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Full text of "Scientific Papers - Vi"

1918]
PROPERTIES  OF  THIN  OILY  FILMS
539
takes place entirely as before. But the drop remains upon the water as a lens, and flattens itself out, if at all, only very slowly. Small admixtures of the original oil with the purified oil behave in an intermediate manner, flattening out slowly and allowing the beautiful transformations which follow to be observed at leisure.
Another point of importance does not appear to have been noticed. Water-surfaces on which purified olive oil stands in drops still allow the camphor-movements. Very small fragments spin merrily, while larger ones by their slower movements testify to the presence of the oil. Perhaps this was the reason why in my experiments of 1890 I found the approximate, rather than the absolute, stoppage of the movements to give the sharpest results. The absolute stoppage, dependent upon the presence of impurity, might well be less defined. 
If, after the deposition of a drop of purified oil, the surface be again dusted over with sulphur or talc and then touched with a very small quantity of the original oil, the dust is driven away a second time and camphor-movements cease.
The manner in which impurity operates in these phenomena merits close attention. It seems pretty clear that from pure oil water will only take a layer one molecule thick. But when oleic acid is available, a further drop of tension ensues. The question arises how does this oleic acid distribute itself? Is it in substitution for the molecules of oil, or an addition to them constituting a second layer ? The latter seems the more probable. Again, how does the impurity act when it leads the general mass into the unstable flattened-out form ? In considering such questions Laplace's theory is of little service, its fundamental postulate of forces operating over distances large in comparison with molecular dimensions being plainly violated.
OP
ncf her really valuable work. It is the second kind of spreading in a thicker layer, resulting in more or less rapid subsequent transformations, which is attributed to the presence of oleic acid. Miss Pockels says : " The Provence oil used in my experiment was shaken up twice with pure alcohol, and the rest (residue) of the latter being carefully removed, a drop of the oil was placed upon the freshly formed water-surface in a small dish by means of a brass wire previously cleaned by ignition. The oil did not really spread, but after a momentary centrifugal movement, during which several small drops were separated from it, it contracted itself in the middle of the surface, and a second drop deposited on the same vessel remained absolutely motionless." I have repeated this experiment, using oil which is believed to have come direct from Italy. A drop of this placed upon a clean water-surface at once drives dust to the boundary in forming the mono-molecular layer, and in addition flattens itself out into a disk of considerable size, which rapidly undergoes the transformations well described and figured by Devaux. The same oil, purified by means of alcohol on Miss Pockels' plan, behaves quite differently. The first spreading, driving dust to the boundary,