X-RAY STRUCTURAL STUDIES OF SOME GROUP VIII COMPOUNDS WITH CATALYTIC IMPLICATIONS By DOUGLAS ALLEN SULLIVAN A DISSERTATION PRESENTED TO THE GRADUATE COUNCIL OF THE UNIVERSITY OF FLORIDA IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF DOCTOR OF PHILOSOPHY UNIVERSITY OF FLORIDA 1975 To Jeanie ACKNOWLEDGEMErJTS I sincerely thank Dr. Gus J. Palenik for his enthusi- astic guidance throughout this work. I am deeply apprecia- tive of the advice and instruction concerning crystallo- graphic techniques given by Dr. M. Mathew and of the diligent synthetic work of Ruth C. Palenik. I wish to thank Dr. Marvin Rausch for providing excellent samples of metallo- cycle compounds. I am indebted to the chemistry faculties of Marshall University and the University of Florida for their apt instruction. I would like to especially thank the other members of the Center for Molecular Structure for their thoughtful suggestions and discussions. The typing expertise of Ann Kennedy is evident in this, perhaps her last, crystallographic dissertation. Lyle Plymale and Don Herbert are acknowledged for their inspirational teaching during my formative years. I would like to express my appreciation to my parents, Mr. and Mrs. I. O. Sullivan, for their support and encouragement throughout my formal educa- tion. Finally, I thank my wife, Jeanie, and my son, David, for their love and devoted understanding. Ill Table of Contents ACKNOWLEDGEMENTS LIST OF TABLES LIST OF FIGURES KEY TO ABBREVIATIONS ABSTRACT CHAPTER 1: CHAPTER 2: CHAPTER 3: CHAPTER 4: CHAPTER 5 CHAPTER 6 CHAPTER 7: INTRODUCTION SYNTHESES AND CHARACTERIZATION X-RAY DIFFRACTION EXPERIMENTAL AN INVESTIGATION OF LIGAND- INDUCED PROTON SHIFT: THE CRYSTAL AND MOLECULAR STRUCTURES OF TRANS- CHLORO (DIMETHYLGLYOXIMATO) (DIMETHYL- GLYOXIME) (4-CHLOROANILINE) COBALT (III) DIHYDRATE, TRANS-CHLOROBIS (DIPHENYL- GLY0XIJ4AT0) ( 4-CHLOROANILINE) COBALT ( III) ETHANOLATE, AND TRANS-B IS (DIMETHYL- GLYOXIMATO) BIS (4-CHLOROANILINE) COBALT (III) CHLORIDE A NOVEL BINUCLEATING LIGAND: THE CRYSTAL AND MOLECULAR STRUCTURES OF 1,4-DIHYDPJ^ZINOPHTHALAZINEBIS (2-PYRI- DINIUMCARBOXALDIMINE) NITRATE DIHYDRATE AND y-CHLOROTETRAAQUA [1 , 4-DIHYDRAZINO- PHTHALAZINE3IS ( 2-PYRIDINECARBOXALDIMINE) ] DINICKEL(II) CHLORIDE DIHYDRATE MODELS OF PROPOSED INTERMEDIATES FOR THE CATALYZED CYCLIZATION OF ACETYLENES: THE CRYSTAL AND MOLECULAR STRUCTURES OF 1- (tt-CYCLOPENTADIENYL) -1-TRIPHENYLPHOS- PHINE-2, 3,4,5-TETRAKIS (PENTAFLUOROPHENYL) COBALTOLE and 1- (tt-CYCLOPENTADIENYL) -1- TRIPHENYLPHOSPHINE-2 ,3,4, 5-TETPAKIS (PENTAFLUOROPHENYL) RHODOLE CONCLUDING REM^FJCS 111 vi ix X xi 1 4 17 30 83 114 141 IV APPENDIX A: BOOTHITl 144 APPENDIX B: OBSERVED AND CALCULATED STRUCTURE FACTORS 154 REFERENCES 230 BIOGRAPHICAL SKETCH 237 LIST OF TABLES Table 1. Table 2. Table 3. Table 4. Table 5. Table 6. Table 7. Table 8. Table 9. Table 10. Table 11. Table 12. Table 13. Table 14. Table 15. Table 16. Elemental Analysis Infrared Spectra Ultraviolet Spectra Crystallographic Data Schemes of Refinement Final Atomic Parameters of Nonhydrogen Atoms for C£Co{H2dmg) (dmg) (clan) Final Parameters for the Hydrogen Atoms for C£Co(n2dmg) (dmg) (clan) Final Atomic Parameters for the Nonhydrogen Attorns of C'tCo(H2dpg2) (clan) Final Parameters for Hydrogen Atoms for C£Co(H2dpg2) (clan) Final Atomic Parameters for Nonhydrogen Atoms of [Co(Hdmg) 2 (clan) 2]C-e Final Pararaeters for Hydrogen Atoms for [Co(Hdmg) 2 (clan) 2]C£ Selected Interatomic Distances in Some Cobaloxime Complexes Selected Interatomic Angles in Some Cobaloxime Complexes Deviations and Selected Lcast- in C£Co(H2dmg) ( Deviations and Selected Least- in C£Co(H2dpg2) Deviations and Selected Least- in [Co (Hdmg) ~ (c Equations of Squares Planes dmg) (clan) Equations of Squares Planes (clan) Equations of Squares Planes Ian) 2]C£ 8 10 15 18 28 33 35 37 41 43 45 52 54 59 61 63 vx Table 17. Table 18. Hydrogen Bonds in Cobaloximes Dihedral Angles Formed by Selected Planes in Some Cobaloxime Complexes Table 19. A Summary of the Average Bond Distances in XYCo(H2dmg2) Complexes Bond Distances and Bond Angles of Coordinated 4-Chloroaniline Molecules Bond Distances, Bond Angles, and Least-Squares Planes of Phenyl Rings in C£Co (H2dpg2) (clan) Final Atomic Parameters of Nonhydrogen Atoms for H2dhphpy(N03)2'^H20 Final Parameters for the Hydrogen Atoms in H2dhphpy(N03)2-2H20 Final Atomic Parameters of Nonhydrogen Atoms for [Ni2C£ {H2O) 4 (dhphpy) I Cl^ • 2H2O Final Parameters for the Hydrogen Atoms in [HiyCl (H2O) 4 (dhphpy) ] Cl^ ' 2H2O Selected Interatomic Distances for H2dhphpy(N03) 2-2H20 and [Ni2C£ {H2O) 4 (dhphpy) ] Cl^ ' 2H2O Selected Angles in H2dhphpy(N02)2'2H20 Table 20. Table 21. Table 22. Table 23. Table 24. Table 25. Table 26. Table 27. Table 28. Table 29. Table 30. 2H2O Selected Angles in [Ni2C£ (H2O) 4 (dhphpy) ] Cl^ Hydrogen Bonds in Hodhphpy(N03) 2-2H20 and [Ni2C£ (H2O) ^ (dhphpy) ] Cl^ • 2H2O Deviations and Equations of Selected Least-Squares Planes in H2dhphpy (N03)2-2H20 and [Ui^Cl (HO) 4 (dhphpy) ] Cl^ • 2H2O 64 73 77 80 81 85 86 88 92 98 100 101 103 109 Vll Table 31 Table 32. Table 33 Table 34 Table 35. Table 36 Table 37 Table 38 Table B-1. Table B-3 Table B-4 Table B-5, Final Atomic Parameters for the Nonhydrogen Atoms in C4 (fph) 4C0 (cp) (tpp) and C4(fph)4Rh(cp) (tpp) Selected Bond Distances of C^(fph)^M(cp) (tpp) Selected Bond Angles of C^(fph)^M(cp) (tpp) Deviation from and Equations of Some Least-Squares Planes of C4 (fph) 4Co(cp) (tpp) and C4(fph)^Rh(cp) (tpp) Average C-F and C-C Distances for the Pentaf luorophenyl Groups in C^ (f ph) ^M (cp) (tpp) Bond Distances and Bond Angles of Pentaf luorophei^iyl Groups in C^(fph)^Co(cp) (tpp) Bond Distances and Bond Angles of Pentaf luorop};.enyl Groups in C^ {fph)^Rh(cp) (tpp) Bond Distances and Bond Angles of Triphenylphosphine in C^(fph)^M(cp) (tpp) Observed and Calculated Structure Factors for C£Co (H^dpg^) (clan) 119 Table B-2. Observed and Calculated Structure Factors for [Co(Hdrag) (clan) ]C£ Observed and Calculated Structure Factors for H-dhphpy (NO^) „ • 2H 0 Observed and Calculated Structure Factors for [Ni„C£ (H^O) . (dhphpy) ] - C£2*2H20 ^ Observed and Calculated Structure Factors for C , (f ph) .Rh (cp) (tpp) 128 129 130 133 134 136 138 156 173 181 190 205 vixi LIST OF FIGURES Figure 1. An ORTEP drawing of 47 C£Co(H2dmg) (dmg) (clan) •2H2O Figure 2. An ORTEP drawing of 49 C£Co(H2dpg2) (clan) •C2H3OH r: 51 Figure 3. " An ORTEP drawing of [Co (Hdmg) 2 (clan) 2KC Figure 4. A projected view along Co-N(l) 70 for CCCo(H2dmg) (dmg) (clan) Figure 5. A projected view along Co-N(l) 72 for (a) [Co(ndrag)2(clan) 2]C£ and (b) CCCo (H2dpg2) (clan) Figure 6. An ORTEP drawing of H2dhphpy (N03)2'H20 Figure 7. An ORTEP drawing of [Ni2C^ (}l20) 4 (dhphpy) ]C£3- 2H2O A packing diagram of 1^^ H2dhphpy (NO3) 2-2K20 Figure 8, Figure 9. A packing diagram of [Ni2C£ (II2O) 4 (dhphpy) ] 0^3 • 2H2O Figure 10. An ORTEP drawing of C4(fph)4Co(cp) (tpp) 95 97 108 126 IX KEY TO ABBREVIATIONS LIPS ligand-induced proton shift H-dmg dimethylglyoxime dmg dimethylglyoxime dianion Hdmg ' dimethylglyoxime monoanion Hpdmg- bis (dimethylglyoximate) with relative proton positions unspecified sulfa sulfanilamide dhph 1, 4-dihydrazinophthalazine dhphpy 1, 4-dihydrazinophthalazinebis (2- pyridinecarboxaldimine) pyca 2-pyridinecarboxaldehyde clan 4-chloroaniline Hjdph diphenylglyoxime Hjmpg methylphenylglyoxime fph pentaf luorophenyl cp cyclopentadienyl anion tpp triphenylphosphine an aniline 4-FPYTSC 4-formylpyridinethiosemicarbazone Abstract of Dissertation Presented to the Graduate Council of the University of Florida in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy X-RAY STRUCTURAL STUDIES OF SOME GROUP VIII COMPOUNDS WITH CATALYTIC IMPLICATIONS By Douglas Allen Sullivan December, 19 75 Chairman: Gus J. Palenik Major Department: Chemistry X-ray structural investigations of compounds containing Group VIII metal atoms are presented. The compounds studied illustrate interatomic interactions which may be of impor- tance in catalytic processes. The structures of metal-con- taining compounds were solved by locating the heav;^' atoms in Patterson functions and locating the remaining atoms in Fourier syntheses. The direct method of symbolic addition was used in the one, all light-atom case presented. Trial structures were refined by the method of least-squares. The crystal structure of trans-chloro (dimethylglyoxima- to) (dimethylglyoxime) (4-chloroaniline) cobalt (III) illustrates an unusual ligand-induced proton shift. Both neutral and dianionic dimethylglyoxime groups are found in the complex and the 4-chloroaniline ligand is oriented over the dianion- ic dimethylglyoxime. The structure of trans-bis (dimethyl- xi glyoximato) bis (4-chloroaniline) cobalt (III) chloride shows that complex to contain two monoatomic dimethylglyoxime ligands and the 4-chloroaniline ligands to be skewed rela- tive to the diglyoxime ligands. The crystal structure of trans-chlorobis (diphenylglyoximato) {4-chloroaniline) cobalt- (III) is described. Trends in the structures of these com- pounds and in the previously reported structures of similar compounds are discussed. Ultraviolet and infrared spectra of these compounds are given. The synthesis of a novel chelating ligand capable of binding two metal ions is described. The characterizations, including crystal structures, of its protonated forin, 1,4- dihydrazinophthalazinebis (2-pyridiniuracarboxaldimine) nitrate dihydrate, and of a nickel complex, y-chlorotetraaqua []. ,4- dihydrazinophthalazinebis (2-pyridinecarboxaldimine) ]dinickel- (II) chloride dihydrate, are presented. The planar ligand is shown to bind tv/o nickel ions with a separation of 3. COS o (1) A. A chloride ion occupies a bridging site in the plane of the nickel atoms and the ligand. The magnetic moment per nickel atom of the chloride bridged complex was deteinnined to be 2.74 B.M. at 40°C. The plausibility of structurally similar complexes mimicking the nitrogen-fixing enzyme nitrogenase is also discussed. The X-ray crystal structures of 1- (ir-cyclopentadienyl) - l-triphenylphosphine-2 ,3,4, 5-tetrakis (pentaf luorophenyl) co- baltole and 1- (Tr-cyclopentadienyl) -1-triphenylphosphine- 2 ,3, 4 , 5-tetrakis (pentaf luorophenyl) rhodole are reported. xii These compounds are viewed as stabilized intermediates in the catalyzed cyclization of acetylenes. In each case the metal atom forms a metallocyclo by a-bonding to the ter- minal carbons of a butadiene-like fragment. The ir-bonding in the metallocycle appears to be dclocalized. XI 11 CHAPTER 1 INTRODUCTION Western civilization has demonstrated the efficiency- oriented phenomenon of expending large amounts of energy to find ways of requiring less human energy. This is evident in the evolution from animal trails to freeways and from muscle to sophisticated, high-energy machinery. On the molecular scale the more efficient path io provided by catalysts. As alchemists searched for the "philosopher's stone" many chemists have been seeking catalysts. The application of catalysis is now advancing through the development of an understanding of the mechanisms of catalytic processes. Life processes are dependent upon chemical reactions controlled by enzymes. "It is not generally appreciated how little is understood about the mechanisms by which enzymes bring about their extraordinary and specific rate accelera- tion." Investigation of enzymes should not only be fun- damental in the understanding and maintenance of life pro- cesses but also should contribute to developing more effi- cient industrial processes. Much of the investigation of enzymes has concerned the use of model compounds. "Model building and the application of material analogues are becoming increasingly important for the elucidation of fundamental problems of biochemical structure and reactivity."^ X-ray structural studies of enzyme models are important for the exploration of structure- activity relationships. Solid state studies of enzym- model compounds are of particular relevance I ocauso of the high degree of order the macromolecular enzymes themselves possess. While electrostatic and hydrogen-bonding forces are usually considered the major binding forces in enzyme-sub- strate interactions, the strong charge-solvating and hydro- gen-bonding ability of water tends to reduce the possibility of obtaining large binding energies from these forces. To explain the large binding energies found, "hydrophobic forces" are presumed to exiso in these intermolecular interacions in aqueous solution.^ The enthalpies of mixing of aromatic li- quids with aliphatic liquids indicate that aromatic mole- cules prefer an aromatic environment. ' "Stacking interac- tions" involving the 7i-systems of aromatic groups within the enzyme's protein structure may account for part of the "hydro- phobic forces" and contribute to the orientation of the enzyme- substrate interaction.^ The ligand-induced proton shift (LIPS) observed in ClCoiU^dx^g) (dmg) (sulfa) [the key to abbreviations is given on page xl is an indication of the importance of this TT-type interaction. A further examination of LIPS v. as under- taken and is presented in this work. The design of enzyme models is often based on sparse structural information about the prosthetic group of the en- zyme. Efforts to miiTLic the nitrocen-f ixing enzyme nitrogenase have been concerned with the metal to nitrogen bond. The 6 7 probable binuclear nature of the enzyme's active site ' has largely been ignored. The structures of a novel binuclea- ting ligand and its nickel (II) complex are presented here as a first step in the construction of a new generation of models for nitrogenase. When the mechanism of a chemical process is believed to be understood, stable compounds similar to the interme- diates of the reaction may be prepared and examined to support the proposed mechanism. One proposed mechanism for the catalyzed cyclization of acetylenes v/ould have a five- membered ring containing a metal atom and a cyclobutadiene 8— 1 3 fragment as one of the intermediates. The first struc- ture of such a stabiliF.ed intermediate containing a cobalt atom and the structure of the rhodiv;m analog are presented in this study. CHAPTER 2 SYNTHESIS AND CHARACTERIZATION Synthesis Crystals of all cobaloxime compounds were generously provided by R. C. Palenik* and were used v.'ithout recrys- tallization. M. D. Rausch and R. H. Gastinger synthesized the 14 15 metallocycles containgmg cobalt and rhodium. They supplied well-formed crystals of those metallocycles for X-ray structural studies. Unless otherwise indicated all solvents were reagent grade and were used without further purification. All pre- parations were carried out in air. All melting points were taken on a Mel-temp apparatus in open capillaries and are uncorrected. 16 The published method was used to prepare dhph for succeeding experiments. To 6.40g (49.0 mmoles) 1,2-dicyano- benzene (98%; Aldrich Chemical Corripany, Milwaukee, Wise.) in 12.5 ml 1,4-dioxane was added a mixture of 15.0 ml (ca. 250 mmoles) hydrazine hydrate (85%; Fisher Scientific Company, Fair Lawn, N. Y.) and 4 . 0 ml glacial acetic acid (reagent; Baker and Adamson, Morristown, N. J.). After being heated *These complexes were prepared using standard procedures with synthetic details to be published at a later date. for three hours the mixture was cooled and the red product was collected (yield, ca . 40%). The decomposition temper- ature of 193 °C was in agreement with the reported value. A solution of 0.0955g (0.50 mmoles) of the previously prepared dhph in 4 0 ml absolute ethanol was added to a solu- tion of 0.237g (1.0 mmoles) UiCl2' ^^2^ (reagent; Matheson, Coleman and Bell, Norwood, Ohio) and 0.095 ml (0.99 mmoles) pyca (99%; Aldrich) in 40 ml absolute ethanol. Upon slow, almost complete, evaporation in air of that solution olive green crystals of [Ni2C£. (H2O) ^ (dhphpy) ] 0^3 • 2H2O formed. Analogous procedures were carried out replacing NiC£2 * H2O with CoCl2'^^-2^' CuC£2 '2^120 (reagent; Fisher), ZnCl2 (reagent; Mallinckrodt Chemical Works, St. Louis, Mo.) and FeC£2'4^2^ (reagent; r4atheson, Coleman and Bell) without success in obtaining a crystalline product. Similar pro- cedures were followed with the addition of ca. 0.2 ml of 12 M hydrochloric acid (reagent, 38%; Baker and Adamson) to solutions of CuC£2'2H20 and FeCc2'4H20. Again, no suitable products were formed. Attempts to separate and recrystallize reaction products from water, water-ethanol , methanol and pyridine failed to give a crystalline product. V7hen CuC£2 was present, gas evolved from the reaction mixture. Additional attempts wore made to isolate complexes similar to {Ni C(l (H 0) (dhphpy) ] Ci^ using dhph obtained by recrystallization from hot water of H2dhphS0^ (ICN-K and K Laboratories, Ir>.c. , Plainviev/, N. Y.) to which an equivalent amount of KOH (certified A.C.S.; Fisher) had been added. Those attempts were unsuccessful. The red-orange plates of H2dhphpy (NO^) 2^ 2H2O used in crystallographic studies had been recrystallized from water. The crude product formed upon cooling a solution made by adding 0.190g (1.0 mmole) dhph in 20 ml warm water to a solution containing 0.583g (2.0 mmoles) Ni (NO-^) 2 ' ^H^O (re- agent; Mallinckrodt) and 0.8 9 ml (9.4 mmoles) pyca in 10 ml warm water followed by drop-wise addition of nitric acid (reagent, 71%; Baker and Adamson) to a pH less than 1. Also, H^dhphpy (NO^) 2 was prepared by first adding 1.90 ml (20.0 miaoles) pyca to a suspension of 2.878g (10.0 mmoles) H2dhphS0. in 100 ml water. A brick-red solid formed upon addition of l.llg (ca. 17 mmoles) KOH. After washing with water and drying in air, the brick-red solid was suspended in 100 ml of 95% ethanol and 1.30 ml (21 mmoles) of nitric acid were added. Small red-orange needles of H2dhphpy (NO^) 2 which decompose at 126°C were filtered, v;ashed with ethanol, and then ether and air dried (yield 4.0g, 75%). Freshly prepared hydrated metal hydroxides were reacted with H2dhphpy (NO^) 2 in methanol. Each of the metal hydroxides was filtered after adding 1 M KOH to aqueous solutions of Ni(N02)2-6H20, Cu (NO^) 2 ' 3H2O (reagent; J. T. Baker Chemical Company, Phillipsburg, N. J.), Fe (C^O^) 2 • 6H2O (reagent; G. Frederick Smith Chemical Company, Columbus, Ohio) and Zn(NO,)2-6H 0 (reagent; Matheson, Coleman and Bell). After the reaction mixtures were stirred until there was no further change in color, they were filtered and the filtrates were allowed to evaporate. Only the reaction with nickel (II) hydroxide produced a crystalline product. Attempts to re- crystallize that maroon product from methanol, ethanol, ethanol-water, and 2-propanol did not yield crystals suitable for crystallographic studies. Discussion of Characterization The microananlyses recorded in Table 1 were performed by Galbraith Laboratories, Inc., Knoxville, Tennessee, for the dhphpy compounds and by Atlantic Microlab, Inc., Atlanta, Georgia, for the cobaloxime complexes. The calculated per- centages of carbon, hydrogen, and nitrogen for the dhphpy compounds correlate well with the measured percentage. Two water molecules per molecule of dhphpy in each are indicated by the elemental analysis. This is confirmed in the struc- tural determination. Similarly, the eleraental analysis of C-tCoCH^dmg) (4-nitroaniline) is in agreement with the expected formula with tv;o water molecules present. Based on the measured density and crystallographic data the molecular weight of [Co (H2dmg2) (4-methylaniline) ] c£ should be 596. This is greater than its formula weight of 538.9 and the presence of molecules of solvation is expected. Three water molecules or one molecule of the ethanol solvent per formula could account for the difference. Neither of these possi- 2 Of U (0 o 13 c O U rH (0 o in cr> r- r^ o m 00 in 1— 1 n ^ (N • • • • • • VD in ^ ^ vo in M rH <-i r-i ra >-< O r- o «N cr> fM H (N • • • • VX> tr VD in pH r-H CM iH in r}< in iH 00 in \D vn fo ■■J C O 00 VD OI ""a* H 00 • • <* 00 0) rH cd C 13 O E O U Ti (D 4-1 O 0) rH 0) o 0) to >1 rH c -p c e rH u rH o C O rH n V.O 00 in r- o tn CN CNl VD • • • • • • m a u CM • OJ ^^ ,,— ^ 0) 0) c c •H ■H H rH •H •H C c « nj 0 ■H u >1 4J J^ •H +J c Q) 1 e «* 1 ^^ ^ .-^ ■ — CN ,-^ tP OJ £ &» •o e CM 73 s CN "*^ E 0 — • o o •^ u o o CM K CM n «N> u 1— » ^-^ O >1 CN| Qi S x: CM a • x: CM T3 ^-^ *■ — ■ CO ^ O ^~. 2 o »*-<' (N >i K a x: ■=v^ Oi O x: CM •a •H CM z X ' — ' bilities is confirmed by the CHN analysis (see Table 1) . IR spectra of samples as mineral oil mulls between polished plates of fused sodium chloride were recorded on a Beckraan Model IRIO grating spectrophotometer from 4000 to 500 cm" . The spectra were calibrated using the 1601.0 cm absorption of a polystyrene film. IR spectra of selected compounds are reported in Table 2. The IR spectra of the bis (diglyoxime) cobalt (III) complexes with aniline derivatives exhibit many features of similar cobalt complexes with nit- , 18 riles and isonitriles described by Batyr et al. The 18 spectra of the cobaloximes shov; the absorption assigned to the C=N stretch between 15 50 cm" and 158 0 cm . The ab- 18 -1 sorptions associated with the N-0 band at ca. 124 5 cm and ca. 1095 cm" are present also. A weak absorption in the 1700-1800 cm" range appears in some of the spectra but with lov/ resolution. Peaks in this region have been assigned to the 0---H-0 bridge between the dioximate ligands. The presence of a symmetrical bridge has been 20 suggested to rationalize this low frequency. Absorption spectra in the ultraviolet region were re- corded on a Gary Model 15 spectrophotometer. Spectra of solutions were measured from 26.7 kK (375 my) to 47.6 kK (210 my) using the double beam method with the pure solvent as the reference. Solutions of the cobaloxime complexes in methanol (spectroquality ; Matheson, Coleman and Bell) and solutions of the diiphpy compounds in 0.1 M hydrochloric 10 CM 0) EH (0 3 O t u Q) -P O 0) iH "^r e CT B cn cn ^ '•— ' *— ' ^-^ *»^ '«— ' '— ' ■*--' >— ' in r- 00 ro ro m CN n >^ o^ o r~ T ^ CO '3' o LO n a\ r^ vc in 'S' CM CM rH (N •-< iH •H rH iH rH rH f-i 11 C •H ■P c o o CM 0) rH (0 CM E -- c O (C U rH «s> U u — CM en a •d CM W ,-> c o (0 O rH ■^n) ^ CJ ^ (D C 1 •H .-^ rH CM-H Cn C e (0 'd O c^U K +J ^^-^ ■H 0 C U 1 -^N* ^ u • — ' I ^ criMH E rH 'd d CN tn o O^ U E U — &^ c E (0 TS rH CMO w — «— ' ^->^ 0 CP CJ E <=s) t3 u — E 5 w 00 in r- 00 ro 00 o IT) rH o o o^ 00 E w w o ro LO 00 ro CO [— r- vD W o a r-l o (0 o ID ro (N 00 CM o^ 00 00 5 w to r^ o in uo m CO r~ r~ ix> m 00 CO o 5 3. 3 00 00 CO in rH CTl CO CO r~- B B "3^ CO CM ^ ID 00 rH O E S E E -P •H W C o -p c -H > •H res rH .Q •rl o .■*; QJ d G, a) >H * Xi •» +J 0) -p C 5h •H i "^^ a, u x: fN ou •H x: Z T3 e^ u C\ "o c •H rH 1 -H — C oj a Cn-H E >i T3 x: (N-U K (U — E 0 1 U 'a- I ^ u E CM -a — K C O -H XI ^ X) ^ «k ^ w ^ 5 to w O O O CT\ CM v£) in ID o in ^ o r^ (^ in n CNI rH fH M o CTi a\ tn o CO W W W 5 ^ w o in in o VD in o '3' r~ VD 00 a\ 00 VD rg ro •^ en CM CM CN rs iH X2 o CN ? tn 10 en o CN VD o ^ 3 O CN o cr> (/) 00 o o VD 00 r~- 00 n o r-« o CN CXi VD VD VD in in rj M M iH nH .H r-i >H rH nH 5 <'-*» ^•"■^ .^-^ -— V ». ..-^ ,,— ^ ^-^ ^,^^ ^■^ cn ^ S 5 X3 B !/;■ tn CO W "^^ ^— ' ■*— ' *^^ ■*»^ v^-^ ^^^ ^^ v.^ in LO o (N LI OJ (N m 'd" in CN —1 CO cr> 00 iH 00 (y\ ro o rH vr n 00 r- VD in •^ CN CN C'T CN CN •H r— ' iH H iH f-i rH 13 0) c •H +) O •0 X 0) C4 0) Id o CM I K a • 'O O I O U CNr-. K -- ''^ a u 4:: cNa •H x; u r— 1 '0 c ■H iH 1 -M ^ c cgtd tJTH e >i 'O x: rM4J K (1) >- g 0 1 u ^ o 00 B 5 ID CO 5 5 e IT) 00 00 CO en o e E_ en 00 r-t ix> 0 CTi e. 00 OT H 0 vT' 0 CO r- t~- CVfN' ^U Cn^ e CO 00 r- r- vO 14 acid were used. The UV spectra are reported in Table 3. The UV spectra of all these compounds are dominated by 21 intense charge transfer bands. Yamano et al. report thrde bands in this region for compounds of the formula [Co(H2dmg2)- A ] where A is an aniline derivative. These three bands are present in [Co (Hdmg) 2 (clan) 2] C-t and [Co (H2dmg2) (4-methyl- aniline)2]C£. The band between 25.0 and 27.5 kK (400 to 360 my) was assigned^-*- to the charge transfer from the aniline ligand to the cobalt ion. In agreem.ent with this assignment the band for the complex of the more basic 4-methylanJ line at 27.6 kK is lower in frequency than that for the analogous complex of clan at 28.9 kK. The band near 33.0 kK (300 my) was assigned^ ■"" to the charge transfer from the cobalt ion to the dioximate ligand. The band near 40.0 kK (250 my) was assigned'*'"'" to the intra-Hdmg tt-^-it* transition. The UV spectra of cobaloxime complexes with a cliloride ligand trans to a substituted aniline shov/ three bands, also. One band is between 27.0 and 33.0 kK (370 to 300 my). The other bands lie near 39.0 kK (255 my) and 43.0 kK (230 my). No assignments have been made for these three bands. The charge transfer spectrum of a solution of [Ni2Ct- (H-0) . (dhphpy)]C£-. •2H 0 in 0.1 M HCl exhibits the same ab- sorptions as that of a solution of H2dhphpy (N02)2 ^^ 0-^ ^ HCl. The intense bands at 25.4, 32.7, and 37.3 kK (395, 305, and 268 my) are presumably due to the aromatic system of the ligand. 15 o o o o O ,— , o o o o o O o o o o o o o o o cH >£> ^ -' rH ■ — ^-' ^^ ■ — r- r- 00 » >* CTi CO CO • • ■<* . • • • 0-. C?i ^ •^ 3< '^ r~ CO o o »— I r- (N CN •^ 1 — I M" Ol r- ^~^ ~-^ • — -^ y^ ■ — ^— ' t 00 in 00 VD • Q-) r~- CM • « • • cri • • ro CN — 1 cn ro ro n ' — ' CO n O o ,^ „^ o o ,-^ o O o o o o o o o o o o o o o o o "^ r-\ CM CO f^J o VD in rH r-i o^ r- r-i CM in CM CO CTi VO r- rH r- CM "^■< 'J' n fo • « • • • • • • C 00 r~ CM rH C^^ r- in U-) <1) 3 CM r^i CO CO CM >, CM w 0) 0) CN m •H •H • 0 rH •rl rH •H CO XI C . — . d U IT3 C 03 1 — 1 « OnJ rH (d 0 ^— m o >1 rH U o >i M x: u ,-, ,— , 4J CM 0. +> OJ +j — C C •H s. r o „^ 0) ^~, (0 (13 c CM CL, 0) c: E en r-{ rH 1 • x; Cl, (0 1 e U o •^ CM ^ w r-H 's- s ■ — ^^ ■—^ ^-~ "^^ U — „-^ ^ — , ^-^ CO '=!• -p ,-, ,-^ CM 04 r e a Cu S ^-' CM o Cn e T3 E "a T3 >i E •H £ TJ CM CM CM CN a ■ > T) CNJ K E K ffi x: =^ (0 E K — ^^ — ' — ' a, u h ■ — • O 0 0 0 x: CNJ ■P 0 0 U U u U -a •H rH U u ^s" «Ni "^ CO CM 2 D U CJ CD u T^ ' — ' C 0 •H +» o c •H +J X OJ Q) Xi +J ^ 4J • •H to :^ , , 0) fc^ D4 r^i ^-^ tu CO > 0) r-i •H 0 o CO c tu OJ u 3 tJ^ >i (U rH tH 5h m O o C p., 0 •H i-t +J o a <4H u o Q) CO M XI (0 <« (0 (U 4J X! o >i (d JQ Ti Q) 0> > • 5h O tn ai rl O — U U — . ,-,c^ tP >i a a * 'd X H fN a. o ^ c .-- rH u o o CQ — - «N - u a o cN e m 2; w cj O f^ ^ - u -- "=!• rH o c 1-1 (1) ■H C (0 o o .-. m4J -u Cr>0 ~- QJ e 2 — e fO --' Cli I ^- x; x: -— o aa^ «< cr> <^ 'O '- e K Oi e o -H O T) U -H rH — -- a (0 o x: (T3 -P CJ Q, O en •— -y-i >-i >i -- -p u u u c 0) a, c3 o (C 0) e u o c +■» cu in to m -p U t/3 f3 1-1 C 3 O Oi E O u (N (N in o O u U u o O CM c o -- c C .-I o O in fN u O in Z 00 (N o ;;^ in CN CN sD M-* ►-^ •^^ ^-^ o CJ CN CJ CJ O U u o fN O (N u u o CM CM o CN CO CN U o (Nl U o o CN o CN x: in CN Dm o o o CN Si o u CN Cn in in CN O CN CN • O ?-. o CN o u u u u u u o rH CN H CN CN IrH I-) rH c n CN Oi + 0^ + u rH + CU 0* a< + cu c C <-t C H C iH CN CN + CN H- CN + II II c II C II c <^ J«i CN A^ CN •N" CN + + II + II H- II x; x:'=s' x:^ x; «^ (D • • (U • • •• • • •• Q) 0) G) •• • • C <^ c «s) c^ .V C C C o ■^ o o o >i o M O 0 0 o M o c x; c x: x: x: x: c: c c x: u •H x: u u o ,Q u u •H u -H ■H u o u E •rH ■H C ■H c c •H ■H •H 0 C c •H c •H -H c c r: ,r-; •H ■H M ■H rH rH •H •H ■H 'u .-H .H o 1— 1 u U rH rH .— 1 0 O o 0 u o O O o u ,C O ■H c •H c c •H •H -H -P c V^ o S-l 0 o M M M M o 4J B 4-) E E -p -l-J 4J 0 E o CN (^ O U u CN CM CQ U w o H 1-3 (0 0) d cr •H c ,c o (U ■p CJ •H x: CO u en O ■P O x: ft E O M-l •d (U c •H a o (1) u is a; (0 •H 0) +j ni (0 +» 'd (0 E (0 T) C 3 O a, 1= 0 o u o «H --- >- o ca o o<: XI o<: (t o < c o e o a ro CTl D a\ CO LD C7> n 00 ro m in r- (N •^ o <>D o U5 O r- 00 CN r- r- m m in O IT) IX) 0-) o LD LD m •^ t^ -H ro CM VD 04 CNJ r-i ^ OJ (N CO CO CM CO r- CM CTl • • • VD r^ in a\ cs •^ ro n CO ro in >X) •^ ro \o o in C a w fci o CTl CM * M 0^ n t- ■^ CN en ro ro in CM in in 1X> CO rH r- r- vo VX) CTl in o o o VX) o CN o o en o iH iH in 00 r- ro in O o H • • • « « »x> o o o o "^i ^3* CO o o o CTl o^ (y\ CTl .H iH en en o^ \D ro rH in OJ a\ vo 00 in LO ro in r-{ o O in o CM in o> ro CO rH CN rH o ,-i CO o CM o ro r-i ^ ro in CM r^ ■^ vo 00 ro CO • in 00 ro o rH • « in CO o o in 1— ! o VD rNi • CO VD CM ■^ ro vr o X) o in cr> >.o y> CO rH CO r' in X) ^ CO • ro • o VC • • • iX> CM ro * 1-0 20 0) xi 0) X Eh 0 -H +J rO •rH •d T) 0) n) CO « D CN r-l o o m 00 a a « 8 a a a « « « « « « « o o o 0 o 0 o s: S s s s s s to r-- in L-) 00 vr o m d o o m rH rH in "^ o • _ ■ • • • • iH ■H o' o o o o o o tC 10 X X ><; X X X X •P K -. CO o rH rH o rH TT in on rH fM n m n m CM >ig q • • • . • • . Sh ■H n o O o o o o O u D ^ X X X X X X X V)' 00 CTv ■"{ ,-i « O r^i rH fi OJ in "^ O (C U rH rH CN r-- CN CM r~- m as O o in ■ • • 9 \D M* • * • CO Q iH rH rH rH r-i rH rH rH r-t rH N fv] '^ rH "^r CO CM CM CM CD ■>* M :3 ■P CM »;:• in VO 00 a\ r~- o r-* CM in r- •"^r r~ r- in n CO CTi (U &i t • • • • . • « • cH •H 00 VD CO o in CM vr> V£> 00 00 O OJ 00 -J* r~ (-> r'l O ■^ r~- u 0 >-i 0) OJ .H o r^ CM ro (T, cri in • W IW o <-i VD o^ in r^ ro O XI 0) o o VD O a% '3' CN 2; O p:5 CN OJ r-i .H CN i-n in CO CM ro in CO CTl 00 CM r-- r- o IT) O O O o O CN .-1 CN CN OJ CN CM ID in in in m in in "^' ■^ M" M' ■ti' •^ ■^ o o o o o o o CN r-{ CN in ■H r-{ O ) O i O o o O o a o w fe o 22 which the reflections wore centered on the diffractometer , and the values of the refined cell constants with their estimated standard deviations compared to the cell constants obtained by photographic methods. All intensity measure- ments v;ere made with a fyntex PI diffractometer at ambient temperature. All unique refelctions up to a limiting 26 value were measured using a variable speed 0-20 scan tech- nique. The scan rate was determined from a fast throe- second counting scan of the reflection peak and varied lin- early from l°/rainute for counting rates of 150.0 c/scc. or less to 24 "/minute for 1500.0 c/sec. or more. The intensity, 1/ was defined: T / 4. \ r /i. J. T ^ \ {bac):ground counts) , I=(scan rate) total scan counts)— ,r: — -, j j. /— ;] . (background to scan rate) Peaks were scanned from 1'^ below Ka, to 1° above Ka„. Mea- surements of the background count were made at the limits of each scan. The estiraatod standard deviation, o(I), of each reflection was taken to be: „fT\-r f4.^*.-.-\ ^ J- \ , (background counts) i 1/2 a(I) = l (total scan counts) + ,r-'T -"j-z r-- — r^ J (background to scan ratio) •^ For molybdenum radiation, the incident beam was monochro- matized by a low order reflection of graphite. Any changes in the system were detected by measuring four standard re- flections after each 96 intensity measurements. A standardized data set was obtained by scaling the data to the initial value of the sum of the measured in- tensities of the standard reflections. The scaled in- 23 tensities of duplicate or equivalent reflections were av- eraged. Reflections with an intensity greater than Ka(I), where K is given in Table 4, were considered reliable. The unreliable reflections with I l^high! F, and F . , are constants given in Table 4. Prior to re- low high finement, an overall scale factor was chosen such that the sum of F ^ equaled the sum of F , . Isotropic temperature obs ^ calc factors were used in the first three cycles of refinement and then anisotropic temperature factors of the form: exp[-(3j^^h^ + 622^^ ^ ^^33^^ '^ ^12^^ "^ ^13^^^ "^ B23h£)] were used. The reliability index, R, was defined by: K — ' obs 27 Calculations were performed on an IBM 370/165 computer with programs written or modified by Dr. Gus J. Palenik, except where previously noted. The refinement of each structure is outlined in Table 5. 28 x: X 4J o •H 'O s c •H 0 o 1 +J -H cn or; c cu M d) 0 0) e >^ t-H 4J QJ 4J (0 0) y-i 05 C 0 g n 0 dJ •H W ^ ra ^ IW -H Q) ^1 • u i f« rO 4-> a. 52 U >; jC (1) ■p T) •H c ^ •H ■p CO « c u n q; -h flj e O^rH 4J 0) 0 (0 GJ IW CO C Jh e E= 0 (D •H 4J n rj rH M-l O Q) M • u 0) w x: m O >i C5 -rH •p a, 2 O CO C CO in iH -P n c ^ ■-i Ti B >^ (d :s >, 0 CO tH x; v^ X C iw >-i Q) 0 (U -d d to -H C B u •H rH 0 3 1 rH +J 0 OS R3 (0 C-H +* c 0) g 0) G •H «»-i (U It; «H o •o n c 0) 3 E 0 0) a JS £ 0 O (0 O V£> fO >x> <£> CM r- in ^D a> to r- vr> r» V£> O o o • o o • o • o • ro in CN O f-H m U5 ro o\ CTi ^' o r- in ro CA m o i-l o rH rH o m rn ro m m ,~. K U c , , , *-^ O ,— , r^ 1 CN a Cu a, — ' c (N K x: a, a , — . nj . — . fvj a, jj ■p U' r4 r* • x: — - ^^ S O .-5 CN S ,— . ,-~, Tl i-i ^-~. a. a. • — • ,-~ 0 OO ^ u 0 ,-, CN — ■ O ,-^ tP CT. CM Z o o x: e a ^-s CN u K -o n3 CP >i X •>* ■^ 04 CN e a ' — • , . E ^ 'O x: e^ x: x: — ■ — ■ E a U a. a O o -^ x: CN i*-( MH U o o -o -rl ■ — • ^-- «^» <:*. o CNJ 2 *r^ ■«• O u t: o u ■p •H 0) u E 0) 0) I a (C 0) x: Eh i •v O rH c (0 -p <-< ■rH 4J It) (0 1 C o Pi 0) d -H E -( --H 4J <-i i (U W 0 >i P^ ,0 >.| ■r^ "Z u •d >1 0) iH •a 1 rH c: C (0 0) x: •H U X +) +j •H ret i •iH W Dj O TJ 0) 5 £5 0 C c 0 5-J -H ■H 1 ns +J -P U-l 1 ■P rO O (U Pi C m H in 0) C -H e (U -P (D 0) tT>Tl 0 ,-H 0 0 >i ct5 x: u ja 2: u c O 6 O o ^D ro ID CM rH CM CO in o O in o o Lfl LD 00 ID ■^ CO (N r^ r^ rH in ro rH rH LD ro o r~- CO in o o o o> CTi CM r^ CO IT) CO ro o o o CO O I ro ro VO O CN o K CN (N E X • CN o CO • in 'c "cN 1 — 1 Q CJ ■N" ^-~ ■-^ • u o >i ^■^ -— N. o ,_, CN CL, a> a c og K X a. a, ._^ (U . — . (N a ■p -p CF> .H C • _r^ •-' ^^ e o m rvi 3 -— ^ .^^ T3 iH .— a. Qa ,-, o CO •^ ^ u , . CN O , — {T> Cr> (N 2 o 0 Xi e CU ^^ ^-' (N u oi -O Xi Cn >. tc ':}• ■=) CN «N e O^ ^-^ ^-v * — * K M ^3 x: =^ j:; x: ffi D. CJ D4 CU O 0 ^^ x: Cvj M-l LM o u o '0 •H ' — *^ — =N> -^ u CVJ 2 •::;f «q o o ^; — u U CHAPTER 4 AN INVESTIGATION OF LIGAND-INDUCED PROTON SHIFT: THE CRYSTAL AND MOLECULAR STRUCTURES OF TRANS-CHLORO (DIMETHYLGI.YOXIMATO) - (DIMETHYLGLYOXIME) (4-CHLOROANILINE) COBALT ( III ) DIHYDRATE, TRANS -CHLOROB IS (DIPHENYLGLYOXIMATO) ( 4-CnLOR07U\:iLINE) COBALT (HI) ETHANOLATE, AND TRA_NS~BIS (DIMETHYLGLYOXIMATO) BIS (4-CHLO.HOANI- LINE) COBALT (III) CHLORIDE. The stability of bis (dimethylglyoxiine) metal coiriplexes has long been known and their importance in both qualitative 37 3 8 and quantitative analysis has been widely recognized. ' Metal complexes of Hdmg have been used to study tlie trans- 39 40 41 effect and the trans- influence ' of various ligands in octahedral complexes. Since the structural determination of the B, „ coenzynie the trans-bis (dimethylglyoxime) cobalt com- 42-44 42 plexes have become of considerable interest. Schrauzer has stated that to be capable of mimickiug P^ ^ ^ complex is required only to have a cobalt ion in tiie presence of a strong- binding planar ligand. Because Co(H„dmgp) complexes success- fully mimic the reactions of a cobalt ion in the corrin ring and because they are synthetically expedient, complexes of Co(H»dmgp) have been investigated extensively in solution as 45 models for B, „ . Until very recently there have been few structural data on Co(Hpdmgp) complexes. ' ' Except for the work of 46 Palenik et al . no structural investigation has been made of the interaction between the axial ligand and the equatorial Hdmg ligands. This interaction may be of considerable con- sequence. 30 31 Although sulfonamides are potent inhibitors of carbonic anhydrase they do not form strong coordination bonds with transition metal ions. Therefore, an interaction of the aro- matic ring of the sulfonamide with the carbonic anhydrase pro- 53 tein has been proposed to make a large contribution to the observed stability of the carbonic anhydrase-sulf onamide com- plex. Since a cobalt atom can replace the zinc atom in car- bonic anhydrase with only a 50% decrease in activity, complexes of Co(H_dmg2) '^^Y pri.^ve to be useful models for investigating the interaction of sulfonamides with carbonic anhydrase. An apparent ligand-- induced proton shift (LIPS) was ob- served in C-^Co (H2dmg2) (si.ilfa) which should be formulated C-^Co (Kpdmg) n3 .c; CU Ifi £ (N (tj K S H CN • 'C Q) ^ C M C nJ ^ nj Cn>H W H o e -^ o ^ -p — O f: U TJ Ti i O Eh U H-4 • o w c o •H W (0 --H U <-i E-« >i ■P i5 p o 47 (0 0) -P b- -P C -I o c 0 •H V^ Ct u o •H > E «« o x: +j (d Q) O 0 x: o -p o tP o •H o o Xi in tn W \xi U CM O lO'd 0) w d 3 o Cri • CO P4 r-' O rH m V — Ci ^ 0) tT" O D. W fa ^o CM >i O Ci u .a u O CO Tl tn-iH f-; o ? fi. CU P5 H E-i (fl f^ E O V^ O < -P 49 g 0) Xi +» •o c Id c ■H d) u -H E 0 4J fO Q) x; +j • Xi CP o c -p •H -p ? •H fO 0 G ^ 0 (0 ra -H Xi o * — • w CN e , — . 0 D^-P a (0 xi a c — 0) o u> u 0 ^ '' M-t >i o ^ cy< Q) c .d •H H ^ nJ v^ • nci Cu •H W o Eh CO Q^. D4 O C rH < OJ 51 52 Tabic 12 Selected Interatomic Distances (X) in Some Cobaloxime Complexes with Their Estimated Standard Deviations.^ C£Co(H2dmcj) (clan) C-CCo (Il2dpg) 2 (clan) Co-N{l) 1.999(6) 1.946(11) Co-N(ll) 1.872(5) 1.908(9) Co-N(12) 1.884 (5) 1.935(11) N(]l)-0(11) 1.3 37 (6) 1.356(11) N(12)-0(12) 1.329(6) 1.316(12) N(ll)-C(ll) 1.311(8) 1.258(15) N(12)-C(12) 1.308(8) 1.292(16) C(ll)-C(12) 1.457 (9) 1.455(16) C(ll)-C(13) 1.488(10) 1.487(17) C{12)-C(14) 1.487(10) 1.536(18) 0(11) ...0(22) 2.497 (7) 2.540(11) 0(11)-H(B) 1.37 (8) 1.41(]4) 0(12)-II(B) 1.36(8) 1.30(10) Co~CZ(l) 2.257 (2) 2.244(4) Co-N(21) 1.908 (5) 1.887(10) Co-N(22) 1.906(5) 1.897 (9) lsj(21)-0(21) 1.348 (6) 1.321(12) N(22)-0(22) 1.359(6) 1.337(11) N(21)-C(21) 1.280(8) 1.331(16) N(22)-C(22) 1.288(8) 1.313(14) C(21)-C(22) 1.468(9) 1.483(15) C(21)-C(23) 1.486(11) 1.4 57 (17) C(22)-C(24) 1.498(11) 1.464 (17) 0(12) -..0(21) 2.479(7) 2.460(12) 0(21)-H(8) 1.13(8) 1.16(10) 0(22)-H(B) 1.16(8) 1.17(15) ♦Distance given is for O (11) —O (1 2 ' ) ^0 (12) •••0 (11 ' ) ^Values for (^©(H^dmg ) (an)^]C£. are listed with atomic number ing corresponding to the compounds of this work. 53 Table 12 - extended C£Co(H2dmg2)(sulfa) '^ [Co (n2ding2)(clan) 2] C£ [Co (H2dmg2)(an) 2] C£ 2.023(8) 2.003(2) 2.001(5) 1.870(8) 1.906(2) 1.885(6) 1.884(8) 1.889(2) 1.889(5) 1.323(11) 1.340(3) 1.353(6) 1.344(11) 1.362(3) 1.333(6) 1.289(14) 1.299(3) 1.286(10) 1.293(13) 1.290(3) 1.303(10) 1.494(16) 1.477(4) 1.463(7) 1.532(17) 1.483(4) 1.482(12) 1.488(16) 1.485(4) 1.476(11) 2.507(11) 2.495(3)* . 2.491(8)* 1.50 1.44(3) 1.29 1.60 1.07(3) 1.21 2.235(3) 1.905(8) 1.896(8) 1.326(10) 1.338(11) 1.292(12) 1.290(14) 1.447(17) 1.494(17) 1.488(16) 2.479(11) 0.90 1.04 54 Table 13 SG^o.oted Intramolecular Angles (°) in Some Cobaloximo Complexes with Their Estimated Standard Deviations.^ C^Co(H dmg2) (clan) C£Co(h2dpg2) (clan) N(l)--Co-N(ll) 90.5(2) 94.8(4) N(l)-Co-N(12) 91.5(2) 92.1(4) N(l)-Co-N(21) 88.4(2) 87.1(4) N(l)-Co--N(22) 88.6(2) 88.6(4) N(ll)-Co N(12) 82.6(2) 81.3(4) N(ll)--Co-N(22) . 98.8(2) 100.0(4) N(ll)-Co-N(21) 178.8(2) 177.5(4) N(12)-Co-N(21) 98.1(2) 97.0(4) N(12)-Co-N(22) 178.6(2) 178.5(4) N(21)-Co-N(22) 80.6(2) 81.7(4) C£(l)-Co-N(ll) 90.6(2) 87.7(3) C^(l)-Co-N(12) 90.6(2) 89.1(3) C£(l)-Co-N(21) 90.5(2) 90.4(3) C£(l)-Co-N(22) 89.4(2) 90.2(3) cr.(l)~Co-N(l) 177.8(2) 177.4(3) Co-N(l)-C(l) 119.7(4) 118.6(8) Co-N(ll)-O(ll) 121.9(4) 123.3(7) Co-N(12)-O(12) 122.2(4) 121.2(8) Co-N(21)-O(21) 123.2(4) 123.5(8) C;o-N(22)"0(22) 123.3(4) 120.7(7) Co-N(ll)-C(ll) 116.0(4) 116.7(8) Co-N(12)-C(12) 115.6(4) 114.1(9) Co-N(21)-C(21) 116.6(4) 116.8(8) Co-N(22)-C(22) 117.0(4) 117.4(8) 0(11)-:](11)-C(11) 122.1(5) 119.7(9) 0(12)-N(12)-C(12) 122.3(5) 123.8(11) 0(21)-N(21)-C(21) 120.3(5) 119.4(10) 0(22)-N(22)-C(22) 119.8(5) 121.7(10) N(ll)-0(11) -0(22) 99.7(3) 95.9(6) N(12)-0(12)-0(21) 99.7(3) 99.2(7) N(21)-0(21) -0(12) 96.9(3) 98.2(7) N(22)-G(22) -0(11) 96.0(3) 100.1(6) 55 Table 13 - extended 46 52 C£Co(H dmg2)(sulfa) [Co (H2dmg2)(clan) 2] C^ [Co (H2dmg2)(an) 2] C£ 90.5(3) 89.8(1) 91.5(4) 91.7(3) 93.2(1) 93.0(5) 89.3(3) 87.8 (3) 82.0(4) 80.8(1) 80.8(3) 98.7(4) 179.3(4) 98.7(3) 179.2(4) 80.6 (3) 89.6(3) 88.5(3) 90.5(3) 91.9(3) 179.7(2) 119.1(6) 119.7(1) 119.5(7) 123.0(6) 121.3(1) 121.4(6) 122.6(6) 122.7(1) 122.9(7) 121.6(6) 123.6(6) 116.4(7) 116.9(2) 116.0(9) 117.4(7) 117.7(2) 117.8(9) 116.3(7) 116.8(7) 120.5(9) 121.8(2) 121.8(12) 120.0(8) 119.6(2) 119.2(10) 122.2(8) 120.1(9) 98.3(6) 97.8(6) 99.2(5) 96.8(6) 56 Table 13 - continued C£Co(H dmg ) (clan) C£Co(H2clpg2) (clan) N(ll) N(ll) N(12) N(12) N(21) N(21) N(22) N(22) C(13) C(14) C(23) C{24) -C ( 1 1 -C(ll -C(12 -C(12 -C(21 -C(21 -C(22 -C(22 -C(ll -C(12 -C(21 -C(22 -C(12) -C(13) -C(ll) -C(14) -C(22) -C(23) -C(21) -C(24) -C(12) -C(ll) -C(22) -C(21) 112.8 (6) 122.9(6) 113.1 (6) 122.5(6) 113.5(6) 112.4 (7) 112.3 (6) 123.2(6) 124.2(6) 124.4 (6) 124.1(6) 124.4 (6) 112.1(10) 125.6(11) 115.5(11) 119.5(11) 112.2(10) 120.9(11) 111.9(10) 126.0(11) 122.3 (11) 125.0(11) 126.8(11) 122.2 (10) The atomic numbering of Co (H2dmg2) (an) 2c/* has been changed to correspoiid to that of compounds of this work. 57 Table 13 - continued - extended C£Co(H2dmg2)(sulfa)'^^ [Co (H2dmg2)(clan) ^]Cl [Co (H2ding2)(an) ^]C.^^ 113.3(9) 112.2(2) 112.4(10) 125.0(10) 125.0(2) 124.6(16) 110.7(9) 112.5(2) 112.2(9) 124.0(10) 124.1(2) 125.0(16) 113.1(9) 120.7 (10) 113.1(9) 122.9(10) 121.7(10) 122.9(2) 123.0(12) 125.3(10) 123.4(2) 122.9(13) 12 6.1(10) 123.6(10) 58 ligands. This is in contrast to results reported for various Co(H2dmg2) complexes^^ ''*''' ''^' ^° ' '^^ as well as for Fo(H2dmg2)-- (imidazole) 2/^^ Ni (H2dm92) , '"'^ and Cu(H2dmg2), where either the hydrogen bridges were assumed to be equidistant from the tv70 oxygen atoms or the ligands were monoprotonated. The assumption of a symmetrical bridge may have in part been based on the earlier TR spectroscopic work on M(H2dmg2) complexes where the v^eak band due to nn O-II vibration near 1725 cm was assumed to indicate a very sl)ort aiid symmetrical O-H-O bridge. "^^'^^ McFadden and McPhail"'"'' reported the structure of Co(H2dmg2) (CH3) (H2O) ii' which both bridging hydrogen atoms if ordered are required crystallographi cally to be on one dmg ligand. No comment" was made concerning the bridging hydro- gen atoms. Although both hydrogen bridges in C^Co {H2dpg2) (clan) appear to be shifted toward one dmg v.'here the 0(21)-H(B2) and o 0(22)-H(Bl) distances are 1.16(10) and 1.17(15) Awhile the 0(12)--H(B2) and 0(11)-H(l!l) distances are 1.30(10) and 1.41 o (14) A, the experimental uncertainty is too large to show that result to be significant. The hydrogen bridges in [Co (Hdmg) 2 (clan) 2] c£ are not symmetrical and each dmg is singly protonated. The 0(12)-H(B1) distance is 1.07(3) A and the 0 (11) • • -H (bl) distance is 1.44 o (3) A. The gross structure is very similar to that of tCo(Hdmg)2(an) 2lC-^- Bowman et al. suggested the N-0 distance to be a sen- sitive indicator of the position of the bridging hydrogen. 59 Table 14 Deviations and Equations of Selected Least-Squares Planes in C£Co(H2dmg) (dmg) (clan)^ ° +3 (a) Deviations (A x 10 ) Plane 1 Plane 2 Plane 3 Plane 4 Co 5 -1796 0* 72 0(11) 25 -2574 209 0(12) -23 2533 80 N(ll) _2* -1260 175 N(12) 2'-' 1218 140 C(ll) 4* -775 251 C{12) -4* 682 220 C{13) 73 -1633 413 C(14) 41 14 98 330 0(21) 34 2602 -22 0(22) -79 -2548 -55 N(21) 48 1269 1* N(22) 7 -1197 _1* C(21) 113 795 -2* C(22) 94 -673 2* C(23) 230 1664 24 C(24) 143 -1482 -17 N(l) 2004 -41 0* C(l) 2752 -12* 0* C(2) 3092 5* 1197 C(3) 3767 5* 1204 C(4) 4105 -9* 18 C(5) 3790 3* -1193 C(6) 3112 8* -1204 Cl{2) 4946 -28 5 ClU) -2252 -29 (b) Coefficients of the Plane Equation ^8 Ax + By + Cz = D Plane A B C D 1 0.8529 0.4975 0.1583 1.6954 Table 14 - continued ^The deviations of atoms used to define the plane are marked with an asterisk. GO Plane A B C D 2 0.9995 0.0282 0.0142 1.6347 3 0.0208 -0.3098 0.9506 1.7440 4 0.8174 0.5536 0.1594 1.8108 61 Table. 15 Deviations and Equations of Selected Least-Squares Planes a in C^.Co(H2dpg ) (clan) ° +3 (a) Deviations (A x 10 ) Plane 1 Plane 2 Plane 3 Plane 4 Co 19 -1932 0* 29 0(11) -56 1350 -101 0(12) 122 -2807 192 N(ll) 17* 160 2 N(12) -18-* -1881 24 C(ll) -30* -945 -30 C(12) 30* "2118 62 C(13) -179 -1048 -195 C(14) 94 -3571 149 0(21) -5 60 0(22) -37 -87 N(21) -43 -8* N(22) 28 8* C(21) -9 13* C(22) -1 -13* C(23) 93 133 C(24) -58 -89 N(l) 1958 -148 0* C(l) 2755 -13* 0* C(2) 3166 4* -1171 C(3) 3843 16* -1184 C(4) 4069 -20* 10 C(5) 3720 5* 1166 C(6) 3076 14* 1205 Cl{2) 4901 -1 -10 c^(l) -2223 24 C(1A) 676 C(2A) 510 C(3A) -529 C(4A) -1417 C(5A) -1255 62 Table 15 - continued Plane 1 Plane 2 Plane 3 Plane 4 C(1B) 1094 C(2B) 1237 C(3B) 427 C(4B) -641 C(5B) -821 C{1C) 1232 C(2C) 1380 C(3C) 3C1 C(4C) -734 C(5C) -827 C(1D) 571 C(2D) 554 C(3D) -230 C(4D) -874 C(5D) -8^38 r p (b) Coefficients of the Plane Equation"^" A>: + BY I- Cz " D Plane A B C D 1 0.1954 -0.9752 -0.1036 3.3476 2 -0.2301 -0.9634 0.1374 ] .9549 3 0.5744 0.0297 0.8181 -7.1571 4 0.1976 -0.9769 -0.0813 3.2302 ^The deviations of atoms used to define the plane are marked with an asterisk. 63 Table 16 Deviations and Equations of Solected Least Squares Planes in po ( Hdmg ) ( c 1 an )2 ]Cl^ (a) Deviations (A x lO'*'"^ ) Co 0(11) 0(12) N(ll) N(12) C(ll) C(12) C(13) C(14) N(l) C(l) C(2) C(3) C(4) C(5) C(6) Cl{2) Plane 1 Plane 2 Plane 3 10 -1772 0* 36 2519 14 -5 2? 0* 1902 0* 428 1* 2567 -1* 1677 26 4046 11 217 3 - 2009 -28 0* 2799 -2* 0* 3030 2* 1194 3758 -1*- 1208 4257 0* 37 4048 0* -1168 3312 1* --1174 5159 -33 53 59 (b) Coefficients of the Plane Equation Ax + By + Cz ^- D Plane A B C D 1 -0.4938 0.67 23 0.5515 -0.0101 2 -0.5672 0.8236 0.0096 1.7716 3 0.7336 0.6506 -0.1594 0.0000 The deviations of atoms used to define the plane are marked with an asterisk. 64 X I Q VO VO >X> 00 CO ro CM (N o n VD .H r- ^ "^ o 'S* r- o fO 00 fVJ in r^ VO VD r- ut iH iH rH rH iH rH iH rH -H »H r-l rH iH -H C o m c a) en o a: Q o K I a m I Q [^(^r^f-«vor~-voin romoj r^r^r•^ cnr^o(T>^rorovo inooo oo(N r-Hr--C^ rOCNCM rHrH nvofoonoooArH r^co"* vor^ rH rH o 00 r^ 00 r- r^ o co C7> rH iH • •■••••t ••• •• r^r^rHOOOOO rHOO rHrH N I I N N N N >1 >i >1 I I N >i >i >i >i X ^ + X X X X -H X I X X I + N N I >1 - I X - + X '-^ I I X c. CN rH ^ CO — CN 1 1 n-* T' 1 — - ^-v . — , 1 1 ^^ o 1—1 (N ^, rH u CM cs rH r-< 3 CO >M>^ *— ' *— ' *»— ' u o O 2i .'-• O rsj O — I is 3 o u 5 CO u c (0 rH u CM CM C (0 N N N ^ ^ »- >i >1 >i XXX O >H >1 I iH o c r G (0 65 Dissimilar N-0 bond lengths should indicate the hydrogen is not symmetrically located and is closer to the dmg with the longer bond. This holds true in C£Co(H2drag) (dmg) (clan) where the N-0 distances appear to be different. The N (21) -0(21) o and N(22)-0(22) distances of 1.348(6) and 1.359(6) A in the diprotonated dmg are longer than the N (12) -0(12) and N(ll)- o 0(11) distances of 1.329(6) and 1.337(6) A in the dianionic dmg. Using the significance test described by Cruickshank and Robertson the N (21) -0(21) distance is possibly longer than the N (12) -0(12) with a t^ value of 2.2 4 and the N(22)- 0(22) bond is significantly longer than the N (11) -0(11) bond with a t value of 2.59. Also, in [Co (Hdmg) 2 (clan) 2] C£ the o N(12)-0(12) bond of 1.362(3) A is significantly longer than o the N (11) -0(11) bond of 1.340(3) A, v/here the bridging hydro- gen atom is bonded to 0(12). Neither the N-0 distances nor the bridging O-H distances in c£Co (H2dpg2) (clan) are signi- ficantly different. In [Co (Hdmg) 2 (an) 2] CZ where the hydrogen atoms are not significantly removed from a symmetrical posi- tion, the N (12) -0(12) distance is shorter than that of N(ll)- 0(11). The difference in these two bond lengths of 1.333(6) and 1.353(6) A is of possible significance (t^ = 2.36). The sensitivity of the N-0 bond as an indicator of the bridge position is questionable. The N-0 bonds are not significant- ly different in C'CCo(H2dmg) (dmg) (sulfa) when both bridging hydrogen atoms are shifted to one dmg. In the closely rela- ted dimethyl ( 3, 3 '-trimethylenedinitrilo) bis- (butan-2--one- oximato) cobalt (III) complex the two N-0 distances are e::ual 6C even though an asyinmetric hydrogen bridge is clearly indi- cated by the difference Fourier syntheses. Although a difference in the N-0 bond lengths as a function of protona- tion is reasonable, there are very few structures so precise- ly determined that this comparison can be made. Hence, no general conclusion may be made. Hov;evcr, when a significant difference in the N-0 distances has been found and the bridg- ing hydrogen atom has been precisely located, the hydrogen atom is associated with the longer N-0 bond. Another point in support of the formulation C£Co(H2dmg)- (dmg) (clan) is the difference in the Co-N bond lengths. The o Co-N distances on the ll2dmg side are 1.908(5) and 1.906(5) A o compared to distances of 1.872(5) and 1.884(5) A on the dmg side. The differences in the Co-N bond lengths are signifi- cant and the shorter distances involve the dianionic group. This holds true in the other cases where the presence of both H2dmg and dmg ligands has been indicated. In CcCo (H2diTig) (dmg) - (sulfa) ' and in Co (H2dmg2) (CII^) (H2O) ^■'" the distance.s from the cobalt atom to the dianionic ligand are shorter than the distances to the neutral H2dmg ligand. This is not the case in C£Co (ri2dpg2) (clan) where the distances from the cobalt atom to what would be the dpg didnionic ligand, 1.9 35(11) and 1.908 o (9) A, appear to be longer than the corresponding distances to the n2dpg ligand, 1.887(10) and 1.897(9) A. These differen- ces together with the apparent positions of the bridging hydro- gen atoms (vide supra) in C£Co(H2dpg2) (clan) are of question- able significance. 67 For the mononegative ligands in [Co (Hdmg) „ (clan) 2] C^ the Co-N distances are significantly different. However, N(12) which is l:ionded to the protonated oxygen atom is closer to the cobalt atom than is K(ll) with distances of 1.889(2) and 1.906 o (2) A, respectively. The same relationship holds in Fe(?Idmg)2- 55 (imidazole) 2 r the only other M(Hdmg)2 complex whose X-ray structure precisely places one bridging hydrogen on each dmg and shov/s a significant difference in the metal to nitrogen distance. /in unsyixmietrical hydrogen-bonding system involving two similar atoms may be fluxional. In such a system two equili- brium positions, i.e. potential v/ells, exist for the hydrogen atom. Each of these positions may be considered as having tiie hydrogen atom covalently bonded to one atom and hydrogen bon- ded to the other. For the system to be truly fluxional the energy barrier betv/een the tv/o positions must be thei:aally accessible. Depending on the relative depths of the potential wellr. , tlie energy barrier betv^een them, and the thermal ener- gy of the system the position of the hydrogen atom as indi- cated by X-ray diffraction experiments would vary. Because of the diffuse appearance of the bridging hydrogen atoms of the M(n2dmg2) complexes in difference Fourier syntheses, a fluxio- nal system with two potential wells of unequal depth seems reasonable. The relative populations of the two positions will depend soniev7hat on the depths of the potential wells. The ex- perimentally determined position (or positions) of the hydro- gen atom v/ill reflect these populations. As the depths of the 68 potential wells approach equivalence and as the energy barrier between them becomes smaller the position of the hydrogen atom will become experimentally more uncertain. A fluxional sys- tem could, in part, account for tlie difficulty iii precisely locating the bridging hydrogen atoms in M(H2dmg2) complexes. The orientation of the 4-chloroaniline ligand in the complexes of this study is quite intriguing. A projected view down the Co-N(l) bond for C£Co{H2dmg) (dmg) (clan) is shovm in Figure 4. A similar view for [Co (Hdmg ) 2 (clan) 2] C£ is given in Figure 5(a) and one for C^Co(H2dpg2) (clan) is given in Figure 5(b) . In CeCo(H2dmg) (dmg) (clan) , as in C£Co(H2dnig) (dmg) (5:.ulfa)^^ the aromatic ring of the aniline is oriented over the dianio- nic dmg ligand. The orientation angle, i.e. the dihedral angle between the planes having Co-N(l) in common with one containing C(l) and the other containing the bisector of the angle N (11) -Co-N (12) , for C£Co (K2dmg) (dmg) (clan) is 0.9° and for C£Co(n2dmg) (dmg) (sulfa) is 1.8° us given in Table 18. In [Co(Hdmg) 2(clan) 2]C£ and in [Co (Hdmg) 2 (an) 2]C£ the ben7ene rings are skewed relative to the equatorial ligands with ori- entation angles of 53.9° and 58.3°, respectively. It seems significant that in the former pair of Co (H^dmg) (dmg) type complexes the rings align while in the latter pair of Co (H- dmg) 2 type complexes the rings are skewed. Although tho ben- zene ring of the aniline is tipped from being parallel to the dmg plane by ca. 30° as in other similar complexes (see Table 18) the alignment and the distances between the two planes in C£Co(H2dmg) (dmg) (clan) suggest a ir-type interaction. The o -I C) CN u Ui CP o -H u CJ M O I o o o l-l n) 0) •H > (U +) o 0) •n O M &. 70 O o- CQ .X O o CM o o o XI c nJ =^ CJ o (M 6 in w QJ O O :3 I o o O H I > ♦d (U -p o 0) -n O U 72 73 en o fH c E o u o CM a, K O O u rH o CM o 10 0) tT> en C c < ■H +> r-] o fO 0) V4 CO m tJ ^1 (U 0) i -d X! Q) G T! -H 0) in N (U C W MH T! « -H 0 X! W '* M •HO) O X (U -M r-l ^J C U fd OJ 0) G r-l U5 C -H p^ -H (0 X5 rH W fij e • (u o--x: • 4-1 rH 4J r, ^^-' ^ u^ --I c c 1 o T) fd ^ JQ C ■-' Sh Id - (0 ^ en o '•'H 0) ^^ M (1) rH 2 X) x: — ns -P S ^ H 0 >, -u C X! 0 •H u en T! C ^3 (1) >i-H 0) r; X! fc C -H +J ■H MH tJ Ci M-' GJ (D 0 Q) ^ii C o li -H tn iH m tn -H 0) nj tJ OJ CN c CO en (ti G) J CJ 0 rH ^v_- . r(3 en u TJ C 1 C rd +J t3 (d en c tT> - (d fd -H — dJ rH iH • rH V 22 r-( r-i ,-^ C tr^ C^ — -H >i C (d s?; >H X! (d 74 0) c o y, I 00 I-l Q) iH a EH o-i ^-^ Cf^ • • o • (N 1X> CO >X) rO OO rH CO n 00 in o r>- — , r- • • o • CO CTi CO c •-H 4-i O QJ W CO >H O) O c; 4J (C CS' n •^' r-> "* vf Ln n cH 1 1 1 1 1 1 1 M 04 r-i ^_l rH rg cs en n 75 distances from the dmg plane to C(l), C(2), and C{6) given o in Table 14 are substantially less then the 3.40 A interpla- nar distance in graphite. A proton transfer occurring from one Hdmg ligand to the other would increase the electron den- sity within the ir-system of the formed dianion. An interac- tion by v/hich the filled it orbitals of the dmg overlap v;ith the empty ii* orbitals of the aniline v;ould enhance the basi- city of the aniline ligand. The complex formed v;ould be stron- ger than might be expected based on the K, value alone. This same argument applies to C-£Co(H-dmg) (dmg) (sulfa) which was the first example of ligand-induced proton shift in a mole- cular complex. While the positions of the bridging protons in C-^Co (H^dmg) (dmg) (clan) and [Co (Hdmg) 2 (clan) 2] C^ are well defined, the bridge in C.£,Co (Hpdpg-^) (clan) is ill defined and the orientation angle of 36.7° is an intermediate value (see Table 18). The 0---0 distances in this complex shov; more variation than those in other related complexes as sho\;n in o Table 12. The 0.08 A difference in the 0...0 distances is the same as for the corresponding N-'-N distances. The N(12)''' N(21) separation is 2.836(15) A and the N (11) • • 'N (22) dis- o tance is 2.914(13) A. Concurring with these observed distan- ces, the N(12)-Co-N(21) angle of 9 7.0(4)° is more acute than the N(ll)-Co-N(22) angle of 100.0(4)°. None of tlie other com- pounds examined shows any significant differences in the cor- responding distances and angles between the diglyoxime li- gands . 76 A comparison of mean bondiny distances for each of the reported Co(H2dmg2) complexes may be made from Table 19. There appears to be little variation in the average Co-N distances or in the average dimensions within the equatorial dimethyl- glyoximc ligands as a function of the axial ligand.^ Those complexes having chloride as an axial ligand show a definite variation with the nature of the trans ligand. The longest Co-Ct distance is found where tpp is the trans li- gand. This is not surprising since phosphines are knovm to have a very large trans- influence but the small influence the tpp ] igand exerts on the trans -chlorine atom compared to 40 that of an ammonia ligand is unexpected. There is no sig- nificant difference in the Co-N(l) distance involving a clan ligand v;hether it is trans to a chlorine atom or trans to another clan ligand. The trans -influence appears to occur in Co (K2dii-ig2) complexes but not to a large extent. The Co-Y distances in the XCo(H2dmg2)Y complexes where Y is a ligand with an sp nitrogen, increase in the following order of Y: NH^ < an '>- clan < sulfa (see Table 19). This series can be rationalized in terms of the relative K, 's for sulfa (2.3 X lO"-*-^),^^ clan (9.6 x lO""'--'-),^^ aniline (4.0 x 10~ ),^^ and ammonia (1.3 x 10~ ) . Bruckner and Randaccio did not consider the J'j-'s of the different nitrogen donors in their argument of the trend in trans- influencing ligands, X, upon the Co-N bond. The same Co-N distances were used for NH^ and aniline complexes in their argument for basing the extent of trans - in fluerrce on the a-donor power of the trains 77 U) i-H u C^ o n O I CO . u i CO I o u I o u IT) CN n o ^-- vo u~> (N CO 0-) en tN cr. ^ LD ro r- Lfl ro oi oo fO 01 in oj K) Lfl CNi v-o ro ro ro 00 CO CO o 9 r-l 00 CO O CO CJ> CO LTl cy. co CO o CT\ CO 05 CO CO CO CO rs in ^3- o") rH •=3* r^ ^s" LO "-H r~- ^ ro m r- LO CM CN OJ c^J r^ rvj CN C^J CN c^ rr> a\ uo ro "^ ■=;r o ro o o CN CN Cvl 04 <^ CM 00 -^ C-) i-f) Ln a^ CO >xi 01 tn cri C?i o o ca CT> (N o og V.O CM c?i ro L'1 O o o crv cr> cr» CM CN v'N O CM U O CJ cv^ e^) cJ u u 0 (3 ro O Ci CN "-^ C U X o u (0 u-l ro m Qj, Cu ►^ 4J r.-^ ro Cu ro O O o o CN E-i u U U P M 0 'O c ■ u m c 13 4-1 O w e ^, O Tj 4J fO 0) +J o o a fd K C (d 4J 0) O +J 6 S-1 O T3 K in •H a -p c o o 01 -H a) -P QJ d o i.^ a en Ci. (d a c 0) >; ^1 e 4-1 c (1) (d V4 c •r-l +J 0 rd Q) -r-l cr> > , QJ P ■ri w o fd (d (d 4J W (/J 15 r-l 4J fd (0 > 6 •rH fH 4J r3 CD -H Di •H O 0) 4-1 o Si 4-> (d u-l ai o E c; o o p > o r-\ 0) r-l M a 0-> :i U) 0) 4J 5-1 O (d P Id w V 0) -H en t! 0) c x: -H 4-) c o QJ 4-> M CUrH r, o c cu > c J o en in 0) cd o QJ a 0) fH >1 x; 4J (1) o u o rH XJ O I CN I >1 c x: o 5-1 o fH x: u I w •H ,0 I oj a, tn •H H '^ c (d ai c •H T3 •r-l V4 >i a. Ti c o I c o .Q U fd o (d tn •H B x: CJ O E^ QJ in c o >1 1 78 0) '0 c a) -p y. 0\ r-i (1) rH a Eh (1) U C < >^ vo O o 0^ n t-H CO t- o ST *J' T ■^ in in T ->r in rH rH cr> cvj r^ CN CO -I 1-1 cr> "<^ >r> «S' M* 'J' tH n in (-' CX) 00 vj '^i' ^ rH I-H rH 00 fO rH »* in cTi o^ o CN m CTi CN CN 00 CN O O CM ^-^ rH r- ro o •^•* VD CO ^-' rH CTv CO CO cri o O r- cr\ C3^ O • • vj' • in • in • • ■^ • in • r-i r-l 0-) CN ro ro ro vo WD M* VD n ■>* •a* "jT •sr ^S' r-l .-I -H e^ ^ ej cU eO d CN --^ >. >t U o u u u CJ U a a; ex 04 Ci. n m o o c Oi ro o c c d UH x: >i u (fl t^ rH r-\ ro a &■ ro CX CM EH rH r-^ CJ 3 K a jcj c E 1 tc a 0 u +■ W P', -u crj ta U O O D 79 ligand as are presented here. In comparing C-^Co (H2dpg2) (clan) with C-CCo (H2dmg) (dmg) (clan) the distances from the cobalt atom to the equatorial nitrogens in the H2dpg complex are longer and the distances to the axial ligands are shorter in the same complex. Because the phenyl substituents are inductively more electron with- drawing than methyl groups , Hdpg should be a v/eaker Lev;is base than iJdmg. The equatorial distances to the Hdpg should, therefore, bo longer. From an electronic standpoint the co- balt ion in the Hdpg complex would be more positively charged and a better Lev;is acid toward the axial ligands than in the Hdn^g complex. From a steric point of view the axial ligands are afforded a wider path of approach and v/ill, therefore, be closer to the central cobalt ion. v/hen the equatorial ligands are farther away . The benzene rings in the clan ligands of Ci^.Co (IlTdmg^J " (clan), C£Co (H2dpg2) (clan) , and [Co (Hdmg) 2 (clan) 2]CC are pla- nar (see Tables 14-16) having average C-C values of 1.376(3), o 1.380(10), and 1.378(3) A, respectively, with individual values reported in Table 20. The phenyl rings of the Hdpg li- gands of C^Co (H2dpg2) (clan) are also planar with pertinent values and equations of least-squares planes given in Table 21 The crystals of C-£Co (H2dmg) (dmg) (clan) are held together by six hydrogen bonds where there are eight hydrogen atom.s capable of hydrogen bonding. Relevant hydrogen-bonding data are presented in Table 17. Although the 0-H---0 bridges be- tween the H2d;ag and dmg groups are not synv.aetrical, th.-; O-II 80 o -p E ■H 4J U V( •H 0) x: ? m (1) H o ns r--| 0) ;Q -!-> fct C •H ■•ci X o o u o (0 0) < c o « •si u CM c" rH u CM K O U r ! u a, CM o <^ u U e K O u u in Id ;^ c; o (0 to (U o C (1) «0 Q +t W Ti •H H -d ci C To o -n « to in o< V c ■P tn •H Q "-f IT, Vi) »tf' ':? rO ro CO ro t- r>-) 00 in o ro r-! r^ iH r-i rH O CN O rH (N CM o a\ £X> O (O •<-' -^ rH r-l -I rH •1 CN m o r- m CN] .H rH (vj n' <.o e5 ^1 vo •>-j< r- o CM ro 00 ro 'a* r- CO CD o r-l o o rH r-l O -^ '-^ r-( CTN CX) OT OO o CO (» cyi '^r r- CO r~ r- ro 00 oo ro oo r- ■i rH -1 I '--1 t ■ m '3' in ^^ ,-. ^~. c^ r-i I- : ■<3< in "vO ^-^ ?», C) a O CJ U CN rvj ro ro 'S' ro r, C^J 00 ro • o CM • in CO • r~ in • • 00 0\ iH O (-1 CM CM tH rH rH CJ^ 00 CN O CTv CTn OJ fH iH CO CM i-H ro ro •^ -=3" CN CM rH rH rH M ,H rH .H <-i --1 n-i rH r-i O r- •^' CTi 00 ro <• C^J r- r-t CM o CM r- O CM cr\ r-- r- rH CM Csl OJ r < CM CNJ rH .H rH CM rH i-M iH iH i-H ■H r-H .-1 r-H rH uo in vr r~ r^ r^ VJ3 ^D vD KD 'd' ■ r- co • r- r- r- • in 00 CNC-J CT^ r^ iH iH CNJ 00 T in vo •^- '— J- ^ ^ ^ ^- >- ^ -- — =V •^^ 81 Table 21 Bond Distances, Bond Angles, and Least-Squares Planes of the Phenyl Rings in C£Co (H2dpg2) (clan) with The.ir Estimated Standard Deviations. 23 24 (a) Distances C{n)-C{lt) C(n)-C{5.e) C{ll)-C{2l) C{2l)-C{3l) C(3£)-C(4.£) C(4^)-C(5^) . (b) Angles (") C(n-2)-C(n)-C(U) C(n-2)-C(n)-C(5£) C(n)-C(U)-C(2£) C{ll)~C{2l)-C{3l) C{2Z)-C{3l)-C(Al) C(3£)-C(4l)-C(5£) C(4£)-C(5£)-C(n) C(5£)-C(n)-C(U) o (c) Deviations (A Rings C(n) C(U) C{2l) C(3l) C{4l) C(5^) C(n-2) n = 13 £ = A 14 B D 1.3G3(18) 1.411(20 1.421(20) 1.396(20 1.368(19) 1.371(20 1.370(21) 1.367(20 1.352(20) 1.391(23 1.37.1(20) 1.390(20 123.9(11) 119.3(12 119.9(11) 120.9(12 122.8(13) 120.6(13 119.5(13) 119.3(14 120.5(13) 121.0(14 120.0(14) 120.4(14 121.0(13) 118.4(14 116.2(12) 119.8(13 X 1.370(19) 1.426(17) 1.356(17) 1.458(18) 1.432(19) 1.385(19) 1.351(21) 1.401(20) 1.371(23) 1.397(20) 1.409(18) 1.397(18) 120.9(11) 121.7(11) 121.2(11) 120.6(11) 122.3(12) 122.6(12) 117.0(13) 117.7(13) 122.2(14) 122.5(13) 118.7(13) 120.2(13) 121.7(12) 119.0(12) 117.9(12) 117.7(11) + 3 10 ) from Least-Squares Planes of Phenyl 2 -7 10 -10 5 -2 -3 41 -14 -31 48 -20 -24 172 -3 8 15 -29 3 19 -16 3 -12 24 -28 20 -7 20 (d) Coefficients of the Plane Equation PX + QY + RZ = S P Q R S Phenyl A Phenyl B Phenyl C Phenyl D -0.5815 -0.4144 -0.6482 -0.1592 0.5296 -0.7511 0.3950 -0.8986 -0.6176 0.4990 -0.6509 0.4088 4.7459 3.1793 4.0341 1 . 3 6 ^: 2 82 distances arc longer than might be expected. The tv;o hydrogen atoms on N(l) of the clan ligand both hydrogen bond to differ- ent water molecules. The hydrogen atoms of one water mole- cule, 0(w2), form reasonably strong hydrogen bonds to 0(12) and C£(l) . The hydrogen atoms on 0(wl), however, have only short contacts with angles indicating only v;eak hydrogen bonds. V^hile [Codldmg) 2(clan) 2]C£ and C£Co (H2c3pg2) (clan) both exhibit the hydrogen bonding botv.'een the equatorial ligands, Ci^Co(n2dpg2) (clan) has no interraolecular hydrogen bonds. While the hydrogen atom on the solvent molecule was not located, a hydrogen bond may exist between 0(S1) and 0(22). Each mole- cule of [Co(ndmg) 2 (clan) 2]C^ possesses two intermo] ocular hy- drogen bonds. Each clan molecule shows a hydrogen bond from N(l) to the 0(11) of another molecule. The other hydrogen on each N(l) is hydrogen bonded to the ionic chloride. Relevant hydrogen-bonding data for these two compounds are also presen- ted in Table 17. o All intermolecular distances less then 3.6 A were cal- culated and carefully examined. No unusually short intermole- cular distances were found. Ligand-induced proton shifts may be of biological sig- nificance. Since proton transfers in living systems are rela- tively comnon, the study presented here provides an impor- tant examination of orientation effects and enhanced stabili- ties which may be achieved by a small shift of one proton. CHAPTER 5 A NOVEL BINUCLEATING LIGAND: THE CRYSTT^ AND MOLECULAR STRUC- TURES OF 1 , 4-DIHYDRAZINOPHTHALAZINEBIS (2-PYRIDINIUMCARBOXAL- DIMINE) NITRATE DIHYDllATE AND iJ-CHLGROTETRi^J'i.QUA [1 , 4-DIHYDRA- ZINOPHTHALAZINEBIS (2-PYRIDINECARBOXALDIMINE) ] DINICKEL(II) CHLORIDE DIHYDRATE Binuclear complexes of chelating ligands have been of interest recently for their potential activation of other 6 8~ 7 3 ligands at an accessible bridging site and for their mag- netic properties. ^'*''^^~^° The structure of [Ni2C£{H20) ^. (dhph- py)]Cl^ shows the planar chelating ligand, dhphpy, to be ca- pable of binding two metal atoms simultaneously. In that com- plex, a bridging site betv/een the nickel ions is occupied by a chloride ion. Therefore, at lea-st one bridging ligand in addi- tion to dhphpy may be accommodated by M2dhphpy complexes. V7hile the study of magnetic interactions betv/een metal ions through bridging atoms in svxch systems is convenient and theoretically significant, the catalytic possibilities of this type system are exceptional. The nitrogen- fixing enzyme nitro- genase has been considered to contain a polynuclear active •4. 6,7 site. ' Although the mechanism of the reduction of N2 to KH^ by nitrogenase is not understood N2 is believed to be coordina- ted to the metal ions of the enzyme. ' ' Nitrogenase has been shown to reduce a wide variety of small molecules 7 which contain a triple bon i , The distance betv/een the rt'etal 83 84 ions should be of importance in the activation of tliose mole- cules. In the complexes of Robson and coworkers and of 8 3 Okawa et al. the metal-metal distance is essentially con- trolled by a single bridging phenoxide ion. However, in dhphpy complexes the metal ion separation is fixed at tx greater dis- tance by the geometry of the chelating ligand. Therefore/ lar- ger molecules which are reduced in the presence of nitro- genase, e.g. N^, N^; ^2^* ^2'^2' ^"^ HCN, should bo suitable for incorporation as bridging molecules opposite the N-IJ bridge of dhphpy. The syntheses and X-ray structures of H2dhphpy (NO^) 2-H20 and [Ni2C£ (H2O) ^ (dhphpy) ] Ci^, • 2H2O were undertaken to examine the nature of the accessible bridging site in coniplexes of this type ligand. So3.ution and Refinement of the Structure of H2dhphpy (N03)'2 • ^^2^ The direct method of syn^olic addition was ust-d in v;hich the signs of tv/o hundred large E's v.'ere assigned. All four- teen nonhydrogen atoms of the ligand within tlie asymmetric unit were located in an E-map computed from the signed K values. Two Fourier syntheses v.-ere used to validate the selec- ted model, locate the remaining nonhydrogen atoms, and re- fine the atomic parameters. The refinement is outlined in Table 5. The observed and calculated structure factors are given in Table B-3. The final positional and thermal parame- ters are presented in Tables 22 and 23. 85 CO CN o fN ro K rH CN CQ rvi ^ — m O ^s ••^-^ CS >i r-t CU ca x: a x: TS CM ffi ro 5-t m O ca H-t (0 e o tJ> ra 0 Eh U 'O >i x; rH c iH o ca Z 0) s: 4J »^ o «4-l N fO CO M 0) -P 0) e (0 >i M (0 Oi o •H g o 4J X < i-l (C e c o ■H +j Ci^ Xl^ooc-^<^r^r-a^oa^y:)c^ III I I I -H i^inoror--*J3 fo i;!' CN r>T <' m CN CN m CM CM ^ VD m r~- m fo ro ro 'y oT ro ■=? -^ "^^ ^ ro CO CO n ■^^ c^i LD fo <^ Q^f.-)(NiiHr^cx)roincyi':j'cy>^ir)n'^Ln'3'r-^ 1 lllltHrHI lllrOrHrHrOCN I I -^ ^ ro O O V-O rH CO CTi CO O CTN £T. in rH CO rvj iTi (-! l."> r--COiH'*COC^OiH';J-'^COCT\OicH(NvO-*Lr)CO -y- CO "=i' "^ --i" T ^ ID IT) "^- ro r-i en f") "^ CO in ro r-- c ^ ^1 fr, (^ VD oT CM "Nf cq r~ r~- OT c»iH'3e5CNr~r-^rocororHO>iH'<*o O^fv-)^00Lnvt'rH^£)LnvDL0-<3'(NC0CNO[^CJ^ vDOinorvjiX)i-.ocriro'^ot— ■^^r-'-or-cJ^^ rHC^JrHCNl IrH-H-HICN I |.HrHI III I mfOoommrn'3"^'=}'mcNCMCNmroro^ro'=r ^X)a^r<-)O^H^~^.:^c^^^oc^^^-cNco^^rlcocnc^J r-)^~c^i;r~C»CO'<3'l-0'^VOiH>X)— 4rHr-< fS CNJ CN C^J rM CM (^i ^^J CN CN rH r-^ rH iH r-J CN CN CM fX COlHM•^^lCNa^COOfOrHO^"lCNCOCOln^OV£)^H r-roLnr^cor->-DiHcorMooor-vi)cN + •H DtN OJ ro (0 ca 10 + C OfN •H Ai +J CN (TJ CN •H ca > 0) + CN T! x; U iH rj rH ro ca c ^ 1 CM ^^ n O S *»— ' >i D. x; ^1 ct. f^ ^ 'a X 0) CN r-1 K .Q (0 r: H -H M f: o +j < n 0) t^^ Q) o O u C rj (C >i 4J w to •H o Q x: +j j^ o <+-( to >-i (D 4J 0) E; r— 1 (U iH < ^ ro c C o •H n (i. in m ^^ o en r^ rH o r>j 00 r-i rH o >-{ rH o iH rH rH rH r-i in iH • o in • • • • • V)' • CM vDcovDincr.r^i>o •* CN f^") CM in <£> r- r-{ \ fM ro ^ in o ro CN o m rn a\ r^ c\ CO '3' in i-^- CO 00 (N VD rOCNfNC^rMfNCNCNrjCM ft r~ o rH ro r^ lo CO vo r^i m H in o vc in LO rH CO o ro CO o — ir— .■ .r-^OfMrO^in — O '-»-~.--^^-^rHl— IrHrHrHCslrH rHrHrO'* — ■ --^ ■^' ^^ ^^ ^^ OOUU— '---- — — — -- .^ ^^ ^~. ^-. O CM 00 ^ LO CM >l rHCMrOvrr-'rHr-'rHrH2Dj l-U 3^ »*4 aC D-l ¥*^ »M-« t^ ^ ZCJ ^ 0 •H (U a • x: o to 4J ^1 0) ■p to V 0 a) to to x: -P •H •p •0 + •H C O 0^ O rH JH OJ >^ M V) (0 -H to to +J u c •H OJ o 4J •H X ^ nJ Q) O.'O 0 ■P r-l ro <0 U E c (0 o 0 TJ 4-> •H c <0 +J (0 •H +J 0) to to x: 0 -p a-o Q) >i < CD rH r-\ a c: . — . •H (OOJ Cn-PcxC to n •H C •H 'O •H r.'o 0 c M +J o (U <0 X3 -P 0) CI tJl g 0) c (ti Cn-ri u 0 TJ ra >-i c 04 -a o >i arH x: to (tj a> g o u V4 x: u o Eh ox: rt 0 -P 87 Solution and Refinement of the Structure of [Ni2Ct:(H20) 4 (dhphpy) ]C£-:;-2H20 The position of Ni(l) was determined from a sharpened three-dimensional Patterson function. The positions of the remaining atoms were determined in a manner analogous to that used v;ith C^CoCH-dmg) (dmg) (clan) . After the hydrogen atoms were located they were included in further refinement with each having an isotropic thermal parameter one unit higher than the refined isotropic value for the atom to which the hydrogen atom v/as bonded. A sutrmary of the refinement is gi- ven in Table 5. The scattering factors for the nonhydrogen 29 atoms were from Hanson et al . and the hydrogen scattering 30 factors from Stewart et al. Lists of observed arid calcu- lated structure factors are given in Table B-4. The final positional and thermal param.sters are listed in Tables 24 and 25. Results and Discussion The atomic numbering and thermal ellipsoids of K2dhphpy" (N02)2*2H20 are shown in Figure 6 and those of [Ni2Cc(H20)^ (dhphpy) ]C£2*2H20 are shown in Figure 7. Selected interato- mic distances of both compounds are listed in Table 26 and corresponding angles Z'-re given in Tables 27 and 28. Both com- pounds crystallize v;ith the cationic complexes, their anions, and water molecules linked in a three-dimensional hydrogen- bonded network. The postulated hydrogen bonds in the struc- tures are listed in Table 29. Diagrams illustrating the pack- 88 Tabic 24 The Final Atomic Parameters^ of the Nonhydrogen Atoms for [Ui^Cl iU^O) 4 (dhphpy ) ] 0^3 . 2H2O Atom e 11 Ni(l) 11817(7) 17289(5) 9891(3) 4 4 2(5) Ni(2) 11346(6) -4660(5) 13854 (3) 407(5) C^{l) 1046(1) 315(1) 650(]) 63(1) C£{2) 1196(2) 4767 (1) 2115(1) 86(2) C£{3) 1297(2) -1548(1) 3350(1) 69(1) C£(4) 1288(2) 3725(2) 4540(1) 90(2) 0(1) -362(4) 1864(3) 639(2) 55(3) 0(2) 2743(4) 1634(3) 1329(2) 55(3) 0(3) -423(3) -532(3) 1026(2) 48(3) 0(4) 2664(3) -435(4) 170,8(2) 48(3) 0(5) 1626(4) -520(4) -194(2) 54(3) 0(6) 1072(4) 5047 (5) 3678(2) 74(4) N(l) 1178(4) 140C(3) 1690(2) 50(4) N(2) 1153(4) 576(3) 1834(2) 48(4) N(3) 1265(4) 2854(3) 1801(2) 74(5) N(4) 1258(4) 2873(3) 1324(2) 53(4) N(5) 1143(4) -469(3) 2395(2) 55(4) N(6) 1165(4) -1007(3) 2025(2) 45(4) N(10) 1234(4) 2554 (4) 433(2) 54(4) N(20) 1163(4) -3776(4) 1227(2) 55(4) C(I) 1233(5) 2052(4) 1992(3) 42(4) C(2) 1251(5) 1919(4) 2495(3) 36(4) C(3) 1280(5) 2594(5) 2826(3) 50(5) C(4) 1300(5) 2410(5) 3302(3) 56(5) C(5) 1288(5) 1559(5) 3450(3) 51(5) C(6) 1260(5) 2?7(4) 3136(2) 47(5) C(7) 1236(4) 1057(4) 2649(2) 29(4) C(8) 1182(4) 394(4) 2288(2) 29(4) C(10) 1281(6) 3550(4) 1076(3) 71(6) C(ll) 1291(5) 3337(5) 578(3) 52(5) Table 24- extended 89 22 33 '12 '13 23 273(4) 106 (1) -66(8) 224(5) 14(4) 244(3) 92(1) 2(B) 184(4) 13(4) 31(1) 10(0) -10(2) 26(1) -2(3) 35(1) 14(0) 8(2) 18(1) 0(1) 50(1) 17(0) 46(2) 39(1) 3 7(1) 72(1) 25(1) -58(3) 26(2) -1(1) 42(3) 21(1) 3(5) 26(3) 6(3) 40(2) 21(1) -6(5) 29(3) 2(3) 58(3) 18(1) -5(5) 23(3) 22(3) C9(3) 12(1) 17(5) 14(3) -2(3) 62(3) 17(1) 1(5) 26(3) -3(3) 111(5) 18(1) 1(7) 35(4) -6(4) 23(2) 11(1) -2(5) 25(3) -1(2) 24(2) 11(1) -1(5) 25(3) 1(2) 26(2) 15(1) -14(6) 38(4) -3(3) 31(3) 14(1) -12(5) 29(3) 3(3) 25(2) 9(1) 1(5) 19(3) 1(2) 26(?) 11(1) -1(5) 21(3) 3(2) 41(3) 14(1) 5(5) 33(3) 10(3) 32(3) 13(1) 13(5) 26(3) 0(3) 24(3) 14(1) -9(6) 26(4) 0(3) 30(3) 13(1) -11(6) 14(4) -6(3) 37(4) 14(1) -12(7) 27(4) -10(3) 44(4) 14(1) -8(7) 26(4) -17 (^i) 55(4) 12(1) -17(7) 23(4) -11(4) 40(4) 9(1) -2(6) 18(4) 1(3) 32(3) 10(1) • -8(6) 15(4) -3(3) 28(3) 12(1) -5(6) 20(3) -2(3) 30(3) 20(2) -7(7) 41(5) 7(4) 36(3) 17(1) -3(7) 29(4) 7('l) 90 Atom Table 24 - continued y 2 '11 C(12) 1343(6) 4055(5) 270(3) 83(7) C(13) 1353(7) 3839(6) -202(3) 86(7) C(14) 1308(6) 2992(6) -348(3) 73(6) C(15) 1251(6) 2361(5) -17(3) 59(6) C(20) 1143(5) -1829(4) 2053 (3) 54(5) C(21) 1147(5) -2273 (4) 1604(3) 48(5) C(22) 1149(6) -3175(5) 1577(3) 64(6) C(23) 1165(6) -3554(5) 1149(3) 77(6) C(24) 1204(6) -3048(5) 758(3) 76(6) C(25) 1195(5) -2157 (5) 812(3) 55(5) ^All values are x 10 except for those of Ni(l) and IU(2) V7]i.i.ch are x 10^, The estimated standard deviations are given in parentheses. The temperature factors are of the form: exp[-(B^^h2 + 332^^ + ^33^^ 12 13 2o 91 Table 24 - extended - continued ^22 ^33 ^12 ^13 ^23 49(4) 20(2) -19(9) 36(6) 19(4) 68(5) 17(2) -27(10) 34(G) 21(5). 68(5) 20(2) 7(9) 47(6). 15(5) 60(5) 14(1) -6(8) 27(5) 5(4) -» 29(3) 14(1) 0(6) 29(4) 6(3) 31(3) 14(1) 10(6) 25(4) 5(3) 32(3) . 21(2) 6(7) 31(5) 3(4) 39(4) 21(2) 15(8) 33(5) -6(4) 43(4) 19(2) 8(8) 24(5) -13(4) 39(4) 16(1) 2(7) 24(5) -6(4) 92 CQ vococccr. cof^oovorMvoinr-ion-^-^vokDin r^ <,• CO r-1 n o> rH ro in r-^ U1 ^3« rH CM C^i ro n m cH 1 1 1 (M r-l H rH ?-1 0, x; tn fO o cr> in m o in «* r^ r-1 CO (N o CTi r- CM in o vo r-; CO ^ iH r-l rg o vi; a\ m VO a\ CO nr rH VD "^ ro r- (N OS in fO .-) r- rn r- r- .-1 '^ r-l CM tn CO "* i 0) o U) a) 4J v!' o:. ro in CO r~- 0-) CM CO CO •^ in cv> o> r- rg r-l CO r^ rH CM •4' CM o> Ch ^1 t^ n o o^ ^ m CO CM n fO C-1 CO m v3< -J* o c^ r-l n a\ CM r- 'a* <-{ t-i rH rH rH rH r-l H r-l rH rH rH rH r-i rH 1 1 f\ o> r~ CJ> m c> CM >XI OA o o o^ o o in 'J* »^ in «4' (N r- CO o o o O O r-l rH CM in CO ^_^ ^^^_^ ^_^ . . ,_^ , ^ o CM ro ^ in o CM CO •TT in m in m •c in KO r-{ rH r-H rH rH ^ a) o d +> P o O 'a' VD m r- (N 1 1 1 1 1 M" "jf CO fO CO cr\ 00 ro CO CO in CM o-< CO s3< o in 05 VD -^ fS r- Vf) C) CO m r^ OJ CO ro 1 1 en CM iH CvJ r-i O r-1 O CTl in 00 VD CO o in r-H m OJ '"^ 00 r— 1 •^ ""* in ^ ' VD O O O O o in O O VD o o ■ — ■ ' — ' ^ ' ' '-^ i__( -~- W-* ' — • rs; ro ro ^ •^ in in VD V£) *— ^ > — ' v.-* ^..-■ ^.^ «--^ ^-^ ^-^ **--' U rH 0) 04 x; o -p u •» 0 CO Cfj 4J H q; >; Q) o^ rJ -P M jQ 'd d C ft! •H K tJ ,. -i C.1 XI -p ^5 O •> ^< ,^ C»r< rH rH d 0 •H UH ^-' d O (U u • > d -— ^ ■r-i (tJCN Cr>+Jort; CO CO •H d •rl rd •H >--' e t? 0 d M 4J c o (tJ Xi d 0^ fc; cu d ;'J en •H M 0 n3 rtJ U d 04 ^ 0 >i 0. H x: CO (TJ (D 0) >. M ^'^ 5-1 .1) E-i 0 _r; ffi (ti CJ P r^ A (d o g u Ok 0) ^ tf.» 4J o in •d c 0) (0 ^ +J tr> C 0 •H -P M 0) E •H y 4J C O 0) •H >^ e 0 rH ■P H (« Q) W x: +J Xi C tT< (6 • a V) •H U E X. ^ •H 0 0 CU-IJ Q) ^ 0 fj M W >H P +> d &>o o Q) ■H eg w D-i Pt^ t'^ •H 0 CM u • ai 'd CN in :^i *— >. rj x; ro 1 d O in o ;3 H d *— ' o >1-IJ !■! a (0 0 x: •W a d ,c i a 0 x: •H rH en 01 r t d x; QJ •r^ t-i ? rH nS o; 'd to B -d o fi^ •H -C W 0 •4-» H to ct; D. >i o •H 4J iH •H C M tH < a> CO 95 k-^ rH rO (0 0 E ■p »-i +j »^ <0 Q) ^ ^ e w ^i Q) C rH 3 O 0 •H 0 S rH o 0 +) B nj u tn Q) c A-i •r-l n ? fi 0 ^ ■•d (0 (U +j o « cNj c; r- rr: -rH r^i 'd Q) . M Vh -- 0 3 '- 0 Cn >i u •r^ Dj C Pm ,c; 3 a .C T) s C (ti ■<« ,^ W o F: cnO m +J (0 «^ u q CMQ) •H Dt Z 0 u -d IW >i 0 4:: tJ> i 0, s: D. .c ti ^«, *— , ^"«. *■— ^ ■^"'* *"** IT) U") v^ CM VO vo «* •W^.^ *. — ■ ^^ ^-^ — ■ " — rH r-l O^ r- CO o o o CiT U' o r- CM (', O o C CO r ) o w •ri • • • • t • (N r>) CJ Oi OJ ri es? G) O >H CV) i C>) fN CJ rs CN' rs< i v.> Eh 0. M- ,C c; . G. •H o Xi CM fO «i^>. m fsi "5 »-' m ti n 0 CM 0 o •H M-l c; z rt <— • (0 4J , <»-^ ^f— N ^^^ c D *^^ in »^:> (N o >£> n} >--^ -— ' ■^ • "---' '-'' *— ' +J ^^^ "tr cr> «t« ^ CO r- w m t~- a\ r-^ (^ CTi rH •H O CTl o m O r-i a • ■ • • • • en •H 00 r^ 00 iH ^^ «.^ •^^ *-^ ^-' *-^ ^^ ^-^ ro cy> r- 00 CM •T (y> ^ rH CO o W3 CO vr> r- vo ro "cj- vr m f1 ro (N ^ rH r-l cooor»v£> invDCM^^ s.. ^«^V^ ^ ^ ^ (J U U O U 2 ^; O I I I I I I I I — ^ ,-, ^ ^ ,-^ ^ ^ o M r~ vo in 00 in >^ c>4 O 7-^ U U U U2ZCJ ro •H Ck^ ,^ ^-> ^-. - — "^ tJlO ^--^OOO^rH^^ — --rH r— . r~-00rHrHrHCTtHC000CnrH Xi >i rocMr^cMm^oovooor^ -P D< u:>0'3", ooorHo^r~•vo^~•ln XI roro^'"=i'co'=?'^c»^mcM^ C Oi ! ••H X! r H r-l rH rH rH rH r-l rH iH rH rH X; 'O 4J ^ •H VD «- 1^ X c -4 r^ c^i ro vr r- u"! c") ^ i~* '-' <^ ^, U C) C.) U U U 2 Z U I WCJ llllllllll'-- »3<«*vrLn rn vrco'*v£>o^'X>co'wOr~»*£>vDr~m nro^ronromnmrM^r rv) —, r-{ ft r- {•-<•-< f-i i-i •-^ '-* --^ '-' >-' . ,-, ^-^ ^~. ^^ ~ - — — OrH >, rHrHr-jf")'*cM<;rrvirorH-^ X ^OOOUOUZZU I Oi I I I I I I I I I • -~ x: ^^^^,-.^ — ^^ — o rQ ^ ^J rH fs] o cN n o^ ,^^ ,. — ^ „— s. *— ^ *<— >. o r— I en n CM o ^-'^ r--> r-\ H rH r-H rH cr> ■ — ^ — «■ — --^ '^-^ — " "p^ 00 o n CM C7^ rH •d Oi CO o r^ C7\ ro LO 0) ^, ro ■=3' n fO n ro 0 Oa ( • • • • • c x; rH .-^ p-^ rH r -1 iH •H S ■P c v-O 0 ^— ^ ,— ». ^•^ ."-^ .--^ *'*^ - — ^ o o CN en •* in o t— ! CM .H rH rH r-l f-1 iH 1 tu v.-*- •«_-' •»— ' ^— ■■ ^^^ * — ' CJ u C^ CJ 2: CJ \s> ■^ 1 1 1 1 1 1 (NJ CJ ^— «« ^'-^ ^ — . y"^ ^"^ *•— >. CNl r-f r-i n ^ LO o 0) •iH rH r-l 1 — 1 rH rH r-I rH 52 — - — ■ ~ — ■ — '-^ jQ L_^ u CJ CJ CJ CJ :?i (0 EH ro o « ro •H ■rH 01 OJ w c 0) P. •H 0) K •H • XI rH CM r1 -g' LT) O ---> — ~ T:J rHrHrHrHrHrHrHrH ^r CJ U 4J CO O) <1) x; rj 100 0) ■H EH nJ i iH a ty x: c CLi <: x: -d fN m c •H W r^) f^"* <••"> ■^ "^ ^ ^ ;^ ii2 nHr^corHfNinorHinror-ic^ (N (Ti O O CO 0^ rH rH rH rH CT^ --------- C)U2 • oz: U U C) U U 7^. C) I I I • I I JL. ,-» ^ ^^ ^« — « --- o c>J Ln ^-. O rH ^^ rH rH -"-J C--1 rH r •H Cn (1) >H (d to c o -H ■p (d •H > TI u 'O c +j (0 ^3 Q) 4J 03 £ ■H 4J 'Jl QJ 0) x: E- 101 Table 28 Selected Angles in [Ni2C£ (H^O) ^ (dhphpy) ] C^^ • 2il 0 Atom Angle Atom Angle N(l)-Ni(l)-C£(l) 98.0(2) N N(l)-Ni(l)-N(4) 76.8(2) N N(l)-Ni(l)-2vI(10) 155.7(2) N N(l)-Ni(l)-0(1) 91.1(2) K N(l)-Ni(l)~0(2) 90.3(2) N N(4)-Ni(l)-C^(l) 174. G(2) N N(4)-Ni(l)-N(10) 78.9(2) N N(4)-Ki(l)-0(1) 87.8(2) N M(4)-Ni(l)-0(2) 91.1(2) N N(10)-Ni(l)-C^(l) 106.3(2) N N(10)-Ni(l)-O(l) 88.5(2) N KM10)-Ni(l)-O(2) 89.6(2) N 0(1)-Ni(l)-Ci:(l) 90.9(2) 0 0(i)-Ni(l)-0(2) 178.0(2) 0 0(2)-Ni(l)-C£(l) 90.3(2) 0 N(10)"C(11)"C(12) 122.2(7) N C(ll)-C(12)-C(13) 117.8(8) C C(12)-C(13)-C(14) 120.3(9) C C(13)-C(14)-C(15) 118.4(8) C C(14)-C(15)~N(10) 122.3(8) C C(15)-N(10)-C(ll) 119.1(7) C N(10)-C(ll)-C(10) 116.2(7) N C(12)-C(ll)-C(10) 121.6(7) C C(ll)-C(10)-N(4) 114.7(7) C C(10)-N(4)-N(3) 125.9(6) C N(4)-N(3)-C(l) 115.3(6) N N(l)-C(l)-N(3) 115.7(6) N C(2)-C(l)-N(3) 122.7(6) C N(l)-C(l)-C(2) 121.6(6) N C(l)-N(l)-N(2) 121.8(6) C C(l)-C(2)-C(7) 116.8(6) C 2)-Ni(2)-Ci(l) 97.8(2; 2)-Ni(2)-N(6) 76.5(2 2)~Ni(2)-N(20) 154.8(2: 2)-Ni(2)-0(3) 93.1(2: 2)--Ni (2)-0(4) 89.5(2: C)~Ui{2)~Cl{l) 174.1(2: 6)-Ni(2)-N(20) 78.2(2: 6)-Ni(2)-0(3) 90.4(2: 6)-Ni(2)-0(4) 91.2(2: 20)-lii{2]--Cl{l) 107.5(2; 20) --Ni (2) -0(3) 88.3(2; 20)-Ni(2)-O(C) 89.8(2; 3)-Mi(2)"Cf-(l) 88.2(2; 3)-Ni(2)-0('0 177.2(2; 4)-Ni(?)-C,C(3) 90.5(2; 20)-C(21)-C(22) 121.9(7 21)-C(22)-C(23) 118.7(7; 22)-C(23)-C(24) 120. 2(P' 23)-C(24)--C(r:5) 117.7(8; 24)-C(25)-K(20) 122.6(7 25)-N(20)-C(21) 118.8(6; 20) -C (21) -C (20) 116.7(6; 22)-C(21)-C(20) 121.4(7; 21)-C(20)-N(6) 113.8(6; 20)-N(6)-M(5) 123.4(6; 6)--N(5)-C(£) 113.8(51 2)-C(8)-N(5) 116.3(6; 7)--C(8)-M(5) 121.8(6; 2)-C(8)-C(7) 121.0(6; 8)~N(2)-N(1) 120.8(51 2)-C(7)-C(a) 117.0(6; 102 Table 28 - continued Atom Angle Atom Angle C(l)-C(2)-C(3) 123.5(6) C (6) -C (7 ) -C (8 ) 123.5(6) C(2)-C(3)-C(4) 119.7(7) C (5 ) -C ( G) -C (7 ) 119.4(G) C(3)-C(4)-C(5) 120.1(7) C (4 ) -C (5) -C (6 ) 121.6(7) Ni(l)-N(l)-N(2) 122.4(4) N.i (2 ) -N (2 ) -N (1) 123.3(4) Ni(l)-N(l)-C(l) 115.8(5) NJ.;2)-N(2)-C(8) 115.9(4) Ni(l)-N(4)~N(3) 115.9(4) Ni (2 ) -N (6) -N ( 5) 117.3(4) Ni(l)-N('l)-C(]0) 118.2(5) Ni(2)-N(6)-C(20) 119.1(5) Ni(l)-N(10)-C(ll) 111.9(1.) Ni(2)-H(20)-C(21) 112.1(5) Ni(l)-N(10)-C(15) 128.9(5) Ni (2) -N (20) -C (25) 129.1(5) Ni(l)-C£(l)-Ni(2) 98.4(1) The estimated standard devjations are given in parentheses, 103 o m ^— ' 1 Q w 0) r-l Cn a < o w CO u ^ >1 o OJ eg O ^-^ -H nj ■— ' £••1 (V5 og • O g^ >i CM a ■d o m d o •d >i O -P w •H Q P I Q o C o -H < 4-» •H 03 o (fl I Q O CM W (N n O '■'■! »* 10 in ■<< n r~ en o vD >£) in vx) ^" -^ vr «^ m c» in "^r r^ in in cN r~ r-- oj 03 • • • ■ CM CM l o o o 000 ^J CO Q) -p Q) >■! ■rl r; > •H N N N >i III CM CM CM X \ \ \ rH H rH -U V ^ •. flj N >< >i ^■i + N H- N H- H CO CM I CM I CM CN -rl \ N CM \ CM \ \ rH I \. rH \ rH rH K V r-H ^ rH ■- - I ^ I O ^ •- I >i I >i I • I ' >i >i >i r-i CM >i >i ^ ^ CM •• CM :;-i CM >t XXX« f^ XXIIrHlrHXrHX U O O (U >H CM U ^ O >. _ _ . 1^ rHrH ^-. XlcMro "^a-coro^-.-— •----,rH ti --''-' '--^-~-'~-'(~^'H^-'—' • --'O r-l CM ,r^ ,>0«0— '— '^le^ C Q . --■- -.- ry CJU — UOU'^^^CJCJ (U • ••• «a<. ••••••••• o ,_,.. ,-^ u ,-»>-(. . O -^-^•^->— ~^-» .—^,-^13 CMP^--^--^ romin'-^---'-^'-^-- >i 2^-rHCM ffi ^agrHrHCMco-^ininvD K -^K^' — — ' ^^--v^^--^-'--' — ^^^.-^«_- I l^ll CJ llllllllll o CN rH rH rH -H OT in r-H rH C-J n v}* in lA VT C> ^^^v.^ ^ ^^^^^^^^■^-.-. p ^; 2 O O — ' 2; 23 O O O O O O O O 1) CO o ■rH .IJ rc! •H > -d na >-■ rj 4-) CO -d •H •4-1 Cfl 0) a> 104 ing and hydrogen bonding in Il2dhphpy (NO-^) 2* 2H2O and in [Ni2C£{Il20) 4 (dhphpy) )C£3-2H20 are presented in Figures 8 and 9. The most noticeable difference in the structures of the two dhphpy ligands is that H2dhphpy (NO-^) 2 * 2il20 contains a tv/ofold rotation axis while the nickel complex docs not. In both cases the ligand is approximately planar (see Table 30) . The nickel atoms and the bridging chloride of [hi.2Cl (II2O) ^- (dhphpy) ]Cf o • 2H2O lie slightly "below" the least-squares plane of the ligand (Plane 3) and both hydrazone portions are pivoted generally about an N(3)---N(5) axis witli both C(14) and C(24) "above" the plane. However, in the protonated li- gand one hydrazone is pivoted "upv,ard" and the other "down- v/ard" as required by the twofold axis. Also, the hydrazone "arm5'. " in the nickel complex are drawn tov^ard each other com- pared to the pro tone'! ted form as indicated by the bond angles within the "arms." All of tl.e pyridine ringn are rotated about tlje C(nO)-C(nl) bond relative to the phthala^ine plane with the pyridine nitrogen atoms tipped toward the coordina- ted species. In [Ni2C£ (lUO) . (dhphpy) JCZ^- 21I2O the pyridine containing N(10) is rotated to a much greater extent than that containing N(20). This is shov/n by tho deviations from plane 4 (Table 30) of N(10) and C(12), 0.121 and 0.222 A, compared to the deviations of N(20) and C(22), 0.148 and o 0.161 A. The rings of the phthalazine fragment in each com- pound appear twisted relative to each other but by less than 2". n:l 0) i-i o X! 0) td n r-\ OJ to oi 1 ' d r-l c ^ 0 1 1 I-I c » Q) IX o ^-i }^ c ' 'd fci ;-~i .<-! M «. 1 '0 >l a' V fj X o 4.J 0 nJ ^■1 04 w E^ O • -P ■d rci .a Q) CO 4-> M •M fO 0) 5 r-! H d 3 o :^ tn f^^! •H cd D3 Pr., CN 1 • rsj fv) \ ^-*. r■^ fo '• o >1 f'. B> s*-- Ix >) P-; 'd ^ c Pi Pi • ,fi w 'O N (1) i 0) e 1 r!^ fd H 0 j-i V. u en X X5 (0 •H -IJ >i nd Ai r^ fd U -P o a •-^ Qa'X^ ■•cJ C c < 1 Co •H 106 Ui •H I ^ O - u ... N N < - >s >1 + >> CM ^<;\ ■P - + to CN rH ^r> Pi M & = o — Ol (N ^d C --, fj ,i^ o >i - M a, N X) ,a I ^\^ -- -re) •^ >i 0) ^ + ■)-> O f^i fO i ■rA -^ ^ l>i u , -'d rt! IX o <: fo a. 108 E • o 109 o 0) -Q o m CM o ^ a. .c c •H (0 0) C! a &< u to I 4J W Oj T.5 0) C Q nJ •H <-7 «0 OJ n O >1 a 1:5 n l-l p-1 o -p < CD o <; CM r--; 0) C rH O ■P < CM rH Q) c rH o -p < I I f-J r 4c IT! Cj I in I I CO u rH ro CM I rH rH CN o V.0 i:> ro r-l I o ro I l-~ VD ID C) u u CO t 4; r- i f- . C "I u t_) r?.; r-~ rH rH '-D ^ •^ ^ o.; r-j r.; r-H ■y. •ji ■r< •!-• * * •Y * * o r- C-4 CO n IM V£) CO m o 1 1 1 rH 1 H C3^ >X) CNJ CN 1 lO i 1 CM 1 -1 H o r-< cn! ro '=? 1/1 c^i rH r-H r-! t-H rl iH r-l •— - --^ •^_.- % ^-^ ^-^ — • *^^ -j-^ 0 4: in 4: 4.- in vo 4: r^; I ro r~ VD CNl O ro -c' cvl r^T O rH rH CM CO rH r-H H •^ in o .-H r-^ i-H ?CC)UUUUOSO 110 en in ^a O + X (Q + X < TJ (U c 3 o C •H •H +> + • (0 C 3 0 U' o Qi 1 Q) c o (0 r<-) rH a Q) iH o JQ -r; ns 4J Eh iw O (0 4J C 0) •rH 0 •H *M U-l O 0 u o u ca 0) c .H 04 in VD o U5 VD iH r^ tH M- r~ "^i' CM "a- OO u:- •^' CO iH in o CO O O I o o I fvj (Nl • O • • >1 « • CM o o a o o K x: CM 04 « jS CM s ^^ ro ■<# O ^-^ 2 o CM >i M G4 .C «^ a U jC (0 n) c (d +J •1-1 e3- 2H2O is comple- ted by two v:ater molecules which lie on a line almost perpen- dicular to the llgand plane. The Ni-0 bond distances are 87 typical for water coordinated to nickel (11) ranging from 2.070(G) to 2.117(G) A. A degree of uncertainty exists concerning the poiitJ.ons of hydrogen atoms abouL 0(1) in Il2dl]phpy (NO^) 2 * 2H2O. The o 0(1) -n(l) distance appears to be very short, 0.78 A, while o the N(10)-H(py) distance appears to be very long, 1.21 A. Although the locations presented for the hydrogen atoms are the most reasonable interpretation of the difference map in terms of rcrk heights, distances, and M-O-H angles, other areas of positive density exist about the N(l), 0(1) , and N(10) positions. Disorder may exist with alternate forms ha- ving N(l) protonated or having a "coordinated hydronium ion." Complexes of dhph:y structurally provide a promising 113 uni-iuolecular system for the incorporation of a small mole- cule at a bridging position. Dinitrogen has been reported as a bridging ligand connecting two metal complexes in the y-dinitrogen-bis{ [1, 2-bis (dimethylphosphino) ethane] hydr ido- [q- (1/ 3, S-trimethylbenzene) jmolybdenum} cation ard similar 89 compounds. No complex has been reported which could retain its structural integrity after the removal of a bridging di- nitrogen. The structures presented here suggest complexes of ligands similar to dhphpy may have such a capacity. CHAPTPjR 6 MODELS OF PROPOSED INTERMEDIATES FOR THE CATALYZED CYPT T- ZATION OF ACETYLENES: THE CKYST/iL AND MOLECULAP STRUCTUPFq OF l-(Tr-CYCL0PENTADIENYL)-l-TRIPHi^NYLPII0SPIiINE-2 3 ^ ^^"-'^^^^ TETRAKIS{PENTAFLU0R0PHENYL)C0RALT0LE AND 1- (tt -CYCLOPFNTA DIENYL) -l-TRIPHENYLPIIOSPIJINE-2 ,3 , 4 , S-TETFJ^KIS (PENTAFLuiRO- PHENYL) RHODOLE The catalysis of tho oligornorization of acetylenes by tran.sition metal complexes has been extensively studied. ^^ A reaction mechanism involving a metallo-cyclopentadiene intermediate has been suggested^"^^ for the trimerization of two molecules of acetylene v^ith one of olefin in the pre- scencc of NiBr^Ctpp)^, Ni (CO) ^ (tpp) 3, and ether nicJ.el cat- alystF:. Metal-containing hererocycles, metallocycles, have been implicated^^" ^^"^^ as intermediates in the react: onr. of acetylenes v/ith Tr-cycIopentadienyJdicarbonyl-metal complexes in which the metal was cobalt, rhodium, or iridium. Yamazaki et_ea. on the bar.is of chemical reactions assigned a metallocyclic structure to a phosphine-containing cobalt complex isolated from the reaction of diphenylacetylene with Co(cp) (tpp)!^ and isopropylmagnesium bromide. They also isolated the same product from the reaction of excess diphenylacetylene with Co(cp) (tpp)^. A preliminary report of the structure of a cobaltacycle formed by the reaction of Co(cp) (tpp) (PhCiCCO^Me) with dimethyl maleate has been reported. 114 115 15 Rausch and Gastmger prepared C. (f ph) .Co (cp) (tpp) by the reaction of bis (pentafluorophenyl) acetylene with r-cyclo- pentadienylcarbonyltriphenylphosphinecobalt. The analogous rhodium compound was prepared by the reaction of the corre- 15 spending rhodium compound. 9 7 Except for one preliminary report no structural data have been available for cobaltacyclopentadiene metallocycles. Therefore, the X-ray diffraction stjrucLural analysis of C. (fpii) 4C0 (cp) (tpp) v/as undertaken. The corresponding rhoda- cycle was studied for comparison with this cobaltacycle and related compounds. Structure Solution emd Refinevaent for C4 (fph) 4Co"(cp) (tpp) ~ The heavy atom method was used in vjhich the positions of the cobalt and phosphorus atoip.s were estimated from a sharpened Patterson function. A Fourier synthesj.s based on these atoms v/as used to estimate the positions of eighteen additional atoms. Successive Fourier syntheses revealed the locations of all nonhydrogen atons in the c;ompound. A differ- (Bnce Fourier synthesis at that point revealed a region be- tween the cobaltacycles which v;as of relatively high electron density. Because this density v/as diffuse no additional ato- mic positions were estimated before starting refinement, R = 0.27. Three cycles of least-squares refinement with indivi- dual isotropic theriual parameters reduced R to O.l'l. A differ- ence Fourier synthesis again revealed relatively high eloc- 116 tron density in the same location as Lefore. Because of the discrepancy of the calculated density 3 3 (1.423 g/cm ) from the measured density (1.59 g/cm ), solvent molecules were presumed to be in the crystal. The deep red 14 crystals of the compound were grown from Skelly C which is a saturated hydrocarbon fraction boiling betv.'een 88 aiid 9 8°C and consisting mainly of n-heptane, ^-j^^i^' ^^ two solvent molecules were in the unit cell the calculated densiity would 3 be much nearer the measured value at 1.55 g/cm . Several maxima were observed in the difference Fourier synthesis v/ith- in the region of high electron density. The distances between these points and the angles made by lines connecting them did not reasonably approximate a hydrocrirbon chain. The thermal parameters were converted to their aniso- tropic equivalent and nine least-squares cycles using a block approximation to the matrix reduced R to 0.077. The sliifts of all parameters during the fineil cycle were less than one- tenth of their resi^cctivc estimated standard deviations. A difference Fourier synthesis calculated at this stage again suggested the presence of an ill-defined solvent molecule. Although the distribution of the peaks, which were not v;ell resolved, suggested a C-, oi' Cg chain, a closer examination of the distances and angles within the group shov.'cd them not to reasonably approximate a hydrocarbon chain. Six peaks were selected which closely retained their positions in the final ?'ourier summation before refinement and in the difference Fourier syntheses just discussed and 117 which seemed the most reasonable in approximately a hydrocar- bon chain. These locations were used isotropically as carbon atoms together with the seventy-three refined positions from the third full-matrix least-squares cycle used anisotropical- ly in a structure factor calculation and in three cycles of block approximation least-squares refinement. Although almost all the poorly matched reflections (|FqV)^ - ^Valc^'*^^^ ^^~ proved, a Fouiier synthesis revealed peaks at positions shif- ted to a less reasonable distribution from the linear hydro- carbon approximation used. The refinement was terminated at this point. An outline of the refinement is presented in TaDle 5. Scattering factors for cobalt, phosphorus, fluorine, 29 oxygon, and carbon v;cre taken from Hanson c t a ]. . A list of 14 observed and calculated structure factors is available. Structure Solution and Refi.neiuent for C4 { fph) 4lZh (cp) (tpp) The method of isomorphous replacement was used for the solution of the structure of C. (fph) ,Rh(cp) (tpp) . The cell constants of C^ (fph) .Co (cp) ( tpp) and C^ (fph) 4Rh(cp) (tpp) as reported in Table 4 are very similar with differences of less than one percent. The positional parameters from the third cycle of full-matrix least-squares refinement for trie non- hydrogen atoms in the isomorphous compound C. (fph) 4Co(cp) (tpp) were used in a structure factor calculation and a difference Fourier synthesis with the C^ (fph) ^P.h (cp) ( tpp) data. The structure factor calculation res\iltod in an R of 0.17 and the 118 difference Fourier synthesis revealed no major structural differences in the tv;o compounds. The same positional para- meters were used in an isotropic least-squares refinement of the C, (fph) ,Ill-i(cp) (tpp) data. A summary of further refinement is given in Table 5. A difference Fourier synthesis after refinement suggest- ed the presence of an ill-defined solvent molecule. As in the 3 case of the" cobaltacycle the calculated density, 1.47S g/cm , 3 is significantly less than the density of 1.60 g/cm obtained from flotation measurements of the yellow crystals. If two molecules of n-heptane are assumed within the unit cell the 3 calculated density v;ould be 1.60 g/cm . An attempt to fit a linear molecule to peaks in the difference Fourier synthesis was also unsuccessful and was not pursued. The scattering factors used v.-ero taken from Hanrion 29 et al. Tlic observed and calculated structures are listed m Table B-5. Results and Discussion for C4{fph) ^Co(cp) (tpp) and C4 (f ph) 4Rh (cp) (tpp) The. final positional and thermal parameters for the. nonhydrogen atoms of both C. (f ph) .Co{cp) (tpp) and C^(fph)^- Rl-i(cp) (tpp) are listed in Table 31. The atonic numbering and thermal ellipsoids of the cobaltacycle are shown in Figure 10. The atomic numbering of the rhodacycle is analogous. Selected bond distances and angles for the two compounds are listed 119 1 ^^ x; a, IW — ' -—- H ---^ ^-^ ^-^ , — ^ , ^ .^-^ , ^ — . - — - — * .— ^ '3< ^^ ^-- .-~. ^^ ^~- .-^ .^ — ~ ^— ^ ^-~ ^-^ o o O rH r»-) •^" •a- LO r-\ ro rH rH u M rH Oi cr\ cr> cr> O^ Ci^ r-{ rH rH rH rH rH rH rH r-i r-l rH rH •d ro VD "C (N MD vo CO rH r— 1 o cv; \0 IX) r- r- (t CQ rH r-i r-i rH a ^--v ---^ .^-^ ^-^ ^_^ *--^ ---^ ^ ^_^ _ _ __ ^^ ^-^ a, ^-^ .—^ o o o o O —v ,-^ ^-^ rH rH ^■^ CN "J.^ "^ r- c;) ■* U5 00 ro 4J r-f rH rH ^ rH rH r-H a> C\ Ci rH rH rH rH rH rH r-l r-H rH rH rH rH , ^ O") CN Cl CM <0 rH r-i CO ■^ in I-- O CM in LO Cl o r- CM r- r>i r-. -"^ a. rH m ^^ .^ — , ,—s. ,-, f s ^-^ ^-» . — ^ , . ^-^ '^a > y— , in \D Ko m LT) in in in V£) l£> i£) r- r-i i-H CN C^j O C5 CO C?l *— ^ • (N rH rH rH rH rH r-) rH rH H rH r-i r-! rH C< CN r-i c-j CM C ! rH r-i x: w ---^ v-^ *-* ^. — -w^ N * ^ v^ » * — ' '-^ ^-- ^ — — ' — > — ' — - — ' a, 0 rM in <:J' O I-- in P"-) «^' VD CN) r- C5 '3' KO si' ■^'' m in iH V.O rH O CTl H-t tfl rH in LO r~ r^ CTi »^ 00 VD in in 00 CO r-~ 00 00 rH r-/ ro rH CO r-i O — 0) CQ .H rH rH rH rH r-l rH 'jj*^ U -P c C Q) . — ^^ ^-^ .^ . — . -— -—. , — ,— . ^~. ^-^ ^-, ^, ,-, , — , ^-», »— , .—, .— . — . ^-, , (0 o o fO 00 ro fO ro ro ro CO -^i- "* «r; ^ in in in r- LO vr> ■53" in cn •=j' in r- vo VD V£> r-~ vrs o-i vri CO r~ C^ CN rH V£> cc CO r~- 1-- ro >--3< g o rs) f\! 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O rH CM C^ icj in rH r-{ CO CO r-l rH rH rH r^ r~- rH rH rH r-< o o rH rH r^ r- rH CO rH 00 t~- r- CM •^ CO CO r-< ro CO CO O rH M* 'S- r- Csl in CM 02 ^i" ^_— • CO V.O CO in CO r- VD C3> o> o o VC' lO rH CM CO CO o en CM C^l CM rH r~- VO o CO CM rvj CM CM rH rH r-\ rH r— 1 rH rH rH r-l r-^ r-i CvJ CM 1 ; H 1 — ! in VO vr «=?• CO CO in m VO VO r- r~- r- r- r- r- VO VD OT CO "--f •^ m VO in m CM VO 'S' •^r C7\ CM r-i o CM CM o LO o ■=r CD 00 CO rH "^ C3^ r-^ "^ r~ ■^ r- r- r^ CM CM '3" CM ro o r-{ CTi o CO o Ol CO CO ^ r-{ C>1 in in 00 01 CM ■vO in VO CI c^ ,-{ •-{ CO CO r-- r^ a> o r- 00 CO CO o o CM CM ^ »* rH ,-\ in ir> 1 1 rH r-\ r-t o o rH o r-i O Cs! 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N 00 00 c— I CT* o o ro 'T m "^ cr\ i-H r~- r^ vd vd CM IT) f-{ o r- r^ vD in in r^ OS in O i-{ in n CTl rH in in CM in in v£) 00 00 cH rH rH r-. in t— in T rH o rH rH r-\ rH vr in •-t r-l in V.O n P-) O rH rH t-A ^^ O rH r- r~ rH r-l rH rH CTl CT\ VD in VD VD CO r- VD in o in in •<3' r~t -^ VD CD 00 o r- VD CTv VD O CM O CTl rH rH vf o. en CN m r- vo O) (N rH -ta* o> o rH CO iTi in CM r^ in CO n vf ■^ n ro ro n vr lo VD VD ■^ ^ en ro ro ro ca f^j f>j VD in r-i r-i rH r-H CO r^ •-■{ r-i r-i CM CM CN O rH CM CM 00 CO in VD rH rH rH rH in VD rH rH 1-1 rH NJ- in •-t CM >-i .H ir, r~. CM OJ in VD •^' CO O 00 o t-- If; ir, iH rH O CO •^ r-i in LO ■>^' CM in t-- a-k VD CT^ cri CM IN LO CM IT) r^ r-H r-i Ki rH CO ro '* cn ro o rH «;i' CO r» ro ro r^ r- 01 CO CT> CTi rH rH CM ro r-i rH h.^ s.»^ «^-^ V—' ^^-^ •k.^ •..-^ v_^ ^^ ^_^ *^^ v,-' — ^ •*--■ ^—^ o CM f- OJ in CnI o ro o>\ CO 01 rH CT> •;r CO ro o r- rvi iri VD CO r-l ro "^ ro in ro u 1 CM lO LO r-i r-i r^ r- o^ 00 o rH iH rH r- CTi r^ 00 VD r^ rH O rH r-l LP VD rH cn CTi CO r- o% en CM ro rH rH r-\ ^ , ,_^ ^^^ _ ^^.^ ^..^ ^_^ ^^^ ^_^ -— ^ _^_^ _ _ _ _ f) . — ^-^ o c-i rH rH ^r in ^^ ■y -H rH rH r-H rH rH r-1 rH r-l ,— J r- r-- r-< rH l-i r-H cr> cn VD VD iH rH o — - V-' ■ ■— ' ■— --^ ^' • — • ^-- *■— ' ■— r-\ rH VD r~- r-i o r- CO r- o ro -a- in r^O CC ■M" en r-- ro 00 VD 'X) CM ■<^ o o CO ro M rH o c> as CO o cr> ro in ^ 'S' o O r~- cn CM CM (— 1 C^ O"! ro VD VD o o VD VO Eh CQ rH rH rH H c-H rH rH rH rH rH rH CM rH CM rvj rH rH r-( rH ro ■«j' in in in VD VD r- r- r~ VD VD in VD CO ro •^ LO in LTi •^ ^ ro ro VD VD ro O CM vr CM O o% C^^ en CM in 00 CTi CM CO LO VD "=r CTv CN CM in in in en "C' rsi ro r- in CO r- t- 'O' VD in "^ rH rj CM r- CO 00 VD VD 00 ro en rH o VD CM CTi a\ o o ^ -a- in tn o; CM 00 CO r-- :- r-- r^ cn a> r-^ ro in ■3' ro r^( en o^ N CnJ cm CM rg •~i rH fH rH rsj CM CM CM C\J CM CM CM ro ro PT ro rH rH vovD cijco coc^ cnrH enrH oo<7> c»co mm vcr^ <^ \s> mm mLO >-h rH rom rHcTv coro rocn oor^ com vd'S' oo^ CMm ^ro vdoo cMm cM's- ^vD -"a-o r--rH r^vo vC'-h vdco mvD t^co ooco vDr~ mm c\ a\ cMt~* rHo CN^ ^ rH vovo ^o r^m cocM or^ rom vDm r^vD vorH men \o cy\ r^t~~ vOrH rHco '3'ro r~o coo t~~co vdo "^rH «:rcn r-vr mm cNr^j ^"r r^r^ oor- vdvd ro^ ro^ o^co oo r^r- cmcm ^vd mmrvjcMrHrHrHrHCMCMrorororo roro'^r^^'^'rHrH I I e. VD rH o r-) vr -p — — < fci U u O OJ PH r-) LO •<3* U 123 rH rH rH o rH rH rH CM rH H r-i rH rH o rH o rH CM rH m r-i CM in rH in o rH CVl ro in ro in CM CO r-l rH rH rH rH rH rH rH rH n n o rH rH -1' -H r-l CO 00 O CM CM CM rn CNJ iXi rH rH r-l o r-H CM rH CM rH in IX) o r-H rH CNJ O rH U5 rH CTi 00 00 m CN in 1- CO 00 00 r-H r-\ CN] rH rH CO rH CN O VD C?i rH O rH CO cn; rH o CO IX) n CO IX) o in v£> "* LO "sr rr '=1' '^ in ^ "^J- •^ in in 1^ t-- oo ricM cocTi coo rHO f^-r- cTiO rHCN in-^' vDr~- unco corn vor-^ cr\rH >■^ rH rH rH rH rH , H rH r-{ rH r-{ rH rH i-H r-\ r~\ rH Cj rH CM r-! r-i rH r-H O .~~ -^^ O O OT 'qT in I^ r~ CO O O UO in rH o ro (■'• rH r-l rH rH rH rH r-i rH CO OO rH rH .-H rH rH r-i rH rH CM C\l rH r ! rH rH rH --i 'J' VX3 CTi (-^ CO rH r^ r-l CM rH r^ CM ix> ixi oo ovj o CT\ vx) CO ix> m oo ro o rH KO ixj in o co in r^i oi r^ oo rH *-H rH rH rH rH rH C^ rH rH t-{ rH rH vDf^ ix5r-~ invD vDVD rHrH invx) vjD[-. cooj CO 01 CO r-l r-- r-~ in l^ ix> ix> iXj O vX.ro rH [^ 1^ LO CN] oo UO 01 vO CM CO OJ C^l r- oo rH 01 CM «* O Ki^ r-l ix>in rHco rH -^ cMin ix5c3i inix) ocm vx'ixj com ooo r-in m aoo r~r-~ rHO C31C0 ^^n -^-^ cooo vioco o c mro ■^'O' rH rH cmcm cio r H rH rH rH rH rH CO Ol 00 OO OO 00 Ti' --:' V3< rj- •^ ■^J' "^r "^ '^j" ■=3' "3' in '-^rH ^-^O .— O ^—O ^-,— . — ^— » oo rHCM CN-y CN'^ Or-I ^-^,— , — ,0 OlrH G1.-H COrH OlrH CMCM C0C31 rH rH rHrH rH r-H rH rH rHrH 0000 CTlrH CT^OT vx)co ID ^ rvio inoo cmo incji ix^r^ \o rH mix? ooo oo'=r "=ro Of) CMOi cjiro oor-- oco r~oo r^oi cicti <3ir~. r^*^" r~-'=i* mco ooo r- IX> 00 rH rH O r-l Oi CM CM CT'. C!1 00 00 UO UO OT OO "^ «;::' r^ r- ** "^ r^ r-- ooro oom ';f"cr in Kt ix>ix> inuo ■>*%}• vt'^ mm ix)ix> vdi^ vduj ixjvxi -~-0 OO --,0 --. — ^ ^-^ .—. ^-^ <-~ C:i rH CMOO CMM" ■^Ifi rH C\i --,^-^ Or-I Ol rH r-l rH CT\ rH Cl 01 CM CM Cl CTl .—trH r-H r-i r-i rH rH r—. rH rH 01 01 rH rH OCM iX)(0 OlrH mci rHOO "vl'CO »T\ IX) IX) r- r- -— ' v.-* ^— ' ^— ' ■w - *.^ >--' •^ ' CJ u u U u u u o 124 r-l ■^ ^ r-l in rH rH o o fH O r-H r-l rH rH rH rH rH r-l .H CO in ^ rH rH QQ O VD o r- CO r^ in in rH rH rH ■H rH r-1 rH rH rH rH rH rH (N iH 1"^ CN rH in rH in r-^ rH rH m .H in rH fS CM rH rH ca (N ID CM o CNJ CN in I^ r- in VD o iH •J' cr. c-, ,H o o r-1 rH rH CO CO ^ IT) in CN (N 0-) O fN CM rH 1^ rH rH .H CO Cf\ rH rH rH CM rH CM rH O') CM n O CN m O r-l iH .H o CO in CO in a\ >X) vo ro m •0 CQ (U 3 d •H 4J f:; 0 .H r-l r-l rH rH r-\ r-' r I r-l rH CN in CO o VD 00 in rA r- m ct rH cv -i ci co •^ rH m rH Cv; ';}< r^J rO rH rH CO O^ V-- 0~> Cy\ Cr\ r-S C> Ci m CO cr\ oo co rH rH rH r-l rH rH iH ^1 ^ -^ -J" ro ■<3' O iH rH rH CN! ro -^ in m vo -^ i^i CN CN rHrH rHrH r-i r-i rHrH rHrH rHrH rHrH rHrH r-irH r-HrH r-l ro PT VD CN CTi VD c?> rH r-l cr, r~- '^' O fo CO r-- rn n vd CN CNJ rH rH O O I-- t^ O CTl O r-l '3' VO T m I > rO rH O rHrHrHrHrHrH rH rHr^.Hr^rHrHr-^r^rH^H vor-« r^r^ vor^ vovo inin vdvd r>r- r-co r-r~- vdvd •^' in CO 'v in (N f^T in co ^ vr.> in o o ^ oi vd oo co co '^ if) r-i ■^' •>^' r-- o^ r^i m ■^ CN r>i «;r cn in cn in ro ■^ in mm ro m mm ct> o C"-» r~- cn cn 'a* 'r iH r-i vd vo "a* ^ mm mm ^^" ri^y m cn roro r<) m -^vr "si'^^a* vT'* OCN OrH OrH --.,— -^-- ,-,,-^ oo oo — «0 — ~-- rHrH rHrH rHrH COCA COCO COCTl rHrH rHrH a\ f-\ C^CTl ^CN rHO m'J' CNCO VDrH OOm CN'^' ^T C^l OOrH ^'r- 00 o n r~ vo o ■«3' vo co o> m -"j" cn cti r-i o r-4 cs t^ o^ CO cTi r- c- "^ m 01 ro r-- r~ c. c^ r-i o t-{ r-i o. cr> r- r~ <^ KD '^o '^ vDvo vDvD r~-t~» t-r-- c. a^ 00 a^o^ coco r-( r-l rH(N rHCN OrH ^-~^> ^^,-, —O rHCv) rHfO rHCN C,-«0 rH rH rH rH rH rH <5> CTl C7N 0> CTl rH rH rH rH rH rH rH rH r-l CO m VD rH o^ •<3''3'mmmmmrorHrH r-irHCN(NmrocNCN U f 1 U '3' m o 00 CX) U oc CO CJ CO O m CO Li e o 4J (0 4-1 (U r. 0) -p «4H o Vl (U M O c ■H 'O 0 -p in -H o >i ca 0) Sh n -p o Vh -p w x: u UH o cn ■P c •H Tl O o o 0) (0 ca Ti B u 4J d 0) •H 0) 4J -P •iH o (i) > to C 5^ O X! ^ in +J -P O u o 0/ o d d (& 'J 4J Q) o m 00 D^ — d U •H M "-d d t-i (ti fci o u 0) ^ ^ o 0 o a) y^ '■ ,d — ■p -a* a o 0 -- . - x; o XI w -P a, trs w «n d "> r^i — -H >i o x; 1T3 o ^ -^ d -d w u n -d w Eh a; o c "d o to r-i O 0) . -d d o x: -p •H 126 127 in Tables 32 and 33. Least-squares planes and deviations are given in Table 34. The molecules are metallocycles with the metal atom also bonded to the cyc]opentadienyl ring and to the triphenylphos- phine ligand. The C(l) to C{4) fragment in both compounds is planar with the largest deviation from the best plane being 0.015 A in the cobalt compound and 0.017 A m the rhodium compound. The metal atoms, however, are significantly dis- placed from the plane in the direction of the cp ring by -0.203 and -0.239 A. This perpendicular displacement is simi- 9 8 lar to that found in other similar metallocycles. The metallocycles may be considered as a dolocalized diena with the metal atom a-bonded to the two carbon atoms of the ring, C(l) and C(4). The Co-C bond distances, 1.995 (11) and 1.993(11) A, and the Rh-C bond distances, 2.060(12) and 2.067(11) A, are similar to various values given by Churchill. ^^ Values of 1.979(1) A"''^ and 1.990(5) A^ have more recently been reported for Co~C bonds in ccbaloxime complexes. Mague '■^"'^'^ has reported structures of similar rhodacyles in which the Rh-C distances are 2.000(11), 1.964 (11), 2.047(16), and 1.998(16) A. Also, Cotton and Norman o report a singi.e-bcnd covalent radius of 1.39 A for Rh(ITI). When this value is added to half the 1.485 A suggested length for a single-bond between sp carbon atoms the Rh-C dis- o tance is predicted to be 2.13 A. The observed Rh-C distances where rhodiuj.i has a formal oxidation number of ^•l are shorter than r.he abc/e prodicted single-bond distance. T'ais iliffer- 128 Talkie 32 Selected Bond Distances (A) of C^ (f ph)^M(cp)(tpp) (M=Co,Rh) with Their Estimated Standard Deviations in Parentheses. M = Co Rh M-C(l) 1.995(11) 2.060(12) M-C(4) 1.993(11) 2.067(11) H-P 2.234(3) 2.293(2) M-C(51) 2.157(12) 2.286(13) M-C(52) 2.121(13) 2.261(14) M-C(53) 2.119(11) 2.250(13) M-C(54) 2.104(9) 2.238(10) M-C(55) 2.133(12) 2.268(12) C(l)-C(2) 1.326(15) 1.343(16) C(2)-C(3) 1.467(16) 1.457(16) C(3)-C(4) 1.335(15) • 1.354(15) C(l)-C(ll) 1.487(16) 1.498(17) C(2)-C(21) 1.523(16) 1.497(16) C(3)-C(31) 1.481(15) 1.478(16) C(4)-C(41) 1.493(16) 1.492(17) P-C(60) 1.848(11) 1.858(12) P-C(70) 1.843(11) 1.821(10) P-C(80) 1.834(12) 1.820(13) C(51)-C(52) 1.463(20) 1.429(22) C(52)-C(53) 1.400(15) 1.420(17) C(53)-C(54) 1.426(18) 1.424(20) C(54)-C(55) 1.433(16) 1.422(17) C(55)-C(51) 1.457(17) 1.431(18) 129 Table 33 Selected Bond Angles (°) of C4 (fph) 4M (cp) (tpp) with Their Estimated Standard Deviations Given in Parentheses. (M=Co,Rh) M = Co Rh M-C(l)-C(2) 112.1(8) 115.5(8) C(l)-C(2)-C(3) 116.8(9) 114.9(9) C(2)-C(3)-C(4) 114.8(9) 115.5(9) M-C(4)-C(3) 113.1(7) 114,8(8) C(l)-M-C(4) 82.4(4) 78.3(4) P-M-C(l) 103.0(3) 101.6(3) P-M-C(4) 95.2(3) 93.3(3) C(ll)-C(l)-M 127.0(7) 123.3(8) C(ll)-C(l)-C(2) 119.6(9) 119.4(10) C(21)-C(2)-C(l) 123.9(9) 124.1(10) C(21)-C(2)-C(3) 119.2(9) 120.9(9) C(31)-C(3)-C(2) 119.7(9) 119.7(9) C(31)-C(3)-C(4) 125.5(5) 124.9(10) C(41)-C(4)-C(3) 119.8(9) 120.3(9) C(41)-C(4)-M 127.0(7) 124.9(7) C(51)-C(52)-C(53) 108.1(11) 108.3(12) C(52)-C(53)-C(54) 109.6(10) 108.8(11) C(53)-C(54)-C(55) 107.7(10) 106.9(11) C(54)-C(55)-C(51) 108.0(10) 109.3(11) C(55)-C(51)-C(52) 106.3(10) 106.8(11) 130 Table 34 Deviations from and Equations of Some Lease-Squares Planes of C4(fph)^Co{cp) (tpp) and C^ (fph) ^Rh (cp) (tpp) .^ ° +3 (a) Deviations {h x 10 ) Atom Plane 1 Plane 2 Plane 3 Plane 4 Co -203 1741 Rh -239 1908 C(l) 8* 9* C(2) -15* -17* C(3) 14* 17* C(4) -8* -9* C(51) -931 -1053 -7* 2* C{b2) -1211 -1307 15* 6* C(j3) -2043 -2168 -16* -12* C(54) -2265 -2437 11* 13* C(55) -1598 -1774 -2* -9* P 1884 1922 3025 3241 59 (b) Coefficients of the Plane AX + BY + CZ = D Plane A B C D 1 0.2201 0.0G27 0.9735 3.2807 2 0.2193 0.0672 0.9733 3.3160 3 0.7356 0.1345 0.6639 -0.8420 4 0.7474 0.1591 0.6450 -1.0481 ^The entries marked with an asterisk were used to define the plane. 131 ence could be indicative of multiple bonding between the ter- minal carbon atoms of the diene and the metal atom. The C-C distances in the metallocycle rings fall into tv/o groups. The C(l)-C(2) and C(3)-C(4) distances are equal within experimen- tal error to the accepted value of 1.337(6) h for a simple C-C double bond. The C(2)-C(3) distances are indicative of a C-C single bond between tv.-o double bonds. The observa- tions of Mague ' on tvi/o rhodacycles suggested a double- bond system similar to those in C^ (fph) ^Co (cp) (tpp) and C^ (fph)4Rh(cp) (tpp) . The cp rings in the compounds arc planar v;ith the maxi- mum deviations from the least-squares planes of -0.016 o and -0.012 A. The distances from the cp ring atoms to the metal atom shov/ that the metal atom is slightly displaced from the center of the cp ring. The range of the Co-C(cp ring) distances is from 2.104(9) to 2.157(12) A v;ith a mean of 2.127 o (9) A. These values are similar to those in other Co-cp complexes. ^05,106 In both the cobalt and rhodium compounds the longest metal-C(cp ring) distance involves C(51), the carbon atom nearest the phosphine ligand. The mean Rh-C(cp ring) distance o is 2.286(13) A. This value is equivalent to the mean distance of 2.246(9) A in Rh (C2F5) (cp) I (CO) "^^"^ and falls within the o 2.19 to 2.26 A range reported for corresponding mean values for other cp- rhodium complexes. The C--C bond distances v/ithin the cp rings range from 1.400(16) to 1.463(20) A with a mean of 1.436(11) A in the 132 cobalt, compound and a range from 1.420(17) to 1.431(18) A o with a mean of 1.4 25 A in the rhodium compound. These C-C distances are comparable to those found in other cp com- plexes. ' The cp rings are tipped relative to the C(l) to C(4) planes by 35.3^ and 36.6°. o The Co-P distance of 2.234(3) A is similar to the Co-P distance in five-coordinate complexes of cobalt where the no ^ range is reported " to be from 2.152(G) to 2.27(1) A. Also, in cobalt-carbonyl complexes such as Co^ (CO) •■ « (Ph2PCiCCB'2) 2 and Co(CO) -;,(N0) (tpp) the Co-P distances are 2,236 and 2.229 A-'--'--' Jn the former and 2.224(3) and 2.230(3) A-*"""-^ in the lat- ter. The Rli-P distance of 2.293(3) A is similar to those in 113 phosphine complexes of rhodiura(I) . ' The metal to phosphine distance in metal-oxime complexes have been found to be some- 40 97 v/hat longer, ' The Co-P distance in cobaloximc complexes has been reported as 2.327(4) h^^ and 2.339(1) A.^^ The PJi-P ° 102 distance in RliC-£loxes in both cobalt and rhodium are equivalent, the phosphorus atom may be in the position of closest approach to the metal atom as limited by the steric constraints of the oxime ligands. The distances in the fph rings have been summarized in Table 35. The individual values for the distances and angles in the fph rings on the metallocycles and the phenyl rings of the phosphides are given in Tables 36-38. The dimensions are not unusual and are in agreement with expected values. 133 -p D4 o< -G Cu w m 0) — u •^ c: o ro -p r. (T. ■H •H Q W • Q^^ u 3 .C 1 0 « u M - O O ,,-, U Xi .H II ' — >lS c — (U x: w 04 C) ^ 0 ^ E-f -P ffl C Oi 0 CL4 C •H Q) j:: C ^--. -P q; o<; > ^-' U tH o o O"! IW o (t u Cfi Cfi c: 0 C fn; o o 4-) c: -H w (0 4J •i-i +J fO p U) -H •M > fc4 D OJ 1 Q u CJ 1 'O ^-N U U (C (^ — Tl 'O c c rt (C 4-> I u -d flj W < w O U m ^ CTi VD r-- n rH in M r~- r~ r~ r- r~ ■ • ro ro JC c::^ CO m ID 00 00 CO 00 CO O fN ro ro rr o r- un V£) •^ M* ^ 'a* '^ on • m • • • 00 •^ CM in O CO •<* •^ «* ^ "^r ro ro ro 00 00 II s tn C •H eH fN ro ■"S- « a> Di C' cr> rH c C r* C rH •H ■rH •-H •r-l < cc Di a1 C^ c o •H •PCN rO\ 3.H CT* .— (U ^ (1) I -p ^ tn \. -H ^^ d I •H 0) -^ 4J rH (d CWll e -H +J tn II 1) -l (U is c o •H -p fO > •o "O v^ n) 13 C (0 4-) CO 134 Table 36 Bond Distances and Bond Angles of Pentaf luorophenyl Groups in C^ (fph)^Rh(cp) (tpp) . o (a) Distances (A) n = 1 2 3 4 Cnl-Cn2 1.384(15) 1.342(16) 1.392(15) 1.385(15) Cn2-Cn3 1.364(20) 1.400(20) 1.374(20) 1.351(20) Cn3-Cn4 1.375(18) 1.358(18) 1.357(19) 1.389(18) Cn4-Cn5 1.367(19) 1.365(20) 1.368(18) 1.355(19) Cn5-Cn6 X. 372(20) 1.373(19) 1.367(18) 1.362(19) CnC-Cnl 1.393(15) 1.389(14) 1.389(16) 1.386(14) Cn2-Fn2 1.347(12) 1.354(12) 1.351(13) 1.344(12) Cn3-Fn3 1.339(15) 1.341(18) 1.349(15) 1.348(16) Cn4-Fn4 1.338(18) 1.337(19) 1.335(18) 1.340(18) Cn5-Fn5 1.343(15) 1.358(14) 1.338(15) 1.357(14) Cn6-Fn6 1.331(13) 1.343(14) 1.351(13) 1.342(13) (b) Angles (°) Cnl-Cn2-Cn3 123.1(11) 122.4(12) 123.7(11) 122.9(11) Cn2-Cn3-Cn4 119.6(13) 119.3(13) 113.8(13) 120.2(13) Cn3-Cn4-Cn5 119.6(13) 119.3(14) 120.8(13) 117.9(13) Cn4-Cn5-Cn6 119.8(13) 120.6(13) 119.0(12) 121.4(12) Cn5-Cn6-Cnl 122.6(12) 121.1(11) 123.6(11) 122.0(11) Cn6-Cnl-Cn2 115.3(11) 117.3(11) 114.1(10) 115.4(10) Cn -Cnl-Cn2 124.2(10) 123.9(10) 123.1(10) 124.1(10) Cn -Cnl-Cn6 120.5(10) 118.8(10) 122.5(10) 120.5(10) Fn2-Cn2-Cnl 120.2(10) 121.3(11) 118.2(10) 119.4(10) Fn2-Cn2-Cn3 116.7(11) 116.4(11) 118.0(11) 117.7(11) Fn3-Cn3-Cn2 120.9(12) 120.7(13) 120.3(12) 120.8(12) Fn3-Cn3-Cn4 119.5(12) 120.0(13) 120.9(12) 119.0(12) Fn4-Cn4-Cn3 120.7(13) 121.3(14) 119.9(13) 119.9(12) Fn4-Cn4-Cn5 119.7(13) 119.4(13) 119.3(13) 122.1(13) Fn5-Cn5-Cn4 120.9(13) 120.1(13) 119.6(12) 118.8(12) 135 Table 36 - continued n = 1 2 3 Fn6-Cn6-Cn5 115.7(10) 118.3(11) 117.6(10) 117.2(9) Fn6-Cn6-Cnl 120.4(10) 118.8(10) 118.5(10) 119.7(9) 136 Table 37 Bond Distances and Bond Angles of Pentaf luorophenyl Groups in C^{fph)^Co(cp) (tpp) . e (a) Distances (A) n = 1 2 3 4 Cnl-Cn2 1.387(14) 1.372(16) 1.394(14) 1.403(15) Cn2-Cn3 1.388(19) 1.368(20) 1.398(19) 1.358(19) Cn3-Cn4 1.387(17) 1.374(18) 1.370(18) 1.348(16) Cn4-Cn5 1.382(17) 1.374(20) 1.372(18) 1.370(17) Cn5-CnC 1.382(18) 1.363(13) 1.362(18) 1.384(17) CnG-Cnl 1.385(14) 1.389(14) 1.408(15) 1.367(14) Cn2-Fn2 1.322(11) 1.341(12) 1.339(13) 1.358(11) Cn3-rn3 1.350(14) 1.338(17) 1.339(14) 1.338(14) Cn4-Fn4 1.360(17) 1.339(19) 1.334(17) 1.335(16) Cn5-Fn5 1.336(13) 1.354(13) 1.330(14) 1.361(13) Cn6-Fn6 1.341(12) 1.355(13) 1.356(12) 1.348(12) (b) Angles (°) Cnl-Cn2-Cn3 122.4(11) 122.9(12) 123.4(11) 122.6(10) Cn2-Cn3"Cn4 119.7(12) 119.2(13) 118.9(12) 120.5(12) Cn3-Cn4-Cn5 119.6(12) 120.1(14) 120.2(13) 118.7(12) Cn4-Cn5-Cn6 118.7(12) 119.0(12) 119.8(12) 120.4(11) Cn5-Cn6-Cnl 123.9(11) 122.9(11) 123.8(11) 123.0(10) Cn6-Cnl-Cn2 115.6(10) 116.0(10) 113.9(10) 114.5(10) Cn -Cnl-Cn2 123.3(10) 123.8(10) 122.9(9) 124.2(9) Cn -Cnl-Cn6 121.0(10) 120.2(10) 123.0(9) 121.3(9) Fn2-Cn2-Cnl 121.4(10) 120.5(10) 119.1(10) 119.8(9) Fn2-Cp2-Cn3 116.2(10) 116.6(11) 117.5(10) 117.7(10) Fn3-Cn3-Cn3 120.4(11) 122,0(13) 119.9(11) 119.1(11) Fn3-Cn3-Cn4 119.9(11) 118.8(13) 121.2(12) 120.4(11) Fn4-Cn4-Cn3 120.0(12) 121.2(13) 118.9(12) 120.1(11) Fn4-Cn4-Cn5 120.4(12) 113.7(13) 120.9(12) 121.2(11) Fn5-Cn5-Cn4 119.7(11) 120.5(12) 119.9(12) 119.8(11) Fn5-Cn5-Cn6 121.6(11) 120.5(12) 120.3(11) 119.8(10) Table 37 - continued n = 1 2 3 137 Fn5-Cn5-Cn6 119.4 (12) 119.3(12) 121.4(12) 119.8(11) Fn6-Cn6-Cn5 117.7(11) 115.0(1.1) 117.6(11) 117.9(10) Fn6-Cn6-Cnl 119.7(11) 119.9(10) 118.9(10) 120.1(10) 138 a D4 o <4-l U C •H ■H ^^ CO x: fo Cu CO i C (U J^ •H u O W at en c < C O m 'd c en o c (0 -p (A a 'd c o CO 0) o (0 4J CO •H D (0 r-- Pi vr> O x: o u ^ « o u 11 fO ^X) o (Ti iH iH in rH iH CM iH CN CM iH O in CO ro U3 O -a- CM cr> •H CM r-i iH m rH CM iH rH in CO 0 in CM 0 fH rH CO CM CN rH CM rH en tH rH 00 CN CN rH 0 CM rH •H rH CM vo cy> r- cr> a\ "tt rH rH r-{ rH fH rH rH "^r CM r-l n 01 r-t rH rH CM CTi rH CO • '4' • • •^ • CO • •^ <--i CO CO rH rH CM rH CM CN rH r-i 0 rH CO CO in r- r- CO n CTi CO rH r-< CM rH r-{ 0 CN 00 rH rH 0 CM ,-H 0 CN r-i CT> rH rH 0 vr rH 00 00 D CO • • • m '3' • ■0 • • m r-^ rH rH in CO ro 00 CM (^ ^. ^-^ CM -"^r ^ CTi CO rH rH rH rH Cr» O O O CO rH CM r^ CM fvj CM rH CM rH rH rH r-4 rH rH rH r-l •■a* r- cr. r- VX) .1— ^ vn r-{ r-\ rH rH i-i r-i r-l fl rH '^ *-- ^~^ ' — ' ^ — CO 0 CM ^>^ v^ r- r- in 0 00 r- C7. VT) i-- CO • '3' f CO ro fO • fO • r-\ en 0 CM in ro CO l-i rH cr> 0 0 cr» 0 rH CM ,-{ r-i .H (N CM rH f-J tr. rH r-i rH .-1 rH rH rH rH C < C7N 0 rH fO rl in r-i rH rH rH * CM r 1 r> CM 00 00 -.r rH iH CN CM rH 0 CM r-i rH rH r-'. r-{ rH CM rH CO rH rH 0 CM rH 00 j r-{ <-l r-i rH r-{ rH rH O Pi rH iH ^^ ■■d 0) 3 c •M 4J f1 o u 1 1 CO ro *—*» *■— *• -^^ in in in d' -—^ ■^— ' ^-^^ iH r- cr» o ^ • • • nJ CM o ro H 0 O o o u iH rH rH II o o o r^ 00 03 «..>' ■*— ' >— ' 1 1 1 1 ex. 1 1 1 1 a, i ., — . .0"^ - — . c o o VXI V£> r~ u u u 140 The fluorinated mctallocycles resist thermal decomposi- tion better than the hydrocarbon analogs. ' Enhanced ther- mal stabilities have been observed in other highly fluorina- 114 ted metallocycles relative to their hydrocarbon analogs. In the compounds of this study the triphenylphosphine ligand and the four fph rings provide an effective shield for the two double bonds in the metallocycles. Although the fluorine atoms of the fph rings and the phenyl rings of the tpp were omitted from Figure 10, the sterically hindered nature of the metallocycle may easily be seen. The lack of a convenient path for an attacking acetylene together v/ith the enhanced thermal stability of the fluorinated derivatives may have allowed the isolation of these intermediate metallocycles. Metallocycles of cobalt and rhodium of the type presented are reasonable intermediates in the catalyzed oligomerization of acetylenes. CHAPTER 7 CONCLUDING REMARKS The structure of C^Co (H2dmg) (drag) (clan) shows the same LIPS phenomenon as c£ Co (H^dtag) (dmg) (sulfa) /'^ These two com- pounds exhibit the unusual feature of containing both neutral and dianionic dimethylglyoxime groups. Also, the orientation of the benzene ring of the sulfa and clan group in the respec- tive compounds is over the dianionic dmg. The various dis- tances and the relative orientation of the axial ligand in both compounds suggest a n-type interaction. LIPS supports the contention that "hydrophobic forces" are important in en- zymic processes.^ The bis (diglyoxima to) cobalt (III) complexes of aniline derivatives have here been shown to be useful mo- dels for the examination of tliis type interaction. An exten- sion of X-ray structural determinations to similar compounds with other aniline derivatives and with other diglyoximes is suggested. Low- temperature X-ray studies could effect better resolution of the inter-drug bridge structure and the N-0 distances . An investigation of the fluorescence spectra of these compounds could reveal additional information concerning the interaction between the equatorial and axial ligands. The fluorescence of 5-dimethylaminonaphthalene-l-sulfonamide was observed to be enhanced while the fluorescence of carbonic 141 142 anhydrasG was diminished when a 1:1 complex of the tv/o was formed. "* Although the major contribution to this observa- tion is believed to be the ionization of the sulfonamide, a portion of the change is attributed to a hydrophobic inter- action. -'■'■' ^^^ The fluorescence spectra of cobaloxime com- plexes with aniline derivatives should help reveal tlie nature of the interligand interaction as a function of the orienta- tion angle. The novel ligand dhphpy has been demonstrated as a bi- nucleating ligand. The bridging site occupied by a chlorine atom in [Ni2C£ (H2O) ^ (dhphpy) ] Cf^ clearly is accessible and of convenient dimensions to accommodate a molecule such as dinitrogen. Further development of this system as a possible model for nitrogenase should include use of molybdenum salts and work with the exclusion of oxygen. Synthesis of similar ligands with saturated "side arms" is also suggested. The compounds C^ (f ph) ^Co(cp) (tpp) and C^ (fph) ^Rh (cp) (tpp) contain a butadiene fragment with each end bound to a metal atom. The metal to carbon bonds are shorter than expected for the single-bonded distance. The metallocycles are, there- fore, believed to contain a delocalized Ti-bonding system. While metallocycles should be higl;ly susceptible to nucleo- philic attack and thermal decomposition the two compounds studied here are very stable. The enhancement of thermal sta- bility by the fluorinated substituents may be at least par- tially responsible. Also, the presence of the four fph rings 143 along with the tpp and cp ligands provides a shield from attack for the metallocycle. The understanding of catalytic processes should improve the efficiency of our existence. Hopefully, enzymic pro- cesses occurring in nature can be duplicated in the labora- tory by suitable models. These model enzyme systems may then be applied to cure the diseased and feed the hungry. APPENDIX A BOOTH I Tl A listing of the FORTRAN language computer program BOOTHITl follows. This program was designed to interpolate atomic positional parameters by Booth's method from the values of a Fourier synthesis calculation. The Fourier syn- thesis program v/ritten by Dr. Gus J. Palenik v;as modified to store the calculated values on a magnetic disk. After supply- ing BOOTHITl with input data of the approximate position of each atom, the stored values are retrieved. The program esti- mates the position of maximum electron density for each atom from these Fourier synthesis values. The positional parame- ters may be translated to equivalent positions and may be passed to a bond distance and angle program. The resulting fractional coordinates are punched into IBM cards in the for- mat required for their input into the Fourier synthesis and least-squares refinement programs. 144 145 » » * Q * * «• z z < * « >■ •K- z a 01 » * » J t- »■ y) aj Q O >■ a. * * « «■ 2 < X •3- .o < z CO (O 'JJ * •N- '.0 o * Z H o z oJ > r^ < » * a ^f- 9- }- X — < •™' z *-> OJ •H ■7 * » J * z t~ z .u > 'X o X Q »^ 11! < _3 .n <* .l; OJ 3 CE * * s * U u s t-# _•? ■3 — o u ^-^ a 3 _j s^* a CJ l;. r') .J ♦ * 1- < * ♦ u z -J • LJ _J _J JJ < U •» * a «• -J LU a 3 o LL LU X ■» # o * 'v") z >- a: t: •-* Z u. z •-* !/) '.J .'J < u J X • 0 « ^4 * J) o «• » < X u iU uJ r-l 1 * »- * J ^ ■» in < s « a •n ^■4 » •-• o < o 3 r s »^ Oj ♦ z 1 'S) a # o ■» > ■» a t/^ li. jj < 1- u X a • CO In J ►-< •-< oo X *-t z P X> ;xJ ♦ •» I ■» _) o 10 ji H — H J. X ■ k. yi Q » -J 3 -J :J o n 1 0 H ♦ » 3 2 «■ IL i • J i a K X. 2; J 3 »— 1 •n v-l n. •u 5 ■j"! • Ld » * . 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I 077 -2 31 0 -2U0 — ^ 103 -£4 -2 fc0 -18 -J3y -84 17 -14b 3 - 1 2 - 126 17 - la 26 a -2C5 -17 - 134 -4 4 -17 -143 -42 -I 1 -13i) -157 -1 > bi2 bia -16 -I J--; 194 -16 -142 -73 - 1 0 - 129 55 -10 -114 eo -lb -I3b 141 - 15 -Ice IbC -9 -142 -38 -9 t46 -b4? -14 ifc;0 -602 -14 238 247 -8 -I'l 1 -66 -0 62 7 -b94 -13 -134 -94 -13 2t5 -239 -7 -127 -60 -7 3/4 38f; -12 -13.^ 199 - 12 41 1 -2{i4 -6 219 217 -C -109 -66 -1 1 213 159 -1 1 288 450 -5 -131 93 -£ 204 96 -10 440 41b -10 232 273 -4 2i b -20b -4 -1 14 -bb -9 333 -324 -9 258 -2Ct « -i 2 £9 320 _3 2196 ?cnc -8 -113 - 1 19 -8 -125 -4o — 2 - 1 ;•: 9 76 — £ 1663 -1 £63 -7 221 146 -7 184 232 - 1 366 -440 -1 22 3 b -24C4 -& 30 X, 27o -6 287 -41 0 — b 610 614 .. c> -116 14 H = 1 t K: 9 H= 1 t K 3 -4 b6 3 -534 -4 5^5 1 028 -3 3--.0 -370 — 5 492 -510 0 -13 6 -111 0 23«1 -2335 -2 32 2 32c! - 2 12l£ ■ -1214 1 -1 25 22 1 ICbC lC3a -1 £.21 £91 - 1 277 2i'>2 2 -1 34 -4 I 2 -1 1 d -b6 3 - 12^, 46 3 8C6 -r.23 H= I. K 5 H = 1. K 7 4 -14 1 148 4 1756 171C 5 -145 - 153 c -112 -144- 0 374 538 0 290 £92 e -145 -2J5 6 226 -22b 1 212 - 190 1 £34 ££2 7 -146 109 7 -111 -13 2 Sot -eet> 2 -118 -150 8 - 1 -. 4 -59 e 7b4 -729 3 -112 -65 3 212 -256 9 2C7 -150 9 707 702 4 o71 672 4 2 1 7 269 10 22 0 174 10 -117 29 5 -114 122 C 164 2C2 1 1 -1 45 -225 1 1 -123 -179 6 6^3 3 -7C5 t 269 228 1 2 -143 - 10c 12 -13C 23A, 7 3^3 34 1 7 204 -26 6 13 230 301 13 -134 25^ 8 2 22 61 8 -135 47 14 -140 96 14 34 9 -3 5<-. 9 .>iiy -386 9 - I2t IC2 - 14 -l-:*2 19 1£ Zt?. -217 10 rv 1 193 10 242 -22 1 -12 -139 — 44 16 2.(9 30O 1 1 -L3^ 2b 1 1 2 48 243 -12 267 -206 17 -13y -0 3 12 32 3 -314 12 298 256 - 1 1 2 4y 201 18 1 97 -2C'C- 13 -139 3 b 13 212 -2C2 -10 -140 95 19 -14 1 -32 1^ icS9 £67 1 4 2£6 -266 -9 30b -257 -19 -i4;i -ie3 -17 -13a 96 17 2-->0 171 - 17 22 1 -220 -e 3t5 33a -It -136 - 1£5 IB -«<3 70 -16 -14b -169 -5 -137 -116 -lb ?29 -233 -IB 32 3 -2btt - lb -142 132 - 4 324 -334 - 14 244 215 -17 -133 -6 - 10 - 124 0 . -3 -128 -lo9 -13 -130 -122 -16 4i-o 442 -13 -137 -lib - 2 -l2o 95 -la 102 64 -1-S -137 1 13 - 12 273 24 6 - 1 195 2 04 -1 1 -1 I 7 £5 -A 4 3(2 -«:2J - 1 1 -127 63 -10 - 1 1 6 -?9 -13 - t.j>> 133 - 10 40 1 -4 JC H- 1 , K- 10 -9 3ti6 -«. : 7 -l:.? -131 -1^3 -9 -133 6 7 -8 -112 - 1C3 -It -ija -23 -8 231 239 0 251 176 158 1 2 3 A t) 6 V 0 9 - 10 - 1 1 - 12 - -li - -12 - -1 1 - -10 - -9 - -8 - -■/ - -C ~ _ c. _ -4 - -1 H= 0 1 3 4 5 t) 7 e s 13 1 1 -1 1 - 10 -y -t -7 -C — c- -4 H= 1 '1 1 l't3 1 'it 2H2 14J ?0^ 2V<* i';3 1 'I -5 1 *•- 1 ^.V 1 tb I '. 0 1 '.0 1'. 0 1'. o l^fc 147 J '«a 1 i. t- 1 , K- •137 -l'»0 -1 ■■( 0 370 31 3 ■ l'*9 -143 -143 - 1 •'( S - WiB 1'. C - ) b:i - ic 1 -14 5 -1 60 2oe 300 -139 209 -13ti - j - 1 'j -1 - 4 - 7 8 -L -7 -6 -b -4 -1 H= 1 3d 142 1 f V 267 1'. 3 13S ■144 140 14b 146 14 7 Ibl 1'. a 2 1 y 14 3 14fc 1 13 146 30 4 143 -1 bO - 1U.3 -1 bl 242 FC ■ 106 -bO -3 -1 231 e7 ■145 •2PP 1 74 129 -190 4 2 114 -22 1 7 3 -34 -147 105 -3 23 4 166 -36 9 -cn 4 1 I 1 1 97 125 -SO -?7C lit* -142 -89 33 -1 8 -23 ie3 - 132 GO 277 -2 27 -36 3 IC6 24 0 -39 -139 -4? 1 03 12 174 97 -38 ie.9 7e -143 - 191 20 19 - 126 bb ^7 -2 06 -38 13 -4b C-6 157 -16 4 -4 -3 -2 - 1 y-~ 0 2 t, 6 O 10 1? 14 1 6 18 -20 -1»^ -16 -14 -1 2 -10 -8 -6 -4 0 1 2 3 4 b 6 7 8 9 10 1 1 la 13 1 'I 15 16 1 7 If 19 -19 -IP -17 -16 -15 -14 -13 -12 -1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 FO - 1 4 9 2 3 4 - 14 « -lb) -14b b9 2 ^^? 113 1 189/5 1 724 7-) 6 24 6 -137 56. i 4cit> - I 4 3 -136 bb7 b4 0 4 -i 4 372 4 6' 91. 6 1 1 2 6 rc - 138 84 -29 -bO -79 569 -916 1113 - 1823 lt97 - 7 / 2 7 2 125 - ^60 46 I - 1 3 1 -156 565 -626 £39 -46 3 -3/8 444 -Sb7 10/3 K- 314 - 1 00 1 529 209 I 2 55 - 1 1 ;. 306 3i;7 359 -114 38 2 4 1 7 42 6 336 50 '•l - 1 3 • -13 9 -13-. -136 -146 -1 3H 350 2<'0 24 I 24 5 -13^ -12 J 33 0 - 1 1 3 62 3 58 1 138 5 602 38 4 1273 180 bi.'8 -98 309 - 1 53 - 1525 -231 1271 -58 -258 380 -322 2 373 -4 14 -435 34 6 555 - 161 -340 38 -4 1 89 -55 -373 170 235 -22 5 121 -■j'2 -292 29 6 19 -583 -1377 £91 399 -1239 78 -491 -272 29 C 7 8 «-;> - I 1 V -2 9.' 4 0? 298 - 1 71 C 1 563 -24 5C -13 8 1 1 0 -267 2 I 238 -279 -4 1 jS ^.2:i 1 14 -135 -72 131 103 -2 2 4 - 162 -163 -83 1«.4 4 7 8 -16b -^28 425 462 -3CS 373 96 -2c3 79 0 1236 -29 C 1 2 4 5 6 7 8 9 1 C 1 I I'c 1 3 14 15 16 1 / 18 - 19 -Id - 1 7 - 16 -1 5 - X'* - 13 -1 2 - 1 1 - 1 0 -9 -ft - 7 -6 -5 -4 _ -^ - 2 - 1 ID 1324 403 t1 13 2 16 -112 234 -113 550 4 I 3 260 - 125 3C9 - 133 -1 39 - 1?3 - 138 -137 -140 -140 -140 -139 239 - 1 3'i 3 79 215 3e8 - 1 2 7 4 3 6 1 7 1 -1 15 -1 13 269 407 2 50 - 1 1 0 - 1 J.' 1520 -110 K- 0 1 2 3 4 5 t 7 e 9 10 1 1 1 2 13 14 1 5 16 17 18 -18 ~ I 7 • 16 -1 5 - 14 - -13 -12 - 1 1 -10 - -9 -8 -7 -6 - _„ t -4 -3 -2 1 -1 1 599 tt I 3t>8 57 5 -115 2 1 6 -1 16 3 19 330 2 84 t U 9 -137 V26 -1 34 281 -140 -139 -140 -1 38 ■\^:i 1 9 7 2 23 - 134 22 I 315 4 3\/ - 1 : 7 5.3 239 693 -114 523 7 1 2 176 1 40 39 7 FC - 1 299 -50 2 52 250 - 200 - 130 £61 4 24 -281 166 32 1 -90 8 8 -4 - 171 -54 ir7 -C2 -lb 2j:o 53 -432 -92 373 127 -431 26 18 0 224 397 -260 84 - 184 1537 121 -620 -899 -344 5G0 -9 5 -3'»3 2/7 1 1 -317 3C3 30 1 -567 -1 16 726 ice -?ol 1 19 43 -96 -14 23« 146 -2 17 - 131 - 1 17 -244 470 1 4 4 -560 -195 o76 -66 - 5 3 "■' -703 - 185 1 1 03 136 9 159 FO FC FO FC FO FC FO FC 0 195 -153 1 t -146 -15 9 494 -493 H= 2. K 6 I - 133 300 12 - 1 4 (J C ( 1 1 ■ 273 -24 7 2 - 130 -') -1 3 -147 -6 8 13 4 0J 4 29 0 26 9 -?>93 3 205 290 -12 - 1 44 1 1 1 15 7i4 -729 1 646 -02C- 4 -134 ~'.2'i - 1 I - 1 4 4 -55 17 294 304 2 b)3'! -l;7f. r^ -1 Jb -142 - IC - 142 5 19 254 - 155 3 -1 J9 - 168 6 -14 1 196 -9 -140 206 -19 -136 -64 4 203 79 7 -142 -89 -8 -140 -96 -17 613 6 34 5 V4 ti 786 0 -1'-) 56 -7 -14 1 -74 - 1 ;; 531 -542 £ 1^7 -2 0'. 9 217 - 162 -6 -129 -25 - 1 3 4 9 7 493 7 64 1 -I..4 2 10 213 12/ -5 -146 -14 8 -1 1 4 40 -4 36 b 2btJ 27 5 1 1 - 1 4 1 7 -4 37 0 -35 b -9 356 -310 S 337 3 34 12 - 139 - 131 -. -3 -14 3 19 -7 101 1 1026 JO 319 -3C5 13 -144 -6 -2 4 88 487 — (^ 1442 ■ -1103 11 -133 1 J 1'! -l'*l -9 - 1 2 CI 226 -3 2( 3 2Z 1 12 -14t -5 15 - 144 121 - 1 1290 ■ -1240 13 -1 '^11 - 120 -16 28 1 -167 H- i . K 1 1 l -194 -1 1 -141 152 "3 - 143 62 2 1796 173 6 -16 -137 poe -10 -145 181 4 307 ^24 •J 281 -27 1 -15 34 7 34 4 -9 - 147 -284 r. -143 -18o 4 583 -569 -14 -141 -253 -a -140 - 1 6 I 6 -144 -73 5 21 1 -2 7 1 -13 3 1 0 - ?. 0 6 -7 3yo 4 15 7 -145 177 6 754 -771 -12 42 I 4 16 -6 - 13^ -34 a -146 - 1 12 7 51 0 - 4 9 2 -11 20 4 210 - 5 -134 -85 9 -149 -29 8 -1 14 124 -IC 360 -35ti -4 481 499 10 327 240 9 710 708 -9 - 1 .'i e 58 -3 2bO 3 04 - 1 1 22Z 163 10 -12 1 - 169 -£ i9<; 256 -2 - 1 29 - 129 -10 - 15d 230 1 1 796 -805 -7 Z0 2 -294 -I 425 -431 -9 -144 - 14t> 12 343 369 -6 -122 -92 -8 29 2 -355 13 44 6 4 32 -5 -12 0 24 6 h'^ 2. K= 9 -7 -14 4 1 19 14 3 07 - 2 6 8 -4 £3 2 -517 -6 331 270 15 199 -127 -3 6C9 -60 1 0 291 -369 — c - 145 -1C2 16 2 15 - 167 — ? 104 5?2 -13 -12 -130 220 94 2a -1 1 - 10 -136 -196 192 _ 3 -? 590 447 -5/4 -490 172 - 1£6 -1 1 -125 -8 -9 -124 -7 - 1 -129 84 -o ^^3 547 -10 -121 -121 -8 525 -5C0 _ c: 2t>? -220 -9 -119 -224 -7 £38 523 l- = 3 . K-: 9 -4 -3 -I 12 21 0 -It) - 161 -e -7 590 2'45 608 2o3 -t -5 -12C 4C7 19 1 -4C7 0 -137 -79 oi.4 CI 0 -6 24ti 233 -4 e?3 -£62 1 22V. 102 - I 36 9 -230 -5 232 - It6 -3 316 314 2 -14 1 13 1 -4 -110 -36 -2 £93 920 T - 1 39 -82 3 t K: I 3 -3 57y 603 - 1 - 1 14 44 4 -13/ -3ei -2 738 -778 5 -144 93 0 1 2 2 -I 15 33 I 1 146 2s»e -9 -281 1 1U2 -331 - 1 H = 3. K: -tSd 5 0 1 3. K: t32 4£6 = 7 626 -456 6 7 e 9 2£6 241 221 2Z2 -:;23 75 213 - 157 4 485 -4 44 0 587 -374 c 2££ 253 10 -144 -67 «L 42 3 426 1 219 47 ^ 443 472 1 1 -1 45 6 7 6 -112 95 2 940 967 4 - 123 -1 1 12 2 1 7 2 73 7 162 72 3 -113 -47 5 -126 -38 13 -151 -70 6 217 244 4 710 -7 18 6 -130 29 - 14 2 22 147 9 -117 -29 5 -lid - 152 7 163 -1C2 - 12 - 1 44 £ 10 328 26C 6 2Uo -277 8 -135 -03 -12 -1 <40 -4 1 1 1 257 25b 7 lo: -153 9 -141 22 - I 1 -1^0 -1.-6 12 33t) -?09 8 386 393 10 2C3 15fc -10 -14 1 - 1 2 3 lo 22 1 -222 9 187 228 1 1 242 -235 -9 -1^1 13a 14 - 1 38 1 93 10 380 -379 12 3£3 -3 7/ -e -1 A4 -9 1 5 -137 199 1 I -1-i^ 34 12 -143 194 -7 -142 101 It -132 169 12 6o6 e3rt 14 - 140 19^ -6 2c3 198 1 7 -139 -63 13 -1)7 64 15 -143 -16 -5 -1 39 - 1 70 18 - 143 -74 I't 218 -210 16 - 144 -2 - 4 £57 - lai -9 -145 -37 2 -109 -23 0 -113 96 c 247 2C8 -6 278 - 1 59 3 - 1 1 2 -7 302 280 t - 12 / 104 -7 — 152 284 4 50 A - 5 1 0 ? 53 1 -;38 7 -140 -178 -6 - 1 4 'k 64 5 529 -560 3 268 264 8 - 145 242 A c 35/ -379 6 359 369 4 659 C51 9 - 142 69 -4 -151 -66 7 - 1 1 7 es 5 6/8 -694 10 -142 -79 -3 349 386 0 208 -1 60 6 8'i 7 -ebi 1 1 -137 1 -2 262 327 s 246 319 7 372 398 1^ 2C5 -£2 - 1 - 1 4b - 1 34 10 209 93 8 413 4bl 13 -14 1 -196 1 1 268 -23 1 c ^■»0 - Jb8 14 - 1A4 18 12 -137 140 10 -13-. - 166 It 2J0 97 161 L FO rc L FC FC L FC FC L FO FC 0 23 7 -227 -1 -113 105 _ 3 -110 -53 h! = 3. K 1 1 1 -ll'i - I 3 5 -2 -1 09 -58 2 62S> 5') 9 H = 4 , K 3 - 1 .24 1 224 0 -1^.7 -69 3 2/0 - 2 V 3 1 -11,6 -3 18 4 -109 8 3 0 -111 -61 h= 4 . K 5 2 -116 t(j 5 401 3 89 1 - 1 1 1 -i 1 4 3 -1L)1 151 6 252 -20-3 2 643 633 0 245 -328 4 -li8 -4 1443 143 1 -6 840 856 -8 -116 ■i.3 — 6 2e 1 - 2 1 ; 6 -2 696 -<.70 -5 4 13 -423 - 7 tt 1 -tvi -5 738 -75 0 -4 -110 121 -e 292 -2 69 -4 8/8 892 H= 4 , K.= 1 -3 7 57 762 -5 £30 <.: 4 8 ^ -a 1 C4 ^^.'* -2 1 1 59 -1 135 -4 189 150 — £ 3to - J!S 162 L 1-0 PC L iU r c L FC FC »- f O 1 C -1 1 7^' -M5 6 -140 92 3 - 152 1 78 1 -109 -160 7 -141 69 i\ if- 3 131 2 '561 564 1= 4 . K 7 n -142 -/7 €. 2 23 -24 0 '» 51 1 4V9 9 23/ -23 6 - 149 -7L. 4 64 0 -665 0 31'> -342 I 0 -140 99 -7 - 1^4 94 5 206 189 1 - l?l; -47 1 1 -143 34 -6 -150 123 6 J71 399 z 2,?b 23 1 12 -145 -56 -5 223 -139 7 2f 6 230 3 i.-0 1 -?40 13 -1 50 -131 -4 - 149 -44 8 26 4 Z:iKi 4 -132 -{.'5 -1 4 - 1 46 97 _ 3 - 145 15o 9 4 2 8 451 <:■ 'ibb 4 64 -13 -14b -36 -2 - 14o l;'.3 1 C .i9 7 -394 c 3 ') b -310 -12 -1 3U -f.b -I -142 13 1 1 Ji./ -364 7 3'.. / -300 -1 1 - 1 3 t' 79 12 -132 17 e 3V9 413 -10 -137 -9d \\~ 5. K 0 13 - 14C -249 9 -1'.3 192 -9 -13y 136 14 -140 190 10 32 a -2b9 -8 ^^^ 6 1 £69 £t 1 15 -1 38 4 9 1 1 313 - 230 -7 - I 4 2 -43 "a 2366 -2341. 16 -1 3:. 146 i:: -l'<0 -l?> -6 -14 1 -93 5 13 1b 1326 17 - 132 20 13 330 324 -6 32 1 -354 7 - 1C9 CO It -14/ 67 14 - 1 '» ii 146 -4 - 1 4 3 1 1 1 9 t56 -Ct 1 "19 2 69 -293 lb -1'. 7 -114 -3 404 4 20 1 1 t72 6 74 -18 -144 220 •16 -14o 7 b -2 313 -261 13 3 04 ^\ 1 - 17 245 37 lb -136 -14 -1 -142 -245 lb - 129 35 -16 -133 -43 It* -1 AO -4 4 17 - 137 -1 1 - 15 -137 -115 13 - 1 3 £i Z2 1 = 4 . K: = 10 -19 4 lO 37 1 -14 269 -29 1 IH -140 -20 -17 Z99 i o4 -13 262 -200 11 -14 1 1 15 0 -140 -133 -15 -137 -20 1 - 1 2 339 384 ■10 -142 -207 1 - 1 .-. 5 5 4 - 1 ; - 132 - ICC - 1 1 7t2 735 -? 22 6 -232 2 -1^1 1 .6 -1 1 £37 -t35 -10 3 1 L. -295 -8 20O 212 3 257 14 1 -q 1210 1201 -9 2 1 1 -157 -7 20 2 -234 4 257 -356 -7 i;£4 -13cS -e -113 140 -6 - 1 3 i - 177 5 -143 -65 _ C 3fc7 348 -7 -1 13 51 -5 6t.y 71b 6 ^3?. 335 -3 -109 -'t7 -6 555 -b4b -ti 4 1 4 - 4 1 4 7 -142 -129 - 1 iCt 172 — '- 4 15 366 — 2 J n 0 - :• .- 1 8 -142 -89 -4 4 56 47 1 -2 I.-/ J, 71 1 9 -142 171 H= e. K = 1 -3 39 3 -307 - 1 - 123 1 in 10 -14iJ - 158 -2 192 -44 11 - 1 49 -29 0 £55 tfcO - 1 -109 53 4, K: 8 -12 206 23 1 -1 1 1 9 0 -1 1 -1 47 - 160 2 3C3 -37t t- = 5, K: 3 0 -13£ -257 -10 -14 2 -9 5 ^ 737 7Jo 1 - 1 3 6 -104 -9 -141 14b 4 4 82 -4 95 C 781 758 P -1 J4 59 -8 -144 222 c 13 3 0 -1323 1 502 -4y2 ■3 -1 3i; -tl -7 -143 76 fc CCl £91 2 738 -759 <4 4 7i. 401 -6 354 -365 7 tt2 644 3 627 -623 5 -14 1 171 -5 -143 - 1 06 8 375 -360 4 299 -310 t -144 -31 0 -4 275 290 9 e 13 -t34 5 otO 492 7 -14 3 -9 -3 -I4t. 23 ' 10 372 365 6 20 1 163 0 -143 1 I -2 272 - 103 1 1 29 2 3<>6 7 326 -363 9 334 -246 -1 -143 - 162 12 -132 64 C 520 508 10 -142 161 13 4 04 -4 09 9 3td 434 1 1 -144 94 H= 4 . K = 1 1 14 - 134 -4t) 10 2£8 -2i.0 12 -l':0 -164 lb -137 113 1 1 - 130 63 13 -14 3 - 185 0 231 -304 16 - 1 3 ti 96 12 196 - 1V4 14 - 1413 101 1 -14 1 99 17 407 4 b 1 13 -145 274 15 -14b 1 1 1 2 -144 93 IB -i4t; -liSi, 14 27o -54 14 -14 4 1 1 1 3 -144 17 - 19 -136 -ijl 1 £ 1 £8 -65 13 -14C 50 4 -142 71 -16 - 138 -loO le -137 -4t< li - 1 3 7 - les s - 144 -57 -17 -132 122 17 -142 -14 1 1 1 -14 1 - 1 76 6 26 7 -246 - It t06 139 - 19 20s 145 10 - J4 J 219 7 -146 5o - 15 -137 IC7 -It -139 -35 -9 - 14 L 24 3 6 214 2.12 - 14 - 133 1 1 - 17 -137 -143 -t b4t -40 3 9 -153 -32 -13 609 590 -16 -1 jj lb -7 -I 39 -TTb -10 -1 51 - 131 - 12 -127 -6 1 - 1 £ 226 - 196 -fc 3i^e 443 — Q -146 - 1 3 - 1 I t 18 -523 - 1 4 - 1 3 5 - 10 -b - 137 -100 -8 -140 214 -10 143 662 - 1 2 2 2'« - 126 -4 -13b -4 3 -7 -142 -I -9 -112 17 - 1 2 3 3 4 334 -3 242 27b -6 - 1 3 9 o -t c-cg -344 - 1 ! -122 2^ -2 -13 1 6 -5 -144 -8 -7 be 1 554 -10 164 ZM -1 -132 -47 -4 363 -223 -6 448 -4 03 -9 -119 -85 -3 360 33 2 - 5 tS7 -^tO -d 29 7 -256 — 4 « K = 9 -2 3o4 3 :.7 -4 CC6 61 7 -7 2t4 -286 -I 495 -401 -3 729 722 -t -111 22 0 0 -143 -6 -2 -110 ■ iJ, . £; 9o7 948 1 -142 175 h- 4 , K- 12 -1 -111 -85 - 4 639 - 6 V t; 2 -14 4 \l ? -3 2/2 -3/3 3 -I'll -10 0 - 1 4 5 -38 H = £ . K- 2 -2 220 179 < -1 42 -59 1 -146 -66 -1 1V9 2 3 7 5 - 140 32 2 - IH? -4 1 0 -110 S5 163 L FO FC L FO FC L FC FC L FG FC Itr; S. K= 6 4 -13£ -ICt -5 -140 44 h=. 5t K= 4 «: 292 -32 7 -4 -143 98 0 -J21 -256 6 -14 0 126 -3 ■^139 -8 0 -1 1 6 -147 t 301 304 7 -143 87 -2 -145 24 1 -113 94 2 521 548 £ - 140 C - 1 -144 37 2 72 4 -721' 3 378 -398 9 -145 83 3 -113 -37 4 50 5 -484 10 -138 66 1 - 5, K: = 1 I A 901 910 5 3?3 392 1 1 238 -254 5 472 -4f 1 6 240 173 12 -1 3e 17 0 -14^ 49 6 -1 18 -134 7 -130 152 13 -i£l 107 1 2 49 177 7 47 t.35 6! 1 -3 437 -453 4 -147 -150 1 - 1 -^i 7 107 -5 39 0 -41 0 -2 -1210 102 c -lec 221 ^ 3;; 5 -297 -<» -1 1 4 56 -I -1 i9 1 14' e - 145 89 5 -154 -19 -3 403 364 7 -14 1 -176 -7 - 1 53 100 -2 -111 -33 H= 5. K = 7 8 260 -1?7 -6 -152 - 1 4 0 -I -114 168 9 - 142 86 -5 -144 62 0 -123 -12 JO - 1 4 4 6o -4 -146 54 H= 5, K 5 1 -125 -53 I 1 ai3 -124 _ -M -1S3 -157 2 1*35 -83 12 - 144 65 -2 -151 9 3 0 299 372 3 -132 -24 -14 -148 123 -1 -149 79 1 6C9 es2 4 231 333 -13 232 -82 2 2b 1 -3C1 5 2iiJ -29 1 -12 -l/;tj -8<* H- 6 1 K: 0 3 319 3C-2 6 33i -393 - 1 1 -1^1 13 2 4 690 -695 7 ',<,.-3 499 -iO -141 6 9 0 -107 123 c 2C9 -132 8 51 * 5 07 -9 -141 -20 2 1292 ■ -12 7 5 6 102C loeo 9 406 -3B4 -6 -144 -3o 4 1232 124 0 7 -125 4b 10 23/ -80 —7 -143 -55 e 2 99 -254 6 1006 -1C40 1 1 -133 62 -£ -143 -37 £ 6C3 - 6 1 9 9 -13? 0 12 -13o - 165 -:s - 144 243 IC I0c4 1071 10 b25 £24 13 -i37 148 —4 -141 37 1 2 -132 -21 11 -137 72 1« -143 -125 » -= 236 -249 14 -135 66 12 3b4 -29 7 15 -1 *6 - 141 — 2 - 138 24 It -139 -46 12 -136 -145 -16 - 1 ■<, 0 76 - 1 -14 1 -c2 - 18 334 -321 14 20b 212 -15 -I'iS - 1-:^2 - 1 6 -130 42 15 -138 CO -14 -t3o -41 H- 5, K^ = 10 -14 -136 -102 16 -I'.b 35 -13 -131 58 -12 715 -744 -le -14fc 163 -1? -132 109 0 -142 -86 - 1 C 832 850 -17 - I 3 b -10 -1 1 - 1 J'^ -85 1 - 146 232 -8 -112 -158 -1& -15S - 165 -10 -13 7 -47 2 -143 ICl -6 1 003 988 -lb -133 -10 -9 -136 82 3 325 -328 -4 - 1 09 1 19 -14 -141 159 -8 212 -186 4 2C2 -57 — 2 -108 -49 -13 219 218 -7 -133 -90 c 282 226 - 12 t.73 -t9 8 -6 33a 2^j2 £ -144 159 H= 6 . K: ~ 1 -11 -133 -97 -5 2^9 -272 7 -142 -13 -10 b/0 563 -4 2y7 -297 £ -142 -66 C -! C7 -7 -9 -120 2 -3 25t> 294 9 -147 -103 1 ■ 301 -32 2 -8 -12b -155 -2 -12? 130 IC - 150 -65 2 10 98 IC84 -7 19/ -137 -1 33'j -305 12 -154 2 89 3 156 -137 -6 eoo -833 -12 2C9 -£2 4 2108 ■ -2038 _ c bSO 561 F- 5. K- 6 -1 1 354 -320 c 323 2(.9 -4 74 7 784 -10 -143 -8 6 6Cb 615 -3 lo7 -129 0 -1 3* 1 0 5 -•9 12 1 £C5 7 181 -U i -2 -lib -60 1 233 -2 32 -U -12/ ^ 1 8 24':l -337 -1 21 3 -273 2 - 1 36 -152 ~7 -l-H-i -Ivb 0 2 64 336 3 -1*2; 2«:.5 -b -140 -151 10 261 252 164 FO FC FU r c FC FC FO FC 1 1 ■ -13 1 62 9 206 -H3 10 2 56 222 - 16 -148 -46 1 3 -l.lt 21 7 -137 -22 10 1 1 ■ -1 J3 -1 J4 -232 21 1 1 12 -14 1 - 1 44 6il Itt - 15 - 1 4 -145 -> 1 4 C - 1 1 5 127 1 5 - 1 JO C4 12 31 0 -2 06 13 f £3 -142 -13 297 253 21 0 1 fit. 13 315 -316 14 -I3f -01 -1 2 -140 -174 16 1 7 • - 1 A 'j 37 2 14 15 • - 1 36 -140 Ibd 77 1'- 16 -14.' -141 3 9 1 1 S - 1 1 -10 -137 2t)4 1 02 302 I '^ • - 1 'i 0 ?1 16 - 143 - 192 -1 7 -14 1 -30 -9 4 1 9 -454 lb 17 1 Cj J-1 1 - 1 J. / IV -Itl - 1 4 9 250 1 7il -251 -16 - 15 - 1 3 1: 13 14t -7 -13 9 -137 1 i'l 100 - 1 :•; 'i 101 -17 -IJtl 69 -14 -137 ?6 -(: - 1 43 — 2 je lb ■ I *i ■- 1 J i; 3A3 -3ra -16 -15 -139 253 31 2 1 7 -13 -1 2 213 22 4 -276 -237 -5 -4 -137 3 94 -21 4 403 I 3 - I :* C 60 -14 2 0^ - 1 70 - 1 1 - 13 1 -4 1 -3 -136 -87 1 ?. - 1 .:■'; -A 3 -13 -134 4-0 -10 - 132 -10 -2 2 I 4 -256 1 1 -lib -77 -12 -131 -lo -9 -132 181 - 1 - 1 3 J 151 10 20e -257 -I I -129 - 4 5 -t - 12e -13 1 -9 i-i'ii -176 -10 35 1 4 CI -7 4C6 -402 1^ 6. K- = .8 — 0 2'/ 2 I'-'i 1 -9 400 -4 05 -t 1 74 - l7o -7 jay 41 6 -8 - 120 Itii! - 5 954 1C06 0 -140 - 100 -6 17 7 6 - -1 745 -7 621 6 55 -4 17G 103 1 -140 -61 253 -b 651 r>39 -6 -111 5o — 2 1125 - -114! 2 -142 ~A 19S7 1 t;26 -5 569 -544 -2 -119 -13 1 T -140 -63 -3 962 -95a -4 39 9 -39 7 - 1 -11? 7 2 4 -141 -69 -2 - 1 Cy -24 -3 266 24 a 5 258 155 - 1 -I I 0 57 -2 167 -13 H-- et k: 6 6 -141 -57 -1 214 254 7 -1 43 1 56 _ 6. K; ; 2 0 34 6 372 8 -141 147 1 — H= 6. K = 4 1 41 8 4 5 C 9 -142 -128 0 1 520 299 523 291 0 230 267 2 3 1C5 f 9C -^.32 -6C7 1 0 1 1 - I 4 5 198 -196 -91 2 99 3 99 1 1 104 - 163 4 3C6 296 12 257 23b 3 995 -<;f;8 2 50U -502 c - 133 43 13 -1 49 - 151 4 22 I - 19a 3 550 t33 6 -133 -152 -15 - 1 4 4> 40 5 2/3 -280 4 523 4t'tl V 2fC 225 -1 4 -145 -2 06 C) <* 7 1 - 4 't 5 5 -120 -92 t 3e5 -35 7 - 1 3 - 143 -96 7 2t^ -2 26 6 -l^b 2 9 9 2 63 -32C - 12 218 236 8 2 J '. -6S 7 -127 50 10 226 231 -1 1 -I - I 3d 7 15 - 1 4 4 jy - 15 -1.0 2C ^ "i 338 - 362 17 2^C 196 16 -140 - 104 - 14 -135 i: 2 -2 20o 124 -19 - 1^6 160 -13 -142 -2J -13 -13t> 95 -1 2 96 276 -10 -1 36 -40 -17 -139 -15 - 12 2.^6 -225 -17 2 I t -r-'2P -16 234 C>4 - 1 1 3C7 -3/2 H= 6. K = 9 - Ic -1 3o 95 -15 -134 1J6 - 1 C itt 2 33 - 15 32 ? 320 -14 3HJ -265 -9 270 312 0 21 1 102 - 1/1 2hJ 194 -13 42 3 -4 3 1 -e -132 -75 1 -144 3 1 -1 3 - 1 30 -41 -12 -1 39 - 12o -7 357 -349 2 2 59 - 127 -12 21 1 239 -1 1 4bi 458 -£ - 13C C *J -145 - 135 - 1 1 'i02 -4 19 -10 - 1 29 49 -5 1£7 19 4 320 2-*a -1 0 « 1 ^! -4 17 -9 3b9 -37.0 -4 -123 -136 c 255 2 06 -9 -120 123 -C -120 -101 — 2 142 £46 e -140 - 146 -8 - 1 I 4 ia3 -7 -120 60 -2 44 7 -470 7 250 -1-34 -7 - 1 1 1 2 -6 621 C07 -1 237 -305 8 -143 o6 -& t:^ <. 517 -5 191 4 1 9 2 13 191 -5 1 5'* 36 -4 295 -244 H = 6, K 7 10 -1 47 -8 -<» 14 I <•• -139« -3 433 -431 1 1 -1 40 -8 358 -32 6 0 - 1 1 1 -5 3 1 1 75 101 6 221 wl 9 -7 -1-41 -12 1 - J 1 1 - 1 1 1 2 - 1 la -66 7 2C4 226 -e -141 37 2 - I 1 'i -200 3 572 - 199 8 - 14 1 -97 -5 -146 21A 3 1 1 HI 1 152 4 -125 -2 03 9 26t; -278 - 4 - 14o -o9 4 C?b 634 5 637 659 10 221 204 _ "3 -143 -60 S t'A^. -653 6 -127 -til 1 1 - 142 -191 -2 - 146 44 e -120 e9 7 553 -574 12 -140 -tb - I -1 43 -4 7 7 -; 1 7 74 0 -136 -214 13 - 1 4 6 263 e -12'* -71 9 J19 3ia 14 -152 -170 165 L FO FC L FC FC L FC FC L FO FC -1 -110 174 H- 7. K- 3 1 349 -325 i= 6. K = 10 2 69 7 -735 F= 7, K- 1 0 285 -412 3 7 126 157 0 -144 258 1 £69 -305 4 840 G62 1 -143 7 7 0 524 -538 2 370 323 5 -130 177 2 ?0d -179 1 673 654 3 -115 160 6 31 1 -318 3 -143 -43 2 5;il -597 tk -lie -£ 1 7 -134 -228 4 -14 1 11 J 3 971 -971 C 253 -287 8 -136 I 19 6 -1 3d e.4 4 613 589 6 -1 19 ?-ti 9 -137 -1 70 (t -144 -30 5 -118 151 7 -124 1 06 I 0 199 186 7 -147 -189 6 294 -363 e 2^9 193 1 1 4 06 412 e -146 -131 7 263 -277 9 -133 -64 12 391 -4 1 0 9 -147 92 8 -126 132 10 -13'. -20 13 195 -97 10 254 266 9 -132 -55 11 £94 -£85 14 -145 216 -11 - 160 22 10 252 -269 12 -139 24 15 -143 •"5 3 -10 38 4 31 1 11 484 507 13 -13c -7 -17 -146 97 —9 -142 -152 12 -139 106 14 -138 125 -16 -14 1 4 7 -e -142 - 107 13 318 -208 15 -137 -63 -15 -14 1 - 189 -7 -140 -51 14 -13U 70 16 -142 1 1 1 -14 -134 1 -6 -130 105 15 -137 83 -18 212 1 19 - 13 235 150 -5 -147 174 16 -139 -106 -17 -138 7 2 - 1 £ 2 34 9 ~A -143 -13 -18 240 - 127 -16 -1?8 -2 -1 1 220 78 ^ -a -141 -38 -17 -139 -52 -15 258 148 -IC 271 330 -2 -144 -254 -16 200 186 -14 - 137 -79 -9 284 -251 -1 - 140 -81 -15 -134 - 156 -13 204 -216 -8 656 -657 -14 371 -376 - 12 -137 219 -7 -12o -1 N= 6. K= 1 1 -13 270 233 - 11 -128 50 -6 725 722 -12 3i5 4C9 - IC ece -522 . c 264 302 0 - 139 eo -1 1 304 -312 -9 42 1 -421 -4 300 -333 1 -143 33 -10 179 -12 -a -122 182 » TJ -122 KS 2 -147 -32 -9 463 449 -7 444 446 — 2 241 257 " 5 -143 -24 -0 4 11 -361 -ft 4C7 -'ica -1 -I 18 72 4 276 -179 -7 830 -829 . ^ 490 -513 5 -147 59 ■ -6 -117 135 -4 275 298 H = 7, K: = 6 e -155 215 -5 1138 1 ICo - 2 £37 -528 7 -150 -76 -4 -112 58 -2 -111 -12 0 538 559 -? -149 3 -3 -110 -41 -1 4 49 475 1 206 -199 -6 -Ibl 110 -2 724 741 2 36 1 -35 7 -7 -146 -56 -I -1 12 -16 H = 7, K = - 4 3 -132 147 -6 250 -219 4 -132 12y -5 -146 73 H^ 7, K 2 0 215 -236 5 249 135 -4 2t)tj 245 1 750 -763 6 -13'* -25 _ -a -14b -6 1 0 447 466 2 -1 16 -97 7 -140 - 16^ -2 -142 -62 1 185 236 3 6£2 638 8 222 -34 1 - 1 - 1 46 9 2 288 -264 4 £71 289 9 223 209 3 219 -272 5 3 29 -2 75 10 573 55 9 H= 6t K- - 12 4 190 209 6 351 -324 1 1 268 -2!^0 5 -117 -66 7 -127 48 12 -139 -98 0 226 -74 6 -118 165 8 a3o 128 13 257 221 1 23b leg 7 454 471 9 -132 -! 9 14 -1 43 -168 2 267 179 8 3 00 -342 10 ee2 -57b - 16 -141 -1', 6 3 226 -168 9 422 -4 15 1 1 -136 176 -15 -1<»1 -9 1 4 -150 -87 10 33a 305 12 £29 £27 -14 310 248 . c -153 -1 11 -134 -23 13 -139 -236 - 13 -137 67 -4 ZijZ -23 12 -140 -2o8 14 -136 -6 -12 3a^ -389 -3 -144 29 13 -137 237 15 -145 -9 -1 1 32 1 329 -2 -150 95 14 -140 -16 io -150 -25 -10 4C5 402 -I -148 -1 18 15 -139 9.0 - 17 - lAA -30 -9 -137 -260 16 -140 68 -16 - 139 c c -a 310 -332 H= 7, K: 0 -18 -145 8 -15 -134 l'"! - 7 252 -243 -17 -141 75 - 14 - 1 .; 1 -175 - e 296 259 1 1005 ■ -1026 -16 -135 -7 -13 -138 1 1 --5 191 155 3 -110 25 -15 370 -353 -12 418 407 -4 201 204 5 240 270 -14 217 -2^4 -1 1 314 338 -3 -127 -82 7 56a -555 -13 421 410 - 10 437 -460 -2 4 ,7 -522 9 8t9 9C6 -12 210 - 1 ■'. 9 -9 366 -358 -I 271 353 1 1 537 -t;76 -1 1 ^rl -3-+y -a -122 -JZ 13 266 238 -10 37a 39 0 -7 331 375 H = 7. K = 7 15 -137 - 144 -9 -1 la 48 -t S47 £25 17 -150 -234 -8 33 0 -361 _ c 341 -312 0 4 16 -46 1 -17 -143 84 -7 269 -254 -4 581 - 6 1 O 1 -133 165 - 15 - 13 7 - 1 17 -6 228 -269 -3 -116 191 2 -I3y 24 4 -13 220 -208 -5 -1 12 - 156 -2 £C5 -1 04 3 393 -JV7 -11 o5 I 653 -4 2^3 333 - 1 £48 £18 4 -IJd -92 -9 380 -346 -3 558 565 5 336 362 -7 -117 - 155 -2 -113 -9b H= 7, K 5 6 -144 1 19 -5 lOi' 1 1 rud -1 -HO lo4 7 -141 -63 -3 799 -810 0 - 12 1 -tC 8 -136 9 166 FCl FC FO FC 10 fC FO FC s -14 1 91 4 429 3 94 t 239 220 10 220 -2 1? F = 7, K=^ 10 f. 4'iC - 4 2 4 7 22 3 1 /3 1 1 -1.14 -Ill t -\c2 -^fc e •-l.':9 3? 12 - 144 103 0 - 139 74 7 -12o 156 9 34 3 -37 1 13 -1 '. L. -1/ 1 -1 3U - 149 e 224 -2 06 IC 32 0 "311 lb -146 12a 2 -1 40 -1?H 9 -133 to 1 1 201 82 14 -l/i4 -bK 3 -I'. 1 IbS 10 444 Cc3 12 -135 -13/ 13 21 3 -349 15 - 1 '.6 -24 4 -4 -lob - 1 I V 1 226 -73 12 -133 -37 -17 -1- 4 14 9 -3 276 23 5 -3 231 134 13 -137 99 - lo -141 135 — 2 -139 59 -r 2b4 -214 14 -136 -1C5 -15 -J 40 -130 - 1 - 1 4 1 - 1 bS - 1 - 149 -o2 lb - 136 4 4 -14 -13b - 1 V 1 16 - 146 i3 1 - 13 420 427 ^= 7, ^■ 9 1-^- 0. <-■ 0 - 10 2C0 22 1 -1 2 -13/ 133 - 17 -140 -3 1 -1 I 3.0 -37 1 0 -1 4) -69 0 2 7b -^'••^ - 16 254 -2/0 - 10 -129 -85 1 - 1 4 4 - 152 2 -lib 1 19 - le jei 267 -9 22b -72 2 - 139 - H3 4 ICO 130 - 14 43'. 464 -8 bl I 53 1 3 -I': 2 177 6 740 -7?b - 1 3 ^'^ji -430 -7 4 5 2 468 4 230 It 3 8 ?6o 7?'. - 12 22 CI -2b4 -6 433 -4 28 5 -137 -99 10 bb2 -b'.4 - 11 iC^ 305 -3 509 -bC6 6 -1" 1 - 135 12 193 17o -1 0 -129 -121 -4 250 - 2 b 3 7 -137 6 14 -13b 76 -9 - Ii9 - 2^t C _ -a 3t6 4 04 £ -141 66 16 4 19 -370 -e 297 35 0 - ;; -i:;0 ie7 9 -144 12 -16 I9a - 133 -7 -123 -184 - 1 -1 19 -no 10 -1/4 50 -16 -13*' 2b -6 5£7 -613 11 -14fc -5 -14 01 0 -80b _ c -114 6b H= Ot K 5 -13 -143 0 -1 2 7o^ 77ti -4 - 1 1 4 IM 1 - \?. -143 I 3 -IC - 1 ^ V -17J — ^ -1 13 -lib C 190 -326 - 1 J 250 134 -8 - 12^ 62 - 2 - 1 15 1 lo 1 4 49 -.,4 9 -10 - 14 4 0 -t> -lib 89 -1 216 157 2 -127 6 3 -9 2^'0 -233 -4 691 -6U0 3 623 6;37 -163 h'= 8, K- 8 1 - 153 -18 4 8 -135 228 12 -134 69 2 316 -276 9 - 142 189 i I 2y 1 320 0 2 05 1 06 3 - 1£ 1 1 C 7 1 0 -) 36 "55 10 - 1 3"> -113 1 -143 1 4 -153 237 1 1 -131 29 -V i>y9 -I'oO 2 -141 50 -7 -\t2 106 1 2 -1 37 -2 7 -8 - 1 3 o -7 3 -138 6 5 -6 -157 235 13 2 75 - 2 4 4 -7 4 29 4 35 A 212 - ) 9 / — 5 2 14 -59 14 -14 1 8 3 -6 - 1 30 200 5 -139 - 154 -4 -147 -79 1 5 -151 207 --b t)7y -S44 6 269 325 _3 -147 -52 - 1 7 255 -326 -4 -K 3 -S9 7 -141 178 — 2 -15 1 i;d -16 377 215 _ "S "12S 16e 8 -141 -174 -1 - 149 i:-.3 -15 397 423 -2 19t3 —94 9 - 1 4 3 42 - 14 236 -254 -1 - 129 250 10 - 148 -21 H- 9, K = 0 -I 3 265 -268 1 1 -141 -101 -12 -1 J5 132 i>t K= 6 -13 -147 7 7 1 -116 -92 -1 1 2tb -2<>7 -12 -143 -97 3 4 72 454 -10 -135 -10 C -132 36 -11 "133 -88 c 222 -243 -9 190 194 1 -1 :. 7 - 1 e6 -10 219 33 7 325 2 94 -8 -J 28 I 17 i: - 1 3 4 -76 -9 -136 9 4 9 267 -2 50 -7 289 -306 3 -^132 -95 -0 - 1 •'! 3 210 1 I - 1 3 V -15C -6 -124 158 4 - 1 3 7 72 -7 217 147 13 395 3 73 _ f- 723 720 5 34 2 34 4 -6 4 19 -453 15 5 CO -4 93 -4 44 7 -'i25 6 3ia -218 -5 -140 -231 - 17 243 3 22 __ -3 163 -23 7 bI4 -C52 -4 -1 46 1 45 - 15 2 24 -2 11 — 2 229 2?6 6 426 41 9 -3 -142 107 -13 198 2C8 -1 311 -223 S 39 3 32y -2 -141 13 -1 1 -140 -260 10 3J 3 -344 -1 -147 -100 -9 -126 32 h= 9 t K.: = 3 1 1 -142 -66 -7 -126 175 12 -142 212 \^- 8. K = 9 -5 569 -5t>4 0 4 19 4 35 13 -146 -3e -3 -116 1C7 1 3t3 41 1 ■lO -146 37 0 387 -3^3 -1 469 -474 2 190 -168 -13 - J 4 3 135 1 -136 -44 3 -1 25 -89 -14 - 138 - 1C3 2 -111 202 H= 9. K: - 1 4 -123 -30 -13 361 -305 3 -140 I 15 5 -1 33 -127 -12 d^y 152 4 -138 --45 0 -1 19 -157 t - 1 Jl 34 -1 1 3t.7 331 5 -14 6 -224 1 tbZ -ttC 7 -131 58 - 10 2 1 4 -1 6 -138 38 2 £7 1 5 5 3 8 Z-^J - 140 -9 -14 1 - 122 7 -140 31 3 295 250 9 -13b -164 -8 -13C 70 6 -147 o2 4 3 60 -3 7 1 10 -142 229 -7 34 2 -292 9 -147 -6 c -124 -t4 1 1 2C5 2u6 -6 196 if*e 10 -151 .Si 6 236 76 12 -136 - 149 -. f. 3t5 334 -12 -134 15o 7 leo -44 13 -138 -93 -4 -136 - 146 -1 1 -14 5 -35 8 -136 3 14 -142 156 -3 -133 -1 7 -10 -146 -loo 9 E23 £23 -17 -148 67 -2 27t< 212 -9 -143 0 10 4.-" 8 -418 -16 -140 19 - 1 - 129 76 -8 -14 1 10? 1 1 5 24 -514 -15 -135 -25 -7 -144 89 12 2£7 32i: - 1 4 37o 3t)7 ■\- 6. K = 7 -6 -137 -11 13 ;5'i 31 C - 1 3 1 9 5 177 -5 -136 20 14 - 139 - 19 I -1 2 M€3 -443 0 410 454 -4 -13rt -12 15 -142 -134 -1 1 197 -142 1 4 e 6 4 67 -3 259 -223 -i / 2^3 131 -10 -135 0 2 453 -460 -2 -1« 1 1 ^.■) - 16 - 14C - 12c -9 -131 -40 "3 33 f. -373 - 1 -l't3 16 0 -15 - 139 101 -a -131 63 4 -143 229 -14 - ». 3 0 -2 4 -7 183 -187 5 -139 1 I 1 1- 8i K 10 -13 409 "3 -1 8 -13 - 143 193 -10 -152 -121 _ -X it 1 -? Ct 1 - 1^3 -e -12 - 135 20 -9 268 -232 ~ £- 367 -352 2 2 39 221 -11 ~\UZ _ oro -8 -1^2 27 -1 335 371 3 - 1 2 9 156 -10 -137 99 -7 236 lo2 4 - 1 2 i -42 -9 39 0 401 -6 -144 107 H- S. K = 2 <;, - 1 32 -^+3 -a 'J,!: li -308 -5 -142 -6 1 t -13-. 168 -7 249 -25^2 -4 -1<*8 -2 09 0 194 lOo 7 - 135 136 -0 3 69 3 75 -3 - 138 52 1 3ee 36 0 8 -143 -171 168 rv re FC »-c f c f c ru FC v r.7 9 -C 302 -2 -14 1 9o - c - 1 .: 4 142 11. -13t; -^o - I 36 1 -36H - 1 :- 100 l^i ^3V 313 -< G97 -6 11 1.1 I'l a 30? h= 9. K 7 H = S. K 1 0 -J 291 2«1 I? - 1 jn -•9 -2 6 76 700 I I 22 I -13 0 423 398 0 - 1 AO 1 1 -I 299 -31 A IC - 1 ih -1 1 1 AGO -AGO 1 -ICl -<40 -9 -133 2 2 32b -32 7 2 2S1 -A Fl- 10. K. 2 ~e 1 i.st> 21M 3 20A 206 3 Z'^jd 2G/ -7 - 12/ 6;.' /i -l';0 6G A -1 e 1 -21 0 A9A 513 -t ■A7J -46;? & 2A1 -232 G -147 -1 CA 1 -12 1 5 -li -130 J'5 6 -1 Al 161 L -11.0 .- % c^ 2 4G3 -AI9 -/| ;?t:>? 22 3 7 -13t; - 14 1 - fa -147 iVi 3 -13 J ) 12 -3 20 t 7P 0 -1A2 -9G -7 -140 196 A 1 96 1 /I -2 - i;>.i 'i3 9 28 1 22/ _ ''. -142 -7o 5 293 -201 - J -131.1 -rofl 10 - 1 A 4 1 1 G — c - 1 4 V - 1A2 6 -137 59 1 1 2A9 - 1:j5 -A - 1 4 i; 2 7 -136 156 1= 9. K: G -14 2A7 226 . -i ?£A 16A e -liG -t'O -13 - 1 A 2 -65 — 2. - I'lO -IG 9 -136 100 0 6/»7 -S37 -12 -1 AM -12G - 1 21: / - lt-7 10 -134 59 1 19L> -C^O -1 1 -1< J 32 1 1 -139 -120 ?. ^8 3 V2f. -10 -13G -b5 H- 9. K 1 1 12 21u -2A9 3 -131 13V -9 -130 -46 13 2 79 23A ^ - 1 3 L. -203 -n -13o -104 0 324 -23G 1 A -lAV 22 7 f-, - 13/ 133 -7 -137 48 1 340 — - ^ Ij -16 -139 170 C - 1 .'.t -20 -6 -lAA 121 2 284 HT -15 -136 -102 1 - 1 3 / 170 -5 -I A I - 1 AG -A - 1 J 7 20 -lA -132 83 V. " 1 '. 0 206 -A .ii>2 3a6 — 3 -I s4 -7o - 13 -134 91 9 ?/dl - 1«? -3 ~\'\0 -141 - 2 -147 tt -12 -132 32 10 2M -305 -2 A 7 0 — A94 -1 21:6 2G0 -1 1 -136 206 1 > -l -13J5 -41 A 239 -200 10 -136 -lr;o -2 2 74 -219 •10 - 1 3 U - 190 0 - 1 3(> 03 12 260 Al'. - 1 2 1 1 -223 -9 - 136 29 6 -139 73 lA A8 6 -At9 -ft 29 0 337 7 -I'.O - lOo -16 3A0 -337 H= 10. K 3 -V -I 3--. 1 le 8 -lA 1 - 126 -14 -131 1C6 -6 - I 30 -17 9 -lAA 6'« -12 -136 130 C -129 107 - L. - 1 3 3 - 1 7A 10 -lAl — 2 - 10 212 - 19t 1 246 -216 -/( 1 SC -06 -12 - 1 A3 -34 -8 2 19 at3 2 ZiJ, 100 - ;i r/ / 3 1 7 -1 1 -IGO -85 -6 f.0 6 -bl7 3 -130 -1d8 — i: ~\i'\ -lO'o -10 22b -123 -A 6 78 toi A -\.2e. 32 - I - 130 78 -9 - I '. 3 1 CA — ti 178 -23A c; -13-, 21:4 -8 - 1 A 1 172 6 210 29! 1 = 9t K = 6 -7 - I 3 .'J - 1 10 h- 10. K = 1 7 27 3 -32 I -6 - 1 AG -?C'G 8 212 -179 0 - 1 3 1 - to -5 - 1 A 2 214 C 194 -2££ 9 -134 1 19 1 - 1 ■; 'i 76 -A -lA 1 - 190 1 221 Itib 10 2o'* 27 1 i- ^'6^ -2M -3 2 36 -153 C 226 IGG 1 1 -132 -1G9 3 ;'C3 190 -2 462 4A0 ■3 le3 - 1C7 12 -139 -193 ^ - 1 3 9 IflO -I 20 7 -5 4 - 1; S 73 13 -141 51 i> - J-S 1 -9e c - l^*; 1C6 - 16 -1 43 -125 C 2'. 3 -2A? 1- 9. K 9 c ^27 -2G9 -1 b 294 266 7 -1'. 1 170 7 - 12? 73 -1 4 243 216 t' ?'ld 206 0 2G2 -26 1 e 232 3. -.A -13 2 01 -240 9 -i3a 102 1 3A0 3G2 9 -134 -62 - 12 2C0 - lo4 10 - 1 A 3 - 13A 2 - I AG 236 IC 299 -i71 - I 1 36 1 3G6 11 -lAZ 1 79 3 - 1 Ao - 123 1 1 -13G 16ft -10 -13/ 130 12 -lAC -79 A -139 14 12 < 1 1 168 -S -136 -197 -IS -^1A6 -62 5 -lAA 0 13 - 142 - If^S - 6 299 294 ■ \iy 30 1 -23 7 6 -143 23 14 - 143 ~nn -7 -13-5 -n 1 -13 -I 39 G'. 7 -1 A6 2 -1 / -1 Ml 13 -t -12s, -79 -li: - 13'V 1 16 B - 1 A9 -90 - 16 27i £tc _ c 234 266 - 1) - ) 33 -3 -1 I - 1 46 - 133 -IG - 13fc 0 -4 2d3 221 -10 -I 3cl 6 3 -10 -1 Al -GA - l'« -I3t -lf'7 — 3 - 12G -l'»2 -9 - 13/ - 1 73 -9 -\'\\L 140 - 15 - 1; I -t9 -i 369 -430 169 L FC FC L FO FC L FO FC L FO i C - 1 527 SOS 10 213 - 179 -9 -147 62 1 315 -33 1 1 1 -1 42 -235 -a -142 70 2 '2 £6 227 1- 10. K = 4 -14 -141 75 -7 - 14C - <, '; 3 207 235 -13 - I3« 66 -£ - 1 4 4 - 150 4 - 13.: - 104 0 272 -23C -12 -13/ 94 -5 - 1 4 4 71 5 -Ki7 -112 1 279 252 -J 1 -1J4 -113 -4 -144 162 t - 134 lo5 i -130 -77 -10 -M'^ 36 — ^ 243 *• -J 7 - 1 3 5 -102 3 - 132 19 -9 217 -99 -2 -\ ''.'.-, - 2 6 {; 8 *" 1 o 3 z:^ 4 -13S -84 -6 192 2>J -1 - 137 59 9 - 1 3 4 38 5 - I 3 / 721* -7 206 222 10 -1 36 -1 6 •- 1 .i S> 27? -6 -130 -90 H = 1 0, K = 10 I 1 - 1 :• J -137 7 - IJo -54 -5 2t}l -254 12 -141 loO 0 -133 -197 -/, -1 43 15t. 0 -146 -46 13 310 293 9 -131 -?<3 -3 -134 71 1 - 150 63 -16 -14b - 1 4 7 10 2E3 257 -2 2tiU -286 2 -144 1 12 -1 5 - 1 39 -6 1 1 2£>1 223 -1 -139 166 3 -146 -4o - 14 -138 70 12 -13t5 -25 4 -147 -56 - 13 -137 - 168 13 2b6 — ?4 4 2 59 292 0 -133 35 -6 -127 24 -7 -130 -36 5 2 87 250 1 31 'i 29C -5 lyi 13 -5 -1Z6 J30 6 245 -192 £ - 1 3 -'( 41 -4 -126 oO -3 - J 2 4 -26 7 20S -160 3 27 3 -17a -3 -137 -200 -1 652 -66 1 a -131 71 4 -135 -l&4 -2 28 1 2o3 9 -136 -17 5 - 1 3 5 -22 -1 3O0 34o .S — 11, K 1 10 - 1 3 7 48 6 - 1 3 6 6 0 1 1 -138 -4 3 7 -1 3b 178 H= 1 0 . K- 8 0 6 19 657 12 -138 -8 e -133 -8 1 — i 3 C 140 -15 238 2 34 9 '^^■^ -310 0 -139 14C 2 - 13 1 - 163 -14 2 64 -276 10 -1 33 -120 1 37V 435 3 -129 1 I -13 - 135 -113 11 27 1 306 2 2 72 -248 4 -\-iZ 2C - 1 2 -137 -132 12 -144 86 3 -138 -7 0 c 4C^' -420 - 1 1 234 163 15 30 1 -266 4 -136 8d 6 -134 6-'i -10 -135 108 l.^. -137 71 5 -135 -22 7 2<;7 ££3 -9 - 137 -132 13 - 139 ia9 6 -134 104 £ - 13? - 161 -6 -13o -185 12 - 133 -12 7 -14 1 - 146 9 -133 62 -7 -135 -189 1 1 233 -45 e -145 9 10 -13-3 13 1 -6 -129 84 10 21 I -157 9 -143 i\l 1 1 -12a •Lzl -5 -129 75 -9 -130 138 -1 1 -142 -58 12 -1 jt- -e2 -4 46 8 -470 -6 -136 23 -10 -135 1 14 I :- - 144 143 -3 -131 -101 -7 243 - IPC -9 213 160 -16 -i4t; -6 -?. 5J5 555 -6 -130 -213 -8 2.20 -231 -15 2 72 -3C7 - 1 - 13o -226 -5 226 -199 -7 -IJO -124 - 14 - 139 S7 -4 -135 156 -6 - 13a 75 -i:: -137 74 H= 11. K: 4 -3 ecd 641 -5 -13b 200 - 12 -135 -^7 -2 224 -2 12 -4 - 136 -43 - I ! -135 52 0 3 1 1 33 7 -1 74C -73-» -3 - i 3o 57 - IC 2 14 21 0 1 293 250 -2 -140 122 -9 -13; -74 2 34 0 -3 10 1= 10, K: e - 1 5uC - 5 y 1 -E -132 58 3 358 -34 0 -7 iCc 2 26 4 • 336 245 0 -135 63 H= 10, K = 9 -e -130 177 5 - 1 35 102 1 219 -30 — 5 -133 -£1 1 6 -i.i2 -46 2 239 -76 0 273 169 -4 -13 1 -229 7 -130 -43 3 -140 34 1 -1-43 -C.7 -3 /to 7ec a -134 -05 4 -13b -151 2 - 1 46 -o3 "~ £. 230 -23 0 9 199 57 c ^-\ 7 -274 3 -VSH \-* ~ 1 504 -531 10 -137 46 C -1 36 75 A -I4c» -130 1 1 -1 35 -83 7 -13/ 232 5 207 -10 H-. 11. K: 2 12 266 -2 52 e -133 43 6 -152 164 - 15 -140 -d 9 -135 24 t -14a 134 0 - 133 -165 - 14 -143 7 170 r u re KU FC » O FC f O FC -13 20J - lOE 6 J20 -240 6 240 242 -2 -135 148 -ir -1 ;n -/b 7 22 ' 227 7 - 1 J3 -6 7 -1 -13/ -214 -1 1 - 13P 120 a - 149 1 1^' e 1^4 10 -10 3'. 7 365 9 243 - 16/ 9 - 143 145 Hi 12, K = 4 -9 - 13 1 -1 1 -12 - l'^3 7 a 1 0 -1 37 -36 -0 3jb -37tj -I 1 - 1 44 -25 1 1 -141 -34 0 -138 -50 -7 -130 t.6 -10 -143 23 -15 -1 J9 62 1 546 -5C8 -6 -134 -17 -9 - 140 22 - 14 - 14 1 65 2 -135 13 -t. 199 179 -6 - 137 - 138 -13 -133 ZZ 3 -l->5 77 -4 -133 SC -7 -137 -4 7 -12 - 138 -24 4 -134 215 -3 -i:*7 -197 -6 2:*b 228 - I 1 - 13t to f -131 -6 -2 3«-b -394 -5 -137 5 - 10 - 132 - 1 1 1 6 -132 -50 -1 -136 -193 -4 ^^(i - It4 -9 264 -2/8 7 -1 36 ~JZ -3 -130 -3 -8 2'i0 247 e 220 -54 H= lit K S -? -1 4t> :i.i -7 - 13 3 7 1 9 -135 5 -I -140 -207 -e r ec -22?. 10 -142 142 0 41.' 1 372 — c. -- 140 175 - 14 - ! 4 5 17 I - 1 36 - 1 10 H- 11. K = 0 - 4 34) 2SM -13 26/ -ao 2 -13b -116 _ -3 -1 34 -151 -1 2 -1 JV CO 3 269 -250 0 2 39 210 -2 t?c> -c5o • 1 1 - 139 100 4 -1 J9 -125 1 -141 - 1 t.4 - 1 - 1; 1 5 -10 -13/ -75 £ -13t 127 2 - 1 4 4 - 1 16 -9 -130 - 193 Ti -I -16 17C 3 -144 24 H- 12. K = 2 -8 305 •-22r. 7 - 1 J2 ee 4 - 1 4 5 J 13 -7 -134 47 a -mtj - it;4 5 - 1 4 3 -39 0 P35 -824 -6 31 1 270 9 -14 2 -53 6 -I 49 120 1 -13'^ Z?i -5 - 139 214 10 - 1 4 / 156 7 -143 -58 2 - 132 40 -4 -1 40 -206 1 1 ZT. 1C7 -10 -115 9 7 3 -134 -173 -3 4 08 -4 A 9 -14 2J4 170 -9 2?o -1^0 4 -139 109 -2 -138 -4 1 - 13 -143 -5 -P - 1 46 "124 c - 13 1 34 -1 V94 810 - IZ 2L3 -219 -7 264 194 C 191 -155 -1 1 -13 7 - 137 -6 -130 -25 7 -136 -44 h= 12, K' 5 -10 -1 3U 19? -5 -13a -64 8 - 1 3 6 1C7 -9 -137 172 -4 -142 91 9 -13'4 0 0 225 161 -t -140 03 -3 -1 ':0 -75 10 - 14£ - 1 Ct A - 13 1 72 -7 -134 -IC'o -2 -141 -09 1 1 270 2Cd 2 -137 - 190 -6 -133 55 -1 -1 40 125 -15 -142 -oi 3 -135 -69 -5 -132 -5 -14 -l'«2 -14'* 4 -131 45 -4 - 1 J ■» 159 H^ 11. K = 9 -1 3 - 1 3 9 5 5 -1J7 17o - J -137 -3 -12 -13/ 1 18 6 -142 -95 -2 t.9ti -066 0 -145 - 104 - 1 1 -134 -0 7 27 9 -250 -1 43 1 426 1 -142 -43 - IC - i;3 -83 8 -137 46 2 - 140 123 -9 - 1 33 1 1 9 -150 I 12 H= 11. K: 6 3 -140 -97 -6 -134 -80 - 13 -149 19 4 -Me -61 -7 -13-'; -•; 1 -12 -14: 0 0 i^f.B -S23 -7 -149 - 1'j4 — t -134 153 -1 1 -13o -3'J 1 2t2 24 9 -6 -\^(y ■~^ r! -5 -130 2 -10 201 107 2 3o3 354 -5 242 226 - 4 2 le -lt7 -9 -136 -I 3 -139 -E6 -4 -141 -15 — 3 -134 49 -8 219 -85 4 31 4 -33o -3 214 -151 -2 tiCt fcl 7 - 7 - 130 - 1 o6 c -136 9 -2 -1 '*3 -29 - 1 £^7 -te 1 -6 -l3o l^^d 6 -136 19^ -1 -144 190 — t -136 222 7 22 '3 -96 H= 12 . K 3 -4 -138 -10 e - 140 -53 H- 12. K = 0 -3 271 -33 7 9 -143 -f.l 0 -138 139 -2 J69 -35 1 10 -149 6 0 94 7 991 1 2 12 - 179 - 1 356 257 -13 -14.^ - 1C3 2 -133 - 1 34 2 -141 -79 -12 -143 6 3 4 - 130 333 3 -136 -30 h = 12, K^ - 6 -1 1 -13b -3 6 2ij0 -218 4 -135 5 7 -10 -i3o -58 S - 1 3 / 3 C. -137 -101 0 -135 -72 -9 -13tl ao 10 -143 1 86 t - 1 33 -4 1 1 390 397 -0 -134 35 12 294 - Jb7 7 192 4 6 2 -135 -126 -7 -13£ -67 -14 -1 Jt. 43 8 -13o -61 3 207 -195 -6 21 1 -131 -12 195 13/ 9 -135 -9 4 -130 141 -5 -131 -41 -10 -120 -1 10 - 139 lo 5 -14 1 30 -4 -136 179 -8 -135 - 158 1 I - 146 - 162 fc 289 -153 -3 -ijy -12a -6 -131 j-9 -14 - 1 tt* -119 7 -147 1 I d -2 3Z'o 291 -4 3t30 3o9 - 13 2C3 173 8 -148 -66 -1 -137 -53 "" £. 1112 - 1 C95 - I < - 134 3 -12 -143 -10 - \ 1 - i3e -o -11 -139 -Ol H= 11. K- 7 h- 12, K^ 1 -1 0 -129 7d -1 0 -140 1 1 -9 3C9 -2 73 -9 214 203 0 263 256 0 -130 104 -8 - 1 3 9 -153 -e 2Co -1^^3 1 -137 170 1 -131 -o2 -7 3 17 3 37 -7 -139 0 2 i'90 -3CC 2 -131 4 9 -o - 137 1 74 -6 -14 5 2o5 3 -139 5 3 2'.y 207 -b -136 -2C7 • c: -134 -154 4 -137 145 4 -130 -loi - 1* 2 to -2cl -4 -134 32 S -140 -124 5 -loo 1 12 -3 42 1 423 -3 -137 36 171 FC PC FO rc FC FC FO FC -2 192 73 H= 13, K: 0 c -134 -177 2 -135 -4 1 - 1 304 -2o3 t> -I 39 -16 3 -1 '^O -20 1 -135 -86 7 2 59 292 4 • 195 124 H- 12. K = 7 3 202 96 a - 136 -51 5 230 - 13 5 -135 16/ 9 223 - 156 e -14 1 -206 0 193 128 7 207 - 190 10 -l/!3 46 7 -14 1 -7 7 1 200 -106 9 ^l^ 160 -13 -136 1 lb e -I4'i 1 2 5 2 -143 127 -13 ~l 40 32 - 12 - ) '! 3 - 12o 9 - 1 4 3 4 6 2 205 135 -1 I -13o 38 - 1 1 190 - 16o -12 -145 100 A -142 -67 -9 -134 -lOo -10 -133 187 - 1 1 -140 4 4 t -1 '';3 -46 -7 -134 0 -9 - 13t 9 9 -IC -140 -153 0 - 1 4 t. 141 -5 -13i1 36 -8 -136 -150 -9 264 204 7 -14 c. - l<^ -3 6d3 -674 -7 -134 99 -e -136 7 J -10 - 1 A 4 7 -1 430 44 2 -6 - i;c 39 -7 194 -20 -9 -147 - lf'4 -5 390 -3 7 0 -6 -133 154 -e -14 0 17 V = 13. K: 1 -4 233 143 -5 -140 -245 -7 2 00 270 _ -a ece £52 -4 400 -404 -6 -1 4 C - 1 CO 0 -132 - 139 -2 344 -286 -3 230 106 -5 -143 -109 1 -133 1 17 -1 -138 -173 -2 4C6 42d -4 -130 144 2 -130 65 - 1 2fcti 195 _ a 201 164 3 265 -2 64 H= i;. K= 3 -2 -134 - 1 0? 4 -135 19 1 - 13, K: = 5 -1 -137 -72 5 2 9 is 294 0 202 -223 6 -136 - 179 1 - 1 3 3 - 117 0 -135 -99 h- 12. K= O 7 -135 -12b 2 -137 150 1 -139 -143 8 209 1 1 1 ^ -136 29 2 -135 54 0 2S8 -195 9 - I3a 24 4 2? t -249 3 - 136 153 1 232 - 135 10 - 1. 4 6 -37 5 - 134 -74 4 24 0 223 2 -14 7 6 3 -14 - I 46 -83 C 213 246 5 -138 -60 3 - 14 1 28 -13 -139 5 5 7 -14C - 16C e 290 -29G A -14 4 -42 -12 -139 1 06 a - 14 1 t5 7 -14 3 1 1 1 5 - l£<0 171 -1 1 -136 - 19b 9 - 1 4 4 64 8 257 99 -8 2e>'.- 14 3. -10 -133 -16 -13 -138 -33 - I 1 -142 -1.^ -7 - 144 - 1 0 n -9 266 296 - i:? - K^9 123 -10 -14 1 149 -C -143 2tJ -0 -130 -6 -1 1 -1^1 109 -9 -140 66 -s -140 144 -7 -130 -1 lo - 10 - 1 3 9 -137 -8 - !43 - 2 6 4 -4 -14') -194 -6 -132 -2 -9 ' *" 3 -289 -7 -l'i2 6 0 -3 27 0 -10? ~r> 271 1 6 9 -8 -135 210 -6 3 1 a 2 1 8 70 74 -10 1 9 5 194 9 229 210 1 1 95 95 9 68 63 -9 1 1 1 11 0 10 •JiJ r.e 12 -12 -10 - 10 131 13o -8 385 367 11 ;;30 2?9 ~l 2 OCJ 69 -9 92 91 -7 231 22 3 12 103 lOE - t 1 -12 - 16 -« 101 99 -6 414 384 13 43 39 -10 42 -44 -7 75 70 -5 24 25 _o 135 133 — 6 140 141 - 4 31 1 3C0 H = Ct r- 1 -G I 17 15 7 -5 206 2 04 -3 30 ~z\ --7 1 I 0 113 -4 178 1 78 -2 4 3 4 5 0 6t>l 636 -6 15 23 -3 2 28 228 -1 653 62 7 1 42t> 400 -5 23 '► 233 ~2 1 90 188 2 34!> 3C9 -4 173 163 -1 1 85 189 h- 1 . K= 1 3 17 :■ If.'. -3 41 2 9 4 235 -217 -2 304 -292 H= Ot K- 7 0 238 -229 5 172 161 -1 239 -225 1 99 94 6 31S -270 0 76 78 2 315 -301 7 226 191 H- 0. K: 4 1 27 28 3 1 10 -1 15 e 101 105 2 59 56 4 343 330 9 6C 54 0 21 1 199 3 124 123 5 72 -6 1 10 190 193 1 104 191 4 97 100 6 223 217 1 1 ai 83 2 333 332 5 54 46 7 34 3 2 12 17''. 177 3 23 b 224 6 -1 1 0 8 2 87 281 13 2/ P! 4 202 201 7 32 37 9 -11 1 1 -13 53 :,7 5 32t4 32 9 8 1 10 11 2 10 127 127 -12 44 -48 6 132 131 -9 -12 2 1 1 1/ 3 2 -11 10 I 103 7 204 199 -3 - 1 1 10 12 -12 -4 -10 -I A 15 8 6 0 67 -7 -1 1 -2 -13 -12 14 -9 67 -6? 9 138 13o -6 -1 1 -7 -12 6 0 60 ~S -12 -8 1 0 60 58 -5 69 68 -11 100 99 ~7 31 1 1 1 132 137 -4 214 21 1 -10 144 1^8 -6 S&5 51 9 -12 104 107 -3 242 247 -9 175 -173 -5 231 216 -1 1 104 105 -2 126 128 -8 166 177 -4 349 337 -10 146 147 - 1 CI 64 -7 55 53 -3 103 - 103 -9 224 230 -6 88 69 -2 G4 -73 -8 75 7<3 H= 0. K-- 8 -5 le4 -164 -1 443 431 -7 194 190 -4 399 -370 -6 160 Ibb 0 104 11 1 "• 3 285 292 H= Ot K- 2 -5 210 214 1 67 66 -2 176 -174 -4 2b3 205 2 93 99 -1 426 421 0 475 -471 -3 31 30 3 1 I 1 112 1 394 367 -2 21 19 4 1 03 lOu h- 1 . K:: 2 2 299 279 -I 1 12 -102 *; 54 97 3 20'' IHK 6 VO 90 0 413 39 4 4 14c. 13 1 H= 0, K= 5 -7 83 83 1 59 53 5 40 -36 -6 £1 62 2 41 1 392 6 4f-7 .'■6 4 0 -1 0 a -5 7 9 78 3 fcl 85 7 2C9 256 1 271 26 6 -4 193 1^4 4 28 4 260 e 3^0 303 2 193 190 -3 2C0 282 5 37 38 9 1 1 5 1 14 3 89 9 4 « > 2 73 .'iV6 6 241 225 10 297 291 4 58 54 -1 192 193 -? 194 lud 11 74 78 5 138 140 0 213 2 '04 12 91 67 6 93 91 H= C. K- 9 9 322 323 -13 34 38 7 21 28 10 81 79 -12 52 47 P 59 -61 0 -11 5 1 1 70 7? -11 36 38 Q 51 -49 1 -1 1 17 12 78 -78 -10 102 IC3 10 28 26 2 26 30 -13 74 7 4 -9 -1 4 21 -1 1 92 94 _3 26 24 -12 145 151 -8 23B 24 1 -IC 195 196 -2 45 45 - 1 I 1 1 0 1 13 -7 67 73 -9 90 93 - 1 26 29 -10 ZA -27 -6 4t'6 472 -0 16 -9 -9 146 l«4 -5 547 51 2 -7 20 -16 H- 1. K = 0 -a 126 132 -4 476 iii-O -6 61 6 0 -7 269 266 -3 4 0U 4 50 -5 60 5 3 0 1-99 676 -6 1 AO I -13 -2 2 3b 228 -4 34 -30 1 2^0 2«2 -5 159 11,0 -1 67 3 660 -3 73 -72 2 4b 40 -4 44 -37 -2 36 4 2 3 671 651 -3 306 323 H = 0, K- 3 -1 25 - 19 4 337 324 -2 300 2 9t> C £2C 491 -1 302 2 'J 4 174 FO FC FO fC ro rc i (I rc -6 127 135 H- 1 , r = 3 H = 1 . K= 6 — 5 175 175 0 24 4 232 -4 ia3 1 »■ 7 1 •1 til 106 0 1S{. 159 0 22 1 225 -3 1 66 173 2 3'.-) 3c) 4 1 23/ - .'. 3 1 1 : '^4 KI2 - 2 1 C4 1C7 3 '.J I 4 --•7 2 1 46 140 2 166 lo6 -1 63 65 4 1<;4 )i.6 3 .- 1 19 4 33 3 7 4 Itttt rV7 H= 1 . K = -7 6 1 t 3 195 5 130 127 5 244 233 7 1// lOJ 6 1' C -14? 6 i;4 151 0 22 24 8 1 1 1 1 13 1 IS 7 IbD 7 37 34 1 30 33 9 12c. 1 17 a - I 1 -1 2 8 102 lO-i 2 63 6 3 10 75 60 9 l^O J 23 -10 105 104 3 107 107 1 1 2 2 26 10 <>6 68 -o 72 69 4 33 2 9 - 12 105 109 1 1 -1 1 9 -8 30 26 5 16 - 12 -1 I 1 1 4 1 15 - 13 'Jt, 99 -7 1 13 1 10 6 38 42 -10 71 7 5 - 1 i: 10 1 10? -6 2c.0 25? 7 100 1 C :•■. -9 170 168 -I 1 - 1 I 10 -5 309 314 e 99 104 -8 133 134 -1 0 1 OH -1 09 -4 246 240 -t 93 93 -7 -1 1 -2 -9 1 J-< 137 -3 1 tt, 175 -7 41 42 -6 262 251 -e t>0 47 -2 160 150 -6 40 35 -5 24 5 229 -7 9f. 96 -1 152 15tJ -5 36 35 -4 350 334 -6 -1 0 15 — A C2 66 -3 2 14 20 7 -r. 2 0 ?fi h= 1. K = 7 -3 45 40 -2 194 193 -<. 2e.7 249 -2 46 -4? - 1 3i:i 380 -3 13 1 - 132 P 53 59 - 1 22 -11 -2 1 t16 17« 1 16 - 14 H- 1 . i;= -3 - 1 loj 177 2 - 1 ) - 5 H= 1 . K= -6 3 4/ 47 0 629 -617 H- 1 . K = 4 4 52 52 0 134 14 1 1 7 1 66 c 56 58 1 22 9 225 2 198 192 0 29 H 295 C - 12 0 2 24 2 24 3 3 37 5 361 I AO-. 400 7 93 10 1 3 1(5 165 4 314 297 2 23 J 2 30 -9 -12 15 4 124 12/ 5 59 -53 3 294 204 -a -12 -1 7 5 120 I'- 5 6 70 6 7 <( 246 24 4 -7 30 -28 fc 9r 10 1 7 3o 36 6 20U 203 -6 22 -20 7 1 13 1 1 4 8 1C9 162 6 K.2 13<: -f. 36 35 P 1 12 11 1 9 -1 1 3 7 1 1 3 1 10 -4 79 80 9 62 t.b 1 0 - J J -9 e 2<3 24 -3 6fl 64 10 1 3 4 136 1 1 -1 1 -19 9 il. 22 -2 h2 D2 - 10 1 1 J ) 12 12 2 8 25 10 i«a Ibl -1 7/ 75 -9 03 85 -12 62 62 -12 t.3 P6 -8 97 94 -1 1 10 -21 -1 1 6t. e.4 H = 1 . K = 8 -7 12 1 123 -10 1C2 1 05 -xo J ■• f! 127 -6 Vt) 7 2 - 9 -1 1 -12 -s isr 1 ?7 0 95 98 -5 1 1 «: 117. -0 V9 82 -e 2 2 '■. 232 1 1 14 1 16 - 4 1 4 1 14 1 -7 40 36 -7 2C.6 267 2 1 14 1 15 ' -J 1 29 125 -6 231 219 -6 2aJ. 291 3 ic^ 107 -2 73 70 -5 1 06 103 -5 2'o'i 251 4 100 93 -1 75 76 -4 439 421 -4 23 1 240 -7 62 8 0 -3 042 507 -3 1 14 1 17 -6 6 3 63 hi= 1 . K = -5 -2 289 263 -2 32 0 319 -5 54 52 - 1 265 26 1 -1 490 4e9 -4 a4 87 0 99 9H -3 149 l4o 1 £5 55 H- 1 . K= -2 H- 1 . K 5 -2 1 19 122 2 145 143 -1 02 83 3 15 17 0 1 06 - IC2 0 102 140 ' 4 -10 3 1 41 1 392 1 314 31 3 h- 1. K- -9 C 62 61 2 3 "^ 5 328 2 136 135 6 40 3b 3 1 r3 164 3 3^J 44 0 66 68 7 20 32 4 503 4i'2 <) 1 j;. 13? 1 1 1 ti 1 1 9 e 37 -42 5 283 270 5 9l5 94 2 64 83 9 68 66 6 405 396 6 18J 1 79 3 21 15 10 7 7 79 7 1 la I 16 7 99 - lOf -3 36 :i7. 1 1 37 40 a 191 189 e 46 -4 4 -2 34 37 - 1 i 1 16 124 9 2 04 2C4 9 iiC S'. -I 25 24 - 1 0 4 6 44 10 31 29 -11 38 37 -9 71 Cti 1 1 /o 73 -10 71 76 1-'= I. *.- -0 -6 - 1 1 -7 12 41 45 -9 -1 I 0 -7 41 -4 I -1 ? 3 5 35 -a SO ^3 0 lo-.- 1 10 -0 7 5 -6« -1 2 1 06 100 -7 1 7 9 175 t 147 154 _ t 72 6 9 -I 1 :>7 57 -6 298 302 7 174 177 -4 -1 0 -2 - 10 206 201 -5 244 24 1 3 1 80 1P6 -3 1 7 -15 -9 254 24 5 -4 20 -1 1 4 1 36 139 -2 la 1 1 -0 197 193 -3 -■9 14 5 1 DO 10 1 -1 48 -51 -7 4 36 404 -2 13 4 6 122 123 -6 23 26 -I 67 76 7 131 131 H- 1 . K = -4 -5 312 29 J 175 FO rc FO f-C FO FC ro FC -4 4.?1 3P4 -11 I 77 178 - 1 1 - 1 1 2 -5 62 64 -3 1149 1 C^7 -1 0 -12. H - 10 CO 61 -4 137 132 -?. 130 1 1 2 '- 0 -9 42 44 -9 170 173 -3 2 09 2 15 -1 lb9 16 7 -0 48 -4 2 -8 34 ,J 3'>9 -2 1 ■-. -> 143 -7 97 102 -7 344 349 - 1 63 83 H- 1 . Kr -1 -6 87 -05 -6 2t3 260 -5 24 -14 -5 2^4 i.91 H- 2. K= -9 0 874 P5? -4 56 52 -4 179 180 1 t.7 -CO -3 355 384 -3 2 16 224 0 22 16 a i:^0 1 10 -? 9o t;8 -2 90 67 1 -: 1 4 3 1 1 2 11 2 -1 94 -C4 - I 171 175 2 26 -26 4 B5 -71 -3 33 31 f. 4 0O 38 3 H= 2. K= 2 H~ 2, K= 5 -2 38 33 6 19 23 -I 17 16 7 130 135 0 441 445 0 35 35 8 -I 0 20 1 1/2 lei 1 64 62 H = 2. K= -8 9 225 ??? 2 232 275 2 9S 102 10 46 4 5 3 24 4 23d 3 1 12 106 0 79 8 1 1 1 1 0':> 1 DVt 4 107 -100 4 149 156 1 79 h.i 12 87 92 5 147 153 5 212 21 0 2 96 ICO -13 '-J 4 0 6 1 80 - 177 6 leo 150 3 1 14 1 13 -12 18 -6 7 271 266 7 43 38 4 101 103 - 1 1 62 61 8 1C7 189 8 73 69 5 1 15 113 - ID IS 24 9 16'4 159 - 1 1 23 23 6 130 132 -9 359 35° 10 80 6 5 - 10 - 1 1 6 -7 IC2 105 -8 lab 176 -1 3 9S loa -9 27 32 -6 120 120 -7 316 302 -1 2 7 b 82 -6 32 29 . ti 82 83 -6 68 -88 -1! 163 167 -7 1 17 121 -4 69 7 2 -£. 45 -30 -10 77 60 -6 104 102 -3 85 85 -4 47 -5? -9 265 269 _ r: 63 6 5 -2 90 102 -3 18 3 -8 141 147 -4 49 46 -1 106 100 -2 734 66 6 -7 184 178 -3 -10 -6 -1 loe -177 -6 17l- 162 -2 24 -26 H= 2. K= -7 -5 88 95 -1 79 -80 n- 2. K= 0 -4 6 79 670 0 37 35 -3 531 56 4 ' H- ? , K- 6 1 4 6 51 0 ?6 4 232 -2 672 646 2 57 62 1 -4 43 46 -9 35 3 3 -12 -12 6 -3 35 28 K= 2. K^ -6 -e 19 3 ICo -1 1 47 -49 -2 179 169 -7 18 -4 -10 62 7S -1 161 132 0 407 415 -6 22 13 -9 1 99 197 1 316 313 -5 272 256 -8 304 3iq H- 2. K= 7 2 165 162 -4 94 -35 -7 1C6 1 09 3 1 19 122 -3 368 350 -6 5o 64 0 38 34 4 152 155 -2 56 5H -5 63 65 1 59 63 5 156 165 -1 534 £24 -4 203 20 1 2 1 16 1 1 5 6 73 7 1 -3 192 192 3 124 129 / 46 42 H= 2. K = 1 -2 269 266 4 3R 39 a -11 7 -1 335 374 5 57 -54 9 22 29 0 64 8 63 7 -8 -11 6 -10 92 95 1 188 176 K^ 2. K.= 4 -7 - 1 1 -6 -9 10 3 106 2 20 1 194 -e - 1 1 -4 -8 155 157 3 170 - 150 0 92 96 -5 - 11 -U -7 167 165 4 24 -18 1 258 254 -4 50 -50 -6 • 63 90 5 101 -9R 2 300 306 -3 21 15 -5 I 17 113 6 22 -21 3 231 2 37 -2 66 68 -4 100 97 7 82 83 4 25 3 2>i2 - I 43 4 5 -3 1 17 1 15 6 4H 46 5 46 47 -2 126 1^4 9 78 n? 6 340 332 H- 2. K-t 8 -I 1 76 175 10 1 1 6 -117 7 168 169 11 56 56 8 14J 1 4t> 0 74 76 H= 2. K= -5 - 13 -12 -P 9 169 173 1 75 77 -12 40 43 -12 62 62 2 109 109 0 364 370 176 L ro PC I. FO FC L ro rc L FO FC 1 235 230 1 38 3 36a - 1 1/6 1 19 h = 3, K = 4 2 126 124 2 326 3ie J 3 20 1 '. 3 2SIO 2ti3 H- 3. K = 1 0 255 207 4 2'.< 1 1 4 121 1 1 t> 1 152 155 S 69 t.9 5 45y 439 0 393 376 2 152 156 C 20 -14 6 243 250 1 f 7 66 3 1 1 1 1 11 7 A2 -4? 7 2i'0 282 2 i4a - - 139 4 120 110 e 36 _-.9 8 I /^ 1«31 3 69 96 5 19H 204 9 27 21 9 24 i 2-5 J 4 -10 9 6 233 233 10 6 6 fc9 1 0 I OJ 9c» 0 372 374 7 1/4 179 1 1 C9 6 9 t I IOC 10b 6 AS -47 8 38 41 10 3fj :^4 -13 C>5 73 7 I'^l 1^2 - 1 1 4 2 42 -9 39 3'.. -1 ? b3 55 t! 9 b 9 3 -10 - 1 1 -6 -li OO f 4 -1 J 1^4 1 I'O 9 -1 1 12 -9 103 105 -V ^:j 4 fi -10 l.'J 123 -13 C-6 6 7 -e f.O 03 -6 239 23=. -9 JnO 3 62 - 12 1 lb 117 -7 100 99 -b 199 icq -8 1S2 143 - 1 1 290 29 0 -6 74 y-j -4 05 £4 -7 2*1 23b -10 135 147 -5 161 ici -3 43 -J*? -6 J 4S 149 -9 1 14 1 06 -4 310 314 -2 96 ■ -100 -5 t /o 163 -8 22 22 -3 172 172 -1 220 220 -4 440 406 -7 t4 63 -2 152 150 -3 ?•>"• 2 59 -6 173 1 7o -1 171 173 1- 2. K= -4 -2 <0i^ 3tf 1 -5 17 12 -1 3'»9 -34 1 -4 324 319 H = 3. K=^ 5 0 128 121 -3 67 52 1 234 229 H= 2. K- = -1 -2 137 124 0 143 107 2 329 32 3 -1 97 99 1 132 133 3 233 230 0 31? -310 2 39 -40 4 190 193 1 2 4-'. 232 H= 3. K= 2 3 25 -24 5 65 63 2 173 16 1 4 4 b -t^ 7 6 203 19? 3 3 1 ':< 31 4 0 2 96 Ti'il 5 72 73 7 146 148 4 I I 6 1 13 1 3. J .i-f^ 6 4 b 41 e 104 103 5 A 1 r 4 09 2 1 81 17b -10 3 .'. 1.1 9 91 «7 6 20L, 194 3 1 til 170 -9 I' ? 3'. 10 153 104 7 5t. SI 4 232 237 -G - 1 "1 I 7 12 14 j 152 8 b-'V 59 €\ leo 17H -7 27 27 1 1 loe 1C9 9 t.i -70 e 10 0 166 -6 21 21 10 120 12 9 10 C-. 64 7 22a 222 -b 64 58 -9 '.O 3E t 1 3* 33 8 24 1 24a -4 91 96 ~ti 08 63 -13 100 101 9 34 3i -3 7 7 -74 -7 1 19 119 -12 -1 1 -1 1 -13 49 50 -2 22 22 -6 473 '55 -1 I z:-- -21 - 12 92 90 -1 90 99 -b 679 •.'74 -10 zz 107 - 10 30 1 ^03 H= 3. (-.= 6 -3 2d0 26 7 -8 9 a 92 -9 1/7 179 -2 lti7 176 -7 li.? - 145 -C 222 22 5 0 139 136 -1 b'la 54 9 -C 7V 79 -7 121 121 1 196 199 -5 24 -1 0 -6 151 156 2 171 169 1 = 2. K = -3 -4 I 7 15 -5 75 80 3 108 1 12 -3 2 3't -230 -4 147 141 4 24 18 0 138 -13 3 -2 ? '■ .^ -206 -3 281 :.03 b - 12 -5 1 -9 4 -1 2CU. -203 -2 225 217 -9 107 102 2 73 70 -1 495 401 -0 90 69 3 36 31 H= 3. »t= 0 -7 121 lis 4 05 rv H = 3. K= 3 -6 li.7 1.6 5 30 -24 0 479 466 -5 21 1 200 6 24 1 24 1 1 97 99 0 73 77 - 4 b8 56 7 233 221 2 6:J 105 1 I 4b 14C. -3 4 b 44 e 1 19 122 3 23 23 2 2 59 260 -2 lOC 102 9 136 136 4 149 151 3 55 59 - 1 99 101 10 77 75 5 30& 3 08 4 1 75 172 11 106 10? 6 2iC 245 5 30 -3b H- 3, K- 7 ■12 10 --10 4 -7 109 1 13 -7 131 13? -7 I 3(-> 131 -4 70 -72 -6 91 91 -6 190 ise -A 212 221 -3 91 54 -5 1 lO 1 15 -5 1 04 104 _e-, 242 233 -2 10/ 105 -4 - 1 1 - 1 7 -4 -10 0 -4 362 354 -1 312 315 -3 78 -G 1 -3 32 -2 3 -3 270 263 -2 -1 1 -7 -2 42 -36 -2 216 214 H = 4, K= 2 - 1 84 85 -1 17b 171 -1 290 2 75 0 196 201 H- 4t K- 6 1= 3, K^ -4 h- 3. K= -1 1 137 135 2 290 2 93 0 145 146 0 266 256 0 192 - 186 3 Its 167 1 1 1 1 109 1 214 210 1 47 -33 4 293 296 2 14t> 140 2 264 271 2 47 -50 5 -1 1 10 -7 1-^9 151 3 253 250 3 123 -110 6 47 46 -t 175 177 178 ru FC FO FC HO FC f O FC », «, 127 133 5 - I 1 - 14 -O 92 91 -7 -1 1 -6 -A -J? lb 6 -I 1 3 -7 1 '^l 184 -6 48 -58 -:i f.I 4 7 I 82 06 -6 195 196 -5 IOC -99 -? £1 y 84 -1 1 11 V 1 19 -5 lo6 163 -4 133 129 - 1 1 1 0 1 1 1 -10 37 39 -4 10 > 102 -3 131 134 -9 103 101 -3 1 2 1 1 19 -2 86 04 n= 4, K- -b -n- 9 7 98 -2 1 ti :> 1H2 -1 39 35 -7 129 127 - 1 If 6 ■ - 169 0 S? 0 0 -6 149 14r3 H- 5. K = 4 1 121 12 1 — «■, 68 71 M = E. K = 0 — 1> U'J <11 -A 149 149 0 125 132 -A, I l 1 74 -8 108 1 13 -1 8t> BO 3 li3 84 -7 62 69 F = ■< , K = -3 4 93 93 -6 34 29 H- A , »■-:- -7 5 94 102 -5 123 124 0 VO -65 6 125 12o -4 152 149 0 ^,<) 4P I 1 7 12 -1 I -12 14 -3 1 o5 lt>3 1 tt' fi9 2 122 123 - 10 l<.o 147 -2 16b 167 2 1 1 2 1 1 4 3 1 17 12 2 -9 1 1 1 1 16 -1 lo3 164 3 eo 7h 4 -1 1 -20 -8 144 144 A b6 53 & Ibl -146 -7 119 124 1-' = 5. K= 5 -V b9 66 6 6« -76 -6 200 191 -t. 30 29 7 49 53 -5 319 321 -6 23 30 -5 A? 40 8 99 100 — 4 123 12 0 -5 54 56 -/f 59 61 -1 2 OS 87 -3 t;7 87 -4 61 62 -3 76 77 -1 1 2 b -25 -2 95 92 -3 69 89 -2 2f. 20 -10 17 19 -1 163 ia4 -2 9b 9t. -1 -1 1 -3 -9 69 66 - I 1 r,7 105 -O 125 127 H= 5. K- 1 H- A , K- -6 -7 57 59 H = 5, K= -7 -6 -I I 5 0 22 1 1 0 1C7 lf

I -3 107 lOd 0 l»5 18t> -10 1 « J 140 0 -1 I 2 -2 1 4t> Ibl 1 16:' 16S -O 1 79 1.» 1 1 10 1 I 1 hi-= 5. K= -4 0 2t.7 26 8 8 37 42 2 26 20 1 271 27li -1 2 4t> 45 3 51 45 0 210 214 2 227 23A -1 1 47 52 4 36 3-i 1 169 1 t<8 3 132 127 -10 21 19 -S Sb 94 2 1 29 Ko A Ab -40 -9 121 129 -8 64 61 3 57 62 379 L PO rc L ru FC L ro FC < 1 Hi 1 1 2 -5 2ie 221 -7 2 3 2 5 5 1 19 122 -4 307 30 8 -6 1 4 6 1 5 3 - 10 16 V J f. 9 -3 223 22 5 - 5 7 0 6 7 -y 1^9 J. -^4 -? 216 219 -4 17 1 -U ip-y 129 -1 165 J 65 ~3 P.3 "2 7 -7 ion ]Oft -2 "1 1 6 -U l^ti 149 H- 5, K.-r -1 - 1 ~ ', 33 -b 9ii 9 7 -4 OA. 6 2 0 1 2b 132 H--- 6 , K.= 2 -3 3 0 31 1 215 21 3 -2 27- 2 7 2 73 71 0 1 2 7 1 2 7 -1 172 16 9 3 75 77 1 2 16 219 4 21 -30 -7 80 0 5 H- r.. K= — 1 5 140 14 5 -6 120 1 1^ 6 10'; 102 -5 7? 7o 0 lAl 139 -1 1 -12 5 -4 1 4 9 146 1 136 1 3P -10 20 17 — "> 12/ 1 :r) 2 iby 160 -9 25 25 -2 1 0 ■■; 102 3 6>1 (M -c -1 1 15 - 1 1 4^ 1 -. y A 71 7? -7 25 I« 5 y «4 05 -10 79 75 -3 139 140 -4 1 00 100 -9 hi H^. -2 127 127 - 3 142 137 -e 'oG 07 -1 tJ4 as -2 94 95 -7 '^U 61 -6 30 23 H= 6, K- 0 t;-=: C t K.- — li -5 1 I 0 1 I 0 -^ A'^ 4 5 0 I 1 I 1 16 0 98 100 -3 If. 3 1 35 36 -6 44 4 6 -2 43 3C 2 1 05 10*3 - 5 - ) 1 6 -1 ISG 167 -5 95 94 -4 26 2 0 -9 64 6:'. -3 54 52 H- 5. K=: -2 -G BO B2 "2 5 7 5 7 -7 151 147 -1 95 9 4 0 2^6 24 0 -6 2 16 2: 9 2 37 2, K = PA 7 26 9f. 73 FC 3?3 - !C0 ?63 -?ft2 0 -?'i 1 ??? ?? 77 K- C e e 0 6 3M 130 ?6 1C.9 0 9 6, b31 13 1 -J 8 SB -22 e. K 29 0 6;.- <5u3 &0 AC - :?q7 3i". - I r:.c. sets i;= 10: K = 0 b't 2 3?/j 4 239 6 Ab e -2 i 09 6P -- 2 0 39 C 1 A . i: -1 a -1 9 22? 79 r.-';0 i;25 1 26 - 30 14 -r9y f-3 ^3 -41 ■3?5 ??9 -*. 5 10 ?3 - 4 C2 -5A I 233 -e? 16, K = 0 2 0 2 I Oh -2 1 -21 IP. K = It.V bl -22 - 1 ^2 -16 3 0 2 FO 20. K: 32 «22 FC 20 85 -21?, K= 7 - b 0 1 6 5,?3 0?4 C IC.i ■i'7 10 St! -24 H= -2. K: 2 4 6 8 1 0 H=; H = 0 1 2 3 4 c 7 8 9 10 0 1 2 3 4 c: 6 7 8 S 10 0 1 2 3 4 5 6 7 e 9 0 1 2 3 4 5 e 7 8 9 ICVl 3 <■. 7) 90 9 7 -21 1 rc 0 -1111 — 3 3*^ ~90 -SO -5 FO FC K = 1 0 401 -309 1 304 -33b 2 7 7 -64 3 1 ;^5 - 133 4 109 - 157 5 120 123 6 f.e -76 7 47 -49 6 29 17 9 -20 -18 10 -2 0 16 1 1 -21 -4 1 13 < 1 9 403 A 6 9 K.5 2ce 1 13 ie3 -19 90 t 1 1 - 1 00 -420 44 1 4 50 170 2C7 1 1 5 163 -14 89 -60 K- 049 9 60 4 99 107 23 3 97 1 10 47 -20 4 0 44 72 £0 2 26 94 309 2 1 3 04 02 46 -21 1 1 1 2 3 1 ^3 6 (.2 2CH 30 76 72 32 4 0 H= 11 501 -966 493 - 106 220 90 117 -02 23 42 -2 7 75 50 -229 1 02 -300 -21 7 -05 -60 -51 -17 -111 30 -174 661 -200 -24 -7t> -72 -40 30 1 H= H= h = 0 J 18 1 15 1 126 -130 2 -JO -4 3 -JO 22 4 62 34 0 37 -00 6 100 9 7 7 40 06 8 -22 1 1 13. K= 1 0 eo -97 1 123 ■ -137 2 -19 -1 0 3 -19 15 A 39 41 5 239 ■ -203 6 1 17 1 14 7 32 30 10. K= 1 0 30 -27 1 -20 37 2 -20 -16 3 03 09 4 -21 7 0 -22 -27 6 -22 -10 17, K- 1 0 1 13 1 14 1 133 131 2 -2i 23 ^ -22 21 ^ -22 1 1 5 -22 -19 19. Iv = 1 0 -21 2 1 -21 12 2 -22 1 3 -22 -9 H= 21, K= 0 -22 H= -21 . K = 1 2 3 4 5 -23 -22 -22 ~Z3 -23 H= - 19, K= 1 2 3 4 5 6 7 87 -21 47 42 -22 -22 68 h- -17, -20 1 -17 -22 -4 -28 22 83 -3 43 52 -I 1 -10 -7 0 1 1 1 1 1 1 1 1 2 64 03 3 47 00 4 60 62 5 38 28 6 31 39 182 f D rc f o PC FC rc (■a f c 7 -z^ -34 e -i3 ?9 9 39 -34 :^ - lb. K - 1 1 -19 -17 P. -19 20 3 1 4 1>P _c,fj 6 i>0 -60 7 33 32 t' -21 12 9 36 52 = - 13. K- 1 1 29? ?PA P 2n- -214 3 2?i; -236 A b'j -58 c, -?0 -4 t> «3 -90 7 34 -12 C -21 -22 s •.0 71 10 <,2 -41 = - 11. K^ 1 1 12 ft 133 2 27 27 3 91 -fc7 4 43 -35 5 71 6G C 79 {(a 7 AZ 40 6 ijO 51 9 -21 3 10 -? 1 C 1 1 -22 -10 1= -9. K = 1 1 334 -330 2 129 12? 3 300 -301 4 1 1 0 107 ft. UJ7 176 C 38 37 7 7 1 -71 0 73 74 9 -21 PA 10 -? 1 20 1 1 -23 -43 H= - 7 . K- I Ol -54 2 eo -62 3 96 10! 4 1(.2 lf)4 5 2 7 0 268 6 -1 7 1 ^ 7 86 -89 e -20 -34 9 51 -40 10 3( -31 1 1 -2^ -24 - -S. K = 1 1 332 -332 2 31 5 314 •a 264 2S0 4 64 -itO 5 32 J 314 O 133 -123 7 31 -2t. 8 99 -93 9 32 9 10 4 9 -4 7 1 1 52 -4'.. 1 125 1*1 ? 202 -2 00 3 IHl - 101 4 4 5 -51 5 lOo - I 19 6 BO -71 7 -IC -16 8 -19 -5 9 87 ao 10 -20 0 1 1 -22 2 = -I. K^ = 1 1 397 -422 2 413 -4 14 3 115 1 1 1 4 149 - 1 4 0 5 3ti 1 AO 70 3 A 233 31 51 3C. 112 4 2 '3 67 - 1 40 7 6 -16 -2A0 -23 -48 -32 H= K = 0 1 2 3 4 6 b 7 e 9 H= 0 1 2 3 4 5 6 7 e l6Ci 79 102 m 117 57 b3 124 -2 I 48 O. K bAO 2i>'> - 16 122 - I e 134 58 30 94 4 b C 7 0 1 2 3 4 r o -21 -20 -21 62 10 lb -B -53 14, K = 102 61 1 1 1 63 -21 -21 -22 91 -61 -107 - Ol -7 -2 -10 4 b 6 7 8 9 10 y- 0 1 ? 3 4 H- 0 1 2 3 H^ H= 16, K- -2 1 -21 -2 1 -21 68 18, K.= -21 -2) 'i 0 -23 2 0 . ►'--- -23 -2 0. <= -170 -01 -103 -00 121 56 -43 - 129 20 -51 1 2 3 4 5 46 1 1 1 162 -23 42 -3 37 -21 -17 71 I I -4 ■43 20 -1 1 23 no 161 0 36 H= - 1 tj , «.= 3 4 5 6 7 6 9 10 FO _lo 30 132 13'. 282 225 / 1 -21 4 3 -10. »- 2 66 113 75 2 1 eo -20 62 £21 -21 -22 10 -40 - 129 142 294 23 6 69 -2 -30 -263 -16-* -66 10 -e4 20 66 -219 28 20 1 2 4 5 6 7 e 9 10 -8. K = 37 107 63 -I 7 C2 165 65 275 1.17 48 --36 1C9 -^•6 -26 59 171 -7 7 -2V6 -125 -49 H= -e, K-- 536 -253 -5 - u e 10 141 -53 25 99 3 4 5 6 7 33 -22 -22 240 -22 46 46 H= -16. H= »0^ K = 1 2 3 4 5 6 7 8 -21 33 6 8 203 256 6 3 35 -23 -40 18 17 -240 1 1 43 54 22 39 -68 -209 -26 1 -5C -38 12 6 7 e 9 10 42 1 173 2J;3 - 16 e2 -li.^ 40 56 -22 141 1 2 3 4 5 6 7 8 9 10 FO 1 12 165 k 10 52 i!08 212 101 -20 66 -21 FC 106 lb 7 llO 51 ■206 -209 -94 -4 60 - 1 H = K- H= 1 2 3 4 5 6 7 8 9 10 202 661 275 30 3 1 55 53 125 -21 169 0 1 2 3 4 5 6 7 8 I 45 U>1 - 1 t, - 19 - 19 48 64 -2 I 36 1 46 174 2 -1 1 33 -69 -3 30 H= -2 H- - 1 4 K.= H= I? K- 1 2 3 4 5 6 7 e 9 32 -19 1 10 -20 -21 299 42 52 44 0 1 2 3 2 7 34 17 1 54 -16 31 - 173 55 H= •12 3t> 37 7 1 1 '> -2 -17 304 -49 -57 -47 4 27 1 2 3 4 5 6 7 8 9 10 112 - 15 2^4 62 44 -18 4 2 62 68 36 0 1 2 3 4 5 6 7 0 9 50 79 2AU 1 CO 2 60 225 65 -19 -20 -21 H= 412 -169 2A5 10 -90 -3 45 -59 -28 13'. -201 -66 5 277 29 -27 58 -92 -126 25 171 -113 38 -241 63 -4 2 0 47 -59 -90 41 0 1 2 3 4 5 6 7 e 9 56 46 -16 167 72 89 39 98 58 50 -66 24 3 98 2r.7 -226 68 14 16 1 47 -63 6 167 -74 -89 29 97 57 44 H- K-- 0 1 2 3 4 c 6 7 8 123 40 4 6 53 41 56 71 97 -21 125 -38 -40 56 -42 -6 1 -64 98 -21 F = K = 0 1 3 4 5 6 7 8 53 233 169 -19 47 71 -21 66 44 -235 -165 0 -47 -72 15 62 -1 1 11 K = 0 1 2 3 4 5 6 7 1 6 0 157 31 -20 -20 ■ 2,7 31 -21 165 ■155 -27 lA -13 -36 -6 26 h= 13. K = 1 , K= 5 149 -138 0 I 2 3 -20 87 79 87 28 -86 73 91 185 4 5 6 0 1 2 3 A 5 FO 1 1 '. -21 -2 1 H= 0 1 2 3 H= 0 1 J5, 37 -? I 1 1 4 6^1 -22 -22 IV, K -21 -22 -21 '>3 1^. K -23 -22 K = H= -19, 1 2 3 A 5 37 131 1H3 -2? '23 FC 1 15 1 0 ■ 107 i-g 1 0 -31 -?5 52 5 30 -V -21 1 19 -179 9 ?0 FO FC -17, 1 5b 56 2 57 50 3 i-vy -140 4 1 01 105 6 89 9? 6 72 6C. 7 -23 -9 -15. K= H= . H: 1 -21 1 1 2 -21 6 3 40 39 4 135 - 135 S 263 263 6 -22 -16 7 -22 -18 6 38 -27 . - 13. K= 5 1 51 -56 2 30 30 3 107 -111 4 89 -66 5 212 217 6 62 -64 7 87 -83 6 82 -80 9 -22 -14 : - 11, K- 5 1 -1 a 7 2 - 19 -?5 3 45 -53 4 76 -81 5 -?0 -1 1 6 187 191 7 253 -252 8 57 49 9 -22 -4 K = I 61 -71 2 65 -66 3 67 66 4 93 -102 5 168 172 6 65 76 7 21 9 -227 8 86 9 0 9 6t) 71 10 90 85 = -7. .<- 5 1 306 -296 2 1 79 - 1 69 3 109 - 10 7 4 ^l -34 5 -19 32 6 -20 -3 7 -21 -37 0 223 -220 9 179 !00 10 -22 0 i= -5, K= 5 1 3 65 -354 2 31 22 3 122 I 1 9 4 2'; 5 242 5 34 -37 6 143 138 7 171 -1C9 8 75 -c;2 9 173 171 iO 8-V -83 ;= -3. K- 5 1 66 -59 2 220 -215 3 32 1 320 4 317 318 5 150 147 6 66 87 7 62 -68 8 -21 2 4 9 54 50 10 107 104 1= -1 . K; 5 1 196 -208 2 310 -299 3 345 327 4 261 -259 5 52 -47 6 132 - 137 7 -20 33 8 76 -74 9 11 I 1 14 10 63 49 »= 0. K^ 6 0 263 260 1 153 -151 2 197 196 3 110 - 105 4 54 -4b 5 60 62 6 -19 17 7 42 -36 8 35 28 9 -21 -2 H = H- H = FO 2. K= FC FO 0 206 195 1 136 1^4 ^ 73 -68 3 152 148 A 26 -10 5 22 29 6 -19 32 7 33 -34 e 39 -29 9 -21 -15 4. K= C 0 197 - - 191 1 217 -221 2 190 - -192 3 82 76 4 122 - -115 5 1 15 11 1 6 -19 -4 7 -20 8 8 54 -42 9 -22 30 6, K- 6 0 165 - -151 1 62 -56 2 13c; - -139 3 1C4 - -102 4 4 7 4 0 5 e5 -62 6 52 45 7 -20 7 0 -21 0 6, K = 6 0 31 24 1 237 231 2 93 93 3 32 31 4 94 94 5 66 -8 7 6 £1 7 8 7 68 -6 4 10. K- 6 0 70 -59 1 -19 16 2 54 61 3 91 84 4 -£0 23 5 61 62 6 -21 -25 7 -22 26 12. K = 6 0 50 -42 1 -20 5 2 -21 22 3 6 6 -72 4 -21 -34 5 -21 -2 6 41 -28 14. K = 6 0 -2 I -1 0 1 42 25 2 54 50 3 37 -35 4 -22 -24 c 34 -35 h= 16. K = 0 -21 1 44 2 -22 3 -22 FC 8 -49 12 -9 H= IC, K- 0 39 -4 3 1 34 -40 - 1 a . K-- 6 I 73 76 2 111 -110 3 83 8-1 4 -22 0 5 47 -32 - 16, K--^ 6 1 44 -46 2 -21 -3 3 58 58 4 4 5 27 5 70 73 6 47 -49 7 80 -78 H= - 1 4 K.= H= 1 85 -69 2 56 55 3 146 - 1 '.)0 4 1 79 1/6 5 75 -55 6 -21 22 7 59 51 8 -22 12 - 12, K = 6 1 1 18 -116 2 55 -4 7 3 -20 18 4 34 -14 5 154 -147 6 -21 -27 7 45 -44 8 6 1 55 9 99 95 - 10. K^ 6 1 138 133 2 -19 42 3 130 132 4 48 -60 5 1 76 174 6 196 -205 7 57 59 8 -21 6 9 -22 -8 -8. K= 6 1 50 58 2 95 66 3 152 159 4 35 27 5 -20 -1 8 6 44 -35 7 106 108 8 -21 7 9 -22 -1 1 186 ro re H= 1 129 -l?ft 2 1 1 9 1 17 3 1 0>^ -too 4 AO - 43 i> 3 3 -;'7 (■ 3>; 'oO 7 1 It) - l?r) t! 1 /4'. 1 A3 9 /J -76 r. -A . K = 0 I 30« 3?0 P - 1 6 -31 3 I 40 - 1 'i -; 4 - 1 I' -e i. 4? -36 G - 1 9 b 7 ?t<» 29 6 4<) 18 9 7 1 -C7 10 -2d -18 H= H.= H= K- 1 9A -96 ? 71 51 3 - 16 -7 4 135 -133 & -IC -21 6 63 58 7 -21 3 e -21 -30 9 lOG 101 K = 0 24 1 30 2 39 3 5 3 4 43 5 4^ 6 83 7 35 8 -21 9 -21 3, 1 0 -1 7 1 65 2 37 3 52 4 93 fa -1 9 C 37 7 46 e -21 K= K- 0 1 3 -3 7 51 38 35 EO 23 1 24 -28 -f.l ■48 9? -17 2 8 41 16 0 186 196 1 V 1 -06 2 - IB 17 3 - 1 9 -6 4 -19 0 S -20 -4 6 -21 -37 7 55 4 3 8 -22 -21 1 2 3 4 5 6 y Ife H= f a 63 79 4L> ■21 -20 61 K--- 0 -19 1 -I 9 2 72 3 -20 4 -L'O 5 2^ 6 -21 11. 1 0 50 1 97 2 57 3 -20 4 60 5 40 13. 1 0 -20 1 72 2 -21 3 -21 A 32 15. 1 0 -2 1 1 -22 2 -21 3 -22 K = K~ 17, -22 H^ -17. K = 1 2 3 4 53 -23 -Z'S -23 h= -15, 1 48 2 5/ 3 50 4 -21 5 63 6 77 H= -13. K = H= -11 FC 50 77 4 5 6 14 -5C> 7 -36 6 -71 9 -4 •25 -7 -51 -9 1 -55 16 -56 ■29 0 -71 -10 -14 ?0 12 -9 24 19 17 7 -4 4 3 7 -34 ■22 51 -61 -51 -5 53 66 FCl fC f o re 1 -21 54 2 50 -56 3 -2 1 2 5 4 100 -94 5 -21 29 6 -21 2 7 40 -48 4 1 24 1 -20 -3 2 38 33 3 49 -59 4 101 loa 5 55 64 6 -21 -20 7 83 -83 8 67 -68 \\- 1 4 9 - 64 2 -19 21 3 36 -54 4 I 1 1 i;;'4 5 -21 -2 5 6 1 I.J I Cv 7 ^1 -£6 e "J -1 -23 H- -7, K- 1 2^7 -225 2 42 39 3 59 58 4 54 -40 5 73 82 C 6 3 -64 7 t?. -5 2 8 -21 24 9 45 40 -5, K = 7 1 C5 -63 2 40 57 3 L2 B? 4 48 -58 5 102 1 07 6 1 1 0 -112 7 tl 66 8 6 5 -60 9 t4 70 H" H- 3 4 5 C 7 8 9 H = 0 1 2 3 4 5 6 7 8 K- 1 80 85 2 -17 4 3 101 95 4 90 - 100 5 100 -100 6 -19 -6 7 51 -60 8 -21 31 9 49 45 -1 . * - 1 7 14 5 87 - 13 1 18 -20 6 7 4 1 4-k 40 - lb ec 4 7 43 53 29 -2 1 54 -12 - 148 66 -8 -113 14 -68 55 -39 8 40 20 -62 41 -44 50 -1 1 2 5 -48 0 35 28 1 356 369 2 56 -6 2 3 - 19 in 4 i;i -69 5 -20 - 1 (. -m 0 7 41 36 a -21 -3 4 . K = G 0 125 129 1 * '• 6 2 2 53 -50 3 -20 -16 4 -20 -7 5 4 5 -34 6 46 52 7 -21 -19 6, K- 0 0 39 31 1 4 0 -51 2 70 -72 3 211 -220 4 -21 -12 5 -20 -a 6 -21 29 7 -22 - 7 0 67 1 -20 2 59 -i VI 4 4 5 5 30 C -22 H= 0 1 2 3 4 0 1 2 3 4 10. K- -21 -21 -21 -21 97 134 H- 8 -69 -27 -7 3 -69 42 4 4 8 26 -29 — 6 12 95 134 12, t -20 30 -21 -21 3y 14 , h -21 -21 -22 H = H- 16, K= 0 34 H- -16. K- 1 55 2 -22 3 40 H= - 14 , K- 1 -22 1 1 '•1 -16 0 50 8 -19 -17 -22 8 -33 8 -50 13 -19 6 -33 187 FO FC FO FC FO FC FO FC 2 -22 30 3 -22 -23 4 62 -CI S -23 "31 6 t>2 -51 - 12. K- 8 1 -20 2 2 t;2 91 3 8) 88 A -21 2 5 40 34 t 04 -P-3 V -22 16 - 10, K^- 8 1 38 -44 2 53 5S 3 -2 1 50 4 -2 1 3 5 66 6 6 6 Sb 60 7 -22 23 H= -6, H= K = 1 49 43 2 e \. -82 3 32 -3? 4 92 -1 00 5 93 -86 0 -21 17 7 -22 -20 e 75 69 -0. r.^- 8 1 2S -26 2 01 -82 3 79 7ft 4 6 0 -64 Cs 51 -71 e -20 0 7 46 -46 8 -22 -5 -4, K = 1 -la -22 2 120 121 3 45 -45 4 29 22 5 -20 6 6 4 2 4 8 7 -21 30 e -21 2 -2. K = 8 1 77 -69 2 82 75 3 -1 9 16 4 72 03 5 50 -59 6 -20 IS 7 41 59 e -21 -1 K = 0 106 104 1 402 -422 2 144 - 143 2 33 -34 4 32 34 5 30 28 H- K- 6 -20 13 7 -2 1 -26 3t K = 9 0 132 136 1 362 . -371 2 93 -ti7 3 45 -/,0 4 -2 0 -9 5 69 -71 6 29 6 5. K = 9 0 4 0 30 1 <,3 23 2 73 -60 3 317 320 4 1 10 10« 5 -2 1 26 6 36 -18 7. K= 9 0 76 78 1 56 -60 2 145 -144 3 296 2*37 4 60 53 5 60 60 M = F= H= 9, K- -21 1 09 -21 -21 46 1 1 K= 0 -21 1 51 2 48 3 33 16 -9t> -6 -15 30 - 14 45 -50 33 13. K- H= 0 -22 -13 1 40 36 13. K= 9 1 -22 34 2 -22 27 3 -22 -7. 4 -22 -7 5 -22 13 11. K= 9 1 51 -38 2 55 56 3 113 - - 124 4 33 -45 5 -21 -16 6 -22 30 -9, K = 9 1 42 39 2 -20 20 3 92 -96 4 55 -5* 5 -21 2 6 -22 16 H = -7. K- 9 0 1 -21 95 -7 -92 1 90 96 2 ■ 98 97 2 -20 17 3 -22 14 3 -20 -0 4 4 4 -55 H- 10. K= 10 5 82 101 £ -21 4 2 0 -22 -35 7 -22 -5. K = 35 9 h- 1 2 -21 -22 12. K = 5 -6 1 0 1 52 -56 2 -20 1 0 -22 -21 ~ 3 1 -48 4 -21 -36 h- 12. K = 10 5 7 7 77 C 34 32 1 -22 22 7 -22 -26 2 67 -62 -3, K = 9 H= 10, K = 1 0 1 47 -46 1 -21 26 2 6? -69 2 75 -03 3 56 -52 3 -21 -6 4 -20 -23 4 -22 -8 5 e3 52 b 4 9 50 F,= -0 , K= 10 7 92 • -100 H,= H- H= H- H = r.- 1 -20 -4 2 -X9 -13 3 43 54 4 -20 12 A ee 95 6 -21 41 7 40 -46 0. K = 10 0 32 41 1 2e 1 0 2 85 65 3 5 8 4a 4 -20 -1 5 -21 3 6 36 22 2, K= 10 0 147 - -143 1 -20 -20 2 14 6 142 3 135 133 4 32 44 5 64 63 4, K= 10 0 132 - ■136 1 -20 6 2 -20 4 3 -20 -8 4 -21 -23 5 33 -19 6. K = 10 0 -20 24 1 122 •120 2 1 I 5 1 15 3 -22 6 4 73 -74 31 50 41 48 -22 H= -6 , K= -2 2 63 -28 59 -14 I 0 H= H- 1 62 58 2 58 67 3 32 -29 4 1 12 1 1 I 5 -21 0 6 -22 -9 -4. K= 1 0 1 103 - 104 2 -20 "" J- 3 -20 16 4 ■45 -50 5 -21 23 6 -22 -31 -2, K= I 0 1 160 -157 2 71 -65 3 77 -72 4 4 0 -56 5 31 41 6 67 -64 0 31 1 -20 2 36 3 -21 4 ■ 56 K= 1 1 9 1 5 - I'r - 16 -54 K- K= 0 -21 1 32 2 -21 3 -21 1 1 26 -0 14 4 H= K= 10 188 H= M = 1 1 (; r C L FO FC L 1 a FC L FO rc I. 2 4 5 -3e H- : -0. K:= 1 1 4 4 7 oc 0 1 2 3 -?i -21 -21 11 -27 -32 -13 -31> 1 -9. K^ 37 -7, K- 1 1 -29 1 1 fr 1 2 3 4 -21 -21 -21 -3t K = -Z7 -6 7 30 4 1 1 H- 1 2 3 4 -1. K= -20 -21 -21 61 1 1 2 17 1 1 54 0 7. K- 79 1 1 -7 2 1 2 3 63 bl -22 -1.2 -b2 -10 1 2 3 -21 3C) 31 61 3C H 0 0. K= 107 - 12 106 1 Si's 40 Table B-4 jlated Stri. (dhphpy) ]Cl^'2E^0 Observed and Calculated Structure Factors for [Ni,c€ (H„0) .- 2 2 4 190 L FO rc L FO FC l- FO FC L FO F C H- 6 . K •■ 0 -4 41 ?. -4 19 -21 194 -212 _ 0 t K= 0 -2 60/ 633 -27 -.93 -1 06 0 1 1 o J - -1171 -26 284 -3^5 2 563 -4 9 0 2 3 015 2 9 ; i / H= 12. K.= 0 -25 217 253 4 t 930 - -20 to 4 91 1 905 -24 -93 - 193 f, £.6 3 b'-JO t> Jt.3 -3'M 0 163 I - - 1 722 -2S ^90 Mi2 {I 1 Mi - 2 '.:. .1 0 9 0 5 - - 1004 2 494 -506 -22 363 384 1 0 oev -t.0 7 10 3 1 / 322 4 427 4 34 -21 -90 -60 12 314 -3. 'J 1^' -79 6 6 -87 1 5? -20 22 7 -375 14 -64 103 14 44 5 -4 34 8 -84 -76 - 19 328 - MjZ 16 130 -1«J 16 22 5 230 -28 b.>l -54 1 - 10 -9 2 -25 1 0 1 4U 1 1 3 10 1 38 -9 3 -26 21 I 200 - 1 7 -90 -42 2 20 242 261 20 -04 -1 06 -24 194 107 -1 6 -90 4 \d 22 I 77 1 H4 -30 602 -57o -22 142 -12o -1 5 -96 -63 24 1 : & -14? -2 8 5r.0 5o7 -20 3 02 -399 - 14 -96 -292 26 700 -t)91 -2o Yt 7 7 54 -1 8 l.-'7 -1/7 -13 5 53 595 -2 4 34 y - J,:\,\ -1 d 3'. 7 35 7 -12 -JU 180 1= 2. K: ■ 0 -2?. 7o5 - / O 0 -1 '♦ 249 2 56 - 1 1 490 - 522 -20 lo3 1 85 -12 181 - 180 -10 190 -24 7 0 403 3 7.1 -10 296 315 -10 -79 3d -9 04 7 -8U7 2 2^30 • -2014 -16 9 ^ 9 -921 -8 -79 61 -3 44 5 512 4 137 -1 i?4 -14 i t.7 197 -6 -80 - 14 -7 20 I -2i2 6 345 -303 -12 167 1 19 -4 374 362 -6 79 8 -705 0 1 693 1 6 li 2 -1 0 14 7 -99 -2 1073 1 1 1 1 -5 14 10 1 4o2 JO 1 24 -119 -0 155 3 14 83 -4 02 7 -696 1 2 1 1 b 1 07 -6 ;/73 9Jo H = 14. K: 0 -3 39 3 2^*4 1 4 C4b 6 4 9 -4 01 6 7a 1 -2 85 7 72 8 16 505 -547 -2 2 4^6 ■ -2 5 05 0 50o -594 -1 124 51 >8 2*j5 251 2 433 436 20 340 3 62 H = 9. K- 0 -24 -«3 -16 H = 3i K = 1 22 342 -354 -22 346 -i^^ 24 41 3 -402 0 39 5 7 41 00 -20 -8 1 66 0 750 -639 26 31 1 292 2 41 1 42 1 -1 8 284 27 7 1 34 8 31 7 ■2 0 &'i9 -54 1 4 429 - 4 36 -I'i 30 o -323 2 -70 - 126 -2 6 4*0 -459 6 d52 270 ■ - 14 171 -1 87 3 301 -331 -24 206 I i;i 0 -/o -ai -12 -3 1 -ill 4 390 -408 -22 4iJ6 443 10 -8 1 -123 -10 197 -2 2 6 5 559 559 -t:0 1 i i -i09 12 i vo - 1 9-> -6 141 136 6 -o7 1 9 -in 269 -274 14 -7 9 57 -6 394 J99 7 -67 -43 -16 060 046 lb -8 I -1 I -4 371 360 8 472 -i»85 -14 560 -551 -30 4 /■2 474 -2 3 78 -41 1 9 447 - 40l -12 283 -322 -20 5^:1 52o 10 -66 -92 - 10 ^•73 3J2 -26 3'+l -332 H = 1 6, K r. 0 1 1 500 -51 o -a 2573 • -2519 -24 -78 18 12 -69 59 -6 13i!8 - lt>66 -22 - fa -24 -16 322 -31 1 1 3 621 6C5 -4 329 -390 -20 -77 9i -14 203 -207 14 199 233 -2 3358 3=05 - 18 1 39 1 60 -12 192 202 15 301 299 -15 448 -44o -10 - 84 5 16 475 -478 i= 4. K 0 -14 31 5 -27o 1 7 3;jt> -332 - 12 126 109 H = 1, K 1 18 -81 51 0 7 329 -84 96 - 10 zrt -2 52 19 426 -4 55 2 242 -231 -8 130 100 0 1935 2098 20 41 1 39 8 4 1140 1 Kt? -6 -Ci5 46 1 1 345 -1410 21 -ti2 -59 6 30f. -2 3l> -4 1 2 J 9 -123 7 2 1 054 -1916 22 450 -430 a 351 -306 -2 lo-v3 -lL.68 3 617 -5 6^ 23 273 24 3 10 9^ 120 4 1209 - 1 loa 24 -84 44 12 4 25 433 H- 10, K. 0- 5 712 -736 -29 -103 - 181 14 199 -2^7 6 347 ^^J -26 -1 00 -2iA 16 -«0 86 0 655 660 7 ^.\3 13 -70 46 -21 Zii -24 0 -24 21 » 2 09 - JO 51 4 502 14 438 4 j/ -20 683 -670 -22 216 -2 17 -28 226 -dZJ 15 793 7 -J 7 -19 -74 -I 04 -20 42 7 -41 7 -26 0J9 -032 16 -7o 1 45 - 18 i71 573 -IB 192 I o2 -24 1 I 3 129 17 310 3 15 - 17 39 2 392 - 1 t> 67 4 65 7 -2ci 06 8 o75 18 353 -3e.4 - 16 352 362 -14 134 126 -20 I Jl -1 0-. 19 -82 -57 - 15 1384 I 34 5 - 12 31 0 2 4 0 - 18 o<\ i. -ol 9 20 551 565 - 1 4 C4 3 -681 -lO 565 04 2 -1(> 7 59 7bd 2 1 25 1 -2 J3 - 1 3 105 - 1 08 -O 669 5'Jd -14 6'>i 349 22 -82 -4 T -12 16 7 4 -1 624 -6 219 -I 4 r -l^ -7 d 5 7 23 336 -356 - I 1 I 773 -I 789 -4 427 3^10 - 10 319 325 24 670 -65t> -10 723 640 -2 1524 1519 -d 574 - 5 •-' 0 25 -91 1 84 -9 -6? 80 -6 519 - 544 2o -8 5 -23 -8 148 - 1 '» i 191 FO FC FU FC FO FC FU FC -7 2'.il 230 12 1 1 7 38 -9 73 5 -721 -1 1 -81 -21 -6 7'j3 -76 5 13 1 23 -1 55 -0 144 157 -I 0 -"80 32 -5 607 -574 1 4 I 75 -151 -7 51 7 -5 0't -9 201 245 -4 1 O'^A lOJL, 1 5 -80 -87 -6 206 -191 -3 -u2 - 108 -3 A t>9 -4 83 1 t> 1 4 9 153 -5 428 431 -7 29-> 332 -2 1 73 7 1655 1 7 -U4 150 -4 3 05 -38 5 -6 -80 - 10 -1 J 00£. -945 13 126 70 -3 203 210 -5 2 57 -24 0 19 2a J 2 54 -2 448 -455 -4 319 32 2 1^ &. K = 1 -30 -84 3 3 — 1 -73 - 39 -3 2 25 -218 -29 200 ^^.i -2 357 3oy 0 lii66 - -1596 -23 48o 47 3 H- 11, K- 1 -1 -84 1 7 1 942 945 -27 Jl 2 -317 2 9b 'i 923 -26 2 95 2o.j 0 -3 2 34 H = 15. K 1 3 405 4 39 -2 5 338 - J 3 -:> 1 -8 2 5 8 4 J'l lb 14 42 -24 47 / - 4 o 4 2 391 -3 78 -22 1 53 -118 5 3l>0 372 -23 393 407 3 - 00 -44 -21 12o 182 6 3'iO -34/ -22 314 -331 4 -8 1 -4 -20 277 2 73. 7 3v0 -379 -21 2<*6 208 5 271 270 - 19 -8y 5o O 330 -338 -20 43 1 t7y 6 221 2?6 -18 -84 55 9 356 -360 - 19 -7 :i 22 7 -82 77 -1 7 -34 9 10 570 553 - 18 450 -4 55 C 234 -19 9 -16 297 -2 77 11 615 64 0 -17 -70 -15 9 171 -13/ - 15 41b -4 15 12 452 -4 50 -It. 337 -32 8 10 236 -214 - 14 -85 - 1 1 3 13 176 21 S -15 032 -c :-:'.! 1 1 228 -237 - 1 3 20 8 -2 19 l'» 365 -342 -14 21 2 2 09 -29 24 2 -2 4 0 - I 2 300 3 02 lb ^65 -462 - 13 25/2 -2 7 8 -28 320 -30 7 - 1 1 416 4 1 4 1& 23C -205 -1 2 1 02 9 I Ct3 -27 206 215 -1 0 -o5 -85 17 204 -229 - I i 1070 1 Ojb -2o 357 -349 -9 188 1 74 18 -81 1 ^4 - 10 39 5 -403 -25 307 3 0 0 -0 -85 -31 19 -81 -1 1 -9 -70 7 0 -24 300 306 -7 1 81 -173 20 276 -275 -0 -70 1 7 -23 297 -29 5 -6 2 52 2 ;. 8 21 -64 79 -7 4 8 5 -480 -22 298 28 3 -5 157 -123 22 -84 3 -5 99/ 9o3 -21 316 -502 -4 -86 - 14 •30 561 -545 —5 -70 -3l. -20 632 -630 -3 -87 47 ■2 9 24 5 240 -■i 886 - 8 ct 0 -1 9 165 -14 3 ■20 -61 -14 -3 5 7 4 5 •■-17 -1 8 I 1 7 120 H = 0. K. = 2 ■27 -82 152 -2 2150- -2161 -1 7 -80 09 2<. 42 1 4 15 -1 1041 1 0 25 -16 524 541 0 321 -349 25 219 -236 -15 7 53 770 1 90 250 •24 319 2 93 H = 9, K: 1 - 14 -78 13 2 76 i -703 23 582 -56 8 -13 249 275 3 23B -327 ■22 687 -601 0 700 712 -12 579 -554 4 402 4^5 21 -77 4 1 348 -34 7 -i 1 59f -6 0 1 5 614 -•+90 •20 3;; 3 369 2 18 / -1 :;.,: -10 143 151 o M3 t.7 •19 5'j1 583 3 -7 7 -53 -9 -77 -105 7 8 76 02 1 •18 519 4 OfJ 4 443 -447 -8 -76 -2 3 8 550 53 7 •17 69 0 69 4 b 21 3 -2^ o -7 128 at 9 6 5C 662 -16 50b -4^77 6 -dO -27 -6 29 7 -267 10 3 7t -3 76 ■1 5 1 2 3 55 7 -80 43 -5 -78 -33 1 1 -71 -3 •14 -64 55 a 1 1 9 63 - 4 290 2 92 12 7 1 5 -74 2 13 702 -622 9 1 29 1 50 -3 14 1 -14 4 1 3 I 073 -1 095 ■12 566 -5t.O 10 27 ^ -2 86 -2 695 904 1 4 975 981 ■1 1 328 2 85 1 1 243 -Zod - 1 40/ -4:^7 1 5 -73 -38 •10 443 39J 12 -B 1 41 1 6 *09 426 -9 1 40 1 4 8 13 22 1 -199 H= 13, < 1 I 7 -86 -31 -8 425 408 14 1 62 1 46 18 4J2 -457 -7 319 275 15 2z.o 2 3 2" 0 61 1 -o'H 19 -9 4 -80 -6 34 b 29 7 -30 4 97 '19 1 1 228 25-' 2 0 264 -311 -5 476 -4 4 9 -29 19o -21 0 2 -83 -16 21 235 -2S0 -4 IC9 1 1 0 -23 I 5* 1 77 3 -84 71 22 -38 86 -3 -68 -70 -27 1 'J I -140 4 379 3C.4 23 2^*0 -2 74 -2 50 5 448 -26 »:>6 - 129 5 149 I4i ■ 24 2 7 -12 359 -35o 9 875 060 192 FO FC FC FO FC FO FC 10 366 -339 -24 Lt 1 52 0 -20 1 18 -136 1 1 7bo -7 6 0 -23 1 4 3 - 1 9;> 11 = O. K- 2 - 19 4,7 0 -463 1 2 ; 10^6 1 0^9 -22 -79 -b2 - 1 8 - /6 1 4 1 3 - 7 1 - 6? -21 25 9 -269 0 337 -3tt2 - 17 b -i 5 - 5b3 1 1 31.0 401 -20 4 29 4^:0 1 1 31 25o - 16 c»34 9b2 1 •_, 1101 1109 -1 9 - 7 b -71 2 214 -24 J - 15 744 7 6-3 I o A 1 0 -4 23 -lo I 1 08 I0c5 3 242 24 2 - 1 4 5 76 589 1 f 1 '( 6 - 1 6 J - 1 7 3cl2 37 5 4 152 163 - 13 46b 4 JO 1 0 ?63 -3 10 -1 6 47J -4 7 7 5 145 -140 - 1 2 10 2 9 - ■1004 1 '■) 7'i9 -/b6 -15 2»-'a 223 6 1 13 I 16 -I I '■J2n - 91 3 20 -H'* - 2ri -14 16.3 - • lo30 7 2L.0 2Ci2 -1 0 151 - 1 35 ?1 - 00 -40 -13 1 o / 2 - -16 79 0 150 1 Id -9 1 7y - 1 92 Z'2 I 73 1 bO -I 2 73 7 721 9 260 2 75 -8 2tS'i 2 55 23 - i',1 -31 - 1 J 39 7 -375 10 16 1 -142 -7 1 78 1 6 6 24 1 t<9 - 154 -10 61 4 619 1 1 1 70 153 -6 206 ? 14 2b -6o 3b -9 804 754 12 49 7 -4 96 -5 2V0 27 9 - 29 -U9 -37 -8 293 -263 13 4 55 -4 7 7 -4 4 33 -432 -2U IbO -14^: -7 baO o02 1 4 2 US 298 -3 -7b 1 3 7 -27 -C* 32 -6 ti06 093 1 5 -84 -95 -2 - 7o - 1 3 I -26 30b -321 -5 -o9 -J2 16 335 343 -1 -71 -94 -25 - W\ -3 -4 4 I O -39 7 1 7 170 179 -2'* -tu 2 a -3 -ro -02 -30 127 -126 H- 12 . K = = 2 -23 -82 -142 -2 371 3 64 -29 153 -156 -22 -81 -59 -I -69 -lo4 -23 333 322 0 231 237 -21 -p. 2 31 -2 7 -79 -50 1 -dl -60 -20 -lib 2 00 H = 6t K.= - 2 -2c. -79 128 2 -82 67 -19 7) 7 -71 7 -25 472 -476 3 140 -142 - 1 3 -iJt? 143 0 542 -523 -24 307 -4 1 0 4 -(32 23 -1 7 4 99 -:>'* 1 1 352 355 -23 127 98 5 1 56 1 74 -1 6 t>f.F) 6 60 2 230 245 -22 -79 -66 6 1 31 -7 I -15 1 19 6 1 1 f'4 3 3 74 3 90 -21 -78 6 7 -85 -9 1 -1 4 -f>6 -120 4 4v5 -4 0.: -20 261 -2 2 9 8 1 66 -1 81 -13 - 7^ 1 1 1 5 3o0 -36b -19 -76 -J 4 -26 2t7 -260 -12 20 17 - 1 004 6 2^3 2o9 -10 733 -732 -2 7 -06 5 -1 1 1 t5 67 - I 7 V 1 7 40 1 -4 3 6 - 17 -73 -27 -26 258 -270 - 10 tCtt i'u'^ 8 35 7 34 -J - 16 -71 Vo -25 355 351 - y 431 332 9 bJ7 -501 -15 362 -343 -24 336 31 5 -c 7v7 7ao 10 b9 I 593 -14 1 O^i 1074 -23 1 3; - 71 -7 1 049 1 I 54 1 1 37^ 402 -1 3 1 C53 1027 -22 -7V -37 -6 7b/i 7 00 12 4o 1 -460 -12 230 -222 -21 -60 -52 -5 I b 0 7 1321 13 1 2 1 66 -1 1 63/ 661 -20 -01 4 1 -4 1370 - U" 4 4 14 21,3 -251 -10 653 -843 - 19 -81 2 4 -3 1 t 0 1 15 573 -5 4 2 -9 831 -853 -18 o03 (sOa -2 3b2 -380 lf> -02 30 -8 132 140 -I 7 - -H -OO -'jO -23 1 ? 1 120 -21 121 -105 23 231 21 7 -7 3t 1 -32 7 -27 -CO 71 -20 -81 92 -30 -06 44 -b 4J2 -4 4 4 -26 30 2 -.34 0 -19 -03 108 -2 9 -07 1 4 0 -5 70d -739 -25 -70 -1 9 - 18 -83 64 -26 34 3 -31 0 - 4 1 I 55 1 103 -24 -79 -89 - 17 252 265 -27 -1-2 90 -3 1 C 7 -1 Oo -23 -80 -42 -16 341 -3^9 -26 -PI 92 -2 22 6 2<.7 -22 -OO -3 - 15 201 -2 '3 I -2b 46b 4ob -1 377 3'::> -9 I 1 70 -2 8 7-4 -379 -25 lti3 -162 10 331 -3a4 -24 -38 227 ■ - 1 293 -236 -24 444 -46 1 1 1 123 -1 69 - 23 ^J,^ 239 -23 208 -193 12 495 527 -22 -o7 -1 76 H = 7. K: 3 -22 1 56 1 65 13 356 -507 -21 7 27 7 4^ -21 463 478 14 -91 351 -20 -3 1 1 48 0 262 -2 8 7 -20 277 -2 89 15 -95 249 -19 655 -6 74 1 21 4 -I 82 -19 370 i^.i 1 6 54 7 590 -18 14 85 1 30 8 2 634 646 -18 -77 -4 7 17 -115 87 - 17 -74 -119 3 230 238 - 17 273 -275 IB 906 -Oy'j - 16 31 2 -307 4 -70 57 - 16 73 7 735 19 -1 I 6 -5 93 -15 540 51 0 5 -73 -I 13 -15 -75 1 20 -1 00 -23H - 14 93 7 -9 28 6 207 -2 0 3 -14 91 0 903 21 415 460 -13 90 3 -d2 6 7 397 -403 -1 3 I 61 1 t>3 22 -94 220 -12 1017 -1 OOd a 6 34 71 1 - 1 2 775 -733 23 210 2 74 - 1 1 859 -8 71 9 -79 -57 -1 1 481 -4 81 24 -90 -187 -!0 1 033 1 072 10 287 -295 -10 1 555 • -15 2 9 25 -87 1 09 -9 8 J2 808 1 1 22 1 197 -9 827 -31 7 26 20 6 21 1 -6 lo5 6 1 549 12 760 -772 -d 439 435 -2S MO 1 48 -7 478 391 13 -aj 68 -7 303 303 -2 7 127 139 -6 8b3 -8 0d 1 4 -30 -36 -6 -71 -74 -26 -82 81 -5 1071 -10 0 7 15 130 -87 -5 4 95 DO 3 -25 -87 -200 -4 5o t> -oOo 16 28 1 277 -4 337 -33 9 -24 491 -438 -3 Job -365 17 133 1 1 0 -3 -73 31 -2 3 -83 -73 -2 o0 8 -536 • 18 361 333 -2 266 275 -22 172 204 -1 -o9 1 19 -30 285 -277 -1 -73 40 -21 651 651 -29 269 -262 -20 32 5 -355 H- 5. K 3 -28 -51 45 K = 11. I<: 3 -19 -70 143 -27 11.3 183 -18 402 41p 0 305 351 -26 3C8 33 7 0 205 206 -1 7 214 -223 1 75 8 -7 70 -2 5 -f;o -97 1 -81 49 -16 65 7 062 2 378 -'*2y -24 1 44 -100 2 1 97 -215 -1 5 1 74 160 3 1 37 -1 .;2 -23 221 -1 97 3 20o -214 - 14 271 2 9o 4 737 -793 -22 2'-*0 226 4 -79 1 9 -13 -71 -8o 5 6^2 944 -21 81 D -840 5 -oO -57 -12 152 3 -1529 6 779 -754 -20 -77 -76 6 -•31 31 -I 1 61 7 -621 7 1 I 3 131 -19 20 I 21 1 7 239 258 -10 1 37 3 - 1 8 0 3 3 71 0 5 93 -18 1237 -1192 8 510 -5 07 -9 41 6 -402 9 7^3 -71 7 -1 7 -74 1 07 Q -35 1 06 -8 I3b7 12ri3 10 91 5 8 99 - lo 162 133 10 -35 -3 -7 1 544 1493 1 I -77 oo -15 2^7 -240 -29 196 1 da -6 596 -503 12 258 -240 - 14 -68 1 05 -26 -80 30 -5 1 175 1^09 13 37o 330 - 1 3 515 4 85 -27 1 41 - l''l -4 339 -35t. 14 3uti -39U -12 531 553 -2t> 2hl -274 -3 126 -I 19 15 298 -2i>9 -I I 71 o 630 -25 -80 29 194 FO FC FO ^C FO rc FO FC 24 -79 -a -5 -05 31 -12 1 393 - 1362 8 501 4(>3 23 -00 133 -4 1 04 1^2 -1 1 -ro -3 3 9 <^92 -690 22 ^^J^ -293 -1 0 1 4 t> - 1 00 10 1 52 225 2 1 766 701 H = 0. K- 4 -9 10/6 10 51 1 1 168 -191 2 0 153 -80 -0 9 35 1003 12 4 JV -*97 1 9 -02 -1 Oo 0 J:>0 316 -7 1 0-.3 1 064 1 3 2 0O -1 09 16 1002 1 0 03 1 13.y9 1346 -6 111! 10?0 14 lo 4 35 -29 510 -510 -y -70 9o 10 153 - 120 0 235 - I /o -20 -04 -'J'i -8 5 15 502 1 1 315 322 I 55 1 - 5 I •! -27 203 1^4 -7 2 9y 209 12 22o -22 J 2 6 15 4 39 -26 -02 2 1 -0 -79 -80 13 -66 10 3 7o0 -732 -25 657 643 -5 150 -152 14 1 09 3 1090 4 212 -216 -24 -02 121 -A 190 -172 15 4 0 6 404 5 1 70 16i -2J 1 02 150 -3 1 <^6 -1 1 I 16 343 365 6 1 90 -193 -22 -00 63 -2 -01 -1 1 3 17 249 -202 7 1 3J 9 13 39 -21 600 -057 - 1 216 2 03 13 I 51 -2 0 7 8 155 -IVO -20 207 1S6 19 1 006 -1 003 9 270 -260 - 19 545 - 5 5 1 i= 1 3 . K= 3 20 260 -26 9 10 2^^ 200 -1 B -/5 -77 21 I 4 3 120 1 1 51 / -5 1 9 - 17 59 6 51 1 0 101 1 83 22 -dl 1 12 12 4 52 447 - It. 204 -1 oO 1 190 -160 2.i 29 7 303 13 -70 29 -1 5 5o3 575 2 -OJ -73 24 -05 4 4 14 033 -031 - 14 21 4 -21 5 3 I «7 -I 72 25 160 202 15 451 -453 -13 -o7 -62 4 152 -1 53 2o -96 -145 16 31 2 -325 - 1 2 04 3 04 1 5 1 54 168 27 41 1 -4 5 9 1 7 -02 -293 -5 203 -230 Id -05 -1 Oi -13 -t>7 9o 0 -01 24 -4 l^'^ 162 19 -dO -I 9 - 1 2 22. / 2 14 ^,'.3 31 7 25 302 -204 -t> '«34 37D 15 2 Jo 22'f -21 J77 -306 -20 -88 42 -5 • 169 - 154 16 21 1 192 -20 -SO 1 IS -27 226 -2 20 -4 209 -100 -29 1 2e> -1 40 -19 -Oo -42 - ^6 -3 4 2 -3 406 -433 -20 3o0 3 79 -18 454 -433 -25 3 JO -30o -2 36e> 370 -27 502 492 -1 7 151 127 -24 -30 -79 -1 120 -33 -2b -79 I 15 -16 -Oo -13 1 -23 -77 -9 -25 -77 17 -15 It) J -190 -22 -33 -13 H = 6. K = 4 -24 126 1 33 -1 4 -till 69 -21 40b •to 2 -?3 301 -32 4 -1 3 -03 9 -20 -01 -130 0 432 -420 -22 201 161 -12 329 322 - 19 2O0 2b0 1 I 4C9 -1413 -21 5 90 -oOl - I I 2 0 -4 30 -20 -80 47 0 4 68 -470 -8 131 122 -13 -8 1 102 -19 62 1 61 5 1 702 - 676 -7 560 562 -12 1 20 -76 -1 8 126 172 2 371 - 37 4 -6 -69 6 - 1 I -dO 1 17 -1 7 215 -195 3 309 -306 -5 654 655 -10 -81 -14 -1 6 -73 -73 4 61 4 f>=>4 -A -59 19 -9 296 o21 - 15 52 2 -5 15 5 1 0 32 1 CVO -3 -69 -52 -a 1 43 -68 -14 107 -51 6 ■226 233 -2 379 -380 -7 -6 1 -53 -13 ■234 282 7 3 59 3al -1 549 -574 -6 -82 o2 -12 51 4 526 8 4 1 1 -4 11 -5 18-> -162 -1 1 42 3 425 9 770 -7r.5 H = 1 0. K: - 4 -4 -8 2 -53 -10 2'i4 225 10 -7d -36 -3 -81 0 -9 491 -480 1 1 255 -275 0 309 305 -2 164 1 34 -8 3 55 -4 2 7 12 1 37 -1»0 1 375 380 -1 41 3 41 6 -7 2513 2452 13 305 -2 94 2 1 60 -1 61 -6 1324 -1274 14 324 319 3 274 -279 -\ = 1 4, K.- = 4 -5 -67 -2^ 15 -81 75 4 -81 51 -4 228 1 78 16 -79 20 5 365 -363 0 164 - 199 -3 2335 -2282 17 -81 48 6 169 -1 68 -24 -37 1 1 1 -2 1535 1 4 59 10 -83 -34 7 -78 -66 -23 271 2 85 -1 57 4 501 19 454 436 6 221 -219 -22 -do 3 4 20 24 8 -232 9 41 6 420 -21 1 ti6 - 103 H = 3. < 5 21 - d 6 20 10 2 74 -279 -20 21 3 218 -29 273 -247 1 1 159 130 -19 452 -^^8 0 96 -37 -28 131 8 7 12 190 215 -18 -63 6 1 185 180 -27 -32 -I 5 -29 352 34 4 -17 -82 05 2 890 -078 -2a 277 271 -26 179 1 1 8 -1 6 -83 -93 3 1063 -1143 -25 53 1 53 7 -27 -81 -63 -15 21 2 193 4 J j8 -320 -24 23 4 299 -26 -SO 37 - 14 20o -222 5 44 1 - 4 8 5 -23 82 7 82 J -25 41 1 -423 -13 -i3 -84 6 789 769 -22 12C -163 -2A -80 -113 - 12 24 3 250 7 1 490 1431 -21 1 88 -1 77 -23 296 -2 8 1 - 1 1 1 20 -oO e 224 2 09 -20 1 72 -1 95 -22 -80 -76 - 10 21 7 20o 9 146 -1 14 -1 9 fO -21 54 3 53/ -9 -o2 25 10 280 -252 -18 i 1 VJ — i i i -2 0 308 -3 1 0 -8 246 -229 1 1 28 9 279 -1 7 344 335 -19 693 703 -7 229 -222 12 339 -378 -lo 179 21 4 -18 -79 5 -6 233 -188 13 350 372 - 1 5 738 7 76 -1 7 478 -478 -5 -33 -64 14 124 1 13 - 14 1 17 140 -16 2 95 293 -4 1 dO 182 15 30 5 -2S3 - 1 3 -67 -38 -15 51 1 -490 -3 462 470 16 178 202 -12 4 76 — 4 8 6 -14 270 247 -2 125 -92 17 402 -371 -1 1 601 - 5o4 -13 1 ft? I'tO -1 -8b 18 13 -32 -27 - 10 2 38 - 190 -12 6J5 -625 ' 19 370 363 -9 768 71 1 -11 -75 -47 H = 1 , K: 5 20 -8'. -32 -3 1 90 193 -10 243 -236 2 1 318 335 -7 1158- -1 lo5 -9 -75 40 0 6 36 601 22 1 75 -193 -6 6 26 672 -8 398 391 1 622 664 23 240 -224 -5 212 -19o -7 300 302 2 392 4L.7 -23 — 9A -99 -4 -69 -58 -6 323 319 3 1 1 3 - 163 -27 335 -340 -3 1 09 9 1111 -5 -77 1 12 4 52o -o6 5 -26 -QB -•3S _ 2 779 - 784 -A 166 -195 5 775 -730 -2 5 274 -290 -7 134 - 1 13 -3 4 82 -493 6 140 -G3 -24 -96 16 -2 2 75 28 1 7 -68 -4- -23 451 504 H = 7, K= 5 -I -70 50 a 471 '^54 -22 269 3 73 9 53 6 5o7 -21 4*3 4 76 0 1 6 0 150 H= 12. K= 4 10 1 93 -2 1 9 -20 421 -4bo 1 334 -347 11 21 7 258 - 19 84 9 -a2i 2 7 3'* 72o 0 -80 64 12 15 1 162 -18 -73 -31 3 1 2 5o 1 30o 1 -82 -74 13 472 4W9 -17 53 9 -531 4 294 304 2 -82 £>4 14 370 -38o -15 -71 127 5 622 645 3 580 -589 15 337 -34o -1 5 510 -503 6 3al - JoS 4 -35 -69 16 -77 40 -14 61 1 619 7 842 -85 7 S 174 -154 17 278 -2o7 -13 342 315 8 1 44 -144 6 -87 -96 1 8 -d4 75 -1 2 -63 -57 9 -80 19 7 431 433 19 3c:9 -825 - 1 1 97 - 1 1 10 -8 1 35 -27 528 -527 20 -3 0 1 372 -1 0 -o9 37 1 1 1 77 - I 60 -2 6 177 -I v? 21 -W9 1 ol -9 603 56 9 12 1 1 5 1 0 4 -25 172 -203 22 - 9-i -30 0 -8 1022 -1012 13 2C2 -201 -24 -U5 -115 23 53 1 538 -7 -67 - 59 14 -81 - 75 -23 42 1 41 9 24 -107 -97 -6 276 -282 15 140 147 -22 -85 -1 32 25 21 8 -20'^ -5 639 -o79 lo 1 33 -93 -idl 694 o7 3 -27 -8'j - 1 04 -4 636 595 17 1 9<. 1 V4 -2 0 -84 124 -2o 209 -213 -3 222 -160 -29 3^8 -369 196 FO FC FO rc FO FC FO FC 20 27 2b ?b 2 4 23 22 21 -07 43'.i 1 66 4b8 1 1 6 0 1 2 -80 28 1 3Jb -3 270 -306 -12 -1 1 -10 -6b -85 -30 -70 -3 -2 - 14 - 1 3 - 12 195 -•68 72b ?34 -87 74b 4 JO 438 24 3 4 626 1 7 0 -644 -1 62 -9 -8 -8<> 288 55 31 1 - 1 1 1 - 10 i9b - 1 lb 14/4 103 tit.3 4Cb 6 J 9 -bb3 -39 9 -6b0 b . 6 7 l.O 1 2 1 8 4 3'. -593 208 4 3b -7 -6 190 1 84 -1 09 1 53 -9 ij:>o -8 188 0 - - 7 1 b 3 1 - u3b 1 9 08. 1 4b0 2 354 732 -916 84 4 713 20 1 9 333 3d9 3 06 404 0 9 lo2 -i4 1 3 9 lOo H = Ot K- 6 — 6 ■" - b 300 ■Jd 17 1 6 -1 5 -7tt 319 -74 61 7 -120 31 1 -79 64 1 -27 -26 -2b -24 30 o -y3 bJ2 -tJl -322 -103 -538 -3 0 1 1 : 2 3 1 64 1 1 04 3 -70 657 1600 94 8 70 -615 -4 -3 -2 -1 7 4 tt 8 7 2 87 7 65 7 ' 1 4 322 -2 90 -23 37 9 392 4 ; 1 b08 - 14 6 9 •13 -7 I -I 1 5 -22 3t>3 36o b ; 1 71.3 - •I bl 5 H- 4 1 y-- 6 12 -1 1 -10 - 9 126 -6tt -6 V 130 -6 7 -21 -20 -19 80 7 274 1 8 2 822 -29o -1 9i 6 7 d 8b7 74 •♦ -64 -■874 -730 2b 0 1 9 58 579 -991 -575 29 1 -291 -10 -no -4b 9 840 778 2 21 8 -225 07 799 9 75 -7 a 1 '.. 32 a 77 9 -349 - 17 - 16 399 -81 -3 8b 22 10 1 1 lab 280 222 306 3 4 -6b 803 — 6 2Ti 201 - lb 31 2 -294 12 1''2 142 5 962 — 5 833 8 0b - 1 ^ 24 b 24 7 13 396 -339 6 7 26 7 3 8 — /J (, ;vy -62 7 -13 182 161 1 4 -73 -89 7 649 66b 1 30 -599 -3 -2 - I 4? I 240 440 -2 12 -12 - 1 1 -8 0 -dO 7 7 10 15 16 39 9 359 421 -364 0 9 - 73 620 460 -463 -10 -9 -80 -79 57 -34 17 18 28 1 388 282 399 10 1 1 4 28 Jit. - 4 0 9 - 331 J — 9. K: - 5 -8 432 - A 40 19 24 8 -250 12 30 7 - 326 1 — -7 21 2 187 20 30b 280 1 3 bo7 3/8 0 1 258 277 -6 21 6 -2 14 21 4 60 -4 6b 1 4 209 205 2 1 8 2 08 -b -81 -1 O.i 22 20 7 -275 lb 2 7 H -2t.a 2 4 328 -00 324 SB -4 -3 1>8 16 i 103 - 1 39 ■ 23 24 I4b I 18 lob I 16 17 468 42 1 4 04 -414 1 79 - 1 49 -82 92 25 293 291 18 24C -2 19 5 C 7 e 9 35 0 1^4 269 ISO 2 7 1 -3 39 -1 Mi -261 1 7b 267 -1 H = 0 -30 IJ. K. 232 60 5 -247 26 H- 0 318 2. K: -67 -3C2 6 56 19 20 21 -28 -27 - 04 273 309 -86 127 9<> -2o4 314 - I 96 1 0 - 00 -a 1 2o2 -263 1 68 3 681 -26 3 1 3 :i2Z 1 1 1 87 160 2 lo I - 171 2 554 -547 -2b 267 2 76 20 1 2 -83 16 3 229 -^6^ 3 870 -?:)3 8 -2-+ -8 1 13 14 -29 -28 -27 -26 -25 -24 -23 -22 191 z:>\. 22b -M?. -80 If. 7 31 9 2S0 636 -79 173 -219 223 -9 30 -1 b4 -316 -2bb -6bb 26 -25 -24 -23 -22 -21 -20 -19 - la -1 / - lo 24 4 174 b4 0 - 64 225 -04 547 -8 2 -81 I3t. 233 194 543 4 238 -93 -5t>0 -13 -8b 1 14 4 5 6 7 8 9 10 1 1 1 2 13 342 144 168 812 1 263 -68 -L.9 7 03 433 -7b -35 1 1 15 -161 i2J 1259 -59 -5 -/•I J -4 2 J 19 -Z6 -22 -21 -20 -19 -1 8 - 17 - 16 -1 5 -1 4 332 3 46 ZC>2 3V6 4 06 677 447 533 72 6 440 3'i4 350 -3 66 -3 92 -413 -i38 4o2 53 o 73 1 4 1 4 -2 I 2 2-^^ -21 7 -I b 2/1 277 1 4 196 -175 -I 3 6 9b -b ;> I -20 I (>b 1 2 * -14 -79 5 15 288 288 - 1 2 2 95 - ::; 9 3 -I y 81 2 8? r - 13 -81 3 7' 16 174 172 - I 1 -67 - I 08 - t 0 -81 -26 - 12 201 -264 17 •♦1 0 -3 38 - 10 453 - 403 -1 7 -78 -70 - 11 1 9 7 -2 04 1 8 2/2 302 -9 809 034 — 16 209 -2uo - 1 0 -32 -99 19 21 2 -2 88 -8 162 - 1 3b - 1 b 6b I -L.'. J -9 403 42 1 20 159 -241 -7 302 - Jb'J - i A -76 -3 1 -d -8 I 5 7 21 -8l> 1 17 -6 59t; 583 - 1 J 1 24 5 0 -7 2 09 -203 22 273 -296 -b 1 099 -1 098 -1 2 -11 bb6 331 560 329 -6 — b 23 1 21 0 203 -2^ 0 24 46o - IC 1 4 73 -191 -4 -3 1123 773 1 1 o9 -812 -10 -9 203 /b.T 306 -7 53 -4 -3 20 4 4MS> 222 bOo -Z7 -2fi 20 9 20 - 179 -233 -2 -1 202 27 1 2 1 3 26 5 -0 1 lU -110 _2 128 - I dd -2b -79 -9 -7 6b 8 671 -T 227 199 -24 -t 5 1 82 H = 6t K .= 6 - 6 b ; . b -b4o -23 578 556 -5 23S 2 33 H = 1 5 . i',= 5 -2 2 2 07 264 0 285 - 3 1 1 -•:.2 7 4o7 -4 -3 270 764 -25b -763 - I 8 -36 14 -21 -20 1 4 5 2 -.'4 165 298 1 2 0 10 503 . -2 299 30* -17 1 o9 14b -I 9 -7 7 -53 3 7o5 7 7 3 :>?.7 -1 12 4 / • - 1 (> -3 0 -34 -le 2b0 -2 2 1 4 52 5 - 1 b I T»2 1 bo -17 42o -413 5 325 334 H = 1 I • 1 <= - 14 I 79 -1 79 - lo 21 6 -215 6 -77 1 Ob - 13 -8 b - 106 -15 I 40 1 24 7 7 55 - 7 59 197 FO FC FO FC FO FC FO FC 0 924 -9 3t> -8 293 296 -6 l5o 1 61 -5 1 062 1 060 9 1U4 -21 2 -7 31 3 -310 -5 3:10 -3 36 -4 458 521 10 -6 2 -84 -6 0 5 1 — L>38 -«4 4ts4 '475 -3 437 438 11 4 75 455 -5 90 2 904 -3 246 -232 -2 1 15 -96 I? 2:u> 214 -4 1 00 3 - -1 COO -2 105 129 -1 318 - 3 3o 1 J -81 40 -3 4 J6 506 -1 195 184 14 -00 23 — 2 -75 -ol H= 3. K 7 1 5 12H -148 -t 139 - 2 1 5 H = 1 <•; . K: = 5 10 -82 -52 0 265 >92 1 / 181 1 93 H = 10. K: - 6 -21 -87 -113 1 458 -4-» 1 1 a -86 -101 -20 — 60 -21 2 214 2S-^ 2ti 21 1 209 0 1 86 195 -19 1 08 -1 30 3 I 1 6 140 ?.7 142 145 1 3 7-J ZoT -1 8 -85 27 4 184 -159 26 304 3o0 2 1 4 5 - 1 4 d -17 -84 34 5 2 36 272 25 203 20b 3 242 -2o7 -1 6 -85 1»0 6 121 -1 54 2'. 171 - 1 9 0 4 2/ 1 - 26o -1 5 -84 -J>2. 7 877 891 23 631 -64-% 5 28 t -300 -1 4 -34 0 8 154 176 22 316 -319 6 -3 i -114 -13 -84 -120 9 706 -71 0 21 353 -340 7 265 24 4 -12 21 I -214 10 3 04 308 20 198 -227 8 503 509 -I 1 2 39 234 1 1 340 -351 19 -78 13 9 I 49 136 -10 252 -251 12 63 1 -628 18 219 182 10 llW 1 .^1 -9 556 661 13 527 52 9 17 352 376 1 1 2S3 -274 -6 3 94 397 14 1 19 133 16 16) 1 72 -27 -84 -90 -7 232 -214 15 658 634 15 160 138 -26 3'» 6 -346 -6 22 7 235 16 '113 4&6 14 -72 -40 -2 5 183 -^02 -5 250 -244 17 399 -413 13 193 193 -24 I 1 7 120 -4 -5 8 -36 18 249 -25 5 12 ^ii3 -?92 -23 395 4 15 -3 1 5l> 156 19 43 1 -429 1 I 914 916 -22 296 28L. -2 232 -^^^ 20 -85 6 2 10 2 CO -288 -21 264 287 21 4<16 450 -9 755 76! -2 0 131 149 H = 1. K: 7 2 2 -90 52 -€ 1085 1088 -19 -31 1 06 -27 232 21 7 -7 8 58 -853 - 18 2J7 -21 0 0 756 -713 -26 -83 - 52 -6 127 140 - 17 3 1 3 -315 1 1 7 8 -1 87 -25 242 226 -5 400 -4 1 1 -16 35 1 -336 2 277 260 -24 -81 57 -4 262 -278 -15 -30 87 3 144 1 00 -23 -79 80 -3 899 879 - 14 1 1 6 90 4 775 -7 69 -22 158 9 3 -2 753 -728 -i3 19/ 227 5 69o -67 J -21 2 7h -2/8 -1 171 -183 -12 47 7 47 1 6 253 200 -20 -ii2. 93 -1 1 61 9 -629 7 1 433 14 50 -19 608 -692 1= 8, K = 6 -10 317 312 O •-* 333 -322 -18 121 -143 -9 82 9 -62d 9 879 91 1 -1 7 -77 51 0 677 674 -8 759 -752 10 14o -159 - 16 - 75 -42 1 479 469 -7 J-t^J ^^a 1 1 527 -521 -15 539 596 2 161 150 -6 17b - 1 9 7 12 165 191 - 14 288 2 46 3 -80 129 -5 239 229 13 125 -1 02 -13 347 -347 4 339 -333 -•* -80 76 14 112 -I 16 - 12 137 -134 b flt,3 -4 59 -3 229 -245 15 207 l^'* -1 I 1 372 -1 376 6 20B -22o . T 2ja ci82 16 148 -93 -10 206 -203 7 419 -405 - 1 -8 I 3o 17 147 125 -9 791 793 8 -SO -53 18 -82 71 -a 231 233 9 -79 89 H = 12. K, 6 19 000 -579 -7 15; 11 19 54 10 -79 92 20 -83 -19 -6 -65 — 5 1 1 220 194 0 322 -31 * 21 42 3 -425 - 5 522 -54 1 12 -82 143 1 128 -1 03 22 -84 -1 16 -4 938 100 5 13 193 -201 2 I oO -1 «9 23 -84 49 -3 1 82 1 3 3 14 -ti'i -79 3 253 -2 3i^ 24 -85 -48 -2 273 -271 15 147 143 4 132 1^4 -26 -83 0 -I 333 -3o4 28 -83 14 5 21 6 I 97 -25 1 ! i 62 -2 7 183 201 -25 -84 4 9 -2 4 176 161 H- 5, K 7 -2 6 303 -2';.4 -24 123 44 ~ZS -81 1 1 1 ■25 261 -252 -23 ,i>iZ 365 -22 -75 -71 3 336 3 52 -24 -80 38 -22 280 200 -2 1 ■ 5 48 55! I -oa 23 -23 390 -3 69 -21 -33 -33 -20 245 -258 2 5oa -55 3 -22 3 40 -338 -20 1 28 -1 1 9 -19 28-:) -269 5 1 41 -1 Co -21 -!;o 128 - 19 2'..0 -2 13 - 1 8 4C4 41 1 4 3o3 3/V -20 147 132 - 18 415 -39 j -I 7 377 -370 5 6u9 obb -19 195 175 -17 -3 I u3 -1 t- 331 -340 6 145 170 -18 52 3 529 -16 147 160 -15 49o 491 7 1 133 - I 1 '1 ! -17 171 -149 -1 5 3rj5 3 ya - 14 Zi7 - 322 8 2o... 257 -16 295 -280 -14 251 2o3 -13 508 492 9 94 0 -9:. 5 -1 S 483 -'>99 -13 1 79 -I 82 -I 2 6S.0 72^ 10 -81 -24 -1 4 353 -3o5 -12 -31 -3C -11 2 69 -283 1 1 497 5 08 -13 4o3 464 - 1 1 202 - 195 -1 0 1 10 -109 12 13C -1 0'-» -12 158 188 -10 1 78 -16o -9 1398 -I •i02 13 248 215 -1 I 314 302 -9 407 '.2 4 -3 104 - I •. 7 14 136 1 21 64 9 -64 5 6 -UO - l\ -19 -84 0 -20 3 70 37 4 ■20 ■^i■.^^ 315 7 374 3o5 -1 0 20 y -21 7 -1 'i -80 -20 19 249 2 73 0 -•J 2 - 1 Co - I r 133 193 -I 8 -3 0 1 04 1 t) <.6<. -4 72 9 4?U 4 5 7 -1 "3 1 3o I 30 -17 5oo -503 ■1 7 ^9U 596 1 0 -04 23 - 15 109 -1 69 - lo -73 -80 lb 36'.> 375 1 1 -06 - 1 8i> -14 245 231 -15 &ZZ 836 1 'J 476 -478 12 -:16 102 -1 3 3D3 -203 -14 -74 -30 •14 290 30 0 -27 -34 -118 -12 190 -1 70 - 1 3 142 147 •13 41.9 -44 7 -26 122 - 1 1 1 -1 1 135 - 162 -12 24 5 21 7 1 2 733 -711 -25 -a 1 - 7 3 -10 -83 -7 7 - 1 1 1199 -1215 •1 1 -69 M4 -24 1 50 I 4 3 -9 621 633 -10 30 5 -292 ■1 0 -70 37 -ZS -7o -31 -3 -04 61 -9 330 395 -9 lOiiC 10ci3 -22 - / i -77 -7 214 21 7 -3 192 1 70 -8 -6t4 2 -2 1 4 1 1 403 -6 -85 37 -7 708 725 -7 4/. b -420 -20 32o -32:i -5 255 -259 -6 765 775 -6 277 -2 60 -I ? -30 -o3 - '♦ I 4 3 -107 -5 351 39 3 -5 501 -525 - la iil 4 14 -3 2 3 5 -240 -'1 216 1 97 -A 228 -251 -1 7 453 -4 i9 -2 -06 -120 -3 1 12 I 1 7 -3 4 7^1 -4 5 6 - 16 295 -3 13 - I 12t 92 -2 13 76 - 1 3 7 9 -2 94 -19 - 15 307 316 -1 699 - 6 9 9 - 1 190 1 o-» -l-'« 43 1 -4. '3 H = 0,- K,= 3 -1 3 72 4 72 4 H~ 4, K 0 t= 7, K: 7 - 12 530 'oZ^ 0 I 309 - -12 90 -1 I -/9 03 1 246 248 0 520 500 0 -75 -40 -10 -79 1 5 7 2 152 1 70 1 31 8 -3»9 1 438 424 -9 1 34o -I 333 3 833 -8S2 2 107 -\ ii 2 340 -351 -t5 2J2 -iiy 4 992 902 3 450 % J4 3 12t. 95 -7 -79 -92 5 3 93 -4 0 0 4 o99 -7C2 4 - V ■> -40 -6 -r J — 2 6 397 370 5 405 t,.-,^. 5 123 -98 — ;> 4 75 4 74 7 249 274 6 320 -2Z'i 6 -81 1 1 7 — •'♦ 31 6 34o 6 4 r ■♦ -501 7 -75 22 7 574 -582 ~3 J I 2 3:7 9 496 495 8 527 524 8 -61 49 -2 21 4 2 1 0 1 0 264 -2 5 1 9 539 -359 9 21 I ?36 -1 -79 -51 1 1 -73 -25 10 32 5 3»0 10 176 -1 07 12 241 -2o2 1 1 -&:i -133 1 1 -83 144 H = 11 . K 7 13 4 22 -404 12 14d 128 12 265 249 14 -77 25 13 463 472 1-3 166 -150 0 -00 14 . 15 -79 57 14 1 2 4 -6 14 -Ct3 -59 1 21 0 -2 13 15 -31 -1 04 15 -dl -85 le. 326 -303 2 166 1 71 17 129 7 0 16 165 1 30 16 2 37 -209 3 -di -ol 1 0 463 455 I 7 260 -267 -2e -84 -6d 4 -8 1 -4:. 19 -0 I -123 16 364 - 3 t 4 -2 7 202 -200 5 -34 -47 20 165 -1 64 19 -86 89 -2t. -82 -23 6 -35 - 12-» 21 134 -125 20 -37 33 -2& 265 -239 7 342 348 22 206 -204 -26 206 -21 5 -2 4 -60 -2 -25 -84 1 19 2 3 1 <.9 -122 -20 262 2 54 -2 3 122 -122 -24 -02 - 1 6 24 343 333 -24 442 -4 36 -22 -79 47 -23 -32 10 2. -ZS -31 'f4 -21 -tl2 1 I 3 -22 -30 -24 H- 2. K- = 8 -22 2 48 220 -20 1J3 -95 -21 -00 -12 -21 -01 -82 -1 y 39o 307 -20 1 :t3 I 62 0 214 -223 -20 378 379 -10 - 79 1 - 19 2^6 -290 1 Orti* -676 - 19 245 -2o2 -17 I 19 132 -1 3 -79 -4 2 1 1 y.-> 1 1 30 -JO 6 74 -562 -1 6 -77 2<* - 1 7 -79 -I 00 3 127 1 00 -17 I 3Z 1 56 -1 5 2''4 -279 - I 6 -79 - Ji 4 -67 13-4 - 1 6 127 -110 -14 -76 - 1 1 - 1 Li 436 509 5 -60 81 - 15 120 107 -1 3 -75 107 - 14 -nO 80 6 24 9 -253 -11 - 75 -.!0 -1 2 1 36 1 3 9 - 13 -79 7 7 275 282 -1 3 697 - 71 1 -I I 933 9o4 -12 1 2 0 -So 8 1 1 1 -60 - 12 129 1 56 -10 -73 <*2 -1 I 61 2 -f.33 9 719 73 9 - I 1 163 -1 50 -9 273 -252 -10 -3 1 -93 10 223 235 -10 -71 2 5 -8 -73 25 -9 -3 I -31 1 1 609 -691 -9 67 7 576 -7 17 11 -1704 -d -3 1 -72 12 21 1 -J 87 -d 4 36 484 -6 2^3 233 -7 800 81 1 1 3 -70 -74 -7 3J4 i'kS -5 ISO 1 32 -5 255 -24 3 1 4 -:-. 1 -20 -6 154 -150 -4 btifa -694 -5 -00 -5 15 776 772 -5 127 -1 J4 -3 21 4 ■^z■:J -4 33 7 343 1 6 -H3 66 -03 385 -10 -/9 52 13 482 -'►72 1 4Q3 4 9J> -9 5/0 -5 71 H = 14 , K; - 8 14 -81 -59 2 l^'iO ■ -1221 -3 4o2 -MliJ 15 1 36 - 128 3 220 193 -7 71 5 -700 -15 -65 -18 16 -81 -20 4 43 1 -a 1 cj -5 -7 8 -24 -15 321 -2 97 17 355 -349 5 -79 39 -5 1 75 1 5i> -1 't -67 86 18 -85 -85 6 325 34 3 -4 7 511 7 46 -13 196 -208 19 -85 33 7 22 1 -206 -3 6^0 602 -1 2 -8o 23 20 293 -29 3 6 199 1 72 -2 580 595 -1 1 327 329 -25 129 - 1 57 9 453 -447 -1 -8 0 -96 -10 -67 93 -24 431 -43 3 1 0 201 -1 e-j -9 279 2 7'» -2 3 275 294 1 1 374 351 H = 10. K 8 -8 -86 24 -22 141 -94 12 -81 99 -21 3 ,^ 4 4 1 5 13 -tiZ -7 0 2V0 -279 H = 1, K: - 9 -20 t\ 74 4ul 14 -83 -18 1 229 -257 -19 4 6*1 - 5 0 4 15 500 -480 2 ^66 474 0 1 509 - -1565 - I 0 198 -176 16 -07 -38 3 1 1 7 -126 1 105 -I 17 -1 7 -ei -44 17 136 133 4 203 1 94 2 591 538 -16 34 2 -340 -2 7 1 70 -171 5 17ti - 1 40 3 -68 7 9 - 15 2-i6 -Zi^i -26 232 -240 6 -d6 - 157 4 564 579 - : 4 -78 -1 02 -2 0 -63 87 7 -8 4 58 5 81 5 -82 3 - 13 -78 1 1 1 -24 303 2 83 0 -87 -1 35 6 537 -538 -12 -76 -78 -23 -82 -79 9 306 2 93 7 -73 5 0 -1 1 1 35 -142 -22 499 505 -25 -85 -1 01 8 687 -696 -10 437 - 4 3 2 -21 2 65 -2 7 7 -24 1 -,0 -150 9 467 *40 -9 537 603 -20 202 -279 -23 -33 -13 10 294 322 -8 75C 770 -19 156 -1 36 -22 436 -<» 16 I I -78 -I 02 -7 300 333 -10 -82 -1 25 -21 322 325 12 149 93 -6 o5 1 f>Ci8 -1 7 47 3 460 -20 2 30 184 13 -80 1 15 -5 942 -9o3 -16 -79 3* -19 1 82 1 75 ■ 14 -60 1 1 -4 387 -383 -IS 608 -607 - la 21 6 214 15 255 -257 -3 I 34 -1 25 -14 -76 47 -17 4o3 -4/1 lo 174 1 71 -2 3 55 -41 I -1 3 -75 -6 -I 5 -:i0 -35 17 -31 6t» - 1 d.iia -2 74 -12 -76 -90 - 15 571 575 18 163 149 -1 1 900 913 -14 -83 - 155 19 417 -421 H = 5. < = 9 -10 125 1-42 -13 21 9 218 20 454 -444 -9 173 -1 38 -12 -32 3 21 210 225 0 1 253 I 2 58 -e -73 - 1 09 -1 1 OC 2 -7 96 22 132 -1 00 1 -76 -35 -7 316 -2 9 5 -10 13 4 -1 84 - 24 -84 -94 2 3o9 -36 0 -6 3A4 -343 -9 179 - 160 -ZS 1 44 -149 3 149 - 1 3 4 -5 382 - 4 1 4 -8 -3 1 -33 -22 4 78 -462 4 779 -7y7 -4 1 75 -166 -7 26 1 2 55 -21 415 3 5 7 5 773 775 -3 338 -371 -6 180 141 -20 29 4 302 6 Ziil 30 3 -2 1034 1057 -5 21 2 244 -19 -79 126 7 219 ^C3 -1 402 41 1 -4 2^6 2 0 0 -1 8 -79 53 3 6 93 3:;8 -3 301 302 -17 370 -373 H= 8. K- 8 -2 3d4 -3 63 -16 -80 77 10 zni -272 -1 172 - 151 -15 -78 - 1 1 4 1 1 -80 80 0 406 -41 0 -1 4 148 151 1 2 233 -203 I 175 1 94 H = 12, K,: a -i 3 555 -570 13 I 51 -18 0 2 1 72 -134 -I 2 139 169 14 1 15 13 3 154 -It. 5 0 205 24'!^ -1 I -ti -58 15 -04 3 0 4 322 32-* 1 -86 -119 -10 24 7 -268 16 -85 -42 S 226 - 196 2 126 1 57 -9 2y J -Zl^ 1 7 -36 -t.3 6 254 240 3 -37 24 -3 -71 -59 -26 685 -653 7 -81 -65 -23 -86 92 -7 899 906 -25 lo5 171 8 142 - 1 44 — 22 -8^1 -a -6 649 661 -24 -84 j2 9 20 1 165 -21 1 :> I 1 J^ -5 39 0 4 1 3 -Z3 3 30 33 7 10 212 -1 78 -20 4-+ I 454 -4 8B8 904 -2Z 702 71 0 1 1 158 151 -I 3 -84 -as -3 -68 3 -21 4 02 -38 3 12 140 -76 - 18 270 -258 -2 75<) -7 85 -20 228 -233 13 176 - 1 ul -I 7 -i:^ 23 -1 -63 -, i - 19 329 -31 1 -26 137 97 -Ic. -Cj4 -111 - 18 .239 -255 -25 2 Ob -189 -15 -81 27 H = 3. K: 9 -17 237 2:>o -24 407 *05 - I 4 — o2 5 - 16 1 1 7 -v4 -23 -30 -32 - 13 2y 7 -271 0 o^,. 975 - 15 1 22 -113 -22 -77 -29 -1 i -82 94 I I 12 -42 -1 4 -79 -S6 -2 1 -HO -98 -1 1 cijy -292 2 4t.D 4 74 - J 3 OJ.3 642 -20 339 -357 -10 -82 - 04 3 1C5 109 - 1 2 - 77 -110 -19 105 1 05 -9 1 i3 ^0 0 4 286 -29 7 -1 1 2yO 319 -I a 405 478 -8 20 9 Z^( 5 264 235 -I 0 -75 34 -1 7 -80 9 -7 429 4 24 6 296 -Z7 2 -9 407 401 -16 1 37 109 -6 -84 31 7 832 AJii — 8 -74 -57 -1 5 1 ;>4 -I 71 -5 -ti3 84 8 -7^ -03 -7 564 -5i 1 200 — 1> -A -J 1 M- t o 4- 3 4 5 6 7 d 9 10 1 1 13 14 -2 6 -.?0 -ii4 -23 -22 -21 -20 -\<^ -Hi -1 ■/ - 16 -15 -i 4 -13 -12 -1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 FO 331 423 - 24« 200 211 7, K = b30 -tu 701 -81 1C9 -80 283 443 -81 -80 233 -82 -83 2i.6 -80 129 21 8 481 106 231 4 70 382 219 128 1 18 28'^ 228 Ibl -80 143 224 428 225 b3 7 3 72 708 617 377 1 84 7 77 -80 FC -348 ■4 08 -7 38 -243 197 -222 -62 5 1 6 -88? t.8 1 8 9 39 2 9 4 -4-j>0 84 -24 -2 4 4 -72 6 227 33 -81 235 4 99 -148 215 -'4 5 3 -397 227 153 -52 ? 8 '» 21 9 1 8 2 -93 1 17 212 4 3 7 - 1 'VI - 5 4 4 - J 264 321 59 7 64 - 14 9 7 1 41 -60 341 -95 -33 32 -301 4 65 4o2 -51 Z7 17 -344 - 155 -225 -42 6 - 150 -2o0 1 1 3 225 317 - I 1 5 ~7 ) -3f.8 -7 13, K- -85 -87 -8o 190 -85 146 -85 1 5o -85 24 6 -87 -87 -38 -8? 420 K = 1132 732 -72 4 I 5 82 0 1 5a 442 335 38 4 1 * I 5 2 U 30 a I d 9 ,^^Z 1 1 / - TO 1 22 -72 -1 73 -30 1 54 20 97 59 21 0 1 20 -45 -94 - 1 35 -4 Oo 10 -1196 7 75 -1 3 95 823 -15 1 -44 3 - M-o -334 - 1 t^d 5 3t> 3"/c -1 Ou 22 3 -y3 15 lu 1 7 IQ 19 20 21 2 2 H- 0 1 2 3 4 5 6 7 8 9 10 1 1 12 1 3 14 15 16 1 7 18 19 2 0 -2 3 -2 I -20 -19 - lb -17 -lo -15 -14 -1.3 -12 -1 I -10 -9 -8 -7 -6 -5 - 4 -3 -2 - 1 FO 171 -81 36^; 182 48 I -33 -84 2 33 2, K:: -72 220 402 744 326 21 9 317 -79 -78 492 2iJ 456 3 79 -62 204 <; 7 J -3 2 454 218 -30 4') 6 1 55 341 226 44 I 1 65 158 428 -81 55 5 2 56 -78 490 4 84 438 640 l<>6 1 4 5 561 322 2 55 7 5 3 377 302 H: FC 1 71 I 02 -37 8 -190 -4 30 -20 22 -24 6 1 0 81 21 4 41 0 -7 51 3.51 -I 6 9 90 -3 4 72 321 442 -333 47 - 21 3 -4 33 -437 233 103 -452 1 3 6 - 3 4 9 202 4'»3 21 1 -212 -'»34 o -606 262 - 9 503 4 9 J -4 39 639 -191 1 46 DOO -34 9 -253 -760 -3 9 1 3 J9 K- 0 1 2 3 4 5 6 7 3 9 10 1 1 1 2 13 14 1 5 1 6 1 7 •2a -23 695 461 344 435 538 -79 261 41 4 395 3D1 400 27 7 -ill 257 1311 295 -04 21 8 233 422 10 71 9 -473 -397 -51 1 52 250 4 33 401 2 93 -4 02 -283 -I 09 -250 1 58 -276 1 I 200 -233 4 19 -22 -21 -dO -I 9 -1 8 - I 7 - 16 - I 5 - 14 -13 -12 - I 1 - 10 -9 -8 -7 -6 -5 -•♦ -3 -2 - I H- FO 2.4 3 200 -82 5'yO -80 65 0 199 -80 2 40 361 334 471 653 -77 - 7b 20 4 2-.>3 -75 01 6 -75 2 1 7 539 H = K = 0 21 1 1 3 88 2 4 52 3 5 09 4 351 5 378 6 3 3o 7 -60 8 -60 9 31 3 10 '4 3'* 1 1 3 1 ~* 1 2 - t- 6 13 I fV 14 1 72 24 1 b6 23 -83 22 463 21 234 20 55b 19 343 18 -79 17 2<->3 16 127 15 52 5 14 -80 13 147 ■ 12 ^J'S • 1 1 21.3 10 Zt."* -9 36 7 -3 169 -7 231 -6 44 5 -5 -80 -4 -76 -3 533 -2 334 - 1 28 1 FC 237 1 68 1 08 •576 59 •6J7 - 184 23 244 506 -672 -88 -58 -215 2 5 4- -di -54 0 79 -230 54 4 10 1 88 - 38 2 -4 35 53 1 -328 37 3 380 52 1 9 -29 3 -4'< 3 -337 144 -1 25 1 68 186 -sa % 56 -2»2 -553 -345 30 2 14 84 536 -7 1 1 1 -2 + 3 -2 St. 2 83 - 3-»6 1-..9 -215 -44 9 1 I 5 -1 5 59 0 J37 -253 K = 0 1 2 3 4 5 t» V 8 9 10 458 312 233 3 52 394 -80 151 20 1 24 1 1 59 198 10 -470 334 -237 324 «36 -1 a -140 -219 -2 54 -163 I o5 201 FO FC FO FC = o FC FO = C 1 1 -85 1 15 H- I . ^- 1 1 -9 24 0 -2 3 7 -1 I 358 -340 i^'i 1 6 1 171 -3 497 -520 - 10 20 1 267 P.3 3 MS - 3 7 3 0 1 5 6 -21 1 -7 1 7 5 -I 06 -9 -81 1 03 2 2 179 - I 7 2 1 -/o -112 — 6 31 1 31 I -8 53 8 5*4 ;;i 240 - 2 C 9 2 2 59 248 -5 -79 -137 -7 -ei' -£.6 20 -til - 1 2 .1 3 168 189 -4 121 1 1 3 -6 JJH -353 19 3D6 .ii.9 t; -76 -Z2 -3 471 474 -5 -83 72 10 1(>0 -I 83 5 39 6 -386 -2 193 -208 -4 305 -305 17 49 4 4 99 6 33 7 -3 10 -1 1 14 -94 -3 341 -3 53 ■16 14 6 136 7 -79 -Zd -2 33 7 31 1 1 S -30 1 02 8 253 233 tl = 5. K = 1 1 -1 -81 -49 1 4 -uo -72 9 1 7 1 -1 86 13 226 -229 1 0 5*rt 5 58 0 229 241 H = 9 . K^ 1 1 li' 271 -2 7 7 1 1 3.- 6 389 1 153 1 1 0 1 1 3 71 -36 7 12 7 0't -t 9 3 2 -80 -7 1 0 1 36 -1 07 10 590 6 00 13 30t> 2 89 3 296 -309 1 -82 -8 -9 -b2 60. 14 53 4 -51 1 4 -00 -66 2 -30 5 -6 -01 4 4 15 31 5 -305 5 267 300 3 172 156 -7 2 I 3 231 1 f> -82 3 3 6 30 6 319 4 -84 62 -6 306 -37 J 17 -o4 -53 7 195 1/4 5 2 1 3 - 197 -5 -a2 9 9 18 41 8 413 8 } 24 -101 6 -33 -85 --i 'i6V 4 82 19 -3 5 -121 9 241 225 -2 1 1 70 ya -3 1 90 -193 20 -86 -44 10 72 9 -738 -20 3t>9 3C.9 -2 3 v. 1 3 56 -21 25 6 2'tiJ 1 1 306 -278 - 19 3J.i 363 -1 4o0 -<.47 -20 t 1 0 4 10 12 355 300 -15 202 174 -19 28 J 2o6 13 292 -2o9 - 1 7 261 303 1 0. K: 1 0 -18 -■JO -68 14 491 475 -16 276 -286 -17 128 lo7 15 196 184 -15 1 64 - 164 0 124 -1 04 -16 22 4 -222 -23 1 as 1 73 - 14 52 6 -D'l 0 1 135 I 64 - 15 Jit ^ -Js>Z — C-'Z -84 76 -1 3 270 -267 2 135 123 -n 409 -413 -21 P2 3 -225 - 12 I 4 3 1 5 7 3 24 1 -225 -I J 403 -3 7 8 -20 522 -527 - 1 1 -81 -22 4 252 228 - 12 '73 489 -19 448 -402 -10 657 576 & 255 - 2 4 5 -1 1 -80 70 -18 -83 -122 -J -81 53 6 -87 -105 -10 6^8 71 0 - 17 255 -2 4 7 -a 194 -21 6 22 432 -4 32 -9 1 12 - 18 -16 340 345 -7 -81 72 21 ?4? 202 -a 68 7 -727 -15 34U 305 -6 53 1 -52 1 •20 42 1 4 13 -7 195 206 - 14 536 555 -5 1 5/ -1 yO 19 391 41 0 -6 729 -759 - 13 320 333 -4 140 12 1 •1 a -84 62 -5 282 -291 -1 2 230 -214 -3 -81 - 1 19 17 -83 -87 -4 331 357 -1 1 -a; -45 -2 143 151 • 16 1 7 0 -152 -3 20 4 -242 -10 680 -705 -1 292 3 04 15 4 99 -500 -2 -76 -32 -9 -81 5 5 14 1S6 - 159 -1 393 4 13 -8 276 275 H- 11. K: 1 1 ■13 163 -1C4 -7 172 -150 ■12 2': 7 226 rl = 3, K: I 1 -6 524 551 0 140 -Ifil ■11 183 169 ' -5 120 31 -13 308 -312 ■10 -32 -86 0 1 26 1 1 5 -4 240 -?39 -17 -S7 -6 8 -9 270 264 1 2 5 5 255 -3 198 I 7-- - 1 6 375 -374 -8 l'k6 -1 83 2 162 175 -2 165 -136 -15 J2J -318 -7 129 1 49 3 21 1 - I 86 -1 196 -1 95 -14 -85 38 -6 1 33 1 35 4 1 34 -173 -1 3 124 -43 -5 145 -85 5 297 -3 04 1 :- 7. K: 1 1 - ! 2 644 6;^ 5 -4 124 -84 6 536 boo - 1 I 215 225 -3 31 5 -285 7 1 25 1 15 0 -81 59 -1 0 -85 0 -2 -32 -84 8 622 oOO 1 157 -1*3 -9 14 1 - 119 -1 -83 106 9 -82 56* 2 -02 -155 -8 353 -353 1 0 4*7 -440 3 167 213 -7 -a A 7 i= 12, K: 1 0 1 1 197 229 4 253 273 -6 -65 130 12 54 7 -54o 5 191 1 67 -5 -00 23 ■18 -86 70 13 J3Z -280 6 324 -2 9 3 -4 1 9 0 1 8^ -17 350 -328 14 277 2 92 7 lc4 -1 53 -3 179 I 84 ■16 172 - 1 8 4 15 432 -39 8 0 467 -4^6 -2 187 -192 •15 104 -1 88 16 2 39 287 9 -as -1 9 -1 -80 J8 ■14 -S7 15 17 -86 85 10 -87 122 -13 -86 79 -22 12o - 14 1 1 -sa -132 H = 0. K: = 12 -12 318 295 -21 Z^ 1 298 -23 214 -210 -1 I 199 1 92 -20 -82 73 -22 -04 2J 0 370 -384 -10 22 2 -238 -19 -B 1 -33 -21 209 -285 1 327 -331 -9 -<35 -1 o - 18 532 --■^9 -20 132 -102 2 132 1 d9 -e -85 -84 -1 / -80 - 1 05 -19 -83 12 3 661 -6o6 -7 -86 -31 - 16 220 -236 -18 400 409 4 1 4 0 - 1 25 -6 237 2:d7 -15 51 9 -4 /u -17 -BC • 59 5 -toO - 100 -5 -87 -Z9 -14 5 8 .' oO-y -16 295 29 5 o 1 o9 -204 -4 258 -22& -13 252 24 1 -15 A31 41 3 7 29 1 298 -3 129 60 -12 I 005 1 038 -14 lb2 -174 8 -80 -62 -2 320 -332 - 1 1 5o4 Ij/^j -13 117 - I 9 125 - 1 6 0 -10 59 1 -600 -12 832 -039 10 t.51 6oO 202 FO FC Fl) FC F O FC FO FC 1 1 i>69 ^b9 - I 1 5 0 I 51 9 -lU 283 -302 12 ?i>3 ?2'H -10 7i 4 -720 H- 1 10 . K= 12 - 1 / ?!•*'} 342 1 J 1 <.ti -178 -9 11.0 - loO - 1 6 1 2<> 92 1 A e>i 0 -4 92 -fa -01 lb 0 175 -140 -1 b I 8 1 - 1 Ob I t) -no 4 3 -7 273 239 -I / -'13 1 SJ. -1 4 JA^ 34 4 1 b 399 -308 -6 - d 1 91 - 16 53 4 -5.-^6 - 1 3 -82 -143 1 7 -B2 5 -b 1 1 7 6b -15 192 1 21 -1 2 -80 - 1 3. 1 U 3 -ifj 33 J -4 -0 1 79 -1 4 2 = 4 -2 1 0 -1 1 -80 1 1 2 1 V -t..l> 4 3 -3 4U4 -4 72 -1 3 -04 - t)4 -10 1«.3 -224 -2 ^J2 -?^-:^ -1 2 47/ 48 > -9 1 /4 - 1 59 2. K^ 12 -1 2u6 -2 7 0 -1 I -87 -56 -a -81 » 7 -10 2 38 231 -7 388 3^4 0 -80 -99 H = b. K- 12 -9 126 12 8 -6 123 -1 37 1 268 -2 83 -8 271 -270 -5 302 31 7 i: 3u7 3 93 0 138 1 42 -7 227 -230 -4 1 20 - 4 y 3 jx;? -316 1 237 222 -6 -Ot> 64 -3 253 - 2 79 A 7 1 i? " t>'/'j 2 337 -3 30 -5 304 301 -2 5i'2 -560 10 134 -1 1 I 0 375 -384 3 520 53b 13 1 t>b -: 32 1 1 I 03 -4b 1 7 66 -769 4 -01 -41 1 <^ 2 73 - 2 6 ■-< -21 237 ZJ'^ tl 624 4 36 5 -02 - 1 I 7 1 b -«3 -33 -20 1 94 -: 61 3 464 -5) 0 6 220 - 1 53 16 31 b 280 -19 -j3 -29 4 -03 40 7 43b -43 3 1 7 -Ot> -37 - 18 4dl 4 7b 5 IbO 1 75 8 -85 J7 ■?.o -86 1 5.« - 17 -0 J -uO 6 2 98 303 9 159 1 4 1 -19 -60 1 1 b -lo 50 6 490 7 Hb2 443 10 180 - 173 -1 U 498 "508 -1 5 1 38 -bJ a -00 12 1 1 - 8 5 - 2 ■ I 7 -83 32 - 1 * -a 1 96 9 1 1-6 - 1 29 - 19 354 3'i 3 -1 6 527 -blC -1 3 -b2 1 33 • 10 164 161 - 18 1 8 7 - 1 77 -1 ti -79 16 -1 2 555 -565 1 1 -82 I 03 - I 7 -tii -77 -1 1 124 1 05 - 1 1 1 .-! 5 1 29 12 -o4 103 - 1 0 30 1 293 -13 20b -197 - 10 239 -302 13 -33 -4 0 - 1 b 298 - itL y 1 2 54 0 056 -9 272 -221 14 310 -290 - 14 135 132 - 1 1 - Bl -66 -8 21 3 254 lb 193 -1 72 -1 3 -00 J 2 -1 0 1 bO 1 46 -7 -82 1 35 lo 340 -277 -12 347 -343 -9 21 1 1 85 -6 -81 -84 - 13 -85 I 15 - 1 1 ~ 1 U3 I 06 -3 -01 -42 - 15 20 5 224 -8 4 00 403 -t> 8X0 836 -2 194 19b -1 't 151 -123 -7 24 8 2 89 -4 94o 93b -1 230 247 -13 135 -1 12 -6 307 -2 9o -3 I 1 6 25 -12 410 422 -5 41 6 -4 42 -2 30/ -3 8 0 H = 8. K 12 -I 1 ls<5 138 - <♦ 161 -130 - i I o5 -I 84 -10 162 165 -3 144 - I 69 0 -81 -92 -9 197 -^25 -2 2 3o 243 r1= 4. K 12 1 -8 1 4o -8 42 1 -429 -1 -81 5 2 1 J 1 -9 0 -7 406 -354 0 275 277 3 220 -220 -6 3D0 339 H- 7 , K = 1 3 1 2 I C 194 4 -83 -7b -5 5bl 562 2 -PO 14 b 1 o3 -1 82 -4 147 157 0 -83 22 3 41 0 4 02 6 -8o -74" -3 277 202 1 270 24 5 4 -81 61 7 -30 1 13 -2 39 3 -403 2 347 -318 S -PO 62 -20 153 1 J J -1 103 -1 ^^ 3 1 1 9 -1 09 c 194 207 -19 -84 -8 4 1 5 0 - 14 I 7 252 -261 -18 51 7 553 H = 3. K 13 5 396 - 4 Oo t! 2 ■-.4 274 - 17 -83 1 5 6 1 37 1 4 •.> y 3m ii 2 96 - I 6 1 <* 0 - 1 -t3 0 149 121 7 -65 7 3 1 0 56 7 -5 52 -15 -8 1 - 1 ■^ 1 22 1 -1 73 - 18 250 238 1 1 324 -3 1 ) -14 bJ4 -bbl 2 3ill 372 - 1 7 29 9 - 2 94 I?. 4^i. -4 1 9 - 13 io4 343 3 -81 57 -16 -83 -33 13 -at, Ob - 12 1 2b -60 4 -80 35 - J 5 -34 94 14 436 4 1 4 -1 1 3o0 -3 7 1 5 bOl 477 - J4 •23 7 -22 1 -€ I -03 - 1. 1 - 10 t,-* 1 04 3 6 2 75 -266 - 13 1 fi9 1 9 5 -2 0 20f. - 2 0 J -? -?0 31 7 175 -1 48 - 12 -82 -OO -19 -84 r i -•^ -30 1 0 8 3 4 19 405 - 1 ! -82 -62 -18 5j4 -594 -7 1 72 - 193 9 186 - 101 -10 -02 70 -17 -82 -3 -b 21 0 -2O0 10 -83 57 -9 140 157 -16 361 3u5 -5 182 - 1 88 1 1 127 95 -8 -79 53 -1 S -80 ''2 -4 -8 1 - 73 12 448 -422 -7 2 27 - 2 33 -1 4 61>4 666 -3 322 297 13 I Jo -1 1 1 -6 1 bO I 50 -I J ;■• ? -271 -2 3:.3 3t.-d 14 -87 -58 -5 425 - 440 -1^ 20a -1 t.4 -I 39 5 4C4 -19 120 -4 -4 -81 4 203 FO FC FO FC FO FC FO FC -3 -80 4 9 -6 1 6 5 183 -1 2 -t;3 -36 0 501 4 96 "? 512 516 -5 41 1 4 1. 0 -1 1 -85 -1 15 1 353 3'+5 - 1 t.t52 562 -4 20 1 -ZO.i -1 0 -84 -29 2 -86 38 -3 1 3 0 1 04 -9 202 202 3 242 -260 -t= 9, K= 13 -2 54 2 -5 7 5 -9 31 3 -325 4 361 -362 - 1 1 7 d - 1 o9 -7 14o -157 -13 4fj6 4 74 0 26 4 -?3 5 -6 20 4 216 -12 1 91 147 -IS 269 270 H = 4, K = 14 -5 2 63 -2 7 0 - 1 1 152 - 167 - I'i 31 b -295 -4 130 1 4o -10 -84 1 1 -1 -i -O-'* 0 0 56 5 5 55 -3 239 224 -9 237 -353 -i 2 1 70 1 d-'i 1 -83 -I 1 2 -2 206 210 -8 161 - 1 4l> -1 1 -OG 64 2 1 J3 133 -1 -84 62 -7 -U4 36 -I 0 I 4 9 1 39 3 475 438 -6 37 9 -33 > -9 -S3 -2t> 4 -J 3 4 H = 1 , K = 15 — 5 3/2 377 -8 434 -4 2 5 5 1 1 7 -59 -4 263 -245 -7 27B -280 6 3o7 -3o9 0 422 -428 -3 2 JO -209 -6 1 9 3 1 87 7 313 -298 1 4 55 -42 i -2 1 78 1 6': -5 2 70 254 8 - 85 aj 2 1 35 1 1 5 -1 172 - 132' -4 24 0 256 9 225 ^:14 3 4^1 4 04 -3 lti9 1 54 10 142 1 13 4 49 1 4 60 H = 7. K.= 15 —2 -ti3 -23 -17 21 3 -162 5 -82 97 - 1 -83 73 -1 b 21 1 -2 0 9 6 147 -I 1 9 -8 2 74 -£87 -1 5 -84 -86 7 leo - 1 65 -7 2.<0 229 rl= 0. K= 14 - 14 16 6 205 8 2f-0 -24 2 -6 170 -171 -13 -dJ 86 9 -85 -114 -5 -86 2 8 0 746 -779 -12 1 28 -73 10 -84 55 -4 390 3 c' 6 1 -ti J -50 - 1 1 210 220 I 1 245 221 -3 328 - 334 2 -80 -4 1 -10 142 60 -1 3 4'! 0 -4 4 5 3 50 2 -479 -9 1 48 -1 60 -12 130 -4 7 H = 0. K = 16 4 -fiO 62 -8 270 281 - 1 1 3 76 377 5 3i 3 315 -7 261 270 -10 -82 - 6 0 237 -274 6 41 1 4 09 -6 31 4 - J4 6 -9 265 27 9 1 -85 -93 7 407 399 -5 208 24 0 -8 1 9 1 153 2 153 I 1 3 e 1 1 7 -125 -4 -81 -47 -7 1 99 -158 3 14 0 ■)1 9 231 -271 -3 3d8 -o20 -6 433 4 36 4 -84 79 10 -81 -54 -2 -81 -116 -5 402 -438 5 273 253 1 1 -62 65 -1 -79 -16 -4 -as 93 6 -84 -33 12 1 4b 120 -3 300 294 7 1 -^^ - 1 53 13 157 I 12 H = 6 . K- = 1^ -2 37 1 -402 8 1 32 1 <+6 14 1 91 -200 -1 -82 1 5 1 & -04 46 0 339 o32 H = 2, K= 1 0 1 .if a 233 H = 3. 1^: 15 H- 2, K.= 14 2 36 1 -378 0 -85 4b 3 -8 3 - 6 0 302 310 1 -84 -77 0 128 -140 4 283 -271 1 -63 -38 2 -8 5 123 1 123 -1 64 5 3o5 -3 55 2 360 346 3 -85 1 33 2 465 463 6 -86 60 3 208 2 88 4 185 132 3 -81 4 1 - lo 1 20 1 1 4 4 -85 36 o -86 -72 4 277 252 - 1 5 -86 -67 5 24 9 -257 -9 3'.ji 354 5 344 358 - 14 -84 92 6 326 -307 -8 I 57 1 55 6 -60 -32 -13 234 225 7 127 -1 00 -7 404 -4 1 0 7 355 -335 -12 164 -1 79 8 260 -185 -6 2 85 -242 8 132 -1 1 0 - 1 I -32 -41 -13 207 202 -5 1 74 - 191 9 161 -134 -10 -84 51 -12 196 1 49 -4 24 1 -a J 5 10 199 182 -9 -33 34 - I 1 427 398 -3 1 67 1 ■>6 1 1 -85 25 -8 lo8 - U,3 - 10 -8 5 30 -2 1 4o - 1 25 12 -87 -144 -7 447 4 1 8" -9 -82 -18 -1 -85 1 7 1 3 238 -205 -6 1 31 -15 1 -8 298 310 -I 6 194 -IB2 — 3 300 -324 -7 2 29 -21 0 H = 4 , K = 1 6 — 1 5 -az 4 -4 -81 58 -6 -84 57 -1 A -04 -64 -3 320 -294 -5 -85 -23 0 264 249 -13 2C4 -182 -2 422 4 42 -4 53/ -52 5 1 -86 I 0 9 -12 170 220 -I -3J 50 -3 34 6 34 7 -7 253 - i;4 9 -1 I -8 1 106 -2 173 -120 -6 -85 -d3 -10 -&1 -122 H = 8. K 14 -1 33) -32 1 -6 2 10 2 1 7 -9 -80 -1 04 -4 -86 - I 0 3 . -8 2?4 201 0 382 -377 H = 5, K 15 -3 129 I 34 -7 402 -451 -13 -8 4 -53 -2 140 - 1 22 Table B-5 Observed and Calculated Structure Factors for C^ (fph) ^Rh (cp) (tpp) 205 FO FC H= K = 1 Jr 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 -21 1C97 67 1 21 3 o -172 53 6 234 — ^ <* "^ -173 K- 0 1 2 3 4 5 6 7 6 9 IC 1 1 12 13 14 15 16 -18 -17 -16 -15 -14 -13 -12 - 1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 -I 164 4 155 30 1 1 179 332 I 2a9 128 53 7 3&9 254 41 0 -63 427 120 2S2 — ^, *! 22 5 -C7 153 192 -6 9 3:) 3 -53 432 123 t20 331 257 63 1 308 S"J9 IC2 50d 1102 552 1 -2456 -Bl -- 1 5 4 1 cr4 -259 - 1 r63 -loe 51 9 423 -?48 -423 -6 403 134 -2G3 1 237 -9 17 4 107 -90 -375 -52 4 ■'5 134 -84 2 -304 250 CO 7 235 -91 5 -36 553 I 44 9 -G50 K = 0 1 2 4 5 6 7 8 9 10 1 1 1? 13 14 15 -19 797 4 4't 61 1 12«t3 157 114 7 7 7 3-^8 3e.a 24 3 329 -66 323 -6/ 301 -70 104 195 -363 -772 -1260 223 1 1C7 14 -37 5 -344 252 3 34 -30 -317 3 6 30 1 38 86 ■18 ■17 -IC ■15 ■I 4 -1 3 -12 -! 1 -10 -9 -r> -7 -6 -5 -4 -3 -2 - 1 FO 177 -65 190 187 172 -61 617 5^ 1 4 60 313 52 2 1415 -b^ 1607 353 -45 920 1C6 FC 173 22 -191 183 157 -6 0 -62 1 -50 4 453 299 -537 ■14 9 3 -53 1629 42V 18'-' -518 154 K= 0 1 2 3 4 5 6 7 8 9 10 1 1 1 2 13 14 -19 -18 -17 -1 6 - 15 -14 -13 -1? -11 -10 -9 -8 -7 -C -5 -4 -3 -2 -1 1 047 30 7 559 46 4 1 ' 9 27- -55 2t7 -62 21 I 33 0 -69 2 93 -69 130 2 4 4 3). 1 35 7 -66 23 V 1 53 1 16 l'*0 3 c?. -54 196 2 20 369 163 964 254 9-i9 1 16 I 1 45 H= 0 1 2 3 4 5 6 7 0 9 10 II 12 13 ■20 -19 -18 -17 -16 -15 -57 286 59 1 624 62b 122 456 14 1 -t>t> 165 26 0 358 104 150 390 -66 414 -64 -OJ - 14 -13 -12 - 1 1 - 10 -9 -6 -7 -6 -5 -4 — 3 -2 -1 FO 223 374 410 4S6 176 409 21 7 238 160 1 1 C2 838 550 682 -57 1".= 699 ■26 0 525 442 1 86 2 18 279 104 • !97 -338 85 29 6 -o4 - 128 -243 -3i<1 363 9 4 -232 - 146 -89 145 406 -1 54 -201 201 32 2 -210 - I 035 -223 -776 253 -997 -64 307 -6 1 0 -6 19 3 28 6 0-O -103 -4 8 8 -112 6 0 153 - 26 1 -35? -125 — 138 384 2 -407 -18 71 0 1 2 6 e ic :i 12 -20 -19 -16 - 17 -16 - 15 - 14 -13 -12 - 1 i - 10 -9 -8 -7 — 6 - 5 -4 -3 — 2 - 1 FC 336 348 -4 02 - 5 1 5 180 431 2C6 -262 -226 1 C6 8 897 -5C9 -613 25 K- 2 53 337 6 48 993 301 46C 167 235 165 543 305 135 238 il > - iS 423 218 184 222 1 0 8 862 720 <;4 4 87 341 470 41 7 efc2 1307 1 195 130 4 1 8 0 I 2 -^ 4 5 6 7 8 9 10 1 1 20 • 19 ■ 18 ■ 17 ■ 16 - 1 5 - 14 - 13 - 1 2 - 1 1 -I 0 -9 -8 1 16 3£5 IBB 2 15 1 69 355 I'lS 213 192 132 -7 1 -72 -67 177 139 163 £27 -11 5 279 1 3S 330 693 ?9'-. ZC9 34 7 -371 646 9 86 -269 -475 165 223 151 - 15t- '305 1 6 -V 252 5t> -307 -52 428 237 J75 -228 96 852 74 1 122 - 4 7 7 -323 - 4 6 '1 J4l -722 - 13C6 1 156 165 4 75 1108 379 -178 -2iO U>9 357 129 -212 -205 147 98 -S8 -66 177 147 -191 -C3e -124 283 - l^fa -344 -63 0 61 SG9 21 1 -7 -6 -5 -4 -3 -2 - 1 FO 4 61 526 -56 '- 56 567 90 470 0 1 2 3 4 5 e 7 8 9 -2 1 -20 -19 -18 -17 -16 -15 -14 -13 -12 -1 I -10 -9 -8 -7 -6 — 5 -4 -3 -2 -1 H- 0 1 2 4 5 6 7 8 -2 1 -20 -19 - 18 -17 -16 -15 -14 -1 3 -12 -1 I - 1 C -9 — 8 -7 -6 -5 -4 -1 h= 590 105 6 0 6 -66 -67 252 173 244 1 13 205 242 -67 93 -64 -i>5 4 52 217 395 1 8 0 300 44 1 145 ^38 370 176 1 02 330 -54 134 326 275 FC -489 -544 4 5 -6 -56 0 6 -415 -603 -107 4 1 5 -6 1 -24 1 - lol 249 132 -U'8 23 7 81 -86 -7 1 -4 1 4-')9 216 -389 -188 309 415 -14 9 -453 -381 199 41 -33 7 -20 1 28 367 292 K- 230 242 -67 -7 0 1^;0 262 -70 21 4 108 326 -68 -&7 173 -68 4Cl -65 /»m5 24 7 148 425 194 464 1 16 541 300 573 390 -60 799 145 235 - 24 1 57 -94 -1 18 2c9 73 -24 5 -72 -325 -1G3 60 16/ 146 -380 -7 455 ■^32 -176 -4 14 206 474 -83 -546 -295 55 7 39 2 -22 -323 -142 K= 444 — 4 4 9 206 I o PC FO fC ro FC I o FC 1 ? 3 4 b 6 -?C - jy -It) -17 -16 -lb -14 300 -39 3 -2 -07 17 -10 521 499 -1 4 129 1 1 1 310 3i; J 30? 3! 1 -1 -67 -80 -14 -13 2h7 300 29/ -2^7 - 1 3 -12 -5tt '80 8 - > 3 -781 — ty H 1 ? n- 0 • K = 12 -12 2 36 -24 4 - 1 1 4i:3 -44 5 112 — '/ 0 -40 0 1 I 7 1 08 - 1 I - 10 3.'" 4 IV 8 -3 03 172 - 10 -9 463 962 51 I 9 09 100 -66 : 03 -66 303 2Ha 20 3 27 I 1^0 207 3oe ??i -26 b -?3C -277 -6 -5 -4 -3 -2 109 -fcV 129 2 1 U 145 -150 64 159 -22 9 -1 39 I 2 -> 4 5 139 7 99 J en 3t.7 ero -216 929 134 -355 -755 2 3 4 5 6 771 4 03 I 19 50ii 98 757 421 107 -471- -86 _2 529 52 7 -I -71 -48 6 f:o4 85o 7 315 339 -1 -oB -6 b K= 0 . K- : 13 7 8 7ti0 2/2 788 -293 8 9 -64 313 -12 -305 K= Oi K- = 10 9 50 I -492 10 276 -2t,& -17 1 25 103 10 21 0 -214 I 1 22:i 196 0 43 0 4 26 - 16 132 134 1 1 153 132 12 320 31 / 1 2 11 0 -68 144 -99 -15 -14 1 00 147 92 - 138 1? 13 4 03 -6L> 401 -30 I 3 14 180 245 - I /t> -236 3 4 112 -71 -125 -4 9 -1 3 -12 225 -oe> -231 34 1 4 15 r t9 -25fc -63 -2 0 -19 -09 3 54 06 -346 — ?0 1 7 <■■ - 1 73 -1 1 -70 122 IC 147 130 -18 -60 -45 -ly -IK -17 -0 7 20 0 360 76 206 -37 / -JO -9 ~C -6/ -o9 10>j 67 -56 - 107 -19 - lo - 17 -67 -CO 192 -30 23 217 - 1 7 - 16 - to 329 132 120 328 :c6 130 - 16 -lb - 1 'i 488 24 1 575 -40 3 25 1 566 -7 -6 -5 -t.9 107 1 66 5 1 136 -1 4o -16 -15 - 14 3J. <. 1 61 3 JO 308 -174 -3C7 -14 - I 3 - 12 324 247 696 -325 -230 fat!3 -13 3»J7 397 -4 -73 - ir.8 - 13 103 109 - 1 1 595 5fc>7 - \2 -1 1 -10 -<» — 6 174 228 34 3 603 -66 -196 -23 3 34 5 eoi 82 -3 H= -15 106 0 t K^ 137 120 14 -12? -12 -1 1 - 10 -9 -8 37 3 120 - 5 1 3^5 1 15 373 147 -23 -370 190 -10 -9 -8 - 7 -6 -51 471 1 11 297 191 — 90 -481 107 362 206 -7 376 -37C -14 1 60 1 1? 6 -7 4 2 4 41 9 — 5 269 -242 -6 -68 -136 -13 20t> 2 06 -6 f.C4 -5bo -4 1 099 -1125 — 5 107 94 -I? -72 -149 -5 700 -731 -3 1222 1037 -4 42 1 400 -1 1 21o -219 -4 407 -471 -2 lirie?. 116 4 -3 -70 1 10 -10 -70 47 -3 73 -4 14 - 1 715 V4 1 -2 AbS -401 -9 171 165 -2 6C0 237 -1 -7 J -75 •■f^ -7 148 -72 133 -74 - 1 e76 102 H-- 1 t r = 4 H= 0, K = 1 1 H= It K = J3 H = 1. K 2 0 1 340 215 297 205 0 1 -70 1 fO -3f - 1 49 0 833 67 1 0 1 1 i3b 15b 1536 ICO 2 3 690 -040 -347 2 -7 J 72 I 13b5 - U OU 2 O09 -546 4 636 608 -20 1 79 16 0 2 070 -4 4 1 3 2C:i -342 5 34 1 3 '4 9 - 19 2'i'i -254 3 2 64 -36 9 4 775 fcC4 6 1 78 177 - 1 C I 7m - 1 90 4 71C -636 C 2 14 26 9 7 I 17 103 - 17 lb'. 156 5 927 699 6 34 1 -343 0 1 44 - 1 09 - 16 HiO -1 72 6 IC64 - I r 2 1 7 4 53 -48J 9 291 3J 7 - 15 It. 6 165 7 I 4 t> V - 1 •. 9 I 8 -59 -100 10 321 324 — 1 A -6b -1 0 8 1 77 148 9 2 03 2tio 1 1 365 - :iStj - 1 3 30 9 -31 1 9 22S 216 10 2 :■ 2 220 12 169 - 19 1 - 1 2 300 363 10 -oO 94 1 1 J77 -153 -2 0 -c8 9 — 1 1 340 3S6 1 1 ?^o -267 12 405 -4C3 - Iv 2oI 258 - 1 C 172 - lOfl 12 409 -404 13 i: 7 147 - 18 -64 5 -9 22 b - 236 1 3 -oa 10? 14 203 225 - J 7 1 42 - 155 -0 lo 1 - 121 14 482 4 90 15 133 95 - J6 230 -214 — 7 lb2 143 15 -69 -6 -19 1 C8 IttO - If- 135 -151 -6 24 7 256 16 145 -1 70 - 18 243 237 -1 '. 089 869 » K 1 bS - 177 -I ^ -09 -39 -17 31 J -31i- -13 ;: 19 223 -4 3db -373 -17 39J -3«0 -1 '.. 1 eil -179 -12 995 -908 -3 -09 90 -16 150 -173 - 15 134 122 -I 1 202 2i>3 207 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 H= 0 1 2 3 4 5 6 7 8 9 10 11 -21 -20 -19 -18 -17 -16 -IS - lA - 13 - 12 -1 1 -10 -9 -6 -7 -6 -5 -4 -3 -2 -1 FO 940 27b -i.4 50b ?. a t. «Jb2 74 S t53 16& 77 1 FC P94 -65 -4 54 -214 icri 7f.t5 -7P7 49 -69 9 1 . K = 0 1 2 3 4 C 6 7 8 9 10 -21 -20 - 19 -18 -17 -16 -15 -14 -13 -12 -1 1 -10 -9 -8 -7 -6 -5 -4 530 ISO 73b 136 1 1 ? -63 -66 22'; 129 34 1 152 l£^0 24C -69 326 122 -65 156 -61 573 1K3 46 4 1C5 747 666 415 337 424 1 191 643 41 I 319 3'5fa 1 . K = 422 438 204 12{. 134 -68 -68 234 1 I 9 -71 -7 1 261 -6B 2?e 1 1 a 25^ 202 274 43 A 25b Ibl 28-;» 57 2 44 2 217 2 1 a o9C 42 3 109 -518 - 174 703 130 -llf. -35 57 24 1 129 -334 -156 169 23 0 42 -326 - 159 6 4 17? -1 7 -562 164 470 171 -750 ■ -691 -379 -3) 9 -372 -I 149 — 549 400 243 361 430 433 -203 - 100 151 79 -5 -217 - 125 87 66 -276 -97 245 98 -238 -21 1 269 436 235 -205 -287 567 442 174 -2C8 -f 52 4 t 5 131 -3 -1 0 1 2 3 4 5 6 7 8 -21 -?:? -to -10 -17 -16 -15 -14 -13 -1 2 -1 1 -10 -9 -8 -7 -6 -5 — 4 -3 -2 -1 H= 0 1 2 3 4 5 6 7 -21 -20 -19 -1 8 -17 -16 -15 -14 -13 -12 -1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 H= 0 1 2 3 4 5 -21 FO 9 3 7C4 -55 1 FC ■ 1C2 ■730 34 K = 552 141 -66 -t.U -68 254 -6 9 237 -73 254 -6 5 152 -64 27 7 432 1 84 507 85 -57 149 -55 797 89 779 97 594 169 -56 550 -59 1 -550 -14 6 6 1 102 19 -255 -14 2 24 - 1 249 -67 -143 2 271 44 ! - 196 -516 -83 67 167 54 -809 57 800 4 1 -604 - 166 87 54 7 0 K- -66 2 54 -70 33 1 102 185 -70 175 172 155 31.18 539 3o3 399 194 236 254 160 310 31 1 758 206 4 6»V 138 31 1 236 173 433 107 1 t r. 490 -69 302 193 -71 21 1 98 14 2oa 71 — 53 J 47 212 6 3 - 1 6 3 -lf.5 160 33 0 334 -356 -385 201 262 23" -14.4 -315 328 770 -186 -51 1 - 1 16 2v3 240 -177 -436 -96 -514 30 302 208 79 -193 87 -20 - 19 - 18 - 1 7 -16 -15 -14 - 13 -12 - 1 1 - 10 -9 -6 -7 -6 -5 -4 -3 -2 -1 0 1 2 3 ■20 ■ 19 -18 -17 - 16 - 15 -14 - 13 - 12 -11 - 10 -9 -8 -7 -6 -5 -4 ^ "2 0 1 -20 - 19 -18 -17 -16 -15 - 1'. -1 3 -12 - 11 -10 -9 -e -7 -6 -5 -4 -3 -2 -1 H= -19 -la -17 FO -67 267 :;71 4 1 6 307 496 3Z:i -C5 1 42 4 56 1 ! 1 4 60 346 602 -63 -65 355 4£ 1 2 9'.' 2 04 164 -70 127 179 -67 135 104 396 169 1 73 £02 3 20 2 39 2 64 i<:£ 224 134 239 2 68 1C6 IVO 2 34 276 -71 1 • X 177 -74 129 2 0 7 -66 -67 122 zco 317 -66 32 2 183 2 '.4 1 3 3 -69 2C5 194 27 1 250 -67 153 -69 FC -J7 -279 •388 4 1 5 299 -50 1 -icy 136 466 -102 -4 30 351 6C4 33 30 4 4f; 2C8 -3C7 10 168 1 02 - 100 -200 -79 141 102 -4 16 - 192 169 529 337 -2o5 -259 216 228 -100 -282 -277 92 177 -242 -258 -79 - 1 1 -156 - 103 152 -199 -96 -40 144 221 -3 05 -<.-7 336 230 - 266 -141 -49 199 179 -280 -2'*8 10 144 50 -16 - 15 -14 -13 - 1 2 -I 1 - 10 -9 -8 -7 -6 -5 -4 -3 -2 h- -17 -16 -15 -14 -1 3 - 12 - 1 1 -10 -9 -8 -7 -6 -5 H= -13 - 1 2 -1 1 H- 5 6 7 8 9 1 0 1 1 12 13 14 15 3 4 5 6 7 a 9 iC 1 I 12 1 3 14 li 16 17 FO 222 -65 216 177 2 58 2 1 0 -67 139 14/ 138 292 206 1 33 -70 109 I K = -68 180 -68 258 177 202 185 -<;9 100 -70 246 179 1 83 I, ^ -74 24 7 -71 -70 20 6 -69 217 187 -68 188 1 19 219 130 2 05 137 -67 282 -66 - ''i 6 -63 - Ob - 66 122 -63 1 69 224 135 1 02 149 -o8 FC -227 -24 21 1 156 -26 b -207 47 149 167 -123 -301 209 121 -15 -14 2 13 72 202 66 -269 -173 207 193 -13 -89 -63 23 7 175 -187 14 93 - 2 7 5 -71 = -14 68 — 194 -49 21 1 185 -15 -169 -133 208 134 -177 - -13 154 -3 -274 10 91 40 -26 - 86 -114 18 1 53 -213 -132 124 1^7 2 2 K= 252 127 ISl 12 256 163 -173 0 1 2 3 4 1 10 -66 315 -66 359 K- -12 93 -53 -3^1 21 361 208 ro FC f o re FO rc ro FC 5 10/ 94 3 -60 -63 1 / 95 i>l -8 -6 5 64 6 3H0 -367 4 22 J -26 0 18 1 ! 4 -64 -7 -62 15 7 1 79 -155 '., 3/5 - J49 19 12'- - 104 -6 377 -356 6 21 r. 2?fl 6 -58 -7 20 -C6 2 9 -5 652 -655 9 34 7 335 7 34 6 343 -10 174 -157 -4 eo -70 10 -Ot. 61 n 215 -229 -9 203 -1/1 -J 34 8 3/5 1 1 '.Oo - r'90 9 <;4 5 - 4 5 5 _ W 190 lf.3 -2 364 363 I?. 11>S - i' 6 3 10 224 20/ -7 308 3:^5 -1 145 146 13 202 217 I i 305 297 -6 31 0 ~:".'i. 14 Itb lA7 -202 -3 421 39U 0 1 574 14 65 17 -OO -•; 0 IS -66 18 "~ «' 59« 590 1 493 425 10 30 'J 2>J6 16 3V7 402 - 1 186 -182 2 743 -923 19 - 67 0 17 -63 -3/ 3 244 -312 - 1 1 / 7 19? 18 1 19 -10 j H- 1 t K = -6 4 1010 1004 19 -66 -9 0 5 -54 92 t- 1, K^ = -11 ?0 I 16 129 0 712 06 4 6 11:^6 -1002 -7 24 0 2 38 1 470 4 10 7 407 -409 0 193 -170 -6 -70 -9a 2 4 06 -39 0 6 24 6 -102 1 -6 3 -29 -5 1 74 -1 S8 3 428 -398 9 131 124 2 27 3 276 -4 217 2C4 4 474 455 10 69 1 685 3 1 1 0 -95 -3 £'j4 2t5 5 4 29 47 1 1 1 3t>3 -3/4 « 358 -3?>4 -2 -t,7 8 3 6 6/4 -680 12 4 4o -4S? 5 -66 -68 - 1 139 -153 7 r. / s -2'i3 13 321 338 6 21 0 20P 8 -50 36 14 191 105 7 190 159 H= 1 . K- = -8 9 305 295 15 -64 -42 8 -64 ?5 10 210 21 1 16 407 -422 9 2b6 -203 0 320 340 1 1 38 5 -390 1 7 1 82 -203 10 99 -37 1 568 -572 12 260 -296 18 2 06 238 11 55 3 n3S 2 2t.6 -246 Ic 105 ice 19 170 175 12 2e2 231 3 £4 fc3 14 2ty 3^C -14 -68 62 13 It 7 - IR2 4 619 577 15 2?6 -235 -1 3 -b'.) 33 14 9 6 124 5 34 8 338 1 6 -66 -59 -1 2 434 -4 4 7 15 -66 - 1,?6 6 266 -27L 17 121 143 -1 1 1 33 - 141 16 147 J 4 6 7 4/9 -487 1 d 293 28/ -10 415 412 1/ 21 I 192 8 2 CI 286 l) 224 205 -9 -62 -31 lU 252 -i^60 9 3 '.5 3/8 20 -o8 -35 -0 36 0 -376 19 -6 7 -1 3 10 -58 -0? - 12 203 -2^0 -V -56 37 -3 274 271 I I 328 -33:) - 1 I 127 - 1 17 -6 -54 74 -2 -66 48 12 1/2 -174 - 10 21 J 207 -5 8 06 797 -1 -64 -24 13 1 09 60 -9 -64 24 -4 316 303 14 271 266 -8 334 -318 -3 821 -795 i= 1. K :^ -10 15 - 1. 4 -47 -7 176 -lt3 -2 4 2 2 -443 16 215 -22.7 -6 188 1 74 - 1 981 1123 0 3tl0 370 1 7 -64 -1C6 -5 aCb 41 4 1 362 -352 18 J 3 0 118 • — '» 2^8 272 H= 1. K = -3 2 357 -36? 19 Kh 160 - 3 ?ei -3t3 3 -64 12 20 190 -190 — 2 42o -4 14 0 2217 • - 1990 A 303 20 e -9 I 38 106 -1 592 617 1 854 563 5 IbO 197 -a li.^ - 18? 2 1/4 4 1?47 6 571 -578 -7 2fH -275 H = 1 . K: = -5 3 283 163 7 59 3 -COl -6 I 75 I 80 4 820 -7/8 8 320 31 2 -5 25 i 275 0 £45 -£87 b 26/ -253 9 431 4?4 -4 -66 -40 1 1 124 ■ -1087 6 15t. -123 10 140 - 10b -3 -63 0 2 1322 120 0 7 265 250 11 6S.3 -714 -2 39 1 -3 J6 3 209 -23:i 8 -53 -30 12 -65 -46 -1 lo3 IL I A 944 -939 9 554 -55 J 13 519 5?7 5 377 -320 10 2Q4 -2/6 14 30 4 34 7 !■' = 1 . K.= = -7 b 1 12 -79 1 1 3'=.2 3^4 IS 207 - 194 7 -54 1 19 12 366 390 16 589 -013 0 14o - 166 6 1^,0 - 161 13 170 -208 17 -63 -15 1 392 39 1 9 834 -610 14 288 -280 18 136 109 2 92 -66 10 361 -3=0 15 27i -299 19 -66 16 3 140 130 1 1 £51 f 7C 16 325 324 20 177 - 164 4 626 542 12 tt2 574 1 7 -66 53 -6 1 1 0 I 04 5 637 -556 13 158 - 139 1 3 248 -256 -5 29ft 266 6 -53 -1 14 -61 31 - I 5 -69 -5 -4 -66 -72 7 393 41 7 15 21 1 195 -14 239 -237 -3 2ce -209 8 -53 37 16 3 5 4 355 -1 3 -64 3 4 » n 1 46 - 15 = 9 95 37 17 -fc3 -5 -1 2 355 355 -1 55 6 559 10 -55 -47 18 326 -313 - 1 1 -63 -47 1 1 -57 -90 19 235 .-233 - 10 218 -230 t= 1 . K = : -9 ! ? 127 141 - 13 -e9 43 -9 1 15 -106 13 105 -84 -12 274 266 -8 254 244 0 470 -453 14 41-,^ -44 J - I 1 -to -19 - 7 553 5fj5 1 -62 24 t 5 1 JtJ 176 - 10 3i:3 -3til -6 361 29 0 2 -60 54 16 12o 130 -V -L7 -lOO -5 538 -532 209 FO FC -A -54 -77 -3 b9V ess -2 479 -CO? -1 I2:i7 -£70 H= K: -2 0 923 IC?! 1 DO 2 ?3« ? 689 -fi2e 3 292 -334 4 793 C?3 5 6S.d 75 J 6 69 9 -^4 0 7 7->.5 -f93 e 190 151 9 i:.fit> f:68 10 20 1 PC 7 11 <.99 -701 1? 29 7 -?'J.9 13 106 -1?? 14 2 0 2 ?C *? l.£. 2b4 ?4e IC -66 -1 17 -6 5 -A9 1 e - 7 1 12 0 - 16 165 -13'^ -15 134 Iti<. -14 231 250 -13 -613 7 - 1 2 131 - i I 4 -11 -62 V2 -10 56 1 56.4 -9 16« I£0 -a 475 -479 -7 914 -93<: -6 119 129 -5 143.'^ 13GH -4 201 -20* -3 1 120 - I i:ji -2 lOt.3 P-S'l -1 142 72<^ 1. K= -1 0 794 -:'7.S 1 1464 lli;5 2 1)22 ?eft 3 6 7 -ire 4 911 61 1 5 97 0 -9C4 6 1006 ^7a 7 1S5U l«i5 6 7 6 e^ 9 54 0 -r-eo 10 -56 -ei 11 300 3?fi 12 20 0 2i»3 13 lie. - 1 -'• 7 14 460 -4t-e 15 -69 JO 16 24 •; 23 0 17 14 3 I'^C: -17 27 5 ?- A - 1 6 15 9 It? -15 2 74 -?'.>', - 1 4 117 - I .: '"i -13 22 1 P.l-c -12 -f C 22 -11 162 -170 -10 2a3 -270 -9 34 0 -3':.-3 -3 121 - 1 24 7 6 B6 2 -632 7 S99 -57 3 a 2e6 289 9 195 184 10 -63 69 11 2i<6 -273 12 269 -266 13 S61 581 l.'» 207 314 15 -uG -bS -19 -j9 56 - I 0 -ft / 2 9 -17 193 -204 - 1 6 -<6& 9 -15 63 0 619 -14 2 94 2«0 -13 -&1 25 -1? 212 "192 -II 65 75 - J 0 Se 3 9 11 -9 aV-3 B4 7 -8 93S -94 3 -7 5<>2 -569 -6 3X0 319. -5 075 -766 -4 lO". 135 -3 l^^O -61.'i -2 2t2 -558 - 1 1120 909 2« K= 1 0 GO 126 1 lieO 9 69 2 -5Ii 27 3 *i»7 -3J2 4 734 -781 5 J!63 -406 6 1C2^^ 1029 7 ^®3 236 0 4 0/ - 4 1 2 9 27.6 -267 10 ISJ -134 11 zap. Zhl 12 191 164 13 33sf -30 6 14 l-£9 -109 -1? tifo -1S9 - 1 3 I "J* - 1 ' : -17 ^37 440 -16 167 176 -15 377 -37 0 -14 2J>4- -255 -13 -S9 -i)5 -12 Jsiit 375 -11 -5.3. 7 7 -10 Si3 -S5« -9 3-59 -364 -8 *5.2 >i31 -7 aff'i -6-iO -6 S3i 93 -5 'J'il -04/ -4 2112-* -1952 -3 ?51 595 -2 1 IV^- 834 -.1 lT46 2 2" 5 -21 2 3 24 1 -2-: 5 4 332 3 06 5 6C7 593 6 2 '12 - 2-;'l 7 254 -23 0 }1 .'. ': 4 34 1 9 3';U :\SVi 10 .'35 234 1 1 2 59 -264 1 2 J Z\: -107 13 -69 123 14 -73 124 20 -60 63 19 4 12 4 03 1 8 130 13f3 17 446 -4 55 I 6 "64 ••16 15 2 20 2C0 J 4 3? / 381 13 -57 -38 12 :-t;i -395 11 c,. 2 -66 10 4 26 45 2 -9 -h5 25 -6 16S 1 16 -7 4 7.3 -493 -6 7Cb 601 -5 1305 I2yi -4 3.74 45 1 -3 102 132 -2 7C1 5 L> 9 - 1 94 120 ?: K- 0 7 00 -li U I -55 -26 2 445 4^6 3 44 0 424 4 IV V -226 5 -£;i -65 6 3t2 .3 7'-. 7 173 156 a 105 - 1 3 4 9 3 63 -358 ic 21 7 -2-^5 1 1 2 '-.2 301 ! 2 -68 4 2 ^0 103 -1 1 0 19 490 - 4 i C 18 10/ -9'.' 17 :;ot. 31 1 16 -63 6 4 15 229 -219 14 £35 -5 05 13 224 - 2 • C 12 20 6 30 7 1 1 202 272 10 223 - 1 i* 9 -9 350 -3V0 -a SO 72 -7 £41 7«S -6 -54 -102 -5 CC4 - V4 9 -4 rci 246 -3 510 624 _p 397 - 4 0 9 -1 1343 -124cJ 1- 2. K: ~ 4 0 416 405 1 79 -60 2 755 -736 3 130 137 4 4 21 4 0 B 5 29U 290 6 266 260 7 316 -319 8 -67 -4 9 496 4G0 10 -Hi - 4 8 11 160 -173 -2 1 243 -231 •20 156 164 -19 4 G 4 !4 -18 "64 -13 -17 2 18 -206 -16 1 JU - I 53 -15 21 » lei •14 5V5 585 -13 3 13 -i\Q -12 3 18 -34 8 •11 146 165 -10 73 -16 -9 568 603' -d -!:;4 -7 8 -7 1205 -1232 - 6 36 3 317 -5 60 1 66C -4 1 0 53 - 1 Coo -3 1311 -1220 -2 1236 -11/5 -1 -57 13 H- K-- 0 17 1 -173 1 -57 2 2 7 24 72 0 3 2Ca 30 1 4 294 -312 5 257 -257 6 -68 -79 7 280 269 8 lie 15 9 30y -316 10 -72 -64 "2 1 icri 19o -20 188 -186 -19 4 48 -456 -18 -63 2 -17 151 111 - 16 243 27 0 -15 -60 -15 -14 293 -301 - 1 3 - 67 67 -12 785 801 -1 1 -53 19 -10 315 -303 -9 19 1 -196 -8 179 198 -7 4C.7 431 -6 108 -148 -5 12 11 -1229 -4 -5S -125 -3 1007 1030 "2 52 0 516 -1 77 80 H= . 2 . K= 6 0 617 600 1 164 177 2 492 -503 3 94 - 1C6 4 -68 60 5 2£7 284 e - 6 8 71 7 2'v8 -30 3 8 -7 1 -128 210 9 -no -19 - IH - 1/ -It- -1 b -13 -li; - 1 J - 10 -9 -0 -7 -6 -5 -4 -3 -2 -1 H- 0 1 2 3 4 5 6 7 -? 1 -20 -19 -16 - 17 -16 - 15 -lA - 1 3 - I?. -1 I -10 -9 -8 -7 -6 -5 -4 -3 -?. - 1 K= 0 1 2 3 4 5 -?l -i'O -19 -1 6 - 17 - 16 - li> -12 2f.H by. 129 AJb 2i;3 bC-.5 231 yu7 2ol 136 161 416 2^.9 r c 1<3P 19P leo 14 1 ■ I'fU ■3•J^ 2K4 617 1 14 -437 ?1 0 ."4 5 664 ■?'» 3 •V04 -23C' e.?6 -10 1 -"".JO -2? 4 K = b'. 4 -6 8 16i5 121 152 1 09 -71 26b 140 -66 -6 4 -Oi> £';3 339 34 9 44b -60 440 230 406 222 89 9 30 b 1 3b -b7 344 29 7 44 1 - 64 -530 -•50 182 10 7 - 142 -1H9 89 259 125 -31 93 -B5 301 36 2 -366 -470 31 439 236 -421 -20? f.7 1 :o6 -146 -31 -323 206 473 37 K= 207 1?3 126 99 lb4 250 -6/ 1 '>( -t 'j -L.'i 47 7 237 -65 1 t4 100 30t. 3*1 4r> J 131 2? 9 343 21 8 'J6 - 138 -34 139 239 -63 91 27 48 -4f 3 -?4? 4 1 160 130 -315 -34 P 4'i 7 174 -320 -6 -5 -4 - 3 -? -1 H- 0 1 2 3 4 -21 -:-'0 -19 -in -17 -16 - 1 5 -14 - 1 3 -\? -1 I -10 -9 -8 -7 — 6 -5 -4 -3 -2 -1 M- 0 I ? -21 -20 -19 -1 P. - 17 - 16 -lb -14 -13 -12 -1 1 - 10 -9 -8 -7 -6 -S - 4 -3 -? -1 H = -20 -19 -\a -I 7 -16 -1 5 -I 4 -13 -12 -1 X -10 -9 -8 FO 361 100 b^2 334 4t>J 1 3b r c -34U 127 5V0 -Jo? -4 62 130 K = 278 -69 131 1 04 lOB -60 106 109 -Ol i:'b 3V4 -06 -Ob 324 195 4 7b 1 3r 44 4 332 312 4 16 104 390 144 453 -272 37 1 03 1 13 -U,7 -3'J -94 - 1 t'. 4 - bo 51b -101 -361 -74 1 7 333 I'OO -4C2 -152 445 3.-^2 308 -421 --31 3d r> - 15? -Ai;) J K= 1 0 20? - 71 120 -08 -o7 2o7 1 92 292 102 22e 3o2 99 2 72 24b 257 26d 1 83 26o 120 22b 1 C6 -oy 3 7* -69 K= -69 393 130 - 6 •:> 103 99 237 -L.6 449 -06 173 -oO 134 191 53 -123 -30 -59 26/ 177 -29 b - 1 0 I 2s2 377 58 -2ol -24 1 Za2 2bl -159 -270 - 100 2^'6 96 -60 -3oa 1 1 1 -5 -39 3 - 144 40 I 17 -103 -23 472 30 -214 26 144 -7 -6 -5 — c. -3 -2 -1 H= - 18 - 1 7 - 16 -1 b -14 - 13 - 12 -1 1 -1 0 -9 -e -7 "6 -5 -4 H = - 16 -l-» - 13 - 12 -I ) -10 -9 -6 H = 7 e 9 10 1 1 12 13 14 lb H = 0 1 2 3 4 c e 7 6 9 1 0 1 1 1.' 1 3 14 I 5 I'j 17 FO ?01 -6H 4 32 1C2 2?0 104 - 71 — f ■•; 1 i! -) -6i. 229 -69 ?. 04 1 4 1 — ^^| '* 1 t .) - (- 'J 2 £3 -7? 3f 2 -72 K- FC -42 -442 -103 206 12b -O !• 1 2 67 -93 - 1C9 42 2^a 103 - 191 -163 ir> 1 ov f;b - 262 Ul 3J3 93 1 3 ro rc 1 4 3 1 ?■: 1 '"•! .. t C) K.3 -71 - rrt ~ !d K 2 ; 9 - /o 220 -67 196 225 -69 34 7 -67 2 by -67 193 lbf< -66 -lf>6 4 4 18t> 22 -64 -94 -6 - -14 237 -bO -^03 b 194 220 -4 b -J3d -103 251 -2 - 166 H= -60 1 1 1 1 t 2 143 ISb -66 1 39 147 123 169 -t.4 31 1 -6b 160 -6b -70 197 -6 7 133 Ibo K= -13 -25 9f. 1 t,b - 12o -I9f. -2 9 146 162 - 1 1 3 -201 -3t> 30b - 166 64 129 197 16 = -12 152 -171 2 207 -20 3 3 26b 2b9 4 '300 .""■>« 5 210 - i^a 0 382. -3';b 7 98 -7 1 11 200 210 9 2b9 26 0 10 247 -2 b 3 1 1 275 -2c J b 1 13 -114 6 4b3 -4 99 7 310 -3C9 e 94 -110 9 26b 289 10 260 -ZOZ 1 1 245 -.^4H 12 2lb 2iii 13 424 427 14 304 295 15 3'-y3 -39 b 16 239 -25 3 17 130 1 1 9 16 309 3C6 19 -6/ -30 -6 396 3d6 -5 202 213 -4 2 2o7 -210 -325 24 26 0 0 2. K = 104 : -6 24 2 3 4 5 94 7 225 753 135 - 03 8 -216 726 1 14 5 6 7 S 1 1 8 99 677 3S.4 -96 -101 -654 4 04 _7 13 6 1 1 fl 1 1029 - -1015 6 2 <^j 0 -294 9 428 4 05 — 6 I '; 1 - 1 7£ 2 68J -77 0 7 5 36 -536 10 1 12 - 160 - 0 —4 9 9 -6& - 120 15 3 4 100 122 -54 -124 3 9 0£i9 565 -646 590 1 I 12 200 2^6 -198 -298 —3 120 161 5 96 -131 IC 1 r: b IC; 13 191 1 78 -2 — 1 314 496 333 -496 6 7 5S6 836 - 07 0 - 1- 7 4 1 i 12 6 -5 .3 -59 -^43 -4 7 14 15 618 -67 624 10 e 135 1 7 7 13 -61 -16 16 264 -201 1=: 2 . K = = -8 9 761 7?0 14 -63 16 17 -69 - 16 10 -54 15 1 5 -66 • 99 -17 203 -213 0 645 64 4 11 447 - 4 3 L 16 -o6 ~r.'( -16 230 -2:1 I -t;6 -26 12 2.-. 1 -Zf -7 -6 -h -< -3 1 - 2 -1 748 ( (id bl 9 36 7 108 9/6 ?b7 I i?e '•.0 3 t'OO - -73 6 -709 4 8.? 33=i -64 -fc>)3 316 1530 -25 123 3 -6 -5 1 -4 -3 -2 -I n = 0 1 3H4 K2'> - 93 7 9 03 133 172 3. K. A7f5 227 -305 • 1 V> 04 bW 970 12H -262 2 509 - 2 3 5 II- 0 1 2 -2a 6 6 7 -21 -20 -19 - 18 - 17 - 16 -1 5 -1 4 -13 X 18 ItiO 100 2 86 -64 452 154 4 00 2 68 173 -157 -330 - 1 7 J 90 2 fib Bl -4b2 -131 420 276 - 1 66 H = 3 • K = 0 2 12 16 - -1233 0 1 59 1 /5 - 12 142 -1 53 3 450 -'.Ol 9 26 4 ,' '♦ M - 1 1 1 t>a - 1 58 0 1 2 3 4 5 131 3^4 — t, 4 -6 4 ti''i9 6^2 10 1^9 -^/O -1 0 ocf^ 69 1 -294 5 6 20 2 265 20 3 -264 -2 1 - 20 160 2^0 -1/8 2." 6 -9 -8 5 2o 72 7 b02 -766 100 21 0 63 I -71 ?C"6 62 7 7 8 9 126 -6 3 41 4 -97 402 -19 "18 - 17 -66 141 125 'j3 -14 1 -130 -7 -6 - 3 80 7 212 570 -61 I 226 5<:«6 I 9 f) 04 'i -55 4 1 0 10a 113 - 16 182 - J V4 -4 1 94 7 -56 -90 11 3oV -36o -15 273 29 0 -3 5 7 1 — o 9 e ■9 3cj0 -63 36 6 6C 12 -20 2C9 -71 -226 129 -14 - 13 364 361 3/7 -354 -2 -1 26 8 370 -2V9. 357 10 1 1 1 '.' 6 20^ - 19 3;:'-' 303 - 12 4?t^ - 4 1 5 = 7 2^3 -31 C -le 127 -106 - 1 1 226 223 h= 3. !'-• 12 13 I'l -19 -18 -17 -16 -I'o -14 -13 — 1 ? -6 6 239 133 2'j? -o7 357 26 2 t>07 -63 -60 2b(' -1 8 23 9 KB 2' •! 56 -36C 26 3 4^3 51 1 C4 -17 -16 -15 -14 -13 -12 -1 1 -1 0 -9 -n -7 29- 141 159 249 9^ lOoo ■ -5 3 001 92 64 'f 84 1 -273 -13f lO-i 2 "J 4 -86 - 1055 1 1 771 106 -6 54- -71 1 -10 -9 ~8 -7 -6 — 5 --'; -2 - 1 — *^ 2 26) 3 70 4l!l -56 73 264 J23 2 4 1 329 30 27 1 -:y>y -Lol 145 125 264 -372 -230 34 1 0 1 2 3 4 5 e -21 -20 -19 307 -O'i 225 -7 1 196 213 2C3 -68 1 10 i-:v. -380 22 21 I 1 16 -19 1 -215 194 1 5 0 -1 J4 -1V4 - 1 1 1 r. ti -201 -6 479 46 3 H- 3 . K- 5 - 1 0 1 04 - 1 1 6 -10 -9 — e 670 402 ^62 72 0 -3'S7 -c?0 -5 -4 -3 138 158 9 'J 1 210 6 -854 0 1 tl5 136 -4C-.S 1 17 - 1 / -16 - 1 5 5b/ 129 59 0 ^M 4 1 16 -607 — 7 ^.^i t> - 336 -2 942 -935 2 3 79 ■Ji^?. - 14 224 -222 -6 -5 -4 -3 - 2 776 171 1 604 1 724 1 1 5 -715 - 17 9 96 - 14 210 -2) 9 H = 3» »' 6 7 31 3 -59 303 7 11 -21 194 206 leb 184 - 13 -12 <37 'i07 63 9 42 7 0 100 119 8 9 13^ 22 1 - 123 - 2 1 5 -20 -19 1 I 7 233 - 1 6 2 -22 7 -1 1 -1 iv 145 i25 -157 -133 1 2 -7 0 23^ 6'. -21 0 1 0 1 57 - 17? -1 « I >3* 1 7 H -9 361 -394 3 1 79 - 189 1 1 458 45^ -17 3 9-* 269 -ft 326 323 4 228 2 2 6 12 13 21 3 I 31 20P - 135 - 16 -15 26 7 3o -251 -7 -6 101 1 5t.2 1 C2 1 -57 1 -2 1 -20 -67 -66 —69 44 232 -20 1 5t< - 155 - 14 319 -304 — c 567 - 5 1 5 - 19 230 - 19 35 1 - 3 3 6 -13 246 267 -4 610 634 -16 1 1 0 1 1 3 - 1 8 -6 5 -19 -1 2 1 0 /'5 I 02 7 -3 £27 i,50 - 1 7 24 2 - ? 5 2 - 17 31 4 307 - 1 1 1 ' . 5 ie3 -2 97 13 0 -16 • 99 - 1 O'i -16 -15 -65 2V4 -1 1 -274 -10 -9 -51 2 >2 54 23 5 -1 305 -29 8 - I 5 -14 1 I'.i -tb 1 C6 -1 O O J -1'. -13 4? 1 -56 -••.2 5 -29 -8 -7 7sl4 95 757 133 H = 3. K - 6 - 1 3 - 12 2 2t> 413 2Z-i -392 1 1 427 92 -63 - 1< 3 - 12 455 46 1 -6 477 -412 0 341 351 - 1 1 -63 - 1 I 190 - 21 1 -5 57/ -4 79 I 190 -204 -1 0 4 25 -10 -9 -e 539 559 -py? 531 56? -4 -3 -2 7oJ 4 i 2 3 ■ -■ 0 - Vi t. -4C9 377 2 3 4 191 134 290 -2 15 2 72 -0 -8 "7 -64 1 59 -7 092 eB9 -1 5','-. -602 5 260 290 -6 -66 15 213 FO FC FO FC FO FC FO FC -5 562 57 3 17 159 140 15 230 24 9 -4 -6 P. 52 -10 137 97 -3 -69 _<;/, 16 r-6A 59 -3 6 03 -51 1 -1 7 1 80 -198 — 1 ice 127 1? 2 07 -2c.2 — £ i;^8 125 -16 2 85 -2 83 - 1 200 222 13 115 -135 - 1 -70 100 -15 -69 43 -9 -68 60 -14 287 28'i H- 3. K- - -1 1 -8 -67 37 H= 3. K.= 9 -13 -70 -4 6 ■-7 -66 1 -12 234 -23 5 0 1 12 -139 -6 164 -16 1 0 264 -235 -1 1 137 - 1 46 1 3 34 2C.3 -5 334 -334 1 -7C 0 -10 1 67 181 2 176 199 -4 1 19 ICfi 2 143 17C -9 165 1 76 3 4 0') - 410 -3 191 1 77 -21 -(yf 63 -8 -72 -98 4 171 -163 -2 -6 4 -4 6 -?0 1 I I 133 ~7 213 -210 c 160 165 - 1 3 34 -330 -1 9 -t (. -7 3 -6 104 65 6 lt6 162 -10 — o^ -3 5 7 1 19 71 H-- 3. K= := -0 -i 7 160 157 H = 3. K- • -15 0 2 ;. 0 -232 -16 2'. b -?SR 9 315 -30 0 0 287 -209 -lb 160 -150 8 -70 -74 10 5C7 5C1 1 51 I -54-2 -14 24 7 23 5 9 1 08 1 16 1 I 2^9 303 2 218 -228 -13 -6S 24 10 106 100 1 (■ 5.rd -53o 3 -54 87 -12 34 3 339 11 130 152 J3 1 15 - 1 3 4 4 388 394 -11 -67 2 1 ■•. -t4 4 5 91 -0 7 -10 194 -206 K= 3, K- : -M 15 122 123 6 84 0 -824 -S» 175 162 16 9..> 50 7 2 72 -•29 5 -0 2:i2 233 3 122 1 1 'J 17 -57 -97 G li.-J 173 -7 -6 8 86 4 192 160 18 28t -26 4 9 228 24 6 -6 -68 -69 5 123 -9 9 -5 - 7 C -54 10 — 5V 1 -5 -70 -13Q 6 180 -108 -4 2 8.S 202 11 5 91 -5v5 -4 133 145 7 -06 -3 ' -3 10! 11 1 12 2 55 -24 0 -3 -69 74 8 106 1 1 0 -2 -67 -65 13 515 52 0 -? -70 -66 9 128 l?-! -1 -64 -17 14 -65 -02 -1 2ti3 -276 10 1 Iti -132 15 106 -99 11 263 -2t 3 K--- J . K- = -:o 16 2 57 -2'i5 H= 3. K: 10 12 -69 93 17 -66 -?. 13 220 216 0 -66 -L7 18 2 45 2o8 0 1 1 3 125 14 -66 -5t 1 6>J':, - V C \> -1 1 -69 7 9 -20 ICl -73 15 143 -129 2 -63 64 -10 132 3 19 -IV 204 21 0 3 17/ la'y -•y — 69 - 1«- ; - 18 -66 91 H= 3, K= - -13 4 -61 6'i -6 430 —44 2 -17 166 -177 5 1 15 -no -7 -68 68 - 16 1 1 b -107 0 117 -00 6 38 5 -382 - o 4C.1 AC>7 -15 -65 -1 3 1 -69 99 7 3C5 -3e5 -5 137 134 -14 -66 36 ? 123 124 0 £17 4 92 -4 -63 -62 -13 108 80 3 271 -2^ 1 o 217 133 -3 138 -111 -12 34 8 -352 4 1<54 -196 10 338 -34 7 . -2 -61 49 -1 I -69 1 5 -64 6 6 1 1 -64 -4 - 1 196 190 -10 263 251 6 324 315 12 2 13 200 -9 -68 32 7 -64 26 13 4C5 427 1-1= 3. K: = -7 -a -67 -17 8 216 -205 14 -t65 51 -7 I 15 -93 9 263 -2/2 15 24 3 -235 0 112 -1 18 -6 -68 -40 10 136 140 16 127 -125 1 30 6 314 -5 263 26 1 11 141 142 17 193 194 2 6 95 642 -4 £1 7 223 12 122 -106 18 203 204 3 -52 -37 -3 376 -379 13 107 -120 -7 -70 50 4 6 33 -624 -2 I 72 - 175 14 -66 - 16 -6 -66 S3 5 190 187 -1 -74 125 15 306 2'=; 5 -5 -67 -77 6 910 908 16 161 159 -4 I'.l -141 7 357 -326 H= 3. K: = 1 1 -1 -70 -99 _ -3 -66 28 a 485 -5C4 — 2 263 3CC 9 479 -462 -19 1 46 - 153 h= 3. K- = -12 -1 378 3^5 10 287 -293 -18 140 -126 1 1 364 353 -17 -69 4 5 0 164 177 H-- 3. K = -9 I 2 -62 -60 -16 196 212 1 190 -203 13 333 -323 - 15 12.. 1 12 2 120 -104 0 329 34 3 14 -63 -35 - 14 U- 1 - 144 3 262 254 1 tT9 616 15 221 223 - 1 3 166 216 4 168 150 2 -53 64 16 326 318 - 12 2"0 250 5 167 - 173 3 1^3 - ! 3 H 17 122 ei -11 149 -i2e 6 31 I -312 4 203 -ISJ 18 2 7C -270 -:o 14S) - 1 ' 3 7 94 -100 5 102 7o - 12 .212 216 -9 -66 -c& 8 26 2 26 9 6 £13 546 -1 1 -67 4 -6 1 I ■■. 5 06 9 218 212 7 194 183 --1 0 320 -333 -7 196 2t e 10 213 -200 8 403 -1t;3 -9 1 17 138 -C -70 -<;? 1 1 292 -286 9 -cl -80 -8 342 346 -b 293 -230 12 149 -131 10 1 1 1 12y -7 120 - 127 -4 -71 42 13 251 24 4 1 1 t?2 5! 1 -e 176 - 168 -3 130 136 14 2 95 318 12 2t9 2u6 -5 328 -331 15 152 - 159 13 5C5 -^23 -1 -59 -1 H= 3, K 12 16 17 = -160 1". -64 -16 -3 497 522 214 HO FC -? ?S1 S'^O -X 080 -t30 ^ 3f K: = -6 0 394 *P? 1 i:^l _ p V, f 2 bl J _ i. ..T p 3 ^/l ^! 5 4 760 74 1 S \--.^ 170 6 90 0 -i'73 7 3:^5 ?E2 e 8o9 »Hl? 9 1V2 ?f! 3 10 -t.7 eo 1 1 3..,? -371 12 l''>3 - J A6 13 70 n i-<.vO 1 A .'4 V O t.r;i^ 10 J I «i - 3 J u lo ?02 -?!1 17 -0 7 J(.9 18 j;70 2*8 13 -7 i -!'.-l9 \Z 2? 7 -2?^ 1 1 -U 29 9 30 2 -A 173 Ibl -3 7r6 - ??•(& -? -C-A -13? -1 A79 *S5 0 1 2 3 4 5 6 7 9 10 1 1 12 13 14 15 16 17 16 - 14 -13 -12 - 1 I - 10 -9 -e -7 -6 -5 -4 -3 -2 -1 M= 0 1 K- 4 1 6 1 01 i) 1 194 CCti 6o5 226 331 -52 34f. C4 7 -bo b4 7 -02 393 «40 2r>7 227 -67 302 1C7 23 1 160 2->0 »' _* *3 ILC 1'' 3 3.^6 40v G2S ■ /A 3 •o3 1 3t14 61 9 3, Y,- 73 1 304 • -4IC.C 1 C'^f: -SI e -7'5E- 229 3.? 3 - 34,f, -637 •537 -S3 -♦as ye? .?*7 -?0 -?;.*7 - 150 ?7'fi l'>-1 -r*T -3t 3 - J A. 2 leo 37 7 -4X3 -01 i 7>-? 6>3 4r"7 -4 eo- ■4C3 2 3 4 6 7 9 I 0 1 1 1 2 1 3 1 4 1 5 16 17 -1 6 - 1 ':> -13 -12 -1 I -10 -9 -R -7 -6 -5 -4 -3 -2 - 1 FO S49 2 0.i 101 / 131 -OS 12ob 914 -0 7 2ao -ii?. 49 2 309 -Ob 331 'y9 -70 207 -07 33U 1 '-.'» 270 o:<4 2'jO 64 2 Soo 4 19 S16 331 746 2 93 2/0 H- 0 1 2 3 4 6 7 e 9 10 1 1 12 13 14 15 16 17 -17 -1 0 -ir, -14 -13 -12 -1 1 -1 0 -9 -8 -7 -6 -5 -■4 -3 -2 -I PC -555 226 930 127 2 2 -1 2i'3 26 <.9rt -2 -252 23 52 i 2U7 -75 -32 2 e9 - C/'j 196 9 7 -3)4 - 109 02 7 247 -6 30 - t*2 419 4 96 -4 06 -093 -loa 307 K- -3 4 60 91 1 1 4 a 9G1 290 t IH b9 6^^5 609 352 54 7 -OO 2CO 210 3o2 -6 a 312 102 13 1 -t.7 34 0 I3t> 29? lOO 4;„0 60 3 I JH 3i^7 239 467 903 41o ';o 511 104/ -469 7 09 1 vv -94 6 - 269 - 1 35 -66 60 0 -6 30 -364 56 7 -77 203 -20 9 -30K 9 5 2 94 - 147 1 C4 70 -34 1 - 14 V 2 65 1 1 1 -4t>6 -6C1 -122 335 21 1 -438 -909 224 82 -2 14 H- K= -2 1279 913 -0-i 4 (.. Cj 3vt.> 1 103 «02 9 4 03 419 S O 7 B 9 1 0 1 I 12 13 14 10 !<■ -17 - 16 - 1 5 - 14 - 1 3 - 12 -1 1 - 10 -9 -f. -7 " o -O -4 — 5 -2 - 1 H- 0 I 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 - 18 --17 -1 6 - 15 -1 4 -13 - 12 - 1 1 -10 -9 -6 -7 -C _ c -4 -3 -2 -I H- 0 I i' 3 4 b 6 7 8 rn 2 57 3 •13 6 4 1 032 193 330 9»- ;oo 350 -C9 ;r 1 a 194 J 09 -67 :'4». 1 9^ l',5 -60 426 1 45 232 216 4 0L' 146 1 (; 1 0 150 104 7 MM ?Z3 r-c 245 -383 - j.':9 627 17 t -JJO -09 -213 309 -96 -230 -17;- -209 -66 356 198 -143 61 416 162 23 7 -206 -4 1 J 1 1 7 937 -434 -1304 -712 158 K= 496 234 149 923 134 151 6) 0 3'>0 £58 216 -62 1 1 3 469 C-22 143 2 4 5 -68 313 -64 1 ei -66 312 I 10 135 278 -t-2 1 76 4 02 3 79 -1.4 1890 303 7 79 1 01 4 . K- 265 4f.9 424 254 10 30 189 31 2 143 96 -1 471 - 160 157 -iJOl 120 10/ 602 -56o -222 1 1 I 4 -4 94 -310 1 66 25 1 4 296 38 - 1 V4 80 304 1C7 90 -2rtl -24 169 426 -389 -7 1267 62 -475 -178 266 -4Ct> -464 .210 1 CIO -17H -334 - 173 133 9 10 1 1 12 1 3 -• 19 - 18 -I 7 - 16 -15 -14 -13 -12 -J 1 -10 -9 -e -7 -6 -b -4 -3 -2 - 1 H- 0 1 2 3 4 0 6 7 8 9 \-j 1 1 1 2 -?0 - 19 -16 - 1 7 - 16 -10 -14 - 13 - 12 -1 1 -10 -9 -8 -7 -e -5 — '*. -J _2 -T H= 0 1 2 3 4 5 6 7 8 9 10 1 1 -i I -20 - 19 PO 318 rOO 2<9 1 19 201 lo3 200 201 2 73 I 73 -61 246 097 I 17 279 54 0 744 683 632 1030 372 1217 5 72 1 109 r c 331 1 -271 -106 24 4 K.a - 2 O 0 -a-.-is 185 39 -24 7 - O 'i 0 -MO 27 3 - 036 -70/ -9 1 7 -6^0 1 tTJ -:';:7 -12 2 7 692 104 3 K = 240 -51 401 468 660 -09 292 1 04 »;--5 2i'9 -69 134 26/ 179 286 1 IV 314 1 19 281 243 284 90 704 207 422 776 I 192 430 397 340 819 344 576 765 90 361 117 192 194 160 325 -Oti 24 0 1 2o 264 3i3 -232 9 b 37o -4 85 -650 18 289 1 IS - 140 -366 O » 212 -4 -1' 5 -2t.<\ J62 298 -125 -3,-2 1 1 1 293 292 -2/0 -82 700 2 34 2a7 -MOO -1 CI 6 39 4 4 25 -24 0 -7rt9 346 -020 -761 68 3t. 6 IC4 - 198 - 190 178 340 -b9 - ? :■ J - 1 0 9 251 324 215 -18 -17 -1 6 - 15 -14 -13 -12 - 1 1 -10 -9 -6 -7 -6 -5 -A -3 -2 -1 FO -65 IVl O i.- 1< 3;>7 4'< 1 t,7 6 -bt 5^9 £.P4 03 3 1307 63 5 0?9 2'-ie ICVO 0 1 '2 3 4 5 6 7 8 y 10 -21 -20 -19 -lb - 17 -16 -IS -lA - 13 -12 -1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 -1 162 -1.7 /;'J9 144 ^53 -05 31 i' 276 171 179 -69 151 26 I 151 -65 103 102 420 -60 439 412 436 6 1 0 30 7 6^7 3a3 673 905 149 59 0 370 tJ09 FC -9P -210 5 e9 42^ 154 -4?0 849 652 4 -5:15 -4yy 694 1 266 -605 -607 333 994 4 2 452 175 -262 -21 204 279 - 151 -1D5 4 0 133 -254 -133 79 126 -2 30 -425 -20 44 4 430 -400 -61 2 4 29 636 372 -936 -668 129 55 7 -335 -tiSl 0 1 2 3 4 5 6 7 0 9 -2 1 -20 - 19 -18 -17 -16 -15 - 14 -13 -12 -11 -10 44 5 333 ^•9 0 275 269 169 1' B 26 7 191 126 -6'3 163 9 7 -0?. 231 143 490 -60 t2 7 243 155 465 429 ■3~5 ■27 0 202 ?^S 200 ■ 1 '. ? -3 06 195 14 1 -29 173 -82 6 -236 -116 483 ?6 -6 56 -246 1 5 6 488 FO 419 404 1 01 1 356 02 5 101 353 51 5 1 14 H- FC 436 -389 -140 12 H 4 6 3.i -10? -352 -5 37 119 K- 0 1 2 3 4 5 6 7 -21 -20 -19 -1 8 -17 -16 -15 -14 -13 -12 -11 -10 -9 -O -7 -6 -5 — /; -3 -2 — 1 \^ 0 1 2 3 4 5 6 -22 -2 1 -20 -19 -18 -17 -16 -15 -14 -13 -I 2 -I ! - 10 -9 -8 -7 -6 -5 -4 -3 _ -» -1 384 376 160 -y8 305 16 1 358 2 :5 -67 2 55 146 -65 320 -64 27 5 93 4 62 276 -57 472 124 533 — 5o 687 324 354 1 87 261 486 -375 380 1 C i -7 -317 - 1 54 35-^ 249 -6 J -24? - ' 44 64 30 7 23 -297 41 477 27 0 25 -475 - 128 550 91. -688 -329 - ~^' 3 192 24 2 -4S< K = 240 3 66 223 -67 253 -69 273 225 -68 183 leo 139 227 212 225 -63 314 152 96 553 -59 497 277 209 -61 91 277 -65 490 219 -3 64 -203 63 26 7 34 -253 -22 3 -d3 190 19'J - 127 -2 34 -228 229 34 -304 -167 72 5L.3 76 -463 -28B -230 -9 -8 0 -264 - 100 473 2 3 4 ■21 ■20 -!. 9 - It -17 - 16 -15 -14 -13 - 1 i- -1 1 ••10 "9 -7 -4 0 1 2 -21 -10 - 19 -18 - 17 -16 -15 - 1 4 -13 - 12 - : 1 - ic -9 -8 -7 -6 -A -3 -1 H= FO 22^ -70 2 09 -c r 1 0 1 50 -65 3 17 3:^5 2 14 -66 -63 2 66 -03 513 -62 23i -64 -6 5 -(5 208 c27 - /I 456 <■ t '; - 69 129 2 ■iO 2:8 i:.'7 2 36 -66 333 -'i50 100 221 -68 3 74 1 ^5 tCti 103 -67 -66 1 15 268 2 36 -69 -68 -68 FC 23 0 •- 4 (.> -271 6<< ->i7 -142 -25 389 :<2 3 -22 6 10 1 -3'^ 263 49 -514 -7 236 33 34 27 ma 624 54 -469 8 57 -ICC -275 -164 134 239 34 -333 -439 -60 226 1 18 -372 162 529 74 -55 -43 121 27 7 -257 -74 27 36 H= K- 176 -68 - 177 108 0 -21 -20 -19 - la - 17 -1 6 -15 - 14 - 13 -12 -1 1 - 10 -9 -8 -7 — ^> ^ c -il -3 -?. - 1 H- 4. K = 102 379 -68 267 - -66 -65 -68 154 116 - 2':;5 9fci 201 168 -o7 330 -4 9 3C4 22/ -70 257 4. K = -79 360 -19 -244 65 227 -33 -102 -128 -119 298 -8 0 -2ij7 175 62 32 1 16 -313 -66 219 -79 -226 10 -20 -19 •-i ^ -17 - 16 -15 -14 -1 3 -12 - 1 1 -1 0 — 9 -a -7 -6 -5 -4 -3 -2 ^,- -18 -17 -16 -15 -14 -13 -12 -1 1 -10 -9 -B -7 — 6 -5 H = -16 - 15 -1 4 -1 3 -12 -1 1 -10 e,- 7 8 9 10 2 3 4 5 6 7 8 9 10 1 1 12 1 3 14 0 1 2 3 4 FU 1 03 '1 51 -68 316 -e.6 234 239 -66 210 -06 -67 -67 1 06 212 1 18 370 -70 230 -71 4, r.= -68 149 -6 8 193 191 166 169 -65 154 -69 142 160 -73 2 05 4, K-- -69 258 -73 178 167 1 12 158 4, K= 1 15 152 123 139 rc 1 09 163 -78 -34 7 -93 241 252 -59 -21o 9 95 63 -ir.9 -22 6 14 6 393 -4 6 -22 6 -14 1 1 C I r 4 7 1 -22 2 -183 170 152 -40 - 175 136 164 - 125 -207 12 -32 2u7 1 17 -14 5 -2C0 -.75 174 -15 - ICO -J 45 -126 125 K= -14 -70 17o 173 146 231 1 03 103 175 168 171 203 1^9 -68 K= 141 275 -66 253 -66 -!C4 198 165 -157 -233 -92 1 13 160 -163 -175 1P3 139 -43 -13 131 30 7 -43 ■244 216 FO FC 5 151 167 6 -C'* - 1 7 -Cij -45 6 10/ -IIP 9 -06 93 10 ^i-l 214 1 1 - CO 67 IP. 90 - 1 c -.' 13 loi - 17P 14 10'. 1 CO I'j P-Jtj rvf. ll. -ft8 -?6 -1 -t>« 0 M= 0 1 2 3 4 5 fe 7 6 y 10 I ) 12 13 1 4 15 16 17 -4 -3 -2 -1 H = 0 1 2 3 4 5 6 7 e 9 10 11 12 13 14 15 16 1 7 -6 -b -4 -3 -2 -I H = 0 I 2 3 4 5 6 7 6 9 103 2) y -Oh 30 1 -^66 -6 5 161 -<>6 352 152 20 f. 31 0 lOH 31 5 -t-u 210 1 1 6 25 3 I 0 6 -67 -66 -C6 -66 2 1 5 15'» 40 1 95 2 03 -65 3t2 190 45 I 25 7 192 Vti ~fo 2A2 206 2tSl 21 2 -60 -67 -64 2 I 0 1 3o K- -12 9? - 107 -73 2*7 6 3 -6 4 ■ 133 -1 7 359 -1?1 -392 -30C 1 49 320 f<9 - 196 -pe 27 3 - 131 -1 2 53 74 K= -1 1 -90 215 - 153 -403 -17 IP ]9C -74 ■34 4 21 4 4 35 -254 -200 -R7 -26 22 3 200 •2/6 ■209 35 85 -3 21 7 15 1 4 . K- -64 306 20 7 ■ 150 166 1 00 5/3 - -6 3 47l> 1 J2 -1 0 -66 -309 -21 I 159 133 -3 0 - 566 3P 49 1 1 16 10 I I 12 13 14 15 16 17 •- 5* -7 -6 -5 -4 -3 H = 0 1 2 3 4 5 6 7 8 9 to 1 t 1? 13 14 15 16 17 -10 -9 -8 -7 -6 -5 -4 -2 -1 H= 0 1 2 3 4 5 6 7 C 9 10 1 1 12 13 14 15 16 17 -1 1 -10 -9 -8 -7 -5 -5 -4 -3 -2 FO -63 I '.. / 1 0 5 465 103 34 3 135 21 1 231 I 16 -6/ 140 144 -64 122 194 FC 26 -1 J(. 47 46 7 107 -35J -152 21 7 -222 -119 42 162 -1 14 -53 82 176 1 06 29 1 67 200 -57 246 501 550 469 203 -64 262 102 4o7 163 263 -65 -66 20 H -60 306 159 26 1 -6 7 2b3 323 147 405 K.= -9 -1 1 -65 -200 -17 230 51 ' -549 -459 -217 09 265 -115 -516 - 169 255 21 -75 -209 12 2<^-9 16 5 -249 -60 289 323 ■ 12 I ■409 1 12 473 150 5 99 807 297 633 1 17 402 406 261 424 3dl 438 -to4 321 201 -67 196 2Z^ -66 170 209 126 147 209 54 2 98 K= -8 103 -■^34 -158 576 750 -303 -509 -04 4 I?. 3 7 si ■267 •442 303 44 0 55 -323 ■205 47 204 239 -69 •169 197 151 162 ■224 ■525 134 L - 1 H = 0 1 2 3 4 b 6 7 8 9 10 1 1 12 13 14 IS 16 17 - 12 - 1 1 -10 -9 -a -7 -6 -5 -4 -3 -2 -1 H= 0 1 2 4 5 6 7 8 9 10 1 1 12 13 14 15 16 17 -I A -1 3 - 12 -1 I -10 -9 -e -7 -6 -5 -4 -1 H = 0 1 2 3 4 5 FO too 4, K = V7 1 545 445 09 t4£ 339 463 -54 4 77 5 29 -CO 426 334 4oO 242 421 23^ -6 7 1 1 k 191 1 £3 292 -6b 207 302 372 ■ -60 481 fc43 3 49 4. K- 150 350 - 296 - 540 773 -52 133 - 26 3 - 4 02 34 0 261 :-9I 235 244 2 23 - 2 '.9 202 - -68 -69 108 - -fcO 277 1 1 3 4C9 - 431 162 - 1 SO 330 3 74 100 - 10 10 425 4 , K = 281 71 1 145 - P.7H ^20 - 2tZ - rc 490 -7 7V7 5/0 424 23 -t57 26 7 450 46 -490 -514 07 4 02 -347 -4 *0 261 445 239 -3 15b -172 -1/1 290 29 -199 -306 -370 65 4ei -793 -3o4 -6 170 -314 -299 £32 726 72 - 139 -242 365 365 -247 -305 233 345 -240 -.-.52 -19<; 55 62 -202 -40 204 -69 -42 I -436 -122 109 36 1 ■401 ■204 9o2 425 -5 -175 71 J ■ 161 ■OiO ■49 b ■250 6 7 8 9 10 1 1 12 13 14 15 1 0 17 - 1 5 - 14 - 1 3 ■ 12 - I 1 - 10 -9 -6 -7 -6 -5 -4 _ 1 0 I 2 3 4 5 6 7 0 9 10 I I 12 13 14 1 S 16 - 16 -15 -14 -13 - 12 -1 1 - 10 -9 -0 - 7 -6 -2 - 1 0 1 2 3 4 6 7 8 9 1 0 1 1 FO 1C3 100 "ol 6 307 402 1 14 -63 1 96 144 197 2l)9 133 1 4 6 -60 2e3 1 19 294 2 03 -62 426 107 647 1 01 762 691 1 1 7 870 FC 96 122 -«•! 0 - J.'-'O 400 103 -4 0 -I'f^ 14 6 200 262 - 1 14 - 165 23 256 -100 -294 -20^ 33 430 -1 56 -64 2 - 15 736 612 7 7 -790 4 , K- -4 439 940 1 176 029 254 216 641 I u;i 64 b 442 233 170 -64 101 120 258 2t3 -«>6 196 -65 309 -65 359 365 -60 700 420 234 4 66 037 963 1 40 6 72 447 -061 - 10 7 4 779 202 -2 16 -63/-. - 1 t'3 CJ4 439 -22 6 -198 -6 0 70 lOo -236 -245 0 109 10 -3C4 -35 3 52 370 -55 -731 -305 24 1 572 -034 ■I 10/ -2CC. 604 332 1215 30O 3'«9 -•-■J 74 758 2b2 399 164 236 345 K= -3 -276 1101 393 -3 2 7 -52 1 0 725 204 -415 -160 233 332 217 FO VC FO FC FO FC ro re 1?. 340 341 -17 162 183 - 10 299 rso 13 4.) 2 -451j -1 6 -64 -80 -•9 7 16 716 h = 5 , K: = 4 14 44tJ - 4 5 0 -15 134 - 1 36 -8 109 -5 • 15 333 33 6 -14 103 8 1 -7 09 -30 0 177 -164 17 lt>6 163 -13 22 1 230 -6 769 -736 1 4 95 -46 2 16 -6 'J' -15 -12 420 44 1 - 5 301 -285 2 -66 -20 ir> 2i>6 -25'^ -1 I -56 -33 -4 7 59 6 09 T -68 ~] 5 l'» 142 1 1 6 -10 4t 1 - 4 9 7 -3 4 2o 3 7-t 4 2 99 2 96 i:< 31 7 31v-> -9 4oy 416 -a 187 -166 5 1'5 1 153 12 -o4 5 7 -B 459 417 - 1 51 J -478 6 3 3 0 -323 1) 1 3U -172 -7 1 7J - 1 9 9 7 -72 -108 10 240 -24 5 -6 264 -290 n- 5. K- 2 -21 -t-O 21 -9 121 112 -5 337 47 1 -20 1 3? 102 -0 73 1 71 7 -4 672 -587 0 3 36 329 -19 - V • '^ 69 -7 2?4 23 6 -3 445 -534 1 7 77 -7o4 - I 8 -Ui> -98 -6 ISO -21 r -2 751 "563 2 5PP -575 -1 7 625 -605 -5 130 31 5 -1 07 - 107 3 197 18!i "16 "67 -82 -« /i4 9 46? /i 3 59 367 -15 315 3! 4 -3 59 2 41 e H= 5. K: 0 ^ 2 26 -222 --14 10 4 -75 -2 1 77 16? 6 222 -190 -13 2 69 -286 -1 <»3 1 -82 1 0 -52 -15 7 -66 -16 -12 -58 47 1 370 -34 6 e 121 152 -I I 3ol 357 (= 4, K = = -2 2 86 6 -650 9 285 29 2 -10 670 S22 3 loy 1 18 10 -69 13 -9 = 198 165 0 1117 1 036 4 41 1 3«4 -.-il -68 7 -8 6 24 -6 33 1 20 ? -277 5 141 137 -20 301 2 76 -7 120 1 14 f 32 7 --59 6 44 4 -431 -1 9 -65 -9 -6 -57 121 3 1 04 9 9 39 7 185 -190 -IC 247 -249 -5 106 -128 •0 1 1'. 0 1 160 8 27 5 2 72 - 1 7 90 -86 -4 2<:6 -311 b 445 41 1 9 243 228 - If -64 27 -3 566 "54 8 6 499 -477 10 1 o9 - 179 -1 5 -64 8 9 -2 199 "204 7 703 -697 I 1 35 3 -374 - 14 203 -183 - 1 425 4 35 8 ?66 28 G 1 2 -71 -7 -1 3 £■^7 - 6 <> 9 9 102 -70 -20 133 130 - 12 3:; 2 -341 H- 5, K = 5 10 223 -?33 -19 10 I I 16 -I I 265 2h3 1 1 474 -AC, I -le 20 5 -205 -10 575 54 9 C -6? 41 IP 139 -189 -1 7 -65 -12 -9 -54 -60 1 2*^3 238 13 21 7 235 -16 3H6 36 R -•8 ~t?. - 1 C7 2 2.05 105 14 26 5 274 -15 251 24 5 -7 310 -27 5 3 -69 -100 15 109 - 164 -14 -62 40 -6 7 39 716 f. 34 8 -344 ■10 -67 -6 9 -13 167 -192 -5 1 14 132 5 "70 9 ■17 234 -222 -1 2 37C -4 0 7 -4 787 -78d 6 2 76 286 16 -t5 -1 0 -11 4 70 473 - 3 232 -374 -2 1 -67 -34 15 232 2 3 9 -10 793 776 -2 — 5 V 75 -20 150 -1 75 ■14 173 185 -9 10>9 -952 -1 573 556 - 19 •■ o4 -7o ■13 210 -232 -8 575 -565 -18 34 1 33 4 ■12 230 -21 6 -7 472 492 , H= e. K- 3 -1 7 573 566 ■ 11 158 134 -6 1111 1 044 -16 176 165 •10 619 C3 2 -5 1033 941 0 2 58 -264 • -15 3 65 -3J>4 -9 1^>4 104 -4 oao -024 1 625 59 is -14 -63 20 -a 692 -695 -3 216 131 2 379 3d>'^. - 13 53 5 53 8 -7 -55 1 1 -2 51 4 502 3 212 - ) 90 -12 -60 -29 -6 e84 e?? -1 560 606 4 236 -241 - I I 4-14 -421 -5 519 -23 1 5 133 130 -10 529 -540 -4 94 i -92 5 H= 5. K = 1 6 1 4 4 173 -9 -60 -79 -3 6B -234 7 232 21 1 -8 795 7 76 -2 797 -7 54 0 569 -C03 a -71 -8 9 -7 -59 -5 -I -54 113 1 7 69 749 -21 -63 -33 -6 4r5 -490 2 901 657 -r.O 22 1 -22 9 — 5 4 26 -433 *=• 4, Kt = - 1 3 356 -541 -19 1 0 7 -68 - 4 337 347 4 352 -346 -lU -r,4 4 9 -3 ^ :< 0 417 0 38 2 ?.4 5 5 149 169 -17 -66 63 -2 -64 - 55 1 e04 71 o 6 2v0 318 -1 6 -65 -84 -1 4 76 -455 2 392 3R9 7 -67 71 -I £ leo -173 3 230 -255 8 225 -228 -14 -62 -?'. H- 3, K: 6 4 io;.9 - 9«'i 9 269 -272 - 13 af 2 262 5 -54 -= A 10 -68 33 - 12 294 304 0 -70 -95 6 550 C43 1 1 269 2 58 - I I 2 79 -277 1 137 -159 7 33 1 31 6 -2:^ 204 -202 - 10 293 -3 19 2 I 76 -157 6 91 -81 -IQ -66 -?7 -9 133 90 3 -70 60 9 1 19 -lie -18 301 296 -8 3^3 36 1 4 163 198 10 -66 13 -1 7 - t>'r> 44 -7 3^4 3'. 3 --2 1 98 -t'5 1 1 195 IRC. -16 1(>C - 125 -6 4 50 - 4 2 2 -20 1 .4 151 12 177 164 -15 93 -92 -5 1 44 -176 - 19 1 18 123 13 127 -15? -14 f.a 59 -4 19C 166 - 1 6 28 1 -288 14 -6H -7r, -13 4 3 I 432 -3 29 8 235 -17 451 -447 -19 -6 6 -BO -12 426 464 _ 7 1 59 -148 - 16 125 108 -18 -6« 81 - 11 573 -544 - 1 327 -32 7 -15 64 8 658 218 FO FC PU FC ' 14 1 09 -06 -1 1 128 -145 - 1 J 1 :» '.1 - > 3 '.. - 10 zee -2O0 - 1 ? -bP 1 1 -9 I/O - 159 - 1 1 1?0 -90 -8 190 224 - 1 0 :.t>i> 5ni> -7 329 33 0 -•3 -o2 -4 1 -6 231 -246 -6 4b2 -46 0 -5 251 -253 -7 ~L-^ -3 'J -4 1 13 98 -f. 2? 1 ?o:> -3 1 12 1 1 7 -t> ti I 61 1 -2 -72 -34 — A -ct> 3f -3 3ce - 3 3 B H = 5. K." 10 -? - 70 10b - i 4 64 472 -19 1 7b I6t: -le -otf -?a h= 5. K: 7 -17 I2ti -159 -1 6 -66 2 0 204 - 196 -15 2 1 / 217 1 107 9 6 -14 160 163 2 loO 176 -13 l'i6 - 131 -? 1 li- "/ 1 C2 -12 22 9 -243 -20 13 1 -1?7 -1 1 -t'l 54 - 19 159 -164 -10 204 21 7 -16 24 b 2^0 -9 -09 -24 - J7 332 Sl-^J -n 134 - 1 53 - 16 22 1 -20H -7 -73 -43 -ir> 628 -64^ -6 1 13 145 - It 22 3 -203 -f. 235 240 -13 107 n 8 -J.? 36 'j. 34 5 H= 5. K - 1 I -1 1 -65 10 -10 faol -5f>8 -17 1 63 175 -9 141 1 1 f> -16 1 1 t 124 -6 30 7 3 0 9 -15 2 73 -274 -7 19 0 167 -14 1 1 0 -111 -6 -66 30 -13 27o 26 1 -r> 2V6 -265 -12 KJ 166 -4 210 196 -I 1 -/ I -121 -3 438 426 -10 -7.S -lis -2 -69 -82 -9 -72 -78 -1 333 -334 H= H= 5. r.= -15 0 -71 81 -21 179 -16? -20 21 0 214 -19 175 156 -IB -0 6 -66 -1 f 98 -95 - lo -65 -91 - J5 269 293 - 14 lci9 214 -13 235 -230 -12 293 -30 7 - I 1 -66 1 19 - 10 434 44 8 -9 -6 7 19 -8 134 160 -7 304 -31 4 -6 lOl -71 -5 218 168 -4 -65 -33 -3 -69 -119 -2 -6e -60 -1 -65 -16 H = 5. K = 9 -20 279 -276 -19 122 -136 -Iti -6/ ?2 -1 7 -66 -84 -It -6 7 -98 -15 253 -24 7 - 14 210 -21 9 - 13 1 77 17P -12 354 33 V 7 8 9 H~ 1 3 4 5 6 7 e 9 10 1 1 12 13 186 I A I 116 169 -6y 319 121 2 53 1 tiS -60 34o l". I 2 -l 3 -o7 203 1^/ H= K = 0 1 2 3 4 5 6 7 R 9 10 1 t 12 1 21 127 16:j -67 -o3 147 -6 7 30 1 -l.'j 1 90 121 21J ■190 ■1 1 1 92 -14 -174 -26 312 lOO -245 -16a 81 352 129 -26 1 -03 2oa 1 17 -1 3 100 124 6 166 -5 53 12 3 100 -2B9 -60 190 1 12 ■215 13 14 -2 -1 H = 0 1 2 3 4 c 6 7 0 9 10 1 1 12 13 14 15 -4 « -a -2 -1 H= 0 1 2 3 4 5 6 7 8 9 10 1 1 12 13 14 15 16 -6 -5 -4 -3 -2 - I FO 225 -to -68 -70 H~ FC ■250 54 •123 L FO J 100 ■2 ?96 •1 430 FC -04 30 3 422 K= -12 -65 332 -66 293 132 If b 279 -64 107 179 303 144 -67 4 05 124 2 50 194 191 -69 368 -65 237 1 29 271 -66 174 -t>b 9'i 137 107 -66 -C:5 -64 123 1 12 273 -67 121 -68 -65 12o 96 les 4 5 6 7 e 9 10 11 12 1 3 1 4 15 1 6 -'J -7 -6 _ c -4 20 -335 -62 296 114 137 -286 -36 103 -207 -302 -120 106 301 lie -232 -leo -202 121 378 : -1 1 8 2& 2 -115 -2ol 13 - 173 -45 o2 - 123 se 43 -93 -60 -124 1.20 273 -24 -1 10 4 90 112 -73 -207 K = -65 4 0 4 -65 2 37 1 19 -0 3 60 4 165 t 11 -66 190 103 277 151 3^9 3; 7 - < o 239 1 19 234 -c4 125 10 -3 -447 68 269 122 -9 -c05 lt)5 tee 79 -204 -«.. 6 271 130 -341 - -51 t 6 -240 1C5 243 - 1 I 0 I 2 3 4 5 6 7 a 9 1 0 1 1 12 13 14 15 16 -10 -9 -a -7 -6 -5 -4 -3 -2 - I H = 109 2d6 -59 -59 310 430 333 266 42«!' -o3 173 16 1 1 ^C 27H 212 2 69 -66 -71 346 191 2 29 19'j -o5 24 0 2 39 2i;3 160 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 - 1 1 - 10 -9 ~a -7 -6 -5 -4 -3 -2 - 1 H= 0 . 1 2 3 4 6 7 e 9 10 K- -9 106 207 25 -35 -290 444 316 -204 -426 -32 162 194 -163 -293 225 2 78 50- 4 7 356 2C4 -231 -164 -12 256 212 -291 - 140 -r>9 54 5 335 564 363 520 272 133 357 221 1 1 1 209 103 22 4 126 299 220 1 30 136 370 2 57 -64 1 84 -ti5 67 7 225 413 57t) -8 -76 -514 -3 09 59 4 379 -522 -29 1 125 354 201 -130 -220 129 235 -9 9 -301 -203 166 1 IC -3«1 -281 -3tt 196 6 -575 542 K- -7 120 4 14 926 525 242 653 -56 1 17 222 3 57 198 126 370 897 -509 -229 632 IM -120 -207 -336 215 219 L FO FC L FO FC L FO FC L FU FC 1 1 340 336 -9 210 200 -1 1344 - ■1229 3 -62 -29 12 -o5 -71 -a 203 209 4 -63 2 6 13 105 -125 -7 226 -196 H= £. K= - -2 5 2 04 -223 1« -64 67 -6 33 7 -364 6 162 -175 15 lOO 167 -5 280 254 0 -55 6 7 -66 76 16 2t.C 2 53 -4 117 203 1 57o -555 8 2 52 2(>7 J 3 109 14 0 -3 106 145 2 320 289 9 163 149 12 1 /4 174 -2 5t'.3 -516 3 2 85 292 10 186 -196 J 1 3t.2 -351 -I »"*3 -232 4 406 405 -20 178 180 10 226 -22 1 5 J 04 - 120 -19 -66 4 -9 120 ice K= S. K = = -4 6 659 — o63 -IcJ Z'j'i -266 -0 -66 6 5 7 94 -46 -1 7 155 -156 -7 -64 -14 0 228 250 8 200 176 -16 148 144 -6 349 -354 1 531 -5i'-6 9 1 la -101 - ib 156 150 -5 19 1 -164 2 594 58 0 10 - 6o -99 - 1 4 145 170 -4 li3 3 56° 3 i 10 1 10 20 ] 1 108 -67 -1 3 345 -350 —3 -59 -18 4 448 455 12 -67 -42 -12 166 -191 -2 66 9 -e3i 5 -54 21 13 3 56 35 2 - 1 1 831 8i>5 - 1 1 0 3 -73 6 513 -526 - 18 -67 -89 -10 -d7 62 7 19/ - 199 -17 3C0 -296 -9 431 -4't2 5. K^ -6 8 53 3 521 -J 6 97 76 -8 — 54 -4o 9 34 7 374 - 15 4li? 4 1 a -7 4 95 -449 0 249 -265 10 4ai -402 -1 4 -66 19 -6 482 493 1 732 -733 1 1 34 1 -330 -13 320 -3''9 -5 55 J 527 2 53a -54 C 12 1 19 122 - 12 -61 -27 -4 717 -669 3 723 709 13 29C 290 - 1 1 2C9 22 5 -3 4 06 -421 i.. 54 -2 818 -7/5 6 149 -11.4 IC 27o 234 -8 3^(3 3*7 -I 440 -^15 7 -69 -3b - 15 -69 - 1 1 1 -7 250 -22 5 8 376 371 - 14 135 12 P. -6 311 -395 H = Ct K 0 -21 -66 23 - 13 304 297 -5 130 -212 -20 165 162 -12 1 19 95 -4 3o2 450 C -56 102 -19 13t. -9 5 -11 22 1 -22 1 -3 10^3 1 0 B 'i I 444 -4o0 -18 32<. -31 9 -10 -65 94 -2 T^O -742 2 230 -323 - 1 7 lo3 - 194 220 ro re FO FC FO FC FO » C ^ t 4 03 464 5 -66 «6 -16 176 ICC 5 -2 -1 -70 -22 6 7-67 b4 -lb :i05 51 0 H- 6 . K = 24 6 - 2 5 0 7 297 ■ -290 - 1 /; - 6 3 -f.7 8 380 -362 - 1 3 62 i) - 1 2 - b V ■625 I 0 1 -60 13/ 89 150 H = 6. K- 8 9 10 196 2 72 170 272 -11 29 2 320 2 -69 12H • 163 • 171 • 231 I 16 -66 -66 239 301 200 -64 -61 221 674 245 b56 23'» 182 157 95 -1 lb '172 - 160 -2 19 -UO 84 6S -223 -274 193 60 -tl -222 -666 219 b66 -274 -182 16 1 - 20 2 77 26 b 11 -67 -19 -10 251 -fj 216 - -8 '.02 - -7 -S3 -6 572 -5 207 -4 31 0 -3 109 -2 -09 -1 171 H= 6. K= 0 -65 1 367 2 -67 3 2b2 4 220 5 -6 7 253 -20 7 -406 -3? t;6 7 ie3 -292 7 1 -89 163 3 40 365 57 -246 -206 -22 3 4 -?l -20 -19 -1 n -17 -16 -15 -14 -I 3 -12 -1 1 -10 -9 -8 -7 -6 -5 - 19 - le -17 - 16 - 15 -14 - 1 3 -12 -1 1 -10 -9 -7 -6 -5 -4 -3 -2 1 26 143 17 J 126 31;1 -67 4 2b 163 -67 1 fi8 -67 37b 327 ; 16 39 7 I 12 236 1C9 10b - 152 -I9b -64 356 79 -430 -160 127 156 bS -393 -34 6 322 398 - 10l> -231 -120 12 13 -2 - 1 h- 0 1 2 3 4 5 6 7 8 9 to 1 1 -6H 1C3 161 -69 6 • K = 131 369 -66 294 1 16 33b 237 127 209 1 17 155 1»;4 -93 -90 -154 -23 -12 -122 -357 -25 29'* 1 13 -3bb -250 141 23 1 -105 -132 -178 6 300 7 -69 2H7 1 -A -3 224 3 66 214 364 H= 6, K = 9 12 13 -65 276 -41 2.^5 -21 -65 - 2 0 1 5 << -1 1 - 196 -2 -1 1 36 2 60 -149 -262 -19 -IS -69 21 0 -24 199 14 -5 -67 -73 -12 -99 -19 -65 42 6, K = -63 1 0 4 154 -67 236 149 9 7 106 192 -6o 6 b6 -115 - 14o - 16 214 133 -131 -120 104 -17 -54 -17 -16 -15 - 14 -13 -12 -I 1 -10 -9 -8 -7 -6 -68 7b -4 235 -^32 - 1 0 216 -17 104 -16 306 -IS 566 -14 -63 -13 tt:i^' -12 32 4 - 1 1 1/9 -10 23 9 -9 251 -8 495 -7 101 21 3 7'.-, -309 -',-92 -47 421 319 - IbO -200 265 4 75 -B4 f) 1 2 -21 -20 -19 -1 8 -17 -16 -1^ -69 364 - te 390 201 149 293 126 4 69 -74 159 199 -71 -363 -7 2 374 200 -123 -30 1 92 463 121 -166 - 179 -3 -2 -1 h- 0 1 2 3 4 5 -6H 3 63 313 6. K = 129 3C I -66 29 7 144 1 01 -bH 370 304 ; -1 1 1 15 31 1 15 -302 -128 88 - 6 24 3 -26 0 -14 -66 6 6 89 684 - 5 4 3 9 -424 -1 3 -6r'. - I 'J 9 H= 6. 1'- = 10. 7 167 169 -4 24 4 24f -12 20 J - 223 8 4b2 -48 1 - 3 3 11 -2 139 -1 462 H= 6. K 0 -cs 1 2<1 7 296 - 133 -475 = 4 -R3 -226 -1 1 -10 -9 -R -7 -6 -5 -4 2 57 53 2 274 255 131 I J2 135 202 : o7 52d -259 -249 129 t,6 1.^2 -lt'4 • -17 - I t - 15 - 14 - 13 - 12 - 1 I - 10 -9 -b 149 -71 307 -6t3 233 1 31 -7 1 151 -72 1^2 -123 -3 1 3C2 40 -c22 -113 67 130 6 3 — /6 9 10 1 1 1 2 13 14 15 -7 -65 -64 217 i;'i 1 1. '- -67 lf-2 -73 45 54 226 103 -176 -43 1 b3 - 151 2 10 3 3 213 210 -3 -2 363 2'c'> -366 213 -6 -5 14cl -69 -126 1 16 4 259 2H 1 -1 130 126 -4 150 153 5 -71 -77 - 7 H = 6. K = -14 -3 1 :.9 143 -2 1 163 159 V-- 6« K -2 -t.6 -73 -20 201 -iy -6 3 -18 152 -17 -64 -16 29b -15 blO -14 90 189 22 -151 -3 7 2^5 51 2 -7 2 0 -21 -2 0 -1 n -in -1 7 1 64 -6y 202 1 9 3 270 2b5 - 18 1 4 b -20 0 -lo7 251 257 - 2 '5 8 1 2 4 5 6 V 110 179 277 -68 164 -67 -«v7 -120 152 27 1 -5 -147 - 13 54 -I H= 0 1 2 231 6. ^ 330 308 -6b -233 = -10 -32b -326 -44 -13 150 - 131 - lb 2i 1 1 it 9 10 1 1 22 1 -69 220 3 173 150 -12 132 -l>fl -15 3 35 -3 licJ -i>2 514 172 -2-7 -3o7 -73 4 4t6 460 -11 23tt -10 544 -9 -6 2 302 ;.66 127 -1- -I 3 -12 -o7 502 1 76 2°5 -70 -303 5 8 5 6 7 1 79 4 79 2 59 -165 -4i>9 2o4 -8 12 3 -7 112 -120 133 -1 '. -10 2 7 2 J46 H = 6, K= -13 8 9 2 49 9 3 2:. 5 -53 -6 229 -5 -62 -4 33b 239 -40 -?"57 -9 -7 299 21 1 10? 3 0 J 224 -62 - I lb -376 277 0 I 221 215 -66 217 -C6 205 214 1 b 10 1 1 12 174 3 36 -64 - 1^0 -344 -30 -3 320 -2 -fco -I 298 -341 50 293 -6 -5 -4 1 04 39 o 307 3 4 -220 13 14 233 -67 250 -3a 221 15 -9 -8 -7 -6 -5 - -6 1 27 7 166 24 9 130 i^^y 104 -6A 30 6 30 9 307 31 5 190 138 -69 155 -66 13 5 209 -65 337 -06 460 3Qb 0 I 2 3 4 5 6 7 8 9 10 1 1 12 13 11 15 ■12 -1 1 -10 -9 -S -7 -6 -4 -3 -2 -1 K= 105 Iv 1 6 0 -31 0 -Ue 257 1 1 5 - 151 -104 -14 29 1 -31 1 - 3 0 6 162 154 57 149 ~3'i -127 -2oa -25 330 -70 -479 -384 ■8 2'>7 4'. 3 2 57 73 1 -60 429 19 4 -to 2 72 132 545 -64 461 1< 4 159 167 -70 230 -6 9 269 -65 -65 26 7 113 44 9 141 3C4 290 -232 -45 1 26 1 726 ?2 -402 - 182 21 235 130 -571 28 460 136 -l.?7 - 196 -52 231 _q^ -273 -46 P3 264 - H4 -4t>0 - M6 35 2 295 K = 0 1 ^ 3 4 192 657 155 4f)l 126 -7 203 6^6 146 -51 2 93 6 7 8 9 10 1 1 I? I 3 14 15 -13 -12 -1 1 -10 -9 -8 -7 -6 -5 -l 7 rc 326 94 -79 -604 -162 528 -6 -38t) -178 69 176 2S0 -13 -363 24 5 237 150 -1 1 -39 7 -220 131 22 -31 2 -300 -6 -4tl -155 -34 414 75 -412 0 -2 200 -36 -403 -174 248 2o4 39 -41 -272 196 ZJ i -J 1 :9 -103 -253 -67 550 26 -387 -153 o4 2 440 K = 0 1 2 3 4 5 6 7 o 9 n 1 1 \2 1 3 14 - 15 -1 ^ -13 -12 1 53 3«9 177 6tJ3 2b0 54 9 2tJ6 -f. I 335 14V 4<»0 1 /3 1 1 / 1 70 -t)6 12-. 1 72 3bo 121 -5 1 19 4 0 0 • 1 B3 •66V* 2SO 531 30 1 6 -37 7 149 436 175 -133 -179 -77 -133 165 36 3 -123 - 1 1 -10 -9 -8 -7 -6 -5 -4 -3 -2 - 1 FO 240 Ao 1 -65 295 7 1 2 t£5 3 5a 569 361 309 321 H= 0 1 2 3 4 5 7 e 9 1 0 1 1 12 13 -17 - 16 ■ 1 5 - 14 -1 3 - 12 -1 1 -10 -9 -6 -7 -6 -5 -4 -3 -2 -1 y.- FC -251 -501 -103 2CJ -642 -689 301 520 34 0 -23 7 -329 FO FC K= 1 76 3c2 -54 221 286 2 10 4 68 92 5C6 1C8 4 06 -64 -67 232 "70 1 18 1C5 215 2^6 11:9 -64 399 5C7 527 212 233 -52 -52 -52 0 1 2 6 7 e 9 10 11 12 13 -17 - 16 - 15 -14 -13 - 12 -1 I -10 -9 -b -7 -6 -5 -4 -3 -2 -4 -192 -336 -88 235 305 -212 -457 46 507 -91 -407 -66 78 235 -96 l2o 66 -21 1 -237 -171 39 412 -37 5 -31 7 540 586 153 -277 -53 81 -2 K= -3 244 4 45 482 456 775 216 779 34 9 227 267 109 218 134 «24 1 1 1 219 251 172 130 221 88 215 444 183 614 173 1 14 310 220 705 270 436 4f 0 -.^54 -757 212 767 -364 -204 273 lOB 212 -9 5 - 403 1! 2 -216 -259 204 166 203 -43 -238 4 25 173 -530 -127 1 8 238 235 -CU3 -1 0 1 2 3 4 S 6 7 a 9 10 1 1 12 -18 - I 7 - 16 -1 5 -14 - 13 - 12 - 1 1 -10 -9 -O -7 -6 -5 -4 -3 — 2 -1 880 -857 6 c r,.- 161 555 544 342 550 21 2 343 -65 -(.7 229 -65 253 -69 177 258 220 360 291 -64 -63 4 32 355 -55 -5'i -53 -52 257 738 103 0 -51 385 H= n- 0 1 2 3 4 5 6 7 9 10 1 1 19 •18 -17 ■16 -15 -14 -13 -12 -1 1 -10 -9 -3 -7 -6 - 5 -4 -3 -2 -1 286 10 14 553 -59 -to 23 1 3t^3 -65 408 177 122 -7 1 97 102 245 1 05 -65 145 1 1'3 3C5 4 04 540 49 3 9 13 -53 4 lo -52 467 3J1 402 ■ 49cS -2 16 1 -54 1 -513 34 2 54 6 -214 -336 50 -60 -26 -24 4 18 -175 -274 239 37 1 -259 -8. -127 447 355 -32 -1 12 106 -10 -253 -695 -956 -; 1 37 4 _ 1 30 0 97t> 535 -95 19 206 333 25 -3*^9 - 104 1 17 108 -78 126 24 2 -107 -51 lo9 106 301 -3'-'l -530 47 0 G64 1 8 -416 -CO 521 356 -..11 -483 K— 0 1 2 3 4 5 262 490 20 1 2Cl -65 196 228 -487 -2CS lt>9 -oO - 19LJ 222 ro rc f o KC f u K. f U rc b -6o -59 -5 -61 36 -12 1 l« 106 ? 190 170 -4 -62 -69 -1 1 278 -28 0 -1 7 -o7 13 b 27 3 2H0 -3 1 liO -I50 -10 140 -105 - 16 '-70 -75 -19 1*3 9 -IhO -2 -04 -53 -9 2 to 2k5 -15 319 -322 - 1 l\ it.1 - ISO -1 2 Jo 219 -8 2 16 219 -14 -69 36 -17 1 .^H 173 -7 l«-9 - 193 -13 2 5^ 248 - Jo AO*; /.CA H = 7, K: -_ -3 -6 152 -14 1 -12 - 71 -35 -It. 2^7 2'>7 — 5 -67 -r\ -1 1 -(,9 -79 ~\t -^b 4 7 0 -c-7 53 -4 424 4 1 9 -10 -71 -44 - 13 A2S -407 1 2/3 269 -3 4i'0 433 -9 z:s2 249 -1? -1.2 -2 1 2 -05 -40 -2 344 -34 6 -1 1 1 '. L< 145 3 246 -237 -1 2 04 -21 1 H= 7. K = -14 -10 -09 -66 4 224 -218 -9 1^9 15(. 5 -70 65 H= 7, K^ =: 6 2 -71 1 10 -e A21 -30;' -2! -69 -84 3 2 1 6 I9« -7 197 19 1 — 2 •* 22 7 -24 9 0 -71 -1 1 4 -70 -71 -6 39 0 416 -lO 1 10 -83 -20 205 177 5 -7C - 1 31 -. *". -b6 -112 -in 1 1 5 1 18 -19 -67 74 6 1 14 -12.0 -4 7oa -700 -17 1-43 16 1 -18 220 -Z2J, 7 14 0 125 -3 128 -111 -16 ~oo -66 -17 -67 -60 a 25H 248 -2 20 3 DJO -15 316 -320 - 16 226 i.?..i 9 15-. - 156 - 1 150 Ki3 - 14 22 5 234 -15 -66 66 -13 4t4 4 1 0 - 14 95 42 H-. 7, K = -13 H- 7. K 1 -12 -63 34 -13 226 -33 0 -1 1 If 5 -170 - J 2 175 - 143 0 215 214 0 -C^ — 53 -10 -t.2 -4 -1 J 2J1 2''; 2 1 191 187 1 ?AiC 27? -9 ««v<; 4 35 -10 1 06 133 2 177 -171 ? -69 - 152 -8 330 323 -9 -68 -103 3 2 2 'J -239 3 23^ -??'. -7 16't 146 -8 242 -246 4 -65 -22 '4 120 140 -6 439 -439 -7 103 120 5 12 2 134 i> -6A 01 -5 155 -148 -6 1 15 88 6 -67 66 i -73 — ^ 190 183 10 2 75 -2t>5 -I 20 3 -21 1 -11 107 128 -7 -66 29 11 1 74 -1 70 -10 147 1 1 I — o 1 43 -1 76 12 305 295 H = 7, K 2 -9 215 -212 -5 -70 -7C -5 1 17 -1 16 -8 2<5 -252 -4 375 36 6 -4 203 -180 0 1 1 'i -93 -7 174 170 -3 122 155 -3 -69 49 1 32d -3 18 -6 I J3 1 09 -2 235 -241 -2 261 2-47 2 130 1?1 -5 -b6 -90 -1 132 136 3 1 e.i 190 -4 23* -?a 6 H= 7, K: = a < -6ii 47 -3 52tt -i2 4 H= 7. K. = -1 1 5 -66 -2 -2 I2S 136 -J9 -67 2 4 6 207 -20 9 -1 3^5 412 -18 156 -148 0 320 309 -20 260 ?-?4 - 17 105 -109 1 166 169 -19 -fj\ rs H- 7. K: 5 - It. -63 -69 2 3! 5 -280 -16 -66 -4 •;! -15 2 77 26 5 3 1 o9 -195 -1 / -eti -53 0 -6S -3 0 - 14 -te -38 4 152 174 -16 -65 8 1 —few «9 - 13 3C 1 -2v3 5 L>1 I 610 - IC 363 :?55 2 136 -2^Q -12 -62 A? -19 -u/i -27 -9 ltf5 - 182 9 -67 114 - 1 1 3t.o 37C -18 1/9 207 -a 3 »6 -^^z 1 0 -o5 1 12 -10 A36 404 -17 Z2d 2J6 -7 151 171 1 1 -04 2 -9 1 1 4 -97 - 16 23 7 -236 -6 222 2t.l 12 2 05 -202 -e 39 3 -175 -15 -oA -oO -5 1 19 1 1 3 13 2 37 -2«3 -7 231 21 0 -14 -t»a -5 -7 2 1 U -170 -6 AZ3 41 1 -13 25/ 22^3 H- 7, K: = 9 -6 -70 -58 223 FO FC FO FC FO FC FO FC -5 -66 0 -9 100 - 144 5 323 323 -1 1 4 30 -4 08 -<^ lO'i e« -e -65 -63 6 234 246 -10 185 -207 -3 -68 75 -7 232 239 7 2 80 -298 -9 .593 6;>.7 -2 297 -309 -6 23 8 273 8 339 -33 1 -8 207 204 -1 )<>6 -142 -5 217 -241 9 -66 100 -7 -57 -llO -4 235 -21 9 10 31 3 318 -6 54 0 -506 H= 7. K^ = -10 -3 243 24 1 1 1 - e4 -.12 -5 184 - 183 -2 233 237 12 -69 - I 1 0 -4 719 646 0 210 -237 -1 H..2 150 -16 127 -125 -3 361 36 1 1 1 1 0 -86 -15 121 -120 -2 1 0 L 0 ■ - 1004 2 -0 4 47 H= 7, K: -7 - 14 1 94 1^^4 - I 198 -166 3 219 21D -13 -65 2 7 4 K. 2 -133 0 171 186 -12 229 -235 H- 7, K -2 t> 7 6 5 -702 1 5 54 556 - 1 1 261 - 2 7 5 6 It, I -120 2 257 256 - 10 168 -16o 0 1 19 -91 7 320 34 4 3 259 -255 -9 299 318 I 143 -160 8 127 131 4 -62 74 -8 -62 -2 0 2 142 -147 9 -62 -■>e 5 2t.3 27 7 -7 2 94 -323 3 44 0 469 10 20 1 -193 6 -t.3 30 -6 "59 73 4 42/ 422 1 1 -64 -?7 7 200 -209 -5 1 73 17o 5 292 -292 12 325 331 8 404 -401 -4 4 68 503 6 138 -156 13 222 2?7 9 -63 64 -3 34/ 340 7 -6t> 85 -9 I9C -170 10 23 7 235 -2 421 -3^7 6 407 429 -6 -69 1 1 1 1 -63 18 -1 372 -357 9 125 1 10 -7 137 133 12 143 -137 1 0 207 -217 -6 130 G9 13 9 338 -2 34 3 34 9 -10 -65 46 2 -57 -34 -14 -65 -40 -1 149 137 -9 -64 69 3 103 123 -13 16o -173 -R 1 03 75 4 ?l 8 4 -12 179 -172 h- 7. K: = -^ -7 170 - 149 5 130 - 1 18 -I 1 46 1 457 -6 514 -513 6 220 -222 -10 3 55 353 0 141 1 1 9 -5 163 176 7 123 155 -9 628 -598 1 -64 92 -4 510 520 6 269 2t.' — V b -5 53 J 500 5 400 39 q 12 145 163 -4 228 -25 4 6 204 216 H= 7, K= = -6 - 17 133 -117 -3 583 -5&7 7 14 1 - 139 - 16 1 16 85 -2 357 374 8 116 - 1 06 0 285 -286 - 15 20 1 190 -1 593 595 9 -63 92 1 607 -626 -J 4 24i "251 10 34 3 356 2 138 129 -13 121 -119 H = 7. K = -1 1 1 -65 -37 3 485 477 -1 2 1 28 1-ia. 12 355 -402 4 -60 -46 - 1 1 £S1 fcCO 0 1 16 -119 13 132 -145 5 251 -248 ' - 10 3 4 7 352 I 45o 459 -10 -67 10 6 -o3 -55 -') 293 -247 2 334 315 -9 145 167 7 1 a 4 122 -e 1 13 -119 3 520 -533 -0 -64 13 8 313 315 -7 1 /2 125 4 129 - 104 -7 228 -22 3 9 140 -153 -6 3 IS 317 5 390 397 -6 290 -338 10 260 -277 -b 152 -122 6 152 145 ~" t> 1 08 12T 11 -64 67 -4 5 2 8 -535 7 310 -327 -A 27? ?72 1 2 194 180 -3 377 -394 8 358 -377 -3 99 -96 13 -68 92 -2 86 128 9 -c7 -21 -2 406 - 4"? -14 204 -207 -1 251 26t. -19 -6 7 42 -1 -63 -27 -13 212 -200 -18 208 219 -1? 188 170 H- 7, K: = -3 -17 -66 -1 5 n= 7, K = -e -1 1 -t)4 -9 -16 450 -44 1 -10 -67 -73 C 668 678 - 15 2 83 -275 0 loa -101 -9 -67 -70 1 161 2 0b - 1 4 -65 -6 3 1 216 -235 -8 24b -251 2 -57 -10 -13 2 5V 274 2 IOl. -7 3 -7 240 217 3 34.. -33 7 -1 2 -63 -53 3 193 167 -6 2rtj 272 4 2Ti -2c4 -I 1 661 -ti41 4 1 16 1 1 6 -5 356 -336 5 19 2 179 -10 -CO 6 5 123 -£4 -4 443 -423 6 133 1 16 -9 8C2 808 6 13B - 14 1 -3 303 -314 7 139 -113 -8 227 234 7 94 m -2 1 59 -121 6 -64 -5 -7 174 -158 8 347 379 -1 2'.6 250 9 1 10 - 1 13 -6 31S -326 9 -6b -1 Id 10 270 2t^ -5 171 -170 JO 236 -24 3 H= 7, K -5 I 1 222 213 -4 32 5 286 1 1 -63 42 -17 134 101 -3 107 103 12 -66 95 0 314 34 3 -16 3t.2 -35 0 -2 454 -5 -3 1 1 1 101 0 1 Af> 15 1 -5 lb6 -163 -Ij I 10 -100 9 •172 -148 0 1 2 -66 -6 6 -119 - 2 3 7 90 -4 -3 -2 3 96 -67 J 59 -400 -61 349 -1 H- -t7 e. K= -16 6 10 1 1 -4 1>:tO - 6l< 2C5 - 1 Ct, 78 -212 3 A b 6 - I V r-9 1 -Ot 17t. ?6 0 1 1 -» 8 200 187 -10 -e>6 0 4 1 39 1 2 5 -I 'J ~1 1 - 1 0 —6 i> -'>■/ -! 7 -66 5b -9 136 -138 5 3C6 309 IM 1 0 ii lis -1 6 1 06 -185 -e 99 -69 6 -^4 -48 -6 3 -I "-> -66 -1 03 -7 -65 60 7 27? -Zu3 —9 329 - ?.o2 -1 4 192. 105 -6 220 ?it, 8 1 32 - 1 20 — 6 2t/6 -302 -13 1 7r, ?;9 -1 1 -10 29i> 217 -27 1 -2C I ^ ^ -69 1 1 1 -7 -60 Ibl — 49 -166 -3 -2 46 1 1 1 I 26 1 - 4e? - 127 ?t>6 -9 -H -7 284 27 0 398 20 7 24 9 -<09 H- -1'1 0, K^ 199 7 20< -6 -5 -4 -69 -68 235 -29 81 232 - 1 336 342 -6 322 -323 - 17 -69 -43 ^ t -LI 59 -5 2 8'+ 2fi2 - 16 24 1 -212 -2 -68 - 1 4 7 ^<= 8i K- 1 -4 157 144 -15 271 -272 -1 -66 7 -3 -^6 33 -14 -66 12 0 265 256 -2 371 -370 -13 295 293 H = 8. K- -- -10 1 2 3 2'jO 199 251 286 - 196 -26 2 -1 3i:7 8. K- -323 = 4 -12 -I 1 -10 -6^ 24 J -67 10 -222 -66 0 1 216 137 -228 -111 4 5 209 -76 20 3 0 -60 -78 -9 -8 -67 210 99 222 2 3 2 32 170 -229 192 - ly -la -1? -16 - 15 - I A 133 168 219 163 3'tb 364. 13? 1 '. 6 20S - 199 -?42 344 1 -?0 -1 9 -\ ^ -! 7 -16 -69 212 -67 271 -65 1 13 - 1 197 43 -26 2 -55 76 -7 -C - -.5 -70 259 e. K= 217 -64 -258 8 240 4 5 6 7 8 9 1 Oo 1 13 151 210 133 100 - 1 16 -113 142 228 126 -95 - 1 3 197 1 8 7 -15 -65 - 4 -14 131 - 1 A 0 10 1 CiO -165 -12 - 1 1 124 -63 -123 -16 -1 4 -13 -m4 -72 -139 - 13 - 12 2'.2 I'-e -264 141 1 1 12 -68 3 74 43 3 36 - 1 0 SB 24 -12 -6b 9 - 1 ' 1 ■. 2 122 -3 -69 73 87 41 -9 21B 266 222 2 5 6 -1 1 -10 3^2 346 90 -16 -70 21 -7 -6 -67 -65 -7 — 6 1.-8 96 - )'. I -98 -9 -3 26<' -239 -At) h = 8. K.= = -14 -5 -4 -64 160 -3 -164 27 -b 31 I 20 1 -7 234 228 4 121 -101 -3 -63 - 4 436 4?3 -6 -Ob 64 5 159 - 157 -2 2 20 2 '^ */ -3 ir6 7 2< 1 -5 -6o -5S' -1 129 -121 -2 169 - 197 -4 13:^ - 120 H = e» K: = -13 8. K = -9 - 1 423 -42 7 _ 1 129 -134 H= -2 3»c5 2u^ 0 2 CO 26 4 H = 6 1 K = 2 -I -ij7 1 1 1 -69 23 0 -67 130 2 1'..4 - 1/7 1 263 27 2 0 1 2 306 31 7 -66 -297 -328 PO -?0 8. K. 174 = 5 - 134 3 4 5 -65 -67 237 8 72 230 2 3 4 21 I -67 484 -218 -OO 471 3 20 1 IRQ -I -3 -fjO -1-1 6 -It a -43 5 379 383 -127 4 10 1 QO -1 8 273 272 7 226 -216 6 1 14 -20 -7 I 124 -17 -6b 74 8 -70 -00 7 202 - 193 -19 -60 -6 3 -1 6 — Ob -4:J 9 296 2 73 8 -62 -51 -16 -17 - 16 223 2f,b 22b -23 1 - 2 :■ 2 24 3 -! 5 -1 4 -13 186 -t>4 Ibl -179 30 153 -1 -69 fc. K 5 a ^ -12 9 10 1 1 -66 - 174 125 95 loa -13A -325 - 1 5 -t>3 1 7 -12 -(>4 22 12 32C - 14 2B4 -27 t -1 1 213 -232 0 134 - 1 J8 -10 -65 52 - 1 3 27 1 -2f 7 -10 -C4 18 1 -66 -10 -9 1-4 143 -1 2 -65 fiP. -«v 2tjt- 255 2 -65 31 -6 -C6 -5 - 1 1 1C9 53 -8 1 1 o 140 T 27 1 25 1 -7 -66 -20 - 1 0 21 e 223 -7 155 - 170 4 -67 -13 -6 -G4 -2 -9 167 - l'^5 -6 172 -187 5 395 -39 7 -5 122 132 -8 262 -25 1 -5 -o7 -72 6 213 -ie7 -4 257 Zb3 225 FO FC FO FC FO FC FO FC -3 209 -?\ 1 -10 -63 52 5 441 4 39 -5 -59 -40 -2 2? 3 -26tJ -9 256 -253 6 -66 77 -4 244 223 -I -Of. e7 -r :'k'5 - 1 9 J 7 131 -124 -3 *-6 0 0 - / J63 35 0 8 Wil - 144 -2 305 -294 H= e, K: = -8 -6 134 134 9 -68 104 -1 192 -186 -G 2 J 5 -;'4;, -1 7 312 -30 3 0 309 -314 -4 2'.. 9 -229 -16 294 -297 h- 9. K.: 0 1 27 7 -278 -3 -63 ---l - 1 5 -c6 79 2 570 578 -2 2 3': 209 -- 14 2'(i^ 236 0 172 -185 3 274 264 -I a9 133 -13 -e 4 28 1 199 -198 4 216 -244 - !2 ?12 -302 2 102 IOd 5 3tS7 -348 H- 8. K: -5 -1 1 420 -'J 09 3 29 9 315 6 -t.4 -26 -10 -6* -73 4 -68 -10 7 27/ 280 0 MO 172 -9 56 3 549 -18 -o7 -33 6 236 247 1 -61 25 -8 -6 1 43 -17 -66 -6 9 -6iS -77 2 96 -95 -7 2 53 -268 -1 6 169 155 10 277 -276 3 403 -&0 7 -6 1 10 - 121 -15 -t.6 133 1 1 -£>7 15 4 -Cn -139 * ^- 1 7ii 196 - 14 4! 3 -4 1.2 12 220 2cq 5 32 i 33 6 -4 7? 7 71V -13 368 -34 3 -12 16t> 3 67 6 -04 2 a -3 2 55 -262 -12 2 54 22 1 -1 1 155 168 7 33 3 -338 -2 875 -887 - 11 22 7 220 - 10 -6'j 0 8 247 - 2 3 H - 1 -to 20 -10 96 -113 -9 -06 -122 9 177 190 -9 214 -2G1 -8 -64 -e,p. 1 0 -67 C9 H- 3, K: r —2 -8 -65 -53 -7 -6 3 30 I 1 99 17 -7 458 4 63 -6 -66 101 -15 1 19 -91 0 -63 73 -6 303 295 -S l&l -161 -14 212 201 1 170 -186 -5 373 -364 -ft 313 -321 -I 3 l4o 123 2 9 5 -34 -4 -66 57 -3 -64 -33 -12 -64 -IV 3 510 507 -3 349 334 -2 lJt4 180 -I 1 -65 -19 4 160 - 1 7 6 -2 296 293 -1 146 139 -1 0 -66 59 c ^ 13 -4 13 - 1 -66 29 -9 34 0 336 e 1C6 -51 H = 6. K: - -7 -•3 -64 1 1 7 164 iho H- 9, K= 1 -7 4U7 -464 B 210 203 0 434 4.4<) -6 191 -203 - 18 Z24 -203 0 2'; 6 247 1 470 AS 5 -5 3 76 392 -17 -69 7 9 1 22 5 189 2 514 -5! 1 -4 4 76 494 -16 1 SO 156 2 1 79 -176 3 29 4 -?S? -3 1 13 9 9 -1 5 -e", -29 3 257 -254 4 137 -t?5 -?. -60 7 - 14 4 02 -412 -19 -68 34 5 -6 6 10? -I 2 7y -27 1 - 13 2f 6 -30 2 -16 133 134 6 126 136 - 12 2 74 i49 -17 -67 34 7 27 1 -29 2 h~ 8. K: :: -4 -I 1 6^12 658 -16 416 -44 2 e 444 -440 -10 -63 9 -1 5 -64 -24 9 -66 53 0 398 -40 2 -9 6 92 -7 04 - 1 4 172 167 10 423 429 1 222 -217 -a -60 -34 -13 -64 -43 1 1 -67 -12 2 -62 6 -7 1 16 123 -12 201 -194 -13 1 1 1 11 1 3 50 5 505 -6 343 323 -1 1 154 -165 -12 l'-.4 -151 4 -65 68 -S -S'i -54 - 10 103 37 -11 171 -167 5 261 -26 7 -4 £26 -814 -9 367 364 -10 -63 36 6 -65 24 -3 191 -232 -8 269 26 6 -9 170 l°i?. 7 314 315 -2 56 9 £94 -7 412 - 4 r< 8 -8 192 les 8 156 134 -1 -61 0 -6 186 - 175 -7 3^17 -363 9 216 -216 -5 -67 3 2 -6 46 7 -4^7 I 0 -6o -97 H= e, K- = -1 -4 -68 -ei -5 212 224 -16 2i'.« 292 -3 -66 61 -4 -64 59 -15 -o6 31 0 -6 3 -18 -2 275 -280 -3 20 4 -19f- -1 4 -t<» -8J 1 3i.'2 39 7 -1 -65 6 -2 145 -l 0 360 -360 -8 -65 -35 7 . 1 "iO -114 -19 IC4 -4 1 -62 -<:■. 7 -7 5^5 553 & 254 -254 -18 2 74 -29 4 2 1 73 1£3 -6 41 I 39 6 -19 -71 77 -17 -66 26 3 297 301 -5 -59 -44 -la 126 143 - i 6 264 2^ 1 4 2fc8 ?Sfl -4 359 -35:: - 17 -t 4 2 - 1 5 1 C4 91 5 132 -139 -3 161 - 143 - 16 t:'6 -126 -14 166 -164 6 196 -ISA -;> 317 313 -15 167 - 1 3 4 -13 150 -131 7 2b9 276 -1 I 74 150 - 1«» « 17 439 - 12 114 124 8 ?ti4 781 -13 2£3 254 - 1 1 168 159 9 -67 _oi H= 8, K.: : -3 - 12 1 1 7 - 1 15 -10 -66 67 10 24 2 -238 -1 1 3 23 -319 -9 459 -4 55 1 1 -66 2 0 24 0 238 -10 43^1 447 -8 -66 -85 -14 IV5 -208 1 156 130 -9 604 607 -7 4 52 459 -13 -69 -106 2 -63 39 -8 PJO 230 -6 226 227 -12 109 I Of. 3 325 -325 -7 1 74 - 180 — 5 -66 25 -11 152 163 4 172 -145 -6 4 94 -454 -4 -66 -w9 226 FO FC -3 2'';4 -257 -2 2'->3 ?4f -I -60 3 3 i~ V. K = 3 0 23ti 23 5 -I'V -69 b? -10 240 ?by -17 -OC -42 -If. 169 -Mi7 -If 1 SO -146 -I* 2Z0 21 3 -13 24 e 26 e -12 -64 -0 3 -11 23.1 -22 4 -10 102 -69 -9 162 206 -6 -60 b? -7 203 -224 -6 2b 4 -?;»e -5 1 09 -39 -<, 352 3'^3 -3 yi 9 224 -2 2 77 -POb -1 100 -7 b H= 9t K = : 4 -19 -60 -43 -IP. 26 4 - 27 3 -1 7 -o6 7 -16 177 16-^ - 15 i;-2 I ft 0 -I'* 24 9 -24 e -13 24 2 -262 -12 -04 eb -1 1 229 ?'«■• -10 19 2 175 -y -68 - 12 1 -r. -t-b -R -7 173 170 -b 196 20C -S -66 16 -4 383 -395 -3 102 -^•i^ -2 171 172 H= 9, K= = 5 -18 276 2ec -17 -6a 27 -16 U.b -15b -lii 1 lO -91 -14 162 lb7 -13 2 7 c) ?P0 -12 -67 -60 - I 1 375 -37? -10 -uo -4 -9 21 b 214 -e -f,l\ 6 2 ~7 137 -122 -6 2b 1 -240 -5 -69 ?G -A 31b 5C1 Yi~ 9, K 6 -17 -70 F4 -16 -68 IP -15 -67 4 '5 - I* 160 - ! S - -13 232 -247 -12 1 1 3 I t I - I I 24 U 2b3 -10 107 -e 1 -9 176 - 14S -8 186 -165 L -7 0 1 2 3 4 5 6 H- 0 1 2 3 4 5 6 7 e -3 -2 -1 l< = 0 I 2 3 4 5 6 7 9 -6 -5 -4 -3 -2 - 1 i-'- FO -71 1 66 -69 -6 6 2 03 Itu 19 1 -6jJ 0 1 2 3 A 5 6 7 8 9 1 0 -fl -7 -6 -5 -4 «_ -» -2 -1 H = ^v- 0 1 2 3 4 b 6 7 1 06 -f-j 317 leo 314 205 103 164 -Of ICO 245 -6e 126 1x39 21 4 -C 3 220 242 -60 220 -66 1 I b -67 -6 b 197 1 14 239 144 FC 04 -13 201 -bl -"• I •176 IP 9 i'.. ' -Itl -12 - 159 -14 5C1 169 -294 -231 CI 16 1 13 155 24 5 -1 06 -1 1 126 -131 -214 -1 "j 207 222 - 109 -210 120 -12 75 ie9 - 1 4B -261 124 K= - 10 130 274 214 424 -64 2 74 -68 252 -64 127 209 -68 -67 145 159 323 1 ;* i 16b -o6 9. !■ IC 1 233 lyO 2 6-1 -Ci* I s.> -(.2 206 66 -273 20 3 423 13 -267 66 25 1 45 - 136 -191 -3 90 143 -138 -3 39 170 194 - 133 C= -9 92 23b ■201 ■ 27d -20 1 C: 1 -2 2 ■195 O 9 1 0 - 10 -9 -0 -7 -6 -4 -3 -2 -1 n- 0 1 2 3 4 5 6 7 ti 9 10 - 1 1 -1 0 — V -8 — 7 -e -4 -3 — ic - 1 H= 0 1 2 6 7 8 9 -13 - 12 - I 1 -10 -9 -a - 7 -6 -5 -4 -3 -2 -1 H = 0 1 2 3 4 5 6 7 6 9 - 14 FO 145 136 ?0b 1 1 2 136 -67 175 ; 19 - 66 145 222 -64 -64 K- 370 -es 16 -532 -1 19 K = 221 305 214 267 -to 306 161 2 70 101 -<.d -69 164 214 160 -65 1 fib 4 50 -66 3 7b 10 1 -63 35-. -04 420 201 C 1 2 3 4 5 100 219 1 bfa 5cO 162 563 ■209 •3C3 225 265 I 19 -296 -171 234 138 -8 -3b -1 bt, -?.■• 0 209 67 -205 -4V6 43 3< 9 -122 -7a -358 -56 4 1 I -199 K= -3 135 204 •143 ■dSO 163 560 227 FO » C FO FC FO FC FO FC 6 7 -17 -If. -11. - 14 -13 -12 -1 1 -10 -9 -8 -66 179 -67 -63 1 1^^ f.7 - 1<^>5 - ia7 -7 7 l!f.9 ? -17 -16 -I -J - 14 -1 3 209 -60 231 -6o 3 9-> -6b ?2'i -29 24 9 -3 4 -3r-0 -69 -16 -15 -14 - 1:; - 12 233 -OS -69 -te 100 224 28 -125 -112 119 -4 -66 -3 184 -2 162 -1 -64 H= 10. K= 43 -21 1 -1 7? -58 -6 1?7 IbO -66 2b4 /.bl IGO 107 - 186 -f 4 25 0 4'.; 7 - 172 -12 . -1 1 -10 -9 -a -7 19'. 160 -63 1 59 -65 357 169 155 22 -182 -7 7 3/B -1 1 -10 -9 -8 -7 -6 2G7 -67 223 -67 -6b 173 310 -47 -237 -42 51 216 0 1 2 3 4 5 352 -64 328 2 56 -65 298 -36 0 -70 3ft 1 254 -30 -29 1 -7 -6 206 105 -196 - 164 -6 -5 l'^'. 236 1 2a -24 1 H= 10, K= 5 6 7 -66 310 -18 31 1 -5 -3 . -?. 244 662 464 53t> 226 646 -472 -526 - 4 -3 _ 2 -1 253 -65 33 1 - 67 — 2£' > -55 336 5 - 14 -13 -12 — 1 1 1 11 ia3 2C9 241 101 157 -201 -^3 1 -10 -9 -8 -7 159 145 160 355 -159 -151 13d 362 -I -04 1 6 li= 1 10. K= 1 -10 -68 66 -e -5 -66 272 -30 -266 H- 0 1 3 4 9, K = ?*5 2 J O 39 1 269 475 : -2 -240 -227 3f43 2f50 -467 0 -17 -16 -15 -14 -S3 269 -67 l7o 2 82 24b 99 27 4 -7 2 -131 2 06 252 1G4 C 1 2 3 10, K = 123 -70 226 -69 -12 -106 100 22 8 -10 -4 -3 -2 -1 154 -64 2 53 -66 10, K= -181 15 249 ' -103 1 -7 5 6 356 -6 9 -37 8 -38 -12 -1 1 212 312 -225 -297 4 -1 207 -70 -199 -106 0 1 335 262 360 261 -17 -16 -6 9 136 120 1^.6 -1 0 -9 -•62 4 03 414 -6 -431 -2 1 226 349- -44 -273 -28 2 184 17S H= 1 0 . ■ K= = -11 2 194 241 -190 -259 -15 -1'. -13 -12 -11 -10 -9 -e -7 -6 -5 -* -3 -O'-i 131 209 3rji 109 193 Ztt- -64 233 339 41 I b92 b02 67 -135 199 34 3 130 - 163 -30e 65 226 323 -ii-SO -617 «97 -8 -7 -6 -5 -4 -3 -2 -I \'.~ -17 -16 - 6 h 4'; 5 -65 230 357 -67 271 -67 10. K= 101 17? 0 1 2 3 4 5 6 -5 -4 -3 -2 -1 -68 -69 1^3 It 4 233 Its -7 0 122 -6'i 136 l-i2 121 79 9 -150 -174 219 167 -107 124 69 -148 - 137 80 4 5 6 7 -12 - 1 1 - i 0 -9 -8 -7 -6 -5 — 4 -63 3 19 1 13 32 3 153 -66 i o6 216 -67 426 -67 1V3 94 23 3 19 67 -310 -130 41 i -^S 21 1 -83 -441 -103 203 I 13 -2 -1 H = SCO 21 0 9 1 K 49 3 217 - -1 -15 -14 -13 -1 2 217 2fc>6 97 21 » -206 -30 6 -8 9 247 0 10. K: 279 = -10 -282 -3 -2 - 1 -64 3 06 -67 -e -310 136 — 1 1 298 30 'J I ie9 - 160 0 405 3?i; -10 16S) -176 2 256 323 137 -277 -59 86 -9 136 28 -199 —72 H= 10, .< = -6 1 2 3 A 5 -IS -1/ -16 125 I5fc 202 123 36 3 134 -67 I 12 -347 -230 104 350 II 0 -'i6 -13 -9 -8 -7 -6 -5 -4 -3 -2 420 -6tt 359 -66 99 318 -68 190 -404 1 IS 333 58 -95 -300 eo 164 3 4 t> 6 7 -7 -6 — 5 -4 -3 -1 173 2^2 -66 -67 -67 1 13 -68 170 — 67 0 1 2 3 4 s 6 7 2 3o -63 115 -63 -67 3ca -63 274 -229 -23 129 50 -78 -31 1 -70 279 -113 -14 -13 -:2 I 17 in -65 179 134 K 0 - 1 i^ -^^ »- = -17 10, K 176 3 -174 3C6 -67 -65 218 82 -46 - 13 -12 -1 1 — 1 0 96 -66 1£5 — OD 55 51 125 -33 - 1 » - 10 243 -66 -24 1 102 -16 -15 2'. 4 -66 -243 61 H= 10 . K - -9 -9 -a -7 -6 -5 -4 -3 267 -65 -265 38 -9 -ft 264 -63 261 -33 -14 -1 3 2Cfi -66 209 75 0 268 288 2 9 5 -t>4 179 • 163 160 294 — 45 -7 -c -4 31 rt 164 427 31 0 -31 3 - 1-4 4 417 337 -12 -1 I -10 -9 243 202 -65 34 f} -250 -2A8 53 356 1 2 3 4 -44 360 156 266 6 -36 3 - 1 6 7 2i..D -20 1 -164 154 5^2 -TO ^ 1 496 -4 90 -3 147 146 5 103 1.^2 — c -I -2 402 -3<^6 -7 22 2 -225 6 -67 88 — Oo -I 227 -r24 -6 -5 134 1 14 -149 I 1 0 7 -9 127 159 - ICO 16C H= 10. K := -5 H- 0 1 10. » 295 214 0 -?<;9 -202 -4 -3 251 -70 10. K 248 -15 ;= 4 -8 -7 -e -5 -69 146 -68 342 4 - ice 6 342 0 1 2 220 138 lt;7 236 -159 -206 228 3 4 5 6 -1'. -1 J -I? - 1 1 -10 -o -8 -7 -t> -'o -A -3 -2 - 1 M = 0 1 ? 3 A 5 O -J t - 1 A - 1 3 -12 - I 1 -10 -9 -8 -7 -6 -0 -< -3 -2 -1 H = FO I I 0 I VO 30^ -h7 101 -ao 20B -ts 13U 3;.'0 ?4«y 273 37 1 106 10, K- 0 1 ? 3 A 'J, -16 -lb - lA -13 - 12 -I 1 -10 -s -e -7 -6 -b -4 -3 -2 -1 336 -6* IVb 293 1 VI 3C.tJ lb2 -6« -67 -C.6 2a 1 133 94 21 6 lt.C 260 1^7 1 09 -66 bC9 -66 320 1 0, K: 2 74 1 16 309 27 9 360 2b3 -66 -66 178 -6b 34b -65 2b7 ~64 -65 -64 23ti -66 b0 2 1 1 0 2 J 2 PC • i:.o 14Q 31 3 -VO 7 9 1.5 -ro I - 160 ri9 I'iO -104 -323 4 1 26? 26;^ -39 0 - £> R 6 IVAi -A -3?f. v3 196 298 -U b - 374 14C -30 -1X3 -12 2H6 124 ~':-2 -235 130 24", - 1 1 'i 20 6 5 517 6 9 -310 -3 273 1 1 4 -3! 5 -27 3 374 274 -35 35 187 44 -330 -04 246 194 1 A -7 0 4 I 21 3 — 44 -435 - 1 25 19 2 10. K = 0 I 2 3 4 •16 15 186 133 262 -69 IbV 142 -66 -20 I - 1 01 2^5 81 -205 112 94 •I 4 -1 3 ■12 -1 1 -1 0 -Q -3 -7 -6 -5 -4 -3 -2 -1 FO -67 -61. 1 72 -t-J 161 -64 95 227 134 120 108 1 1 I 97 -64 FC -17 • 5 3 1U2 17 -205 -b4 8b 2~^0 14 1 -131 -i;'3 106 106 -4U H= 10. K = - 1 0 1 2 3 -t 7 -16 •1 5 -14 -13 -12 -I 1 -10 -9 -8 -7 -6 -5 -4 -3 H= -15 -14 -1 T -12 -1 I -10 -9 -8 -7 -6 -5 -4 -3 -2 32.5 245 2 59 247 -6 b 22 1 267 167 148 2 y t- -C.3 1 4o 1 2ci -64 32 b 297 2:<3 109 2d 1 91 337 242 -266 ■24 9 -16 -208 -282 176 164 - 266 -64 140 1 1 1 -26 -326 -301 220 I 10 121 -267 -4 1 1 K = -1 5 -14 -1 3 -1? -1 1 -1 0 -9 -R -7 -6 -5 -4 H- -15 -14 -t 3 -12 -1 I 104 2Cd -CO 169 1 4 9 1 1 7 2 55 -65 277 -66 127 100 130 131 11. K -6 6 -67 -66 1 1 5 26J 22 0 257 -67 l-jl -or 1 30 1 12 -86 -ins 54 176 l'<7 -127 -276 17 275 94 -112 -140 129 150 28 74 -29 -152 -254 220 239 -85 -182 -56 146 144 1 1 K = 1 3 4 ICO 1 1 0 1 6 9 ^4 3 •136 I ! 4 -113 1 43 222 I. - 10 -'> -H -7 -C \ •■ -13 - 12 - 1 1 - 10 -9 H-- FO 1 89 140 1 04 202 -69 1 1 K = I 75 192 233 1 5-; 1 V7 1 1 K 0 16U H- 11. K= 0 1 2 3 -4 -3 ^ r - 1 0 I 2 3 4 -7 -6 -5 -4 -3 - T 0 1 2 3 4 -9 -a -7 -0 -5 -4 -3 - 2 - 1 Z->7 -1,1 220 -69 293 -V J 340 140 124 FC U 8 119 109 198 6 1 169 ■; 15 -116 153 1S6 - 1 1 18^ -10 -269 -31 332 7C -263 -2 31 1 147 -141 - 2 - 1 FO 1 03 2 35 H= M 263 -06 2i)H -66 220 255 -69 199 147 254 ie2 140 H= 1 1 28 7 -68 203 - tb 161 1 44 171 123 196 152 1 19 30 7 101 214 250 3 0 •3 04 2 5 208 -244 IOC 192 -lit. -255 ■ 193 143 K- -8 ■287 102 213 -35 • 152 -133 190 1 lo - 194 -147 1 1 7 302 117 -2C4 M- 1 1 0 1 2 3 4 -1 1 -10 -9 -8 -7 -6 -S -4 -3 35^^ 148 22Z 159 -70 -69 143 216 266 216 121 126 -es 119 35 C -147 -233 - 1J7 a 1 -9 1 13U 203 -273 -21 6 90 124 -1 1 - 143 h= 1 I . K- 0 1 2 3 4 -J 2 - 1 1 -1 C -9 -8 -7 -6 -5 -4 -3 _ -^ -1 H- 0 1 2 3 -13 -12 -1 1 -10 -9 -y -7 - 6 -5 -4 -3 -2 - 1 3 < ' 6 -66 132 222 -70 131 IS'* r0 2 1 C4 ir.t) 198 127 -65 13b -67 134 2 4 5 n . K 264 134 -69 -174 -6 6 -1 1 1 14 1 14 -2 -1 J F.O 197 145 -216 -7 -6 222 1 10 -24 9 84 -66 233 -67 20b -40 -246 -?? 303 -10 -9 -0 20 7 230 10 1 -213 -203 102 H = -1 1 12. K- -67 - -5 -38 -5 -4 -3 -2 223 -67 123 167 225 23 - 1 5 1 -148 -1 1 -10 -9 -e -7 -fc -5 -« -3 -2 -1 -66 2b9 -9 --3 2 - 2r 4 0 12c K= 172 ■ -8 - 199 -IC -9 -e 211 -66 142 21 b 15 - 137 H= 12. K= -2 -c'3 27 1 - t,7 Ci02 -66 199 -60 -6,. -78 274 -5 1", -6 -5 -4 -6H 149 1 20 -25 -150 -138 -7 -6 -5 106 1 4? 293 -66 J20 2i.7 -12 -1 1 -10 -70 -60 1 14 132 60 -02 -«og -6? 194 35 7 -3 -2 -1 -66 160 1V4 12. K: 93 143 -161 -- -7 -4 -3 -2 -1 H = -69 208 1 17 217 12. K= 60 -233 -157 229 -4 -9 -a -7 -6 -5 -4 183 103 27 0 120 210 1 10 -201 1 16 302 -81 -219 -101 H= 1 ! . K: = -I 0 -6 146 155 122 - 143 -1 1 -69 -25 H= 12 , K^ -1 0 -1& -14 -13 -12 -11 — 10 35b 162 377 -70 2S7 -66 -60 352 136 37 5 -115 -2nfj -68 94 -7 -6 -5 -4 -3 -2 -1 130 -69 26 4 119 210 132 177 -134 60 27 9 101 -236 - 11 9 191 -10 -9 -8 -7 -6 -4 226 -66 -65 150 -67 153 103 -235 -75 26 176 42 -158 -6b - 12 -I 1 -10 -5 -8 -7 165 97 193 201 127 213 -152 -103 185 220 - 129 -214 -9 25 e 301 -3 177 147 -6 -67 4C> — C -6A -1 4 H = 12, K: -6 -2 1 1 1 14 1 -7 30 1 - 2Ut . -1 IbO - 1^4 REFERENCES 1. W. P, Jencks, "Catalysis in Chemistry and Enzymology," McGraw-Hill Book Company, New York, 1969, p 1. 2. G. N. Schrauzer, "Advances in Chemistry Series," No. 100, R. F. Gould, Ed., Am. Chem. Soc . Publications, Washington, D. C. , 1971, p 2. 3. W. P. Jencks, op. cit . , pp 393-436. 4. W. Kauzmann, Advan. Protein Chem., 14_, 1 (1959). 5. A. E. P. Watson, I. A. McLure, J. E. Bennett, and G. C. Benson, J. Phys . Chem., 69^, 2753 (1965). 6. R. Murray and D. C. Smith, Coord. Chem. Revs., 3^, 438 (1969). 7. R. W. F. Hardy, R. C. Burns, and G. W. Parshall, "Advan- ces in Chemistry Series," No. 100, R. F. Gould, Ed., Am. Chem. Soc. Publications, Washington, D. C, 1971, pp 219-247. 8. T. L. Cairns, V. A. Engelhardt, H. L. Jackson, G. H. Kalb, and J. C. Sauer, J. Am. Chem. Soc, 7_4, 5636 (1952) 9. J. C. Sauer and T. L. Cairns, J. Ajn. Chem. Soc, 79 , 2659 (1957). 10. P. Heimbach, K. J. Ploner, and F. Thomel, Angew. Chem., 83, 285 (1971) . 11. A. J. Chalk, J. Am. Chem. Soc, 94_, 5928 (1972). 12. G. M. Whitesides and W. J. Ehmann, J. Am. Chem. Soc., 91, 3800 (1969) . 13. A. v;. Parkins and R. C. Slade, J. Chem. Soc, Dalton Trans. , 1352 (1975) . 14. R. H. Gastinger, M. D. Rausch, D. A. Sullivan, and G. J. Palenik, J, Am. Chem. Soc, in press. 15. M. D. Rausch, private communication. 230 231 16. Chemical Abstracts, 49_, 76C6e (1955). British patent no. 707337 (1954) . 17. A. Ablov, Bull. Soc. Chim. Fr . Mem., 1_, 151 (1940). 18. D. G. Batyr, M, P. Starysh, V. N. Shafranakii, and Yu. Ya. Kharitonov, Russ. J. Inorg. Chem. , 11_, 1728 (1972). 19. K. Nakamoto, "Infrared Spectra of Inorganic and Coor- dination Compounds," 2nd ed . , John Wiley and Sons, New York, 1970, pp 230-232. 20. A. Nakahara, J. Fujita, and R. Tsuchida, Bull. Chem. Soc. Japan, 29^, 296 (1955) . 21. Y. Yamano, I. Masuda, and K. Shinra, Bull. Chem. Soc. Japan, 44^, 1581 (1971) . 22. J. Loliger and R. Scheffold, J. Chem. Ed., _49, 646 (1972) . 23. D. F. Evans, J. Chem. Soc, 2003 (1957). 24. P. W. Ball and A. B. Blake, J. Chem. Soc. A, 1415 (1969) 25. M. J. Buerger, "X-Ray Crystallography," John Wiley and Sons, New York, 19 42. 26. M. J. Buerger, "The Precession Method," John Wiley and Sons, New York, 1964. 27. George H. Stout and Lyle H. Jensen, "X-Ray Structure Determination," The Macmillan Company, New York, 196 8. 28. C. V7. Bunn, "Chemical Crystallography," Oxford Univ. Press, London, 1961. 29. H. P. Hanson, F. Herman, J. D. Lea, and S. Skillman, Acta Crystallogr. , 17^, 1040 (1964). 30. R. F. Stewart, E. R. Davidson, and W. T. Simpson, J. Chem. Phys., A2, 3175 (1965). 31. P. A. Doyle and P. S. Turner, Acta Crystallogr., A2 4, 390 (1968) . 32. A. J. C. Wilson, Nature, 150, 152 (1942) . 33. A. J. C. Wilson, Acta Crystallogr., 2, 318 (1949). 232 34. M. J- Buerger, "Crystal Structure Analysis," John Wi- ley and Sons, New York, 1960. 35. E. B. Fleischer, R. B. K. Dewar, and A. L. Stone, pri- vate communication (1966) . 36. Robert B. K. Dewar, "Use of Computers in the X-Ray Phase Problem," Ph. D. Thesis, The University of Chicago, 1968, 37. R. A. Day, Jr. and A. L. Underwood, "Quantitative Ana- lysis," Prentice-Hall, Inc., Englewood Cliffs, N. J., 1958. 38. K. Burger, I. Ruff, and F. Ruff, J. Inorg. Nucl. Chem. , 22, 179 (1965) . 39. G. Cost