliy fome volcanos produce pumices, but never glafs ; as may be remarked of Santo- rine. Their fires are only fufficiently powerful to generate pumices, but not to produce glafs ; an obfervation applicable to the prodigious eruption from the fea de- fcribed by Thevenot. On the contrary, at Rotaro in Ifchia, at Vefuvius, and other parts of the Phlegrsan Fields, as alfo at Vulcano, Lipari, Felicuda, and Alicuda, glafTes are found mixed with lavas ; which fhews that the fire has aded unequally ia thofe places. It is to be remarked, at the fame time, that the heat requifite for vitrifi- cation is not of the moft violent kind, as I have {hewn in Chap. XVI. We muft however obferve, that as the produdlion of ccmpa£l: lavas is a fecret which Nature has hitherto referved to her- felf ; fmce v/e are unable to imitate them with our common fires ; fo alfo are we ignorant of the preciie caufes of the forma- tion of pumices. Among iome thoufands of fufions which I have made in the fur- nace. ( iS9 ) nace, both of lavas and primordial rocks and ftones, thofe likewife from which pu- mices are moft frequently produced, as pe- troiil^ces and feltfpars, I never obtained a product which could be faid to poffefs all the charad;eriftics of pumice. It has al- ways been either a glafs, an enamel, or fcoris ; nor do I remember to have read or heard, that among the innumerable ex- periments which chemifts have made upon earths with fire, the refult ever was a true pumice : and though in lime-furnaces we may frequently obferve a change of certain ftones into glafs ; yet they never produce lavas fimilar to the volcanic ; and equally incapable are they to form pumices. It cannot be alleged that the fire of our fur- naces is too ftrong to induce that flight de- gree of vitrification which characterizes pumices ; fince, when I have ufed a more moderate fire, the fubfi:ances on w^hich I made my experim,ents have either not melted, or been more or lefs vitrified. I (hall conclude thefe obfervatlons on the pumices ( I90 ) pumices of LIpari with a remark relative to their colour. Except a few that are dark, they are all white as fnow. Hence the mcuntaiii of Lipari, which forms the great magazine of thefe ftones, is called Campo B'uvico (the White Field) : but cer- tainly there muft have been a time when it fliould have been denominated Campo Nero (the Black Field) ; at leaft it is certain that pumices when newly ejeded from volcanos are of a black colour. This re- mark, which has been omitted by almoft all who have made obfervations on this fubjed, who content themfelves with faying that this or the other volcano throws out pumices, has been exprefsly made by Don Gaetano de Bottls in his " Hiftory of the Conflagrations of Vefuvius *." He tells us, the pumices ejeded at various periods by this volcano are black. He likewife remarks, that on comparing them with thofe which overwhelmed Pompeii, he found them perfedly fimilar in their ftrudure. * Iftcria di varj Incendj del Vefuvlo. Their ( I90 Tiieir whitenefs was fubfequently acquired, and probably was caufed by the impreffions of the atmofphere. Before I conclude thefe obfervatlons on the Eolian ifles, I think it neceffary to fay a few words on a fubjedl which has a re- lation to the productions of Vulcano and AHcuda, and on which the opinions of modern naturalifts are divided ; I mean the bafahiform lavas which are found within the crater of the former ifland, and along the fhores of the latter *, and which by their conformation cannot but remind the reader of the enquiries and difputes which have taken place wdthin thefe few years relative to the orifrin of bafaltes. To re- o peat all that has been written on the fubjed: would fill a volume ; but I am far from purpofing to tire either my own or the reader's patience in any fuch manner. It, befides, appears to me that this long agitated queftion may, at prefent, be determined * See Chaps. XIII and XVII. without ( 192 ) without any very prolix argumentation. Literary diiputes and differences of opinion frequently arife from want of previoufly fixing the ftate of the controverfy ; that is, from not defining in precife and clear terms the thing in queftion. Before we enquire what is the origin of bafaltes, that is to fay, whether they are the refult of the adtion of fire or water, it will be proper to de- cide what we mean by the term ; or ra- ther what the ancients underftood by this "word, which is the name they gave to a certain kind of flones. It is now generally known, becaufe it has been repeated by a hundred writers, though perhaps by the greater part without due confi deration, that the word bafaltes is ufed by Pliny and Stra- bo to denominate an opake and folid ftone, of the hardnefs, and nearly of the colour, of iron, commonly configurated in prifms, and originally brought from Ethiopia ; of which flone the Egyptians made fi:atues, far- coph-^gi, mortars, and various utenfils. This premifed, it remains to enquire whether this ftone was of volcanic origin or net, by ( m ) Ly repairing to the places where it was found, and attentively examining the coun- try to difcover whether it bears the cha-* radteriftics of volcanization. This labour^ however, has not, to my knowledge, been hitherto undertaken by any one ; but M. Dolomieu, to whom Lithology and the Hiftory of Voleanos are fo much indebted, has difcovered, during his ftay at Rome^ ail equivalent, in fome meafure, vvith re- fpedl to the folution of this queftion. Among the many noble monuments in that fuperb capital which are inftru£tive not on- ly to the admirers of the arts, but to the contemplators of nature, are a great number of ftatues, farcophagi, and mortars brought from Egypt, v/hich have all the charaders attributed to bafaltes, and llkewife preferve the name. Thefe he has ftudied with the greateft attention, and declares that the llone of which they are formed manifefts no fign of the adion of fire. Among other Egyptian monuments, he obferved fome of a green bafaltes, which change co- lour, and aifume a brown tinge, fimilar to VOL. III. O that ( 194 ) that of bronze, on being expofed to the flightefl heat. All thofe that have been burned have acquired this colour ; which proves, as he very judicioufly ohferves, that the green bafaltes have never fuffered the adion of fire *. The Egyptian ftones, therefore, to which the ancients gave the appellation of bafaltes, have been produced by Nature in the humid way. Thefe obfervations perfectly agree with thofe of Bergmann on the trapps produced in the fame way ; and which have, both externally and internally, the fame charaderiftics with the bafaltes t. Werner, taking the term bafaltes in a %vider fenfe, and underftanding by it all thofe columnar ftones which, by their prif- matic configuration, refemble the Egyptian bafaltes, fuppofes both to have the fame origin, and adduces, as a proof of that ori- gin, the bafaltes of the hill of Scheibenberg, * Rozier, torn, xxxvli. an. 1790. t De Produclls Vulcanicis. which - i 195 ) Ivhich are the efFedl of a precipitation by means of water ; and concludes that " ail bafaltes are formed in the humid way ^K^^ Though I am willing to beftovv the pralfe due to his difcovery, I cannot admit his conclufion ; for though many bafaltes, taking that term in the fenfe of this author and other naturalifts, may derive their ori- gin from water, many others are certainly the produdl of fire. I fhall not repeat what various v'olcanifts have written on this fubjed, but merely refer the reader to what I have already faid relative to the bafaltine lavas of Vulcano and Felicuda. With refped to the former ifland, I have remarked, in Chap. XIII, that I found within its crater a range of articulated prifms, with unequal fides and angles, which, in part, compofed one whole with a mafs of lava ; and, in part, were detached from it. 1 have alfo there * Rozleri torn, xxxvili. an. lypi* O 2 defcribe4 ( 196 ) defcribed the qualities and nature of tliefeJ pi'ifms. In Chap. XVII 1 have particular- ly defcribed the literal lavas of Felicuda, which, near the water, are prifmatic. It is therefore evident, thatj in thefe two fituations, the origin of the bafaltes there found cannot be what it has been aflumed, generally, by Werner and ether Germans, but that it is truly volcanic. It confe- o quently appears that Nature obtains the fame effed by two different ways. In the fofhl kingdom, one of her grand operations is cryftallization ; which, though it be mofl frequently effected in the humid way, is fometimes produced in the dry ; as we fee, among other inftances, in iron, which Na- ture cryftallizes within the earth, both by the means of water and of fire, in which latter way the beautiful fpecular iron of Stromboli is produced *. Nor are there wanting other inftances, of the cryftalliza- tion of the fame metal by the adion of fire. * See Chap. XI. And ( 197 ) And did other metals exlft In the entrails of volcanos, and the neceflary clrcumftances concur to their cryftalUzation, it Is Indubi- table that this may be effedled by fire as well as by water. Thus we fee that, by taking certain precautions, metalHc fub- ftances afliime a regular and fymmetrical difpofition within the crucible. The fame Is true of bafaltes, the prifmatic configu- ration of which, though not ftridly a cry- ftallization, has the moft exad: refemblance to it. Obfervation, llkewife, teaches us that the fame combination of earths, ac- cording to different circumflances, forms prifmatic bafaltes, fometimes in the humid, and fometimes in the dry way. The flone called trapp, found In the mountains of Sweden, is configurated in prifms, though thofe mountains are of aqueous origin ; and the horn-ftone, which is fo analogous to the trapp, has the fame configuration at Fe- licuda, notwithflanding it is a true lava. In the fame Ifland, likewife, other bafalti- form lavas have for their bafe fhoeri ia mafs, and thofe of the crater of Vulcano, O 3 the ( '98 ) the petrofilex ; which two flones, according to the obfervations of M. Dolomieu, form fome of the Egyptian bafaltes, which are a work of the waters. Thefe two agents, fire and water, are not, in fa£t, fo different in their aCcion as we might at firft be in- clined to imagine. The prifmatic figure in the humid way arifes in the foft earth by the evaporation of the water ; in confe- quence of which the parts dry, contrail their volume, and fplit into polygonal pieces. The fame phenomenon may be remarked in margaceous earths, imbued with water, and expofed to the ventilation of the air ; and I have frequently feen the mud of rivers, when dried in the fun, in fummer, to make pottery-ware, divide, when it became dry, into fmall polyedrous tablets. Similar configurations are pro- duced in different lavas by the congelation and contraction that take place by the pri-. vation of the fire which held them in a flate of fluidity. It appears to me, therefore, that the dlf- pute ( 199 ) pute relative to the origin of bafaltes is at an end ; nor would there be any difference of opinion if, inftead of generalizing ideas and fabricating fyftems, naturallfts would make an impartial ufe of their own obfef va- tlons and thofe of others. Some volcanlfts, perceiving that the generation of various bafaltes is evidently igneous, have immedi- ately inferred that all muft have the fame origin. In confequ^nce of this principle, they have drawn lines or zones, in different parts of the globe, indicative of extln(St vol- canos, which they have inferred from find- ing bafaltes there ; and thus pourtrayed a pidure of prodigious dimenfions, repre- fenting the ruins caufed in the world by fubterranean conflagrations. Other natu- rallfts, on the contrary, being convinced that certain bafaltes are the produce of w^ater, have affigned to all the fame origin. From the fad:s now adduced, it is, however, fufficiently evident that both thefe hypothe- fes are erroneous. The bafaltes, taking the term generally, when examined de- tached, do not bear exclufively any declfive O 4 marks ( (200 ) inarks of their origin. Local circumftance^ alone can determine to which of the two principles it is to be afcribed ; to difcover ^?vhich we muit attentively examine whether the places where thefe figured ftones are found exhibit any indubitable figns of vol- canization. Yet even thefe are frequently not fufficient, as there are many hills and mountains which owe their origin to both the great agents of nature, fire and water j in w^hich cafe it will be neceffary to re- double our attention, and fix it on the fub- ftances originating from each ; to deter- mine, by the relations thefe have to the ba- faltes, from which of the two the latter de- rive their formation. By diligently em- ploying thefe means, we fliall be certain, without fear of error, to elucidate and ad- vance the enquiries relative to baialtes, and be enabled accurately to determine which of them are to be afcribed to the adlion of water, and which to that of fire. But here a fecond queftion occurs, not lefs interefting than the firft, relative to the caufe ( 201 ) caiife why certain lavas, differing from in- numerable others, become bafahiform; fmce, if this configuration depended on conge- lation, it muft be found in all lavas when they had ceafed to flow. The firft writer, to my knowledge, who has adverted to this is M. de Luc, who, in the fecond vo- lume of his Travels, is of opinion that they have taken this regular figure in the fea, by the fudden condenfation which took place on their flowing into it in a liquid fl;ate ; other fecondary circumflances, how- ever, concurring, fuch as a greater homo- geneity, and a certain attradion of their parts. Of the fime opinion is M. Dolomieu ; though he does not deny that even porous lavas may fometimes, likewife, take the form of prifns. The former of thefe opi- nions is little lefs than hypothetic, while the latter is fupported by fads too import-^ ant to be curibrily fl:ated. M. Dolomieu obferves that all the currents of the lavas of Etna, the periods of which are preferved in hi (lory, (203) hiilory, have conllantly experienced two effects in their congelation. Thofe which have cooled in the air, have divided, in confequcnce of the contradion they have fuf- fered by the lofs of their caloric (heat , into irregular mafles ; while aK the others, which have precipitated into the fea, have, on their fudden congelation, contracted in a regular form, and divided into prifmatic columns, which form they have only taken in the parts in contact with the water of the fea. Of this he met with evident proofs along the fhore which extends from Catania to Caftello di Jaci ; and the famous lava of 1669, though unapt to the prifmatic form, from being fpungy and little in qMr-ntity, yet in fome parts exhibits a kind of rude imperfed; prifms. Among the objeds to which I was at- tentive in my volcanic travels through the two Sicilies, the prifmatic lavas were cer- tainly not the lad. While making the cir- cuit or the Eolian iflands, of Etna and of Ifchia, 1 conftantly obferved carefully the CQnformatlcn of the flony currents which fall ( 203 ) £ill into the fea. I have remarked, when treaiing of Ifchia, that this configuration 13 frequently prlfmatic, and that the prlfms are conftantly formed In thole parts of the currents which immerge into the water, and reach to a few feet above the level. This obfervation of mine certainly accords admirably with thofe of M. Dolomieu ; the fituation of thefe prifms clearly fliowing that they were formed at the time of the immerfion of the lava into the fea, Vx^hich, when it flowed, rofe to where they begin to appear. But, though I agree with him in this, I cannot in the remainder of my obfervations. Alicuda, as v/ell as Felicud.i, prefents us with numerous currents and rocks that defcend into the fea ; and they are likewife found at Saline, Lipari, Strom- boli, Panaria, JBafiluzzo, and Vulcano ; but thefe rocks and currents, which to- gether extend over a fpace of more than fixty miles, do not aiford the flighteft indi- cation of prifms. As I went by fea from Meffina to Cata- nia, ( 204 ) nla, and returned to Meflina from Catania, I had an opportunity twice to examine, at my leifure, that tra6t of fhore, which, for the fpace of nearly three-and-twenty miles, is volcanic. One third of it, beginning at Catania, and proceeding to Caftello di Jaci, confills of prifms more or lefs charadierized, and fuch as they have been defcribed by M. Dolomieu j but the other two thirds, though equally compofed of lavas with the former, and for the moft part falling per- pendicularly into the fea, have no fuch figure ; and only prefent, here and there, irregular fiflTures and angular pieces, fuch as are, generally, obfervable in all lavas, which feparate m^ore or lefs on their conge-" lation. In my circuit by fea round the fhores of Ifchia, I was particularly attentive, as I was every where elfe, to the conformation of the lavas ; and here there feemed a great probability of finding them prifmatic, from the abundance of them which in different dire(^cions and angles fall into the ( 265 ) the fea : but I have already obferved, wheti treating of the ifland, and I now repeat it, that I did not find one with a regular form. At Naples, the prifmatic lavas of the currents of Vefuvius, under the Park of Por- ticl, have been much fpoken of. When I made my cbfen^ations on this burning mountain, I had not time to vifit thefe la- vas. It is with great pleafure, therefore, that I learn they have been examined by a perfon fo well experienced in matters of this nature as the Chevalier Gioeni un- doubtedly is. But the celebrated prifms difapppeared in the prefence of fo accurate an obferver. The following is the account he gives ; which is of confiderable import- ance to our prefent fubjed: : — " I wifhed " to examine the bafaltes which were " pointed out to me as to be found on the " fea-fhore, under the Royal Park of Por- " tici ; but they proved to be only a com- " pa(ft lava, with perpendicular and ex- ** tremely irregular fiffares, forming qua- " drangular. ( 206 ) *' drangular, and fometimes trapezoidal pU " lafters, which have been employed in " buildings. Similar fiflures are likewife *' obferved in tufas, and earths of different " kinds, and can never miflead any perfon " accuftomed to them, and acquainted with •' their true caufes." By this faithful relation of fads, I flatter myfelf, I have clearly fhown that it cannot be fupported as a general hypothefis, that flowing lavas take a prifmatical configura-^ tion from the fudden coagulation they fuffer on falling into the fea. It may, perhaps, be objected, that thefe prifms once exifted in the lavas I obferved, but that the irrefiftible violence of the waves, in a long feries of years, has cor- roded and deftroyed them. Every perfon acquainted with the fub- jed: muit immediately perceive how little folidity there is in this objedion. I admit that the violence of the fea may, in fome lavas. ( 2o; ) iavas, have totally deftroyed thefe prifms; but that it can have had that efFed on all, and through fo extenfive a fpace, is utterly improbable. Nor is it conceivable that Felicuda, among the Eolian ifles, fhould ftill preferve its prifms perfedi:, while the reft of thofe iflands have entirely loft theirs, notwithftanding they are all equally expofed to the fhocks of the waves. I cannot here omit another remark. It is certain that more than one of thefe lllands w^ere not formed by one eruption, but by fucceflive ejedions of lavas accu- mulating on each other ; and in fome deep fiflures, occafioned by the fea, this fuccefTive formation is difcoverable by the eye, as we may perceive five or fix different ftrata of lava one above the other. The inter- nal ftrata in very remote periods", having flowed into the fea, as the external flowed afterwards ; it is evident that, if the latter, on touching the water, became prifma'ic, the fame change muft have taken place, alfo, in the former ; w^hich being defended 4 from ( 2o3 } from the injuries of the fea, by the extCf-^ nal ftrata, muft ftill preferve their prifmatie configuration, of v/hich, however, no traces remain. We muft, therefore, conclude that innumerable lavas may fall into the fea, without having their external appear- ance in the leaft changed by the fudden congelation VN^hich then takes place. That the prifmatie configuration of lavas is not always the effedl of their immerfion in the waters of the fea, likewife appears from many of them taking the fame form in the air ; of which v/e have a diftin- guifhed example in the crater of Vulcano. Here, certainly, we cannot fuppofe any in- tervention of the waters of the fea. Si- milar obfervations have been made on Mount Etna by the Chevalier Gioeni. " I have obferved,'^ fays he, in the work before cited, " bafaltic columns, at the " fummit of Etna, and nearly on a level " with the bafe of its vaft crater, v^^here *' there is certainly no probability of the " fea ever having reached j and I have " frequently ( 209 ) ** frequently found polyhedrous bafaltes " perfcdly charadterized in excavations *' made by men in the centre of lavas, " which have iflued from the fides of " Mount Etna, in periods much pofterior " to the retiring of the fea." I jfhould, however, appear deficient in candour, did I not mention that M. Dolo- mieu admits that lavas may fometimes, in the air, aflume the prifmatic form, if they fall into clefts and fiffures where they fuddenly cool, of which he adduces an ex- ample in the iflands of Ponza. I {hall only remark, that I do not per« ceive the abfolute neceffity of the fiffures in this cafe ; fmce we frequently find lava3 with this configuration in perfea^ the Eoliany Safitorine^ ^c. — Their prodigious afiiiqui- ty^ and vicinity to civilized places^ two caufes of the great chajiges they have un- dcrgone — Their lavas analogous to thofe of other volcanos^ in having rocks for their . bafe — Comparifon between the rocks of ether volcanos and thofe of the Euganean mountains — Immeife depth of thefe rocks^ ivhich would remain unknown to men were it not for volca?ios — Three different bafes in the Euganean rocks ^ defer vi7ig ob- fervation : the feltfpar in the mafs^ the volcani%ed petrofilex^ extremely refembling the natural^ and the pitch-fone — Volcanos ivhich have fiot this fone^ and others in ivhich it is found more or lefs — Magnefa 7iot me of the elements of the pitch-fone of volcanos^ as fume have thought — Interef- ing obfervaiion of the change of petrcflex into pitch-fone — Chemical analyfis of thefe two fones agreeing with this obfervation — FrobablUty that fome volcanic pitch-foncs are ( 221 ) ; are derived from the tion^volcanic — Our commoftjirc equally vitrifies the Euganean lavas, and thofe of other volcanos — Singu- lar obfervation relative to the eafy fufon of feltfpars — Euganean bafaltes the products of fre — One of the fl ones of thcfe moun^ tains formed in prifms in one place i?i the dry ivay, and in another in the humid — Confrmatio7t of the offer tion, that it can ordy be determined by local circumflances^ which of the two modes Nature has em- ployed in the conformation of bafaltes. I N the year 178S, I prefented the Impe- rial Mufeum of Pavia with an ample col- ledtion of volcanic prcdudlions, from the two Sicilies ; and afterwards formed the de- fign of increafing it, during the vacations of the following year, with others of the fame kind from the mountains of Padua which had been extindl from time imme- morial. This defign I carried into efFeel, with the fufion of the feltfpars and the micas. In feveral parts of the moun- tain, when we dig into it, we find imper- fect prifins ; and they frequently proje«£t out near tlie fumniit, and on tie fides ; as we may obferve in the road leading to Praglia. The mountain U formed of this lava, which, on the furface, is decompofed and become earth, in which a number of olive-trees grow and thrive. A fimilar de- compoiitlon is obfervable at Monte Roflb, the earth of which is, in a great meafure, a mixture of fragments of micas, feltfpars, and flioerls. The ( 234 ) The Eiiganeari mountains, which form maffes, for the moft part conical, fome de- tached, and others coiitij2,uoii« at their bafes, are principally compofed of lavas, with which, in feverai of them, are mixed cal- careous carbonates. Thefe two kinds of ftones arc of fome value to the Venetians, who ii^e the lavas, which they call mafegne^ to pave the ftreets, and the carbonates to make lime. There are therefore here fe- veral quarrie?, fomie of which are now worked, while others, that are either ex- haufl(d, or become iefs produdlve, are abandoned. I entered two of thefe quarries, the one at Monte RoiTo, and the other at Monte Ortone ; and, having continued there fome time, determined to go down into fome others, as I found they were extrem.ely convenient for obferving in their fides the ilony fubftances 1 wiflied to examine. I therefore proceeded to Monte Merlo, where there is a very large excavation of this kind within the lava. To extrad the ftones, which ( 235 ) %7]ilch are very hard, the labourers have recourfe to the following dangerous method. A man, faftened by a rope, is let down to a certain depth againft the perpendicular fides of the cavern ; and, the other end of the rope being made faft at the top, breaks the flone in pieces with pickaxes, availing himfelf of certain vertical fiilures, which greatly facilitate the labour. Mines are like wife prepared, in fome cafes, which blow the fragments of the ftone into the air. In this excavation, and in another of lefs dimenfions, not far dlilant, the lava of the mountain is truly granitous, and the granite has for its bafe the feltfpar, which is fo abundant that it compcfes the greater part of the rock. It would be fuperfiuous to dcfcribe it, as it is perfectly funilar, even in its cryftallization, to that of Monte Rcflb and Monte Ortone. Befides the feltfpars, which, by their brilliancy and other exclu- five chara(£«:ers, immediately declare their mature, certain white fpots prefent them- felves ( n6 ) felves to the eye, which at firil: view may excite a doubt to what kind of ft nes they appertain ; but, when exatiiined atteniively and under dilTerent refledions of the light, we are convinced that they are t:ue fclt- fpars, but in part calcined. Thefe feltfpars are accompanied with the ufual hexagonal micas, and fome fhoerlaceous points. This granite, liquefied by the volcanic £re, reminds me of tlie great a(ftivity re- quifite in our common fires, for the fulion of granites that are not volcanic, and even of thofe which are ; as I have ihown in Chap. XII. I have fmce thougl t that pof- fibly fo great a degree of beat was not ne- ccflary in the prefent inftance, from this granitous lava being deprived of quartz, one of the elements of the granites on which i made my experiment?,. and which certainly is that among them m; ft relrado- rj to fuhon. I have found, in fait, that this iava, when continued a long time in the furnace, affords a vitreous produd of a black colour, and nearly homogeneous, fome ( m ) fome feltfpars only being perceivable in it in the form of v/hite fpots, I have faid, a little above, that black mi- ca is one of the component parts of this granite. 1 fliall here add, that when it is detached from the volcanic rock and ap- proached to the magnet, it will adhere to it like a particle of iron ; which property it fhares with other black micas, before de- fcribed, and with almoft all I fnall hereafter have occafion to mention. This curious phenomenon was pointed out to me at Ve- nice, before I made my excurfion to the Euganean mountains, by that excellent na- turalift Sig. Giovanni Arduino. The greater part of the ftreets of that capital are paved with thefe Paduan ftones, and it was in fome of them I was fliown this quality by Sig. Arduino. He, indeed, was of opinion that thefe fhining black particles were rather particles of iron than of mica ; but ocular examination convinced me that they apper- tain to this ftone ; fmce with the lens v/e may perceive that they con fill of delicately thin ( 238 ) thin and femltranfparent lannns, whicbj when touched with the point of a needle, are found to be flexible and elaftic, and fe- parate from each other. In the fire, as has been faid, they vitrify, and the glafs pro- duced from them is of a blackilh colour, and femltranfparent. The magnetic property of thefe micas, among the many I have examined, I have found in none vvhich enter into the compo- fition of granites not affected by the firCo In my return by land from Conilantinople to Italy, I coUedted fpecimens of the ftones compohng the mountains over which niy road led me, and, among others, of a con- iiderable number of granites, which, from the nature of the places where they were found, were certainly not volcanic. Many more I found in the Alps, and other coun- tries not volcanic. On the micas they con- tained I m.ade experiments with the magnet ; but I did not find one, whatever was its colour, which fliowed the lead fign of at- tradion. In fevcral of them, indeed, I found { 239 ) found it after they had been expofed for feme time to the fire. This exclufive pro- perty of the Euganean micas is therefore a proof that they have felt the influence of this agent, and is a ftrong confirmation of their volcanization. Before I difmifs the quarries of Monte Merlo, I fhall briefly ftate two facSts not undeferving the attention of the readen Firft, it is not unufual to find within the granitous lava nodofities of pure quartz, of the thicknefs of one, two, and fometimes even five inches. Befides giving fparks plentifully with fteel, which is the peculiar property of this ftone, it has a colour lightly amethyfline ; it is tranfparent, fomewhat und:uous to the touch, folid, and of an in- determinate figure. But to what are we to attribute the exiftence of thefe quartzofe nodofities, which are uninjured, within this volcanic granite ? I cannot perfuade my- felf that they exifted in it previous to its ig- nition ; fmce, had this taken place after- wards, it mufl; have altered the quartz, by • depriving ( 24^ ) depriving it of its tranrparency, and render-* ing it full of cracks, and extremely friable ; all which changes follow on expofmg it a fliort time to the furnace. I fhall obferve, further, that two of thefe nodofities being left in a crucible placed on burning charcoal only for a quarter of an hour, loft tbelr amethyftine colour, and acquired a more than fuperficial whitenefs, with a number of cracks, and very apparent friability. I, therefore, cannot believe that they have been taken up by the way, and enveloped in the lava when it flowed, as fometimes happens, V7hen nerv torrents meet with extraneous ftones in their paffage. I am, in faifl, of opinion, thatthefe fmalimafTes of quartz have been produced pofterior to the congelation of the lava, by the filtration of water impreg- nated with the molecules of quartz, which has penetrated into fome fmali cavities, and gradually filled them ; in the fame manner as we have explained the formation of the calcedonic globes found in fome of the lavas of Lipari *. * See Chap. XV. The ( 241 ) The other fadt is very fimllar to this, and may be explained in the fame manner. It relates to the large pieces of flioerl which are contained in this volcanic rock, and are difcovered on its being broken into pieces, in the fime manner as the quartz. Thefe are compofed of a number of rhomboidal fho- erlaceous prifms, fo confufedly heaped and joined together, that it is impoffible to ob- tain a fingle prifm entire. Excepting in the largenefs of their fize, they perfectly refemble thofe of the porous lava, with the horn-ftone bafe, of Monte Doriati, of which we have fpoken above. Thefe (hoerls, like all the others of the Euganean mountains, concur to prove the volcanization of the latter, by the fame property which is found in the black micas of this country ; I mean their magnetifm. Baron Dietrich, defcrib- ing the volcanos of Old-Brifach, fhews that the adion on the magnet of the black cryf- taliized Ihoerls, is the exelufive property of thofe that are volcanic. Though, in the courfe of this work, I believe, I have only mentioned the fhoerls of Monte Roflb, at VOL. III. R Etna, ( 242 ) Efna, as pofleffing the property of fironglf moving the magnetic needle*, I did not fail to make the fame examination relative to numerous fhoerls of the Phlegrean Fields and EoHan I lies, and can pofitively affirm that I found this quality in them all. It is- at the fame time to be obferved, that I could not perceive it in eleven fpecies of fhoerls, whatever was their colour, fome of which were detached from granites, and others found folitary. This obfervation, w^heii treating of the Euganean mountains, ap- pears to me too important to be omit- ted. Thefe Ihoerlaceous lumps or groups, I am of opinion, mud have been produced in the granitous rock by filtration, with this fingle difference, that the quartzofe groups have remained amorphous, and the fhoerlaceous are confufedly cryftallized ; probably from the more ready tendency of the integrant molecules to take a determinate form. * See Gliap. VII. Havlag ( 243 ) Having examined forae of the Quarries which furnifh volcanic ftones, I proceeded to vifit thofe where carbonate of Ume is dug, of which ftone there is no fcarcity in the Euganean mountains. Such are the quarries of BattagHa, Fraflinelle, and Saint James, fituated on the dechvities of the Monte Grande, above Teolo. Before we reach the lava of Battagiia, we meet with this carbonate. It is fcifTile, and eafily di- vides in flakes, for the mofi: part, horizontal. This quarry is very large, and in fome places forty-five or fifty feet deep. It prin- cipally confifts of this ftone, which is excel- lent for making lime. The lime-ftone is difpofed in ftrata of different thicknefs ; from thofe of one inch or lefs to thofe of a foot. We feldom meet with ftony ftrata which preferve fo well their parallelifm to each other, and to the horizon. In the midft of the carbonates are found numerous flints, or fire-ftones, already well known from the mention made of them by other writers; for the Euganean mountains,where- ever they afford calcareous carbonates, ccrti- R 2, tain ( 244 ) tain likewife flints. On examining thofe of the quarry of Battaglia, I found feveral of them fo clofely united with the calcare- ous carbonate, as to prefent the moft fpe- cious appearance of a tranfmutation of the lime into filex. But to give a clearer idea of this apparent tranfmutation, it will be neceiTary to defcribe both the carbonate of lime and the flint. The lime-fl-one is white, compadl, not very heavy, compofed of impalpable parti- cles, foft to the touch, with a fmooth and fometimes conchoidal fradure, and break- inc; into obtufe and amorphous fra2;ments. it is diflblvcd by acids with confiderable effervefcence. Both internally, and on the furface of this vv^hlte flone, black, dendritic, and not inelegant fpots and ftreaks are very confpicuous. The flint is of a deep flefh-colour, fome- times brown and even black ; its grain is extremely compad and fine ; its fradure fmcoth, and almoll always conchoidal, and its ( HS ) its fragments angular, acute at the extremi- ties, and femi-pellucid. It is more than moderately heavy, the file will not touch it, and it gives fparks flrongly with fteel. Notwithftanding their great hardnefs, how- ever, the generality of thefe flints eaiily break into fmall pieces under the hammer. Some of them, in the quarry of Battaglia, are placed between the llrata of the carbo- nates of lime; but they frequently alfo form a continuation with them ; fometimes, indeed, divided by a fudden and abrupt fe- paration, but frequently, likewife, by infen- fible gradations ; in which latter cafe there is a fpecious appearance of an infenfible tranfition of the lime into filex ; and the opinion that this is really the fad has been adopted by many. A piece which exhibits this appearance lias one part of it white ; w^hich colour in- fenfibly difappears, and is fucceeded by a reddiHi tinge, that gradually increafes till the remainder of the piece at length ailumes the red, bro\\n, or black colour v;hich is R 3 proper ( H6 )• proper to this flint. The change of colour is accompanied by a difference in the hard- nefs, which fucceflively increafes, as appears from its fcintillation with fteel ; the white part of the ftone yielding no fparks ; the light red, very few ; but the deep red, or black, aiFording them plentifully. If. a flream of nitric acid be poured from one end to the other of fuch a piece, where the colour is white an, efferi'efcence arifes, which becomes lefs fenfible in the pale red parts, diip.inifhing as that colour increafes, until no appearance of it is difcoverable where the rednefs is deepeft, and the fcintil- lation with fteel ftrpngeft. Thefe charac- ters, however, to the chemical eye are not decifive of the fadt in queftion. For, not to mention that difference of colour never conftitutes a diverfity of fpecies in either of the three kingdoms of Nature, the proper- ties of hardnefs, and giving fparks with fteel, do not exclude the prelence of carbo- nate of lime ; fmce, though it has been con- fidered as the diftinguilhing property of calcareous carbonates, that they do not af- ford ( 247 ) ford fparks with ft eel, it has been proved that there are feveral Vv^hich have tlils qua- lity. I pofTefs feverrJ fpecimens of n^iar- bies, that I collevet it ; for v/etting is to rough ftones a kind of half polifli. It then has the exad; appearance of the pitch-ftones. In fome parts it is of a red colour ; fome- times pale, fometimes more lively, and fometimes inclining to a yellow ; in which latter cafe, it relembles certain kinds of am- ber ; but in other parts the colour is a mixture of blue, green, and white, but all of them very pale. The fra^ures are al- ways amorphous, of unequal furface, and little brilliancy. The thinner flakes are tranfparent ; as is the property of foraej pitch- ( 252 ) pkch-ftones. This lava contains unequally diftributed feltfpars of a flat form, friable, and not very brilliant. Every flroke with the fleel breaks off fome pieces, but extracts no fparks. A few hours in the furnace deprive this ftone of its colours, rendering it of an afh grey : it likev^ife lofes its friability and foftnefs, and becomes capable of giving fparks with fteel ; refembling then a pafte of porcelain. Continuing the heat longer, the cinereous colour remains, with the ap- pearance of very numerous bubbles ; and the lava pafles into a homogeneous veficu- lar enamel, with a fufion of the feltfpars. The fmall valley of Bajamonte is not, however, the only place in which this pitch-ftone lava is found ; it is met with in feveral others ; as at Monte Sieva, and its environs. We there find banks or veins inclined in different angles to the horizon, and fometimes perpendicular to it. The lava of one of thefe has exadly the £ colour ( ^53 ) colour and luflre of pitch, and contains numerous feltfpars. In its external appear- ance it does not differ from that before defcribed. It has, however, one peculiarity which mufl; render it valuable in the eyes of the volcanift. Pumices are a kind of produds which bear in them, demonftratively, the evidences of fire ; and the traveller who on any mountains meets with a vein of uncertain, origin which pafTes immediately into the ftate of pumice, is fully warranted to de- clare it volcanic. This is the cafe in the prefent pitch-ftone. It contains groups, more or lefs large, of fibrous, light, cellular pumice, not merely contained within it, but compofmg one fmgle body with it : whence it appears that foaie parts of this rock, either by a more violent adion of the fire, or becaufe they were more eafily vitrifiable, have pafTed into the flate of pumice. In the fame Monte Sieva, befides a lava with ( 254 ) With a petrofillceous bafc, which, from its compadnels, extremely refembles the natu- ral petrofilex, but which is fufible in the furnace, we find another vein of pitch- flone lava, but of much greater extent, and ■which is difpofed ahnoll vertically. On digging into this vein, we find very beau- tiful and well preferved pieces of pitch- ilone lava. For the mofi: part it has the colour of refin, an elegant luftre, a fine grain, and great compattnefs. It is fmooth and clear in the fracture, with amorphous fragments, femi-tranfparent In the points. It is not, however, fufficiently hard to give fparks with fteel. It is not without felt- fpars, which have a vitreous afpedt:. This lava does not entirely compofe this extenfive vein ; but is found there in pieces, ufually fmall, which are clofely bound together by a ftony fubftance which aQs with refpe^t to them as a gluten or cement. Thefe pieces have not been rolled by a ftream or weaves, and thereby become round, but are amorphous, and with acute angles. ( 255 ) angles. It is evident, therefore, that this lava has been broken by fome violent agent ; and its pieces afterv^^ards have been taken up, and inclofed v^ithin the ftony fubftance, which, when carefully examined, is found to be only, a conglutination of very fine dull of the fame pitch- flone ; which al fo contains ftones of feveral other kinds. At Cataio, where is the villa of the Marr chefe degli Obizzi, are large excavations in the fide of a mountain, made in the fame brecciated pitch-ftone. We here, likewife, find only very fmall, but numerous, frag- ments of this ftone bound together, in like manner, by a congenerous ground. In another part of this mountain the fame flone again appears ; it does nor, how- ever, refemble a breccia, but forms thin veins, and is extremely fimilar to that of Bajamonte. The experiments which I made in the furnace on the firft fpecies of lava I repeated • on { 2S6 ) on the others ; not excepting the bafe of thofe I have termed breccias ; and I ob- tained from them the fame kind of grey and cellular enamel. I have called the lavas now defcribed pitch-ftone lavas, becaufe they refemble in their external appearance the ftone defigned by that name. I have likev\^ife the autho- rity of M. Dolomieu, who treating of lavas found by him in the Paduan mountains, and in the iflands of Ponza, gives them that denomination. He afferts, however, that the lavas differ from the pitch-ftone in a peculiar property, which confifts in the extreme eafe with which the volcanic pitch- ftones may be fufed, and the infufibility of the true pitch-ftone even In a violent fire *. Having obtained a number of pltch- ftones that were not volcanic, I determined to make experiments on them in the fur- * In his Notes to Bergmann's DifTertatlon on Vol- canic Produds. nace. ( 257 ) iiace. They were, in the whole, nine : three from the ifle of Elba ; one clneritious and almofi: opake ; the fecond femitranfpa- rent and yellowiih ; and the third opake and inclining to black : three from Germa- ny ; the firft yellow, the fecond red, the third blacik, and all opake : the three laft from the Pyrenees ; one reddifh, the other green, and the third of a colour between a green and a pale blue ; and all three fomewhat tranfparent in the angles. The firft fix, after having continued forty-eight hours in the furnace, fhewed no fign of liquefac- tion ; but only became white, extreiiiely light, and pulverable under the finger. Thofe of the Pyrenees were changed into a beautiful white enamel, giving fparks with fteel, and full of minute bubbles. The pitch-ftones of Saxony, which are found in places not volcanic, are eafily fuHble in a not very ftrong fire, as Delametherie has obferved. Several analyfes have been made of pech-ftein or pitch-ftones. In one, Berg* VOL. III. S mann ( 25S ) mann found the portion of filex to he greateft, that of alumine, little, and that of lime, leaf!:. Another, analyzed by Wiegleb, gave Silex - - - 65 Alumine - - - i5 Iron - - « ^ The other 14. parts requifite to com- plete the 100 were difperfed in the opera- tion -. A third by Gmelin Silex - - - 90 Alumine - - - 7 Iron - - - 2 The pitch-ftone lavas of the Euganean mountains having never to my knowledge been analyfcd, I undertook this operation on the three fpecies mentioned above ; and the following were the refults : * KIrwan's Mineralogy, Pitch- ( 259 ) , Pitch-flone lava below B? jamonte. Silex 71 Alumlne 18 Lime 4 Iron S Pitch- ftone lava of Monte Sieva in beau- tiful and v^ell preferved pieces, Silex - - . y^^ Alumina - - - 14 Lime - - - g Iron ' ' - 3i Pitch-ftone lava of the fame Monte Sieva, ferving as a cement or bafe to the above pieces, Silex - ... 68f Alumine - - - 19 Lime - - - 8 Iron - - - 2 When thefe three analyfes of mine of the volcanic pitch- ftones of the Paduan mountains are compared with thofe of Bergmann, Wiegleb, and Gmelin, we fhall S 2 ' find ( 26o ) - find that the principle moil abounding in thefe fix ftones is the filex ; that the alu- mine is but in a moderate or fmall propor- tion ; as are likewife the lime and iron when they enter into the compofition of thefe ftones. It is therefore evident that thefe fix ftones are of the fame fpecies ; nor can the infufibility of feveral pitch- ftones, which are not volcanic, diftingulfh them as eflentially different from the volca- nic, fince we find in the genus of petrofi- lices fome which fufe in the furnace while others remain refradory. It is, befides, not invariably true that volcanic pitch- ftones are eafily fufible. Thofe of Monte Muffato, of which I fhall prefently treat, require a continuance of feveral days in the furnace before they are completely fufed. Some pitch-ftone lavas of the iflands of Ponza, which are of a pale white colour, and of a fmooth and fliining fradlure, after continuing feveral hours in the furnace, only become of a deep red colour, and fu- fion does not take place till after thirty hours. It is remarkable that almoft alLvol- canic { 26l ) canic pitch-ftone lavas, whatever may be their colour, as foon as they are expofed to our common fire, become red. Thefe pitch-ftone lavas, which are found In other parts of the Eugahean mountains befides thofe already mentioned, have in- duced Father Terzi, a Benedld:ine, to fup- pofe that they were no other than real glafs, an opinion which he publifhed a few years fmce in fome letters on the Euganean produdis. He informs us that he difcovered large veins of them in the Mont^ del Muflato, and at Brecalon, as well as in other places. The novelty of the difcovery greatly ex- cited the furprife of many Paduan natural- ifts, and efpecially of the Abbe Fortis, who having frequently made excurfions to thefe mountains to examine their products, could never meet with this extraordinary glafs. To afcertain the truth, he, with fome other perfons well acquainted with tjiis branch of natural fcience, repaired to the mountains, and foon difcovered the error which had been committed by the good Father mif- S 3 taking ( 262 ) taking tliefe pitch-ftone lavas for glafs, which error he detedled and proved in a Memoir entitled On certain parts cf the Faduan Moufita'ms ^. In September 1792, the Marchefe Anto- nio Orologio and myfelf, having made an excurfion to the Euganean mountains, to vifit this celebrated naturaiift, who refided at the village of Galzignano, he con- duced us to Monte del MulTato, where thefe fuppofed veins of glafs were to be feen ; but we found that they were only large mafles of pitch-fione lava, fimilar to that above defcribed ; of which I was ftill more convinced afterwards, as I took fome fpecimens from the fpot and carried them with me to Pavia. This pitch-ftone lava is of tvvo kinds. The one is interrupted with thin ftreaks of a white earth, which attaches . to the tongue and emits an argillaceous fmell, and by which the lava often appears as if divided in fmall pieces ; it alfo, in * Sopra parecchle localita de' Monti Padovani. many ( 263 ) many places, includes extraneous bodies, feme of which are of conlidcrable import- ance to volcanic enquiries. Thefe are fmall pieces of hom-flone pofleffing that porofity which characterizes them for true lavas. One of the fpecimens above men- tioned contains a fragment of this kind two inches in thicknefs, extremely perfedt, and very porous. The vacuities are round and elliptical : fatisfacflory figns that it has made a part of fome current. The other lava from the fame mountain refembles the former, as far, at leaft, as can be judged from the fpecimens I brought away, in its colour, w^hich is that of tur- pentine, only much darker and lefs lively.; and in its confidence ; except that it forms unmixed mafles, and contains amorphous feltfpars, of Uttle or no brilliancy. Among all the pitch-ftone lavas of the Euganean mountains that fell under my obfervation, this is the moft compact, heavy, and hard. The eye alone, however, is fufficient to .difcern the great difference between thefe S 4 pitch- ( 264 ) pltcK-ftone lavas and volcanic glafs. The idea of volcanic glafs is derived from that we have from our common glafles j the infeparable chara6:ers of which, as we well know, are, that they fhould have a fhining and bright furface ; be compofed of indif- cernible particles ; break into angular pieces, extremely thin at the edges, and with acute and piercing points ; with a fradure either entirely ffnooth and clear, or, as we fre- quently find, with waving and curved flreaks ; not to mention its tranfparency, a quality known to every one, and, in glafs,one of the moft valuable. The fame, precifely, are the charaders of the greater part of volcanic glafles ; but the defcription of the pitch-done lavas is very different. They have commonly a dead and dull iuftre ; their pafte is fine, indeed, but not compa- rable in finenefs to that of glafs ; they are lefs fmooth in the fradures, lefs fharp and cutting at the edges, and have little or no tranfparency. They are likexvife diftin- guiflied by another property from volcanic glafles, the greater part of which are fuifi- ciently ( 265 ) ckntly hard to extradl fparks from fteel, that is to fay, to melt it : on the contrary, I was never able to extrad: the fmallefl: fpark from the pitch-flpne lavas above mentioned, though I made the experiment on them with the heft fteel. They are therefore lefs hard than volcanic glafs, as is indeed appa- rent from the facility v/ith which pieces fly off at every ftroke. To thefe evident diffi- milarities we may likewife add the weight, which in pieces of the fame iizt is always greater in volcanic glafs than in pitch-ftone lavas. Father Terzl may, however, eafily con- vince himfelf that thole veins of the Euga- nean mountains which he calls glafs, are by no means entitled to that appellation, if he will fufe a fmall portion of them in the fur- nace. He will then find the prcdudl a true enamel, exhibiting a vitreous afped: not at all difcoverable in the pitch-flone lava from which it was produced. This is true, like- wife, of the veins of Monte Muffato ; and fhews that the pitch-ftone lavas rauft not ©nly (• 266 ) only be excluded from the clafs of volcanic glalTes, but even from that of enamels. When, in the year 5789, I made an ex- curfion over the mountains of Padua, in fearch of volcanic objedls, accompanied by the Marchefe Orologio, we, at Praglia, were received and moft hofpitably entertained in the ancient and magnificent monaftery of the Benedidines- by the excellent Father Terzi, who, after dinner, took us into his private cabinet of volcanic-marine products, collected on the Euganean mountains. He prefented us likewife with fome fpecimens, informing us at the fame time where they had been found, which I think deferving of a particular defcription. The firfl:, which, according to the ac- count he gave us, was brought from Schi- vanoja, is a mixture of amorphous, white, and friable feltfpar, and black, prifmatic, and extremely brilliant (hoerls, m.uch refembllng fome fpecies of tourmalins. From this mix- ture is obtained, in the furnace, an extreme- ( 267 ) ij black enamel, of the greateft compa(3:- nefs, fcattered over with white points, which are feltfpars not entirely vitrified. The magnetic needle is fenfible to thefe fhoerls at the diftance of one line and four- fifths. The fecond product, which is from Mon- te Merlo, confifts of an aggregate of ex- tremely w^iite and fliining half-cryfiallized feltfpars, of a changeable colour, which in the furnace produce a white, and fpungy, but hard glafs. The third, which is from the fame moun- tain, at firfl view, might be taken for a pu- mice, as it fwims in water ; but, when pro- perly examined, appears to be a vitreous fcoria, in the folid parts fufficiently hard to give iparks with fteel ; i reflated and rendered fpungy by the adion of fire, and aeriform fubftances. The furnace perfedly vitrifies it. Two other produds, one from Mafcabo, near Pragtia, the other from Tramonte, were ( 268 ) w-ere true pitch- flone lavas, though Father Terzi believed them to be real glares. I had not time to certify myfelf with re- fpedt to the places where thefe produdions were found ; but I cannot doubt the truth of the accounts I received concerning them. I can at lead affirm, that there was no error with refpedl to the tvv^o products of which I fliall now proceed to fpeak, as I found them precifely in the places which had been pointed out to me by the Reverend Father. The firft of thefe is met with at the foot of a very high rock, called Pendife, and forms a vein, which runs from eaft to weft, and, in the opinion of Father Terzi, is glafs. Certainly, v/hen we , take off the outer coating, which, as in a great number of other ftony fubftances, is in a ftate of de- compofitioUj and, confequently, has loft, in a great degree, its external charaders, the interior mafs may at firft deceive the eye of tlie obferverj and induce him to confider it ( 2% ) as real glafs. The arpe(£t is faiooth and Ihining, like that of glafs ; but with fome undtuofity, as is the property of fome lefs perfed: volcanic glafles. But on examining, with greater attention, the pieces recently fractured, we do not find in them the cha- radleriftics of volcanic glafs ; as they have not the finenefs of confidence, the undulat- ing fuperficial ftreaks, the fharp edges, nor the acute points. We may even handle and prefs the flakes and fragments of them with- out fear, wdiich cannot be done with impu- nity by volcanic glaffes. We know, likewife, that the primordial rocks, when they are changed by the ad ion of fubterranean fires into the nature of glafs, are no longer recognizable ; as they have loft their primitive ftrudlure, and are redu- ced, together with the extraneous fubflances they contain, as flioerls and feltfpars, to one fmiilar and homogeneous mafs; whereas, on the contrary, the vein in queftion fuffi- ciently declares its origin, which is a petro- filex of a dark green colour, a fra6^ure fomewhat ( 27d ) fomewhat fcaly and conchoidal, of a grain moderately tine, giving fcarcely any fparks with fteel, and having, in the points, a very flight degree of tranfparency. The feltfpars and micas, however (of the former of which the number is but fmall, but that of the lat- ter very conliderable), do not form one ho- mogeneous pafte with the bafe, but are both in a flate of the greateft j^refervation. The feltfpars exhibit a cryftallized form, but it is impoffible to define it where the petrofilex has not been altered. It is not the fame with the fuperficial cruft, the bafe of which, having been in part deflroyed, holds thefe ftones but feebly ; fo that they may eafily be detached entire with a knife ; when they appear to be prifmatic cryftals, with tetra- hedral rectangular facets. We cannot, there- fore, in any manner, call this vein a glafs, but only, at the utmoft, a vitreous lava. By the fide of this volcanic rock, there is another, of a congenerous bafe, and con- taining the fame micas and feltfpars ; but it is of a pale green colour, and tolerably I hard : ( ^71 ) hard ; it has not, however, the brilliancy of the former. Both thefe rocks produce ia the furnace a greyifli enamel, with an entire fufion of the feltfpars, but not of the micas, which leave black points within the enameL The other product of which I went in fearch, according to the directions given me by Father Terzi, was, in like manner, in his opinion, a volcanic glafs, but detached and fcattered. It is found near the Church of Valfanzibio, Having taken a fpecimen of this into my hands, and examined it care- fully on every fide, I perceived that in this inftance he was not miftaken, and congra- tulated him and myfelf on the difcovery. It exhibited, in fad, the moft indubitable cha- radlers of a true glafs. It was black, and gave fparks with fteel. I was, therefore, very anxious to examine the place where it was found, and repaired without delay to Valfanzibio ; where I found more than one piece of it, not infixed in the earth, nor in the mid ft of any rock or ftony vein, but loofe, and fcattered over the ground, like ftones^ ( ^70 ftOnes in a public road. I was fomewliat furprifed at this ; and, on making enquiries of fome peafants on the ipot, they told me, that fome fhepherds had brought that glafs from the grottos round the fountains of the garden of N. U. Barbarizo, at a little dif- tance from the Church of Valfanzlbio, and, finding it i^felcfs, had thrown it away there. I repaired, accordingly, to the place they pointed out, and found that it was, without the leaft doubt, of the fame kind. I, after- wards, learned from the keepers of the gar- den, that it had been procured from the fco- ricS of the furnaces of Murano, near Venice. I fhall conclude this account of the vol- canic fpecimens of the Euganean mountains ihown me by Father Terzi, in his cabinet of natural curiofitles, with mentioning one more, which in his opinion was a volcanic glafs, and had been found detached on Mon- te Merlo. To this, likewife, i canuot refufe the appellation of glafs. It is, like the for- mer, black, compadt, and heavy. As I did not go to the place where it was found, I cannot ( 273 ) cannot pronounce with certainty relative to its origin. It is poffible that this glals may be the produdi .n of thofe very ancient vol- canos, fince Sir John Strange, at number 61 of his Catalogue before cited, mentions fome pieces of fofTil glafs, but winch are fo- iitary and accidental, found in fome parts of the Euganean mountains. It is not, how- ever, dbfolutely impoffible but that it may be glafs from the furnace ; at leafl: the acci.lent of the glafs of Murano ought to teach us to be cautious, and fufpend our judgnnent relative to the queftion, whether a mountain may have been volcanic or not, when we have no other proof than finding a loofe piece of glafs, fcoria, or other fab- ftance deriving its origin frc^m fire, while we are uncertain whether that fire was, or was not, volcanic. For, even though the pieces found (hould be really volcanic, they cannot afford a certain proof of the volcani- zation of the place wh.re they are found detached. Of this 1 can produce an inftance which happened to myfelf in a curfory vifit that 1 made to Capo Colonne, a promontory VOL. fii. T of ( ^74 ) of Attica dlftant twenty miles from Athens, when, in 1785, I accompanied his Excel- lency the Venetian Envoy, the Cavaliere Zulian, to Conftantinople. I there found pumices fcattered over the ground, to my no little furprife, as tlie place exhibited no indications of being volcanic. They were of that kind which, from their levity, fwim in water ; and, being of a glofeofe figure, I fufpeQed that they had once flowed. On defcending the promontory on the top of which thefe pumices are found, and pro- ceeding to the fhore, near a narrow penin- fula, expofed to the dafliing of the waves, I found three other fimilar pumices, which authorifed me to conclude that thofe on the height abave, which is about one hun- dred and fixty feet above the level of the fea, were fome of thofe that had been thrown by the waves on the fhore, and af- terwards carried thither by men : the only explanation of which, in my opinion, the cafe admitted. To the fhore they had been brought by the fea ; for it is well known that many illands in the Archipelago are volcanic; ( ^IS ) Volcanic ; and that Santorlne, in partlcularj is only one immenfe mine of pumices *. The objedions which may be made to the relations that afcribe a volcanic orlirin o to a country, merely becaufe certain fub- ftances that bear the marks of fubterranean fires are found in it, permit me to fay, are equally applicable to other proofs of the fame kind which are by no means more decifive. Here, it is faid, there mufl: have been a volcano, becaufe the matters found are extremely black, and therefore bear the charaders of fire. There we are authorifed to form the fame opinion, becaufe lavas have iflued from the entrails of a mountain, or volcanic veins and ilrata are found in its fiiTures, There are many writers who, without adding any other proof, ufe thefe expref- fions to fignify to their readers the difco- very of fome ancient volcano. I do not * See Chap. XIX. Ta deny ( ^7^ ) deny the poffibility of there havuig been a volcano in fiich places ; but I muft affirrn that thefe indications are equivocal, and, therefore, may be fallacious. It is true that many volcanic products are black, with a colour varying from the blacknefs of iron to a greyifh black. It is equally true that, in a long feries of time, this colour is not loft by many volcanic produc- tions, as appears from fome lavas in the Eolian iHes. But it is likewife true, that in many others the blacknefs dimini(hes in time, and, at length, totally difappears, as we fee in the greater part of the lavas of Vefuvius and Etna, which, though at firft they approached more or lefs to a black colour, have gradually loft that colour, till at laft they have acquired one refembling that of common earth. It is fufficient merely to caft the eye on the recent cur- rents, thofe of a moderate age, and the ^ moft ancient, of thofe tw^o volcanos, to per- ceive thefe fucceffive changes. Every lava, however, though of a recent date, is not black. The colour which is proper to the primordial ( ^11 ) primordial rocks frequently does not difapr pear in confequence of the adiion of fire. The colour of many lavas approach^fs to a black, becaufe that was the colour of their relpedive primitive rocks, as we fee in the lavas with a horn-ftone bafe. la others it is a cinereous grey, and even white, be- caufe they derive their origin from ftones of a fimilar colour, as, for inftance, feltfpars and petrofilex. This diverfity of colours, black, grey, cinereous, and more or lefs white, is not unfrequently preferved even in the enamels and glaifes produced from thefe rocks when fufed in the crucible. It is therefore certain that the colour of the products alone is not a certain indication of a volcano. I confider as illufory, and not merely inconclufive, the alTertlng the exiftence of ancient volcanos becaufe there exift veins or volcanic matters ; iince this is the fame thing as faying there are vol- canos becaufe there are volcanos. And though a writer fhculd be convinced T 3 fro:n ( 278 ) from his own obfervation that thefc matters have really fuffered the action of fire, if he wifhes to convince the philofo- phical world he muft fpecify their nature ; as whether they are puzzolanas, afhe?, glafles, enamels, fcorix or lavas. The precifion and exadnefs required in the pre- fent difcerning age likewife render it necef- fary that he fhould charaderize thefe dif- ferent volcanized fubftances ; and it will be to little purpofe that he adduces in proof of an extinguifhed volcano the remains of a current of lava, unlefs he properly defcribes it, fuice the advancement of this fcience depends entirely on exad defcrlptions of produds affeded by the fire. The moft able volcanifts of the prefent time write after the manner of accurate mineralogies. Among thefe volcanifts, the firft place is certainly due to M. Faujas de Saint Fond, as is fufficiencly proved by his Mineralogy af Volcanos dlcx^ and a very fmall quantity of lime. It is ufuaUy refractory to the fire of a glafs furnace ; but fornetimes v;^ill fufe when it contains, a rather larger proportion of lime. Of this kind of earth I made fome fmall fpheres and cubes, which I left four or five hours in the furnace ; when the vitri« fication had penetrated to the depth of two thirds of a line, and in feme even a whole lin?, and the central part had become femi- vttrecus. Similar eftedis take place In lavas. Their fu-fface afliimes an enamel or vitreous afpecl, which in the internal part is lefa apparent. In fome, however, we find points which have become vitreous, though thefe lavas before did riot contain a fmgle atom of glafs. In general, they lofe that grain and texture, which indicate the primitive rocks whence they were derived, and they all, or nearly all, may be called vitreous. ( 283 ) Thus we have a prodigious number of foffil produ6lions which have the moft fpe- cious appearances of lavas, and vitreous lavas, though they have never fuffered li- quefaction ; as is incontrovertibly proved by the pieces, which, when they come out of the furnace, retain exactly the configu- ration they had before they were expofed to the tire. Inftrudted by thefe fa£ls, I confefs that the firll: time I faw the Euganean moun- tains, and found myfelf in a theatre very different from that prefented by the Eolian ifles, not to mention Etna and Vefuvius, I could not avoid entertaining doubts whether the numerous foeks, which in a great part form thefe mountains, owed their origin to volcanic eruptions, or were pre-exiflent to the fubterranean conflagrations, that had only penetrated them, infixing in them in- delible traces of their adion, but ftill leav- ing them in the place where we at prefect fee them. Every doubt however was re- moved, and I remained convinced that thefe ( 284 ) thefe prodigious malTes of rocks were igneous eruptions, or, in fad:, currents of lava, of which the porofity of fome of them was a very evident and fatisfaflory proof. It is indubitable that the elaftic gafe?, which generate pores and vacuities m the recks acfled on by lire, cannot pro- duce that efTevfl unlefs thefe rocks are foft. ened fufFiciently to yield to the expanfive force of thefe aeriform fubftances, which muPc precifely happen in their a6lual lique- faction. This, though fufficiently evident in iifelf, is undeniably proved by experi- ments I made in the furnace. When the porphyries with a petrofiliceous or horn- fione bafe, and, generally, when compact Javas alTuai^d the fimple vitreous varnifh, and fomewhat of a vitreous afpe£l inter- nally, but v/ithout the pieces conglutinating and forming one fmgle uniform mafs, they rarely or never contained bubbles ; w^hich, on the contrary, were confpicuous and nu- merous when the fufion w^as complete, and iht larger, the greater the degree of liqui- dity produced by the iire in the fljony bodies. The ( ^85 ) The porofity of volcanic rocks Is, therefore, a decilive proof that they were once in a fluid ftate. Several of the Euganean rocks are porous and cellular, as I have already fhown of more than one, and fhall proceed to fhow of fome others. There is a declivity on one of the Euga^ nean mountains, the name of which I can- not give, having negled:ed to note it in my journal, an omiffion of little importance to the truth of the fa£t ; which declivity is compofed of a rock with a horn-ftone bafe, containing fekfp^thofe cryftals, and full, both on the furface and in the internal parts, of round vacuities, fu cb, preclfely, as are ufuaily produced in lavas by aeriform fluids, I fhall make a few more obfervations on the Euganean lavas ; and (hall notice that one of them containing bubbles, and that in a confiderable number, is found in im- menfe quantirits in, and on the fide of, the road leading from Eajamoate to Rua, 2 This ( 286 ) This lava, which has for its bafe the horn'» ftone, and emits a ftrong argillaceous odour ^ has the colour of a dead leaf, a grain fome- what Tandy, and a great number of round pores, from thofe of a fize fcarcely difcerni- ble, to others feven lines in diameter. Many of thefe pores are occupied by cryftallized globules of carbonate of lime, produced by filtration. This lava has the external appear^ ance of being very ancient. In the furnace it affords one of the ufual black and opake enamels. To the fouth-Vv-eft of a decliWty of Rua we find great m.affes of a volcanic rock that has fallen down, the feltfpars of which are an exception to thofe of the innumerable lavas defcribed in this work on account of the extraneous bodies enclofed within them. This rock, the different pieces of which are of different colours (fome being afh-grey, others red, others of a pale violet), is of a petrofiliceous bafe, with an earthy grain, and contains, hefides hexagonal micas with oblique fides, tranfparenc feltfpars, cubical, prifmatical^ ( =8? ) l^nfmaticaljand fometimes amorphous, whlcfi give fparks ftrongly with fleel, and form very brilliant plates. The hirged are live lines and three quarters in length. Each of th^fe feltfpars inchides within it a fmall portion of the petroiiliceous bafe, which forms in it a kind of nucleus, and occupies a confiderable part of its fubftance. But to what caufe arc we to afcribe this Angularity ? I can conceive no other method of explaining it, but by fappofrng, that when the integrant particles of the feltfpars, diffeminated in the earthy and liquid i^afe, united by the force of aggre- gation in cryftallizcd mailes, each of thefe jnafTes included a fmall part of tliis bafe, greater or lefs in quantity. The rarity of the phenomenon, however, fuppofes a local cir- cum Ranee, which had a dire^^t relation to this fmgular combination, and of the nature of which I am ignorant. The feltfpars fufe in the furnace, and be- come intimately mixed with the bafe in fuch a manner, that the refult is a folid, white, femi-traniparentglafs, with black fpots,occa- fioned C 288 ) fioned by the micas of that colour which have remained, ina greatmeafure, refradory. I fhall omit to defcribe another porous lava, Hkewife from Rua ; and two of the compact Ipecies, with a horn-ftone bafe, found in that vicinity. I think more de- ferving of attention one difpofed in ftrata obhque to the horizon, which is found on the fides of the road leading from Galzig- nano to Ciefa. This lava'is white, and has the compa£l- nefs of fine carbonates of lime, which it re~ fembles in appearance, fracture, and weight. It affords a few fparks with fteel, and is dul:inguiihed from other lavas by numerous points of a delicate green, fcattered over the white ground ; but which, to be viewed diflinctly, require a lens with a ftrong light. When thus magnified, v\^e find that they are a femi-pulverous earth, which may be de- tached with the point of a needle, and is placed between the fiffures of minute amor- phous maiTes of fhining, white, and ex- tremely ( 2Sg ) tremely tranfparent quartz. I know not whether this powder be a decompolition of quartz, which, however, does not appear very probable, as it is found deep in the in- ternal part of the lava, where it is not in the leaft altered ; or whether it be an ex- traneous and adventitious fubftance. Be- fides the quartzofe grains, the petrofiliceou? bafe contains a few very fmall feltfpars, which, from their changeable briiliancrj, their rhomboidal form, and their being compofed of minute laminse, cannot be confounded with the quartzofe grains. It is neceflary to obferve that the bads of this lava, in the furnace, ferves for a flux to thefe quartzofe grains ; the relult being a homogeneous and white enamel, without the fmaileft appearance of any remains of the quartzofe grains, or the feltfpars. Another lava, found on each fide of the road, in a place called the Pigozzo, oppofite VOL, III. U Catajo, ( ^9o ) Catajo, IS In no refpecl dliFerent from this, except that the quartzofe grains are not accompanied with green fpots. It yields in the furnace the fame volcanic produdt. At Monte Niiovo we find feveral mafles of a lava which deferves our notice, from its being reduced to fuch a ftate that it is pulverable by the mere prefllire of the fin- ger. It has an argillaceous bafe, and con- tains an abundance of feltipars v/hich have preferved their prifmatic figure, but are ne- verthelefs pulverable. It is rare, in volca- nic places, to find feltfpars fo much injured, even where they have been adted on by fulphureous acids ; of which there are here no traces; and therefore this decompofition feems to be derivable from the humid ele- ments, and other caufes in the atmofphere. On breaking this lava we difcover fome minute octagonal and hexagonal prifms, obliquely truncated, lefs foft than the bafe to which they are attached. They do not in the leaft appertain to the genus of either fhoerls ( 291 ) flioerls or feltfpars ; and, in their external charaders, feem not to difFer eiTentially from the lava itfelf. Among the number of the pitch-ftone lavas- already mentioned there is one which muit peculiarly attracfi the attention of vol- canifts, from the pumices it contains. Mon- felice, one of the Euganean mountains, whicn ftand^ detached, and is of a moderate extent and height, is partly compofed of a white argillaceous i .va, of an earthy afpedt, in which we find this peculiarity ; only that, while t'le pumices of the pitch-ftone lava are derived from the parts of it being dilated and tumefied by gafeous elaftic fub- ftances, thofc of the prefent lava appear to be adventitious, confifting in white globules eafily feparable from the bafe, from which probably they were taken when it was in a fluid flate. Except that they are lefs, they confiderably refemble the pumiceous globules of Pompeii near Vefuvius ; and both, in the furnace, produce a fimilar enamel. U 2 This ( 292 This lava, befides the pumices, contains elegant feltfpathofe cryftals, which, toge- ther with it, completely vitrify in the fur- nace. Monte d'Arqua was the laft which I vifited. Its fummit is compofed of a grey compa6l lava, which has a horn-ftone bafc, affords fparks with fteel, and contains mi- caceous and feltfpathofe cryftals. This lava is found in fome places in ftrata nearly ho- rizontal. To thefe lavas, which I found on the fpot, while accompanied in my refearches by the Marchefe Orologio, I fhall add a few others from the Monte del Catajo, which were afterwards noticed and exa- mined by that iliuftrious nobleman and naturalift, who vifited every part of that mountain to which his villa is contiguous, and coUeded fpecimens of the fpecies of moft importance, obferving the places where they were found. At my requeft hs tranfmittcd them to me, with their fe- ( 293 ) veral defcrlptions, which I fhall here briefly give the reader, only making fuch altera- tions as appear to be necefTary. T. Is one of the fineft lavas of the Eu« ganean mountains. Its bafe is feltfpar in the mafs, but it is with difficulty recog- nized from its exterior charad:ers, the fire having changed it into a vitreous lava. It is of a cinereous colour, compafl:, but not very hard, on account of its numerous fif- fures* It contains cryfcallized micas and feltfpars ; and the enamel it produces in the furnace, fimilar to that of the pitch- ftone lavas, forms one homogeneous mafs with the fufed micas and feltfpars. This lava, on which the noble palace of the Marchefe degli Obizzi is built, occupies an extenfive tra mon fire, how fuch a flone can be liquefied and flow without lofmg one of its natural lineaments. LaRly, the lavas with a piteh-flone bafe, which are very abundant in thefe moun- tains, are a third objed: deferving our attention. It is not certain that Etna or Vefuvius have ever thrown out a fingle fragment of them : and the fame obferva- tion may be made of the reft of the Phle- grsean fields. In Lipari alone, among all the Eolian iflands, I have found detached and fcattered pieces, but which had rather pafied into the ftate of enamel *. The volcanic pitch-ftone is not peculiar to the Euganean mountains : the volcanos of Hungary and thofe of Auvergne furnifh fome noble fpecimens .of it. It remains, however, to enquire whether it is to be clafled among the lavas, or rather whether it has ever formed currents. We may be. * See Chap. XVII. fatlsfied ( 3it ) fatlsfied that it muft, as well as the pitch- flones of the ifles of Ponza, from the ob- fervations of Dolomieu. According to this author, the fimilar kinds of lavas found in thefe two countries have for their bafe the feltfpar, with a very confiderable quantity of magnefia * ; and, in a note to his work on the iflands of Ponza, fpeaking of the Vicentine lavas, he remarks, that he found among them fome produdtions of pitch- ffcone, which he could not confider as a true volcanic produd:, but rather as a con- cretion formed afterwards by the decompo- fition of volcanic matters ; and that they contained a great quantity of magnefia* From which we may gather that magnefia, in the opinion of this author, is one of the conftituent principles of the pitch-ftones of volcanos. The truth however is, that in the three analyfes above mentioned, of the pitch-ftone lavas of the mountains of Sieva and Bajamonte, two of the Euga- cean mountains, J did not find an atom of this earth, * Notes on Bergmann. X 4 The ( ^^2 ) ■The Abbe Fortis affirms tbat he had difcovered, In the pitch-ftone lavas of Monte Brecaion, the evident tranfition of petrofilex into pitch-iftone lava ; and on comparing the analyfes of petrofilex made by others, with thofe I have made of three pitch-ftones, it will be found that they perfeftly agree — with no other difference deferving notice, but that the petrofilex ufually contains no iron, of which a very fmall quantity was found in the pitch-ftones I analyfed. ' • As' it has been already fhowm, that pltch-ftones that are not volcanic and thofe which are, are of the fame genus, I find little drfEculty in believing that many of the latter are derived from the former. In. all my refearehes relative to the rocks of the volcanos in the two Sicilies, I have always been attentive to difcover at what degree of heat they fufe in our common fire, that I might infer the adivity of the ' ' fubterranean' ( 3^2, ) fubterranean conflagrations by which they have been, inelted. I have proceeded in the fame manner with refped to the volca- nic rocks 6f the Euganean mountains, em- ploying conftantly the fame fire, I mean that of the glafs^furnace. As to the bafes of thefe rocks, we have already feen that not one of them proved refradory, not even excepting the hardeft and moft corn- pad petrofilices, which have formed cur- rents. The feltfpars arid micas, with which the Euganean lavas fo abound, appeared equally fufible. The eafy fufibllity of the feltfpars excited in me fome furprife, when I confidered the infufibility which, if not conftantly, is very frequently the property of the fame (lones in the rocks of other volcanos when expofed to the fame degree of heat -, and, as I obtained the fame fufion when the Euganean feltfpars v,^ere detached from their bafe, it cannot be alleged that this bafe ferved as a flux. A dif- ference f6 remarkable, it feems probable, can only proceed from the different proportionfi z of ( 3^4 ) of the conftltuent principles, unlefs w^ choofe to fuppofe that in the Euganean felt- fpars, befides the elements common to that ftone, there exifts fome other which facili-^ tates their fufion, though it is imperceptible to the eye^ the external appearance of the fufible exactly refembUng that of the infu- fible feltfpars. With refped to the produd by fufion in common fire, of the lavas of the Euganean mountains, it is found to be exadly the fame with that of other lavas, I mean an enamel or glafs, as appears from what has been faid above. The adion of our com- mon fire, therefore, deftroys in thefe volca* nic produds that primitive charaderiftic ftrudure which had been left in them by the fubterranean conflagrations. The bafaltes of Vulcano and Felieuda are produds of fire, and equally fo are thofe of Monte Roflb, Monte Ortone, and Catajo j for they are integrant parts of continued \olcanic rocks j which truth did not efcape the ( 3^5 ) the acute obfervatlon of Sir J. Strange and other difcerning naturalifts. It deferves re- mark, likewife, that the trapp has taken a prifmatic configuration at Catajo, in the dry way, and in Sweden in the humid, as has been elfewhere fhown. This may teach us, that we can only determine by local circumftances in which of the two ways bafaltts have been formed. Thefe two ways, however, have united in the formation of the hills and mountains of Padua, as appears from the mixture of calcareous carbonates with lavas. This combination, which is not found in the Eo- lian ifles, but is obfervable in the Vicentlne mountains, at Vcfuvius, in the extinguiilied volcanos of the Val di Noto in Sicily, in thofe of Portugal, and Germany near Old- Brifach, and probably in other volcanized mountains, fhould incite the naturalift to enquire which of thefe two contrary agents was prior in point of time. I (hall not enter into this queftion, which indeed appears to be precluded by the obfervations of the Abbe ( 3i6 ) Abbe Fortis ; my only objed, In fad, being, in this (hort excurfion to the Euganean mountains, to collect feme of their volcanic produds in the places where they are found, v;ithout entering into a very minute examination of the nature of thofe places, and faithfully to give fuch a defcription of them as might contribute to enlarge our knowledge relative to volcanos. CHAP. ( yy ) CHAP. XXI. EXPERIMENTAL ENQUIRIES RELATIVE TO THE NATURE OF THE GASES OF VOLCANOS, AND THE CAUSES OF THEIR ERUPTIONS. The perfeEl refemhlance of the effecis produ- ced by fame gafes of volcanos and thofe of others generated in lavas ^ and other fimilar fubjiances^ -when re- melted in our common Jire^ may enable us to difcover the nature of the former^ by invefigaiing that of the latter — Matrajfes of clay^ filed to a cer- tain height with volca?iic products^ expofed to the fire of a chemical furnace^ and com- municating nsoith a pneumatic-chemical ap- paratus prepared 'with mercury — Experi- ments made in this manner on the fpotted glafs of Lipari— Phenomena obferved njuithin the matrafs during ignition — No gas appeared above the mercury — Ebidli- ent Jlate in which the glafs was found when ( 3'8 ) *vohen left to cool in the matrafs^ after haV" ing been eight hours expofed to the fre — No reafon to believe that the bubbles ijoere an effect either of the atmofpheric air in- cluded in the int erf ices of the glafs^ or of any permanent gas — ConjeEliire that thefe bubbles proceeded from the gaffication of the glafs itfelf occafioned by the vehemence cf the heat — Proof of this conjecture in the piiref glafs of Lipari — 'The breaking of the matrafs in the frongcf heat occafioned by this gaff cation- — Caife "why the glafs rendered gafeous does not pafs into the pneumatic apparatus — Breaking of a third matrafs by the violent gaffcatioji of aii enamel of Ifchia — Ena?nel of Procida dur- ing the gaff cation fiblimcd^ and adhered to the fides of the matrafs in the form of a thin crtfly and ena7nel points — Confrination cf this in another matrafs^ ^f^'S ^^^ fame enamel — Evident fgns of this fublimation in the fufon of fome volcanic fubfances placed in the furnace in covered crucibles — Reafn why this fublimation does not appear in every experiment — Black faBi- tious- ( 3^9 ) thus glafs which does not produce gas in the furnace^ but njuhich produces it, y letting fall the fame fluid on iron or copper 171 a flate of fufion — Explofiojis and detonatio7is in water^ as foofi as it touches the furface of melted tin or lead — ' Ihefe explofions greater vohen the water remai7is enclofed within thefe melted metals -^Remar-kable diverfities in thefe expert- fnents — Kxperime7its 07i lavas melted in the VOL. in. Y furnace— ( 322 ) furnace — No explcjion produced by pouring water on them^ when it is not introduced , within them — -The explofion the Jlronger the more the water penetrates into them — ■ The reftdts the fame 'when fea-water is I fed iiftead of frefh — Conclifion^ that nsoater is incapable of producing eje&ions 'when it falls on the burning craters of volcatws ; but that it muft produce very violent one& when it penetrates into them from below or by the fides — The different permanent gafcs dfcoverable in volcanos feem alone to be the caufe of the more mo- derate and fmaller eruptions — The fymp- toms^ and inceffant eje&ionsy of Stromboli cannot be caufcd by the evaporation of water ^ nor by that of the liquefied lava^ but mujl depend on the aEiivity of fome permanent gafes — Enqui?y whether this gcis be hydrogenous — That fuppoftion re- jeBed — // cannot be fuppofed to be atmo' fpheric air — The hypothefis which has recourfe to oxygenous gas to explain the phenomena of the volcano of Stromboli^ feems leaf improbable, HAVING ( z^z ) JriAVING finifhed the defcriptlon of the products I obferved in my excurfion to the Euganean mountahis, I might confider my Volcanic travels as concluded ; br.t agree- ably to the plan I propofed to myfelf in the Introdudion to this work, it ftill remains for me to difcufs fome particulars which have a relation to volcanos in general, and are too intimately conneded with the fub- jeds hitherto treated of to be omitted, without juftly incurring the blame of the reader. In various parts of this work men- tion has been made of the gafes of volcanos. It has been fhown that, by their elafticity, ftony fubftances fufed in the fire are rare- fied, inflated, and become cellular ; as is proved by a great number of lavas, glaiTes and enam.els. We have feen that, by the violence of thefe gafes, the liquefied matters are haftily raifed from the bottom of the craters to the top, filling their whole in- ternal capacity, and flowing over their fides ; fmce, by the adion of the fame gafes, we frequently obferve fimilar pheno- Y 2 mena ( 324 ) mena in the furnace. But, in the prefent age, in which naturalifts and chemifts are fo earneftly employed in analytical re- fearches relative to the nature of aeriform fluids, it is not fuffieient to affert and prove the prefence of gafes in liquefied volcanic products ; it is likewife incumbent on us to endeavour to difcover their peculiar nature, and thus prepare the means to afcertain what part they may take in the eruptions of volcanos. A fecond intereftlng objcd pointed out in the Introduction, and which well merits difcuffion, is the enquiry relative to the adivity of volcanic fires. It is true, that from a number of experiments which I made in the furnace, both on volcanic pro- ductions, and on the primitive rocks, almoft all of which I fubjeCted to fufion, it appears to be proved that this activity may not be very great ; as a not very ftrong common fire is fufficient to produce the fame effeCts. From thefe experiments we certainly ac- quire fome knowledge of which we were not ( 3^5 ) not before in pofleflion ; but I do not con- lider the problem as undeniably folved ; lince to thefe facts a great number of others of a contrary nature may be oppofed, of which, as they are related by writers well deferving credit, I cannot omit the exami- nation. I (hall impartially confider the weight of each, and afterwards give my fincere and unbiaiTed opinion* Thefe two fubjeds I (hall proceed to confider in two chapters, between which i (hall infert a very fhort one, containing an account of a chemical difcovery made ia the courfe of my experiments. Thefe will conclude my enquiries relative to thefs truly terrific phenomena. Having obferved that the bubbles, vacui- ties and tumours, which are generated by aeriform fluids in many lavas, glafles, and enamels, are likewife produced by the fame fluids in the fame bodies, when expofed to common fire ; I determined to avail myfelf of that means to difcover the nature of Y 3 thefe ( 32S ) thefe fluids. I refolved, in confequence, to fufe within mairafles various volcanic pro- dudls ; fucii, efpecially, as, by the fupera- bundance of their gafeous bubbles, rife from the bottom of the crucibles, and expand over them. I fitted the necks of the ma- trafles to a chemical pneumatic apparatus v>^ith mercury, in order to colled: and exa- mine the gafes which fhouid be difengaged, by the adion of the fire, from the liquefied fubftances. The matrailes were of clay, of the fame kind with that ufed for the re- ceivers in which melted glafs is kept for the making of different veUels in a glafs-houfe. They had a fpherical bottom with a long neck, and were of the thicknefs of lix full lines. I tried them by plunging them into water and blowing ftrongly into them, when I did not find the fmallefc bubble of air efcape. For the greater fecurity I coated them externally, and tried them with the air-pump ; but I did not perceive the leafl hiffing found that might indicate the efcape of air. I repeated thefe proofs, likewife, after I had made my experiments, and thus ■ ' was { 3^7 ) was certain that the fluids I found in the veflels could not have entered them from without. To the neck of the matrafies I luted a glafs tube, the other extremity of which was inferted in the mercury ; in order that, if any liquor (hould be feparated from the volcanic matters, I might collecSt it. Such a liquor was, in fadt, feparated ; and I found it to be of a nature which I never could have imagined. I fliall defcribe it in a diftind: chapter, to prevent the confound- ing of obje(5ts totally unlike in one difcuf- fion. The firft produd on which I made my experiments, was the fixth fpecies of the glaffes of Lipari ; that which I have de- fcribed as having a black ground fpot- ted v/ith white points *. I placed twelve ounces of it in a matrafs, reducing it firft to powder, as I did all thefe produds, before I began my experiments, to deftroy the bubbles that might have been produced by * See Chap. XV. y 4 the ( 3^3 ) the volcanic fires. The matrafles were of that capacity, that the twelve ounces of every product fcarcely occupied one third of their body ; fo that the melted matter might inflate and tumefy without impedi- ment. This glafs I expofed in a chemical fur- nace to a fire of eight hours continuance ; three with a moderate, and five with a ftrong heat. At the end of an hour and three quarters, there appeared upon the mercury a fmall quantity of aeriform fluid, which, when examined, did not take fire at the flame of a candle immerfed in it, no|* extinguifh that flame, nor render it brighter, but left it precifely as it was in the atmo- fphere ; confequently this fluid muft be confidered as common air, that is, a portion of that contained in the vefl^els ufed in the experiment. That fuch was the fadt, I was ftill more convinced by fubjeding this fluid to other experiments. Another fmall quan- tity of fluid afterwards colled>^ ) iv"hen I have fpoken of volcanic produds become ebullient within the crucibles, and alfo of thofe which have pafled into fuch a ftate by the adion of fubterranean fires ; nor do I conceive that it will be contro- verted by any perfons. Whoever has feen fuch produdiions, will admit that this fup- pofition is fupported by the flrongeft evi« dence. But what may be the nature of thi$ fluid ? We cannot imagine it to be atmo- fpheric air which occupied the pores of the pulverifed glafs contained in the matrafs, fmce this muft have been expelled at the very beginning of the fufion ; whereas the tumours on the furface of the liquid glafs were produced in the ftrongeft heat of the fire, and continued as long as it remained ; an inconteftable proof that, then, the fluid in queftion copioufly iiivefted and agitated the vitreous mafs. This fluid, likevvife, cannot be called permanent, like the differ- ent aeriform gafes, fince, w^ere it fo, it would have colle(5ted on the mercury. I therefore began ( 333 ) began to fufpe^l that it muft be an evapo- ration of the glafs itfelf, which, in confe- quence of the vehement heat, paffed from the ftate of fluidity to that of vapour or gas, and continued fo while the degree of heat remained the fame. Thus we fee metals, a(Sted on by a violent fire, boil and evapo- rate : and the opinion of Lavoifier feems extremely probable — that almoft all natural bodies are fufceptible of exifting in a folid ftate, the ftate of fluidity, and the aeriform ftate ; thefe three different ftates depending on the quantity of caloric combined with them. The evaporated glafs, however, which caufed the bubbles, did not pafs into the chemical-pneumatic apparatus, becaufe the heat near the neck of the matrafs, being Icfs violent, was incapable of preferving it in a gafeous ftate. To afcertain the truth of this conjedure, it was neceftary to have recourfe to other proofs. I, therefore, proceed to the fe- cond experiment, in which the circum- ftances were the fame as in the former ; except ( 334 ) except that, during the laft four hours^ the fire was violent. The glafs on which I made this experiment was the fifth fpe- cies of the glafles of Lipari ; which is the xnoft perfed: and the pureft glafs afford- ed by the ifland. The refults were as fol- low : The fmall quantity of air which rofe above the mercury during the ignition was found to be purely atmofpheric. After half an hour's violent fire, I perceived, through the glafs tube inferted into the raa- trafs, the vitreous mafs beginning to rife in tumours, which prefently rofe fo Itrongly that I could only fee a tumultuary inteftine motion of the liquid fiery mafs. In thefe experiments I took the precaution to open, from time to time, the fmall door of the furnace, to examine the appearance of the outfides of the matraffes. After a conti- nuance of a very ftrong fire for two hours and three quarters, I perceived that the matrafs was broken, and that a long thread of glafs had begun to iffue through the fradure. ( 335 ) fra<3:ure, I therefore caiifed the fire to be extinguiflied, and, after the matrafs had cooled, examined it within and without. I found, on one fide, an angular fifTure, four- teen lines in length, from which hung, ex-' ternally, two thin cones of glafs, which, however, was the only part of the fluid that had ifTued from the matrafs. Within was an oval bubble, occupying two full thirds of the body of the matrafs. This fad: ap- peared to me of confiderable importance. It is evident that this bubble was the efFe£t of an aeriform fluid, w^hich by its expanfive force had not only produced that vacuity, but broken the matrafs by ftriking forcibly againft its fides. It is likewife equally clear, that this^fluid could be no other than the glafs itfelf, rendered here much more gafeous from the greater violence of the fire. The remainder of the glafs not occupied by that bubble was full of minute cavities. The accident of breaking, accompanied v^ith a very large bubble, happened to ano- ther matrafs containing an enamel of If- £ chia. { 336 ) chla. Here,' therefore, the ftrofig gafifica- tion of the enamel, by the violent energy of the fire, had produced a vacuity which oc- cupied more thjln half the matrafs, forcing up the enamel, and compelling it to afcend through the neck ; breaking at the fame time the fides of the matrafs. In a fourth experiment I made u'fe of an enamel of Procida. During a continuance of eight hours in the fire, I obferved it at- tentively, but could not perceive any figrt of ebullition. I afterwards broke the ma- trafs, and found that, notwithftanding its' complete fufion, and that it was in every part full of bubbles, the bubbles were in general fraall. No particular gas appeared above the mercury. Examining, afterwards, the interna] fides of the matrafs, above the hardened enamel, I made an obfervation that appeared to me i-mportant. A great number of very minute globules of the fame enamel adhered, here and there, to the fides, at the diftance of half ( 337 ) half an inch, an inch, or two inches, frorti the enamel below. Befides thefe globules a kind of thin ftreaks of enamel were at- tached to the fides ; and where the neck was wideft there was an accidental fwelling, which formed a ring round the inner fur- face. Around this ring, on the fide next to the body of the matrafs, was attached a very thin thread of the fame enamel. It is not to be fuppofed that the enamel during its vehement fufion could have rifen to the places where the traces of it fo evidently appeared ; fince then the fides would have been varniflied over with it ; as we fee in crucibles in which the melted matter has rifen and funk again. Here, on the con- trary, the fides of the matrafs, in the places between thefe ftreaks, were as perfedlly free from any appearance of enamel, as they were before the expetiment Was made. I then could not but recoiled: the experiment of Lavoifier, and others, of a plate of gold filvered over by expofing it to the fumes of filver exhaling by the adion of a vehement fire ; as alfo another, its companion, in VOL. III. Z which ( 338 ) which a plate of filver was gilt by a like efFed: of fire on gold. I concluded, there- fore, that the globules and the other traces of enamel congealed on the fides of the matrafs were the refult of the fublimation of the enamel itfeif at the time it Was ex- pofed to the moft violent heat, A- doubt however remained, which it was neceflary to remove. It feemed not impof- fible that, in putting the pulverifed enamel into the matrafs, fome fmall portion of the powder might have adhered to the fides or the fwelling in the neck, and afterwards have been melted by the adion of the fire. But this doubt was completely removed by obferving the fame appearance on the fides and neck of another matrafs, in which an equal quantity of the fame enamel had been placed, not in powder, but in pieces. This obfervation, which confirmed me in my opinion that the ebullition of fubftances fufed in matrafTcS was a confequence of their vaporifation, determined me to make a general ( 339 y a general revifion of the various crucibles I had before made ufe of in the furnace, and which had contained veficular volcanic pro- duds 5 as 1 had not before examined them with a view to this objedt, believing that the veficles or bubbles were caufed by fome permanent gas. There were not a fev^r, to fay the truth, the internal fides of which exhibited, above the fufed produd:, fmall drops of the fame fubftance : but it was eafy to perceive that thefe were not coUeded there by fublimation ; but were thrown to that height by the inreftine motion of the produds in fufion. There was, however, no crucible which prefented that thin coating, or that aggregate of infinitefimal globules, obfervable in the laft experiment, and which manifefted an evident fublimation of the fufed fubflances. This, indeed, did not furprife me ; as the crucibles were of a cylindrical, or inverted conical form, and open at the top ; fo that the particles which might fublime met with no oppofing body to detain and colled them. Z 2 I, there- ( 34^ ) I, therefore, refolved to endeavour to af- certain whether this fubUmation took place, likewife^ in crucibles in the furnace when covered with other crucibles. I had nine- teen in the whole, within which I placed thofe kinds of volcanic matters which are moft liable to inflate in large bubbles. On the fides, and at the top of three of the inverted crucibles that ferved as covers to the others, I perceived evident figns of fub- limation ; in fome fine vitreous traces, and a great number of extremely minute vitreous globules, which, in fubftance and colour, did not in the leaft differ from the refpedive matters fufed in the three crucibles. But nothing fmiilar was apparent in the other three crucibles. The former of thefe fads, which is pofitlve, is a new and luminous proof of the gafification of volcanifed produc- tions ; and the latter, which is negative, no proof to the contrary ; fmce, though every one of thefe fixteen produds were ebullient within the crucibles, and therefore, from what has been above faid, there is the ftrong- eft reafon to believe they were rendered fo by { 341 ) by internal vaporlfation ; it Is not neceflary that they fliould fubllme with evident ex- tern?' indications ; this depending on the nature of thefe fubftances ; fome fubhming with one degree of heat, and others requir- ing another and a greater. Hence we may perceive why, in the different experiments in different matraffes, indications were not difcernible of this fubUmation ; though I have no doubt that it would have been ob- tained Ukewife in them, had the fire been fufEciently increafed. But to return to the experiments I was relating. After having made thofe now defcribed on volcanic glaifes and enamels, I proceeded to fubjed: to the fame proof a fad:itious glafs ; of that kind which is of a black colour, and has little tranfparency, and which is ufed in many countries to make thick bottles to contain wine. I took one of thefe bottles, which had never had in it any wine or other liquor, and placed twelve ounces of it, as before, in powder, within a matrafs, I had before cbferved that this Z 3 glafs ( 342 ) glafs in the furnaces of Pavia requires a longer time to fufe it than common white glafs, and that in its actual fufion it is little or not at all inflated. The fadt, however, is, that after remaining the ufual eight hours in the furnace, the matrafs having been broken, the ebulUtion and exaltation ap- peared to have been fuch, that the glafs had rifeJi to the middle of the neck ; though when the heat had ceafed it had funk to the bottom of the belly. This was evident from a fhining thin vitreous coating, occu- pying the whole interior furface of the matrafs, beginning from the level furface of the glafs lying at the bottom, and proceed- ing to the middle of the neck, where there remained a lump of glafs that entirely clofed the aperture. The appearances which took place in this faditious glafs, both in the matrafs and the glafs-furnace, may be underftood and fatif- fadlorily explained by the theory of the ga- fitication of the fubftances hitherto treated pf. The heat of the furnace was fufiicient tQ 4 C 343 ) fafe this glafs, but not to convert It Inro gas. The chemical furnace, being more adlve, rendered it gafeous. Hence arofe that violent tumefadion ; though the adion of the fire having afterwards diminiflied, the glafs confequently paifed from the aeri- form to the liquid ftate, and defcended to the bottom of the matrafs, where it congealed. That no permanent gas had any part in this ebullition is proved by the mercurial pneumatic apparatus, in which it muft have collected, more or lels, above the mercury : but nothing was found except common air, as in the other experiments. Fitherto I had only ufed thofe volcanic products, which, in the furnace, are filled Vv'ith bubbles more than others ; being de- fu'ous to obferve whether the f.ime effedl would take place in the matralTes, as was in fad the cafe. I afterwards refolved to make experiments on others lefs liable to inflate in bubbles. To avoid needlefs pro- lixity, however, I fhall only ftate the qua- Z 4 llties ( 344 ) lities of the fubftanccs I ufed, and the re- fults obtained. Thefe fubftances were fix in number : a lava with garnets from Vefuvius -, another, which, vAicn I vifited that volcano, had re- cently flowed ; a lava of Vulcano, invcfted with a criifl of enamel j the lava continu- ally ejedted by Stromboli ; the lava Vv^hich, in 1787, iflued from the higheft crater of Etna ; and a folid pumice of Lipari, I have already defcribed each of thefe pro- du.d:s, when treating of their refpedlive vol- Canos. After they had been expofed to the fire eight hours, in matraifes, nothing was found to afcend above the mercury but atmofpherip air, or a portion of tliat the veffels con- tained. Thefe fix produ6:s, therefore, af- forded no indication of any perm.anent gas ; but they evidently fliowed that they had pafTed from the ftate of liquidity to |:hat of a flroncj galification, from the quantity ( 345 ) quantity and fize of the bubbles they con^ t.aincd. This is confequeiuly another an4 a mofl convincing proof, that a greater gafificaiion of flony fubPtances may be ob- tained ill a very firong heat than in a weaker. From thefe ten experiments I conceive niyfelf fufficiently warranted to conclude, that thofe bubbles and inflations of various lizes, which v^'e fo frequently obferve in the products of volcanos, are hj no means canfed by the aalon of any permanent gas, but by that of an aeriform fluid produced by the exceffive attenuation of thofe fame produdis in confequence of heat. I do not know that fnr/ilar experiment^ have been made by any other perfon ex- cepting Dr. PrieRley, Vv'ho defcribes three, whicl:^ I thinl>: proper to be mentioned here, as they differ fomewhat from mine. This liaturaiift, having fufcd in a fand-fcone re- tort 4-^ ounces of Iceland lava, obtained 20 jnpafures of air, the half of wbich, about the beginning ( 346 ) ^ beginning of the procefs, was carbonic acid gas, and the remainder in purity 1.72 ; and extinguifhed a candle. He remarked that the interftices of this lava contained a fand, which he was not able to feparate from it. 5^ ounces of lava of Vefuvius gave 30 nieafures of air ; the firfl portion of which fliowed a flight appearance of carbonic acid gas ; and the remainder was azotic gas from the degree 1.64 to 1.38, with refped; to what came laft. The retort broke by the inflation of the refldue, when it became cold. Another ounce of lava, of the confifl:- ence of a hard fl:one, gave only 2^ mea- fures of gas, principally hydrogenous, de- rived, as he conjed:ured, from the gun-bar- rel in which this experiment was made. From thefe refults the Englifli naturallft infers, that it is probable that the true lavas do not afford much air ; which, however, according; ( 347 ) according to him, muft depend on the de- gree of heat to which they have heen ex^* pofed in lubrerranean fires *. Leaving unnoticed the laft of thefe ex- periments, as being too equivocal, and con- fiderlng only the two former, I could have wiflied that Dr. Pricftlty had explained himfelf more fully relative to thefe two la- vas ; and afforded us certainty that the two flones on which he made his experiments were really volcanic. But fuppofing they actually were fuch, if we oppofe our ten procefTes to the two of Dr. Prleftley, the ccnfequence to be de- rived will be, that volcanic products are not always deftitute of permanent gafes ; which dedud;ion will be found perfectly to agree with obfervaticns we fhall have hereafter to make, and is by no means contrary to thofe already made. In the latter, I have princi- pally fhown that the numerous pores in volcanic products expofed to our common '^ Experiments and Obfervaticns on Air, Vol. IV. iire. ( 348 ) £re, and, confeqiiently, thofe fo extremely fimilar frequently found in lavas, are pro- bably not the effects of permanent gafes, but of the gafification of the lavas them- felves : and this difcovery remains uncon- troverted notwithflanding the above- cited obfervations of Dr. Prieftley, I fhall now proceed to enquire what part this aeriform vapour ad:s in the eruptions of volcancs. Where it exifts in the depths of a volcanic crater, abundantly mixed with a liquid lava violently urged by fubterra- nean conflagrations, I can eafily conceive that by its energetic force it may raife the lava to the top of the crater, and compel it to flow over the fides, and form a current. Art can imitate this great operation of na- ture, on an infinitely lefs fcale. I placed in a glafs-furnace a cylindric crucible, one foot high, and two inches and a half in breadth, which I filled half full with one of thofe volcanic products which moft inflate a|id boil in the fire. After fome hours, I obferved that the liquid matter began flowly to rife, and afterwards to rife higher until it { U9 ) It at laft overflowed the edges of the cruci-» ble, forming fmall ftreams down its fides, which, when they reached the plane on which the crucible flood, gave origin to fmall currents, if that plane was at all in- clined. When I put more of the fame pro- dudl into the crucible, the currents became larger. If the plane was then taken from the furnace, and the fmall currents thus pro- duced examined, they were found full of minute bubbles, as was likewife the matter which remained in the crucible. This cu- rious experiment I made with feveral glafles and volcanic enamels, as alfo with a variety of cellular lavas, and always with the fame fuccefs. It is likewife probable that this elaftic vapour, when collected in a large quantity, if it finds under the earth any impenetrable obftacle, produces local earthquakes, and fub- terraneous thunders and roarings ; burfting open the fides of the lava, and forcing out the lava. We have an example of this, if 1 may fo fpeak, in miniature, in the two matrafles ( 35^ ) matrafles broken by this fluid from its exu- berance and the refiflance it met with. I afterwards made in the furnace fome expe^ riments more decifive. I caufed three ma- trafles to be made, on purpofe, of clay, the fides of which were an inch thick, and the belly, which I more than half filled with a cellular lava, four inches and three quarters in diameter ; the neck projected in part from the furnace. At the end of eleven hours the three matralTes were broken in the belly, with feveral filTures, through which the lava iflued. Having afterwards broken up the matralTes, I obferved that they were entirely filled with a glafs full of large bubbles, which did not extend beyond about half the neck, becaufe there the heat was no longer iufficient to keep it in fafion. It was eafy to underftand the caufe of the matrafs breaking. The glafs rarefied by the aeriform vapour, the belly being unable to contain it, had rifen into the neck ; but lofing there its fluidity from the cold, it could advance no further ; and, its inflation in- creafing from the vehemence of the heat, the ( 2S-^ ) the matrafs at length was forced to open* I find, therefore, no difficuky in beUeving that fuch a vapour may produce fimilar effecls, on a larger fcale, within the* earth, when it meets any obllacle to its expanfion. I cannot, however, fo eafily admit that the fame vapour is the caufe of the f ery hail or eje£lions of volcanos, as the break- ing of the matraffes happens without the leaft noife, and without the ejedlion or fcat- tering of the contained matter. I atten- tively watched two matraffes placed in the furnace when they began to open, and I obferved that the apertures enlarged infen- fibly ; which proves that the power of this vapour, though fuperior to the refiftance of the matraffes, acts neverthelefs very llowly ; whereas the agent which hurls the burning matters into the air from the volcanic mouths mull a6t with the utmoft rapidity and violence. To explain thefe ejections, therefore, we muft have recourfe to other principles. Modern ( 3^^ ) Modern volcanifts have fuppofed that thefe are various gafes, which, endeavouring to obtain a palfage through the liquid fub- flances In which they are enveloped, force them impetuoully out of the crater, and fometimes to an enormous height. The prefence of thefe gafes is certainly not ob- fcurely manifefted by the hiffing founds that are heard during the raging of volca- nos, as has been obf^rved of Vefuvius, which, from its vicinity to Naples, is the volcano that has been mofl: attentively exa- mined. Simikir hifling founds I likewife obferved at Stromboii, of the eruptions of Vv^hijh volcano I Ihall prefently have occa- fion again to fpeak. But what is the nrture of thefe different gaifes ? It is evident that to afcertain this it would be neceiTary to colled: them in the volcanic effervefcences for a chemical exa- mination, which is perhaps impoffible, from the manifeft danger there would be of fall- ing a viftim to fo imprudent a curiofity. We can therefore obtain no knowledge df them ( 35:^ ) them but by an indired way, that is, by obferving the gafeous fubftances which arife from volcanos when they have return- ed to a ftate of tranquillity. If we perufc the works of writers on this fubjedt, we fhall find feveral of them named ; fuch as hydrogenous gas, fulphurated hydrogenous gas, carbonic acid gas, lulphureous acid gas, azotic gas, &c. thefe different gafes having been found in volcanic countries *, But, befides thefe concurrent caufes, It is extremely probable that, in the greater and more terrible ejedlions, another more powerful principle comes in aid, which is * From the agents which by their expanfive force produce the eruiSlations of volcanos I do not mean to exclude caloric, which fometimes mud neceffarily co- operate J that is, when in the volcanic recefles a greater quantity of this fluid is fuddenly difengaged than can eafily find a pafTage through the pores of the furround- ing bodies. Then, as Lavoifier has obferved. Caloric will adl like other common eiaftic fluids, and overturn C'^'ery thing which oppofes it. Except in this circum- ftance, however, I do not fee what immediate adlion it can have in volcanic eje6lions. v©L. nr. A a water. ( 354 ) water, principally that of the fea. It would be fuperfluous to (how, fince it is generally known, that the volcanos fcattered over the globe, and which at prefent throw out fire, are either furrounded by the fea, ot at a fliort diftance from it ; and that thofe which have long fince ccafed to burn are, for the moft part, at a confiderable di- ftance from it. The confervation, and we may likewife fay the origin of thefe fubter- ranean conflagrations, have therefore a fecret relation to the waters of the fea. There is little doubt but thefe waters com- municate by fecret paflages with the fpa- cious caverns and profound depths which exiftj certainly, in burning mountains ; and, though we are not able to difcover this im- mediate communication from without, it is fufficlently vifible by its effed:s ; I mean the fudden retiring of . the fea at the time of the moil violent eruptions, occafioned, pro- ,' bably, by the vail: volume of its waters abforbed in thofe immenfe caverns. One of thefe retirings of the fea, according to the obfervation of Pliny the younger, hap- 2 p^ied ( 355 ) pened in the reign of the Emperor Titus, in that dreadful ejedion of lava, fmoke, and afhes, which Vefuvius caft forth, and in which Pliny the Naturalift perlihed. An- other fimilar took place in modern times, in the fame fea, during another terrible eruption of Vefuvius, as is recorded by authors worthy of credit who lived at the time. Serao, in his Relation of the Con- flagration of Vefuvius in 1737, referring to the accounts of former conflagrations of that mountain, remarks, that " if not in all, at leaft in the more terrible conflagrations, mention is made of the retiring of the fea as a concurrent circumftance." Steller, in his Obfervations on the Volcanos of Kam- fchatka, remarks, that the greater part of earthquakes happen at the time of the equi- noxes, when the fea is moft fwelled, and efpecially at the autumnal equinox, when its waters are higheft. It is therefore evident that a great mafs of water fuddenly reduced to vapour by fubterranean fires mud caufe prodigious ex- A a 2 plofions, ( 356 ) plofioRS, and detonations, far more violent than thofe occafioned by the elaftic gafes before mentioned. Thus, if a cannon, after having been fired feverai times, be fpunged with a wet rammer which too exadily fits the calibre, the vapour produced at the bot- tom of the cannon, unable to efcape as it expands, will force the rammer out with fuch violence as fometimes to carry away the arm of the gunner. If a fmall quan- tity of water be inclofed in a globe of iron, or any other metal, fo that the vapour cannot efcape, and the globe be expofed to a ftrong fire, it will foon buril with a loud noife, ia the fame manner as if the explofion had been caufed by gunpowder. But nothing, in my opinion, more aptly (hows the nature of the de(lrud:ive explo- iions which volcanos may produce by the evaporation of water, than the fatal acci- dents which fometimes happen in confe- quence of pouring melted metals into moulds not fufficiently dried. An account of cue of this kind may be found in the fourth ( r^7 ) fourth volume of the Memoirs of the Aca- demy of Bologna, which 1 fhall here briefly Hate, as it is particularly applicable to the prefent fubjedl. A bell of a very large fize was to be caft at Modena under a fpacious portico. The metal was melted, and was let flow, through a fmall channel, into the earthen mould, which was at a little diflance under the pavement. But at the moment the melted metal reached the mould, fuch a violent explofion took place, that the metal, the mould, and a great quantity of earth, were thrown up with inconceivable vio- lence. The furnace was blov/n in pieces ; the portico, walls, and beams of the roof torn up and broken in many places ; a large opening made in the roof, the tiles fcattered about, and a wide and deep hole funk in the ground. Some of the byfl:anders were killed, others feverely wounded and hurt, and all overwhelmed v/ith dread and con- fternation. Such dreadful eff*e(fts were pro- duced by a little moifture being left in the earthen mould, through the inattention of the w^orkmen. We may hence conclude A a 3 what ( 358 ) tvhat terrible and deftrudive explofions may be caufed in volcanos by a large quantity of water entering among the fub- terranean fires. Here a queftion naturally arlfes, which it may not be unufeful to difcufs. It can admit of no doubt, that water infmuat' ing itfelf under the burning matter, and fuddenly reduced to vapour by the extreme heat, if it can obtain no paiTage, will caufe the moft terrible erudations. But what effedl will it produce fhould it fall upon the fire, fiippofing it either fea- water or rain ; for the latter may eafily penetrate, through the pores and fiflures of the earth, to the volcanic furnaces ? If we attend to fome experiments, \we fhall be inclined to fup- pofe that the evaporation of the water in the latter cafe will produce the fame effei^ as in the former. Thus, if we throw drops of water on an oily and boiling mat-r ter, fuch as butter, fat, or oil, the water, by its violent expanfion in evaporation, will force out the oily particles with a kind of explofion ( 359 ) Cxplofioii and fhaking of the containing ■veflels. But other fadls, more confentaneous to the nature of volcanos, prove the contrary. It is well known to all mineralogies, that, if water be dropped upon melted copper or filver, the abundant vapours which arife will produce a kind of noife, but no explo- fion. The elegant experiments of Deflandes, relative to the effeds of water poured upon melted glafs contained in capacious cru- cibles, in a glafs-furnace, are equally de- ferving attention in themfelves, and appli- cable to the prefent queftion. I fliall give a brief abftrad: of them. A glafs of water having been thrown on a quantity of melted glafs, the water fuddenly formed a globule without producing the leaft found : it af- fumed, or feemed to aflame, a red colour, fimilar to that of the crucible and the melted glafs. It rolled on the furface of the glafs ; and, nearly in the fame manner as lead A a 4 is ( 36o ) is confumed in the cupel, its volume gra« dually diminlnifhed, until in three minutes it was entirely evaporated, without emit- ting any apparent fume. In another expe- riment the vitreous matter was poured up- on a table, and made to flow, before the water was entirely evaporated : no detona- tion, however, followed. The convenience of accefs to a glafs- fur- nace incited me to repeat thefe eafy experi- ments, v.'hich have not, to my knowledge, been verified by any other perfon. Before 1 proceeded to make them, I fpoke to one of the workmen on the fubjedt, whom I found fo well acquainted with the fad: that he offered to pour as much water on melted glafs' as I pleafed, aifuring me that not the fmallefc ill effeft was to be apprehended. I perceived, therefore, that this was one of thofe phenomena which are publifhed to the world as new, and which, in fad:, are fo to the learned, but have been long well known to many of the vulgar, I becfaa ( 36i ) I began my experiments with pouring fix ounces of well-water into a cylindrical clay vefPel, about two feet in diameter, which had for fifteen days been nearly full of melted fadiitious cryftal-glafs. The water immediately difperfed itfelf into a number of globules, in the fame manner as mercury divides when thrown upon a plain furface. Thefe globules rolled about, gradually di- minilhing in fize, and, in lefs than two mi- nutes, difappeared. All this time not the leaft detonating found was to be heard ; but, attentively obferving the larger globules by the bright light of the furnace, I could perceive them in a ftate of fcarcely difcerni- ble ebullition. I repeated this experiment by emptying into the vefTel a pot contain- ing eight-and-forty ounces of the fame water, which now dividing into larger glo- bules, enabled me to obferve the appear- ances which took place in them with greater precifion. At firft the globules, moving as ufual on the furface of the melted glafs, ihowed no fign of ebullition ; but this, a few inftants afterv/ards, became vifible, in thofe, ( 3^^ ) tliofe^ atleaftj thatwerenearefttome; whence it may be concluded that the fame happened in thofe at a' greater diilance. They boiled and fwelled perceptibly, but did not caufe th^leaft found ; the water being in a fpace, if not deprived of air, at leaft containing: cxnly fuch as miiil be highly rarefied. They, however, as in the former experi- ment, continually diminilhed in fize, andj after 'about four minutes, - entirely 'dlfap- peared. During their ebullition, no fign of any vapour was difcoverable around them. It would be fuperfiuous prolixity to dc- fcribe feveral other experiments which I made with ftill greater quantities of water, no difference being difcernible in the re- iults. T very attentively obferved whether the water aifumed a red colour, but faw no- thing like it : this miftake muft have been occafioned by the rednefs of the hot glafs furrounding the water. On comparing thefe fads with thofe ob- ferved ( 363 ) ferved by Deflandes, I find them perfe£lly accord, except that the ebullition, which certainly takes place, was not obfcrved by him. When we proceed to apply them to volcanos, with refped: to the falling of water on their bufning mouths, we ihall be ready to conclude that water fo falling cannot caufe eruptions. To enable myfelf, however, if not to decide this queftion, at leaft fomewhat more to elucidate it, I made fome other experiments, both on different metals and lavas in fufion. ' I made ufe of iron, copper, tin, and lead. With refped: to the iirft, I employed filings of it, to faci- litate its fufion ; as I have already remarked in the Introdu^Ilion to this work, that, by this means, a decifive principle of fufion may be obtained in this metal in the fur- nace. The crucibles for thefe experiments were wide at the top, narrow at the bottom, and of confiderable capacity ; and I never entirely tilled them with metal, that there might be room to pour on it a fufficient quantity of water. After ( 364 ) - After the iron had remained twenty- four hours in the furnace, and was femi- fufed, I let fall a few drops of water on it. They at liril: remained motionlefs, . without apparently diminifhing in bulk ; but they foon after began to leap about and boil, wafting away, till, in lefs than a minute, they difappeared. When I poured on more v/ater the effeds were the fame, only the ebullition was more fenfible, becaufe it was proportioned to the greater quantity of water. Leaving the iron in the furnace, I, afrer feven hours more, repeated the experiment, having firH; removed the crucible into the cold air. I threw on the iron a flight fprinkling of water ; but this in an inftant difappeared wiihout the leaft found. I then poured the quantity of an ounce on it. For a moment the water remained quiet ; it then divided into globules, and began to boil with fome flight noife. In a (hoit time it entirely evaporated. The { 3(>S ) The rednefs of the iron was now lome- what obfcured ; and 1 availed myfelf of the circumftance to drop more water on it ; but here the refult changed its appearance. At the moment the water touched the me- tal it began to boil, and an undulating vapour arofe, with noife, which continued till the entire difperfion of the liquor. The heat of the iron continued fufficient for me to repeat this experiment twice more with the fame effed:. Copper in the furnace was complete!).' fufed. I miade the fame experiments on it, and with the fame circumftances as on the iron. I omit defcribing the I'efults, as that would only be to repeat exadtly what I have faid relative to the former metal. To make the fame experiments on tin and lead, the furnace was not neceflary, a much lefs heat being fufEcient for the fu- fion of thele metals. But I foon perceived that the confidence with which I had made my trials on Ae iron and copper, mull not ( 3«6 ) not be continued with the lead, and flill lefs with the tin, on account of the violent explofions excited by their touching the water. I made a great number of different experiments on both thefe metals ; but, for the fake of brevity, I fhall only mention the principal. When water was let fall, drop by drop, on melted tin in the crucible, it ex- ploded with a loud noife, and pieces of the metal were thrown to the diftance of two, three and four feet. If fo much water was poured as to form a thin covering over a part of the furface of the tin, the detona- tion increafed in proportion, and a great part of the metal was thrown out, with a loud explofion, to a confiderable diftance from the crucible. Not the leaft appearance of any vaporous fume was obfervable. Approaching as near as this dangerous experiment would permit me, and attentive- ly watching the progrefs of it, I obferved, that as often as the drop of water touched the ( 357 ) the metal, the latter, by its fluidity, became in motion. I likewife remarked that, at the fame time, a momeatary cavity was pro- duced in its furface, from the fall of the drop, efpecially if it fell from any heights It then occurred to me, that it might be poflible that the explofion and detonation might be the effect of the water finking into the cavity, and being in part confined in the melted metal ; where, paiTmg fuddenly into the (late of vapour, and finding no room for its dilatation, it impetuoufly farced out the metal. But this fuppofition did not accord with the fact. Had this been the cafe, if the drop had touched the melted tin without fmking the fmall cavity, it would have caufed no explofion ; which muft hav-e been the louder and more violent, the deeper the cavity, which would then have contained more water. I, therefore, firfl let fall the drops of water on the tin from a very fmall height, and afterwards from one of five or fix feci ; but I found DO fenfibJe difference, either In the explo- fion ( 36S ) fion or eje(fllons. The effecl defcrlbed, it may, confequently, be concluded, was pro- duced merely by the fimple contact of the water and the tin. I had, befides, fufficient proof that the water, when included within this melted metal, caufes ejedions much ftronger and with a louder report. Having taken a crucible containing melted tin from the fire, the furface foon began to cool. I then with the point of a nail made a perforation through the cruft that had gathered over it, which was flill thin and foft, and poured on it half an ounce of water, a part of which entered the perforation, when im« mediately the cruft was forced up with an unufual explofion, almoft all the melted metal violently thrown out, and the earthen crucible broken to pieces. The cooling and confequent contraction of th€ cruft had produced a vacuity between it and the melted metal, which admitted the water, but was much too confined for its expan- fion ( 3^9 ) fion when reduced to vapour, which, by its elnftlcity, caufed the violent effedts that followed. When the furface of the tin was cooled and cdnfolidated fo that the^ water could not penetrate to the part which ftill re- mained fluid^ the latter only boiled, and re- folved into a fmall vaporous cloud which rofe in the air. In thefe explofions, however, irregulari- ties happen for which it is not eafy to affign a reafon. For example : after five or fix explofions had been produced by letting fall drops of water on the tin in fufion, they would fuddenly ceafcj though I conti- nued the fall of the drops, which, when they reached the metal, only boiled and evaporated. Bui: what muft appear mofl: extraordinary was, that after three or four drops had produced no explofion, others which fell immediately after again caufed it. Nor muft we imagine that the failure was occafioned by the water falling not imme- VOL. III. B b diately ( 37° ) dlately on the tin, but on the pulverulent pellicle with which it is invefted by oxyda- tion, fince I carefully removed it as often as it was formed. Melted lead exhibited the fame appear- ances with the tin, and fimilar irregularities, except that its explofions w^th water were not fo frequent, nor, as it appeared to me, fo ftrong. I fliall not here enquire why the water in the furnace exhibits no evaporation of any kind, nor boils till after fome inftants 'y whereas, when the experiment is made in the open air, the ebullition and evaporation follow immediately that the water touches thefe two metals, now fomewhat cooler : nor why, Vvhen the water falls on lead and tin, it explodes with a loud noife, while no fuch explofion happens with copper and iron. Such refearches, to be properly made, require other experiments, which would lead me too far from my fubjecl. It ap- pears to me preferable to proceed imme- I diately { 5-1 ) dlately to relate what 1 obferved in lavas la fufion, contained in crucibles of the form and fize before defcribed, and tried by the fame experiments which I had made on glafs and metals. The firfl: I ufed were of that fpecies which in the furnace become but Uttle po- rous. The water, w^hen poured upon thefe in a ftate of fufion, for feme inftants re- mained motionlefs ; afterwards it began to boil, and the ebullition continued until it was entirely diffipated. I repeated the ex- periment on the fame lavas, after having taken them out of the furnace, and when they had in part loft their glowing red- nefs. The water, on touching them, arofe in noify bubbles, producing a profufion of vapours ; and, as the lavas became cooler, the quantity of vapours became more abun- dant, at leaft to a certain degree of cool- nefs. Thefe lavas, therefore, did not differ from glafs, copper, and iron, with refpe<5l to their caufing no explofion with water. B b 2 I next ( 3/2 ) I next proceeded to the lavas filled with pores and bubbles ; but here more caution was neceflary. In one of them, two large bubbles appeared perforated on one fide. On pouring the water into the crucible, it exploded with a noife equal to the report of a fmall piftol, and forced out the lava in fcattered fragments. I was then convinced that this explofion had not been produced by the water that had merely touched the. furface of the lava, but by that which had penetrated into the two open bubbles. I had recourfe, therefore, to a proof which could not but be decifive, which was, to re- peat the experiment on the fame kind of lava, but on fuch as contained no fracture of any bubble, which may frequently be obtained among fufed lavas of this fpecies. When this lava was liquefied I let fall into the crucible the fame quantity of water, which produced only a fimple ebullition ; and the fame happened on repeated trials, which convinced me I was not miftaken in my opinion. < I con- ( 373 ) I concluded thefe experiments with the following : Having fufed a lava in a capa- cious receiver of clay, I perforated it ob- liquely fronni the top to the bottom by im- merging in it a pointed iron wire three lines and a half in diameter. We fhall fee in Chap. XXIII. that the lavas which are moft eafily fufible, and which are inflated and overflow the crucible, forming a flream down the fides, retain, neverthelefs, fo great a tenacity in their parts, that th^y are with difficulty pierced, and that the cavity made by fuch perforation remains entire but a very fliort time. I refolved to in- troduce water into this cavity ; but as the experiment was dangerous, I removed the receiver from the furnace into a court-yard, and poured in the water by means of a long tube of iron, which reached the vefTel through a hole in the door that fliut in the court-yard. As foon as the w^ater entered the cavity, the pieces of the receiver and of the lava were forced violently to the diftance of many feet, with a detonation equal to the report of a mufket. B b 3 \yhile ( 374 ) . While making thefe experiments, I wifh- ed to fatisfy my curiofity relative to another particular. Hitherto I had ufed frefh wa- ter from a well : and 1 wiflied to afcertain whether there was any difference in the efFecls produced by water from the fea ; fmce it appears highly probable that this water, by entering among the iires of vol- canos, is the caufe of their moft terrible eructations. I, therefore, caufed fome to be brought, in clofed vefTels, from the neighbouring gulpli of Genoa ; but, when I made ufe of it in fimilar experiments on the fufed lavas, I found the refults per- fectly the fame with thofe already defcribed. From this feries of experiments I think we are authorifed to conclude, that when a quantity of water falls on the burning crater of a volcano, it has not the power of producing explofions ; but that ^he latter on the contrary are very violent when the water, penetrating below, reaches the con- flagration ; when fuddenly reduced to va- pour by the heat, it finds no room for its dilatation ; ( 375 ) dilatation ; or when it infmuates kfelf late- rally among the liquefied matters ; of which we have a fatlsfadory proof in the explo. fion of the lava, violently forced from the containing vefl'el, on the introduction of water inro a cavity made in it. Though, from the faCls now adduced, there is the utmoft reafon to believe, that water changed to vapour, by the incredible power it acquires, is extremely well adapted to produce the great volcanic eruptions ; and, by the ludden fmkings of the fea, which frequently happen on fuch occafions, it is nearly certain that they are to be afcribed to this moft powerful agent ; it is not neceflary to recur to it for the caufe of the more moderate and fmaller ejed:Ions ; as, to produce thefe, the different perma* nent gafes mentioned above are fufficient ; and it is, in fad:, beyond doubt, that they are the caufes of fuch eruptions in fome volcanos, as, for inftance, that of Stromboli* In Chap. X. v/e have feen that the fymp- toms of that volcano confift In an ebullition B b A of { 376 ) of the liquid lava within the crater, by which it rofe to a certain height, inflating with multiplied tumors, which burft at the moment the detonation and ejedion took place ; that this was immediately followed by a finking of the lava to a certain depth, to which fucceeded a new riimg of the fame, with like inflations and tumors that burft v^'ii.h iimilar ejed:ions and explofion ; and that in this alternation coiififted the aiftion of that volcano* I have already fuppofed that thefe tumors are cauf-d by an elaftic fluid imprifoned within them, which endeavours to obtain a pafTage, and at length finds one, by burfting the tumors and forcing up their fragments to a confiderable height ; and this con- jecture I then thought extremely well- founded, and am ftill of the fame opinion. It Oily remaiiied to enquire what might be the nature of this fluid ; which enquiry I referved to be made in the prefent chapter, in which I treat of the nature of the gafes of volcanos. From the obfervations I made on ( 377 ) pn die fpot, I was fufficiendy convinced that the fluid contained in the tumors could not be derived from the evaporation ©f the lava, fince this evaporation (which, from the fad:s adduced, cannot be denied) was, indeed, fufEcient to burft them, but not to produce the ejedions continually " pbfervable. Nor can v^'e attribute them to evaporated v^^ater, as this would not have deferred its detonation when included in thofe bubbles till it had reached the fuiface of the lava ; but the explolion and ejed:ioii would have taken place at the moment the water had come in contad: with the burning lava, and, confequently, at a much greater depth, Befides, had that multitude of ca- pacious tumors been filled with water which had padded into the ftate of vapour, it muft be maniieft that every eruption would be much m.ore violent and loud. "We muft therefore conclude that the fluid in quef- tion is a permanent gas, and probably one of thofe which are difcover?ble in volcanos when, in a ftate of tranquillity, they are ac- ceflTible, ( 378 ) cclTible, fuch as the carbonic acid gas, hy- drogenous gas, oxygenous gas, &c. In fad:, M. Dolomieu^ though he did not approach fo near to the crater of Stromboli as I did, yet, from the obferva- tions he made, conjectured that its ad:ion was caufed by hydrogenous gas. He fup- pofed that the internal fire might difengage this gas from the matters exifting near, but not immediately touching, the volcanic fur- nace ; and that this gas, by fubterranean paflages, might reach the principal cavity in which the conflagration rages, and there fuddenly take fire. This hypothefis, which that judicious naturaUft has propofed only in the fhape of a doubt or conjediure, is extremely plau- fible, nor do I hefitate to believe that it Is frequently the true explanation of what takes place in burning volcanos ; though, with refpedt to Stromboli, it cannot be maintained when we compare it with the fafts ( 379 ) facls obferved. For, in the firfl place, though this gas has the property of rifing in flame, it has alfo that of extinguifhing fire placed within its atmofphere. How- then can the lava melted in the cavern of Stromboli be penetrated, put in motion, and rarefied by this gas, without the dimi- nution, not to fay the entire lofs, of that ardent rednefs which I obferved in it during the night ? Secondly, though, in this vol- cano, the detonation is always infeparable from the explofion, we cannot fuppofe the former occafioned by hydrogenous gas, un- lefs we would admit an efFed: incomparably lefs than the caufe. In the repeated vifits I made to that volcano, I obferved that the ftrongeft detonations were not louder than the found of a very fhort hollow thunder ; and that, at the moment they are heard, the tumors which cover the lake of fiery lava, many of which are feveral feet in dia- meter, burft. Is it not then evident that the fuperabundant quantity of this gas, contained in fo great a number of tumors, and fulminating almoft at one inftant, muft caufe ( 38o ) caufe a mucli ftronger detonation ? But the proof that admits of no reply, or rather the abfolute demonftration of the infuffi- ciency of this hypothefis, is the following : When thefe tumors burft by the force of the imprifoned fluid at the time it difen- gages itfelf, were this fiuid hydrogenous gas, it would take fire at the fame moment, and cover with flame the furface of the lava ; but it is certain that not the lead ap- pearance of the feebleil flame is difcoverable in the lava in any eruption ; as I can af- firm from the various obfervations I have made, at a very fhort diftance, of the moft minute accidents that take place within the crater. Compelled, ^ therefore, to abandon this explanation, it occurred to me whether at- mofpheric air might not pofllbly produce the phenomena in queftion. I confidered, however, that, before this hypothecs was admitted, it would be necefTary to fhow that the atmofpheric air had free accefs from without the mountain to the volcano ; that ( 3Si ) that It infinuated itfelf into the body of the lava ; and ifTued out upv>rards, caufmg the Inflations, ejedions, and detonations. As to the poflibility of its entrance to the moft internal recefTeSj containing the melted lava ; it feemed to admit of eafy proof from the cavernous ftrudlure of volcanic mountains. But how this air could be fufficiently pow- erful to infmuate itfelf into the great mafs of lava, traverfe it to the top, and there oc- cafion the explofions, I could not conceive, from the two following, in my opinion, in- fuperable obftacles. Firft, it is undeniable that the atmofpheric air which might pene- trate through the cavities of the mountain, till it approached the immenfe mafs of melted and burning lava, would be ex- tremely dilated, and make its way where it found the eafieft paflage, which v/ould be by the caverns that had admitted it ; but it could never penetrate the lava, from its too great refiftance. Secondly, even granting for a moment that it might penetrate the lava, from the dilatation it mufl fuffer, it would penetrate it extremely rarefied, and be ( 382 ) be incapable of producing the explofions continually obferved at Stromboli. I omit feveral other objedlions, as 1 think thefe two are fufficient to demonftrate that this fecond hypothefis, likewife, cannot be main- tained. Shall I venture to propofe a third, which) in my opinion, is not contemptible, though I ofFer it merely as conjectural ? May not the phenomena of this volcano be attributed to the adtion of oxygenous gas ? On the one fide, it is well known that the fulphatc of iron and the fulphate of alumine afford this gas in abundance, when ad:ed on by a ilrong fire ; and, on the other, it is equally certain that thefe two falts are copioully produced in volcanos. They may, there- fore, in the profound recefies of Stromboli, furnifh a rich and inexhauftlble mine of oxygenous gas, which, mixing with the lava, and afcending through it by its levity, may colled:, in a confiderable quantity, in the narrow neck of the crater, and producing inflations and bubbles in the lava, force its ( 3S3 ) its way out with detonation, burfting and throwing up the fragments of the lava, from its expanfive force being greatly inr- creafed by heat. The ejedions v/ill b€ great, fmall, or moderate, according to the different quantities of this gas collected and difengaged. Againft this hypotheGs two objedlions may certainly be made ; the one, that, ad- mitting it, the ignited lava would be fo bright that the eye could not bear to look on it ; as w^e know that it is with difficulty we can bear to look on a fmall flame ani- mated by oxygenous gas ; whereas, on the contrary, the rednefs of this lava is not greater than that of melted glafs or metal. The other objediion is, that the burning lavas adted on by this gas w-ould be con- verted into a glafs, or homogeneous enamel ; whereas the lavas continually throve n out by Stromboli, befides that the bafe of the primitive reck is fufficiently recognizable in them, ftill preferve their llioerls and feltfpars in their original ftate of cryftallization. Both ( 384 ) Both thefe objedions, however, will, i^ my opinion, be found to have little weight,- "when we confider that this gas in burning volcanos can never be pure, but muft ne- ceflarily be mixed with fome mephitic gas,* and, efpecially, v^ith carbonic acid gasy which.; in volcanic countries, is rarely want- ing. By this mixture the vivid brightnefs which pure oxygenous gas would produce in the ignited lava, will be greatly weakened^ and the aftion of the fire be prevented from being fo violent as to deftroy the charadters of the primitive rock. This hypothefis, however, as I have faidj I offer only for examination, and fhall be very ready to rejedt it fliould it be found defediive. The impofTibility of collecting the fluid that efcapes with detonation from this volcano, prevented me from afcer- taining its nature accurately. I am, there- fore, obliged to feek it by conjed:ure, hav- ing recourfe to that elaftic fluid, the ex- iftence of which in the volcano of Strom- boli 1 believe certain, and which, in fome meafure. ( 385 ) meafure, at leaft, may explain the pheno- mena. At the fame time it is to be obferved, that we know not but that in thofe immenfe laboratories of Nature which we call volca- nos, certain gafeous fubftances, hitherto un- known to us, may be produced or developed by the means of fire, and adt a confiderable part in their eruptions and explofions. Of the exiftence and nature of thefe fubftances, perhaps, we may not always remain igno- rant. VOL. III. Co CHAP. ( 386 ) CHAP. XXII. DISCOVERY THAT VARIOUS VOLCANIC PRODUCTS CONTAIN MURIATIC ACID ENQUIRY HOW THIS ACID HAS BEEN" PRODUCED, AND MIXED WITH THEM. Ah acid Uqiior extrafled from the fpotied glafs of L'lpari^ during ignition— Proofs that this acid is muriatic — T^he fame re- fult followed on a repetition of the experi- ment— Afimilar acid, liquor produced from the black gl'fs of Lipari — Fadlitious glaffes do not furnif it — Proof both by the dry and humid nsjay^ that the muriatic acid is not combined -with thefe two glajfes^ but only mechanically united to their parts — Seveji other 'volca7iic produHs fubjecled to the fame experiments^ from fojne of ivhich the fame acid liquor was obtained, and from others not — Difcovery that this acid does fiot exif in volcanic produds when in .' a fate ( 387 ) a Jlate of ftifton or ignition y btit is intro- duced aftcrivards — This muriatic acid not derived from the muriate of ammojiiac — // is probable that it proceeds either from fubterranean places^ or from the decompo- ft ion of the muriate of foda. A^EAR the beginning of the former chap- ter, it has been obferved that, when we enquired whether volcanic produdis, placed in matrafles and expofed to the fire, afforded any gas, and of what nature, a method there deicribed was adopted to afcertain whether any liquor wa& produced from the fame. It was alfo mentioned that fuch was ob- tained, which was found to be of a very fingular charad:er, and cf w^hich a defcrip- tion was referved for another place, as we were then occupied in the details of the gafifications of the faid products, and other particulars of the fame nature. It is now proper to proceed to a more full defcription of this liquor, and the circumftances that accompatiied it. C c 2 I fhall ( 388 ) I fhall begin by defcribing the manner in which it was obtained from two fpecies of the glafles of Lipari, the fpotted and the black. With refpecTt to the former of thefe, when the fife began to heat confiderably the matrafs, there appeared in the i\eceiver a white cloud, which increafed till it filled the whole cavity ; and then gradually difperfed, adhering to the internal fides of the glafs in the form of drops ; and, after two hours and three quarters, entirely difappeared, leaving at the bottom of the receiver a fmall i]uantity of limpid liquor. This liquor, on examination, manifefted the following charadlers : Its weight was 144 grains ; and its tafte was that of di- luted muriatic acid. The ferruginous prufliate of pot-a(h, not faturated, and the tindture of galls made with fpirit of wine, do not fhow any iign of iron. The ( 2^ ) The ammoniacal carbonate, In like man- ner, exhibits no appearance of earth. The tIn ) rcdj and the acid of which was inanlfeftly muriatic, from the fleecy turbidnefs produced by mixing it with the nitrate of filver. On comparing all thefe facls, it appears that, of nine volcanic produd:s expofed to the a(Stlon of the fire and fufed, fix nnani-^ fefted the prefence of the muriatic acid, and in three not the leaft fign of it appeared. From a comparifon of the local circum- ftances of thefe nine produd:s, we mufl: be convinced that the muriatic acid does not exift in thefe produ<51:s when they are either fufed, or heated to rednefs ; but that it unites with them afterwards, fince the three lavas, one from Vefuvius, another from Stromboli, and a third from Etna, which had been recently ejected from the fubter- ranean furnaces, contained none, though they afforded a fmall portion of water ; while the fix others which had ceafed to burn for a longer or (horter time, gave a greater or lefs quantity of this acid. It is alfo a confirmation of this fa<5l, and merits attention, that the fame lava of Stromboli 5 war. ( 401 ) ^vfls deftitute of it when firft ejeded ; but, after fome time was elapfed, began to ac- quire it. The idea occurred to me whether this acid' might not be derived from the ammo- niacal muriate, as this fait is almoft always found in volcanos. I, therefore, poured a fmall quantity of the acid liquors obtained from the two glafles upon lime w^ithout making ufe of the carbonate of pot-afh ; but I did not perceive any thing of the ilrong odour of ammoniac ; an evident proof that it was not the ammoniacal mu- riate. I rather incline to fuppofe that this acid originates either from the fubterranean places in which we know that it is fome- tlmes found, or rather perhaps from the fea, penetrating beneath the volcanic mountains; that it is generated from the decompoH- tion of the muriate of foda, by the means of lulphureous acids in w^hich volcanos abound; and that, abforbed by the humidity of the VOL. III. D d air. ( 402 ) air, it is introduced with it into the volcanic produds. I cannot, however, deny but that it muft appear furprifing that this fait in conjundion with water fhould have been able to find an entrance into the two glafles of Lipari ; and efpecially the black fpecies, as it is extremely compadt, and has not the leaft appearance of any cleft or crack. But we know that water can fub- tilize itfelf in fuch a manner as to penetrate other bodies equally folid and cpmpadi, ia which our eyes, though aflifted by a lens of a ftrong magnifying power, cannot difcover the fmalleft fiflure or minuteft pore. END OF THE THIRD TOLUME. V "d^^ci - ^'^