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THE
ELECTRICAL CONDUCTIVITY
AND
IONIZATION CONSTANTS
OF
ORGANIC COMPOUNDS
A bibliography of the periodical literature from 1889 to 1910 inclusive,
including all important work before 1889 and corrected to the
b^inning of 1913. Giving numerical data for the ioniza-
tion constants at all temperatures at which they
have been measured ; and some numerical
data of the electrical conductivity
BY
HEYWARD SCUDDER, B.A., B.S., M.D.
Member ofths Ammicam Chmnwal SocUty, the Am&rioan Electroehemiecd
SoeUty^ etc.
NEW YORK
D. VAN NOSTRAND COMPANY
Twenty-five Pabk Place
1914
w^
^
JUL 17 1919^
^/tX^ia/MJ^
COPTRIOHT, 1914,
By Heywabd Scuddes
THE UNIVfiRBITT PRESS, CA1CBRITX3E, U.S.A.
u
CONTENTS.
Paob
Explanation 5
Abbreviations op Words 28
Abbreviations op Journal Titles 31
Cyclic Formulae 36
Tables 41
Compounds arranged Alphabetically, with the Ionization Con-
stant, some Data of Conductivity, and all Bibliographical
References given under each Compoimd.
Formula Index 323
Author List 390
Bibliography of Authors' Names arranged Alphabetically.
Subject Index 540
Journal List 656
Names of Journals arranged Alphabetically.
Addenda 567
ERRATA
Page 52. ^eiicfo-Acetylpyrrolecarbozylic acid. Change the cross
reference to 2-Methylpyrrylketone-6-carbozylic acid.
Page 54. Adipic acid; line 7. Close the parenthesis after (1024 .
Page 59. p-Aminobenzoic acid ethyl ester. There should be no
period between the end of the first formula and the equality
sign.
Page 89. Butyl cyanide. The cross reference should begin with a
capital V.
Page 108. Cobalt. Add 1126 at the end of line 7.
Page 150. Dithiolcarbozyacetic acid. The cross reference should
read Dithio-carbondiglycollic acid.
Page 167. Gliadin. Insert 146b before 2006.
Page 170. Guanidine. The reference number is 1776, not 1176.
Page 200. 2-Methozy-3,5-dichloro-benzoic acid. The synonym in
parentheses should read Methyl-dichloro-salicylic acid.
Page 239. p-Orsellic acid. The synonym in parentheses should
read p-, not p. .
Ozaldihydrozamic acid; last line. The number 756 should be in
bold-face type, as a reference number.
Page 246. Phenaceturic acid. The synonym in parentheses should
read Phenylaceturic acid.
Page 257. Phosphorus; middle of line 6 should read sulphide, not
oxide.
Page 261. Platinum; last line. Insert 1417 before 1466.
Page 285. Telltuium; line 2. The first word should read hydroxide,
not chloride.
Page 360. CgHioONj. There should be a hyphen in the first name,
between N and phenyl.
Page 429. 567. The date should read 1890, not 1980.
Page 530. 1915; last line. The bracket should be closed after 1929.
Note. The cross references for substittUed amides on pages 74, 79,
92, 132, 192 and 319 lead to the unsubstituted amide. Following
this will be found the substituted amides.
EXPLANATION.
INTRODUCTORY.
THE ol^eet of this book is to present, as far as lies in my power,
a bibliography of all the measurements of the ionization con-
stants and the electrical conductivity of organic compounds
that have appeared in the periodical literature between the years
1889 and 1910 inclusive, together with the values of the ionization
constants, and certain values of the electrical conductivity measure-
ments. Qualitative work is also included. Before the year 1889,
little work of value at the present time was published. All that is
of value is included here. From 1910 to the beginning of 1913, im-
portant corrections that have come to my notice have been inserted.
Beginning with 1910, full data of the entire periodical literature are
published in the Tables Annuelles Internationales de Constantes et
Donn6es Num^riques.
Exceptions. The references to subjects chiefly of biological in-
terest, as albumin, blood, sap, etc., are complete only for the last
few years (roughly the last five or ten), but afford a means both of
knowing where to get at the important work, which is all recent, and
where to start in any more thorough search of the literature.
The references to the resistance of substances such as rubber, wood,
etc., have not been looked up. They are of value almost exclu-
sively in connection with the question of electrical insulation. A
few are given. There is a biological interest in some cases.
The fact that the references to the literature of any compound or
substance are not complete, is stated in the tables immediately after
the name.
References to the conductivity of inorganic compounds in organic
solvents have not been looked up specially, though in cases where
salt formation is to be expected they have been taken. When given,
they will be foimd under the head of miscellaneous measurements,
either separately from the references to organic compounds, or dis-
tinguished from them by being placed in parenthesis. A few pages
farther on, in the detailed description of miscellaneous measure-
ments, will be given certain considerations of the question of com-
bination of solvent and solute in making new compounds.
6 EXPLANATION
AddiHom. In the author list are given some articles which con-
tain only measurements of inorganic compounds, or matter which is
theoretical. Such references are inclosed in parenthesis to dis-
tinguish them, both in the author list and wherever else they may
be used. The object of including them is to save time to persons
who are interested only in original measurements of organic com-
pounds. Experimental work in connection with theoretical con-
siderations of dissociation and of electrical conductivity is almost
invariably first carried on with inorganic compounds. Later work
often refers to organic compounds for the sake of analogy, clearness
or additional proof. In consequence of this, references are often
met with, which are apparently to original work on organic compounds,
when as a matter of fact the original article contains only quotations
of experimental work on organic compounds, while the new experi-
mental work is entirely on inorganic compounds.
In the case of work on the conductivity of molten salts, which is
quite recent, I have inserted a number of references to work on in-
organic compounds, because experience has shown that these articles
will be referred to, as soon as similar work on organic compounds be-
comes common.
In the tables, a number of references are given to work on the
comparative strength of different compounds (measured in various
ways), because to many chemists the chief value of the ionization
constant of a compound, or of a measurement of its electrical con-
ductivity, is to determine its strength as an acid or a base. When no
quantitative data are available, qualitative data may be quite use-
ful. Negative results, as the fact that a compound has no appreciable
conductivity in hydrochloric acid, may be of use in determining the
nature of a compound or as a guide for subsequent investigation.
The statements in the tables always indicate when the work is of
a qualitative nature, or when negative results have been obtained.
A few measurements of inorganic compounds have been inserted
for purposes of comparison.
Method of search of the literature. Seventy-eight of the journals
and about five thousand dissertations have been examined page by
page; the other journals have been examined by index and table of
contents, with page by page examination of articles that might con-
tain information. The titles of articles usually give no indications
of value, so omissions are to be expected. The omissions are most
likely to occur in the case of measurements of the conductivity of
salts, since these are frequently inserted very briefly, with no special
mention of them in the text.
/
/
EXPLANATION
ARRANGBMSNT.
The book is divided into a set of tables arranged according to the
names of the compounds, containing all the data that may be given,
with a bibliography of all the references to each compound; a form-
ula index to the compounds; a bibliography arranged according to
the names of authors; a subject index to certain subjects; and a
journal list giving the names of all journals examined with the number
and date of the last volume examined.
Order. Alphabetical order is used as a rule, but where the numeri-
cal order is more natural (as in the case of mono- and di-, etc. com-
pounds) that is tised. With a few exceptions, due chiefly to recent
practice, and the necessity of selecting a definite form or name in
cases of dispute, Beilstein's Organische Chemie (3d edition), Richter's
Lexikon der Kohlenstoff-Verbindungen and the International Cata-
logue of Scientific Literature, have been used as guides and authori-
ties. While I do not approve of a number of details in any one of
these publications, it is obvious that if there is no yielding of personal
prejudice all attempts at general uniformity will fail. Some incon-
sistencies in names and formulae are due to the fact that no one
authority can be followed throughout.
In cases where more recent work has decided the composition or
structure of a compound, such work has been accepted. It must
always i)e remembered that the latest work on any subject is not
necessarily the best, even when the newest theories and apparatus
have been used.
DETAILED DESCRIPTION OF THE DIVISIONS.
TABLES.
Arrangement of the Compounds.
While the arrangement of the compounds in the tables is alpha-
betical, in order to bring together certain closely related compounds
some exceptions are necessary, which are chiefly the use of customary
names of isomers and of positions. Ortho-, meta- and para- com-
pounds are placed in the usual order. Iso-, alio-, etc. compounds
are placed after the normal compound, the prefixes (which are
in italics) not being considered at all. The numerical order is
followed in the case of mono-, di-, etc., derivatives of polybasic com-
pounds. Immediately after each acid are given the amides, the
anhydride and then the esters. On account of the small number of
8 EXPLANATION
compounds and the system of nomenclature used; there is little actual
displacement due to these exceptions. Thus, iso-butyl alcohol comes
immediately after norm.-butyl alcohol, while iso-butyric acid follows
butyric acid, but on account of the intervention of the butyric acid
amides and esters it comes immediately after butyric acid propyl
ester. The few other exceptions will be found by means of the cross
references. In the case of the substituted amides there is an im-
portant exception discovered too late for correction. When an
anilino or toluidino radical is substituted for a hydrogen atom in the
NH2 group, the compound is not mentioned at all under the head of
the amides. Thus, acetanilide is not mentioned as acetic acid
phenyl amide, nor is oxanilic acid mentioned as oxalic acid mono
phenyl mono amide.
Nomenclature.
When an alphabetical arrangement is used, the place of any com-
pound will vary according to the judgment used in the selection of
the name, as in the case of methoxy-benzoic acid instead of hydroxy-
benzoic acid methyl ether, and also according to the way in which a
compound is regarded, as in the case of oxanilic acid which may be
regarded as an amide.
In the tables, when the choice lies between a common name and a
systematic name, as gallic acid or trihydroxy-benzoic acid, most
compounds with very familiar names are given under the common
name, since few chemists except those working with organic com-
pounds are able to remember the structure of the higher organic
compounds. This use of common names has the disadvantage of
separating isomers. The use of systematic names has two chief
disadvantages. It requires a knowledge of structure. Apart from
the difficulty of remembering the structure of a number of com-
poimds, our ideas of structure are constantly changing with increased
knowledge. In the second place, there is no fixed use of systematic
names. On the other hand, any consistent use of systematic names
will bring together isomers, and sometimes closely related compounds;
and the name will furnish some knowledge of the structure.
Cross references are in general given only to the parent compound
and not to the substituted compound. Thus, nitroterephthalic acid
is not given (though a nitro-p-phthalic acid is in the tables), because
under terephthalic acid is given the cross reference to p-phthalic
acid. The formula index shows at once the name used in the tables.
The names and the formulae of dyes are given as accurately as is
possible under the circumstances, but any information concerning
them must be used with caution. In most articles, on account of
EXPLANATION 9
the totally inadequate description given, and the ambiguous use of
words, it is impossible to tell exactly what compound was used for
measurement. Most commercial dyes are mixtures of compounds.
If we assume that for any measurement the chief constituent of such
a mixture has been isolated and purified, and is called in the article
the pure dye, the structure may be in doubt, since different makers
give the same name to dyes of different structure. Then in the case
of the greater number of dyes, which are salts, it is quite impossible
to tell which salt was the dye in question. There is some difference
between the conductivity of a sodium and a potassium salt, or be-
tween that of a hydrochloride, a sulphate and an acetate; yet as a
rule, the descriptions do not state the particular salt which was used.
In most cases, the statement that the pure dye base was used is mis-
leading, for the statement really means that a salt of one compound
was used, and not the salts of several compounds mixed — though
as just mentioned, it is usually impossible to tell what the salt was.
The same confusion of terms also exists in reference to the acid or
base of a dye, here again a salt really being meant, and not an acid
or a base.
Hyphens and spaces are used to indicate particular groups, to
avoid as far as possible the necessity of referring to the formulae.
NumberSf letters and abbreviaHans used to indicate position are
placed directly in front of the group or element which they affect.
In a few cases, the termination of the name shows the character of
the group, as ** one " for the keto group in pyrazolone. In these
cases the number follows in parenthesis.
In the numbering of substituted cyclic compoundSf the first sub-
stituted group is always given the number one. Thus, in the sub-
stituted benzoic acids, the carboxyl group is one; in the substituted
anilines the amino group is one. In the toluic acids, the methyl
group is one; but if they were regarded as methyl benzoic acids
(derivatives of benzoic acid), the carboxyl group would be number
one, and the number of the methyl group would vary according to
the acid.
The abbreviations C, N and O (used instead of numbers) show that
the substituting group is attached to the corresponding carbon,
nitrogen or oxygen atom. Bz, shows substitution in the benzene
ring; Py, in the pyridine ring. Carboxylic, in the name of an acid,
shows the group COOH. For ambiguities in the use of the word
hydrOf see the following paragraph. The word nor, as in noropianic
acid, shows that there is an unsubstituted compound, of which the
substituted derivative (including esters and ethers as substituted
compounds for the purpose of the present definition) has first been
known, and named by the name which would naturally belong to
10 EXPLANATION
the unsubstituted compound. In this case, opianic acid is the dime-
thoxy acid, noropianic acid is the dihydroxy acid. The word oxy
means only oxygen, hydroxy being tised to show the hydroxyl group
OH. The word stUphinic shows the group HSO^. The word atdpho
(as in sulphobenzoic acid) or sulphoniCy shows the group HSQi. The
word Bvlphoney as in sulphonediacetic acid, shows the group SQ2.
Differences in nomenclature causing confusion. In comparing the
name of a compound described in an article in a journal, with the
name used in other articles, or in standard works as those of Beil-
stein and of Richter, or with the name in these tables, a number of
differences in usage will be found, which may lead to error. It seems
advisable to explain a few of the most common of these, which have
caused a number of mistakes.
In the case of compounds containing sulphur, there is so much
variation in nomenclature, that the formula should always be ex-
amined. Most chemists use sulphinic, sulpho, sulphone and sul-
phonic, in the manner described in the preceding paragraph as used
in these tables. The word thio, is used to show the replacement of
any element by sulphur, or in making a name for a sulphur compound
which is analogous to any nonnsulphur compound. Thus, a thio-
acetic acid may be CH3.COSH, or CH|.CSSH, or CHS.COOH.
There is much ambiguity in naming compounds containing a sub-
stituting group. Methyl-salicylic acid may mean methoxy-benzoic
acid, or it may mean hydroxy-toluic acid, depending on whether
substitution is in the hydroxyl group or in the benzene ring. Cyano-
acetamide may mean cyanoacetic acid amide, or acetic acid cyanoa-
mide. It is sometimes impossible to tell what compound is meant in
cases such as these, unless the context supplies some means of identi-
fication. There is a certain amount of error in statements concern-
ing the measurements of organic acids by Ostwald, published in 1889
(less than twenty-five years ago), simply from this sort of confusion
of names.
There is the same possibility of confusion, when the place of the
substituting group is indicated in the name by a number or a letter.
Thus, acridine in Beilstein has the nitrogen numbered 10, placed
between carbons numbered 4 and 5. In Richter's Lexikon the
nitrogen is also numbered 10, but is placed between carbons numbered
1 and 9. In journal articles the starting point of the numbering
varies, and the direction of the numbering, as in the direction of the
hands of a watch or the reverse. This last variation of direction
while of minor importance, is apt to create confusion when isomers
which are mirror images are concerned.
The word '' hydro " is used in a most confusing manner. Thus,
pyrrole is CiHsN. Tetrahydro-pyrrole (p3rrrolidine) is naturally
EXPLANATION 11
C4H9N; yet it may be called hydro-pyrrole. In the same way in
the case of other compounds, the dihydro- or hexahydro- compound
of one man will be the hydro- compound of another. Furthermore,
when substituting groups are present, the word hydro may be used
to show the theoretical addition of hydrogen with subsequent sub-
stitution of two atoms of hydrogen at that point. Thus, imideazole
is C8H4N2. Parabanic acid, C8H2O3N2, is called triketo-tetrahydro-
imideazole, though only two hydrogen atoms are present. In this
case, four hydrogen atoms are supposed to be added; then, in the
three CH2 groups, hydrogen is replaced by oxygen giving three CO
or keto groups, leaving the fourth hydrogen attached to a nitrogen
atom. This use of hydro is of convenience when type formulae are
used, instead of printing formulae in the text, and is employed in
Richter's Lexikon.
Details of the arrangement under each compound.
In order to aid identification or to show the purity of a compound
for which any numerical data are given, the melting-point or boiling-
point is given in the tables when it is stated in an article. This
melting-point or boiling-point refers to the sample measured, and
not necessarily to the most highly purified sample described in the
article. In some cases the melting-point or boiling-point of a deri-
vative (as a salt) may be given, when the article does not' furnish
such data for the pure compound. The position of these identifying
data is directly after the ionization constant, or after the measure-
ment of the conductivity. In many cases, where the original sup-
plies no such data, I have looked up the mode of preparation, in order
to make sure what the compound is. There is a good deal of reason-
able doubt as to the position of substituted groups in a number of
compounds, for instance in the toluidine sulphonic acids.
Immediately after the name, are given (in parenthesis) the syno-
n3rm8. These are inserted in some cases only for convenience in
referring to the original articles, since the names used there have
been abandoned. After the synonyms, comes the empirical formula,
and when convenient the extended formula. Cyclic formulae are
given only in the grouping on the pages directly in front of the tables.
The extended formulae are intended to be of assistance, but not to
represent the definitive structure, nor to exclude the possibility of
tautomeric forms, floating double bonds, etc.
The bibliographical references for each compound are arranged
under definite headings which are not specifically named in the text.
These headings are; (1) the specific conductivity of the pure com-
pound; (2) the ionization constant; (3) the conductivity in aqueous
12 EXPLANATION
solution; (4) the conductivity in solvents other than water; (5) mis-
cellaneous measurements, as the conductivity of mixtures with other
compounds, conductivity under varying pressure, etc.; (6) the con-
ductivity of the salts.
In general, a reference with no explanation is either to the conduc-
tivity in aqueous solution, or to the measurement of the ionization
constant.
With the exception of old values of specific conductivity, which
have been changed to make them correspond to the modern values,
all data are given in the tables as in the original articles, rounding off
decimals to tenths — a change that is actually of slight importance,
since few of the measurements justify the use of the hundredths
place. Values given in Siemens or mercury unit * have not been
calculated to the corresponding values in reciprocal ohms for reasons
which will be given later.
Under each heading are given all the references in the bibliography
bearing on that subject. These references are given as numbers in
bold face type, corresponding to the numbers in the author list.
Duplicate references, that is, references to publication of the same
measurement in more than one journal, are not given in the tables.
They may be found by means of the author list, in which all such
duplications are given, the fact being noted after the title of the article.
Thus, under the heading of the ionization constant of butyric acid
at 25^, is given number 180. The author list shows that this is an
article by Billitzer in the Monatshefte ftir Chemie. After the title
is the statement in brackets, '' [same as 183] ", showing that the same
measurement wiU be found in 183, which is an article published in
the Sitzungsberichte der kaiserlichen Akademie der Wissenschaften
(Wien). Either article gives the original measurement. In these
cases of duplication, the reference number used in the tables is to
the article in the most readily accessible journal.
While as far as possible, no references to repetitions of the same
measurement in different articles are given in the tables, it is impos-
sible to avoid this altogether. Some of the measurements, in an
article containing a number of measurements, may have been made
by a person whose name is not mentioned. This person may after-
ward publish these measurements in an article under his own name,
with no mention of the fact that they have already appeared in print.
Such cases have come to my notice. References to new measure-
ments of the same compound or to measurements of different prepa-
rations of the same compound, by the same observer, are given be-
cause they tend to establish the accuracy of the first value.
* The customary usage of regarding this as a unit of conductivity is fol-
lowed, instead of speaking of it as the reciprocal of the unit of resistance.
EXPLANATION 18
When there is any advantage in one article, either from its greater
acciiracy, or from its more extended measurements, that reference
number is placed first. In other cases the reference numbers are
given in numerical order, though of course the number of an article
from which any data are taken is placed directly after such data,
followed by the numbers of the other articles. If the ionization
constants or conductivity measurements in two articles are widely
different, both are usually given, placing first the more reliable, and
stating any possible explanation of such difference. But if the data
in one article are evidently inaccurate, they are not given, though
the reference number of that article is given. When there may be
doubt from the name alone, what compound is referred to, greater
weight is usually given to articles containing some means of determin-
ing what compound was really measured, and how pure it was. In
the case of isomers, when no identifying statements, such as melting-
point, mode of preparation, etc., are made in an article, I have assumed
that the most easily prepared or procured isomer was used.
For all statements enclosed in brackets, I am responsible.
Detailed description of the headings under each compound.
1. Specific condttctivUy, As is customary, the old values are mul-
tiplied by 10^ to make them comparable to the modern.
The generalization that the specific conductivity of a compound
is a safe guide to its purity (the purest sample having the lowest
conductivity), is incorrect. It seems probable that the character of
the impurity has a considerable influence, and that the closer it is in
structure to the compound to be purified, the more difficult it is to
detect very small amounts by the fall in conductivity. It is also
probable that there is some actual effect of solute on solvent in many
cases. Turner 1766, finds that conductivity alone is not a sure indica-
tion of the amount of water in ethyl alcohol containing very small
amounts of water. Foussereau 697, and Walden 1843, 1844, hold to
the opposite view. Dutoit, Rappeport 491, find that the conductivity
gives no absolute indication of the presence of very small amounts
of impurity. See also 466, 1223, 1388 and 1389 in this connection.
2. Ionization constant. The ionization constant, k, is calculated
(a) 2
from electrical conductivity measurements by the formula k = .
(l-a)v
In this, V is the volume in liters in which is dissolved one equivalent
weight in grams of the compound, and a, is the degree of dissociation
measured by -— — -. Text books must be consulted for a treatment
A(<x>)
14 EXPLANATION
of the inaccuracy of this formula in the case of bases, stronger acids,
and polybasic acids in which the influence of the second hydrogen ion
is felt at moderate dilutions; and also for the calculation of the con*
stant by other means, as the hydrolysis of salts, etc. See also the
Subject Index under the headings, Dilution Law, and Ionization
Constant, for articles on the subject. The earlier authors follow
Ostwald in expressing the value in decimals, and using a constant
one hundred times k=K, to avoid unnecessary ciphers. In the
tables the true constant k is used, expressed in powers of 10; thus,
for acetic acid at 25**, k X 10* = 1.86.
It is ^ven for each temperature at which it was measured, with
an abbreviated explanation of the method used for its determination,
if this was not by the direct measurement of the electrical conduc-
tivity of an aqueous solution of an acid or a base. When the value
is greater than 10~^, the value found by direct measurement of the
electrical conductivity is generally chosen. When it is less than 10~^,
a value determined in some other way, by hydrolysis, etc., is given
when possible; though in certain cases the value found by electrical
conductivity is also given for the purpose of comparison with similar
compounds, for which no method of measurement other than the
electrical has been used.
In the case of measurements by the conductivity method, the fact
that the specific conductivity of the water of solution has not been
subtracted in calculating the value of the constant is noted by the
abbreviation aq., placed directly after the value of the constant,
thus, 1.8aq. The difference between the value corrected and uncor-
rected, as a nile is less than five per cent, but may be sufficiently
great to account for discordant results obtained by different persons.
The statement that the value of the constant increases or dimin-
ishes on dilution, is given for the purpose of attracting attention to
the fact, since it may indicate the change from one isomer to another,
or the presence of impurity. The cause of such variation is not always
known. The assumption that a constant value not affected by dilu-
tion is a criterion of purity, and that a steady diminution is always
an indication of impurity, was first made by Ostwald 1371, who in
the same series of articles rejects this criterion when it affects un-
favorably the position of an acid in a series. Since that time classes
of acids have been found, as the alkyl succinic acids, in which there
is always a diminution in value on dilution. Noyes 1342 in the case
of a regular diminution in the value of the constant of o-nitrobenzoic
acid of great purity, states that this diminution means nothing of
great consequence. See also 616 and 2018. For a detailed treatr
ment see 1609.
If the value of the constant is determined by conductivity measure-
EXPLANATION 16
ments, and there is an increase or diminution in the value on dilu-
tion, the particular value chosen depends on the structure of the
compound. In the case of a diminution in the value, the value at
a dilution of about 32 liters is taken when possible, as being fairly
accurate and affording a standard value for that compound com-
parable with the greatest number of other compounds. If the value
increases on dilution, in the case of the stronger amphoteric electro-
lytes the value at a dilution of about 1024 liters is taken. This value
is selected, because in a number of cases, as for instance the amino-
benzoic acids, it corresponds fairly well with the value obtained by
other methods. If the compound is a polybasic acid, the value for
a lower dilution is chosen, when the influence of the second and third
carboxyl groups is evident. In other cases, it has been impossible
to follow any definite rules.
The ionization constant for the second and third hydrogen and
hydroxyl ions is also given, with an indication of the method by which
it has been determined.
In comparing the values of the ionization constant obtained by two
different persons, certain general considerations have to be taken
into accoimt, as the purity of the compound (and sometimes its
identity), the method employed and whether the value chosen as the
best, is a mean value, or is extrapolated or otherwise derived from the
measurements. If the method is that of the electrical conductivity,
three factors must be especially considered; the temperature; the
specific conductivity of the water (or other solvent); and the value
used for A(a>).
The temperature of the measurement is usually given, since its
importance in chemical work has been recognized for such a long
time. The ionization constant of most organic acids and bases
increases with the temperature up to about 40^ to 50^, and then
diminishes as the temperature is raised still higher. See acetic acid
for an illustration of this, and 1332 and 1341 for measurements cov-
ering a wide range of temperature. When no temperature is stated
in an article, it is safe to assume that it was either 18^ or 25^, except
for compounds like the diazo compounds which decompose readily at
ordinary temperatures.
The value of the specific conductivity of the water of solution gives
an indication of its purity. The purification to water having a specific
conductivity of 2 to 3 X 10~* at 25** is so easy, that for a number of
years, measurements have been made with water at least as pure as
that. The question of whether this conductivity is to be subtracted
in whole or in part or not at all, is still a matter of dispute, the cor-
rection made varying with the individual opinion. The difference
made by this correction may be of some importance; thus in the case
16 EXPLANATION
of a-i«o-phenylacetic acid at 25^, the ionization constant (multiplied
by 10*) is 3.76 with no correction, but is 3.67 when corrected for the
conductivity of the water. This water had a specific conductivity
of 1.4xl0~* at 25^. See 1633 for the details of this measurement.
The value used for A(») depends chiefly on the unit of conduc-
tivity, and on the values used for the equivalent conductivity of the
hydrogen and hydroxyl ions; to a much less degree, on whether it is
calculated from the measurements made, or is taken from a set of
tables. For almost all measurements made before the year 1898,
the Siemens unit was used. Since that time, either this unit or the
reciprocal of the ohm then proposed by Kohlrausch is used, the
tendency being more and more to use the reciprocal ohm. For
acetic acid, at 25°, the value of A(oo) is about 364 in Siemens unit,
and 388 in reciprocal ohms, the mean factor for the conversion to
reciprocal ohms being 1.066. The error of using one unit for the
other is rarely made. It is due to the false assumption that all values
for the specific and molar conductivity published in the last ten years,
are in reciprocal ohms. The value for the molar conductivity (reaUy
in Siemens unit) will be taken from some article, the value for A(» )
in reciprocal ohms will be taken from a table, and the ionization con-
stant calculated from this mixture will naturally differ from any that
has been known before.
The value for the equivalent conductivity of the hydrogen ion is
not yet settled, there being a difference of about six per cent between
the extreme values given for 25°, that is 340 and 365 in reciprocal
ohms. There seems to be no doubt at the present time, that this
value varies with the concentration; and it is possible that other
factors may also influence it. See Kendall, Jour. Chem. Soc. 101,
1275, (1912), for a review of the subject with new data, and Lewis,
Jour. Am. Chem. Soc. 34, 1631, (1912), for certain theoretical con-
siderations. The value for A(<» ) of acetic acid at 25°, will vary from
381 to 408, in reciprocal ohms, depending on the value used for the
hydrogen ion. Taking the molar conductivity at a dilution of 32
liters as 9.2, this gives the ionization constant (multiplied by 10*)
as 1.86 in one case, 1.64 in the other. A difference as great as this
is often used as a basis for showing that a compound has a particular
structure, or is a new compound. Up to the year 1910, practically
all the organic acids have had their ionization constants calculated
with a value of A(<») in which the equivalent conductivity of hy-
drogen is from 345 to 348, occasionally a little higher, but in no case
high enough to make such a difference from other measurements, as
has just been shown possible. But the use of this much higher value
for the hydrogen ion is becoming more common, and may lead to
some mistakes.
EXPLANATION 17
In the case of bases, the equivalent conductivity of the hydroxyl
ion, makes a corresponding difference. But there have been practi-
cally no changes made in it by new measurements, since the year 1894.
It is to be noted that Bredig 271, used an older value in calculating
the ionization constants of the bases published by him in that year,
and stated that with the present value the ionization constants are
about sixteen per cent too high. In the tables they are given in their
uncorrected form, with a statement of the correction. In Kohlrausch
and Holborn's Leitvermdgen der Elektrolyte, they are given uncor-
rected, though the values of the conductivity are calculated from the
original form to reciprocal ohms.
The values of A(») calculated from measurements of the salts of
acids, made at the same time and under the same conditions as the
measurements of the acids, do not vary enough from the values pub-
lished in the tables of Ostwald, and of Lund^n* to cause any trouble.
They ought to be more accurate for their purp,ose, than the table
values. See White and Jones 1968a, for an illustration.
In determining the ionization constant by methods other than the
direct measurement of electrical conductivity, the value used for the
ionization constant of water often enters into the calculation. The
value most frequently used is the old one for 26°, kw = 1.2x10"^*.
If a measurement is made at 25°, the error from the use of this value
is smaU, but the farther the temperature departs from 25° the greater
is the error. At 0°, the constant of water is about 0.1 instead of 1.2,
k
so that the substitution of this higher value in the equation k»— ,
X
where x is the hydrolysis constant, will give a value for the ionization
constant which is about ten times too large.
Calculation of the ionization constant by factors for various groups
and for different positions of the same group, gives results that are
not reliable. In some cases, the agreement is good, in others bad.
There is not yet sufficient knowledge to make such a calculation of
much value except where the constants of closely related compounds
are known.
3. Conductivity in water. As a rule the only data given under this
head are the values for the molar conductivity at 25°, for dilutions
of 32 and 1024 liters (or as close to these dilutions as possible) and
the value at infinite dilution. Occasionally the values for the cor-
responding dilutions at 0° are also given. In the case of the more
important compounds, the references are arranged according to
* Lund^n 1148 and Affinit&tsmessungen an schwachen Sauren und Basen,
gives a table of the values of A(oo) calculated for acids containing from
twelve to thirty atoms, at temperatures from 0° to 50°.
18 EXPLANATION
temperature. When only one measurement of a compound has been
made and the ionization constant determined from this, the tempera-
ture is given only under the head of the ionization constant, unless
there is some intervening statement, such as the ionization constant
of the second hydrogen ion. If all the references to the conductivity
are desired, it is advisable to look up those given under the ioniza-
tion constant as determined by the measurement of conductivity,
as well as those given under this heading, though in general such
references are given under both headings.
The values given for the molar conductivity are not reduced to a
common unit, nor corrected for the specific conductivity of the water
used, because in many articles there is a lack of data for making such
reductions. Experience shows that when corrections are made in
some cases and not in others, persons using a set of tables will as-
sume that the correction is always made and that the values are com-
parable. Reference to the author list (which is necessary to find out
the name of the person corresponding to the key number) shows at
once whether an accurate comparison can be made with the values of
other compounds. In articles published up to the year 1898, it is
safe to assume that the unit is the Siemens unit. The factor to con-
vert this into the reciprocal ohm varies from 1.063 to 1.069 for most
measurements, the mean value 1.066 being sufficiently accurate for
most purposes. For details see Kohlrausch, Holbom, Diesselhorst
1002, or Kohlrausch and Holbom, Leitvermogen der Elektrolyte. A
few of the old measurements made in a special unit have been cal-
culated to Siemens units when given in the tables, and a note of this
change made both in the tables and in the author list. When the
author list does not show the unit of measurement, it can often be
found if a value of A(<» ) is given for an acid, by comparing this value
to that of other acids, or with the values in tables. A comparison
of the value of the conductivity at a given dilution with that (in a
known unit) of some similar compound at the same dilution is useful.
But it may be quite misleading, unless the compounds are near each
other in an homologous series.
4. CondiLctivUy in solvents other than water. No numerical data
are given. The references to inorganic solvents are given first, then
to organic solvents. No distinction is made between pure solvents
and solvents diluted with water. Reference to the subject index in
which such a distinction is made, will usually settle this point. When
alcohols are used as solvents, many measurements often cover the
entire range from the pure solvent to very high dilutions or to pure
water.
A number of researches of a qualitative nature have been made with
these solvents, especially with the inorganic solvents. The results
EXPLANATION 19
of such researches are expressed in the tables with a qualifying clause
to show that they are not quantitative, thus, '' In ethyl alcohol, small
cond." When, for any solvent, quantitative as well as qualitative
measurements have been made, the references to the quantitative
work are always given first, then the references to the qualitative
work prefixed by the qualifying clause to show their nature.
5. MisceUaneoua metiaurements. Under this heading are given
references to a variety of measurements, most of them to the con-
ductivity of the compound in solutions containing other compounds.
In consequence, the heading in the tables usually begins, *' Cond.
with ".
These measurements of mixtures have been made for a great variety
of purposes and can not conveniently be subdivided in any brief way.
For instance, under acetic acid they are divided into conductivity
with inorganic compounds — acids, bases and salts; and with organic
compounds — acids, bases, salts and other compounds. In the case
of an acid, the measurement of the conductivity with a base may be
made to show the number of carboxyl groups, or to show the effect
of the presence of small or large amounts of the salt of the acid, or
whether any salt formation actually occurs. If the measurement is
of a solution to which an alcohol is added, the object may be to show
the effect of adding a non-electrolyte, or to show if any esterification
occurs. In other cases, as of a phenol in a solution containing iodine,
the measurement may show that oxidation or substitution occurs.
These cases of mixtures of compounds can not strictly be separated
from the cases of a compound in a dilute aqueous solution of a non-
aqueous solvent, though in practice such a distinction is usually made.
The references to the conductivity of mixtures of organic compounds
are usually ^ven under all the compounds in question.
The references to the compound as solvent, are to the conductivity
of the compounds dissolved in it, or to complexes that may form.
Thus, under acetic acid, the first reference to the acid as solvent gives
the conductivity of sodium acetate in the pure acid, and in aqueous
solutions of various strengths. The same reference is also to be
found under the sub-heading of conductivity with organic salts. The
references to the conductivity of compounds as solvents, are not
complete for the cases when an inorganic compound is the solute.
The nature of the other miscellaneous measurements is obvious
from the brief explanation, as, ** under pressure," etc.
6. SaUs. These are arranged, first as inorganic salts, then as or-
ganic, in alphabetical order.
The data given, when possible, are the molar conductivity at 25^,
for dilutions of 32 and 1024 liters, of the sodium (or potassium) salts
of acids, and the hydrochlorides of bases. This selection is made,
20 EXPLANATION
because these salts are most often made, and the conductivity of
their solutions measured, and these dilutions are used to determine
the basicity of acids. In a number of cases, the only data of a con-
ductivity measurement given in the original article is the difference
between the conductivity at 1024 and 32 liters. In the case of very
readily hydrolyzed salts, when the measurement is also made with
repression of hydrolysis by excess of acid or base, this measurement
is also given.
The number of radicals in the salt is indicated by the figure pre-
fixed. Under oxalic acid, for instance, Na.A is the mono-sodium or
acid salt, while 2Na.A is the di-sodium salt. Under acetic acid,
Ca.2A, is the calcium salt, requiring two acid radicals.
FORMULA INDEX.
This is arranged in the customary manner. For each compound
is given only the name used in the tables, the synonyms being given
in the tables. A number of salts are inserted for convenience, especi-
ally when the acid or base has not been made, or isolated in pure form.
In general, salts are to be found by looking up the acid or base from
which they are derived.
AUTHOR LIST.
The names of the authors are arranged alphabetically. Prefixes
not beginning with a capital letter, as de and vorij are not considered
in the arrangement. A few errors may be present, on account of
the apparent indifference of some persons as to the initials which
belong to their names. The English names beginning with Mac and
Mc are sometimes quoted in foreign literature without the prefix,
thus. Coy instead of McCoy.
Each name is preceded by a number which is used throughout the
book for all reference to that particular article. After the name, is
given the abbreviation of the journal title, the series number in
parenthesis, the volume number, page number and date. Then
follows the name of any person who is said to have made a measure-
ment described in the article, thus, 11 . . . (1898). Meas. E, Cohen.
A cross reference is given from the name of the individual making
the measurement; thus, under the letter C, is Meas, £. Cohen, see 11.
If only a part of the measurements were made by a person other than
the author, the name is preceded by the sign HH , thus mt Meas. Smith.
The name of the measurer is so often given with scrupulous accuracy
in the literature, that it has been necessary to burden the bibliog-
raphy in this way in order to make known that such measurements
EXPLANATION 21
were not overlooked. On the other hand, there are many cases in
which there is no doubt that the author did not make the measure-
ments, but there is no way of finding out who did make them.
When an author has published articles in different journals, the
joumab are arranged in alphabetical order in two divisions, giving
first the more accessible. Under each journal, the articles are ar-
o'anged chronologically. For an iUustration, see the references to J.
Walker.
The title of the article is given in full, translated into English in
the case of titles in Russian. If the same article, or a summary is
printed in some other journal, the full title is not repeated, only
enough being given to indicate that it is the same as in the first
reference.
Articles in parenthesis contain no original measurements of the
ionization constant or of the electrical conductivity of organic com-
pounds.
In brackets immediately after the title, is given information as to
whether the numerical data in the article are republished in some
other journal. Such statements do not refer to the text. The un-
qualified statement, " same as ", indicates that the numerical data
are the same in both articles. The unqualified statement, ** given
in ", indicates that there are additional numerical data, or additional
compounds measured, in the article referred to. When it does not
take too much space, the difference between the two articles is stated
in the bracket. The most common difference is that one will give
only the ionization constant, while the other will give full details of
the measurement from which the constant was calculated, with
tables of the conductivity at different dilutions, in the case of con-
ductivity measurements. This difference is always noted in the
bracket, by some such statement as, ** k, but not A is given in ".
Information of other kinds is also ^ven in brackets, as to whether an
article contains only qualitative work, etc. In a certain number of
cases, it is impossible to tell whether the same numerical data have
been republished in different articles or whether new measurements
of the same compounds have been made. Some duplications un-
doubtedly have been given in the tables on this account.
In the tables and in the subject index, in cases of repetition of
measurements, only one key number is given, referring to the most
accessible journal. Examination of the author list will show whether
any other article contains the same numerical data.
After the title are given (when the original supplies them) certain
data of use in comparing constants, or for further information. These
are; the temperature, with extremes if several different temperatures
have been used; the unit of conductivity; and the specific conduc-
22 EXPLANATION
tivity of the water of solution, with a note of whether this conduc-
tivity was subtracted from the conductivity of the solution, indicated
by the abbreviation, " sub." Thus, x aq. =1 xlO"*; sub.
SUBJECT INDEX.
The headings in this index depend so much upon the individual
point of view, that in using it, it is advisable first to look through
the headings and to consider the definitions and illustrations.
In cases of doubt, or in cases open to legitimate difference of
opinion, the reference is given under all possible headings.
For the sake of brevity, consecutive references by the same author
are sometimes given inclusively, thus 60-63, instead of giving each
number separately. These inclusions are never used if the numbers
cover more than one name.
JOURNAL LIST.
The journals examined include all the important journals, and as
many of the minor journab (and dissertations) as has been possible.
Most of the articles in the Journal of the Russian Physico-chemical
Society have been examined by Mr. G. Torossian, and the statements
translated by him. They have been checked by me, as far as a very
limited knowledge of the language allows.
The arrangement is alphabetical for the chief words in the title,
particles such as, and^ de, der, etc., not being regarded. This sepa-
rates distinct publications of the same society, as Proceedings, and
Memoirs, but does not necessitate an exact knowledge of the title.
The volume number (and when necessary the page number or
division number) and the date of the last volume examined, are
given immediately after the title.
When a title is preceded by the sign ^, as jff Annales de, etc., the
journal is not complete through the year 1910, either because it has
been impossible to examine one or more volumes, or because the
volume for the year 1910 has not been issued. A note of the number
or of the date of missing volumes is given.
The titles are those in use at the present time. If any important
change in a title has been made, the fact is noted, and a cross refer-
ence is given.
Different libraries adopt different methods of numbering volumes
when a publication appears in several series, some using continuous
numbers, others following the numbers of each series. Different
methods of dating are also used, when a volume covers more than one
year, some giving the date of the year of publication, others the dates
EXPLANATION 28
of the years included in the volume, others the date of the appearance
or of the reading of the last article in the volume — a date that may
be several years earlier than the date of publication. These differ-
ences are a source of some confusion in references in the literature.
In addition to these difficulties, some societies issue a number of
publications, which may be bound separately under individual titles,
or in various combinations under various titles.
Journals are sometimes referred to by the name of a past or present
editor, as Drude's Annalen instead of Annalen der Physik. Cross
references have been given to all the cases that have come to my
notice.
The names of journals which have contained no data are inserted
in order to show exactly what journals have been examined.
At the end is added a list of the authors of articles in the Journal
of the Russian Physico-chemical Society, arranged chronologically,
with the page numbers of the articles. This is given because the
variations in names due to different systems of transliteration, make
checking of references to this journal slightly difficult.
BOOKS.
Much of the numerical data published in the journals has been col-
lected and republished in various forms in text-books and mono-
graphs. Three of these are very useful. Taking them in chrono-
logical order; Das Leitvermdgen der £lektrol3rte, Kohlrausch and
Holborn, (1898), contains fairly complete data of the ionization con-
stants, and of electrical conductivity in aqueous solution (with all
values calculated to reciprocal ohms, but no values of A(<») given).
Bredig's constants for the bases, as previously noted, are about six-
teen per cent too high. The Conductivity of Liquids, Tower, (1905),
contains data of the specific conductivity of pure liquids, and some
data of the conductivity in solvents other than water; and also some
data of conductivity in aqueous solution, published between the years
1898 and 1905. Affinitatsmessungen an schwachen Sauren und
Basen, Lund^n, (1908), gives tables of the best values of most of the
ionization constants published from 1889 up to 1908, corrected
(when necessary) for the values of the ionization constant of water
at various temperatures, with a table of the values used in making
these corrections. Bredig's ionization constants for the bases are
given with no comment that they are too high. A number of tables
of value are also given, though little numerical data of electrical con-
ductivity are given, except as illustrations. All three books contain
some bibliography. Die Theorie der elektrolsrtischen Dissociation,
Abegg, (1903), also has some numerical data of value. Volume 1 of
24 EXPLANATION
the Tables Annuelles Internationales de Constantes et Donn6es
Num^riques, containing complete numerical data of ionization con-
stants and of electrical conductivity published in the periodical litera-
ture for 1910 has been issued. Volume 2 for the year 1911, is in
print, but at the time of writing has not been published.*
GENERAL.
The difficulty of a search through the literature for all references
to subjects which are rarely indicated by the titles of the articles, can
be appreciated only by those who have'done that sort of work. Omis-
sions are to be expected, chiefly I should suppose, in the case of the
measurements of the conductivity of salts.
When an article has been found, there is sometimes doubt and
sometimes entire uncertainty as to what the author really means.
The confusion due to nomenclature has already been mentioned.
There is also confusion from diversity in the use of symbols. For
the ionization constant, a small k or a capital K is used indifferently
(and occasionally an italic k), although in the majority of cases a
capital K (following the usage of Ostwald) stands for 100k. When
numerical data of the measurement are given, it is possible to find
out by calculation, whether k or 100k is meant. But the simple
statement that k (or K) is a given quantity, leaves the case in some
obscurity, unless the compound is one of an homologous series, in
which the values of the ionization constant for members of the series
close to it are known. It must always be remembered, that the
rules given for calculating constants by means of factors for certain
groups, and positions, while satisfactory in many cases, are quite
unreliable in many other cases.
In the case of the ionization constant, the use of some letter other
than a Roman k, may lead to confusion, unless there is a direct state-
ment that this constant is meant. For instance, the Greek letter
kappa, is frequently used as a symbol for specific conductivity. The
statement, " electrical conductivity shows that x =0.14 ", may mean
that the specific conductivity is 0.14, or it may mean that the ioniza-
tion constant is this quantity, for an italic k may have been written,
which was incorrectly printed.
Almost every letter in the English alphabet, and many of the
letters of the Greek alphabet have been used as symbols for specific
conductivity, molar conductivity and degree of dissociation. The
use of such a symbol with no explanation, leaves in doubt which of
these three quantities was intended, unless there is some way to
check it from preceding articles, or from the context.
* It has been issued in July, 1913.
EXPLANATION 26
It is interesting to note that in general the obscurity varies with
the chief occupation of the author. At one extreme is the chemist
chiefly interested in organic work. He describes his compound
accurately, gives the formula, and some data, as melting-point, etc.,
by which it may be identified. Then he says, " The conductivity of
this acid I have found as follows: k=*lAx 10"*." But he means the
ionization constant, not the specific conductivity, and gives no data
of conductivity values at all, in spite of his direct assertion that he
does. It is left to the reader to find out what he means, and to check
off as far as possible the value of the constant, in order to know
whether k or 100k is meant. At the other extreme is the chemist
chiefly interested in physical chemistry. He states that the com-
pound he is using is methylsalicylamide; and that it is pure because
it came from Kahlbaum, and the melting-point remained unchanged
after five recrystallizations from alcohol. All the definitions and
data relating to the measurement of the conductivity are given
clearly. But there may be grave doubt as to what the compound is.
The name is ambiguous, for the position of the methyl group is not
stated. No formula is given, and no melting-point. Even the fact
that this unknown melting-point remained unchanged after recrystal-
lization is no proof of purity, for many cases are known of mixed com-
pounds of definite melting-point which crystallize unchanged from
one solvent and can be broken up only by crystallization from a dif-
ferent solvent.
In the determination of the ionization constant by methods other
than the direct measurement of electrical conductivity, certain other
obscurities may be present.
The identity of the compounds, I have verified as far as possible
by a careful examination of the formula, method of preparation,
melting-point or any other data available in the original. The
values for the ionization constant have been checked off, whenever
the necessary data have been given in the original, making possible
the correction of some mistakes due to errors in calculation.
Numerical data taken from publications generally inaccessible, as
dissertations, are given more fully in the tables than the data from
accessible publications. More numerical data and more explicit
subdivisions of headings are given in the case of important compounds,
than of unimportant compounds.
A small number of compounds are given in the tables, which are
mentioned neither in Beilstein, nor in Richter's Lexikon. Since the
measurements of their conductivity are described by thoroughly re-
liable men, it seems reasonable to suppose that such compounds were
actually made, but that, for some reason, the description of them has
never been published.
26 EXPLANATION
Since the object of publishing bibliography ia the saving of time to
others, I have used much freedom in certain methods of presentation.
Thus, the name Tschugaeff is familiar to many chemists. It is used
in the author list under this form, and not under the form required by
the system of transliteration employed. The cross reference is
therefore from the unusual to the better known form. This same
principle of using well known forms, has been employed in a variety
of other cases. A liberal use of cross references and some repetition
have been necessary to cover all cases.
The reliability of the work published in the journals is usually
sufficient, but its accuracy is not as great as is supposed. This is
due both to lack of definite knowledge of certain theoretical considera-
tions necessary in making various corrections, and also to the uncer-
tainty of some of the fundamental values. The limitations of the
methods employed are fairly well understood, though there is a tend-
ency to exaggerate the accuracy of some of these methods, as for
instance colorimetric methods, especially when used in the case of
very weak compounds.
Our knowledge of the action of the solvent on the solute is still
imperfect, and the corrections for such action, even when water is
the solvent, are either matters of opinion, or are not known at all.
Various other corrections are still uncertain, because our knowledge
of the subject is not yet perfect.
There are three fundamental values, the equivalent conductivity
of the hydrogen ion, and of the hydroxy] ion, and the ionization con-
stant of water, one of which enters into almost every calculation of
the ionization constant of any compound. It must be emphasized
again, that any considerable change in one of these values affects
considerably the value of all the ionization constants calculated with
its aid. A recalculation of practically every constant that has been
published up to the present time, may be necessary when these three
values are finally established.
The rounding off to tenths of the numerical data printed in the
tables has saved much space and added greatly to the accuracy of
the comparison of the figures with the originals, while the error in-
volved is too slight to be of consequence, except in a few cases.
The apparently excessive number of abbreviations b due to the
fact that all abbreviations are given, even those so commonly used
that they are not usually explained, such for instance, as o for ortho.
Most of the abbreviations, including those of the titles of journals,
can be understood without looking up the full meaning.
Details are given in this explanation which will appear to many to
be unnecessary. But together with the abbreviations, they make it
possible to understand anything that is in this book, without the
EXPLANATION 27
special search for the usage of the time or place or school or author,
so often necessary for the understanding of what has been printed;
for, in addition to changes due to the growth of knowledge, there are
changes of fashion in science as weU as in the world at large. In the
case of nomenclature, it has often happened that an author proposes,
but Beilstein disposes of new ideas.
Against two criticisms I have no defense. The first is, that this
is an overelaboration of an unimportant subject. The second (which
is not contradictory to the first) is, that sufficient numerical data are
not given to make the table of compounds of much value. Other
criticisms could be answered, for many results are not yet positively
established. Theories and compounds that have, " forever been
swept from the literature," have at times come back with an in-
creased knowledge, while others that have been firmly established by
physical chemistry, have been greatly modified or have disappeared.
Our understanding of the dissociation theory has changed so much
by degrees, that the statement of James Walker made two years
ago,* ** We are justified in attributing the fact that acetic acid is a
weak acid, whilst trichloracetic acid is a powerful one, rather to the
properties of the un-ionized substances than to the properties of the
ions," is an upholding of the dissociation theory and not an attack
on it, as would have been the case twenty years ago.
Serious physical disability coming when the greater part of the
material for this bibliography was collected, has made necessary
rather awkward insertions, has delayed its publication, and pre-
vented as full a presentation of the subject as I had hoped. No
information at all has been given about apparatus and methods. The
references to the conductivity of inorganic compounds in organic
solvents are incomplete, though recent work makes it clear that in
many cases some complex is formed. I have been unable to make
some changes in arrangement, which would have given a more sys-
tematic presentation. The references often contain more informa-
tion on the subject than might be gathered from the headings under
each compound, for great detail in subdivision of headings is obvi-
ously out of place in a bibliography of this sort. While its use will
be limited to a small number of persons, I trust that the work as it
stands will be of sufficient value to justify a very dreary and un-
pleasant task.
Thanks are due to Dr. Wilder D. Bancroft, Dr. Alice F. Blood and
Dr. James F. Norris for advice, and to Dr. Olin F. Tower for per-
mission to use some tables from his book.
March, 1913.
♦ Chem. News, 104, 106, (1911).
ABBEEVIATIONS OF WORDS.
A
acid. For salts, A is used to indicate the acid radical,
thus: NaCl-Na.A; Na«S04=2Na.A.
Afd.
afdeeling.
ale.
alcohol.
aq.
water.
asym.
asymmetrical.
B
base. For salts, this is used to indicate the radical, as
und^ A.
b. p.
boiling-point.
Bu
butyl =C4H9.
Bz
benzoyl -CeHftCO.
catal.
catalysis.
cf.
compare.
colorim.
colorimetric.
cond.
conductivity.
cor.
corrected.
d
dextro.
dec.
decomposition.
dil.
dilute.
diln.
dilution.
Et
ethyl -CaHft.
Fasc.
fascicule.
f. p.
freezing-point.
fum.
fumaroid.
g
gram.
Hg. U.
mercury unit.
hydrol.
hydrolysis.
inact.
inactive.
inorg.
inorganic.
insol.
insoluble.
k
ionization constant. Second k or third k is the constant
of the second or third H or OH ion.
k . . . aq.
ionization constant, calculated without subtracting the
conductivity of the solvent.
kw
ionization constant of water.
X
specific conductivity.
ABBREVIATIONS
29
A
equivalent conductivity.
1
laevo.
liq.
liquid.
m
meta.
M
conductivity of a salt, when the hydrolysis is not checked
by excess of acid or base. Used chiefly when the con-
ductivity with hydrolysis checked by acid or base, is
also given.
mal.
maleinoid.
Me
methyl -CH|.
Meas.
measured by. jf^Meas. -in part measured by.
Mem.
memoir.
m. p.
melting-point.
M
molar conductivity.
N
substituting group attached to nitrogen.
neutral.
neutralization.
N. F.
Neue Folge.
no.
number.
norm.
normal.
N. S.
new series.
o
ortho.
0
substituting group attached to oxygen.
P
para.
part.
partition.
Ph
phenyl -CeHs.
Pr
propyl »CsH7y in formulae. In names, as Pr-Methylin-
dole, Pr shows the ring to which the substituting group
is attached.
qua!.
qualitative.
q. V.
which see.
R
ring or cyclic.
rac.
racemic.
R. 0.
reciprocal ohms.
sapon.
saponification.
satd.
saturated.
Sect.
section.
sol.
soluble.
soln.
solution.
solub.
solubility.
Sp. gr.
specific gravity.
S. U.
Siemens unit.
sub.
subtracted.
sjrm.
symmetrical.
T
temperature in degrees centigrade.
80 ABBREVIATIONS
uncor.
uncorrected.
V
volume.
vac.
vacuum.
Vol.
volume.
00
infinite dilution*
ABBREVIATIONS OF JOURNAL TITLES.
For a complete list of the journals examined see the section on
Journals. The abbreviations are only of the titles of those journals
from which references have been taken.
Abhand. Eon. Sachs. Ges. Wis. Abhandlungen der koniglich sach-
sischen Gesellschaft der Wissenschaften. Mathematisch-
physische Classe.
Am. Chem. Jour. American Chemical Journal.
Am. Jour. Physiol. The American Journal of Physiology.
Am. Jour. Science. The American Journal of Science.
Analyst. The Analyst.
Ann. Chemie. Annalen der Chemie. (Justus liebig's).
Ann. Chim. Phys. Annales de chimie et de physique.
Ann. Physik. Annalen der Physik.
Ann. Physik. Erganz* Annalen der Physik und Chemie. Erg&nz-
ungsband.
Ann. Univ. Lyon. Annales de Tuniversit^ de Lyon.
Arbeit, k. Gesundh. Arbeiten aus dem kaiserlichen Gesundheitsamte.
Arch. Anat. Physiol. Archiv ftir Anatomic und Physiologic. Phy-
siologische Abteilung.
Arch. Fisiol. Archivio di fisiologia.
Arch. Gesammt. Physiol. Archiv ftir die gesammte Physiologic des
Menschen und der Tiere. (Pfliiger's Archiv).
Arch. Mus6e Teyler. Archives du Mus6e Teyler. (Haarlem).
Arch. Pharm. Archiv der Pharmazie.
Arch. Sci. Phys. Nat. Archives des sciences physiques et naturelles.
Arkiv Kemi. Arkiv for kemi, mineralogi och geologi.
Atti Accad. Gioenia. Atti della accademia Gioenia di scienze natu-
rali in Catania.
Atti Accad. Torino. Atti della reale accademia deUe scienze di
Torino.
Atti 1st. Veneto. Atti del reale istituto veneto di scienze, lettere ed
arti.
Atti Pont. Accad. Nuov. Lincei. Atti della pontificia accademia
romana dei nuovi Lincei.
Beibl. Ann. Physik. Beiblatter zu den Annalen der Physik.
Beitr. Chem. Physiol. Pathol. Beitrage zur chemischen Physiologic
imd Pathologic. Zeitschrift ftir die gesamte Biochemie.
82 ABBREVIATIONS
Ber. Deutsch. Chem. Ges. Berichte der deutschen chemischen Gesell-
schaft.
Ber. Verhand. Sachs. Ges. Wis. Berichte Qber die Verhandlungen
der koniglich s&chsischen Gesellschaft der Wissenschaften zu
Leipzig. Mathematisch-physische Klasse.
Bihang. Svensk. Vet.-Akad. Hand. Bihang till kongl. svenska vet-
enskaps-akademiens handlingar.
Biochem. Zeit. Biochemische Zeitschrift.
Bol. Accad. Gioenia. BoUettino deUe sedute deUa accademia Gioenia
di scienze naturali in Catania.
Bui. Acad. Belg. Bulletin de I'acad^mie royale des sciences, des
lettres et des beaux-arts de Belgique. Bulletins de la classe
des sciences.
Bui. Acad. Cracov. Bulletin international de Pacad^mie des sciences
de Cracovie.
Bui. Soc. Chim. Bulletin de la soci^t^ chimique de France.
Bui. Soc. Franc. Phys. Bulletin des stances de la soci^t^ fran^aise de
physique.
Bui. Soc. Sci. Nancy. Bulletin de la soci^t^ des sciences de Nancy.
Bui. Soc. Vaudoise. Bulletin de la soci^t^ vaudoise des sciences natu-
relles.
Chem. News. The Chemical News.
Chem. Ztg. Chemiker-Zeitung.
Compt. Rend. Comptes rendus hebdomadaires des s^nces de Taca-
d6mie des sciences. (Paris).
Dis. Dissertation.
Ergebn. Physiol. Ergebnisse der Physiologie.
Festschr. Festschrift.
Gaz. Chim. Ital. Gazzetta chimica italiana.
Giorn. Sci. Nat. Econ. Giornale di scienze naturali ed economiche.
Habilitschr. Habilitationsschrift.
Jour. Am. Chem. Soc. The Journal of the American Chemical
Society.
Jour. Biol. Chem. The Journal of Biological Chemistry.
Jour. Chem. Soc. The Journal of the Chemical Society. (London).
Jour. Chim. Phys. Journal de chimie physique.
Jour. Indust. Eng. Chem. The Journal of Industrial and Engineer-
ing Chemistry.
Jour. Phys. Journal de physique.
Jour. Phys. Chem. The Journal of Physical Chemistry.
Jour. Physiol. The Journal of Physiology.
Jour. Prakt. Chem. Journal fur praktische Chemie.
Jour. Russ. Phys.-chem. Soc. Journal of the Russian Physico-chemi-
cal Society.
ABBREVIATIONS 88
Jour. Soc. Chem. Ind. The Journal of the Society of Chemical In-
dustry.
Jour. Soc. Dyers Colour. The Journal of the Society of Dyers and
Colourists.
Kong. Danske Vids. Selsk. Skrift. Det kongelige danske videnska-
bernes Selskabs Skrifter.
Med. Nobelinst. . Meddelanden fr&n k. vetenskapsakademiens No*
belinstitut.
M^m. Acad. Belg. M^moires couronn^s et autres m^moires publics
par Facad^mie royale des sciences, des lettres et des beaux-
arts de Belgique. In 8^. Classe des sciences.
Mem. Accad. Bologna. Memorie della reale accademia delle scienze
deiristituto di Bologna.
Mem. Accad. lincei. Memorie deUa reale accademia dei Lincei.
Classe di scienze fisiche, matematiche e naturali.
Mem. Accad. Torino. Memorie della reale accademia deUe scienze
di Torino. Scienze fisiche, matematiche e naturali.
Mem. Pont. Accad. Nuov. Lincei. Memorie della pontificia acca-
demia romana dei nuovi Lincei.
Mem. Proc. Manchester Lit. Phil. Soc. Memoirs and Proceedings
of the Manchester Literary and Philosophical Society.
Mem. R. Acad. Madrid. Memorias de la real academia de ciencias
exactas, ffsicas y naturales de Madrid.
Mem. R. Accad. Modena. Memorie della regia accademia di scienze,
lettere ed arti in Modena.
Monatsh. ' Monatshefte f fLr Chemie. *
Nachr. Ges. Wis. Gdttingen. Nachrichten von der k5nigl. GeseU-
schaft der Wissenschaften zu Gdttingen. Mathematisch-
physikalische Klasse.
Nature. Nature.
Naturwis. Rundsch. Naturwissenschaftliche Rundschau.
Nuovo Cim. II nuovo cimento.
Ofvers. Finska Vet.-Soc. F5rhand. Ofversigt af finska vetenskaps-
societetens forhandlingar. (Helsingfors).
Ofver. K. Vet.-Akad. Forhand. (Stockholm). Ofversigt af kongl.
vetenskaps-akademiens fdrhandlingar. (Stockholm).
Ov. Danske Vids. Selsk. Forhand. Oversigt over det kongelike
danske videnskabemes Selskabs Forhandlinger.
Phil. Mag. The London, Edinburgh and Dublin Philosophical Mag-
azine and Journal of Science.
Phys. Rev. The Physical Review.
Phys. Zeit. Ph3rsikalische Zeitschrift.
Proc. Am. Acad. Arts Sci. Proceedings of the American Academy of
Arts and Sciences.
I
84 ABBREVIATIONS
Proc. Am. Ass. Advanc. Sci. Proceedings of the American Associa-
tion for the Advancement of Science.
Proc. Cambridge Phil. Soc. Proceedings of the Cambridge Philoso-
phical Society.
Proc. Chem. Soc. Proceedings of the Chemical Society. (London).
Proc. Iowa Acad. Proceedings of the Iowa Academy of Sciences.
Proc. Phys. Soc. London. Proceedings of the Physical Society of
London.
Proc. R. Soc. Edinburgh. Proceedings of the Royal Society of Edin-
burgh.
Proc. R. Soc. London. Proceedings of the Royal Society of London.
Proc. Trans. Nova Scot. The Proceedings and Transactions of the
Nova Scotian Institute of Science.
Proc. Trans. R. Soc. Canada. Proceedings and Transactions of the
Royal Society of Canada.
Proc. Washington Acad. Proceedings of the Washington Academy
of Sciences.
Progr. Programschrift.
Rec. Trav. Chim. Recueil des travaux chimiques des Pays-Bas et
de la Belgique.
Rend. Accad. Lincei. Rendiconti della reale accademia dei Lincei.
Rend. Accad. Scienz. (Napoli). Rendiconto dell'accademia delle
scienze fisiche e matematiche (sezione della society, reale di
Napoli).
Rend. R. 1st. Lombardo. Rendiconti. Reale istituto lombardo di
• scienze e lettere.
Rend. Soc. Chim. Roma. Rendiconti della society, chimica di Roma.
Rev. R. Acad. Madrid. Revista de la real academia de ciencias
exactas, ffsicas y naturales de Madrid.
Schrift. Naturw. Ver. Schleswig-Holstein. Schriften des naturwis-
senschaftlichen Vereins fiir Schleswig-Holstein.
Science. Science.
Sitzber. Akad. Wien. Sitzungsberichte der mathematisch-naturwis-
senschaf tlichen Classe der kaiserlichen Akademie der Wissen-
schaften. (Wien).
Sitzber. Ges. Isis Dresden. Sitzungsberichte und Abhandlungen der
naturwissenschaf tlichen Gesellschaft Isis in Dresden.
Sitzber. Ges. Naturw. Marburg. Sitzungsberichte der Gesellschaft
zur Beforderung der gesammten Naturwissenschaften. (Mar-
burg).
Sitzber. K. Preuss. Akad. Berlin. Sitzungsberichte der koniglich
preussischen Akademie der Wissenschaften. (Berlin).
Sitzber. Phys.-med. Ges. Wtirzburg. Sitzungsberichte der physik-
med. Gesellschaft zu Wtirzburg.
ABBREVIATIONS 86
Trans. Am. Electrochem. Soc. Transactions of the American Elec-
trochemical Society.
Trans. Faraday Soc. Transactions of the Faraday Society.
Trans. R. Scot. Soc. Transactions of the Royal Scottish Society of
Arts.
Trans. R. Soc. Edinburgh. Transactions of the Royal Society of
Edinburgh.
Trans. R. Soc. London. Philosophical Transactions of the Royal
Society of London.
Trans. Wisconsin Acad. Transactions of the Wisconsin Academy of
Sciences, Arts and Letters.
Verhand. Akad. Amsterdam. Verhandelingen der koninklijke aka-
demie van wetenschappen. (Amsterdam).
Verhand. Deutsch. Phys. Ges. Verhandlungen der deutschen phy-
sikalischen Gesellschaft.
Verhand. Naturf. Ges. Basel. Verhandlungen der naturforschenden
Gesellschaft in Basel.
Verh. Ges. Deutsch. Naturf. Aerzte. Verhandlungen der Gesellschaft
deutscher Naturforscher und Aerzte.
Verslag Akad. Amsterdam. Verslag van de gewone vergaderingen
der wis- en natuurkundige afdeeling. Koninklijke akademie
van wetenschappen te Amsterdam.
Zeit. Analyt. Chem. Zeitschrift fiir analytische Chemie.
Zeit. Angew. Chem. Zeitschrift fiir angewandte Chemie.
Zeit. Anorg. Chem. Zeitschrift fiir anorganische Chemie.
Zeit. Biol. Zeitschrift fiir Biologic.
Zeit. Chem. Ind. Eolloide. Zeitschrift ftir Chemie und Industrie der
KoUoide.
Zeit. Elektrochem. Zeitschrift fiir Elektrochemie und angewandte
physikalische Chemie.
Zeit. Phys. Chem. Zeitschrift ftir physikalische Chemie.
Zeit. Physiol. Chem. Zeitschrift fiir physiologische Chemie. (Hoppe-
Seyler's).
Zeit. Ver. Riibenzuck. Ind. Zeitschrift d. Vereins f. Rtibenzucker
Industrie.
CYCLIC FOEMULAE.
THE formulae given here are mostly type formulae, that is the
formulae of compounds selected as the simplest members of
various groups of compounds. TJbe position of substituting
groups is indicated in the name of a compound by numbers, the num-
bers corresponding to those used in the formula of the type compound.
The presence of CH is shown by an angle. Any other combina-
tion of elements is given in full. Valences are not represented.
Tautomeric formulae are not given as a rule, nor the formulae of alka-
loids and dyes. For the purpose of comparison with original articles,
and with older names, various letters which represent position are
given as well as numbers.
In the tables the name of the type compound may be given in the
first name, as in dimethyl-parabanic acid, or it may be given in one
of the synonyms in parenthesis, as in the case of alizarin (1,2-dihy-
droxy-anthraquinone). In a more complicated case, as in the case of
anilopyrine (which is referred to pyrazole), iminopyrazole is also given
as a type formula to show the manner of attachment of the imino
group. In certain of the types no numbers are shown, as in cyclo-
butane, because it is immaterial where the numbering begins. In such
a case, the position of numbered substituting groups is readily found.
For a detailed treatment of certain doubtful or unsettled points con-
cerning names, see the heading " nomenclature," in the explanation.
CYCLIC FORMULAE
87
7
6
10
Acridine
Alloxan
co<^«V^^<^-^>co+3«,. r
'NH.CO
CO.NH-
AUoxantine
H
Antfanqiiinone
Azole
(FyiTole)
^NH.CO'^
3 4
Barbitoiic Add
^•^^>^°
o
5 8
o
CHi.CH.CHi.COiH
I CMei
CH : CMe
o-Beszoic
milphinide
CH:CMe
I CMe,
CHi.CH.CO,H
Campholytic
add
p-Benzoquinone cuCampholenic
add
CHt.CMei
I CMe
CH..C.CO,H
MO-Can^olytic
add
CHi.CMe.COiH
I CMe,
CH,.CO
Can^ononic
add
7
s. 5y\io/\4
Anthncene
m
6
5
CLOT II
-N
Benzimideazole
CH,.CHMe
I CMe,
CH,.CMe.CO,H
Campholic add
CHj.CH.COiH
I CMe,
CH,.CH.CO,H
Camphopyric
ada
CO
-O
Me,C.C(Me)(CO,H).CH.COiH
Camphoranic add
OC CMe
O
Me
Carboxydehydroacatic
add
^CH.CO,H
Camphorcarbozylic
add
HO.C.N-
<:;.0H
N:C(OH).N
Cyantsricadd
CH,.CH.COJI
I CMe,
CH,.CMe.CO,H
Camphoric
add
CHi.OHi
CH,.CHt
Cydotmtane
(Tetramefhylene)
88
CYCLIC FORMULAE
GHs.CUi.CU!
<iH..CH..CH.>*' Jh.CH:C>?' <!h..CH.CH>?
Cydoheptane
(Heptamefhylene)
CHs.CHt.CHt
CHt.CHs.CHt
C^ohezane
(Etexahydro-
benzene.
Hezamefhyl-
ene)
4 3 2
2, 4, S-Cydohepta-
triene
CHi.CHi.CHt
CH,.CH : CH
^dohexene
(Tetrahydro-
benzene)
CHi.CH
4 3 2
z-Cydoheptene
CHi
T J>CH, 1 >CH,
CHs.CH] CHs
Cyclopentane
(Pentametliylene)
CydoprO"
pane
(Trunetfayl-
ene)
OC CMe
A
H,
O
Dehydroacetic add
H
OC C.OH
H,C CH,
\c/ \/
H, Hs
Dihydro-resordnoL (m-Diketo-
hezamefhyleiie)
OC CMe
HC C.COjH
Me
£so-Dehydroacetic add
OC 00
H,C • CH,
CH,.CHi
CO . cx>
>CH,
Diketo-penta-
metfaylene
CH
CH,
Ethylene
oxide
'>o C0<
CH,.CH— CH.CO,H
I NMe CH.OH
CHj.CH— CH,
/-Ecgonine
NH.CH,
Diketo-hexametfaylene
see Dihydro-resordnol
CH, CH,
CO.NMe.CH.CH,.COJH
rac.-Ecgoninic add
NH.CH,
Ethylene
urea
Fluorene
Fluorenol =» Hy droxy-
fluorene
fyr-
A
.A\
6 8
\y — NJ/
^'
p
H
fi
1-N
-N
Fluorenone (9-Keto- Ftirfurane
fluorene) (Furane)
Glyoxaline
(Imideazole)
Heptameth^ene see
Cydoheptane
CYCUC FORMULAE
89
Hezahydro-benzene
see C^dohezane
Hezamefhylene
see Cydohezane
HCH.N.OH - HC( :N.OH) . OH
icadd
Lnideazole see
Glyozaline
AJ
2,5-Iininopy-
razole
/K/!\
\/
^
Indole. (Pr-showB
substitution in the
N ring)
6 3
Indone *
(1-Ketoin-
dene)
Ketofluore&e
Fluorenone
P
/^/\
^
a' tt'
Naphthalene
:N.OH
^«=^H.OO
tso-Nitrosothio-
hydantoin
CO.NH
:>co
CX)^H
Parabanic add
Pentametfaylene see
Cydopentane
H,N
NH,
PhOH
Phenosafranine
CH-C.CJO,H
PI1.C.O.N
Phenylisozazolecar-
bozylic add
CH.CO
PI1.C.NH
>>
8-Phenylisozazo-
lone (6)
1 N=CH 7
2HC6C— NH- 8
3N— C— N
4 9
>CH
Purine
^\
2
Pyrazole.
See also Im-
inopyraaole
H
16 21
H,ci-ll
Pyrazo-
lone(6)
Pyridine
o
5 3
6 2
\y
Pyrone
H,o
1 5
5 2
H
Pyrrole
(Azole)
-CH,p
4 3
5 2
a'H,0 1 CH,a
H
Pyrrolidine
* The indone of rosindone contains a N ring.
40
CYCLIC FORMULAE
Pynfi', used for de-
rivatives of I^pnole
A\/K
Bi
Py
NSAj/
8-0- -HI
7-m— [21
6-p. -(3J
When numbered
from the Bi ring
QalsoUne
/i\A\
3
Bi
3
^2
N
tso-Quinolme
Tetrahydro-benzeiie
see Qrclohezene
A.
f
^
Mormeso
Thiazole
Tetrmmetliyleiie see
Cydobtttane
Thienyl; used for deriva-
tives of Thiophene
.N>
[6 ^ 2^
1,2,4,6-
Tetraxme
H
4 8|
N N
\
1,2,8,4.
Tetnzole
NH,.C*H,<; g ^C»H, : NH
Thionine
A\a
5 2
4 3
^
Thiophene
XI,
OC6 3C.SH
Thiourazde
N 5 2^
H
N-
3
-K
1,2,6-TriAZole 1,8,4-Triazole
Trunethj^ene see
Cydopropaiie
1 .NH.cWp4
6 6
Undl
0C<
OC6 3C.0H
Urazole
laoliiric add
TABLES
THE eompounds are arranged alphabetically, except where the
numerical order is more natural, as in the case of mono- and
di- derivatives. Immediately after each acid are given the
amides, the anhydride and then the esters. Iso-, alio- etc. compounds
are placed after the normal compound, the prefixes not being con-
sidered.
The headings under each compound are: (1) the specific conduc-
tivity of the pure compound; (2) the ionization constant; (3) the
conductivity in aqueous solution; (4) the conductivity in solvents
other than water; (5) miscellaneous measurements; (6) the conduc-
tivity of the salts.
Numbers in bold face type are bibliographical key numbers, ro-
ferring to the corresponding numbers in the author list. When the
same measurements are published in more than one journal, the key
number is to the most accessible article. In the author list, after the
title of this article are given references to the less accessible articles.
When the value of the ionization constant has been determined by
measurements of the conductivity of the compound, no statement of
the method is made except for emphasis; other methods are shown by
an abbreviation in parenthesis. The abbreviation aq., placed after
the value, shows that the conductivity of the water has not been
subtracted in calculating the value. Second, etc., k, means the
constant of the second, etc. H or OH ion.
Numerical values of conductivity, unless otherwise stated, are for
aqueous solutions; with the obvious exception of those for the specific
conductivity of the pure compound, which can always be recognized
because neither concentration nor dilution is given. If all the refer-
ences to the conductivity in water are desired, look up also the refer-
ences given under the ionization constant, for in some cases these have
not been repeated under the heading, conductivity in aqueous solution.
The dilution in liters is given in parenthesis in its proper place.
Thus, A(32) » 9, shows that the equivalent conductivity at a dilu-
tion of 32 liters is 9 reciprocal ohms, or whatever unit may be used.
The values given for the equivalent and the molar conductivity are
in the unit used in the original article, unless otherwise stated in the
table. Reference to the author list will show what this unit is.
When different values of the ionization constant or of the conduc-
tivity are compared, it is advisable to read in the explanation the
precautions necessary for a proper comparison.
42 TABLES [Abi
Abietic acid« C20H80O2; also given as Ci^HssOs.
Cond. with NaOH; acid of m. p. 153'*-154^ and m. p. 179**;
1017. With NaOH in Et ale; acid of m. p. 167**-172*';
1608.
Acet- see Acetyl- for most compounds; see also Aceto-.
Acetaldehyde. C2H40 = MeCHO.
XX 10* at 0**=1.20; b. p. 20*»-21*'; 1843. Also 1842, 1844. At
15^=1.67; 1844.
kAXlO" at 0**=7.0 (hydro!.); 612. At 1^=5.0 (hydroL); 612.
At 25^ A(13.1)=4.9, (104.8) = 14.3; 969. T not stated; 1843.
In HON, no cond.; 943. In NHs, qual.; 606. In MeNH2, fair
cond.; 637.
Cond. with inorg. acids and bases; 612, 1843. As solvent of
various salts; 1844. Of compound with H2SO8; 969.
Acetaldehyde ammonia in NHs, qual.; 606.
Meta-acetaldehyde. (CsH40)x. x»2 or 4.
In H2SO4; 760.
Para-acetaldehyde. (Paraldehyde). (C2H40)x. x probably is 3.
X XlO^ at 25** is less t^han 3.4; 1106, 1107.
At 15^ A(32) = 0.7, (64) = 1.1; 1741. - 1843.
In H2S, no cond.; 1897. In H2SO4; 760. In NHs, qual.; 606.
As solvent; 1106, 1107.
Acetaldehyde ammonia. C^HrON.
In NHs, small cond.; 606.
Acetaldehyde sulphurous add. C2H6O4S » Me.CHOH.HSOs.
kAXlO at 25**=3.6; diminishes on diln. A (26.2) « 332.7,
(104.8) =338.8, (00) = 378; 959.
Acetaldoxime. (Methyl aldoxime). C2H60N=MeCH:NOH.
xXlO® at 25** is less than 1; b. p. 114**-115** @ 749 mm.; 1848,
1844.
Cond. as solvent of NEt4l; 1844.
Acetamide see Acetic acid amide.
Acetamino- see Acetylamino-
AcetaniUde. C8H90N= MeCO.NHPh.
kB X 10^* at 40.2** =4.4 (catal.); m. p. 115**; 1996.
In HBr, good cond.; in H2S, no cond.; 1897. In HCN, small
cond.; 943. In NH3, fair cond.; 606.
Acetanilino- see Acetylanilino-
r-o~i
Acethydrozamic acid. C2H602N» MeCH.N.OH.
kAXlO^ [at 25** 1=2.8.
Ace] TABLES 48
A(14.5)-0.21, (68.2)-0.7, (oo)-[380]; 18B8a.
Fe.3A, cond. alone, and with HCl; 766.
Acetic add. CiH40s» Me.COsH.
XX 10» at 0** is less than 2; 943. At 15^=5.47; 1844. At 16^;
1419. At 18''»1.2; 1470; also 362, 787, 986, 1967. At
20''; 694. At 25'' is less than 2; 1388; also 44, 763, 908,
1427, 1844. See also 900, 1380.
kAXlO^ at O^'^l.TT; 1144, 1968a, 141. Calculated; 1144. At
2.6°= 1.8; 387. At S^'-l.SS; 1144. At 9.2''»1.79; 1968a.
At 10*'= 1.81; 876, 1144. At 15^-1.85; 1143, 1144. At
17''=1.78 aq.; 164. At 18''=1.82; 93, 94, 1211, 1332,
1341, 1866; -1.86 in 44% Et ale; 613; (colorim.); 1663.'
At 20**= 1.85; 876. At 25**= 1.86; lowest value=1.70, high-
e8t=1.89; 44, 296, 1143, 1144, 1184, 1368, 1370, 1600a,
1639, 1673a, 1968, 1968a, 1971; (catal.); 1043; =1.74 (sapon.
and cond.); 1143; (neutralization); 463; (colorim.); 1729b.
At 30**= 1.87; 876. At 35^=1.83; 1968a. At 40**- 1.80;
876, 1143, 1144. At 50''= 1.74; 1144. At 52"= 1.62; 43, 44.
At 54.3^=1.62; 43, 44. At 55"= 1.46 (action of diastase on
starch); 2002. At 60"= 1.66 (calculated); 1144. At
76"= 1.5; 1391a. At 100"= 1.114; 1332, 1341. At 156"=
0.536; 1332, 1341. At 218"=0.172; 1332, 1341. At 306"=
0.0139; 1332, 1341. T not stated; (colorim.); 278, 961, 1643,
1781, 1866; (precipitation of casein); 693.
Cond. At 0", A(32)=5.3, (1024)=28.0, (oo)=227; 1968a. At
25", A(32)-8.7, (1024)=46.0, (oo)=.364; 1370. At -3"
to +10"; 347. At 0"; 141, 910, 943. At 0"-35"; 1968, 1968a.
At 8"-50"; 1144. At 10"-50"; 876. At 14" and 19"; 838.
At 18" and 52"; 43. At 18"-306"; 1332, 1341. At 35"-65";
888a. See also 94, 146a, 146b, 171, 177, 294, 299, 377, 386,
386, 463, 642, 694, 782, 788, 900, 910, 1094, 1122, 1427, 1496,
1618, 1620, 1637, 1639, 1669, 1673a, 1636, 1747, 1964,
1967.
In HBr; 30, 147a. No cond.; 1897. In HCl; 30, 147a, 223.
Qual.; 1897. In HCN; 943. In HI, no cond.; 147a. In
HsS, no cond.; 147a, 1897. In HNO»; 223. In H3PO4; 223.
In H2SO4; 222, 223, 760. In N2O4, no cond.; 602. In SOs;
1842. In NH3, qual.; 606. In norm.-amyl ale; 787, 788.
In amyl ale; 647. In benzene, no cond.; 1801. In Et ale;
613, 647, 764, 782, 787, 788, 1311, 1791, 1820. In Me ale;
336, 787, 788. In MeNHj, good cond.; 637.
Cond. with inorg. acids; 177, 378, 463, 799, 900, 1184, 1496,
1618, 1718, 1821. With inorg. bases; 171, 294, 299, 463,
1341, 1717, 1718. With inorg. salts; 378, 1888, 1470, 1639,
44 TABLES [Ace
1993, 1994. With other inorg. compounds; 1163, 1386,
1496, 1518. With organic acids; 44, 93, 146b, 463, 1388,
1717, 1718, 1821. With organic ba^es; 44, 146a, 146b, 613,
1011, 1144, 1388. With organic salts; 94, 378, 908, 1280,
1388, 1639, 1673a, 1618a, 1809, 1993, 1994. With other
organic compounds; 46, 799, 1120, 1223, 1311, 1386, 1388,
1669, 1747, 2032. Under pressure of 1 to 500 atmospheres;
at 0^; 220, 1708a; at 0.1'*-40**; 1708; at 14**; 642; at room
temperature; 1427. As solvent; 908, 1280, 1311, 1388, 1669,
1809, (1818), 1844, 1994.
A1.3A; 1088. - NH4.A, at 15*»-40*»; 1143; at 18^-306**; 1332,
1341. Also 146a, 166, 463, 823. In HBr, good cond. ; in PHs,
no cond.; 1646. - Ba.2A, at 0°-36°; 911. Also 1088, 1174,
1673a, 1963a. Cond. alone and with glycocoll; 1086. In
NH3, qual.; 606. - Cd.2A; 881a, 1086, 1088. With glycocoU;
1086. - Ca.2A; 1174, 1673a. In NH3, qual.; 606. - Ce.SA;
1088. - Cr.SA; 1963a. - Co.2A, at 0**-35^ 911. Also 1086,
1088, 1673a, 1963a. With glycocoU; 1086. - Cu.2A; 377,
640, 1086, 1088, 1618a. With organic compounds; 46, 1086,
1669, 1618a. In NHs, qual.; 606. Under pressure of 1-500
atmospheres; 1427. Also 1047. - Fe.3A; 1962. - Gl com-
plex; 1711. - La.3A; 1088. - Pb.2A; 377, 881a, 1088, 1343,
1746, 1747. Also 1047. In NHs, qual.; 606. With PbO;
1386. With organic compounds; 381, 1747. - Li. A; 1367.
In flame; 682. - Mg.2A; 1836, 1963a. Under pressure of
1-500 atmospheres; 1427. - Mn.2A; 1086, 1088, 1737. With
glycocoll; 1086. - Hg.2A; 247, 466, 1088, 1094. With
FeaOs; 466. With HgS; 247. 2Hg.2A in NH,, qual.; 606.
- Ni.2A, at 0**-35**; 911; also 1086, 1088. With organic
compounds; 1086. Under pressure of 1-500 atmospheres;
1427. - K.A, at -21** to +7**; 793. At 35*'-65°; 388a.
Also 94, 164, 166, 171, 294, 299, 377, 463, 688, 966, 996, 1078,
1367. In HCl, HNQs, HsPO*; 223. In H28O4; 222. In
NHs, qual.; 606. In acetic acid; 94, 1280, 1809. In Me
and Et ale; 968, 1280, 1386b, 1807. In glycerol; 1279.
With inorg. compounds; 379, 496. With organic compounds;
94, 381, 1280, 2032. In flame; 682. - Ag.A, at 25'*-60°;
1637. Also 881a, 1111, 1174. Saturated soln.; 666. In
Na.A, soln.; 1331. In NHs, qual.; 606. - Na.A, at 0'*-35'';
632, 924, 1968a. At 10^-50**; 876. At IS^'-SOG^ 1332,
1341, 1341b. At 25*'-60'*; 1637. At 35^-65**; 1963a. At
18** and 52^ 43. At 89^• 1229a. At 25°, A(32)=75.5,
(1024) » 85.0; 1367, 1368a. Also 94, 372, 377, 391, 738, 810,
889, 996, 1199, 1331, 1639, 1717, 1718, 1966, 1968a. In HsS04;
Ace] TABLES 45
228,1834. InHCl, little cond.; in PHs, no cond.; 1646. la
N^, qual.; 606. In acetic acid; 94, 908, 1280. In Me and
Et ale; 335, 391, 491, 1386b, 1390, 1470, 1807. With
inorg. compounds; 796, 810, 1199, 1227. With orgain<^
compounds; 46, 94, 378, 381, 449, 908, 1280, 1639,; 1746,
1747, 1994, 2032. Under pressure of 1-260 atmospheres;
542. In flame; 682. - Sr.2A; 319, 1174, 1963a. Jn flame;
682. - T1.3A, in flame; 682. - UO2.2A cond. alone and
with Na.A; 449, 1963a. - Zn.2A; 377, 1086, 1088. In,
NH», qual; 606. With inorg. salts; 379, 381. With organic
compounds; 381, 1086, 1673a. Under pressure of 1-500
atmospheres; 1427. E.m. f.; 1047.- Zr0.2A; 1620.- Or-
ganic salts; 146a, 146b, 613, 637, 1011, 1143, 1144, 1388,
1791,1801.
Acetic add amide. (Acetaniide). C^HgON^Me.CONHs.
XX 10* at 80**=3.0. At 81**=2.9; m. p. 82^ 1843. At 100° =«
0.43; 1894.
kaXlO" at 25**-0.31 (catal.); 1864 and 1160. At 40.2*'=3.3
(catal.); 1996. At OO^'^^l (inversion); 1880 and 1160.
Cond. at IS**; 1741. At25^ A(32)=0.95; 1729. Qual.; 1904.
In HBr; 33, 1646; qual.; 1897.- In HCl; 1646; qual.; J1897.
- In HI, poor cond.; in HjS, no cond.; 1897. - In NH3;
607, 610. - In MeNHs; 606; qual.; 637. - In SO2; 1842.
CJond. with HCl; 17, 410, 781. - With NaOH; 412, 781. With
ECN and inorg. salts; 1097, 1894. As solvent; 1894.
Hg.2A at 0**; 726. At 25^ alone and with HCl; 1094. Also 963.
- B.HCl at 25^ A(50) =369.9. - 2B.H2SO4; 1864.
Acetic add benzylamide. (Benzylacetamide).
' C9H11ON « MeCO. NH (CHjPh) .
Cond. with HgCU; 1097i
Acetic add bromoamide. (Acetbromoamide).
C2H40NBr- MeCO.NH(Br) .
kA X 10^ at 25^, is less jbhan 1; is dec. in aq.; m. p. 138^.
A(16)» 0.15, due to decomposition.
Nasalt, A(32)=68.2, (1024) = 80.0; 767.
Acetic add chloroamide. (Acetchloroamide).
C2H4ONCI =MeCO.NH(Cl).
Cond. at 25** is due to presei^ce of- HCl; m. p. 110°; 767.
Acetic add cyanoamide. (Acetylcyanoamide).
CsH40N,=MeC0.NH(CN).
kAX 10* at 25^-1.5; 70. - [Quoted?]; 767.
A(24.8)=21.3, (793.6) -102.2, (oo)=.354; 70. ,
Na salt at 25^ A(32)=74.4, (1024)^83.1; 270.
46 TABLES [Ace
Acetic add dimethyl amide. (Dimethyl-acetamide).
C4H90N-MeCO.NMe2.
(3ond. with HCl; 781.
Acetic add anhydride. C4H«08 » (MeC0)2O.
X X 10« at 0°«1.01; b. p. 137**-138^ 1843. At 20**=0.76; 1690a.
At25**-1.18; b.p. ISSMSQ**; 1843; - 1844.
Cond. Showing change to acid; 1600a. As solvent; 1690a, 1844.
As solvent, under pressure; 1690a.
Acetiic add amyl ester. CrHuOs^ MeCC^.CsHn.
In HCl, in HBr and in HI, good cond.; in HsS, no cond.; 1897.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Acetic add iso-butyl ester. C^HisOs^MeCQs.iso-Bu.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Acetic add capryl ester. (Octyl ester). CioHioOs^MeCQs.CsHiT.
In NHs, qual.; 606.
Acetic add ethyl ester. CJEL^Oi-' MeCQs.Et.
X X lO' at 25''»4.5; 941, 1107. T not stated; 306.
In HBr and in HCl, qual.; 16. In NH«, qual.; 606.
Cond. with NaOH; 1879. With Cu oleate; 1669. With inorg.
salts; 941, 1107. Effect of temperature on cond.; 106. As
solvent; 1669, (1818).
Relative basicity in organic solvents; 1061.
Acetic acid glyceryl ester. (Triacetin) . CsHuO^^ (MeCQt)t CsH(.
Effect of temperature on cond.; 106.
Acetic add methyl ester. CsH602« MeCOs.Me.
X X 10» at 25'' is less than 2; b. p. 54''; 1388.
In HBr, qual.; 16.
Cond. with HCl and acetone and glycerol; and with H2SO4;
799. With HNO4; 1669. With NaOH; 1879. Effect of
temperature on cond.; 106. With inorg. and organic com-
pounds; 1388. As solvent; (38).
Acetic add phenyl ester. CsHgOs.
In NHs, qual. ; 606.
Acetic acid propyl ester. C(Hio02.
In NHs, qual. ; 606.
Effect of temperature on cond.; 106.
Acetnaphthalide. CuHuON.
In NHs, qual.; 606.
Aceto- see also Acetyl- and Acet-
Acetoacetic add. C4H6()»» MeCO.CH2.CQtH.
kA X 10*= 1.5 (colorim.) ; 804.
Ace] TABLES 47
Acetoacetic add ethyl ester. CeHioOi-MeCO.CHi.COs.Et.
XX 108 at 25"-4.0; b. p. 174M76° @ 736 mm.; 941. » 170
1669. Also 668.
kAXlO* at 1**-1.9; 1366. At 25**-0.02 (8apon.);-4 (cond.)
662. Also 661. At 35''»5.4; 1366.
At 25% A(32)-0.5, (612)=2.1, (oo)-360; not very accurate
661. - 698, 844, 1823, 1831.
In HBr, and in HI, good cond.; in H2S, no cond.; 1897. In
HON, no cond.; 943.
Cond. In NaOH+HCl; 844. - With inorg. salts; 941. As sol-
vent; 478, 483, 668, (941).
Salts. Fe.A; 766. - K.A. with HgNOs; 149.
Acetoacetic add methyl ester. CeHgOs.
kAXlO^i at 25''»2 (sapon.); 666, 1694.
At25% A(64)-0.26, («>)-[360I; 698.
/3-Aceto-ua-butyric add. (a-Methyl-laevulinic acid).
CeHioOi- MeCO.CH2.CHMe.CO2H.
kAXlO* [at 25^1-3.03; b. p. 153M56^ @ 3 mm.; 902.
7-Acetobutyric add. CeHioOs* MeCO.(CH2)8.C02H.
kA XlO* at 25** -2.2 aq.; b. p. 180** @ 20 mm.
A(32)-9.9, (1024)=52.1, (oo)=376; 1688.
Acetoguanamine. C4H7N6.
ksXlO^i at 40*'»3.06 (catal.); 1996 and 1160. At 40.2**-2.96
(catal.); m. p. 265**; 1996.
Acetol. C»H«02-MeCO.CH20H.
Cond. with NaOH; b. p. 145*^-146^; 976.
Acetone. CsHeO^ Me.CO.Me.
X XlO' at -15**» 0.011; 1863a. At0^«3; 922; -also 906,916,918,
920. At 13''; 1477. At 18**»0.2; 478; also 362, 487, 1066,
1070. At 20**= 1.2; 1690a. At 25*^-1.73; 1844.-2.27;
1843; - also 334, 347, 904, 906, 906, 916, 918, 922, 941, 1388,
1669,1830,1847,1863a. At 15** to 35**; 1477. T not stated;
306, 336, 476, 1620.
At 25^A(2)- 0.017; 1843.
In HBr; 1646; good cond.; 1897. In HCN, no cond.; 943. In
HCl and HI, good cond.; in H2S, poor cond.; 1897. In
MeNH2, poor cond.; 637.
Cond. with HCl and methyl acetate; 799. With inorg. bases;
979, 1036. With H2SOS and Na^SOs; 1636. With HCl
qual.; 1663. With organic acids, bases and salts; 46, 476,
922, 979, 1066, 1388, 1669, 1620, 1844, 1847, 1848, 1863a.
^ith HCl and benzene; 1669. As solvent; 334, 336, (347),
474, 476, (478), 487, (748), 767a, (904), (916), (916), (918),
(920), 922, (941), 1066, 1070, 1286, 1329, 1379, 1388, (1389),
48 TABLES [Ace
1669, 1590a, 1620, 1623, (1681), 1712, 1830, 1841, 1844,
1847, 1848, 1863a. As solvent, under pressure; 1690a.
Relative basicity in organic solvents, (colorim.); 1061.
Acetone-diacetic acid see Hydrochelidonic acid.
Acetone-diozalic acid anhydride see Chelidonic add.
Acetone-dicarbozyHc add. CsHeOs^ CO(CH2C02H)2.
kxXlO^ at 25°-7.9 aq.; diminishes on diln.; m. p. 135**.
ii(21.5)=43.1, (686.7) « 172.2, (a>)«354; 23.
Acetone semicarbazone. C4H90Ns» Mes.C : N.NH.CONHs.
kaXlO^* at 40**-3.29 (catal.); 1160 and 1996. At 40.2**«3.18
(catal.); m. p. 184"; 1996.
Acetonitrile. C2H8N»Me.CN.
XX W at O'^^S.igS; 1843.»39; 1844; - 482, 1846. At 25''»
3.98; 1843;»3.8; 1849; - 482, 1423a, 1842, 1844, 1846.
At 0**, A(32)=0.18; 684, 683.
In HBr; 1646; - qual.; 1897. In HCl; 33, 1646; - qual.; 1897.
In HI, poor cond.; in HsS, good cond.; 1897. In AsCU;
1842. InNH3,qual.; 606.
Cond. as solvent of inorg. salts; 482, 1844, 1846. As solvent of
organic compounds; 482, 767a, 936, 1423a, 1827, 1842, 1844,
1848, 1849.
Acetophenone. (Methylphenylketone). CgHgO* Me.CO.Ph.
xXlO^ at 25.°-1.8; 1106, 1107;=2.2; 1323; - 1669.
In HBr, good cond.; in HsS, no cond.; 1897. In NHe, qual.; 606.
Cond. With Cu oleate; 1669. As solvent of inorg. salts; 1106,
1107, 1323. As solvent of organic compounds; 482, 1106,
1107, 1669.
p-Acetophenone-azo-diethyl-aniline.
Ci8H2iON8= MeCO.CeH4.N,.CeH4.NEt2.
H ion concentration -5 X 10"* (colorim.); m. p. 162**-163**; 1730,
p-Acetophenone-azo-diethyl-anifine ozime. C18H2SON4.
H ion concentration is less than 5 X 10~* (colorim.); m. p. 199**-
200**; 1730.
p-Acetophenone-azo-dimethyl-anifine. CieHirONs.
H ion concentration is less than 5 X 10"^ (colorim.) ; m. p. 203**-
204**; 1730.
p-Acetophenone-azo-phenylaniline. CsoHirONj.
H ion concentration is less than 5x 10~^ (colorim.); m. p. 184**-
185**; 1730.
Acetophenone ozime. (Methylphenylketonme).
C8H90N=Me.C(N.OH).Ph.
kxX 10* at 25**=3.7 [aq.?]; 1748. - 733.
At 25^ A(128)*0.24, (1024)^0.68, (a>) = [356]; 1748.
/3-Acetopropionic add see Laevulinic add.
Acal TABLES 49
Acetoziine. CH7ON- Me2C : NOH.
kAXlO" at 15*^-4.05 (catal.). At 18^-4.6 (catal.). At 22^-
6.39 (catal.). At 25°=-6.b (catal.). At 28.07**-6.89
(catal.). At 35*-8.55 (catal.). At 40*'-9.9 (catal.); m. p.
59.7**-60.0**; 1160.
kaX 10" at 15**=- 2.86 (catal.). At IS^'-S.T (catal.). At 25**=
6.5 (catal). At 35**= 13.0 (catal). At 40**= 19.0 (catal);
1160. At 40.2**= 17.5 (catal.); m. p. 61**; 1996.
At 25^ A(32)-0.07, (256)-0.17, (a>)-[3661; 1748.
In NQi, no cond.; 604.
o-Acetozy-benzoic add. (Acetylsalicylic acid. Aspirin).
C9H804= MeCO,O.C6H4.C()2H.
kAXlO* at 25**=3.33. A(64)-48.4, (1024) = 151.5, (oo)-351;
1371.
m-Acetozy-benzoic add. C9H8O4.
kAXlO* at 25**-9.86. A(256)=51.5, (1024)-95.2, (a>)=351;
1371.
p-Acetozy-benzoic acid. C9H8O4.
kAXlO* at 25*'-4.22. A(64)-17.8, (1024)-64.4, (oo)-351;
1871.
p-Acettoluide. C9H11ON.
In NHs, qual.; 606.
Acettolylglyctne see Acetyltolyl amino-^cetic add.
Aceturic add see Acetylamino-acetic add*
Acetyl- see also Acet- and Aceto-
AcetyUcetone. C6H8()2-MeCO.CHj.COMe.
xXlO^ at 0''=2.02; 1844. At 25**=2.79; 1844; - 1669, 1843;
- qual.; 1904.
kAXlO» at 25**-4.7 aq.; 1688;=150; 698.
At 25^ A(32)=0.47 (a>)-378; 1688. - 844.
In Et ale. qual. ; 1298.
Cond. WithNaOHandHCl, qual.; 844. With boric acid; 766.
With Cu oleate; 1669. As solvent; 1669, 1844.
Salts. A1.3A; 756. - G12A, A(256) = 1.5, (512) = 1.7; 388.
- Fe.3A. - La.3A; 766. - Na.A, A(32)-82.6, (1024)-
109.0; 388.
Acetylamino-acetic add. (Aceturic acid. Acetyl glycine).
C4H704N= (MeCO)NH.CH2.C02H.
kA X 10^ at 25**= 2.3; aq. used for soln. was impure.
A(32)-29.2, (1024) = 133, (oo)-355; 1370.
Cu.2A, at 25^ A(32)=42.7; 1086.
o-Acetylamino-benzoic add. CoHoOsNs
(MeCO)NH.QH4.C02H. [(MeC0)NH-2; COjH-l].
50 TABLES Ace
IcaX 10* at 25^-2.36.
A(128)=55.7, (1024)-135.0, (oo)-350; 1871.
Na.A, at 25**, A(32)= 62.4/ (1024) -74.1; 1867.
m-Acetylamino-benzoic acid. CgHsOsN.
kAX 10* at 25*^=8.5.
A(256)-47.9, (1024) -88.8, (oo)-350; 1871.
p-Acetylamino-benzoic acid. CgHoQsN.
kAX 10* at 25°= 5. 17.
A(256)-37.9, (1024)-71.8, (oo)-350; 1871.
4-Acetyla2nino-xii-phtha]ic add. CioHoOsN-
(MeCO)NH.C6H3(C02H)2. [C0,H-1,3; MeCONH-4].
kAXlO* [at25°]=7.9; 1914;-11; 1913.
Second kAX 10*= 1.3; 1913.
lAt 25^1, /i(2234)»287, («)-375; 1913.
a-Acetylamino-p-phthalic add. CioHsOeN. [C02H»1,4].
kA X 10* at 25**»9.8; m. p. 355**. The value of k is probably too
high, on account of influence of the second carboxyl group;
1684. Quoted in 1914.
m(600) = 197.7, (1200) -248.5, (oo)«375; 1684.
2-Acetylaiiiino-p-phthalic acid 4-mono methyl ester.
CuHuOsN. [C(WE[-l;C02Me-4].
kA X 10* [at 25°]-7; m. p. 163**; not entbely pure; 1684. Quoted
in 1914.
m(700)-187.7, (1400)-229.4, (oo)=374.4; 1684.
Acetylanilino-acetic add see Phenylacetylamino-acetic add.
a-Acetylanilinobutyric add.
Ci2Hi604N=Et.CH.N(Ph)(MeCO).C02H.
kA X 10* at 25*^-1.09; m. p. 119^
A(320)-57.8, (1280) -109.6, (oo)=348; 1840.
/3-Acetylanilino-i5a-butyric add.
Ci2Hi50jN-(Ph)(MeCO)N.CH,.CHMe.C02H.
kAX 10* at 25**-2.9; m. p. 174**.
A(295)-29.7, (1180) -58.7, (oo)x:348; 1840.
a-Acetylanilino-propionic acid.
CiiHi80»N-Me.CH.N(Ph)(MeCO).C02H.
kA X 10* at 25**- 1.25; m. p. 143**.
A(128)-41.8, (1024)-105, (oo)-352; 1840.
Acetyl bromide. C2H8OBr-MeCO.Br.
X X W at 0**-2.09. At 25''-2.38; 1843, 1844.
In HBr and HCl, good cond.; in HI, no cond.; 1897.
Cond. as solvent of NEtil; 1844.
Acetyi-bromoanilino-acetic add see Acetyl-bromophenyl-amino-
acetic add.
Ace] TABLES 51
Acetyl-bromophenyl amino-^cetic add. (Acetyl-bromoanilino-acetic
acid. Acetyl-bromophenyl glycine).
CioHio04NBr-(MeCO)(C6H4Br)N.CH2.CQ|H.
kxXlO* at 25*'-2.85; m. p. 176**-177^
A(300)=89.0, (1200)«156, (oo)=355; 1840.
Acetylcarbopyrrolic see Methylpyrrylketone carbozylic.
Acetyl chloride. CaHsOCU M eCO.Cl.
xxl(f at 0''»3.52; 1844. At 25''»4.21; 1844, 1848.
In HBr and HCl, good cond.; in HI and HsS, no cond.; 1897.
In HON, fab cond.; 943. In SO2; 1842.
Cond. As solvent of NEtil; 1844. With allyl thiocarbimide,
qnal.; 1223.
Acetylcyano- see Cyanoaceto- and Cyanoacetyl-
Acetylcyanoaxnide see under Acetic acid amide.
Acetyldibromo-acryHc acid. CsH^O^Br^ =» MeCOCBr : CBrCOsH.
kA X 10* at 25**=6.2 aq.; m. p. 78'*-79**; diminishes on diln.
A(90.3)=25.6, (1444.8) =89.1, (oo)=365; 23.
Acetylene. CiHs » HC ! GH.
kA X 10^0 at 18^ is less than 1.3; 1883.
Cond. At 0°, no cond.; 895, 902. Of liquid acetylene alone
and with Et ale. and ether, qual. ; 1234. Qual. ; 273.
In MeNHs, no cond.; 637.
Acidity shown by solubility experiments; 181; see also 182.
Acetylene-dicarboxyUc add. C4H2O4 » CO2H. C ': C. COsH.
Second kx too great to measure by inversion; 1838.
At25^M(64)=467, (1024)=721; 1372.
2Na.Aat25**, A(32)=84.2, (1024) = 101.4; 270.
Acetylene tetrachloride see Tetrachloro-ethane.
Acetylglydne see Acetylamino-acetic acid.
Acetylmalonic add diethyl ester. CqHmOs^ MeCO.CH(COsEt)s.
No cond. in aq.; 698.
Acetylmalonic add dimethyl eater. ' CtHiqOs.
Cond. increases on standing; at 25^, /i(128)»13.7 after 15
minutes standing; 698.
N-Acetylmethylamino-p-phthalic add.
CuHuOfiN- (MeCO)NMe.CeH8(CQ2H),.
IcaX 10* [at 25^] is less than 1.26; increase on diln. is due to the
second carboxyl group; m. p. 255^.
m(700)- 223.5, (1400) =280.4, («)« 374.4; 1684.
Ace^-/3-naphthalino-iso-butyric add see Acetyl-|3-naphthylamino-
i$o-butyric add.
Acetyl-a-naphthylamino-acetic add. (Acetyl-a-naphthyl glycine).
Ci4HuO«N- (MeCO)(CioH7)N.CHa.C02H.
S2 TABLES [Ace
kA X 10* at 25** -2.07; m. p. 156**.
A(283)=74.7, (1132)- 132, (oo)-348; 1840.
Acetyl-zS-naphthylamino-acetic add. (Acetyl-|3-naphthyl glycine).
CmHuOjN.
kx X 10* at 25** -2.41; m. p. 172^
A(500)-1D0.7, (1000)-135, (oo)»348; 1840.
.Acetyl-/3-iiaphthylaiiiino-ua-butyric acid. (Naphthylamino-iso-buty-
ric acid acetyl derivative).
CieHnOjN- (MeCO)(CioH7)N.C8H«.C02H.
kx X 10* at 25*^-2.2; m. p. 188^
A(800)=43.0, {1600)-59.4,(oo)-347; 1840.
Acetylphenylbutyric add see Phenylacetyl-butyric add.
Acetylphenyl glydne see Phenyl-acetylamino-^cetic add.
Acetylphenylglydne-o-carbozylic add.
CiiHu05N-C02H.CeH4.N(COMe)(CH,.C02H.)
HaXIO* at 25**- 1.05; m. p. 213**, varies from 210** to 215^ ac-
cording to manner of heating; 1245, 1814.
At 25°, A(79.4)-92.5, (oo) = 373; 1246.
Acetylpheiiylglydne-o-carbozylic add esc mono ethyl eater.
CisHibOsN - Et02C.C6H4.N(COMe) (CHa.COjH).
kxXlO* at 25**-3; m. p. 132**; 1246, 1814.
A(72.3)-51.8, (oo)-371; 1246.
Acetylphenylglycine-o-carboxylic add ezo mono ethyl eater.
Ci8Hi606N-C02H.C6H4.N(COMe)(CH,.C02Et).
kxX 10* at 25**-3.8; m. p. 87**; 1246, 1814.
A(40.8)-43.6, (oo)=371; 1246.
^seiido-Acetylpyrrolecarbozylic add see 2,6-Methylpyrrylketone car-
bozylic add.
Acetylsalicylic add see o-Acetozy-benzoic add.
Acetyltoluidino-acetic acid see Ace^tolyl amino-acetic add.
a-Acetyl-o-toluidinobutyiic add.
Ci3Hi704N-MeC«H4.N(MeCO).CHEt.C02H.
kx X 10* at 25**-9.2; m. p. 116^
A(290) = 52.2, (1160)=97.2, (a>) = 348; 1840.
/3-Acetyl-o-toluidino-tso-butyric add.
Ci3Hi708N-MeC6H4.N(MeCO).CH2.CHMe.C02H.
kxX 10* at 25**= 2.1; m. p. 2l9^
A(480)-33.5, (960)=44.6, (oo)«348; 1840.
a-Acetyl-p-toluidinobutyric acid. CisHnOsN.
kxX 10* at 25**= 1.07; m. p. 149^
A(300)-56.4, (1200)-105, (oo)-348; 1840.
a-Acetyl-p-toluidino-iio-butyric acid. CuHnOsN.
kx X 10* at 25**-9.5; m. p. 146^
A(280)-52.0, (1120)-96.3, (oo)-348; 1840.
Aco] TABLES 58
0-Acetyl-p-toluidino-wo-btttyric add. CuHitO^N.
kAX 10* at 25^-2.29; m. p. 206^
A(386)»31.2, (1544) » 59.6, (oo).348; 1840.
a-Acetyl-o-toluidinopropioiiic acid.
CttHifiOiN- (MeCflH4)N(MeCO).CHMe.C02H.
kAXlO* at 25*'=1.04; m..p. 177^
A(300)-55.7, (1200)- 103, (oo)-348; 1840.
a-Acetyl-p-toluidinopropioiiic add. CuHisOsN.
kA X 10* at 25**= 1.04; m. p. 166^
A(300)=55.7, (1200) -103, (oo)-348; 1840.
Acetyl-o-tolyl amino-acetic add. (Acetyltoluidino-acetic acid. Acet-
yl-o-tolyl glycine).
CuHiaOiN- (MeC«H4)N(MeCO).CH2.C02H.
kAX 10* at 25*^-2.19; m. p. 210^-212**; 1840; m. p. 214**; 1246.
A(194)=:65,l, (1552) = 152.3, (oo)-352; 1840.
Acetyl-p-tolyl amino-acetic add. . (Acetyl-p-tolyl glycine).
CiiHwOjN.
kAX 10* at 25**=2.19; m. p. 175M76^
A(200)=66.5, (800) = 120, («>)-352; 1840.
Acetyltolyl glycine see Acetyltolyl amino-acetic add.
Aconitic add. CeH^Oe- C02H.CH2.C(C02H) : CH.COjH.
kAXlO* at 19^-1.3 aq.; 164. At 25**=1.36; m. p. 180M83**;
1839.= 1.58; 1859. [It is possible that the disagreement of
the values of k here, is due to the fact that different aconitic
acids were measured. See under Aconitine.]
Second kAXlO*-3.5 (cond.); 1911.
At 25^ /i(32) = 66.4, (1024)=251, (oo)=353; 1839. /i(28.1) =
67.0, (899.2) =249.0, (oo)-353; 1859. Also 172.
Cond. with KOH; 172.
In NHs, qual. ; 606.
Salts. 3Mg.2A; 1836. - 3K.A; 164, 495. - 3Na.A at 25^
/i(32)=81.8, (1024) = 109.6; 1367.
^setfcfo-Aconitic add. (as-^an8-Trimethylene-l,2,3-tricarboxylicacid).
CeH^Oe.
3 Na.A at 25**, /i(32)=84.3, (1024) = 113.9; 1369.
Aconitine. CssHisOuN and C84H47O11N. [The composition of aconi-
tine from different sources varies, depending apparently, both
on the species and also on the locality in which the plant
grows. See Dunstan, Henry, Jour. Chem. Soc. 87, 1650,
(1905). See F. O. Taylor, Jour. Indust. Eng. Chem. 1, 549,
(1909), for references to recent literature on this subject.]
ks X 10« at 15**= 3 (hydrol.) ; 1779.
In HCN, small cond.; 948.
B.HCl at 25^ A(32)=72.4, (1024)=83.9; 270.
54 TABLES [Act
Acridine. CuH^N.
B.Mel; 763.
Acridine Yellow. (2,7-Dimethyl-3,6-diamino-acridine). CisHuNt.
B.HCl at 25^, A(1024)-86.5; 882.
AciyUc add. CsHiOs^ CHs: CH.CO2H.
kx X 10^ at 25** » 5.6; aq. used for soln. was impure.
A(32)-14.7, (1024)«73.0, (oo)=360; 1371.
Na.A at 25^ A(32)-71.0, (1024)=81.7; 1368a.
Adipic add. C6Hio04» C4H8(COsH)2.
kA X 10* at 18^=4.2, (colorim.); 1663. At 26^=3.65; m. p. 147*^;
279. This acid is probably the purest that has been meas-
ured. The other measurements approximate 3.75; 1371,
1638, 1810.
Second kAXlO^» 3.2, (inversion); 1335;»2.4; 1638.
At 25^ m(32)-11.9, (1024-61.7, (oo)-352; 279.
Cond. with organic acids; 1638.
2Na.A, at 25**, A(32)-75.7, (1024)-90.9; 270.
Adipic add anhydride. CeHsO).
Cond. of soln. showing change to acid; m. p. 98^; 1810.
Adipic add mono ethyl ester. C8Hi404» C4H8(C02H) (COsEt).
kx X 10* at 25**= 2.5 (?), not perfectly pure.
A(93.0) = 17.3, (1488.0) « 57.1, (oo)«351; 1869.
Alanine see Aminopropionic add.
Alaninetoluric add see Methylbenzoyi amino-propionic add,
Alanyl-aminoacetic add. (Alanyl glycine).
CjHioOjNj- MeCH(NH2)CO.NH.CH2.CQiH.
kAXl08at25**-1.8(catal.).
kB X 10^1 at 25^=2 (catal.); 619, 622.
Cond. with NH4OH and HCl; 622.
Alanyl glycine see Alanyl-aminoacetic add.
Albumin; egg albumin etc. [The references are not complete.]
X at 18** is of the order of 1 XlO"*^; 1226. At 16% 25** and 42**;
2032.
Cond. in aq.; 1207, 1226a, 1268, 1289a, 1973a, 1983, 2032. See
also 1393, 1394, 1396, 1396. Qual.; 1618c.
Cond. with inorg. compounds; 62a, 617a, 724a, 1137a, 1289b,
1973a, 1983. Qual.; 1618c. With organic compounds; 62a,
614a, 724a, 1289b, 2032. Cond. not affected by radium;
2031. H ion concentration; 376a, 1268b, 1269c, 1639b.
See also Blood.
2-Aldehydo-3-nitrobenzoic add.
C8HBOBN=CHO.CeH3(NO»).CQiH. ICHO-2; N0»=3;
CQ2H=1.]
Am TABLES 66
kAXlO* [at 25^-1.3; m. p. 156M57^
A(128)=4.8, (1024)-13.6, (oo)-378; 1684.
2-Aldehydo-5-iiitrobenzoic add. CgHsOsN.
kAX 10* at 25*'=1.0; m. p. 159M60**; k diminishes on diln.
A(128)=40.5, (1024) =-101.8, (oo)=378; 1684.
AHzarin. (1, 2-Dihydroxy-anthraquinone). Ci4H804»Ci4H60s(OH)2.
kAXlO' at 18**-19^-8.8 (colorim.); 1661, 1662.
Resistance; 983a.
In NH«, qual. ; 606. - In MeNH2, small cond. ; 637.
Alizarin cyanin see Pentahydroxy-anthiaquinone.
Alkali Blue. [Structure not given. Probably it is triphenyl-p-
rosaniline mono sulphonic acid.] The purity of the com-
pound was doubtful.
Na salt at 90^ /i(200)- 212.4, (800) » 242.4; 976a.
Anantoin. C4H«08N4.
kAX 10» at 25** =1.17 (catal.); 1996.
Alio- see under head of next word, e. g. allocinnatntc add, see under
ano-Cumasrdc add.
Anophanic add amide. (Biuret). C2H6O2N80NH2.CO.NH.CO.NH2.
In HCN, small cond.; 948.
Cond. with HgCt; 1097.
Allozan. C4H2O4N2.
kAXlO'at25*»=2.3; /i(64)-2.2; 1996.
At 25% m(32)-16.6, (1024) -25.2; 1748.
Hg salt; 963.
Allozantine. C8H«08N4.
At 25**, m(256)=46.4, (1024) =45.0; 1748.
In NH8, qual. ; 606.
AUjIacetic add. (7, 5-Pentenoic acid).
C6H802=CH2:CH.CH2.CH2.CQ2H.
kAXl0^at25*'»2.13; diminishes on diln.; 571; - 664.
A(32)=9.9, (1024)=50.2, (oo)-380; 671.
Na.A at 25% A(1024 - 32) = 10 - 11; 671.
Any! alcohol. C8H«0=CH2:CH.CH2.0H.
XX 10« at 25^=6.5; 1106, 1107.
In HBr; 29. In NHs, qual.; 606.
Cond. with oxalic acid; 45. As solvent; 834, 1106, 1107, 1626.
Allyl amine. C8H7N»CH2:CH.CH2.NH2.
kB X 10* at 0^-3.85. At 25**»4.6; 776;=5.7 aq.; about 16% too
high; 271. At 30^-4.84. At 35^-5.00. At 40^=5.10. At
46**- 5.06; 776.
At 25% m(32)-8.9, (256)-23.5, (oo)-209; 271. At 0% 501.
Cond. with KCl; 601.
B.HCl at 25% A(32)-97.6, (1024) -109.2; 270.
56 TABLES [AU
l-AUyl-i-hydrozy-S-mefhozy-benzene see Bugenol.
AUyl iodide. C8H5l-CHs:CH.CH2.I.
In SQ2, cond. is very smaU; b. p. 102-102.6*'; 1829, 1842.
AUylmalonic add. C6H8O4- CH2 : CH.CH«.CH(C0sH)2.
kAX 10» at 25^-1.54; m. p. 102^
/i(32)-70.9, (1024) =249, («>)-356; 1888.
p-Allyl phenol methyl ether see Anethole.
Allylpropyhnalonic acid. C9HMO4- CH2 : CH.CH2.CPr(CQtH)2.
kxXlO'^O.S; diminishes on diln.; m. p. US'*; 828.
/i(32)-147.9, (612)=291, (oo)-367; 831.
Allyl-tso-propylmalonic acid. C9HMO4.
kAXlO^«1.46; diminishes on diln.; m. p. 107.5°, varies with
mode of heating; 112.5° was the highest obtained; 828.
/i(32) = 171.3, (512)-307, (oo) = 351; 831.
Allylsucdnic acid. C7Hio04=C02H.CH2.CH(CH2.CH:CH2).C02H.
kx X 10* at 26°= 1.09; m. p. 92°-93°.
/x(32) = 20.3, (1024)=98.4, (oo)=353; 1838.
Allyl thiocarbimide. (Allyl mustard oil). C4H6NS-C8H6.NCS.
X X 108 at 26° is less than 4.3; b. p. 150.0° @ 737.8 mm.; 939;=
800; 1223.
In NHs, qual. ; 606.
Cond. with organic compounds, and as solvent; 1228. - 939.
Allylthiourea. C4H8N2S.
In NHs, qual. ; 606.
Allyltriethyl- see Triethyl-allyl-
Almond oil. [The references to this are not complete.]
X at 24°; 1010.
Aluminum.
Complex oxalate; 1615, 1616.
See also the following compounds.
Aluminum acetylacetone see under salts of Acetylacetone.
Aluminum bromide complexes.
AlBrs in EtBr; 1437. - AlBrs in nitrobenzene; 1444a. - AlBrs
in Br, CS2 and CHCI3, no cond. ; 1446.
AlBr8.3C6H6 and AlBr8.3C7H8 in toluene; 1314. - AlBr8.Et20 in
Br, CS2 and CHCls, moderate cond. ; 1446. - AlBr6C2H6BrCS2
in Br; 1446; in EtBr; 1437. - AlBr^CSs in Br; 1446.
Aluminum chloride.
Cond. in various organic compounds; 1893.
Aminoacetic acid. (Glycine. Glycocoll). C2H6Q2N=NH2.CH2.C02H.
kx X 101® at 18°= 1700 aq.; 164. At 25°- 1.8 (hydrol.) ; 1160 and
1984. =3.4 (hydrol.); 1984 and 890.
ka X 10i« at 25°=2.8 (hydrol;) ; 1984 and 890, 1160. - (Colorim.) ;
1773, 1775. At 60°- 28 (inversion); 1880 and 1160.
Ami] TABLES 67
At 18^ A(100)»1.13, (160)=1.45, (cx>)=278; 164. At 25%
A(16)-0.05; 690. Also 89, 146b, 1027, 1619, 1874.
In NHs, qual. ; 606.
Cond.; alone, and saturated with CO2; 146b, 1619. With NaOH
and HCl; 690, 1318. With CuSO*; 88, 89. With Ba, Cd, Co,
Cu, Mn, Ni, and Zn acetates and with HCl. Qual. with
aminopropionic and piperidinoacetic acid; 1086. With or-
ganic acids and esters, 146a, 146b. E. m. f.; 1639b.
Cu.2A; 1087. - Hg.2A; 1094; also 963. - K.A alone; with HCl;
164.- Na.Aat25°,A(32) -73.6, (1024) = 84.2; M(32) = 76.2,
(1024) = 102.0; 1984. See also 1639b. - B.HCl at 25% A(32) -
106.4, (1024) = 117.4; M(32)-183.0, (1024) = 352.3; 1984;
- 1864. Effect on inversion of sugar; 1880. - 2B.H2SO4;
1864.
Amlnoacetic add anhydride. (Diketopiperazine. Glycine anhy-
dride). C4He02N2.
kaXlO" at 18^=1.8 [hydrol.?].
Cond. with NaOH and HCl; 623.
Aminoacetic add ethyl ester. C4H9O2N » NH2.CH2.C02Et.
kBXlO« at 15''-18''=9.7 (colorim.); 1776. At 25^ is stronger
than the methyl ester; 891. Cond. with the acid; 146a.
Amlnoacetic add methyl ester. CSH7O2N.
kB X10» at 25°= 2.2 (catal.); 890.
Aminoazobenzene. CuHnNg^ Ph.N : N.CCH4.NH2.
knX 10^' at 25''»9.5 (part.); 648. B. Acetate; 146a.
Aminobarbituzic add. (Uramil). C4HSO8N8.
In NHs, qual.; 606.
Aminobenzene solphonic add see Aniline sulphonic add.
o-Aminobenzoic add. (Anthranilic acid).
C7H7O2N-NHa.C6H4.CO2H.
kxXlO* at 0**=0.55. At 7.5''-0.66; 1968a. At 15^=0.865
(sapon.); 1160. At 17**= 0.99 aq.; 164. At 18^=0.88 - 1.1
(colorim.); 1663. At 25''= 1.04 (catal.); 414;= 1.06 (catal.);
1160; also 866. (Colorim.); 496, 1773. Electrical con-
ductivity measurements give values of k increasing on diln.
The mean for v(64)=0.66, v(1024) = 0.96, v(2048)=0.91;
164, 1371, 1868, 1968, 1968a, 1984. At 35''=1.25 (sapon);
1160; (cond.); 1968a. At 40^=1.35 (sapon.). At 45^-1.44
(sapon.); 1160.
kaXlO" at 12.42''=0.62 (catal.). At 13.1°=0.66 (catal.). At
14.1*'=0.72 (catal.); 1160. At 25''=1.35 (catal.); 414, 1160;
(part.); 648; (hydrol.); 1984. At 25.75^=1.45 (catal.). At
34.15*^=2.22 (catal.). At 36.77^=2.64 (catal.). At 36.91°=
2.69 (catal.). At 40**=3.16 (catal.); 1160.
58 TABLES [Ami
Cond. At 16^ to 45^ 1160. - At 0^ to 35^ 1968. At 25^ A(64) -
7.2, (1024)=:33.5, («)=355; 1371. Also 170.
In HBr, no cond.; 30. In NHs, qual.; 606.
Cond. with KOH; 170.
Na.A, at 25^ A(32)»67.8, (1024) -78.5; 1984, 1368a, 1968a.
- B.HCl, at 0^ 177. At 17**; 164. At 25% A(32)- 100.2,
(1024) = 111.2; M (32) -194.5, (1024)=360.8; 1984.-B.HNQ,;
177.
0-Aminobenzoic add ethyl ester. C9HiiOsN-NHa.CeH4.C02Et.
kBXlO"=1.5 (catal.); (B.HCl has m. p. 168''); 414.
0-Aminobenzoic add methyl ester. C8H9O2N.
kBXlO«-1.7 (catal.); (B.HCl has m. p. 135^); 414.
m-Aminobenzoic add. C7H7O2N - NH2.C6H4.CO2H.
kx X 10* at 17''=0.99 aq.; 164. At 25^=1.63 (catal.); 414;-1.67
(catal.); 856. - T not stated (colorim.); 1773. Electrical
conductivity measurements give values of k increasing on
diln. after an initial diminution. The mean for v(64)— 1.0,
v(1024)-l.l; 164, 1371, 1868, 1984. See also 1374.
kB X 10^1 at 25*'- 1.3 (catal.); 414, 1984 and 1160.
At 25% A(64) = 9.4, (1024) -35.2, (cx>) = 355; 1984. Also 170.
In NHa, qual. ; 606.
Cond. with KOH; 170.
Na.A at 25^ A(32)-65.9, (1024) -75.7; 1984, 1368a. - B.HCl;
164. At 25% A(32)-97.4, (1024) - 108.4 ; M (32) -128.9,
(1024) -269.9; 1984.
m-Aminobenzoic add methyl ester. C8H902N-NH2.C6H4.C02Me.
kBXlO" at 25''=4.4 (catal.); 414.
p-Aminobenzoic add. C7H7O2N - NH2.CeH4.COsH.
kxXlO* at O'^-O.BS. At 10.2*'-0.95; 1968a. At 17''-1.2 aq.;
164. At 18''=0.99 (colorim.); 1663. At 25*'=1.2 (catal. and
hydrol.); 866, 890 and 1984. - T not stated (colorim.); 1773.
Electrical conductivity measurements give values of k in-
creasing on diln. The mean for v(64)=0.71, v(1024) = 1.06,
v(2048)-1.13; 1371, 1868, 1968, 1968a, 1984. At 35''-1.2;
1968a.
kB X 10« at 25^=3 (hydrol.); 1984, 890; -2.3 (corrected); 1160.
At 25% A(64)-7.5, (1024)-35.0, (oo)«355; 1371. At 0^-35*^;
1968. At 17^ 170.
In NHg, qual.; 606.
Cond. with KOH; 170.
KA; 164. - Na.A at25^ A(32)-66.5, (1024)=77.0; 1984. -
B.HCl; 164, 1984. At 25^ A(32)-98.7, (1024)-109.7;
M(32)- 170.2, (1024) =344.2; 1984.
Amq TABLES 69
p-Aminobenzoic add efhyl ester. C9Hu02N.aNH2.C6H4.CQiEt.
ka X 10^2 at 25^=2.88 (catal.); m. p. 91°; 890.
p-Aminobenzoic add methyl ester. CsH^OsN.
kaXlO^* at 25°«2.42 (catal.); m. p. 112*^; 890.
o-Aminobenzoyl-formic add. (Isatinic add. Isatoic acid).
C8H7O8N-NH2.CeH4CO.CO2H.
Na.A, with HCl, cond. on standing; 443.
o-Aminobenzoyl-formic add anhydride. (Isatin). C8H6O2N.
Cond. of aq. soln. too small to measure; 733, 754.
In pyridine, at 25^ m(32)=0.02; 764.
Na salt, cond. on standing; 443.
p-Aminobenzyl solphonic add. CrHgOsNS « NH2.C6n4.CH2.SO8H.
kAX 10^ at 25*^=2.34. A(128) = 18.9, ( 1024) « 50.6, { 00) =356; 492.
'y-Aminobutyric acid. (Piperidic acid).
C4H9O2N = NH2. (CH2)8.COaH.
kAXlO" at 25**=3.7 (hydroL).
kB X 10^0 at 25°= 1.7 (hydroL),
At 25% A(32) is about 0.2.
Cond. with Cu acetate.
Na.A at 25% M(64)«94.8, (128) = 102.5; A(64)=74. - B.HCl at
25% M(64) = 123.1, (256) = 149.5; A(64) = 104; 1086.
8-Aminocaffeine. (6-Aminocaffeine. l,3,7-Trimethyl-8-amino-2,
6-dioxy-purine). C8HUO2N6.
kB X 10" at 40''=4.8 (catal.); 1995 and 1160.
Aminocaproic add. (Leucine).
C6Hi802N = Me2.CH.CH2.CHNH2.CO2H.
kAXlO^o at 25^-1.8 (hydroL); 1160 and 1984.=3.1 (hydro!.);
1984.
kB X 10" at 25''=2.5(hydrol.) ; 1160 and 1984. - (Colorim.) ; 1776.
In NH8, qual.; 606.
Cond. with CO2, with inorg. and organic acids and bases, and
with esters; 146a, 146b.
NH4.A; 146a. - Na.A at 25*^ A(32)=62.4, (1024)=73.4; M(32) =
67.8, (1024) =97.6; 1984. - B.HCl at 25% A(32) = 95.4,
(1024) = 106.4; M(32) = 177.9, (1024)=352.5; 1984. - (hy-
droL); 1776. B.Acetate; 146a.
Aminocaproic add ethyl ester. C8H17O2N.
Cond. is greater than that of the acid; 146b. Cond. with organic
acids; 146a, 146b.
S-Amino-S-chlorobenzoic acid.
C7HeO2NCl-NH2.C6H8Cl.CO2H. [CQ2H=1].
kAX 10*=6.6; increases on diln.; m. p. 158**.
A(64.1)=63.4, (1025.8) =209.0, («)=378; 846.
60 TABLES [Ami
S-Amino-B-chlorobenzoic add. CVH^OsNCl.
kxX 10*^=9; increases on diln.; m. p. 188^-188.6**.
A(64)=21.8, (1024)«99.2, {cx>)-378; 79.
2-Amino-4-chlorophenol. CeHeONCl-NHa.CeHgCl.OH. [OH-1].
Cond. with NaOH alone, and with HCl; 1508, 1718.
4-Amino-2-chlorophenol sulphdnic add.
C«H604NC1S=(NH2)(C1)C5H2(0H)(S08H).
kAXlO«at25''=8.22.
m(128)-34.5, (i024)=88.9, (a>)=354; 492.
2-Amino-4,6-dimtro-phenol. (Picramic acid). CeHsOsNs.
Cond. in Et ale. alone, and with NaOH; 1508, 1718.
Aminoethyl- see Ethylamino-
Aminoformic acid see Carbamic add.
d-Aminoglutaric add. (Amino-normo^pyrotartaric acid. d-Gluta-
mic acid). C6H»04N-C02H.(CH2)2.CH(NH2).C08H.
kx X 10^ at 25''«4.12 (catal.) ; 855.^4.75; increases on diln.; 1838.
m(32)-9.6, (1024) = 69.6, (a>)=352; 1838. At 39.4**; 146b.
Cond. with organic acids; 145a.
d-Aminogiutaric add ethyl ester. C7H18O4N.
Cond. with organic acids; 145a.
macf.-Aminogiutaric add. (inod.-Glutamic acid.) C6H9O4N.
k^XlO^ at 25^=4; increases on diln.; m. p. 198**; 1838, 1824.
m(32) = 9.7, (1024)=69.9, («)=352; 1838.
Amino-hydrodnnamic add see Phenyl-aminopropionic acid. .
p-Amino-2-hydrozy-benzoic add. (p- Aminosalicylic acid). C7H7O3N.
Cond. alone and with NaOH; dec. above 200**; 1508, 1718.
8-Amino-2-hydrozy-5-8ulphobenzoic add. (3-Amino-5-sulphosalicylic
acid). C7H7O6NS.
Cond. alone and with NaOH; 1508, 1718.
Aminoisethionic add see Taurine.
Aminomalonic acid. C8H5O4N -= NH2.CH(C02H)2.
kA X 10* at 25**= 7.7; m. p. 108M09*.
m(32) = 51.9, (512) = 164, (oo) = 357; 1157.
8-Amino-l-naphthol-3,6-di8ulphonic add.
CioH»07NS2- OH.CioH4(NH2) (SOjH),.
kAXlO^«7 (colorim.); 1774.
5-Ainino-l-naphthol-3-8ulphomc acid.
CioH904NS=OH.CioH6(NH2).SOj|H.
kAX 10^= 5 (colorim.); 1774.
6-Amino-l-naphthol-3-8ulphonic acid. CioH»04NS.
kAXlO*=l (colorim.); 1774.
6-Amino-2-naphfhol-4-sulphonic acid. CioH»04NS.
kA X 10*= 2.2 (colorim.) ; 1774.
Ami] TABLES 61
8-Ainino-l-]uiphfhol-4-sulphoiiic add. C10H9O4NS.
kAXlO»-3.5 (colorim.); 1774.
8-Aiiiino-i-]uiphthol-5-sulplionic add. C10H9O4NS.
kAX 10^=1 (colorim.); 1774.
Aminoiiaphfhyliiaphthinduline see Naphthalene Red.
3-Amino-5-mtrobenzoic add. C7H604N2»NH2.C6H8(N02).C02H.
kA X 1(H at 25^ » 2.1; increases on diln.
/i(83.3)«40.4, (1333.3) -144.8, (a>)-354; 176.
2-Ainino-4-mtro-diphenyl-metfayl amine.
CuHuOjNa- Ph.NMe.C6H8(N02) .NH2.
kB X 10« at 25**- 5.0 (part.) ; 683.
3-Amino-6-nitro-2-hydrozy-benzoic add. (3-Amino-5-mtro-salicylio
acid). C7H606N2-(NH2)(NOj)C6H2(OH)(C02H).
kA X 19 at 25**= 1.33 (neutral.).
Cond. alone and with NaOH in Et ale; m. p. 223""; 1608, 1718.
2-A]iihio-4-mtrophenol. C6H60sN2-NH2.C6H8(N02).OH.
kAXlCF at 25*^-2.6.
I«(202.5)=2.6, (810) -5.2, (cx>) = 354; 70.
Amino-nitro-salicyfic add see Amino-nitro-hydrozy-benzoic add.
Aminophenazine (CuHgNs) see Phenosafranine.
o-Aminophenol. C6H7ON-NH2.C6H4.OH.
kBXlO^^at 15*^-2.18 (colorim.); 1777.
Cond. alone and with NaOH; 1508, 1718; with HCl; 1608.
In NHs, qual. ; 606.
o-Aminophenol ethyl ether see o-Phenetidine.
o-Aminophenol methyl ether see o-Aniddine.
m-Aminophenol. CsHtON.
Cond. alone and with NaOH and HCl; 1608, 1718.
p-Aminophenol. CsHtON.
kaXlO* at 15*^-6.6 (colorim.); 1777.
Cond. alone and with NaOH and HCl; 1608, 1718.
in NHs, qual.; 606.
B.HCl at 25**, m(50)-94.9. - B.H2SO4; 1864.
p-Aminophenol ethyl ether see p-Fhenetidine.
p-Amlnophenol methyl ether see p-Anisidine.
2-Aminophenol-4-8ulphonic add.
C«H704NS=NH2.C6H8(OH).S08H. [OH-1; NH2-2;
SaH-4].
kAXl0*at25**=9.41.
/i(64)-26.5, (1024) -94.3, (cx>)=:355;'492.
Cond. alone and with NaOH; 1608, 1718.
4-Aminophenol-2-8ulphonic add. C6H7O4NS.
• kAXl0«at25°-8.3.
m(256) = 16.0, (1024)-31.3, («)=355; 492
62 TABLES [Ami
o-Aminophenyl efhyl carbonate. (Carbonic acid ethyl o-aminophenyl
di-ester) . CgHuOsN = Et02.CO.C«H4.NHa.
ksXlQi^ at 0°=9 (hydro!.).
B.HCl; 1660.
o-Aminophenyl mefhyl carbonate. CgHgO^N.
kBXlO^UtO^=l (hydrol.).
B.HCl at 0^ M(32)-78.5, (256) = 125.6; /i(32)«45.9; 1660.
p-Aminophenyl ethyl carbonate. CgHuOsN.
kB XlO^® at 0**=2.7 (hydro!.).
B.HCl at 0^ M(32)«51.0, (256)=66.3; /i(32)=43.8; 1660.
p-Aminophenyl methyl carbonate. CsHgOsN.
ka XlO^® at 0^=2.8 (hydrol.).
B.HCl at 0^ M(32)=52.8, (256)=67.5; m(32)=45.9; 1660.
2-Amino-p-phthalic acid. (Aminoterephthalic acid).
C8H704N=NH2.C6H8(COaH)2. [C02H=1,4; NH2=2].
kAXlO*at25**=2.65.
/i(512)« 115.3, (1024)- 152.3, (oo)=377; 1684.
2-Amino-p-phthalic acid 4-mono methyl ester. C9H904N»
NH2.CeH,(C02H)(C02Me). [C02H=1; C02Me-4].
kAXlO*^ at 25**»6.52; m. p. 213^
m(512) = 58.1, (1024) = 79.5, (a>) = 376; 1684.
?-Amino-p-phthalic acid ?-mono methyl ester. C9H9O4N.
kAXlO* is about 1.5; m. p. 216^-217** (cor.); 1916.
a-Aminopropionic add. (a- Alanine). CsH702N» Me.CH(NH2).C02H.
kAXlO^^ at 25*^=2 (hydrol.); 1086, 1984 and 1160.- T not
stated, (colorim.); 1773.
kaXlO^^ at 25^=3.1 (hydrol.); 1086;=5.14 (hydrol.); 1160 and
1984.
At 25% A(64)=0.3, (1024)=2.6, (oo)=350; 601; - 146b, 690,
1619.
In NHa, qual.; 606. In SO2; 1842.
Cond. of soln. saturated with CO2; 146b, 1619. With organic
compounds; 146a, 146b, 1086. - With inorg. compounds;
690.
Na.A at 25°, M(32)=70.8, (1024)-99.8; A(32)=68.5; 1984;
M(64)=84.6; A(64) = 76; 1086. - B.HCl at 25% M(32) =
166.5, (1024)=341.3; A(32) = 106.5; 1984; M(64)=225;
A(64) = 108; 1086.
a-Aminopropionic acid ethyl ester. C5H11O2N.
Cond. is greater than that of the acid; 146b.
/3-Aminopropionic acid. (|3-Alanine). CsH7O2N-NH2.CHa.CHa.CO2H.
kAXlO" at 25°»7.1 (hydrol.).
kaXlO" at 25°=5.1 (hydrol.).
Amg TABLES 68
Cond. with organic compounds.
Na.A at 25^ M(64)=90.8, (512) = 121.4; A(64)-76. - B.HCl at
25% M(64) = 141, (128) = 158.3; A(64) = 108; 1086.
IHAxninosalicylic add see Amino-hydrozy-benzoic add.
Aminosuccinamic add see Aminosuccmic add mono amide.
Aminosucdnic add. (Asparaginic acid. Aspartic acid).
C4H704N=C02H.CH2.CH(NH2).C02H.
kA XlO* at 15.4**= 1.15 aq.; 164. At 25''= 1.4 (catal. and hydroL);
866, 1160, 1984. Electrical conductivity measurements
pve mean value for v(32)=0.67, for v(1024) = 1.3; 1838,
1984 and 1673. - (Colorim.); 1773.
ksXlO^^ at 25**= 1.2 (hydro!.); 1160 and 1984.
Cond.; 146a, 166, 1227. At 25% m(32) = 16.1, (1024) = 109.4,
(oo)=354; 1838.
Cond. with inorg. acids, bases and salts; 146b, 166, 167, 1184,
1227, 1984. - With organic acids, esters, and salts; 44, 146a,
146b, 167.
Na.A at 25% m(32)=66.1, (1024)=75.9; 1984; also 166, 167, 1227.
- KA. and 2K.A; 164. - K.A.; 1227. - B.HCl at 25%
/i(32) = 97.4, (1024) = 108.4; M(32)=211.9; 1984; 1864.
- 2B.H2SO4; 1864.
Aminosucdnic add mono amide. (Aminosuccinamic acid. Aspara-
gine). C4H808N2=CONH2.CH2.CH(NH2).C02H.
kAXlO' at 14.8**=0.69 (sapon.). At 15**=0.72 (sapon.). At
18*^=0.88 (sapon.). At 25*^=1.35 (sapon.); 1160;=5.2
(hydrol.); 1984;=25 ; diminishes on diln. (cond.); 1838,
1984, At 28.1**= 1.84 (sapon.). At 35.0*'=2.40 (sapon.).
At 40*'=3.15 and 3.22 (sapon.); 1160.
kBXlO^^ at 15*^=0.68 (sapon.). At 15.82**=0.74 (sapon.). At
25**= 1.53 (sapon.) ; 1160.= 1.8 (hydrol.) ; 1984. At 35**- 3.20
(sapon.). At 40**=4.23 (sapon.); 1160. At 60**= 19.0 (in-
version); 1880 and 1160.
At 25% m(32)=0.3, (256)=0.9, (cx>) = 355; 1984; - 690, 1838,
1868. Qual.; 1684.
In HCl, no cond. ; 30. In NH4, qual. ; 606.
Cond. with NaOH and HCl; 690, 1318. With KCl; 690.
Na.A at 25% m(32) = 65.3, (1024)=76.3; M(32)=66.7, (1024) =
82.7; 1984. - B.HCl at 25% /i(32)=98, (1024) = 109; M(32) =
196.3, (1024) =361.2; 1984; 1864. Effect on inversion of
sugar; 1880. - 2B.H2SO4; 1864.
2-Amino-4-8ulphobenzoic add. C7H705NS=
NH2.C6H8(S08H).C02H. [C02H=1; NH2-2; S08H-4.1
kAXlO* at 25**= 3; diminishes on diln.
m(150)=312.5, (1200)=356.4, (cx>)=377; 466a.
64 TABLES [Ami
4-Amino-2-8iilphobeiizoic add.
CtHtObNS. [COaH^l; NH2-4; SQ,H-2.1
kAXltf at 25''«:3; diminishes on diln.
m(150)- 187.8, (1200) =302.4, (oo)-377; 468a.
4-Axnmo-3-8alphobeiizoic add.
C7H7O5NS. [C02H=1; NH2-4; SOsH-S.]
kx XlO* at 25** =8; diminishes on diln.
m(150)« 349.6, (600) -360.0, (cx>)-377; 466a.
S-Amino-2-sulphobeiizoic add.
C7H7O6NS. [CO2H-I; NH2=5; SQ,H-2.]
kA XlO" at 25^=6; increases on diln.
m(150)=. 214.5, (1200) = 332.4, (oo)=377; 466a.
6-Amino-S-8ulphobeiizoic add.
CtHtOsNS. [C0jH=1; NH2-5; SQ,H-3.]
kxXlO" at 25**= 2; diminishes on diln.
m(150) = 165.7, (1200)=302.4, (oo)-377; 466a.
Aminosulphonic add. NH808S=NH2.SQsH. [The references to this
are incomplete. ]
kxXlO at 25^=1; diminishes on diln.; m. p. about 205^; 1657,
1984.
/i(32) = 294.7, (1024) = 363.7, (cx>)-371; 1984.
Na.A at 25^ m(32)=81.5, (512)-91.9, (1024) = 94.2?; 1984
- ; 1667. - B.HCl; 1984.
Amino-sulphosalicylic add see Amino-hydrozy-sulphobenzoic add.
6-A]iiino-l,2,3,4-tetrazole. (Aminotetrazolic acid. Aminotetrazotic
acid). CHsNfi-NHa.C.NiH.
. kxXlO^ at 0*^=3.12. At 10''=4.16. At 18°= 5.4. At 20**= 5.73.
At25*'=6.6. At 30*^=7.44. At 40'*=9.14; 143, and Lund^n,
Affinitatsmessungen, and 142.
At 25^ /i(32) = 1.9, (1024) = 11.6, (a>)=354; 1720, 142.
In pyridine; 764.
Na salt, at 25^ m(32)=78.7, (1024) =93.3; 142, 143, 1720. At
0**-40^ 143.
Aminotetrazotic acid see Aminotetrazole.
l-Amino-l,3,4-triazole. (iso- or N-Dihydro-tetrazine). C2H4N4.
ksXlO" at 25**=1.77 (sapon.); m. p. 151**; 428.
Amino-xylene see Xylidine.
Ammonchelidonic acid. (4-Hydroxy-pyridine-2,6-dicarboxylic acid).
C7H6O6N = OH.CftHjN. (C02H)2.
At 25^ m(170.5)=367, (1364)=546; 1372.
Ammonia. NHs. [The references to this are incomplete. ]
X at -33** is below 1 XlO-^ 610. At -20**= 1.6x10-*; 678.
Ammonium hydroxide. NH4OH. [The references to this are in-
complete. ]
Amy] TABLES 65
kflXlO* at 0*^-13.9. Atl8''-17.2. At25''-18.0. At 50^-18.1.
At 75**- 16.4. At 100*^=13.5. At 125*'= 10.4. At 156** -6.28.
At 218^-1.80. At SOe'^-O.OOS; 1332. - Also 165, 271, 649,
650, 776, 949, 1144, 1283, 1341, 1363.
Cond. Under pressure of 1 to 500 atmospheres; 220. - Of mix-
tur-e with diacetone alcohol; 979. - See also 48 and 1631.
Amniotic fluid. [The references to this are incomplete. ]
Concentration of H and OH ions; 587.
Amygdalin. C2oH2rOiiN.
InNHs, qual.; 606.
Amygdalinic add see PhenylglycoUic add.
norm.-Amyl alcohol. C5H12O - C6Hu.0H.
xxl0«at 17*'-6.9.
As solvent; 787.
tso-Amyl alcohol. (Pentyl alcohol.) CsH^O.
xXlO* at 17.1**-3.2; 1900. At 18**=5;. 647, 478; ako 362, 438,
and 1472. At 20*'= 4.3; 1590a; 783; - 1316. At 25** -50;
1669; - 21 and 20. ~ T not stated; 305.
In HBr; 29. In NHs, qual.; 606.
Cond. under pressure of 100 atmospheres; 1472. Under pres-
sure, as solvent; 1590a. With Cu oleate; 1569. As sol-
vent; 20, 334, 438, 472, 483, 647, (783), (1477), 1569, 1590a.
iso-Amyl amine. C5HUN-C5H11.NH2.
xXlO^ at 25^ is less than 2; b. p. 96*"; 1388; - 942, 943.
ka XlO* at 25**- 5 aq.; about 16% too high; 271.
At 25^ m(32)=24.3, (256) -59.1, (00) = 201; 271; 1363.
In HCN; 943. In NH4, qual.; 606.
Cond. As solvent; (942), 1388. With organic compounds;
1388.
B.HCl at 25°, A(32)-90.3, (1024) = 101.3; 270.
Amylase.
Cond. of aq. soln. ; 690.
Amyl bromide. CeHnBr.
X X10» at 25** is less than 2; b. p. 118.5'*-119** @ 742 mm.; 1388.
In NHa, qual.; 606.
Cond. with inorg. and organic compounds; 1388.
tso-Amylbrudnium chloride. (Brucine iso-amylochloride).
C28Hw04N2Cl-B.N.(C6Hii)Cl.
At 25% A(64)-79.8, (1024)-89.8; 270.
nonn.'Amylene. C5H10.
X XlO^ at 25** is less than 2; b. p. 40" @ 724 mm.; 1388.
Cond. affected by radium and X-rays; 417. With other com-
pounds; 1388.
66 TABLES [Amy
Amyl efher . (Diamyl ether) . CioHaO - (C6Hu)20.
In NHs, qual.; 606.
Amyl iodide. CeHuI.
XX 108 at 25** is less than 2; b. p. 127^-128** @ 740 mm.
Cond. with inorg. and organic compounds; 1388.
iso-Amylisethionic add. (Hydroxy-amyl sulphonic acid).
C6Hi204S=C6Hio(OH).SOsH.
kA X 10' is approximately 4. The acid is 97% dissociated at v(256).
A(1024-32) of the salts shows that the acid is monobasic; 394.
tso-Amyl mercaptan. (Amyl sulphhy droxide) . CsHisS = CeHuSH.
X XlO« at 25** is less than 2; b. p. 115** @ 742.8 mm.; 1388.
In HON, no cond.; 943.
Cond. with inorg. salts; 149, 1388. With organic compounds;
1388.
Amylmefhyl- see Methylamyl-
Amyl nitrate see Nitric add amyl ester.
Amyl nitrite see Nitrous add amyl ester.
Amylsulphhydrate see i$a-Amyl mercaptan.
Amyl sulphhydrozide see iso-Amyl mercaptan.
Amyl thiocyanate see Thiocyanic add amyl ester.
tso-Amyltriphenyl phosphonium chloride.
CisHaeClP^ (CsHu) (Ph8)P.Cl.
At25^ A(32) = 77.1, (1024)«88.5; 270.
Anethole. (p-Allyl phenol methyl ether). CioHuO,
In NHs, qual. ; 606.
AngeUc acid. C6H802= Me.CH : CMe.CQsH.
IcaXIO*^ at 25*'«5.01; 1371 and 1368.
A(32) = 13.9, (1024) = 71.9, (oo) = 355; 1371.
Na.A at 25^ A(32) = 66.3, (1024) -76.0; 1368a.
Anhydroecgonine. C9H18OSN.
ksXlO" at 14°=3.68 (colorim.); 1778.
Anil- see Anilino-
Anilido- see Anilino-
Aniline. CeHyN-Ph.NHa.
XX 108 at 18** to 25''- 1. At 18**=0.92; 1900, 1472. At 20**=6;
not purified; 1316. At 25** is less than 2; 1388. Also 306
and 1477.
ksXlO^o at 12*'-2.6 (colorim.); 1777. At 15**=3.1 (hydrol.);
1143, (colorim.); 1777. At 18*'=3.5 (hydrol.); 436, 632.
At 25**= 5; (hydrol.); 270, 271, 436, 660, 1043, 1116, 1143,
1160, 1293; - (part.); 648; - (solub.); 660, 1116.=4.2 (col-
orim.); 1729b. Electrical conductivity measurements; 269,
1241. At 40**= 7.6 (hydrol.); 1143, (catal.); 19 and 1160.
At 60**»17.1 (inversion); 1880 and 1160.
Am] TABLES 67
[At 25''], A(25.6}-0.10, (51.2) -0.16; 269. Also 146a, 146b.
In HCN, no cond.; 943. In HBr and HI, small cond.; in H2S,
no cond.; 1897. In NH4, small cond.; 610 and 606. In
benzene, no cond.; 1802, 1803.
Cond. under pressure of 100 atmospheres; 1472. Of thin layer;
301. With organic acids; 146a, 146b, 169, 513, 632, 1011,
1388, 1802, 1900. With organic bases; 1388. With Cu
oleate; 1669. With xylene; 1900. As solvent; 480, 1652a,
1569, 1900.
B.HBr, inorganic solvents; 1662a. - B.HCl at 25**, A(32)=99.7,
(1024)=147.5; 1327; A(64)-96, (1024) = 103.3; M(64)-
106.2, (1024) » 144.0; 270.- 19, 165, 271, 434, 436, 734,
1143, 1659, 1791, 1864, 1880. Effect of diazotization on
cond.; 1601. - B.H2SO4; 1327, 1864. - B Acetate; 44, 146a,
146b, 165, 1143, 1791, 1802, 1803, 1864. - B.Benzoate;
1802, 1803. - B.Maleate; 146a. - B.tso-Nitrosomethylpyra-
zolone; 1143. - B.Picrate; 1802. - B.Salicylate; 145a, 532.
Aiiil]ne-2,4-disalphonic acid. C«H706NS2=NH2.C6H8(S08H)2.
kA is between k of m- and p- Aniline sulphonic acids, (colorim.);
1773.
o-Anilme sulphonic add. (o-Aminobenzene sulphonic acid).
C6H7OsNS-NH2.C6H4.SO8H. [NH2=1; S08H=2.]
kA X 10* at 25''»3.3; diminishes on diln.; 1372.
Cond.; 466a. At 25% A(64)«130.4, (1024) = 286.9, (oo)-366;
1372.
In NHs, qual. ; 606.
m-Anifine sulphonic add. (Metanilic acid) . CeHyOsNS. [SOsH » 3. ]
kxXlO* at 0*^=0.90. At 12''= 1.34; 1968a. At 25**=1.99;
1968a;=1.86; 1372. - (Colorim.); 1773. At 35°=2.62; 1968a.
At 25% A(64)-36.5, (1024) = 123.5, («)=356; 1372. A(1024)-
125.8, (cx>)»351; 1968a.
In NHs, qual.; 606.
p-Aniline sulphonic add. (Sulphanilic acid). CeHrOsNS. [S08H=4.]
kAXlO* at 0**=3.3. At e.S'^-^O; 1968a. At 25''=6.6; 1968a,
1968;=5.9; 1984, 1372.- (Colorim.); 1773. At 35°=8.2;
1968a.
Cond. at O** to 35%- 1968, 1968a. At 25% A(32)=45.5, (1024) =
188.6, («)=356; 1372. A(1024) = 193.0, (a>)=351; 1968a.
- 456a, 1984.
In NHa, qual.; 606.
Na.A at 25% A(32)=68.1, (1024)=78.3; 1984; 1968a.- B.HCl
at 25% M(32)=384; 1984.
AnUino-acetic add see Phenylamino-acetic add.
68 TABLES [Ani
Anilinoacetic-acid-o-carbozylic add see Phenylglyciiie-o-carbozylic
acid.
a-Anilmobutyric acid. CioHis02N-Et.CH(NHPh).C02H.
kAXlO*^ at 25**=3.2; m. p. 140**; increases on diin. A(130) =
19.8, (1040) -58.4, (oo)=350; 1840.
a-Anilino-iso-butyric acid. CioHi802N-Me2C(PhNH).C02H. Wal-
den calls this an Anilinobutyric acid.
kx X 10* at 25*'=3.9; increases on diln.; m. p. 142^
A(200)«27, (800) = 56.4, (cx>) = 350; 1840.
Anilino-iso-butyric acid. C10H18O2N.
kxX 10« at 25*'-8; m. p. 178*^-182^ impure?; 1840.
/3-AniUiio-isa-butyric acid. CioHuOsN«(Ph)NH.CH2.CHMe.CO|H.
kx X 10* at 25*'«1.1; increases on diln.; m. p. 185**.
A(200)-4.9, (800) -10.2, (cx>)=350; 1840.
Anilinochlorooxalic add see Chloro-oxanilic acid.
Apilinochlorosaccinic add see Chlorosucdnanilic add.
Anilinodiacetic-o-carbozylic add.
CiiHii06N-C02H.C«H4.N(CH2.CO|H),.
kxXlO' at 25**-3; increases on diln.; m. p. 212**; 1845, 1817,
1301. A(74.6)- 138.7, (596.6) -305.4, (oo)-372; 1845.
AniUnofumaric add see FumaraniHc add.
Anilinoglyozylic add see Diamino-stilbene dicarbozylic add.
Anilinomalonic add see Malonanilic add.
Anilinoozalic add see Ozanilic add.
a-AniUnopropionic acid. (Phenyl-a-alanine).
C9H11O2N- Me.CH(NHPh).C02H. 4
kxX 10* at 25**- 2.2; increases on diln.; m. p. 162^
A(136)-18, (1088)-50.3, (a>)=353; 1840,
/3-Anilinopropionic acid. (Phenyl-j3-alanine).
C9Hii02N-PhNH.(CH2)2.C02H.
kx X 10« at 25**-4.2; increases on diln.; m. p. 59**-60^
A(200) = 9.4, (800) = 19.8, («)-353; 1840.
Anilinosucdnic add see SuccinaniHc add.
Aniloandpyrine see Anllopyrine.
Anilopyrine. (Aniloantipyrine. 2,3-Methyl-l-phenyl-2,6-phenyli-
minopyrazole). CnHnNs, ,.
Cond. at 18*^ is about one half that of Benzyliminop3rrine; m. p.
79**-80**; 1266.
Animals. [The references to this subject are incomplete.]
Cond. of the body fluids of various animals; 260, 263, 6d4a.
See also separate heads, as, Blood, Heart, etc.
Anisaldehyde see Anisic aldehyde.
Ani] TABLES 69
mte^-Anisaldoziine. (p-Methoxy-benzaldehyde onfo'-oxime).
CaH.OjN^ MeO.C«H4.CH : NOH.
Na.A at 0% A(32)=43.1, (1024) -75.2; 035.
Anishydroxamic add. (4-Methoxy-benzhydro3camic acid).
C8H9Q,N-MeO.C6H4.CH.N.OH.
kAXlOMat25°]-7.3.
A(128)=3.6, (512)=6.9, (oo)- [380]; 1358a.
Anisic add see p-Methozy-benzoic add.
Anisic aldehyde. (Anisaldehyde. p-Methoxy-benzaldehyde).
C8H862-MeO.C8H4.CHO.
XX 10»at0^«9; 1843, 1844; 1847. At 20**- 8.6; 1690a. At 25**=
12; 1843, 1844, 1847, 1853a and 1569.
In HBr and HI, good cond.; in H2S, poor cond.; 1897. In NH^,
qual.; 606.
Cond. with Cu oleate; 1569. As solvent; 1569, 1590a, 1844,
1847, 1853a. As solvent, under pressure; 1590a.
o-Anisidine. (o-Aminophenol methyl ether).
C7H9ON-NH2.C6H4.OMe.
kB X 10^» at 15*^=1.9 (colorim.); 1777.
p-Aidsidine. (p-Aminophenol methyl ether). C7H9ON.
kB X 10» at 17''- 5.7 (colorim.); 1777. At 25**- 1.47 (part.); 548.
B.HCl, cond.; 501. Cond. as affected by diazotization; 1601.
Anisole. (Phenol methyl ether.) CrHsO-CeHs.OMe.
In HBr and HCl, good cond.; in HI and H2S, no cond.; 1897. In
NHs, qual.; 606.
Cond. as solvent of AlCU; 1893.
p-Anisole diazonium hydroxide. (p-Diazo anbole. p-Diazo phenol
methyl ether.) C7H8O2N2-MeO.C8H4.N2.OH.
Strong base. At 0^ A(128)-116.3, (oo) = i35; cond. diminishes
on standing.
B.Cl at 0^ A(128)-52.0, (256) -52.4; 501.
B.CN. 5i/n-cyanide, m. p. 50*'-51**; at 0**, A(256), in ale- 1.0;
in aq.-49.6. A«/i-cyanide, m. p. 121'*-122**; at 0*" in ale.
no cond.; 735. - B.CN.HCN; 531.
o-Anisole sulpbinic add. (o-Methoxy-benzene sulphinic acid).
C7H8O8S- MeO.C8H4.SO2H.
kA X 10* at 25''= 2.11; diminishes on diln. A(32) -194.4, (1024)-
305.1, (a>)«353; 54.
K.A. - Na.A at 25^ A(32)-61.6, (1024)-75.5; 54.
Anisole sulphonic add see Methoxy-benzene sulphonic add.
Anisuric add. C10H11O4N-MeO.C8H4.CO.NH.CH2.CO2H.
kAXlO*at25**-1.62.
I«(7 16.9) -100.8, (1433.8) = 132.9, (cx>)=350: 601.
I
70 TABLES [Ant
Anthracene. C14H10.
Resistance when solid and when molten; 988a.
In MeNH2, no cond.; 837. In SO2; 1842.
Vapor at 200''-250'', no cond. under diminished pressure; 869a«
Anthranilic add see o-Aminobenzoic add.
Anthraquinone. CiiHsOs.
In MeNHs, no cond.; 837.
Antimony compounds see Tetraethyl and Tetramethyl stibonium
hydroxide, and Trimethyl and Triphenyl stibine.
Antipeptone a. (Trypsinfibrinpeptone a). CioHnOtNs.
Cond. in aq. soln.
Cond. with NaOH and HCl.
Na salt, m(32)-72.98, (1024)=90.8; 1318.
Antipeptone /3. (Trypsinfibrinpeptone /3). CuHiftOsNs.
Cond. in aq. soln.
Cond. with NaOH and HCl.
Na salt, m(32)-82.2, (1024) = 104.7; 1318.
Antipyrine see 2,3-Dimetliyl-l-phenyl pyrazolone.
ApioUc add. CioHioOe^ CHj : O2 : CeH(0Me)2.C0aH. [OMe= 2, 5;
CHjOj-B, 4.]
kA X 10* at 25**=8.03 aq.; m. p. 175^ m(1320)=97.5, (a>)-352;
23.
Apionketonic add see Apionylglyozylic add.
ApionylglyozyUc add. (Apionketonic acid).
CiiHio07«CH2:02:C6H(OMe)2.CO.C08H.
kA X 10* at 25**«3.35 aq.; m. p. 160M72° dec.
m(91.2) = 278.8, (729.9) =335.3, («)=351; 23.
Cond. not increased by boric acid; 1188.
Apocamphoric add see Camphopyric add.
Arabinose. C5H10O6.
InNHa, qual.; 808.
Argenti- see under Silver.
Argento- see under Silver.
Arginine. (Guanidine-a-aminovaleric acid).
C6Hi402N4= NH: C(NH2).NH.(CH2)3.CH(NHa).C02H.
kAX 10^* at 25** is over 1.11 (sapon.).
ka X 10^ at 25** is less than 1.0 (sapon.).
Second ks X 10^* is less than 2.2.
Na salt at 25"*, ai(32) is about the same as that of NaOH; 948.
Arsenic see Cacodylic add, Methyl arsenic add, Tetraethyl arsonium
hydroxide, Tetramethyl arsonium hydroxide, Trimethyl
arsine, Triphenyl arsine.
" In complex salts. With tartaric acid. KASC4H4O6; M(25)a
91.97, (1600) = 186.4; 938.
Axo] TABLES 71
Arum italicum. [The references to this are incomplete.]
Cond. of the fruit; 1326.
Asparagic add see Aminosucdnic add.
Asparagine see Aminosucdnic add mono amide.
Asparaginic add see Aminosucdnic add.
Aspartic acid see Aminosucdnic add.
Aspirin see o-Acetozy-benzoic add.
Atropic add. (a-Phenylacrylic acid.) C9H802-CH2:CPh.COiH,
kAX 10* at 25**= 1.43.
A(128)=45.8, (1024) = 111.4, («)=352; 1371.
iso-Atropic add see Truzillic add.
Atropine. CnHssOsN.
kB X 10^ at 14*^-18** is over 1 (hydro!.); 1778.
At 25^ m(200)=34.6, (800) =43.7; 1864.
In HCN, fair cond.; 943.
With allyl thiocarbimide, no cond. ; 1223.
Auramine. C17H21N3.
Auramine; saturated soln. has no conductivity. Auraminium
hydroxide is a strong base, changing on standing to the
weak carbinol, auramine; 770.
Auramine G. (Imino-dimethyl-diamino-di-o-tolylmethane).
HN:C(Me.C6Ha.NHMe)2.
At 25^ /i(1024)=48.3 at once, » 35.4 after 56 minutes; also
cond. at 0**.
B.HCl at 0% m(512)=50.3. At 25^ m(512)=96.5; 2006, 770.
Auramine O. (Imino-tetramethyl-diamino-diphenyl-methane).
HN:C(CeH4.NMe2)2. j
At 25% m(1024)»43.7 at once,«30.8 after 60 minutes; also cond.
atO^
B.HCl at 0% m(512)=77.6. At 25°, /i(512) = 136.0; 2006.
In 2006 it is stated that Hantzsch, in a letter, wrote that the
measurements of 770 may have been made with Auramine G.
Azelaic add. C9Hie04=C02H.(CH2)7.C02H.
kAXlO*^ at 18**=2.6 (colorim.); 1663. At 25''-2.53 aq.; m. p.
106°-106.5°; 1638;=2.96; 176, 1810.
Second kAXl0*»2.4 (cond.),»3.3 (part.); 370; also 1638, 1911.
At 25% /i(68.2) = 14.3, (1091) = 55.1, (cx>) = 350; 1638.
NaH.A at 25% m(32)=68.9, (1024) «85. - 2Na.A at 25% m(32)-
75, (1024) =91; 370.
Azelaic add anhydride. C18H30O7.
Cond. of aq. soln., showing change to acid; 1810.
Azobenzene. CiaHioN2 - PhN : NPh.
In HBr, poor cond., in HI, no cond.; 1897. In H2S, no cond.;
27, 1897. In MeNH2, no cond.; 637.
72 TABLES [Azo
Azobenzene-p-sislphonic acid. CisHio03NsS«Ph.N8.C6H4.S03H.
In pyridine at 25^ A(32)-8.68; in 60% pyridine, A(28)=36.2;
764.
Azounide see Hydrazoic add.
Azooxybenzene. CiiHioON2=Ph.NON.Ph.
In HBr, poor cond., in HI and HsS, no cond.; 1897.
p-Azophenol. (4,4'-Dihydroxy-azobenzene. Quinone-p-oxyphenyl-
hydrazone). CuHioOsNj- OH.C6H4.N2.C6H4.OH.
Na.A at 25^ m(32)=67.6, (1024) = 79.7; 646.
Azophenosafranine.see asym.-Phenosafranine.
Azotetrazole. C2H2N10-N4H.C.N2.C.N4H.
2Na.A at 25^ /i(32)=86.8, (1024) -103.6; 142.
B.
Barbituric acid. (Malonyl urea). C4H40tN2.
kx X 10* at 26**- 1.0; 1748, 1996.
Ai(32)-19.5, (1024) = 97.0, (oo)«358; 1748.- 782.
Cond. in Et ale. ; 782.
Na.A at 25^ m(32) = 64.5, (1024)=74.5. - 2Na.A at 25^ m(32) =
92.0, (1024)- 123.0; 1748.
Begonia semperflorens. [The references to this are incomplete. ]
Cond. of stem; 1326.
Benzalanisal- see Methoxy-dibenzal-
Beiizaldehyde. C7H6O - Ph.CHO.
xxW at 20^=4.9; 1690a. At 25*^-1.6; 1843.=4.5; 941;=10;
1388.
kA X 10*« at 18** is about 1.2 (hydroL); 632.
In HBr and HI, good cond.; in H2S, no cond.; 1897. In HCl,
qual.; 16. In HCN, no cond.; 943. In NHs; 607. In
Et ale; 1664. In MeNH2, fair cond.; 637.
Cond. with HCl, qual.; 1663. With NaOH; 632. With KCN;
1664. As solvent; (941), 1388, 1690a, 1844. As solvent,
under pressure; 1690a.
Benzalmalonic acid. CioH804= Ph.CH : C(C02H)2.
kA X 10» at 25''=4.08; 1372.
Second kAXlO«=3.2 (cond.); 1911.
At 25^ /i(32) = 106.7,. (1024) = 294.1, (oo)=353; 1372.
Benzalpiperonal acetone. CisHhOs.
Comparative strength (colorim.) ; 1663. .
Benzalpiperonal cydopentanone. C20H16O8.
Comparative strength (colorim.); m. p. 176°; 1663.
iso-Benzalpiperonal pyclopentanone. C20H16OS.
Comparative strength (colorim.); m. p. 192°; 1663.
Benl TABLES 78
Benzamide see Benzoic acid amide.
BenzaniHde. CuHuON.
In NH«, qual. ; 606.
Benzbetaine see under Trimethyl-aminobenzoic acid.
Benzene. CeH^.
Pure, no cond.; 936, 978, 1098. xX 10^ at 25"" is less than 2;
b. p. 79.4''-79.5** @ 746.9 mm.; 1388; also 306, 384, 386,
872, 1010, 1830.
In HON, no cond.; 943. In NHs, qual.; 606.
Cond. with organic compounds; 383, 384, 386, 936, 941, 1021,
1223, 1388, 1669, 1893. As solvent; 289, 431, (842), 936,
941, 1021, 1388, 1436, 1669, 1712, 1797, 1801, 1802, 1830,
(1893). At critical point; 107, 133. As affected by long
continued current; 1606. As affected by X-rays and rays
from radium; 417, 872, 1491. Of thin layer; 301.
Benzeneazodibromo-phenol see Hydrozy-dibromo-azobenzene.
Benzeneazophenol see p-Ozy-azobenzene.
Benzene-l-carbozylic-add-amide-2-methylcarbozylic add see Hom-
ophthalic add 1-mono amide.
Benzene diazonium hydroxide. (Diazo benzene).
C6HflON2-Ph.N,.OH.
kB X 10» at 0''=1.23; 426, 601.
/i(31.9)=24.9, (517)=73.2, («) = 139.7; 426.
Cond. with NaOH; 426.
Na.A at 0**, m(60)=71.2, (650) = 147.2; 426. - B.Br, cond., and
cond. with HBr at 0**; 426. Cond. at V; 730. - B.Cl, cond.,
and cond. with HCl and HI at 0""; 426. Cond. at 1""; 426,
730. - B.NOi, cond. at 0**; 426. At l*'; 426, 730. - B.CN;
736.
Benzene sulpldmc add. CeHeC^S^Ph.SOzH.
kAXlO* at 18*^-4.4; 64. At 25*'=3.5; 64, 1134. At 30**=2.7;
64. Diminishes on diln. in all these measurements.
At 25^ A(34.4)=229, (274.8)=316, (oo)=356; 1134.
Benzene sislphocyamic add see Benzene sislphonic acid cyanoamide.
Benzene sulphocyanoamide see Benzene sislphonic add cyanoamide.
Benzene sulphonamide see Benzene sulphonic add amide.
Benzene sulphone-aminoacetic add. (Benzenesulphonegly collie add).
C8H904NS= Ph.SO2.NH.CH2.CO2H.
kx X 10^ at 25^ » 3.51; diminishes on diln.
A(64)=49.0, (1024) = 155.9, (00) =349.
Na.A at 25^ A(32)=62.5, (1024) =73.7; 1134.
Benzene sulphone-aminosucdnic add. (Benzenesulphone-aspartic
acid). CioHiiO«NS=Ph.S02.NH.C2H8.(C02H)2.
74 TABLES [Ben
kA X 10^ at 25^-7.15; increases slightly on diln.
A(25)=43.2, (1600)=227.2, (oo)-361; 1134.
Benzene sulphone-aspartic acid see Benzene sulphone-aminosuccinic
add.
Benzene sulphones^ycoUic acid see Benzene sulphone-aminoacetic
acid.
Benzene sulphonic add. CeHeOsS-Ph.SOsH.
At25% A(32) = 326, (1024)=358; 1366.
Cond. with maleic add; 1630. Under varying pressures; 220.
Li.A; 1366. - Mg.2A; 1836. - Na.A at 25% A(32) = 69.1, (1024)-
80.6; 1366; alteration of cond. by KOH; 496. - Ag.A; 1111.
Benzene sulphonic add amide. (Benzene sulphamide. Benzene sul«
phonamide.) C6H702NS= Ph.SQ2NH2.
Cond. at 0**; 726. At 25% A(32)=0.98, (1024) =6.63; 1676.
In NHs; 607, 610. In MeNHj; 606.
Cond. with HCl, and NaOH; 781.
Benzene sulphonic add benzoylamide. (Benzoyl benzenesulphonic
amide). CiBHuQsNS-Ph.S02.NH(C0.Ph).
Na.A at 26% A(32)=69.7, (1024) =70.1; 781.
Benzene sulphonic add cyanoamide. (Benzenesulphocyamic acid.
Benzene-sulphocyanoamide). C7H«02N2S= Ph.S02.NH(CN).
kAXlO«at25**=1.3; 70.
A(115) = 12.7, (920)=36.6, (oo)=363; 70. A(128)=337.6; 782.
[This difference is inexplicable. ]
In Et ale. ; 782.
Benzene sulphonic add nitroamide. (Benzene sulphonitroamide.)
C6Hfl04NjS=Ph.S02.NH(N02).
AtO% A(40)=214.0, (320) = 224.9, (oo)=236.9.
Na.A at 0% A(1000)=67.3; 143.
p-Benzene sulphonic add azo-/3-naphthol. C16H12O4N2S.
2Na.A (Orange II), cond. at 18*» to 90**; 1796, 1798.
Cond. with H,S04; 1798.
Benzene sulphonitroamide see under Benzene sulphonic add amide.
Benzenylphenylamino-p-tolyllmidine see Phenyl-p-tolylbenzenylami-
dine.
T-O-i
Benzhydrozamic add. C7H702N« PhCH.N.OH.
kx X 10^ [probably at 26**] =7.6.
m(32) = 1.82, (64) = 2.11, (oo)=[380]; 1363a.
Benzidine. Ci2Hi2N2= NH2.C6H4.C6H4.NH2.
Hydrolysis value, (colorim.).
Second kBXl0"=7.4 (hydroL); 1777.
Benzil. CwHioOi^ Ph.CO.CO.Ph.
Ben] TABLES 75
In HBr, good cond.; in HI, poor cond.; 1897. In HCN, no
cond.; 943. In HsS, no cond.; 27, 1897. In MeNHs, little
cond.; 637. In NHs, qual.; 606.
/S-Benzil diozime. CuHu02Nt.
In NHs, qual.; 606.
Benzoic add. (Diphenyl-glycollicacid). CuHi20t-Ph2.C(OH).C02H.
kAXlO* at 25*^-9.1; m. p. 150%- 1186, 176.
A(64)=75, (512) = 170, (cd)-350; 1186.
Cond. with boric acid; 1186.
Benzunino- see Iminobenzoic-
Benzine. [This is the commercial article, a mixture of different com-
pounds in varying amounts. The references are not com-
plete.]
x; 263, 931, 1206, 1666, 1606. With organic compounds; 263.
As solvent of organic comi>ounds; 931. Effect on x of long
continued current; 1606.
Benzoic acid. CrHfiC^-Ph.COzH.
kAXlO*^ at 0''-6.2 aq.; diminishes slightly on diln.; 616, 1968a;
increases slightly on diln.; 1018. At 15.8''»6.7; 1968a. At
17*»=6.25 aq.; 164. At 18*»=7.2 (colorim.); 1663. At 20*»=
6.64 aq.; 616. At 25''»6.6; the highest value found is 7.4,
the lowest is 6.0; in almost all these measurements, k dimin-
ishes at dilutions greater than v(lOOO); 616, 1184, 1371,
1418, 1429, 1681, 1649, 1968, 1968a; (absorption of CO2);
139. At 30''-6.72 aq. At 35''»6.73 aq.; 616, 1968a. At
40*'- 6.75 aq.; 616, 1681. At 45**= 6.68 aq.; 616. At 50**«
6.5 aq.; 616, 1681. At 60*^=6.1 aq. At 70**=5.7 aq. At
80*'=5.4aq. At 90**- 4.9 aq. At 99** -4.5 aq.; 1681. T not
8tated;-6.3 (colorim.); 496, (colorim.); 961, 1781, (part.);
1820.
At 26^ A(64)-22.3, (512)-59.8, (1024)-79.6, (cd)«351; 1968a.
A(64)-21.4, (512)-57.6, (1024)-78.9, (oo)=356; 1371.
Also 168, 171, 642, 782, 838. At 0**-50*'; 616, 388a.
In HBr; 30, 147a. Qu^L; 1897. In HCl; 30, 147a. Qual.;
1897. In HON, no cond.; 943. In HsS, no cond.; 147a.
In H3SO4; 223, 760. In N2O4, no cond.; 602. In NHs,
qual.; 606. In MeNHs, good cond.; 637. In acetonitrile;
482. In alcohols; 764, 782, 1649. In benzene, no cond.;
1801. In dextrose soln.; 1649. In ether, very small cond.;
366. In piperidine and in pyridine; 764.
Cond. with boric acid; 1184. With inorg. bases; 168, 169, 171,
1017. With aniline; 169. TTith ECN; 1664. Under pres-
sure of 1-260 atmospheres; 642.
Salts. NH4.A; 823. At 15**-40**; 1143. - Cs.A; 1728. - Gl com-
J
76 TABLES [Ben
plex; 1712. - Li.A; 1728. In NHs, qual.; 606. - E.A; 1728,
164. At 35''-65*'; 388a. In flame; 682. - AgA; 848.
- Na.A at 25^ A(32)=68.7, (1024)-77.0; 1368a; - also
1728, 1276, 1968a. At 0**-60**; 616. At 25^-99^ 1681.
Under pressure of 1-260 atmospheres; 642. In flame; 682.
- RbA; 1728. - UQ2.2A; 449. - Cinchonine.A, in Me ale,
Et ale. and acetone; 1620.
Benzoic acid amide. (Benzamide). C7H70N»Ph.CO.NH2.
At25^ A(64) = 1.3, (1024)«4.2; 1729..
In NHs; 610. In Et ale, small cond.; 1904. In HON, small
cond.; 943.
Cond. with NaOH; 781.
Hg.A.; 963.
Benzoic acid cyanoamide. (Benzoylcyanoamide).
C8H60N2=Ph.CO.NH(CN).
kA X 10* at 25**=2; diminishes on diln.; m. p. 143**; 70, 767.
A(88) = 117.0, (1408) 1=263.1, (cd)=364; 70.
In pyridine; 764.
Na.A at 25^ A(32)-66.8, (1024)=75.3; 270.
Benzoic acid anhydride. CuHioOs.
In NHs, qual.; 606.
Benzoic acid esters.
Compounds of the type RR-carbinol benzoate; see under al-
phabetical heading of the first R; as Methylethyl-dimethyl-
amino-methyl carbinol benzoate.
Benzoic acid amyl ester. CisHi602»Ph.C02C6Hu*
In NHs is insol. ; 606.
Effect of temperature on cond.; 106.
Benzoic acid »o-butyl ester. CUH14O2.
In NHs is insol.; 606.
Effect of temperature on cond.; 106.
Benzoic acid ethyl ester. C9Hio02»Ph.C(^Et.
X X 10^ at 25*^=1.8; 1106, 1107.
In HCl, good cond.; 1897. In HI; 1646. In NHs, qual. ; 606. In
Et ale, qual.; 1816.
Cond. in Et ale. with EtONa; 1816. Effect of temi>erature on
cond.; 106. As solvent; 1106, 1107.
Benzoic acid methyl ester. CsHsC^.
In HCl, qual.; 16. In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Benzoic acid imide see Dibenzamide.
o-Benzoic sislpbinide. (Saccharin). CtHsOsNS.
kAXlO» at 25*'=3.6; m.p. 217^ A(320)-228.0, (640) = 257.3,
( 00 ) = 353 ; 781, (colorim.) ; 1773.
Ben] TABLES 77
In NHi; GOT, 610; qual.; 606. In MeNHt, good cond.; 637. In
pyridine; 764.
Na.A, at 25% A(32)-69.5, (1024) -80.5; 781.
Benzoin. CuHuQa = Ph.CH(OH) .CO.Ph.
In HCl and HBr, good cond.; in HI and HaS, no cond.; 1897.
Benzonitrile. CtHsN- Ph.CN.
xXlfl' at 0**=33.6; 1844. At 20*»=400; 1733. At 25**= 1.7;
1847. =0.8; 1323; also 1084, 1106, 1107, 1388, 1669, 1843,
1844. T not stated; 617, 669.
In NHs; 606.
Cond. with organic compounds and with AgNQs; 1388, 1669.
As solvent of inorg. compounds; 1106, 1107, 1328. As sol-
vent of organic compounds; 669, 936, 1084, 1388, 1669,
1733, 1844, 1847.
Benzophenone. CuHioO^ Ph.CO.Ph.
In HBr, HCl and HI; 147a. In HBr and HI, good cond.; 1897.
In HCN, no cond. ; 943. In H2S, no cond. ; 147a, 1897. In
MeNHa, very little cond.; 637.
Benzophenone chloride see Diphenyl-dichloro-methane.
Benzophenone ozime. (Diphenyl-ketoxime). CuHuON.
In MeNHs, little cond. ; 637.
Benzopurpaiine 4 B. The salt of o-tolidine-disazo-binaphthylamine
sulphonic acid. Cs4Hs6N6(S08H)3.
Q4H«Ne(S0,K),.
At 18^ /i(200) = 145.4, (1600) =205.2. At 90^ Ai( 100) =434.7,
(1600) =588.8.
Cond. with KCl; 976a.
CMH26N6(S08Na)2.
Cond. before and after dialysis and filtration; 186; also see
186a. [The composition of the dye is not stated in 186, but
it is said to have come from Merck. In Merck's Index for
1907 the dye is said to be the sodium salt, as given here.]
o-Benzoquinone diozime. CeHeOzNs- NOH :C6H4 :NOH.
kx X Iff at 25**= 1.8.
A(512)-3.7, (1024) = 5.0; 768.
In pyridine; 764.
Na.A at 25^, A(64)=74.4 at once. Changes on standing to the
anhydride, Phenylenefurazane; 768.
p-Benzoqtiinone. (Quinone). C6H4O2.
kAX 10" at 18** is greater than 1 (hydrol.); 624.
At 25% m(32)"0.03 for fresh soln.;=6.2 after two hours standing,
from formation of an acid; 647.
Cond. with NaOH; 624.
In NHs, qual.; 606. In MeNHs, fair cond.; 637.
78 TABLES [B
p-Benzoqiiinone chloroimide. CeHiONCl.
Cond. of dil. soln. is about 0.3% that of corre8i>ondmg saline
chloride soln.; explodes above 85^; 318.
p-Benzoquinone monoozime. C6H6O2N.
At 25"", m(1024)»6.4; 647. See p-Nitrosophenol.
p-Benzoquinone diozime. (Quinone dioxime).
CeH«02N2 = NOH : CeH4 :NOH.
At 25% Ai(800)=:0.25.
Na.A at 25% Ai(32)»64.5, (1024) « 82.1; changes, on standing, to
the polymeric anhydride (C6H40N2)x; 547.
Benzoylacetic acid ethyl ester. CnHuOs^PhCO.CHi.COsEt.
xXlO* at 0*'=6.91. At 25**=9.0; b. p. 186M86** @ 39 mm.;
Cond. as solvent of NEt4l; 1844.
Fe.3A at 25% in Et ale; m. p. 128**; 766.
Benzoylacetone. C10H10O2.
Fe.3A, too insol. in aq. to measure; 766.
Benzoylalanine see Benzoylamino-propionic acid.
Benzoylamino-acetic acid. (Hippuric acid).
C9H908N= CH2(NH.PhCO).C02H.
kxXlO* at 0*^=2.2. At 12*^-2.3; 1968a. At 25**-2.2; 1186,
1370, 1984;«2.4; 1968a. At 35''-«2.3; 1968a.
At 25% A(32)-28.2, (1024) = 131.1, (cd)=350; 1370.
In HBr, no cond.; in HCl, small cond.; 30. In NH«, qual.; 606.
In MeNH2, good cond.; 637.
Cond. with boric acid; 1186. With NaOH; 1984.
Na.A at 25% A(32)=63.0, (1024)-73.4; 1984; 1968a. MeNHs.A,
qual.; 637. Hg.A; 963. B.HClat25% M(32)=384, (1024) =
448; 1984.
Benzoylamino-propionic add. (Benzoylalanine).
CioHu03N-Me.CH(NH.PhCO).CQ2H.
kA X 10* at 25** =1.97; slight diminution on diln.
A(128)-51.3, (1024) = 124.7, (oo)=350; 601.
Benzoylamino-succinic acid. (Benzoyl-aspartic acid).
CiiHiiO6N=CO2H.CH2.CH(NH.PhCO).C08H,
kxX 10* at 25*'- 5.31.
Ai(64)=63.0. (256) = 114.8, (00) =374; 1397a.
Benzoylamino-succinic acid a-mono methyl ester.
Ci2Hi806N=C02H.CH2.CH(NH.PhCO).C02Me.
kAXlO* at 25**= 1.93; diminishes on diln.; sinters 117M20%
melts 123**-124**.
Ai(32)=28.3, (512)=98.1, (oo)=374; 1397a.
Benzoylamino-succinic acid /3-mono methyl ester.
Ci2Hu06N-C02Me.CH2.CH(NH.PhCO).C02H.
Ben] TABLES 79
kxX 10* at 25**»6; m. p. 154** (cor.).
Ai(64)=61.3, (512)-147.0, (oo) = 374; 1397a.
Benzoyl-aspartic acid see Benzoylamino-succiiiic add.
Benzoyl benzenesislphonic amide see under Benzene sislphonic acid
amide.
o-Benzoylbenzoic add. Ci4HioQs"PiiCO.C6H4.C02H.
kAX 10^-3.8; diminishes on diln.
A(1024)« 171.7, (2048) =211.5, («)= 374.5; 1246.
Benzoyl chloride. CrHsOCl^ PhCO.Cl.
Cond. with anisole and AlCU; 1893.
Benzoyl cyanoamide see under Benzoic add amide.
Benzoylecgonine. C16H19O4N.
ks is of the order of IQr^^ (colorim.); 1778.
Benzoylecgonine methyl ester see Cocaine.
Benzoylmethyl- see Methylbenzoyl-
Benzoyl peroxide. Ci4Hio04» (Ph.CO)202.
In SO2, no cond. ; 1842.
^-Benzoylpropionic add. CioHioOj* PhCO.CH2.CH2.CO2H.
kA X 10^ at 25**=2.2; diminishes on diln.
A(64) = 13.3, (1024)=49.3, (oo)=356; 768.
IttbUe ^-Benzoylpropionic add ozime. (an^-Phenylketoximepropionio
acid). CioHuOiN=Ph.C(N.OH).C2H4.C02H.
AtO^ A(100.6)-17.7, (402.4)=27.4; m. p. 91^ 768.
siabUe /3-Benzoylpro^onic add ozime. (^n-Phenylketoximepro-
pionic acid). CioHuOjN.
kAXlO^ at 25^»1.7; increases on diln., from change in soln. to
the isomeric anii- acid; m. p. 129°.
At 0% A(101.6) = 10.8, (406.4) =22.8. At 25% A(64) = 11.7,
(1024)«50.5, (00) =355; 768.
Benzoylpyroracemic add. (Benzoylpyruvic acid).
CioH804= Ph.CO.CH2.CO.CO2H.
kAX 10* at 25*'=6.6 aq.; increases on diln.; m. p. 156**-158®.
A(400)=267.6, (1600)=325.9, (oo)=354; 23.
Benzoylsarcosine see Methylbenzoylamino-acetic add.
/3-Benzoyl-iso-succinic add. CuHioOs^ PhCO.CH2.CH(C02H)2.
kAX 10» at 25''=2.5; diminishes on diln.; m. p. 178M79%
Second kA X 10^=4.7 (inversion).
At25%M(64) = 114.5, (1024)=262.4, (oo)=351; 1638.
Benzylacetamide see under Acetic add amide.
Benzylacetic add see Hydrocinnamic add.
Benzyl alcohol. C7H80=PhCH2.0H.
X X 10« at 25**= 1.76; 1106, 1107.
In NH3, qual. ; 606.
As solvent; 334, 1106, 1107, 1680.
80 TABLES [Ben
Benzylalcohol-o-carbozylic acid see o-Hydrozymethyl-benzoic add.
Benzyl amine. CrHaN^PhCHs.NHs.
ka X 10* at 0**= 1.52; 776. At 25^-1.95; 776;-2.4 aq.; 16% too
high; 271. At 30*^-2.00. At 35**=2.18. At 40**-2.34. At
45**=2.33. At 50**=2.27. At 55*»=2.23; 776.
At25^ A(32)-5.6, (256)-16.3, (oo)«201; 271.
With allyl thiocarbimide, no cond.; 1223.
Relative strength by optical rotation; 1631.
B.HCl at 25^ A(32)=90.7, (1024) -101.4; 270. In SOj; 1866.
Benzyl bromide. CrHTBr = PhCHj.Br.
In SOs; 1829; qua!.; 1842.
Benzyl-iso-butenyltricarboxylic add. (Methylbenzylcarboxyglutaric
acid.) Ci4Hi606=PhCH2.C(C02H)j.CMe2.C08H.
kx X 102 at 25*^=1.4; m. p. 178^
m(64)=209, (512) =301, (oo)=348; 1839.
Benzyl chloride. CtHtCI^ PhCH2.Cl.
In HBr, no cond.; 1897. In SO2; 1842.
/3-Benzylcinnamic add see Diphenyl-crotonic add.
Benzylcresotinic add. CisHmOs « (PhCHj) (Me)C8H2(OH) (CO2H).
Cond. increased by boric acid; m. p. 164°-166®; 1186.
Benzyl cyanide. CsHtN = PhCH2.CN.
XX 10^ at 0^=1.10; 1843, 1844. At 20**=12; 1690a. At 25**-
1.56; b. p. 127*^ @ 23-25 mm.; 1844, 1843.
In NHs, qual. ; 606.
As solvent; 1690a, 1844, 1863a. As solvent, under pressure;
1690a.
Benzyldimethyl- see Dimethyl-benzyl-
Benzylethenyltricarboxylic add.
Cl2Hi206-CH2(C02H).(PhCH2)C(C02H)2.
kx X 102 at 25*'«3.2; m. p. 168.5^.
m(32)=217.7, (1024)=342, (oo)=350; 1839.
Benzylethyl- see Ethylbenzyl-
Benzylglutaconic acid. Ci2Hi204= PhCH2.CH(C02H).CH :CH.C02H.
kxX 10* at 25^=1.53; m. p. 145^
/i(69)-34.0, (1104) = 118.7, (00) =353; 1838.
BenzyUdene chloride. CyHeCfe-Ph.CHCk.
In HBr and H2S, no cond.; 1897.
BenzyUdene di-thioglycollic acid.
CiiHi204S2=PhCH: (SCH2.C02H)2.
kxX 10* [probably at 25**] =5.75; increases on diln.; m. p. 126**-
127^
/i(128)=89.1, (512) = 166.7, (oo)»375; 866.
7-Benzylidene-7-phenylp3rrotartaric add.
ei8Hi604= (Ph)(PhCH:) C.CH(C02H)(CH2C02H).
TABLES 81
kAX 10*-1.2; m. p. 151** for A.2H«0.
Ai(640)»84.5, (1280)- 111.5; 1664.
2,6-Benz7]i]iilnopyrine. (2,3-Dimethyl-l-phenyl-2,5-benzyliininopyra<
zole. Methylphenylbenzylaminopyrazole) . CisHi^Ns.
At 18^ A(20)=. 157.6, (1000) -154.
B.HI; m. p. 159**; at 18^ A(30)-65.7, (1200)-78.0; 1266, 214.
Benzyhnalonic add. C10H10O4- (PhCH2)CH(C02H)2.
kAX 10» at 18*'=1.6 (colorim.); 1663. At 25*^-1.51; m. p. 117**;
1838.
Second kxX 10^-4.9 (inversion); 1638.
At 25^ m(32)-68.9, (1024) -243, («)-354; 1838.
Benzyl mercaptan ethyl ether see Ethylbenzyl sulphide.
Benzylmethyl- see Methylbenzyl-
Benzylsacdnic add. CuHi204-C02H.CH2.CH(PhCH2).C08H.
kx X l(fi at 25**= 9.1; m. p. 161**; 201, 1838.
Ai(64)-25.6, (512) -67.5, (00) =351; 1838.
Benzyl sulphonic add. (Tolyl sulphonic acid).
C7H8O.S-PhCH2.SOjH.
At 25^ A(32)= 340.8, (»)=350. kx calculated by different
formulae gives no constant value.
Na.A at 25^ A(32)-61.5, (1024)=73.2; 423.
Benzyltartronic add. CioHioOs- PhCH2.C(0H) (C02H)a.
kxX 10» at 25**=5.5; m. p. 143^
Ai(72.5) = 163, (1160) -312, (00) = 352; 1838.
Benzyl nrethane see Carbamic add benzyl ester.
Beryllium see Gludnum.
Betaine see Trimethyl-aminoacetic acid.
Bi- see also Di-
Bibenzyldicarboxylic add see Diphenyl-succinic add.
Bile. [The references to this are incomplete. ]
Cond.; 261. Concentration of H and OH ions; 687.
Biliverdic add see Haemitinic imide.
Biliverdinic add see Haemitinic imide.
2,2'-Bis-ethyl8a]icylal-acetone. C2iH220s.
Comparative strength; m. p. 89*^; 1663.
2,2'-Bis-ethylsaUcylal cydopentanone. C28H240t.
Comparative strength; m. p. 110**; 1663.
Bis-methylvanillal-acetone. C21H22O5.
Comparative strength; m. p. 84**; 1663.
Bia-methylvanillal cydopentanone. C23H24O6.
Comparative strength; m. p. 195.5**; 1663.
Bia-nitrophenozy-malonic acid.
C15H10O10N2- (N02.C6H40)2C(C02H)2.
2Na.A, A(1024-32)-32; 194.
82 TABLES [Biu
Biuret see Allophanic acid amide.
Blood and blood serum. [The references are incomplete.]
X at b"" to 60%- 162, 163, 166a, 261, 262, 262a, 268, 266, 267, 268,
306, 307, 810a, 310b, 376a, 446b, 461, 607a, 644, 600, 628,
626a, 783a, 886a, 878, 880, 881, 1073, 1137a, 1239a, 1239b,
1361, 1362, 1363, 1462, 1632, 1670, 1619, 1622, 1623, 1624,
1626, 1626, 1626a, 1666a, 1666b, 1666c, 1768, 1769, 1983.
Cond. With acids; 1239b. With bases; 262a, 1239b. With
inorg. salts and organic compounds; 724a, 1363, 1397b,
1626a, 1666a, 1666c. With NaCl and with adrenaline; 267.
With various alcohols and with acetone; 1239b, 1622, 1623,
1624, 1626, 1626. Effect of coagulation; 600. Effect of
heating; 1239a, 1239b, 1462. Effect of pressure; 162, 163.
Concentration of OH ions; 648, 687, 803, 886, 886, 1111a,
1268b, 1269. Concentration of H ions; 687, 803, 1111a,
1268b, 1268c, 1269, 1601a. Effect of CO2; 1016.
Boric acid triethyl ester. C6Hi60tB»B(OEt)8.
In HCl, good cond. ; 1897.
Boric add trimethyl ester. C3H9QsB»B(OMe)s.
X X l(f at 0**-4.9. At 25**=6.2.
As solvent of NEt4l; 1844.
d-Bomeol. CioHisO = C10H17. OH.
In HCN, no cond.; 943. In NHg, qual.; 606.
cis-Bomeolcarboxylic acid. CiiHi80s»CioHie(OH).C02H.
kAXlO*=1.05 (colorim.); m. p. 101M02**; 274.
cis-frons-Bomeolcarboxylic acid. CuHigOs.
kAX 10^=2.55 (colorim.); m. p. 171**; 274.
Boron see Boric acid esters.
Brain. [The references to this are incomplete.]
Cerebrum, cond.; 166a.
Brilliant Green. (Tetraethyl-diamino-triphenyl carbinol.) C37HS4ON2.
The dye is a salt, usually the sulphate or a salt with zinc chloride.
Icb X lO' is less than 5.3 (colorim.) ; 1614.
Free base at 0^, |i(256)=24.3 at once; changes, on standing, to
the pseudobase which has no cond.
B.H2SO4, at 25**, A(128) = 173.7; also cond. at 0**; 770.
Brom- see Bromo-
Bromal hydrate. C2H0Bri(= CBrs.CHO) + H20« CjHsOiBri.
In NHs, qual. ; 606.
p-Bromo-acetanilide. (Acet-p-bromo-anilide).
CsHaONBr- C6H4Br.NH(MeCO).
In MeNH2, little cond.; 637.
Bromoacetic acid. C2H302Br » CH2Br.C02H.
IcaX 10" at 0**-1.56 aq.; decreases on diln.; 1018. At 18**= 1.46
Bro] TABLES 88
or 1.30 depending on value of A(a>) used; 460. At 25°»
1.38; slight decrease on diln.; 1370. T not stated (colorim.) ;
961.
At 25^ A(32)=68.7, (1024) -241.2, (00)= 362; 1370.
In HBr, good cond.; in HCl and HI, small cond.; in H2S, no
cond.; 1897. In NH3, qual.; 006. In Et ale; 647, 782,
1820.
Na.A at 25^ A(32)=72.0, (1024) -83.8; 270.
Bromoacetyl-anilinoacetic add see Bromoacetyl-phenyl aminoacetic
add.
Bromoacetyl bromide. C2H20Bi^ - CH2Br.C0Br.
X X 10^ at 0^=7.25; b. p. 146M47^
In SO2; 1842.
Bromoacetyl-plienyl amino-acetic add. (Bromoacetyl-anilinoacetic
acid. Bromoacetyl-phenyl glycine).
CioHiaO»NBr-Ph.N(CH2BrCO).CH2.C02H.
kAX 10^ at 25^-3.4; diminishes on diln.; m. p. 152^
A(200)-81.4, (1600)-180, (oo)=355; 1840.
Bromoacetyl-phenyl s^ydne see Bromoacetyl-phenyl amino-acetic
add.
Bromoaminobenzene see Bromoaniline.
Bromoanilic add. (2,5-Dihydroxy-3,6-dibromo-p-benzoquinone).
C6H204Bi^= (OH)2CeBr202.
m(192)=493.5, (1536)-658.1, (co)=871; 677. Quoted in 389.
At25^ A(128)=201.4, (1024)-293.0; 1276.
2Na.A, /i(192) -217.3; 677. - Na.A, at 26^ A(32)-126, (1024)-
288. - 2Na.A, A(32)-77.0, (1024)-87.1; 1276. - K.A; 677.
m-Bromoaniline. (Bromoaminobenzene).
C6HeNBr-Br.C6H4.NH2. [NH2-1.]
kB X 10*1 at 19*»-9.5 (colorim.); 1777. At 25**-3.82 (part.); 684.
p-Bromoaniline. CeHeNBr.
kaXlO^® at 18*^-2.07 (colorim.); 1777. At 25**- 1.0 (part.);
Cond. after diazotization; 1601.
2-Bromoaniline-6-sulphonic acid.
C6H60,NBrS-Br.C6H,(NH2).SO«H. [NH2-I; Br-2;
S0»H=5.1
kAX 10* at 25**= 1.49; impure, k diminishes on diln.
A(73.5)- 224.4, (1176)-312.6, (<x))-354; 1372.
4-Bromoamline-2-6ttlphonic add.
C6H«08NBrS. INH2-I; Br-4; SOjH-2.]
kx X 10* at 25**- 1.7; diminishes on diln.
A(219)-294, (1652)-322, (oo)-364; 1372.
84 TABLES [Bio
4-Bromoaiiiline-8-8ttlphoiiic acid.
CcHeOjNBrS. [NHj-l; Br=4; S0«H=3.]
kx X 10* at 25**«7.2; diminishes on diln.
A(64)-70.0, (1024)- 197.5, (a>)«364; 1372.
Bromobenzene. CeHsBr.
xXlO^at 18**=9.9; 386.
In HBr and HsS, no cond.; 1897. In NHs, qual.; 606. In
MeNHs, no cond.; 637.
Cond. with carvene and chloroform; 386.
p-Bromobenzene diazonitun syn-cyanide. (p-Bromodiazo benzene
cyanide). C7H4N8Br-C6H4Br.N2.CN.
Cond. in Et ale; m. p. 43''; 736.
p-Bromobenzene diazonium hydroxide. (p-Bromodiazo benzene).
CeHfiONjBr- C6H4Br.N2.OH.
kaX 10* at 0**=1.5. A(128) = 17.9, (1024) -47, (oo) = 135; 601.
B.Br; 730. - B.Cl cond. with KCN; 736. - B.CN; 736. - B.NOt;
730. anti-K.A; 774.
o-Bromobenzoic acid. C7H5O2Br-Br.C6H4.CO2H.
kx X 10* at 18**= 1.35 (colorim.) ; 1663. At 25''- 1.45; diminishes
on diln.; 1371.
At 25^ A(128)- 124.5, (1024) -242.2, (cd) = 356; 1371.
K.A; 1728. - Na.A at 25^ A(64)-66.1, (128) -68.0; 1728;
A(1024)-75.0; 1681.
m-Bromobenzoic add. C7H502Br.
kxXlO* at 18*^-1.4 (colorim.) ; m. p. 153M54**; 1663. At
25*^=1.37; 1371.
At25^ A(512)-82.6, (1024)-110.7, (cd)=356; 1371.
In NHs, qual.; 606.
Na.A at 25% A(32)-67.2, (1024)-77.2; 1368a. At 25** to QO*';
1681.
p-Bromobenzoic acid. C7H602Br.
kA X 10^ at 25**= 6.6 (solub.); 1116. Too insol. in aq. to measure
cond.; 1371.
Cs.A. - K.A. - Na.A at 25% A(64)=65.1, (128)-67.1. - Rb.A;
1728.
a-Bromobutyric acid. C4H7O2Br-Et.CHBr.CO2H.
kAXlO»at25**-1.06. A(128) - 109, (1024) =218, («) -355; 1840.
In SO2; 1842.
a-Bromobutyric acid ethyl ester. CdHuOzBr.
In SO2, no cond. ; 1842.
7-Bromobutyric add. C4H702Br = CH2Br.CH2.CH2.CO2H.
kx X 10* at 25°-2.62; m. p. 32*'-33% 1099 and 1908.
A(32) = 10.9, (64)-15.1, (cd)-356; 1099.
Bro] TABLES . 85
a-Bromobutyryl bromide. C4HeOBrs" Et.CHBr.COBr.
In SOi; 1842. [Walden gives the formula for the normal Bro-
mobutyryl bromide; but calls it the iso compound. No
b. p. is given.]
a-Bromo-tso-butyTyl bromide. C4H6OBr1sMe2.CBr.COBr.
In AsCla and in SO2; b. p. 161**-163^ 1842.
o-Biomocamphor sulphonic acid. (d-a-Bromocamphor-ir-sulphonic
acid.) CioHw04BrS.
At 25% m(30)«329, («)=355; 1841.
In acetone; 1841. In SO2, no cond.; 1842.
Cond. with quinidine; 1841.
Ba.2A. - G1.2A. - K.A. - Na.A at 25% m(30)=65.5, (960)-
76.0. - TLA. - Zn.2A. - Quinidine. A.; 1841.
Bromocamphorsolphonic chloride. CioHuO^ClBrS.
In SO2; 1842.
/3-Bromocaniiin. (Bromocarminic acid). CuH504Brs.
2NaA at 25% A(32)-76.7, (1024)=87.3; 1276.
Bromocarminic acid see Bromocarmin.
a-Bromodnnamic add. C^HTOsBr^ PhCH: CBr.C0sH.(j3- acid).
kAXlO* at 25^-9.3. A(441)-165.0, (1764)=246.2, (oo)-352;
1371.
jS-BromodimAmic add. C9H702Br-PhCBr:CH.C02H.(a- acid).
kAXlO* at 25*^=1.44; 1371;=1.3 aq.; 1681. At 40*'-0.96 aq.
At 50*^=0.79 aq. At 60*^=0.65 aq. At 70*^=0.53 aq. At
80''=0.44aq. At 90**- 0.36 aq. At 99"*= 0.29 aq.; 1681.
At 25% A(lll)-246, (888) = 329, (00) =352; 1371.
Bromodtraconic add. C6H604Br= C02H.C(CH2Br) : CH(C02H)?
kA XlO* at 25^» 1.49 aq. ; diminishes on diln. ; m. p. of the anhyd-
ride is 100*^-101^
/i( 107) =247.3, (856) =325, (00) = 355; 23.
Bromodtraconic add anhydride. CsHsOsBr.
Cond. of soln. in aq. showing change to acid; 23.
Bromodehydracetic add. C8H704Br.
Too insol. to get cond.; m. p. 136'*-137**; 668.
Bromo-diamino-p-suiphotolulc add see Bromo-2,6-toluylenediamine-
4-8ulphomc acid.
p-Bromodiazobenzene see p-Bromobenzene diazonium hydroxide.
2-(/3)-Bromoethyl amine. CsH«NBr= C2H4Br.NH2.
B.HBr at 25% A(32)=98.0, (1024) = 109.7; 270.
Bromoethyl bnsdnium chloride.
C26H3o04N2ClBr = CMH2604N2.(C2H4Br)Cl.
At 25% A(32)-75.1, (1024) = 91.5; 270.
86 , TABLES [Bio
Bromoethyl strychnlniiim chloride.
CasHMQaNaClBr* C2iHM02N2.(CjH4Br)CL
At 25^ A(32)=78.6, (1024)-90.8; 270.
Bromof orm see Tribromo-mefhane.
Bromogallic add. (3,4,5-Trihy(lroxy-2-bromobenzoic acid).
C7H606Br= (OH)8CeH(Br).C02H.
kAXlO* at 25^=5.91. iii(64)=62.4, (1024) = 188.0, (oo)-352;
1371.
Bromomaleic acid. C4H804Br » COsH.CBr : CH.CO2H.
At 26^ /i(32)=263, (1024) =355; 1372.
Bromomefhyl- see Mefhylbromo-
l-(a)-Bromonaplithalene. CioHyBr.
In SO2, no cond.; 1829, 1842.
Bromonitro- see Nitrobromo-
Bromophenylacetyl- see Acetyl-bromophenyl-
p-Bromophenyl-cyanourea. CgHeONsBr = Br.CeH4NH.C0.NH(CN).
kA X 10* at 25*'=2 (cond. and colorim.).
A(2048) = 188.4, (oo)»378; dec. above 325^ 214a.
l-p-Bromoplienyl-6-hydroxy-l,2,8-triazole-4-carbozylic acid ethyl
ester. CnHioOjNsBr.
kx X 10* at 25**= 2; m. p. 138.5** slowly heated.
m(420.3)=335, (1681.2) =359.9, (00) =371; 448.
norm.-p-Bromophenyl-nitromethane.
C7H«02NBr=Br.C6H4.CH2.N02.
At 0**, /i(2780)=2.5, probably due to absorption of COi; m. p.
60**; 776.
iso-p-Bromophenyl-nitromethane. C7H602NBr.
At 0^ /i(388)=23.2; m. p. 89**-90^ '
Na.A at 25^ /i(32)=73.6, (128)=79.9; also cond. with HCl; 776.
2-Bromo-p-phthalic acid.
C8H604Br=Br.CsH8(C02H)a. IC02H=1, 4; Br=2.]
kAXlO»at25**=6.2; 1909.
Second kAX 10**= 7.6; 1911.
At 25^ /i(254.8)= 263.3, (1020)=359.5, (co)=377; 1909.
2-Bromo-p-phthalic acid 1-mono methyl ester.
C»H704Br=Br.C6H8(CQ2Me)(C02H). [C02H=4; COaMe^l.]
kA X 10* at 25*'=3.7; diminishes on diln.; m. p. 145**; 1909, 1930.
iii(471.4) = 127.8, (1888)=207.3, (oo)=376; 1909.
2-Bromo-p-phthalic acid 4-mono methyl ester.
C9H704Br. [C02H=1; C02Me=4.]
kA X 10» at 25^=5.0; diminishes on diln.; m. p. 164**; 1909, 1930.
m(260)=249.6, (1041)=316.9, (oo)=376; 1909.
a-Bromopropionic acid. CsHsOaBr = Me.CHBr.CO2H.
kAX Iff at 25*^=1.08; m. p. 15**-20^
Bro] TABLES 87
A(128)- 110.4, (1024) -226, (oo)-368; 1840.
In SO2; 1842. In NHs, qual.; 606.
j3-Bromopropionic add. C8H5OsBr-CH2Br.CHs.CQ2H.
Ica X 10* at 25*'=9.8; diminishes slightly on diln.; m. p. 62.5**.
A(32) = 19.5, (1024) -95.3, (00) -358; 1840.
In NHs, qual.; 606.
Bromopyrotartaric add. C6H704Br - CsHsBr (C0tH)2.
kAXlO» at 25**=4.78; m. p. 204''; 1838.
Second kxX 10*^=5.1 (cond.); 1911.
At25^ m(64)-150, (1024)=322, (oo)=356; 1838.
(«).l*-Bromostyrolene. CgHyBr- Ph.CH : CHBr.
In SQ2, no cond.; 1829, 1842.
mod .-Bromosucdnic add. C4H504Br- CO2H.CH2.CH6r.COiH.
kAXlO* at 25''=2.7; m. p. IGO^'-iei^ 1824, 1838.
Second kAX 10^-3.9 (cond.); 1911.
At 25^ m(32)=91.5, (1024)-294, (oo)-356; 1838.
l-Bromosucdnic acid. CiHsOiBr.
kAXlO»at25**-2.7; m. p. 172^ 1824.
Second kAXlO*=2.5 (part.);-3.9 (cond.); 870.
InSOft, isinsoL; 1842.
NaH.A; 370.- 2Na.A at 25^ A(32)=81.7, (1024)-99.4; 270;
- 370.
Bromotetric add. C6H60iBr-Me.CBr.C8H20s.
kA X 10* at 25^-1; diminishes on diln.; m. p. 75'*-77^
m(640)-27, (1280) =34.9, (a>)-356; 1831.
3-Bromo-2-toluidine-<5-8ulphomc add.
CrHsOsNBrS = (Br) (NH2) .C6Hs(Me) (SO^H) . [Me - 1 ;
NH,-2; Br=3; S08H-5.1
kA X 10 at 25^-1; diminishes on diln.
A(32)-283.3, (1024)-333.1, (oo)»354; 492. [In 492 this is
given as Me-1; NHa=2; Br-5; SOjH-3.]
?-Bfomo-2-toluidine-?-8ulphonic add.
CrHsOsNBrS. [In 492 given as,
Me=l; NH2-2; S08H-4.]
kA X 10" at 25^ is about 1.4; diminishes on diln.
A(256)-159.2, (1024)=213.3, (a>)=353; 492.
?-Bro]no-4-toluidine-2-sulphonic add.
CrHgOiNBrS. [Me-1; NH2-4.]
kA X 10* at 25^-4.5; diminishes on diln.
A(64)-145.7, (1024)-287.6, (oo)=353; 492.
Bromo-2,6-toliiyieiiediamine-4-8ulphonic add. (Bromo-diamino-p-
sulphotoluic acid). C7Hs08N2BrS-Me.CoH(Br)(NH2)2.SOjH.
[Me-1; NH2=2,6; Br-3; SOjH-4.]
88 TABLES [Bio
kA X 10^ at 25''-1.72; diminisheB on diln.
A(135.5)-50.4, (1084)-122.1, (a>)-363; 1872.
Bromotrihydrozy- see Tiihydrozy-bromo-
5-Bromovaleric add. CftHaO^Br^ CH2Br.(CHs)s.C08H.
kAXlO* at 25''- 1.91; m. p. 39**-40**; 1099, 1908.
A(64) = 13.0, (00 ) =354; 1099.
Brudne. CS8HS6O4N2.
ks X 10* at 15^ is about 0.07 (hydrol.) ; 1779. At IS'^-O.l (cond.) ;
1224. At 20** is over 1.7 (colorim.) ; 1776. At 25**= 1 aq.;
1241.
Second keX 10"=2.5 (colorim.); 1776.
At 18^ m(751)-5.13, («)»193; 1224. At 25^ m(713)-11.1,
(1426)-22.3, (oo)-189.4; 1241.
In HON, fair cond. ; 948. In NHs, qual. ; 606.
B.HCl at 25^ A(32)-75.5, (1024)=89.2; 270; 1224. In
HON, smaU cond.; 948. - B.HNQs and 2B.HsS04; 1611.
- B.CfiHuCl, B.EtCl and B.(C2H4Br)Cl; 270. - B.Acetate;
146b.
Buckthorn see Rhanmus Frangula.
Bulbine.frutescens. [The references to this are incomplete.]
Cond. of sap of stem and leaves; 253, 1326.
a-Butanetetracarbozylic add. (Tetracarboxylic acid).
C8Hio08=CQ2H.CH2.CH(CQ2H).CH(CQ2H).CH,.C02H.
kxXlO^ at 25'*«4.0; increases on diln.; m. p. 233**; 1839; m. p.
236**; 66.
m(64)-51.8, (1024)-173, (oo)-350; 1839. m(32)-37.4, (oo)*
351; 868.
4Na,A, m(32)=81.0, (1024) -110.0; 66.
/9-Butanetetracarbozylic add. CsHioOg.
kA X 10* at 25*'-8; m. p. 189**; 1839;-4; m. p. 189**; 66. [Walden
says that the acid he measured, titred as a dibasic acid, and
that Bischoff got an acid, m. p. 185**, purer than that of
Auwers. ]
M(32)-37.1, (00) -351; 868.
Nasalt, m(32)-81.8, (1024)-110.8; 66.
ButenyltricarbozyUc add. (Ethylethenyltricarboxylic acid).
C7Hio06=Et.CH(C()2H).CH(C02H)2.
kAXl0'at25'*-3.07; m. p. 136*'-137.5'*; 1839.
Second kA X 10*- 2.2 (cond.); 1911.
At 25^ M(32)-94.7, (1024)-290, («)»353; 1839.
ifo-Butenyltricarbozylic add. (Dimethyl-ethenyl-tricarboxylic acid).
CrHioOft- Me2.C(C()2H).CH(COiH)2.
kA X 10» at 25**- 3.34; m. p. 148^
But] TABLES 89
m(32)»97.5, (1024)-297, (oo).353; 1839. See also /S-Dimethyl-
ethenyltricarboxylic acid.
tfo-Butylacetic add. C6Hi20s-MesCH.(CH2)2.C08H.
kxX 10* at 25*'= 1.6; b. p. 199 J"" (cor.); 180, 801.
A(32)«7.8, (1024)=41.7, (oo)=352; 180.
Na.A at 25^ A(32)=63.3, (1024) -73.6; 801.
norm.-Butyl alcohol. C4H10O.
In NHs, qual.; 806.
tso-Bntyl alcohol. C4HioO=- Mes.CH.CH2.OH.
X X 10> at IS"" is less than 1; 478. At 25''»8.4; 1849;-34; 1569.
In NHs, qual.; 606.
Cond. with oxalic acid; 46. As solvent; 334, 483, 1579, 1649.
iertkarjfButyl alcohol. (Trimethyl-carbinol). C4HioO»Mes.C.OH.
In SQs; 1829, 1842. In NHs, qual.; 606. In MeNHs, no cond.;
637.
Cond. with oxalic acid; 45. As solvent; 334.
iio-Butyl aldehyde. CiHgO.
In NHs, qual. ; 606.
iso-Butylaiiime. C4HuN-Me2.CH.CHs.NHs.
X X 10« at 25** is less than 2; b. p. 67 ''-69'' @ 745 mm.; 1388.
ks X 10^ at 25'' -3.1 aq.; about 16% too high; 271, 420. '
m(32)=19.6 (256)-48.6, (oo)-204; 271.
Cond. with acetic acid; and as solvent; 1388.
B.HCl at 25^ A(32)-92.4, (1024)-103.8; 270.
s«oofMfii7y*Bistylaiiime. (Methylethylcarbinamine) .
C4HuN-Et.CH(NH,).Me.
kB X 10^ at 25'' -4.4 aq.; about 16% too high.
m(32)=23.0, (256) -57.1, («)=204; 271.
B.HCl at 25^ A(32)-92.0, (1024) -103.8; 270.
leftaorif-Butylamine. (Trimethyl-carbinamine).
C4HuN-Me8.C.NH2.
kB X 10* at 25** =3.4 aq.; about 16% too high.
m(32)-20.3, (256)-50.4, (oo)=204; 271.
B.HCl at 25^ A(32)-92.3, (1024)«104.2; 270.
tfo-Butyl bromide. C4H9Br.
In NHs, qual.; 606.
Butyl cyanide see valeronitrile.
Bittylene bromide. C4H8Bi^i.
X X 10« at 25^ is less than 2; b. p. 150*^-152^ @ 741.2 mm.
Cond. with organic compounds and AgNt)s; 1388.
tfo-Butylene bromide. C4H8Brs- Me2.CBr.CH2Br.
With allyl thiocarbiinide, no cond.; 1223.
uo-Butylfnmaiic acid. (iso-Propylmesaconic acid).
C8His04-i8o.Bu.C(C02H) :CH(C02H).
90 TABLES [But
kAXlO* at 26**-9.3; m. p. 184^-185^
m(128)» 102.4, (1024) -220, (oo)-353; 1838.
norm.-Butyl iodide. C4H9I.
In HBr, HI and H2S, no cond.; 1897.
tso-Butyl iodide. C4H9I.
In HBr and H2S, no cond.; 1897.
/er^tdrif-Butyl iodide. (Trimethyl-methyl iodide). C4H9l»MesCI.
In SQ2; b. p. 99''-100''; 1829, 1842.
Butylmalonic acid. CrHisOi^ Bu.CH(C0ftH)2.
kxXlO' at 25*'«1.03; diminishes on diln.; m. p. 102^
m(32)»58.9, (1024)- 218, (<»)-355; 1838.
iso-Butylmalonic add. C7H12O4.
kxXlO* at 25''=9.0; diminishes on diln.; m. p. 107^
m(32)=55.4, (1024)«214, (oo)-365; 1838.
Butylmethyl- see Metliylbatyl-
iso-Butyl nitrate see Nitric acid iso-butyl ester.
tfO-Butylphenol. C10H14O.
kAXl07at25''=2.7.
A(328)=3.3, (1312)=6.7, (a>)-366; 70. [There is no way of
determining what this phenol is. ]
iso-Butyl phosphoric add see Phosphoric add tso-butyl ester.
Butylquinolinium tri-iodide. CuHuNIs^CsHtN.BuI.Is.
Cond. in molten state; m. p. 60.7^; 1578.
ifO-Butylquinolinium tri-iodide. CuHuNIs.
Cond. in molten state; m. p. 85.6^; 1578.
ifO-Butyl-sucdnic add. C8Hi404« COzH.CHCtso-Bu) .CH2.CQ2H.
kAXlO* at 25*'=8.82; m. p. 104*^-105**; 1823, 1838.
m(32) = 18.1, (1024) = 90.4, («) = 351; 1838.
2Na.A at 25^ /i(32)=74.7, (1024)-92.3; 1823.
iso-Butylsulphuric add see Sulphuric add mono tso-butyl ester.
Butyramide see Butyric add amide.
rO-1
Butyrhydrozamic add. C4H902N- CsHyCH.N.OH.
kAX 108 [probably at 25*']= 2.3.
m(16)=0.2, (32)=0.4, (oo)=[380]; 1363a.
Butyric acid. C4H8Q2« Me.CH2.CH2.CQ2H.
xXlO^ at 18''»6; 1380; also 517.
kAXlO^ at O^'-l.ee aq.; slight increase on diln.; 1018, 1968a.
At 9.4^*1.63; 1968a. At 10*'-1.67; 875. At 14^=1.56 aq.;
838. At 18''- 1.6; 93, 94, 48; (colorim.); 1563. At 20''»
1.71; 875. At 25**= 1.6. The values vary greatly, probably
because of the difficulty of purifying the acid. The extremes
are, 1.45 and 1.75; 180, 461, 601, 1184, 1368, 1370, 1968,
1968a; - (absorption of CQ2); 139. At 30^=1.70; 876. At
But] TABLES 91
35^-1.47; 1968a. At 40**- 1.66; 875. At 62^-1.64; 48.
At 55^»70 (action of diastase on starch); approximate;
2002. T not stated; (colorim.); 951, 1643, 1781; (precipita-
tion of casein) ; 693.
At 25% A(32)=7.7, (1024)=40.6, (a>)=356; 1370. A(1024) =
42.2; 180. At 0''-35*'; 1968, 1968a. At 10*^-50**; 876. Also
43, 93, 642, 646, 787, 788, 1747.
In HBr and HCl; 30. In NI^, qual.; 606. In Me, Et and norm.
-amyl ale. ; 787, 788. In amyl ale. ; 932.
Cond. with boric acid; 1184. With inorg. salts; 1994. With
organic compounds; 93, 94, 1011, 1620, 1747, 1994. Under
pressure of 1-260 atmospheres; 542.
Ba.2A; 94. - Li.A; 1367. - Mg.2A; 1836. - E.A; 94, 1367.
- Ag.A; 1637.- Na.A at 25% A(32)=67.4, (1024)=77.4;
1368a, 1367. Also 43, 93, 94, 875, 1416, 1537, 1837, 1968a.
With organic compounds; 94, 1994. Under pressure of
1-260 atmospheres; 542. - Cinchonine.A; 1620.
Butyric acid amide. (Butyramide) . CiH^ON = Me. (CH2)j.CO.NH2.
Cond. with HCl and NaOH; 410, 412. With HgCl,; 1097.
Butyric acid cyanoamide. (Butyrylcyanoamide).
CbHsON,- Me.(CH2)2.CO.NH(CN).
kx X 10* at 25**= 1.12; increases on diln.
A(35.9)=20.7, (1148.8) = 105.6, (a>)=352; 70.
Butyric add amyl ester. C9Hi8Q2» Me.(CI^)2.CQ2C6Hu.
In NH,, qual.; 606.
Effect of temperature on cond.; 106.
Butyric acid tso-butyl ester. CgHieQs.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Butyric add ethyl ester. CeHuO^^ Me.(CHt)s.CQ2Et.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Butyric add glyceryl ester. (Tributjrrin).
Ci6HmO«= (PrCQ2)8.C8H6.
In NHs, qual. ; 606.
Butyric add methyl ester. C6HioOt.
In NHs, qual. ; 606.
Effect of temperature on cond.; 106.
Butyric add propyl ester. C7H14Q2.
Effect of temperature on cond.; 106.
ic add. C4H8Q2* Me2CH.CQ2H.
X IB very small; 517.
kA X 10* at 0^-1.55; 1968a. At 10^=1.59; 875. At 16.5**- 1.53;
1968a. At 18^-1.6 (colorim.); 1563. At 20*'=1.62; 875.
92 TABLES [But
At 25^»1.6. The variation of values is probably due to the
difficulty of purifying the acid. The extremes are 1.41 and
1.62. See 180, 420, 461, 601, 1370, 1968a. At 30''= 1.61;
875. At SS*'^ 1.42; 1968a. At 40**- 1.56; 876. At 55**= 80
(action of diastase on starch); approximate; 2002. T not
stated; (colorim.); 1643.
At 25% A(32)=7.9, (1024)-43.6, (oo)«356; 180. A(3.2) = 7.5,
(1024)«39.7; 601. At 0*'-35^ 1968a. At 14^-50*'; 876;
also 642, 619, 1564.
In NHs, qual.; 606.
Cond. with inorg. salts; 1554. With organic salts; 1994. Under
pressure of 1-260 atmospheres; 542.
Li. A; 1367. - Mg.2A; 1836. - K.A; 1367. - Ag.A; 656, 1537.
- Na.A at 25% A(32)=67.2, (1024)«77.7; 1368a, 1367. At
10''-50**; 875. Under pressure of 1-260 atmospheres; 542.
iso-Butyric acid amide. (iso-Butyramide) .
C4H»0N- MejCH.CONHj.
Cond. with HCl; 410. With NaOH; 412.
tso-Butyric acid anhydride. CsH^Os.
X X 10^ at O''^ 0.994. At 25''» 1.60; 1843, 1844.
Cond. as solvent of NEtJ; 1844.
ISO-Butyric acid tso-butyl ester. CsHuOz.
Effect of temperature on cond. ; 106.
ISO-Butyric add ethyl ester. QHuC^.
Effect of temperature on cond. ; 106.
Butyro nitrile. (Propyl cyanide) . C4H7N = CtH7.CN.
xXlO* at 25**= 1; b. p. 115.4M15.6** @ 739 mm.; 482.
Butyrylcyano- see Cyanobutyryl-
Butyrylcyanoamide see Butyric acid amide.
C.
Cacalia anteuphorbium. [The references to this are incomplete.]
Cond. of sap; 253, 1326.
Cacodylic add. (Dimethyl-arsinic acid). CsH7QsAsBMe2.AsO.OH.
kAXlO^ at 0*»-4.1; 2009. At 25*^-7.5 (sapon.); 855a;=6.4
(cond.); 888; 2009; (sapon.); 738, 1141, 1160. (Colorim.);
1773.
kB X 10"» at 0*'=0.42 (hydroL); 2009, 2010. At 25''=3.8; 888;=
5.6 (sapon.); 855a, also 2009, 2011, and 738.
Cond.; 1269, 1747, 1836. At 25^ m(32)«1.3, (256)=4.4, (00 )«
354.5; 888.
Cond. with HCl and HNQs; 2009. With MoQs; 1269. With
lactose; 1747.
Cim] TABLES 98
Ba.2A; 2009. - Mg.2A; 1836. - Na.A at 0^ 2009. At 25^
m(32)=63.7, (1024)=74.1; 2009; 788. -B.HCl and B.HNOs;
2009.
Cadmium.
In complex salts; 1384, 1481, 1482, 1946.
See also the following compound.
Cadmium cyanic acid. C4H2N4Cd » H2Cd(CN)4.
2K.Aat25% A(32)-110.0, (1024) = 125.1; 1832; 1486.
Caffeic add. (3,4-Dihydroxy-cmnamic acid). CaHsOi.
Cond. increased by boric acid; 1186.
Caffeine. (l,3,7-Trimethyl-2,6-dioxy-purine. 1,3,7-Trimethyl-xan-
thine). C8H10Q2N4.
IcaX 10" at 25*" is less than 1 (solub.); m. p. 234**; 1997.
kB X 10^® at 15** is less than 1 (colorim.); 1776. At 25''=200 aq.
[of doubtful value]; 1241. At 40. l''^ 0.0004 (sapon.); 1996,
1997 and 1160.
At 25^ m(22)=-0.15, (42)=0.2, (oo) = l95; [accuracy doubtful];
1241.
In HON, no cond.; 943. In SOt; 1842. In NH,, qual. ; 606. [In
1842 this is given as theine, with formula C8H10O4N2, diie
probably to a typographical error. ]
Camphocarbozylic see Camphorcarbozylic.
a-Campholenic acid. CioHi602=C9Hi5.C08H.
kAXlO* at 18*'=1.7; b. p. 258^-261^
A(361)=22.3, (1911)«53.1, (oo)-317; 1899.
Campholic acid. CioHi802«C9Hi7.C(>2H.
kx X 10* at 25''»4.6; diminishes on diln.
A(1024)-23.5, (2048)=30.8, (oo)=353; 1372.
€i»-A^ai»-Camphol3rtic add. C9Hi4Q2=C8Hi8.C02H.
kxXlO* at 25**=9.3; b. p. 240^-242^
A(94.5)-10.3, (756.0)-28.8, (oo)=352; 1861.
tso-Camphol3rtic add. (iso-Lauronolic acid). C9Hi4Q2»C8His.C02H.
kA X 10* [at 25**]= 8.6; m. p. 133^ (cor.); 1862, 1861. [This is the
camphothetic acid of 1861.]
A(850)=28.7, (00) -351; 1862.
Camphononic add. CaHuOs^ CtHmCO.COzH.
kxXlO* at 18**= 3.9 (colorim.); 1563.
Camphopyric add. (Apocamphoric acid. Pyrocamphenic acid).
C9Hi404= C7Hi2(COjH)2.
kAXlO* at 18**-3.5 (colorim.); 1663.
d-Camphor. CioHuO.
In HON, no cond.; 943.
Cond. with acetic acid;. 1386.
Camphoramic add see Camphoric add amide.
94 TABLES [Cam
Camphoranic add. (a-Hydroxy-camphoronic acid).
C9H12O6 +H20= C6HioQ2C(C02H)2 +H2O.
kAXlO'at25''=3.2; 1872.
Second kAXlO«= 6.5 (inversion); 1638;»13; 1911.
At 25^M(64)- 127.6, (1024) = 286.2. (oo)-352; 1372.
Camphorcarbozylic acid. CuHuQs^CioHisO.COzH.
IcaX 10* at 18**«2 (colorim.); 1663. At 25^=1.74; 1372.
At 25^ A(64)=35.0, (1024)-119.6, (oo)=«351; 1372.
In benzene, no cond.; 289. In Me ale; 290.
Na.2A; in benzene, no cond. - Na.A in Me ale; 289.
Camphorcarbozylic acid amyl ester. CuHseO^.
Na.A in ether, no cond.; 289.
Camphorcarbozylic acid methyl ester. CuHisOs.
Na.A in benzene, no cond. Cond. in Me ale; 289.
d-Camphoric acid. CioHwOi- C8Hi4(CQ2H)2.
kAXlO* at 18*'=2.5 aq.; 164; (colorim.); 1562, 1563. At 25^«
2.25; 1372; m. p. 186^ and 187**; 1666, 1824.
Second kAX 10^=7 (inversion); 1638;»140 (part.); 370.
At 25^ m(64) = 13.0. (1024) =49.3, (oo)=352; 1372. Also 171.
In HCN, little cond.; 943.
Cond. with KOH; 171. Cond. not increased by boric acid; 1184.
2K.A at 18.2^ /i(150)=75.3, (1500)=82.2. - KH.A; 164.
Camphoric acid a-mono amide. (a-Camphoramic acid).
CioHi70aN=C8Hi4(C02H)(CONH2). [CQjH^/S.]
kAXlO^ at 25^" 1.4; diminishes on diln.;»0.84 after 16 hours;
1243.
At 25^ m(64)«10.3, (256) = 17.5, («)c=350; 1244.
Camphoric add /3-moiio amide. (/3-Camphoramic acid).
CioHnOsN = C8Hi4(CONH2) (CO2H) . [CQjH =a. ]
kAX 10* at 25**= 1.28; increases on diln.; 1243.
At 25^ m(64)=9.7, (512) =27.7, (oo)-350; 1244.
d-Camphoric add mono aHo-methyl ester.
CuHisOi- C8Hu(CQ2H) (CQjMe).
kA X 10* at 25''=1.08; m. p. 85.5^
/i(209.5) = 16.2, (838.0)=31.5, («)«350; 1860.
d-Camphoric add mono o-methyl ester.
C11H18O4- C8Hi4(CQ2Me) (CQ2H).
kA X 10« at 25**-7.95; m. p. 76^
m(118)«10.5, (944) -29.1, (oo)=350; 1860.
1-Camphoric add. C10H16O4.
kAXlO* at 26^=2.28; m. p. 187^; 1824.
Second kAXlO''= 7 (inversion); 1688.
Cond. with organic acids; 1638.
Cap] TABLES 95
moc^.-Camphoric add. C10H16O4.
IcaX 10* at 25*^=2.29; m. p. 202**-203*'; 1824.
Second kAXlO'=7 (inversion); 1688.
d-tso-Camphoric acid. C10H16O4.
kAXlO*at25*'=1.74; m. p. 171M72%- 1824.
1-uo-Camphoric add. C10H16O4.
kA-X 10* at 25''= 1.60; m. p. 172.6^ 1889.-1.74; m. p. 171M72^;
1824.
Second kxX 10^=5.9 (inversion); 1688.
At 25^ m(70.5) = 11.7, (564) =31.8, (oo)-352; 1889.
Cond. with organic acids; 1688.
1-tso-Camphoiic add mono o-ethyl ester.
Ci2H2o04= C8Hi4(CQ2H) (COaEt).
kA X 10* at 25*^=6.5; m. p. 73.5^
m(244) = 13.8, (488) = 19.1, («)=350; 1889.
moc/.-isa-Camphoric add. C10H16O4.
kAX 10* at 25**= 1.74; m. p. 190''-19r; 1824.
meso-Camphoric add. C10H16O4. [This was a mixture of acids.]
Second kAX 10^=6.6 (inversion); 1638.
Camphoric add imide. (Camphorimide). CioHisC^N.
Cond. with HgCU; 1097.
l-Camphoronic add. (oajS-Trimethyl-tricarballylic acid).
C9Hi406=C02H.CH,.CMe(C02H).CMe2.CQ2H.
kAX 10* at 18^=1.8 (colorim.); 1562, 1663. At 25^=1.75; 1372.
Second kAXlO«= 8.3 (?) (inversion); 1638.
At 25% m(32)=25.3, (1024) = 121.3, (oo)=352; 1372.
Camphor ozime. CioHnON.
In NHs; 604.
Camphor quinone. CioHi402-
KCN derivative (=CioHi40.0K.CN) is a moderately good
electrolyte; 1060.
Camphothetic add see uo-Campholytic add.
Cane sugar see Saccharose.
Capric add. CioH2o02= Me.(CH2)8.C02H.
In NH,, qua].; 606.
Caproic add. (Capronic acid. Hexoic acid).
C6Hi202= Me.(CH2)4.C.02H.
kAXlO* at 25''= 1.46; 180, 461, 1370;= 1.38; b. p. 205.7% 601;
(colorim.); 1781.
A(32)=7.5, (1024)=40.3, (oo)=352; 1370.
In NH3, qual.; 606.
Na.A at 25% A(32)=64.0, (1024)=73.8; 601, 1368a.
Caproic add amide. (Capronamide). C6Hi80N= Me.(CHs)4.CONH2.
Cond. with HCl; 410. With NaOH; 412.
96 TABLES [Cap
tso-Caproic add. (tso-Capronic acid).
QHiaOi- Mej.CH.CHMe.COjH.
kAXlO*^ at 25*'=1.57. A(27.8) = 7.5, (442.5)=29.6, («)-368;
461. Cond. with organic acids; 145b.
Capronamide see Caproic acid amide.
Capronic add see Caproic add.
Capronitrile. (i«o-Amyl cyanide. Caproyl nitrile).
CeHuN-CftHii.CN.
xxl0«at25*'«3.3.
Cond. with Cu oleate; and as solvent; 1669.
CapryUc add. C8Hi«02« Me. (CH2)6.COjH.
kxX 10* at 25**= 1.44; b. p. 237.5*' (cor.).
A(256)=20.6, (1024)=40.2, (oo)=351; 601.
In HCl, little cond.; 30. In NH3, qual.; 606.
Caprylic acid ethyl ester. CioH2oQ2.
In NH,, qual.; 606.
Carballylic acid see Tricarballylic add.
Carbamic add. (Aminofofmic acid). CHsO^NsNHs.CC^H.
NH4.A; 302a.
Carbamic add amide see Urea.
Carbamic add benzyl ester. (Benzyl urethane).
CsHgOsN" NH2.CQ2.CHtPh.
In pyridine; 764.
Carbamic add ethyl ester. (Urethane). CsHTOzN^NHs.CQsEt.
xXlO^at 18*'=5; 1470.
In HON, no cond.; 943. In NHs; 610.
Cond. with HgCh; 1097. As solvent of inorg. compounds; 748,
1470.
Carbamide see Urea.
Carbamide imide azide see Diazo guanidine.
o-Carbaminebenzene sulphonic add see o-Sulphobenzoic add amide.
CarbaminethioglycoUic add. C8H608NS» NH2CO.SCH2.CO2H.
kAXl0*at25**=2.66;=2.61 (catal.); m. p. 139M39.5'' with dec;
864, 1370.
A(32) = 30.5, (1024)« 136.8, («)=:360; 1370.
CarbaminethioglycoUic add anhydride see Diketo-tetrahydro-thiazole.
Carbazole. C12H9N.
InNHs, qual.; 606.
Carbon disulphide. CS2. [The references to this are incomplete.]
XX 10^ at 18''»2; 263, 306, 384, 386, 1010, 1098, 1344, 1666.
Cond. with organic compounds; 263, 386. Complex with AlBrs,
EtBr; 1437. Of thin layer; 301. Effect of radium and
X-rays on cond.; 417, 872, 1491, 1806. As solvent; (711),
(1446).
Cas] TABLES 97
Carbonic add. CH«0^. [The references to this are incomplete.]
kAXlO^ at 18^-3; 733, 1866, 1883.
Carbonic acid diethyl ester. C6HioQs» 0C(0Et)2.
In NHs, qual.; 606.
With allyl thiocarbimide, no cond.; 1223. Effect of tempera-
ture on cond.; 106.
Otiier esters of carbonic acid.
Aminophenyl ethyl carbonate see under that head.
Aminophenyl methyl carbonate see under that head.
Methyl-aminophenyl ethyl carbonate see under that head.
Carbon tetrachloride see Tetrachloro-methane.
Carbonyldi-thioglycollic acid see Dithio-carbondiglycollic add.
Carbopyrrolic add see Pyrrolecarbozylic add.
Carbostyril. (2-Hydroxy-quinoline). C9H7ON.
kaXlO' at 18*'«1.94 (colorim.); 1777. Cond. very small, due
to impurity; 733.
o-Carbozyanilinoacetic add methyl ester see Phenylglycine-o-car-
bozylic add ezo mono methyl ester.
Carbozydehydroacetic add. (Dehydroacetylcarboxylic acid).
CsHsOe.
kxXlO* is about 3. m(158)=300.2, (632)«318, (oo)=350; m. p.
154**; 13d9.
o-Carboxymethyl-anilinoacetic add see Phenylglycine-o-carbozylic
add eso mono methyl ester.
Carbylozime see Fulminic add.
Carminic add. C22Hs20is. Also given as C11H8O4, CuHuOe, C11H12O7
and CitHisOio.
Na.A at 25**, A(32)-58.0, (1024) -69.6 for molecular weight 480.
" =63.1, " «80.0 " " " 492.
" =56.5, " -87.6 " " " 534;
1276.
Canracrol. (4-MO-Propyl-2-hy droxy-toluene) .
C10H14O- Me2CH.C6H3(OH).Me.
In HBr; 29.
Cond. with NaOH alone, and with HCl; 1608.
Carvene see Limonene.
Carvole see Carvone.
Carvone. (Carvole). C10H14O.
In NHs, qual. ; 606.
Cascarilla. [The references to this are incomplete. ]
Cond. of dil. soln. of bark; 146.
Casein. [The references to this are incomplete. ]
The composition of casein seems to depend on its source. There
are several different caseins, and the difficulty of purifying.
98 TABLES [Cos
makes it impossible to get one moderately pure compound.
In the following references the casein is probably from cow's
milk. For a partial review of the literature see 1501.
Cond. alone; U6b, 1699. With acids; 1120, 1636. With bases;
145b, 1504, 1606a, 1636. With inorg. salts; 146b, 1599.
With HgCls, formaldehyde and phenol; 1599. With pepsin
and with trypsin; 145b. Concentration of H and OH ions;
422, 1506, 1611b.
NH4 salt; 145a, 146b, 1054, 1504, 1505, 1565. - Mg salt; 1365a.
- Na salt at 25^; composition uncertain, is 4Na or 6Na.A;
A(40)»46.5, (640)»69.5; 1063.- 146a, 1054, 1504, 1605,
1666, 1599, 1636. With NaOH soln. and erepsin; 523.
- Acid Na salt; 1053.
Casein from cow's milk. NH4 salt. - Li neutral and acid salts.
- K neutral salt. - Na neutral salt at 20^ A(1024-32) =
26.2; also acid and basic Na salts; 1118. Effect of diges-
tion with pepsin and HCl; 1119. Ba, Ca and Sr salts;
1506b.
Casein from goat's milk. Neutral K salt and Na salt; 1118.
Effect of digestion with pepsin and HCl; 1119.
ISO-Casein. [The references to this are incomplete. ]
Na salt at 25^ A(137)«67.5, (1096)«89.2; 1064. Qual.; 1555.
^ara-Casein. [The references to this are incomplete. ]
Cond. at 25^ is about 2% higher than that of casein; 1053.
Caseinogen. All references to this are given under Casein.
Castor oil. [The references to this are incomplete. ]
Resistance; 1010.
Castor oil plant see Ricinus communis.
Cerebrospinal fliud. [The references to this are incomplete.]
x; 621.
Cerebrum see Brain.
Cetyl alcohol. Ci«H840 = CwHaa.OH.
Cond. at 0**-104^; 101, 110.
In NH3, insol.; 606. In MeNH2, no cond.; 637.
Cetylmalonic add. CieHscOi* C02H.CH(Ci6H88).CQ2H.
kx X lO'' at 25**= 3; increases on diln.
/i(256) = 2.6, (1024) = 6.1, (00) = 350; 1638.
Chelidonic acid. (Acetone-dioxalic acid anhydride).
C7H406= CO(CH : C.C02H)2 :0.
At 25% m(62.9)=427, (503) = 611; 1372.
Chlor- see Chloro-
Chloral. (Trichloro-acetaldehyde). CaHOCla^CCla.CHO.
In HCN, no cond.; 943.
Chloral alcoholate, hydrolysis; 292.
Chi] TABLES 99
Chloralcyanohydrate see Trichloro-lacto nitrile.
Chloral hydrate. CHOCla(=CCla.CHO)+H20=C2H8Q2Cl,.
kA X 10" at 0*'«0.4 (hydro!.). At 18*'= 1 (hydro!.); 612.
At 0.65**, X X 10« of 0.01 normal soln.=6; 602.
In NHs, qua!.; 606.
Cond. with inorg. acids; 741. With inorg. bases; 602, 612.
Hydrolysis measured by b. p. elevation and f. p. depression;
292.
Chloroacetamlino-acetic acid see Chloroacetyl-phenyl amino-acetic
acid.
Chloroacetic acid. C2H802C1»CH2C1.CQ2H.
kAXlO^ at 0*'=1.81 aq.; diminishes on diln.; 1018. At U.I*'-
1.58 aq.; 888. At 25*'=1.55; 1370; (neutral.); 296, 1718;
(colorim.); 1643. Relative strength (polarimetric) ; 1866;
(precipitation of casein); 693.
Cond.; 294, 347, 441, 782, 877, 1094. At 25^ A(32)=72.4,
(1024)=249.2, (cx>)=362; 1370.
In HCl, poor cond.; in HBr, HI and H2S, no cond.; 1897. In
SQz; 1842. In H2SO4; 223, 1834. In N2O4, no cond.; 602.
In NHs, qual.; 606. In acetone; 476. In Et ale; 647, 782,
932. In pyridine; 764. ' In tetranitro-methane; 1844.
Cond. with HCl; 426. Cond. not increased by boric acid; 1184.
With EOH; 294. With KCl; 1994. With acetic acid and
NaOH; 1717, 1718. Under pressure of 1-500 atmospheres;
220.
NH4.A;823. - Hg.2A;1094. - Na.A at 25^ A(32)= 73.4, (1024) «
85.2; 1368a, 270. In Et ale; 932. - UQ2.2A; 449.
Chloroacetic add amide. (Chloroacetamide).
C2H40NC1=CH2C1.C0NH2.
In NHs; 610.
Cond. with HgCl2; 1097.
Chloroacetic add ethyl ester. C4H702Cl»CH2Cl.CQ2Et.
X X 10« at 25** is less than 1.7; b. p. 143.5**; 1106, 1107.
Effect of temperature on cond. ; 106.
As solvent; 1106, 1107.
Chloroacetyl bromide. C2H20ClBr = CH2Cl.C0Br.
In SQ2; 1842.
Chloroacetyl-phenyl amino-acetic acid. (Chloroacetanilino-acetic acid.
Chloroacetyl-phenyl glycine).
CioHio03NCl=(Ph)(CH2ClCO)N.CH2.C02H.
kA X 10* at 25^=3.4; m. p. 130^
A(200)=81.6, (1600) = 182, (a>)=355; 1840.
Chloroamino- see Aminochloro-
100 TABLES [Chi
Chloroaiiil. (Tetrachloro-p-benzoquinone) . CeOftCU.
In NHs, qual.; 606.
Chloroanilic add. (2,5-Dihydroxy-3,6-dichloro-p-beii2oquinone).
C6H204Cl2= (OH),C«Cl2Q2.
m(192)-369.1, (1536)-514.3, (oo)-754; 577. Quoted in 889.
At 25^ A(128) = 192.4, (1024) -263.7; 1275. -729.
2K.A; 677, 1276.- 2Na.A at 25^ A(32)=78.6, (1024)=88.7;
1276; m(192) = 175.1; 677. - Na.A; 1276.
o-Chloroaniline. CeHeNCl- Cl.CeHi.NHj.
kB X 10" at 19*'=9.16 (colorim.); 1777.
B.HCl at 25^ m(50) « 160.0. - 2B.H2SO4; 1864.
m-Chloroaniline. CeHeNCl.
keX 10" at lO^'-O.ee (colorim.). At 13**-0.77 (colorim.); 1777.
At 25''^4.8 (hydrol.); 660, 1293.-3.45 (part.); 684.
B.HCl at 25^ m(50)-132.6; 1864. M(32)-116.6, (512) = 190.7;
m(32)-92.6; 1293.- 2B.H2SO4; 1864.
p-Chloroaniline. CeHeNCl.
kaXlO" at 10*'-1.24 (colorim.); 1777. At 25^=9.9 (part.);
684,648.
B.HCl at 25^ m(50)- 120.0. - 2B.H2SO4; 1864.
Chlorobenzene. QHsCl.
In NHs, qual. ; 606.
p-Chlorobenzene diazomum sirn-cyanide. (p-Chlorodiazo benzene
cyanide). C7H4NaCl-Cl.C6H4.N2.CN.
At0^/i(327) = 15.3; 736.
o-Chlorobenzoic add. C7H6O2CI - CI. CeH4. CQ2H.
kA X IV at 18**- 1.35 (colorim.) ; 1663. At 25**= 1.32; 1371, 1681.
At40'*«1.0aq. At 50*'- 0.9 aq. At 60** -0.8 aq. At 70*'=
0.7 aq. At 80''-0.6 aq. At OO^'-O.S aq. At 99**- 0.4 aq.;
1681.
At25^ A(64) = 89.2, (1024)-238.7, (a>)«356; 1371.
Na.A at 25^ A(32)-67.3, (1024) -77.8; 1368a. At 25*^-99**;
1581.
m-Chlorobenzoic add. C7H6O2CI.
kxXlO* at 18**- 1.4 (colorim.); 1663. At 25*'-1.55; 1371.
At25^ A(256)-64.3, (1024)-116.2, (oo)«356; 1371.
p-Chlorobenzoic acid. C7H6Q2CI.
kxX 10* at 18**-9.9 (colorim.); 1663. At 25''-9.3; 1371.
At25% A(2048) = 125, (oo)=356; 1371.
Chlorobromofluoroacetic add. C2H02ClBrF-CClBrF.CQ2H.
kx X 10 at 25** is about 2.
A(32)-313.9, (1024)-350.8, (oo)=351.6.
Na.A at 25% A(32)-67.4, (1024)-75.8; 1701.
GU] TABLES 101
S-Chloro-B-bromogaUic add ethyl ester. (3,4,5-Trihy(lroxy-2-chloro-
6-bromo-benzoic acid ethyl ester).
C»H80«ClBr«(Cl)(Br)C6(OH)8.CQ2Et. [CQaH^l.]
kA X 10« at 25'*»2.2; diminishes on diln.; m. p. 134**-135^
m(32)=3.0, (256) -6.0, (oo)=349; 404.
2-Chloro-6-bromogaUic add methyl ester. (3,4,5-Trihydroxy-2-chloro-
6-bromo-benzoic acid methyl ester). CsHflOsClBr.
kAXlO" at 25*'=5.2; diminishes on diln.; m. p. 162M63^
/i(32)«4.5, (256) =7.2, (oo)- 350; 404.
p-Cblorobromosacdnic add. C4H404ClBr»C()8H.CHCl.CHBr.CQ2H.
In SQs, insol. ; 1842.
a-Chlorobutyric add. C4H7O2Cl-Me.CH2.CHCl.CQ2H.
kA X 10» at 25*'-1.5; diminishes on diln.; b. p. 101.3** @ 15 mm.
A(32)-69.8, (1024) -232.5, (oo)«356; 1099.
/5-Chlorobutyric add. C4H7Q2Cl-Me.CHCl.CH2.CQ2H.
kAX 10* at 25*'-9; b. p. 108.5*^-109.5*' @ 17 mm.
A(32)-18.6, (1024)-91.7, («)-356; 1099.
T-Cblorobutyric add. C4H7Q2CI-CH2CI.CH2.CH2.CQ2H.
kAX 10* at 25*^-3.
A(32) = 11.5, (64) = 16.2, (oo)=356; hydrolyzes to HCl; 1099.
Cblorocarbonic add see Chloro-formic add.
l^Chlorocixmamic add. (a-Chloro-iso-cinnamic acid).
C9H7O2CI - PhCCl : CH.CQ2H.
kAXlO*-1.14; diminishes on diln.; k (203)-1.14, (812) = 1.00;
m. p. 110.5*"; 1299; quoted in 1683.
P-Chlorodimamic add. (Phenyl-a-chloroacrylic acid).
C9H7O2CI- PhCH : CCI.CO2H.
kAXlO»-1.05; diminishes on diln.; k (273) = 1.05, (1892)-0.087;
m. p. 139*"; 1299; quoted in 1683.
ff-ChlorodnnamIc add. (^Chloro*t8o-cinnamic acid). C9H7O2CI.
kAX 10^=2.75; diminishes on dihi.; k (342) -2.75, (1368)-2.67;
m. p. 132.5*"; 1299; quoted in 1683.
oOcH/S-Clilorodnnamic add. (jS-Chlorocinnamic acid). C9H7O2CI.
kAXlO*-2.82; diminishes on dUn.; k(707)=2.82, (1414)-2.75;
m. p. 143*"; 1299; quoted in 1683.
a-Chlorocrotonic add. C4H6O2CI- MeCH : CCI.CO2H.
kA X 10* at 25**- 7.2; increases on diln.
A(32)-49.7, (1024)-203.7, («)=357; 1371.
/3-Chlorocrotonic add. C4H602C1- MeCCl : CH.CQ2H.
kAXlO* at 25*^-1.44.
A(32)-23.4, (1024)-113.4, (oo)-357; 1371.
Na.A at 25% A(32)-68.2, (1024)-78.8; 1368a.
a-Chloro-iso-crotonic acid. C4H6O2CI- MeCH: CCI.CO2H.
kAXlO* at 25*^-1.58; 1371, 1368.
102 TABLES [CU
A(32)-71.6, (1024)-250.7, (a>)-357; 1871.
Na.A at 25^ A(32)=68.4, (1024)=79.2; 1868a.
/S-Chloro-iso-crotonic add. C4Hfi02Cl« MeCCl : CH.COkH.
kx X 10' at 25''»9.47; increases on diln.
A(32) = 19, (1024) -95.7, (oo)-357; 1371.
Na.A at 25°, A(32) = 68.4, (1024) -78.9; 1368a.
Chloro-dibromo-acetic add. C2HOkClBr2»CClBi^.C02H.
kx X 10 at 25"^ is about 3.
A(32)=318.6, (1024)=351, (oo)=353.8.
Na.A at 25^ A(32)=68.1, (1024)=78.2; 1701.
Chloro-difluoro-acetic add. C2H02ClF2-CClFs.COftH.
At 25^ A(32)- 379.8, (256) -391.0; m. p. 22.9^
Na.Aat25^ A(32)-83.0, (64)-86.3, (a>)-96.3; 1690.
m-Cbloro-dimethyl-aniline. C8H10NCl-Cl.C6H4.NMe2.
Weaker base than dimethyl-aniline, (hydrol. of B.HCl); 660.
Chloroethyl alcohol see Glycol chlorohydrin.
Chloroform see Tiichloro-methane.
Chloro-formic add ethyl ester. (Chlorocarbonic acid ethyl ester).
C8H50ftCl-ClCQ2Et.
In SO2; 1842.
Effect of temperature on cond. ; 106.
2-Chlorogallic add ethyl ester. (3,4,5-Trihydroxy-2-chloro-benzoic
acid ethyl ester).
C9H905Cl-Cl.CeH(OH),.C02Et. [C02H- l.J
kxXlO^ at 25*^-1.8; m. p. 106*'-107^
/i(24.2)-0.7, (193.6) -2.5, (00) =350; 404.
2-Chlorogallic acid methyl ester. (3,4,5-Trihydroxy-2-chloro-benzoic
acid methyl ester). CgHyOjCl.
kxXlO^ at 25*^-3.6; diminishes on diln.; m. p. 159M60^
/i(32)-1.2, (256) -2.7, (oo)=351; 404.
Chlorohydrin. C3H7Q2C1-CH2C1.CH(0H).CH20H.
xXlO' at 25*^-4.9.
Cond. with Cu oleate; and as solvent; 1569.
Chlorohydrozy- see Hydrozy-chloro-
Chloromaleic acid. C4H8O4CI.
InS()2, insoL; 1842.
Chloromalonic add. C8H804C1-C1CH(C02H)2.
kx X 10^ at 25** is about 4; m. p. 132* dec; 1888.
Second kxX 10*- 1.94 (cond.); 1911.
At 25^ M(32)-236, (1024)-411, («)=358; 1838.
Chloromethyl- see Methylchloro-
Chloronaphthophenazonium see Chlorophenylnaphthophenazonium.
Chloronitro- see Nitrochloro-
CU] TABLES 108
o-Chloro-oxanilic add. (Anilinochloro-oxalic acid. Chloroanilino-
oxaUc acid). CgHeOsNCl-CQjH.CO.NHCCeaCl).
kA X 10* at 25*'=2.03; diminishes on diln.
m(32) = 191.9, (1024)=334.8, («)=351; 1371.
p-Chloro-oxanlHc acid. CsHeOsNCl.
kx X 10* at 25**= 1.4; increases on diln.
m(256)- 285.8, (1024) =330.0, (a>)«351; 1371.
o-Chlorophenol. CeHsOCl^ CI.C6H4.OH.
kAX 101® at 25^=7.7 (catal.); 1160 and 733, 1718;=360 (cond.);
70.
A(40.6)=0.4, (324.8) = 1.6, (a>)=356; 70.
Cond. in Et ale.
Cond. with NaOH; 1608, 1718.
Na.A at 25°, A(32) = 72.0, (1024) =88.7 aq.; 733.
p-Chlorophenol. C^HsOCl.
kAX 10^0 at 25*^=4.1 (catal); 1160 and 733, 1718;=210; 70.
A(64)=0.4, (512)=2.3, (oo)=:356; 70.
Cond. in Et ale.
Cond. with NaOH; 1608, 1718.
Chlorophenophenazomum see Chlorophenylphenazonium.
G-Chloro-o-N-phenylnaphthophenazoxiium hydroxide. C22H15ON2CI.
This compound, not isolated, exists in the solution of rosindone +
INaOH. At 0% m(512) = 110 after two minutes.
B.Cl=CsaHi4N2Cl2 (Rosindone chloride) at 25**, m(32) = 124.5 ex-
trapolated, (1024) = 138.8. Cond. with NaOH; 770.
nonn.-p-Chlorophenyl-nitromethaiie. C7H602NC1= CI.C6H4.CH2.NO2.
In 50% Me ale. at 1.1°, very small cond.; m. p. 33°-34°.
E salt and Na salt; 1464.
iso-p-Chlorophenyl-nitromethane. C7H6O2NCI.
In 50% Me ale, conducts well, but becomes transformed to the
normal compound; m. p. 64*^.
Na salt; 1464.
3-Cliloro-N-phenylphenazoiiium bromide. (Chloro-N-phenophenazo-
nium bromide). Ci8Hi2N2ClBr.
m(64)=82.8, (1024) = 101.1; 770.
4-Chloro-o-phthaUc add. C8Hb04C1=C1.C6H8(C02H)2. [C02H=1, 2.]
kx X 10^ at 25*^=2.5; extrapolated on account of great dissociation
at small diln.
m(64)=259, (1024)=446, (a>)=356; 1372.
Chloropicrin see Nitrotrichloro-methaiie.
a-Chloropropicnic add. C8H602C1= Me.CHCl.COaH.
kA X 10* at 25**= 1.6; diminishes on diln.; b. p. 82.5** @ 13.5 mm.
A(32)-71.6, (1024)= 237.2, (c»)«358; 1099.
104 TABLES [Chi
/3-CUoropropiomc add. CsHsOkCl- CH2Cl.CH2.COkH.
kx X 10^ at 25° » 8.6; increases, then diminishes on diln.; m. p. 40°.
A(32) = 18.3, (1024)=:89.1, (oo) = 358; 1099.
Chloro-salicylic acid see 2-Hydrozy-chlorobenzoic add.
o-Chlorosucdnanilic add. (Anilinochlorosuccinic add. Chloroanili-
nosucdnic add).
CioHio08NCl«C04H.C2H4.CONH(C6H4Cl).
kx X 10* at 25° =2.1; slight increase on diln.
m(128) = 17.7, (1024)=47.6, (a>)=350; 1372.
m-Chloro8uccinanilic add. CioHioOsNCl.
kx X lO'^ at 25°= 2. 1; slight increase on diln.
/i(128) = 17.4, (1024)=47.2, (oo)=350; 1372.
p-Chlorosucdnanilic add. CioHioOsNCl.
kx X 10' at 25°«2.1; slight increase on diln.
m(128) = 17.3, (1024)=47.9, (oo)=350; 1372.
tnart.-Chlorosuccimc add. C4H604C1* CO4H.CHCI.CH2.CQ2H.
kxXlO» at 25°=2.94; m. p. 153°-154°; 1824, 1838.
Second kxXlO*=3.6 (cond.); 1911.
At 25°, m(32)=92.2, (1024)-294, (a)=356; 1838.
d-Chlorosacdnic acid. C4H5O4CI.
kx X 10» at 25°= 2.94; m. p. 176°; 1824.
l-Chlorosuccinic add. C4H5O4CI.
kxXlO»at25°=2.94; m. p. 176°; 1824.
p-Chlorotoluene. C7H7CI.
In NHs, qual. ; 806.
/3-Chloro-trimethylene diamine. C8H9N2C1= CHC1(CH2.NH2)2.
B.2HC1 at 25°, A(32) = 106.9, (1024) = 127.8; 270.
6-Chlorovaleric add. CbH»02C1 = CH2CI. (CH2)8.CQ2H.
kxX 10* at 25°=2; b. p. 141°-149° @ 12 mm. with dec.
A(32)=9, (1024)=47.8, (oo)=354; 1099.
Chromicyanic acid. CcHsNeCr = HsCrCCN)^.
3K.A at 25°, A(32) = 130.5, (1024) = 160.8; 1837.
Chromioxalic add. CeHsOuCr = H3Cr(C204)s.
3NH4.A; 1192, 1198, 1616. - 3K.A; 971, 1616, 1616. - 3Ag.A;
971. -3Na.A at 25°, A(32) = 73.2, (1024) = 105.6; 1616,
1192, 1198.
Chromithiocyanic add. CeHsNeSeCr = HsCr (CNS)6.
3NH4.A; compound with acetic add; 1164. - 3E.A; 1192, 1641.
- 3 Na.A at 25°, A(20)=265, (1280)=344; 1192.- Com-
pound with urea; 1944.
Chromium see Chromicyanic acid, Chromioxalic acid, Chromithiocya-
nic add and Chromimn complex salts.
Chromium complex salts.
320b, 1164, 1384, 1487, 1616, 1616, 1673, 1641, 1944.
On] TABLES 105
aflo-Chrysoketonecarbozylic acid. CisHioOs.
Comparative strength (colorim.); m. p. 285*'-286® with dec;
1666.
oOo-Chiysoketonecarbozylic acid ethyl ester. CtoHuOg.
Comparative strength; m. p. 187**-188*'; 1666.
Chrysophenine. A salt of StUbenedisulphoiiic acid disazophenol
mono ethyl ether. '
C8Ha08N4S2K2- OH.C6H4.N2.C6H8(SOsK).CH : CH.C5H8
(SOsK).N2.C«H40Et.
At 90^ m(200)=424, (1600) -512; 976a.
Chyle. [The references to this are incomplete. ]
Cond.; 263.
Cinchomeronic add see P3rridine-3,4-dicarbozylic acid.
iso-Cinchomeronic add see Pyridine-2,5-dicarbozylic add.
Cinchona. [The references to this are incomplete. ]
Cond. of dil. soln. of bark; 146.
Cinchonamine. Ci9Hi40N2.
ks X lO' at 15*^ is less than 1 (colorim.).
Second ks X 10*® is about 3 (colorim.); 1776.
Cinchonidine. C19H22ON2.
kaXlfl' at 15^=3.72 (hydro!.); 1779.
Second ks X 10*® is about 3.3 (colorim.); 1776.
In NH3, qual.; 606.
With allyl thiocarbimide, no cond.; 1223. Relative strength;
1631.
B.HCl at 25^ A(32)=76.9, (1024) =91.1; 2Y0. - 2B.HaS04; 1611.
Cinchoiiiiie. CisHsaONa.
kBXlO« at 15*^=0.16 (hydrol.); 1779. At 18^-1.2; 1224.
Second ka X 10*® is about 3.3 (colorim.); 1776.
At 18^ m(14020)-24, (oo) = l94; 1224.
Cond. with acids and phenols in Me ale. and acetone; 1620.
B.HCl at 25^ A(64)=82.1, (1024) = 90.9; 270; 177, 1224. Salts
of organic acids; 1620.
Cinchoninic add. (Quinoline-4-carboxylic acid. 7-Quinoline car-
boxylic acid). CioH7Q2N=C6H4.C8H2N.CQ2H.
kAX 10* at 25**= 1.3.
/i(64)=9.9, (1024)=37.2, («)=355; 1372.
Cinenic see Cineolenic.
Cineole. (Eucalyptole). CioHisO.
At 22^, almost no cond. With HCl, shows almost complete
hydrolysis; 1653.
Cineolenic add. (Cinenic acid). CgHieOs^CgHisO.CC^H.
(a). Acid; m. p. 83**-84^. At 18^ m(32)=52.2, (1024)=62.5;
[this apparently means the conductivity of a salt]; 1544.
106 TABLES [Cin
(6). fi-stabile Acid; b. p. 124.5**-125*' ® 12 mm. At 20^ /x(32) =
62.1, (1024) s 73.5; [this apparently means the conductivity
of a salt]; 1546.
CineoHc add. CioHuOs^ CsHuO.CCOkH)!.
kxXlO* at 25^=1.17 aq.
/i(32)=20.6, (1024) = 102, (oo)=350.
Cond. with boric acid; 1186.
At IS'', iu(32)» 125.1, (1024) » 146.4; [this apparently means the
conductivity of a salt]; 1644.
Cinnamenyl- see Styryl-
Cinnamic add. (jS-Phenylacrylicacid). C9H802=Ph.CH:CH.C02H.
kAXlO*atO*'-3.2. At 5.2** =3.4; 1968a. At 18*^=3.5 (colorim.);
1563, 1781. At 25*'-=3.6; 507, 1371, 1581, 1968, 1968a. At
•>*35**- 3.7; 1968a. At 40^=4.1 aq. At 50** =4.0 aq. At 60**=
4.0 aq. At 70^=3.8 aq. At 80**=3.7 aq. At 90^=3.4 aq.
At 99° =3.2 aq.; 1581. See also the isomeric cinnamic acids.
Cond. at 0**-35^ 1968, 1968a, 1581. At 25^ A(256)=32.2,
(1024) = 61.3, (oo)=:352; 1371.
In HCl, good cond.; in HBr, slight cond.; 30. In HON, no
cond.; 943. In NHsi qual.; 606. In pyridine; 754.
Na.A at 25^ A(32)=64.3, (1024) -73,8; 1368a; also 1275,
1968a. At 25^-99^ 1581.
Cinnamic add ethyl ester. C11H12O2.
Effect of temperature on cond. ; 106.
Isomeric cinnamic adds.
Erlenmeyer has found four isomeric acids which (according to
their 'source) are grouped in two pairs, the storax and the
hetero acids. See 507 and Ber. Deutsch. Chem. Ges. 43,
■ 453, 955 and 1076.
(«)
374.7.
374.7.
374.7.
374.7;
507.
oSo- and tso-Cinnamic adds. There is, at present, an agreement that
there are three isomeric forms of m. p. 42°, 58° and 68°, and
that any one of these may be transformed into any one of
the other isomers having a different melting-point. See Ber.
Deutsch. Chem. Ges.; 34, 3641; 36, 901; 38, 2562, 3496;
39, 1570; 42, 182, 521, 1027, 1443, 4659, 4865; 43, 411; 44,
2739, 2966. The acids which were first prepared often con-
tained some cinnamic acid, giving too high conductivity
values.
At 25°
m. p.
kxXlO*
A(320)
(1269)
Storax a-add.
134°-135°.
3.62.
38.2
72.9
Storax /3-add.
132°-133°.
3.70.
38.8
77.5
Hetero a-add.
130°-131°.
3.50.
37.6
72.2
Hetero /3-add.
128°.
3.59.
38.1
71.8
atl TABLES 107
Isomer m. p. 42**. The iso-acid of Erlenmeyer, Sr.
IcaXIO* at 25^-1.38; 179a, 1103, 1106. A(ol.l)=30.3, (511)=
87.6, ( 00) =374; 17»a.
Isomer m. p. 58^. The iso-acid of Liebermann.
kA X 10* at 25** = 1.41 ; 179a ; 70, 1102, 1106, 137S. A(50.6) - 30.3,
(506) « 87.7, ( 00) -374; 179a.
Isomer m. p. 68**; aUo-ciD.nsjmc acid.
kAXlO* at 25**= 1.42; 179a, 1103, 1106. A(50.3)=30.5, (50o) =
87.7, ( 00) =374; 179a.
Cinnamic alcohol. C9H10O.
In NHs, qual.; 606.
Cinnamic aldehyde. C9H80»Ph.CH:CH.CHO.
X is too small to measure; 1663.
In NHs, qual. ; 606.
Cond. with HCl, qual.; 1663. Compound with HaSOg; (hydroL);
961.
Cinnamon. [The references to this are incomplete. ]
Cond. of dil. soln. of bark; 146.
Cinnamyl chloride. CjHtOCI- Ph.CH : CH.COCl.
In SO2; 1842.
Citraconanilic acid. (Mesaconanilic acid. Methylmaleinanilic acid).
CuHuQsN.
NH4.A, A(33.0)-63.2, (1057)=76.2; m. p. 65**-80** with dec;
(free acid has m. p. 151**-153^); 1749.
Citraconic add. CfiH604» CO2H.CH : CMe.CC^H.
kAXl0'at0''»4.36; 1968a ;» 3.69 aq.; diminishes on diln.; 1018.
At 12*^=4.07; 1968a. At 17**=3.61 aq.; diminishes on diln.;
164. At 18^=3.7 (colorim.); 1663, 1781. At 25°=3.81;
1968a;»3.44; diminishes on diln.; 1372; 1600b. At 35^»
3.63; 1968a.
Second kx X 10'«3.9 (inversion); 1336 and 1746;»2.4 (inversion);
1638.
At 25**, /i(68.3) = 135.0, (1092)-288.0, (oo)=355; 1372. Also,
170, 1600b. m(32)» 103.0, (1024) » 289.1; 1968a.
In NHsi qual.; 606.
Cond. with KOH; 170.
K.A; 170. - 2Na.A at 25^ /i(32)=77.7, (1024) -96.6; 1867,
1838. - NaH.A; 1838.
Citraconic add anhydride. C6H4C)8.
X X lO' at 0^=0.958. At 25*'=2.02; 1844, 1843.
As solvent of NEtJ; 1844. Cond. of soln. showing change to
add; 1600b.
Citric add. CeH«07-CO»H.CH2.C(OH)(C02H).CH,.C02H.
kxXlO* at 0^-6.9. At 18.1^-8.4; 1968a. At 18.5^=7.9 aq.;
108 TABLES [CU
164. At 25°-8.2; m. p. 152*»-154**; 1839, 1869;-8.7;
1968a; (colorim.); 1648. At35^«9.1; 1968a.
Second IcaX 10*=3.2 (inversion); 1638.
Third Ica X 10'«7.0 (inversion); 1638.
Cond.; 172, 454, 591, 691, 692, 910, 1122, 1248, 1495, 1968a.
At 25^ m(64)=71.9, (1024)=212, («)=352; 1839. m(32) =
52.7, (1024) = 218.1, (c»)=345; 1968a.
In HBr and in HCl, no cond.; 30. In NHsj qual.; 606. In ether,
no cond.; 366.
Cond. with boric acid; 1839; qual.; 1184. With MoOs; 691,
1495. With KOH; 172. With NaOH; 454. Under pres-
sure of 1-500 atmospheres; 220. E. m. f.; 1639b.
2Mg.3A; 1836. - Acid K salt; 164. 3K.A at OMOO^; 1338 and
889; also, 164, 172, 495, 588. Under pressure of 1-500 atmos-
pheres; 220. - Na.A. - 2Na.A. - 3Na.A at 25°, /i(32)=81,
(1024) -109; 1838. 454, 1199, 1367. With boric acid; 1199.
Complex with MoOs and WOs; 692. With NaCl and NaOH;
1227. With UO^.A; 449. - 3U0|.2A alone, and with 3Na.A;
449.
Citric acid triethyl ester. C12H20O7.
In NHs, qual.; 606.
Citronella aldehyde see Citronellal.
Citronellal. (Citronella aldehyde). CioHisO.
Compound with H2SO8; (hydroL); 961.
Citronellideneacetic acid. C12H20O1.
The acid (a mixture of isomers) was too insol. to measure cond.;
1545.
Clupeine. CsoHstOsNi?.
B. Carbonate shows an increase of cond. after digestion with
trypsin; 145b.
Cobalt.
In complex salts. With dimethyl-glyoxime; 1751, 1753, 1754,
1766, 1757, 1759, 1760a, 1761. With ethyl amine; 1751,
1757. With ethylene diamine; 1415, 1417, 1948, 1949.
With methylethyl glyoxime; 1759. With pyridine; 1481,
1482, 1751, 1757, 1760a. See also 1384, 1385, 1481, 1526,
1947.
See also the following compounds.
Cobalticyanic acid. C«H8N6Co= H8Co(CN)«.
3K.A at 25^ A(32)= 121.5, (1024) = 151.4; 1832, 971.
Cobaltophenyltfaioacetic acid. C16H14O4SSC0 « Co(S.CHPh.COkH)s.
2Na.A, m(32)-55.1, (1024)-80.6; 1385.
Cobaltothiocyanic add. C4H2N4S4C0 = H2Co(SCN)4.
2NH4.A at 25^ m(32)-39.1, (512)=72.9; 1527.
Con] TABLES 109
Cobaltothiophenyl- see Cobaltophenylthio-
l-Cocaine. (Benzoylecgonine methyl ester). C17H21O4N.
kaX 1(F at 14^ to 18** -4 (colorim.); 1779, 1778.
In HCN, fair cond.; 943.
B.HCl at 25^ A(32)=79.7, (1024)=91.7; 270. In S0»; 1842.
In NHs, qual.; 606. - B.HNOb, in SOi; 1842.
r-Cocaine. Ci7H»i04N.
B.HCl at 25^ A(32)=78.9, (1024) =90.8; 270.
Coddne. CigHuOsN.
In NH», qual.; 606.
B.HCl at 25^ A(32)=78.3, (1024) =91.0; 270.
Coenilein. C^oHioO^; also given as CtoHsOe.
In MeNHs, poor cond.; 637.
CoUidine see 2,4,6-Trimethyl-pyridine.
Cafaimbittin. (Niobium).
Complex with oxalic acid. NH4, E, Rb, and Na salts; 1650.
Comanamic add. (/3-Hydroxy-picolinic acid).
CeH608N-C6H80.NH(CQ2H).
kAXlO*=2.66.
m(64)=46.1, (256)=87.3, (oo)=380; 1407.
Comanic add. (ly4-Pyrone-2-carboxylic acid).
C«H404=C6H8Q2(C04H).
kAXl0*==2.8; m. p. 252^
l*(128)=311, (512)=357.9, (a)=380; 1407.
Comeiuunic add. (Dihydroxy-picolinic acid).
C«H604N - C6H2O (NH) (CO4H) (OH) .
kAXlO*=2.45.
M512) = 112.6, (1024) = 148.5, (a>)-379; 1407.
Comenic add. (l,4-Pyrone-6-hydroxy-2-carboxylic acid).
CeH405- (OH)C6H202(COsH).
kAXl0*=2.
/*( 128) -292.2, (512)=347.6, (oo)=380; 1407.
Condurango. [The references to this are incomplete. ]
Cond. of soln. of bark; 146.
Congo Red.
This is a sodium salt, usually the salt of Benzidine-tetrazo-dinaph-
thylamine-disulphonic acid. C82H24O6N6S2.
Colloidal solution of free acid at 25^, A =5.
Na salt (= Congo Red) at 25**, A(800 to 3200) is about 110; 1402.
A(32)=:58.7, (1024) =96.1; 186a.
d-Coniine. (2-Propyl-hexahydro-pyridine) . CgHnN .
kB X 10» at 25^=1.32 aq.; 16% too high; 271; 1241.
At25^M(32)=36.4, (256)=83.0, («) = 195; 271; 1241, 2014.
110 TABLES [Con
In HCN, very little cond.; 943.
B.HCl at 25% A(32)=84.1, (1024)-94.9; 270.
Conquinine see Quixiidine.
Copper. In complex salts; 1008, 1524, 1530, 1750, 1755.
See also Cupricyanic add and Cuprocyanic add.
Cotarnine. CUH15O4N.
kBXlO»atO**=2; 763. At IS^isover l(hydrol.); 1779. At 25^=
5; diminishes on diln; 763.
At 25% m(128)- 124.2, (1024) = 148.2, (oo)=226; - B.HCl +
AgsO, /i( 128) = 139.5; 763.
B.HC1 at 25% m(32)-86.6, (1024)«96.9; 763, 764. With KCN;
764. - B.CN; 764.
Cotarnine cyanide. CuHuOsNa.
At 25% m(1024)»26.1; also in Et ale; 764.
o-Cotunaric add. (o-Hydroxy-dnnamic add).
CgHsOs" C6H4(OH) .CH : CH.CO^H.
kAX 10' at 25°=2.2; m. p. 208.5^ 1186, 1371.
A(256)-25.3, (1024)=48.2, (a)=352; 1371.
In HBr, no cond.; 30. In Et ale; 1185, 1508, 1718.
Cond. with boric acid; 1185. With NaOH; 1508, 1718.
m-Coumaric add. (m-Hydroxy-cinnamic acid). CsHsQt.
Cond. in Et ale, alone and with NaOH; m. p. 19r; 1508, 1718.
p-Coumaric add. (p-Hydroxy-cinnamic acid). C9H8Qt.
kx X 10' at 25''»2.16; diminishes on diln.
A(128) = 18.1, (1024)=47.9, (oo)=352; 1371.
Coomarin. C9H6O2.
In NHs, qual.; 606.
Creatine see Methylguanidine-acetic add.
Creatinine. (Methylguanidine-acetic acid anhydride?). C4H7ONS.
ksX 10" at 40°=3.69 (sapon.); 1995 and 1150. At 40.2**=3.57
(sapon.); 1995.
o-Cresol. CrHgO = Me.CeBU.OH.
kxX 108 at 25° -4.2.
A(19.3)-0.3, (38.7)=0.5, (oo)=356; 70.
In HBr; 29. In HBr, good cond.; in HCl and HI, poor cond.;
in H2S, no cond.; 1897. In NHs, qual.; 606.
Cond. with NaOH and HCl; 1508.
m-Cresol. CyHsO.
kAXl0«at25°=1.7.
A(20)-0.2, (160)=0.8, (a)=356; 70.
In HBr; 29. In NHs, qual.; 606.
Cond. with NaOH and HCl; 1508. As solvent; 78.
p-Cresol. CrHgO.
kxXlO* at 25*^=1.1.
Cum] TABLES 111
A(28.8)=0.2, (115.2) = 0.5, (a>)=356; 70.
In HBr; 29. In HBr, good cond.; in H2S, no cond.; 1897. In
NHs, qual.; 606.
Cond. with NaOH and HCl; 1608.
Cresotinic add see Hydrozy-toluic add.
Croconic add. CbHsOs » C5OS (0H)3 ?
At25% /i(27.9)« 359.4, (1787.4) =621.1, (oo)=775.
K salt. - Na salt at 25^ /i(32) = 175.5, (1024) -228.^; 389.
a-Crotonic add. C4H60i= Me.CH : CH.CO4H.
kAX 10* at 0*^=1.99. At 12^=2.10. At 25^-2.15; 1968a;«2.04;
1184, 1371; (colorim.); 951, 1781. At 35^=2.11; 1968a.
At 25^ A(32)=8.9, (1024)=47.5, (a>)=357; 1371. A(32)=9.1,
(1024)=48.0, (a>)=352; 1968a.
Cond. of satd. soln.; 943. At 0*" to 35''; 1968a.
In HCN, little cond.; 943. In NHs, qual.; 606.
Cond. with boric acid; 1184.
Gl complex salt; 1711. - Na.Aat25^ A(32)=69.0, (1024)=78.8;
1368a; 1640, 1968a.
/M^rotonic add. (iso-Crotonic acid). C4H6O2" Me.CH: CH.CO2H.
IeaX 10* at 25^=3.6; diminishes on diln. because of presence of
a-crotonic acid.
At25% A(32) = 11.3, (1024)=55.5, («>)=357; 1371.
Gl complex salt; 1711. - Na.A at 25^ A(32)=69.3, (1024)=78.9;
1368a.
Crystal Ponceau. (Crystal Scarlet 6 R. Ponceau 6 R) . C20H14O7N2SS.
The dye is the disodium salt of a-Naphthalene-azo-j3-naphthol-
disulphonic acid. CioH7.N2.CioH4(OH)(S08H)2.
Free acid at 25% /i(100)= 344.7, (1600)-368.1; 1402; - 1401.
Mg.A. - 2Na.A (Ponceau) at 25% /ti( 100) =82.4, (1600)«89.2;
1402. Cond. with Methylene Blue; 1401.
Ciystal Scarlet see Crystal Ponceau.
Crystal l^olet see Hezamethyl-triamino-triphenyl carbinol.
Cubelnn. CioHioOs.
In NHs, qual.; 606.
Cumaric see Coumaric.
Cumene. CgHu^ Me2CH.Ph.
xXlO" at 18*^=6; 386.
In HBr, no cond.; 1897. In NHs, insoL; 606.
Cond. with m-xylene; 386.
^^eittfo-Cumenecarbozylic add see 2,4,5-Tiimethyl-benzoic add.
j^eifcfo-Cumene diazonium hydroxide. (Diazo pseudo-cnmene).
C9Hi20N2= Me8.C6H2.N2.OH. [Me= 1, 2, 4. ]
At 0^ M128) = 107, (00) = 135; 601.
B.Cl. - B.CN at 0^ m(512)-50.6; 736.
112 TABLES [Cum
^^eiMfo-Cttmenesalphone-aininoacetic add. (pseticto-Cumenesulphoiie-
glycine). CuHuOiNS- (MeB.CeH,.SOi)NH.CHa.CO|H.
kxXlO* [at 25^1-2.48.
A(266)-77.1, (1024) = 135.1, («)-347.
Na.A [at 25**], A(32)«59.6, (1024)=68.3; 1184.
2-^eiMfo-Ctimene-5-8ulphoiiic add. (l,2,4-Trimethyl-ben2ene-5-Bul-
phonic acid). CsHuOsS^ Mes.CeHa.SOsH.
At25VA(32)-319.5, (1024)-362.6; 1866.
K.A; 1366. - Ag.A; 1111. - Na.A at 25^ A(32)-62.5, (1024)-
75.2; 1866.
Ciimic add see Cuxninic add.
<ym.-^5eiMfo-Cumidine. CsHuN-Mes.CeHs.NHt. [Me-1, 2, 4;
NH2-5.I
kBXlO» at 18*'-4.8 (colorim.); 1777. At 25**- 1.72 (solub.);
1116.
In benzene, no cond.; 1602.
B.HCl at 25^ A(64)-89.1, (256)-93.7; 270. Effect of diazoti-
zation; 1601. - B.Picrate in benzene, no cond.; 1602.
Cuxninic add. (Cumic acid. p^o-Propylbenzoic acid).
CioHi204=i«>-Pr.C6H4.CO|H.
kAX 10* at 18*^-3.35 (colorim.); 1668. At25**=5; 1871.
At25^ A(512)=52.2, (1024) =70.9, («)-350; 1871.
Cumophenolcarbozylic add.
CioHtt08=C8H7.CeH8(OH).COsH. [COaH-l; OH-6;
C8H7-3.I
kA X 10^ at 25*"- 7.38 aq.; diminishes on diln.; m. p. 121.5^
/ti(800) = 185, (1600) -225, (a)=350.
Cond. with boric acid; 1186.
Cupricyanic add. C8H2N8Cu-2HCN.CuCN.
2Na.A at 25% /ti(32) - 102.7, (1024) = 117.2; 690.
Cuprocyanic add. C4H8N4Cu = 3HCN.CuCN.
3K.A. - 3Na.A at 25% m(32)- 108.2, (1024) -128.8; 690.
Cyan- see Cyano- for most compounds.
Cyanic add. CHON-NC.OH.
kxX 10* at 0^=1.2; 1809a.
NH4.A; 662, 1886. - K.A at 18% A(100)-109.4, (1000)-121.2;
1809a. Cond. of satd. soln.; and cond. in HCN; 948. In
NHa, qual.; 606. - Ag.A in HCN, qual.; 948.
Cyanine. C29HS6N2I or C80H89N2I.
keXlO* at 18*^=4.2 (colorim.); 1662.
In HCN, no cond.; 948. In Et ale, cond. increased by light;
1821.
Cyanoacetlc add. CaH802N=CH2(CN).C04H.
kxXlO^at 25*^=3.73; diminishes on diln. ; 1870; (neutral.); 296.
CyiJ TABLES 113
Cond. of Batd. 8oln.; 943. At 25% A(32)- 105.3, (1024) » 297.3,
(oo)-362; 1370.-294.
In HCl, poor cond.; in HBr and H2S, no cond.; 1897. In HON;
943. In Et ale; 647, 1820. In acetone and in soln. of
sugar; 1820.
Cond. with acetic acid; 1821. With KOH; 294.
Na.A in ale; 647. - K.A; 294.
Cymnoacetic add amide. (Gyanoacetamide).
C»H40N2=CH2(CN).CONH».
In NHs; 610.
Cond. with HgCU; 1097.
Cyanoacetic add ethyl ester. C5H702N-CHs(CN).C02Et.
X X lO' at 0**«1.9; 1844. At 25**=3.6; b. p. QS'^-QQ*' ® 18 mm.;
1106, 1107, 1843, 1844.
At25% A(250)-0.45, (500)=0.51; 1831.
Cond. as solvent; 1106, 1107, 1844.
Cyanoacetic add methyl ester. C4H6O2N.
xXlO' at -51^=0.2. At -31**=1.0; 1863a. At 0^-3.17; 1844,
1853a. At 25''-= 4.49; b. p. about 202*'; 1843, 1844, 1853a.
At 25% A(32)=0.31, (64)-0.38; 698.
As solvent; 1844, 1853a.
Cyanoacetoacetic add iso-amyl ester.
CioHuQiN=MeCO.CH(CN).CQ2C6Hu.
kxX 10* at 25*'-5.8; b. p. 168** (S^ 46 mm.
A(1024) = 185.3, (oo)=351.
Na.A at 25^ A(1024-32) = 10-12; 699.
Cyanoacetoacetic add iso-butyl ester. CgHuOsN.
kxXlO* at 25''»7; diminishes on diln.; b. p. 142"" @ 32 mm.;
699.
A(512)- 155.5, (1024) = 190.5, (») = 352; 699.
Na.A at 25% A(32)=65.3 (1024) = 77.3; 700; - 699.
Cyanoacetoacetic add ethyl ester. C7H9O8N.
kx X 10* at 25^»6.5; diminishes on diln.
A(64)=65.1, (1024) = 181.4, («) = 353.
Na.A at 25% A(32)=63.6, (1024) =74.4; 698.
Cyanoacetoacetic add methyl ester. CsHtOsN.
kx X 10* at 25^=8.5; diminishes on diln.
A(64) = 73.4, (1024) -200.0, (a>)-356.
Na.A at 25% A(32) = 65.6, (1024) -78.1; 698, 700.
Cyanoacetoacetic add propyl ester. CsHuOsN.
kxX 10* at 25'' =5.9; diminishes on diln.; m. p. 35''-36^
A(128)=84.4, (1024) = 180.4, (a>)-352; 699.
Na.Aat25% A(32)=65.7, (1024)-78.3; 700; 699.
114 TABLES ICya
Cyanoamide. CHsNs- CN.NHt.
Aq. soln., almost no cond.; 70.
In NHs; 610.
B.2HC1 at 25^ m(30)=743; 779.
Cyanoaminocarbonic add ethyl ester. C4H60sN2"(CN)NH.COkEt.
kxX 10* at 25^=4.7.
A(49.6)=50.8, (793.6) = 157.7, (a>)-352; 70.
K.A. - Na.A at 25^ A(32)=70.4, (1024)=79.4; 270.
m-Cyanobenzoic add. C8H502N«CN.C6H4.C0|H.
kAXlO* at 25*^=1.99.
A(133.3) = 52.9, (1066.7) = 129.5, (»)«354; 1371.
Cyanobenzoylacetic add methyl ester.
CiiH90iN-PhCO.CH(CN).C02Me.
Na.A at 25% A(32)=63.0, (1024)=75.0; 700.
Cyanobutyrylacetic add methyl ester.
CsHuObN- C8H7CO.CH(CN) .CQ2Me.
kxX 10* at 25^ » 6.3; diminishes on diln.; b. p. 135.3"" @ 25 mm.
A(128)=86.6, (1024) = 184.0, (a>)=351; 699.
Na.A at 25% A(32)=:65.2, (1024) =77.8; 700, 699.
Cyano-fio-butyrylacetic add methyl ester. CsHuOsN. /
kA X 10* at 25**= 5.0; b. p. 139** @ 48 mm.
A(512)- 138.7, (1024) » 178.0, (oo) = 351; 699.
Na.A at 25% A(32) = 64.8, (1024) =77.8; 700, 699.
Cyanoform. (wo-Cyanoform. Tricyano-methane). C4HN8=HC(CN)8.
At 25% m(64) = 346.5, (1024) =358.3.
Na.A at 25% /i(64)-81.6, (1024)=87.5; 769.
Cyanoformylacetic add methyl ester. (Hydroxymethylene-cyanoace-
tic add methyl ester). C6H608N=CHOH:C(CN).COsMe.
kx X 10^ at 25**= 1.56; diminishes on diln.
A(32) = 188.6, (1024)=321.5, (a>) = 378.0; m. p. 136M37^
Na.A at 25% A(32) = 74.4, (1024) =86.4; 226.
Cyanogen. (Dicyanogen. Oxalic add nitrile.) C2N2=NC.CN.
X X 10> at 0"* is less than 7; 367, 369.
Cond. in aq.; 1309a.
Cyanogen iodide. CNI.
Cond. with allyl thiocarbimide; 1223.
Cyanomalonic add diethyl ester. C8H11O4N « CH(CN) . (CQ2Et)2.
kAXlO«at25**=3.7.
m(64)=265.3, (1024)=331.8, (oo)«350; 698.
Na.A at 25% m(32)=59.9, (1024)=72.0; 698, 700.
«
Cyanonitrosoacetic add. (Cyanoketoxime-carboxylic add. Cyano-
oximinoacetic add). C8H208N2=CN.C(N.OH).CO»H.
kA X 10^ at 25^= 1.39; diminishes on diln.
m(32) = 174.2, (512)-321.4, (oo)=363; 768.
Cyc] TABLES 116
Cyanonitrosoacetic acid ethyl ester. C5H608N2»CN.C(N.OH).CQ2Et.
kxX lO'^ at 25^=2.28; m. p. 128^-129^ 1296, 1390.
At 25^ A*(32) = 10.1, (1024)-53.4, (oo)=380.6; 1296.
In Me ale; 1390. In pyridine; 754.
Na. A at 25^ /x(64) » 76.7, (1024) » 82.9; 1296. In Me ale. ; 1390.
__ «
Cyanonitrosoacetic add methyl ester. C4H4QtN3.
kAXlO* at 0^=1.32 aq. At 18^=2.21 aq.; 1296. At 25^=3.16
(extrapolated); m. p. 119^ 1296;»2.61 aq.; 1296. At 35''-
3.08 aq. At 40''»3.24 aq.; 1296.
At 25^ m(32)-11.9, (1024)-59.5, («)=383.4; 1296. -
Na.A at 26% /i(32)=74.8; 1296. iiA(64)-78.1, (1024)«85.6;
1296.
Cyanonitrosoacetic add propyl ester. CeHsQsNa.
kAX 10* at 25^=2.3; m. p. 106°-107^
/i(64) = 14.2, (1024)=63, («>)=377.5.
Na.A at 25% /i(128)=76.0, (1024)=79.5; 1296.
Cyanooximinoacetic add see Cyanonitrosoacetic add.
p-Cyano phenol. (p-Hydroxy-benzonitrile) . CtHsON = CN.C8H4.OH.
kA X 108 at 0** is less than 3 aq. ; 733. At 25**= 1.3 (catal.) ; 1160,
733;=6 aq.; 733. At 35^=8 aq.; 733.
At 25% A(32)=0.5, (256) = 1.3, (a>)=356; 733.
Na.A at 25% A(32)=66.3, (1024) =78.0 aq.; 738.
Cyanopropionylacetic add methyl ester.
C7H908N=EtCO.CH(CN).C04Me.
kAXlO* at 25'*=7.5; diminishes on diln.; m. p. 39*'-40%
A(256) = 122.2, (1024) = 190.5, (a)=352; 699.
Na.A at 25% A(32)=67.0, (1024)=78.9; 700, 699.
Cyanotoluene see Tolunitrile.
Cyano-jisa-valerylacetic add methyl ester.
C9Hi,QsN=Me2CH.CH2.CO.CH(CN).C02Me.
kAXlO* at 25^=7; 700.
Cyanuric add. (iso-Cyanuric acid). CsHsQsNs.
kAXlO^ at 25*^=1.8; 742;=3.8; 70.
At 0% m(64)=0.66; 1428. At 25% /ti(128) = 1.7, (1024)=5.1; 742.
m(32) at 70^=2.6; at 80^=2.8; at 90^=3.9; at 96.2'' =4.2;
1428. At 30*^-63% 742.
In NHs, qual.; 606. In p3rridine; 764.
Hg.A, e. m. f.; 963. - 2 Na.A at 25'', m(32)= 176.5, (512) =249.2.
3 Na.A at 25% m(32)=396, (512) =485; 742, 1428.
Cyanuric add N-dimethyl ester. (Dimethyl-cyanuric acid).
CjHTOiNg.
At 25% /ti[(64)?I=0.26; m. p. 222% 1428.
Cyclobtttane-carbozylic add see Tetramethylene-carbozylic add.
116 TABLES ICyc
Cydoheptane-carbozylic add. (Suberane carboxylic acid). CsHuOs.
kxXlO' [at 26^1=1.22.
A(240.6) = 18.5, (962.4) = 35.7, (a)»352; 2026.
Cydoheptatriene-carbozylic add see tso-Phenylacetic add.
1-Cydoheptene-l-carbozylic add. (Suberene carboxylic acid).
C8Hi202*
kAXlO* at 25^=9.92 aq.; 1633;=8.3; (m. p. of amide is 134^-
135**); 1976.
A(256) = 16.9, (1024)=33.2, (oo)«375; 1976.
2-Cyclohepteiie-l-carbozylic add. CsHuC^.
kxXlO* at 25^=2.7 aq.; m. p. 18^-20^
A(63.9)-15.3, (256.6)-29.9, (oo)=l375]; 1633.
Cyclohezane-acetic add. (Hexahydro-phenyl acetic acid).
C8Hi402== CeHu.CHs.COiH.
kAXlO* [at 25**] =2.36.
A(186.6)-28.4, (1173.1)=60.1, (oo)=352; 2026.
Cyclohezane-carbozylic add see Hezahydro-benzoic add.
Cyclohezane-propionic add. (jS-Hexahydro-phenyl propionic acid).
CgHieOs™ C6H11.CH2.CH2.CO1H.
kAXlO* [at 25^1-1.34.
A(185) = 17.1, (1480)=46.2, (oo) = 352; 2026.
Cyclohezene-acetic acid. Liquid isomer. C8H12O2.
kAXlO*^ [at 25**] =2.60; 2026.
Cydohezene-acetic add. Solid isomer. CsHuC^.
kA X 10* [at 25**] =2.49; m. p. 38^
A(52.2) = 12.6, (835.5)=47.4, (a>)=:352; 2026.
Cyclopentane-carbozylic add see Pentamethylene-carbozylic add.
Cyclopentane-dicarbozylic add see Pentamelliylene-dicarbozylic acid.
Cyclopropane-carbozylic add see Trimethylene-carbozylic acid.
Cymene. CioHw* Me.C6H4.CHMe2.
X X 108 at 25* is less than 2; b. p. 167*'-169* ® 740.2 mm.
In HBr, HCl and HjS, no cond. ; 147a.
Cond. with other compounds; 1388.
Cytisine. C11H14ON2.
Cond.; m. p. 152**-153^ 303.
Dahl's salt see l-Naphthylamine-4 J-distdphonic acid.
Datura stramonium. (Thorn-apple). [The references to this are in-
complete. ]
Cond. of dil. soln. of leaves; 146. Of root and stalk; 1326.
Dehydroacetic add. C8H8O4.
kAXlO«at25**=5.3; 1372;=1.0; 397.
Dia] TABLES 117
m(119.4)«8.9, (955.2) -24.3, (<x))-351; 1372.
Cond. not increased by boric acid; 1184.
iso-Dehydroacetic add. (Dimethyl-coumalic acid. Hydroxy-mesi-
tene-dicarboxylic acid anhydride). CsHsOa.
kAXlO" at 25^-5.3; m. p. 155%- 1186, 1372.
/i(65.3) = 155.6, (1044.8) -305.1, (oo)-353; 1372.
Cond. with boric acid; 1186.
Dehydroacetylcarbozylic add see Carbozydehydroacetic add.
Dehydrodiacetyl-laevulinic add. C9H10O4.
kAXlO»-6.8; m. p. 151.5*'-152^
m(265)=44.0, (1060)=84.2, (a) = 352; 1202.
Desozy-S-methylzanthine see 3-Methyl-2-ozy-l,6-dihydro-pi2ri]ie.
DesozytheophyUine see l,3-Dimethyl-2-ozy-l,6-dihydro-purine.
Desozyxantfaine see 2-Ozy-l,6-dihydro-purine.
Dextrose see Glucose.
Di- see also Bi-
DUceto-acetic add ethyl ester. CsH^Oi- (MeCO)2CH.C02Et.
At 25"*, A(128)»4.22 after standing one-quarter hour; 698.
Diacetone alcohol. QHuOa.
Cond. with bases; 979.
Diacetyl-diketo-hezaxnethylene-dicarbozylic add. (DuHuOg.
m(1000) -321.9; dec. 246''; 668.
Diacetj^-socdnic add. CgHioOe.
InNHs, qual.; 606.
Diacetyl-tartaric add. CgHioOg- (MeC02)2(iH2(C02H)2.
kx X 10* at 25° is more than 3. The anhydride (m. p. 128''-
129*^) dissolved in water gives at 25^ m(32) = 214, (1024)-
517, (go) -354. No constant can be calculated.; 1838.
Deakin, Rivett, Jour. Chem. Soc. 101, 127, (1912), find
kx X 10* at 25*^-2.5 in strong soln. Second kx X 10* approxi-
mates 1.1 (cond.).
Diacetyl-tartaric add anhydride. CgHgO?-
See the acid.
DiaUyl-malonic add. C9H12O4- (CH2 : CH.CH2)2C(C02H)2.
kAXlO" at 25**-7.6; diminishes on diln.; m. p. 133**.
/i(32) = 136.0, (1024)-313, (oo)=353; 1838.
Dialisric add. (5-Hydroxy-barbituric acid). C4H4O4N2.
kA at 25** is probably of the order of 10"*.
/i(128)-51.5, (1024)=67.7; 1748.
In NHs, qual. ; 606.
Dxaxnlno-benzene see Phenylene-diamine.
3,6-Diaimno-benzoic add.
C7H8Q2N2-(NH2)2C6H8.C02H. [CQ2H-I; NH2-3, 5.]
118 TABLES [Dk
kAXlO* at 25^»5; k on diln. diminishes, with minimum value
near v(288), then increases.
A(36)-6.9, (288) -12.5, (576) = 17.9, (»)-354; 175.
Diamino-caproic add see Lysine.
2,6-Diamino-phenol-4-8ulphonic add. CeHsOiNsS. [OH » 1 . ]
Cond. alpne and with NaOH; 1608, 1718.
2,S-Diamino-propiomc add.
CH8Q2N2-CHa(NH2).CH(NH2).C02H.
Cond. alone, and with organic acids; 146a.
Diamino-stilbene dicarboxylic add. (Anilinoglyoxylic acid).
C16H14O4N2 or C8H7O2N.
a- and fi- acids. Cond. with EOH; 499. [In 798 it is said that
these acids in 499 should be interchanged.]
Diamino-triphenyl carbinol. CwHigONa- (NH2C6H4)2.CPh.OH.
kB X 10* at 21*^=4 (colorim.); 1617.
Di-tso-amyl amine. CioH28N» (C6Hu)2.NH.
ke X 10* at 25*'=9.6 aq.; about 16% too high.
A(216)=70.6, (432) =87.6, (oo) = l91; 271.
In NHs, qual. ; 606.
B.HCl at 25^ A(32)-80.2, (1024)«91.6; 270.
Diamyl ether see Amyl ether.
Diamyl-j8-naphthyl amine. C20H29N.
In SQ2; 1842.
Dianisal see Dimethozy-dibenzal.
Diaterebic add anhydride see Terebic add.
Diazo compounds.
At the present time the nomenclature of diazo compounds is not
settled. Their structure also is still a matter of dispute.
The most general usage is to speak of the compound as a
diazo body, while its salt is a diazonium salt, e. g. diazo-
benzene, benzenediazonium chloride. This is done regard-
less of the question as to whether there are always two
isomers, one a neutral body (diazo) the other a salt-forming
body (diazonium). In these tables there is, therefore, a
lack of uniformity in the position of diazo compounds, in-
creased by the fact that the cyanides, chlorides, etc. are
regarded by some as separate compounds and by others as
salts. A duplication of references has been used to cover
such differences of opinion, since our present knowledge
does not seem to justify any final conclusion.
p-Diazo anisole see p-Anisole diazonium hydroxide.
Diazo benzene see Benzene diazonium hydroxide.
Diazo benzene add see Phenylnitroamine.
Dib] TABLES ' 119
Diazo benzene cyanide. C7HsNs»sPh.Ns.CN.
At 0^ m(64)=-25.0, (256) -30.3.
Cond. with HON; 735.
Diazo benzene p-sulplionic add. (Diazo sulphanilic acid).
C«H408N2S.
At0%/i(64) = 1.5; 635.
Cond. with NaOH; 636, 731.
KA; 774.- anii-2Na.A at 0% /i(32)=80.2, (1024) =97.4. syn-
2NaA at 0% /i(32)-81.6, (1024) is about 113; 636, 731.
Diazo guanidine. (Carbamide imide azide). CHfiONs.
At 25°, /i(32)sl9.8; changes in soln. to aminotetrazole.
B.HNOi at 25^ /i(32) is about 92, (1024) is about 114?; 779.
aitfi-j8-Diazo naphthalene. CioHsONs » C10H7.N2.OH.
Na.A at 0°, m(32)=34.4, (1024)=38.6; 600.
o-Diazo phenol. C6He02N2=OH.C6H4.N2.0H.
At25^M(64)=0.8.
B.Cl at 25^ /i(32)= 289.6, (1024) =384.5; 766.
p-Diazo phenol. C6H6O2N2.
At 25^ m(32) = 1.3, (64)= 1.7; m. p. 38*^-39^
B.Cl at 25% m(32) = 125.9, (1024)=254.2; 766.
Diazo sulphanilic add see Diazo benzene p-sulphonic add.
anA-Diazo urethane. (Nitroso-urethane). C8H6O8N2-EtO2C.N2.OH.
kAXlO« at 0^=1.6; m. p. 51*^-52^ /i(64)=2.2, (512)=6.4, («)«
221.
K.A at 0% /i(32)=42.4, (1024)=45.6; 774.
Dibenzal-acetone. (Dibenzylidene-acetone) .
C17H14O- (PhCH:CH)2C0.
Comparative strength (colorim.); m. p. 112.5^; 74, 1663.
l,3-Dibenzal-cydo-2-pentanone. Ci^HuO.
Comparative strength (colorim.); m. p. 189**; 1663.
Dibenzamide. (Benzoic acid imide). C14HUO2N.
Hg salt, e. m. f . ; 963.
Di-benzenesulphonic hydrazide. Ci2H]204N2S2 - (PhS02)2N2H2.
With NaOH at 25"", m(32)=62.4, showing cond. of a salt, Na.A;
m. p. 245*^; 781.
Dibenzoyl-acetone. C17H14O8.
Very weak acid in aq.
In pyridine; 754.
Dibenzoyl-tartaric add. CisHuOg - (PhC02)2C2H2(CQ2H)s.
kA X 10* at 25** is over 4; m. p. 90^-95**.
m(300)=241, (1200)=337, (oo)=352; 1838.
Dibenzyl-malonic add. Ci7Hi604= (PhCH2)2C(C02H)2.
kxXlO* at 25*^=4.1; m. p. 171^ 1838.
120 * TABLES [Dib
Second kAXlO*«1.9 (cond.); 1911.
At 25^ m(128) = 302, (1024)=349, (a>)=350; 1838.
2,6-Dibenzyl-pimelic aeid.
C2iHa404=C02H.(CH2Ph)CH.(CH2)8.CH(CH2Ph).C02H.
kxX 10^ at 25*'=4.8; m. p. 120*'; 1869, 1412.
m(2200) = 96.9, (4400) = 126.5, ( « ) = 350; 1869.
Dibromo-acetic acid. C2H202Br2.
In NHs, qual. ; 606.
Dibromo-acetyl- see Acetyldibromo-
4,6-Dibromo-anilme-2-8tilphomc add.
C6HB08NBr2S»Br2.C6H2(NHa).S08H. [NH2=1.]
kxXlO^ at 25*^=8.
A(278)=338, (1112)=351, (oo)=353; 1372.
4,6-Dibromo-anilme-2-8ulphomc add. CsHsOsNBraS.
kxX 10 at 25**= 1.8.
A(109.8)=338, (878.4)-348, (oo)=354; 1372.
4,6-Dibromo-am]ine-3-8tilphoiiic add. CeHsOsBNBi^S.
kx X 10^ at 25*'«2.9; diminishes on diln.
A(71.9) = 262, (1150.4)=340, (oo)=354; 1372.
2,6-Dibromo-aniline-4-stilphonic add. QHsOsNBr^S.
At 25^ A(64)- 330.1, (1024) =338.4, (oo)-354; 492.
Dibromo-barbituric add. C4H2()bN2Bi^.
kxXlO^ at 25^»8.6; diminishes on diln. because of decomposi-
tion.
m(32) = 5.9, (512)-24.2, (oo)=358; 1748.
Dibromo-benzene. C6H4Br2.
In NHj, qual.; 606.
2,4-Dibromo-benzeiie diazonium syn-cyanide.
C7H3N8Br2-Br2.C6H8.N2.CN.
AtO°, m(512) = 5.0.
In Etalc; 736.
2,4-Dibromo-benzene diazonium hydroxide. (2,4-Dibromo-diazo
benzene) . C6H40N2Br2= Bi^.C6H8.N2.0H.
kxX 10* at 0^=1.36; 601.
m(256)-23.7, (512)=31.2, (oo) = 137; 601.
B.CN; 736.
Dibromo-fluoroacetic acid. C;2H02Br2F» CBr2F.C02H.
At 25^ A(32) = 338.1, (1024) = 359.8, (oo)=360.1; b. p. 108^
Na.A at 25^ A(32)=71.7, (1024)=82.3; 1694.
Dibromo-gallic add. (3,4,5-Trihydroxy-2,6-dibromo-benzoic add).
C7H406Br2-Br2.C6(OH)8.C02H. [C02H= 1.]
kxX 102 at 25^- 1.21.
m(32) = 162.3, (1024)=337.7, (oo)=352; 1371.
Dib] TABLES 121
Dibromo-gallic add ethyl ester. C9H806Bi^-Bi^.C6(OH)s.C02Et.
kA X 10« at 25*^ is at least 1; m. p. 137**.
m(80)=4.8, (630) = 10.7, (oo)»349; - but some HBr is probably
present, making the values too high; 404.
Dibromo-gallic add methyl ester. CgHeOsBi^.
kAXlO« at 25^-1.1; m. p. 169^
m(32)=2.1, (256)=5.7, (a>) = 360; 404.
Dihromo-hydroshikimic add. (Dibromo-shikimic acid. Hydroshiki-
mic acid dibromide). CrHioOsBi^.
kA X IV at 12'-8; m. p. about 188** with dec.
m(41.8) = 132.5, (334.0) -239.1, («)= 294.6; 541.
Dibromo-hydrozy- see Hydrozy-dibromo-
2,3-Dibromo-l-mdone. (Dibromo-indenone. Dibromo-ketoindene) .
C»H40Bri.
Comparative strength (colorim.) ; 1665.
3,4-Dibromo-l-methylpyrrylglyozylic add.
CrHfiOjiNBri- Me.N.C4HBri(CO.C02H).
At 25^ A(294.8)- 334.5, (1179.4) -355.4, (<x))«357; m. p. 160^
j3-IHbromo-methylsulphonepropionic add.
CiHeOiBi^S- CHBrj.SO2.CH2.CH2.CO2H.
kAX 10^ [at 25'' 1=2.1; diminishes oh diln.
m(32)-27.8, (512) = 96, (<x))-352.
Na.A [at 25**], m(32)-63.0, (256)=71.2; 1134.
oa-Dibromo-propionic add. C8H4O2Br2-CHs.CBrk.CO2H.
kA X 10* at 25*^-3.3; diminishes on diln.; m. p. 61°.
A (32) -223, (1024) -345, (oo)-357; 1840.
ajS-IMbromo-propioiiic add. C8H402Bik - CH2Br.CHBr.CO2H.
kA X 10* at 25'*-6.7; diminishes on diln.; m. p. 64**.
A(32)-131, (1024)-332, (oo)-357; 1840.
Dibromo-shikimic see Dibromo-hydroshikimic.
^m.-I>ibromo-sttcdnic add. C4H4O4Bik-CO2H.CHBr.CHBr.CO2H.
kA X 10* at 25** is over 5; m. p. is over 200*"; 1838, 1638.
Second kAX 10*= 1.54 (part.); 370.
At 25^ m(32)-246, (1024) =571; 1838, 1638.
In NHs, qual.; 606.
Na.A; 370. - 2Na.A at 25^ A(32)-79.7, (1024)-96.7; 270, 370.
tM>-Dibromo-sttccinic acid. C4H404Br2.
At 25^ /i(65.2)-283, (1043)=463; m. p. 161^ 1638.
3,5-Dibromo-2-toltudine-4-sulphoiiic add.
C7H70»NBr2S-NH,.C6HBr2(Me).SO»H. [Me-1; NH2-2;
SO4H-4.]
kA X 10> at 25''-3.8; diminishes on diln.
A(64) -269.3, (512) =304.8, (00) -354; 492.
122 TABLES pib
Di-tso-butyl amine. CsHi^N - (CiHO^NH.
ks X 10^ at 25^=5 aq.; diminishes on diln.; about 16% too high.
A(64)=31.7, (256)-55.8, (<x))-194; 271.
In UiS, good cond.; 1897.
B.HCl at 25^ A(32) = 82.6, (1024) =94.4; 270.
Di-iso-butyl-dithio carbamic add. (Di-iso-butyl-thiosulphocarbamic
acid). C»HwNS2=(C4H»)2N.CS.SH.
Cu.2A in benzene, little cond.; 431.
Di-tso-butyl-pimelic add. C15H28O4.
Too insol. to get k accurately; m. p. 82^-84^; 1412.
cts-sym.-Di-iso-butyl-sucdiiic add.
CuH2204= C02H.CH(C4H9).(C4H9)CH.C02H.
kxXlO* at 25**«5.6; m. p. 97**-98^
m(668.5) = 157.0, (1337.0) = 198.0, (oo)=[351]; 236.
A'ans-s^m.-Di-tso-butyl-succinic add. C12HSO4.
kxXlO* at 25*'=2.25; m. p. 193M95^
m(1060) = 134.5, (2120) = 172.2, (»)-[351]; 286.
Di-iso-butyl-thiosulphocarbamic add see Di-iso-butyl-ditfaio-carbamic
add.
Dicarbozyl-glutaconic add tetraethyl ester.
Ci6H2208= (CQ2Et)2CH.CH:C(C02Et)2.
Fe.3A, in Et ale; 766. - Na.A in SO2, no cond.; 1842.
fi 7-Dicarboxylic^-valerolactone. (jS 7-Dicarboxylic^-valerolactonic
anhydride) . CrHgOe* C6He04(C02H)2.
kxX 10* at 25**= 6.6; diminishes on diln.; m. p. 168® with dec.
m(32) = 129, (1024)=308, (oo)=352; 1839.
Dichloro-acetic add. C2H2O2CI2 » CHCls.CO^H.
kAXlO« at 0** is about 7; 515, 2004. At 18°«5.15; 460. At
21.5*'=6.3 for v(20); 1416. At 25**=5.14; 1370;=5.7 aq.;
615; (neutral.); 296; (precipitation of casein); 693; (dis-
sociation) ; 1972, 1973.
Cond. at 0*»; 2004. At 12.5^ 709. At 17^ 1011. At 18** and
52^ 43. At 25^ A(32)=253.1, (1024)=360.1, (oo)=361;
1370; 294, 877.
In H2SO4; 167, 157a, 760. In NHs, qual.; 606. In Et ale; 664,
667, 1679, 1970, 1971. In Me ale; 1679.
Cond. with KOH; 294. Under pressure of 1-500 atmospheres;
220.
KA; 294. - Na.A at 25^ A(32)=71.9, (1024)=81.8; 1368a. At
18** and 52°; 43. - UQ2.2A; 449.
Dichloro-acetic acid ethyl ester. C4H602C12.
Effect of temperature on cond. ; 106.
Dichloro-aniline-S-sulphonic add.
C6H6Q8NCl2S=Cl2.C6H2(NH2).S08H. [NH2-I.]
Dic^ TABLES 128
kAXlO* at 25^*1.6; diminishes on diln.
A(128)-130.1, (1024)=227.7, (oo)=354; 492.
Bichloro-barbituric add. C4H208N2Cb.
kAXlO^ at 25^»1.75; diminishes on diln., because of decomposi-
tion in soln.
/*(64)=8.4, (1024)=29.3, (oo)=358; 1748.
/rniL-ajS-Dichloro-butyric add. C4He02Cla= Me.CHCLCHCl.COjH.
kAXlV^e.l; m. p. 78^
A(32)-127.5, (1024)=314.1, (oo)=357; 1264.
iruif.-aj8-Dichloro-butyric add. C4H602C12.
kAX 10^=8.2; increases on diln.; m. p. 63°.
A(32)-41.3, (1024)-337.3, (oo)==357; 1254.
Dichloro-fluoroacetic add. C2H02Cl2F»CCl2F.C02H.
At 24.7^ A(32) = 332.7, (1024)=356.4, (oo)=358.4; b. p. 162.5%-
1700; qual. (sapon.); 1691.
Na.A at 25% A(32) = 73.3, (1024)«85.3; 1700.
Dichloro-gallein. C20H10O7CI2; formerly given as QoHsOrCb.
In MeNH2, very poor cond. ; 637.
2,6-Dicliloro-gallic add ethyl ester. (3,4;&-Trihydroxy-2,6-dichloro-
benzoic acid ethyl ester).
C»H806Cl2=Cl2.C6(OH)8.CQ2Et. [C02Et=l.]
kAXlO^ at 25*'-4.2; m. p. 151*'-153^
m(32) = 1.3, (256)=3.7, (oo)-349; 404.
2,6-Didiloro-gallic add methyl ester. CsHeOsCb.
kAXlCF at 25**= 6.0; increases on diln.; m. p. 160M70%
m(32) = 1.5, (256) =4.6, (oo)-350; 404.
Didiloro-hydiin. (^m.-Dichloro^>o-propyl alcohol).
CHeOCl2=.CH2Cl.CHOH.CH2Cl.
xxl0*at25*'=1.09.
Cond. with Cu oleate; and as solvent; 1569.
Didxloro-hydrozy- see Hydrozy-dichloro-
jS-IMdiioro-methylsulphonepropionic add.
C4He04Cl2S=CHCl2.S02.CH2.CH2.C02H.
kAXlO^»2; diminishes on diln.
m(32)-26.9, (256) =70.5, (oo)=352; 1134.
Dichloronitro- see Nitrodichloro-
2,4-Didxloro-phenol. C6H40Cl2= Ck.CeHs.OH.
kAXlO^ at 25*'=-1.3 (sapon.); 733 and 1150;=2; 733; (neutral.);
1718.
A(64)-0.5, (256) = 1.1, (oo)=356; 733. - 1508, 1718.
Cond. with NHs; 733. With NaOH; 1508, 1718.
NHi.A. - Na.A, A(32)=64.2, (1024)=76.1; 733.
3^6-Didxloro-o-phthalic add.
C8H404Cl2-Cl2.CeH2(C02H)2. [C02H=1,2; CI- 3, 6.]
124 TABLES [Die
IcaXIO' at 25°»3.4; increases on diln.; (m. p. of anhydride^
187.5*'-189.5^); 1909.
Second kAXlO*-2.8; 1911.
At 25% /i(32.0)- 240.1, (1031)-444.7, (oo)=377; 1909.
3,6-Dichloro-o-phthalic acid mono ethyl ester.
CioHgOiCU = Cl2.QH2(CQ2H) (CQiEt) .
kA XlO* at 25** is about 1.5.
/i(514.5)« 335.6, (1030)=354.3, (oo)=374; 1909.
5ym.-Dichloro-tso-propyl alcohol see Dichloro-hydiin.
3,6-Dichloro-quinonedinialonic add tetra ethyl ester. CS0H22O10CI2.
Satd. soln. has minimum cond.; 1188.
/iim.-2,S-Dichloro-8uccimc add.
C4H4O4CI2- CO2H.CHCI.CHCI.CO2H.
kAXlO^=4; increases on diln.; m. p. 215®.
/i(32)-237.2, (64)«291.1; (oo)«[351]; 1264.
iiui{.-2,3-Dichloro-sucdmc add. (aZ2o-2,3-Dichloro-succinic acid).
C4H4O4CI2.
kAXlO*=7; increases on diln.; m. p. 175**.
m(32)- 252.3, (64) -308.5, (00)- [351]; 1254.
6,6-Dichloro-veratric add. (3,4-Dimethoxy-5,6-dicbloro-ben2oic acid).
C»H804Cl2= (MeO)2C6H(Cl)2.C02H. [CQ2H= 1. ]
kAXlO* at 25*'»1; diminishes on dUn.; m. p. 182M83^
/i(1354) = 237, (2708) = 258, (a>)-352; 404.
Didnnamenyl-acetone see Dicinnamenyl-vinyl-ketone.
Dicinnamenyl-cyclopentanone. C28H20O.
Comparative strength (colorim.); m. p. 89®; 1663.
Dicinnamenyl-dichloro-methane. (Dist3rryl-dichloro-methane) .
C17H14CI2.
In SO2; m. p. 77®; 1676.
Didnnamenyl-vinyl-ketone. (Dieinnamenyl-acetone). CnHigO.
Comparative strength (colorim.); m. p. 142®; 1663.
Dicrotonic acid. (/S-Methyl-a-ethylidene-glutaric acid).
C8Hi204-C02H.CH2.CHMe.C(:CHMe)C02H.
kAXl0^=2.81; m. p. 129®.
Nasalt, cond. (1024-32) -11.9; 1398.
Dicuminal-acetone. C28H26O.
Comparative strength (colorim.) ; 1668*
Dicuminal-cyclopentanone. C26H28O.
Comparative strength (colorim.) ; 1663.
Dicyano-diamide. C2H4N4-NH:C(NH2).NH(CN).
Very weak acid. H ion concentration of 2% 8oln.»10~'. 0.3%
soln., xXlO«-2.4; 882.
Dic3ranogen see Csranogen.
Die] TABLES 125
3,4-Diethozy-benzoic acid. (Diethyl-protocatechuic acid. Proto-
catechuic acid 3,4-diethyl ether).
C11H14O4- (EtO)jC6H,.CQ2H. [COiH- 1. ]
kAXlO*at25*'=3.38.
A(1024)-59.3, (oo)«350; 1371.
Diethyl-acetic add. CeH^Oa^ CHEt2.C02H.
kAXlO* at 25*^=2.03; b. p. 190^ 180, 1840;=1.89; 601.
A(76)-13.5, (1216) = 50.5, (a>)=352; 1840.
Na.A at 25^ A(32)-63.7, (1024) =73.4; 601.
Diethyl-amine. CiHuN » Et2NH.
keXlO" at 25**- 1.26 aq.; about 16% too high.
A(32)=37.1, (256)=86.6, (oo)=203; 271.
In NHs, qual.; 606.
Cond. with ethyl sulphamide; 1676.
B.HCl at 25^ A(32)=92.0, (1024) = 103.7; 270. In HBr, good
cond.; 1646. In SO2; 1865. In NHs; 610. In Et ale;
1884.
Diethylamino-acetic add. (Diethyl-glycine).
CeHisOaN* NEt2.CH2.CO2H.
Cu.2A at 25^ A(32)=0.15, (64) =0.28; 1087.
Diethyl-amino-azobenzene. CieHi^Ns.
Cond. in HCl of compound not wholly pure; 1984.
2,6-Diethyl-l-aiiiino-l,3,4-triazole. (Diethyl-isodihydro-tetrazine).
C«Hi2N4.
keXlO^® [at 25^]-1.68 (solub.); m. p. 167^ 428.
Diethyl-aniline. CioHuN = CeHs. NEt2.
kB Xl(F at 19** is at least 1 (colorim.); 1777.
In HBr, good cond.; in H2S, poor cond.; 1897. In NHs, qual.;
606.
B.HCl at 25^ A(64)-87.9, (256)=93.8; 270.
5,6-IMetliyl-barbituric add. (Veronal.) C8Hi20kN2.
kxXlO' at 25*'=3.7; m. p. 187^
m(64)=0.6; 1996.
In pyridine, almost no cond. ; 754.
Diethyl-benzyl amine. CuHi7N=PhCH2.NEt2.
keXlO^ at 26^=3.6.
m(137.7) = 13.1, (550.8)=24.7, (oo) = 192; 664.
Dietfayl-m-cUoroaniHne. CioHi4NCl= Cl.C0H4.NEt2.
ks XlO^® at 25"^ is less than 2.4 (colorim. and solub.); 660, 957.
Dietfayl-ifo-dihydro-tetrazine see Diethyl-amino-triazole.
Dietfaylene diamine. (Piperazine). C4HioN2=NH(C2H4)2NH.
ks XlO^ at 25^=6.7 aq.; about 16% too high; diminishes on diln.
A(32)=9.1, (256) = 23.9, (oo)-202; 271.
B.2HC1 at 25^ A(32)- 116.0, (1024) = 145.2; 270.
126 TABLES pie
/3-Diefhyl-efhylenelactic acid. CtHuQs^ EtsC(OH).CH2.CQ2H.
kAXlO* at 25*'=3; m. p. 38**-39^
m(35.1)-11.1, (1123.8) =59.7, (oo)=350; 1704.
a-s|/m.-Diethyl-glutaric add. C^HwO*" CHa(CHEt.COiH)t.
kAXlO*^ at 25°=:5.3; m. p. 118^-119^ 61, 1418.
m(128) = 27.7, (1024)=74.8, (oo)«351; 61.
j3-5](m.-Diethyl-glutaric acid. C9H16O4.
kAXlO* at 25*'=5.9; m. p. 76*^-78^ 61, 176, 1418.
/i(128)=29.3, (1024)=77.5, (oo)«351; 61.
Diethyl-malonic add. CrHuOi^ Et2C(C02H)2.
kAXl(Patl8*'-8.5 (colorim.); 1663. At 25**= 7.4; m. p. 120^-
121°; 1838.
Second kAX 10^= 1.8 (inversion); 1638.
At 25^ /i(32) = 135.7, (1024)=312, (a>)«354; 1838.
Diethyl-malonic acidmono ethyl ester. C9Hi604» Et2C(CQ2H) (CQaEt).
kAXlO^ at 25^=2.31; diminishes on diln.
/i(36.5)=30.9, (1168.0) = 140.0, (oo)=351; 1869.
Diethyl-pentanetetracarhozylic acid.
CisH2o08=(C02H)2CEt.(CH2)«.CEt(C02H)2.
kAXlO*at25*'-2.1.
/i(11.3) = 120.4, (1446.0) = 51 1.0, (a>)«350; 1869.
Diethyl phosphoric add see Phosphoric acid diethyl ester.
2,6-Diethyl-pimeUc add. CiiH2o04=CH2(CH2.CHEt.CQiH)2.
kAXlO*^ at 25*^=3.45; m. p. 96*'-97^ 1412, 1869.
/i(155.0) = 24.6, (310.0) =34.5, (a>)=350; 1869.
Diethyl-protocatechuic add see 3,4-Diethoxy-benzoic acid.
Diethyl selenium thetine. C6Hi403Se= OH.SeEt2.CH2.CQ2H.
kB XlOio=3 (hydro!.); 360 and 1160.
/i(32)=7.2, (256) = 11.9.
B.Br, /i(32)=96, (1024) = 105; M(32) = 106.5; 360.
/um.-sym.-Diethyl-succinic add. (para- acid).
C8Hi404= CQ2H.CHEt.CHEt.CO2H.
kAXlO* at 25*^=2.35; m. p. 192**; 280, 196, 200, 1371, 1838,
2018.
M(65.9)=41.2, (1054) = 136.6, (a)=351; 280.
ma/.-sym.-Diethyl-suCdnic add. (anti- acid. Diethylene-succinic
acid). C8H14O4.
kAXlO* at 25^=3.47; m. p. 130^ 280, 196, 200, 1371, 1838,
2018.
/i(93.7) = 58.0, (1499) -177.2, (oo)«351; 280.
DiethylHSucdnic add. (Bischofif's).
kAXlO^ at 25^=3.8; diminishes on diln.; impure?; m. p. 137.5^;
198, 1838.
Dig] TABLES 127
m(32)«36.9, (1024) = 160, (<x))=351; 1838. ^
2Na.A at 25^ /i(32) = 73.1, (1024)=90.6; 1838.
Diethyl sulphide. (Ethyl sulphide) . C4H10S « Et2S.
Cond. with EtI in Me, Et and benzyl ale; 334. With Hgis in
acetone; 1379.
Diethyl sulphite see Sulphurous add diethyl ester.
osym.-Diethyl sulphite see Ethyl sulphonic acid ethyl ester.
Diethyl thetme. CeHuOsS^ OH.SEt2.CH2.CO2H.
kBXl0"=5 (hydrol.); 360 and 1160.
m(32)=2.5, (256)-3.1.
B.Br.- B.Cl, /i(32)=93, (1024) = 103; M(32)=268.4; 360.
Diethyl-m-toluidine. CnHnN^ Me.C6H4.NEt2.
kB XlO^ at 25** is over 2.3 (solub.); 660, 967.
Diethyl-txiazole. CeHuNg.
kBXl0^^=5 (sapon.); m. p. 66**; 428.
Diethyl-urea. C6H]20N2.
B.HCl at 25^ A(50)= 362.3; 1864.
Diferri-pentaacetyl hydroxide. CioHi60iiFe2=Fe2(C2H«02)6.0H.
At25^ A(32)=9.3, (1024>=82.2; 1628.
Difluoro-acetic acid. C2H2O2F2 » CHF2.CO2H.
kAXlO* at 25**= 5.7; b. p. 134.2** (cor.) @ 766 mm.
A(32)=283.7, (1024)=394.5, (oo)=395.
Na.A at 25% A(32)=85.7, (64) = 89, (oo)=99; 1696.
Difluoro-ethyl alcohol. C2H4OF2 = C2H8F2.OH.
0.5 normal soln. [at 25**], A=0.02; b. p. 95.5**-96°; 1696.
Difluoro-ethyl amine. C2H6NF2=CHF2.CH2.NH2.
kflXlO' [at 25^]=3.3; b. p. 67.5**-67.8° (cor.) @ 757 mm.
A(32)=0.8, (128) = 1.6, (oo)=245.2.
B.HCl [at 25^], A(^2.3) = 105.5, (1034.2) = 123.5; 1697.
Difluoro-ethyhiitroamine. C2H402N2F2= CHF2.CH2.NH(N02).
kxXlO^ [at 25'']= 1.36; b. p. 111°-112° @ 12 mm.
A(33.2) = 8.0, (1061.1)=44.3, (oo)«382.6.
Na.A [at 25**], A(33.2)=77.2, (1061.1)=88.6; 1697.
Difural see Difurfural.
Difurfural-acetone. CisHioOs.
Comparative strength (colorim.); 1663.
l,3-D]furfural-cyclo-2-pentanone. C16H12O3.
Comparative strength (colorim.); m. p. 163^; 1663.
a-DigaUic add. C14H10O9- (OH)8.C6H2.CO2.CeH2(OH)2.C02H.
kAXlO^ at 25**= 1.2; sinters 120^ dec. 150^
/i(32)=6.8, (128) = 13, (a)=350; 1826.
Digitaline. [A mixture?]
In NHs, qual.; 606.
128 TABLES [Dig
Digitalis. (Foxglove). [The references to this are incomplete.]
Cond. of soln. of powdered drug; 146.
Diglycolamic acid. CiHTOiN^ NH(CH2.C02H)2.
kAXlO'<«2; increases on diln.
/i(32) = 59.5, (1024)-265, (oo)=354; 1673. Qual.; 1669.
Hg.A, e. m. f.; 963.
Diglycollic acid. CiHeOs- 0(CH2.C02H)2.
kAXlC? at 25^=1.1; 1370.
Second kxX 10* =3.7 (cond.); 1911.
At25^ m(64)-82.0, (1024)=239.6, (a>)=356; 1370.
2Na.A at 25^ A(32)=81.0, (1024) = 99.0; 270.
Dihydro- see also Hydro-
Dihydro-camphoric acid. CioHi804=C8Hi6(C02H)2.
kAXlO'*=4.15; m. p. 106^ 413.
Dihydro-coUidinedicarboxylic acid diethyl ester. C14H21O4N.
In NHs, qual. ; 606.
AajS-Dihydro-muconic add. (stabile acid).
C6H804=C02H.(CH2)2.CH:CH.C02H.
kxXlO* at 25** =2.20; diminishes on diln.; m. p. 169M70°;
1638, 1643.
Second kAXl0*= 7.9 (inversion); 1638.
At 25^ /i(66.7)=40.4, (1077) = 103.0, (oo)-354; 1638.
Ajdy-Dihydro-muconic acid, {labile acid).
C6H804= CO2H.CH2.CH :CH.CH2.CQ2H.
kxXlO* at 25*^=1.02; m. p. 195^• 1638,1643.
Second kxX 10*= 5.3 (inversion); 1638.
At 25^ /i(64) = 27.4, (1024) =96.0, (00) =354; 1638.
A^-Dihydro-a-naphthoic add. (a or labile acid).
Ciillio02= C10H9.CO2H.
kxXlO* at 25*^=1.14; m. p. Ol*'; 176, 71.
A(80.2)=31.9, (1282.7) = 112.1, (a>)=350; 176.
A^-Dihydro-a-naphthoic acid. (j3 or stabile acid). CiiHio02-
kxXlO* at 25°=8.0; m. p. 125**; 176, 71.
A(335.1) = 53, (1340.4) =99.1, (oo) = 350; 176.
A^-Dihydro-jS-naphthoic acid. (A^ or labile acid). C11H10Q2.
kxXlO* at 25*'=5.15; increases on diln.; m. p. 104**; 70, 71.
A(226.7) = 35.8, (906.8)=69.1, (a>) = 352; 70.
A^-Dihydro-/3-naphthoic add. (A^ or stabile acid). C11H10O2.
kxXlO* at 25*'=2.9; increases on diln.; m. p. 161**; 70, 71.
A(1795)=72.2, (3590)=97.3, (oo)-352; 70.
A i-'-Dihydro-o-phthaHc acid. C8H804= C6He(CQ2H)2. [CO2H -1,2.]
kxXlO* at 25** =7.98; diminishes on diln.
m(32)=55.6, (1024) = 199.3, (a>)-:377; (the anhydride has m. p.
58**); 1.
Dih] TABLES 129
A'-^^Dihydro-o-phihaUc add. CgHgOi.
kAXlO* [at 25*']- 1.55; m. p. 179M80^ 72.
A2.s.Dihydro-o-phthaUc add. CsHgOi.
kx XlO^ at 25^»5.5; diminishes on diln.
/i(32)=46.9, (1024)- 187.6; (oo)-377; (the anhydride has m. p.
73*^-74^); 3.
A>'«-Dihydro-o-phthaUc add. CsHsOa.
kAXlO* at 25*'=1.7; m. p. 215'; 72, 1638.
Second kAXlO*« 1.2 (inversion); 1638.
At 25^ m(64)=33.4, (1024) = 116.9, (a>)=353; 1638.
frans-A^*^-Dihydro-o-phthalic add. C8H8O4.
kAXlO* [at 25^-2.46; m. p. 210^• 72.
Dihydro-resorcyiol (Hydroresorcinol). CeH8Q2='CeH70(OH).
kAXlO«at25°=5.5aq.
A(32)=4.8, (1024) = 28.4, (a) = 377.
Na.A at 25^ A(32)=68.7, (1024) = 81.4; 1588.
Dihydro-tetrazine see Amino-triazole.
Dihydrozy- see also Dioxy-
1,2-Dihydroxy-anthraquinone see Alizarin.
4,4'-I>ihydrozy-azobenzeiie see p-Azophenol.
2,4-Dihydrozy-benzaldehyde. (Resorcyl aldehyde).
C7H«0»=(OH)2.C6H8.CHO. [CHO-l; OH-2, 4.]
kAXlO« at 25^=3.57; m. p. 134M35.*'
m(128)=7.5, (1024)«21.0, (oo)=355; 643.
2,&-Dihydroxy-benzaldehyde. (Gentisic aldehyde). CtHsO^.
kAXlO** at 25**=4.2; m. p. 99**.
/i(128)=25.4, (1024) = 66.4, (oo)=355; 643.
3,4-Dihydrozy-benzaldehyde. (Protocatechuic aldehyde). C^HeOs.
kAXlO** at 25*^=3.1; 643;=:0.0028; 1397c.
m(256)=32.4, (1024)«58.2, (oo)«355; 643. m(32) = 0.4, (128) =
0.8, (00) =379; 1397c. - 1718. [While the values of k and
IX in 643 are probably too high, the values in 1397c seem to
be entirely too low. ]
Cond. with NaOH in aq. and Et ale; 1718.
o-Dihydrozy-benzene see Pyrocatechol.
m-Dibydrozy-benzene see Resorcinol.
p-Dihydrozy-benzene see Hydroquinone.
2,3-Dfliydrozy-benzoic acid. (3-Hydroxy-salicylic acid. m-Oxy-
salicylic acid. Pyrocatechin-o-carboxylic acid).
C7H«04-(OH)2.C6H8.C02H. [C02H=1; OH-2, 3.]
kAXlO» at 25**= 1.14; 1368, 1371.
m(64)=84.1, (1024)=230.0, (oo)=356; 1371.
2,4-IMliydrozy-benzoic add. (j3-Resorcylic acid, a-acid of Ostwald).
CrHeO*.
180 TABLES [Dih
kAXlO* at 25^=5; m. p. 188^ to 206*»; 1186, 1871, 1684 ;« 8.8
(neutral.); 1718.
/*(64)=58.6, (1024)-181.7, (oo)-356; 1371.
In Et ale; 1186, 1718, 1970.
Cond. with boric acid; 1186, 1186. With NaOH; 1608, 1718.
2,6-Dihydroz7-benzoic add. (Gentisic acid. 5-Hydroxy-8alicylic
acid). . CiHeOi.
kAXlC? at 18*'=1.2 (colorim.); 1663. At 25°«1.08; increases
on diln.; 1371.
At 25^ m(64)«80.5, (1024) =227.1, (00)= 356; 1371.
S,6-Dihydroxy-benzoic add. (j3-Resorcylic acid of Ostwald). CjB^Oi*
kAXlO^ at 25*^=5.
m(64)«285, (1024)=347, (oo)-356; 1371.-1608, 1718.
Cond. with NaOH; m. p. 150** dec; 1608, 1718.
3,4-Dihydrozy-benzoic acid. (Protocatechuic acid). Cj'H^Oi.
kxXlO* at 18*'=4.1 (colorim.); 1663. At 25*'=3.3; increases on
dUn.; m. p. 199**; 1186, 1371.
At 25^ /i(32) = 10.7, (64) = 15.1, (1024) =59.3, (00) =356; 1371.
- 1718.
In Et ale; 1186.
Cond. with boric acid; 1186; qual.; 1184. With NaOH; 1608,
1718.
3,6-Dihydroxy-benzoic acid. C7H6O4.
kAXl0fiat25**=9.1.
/i(32) = 18.7, (64) = 26.1, (1024)=94.5, (oo)«356; 1371.
Di(hydroxybenzyl) hypophosphoric add.
Ci4Hi504P= (Ph.CH0H)2P0.0H.
Relative cond.; (the aniline salt has m. p. 190® dec); 1771.
Dihydrozy-carbostyril see Trihydroxy-quinoline.
2,4-Dihydrozy-dnnamic acid see UmbeUic acid.
3,4-Dihydrozy-cinnaimc acid see Caffeic acid.
Dihydrozy-dibromo-benzoquinone see Bromoanilic add.
3,4-Diliydroxy-2,6-dicliloro-benzoic add. (Dichloro-protocatechuic
acid).
CVH4O4CI2- (OH)a.C6HCl2.C02H. [C02H= 1; OH=3,4;
Cl=2, 5.]
kAXlO* at 25° is about 1.2; increases on diln.
m(32)=46.5, (64) = 70.7, (1024)=229.1, (oo)=355; m. p. 220°;
404.
3,4-Dihydroxy-2,6-dichloro-benzoic add methyl ester.
C8H6O4CI2. [C02Me=l.]
kA X10« at 25**=4.4; m. p. 105^
m(256)«11.9, (1024) = 23.5, (oo)=352; 404.
Dim] TABLES 181
3,4-Dihydrozy-6,6-diclilQro-beiizoic add. C7H4O4CI2. [COiH»l.]
kAXlO" at 25° is about 1.2; increases on diln.
m(64)=70.6, (1024)=223.5, (a>)=355; m. p. 239^ 404.
3,4-Dihydrozy-6,6^dichloro-benzoic acid methyl ester.
C8He04Cla. [C02Me=l.]
Too insoi. in aq. to measure; m. p. 223*^-225°; 404.
a-Dihydrozy-dihydro-campholenic acid.
C10H18O4- C9Hib(OH)2.C02H.
kAXlO^ at 18'*='2.5; increases on diln.; m. p. 144M45^
/i(59)=11.8, (1185)=50.4, (oo)=317; 1899.
Dibydrozy-dimethyl- see Dimethyl-dihydrozy-
Dibydrozy-ftimaric add. (jS-acid).
C4H40e=C02H.C(OH) :C(0H).CQ2H.
IcaXIO^ at 25.2° is about 7.2 aq. Cond. increases rapidly on
standing, therefore the values are not accurate.
/i(64)=306, (00) =356; 1629.
Dihydrozy-hydroshikimic add. (inactive). C7H12O7.
kAXlO* at 19°=7.2; m. p. 156° dec.
m(20)=36.6, (320) = 121.7, (oo)=:323.8; 641.
Dihydroxy-maleic acid. C4H406* COjH.CCOH) :C(0H).C02H.
kAXlO* at 25° is about 7.2 aq. Cond. increases rapidly on
standing; but the values are more accurate than for dihy-
droxy-fumaric acid.
/i(64)= 298.4, (128) =325, («>)=356; 1629.
1,7-Dihydrozy-naphfhalene. CioHgOa.
Cond. with NaOH; m. p. 178°; 1017.
DDiydrozy-picoliiiic add see Comenamic acid.
Dihydrozy-quinonedicarbozylic add diethyl ester. CuHuOg.
In pyridine; 764.
Dihydroxy-tartaric add. C4H608=C02H.C(OH)2.C(OH)2.C02H.
kA XlC at 25° is about 1.24 aq.; diminishes on diln., because of
changing to tartronic acid and CO2.
m(32) = 162, (1024) =322, (oo)=354; 1629.
3,6-Dihydrozy-tolueiie see Orcinol.
Dihydrozy-triazolidine- see Methyl-dihydroxy-triazole etc.
Diketopiperazine see Aminoacetic add anhydride.
2,5-Diketo-tetrahydro-thiazole. (Carbamine thioglycoUic acid anhy-
dride. Dioxy-thiazole. Mustard oil acetic acid).
C8H8O2NS.
kAXlO^ at 0°=0.71. At 18°= 1.5. At 25°= 1.8; 949;=2.4; 1370.
At 25°, m(16)=0.7, (32) = 1.0, (oo)«360; 1370. - 949.
In Et ale; 782.
NH4.A; 949.
3,4-Dimethozy-benzoic add see Veratric acid.
182 TABLES pim
2,2'-Dimethoxy-dibenzal acetone. (o,o'-Dianisal-acetone).
CigHigOj.
Comparative strength (colorim.); m. p. 125^; 74.
SyS'-Dimethoxy-dibenzal acetone. (m,m'-Dianisal-acetone),
C19H18O3.
Comparative strength (colorim.); m. p. 62**-54**; 74.
4,4'-Dimethoxy-dibenzal acetone. (p,p'-Dianisal-acetone).
CigHisQs-
Comparative strength (colorim.); m. p. 130^; 74, 1663.
ly3-Dimethozy-dibenzal-cyclo-2-pentanone. (Dianisal-cyclopenta-
none). C21H20OJ.
Comparative strength (colorim.); m. p. 212^; 1663.
3,4-Dimethoxy-5,6-dichloro-benzoic acid see 6,6-Dichloro-Teratric
acid.
Dimethozy-norhemipinic acid see Hemipinic acid.
Dimethozy-noropianic add see Opianic acid.
3,6-Dimetiiozy-phenylzanthonium carboxylic add methyl ester.
C23H2oO«= (MeO)2Ci9HioO(C02Me).OH.
At 0, A(200)=82;=68 after 1 minute,=16.6 after 20 minutes;
956a, 1292a.
B.Cl (=C28Hi906Cl) at 18^ A(64)-148.7, (1024) = 170.0; 966a.
3,4-Dimethozy-o-phthalic acid see Hemipinic add.
Dimethyl-acetamide see Acetic add amide.
aa'-Dimethyl-/3-acetozy-gIutaric add. (Dimethyl-hydroxy-glutaric
acid acetyl derivative).
CgHuOa^ MeC02.CH(CHMe.C02H)2.
kAXlO* at 25**=2; m. p. 120^-121*'; 1476, 1704.
iu(33.4)=27.2, (1068.8) = 126.6, (00) =348; 1704.
/3-Dimethyl-acryUc acid. C6H8O2 = Me2C :CH.C02H.
kxXlO* [at 25**]=2; m. p. 70^ 1411.
a-5ym.-Dimethyl-adipic add. (fum,).
C8Hi404=C02H.CHMe.CH2.CH2.CHMe.C02H.
kxXlO'^ at 26*'=4.2; m. p. 140*^-14^; 2016, 2018, 2021.
Second kxXlO'^ 1.7 (inversion); 1638.
At 25^ /x(56.1)-16.6, (448.6)=44.9, (co) = 351; 2018.
/3-sym.-Dimethyl-adipic add. (moZ.). C8H14O4.
kxXlO^ at 25**=4.2; m. p. 74*'-76^• 2016, 2018, 2021.
Second kxXlO*- 1.7 (inversion); 1638.
At 25^ /x(24.8) = ll.l, (396.8)=42.7, (oo)=361; 2018. '
Dimethyl-alloxan. CeH604N2.
At25% A(32)=7.5, (1024)-16.1, (00)= [366]; 1748.
Dimethyl-amine. C2H7N » Me2NH.
kBXlO* at 0^=3.71. At 6.5**-4.18. At 10**-= 5.01. At20*'«5.10.
At 25*'=6.35; 776;=6 (neutral.); 299a;-7.4 aq.; about 16%
Dim] TABLES 183
too high; 271. At SO^'-S.ae. At 35*'-5.46. At 40^-5.67.
At 45*'=5.67. At 50** =5.63; 776.
At 25% A(32)-31.0, (256)=75.4, (oo)=217; 271. - 299a.
Cond. with HCl; 299a. With NaCl; 177. Complex with sue-
cinimide; 1760, 1766.
B.HClat 25°, A(32) = 106.3., (1024)= 117.6; 270. In SOj; 1842,
1866. In NH4OH; 660. In CHCb; 740.
Dimethyl-amlnoacetic acid. (Dimethyl-glycocoll).
C4H902N= NMe2.CH8.COsH.
kAXlO^® at 25°=1.4 (catal.);=2000 (cond.).
ksXlO" at 25**= 1.06 (catal.); m. p. 157°-160**; 890.
Dimethyl-aminoazobenzene. CuH^Ns^ Ph.Ns.C6H4.NMes.
• kAXlO^i at 18°-19°=1.45 (colorim.); 1662.
p-Dimethyl-aminoazobenzene-o-carboxylic acid. (Methyl Red).
Ci6Hi602N8=Me2N.C«H4.N2.CeH4.C02H.
kxXlO*^ at 18**= 1.05 (colorim.).
ksXlO" at 18**=3 (colorim.); 1729a.
p-Dimethyl-aminoazobenzene sulphonic add. (Sodium salt»Heli-
anthine. Methyl Orange, Orange III or Tropaeolin).
Ci4Hi60aN8S= Me2N.CeH4.N2.C6H4.SOjH.
kAXlO* at 18^-19**= 4.6 (colorim.); 1662. At 25** is about 0.3;
1984. =4.3 (colorim.); 1729a.
kB XlO^^ at 25'', is less than 1 (colorim.); 1729a.
At 25^ A(970) = 52.0, (1940) =62.4, (oo) = 349; 1984.
Cond. with HCl and with bases; 1984.
Na.A at 25^ A(256)=68.5, (1024) =70.4; 1984, 1770. With
inorg. acids; 1770, 1984. With NaOH; 1984. In MeNHj,
fair cond.; 637. - E.A; 1984. [See 1706, 1706a, 1782, con-
cerning accuracy of colorimetric methods. ]
o-Dimefhyl-aminobenzoic add. (Dimethyl-anthranilic acid).
C9Hii02N=Me2N.C6H4.C02H.
kA X10» at 25**=2.3 (catal.).
knXlO^ at 25*^=2.8 (catal.); m. p. 70^
At 26% A(8) = 0.06.
Na.A at 25% A(32) = 67.4, (1024)=80.8; 414.
o-Dimefhyl-aminobenzoic add methyl ester.
CioHu02N= Me2N.C6H4.C02Me.
kBXlO" at 25*^=6.1 (catal.); (B.HCl has m. p. 145°-147°); 414.
m-Dimefhyl-aminobenzoic acid. CBH11O2N = Me2N.C6H4.CO2H.
kAXlO* at 25°=8 (catal.). =5.5 (cond.).
ka XlO^^ at 25**= 1.9 (catal.).
At 25% A(128)=8.6, (1024)=27.0, (oo)-375; 414.
ffl-Dimethyl-aminobenzoic add methyl ester. C10H13O2N.
ksXlO" at 25*'=7.3 (catal.); (BJICl has m. p. 175M77**); 414.
184. TABLES pim
p-Dimethyl-aminobenzoic add. C»Hii02N = Me1N.C6H4.CQ2H.
kAXlO« at 25**-9.4 (solub.);=8.6 (cond.).
kBXlO^* at 26**= 3.26 (solub.); m. p. 235**-236^
A(2260)=49.0.
Na.A at 25°, A(32) = 67.0, (1024) =79.0; 890.
p-Dimethyl-aminobenzoic add methyl ester. CioHuOiN.
kBXl0^2 at 25*^=3.34 (solub.); m. p. 102**; 890.
m-Dimethyl-aminophenol. (m-Hy droxy-dlmethyl-aniline) .
CgHuON^ Me2N.C6H4.OH.
In Et ale, alone and with NaOH; m. p. 86**; 1608.
2,5-Dimethyl-l-amino-l,3,4-tiiazole. (Dimethyl-isodihydrotetra-
zine). C4H8N4.
kBXl0i<> [at 25*']= 1.4 (solub.); m. p. 199**; 428.
oa-Dimethyl-a'-iso-amylsucdnic add.
CiiH2o04-C02H.CMe2.CH(C6Hu).C02H.
kxXlO* at 25**=6.16; diminishes on diln.; m. p. 143*'-144^
m(121.2)=83.4, (969.6) = 184.2, (oo)=[351]; 236.
Dimethyl-aniline. C8HuN= C6H6.NMe2.
kaXlO^® at 18*'=2.42 (colorim.); 1777.
In HBr, HCl and HI, good cond.; in H2S, poor cond.; 1897. In
SO2; 1842. In NHs, qual.; 606. In benzene, no cond.; 1802.
Cond. with acetic acid; 1011, 1388. With picric acid; 1802.
With allyl thiocarbimide, no cond.; 1223. As solvent;
1552a.
B.HCl at 25^ A(64)=93.6, (256) =98.3; 270, 1864. - B.H2SO4;
1864.
Dimethyl-aniline-4-8ulphonic add.
C8Hii08NS=Me2N.C6H4.SQ8H. [NMea^l.]
kAXlO* at 25*^=3.75.
A(32)=36.6, (512) = 124.2, (cd)«353; 492.
Dimethyl-anthranilic add see o-Dimethyl-aminobenzoic add.
Dimethyl-arsinic add see Cacodylic add.
6,5-Dimethyl-barbituric add. C6H8O8N2.
kxXlO^ at 25*^=7.3.
m(64)=0.9; 1996.
2,4-Dimethyl-benzoic acid. (l,3-Dimethyl-4-benzoic acid. m-Xylic
acid). C9Hio02=Me2.C6Hs.C02H. [C02H=1; Me=2, 4.]
kxXlO^ at 25**=9; diminishes on diln.
A(1024) = 91.9, (2048) = 119.5, (00) = 352; 1418.
2,5-Dimethyl-benzoic add. (l,4-Dimethyl-2-benzoic acid. p-Xylic
acid). CftHioOa. [C02H=1; Me=2, 5.]
kxXlO^ at 25**= 1.2; increases on diln.
A(512) = 75.6, (1024) = 102.7, (co)=352; 1418.
Dim] TABLES 185
3,6-Dimethyl-beiizoic add. (ly3-Dimethyl-5-benzoic acid. Mesi-
tylenic acid) . C9H10O2. [CQ2H = 1 ; Me = 3, 6. ]
kAXlO* at 25°=4.8; 176.=7.3; 1418. [These, apparently, are
measurements of different acids. ]
A(835.6)=65.4, (1671.2) =87.0, (oo)=354; 176. A(2048) = 112.3,
(00) = 352; 1418.
Dimethyl-benzyl amine. CgHi3N»PhCH2.NMQ8.
kBXl0^at25°=1.05.
A(36.1)=3.7, (578.2) = 16.2, (oo) = l96; 664.
Dimethyl-benzylsuccinic add.
Ci8Hi604=C02H.CMe2.CH(PhCH2).C02H.
kAXlO^ at 25°=4.56; m. p. 139**; 189, 1838.=0.69; m. p. 128°-
130°; methylbenzylglutaric acid?; 201.
m(64) = 55.0, (612) = 133.1, (oo)«350; 1838.
aS-Dimethyl-butane-a/Sd-tricarbozylic add.
C9Hi406=C02H.CHMe.CH(C02H).CH2.CHMe.C02H.
kxXlO^ at 25**= 1.6; increases on diln.; m. p. 107°.
iu(83.5)=39.1, (668.2) = 100.4; 813.
Dimethyl-/3-tso-butylethylenelactic add.
C9Hi80s=i8o-Bu.CH(OH).CMe2.C02H.
kxXlO^ at 25°=1.47; m. p. 81°; 1034, 1704.
At 25°, /x(35.6)=7.9, (570.2) = 30.2, (00) =349; 1704.
aa-Dimethyl-a'-t50-butylsuccinic add.
CioHi804= C02H.CMe2.CH(iso-Bu).C02H.
kxXlO^ at 25°=4.32; m. p. 143°-144°.
m(273.0) = 101.4, (1092.0) = 171.5; 236.
Dimethyl-coumalic add see uo-Dehydroacetic add.
Dimethyl-cyanuric add see Cyanuric add dimethyl ester. ^
l,3-Dimethyl-cydohexane-3-carbozylic acid. C9H16O2.
kAXlO« [at 25°] =6.30.
A(282.1) = 14.5, (1128.4) =28.4, (oo) = 352; 2026.
d5-l,3-Dimethyl-cyclohexane-6-carbozylic acid. CgHieC^.
kAXltf^ [at 25°]= 1.07; m. p. 65°-65.5°.
A(225.1) = 17.5, (900.4)=34.4, (oo) = 352; 2026.
fr(m5-l,3-Dimethyl-cydohezane-5-carbozylic add. C9H16O2.
kAXlO* [at 25°]= 1.09; m. p. 67°-67.5°.
A(312.2) = 19.5, (1249.2) =39.3, (oo)=352; 2026.
l,2-I>imethyl-cyclopropane-l,2-dicarbozylic acid. (1,2-Dimethyl-
trimethylene-l,2-dicarboxylic acid). C7H10O4.
kA XlO^ at 25°= 9.90; m. p. 149°-150.5°.
m(26.4) = 17.5, (211.4) =48.6, (oo) = 380; 814.
1,3-Dimethyl-desozyzanthine see l,3-Dimethyl-2-ozy-l,6-dihydro-
purine.
186 TABLES [Dim
Dimethyl diethyl ammonium hydroxide. C6Hi70N«Me2EtsN.OH.
B.Cl at 26°, A(32)-93.8, (1024) = 106.9; 270.
Dimethyl-dihydro-resordnol. CgHuOi- CsHuOCOH).
kAXlO« at 26**-7.1 aq.; m. p. 130**-148^
A(64)=7.8, (1024)-30.8, (oo)-374; 1688.
In pyridine; 754.
Dimethyl-tso-dihydro-tetrazine see Dimethyl-amino-tiiazole.
a-Dimethyl-dihydroxy-adipic add.
C8Hi406=C02H.MeC(OH).CH2.CH2.(OH)CMe.CQ2H.
kAXlO^=3.17; m. p. 212°; 2026.
7-Dimethyl-dihydroxy-adipic acid. CgHuOs.
kAXlO*=3.30; m. p. 191°-192°; 2026.
Dimethyl-dihydrozy-glutaric add. C7H12O6- CHs(MeC.0H.C02H)s.
kxXlO* at 26°= 1.8; diminishes on diln.; m. p. 103°-104°.
m(36.2)»80.0. (1159.7) =256.6, (oo)=363; 2018.
Dimethyl-dihydroxy-glutaric lactone. CrHioOs.
kAXlO* at 26° is about 6.6; diminishes on diln. from change of
lactone to acid.
m(41.1)- 134.7, (1316.6) =306.0; 2018.
Dimethyl-dimethylamino-methyl carbinol benzoate. (Methyl sto-
vaine derivative). Ci8Hi902N=PhCO.O.CMe2.CH2.NMe2.
kBXlO^ at 16°= 3.22 (hydro!.); 1779, 1777.
l,8-Dimethyl-2,6-diozy-purine. (1,3-Dimethyl-xanthine. Theophyl-
line). C7H8O2N4.
kAXl0» at 25°= 1.62 (sapon.).
kBXlO^^ at 26°=1.9 (sapon.). At 40.1°=6.6 (sapon.); 1997.
l,7-Dimethyl-2,6-dioxy-purine. (1,7-Dimethyl-xanthine. Paraxan-
thine). C7H8O2N4.
kAXlO* at 26°«2.22 (sapon.).
kBXlO" at 40.1°=3.29 (solub.); 1997.
8,7-Dimethyl-2,6-dioxy-purine. (3,7-Dimethyl-xanthine. Theobro-
mine). C7H8C^N4.
kAXlO^ at 18°= 1.3 aq.; 1391. At 26° =0.011 (sapon.); 1997.
keXlO^* at 18°= 1.5 (hydrol.); 1391; (colorim.); 1776. At
40.1° =4.6 (solub.); 1997. = 16 (catal.); 1996.
At 18°, iu(601.3) = 1.0, (1202.6) = 1.4, (oo) = 336. At 26°, iu(601.3)
= 1.7, (1202.6) = 2.2, (00)= [372]; 1391. — 1241.
In HON, no cond.; 943. In NHs, qual.; 606.
Cond. with NaOH and HCl; 1391.
jS-Dimethyl-ethenyl-tricarboxylic add.
C7H10O6- G02H.CHMe.CMe(C02H)2.
kAXlO' at 26°=6; diminishes, then increases on diln.; m. p.
156°-168°.
iu(32) = 116.6, (1024) = 322, (oo)=362; 1839.
Dim] TABLES 187
Dimefhyl-ethenyl-tricarboxylic add see tso-Butenyltricarboxylic acid.
Dimethyl-efhylacetic acid. C6HuQ2 - CMesEt. CO^H.
kAXlO«at25**=9.57.
A(32) = 6.1, (1024)«33.8, (oo)=362; 180.
Dimethyl-efhyl carbinol. CsHuO » CM02Et.OH. .
Cond. with oxalic acid; 45.
Dimefhyl-efhyl-efhylenelactic add.
C7Hi40,=Et.CH(OH).CMe8.CO|H.
IcaXIO* at 25**= 1.60; m. p. 103**; 1704, 1706.
m(30.2)«7.4, (987.4)=40.0, (oo)-350; 1704.
Dimetfayl-ethylphenyl ammonium hydroxide.
CioHnON^ (Me2)(Et)(Ph)N.0H.
B.Cl at 25^ A(32)=88.4, (1024) = 100.8; 270.
Dimethyl-ethylsucdnic add. C8Hi404» COkH.CMe1.CHEt.CO2H.
kxXlO* at 25**=5.6; m. p. 139**-140^ 189, 198, 236, 1264, 1838.
[Two acids, one of m. p. 62°, k Xl0*=5.7, the other of m. p.
105®, kxl0*=5.9, given in 201, apparently are methyl-
ethyl glutaric acids.]
m(32)=43.7, (1024) « 183.4, (00) =351; 1838.
Dimethyl-fumaranilic add. (Dimethyl-maleinanilic acid).
CuHiiO,N-NH(Ph).CO.CMe:CMe.C02H.
NH4.A, A(28.3) = 120.0, (906.9) -187.7; m. p. 67**-70**; (the acid
hasm. p. 59*^-64**); 1749.
2,4-Dimethyl-furfurane-3-carbozylic add. CrHgOs.
kx X 10* at 25°= 1.1; m. p. 122°.
A(512)=25.5, (1024)-36.0, (oo)=356; 669.
aa'-Dimethyl-glutaconic add.
C7Hio04=C02H.CHMe.CH:CMe.C02H.
kA X 10^ at 25°= 1.29; diminishes on diln.; m. p. 146°-147°.
m(32.5)-22.2, (1040)- 102.5, (oo)=353; 1704.
/um.-jym.-Dimetl^yl-glutaric add. (a a-acid) .
C7Hi204= CH2(CHMe.C02H)2.
kAX 10* at 25°=5.9; m. p. 140°-141°; 69, 60, 63, 1473, 1704.
Second kx X 10*= 1.5 (inversion); 1638.
At 25°, m(207.6)-36.3, (1660.8) =94.4, (oo)-351; 1704.
mal.-sym.-Dimethyl-glutaric add. (p-acid. cw-acid). C7H12O4.
kxXlO* at 25°=5.6; increases on diln.; m. p. 127°~128°; 60,
175, 232, 1473, 1704, 1838, 2018.
Second kx X 10*= 1.6 (inversion); 1638.
At 25°, m(293) = 10.9, (1172)-76.6, (oo)=351; 1704.
jS^-Dimethyl-^utaric add. C7Hi204» CO2H.CH2. CMes.CH2.CO2H.
kxX 10^ at 25°=2.3; 1418.=0.17; 61.
/x(64)=39.9, (oo)-352; m.p. 100°-101°; 1418; - m(64) = 11.3;
61. [The values of i* given in 61 give k=0.17, not 2.2.
188 TABLES [Dim
Note that the melting-point and the value of k correspond
to a methylethyl-succinic acid.]
^ym.-Dimethyl-glutaric acid, (aa-acid, j3-acid and m-acid). C7H12O4.
kAXlO^ at 25°= 5.0-6.5; in some measurements increases, in
others diminishes, on diln.; m. p. 99**-101**, 102*'-104%
105**-106^ 66, 70, 176, 201, 1838, 2018. [This acid was a
mixture of isomers. ]
Dimethyl-glycocoll see Dimethyl-aminoacetic acid.
Dimethyl-glyozime. C4H8O2N2.
In complex compounds; 1751, 1763, 1754, 1766, 1757, 1769,
1760a, 1761.
Dimethyl-hezylethylenelactic add see Dimethyl-hydrozy-pelargonic
acid.
Dimethyl-hydroresorcylic acid methyl ester.
CioHi404= OH.C8HioO.C02Me.
kAXlO'^at25**«4.9aq.
A(28) = 13.4, (896) -69.9, (co) = 372; 1688.
aa'<-Dimethyl-/3-hydrozy-glutaric acid.
C7Hi206= OH.CH(CHMe.C02H)2.
kxX 10^ at 25**= 1.2; m. p. 136**-137; 1473, 1475, 1704.
m(74.6) = 29.9, (1194.2) = 104.9, (00) = 350; 1704.
aa'-Dimethyl-j3-hydrozy-glutaric add acetyl derivative see Dimethyl-
acetozy-glutaric add.
a-Dimethyl-jS-hydroxy-pelargonic acid. (Dimethyl-hexylethylene-
lactic acid). C11H22O8- C6His.CH(OH).CMea.C02H.
kx X 10*^ at 25**= 1.9; diminishes on diln.
m(124.4) = 16.7, (1990.4) =54.2, (oo) = 350; 1704.
a-Dimethyl-laevulinic acid. (Mesitonic acid).
CyHisQs^ Me.CO.CH2.CMe2.CO2H.
kxX 10*^ [at 25**]= 1.08; m. p. 74°-77**; 202.
Dimethyl-maleic add. (Pyrocinchonic acid).
C6H804=C02H.CMe:CMe.C02H.
kx X 10^ at 25° is over 1.08; from cond. of soln. of the anhydride
(m. p. 96**) which apparently polymerizes, giving too low
cond.; 191, 1838.
At 25^ m(64) = 28.3, (1024) = 101.2, (oo) = 354; 1838.
Dimethyl-maleic add anhydride. CeHeOs.
Cond. of aq. soln.; 1838.
Dimethyl-maleinanilic add see Dimethyl-fumaranilic add.
Dimethyl-malonic add. (/S-iso-Pyrotartaric acid).
C6H804=Me2C(C02H)2.
kxXlO* at 18*'=7.6 (colorim.); 1663. At 25**=7.6; m. p. 185°;
1838, 1371.
Dim] TABLES 189
Second kAXl(F»3 (inversion); 1336, 1638.
At 25^ m(32)-51.3, (1024) = 204.4, (oo)-356; 1838.
Dimefhyl-malonic acid mono efhyl ester.
C7Hu04« Me8C(C0|H) (COiEt).
kAX 10^ at 25^»3.12; diminishes, then increases on diln.
m(44.0) =38.9, (1408.0) = 167.5, ( oo ) = 352; 1869.
Dimethyl-2-naphthylamine-8-8ulpho]iic acid.
CuHuQjNS- Me2N.C10Hfl.SQ1H.
kx X 10* is about 2 (colorim.); m. p. 244°; 1773.
Dimethyl-nitrobarbituric add. C6H706Ns-CO(NMe.CO)8C:NOkH.
At 24.5^ A(32)=313.3, (1024)=337.6, (oo)=352; pure acid is
dec^ at 152°, slightly impure is dec. at 132°; 846.
l,3-Dimethyl-2-oxy-l,6-dihydro-purine. (Desoxytheophylline. 1,3-
Dimethyl-desoxyxanthine). C7H10ON4.
kAXlO^* at 26°= 5.61 (sapon.); m. p. 215°-225° (in vac);
1707.
Dimeth3d-parabanic add. C6HflQsN2.
At 25°, A(32)-0.33, (128)=0.49; 1748.
2,6-Dimethyl-pentane-2,6-tetracarbozylic add.
CuHifl08= (C02H)8CMe.(CH2)8.CMe(CQ2H)2.
kx X 10* at 25° =3.7; increases on diln.
/i(17.2)-77.6, (275.0) =240.5, (oo)=350; 1869.
Dimethyl-phenonaphthozazine see Meldola Blue.
2,3-Dimethyl-phenyl-2,6-benzylimmopyrazole see 2,6-Benzylimino-
pyiine.
Dimethyl-p-phenylene diamine. C8H]2N2=Me2N.C)6H4.NH2.
At 25°, A(13) is over 0.19; 741.
Dimethyl-phenyl-ethylenelactic add see Phenylhydrozy-pivalic add.
Dimethyl-phenyl-hydrozy-propiomc add see Phenylhydrozy-pivalic
add.
2,3-Dimethyl-l-phenyl pyrazolone. (Antipyrine). C11H12ON2.
In aq., little or no cond.; 977, 1266. 0.1 normal soln. cond.=
9.02xlO-«; 214.
B.HI at 18°, A(20)=222, (1000) =377; 1266,
3,4-Dimethyl-l-phenyl pyrazolone. CuH]20N2.
In molten state, conducts fairly well.
Cond. in aq. equals that of a 1% NaCl soln.; 977.
2,6-I>imethyl-4-phenylpyridine-3,6-dicarboxylic add see Phenylluti-
dine-dicarboxylic add.
Dimethyl-pimelic add. C»Hi604.
kAXlO* at 25°=3.4; at 25°, iu(128)=22.1, (1024) = 59.4, («) =
350; the acid, m. p. 71°-73° and 74°-76°, of 1412, 1869,
2018, is made up of the following two isomers.
140 TABLES [Dim
untt-oa'-Dimefhyl-pimelic acid. CBHi604»CHs(CH2.CHMe.COkH)8.
kx X 10^ [probably at 25**]=3.43; m. p. 76**-76.6^ 966.
^a-aa'-Dimethyl-pimelic add. C9H16O4.
kAXlO^ [probably at 25**l-3.44; m. p. 8r-81.6^; 966.
Dimethyl-a-propionyl thetine. C5HuQsS-OH.SMes.CHMe.CQ2H.
ki X 10" at 26** -2.1 (hydro!.); 860 and 1160.
At 25^ m(32)-4.1, (256) =6.9.
B.Br. - B.Cl, m(32)-93, (1024)- 103; M(32) -275.6; 360.
Dimethyl-^-propionyl thetine. C6H12QsS-QH.SMes.CH2.CH2.CQ2H.
kaX 10" at 25**- 1.2 (hydroL); 360 and 1160.
B.Br, /x(32)-95, (1024)-105; M(32)-123.8; 360.
a-Dimethyl-/3-£so-propyl-ethylenelactic acid.
CsHieQs- Me2CH.CH(QH).CMe2CQ2H.
kA X 10* at 25**- 2.2; increases on diln.; m. p. 92**.
/x(34.8)=9.5, (11 19.7) -51.2, (oo)-350; 1704.
Dimethyl-propylsucdmc acid. C9Hi6Q4»CQ2H.CMes.CHPr.CQ2H.
kxXlO^ at 25**-6.0; m. p. 145**; 236.-5.5; m. p. 140**-141.5**;
189, 1838. The acids, m. p. 101** and 51^ k=5xl0-^ in
201 are, apparently, Methylpropyl glutaric acids.
At 25^ m(108.5)-78.7, (868.0)- 176.5; 236. /i(64)=59.8, (1024)
-183, (00) -350; 1838.
oa-Dimethyl-a'-tso-propylsuccimc add. C8HmQ4.
kx X 10^ at 25**- 1.58; diminishes on diln. m(06.1)-35.7, (528.8)
-85.1, (00)= [351]; m. p. 141M42**; 236.
N-3-Dimethyl pyrazole. CsHgNs.
kaX 10" [probably at 25**]-1.3 (solub.); b. p. 148^ 428.
3,6-Dimethyl pyrazole. C6H8N2.
kB X W^ [probably at 25**]-2.5 (solub.); m. p. 107**; 428.
2,6-Dimethyl-pyridine. (2,6- or aa-Lutidine). C7HBN-Me2.C5HsN.
kBXl0^at25**-l.
M32)=0.4, (256) = 1.2; 1293.
In SQ2; 1842.
B.HCl at 25% A(50)-92.2. - B.H2SQ4; 1864. - B.MeCl; 270.
Dimethyl-pyridine. CyHgN.
B.HCl at 25% A(64)-95.5, (256)- 102.5; 270.
2,6-Dimethyl-pyridine-3,6-dicarbozylic add. (aa'-acid. Lutidine-
dicarboxylic acid). C9H»Q4N-Me2.C6NH(CQ2H)2.
kx X lO' at 25^-3.7; increases on diln.
m(128)-168.5, (1024)-288.5, (oo)=352; 1372.
2,4-Dimethyl-pyridine-3,6-dicarbozylic add. (a7-acid). C9H9Q4N.
kx X lO' at 25**- 5.5; diminishes on diln.
/x(128) - 197, (1024) - 296, ( 00 ) = 352; 1372.
2,6-Dimethyl-pyrone. C7H8Q2.
kA X 10" at 26**- 8 (hydrol.).
Dim] TABLES 141
kBXlO" at 0*^=3 (hydro!.); 1827;=0.3 (corrected); 1160. At
25*'-2 (hydrol.) 1827;-0.8 (corrected); 1160. At 40.2*'=.
6.5 (catal.); 1996.
Cond. at 25^ m(32)=0.10, (612)-0.36, (oo)-202; 1827.
In HBr and HCl; 123da. In H2SO4; 760, 167a. In AsCb; 1842.
In SOi; 1827, 1842. In acetonitrUe; 1827. In EtBr; 1436.
In hydrazine hydrate; 1828.
Cond. with HCl and H,S04; 741. With NaOH; 1827. With
tribromo-acetic acid; 1436, 1827. With trichloro-acetic
acid; 1436. With picric acid; 1827. With potassium tri-
chloro-acetate; 1439.
Na.A; 1827. - B.HCl at 25^ A(32)=369; 738, 401. - B.H1SO4;
741. - B.Oxalate; 401.
Dimetfayl-pyrone carboxylic acid. CsHsOi.
kA X 10^=3.85; m. p. QS.S^'-QQ*'.
m(43.2)-43.2, (346.0) » 104.2; 667.
2,4-Dimethyl-pyrrole-3-carboxylic add. (m-Dimethyl-/3-acid).
C7H9O1N.
kx X Ifl' at 25*^-7.5 aq.; m. p. 186^
m(228.8)=4.6, (915.2)-9.3, (oo)=356; 23.
2,4-Dimethyl-pyrrole-6-carboxylic add. (m-Dimethyl-a-acid).
C7H9O2N.
kxX 10^ at 25^»2.15 aq.; diminishes on diln.; m. p. 137^
m(790) = 14.3, (1580) = 17.0, (oo)=366; 23.
2,6-I>imethyl-pyrrole-3-carboxylic add. (p-Dimethyl-/3-acid).
CtH^OiN.
kAXlO* at 25**«1.1 aq.; m. p. 213^
/x(307.5)-6.6, (1230.0)-13, (oo)=356; 23.
2,4-Dimefhyl-pyrrole-3,6-dicarboxylic add. (m-acid). C8H9O4N.
kA X 10^ at 25''«2.13 aq.; diminishes on diln.; m. p. 260'' dec.
m(1320) = 64.2, (2640=73, (oo)«355; 23.
2,6-Dimethyl-pyrrole-3,4-dicarboxylic add. (p-acid). C8H9O4N.
At 25°, m(1316) =323.6, (oo)=356; m. p. 251**; 23.
5ym.-an/i-Dimethyl-8ucdnic add. (c»- or maleinoid).
CeHio04- COiH.CHMe.CHMe.COiH.
kAXlO* at 25**= 1.38; diminishes on diln.; m. p. 120M21**;
280. = 1.23; 200, 234, 1838, 2018.
Second kxX 10^=5.3 (inversion); 1638.
At 25^ m(56.6)=30.0, (904.8) = 104.4, (oo)=364; 280.
^ym.-an/f-Dimetfayl-sucdnic add mono methyl ester.
C7Htt04= CQ2H.CHMe.CHMe.C02Me.
kA X 10» at 26*^-4.5; m. p. 38^
m(22)-11.1, (175.8)=29.8, (oo)-352; 244.
142 TABLES [Dim
sym.-p-Dimethyl-sucdnic add. (trana" or fumaroid)«
CeHioOi" CO1H.HCMe.MeCH.CQ2H.
lux 10^ at 25''»2.08; diminishes on diln.; m. p. IQd''; 280.
»1.91; 1838, 176, 200, 234, 1418, 2018.
Second kxX 10*=1.3 (inversion); 1638.
At 26^ m(100)=47.7, (800)-117.6, (oo)-354; 280.
In Me ale. ; 2029.
jym.-p-Dimethyl-succinic add mono methyl ester. C7H12O4.
kxX 10^ at 25^=6; increases on diln.
m(34.5) = 16.5, (275.8) =42.8, (oo)=352; m. p. 49**; 244.
asym.-Dimethyl-sucdnic add. C6Hio04» CO2H.CMe2.CH2.CQ2H.
kAX 10^ at 25^== 8.0; increases, then diminishes on diln.; m. p.
UO"*; 61, 175, 201, 234, 1418, 1838.
m(32)-17.3, (612) = 63.6, (co)=353; 1838.
asym.-Dimethyl-sucdmc add a-mono methyl ester.
C7Hi204= CO2H.CMe2.CH8.CO2.Me.
kxX 10^ at 26**= 2.28; increases on diln.; m. p. 62^
m(25.2)=8.3, (201.4) =23.2, (00) =352; 244.
as|^.-Dimethyl-succimc add /3-mono methyl ester.
C7Hi204= CO2Me.CMe2.CH2.CO2H.
kxX 10* at 26**=2.66; increases on diln.; m. p. 40.6°.
m(27.6)=9.1, (220.8) = 25.8, (oo)=362; 244.
Dimethyl sulphide. (Methyl sulphide). C2H6S=Me2S.
XX 108 at 25** is less than I; b. p. 36**-36.5**; 1843, 1844.
As solvent; (1844).
B.HNOs, A(32)=391. - B.Br2; 760.
Dimethyl thetine. C4Hio08S= OH.SMe2.CH2.CO2H.
kB X 10" at 25*^=1.9 (hydroL); 360 and 1160.
At 25^ A(32)=2.2, (256)=2.1.
B.Cl, A(32) = 103, (1024) = 115; M(32)=277.7. - B.Br; 360.
Dimethyl thetine ethyl ester. CoHuOsS = 0H.SMe2.CHs.C0kEt.
At 25^ A(32)=2.7, (256) = 3.1, (512)=7.4.
B.Br, A(32)=91.6, (1024) -103.9; 360.
Dimethyl-thiazole. CsHtNS.
B.HCl at 25^ A(50) = 121.4. - B.H2SO4; 1864.
2,4-Dimethyl-thiazole-6-carbozylic add. (meso-Methylthiazole-a-
methyl-/3-carboxylic acid). CcHyQiNS.
kx X 10* at 25*'= 1.25; increases on diln.
A(263.2)=55.7, (1052.8) = 106.4, (00) =357; 176.
Dimethyl-o-toluidine. C9HuN=Me.C6H4.NMe2. [Me=l; NMei"2.]
kaX 10» at 15**= 3.08 (colorim.); 1777.
B.Picrate in benzene, no cond.; 1802.
Dimethyl-m-toluidine. C»HuN.
kaX 10» at 25*^=2.4 (solub.); 660, 967.
Din] TABLES 148
Dimethyl-p-toluidine. C»HuN.
kBX 10» at 15**=6.36 (colorim.); 1777.
Dimethyl-triazole. C4H7N8.
kaX 10^* [probably at 25°]-6.2 (sapon.); m. p. 142*^; 428.
oa-Dimethyl-tricarbaUylic add.
CsHuOe- CO|H.CMe2.CH(CQ2H).CH,.CQ2H.
kA X 10^ at 25'' « 3.2; diminishes on diln.
/i(23.7)-29.2, (189.4)=76.1, (00)- [351]; m. p. 143**; 287.
oa-Dimethyl-tricarballylic add a?-mono methyl ester.
C»Hi406=CO|H.CMe2.CH(C02H).CH,.CQ2Me.
kA X 10^ at 25^= 1.8; diminishes on diln.
m(31.2)-25.3, (249.6)=66.9, (00)= [351]; 287.
aa-Dimetfayl-tricarbaUylic add ?-mono methyl ester. CvHuOt.
k^X 10^ at 25*'»8.6; diminishes on diln.
m(35.8) = 18.9, (71.6)=26.3, («)=[351]; 287.
oa'-Dimethyl-tricarballylic add.
C8Hi206-MeCH(CQ2H).CH.CO|H.CHMe(CQiH).
a) acid. (a7-acid.) .
kAXlO* at 25^=4.45; m. p. 206°-207*'; 287, 2017.
m(33.7)=40.2, (269.7) -101.7, (oo)=[351]; 287.
b) add. (a7-add).
kA X 10^ at 25**=5.4; m. p. 174**; 287, 2017.
/i(20.7)=35.0, (165.6) =90.6, (»)=[351]; 287.
c) add. (a7-add).
kAX 10^ at 25*^=5.72; diminishes on diln.; m. p. 143**; 287.-6.1;
m. p. 148**-149**; 2017.
m(21.8)-37, (174.2)=94.3, (oo)-[351]; 287.
Dimethyl-trimethylene-dicarboxylic add see Dimethyl-cydopropane-
dicarboxylic add.
o-Dimethyl-uradl. C6H8O2N2. [Me- 2, 3.]
kAXlO^i at 25°=8.8 (catal.); m. p. 220**-230**; 1996.
/3-Dimethyl-uradl. C6H8Q2N2. [Me- 3, 6.]
kAX 10" at 25**«7.4 (catal.); m. p. 258*^; 1996.
Dfanetiiyl-violuric add. CeH704N8-CO(NMe.CO)2C:NOH.
kAX 10* at 26**= 1.57.
/i(32)-7.9, (512)-29.9, (oo)-352; 1188.
In pyridine; 754.
K.A at 25% A(40)-82.5, (1280)=96.3; 1188.
Dinicotmic add see Pyiidine-8,&-dicarbozylic acid.
2,4-Dinitro-aiiiline. C6H504N8-(NQ2)2.C6Hs.NH2. [NH2-I.]
In NHs; 604; qual.; 610. In MeNH2, good cond.; 687.
o-Dinitro-benzene. C6H4O4N2 - (N02)2C6H4.
In NH8; 604.
144 TABLES [Din
m-Dinitro-benzene. C6H4O4N2.
In HBr, good cond.; in HsS, no cond.; 1897. In NHs; 604, 607.
In MeNHs, good cond.; 637. In pyridine, no cond. [m-
Dinitro-benzene-7]; 754.
p-Dinitro-benzene. C6H4O4N2.
In NHe; 604.
2,3-Dinitro-benzoic add.
C7H406N2«(N02)2.C6H,.CQ2H. [COiH-1; N0|-2, 3.]
kx X 10^ at 25''« 1.44. At 40''- 1.38; diminishes, on diln.; m. p.
201** and 204.1^
At26^ A(100)«256, (1600)«348, (oo)-377.
InEtalc; 1627.
2,4-Dinitro-benzoic add. C7H4O6N2.
kAXlO^ at 25''»3.85. At 40''»3.2; diminishes on diln.; m. p.
180.9^
At 25% A(100) = 310.5, (1600) -360.6, (a) = 377.
In Et ale; 1627.
2,5-Dinitro-benzoic add. C7H4O6N2.
kA XlO* at 25*^=2.64. At 40** =2. 16; diminishes on diln.; m. p.
177^
At 25% A(100)-291.6, (1600)=360.5, (oo)=377.
In Et ale. ; 1627.
2,6-Dinitro-benzoic add. C7H4O6N2.
kA XlO* at 25**=8.15. At 40^-7.57; m. p. 202** and 206%
At 25% A(IOO) -339.5, (1600) -369, (00) -377.
InEtalc; 1627.
3,4-Dinitro-benzoic add. C7H40eN2.
kAXlO" at 26**= 1.63. At 40**- 1.71; diminishes on diln.; m. p.
163.3^
At 25% A(100) = 124.6, (1600) = 284.6, (00)= 377.
In Et ale. ; 1627.
3,5-Dinitro-benzoic add. C7H4O6N2.
kAXlO" at 18**-1.6 (colorim.); 1663. At 25**=1.63; diminishes
on diln.; 175, 1627. At 40**- 1.77; diminishes on dihi.; 1627.
At 25% A(200)-162.5, (1600)-292.5, (oo)=377.
InEtalc; 1627.
l,3-Dimtro-4-bromobenzene. C6H304N2Br- (N02)2C6Hj.Br.
In NB[s; 604.
Dinitro-bromomethane. CH04N2Br- Br.CH(N0|)2.
kAXlO*atO**-1.7; 796.
Cond. at 0** and 25**; 780.
K.A at 0% A(64)-68.3, (256) -59.8; 796.
Dinitro-butane. C4H8O4N2 - C4H8(N02)2.
K.A at 25% A(32)=94.6, (1024) -104.5; 796.
Bin] TABLES 145
/3^-Dimtro-caproic add. C6Hio06Ns"Mes.C(CO|H).C(NQ8)aMe. 7
kA XlO^ at 25^ s 6.9; diminishes on diln.
m(128)-90.8, (1024) -195.2, (oo)-360; 1870.
Dimtro-efhane. C8H4O4NS- Me.CH(NOk)s.
kAXlO<^atO''-2.3; 796. At 25''- 5.8; 1092. A weak acid; 780,
795.
At25^ A(32.5)-5.3, (130)-10.2, (oo)-388; 1092.
KA at 25% A(32)- 101.7, (512)- 111.0. With HCl; 796, 1092.
Dinitro-ethane alcoholate. (Dinitro-ethane ethyl ester acid).
C4Hio06N2=MeCH(NO|).NO(OH)(OEt).
kAXl0^at25**-1.7.
A(128)-49.6, (1024) = 122.1, (oo)-356.4.
KA at 25% A(32)-86.4, (1024)- 101.3; 772.
2,6-Diiiitro-hydroquiiione. (2,6-Dimtro-l,4-dihydroxy-benzene).
C6H40eN2- (NQ2)2C«H2(OH)2.
kAXlO* at 25*^-7.1.
m(200)«40.1, (1600)- 105.3, (oo)-353; 70.
Dinitro-methane. CH2O4N2 - (N02)2CH2.
kAXlO^ at 0**-1.4. At 25*^=2.8; diminishes on dUn.; 780, 796.
At 25% A(64)-46.8, (512)- 110.6, (a))=369; 780. Qual.; 795.
K.AatO% A(64)-61.9, (256)-64.9; 796.
2,4-Di]iitro-l-iiaphthol-7-8ulphomc acid.
CioH608N,S-CioH4(NO|)20H.SOaH.
[2K.A or 2Na.A is the dye Naphthol Yellow S.]
At 18% m(100)-416, (1600)-600; 976a. At 25% A(100)-245,
(800)-332.9; 1402. At 90% m(100)-753.9, (800)-1019.2;
976a.
Ca.A; 976a.- Mg.A. - 2NaA at 25% A(100)-96.4, (1600)-
110.1; 1402, 1401. With Methylene Blue, qual.; 1401.
Dinitro-oxybenzo furazane. C6H2O6N4.
A(64)-341.7, (512)-361; m. p. 138** with dec; 1426.
2,3-Dinitro-phenol. (eDinitro-phenol) .
C6H406N,-(N02)2C6H,.OH. [OH-1; N0,-2, 3.1
kAXlO* at 25^-1.3; 70, 847.
/i(256)-19.9, (1024)«40.0, (oo)-354; 847.
2,4-Dimtro-phenol. (a-Dinitro-). C6H4O5N2.
kAXlO^ at 25*^-1; m. p. 113**; 847; 70, 1362.
m(256)-51.7, (1024)-99.9, (oo)=354; 847.
In NHs, qual.; 606. In pyridine. In piperidine; 764. In Et
ale; 1608, 1718.
Cond. with NaOH; 1608. 1718.
2,5-Dinitrol-phenoL (7-Dinitro-). C6H4O6N2.
kAXlO* at 25^-7.0; 70, 847.
m(256)-14.4, (1024)-29.9, (oo).354; 847.
146 TABLES [Din
2,6-Diiiitro-ph6nol. (j3-Dinitro-). C6H4O5N2.
kAXlO* at 25^-2.7; m.p. 64**; 847.=1.7; 70.
m(266)-78.6, (1024)-145.1, (oo)-354; 847.
8,4-Dimtro-phenol. (S-Dinitro-). G6H4O6N2.
IcaXIO* at 25*^-4.3; m. p. 134^ 847, 70.
/i(256) = 11.4, (1024) -22.6, (a))«354; 847.
8,5-Dmitro-phenol. (0-Dinitro-). C6H4O5N2.
kA X 10^ at 26*'=2.1; m. p. 124^
m(100)-1.6, (400) » 3.2, (00) -354; 847.
2,6-Diiiitro-phenol-4-sulphonic acid. O6H4O8N2S. [S08H-4.]
K.A, cond. alone and with NaOH; 1718.
Dinitro-propane. C8H6O4N2.
K.A at 25^ A(64)- 101.3, (512) = 107.5; 796.
Di-fso-nitroso-butyric add see Diozimino-butyric add.
l,2-Dimtroso-3,5-dinitro-benzene. O6H2O6N4- (NO)2C6H2(NOk)2.
kAXlO^=l.l; m.p. 172^ m(2000) = 142, (4000)-172, (oo)-384.
KA, iu(128)=96, (1024) = 109.6; 1426.
2,4-Diiiitro-toluene. C7H6O4N2.
In NHs, qual.; 606.
Dinitro-toluene nitroic add see Trinitro-toluene.
3,6-Dinitro-2,4,6-tribromo-phenol.
CeHOfiNjBr," (N02)2C6Brs.OH.
K.A, yeUow salt, at 25% A(32)- 112.7, (1024)- 125.0. The
orange and red salts were also measured. There is little
difference between them and the yellow salt; 744.
sifn-Diozimino-butyric add. (Di^o-nitroso-butyric add. Methyl-
synglyoxime carboxylic acid).
C4H604N2-MeC(N.OH).(OH.N)C.C02H.
kA XlO^ at 25^=1.4; increases on diln.
m(32) = 172.1, (256)-308.7, (oo)-358; 768.
am^/^-Dioziimno-butyric add. (Di-4«o-nitroso-butyric acid. Methyl-
amphiglyoxime carboxylic acid).
C4H604N2-MeC(N.OH).C(N.OH).C02H.
kAXlO* at 25**«2; [an extrapolated value.]
Na.A, m(1024-32)-10; 768.
Diozimino-propioiiic add. LabUe. (amp^t-Glyoxime carboxylic acid).
C8H404N2-HC(OH.N).(OH.N)C.CO|H.
kAXlO" at 25^-4.17; m. p. 140**-141^
m(32)- 109.2, (512)-264.9, (oo)=358; 768.
Dioziinino-propioilic add. Stabile. (an<t-Glyoxime carboxylic acid).
C«H404N2-HC(OH.N).(N.OH)C.CO|H.
kAXlO* at 25°-2.85; diminishes on diln.; m. p. 171^
m(32)-93.1, (512)=242.2, (oo)-358; 768.
Dip] TABLES 147
aa-Dioximino-sacdnic acid. (anti-Glyoxime dicarboxylio acid).
C4H406N,=C04H.C(OH.N).(N.OH)C.CQ8H.
kAXlO^ at 25**»1; increases on diln.
/i(32) = 157.4, (256)-293.7, (oo)=358; 768.
/3/3-Dioziiiiino-sucdnic acid. (syn-Glyoxime dicarboxylic acid).
C4H40*N,=C04H.C(N.OH).(OH.N)C.CO»H.
JcaXIO* at 25^=6 (?).
/i(32)= 287.4, (256) =495. 4, (oo)«358; 768.
2,6-Diozy-piirine see Xanthine.
Diozy-thiazole see Diketo-tetrahydro-fhiazole.
Dipentene. CioHie.
Dipentene.2HBr, in SQs; 1829. - Dipentene.2HI, in SQs; 1829,
1842.
Diphenic add* (Diphenyl-dicarboxylic acid).
Ci4Hio04= CQ2H.C0H4.C0H4.CQ2H.
kx XlO^ at 25^ is about 5; inaccurate, because of impurity of aq.
used for soln.
/i(128)=79.2, (1024)-178.0, (oo)-[356]; [in Hg.U.J; 1862.
Diphenyl. CuHio^ Ph.Ph.
In NHsi qual.; 606. In acetonitrile, no cond.; 986. In MeNHs,
no cond.; 637.
Diphenyl amine. CuHuN - Ph2NH.
In HBr, good cond.; in H2S, no cond.; 1897. In HCN, very
small cond.; 943. In HsS04; 760. In SO^; 1842. In
acetonitrile and in benzonitrile, no cond.; 936.
Diphenyl-p-anisyl carbinol. C20H18O2.
Comparative strength (colorim.); m. p. 68*'-61®; 74.
ly2-Diphenyl-8-ben27l-hydrozy-afflidine. (Phenylbenzyl - etc.).
C2oHi80N2=PhC(:NPh).N(C7H7).OH.
B.HCl at 25^ M(128) = 116.6, (512) = 148.0; A(128)=86; m. p.
194"^; (the base has m. p. 150''); 1088.
Diphenyt-bromomethane. CuHuBr.
In SQs; 669.
Diphenyl-crotonic add. (jS-Benzylcinnamic acid).
Ci8Hi4Q2= PhCH2.PhC : CH.CQ2H.
kx XlO^ at 25''»8; diminishes on dihi.
A(512)«68.2, (1024)=89.8, (oo)=371; m. p. 130M31**; 867,
1068.
Diphenyl-cydobutadiSne-dicarbozylic add see Phenylnaphthalene-
dicarbozylic add.
Diphenyl-dicarbozylic add see Diphenic add.
Diphenyl-dichloro-methane. (Benzophenone chloride).
CiaHioCl8=Ph2CCl,.
In SQ2; b. p. ISe'' @ 26 mm; 669, 1676.
148 TABLES pip
NjN'-Diphenyl-endaiiilodihydro triazole. (Nitron). CS0H16N4.
B.Benzyl chloride. - B.Mel at 25^ A(272)=85; m. p. 213^; 314.
Diplienyiene-glycollic acid. (9-Fluorenol-9-carboxylio acid).
CuHioQa- CuHsCOH) (CO4H).
kAXlO* [at 25^1=1.0.
m(128.5) = 104.8, (1028)=217.5, (oo)-[356]; 1184.
Diplienyl-glutaric add. (sym.-acid). Ci7HM04"»CHs(CHPh.CQsH)s.
kx XlO* at 25°= 1.48; m. p. 164°.
m(319.6)=67.3, (1278.4) = 120.5, («>)=346; 2018.
Diplienyl-glycoUic acid see Benzilic add.
Diplienyi iodonium liydrozide. CisHuOI = PhsI.OH.
At 25°, A(32) = 186.2, (128)- 191.2.
B.Clat25°, A(32)=81.9, (1024)=92.9; 1687. In NHs; 604. - B.I
in NHs, qual.; 606. - B.NOj; 1687.
Diplienyl-ketozime see Benzoplienone ozime.
sym.-Diphenyl-sucdmc add. (a- or anti-acid).
CieHi404=CQ2H.CHPli.CHPh.CQ2H.
kxXlO* at 25°=2.6; increases on diln.; m. p. 183° and 220°.
m(92)=49.6, (736)-127.1, (oa)=350; 183fi.
/9-(^a)Diphenyl-succimc add. (jS-Bibenzyldicarboxylic acid).
» C16H14O4.
kAXl0^at25°=2; extrapolated; m. p. 229°.
m(2250) = 177.3, (4500) =220.8, (oo)=350; 1838.
Diphenyl-tfaio urea see Thiocarbanilide.
Diphenyl-toiylamidine see Phenyi-tolylbenzenylamidine.
l,2-Dipheiiyl-3-p-tolyl-hydrozy-a]nidhie.
C2oHi80N2= PhC( : NPh).N(0H).CeH4Me.
B.HCl at 25°, A(512) = 144.5, (1024) = 171.5; m. p. 186°; 1093.
/37-Diphenyl-vinylacetic add. CwHmQj" PhCH : CPh.CHj.COjH.
kxXlO^ at 25°=6.6; diminishes on diln.; m. p. 172°-173°.
A(512)=152.4, (1024) = 181.6, (a>)=371; 667, 1068.
Dipiperonal-acetone. C19H14O6.
Comparative strength (colorim.); m. p. 87° [? a typographical
error for 187°]; 1663.
Dipiperonal-cyciopentanone. CuHuOs.
Comparative strength (colorim.); m. p. 252°; 1663.
Dipropyi-amine. CeHisN = Pr2NH.
kB X 10* at 25°= 1.02 aq.; about 16% too high.
A(32)=33.1, (256)-77.6, (oo) = 197; 271.
In NHs, qual.; 606.
B.HCl at 25°, A(32)=86.1, (1024)=97.9; 270.
Di-iso-propyi-amine. CeH^N.
In Me ale. at 25°, A(31.8)=2.3, (254.1) = 12.0; b. p. 84° @ 757 mm.
B.Hydrate in Me ale; 336.
Dip] TABLES 149
Dipropyl-aniline. C12H19N « Ph. NPi^.
kB X 10^^ at 25^ is at least 3 (solub.); too insol. to get a constant;
660, 957.
Di-tso-propylene-sacdnic acid.
CioHi404=C04H.C(:CMe2).C(:CMei).C02H.
kx X 10^» 1.4; diminishes on diln.
M128)=49.8, (1024)=111.9, (oo)=399.3; m. p. 231%- MO.
Di-tso-propyl-glycollic acid. (Di-^MO-propyl-oxalic acid).
C8HMQ8-i«o-Pi^.C(OH).CQ2H.
kx X 10* at 25**- 1.27; diminishes on diln.; m. p. 111°.
/i(32.5) = 22.0, (1040) -106.2, (oo)=350; 1704.
Dipropyl-malonic acid. CftHisOi- Pr2C(CQ2H)s.
kxX 10> at 18°»1.2 (colorim.); 1663. At 25*'»1.12; diminishes
on diki.; m. p. Ide""; 1638, 1667.
Second kx X 10^=5 (inversion); 1638.
At 25^ m(64)- 196.2, (1024) =320.0, (oo)=350; 1638.
Di-iso-propyl-ozalic acid see Di-iso-propyl-glycollic add.
2,6-Dipropyl-pimeUc add. CuH2404» CH2(CH2.CHPr.C02H)s.
kxX 10* at 25°-3.0; m. p. 95*'-96°; 1412, 1869.
/i(1114.0)-60.5, (2228.0) =81.9, (oo)-350; 1859.
2,6-Di-iso-propyl-pimelic add. C]sHa404.
kx X 10* at 25^=3.2; m. p. 96*'-98°; 1412, 1859.
m(237.0) = 29.2, (948.0) =56.0, («>)=350; 1859.
cis-jym.-Dipropyl-succimc add. C10Hi8O4-CQsH.CHPr.CHPr.CQsH.
kxX 10* at 25*^=4.9; diminishes on diln.; m. p. 119M21°.
/i(128)=77.4, (1024)=173.5, (oa)=[351]; 235.
6raii5-iym.-Dipropyl-sucdnic add. C10H18O4.
kx X 10* at 25*^=2.5; diminishes on diln.
/i(256)=78.8, (1024) = 144.4, (®)=[3511; m. p. 182M83°;
235.
ds-iym.-Di-tso-propyl-sttcdmc add.
CioHi804= CO8H.CH-480-Pr.CH-Mo-Pr.CQ2H.
kxXlO* at 25°=2.4; diminishes on dUn.; m. p. 171**; 235.=at
least 3.0; diminishes on diln; m. p. 180"^, (varies with
manner of heating) ; 61, 1418.
/i(128) = 146.8, (1024)=262.4, (oo)=[351]; 235.
cts-sym.-I>i-isa-propyl-8ucdnic add mono methyl ester.
C11H20O4- CO2H. (CH-i8o-Pr)2.C04Me.
kx X 10* at 25*'=1.15; increases on diln.
m(238) = 52.9, (952) =98.3, («)=[350]; 235.
lrans-iym.-Di-tso-propyl-8uccinic acid. C10H18O4.
kx X 10* at 26^=1.08; m. p. 226°.
M(256) = 5a7, (1024) = 98.9, (»)=[351]; 236.
160 TABLES [Dip
^aiM-iym.-Di-i«o-propyl-8ucciiiic acid mono methyl ester. CUH20O4.
kA X 10<^ at 25''»6.4; diminishes on diln.
m(380) = 60.4, (1520)=91.4, («)-[350]; 235.
a7-Di-iso-prop7l-tricarballylic add.
Ci2H2o06=C02H.CH-Mo-Pr.CH(CQ2H).CH-Mo-Pr.C02H.
kA X IV at 25°- 1.93; m. p. 173^
m(171.5) = 161.6, (1372.0) -270.7, (oo)=[3511; 287.
a7-Di-iso-propyl-tricarballylic acid. C12H20O6.
kAX 10» at 25*^=1.63; increases on diln.; m. p. 156^
/i(95.9)- 113.7, (767.2) =230.0, («>)-[361]; 287.
3,2'-Dipyridyl-3'-carbozyUc acid. CuH8O8N2-C6H4N.C6H8N.CO2H.
kA X 10^ at 25^-2; increases on diln.
m(64) = 10.2, (1024)=46.8, (oo)=350; 1872.
8,2'-Dipyridyl-2,8'-dicarbozylic acid.
Ci2H804N2= CO2H.C6H8N.C6H8N.CO4H.
kA X 10^ at 25^-3.2; increases, then diminishes on diln.
m(128)=63.1, (1024) = 150.9, («>)=350; 1872.
Distyiyl-dichloro-methane see Didnnamenyl-dicbloro-methane.
Ditfaio-carbamine glycoUic acid. C8H602NS2»NH2CS.CHSH.CQ2H.
kAXlO^ is about 5 (catal., and cond.); unstable in aq.; m. p.
136°-137^
m(32)=46.0, (512) = 142.2, (oo)=382; 854.
Ditfaio-carbamine glycollic acid anhydride see Rhodaiiin.
Ditfaio-carbondiglycollic acid. (Carbonyldi-thioglycoUic acid. Dithi-
olcarboxyacetic acid). C6H6O6S2- (C02H.CHSH)2: CO.
kA X 10* [at 25°]= 1.56; increases on diln.
m(32.2)=75.5, (1085)=301.1, (oo)=378; m. p. 156°; 858.
Ditfaio-diglycollic acid see Di-tfaioglycollic acid.
a-Ditfaio-dilactylic acid. C8Hio04S2=C02H.CHMe.S2.CHMe.C02H.
kAXl0^at25°=9.
m(32)=55.2, (1024)=216.8, («>)=356; 1188.
/3-Ditfaio-dilactyUc acid. C«Hio04S2 - CO2H. (CH2)2.S2. (CH2)2.C02H.
kA X 10* at 25°= 9; diminishes on diln.
m(256)=52.2, (1024)=91, (oo)=356; 1138.
Di-thioglycollic acid. (Dithio-digly collie acid).
C4H804S2= CQ2H.CH2.S2.CH2.CO2H.
kAX 10* at 25°= 6.8; increases on diln.; 1870.
Second kAX 10^^=5.2 (cond.); 1911.
At 25°, /i(32)=49.3, (1024) =215.6, («>)=358; 1870.
Ditfaiolcarbozyacetic acid see Ditfaio-carbonglycollic acid.
noHiL-Dodecane-dicarbozylic add. Ci4H2604-C02H.(CH2)i2.CQ2H.
Too insol. in aq. to measure; m. p. 123°; 279.
Eth] TABLES 161
Duldtol. CsHMOe- CeH8(OH)6.
In NHs, qual.; 606.
Cond. alone and with boric acid; 1180.
Dur^ecarbozylic acid see 2,S,5,6-Tetramethyl-be]izdc acid.
tso-Durenecarbozylic add see 2,3,4,6-Tetrameth7l-benzoic add.
Duiylic add see 2,4,6-Trimethyi-benzoic add.
tso-Duiylic add see 2,4,6-Trimethyl-benzoic add.
£.
Ecgonine. CftHieOsN.
kB X 10" at 14'* is between 0.2 and 8 (colorim.); 1778.
roc.-Ecgoninic add. CtHuOi^N.
kA X 10* at 25**= 9.5; increases on diln. ; m. p. 93°-04*. A(71.2) =
27.6, (688.9) =84.6, (oa)=375; 1978.
Bdestin. [The references to this are incomplete. ]
Concentration of H ions; 1611b.
Egg albumin see Albumin.
Elder see Sambucus nigra.
Emetine. CsoH4o06Ns. Also given as CS0H44O4N2 and CibHsQsN.
keX 10* at 15^=1.98 (hydrol.); 1779.
Enteric see Intestinal.
Eosin see Tetrabromo-fluorescein.
Epichlorohydxin. CsHsOCl.
X X 108 at 0*^-3.9. At 25^-6.2.
Cond. as solvent of salts of amines; 1844, 1851.
Erica see Erika.
Erika B. A salt of Methylbenzenyl-amino-thio-zylenol-azo-a-naph-
thol-disulphonic add.
C»Hi907NsSjKa=Ci6Hi4NS.N2.CioH4(OH)(SOsK),.
At 18^ /i(400)- 202.0, (1600) =229.1. At 90**, m(400)= 539.6,
(1600) = 590.4. Cond. with KCl ; 976a.
Erythran phosphoric add see Phosphoric add erythran ester.
Erythrite see Erythrol.
Erythrol. (Erythrite). C4Hio04=C4H«(OH)4.
Cond. in aq. soln. is very small; 944, 1181.
In NHs, qual. ; 606.
Cond. with boric acid; 944, 1181.
Erythronitrolic add see Ethylnitrolic add; salts.
Ethenylgiycollic add. (a-Hydroxy-butenoic acid. VinylglycoUic
acid). C4HeQ»=CH2:CH.CHOH.CQ2H.
kxX 10^-5; diminishes on diln.; m. p. 33^ and 40''; 300, 1633.
A(32)=42, (1024)=169.2, («)-360.6; 1633.
Na.A, A(32)-71.4, (1024) =83.7; 1633.
152 TABLES [Eth
Ethenyl-tricarbozyUc add. CsHeOe" CQsH.CH2.CH(CQ2H)2.
kAX 10» at 25°=3.2; m. p. 150^ /i(32)-96.6, (1024)=290, (00) =
354; 1839.
Ether bromide see Ethyl ether.
^thozy-acetic acid. (Ethylglycollic acid. Glycollic acid ethyl ether).
C4H8Q8-EtO.CH2.CO2H.
IeaX 10^ at 25''»2.34; diminishes on diln.; aq. used for soln. was
not pure. A(32)=29.5, (1024) = 134, (oo)=356; 1370.
Na.A at 25^ A(32)=67.2, (1024)=78.6; 1867.
o-Ethozy-benzoic acid. (Ethyl-o-hydroxy-benzoic acid).
CjHioOa- EtO.C6H4.CO2H.
kx X 10* at 25*^=7.2; diminishes on diln.
A(128)=32.1, (512)-60.8, (oo)=352; 1429.
m-Ethozy-benzoic acid. (Ethyl-m-hydroxy-benzoic acid). C9H10O3.
kA X 10* at 25''-9.2; diminishes on diln.
A(512)=68.4, (1024)-92, (oo)=352; 1429.
p-Ethozy-benzoic add. (Ethyl-p-hydroxy-benzoic acid). CgHioOs.
kx X 10* at 25° « 5.1; diminishes on diln.
A(2048)=97.0, (co)-352; 1429.
2-Ethozy-5*chlorobenzoic add. (Chlorosalicylic acid ethyl ether).
CftHjOaCl- EtO.C6H8(Cl).CQ2H.
kx X 10* at 25^-1.33; m. p. 118°.
A(893) = 102.7, (1786) » 135, («>)=351; 404.
Ethozy phosphorus chloride. [C2H60C12P?].
In HCl, good cond.; 1897.
a-Ethozy-propionic add. (Ethyl-lactic acid. Lactic acid ethyl ether).
CsHioOa" MeCH(0Et).C02H.
K.A. - Na.A at 25°, A(32)«64.2, (1024)-75.1; 1367.
3-Ethozy-p-toluic add. (Ethyl-m-homo-o-hydroxy-benzoic acid).
CioHi208-Me.C6H8(OEt).C02H. ICQ2H-4; Me=l.]
kx X 10* at 25°-3.5; diminishes on diln. A(512) =44.3, (1024) -
60.1, (00), 352; m. p. 79.5°; 1429.
Ethylacetoacetic add ethyl ester. C8H]403»MeCO.CHEt.C02Et.
kxX 10" at 25°»9 (sapon.); 666; is about 0.3 (sapon.); 1694.
At 25°, A(256)=0.07; 1823.
a-Ethyl-/9-acetylpropioiiic add. (Ethyl-laevulinic acid).
CrHiaOs- MeCO.CH2.CHEt.CQ2H.
kx X 10* [probably at 25°] =2.93; b. p. 170°-175° @ 45 mm.; 202.
a-Ethyladipic add. C8Hi404» CO2H. (CH2)s.CHEt.C02H.
kx X 10* at 24.2°=4.15; m. p. 48°.
/i(47.2) = 15.1, (755.2) -57.6, (oo)=351; 1240.
Ethyl alcohol. C2H60» Et.OH.
xXltf' at -9°-0.8; 1853a. At 0°« 1.487; 1843, 1844, 1419;=2;
920. - 426, 916, 918, 922, 1472, 1690a, 1661, 1766. At 14.6°;
£01] TABLES 158
787. At 15^ 456, 597, 1419, 1421, 1472. At 16^ 1419.
At IS'^^l; 491;»1.53; 647;»3; 1724; - 362, 366, 391, 478,
783, 956, 986, 1316, 1420, 1421, 1534, 1791, 1800, 1807,
1970. At IQ""; 418, 1021. At 20^»1.11; 1766; - 1590a.
At 24**; 1010. At 25^ is less than 0.2; 1388.-0.75; 1766.-
1.03; 1844; - 18, 347, 656a, 754, 764, 782, 904, 908, 912,
917, 918, 922, 941, 1423a, 1434a, 1569, 1580, 1592, 1649,
1815, 1843, 1849, 1853a, 1884, 1903a, 1971. [So-called
" anhydrous " alcohol carefully prepared has x=2 x 10"" or
less. In 1766 it is stated that it is easy to prepare alcohol of
x»2 X 10^; and that its cond. is less affected by exposure to
air than that of aq. See especially 1766, 1843.] At 30**-
1.12; 1766, 1472; - 1420, 1421. At Bd'^-LBS; 1766. At
45^=6.7; 1434a; 1472. At 50^=1.85 and 4.5; 1766. At 60^;
1472. At 70''; 1800. T not stated; 263, 580, 816, 1098,
1344, 1556, 1620.
Cond. of dil. soln.; 305, 455, 456, 1534, 1582, 1627.
In HBr; 29, 30; good cond.; 1897; no cond.; 147a. In HCl, m;
147a. In HCN, no cond.; 943. In HI, p; 147a. In HsS,
no cond.; 147a. In NHs, qual.; 606. In CI, no cond.; in
CI with HCl, moderate cond.; 887.
Cond. with KOH; 597. With NaOH; 748, 1035, 1724. With
inorg. salts; 34, 580, 597, 748, 904, 905, 906, 912, 916, 918,
920, 922, 941, 1388, 1534, 1582, 1592, 1844, 1994. With
organic compounds; 45, 263, 816, 922, 1021, 1388, 1421,
1423a, 1434a, 1569, 1620, 1724, 1800, 1807, 1844, 1853a,
1903a. - Qual.; 1311. With very small amounts of aq.;
456, 491, 597, 1766, 1843. Effect of radium on cond. ; 2031.
Cond. of thin layer; 301. Under pressure; 1509, 1590a. As
solvent; 16, 18, 20, (34), 75, 82, (90), 325, (327), 334, 344,
(347), 391, 418, 425, 438, 480, 491, 513, 532, (580), 647, 654,
656a, 667, (697), (711), 754, 764, 777, 782, (783), 787, 788,
789, 833, (876), (912), (915), (916), (918), (920), 922, 923,
932, (1015), 1021, 1066, 1071, 1185, (1280), 1298, 1311, 1316,
1321, 1421, 1423a, (1432), 1434a, 1452, 1470, 1508, 1526,
1530, (1534), (1541), 1569, 1579, (1582), 1590a, 1620, 1622,
1627, 1649, (1651), (1653), 1654, (1681), 1718, 1724, 1763,
(1766), 1791, (1794), 1797, 1807, 1815, (1818), 1820, 1844,
1853a, 1884, 1886, 1903a, 1904,. 1970, 1971, (1994), 2029,
(2031). Dielectric constant; 445, 1509. Relative basicity
in organic solvents, (colorim.); 1051.
Na.A; 344, 1452, 1724, 1815. With menthone; 1763.
p-syin.-£thyla]lylsttccimc add.
C9Hi404=CQ2H.CHEt.CH(C8HB).COaH.
154 TABLES [Eth
kA X 10* at 25*^-2.69; diminishes on diln.; m. p. 165^-156^ 1838;
m. p. 163^-166%- 826.
Second kxX 10*" 2.3 (inversion); 1838.
At25%/i(32)=31, (1024) = 135.8, («>)=360; 1838.
meso-sym.-Ethyla]lylsucciiiic add. C9H14O4.
kAX 10* at 25^=3.69; diminishes on dihi.; m. p. 110M15^ 826,
1838.
m(32)=36.7, (512) = 116.3, (oo)»360; 1838.
Ethyl-amine. C2H7N - Et.NH2.
X Xl(F at O"" is about 4; 1612.
ka XlO* at 25^=5.6 aq.; about 16% too high; 271.
At 25% A(32)=27.0, (256)=65.6, (»)=214; 271.
Cond. as solvent of inorg. compounds; 1612.
B.HCl at 25% A(32)- 102.9, (1024) = 114.3; 270. In SQj; 1856.
In NHa; 610. - Complex salts; 1760, 1761, 1767.
Ethylaminosuccinic acid. C6H11O4N = CQ2H.CHNHs.CHEt.CQ2H.
kAXlO*=3.47; m. p. 132°.
m(32)=35.3, (1024)«153.2, (oo).352; 1168.
Ethylaniline. C8HiiN=Ph.NHEt.
kaX 10^® at 19°-4.17 (colorim.); 1777.
In benzene, alone and with picric acid, no cond.; 1802.
B.HCl at 25% A(64)«90.4, (256)=95.1; 270.
Ethylaniline-3-siilphonic add. (Ethyl metanilic acid).
C8H11OsNS-EtNH.C6H4.SQ8H. [EtNH-l; S08H=3.1
kAXlO*=1.59; dec. 294^ A(32)»24.6, (1024) = 116.3, («) =
356.5.
Na.A, A(32)=67.8, (1024)=78.5; 646.
Ethyiaiiiline-4-sulphomc acid. (Ethyl sulphanilic acid). C8H11Q3NS.
kxX 10^=1.25; dec. 258^ A(32)=21.7, (1024) - 107.0, (») =
355.5.
Na.A, A(32)-67.8, (1024) =76.6; 646.
6-Ethylbarbitttric acid. C6H8Q3N2.
kA X 10*^ at 25*^=3.83. m(64)=18.2; 1696.
Ethyl benzene. C8H10.
In NH8, qual.; 606.
o-Ethylbenzoic add. CbHioO^ - Et.C6H4.CQ2H.
kAXlO^ at 25^=1.7. A(256)=66.5, (oo)=354; 1418.
Ethylbenzyl ether. CbHuO.
InNHs, qual.; 606.
Ethylbenzylmalonic add. Ci2Hi404» (PhCH2)(Et)C(CQ2H)2.
kx X 10* at 25'*= 1.46; diminishes on diln.
m(32)=171.6, (1024)=332, (oo)«352; 1838.
meso-Ethylbenzylsuccinic add.
Ci8Hi604=«CQ2H.CHEt.CH(C7H7).C02H.
Etfa] TABLES 166
kAXlO^at 25^ » 4. 14; increases, then diminishes on diln.; m. p.
122''; aOl, 1838.
m(32)=38.0, (512)-126.9, («>)=350; 1838.
^ara-Ethylbenzyisucdnic acid. CuHi604.
kxX 10^ at 25''»2.62; increases, then diminishes on diln.; m. p.
154''; 200, 1838.
/i(64)=42.4, (1024) = 137.4, (oo)=350; 1838.
Ethylbenzyl sulphide. (Benzyl mercaptan ethyl ether).
CgHisS^ CrMT.SEit.
In SO2; 1842.
Ethyl bromide. C2H6Br.
X X 108 at 26'* is less than 2; b. p. 37.4*'-41^ @ 732.4 mm.; 1388,
1437.
In NHs, qua!.; 606.
Compound with AlBrs and AlCk; 1437, 1893.
Cond. as solvent of inorg. and organic compounds; 1388, 1436,
1437.
a-Ethylbromosttcdnic acid. (N acid).
C6H9O4Br-CO2H.CHBr.CHEt.CO2H.
kAX 10» at 25°=4.23; diminishes on diln.; m. p. 114**; 1838.
Second kx X 10^^-3.6; 1911.
At 25% m(32) = 109.0, (1024)=311, (a>)=355; 1838.
jS-Ethylbromosucdnic acid. (H acid).
C6H904Br=CQ2H.CHBr.CHEt.CQ2H.
kxXlO* at 25** =5.41; increases on diln.; m. p. 192°; 1838.
Second kxX 10* =6.4; 1911.
At 25% m(32)= 120.1, (1024) =330, (oo)=355; 1838.
Ethylbrudnium chloride. (Brucine ethochloride).
C26H,i04N2Cl=B.EtCl.
At 25% A(32)=75.3, (1024)=90.7; 270.
Ethyl chloride. C2H5CI.
X of commercial ethyl chloride; 634.
Cond. with HgCl2; 634. With allyl thiocarbimide, no cond.;
1223.
Ethylcrotonic add see a-Methyl-/37-pentenoic acid.
Ethylcyclopentane-carbozylic acid see Ethylpentamethyiene-carbozy-
lic acid.
Ethyl-oA-dithio-carbonglycollic add.
C6H808S2=EtS.CS.CHOH.C02H.
kxX 10» at 25^=2.12; m. p. 77°-78^
M(39.8)=95.5, (627.2) = 257.8, (oo) = 378; 863.
Ethyl-/9A-dithio-carbonglycollic add. (Ethylsulphothiocarbonglycol-
lic acid. Ethylxanthoacetic acid. Ethylxanthogenacetic
acid). CftH808S2«EtO.CS.CHSH.CQ2H.
156 TABLES [Eth
kxX 10* at 25^-6.6 aq.; m. p. 57.5^-58^
M31.8)=-50.6, (1071) -210.1, (oo)«378; 852.
Ethylene acetic acid see Tximethylene-carbozylic add.
Ethylene bromide. (Ethylene dibromide).
C2H4Br2= CHjBr.CHjBr,
X at la^'^S.S X 10-1^ [?]; 1477. At 25^ is less than 2 X 10"«; b. p.
128.5*'-128.7° @ 741.2 mm.; 1388.
In HBr and H2S, no cond.; 1897. In NHs, qual.; 606. In
MeNHs, good cond. ; 637.
Cond. with AgNOs and organic compounds; 1388.
Ethylene chloride. (Dichloro-ethane). C2H4Cl2»CH2Cl.CH2Cl.
As solvent; 840.
Ethylene chlorohydrin see Glycol chlorohydrin.
Ethylene cyanide. (Succinic nitrile). C4H4N2=CN.CH2.CH2.CN.
xXlO* at 25*'=0.165. At 60**= 1.50. At 63**= 1.68. At 72*^=
1.78; b. p. 88^-90° @ 48-52 mm.; 1844, 1843.
In HCN, no cond. ; 943.
Cond. as solvent of NEtil; 1844.
Ethylene diamine. C2H8N2"NH2.CH2.CH2.NH2.
ksXlO^ at 25°»8.5 aq.; about 16% too high; diminishes on
dUn.; 271.
Second ks X lO' at 16** is about 6 (colorim.) ; 1776.
At 25^ A(32)-10.8, (256)-28.1, (a>) = 210; 271.- 1364.
B.HCl at 25^ A(32)-98.3, (1024) = 143.2. - B.2HC1 at 25%
A(32)- 118.6, (1024) = 140.0; 270. In aq. and in Me ale;
2029. - Complex salts; 886, 1416, 1417, 1762, 1766, 1946,
1948, 1949.
Ethylene dibromide see Ethylene bromide.
Ethylene-ethyl amine see Methylenecyclopropane amine.
Ethylene glycol. (Glycol). C2H6Q2=OH.CH2.CH2.0H.
X X 10' at 0''^2.37; 1844. At 25^»3.03; 1844, 1863a.
In H2S, little cond.; 1897. In NHs, qual.; 606.
Cond. with borax; 944. As solvent of NEtJ; 1844, 1863a.
Ethylenehezaphenyl phosphonium chloride.
CS8HWCI2P2- C2H4(PPh,Cl)2.
At25% A(32)=80.4, (1024) -98.0; 270.
Ethylene oxide. C2H4O.
Cond. in aq. soln. very small; 273.
Cond. with HCl, showing change to glycol chlorohydrin; 760.
Cond. with acids, very small; 1867.
Ethylene urea. C8H6ON2.
At 26% /i(32)«0.32, (266)«0.40; 1748.
Ethylethenyltricarboxylic add see Butenyltricarbozylic add.
Eth] TABLES 167
Ethyl ether. (Diethyl ether. Ethyl oxide). C4HioO-Et.O.Et.
X is 80 small that no approximately accurate figures are possible.
It is evidently less than KT^. Attempts have been made to
measure it at temperatures from 0^ to about the critical
point. See; 305, 362, 366, 636, 816, 986, 1010, 1098, 1316,
1344, 1421, 1666, 1696, 1842, 1843. Near critical tempera-
ture; and dielectric constant; 634, 636; qual.; 133.
At25^ A(2) -0.065; 1843.
In HBr; 1646. Qual.; 1897. In HCl; 634, 1646. Qual.; 887,
1897. In HON, no cond.; 943. In HI; 33, 1646. Qual.;
1897. In H2S, no cond.; 1897. In H4SO4; 760. In CI, no
cond.; addition of HCl gives a conducting soln.; 887. In
NHs, qual.; 606.
Cond. with HCl; 634. With inorg. salts; 748. With Et ale;
816, 1421. With Br; 1447. With AlBra; 1445. With
. organic acids; 45. As influenced by radium; 2031. Effect
of Rontgen rays on cond. qual.; 1805. As solvent; 20, 289,
360, 366, (711), 1071, 1421, 1580, 1797.
Relative basicity in organic solvents (colorim.) ; 1061.
Ethyl ether bromide. C4HioOBrs.
Cond.; 1447. [An addition product?]
Ethylfumaiic acid. (Methylmesaconic acid).
CeHgOi^ C08H.CH : CEt.COjH.
kAXlO^ at 26*'=9.4; m. p. 193**-195^; 191, 1823, 1831, 1838.
m(32) = 56.2, (256) = 137, (00) =354; 1823, 1831, 1838.
o-Ethylglutaric acid. C7Hi204-CQ2H.(CH2)2.CHEt.C02H.
IcaXIO* at 24.2^=6.6; m. p. 60°-61°; 1240.=5.9; increases on
diln.; 61, 1418.
m(44.6) = 16.9, (713.6) -63.2, (»)=352; 1240.
Ethylgiycollic acid see Ethozy-acetic acid.
M*Ethyl glyozaline. CsHgNs.
ka X 10* [probably at 25**]= 1.0; m. p. 89^
A(32) = 1.2, (1024) = 7.2, ( 00 )« 222.7.
B.HNQs [probably at 25** 1, A(32)=89.4, (1024) = 102.2; 428.
N-Ethyl glyoxaline. C6H8N2.
kaXlO^ [probably at 25**]= 3; diminishes on diln.; b. p. 206^
A(32)=0.7, (1024)=3.1, (oo) = 222.0.
B.Picrate [probably at 25**], A(128)=61.1, (1024)=69.5; 428.
Ethyl-m-homo-o-hydrozy benzoic acid see Ethozy-p-toluic add.
Ethyl-hydrozy-benzoic acid see Ethozy-benzoic acid.
Ethylidene chloride. (1,1-Dichloro-ethane). C;2H4Cl2"Me.CHCl3.
In NHs, qual. ; 606.
Cond. with Cu oleate; and as solvent; 1669.
158 TABLES [Eth
a-Ethylidenegltttaric add.
C7Hio04=Me.CH:C(CQ2H)CH,.CH«.CQ2H.
kx X 10* at 25*^-3.2; m. p. 162°; 568.
A(32)«11.9, (1024)=60.9, (oo)«[380]; 1291.
2Na.A at 25°, A(32)-82.3, (1024) =98.7; 1291, 568.
a-Ethylidene-/3-methylgitttaric acid see Dicrotonic acid.
Ethylidenepropionic add. (jSy-Pentenoic acid).
CsHsOs^ Me.CH: CH.CH2.CO2H.
kAXlO*^ at 25°«3.6; diminishes on diln. A(32)-12.6, (1024)-
62.5, (00) = 380.
Na.A at 25°, A(1024-32) = 10-11; 571, 564.
Ethylidenesuccinic acid see iso-Sucdnic add.
Ethyl iodide. C2H5I.
XX 108 at 25° is less than 2; b. p. 71°-71.1° @ 747 mm.;
1388.
In HON, no cond.; 943. In NH3, qual.; 606.
Cond. with Et2S in ale; 334. With AgNQs and organic com-
pounds; 1388. WithAlCk; 1893.
£thyl-^seii£fo-isatiii-/3-ozime. (Ethyl isatoxime). C10H10O2N2.
kx X 10^ at 25° is about 2 (sapon.); 752 and 1150.
Ethyl isatoxime see Ethyi-^semfo-isatin ozime.
EthyUtaconic acid. C7Hio04=Et.CH:C(C02H).CH2.C02H.
kAXlO*^ at 25°=3.6; diminishes on diln. A(32) = 12.6, (1024) =
58.9, (oo)=376; m. p. 163°-167° with dec; 571a.
Ethyl-lactic acid see Ethozy-propionic add.
Ethyl-laevulinic acid see Ethyl-acetylpropionic add.
Ethylmaleic acid. (Methylcitraconic acid).
C6H804=C02H.CEt:CH.C02H.
kxXlO* at 25°=2.4; diminishes on diln. /i(32)=86.3, (1024) =
263, (oo)«353; m. p. 100°-101°; 191, 1838. - 1823, 1831.
Ethylmaleinanilic add see Methyldtraconanilic add.
Ethylmalonic add. (a-iso-Pyrotartaric acid).
CBH804=CHEt(C02H)2.
kAXlO» at 18°= 1.3 (colorim.); 1563, 1781. At 25°= 1.27;
diminishes, then increases on diln.; m. p. 110°--112°; 1838,
1371.
Second kxX 10^=5.4 (inversion); 1638, 1335.
At 25°, m(32) = 65.1, (1024)=236, (oo) = 356; 1838.
2Na.A at 25°, A(32) = 78.6, (1024) =95.3; 270.
Ethylmalonic add mono ethyl ester.
C7Hi204= CHEt(CQ2H) (CQ2Et).
kAXl0*at25°=4.0.
/a(33.8)=39.5, (1080.0) = 167.9, (oo)«362; 1859.
Bth] TABLES 159
l-Efhybnenthyl amine. CisHssN^ CioHi9.NHEt.
B.HCl at 25^ A(32)=79.9, (512)=92.2, (1024)-99.1 (?).
- B.HNQs. Also both salts in Me ale; 2029.
Ethyl mercaptan. C2H6S - Et.SH.
H at 25^ is extremely small.
Cond. as solvent of NEtJ; 1844.
Ethyl-mesaconic acid see Ptopylfumaiic acid.
Ethyl metanilic acid see Ethylaniline-3-sulphonic acid.
Ethylmethyl- see Methylethyl-
Ethyl mustard oil see Ethyl thiocarbimide.
Ethyl nitrate see Nitric acid ethyl ester.
Ethylnitrolic acid. (Nitroacetaldehyde oxime. Nitroaldoxime).
C2H4Q8N2- MeC(N02) : N.OH.
kxX 10> at O^'^G; m. p. 82*^; 762, 688, 684, 783.
AtO^ A(32) = 0.1, (oo)=213; 762.
In pyridine; 764.
On account of the small hydrolysis of the sodium salt at v(32),
Hantszch considers this ethylnitrolic acid a pseudo acid,
while the salt-forming acid would be stronger than acetic
acid. The following salts are derived from the isomer giv-
ing colored salts »Erythronitrolic acid.
E.A at 0", A(32)»48.7, (1024) -59.6. No acid potassium salt
exists in aq. soln. - Pyridine. A, exists in aq. soln.; 684.
Ethyl-tso-nitrosoacetone see tso-Nitrosomethylpropyl ketone.
Ethyl oxide see Ethyl ether.
l-Ethylpentamethylene-2-carbozylic acid. (l-Ethylcyclopentane-2-
carboxylic acid). C8H14O2.
kAXlO*^ [at 25*']=1.11. A(64.5) = 9.3, (1032.3) =35.6, (oo)=352;
2026.
a-Ethyl-ajS-pentenoic acid. C:J7Hi202 = MeCH2.CH : CEt.C02H.
kxX 10* at 25*'=2.2; diminishes on diln.; b. p. 120^ @ 12 mm.;
669, 670. A(64)«14,,(1024) = 48.1, (oo)=[376]; 670.
a-Ethyl-/37-pentenoic acid. CtH^Os^ Me.CH : CH.CHEt.CO2H.
kxXlO* at 25'*=3.6; diminishes on diln.; b. p. 116° @ 12 mm.;
669, 670. A(32) = 12.6, (1024)=61.4, (oo)=376; 670.
Ethylphenylethylenelactic acid see Ethylphenylhydrozypropionic acid.
a-Efhyl-/3-phenyl-/3-hydrozy-propionic acid. (a-Ethyl-j3-phenylethyl-
enelactic acid. Ethylphenyllactic acid).
C11H14Q8- PhCH(0H).CHEt(C02H).
kxXlO* at 25*'=3.08; increases, then diminishes on diln.; m. p.
111.5M12.5^ A(29.7)-10.3, (950.4)-59.0, («>)=348; 1704.
Ethylphenyl ketone. CqHioO^- Et.CO.Ph.
In HBr, good cond.; in H2S, no cond.; 1897.
Ethylphenyllactic acid see Ethylphenylhydrozy-propionic acid.
160 TABLES [Eth
0-£thyl-N-phenyl ^eii^fo-urea. (Ethylphenyl iso-urea) .
C9Hi20Nj-NH:C(NHPh)OEt.
ksXlO' at 25**=5; b. p. ISS.S^'-ISQ.S*' @ 18 mm.; 285, 286.
At 25^ m(26.0)=0.8, (833.1) = 5.4, (oo) = 224.2.
B.HCl at 25^ A(32)=89.0, (1024)-101.4; 286.
Ethyl phosphoric acid see Phosphoric acid mono ethyl ester.
Ethyl-a-picolinium chloride. CgHuNCl » CaH?. NEtCl.
At 25^ A(32)=90.6, (1024) = 103.0; 270.
Ethylpropylmalonic acid. C8H14O4 « CEtPr(C0aH)2.
IcaXIO" -8.9; 1667. [Misprinted as Methylpropyl- etc.]
Ethylpyridine. C7H9N - Et. C6H4N.
B.HCl at 25^ A(64)=96.1, (1024)« 102.2; 270.
Ethylpyridinium chloride. (Pyridine ethochloride or chloro-ethylate).
C7HioNCl-C6H6.NEtCI.
At25^ A(32)=94.6, (1024) = 106.0; 270.
Ethylquinolinium tri-iodide. (Quinolinium ethoiodide diiodide).
CiiHi2NIs= C9H7.NEtI.I,.
X of molten salt; m. p. 43°-45**; 1678.
Ethylstrychnimum chloride. (Strychnine ethochloride).
C28H27Q2N2CU C2iHa208N2.EtCl.
At 25^ A(32)«77.8, (1024) -91.5; 270.
Ethylsuccinic acid! CeHio04= CQ2H.CHEt.CH2.CO4H.
kA X 10"^ at 25*'=8.5; m. p. 98**; 1838, 176, 200.
Second La X 10*= 1.3 (inversion) ; 1638.
At 25°, m(32) = 17.9, (1024)=90.1, (cd)-353; 1838.
Ethyl sulphamide see Ethyl sulphonic acid amide.
Ethyl sulphanilic acid see Ethylaniline-4-sulphonic acid.
Ethyl sulphide see Diethyl sulphide.
Ethylsulphocyamic acid see Ethyl sulphonic acid cyanoamide.
Ethyl sulphonic acid amide. (Ethyl sulphamide).
C2H7O2NS-Et.SO2.NH2.
At 25°, A(32) = 5.0, (1024) -20.2.
Gond. with diethyl-amine; 1676.
Ethyl sulphonic acid cyanoamide. (Ethylsulphocyamic acid).
C8H«02N2S-Et.S02.NH(CN).
kAX 10" at 25° -7.3; diminishes on diln., from decomposition in
soln.
m(104.4)-9.6, (835.2)=22.6, (a>)=360; 70.
Ethyl sulphonic acid ethyl ester. (o^m.-Diethyl sulphite).
C4H10O8S-Et.SO2.OEt.
X X lO' at 0°«3.00. At 25°=4.96; b. p. 93° @ 10 mm.
Cond. as solvent; 1844.
EthylsulphothiocarbonglycoUic acid see Ethyl-/9A-dithio-carbongly-
• collie acid.
Bye] TABLES 161
Ethyl sulphuric acid see Sulphuric acid mono ethyl ester.
Ethyl sulphurous acid see Sulphurous add mono ethyl ester.
Ethyl thiocarbimide. (Ethyl mustard oil) . CsHsNS « CSNEt.
xX 10^ at 0°-0.873; 1844. At 25**= 1.258; b. p. ISIMSLS** @
760 mm.; 1844, 939, 1223, 1843.
In NHs, qual.; 606.
Cond. as solvent of organic compounds; 939, 1844.
Ethyl thiocyanate see Thiocyanic acid ethyl ester.
EthylthioglycoUic acid. C4H802S»EtS.CU2.C02H.
kAXl0^at25°=1.83aq.
A(31.5)=27.8, (503.4)-99.1, («)-380; 1466.
Pt.2A, v(40), cond. is of order of water; 1466.
Ethylthio-phenyl- see Phenyl-ethylthio-
Ethyltricarballylic add.
C8Hi20e=CQ2H.CH2.CH(C02H).CHEt(C02H).
JcaX 10^ at 25^=3.2; m. p. 147*'-148^ 1839, 67.
m(32) = 33.6, (1024) -151, (oo) = 341; 1839.
Ethyltriphenyl phosphonium chloride. C2oHsoClP« (Et) (Ph8)PCl.
At 25^ A(32)=79.6, (1024)^90.6; 270.
Ethyltrithio-carbonglycolUc add. CbHsO^Ss" EtS.CS.CHSH.COjH.
kxXlO^ [at 25^1=8.2; m. p. 75.5^-76^
m(91.4)=90.7, (724.8) =202.5, (cd)-378; 853.
Ethyl &o-urea. QHgONj^ NH2C(0Et) :NH.
kB X 10* at 25**- 1.04; b. p. 89** @ 10.5 mm.; 286, 286.
A(32)-13.3, (256) =34.9, («)= 234.6.
B.HCl at 25^ A(32) = 99.2, (512)^110.8; m. p. 123*^-124°; 286.
Ethylxanthoacetic add see Ethyl-/3A-dithiocarbonglycollic add.
Ethylxanthogenacetic add see Ethyl-/3A-dithiocarbonglycollic add.
Ethyl zanthogenate see Zanthic acid ethyl ester,
Eucalyptole see Cineole.
Eugenol. ( 1- Allyl-4-hy droxy-3-methoxy-benzene) .
CioHM02=CH2:CH.CH2.C6H,(OH)(OMe).
In NHs, qual.; 606.
Cond. with NaOH and HCl; 1608.
Euphorbia helioscopia. (Sun spurge). [The references to this are
incomplete. ]
Cond. of sap; 263.
Eye. [The references to this are incomplete.]
Cond. of fluids of eye; 263. Concentration of H and OH ions in
aqueous and in vitreous humor; 687. Cond. of crystalline
lens; 269, 260.
162 TABLES \Fea
F.
Fencholenic add. CioHi602»CoHi5.C02H.
kx X 10^ at 18^ is about 1 ; increases on diln.
A(381)-18.0, (1933)=44.3, (oo)=317; b. p. 260*^-261 °; 1899.
[This acid has been split into two isomers. The acid
measured was chiefly the a-acid. ]
Ferriacetoacetic ester see Acetoacetic acid ethyl ester; - salts.
Ferriacetylacetone see Acetylacetone; - salts.
Ferribenzoylacetic ester see Benzoylacetic acid ester; - salts.
Ferribenzoylacetone seeBenzoylacetone; - salts.
Ferricyanic acid. (Hydroferricyanic acid). C6H3N6Fe«H8Fe(CN)6.
3K.A, at 0^• 901, 903, 1959, 1963. At 18^ 971. At 25^ A(32) =
121.3, (1024) = 153.0; 1836, 971. Cond. with coUoidal cop-
per; 313. E. m. f.; 372.
Ferri-diacetyl bromide. C4H604BrFe= Fe(C2H802)2Br.
Cond.; 1528.
Ferri-diacetyl chloride. C4H604ClFe=: Fe(C2H8Q2)2CL
Cond.; 1528.
Ferri-oxaUc add. C6H80i2Fe=H8Fe(C204)a.
Cond.; 1677.
3(NH4)A; 971. - 3K.A; 1485. E. m. f.; 1681a. '^
Ferrocyanic acid. (Hydroferrocyanicacid). C6H4NeFe"H4Fe(CN)6.
At 25^ m(32)-875, (1024) = 1223.6; [in Hg.U.]; 1362.
Under pressure of 1-500 atmospheres; 220.
2Ba.A; 1338. - 2Ca.A; 168, 1338. - 2Mg.A; 1836. - 4K.A at
25^ A(32) = 108.1, (1024)»152.2; 1836, 901, 903, 924, 1338;
at 0^' to lOO"*; 839, 889, 901, 903, 924, 1024, 1338, 1709,
1953a. Under pressure of 1-500 atmospheres; 220. Cond.
with gelatin; 468. Cond. with CUSO4; 1709. E. m. f.; 372.
- 2Sr.A; 158. - 2Zn.A in NHs, qual.; 606.
Ferro-oxalic acid. C4H208Fe= H2Fe(C204)2.
3K. A, e. m. f . ; 1581a.
Ficus elastica. (India-rubber tree). [The references to this are in-
complete. ]
Concentration of H and OH ions in sap; 587.
Ficus sicomorus. (Mulberry fig). [The references to this are incom-
plete. ]
Cond. of sap; 263.
Fishes. [The references to this subject are incomplete.]
Cond. of fluids of various parts and organs of fishes, with a bib-
liography of the literature; 250, 253.
FlavinduUnium see Phenylphenanthrophenazonium hydroxide.
For] TABLES 168
Fluor- see Fluoro-
Fluorenol-carbozylic add see Diphenylene-glycollic add.
Fluorenone. (Diphenylene-ketone. d-Ketofluorene). CuHsO.
Comparative strength (colorim.); 1665.
Fluoreiione-5-carboiylic add. (Diphenylene-ketone carboxylic add.
d-Eetofluorene-4-carboxylic add). CuHsOs.
Comparative strength (colorim.); m. p. 227*^; 1666.
Fluorenoiie-S-carbozylic add ethyl ester. CieHuOs.
Comparative strength (colorim.); 1665.
Fluorescein. CsoHuOs.
Effect of fluorescence on cond.; 1476. Effect of light on cond.;
325, 833, 1321. 2Na salt, effect of light on cond.; 1471a.
[The salt may have been used in the other references.]
Flttoroacetic add. C2H302F» CHsF.CC^H.
kAX 10» [at 25**]=2.17; m. p. 33^
A(32)=82.3, (1024) = 270.4, (oo)=362.5.
Na.A [at25M A(32)=76.7, (1024)=86.7; 1693.
m-Fluorobenzoic add. CyHsO^F^ F.C0H4.CO2H.
kx X 10* at 25**= 1.36; increases on diln.
A(64)=31.5, (1024) = 111.4, (oo)=355; 1371.
Formaldehyde. CH20= ECHO.
kxXlOi* at 0*^=1.4 (hydroL); 529, 512, 528.=2.1 (hydroL); 58.
At25^ A(38.1)=2.5, (608.8) =• 7.6; 959.
Cond. with NaOH; 58, 528. With casein and with gelatin; 1599.
Formaldehyde sulphurous add. CH4O4S » HCHO.HsSOs.
At 25^ A(38.1)-361.1, (608.8) =381.4, (oo)=379.1 or 388.1; 959.
KA at 25^ A(32)=97.8, (1024) = 116.7; 643.- Na.A at 25**,
A(1000)=89.6; 959.
Formamide see Formic add amide.
FormaniUde. C7H70N=Ph.NH.CHO.
kxXlO^* at 25*^=5. m(20)=0.03, (160)-0.10, (oo)=355; 538.
In NHs, qual.; 606.
Cond. with NaOH; 538.
rO-i
Formhydroxamic add. CH8O2N-HCH.N.OH.
kxXlO' at 25*^=1.
m(32)=0.7, (64) = 1.2, (00)- [380]; 1363a.
Formic add. CH202= HCO2H.
X XlO* at 0**=4.69; 787. At 8.62*'=0.15, extrapolated; 1330. At
15*^=1.23; 1330. At 17^=0.1705; 347. At 18*^=6.47; 787
1380. At 18.8**= 0.4; m. p. 8.39**, contained about 0.2% aq.
1575. At 19*'=0.668; 1853c. At 25**=2.91; 2008;= 1.6
753. At 30*^-7.99; 787.
164 TABLES [For
In all the following measurements, k diminishes on dilution.
kxXlO* at 10*'«1.94; 876. At 14.1*'- 1.98; 888. At 17*^=
2.07 aq.; 164. At 18*^-2.2 (colorim.); 1663. At 20**= 1.96;
876. At 25''-2.14; 1370, 44;=2.0 (neutral.); 296. At
30**- 1.97; 876. At 40*^=1.96; 876. At 54.3^ « 1.83; 44. At
55^-2.5 (action of disastase on starch); 2002. T not stated;
comparative, (colorim.); 961; (precipitation of casein); 693.
Cond.; 171, 294, 380, 642, 787, 788, 838, 1330, 1747, 1863c, 1967.
At 25^ A(32)-29.3, (1024) = 134.7, (oo)=376; 1370.
In HCl; 30; qual. ; 1897. In HBr, no cond. ; 30, 1897. In H2S, no
cond.; 1897. In HSSO4; 223. In N2O4, no cond.; 602. In
S02;1842. In NHs, qual.; 606. In Et and Me ale. ; 787, 788.
Cond. with KOH; 171, 294, 299. With boric acid, qual.; 1184.
With alcohols and sugar; 46. With lactose; 1747. With
Cu formate; 1618a. With albumin; 2032. Under pressure
of 1-260 atmospheres; 642. E. m. f.; 372. As solvent;
(223), (347), 746, 763, (1863c), 2008.
NH4.A; 823. - Ba.2A; 911, 1963a. - Ca.2A; 602, 1963a. - Ce.3A;
1496. -Cu.2A; 1618a. In NHs, qual.; 606. Cond. with
formic acid; 1618a. Cond. with pyridine; 1669. - Gl salt;
1711.-La.3A; 1496. - Pb.2A, in NH3, qual.; 606. -Li. A;
1367.-Mg.2A; 1836, 1837, 1963a. -KA; 1367, 380, 763.
In HCO2H; 763. In flame; 682. - Na.A at 25^ A(32) =
87.8, (1024)-98.1; 1368a, 1367. At 10^-40**; 164, 876.
Under pressure of 1-260 atmospheres; 642. Cond. with
organic compounds; 1994. In HCO2H; 763. In NHg, qual.;
606. In flame; 682.- Sr.2A; 911. - UO2.2A; 449.
Fonnic add amide. (Formamide). CH30N"H.CONH2.
xXlO* at 0**=1.80. At 25**=3.87; b. p. 118^19** @ 18 mm.;
1844, 1843; 1606d, 1863b. At 19''«17.7; 1863c.
At 19**, A(17.7)-0.06; 1863c.
In SO2; 1842. In NHs; 610.
Cond. with HCl; 410, 1606d. With NaOH; 412. With HgCU;
1097. With Na formamide; 1606d. As solvent; 1606d,
1844, (1863c).
B.3HC1; 1606d.
Fonnic add amyl ester. CeHis02»H.C02C6Hu.
In NHs, qual.; 606.
Effect of temperature on cond. ; 106.
Formic add iso-butyl ester. C6H10O2.
Effect of temperature on cond.; 106.
Formic add ethyl ester. C8H6O2.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Fum] TABLES 165
Fonnic acid methyl ester. C2H4O2*
Effect of temperature on cond.; 106.
Fonnic acid propyl eater. C4H8Q2.
Effect of temperature on cond. ; 106.
Orthofdrmic add see under the letter O.
Formylcyano- see Cyanoformyl-
Fozglove see Digitalis.
Fructose. (Laevulose). CeHuOe- CH20H.(CHOH)«.CO.CH20H.
kAXlO" at 0**=3.6 (hydroL); 612. At 10^«4.6 (catal.) At
18**=6.6 (catal.). At 25^-8.8 (catal.). At 40**- 14.9
(catal.) ; 1177, and 1160.
At 25^ A(4)-1.54; 1843; -also 1108, 1110, 1497.
In NHs, qual.; 606.
Cond. with boric acid and inorg. salts; 1497.
Fttchsine.
This is the hydrochloride or acetate of rosaniline or of a mixture
of bases of which rosaniline is the chief part.
B.HCl [Probably, pure p-rosaniline HCl], at 25^ m(273) = 98.3;
1402. m(256)»87.3; 882, 1265, 1266. At IS^'-QO^ 1796.
At 15**-100^; alone and with H2SO4; 1798.
[Structure not given.] Effect of light on cond.; 1321. In
MeNH2, small cond.; 637.
Fulminic add. (Carbyloxime). CHON=C:N.OH.
Hg.2A; 1094. In NHs, qual.; 606. - NaA at 0^ A(32)-52.4,
(1024) » 57.6; 1986. In aqueous soln. the sodium salt gives
also the reactions of hydroxamic acid, showing a change
due to hydration; see Palazzo, Tamburello, Gaz. Chim.
Ital. 37, 1, 1, (1907).
Fomaranilic acid. (Anilinofumaric acid).
CioH»0»N- CO2H.CH : CH.CO.NHPh.
Na. A, [at 25M A(32)=64.1, (1024) =74.2; 191.
Fumaric acid. C4H404* CO2H.CH : CH.CO2H.
k increases on diln. in all measurements of cond.
kxXlO^at 0*^=9.4; 1968a;-8.0 aq.; 1018. At 12*'-9.7; 1968a.
At 18**- 11 (colorim.); 1662, 1663, 1781. At 22*^-9.4 aq.
164. At 25**=10.1; 1968a.-9.3; 1372; -11.8 (neutral.); 1718.
At 35'' -10.0; 1968a.
Second kAXlO*=2.2 (part.); 370; (inversion); 1336, 1638.-3
(cond.); 370, 1911.
Cond.; 170, 1718. At 25^ m(32)-58.0, (1024)=228.1, («)=-
353; 1968a. m(32)-56.4, (1024)-228.0, (oo)-357; 1372.
-Qual.; 1387.
In HBr, no cond. In HCl, small cond.; 30.
Cond. with KOH; 170. With NaOH; 1608, 1718.
166 TABLES [Pum
Mg.A; 819, 1836.-2K.A and KHA; 164.-NaHA; 370.
-2NaA, at 26% A(32)=89.5, (1024) = 108; 870, 270; -496.
Fumaric acid mono ethyl ester. C6H804= CQ2H.CH: CH.CO»Et.
kxXlO* at 25**«4.8; diminishes on diin.
m(22.0)=34.5, (704.0) = 153.2, (oo)=354; 1869.
Furfur- see also Furyl-
Furfuraciylic acid. CrHeOs^ C4H8O.CH: CH.CO2H.
kAXlO«=3.25; m. p. 141^; 1104.
affo-FurfuraciyUc acid. C7H608= CiHsO.CH : HC.CO2H.
kAX 10^=7.82; m. p. 82*'-86**; this acid contained a little fur-
furacrylic acid; 1104.
Furfurol. (Furfuraldehyde. Furol). C6H402=C4H80.CHO.
xXlO^ at 0^=9.73; 1844, 1843. At 20*^=11; 1690a. At 26**=
1.61; b.p. 161** @ 753 mm.; 1847, 617, 1106, 1107, 1669,
1844.
kx Xl0i« at 0** is less than 1 (hydro!.); 612.
At25% A(2)=0.15; 1843.
In HBr and HI, good cond. ; in H2S, poor cond. ; 1897.
Cond. with Cu oleate; 1669. As solvent; 1106, 1107, 1669,
1690a, 1844, 1847, 1849, 1863a. As solvent under pressure;
1590a.
Compound with HsSOs, no cond.; 962.
Fuiyldihydro-resordnol. CioHio08= C4H80.CeH60(OH).
kAXlO* at 25**= 1.5 aq.; diminishes on diln.; m. p. about 150**
with dec. A(326.7)=25.4, (1307)=48.0, (a>)=374; 1688.
G.
Galactose. CeHi206=CH20H.(CHOH)4.CHO.
X of soln. of 1 mol in 1 litre=3.5 Xl0~^ 322.
In NHs, qual.; 606. In MeNHg, little cond.; 637.
Gallein. C20H12O7; formerly given as C20H10O7.
In MeNH2, little cond.; 637.
Gallic add. (3,4,5-TrihydroxJ^-benzoic acid).
C7H605-(OH)8CeH2.C02H. [C02H=1; 0H=3, 4, 5.1
kAXlO* at 0°=3.38; increases on diln. At 6.5^=3.6; increases,
then diminishes on diln.; 1968a. At 18°= 5.9 (colorim.);
1563, 1781. At 25®= 3.9; increases, then diminishes on
diln.; 1371, 1968, 1968a, 1184. At 35**= 3.9; increases,
then diminishes on diln.; 1968a.
At 25% M(32) = 11.7, (1024)=66.5, (oo)=356; 1371. m(1024) =
62.5, (00 ) = 348; 1968a. - 1718.
In NHs, qual.; 606. In Et ale; 1186.
Gill] TABLES 167
Cond. with boric acid; 1184, 1186. With NaOH; 1608, 1718.
Na.A at 25"", m(2048)-74.4; 1968a.
Gallic acid ethyl ester. CsHioOs^ (OH)aC6H8.CQ2Et.
kAXlO' at 26**=9.7; diminishes on diln.; m. p. 155**.
m(32) = 0.6, (256) = 1.6, (a>)=351; 404.
Gallic acid methyl ester. CgHsOs.
kAXlO^ at 25^=9.7; diminishes, then increases on diln.; m. p.
193^
m(32)=0.6, (256) = 1.9, (00 ) = 352; 404.
Gallotannic acid see Tannic acid.
Gasteria maculata. [The references to this are incomplete.]
Cond. of sap; 263.
Gastric juice. [The references to this are incomplete. ]
Cond.; 263.
Concentration of H and OH ions; 687.
Gelatin. There is still doubt as to whether gelatin is CzHxOxNx, or
whether it also contains sulphur.
X of 0.726 g in 100»5.2xlO'^ 446a. - 146b, 468, 1226b, 1226c,
1226, 1397, 1699.
Cond. with K4Fe(CN)6 and KCNS; 468. With HCl and inorg.
salts; 1397. With EsCrsO?; 1226b, 1226c, 1226. With
NaOH; 617a. With inorg. salts; 146b, 1699. With dia-
stase; 807, 808. With formaldehyde and phenol; 1699.
With trypsin; 146b. Penetration by X-rays, [no cond.];
164. Effect of light on chromatized gelatin; 1226b, 1226c,
1226.
Gelsemine. QbH«804N2; also given as C24HS8O4NS.
ksXlO^ at 15^=1.8 (hydroL); 1779.
Gentisic acid see 2,6-Dihydroiy-benzoic add.
Gentisic aldehyde see 2,6-Dihydrozy-benzaldehyde.
Gentisinic see Gentisic.
Gliadin. [The references to this are incomplete. ]
H ion concentration; 1611b. See also; 2006.
Globulin. [The references to this are incomplete. ] See Edestin and
Serum globulin; also Blood.
Glu- see also Gly-
Glttcinum. (Beryllium).
Complex salts with organic acids; 320a, 1621, 1711, 1712.
Gluconic add see Glyconic.
Glucose. (Dextrose). CeHwOe- CH20H.(CHOH)4.CHO.
kAXlO" at 0*^=1.8 (hydro!.); 612. At 10*^=2.4 (hydroL); 1177
and 1160. At 18*^=3.6 (hydro!.); 1177 and 1160; approxi-
mates 0.14 (hydro!.); 632. At 25''«5.9 (sapon.); 1364, 392,
1036, 1177, 1160. At 40''»9.8 (hydro!.); 1177 and 1160.
168 TABLES [Glu
Cond.; 322, 1108, 1110, 146ia, 1497, 1746.
In NHs, qual.; 606. In MeNHs, little cond.; 637. In Me ale;
1746.
Cond. with inorg. acids; 741, 1497, 1746. With organic acids;
46. With NaOH and other bases; 632, 1746. With salts;
1497, 1746. Concentration of H ions; 1269b.
Gltttaconic add. CsH6O4-CQ2H.CHs.CH : CH.CQ2H.
kxXlO* at 25*'= 1.83; increases on^diln.; m. p. 132^
m(32)-26.2, (1024) -127.0, (00)= 366; 1838.
Gltttamic add see Aminoglutaiic add.
Glutaminic add see Aminoglutaiic add.
Glutaric acid. C6H804= CH2(CH2.C02H)2.
kxXlO* at IS^'-S.S (colorim.); 1663. At 26^-4.75; 1371, 1638,
1810.
Second kAXlO®-2.7 (inversion); 1336, 1638.-3.4 (part.);-2.9
(cond.); 370.
At 25^ m(64)-19.0, (1024) -70.0, (oo)-354; 1371.
Co.A. - Mg.A. - NiA; 1736. - 2K.A; 494. - NaH.A; 370.
- 2Na.A at 25% A(32)-82.9; (1024) -99; 370, 270.
Glutaric add anhydride. CsH^Oa.
Cond. showing change to acid; 1810.
Gluten.
A mixture of gliadin and glutenin; (with some included starch;
2005).
Relative cond. with inorg. and organic acids; 2006.
o,|8-Glyceric add. CtH6O4-CH2OH.CHOH.CO2H.
kxXlO* at 25^-2.3; 1184, 1370.
M(32)-29.1, (128)-55.3, (a>)-367; 1184.
Cond. with boric acid; 1184.
Glycerine see Glycerol.
Glycerol. (Glycerine). C8H80»-C8H5(OH)8.
X XlO» at 0*^-2.2. At 5.9*'-3.6. At 11.7*'-6.6. At 14.8^-7.8.
At 16*^-8.4. At 17.6**= 9.6.; 361. At 20*^-10; 1690a. At
21.3*'-12.3; 361. At 25*^-6; 1592.
Cond.; 806, 1181, 1222, 1434, 1980.
In HBr, good cond. In H2S, no cond.; 1897. In HCN, no
cond.; 943. In NHs, qual.; 606. In MeNH2, fair cond.;
637.
Cond. with inorg. acids; 799, 1181. With organic acids; 799,
45. With EOH; 385. With NaOH; 1035. With salts;
146b, 361, 944, 1279, 1692. As solvent, under pressure;
1690a. As solvent; (361), (385), (1221), (1278), 1279,
1434a, 1690a, (1592). Dielectric constant; 582.
Glycerol phosphoric add see Phosphoric add glycerol ester.
Gly] TABLES 169
Glycine see Aminoacetic acid.
GlycochoHc add. C26H4306N»C24H«904.NH.CHs.CO^H.
' kxXlO* at 25''=1.32; diminishes on diln.
m(750)=97.7, (1500) -128.3, (oo)=363.
Na.A at 25% m(200)=60.4, (800) -64.9; 228.
Glycocoll see Aminoacetic acid.
Glycocoll-p-phenetidine. (PlienocoU) .
C10H14O2N2-EtO.C6H4.NH.CO.CH2.NH1.
B.HCl at 25% A(32)-82.4, (1024)-93.0; 270.
Glycocyamine see Guanidineacetic add.
Glycogen. (CeHio05)z.
Diaiyzed soin., x at 20'', is of the order 3 XlOr^; 2M, 256. - 252a.
Cond. with NaOH; 252a.
Glycol see Ethylene glycol.
Glycolamide see Glycollic add amide.
Glycol chlorohydrin. (Chloroethyi alcohol. Ethylene chlorohydrin).
C2H5OCI- CH2CI.CH2OH.
Cond. with HCl; 760.
Glycoliminohydrin. C4H10O4N2 or C2H6O2N.
At 25% m(64)-67.3, (1024) =76.5 for formula, C4H10O4N2;
m.p.-162M63^
Cond. with HCl and NaOH; 781.
GlycoUic add. C2H4OB = CH2OH.CO2H.
kAXlO* at 17^=1.57 aq.; 164. At 18*^ is about 1.5; 93. At
25^-1.52; 1184, 1370; (colorim.); 1781.
Cond.; 93, 94, 171, 782, 1094, 1495. At 25% A(32)-24.8,
(1024)-116.7, (oo)=363; 1870.
In HCl, no cond.; 30. In NH3, qual.; 606. In Et ale; 782,
1820.
Cond. with boric add; 1184. With Cr(OH)a; 320b. With
MoOb; 1495. With acetic add; 93, 1821. With KOH;
171. With organic salts; 94.
Hg.2A; 1094. - K.A; 94. - Na.A at 18%- 93, 94. At 25%
A(32)=74.0, (1024)-84.7; 1368a.- UO2.2A; 449.
GlycolUc add amide. (Glycolamide). C2H6O2N-CH2OH.CONH2.
Cond. with HCl and NaOH; 781.
GlycoDic nitrile. C2H8ON- CH2OH.CN.
xXlO« at 0*^-5.16. At 25*^-8.34; b. p. 98^ @ 10 mm.; 1843,
1844.
As solvent of NEt4l; 1844.
Glycol phosphoric add see Phosphoric add mono glycol ester.
Glyconicadd. (Gluconic acid). CeHi207-CHsOH.(CHOH)4.C02H.
Ca.2A at 17% A(0.09)=25.0; 525.
Glycosaccharic add see Saccharinic acid.
170 TABLES [Gly
Glycyl-aminoacetic add. (Glycyl glycine).
C4H«Q,N2=NHi.CH2.CO.NH.CHi.CQ2H.
kxXlO^ at 25*'-1.8 (hydrol.).
kBXlO" at 25*'=.2 (hydrol.); 619, 623.
Cond. with HCl and NH4OH; 622. With erepsin and pancreatin;
619, 623.
Glycyl glycine see Glycyl-aminoacetic acid.
Glycyl-hydrozyphenyl-aminopropionic acid. (Glycyl tyrosine).
Cond. after digestion with trypsin; 146b.
Glycyl tyrosine see Glycyl-hydrozyphenyl-aminopropionic add.
Glyoxal. C2H202= OHC.CHO.
In NHs, qua!.; 606.
Glyozalic add see Glyozylic add.
Glyozaline. CaH4N2.
keXlO^ [at 25*']=1.2; m. p. 90^
m(32) = 0.42, (256) = 1.4, (00) =231.4.
B.HNOj [at 25°], m(32) = 98.1, (1024) = 109.9; 428.
Glyozime carbozylic add see Dioximino-propionic add.
Glyoxime dicarbozylic acid see Diozimino-succinic add.
Glyozylic acid. (Gly oxalic acid).
C2H404=(OH)2.CH.C02H-CHO.C02H +H80.
kA XlO^ at 25° is about 4.7; aq. used for soln. was not pure.
m(32)=41.7, (1024)«174, (oo)=361; 1370.
Granatum. (Pomegranate). [The references to this are incomplete. ]
Cond. of soln. of bark; 146.
Grape. [The references to this are incomplete.]
Concentration of H and OH ions in grape juice; 687.
Guaiacol. (2-Methoxy-phenol. Pyrocatechol mono methyl ether).
C7H802=MeO.C8H4.0H.
xXl0^at25°=2.6; 1669.
kxXlO^ at 26° is about 1; increases on diln. m(23.7)=0.4,
(189.2)=2.0, (oo)=356; 70.
In NH«, qual.; 606.
Cond. with NaOH and HCl; 1608. With Cu oleate; and as
solvent; 1669.
Gisaiacolcarbozylic add. (2-Hydroxy-3-methoxy-benzoic acid).
C8H804-OH.C6H8(OMe).C02H. [C02H=1.]
kxXlO* at 25°= 1.38 aq.; diminishes on diln.; m. p. 149°-149.5°.
iu(128)=121, (1024)=236, (oo)=354; 1186.
InEtalc; 1186.
. Cond. with boric acid; 1186, 1186.
Guanidine. CH6N8=HN:C(NH2)2.
kaXlO^at 15°=1.1 (colorim.); 1176.
Hd] TABLES 171
Cond. at 25®, m(32) = 189.7, (256) =208.3; in aq. contaimng some
NH4OH; 1363.
B.HC1 at 25^ A(32) = 106.1, (1024) = 117.1; 270.- B.HNQs in
f NHs, qual.; 606. - B.Picrate; 406.
Gnanidlneacetic acid. (Glycocy amine).
C3H702Na= HN : C(NH2).NH.CH2.C02H.
kBXlO^i at 40*^=2.4 (catal.); 1996 and 1160. At 40.2*'=2.32
(catal.); 1996.
Guanine. (2-Amino-&-oxypurine). CsHsONs.
ksXlO^* at 40*^=8.35 (catal.); 1996 and 1160. At 40.2*^=8.07
(catal.) ; 1996.
Gum arable. [The references to this are incomplete. ]
Cond. of aq. soln. is not affected by radium; 2031. Cond. with
ECl; 146b.
H.
Haematlnic acid anhydride. C8H806»C02H.H7C6: (C0)20.
kx XlO* at 25^^=2.4; increases on diln. iu(40)-33.8, (1280)-157;
m. p. 96*^-97^ 1029.
Haematlnic imide. (Biliverdic acid. Biliverdinic acid. Haemo-
tricarboxylic acid imide.) C8H»04N=C02H.H7C5: (COjNH.
kxXlO* at 25''-3.6; diminishes on diln.; m. p. 113.4**-114.5^
m(40) = 14.1, (1280) = 72.9; 1029.
Cond. different from that in 1029; no data; 1032.
Haematozylin. CuHuOe.
In NHs, qual. ; 606.
Haemotricarbozylic acid.
C8HKO6=CO2H.(CH2)2.(CO2H)CH.CHMe.C02H.
a)m.p. 140M41^
kxXlO* at 25*^=2.50; diminishes on diln. iu(32)«32, (1024)-
125.3, (oo)=375; m. p. 140^-141**; 1030,1033.
b) m. p. 175^-176^
kAXlO* at 25^=2.45; diminishes on diln. m(32)-51.7, (1024)-
130, (oo)=375; m. p. 175M76^• 1030, 1033.
Heart. [The references to this are incomplete.]
Cond.; 166a, 263, 623, 624.
Heliantfaine see Dimethyl-aminoazobenzene sulphonic acid.
Heliotropine see Piperonal.
Helvetia Blue. (Soluble Blue.) Trisulphonic add. The dye is the
sodium salt. The free acid is triphenyl-p-rosaniline-tri-
sulphonic acid C87H280N3(S08H)8.
Free acid, at 18^ m(400)= 556.0, (1600) « 667.2. At 90% iu(400)-
1156, (1600) » 1242. This is the cond. of a disulphonic acid.
Cond. with KCl; 976a.
172 TABLES [Hem
Hem- see also Haem-
Hemipic see Hemipmic.
Hemipinamic add see Hemipiiiic acid mono amide.
Hemipinic add. (Dimethoxy-norhemipinic acid. 3,4-Dimethoxy-o-
phthalic acid. Hemipic acid).
CioHioOe=(MeO)2C8H2(C02H)2. [CQ2H=1, 2; MeO-3,4.]
kAXlO* at 25^=1.17; increases on diln. iu(32)=68.7, (1024) =
230.4, (00). 352; 966,1909.
Hemipinic add 2-mono amide. (2-Henupinamic acid, a- acid).
CioHuOsN. [C02H-1; CONH2-2.]
kxXlO* at 25*^-7.0; diminishes on diln. m(64)=22.6, (1024)«
75.4, (00) -350; m. p. 160^-162*'; [k is not given correctly
in the original]; 1243, 1244.
Hemipinic add 1-mono amide. (1-Hemipinamic acid. /3- acid).
CioHuOsN. [C0jH=2; CONH2-I.]
kxXlO* at 25*'-4.3; diminishes on diln. m(64)=53.7, (1024) =
147.5, (» )=350; m. p. 142^; [k is not given correctly in the
original]; 1243, 1244.
Hemipinic add 1-mono ethyl ester, (fi- ester).
C12H14O6- (MeO)2C5H,(CQ2Et)(CQ2H). [C0jH=2; COjEt=
1.]
kxXlO* [at 25^]= 1.48; m. p. 144M45^ m(182)«62.8, (1456)-
123.6, (00) -350; 1907.
Hemipinic add 2-mono ethyl ester, (a- ester).
C12H14O6. [C02H=1; C02Et-2.]
kxXlO* [at 25*']-1.01; m. p. 147.5M49**. m(139.3) = 108.6,
(1114.4)=213.2, (oo)=360; 1907.
Hemipinic add 1-mono methyl ester. (/3- acid).
C11H12O6. [C02H=2; C02Me-l.]
kAXl# at 25*^=1.30; m. p. 136M37**; 1371, 1941. m(136.1) =
126.9, (272.6) -162.0, (00) -373; 1941.
Hemipinic add 2-mono methyl ester, (a- acid).
C11H12O6. [CO2H-I; C02Me-2.]
kxXlO* at 25^=1.67; m. p. 117M19**; 1941;=1.60; diminishes
on diln.; 1371. iu(324.8)-77.5, (660.6) - 104.3, (oo)-373;
1941.
Hemipinic add 1-mono propyl ester. 03-n-ester).
CwHieOfl. [CO2H-2; C02Pr=l.l
kxXlO* at 25^-9.3; m. p. 125*'-125.5^ 1909, 1907. m(255.5)-
142.6, (1025)-225.8, (oo)=:372; 1909.
Hemipinic add 2-mono propyl ester, (a-n-ester).
CisHieOe. [CQ2H-I; CQ2Pr=2.]
kxXlO* at 25^-1.46; m. p. 131M32°; 1909, 1907. iu(610.9)-
88.9,(1023)-117.0,(a>)=372; 1909.
Hex] TABLES 178
m-Hemipiiiic add. (4,5-Dimethoxy-o-phthallG acid. Hemipinic
acid of Ostwald).
CioHio06« (MeO)2C5H2(C02H)2. [CQ2H= 1,3; MeO=4,5.
See Kirpal, Monatsh. 18, 462. ]
kAXlO* at 25**= 1.47; diminishes on diln. m(64)-92.6, (1024) =
237.0, (oo)-352; 1371.
Heptadi-inene-carbozylic acid see ^seudo-m-Toluic add. •
Heptane. C7H16.
xXlQi^at 18**=-4.1.
Cond. with hydrocarbons; 386. As influenced by radium; 873.
a/3-Heptenoic add. C7Hu02= Me. (CH2)8.CH : CH.CO2H.
kAXlO*-1.6; b. p. 225*^-228*' @ 737 mm. A(64)-11.9, (1024)«
42, (00)- [376]; 1647.
Heptiidc add. (iso-Gentisic acid. iso-Heptinic acid). CsHuOa.
kAXlO* at 25^=8.3; m. p. 149^-151**; 1823, 1831. iu(128) =
34.4, (512)=65.4, (oo)-:352; 1823.
Heptoic add. (Heptylic acid. Oenanthylic acid).
CiHmQj" Me.(CH2)6.C02H.
kxXlO* at 25**- 1.31; b. p. 221.3^ (cor.); 801;- 1.47; 461.
A(128)=14.1, (1024)=38.2, (oo)=352; 601. A(90.9)-13.2, («)
-368; 461.
In NHs, qual. ; 606.
Na.A at 25^ A(32)-68.5, (1024) =73.0; 601.
Heptoic aldehyde see Heptyl aldehyde.
Heptyl alcohol. CtHmO.
In NH3, qual.; 606.
Heptyl aldehyde. (Heptoic aldehyde. Oenanthylic aldehyde).
C7Hi40=Me.(CH2)6.CHO.
In HBr and HCl, good cond.; in HI, poor cond.; in H2S, no cond.;
1897. In NHs, qual.; 606.
Heptylic add see Heptoic add.
Heptylmalonic add. CioHi804=Me.(CH2)4.CHMe.CH(C02H)8.
kxXlO* at 25**=!; m. p. 97^-98**; 1638, 1667.
Second kxXltf'- 6.1 (inversion); 1638.
At 25^ iu(199) = 125.8, (1592)=240:0, (a>)=349; 1638.
Hetero dnnamic add see Cimiamic add.
Heteroxanthine see 7-Methyl xanthine.
Hexachloro-benzene. (Perchloro-benzene) . CeCU.
In NHsi qual.; 606.
Hexahydro-benzoic add. (Cyclohexane-carboxylic acid).
C7Hi202= CeHii.C02H.
kAXlO*^ at 25*^=1.28; increases on diln.; b. p. 232.5**; 1138; =
1.34; 2026. A(64) = 10.4, (1024)=40.6, (oo)-374.5; 1138.
A(80) = 11.5, (1280)=43.3, (oo)-352; 2026.
174 TABLES [Hex
Hezahydro-pheHyl acetic acid see Cydohexane-acetic add.
Hezahydro-phenyl propionic add see Cydohezane-propioxiic add.
cis-Hezaliydro-o-phthalic acid. (Hexamethylene-l,2-dicarboxylic
acid) . CgHiaOi- C6Hio(C02H)2.
kAXlO* [at 25°]-4.4; m. p. 192^ 72, 1410.
A^ons-Hexaliydro-o-phthalic add. C8H12O4.
kxXlO* [at 25^]-6.2; m. p. 221**; 72, 1410.
cif-Hexahydro-p-phthalic add. (Hexamethyleiie-l,4-dicarboxyIic
acid). C8H12O4.
kAXlO* at 25*^=2.97 aq.; m. p. about 162^
Second kx X 10'=3.0; (inversion).
At 25^ m(68.4)-16.5, (1094) =57.3, (oo)=351; 1888.
A^ons^Hexahydro-p-phthalic add. C8H12O4.
kxXlO* at 25** =4.56 aq.; m. p. above 300^
Second kAXlO*«2.5 (inversion).
At 25^ iu(204.6) = 31.3, (1637)=83.7, (a>)«'351; 1638.
Hexahydro-toluic add see Methylcyclohezane-carboxylic add.
Hexaliydroxy-trichloro-bromotriketo-hexamethylene. CsHsQsCbBr.
[At 25**], M(128)-3.1, (512)=4.6; m. p. 87**; 727.
Hexamethylene-dicarboxylic add see Hexahydro-phthalic add.
1,1,3,3-Hexamethylene-tetracarboxylic add. QoHisOs.
kxXlO* at 25"*- 1.2; increases on diln. m(21.3)»52.1, (680.0)»
228.6, (00) =350; 1869.
Hezamethyl-p-rosamline see Hexamethyl-triamino-triphenyi carbinoL
Hezamethyi-p-triamino-triphenyl carbinol. (Crystal Violet. Hexa-
methyl-p-rosaniline) . C26HtiONa - (C6H4.NMc2)8C.OH.
Free base at 0**; 770. At 25^ m(256) = 150.5; 770.
B.Br and B.Br.2HBr; 734, 1671. - B.Cl at 0**; 770. At 25%
iu(128)=88.3, (1024) =95.0; 770, 1266. - B.HCl, B.3HC1;
734.
Hezanaphthene-carbozylic add see Methyipentamefliylene-carboxy-
lie add.
Hexane. CeHu.
X is extremely small; 386, 873a.
Cond. alone and as affected by radio-active 'substances; 873.
Cond. before and after continued passage of current; 1606.
With organic compounds; 386.
Hexanitro-diphenyl amine. CuHsOuN?.
In aq. is too insol. to measure; 321, 764. In pyridine; 764; qual.;
321.
Hexaphenyl-ethane. CssH^o- PhaC.CPba.
In SC^, no cond.; 671. See also Triphenyl-methyl.
Hezenic add see Hezenoic add.
Horn] TABLES 176
a/S-Hezenoic add. (Hexenic acid).
CeHioQj- Me.(CH2)2.CH: CH.CQjH.
kAXlO* at 25^-1.89. A(32)=9.2, (1024)-49.2, (oo)-378,
Na.A at 25% A(1024-32)- 10-11; 671.
^-Hezenoic add. (Hydrosorbic add).
CeHioOi- Me.CH2.CH : CH.CHt.COiH.
kAXlO* at 25''-2.7; diminishes on diln.; 671.»2.4; 1371. A(32)-
11.0, (1024)=55.3, (oo)-378; 671. A(32)«9.7, (oo)«357;
1371.
Na.A at 25% A(32)-64.9, (1024)«75.2; 1368a;- 671.
7$-Hezenoic add. QHioC^^ Me.CH: CH.(CHs)s.COiH.
kxXlO* at 25*^-1.74; diminishes on diln. A(32)-8.8, (1024)-
47.1, (00) =378.
Na.A at 25% A(1024r-32) = 10-11; 671.
de-Hezendc add. C6HioQ2»CH2:CH.(CHs)s.COiH.
kAXlO* at 25''«1.92; diminishes on diln. A(32)»9.3, (1024)-
49.2, (00) =378.
Na.A at 25% A(1024-32) = 10-ll; 671.
Hezimc add. C7H10Q8.
kAXlO»at25*'-8.4; m. p. 126M27^ iu(64) = 25.1, (612)=66.3,
(oo) = 354.
Na. A at 25% m(32)=:65.9, (1024)=76.9; 1823, 1831.
Hexoic add see Caproic add.
Hippuric add see Benzoylamino-acetic add.
Histidine. (a-Amino-j3-imidazole-propionic acid).
CeH902N8= CsH8N2.CH2.CH(NH,).C02H.
kAXlO» at 25**=2.2 (hydrol.).
kB X 10» at 26*^-: 5.7 (hydro!.).
Second kBXl0"=5.0 (catal.).
At 25% A(32)=3.7, (1024) = 9.3.
Na.Aat25% A(32)=65, (1024)=76; M(32)=66.3, (1024)=87.0.
- B.HCiat25% A(32)=87, (1024)=98; M(32)=88.9, (1024)
-109.7.- B.2HC1; 948.
Hofmaxm's ^olet. (Triethyl-rosaniline). The dye is a mixture of
salts of rosaniline and p-rosaniline bases.
In HCN, no cond.; 943. Effect of Rdntgen rays on cond.; 416,
1476.
Homatropine. CieHnOsN.
ksXlO^ is over 1 (colorim.); 1778.
Homo-hydroxy-benzaldehyde see Hydroxy-toluic aldehyde.
Homo-hydroxy-benzoic add see Hydroxy-toluic add.
Homophfhalamic add see Homophthalic add mono amide.
176 TABLES [Horn
Homophthalic add.
C»H804=C6H4(C02H)(CH2COjH).
[CQ2H-I; CH2CQ2H-2.]
kAXlO* [at 25*']=1.9. m(256)-74.5, (1024)-132.6, (oo)-376.5;
1684.
Homo-o-phfhalic add l-mono amide. (Benzene-1-carboxylic-acid-
amide-2-methylcarboxylic acid. Homophthalamic acid)-
CftHftOaN = CeH4(CONH2) (CH2CO2H) . [CONH2 - 1 . ]
kAX 10*^=5.0. m(512)-56.6, (1024) = 76.7, (00) =376; 1684.
Homo-o-phthalic acid 2-moiio amide. (Homophthalamic acid.
Phenylacetamide-o-carboxylic acid) .
C9H9OSN = CflH4(C02H) (CH2CONH2). [CO2H- 1.1
kAXlO^-8.9; diminishes on dUn. m(256)-52.7, (1024)=93.7,
(00) =376; 1684.
Homo-o-phthalic add l-mono ethyl ester, (a- ester).
CuHi2O4=C6H4(CO2Et)(CH2C02H). [C02Et= 1.]
kAXlO'^=4.6; diminishes on diln.; m. p. 111M13^ iu(512) =
53.4, (1024)=71.9, (oo) = 374.6; 1684.
Homo-o-phthalic add 2-moiio ethyl ester. (j3- ester).
C11H12O4- C6H4(C02H) (CHjCOjEt) . [COsH- 1. ]
kAX 10* =7.1; diminishes on diln.; m. p. 107°. iu(256)=47.1,
(1024) =87.3, (00) =374.6; 1684.
Homo-o-phthalic add l-mono methyl ester, (a- ester).
CioHio04=C6H4(C02Me)(CH2C02H). [COjMe-l.l
kAXlO*=4.34; m. p. 143*^-145^ 1684; qual.; 1934. m(512) =
51.9, (1024) = 71.2, (oo) = 375.3; 1684.
Homo-o-phthalic add 2-mono methyl ester. (/9- ester).
CioHio04= C6H4(CQ2H) (CHaCOjMe). [COsH- 1. ]
kAXlO«-7.64; m. p. 96*^-98°; 1684; qual.; 1984. m(256)=48.9,
(1024)=90.7, (oo)=375.3; 1684.
Homo-salicyl aldehyde see Hydrozy-toluic aldehyde.
Homo-salicylic acid see Hydrozy-toluic add.
Hydantoin. (2,4-Diketo-tetrahydro-imideazole) . CtH402N2.
kAXlO^® at 25^=7.59 (catal.); m. p. 216**-217^ 1996. At 26%
iu(32)=0.08, (266) =0.12; 1748.
Hydr- see also Dihydr-
Hydracrylic add. (j3-Hydroxy-propionic acid).
C8H«0,=CH2(OH).CH2.C02H.
kAXlO*^ at 25*^=3; 1186, 1370. m(32) = 10.7, (1024)=57.3, (<») =
358; 1186.
Cond. with boric acid; 1186.
Hydrastine. C21H21O6N.
ke X 10^ at 20** is about 1 ; (colorim.) ; 1779.
Hyd] TABLES 177
Hydratropic acid. (a-Phenylpropionic acid).
C9H10Oj-Me.CHPh.CO2H.
kAXlO* at 25**=4.25; increases on diln. A(64) = 17.8, (1024)-
66.6, ( 00) -352; 1371.
Hydraziacetic add. C2H4OSN2 » COjH.CHsNj.
At 25% A(32)«73.0; dec. about 190^; 767.
Hydraztne. N2H4-H2N.NH2. [The references to this are incom-
plete. 1
xXlO* at 0^=3.4; b. p. 118.5^ 1828. At 25**=4; 393.
kfiXlO* at 25^-3 aq.; diminishes on diln.; about 16% too high;
271.
Cond.; 393; qual.; 1702. At 25% A(32)-1.9, (256)=5.1, (»)«
224; 271.
Cond. as solvent; 393, 1828.
B.HCl at 25% A(32)-111.5, (1024) = 125.0; 270.
Hydrazoic add. (Azoimide). HNs. [The references to this are
incomplete. ]
kxXlOS at 0^=1.0; 733. At 25**=1.98; diminishes on diln.;-
1.86 (inversion); 1964; qual.; 419.
At 25% A(10) = 5.4, (1000)=46, (oo)=385; 1964.
Na.A at 25% A(32)=- 100.8, (1024) = 107.9; 1964.
Hydro- see also Dihydro-
Hydro metallo cyanic adds of the general t3rpe HxRz(CN)x, where R
is a metal, should be looked for under the head of the metal.
Those given in the tables, arranged by the metals, are:
cadmium, chromium, cobalt, copper (cupri- and cupro-),
iridium, iron (ferri- and ferro-), manganese, mercury, molyb-
denum, nickel, palladium, platinum, silyer, zinc. The
existence of some of these is denied, the so-called salts being
regarded as mixtures or complexes of indefinite composition.
Hydrochelidonic add. (Acetone-diacetic acid).
C7H10O6- CO(CH2CH2C02H)2.
kAXlO*at25*'=4.6aq.; m. p. 143^ m(32) = 13.2, (512)=50.0,
(00) =352.
Cond. with boric acid; 1186.
Hydrochloric acid. HCl. [The references to this are incomplete. ]
Unit^R.O.
V- (16) (32) (128)
' A at 0''=245.9 249.0 • 254.8
A at 15**=330.5 342.3 349.1
A at 25** =388.5 395.6 403.7
(Tower, Conductivity of Liquids.)
Hydrocinnamic acid. (Benzylacetic acid).
C9Hio02« PhCH2-CH2.C02H.
(512)
(1024)
256.4
256.5
349.3
349.3
403.7
403.7
178 TABLES [Hyd
kAXlO* at 18*^-2.5 (colorim.); 1563, 1781. At 25*^«2.27; 1371.
At 25% A(64)=-13.2, (1024)-49.1, (oo)-352; 1371.
m-Hydrocoumaric acid. (m-Hydroxy-hydrocinnamic acid).
C9HioOj-C6H4(CH2CH2COjH)(OH).
Cond. alone and with NaOH in Et ale; 1508, 1718.
p-Hydrocoumaric acid. CoHioQs.
kxXlO* at 25^= 1.75; diminishes on dHn. A(128) = 16.3, (1024)-
43.4, ( 00) =352; 1371. See Phloretic acid.
Hydrocyanic acid. CHN - HON and HN :C.
xXlO<^ at 0''-3.26; 1853c.=4.73; 943, 1843; 369. - 631.
kAXlQi® at 10^=2.8 (catal.); 1177 and 1150. At 18**«4.7
(catal.); 1177 and 1150;- 1287.-13; 1883, 1865. At 25''-
7.2 (catal.); 1177 and 1150. - 1043. At 40''- 15.7 (catal.);
1177 and 1150.
Cond.; at 25% A(25.9) -2.4; 1984. - 1362. A (75) -0.4; 770.
- 1853c.
In HCl; 1646.
Cond. with HCl and NaOH; 1984. With NHi; 733. WithAgO;
510. As solvent; 369, 943, (1853c).
Ba.2A; 1654. - Cd.2A, complex; 1485. - Or, complex; 1487.
- Cu.A in NHs, qual.; 606. - Au.2A in NHi; 610. - Hg.A;
246; complex; 246; 689. Hg.2A; 246, 841, 907, 1094,
1461. In NHi; 315, 607, 610. In NH«, qual.; 606. In
MeNHs, fair cond.; 637. In organic solvents; 1106, 1107.
With inorg. acids; 1097. With HgO; 246, 841. E. m.f.;
963. Complex; 149, 246, 604, 689, 785, 841, 1008, 1094.
- E.A.; 907. In HBr and HCl, good cond. In HI and
PHs, no cond.; 1645. In NHs; 610. In NH|, qual.; 606.
In acetamide; 1894. In ale; 764, 1654. Cond. with
organic compounds; 1654, 1746, 1747. Complex; 149,
604, 907, 1050, 1485. - Ag.A; 216. In HCN, Uttle cond.;
943. In NHs; 604, 607, 610. In NHs, qual.; 606. In
pyridine, little cond.; 1106.- Na.A; 1664.- Zn.2A in NHa;
610. In NHs, qual. ; 606. - " Double " salts, and complex
salts; 149, 246, 510, 604, 689, 785, 907, 971, 1008, 1050,
1094, 1434a, 1485, 1487, 1709, 1832. See also under the
separate headings, as Ferricyanic acid etc., for the ''double"
salts.
Hydrocyan-p-rosaniline. (p-Triamino-triphenyl acetic acid nitrile).
C2oHi8N4= (H2N.C6H4)sC.CN.
The salt-forming base changes to a pseudo base. At 25^, ti(bl2) -
74.9 after 1 minute, = 11.9 after 60 minutes; 770.
Base+SHCl, at 25^ m(128) = 361.2, (1024)=539.5; 1266.
Hydrof erricyanic add see Ferricyanic add.
Hyd] TABLES 179
Hydroferrocyanic add see Ferrocyanic add.
Hydronitroprussic add. (Nitroprussic acid).
CsHjONeFe- H2Fe(CN)5NO.
2Na.Aat 25% A(32)=92.1, (1024) = 109.3; 1832.
Hydroquinone. (1,4-Dihydroxy-benzene. Quinol) .
C6H60j=C«H4(OH)2.
kA XlO*® at 0^-0.57 (hydro!.); 624. At 25*'=1.1 (hydro!.); 624;-
200?; increases on di!n.; 70.
Cond.; 1718. At 25% m(23.2)=0.3, (92.8) = 1.9, (oo)=356; 70.
In HBr, !itt!e cond., in H2S, no cond.; 1897. In NHs, qua!.;
606.
In MeNHs, good cond.; 637.
Cond. with NH4OH; 733. With NaOH; 1608, 1718. With
FeCl,; 766.
2NH4.A. - 2Na.Aat25% A(200)=68.1, (400)=69.5; 624. - Com-
pound with FeC!s; 766.
Hydroshikimic add. C7H12O6.
kxXlO* at 19**=3; m. p. ITS*' (uncor.). m(29.6)=9.6, (59.2)=
13.2, (00) -323.8; 641.
Hydroshikimic add dibromide see Dibromo-hydroshikixnic add.
Hydrosorbic add see j37-Hezenoic add.
Hydrozy-amyl sulphonic add, see iso-Amylisefhionic add.
Hydrozy-azobenzene see Ozyazobenzene.
o-Hydrozy-benzaldehyde. (Saiicyl a!dehyde).
CrHeOi^ C6H4(OH)(CHO).
xXlO' at 0**=1.0; b. p. 192M93'' @ 753 mm.; 1843;=2.3;
1844. At 25''-1.64; 1843;»4.1; 1844; 1106, 1107.
kAXlO* at 25** is under 10 (colorim.); 1397c; =15.7; 643.
At 25% A(32)-7.8, (256)=22, (oo)=356; 643. [The vaiues of
k and of A in 643 are probabiy too liigh. See the m- and p-
isomers.] A!so; 1608, 1718.
Cond. with NaOH and HC!; 1608, 1718. As soivent; 1106,
1107, 1844.
m-Hydrozy-benzaldehyde. C7H6O2.
kAXlO* at 25**= 1.0 (cond.); is under 1.8 (co!orim.); m. p. 104**;
1397c.
At 25% A(16)-0.17, (32)-0.20, (oo)=380; 1397c. A(32)-3.8,
(64)-5.3, (oo)=356; m. p. 104**; 643.
Cond. with NaOH and HCl; 1608.
p-Hydrozy-benzaldehyde. C7H6O2.
kAXlO* at 25'*=2.2 (cond.); is under 8 (co!orim.); 1397c.
At 25% A(32)=0.29, (128)=0.63, (oo)=380; 1397c. A(64)»3.6,
(512)-10.3, (oo)=356; m. p. 116% 643.
Cond. with NaOH and HC!; 1608.
180 TABLES [Hyd
o-Hydrozy-benzoic add. (Salicylic acid). C7H6Qi»G6H4(OH)(C02H).
kA X10> at O'^^OM aq.; 616;-0.83; 1968a. At e.g^'^Q.d; 1968a.
At 17^=1.01 aq.; 164. At 18^=1 (colorim.); 1781, 1663.
At 20** « 1.04 aq.; 616. At 25''= 1.05; the extremes are
1.02 and 1.08 aq.; 473, 616, 1184, 1371, 1681, 1968, 1968a.
(neutral.); 1718. At 30^»1.09 aq.; 616. At SS'^-LOG;
1968a; 616. At 40''»1.12 aq.; 616; 1681. At 45''- 1.13
aq.; 616. At bO'^^l.U aq.; 616, 1681. At GO'^^Lll aq.
At 70**= 1.07 aq. At 80**- 1.01 aq. At 90^=0.95 aq. At
99''»0.87 aq.; 1681.
Cond.; 168, 170, 388a, 616, 1968, 1968a. At 25^ m(64)-80.1,
(1024) = 224.1,(oo)=357; 1371.
In HBr and HCl; 30. In NHs, qual.; 606. In SO2, no cond.;
1842. In Et ale; 632, 647, 1316, 1649, 1718. In other
organic solvents; 366,1689,1649; qual.; 934.
Cond. with boric acid; 1184. With NaOH; 168, 1091, 1608,
1718. With KOH; 170. With NH4OH; 169. With ani-
line; 146a, 169, 632. With allyl thiocarbimide, no cond.;
1223.
NH4.A; 146a, 166, 823. Basic NH4 salt; 166.- Cu.2A, qual.;
1090. - Li. A in NHs, qual.; 606. In organic solvents; 474,
482, 1689. - K.A; 164, 166. Basic K salt; 164. - Ag.A;
848.- Na.A at 25^ A(32)-68.3, (1024)=79.7; 270, 1091,
1199. At 25*'-99^ 1681. At 0*'-50^ 616. At 0^-35^
1968a. In NH«, qual.; 606. In organic solvents; 474,
647. With boric acid; 1199. - UO2.2A; 449.
o-Hydrozy-benzoic add amide. (Salicylamide).'
C7H70aN-C6H4(OH)(CONH2).
Hg salt, e. m. f . ; 963.
o-Hydrozy-benzoic add methyl ester. CsHsOs » C6H4(OH) (CO^Me) .
kxXlO" at 25^=1 (hydrol.); 666, 1694.
In NHs, qual.; 606.
o-Hydrozy-benzoic add phenyl ester. CisHioOs.
In NHs, qual. ; 606.
tso-o-Hydrozy-benzoic add. (iso-Salicylic acid). CtHsOs.
This acid, with kx XlO" at 25^=1.1, was shown to be an impure
salicylic acid; 473.
m-Hydrozy-benzoic acid. CrHeOj = C6H4(OH) (CO2H) .
In molten state, no cond.; 1066.
kxXlO^ at 0^-7.6 aq.; 616;-7.2; 1968a. At 13.2^=7.8;
1968a. At 17**= 9.27 aq.; 164. At 18*'=9.2 (colorim.);
1663. At 20^ « 8.29 aq.; 616. At 25°=8;-8.33 aq.; 616;=
7.60 aq.; m. p. 200**; 1186;=8.67; 1371;-7.98; 1968a. At
30**=8.33 aq. At 35^»8.30 aq.; 616;»7.95; 1968a. At
Hyd] TABLES 181
40^=8.26 aq. At 45'' « 8.20 aq. At 60** -8. 11 aq.; diinin.
ishes on diln.; 615.
Cond.; 168, 170, 616, 1608, 1718, 1968a. At 25^ m(32) = 18.2
(1024)^91.6, ( 00) -357; 1371.
In NHs, qual. ; 606.
Cond. with boric acid; 1186. With NTI40H; 169. With KOH;
170. With NaOH; 168, 1091, 1608, 1718. With aniline;
169.
NH4.A and basic NH4 salt; 166. - E.A; 164, 166. Basic K salt;
164.- Na.A at 25^ m(32)=69.7, (512)=78.6; 1091; 616.
p-Hydrozy-benzoic add. C^HaOj = C6H4(OH) (CO|H) .
kAXlO^at 0**=2.51. At 13.2**- 2.71; 1968a. At 17^=2.88 aq.;
164. At 18^-3.3 (colorim.); 1663; - 1781. At 25*^=2.86;
1371, 1968a;»2.8; 1091;-2.68 aq.; m. p. 213^ 1186. At
35*^=2.87; 1968a.
Cond. ; 168, 170, 1608, 1718, 1968a. At 25^ m(32) = 10.6, (1024) =
56.3, (00) =357; 1371.
In HCl; 30. In HBr, no cond.; 30. In NH3, qual.; 606.
Cond. with boric acid; 1186. With NH4OH; 169. With KOH;
170. With NaOH; 168, 1091, 1608, 1718. With aniUne;
169.
NH4.A and basic NH4 salt; 166. - E.A; 164, 166. Basic K
salt; 164.- Na.A at 25^ A(32)=68.8, (512)»77.0; 1091.
- Cinchonine. A; 1620.
Hydrozybenzyl hypophosphoric acid. C7H9OSP- Ph.CHOH.POH.OH.
Relative cond.; (the aniline salt has m. p. 99°); 1771.
2-Hydrozy-3-bromo-a-iiaphthoquinone. CioHsOsBr » OH.CioH40sBr.
K.A at 25^ A(32) = 75.8, (1024) =82.1; 1276.
Hydrozy-butenoic add see EthenylglycoUic acid.
a-Hydroxy-butyric add. C4H8Q8= Et.CHOH.COjH.
At 25^ m(32) = 16.9, (1024) =70.8, [in Hg.U.J; 1362.
/5-Hydroxy-butyric add. C4H808= Me.CHOH.CH2.CO2H.
kAXl05=3.1; 1640;=2 (colorim.); 804.
A(32) = 11.2, (1024) = 58.4, (oo)-358.7; 1640.
In £t ale, cond. alone and with boric acid; 1186.
Na.A, A(32) = 69.4, (1024) =82.9; 1640.
7-Hydroxy-bu^c add. C4H804= CH2OH.CH2.CH2.CO2H.
kAXl0fi=1.93. m(79.8) = 13.8, (319.0)=27.3, (oo)=358; 812.
Hydroxy-iso-butyric add. C4H8Q8= Me2.C(OH).C02H.
kAXlO* at 25**= 1.06; 1370, 1186; (colorim.); 1643. At 25^
m(32) = 20.1, (1024)=99.5, (®)=355; 1370.
In NHs, qual. ; 606.
Cond. with boric acid; 1186; qual.; 1184.
Na.A at 25^ m(32) = 67.7, (1024) =79.4; 1367.
182 TABLES [Hyd
a-Hydrozy-camphoronic acid see Camphoranic add.
jS-Hydroxy-camphoronic add. CgHMOz- CeHio(OH) (C02H)8.
kAXlO* at 25^«6.5; diminishes, then increases on diln.; 1372.
Second kAXlO<^==8.4 (inversion); 1638;»21; 1911.
At 25^ m(64) = 166.4, (1024)=316.8, (oo)=352; 1372.
2-Hydrozy-5-dilorobeiizoic add. (5-Chloro-salicylic acid).
C7H608C1=C1.C6H8(0H)(C02H). [C02H=1.1
kAXlO" at 25**= 1.97; increases on diln.; m. p. 172^ /i(320)-
191.5, (1280)=274, (a>)=356; 404.
8-Hydrozy-2-dilorobeiizoic acid. CrHsQsCl.
kAXlO* at 25**= 1.40; increases on diln.; m. p. 166*'-157^
m(256) = 158.3, (1024) -242.8, (oo)=356; 404.
S-Hydrozy-G-chlorobenzoic acid. CtHbQsCI.
kAXlO* at 25° « 1.40; increases on diln.; m. p. 178**.
m(64)=91.8, (1024) « 240.3, (oo)-356; 404.
4-Hydrozy-3-clilorobenzoic add. CrHeOsCl.
kAXlO^ at 25''=5.7; increases on diln.; m. p. 169*'-170'.
m(128)«29.1, (1024) = 77.6, (oo)=356; 404.
8-Hydroxy-2-chloro-6-bromobe]izoic add.
C7H404ClBr=(Cl)(Br)C6H2(OH)(C02H). [CO2H-I.]
kAXlO* at 25**= 2.4; diminishes on diln.; m. p. 11 6M 18'.
m(139.4)- 286.0, (1115.2) =343.9, (oo)-355; 404.
8-Hydrozy-6-chloro-2-bromobeiizdc add. C7H4C)sClBr.
kAXlO" at 25''=2; m. p. 194M95^ ^(128) = 139.5, (1024)-
256.4, (a>)=355; 404.
OF-Hydroxy-Jso-dnchomeroxiic acid. (6-Hydroxy-pyridine-2,5-dicar-
boxylic acid). C7H506N=C6H2N.(OH)(COjH)2.
kAXlO* at 25*'=1.67; diminishes on diln.; 1372.
Second kAXlO«=2 (cond.); 1911.
At 25^ m(128)=264, (1024)=337, (oo)=355; 1372.
Hydrozy-cinnamic add see Coumaric add.
Hydrozy-dehydroacetic add. CgHgOs.
kAXlO'=1.59; diminishes on diln.; m. p. 253*'-256* with dec.
m(512) =210.1, (1024) =245.8, (oo)=360; 668.
Cond. increased by boric acid; 1186.
Na.A, m(32)=63.4, (1024)=74.3; 668.
4-Hydrozy-3,6-dibromo-azobenzene. (Benzeneazodibromo-phenol.)
Ci2H80N2Bri= Ph.N2.C8H2Bi^(OH).
In pyridine; 764.
4-Hydrozy-3,6-dibromo-benzoic add.
C7H408Br2=OH.C6H2Bi^.C02H. [C02H=1.]
In Et ale, cond. alone, and with boric acid; m. p. 267^-268^;
1186.
Hyd] TABLES 188
2-H7drozy-3,6-dichloro-be]izoic acid. (3,5-DichloroH3alicylic acid).
C7H4O8CI2-OH.C6H2CI2.CO1H. IC02H=1.]
kAXlO* at 25^»4.65; diminishes on diln.; m. p. 219.5^
m(630)= 279.7, (1260) « 308.9, (®)==355; 404.
3-H7drozy-2,6-dicliloro-beiizoic add. C7H40sC]t.
kAXlO* at 25**= 2.26; m. p. 122M24^
m(128)= 279.4, (1024) =342.7, (00)- 355; 404.
m-Hydroxy-dimethyl-aniline see m-Dimethyl-aminophenol.
Hydrozyetiiyi sulphonic acid see Isethionic acid.
Hydroxy-fumaric add. C4H406= COaH.C(OH) : CH.COsH.
kAXlO* at 17*'=2.76; m. p. 184^
m(20)=70.4, (320)-201.1, (oo)=337.1; 1M2.
o-Hydroxy-glutaric add. CsHgOs^ C02H.(CH2)2.CHOH.C02H.
Co salt.- Mg.A at 18% m(32)-93.7, (1024) = 156.3. - Ni salt;
1736.
m-Hydroxy-hydrodnnamic add see m-Hydrocoumaric add.
Hydroxy-hydroquinone. (1,2,4-Trihydroxy-benzene).
C6H«Oi=C6H8(OH),.
Cond. alone and with NaOH; m. p. 140"*; 1508, 1718.
Hydroxy-hydroquinone aldehyde. (2,4,5-Trihydroxy-benzaldehyde).
C7H«04« (OH)8CeH2.CHO. [CHO- 1. ]
kAXlO*at25**=1.8.
At 25% m(128)-16.7, (1024)=45.2, (oo)=-355; 643.
Hydroxylamine. HsON=NHsOH. [The references to this are
incomplete. ]
xXlO^ at 33*^ is approximately 8; [in molten state]; 1176.
kfiXlO* at 15**=6.5 (colorim.); 1776. At 25^=7.4 (hydrol.);
1984.
Cond. at y(14.2), is no greater than that of pure water; 1984.
At 18% m(20)=0.4, (500)-1.4; 1176; A(500) = 19; 1631.
Cond. with NaOH; 1984.
B.HCl at 25% m(32) = 105, (1024) = 116; M(32)-107; 1984; 270,
599, 1531, 2029. In NH3, qual.; 606. In Me ale; 2029.
- B.HNO4; 1531. - B.H8PO4. - B.H2SO4; 599, 1531.
Hydroxy-maleic add. C4H406= C02H.C(0H) : CH.COsH.
kAXlO» at 17^=2.5; m. p. 152^
m(20)«68.5, (320) « 193.3, («)= 337.1; 1992.
Hydroxy-maleic add anhydride. C4H2O4.
Pyridine salt, in pyridine; 1991.
Hydroxy-malonic add see Tartronic add.
Hydroxy-inesitene-dicarboxylic add anhydride see iso-Dehydroacetic
add.
Hydroxy-methane sulphonic add. (Hydroxy-methyl- etc.)
CH4O4S-OH.CH2.SOjH.
184 TABLES [Hyd
kx XlO^ is about 4; the acid is 97% dissociated at v(256); 394.
K.A at 25^ A(32)«184.0, (1024)»243.1; 643. A(1024-32) of
tlie salts shows that the acid is monobasic; 394.
2-Hydrozy-3-methozy-be]izoic acid see Guaiacolcarboxylic acid.
4-Hydrozy-3-methoxy-benzoic acid see Vanillic add.
3-Hydrozy-4-methozy-benzoic add see iso- Vanillic add.
o-Hydrozymethyl-benzoic add. (Benzylalcohol-o-carboxylic acid).
C8H804-C«H4(COiH)(CH20H).
kAXlO* at 25^=1.51; diminishes on dUn. M. p. 120^ m(50) =
29.4, (1600) = 123, (oo)=363; 396, 827.
Hydrozymethylene-acetoacetic add ethyl ester.
C7Hio04« MeCO.C(:CHOH).COjEt.
kxXlO* at 3.7*'-3. At 23.5**=3; increases on diln. from dec;
b. p. 200** @ 750 mm.
At 3.7^ m(64.1)=8.7, (512.8) = 23.8, (oo)=202.6. At 23.5^
m(33.3) = 10.3, (266) =32; 387.
Hydrozymethylene-acetylacetone.
C6H8Q8=MeCO.C(:CHOH).COMe.
kx XlO* at 2.6** =2.2; m. p. 47*'-48^
m(32)=5.1, (256) = 14.2, (oo) = l95; 387.
Hydrozymethylene-malonic add diethyl ester.
CgHiaOs* COjEt.C( :CHOH) .COjEt.
kx is greater than that of acetic acid; b. p. 217^-219®; 887.
a-Hydrozy-naphthoic add. CuHgOs » CioH6(OH) (COsH) .
Cond. increased by boric acid; 1186.
2-Hydrozy-l,4-naphthoquinone. (Naphthalic acid).
CioHflOs = 0 H . CioHsOj .
Na.A at 25^ A(32) is about 71, (1024) is about 76; 1276.
a-Hydrozy-nicotinic add. (2-Hydroxy-pyridine-3-carboxylic acid.
a-Hydroxy-picolinic acid?). QHsQsN.
kxXlO* at 25*^=5.7; diminishes on diln. /i(128) = 9.6, (1024) =
25.1, (a>) = 357; 1372.
o-Hydroxyphenyl-acetic add. C8H8O4-OH.C6H4.CH2.CO2H.
Cond. in Et ale, alone and with NaOH; m. p. 137**; 1608,
1718.
p-Hydrozyphenyl-acetic add. CsHsOs.
Cond. alone and with NaOH; m. p. 148**; 1608, 1718.
p-Hydroxyphenyl-a-aminopropiomc acid. (Tyrosine).
C9Hn08N=OH.C6H4.CH2.CH(NH2).C02H.
kA X 10» at 25**= 4 (hydrol.) ;=67 (cond.).
Second kAXl0*«=4 (hydrol.).
kBXlO»2 at 25**=2.6 (hydrol.)
At 25^ m(512)-0.5, (1024) = 3, (®)=365; 947.
Hyd] TABLES 185
In NH|, qual.; 606.
Na.A at 25^ M(64)=68.3, (1024)=82.2; /i(64)-66.5. - 2Na.A,
M(128)- 166.4, (1024)- 196.7; m(128)-160. - B.HCl at 25^
M(256)-288.4, (1024)=351.3; m(256)-110; 947.
Hydrozy-phenyl-propionic add see Phenyl-hydroxy-propioiiic add.
Hydrozy-phenyltrimethyl ammonium hydroxide see Trimetliyl-
aminophenol.
o-Hydroxy-phenyl urethane. CaHuQsN-HO.CeHiNH.CO^Et.
X of satd. soln. at 25*'=6.2 XlO^.
With HCI, no change of cond.; 1660.
4-Hydrozy-o-phthalic add.
C8H«06=OH.CeHs(C02H)2. [COjH=l, 2; OH-4.]
lux 10* at 25^ » 1.2; probably contained a trace of iron; m. p.
181°. [Bentley, Weizmann, Jour. Chem. Soc. 91, 99,
(1907), say that the true m. p. is 204*^-205 ''; the acid m. p.
181° contains some 3-Hydroxy-phthalic acid.] m(32.1)»
67.9, (1033)=246.S, (oo)»377; 1909.
4-Hydroxy-o-phthalic add 1-mono methyl ester.
CaHgOs. [C02H=2; CO|Me«l; OH-4.]
kxXlO* [at25°l=1.54; m. p. 159M60°; 1932.
4-Hydroxy-o-phthalic acid 2-mono methyl ester.
CtHgOj. [C0|H=1; C0jMe«2.]
IcaXIO* at 25°=2.05; m. p. 166°.
m(63.7)=40.6, (1024) = 136.7, (oo) = 375; 1909.
4-Hydroxy-o-phtlialic add dimethyl ester.
CioHioOs- OH.C6H8(COjMe)2.
kxXlO' at 25°- 1 aq. m(127.4)-1.5, (1022)-3.1, (oo)«374;
1909.
2-Hydrozy-p-phthalic add. (2-Hydroxy-terephthalic acid).
C«H«06. [COjH=l, 4; 0H=2.]
kAXlO^ at 25°-2.7; increases on diln.; 1372, 1909.
Second kxX 10^ -2.1 (inversion); 1638;»4.5 (cond.); 1911.
At 25°, /i(256) = 198.5, (1024) -290.5, (oo)-355; 1372.
2-Hydrozy-p-phtlialic add 1-mono methyl ester, (a- ester).
CaHsOs. [C02H-4; CO|Me-l; OH-2.]
kxXlO* at 25°- 2.50; m. p. 206°-208°.
m(910)-141.3, (1820)-181.8, (oo)-375; 1909.
2-Hydroxy-p-phthalic add 4-mono methyl ester. (/9- ester.)
CgHgOs. [C02Me-4.]
kA Xl0» at 25°- 2.77; m. p. 175°-176.5°.
m(255.7)- 209.0, (1026)-294.9, (oo)=375; 1909.
a-Hydroxy-picolinic add see a-Hydrozy-nicotinic add.
/3-Hydrozy-picolinic acid see Comanamic add.
186 TABLES [Hyd
Hydrozy-pimelic add anhydride. C7H10O4-G6H9Q1.CQ1H. [A lac-
tone acid of pimelic acid.]
kAXlO^ at 25*^=2.76; diminishes on diln.; m. p. 82.5^.
m(32) = 11.0, (1024) = 57.4, (oo)=376; 1976.
Hydrozy-piyalic acid. (Hydroxy-trimethyl-acetic acid).
CeHioOi- Me2.C(CH2.0H)C02H.
kAXlO* at 25^-1.39; m. p. 124^
m(32)-7.8, (1024)=42, (oo)=376.4; 1216.
a-Hydrozy-propiomc add see Lactic add.
jS-Hydrozy-propionic acid see Hydracrylic add.
4-Hydrozy-pyridine-2,6-dicarhoxylic add see Ammonchelidoiiic add.
6-Hydrozy-pyridine-2,5-dicarbozylic add see a-Hydrozy-uo-cin-
chomeronic add.
2-Hydroxy-quinoUiie see Carbostyril.
p-Hydrozy-quinoHne-o-carbozylic add. CioHyOsN.
Cond. increased by boric acid; m. p. 260''-262** with dec; 1186.
Hydroxy-salicylic add see Dihydrozy-benzoic add.
2-Hydrozy-6-8ulphobenzoic add see 5-Sulphosalicylic add.
8-Hydrozy-o-toluic add. (m-Homo-salicylic acid).
C8H8Q8-Me.CeH8(OH)(COjH). [Me=l; COjH-2; 0H=3.]
kAXlO»=1.06; 1670. A(l 194.0) =234.5; 1672.
6-Hydrozy-o-toluic acid. (jS-o-Homo-m-hydroxy-benzoic acid).
CsHgOi. [Me=l; C0aH=2; 0H=6.]
kxXlO* at 25''= 1.69; diminishes on diln.; m. p. 183^
/i(256)=66.5, (1024) = 118.7, (®)=355; 1429.
S-Hydrozy-m-toluic add. (jS- or o-Cresotinic acid. o-Homo-sali-
cylicacid). CgHgOs- [Me=l; C0iH=3; 0H=2.]
kAXlO* at 18''= 1.15 (colorim.); 1663. At 25''= 1.03; diminishes
on diln.; 1186, 1429, 1670.=0.98 aq.; 1186.= 1.06; 1429.
At 25^ m(512) = 178, (1024) = 218, (oo)=354; 1186.
InEtalc; 1186.
Cond. with boric acid; m. p. 166**-167^• 1186, 1186.
4-Hydrozy-m-toiuic add. (a- or p-Cresotinic acid. p-Homo-sali-
cylicacid). CgHgOj,. [Me=l; C02H=3.]
kxXlO* at 18''=11 (colorim.); 1663. At 25*'=8.9; diminishes
on diln.; m. p. 151^ 1186, 1429, 1670.
At25^M(512) = 172, (1024)=212, (oo)=354; 1186.
In Et ale. ; 1186, 1608.
Cond. with boric acid; 1186, 1186. With NaOH; 1608.
8-Hydrozy-p-toluic add. (7- or m-Cresotinic acid. m-Homo-sali-
cyHc acid) . CgHgOj. [Me= 1 ; C0jH=4. ]
kAXlO* at 18''=6.5 (colorim.); 1663. At 25''=7.5; diminishes
on diln.; m. p. 177^ 1186, 1429;= 6.8; 1670.
At25%M(512) = 162, (1024) = 202, (oo)-354; 1186.
Hyd] TABLES 187
InEtalc; 1186.
Cond. with boric acid; 1186, 1186.
6-Hydroxy-o-toliiic aldehyde. (m-Homo-p-hydroxy-benzaldehyde).
C8H80i-Me.C6H8(OH).CHO. [Me-1; CH0=2; OH-5,]
kAXlO* at 25^=2.95; m. p. 110^
/i(128)-6.8, (1024) = 18.8, (oo)=354; 643.
2-Hydroxy-m-toIuic aldehyde. (o-Homo-salicyl aldehyde).
CgHsOi. lMe=l; CH0=3; 0H=2.1
kAXlO* at 25^-1.62; b. p. 208**.
/i(128) = 15.2, (1024) =41.5, (oo)«354; 643.
4-Hydrozy-m-toIuic aldehyde. (p-Homo-salicyl aldehyde).
CgHgOj. [Me=l; CH0=3; 0H=4.1
kAXlO* at 25''- 2. 17; m. p. 56^
/i(256) = 25.4, (1024)=49.3, («)=354; 643.
6-Hydrozy-m-toluic aldehyde. (o-Homo-p-hydroxy-benzaldehyde).
CgHsOj. [Me-1; CH0=3; 0H=6.]
kxXlO^ at 25*'-4.66; m. p. 118^
m(128)=8.5, (1024) =23.6, (oo)=354; 643.
8-Hydroxy-p-toliiic aldehyde. (m-Homo-salicyl aldehyde).
CgHsOj. [Me=l; CH0=4; 0H=3.1
kAXlO« at 25^-7.62; b. p. 220^
/i(256) = 15.3, (1024) -29.9, (oo) = 354; 643.
Hydroxy-triazolinacetic add see Methyl-hydrozy-triazole carbozyUc
add.
4-Hydrozy-2 ',4 'fi '-tribromo-azobenzene. (Tribromo-benzene-azo-
phenol). C1aH7ON2Bri-Br8C6H2.N2.C6H4.OH.
In pyridine; 764.
Hydrozy-trimethyl-acetic add see Hydroxy-piyalic add.
Hydrozy-trimethyl-phenyl ammonium hydroxide see m-Trimethyl-
aminophenol.
a-Hydrozy-ajS/3-trimethyl-propionic acid.
C6Hi208=Me2CH.CMe(OH).COjH.
kAXlO*=1.14; m.p. 75*^-77*'; 1411.
/3-Hydrozy-aj9/3-trimethyl-propionic add. (terfoary-Trimethyl-ethyl-
enelactic acid). C6Hi208=MQ2C(OH).CHMe.C02H.
kxXlO* at 25*^=3.5; diminishes on diln.; b. p. 160** @ 35 mm.;
640, 1411, 1704.
M(39.5) = 13, (632) =47, (00) =351; 1704.
Hydrozy-trimethyl-sucdnic add.
C7Hi206-C02H.C(OH)Me.CMe2.C02H.
kAXlO^ at 25''=9; [the values 8.46 in 64, and 9.38 in 229,
differ because of the use of different values of m(® )]; m. p.
151'', 153^ 159"* depends on mode of heating; 64, 229, 1418.
188 TABLES [Hyd
m(28)-52.3, (112)=97.1, («>)-351; 229. m(1 112.5) -214.7, («)
-353; 64.
Hydroxy-uracil see Ozyuracil.
a-Hydrozy-yaleric acid. CeHioOs = Me. (CH2)2.CHOH.C02H.
kAXlO* at 25^-1.32 aq.
m(»4)=30.7, (512) -79.8, (oo)=350.
Cond. with boric acid; 1186.
7-Hydrozy-yaleric add. CsHioOj- Me.CHOH.(CH2)2.COjH.
kxX 10^-2.07; diminishes on diln.
m(36.4)-9.7, (1163.2) -50.4, (oo)-358; 812.
Hyoscyamine. (1-Tropic acid tropine ester). CnHnOsN.
At25^ m(100)-18.1, (800) -38.6; 1864. [Hyoscyamine is partly
decomposed by aq., therefore the cond. may be due to
tropic acid].
I.
Imido see Imino.
Iminobenzoic acid iso-amyl ester. (Benzimino amy! ether).
CBHi70N-Ph.C(NH)O.C6Hu.
keXlO^ at 25**- 1.7 (hydro!.); 1233, 1667.
B.HClat25^ A(32)-86.7, (256)-95.3; M(32)-88.5; 1233.
Iminobenzoic add tso-butyl ester. CiiHi60N=Ph.C(NH)0.i8o-Bu.
kBXlO« at 25^-1.25 (hydrol.); 1233, 1667.
B.HCl at 25% A(32)-85.8, (256) -95.8; M(32)-87.7; 1233.
Iminobenzoic add ethyl ester. (Benzimino ethyl ether) .
C9HiiON-Ph.C(NH)O.Et.
kBXlO^ at 25**-l.l (hydrol.); b. p. 115° @ 21.5 mm.; 439,
1667.
B.HCl at 0^ 1690. At 25% A(32)=83.4, (256)-92.4; M(32)-
85.1; 439.
Iminobenzoic add methyl ester. C8H»0N-Ph.C(NH)0.Me.
kB XlO* at 25^-4.7 (hydrol.); b. p. 104** @ 20.5 mm.; 439, 1667.
B.HCl at 0^ 1690. At 25% A(32)-86.5, (256)-94.5; M(32)-
89.7; 439.
Iminobenzoic add norm.-propyl ester. CioHisON-Ph.C(NH)O.Pr.
kaXlO* at 25*'-1.54 (hydrol.); b. p. 121** @ 16 mm.
B.HCl at 25% A(32)-82.4, (256)=91.1; M(32)-83.6; 439.
Iminobenzoic add tso-propyl ester. CioHuON.
kBXlO* at 25^-1.8 (hydrol.); b. p. 114° @ 20 mm.
B.HCl at 25% A(32)-82.0, (256)-90.1; M(32)-83.9; 439.
Iminomethyl- see Methylimino-
Imino-/3-naphthoic add ethyl ester. CuH]BON-CioH7.C(NH)O.Et.
kBXlO» at 25°-7.9 (hydrol.); 1233, 1667.
B.HCl at 25% A(32)-87.8, (256)-96.6; M(32)-90.0; 1233.
lod] TABLES 189
Imino-m-nitrobenzdc acid ethyl ester.
CtHioQsNj- N0j.C«H4.C(NH)0.Et.
keXlO' at 25**«1 (hydrol.); 1238, 1667.
B.HCl at 25% A(32)=88.1, (256)=96.9; M(32)-94.1; 1288.
Imino-m-mtrobeiizoic add methyl ester.
C8H8Q8N,=-NOi.CeH4.C(NH)O.Me.
kB XlQi® at 18**-3.7 (hydrol.); m. p. 50.6^
B.HCl at 18% A(32)=73.8, (256) = 80.8; M(32)=79.3; 439.
Imino-phenylacetic add ethyl ester. CioHuON.
kB X10» at 25*'=4 (hydrol.).
B.HCl at 25% A(32) = 85.6, (128)=93.2; M(32)-90.1; 1233.
Imino-o-toluic add methyl ester. C^HuON.
kBXlO» at 25*'-2.3 (hydrol.).
B.HCl at 25% A(32)=94.8, (256) = 103.3; M(32)=99.0; 1233.
Imino-p-toluic add ethyl ester. CioHuON»Me.C6H4.C(NH)0.£t.
kBXlO* at 25**= 1.97 (hydrol.); 1233, 1667.
B.HCl at 25% A(32)=88.0, (256)-95.2; M(32)-89.1; 1233.
Indenone see Indone. [Derivatives given in 1666.]
Indigo.
In MeNHs, good cond.; 637.
Indigo White. Ci6HuO1N2-OH.C1eH10N2.OH.
Mono Na salt at 18% m(19.4)»62.6, (37.9)=67.7; 976c.
Measurement of an impure salt; 976b.
Pr-2-(a)-Indolecarboxylic add. CaHrOiN.
kAXlO* at 25**= 1.77 aq.; m. p. 204**.
A(173.2)=56.4, (1385.6)- 136.1, (oo)-352; 23.
Pr.3-(j9)-Indolecarboxylic add. C9H7O2N.
kAXlO^ at 25**-5.6 aq.; diminishes on diln.; m. p. 218**.
A(700)-21.5, (1400)-29.3, (oo)»352; 23.
Indophenosafranine see syiiL-Phenosafranine.
Indozylic add ethyl ester. CnHuOsN.
In pyridine, almost no cond. ; 764.
Inosinic add. C10HUO8N4P.
kAXlO* at 25**= 1; diminishes on diln. m(32)-161, (1024)-
243.6, (00) = 373.
2Na.A at 25% A(32)-66.8, (1024)-87.7; 708.
Intestinal juice. [The references to this are incomplete.]
Concentration of H and OH ions; 687.
Invertin.
Concentration of H ions; 1639b.
led- see lodo.
lodoacetic add. C2H8Q2I - CH2I.CO2H.
kAXlO* at 25*^-7.1; m. p. 82^
190 TABLES [lod
A(32)=50.6, (1024)»207, (oo)«362; 1840.
In acetone; 476.
lodoacetic acid ethyl ester. C4H708l«CHsI.COsEt.
In SO2, Httle cond.; b. p. 178**-180^ 1829, 1842.
lodobenzene. CeHsI.
In SO2, no cond.; 1829, 1842. In NHs, qual.; 606.
o-Iodobenzoic add. C7H6O2I » I. C6H4. CO2H.
kAXlO* at 25*'=1.32; m. p. 226**; 63, 1681. At 40^-1.1 aq.
At 50''=0.93 aq. At 60*^=0.78 aq. At 70*'-0.68 aq. At
80*'-0.58 aq. At 90*^=0.49 aq. At 99*'«0.42 aq.; 1681.
[At 25M A(169)-134, (1352) = 254, (oo)=[3561; 63.
K.A; 1728. - Na.A at 25^ A(64)=:64.2, (128) =67.4; 1728;
A(1024)-75.0; 1681.
m-Iodobenzoic add. CyHsOsI.
kAXlO* at 25*^=1.63; diminishes on diln.; 176. At 60*^=1.25
aq. At 70^=1.2 aq. At 80*^=1.1 aq. At 90*^=1.0 aq.
At 99''»0.94 aq.; 1681.
At 25^ A(1357) = 132.5, (2714) = 166.8, (oo)=356; 176.
p-Iodobenzoic acid. CrHeOsI.
Cs.A.- K.A.- Na.A at 25^ A(64)=66.0, (128)»67.4.- Rb.A;
1728.
7-Iodobutyiic add. C4H702l= CH2l.(CH2)2.C02H.
kAXlO' at 25**=2.3; m. p. 40*^-41^; 1099 and 1908.
A(32) = 10.2, (64) = 14, (oo)=356; 1099.
Iodoform see Triiodo-methane.
lodomethyl-triethyl ammonium chloride.
C7Hi7NCiI=(CH2l)(Et«)N.Cl.
At 26**, A(32)=86.1, (1024) = 98.6; 270.
lodomethyl-trimethyl ammonium chloride.
C4HuNClI= (CH2l)(Me8)N.Cl.
At 25^ A(32)=92.6, (1024) = 105.2; 270.
jS-Iodopropionic add. C8H6O2I - CH2LCH2.CO2H.
kA XlO' at 25*^=9; aq. used for soln. was not pure; 1370.
A(32) = 18.6, (1024) =90.7, (oo)=358; 1370.
In SO2; 1842.
Na.A at 25^ A(32) = 66.9, (1024) = 78.6; 270.
lodosobenzene. CqHbOI = Ph.IO.
In NH3, qual. ; 606.
o-Iodosobenzoic acid. C7H608l= C6H4(IO).C02H.
kAXlOMat25°l=6; m. p. 226''to244**; varies with mode of
heating.
A(224)=4.4, (896)=8.2, (00)= [356]; 63.
4-Iodo-2-toluidine-6-8ulphomc acid.
C7H808NIS=Me.C«H2(NH2)(I).SQ|H. [Me=l; NH2=2.]
Ita] TABLES 191
IcaXIO^ at 25^ is about 5; decomposes during measurement.
/i(256)- 123.5, (1024)- 144.3, (oo)=[355]; 492.
Modovaleric add. CsHaOgl^ CH2l.(CH2)8.CO|H.
kxXlO* at 25**-1.7; m. p. Se^'-S?**; 1099 and 1908.
A(64) = 12.3, extrapolated, (oo)«:354; 1099.
lodoxybenzene. QHsC^I.
In NHs, qual.; 606.
Iridium cyanic acid. QHsNelr- HsIrCCNJe.
3Ba.2A. - 3Cu6NH8.2A. - 3K.A at 25^ A(32)= 136.0, (1024)-
173.3; 1494.
Iron see Diferri-pentaacetyl-hydrozide, Ferricyanic add, Ferri-
diacetyl bromide, Ferri-diacetyl chloride, Ferri-oxalic add,
Ferrocyanic add, Ferro-oxalic add, Hydronitroprusdc add^
Ozyhaemogiobin.
Isatin see o-Aminobenzoyl-formic acid anhydride.
Isatinic add see o-Aminobenzoyl-formic acid.
Isatoic acid see o-Aminobenzoyl-formic add.
Isatoxime. (Nitroso-oxindole). CgHeOsNz.
kAXlO® at 25**=2.8 (catal.);«0.02 (cond.); m. p. 202'.
m(480)=0.1, (960) -0.2, (oo)==351; 762.
Isethionic add. (Hydroxyethyl sulphonic acid).
C2H6O4S-OH.CH2.CH2.SO4H.
kAXlO^ is approximately 4; the acid is 97% dissociated at
v(256); A(1024-32) of the salts, shows that the acid is
monobasic; 394.
Iso see under letter beginning the next word; e, g. tso-Amyl is given
under Amyl.
Itaconic add. C6H«04=COjH.CH2.C(:CH2).C02H.
k^XlO^ diminishes on diln. at all temperatures above 17*^. At
0^-1.24; 1968a. At 17^=1.44 aq; 164. At 18*»-1.6
(colorim.); 1663, 1781. At 18.1*'-1.45; 1968a. At 25**-
1.51; m. p. 161^ 1638, 1968a;= 1.21; 1372, 1600b. At
35''- 1.55; 1968a.
Second kAXlO*-2.2 (part, and inversion); 370, 1638.
Cond.; 170. At 0^-35^ 1968a. At 25% m(32)-23.7, (1024)-
113.3, («>)=13511; 1968a. m(44.4)-25.2, (a>)-355; 1372.
Cond. with KOH; 170.
Mg.A; 1836.- Na.A; 370.- 2Na.A at 25% A(32)-80.7, (1024)
-97.0; 270, 370.
Itaconic add anhydride. C6H4O8.
Cond. showing change to acid; 1600b.
192 TABLES [Ket
K.
Ketofluorene see Fluorenone.
Ketoindene see Indone. [Derivatives given in 1666.]
Ketozime-acetic-carbozylic acid see Oximinosuccinic acid.
Kidney. [The references to this are incomplete. ]
Cond. ; 166a, 623 and 263.
Kinase. [The references to this are incomplete.]
Cond. of gelatin soln. containing kinase; 807, 808.
L.
Laccase. [The references to this are incomplete. ]
X at 17** of 0.9866 g in 60 cc. aq. = 4.486 XlO"*; 626.
Lactic acid. (a-Hydroxy-propionic acid).
CaHflOs- Me.CH(0H).C()2H.
kAXlO* at 25^=1.4; 1370, 1184;=3.1; 667, and Ostwald, Zeit.
Phys. Chem. 32, 163, (1900), for a commercial preparation.
Relative strength (colorim. etc.) ; 693, 1643, 1781.
Cond.; 320a, 642, 1636, 1496. At 25% m(32)=23.1, (1024) =
109.7, ( 00) -358; 1370.
In HBr, no cond.; 30. In NHs, qual.; 606.
Cond. with boric acid; 1184. With GIO; 320a. With MoOs;
1496. With acetone; 1669. Under pressure of 1-260 at-
mospheres; 642.
Ca.2A; 1199. - Fe.2A in NHs, qual.; 606. - K.A; 1367. - Na.A
at 25^ m(32)-69.6, (1024) -79.8; 1368a, 1367. Under
pressure of 1-260 atmospheres; 642. - UQ2.2A; 449. - Zn.2A
in NHs, qual. ; 606.
Lactic acid cyanoamide. (Lactocyanoamide).
C4H602N2= Me.CH(OH).CO.NH(CN).
kxXlO^ at 26^»3; diminishes on diln.; decomposed?
iu(33.1)-l.l, (264.8)=2.2, (a>)-355; 70.
Lactic acid ethyl ester. CsHioOs.
In NHs, qual. ; 606.
Lactic acid nitrile. (Lactonitrile). CsHbON- Me.CH(OH) (CN).
xXlO* at -68*^=0.5. At -52*^=1.4. At -15**= 12; 1863a. At
0°=0.18; 1844;=24; 1863a. At 25^=0.311; b. p. 83.9** @
12-20 mm.; 1844, 1843; » 44; 1863a.
Cond. as solvent of NEt4l ; 1844, 1863a.
Lactocyanoamide see Lactic acid amide. #
Lactonitrile see Lactic acid nitrile.
Lun] TABLES 198
Lactose. C]2H220u.
X at 25^ of 4.275 g (anhydrous) in 100 cc. aq. -0.2218; 1747; 322.
In NH«, qual. ; 606.
Cond. with organic and inorg. compounds; 1747.
Laevulinic acid. (/3-Acetopropiomc acid).
CsHga^ MeCO.CHj.CHj.COjH.
kAXlO* at 0^=2.11; 701. At 25^»2.7; b. p. 150M55^ @ 10
mm.; 202;-2.65; 1370;=2.4; 701, 1186. At 35.5^-2.29;
701.
Cond.; 701, 782. At 25^ A(32)=9.9, (1024) -52.5, («)-352;
1370.
InEtalc; 782,1185.
Cond. with boric acid; 1186, 1185; qual.; 1184.
Gl complex salt; 1711. - Na.A, alteration of cond. by KOH; 496.
Lactulose see Fructose.
iso-Lauronolic acid see iso-Campholytic acid.
Lauth's ^olet see Thionine.
Lecithin. C^HwOaNP or CttHsoOaNP or CuHsoOuNP.
Cond. of dil. soln. of lecithin from various sources; 1121.
Lepidine. (4-Methyl quinoline). CioHoN.
B.HCl at 25% A(64)-92.0, (256)-95,9; 270.
Leucaniline see Tri-p-aminotriphenyl-methane.
Leucine see Aminocaproic acid.
Leuconic acid. C5H8O9.
At 25% /i(54.8)-48.6, (1752.4) -60.0; 389.
Leucotannic acid see Tannic acid.
Leucylaminoacetic acid. (Leucylglycine).
C8Hi6QjN,-C4H9.CH(NH2)CO.NH.CH2.CO,H.
kA X10» at 25*^-1.5 (hydrol.).
kaXlO" at 25*^-3 (hydrol.); 519, 622.
Cond. with NH« and HCl; 622.
Ley- see Laev-
Limonene. (Carvene). CioHie.
xXlO^ at 18*^-3.3; 386.
In NH», qual.; 606. In SOi, little cond.; 1842.
Cond. with organic compounds; 386.
Linseed oil. [The references to this are incomplete.]
x; 1010, 1471.
Liver. [The references to this are incomplete.]
Cond. ; 156a, 623 and 263.
Concentration of H and OH ions in cell fluid; 587.
Lung. [The references to this are incomplete. ]
Cond. ; 156a, 623 and 253.
194 TABLES [Lut
Lutidine see 2,6-Dimethyl-pyridme.
Lutidine-dicarbozylic acid see Dimethyl-pyridine-dicarbozylic acid.
Lutidinic acid see Pyridine-2,4-dicarbozylic acid.
Lymph. [The references to this are incomplete.]
Cond.; 166a, 263, 268, 1137a, 1806.
Concentration of H and OH ions; 687.
Lysine. (aeDiamino-caproic acid).
C6Hi402N2=NH2.CH2.(CH2)8.CH(NH2).CO,H.
kAXlO" at 25^ is about 1 (hydro!.).
kB XlO^ at 25** is less than 1 (hydroL).
Second kaX 10"= 1.1 (hydroL); M8.
Cond.; 146b.
B.2HC1 at 26^ M(64) -331.0; /i(64) = 210.0; 048. B.Carbonate;
146b.
M.
Magdala Red see Naphthalene Red.
Malamic acid see Malic acid mono amide.
Maleic acid. C4H404= CO2H.CH :CH.C()2H.
kxXlO^ diminishes, then increases on diln. At 0^^1.4; 1968a;
1018. At 12°= 1.45; 1968a. At 18**= 1.3; 460; - (colo-
rim.); 1663, 1781. At 22°= 1.18 aq.; 164. At 25°= 1.3;
1372;= 1.54; 1968a;=1.2; 1600b. At 35°= 1.51; 1968a.
Second kAXlO^=2.0 (part.); 370;=3.9 (inversion); 1638;=5.5
(inversion); 1336; 2.6 (cond.); 370;=80? (cond.); 1911.
Cond.; 170, 1600b, 1608, 1630, 1718, 1968a. At 25°, m(32) = 168,
(1024)=331, (a>) = 357; 1372. /i(32) = 175.4, (1024)=337.9;
(oo)»353; 1968a.
In HCl, good cond. ; 30.
Cond. with inorg. and organic acids; 1630. With KOH and
NaOH; 170, 1608, 1718. With aniline; 146a.
2(NH4).A; 146a. - Gl complex salt; 1711. - Mg.A; 319, 1836.
- K.A and 2K.A; 164. - 2Na.A at 25°, m(32)=90, (1024) =
108; 370; - 270, 1837, 1838. Alteration of cond. by KOH;
496. - Na.A; 370. - Zn.A; 319.
Maleic acid anhydride. C4H2O3.
xxl0^at60°=1.19; 1843.
Cond. of soln. showing change to acid; 1600b.
Maleic acid mono ethyl ester. C6H804=C02H.CH:CH.COsEt.
kAXl0« at 25°=1.10. /i(51.0)=74.9, (816.0) = 212.0, («>)=354;
1869.
Malic acid. C4H606-C02H.gH2.CH(OH).C02H. [Probably 1-malic
acid in all measurements. ]
Mai] TABLES 195
kAXlO* at 17**=3.83 aq.; 164. At 25**«4.0; m. p. 100**; 1372,
1824, 1186; (colorim.); 1643, 178L
Second kAXlO*=7.5 (cond.); 1911.
Cond.; 642, 691, 1496, 1618. At 25^ /i(32)-37.9, (1024) « 166.6
( 00) =356; 1372.
In HBr and HCl, no cond.; 30. In NH«, qual.; 606. In Et ale;
1186.
Cond. with boric acid; 1186, 1186; qual.; 1184. With MoQt;
691, 1496, 1618. Under pressure of 1-260 atmospheres; 642.
Go. A; 1736. - Cu.A; 319. - Gl complex; 1621. - Mg.A; 1736,
1836. - Ni.A; 1736. - K.A; 164, 1648. - 2KA; 164, 496,
688.- NaA; 1838; qual.; 1643.- 2Na.A at 25^ A(32)«
82, (1024) = 100; 270, 1838. Under pressure of 1-260 at-
mospheres; 642. - Complex salt; with MoO^ and WO^;
692; with Zr(>2; 1648.
1-Malic acid mono amide. (Malamic acid).
C4H704N=C()2H.CH2,CH(OH).CONHa.
IcaXIO* at 25°=2.86; diminishes on diln.; m. p. 149^
A(32)=32.5, (1024) = 146.1 (a>)=356.
Na.A at 25^ A(32)=67.1, (1024) = 76.5; 1166.
1-MaUc acid dimethyl ester. C6Hio06-C08Me.CH2.CH(OH).C02Me.
xXlO' at 0^=2.98; 1844. At 25^=5.45; 1843, 1844, 1830.
In organic solvents; 1830.
As solvent of NEtil; 1844.
ihac/.-MaUc acid. CiHeOj- C()2H.CH2.CH(OH).C()2H.
kAXlO* at 25*^=4.0; m. p. IBOMSl^ 1824; 1372.
Second kAXlO'=8.3 (inversion); 1638; =5.5 (cond.); 1911.
Malic add from Crassulaceae. C4H6O6.
Nasalt, /i(32)=79.98, (1024)=98.84; 11.
Malonanilic add. (Anilinomalonic acid).
C9Ha08N=C02H.CH2.CO.NH(Ph).
kAXlO* at 25^=1.96.
A(64) = 37.1, (1024) = 126.3, (a>) = 350; 1372.
Malondihydroxamic add. (Malonhydroxamic acid).
C8H604N2* (N.0H)CH.CH2.C(N.0H)H.
kA XlO^ at 25"*= 6; increases on diln.
m(32)=0.5, (128) = 1.1, (00)= [400]; 1363a.
Malonicadd. C3H404-»CH2(C(>2H)2.
kA at 10« at 0^=1.48; 1968a, 1887;= 1.36 aq.; 1018. At 4.9**=
1.52; 1968a. At 17**= 1.64 aq.; 164. At 18^=1.6 (colorim.);
1663, 1781. At 25^=1.63; m. p. 131^-132°; 1838, 1968a,
1968;=1.58; 1371;=1.71; 176. At 35^=1.63; 1968a. Rel-
ative value; 1866.
196 TABLES [Mai
Second kAXlO'-2.0 (part, and cond.); 870;-»1.0 (inversion);
1638, 1336 ;» 10 (cond.); 1911. Relative value; 1866.
Cond. ; 164, 171, 176, 370, 388a, 1018, 1371, 1887, 1968, 1968a.
At 25°, /i(32)=73.0, (1024)=250.8, (oo)-368; 1838.
In HBr and HCl, no cond.; 30. In N2O4, no cond.; 602. In Et
ale; 647, 1690a.
Cond. with KOH; 171. Under pressure, in alcohols; 1690a.
Under pressure at 0°; 1708a.
2(NH4).A; 1126. - Ba.A; 469. - 2Cs.A; 1126. - Ca.A; 469.
- Co.A; 1126, 1736. - Mg.A; 1736, 1836. - NiA; 1736.
K.A; 164. - 2K.A; 164, 1126. - Na.A; 1838, 370. - 2Na.A
at 25^ A(32)=91.7, (1024) -112; 370; 494, 1367, 1838.
-2Rb.A; 1126. - Sr.A; 469. - " Double " salts; 1126.
Malonic add di-amide. (Malonyl amide). C3H6O2N2.
Hg salt, e. m. f . ; 963.
Malonic acid mono ethyl ester. C6H804»CO|H.CH2.CO|Et.
kAXlO^ at 25^-4.6; increases, then diminishes on diln.
/i(17.1)-30.3, (274.2) -104.1, (a>)=356; 1869.
Malonic acid diethyl ester. C7Hi204-CH2(CO|Et)2.
kA at 25° is not very different from that of aq.; (hydrol.); 666;
-1.6x10^^; increases on diln.; 1816.
Cond.; no cond. in aq.; 844, 1298. [Cond. is probably due to
sapon.l At 25^ /i(128)-0.17, (256) =0.15; 1831; - 1816.
Effect of temperature on cond.; 106.
In HBr, good cond.; 1897. In NHs, qual.; 606. In Et ale,
little or no cond. ; 1816, 1298.
Malonic acid dimethyl ester. C5H804-CH2(C02Me)2.
xxlff at 0^-0.794. At 26'*- 1.20; b. p. 181M82*» @ 762 mm.;
1843, 1844.
Cond. at 25^ A(64)-0.49, (128)-0.63; 698.
Cond. as solvent; 1844.
Malonitrile. C3H2N2-CH2(CN)2.
At25%/i(64)=0.37; 698.
Malonyl amide see Malonic add di-amide.
Malonyl urea see Barbituric acid.
Maltose. C12H22OU.
In NHs, qual. ; 606.
Cond. with potassium tartrate; 1468.
Mandelic acid see Phenylglycollic acid.
Manganese cyanic add. C6H3N6Mn-H8Mn(CN)6.
3K.A at 25^ A(32)- 126.3, (1024)- 143; 1832.
Mannide phosphoric add see Phosphoric add mono mannide ester.
Mamiite see Mannitol.
Mes] TABLES 197
d-Mannitol. (Mannite). C6Hi405«CH80H.(CHOH)4.CH20H.
At 25'', m(33.1)»0.17; 1618. Also; 322, 944, 1434. Cond. of.
satd. soln. ; 1179, 1189.
In HBr and H2S, no cond.; 1897. In NHs, qual.; 606.
Cond. with boric acid; 944, 1179, 1183, 1189, 1316. With MoO^;
1618. With inorg. salts; 748. With oxalic acid; 46.
Meconic add. (Hydroxy-chelidonic acid).
C7H407« CsHOj. (OH) (C02H)2.
At 25^ iu(32)-413, (1024)=664; 1186; 1372.
Cond. with boric acid; 1186.
Meldola Blue. (j8-Naphthol Violet. New Blue R). A salt of Dime-
thyl-phenonaphthoxazine. CigHuONs.
B.HClat25^ A(64)=78.1, (1024)=92.0; 741.
MeUitic acid. CuHeOu = C6(C(>2H)e.
Cond. at 10^ 164. At 25% m(69.9) =421.6, (1118.4) =717.7; 176.
6K.A; 164.- Na.A at 25% /i(32) = 171, (1024)=313.- 2Na.A.
- BNa.A. - 4NaA. - 5Na.A. - 6Na.A at 25% /i(32)=68,
(1024) = 122; 1838.
Menthol. CioH2oO=CioHi9.0H.
In HCN, no cond.; 943. In NHs, qual.; 606.
1-Menthone. CioHigO - C9H18. CO.
Cond. in organic solvents; b. p. 81° @ 21 mm.; 1763.
Menthyl amine. CioHsiN^ C10H19.NH3.
B.HCl at 25% A(32)=82.0, (1024)^93.4; 270.
Mercury.
See compounds that follow; see also Trimercury-diacetone hy-
droxide. *' Double " salts and complex salts, see; 149, 246,
604, 689, 786, 841, 907, 1008, 1094, 1379, 1486.
Mercury cyanic acid. (Mercurocyanic acid).
C4H2N4Hg-H2Hg(CN)4.
2K.Aat25%A(32) = 113.1, (1024) -134.8; 1832;- 149,907,1486.
Cond. with salts; 149.
Mercury diethyl. C4HioHg» Hg.Et2.
In SOi, no cond. ; 1842.
Mercury ethyl chloride see under the hydroxide.
Mercury ethyl hydroxide. C2H«0Hg» Et.Hg.OH.
At 25% A(64)-1.7; 426; 271.
Cond. with NaOH; 425.
B.Cl=Et.Hg.Cl; 1669.
Mesaconanilic add see Citraconanilic acid.
Mesaconic acid. C6H604»CQ2H.CMe:CH.C02H.
kxXlO^; increases on diln. in all measurements. At 0^b8.4;
1018, 1968a. At 12''^SA; 1968a. At H'^^S.O aq.; 164.
At 18**-8 (colorim.); 1668, 1781. At 25^=8.0; m. p.
198 TABLES [Mes
201''-202^ 1372, 1823, 1831, 1838, 1968a. At dS'^^TJ;
1968a.
Second IcaXIO' »6.8 (inversion); 1638, 1336;= 9 (cond.); 1911.
Cond.; 170, 1968a. At 25°, /i(32)=52.0, (1024) =209.8, («) =
[351]; 1968a. /i(48)=63, («>)-355; 1372.
In HCl, no cond.; 30. In NH«, qnal.; 606.
Cond. with KOH; 170.
Mg.A; 1836. - 2K.A; 170. - 2Na.A at 25^ A(32)-80.6, (1024) =
96.6; 270; - 1823, 1831.
Mesitonic acid see Dimethyl-laeTulinic acid.
Mesitylene. C0H12.
Insol. in NHs; 606.
Mesitylene mono-carbozylic acid see 2,4,6-Trimethyl-benzoic acid.
Mesitylenedicarbozylic acid. (2,4,6-Trimethyl-m-phthalic acid).
CiiHi2O4=Mes.C6H(C08H)2. [C()2H=2,4; Me-1,3,5.1
kAXlO* at 25°=9.8; diminishes on diln. /i(64)=82.3, (1024)=
180.0, (00) =373; m. p. 283** with dec.
2Na.A at 25% m(32)-70.1, (1024)=89.5; 276.
Mesitylenediglyozylic acid.
Ci8Hi206=Me8.C«H(CO.CO|H)2. [CO.C02H=2,4; Me=l,
3,5.]
kxXlO^ at 25^=5; diminishes on diln. /i(32)=260.2, (1024) =
377.1, (a>)=371; m. p. not definite.
2Na.A at 25% iu(32)=73.2, (1024) =89.4; 276.
MesityleneglyozyUc add. (Mesitylene-mono-glyoxylic acid. Tri-
methyl-benzoylformic acid).
CiiHiaOa-Mes.CeHa.CO.CQjH. [C0.C0|H-2; Me= 1,3,5.]
kA XlO^ at 25^=5.4; diminishes, then increases on diln. m(32) =
256.5, (256)=334.9, (1024) = 359.0, (oo)=360.7; m. p. 115^
Na.A at 25% A(32) = 63.8, (1024)=80.3; 276.
Medtylenic acid see 3,6-Dimethyl-benzoic acid,
meso- see under letter beginning the next word, e. g. Mesomethyl-
see meso-Methyl-
Mesozalic acid. (Dihydroxy-malonic acid).
C3H406= (OH)2.C.(C02H)2.
Cond. increased by boric acid; 1186.
Metacetaldehyde see Acetaldehyde.
Metanilic acid see m-Aniline sulphonic acid.
Methacrylic acid. Polymeric. (Polymethacrylic acid).
C32H480ie=(C4H6()2)x; x=7 or 8.
kAXlO« at 25^=3.4; diminishes on diln. iu(32) = 3.6, (1024) =
15.8, (00) = 345; dec. 200^-300° without melting.
U salt.- K salt.- Na salt at 25% m(32)=32.9, (1024)=79.7;
1273.
Met] TABLES 199
Methane-disulphonic acid see Methylene-disulphonic add.
Methanetricarbozylic acid triethyl ester. CioHi606»CH(CC>2Et)s.
Cond. very small; 1298.
Methinetrithio-glycomc add. CrHioOeSs- (C()2H.CHSH)8CH.
kAXlO* [at 25**]- 1; increases on diln. m(32) = 58.7, (512)=210,
(oo) = 375; m.p. 173*^; 860.
Methozy-acetic add. (GlycoUic acid methyl ether. Methyl-glycoUic
acid) . CsHeOs = CHa.OMe. CQjH.
kA XlO* at 25° =3.4; aq. used for soln. was not pure.
A(32)=35.2, (1024) = 151, (oo)=358; 1370.
Na.A at 25% A(32)=70.0, (1024) = 81.6; 1367.
p-Methozy-benzaldehyde see Anisic aldehyde.
o-Methozy-benzene sulphonic acid amide. (o-Anisole sulphonic acid
amide). C7H»08NS= MeO.C(,H4.S02NH2.
In NHj; 607, 610.
m-Methozy-benzene sulphonic add amide. (m-Anisole sulphonic
acid amide). CtHjOsNS.
In NHs; 604, 607, 610.
p-Methozy-benzene sulphonic acid amide. (p-Anisole sulphonic
acid amide). CtHsQsNS.
In NHs; 607, 610.
o-MeUiozy-benzoic acid. (Methylsalicylic acid).
CsHgO^^ MeO.C6H4.CO2H.
kAXlO* at 18°=11 (colorim.); 1663. At 25'*=8.2; increases,
then diminishes on diln.; 1371, 1429.
At25% A(32) = 17.5, (1024)=86.9, (oo) = 355; 1371.
Na.A at 26% A(32) = 69.7, (512) =79.1; 1091.
m-Methozy-benzoic acid. CgHgOs.
kAXlO* at 25^=9.0; diminishes on diln.; m. p. 95** and 106^
A(256) = 50.0, (1024)=92.1, (oo)=355; 1429.
p-Methozy-benzoic add. (Anisic acid). CsHgOs.
kAXlO*^ at 18^=4.1 (colorim.); 1663, 1781. At 25°=3.2; 1371;
=3.6; 1429. At 50^=3.2 aq. At 60^=3.1 aq. At 70°=
3.0 aq. At80°=2.8aq. At 90° =2.6 aq. At 99°=3.6 aq.;
1681.
At 25°, A(512)=42.7, (1024) = 58.1, (a>)=355; 1371.
In NHs, qual. ; 606.
Na.A at 25°, A(32)=65.8, (1024)=75.2; 1368a. A(32)=69.7;
1091, 1681.
8-Methozy-6-chlorobenzoic add.
C8H70sCl=MeO.C6HsCl.C02H. [C02H=1.]
kAXltf at 25°=1.36; increases on diln.; m. p. 168°-169°.
A(458)-190.6, (916)=232, (a>)-354; 404.
200 TABLES [Met
4-Methozy-dibenzal-acetoiie. (Benzal-p-anisal-acetone) . CisHieOs.
Comparative strength (colorim.); m. p. 96.5^; 74, 1663.
4-Methozy-dibenzal-cyclopentanone. (Benzal-p-anisal-cyclopenta-
none). C80H18O2.
Comparative strength (colorim.); m. p. 153^; 1668.
iso-Methozy-dibenzal-cyclopentanone. (Mo-Benzalanisal-cyclopenta-
none). CjoHigOs-
Comparative strength (colorim.); m. p. 147^; 1663.
2-Methozy-3,6-dichloro-benzoic acid. (Dichloro-salicyHc acid).
CgHeOjCk- MeO.C6H2Cl2.CO8H.
kAXlff at 25^=1,37; m. p. 166.5'*-167^
A(2170)- 279.7, (4340) -309.2, (oo)=364; 404.
o-Methozy-phenyl urethane. CioHuO^N- MeO.C6H4.NH.CO|Et.
At 25% X of satd. soln.- 5.2x10"^; 1660.
4-Methozy-m-phthalic acid.
C9H806»MeO.C6H8(C02H)2. [C0|H=1, 3; MeO-4.]
IcaXIO* at 25^=2.5, extrapolated; m. p. 260"*.
/i(512) = 107.5, (1024) -142.6, (00) -352; 1429.
6-Methozy-o-toluic add. (Methyl-m-homo-p-hydroxy-benzoic acid).
CftHioOj-MeO.CeHsMe.COjH. [Me-1; CO2H-2; MeO=5.]
IcaXIO^ at 25^-5.4; diminishes on diln.
A(2048)-98.8, (4096) - 128.6, (00) -352; 1429.
4-Methozy-m-toluic acid. (Methyl-p-homo-o-hydroxy-benzoic acid).
C9H10Q8. [Me-1; CO2H-3; MeO-4.]
kAXl05at25°-6.8.
A(128)«31.2, (1024)=81.2, (oo)=352; 1429.
6-Methozy-m-toluic add. (Methyl-o-homo-p-hydroxy-benzoic acid).
CjHioOj. [Me-1; CQ2H-3; MeO-6.]
IcaXIO* at 25**»3.48; diminishes on diln.
A(2048)-82.3, (4096) -108.7, («>)«352; 1429.
8-Methozy-p-toluic add. (Methyl-m-homo-o-hydroxy-benzoic acid).
CftHioOj. [Me-1; C0|H-4; MeO-3.]
kAXlO* at 25**=4.1; diminishes on diln.; m. p. 103^
A(256)=34.4, (1024)-65.1, (oo)-352; 1429.
Methylacetoacetic add ethyl ester. CrHisOs-MeCO.CHMe.COiEt.
kA is between 10"" and 10"" (catal.); 1694.
/3-Methyl-7-acetylbutyric add.
C7H12O8-MeCO.CH2.CHMe.CH2.CQ2H.
kAXlO^ at 25**-2.7 aq.; b. p. 141** @ 15 mm.
A(31) = 10.8, (990.7) -56.4, (oo)-374; 1688.
Methylacridine. CmHuN.
B.OHatO% A(256)-23.
B.Mel; 763.
Met] TABLES 201
Methylacridinium iodide. Ci4H]2NI.
Cond. with NaOH; 763.
d-Methyladipic acid. C7H1SO4" CO|H.(CHs)8.CHMe.C02H.
kAXlO*^ at 24.4**«4.0; increases on diln.; m. p. 63"*.
m(54.3)-15.8, (869) = 62.6, («>)=352; 1240.
Methyladipic acid see 7-Pixnelic acid.
Methylal. CsHgOs.
In NHs, qual.; 606.
Methyl alcohol. CH4O = Me.OH.
xXlO* at 0*^=0.8; 920;-1.0; 916, 918; - 906, 1661. At 17^=
1.3; 289; 290. At 18''»0.44; 1724;»1.2; 1807; 362, 438,
680, 783, 787, 842, 1470. At 20^=5.8; 1590a. At 25°=
0.07; 337 ;« 0.74; 1844. Carefully purified methyl alcohol
has x=l-2. See also 335, 338, 347, 904, 905, 906, 908, 912,
913, 917, 918, 922, 941, 1388, 1390, 1423a, 1434a, 1679, 1680,
1692, 1620, 1746, 1843, 1987, 2029. At 35^=1.0; 1390.
At 45**= 1.7; 1434a. At critical point, qual.; 107; 133.
kjL is very small; qual.; 58. Relative basicity in organic sol-
vents (colorim.); 1051. Concentration of OH ions; 343.
Cond.; 337.
In HBr; 29. In HBr, HCl and HI, good cond.; in H^S, poor
cond.; 1897. In HCN, no cond.; 943. In H2SO4; 760. In
NHa^ qual.; 606. In MeNHj, little cond.; 637.
Cond. with other compounds; 46, 145b, 433, 748, 1035, 1388,
1724, 1746. As solvent; 82, 289, 290, (327), (331), 334, 336,
(337), 338, 344, (347), 433, 438, (580), 746, (783), 787, 788,
(842), (904), (912), (915), (916), (918), (920), 922, 923,
(941), 958, (1026), (1026), 1263, 1286, 1386b, 1388, 1390,
1423a, 1434a, 1464, 1470, 1579, 1580, 1590a, (1592), 1620,
1624, (1651), 1724, 1746, 1759, 1807, 1844, 1848, 1849,
1853a, 2029. Under pressure; 1590a.
NH4.A. - K.A; 335. - Na.A at 18% A(12) = 32.5, (31)=40.8,
(50) =43.7, («>)=94 (?); 433; 335, 344, 1724.
Methyl aldozime see Acetaldozime.
MethylaUozan. C5H4O4N2.
At 25% /i(32)=9.3, (1024) = 18.8; 1748.
o^Methylallylphenylbenzyl ammonium chloride.
Ci7H«oNCl= (Me) (CjHb) (Ph) (PhCHa) .NCI.
At 25% A(64)=92.9, (512) = 102.2; m. p. 152M54^ 1903.
mefo-Methylaliylsucdmc add.
C8Hi2O4«CO2H.CHMe.CH(CjH6).C02H.
kAXlO* [at 25**]=2.34; diminishes on diln. m(32)=29.1, (1024)
= 125.5, (00) =351; m. p. 86'*-87^; 826.
202 TABLES [Met
p-Methylaliylsttccinic add. C8Hu04.
kAXlO* [at 25^1-2.49; diminishes on dUn. m(32)«30, (1024)-
131.0, (oo)=351; m. p. 147M48^; 826.
Methyl amine. CHsN^ MeNH2.
xXlO^ [at20°?]=7; 605.
kB XlO^ at 25^-5 aq.; diminishes on diln.; about 16% too high;
271 ;« 4.1 (neutral.); 299a. Relative strength; 1631.
Cond.; 299a. At 25^ A(32)=27.0, (256)=65.4, (oo)=225; 271.
In NHs; qual. ; 606.
Cond. with HCl; 299a. With AgO; 510, 520. With succini-
mide; 1752. As solvent; (520), 605, 637.
B.HCl at 25% A(32) = 113.4, (1024) = 125.1; 270. In NH4OH;
660. In SOs; 1829, 1856. - Complex salts; 1750, 1752,
1766.
Methylamino-acetic acid. (Methylglycine. Sarcosine).
C3H7O2N- NHMe.CH2.C()2H.
kAXlO^® at 25^=1.3 (hydrol.); 1984.
kaXlO" at 25^=1.8 (hydrol.); 1984; 890, 1160; (colorim.); 1776.
At 25% A(914)= 228.6, (a>)=350; 601.
In NHs, qual.; 606.
Na.A at 25% A(32)=68.0, (1024)=82.6; M(32) = 76.1, (1024) =
111.- B.HCl at 25% A(32)-102, (1024) = 113; M(32) = 199,
(1024)^366; 1984.
o-Methylamino-b^nzoic acid. (N-Methylanthranilic a<^id).
CsHsOaN^ NHMe.C6H4.CC)8H.
kAXlO^ at 25*^=4.6.
ka XlO"^ at 25**=9.4 (catal.).
At 25% A(775)=21.1, (1025)=24.9, (oo)«378.
Na.A at 25% A(32)=68.9, (1024) =78.4; 414.
o-Methylamino-benzoic add methyl ester. (N-Methylanthranilio
acid methyl ester). C9Hii02N=NHMe.C6H4.CC)8Me.
ke XlO^i at 25*^=3.36 (catal.); 414.
m-Methylamino-benzoic acid. C8Ho02N»NHMe.C6H4.C02H.
kAXlO* at 25°=8 (catal.);=6.7 (cond.); m. p. 147^
kB XlO^i at 25** is about 1.2 (catal.).
At 25% A(82)=7.5, (1312)=31.8, (oo)«377.
Na.A at 25% A(32)=69.9, (1024)=79.7; 414.
p-Methylamino-benzoic acid. C8Ho02N»NHMe.C6H4.C02H.
kAXlO* at 25'*=9.2 (catal.);=8.8 aq. (cond.); m. p. 144M45%
kflXlO" at 25*^=1.66 (catal.).
At 25% A(128) = 10.2, (1024)=34.1, (oo) = 377.
Na.A at 25% A(32)«68.3, (1024) =80.7; 890.
p-Methylamino-benzoic acid methyl ester. C9H11O2N.
kflXlO^* at 26**=2.0 (part.); m. p. 75°-76^ 890.
Met] TABLES 208
4-Methyl-2-axiimophenyl ethyl carbonate.
CioHuO|N-Et02CO.C6H3(Me).NH,.
kBXlO" at 0**=1.23 (hydro!.).
B.HCl at 0% /i(32)»42.6; M(32)-73.5. Cond. on standing;
m.p. 135M37Mec.; 1660.
5-Methyl-2-axmnophenyl ethyl carbonate. CioHuO^N.
kBXlO^i at 0*'«2.16 (hydro!.).
B.HCl at 0^ /i(32)=42,6; M(32)=69,l. Cond. on standing;
1660.
6-Methyl-2-aininophenyl ethyl carbonate. CioHuOsN.
Icb XlO" at 0^=1.05 (hydro!.).
B.HCl at 0^/i(32)- 42.6; M(32) = 78.5; 1660.
2-N-Methylamino-p-phthalic acid.
C9H904N-MeNH.C6H8(C08H)2. [C08H=1,4; MeNH=2.]
Ica X 10^=3; m. p. 277**-279^; 1684. In 316 it is stated that this
acid contained some dimethy!-amino-p-phtlialic acid, and
tliat kx of the pure acid is a little smaller. No figures are
given.
/i(610) = 130, (1200) -171.2, (oo)=376; 1684.
Methylammonium acetate see Acetic acid; organic salts.
Methylammonium hippurate see Benzoylamino-acetic add; salts.
MeUiylammonium phenylacetate see Phenylacetic add; salts.
Methyl-iso-amyl-dimethylamino-methyl carbinol benzoate. {iso^
Amyl stovaine derivative).
Ci7H2702N-PhCO.O.CMe(CBHii).CH2.NMe8.
keXlO' at 15^ is about 1 (hydro!.); 1777, 1779.
cts-a-Methyl-a'-tM>-amyl-sucdnic add.
CioHi804=C02H.CHMe.CH(C6Hii).C08H.
kxXlO* at 25*^=3.85; m. p. 93^
m(52.3)=46.3, (418.4) = 115, (oo)=[351]; 236.
Iran^-a-Methyl-a'-tso-amyl-succmic add. C10H18O4.
kxXlO* at 25^=2.36; m. p. 141^-142^
/i(183.4)=65.6, (1467.2) -154.7, (oo)-[351]; 236.
Methylaniline. CtHsN- Ph.NHMe.
kaXlO^® at 18**-2.55 (colorim.); 1777. At 60^-74 (inversion);
1880.
In HC! and HBr, good cond.; in HsS, no cond.; 1897. In ben-
zene, no cond.; 1802.
Cond. with acetic acid; 1011. With ally! tliiocarbimide, no
cond.; 1223. With picric acid; 1802. As solvent; 1662a.
B.HCl at 25^ A(64)-95.0, (256)«99.4; 270; 1864.- B.H2SO4;
1864.
l-Methylaniline-4-sulphonic add.
C7H9Q8NS-NHMe.CeH4.SQ8H. [NHMe-1; S08H=4.]
204 TABLES [Met
kAXlO* at 25^-6.66.
A(128)=89.4, (1024) -195.5, (®)«364; 492.
Methylanthranilic add see o-Methylamino-benzoic add.
Methyl arsenic add. (Mono methyl arsenic acid. Methyl arsonic
acid). CH603As=Me.AsO(OH)2.
kA XlO^ at 25'' is about 1; 2009.
Cond. alone and with MoQs; 1269.
Methyl arsonic acid, see Methyl arsenic add.
Methylbenzenyl-amino-thio-zylenol-azo-a-naphtfaol disulphonic add
see Erika B.
a-Methyl-m-benzimideazolecarbozylic add. (meso-Methylphenmi-
azolemonocarboxylic acid). C9H8Q2N2.
kxXlO* at 25*^=1.0.
/i(760.7)-9.6, (1521.4) = 13.6, (a>)=350; 70.
m-Methyl-a-benzixnideazolecarbozylic add. C9H8O2N2.
kxXlO* [at 25°]= 1.1; m. p. 143° slowly heated; 80.
Methylbenzoylamino-acetic add. (Benzoylsarcosine).
CioHiiOsN- PhCO.NMe.CHjCOiH.
kAXl0*at25°=5.05.
^(64) -57.6, (1024) -175.6, (oo) = 350; 601.
2-Methylbenzoyl amino-propionic add. (o-Alaninetoluric acid).
CiiHuQjN- MeC6H4CO.NH.CHMe.COjH.
kAXlO^at 25°-1.65.
/i(411.4)-80, (1645.6) -141.3, (a>)-350; 601.
4-Metfaylbenzoyl amino-propionic add. (p-Alaninetoluric acid).
CiiHisQsN.
kAXlO* at 25°- 1,70; diminishes on diln.
ii*(408.5)=81.1, (1634.0) -141.5, (oo)-350; 601.
Methylbenzylcarbozyglutaric add see Benzyl-iM>-butenyltricarbozy]ic
add.
Methylbenzylglutaric add. C13H16O4.
kAXlO'^at25°-5.9; m. p. 128M30°; called dimethyl-benzylsuc-
cinic acid, with some doubt as to real structure.
m(32)-14.5, (512)-55.7, (a>)=350; 201.
Methylbenzylmalonic add. CiiHi204= (Me) (PhCH2)C(C02H)2.
kAXltf at 25°=2.66 aq.; diminishes on diln.; m. p. 138°.
Second kAXlO^-1.2 (inversion).
At 25°, /i(64) = 117.9, (1024) =265.9, (oo)-351; 1688.
ine90-5ym.-Methylbenzylsuccinic add.
C,2Hi404=C02H.CHMe.CH(PhCH2).C02H.
kAXlO^ at 25° -2.47; increases, then diminishes on diln.; m. p.
137°-138°; 201, 1838.
m(32)-29.7, (512)- 103.4, (oo)=350; 1838.
Met] TABLES 205
p-sym.-Methylbenzylsttcdxiic add. C12H14O4.
kAXlO* at 25°=2,18; increases on diln.; m. p. 169M60**; 201,
1838.
m(32)-27.8, (512)-99.1, (oo) = 350; 1838.
Methyl-bromo-uradl. CsHfiO^NsBr.
kAXlO« at 25*^=2.6.
/i(512) = 1.3, (1024) = 1.8; 1748.
ds'^ia'-Methyl-t^a-butyl-sucdxiic acid.
CaHi604=C08H.CHMe.CH(Mo.Bu).CO,H.
kAXlO* at 25^=4.27; diminishes on diln.; m. p. 88^-90**.
Ai(34.5)-40.1, (276.0)^101.0, (00)= [361]; 236.
frons'^ui'-Methyl-tso-butyl-succifiic add. C0H16O4.
kAXlO^ at 25'' » 2.36; diminishes on diln.; m. p. 133^
m(88.9)=47.3, (711.2) = 116.1, («>)-[351]; 236.
N-Methylddoroglyozaline. C4H5N2CI.
kBXlO«at25'*=1.7.
m(32)-0.16, (128) =0.35, («)= 222.4; 428.
Methyl-chloro-uradl. C6H6O2N2CI.
kAXlO« at 25*^=3.3.
m(612) = 1.5, (1024) = 2.0; 1748.
Methyldtraconanilic add. (Ethylmaleinanilic add). CuHuOsN.
NH4.A, A(33.0)=47.0, (1056.6) = 64.8; (the free acid has m. p.
106^-107**); 1749.
Methyldtraconic add see Ethylmaleic add.
l-Methylcydohezane-3-acetic add. CsHieOs.
kAXlO^ [at 25^1=1.59.
/i(190.3) = 19, (1522.4)«50, (oo)=352; 2026.
1-Methylcyclohezane-l-carbozylic add. CgHuOi. '
kAXlO* [at 25*^1=6.9.
/i(126.7)-10.2, (1013.8) =28.2, (oo)=352; 2026.
a9-l-Methylcydohexane-2-carbozylic add. (m-Hexahydro-o-toluic
acid). CsHuOs.
kAXlO* [at 25° 1=1.64.
/i(193.2) = 19.3, (1545.6) = 53.5, (00) = 352; 2026.
/raii«^l-Methylcydohezane-2-carbozyfic add. (trans-Hexahydro-o-
toluic acid). CsHmOs.
kAXlO^ [at 25*^1=2.05; m. p. 50**-51^ '
/i(48.3) = 10.8, (1545.6) =58.8, (a>)«352; 2026.
l-Methylcydohezane-3-carbozylic add. (Hexahydro-m-toluic acid).
CgHuOs.
kAXlO^ [at 25^1-1.28.
/i(57.7)=9.4, (923.5)=35.4, (od)=362; 2026.
l-Methylcydohezane-4-carbozyUc add. (Hexahydro-p-toluic acid).
C8Hi402*
206 TABLES [Met
kAXlO* [at 25*^]- 1.11.
/i(209.5)-16.5, (1676.3) =45.3, (a>)=352; 2026.
l-Methylcyclopentane-3-carbozylic add see 1-Methylpentamethylene«
2-carbozylic add.
3-Methyl-de80zyzanthine see 3-Methyl-2-ozy-l,6-dihydro-ira]ine.
Methyldiethyl-amine. C5H13N- Me.N.Ets.
kB XlO* at 25'*=2.7 aq.; about 16% too high.
A(32) = 18, (256)=46.2, (oo)-203; 271.
B.HCl at 25% A(32)-91.7, (1024) = 103.2; 270.
m-Methyldihydro-resordnol. CrHioOs.
kAXlO« at 25^-5.7 aq.
A(33.2)=5.1, (1031)=27.9, (oo)«376; 1588.
4-Methyl-l,2-dihydrozy-l,2,6-tiiazole 3-carbozylic add ethyl ester
(Dihydroxy-triazolidine-acetic add ethyl ester. Methyl-
dihydroxy-triazolidine-carboxylic add ethyl ester).
C6Hn04N,.
kAXlff at 18^=6.17; m. p. 70**-71^
At 18% A(23.8)- 108.2, (119.2) = 193, (oo)=340; 627.
Methyl-dihydrozy-triazolidine see Methyl-dibydrozy-triazole.
Methyldiphenyl amine. CuHuN.
In NHs, qual.; 606.
Methylene Blue see Tetramethyl-thionine ddoride.
Methylenecydopropane amine. (Ethylene-ethyl amine).
C4H9N= (C3H6.CHj)NH2.
kB XlO* at 25*^=4.4; b. p. 86** (in vapor.)
/i(29.4) = 21.7, (471)=74, (a>)=204; 420.
Metfaylene-dihydro-benzoic add see iso-Phenylacetic add.
Methylene di-hydroresorcinol. C18H16O4.
Too insol. in aq. to measure, therefore kx is less than that of
dihydroresorcinol, (=5.5xlO-«); m. p. 132**; 1816.
Methylene-dimethyl-sucdnic add.
C7Hio04=C()2H.Me2C.C(:CH2).C08H.
kxXlO* at 25^=1.67; m. p. 142.5^
m(20) = 19.7, (80) =38.5, (00)- 352; 229.
Methylene-disulphonic add. (Methane-disulphonic acid).
CH406S2=CH2(S03H)2.
2Na.A at 25% /i(32)=92.7, (1024) = 117.6; 1367.
Methylenedi-thioglycomc add. C6H804S2=(C02H.CHSH)2:CH2.
kxXlO* [at 25']=4.67; increases on dUn. /i(32)=43.6, (512)-
158.2, (oo)=378; m. p. 128.5^-129'* (uncor.); 856.
A-Methyleneglutaric add. C6H804=C02H.C(:CH2).(CH2)2.C02H.
kxXlO^ at 25'*=6.7; increases on diln.; m. p. 130M31^
A(32) = 17.0, (1024) =86.8, [(«>) is about 3801.
2Na.A at 25% A(32)=84.5, (1024) = 101,9; 565.
Met] TABLES 207
7-Mefhylene-7-phenylpyrotartaiic add. (Methylphenylaticonic acid).
CttHi204«Ph(CH2:)C.CH(C08H).CH2.CQiH.
kAXlO* [at 25**]- 1.95; m. p. 152M54^
m(63.8)=»36.8, (1021)-124.6, («)-350; 1661, 817.
Mefhylefhylacetic add. C5H10Q1 » (Me) (Et) CH.COsH.
kAXlO*^ at 25*'-1.69; b. p. 176**; 180, 1840.
A(32)=8.3, (1024)-43.6, (a>)=362; 1840.
Methylethylacxylic add see a-Mettiyl-a,/3-pentenoic add.
Mefhylethylanmne. CgHuN » Ph.N (Me) (Et) .
B.HCl at 25% A(64)=90.2, (256) =94.9; 270.
Mefhylefhyl-aticonic add. (7-Methyl-7-ethylidenepyrotartaric acid).
C8HB04-Me(Me.CH:)C.CH(CQiH).CH2.C02H.
kAXlO* [at 25**]= 1.12; m. p. 140M4r.
/i(45.7)=24.2, (1462) = 114.9, («)=351; 1662.
Methylethylcarbinamine see secondary'Butyl amine.
Methylethylcarbozylglutaiic add.
C9Hi40«=Me.CH(C02H).CH2.C(Et)(C02H)2.
kAXlO* at 25**=9.74; m. p. 166**.
m(32) = 148.4, (1024) -324, (oo)«350; 1839.
Mefhylethyl-dimethylamino-methyl carbinol benzoate. (B.HCl is
Stovaine). Ci4H2i02N=PhOCO.C(Me)(Et).CH2.NMe2.
keXlO' at 15**- 1.5 (hydro!.); 1779; 1777.
meso-a-Methyl-a'-ethylglutaiic add.
C8Hi404= CO2H.CHEt.CH2.CHMe.CO2H.
kxXlO* at 25**=5.6; m. p. 63**-67**; 189, 201, 1838. [CaUed
also, dimethyl-N-ethylsuccinic acid in 201. ]
/i(32)-14.4, (1024) -73.2, (oo).351; 1838.
/3-Methyl-a-ethylglutaric add.
C8Hi404=C()2H.CH2.CHMe.CHEt.C()2H.
kAXlO* [at 25**?] =6.7; m. p. 100**-101**; 1398. [? same as di-
methyl-H-ethylsuccinic acid, kA=5.9; m. p. 105**. /i(32)-
14.9, (512) =54, (00) -351; 201.]
Methylethyl glyoxime. C6H10O2N2.
Co complex salt; 1759.
Methylethylidene-glutaric add see Dicrotomc acid.
Mefhylethylidenepyrotartaric add see Methylethyl-aticoiiic add.
Methylethyl-itaconic add. C8Hi204= MeEtC :C(C02H).CH2.C02H.
kAXlO* at 25**= 1.50 aq.; diminishes on diln.; m. p. 179**-181*
dec; 1638, 1662.
Second kAXlO'=4.6 (inversion).
At 25% m(139.4) = 47, (1115)-116.3, («)-351; 1638.
Mefhylethyl ketone. C4H80- Me.CO.Et.
xxl0'at25**-1.0; 1423a;=3.07; 1323.
Cond. as solvent; 474, 1106, 1107, (1323), 1423a.
208 TABLES [Met
Methylefhylmaleic add. C7H10O4- CQiH.CMe:CEt.COsH.
kA XlO^ at 25^ "9.7 from soln. of the anhydride in aq. Apparently
polymerizes in sohi. as shown by smaU cond.
m(128)»37, (1024)«94; 1838, 1030.
Methylethylmaleic anhydride. CrHgOt.
See the acid.
Methylethylmalonic add. CoHioOa" (Me) (Et)C(C02H)s.
kAXlO» at IS^'^l.e; 1663. At 25**-1.61; m. p. 118M19*;
1838, 176.
Second kAXlO^» 1.7 (inversion); 1638.
At 25^ m(32)-71.8, (1024)-248, («)-355; 1838.
asym.-Methylethylsucdnic add see iso-Pimelic add.
/um.-sym.-Methylethylsucdnic acid. (jS, or h-, or p- acid).
07Hi,04- COjH.CHMe.CHEt.CQ2H.
IcaXIO^ at 25*'=2.10; m. p. varies from 169** to ISO**; pure acid
has m. p. 180^ 61, 62, 176, 200, 1418, 1838.
At 25^ /i(32)-27.5, (1024) = 126.4, (<»)»352; 1838.
mitf .-^m.-Methylethylsucdnic add. (a, or meso-, or n- acid).
C7H]i04>
IcaXIO^ at 25**=2.10; m. p. varies from 84** to 101**; pure acid
has m. p. 101**-102**; 62, 176, 201, 1418, 1838. - 61.
At 25^ /i(32)-27.1, (512)=95.3, (<»)=352; 1838.
cu-jS-Methylglutacomc add. C6H804» CQjH.CH :CMe.CHs.COsH.
IcaXIO^ at 25**»1.3; diminishes on diln.; m. p. 152^
/i(32) = 22.9, (1024) = 110; 672.
(ron^-jS-Methylglutaconic add. C6H8O4.
kAXlO^ at 25**»1.4; increases, ^hen diminishes on diln.; m. p.
116^
/i(32)=24.4, (1024) -116.5; 672.
a-Methylglutaric add. C6Hio04= COjH.(CHi)2.CHMe.C02H.
kAXlO* at 25**= 5.4; m. p. 77**-78**; 176, 197, 603, 1240, 1838.
At25^/i(32)-14.1, (512) = 52.2, (oo)=352; 1838.
j8-Methylglutaric add. C6H10O4- MeCH(CH2.COjH)2.
kAXlO* at 25**=5.9; increases on diln.; m. p. 85**-86*.
At 25^ /i(32)=-15, (512) = 58.a, (oo)=352; 1838.
Methylglydne see Methylaminoacetic acid.
Methyl-glycollic add see Methozy-acetic add.
a-Methyl glyozaline. (4-or 5-Methylimideazole). C4HeN2.
keXlO^ at 18** is more than 1 (colorim.); 1776. [At 25**]-4.1;
m. p. 56**; 428.
Second keX 10^°= 2.8 (colorim.); 1776.
[At 25M iLi(32)-0.9, (1024)-5.3, (a>)=229.7; 428.
B.HNOj [at 25M A(32)=97.8, (1024)-110.6; 428.
Met] TABLES 209
fi-Methyl glyoxatine. (2-Methyliinideazole). CiHeNs.
kBXlO« [at25**]«1.3; m. p. 139^
m(32) = 1.5, (1024) = 10.2, («)=:224.2.
B.HNQ. [at 25**], A(32)=90.6, (1024) = 103.8; 428.
N-Meth^ giyozaline. (1-Methylimideazole). C4H«N2.
keXlO' [at25**l-2.1; b. p. 198^
m(32)=0.6, (1024) =7, («>)- 229.7.
B.Picrate [at 25M A(128)-68.9, (1024) =75.7; 428.
Methylglyoximecarbozylic add see Diozunino-butyric add.
Methylguanidine-acetic add. (Creatine).
C4H908N8=NH:C(NH2).NMe.CH2.CQiH.
kBXlO^i at 40*^=1.87 (catal.); 1996 and 1160. At 40.2*'= 1.81
(catal.); 1996.
In NHs, qual. ; 606.
Cond. with HCl; 1318.
Methyl-homo-hydrozy-benzoic add see Methozy-toluic add.
Methylhydroresorcylic add ethyl ester.
CioHi404=C7H80(OH).C02Et.
kxXlO^ at 25^=3.7 aq.; increases, then diminishes on diln.;
m. p. 89*'-90**.
A(32.1) = 12.6, (1026)=64.9, (<») = 372; 1688.
3-Methyl-6-hydrozy-phenyl urethane.
CioHiaQsN- HO.CeHs.Me.NH.COiEt.
. At 25**, X of satd. soln.=5.2xl0-^ m. p. 101**.
With HCl, no change of cond. ; 1660.
4-Methyl-l-hydrozy-l,2,6-triazole 3-carbozylic add. (Hydroxy-
triazolin acetic acid. Methylhydroxytriazolidine carboxylic
acid.) C4H6Q8N8.
kxXlO* at 21.5*'=6.1; diminishes on diln.; m. p. 184**-185**.
A(29.8) = 122, (297.7) = 252, (oo) = 353; 627.
Methyl-hydrozy-triazolidine see Methyl-hydrozy-triazole.
Methylimideazole see Methyl glyozaline.
Methylimino-uracil. C6H7ON3.
kAXl08at25**=3.8.
m(128) = 0.8, (1024) = 2.2; 1748.
2-Methylindole-3-acetic add. C11H11O2N.
kAXlO^ at 25^=2.18 aq.; diminishes on diln.; m. p. 195**-200*
dec.
A(270) = 25.9, (1080)=49, (<»)=350; 23.
Pr-2-Methyl-indole-2-carbozy]ic acid. (a-Methyl-jS-indole etc.).
CioH«02N.
kxXlO* at 25**=1.3 aq.; m. p. 176**-177**.
A(1124) = 12.9, (2248) = 17.9, (<») = 351; 23.
210 TABLES [Met
S-Mefhyl-indole-S-carbozylic acid. (/S-Methyl-o-indole etc. /3-Ska-
tole-carboxylic acid). C10H9Q1N.
kxXlO*^ at 25**-4.7 aq.; m. p. 167^
m(453.6)-47.7, (907.2) =66.7, (»)-351; 23.
Methyl iodide. (lodomethane). CH«I.
X xlO^ at 25'' is lees than 0.2; b. p. 41''-43^ @ 743 mm.; 1388;-
1.3; 1669.
In NHs, qual.; 606. In SOs, no cond.; 1842.
Cond. with organic compounds; 1388, 1669, 1866. With AlCU;
1893.
Methylisoxazolone see /3-Oziminobutyric add anhydride.
MethyUtaconic acid. C6H8O4- MeCH :C(C02H).CH2.CQ2H.
kAXlO^ at 25''»9.5; diminishes on diln. m(32)»19.0, (1024)-
91, (00) -354; m. p. 166M67**; 191, 609, 1838.
Methyl-laevulinic acid see Aceto-tso-butyric add.
Methyllutidimum chloride. CgHisNCl-CrHsN.MeCl.
At 25^ A(32)=90.8, (1024)- 103.0; 270.
Methylmaleinanilic add see Citraconanilic add.
Methylmalonic add see iso-Sucdnic add.
Methylmesaconic acid see Ethylfumaric add.
Methylmorphine see Methylmorphinium hydroxide.
Methylmorphinium hydroxide. (Methylmorphine. Morphine methyl-
hydroxide) . C18H28O4N - CnHijOsN. MeOH.
0.05 normal soln., fi is about 5; 706.
B.Cl (-CnHiaQsN.MeCl) at 25^ A(32)-79.2, (1024) -91.7; 270.
Methyl nitrate see Nitric add methyl ester.
Methylnitroamine. CH4O2N1- Me.NH(N02).
kAXlO^ at 0**=3; 733. At 25**- 7; 733, 767. At 35** or 40*=
8; 733.
Cond.; 1094. At 25^ iLi(64)-2.2; 782.
In NHa; 610. In pyridine; 764. In Et ale; 764, 782.
Hg.A; 1094.
Methylnitronium iodide. (Nitron methoiodide).
C2iHi9N4l-C2oHi«N4.MeL
At25^ A(272) = 85; 314.
3-Methyl-4-iso-mtrosopyrazolone. C4H6O2N8.
kxXlO* at 15**=0.90. At 25**- 1.2 (hydrol. and cond.); m. p.
232** cor. [132** is a typographical error]; 1141, 1143; is
over 18 (hydrol.) for true acid;-2.2 (cond.); 762. At 40**-
1.72 (hydrol. and cond.)- 1141, 1143.
ks XlO^^ at 25** is less than 1 (hydrol.); 1143.
At25^ A(194.9)-5.8, (389.8)-8.0, (a>)=378; 1143.
Na.A at 25% A(32)-70.7, (1024)-81.1; 762. At 15**-40**; 1143.
- AniHne salt; 1141, 1143.
Met] TABLES 211
Mefhylnitro-uracil. C6H6O4N8.
kAXlO' at 26^-4.
m(512)-5.2, (1024) » 6.5; 1748.
Mefhyl Orange see Dimethyl-axnmoazobenzene sulphonic add.
Mefhyloziiiiino-S2fn-oxazolone. C4H4QtN2.
kAXlO* at 0**=0.8. At 25**=3.5. At 35.6^=5.9.
Cond. showing decomposition in soln. into amp/ii-Dioximino-
butyric acid.
At 25^ /i(32) = 11.7, (00) -357; 701.
Neutral KA at 0^ A(64)=48.5; 702, 701.
3-Methyl-2-ozy-l,6-dihydro-pii]ine. (De80xy-3-methylxanthine. 3-
Methyl-desoxy-xanthine). C6H8ON4.
IcaXIO" at 25*'=7.9 (catal.); 1707.
Methylparabanic add. C4H4Q8N2.
At 25'', /i(32)»2.6, (1024)»6.0; decomposes in soln.; 1748.
l-Methylpentamethylene-2-carbozylic add. (Hexanaphthene-car-
boxylic acid. l-Methylcyclopentane-3-carboxylic acid.)
C7H12Q1.
IcaXIO* [at 25**]= 1.07.
A(53.4)=8.3, (855.0) =31.7, (00) =352; 2026.
a-Methyl-a/3-pentenoic add. (a-Methyl-j8-ethylacrylic acid).
CeHioOj- Me.CH2.CH iCMe.COiH.
kAXl0«at25**=1.0; diminishes on diln.- 1.12; 1371; =0.99; 671.
A(32) = 6.7, (1024)=35.2, (a>)=378; 671.
Na.A at 25^ A(1024-32) = 10-11; 671.
a-Methyl-j37-pentenoic add. (a-Ethylcrotonic acid).
C«HioQ2= Me.CHiCH.CHMe.COjH.
kAXltf^ at 25**= 3.05; diminishes on dOn.; b. p. 198**-199^
A(32) = 11.6, (1024)=59.2, (oo)=378.
Na.A at 25^ A(1024-32) = 10-11; 671.
a-Methyl-75-pentenoic add. C6Hio02=CH2:CH.CH2.CHMe.C02H.
kAXlO* at 25*^=2.16; b. p. 193-194^
A(32)=9.8, (1024) = 52.1, (a>) = 378; 671.
Na.A at 25^ A(1024-32) = 10-11; 671, 622.
/3-Methyl-a/3-pentenoic add. C6Hio02= MeCH2.CMe:CH.C02H.
kAXlO« at 25**=8.1; diminishes on diln.; m. p. 46**; 666, 669,
642.
At 25^ A(32)=6.2, (1024)=30, (»)=378; 666.
/3-Methyl-/37-pentenoic add. C«Hio02 = MeCH :CMe.CH2.C02H.
kAXlO^ at 25*^=3.1; diminishes on diln.; b. p. 199**; 666, 669,
642.
At 25^ A(32) = 11.7, (1024) = 56.3, («)=378; 666.
Na.A at 25^ A(32)=69.1, (1024)=80.6; 642.
212 TABLES [Met
meso-Methylphenmiazolemonocarbozylic acid see a-Mefh^-m-benzi-
mideazole-carbozylic add.
Methyl-phenyl-acridinium hydroxide. (Methylphenylacridonium hy-
droxide. 9-Phenyl-acridine-lO-methylium hydroxide).
CioHnON - Ci»HuN. MeOH.
At 0®, /i(256) = 117; changes in soln. to Methylphenyldihydro-
acridol; 763.
B.Cl (-CigHu.NMeCl) at 0^• 763. At 25^ m(32)-86.8, (1024)-
100.6; dec. 225**; 1075. - B.CN; 763. - 2B.SQ8; 1075. -
2B.SO4; 747, 1075.
Methylphenylacridol see Methyl-phenyldihydro-acridol.
Methylphenylaticoiiic acid see Meth^enephenylpyrotartaric add.
Methylphenylbenzylaminopyrazole see Benzyliminopyrine.
N-Methyl-phenyldihydro-acridol. (Methylphenylacridol. 10-Methyl-'
0-phenyl-0-hydroxy-9,10-dihydro-acridine). CtoHnON.
No cond. in aq.
B.CN=CN.Ci«Hi8.NMe (Phenyldihydro-acridine carboxylic acid
nitrile). Almost no cond. in aq.; 763.
Methylphenyldihydro-resorcylic add nitrile.
CmHuOjN* OH.CisHiiO.CN.
kxXlO* at 25^=2 aq.
A(266.5)=77.7, (1066) = 136.9, (a>)=372; 1588.
Methylphenyl-dimethylamino-methyl carbinol benzoate. (Phenyl
Stovaine derivative).
CisHaOjN = PhCO.OCMePh.CHj.NMe2.
keXlO^ at 15^ is about 1 (hydroL); 1779, 1777.
3-Methyl-l-pheiiyl-5-ethozy-pyrazole. C12H14ON2.
No cond. in aq.; m. p. 40°; 977.
4-Methyl-l-phenyl-3-ethozy-urazole. CnHuOjNj.
Cond. in ale. soln. of HCl; 18.
Methylphenylethylenelactic acid see Methylphenylhydrozy-proidonic
acid.
a-Methyl-jS-phenyl-jS-hydrdzy-propioiiic acid. (Methylphenylethyl-
enelactic acid). CioHia08=PhCH(OH).CHMe.CQiH.
kxXlO^ at 25° » 3.47; increases, then diminishes on diln.; m. p.
95°.
iLi(39.9) = 12.7, (1277.8) =64.1, (a>)=349; 1704.
7-Methyl-7-pheiiylitacoiiic add.
CuHB04=PhMeC:C(COjH).CH2.COjH.
kxXlO^ at 25°=2.01; diminishes on diln.; m. p. 171° with dec.
m(64)-37.6, (1024) = 123.9, («)-[350]; 1661, 817.
7-Methyl-7-phenyl-tso-itacoiiic add.
CiaHi204- PhMeC :C(COiH) .CH2.CQ2H.
Met] TABLES 218
kAXlO* at 25**«2.3 aq.; diminishes on diln.; m. p. 178M79**;
1638; m. p. 183^-185^ 1661, 817.
Second kxX 10^=6.2 (inversion); 1638.
At 25% /i(640)- 110.4, (1280)-143.2, («)-[3501; 1661.
Methylplienylketone see Acetophenone.
Methylphenylketozime see Acetophenone oxime.
3-Methyl-l-phenyl-4-tso-iiitro80-5-pyrazolone. CioHgOzNg.
kA XlO* at 25**=2.4; of true, salt-forming, acid is over 18(hydrol.).
/i(256)-8.5, («)-351.
Na.A at 25% A(32)-61.1, (1024)=71.6; 752. In pyridine; 754.
3-Methyl-l-pheiiyl-5-pyrazoloiie. CioHioOf^.
In molten state, fair cond.
Cond. in aq. equals that of a 1% NaCl soln.; 977.
/iim.-5ym.-Methylphenyl8uccinic add.
CiiHi,04= CO2H.CHMe.CHPh.CQ8H.
kxXlO* at 25**=3.74; diminishes on diln.; m. p. 192M93**;
2018, 2023.
m(80.3)-54.8, (1285) -169.2, («)- 345; 2018.
mitf.-5ym.-Methylphenyl8ucciiiic add. CuH]i04.
kxXlO* at 25**=2.33; diminishes on diln.; m. p. 170M71*;
2018, 2023.
m(78.8)=43.7, (1260)-139.8, (a>)-345; 2018.
4-Methyl-l-pheiiyl-3-thio-urazole. CgH^ONsS.
kxXlO^ at 25''- 1.8; diminishes on diln.; m. p. 196^
A(256)- 299.7, (512) -309.7, (a>)-355; 18.
2-Methyl-l-pheiiyl-iirazole. C^HsQiNs.
kAXl0« at 25**-6.7; m. p. 185^
A(128) = l, (1024)-2.5, (oo)-345.
Na.A at 25% A (64) -59.1, (1024) =66.1; 18.
4-Methyl-l-phenyl-urazole. CsHgQzNa.
kxXlO^ at 25**- 1.2; diminishes on diln.; m. p. 225^
A(512)-27, (1024) -37.5, (00) -355.
Na.A at 25% A(64)-55.8, (1024) -63.8; 18.
O-Methyl-N-phenyl-^seiKfo-urea. CgHioONs- NH :C(NHPh)OMe.
keXlO^ at 25*'=2.5; m. p. 46.5% 285, 286.
A(32)-0.6, (256)-2.1, (a>) = 225.5; 285.
B.HCl at 25% A(32)-90.4, (1024) -102.6; 286.
Methyl-m-phthalic add see XJvitic add.
Methylpicolinium chloride. C7H10NCI- CeHyN.MeCl.
At 25% A(32)=94.4, (1024) -106.6; 270.
o-MethylpimeUc add. C8Hi404= COjH. (CH2)4.CHMe.C02H.
kxXlO^ [at 25**]-3.15; m. p. 57**-58% 2024.
Methylpropylcarbozyglutaric add see Propyl-iso-butenyltricarbozylic
add.
214 TABLES [Met
a-sym.-Methylpropylglutaric add.
CgHieOi^ CQ1H.CHMe.CH2.CHPr.CO2H.
kA XlO* at 25'*=5.4; m. p. 51'*-63^ [Given as either Dimethyl-
N-propylsuccinic acid or this acid.]
m(64)-20, (512)«52.2, (oo)«350; 201.
/3-sirm.-Methylpropylglutaric acid. C9H16O4.
kA X 10*^ at 25**= 5.9; m. p. 101*'-102^. [Given as either Dimethyl-
H-propylsuccinic acid or this acid. ]
m(64)=20.9, (612) « 53.8, (a>)=350; 201.
Methylpropyl ketone. CsHioO^ Me.CO.Pr.
xXlO' at 25**«9.5; 1106, 1107.
In HBr and H2S, fair cond.; 1897.
As solvent; 474, 1106, 1107.
Methylpropylmaleic add. C8Hi204= C02H.CMe .CPr.COiH.
kA XlO* at 25® =7.3; measured in aq. soln. of the anhydride.
m(64)=25.2, (1024) = 89.5, (a>)=376; 1031.
Methylpropylmaleic add anhydride. CgHioOs.
B. p. 241**-242° cor.; see the acid.
Methyl-tso-propylmaleic add. C8Hi204=CQ2H.CMe:Ciso-Pr.C02H.
kAXlO^ at 25^=1.5; diminishes on diln.; measured in aq. soln.
of the anhydride.
m(64)=35, (1024)=84.7, (a>)-376; 1031.
Methyl-tso-propylmaleic add anhydride. CgHioQs.
B. p. 240**-242**; see the acid.
Methylpropylmalonic add, C8H14O4, in 1667 is a misprint for Ethyl-
propyl- etc.
Methylpropylphenylbenzyl aminomum bromide.
Ci7H22NBr = (Me) (Pr) (Ph) (PhCHj) N.Br.
At 25^ A(32)=86.9, (1024)=91.6. In Et ale; 1903a.
cis-aai-Metiiylpropylsucdnic add.
C8Hi404= CQ2H.CHMe.CHPr.CQ1H.
kAXlO* at 25^=2.71; m. p. 92**-93^
m(26.5)=28.4, (212.0=74.7, (00)- [351]; 236.
froiu-aai-Methylpropylsucdnic add. C8H14O4.
kAXlO* at 25**=3.35; m. p. 158M60^
m(55.0)=44.4, (440.0) = 110.3, (00) =[351]; 236.
c»-5ym.-Methyl-tso-*propylsucdnic add. C8H14O4.
kAXlO* at 25''=6.6; increases on diln.; m. p. 125**-126**.
/i(90.8)=75.4, (726.4) = 173.8, («>)=[351]; 236.
fran«-5ym.-Methyl-tso-propylsuccinic add. C8H14O4.
kAXlO* at 25**= 1.54; increases on diln.; m. p. 174M75^
/i(161.7) = 51.8, (1293.6) = 127.1, (00)= [351]; 235."
N-Methyl pyrazole. C4H6N2.
ksXlO" [at 25**]=1.1 (catal.); b. p. 127**; 428.
Met] TABLES 215
S-Methyl pyrazole. C^HeNs.
kBXlO^^ [at 25**]-3.6 (solub.); b. p. 202*»; 428.
Mefhylpyridine see Picoline.
2-Mefhylpyridine-8,5-dicarboz7lic add. C8H7O4N.
kAXlO"at 25**=2.
/i(128)- 138.6, (1024)«264.4, (a>) = 353; 1372.
2-Methylpyridine-8,6,6-tricarboz7]ic add. C^HTOeN.
At 25^ /i(128)=285, (1024)-468; 1372.
Na.A at 25^ iLi(32)=84.3, (1024) = 115.1; 1369.
4-Mefhylpyridine-3,5,6-tiicarbozy]ic add. (7-Methyl- etc.).
CaHTOaN.
At 25^ m(128)=343, (1024) « 538; 1372.
Methylpyridinium hydroxide. CeHgON » CsHsN.MeOH.
At25^ A(32)«217.4, (256)=224; 763.
B.CK-CfiHfiN.MeCl) at 25^ A(32)-99.7, (1024)-112.2; 270.
- B.I, in pyridine; 768. - B.I.Bri; m. p. 68^-69**, cond.
when molten; 1678.
N-Methyl-pyrrolidine-aa -dicarbozylic add. C7H11O4N.
kAXlO^ at 25** is over 1. /i(32) « 198.8, (1024)=620.1; m. p.
273**-274**; 1OT9.
l-MethylpyrrylglyozyHc add. C7H7Q8N=Me.C4H«N.CO.C02H.
kx X 10* at 25**= 2.7 aq. /i(30) = 208, (960) - 340, ( » ) = 357 ; m. p.
142.5**; 23.
Cond. not increased by boric acid; 1186.
^MefhylpyTrylketone-6-carbozylic add. (a- or psetMio-Acetylcarbo-
pyrrolic acid. 2-Acetyl-pyrrole-5-carboxylic acid.)
O7H7Q8N-MeCO.C4H8N.CO2H.
kx XlO^ at 25** « 3 aq.; increases, then diminishes on diln.; m. p.
186**; 23, 1186.
m(40)=37.0, (1280) = 163.7, (»)-357; 23.
Cond. with boric acid; 1186.
2-Methyl quinoline see Quinaldine.
4-Methyl quinoline see Lepidine.
6-Methyl quinoline see p-Tolu quinoline.
Methylquinolinium hydroxide. CioHuON- C9H7N.MeOH.
At 0**, A(32)»209; changes in soln. to Methylquinolinium oxide;
763.
B.Cl (=C9H7N.MeCl) at 25**, A(32)=92.0, (1024) = 104.4; 270.
- B.I, in propionic aldehyde; 1844. - B.I.I2, m. p. 108.6**-
109.6** and B.I.I4, m. p. 72**-73**; cond. when molten; 1578.
Methyl-£so-quinolinium hydroxide. CioHuON.
AtO^ A(32) =206.9; 768.
B.CK-CgHTN.MeCl) at 25^ A(32)=92.4, (1024) -104.6; 270.
216 TABLES [Met
Methylquinolinium oxide. CtoHioON2» (C9H7NMe)20.
No cond. in aq.; 763. [In 768 it is claimed that this compound
was prepared pure. Decker (Ber. Deutsch. Chem. Ges. 36,
1210) could not make a pure compound of this description.]
Methyl Red see p-Dimethyl-amino-azobenzene-o-carbozylic add.
Methylsalicylic acid see o-Methoxy-benzoic add.
Methylsuccinic acid see Pyrotartaric add.
Methyl sulphide see Dimethyl sulphide.
Methyl sulphuric acid see Sulphuric add mono methyl ester.
Methyl sulphurous add see Sulphurous add mono methyl ester.
Methyltartaric add see Tartaric add mono methyl ester.
/3-Methyltetramethylene diamine.
CfiHuNj^ NH2.(CH2)2.CHMe.CH2.NH2.
ka XlO* at 25^=5.6 aq.; about 16% too high.
A(64)=33.8, (256) -60.6, (oo) = i97; 271.
B.2HC1 at 25^ A(32) = 104.6, (1024) = 125.6; 270.
4-Methylthiazole-6-carboxylic add. C5H5O2NS.
kx XlO* at 25^=3.9; increases on diln. A(131.1)=65.8, (1048.4)
« 163.8, (00) =357; 176.
2-Methylthiazole-4,5-dicarbozyUc add. CdHsO^NS.
kA XlO^ at 25° » 7; diminishes on diln.
/i(98.9) -317.6, (1581.6) =355, (a>)=357; 176.
meso-Methylthiazolemethylcarbozylic add see 2,4-Dimethyl-thiazole-
6-carbozylic add.
Methyl thiocarbimide. (Methyl mustard oil.) C2HsNS=CSN.Me.
X XlO^ at 50**= 3.3; b. p. 117** ® 758 mm.; 1843.
As solvent > 1844.
Methyl thiocyanate see Thiocyanic add methyl ester.
Methylthio-phenyl- see Phenyl-methylthio-
Methyl-thio-uracil. CbH^ONsS.
kAXl08at25**=5.
m(512) = 1.7, (1024) = 2.4.
Na.A at 25°, /i(32) = 241.0, (1024) = 346.3; 1748.
6-Methyl-2,3-triazo-4-hydrozy-7,0"-pyridazine.
C6H60N4= Me.C5H2N4.OH.
kA XlO^ at 25°= 1.74; decreases on diln.
A(256) = 24.3, (1024)=43.8, (a>)=376; 306a.
/um.-a-Methyltricarballylic add. {trans- acid).
C7Hio06=CQ2H.CH2.CH(C()2H).CHMe(C02H).
kAXlO* at 25° =3.2; increases on diln. /i(32) = 33.4, (1024)-
153.3, (oo)=352; m. p. 180°; 1889; - 237, 67.
ina/.-a-Methyltricarballylic add. {ds- acid). C7H10O6.
kAXlO* at 25°=4.8; increases on diln. ^(20.6)= 32.8, (165.1)-
90, (a>)-[351]; m. p. 134°-135°; 237.
Mor] TABLES 217
ma/.-a-Methyltricarba]lylic add mono methyl ester. CsHuOa.
kAXlO* at 25'' =8.93; =8.57 and 8.88 for other preparations; 237.
[The methyl group may be in different places in these three. ]
Methyltriethyl ammonium chloride. CrHigNCl^ MeEtsNCl.
At26^ A(32) = 90.2, (1024) -102.0; 270.
jym.-Methyltrimethenyl-dicarbozyUc acid. C6H604=Me.C8H(CQiH)2.
kAX 10^=5.9; increases, then diminishes on diln.; m. p. 200°.
m(64)-62.8, (1024) = 191.9, (a>)=356; 559.
Methyltriphenyl phosphonium chloride. Ci^HigClP- (Me) (Ph3)PCl.
At 25^ A(32)=80.2, (1024) = 91.3; 270.
Methyltriphenyl phosphonium iodide. CigHiglF- (Me)(Phs)PI.
In SQ2; 1855.
Methyluradl. CsHeQzNi.
kAXlO^o at 25^=3.14 (catal.); 1996;-46 (cond.); 1748.
At 25^ m(64)=0.19, (1024)=0.87, (»)= [356]; 1748.
Methyl urea. CHeONj-NHj.CO.NHMe.
Cond. with HCl; 781.
B.Oxalate at 25^ m(32) = 176.1, (1024)=228.1; 1748.
O-Methyl-iso-urea. CaH^ONa- NH2.C(0Me) :NH.
kBXlO*^ at 25^=6.4; diminishes on diln.; m. p. 44^-45*'; 285,
286.
A(32)-10.6, (612) =37.4, (»)- 239.6.
B.HClat25^ A(32)-104.1, (512) = 115.7, (1024)«118?; 286.
7-Methyl xanthine. (Heteroxanthine. 7-Methyl-2,6-dioxy-purine.)
CeHeOjN^.
kAXlO" at 40.1**=4.02 (solub.).
kBXlO" at 40.r-l.18 (solub.); 1997.
MUk; see also Casein. [The references to this are incomplete.]
Cond.; 253, 308, 1072, 1511a.
Concentration of H and OH ions; 422, 587.
Molybdenum.
Complex salts; 692, 1162, 1163, 1269, 1495, 1515, 1516, 1572.
See also the following compounds.
Molybdenum cyanic add. C8H4NgMo=H4Mo(CN)8.
4K.A at 25% A(32)- 119.3, (1024) -166.0; 376. A(32)- 118.7,
(1024)- 167.7; 1517.
Molybdenum oxalic add.
Complex salts; 692, 1495, 1515, 1516.
Molybdenum tiiiocyanic add.
Complex salts; 1162, 1163.
Morphine. CirHisQsN.
ksXlO* at 18^-1; m(2134)- 9.48, (»)- 196; 1224. At 25%
kxl0«=20 aq.; m(1708)-32.6; 1241. [It is evident from
218 TABLES [Mac
the difference in cond. of these two measurements that at.
least one of them is in error.]
X of satd. soln. at O'^-l.dlxKr^; 943.- Also 1224, 1241, for
cond.
In HCN; 943.
B.HCl at 18**; 1224. At 25^ A(32)-78.4, (1024)-90.7; 270.
With allyl thiocarbimide, no cond.; 1223.- B.HNQs.
- 2B.H2SO4; 1611. - B.MeCl; 270.
Mudc add. CeHioOg- (CH0H)4(C0sH)s.
kx XlO^ at 25^»6.3 aq.; diminishes, then increases on diln.; m. p.
213.5**; 1186; (colorim.); 1781.
At 25^ iLi(60)=62.2, (960) -186, (»)=352; 1186.
In NHs, qua!.; 606. In Et ale; 1185.
Cond. with boric acid; 1185, 1186.
Mucous membrane. [The references to this are incomplete.]
E. m. f . ; 622a.
Murexide see Purpuiic add; ammonium salt.
Muscle. [The references to this are incomplete.]
Cond.; 251, 262, 253, 622a, 624, 1666b.
Mustard oils see Thiocarbimides.
Mustard oil acetic add see Diketo-tetrahydro-thiazde.
N.
Naphthalene. CioHg.
Resistance when solid, and when molten; 983a.
In NHs, qual.; 606. In acetonitrile, no cond.; 936. In MeNHs,
no cond. ; 637.
Cond. with AlCU and EtBr; 1893. With benzene and toluene;
384. With picric acid in SO2; 1842.
Naphthalene Red. (Magdala Red). [The dye is a mixture of
aminonaphthyl-naphthazonium compounds. ]
Effect of light on cond. ; 833, 1321.
Naphthalenesulphonecyamic add see Naphthalene sulphonic add
cyanoamide.
Naphthalenesulphonecyanoamide see Naphthalene sulphonic add
cyanoamide.
a-Naphthalene sulphonic add. CioHgQsS^CioHr.SQsH.
At 25^ A(32)=318.9, (1024)-351.7; 1366.
Li.A. - K.A; 1366.- Ag.A; 1111.- Na.A at 25^ A(32)=65.0,
(1024) -78.4; 1366.
a-Naphthalene sulphonic add cyanoamide. (a-Naphthalenesulphone-
cyamic acid. a-Naphthalenesulphonecyanoamide).
CiiH8Q2N2S-C,oH7S02.NH(CN).
Hap] TABLES 219
kx XlO^ at 25° » 1.6. [Incorrect in the original.]
A(1950)=57.7, (3900)=76.4, (oo)«354; 70.
/^-Naphthalene sulphonic add. CioHgOaS » CiqHt.SOsH.
IcaXIO* at 25^=2.7 aq. A(39.9)« 360.3, (1278)=378.1, (»)-
378.2; m. p. 122^-124**.
K.A.- Na.A at 25^ A(256)=76.7, (1024)=79.6; 1940.
/S-Naphthalene sulphonic add cyanoamide. (jS-Naphthalenesul-
phonecyamic acid. /S-Naphthalenesulphonecyanoamide).
CuHsQiNaS- CioH7S08.NH(CN).
kAXl0*at25**=6.9.
A(2368)« 113.2, (4736) = 135.1, (<»)=354; 70.
1,4-Naphtfaaleiie sulphonic add azo-j3-naphthol. C20H14O4N2S.
2Na.A (Roccelline) at 18**, ^(32) = 102-1 15. Cond. with H2SO4;
1796, 1798.
Naphthalic add see Hydroxy-naphthoquinone.
a-Naphthoic add. (Naphthalene-1-carboxylic acid). CuHsOs.
kAXlO* at 25^-2; m. p. 160**; 176, 71.
A(2133)-167, (a>)=350; 176.
Cond. with NaOH; 1017.
jS-Naphthoic add. (NaphthaIene-2-carboxylic acid). C11H8O2.
kAXlO* at 25*^=7; m. p. 182%- 176, 71;-5; 70.
A(3124)« 128.3, (a>)=350; 176.
Cond. with NaOH; 1017.
a-NaphthoL (l-Hydroxy-naphthalene.) CioHgO.
kAXlO^ at 25** is about 1. A(500)=0.80, (1000)-1.15; 1823.
HBr; 29. In NHs, qual.; 606. In MeNH2, good cond.; 687.
/S-Napkhol. (2-Hydroxy-naphthalene.) CioHgO.
In HBr; 29. In NHs, qual.; 606. *In MeNHj, good cond.; 637.
Cond. with picric acid; 1042, 1842.
/3-Naphthol Violet see Meldola Blue.
Naphthol Yellow see 2,4-Dinitro-l-naphthol-7-8ulphonic add.
o-Naphthonitrile. CuHtN = C10H7.CN.
In HCN, no cond.; 943.
/S-Naphthonitrile. C11H7N.
In HCN, no cond. ; 943.
a-Naphthyl amine. (1-Amino-naphthalene.) C10H9N.
kBXl0i<> at 15**=2.8 (colorim.); 1777. At 25**=0.99 (part.);
648.
In HBr, HI and HsS, no cond. ; 1897. In NHs, qual. ; 606. In
benzene, alone and with picric acid, no cond.; 1802.
B.HCl at 25^ A(IOO)- 112.2, (400) = 124.8; 1864. Eflfect of
diazotization on cond.; 1601. - 2B.H2SO4; 1864.
/3-Naphthyl amine. (2-Amino-naphthalene.) C10H9N.
kBXlOi<> at 16**«3.9 (colorim.); 1777. At 25**=2.0 (part.); 648,
220 TABLES [Nap
In HBr, little cond. In HI, no cond.; 1897. In H2S, no cond.;
27, 1897. In NHs, qual.; 606. In benzene, alone and with
picric acid, no cond.; 1802.
B.HCl at 25% A(IOO)- 105.6, (400) -118.5; 1864. Effect of
diazotization on cond.; 1601.- 2B.H2SO4; 1864.
l-Naplithylamine-2,4-disalphomc add.
CioH«0«NS,-=NH2.CioH5(SOsH)2. [NHj-l; HSQ8«2,4.]
(Colorim.) [kA X 10* is about 1.7]; 1773.
l-Nap]ithylamine-2,5[?]-di8ulphomc add.
CioHgOftNSj. [NHj-l; HSQ8-2,5 [?].]
At 25% /i(64)- 317.2, (1024) -377.4; 492.
l-NaplithylA2iiine-4,6-disiilphonic add.
CioHgOftNSj. [NH,-1; HSOs-4,6.]
At 25% m(64)- 197.6, (1024)-313.8, (»)- [350]; 492; (colorim.)
1773.
l-Nap]ithylA2iiine-4,7-di8i]lplionic add.
CioHgO«NS». [NHj-l; HSOs-4,7.]
At 25% /i(32) = 174.0, (1024)-335.6, (»)= [350]; 492; (colo-
rim.); 1773.
Na.A (Dahl's salt); catal. shows that one sulphonic acid group
is much dissociated, the other is little dissociated; 967.
l-NaphthylA2iiine-4,8-di8ulphomc add.
CioHgOaNSj. [NHj-l; HSQ8«4,8.]
Almost no acid reaction; (colorim.); 1773.
l-Naphthylamine-6,7?-di8ulphonic add.
QoHgOeNSa. [NH,= 1; HS08-5,7?.]
No acid reaction; (colorim.); 1773.
2-Naphthylaxnine-3,6-disulphonic add.
CioHaOftNSj. [NH2-2; HSOs- 3,6.1
About as strong as the l-Naphthylamine-4,7-disulphonic acid
(colorim.); 1773.
2-Naphthylamine-4,8-disulphonic add.
C10H9O6NS2. [NH2-2; HSOs-4,8.1
At 25% iLi(64)-112.8, (1024)-226.4, (co)-[350]; 492. [From
this measurement kx X 10* is about 2. ]
2-Naphthylamme-6,8-disulphonic acid.
CioHaO^NSj. [NH2-2; HS08-6,8.]
No acid reaction (colorim.) ; 1773.
l-Naphthylamine-2-sulphomc add.
CioH90,NS=NH2.CioH«.SQ8H. [NH2-1; HS08-2.1
kxXlO* at 25''=2.2; diminishes on diln.; 492, 604; (colorim.);
1773.
At 25% iLi(64)= 238.0, (1024) -327.6, (»)=351; 492.
Nap] TABLES 221
l-NaifththylA2iiine-4-8i]lphoiiic add.
QoHgQsNS. [NH2-I; HSQ8-4.1
kAXlO* at 25''»2; diminishes on dUn.; 498, 604.
At 25^ m(1024)= 258.7, (2048)-282.8, (a>)-351; 498.
l-Naphfhylainine-5-8ulphonic add.
CioHgOsNS. [NH,-1; ESQ.- 5.]
kAXlO^ at 25''" 2.4; diminishes on diln.; 492, 604; (colorim.);
1773.
At 25% m(256)-77, (1024) = 130.6, (a>)-351; 498.
l-Naphfhylamine-B-sulphonic add.
CioHgQsNS. [NH,= 1; HSQs^C.]
kAXlO* at 25**- 1.96; 498, 604; (colorim.); 1773.
At 25% m(256)-70.3, (1024) -126.0, (a>)=361; 498.
l-Naphthylamine-7-siilphonic add. CioHgOsNS. [NHs»l; HSQ8-7.]
kAXlO^ at 25''»2.3; diminishes on diln.; 492, 604; (colorim.);
1773.
At 25% /i( 128) -55, (1024)-132, (a>)=351; 492.
l-Naphthylamine-a-sulphonic add. CioHgOsNS. [NH«-1; HS0s»8.]
kxXlO^ at 25''- 1.02; 498, 604. No acid reaction, (colorim.);
1773.
At 25% iLi(1024)=34.1, (2048)-47.4, (»)=351; 492.
8-Naphthylamine-l-8ulphonic add. CioHgOsNS. [NH2-2; HSOs»l.]
About the same strei^gth as the l-Naphthylamine-2-sulphonic
acid, kAXl0*=2.2 (colorim.); 1773.
8-Naphthylamine-6-8ulphonic add. CioHgOsNS. [NH2-2; HSOs-5.]
kAXl0*at25*'=9.4; 492; (colorim.); 1773.
At 25% iLi(256)-50.3, (1024) = 93.2, (oo).351; 492.
8-Naphthylamine-6?-sulphomc add.
CioHgOsNS. [NH2-2; HS0s=6?.]
kAXlO* at 25**= 1.7; 492; (colorim.); 1773.
At 25% iLi(1024)- 118.1, (00) =351; 492.
8-Naphthylamine-7-8ulphomc add. CioHgOsNS. [NH2-2; HSQs-7.]
kAXl0^at25''=1.0; 492; (colorim.); 1773.
At 25% /i(512)-71.6, (1024) -96.6, (00) = 351; 492.
8-Naphthylamine-3-sulphomc acid. CioHgOsNS. [NH2-2; HSOs-8.]
kA XlO* at 25^-1.2; 492. No acid reaction, (colorim.); 1773.
At 25% m(512)-77.6, (1024) -104.3, (oo)=351; 492.
l-Naphthylamine-2,4,7-trisulphoiiic add.
CioHgOgNSs-NH2.CioH4(SOsH)8. [NH2-I; HSOs=2,4,7.1
At 25% /i(96)- 180.6, (1536) -233.1; 498. [kA is of the order of
10-».]
l-Naphthylaimne-3,6,3-tri8ulphonic acid.
CioHgOgNSs. [NH2-I; HS08-3,6,8.]
222 TABLES [Nap
At 25^ m(96)« 185.4, (1536) » 270.3; 492. [kx is of the order of
l(r».]
a-Naphthylamino-acetic add. (a-Naphthyl glycine).
C12H11O2N- (CioH7)NH.CH2.C02H.
kAXlO^ at 25''»3.3; diminishes on diln.; m. p. lOO"*; 196, 1840.
[k=4 is an extrapolated value.]
A(1040)=58.9, (2080)=78.1, (oo)=.350; 1840.
/S-Naphthylamino-acetic acid. (/3-Naphthyl glycine). CuHuOsN.
kAXlO*^ at 25**-5.9;.m. p. 133*'-136*'; 196, 1840.
A(660)-58.1, (1120) -74.2, (00) =350; 1840.
Naphthylamino-tso-butyric add acetyl derivative see Acetyl-/^
naphthyl-amino-tso-butyric acid.
Naphthyl glycine see Naphthylamino-acetic add.
a-Naphthylimino-diacetic add. Ci4Hi804N-CioH7.N(CH<C02H)s.
kxXlO* at 26**= 6.1; m. p. 133M34^
/x(212)=96, (848) = 166, (00) =348; 1840.
|3-Naphthylimino-diacetic acid. C14H1SO4N.
kxXlO* at 26**=2.6; diminishes on diln.; m. p. 182**-183^
/x(200)-173, (800) -248, («)-348; 1840.
/S-Naphthylnitroso amine. CioH80Ns=CioH7.NH(NO).
No cond. in aq., when pure; 600.
Naphthylphenyl- see Phenylnaphthyl-
Narcotlne. C^HnOrN.
kaXlO* at 17*'-7.9 (colorim.); 1779.' At 18^=8; 1224.
At 18^ /x(23837)=8.3, (00) = 196; 1224.
In HON, no cond.; 943.
B.HCl at 18^ /x(251.3)-89.8, (1005.2) = 101.9; 1224.
Nerium oleander. (Oleander) . [The references to this are incomplete. ]
Cond. of sap; 263.
Neurine see ^^yltrimethyl ammonium hydroxide.
New Blue R see Meldola Blue.
Nickel.
Complex and "double" salts; 427, 971, 1384, 1481, 1482, 1734,
1762, 1766, 1832, 1946. See also the following compounds.
Nickel carbonyl. C404Ni = Ni(C0)4.
X XlO» at 0**=1; 1272; -20; 28. At 20** and at -20*' ; 1272.
Nickel cyanic add. C4H2N4Ni = H2Ni(CN)4.
2K.A at 26^ A(32) = 126.2, (1024) = 146.6; 1832; 971.
Nicotine. C10H14N2.
At 26^ /x(32) = 1.87, (1024) =32.0; 1306. [This gives a value of
kfiXlO^ increasing from 0.3 to 3.]
In HBr, fair cond. In HI and H2S, good cond. ; 1897. In HCN,
no cond.; 943. In H2S; 1646. In NHs, qual.; 606.
Nicotinic acid see PyTidine-3-carbozylic add.
Ifit] TABLES 228
iso-Nicotiiiic add see Pyridine-4-carbozylic add.
Night Blue. C38H41N8.HCI.
The dye is the chloride of p-Tolyl-tetraethyl-triamino-diphenyl*
a-naphthyl carbinol, with the formula given above.
Cond. of soln. at 25'', showing the effect of dialysis; 186, 186a.
Niobium see Columbium.
Nitr- see Nitro-
Nitric add. HNOs. [The references to this are incomplete.]
At 26**.
V (16) (32) (128) (512) (1024) Unit -reciprocal ohm.
A 383.8 389.1 389.5 390.5 392.3., (Tower, Conductivity of
Liquids).
Nitric add amyl ester. (Amyl nitrate). CsHuOsN»N02.0CsHu.
xXl(Fat25**=2.6.
Cond. with Cu oleate; and as solvent; 1669. Effect of tempera-
ture on cond.; 106.
Nitric add iso-butyl ester. (tso-Butyl nitrate).
C4H9Q8N-NO2.OC4H9.
X XIO* at 25*' is less than 2; b. p. 120M24*' @ 728 mm.
Cond. with AgNOs and organic compounds; 1388. Effect of
temperature on cond.; 106.
Nitric add ethyl ester. (Ethyl nitrate). C2H60sN»N02.0Et.
xXlO^ at 0*^=2.26; b. p. 87.2*» @ 767 mm.; 1844; 1843. At
25*^=1.0; 1847; 1844,1669.
Cond. with organic salts; 1669, 1844, 1847. Effect of tempera-
ture on cond.; 106. As solvent; 1669, 1844, 1847.
Nitric add methyl ester. (Methyl nitrate). CH808N-N02.0Me.
X XlO* at 25** =4.52; b. p. 64.4** @ 730 mm.
Cond. with AgNOs and organic compounds; and as solvent; 1388.
Nitric add propyl ester. (Propyl nitrate). CaHyOjN-NOa.OPr.
In HCN, no cond. ; 943.
Nitroacetaldehyde ozime see Ethylnitrolic add.
Nitro-acetaldehyde phenylhydrazone.
CgHgQaNs- Me.C(NQ2) -.N.NH.Ph.
No cond. in aq. soln.; m. p. 141**-142®; 78.
Nitroacetic add ethyl ester. C4H7O4N » N02.CH2.C02Et.
kA XlO* at 25''»1.4; diminishes on diln.
A(29.1) = 2.5, (465.8) =9, («>)== [380]; 1092, 1667.
Nitroacetone. CaHjOjN^ Me.CO.CH :NO.OH.
kxXlO* at 25**= 1.0; m. p. 49^
/x(32)-6.4, (256) = 18.0, (oo)«358; 1137.- 782. Qual.; 780.
InEtalc; 782.
1^-Nitroacetophenone. (iso-Nitro- etc.).
C8H708N=Ph.CO.CH:NO.OH.
224 TABLES [Nit
kxXlO* at 25'*=6.3; increases on diln.; m. p. 108^
m(256)«41.1, (1024)-79.2, (oo)-350; 780.- 782.
In Et ale. ; 782.
Na.A at 26^ /x(128)-65.0, (612) -70.0; 780.
Nitro-aldehydo- see Aldehydo-nitro-
Ifitroamide. H202N2«N02.NH2. [The references to this are in-
complete.]
kAXlO'^ at 0** is about 3. m(26.8)-0.86, (63.1) = 1.13; 141, 146,
766.
In NHa; 610.
If itroamino- see Axninonitro-
Nitroanilic acid. (3,6-Dinitro-2,5-dihydroxy-p-benzoquinone).
C6H2O8N2.
/i(31.6)» 634.1; decomposes in soln.; 729.
o-Nitroaniline. C6H6O2N2-NO2.C6H4.NH2.
No acid properties (part.); 648.
kBXlO^* at 26^-1.5 (solub.); 669, 1116;-0.66 (part.); 648.
In benzene, alone and with picric acid, no cond.; 1802.
B.HClat25^ A(IOO) = 378.3. - B.H2SO4; 1864,
m-Nitroaniline. C6H6O2N2.
kaXlO" at 17**-3.2 (part.); 683. At 25**-4 (solub.); 1116;
(part.); 648.
In HBr, HCl and H2S, no cond.; 1897. In NHs, little or no
cond.; 606, 610. In benzene, alone and with picric acid,
no cond.; 1802.
B.HCl at 26^ A(50)- 182.1. - B.H2SO4; 1864.
p-Nitroaniline. C6H6O2N2.
kBXlO^* at 25^=1.1 (solub.); 1116; =0.12 (part.); 648.
In HBr and H2S, no cond.; 1897. In NHt, little or no cond.;
606, 610.
3-Nitroaiiili]ie-6-8ulphomc acid.
C6H«06N2S=NH2.C6H,(N02).SOtH. [NH2=1; NQ2-3;
HS08=6.]
kAXlC at 25^=8.5; increases on diln.
A(64) = 180, (512)=324.1, (oo)=355; 492.
p-Nitroanisole. (l-Methoxy-4-Nitrobenzene| p-Nitrophenol methyl
ether). C7H708N= NO2.C6H4.OMe.
In aq. and in Me ale, very small cond. In HCO2H, no cond.;
746. In NHa, qual.; 606.
Ifitrobarbituric acid. C4Hs06Ns.
At 26^ /x(32)=323.4, (512) = 341.4, (oo)-366; 846. 1748.
Cond. with NaOH; 846.
Na.A at 25^ m(32) =67.0,' (1024) -77.1; 1748.
Hit] TABLES 226
m-Nitrobenzaldehyde. C7H6O8N-NQ2.C6H4.CHO.
In NHs, qual.; 606. In MeNHs, Httle oond.; 637.
p-Nitrobenzaldehyde. QHsOsN.
kAXlO" at 18° is about 3 (hydro!.).
Cond. with NaOH; 632.
Ifitrobenzamide see Nitrobenzoic add amide.
Nitrobenzene. C6H602N= Ph.N02.
X at 0** is extremely small; 923. At 20**, x Xl0'=1.8; 1690a. At
25^ xXlO^ is less than 0.2; 617, 923, 1388;- 1.13; 1844;
- 941, 1106, 1107, 1669.
In HBr and HI, good cond. In HjS, no cond. ; 1897. In NHa,
qual.; 606. In MeNH2, little cond.; 637.
Cond. with HCl; 1663. With inorg. and organic compounds;
923, 941, 1106, 1107, 1223, 1388, 1669, 1844. Dielectric
constant; 682. As solvent, under pressure; 1690a. As
solvent; (147), (291a), (293), 923, (941), (1444a), 1669,
1690a, (1818), 1844.
p-Nitrobenzene-azo-a-naphthol sulphonic acid.
Ci«Hii08N,S-OH.CioHa.N2.C6H3(N02).S08H.
kA is about the same as that of phenolphthalein (colorim.) ; 818.
p-Nitrobenzene diazonium hydroxide. (p-Nitro diazo benzene).
CeHsOjNt- NO2.C6H4.N2.OH.
kx XlO^ at 0° decreases, from 8.8 to 4.0, on account of decompo-
sition. A(128)- 12.9; 601.
Na.A at 0^ A(1024-32)-4.8. At 25^ A(32)-66.2, (1024)-77.1;
774.
iso-p-Nitrobenzene diazonium hydroxide. (p-Nitrophenylnitrosoa-
mine). CeHeOsNs.
B.C1(=N02.C6H4.N2.C1) at 0^ A(512)=76.5; 601.
m-Nitrobenzene sulphimide.
In MeNH2, good cond.; 637.
o-Nitrobenzene sulphonic add amide.
C6H804NaS= NO2.C6H4.SO2NH2.
Cond. with NaOH; 781.
m-Nitrobenzene sulphonic add. CsHsOsNS - NO2.C6H4.SO3H.
At 25% A(32)-326.0, (1024) = 355.6; 1366.
Li.A. - KA; 1366. In NHa; 607. - Na.A at 25% A(32)-68.0,
(1024) -78.8; 1366. Alone and with Na«S; 660a.
m-Nitrobenzene sulphonic add amide.
C«H604N2S= NO2.CCH4.SO2NH2.
In NHa; 607, 610. In MeNHa; 606.
Cond. with NaOH; 781.
p-Nitrobenzene sulphonic acid amide. C6H6O4N2S.
Cond. with NaOH; 781.
226 TABLES [Ifit
o-Nitrobenzoic acid. C7H6O4N = NO2.C6H4.CO2H.
k diminishes on diln. in almost all these measurements. See
1342 for explanation that this is not due to impurity.
kAXlO* at 0*'=10 aq.; 616. At 10^=7.6. At 15°-7.07; 1342.
At 18^=7 (colorim.) 1663. At 20^-6.66; 1342;=6.96 aq.;
616. At 25^=6.15; 616, 666, 1371, 1681; (hydroL); 1972,
1973;=6.02; m. p. 146.33° cor. and 146.27** cor.; 1342. At
30''»5.86aq.; 616;»5.48; 1342. At Sd^'-d.SQ aq.; 616. At
40^=4.94 aq.; 616, 1681. At 45*'-4.53 aq.; 616. At 50**=
4.14 aq.; 616, 1681. At 60^=3.4 aq. At 70**- 2.8 aq. At
80^-2.4 aq. At 90^-1.9 aq. At 99**= 1.6 aq.; 1681.
[Values in 1681 are approximate. ]
Of satd. or nearly satd. soln., at 25**= 6.03; 1342.
Cond. at 0*»-35^ 616, 911, 1342. At 25**-99**; 1681, 616. At
25^ A(32) = 140.2, (128.2) = 223.8, (00 )«396.9; 1342. A(128)
-205.3, (1024)=312.3, (oo)«355; 1371.
In HBr, no cond.; 30. In HCN, small cond.; 943. In NHt,
qual.; 606. In Et ale; 647 and 144, 1820. In MeNHs,
good cond.; 637. In pyridine; 764.
Na.A at 25^ A(32)=66.7, (1024) =76.4; 1368a. At 25**-99**;
1681.
m-lfitrobenzoic add. C7H(04N.
kxXlO* at 0**=2.98 aq.; 615. At 18**=3.5 (colorim.); 1663. At
20*»=3.35 aq.; 615. At 25**=3.45; 1371, 616, 1681. At
30** = 3.43 aq.; 616. At 35** =3.45 aq.; 616. At40**=3.47aq.;
616, 1681. At 45**= 3.47 aq.; 616. At 50** =3.48 aq.; 616,
1681. At 60** =3.5 aq. At 70** =3.3 aq. At 80** =3.1 aq.
At 90** =2.9 aq. At 99**= 2.6 aq.; 1681. [Values in 1681
are approximate.]
Cond. at 0**-35**; 616, 911. At 25**-99**; 1681, 616. At 25^
A(64)=48.7, (1024) = 157.6, (oo)-355; 1371.
In HBr and HCl, small cond.; 30. In NHs, qual.; 606. In
N2O4, no cond.; 602.
Na.A at 25**, A(1000) = 78.3; also at 0**-50**; 616. At 25**-99**;
1681.
m-Nitrobenzoic acid amide. C7H60sN2= NOs.CftH4.CONH2.
Cond.; 1479.
p-Nitrobenzoic add. C7H6O4N.
kxXlO* at 18**=4 (colorim.); 1663, 1781. At 25**=4.01; dimin-
ishes on diln.; 1371.
At25^ A(256) = 97, (1024) = 164.7, («)=355; 1371.
In HBr, no cond. ; 30. In NHs, qual. ; 606.
Na.A at 25^ A(32)-67.4, (1024) =76.4; 1368a. At 25**-99**;
1681.
Hit] TABLES 227
p-Nitrobenzdc add amide. CrH^OaNs.
Cond.; 1479.
o-Nitrobenzoyl-malonic acid diethyl ester.
Ci4Hu07N=C6H4(NQ2).CO.CH(CQ2Et)2.
kAXlO* at 25^=2.08. m(1200)«136, (2400)-174, (oo)=349.
K.A.- Na.A at 25^ /x(32)=61.1, (1024)-70.2; 1823, 1831.
St-Nitro-S-bromobenzoic add.
C7H4O4NBr-NO2.C6H3Br.CO2H. [CQ2H-I; NO2-2;
Br=3.1
kAXlO* [at 25^-3.4.
A(1024)-287, (oo)-353; 849.
S-Nitro-St-bromobenzoic add. C7H404NBr.
kxXlO* [at 25^1=1.16.
A(256) = 278, (1024) - 328, ( » ) - 353 ; 849.
6-lfitro-St-bromobenzoic add. C7H404NBr.
kAXlO* [at 25^]«9.1; increases on diln.
A(256)=286, (1024)=324, (oo)=353; 849.
6-Nitro-3-bromobenzoic add. C7H404NBr.
kxXlO^ at 25^»1.5; increases on diln.; 849;»1.4; diminishes
on diln. ; 1371.
A(256)=290, (512)-318, («)-355; 849.
mtrobromomethane. CH202NBr » CH2(N02) (Br).
A(32)-0.1; b.p. 145^-146°; 780.
Nitrocaproic add. C«Hu04N=C6Hio(N02).C02H.
kxXlO^ at 25'' » 1.23; diminishes on diln.
A(64) = 29.9, (1024)- 102.5, (oo)=352; 1370.
Nitrocarbamic add ethyl ester. (Nitro-urethane).
C8H6O4N2 - NO2. NH.C02Et.
kAXlO*atO**=3.03. At 10**=3.85; 143. At 20^=4.83; 143;-
3.9; 767. At 30^-5.71. At 40** -6.44; 143.
Cond.; 141, 143, 782. At 20^ A(32)-40.9, (256) = 104.4, (00)-
351.9; 143.
In Et ale; 754, 782. In piperidine and in pyridine; 754.
NH4.A in NH3; 610. - Na.A at 0*^-40^ at 20^ A(IOOO)- 100.5;
143.
m-Nitrochlorobenzene. CeHiC^NCl.
In NHs, qual. ; 606.
p-Nitrochlorobenzene. C6H4Q2NCI.
In NHt, qual.; 606.
2-Nitro-3-chlorobenzoic add.
C7H4O4NCl-NQ2.C6H3Cl.CQ2H. [CQ2H-I; NQ2-2;
CI- 3.]
kA XlO* [at 25^1-4.5; diminishes on diln.
A(512)=268, (1024)-298, (oo)=356; 849.
228 TABLES [Nit
d-Nitro-i-chlorobenzoic add. C7H4O4NCI.
kx XlO^ at 25^b1.0; diminishes on diln.
A(245.7) -271.4, (982.8) -317.7, (oo)=366; 176.
3-Nitro-2-€Uorobeiizoic add. C7H4O4NCI.
kAXlO* [at 25**]=8.7; m. p. 185^
A(256) = 267, (1024)-323, (oo)-366; 849.
8-Nitro-4-chlorobenzoic add. C7H4O4NCI.
kxXlO^ at 25''-4.6; diminishes on diln.
A(390.5) = 122.8, (1562)-196.9, (oo)«356; 176.
4-Nitro-2-dilorobenzoic add. C7H4O4NCI.
kxXlO* at 25''=1.03; diminishes on diln.
A(32.1) = 153.8, (514.1) = 302.2, (oo)-366; 176.
6-Nitro-2-chlorobenzoic add. C7H4O4NCI.
kx XlO* at 25''-6.5; diminishes on diln.; 176, 849.
A(256)-252, (1024)»309, (oo)=356; 849.
6-Nitro-3-ddorobenzoic add. C7H4O4NCI.
kxXlO^ at 25''-1.44; diminishes on diln.; 849;«1.52; dimin-
ishes on diln. ; 176.
A(256)-291, (1024) -333, (oo)«366; 849.
4-Nitro-2-€hloroiftheiiol. C6H4QsNCl-NQ2.C6HsCl.OH. [QH-1.]
kAXlO*at25**-1.8.
A (346.2) -78.6, (1380.8) -137.1, (oo)-364; 70.
8-Nitro-4-dilorotolueiie. C7H6Q2NCI.
In NHs, qual. ; 606.
o-Nitrodnnamic add. C9H7Q4N.
In NHs, qual.; 606.
m-Nitrodnnamic add. C9H7Q4N-NQ2.C6H4.CH:CH.CQ2H.
Na.A at 25^ A(32)-64.1, (1024)-76.5; 1367.
p-Nitrocinnamic add. C9H7O4N.
Na.A at 25^ A(32)-64.8, (1024) -77.0; 1367.
S-Nitrocuminic add. CioHuQ4N-C8H7.C6Hs(NQ2).CQ2H.
kAXlO* at 25^-2.16.
A(2008)- 167.8, (4016) -207.3, (00) =350; 176.
p-Nitro diazo benzene see p-Nitrobenzene diazonium hydroxide.
4-Nitro-2,6-didiloro-phenol.
CeHsQsNClj = NQj. C6H2CI2.QH. [QH = 1 . ]
kxXlO* at 25^-2.1.
A(374)-84.1, (1496)-151.2, (oo)-363; 70.
If itro-l,4-dimefhozy-benzeiie see Nitro-hydroquinone dimethyl ether.
Nitro-dimethyl-aniline sulphonic add.
CgHioQsNjS- NMe2.C6Hs(NQ2).SQ»H.
At 25^ A(32)-82.9, (1024)=90.6, (oo)-353; [this gives a value
of kx diminishing from 2 XlO"* to 8 XlO"*]; *W.
mt] TABLES 229
IVitroethane. CzHsQsN^CsHs.NOs.
No cond. in aq. soln. The salts are really the salts of iso-
nitroethane. Cond. with NaOH and Ba(OH)s showing
change to isomer; 780. [The salts are described here, on
account of their mode of preparation and the doubt as to
the structure of the isomer. ]
K.A, cond. with HgNQs; 149.- Na.A at 25^ A(32)-69.0,
(1024)=81.9; 1686.
iso-Nitroethane. C2H5O2N.
The pure compound would be as strong as acetic acid, as shown
by cond. of salts. At 0**, A(48)=9.4; 780.
Salts; see under Nitroethane.
Nitroform see Trimtro-methane.
a-Nitroformaldehyde phenylhydrazone, m. p. 74.5^-75.5^ and /3-Nit-
roformaldehyde phenylhydrazone, m. p. 84.5^-85.5^.
CtHtOjNs^ NO2.CH iNjH.Ph.
[The references are to both compounds. ]
In aq. soln., almost no cond.; 82; - 78, 1693.
Cond. in Me and Et ale; 1693.
Cond. with NaOH and HCl; 82, 1693.
Na.A; 82, 1693.
Witroguanidine. CH402N4= NO2.N rCCNHj),.
keXlO" at 40.2^=2.1 (catal.); 1996 and 1160.
In NHa; 610.
Witrohemipinic add. CioHgOgN = (MeOjCeHCNOj) (COjH),.
' [CQiH^l, 2; 0Me=3, 4; N02=6.]
kAXlO* [at 25**] « 2.1; increases on diln.
m(32)= 205.4, (256) = 335.7, (00) =374; 1684.
Nitro-hydroquinone dimethyl ether. (Nitro-l,4-dimethoxy-benzene).
C8H9O4N.
Cond. in aq. and in Me ale, very small; in HCO2H, no cond. ; 746.
3-Nitro-2-hydrozy-benzoic acid. (o-Nitrosalicylic acid).
C7H606N=OH.C6H8(N02.).CQjH.
kxXlO* at 25*'= 1.57; diminishes on diln.; m. p. 146**; 1186,
1371, 1366.
A(128)=260, (1024) = 335, (a>)=355; 1371.
In Et ale; 1186, 1608, 1718.
Cond. with boric acid; 1185, 1186. With NaOH; 1608, 1718.
6-Nitro-2-hydrozy-benzoic add. (p-Nitrosalicylic acid). CtHsOsN.
kAXlC at 25*'=8.9; 1371;=8.0 aq.; m. p. 228^-228.5**; 1186,
1366.
A(256)=267, (1024)=322, (oo)-355; 1371.
In Et ale; 1186, 1608, 1718.
Cond. with boric acid; 1186, 1186. With NaOH; 1608, 1718.
280 TABLES [Nit
Nitro-4-hydrozy-3-mefhozy-benzoic add see Nitroranillic acid.
Nitromalonic acid amide. G8Hs04Nt«CH(NOs)(CONHs)3.
kAXlO^ at 25^»5.9; diminishes on diln.
/x(128)-90.9, (512) « 157.3; 746; 1667.
Nitromalonic acid diethyl ester. C7Hu06N«CH(N02)(C02Et)s.
kxXlO* at 25^-7.3.
m(81.6)=81.2, (163.1) = 108.4; 746; 1667.
Nitromethane. CH8O2N- Me.N02.
KXl(f at 0*^=4.43; b. p. 101.5^ @ 757 mm.; 1843; - 1844. At
18''"6.4; 291. At 25''»5.44; 1843; - 1844, 1423a.
kx XlO" at 25** is about 7; 1092.
Cond.; 780, 1092. At 25^ A (10.3) =0.003, (a>)=389; 1092.
InNHs;607. In Et ale; 764. In MeNH2, fair cond. ; 637. In
pyridine, no cond.; 764.
Cond. with Ba(OH)s; 780. As solvent; 291, 1423a, 1844, 1848,
1863a.
NaA at 25% A(32) = 84.4, (1024) -108.6; 1686. In NHi; 610.
iso-Nitromethane. CH8O2N.
Very weak acid (cond.) ; 780.
Nitron see Diphenyl-endanilodihydro triazole.
l-(a)-Nitronaphthalene. C10H7O2N- C10H7.NQ1.
In H2S, no cond.; 27.
Nitroopianic acid. CioHgOrN- (MeO)2C«H(N02) (CHO).CQiH.
[CQjH-l; 0Me=2, 3; N02«5; CHO-6.]
kxXlO* [at 25**]=2.9; 1684,1906.
A(256) = 10.1, (1024)-19.5, (oo)=376; 1684.
o-Nitrophenol. CoHsQsN = NO2.C6H4.OH.
kA X10» at 0**=6 aq.; 733. At 18**- 5.6 (cond. and hydro!.); 624.
At 25^=6.8; 847;=5.6; 746;-7aq.; 733; =40; 70. At 35**
=8aq.; 733.
Cond.; 614, 1362. At 25% A(100) = l, (800)-2.6, (oo) = 355;
847.
In HBr, HCl and HI, fair cond.; 1897. In H2S, no cond.; 27,
1897. In NHs; 604, 607. In Et ale; 1608, 1718. In
pyridine; 764.
Cond. with NaOH; 1608, 1718. With cinchonine; 1620.
m-Nitrophenol. CeHeOsN.
kAXl08atlO**=0.33. At 15^=0.39; 1160a. At 25**=1.0; 847;«
0.53; 1160a, 624; 70. At 40**=0.77. At 50*^=0.95; 1160a.
Cond.; 614, 1362. At 25% A(50)=0.21, (200)-0.56, («)=356;
847.
In Et ale; 1608, 1718. In pyridine; 764.
Cond. with NaOH; 1608, 1718.
Nit] TABLES 281
p-Nitrophenol. CcHsOsN.
kxXlO* at 0^=5 aq.; 733. At 10^-4.5 (hydro!.). At 16**=6.2
(hydrol.); 1144. At 18** -5.8 (cond. and hydrol.); 624; =23
(coloiim.); 1662. At 25''»6.4 (solub.); 1116; (cond.); 847;
-7.0 (hydrol.); 1144;-4.4 (catal.); 733 and 1160;»10
(neutral.); 299; (cond.); 733; - also 70, 746. At 35''- 15
aq.; 733. At 40**- 10.2 (hydrol.). At 50**- 12.7 (hydrol.);
1144.
Cond.; 614, 666, 733, 1144, 1362. At 25^ A(32)-0.5, (512) -2.2,
(oo)=355; 847.
In NHs; 609; qual.; 606. In £t ale; 1606, 1718. In pyridine;
764.
Cond. with NaOH; 299, 1608, 1718. With cinchonine; 1620.
With trimethyl-pyridine; 1144.
Na.A at 25% A (231.1) -79.4, (923.0) -81.8; 1144. At 0**-35**;
733. At 10**-50*; 1144;-666.
p-Nitrophenol methyl ether see p-Nitroanisole.
o-Nitrophenol-4-8ulphonic add. CeHtO^NS.
K.A, cond. alone and with NaOH in Et ale; 1718.
o-Nitrophenozy-acetic acid. (o-Nitrophenyl-glycollio acid).
C8H7OBN-NO2.CeH4O.CH4.CQjH.
kAXlO»at25**-1.58.
A(64)-95.1, (1024)-244.6, (oo)»351; 1370.
p-Nitrophenozy-acetic add. (p-Nitrophenyl-glycollic acid).
CsHtObN.
kx XlO* at 25**- 1.56; diminishes on diln.
A(128)-125.6, (1024)-241.6, (oo)-351; 1370.
Nitrophenozy-malonic acid see Bis-nitrophenozy-malonic add.
Nitrophenyl-glycoUic add see Nitrophenozy-acetic add.
m-Nitrophenyi-nitromethane. C7H6O4NS- NO2.C6H4.CH2.NQs.
At 25% m(600)-5-6; 1092; 844.
The salts are from the isomeric NQ2.C«H4.CH.NO.OH.
At25%/x(320) = 132; 844.
Na.A; 1092.
p-Nitrophenyl-nitro8oamine. C8H6O8N8-NO2.C8H4.NH.NO.
Cond. showing change to isomeric diazo compound; 601.
o-Nitro-phenyipropioUc add. C9H6O4N- N02.C^H4.C i C.CO2H.
kA XlO^ at 25**- 1.08; diminishes on diln.
A(256)-272, (1024)-322, (oo)=349; 1371.
In NHs, qual. ; 606.
Nitrophenyl-trimethyi- see Trimethyl-nitrophenyl-
3-Nitro-o-phtiialic add. (a-Nitrophthalic acid).
C8H608N-NQ2.C8H8(CQ2H)2. [CQ2H-1,2.]
282 TABLES [Nit
kA XlO* at 25^ is about 1.3. » 1.2; aq. used for soln. was impure;
ld72;-1.3; 1909. In 1911 the value in 1372 is considered
the better value.
Second kxX 10^ "4.0; 1911.
At 25^ m(32) = 164, (1024)-342, (oo)=352; 1372.
Mg.A; 1836.- Na.A. - 2Na.A at 25% m(32) = 76, (1024)-93;
1838.
3-Nitro-o-phtiialic add 1-mono methyl ester.
CgHTOeN. [CQjMe^l; CQiH.=2.1
kAXlO* at 25*^=1.68; diminishes on diln.; m. p. 157^
m(63.9)- 235.4, (612.8) =336.2, (co)-375; 1909, 1938.
3-Nitro-o-phthalic add 2-mono methyl ester.
C9H7O6N. [CQ2H=1; C02Me-2.]
kAXl0'at25^isabout2; diminishes on diln.; not perfectly pure;
m. p. 146^-149^
m(128) = 151.3, (1026) = 270.6, (oo)-375; 1909, 1938.
4-Nitro-o-phtfaaUc add. (|3-Nitrophthalic acid). CgHsOeN.
kAXlO* at 25^-7.7; m. p. 160^-160.6*^; 1909;-6; aq. used for
soln. was impure; 1372.
Second kxX 10* =4.0; 1911.
At 25% m(32) = 146.1, (1028)=353.3, (oo)-376; 1909.
4-Nitro-o-phthalic add 1-mono ethyl ester.
CioHjOeN. [C02Et=l; CQ2H-2.]
kAXlO» [at 25**]-3.05; m. p. 127**; 1932.
4-Nitro-o-phtiialic add 2-moiio ethyl ester.
CioHjOeN. [C02H=1; C02Et=2.1
kAXlO» [at25^]-6.2; m. p. 137^ 1932.
4-Nitro-o-phthalic add?-mono methyl ester. C9H7O6N.
kxXlO* at 25*^=4.8; diminishes on diln.; m. p. 128^-129**.
m(64) = 157.9, (1029)-314.2, (oo)=376; 1909.
2-Nitro-p-phthalic add. (2-Nitroterephthalic acid).
CgHfiOeN^NOj.CeHsCCOiH),. [C02H= 1,4. ]
kAXlO* at 25*^=1.87; 1909.
Second kAXl0*=2.00; 1911.
At 25% m(32)-199.3, (256.4) =333.9, (oo)-376; 1909.
2-Nitro-p-phthalic add 1-mono methyl ester.
C9H7OCN. [C02Me=l; C02H=4.]
kAXlO* at 25*^=7.7; diminishes on diln. ; m. p. 174M75.5^
m(257) = 133.6, (1028)=213.2, (oo) = 375; 1909.
St-Nitro-p-phthalic add 4-mono methyl ester.
C9H7O6N. [C02H=1; C02Me=4.1
kAXlO* at 25**= 1.98; diminishes on diln.; m. p. 133^-134**.
m(64)=247.4, (1027) = 355.4, (co)=375; 1909.
Kit] TABLES 288
Nitropropane. C8H7Q2N-Et.CH2.NO2. B. p. 126^-127^
Na.A at 25% A(32)«67.8, (1024) =80.8; too high, on account of
increase of cond. on standing; 1686.
22-Nitropropane. (Nitro-iso-propane). C8H702N=«Me.CH(N02).Me.
B. p. 115**-120^
Na.A at 25'', A(32)-65.0, (1024)«93.1; approximate values;
different measurements do not agree; 1686.
a-Nitropropionic acid ethyl ester. CsHo04N»Me.CH(N02).C02Et.
kxXltf at 0**-0.67; 1667. At 25**-4.6; diminishes on diln.;
1092, 1667.
At 25% A(39.7)-1.6, (158.7) -2.7, («)= [380]; 1092.
Na.A, cond. with HCl; 1092, 1667.
The preceding salt is formed from an isomeric ester Me.C.NO.-
0H.C02Et, kxXlO* at 0''«5.85, extrapolated from cond.
of Na.A+HCl. It changes in soln. to the true ester; 1667.
/^-Nitropropionic add. C8H6O4N - CH2(N()2) .CH2.CO2H.
kxXlO^ at 25''- 1.62; diminishes on diln. A(32)-24.9, (512)-
86.3, (00) -358; m. p. 65**~67% 1840.
Nitropropionic aldehyde phenylhydrazone.
C9H11O2NS- Et.NQ2.C :N2H.Ph.
No cond. in aq. soln.; m. p. 98.5**-99.5®; 78.
Nitroprussic add see Hydronitroprussic add.
St-Nitroresordnol. (2-Nitro-l,3-dihydroxy-benzene).
C8H6O4N- N02.C«H8(OH)2.
kxXlO* at 25^-1.3.
/x(299)=21.3, (1196)-40.8, (oo)=354; 70.
4-Nitrore8ordnol. (4-Nitro-l,3-dihydroxy-benzene). C6H6O4N.
kAXl0«at25**-1.2.
m(120)-3.9, (960)-12, (oo)=:354; 70.
Nitrosalicylic add see Nitro-hydrozy-benzoic add.
Nitrosoacetic add see Ozimino-acetic add.
iso-Nitro8oacetoacetic add ethyl ester.
C6H904N-MeCO.C(:NOH)C02Et.
kx XlO* at 0^=4.0 aq. At 18^=7.3 aq.; 1296. At 25**=8.6 aq.;
m. p. 58*'-59^; 1296;=7.0; 1567. At 35**- 10.9 aq. At
40^-11.8 aq.; 1296.
At25^ A(32)=0.66, (64)-0.97, (oo)=395.3; 1296.
Na.A at 25% A(32)-67.6, (1024)=79.7; 1296; 1667.
tfo-Nitrosoacetone. C8H602N- Me.CO.CH(NOH).
kxXlO* at 18'' is about 3 (colorim.). At 25**-3.8 (catal.);-3
(cond.); m. p. 66**; 1141, 1143; -2.7 (cataL); 762; - 647,
1092.
kB X 10^^ at 25** is less than 1 (catal.) ; 1141, 1143.
284 TABLES [Nit
At 26^ A(2L6)-0.12, (43.2)-0.18, (oo)-384; 1143. 647, 1092.
Na.A at 25^ A(32)=68.8, (1024)=81.2; 647.
jS-Nitroso-benzylhydroxylamine. CyHsQiNj^ PhCHj.N(NO)OH.
kxXlO^ at 0^-5.8. At 26^=6.5.
At25^M(512) = 19.6; 736.
6-Nitro80-m-cresol. (Toluquinone-o-oxime) .
CrHTOjN-Me.CeHaCNO.OH.
kxXlCF at 25^ « 4; diminishes on diln.
A(128)-2.5, (1024) =6.6.
Na.A at 25^ A(32)=65.9, (1024) « 76.6; 547.
Nitrosocyano- see Cyanonitroso-
i50-Nitro8odiketo-hydrindene. CoHsOsN « C6H4(CO)i :C :NOH.
kAXl08at25**=1.7; 762; 1188.
A(266)=7.7, (1024) = 14.4, (a>)=354; 762.
NaA at 25% A(32)=:67.8, (1024)=80.4; 762.
Nitrosodimethyl amine. (Nitrosodimethylin).
C2H60N2=Me2N.NO.
XX 10*^ at 0**-1.192. At 25**-1.615; b. p. 149M49.5^ @ 755
mm.; 1844, 1843. At 19''»20; 1863c.
At 19% A( 15.0) =0.41; 1863c.
Cond. as solvent; 1844, (1863c).
p-Nitro80 dimethyl aniline. CgHioONt^ NO.C6H4.NMe1.
keXlO^® at 25**= 1.95 (part.); 648.
Nitrosodimethylin see Nitrosodimethyl amine.
Nitrosomethyl- see also Methylnitroso-
Nitrosomethylacetone see tso-Nitrosomethylethyl ketone.
p-Nitroso-methylaniline. C7HgON2= NO.C6H4.NHMe.
kxXlO" at 6*^=1.12 (part.).
ksXlO^® at 6^=1.63 (part.); 648.
iso-Nitrosomethylethyl ketone. (Nitrosomethylacetone.)
C4H702N=Me(NOH:)C.COMe.
kxXlO^® at IS^'^l.S aq.; m. p. 76^
Na.A at 25% A(100)=83.4; 1296.
fio-Nitrosomethylpropyl ketone. (Ethyl iso-nitrosoacetone).
C6H902N=MeCO.C(:NOH)Et.
kAXl0i«at25**=3.1 (cataL); 752.
4-Nitroso-l-naphthol. (a-Naphthoquinone oxime. a-Nitroso-a-naph-
thol. 4-Nitroso-l-hydroxy-naphthalene) .
CioH702N=NO.CioH«.OH.
kAXl07at25**=2.6.
m(1024) = 5.7, (2048) = 8, (»)=[355]; 1748.
2-Nitro80-l-naphthol. (|3-Naphthoquinone oxime. /3-Nitroso-a-naph-
thol). C10H7O2N.
Hit] TABLES 285
kAXlO* at 25^=2.6.
m(612) = 1.4, (1024) = 1.8; 1748.
l-lfitro80-2-naphthol. (/S-Naphthoquinone ozime. a-Nitroso-/3-
naphthol.) C10H7Q2N.
kAXlO»at25*'=2.6.
/i(512)»1.4, (1024) = 1.8; 1748.
InNHs, qual.; 606.
Y-iso-Nitroso-jS-nitrosoamino-crotonic add efhyl ester. C6H9O4N8.
NH4.A (=C«Hi204N4), at 18% X of 0.511 g. in 50.1 cc. aq.-3.7x
10-*; m. p. 170^ 626.
4-lf itrosoordnol. C7H7OSN = Me.C6Hs(0H)s.N0.
Yellow isomer; dec. 163**.
kAXlO*at25*'-3.7; 777;=3.3; 810;-4.5; 547.
At 25% m(512)«108, (1024) = 130; 777. - 782.
InEtalc; 777,782.
K.A, A(32)=88.8, (1024)=99.8, - Na.A, A(32)=67.3, (256)-
73.5; 810.
Red isomer; dec. 124**-125**.
kAXlO* at 25^=5.1.
Cond. in aq. and in £t ale; 777. 547. At 25"", m(128)-85,
(1024) = 190; 777.
Nitroso-ozindole see Isatozime.
p-Nitrosophenol. (Benzoquinone mono oxime).
C6H602N=NO.C«H4.0H=0:C6H4:NOH.
kA Xl(F at 25^=3; increases, then diminishes on diln.; 547; =7.5;
1748.
Cond. in aq.; 782. At 25% m(128)=2.1, (1024)-6.4; 547.
In p3nridine; 754. In Et ale; 782.
Na.A at 26% m(32) = 67.2, (1024)=77.3; 547.
Nitrosophenyl- see Phenylnitroso-
Nitrosopropionic add see Oziminopropioiiic add.
iso-Nitrososttcdnic add see Oziminosucdxiic acid.
iso-Nitrosothiohydantoin. CsHsOsNsS.
kAXlO* at 26^=5.
A(512) = 1.8, (1024) =2.8, (oo)«358.
Na.A at 25% A(32)=77.7, (1024) =86.7; 762.
Nitroso-urethane see onfi-Diazo-urethane.
4-Nitro-2it-8ulphobenzoic add ethyl ester.
CgHjOrNS- N02.C«H3(SQsH) .CQjEt. [CO^Et = 1. ]
As strong as HCl, (colorim.) ; 960.
o-Nitrotoluene. C7H702N= Me.C6H4.NO2.
X XlO' at 25'' is less than 1.8; 1106, 1107.
In HBr; 1646. In HBr and HCl, fair cond. In HsS, no cond.;
1897. In NHs, qual.; 606.
286 TABLES [Ifit
Cond. with inorg. and organic Baits; 1106, 1107| 1893. As sol-
vent; (1893).
m-Nitrotoluene. QHtOsN.
X xl(F at 25"" is less than 1.8.
As solvent; 1106, 1107.
p-Nitrotoluene. C7H7O2N.
In HBr, good cond. In H2S, no cond. ; 1897. In NHs, qual. ; 606.
m-Nitrotoluene sulphonic add. CtHtOsNS^ Me.C6Hs(N02).SO»H.
K.A, at 25"*; x of 0.1 g. in 50 cc. aq.=7.7 XlO"*; 466a.
3-Nitro-4-toluidi]ie. QHgOaNs- Me.CeHaCNQs) .NH3.
[Me=l; NH2-4; N02=3.1
kaXlO^* at 25^=6.4 (solub.); 669.
2it-Nitro-4-toluldi]ie-6-8ulphomc acid.
C7H806N2S=Me.C6H2(N02)(NH2).SO»H. [HSQ,-5.1
At25^ A(128)=301.9, (1024)=318.9, (a>)=[355]; 492.
2it-Nitro-4-tolylhydrazine-6-8ulphonic add.
C7H906NsS-Me.C«H2(N02)(NHNH2).SO»H.
[Me-1; NO2-2; NHNH2=4; HS0»-5.1
kxXlO^ at 25''»1.3; diminishes on diln.
A(512)=79.6, (1024) =97.9, (00) -362; 492.
Nitro-trichloro-methane. (Chloropicrin). CQsNCIs^NQs.C.Cb.
X X 10^ at IS"" is less than 6; 291.
In NHs, qual; 606.
As solvent; 291.
Nitrotrimethyl-aniline see Trimethyl-nitrophenyl ammoiiitiin hy-
droxide.
Nitro-uradl. C4Hs04Nt.
kAXlO«at25**=3.25.
m(128)-7.2, (1024)-20.0, (oo)-356; 1748.
Nitro-uracilcarbozylic acid. CsHaOoNs.
At 25^ m(32)- 318.7, (1024) =349.6.
Na.A.- 2Na.A at 26% m(32)=81.3, (1024)-99.9; 1748.
Witro-urea. CHjOgNs- NH2.CO.NH(N02).
kAXlO*^ at 0*'=3.9; 141, 143. At 10^=5.5. At 20*^=7.1. At
30** =8.6. At 40** is over 9. From 0** to 20** k diminishes,
then increases on diln. ; at 30** and 40** k diminishes on diln.
because of dec; 143; [quoted?]; 767.
At 20% A(32)-19, (612)=69.0, (oo)-403.2; 143.
NaA at 20% A(1000) = 151.8; - also at 0**-40**; 143.
Nitro-urethane see Nitrocarbamic acid ethyl ester.
IVitrouB add. HNO2. [The references to this are incomplete.]
kxXlO* at 20*^=4.5; 1601; (hydroL); 678. [At25**]=6.4±10%;
139.
At 20% A(612) = 161.2, (1024)-190.6, (oo)=391.5; 1601.
Ole] TABLES 287
Nitrous add amyl ester. (Amyl nitrite). CftHuQtNoNOk.CtHu.
xXlCF at 18*^=3.6; 860. At 25**=1.8; U06, 1107;=15; 1669.
In HBr and HI, fair cond. In H«S, no cond.; 1897. In NHs,
qual.; 606. In ether; 860.
Cond. with inorg. and organic salts; 1106, 1107, 1569. As sol-
vent; 1569.
Nitrous add ethyl ester. (Ethyl nitrite). CsH50kN«N0k.Et.
A(512)s 152.6, showing complete saponification; 578.
Nitro-iso-valeric aldehyde phenylhydrazone.
CuHisQiNs- (C4H»)(NQi)C:N,H.Ph.
a-) m. p. 61.5**-52**.
/5-) m. p. 92.5**-93**.
In aq. soln., no cond.; 78.
Nitrovanillic add. (7-Nitro-4-hydroxy-3-methoxy-benzoic acid).
CgHjOeN- NQs.CeHaCOH) (OMe).CQiH. [CQjH- 1. J
kAXlO^ at 25^sl.2; diminishes on diln.
A(600)-82.8, (1200)-108.6, (oo)-353; 175.
6-Nitroveratric add. (6-Nitro-3,4-dimethoxy benzoic acid).
C9H90«N=NQ2.C6H2(OMe),.GQ2H. [CQ|H.=1.]
kAXlO* at 25^ » 3.6; diminishes on diln.
A(126) = 170, (504) =238.4, (oo)-351; 175.
Norhemipinic add dimethyl ether see Hemipinic add.
Noropianic add dimethyl ether see Opianic add.
O.
Oak. [The references to this are incomplete.]
Cond. of soln. of bark; 146.
bo-Octinic add. CbHmOs.
kAXlO* at 25**-7.7; m. p. 128M29^
m(256)-45.6, (512)=62.9, (oo)=350; 1828, 1831.
Octoaspartic add. CasHisQssNs.
Cond. with NaOH.
8K.A. - 4Na.A. - GNa.A. - 8Na.A at 28^ m(32)=45.6, (1024)-
69.9. Cond. with NaCl and NaOH; 1227.
Octyl alcohol. CsHigO.
In NHs, qual. ; 606.
Octylmalonic acid. CiiH2o04» CH(C8Hi7) (C02H)j.
kxXlO^ at 25^=9.2 aq.; diminishes on diln.
Second kxXKF =6.5 (inversion).
At 25% m(450) = 163.9, (1800)=241.6, (a>)-349; 1688.
Oenanthylic add see Heptoic add.
Oenanthylic aldehyde see Heptyl aldehyde.
Oleander see Nerium oleander.
288 TABLES [Ole
Oleic acid. Ci8HmQ2 » CitHss-CQiH.
In benzene, no cond.; 935. In amyl, Et and Me ale; 488.
Co.2A and Cu.2A in benzene, no cond.; 935.- Cu.2A cond.
with organic compounds; 1569. - Mg.2A in commercial
benzine; 931.- Ni.2A in benzene, no cond.; 985. - E. A
in aq., Et and Me ale; 488. - Na.A at 25^ A(32)»42.1,
(512)«70.6, (1024)^84.4; 945. A(32)»23, (512)^60; 488.
At 18''-75%- 488, 945. In amyl, Et and Me ale; 438. In
HON, small cond. ; 948. Cond. of thin layer; 1480.
Olive oil. [The references to this are incomplete.]
> Cond.; 1010. In commercial benzine; 931. Cond. increased by
radiimi rays; 1491.
Opianic add. (Dimethoxy-noropianic acid).
CioHio06=(MeO)i.C6H2(CHQ).CO,H. [CHO-1; CQiH-2;
MeO=3,4.]
kAXlO*atl8**=9.3(colorim.); 1568. At 25*^=8.8; 1871.
At 25^ A(128)-99.9, (1024)-212.5, (a>)«352; 1871.
Cond. not increased by boric acid; 1186.
Orange n see p-Benzene svljftiotdc add azo-/3-naphthol.
Orange m see p-Dimethyl-aminoazobenzene sulphonic add.
Orcinol. (3,5-Dihydroxy-toluene) .
C7H8Q2=Me.C6H8(OH)2. [Me=l; OH=3,6.]
kxXlO* at 25** is over 3. m(26)=0.1, (208)-0.9, (oo)-365; 70.
Cond. alone and with NaOH; 1608, 1718.
In NHs, qual.; 606.
Ordnolcarbozylic add. (3,5-Dihydroxy-phenylacetic acid).
CgHgOi^ (H0)2C6H«.CH2.C0,H. [0H=3,5; CHa.CQiH-l.l
Cond. decreased by Ba(0H)2; 1719.
In Et ale, alone and with NaOH; m. p. 165''; 1608, 1718.
Orcyl aldehyde.
C8H808=Me.C6H2(OH)2.CHO. [Me-1; OH«3,5; CH0-2.J
IcaXIO* at 25^=4.1; m. p. 179**; 648.
At 25% m(1024)»64, ((»)-354; 648.- 1718. Cond. increased
byBa(0H)2; 1719.
In Et ale, alone and with NaOH; 1508, 1718.
Orobanche hederaeolia. [O. hederafolia? Ivy broom-rape.]. [The
references to this are incomplete.]
Cond. of sap; 258. Of stem and buds; 1826.
OrselUc add. (Orsellinic acid).
C8H804=MeC6H2(OH)2.C02H. [Me=l; CQ2H-2; OH=3,6.
Possibly Me=2; CQzH^l.]
IcaXIO* at 25^=1.3; dee 175**-176°.
m(128)=43.2, (1024)-103.6, («)=358; 809.- 1608, 1718.
On] TABLES 289
Cond. increased by Ba(0H)2; 1719. Cond. in aq. and in Et ale,
with NaOH; 1608, 1718.
p-OrselHc add. (p. Orsellinic acid).
C8H804=Me.C6H2(OH)2.CO|H. [Me-1; CQiH-4; OH-3,
5.1
kxXlO^ at 25''»4.1; 1371. Measurement of 1871 confirmed;
[no data]; 809.
At 25^ m(128)-307, (1024) =355, (od)-358; 1371.
In Et ale, alone and with boric acid; 1185.
Orsellinic acid see OrselUc acid.
Orfho-foimic acid triethyl ester. (Ethyl orthoformate).
C7HieOs=CH(OEt)s.
In NHs, qual.; 606.
Ovo-mocoid. [The references to this are incomplete.]
Cond. in HCl and in KOH shows it to be more basic than acid;
1606c.
Ozalacetic add. C4H4O6.
kA XIO^ at 25''» 1.33; 926. See Hydrozy-fumaric and Hydrozy-
maldc acids, the isomers into which this acid has been split.
Oxalacetic add phenylhydrazone. C10H10O4N2.
kAXl0» at 25^-1; dec. 95^-100**; 926. See the acid.
Oxaldihydroxamic add. C8H404N2» C2Qi(NHOH)2.
kAXlCF [at 25''] =2; increases on diln.
m(32)=0.9, (128)«2.1, («)=[3801; 1353a.
Fe.A; 756.
OzaUc add. C2H204» CQ2H.CO2H.
kA diminishes on diln. in all measurements.
kAXlO* at 18**=9 (colorim.); 1662, 1663. At 20*^=6 aq.; 164.
At 25''- 10; 1371. Relative strength (colorim. etc.); 693,
1643.
Second kAXl0*-4.1 (part.);=4.9 (cond.); 370;»1.6 (inversion);
1336.
At 0^ m(32)« 169.8, (512)=223.7; 924;- 910. At 11.8°; 924.
At 15*'; 1741. At 15*'-25*'; 171, 377, 591, 1122, 1123, 1211,
1677. At 25^ M(32)=267, (512) -364, (1024) =383, («)»
3657; 1371; /i(32)»262.3, (512)-349.9; 924;- 691, 1023,
1270, 1495, 1508, 1518, 1718. At 35''; 388a, 9i24. At 50^
At 65''; 388a. - See also, 401, 556.
In HCl, no cond.; 30. In H2S04; 223, 760. In Me ale; 1579,
2029. In Et ale; 788, 789, 1579. In pyridine; 754.
Cond. with inorg. compounds; 171, 223, 556, 691, 692, 750, 1023,
1184, 1209, 1350, 1495, 1608, 1516, 1518, 1718. With or-
ganic compounds; 46, 378, 401, 556, 754, 1223, 1577, 1680,
2006. Under pressure of 1-500 atmospheres; 1427.
240 TABLES [Oa
NH4.A; ISM. - 2(NH4).A; U6a, 666, 828, 1619, 1677. In HCl,
smaU cond.; 1646.- Ba.A; 990, 991, 993, 1004.- Cd.A;
990, 991, 993. - Ca.A; 848, 990, 991, 993, 1004. - 2Ce.3A;
1496. - Cr, see Double and complex salts, also Chromioxalic
acid, and Chromium, complex salts. - Cb double salts;
1660. - Cu.A; 1677. - 2Fe.3A; 1677. - 2La.3A; 1496.
- Pb.A; 216, 990, 991, 993. - Mg.A; 990, 991, 993, 997,
1003. - 2Nd.3A; 1496. - Ni.A; 427. - KA; 164, 1619,
1660. - 2K.A; 164, 171, 427, 692, 889, 997, 1023, 1174, 1338.
1616, 1619. - 2Pr.3A; 1496. - 2Sa.3A; 1496. - 2Ag.A; 216,
990, 991, 993.- Na.A at 25^ m(32)-97, (1024) = 182; 370;
1660, 1643, 1838.- 2Na.A at 25^ m(32)»93, (1024) » 113;
1838; 370, 449, 496, 692, 1023, 1227, 1367. - Sr.A; 990, 991,
993, 1004. - 2T1.A; 10, 216. - UQ2A; 449. - 2Yb.3A; 1496.
- 2Yt.3A; 1496, - Zn.A; 990, 991, 993. - " Double " and
complex salts. The number of atoms and of acid radicals
is not given under this heading. NH4, K, Rb or Na with;
-Al; 1616, 1616;- with Sb; 1619;- with Cr; 971, 1192,
1198, 1616, 1616; - with Co; 1948; - with Cb; 1660; - with
Fe; 971, 1209, 1616, 1677, 1681a;- with Mo; 691, 692,
1023, 1616, 1618;- with Ni; 427;- with Ag; 971;- with
Te; 1630a; - with W; 692, 1023, 1616, 1616; - with V;
1616, 1616.
Oxalic acid mono amide. (Oxamic acid).
CjHaOsN- COjH.CONHj.
kAXlO» at 25^=8.5; diminishes on diln. /i(32) = 146.4, (512)-
300.2, (a>)«352; 1371.
OzaUc add di-amide. (Oxamide). C2H4O2N3-CONH2.CONH1.
In NHs, qual.; 606.
Hg salt, e. m. f . ; 963.
Oxalic acid diethyl ester. C6Hio04«C02Et.C02Et.
xxl07at25**=7.12; 1106, 1107;- 11; 1669.
In HBr, good cond. In H2S, fair cond.; 1897. In NHg, qual.;
606.
Cond. with inorg. and organic salts; 1106, 1107, 1669. Effect of
temperature on cond.; 106. As solvent; 1106, 1669.
OxaUc add dimethyl ester. CiHeOi- (C0sMe)2.
Effect of temperature on cond.; 106.
Oxalic add nitrile see Cyanogen.
Oxaltoluidic add see Tolyloxamic add.
Oxaluric add. C8H4O4N2- NH2CO.NH.CO.CO2H.
kxXlO* at 26^-4.5. /i(64)=284, («)= 360; 1371. k-0.3. /*(64)
-98.8, (1024)- 144.5; decomposes in soln.; 1748. [It is
Ozi] TABLES 241
impossible to harmonize these measurements. The acid
in 1371 may have been decomposed. ]
NH4.A, in NHs, qual.; 606. Na.A at 25^ m(32)» 168.2; de-
composes in soln.; 1748.
Ozamic acid see Oxalic acid mono amide.
Oxamide see Oxalic add di-anide.
Oxanilic add. (Anilinooxalic acid).
C8H70,N=CO(NH.Ph).CQ2H.
kAXlO* at 25^-1.2; 1371,1334; (colorim.;) 1773.
At 25^ m(32) = 161.2, (1024)=322.7, (oo)=351; 1371.
Oximino-acetic add. (Aldoxime-^j/ri-carboxylic acid. Nitrosoacetio
acid). C2H808N=H.C(:NOH)C02H.
kAXlO»at25**=l; 768;=1; diminishes on diln.; m. p. 140M41*^
with dec. ; 866.
/i(32) = 59.4, (1024)=227.6, (oo)=365; 768.
Na.A at 25^ m(32)-75.6, (1024) = 92.0; 866.
a-Oximino-butyric add. (Ethyl-sj^ketoxime carboxylic acid. Nitro-
sobutyric acid). C4H70sN=Et.C(:NOH)CQ2H.
kxXlO* at 25**=8; diminishes on diln.;-8.67; 768;=7.8; m. p.
154** with dec; 865.
/*(32)-55, (1024)=209.1, («)-359; 768. m(32) = 55, (»)-
379; 865.
Na.A at 26^ /i(32)=69.6, (1024) =85.0; 866.
/S-Oximino-butyric add. C4H7O8N.
kA at 25^ is probably about the same as that of the a-acid, as
shown by cond. of the anhydride; 768.
jS-Oximinobutyric anhydride. (Methyl-sj^ketoxime carboxylic acid.
Methylisoxazolone or Methyl-«yn-oxazolone). CiHsQsN.
kAXlO^ at 25*"= 5; diminishes on diln.
At 25^ m(512) = 142.5, (1024) = 155.1, (oo)=355. The cond. is
probably due to presence of the acid; 768.
Oximino-cyanoacetic add see Cyanonitrosoacetic addJ
Oximinomethyl- see Methyloximino-
a-Oximino-propionic add. (Methyl-«i^ketoxime carboxylic acid.
Nitrosopropionic acid). CsHsOjN-MeC.NOH.CQsH.
kAXlO* at 25**=5; diminishes on diln.=5.0; m. p. 176**-178^;
1840;=4.9; m. p. 180M81** with dec; 865;-5.3; 768.
M(32)=43.7, (1024) = 182.5, (oo)=359; 768. m(32)=45, («)-
381; 866.
Na.A at 25^ m(32)=72.0, (1024) =89.0; 865.
/3-Oximino-propionic add. (Aldoxime-oTiti-acetic acid).
CsH60sN=H(NOH:)C.CH2.CQ2H.
kAXlO* at 25**= 1; diminishes on diln. /*(64)-28.1, (1024)-
90.8, (00) =359; 768.
242 TABLES [Ozi
a-Ozimino-8ttccinic acid. (Ketoxime-an(i-acetic-carboxylic acid, iso-
Nitrososuccinic acid).
C4H606N=C02H.(NOH:)C.CH2.C02H.
kAXlO* at 25^»1.1; increases on diln.
m(32)=60.6, (1024)=249.7, (oo)=357; 768.
o^Ozimino-succiiiic acid mono ethyl ester.
QHjOfiN = CQsEt. (NOH :) C.CH2.CO2H.
kAXlO*at25**=1.9.
m(32)=26.6, (1024) = 125.9, (a))-357; 768.
/S-Oximino-succinic acid. C4H606N=CQ2H.C(:NOH).CH2.CQ2H.
In soln. decomposes instantaneously to cyanoacetic acid; 768.
/S-Ozimino-succinic add mono ethyl ester.
C6H906N=CQ2Et.C(:NOH).CH2.CO,H.
kAXltfat 25**=6.3?
m(32)=120.1, (1024)-287, (a>)-357; 768.
a-Ozimino-valeric add. (Nitrosovalerio acid. Propyl-sj^ketoxime
carboxylic acid). CBH908N-Pr.C(:NOH).C02H.
kAXlO* at 25** is over 6; diminishes on diln.; 768; m. p. 140*
with dec. ; 865.
m(32)-49, (1024) = 190.3, (oo)-356; 768. m(32)«49.4, (») =
378; 865.
Na.A at 25^ A(32)=68.7, (1024) =84.5; 866.
Y-Ozimino-valeric acid. (Methyl-«i^ketoximepropionic acid).
CBH9QsN=Me.C(:NOH).CH2.CH2.CO,H.
kA XlO'^ at 25**»2.7; diminishes, then increases on diln. m(32)»
10.4, (1024) =45.6, (00)= 356; 768.
Ozy- see also Hydroxy-. Compounds containing an OH group are
called hydroxy.
p-Ozyazobenzene. (Benzeneazophenol. Hydroxy-azobenzene.)
Ci2HioON2=0:C6H4:N(NH.Ph).
kAXlO® at 25^=4.9 (part.); 545.
At25^M(1100) = l; 546.
In pjrridine; 764.
Na.A at 25^ m(32)=62.6, (1024) =74.2. The salt, formed
from the hydroxy compound [=acid+H20] is
PhNH.N:C6H4(OH)(ONa), and is the salt of a strong acid;
546.
Ozy-iso-butyryl-jS-anilino-iso-butyric anhydride. C14H17O8N.
Na.A at 25^ A(32)=60.4, (1024) =70.5; m. p. of the anhydride
is 120^ 1840.
/3-Ozy-»o-butyryl-o-toluidino-J50-butyric anhydride. CiBHigOsN.
Na.A at 25°, A(32)=59.6, (1024) = 69.4; m. p. of the anhydride
is 95''; 1840.
Pap] TABLES 248
/9-Ozy-iso-btityryl-p-toluidino-tso-butyric anhydride. CisHiqOsN.
Na.A at 25% A(32)»59.2, (1024) » 69.0; m. p. of the anhydride
is ITO""; 1840.
2-Ozy-l,G-dihydro-purine. (Desox3rxanthine). C5H6ON4.
kAXlO^* at 25*^=2.97 (catal.); 1707.
Ozyhaemoglobin. [The references to this are incomplete.]
Cond. in aq. at 0''-39''; 625, 1665a.
Oxymenthylic acid. CioHisOs.
kAXlO* at 25** =2.1; diminishes on diln.
m(42.7) = 10.5, (1366.4) « 54.9, (a>)-351; 1372.
Ozymethylene-cyanoacetic acid see Cyanof ormylacetic add.
Oxypyridine. CsHsON.
Cond. less than that of phenol; 733.
Oxyuradl. (Hydroxy-uracil.) CiHiOsNs.
1i;aX10» at 25**- 2.5 (catal.); 1M6.
P.
Palladiism.
Complex salt; 1762.
See also the following compounds.
Panadium cyanic add. C4H2N4Pd » H2Pd(CN)4.
2K.A at 25°, A(32)- 113.1, (1024) = 134.0; 150.
thiocyanic add. C4H2N4S4Pd=H2Pd(SCN)4.
2KA at 25^ A(32) = 106.7, (1024) = 126.3; 150.
add. Ci6H32Q2^Ci5H8i.CQ2H.
In HBr, no cond.; 30. In MeNH2, fair cond.; 637.
K.A; 045.- Na.A at 89.75^ A(20)=86.0, (100) = 135.3; 1220a.
P&ncreatic jtdce. [The references to this are incomplete.]
Concentration of H and OH ions; 587.
Cond. with gelatin; 807, 808.
Papaveric see Papaverinic.
Papaverine. C20H21O4N.
IcbXIO' at 18**=2.8; 1224. At 20^=0.9 (colorim.); 1779. At
25*^=500 aq. [probably too high.]; 1241.
At 18% m(7634)=8.9, (oo)=196; 1224. At 25°, /i(6130)=81.1,
(00) = 190.5; 1241.
In HCN, no cond. ; 943.
B.HCl at 18% m(260)=82.5, (1040)=85.9; 1224.
Pftpaverinic add. Ci6Hi8OrN=(MeO)2.CeH8.CO.C6H2N(C02H)8,
kxXlO^ at 25''= 1; increases on diln.; 966, 1372.
Second kAXlO«= 7; 1911.
At 25% m(256)=273, (1024) -340.2, (oo)=350; 966.
244 TABLES [Pap
PaiMiveriaic add /3-mono methyl ester.
Ci7Hw07N-(MeO)2.CaHa.CO.C6H2N(CQiH)(C02Me).
kAXlO' at 25''-4sb20%; saponifies in soln.; m. p. Ide"*; 1909;-
7.8; 966.
m(593)=280.2, (1190)=303.2, (oo)-372; 1909. m(512)=290.2,
(00 ) =360; 966.
PapaYerinic add 7-mono methyl ester, CirHuOrN.
kAXltf at 25**«6*20%; saponifies in soln.; m. p. 196.5''-197**;
1909,966.
m(910)-322, (00) =372; 1909.
Papaverinic add ozime. (Papaverinic ketoxime). C10H14O7NS.
At 25^ m(463.5)- 380.5; 176.
PapaYerinic add phenylhydrazone. C22Hi906Nt.
kAXlO" at 26^=4.7.
m(2124) =319.6, (oo)=350; 176.
Parabanic add. C8H2C)sN2.
kAXlO' at 25^=7.5; 1996.
Cond.; 1748. At 25^ m(32)-2.1; 1996.
InNHs^qual.; 606.
Hg salt, e. m. f . ; 968.
Paraffine. [The references to this are incomplete.]
Effect of radium on cond. ; 148.
Paraffine oil. [The references to this are incomplete.]
Effect of radium and of a-rays on cond.; 687, 834.
Parafuchsine see Fuchsine.
Paraldehyde see Acetaldehyde.
Paratartaric add see Tartaric acid.
Para xanthine see l,7-Dimethyl-2,6-diozy-purine.
Pear. [The references to this are incomplete.]
Concentration of H and OH ions in pear juice; 687.
Pelargonic acid. CoHi8Qi»C8Hi7.C02H.
kAXlO*^ at 25^=1.
A(1226)=38.8, (2452)«53.1, (oo)=351; 601.
Pelargonic add ethyl ester. C11H22Q2.
In NHj, qual.; 606.
Pentachloro-butenecarbozylic add see Pentachloro-pentadiSne-car-
bozylic add.
1,1,3,4,4-Pentachloro-pentadifoe-carbozyHc add. (Pentachloro-
butenecarboxylic acid).
CfiHQsCU-CClaiCiCCLCCla.COzH.
kAX 10^-6 [no data given]; 1028, 2030.
Pentacyanin see Pentahydrozy-anthraquinone.
1,2,4,6,8-Pentahydrozy-anthraquinone. (Alizarin cyanin. Pentacy-
anin). CiiHsOr.
PV] TABLES 245
At 25"; 2Na.A, A(32)-81.1, (1024) - 119.8. - 3Na.A, A(32)-
97.8, (1024)-120.- 5Na.A, A(32)- 107.6, (1024) -148.9;
1276.
Pentamethylene-carbozylic add. (Cydopentane-oarbozylio acid).
CfHioQi.
kAXlO* [at 25^1-1.24.
A(20.9)=5.6, (667.2) -30.5, (oo)-362; 2026.
Pentamefhylene diamine. C6HmN2«NHs.C5Hio.NH2.
kaXlO* at 25**=7.3 aq.; about 16% too high; 271.
Cond.; 1364. At 25^ A(32)=28.2, (256)=67.8, (a>)=197; 271.
B.2HC1 at 25°, A(32) = 105.0, (1024) = 125.8; 270.
cJs-Pentamethylene-l,2-dicarbozylic acid. C7H10O4.
kAXlO* [at 25^1=1.58; m. p. 141**; 1410.
fraiu-P6ntamethylene-l,2-dicarbozylic add. (a/S-acid). C7H10O4.
kxXlO* at 25**= 1.2; m. p. 160**; 1410, 1638, 1859.
Second kAX 10'= 3.7 (inversion); 1638.
At25^M(70.8)=31.3, (1132) = 109.1, («)=352; 1859.
af-Pentamethylene-l,3-dicarbozylic acid. (ci8-Cyclopentane-l,3-
dicarboxylic acid). C7H10O4.
kAXlO*=5.3; increases on dUn. m(32) = 14.1, (1024)=74.8, (»)
= [3521; m. p. 120M21.5**; 1460.
frans^Pentamethylene-l,3-dicarbozy]ic acid. (^an«-Cyclopentane-l,
3-dicarboxylic acid). C7H10O4.
kAXlO*=5.0; increases on diln. /a(32) = 13.7, (1024)=73.7, (»)
- [352]; m. p. 87**-88.5**; 1460.
norm.-Pentaiie. C5H12.
In MeNH2, no cond.; 637.
Pentenic see Pentenoic.
a/3-Pentenoic add see Propylideneacetic add.
/37-Pentenoic add see Ethylidenepropionic add.
7$-Pentenoic add see Allylacetic add.
Pentinic add. CeHsOs.
kxXlO*^ at 25** =8.7; m. p. 127**.
m(32) = 18.3, (1024)=91, (oo)=356.
Na.A at 25% A(32)=67.7, (1024)=77.7; 1823, 1881.
Pentyl alcohol see iso-Amyl alcohol.
Peppermint. [The references to this are incomplete.]
Cond. of soln. of leaves; 146.
Pepsin. [The references to this are incomplete. ]
H ion concentration; 1268a. Cond. with albumin, showing
digestion; 614a.
Pepdnfibrinpeptone a. CnHMOoNe.
Cond. alone and with NaOH and HCL
246 TABLES [Pep
Nasalt, A(32)-72.3, (1024) -101.9; and A(32)«77.5, (1024) =
106.6; 1318.
Pepsinglutinpeptone a. C28H89C)ioN7.
Cond. with NaOH and HCl.
Nasalt, A(32)=75.8, (1024) = 105.5; 1318.
Peptones see Antipeptone, Pepdnfibrinpeptone, Pepsinglutinpeptone.
Also see 146b.
Perchloro-benzene see Hezachloro-benzene.
Petroleum ether. [The references to this are incomplete. ]
Cond.; 1010. Effect of a-rays on cond.; 687. Effect of radium
on cond. ; 215, 872, 873, 874, 1491.
Phenacetuiic acid. (Phenylaceturic).
CioHiiOjN-Ph.CHa.CO.NH.CH2.CO,H.
kAXlO*at25**=2.03.
M(133)=52.9, (1064) = 128.6, (oo)-350; 601.
Phenantfarene. CuHio.
In MeNH2, no cond. ; 637.
Phenanthrene-3-8tiiphonic add. Ci4Hio08S=Ci4H9.SOsH.
At 18^ A(32)=313.2, (1024)-335.5, (oo)«344; m. p. 175M77**;
1574.
Phenenyltribenzdc acid see l-Phenyl-2,3-naphthalenedicarbozylic
acid.
o-Phenetidine. (o-Aminophenol ethyl ether).
C8H11ON-EtO.CeH4.NH2.
ksXlO^® at 20**=4.64 (colorim.); 1777.
p-Phenetidine. (p-Aminophenol ethyl ether). CgHuON.
'kBXl0» at 15**=2.15 (colorim.); 1777.
Phenetole. (Phenol ethyl ether). C8HioO=Ph.OEt.
In NHs, qual. ; 606.
PhenocoU see Glycocoll-p-phenetidine.
Phenol. C6H60=Ph.OH.
xXlO^ at 43^=4.5; m. p. 39.8^; 1488.
kAXlO^o at 10^=0.56 (hydrol.). At 15**=0.66 (hydroL); 1160a.
At 18**«1.3; 1865, 1883. At 21**= 160 (solub.); inaccurate;
1116. At 24''»1.2 (catal.); 1610a and 1116, 661, 1043. At
25**«0.97 (hydrol.); 1160a;=1.2 (catal.); 733 and 1160;=
50 (cond.); 733, 70. At 40*^=1.51 (hydrol). At 50**=2.05
(hydrol.); 1160a.
Cond.; 70, 168, 733, 789, 1488, 1608, 1718, 1747, 1865, 1883. At
25^ A(32)«0.14, (256) =0.43, (oo)=357; 733.
In HBr; 29; qual.; 1897. In HCl and in H2S, no cond.; 1897.
In HCN, no cond.; 943. In NHs, qual.; 606. In Et ale;
789. In MeNH2, good cond. ; 637.
Cond. with bases; 166, 168, 169, 612, 738, 1160a, 1608, 1718.
Phel TABLES 247
With salts; 766, 1488, 1599. With organic compounds;
1669, 1599, 1747. As solvent; (1488), 1669.
NH4.A; 166, 169, 733, 1160a,; (hydro!.); 302, 302a. - E.A; 166,
168. Na.A at 25°, A(32)=72.7, (1024) = 100.9; 733; 168,
1608, 1718.
Phenol-2,4-di8ulphonic acid. C6H607S2»OH.C6H8(SOsH)2.
Stronger than Phenolsulphonic acid (hydroL); qual.; 1346.
Phenol ethyl ether see Phenetole.
Phenol methyl ether see Anisole.
Phenolphthalein. C20HMO4.
kA is probably of the order 10^^^ to 10~^°. The following values
are approximate. See 1916. Phenolphthalein is dibasic;
1916, 632. kAXlO^^'at 18** to 19**=8 (colorim.); 1662. At
23^-1.8 (colorim.); 1916. At 25**=0.76 (colorim.); 1230;-
1.7 (colorim.); 822.
Cond. alone and with NaOH in Et ale; 632.
In MeNH2, fair cond.; 637.
o-Phenol sulphonic add. C6HeO4S-HO.C6H4.HSOs.
Stronger than p- acid, (hydroL); 1346.
Cu.2A at 25^ m(32) = 67.0, (512) =81.4; 1090. - Na. A cond.
alone and with NaOH; 1608, 1718.
m-Phenol sulphonic acid. C6H6O4S.
Weaker than p- acid, (hydroL); 1346.
p-Phenol sulphonic add. C6H8O4S.
Weaker than o- acid, (hydrol.) ; 1346.
Cu.2A at 25^ m(32)=65.6, (512)=81.9; 1090. - Na.A; 1608.
Phenosafranine. Ci8Hi60N4«Ci8Hi6N40H; or Ci8Hi4N4,(+H20).
Barbier, Sisley, 86, state that they have split this into two isom«
ers. Hewitt, Newman, Winmill, Jour. Chem. Soc. 95,
577-584, (1909), say that the asymmetrical isomer (azo-
phenosafranine) is really aminophenazine. Therefore the
particular compound measured seems to be in doubt. The
arrangement here follows the old order.
Phenosafranine.
At25^ A(512)- 176.6; 770.
B.HCl (=Ci8Hi6N4Cl) at25^ A(128)-79.4, (256) = 81.7, (1024)-
83.1; 882, 1266. A(256)-90.6, (1024) -92.6; 770.
lym-Phenosafranine. (Indophenosaf ranine) .
B.HCl; 86.
osym-Phenosafranine. (Azophenosaf ranine). Aminophenazine?
B.HCl; 86.
Phenozy-acetic add. (Glycollic acid phenyl ether. Phenylglycollic
acid. Phenyloacetic acid). C8H8O8-PhO.CH2.CQ2H.
kAXlO* at 25** -7.7; diminishes irregularly on diln.; 1870, 1670.
248 TABLES [Phe
A(32)-51.2, (1024)-202.2, (a>)-353; 1370.
Na.A at 26% A(32)-64.7, (1024)-74.8; ld68a.
o-Phenoxy-butyric add. CioHuOs-Et.CH(OPh).CO|H.
kAXlO* [at 25**]-6.82; m. p. 82^-83%' IW.
a-Phenoxy-iso-butyiic add. CioHiaOa- Pl1O.CMe1.CO2H.
kAXlO* [at 25** 1-4.34; m. p. 97. 5*^-98. 2**; 193.
a-Phenozy-propionic add. (Lactic acid phenyl ether).
C9Hio08=Me.CH(OPh).CQ2H.
kAXlO* [at 25**] =7.75; b. p. 265*'-266°; 192.
/8-Phenoxy-propioiiic add. C9Hio08=PhO.CH2.CH2.CO|H.
kAXltf^ [at 25**]-5.4; m. p. 98**; 192.
a-Phenozy-iso-valeric add. C^HmOs^ Me2CH.CH(0Ph).C0|H.
kAXlO* [at 25**] « 4.66; m. p. 81.5**-82.3**; 193.
Phenylacetamide see Phenylacetic add amide.
Phenylacetamide-o-carbozylic add see Homo-o-phtfaalic add 2-mono
amide.
Phenylacetic acid. (a-Toluic acid). C8H802>»PhCH2.CQ2H.
kAXlO^y increases, then diminishes on diln. At 0**"5.4. At
13.25** -^5.4; 1968a. At 25**-5.4; 1968, 1968a;-5.5; 1371;
1673. At35**»5.3; 1968a.
Cond.; 1496. At 0*'-35%- 1968, 1968a. .At 25% A(32)-14.8,
(1024)-76, (oo)=356; 1371.
In NHs, qual.; 606. In Et ale; 1066. In MeNH2, good cond.;
637. In p3rridine; 764.
Cond. with MoOs; 1496.
Ba.2A; 1066.- NaA at 25^ A(32)»66.5, (1024)»76.4; 1368a.
- MeNH8.A; 637.
Phenylacetic acid amide. (Phenylacetamide).
CgHgON = PhCH2.CONH2.
In NHs; 610.
a-iso-Phenylacetic add. (a-Cycloheptatriene-carboxylic acid. Me-
thylene-dihydro-benzoic acid). C8H802=C7H7.C02H.
kAXlO* at 25**=3.67;=3.76 aq.; m. p. 71^
A(75.7) = 19.5, (908.0)=63.4, (oo)-377; 1633.
/3-tso-Phenylacetic add. (7-Cycloheptatriene-carboxylic acid. j3-p-
Methylene-dihydro-benzoic acid). C8H8Q2.
kAXlO* at 25** is about 4;-3.96;=4.10 aq.; 1633;»3.79; m. p.
55**; 1976.
A(104.4)=23.9, (417.8)=46, (oo)=377; 1633. A(64) = 18.1; 1976.
^uo-Phenylacetic add. (a-p-Methylene-dihydro-benzoic acid).
C8H8Q2.
kAXlO* at 25**=«3.96; m. p. 32**.
A(64) = 18.5, (1024) -68.4, (oo)=377; 1976.
Phe] TABLES 249
Phenylaceturic see Phenaceturic.
Phenylacetylamino-acetic add. (Acetylanilino-acetic acid. Acetyl-
phenyl glycine). CioHii08N=PhN(MeCO).CH2.CQ2H.
kAXlO* at 25**=2.6; m. p. 194M95^
A(200)=72.5, (1600) = 168, (a>)-356; 1840.
|8-Phenyl-7-acetylbutyric add.
CisHmOs* MeCO.CHa.CHPh.CH2.CO2H.
kAXlO* at 25^=3.2 aq.
A(32) = 11.6, (1024)-61.1, (oo)=372; 1688.
Phenylacridinemethyl- see Methyl-phenyl-acridinitiin-
Phenylacrylic add see Atropic add and Cinnamic add.
Phenylalanine see a-Anilinopropionic add and Phenyl-aminopropionic
add.
Phenylamino-acetic add. (Anilino-acetic acid. Phenyl glycine).
C8H9Q2N=PhNH.CH2.CQ2H.
kAXlO*^ at 25^=3.8; m. p. 127^-128^; 1840, 1370, 196.
A(128)«22.6, (1024)-63.5, (oo)=356; 1840.
snact-Phenyl-a-aniinopropionic add. {roc, 1^-Amino-hydrocinnamio
add. Phenylalanine). C9Hu02N=Ph.CH2.CHNH2.CQiH.
kAXlO* at 25^=2.5 (hydrol.);=950 (cond.).
ksXlO" at 25**= 1.3 (hydro!.); 947.
A(128)-3.9, (1024) = 10.8, (a>)=365; 947. Also 146b.
Cond. with organic compounds; 146a, 146b.
Na.A at 25^ A(32)-61, (1024)=72; M(32)-62.9.- B.HCl at
25^ A(128) = 108, (1024) = 112; M(128)=271; 947.
Phenylazozazolecarbozylic add. C9H8O8N2 = Ph. C2ONS. CO2H.
kx XlO* at 25*'=3.3?. A(64)=260.5, (128)=302.7, (« )=350; 768.
Phenylbenzylozyamidine see Diphenyl-benzyl-hydrozy-amidine.
Phenylboric add. C6H7Q2B = Ph.B(0H)2.
At 25°, M of 0.3792 g. in 25 cc. aq.=0.13; m. p. 216**; 1676a.
d-Phenylbromoacetic add iso-butyl ester.
Ci2Hi6Q2Br= Ph.CH.Br.COs.C4H9.
In SQ2, very small cond.; 1829; 1842.
Phenylcarbamic acid ethyl ester [7] (Ethylphenylcarbamate).
C9H11Q2N.
In NH«, qual. ; 606.
PhenylcarbopyrrodiazoHc acid see l-Phenyl-6-pyrrodiazolone-8-car-
bozylic acid.
Phenyl-di-p-anisyl carbine!. C21H20OS.
Comparative strength (colorim.); 74.
l-Phenyl-3,6-diethozy urazole. Ci2Hi6Q2Nt.
Cond. in alcoholic HCl; m. p. 53°; 18; qual.; 16.
250 TABLES [Phe
Phenyldihydro-resordnol. CuHuQi.
lux 10^ at 25^»1.2 aq.; diminishes on diln.
A(512)=28, (1024)-38.2, (a>)-374; 1688.
Phenyldihydro-resorcyllc add efhyl ester.
Ci6Hi604='Ph.C6H60(OH).CQiEt.
kx XlO* at 25^ » 6.3 aq.; diminishea on diln.
A(270.2)«45.3, (1081)-83.4, («>)=[372]; 1588.
Phenyldihydro-resorcylic acid nitrile.
CuHuQ,N-Ph.C6H60(OH).CN.
kAXlO^ at 25^«2.0 aq.; diminishes on diln.
A(339.7)=86.1, (1359)« 145.6, (oo)-373; 1588.
Phenyldimethyl- see Dimefhyl-phenyl-
Phenyldinitro-methane. C7H604N2-Ph.CH(N02)2.
In aq. too insol. to measure. Cond. in pyridine; 754.
o-Phenylenediacetic add. CioHio04-C6Hi(CHsCOkH)s.
kAXlO*-l.l; m.p. 148.5M49^
m(67.8)«28.9, (1085.4) = 102.6, (a>)-350; 81.
o-Phenylene diamine. (o-Diamino-benzene). C6H8N2-CeH4(NH2)s.
ksXlO^® at 25'' » 3.3 (part.); 548. Comparative strength (colo-
rim.); 1777. "^
Second kaX 10"- 1.45 (colorim.); 1777.
m-Phenylene diamine. C6H8N2.
Weaker than o-Phenylene diamine (hydrol.).
Second kaX 10"= 1.35 (colorim.); 1777.
p-Phenylene diamine. CeHgNi.
Stronger than o-Phenylene diamine (hydrol.).
Second kaX 10 "« 2.48 (colorim.); 1777.
o-Phenylene diamine 3-sulphonic add. (Diamino-bensene sulphonic
acid). C6H80sN2S=(NH2)2C6Hb(S08H). [NHi=l,2; HSO,
-3.]
kAXlO^ at 25""- 5; increases on diln. A(43.7)-14.8, (1398) =
81.3, (a>)=352; 1372.
Phenylene furazane. (o-Benzoquinone dioxime anhydride).
CeH40N2.
Cond. with NaOH; 758.
Phenylene ^olet see Thionine.
Phenylethozyacetic add. CioHi20s-Ph.CH(OEt).COkH.
kAXlO^=5.3; increases, then diminishes on diln.
A(22.3)=38.4, (712.9) = 163.2, (oo)=375; 574.
l-Phenyl-3-ethozy-urazole. C10HUQ2N8.
kAXlO® at 25^=3; m. p. 152^
A(1024)-2.1, (2048)=3.5, (oo)=357.8; 18.
In HBr, qua!.; 16. In alcoholic HCl; 18; qual.; 16.
Na.A at 25^ A(32)-59.i, (1024)-69.7; 18.
Phe] TABLES 261
l-Phenyl-S-efhyltfaio-urazole. CioHuONsS.
kAXlO^ at 25**«5; m. p. 137M38^
A(2048) = ll, (4096) -19.3, (oo)=355; 18.
Phenylglucosazone. C18HS2O4N4.
In NHs, qual.; 606.
Phenylglutaric acid. CuHuO*- Ph.CH (CH2CQ2H)j.
kxXlO* at 25^=7.7; m. p. ISS**; 1246, 1813.
A(45.6)=21.5, (364.8) = 57, (oo)=373; 1813.
Phenyl glycme see Phenylaxnino-acetic acid.
Phenylgiydne-o-carbozylic acid. (Anilinoacetic acid carboxylic acid).
C9H904N=CQ2H.C6H4.NH(CH2.COsH).
kAXlO^ at 25''»2.3; diminishes on diln.
A(240.8)=77.3, («)=374; 1246.
Phenylgiydne-o-carbozylic add eso mono methyl ester. (o-Carboxy-
methyl-^mlinoacetic acid).
CioHii04N=:CQiMe.C6H4.NH(CH2.CQ2H).
kAXlO* at 25**= 1.4; diminishes on diln.; m. p. 182^
A(963.9)« 112.4, («>)=373; 1246.
Phenylglydne-o-carbozylic acid exo mono methyl ester. (o-Car-
boxyanilipoacetic acid methyl ester).
CioHu04N=CQ2H.C6H4.NH(CH2.C02Me).
kAXlO* at 25**=2.8; diminishes on diln.; m. p. 160^
A(297.3)=32.5, (00) =373; 1246.
iiriac^-Phenylglycollic acid. (Amygdalinic acid. Mandelic acid).
C8H808=Ph.CH(OH).CQ2H.
kAXlO* at 0**=4.30. At 12^=4.29; 1968a. At 25** -=4.17; 1371,
1184;=4.29; 1968a;=4.3; m. p. 118M19**; 1824;=3.7 (neu-
tral.); 463. . At 35*" -=4.24; 1968a. Relative value; 1866.
Cond. at 0**-35*; 1968a; 1496. At 25^ A(32)=38.5, (1024)=
167.5, (oo)=353; 1371. A(32)=38.6, («>)=349; 1968a.
Cond. with boric acid; 1184. With MoOs; 1496. With KOH
and acetic acid; 463.
Na.A at 26% A(32)=64.6, (1024)=.75.0; 1368a; A(32)=67.7,
(1024) =78.0; 1276. At 0*'-35%- 1968a.
PhenylglycolHc acid methyl ester. C»HioOi=Ph.CH(OH).COiMe.
In HCl, good cond. ; 1897.
1-Phenylglycollic acid. CsHsOi.
kAXlO* at 25**=4.3; m. p. 130**; 1824.
Phenylglyoximecarboxylic add. (Phenylamphiglyoxime carboxylic
acid). C9H804N2=PhC(:NOH).C(:NOH)(COsH).
Exists only in soln. From cond. of the lactone in water, kA XlO*
at 25*^ is at least 2; 768. See the lactone, Phenyloximino-
82/n-oxazolone.
Cond.; 701.
252 TABLES {Pbe
Phenylglyozylcarbozylic add see Phthalonic add.
Phenylglyozylic add. (Benzoylformic acid).
C8H«0,=Ph.CO.CQ2H,
kAXlO' at 25^" 6; increases on diln.
A(29.1) -262.6, (931.2) -325.7, (a>)-354; 70.
Phenylglyozylic add on<»-ozime. (Phenylemti-ketoxime carboxylic
acid. Phenyloximinoacetic acid; on/i-derivative).
CsHtOsN - Ph. (NOH OC.CQjH.
kAXlO^ at 25^-1.5; diminishes on diln. from change to the
isomeric aynrojdme.
m(32) = 177, (1024) =291.3, (a>)-354; 768.
PhenylglyozyUc add syn-ozime. C8H70»N-PhC(:NOH).COsH.
kAXlO" at 25^-1.8; 70, 768.
m(32)-75.4, (256)-172.2, (a>)-354; 768.
2Na.A at 0^ m(32)=74.0, (256) -101.1; 635.
Phenylhydrazine. C6H8Ns-Ph.HN.NH2.
X is very small; 1844.
keXlO* at 15^-1.62 (colorim.); 1777. At 40^-1.6 (catal.); 19
and 1777.
In HBr, fair cond. In HsS, no cond.; 1807. In HON, small
cond.; 943. In benzene, no cond.; 18b2. In MeNHs,
small cond.; 637.
Cond. with allyl thiocarbimide; 1223. With picric acid in ben*
zene, no cond.; 1802. As solvent; 1844.
B.HCl; hydrolysis at 40**; 19.
o^Phenylhydrozy-diazomalonic add diethyl ester. CuHuOsNs.
Cond. in Et ale.
KAinEtalc; 418.
Phenylhydrozy-pivalic add. (Dimethyl-phenyl-ethylenelactic acid.
Dimethyl-phenyl-hydroxy-propionic acid) .
C11H14Oj-Ph.CHOH.CMe2.CQ2H.
kAXlO*^ at 25^-4.5; increases, then diminishes on diln.; m. p.
134^
A(33.1)-13.1, (1058.4) -67.9, (oo)=348; 1704.
/3-Phenyl-a-hydrozy-propioiiic add. C9H10Qs-PhCHs.CHOH.CO2H.
kAXlO*-1.9.
A(109) = 51, (436)-92.4, (oo)-376; 574.
/3-Phenyl-/3-hydrozy-propiomc add.
C9HioO*-PhCH(OH).CH2.C02H.
kAX 10^-4.
A(109)-23.9. (872)-65.4, (a>) = 376; 574.
l-Phenyl-5-hydrozy-l,2,3-triazole-4-carbozylic add methyl ester.
CioHaO^Nt.
Phe] TABLES 268
kAXlO'at25^<*1.6; diminishes on diln. At50^»1.5; diminishes
ondUn.; m.p.74^ At 26^ A(148.4)- 280.3 (1187)=346.3,
(a>)-371; 447.
Enolic and ketonic fonns in pyridine; 754.
Na.A at 25^ A(32)-63.3, (1024)=72.9; 447.
Phenyliminodiacetic add. C10H11O4N » PhN (CHsCO^H)!.
kAXlO" at 25*'-2.73; diminishes on diln.; m. p. 150M65^
m(210)-184, (840)-262, (oo)-362; 1840.
Phenylindone-acetic acid. (3-Phenyl-l-ketoindene-2-methylcarboxy-
lie acid). CnHuOs.
Comparative strength (colorim.); m. p. 167.5^; 1666.
Phenylindone-acetic add methyl ester. CisHuOs.
Comparative strength (colorim.); 1666.
Phenylisoxazolecarbozylic add. CioHtOsN.
kAXlO" at 25^=6.5 aq.
A(186.6) =218.5, (1492.8)-320, (oo)=354; 23.
S-Phenylisoxazolone (6) . (Phenyl-si^-oxazolone) . CaHrOsN.
kAXlO'^ at 25^" 5.5; diminishes on diln.
A(512)=54.1, (1024)-72.7, (a>)=355; 768.
PhenyUtaconic add. CiiHio04-Ph.CH:C(COjH).CH2.CQ2H.
kAXlO* [at 25^1-1.37.
m(128)-46.4, (1024) = 115.6, («)=375; 1684.
Phenylketoximepropionic add see /3-Benzoylproidonic add ozime.
Phenyllutidinedicarbozylic add. (2,6-Dimethyl-4-phenylpyridine-3,
6-dicarboxylic acid). Ci6Hw04N-(Me2)(Ph)CBN(C04H)2.
kAXlO* at 25^=1.2.
m(512)=76.9, (1024) = 101.4, (a>)=350; 1372.
Phenyllutidinedicarbozylic acid mono ethyl ester.
Ci7Hi704N-CuHiiN(C02H)(C04Et).
kAXlO^ at 25''»5.3; diminishes on dUn. m(128)»27.6, (1024)-
66, (oo)-350; 1372.
1-Phenyl-methozy-acetic acid. (1-PhenylglycoIlic acid methyl ether).
C»HioQ8=Ph.CH(OMe).C04H.
kAXlO* at 25^=7.4; m. p. 63^-64^ 674, 1239.
A(32)=53.9, (1024)=211.1, (oo)=376; 674.
Phenylmethyl- see Me^ylphenyl-
l-Phenyl-3-methylthio-urazole. C9H9ON8S.
kAXl(F at 25^=1.3; m. p. 174^-175^ A(1024)-4, (2048)-6.4,
(00) =355.
Na.A at 25^ A(64)=63.6, (1024) =72.9; 18.
l-Phenyl-2,3-naphthalenedicarbozylic add. (3,4-Diphenyl-2,4-cyclo-
butadi6ne-l,2-dicarboxylic acid. Phenenyltribenzoic acid.
Triphenyl-trimesic acid). Ci8Hi204=Ph.CioHB(COiH)2.
Na salt at 25^ m(32)-63.3, (1024) =84.3; 1213.
264 TABLES [Phe
Pheiiyl-/3-naphfhylamine tiisulphonic add. (a-Naphthylphenylamine
trisulphonic acid). CieHi309NS8=CwHioN(HS08)8.
At 25^ m(768)= 329.7, (1536) =329.7; 492.
Phenylnitroamine. (Benzene diazoic acid. Diazo benzene acid).
C6H«Q2N2=Ph.NH(NQ2).
kAXlO*^ at 1^=1.2. Atl0**=1.5. At 18**-1.7; m. p. 46.7^ 618.
At25**=2.3; 736;= 1.3; 77.
At 25^ A(128) = 19, (1024)=v51.6, (oo)=351; 736.
In Et ale. ; 613.
Phenyl-iso-nitroamine see Phenylnitrosohydroxylamine.
Phenylnitromethane. ( l^-Nitrotoluene) . C7H7Q2N = Ph. CH2. NO*.
No cond. in aq. ; 776.
iso-Phenylnitromethane. C7H7O2N - Ph. HC. (ONOH) .
Na.A at 25**, A(32)=75.8; m. p. of acid is 84**, rapidly heated;
776.
Phenylnitrosohydroxylamine. (Phenyl-iso-nitroamine) .
C6H«02N2=Ph.N(NO)OH.
kAXlO« at 0**=5; increases on diln. A(128)-5.5, (512) = 11.7,
(<»)=221.
Na.A at 0°, A(128)=66.6, (1024) =70.0; 786.
Phenyl-iso-oz- see Phenylisoz-
Phenyl-syn-ozazolone see Phenylisozazolone.
Phenyloziminoacetic acid see Phenylglyoxylic acid ozime.
Phenylozimino-syn-ozazolone. C9H6O8N2.
kxXlO* at 25**= 1.9; 768; 701. m(512)=93.7, (1024) = 122.1,
(00) =350; 768.
In Et ale. ; 701.
K.A at 0^ m(32)=46.6, (1024) =51.2; 701.
Phenylparaconic add. C11H10O4.
Cond.; m. p. 170**; 679.
tso-Phenylparaconic add. C11H10O4.
Cond.; m. p. 170^ 679.
Phenylphenanthrophenazonium hydroxide. C26H18ON2.
At 0^ A(512) = 3.4 from cond. of B.Cl+NaOH. Is a strong base,
but changes almost at once to the pseudo base, which has no
cond.
B.Cl (flavinduUnium chloride) at 25^ A(64)=86.3, (512) =92.5;
770.
PhenylpropioUc add. C9H602=Ph.C i C.CO2H.
kx XlO* at 25**= 5.9; diminishes, then increases on diln.
A(60) = 158.5, (960) =305.5, (oo)=352; 1371.
Na.Aat25^ A(32)=64.6, (1024) = 74.3; 1868a;- 1218.
Phenylpropionic add see Hydratropic acid.
Phc] TABLES 255
Phenylpropoxyacetic add. CuHmOj^ Ph.CH(0Pr).C04H.
kxX 10^=4.9; increases, then diminishes on diln.
A(27.1)=40.6, (867.5) = 170, (<»)=374; 574.
l-Phenyl pyrazole. CsHgNs.
In aq., no cond.; 977.
3-Plienylpyridinecarboxylic add. (Bz-2). (o-Pyridinebenzoic acid).
Ci2H902N=CQ2H.C«H4.C6H4N. [C02H=2.]
kxXlO* at 25^=5. A(128) = 7.7, (1024)=23.3, (oo)=350; 1372.
a-Phenylpyridine-dicarboxylic acid. (2-Phenylpyridine-Bz-2,Py-2-
dicarboxyUc acid). Ci3H904N=C02H.CeH4.CBH8N.C02H.
kxXlO* at 25*^=1.4. m(128)«40.2, (1024) = 110.3, (oo)=350;
1372.
2Na.A at 25^ m(32)=70.5, (1024)-88.6; 1369.
/S-Phenylpyridine-dicarboxylic add. (3-Phenylpyridine-Bz-2,Py-2-
dicarboxylic acid). C18H9O4N.
kAXlO*at25^-l.l. m(64)=27.2, (1024) = 100.9, (oo)=350; 1372.
l-Phenyl-6-pyTrodiazoloiie-3-carbozylic add. (Phenylcarbopyrro-
diazolic acid). CqHtOsNs.
A strong acid [no data]; m. p. 183^-184®.
Cond. increased by boric acid; 1186.
Phenylrosinduline. C28H19N8.
Very small cond.; is really a non electrolyte; 770.
Phenylsuccinic add. CioHio04=C02H.CHPh.CH2.CQaH.^
kAXlO* [at 25**]= 1.64; 1684, 1936.
m(64.2)=35.8, (1035) = 123.1, (<x>)=374; 1936.
Phenylsuccinic acid a-mono methyl ester.
CiiHi204=C02Me.CHPh.CH2.C02H.
kxXlO* [at 25**] =4.9; diminishes on diln.; m. p. 102^
m(510.9) = 54.6, (1023) = 74, (oo)=374; 1936.
Phenylsuccinic acid jS-mono methyl ester.
CiiHi204= C02H.CHPh.CH2.C02Me.
kAXlO* [at 25**]=1.1; diminishes on diln.; m. p. 92**; 1684,
1936.
m(256.6)=57.4, (1030) = 102.6, (oo)=374; 1936.
Phenylsulphone-acetic acid. C8H804S= Ph.SO2.CH2.CO2H.
kAXlO* at 25*^=4.22 (hydroL); m. p. 112.5M13** (cor.); 1467
and Lund6n, Af!initatsmessungen.
a-Phenylsulphone-propionic acid. C9Hio04S=MeCH(S02Ph).C04H.
kxXlO" at 25*^=3.14 (hydroL); 1467 and Lund^n, Affinit&tsmes-
sungen.
Phenyltetric add. CnHioOs.
kAXlO* at 25^=1.94. m(270)=72, (1080) = 128, (oo)=353.
Na.A at 25^ m(32)=65.3, (1024)=74.0; 1831.
256 TABLES [Phe
Phenyl ffaiocarbimide. (Phenyl mustard oil. Phenyl-^o-sulphocya-
nate). C^HBNS-CSNPh.
xXlO^ at 26°- 1.8; b. p. 222** @ 754 mm.; 1848; - 1228.
In NHs, qual. ; 606.
Cond. with I; 1228.
l-Phenyl-8-thio-iirazole. CgHyONsS.
kAXlO* at 25°=1.7; increases on diln.; m. p. 192*'-193''.
A(64)= 226.4, (266) -292.8, (a>)=355.
Ba.2A. - Na.A at 25^ A(32)-43.0, (1024) =65.0; 18.
Phenyl-p-tolylbenzenylamidine. (Benzenylphenylamino-p-tolylimi-
dine. l,2-Diphenyl-3-p-tolylamidine) .
C2oHi8N2=PhC(NHPh) iN.CeHiMe.
B.HC1,A(128)-84.1, (1024)-92.2; m. p. 243^-244^ 1093. [The
base has m. p. 135*'-136°.]
Phenyltiiethyl- see Triethyl-phenyl-
Phenyltrimethyl- see Trimethyl-phenyl-
/3-Phenyl-7-trbnethylacetyl-butyric acid.
C15H20O8- Me8C.CO.CHa.CHPh.CHa.CQ2H.
kAXlO* at 25^-2.6 aq.
A(641)=45.3, (1282)-60.7, (a>)=372; 1688.
1-Phenyl-urazole. C8H7O2N8.
kxX 10* at 26°- 1.1; m. p. 266°-267°. A(612)-26.4, (1024)-36.3,
(00) =356.2.
Na.A at 25°, A(32)-60.0, (1024)-81.6; 18.
Pliloretic add. CqHioO^- MeCH(C6H4.0H).COftH.
kAXlO* at 25°-2.03.. [Bougault, Compt. Rend. 131, 43, says
that this is the same acid as p-Hydrocoumaric acid, k X 10*-
1.7.]
A(64)-12.6, (1024)-46.6, (a>)-376; 1871.
Pfaloridzin. C21H24O10.
InNH,, qual.; 606.
Phlorogludiiol. (1,3,5-Trihydroxy.benzene). C6H60j=C6H8(OH)j.
kA=?. At 26°, k X108 for v (33.4)-8, for v (133.6)-18.
m(33.4)-0.6, (133.6) = 1.7, (od)=365; 70.
Cond. alone and with.NaOH; 1508, 1718.
Pliloroglucinol aldehyde. (2,4,6-Trihydroxy-benzaldehyde).
C7H604=CH0.C6H2(0H),. [CHD-1.]
kAXlO*at25°-4.3.
m(315.4)=:39, (1261.6) -72.8, (oa)-355; 643.
Plilorogludnol carbozylic add. (2,4,6-Trihydroxy-benzoic acid).
C7H«05- C04H.C6H2(OH)8. [CO4H- 1. ]
kAXlO^ at 25° -2; diminishes on diln.
m(32)-194, (1024)=329, (oo)-356; 1371.
Cond. alone and with NaOH in Et ale; 1608, 1718.
Pht] TABLES 257
Phorone. C9H14O- MqsC :CH.C0.CH :CMqs.
In SOs; 1842.
Phosphoric add mono tso-butyl ester. (im>-Butyl phosphoric acid).
C4HUO4P = 0P(0C4H») (0H)2.
At 25^ m(32)=237, (512)=:366; 854.
Phosphoric acid mono ersrthran mono ester. (Erythran phosphoric
acid). C4H»06P-OP(O.C4H704)(OH)2.
At 25^ m(32)=283, (612) =370; 354.
Phosphoric add mono erythran di ester. (Dierythran phosphoric
acid). C4H70bP-OP(04:C4H«0)(OH).
Mixed with 65% of the mono ester, at 25'', m(8)-232; 354.
Phosphoric add mono ethyl ester. (Ethyl phosphoric acid).
C2H704P= OP(OEt) (0H)2.
At 25^ m(32)-241, (512)=369; 854.
Phosphoric add diethyl ester. (Diethyl phosphoric acid).
C4Hii04P-OP(OEt),(OH).
kAXlO* at 25°-9.8 (cond.);=10 (inversion).
At 25^ m(32)=300.8, (1024)=373, (oo)«379.
Na.A at 25^ m(32)-68.4, (1024) « 80.4; 859.
Phosphoric add tetrafluoro-diethyl ester. (Tetrafluoro-diethyl phos-
phoric acid). C4H704PF4=OP(OC2H8F2)a(OH).
kxXlO at 25**»6.2 (inversion).
At 25^ m(32)=346.5, (1024)-379.2, (od)=382.
Na.A at 26^ m(32)=70.7, (1024) -83.6; 859.
Phosphoric add mono glycerol ester. (Glycerol phosphoric acid).
C3H»06P-OP(O.C3H704)(OH)2.
At 26^ m(32)-263, (512)-364; 354.
Phosphoric add mono glycol ester. (Glycol phosphoric acid).
C2H70bP-OP(O.C3H60)(OH)2.
At 26^ m(32)-265, (512) -358; 854.
Phosphoric add mono mannide ester. (Mannide phosphoric acid).
C6Hu07P=OP(O.C6H90,)(OH),.
At 25% m(32)-274, (512)-364; 854.
Phosphorus see the preceding compounds; also iso-Amyltriphenyl
phosphonium chloride, Ethozy phosphorus chloride, Ethy-
lenehezaphenyl phosphonium chloride, Ethyl-, Methyl- and
Propyl-triphenyl phosphonium chloride, Tetrahenzyl-, Tet-
raethyl- and Tetramethyl- phosphonium hydroxide, Triethyl
phosphine, Triethyl phosphine oxide, Triphenyl-benzyl phos-
phonium chloride, Triphenyl phosphine; and complex salts;
815, 1522.
o-Phthalaldehydic add. C8H6Q8-CHO.C6H4.COsH.
kAXlO* [at 25^ 1-3.6; 1912.
Phthalamic add see o-Phtiialic add mono amide.
258 TABLES [Pht
Phthalaminoacetic acid see Phthalylamino-acetic acid.
Phthalanilic acid. (Phenylphthalainic acid).
CwHiiOsN - CO2H. CeHi. CONH (Ph) .
Cond. too irregular to get au approximate value of k; [no data
given.]; 1372.
Na.A at 25^ A(32)=60.7, (1024) « 71.0; ISeSa.
o-PhthaHc acid. (Phthalic acid). C8He04=C02H.C6H4.C02H.
kAXlO" at 0°=r.34; 1968a;=1.18 aq.; [with a different value of
m(«>)]; 1018. At 8.23*^=1.28; 1968a. At- 17^=1.25 aq.
164. At 18^=1.3 (colorim.); 1663, 1781. At 25*^-1.21
1372, 1600b, 1968;= 1.26 [with a different value of m(»)]
1968a; the value in 860 is of doubtful accuracy. At 35^ »
1.22; 1968a.
Second kAXl0*=3.1 (part.)=3.9 (cond.); 370;=1.7 (inversion);
1638 ;» 2.2 (inversion); 1336.
Cond.; 164, 171. At 0*^-35^ 1968, 196«a. At 35**-65^ 388a.
At 25^ m(64)=85.9, (1024)=232.1, (oo)=354; 1372. m(64)
=85.9, (00) =349; 1968a.
In HBr, no cond.; 30. In HCl; 30. In NHs, qual.; 606. In
N2O4, no cond. ; 602. In Et ale. ; 647.
Cond. with KOH; 171.
K.A; 164. - 2K.A; 164, 171. - Na.A at 25^ m(32)=70.6, (1024)
= 100; 370.- 2Na.A at 25^ m(32)=81.5, (1024)=98; 370.
A(32)=76.7, (1024)=93.8; 270.
o-Phthalic acid mono amide. (Phthalamic acid).
CsHtOsN^ CO2H.C6H4.CONH2.
kxXlO* at 25^=1.60.
m(32)=24.2, (1024) = 116.6, (oe))=353; 1372.
o-Phthalic acid anhydride. (Phthalic anhydride). CsH^Os.
Cond. of soln. showing change to acid; 1600b.
In H2SO4; 223, 760.
o-Phthalic add mono ethyl ester. CioHio04= C02H.C6H4.C02Et.
kxXlO* at 25*^=5.5.
m(120)-79.9, (960) = 179, (<x>) = 352; 1869.
o-Phthalic acid mono methyl ester. C9H804=C02H.C6H4.C02Me.
kAXlO* at 25*^=6.56; m. p. 82.5^
m(102) = 79.9, (816) = 180.2, (a>) = 352; 1869.
m-PhthaUc acid. (wo-Phthalic acid). C8H604=C02H.C6H4.C04H.
kxXlO* at 0*^=2 aq.; 1018. At 18**=3.3 (colorim.); 1663. At
25® =2.9; aq. used for soln. was not pure; 1372.
Second kAXl0*=2.7 (part.);=2.4 (cond.); 370;=1.0 (inversion);
1336.
At 25^ m(612) = 112, (1024) = 147, (od)-354; 1372.
In HBr and HCl, no cond. ; 30.
Pic] TABLES 259
Na.A at 25^ m(256)=91.3, (1024)- 115. - 2Na.A at 25^ m(266)-
92, (1024) =98; 370.
p-PhthaUc acid. (Terephthalic acid). C8H«04=C04H.C6H4.C02H.
kAXlO* at 25**- 1.5 (calculated); 1372, 1911.
In NHs, qual. ; 606.
Phthalimide. C8H602N= C6H4(CO)2NH.
kA X 10« at 25** is about 5 (colorim). At 15°-40*'=26 to 40 (cond.) ;
the values are too high; m. p. 229.0^-229.3**; 1143. At
25**= 100; 1996.
At 25^ A(256) = 1.99; 1996.
In NHs; 610; qual.; 606.
Hg salt, e. m. f.; 963. - K.A, decomposition to phthalamic acid;
qual.; 781. In HCN, small cond.; 943.- Na.A, e. m. f.;
149.
Phthalonic acid. (a-Phenylglyoxyl-o-carboxylic acid.)
C»H«Ob= CQ2H.C6H4.CO.CQ2H.
kAXlO^=2; diminishes on diln.
M(128)=293.6, (1024)=348.3, (a>)=377; 1684.
Phthalonic acid mono methyl ester. CioH806=C02H.C6H4.CO.COftMe.
kA XlO^ is about 1.5; saponifies easily in soln.
m(256)=66.1, (1024) = 113.4, («)=375.7; 1684.
Phthaluric add. C9H804N2=CQ2H.C6H4.CO.NH(CO.NH2).
kAXlO*at25**=2.9.
m(64)=44.3, (1024) = 145, («)=350; 1372.
Na.A at 25^ m(32)=61.1, (1024)=71.3; 1368a.
o-Phthalylamino-acetic acid. (Phthalaminoacetic acid. o-Phthalyl
glycine). CioH704N=C6H4(CO)2N.CH2.CQ2H.
kAXlO>at25**=l.
m(64)=27.6, (1024) =220, (<x>)=351; 1370.
Phthalyl glycine see Phthalylamino-acetic add.
Phytolacca dioica. (Tree poke. Umbra tree). [The references to
this are not complete. ]
Cond. of stem and leaves; 1326.
o-Picoline. (2-Methyl pyridine) . CeHzN = Me. C5H4N.
xXl0^at25**=5.3; 1569.
ks X10« at 15** is about 5 (colorim.); 1777. At 25**=3.2 (hydrol.);
b. p. 128.8** (in vapor); 402;=0.46 (hydrol.); 1354;=4.5?
(cond.); 664.
At25^ A(22.6)=0.18, (361.6)=0.84, (oo)=206; 664.
In SQ2; 1842, 1855. In NHs, qual.; 606.
Cond. with Cu oleate; and as solvent; 1669.
B.HCl at 25^ A(64)=98.4, (128) = 101.9; 270.- B.Picrate at
25^ A(128)=58.4; M(128)=60.7; 402. - B.EtCl. - B.MeCl;
270.
260 TABLES [Pic
/3-Picoline. (3-Methyl pyridine). CoHtN.
keXlO^ at 25^-1.1 (hydro!.); b. p. 143.4^ (in vapor).
B.Picrate at 25^ A(128)-59.9, (512)-64.9; M(128)»63.6; 402.
7-Picoline. (4-Methyl pyridine). CJcHtN.
kaXlO* at 26''-l.l (hydrol.); somewhat too high; b. p. U3.V
(in vapor).
B.Picrate at 25^ A(128)-58.0, (512)-62.7; M(128)-62.4; 402.
Picolinic acid see Pyridine-2-carbozylic acid.
Picramic add see 2-Ainino-4,6-diiiitro-ph6noL
Picramide see Trinitro-amline.
Picric acid see Trinitro-phenol.
Picrotozin. [A mixture of compounds.]
In NHs, qual. ; 606.
Pilocarpine. CuHuO^Ns.
ks at 16^ is of the order IQ-^ (hydrol.); 1776, 1779.
Second kBXlO"=4.2 (colorim.); 1776.
fiorm.-PimeUc add. C7H]204"COftH.(CH2)6.COsH.
kAXlC^ at 25^ » 3.4. The values found, fall in three groups,
differing slightly. The origin of the acid seems to affect the
value, k-3.41; 1178, 1412, 1838, 1859;»3.48; m. p. 106'';
1217, 1219, 1838, 2018;»3.23; m. p. 103^ 197, 1638, 1810,
1838;a3.57, probably impure; [no regular decrease in k];
1371.
Second kAXlO*-4.4 (part.); 370;=2.6 (inversion); 1638.
At 25^ m(32)-11.6, (1024)=61.1, (oo)=351; 1838.
Cond. with organic acids; 1638.
2Na.A at 25^ A(32)=73.9, (1024) -88.9; 270.
Pimelic add anhydride. CrHioOs.
Cond. of soln. showing change to acid. M. p. 55^; 1810.
tso-Pimelic acid. ((ui^.-Methylethylsuccinic acid).
C7Hia04- CO4H.CH2.CMeEt.COjH.
kAXlO* at 25^-9.6; =9.0; m. p. lOSMOC**; 197, 1838; -9.8;
m. p. 104^ 62, 1838. m(32)-18.9, (1024)-96.3, (oo)-351;
1838.
7-Pimelic add. (/S-Methyladipic acid. j3-Rmelic acid).
C7Hi204*COjH.(CH2)2.CHMe.CH2.C02H.
kxXlO* at 25**=4.0>-3.97; m. p. 88.5*^-89^; 1212; -4.2; m. p.
86^-87.5^ 1838. At 25^ m(32) = 12.3, (1024) -63.9, («)-
351; 1212.
2Na.A at 26^ A(32)-76.6, (1024) -94.6; 1838.
Pinacone. CeHuO^.
In NHs, qual. ; 606.
Piperazine see Diethylene diamine.
Piperidic add see 7-Aminobutyric add.
Pod] TABLES 261
Piperidine. (Hexahy dro-pyridine) . CsHuN - CsHio. NH.
X xlO' at 25"" is less than 1.8; 1106, 1107.
kBXlO» at 0^-0.89. At 6.5^=0.95. At 10**= 1.07. Atl6°-l.ll.
At 20*^=1.15; 776. At 25**= 1.20; 776;= 1.58 aq.; about 16%
too high; 271. See also; 1283. At 30**= 1.24. At 35**= 1.25.
At40**=1.24. At45**-1.23. At 50^=1.21.; 776.
Cond.; 426, 426, 593, 776, 979. At 25^ A(32)=41.3, (256)-
93.2, ( 00) -203; 271.
In HBr,smaU cond.; 1897. In HiS; 1646; qual.; 1897. In NHj,
qual.; 606.
Cdnd. with bases; 426, 426. With salts; 1106, 1107. With
organic compounds; 693, 979, 1106, 1107. As solvent; 764.
B.HCl at 25^ A(32) -92.0,. (1024) - 103.3; 270. In NBUOH; 650.
Piperidinoacetic acid. CtHuOsN = C6Hio.N.CH2.COsH + HsO.
kAXlO" at 25**-8.2 (hydro!.),
ke XlO" at 25**=1.1 (hydrol.).
Cond. with glycocoll and acetates.
Na.A at 25^ M(64)-84.4, (266)-102.2; A(64)-70. - B.HCl at
25^ M(64) -271.6, (256) -350; A(64)-102; 1086.
Piperonal. (Heliotropine) .
C8H«0,-CHO.C6H8.Q2CHt. [CHO-1; 0-3, 4.1
In NHs, qual.; 606.
PiperylenedicarboxyUc add. CrHgOi-^ C6H«(C0ftH)s.
kAXl0*=1.16; m. p. 169**.
m(32)=20.8, (1024)-103.4, (oo)=354; 1974.
Piaddic add. CuHuOz; probably C9H80(OH)2(C02H)a.
2NaA at 25**, A(32)-68.9, (1024) = 89.0; m. p. 182**-186**; 617.
Pivalic add see Trimethyl-acetic add.
Plants. [The references to this subject are incomplete.]
See 146, 253, 587, 792, 1326.
Platini thiocyanic add. CeHsNeSePt- H2Pt(CNS)6.
2K.A at 25^ A(32)- 100.8, (1024) = 118.0; 1832.
Platino cyanic add. C4HsN4Pt=H2Pt (CN)4.
At 25^ m(32) -705.8, (1024) =760.0; 1837.
Mg.A; 1836. - 2K.A in HCN, good cond.; 943. - Na.A.- 2Na.A
at 25^ A(32)- 103.4, (1024) = 122.0; 1837.
Platino thiocyanic add. C4H2N4S4Pt= H2Pt(CNS)4.
2K.A at 25^ A(32)-96.8, (1024)-114.9; 150.
Platinum.
"Double" and complex salts; 550, 816, 886, 1522, 1762, 1948;
also see the preceding compounds, and 1466.
Pomegranate see Granatum.
Ponceau see Crystal Ponceau.
262 TABLES {Pre
Prehnitic add see 2,3,4,6-Tetramethyl-beiizoic acid.
Prehnitylic acid see 2,3,4-Trimethyl-benzoic acid.
Proline see Pyrrolidine-a-carboxylic acid.
Propargylenetetracarboxylic acid. (Trimethylene-tetracarboxylic
acid). CVH^Os-CsHaCCOjH)*.
4Na.A at 25^ m(32)=81.9, (1024) = 123.7; 1369.
Propenylsuccinic add. C7Hio04=C02H.CH2.CH(CH:CHMe)C02H.
kx X 10* at 25**= 5.96; diminishes on diln. A(32) = 16.0, (1024) -
74.6, ( 00) =376; m. p. 135**; 571a.
PropenyltricarboxyUc acid. C6H806-C02H.MeCH.CH(CQ2H)2.
kx XlO* at 25**=3.05; m. p. 146**. [A typographical error in the
original makes k«30.] m(32)=94.7, (1024)=290, («)-
353; 1839.
Propionamide see Proi^onic acid amide.
r-O-i
Propionhydrozamic add. C8H702N» Et.CH.N.OH.
kxXlO* [at 25**] =3; increases on diln.
. m(16)=0.23, (32)=:0.40, («>)=[380]; 1853a.
Propionic add. CsH^Qz » Et. CO2H.
xXlO»at25**-7; 1380.
kxXlO* at 0**-1.33. At 6.9**= 1.36; 1968a. At 10**= 1.38; 875.
At 18**- 1.4; 93, 94; (colorim.); 1668. At 20**= 1.42; 875.
At 25**- 1.35. = 1.34; 601, 1870;- 1.38; 1968, 1968a;=1.45;
461; (colorim.); 496, 1643, 1781. At 30**- 1.43; 876. At
35**= 1.36; 1968a. At 40**- 1.41; 876. At 55^=60; (action
of diastase on starch); 2002.
Cond.; 93, 94, 542, 1094, 1496. At -1** to +10**; 347. At
0**-35**; 911, 1968, 1968a. At 10**-50**; 876. At 18** and
62*^; 43. At 25^ A(32)=7.4, (1024) = 38.7, (oo)«356; 1370.
A(32)=7.4, (1024)=38.9, (oo)=354; 1968a.
In HBr, good cond. ; 80, 1897. InHCl; 30; qual.; 1897. In H2S,
no cond.; 1897. In H2SO4; 223. In NHs, qual.; 606.
Cond. with inorg. compounds; 1496, 1994. With organic com-
pounds; 93, 94, 1011, 1618a, 1821, 1994. Under pressure of
1-260 atmospheres; 642.
Cu.2A; 1618a. - Gl salt; 1711. - Li.A; 1367. - Mg.2A; 1836.
- Hg.2A; 1094. - K.A; 94, 1367. - Ag.A; 666, 1537. - Na.A;
93, 94, 1367. At 25^ A(32)=70.8, (1024)=81.0; 1368a.
At 0**-35**; 1968a. At 10**-52**; 876. At 18** and 52**; 43.
At25**-60**; 1537. In NH3, qual.; 606. With organic com-
pounds; 94, 1994. Under pressure of 1-260 atmospheres;
542. - UO2.2A; 449.
Propionic add amide. (Propionamide). C8H70N=Et.CONHs.
In NHs, qual. ; 606.
Pro] TABLES 268
Cond. with HCl; 410. With NaOH; 412. With HgCk; 1097.
Hgsalt, e. m. f.; 963.
Propionic acid amyl ester. C8Hi608»Et.COtC6Hu.
In NHs, qual. ; 606.
Effect of temperature on cond. ; 106.
Proi^onic acid efhyl ester. C6HioQ2=»Et.COtEt.
In HBr; 1646.
Effect of temperature on cond. ; 106.
Propionic acid methyl ester. CiHgO^.
In HBr, fair cond. In H2S, no cond. ; 1897. In NH^, qual. ; 606.
Effect of temperature on cond. ; 106.
Propionic acid propyl ester. C6H1SO2.
InNHa, qual.; 606.
Effect of temperature on cond. ; 106.
Propionic aldehyde. (Propionaldehyde). CsHeO^Et.CHO.
xxlO^ at 0*^=6.98. At 25°=9.5; b. p. 48**H19^ 1843, 1844.
As solvent; 1844.
Propionitrile. (Ethyl cyanide) . CsHbN = Et.CN.
X X10« at -26**=x0.06; 1863a. At +25** is less than 0.001; 1843;
»0.085; 1844, 1847;= 1.0; 1853a; 482. At 5V^l.Q. At
61^=1.8. At 70*^=2.2. At 81**=2.9; 1853a.
ks X 10" at 25**= 1.8 (catal.) ; 1864 and 1150. At 40**=28 (catal.) ;
1995 and 1150. At 60*"= 95 (inversion); 1880 and 1150.
In NHa, qual. ; 606.
Cond. as solvent; 474, 1844, 1847, 1848, 1849, 1853a.
B.HCl at 25^ m(50) =373.4. - 2B.H2SO4; 1864.
Propionylcyano- see Cyanopropionyl-
a-Propyladipic add. C9Hie04= CO2H. (CH2)8.CHPr.C04H.
kAXlO^ at 24.4**=4.2; m. p. 55**-59^
m(38.5) = 13.3, (601.2) = 52.5, (a>)=:350; 1240.
Propyl alcohol. CsHgO = Pr.OH.
xxl0» at 18*^=4.5; 478. At 25^=8; 912, 913, 1589;-74; 1569.
In HBr; 29. In NHs, qual.; 606.
Cond. with Cu oleate; 1569. As solvent; 334, 844, 471, 488,
(912), 1569, 1589, 1625, 1724.
Na.A; 344, 1724.
tso-Propyl alcohol. CsHgO^ Me2.CH.OH.
xXl0« at 25^=3.3; 1569.
In MeNH2, no cond.; 637.
Cond. with organic compounds; 45, 1569. As solvent; 334,
1569.
Propylallyl- see Allylpropyl-
fiorm.-Propyl amine. CjHQN^Pr.NHj.
keXlO^ at 25^=4.7 aq.; about 16% too high; 271.
264 TABLES [Pro
Cond.; 1368. At 25^ A(32)-23.9, (266)-69.6, (oo)«207; 271.
B.HCl at 25^ A(32)-96.2, (1024)-107.6; 270.- Complex salt
with succinimide; 1766.
tso-Propyl amine. C8H9N-Me2.CH.NH2.
kaXlO* at 25^=5.3 aq.; about 16% too high. At 26^ A(32)
=25.4, (256) -62.3, (oo)-207; 271.
B.HCl at 25^ A(32)=96.1, (1024) = 107.3; 270.
iso-Propylbenzoic add see Cuminic add.
Propyl bromide. CsHrBr.
X xlO^ at 25** is less than 2; b. p. 69**-71*' @ 740.1 mm.
Cond. with AgNOs and organic compounds; 1388.
PropylHso-btttenyltricarboxylic add. (Methylpropylcarboxyglutaric
acid). CioHi606=CQ2H.Me2C.CPr.(C08H)2.
LaXIO* at 25**»1.02; increases on diln.; m. p. 167^
m(32)- 150.2, (1024) -328, (od)=350; 1839.
ap>isa-Propyl-i3-tsa-butylhydraciylic add. (o-MO-Propyl-jS-iso-butyl-
ethylenelactic acid). C10H20OS.
[The structure of this acid is not definitely known. ]
kAXlO*-1.9; increases on diln.; m. p. 120''-121^
m(58.4)-11.3, (467) -36, (a>)-350; 1464.
Propylene diamine. C8HioN2»Me.CH(NH2).CH2.NH2.
Complex salts; 1762, 1948.
Propylene glycol. C8H8O2.
InNHs, qual.; 606.
Propylfumaiic add. (Ethyl-mesaconic acid).
C7Hio04-CQ2H.CPr:CH.C04H.
kAXlO* at 25''=9.3; increases on diln.; m. p. 173''-174°; 1823,
1831, 1838. At 25^ m(64)-76.3, (1024)=221, (a>)=355;
1838.
a-Propylglutaric add. CgHuO*' CO2H. (CH2)2.CHPr.CQ2H.
kAXlO* at 24.4^-5.8; m. p. 66^-68^
m(62.5)=20.2, (1000.6) -76.1, («)-351; 1240.
a-Cso-Propylglutaric acid. C8Hi404= CO2H. (CH2)2.CH-wo.Pr.C02H.
kAXlO* at 24.4^-5.6; m. p. 94^; 1240;-5.3; m. p. 96^• 26.
At 24.4^ m(36.5)-15.3, (1168) -79.3, (a>)«361; 1240.
j8-i«>-Propylglutaric add. C8Hi404=Mo-Pr.CH(CH2.C04H)f.
kAXlO* at 25^-6.5; m. p. 100**; 861.
iso-Propyl-hydroxy-toluene see Thymol.
Propylideneacetic add. (aj3-Pentenoic acid.)
CBH802=Me.CH2.CH:CH.C02H.
kAXlO* at 25**- 1.6; diminishes on dUn. A(32)-8.4, (1024)-
42, (00) -380; 664,671.
Na.A at 25% A(1024-32) = 10-ll; 671.
Pn>]. TABLES 265
Propyl iodide. CtH?!.
Cond. with AlCb; 1893. With aliyl thiocarbimide, no cond.;
1223.
Propylmalonic acid. C4H10O4- CHPr(COtH)s.
kAXlO" at 25^-1.12; m. p. 94^-96^; 176, 1838.
m(32)=61.4, (1024)-230.1, (oo)=356; 1838.
iso-Propylmalonic acid. C6Hio04»CH-t8<>-Pr(C02H)9.
kAXlO» at 18**-1.3 (colorim.); 1563. At 25^-1.27; m. p. 87**-
90''; 175, 1838.
Second kAXlO^»3.5 (inversion); 1638.
At 25^ m(32)-64.9, (1024)=-237, («)=366; 1838.
uo-Propylmesaconic add see iso-Butylfamaric add.
Propylxnethylcarbozyglutaiic add see Propyl-tso-butenyltricarbozylic
add.
Propyl nitrate see Nitric add propyl ester.
iso-Propylphenylethylenelactic acid see tso-Propylphenylhydroxy-
propionic add.
a-tsa-Propyl-/3-phenyl-i3-hydroxy-proidomc add. (iso-Propylphenyl-
ethylenelactic acid). C12H1eOs-Ph.CHOH.CH-Mo-Pr.CQ2H.
kAXlO^ at 25^»5.7; increases, then diminishes on diln.; m. p.
107^
m(36.7) = 16.6, (1175.7)-79.3, (a>)=349; 1704.
cf9-a-Prop^-a'-iso-propyl*8ucdnic add.
CioHi804= CO2H.CH-iso-Pr.CHPr.CQ2H.
kxXlO* at 26^=2.97; m. p. 151M52^
m(128)=62.6, (1024) = 145.4, (oo)=[350]; 235.
fran«-arPropyl-a'-tso-propyl succinic add. C10H18O4.
kxXlO* at 25**= 1.49; diminishes on diln.; m. p. 192M94^
m(266)=61.7, (1024)-112.7, («)-[350]; 236.
N-Propylquinolinium iodide di-iodide. (Quinolinium-N-propyl tri-
iodide). C12H14NI3-C9H7N.PrI.I2.
Cond. of molten salt; m. p. 60°; 1678.
Propylsucdnic add. C7H12O4- CO4H.CHPr.CH2.CO4H.
kxXlO* at 25^-8.9; diminishes on diln.; m. p. 91°-92°; lOT,
1823, 1831, 1838.
Second kAXlO«=1.2 (inversion); 1638.
At 25^ m(32)-18.2, (512) =66, (a>)-351; 1838.
iso-Propylsuccinic add. C7Hi204= CQ2H.CH-iso-Pr.CH2.CO4H.
kAXlO* at 25^=7.5; diminishes on diln.: m. p. 112M15°; 1«7,
1823, 1831, 1838; - 1349.
At 25^ m(64)-23.6, (1024) =84.5, (00)- 351; 1838.
Propyl sulphuric acid see Sulphuric acid propyl ester.
Propyltricarballylic add.
C9Hi406-CQ2H.CH2.CH(C02H).CHPr.CQ2H.
266 TABLES [Pro
kAXlO* at 25^-3.1; m. p. 136^ 67, 1839.
m(32)-33.3, (1024) = 153.2, (oo)-350; 1839.
tso-Propyltricarballylic acid.
C9Hi406=C02H.CH2.CH(C02H).CH-t8o-Pr.CQiHl
kxXlO^ at 25*^=4.3; m. p. 161**; 67, 1839.
m(32)=38.9, (1024) = 169, (oo)«350; 1839.
Propyltriphenyl phosphonium chloride. C2iH22ClP»(Pr)(Ph3)PCl.
At 26°, A(32) = 78.6, (1024) = 89.0; 270.
Protocatechuic acid see 3,4-Dihydroxy-beiizoic acid.
Protocatechilic aldehyde see 3,4-Dihydroxy-beiizaldehyde.
Protocatechuic aldehyde methylene ether see Piperonal.
Protocatechuic aldehyde methyl ether see Vanillin.
Pseudo- see under the letter beginning the next word, e. g. pseudO'
Isatin, see under I.
Pulegonic acid. CioHisOs" OH.C9HM.CO2H.
m(32) = 118.0, (1024) = 129.9; 1969. [This probably is the
measurement of a salt, since the object was to determine
the basicity of the acid. ]
Purpuric acid. CgHsOeNs.
kAXlO* at 0**=1.58. At 0^ m(512)=225, (oo)-248.8; 773.
NH4.A (Murexide)-C8H80eNe or CgPioOzNe, at 0^ A(256) =
51.2, (1024)=51.8; 773. In NH,, qual.; 606.
Purpurin. ( 1 ,2,4-Trihydroxy-anthraquinone) . CuHgOe.
Na.A at 25^ A(32)=65.4, (1024)«83.5. - 2NaA at 25^ A(32) =
76.8, (1024)=97.9.- 3Na.A at 25^ A(32)=69.2, (1024)-
80.9; 1276.
Pyrazole. C»H4N2.
In molten state, fair cond.; 977.
kBXlO" [at 25°]=«3 (catal.); m. p. 70°; 428.
Cond. equals that of a 1% NaCl soln.; 977.
Pyridine, CsHsN.
xxl0» at 0**; 786. At 18^»6; b. p. 116M18°; 478; - 1057.
At 25** is less than 2; b. p. 114^-1 17**; 1084, 1388, 1669,
764; - 347, 767a, 786, 817a, 943, 1106, 1107, 1260, 1389.
kaXlO* at 10^«1.06 (hydrol.). At 15*^=1.41 (hydroL); 1144;=
1.06 (colorim.); 1777. At 25** « 2.3 (hydrol.). The extremes
are 2.1 (hydrol.) and 3.0 (hydrol.); 270, 402, 664, 1144. At
40**-4.25 (hydrol.); 1144. At 50**=6.19 (hydrol.); 1144.
At 60*^=8.6 (hydrol.); 1144;= 8.5 (inversion); 1880 and
1144.
Cond. ; 786, 1389.
In HBr, HI and H2S, good cond. ; 1897. InHCN;943. InS02;
1842,1866. InNHs, qual.; 606. In benzene, no cond.; 936.
In MeNH2, no cond.; 637.
Pyr] TABLES 267
Cond. with inorg. compounds; 611, 620, 748, 786, 1106, 1107,
1888, 1389, 1481, 1482. With organic compounds; 984,
1084, 1106, 1107, 1223, 1388, 1669. As solvent; 321, (347),
478, 480, 488, (620), 768, 764, 767a, (817a), 934, 1067, 1084,
1106, 1260, 1388, (1389), 1669, (1818), 1991.
B.HBr in organic solvents; 1662a.- B.HCl at 25^ A(64)»
104.1, (256) -108.6; 270; 1864. At 10*^-50^ 1144. - B.HI;
763. - B.HNOt; 664. - B.H2SO4; 1864. - B.Acetate; 146a,
1144. - B.Picrate at 26% A(128)-64.1, (512) -68.2; M(128)
-70.6; 402; 768. - B.Trinitro-methane; 763. - B.EtCl.
- B.MeCl; 270.- B.Mel; 763.- B.Mel.Br^; 1678.- Com-
plex salts; 620, 660, 1384, 1417, 1481, 1482, 1672, 1760,
1761, 1766, 1767, 1760a.
PyridinebexizQic add see Phenylpyridine carbozylic add.
Pyridine-2-carbozylic add. (Picolinic acid). C6H(02N.
kAXlO* at 25''-5; diminishes on diln. A(64)-6.6, (1024)-
21.4, («)=367; 1372v
Cond. not increased by boric acid; 1186.
Pyridine-3-carbozylic add. (Nicotinic acid). CeHsOiN.
kAXlO» at 26^-1.37. A(128)-14.3, (1024)-39.3, (a>)=367;
1372.
Cond. not increased by boric acid; 1186.
Na.A at 25% A(32)-68.4, (1024) -78.8; 1369.
Pyridine-4-carbozylic add. (iso-Nicotinic acid). CeHsOiN.
kAXlO» at 25*^-1.09.
A(128)-13.1, (1024)-36, («)-357; 1372.
Pyridine-2,3-dicarboz]^c add. (Quinolinic acid).
C7H604N-C6H8N(C02H),.
kAXlO* at 25^-3; diminishes on diln.; aq. used for soln. was
impure.
m(64)-126.6, (1024)-276.2, (oo)-355; 1372.
2Na.A at 26% m(32)-77.2, (1024) -97.0; 1369, 1838.
Pyridine-2,3-dicarboz]^c add 2-mono methyl ester, (a-ester).
C8H704N-CjH8N(C04Me)(C04H). [C02Me-2; COtH-3.]
kAXlO» [at 26** 1-2.65; m. p. 123**.
M(64)-117.7, (1024)-274.1, (a>)-363; 967.
Pyridine-2,3-dicarbozylic add 3-mono metiiyl ester. (/3-ester).
C8H7O4N. [CO4H-2; C04Me-3.]
kAXlO» [at 25**]- 1.38; m. p. 106%
M(64)-91.5, (1024) -236.9, (oo)-353; 967.
Pyridine-2,4-dicarbozylic add. (o,p-Lutidinic acid). C7Ht04N.
kAXlO* at 26^-6; diminishes on diln.; aq. used for soln. was
impure.
m(128)-203.1, (1024)-304.7, (a>)-365; 1372.
268 TABLES [Pyr
Pyridiiie-2,6-dicarbozylic add. (tso-Cinchomeronic acid). C7H6O4N.
kAXlO' at 25^=4.3; diminishes on diln.; aq. used for soln. was
impure.
m(128)«182.9, (1024)=293.8, (oo)=356; 1872.
Pyridine-8,4-dicarbozylic acid. (Cinchomeronic acid). C7H504N.
kAXlO' at 25^-2.1; diminishes on diln.; aq. used for soln. was
impure.
m(128) = 141.5, (1024) -257.2, (oo)=355; 1372.
Pyridine-8,4-dicarbozylic add mono ethyl ester.
C9H«04N-CftHiN(C04H)(C02Et).
kAXlO^at 25°«5; diminishes on dihi.; impure.
m(150.1)-84.1, (1200.8) =180.9, («)=365; 176.
Pyridine-3,4-dicarbozylic add 3-mono methyl ester. (jS-ester).
C8H7O4N. [C04Me=3; CO4H-4.]
kAXlO* [at 26^-6.66; m. p. 182^
m(64)=65.4, (1024) = 195, («)-363; 967.
Pyridine-d,4-dicarbozylic add 4-mono methyl ester. (7-ester).
C8H7O4N. [CQ,H=3; C04Me=4.]
kAXlO* [at 25**]-6.7; increases on diln.; m. p. 172*'; 967;-3.3;
impure; 176.
m(64)=64.8, (1024) -195.8, (oo)=353; 967.
Pyridine-3,5-dicarbozylic add. (Dinicotinic acid. /3j3-Pyridinedicar-
boxylic acid). C7H6O4N.
kA XlO* at 25^-1.5; aq. used for soln. was impure.
/i(256)- 161.4, (1024)-245.1, (a>)-355; 1372.
Pyridinepentacarbozylic add. QoHbOioN- C5N(C02H)s.
At 25^ M(256)-610, (1024) -763; 1872.
6Na.A at 25^ m(32)-77.7, (1024) -127.8; 1369.
Pyridine-2,8,4,6-tetracarbozylic add. CgHsOgN.
At 25^ m(256)-466, (1024)-590; 1372.
4Na.A at 25^ m(32)-80.8, (1024) -121.2; 1869.
Pyridine-2,3,4-tricarbozy]ic add. CgHsOeN.
At25% m(266)-337, (1024) -438; 1878.
3Na.A at 26^ m(32)-82.1, (1024) -113.1; 1369.
Pyridine-2,8,6-tricarbozy]ic add. CgHsOeN.
At 26^ M(256)-327, (1024) =439; 1372.
3Na.A at 25^ m(32)»82.4, (1024)-111.8; 1369.
Pyridine-3,4,6-tricarbozylic add. CgHsOeN.
At 25^ m(256)-278, (1024) -371; 1372.
Pyrocamphenic add see Camphopyiic add.
I^ocatechol. (1,2-Dihydroxy-benzene. Pyrocatechin).
C6H802 = C6H4(OH)2.
kAXlO^® at 18^-3.3 (hydrol.); 524. At 25*^-4; 1897c. Also;
70.
Pyr] TABLES 269
Cond. At 25^ m(16)-0.03, (32) » 0.05, (oo)=381; 1397c. At
25^ m(32.8)=0.33, (66.6)-0.61, (oo)-356; 70. Also; 1134,
1608, 1718.
In NHs, qual. ; 606.
Cond. with boric acid; 756, 1184. With NaOH; 1017, 1608,
1718. With FeCU; 766.
2(NH4).A at 18^ A(100)=42.9, (200) -44.3; 624.
Pyrocatechol mono methyl ether see Guaiacol.
Pyroemchonic add see Dimethyl-maleic add.
Pyrocinchonic anhydride see Dimethyl-maleic add anhydride.
PyrogaUol. (1,2, 3-Trihydroxy-benzene) . CeHcOs « CeH, (0H)«.
kA=? At 25**, k XIO* increases from 5.1 to 17; 70.
Cond.; 1184, 1608, 1718. At 25^ m(56)»0.60, (448) -3. 12,
(00 ) =355; 70.
In HBr and H2S, no cond.; 1897. In NHs, qual.; 606. In
MeNH2, good cond.; 637.
Cond. with boric acid; 1184. With NaOH; 1608, 1718.
Pyrogallol aldehyde. (2,3,4-Trihydroxy-benzaIdehyde).
CtHcO*- CHO.CeH2(OH)8. [CHO« 1. ]
kAXlO* at 25^-1.14; m. p. 157^
m(256)-59.5, (1024)-102.4, («)«355; 643.
Pyrogallol carbozylic add. (2,3,4-Trihydroxy-benzoic acid).
C7H«06=C02H.CflH2(OH)8. [CQjH^l.]
kAXlO^ at IS^'-e (colorim.); 1663. At 25''»5.3; increases on
dihi.; 1186, 1371.
At 25^ m(64)=58.8, (1024) = 186.9, (oo)==356; 1371.
In Et ale; 1186, 1608, 1718.
Cond. with boric acid; 1186, 1186. With NaOH; 1608, 1718.
Pyromeconic add. C5H4O8 » C6H8O2 (OH) .
At 25^, m(32)»0.54; this cond. is due to traces of impurity; the
pure compound would have only one-tenth as much; 1872.
[This measurement gives kx XlO^-6.]
PyromelUtic add. CioHeOg^ C0H2(CQ2H)4.
At 25^M(69.9)- 240.5, (1118.4) -505.2; 176.
Pyromudc add. (Furfurane-2-carboxylic acid). CsILOs.
kAXlO* at 0^=8.7. At 12^=8.1; 1968a. At 25^=7.6; 1968a;-
7.1; 1186, 1372. At 35^=7.0; 1968a.
Cond. at 0^-35^ 1968a. At 25^ m(32)=51.2, (1024)-201.3,
(oo)-355; 1968a. m(32)=50.5, (oo)-359; 1372.
Cond. with boric acid; 1186.
Na.A at 25% m(32) «69.8, (1024) -80.6; 1368a. At 0*^-35^ 1968a.
uo-Pyromudc add. C6H4O8.
kx XlO^ is about 3; diminishes on diln.; m. p. 92^.
m(29.4)-0.32, (70.4) =0.45, («)»358; 376.
270 TABLES [Pyr
PyronecarbozyUc add. (2-Methylpyrone-6-acetic acid). CsHsOi.
kAXlO^-1.52; m. p. gO"*; 399. [In 400 this is given, kxl0*»
1.52, probably from a t3rpographical error. No measure-
ments are given.]
Pyropapayeiinic add. Ci6HuOtN-(MeO)2.C6Hs.CO.CtH8N.C02H.
At 26^ kAXlO* at v(763) = 1.3, at v(1606)=0.88; from analogy
to papaverinic add a calculation gives kxlO^ as about 1.5;
[the assumptions in this calculation are of doubtful validity].
m(753)-94.7, (1506) = 106.1, (a>)-350; 176.
Pyropapayerinic add ozime.
Ci5Hi406Nj-(MeO)2C6Hs.C(NOH).C6HsN.CQ,H.
kAXlO* at 25*'«3.7; diminishes on diln.
m(883)-58, (1766)-67.1, («)=350; 176.
Pyropapaveiinic add phenylhydrazone.
CnHi904N8=(MeO)2CeHs.C(HN,Ph).C5HsN.C04H.
kAXlO« at 25*^=3.8.
m(1130)-22.2, (2260) -29.5, (oo)-350; 176.
Pyroracemic add. (Acetyl formic acid. Pyruvic acid).
CsHiOi^ Me.CO.CO2H.
k^XlO* at 25^ is about 5.6 (inversion); 768; is about 3 (cond.);
diminishes on diln.; 1S70.
In H2SO4; 223.
Cond. not increased by boric acid; 1184.
Pyrotartaiic add. (Methylsuccinic acid).
CjHgO*- CO4H.MeCH.CH2.CO2H.
kAXlO* at 0**=7.9. At 12*^-7.9; 1968a. At 17*^-8.3 aq.; 164;
(colorim.); 1781. At 25^=8.6; m. p. Ill**; 284, 1371, 1600b,
1823, 1831, 1838;»8.7; 1968a. At 35''-8.9; 1968a.
Second kAXlO^-1.6 (inversion); 1336, 1638.
Cond. at 0**-35^• 1968a. At 17**; 171. At 25% m(32)-18.1,
(512)-66.5, (oo)-364; 1838. m(1024)-89.7, (a>)-349;
1968a.
Cond. with KOH; 171.
KA.- 2K.A; 164.- Na.A at 25% m(32)-70, (1024)-89; 1838.
- 2Na.A at 25% m(32)-78, (1024)-96; 1838; 270, 1367,
1823, 1831, 1837.
Pyrotartaiic add anhydride. CsHeOi.
Cond. of soln. showing change to acid; 1600b.
Pyrotartaric add mono methyl ester.
C6H10O4-CQ2Me.MeCH.CH2.COtH.
Three different preparations gave; kAXlO* at 25^ "3.90 for
ester, b. p. 140** @ 11 mm.; -3.85 for ester, b. p. X42*'-143*
@ 15 mm.; «3.80 for ester, b. p. 138**-140*' @ 13 mm.
Qui] TABLES 271
m(42.4)-14.1, (169.6)-27.6, (oo)-353; for the first ester, k«
3.90; 244.
a-iio-Pyrotartaiic add see Sfhylmalonic acid.
^-iso-Fyrotartaric add see Dimethyl-malonic add.
Pyrrole. C4HjN.
In HBr, HCl and HI, good cond. In HsS, no cond. ; 1807.
Pyrrole-2-carbozylic add. (Carbopyrrolic add). C6H6O2N.
kAXlO* at 25*'-4.03 aq.; m. p. 192**; 23;=3.65 aq.; 1186.
A(40)-14.2, (1280)-72.8, (a>)-359; 23.
Cond. with boric acid; 1186.
2-Pyrrolepyroraceniic add. C8H7O4N-C4H4N.CO.CHj.CO.CQtH.
kAXlO^at 25^ » 8.9 aq.; from soln. of the anhydride in aq.;
diminishes on dihi. A(200)- 121.6, (1600) -236.3, (»)-
355; 23.
2-Pyrrolepyroracemic add anhydride. (2-Pyrroylpyroracemic acid
anhydride). CsHsOjN.
For measurement see the acid.
Pyrrolidine-orcarbozylic add. (Proline). C^HgOiN.
Cond.; m. p. 206**-207^ 146b.
Pyrroylcarbozylic add see PyrrylstyozyUc add.
2-(a)-Pynylglyozylic add. (a-Pyrroylcarboxylic acid).
CeHsOiN - C4H4N.CO.CO2H.
k^XlO* at 25^-9.7 aq.; diminishes on diln. from decomposition.
A(60)-188, (960)-263.4, (oo)=358; m. p. 76^ 23.
PyntTic add see Pyroracemic add.
QisiUaja. [The references to this are not complete.]
Cond. of soln. of bark; 146.
Qttlnaldine. (2-Methyl quinoline). C10H9N.
kB X 10* at 14^-3.6 (colorim.); 1777. At 25^ is about 4 (hydro!.);
664.
B.HClat25^A(64) -90.4, (256) -95.2; 270; - 1864.- B.H2S04;
1864.
Quinaldinic add. (o-Quinoline carboxylic acid. Quinoline-2-car-
boxylic acid). C10H7O2N.
kAXlO*at25''-1.26; diminishes on diln. A(128) -13.9, (1024)-
34.8, (a>)-355; 1372.
Quinalizarin. (1,2,5,8-Tetrahydroxy-anthraquinone) . CuHgOe.
2Na.A at 25^ A(32)-95.6, (1024) - 118.4. - 3Na. A at 25%
A(32)- 120.6, (1024) -133.5.- 4Na.A at 25% A(32)- 138.6,
(1024) -152.7; 1276.
272 TABLES [Qui
Quinic add. CrHuOe- (0H)4C6H7.CQ|H.
kAXlO* at 14.r-2.77; m. p. 161^ 641. At 18**=2.6 (colorim.);
1663. At 25''»2.9 aq.; 1186 ;» 2.8 increaaing on diln.;
1648.
Cond.; 1496. At 25^ m(32)-32.7, (512) = 108, (<x>)=350; 1186.
In Et ale. ; 1186.
Cond. with boric acid; 1186, 1186. With MoOs; 1496. With
Zr02 and NaOH; 1648.
uuzcf.-Qiiinic acid. CrHuOe.
kAXlO* at 9^=2.2; 641.
Quinic acid see also Quininic add.
Quinidine. (Conquinine). CioHmOsNs.
kBXlO' at 15^=2.36 (hydroL); 1779.
Second kBXlO^<*= 3.2 (colorim.); 1776.
Cond. with o-bromocamphor sulphonic acid in aq. and in acetone;
1841.
Quinine. CS0HS4Q2N2.
kaXlO' at 15^=2.16 (colorim.); 1779. At 16** =-26 (colorim.);
98a. At 18**«17 (cond.); 1224. At 25^=120 aq. (cond.);
1241.
Second kBXlO^®=3.3 (hydroL); 1776;= 1.3 (colorim.); 98a.
At 18^ m(1671) = 10.3, (oo) = 196; 1224. At 25% m(1335.7) =
21.5, (00 )« 189.4; 1241.
In SQ2; 1842.
With allyl thiocarbimide, no cond. ; 1223.
B.HBr in SO2; 1842.- B.HCl at 25, A(32)-75.8, (1024)=89.1;
270; 1224, 304. In SQ2; 1842. - B.HF and B.HI in SOs;
1842. - B.HNOa; 304, 1611. - B.HjPQa in NHs, qual.; 606.
- B.H2SO4; 304. - 2B.H2SO4; 304; qual.; 943, 1223. - B. Ace-
tate; 304.
Quininic add. (6-Methoxy-quinoline-4-carboxylic acid. Quinic
acid. Xanthoquinic acid methyl ether). CuH^OsN.
kA X10« at 25^*9.7; diminishes on diln. A(256)«17.1, (1024) =
31.4, (<x>)«351; 1372.
Quinol see Hydroquinone.
Quinoline. C0H7N.
xXlO' at 0**«3.8; 1844. At 25**=3.7; 1106, 1107.
kBXlO* at 15**= 1.6 (colorim.); 1777. At 25^=0.8 (hydroL);
664. At 60^=7.4 (inversion); 1880.
In HBr and H2S, fair cond.; 1897. In HCN, small cond.; 943.
In SQ2; 1842, 1866. In AsCb, in POCU, and SQ2CI2; 1842.
In NHs, qual. ; 606.
Cond. with inorg. compounds; 1106, 1107, 1481. With organic
compounds; 1388. As solvent; 1844.
Bho] TABLES 273
B.HCl at 25^ A(64)»95.6, (256) -99.2; 270; 1864.- B.HsSOi;
1864. - B.MeCl; 270. - B.Mel; 1844. - B.HI.I2, - B.BuI.l2,
-B.-i«a-BuI.Ij, - B.Etl.Ii, - B.Mel.Ij, - B.MeI.l4, - B.Prl.Ii;
cond. of these iodides in molten state; 1678.
iio-Qiiinoline. C9H7N.
kaXlO* at 15*^=3.6 (colorim.); 1777. [10" in 1777 is a typo-
graphical error. ]
In NHs, qual. ; 606.
B.HCl at 25^ A(64)-95.2, (256) = 100.1. - B.MeCl; 270.
a-Quinoline carbozylic acid see Qtunaldlnic add.
7-Quinolme carbozylic add see Cinchoninic add.
Quinolinic add see Pyridine-2|8-dicarbozylic add.
Quinone see p-Benzoqulnone.
Qulnone-p-ozyphenyl-hydrazone see p-Azophenol.
R.
Racemic add see poro-Tartaric add.
RafBnose. CisHnOis.
Cond. alone and with lactose; 1747. Cond. with KCl; 146b.
In NHs, qual. ; 606.
Resorcinol. (1,3-Dihydroxy.benzene). CeH«02-C«H4(OH)2.
kA XlO* at 0** is less than 3.1; 733. At 18^-0.36 (hydro!.); 624.
At 25"" is less than 6; 733. - (solub.); 1116; (cond.); 70. At
40'' is less than 37; 738.
Cond.; 70, 738, 1184, 1608, 1718. At 26% m(34.1)=0.3, (68.2)-
2.1, (00) =366; 70. m(32)»0.14; 733.
In HBr; 29. In HCN, no cond.; 943. In NH«, qual.; 606. In
MeNH2, good cond.; 637.
Cond. with boric add; 1184. With NaOH; 1017, 1608, 1718.
With FeCU; 766.
NH4 salt at 18% A(200)»44.4, (400) » 46.2; 624.
Resorcyl aldehyde see 2,4-Dihydrozy-benzaldehyde.
Resorcylic add see 2,4-Dihydrozy-benzoic add and 2,6-Dihydrozy-
benzoic add.
Rhanmus Frangula. (Buckthorn). [The references to this are in-
complete.]
Cond. of soln. of bark; 1^.
Rhodamiae. [CtoHuOsNs? There are several Rhodamines of dif-
ferent composition. The following references do not state
which was used.]
In Et ale, cond. is increased by light; 833, 1821.
Rhodanic add see Rhodanin.
274 TABLES [Rbo
Rhodanin. (Dithio-carbamine glycollic acid anhydride. Rhodanic
acid.) CsHsONS2=CO.CHaS.CS.NH.
kAXlO* at 26**-3 (cataJ.); m. p. 168*^-169**; 8M.
Rhodanoacetic add see Thiocyanoacetic add.
Rhodizonic add. CeHsOe- CeOiCOH)!?
At 25^ m(264.8)- 130.6, (1019.1) -161.3.
Na.A at 25^ m(128) = 178.6, (1024) = 198.7; 389.
Ridnus commuiiis. (Castor oil plant). [The references to this are
incomplete.]
Cond. of sap of root and stalk; 203, 1326.
RoccelUne see Naphthalene solphonic add azo-/3-iiaphfhol.
Rosa banksia. [The references to this are incomplete.]
Cond. of sap; 203.
Rosaniline see Fuchsine.
p-Rosaniline see Triamino-triphenyl-carbinol.
Rosindone. (Rosindulone). CttHi40N2.
Is a non-electrolyte; 770.
B.Cl see under Chlorophenylnaphfhophenazonium hydroxide.
Rosinduline. CbHisNs.
Pure rosinduline is a pseudo-base with no cond. The salts are
formed from Rosindulinium hydroxide, CttHuNt.OH; which
gives at 25^ m(512)-23.4.
B.Cl-CaHiflN,Cl (Rosinduline HCl); at 25% m(256)-94.0,
(1024) -95.9; 770.
Rosindulone see Rosindone.
Rosolic add. C2oHi60t.
kAXlO« at IS'^-l.l (colorim.); 1562.
S.
d-Saccharic add. CeHioOs- (OH)4C4H4(COiH)s.
At 25^, k^XlO* is about 1, calculated from values given by a
slightly impure acid; 1249; is about 1.9; aq. used for soln.
was impure; 1362. [In 1249 the value of A(a>) is given as
330, an unusual value.]
At 25% A(32) is about 60, (1024) is about 225; (<»)-330; 1249.
In HCl, no cond.; 30.
Saccharin. (Saccharinic acid anhydride or lactone). C«HioOs.
kAXlO* at 25''-1.3; diminishes on dUn.; 1823, 1831.
Cond.; 1493. At 25% m(32)-2.3, (128)-4, (a>)-358; 1828.
Saccharin see Benzoic sulphinide.
tso-Saccharin. (tso-Saccharinic acid anhydride or lactone). CeHioOs.
Sap] TABLES 276
kAXlO* at 25''-1.8; diminkhes on diln.; 1823, 1831.
m(32)-2.7, (128)=4.5, («)=358; 1823.
Sacchazinic add. (Olycosaccharic acid). CeHuOe^ (OH)4C6H7.CQ2H.
KA at 25^ A(32)»78.9, (1024)-99.2. - Rb.A; 1493.
Saccharinic add anhydride see Sacdiarin.
Sacdiarinic add lactone see Saccharin.
tso-Sacchannic add lactone see tso-Saccharin.
d-Saccharo-lactonic add.
CeHsOr- (CHOH),.CO.O.CH(CHOH).CQtH.
kA X 10» at 25**= 1.7; m. p. 129**-130^ [The value of A(oo ) used
here is 330, an unusual value.] A(32)»67, (1024)»235.8,
(oo)»330; 1249.
Saccharose. (Cane sugar. Sucrose). CuHaQu.
kAXlO" at 10*^=0.7 (catal.). At 18^-1.14 (catal.); 1177 and
1160. At 20.7**= 1.1 (catal.); 1036. At 26**- 1.86 (catal.).
At 40^-4.3 (catal.); 1177 and 1160. (Colorim.); 1639b.
Cond.; 688, 641, 686, 1036, 1108, 1110, 1222, 1478, 1747, 1983.
In NHs, qual.; 606. In MeNHs, small cond.; 637.
Cond. with morg. acids and bases; 741, 1036, 1039, 1220, 1383.
With inorg. salts; 146b, 210a, 324, 686, 1220, 1432, 1983.
With organic compounds; 46, 1468, 1669, 1639b, 1747.
Salidn. dsHisO?.
In NHs, qual.; 606.
Salicyl aldehyde see o-Hydrozy-benzaldehyde.
homo-Salicyl aldehyde see Hydrozy-toluic aldehyde. >
Salicylamide see o-Hydrozy-benzoic add amide.
r-O-,
SaUcylhydrozamic add. C7H70tN»OH.C6H4.CH.N.OH.
kAXlO« [at 25**] =6.4.
/i(32)«5, (128) = 11.2, (»)- 13801; 1363a.
Salicylic add see o-Hydrozy-benzoic add.
tso-Salicylic add see tso-o-Hydrozy-benzoic add.
Saliva. [The references to this are incomplete.]
Cond.; 267, 290a, 878, 879, 880, 881, 1447a; 263. Concentration
of H and OH ions; 687.
Sambuctts nigra. (Elder). [The references to this are incomplete.]
k » Cond. of sap; 263.
Saponin. There are a number of saponins of different formulae;
CitHmOio, CisHisOio, CigHsoOio, C82HbOi7, CsHmOis. See
also Weil, Arch. Pharm. 239, 363, (1901).
Soln. of saponin, CisHisOio, has no cond.; 2013.
In benzine; 931.
Cond. with NaOH; 617a. With allyl thiocarbimide, no cond.;
1223.
276 TABLES [Sar
Sarcosine see MethyUmino-acetic add.
Scombrine. CsoHeoOeNie.
B.2H2SO4 shows increase of cond. after digestion with trypsin;
145b.
Sebadc add. CioHi804-CQiH.(CHs)8.CQiH.
kAXlO*^ at 18^-2.5 (colorim.); 1663. At 26^«2.76; m. p. 128**;
279;»2.8 aq.; m. p. 134.5^• 1810;-2.34; 1871, 1638.
Second kAXlO«=2.6 (part.);=2.5 (cond.); 870;=2.6 (inversion);
1638.
At 25^ m(256)-28, (1024)-54.3, (oo)=360; 279.
In HBr and HCl, no cond.; SO.
Na.A; 870. - 2Na.A at 25^ A(32)=69.4, (1024) -84.4; 270;
870.
Sebadc add anhydride. CioHuOs.
Cond. of soln. showing change to acid; 1810.
Sebadc add mono ethyl ester. C]2H2204"C02H.(CH2)8.C02Et.
kAXlO* at 25*^=1.4; m. p. 38^
/i(483)=28.1, (966) = 38.8, (<x>)=350; 1869.
Selenium see Diethyl selenium thetlne, and the following compounds.
Selenium diglycolUc add. C4H604Se" Se(CH2.C02H)2.
kxXlO* [at 25^1=4.2.
m(32)-39.2, (1024)-183.6, («>)-358; 1134.
Selenium dilactylic add. C6Hio04Se-=Se(CsH4.C02H)2.
(a) kxXlO* at 25**=4.16; m. p. 145^ m(42.4)-43.5, (1356.2)-
187.6, (00) -356.
(b) kxXlO* at 25^-3.8; increases on diln.; m. p. 109^
m(44.2)-42.4, (1413)-187, (a>).356; 403.
Semicarbazide. CHbONj-NHs.CO.NH.NHj.
kBXlO*® at 15^-91 (colorim.); 1776. At 40.2^-0.26 (catal.);
1996.
Senna. [The references to this are incomplete.]
Cond. of soln. of leaves; 146.
Serum see Blood.
Serum globulin. [The references to this are incomplete.]
Serum globulin is probably a mixture of at least two compounds.
The following references are to the globulin of the blood of
the horse and ox.
As acid, at 20°, it is about the strength of phosphoric acid,
(catal.); 783a.
Cond. of suspension in aq. at 18°; 783a.
Cond. with inorg. acids; 783a, 1603. With inorg. bases; 617a,
783a, 1603. With organic acids; 783a. Concentration of H
ions; 1611b.
Sta] TABLES 277
Shikimic acid. C7H10O6.
IcaXIO^ at 14.1**«7.1; m. p. 184**. [The same measurement is
given in both references.] m(41)=15.9, (1305) =78.4, (00)-
303; 641, 838.
Silicic acid tetra ethyl ester. C8H2o04Si-Si(OEt)4.
X XlO^ at 25** is less than 3; b. p. 165.5'' @ 740 mm.
Cond. with trichloro-acetic acid; as solvent; 1223.
Silicic acid tetramethyl ester. C4Hi204Si»Si(OMe)4.
xXlO« at 25^-1.6; b. p. 120*'-122^
Cond. with FeCU and with trichloro-acetic acid; as solvent;
1223.
Silicon. See the preceding and succeeding compounds.
Silicon tetraphenyl. Cx4H2oSi»Ph4Si.
In SQ2; 1842.
Silver. See the succeeding compound, and 971.
Silver cyanic acid. (Argenti- or argento- cyanic acid).
C2HN2Ag-HAg(CN),.
See 510.
K.A at 25^ A(32)» 103.2, (1024) -115.5; 1832; 971; - 1484a.
In organic solvents.; 1434a.
Skatolecarbozylic add see 3-Methyl-indole-3-carbozy]ic acid.
Solanum ladniatum. [The references to this are incomplete.]
Cond. of fruit; 1326.
Soluble Blue see Helvetia Blue.
Sorbic add. CeHgOi* MeCH :CH.CH :CH.C02H.
kAXlO«at26**-1.73.
A(128) = 16.2, (1024) =44.3, («)=355; 1371.
In HCl, small cond.; 30.
Sparteine. CuHaeNs.
kBXlO* at 15** is over 1 (hydrol.); 1779.
Spirit Blue.
Trisulphonic acid. [This is called Triphenyl-p-rosaniline tri-
sulphonic acid (^CjtEUiOioNsSs) in the following reference.
The dye is usually said to be the hydrochloride, sulphate or
acetate of a mixture of triphenyl-p-rosaniline and triphenyl-
rosaniline.]
At 90^ m(200) = 1239, (1600) = 1486; 976a.
Spleen. [The references to this are incomplete.]
Cond.; 166a, 623, 624; 258.
Stanni- see under Hn.
Stanno- see under Tin.
Starch. (QHioOs)..
When pure is insol. in aq. The last wash liquor has x Xl0*=4;
1209a. 1% soln., x XlO» at 18**= 1.8; 1160. 2% soln.
278 TABLES [Ste
XX 10* at 25^»1.5; 590. Increase of cond. during trans-
formation from colloidal to granular form; 695. Form when
in soln.; 260a.
Cond. with acids; 783a; qual.; 594. With bases; 593, 783a.
With KI and I; 1160, 1381.
Stearic add. CisHseOk- CitHss-CQiH.
Dielectric constant; 1206.
K.A at 25^ A(64)-68.8, (1024) -110.2; 945.
Stearic add glyceryl ester. (Tristearin).
CstHuoOb™ (Ci8He(02)tCsH6.
Effect of temperature on cond.; 106.
Stilbene disolphonic add disazophenol mono ethyl ether see Chry-
sophenine.
Storaz dxmamic add see Cinnamic add.
Stovaine see Methylethyl-dimethylamino-methyl carbinol benzoate.
Strychnine. CnHnQsNs.
kBXlO^ at 16*^=1.43 (hydro!.); 1779, 1776. At 18**»8.6; 1224.
At 25^-600 aq. [apparently erroneous]; 1241.
Second kaX 10^^=5.95 (hydroL); 1776.
Cond. at 18% m(4382) = 11.6, (oo) = l95; 1224; - 943. At 26%
m(4906)-83, ( 00) -190; 1241.
In HBr and HsS, no cond.; 1897. In HCN; 943.
B.HClat25% A(32)-79.0, (1024)-91.9; 270; - 1224. -B.HNOi;
1611. - B.Hglj; 1223. - B.(CH4Br)Cl. - B.EtCl; 270.
Styphnic add see Trinitro-resordnol.
Suberane carbozylic add see Cydoheptane-carbozylic add.
Sttberene carbozylic add see 1-Cydoheptene-l-carbozylic add.
Suberic acid. CsHuOi- CO2H.(CH2)6.C02H.
kAXlO*^ at 18^=2.8 (colorim.); 1563. At 25*^-2.96; m. p. 138^
279; 1638, 1810;-2.58; 198, 1371;-3.11; 176.
Second kAXlO^-2.1 (inversion); 1336; -2. 5 (inversion); 1638;-
1.9 (cond.);-3.7 (part.); 370; - 1911.
At 25% m(128)-21, (1024)=56.2, (a>)«351; 279.
Na.A; 370. - 2Na.A at. 25% A(32)-72.3, (1024) -87.3; 270; 370.
Suberic add anhydride. CgHuOt.
Cond. of soln. showing change to acid; 1810.
Suberic add mono ethyl ester. CioHi804«C02H.(CHs)6.C02Et.
kA XlO* at 25**- 1.46; m. p. 18^
m(74.5) = 11.6, (1192)-43.3, («)=351; 1859.
Succinamide see Succinic add amide.
Sucdnanilic add. (Anilinosuccinic acid).
C10H11O3N-CQ2H.C2H4.CO.NHPh.
kAXlO** at 25** -2.07; increases on diln.
m(64)»12.2, (1024) -47.3, (a>)-350; 1372.
Sue] TABLES 279
Sttcdncyaiianiic acid see Succinic acid mono cyanoamide.
Sucdncyanoamide see Succinic acid di-cyanoamide.
Sucdn-dialdehyde. C4H602» CHO.CH2.CH2.CHO.
XX 10^ [at 20^?] « 1.0; diminishes on standing from polymeriza-
tion; b. p. leQ'^-lTO^ 784.
Succinic add. C4H6O4-CO2H.CH2.CH2.CO2H.
kAXlO* at 0*^=5.62; 1968a;=5.11 aq.; 1018. At 5.7**=6.15;
1968a. At 17''»6.35 aq.; 164. At IS'^^e.O (colorim.); 1663;
1781. At 21.6**-6.0; 1416. At 26*^-6.8; m. p. ISO**; 279,
190. The other values vary from 6.3 to 6.9 aq.; - 1184,
1371, 1600b, 1687, 1810, 1968, 1971; -6.65; 1968a; (com-
parative); 1643. At 35'*»6.69; 1968a.
Second kAXl0«=2.2 (part.);=2.7 (cond.); 370;«2.3 (inversion);
1335, 1638;»4 (part.); 1231.
Cond.; 171, 542, 691, 782, 1023, 1122, 1495, 1500b, 1508, 1718;
qual.; 865. At 0**; 910. At 0^-36**; 1968, 1968a. At 5**-
18^; 1741. At 18** and 52^• 43. At 35**-65**; 388a, At
25^ M(32)-16.3, (1024) « 83, (oo)-356; 279.
In HSSO4; 223. In N2O4, no cond.; 602. In Et ale.; 754, 782.
In pyridine, fair cond.; 934.
Cond. with boric acid; 1184. With MoOt; 691, 1023, 1495. With
K0H;171. With NaOH; 1508, 1636, 1718. With Na2W04;
1023. With acetic acid; 1821. With tso-caproic acid; 145b.
Under pressure of 1-260 atmospheres; 542.
2(NH4).A; 145a, 823. - Co.A; 1735. - Mg.A; 1735, 1836. - Ni.A;
1735. - K.A; 164. - 2K.A; 164, 171, 494. - Na.A at 25%
A(32)=76, (1024) «94; 370; - 43, 1643.- 2Na.A, at 0^
635. At 25% A(32)-81.7, (1024)»98.0; 270, 370; 1508,
1636, 1718. tfnder pressure of 1-260 atmospheres; 542.
Succinic add di-amide. (Succinamide).
C4H8O2N2-CONH1.C2H4.CONH,.
Hgsalt, e. m. f.; 963.
Succinic add mono cyanoamide. (Succincyanamic acid).
C6H«OiN2=CQ2H.C2H4.CO.NH(CN).
IcaXIO* at 25**=3.0. m(61.9)-45.6, (990.4) - 146.4, (a>)=352;
70.
Succinic add di-cyanodiamide. (Succincyanoamide).
CeH8Q,N4-CO.NH(CN).C2H4.CO.NH(CN).
kAXlO» at 25**= 6.7; diminishes on diln. m(157.5)=34.3, (1260)-
62.4, (00) -350; 70.
Succinic add anhydride. C4H40t.
Cond. of soln. showing change to acid; m. p. 120°; 1500b, 1810,
1838.
280 TABLES [Sue
Succinic acid mono eftkjl ester. C6Hio04"CQiH.C2Hi.CQ2Et.
kAXlO*at25**-3.02.
m(36.4)-11.6, (582)-43.5, (oo)«352; 1859.
Succinic add diethyl ester. C8Hi404«C2H4(COkEt)s.
In NH«, qual.; 606.
Effect of temperature on cond. ; 106.
Succinic acid mono methyl ester. C5H804"C(^H.C2H4.CQtMe.
kAXlO* at 25*^-3.2; m. p. 58**; 244, 1869.
m(38.8)-12.4, (620.8)=46.9, (oo)'=354; 1869.
ifo-Sucdnic add. (Ethylidenesuccinic acid. Methylmalonic acid)
C4H«04= Me.CH(C02H)2.
kA XlO* at 25**-8.6; diminishes on diln.; m. p. 128^ 1838, 1371.
Second kAX 10^- 7.6 (inversion); 1638.
At 25^ m(32)=54.4, (512) = 168.9, (oo)-357; 1838.
tso-Sucdnic add mono ethyl ester. C6H10O4- McCHCCO^H) (C02Et).
kA XlO^ at 25''"3.9; diminishes on diln.
m(34)=38.3, (544) « 127.8, (oo)=352; 1869.
iso-Sucdnic add diethyl ester. C8H14O4.
Relative strength (inversion) ; 1764.
Succinic nitrile see Ethylene cyanide.
Sucdnimide. C4HSO2N.
kA X 10^1 at 25^ « 3.0 (catal.) ; 1996. - 1888.
Cond. at 25% m(32)-0.4; 1097, 1888; qual.; 70.
In NHs, qual. ; 606.
Cond. with inorg. salts; 149, 1097. With organic compounds;
1096.
Cu.2A; 1086. - Eg. A; 1094, 1097. In NHs; 610. E. m. f.; 149,
963.- KA with inorg. salts, e. m. f.; 149.- Ag.A; 1096.
- Na.A at 25% m(32)-74.8, (1024)-95.4; 1838.- Com-
plex salts; 1097, 1760, 1762, 1766.
Sucdnthionuric add see Thiosucdnuric add.
Succintoluidic add see Tolylsucdnamic add.
Sucdnuric add. C5H804N2-C02H.C2H4.CO.NH(CONHj).
kAXlO» at 25^=3.1.
A(64) = 15.2, (1024)«57.4, («)=352; 1372.
Na.A at 25% A(32)=63.2, (1024) =73.1; 1368a.
Sucrose see Saccharose.
Sulphamide see Sulphuric add di-amide.
o-Sulphaminebenzoic add. C7H7O4NS » CO1H.C6H4.SO1NHS.
kAXlO»at25**=2.3; m. p. 152^ 1981;-2.1; 781.
A(25)=76, (800)«251.1, (oo)=360; 1981.- 781.
p-Sulphaminebenzoic add. C7H7O4NS.
kAXlO* at 26^-2.6.
Sul] TABLES 281
A(160)-64.4, (1280) » 149.1.
Na.A at 25^ A(32)=62.6, (1024)=72.5; 781.
Sulphaminobarbituric acid see Thionuric acid.
Sulphanilic add see p-Aniline solphonic add.
Sulphimide see Trisulphimide.
o-Sulphobenzoic add amide. (o-Carbaminebenzene sulphonic acid).
C7H7O4NS-CONH1.CflH4.SOsH.
At 25% A(50)-317, (100)=326.5, (a>)-361;m.p. 193M94**
(uncor.).
Na.A at 25% A(20)-69.1, (40)=72.8; 1981.
m-Sttlphobenzoic add. C7HflO5S-CQ2H.CflH4.SO8H.
kAXlO at 25*^-4?. m(22.6) =343.9, (<x>)«377; 1909.
m-Sttlphobenzoic add a-mono methyl ester. (Sulphonic ester).
CsHflOjS- C02H.C6H4.S08Me.
kAXlO^ at 25''«6.8; extrapolated, because of saponification;
m. p. 134''-136^
A(651) = 198.6 at once, -239.7 after 225 minutes, (<»)»375; 1909.
m-Sttlphobenzoic add j3-mono methyl ester. (Carboxylic ester).
C8H8O6S-CO2Me.CflH4.SO8H.
kAXlO at 25^-2?; m. p. 56'^-62^ A(43.2) -341.8, (1397)-
373.2, (00) =375; 1909.
Sttlphocyanic add see Thiocyanic add.
iso-Sttlphocyanic add. See the thiocarbimides; e. g. allyl thiocarbi-
mide etc.
Sttlphonediacetic add. C4H80flS-SQ2(CHsCQ2H)s.
kAXlO* at 25^-1.30; 1133.
Second kAXlO*-4.8 (cond.); 1911.
At 25^ m(32)-168, (256)=328, (oo)-358; 1183.
a-Sttlphonedipropionic add. CflHioOflS-SQ2(CHMe.C02H)2.
kAXlO* at 25^-1.03; 1133.
Second kAXlO*-3.6 (cond.); 1911.
At 25^ m(32) = 155.6, (256)-304, («)=355; 1133.
/3-Sttlphonedipropiomc add. C«HioOflS-S02(CH2.CH2.C02H)s.
kAXlO* at 25^-2.4.
m(128)-58, (256)-77.3, (1024)-139.2, («)=355; 1133.
a-Sttlphonepropionicacetic add.
C8H8OflS-CQ2H.CH2.SO2.CHMe.CO2H.
kAXlO* at 25*^-1.2; 1133.
Second kAX 10^=^4.5 (cond.); 1911.
At 25^ M(32)- 163.3, (256)-321.3, («)-356; 1138.
/3-Sttlphonepropionicacetic add.
C6H80bS- CO2H.CH2.SQ2. (CH2)2.COiH.
kAXlC at 25^-5.1.
m(32)- 117.2, (256)-235.8, (oo)=356; 1188.
282 TABLES [Sul
6-Sttlpho8alicylic acid. (2-Hydroxy-5-sulphoben2oic acid).
C7H«06S-HSQ8.C«H,(OH).C04H. [CQsH-l; OH-2;
SOjH-S.]
Cond. alone and with NaOH; m. p. 120''; 1608, 1718.
Sulphuric add. H2SO4. [The references to this are incomplete.]
V (16) (64) (256) (612) (1024)
At 0^ A» 187.0 213.6 239.8 253.2 260.3
Atl5^A-237.0 270.9 304.7 335.8 343.0
At 25°, A-261.2 310.6 359.8 371.6 376.2
In reciprocal ohms. (Tower, Conductivity of Liquids.)
Sulphuric add di-amide. (Sulphamide). O^S(NH2)2. [The refer-
ences to this are incomplete.]
No cond. in aq. soln.; m. p. 91.6°; 761.
In NHs; 610.
Sulphuric add mono iso-butyl eater. (tso-Butyl sulphuric acid).
C4Hio04S-04S(OC4Hg)(OH).
At 26°, m(32)-328.4, (1024)-354.8.
Na.A at 25°, m(32)-67.2, (1024)-79.1; 1366.
Sulphuric add mono ethyl eater. (Ethyl sulphuric acid).
C2H604S-04S(OEt)(OH).
At 26°, m(32)-340.9, (10r4)-367.4; 1366.
Ag.A; nil.- Na.A at 25°, m(32)-77.2, (1024) -87.5; 1366.
In NHe, qual.; 606.
Sulphuric add diethyl ester. (Diethyl sulphate).
C4Hio04S-Q2S(OEt)2.
xXlO^ at 0°-1.64. At 25°-2.63; b. p. 110°-111° @ 25 mm.
Cond. as solvent of NEtJ; 18ii.
Sulphuric add mono methyl ester. (Methyl sulphuric acid).
CH404S-02S(OMe)(OH).
At 25°, m(32)» 345.0, (1024) -368.1; 1366. Comparative
strength (colorim.); 1643.
Na.A at 26°, m(32)-79.6, (1024)-91.4; 1366.
Sulphuric add dimethyl ester. (Dimethyl sulphate).
C2H604S-QsS(OMe)s.
xxlff at 0°-1.644; 1844. At 20°-10.0; 1848. At 25°-3.085;
1844; - 1884, 1648, 1869.
In H2SO4, qual.; 760.
Cond. as solvent; 1869, 1884, 1844.
Sulphuric add propyl eater. (Propyl sulphuric acid).
CiH804S-Q2S(OPr)(OH).
At 26°, m(32) -333.8, (1024) -359.9.
Na.A at 25°, m(32)-71.0, (1024) -83.0; 1366.
Sulphurous add. H2SOS. [The references to this are incomplete.]
Tan] TABLES 288
kAXlO*at25**-1.6; 460;- 1.74 (cond.);-1.64 (hydro!.); 960.
m(20.1)- 169.5, (40.0) -207.6, (79.3) -244.5, (oo)- 390; 960.
Sulphurous add mono ethyl ester. (Ethyl sulphurous acid).
C2H«QBS-0S(0Et)(0H).
Na.A at 25% m(32)-79.7, (1024) -105.4; 1623.
Sulphurous add diethyl ester. (Diethyl sulphite).
C4HioO«S=OS(OEt)i.
xXlO' at 0**-2.06. At 26^-3.46; b. p. 158.5** @ 750 mm.
Cond. as solvent; ISii.
asi^.-Sulphurous add diethyl ester see Bthyl sulphonic add ethyl
ester.
Sulphurous add mono methyl ester. (Methyl sulphurous acid).
CH4Q8S-OS(OMe)(OH).
Na.A at 25°, m(32)-78.9, (1024)=115.5; 1628.
Sun spurge see Buphorbia helioscopia.
Sweat. [The references to this are incomplete.]
Cond.; 1713.
Concentration of H and OH ions; 687.
T.
Tannic add. (GaUotannic acid. Leucotannio acid. Often called
tannin). CiiH^nOae? C14H12O9? See also Digallic acid
and Tannin. The f(Mrmula and structure are in doubt.
Fischer, Freudenberg, Ber. Deutsch. Chem. Ges. 45, 915,
2709, (1912) have made a synthetic pentagalloyl-glucose
[called by them pentadigalloyl-glucoee in some places]
C4iH820te«C«H706[C«H2(OH)sCO]6 which gives the reac-
tions of purified tannin (-tannic acid). Nierenstein, Ber.
Deutsch. Chem. Ges. 43, 628, (1910) finds that the formula
is Ci4Hi2Og-(OH)8CeH2.CHOH.O.C«H2(OH)2.C02H. Pan-
iker, Stiasny, Join*. Chem. Soc^ 99, 1819, (1911) show by
partition measurements the probable presence of a carboxyl
group. The purity of the preparations used in making the
following measurements is rather doubtful under the cir-
cumstances. It is probable that tannins from various
, sources will be found to contain isomeric or homologous
I tannic acids, instead of all containing one acid.
, kAXlO* at 25°-l. m(32)-2, (128)-3, (oo)=350; 1826.
At 18**, XX 10* of 1% soln.-8.97; after boiling 12 hours- 14.97;
' Nierenstein, Manning, (Private communication). Also;
1160.
In HBr, no cond. ; 80. In NHs, qual. ; 606.
! Cond. with iodine; 1160.
284 TABLES [Tan
Taxmin. See also DigaUic acid and Tannic add.
This is a mixture.
In the literature up to within a few years, the word tannin is
used very loosely. In general it means a more or less well
purified mixture of acids, chiefly tannic and digallic acids.
At 18^ xXlO^ of a 1% soln.»l.l, after heating for some time
near 60**.
Cond. with iodine; 1160.
d-Tartaric acid. C4H«0«= CO4H.CHOH.CHOH.CO2H.
kAXlO* at 0**-5; 910. At 17**=10.1 aq.; 164. At IS^'^ll
(colorim.); 1662, 1663. At 25''=9.7; m. p. ITO**; 200, 692,
1182, 1372, 1824, 1838; - relative value; 1643, 1781, 1866.
Second kAXlff^-S.Q (inversion); 1638;«3.4 (part.); 1231;=4.5
(cond.); 1911; - (part.); 1866.
Cond. at 0^ 910. At 17%- 170. At 18^ 377, 1122, 1664. At
20**; 1463. At 25''; 372, 691, 692, 1496, 1618, 1664, 1648,
1747. m(32)-57.9, (1024)-232, (a>)=357; 1838. At 37^
309. At 0''-42^; 179.
In HBr and HCl, no cond. ; 30. In HON, small cond. ; 943. In
H2SO4; 223. In NHs, qual.; 606. In pyridine, fair cond.;
934.
Cond. with inorg. acids and bases; 170, 691, 1182, 1189, 1496,
1618. With inorg. salts; 378, 1463, 1648, 1664, 1994. With
organic compounds; 46, 377, 378, 1223, 1747. Under pres-
sure of 1-500 atmospheres; 220.
Ba.A; 1736. - 2Ce.3A; 1496. - Co.A; 1734, 1736. - 2La.3A;
1496. - Pb.A; 938. - Mg.A; 1736, 1836. - Mn.A; 1736.
- Ni.A; 1734, 1736.- K.A at 25^ m(32)-95.0, (1024) =
155.6; 1838; 200, 1199. - 2K.A; 164, 170, 496, 688, 1468,
1619, 1734. - KSb.A; 160, 706, 1468. - 2Rb.A; 1492.
- Na.A at 25^ m(32)»73, (1024)- 132; 1838; 1648. Rela-
tive strength; 1643. - 2Na.A at 25**, /i(32) = 82, (1024) -101;
1838; 179, 377, 378, 449, 1199, 1367. Under pressure of
1-500 atmospheres; 220. - NaNH4.A; 179. - UO2.A; 449.
-Complex salts; 692, 938, 1619, 1621, 1648, 1734.
d-Tartaric acid diethyl ester. CsHuOa.
In NHs, qual.; 606.
Tartaric add mono methyl ester. (Methyltartaric acid).
CfiHsOe- COjH.CHOH.CHOH.COjMe.
kAXlO^ at 25^-4.6; diminishes on diln.; m. p. 69**-70^
/i(32)=39.9, (1024) = 163, (a>)=350; 1838.
1-Tartaric add. C4H606= CQ2H.CHOH.CHOH.CQ2H.
kxXlO^ at 25''=9.7; m. p. 170^ 200, 1372, 1824, 1838.
Second kAXl0*=4.2 (cond.); 1911.
Teq TABLES 285
Cond.; S09. At 25^ m(32)-57.9, (1024)-232, (oo)-357; 1838.
KA at 25% m(32)-95J2, (1024)-155.4; 1838; 200.
mocf. -Tartaric add. (meso- or an(t-Tartario acid). C4H6O6.
kAXlO* at 17°-5.82 aq.; 164. At 25*'-6.0; m. p. 140M43^
200, 1824, 1888.
Cond.; 170, 309. At 26% m(32)-46, (1024)«190.4, (oo)-367;
1838.
Cond. with KOH; 170.
E.A at 25% m(32)»89.3, (1024)-: 128.2; 1838; 200.
^a-Tartaiic add. (Racemic acid). C4H6O6.
kAXlO*atO**-9.1. At 12*»9.9; 1968a. At 17^=10.1 aq.; 164.
At 25^-9.7; m. p. 205*'-206^; 200, 1372, 1824, 1838;=
10.8; 1968a. At35''»11.2; 1968a.
Second kAX 10*= 4.0 (cond.); 1911.
Cond.; 170, 309, 692. At 0^-35^ 911, 1968a. At 0^-42% 179.
At 25% m(32)=57.9, (1024)=231.9, (a>)=357; 1838.
In HBr and HCl, no cond. ; 30.
Cond. with KOH; 170. With Na^WOs; 692.
E.A at 25% M(32)»95.2, (1024) = 155.0; 1838; 200. - 2K.A; 164.
- Na.A at 25% m(32)-73, (1024)«132; 1838.- 2Na.A at
25% m(32)=82, (1024) = 101; 1838; 179.- NaNH4.A; 179.
Complex salt; 692.
Tartronic add. (Hydroxy-malonic acid).
C$H406- CQ2H.CHOH.CO2H.
kAXlO* at 26*'=5; m. p. 158''-159^ 1629;= 1.07; 1372. [There
is no way of determining why these values are so far apart.
It is probable that this acid is stronger than malonic acid,
kxl0"=1.6.1
At 26% M(44.3) = 132, (88.6) = 167.5, (00) =358; 1629. m(32)-
60.2, (1024)=234.2, (oo)-357; 1372.
Cond. increased by boric acid; 1186.
Co.A- Mg.A at 25% m(32)=51.5, (1024) - 123.0. - Ni.A; 1735.
- 2E.A; 496.
Tawine. (Aminoisethionic acid). C2H708NS=NH3.CH2.CH2.S08H.
kAXlO» at 25**= 1.6 (hydrol.).
ks at 25^ is between that of aspartic acid and of hippuric acid.
Na.A at 25% A(64)=72.9, (1024)-80.4; M(64)=76.2, (1024)-
87.5. - B.HCl at 25% A(64)=373, (1024)=386; 1984.
Tears. [The references to this subject are incomplete.]
Concentration of H and OH ions; 587.
Tellttrium see Triethyl tellurium chloride, Trimethyl tellurium
chloride and the following compound.
Tellurium complex oxalate; 16dOa.
286 TABLES [Ter
Teraconic add. C7Hio04-CQ2H.CHt.C(:CMej)C04H.
kAXlO^ at 25°b1.40 aq.; increases, then diminishes on diln.;
m. p. 161M63^
Second kAXlO'-4.6 (inversion).
At 25^ m(49.6)-28.2, (794.2)-97.8, (oo)-352; 1638.
TereMc add. (Diaterebic add anhydride). C7H10O4.
kAXlO^ at 25''"2.65; diminishes on diln.
m(32)=31, (1024) -138.8, (oo)-352; 1872.
Terephthalic add see p-Phthalic add.
Terpylonic add. C^HuOe.
kAXlO* at 25**- 1.05; m. p. 135^
m(32)-19.9, (1024)-97, (oo)-352; 1697.
Tetraaapartic add. CieHtiOisN4.
4K.A.- 4Na.A at 28^ m(32)-65.9, (1024) -76.8. Cond. with
NaOH and NaCl; 1227.
Tetrabenzyl phosphonium hydroxide. C28HyOP.
B.Cl-(PhCHt)4P.Cl, at 25^ A(612)-88.1, (1024)=89.6; 270.
Tetrabromo-fluorescein. (Eosin. Tetrabromo-fluoresceinic acid
anhydride). C2oH805Br4.
[The 2E and 2Na salts are also called Eosin.]
Effect of light on cond.; 826, 888, 1821, 1476. Effect of Rdntgen
rays on cond.; - 1476. 2Na salt, effect of light on cond.;
1471a.
Tetrabromo fluoresceinic add anhydride see Tetrabiamo-flnoresceln.
Tetrabromo-phenolphtfaalein. C2oHio04Br4.
Cond. with NaOH; 1260, 1261.
Tetracarbozylic add see Butanetetracarbozylic add.
Tetracbloro-diketo^pentajnethyiene-hydrozy-carbozylic add.
CeHsOsCU.
[At 25^?] A(23.3) -388.4; m. p. 217**; 729; 728.
Tetracbloro-ethane. (Acetylene tetrachloride).
C2H2Cl4-CHCla.CHCla.
With perchloric acid, no cond.; b. p. 144** @ 720 mm. As sol-
vent; 840.
Tetrachloro-galiein. C20H8O7CI4; formerly given as CtoH^OrCU.
In MeNHs, poor cond.; 687.
Tetrachloro-methane. (Carbon tetrachloride). CCU.
XX 10* at 25*" is less than 2; b. p. 76.2*-75.7* @ 740.4 mm.;
1888; 886, 716, 872.
Cond. with carbon disulplude and hexane; 886. Effect of radium
on cond.; 872. With inorg. and organic compounds; 1888.
As solvent; (298), 1888.
Tetrachloro-quinone see Chloroanil.
Tet] TABLES 287
Tetraefhyl ammonittm hydroxide. CgHnON » Et4N.0H.
[At 25''] A(32)->79.6, (1024) » 182.6; aq. used for soln. was not
pure; 1363.
In Me ale; 336.
Relative strength; 409.
B.Br(=NEt4Br). In PBrj, no cond.; 1833. In acetonitrile;
1844. In Me ale; 336.- B.Cl(»NEtiCl) at 25% A(32)-
88.2, (1024) -99.5; 270. In epicUorohydrin; 1844. In Me
ale; 336.- B.I(=NEtJ) at 0% A(32)=47.7, (1024)-64.8;
1826. At 25% A(32)=86.8, (1024)« 104.0; 336; 923, 1423a,
2029. In inorg. solvents; - in bases; 1828; - in bromides,
chlorides and oxychlorides; 1833, 1834; - in esters; 1834,
1844, 1847; - in oxides, as SQ2; 1826, 1833, 1866. In
organic solvents; - in acids; 1844; - in acid chlorides, etc.;
1844; - in alcohols; 336, 923, 1423a, 1690a, 1844, 1848,
1849, 1863a, 2029; - in aldehydes; 1690a, 1844, 1847, 1849,
1863a; - in amides; 1844; - in anhydrides; 1690a, 1844;
- in bases; 1844; - in esters; 1834, 1844, 1847, 1863a; - in
hydrocarbons and nitrohydrocarbons; 923, 1423a, 1690a,
1844, 1848, 1863a; - in ketones; 336, 1423a, 1690a, 1844,
1847; - in nitriles; 1423a, 1690a, 1844, 1847, 1848, 1849,
1863a; - in oximes; 1844; - in thiocarbimides, thiocya-
nates, mercaptans, etc.; 1844, 1846, 1847, 1849, 1863a.
- Under pressure, in organic solvents; 1690a.
Tetraethyl arsonium hydroxide. CsHnOAs.
B.Cl(«Et4As.Cl) at 25% A(32)-85.6, (1024)«97.5; 270.
Tetraethyl-diamino-triphenyl carbinol see Brilliant Green.
Tetraethyl-dichloro-quinone diamalonate see Dichloroquinone-dima-
Ionic acid.
Tetraethyl phosphonium hydroxide. CgHsiOP.
B.Cl(-Et4P.Cl) at 25% A(32)=86.2, (1024)-98.3; 270.
Tetraethyl stibonium hydroxide. CgHsiOSb.
B.Cl(=Et4Sb.Cl) at 25% A(32)=83.3, (1024)=95.1; 270.
Tetraetiiyl-Bucdnic add. Ci2H2204»C02H.CEt2.CEt8.C02H.
kx XlO^ at 25*^ is about 4; m. p. 149^.
/n(889) = 171, (00) =373. These values are only approximate;
1888.
Tetraethyl-sucdnic acid mono methyl ester.
C13H24O4- C02H.CEt2.CEt2.C02Me.
Too insol. in aq. to get good values of k; 1888.
Tetrafluoro-diethyl amine. C4H7NF4= (CHF2CH2)2NH.
kBXlO^^ [at 25^1=1.51 (hydrol.); b. p. 124.4'' (cor.) @ 755 mm.
[At25*'I, m(16)=0.12.
B.HCl [at 25°], m(32) = 108.6, (1024) -182.9; 1697.
288 TABLES [Tet
Tetrafluoro-diethyl phosphoric add see Phosphoric add tetrafluoro-
diethyl ester.
Tetrafluoro-triethyl amine. C6HiiNF4= (CHF2.CH2)2NEt.
Base has b. p. 137^ @ 754 mm. No good values for cond. can be
obtained.
B.HCl [at 25*^], m(32) = 133.9, (1024) = 302.1; 1698.
A^Tetrahydro-benzoic add. C7HioOs«QH9.CQeH.
a) Liquid phase, b. p. 240**-243°; kxX 10^^=2.14; diminishes on
diln. A(32)=9.2, (1024)=40.7, (oo)=350.
b) Solid phase, m. p. 29**; kxX 10*^=2.22; diminishes on diln.
A(32)«9.4, (1024)=45, (oo)=350; 62.
A^Tetrahydro-benzoic add. C7H10Q2.
kAXl05=3.05; diminishes on diln. A(32)-ll, (1024)=50.5,
(oo)=350; b. p. 234*^-236^ 62.
Ar-a-Tetrahydro-naphthoic add. CiiHuQ2'»CioHii.CQ2H.
kAXl05at25**=4.45; m. p. 85°; 176; 71.
A(112.6)=23.9, (900.8)=63.4, (oo)=350; 176.
/3-Tetrahydro-naphthoic add. CuHuOa.
kx X10«^ at 25*^=2.5; m. p. 96*^; 70, 71.
A(205.8)=23.9, (823.2)-47, (oo)=350; 70.
trans- A ^-Tetrahydro-o-phthalic add. C8Hio04« C«H8(CQ2H)2.
kxXlO^ [at 25*^1=5.9; m. p. 120**; 72.
A^-T6trahydro-o-phthalic add. C8H10O4.
kxXlO*^ at 25°«7.59; diminishes on dihi.; m. p. 216**; 1638; 72.
Second kxX 10^=3.2 (inversion); 1688.
At 25^ m(64)=23.7, (1024)«84, (a>)=352; 1638.
A'-Tetrahydro-o-phthalic add. CgHioOi.
kxXlO^ at 25** "5.85 aq.; increases, then diminishes on diln.;
from cond. of soln. of the anhydride (m. p. 70**).
At 25^ /i(32)=47.7, (1024) = 195.9, (00)= [377]; 1.
A'-Tetrahydro-o-phthalic add anhydride. CgHgOs.
Cond. of soln. in aq., see the acid; 1.
d5-A^-Tetrahydro-o-phthaUc add. C8Hio04«C6H8(COsH)s.
kxXlO^ [at 25**]»6.2; 7.
^ons-A^Tetrahydro-o-phthalic add. C8H10O4.
kxXlO* [at 25**]= 1.18; m. p. 218**; 72;= 1.30; 7. [No measure-
ments of cond. are given in either of these articles. ]
A^Tetrah^dro-p-phthalic add. C8H10O4.
kxXlO* at 25''=5.0 aq.; m. p. above 300^
Second kAXlO*=2.8 (inversion).
At 25^ m(321)=41.9, (1284)=78.8, (oo)=352; 1638.
Tetrahydro-a-thiophenecarbozylic add. C6H80^S=C4H7S.CQ8H.
kxXlO* at 25®= 1.15; increases on diln.
A(35.4)=22.1, (566.4)=81, (a>)=359; 70.
Tet] TABLES 289
l,2,6,8-Tetrah7drozy-anthraqtii]ione see Quinalizarine.
^fm.-Tetra]nefhyl-/3-acetozy-glutaxic add.
CuHigO^i* MeCO.O.CH(CMe8.C02H)2.
kAXlO^ at 25^ » 5.3; increases, then diminishes on diln.; m. p.
158^-159°.
m(38.4) = 14.9, (613.8) -55.7, (oo)=349; 1261.
Tetramethyl ammonium hydroxide. C4H13ON » MetN.OH.
At25^ A(16)=205, (64)-211, (oo)=211; 271.
B.Br(=Me4N.Br); 2029. In HBr; 1646. In PBr*, no cond.;
1833. In SQ2; 486, 1866. In Me ale; 2029. In epichloro-
hydrin; 1844. - B.Cl(=Me4N.Cl) at 25^ A(32)=99.1,
(1024) » 111.4; 270. In HBr; 1646; qual.; 1646. In H2S;
1646. In NH4OH; 660. In SO2; 1866. In epichlorohydrin;
1844. - B.I (=Me4N.I) at 0^ A(32) = 64.8, (1024)-62.6;
1826. At 25^ A(32)- 103.4, (1024) -123.8; 822a, 2029. In
HBr; 1646. In H2S, fair cond.; 27. In Br, no cond.; 1833.
In SQ2; 486, 1826, 1866. In NHs, qual.; 606. In acetone;
836. In epichlorohydrin; 1844. In Me ale; 336, 2029.
- B. Acetate; 145a.
Tetramethyl arsonium hydroxide. C4HUO As - Me4As. OH.
At25^ A(64)-202, (256)=204, (oo)=205; 271.
B.Cl(=Me4As.Cl) at 25^ A(32)=93.6, (1024) = 105.6; 270.
2,3,4,6-Tetramethyl-henzoic acid. (Prehnitene-carboxylic acid. Preh-
nitic acid. l,2,3,4-Tetramethyl-5-benzoic acid).
CuH14O2-Me4.CflH.CQ2H. [CO4H-I; Me=2,3,4,5.]
kxXlO* at 25^-6.
A(2048)- 103.4, (a>)-351; 1418.
2,8,4,6-Tetramethyl-benzoic acid. (iso-Durenecarboxylic acid.
1 ,2,3, 5-Tetramethyl-4-benzoic acid) .
C11H14Q2. [C02H-1; Me=2,3,4,6.]
kxXlO^ at 25^-1.
A(2048)- 131.5, (oo)»351; 1418.
2,3,6,6-Tetramethyl-benzoic add. (Durenecarboxylic acid. 1,2,4,5-
Tetramethyl-3-benzoic acid).
CUH14Q2. [CQ2H-I; Me- 2,3,5,6.1
kAXlO* at 25^=3.
A(1024) = 146.9, («>)-351; 1418.
Tetramethyl-diamino-benzophenone. C17H20ON2- CO(Ce^.NMe2)2.
In HBr and HI, poor cond. In H2S, no cond.; 1897.
oaa'a'-Tetramethyl-dihydro-muconic acid.
CioHi«04- CQ2H.CMe2.CH:CH.CMe2.CQ2H.
kAXlO* at 25^ for acid, m. p. 68^-1.8. m(46)-9.9, (184) =
19.5, (00) =350.
290 TABLES [Tet
IcaXIO* at 25^ for acid, m. p. 61^-1.83. m(40)-9.3, (160)-
18.5, (00 ) -350; 229.
Tetramefhylene-carbozylic add. (Cyclobutane-carboxylic acid. Tri-
methylene-acetic acid). CtHgO^.
kAXlO* at 25^-1.82; b. p. 192M97^ 1414, 1869, 2026.
At 25% m(29)-8.1, (928)-43.3, (oo)-356; 1859.
Tetramethylene diamine. C4HuN2»NH2.(CH2)4.NH2.
kBXlO* at 25^=5.4 aq.; about 16% too high; 271.
Cond.; 1364. At 25% A(32)-24.6, (256)-59, (od)«200; 271.
B.2HC1 at 25% A(32) = 108.8, (1024) -129.9; 270.
Tetramethylene-l,l-dicarbozylic acid. C6H6O4.
kAXlO^ at 25''-8.33; 1414, 1869;-8.0; diminishes on diln.;
m. p. 158% 1638, 1666.
Second kxXlO^-S.O (inversion); 1638.
At25%M(33)=53.8, (1056)=215.2, (oo)-353; 1869.
ds-Tetramethylene-l,2-dicarbozylic add. (Ethylenesuccinic acid).
C6H8O4- CQ2H.C4H6.COjH.
kxXlO* [at25'']=6.6; m. p. 138*^; 1410.
^ans-Tetramethylene-l,2-dicarbozylic add. C6H8O4.
kAXlO* [at25^]-2.8; m. p. 131**; 1410.
Tetrametiiyl-ethylenelactic add. C7Hi408»Me2.COH.CMe2.COjH.
kxXlO* at 25^-4.34; m. p. 152*-153^
m(32.6)-13, (1042.6)-67, (oo)-350; 1704.
jym.«Tetramethyl-/3-hydrozy-g^utaric add.
C9HwO6-CQ2H.CMe2.CHOH.CMe2.CQ2H.
kAXlO* at 25^-1.35; m. p. 162M63^
m(49.6)-27.6, (1588.2) = 127.4, (oo)-350; 1261.
Acetyl derivative see Tetramethyl-acetozy-glutaric add.
sifm.-Tetramethyl-/3-hydrozy«glutaric acid lactone. C9Ht404.
a) Acid, m. p. 120^-124% kxXlO* at 25''-1.5. m(31.7)-67.1,
(542.3) -203.2, (a>)-351.
b) Acid, m. p. 140M41% kx XlO» at 25**-1.3. m(118.3)- 111.3,
(898.9) -229.4, (a>)=351; 1262.
Tetramethyl phosphonium hydroxide. C4Hi80P» Me4P.0H.
At 25% A(64)=207, (a>)-207; 271.
B.Cl(-Me4P.Cl) at 25% A(32)-95.0, (1024)-107.4; 270.
Tetramethyl stibonium hydroxide. C4HuOSb-Me4Sb.OH.
At 25% A(64)-169, (256)-171, (oo) = l99; 271.
B.Cl(-Me4Sb.Cl) at 25% A(32)=87.8, (1024)-99.9; 270.
Tetrametiiyl-succinic add. C8Hi404=C02H.Me2C.CMe2.C02H.
kA XlO^ at 25^-3.11; m. p. 195*^; 280; 176, 202. At 25% m(86)*
52.6, (688) = 127.7, (oo)«348; 280.
2Na.A at 25% m(32) = 77.2, (1024) = 98.1; 176.
Tet] TABLES 291
Tetramethyl-sucdnic add mono mefhyl ester.
C9Hi604» C02H.Me2C.CMes,C02Me.
kAXlO*^ at 25**=1.22; m. p. 63^
m(47.8)-8.4, (382.5)-23, (oo)«350; 244.
Tetramethyl-tliioiiiiie hydroxide.
Ci«Hi8N8S.OH«M^N.C«H,(NS)CeH,:NMe2(OH).
Free base, (from cond. of B.Cl+NaOH) at 0^ /n(512)-98.8. At
26^ m(512)« 149.9; 770; 741.
B.Cl, Methylene Blue, (=CieHi8N,S.Cl) at 0^ 770. At 25^
m(128)- 88.97, (1024)«96.6; 882, 1266; - 770, 1402. Cond.
with other dyes; 1401.
(t-Tetrainethyl-tricarballylic add. (p- acid).
CioHwOe- (Me2C.CQ2H)2CH.CQ2H.
IcaXIO* at 25°=9.8; increases on diln.; m. p. 156^
m(32)=19.1, (1024)=97.6, (oo)»350.
Na salt at 25^ m(32)=78.3, (1024) « 101.3; 1839.
/S-Tetramethyl-tricarballylic add. (a- acid). CioHuOa.
kAXlO* at 26**-l.ll; increases on diln.; m. p. 133°.
m(64)=28.2, (1024)-101.4, (oo)=350; 1839.
aa77-Tetramethyl-tiicarballylic add.
CioHi60e=C02H.CMe2.CH(CQ2H).CMe2.CQ2H.
kA XlO* at 25°= 1.5; m. p. 140°.
m(34.4)=24.8, (276.2)«66.7; 813.
Tetramethyl-urea. C6Hi20N2=OC(NMe8)2.
Cond. with HCl; 781.
Tetranitro-methane. C08N4« C(N0s)4.
xxl0» at 25° is less than 1; b. p. 125.0°-125.5° @ 746 mm.;
1843, 1844.
In NH8; 610.
Cond. as solvent of organic compounds; 1844.
Tetrapropyl ammonium hydroxide. C12H29ON.
B.I»Pr4N.I. In acetone; 1848, 1863a. In Et ale; 1863a. In
epichlorohydrin; 1844, 1861. In propionitrile; 1848.
Tetrazole. CH2N4.
At 25°, m(32)=3.9, (1024) =37.9; 142, 146, 1720.
Tetric add. (Tetrinic acid). CsHeOs.
kAXlO* at 26°=8.2; diminishes on diln.; m. p. 188°.
>i(32)=17.9, (256) =47.9, (oo)«358; 1823.
Na salt at 25°, m(32)=69.9, (1024) =80.1; 1823, 1831.
Tetrinic add see Tetric add.
TctroUc add. C4H4Q2« MeC : C.CO2H.
kA XlO* at 25°= 2.5; diminishes on diln.
A(32)-88.6, (1024) =275.8, (<x>)=361; 1371.
Na.Aat25°, A(32)=72.4, (1024)=82.4; 1368a.
292 TABLES [Tha
Thallittm.
See the following compound.
Thallium diefhyl hydroxide. C4H11OTI.
B.Cl(=Et2Tl.Cl) at 25^ m(20)=84, (1280) = 131.3; 1613.
Theine. C8H10O4N4. [A typographical error for CsHioQ2N» Caf-
feine?.]
In SO2; 1842.
Thenoyl- see Thienyl-
Theobromine see 3,7-Dimethyl-2,6-diozy-puiine.
Theophylline see l,3-Dimethyl-2y6-diozy-puiine.
Thiazole. QHaNS.
kBXlO" at 25*^=3.3 (catal); 1864 and 1160;«2.1 (catal.);
177.
Cond. with KCl and HCl; 177.
B.HCI at 25^ A(50) = 189.8; 1864; 177.- B.H«S04; 1864.
Thiazolemethyl- see Methylthiazole-
o-ThicnylglyoxyUc acid. C6H4O8S-C4H8S.CO.CO4H.
kA XlO' at 25^»8; increases on diln.
A(32)=274.1, (1024)=354, (<x>)=357; 768.
Thienyl-syn-ketozime-carbozylic acid. (Thienylglyoxylic acid oxime).
C6H608NS-C4H8S.C(NOH).CQ2H.
kx XlO^ at 25^»5; diminishes on diln.
A(64) = 153.5, (1024)=300, (oo)=352; 768.
Thienylpyroracemic acid. C8H8O4S- C4H8S.CO.CH2CO.CQ2H.
kxXlO^ at 25^=4.6 aq.; m. p. 180^
m(280.5)= 234.9, (1122)-304.9, (a>)=.355; 23.
Thioacetic acid. C2H4OS ^ Me. COSH.
xxl0« at 0^=2.9. At 26^-2.69; b. p. 97^-99^ 1843, 1844.
kxXlO^ at 25^»4.7; increases, then diminishes on diln.
A(32)=42.1, (1024)= 176.8, (od)=365; 1370.
In SQ8; 1842.
Cond. as solvent of NEtJ; 1844.
Na.A at 25^ A(32) = 78.6, (1024) -90.3; 270.
Thiobenzoic acid amide. CtHtNS^ Ph.CS.NH9.
In NH,; 610.
Cond. with NaOH; 781.
Thiocarbamic add ethyl ester. (Xanthogen amide).
C8H70NS= NH2.CS.OEt.
In Et ale. at 25^ /i(1024)=0.52.
CuCl salt; 1630.
Thiocarbamine glycoUic acid. CsHsOsNS » NHs.CS.CHOH.COsH.
kxXlO^ at 25**= 1.13 (cond.) ;= 1.1 (catal.).
m(32)=67.1, (1024)^197.8, (oo)«382; 864.
Thi] TABLES 298
Thiocarbanilide. (ab-Diphenyl-thio urea). CisHuNtS.
In NHs, qual.; 606.
^-TliiocarbonglycoUic add mono ethyl ester.
C6H804S=CQ2H.CHSH.CQ2Et.
kAXlO^ at 26^=4.9.
m(31.6)=44.4, (505.6) = 148.4, (oo)=378; 854.
Thiocarbonyl-di-thioglycoUic add see Trithio-carbondiglycollic add.
Thiocyanic add. (Sulphocyanic acid). CHNS=NC.SH.
At 25^ A(32)=358, (1024) =367, in Hg.U.; aq. used for soln.
was not pure; 1362; 1162.
NH4.A; 681, 1276, 1746, 1747. In SQ2; 1826, 1865. In NHs,
qual.; 606. In Et ale; 491, 1470. In ketones; 474, 482,
487, 1056, 1070, 1106, 1107. In nitriles; 474, 482. In
P3rridine| 1057. With inorg. salts; 793, 1276. With organic
compounds; 1747. - Cr.3A; 1641. - Co.2A; 1526. - CuA;
990, 1004.- Pb.2A; 216.- Hg.2A, qual.; 1392. In NH3,
qual.; 606.- K.A at 0^ A(32)=66.4, (128) -69.4; 1826.
At 25^ A(32)-118.7, (1024)-131.6; 911; - 468, 681, 793,
820, 922, 1007. In HON; 943. In SQ2; 1826. In NHs,
qual.; 606. In alcohols; 491, 922, 1470. In ketones; 487,
922, 1056, 1070. In nitriles; 1844. In pyridine; 478, 1057.
With inorg. salts; 793. With gelatin; 468. - Ag.A; 216, 217.
- Na.A, in alcohols; 471, 491, 1470. In esters; 478. In
ketones; 487, 1056, 1070. In nitriles; 1844. In pyridine;
478, 1057.- Tl.A; 216, 1337.- Complex and "Double"
salts; 1162, 1163, 1164, 1192, 1526, 1527, 1573, 1641, 1752,
1944, 1947, 1948.
Thiocyanic acid amyl ester. (Amyl thiocyanate).
CeHuNS-NC.SCfiHii.
XXIO* at 25''=1.47; b. p. 193.5M95^ @ 739.5 mm.
As solvent; 939.
Thiocyanic acid ethyl ester. (Ethyl thiocyanate) . CjHbNS = NC.SEt.
xxl0<^ at 0''»1.45; 1844. At 25''»1.23; 1844;»2.62; 1843;
- 939, 1223.
In NHs, qual. ; 606.
Cond. with I; 1223. As solvent; 939, 1223, 1844.
Thiocyanic add methyl ester. (Methyl thiocyanate).
CaHaNS-NC.SMe.
xxl0« at -50^-0.3. At -40^=0.5. At -15^=0.9; 1853a.
At O^'^l.S; 1853a;»3.1; 1844; 1847. At 25''»1.8; 1853a;»
1.46; 1843;»4.1; 1844; - 939, 1223, 1846, 1847. At 40''»
6.6. At 50°«7.0; 1844. At 130**«20.6; 1846.
Cond. as solvent; 939, 1844, 1646, 1847, 1849, 1853a.
294 TABLES [Thi
Tliiocyanoacetic acid. (Rhodanoacetic acid.)
CHaO4NS-CH2.SCN.CQ2H.
kAXlO* at 25^»2.67; diminishes on diln. from decomposition in
soln.
A(32)=91.4, (1024)-277.8, (co)-362; 1370.
Thiodiglycomc acid. C4H«OiS-S(CH2C04H),.
kAXlO^ at 25^-4.8; 1133, 1370.
Second kxX 10*^- 3.3 (cond.); 1911.
At 25^ m(32)-42, (1024)=183, (od)-:358; 1133. m(1024)-190,
(00) =358; 1370.
2NaA at 25^ A(32)-81.2, (1024) -99.0; 270.
Thiodihydracrylic acid see /3-Thiodilactylic acid.
Tbiodilactylglycollic acid see Thio-a-lactylhydracrylic acid.
a-ThiodilactyUc acid. C«Hio04S-S(CH.Me.CQ2H)2.
a-modification, kAXlO* at 25''=4.9; m. p. 125°.
m(32)=42.6, (1024)- 181, (oo)-356.
fi-modification, kAXlO* at 25**-4.4; m. p. 109^
/i(32)-40, (1024)- 181, (<x>)«356; 1133.
/3-Tbiodilactylic add. (Thiodihydracrylic acid).
CflHio04S-S(CH2.CH2.CQ2H)2.
kAXlO'^ at 25*^-7.8.
m(32)«17.4, (1024)-83.5, (oo)-366; 1133.
ThioformaniUde. CrHiNS-CHS-NHPh.
Cond. in NaOH; 538.
Tbiogiycolhydracrylic add. (/9-Thiolactylglycollic add).
CbH804S=CQ2H.CH,.S(CH2)2.COjH.
kAXlO^ at 25''-2.6; diminishes on diln.
M(32)-31.1, (1024) - 136.2, (oo)=357; 1133.
Thioglycomc add. C2H4O2S-CH2.SH.CO2H.
kAXlO*at25''-2.91aq.; 972;-2.25; 1370.
A(60)-43.7, (1000)- 158.8, (<x>)=384; 972. A(32)=29.4, (1024)
-132.7, (00) =360; 1370.
Thiohydantoin. (2-Imino-4-keto-tetrahydro-thiazole) . C9H4ON2S.
kB XlO" at 25''- 9.6 (catal.); 1864 and 1160,
B.HCl at 25^ A(50)-233.2; 1864.
a-ThiolactylgtycoUic add. C6H804S-Me.CH(CQ2H).S.CHs.C04H.
kAXl0*at25**-4.8.
/i(32)=41.7, (1024) -179, (00) =357; 1133.
/3-ThiolactylglycoUic add see Thioglycolhydracrylic add.
Thio-a-lactylhydracrylic add. (ajS-ThiodilactylglycoUic acid.)
C6Hio04S-Me.CH(CQ2H).S(CH2)2.CQ2H.
kAXlO* at 26*^-2.2.
m(32)-28.3, (1024) = 135, (oo)=356; 1133.
Thy] TABLES 296
TfaiomaUc add. C4H6O4S » CQsH.CHCSH) .CHs.CQiH.
kAXlO* at 26^-5.2; m. p. 150°.
m(32)»46, (1024) -201; 1629.
Thiomefhyl- see Mefhylthio-
Thionine. (Lauth's Violet. Phenylene Violet). CuHgNtS.
Free base, A(256)»-17.7y after 5 minutes standing.
B.HCl at 25°, A(128)-75.7, (1024) -80.9; 741.
Tbionuric add. (Sulphaminobarbituric acid). C4H6O6NSS.
NH4.A, in NHs, qual.; 606.
ThioiMrabaxiic add. C9H3O2N2S.
Dissolved in cold aq., m(64)»2.4, (1024)-5.7; 1748.
Thiophene. C4H4S.
In HCl and HBr, good cond. In HI and H3S, no cond.; 1897.
a-Thiophenecarbozylic add. [jS-acid in 1372.] C6H4Q2S.
kxXlO^ at 25°=3.16; m. p. 126.2°; 1811; 70, 1372.
A(25)-32.4, (800) = 149.3, (oo)«382.7; 1811. A(64)=46.9,
(1024) -150.2, (00) -359; 1372.
/3-Thiophenecarbozylic add. C6H4O2S.
kxXlO* at 25°-7.8; m. p. 138.4°; 1134, 1811.
A(50)-23.2, (800) =84.7, (»)= 382.7; 1811.
Tfaiosucdniuic add. (Succinthionuric acid).
CsHsaNaS- CQ2H.CH4.CO.NH(CSNH«).
kAXlO* at 25°= 3.37; increases on dibi.
A(64) = 15.8, (1024)=59.5, (oo)=353; 1372.
Thiourea. CH4N2S=SC(NH2)2.
ksXlO^^ at 25°= 1.1 (catal.); 1864 and 1160. At 60° -95 (in-
version) ; 1880 and 1160.
At 25°, m(32)=0.06, (256) -0.20; 1748. - 1008,
In HON, small cond. ; 943.
Cond. with inorg. salts; 149, 748, 1008, 1624, 1626.
Cu.2A; 1008.- B.HCl at 25°, m(50)-371.0. - B.H2SO4; 1864.
- B.Oxalate; 1748. - Complex salts; 1008, 1624, 1626, 1630.
Thorn-apple see Datura.
Thymol. (4-i«o-Propyl-3-hydroxy-toluene).
CioHmO- (Me) (i8o-Pr)CflHa.OH. [Me- 1. 1
In HBr; 29, 30, 147a. In HCl; 147a. In H2S, no cond.; 147a.
In NHs, qual. ; 606. In MeNH2, fair cond. ; 637.
Cond. with NaOH and HCl; 1608.
p-Thymotic aldehyde. CiiHi402-Me.C«H2(i8o-Pr)(CHO)(OH).
[Me-1; CHO-2; C,H7-4; OH-5.]
kxXlO* at 25°-l; m. p. 133°. A(4096)- 164.4, (oo)-351; 643.
Thyroid gland. [The references to this are incomplete.]
Cond.; 166a.
296 TABLES [Tig
TigUc add. CsHgOa - Me.CH :CMe.CQ2H.
kAXlO«at25**-9.57.
A(32)=6.1, (1024)-33.3, (od)^355; 1371.
Na.A at 25% A(32) = 66.4, (1024) -75.8; ISeSa.
Tin.
See the following compounds.
Tin diethyl diiodide. C4Hiol2Sn«EtsSnl3.
At 25% m(128)=281.0, (1024)-393.1.
In Me ale. ; 2029.
Tin methyl tribromide. CHsBi^Sn « MeSnBi^.
At 25% m(20)=756; m. p. 63°; 1613.
Tin triethyl hydroxide. CaHieOSn.
B.I (»C«Hi6lSn»Et3SnI), in Me ale.; 2029.
Tin trimethyl hydroxide. CsHioOSn » MesSn.OH.
kBXlO^ at 25° is about 1.7. >i(34.6)=0.49, (276.8) -1.4, («>) is
about 200; 271.
p-Tolubenzyl sulphonic acid. (p-Xylene- or p-Xylyl sulphonic acid).
C8H10O8S-Me.C6H4.CH2.SOjH. [CHjSOjH-l; Me =4.]
kxXlO at 25° is about 1. A(32)-334, (1024)=348.8, (a>)=350.
Na.A at 25% A(32)=60.2, (1024) -72.2; 423.
Toluene. CrHs^^Me.CeHs.
X X10» at 25° is less than 2; b. p. 108°-110° @ 744.5 mm.; 1388;
- 806, 384, 386, 1010, 1604, 1606.
In HBr, HI and H8S, no cond. ; 147a, 1897. In HCl, no cond. ;
147a. In NHj, qual. ; 606. In MeNH2, no cond. ; 637.
Cond. with salts and organic compounds; 383, 384, 386, 842,
1314, 1388, 1669. As solvent; (1314), 1669.
o-Toluene Bttlphinic add. C7H8OsS-Me.C6H4.SO2H.
kxXlO' at 25°-2.2; diminishes on diln.
A(32)- 196.4, (1024)=303, (oo)=353; 54.
p-Toluene sulphinic acid. CtHsOsS.
kAXlO« at 18°-3.1; 64. At 25°-2.3; 54, 1134. At 30°-1.9; 64.
At 25% A(32) = 199.1, (1024)=323, (a>)=353; 54. A(33)-207.2,
(528) -320.8, (00) =355; 1134.
o-Toluenesulphone-aminoacetic acid. (o-Toluenesulphoneglycocollic
acid). C9H11O4NS-Me.C6H4.SQ2.NH.CHa.CO2H.
kAXlO* [at 25°] -2.82.
A(67.4)=44.4, (1077.6) -146.6, (od)-349; 1134.
p-Toluenesttlphone-aminoacetic acid. (p-Toluenesulphoneglycocollic
acid). C9H11O4NS.
kAXlO* [at 25°] -3.47.
A(81.7)=53.9, (653.6) -132.6, (od)-349; 1134.
p-Toluene sulphonic acid. CrHsOsS - Me.C6H4.SO8H.
kAXlO at 25°-2?; 423, 1940.
Tol] TABLES 297
A(64.4)-366, (oo)«380; 1940. A(32)-336.6, (64)=344.6, (»)-
350; 423.
In H2SO4; 167.
K.A.- Ag.A; 1940.- Na.A at 26^ A(32)-61.4, (1024)-72.7;
423; 1940.
a-Toluic acid see Phenylacetic add.
o-Toluic acid. CsHsO^" Me.C6H4.CO^H.
kAXlO^ at O^'^LSg; 196aa;»1.45 aq.; 616. At 12''»1.49; 1968a.
At 18**- 1.3 (colorim.); 1663. At 20**- 1.29 aq.; 616. At
25''- 1.25; 616, 1371, 1418;- 1.37; 1968a, 1681. At SO''^
1.20 aq.; 616. At 35''- 1.25; 1968a;- 1.17 aq.; 616. At
40''-l.ll aq.; 616, 1681. At 45*^-1.06 aq.; 616. At 50*^-
1.01 aq.; 616, 1681. At 60** =0.96 aq. At 70^=0.86 aq. At
80*'-0.77 aq. At 90*^-0.67 aq. At 99*^-0.59 aq.; 1681.
Cond. at 0*^-35^ 1968a. At 0*'-50^• 616. At 25*^-99 **; 1681. At
25^ A(128)-41.3, (1024)- 103.4, (oo)-356; 1371. A(1024)
-106.7, (00) -349; 1968a.
In HBr; 30. In HCl, good cond.; 30. In NHs, qual.; 606. In
N2O4, no cond. ; 602.
Na.A at 25^ A(32)=66.5, (1024) -76.5; lS68a. At 0*^-35^
1968a. At 0*'-50*»; 616. At 25*^-99^ 1681.
m-Tolnic add. CgHgOs- Me.C6H4.CQ2H.
kx Xl0*at0**-5.15. At 12*^-5.48; 1968a. At 18*»=5.9 (colorim.)
1663. At 25''-5.2; 1371, 1418;-5.60; 1968a; -5.8 aq.;
1681. At 35**- 5.54; 1968a. At 40*^-5.8 aq. At 50^=5.5
aq. At 60*^-5.3 aq. At 70*^-5.0 aq. At 80*^-4.7 aq. At
90*^-4.4 aq. At 99*^-4.0 aq.; 1681.
Cond. at 0*'-35%- 1968a. At 25*'-99°; 1681. At 25% A(128) =
27.4, (1024) =72.5, (oo)-356; 1371. A(1024)-74.2, (00) =
349; 1968a.
In HBr and HCl; 30. In NHs, qual.; 606.
Na.A at 25% A(32)-66.6, (1024)-76.6; lS68a. At 0*^-35^;
1968a. At 25*^-99% 1681.
^euefo-m-Tolnic add. (Aar-Heptadi-inene-d-carboxylio acid).
CgHsOi- (CH : C.CH,)2CH.CQ|H.
kAXlO*-1.3; m. p. 47**; 1413.
p-Toluic add. CgHgO^- Me.C6H4.CO2H.
kAXlO* at 0*^=3.8. At 12*'-4.1; 1968a. At 18*'-5.4 (colorim.);
1663, 1781. At 25®- 4.5. The values given vary consider-
ably, ranging from 5.2; 1371, to 3.8; 1418. In all cases k
diminishes on diln. k-4.3; 1968a;-4.6; 1429, 1581. At
35*^-4.4; 1968a. At 40^-4.6 aq. At 50^-4.5 aq. At 60®-
4.3 aq. At 70®-4.1 aq. At 80®=3.9 aq. At 90®=3.6 aq.
At 99®- 3.3 aq.; 1581.
298 TABLES [Tol
Cond. at 0°-36^ 196aa. At 26**-99**; 1681. At 25**, A(256) =
38.7, (1024)-72.6, (oo)-356; 1371. A(1024)-66.1, («>) =
349; 1968a.
IiiHBr;30. In HCl, good cond.; 30. In HsS04; 157a. In NHs,
qual.; 606.
Na.A at 25^ A(32)-66.2, (1024)-76.6; 1368a. At 0^-35**;
1968a. At 25''-99^; 1581.
o-Toluidine. C7H9N - Me.QHi. NHs.
xXlO«at26**-1.7; 1569.
ksXlO^** at 12^=1.34 (colorim.); 1775. At 18^-3.0 (hydrol.);
436, 435. At 25**-3.6 (hydrol.); 435;-3.2 (hydrol.); 271;-
0.7 (part.); 648. 'At OO^'-IO.O (inversion); 1880 and
1150.
In benzene, alone and with picric acid, no cond.; 1802. In
NHs, qual.; 606.
Cond. with HCl; 1553. With acetic acid; 1011. With organic
compounds; 1223, 1569. As solvent; 1569.
B.HCl at 25^ A(64)«93.9, (256) -97.4; 270; A(32)-89.7;
M(32)-98.5; 271.-435, 1601, 1864. - B.HsS04; 1864.
- Organic salts, in benzene, no cond.; 1801, 1802.
m-Toluidine. C7H9N.
kBXlO^® at 13**-3.6. At 14**=3.9 (colorim.); 1777. At 25^-
6.5 (part.); 584;-6 (hydrol.); 271;=2.9 (part.); 548.
In benzene, alone and with picric acid, no cond.; 1802.
B.HCl at 25^ A(64)-92.8, (256)-97.3; 270; A(32)-89.0;
M(32)-95.7; 271; 1864.- B.H2SO4; 1864.
p-Toluidine. C7H9N.
ksXlO* at 15*'-0.45 (colorim.); 1777. At 18**-1.6 (hydrol.);
436; 435. At 25''-2.1 (solub.); 1116;-2.2 (hydrol.); 436,
435;-1.6 (hydrol.); 271; (part.) 584;=1.1 (part.); 548. At
60''-3.6 (inversion); 1880 and 1150.
In HBr, HI and HsS, no cond.; 1897. In HCN, no cond.; 943.
In NHs, qual.; 606. In benzene, alone and with picric acid,
no cond.; 1802.
B.HCl at 25^ A(64)-93.0, (256) -97.4; 270; A(32)-89.2;
M(32)-93.6; 271; - 435, 1601, 1864, 1882. - B.HSSO4;
1864. - Organic salts, in benzene, no cond.; 1801, 1802.
2-Toli]idine-3,5-di8ulphomc acid.
C7H906NS2-Me.C6H2(NH,)(SOiH)2. [Me-1; NH,-2;
S08H-3,5.]
At25^ m(64)-332.0, (1024)-363.4, (oo)=355; 492.
3-Toli]idine-2,4-di8ulphonic acid.
CrHaOeNSj. [Me=l; NH2-3; S0|H-2,4.1
At25^ m(32)=44.2, (1024)-253.6, («)-356; 492.
Toll TABLES 299
2-Toli]idi]ie-4-8tilphoiiic add.
C7H908NS-Me.CeHs(NH,)(SQ«H). [Me-1; NHi-2;
. SQ«H«4.]
kAXlO* at 25^-2.4; 1S72;=2.6; 402.
A(32)=30.4, (612) = 106.1, (oo)=356; 492. A(1024)- 137.6,
(oo)-366; 1372.
a-Tolnidine-S-sulphonic add. C7H9O8NS.
[Me-1; NH2=-2; SOsH-d. SOsH-S in 492 and 1372.]
kAXlO* at 25°=7.5; 492, 1372.
A(32)-61, (512) = 162.6, (a>)=365; 492.
3-Toluidine-2-8tilphoiiic add.
CrHaOaNS. [Me-1; NH2-3; S0,H-2.I
kAXlO^ at 25'' -3.57; diminishes on diln.; 492, 1372.
A(128)-68.2, (1024)-158.7, (oo)-356; 492.
4-Toliiidlne-2-8ulphoiiic add.
CrHaOaNS. [Me-1; NH2-4; S08H-2.]
kAXlO*at25*'-4.08.
A(32)-12.6, (512)-47.7, (oo)-355; 492.
4-Toliiidine-3-sulphonic add. ^
CrHaOaNS. [Me-1; NHj-4; S0|H-3.1
kAXlO*at25**-8.6.
A(32) = 53.9, (1024) -210.9, («)=355; 492.
4-Toliiidine-?-8ulphoiiic add.
CrHaOaNS. [Me-1; NH2-4; SOaH-?.]
kAXlO^ at 25^-7.95; diminishes on diln.; 1372. [Given in
1372, as of doubtful structure. Note that k approaches in
value k of 4-Toluidine-3-8ulphonic acid. ]
A(64)-71.4, (1024)=203.9, (oo)=354; 1372.
Toluidino-acetic add see Tolylamino-acetic add.
a-o-Tolnidinobutyric add. C11HiBQ2N-Me.C6H4.NH.CHEt.CQ2H.
kAXlO^ at 25^-5.3; increases on diln.; m. p. 84^
A(200)-33.5, (800) -66.1, (a>)-349; 1840.
a-o-Toluidino-iso-butyric add. CiiHi6Q2N-C7H7NH.CMe2.CO^H.
kA X10« at 25*^-4.9; m. p. 62**.
A(200)-10.6, (800)-21.2, (oo)=349; 1840.
^-o-Toluidino-iso-butyric add. CiiHiB02N-C7H7NH.(CH»),.COiH.
kA XlO* at 25*'-4.0; increases on diln.; m. p. 112**.
A(200)-9.4, (800)-19.7, (oo)-349; 1840.
a-p-Toluidinobutyric add. CnHuC^N.
kA XlO* at 25*'- 1.04; increases on diln.; m. p. 153M56^
A(287)-18.5, (1148)-36.2, (oo)=349; 1840.
a-p-Tolnidino-iso-butyric add. CiiHisC^N.
kAXlO« at 26*'-6.8; m. p. 150^
A(200)-12.7, (800)-24.6, («)-349; 1840.
800 TABLES [Tol
/S-p-Tolnidino-iso-butyric acid. C11H16O2N.
kAXlC? at 25*'=4.1; m. p. 195M96^
A(200)-3.1, (800)=6.5, (oo)=349; 1840.
Toluidino-oxalic acid see Tolylozamic acid.
a-o-Tolnidinopropionic acid. CioHiaOzN^CrHTNH.CHMe.COiH.
kAXlO* at 25**=3.9; increaaes on diln.; m. p. 115^
A(207)=28.8, (828) =59, («)«358; 1840.
a-p-Toltiidinopropioiiic acid. CioHuQzN.
kx XlO* at 25^=6.9; m. p. 158^
A(467)-19.1, (934)=27, (oo)=350; 1840.
/3-p-Toluidinopropioiiic acid. CioHi802N=C7H7NH.CHs.CH2.C02H.
kx XlO* at 26**=2.2; m. p. 86^
A(200)-7.8, (800) = 14, (oo)=350; 1840.
Toluidinosuccinic acid see Tolylsuccinamic acid.
p-Toltmitrile. (Cyanotoluene). CgHrN* Me.CeH4.CN.
xxl0*at26**=5.4; 1669.
In NHs, qual. ; 606.
Cond. with Cu oleate; and as solvent; 1669.
p-Tolu quinoline. (6-Methyl quinoline). CioHgN^Me.C^HeN.
kBXlO» at 25*^=1 (hydro!.).
B.HN08at26^M(32)=82.5, (256)=88.5; M(32)-88.4; 1293.
Toluquinone-o-ozime see Nitroso-cresol.
o-Toluric acid. (o-Toluyl glycine).
CioHiiOiN= MeC«H4.CO.NH.CH2.COiH.
kAXlO* at 26^=1.93.
A(256)=69.8, (1024) = 124.8, (oo)=350; 601.
m-Toluric acid. CioHnOsN.
kxXlO* at 25*^=2.1.
A(253) = 72.1, (1012) = 128.5, (oo)=360; 601.
p-Toluric acid. CioHiiO»N.
kxXlO^ at 25^=2.0.
A(276.4)=73.2, (1101.6) = 130, («)=350; 601.
2,4-Toluylene diamine. CyHioNs^ Me.C6H8(NH2)2. [Me= 1. ]
ka at 15® is probably of the order 10"*.
Second kaX 10^=3.2 (colorim.); 1777.
2,6-Toluylene diamine. C7H10N2.
kB at 15** is probably of the order 10"*.
Second keX 10**= 1.46 (colorim.); 1777.
3,4-Toluylene diamine. C7H10N2.
ka at 15** is probably of the order 10"*.
Second kaX 10"= 1.16 (colorim.); 1777.
2,4-Toluylene-diamine-6-8ulphonic add.
CtHioOsNjS- Me.CeH2(NH2)2.S08H. [Me- 1 ; NHj- 2,4;
S08H=5.]
Tol] TABLES 801
kAXlO*at26**«2.2.
A(256)-74.1, (1024) = 131.2, (oo)=353; 402.
^ .^Toluylene-diaiiiine-4-sulphoiiic acid. (Diamino-p-fiulphotoluic
acid). CrHioOjNaS. [Me=l; NH2«2,6; S0iH-4.]
IcaXIO* at 25®=4.7; increases on diln.
A(60.4) = 17.7, (966.6)=67.3, (oo)«353; 1372.
Tduyl glycine see Toluric acid.
o-Tolylamino-acetic acid. (o-Toluidino-acetic acid. o-Tolyl gly-
cine). C»HiiQ2N= MeCeH4.NH.CH2.CQ2H.
kAXlO* at 25**= 5.9; increases on diln.; m. p. 148**-149**; 196,
1840.
A(200)=34.7, (800)«68.7, (oo)=353; 1840.
p-Tolylamino-acetic acid. (p-Tolyl glycine). C^HuQiN.
kAXlO* at 25**= 1.7; increases on diln.; m. p. 112M14**; 196,
1840.
A(200) = 17.7, (800) =39.2, (oo)=353; 1840.
Tolylene see Toluylene.
Tolyl glycine see Tolylamino-acetic acid.
l-p-Tolyl-6-hydrozy-l,2,3-triazole-4-carbozyHc acid ethyl ester.
C12H13O3N8.
Enol ester, kA XlO^ at 25**= 1; m. p. 98**-99** heated slowly.
A(173.5) =265.7, (694) =326, (oo)=370.
Na.A at 25°, A(32)=61.5, (1024) =71.7; 448.
o-Tolylimino-diacetic acid. CiiHu04N= Me.C6H4.N(CH2CO^H)2.
kxXlO* at 25**= 2.1; diminishes on diln.; m. p. 158M62^
m(206) = 167, (824) - 243, ( « ) = 351 ; 1840.
p-Tolylimino-diacetic acid. CuHia04N.
kAXlO* at 25**= 1.5 (extrapolated); diminishes on diln.; dec.
100^
m(300) = 173.3, (600) =206, (oo)»351; 1840.
p-Tolylozamic acid. (p-Oxaltoluidic acid. Toluidino-oxalic acid).
C»H908N=C02H.CO.NH(C6H4.Me).
kAXlO»at25**=9.
A(128)=223.5, (1024)-314.8, («>) = 350; 1371.
o-Tolylsuccinamic acid. (o-Succintoluidic acid. o-Toluidinosuccinic
acid). CiiHi308N=COiH.C2H4.CO.NH(C7H7).
kAXlO*at25**=2.1.
A(64) = 12.3, (1024)=47.3, (oo)=350; 1372.
p-Tolylsttccinamic acid. CuHuOsN.
kAXlO* at 25^=1.93.
A(256)=23.7, (1024) =45.9, (oo)=350; 1372.
Na.A at 25^ A(32)=59.8, (1024) =69.9; 1367,
Tolyl sulphonic add see Benzyl sulphonic acid.
802 TABLES [Ton
Tongue. [The references to this are incomplete.]
Cond.; 623, 263.
Triacetin see Acetic acid glyceryl ester.
p-Triaxnino-triphenyl-acetonitrile see Hydrocyan-p-rosaniline.
p-Triamino-triphenyl carbinol. (p-Rosaniline leucohydrate).
Ci»Hi»ON«- (C6H4NH2)3.C.OH.
The salt-forming base changes to a pseudo-base; at 0^, A(512)«
85.6 after 1 minute, = 1.7 after 222 minutes. At 25**, A(512)
is about 135 after 1 minute, is about 0.1 after 180 minutes;
770.
In MeNH2, small cond.; 637. In ale; 76.
B.Cl at 25^ A(128)=84.2, (1024) =93.3; 1266; 741, 770, 1266.
- B.3HC1; 734, 1266. - B.I. - 2B.SO4; 1731. - B.CN; 770,
1266.
Tri-p-aminotriphenyl-methane. (p-Leucaniline).
CwHwNs- (C«H4NHa)8.CH.
B.3HC1 at 25^ m(128) =343.9, (1024) -465.3; 1266, 770.
Tri-iso-amyl amine. CisHssN = N(CsHii)s.
B.HI in SQz; 1866.
Tri-o-anisyl carbinol. C22H22O4.
Comparative strength (colorim.); m. p. 181^; 74.
o,o,p-Triani8yl carbinol. C22H2s04.
Comparative strength (colorim.); m. p. 109^-110**; 74.
Tri-m-anisyl carbinol. C2SH22O4.
Comparative strength (colorim.); m. p. 119.5**; 74.
Tri-p-anisyl carbinol. C22H22O4.
Comparative strength (colorim.); m. p. 83.5**-84®; 74.
B.Perchlorate=CaH2i08.C104; m. p. 195**; in ethylene chloride
conducts. Cond. in tetrachloro-ethane; 840.
Triazo-acetic acid. C2Hs02N8=N8.CHs.C02H.
kxXlO^ at 25**= 9.9 aq.; diminishes on diln.; m. p. about 16**.
A(28.7) = 59.5, (287) = 151.6, (oo)-390.
Na.A, A(«>)=91; 1422.
1,2,4-Triazole. (1,3,4-Triazole). C2H6N8.
ksXlO^^ [at25**]=2 (sapon.); m. p. 121**; 428.
The 1,2,4- and 1,3,4-Triazoles are identical, the position of the
N apparently fluctuating f^om 2- to 3-.
a-Triazo-iMropionic add. C8H602N3= MeCH(N8).C0^H.
kxXlO^ at 25**= 8.8 aq.; diminishes on diln.
A(32.6) = 59.9, (326) = 155.5, («>) = 386.
Na.A, A(oo)==87; 1422.
Tribenzyl amine. C21H21N = (PhCH2)8. N.
Too insol. in aq. to measure. From hydrolysis, ks is hardly
greater than 4 XlO"*; 664.
TH] TABLES 808
Tiibromo-acetic add. CaHO^Bn^ CBr8.C02H.
At 26.2% A(32)=321.4, (oo)=357.9; 16W.
In inorgj solvents; 1833. In organic solvents; 291, 1827, 1834.
Cond. with dimethyl-pyrone; 1436, 1827.
Na.A at 25% A(32)=69.4, (1024)=80.1; 1694.
4,6,6-Tribromo-amline-2-8tilphonic acid. (Tribromo-aminobenzene
sulphonic acid).
C6H408NBr8S=BriC6H(NH2).S08H. [NH,-1; Br-4,5,6;
S08H=2.]
At 26% A(194.5)=343, (oo)=»354; 1372.
2,4,6-Tribromo-a]ii]me-3-8ulphonic acid.
C6H403NBr3S. [NHj^l; Br=2,4,6; S08H=3.]
At 25% A(lll):==340, («>)=354; 1372.
2,6,6-Tribromo-amline-3-8uiphomc acid.
CflH408NBr8S. [NHa^l; Br=2,5,6; S03H=3.]
At 25% A(111.5)=338, («>)=354; 1372.
Tribromo-benzene-azophenol see Hydrozy-tribromo-azobenzene.
2,4,6-Tribromo-benzene diazonium hydroxide. (Tribromo-diazo
benzene) . C«H80N2Brs = Bi^. C6H2 . N2. OH.
kB XlO* at 0** is less than 1; 601, 737.
B.NOi at 26% A(32)=is about 80; 426. - B.CN in Et ale, no
cond.; 736.
2,4,6-Tribromo-benzene sulphonic acid amide.
CeH4Q2NBr3S-Br8.C«H2.SQ2NH2.
Cond. with NaOH; 781.
2,4,6-Tribromo-benzoic acid. C7HsQ2Br8»Br8.C«H2.C02H.
kAXlO* at 25**=3.9. A (128.6) =324.5, (oo)=379; m. p. 188°-
189% 1909.
Tribromo-diazo benzene see Tribromo-benzene diazonium hydroxide.
Tribromo-methane. (Bromoform). CHBi^.
XX 108 at 25** is less than 2; b. p. 144**-146.2° @ 740.6 mm.;
1388.
In NHs, qual.; 606.
Cond. with AgNOs and organic compounds; 1388.
Tribromo-triketo-pentamethylene. CsHOsBrs.
m(30.4)= 324.6, (972.8) =349.6; 729.
Tri-iVo-butyl amine. C12H27N - (C4H»)8N.
kB XlO* at 25**= (2.7 aq.); about 16% too high.
A(489)=57.6, (978) =74.2, (a>)«190; the values are only approx-
imate; 271.
Tributyrin see Butyric acid glyceryl ester.
Tricarballylic acid. (Carballylic acid).
CeHgOe- CQ2H.CH2.CH(CQ2H).CH2.CQ2H.
804 TABLES [Tri
kAXlO* at 15.3**-2.2 aq.; 164. At 25**-2.2; m. p. 158**; 237.
1839, 1869, 67.
At 26^ m(32)-28.3, (1024)-139, (oo)=353; 1839. Also; 172,
1496.
Cond. with KOH; 172. With MoOa; 1496.
K salts; 164, 496.
Tricarballylic acid a-mono methyl ester.
C7HioO»-COiMe.CH2.CH(COiH).CHi.COiH.
kAXlO«at26*'=7.6.
m(30.5)-16.4, (61)-23, (<»)-[351]; 237.
Tricarballylic acid /3-mono methyl ester.
CrHioOe* CQ2H.CH2.CH(C02Me).CH2.COiH.
kAXlO* at 25*'=9.25, and 9.45.
m(26.6) = 16.8, (102.8)=32.9, (»)= [361], for k= 9.45; 237.
Trichloro-acetaldehyde see Chloral.
Trichloro-acetic acid. C2HO^Cl8 « CCI8CO2H.
K at 60** =0; 1967.
kAXlO at 0**=3 (hydroL);=9 (cond.); 461. At 12.5**-2; 709.
At 16**=2; 1499. At 18**=2-4 (cond.);=3 (hydrol.); 460;=
2.2 (hydrol.); 1973. At 25**=12.1 (inversion); 1370. 12.1
is a better value than 4, (calculated); 684. Relative value;
693, 1643.
Cond. at 0**; 461, 911, 2004. At 10**; 911. At 12.5**; 709. At
16**; 1499. At 18**; 460, 1317. At 25^ A(32) -323.0, (1024)
>= 356.0, (a>)« [360]; 1370. - 294, 782, 877, 911, 2004. At
35**; 911. At 60**; 1967.
In HBr, HCl, HI and HjS, no cond.; 1897. In HBr, no cond.;
1646. In HON; 943. In HsS04, no cond.; 167, 167a, 760.
In N2O4, no cond.; 297, 602. In SO2, no cond.; 1842. In
NHs, qual.; 606. In acetone; 336, 1286. In alcohols; 336,
664, 764, 782, 932, 1021, 1263, 1286, (1620), 1820, 1970,
1971, 2029. In EtBr, no cond.; 1436, 1437. In formic
acid; 2008. In hydrocarbons; 1223. In pyridine; 764. In
silicic acid esters; 1223. In thiocyanic acid esters; 939. In
thiocarbimides; 939, 1223..
Cond. with KOH; 294. With aniline; 1900. With dimethyl-
pyrone in organic solvents; 1436. — [See also cond. in vari-
ous solvents in preceding paragraph.] — Under pressure
of 1-500 atmospheres; 220. Purity as shown by e. m. f.;
372.
Ba.2A, in EtBr, slight cond.; 1437. - Li.A; 1367. - Hg.2A; 1084.
- K.A; 294, 1367, 1437, 1439. - Na.A at 25^ A(32)=69.6,
(1024)^79.2; 1368a, 1367; - 336, 1084, 1437.- UQ2.2A;
449.
V
Tri] TABLES 805
Trichloro-acetic acid amide. CsHtONCls » CC]«.CONHs.
Cond. with NaOH; 781.
Tiichloro-acetic acid efhyl ester. C4H50^Cl8.
Effect of temperature on cond.; 106.
2,4,6-Trichloro-benzene diazonium hydroxide. (Trichioro-diazo ben-
zene). CeH»ON2Cl8.
B.Cl(=Cl8.C6Ha.N2.Cl) at 26^ A(32)-94.6, (512) = 102.8; 780.
aa/5-Trichloro-butyric acid. C4H6O2Clj-Me.CHCl.CCl2.CQ2H.
kx XlO at 18**= 2; 460, 1817. At 25** is about 1 *50%; 1870.
Cond.; 1317. At 25^ A(32)-288.5, (1024)=343.1, (oo)=352;
1870.
In N2O4, no cond.; 602. In Et ale; 666a; 664.
Trichloro-diketo-pentamethylene-hydrozy-carbozylic acid. CeHsOsCls.
kAXlO* at 25^=6; m. p. 170^ m(32)«258, (1024) -353.4, (00)-
355; 729, 1186.
In Et ale, alone and with boric acid; 1186.
Cond. with boric acid; 1186.
Trichloro-lactic acid. CsHsOaClj- CClj.CHOH.COiH.
kAXl0» at 18^=4.8; 1817. At 26*'=4.8; diminishes on diln.;
1870, 1186.
Cond.; 948. At 25^ A(32) = 115.1, (1024)=302.2, («>)-356;
1370.
In HCN; 948. In Et ale, alone and with boric acid; 1186.
Cond. with boric acid; 1186.
Na.A at 25^ A(32)«65.2, (1024)=74.4; 1368a.
Trichloro-lacto nitrile. (Chloralcyanohydrate).
C8H20NC18- CCU.CHOH.CN.
In NHs, qual. ; 606.
Trichloro-methane. (Chloroform). CHCls.
xXlO^ at 25'' is less than 2; 740, 1388;=4.4; 1880; 806, 886,
1477.
In HBr and H2S, no cond.; 1897. In HCN, no cond.; 948. In
NHs, qual.; 606. In MeNH2, fair cond.; 637.
Cond. with AgNOs; 1388. With organic compounds; 886, 1388.
As solvent; 740, 1486, (1446), 1830.
Trichloro-R-pentene-dihydrozy-carbozylic acid.
C6H604Cl3= (OH)2C6H2Cl3.C02H.
kA XlO* at 25^*8.8 aq.; diminishes on diln.; m. p. 177° with dec;
1186, 727.
m(64)=183, (512) =288, (a>)=352.
Cond. with boric acid; 1186.
2,4,6-Trichloro-phenol. CeHsOCls » Cls.C6H2.OH.
kAXlO« at 25** =^2.6 (hydrol.); 733 and 1160; is less than 100
(cond.); 733; see also 738.
806 TABLES [Tri
At25^ A(256)=6.4, (1024)-12.3, (»)-356; 788.
In SQz; 1842. In Et ale; 782. In pyridine; 764.
Cond. with cinchonine, in acetone, Et and Me ale; 1690.
Trichloro-tetraketo-hezamethylene-hydrate. CeHsOsCls.
kAXlO*»1.2; diminishes on diln. m(64)-317, (1024)>359,
(oo)=356; m. p. 158^ 729.
Trichloro-triketo-pentamethylene. CeHOsCb.
m(31.2)-323, (998.4)=354; 729.
Tricyano-methane see Cjranofonn.
Triethyl-aUyl ammonium chloride. C»HsoNCl » (Etc) (CsHs) N.Cl.
At 26^ A(32)=87.3, (1024)-98.9; 270.
Triethyl-amine. QHuN » EtcN.
k»XlO*atO*'=2.2. At 9**= 3.8; 776. At 26^=4.4; 776; =6.4 aq.,
16% too high; 271, 664. At 30*'=4.6. At 36''=4.6. At
40*^=6.1. At 50**-5.0; 776. - See also 1283.
Cond.; 979, 1363. At 26^ A(32)=27.1, (256) =66.4, (oo).200;
271.
In Me ale; 386.
Cond. with organic compounds; 979.
B.HCl at 25^ A(32)=88.3, (1024) = 100.2; 270. In HBr; 1646;
qual.; 1237. In HCl; 1646. In HI; 32, 1646. In H2S; 33,
1646; qual.; 1237. In SO2; 1866.
Triethyl-iso-amyl ammonium hydroxide. CnHsrON.
B.Cl,=(Ett)(C5Hii)N.Cl, at 26^ A(32)=82.2, (1024)-93.7; 270.
Triethyl-iso-butyl ammonium hydroxide. CioHasON.
B.Cl, = (Et8)(C4H9)N.Cl, at 25^ A(32)=84.8, (1024)=96.4; 270.
Triethyl-iodomethyl- see lodomethyl-triethyl-
Triethyl-phenyl ammonium hydroxide. C12H21ON - (Ets) (Ph) N.OH.
At 25'', A(32)» 184, (1024) » 185; aq. used for soln. was not pure;
1363. Quoted in 271.
Triethyl phosphine. CeHuP^ EtsP.
Triethyl phosphine dibromide. EtsP.Bi^, m(64)- 513.6; 760.
Triethyl-phosphine-carbon-disulphide methyl iodide. (Triethyl-
phosphonium thiocarboxylic acid anhydride methyl iodide).
EUP.C&.Mel, m(32)=93.8; 760.
Triethyl phosphine sulphide. C«Hi6SP» EtcPS.
B.Mel, at 25^ A(32)=89.7, (512) = 105.7; 760.
Triethyl-propyl ammonium chloride. C9H22NCl»(Etc)(Pr)N.Cl.
At 25^ A(32)=85.1, (1024) =97.0; 270.
Triethyl-rosaniline see Hofmann's ^olet.
Triethyl-sulphine see Triethyl sulphonium.
Triethyl sulphonium hydroxide. TTriethyl sulphine hydroxide).
CeHwOS=Et,S.OH.
tt tt
tl ((
Tri] TABLES 807
At 25^ A(32)-201, (1024) » 205; 1363. Quoted in 271. Qual.;
1802.
B.Cl(-EtiS.Cl), at 25^ A(32)-89.7, (1024)-102.2; 270.- B.I
in aq.; 334, 335, 760, 2029. In acetone; 334. In alcohols;
334, 336, 2029.
Triethyl tellurium chloride. QHifiClTe^ EtsTeCl.
At25^ A(32)-87.4, (1024)-100.2; 270.
Triglycolamic add. QH^OeN - N(CHsCQsH)s.
Hg salt, e. m. f . ; 963.
Triglycyl-aminoacetic acid ethyl ester. (Aminoacetyl-bisglycyl-
aminoacetic acid ethyl ester). C10H18O6N4.
On hydrolysis shows a rise in cond. ; 146b.
Triglycyl-glydne see Triglycyl-aminoacetic add.
1,2,4-Trihydrozy-anthraquinone see Purpurin.
Trihydrozy-benzaldehyde see Hydrozy-hydroquinone aldehyde.
see Phlorog^ucinol aldehyde,
see Pyrogallol aldehyde.
1,2,3-Trihydrozy-benzene see I^ogallol.
1,2,4-Trihydrozy-benzene see Hydrozy-hydroquinone.
1,3,5-Trihydrozy-benzene see Phlorog^udnol.
2,3,4-Trihydrozy-benzoic add see Pyrogallol carbozylic add.
2,4,6-Trihydrozy-benzoic add see lUorogludnol carbozylic add.
3,4,5-Trihydrozy-benzoic add see Gallic acid.
3,4,5-Trihydrozy-2-bromobenzoic add see Bromogallic add.
3,4,5-Trihydrozy-chlorobenzoic add see ChlorogaUic add.
3,4,6-Trihydrozy-2,6-dibromo-benzoic acid see Dibromo-gallic acid.
3,4,6-Trihydrozy-2,6-dichloro-benzoic add see Dichloro-gallic add.
1-Trihydrozy.glutaric add. CBH807=COiH.(CHOH)3.CQ2H.
kAXlO* at 25''» 1.5; diminishes on diln.; m. p. 127''; 1542.
[Since k is twice the value of k of the other stereo isomers,
apparently there is some error. Compare the tartaric acids. ]
m(52.6)-82.2, (105.3) = 107.7, (oo)=352; 1542.
Co.A.- Mg.A at 18^ m(32)-52.0, (1024) = 124.0. - Ni.A; 1736.
rac.-Trihydrozy-glutaric add. CsHgOr.
kxXlO* at 25*'=6.9; m. p. 154.5** cor.
m(52.5)=61.4, (105.3)=82.9, (oo)-352; 1542.
tnacf.-Trihydrozy-glutaric acid. CsHgO.
kxXlO* at 25^-6.6.
m(52.5)«59.5, (105.3)=81.6, (oo)=352; 1542.
2,3,4-Trihydrozy-quinoline. (/37-Dihydroxy-carbostyril) . CgHTOaN.
At 25**, m(1250)=2.03; 1823.
Triiodo-methane. (Iodoform). CHIs.
In HsS, conducts; 27. In NHs, qual.; 606.
Cond. with allyl thiocarbimide; 1223.
808 TABLES [Tri
Trimercisry-diacetone hydroxide. CeHuOeHgi.
At 18^ m(256)- 0.018, (612) =0.022.
Cond. with HCl, showing decomposition.
B.Picrate at 18^ /i(1100)=0.04; 69.
Trimesic acid. CgHeOe- C6H8(CQtH)s. [COiH- 1,3,6. ]
kx X 10^ at 26"*- 9?. Increases on diln.
m(55)»56.5, (220) = 126.5, (880)-226, (oo)=:352; 176.
Trimethyl-acetic add. (Pivalic acid). C6Hio02»Me8C.C02H.
kAXlO«=9.8; m. p. 34*'-36**.
A(32)-6.2, (1024)=32.9, (oo)=354; 1448.
Trimethyl-aciylic acid. CeHioQz^ Me2C :CMe.C02H.
kx XlO* at 26^=3.9; m. p. 69.6**-70.5^ 640, 1704.
At25^ A(l 16.5) =22.9, (932)=60.2, (oo)-353; 1704.
Trimethyl-aUyl ammonium chloride. C8Hi4NCl=(Mes)(CsH6)N.Cl.
At 26^ A(32)-93.9, (1024) = 105.3; 270.
Trimethyl amine. CsHoN = MesN.
kB XlO* at 0*^=2.4; 776. At 26**-5.9; 776;=7.4 aq.; about 16%
too high; 271; =6.5 (neutral.); 299a. Relative strength;
1631. At 35*^=6.8; 776.
Cond.; 299a, 769, 1363. At 25^ A(32)-10.2, (256) =27.5, («) =
214; 271.
In NHs, qual. ; 606.
Cond. with HCl; 299a. With HCIO; 769.
B.HCl at 25^ A(32) = 102.7, (1024)= 114.6; 270. In Sd; 1866.
In NH4OH; 660.
Trimethyl-aminoacetic add. (Betaine. Trimethyl-glycocoll).
CbHuOjN +H20=OH.NMes.CH2.C02H.
kxXlO^^ at 25** is about 1 (catal.); 890;= 1.33 (hydrol.); 1682.
kBXlOi* at 25^=8.7 (catal.); 890;=7.6 (hydrol.); 1984, 271;=
6.2 (hydrol.); 360 and 1160; - 1682, 1773.
At 25% A(32) = 1.7, (256) = 1.8; 360.
Cond. with NaOH; 1984.
B.HBr; 360.- B.HCl at 25% A(64) = 103, (1024) = 111; M(64) =
273; 271; - 360, 890, 1984.
Trimethyl-aminoacetic add ethyl ester.
C7H16Q2N +H20=OH.NMe8.CH2.C02Et.
keXlO^^^ at 25^=1.1 (catal.); 890.
o-Trimethyl-aminobenzoic add anhydride. (o-Benzbetaine).
C10H13O2N +H20=OH.NMe8.C6H4.C02H.
kAXlO" at 25** is less than 1 (catal.); m. p. 225**.
kBXlO" at 25*^=2.8.
Cond. of 0.06 normal soln. is about three times that of aq.; 414.
o-Trimethyl-aminobenzoic add methyl ester.
C11H17O8N = OH. NMe8.C«H4. COjMe.
Tril TABLES 809
ks at 25^ is very great (catal.)
At 1.2'', A(60)»0.13; 414. [If ks is really large, the cond. ought
to be greater than the value given. ]
m-Trimethyl-aminobexizoic acid anhydride. (m-Benzbetaine).
CioHiaOiN +H20=OH.NMe,.CeH4.C02H.
kA XlO" at 25** is less than 1 (catal.); m. p. 215**-220^
ksXlO^i at 25''»3.4 (catal.); 414.
m-Trimethyl-aminobenzoic acid methyl ester.
CuHi70sN-OH.NMe,.CeH4.C02Me.
ks at 25^ is very great (catal.); 414.
p-Trimethyl-aminobenzoic acid anhydride. (p-Benzbetaine).
CioHuQjN +H20-OH.NMe3.C6H4.C02H.
kA at 26® is about 10"" (catal.); is between 10"^ and 10"* (cond.);
m. p. 255**.
kBXlO" at 25^=3.2 (catal.); 890.
p-Trimethyl-aminobenzoic add methyl ester.
CuHnOaN^ 0H.NMes.CeH4.C0iMe.
ks at 25** is very great (catal.); 890.
o-Trimethyl-aminophenol. C9Hi5QsN»OH.NMe«.C6H4.0H.
At25^M(32) = 1.7.
B.Cl(«Cl.NMe8.CeH4.0H) at 26% m(32)-89.4, (1024)-99.9; 766.
m-Trimethyl-aminophenol. (m-Hydroxy-trimethyl-phenyl ammo-
nium hydroxide). CaHisQzN.
At 25% /i(32)=2.2; m. p. 110*'-111^
B.Cl at 25% m(32) = 102.9, (1024) = 114.9; 766.
p-Trimethyl-aminophenol. CsHisO^N.
At26%M(32) = 2.6.
B.Cl at 25% m(32) = 114.1, (1024) -121.4; 766.
Trimethyl-iio-amyl ammonium hydroxide. CsHnON.
B.Cl, = (Me,)(C5Hu)N.Cl, at 25% A(32)-86.7, (1024) -98.2; 270.
Trimethyl arsine. CsHgAs.
Trimethyl arsine dibromide, MesAs.Bi^, m(64)» 496.8, (1024) »
659.6; 760.
2,3,4-Trimethyl-benzoic acid. (Hemellitolcarboxylic acid. Preh-
nitylic acid. l,2,3-Trimethyl-4-benzoic acid).
CioHi20i=Me,.CflH2.CQ,H. [CQ2H-I; Me=2,3,4.]
kAXlO*at25**=3.5; m. p. 165^ 276;-3.1; 1418.
A(512)=44.3, (1024) = 61, (oo) = 351; 276.
Na.A at 25% A(32) = 60.6, (1024)«70.9; 276.
2,4,6-Trimethyl-benzoic acid. (pseudo-Cumene carboxylic acid.
Durylic acid. l,2,4-Trimethyl-5-benzoic acid).
C10H12G2. [CQ|H=1; Me-2,4,6.]
kxXlO^ at 25*^=9.9; diminishes on diln.
A(1024)«94.8, (00) =361; 1418.
810 TABLES [Tri
2,4,^Trimetiiyl-beiizoic add. (j8-uo-Durylic acid. Mesitylene 2-
mono carboxylic acid. l,3,5-Trimethyl-4-benzoic acid).
CioHaOi. [CQ2H-I; Me-2,4,6.]
IcaXIO^ at 25^»3.8; increases, then diminishes on diln.; m. p.
150.5M51^ 276, 1418.
A(128)=69.2, (1024) = 160.2, (oo)-352; 276.
Na.A at 25^ A(32)=61.6, (1024)-72.4; 276.
Trimethyl-benzoyl formic add see Mesityleneglyozylic add.
Trimethyl-2-bromoethyl ammonium chloride.
CjHisNClBr- (Me,)(C2H4Br)N.Cl.
At25% A(32)-91.5, (1024)- 104.0; 270.
Trimethyl-£fo-butyl ammonium chloride.
C7H18NCI- (Me,)(C4H«)N.Cl.
At 25^ A(32)-89.7, (1024) = 101.2; 270.
Trimethyl-carbinamine see fer^iory-Butylamine.
Trimethyl-carbinol see tertiary-Butjl alcohol.
Trimethyl-/3-chloroethyl ammonium chloride.
CjHuNClj- (Me,)(C2H4Cl)N.Cl.
At25^ A(32)-92.8, (1024) -106.0; 270.
Trimethyl-diozy-purine see Caffeine.
Xrimethylene-carbozylic add. (Cyclopropane-carboxylic acid. Ethy-
lene acetic acid). C4H6O2.
kxXlO* at 25*^-1.7; b. p. 182M84^ 238; =1.4; 231, 420, 2026.
A(35.8)=8.8, (71.6) = 12.2, (oo)-358; 238. A(21.1)-6.2, (673.6)
=33.6, (CO ) =362; 2026.
Trimethylene diamine. C8HioN2=NH2.(CH2)8.NH2.
ksXlO* at 25**=3.6 aq.; about 16% too high; 271.
Cond.; 1364. A(32)-20.6, (256)-50.2, (a>)=203; 271.
B.2HC1 at 25^ A(32) = 113.0, (1024)-134.7; 270. - Complex
salts; 1762, 1768, 1762.
Trimethylene-l,l-dicarbozylic add. (Vinaconic acid). C6H6O4.
kAXlO« at 25*^=2.0; diminishes on dUn.; m. p. 140M41**; 288,
1638.
Second kxX 10^= 1.2 (inversion); 1638.
At 25^ /i(34.2)- 197.3, (136.6) =273.7, (oo)=356; 238.
nui(.-Trimethylene-l,2-dicarbozylic add. (cM-acid). C5H6O4.
kxXlO* at 25**=4.1; m. p. 136M37^
M(50.7)-47.7, (202.8)=88.2, (oo)=366; 238.
/um.-Trimethylene-l,2-dicarbozylic add. (frans-acid). C5H6O4.
kAXlO*at26**=2.1; diminishes on dUn. ; m. p. 171M73**.
m(95)=46.9, (380.1)=86.9, («>)-366; 238.
Trimethylene-sulphide see Trithio-fonnaldehyde.
Trimethylene-tetracarbozylic add see Propargylenetetracarbozylic
add.
Tri] TABLES 811
Triinefhylene-l,l,2-tricarbozy]ic add. CeHeOs.
kAXlO»at25**=9.1; 1889.
Second IcaX 10* =4.1 (cond.); 1911.
At 25% m(32) = 146.2, (1024)=338, {»)=354; 1889.
€is-fraiis-Triinefhylene-l,2,3-tricarbozy]ic acid see ^^eudo-Aconitic
acid.
Trimefhyl-efhyl ammonium hydroxide. CsHuON.
B.Cl,=(Me8)(Et)N.Cl, at 25% A(32)-96.1, (1024)-108.0; 270.
Trimethyl-ethylene lactic add. CeHuOs»Me.CHOH.CMe2.CQ2H.
kx XlO* at 25**-2.2; diminishes on diln. A(33.6)=9.4, (1076.2)-
46.4, ( 00) =351; 1704.
/arfiary-Tiimethyl-ethylene lactic add, see /3-Hydrozy-a/3/3-trimethyl-
propionic add.
ooa'-Trimethyl-glutaric add. (Formerly called dimethyl-adipic
add). C8H14O4-CO2H.CHMe.CH2.CMe8.CO1H.
kAXlO* at 25**»3.5; m. p. 94**; 202, 176.
/i(85.3) = 18.5, (1365.1) -68.5, («)-350; 175.
2Na.A at 25% m(32)=76.6, (1024) -97.5; 175.
a/3/3-Trimethyl-glutaiic add.
C8H14O4-CO2H.CH2.CMe2.CHMe.CO2H.
kxXlO* [at 25*']-1.5; diminishes .on diln.; m. p. 88**-89%
m(32)-23.4, (1024)-109.6, («)=351; 76.
Tiimethyl-glycocoU see Trimethyl-aminoacetic add.
Trimethyl-hydrozy ammonium chloride. (Trimethyl-oxamine hy-
drochloride). CaHioONCl- (Me3)(0H)N.Cl.
At 25% A(32) = 101.9, (1024) = 142.3; 769.
Trimethyl-hydrozy ammonium iodide. CsHioONI.
At 25% A(32)- 103.3, (1024) = 145.8; 769.
Trimethyl-iodomethyl ammonium hydroxide.
C4HUONI- (Me8)(CH2l)N.OH.
At 25% A (64) -203, (256) -202; 271.
B.Cl,=(Me8)(CHaI)N.Cl, at 25% A(32)-92.6, (1024)- 105.2;
270.
Trimethyl-methyl iodide see terHary-Butyl iodide.
Trimethyl-a-naphthyl ammonium hydroxide. CuHnON.
B.Cl,-(Me3)(CioH7)N.Cl, at 25% A(32) = 86.6, (1024)-98.3; 270.
Trimethyl-/3-naphthyl ammonium hydroxide. C13H17ON.
B.Cl at 25% A(32)=86.5, (1024)=97.8; 270.
Trimethyl-m-nitrophenyl ammonium hydroxide. (m-Nitrotrimethyl-
aniline). CsHwOaNj- (NQ2)C6H4.NMe8.0H.
B.Br.- B.Cl at 25% A(100)=99.3, (801)- 106.9; 660a.
Trimethyl-phenyl ammonium hydroxide. C»Hi60N-(Me«)(Ph)N.0H.
At 25% A(256)- 189.8; 770.
B.Cl at 26% A(32)-90.1, (i024)-101.6; 270.
812 TABLES [Tri
3,4,4-Trimethyl-l-phenylpyrazolone (6). CuHuONs.
In aq. soln., no cond.; 977.
Trimethyl propyl ammonium hydroxide. ^ CsHitON" (Mes)(Pr)N.OH.
B.Cl at 25^ A(32)«91.9, (1024) -103.6; 270.
2,4,6-Trimetliyl-pyridine. («vm.-CoIlidine) . CgHuN.
kBXlCF at 10*'=1.22 (hydrol.). At 15*'=1.42 (hydro!.); 1144.
At 25^=2.05 (hydro!.); 1144;=2.5 (cond.); 864. At 40^=
3.05 (hydro!.). At 50*'=3.75 (hydro!.); 1144.
At 25^ A(36.6)-0.60, (71.2)=0.88, (oo)=202; 664.- 1144.
In NHs, qua!.; 606.
Cond. with p-nitropheno!; 1144.
B.HC! at 25^ A(64)-94.1, (128)=97.6; 270. At lO^'-SO*'; 1144.
Trimethyl stibine. CgHoSb = MesSb.
Dibromide (=Mej,Sb.Bri), /i(64) - 500.0, (1024) = 521.0; 760.
Trimethyl-stibine hydroxy bromide. CsHioOBrSb- MesSb.(OH)Br.
At 25^ /i(64)-201.2, (1024)=243.9; 760.
Trimethyl-succinic add. C7Hi204=C02H.CMe2.CHMe.C02H.
!caX10* at 25*'=3.1; diminishes on di!n.; m. p. 139.5**; 188, 1838;
m. p. 147**; 60, 68,; m. p. 151M52*'; 232;-3.2; m. p. 148^•
234; m. p. 140^ 2018, 2021.
At 25^ /i(32)-33, (1024) = 148, (oo)«351; 1838.
Trimethyl-succinic acid; m. p. 100'*-105*', ltA= 5-6x10"*, was a mix-
ture of trimethyl-succinic acid with dimethyl-glutaric acid.
Trimethyl-succinic add mono methyl ester. C8H14O4,
ItA XlO* at 25®= 3.1; =2.7 for one preparation.
/i(42.6) = 12.6, (170.6)=24.4, (oo)=351, for lt=3.1; 244.
Trimethyl-sulphin see Trimethyl sulphonium.
Trimethyl sulphonium hydroxide. CsHioOS = MetS.OH.
[At 25^1, A(32)=213.4, (256)=219.9, (oo)»215; 1649.
In Me ale. ; 336.
B.Br, in Me a!c.; 335.- B.C!at25^ A(32) = 101.2, (1024) = 117.8;
270. In Me ale; 336. - B.I at 0^ 1826. At 25^ A(32) =
100.2, (1024) = 112.6; 2029; 1649. In HON; 369. In NH3;
604. In other inorg. solvents; 1826, 1833, 1856. In organic
solvents; 335, 336, 1844, 2029.
Trimethyl teUurimn hydroxide. CsHioOTe = MetTe.OH.
At25^ A(64) = 202, (oo)=205; 271.
B.C! at 25^ A(32)=91.6, (1024) = 105.1; 270.
aa/3-Trimethyl-tricarballylic acid see Camphoronic add.
aoy-Trimethyl-tricarballylic add.
C9Hi406=COaH.CHMe.CH(C02H).CMe2.C02H.
ItxXlO* at 25^=1.44; increases on diln. /i(27)=21.5, (216) =
59.5,; m.p. 133^-134®; 813. [Same acid?] lt=1.4; in-
TW] TABLES 818
creases on diln. /i(32)»21.4, (1024)- 111.4, (oo)«350;
m. p. laO^'-UO^ 444.
???-Trimethyl-tricarbaUyUc add. CoHuOs.
kxXlO* at 25''-2.6; slight increase on diln.; m. p. 136*'-136^
/i(64)»41.9, (1024) » 139.8, (<»)-350; 444.
Trimethyl-xanthlne see Caffeine.
2,4,6-Trinitro-amliQe. (Picramide) .
CeH40eN4- (NQ2)sC6H2.NH2. [NH2- 1. J
In NHs; 604, 610. In MeNHs, good cond.; 637.
1,3,5-Tiimtro-benzene. QHsOsNa^ C6H8(NOs)s.
In aq., no cond.; 771. In NHs; 610. In p3rridine; 7M.
Trinitro-benzoic acid. CrHsOgNs- (N02)sC6H2.C02H.
Na.A, cond. with NaOH; 766.
Tiinitro-metliane. (Nitroform). CHOeN8-CH(N08)i.
At25^/i(32)«327, (512)=351.2; 772; 782.
In Et ale; 782. In pyridine; 764.
Hg.2A; 1084, 1094.- K.A; 763, 772.- Na.A at 25^ A(32)-
80.2, (64) = 83.0; 772. Pyridine salt [?]; 763.
2,4;6-Trimtro-phenol. (Picric acid).
CeHjOzNs- (NQ2)sC6H2.0H. [0H= 1. ]
luXlO at 18''»1.6 (part.); 1636.»2; diminishes on diln.; 460.
At 25^ ==2.3; diminishes on diln.; 1636, 680.
At 0^ A(33.3)- 219.8, (100) =229.5; 680. At 18^ A(25) =
309.9, (1600)=351.2; 976a. At 25^ A(32)-340.1, (1024)-
370.4, (00) =387; 1636; - 70, 402, 1042, 1071, 1366, 1608,
1679, 1718. At 0*^-25*'; 680. At O^'-SS*'; 911. At 18** and
SO**; 1800. At 18** and 90^ 1796.
In HBr, no cond.; 1897. In HON, no cond.; 943. In H2S, no
cond.; 27. In H2SO4, no cond.; 760. In N2O4, no cond.;
297, 602. In SQ2, no cond. ; 1842. In NHs, qual. ; 606. In
MeNH2, good cond.; 637. In alcohols; 664, 764, 1071,
1679, 1680, 1800. In benzene, no cond.; 941, 1800, 1802.
In ether, very small cond. ; 1071, 1680, 1800. In EtBr, no
cond.; 1437. In piperidine and pyridine; 764.
Cond. with acids; 1800. With bases; 1608, 1718. With bases
in benzene, no cond.; 1802. With dimethyl-pyrone; 1827.
With naphthol ; 1042,1842. With naphthalene, in SQ2; 1842.
NH4.A in SOi; 1842. - Mg.2A; 1836. - K.A; 976a. In HsS,
no cond.; 27. In SQ2; 1842. In pyridine; 763.- Na.A
at 25% A(32) = 72.8, (1024) « 82.6; 1636; 402, 496, 680,
1366. - U<%.2A; 449. - Salts of organic bases; 402, 406,
763, 764. Organic salts in benzene, no cond. ; 1802.
2,4,6-Trimtro-re8orcinol. (Styphnic acid. 2,4,6-Trinitro-l,3-dihy-
droxy-benzene). CsHsOgNs- (N02)sC6H(OH)2. [OH = 1,3. ]
814 TABLES [TW
At 25^ /i(101.4) -333.2, (81 1.2) -349.7, (a>)-361; 70.
Cond. alone and with NaOH; 1608, 1718.
Trinitro-toluene. [Probably the 2,4,6- compound.]
CrHjOeN,- (N02)sCeH2.Me.
In NHs; 607. In pyridine; 764.
Cond. with NaOH and HCl showing existence of a nitro-acid;
766. The compound with Me aJc. described in 766 has no
existence; 771.
Trioxy- see Trihydroxy-
Triphenyl amine. CigHuN - PhjN.
In SO21 no cond.; 1842.
Triphenyl aralne. CigHiBAs-PhsAs.
In SO2, no cond. ; 1842.
Triphenyl-benzyl phosphonium chloride.
C2bH»C1P- (Ph,)(PhCH2)P.Cl.
At 26^ A(32)-78.3, (1024)=89.3; 270.
Triphenyl-bromomethane. CioHi5Br « Ph<CBr.
In SO2; m. p. 152"*; 669, 1829, 1842. In acetone, conducts—
probably from decomposition; 767a. In pyridine; 767a,
1260.
Triphenyl carbinol. CigHuO- PhjC.OH.
Comparative strength (colorim.) ; 74.
In SO2; m. p. 159''; 1829, 1842.
Perchlorate^CittHwClOi; m. p. 150®. In ethylene-chloride, con-
ducts. In tetrachloro-ethane; 840.
Salts, see Triphenyl-bromomethane, etc.
Triphenyl-chloromethane. C19H15CI - Ph<CCl.
In SO2; 669, 1676; m. p. 105''-109''; 1829, 1842. In organic
solvents; 73, 668, 669, 767a, 840.
Triphenyl-iodomethane. C19H16I - Ph<CI.
In SO2; 1842.
Triphenyl-methane. CioHu- Ph<CH.
In SOs; 669. In MeNH2, no cond.; 637.
Triphenyl-methyl. Ci9Hi5» Ph^C.
Molecular weight determinations show this to have the formula
of hexaphenyl-ethane (Ph<C)2.
In SQ2; m. p. about 145^-147®; 671; the values in 671 are 10-15%
too low; 673, 1842. (Ph«C)2S04 in SO2; 672. - Perchlorate
in ethylene chloride; 840.
The halogen salts are variously regarded as separate compounds
or as identical with the triphenyl halogen-methane com-
pounds. See Triphenyl-bromomethane etc.
TriJ TABLES 815
Triphenyl-methyl acetic acid ethyl ester.
CttHwOi- (Ph«C)s.MeCQ2Et.
In SO2) no cond. till decomposed; 1842. Gomberg (Ber. Deutsch.
Chem. Ges. 34, 2729) says that this is simply an addition
product.
Triphenyl-methyl peroxide. C38H8o(^ » (Ph8C)202.
In SOsi no cond. until after standing some time; 1842.
Triphenyl-methyl pyridinium hydroxide. (Triphenyl-methyl pyri-
donium hydroxide). CJ4H21ON.
B.BrC-PhsC.NBr.CfiHB) in pyridine; 767a, 1250.
Triphenyl phosphine. CigHuP^* PhjP.
In SO2; 1842, 1866. Compound with Mel in SO2; 1866.
Triphenyl-p-rosaniline trisulphonic add see Helvetia Blue and Spirit
Blue.
Triphenyl stibine. Ci8Hi5Sb»Ph<Sb.
In SOs; 1842.
Triphenyl-trimesic add see Phenyl-naphthalene-dicarboxylic add.
Tripropyl amine. CgH^N » PrsN.
ksXlO^ at 25^»5.9 aq.; about 16% too high; diminishes on
diln.
A(209)=56.8, (a>)-193; 271.
Cond. with allyl thiocarbimide; 1228.
B.HCl at 25^ A(32)=81.2, (1024) =93.0; 270.
Tristearin see Stearic add glyceryl ester.
Trisulphide-acetic add see Trithio-diacetic add.
Trisulphimide. (Sulphimide). Hs06NsS»(S02NH)s. [The references
to this are incomplete.]
/i(69.3)« 709.2; m. p. about 165**; 761.
Trithio-carbondiglycoUic add. (Thiocarbonyl-di-thioglycoUic acid).
C5H604Ss= (CQ2H.CHSH)2CS.
kx XlO* at 25^=2.6; increases on diln.
/i(100) = 148.9, (400)=258.7, (a>)-378; 863.
Trithio-diacetic add. (Trisulphide-acetic acid).
C4H«04S8-S(S.CH,.COjH)2.
kxXlO' at 25**= 1.04; increases on diln.; in. p. 123.5M24^
m(48)=75.5, (768)=244.6, (oo)-378; 861.
a-Trithio-dilactylic add. C6Hio04Ss='S(S.CHMe.CQ2H)s.
kx XlO^ at 25^=8.1; increases on diln.
m(32)=52.2, (1024)=224.5, (oo) = 356; 1133.
Tri-thio-formaldehyde. (Trimethylene-sulphide). CsHeSt^ (HCSH)s.
In HI, poor cond. In H2S, no con^.; 1897.
Tri-p-tolyl bromomethane. Cs2H2iBr= (MeC6H4)sCBr.
In SO2, qual. In benzonitrile; m. p. 165^; 1733.
816 TABLES [Tri
Tri-p-tolyl carbinol. CssH^O.
Salts; see the preceding and the following compound.
Tii-p-tolyl chloromethane. CtiHsiCl- (MeC6H4)8CCl.
In acetone, conducts; 1329. In SO2, qual. In benzonitrile;
m. p. 173**; 1733.
Tropaeolin see p-Dimethyl-aminoazobenzene suiphonic acid.
Tropanol see Tropine.
Tropic acid. CgHisOiN.
kx XlO^ at 25^ » 4.4; increases, then diminishes on diln. /i(32)->
40.6, (266)-106, (1024)-176.7, (oo)=374; 1979.
Tropic acid. (Tropinic acid). C9Hio08«Ph.CH(CH20H).CQ2H.
kAXlO*^ at 25*'=7.5; 1371;=7.9 aq.; m. p. 117M18**; 1186. In
both measurements k increas^, then diminishes on diln.
At25^ A(64)=23.6, (1024)«83.9, (oo)=352; 1371.
Cond. with boric acid; 1186.
Na.A at 25^ A(32)-64.0, (1024)-73.6; 1368a.
Tropine. (Tropanol). CgHuON.
kAXlO" at 26** is not over 1 (hydrol.); 1145a.
ksXlO* at 10^-1.87; 1146a. At 18*'=0.00002 (colorim.); 1778.
At 25** =2.74. At 50^=3.89; m. p. 63**; 1146a.
At25^ A(31.2)-20.1, (91.5)=33.3, (oo)=227.
Cond. with NaOH.
B.HCl at 25^ A(328.5)- 101.8, (656.9) = 103.0; 1145a.
Tropinic acid see Tropic add.
a-Tnudllic acid. (7-180- Atropic acid). Ci8Hi604-Ci6Hi4(CC)kH)s.
kxXlO* at 25^=5.
/i(4332) = 144.5, (oo)«350.
2Na.A at 25^ /i(32)=65.3, (1024) =81.9; 70.
7-TruzilHc add. (e-tso-Atropic acid). C18H16O4.
kx XlO* at 25®= 1.1; diminishes on diln.
m(570) = 81.6, (1140) = 111.9, (a>)=350.
2Na.A at 25^ m(32) = 65.3, (1024) =82.9; 70.
Trypsinfibrinpeptone see Antipeptone.
Tungsten.
Complex salts containing tungsten; 692, 1515, 1516.
Turpentine; also Essence of Turpentine, and Oil of Turpentine.
[The references to this are incomplete.]
x; 1010. X of thin layer; 301. Effect of radium on x; 1491.
Tyrosine see Hydrozyphenyl-aminopropiomc add.
U.
TJmbeUic add. (2,4-Dihydroxy-cinnamic acid).
C9H804= (OH)2CeH3.CH:CH.C02H.
Val] TABLES 817
kx XlO* at 25^-1.9; diminishes on diln.
/i(128) = 16.9, (1024)=44.9, (oo)=352; 1371.
Uramil see Aminobarbituric acid.
Urea. (Carbamic acid amide. Carbamide). CH^ONs^COCNHOs.
kaXlO" at 0*'=0.67 (hydro!.); 2011. At 25*'«1.5 (cataL);
1890; (hydrol.); 663;- 1.2-1.5 (hydro!.); =1.6 and 3.4 (in-
version); 2011. At 40.2**=3.7 (cata!.); 1996. At GO^'-Sl
(hydro!.); 1880 and 1160. Reiative basicity in a!c.; 1061.
At 25% m(32)=0.07, (256)=0.26; 1748. Cond. too sma!l to
measure; 149, 662, 663, 1983.
In HBr and HI, good cond.; in H2S, no cond.; 1897. In HCN,
no cond.; 943. In H2SO4; 760. In NH3, sma!! cond.; 606,
610. InNH4OH;660. In MeNH2, smaU cond.; 637.
Cond. with inorg. acids; 663, 781, 1984, 2011. With inorg.
bases; 663. With NaOH, /i(32)»213; M(32)-211; 1984.
With inorg. sa!ts; 663, 748, 1097, 1983. With organic com-
pounds; 1289b, 1747, 1748.
B.HC! at 25% /i(50)=368.6; 1864; M(32)=369; 1984; - 1791,
2011. - B.HNQs, in NHg, qua!.; 606. - B.H2SO4; 1864.
- B.Acetate; 146a, 1791. - B.Oxa!ate; 1748. - Sa!ts; e. m. f.;
149, 963. - Compiex sa!ts; 1944.
Urethane see Carbamic add ethyl ester.
Uric acid. (2,6,8-Trioxy-purine). C6H4O8N4.
kAXlO* at 18*'=1.5; 826. At 37^-2.3; 696.
At 18% m(6640)«32.2, (oo)=339; 826. At 37**; 696.
In NHs, qua!.; 606.
NH4.A; 696. - Hg.2A, e. m. f.; 963. - K.A; 696, 826. - Na.A at
18%/i(2359)»64.2; 826; 696.
Urine. [The references to tliis are incompiete. ]
Cond.; 218, 261, 262, 263, 267, 307, 310b, 468, 703, 1768. Con-
centration of H and OH ions; 687, 1498.
Uroferrinic add. CssHeeOigNgS.
Cond. shows it to be one-fifth dissociated in aq. [No data
given.]; 1721.
sym.-Uvitic add. (Methy!-m-phtha!ic acid).
C9H804=Me.C6H8(C02H)2. [Me=l; C02H=3,5.J
kAXlO* at 25*^=3; 176.
Second kAXlO'^-5.3? (cond.); 1911.
At25^ m(241.4)=83.6, (965.4) = 158.8, (oo)«353; 176.
Valeramide see Valeric add amide.
Valerianic acid see Valeric add.
818 TABLES [Val
Valeric add. (Propylacetic acid. Valerianic acid).
CjHioQt- Me.(CH2)s.CQ2H.
X is extremely small; 517.
kAXlO* at 10''-1.84; 875. At IS'^^l.e; increases on diln.; 93;
-1.8 (colorim.); 1663; 1643, 1781. At 20''- 1.77; 875. At
25^-1.6; 180, 461;- 1.61; aq. used for soln. was not pure.
1370;- 1.5; 601. At 30**- 1.67. At 40^-1.55; 875.
Cond. at 14*'-60%- 875. At IS**; 93. At 25^ A(32)-7.7, (1024)-
42.6, (oo)»354; 180.
InNHs, qual.; 606.
Cond. not increased by boric acid; 1184. With organic acids;
93.
Fe.2A, in NHs, qual.; 606. - Li.A; 1367. - Mg.2A; 1836. - K.A;
1367. -Na. A at 25^ A(32)-65.6, (1024) -75.4; 1368a,
601;- 1367. At 18**; 93. At 10*'-50**; 875. Cond. with
acetic acid; 93, 1993, 1994. - Zn.2A in ether, almost no
cond.; 366.
Valeric add amide. (Valeramide). C6HuON-C4H9.CO.NHa.
Cond. with NaOH; 412.
Valeric add amyl ester. C10HtoOk-C4H9.CO2.C6Hu.
In NHs, qual.; 606.
Effect of temperature on cond.; 106.
Valeric add tto-butyl ester. C9H18Q1-C4H9.CO8.C4H9.
In NHs, qual. ; 606.
Effect of temperature on cond.; 106.
Valeric add ethyl ester. C7H14Q1 - C4H9.C02Et.
In NHj, qual.; 606.
Effect of temperature on cond.; 106.
Valeric add methyl ester. CeHuOg.
Effect of temperature on cond.; 106.
Valeric add prop]^ ester. C8H16O2.
Effect of temperature on cond. ; 106.
ifo-Valeric add. C6Hio02» Me2CH.CHt.COkH.
kxXlO* at 25'*-1.7; 180, 601;- 1.8; 461. [The acids measured
are of doubtful purity.]
At25^ A(32)-8.3, (1024)-44.1, (oo)-354; 180.
In HBr; 30.
Ag.A; 1637. - Na.A at 25^ A(32)-65.6, (1024)-74.4; 601. At
25*'-60*'; 1637.
iso-Valeric add amide, (iso- Valeramide). CsHuON.
Cond. with HCl; 410.
uo-Valeric add cyanoamide. (tso-Valerylcyanoamide).
CeHioON2-C4H9CO.NH(CN).
Vin] TABLES 819
kAXlO*at26**=1.4.
A(43.2)»26, (1382.4) -123.4, (oo)-360; 70.
Valeric aldehyde. C»HioO - Me. (CH2)s.CH0.
In NHs, qual.; 606.
iso-Valeric aldehyde. CtHioO- Me2CH.CHt.CHO.
X X10» at 0*'=7.94. At 25^-9.94; b. p. 92.5*'-93''; 184S, 1844.
Cond. as solvent of NEtil; 1844.
Valeronitrile. (Butyl cyanide). C5H9N-Me.(CH,),.CN.
xXlO* at 26^-6.4.
Cond. with Cu oleate; and as solvent; 1669.
uo-Valeiylcyano- see also Cyano-uo-valeryl-
ifo-Valeiylcyanoamide see ifo-Valeric add amide.
In complex salts; 1616, 1616.
VaniUic acid. (4-Hydroxy-3-methoxy-ben2oic acid).
C8H804«MeO.C»H,(OH).CQiH.
kAXlO* at 18**-4.2 (colorim.); 1663. At 25*'-2.98; 1871;»3.4,
aq., not perfectly pm'e; 1186.
At25^ A(64) = 15.0, (256)-29.5, (1024)»66.7, (oo)-364; 1371.
InEtalc; 1608,1718.
Cond. with boric acid; 1186. Cond. with NaOH; 1608, 1718.
iso-VaniUic acid. (3-Hydroxy-4-methoxy-benzoic acid). CgHgOi.
kAtXlO^ at 25'' -3.23; diminishes on dihi.
A(266)-30.8, (1024) -57.9, (oo)=354; 1371.
Vanillin. (Protocatechuic aldehyde methyl ether).
C8H80«-MeO.CeH,(OH).CHO. [CHO-1; OH-4; MeO-3.1
kA XlO« at 25^-4.8;. m. p. 80**; 643.
At25^ A(128)-8.7, (1024)-24.0, (oo)=354; 648.
In NHe, qual.; 606. In Et ale; 1608, 1718.
Cond. with NaOH; 1608, 1718.
Vaseline. [The references to this are incomplete. ]
Effect of radium on cond. ; 216, 834, 1491.
Vera^tric add. (3,4-Dimethoxy-benzoic acid).
C9H10O4- (MeO)2C6H,.CQ2H.
kAXlO* at 18^-5.4 (colorim.); 1663. At 26*'-3.63; diminishes
on diln.; 1371.
At 25% A(266)-32.6, (1024)-61.8, (oo)-352; 1371.
Veratrine. CSH49O9N.
In HCN, fair cond.; 943.
Veronal see Diethyl-barbituric add.
Vinaconic add see Trimethylene-dicarbozylic add.
^mylacetic add. CiHsOs-CHsiCH.CHs.CO^H.
kAXlO* at 25**-3.8; b. p. 163**; 671, 664;-4.7; 20a6;-5.1; 673,
corrected in 671.
820 TABLES [Vin
A(32)«13.2, (1024)-68.9, (oo)==383; 671. A(36.8)-14.3, («) =
352; 2026.
Na.A at 25^ A(32)=75.8, (1024)=88.1; 673.
^^^ylglycoUic acid see EthenylglycoUic add.
Vinyltximefhyl ammonium hydroxide. (Neurine).
CBHuON=CH,.NMe«.OH.
At 25^ A(32) -205.6, (512) =207.3; aq. used for soln. was not
pure; 1363.
B.Cl at 25^ A(32)-97.3, (1024) = 109.6; 270.
Violiiiic acid. C4HSO4N8.
kA XlO*^ at 0**=1.44; 701. At 18°«2.6 (hydro!.); 613. [At 18**?]
=2.72; 1190. At 25**=2.73; 701. At 35.6**=3.33; 701.
Cond. at 0^ m(32)-4.7; 701. [At 18**?,] /i(32) = 10.3, (512) =
39.2, (oo)=355; 1190; qual.; 1819; - 782. At 0**-54.1**;
701.
In Et ale; 764, 782. In p3rridine, too insol. to measure; 764.
Cond. with aniline; 613.
K.A at 18^ /i(40)=73.6, (1280)=83.0; 1190.
Violuric add methyl ester. C6H5O4NS.
kx XlO^ at 25**= 1.85; diminishes on diln.; m. p. 268**.
At 25^ A(256)=2.41, (1024) =4.76; 762.
w.
Water. H2O. [Thereferences to this are incomplete.] The ioniza-
tion constant is really the product of the concentration of the
ions, CoHXCH=kw.
40** 50** 100** 156** 218** 306**
5.66 58.2 1
48 223 461 168 ^
1.05 2.94 5.17 »
^ 819 from 999. > 1341 and 949. < 1144.
See also; 46, 269, 822, 1048, 1116, 1129, 1269, 1316, 1376,
1777.
X.
Xanthic add. (Ethylxanthogenic acid). CsHsOSi^'EtO.CS.SH.
K.A, with inorg. salts; e. m. f.; 149.
Xanthic add ethyl ester. (Ethyl xanthogenate).
C6H10OS2 = EtO. CS2. Et.
X Xl0» at 25** is less than 2; b. p. 194**-196** @ 742.8 mm.
Cond. with AgNOs and organic compounds; 1388.
kwXl0"at
0** 10** 15** 18**
25**
0.12 0.28 0.59
1.04
0.09 0.46
0.82
0.12 0.31 0.46 0.62
1.05
Xyl] TABLES 821
Xanthine. (2,6-Dioxy-purine). C5H4Q1N4.
kAXlO*® at 40.r-1.2 (solub.); 1997.
kaXlO" at 40.1*'-4.6 (catal.); 1996;-6.1 (solub.); 1997.
p-Xanthlne see l,7-Dimethyl-2,6-diozy-puiine.
Xanthogen amide see Thiocarbamic add ethyl ester.
Xanthoquinic add see Quininic add.
o-Xylene. CgHio » CeHi. Mes.
In NHs, qual. ; 606.
m-Xylene. CgHio.
xXlO'at 18*^=1.3; 386.
In NHs, qual. ; 606. In MeNHs, no cond. ; 637.
X with organic compounds; 386. The following articles do not
state which xylene was used, x; 306, 1010, 1388. Cond.
with other compounds; 1388, 1900. Effect of radium on
cond.; 2031.
p-Xylene. CgHio.
In NHs, qual.; 606.
m-Xylenesulphone-aminoacetic add. (m-Xylenesulphone-glycine) .
CioHm04NS=C()2H.CH2.NH.S02.C8H9. [Me- 1,3; SQ2-4.]
kAXlO* [at 25**]=:2.70. A(72)=45.2, (575.6)- 112.2, (00)-
348; 1134.
m-Xylenesulphone-4UB]noiirDpionic add. (m-Xylenesulphone-alanine) .
CuHi6O4NS-CQ2H.CjH4.NH.SOi.C8H9.
kxXlO* [at 25*']=2.43. A(134.6)-67.4, (1076.5) -137.8, (»)-
347; 1134.
o-Xylene-?-sulphonic add. CgHioOsS.
Na.A in NHs, qual.; 606.
1,4-Xylene-l-sulphonic add see p-Tolubenzyl sulphonic add.
l,4-Xylene-2-sulphomc add.
CgHioQ8S=Me,.C6Hs.SOjH. [Me- 1,4; S0,H-2.]
kx XlO at 26*' is about 1.6. A(64)-347.7, (oo)=350. ^
Na.A at 25^ A(32)-61.3, (1024)-72.6; 423,
l,3-Xylenol(4). (l,3-Dimethyl-4-hydroxy-benzene).
CgHioO- Me2.C»H,.0H.
kxXlO^ at 25** is about 3.5. A(72)-0.18, (288)-0.93, («)-
355; 70.
Xylenolcarbozylic add see p-Xyletic add.
p-Xyletic add. (2-Hydroxy-l,4-xylenecarboxylic acid).
C9HioOj-Me,.C»H2(OH).CQ2H. [Me- 1,4; CQ2H-3.]
kAXlO* at 25**-6 aq. A(600) = 158, (1200)-196, (oo)=350.
Cond. with boric acid; 1186.
m-Xylic add see 2,4-Dimethyl-benzoic add.
p-Xylic add see 2,5-Dimethyl-benzoic add.
322 TABLES [Xyl
o^m.-m-Xylidine. (4-Amino-l,3-xylene).
C8HiiN-Me8.C6H«.NH,. [Me- 1,3.]
kBXlQi® at 15**- 6.3 (colorim.); 1777.
In NHs, qual.; 606.
B.HCl at 25^ A(64)-89.9, (256)-94.4; 270.
p-XyUdine. (2-Ainino-l,4-xylene). CgHuN. [Me- 1,4.]
kBXlO*® at 20*'=9.6 (colorim.); 1777.
XyHdine. CgHuN.
[No statement as to which was used. The preceding xylidinea
are the common isomers. ]
In HON, no cond.; 943. In benzene, alone and with picric acid,
no cond.; 1802.
Cond. with pyridine and acetic acid; 1388.
l,4,2-Xylidine-5-8i]lphonic add. (l,4-Dimethyl-2-amino-benzene-5-
sulphonic acid). G8HuOkNS-Mes.C6Ha(NH2).SQtH.
[Me-1,4; NH2-2.J
kAXlO* at 25^=4.4. A(64)- 55.4, (1024) -170.1, (00)- 354; 1872.
Xylyl sulphonic add see p-Tolubenzyl sulphonic addk
Z.
Zinc.
In complex salts; 1384, 1946.
See also the following compound.
Zinc cyanic add. G4HsN4Zn - H2Zn(CN)4.
2E.A at 25% A(32)- 117.5, (1024)- 132.4; 1882; 1485.
Zirconium.
In complex salts; 1620, 1648.
C29HWN,.
A dye-base analogous to the triphenyl-methane bases.
B.3HC1, cond. alone and with NaOH to show change to a car-
binol; 1668.
FORMULA INDEX.
Only the names used in the tables are given here. Synonyms are
given in the tables.
Some salts are given, but in general they should be looked for
under the head of the acid or base from which they are derived.
1 L
CGk
Tetrachloro-methane.
C8b
Carbon disulphide.
1 n.
CHN
Hydrocyanic acid.
CHCb
Tn<}hloro-methane.
CHBn
Tribromo-methane.
CHIt
Triiodo-methane.
cmo
Formaldehyde.
CHiOi
Formic acid.
CHiOi
Carbonic acid.
CHsNi
Cyanoamide.
CHiN*
Tetrazole.
CH,N,
Aminotetrazole.
CHiT
Methyl iodide.
CH«0
Methyl alcohol.
CH,N
Methyl amine.
CH»N,
Guanidine.
C0gN4
Tetranitro-methane.
CNI
Cyanogen iodide.
1 m.
CHON
Cyanic acid.
Fulminic add.
CHOjN,
Trinitro-methane.
CHNS
Thiocyanic acid.
CBtO^t
Dinitro-methane.
CH,ON
Formic add amide.
CHiOjN
Carbamic acid.
824
FORMULA INDEX
CH,OiN
Fonuhydroxamic acid.
Nitromethane.
uo-Nitromethane.
OHAN
Nitric acid methyl ester.
<:h,o,n.
Nitro-urea.
('<H|Bt)Sii
Tin methyl tribromide.
CH.ONj
Urea.
CH«0,N,
Methylnitroamine.
CH«02N«
Nitroguanidine.
CH40,S
Sulphurous acid mono methyl ester.
CH4O48
Formaldehyde sulphurous acid.
Uydroxy-methane sulphonic acid.
Sulphuric acid mono methyl ester.
CH«OA
Methylene-disulphonic acid.
CHiNjS
Thiourea.
CH»ON,
Semicarbazide.
CH»ON»
Diazo guanidine.
CHsOtAs
Methyl arsenic acid.
CO.NCI,
Nitro-trichloro-methane.
CBi^Al
See under Aluminum.
•
1 IV.
CH04N,Br
Dinitro-bromomethane.
C&QiNBr
Nitrobromomethane.
CH,
2 I.
Acetylene.
CN,
Cyanogen.
2 n.
Ci^Oj
Glyoxal.
CH,04
Oxalic acid.
C»H,Nia
Azotetrazole.
CH,C1«
Tetrachloro-ethane.
CU,N
Acetonitrile.
CH,N,
1,2,4-Triazole.
CtH«0
Acetaldehyde.
Meta-acetaldehyde» (C^HiO),.
Para-acetaldehyde- (CtH40)x.
Ethylene oxide.
CtHiOb
Acetic acid.
Formic acid methyl ester.
CiH40»
Glycollic acid.
FORMULA INDEX
825
C2H404
Glyoxylic acid.
CH4N4
l-Amino-l,3,4-triazole.
Dicyano-diamide.
C2H4Clai
Ethylene chloride.
Ethylidene chloride.
C2H4Bii
Ethylene bromide.
CtHBCl
Ethyl chloride.
CtHfiBr
Ethyl bromide.
CtHfil
Ethyl iodide.
CiHaO
Ethyl alcohol.
CtHzOt
Ethylene glycol.
CjHeS
Dimethyl sulphide.
Ethyl mercaptan.
CtHyN
Dimethyl-amine.
Ethyl amine.
CtHsN,
Ethylene diamine.
2 m.
C2HOCI,
Chloral.
Chloral hydrate.
CjHOBi^
Bromal hydrate.
CsHOiCl,
Trichloro-acetic acid.
C2HQ2Bi^
Tribromo-acetic acid.
CiHNjAg
Silver cyanic acid.
CjHjOBii
Bromoacetyl bromide.
CtH2Q2Cla
Dichloro-acetic acid.
C2H2Q2Bli
Dibromo-acetic acid.
CiHaOjF,
Difluoro-acetic acid.
CsHjON
Glycollic nitrile.
CsHjOCl
Acetyl chloride.
CjHjOBr
Acetyl bromide.
C2HSQ2N,
Triazo-acetic acid.
CsHsOiCl
Chloroacetic acid.
CHACl,
Chloral hydrate.
C2H>02Br
Bromoacetic acid.
C2H802Bl^
Bromal hydrate.
CsHsOal
lodoacetic acid.
CsHjOjF
Fluoroacetic acid.
CsHjOiN
Oxalic acid mono amide.
Oximino-acetic acid.
CjHeNS
Methyl thiocarbimide.
Thiocyanic acid methyl ester.
C2H4OF,
Difluoro-ethyl alcohol.
826
FORMULA INDEX
C2H4OS
C2H4O8NS
C2H4Q2S
CsHiOkNs
CtH404Nt
CjHjON
CHjOCl
QiHftOiN
CsHsOkNt
CiHjO^N
CjHfiNF,
CjHfiClHg
CtHaONs
CjHeOHg
C2H«0^
CsH«04S
CjHeNBr
C2H7ON
C1H7O2AS
C2H7O4P
C2H7O6P
CiNjAgK
Thioacetic acid.
Hydraziacetic acid.
Oxalic acid di-amide.
ThioglycoUic acid.
Ethylnitrolic acid.
Dinitro-ethane.
Oxaldihydroxamic acid.
Acetaldoxime.
Acetic acid amide.
Glycol chlorohydrin.
Acethydroxamic acid.
Aminoacetic acid.
Glycollic acid amide.
Glycoliminohydrin.
Nitroethane.
iso-Nitroethane.
Nitrous acid ethyl ester.
Allophanic acid amide.
Nitric acid ethyl ester.
Difluoro-ethyl amine.
Mercury ethyl chloride.
Methyl urea.
0-Methyl iao-urea,
Nitrosodimethyl amine.
Mercury ethyl hydroxide.
Sulphurous acid mono ethyl ester.
Acetaldehyde sulphurous acid.
Isethionic acid.
Sulphuric acid mono ethyl ester.
" " dimethyl ester.
2-(/3)-Bromoethyl amine.
Acetaldehyde ammonia.
Cacodylic acid.
Phosphoric acid mono ethyl ester.
Phosphoric acid mono glycol ester.
Potassium silver cyanide.
CiHQ2ClBii
C2HQ2CIF2
CiHQjCliF
C2HQ2BiiF
CjHiONCU
2 IV.
Chloro-dibromo-acetic add.
Chloro-difluoro-acetic acid.
Dichloro-fluoroacetic acid.
Dibromo-fluoroacetic acid.
Trichloro-acetic acid amide.
FORMULA INDEX
827
CHiOClBr
Chloroacetyl bromide.
CH4ONCI
Acetic acid chloroamide.
Chloroacetic acid amide.
CH40NBr
Acetic acid bromoamide.
CiaOiNtF,
Difluoro-ethylnitroamine.
CHfiOClaP
Ethoxy phosphorus chloride.
C2H7Q1NS
Ethyl sulphonic acid amide.
CH7Q1NS
Taurine.
2 V.
CHQiClBrF
Chlorobromofluoroacetio acic
s n.
CsHiN,
Malonitrile.
C,H4Qi
Acrylic acid.
CH40i
P3rroracemic acid.
CU4O4
Malonic acid.
CSH4O6
Tartronic acid.
CU40s
Mesoxalic acid.
CsH4N,
Glyoxaline.
Pjrrazole.
CsHftN
Propionitrile.
CtHsI
Allyl iodide.
GsHtfO
Acetone.
Allyl alcohol.
Propionic aldehyde.
CsH«0»
Acetic acid methyl ester.
Acetol.
Formic acid ethyl ester.
Propionic acid.
C,H«0*
Hydracrylic acid.
Lactic acid.
Methoxy-acetic acid.
C,H«04
aj8-Glyceric acid.
CsHeSt
Tnthio-formaldehyde.
CsHtN
Allyl amine.
CsHTBr
Propyl bromide.
CsHtI
Propyl iodide.
CsHsO
Propyl alcohol.
iso-Propyl alcohol.
CiHsQi
Methylal.
Propylene glycol.
CiHsO*
Glycerol.
828
FORMULA INDEX
CtHsN
nww.-Propyl amine.
isfh
Trimethyl amine.
C8H9A8
Trimethyl arsine.
CsH^Sb
Trimethyl stibine.
CiHioN,
Propylene diamine.
Trimethylene diamine.
3 m.
CHiO^N,
Cyanonitrosoacetic add.
Parabanic acid.
CsHjNjCu
Cupricyanic acid.
CsHeQjN
Cyanoacetic acid.
CsHsO^N,
Cyantiric acid.
CtHsO^Cb
Trichloro-lactic acid.
C8H804C1
Chloromalonic acid.
CHsNS
Thiazole.
CSH4ON,
Acetic acid cyanoamide.
Cyanoacetic acid amide.
CsHiQjN,
Uydantoin.
CsHiOzBr^
aa-Dibromo-propionic acid.
a/3- " " "
CU4O4N,
Dioximino-propionic acid.
Oxaluric acid.
CjHjON
Lactic acid nitrile.
C8H5OCI
Epichlorohydrin.
CH6Q2N
ido-Nitrosoacetone.
CH5Q2NS
a-Triazo-propionic acid.
CsHfiQiCl
Chloro-formic acid ethyl ester.
a-Chloropropionic acid.
/3- " "
GsH»QiBr
a-Bromopropionic acid.
/3-Iodopropionic acid.
CsHsQjI
CsHjOsN
Nitroacetone.
a-Oximino-propionic acid.
^ U it It
CsH604N
Aminomalonic acid.
/3-Nitropropionic acid.
C8HBO4N,
Nitromalonic acid amide.
CHfiNS
Ethyl thiocarbimide.
Thiocyanic acid ethyl ester.
CsHeON,
Ethylene urea.
FORMULA INDEX
829
CsHtOCb
CtHfOSs
C,H,0,N,
C,H,04N,
CtHjON
CiHtO,N
CHtCN,
CtHTOtCl
C»H70»N
CtHsONi
CtHgOiNj
CtHg04S
CsHqQsB
C|H»OeP
CHftNsCl
CHioOS
CiHioOTe
GsHioOSn
CsNsCuNas
Dichloro-hydrin.
Xanthic acid.
Malonic acid di-amide.
anti-Diazo urethane.
Dinitro-propane.
Malondihydroxamic acid.
Nitrocarbamic acid ethyl ester.
Acetoxime.
Propionic acid amide.
Aminoacetic acid methyl ester.
a-Aminopropionic acid.
/S- " "
Carbamic acid ethyl ester.
Methylamino-acetic acid.
Nitropropane.
2-Nitropropane.
Propionhydroxamic acid.
Guanidineacetic acid.
Chlorohydrin.
Nitric acid propyl ester.
Ethyl tso-urea.
2,3-Diamino-propionic acid.
Sulphuric acid propyl ester.
Boric acid trimethyl ester.
Phosphoric acid mono glycerol ester.
j8-Chloro-trimethylene diamine.
Trimethyl sulphonium hydroxide.
Trimethyl tellurium hydroxide.
Tin trimethyl hydroxide.
Sodium cupricyanide.
CgHjONCla
CsHsQsNsS
CHsONSa
CsHsQiNS
CsHaOzNsS
C8H4ON2S
CSH6Q2NS2
CsHfiOaNS
CsHsBr6S2Al
3 IV.
Trichloro-lacto nitrile.
Thioparabanic acid.
Rhodanin.
Diketo-tetrahydro-thiazole.
Thiocyanoacetic acid.
{«o-Nitrosothiohydantoin.
Thiohydantoin.
Dithio-carbamine glycollic acid.
Carbaminethioglycollic acid.
Thiocarbamine glycollic acid.
See under Aluminum.
880
FORMULA INDEX
CHsQzNsS
CsHtONS
CHioONCl
CHioONI
CsHioOBrSb
Ethyl sulphonic acid cyanoamide.
Thiocarbamic acid ethyl ester.
Trimethyl-hydroxy ammonium chloride.
Trimethyl-hydroxy ammonium iodide.
Trimethyl-stibine hydroxy bromide.
C4HN1
C4H2O4
C4H40»
CiPAOt
C4H4O4
C4H4O6
C4H4N,
C4H4S
C4H5N
C4H^
C45A
CiHeO*
C^HeOi
C4H«0s
4 n.
Cyanoform.
Maleic acid anhydride.
Acetylene-dicarboxylic acid.
Hydroxy-maleic acid anhydride.
Tetrohc acid.
Succinic acid anhydride.
Fumaric acid.
Maleic acid.
Hydroxy-fumaric acid.
Hydroxy-maleic acid.
Oxalacetic acid is a mixture of the above acids.
Dihydroxy-fumaric acid.
Dihydroxy-maleic acid.
Ethylene cyanide.
Thiophene.
Pyrrole.
a-Crotonic acid.
Methacrylic acid.
Succin-dialdehyde.
Trimethylene-carboxylic acid.
Vinylacetic acid.
Acetic acid anhydride.
Acetoacetic acid.
Ethenylglycollic acid.^
Methylmalonic acid.
Oxalic acid dimethyl ester.
Succinic acid.
i80-Succinic acid.
DiglycoUic acid.
Malic acid.
tnod.-Malic acid.
d-Tartaric acid.
iTiod.-Tartaric acid.
paro^Tartaric acid.
FORMULA INDEX
881
C4EU08
Dihydroxy-tartaric acid.
C4H,N,
a-Methyl glyoxaline.
N- "
N-Methyl pyrazole.
a- "
Butyro nitrile.
CJiHtN
C4H7N,
Dimethyl-triazole.
CiHTNj
Acetoguanamine.
C«H80
t6(^-Butyl aldehyde.
Methylethyl ketone.
CiHsOi
Acetic acid ethyl ester.
Butjoic acid.
i80-Butyric acid.
Formic acid propyl ester.
Propionic acid methyl ester.
C4HsO»
Ethoxy-acetic acid.
a-Hydroxy-butjoic acid.
^ (( u u
^. « <' «
Hydroxy-MO- " "
C4H,N4
2,5-Dimethyl-l-amino-lj3,4-triazole«
CiHsBti
Butylene bromide.
tso-Butylene bromide.
C«H,N
Methylenecyclopropane amine.
C4H,Br
iso-Butyl bromide.
CtUd
norm.-Butyl iodide.
iso-
terHary- "
C(HioO
norm.-Butyl alcohol.
iscH
tertiary- " "
Ethyl ether.
C4H10O4
Erythrol.
C«Hi«Ni
Diethylene diamine.
C4H10S
Diethyl sulphide.
C4HioHg
Mercury diethyL
C4HioSn
Tin diethyl.
C4HUN
isc^Butylamine.
seconJari^-Butylamine.
tertiary' "
Diethyl-amine.
CUHisNs
Tetramethylene diamine.
C404Ni
Nickel carbonyl.
882 FORMULA INDEX
4 m.
C4H2O4NS Alloxan.
C4H208Fe Ferro-oxalic acid.
C4H2N4Cd Cadmium cyanic acid.
C4H2N4Hg Mercury cyanic acid.
C4H2N4Ni Nickel cyanic acid.
C4H2N4Pd Palladium cyanic acid.
C4H2N4Pt Platino cyanic acid.
C4H2N4Zn Zinc cyanic acid.
C4H8O4N8 Nitro-uracil.
Violuric acid.
C4II8O4CI Chloromaleic acid.
C4H804Br Bromomaleic acid.
C4II8O5NS Nitrobarbituric acid.
C4H8N4CU Cuprocyanic acid.
C4H4O8NS Barbituric acid.
Cyanonitrosoacetic acid methyl ester.
Methyloximino-9yn-oxazolone.
Methylparabanic acid.
Oxyuracil.
C4H4O4N1 Dialuric acid.
C4H4O4CIS /um.-2,3-Dichloro-succinic acid.
maZ.-2,3- " " "
C4H404Br^ «ym.-Dibromo-succinic acid.
180- " " "
C4H4O6N1 aa-Dioximino-succinic acid.
/3/3- " " "
C4H6Q1N Cyanoacetic acid methyl ester.
/S-Oximinobutjoic anhydride.
Succinimide.
C4H8Q2NS 3-Methyl-4-i80-nitro8opyrazolone.
C4H8Q1CI a-Chlorocrotonic acid.
a-Chloro-iso-crotonic acid.
a tt << t( ft
C4H5Q|C]8 Trichloro-acetic acid ethyl ester.
aaj8-Trichloro-butyric acid.
C4H6Q3N8 Aminobarbituric acid.
Methyl-hydroxy-triazole carboxylic acid.
C4H5O4CI tnad.-Chlorosuccinic acid.
d-
1 (t tt
C4HB04Br tnoc^.-Bromosuccinic acid.
FORMULA INDEX
888
C4H604Br
C4H5O6N
C4H6NS
C4HftN2Cl
CiHeOBft
C4H.08N,
C4HeOaC]3
l-Bromosuccinic Acid.
a-Oximino-succinic acid.
^ U it u
Allyl thiocarbimide.
N-Methylchloroglyoxaline.
a-Bromobutyryl bromide.
o-Bromo-wo-butyryl bromide.
Aminoacetic acid anhydride.
Cyanoaminocarbonic acid ethyl ester.
Lactic acid cyanoamide.
Dichloro-acetic acid ethyl ester.
a/S-Dichloro-butyric acid, (fum.).
a^ " " " (mal.).
C4U,0,N«
Allantoin.
CiH,04N,
«2/n-Dioximino-butyric acid.
amphin " " "
C4H«04S
Thiodiglycollic acid.
Thiomalic acid.
C4H,04Sf
Di-thioglycollic acid.
CiBtOSt
Trithio-diacetic acid.
CiHtOiSe
Selenium diglycollic acid.
QHtOtS
Sulphonediacetic acid.
O4HTON,
Creatinine.
C^HtOiN
MC^Nitrosomethylethyl ketone.
C4HTO1CI
Chloroacetic acid ethyl ester.
a-Chlorobutjrric acid.
/S-
C4H70»Br
a-Bromobutjrric acid.
CiHTCI
7"
lodoacetic acid ethyl ester.
7-Iodobut3aic acid.
C4H7Q1N
Acetylamino-acetic acid.
•
a-Oximino-butjrric acid.
j8- " " "
Aminosuccinic acid.
C4H7O4N
Diglycolamic acid.
Malic acid mono amide.
Nitroacetic acid ethyl ester.
C4H7O6P
Phosphoric acid mono erjrthran di-ester.
C4H7NF4
Tetrafluoro-diethyl amine.
C4H8Q,N,
Dimethyl-glyoxime.
Succinic acid di-amide.
C4H8Q2S
Ethylthioglycollic acid.
884
FORMULA INDEX
C4H80^3
C4H8O4N1
C4H8NtS
C4H»0N
C4H9ON1
CiHaQiN
C4H9Q,N,
C4H90iN
C4H90eP
C4HioOBi^
C4H10QSS
C4H10O4N2
O4H10O4S
C4Hio05Nf
C4H10CITI
C4HioIsSn
C4H11OTI
C4H11O4P
C4Hi204Si
C4HUCIP
C4H11CIAS
C4Hi2ClSb
C4H1SON
C4H„0P
C4Hi,0Sb
C4HUOAS
C4N4CdK8
C4N4CUK1
C4N4CuNa«
C4N4HgK8
C4N4K2Ni
C4N4K»Pd
C4N4K8Pt
C4N4KsZn
Aminosuccinie acid mono amide.
Glycyl-aminoacetic acid.
Dinitro-butane.
Allylthiourea.
Acetic acid dimethyl amide.
Butyric acid amide.
W(^-Butyric acid amide.
Acetone semicarbazone.
Aminoacetic acid ethyl ester.
7-Aminobut3rric acid.
Butyrhydroxamic acid.
Dimethyl-aminoacetic acid.
Methylguanidine-acetic acid.
Nitric acid t8o-butyl ester.
Phosphoric acid mono erythran mono ester.
Ethyl ether bromide.
Dimethyl thetine.
Ethyl sulphonic acid ethyl ester.
Sulphurous acid diethyl ester.
Glycoliminohydrin.
Sulphuric acid mono ^8(^-butyl ester.
Sulphuric acid diethyl ester.
Dinitro-ethane alcoholate.
Thallium diethyl chloride.
Tin diethyl diiodide.
Thallium diethyl hydroxide.
Phosphoric acid mono t«o-butyl ester.
" " diethyl ester.
Silicic acid tetramethyl ester.
Tetramethyl phosphonium chloride.
Tetramethyl arsonium chloride.
Tetramethyl stibonium chloride.
Tetramethyl ammonium hydroxide.
Tetramethyl phosphonium hydroxide.
Tetramethyl stibonium hydroxide.
Tetramethyl arsonium hydroxide.
Potassium cadmium cyanide.
Potassium cuprocyanide.
Sodium cuprocyanide.
Potassium mercury cyanide.
Potassium nickel cyanide.
Potassium palladium cyanide.
Potassium platino cyanide.
Potassium zinc cyanide.
FORMULA INDEX
885
CAO^NsCk
CA0^N2Bik
C4HiN4SiCo
C4HsN4S4Pd
C4H«N4S4Pt
C4H404ClBr
CiHftOsNtS
C4He04ClFe
C4H604C12S
C4He04BrFe
C4H604Bl^S
C4H7O4PF4
C4H8N6S4C0
C4H11NCU
C4HUONI
C4N4S4K,Pd
C4N4SiEsPt
4 IV.
Dichloro-barbituric acid.
Dibromo-barbituric acid.
Cobaltothiocyanic acid.
Palladium thiocyanic acid.
Platino thiocyanic acid.
p-Chlorobromosuccinic acid.
Thionuric acid.
Ferri-diacetyl chloride.
/^Dichloro-methylsulphonepropionic acid.
Ferri-diacetyl bromide.
/S-Dibromo-methylsulphonepropionic acid.
Phosphoric acid tetrafluoro-diethyl ester.
Ammonium cobalt thiocyanate.
Trimethyl-iodomethyl ammonium chloride.
Trimethyl-iodomethyl ammonium hydroxide.
Potassium palladium thiocyanate.
Potassium platino thiocyanate.
CsHio
CsHu
6 I.
norm.-Amylene.
norfn.-Pentane.
C^HsOs
C6H40»
CsH40k
CsHjN
CsHeO^
CsHe04
6 n.
Croconic acid.
Furfurol. ^
Citraconic acid anhydride.
Itaconic acid anhydride.
Pyromeconic acid.
Pyromucic acid.
iso-Pyromucic acid.
Pyridine.
Glutaric acid anhydride.
Pyrotartaric acid anhydride.
Tetric acid.
Citraconic acid.
Glutaconic acid.
Itaconic acid.
Mesaconic acid.
Trimethylene-l,l-dicarboxylic acid.
moZ.-Trimethylene-l ,2-dicarboxylic acid.
fum,'
ti
-1,2-
n
It
886 FORMULA INDEX
CftH^Oi Acetone-dicarboxylic acid.
CsHeOs Ethenyl-tricarboxylic acid.
CsHgQi Acetylacetone.
Allylacetic acid.
Angelic acid.
/3-Dimethyl-acrylic acid.
Ethylidenepropionic acid.
Propylideneacetic acid.
Tetramethylene-carboxylic acid.
Tiglic acid.
C^HgOs Acetoacetic acid methyl ester.
Laevulinic acid.
C6H8O4 Dimethyl-malonic acid.
Ethylmalonic acid.
Glutaric acid.
Malonic acid mono ethyl ester.
" dimethyl
Pyrotartaric acid.
Succinic acid mono methyl ester.
CsHsOi a-Hydroxy-glutaric acid.
CsHgOe Tartaric acid mono methyl ester.
C^HgOr trkic<.-Trihydroxy-glutaric acid.
1 tt It ((
roc.' " " "
C6H8O9 Leuconic acid.
C(HsNi N-3-Dimethyl pyrazole.
3,5-
/A-Ethyl glyoxaline.
N- "
C6H9N Valeronitrile.
CbHioO Methylpropyl ketone.
Valeric aldehyde.
i«o-Valeric aldehyde.
CsHioOk Acetic acid propyl ester.
But3rric acid methyl ester.
Formic acid iso-butyl ester.
Methylethylacetic acid.
Propionic acid ethyl ester.
Trimethyl-acetic acid.
Valeric acid.
tso- Valeric acid.
CsHioOk Carbonic acid diethyl ester.
a-Ethoxy-propionic acid.
Hydroxy-pivalic acid.
FORMULA INDEX
887
CbHioOs
a-Hydroxy-valeric acid.
Lactic acid ethyl ester.
CsHioOs
Arabinoee.
CfiHuN
Piperidine.
C»HuBr
Amyl bromide.
CbHuI
Amyl iodide.
CbHuO
norm.-Amyl alcohol.
Dimethyl ethyl carbinol.
CbHuS
t8o-Amyl mercaptan.
CHuN
tso-Amylamine.
Methyldiethyl-amine.
C5H14N,
/^Methyltetramethylene diamine.
Pentamethylene diamine.
6 m.
CftHQiCU
1, 1,3,4,4-Pentachloro-pentadiene-carboxylic acid
CfiHCCU
Trichloro-triketo-pentamethylene.
CBHOiBn
Tribromo-triketo-pentamethylene.
C6H,0»Br
Bromocitraconic acid anhydride.
CsHsOeNs
Nitro-uracilcarboxylic acid.
CBU4Q2N4
Xanthine.
C»U4QsS
a-Thiophenecarboxylic acid.
Uric acid.
CBH4Q8N4
CsHiOsBr^
Acetyldibromo-acrylic acid.
CBH4O4N,
Methylalloxan.
CftHftON
Oxypyridine.
CjHbONb
Guanine.
CbHbQiN
Pyrrole-2-carboxylic acid.
CjHeOiN
Cyanof ormylacetic acid methyl ester.
CsHfiOiBr
Bromotetric acid.
C6H6O4N8
Methylnitro-uraciL
Violuric acid methyl ester.
C6H604Br
Bromocitraconic acid.
CftHeON*
2-Oxy-l,6-dihydro-purine.
CbHsQiN,
Methyluracil.
CsHeQjN,
Cyanonitrosoacetic acid ethyl ester.
Dimethyl-parabanic acid.
Succinic acid mono cyanoamide.
C6H804S«
Trithio-carbondiglycollic acid.
C5H41O6S1
Dithio-carbondiglycoUic acid.
888
FORMULA INDEX
CtHrONt
CtHTOiN
C6H70tNt
C(HT04Br
CtHrNS
C»H,ON,
C(HsOiS
CfHgO^s
CjHaOsS,
CsHsO^Ni
CftHsOiS
C6H8O4SS
CsHsOeS
C5H9Q1N
C6H9Q.C1
CsHsQiBr
C»H9Q2l
CsHjO^N
C6H904N
CftHioOSs
C»HioQiNs
CjHioOjNt
CjHuON
CjHiiQjN
CjHiiO^N
CsHuONi
CsHuQsS
CjHwON
CjHiaNCli
CjHiftON
Methylimino-uracil.
Cyanoacetic acid ethyl ester.
Cyanuric acid N-dimethyl ester.
Bromopyrotartaric acid.
Dimethyl-thiazole.
Butyric acid cyanoamide.
Tetrahydro-a-thiophenecarboxylic acid.
Ethyltrithio-carbonglycollic acid.
Ethyl-aA-dithio-carbonglycollic acid.
tc
tt
u
u
./3A.
Succinuric acid.
iS-Thiocarbonglycollic acid mono ethyl ester.
Thioglycolhydracrylic acid.
a-ThiolactylglycoUic acid.
Methylenedi-thioglycollic acid.
a-Sulphonepropionicacetic acid.
t«o-Nitrosomethylpropyl ketone.
Pyrrolidine^-carboxylic acid.
d-Chlorovaleric acid.
d-Bromovaleric acid.
d-Iodovaleric acid.
a-Oximino-valeric acid.
l€
it
tl
d-Aminoglutaric acid.
inod.-Aminoglutaric acid.
a-Nitropropionic acid ethyl ester.
Xanthic acid ethyl ester.
Methylethyl glyoxime.
Alanyl-aminoacetic acid.
Valeric acid amide.
^s(^- Valeric acid amide.
a-Aminopropionic acid ethyl ester.
Nitrous acid amyl ester.
Trimethyl-aminoacetic acid.
Nitric acid amyl ester.
Diethyl-urea.
Tetramethyl-urea.
Dimethyl-a-propionyl thetine.
MC^Amylisethionic acid.
Vinyltrimethyl ammonium hydroxide.
Tritnethyl-^hloroethyl ammonium chloride.
Trimethyl-ethyl ammonium hydroxide.
FORMULA INDEX
889
6 IV.
CftHsONeFe
Hydronitropnissic acid.
CsHsQiNS
4-Methylthiazole-5-carboxylic acid.
CfiHjOiNiCl
Methyl-chloro-uracil.
CsHftQiNiBr
Methyl-bromo-uracil.
CftHtfONtS
Methyl-thio-uracil.
CfiHaOiNtS
Thiosuccinuric acid.
CsHuNClBr
Trimethyl-2-bromoethyl ammonium chloride
6 L
CeHe
Benzene.
CsHm
Hexane.
CeCle
Hexachloro-benzene.
6 n.
CeHiOe
Rhodizonic acid.
CeHiQ,
p-Benzoquinone.
C6H4O4
Comanic acid.
C6H4O6
Comenic acid.
CeHiBr^
Dibromo-benzene*
CeHfiCl
Chlorobenzene.
CeHsBr
Bromobenzene.
C.HJ
lodobenzene.
CsHeO
Phenol.
C»H«0»
Hydroquinone.
Pyrocatechol.
Resorcinol.
CeHeO*
Dimethyl-maleic acid anhydride.
Hydroxy-hydroqninone.
Phloroglucinol.
Pyrogallol.
C6H.O4
aym.-Methyltrimethenyl-dicarboxylio acid.
CeHeOe
Aconitic acid.
psetido-Aconitic acid.
Trimethylene-tricarboxylic acid.
CeHjN
Aniline.
a-Picoline.
/8- "
7- "
CeHsO*
Dihydro-resorcinol.
Sorbic acid.
CsHgO*
Adipic acid anhydride.
840
FORMULA INDEX
CeHsQi
CeH«04
CeHaOi
CeHaOr
CeHaN,
CeHioQi
CeHioQi
GeHioO^
Hydroxymethylene-acetylacetone.
Pentinic acid.
ALlylmalonic acid.
Aa/3-Dihydro-muconic acid.
A/8y- " " "
Dimethyl-maleic acid.
Ethylfumaric acid.
Ethyllnaleic acid.
Fumaric acid mono ethyl ester.
Maleic acid mono ethyl ester.
o^Methyleneglutaric acid.
CM-iS-Methylglutaconic acid.
trorw-jS- " "
Methylitaconic acid.
Tetramethylene-l,l-dicarboxylic acid.
a8-Tetramethylene-l,2-dicarboxylic acid,
trans- " -1,2-
Propenyltricarboxylic acid.
Tricarballylic acid.
Citric acid.
d-Saccharo-lactonic acid.
o-Phenyiene diamine.
tt
i€
m-
it
tt
ft
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
i€
tt
tt
Phenylhydrazine.
aj9-Hexenoic acid.
6e-
a-Methyl-a/3-pentenoic acid,
a. " -i^.
o- " -7«-
/8- " -a/3-
Pentamethylene-carboxylic acid.
Trimethyl-acrylic acid.
Acetoacetic acid ethyl ester.
jS-Aceto-Mo-butjrric acid.
7-Acetobut3rric acid.
Adipic acid.
«ym.-p-DimethylH3uccinic acid.
«2/m.-an<i-DimethylH3uccinic acid.
a«2/f't*-Diniethyl-succimc acid.
Ethylsuccinic acid.
FORMULA INDEX
841
C6H10O4
MethylethylTnalonic acid.
a-Methylglutaric acid.
/3- " "
Oxalic acid diethyl ester.
Propylmalonic acid.
iso-Propylmalonic acid.
Pyrotartaric acid mono methyl ester.
Succinic acid mono ethyl ester.
Mo-Succinic acid mono ethyl ester.
GeHioOft
1-Malic acid dimethyl ester.
Saccharin.
i80-Saccharin.
(CHio08)x
Glycogen.
Starch.
CeHioOs
Mucic acid.
d-Saccharic acid.
CeHuN
Capronitrile.
CeHuN,
Diethyl-triazole.
CeHiiQi
Acetic acid iso-butyl ester.
tso-Butylacetic acid.
Butyric acid ethyl ester.
tso-Butyric acid ethyl ester.
Caproic acid.
tso-Caproic acid.
Diacetone alcohol.
Diethyl-acetic acid.
Dimethyl-ethylacetic acid.
Formic acid amyl ester.
Propionic acid propyl ester.
Valeric acid methyl ester.
GsHiiO^
a-Hydroxy-aj8i3-trimethyl-propionic acid.
/3- " -a/3/5-
Paraldehyde; see under Acetaldehyde.
Trimethyl-ethylene lactic acid.
CeHuOs
Fructose.
Galactose.
Glucose.
Saccharinic acid.
GsHuOr
Glyconic acid.
C6H]sN4
2,5-Diethyl-l-amino-l,3,4-triazole.
CeHuOi
Pinacone.
CsHmO*
Dulcitol.
d-Mannitol.
CeHuN
Dipropyl-amine.
842
FORMULA INDEX
CeHisN
Di<80-propyl amine.
Triethyl-amine.
C.H„P
Triethyl phosphine.
c.o,cu
Chloroanil.
6 m.
CeHjOiCl,
Chloroanilic acid.
CeH204Bi^
Bromoanilic acid.
CsHsOfiCU
Tetrachloro-diketo-pentamethylene-hydroxy-car*
boxylic acid.
C.H20.N4
Dinitro-oxybeiuo furazane.
l,2-DimtroBo-3,5-dinitro-ben2ene.
CeaOsN,
Nitroanilic acid.
CHtOCl,
2,4,6-Trichloro-phenoL
CeHtCCl,
Trichloro-diketo-pentamethylene-hydroxy-car-
boxylic acid.
Trichloro-tetraketo-hexamethylene-hydrate.
C.HtO*N,
1 ,3,5-Triiiitro-benzene.
CeHtOrN,
2,4,6-Trinitro-phenol.
CeH^OsN,
2,4,6-Trinitro-reBorcinoL
CeH«OuCr
Chromioxalic acid.
CeH«OuFe
Ferrioxalic acid.
CeHiNeCr
Chromicyanio acid.
CsHsNeCo
Cobalticyanic acid.
CeHgNeIr
Iridium cyanic acid.
GeHsNeFe
Ferricyanic acid.
CeH.NeMn
Manganese cyanic acid.
CH4ON,
Phenylene furazane.
CcHiOCla
2,4-Dichloro-phenol.
CHiOsS
o-Thienylglyoxylic acid.
C.H4O4N,
o-Dinitro-benzene.
m- " "
CsH40sN,
p. " "
2,3-Dinitro-phenol.
2,4- "
2,6- "
2,6- "
3,4- "
3,6- "
C5H406N,
2,6-Dinitro-hydroquinone.
C.H40.N4
2,4,6-Trinitro-aniline.
QHiNeFe
Ferrocyanic acid.
QHfiOCl
o-Chlorophenol.
FORMULA INDEX
848
CeHsOCl
p-ChlorophenoL
GeUsOI
lodosobenzene.
GeHsOtoN
Nitrobenzene.
p-Nitrosophenol.
Pyridine-2-carboxylic acid
(( ^ li ti
i( ^ it «
QtB^OJ.
lodoxybenzene.
GsHsQsN
Comanamic acid.
a-Hydroxy-nicotinio acid.
o-Nitrophenol.
m-
2-(o)-Pyrrylglyoxylic acid.
CeHfiOiN,
p-Nitrobenzene diazonium hydroxide.
MO-p- " " "
p-Nitrophenyl-nitro8oamine.
CeHsOiN
Comenamic add.
2-NitroreBorcinol.
2,4-Dinitro-aniline.
C^HjOiN,
CHsOiCU
Trichloro-R-pentenedihydroxy-earboxylic add.
CH5O6N,
2-Amino-4,6-dinitro-phenol.
GeH«ONs
Benzene diazonium hydroxide.
CH«0N4
6-Methyl-2,3-triazo-4-hydroxy-7,0''-pyridazine.
C.H,0*N,
o-Benzoquinone dioxime.
-. tt u
P"
o-Diazo phenol.
P^
o-NitroaniUne.
m-
P-
Phenylnitroamine.
Phenylnitrosohydroxylamine.
C.HeQ,N4
7-Methyl xanthine.
Succinic acid di-cyanodiamide.
CeHaOjS
Benzene sulphinic acid.
CeHtOjN,
2-Amino-4-nitrophenol.
GeHeOsS
Benzene sulphonic acid.
C.H«04N,
Dimethyl-alloxan.
GeHeOiS
o-Phenol sulphonic add.
m- " " "
•v_ tt il ti
GtHtOrSi
Phenol-2,4-disulphomo add.
844
FORMULA INTIF.X
CHeNCl
o-Chloroaniline.
m-
CVHiNBr
P-
m-Bromoaniline.
CHjON
P-
o-Aminophenol.
m-
CjHtOjB
P-
Phenylboric acid.
CHjOiN
Cyanoacetoacetic acid methyl ester.
C,H704N,
Dimethyl-violuric acid.
QHtOsN*
Dimethyl-nitrobarbituric acid.
CHgON*
3-Methyl-2-oxy-l ,6-dihydro-piirine.
Cai.O,N,
a-Dimethyl-uracil.
CyanonitroBoacetic acid propyl ester.
CHgOiNi
5,5-Dimethyl-barbituric acid.
5-Ethylbarbituric acid.
QHgNCl
Methylpyridinium chloride.
QHgNI
Methylpyridinium iodide.
C.H90N
Methylpyridinium hydroxide.
C,H,0,N,
Histidine.
C«H904N
Mo-Nitrosoacetoacetic acid ethyl ester.
CeH«04Nt
7-i8o-Nitroso-/3-nitro8oamino-crotomc a<
ester.
C(H,0«Br
a-Ethylbromosuccinic acid.
a-Oxlmino-succinic acid mono ethyl ester.
CH,0»N
O (t It it ti (t it
GeHtOtN
Triglycolamic acid.
CiHioON,
MO-Valeric acid cyanoamide.
C,Hio04S
a-Thiodilactylic acid, (a-modification).
CeHio04Ss
C6H10O4S8
C6Hio04Se
CeH,oO*N2
CeHioOsS
CeHuQjBr
C.HUO4N
ethyl
tt
it
OS-
t€
tt
a-
Thio-a-lactylhydracrylic acid.
a-Dithio-dilactylic acid.
a-Trithio-dilactylic acid.
Selenium dilactylic acid.
/3/3-Dinitro-caproic acid.
a-Sulphonedipropionic acid.
/8- " "
a-Bromobutyric acid ethyl ester.
Ethylaminosuccinic acid.
).
FORMULA INDEX
845
CHuO«N
C,H„04N,
CHuOtP
CHuNS
QHuNF,
CcHuOtN*
CcHuOtHgi
C(HuON
CHaOiN
CHwOiNi
CeHuOiS
CcHuQiSe
QHmNCI
CeHisOsB
CeHuClTe
CeHifilSn
QHibSP
CeHieOS
GsHuOSn
CeHwNCl
CeHnON
CeOuCrNa.
CeOuFeKs
CeNeCrKs
CeNeCoKs
QNelrKs
CeNeFeEs
GeNeMnEs
Nitrocaproic acid.
Methyl-dihydroxy-triazole carboxylic acid ethyl
ester.
Phosphoric acid mono mannide ester.
Thiocyanic acid amyl ester.
Tetrafluoro-triethyl amine.
7-iao-Nitroso-j9-nitrosoamino-crotomc acid ethyl
ester ammonium salt.
Trimercury-diacetone hydroxide.
Caproic acid amide.
Aminocaproic acid.
Diethylamino-acetic acid.
Lysine.
Argmine.
Diethyl thetine.
Dimethyl thetine ethyl ester.
Diethyl selenium thetine.
Trimethyl-allyl ammonium chloride*
Boric acid triethyl ester.
Triethyl tellurium chloride.
Tin triethyl iodide.
Triethyl phosphine sulphide.
Triethyl sulphonium hydroxide.
Tin triethyl hydroxide.
Trimethyl propyl ammonium chloride.
Dimethyl diethyl ammonium hydroxide.
Trimethyl propyl ammonium hydroxide.
Sodium chromi-oxalate.
Potassium ferri-oxalate.
Potassium chromicyanide.
Potassium cobalticyanide.
Potassium iridium cyanide.
Potassium ferricyanide.
Potassium manganese cyanide.
CeHOsNsBi^
CeHsOsClsBr
CeHjNeSePt
CeHsONjCla
CeHsONaBr^
GeHsOsNCls
6 IV.
3,6-Dinitro-2,4,6-tribromo-phenol.
Hexahydroxy-trichloro-bromotriketo-hexamethy-
lene.
Platini thiocyanic acid.
2,4,6-Trichloro-benzene diazonium hydroxide.
2,4,6-Tribromo-benzene diazonium hydroxide.
4-Nitro-2,6-dichloro-phenol.
846
CeHsOiNsBr
CeHsN«SeCr
C6H4ONCI
GeHiONsBi^
C6H4O2NCI
CeH4QsNCl
CeH40sN2S
CeH408N2S
CeHsONjBr
CeHftOjNS
CeHsOiNS
CeHsOsNS
CeHsOeNS
CHeONCl
GSH6O4N3S
GeHsOtNsS
C6H7O2NS
GsHrOsNS
CH7O4NS
GeHTOeNS)
GeHgOtNsS
CeH804N2S
CeHuC^BrS
CeHuOsBrSe
GeN6S6K2Pt
GeNaSeCrEs
FORMULA INDEX
l,3-Diiiitro-4-bromobenaene.
Chromithiocyanic acid.
p-Benzoquinone chloroimide.
2,4-Dibromo-beiizene diasonium hydroxide.
m-Nitrochlorobenzene.
p-
4-Nitro-2-chlorophenoL
Diazo benzene p-sulphonic acid.
2,6-Dinitro-phenol-4-sulphonic acid.
p-Bromobenzene diazonium hydroxide.
Thienyl-8vri-ketoxime-carboxylic acid.
2-Methyltbiazole-4,5-dicarboxylic acid*
m-Nitrobenzene sulphonic acid.
o-Nitrophenol-4-8ulphonic acid.
2-Aniino-4-chlorophenol.
Benzene sulphonic acid nitroamide.
o-Nitrobenzene sulphonic acid amide.
m-
«
tt
a
((
ti
tt
it
«
3-Nitroaniline-6-eulphonic acid.
Benzene sulphonic acid amide.
2,4-Dimethyl-thiazole-5-carboxylic acid.
o-Aniline sulphonic acid.
m- " " "
p. « " "
2-Aminophenol-4-6ulphonic acid.
4- " -2- " "
Aniline-2,4-di8ulphonic acid.
o-Phenylene diamine 3-Bulphonic acid.
2,6-Diamino-phenol-4-Bulphonic acid.
Dimethyl thetine ethyl ester bromide.
Diethyl selenium thetine bromide.
Potassium platini thiocyanate.
Potassium chromithiocyanate.
6 V.
C6H4Q2NBrtS 2,4,6-Tribromo-benzene sulphonic acid amide.
G$H408NBrsS 4,5,6-Tribromo-aniline-2-sulphonic acid.
2,4,6- " " -3-
2,5,6- " " -3-
GeHsOtNClsS Dichloro-aniline-S-sulphonic acid.
GeHsOsNBi^S 4,5-Dibromo-aniline-2-sulphonic acid.
4,6- " " -2-
tt
(I
u
it
tt
tt
FORMULA INDEX
847
GeHftOtoNBi^S 4,6-Dibromo-aniline-3H9ulphomc acid.
2,6- " " -4- " "
GeHsQgNBrS 2-Bromoaniline-5-8ulphonic acid.
4- " -2- " "
4- " ^ " "
CsHsOaNCIS 4-Amino-2-chlorophenol sulphonic acid.
7 I.
CtHs
Toluene.
C7H11
Heptane.
7 n.
C7H40*
Chelidonic acid.
GiBaOi
Meconic acid.
CtHsN
Benzonitrile.
C7H5N,
Diazo benzene cyanide.
C7HeO
Benzaldehyde.
C7H«0i
Benzoic acid.
o-Hydroxy-benzaldehyde.
111—
p- " "
OtH^O*
2,4-Dihydroxy-benzaldehyde.
2,6-
3,4-
Furfuracrylic acid.
oZIa-Furfuracrylic acid.
o-Hydroxy-benzoic acid.
m-
p- " " "
O7H6O4
2,3-Dihydroxy-benzoic acid.
2,4-
2,5-
2,6- " " "
3,4-
3,5-
Hydroxy-hydroquinone aldehyde.
Phloroglucinol aldehyde. '
Pyrogdlol aldehyde.
CyHeOs
Gallic acid.
Phloroglucinol carboxylic acid.
Pyrogallol carboxylic acid.
CyHeOs
Propargylenetetracarboxylic acid.
O7H1CI1
Benzylidene chloride.
848
C7H7CI
CyHTBr
CrHgO
CtHsQ,
CrHgOj
C7H8O4
CrHsOe
C7H9N
CtHioQs
C7H10OS
C7H10O4
FORMULA INDEX
Benzyl chloride.
p-Chlorotoluene.
Benzyl bromide.
Anisole.
Benzyl alcohol.
o-Cresol.
m-
li
it
2,6-Dimethyl-pyrone.
Guaiacol.
Orcinol.
2,4-Dimethyl-furfurane-3-carboxylic acid.
Methylethylmaleic anhydride.
Piperylenedicarboxylic acid.
/9y-Dicarboxylic^-valerolactone.
Benzyl amine.
Dimethyl-pyridine.
2,6-Dimethyl-pyridine.
Ethylpyridine.
Methylaniline.
o-Toluidine.
m-
n
it
m-Methyldihydro-resorcinol.
A*-Tetrahydro-benzoic acid.
Hexinic acid.
Pimelic acid anhydride.
Allylsuccinic acid.
l,2-Dimethyl-cyclopropane-l,2-dicarboxylic acid
aa'-Dimethyl-glutaconic acid.
a-Ethylideneglutaric acid.
Ethylitaconic acid.
Hydroxy-methylene-acetoacetic acid ethyl ester.
Hydroxy-pimelic acid anhydride.
Methylene-dimethyl-succinic acid.
Methylethylmaleic acid.
cia-Pentamethylene-l,2-dicarboxylic acid.
trans- " -1,2-
aV " -1,3-
trans' " -1,3-
Propenylsuccinic acid.
Propylfumaric acid.
Teraconic acid.
tl
((
tt
«
«
it
CrHioOi
C7H10OS
CrHioOto
C7H10N1
C7HttQ,
OiHttO*
C7HUO4
FORMULA INDEX
Terebic acid.
Acetylmalonic acid dimethyl ester.
Dimethyl-dihydroxy-glutaric lactone.
Hydrochelidonic acid.
Shikimic acid.
Butenyltricarboxylic acid.
180-
849
«
n
it
/3-Dimethyl-ethenyl-tricarboxylic acid.
/tim.-a-Methyltricarballylic acid.
Tricarballylic acid a-mono methyl ester.
2,4-Toluylene diamine.
«
u
it
a
((
((
2,5.
3,4-
a-Ethyl-a/3-pentenoic acid.
tt
-py-
«
u
O-
a/3-Heptenoic acid.
Hexahydro-benzoic acid.
l-Methylpentamethylene-2-carboxylic acid.
a-Dimethyl-laevulinic acid.
a-Ethyl-j9-acetylpropionic acid.
Methylacetoacetic acid ethyl ester.
j8-Methyl^-acetylbutyric acid.
Butylmalonic acid.
t«o-Butylmalonic acid.
Diethyl-malonic acid.
maI.-«|^m.-Dimethyl-glutaric acid.
/3/3-Dimethyl-glutaric acid.
Dimethyl-malonic acid mono ethyl ester.
8ym.-anfo-Dimethyl-succinic acid mono methyl
ester.
8ym.-p-Dimethyl-succinic acid mono methyl ester.
(uym.-Dimethyi-succinic acid a-mono methyl ester.
aaym.' " " " /5- "
a-Ethylglutaric acid.
Ethylmalonic acid mono ethyl ester.
Malonic acid diethyl ester.
a-Methyladipic acid.
/um.-8ym.-Methylethylsuccinic acid.
mal.-syin,'
norm.-Pimelic acid.
iso-
tt
ti
tt
tt
((
tt
850
FORMULA INDEX
C7H11O4
CtHmOs
CtHisO^
OiHiiOr
C7H14O
OiBuOt
Oi^uOi
CtHmO
CtHmOb
7-Pimelic acid.
Propylfluccinic acid.
iao-Propylsuccinic acid.
Trimethyl-Buccinic acid.
aa'-Dimethyl-j9-hydroxy-glutaric acid.
Hydroshikimic acid.
Hydroxy-trimethyl-succinic acid.
Dimethyl-dihydroxy-glutaric add.
Quinic acid.
tno^.-Quinic acid.
Dihydroxy-hydroshikimic add.
Heptyl aldehyde.
Acetic acid amyl ester.
Butyric acid propyl ester.
Heptoic add.
Valeric acid ethyl ester.
j3-Diethyl-ethylenelactic acid.
Dimethyl-ethyl ethylenelactic acid.
Tetramethyl-ethylendactic add.
Heptyl alcohol.
Ortho-formic acid triethyl ester.
CrHeOsBr^
OrHtOgN,
GtH^NsBi^
C7H40tCl8
C7H40sBi^
07H404Clt
G7H40ftBi^
C7H40*N,
C7H4N,C1
C7H4N,Br
CVHbON
CtHsOCI
CyHftQjCl
ti
t€
7 in.
2,4,6-Tribromo-benzoic acid.
Trinitro-bensoic acid.
2y4-Dibromo-beiizene diazonium «yi»-oyanide.
2-Hydroxy-dy5-dichloro-benzoic acid.
3- " -2,6- " " "
4-Hydroxy-3,5-dibromo-benzoic acid.
3,4-Dihydroxy-2,&-dichloro-benzoic add.
3,4- " -5,6- "
Dibromo-gallic acid.
2,3-Dixiitro-benzoic acid.
2,4-
2,6-
2,6-
3,4.
3,5-
p-Chlorobenzene diazonium «yfi-cyanide.
p-Bromobenzene diazonium ^yn-cyanide.
p-Cyano phenol.
Benzoyl chloride.
o-Chiorobenzoic acid.
FORMULA INDEX
861
CrHiOka
CrHfO^r
CrHtOiI
QHiOkF
GrHtOtN
CrHtOtCl
CrHtOa
CtH»04N
OiHiOtN
GrHtOtBr
CrHtOiNt
C;H(NS
QHeOiNs
C,H,04N,
CrHcOtNt
QHtOtS
C7H1O1S
CtHtON
C7H7O1N
m-Chlorobenzoio acid,
p. " "
o-Bromobenzoio acid.
m- " "
it
tt
o-Iodobenzoic acid.
m-
(t
u
tt
(t
m-fluorobenzoic acid.
m-Nitrobenzaldehyde.
p-
2-Hydroxy-&-chlorobenzoic acid.
3- " -2- " "
3- " -6- " "
4- " -3- " "
o-Iodo8obenzoic acid.
o-Nitrobenzoic acid.
m-
«
tt
tt
tt
Pyridine-2,3-dicarboxylio add.
tt .2,4- " "
" -2,6- " "
" .3,4. " "
tt .35. tt tt
Ammonchelidonic acid.
a-Hydroxy-MO-cinchomeronic acid.
3-Nitro-2-hydroxy-benzoic acid.
5- " -2- " " "
Bromogallic acid.
Trinitro-toluene.
Phenyl thiocarbimide.
m-Nitrobenzoic acid amide.
n_ « tt tt
3-Ainino-5-mtrobenzoic acid.
2,4-Dimtro-toluene.
m-Nitrophenyl-nitromethane.
Phenyldinitro-methane.
3-Ainino-5-nitro-2-hydroxy-beiizoic acid.
m-Sulphobenzoic acid.
5-Sulphosalicylic acid.
Benzoic acid amide.
Formanilide.
o-Aminobenzoic acid.
m-
tt
tt
852
C7H70iN
CtHtOjNs
C7H7O3N
C7H7NS
C7H8ON2
C7H80,N,
OrHgOjN*
CrHgQtS
CyHgOsS
C7H9ON
CtHqQiN
C7H9OJN
CrHgOjP
C7H10ON4
CrHioOftBiii
CrHioOttSt
CrHioNQ
FORMULA INDEX
p-Aminobenzoic acid.
Benzhydroxamic acid.
o-Hydroxy-benzoic acid amide.
6-Nitro80-m-cre8ol.
o-Nitrotoluene.
m-
tt
it
Phenylnitromethane.
iso-Phenylnitromethane.
a-Nitroformaldehyde phenylhydrazone.
p-Amino-2-hydroxy-benzoic acid.
2-Methylpyrrylketone-5-carboxylic acid.
l-Methylpyrrylglyoxylic acid.
p-Nitroanisole.
4-Nitrosoorcinol.
Salicylhydroxamic acid.
Thiobenzoic acid amide.
Thioformanilide.
p-Nitro80-methylaniline.
p-Anisole diazonium hydroxide.
3,5-Diamiiio-beiizoic acid.
jS-Nitroso-benzylhydroxylamine.
3-Nitro-4-toluidine.
1 ,3-Dimetliyl-2,6-dioxy-purine.
1,7. " -2,6-
3,7- " .2,6-
o-Toluene sulphinic acid.
P-
o-Anisole sulphinic acid.
Benzyl sulphonic acid.
p-Toluene sulphonic acid.
o-Anisidine.
€t
a
((
u
it
2,4-Dimethyl-pyiTole-3-carboxylic acid.
«
it
u
((
2,4. " " .5-
2,5- " " .3.
Cyanoacetoacetic acid ethyl ester.
Cyanopropionylacetic acid methyl ester.
Hydroxybenzyl h3rpophosphoric acid.
1 ,3-Dimethyl-2-oxy-l,6-dihydro-purine.
Dibromo-hydroshikimic acid.
Methinetrithio-glycollic acid.
Ethylpyridinium chloride.
CtHioNCI
CtHuQiN
C7HUO4N
OrHuOeN
C7HUO4N
C7H16O2N
C7H15O2N
C7H18NCI
FORMULA INDEX 868
Methylpicolinium chloride.
rac.-Ecgoninic acid.
N-Methyl-pyrrolidine-aa'-dicarboxylic acid.
Nitromalonic acid diethyl ester.
d-Aminoglutaric acid ethyl ester.
Trimethyl-aminoacetic acid ethyl ester.
Piperidinoacetic acid.
Methyltriethyl ammonium chloride.
Trimethyl-tso-butyl ammonium chloride.
C7H4QtClBr
C7H4O4NCI
C7H404NBr
CyHsOsNBri
CiHsOjNS
CtHjOjNCI
CyHeOiNBr
CyHeOiNjS
C7H7O4NS
CtHtOsNS
" -2-
" -2-
-3.
-3-
" .4-
l(
n
n
it
tt
it
It
n
u
((
tt
tt
n
It
tt
It
7 IV.
3-Hydroxy-2-chloro-6-bromobenzoic acid.
3- " .6- " -2- " "
3-Nitro-2-chlorobenzoic acid.
4-
6-
2-
6-
2-
3-
3-Nitro-2-bromobenzoic acid.
5. " -2- " "
2- " -3-
6- " -3-
3,4-Dibromo- l-methylpjrrrylglyoxylic acid.
o-Benzoic sulphinide.
3-Amino-2-chlorobenzoic acid.
3- " -6- '* "
norm.-p-Chlorophenyl-nitromethane.
i«o-p-
3-Nitro-4-chlorotoluene.
norm.-p-Bromophenyl-nitromethane .
wo-p-
Benzene sulphonic acid cyanoamide.
o-Sulphaminebenzoic acid,
p- " "
o-Sulphobenzoic acid amide.
2-Amino-4-sulphobenzoic acid.
4- " -2-
4- " -3-
5. " -2-
5- " -3-
m-Nitrotoluene sulphonic acid.
(t
tt
tt
tt
tt
tt
tt
tt
854
C7H70«NS
CrHgOsNiS
CrHgOsNS
C7H9OSN8S
C7H9O6NSS
CrHioQsNsS
C7H17NCII
FORMULA INDEX
3-Amino-2-hydroxy-5H9ulphobeiizoic acid.
2-Nitro-4-toluidine-5H9ulphonic acid.
p-Aminobenzyl sulphonic acid.
o-Methoxy-benzene sulphonic acid amide.
jjl_ it it ti ii It
P-
l-Methylaniline-4-8ulphonic acid.
2-Toluidine-4-8ulphonic acid.
2- " -6-
3- " -2- "
4- " -2- "
4. " .3. "
4. " .?.
2-Nitro-4-tolylhydrazine-5-sulphomc acid.
2*Toluidine-3,5-di8ulphonic acid.
3- " -2,4. " "
2y4-Toltiiylene-diainine-5-sulphonic acid.
2,6- " " -4. " "
lodomethyl-triethyl ammonium chloride.
a
tt
tt
tt
tt
7 V.
CrHrOsNBi^S 3,5-Dibromo-2-toluidine-4-sulphonic acid.
CrHgOtNBrS 3-Bromo-2-toluidine-5H9ulphonic acid.
7- " -2- " -?- " "
9 tt A tt .0 tt tt
CrHsOsNIS 4-Iodo-2-toluidine-5H9ulphonic acid.
C7H90sNsBrS Bromo-2,6-toluylenediamine-4H9ulphonic acid.
CgHeOft
8 I.
CgHio
Ethyl benzene.
o-Xylene.
m- "
P- "
8 n.
C8H4Q1
o-Phthalic acid anhydride.
CgHeQg
Phenylglyoxylic acid.
o-Phthalaldehydic acid.
Piperonal.
CgHsOi
o-Phthalic acid.
m-
tt
tt
tt
tt
4-Hydroxy-o-phthaIic acid.
FORMULA INDEX
856
CsHeOft
CsHjN
CsHrBr
CsHsO
CaHsC^
CsHsQi
CsHgOi
2-Hydroxy-p-phthalic acid.
Benzyl cyanide.
p-Tolunitrile.
(ci))-l*-Bromo8tyrolene«
Acetophenone.
Acetic acid phenyl ester.
Anisic aldehyde.
Benzoic acid methyl ester.
6-Hydroxy-o-toluic aldehyde.
2- " -m- "
4- " -m-
e- " -m-
3- " -p-
Phenylacetic acid.
a-iso-Phenylacetio add.
o-Toluic acid.
It (t
it
tt
ti
(t
n
tt
tt
tt
tt
tt
tt
m-
tt
tt
pseudo-mrTohne acid.
o-Hydroxy-benzoic add methyl ester.
o-Hydroxymethyl-benzoic acid.
o-Hydroxyphenyl-acetic acid,
p- " "
3-Hydroxy-o-toluic acid.
6- " -o-
2- " -m-
4- " -m-
tt
tt tt
tt tt
tt tt
tt
tt
3- " -p-
o-Methoxy-benzoic add.
m- " " "
p. " '« "
Orcyl aldehyde.
Phenoxy-acetic acid.
tnod.-Phenylglycollic add.
1 tt tt
A*-Tetrahydro-o-phthalic acid anhydride.
Vanillin.
Dehydroacetic acid.
i8o-Dehydroacetic acid
A***-Dihydro-o-phthalic acid.
A*»*. " -o- " "
A^«. " -o- " "
356
FORMULA INDEX
CgHgOl
CsHgOfi
CgHgOr
CgHioO
CgHioOg
CgHio04
CgHioOg
CgHioOg
CgHuN
CgHu02
CgHuQg
CgHuOi
A*'*-Dihydro-o-phthalic acid.
iran«-A*'*-Dihydro-o-phthalic acid.
Dimethyl-pyrone carboxylic acid.
Guaiacolcarboxylic acid.
Orcinolcarboxylic acid.
Orsellic acid.
p-Orsellic acid.
Pyronecarboxylic acid.
Vanillic acid.
i«o- Vanillic acid.
Gallic acid methyl ester.
Haematinic acid anhydride.
Hydroxy-dehydroacetic acid.
Diacetyl-tartaric acid anhydride.
Phenetole.
l,3-Xylenol(4).
Methylpropylmaleic acid anhydride.
Methyl-uo-propylmaleic acid anhydride.
(ran«-A*-Tetrahydro-o-phthalic acid.
A*-Tetrahydro-o-phthalic acid.
A». " -o-
((
(t
cw-A*-Tetrahydro-o-phthalic acid.
irana-A*-Tetrahydro-o-phthalic acid.
A*-Tetrahydro-p-phthalic acid.
Diacetyl-succinic acid.
a-Butanetetracarboxylic acid.
/3. " «
Diacetyl-tartaric acid.
Dimethyl-aniline.
Ethylaniline.
2,4,6-Trimethyl-pyridine.
cwym.-m-Xylidine.
p-Xylidine.
1-Cycloheptene-l-carboxylic acid.
2- " -1- " "
Cyclohexene-acetic acid. Liquid isomer.
" " Solid
Dimethyl-dihydro-resorcinol.
Heptinic acid.
Suberic acid anhydride.
tso-Butylfumaric acid.
Diaceto-acetic acid ethyl ester.
Dicrotonic acid.
a«-Hexahydro-o-phthalic acid.
a
CgHuO^
CgHuOs
CgHuOe
CsHuNs
CsHmOi
CsHmOj
CgHuO*
FORMULA INDEX
857
((
l(
it
a
<ran«-Hexahydro-o-phthalic acid.
cis- ** -p-
trans' " -p-
p-Methylallylsuccinic acid.
m€«o-Methylallylsucciiiic acid.
Methylethyl-aticonic acid.
Methylethyl-itaconic acid.
Methylpropylmaleic acid.
Methyl-ifio-propylmaleic acid.
Hydroxymethylene-malonic acid diethyl ester.
oo^Dimethyl-tricarballylic acid.
u
t(
(t
tt
tt
aa -
aa'-
aa'-
Ethyltricarballylic acid.
Haemotricarboxylic acid.
tt
tt
tt
a) acid.
b)
c)
tt
tt
tt
tl
tt
m. p. 140**-141^
m. p. 175*^-176^
mai.-a-Methyltricarballylic acid mono methyl ester.
Dimethyl-p-phenylene diamine.
Cycloheptane-carboxylic acid.
Cyclohexane-acetic acid.
l-Ethylpentamethylene-2-carboxylic acid.
1-Methylcyclohexane-l-carboxylic acid.
ci«-l-Methylcyclohexane-2-carboxylic acid.
tranS'U " -2- "
l-Methylcyclohexane-3-carboxylic acid.
1- " -4- " "
ISO-Butyric acid anhydride.
Ethylacetoacetic acid ethyl ester.
Adipic acid mono ethyl ester.
iso-Butyl-succinic acid.
/ttm.-sym.-Diethyl-succinic acid.
mal.sym,' " " " '
a-8yw.-Dimethyl-adipic acid.
p'Sym.' " " "
Dimethyl-ethylsuccinic acid.
a-Ethyladipic acid.
Ethylpropylmalonic acid.
wi€SO-a-Methyl-a'-ethylglutaric acid.
/3-MethyI-a-ethylgIutaric acid.
a-Methylpimelic acid.
a«-aai-Methylpropylsuccinic acid.
trans-aai' " "
ci«-«ym.-Methyl-wo-propylsuccinic acid.
858
FORMULA INDEX
CsHuO^
CsHmOs
CgHieOi
CgHieOj
trafM-^m.-Methyl-'MO-propylsuccinio acicL
a-Propylglutaric acid.
a-Mo-Propylglutaric acid.
Suberic acid.
Succinic acid diethyl ester.
iso-Succinic acid diethyl ester.
Tetramethyl-succinic acid.
ooa'-Trimethyl-glutaric acid.
a/3/S. " " "
Trimethyl-succinic acid mono methyl ester.
a-Dimethyl-dihydroxy-adipic acid.
(I
(t
ti
ti
y-
d-Tartaric acid diethyl ester.
Butyric acid t«o-butyl ester.
ISO-Butyric acid iao-butyl ester.
Caprylic acid.
Propionic acid amyl ester.
Valeric acid propyl ester.
a-Dimethyl-/§-i«o-propyl-ethylenelactic acid.
Di-wo-propyl-glycollic acid.
CgHnN
d-Coniine.
CgHigO
Octyl alcohol.
CgHwN
Di-i«o-butyl amine.
8 m.
C8H404Cla
3,6-Dichloro-o-phtha1ic acid.
C8H4N8M0
Molybdenum cyanic acid.
CsHbO^N
o-Aminobenzoyl-formic acid anhydride.
m-Cyanobenzoic acid.
Phthalimide.
CsHbOsN
2-Pyrrolepyroracemic acid anhydride.
C8HBO4CI
4-Chloro-o-phthAlic acid.
C8HB04Br
2-Bromo-p-phthalic acid.
CsHbObN
2-Aldehydo-3-nitrobenzoic acid.
2- " -5- " "
CsHbOsN
3-Nitro-o-phthalic acid.
4- " -0- " "
2- " -p- " "
Pyridine-2,3,4-tricarboxylic add.
" .2,3,5. " "
." .3,4,5. " "
CsHsOttNB
Purpuric acid.
FORMULA INDEX
859
CaHflON,
Benzoic acid cyanoamide.
CsHeO^N,
Isatoxime.
CgHaOaCla
2-Methoxy-3,5-dichloro-benzoic acid.
C8H604Cla
3,4-Dibydroxy-2,5-dichloro-benzoic acid
ester.
methjd
3,4-Dihydroxy-5,6-dichloro-benzoic acid
methyl
ester.
C8H«04R
Thienylpyroracemic acid.
CsHaOsClj
2,6-Dichloro-ga11ic acid methyl ester.
CsHtfOsBi^
2,6-Dibromo-gallic acid methyl ester.
C8H«08N4
AUoxantine.
CsHtOjN
Diamino-stilbene dicarboxylic acid.
CsHtOjN,
1-Phenyl-urazole.
•
CsHyOjN
o-Aminobenzoyl-formic acid.
I'-Nitroacetophenone.
Oxanilic acid.
Phenylglyoxylic acid arUi oxime.
o-Phthalic acid mono amide.
*
CgHyOsCl
3-Methoxy-6-chlorobenzoic acid.
C8H7O4N
2-Amino-p-phthalic acid.
2-Methylpyridine-3,5-dicarboxylic acid.
Pyridine-2,3-dicarboxylic acid 2-mono methyl ester.
(( 0 Q_ '* '* ^ " "
it
« .3'4. a a 3. « «
ti
it .34. a it 4. a a
ti
2-Pyrrolepyroracemic acid.
C8H704Br
Bromodehydracetic acid.
CsHtOrN
o-Nitrophenoxy-acetic acid.
CjHtObCI
P"
2-ChlorogalUc acid methyl ester.
CaHrOttN
Nitrovanillic acid.
C8H8Q8N2
Imino-m-nitrobenzoic acid methyl ester.
C8H8O4S
Phenyls!]] phone-acetic acid.
CsHsObS
m-Sulphobenzoic acid a-mono methyl ester.
.
-
m- " " jS- " " "
t
CaHsOeNe
Murexide.
C8H«0N
Acetanilide.
C8H9Q2N
Acetophenone oxime.
Iminobenzoic acid methyl ester.
Phenylacetic acid amide.
o-Aminobenzoic acid methyl ester.
«• " " " "
m-
•« tt it it it
860
FORMULA INDEX
CgHgOiN
C8H9Q2NS
CsHgOaN
C8H9O4N
CsHioONj
C8H10Q2N4
CgHioQ^
C8H10O4N4
CsHioOrNe
CgHioNCl
CgHuON
CsHuQaNs
CsHuQjN
C8H11O4N
CgHuQjNj
CgHttNCl
C8HUO4N
CsHibON
C8H16O8N2
C8H17O2N
C8H2o04Si
C8H20CIP
C8H21ON
anti- Anisaldoxime.
Carbamic acid benzyl ester.
o-Methylamino-benzoic acid,
m- ''
(t
tt
it
tt
tt
Phenylamino-acetic acid.
Nitro-acetaldehyde phenylhydrazone.
o-Aminophenyl methyl carbonate.
,^ tt tt It
Anishydroxamic acid.
2,4-Dimethyl-pyrrole-3,5-dicarboxylic acid.
2,5- " " -3,4- "
Haematinic imide.
Nitro-hydroquinone dimethyl ether.
0-Methyl-N-phenyl-p«etido-urea.
p-Nitroso dimethyl aniline.
Caffeine.
p-Tolubenzyl sulphonic acid.
l,4-Xylene-2-sulphonic acid.
o- " -?- " "
Tbeine.
Ammonium purpurate.
m-Chloro-dimethyl-aniline.
m-Dimethyl-aminophenol.
o-Phenetidine.
P-
8-Aminocaffeine.
Cyanoacetoacetic acid propyl ester.
Cyanobutyrylacetic acid methyl ester.
Cyano-iso-butyrylacetic acid methyl ester.
Cyanomalonic acid diethyl ester.
5,5-Diethyl-barbituric acid.
Ethyl-a-picolinium chloride.
Methyllutidinium chloride.
Tropic acid.
Tropine.
Leucylaminoacetic acid.
Aminocaproic acid ethyl ester.
Silicic acid tetra ethyl ester.
Tetraethyl phosphonium chloride.
Tetraethyl ammonium hydroxide.
Trimethyl-t«o-amyl ammonium hydroxide.
FORMULA INDEX
861
CgHnOP
CgHaOSb
CgHuOAs
CsNsKiMo
Tetraethyl phosphonium hydroxide.
Tetraethyl stibonium hydroxide.
Tetraethyl arsonium hydroxide.
Potassium molybdenum cyanide.
CsHtfONsBr
CgaOjNCl
CgHgOBClBr
CsHtONsS
CsHgONBr
C8H9O4NS
CsHioObNsS
CsHuQsNS
8 IV.
p-Bromophenyl-cyanourea.
o-Chloro-oxanilic acid.
.. tt ft a
2-Chloro-6-bromogallic acid methyl ester.
l-Phenyl-3-thio-urazole.
p-Bromo-acetanilide.
Benzene sulphone-aminoacetic acid.
Nitro-dimethyl-aniline sulphonic acid.
Dimethyl-aniline-4-sulphonic acid.
Ethylaniline-3-sulphonic acid.
t(
It
tt
l,4,2-Xylidine-5H3ulphonic add.
C.H
12
9 L
Cumene.
Mesitylene.
9 n.
CgHeOj
Coumarin.
Phenylpropiolic acid.
CgHeOj
Phthalonic acid.
CsHeOe
Trimeftic acid.
C9H7N
Quinoline.
iso-Quinoline.
C9H8O
Cinnamic aldehyde.
CsHgOj
Atropic acid.
Cinnamic acid.
a22a-Cinnamic acid.
180-
CgHsOs
o-Coumaric acid.
C9H804
m-
tt
tt
o-Acetoxy-benzoic acid.
862
FORMULA INDEX
C»H804
CgHsOs
C9H8N2
C9H10O
CtHioQi
CgHioQs
C9H10O4
CgHioOs
tt
ft
tt
It
tt
tt
tt
tt
tt
m-Acetoxy-bencoio acid,
-j^ It tt tt
Caffeic acid.
Homophthalic acid.
o-Phthalic acid mono methyl ester.
Umbellic acid.
«ym.-Uvitic acid.
4-Hydroxy-o-phthalic acid 1-mono methyl ester.
4. " -o- " " 2-
2- " -p- " " 1-
2- " -p- " " 4-
4-Methoxy-m-phthalic acid.
Carboxydehydroacetic acid.
1-Phenyl pyrazole.
Cimiamic alcohol.
Ethylphenyl ketone.
Benzoic acid ethyl ester.
2,4-Dimethyl-ben2oic acid.
2,6-
3,6-
o-Ethylbenzoic acid.
Hydratropic acid.
Hydrocinnamic acid.
o-Ethoxy-benzoic acid.
m- " " "
^ tt tt tt
tt
tt
tt
tt
it
tt
m-Hydrocoumaric acid,
p.
5-Methoxy-o-toluic acid.
4. " -m- " "
6- " -m- " "
3- " -p- " "
a-Phenoxy-propionic acid.
o tt tt It
Phenylglycollic acid methyl ester.
/3-Phenyl-a-hydroxy-propiomc acid.
/3. " -/3- " " "
1-Phenyl-methoxy-acetic acid.
Phloretic acid.
Tropic acid.
p-Xyletic acid.
Dehydrodiacetyl-laevulinic acid.
Veratric acid.
Gallic acid ethyl ester.
FORMULA INDEX
868
CgHisO
CgHuQi
CsHuQb
CgHuS
CgHisN
CgHuO
CgHuQi
CgHuOs
C9HU04
CgHuOs
C9H1406
C9H1407
CgHieOi
Ethylbenzyl ether.
Diallyl-maloiiic acid.
Camphoranic acid.
Ethylbenzyl sulphide.
sym.-pseudo-Cvimidine.
Dimethyl-benzylamine.
Dimethyl-o-toluidine.
it
tt
-m-
u
tt
Methylethylaniline.
Phorone.
t80-Campholytic acid.
ct«-/ranfi-Campholytic acid.
Camphononic acid.
MO-Octinic acid.
Allylpropylmalonic acid.
Allyl-tdo-propylmalonio acid.
Camphopyric acid.
p-eyfn.-Ethylallylsuccinic acid.
me«o-8ym.-Ethylallylsuccimc acid.
«ym.-Tetramethyl-j8-hydroxy-glutaric acid lactone.
m. p. 120**-124^.
«ym.-Tetramethyl-/3-hydroxy-glutaric acid lactone.
m. p. 140**-141^
Acetylmalonic acid diethyl ester.
Acetic acid glyceryl ester.
1-Camphoronic acid.
aa'-Dimethyl-j3-acetoxy-glutaric acid.
a5-Dimethyl-butane-a/35-tricarboxylic acid.
aa-Dimethyl-tricarballylic acid a-mono methyl
ester.
aa-Dimethyl-tricarbaUylic acid 7-mono methyl
ester.
Methylethylcarboxylglutaric acid.
PropyltricarbaUylic acid.
i«o-Propyltricarballylic acid.
Terpylonic acid.
aa7-TrimethyMricarballylic acid.
/^Hydroxy-camphoronic acid.
Cyclohexane-propionic acid.
l,3-Dimethyl-cyclohexane-3-carboxylic acid.
cia-l,3-Dimethyl-cyclohexane-5-carboxylic acid.
tr an«- 1,3-
it
tt
-5-
tt
tt
864
FORMULA INDEX
C9H15O4
C9H15OJ
C9H16O4
CgHieOs
CgHisQs
CgHuN
l-Methylcyclohexane-3-acetic acid.
Cineolenic acid.
Azelaic acid.
a-^v^'-Diethyl-glutaric acid.
Diethyl-malomc acid mono ethyl ester.
paro-oa'-Dimethyl-pimelic acid.
anti-aa'- " " "
Dimethyl-propylsuccinic acid.
oa'-Dimethyl-a'-tso-propylsuccinic acid.
Dipropyl-malonic acid.
cuHUL'-Methyl-tdo-butyl-Buccinic acid.
irans-aa'- " " " "
a-8ym.-Methylpropylglutaric acid.
a-Propyladipic acid.
Tetramethyl-Buccinic acid mono methyl ester.
«y9n.-Tetramethyl-/3-hydroxy-glutaric acid.
Butyric acid amyl ester.
Pelargonic acid.
Valeric acid i^o-butyl ester.
Dimethyl-/3-t8o-butylethylenelactic acid*
Tripropyl amine.
C9H40Bik
C9HbO»N
C9HBO4N
C9H«08N
C9H<OsN2
C9H7ON
C9H70a
C9H7Q1N
C9H70iCl
C9H7QiBr
CsH70»N
9 m.
2,3-Dibromo-l-indone.
Mo-Nitrosodiketo-hydrindene.
o-Nitro-phenylpropiolic acid.
Pyridine-2,3,4,&-tetracarboxylic acid.
Phenylazoxazolecarboxylic acid.
Phenyloximino-«yn-oxazolone.
Carbostyril.
Cinnamyl chloride.
Pr-2-(a)-Indolecarboxylic acid.
Pr-3-(/3)-
3-Phenylisoxazolone(5) .
1^-Chlorocinnamic acid.
I'-Chlorocinnamic acid.
/^Chlorocinnamic acid.
aUa-/3-Chlorocinnamic acid.
a-Bromocinnamic acid.
2,3|4-Trihydroxy-quinoline.
«
C9H7Q8NS
C9H704N
CgHrOiBr
C9H7O6N
CgHsQiNs
C9H8O4N2
C9H804Cla
C9H8O6CI8
CgHgOsBi^
C9H90kN8
C9H90SN
C9H9ChCl
C9H904N
C9H906C1
C9H906N
C9H10Q8N1
C9H10O4S
C9H110N
FORMULA INDEX
l-Phenyl-5-py]Todiazolone-3-carboxylic acid.
o-Nitrocinnamic acid.
865
m-
tt
t(
(t
t(
2-Bromo-p-phthalic acid 1-mono methyl ester.
2- " -p- '* " 4- " " "
2-Methylpyridine-3,5,6-tricarboxylic acid.
4- " .3,5,6-
3-Nitr(M)-phthalic acid l-mono methyl ester.
3- " -o- " " 2-
«
((
tt
ti
-o-
i<
" ?-
((
it
it
It
it
ti
tt
tt
tt
2- " -p- " " 1-
2- " -p- " " 4-
a-Methyl-m-benzimideazolecarboxylic acid.
m-Methyl-a-benzimideazolecarboxylic acid.
Phenylglyoximecarboxylic acid.
Phthaluric acid.
5,6-Dichloro-veratric acid.
2,6-Dichloro-gallic acid ethyl ester.
2,6-Dibromo-gallic acid ethyl ester.
2-Methyl-l-pheiiyl-urazole.
4- " -1- " "
o-Acetylamino-benzoic acid.
m-
((
it
it
it
tt
it
Benzoylamino-acetic acid.
Homo-o-phthalic acid 1-mono amide.
tt .^ tt u 2- " "
Malonanilic acid.
p-Tolyloxamic acid.
2-Ethoxy-5-chlorobenzoic acid.
2-Amino-p-phthalic acid 4-moiio methyl ester.
O tt _«v tt tt 0 tt tt tt
2,4-Dimethyl-p3rridine-3, 5-dicarboxylic acid.
2,6- " " -3,&-
2-N-Methylamino-p-phthalic acid.
Phenylglycine-o-carboxylic acid.
Pyridine-3,4-dicarboxylic acid mono ethyl ester.
2-Chlorogallic acid ethyl ester.
6-Nitroveratric acid.
Imino-m-nitrobenzoic acid ethyl ester.
a-Phenylsulphone-propionic acid.
Acetic acid benzylamide.
p-Acettoluide.
866
CaHuON
CgHuQiN
CtfHuO^Ns
C9HuO«N
CgHuONs
CgHuQsS
CgHuOsN
CgHuOsN
C9HUQ8N2
C«HibON
C9H16O4N
CgHisOsN
C9H19NS,
C9H20NCI
C9HBNCI
FORMULA INDEX
Iminobenzoic acid ethyl ester.
Imino-o-toluic acid methyl eeter.
o-Aminoben2oic acid ethyl ester.
•V. tt It «( ((
a-Anilinopropionic acid.
o-Dimethyl-aminobenxoic acid,
m- " " "
p- " " <*
o-Methylamino-benzoic acid methyl ester.
rk. « « « « «
inac<.-Phenyl-a-aminopropioiiic acid.
Phenylcarbamic acid ethyl ester.
o-Tolylamino-aoetic acid,
p- " " "
Nitropropionic aldehyde phenylhydrasone.
o-Aminophenyl ethyl carbonate,
p- " " "
p-Hydroxy-phenyl-a-aminopropionic acid.
o-Hydroxy-phenyl urethane.
pseudo-Cumene diazonium hydroxide.
0-Ethyl-N-phenyl pseudo-Mies,.
2-p«eii(2a-Cumene-5-eulphomc acid.
Anhydroecgonine.
Cyanoacetoacetic acid t^o-butyl ester.
Cyano-t80-valerylacetic acid methyl ester.
Trimethyl-m-nitrophenyl ammonium hydroxide.
Trimethyl-phenyl ammonium hydroxide.
o-Trimethyl-aminophenol.
m-
p- " "
Ecgonine.
Di-t8o-butyl-dithio-carbamic acid.
Triethyl-allyl ammonium chloride.
Triethyl-propyl ammonium chloride.
C9H806ClBr
C9H9ON8S
C9H9O7NS
C9HUO4NS
9 IV.
2-Chloro-6-bromogallic acid ethyl ester.
4-Methyl-l-phenyl-3-thio-urazole.
l-Phenyl-3-methylthio-urazole.
4-Nitro-2-sulphobenzoic acid ethyl ester.
o-Toluenesulphone-aminoacetic acid.
tt
tt
it
FORMULA INDEX
867
CioHs
CioHu
CioHie
10 L
Naphthalene.
Cymene.
Dipentene.
limonene.
CioHtfOs
CioHeOg
CioHtBf
CioHsO
CioHgOi
C10H8O4
CioHsOs
C10H9N
CioHioQj
CioHioQs
C10H10O4
CioHioOi
CioHioOs
C10H12O
C10H12Q1
10 n.
2-Hydroxy-l,4-naphthoquinone.
Pyromellitic acid.
l-(a)-Bromonaphthalene.
a-Naphthol.
1,7-Dihydroxy-naphthalene.
Benzalmalonic acid.
Benzoylpyroracemic acid.
Phthalonic acid mono methyl ester.
Lepidine.
a^Naphthyl amine.
Quinaldine.
p-Tolu quinoline.
Ben2oylacetone.
/3-Benzoylpropionic acid.
Cubebin.
Furyldihydro-resorcinol.
Benzylmalonic acid.
Homo-o-phthalic acid 1-mono methyl ester.
it
-o-
<<
t(
u
it
o-Phenylenediacetic acid.
Phenylsuccinic acid.
o-Phthalic acid mono ethyl ester.
Benzyltartronic acid.
4-Hydroxy-o-phthalic acid dimethyl ester.
Opianic acid.
Apiolic acid.
Hemipinic acid.
m-Hemipinic acid.
Anethole.
Cuminic acid.
Eugenol.
2,3,4-Trimethyl-benzoic add.
2,4,6-
2,4,6-
«
It
t(
tt
it
ti
868
FORMULA INDEX
CioHwOj
Cumophenolcarboxylic acid.
3-Ethoxy-p-toluic acid.
a-Methyl-/3-phenyl-j8-hydroxy-propionic add.
a-Phenoxy-butyric acid.
a-Phenoxy-wo-butyric acid.
Phenylethoxyacetic acid.
CioHuOs
1,1,3,3-Hexamethylene-tetracarboxylic acid.
C10H14O
wro-Butylphenol.
Carvacrol.
Carvone.
Thymol.
CioHmQs
Camphor quinone.
C10H14O4
Dimethyl-hydroresorcylic acid methyl ester.
Di-t«o-propylene-succinic acid.
Methylhydroresorcylic acid ethyl ester.
CioHmNj
Nicotine.
CioHuN
Diethyl-aniline.
CioHieO
d-Camphor.
CioHmQi
a-Campholenic acid.
Fencholenic acid.
CioHwOj
Sebacic acid anhydride.
CioHm04
d-Camphoric acid.
1 tt u
tmu^.-Camphoric acid.
meso- " "
d-wo-
1-wo-
imu^.-tso-Camphoric acid.
aaa'a'-Tetramethyl-dihydro-muconic add.
CioHieOfi
Cineolic acid.
CioHwOe
Methanetricarboxylic acid triethyl ester.
Propyl-wo-butenyltricarboxylic acid.
a-Tetramethyl-tricarballylic acid.
Q It tt tt
oory-Tetramethyl-tricarballylic acid.
CioHigO
d-Bomeol.
Citronellal.
Cineole.
1-Menthone.
CioHisQi
Campholic acid.
CioHigOj
Oxymenthylic acid.
Pulegonic acid.
C10H18O4
Dihydro-camphoric acid.
a-Dihydroxy-dihydro-campholenic acid.
FORMULA INDEX
869
CioHitO^
oa-Dimethyl-a'^iso-butylsuccinic acid.
m-flym.-Dipropyl-BUCcinic acid.
transom.' " " "
cia-^m.-Di-^o-propylHSUCcimc acid.
Heptylmalomc acid.
cM-a-Methyl-a'-i«o-amylH9Uccimc acid.
ci»-a-Propyl-a'-t80-propylH9uccimc acid.
(ran«-a- " -a'-*8a- " "
Sebacic acid.
Suberic acid mono ethyl ester.
tt
CioHmO
Menthol
CioHjoQj
Acetic acid capryl ester.
Capric acid.
Caprylic acid ethyl ester.
Valeric acid amyl ester.
CioHsoOs
a-i«a-Propyl-/3-wo-butylhydracrylic acid.
CioHttN
Menthyl amine.
CioHnO
Amyl ether.
CioHaN
DiH^o-amyl amine.
10 m.
CioHsQsBr
2-Hydroxy-3-bromo^-naphthoquinone.
CioHftOioN
Pjrridinepentacarboxylic acid.
C10H7Q1N
Cinchoninic acid.
l-(a)-Nitronaphthalene.
4-Nitroso-l-naphthol.
2- " -1- "
1- " -2- "
Quinaldinic acid.
CioHyOjN
p-Hydroxy-quinoline-o-carboxylic acid.
Phenylisoxazolecarboxylic acid.
C10H7O4N
o-Phthalylamino-acetic acid..
C10H8ON2
anti'fi-DiSLZo naphthalene.
^Naphthylnitroso amine.
CioHsOiS
a-Naphthalene sulphonic add.
Q It it U
3,6-Dichloro-o-phthalic acid mono ethyl ester.
CioH804C]3
CioH«Q2N
Pr-2-«Methyl-indole-2-carboxylic acid.
3- " " -3- " "
C10H9Q2N,
3-Methyl-l-phenyl-4-i6a-nitroso-5-pyrazolone.
C10H9Q8N
Fumaranilic acid.
870
FORMULA INDEX
CioHtOsNi
CioHgOsN
CioHgOeN
C10H9O7N
CloHgOgN
CioHioONi
CioHioQjNj
C10H10O4N2
CioHuON
CioHuQsNs
Ci9HuQiN
OioHuOiN
CioHuOeN
CioHuON
CioHuQjN
l-PhenyI-5-hydroxy-l,2,3-triazole-4-carboxylio
acid methyl ester.
4-Acetylamino-m-phthalic acid.
2- " -p- " "
4-Nitro-o-phthalic acid 1-mono ethyl ester.
It
-o-
«
" 2- "
tt «
Nitroopianic acid.
Nitrohemipinic acid.
3-Methyl-l-phenyl-&-pyrazolone.
Ethyl-p«eiMio-i8atin-/3-oxime.
Oxalacetic acid phenylhydrazone.
Methylquinolimum hydroxide.
Methyl-iso-quinolinium hydroxide.
l-Phenyl-3-ethoxy-urazole.
Benzoylamino-propionic acid.
labile /S-Benzoylpropionic acid oxime.
BUjUnUfi- " " "
Methylbenzoylamino-acetic add.
Phenaceturic acid.
Phenylacetylamino-acetic add.
Succinanilic acid.
o-Toluric acid.
m-
n
u
p-
Anisuric acid.
3-Nitrocumiiiic acid.
Phenylglycine-o-carboxylic acid eso mono methyl
ester.
Phenylglycine-o-carboxylic acid exo mono methyl
ester.
Phenyliminodiacetic acid.
Hemiplnic acid 1-mono amide.
It It O tt it
Iminobenzoic acid norm.-propyl ester.
it
tt
XBO-
tt
tt
Imino-phenylacetic acid ethyl ester.
Imino-p-toluic acid ethyl ester.
a-Anilinobutyric acid.
a-Anilino-iso-butyric acid.
fi tt tt tt tt
o-Dimethyl-aminobenzoic acid methyl ester.
j^^ tt tt tt tt tt
P-
a-o-Toluidinopropionic acid.
FORMULA INDEX
871
CioHuQiN
CioHuQiN
CioHuQiNi
CioHmNQ
CioHuCN
CjoHnO»N
CioHuOuFei
CwHmNCI
CioHnON
C,jai7Q,N
QoHirOsNi
CioHwOsN*
C,«Hi4Na
Cio^tON
tt
tt
tt
tt
tt
tt
tt
a-p-Toluidinopropionic acid.
jS-p- " .
o-Trimethyl-aminobensoic acid anhydride,
m-
P-
o-Methoxy-phenyl urethane.
4-Methyl-2-aminophenyl ethyl carbonate.
^ " -2- " " "
R. '* -2- " " "
3-Methyl-6-hydroxy-phenyl urethane.
Glycocoll-p-phenetidine.
Diethyl-m-chloroaniline.
Camphoric acid imide.
Cyanoacetoacetic acid Mo-amyl ester.
Diferri-pentaacetyl hydroxide.
Dimethyl-ethylphenyl ammonium chloride.
Camphor oxime.
Dimethyl-ethylphenyl ammonium hydroxide.
Camphoric acid a-mono amide.
tt tt Q tt tt
Antipeptone a.
Triglycyl-aminoacetic acid ethyl ester.
Triethyl-i^o-butyl ammonium chloride.
Triethyl-t80-butyl ammonium hydroxide.
C10H6O8N2S
CioHtOsNS
C10H9O4NS
10 IV.
2,4-Dinitro-l-naphthol-7-sulphonic acid.
-Naphthylamine-2-8ulphonic acid.
-4-
.5-
-6-
-7-
-8-
-1-
-6-
-6?.
.7.
-8-
2-
2-
2-
2-
2-
5-Amino-l-naphthol-3-8ulphonic acid.
e- " -1- " -3- " "
a tt jn tt A tt tt
ft. " -1- " -4- " "
8- " -1- " -6-
tt
tt
872
FORMULA INDEX
CioH»06NS2 l-Naphthylamine-2y4-di8ulphonic acid.
CioHgOrNSt
C10H9O9NSS
CioHioQ«NCl
CioHioQjNBr
CioHuONsS
CioHuOfcNS
C10HUO4NS
CioHuOgNiP
CioHi604BrS
1-
1-
1-
1-
1-
2-
2-
2-
it
tt
tt
-2,5?-
-4,6-
-4,7-
-4,8-
.5,7?-
-3,6-
-4,8-
-6,8-
8-Amino-l-naphthol-3,6-disulphomc acid.
l-Naphthylamine-2,4,7-tri8ulphomc acid.
1- " -3,6,8-
Chloroacetyl-phenyl amino-acetic acid.
o-Chlorosuccinanilic acid.
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
tt
m-
tt
tt
tt
tt
Acetyl-bromophenyl amino-acetic acid.
Bromoacetyl-phenyl amino-acetic acid.
l-Phenyl-3-ethylthio-urazole.
Benzenesulphone-aminosuccinic acid.
m-Xylenesulphone-aminoacetic acid.
Inosinic acid.
o-Bromocamphor sulphonic acid.
10 V.
CioHuOsClBrS Bromocamphorsulphonic chloride.
11 n.
C11H7N
a-Naphthonitrile.
a-Naphthoic acid.
CiiHsOj
/S- " "
CuHgOs
a-Hydroxy-naphthoic acid.
CnH804
Carminic acid.
CiiHioOj
A^-Dihydro-a-naphthoic acid.
A*. " -«- " "
A«- " -/3- " "
A*. " -j3- " "
CiiHioOs
Phenyltetric acid.
C11H10O4
Phenylitaconic acid.
Phenylparaconic acid.
tso-Phenylparaconic acid.
FORMULA INDEX
878
CuHioOs
CuHioOy
CuHuOj
CuHisOi
CuH]s04
CuHisOb
CuHuO?
CuHmOj
CuHmQi
CUH14O4
CuHisQs
CiiHisOs
CuHitN
CuHigOj
CuHl804
CuHisQs
CuHso04
/S-Benzoyl-tso-succinic acid.
Apionylglyoxylic acid.
Cinnamic acid ethyl ester.
Ar-a-Tetrahydro-naphthoic acid.
/S-Tetrahydro-naphthoic acid.
Benzoylacetic acid ethyl ester.
Mesityleneglyoxylic acid.
Benzylsuccinic acid.
Homo-o-phthalic acid l-mono ethyl ester.
Mesitylenedicarboxylic acid.
Methylbenzylmalonic acid.
/um.-«ym.-Methylphenylsucciiiic acid.
fikiZ.-«ym.- " "
Phenylglutaric acid.
Phenylsuccinic acid a-mono methyl ester.
(t (( A it it it
Hemipinic acid l-mono methyl ester.
Carminic acid.
Piscidic acid.
Benzoic acid i<o-butyl ester.
2,3,4,&-Tetramethyl-benzoic add.
2,3,4,6- " " "
2,3,5,6- " " "
p-Thymotic aldehyde.
a-Ethyl-/3-phenyl-/3-hydroxy-propiomc acid.
a-Phenoxy-i«o-valeric acid.
Phenylhydroxy-pivalic acid.
Phenylpropoxyacetic acid.
3,4-Diethoxy-benzoic acid.
Camphorcarboxylic acid.
2,6-Dimethyl-pentane-2,6-tetracarboxylic acid.
Diethyl-benzyl amine.
Diethyl-m-toluidine.
cia-Bomeolcarboxylic acid.
ci8-<ra7i«-Bomeolcarboxylic acid.
d-Camphoric acid mono oZIo-methyl ester.
d-Camphoric acid mono o-methyl ester.
«ym.-Tetramethyl-/3-acetoxy-glutaric acid.
2,6-Diethyl-pimelic acid.
oa-Dimethyl-a'-iso-amylsuccinic acid.
ci8-«|/m.-Di-^o-propyl-8UCcinic acid mono methyl
ester.
874
CiiHsoO^
CuQbOs
FORMULA INDEX
trar»-92^.-Di-MO-propyl-succimc acid mono methyl
ester.
Octylmalonic acid.
Pelargonic acid ethyl ester.
a-Dimethyl-/3-hydroxy-pelargonic add.
CuHftOiBr^
CuHsQiNs
CuH,Q,N
CuHuQiN
CuHuQ«N
CuHuOjN
CuHuO^N
CuHuON,
C11H1SO4SS
CiiHuNI,
CuHmOjNs
CuHuOiN
C11HMO4N
CuHmON,
CuHuON
CuHuOiN
CuHuO^Ni
11 m.
/3-Bromocarmin.
3,2'-Dipyridyl-3'-carboxylic acid.
Cyanobenzoylacetic acid methyl ester.
Quininic acid.
2-Methylindole-3-acetic acid.
Citraconanilic acid.
Indoxylic acid ethyl ester.
2-Acetylamino-p-phthalic acid4-mono methyl ester.
N-Acetylmethylamino-p-phthalic acid.
Acetylphenylglycine-o-carboxylic acid.
Benzoylamino-Buccinic acid.
Anilinodiacetic-o-carboxylic acid.
2,3-Dimethyl-l-pheiiyl pyrazolone.
3,4 " -1- " "
Benzylidene di-thioglycollic acid.
Ethylquinolinium tri-iodide.
4-MethyH-phenyl-3-ethoxy urazole.
a-Acetylanilino-propionic acid.
Acetyl-o-tolyl amino-acetic acid.
«
-P-
n
it
tl
It
2-Methylbenzoyl-amino-propionic acid.
A ti it 11 tl
o-Tolylsuccinamic acid,
p-
o-TolylimincMiiacetic acid.
~_ tl II tl
P-
Cytisine.
Iminobenzoic acid iso-butyl ester.
a-o-Toluidinobutyric acid.
a-o-Toliiidino-i«o-butyric acid.
/5-0- " " " "
a-p-Toluidinobutyric acid.
a-p-Toluidino-oso-butyric acid.
/3-p- " " « "
a-Nitro-iso-valeric aldehyde phenylhydrazone.
/3-
((
tl
It
tt
It
FORMULA INDEX
876
CuHmOjN,
CuHitQjN
CuHwOsNb
CiiH«NCl
CuHwON
Pilocarpine.
o-Trimethyl-aminobenzoic acid methyl ester.
V. (t II U it It
P-
Antipeptone j3.
Triethyl-tso-amyl ammonium chloride.
Triethyl-tso-amyl ammonium hydroxide.
11 IV.
C11H8QSN2S a-Naphthalene sulphonic acid cyanoamide.
Q tt tt tt tt
CuHioOsNsBr l-p-Bromophenyl-5-hydroxy-l,2,3-triazolecarboxy-
lic acid ethyl ester.
CuHuOiNK Camphor quinone potassium cyanide derivative.
CuHit04NS p«eiido-Cumenesulphone-aminoacetic acid.
m-Xylenesulphone-aminopropionic acid.
CiiH
10
Diphenyl.
12 I.
12 n.
dsHeOis
Mellitic acid.
CuHtN
Carbazole.
CuHtNi
Aminophenazine.
CsHioNi
Azobenzene.
CaHuN
Diphenyl amine.
CuHuN,
Aminoazobenzene.
CuHisOk
Phenyldihydro-resorcinol.
C]sHi204
Benzylglutaconic acid.
7-Methylene-7-phenylpyrotartaric acid.
7-Methyl-7-phenylitaconic acid.
7-Methyl-7-phenyl-i«o-itaconic acid.
CisHisOi
Benzylethenyltricarboxylic acid.
CuH]208
Diacetyl-diketo-hexamethylene-dicarboxylic acid.
Dihydroxy-quinonedicarboxylic acid diethyl ester.
CuHuN,
Benzidine.
CuHmQs
/5-Phenyl-7-acetylbut3nic acid.
CUH14O4
Ethylbenzylmalonic acid.
p-«ym.-Methylbenzyl8uccinic acid.
meso-^ym.-Methylbenzylsuccinic acid.
CuHuOb
Hemipinic acid 1-mono ethyl ester.
tt tt 0 " *' **
CisHitQt
Benzoic acid amyl ester.
876
FORMULA INDEX
CiaHwQs
CuHisOi
CuHijN
CuH2oOk
C]sH2o04
CisHsoQs
C]2H2o07
CuHaOu
a-wa-Propyl-/3-phenyl-/3-hydroxy-propionic acid.
Camphorcarboxylic acid methyl ester.
Dipropyl-aniline.
CitroDellideneacetic acid.
l--Mo-Camphoric acid mono o-ethyl ester.
a7-Di-wo-propyl-tricarballylic acid; m. p. 173®.
a7. " " " " m. p. 156^
Citric acid triethyl ester.
ci«-«|/m.-Di-i8o-butyl-6uccimc acid.
tranasym.' " " "
Sebacic acid mono ethyl ester.
TetraethylHsuccinic acid.
Lactose.
Maltose.
Saccharose.
<(
CisHsftN
1-Ethylmenthyl amine.
CisHstN
Tri-i«o-butyl amine.
12 m.
CisHsOuNt
Hexanitro-diphenyl amine.
C1SH8O4NS
3,2'-Dipyridyl-2,3'-dicarboxylic acid.
C12H9Q1N
3-Phenylpyridinecarboxylic acid. (Bz-2).
CuH.N,S
Thionine.
CuHioONj
Azooxybenzene.
p-Oxyazobenzene.
C12H10Q1N2
p-Azophenol.
CmHuON
Acetnaphthalide.
CuHuOI
Diphenyl iodonium hydroxide.
CiiHuOjN
a-Naphthylamino-acetic acid.
a a « a
Dimethyl-fumaranilic acid.
CttHuOlN
Methylcitraconanilic acid.
CuHuQsNs
l-p-Tolyl-&-hydroxy-l,2,3-triazole-4-carboxylic
acid ethyl ester.
CuHuObN
Benzoylamino-succinic acid a-mono methyl ester
ti It t( a 11 (( tt
C12H14ON2
9 ~
3-Methyl-l-phenyl-5-ethoxy-p3nrazole.
3,4,4-Trimethyl-l-phenylpyrazolone (5).
CisHuOsBr
d-Phenylbromoacetic acid iso-butyl ester.
CttHuOiN
a-Acetylanilinobutyric acid.
/3-Aoetylanilino-wro-butyric acid.
a-Acetyl-o-toluidinopropionic acid.
a-
ti
-P-
((
ft
FORMULA INDEX
877
CitU»04N
Cotarnine.
CitHuOiNi
l-Phenyl-3,5-diethoxy urasole.
CmHitON
Iminobenzoic acid iso-amyl ester.
CiiHnON
Triethyl-phenyl ammonium hydroxide.
CiiHssNI
Tetrapropyl ammonium iodide.
CmHmON
Tetrapropyl ammonium hydroxide.
12 IV.
CttH70NjBn
4-Hydroxy-2,4,6-tribromo-azobenzene.
CuHsONiBi^
4-Hydroxy-3,5-dibromo-azobenzene.
GuHioOkNtS
Azobenzene-p-8ulphonic acid.
CbHu04NiSi
Di-benzenesulphonic hydrazide.
CiaHuOiNS
Dimethyl-2-naphthylamine-8-8ulphomc aci(
IS n.
CuHgO
Fluorenone.
CuHtN
Acridine.
CuHjoO
Benzophenone.
CuHioOi
Difurfural-acetone.
o-Hydroxy-benzoic acid phenyl ester.
CuHioCli
Diphenyl-dichloro-methane.
CuHuBr
Diphenyl-bromomethane.
CuHiiOi
Mesitylenediglyoxylic acid.
CuHuN
Methyldiphenyl amine.
CiaHit04
Dimethyl-benzylsuccinic acid.
paro-Ethylbenzylsuccinic acid.
me8(h
Methylbenzylglutaric acid.
Methylene di-hydroresorcinol.
CuHuOb
Hemipinic acid 1-mono propyl ester.
t( (t o " " <'
CuHisOt
Salicin.
CuHsoOs
Diethyl-pentanetetracarboxylic acid.
Cl,H,404
2,6-Dipropyl-pimelic acid.
2,6-Di-t«o-propyl-pimelic acid.
TetraethylHsuccinic acid mono methyl ester
IS m.
Ci,H,04N
a-Phenylp3nidine-dicarboxylic acid.
a It tt tt
Benzanilide.
CuHuON
Benzophenone oxime.
878
FORMULA INDEX
CwHuOjN
CuHuNsS
CwHuON
CuHuOjNb
CuHmQbNq
CuHwOftN
CuHwOftNa
CwHieNIs
CuHitON
CuHnOiN
CuHwQiN
Phenyldihydro-resorcylic acid nitrile.
Thiocarbanilide.
Imino-/3-naphthoic acid ethyl ester.
2-Amiiio-4-mtr(>-diphenyl-methyl amine.
Cotamine cyanide.
Acetylphenylglycine-o-carboxylio add eso mono
ethyl ester.
Acetylphenylglycine-o-carboxylic acid exo mono
ethyl ester.
a^Phenylhydroxy-diazomalonic acid diethyl ester.
Butylquinolinium tri-iodide.
wo- " "
Trimethyl-<i-naphthyl ammonium hydroxide.
" -fl- ** " '*
a-Acetyl-o-tolnidinobutyric acid.
/3- " -o-toluidino-iso-butyric acid.
a- " -p-toluidinobutyric acid.
a- " -p-toluidina-i80-butyric acid.
/3- « -p- " " "
Dimethyl-dimethylamino-methylcarbinol bensoate.
13 IV.
CuHuOiNS Benzene sulphonic add bensoylamide.
14 L
C14H10
Anthracene.
Phenanthrene.
14 n.
C14H8QJ
Anthraquinone.
Cl4H80*
Fluorenone-5-carboxylic acid.
C14H804
Alizarin.
C14U808
Purpurin.
CmHbO*
Quinalizarin.
Ci4H«07
1,2,4,5,8-Pentahydroxy-anthraquinone.
CmHioQi
Benzil.
CmHioQj
Benzoic acid anhydride.
o-Benzoylbenzoic acid.
Diphenylene-glycollic acid.
C14H10O4
Benzoyl peroxide.
Diphenic acid.
C14H10O9
a-Digallic acid.
FORMULA INDEX
879
C14H10O9
Ci4HuN
Ci4HisOk
CuHisOi
CuHuO*
Ci4HuNb
CmHwOs
C14HMO4
Tannic acid.
Methylacridine.
Benzoin.
Benzilic acid.
Tannic acid.
Dimethyl-aminoazobenzene.
Benzyl-4so-butenyltricarboxylic acid.
norm.-Dodecane-dicarboxylic acid.
C14H10Q1S
CmHuOjN
CmHuOiN
CmHbOjNj
Ci4HuNI
Ci4Hi,0jN
Ci4HwQ8N
C14HWO4N
C14H16O4P
Ci4Hib07N
Ci4Hi70|N
CiiHnQiN
C14H21O4N
14 m.
Phenanthrene-3H3ulphonic acid.
Dibenzamide.
Phthalanilic acid.
/3-Benzil dioxime.
Methylacridinium iodide.
Methylphenyldihydro-resorcylic acid nitrile.
Acetyl-<i-naphthylamino-acetic acid.
a-Naphthylimino-diacetic acid.
Di(hydroxybenzyl) hypophosphoric acid.
o-Nitrobenzoyl-malonic acid diethyl ester.
Oxy-t«o-butyryl-/3-anilino-ifio-butyric anhydride.
Methylethyl-dimethylamino-methyl carbinol ben-
zoate.
Dihydro-collidinedicarboxylic acid diethyl ester.
14 IV.
C14H160IN8S
p-Dimethyl-aminoazobenzene sulphonic aci<
16 n.
CijHttOe
l,3-Difurfural-cyclo-2-pentanone.
CisHuQs
Benzylcresotinic acid.
CisHiftNs
Acridine Yellow.
C15H16O4
Phenyldihydro-resorcylic acid ethyl ester.
C15H20O1
/3-Phenyl-7-trimethylacetyl-but3nic acid.
C15H22O8
Dicarboxyl-glutaconic acid tetraethyl ester.
Ci6H«0.
Butyric acid glyceryl ester.
CisHmN,
Sparteine.
C15H28O4
Di-ifio-butyl-pimelic acid.
CnHssN
Tri<so-amyl amine.
880
FORMULA INDEX
CiftHioOioNj
C16HWO4N
CiftHuOBN
CwHuOfiN,
CuHuOjN,
CuHxgOsN
CiftHsiOsAl
CisHiiOeFe
C15H22OSN
16 m.
Bis-nitrophenoxy-malonic acid.
Phenyllutidinedicarboxylic acid.
Pjrropapaverimc acid.
Pyropapaverinic acid oxime.
p-Dimethyl-aminoazobenzene-o-carboxylic acid.
j8-0xy-i«o-butyryl-o-toluidino-wo-butyric anhydride.
/3- " " -p-
((
(I
n
tt
Aluminum acetylacetone.
Ferric acetylacetone.
Emetine.
CieHuOs
CuHmOi
C16H14O4
CieHuOs
CwHibNb
CieHjjQs
CieHoOj
CieHwO
CWH12O2N2
C16H13O7N
Ci6Hi404N2
C16H1407N2
CieHiTON,
CieHnOsN
C16H19O4N
CieHaiOjN
Ci«H220i3N4
16 n.
Fluorenone-5-carboxylic acid ethyl ester.
Diphenyl-crotonic acid.
jSy-Diphenyl-vinylacetic acid.
fiym.-Diphenyl-BUccinic acid.
/3-(para)Diphenyl-8UCcinic acid.
Haematoxylin.
Diethyl-amino-azobenzene.
Camphorcarboxylic acid amyl ester.
Palmitic acid.
Cetyl alcohol.
16 m.
Indigo White.
Papaverinic acid.
Diamino-stilbene dicarboxylic acid.
Papaverinic acid oxime.
p-Acetophenone-azo-dimethyl-aniline.
Acetyl-^-naphthylamino-wo-butyric acid.
Benzoylecgonine.
Homatropine.
Tetraaspartic acid.
CieHuOeNjS
C16H12O4N2S
CieHwOjNSa
C16H14O4S2C0
CieHigNsClS
CwHibONsS
16 IV.
p-Nitrobenzene-azo-a-naphthol sulphonic acid.
p-Benzene sulphonic acid azo-/3-naphthol.
Phenyl-/3-naphthylamine trisulphonic acid.
Cobaltophenylthioacetic acid.
Tetramethyl-thionine chloride.
Tetramethyl-thionine hydroxide.
FORMULA INDEX
881
Ci7H]2Qb
C17H140
C17H1408
C17H14C11
C17H1804
Ci7H,7N,
CnHigOio
C17H21N8
17 n.
Phenylindone-acetic acid.
Dibenzal-acetone.
Dibenzoyl-acetone.
Dicinnamenyl-dichloro-methane.
Dibenzyl-malomc acid.
Diphenyl-glutaric acid.
Anilopyrine.
Carminic acid.
Auramine.
17 m.
C]7Hi(07N Papaverinic acid /3-mono methyl ester.
C17H17O4N
C17H19O8N
Ci7HtoON2
C17H20NCI
C17HJ1ON
Ci7Hn04N
Ci7H22NBr
Ci7H»Q8N
C17HJ7O2N
tt
" y "
II
II
Phenyllutidinedicarboxylic acid mono ethyl ester.
Morphine.
Tetramethyl-diamino-benzophenone.
a-Methylallylphenylbenzyl ammonium chloride.
a-Methylallylphenylbenzyl ammonium hydroxide.
l-Cocaine.
((
r-
Methylpropylphenylbenzyl ammonium bromide.
Atropine.
Hyoscyamine.
Methyl-t«o-amyl-dimethylamino-methyl carbinol
benzoate.
18 n.
CigHioQs
a22o-Chrysoketonecarboxylic acid.
Ci8Hia04
l-Phenyl-2,3-naphthalenedicarboxylic acid
CisUmQi
Benzalpiperonal acetone.
Phenylindone-acetic acid methyl ester.
CigHuOg
Dibenzoyl-tartaric acid.
C18H14N4
«ym.-Pheno8afranine.
asym.- "
C18H15N
Triphenyl amine.
C18H16P
Triphenyl phosphine.
Ci8HibAs
Triphenyl arsine.
Ci8Hi6Sb
Triphenyl stibine.
Ci8Hi60s
4-Methoxy-dibenzal-acetone.
C18H16O4
7-Benzylidene-7-phenylpyrotartaric acid.
882
FORMULA INDEX
CisHwO*
a-Truxillic acid.
CigHisOio
7-
Saponin.
CisH«N,
2,&-Benzyliminopyrine.
CigHsoOr
Azelaic acid anhydride.
CisHttOie
Raffinose.
CisHstOs
Oleic acid.
CisHwOj
Stearic acid.
18 m.
CigHi6N4Cl
si/m.-Phenosafranine chloride.
aaym,' " "
CisHieONj
Meldola Blue.
Ci8H,«ON4
Phenosafranine.
CiaHaONB
p-Acetophenone-azo-diethyl-aniline.
CisHnOiN
Methylphenyl-dimethylaTnino-methyl carbinol
benzoate.
CisHnOsN
Codeine.
CigHaON4
p-Acetophenone-azo-diethyl-aniline oxime.
Ci8Ha04N4
Phenylglucosazone.
Ci8Ha04N
Methylinorphinium hydroxide.
18 IV.
CisHuNsClBr 3-Chloro-N-phenylphenazonium bromide,
CisHttQiNCl Methylmorphinium chloride.
19 I.
CnHis
Triphenyl-methyl.
Ci»Hm
Triphenyl-methane.
19 n.
C19H14O6
Dipiperonal acetone.
C19H16CI
Triphenyl-chloromethane.
CiftHisBr
Triphenyl-bromomethane.
C19H18I
Triphenyl-iodomethane.
CitfHieO
l,3-Dibenzal-cyclo-2-pentanone.
Triphenyl carbinol.
Ci^HigOi
2,2'-Dimethoxy-dibenza1 acetone.
3,3'- " " "
4 4'. ti it a
Ci»Hi9N8
Tri-p-aminotriphenyl-methane.
FORMULA INDEX
888
CuHssOi
Abietic acid.
CuHwOit
Saponin.
CitHiiOi
Cetylmalonic acid.
19 m.
CitHwON,
Diamino-triphenyl carbinol.
C1.H18OIP
Methyltriphenyl phoephonium chloride. '
CifHisIP
Methyltriphenyl phosphonium iodide.
Ci,Hi,ONi
p-Triamino-triphenyl carbinol.
Ci,H„OP
Methyltriphenyl phosphonium hydroxide.
Ci»HaONt
Cinchonidine.
Cinchonine.
Ci.Hj«ON,
Cinchonamine.
20 n.
CioH«Ot
Coerulein.
CioHioOt
Coerulein.
CwHioOr
Gallein.
CtoHuOj
Fluorescein.
CtoUiiOi
Gallein.
CmUmOs
o^^o-Chrysoketonecarboxylic acid ethyl ester.
CmHmO*
Phenolphthalein.
CSioHuOt
Benzalpiperonal cyclopentanone.
tao-Benzalpiperonal cyclopentanone.
Rosolic acid.
CioH»N«
NyN'-Diphenyl-endanilodihydro triazde.
CwHitOi
Diphenyl-p-anisyl carbinol.
4-Methoxy-dibenzal-cyclopentanone.
CioHigN,
•OCT"
Phenyl-p-tolylbenzenylamidine.
CmHisN4
Hydrocyan-p-rosaniline.
Cm]^N
Diamyl-j3-naphthyl amine.
CwHmOi
Abietic acid.
20 m.
CwHiiOtCU
Tetrachloro-gallein.
CsoH80(Br4
Tetrabromo-fluorescein.
CtoHsOrClt
Dichloro-gallein.
CfoHgOrCU
Tetrachloro-gallein.
CsoHio04Br4
Tetrabromo-phenolphthalein.
CsoHioOrClf
Dichloro-gallein.
CwHmQsN,
Rhodamine.
884 FORMULA INDEX
C2oHi70N N-Methyl-phenyldihydro-acridol.
Methyl-phenyl-acridinium hydroxide.
C20H17ONS p-Acetophenone-azo-phenylaniline.
C20H18ON2 1 ,2-Diphenyl-3-benzyl-hydroxy-ainidine.
1,2- " -3-p-tolyl- "
C20H20ON2 Methylquinolinium oxide.
C20H20CIP Ethyltriphenyl phosphonium chloride.
C20H21ON8 Rosaniline.
C20H21OP Ethyltriphenyl phosphonium hydroxide.
C20H21O4N Papaverine.
C20H22O10CIS 3,6^Dichloro-quinonedimaloniG acid tetra ethyl
ester.
C20H24O2N2 Quinidine.
Quinine.
QoHotOuN Amygdalin.
20 IV.
C20H14O4N2S Iy4-Naphthalene sulphonic acid azo-/3-naphthol.
C20H14O7N2S2 See Crystal Ponceau.
20 V.
C2oH]207N2S2Na2 Crystal Ponceau.
21 n.
C21H16O5 Dipiperonal-cyclopentanone.
C21H18O Dicinnamenyl-vinyl-ketone.
C21H20Q8 l,3-Dimethoxy-dibenzal-cyclo-2-pentanone.
Phenyl-di-p-anisyl carbinol.
C21H21N Tribenzyl amine.
C21H22O8 2y2'-Bis-ethylsalicylal-acetone.
C21H22O5 Bis-methylvanillal acetone.
C21H24O4 2,6-Dibenzyl-pimelic acid.
C21H24O10 Phloridzin.
21 m.
C21H19O4N8 Pyropapaverinic acid phenylhydrazone.
C2iHi9N4l Methylnitronium iodide. .
C21H21O6N Hydrastine.
C21H22O2N2 Strychnine.
C21H22CIP Propyltriphenyl phosphonium chloride.
C21H28OP Propyltriphenyl phosphonium hydroxide.
C21H84O9N6 Pepsinfibrinpeptone a.
FORMULA INDEX
886
CaHuNi
CisHsiCl
CisHtiBr
CttHttO
C|sH2s04
CaHttOu
22 n.
Roeinduline.
Tri-p-tolyl chloromethane.
Tri-p-tolyl bromomethane.
Tri-p-tolyl carbinol.
Tri-o-anisyl carbinol.
ti
it
-m-
-P-
((
<(
((
t(
OyO,p-Trianisyl carbinol.
Carminic acid.
C»Hi40N2
CbHssOjN
C»H8804N2
22 m.
Rosindone.
Papaverinic acid phenylhydrazone.
Narcotine.
Gelsemine.
22 IV.
CaHuONsCl &-Chloro-o-N-phenylnaphthophenazonium hydrox-
ide.
CaHsoO
CisHsoOe
CBH24O8
CBH24O6
C2sHs60
28 n.
Dicinnamenyl-cyclopentanone.
3,^Dimethoxy-phenylxanthonium-carboxylic
acid methyl ester.
2,2'-Bis-ethyl8alicylal cyclopentanone.
Bis-methylvaniUal cyclopentanone.
Dicuminal-acetone.
C2SH19O5CI
CBH«04Nt
CnHseClP
CbH«OP
CtiHnOioNT
23 m.
3,6-Dimethoxy-phenylxanthonium-carboxylic acid
methyl ester chloride.
Brucine.
i<o-Amyltriphenyl phosphonium chloride.
i«o-Amyltriphenyl phosphonium hydroxide.
Pepsinglutinpeptone a.
23 IV.
Cs2H«7QsNsCl Ethylstrychninium chloride.
886
FORMULA INDEX
28 V.
CaHseOsNaClBr Bromoethyl strychninium chloride.
CmHmS!
CMHsoNBr
CmHjiON
C14HS8O4NS
QftHssO
QftHaQP
CtftHaOP
CttHaONs
24 n.
Silicon tetraphenyl.
24 m.
IMphenyl-methyl pyridinium bromide.
Triphenyl-methyl pyridinium hydroxide.
Gelsemine.
26 n.
Dicuminal-cyclopentanone.
26 m.
Triphenyl-benzyl phosphonium chloride.
Triphenyl-benzyl phosphonium hydroxide.
Hexamethyl-p-triamino-triphenyl carbinoL
26 IV.
QtHn04N2Cl Ethylbrucinium chloride.
26 V.
Ct6Hso04NsClBr Bromoethyl brucinium chloride.
CmHisON,
CmHssONs
C«H«O.N
26 m.
Phenylphenanthrophenasonium hydroxide.
Triethyl-rosaniline.
Glycocholic acid.
26 IV.
CieHtiOrNtSi Erika B.
26 V.
CieHiANtSiEs Erika B.
27 m.
C17H14ON2 BriUiant Green.
FORMULA INDEX
887
CnHitNs
28 n.
Phenylrosmduliiie.
CttHMCaP
CmHmOP
28 m.
Tetrsbensyl phosphonium chloride.
Tetrabenzyl phosphonium hydroxide.
Cisl^OsNiSi
Ci8H,t04N,C1
28 IV.
See Chrysophemne.
Mo-Amylbrucinium chloride.
28 V.
CM^0sN4StE« ChryBophenine.
29 n.
Ci.H«N,
See at the end of the tables.
29 m.
CtiHssNsI
Gyanine.
30 n.
CtoHioNi
Naphthalene Red.
30 m.
CsoHsaNsI
CmH4oO»Ns
CwHuOiNs
CmHwO*Ni7
CsoH«oOoNi6
Gyanine.
Emetine.
Emetine.
Clupeine.
Scombrine.
82 n.
CbHisOia
CaHttOn
Methacrylio add. (Pcdymerio).
Saponin.
82 m.
CnHaOk»N8
CaHitOaN
Octoaspartic acid.
Veratrine.
888
FORMULA INDEX
82 IV.
CnBuOtJUSt See Ck>iigo Red.
88 m.
CuHtiOtFe Ferribenzoylacetic acid ethyl ester.
CnH4iOitN Aconitine.
84 m.
CmHitOuN Aconitine.
84 IV.
Ct4HtsO(N(St See Benzopurpurine.
84 V.
CmI^0(N«SiE4 Bensopurpurine 4 B.
CMHstOiNtSiNat
((
86 IV.
CsftHseOigNsS Urofeninic acid.
87 IV.
Cs7HiiOioN|S| Helvetia Blue trisulphonic acid.
Spirit Blue
ft
CuHso
88 I.
Hexaphenyl-ethane.
CsfiHsoOs
C»8H4iN,
88 n.
Triphenyl-methyl peroxide.
See Night Blue.
CasHjuCbPa
CasHfiNsCl
88 m.
Ethylenehexaphenyl phosphonium chloride.
Night Blue.
FORMULA INDEX 889
41 n.
C4iHtt026 Tannic acid.
42 n.
C^sHssQs Triphenyl-methyl acetic acid ethyl ester.
42 IV.
C4sH840gNP Lecithin.
48 IV.
CttHsoOaNP Lecithin.
44 IV.
CiiHsoOuNP Lecithin.
67 n.
CsjHuoOe Stearic acid glyceryl ester.
AUTHOR LIST.
The names are arranged alphabetically. Prefixes not beginning with a
ci^ital letter, as de, van and voUf are not oonsidered in the arrangement.
Each article is preceded by a nmnber in boldface type, used as a key nmn-
ber in all references, to that article.
Notes in brackets after the title, refer only to nmnerical data and not to
the text. Thus, [Quoted], shows that such data have been quoted from
some other article; [Same as], shows that such data are the same in another
article, the number of which is given. Occasionally a brief explanation is
given, as Qualitative, Indicators etc.
The name of a person who made measurements described in the article,
follows the date of the journal. When only part of the measurements were made
by such a person, the name is preceded by the sign fH , thus, HH Meas. Smiih,
When an author has published articles in different journals, the journals are
arranged in alphabetical order in two divisions, giving first the more accessi-
ble. Under each journal the articles are arranged chronologically.
Articles enclosed in parenthesis contain no original measurements of the
ioniaation constant or of the electrical conductivity of organic compounds.
AUTHOR LIST.
1. O. AbatL Gai. Chim. Ital. 36, U, 834-837, (1906).
Sopra gli acidi idroftalid. La costante d'affibaiUi delle due nuoTe anidridi.
[Same as 4.]
T-26^ R. O. X aq.-l-2X10-«; }^x aq. is sub.
2. (G. Abati. Gas. Chim. Ital. 36, II, 848-^55, (1906).
Influenza della posizione del legame etilenioo sulla sua elettroaffimt& e sui
caratteri di acidi non saturi aliciclici.) [Same as 6. Quoted.]
8. G. AbAti. Gas. Chim. Ital. 38, 1, 152-161, (1908).
Sopra gli acidi idroftalici. L'acido ^.s diidroftalioo. Discussione sulla
costitusione sua e su quella dell'acido Ai^. [Same as 6.]
T-25.0«. R. O. X aq.=1.02X10-«; Hx aq- is sub.
4. G. Abati. Rend. Accad. Sciens. (Napoli). (3*), 12, 207-210,
(1906).
Sopra gli acidi idroftalici, etc. [Same as 1.]
6. (G. Abati. Rend. Accad. Sciens. (Napoli). (3*), 12, 220-226, (1906).
Influenza della posisione, etc.) [Same as 2.]
6. G. Abati. Rend. Accad. Sciens. ;(Napoli). (3*), 12, 466-473, (1906).
Sopra gli addi idroftalici, etc. [Same as 8.]
7. G. Abati. [M. Solimene.] Gas. Chim. Ital. 38, 11, 577-^587,
(1908).
Sopra gli acidi idroftalici. La velocity di addisione del bromo alle anidri
tetraidroftaliche. [Same as 8. Quote measurements of A. Dom. ]
8. G. Abati. [M. Sdimene.] Rend. Accad. Sciens. (Napoli). (3*), 14,
181-191, (1908).
Sopra gli acidi idroftfdici, etc. [Same as 7.]
G. AbatL [M. Solimene.] Rend. Accad. Sciens. (Napoli). (3*), 14,
181-191, see G. Abati.
C. G. Abbot see A. A. Noyes.
9. (R. Abegg. Zeit. Elektrochem. 10, 185-189, (1904).
Anwendung der physikalischen Chemie auf die organische Chemie.) [Quoted. ]
R. Abegg see 8. Labendzinaki.
" see H. Schlfer.
10. R. Abegg, J. F. Spencer. Zeit. Anorg. Chem. 46, 406-414, (1905).
Zur Kenntnis der Thalliumoxalate.
xaq.=2XlO-«.
11. J. H. Abersoo. Ber. Deutsch. Chem. Ges. 31, 1432-1449, (1898).
Meas. E, Cohen,
Die Aepfelsfture der Crassulaceen. [Same as 18.]
X aq. sub.
12. J. H. Aberson. Verslag. Akad. Amsterdam. 6, 535-537, (1897-1898).
De Isomeric van het Appelsuur. [An abstract of 18. Qualitative.]
892 AUTHOR LIST
18. J. H. Aberaoo. Vcrhand. Akad. Amsterdam. (1. Sectie). Vol. 6, no.
4, 1-42, (1897-1899).
De Iflomerie van't Appelsuur. [Same as 11.]
14. (O. AccolU. Atti Accad. Gioenia. (4), 18, Mem. VI, 1-15, (1905).
Su un metodo per la misura delle picoole variasioni di resistensa negli elet-
troliti e sua applicaadone.) [Xnorganic]
16. S. F. Acree. Am. Chem. Jour. 38, 1-91, (1907). Metu. 0, H.
Shadinger,
On the constitution of phenylurazole. Ill; A contribution to the study of
tautomerism. [Measurements given in 18.]
T-25^
16. S. F. Acree, J. M. Johnson. Am. Chem. Jour. 38, 258-355,
(1907).
Studies in catalysis. [Qualitative.]
17. S. F. Acree, 8. Nlidlinger. Am. Chem. Jour. 38, 489^507, (1907).
On the hydrolysis of amides by acids.
T = 18^
18. S. F. Acree, O. H. Shadinger. Am. Chem. Jour. 39, 124-145, (1908).
[Meaa. Shadinger.?]
On the a£Snity constants and constitution of several urasoles. [See 16.]
T=25^ xu aq. = 1.8-2.3Xl(H.
L. D'Agoatini see G. Carrara*
Meas. A. Aita; see 294, 296.
A. Aita see G. Bnini.
Meas, C. R. AUen; see 902.
C. R. Allen see H. C. Jones.
19. B. T. Allen. Jour. Am. Chem. Soc. 25, 421-444, (1903).
Precipitation and separation by weak organic bases. [Hydrolysis of
salts.]
T-40^
[The Andrews in the following three references is the same man.]
20. L. Andrews. Proc. Iowa Acad. I, Ft. IV, 12-15, (1887-1893).
Some peculiarities of solutions of ferric sulphocyanate.
21. L. W. Andrews, C. Bnde. Zeit. Phys. Chem. 17, 136-144, (1895).
Eine Studie der physikalischen Eigenschaften von Chlorlithiuinldsungen in
Amylalkohol. [Same as 22.]
T=25^
22. L. W. Andrews, C. Bnde. Proc. Iowa Acad. 2, 95-103, (1894).
A study of the physical properties of solutions of lithium chloride in amyl
alcohol. [Same as 21. ]
28. A. AngeU. Gaz. Chim. Ital. 22, II, 1-31, (1892).
Sulle coetanti di affinity di alcuni acidi della serie del pirrolo e dell'indolo.
[Same as 24. Gives all the acids in 26 and also some ketonic acids.]
T =25^ X aq. =0.002-0.003; not sub.
24. A. Angeli. Mem. Accad. Bologna. (5), 2, 455-484, (1891).
Sulle costanti di affinity, etc. [Same as 28.]
26. A. AngeU. Rend. Accad. Lined. (5), 1, 1, 160-169, (1892).
Sulla condudbihtft elettrica di alcuni acidi pirrolcarbonid ed indolcaibonid.
[Given in 28 and 24.]
26. A. AngeU, B. Bimlni. Gaz. Chim. Ital. 26, H, 34r45, (1896).
Sull'azione deU'acido nitroso sopra la canforossima.
AUTHOR LIST 898
27. U. Antony, G. MsjEri. Gas. Chim. Ital. 35, 1, 206-226, (1005).
L'idrogeno solforato liquido oome solvente. [Qualitative. ]
T- -52'.
M. P. Applebey see H. Harttey, N. G. Thomas.
28. R. Apt. Sduift. Naturw. Ver. Schleswig-Holstein. 11, 242-245, (1896-
1898).
Ueber die elektrischen und magnetischen Eigenschaften des Nickeltetra-
carbonyls.
Hg.U.
29. B. H. AichitMad. Jour. Am. Chem. See. 29, 665-683, (1907).
The electrical conductivity of solutions of the alcohols in liquid hydrogen
bromide.
T » —80^. R. O. X of solvent is sub. in a few cases.
SO. £. H. Archibald. Jour. Am. Chem. Soc. 29, 1416-1439, (1907).
The electrical conductivity of solutions of the organic acids in liquid hydrogen
chloride and bromide.
T s —80^ and about —96°. R. O. x solvent sub. in some cases.
81. (B. H. Archibald. Proc. Trans. Nova Scot. 10, 33-48, (1898-1902).
On a test, by the freezing-point method, of the ionization coefficients deter-
mined by the conductivity method for solutions containing potassium and
sodium sulphates.) [Inorganic]
E. H. Archibald see B. D. Steele, D. Mcintosh.
'' " " see J. W. Walker, D. Mcintosh.
82. B. H. Archibald, D. Mcintosh. Proc. Trans. R. Soc. Canada. (2), 10,
Sect. Ill, 43-46, (1904).
The variation of the valency of elements with temperature.
T=-50''to -150^
83. B. H. Archibald, D. Mcintosh. Proc. R. Soc. London. 73, 454-455,
(1904).
On the liquefied hydrides of phosphorus, sulphur, and the halogens, as con-
ducting solvents.
R. O.
84. E. H. Archibald, W. A. Patrick. Chem. News. 100, 150, (1909).
The electrical conductivity of solutions of iodine and of platinum tetraiodide
in ethyl alcohol.
86. (H. B. Armstrong. Proc. R. Soc. London. 40, 268-291, (1886).
Electrolytic conduction in relation to molecular composition, valency and the
nature of chemical change; being an attempt to apply a theory of ''residual
affinity.") [Theoretical, quoted and inorganic]
86. (H. B. Armstrong, and others. Proc. R. Soc. London. A, 81, 80-140,
(1908-1909).
Studies of the processes operative in solutions.)
87. (H. B. Armstrong. Proc. R. Soc. London. A, 81, 80-95, (1908-1909).
Hydrolysis, hydrolation and hydronation as determinants of the properties of
aqueous solutions.) [Inorganic. ]
88. (H. B. Armstrong, D. Crothers. Proc. R. Soc. London. A, 81, 102-112,
(1908-1909).
The influence of salts on hydrolysis and the determination of hydration values.)
[Inorganic. ]
89. (H. B. Armstrong, B. Wheeler. Proc. R. Soc. London. A, 81, 95-102,
(1908-1909).
The relative efficiencies of acids as deduced from their conductivities and
hydrol3rtic activities.) [Inorganic. ]
894 AUTHOR LIST ^
40. (K. Amdt Ber. Deutsch. Chan. Gea. 40, 2037-2940, (1907).
Die dektiolytische Diasosiation geschmolxener Salze.) [Inoiganic]
4L (K. Amdt. Ber. Deutsch. Chem. Ges. 40, 3612-3614, (1907).
Die elektrolytische DiasoBiation geechmolaener Salse.) [Inorganio.]
42. (K. Amdt Zeit. Elektrochem. 13, 809-^12, (1907).
Z&higkeit und LeitfShigkeit.) [Inoiganio.]
48. S. Arrheniiss. Zeit. Phys. Chem. 4, 96-116, (1889).
Ueber die Diaaociationswftnne und den FiinfluBs der Temperatur auf den
Diasodationagrad der Mektrolyte.
T-18**and52^
44. S. Anhenius. Zeit. Phys. Chem. 5, 1-22, (1890). HiMeas. J.
Walker.
Ueber die Gleichgewichtsverh<niBse iwischen Elektrolyten. [Same as 49.]
T=26*and64*. S. U.
46. S. Arxhenius. Zeit. Phys. Chem. 9, 487-^11, (1892).
Ueber die Aendenmg des elektrischen LeitungsvermOgens einer Ldsung durch
Zusatx von kleinen Mengen eines Nichtleiters. [Same as 50.]
T>-25^ for part of the measurements.
46. S. Arrhenitts. Zeit. Phys. Chem. 11, 805-828, (1893).
Die Mektrolyse von Alkalisalzen.
47. (S. Arxhenitts. Zeit. Phys. Chem. 31, 197-220, (1899).
Ueber die Aenderung der St&rke achwacher Sauren durch Saksusata.) [In-
organic]
48. S. Arrheniua. Med. Nobelinst. 1, no. 9, 1-17, (1906-1909).
Ueber die SchUta'sche Kegel bei Reaktionsgeachwindigkeiten. [No data.]
T-14.8^
49. S. Airheniua. Ofver. K. Vet.-Akad. Fdrhand. (Stockhohn). (1889),
619-645.
Ueber die Gleichgewichtsverh<nisae, etc. [Same as 44.]
60. 8. Anfaeniua. Bihang. Svensk. Vet.-Alcad. Hand. Stockhohn. 18, Aid.
1, no. 5, 1-31, (1892-1893).
Ueber die Aenderung dee elektrischen, etc. [Same aa 46.] |
61. (S. Airheniua, T. Madaen. Cv. Danske Vids. Selsk. Forhand. (1904),
269-305.
Tozines et antitoxines. Le poison dipht^rique.)
62. O. Ascfaan. Ann. Chemie. 271, 231-284, (1892). Meas. U. CoUan,
Ueber Hydrobenzo@6&uren.
62a. L. Aaher, T. Karaulow. Biochem. Zeit. 25, 305-327, (1910).
Beitrage zur Physiologie der DrCksen. XV. Mitteilung. Untersuchungen aber
die Besiehungen zwischen physikalisch-chemischen Eigenachaften voa-DrOs-
enproteiden und dem ScheidevermOgen der DrOsen.
T-30*.
68. P. Aakenasy, V. Meyer. Ber. Deutach. Chem. Ges. 26, 1354^1370,
(1893). Meas, W. Oslwald.
Ueber die Jodosoverbindungen.
64. M. Aariel. Dis. Heidelberg. (1900).
Physikalisch-chemische Studien tiber aromatische Sulfins&uren.
T = 18^ 25** and 30^ x aq. sub.
B. Aaton see P. Dutoit
•* " see J. Walker.
66. (A. H. W. Aten. Zeit. Phys. Chem. 66, 641-671, (1909).
Elektrizit&tsleitung in Mischungen von Metallen und ihi«n Salzen.)
AUTHOR LIST 895
66. (B. y. Aubel. Phys. Zeit. 4, 551-552, (1902-1903).
Bemerkungen zu den Franz Streintzschen Untersuchungen fiber elektrische
Leitfahi^eit komprimierter Pulver.) [Inorganic. ]
57. A. Auerbachy H. Friedentlial. Arch. Anat. Physiol. — Physiol. Abtheil.
(1903), 397-411.
Ueber die Reaction des menschlichen Hames unter verschiedenen EmlLhrung»-
bedingungen und ihre quantitative Beetimmung. [Physiological. Indicators. ]
68. F. Auerbach. Ber. Deutsch. Chem. Ges. 38, 2833-2836, (1905).
Zur Kenntniss dee Formaldehyds und der Formiatbildung. [Criticizes 628.
See also 629.]
69. S. M. Attld, A. Hantzsch. Ber. Deutsch. Chem. Ges. 38, 2677-2685,
(1905).
Ueber Verbindungen von Ketonen und Aldehyden mit Quecksilberoxyd.
T = 18^
60. K. Auwers. Ann. Chemie. 285, 241-282, (1895). Meas. [T.]
Paid.
Ueber die IsomerieverhSltnisse der Trimethylbemsteinsfture und der symme-
trischen a,a-Dimethylglutars&ure.
61. K. Auwers. Ann. Chemie. 292, 132-243, (1896). Meaa. Pfajf,
Studien in der Gruppe der Bemsteinsauren und Glutarsauren.
62. K. Auwers. Ann. Chemie. 298, 147-181, (1897). Meaa. P. Walden,
Untersuchungen Uber substituirte Bemsteinsauren.
68. K. Auwers. Ber. Deutsch. Chem. Ges. 28, 263-270, (1895). Meaa.
IT,] Paul.
Ueber Trimethylbemsteins&ure und symmetrische a,a-DimethylglutarB&iu'en.
64. K. Auwersy G. v. Campenhausen. Ber. Deutsch. Chem. Ges. 29,
1543-1549, (1896). Meaa, Pfaff.
Ueber Oxytrimethylbemsteins&ure. [Same as 826.]
66. K. Auwers, L. L. Jackson. Ber. Deutsch. Chem. Ges. 23, 1599-1617,
(1890). Meaa. R, Bader.
Ueber Structurbestimmung aliphatischer S&uren und die sogenannte *' dynar-
mische Isomeric."
66. K. Auwers, A. Jacob. Ber. Deutsch. Chem. Ges. 27, 1114-1132, (1894).
Meaa, H, Wialicenua.
Ueber stereoisomere Butantetracarbons&uren. [The acids only are given in
868 with tables of /u. Sodium salts also are given here.]
67. K. Auwers, £. Ktfbner, F. v. Meyenbuig. Ber. Deutsch. Chem. Ges.
24, 2887-2901, (1891). Meaa. P. Walden,
Synthesen mehrbasischer Fetts&uren.
68. K. Auwers, A. Oswald. Ann. Chemie. 285, 283-309, (1895). Meaa,
IT.] Paid,
Ueber Trimethylbemsteinsauren verschiedener Herkunft. I. Trimethylbem-
steins&ure aus a-Cyanpropionsaureester und a-Bromisobuttersaureester.
T=25^
69. K. Auwers, J. F. Thorpe. Ann. Chemie. 285, 310-339, (1895). Meaa,
[T,] Paul.
Ueber symmetrische aa-Dimethylglutars&uren.
T-25^
896 AUTHOR LIST
B.
70. R. Bader. Zeit. Phys. Chem. 6, 289-318, (1890).
Ueber die Affinitatsgrdssen organischer S&uren iind ihre Beziehung zur
Zusammensetzung iind Konstitution derselben.
T=25''.
Meas, R. Bader; see 65, 71, 1373.
71. A. Baeyer. Ann. Chemie. 266, 169-202, (1891). Meat. R. Bader and
H. G. Bethmann.
Ueber die HydronaphtoSeauren. [Probably the same measurements as in 70
and 175. Only k is given here, not A. ]
72. A. Baeyer. Ann. Chemie. 269, 145-206, (1892). Meaa, W, Ostwald.
Ueber die Reductionsproducte der Phtalsaure.
73. A. Baeyer. Ber. Deutsch. Chem. Ges. 42, 2624r-2633, (1909).
Dibenzalaceton imd Triphenybnethan.
74. A. Baeyer, V. Villiger. Ber. Deutsch. Chem. Ges. 35, 3013-^3033, (1902).
Dibenzalaceton imd Triphenybnethan.
76. F. Baker. Jom-. Chem. Soc. 91, 1490-1500, (1907).
The structm« of carbonium salts.
76. L. Balbiano. Caz. Chim. Ital. 29, II, 490-592, (1899). Meas. MorUe-
martini.
Ricerche analitiche sull'acido canforico.
77. £. Bamberger. Ber. Deutsch. Chem. Ges. 27, 359-379, (1894). Meas.
HdypUi.
Ueber die Diazobenzolsaure.
78. £. Bamberger. Ber. Deutsch. Chem. Ges. 31, 2626-2635, (1898).
Meas. O. Schmidt, 0. Weber.
Zur Kenntniss der sogenannten ** Nitroazoparaffine." [See 82 for measure-
ments. ]
79. £. Bamberger. Ber. Deutsch. Chem. Ges. 35, 3697-3710, (1902).
Meas. A. Holleman.
Ueber die Einwirkimg von Salzsaure auf m-Tolylhydroxylamin.
80. £. Bamberger, B. Berl6. Ann. Chemie. 273, 303-342, (1893). Meas.
Zengelis.
Die a-st&idige Methylgnippe der Benzimidazole und das Verhalten der
letzteren bei der Oxydation.
81. £. Bamberger, W. Lodter. Ann. Chemie. 288, 74-133, (1895). Meas.
[G.\ Bredig.
Studien fiber alicyclische Naphtalinderivate.
82. £. Bamberger, O. Schmidt. Ber. Deutsch. Chem. Ges. 34, 574-594,
(1901). Meas. O. Schmidt.
Ueber das Phenylhydrazon des Nitroformaldehyds. [Same as 1593. ]
T«0*»and25^
83. - (B. Bamberger, O. Schmidt. Ber. Deutsch. Chem. Ges. 34, 2001-2017,
(1901).
Ueber isomere Hydrazone.) [Quoted from 82. ]
L. des Bancels see V. Henri.
84. (W. D. Bancroft Zeit. Phys. Chem. 31, 188-196, (1899).
The dilution law.)
85. P. Barbier, P. Sisley. Ann. Chim. Phys. (8)> 13, 96-142, (1908).
Recherches sur les saf ranines. [Same as 86.]
T=24.9'.
AUTHOR LIST 897
86. P. Barbier, P. Sisl^. Bui. Soc. Chim. (3), 33, 119Q-1198, (1905).
Sur les ph^nosafranines sym^trique et dissym^trique. [Same as 85. ]
T=24.9^
87. (P. Barbier, P. Sisley. Bui. Soc. Chim. (3), 35, 1282-1285, (1906).
Nouveau mode de formation des safranines dis83rm6triques.}
88. J. T. Barker. Chem. News. 97, 37-40, (1908).
A physico-chemical study of the complex copper-glycocoll sulphates.
T = 13•andl7^
89. J. T. Barker. Chem. News. 97, 51-54, (1908).
A physico-chemical study of the complex copper-glycocoU sulphates.
T=25^ R. O. xaq.=2Xl0-«; sub.
90. (P. S. Barlow. Phil. Mag. (6), 11, 595-604, (1906).
The osmotic pressures of alcoholic solutions.) [Inorganic. ]
91. (F. Barmwater. Zeit. Phys. Chem. 28, 115-144, (1899).
Ueber das Wesen des osmotischen Dnicks.) [Quoted. ]
92. (F. Barmwater. Zeit. Phys. Chem. 28, 424-430, (1899).
Ueber das Leitvermogen der Gemische von Elektrolyten.) [Theoretical and
inorganic. ]
98. F. Barmwater. Zeit. Phys. Chem. 45, 557-565, (1903).
Ueber das Leitvermdgen der Gemische von Elektrolyten.
T=18^ R. O. Xi8 aq.« 1.5-2 XlO-«; sub.
94. F. Barmwater. Zeit. Phys. Chem. 56, 225-235, (1906).
Ueber das Leitverm6gen der Gemische von Elektrolyten.
X aq. = 1 .5-2 X 10-«; sub. [T probably 18**; see 98. ]
96. (H. T. Barnes. Proc. Trans. R. Soc. Canada. (2), 6, Sect. Ill, 75-76,
(1900).
Note on the effect of a change in dissociation on the density-curve of a hy-
drated electrolyte in aqueous solutions of different concentration.) [Inorganic]
96. (J. Barnes. Proc. Trans. R. Soc. Canada. (2), 6, Sect. Ill, 37-54,
(1900).
On the depression of the freezing-point in solutions containing hydrochloric
and sulphuric acids.) [Theoretical and inorganic. ]
97. (J. Barnes. Proc. Trans. Nova Scot. 10, 129-138, (1898-1902).
On the calculation of the conductivity of aqueous solutions containing hydro-
chloric and sulphuric acids.) [Inorganic]
98. (J. Barnes. Proc Trans. Nova Scot. 10, 139-161, a898-1902).
On the depression of the freezing-point by mixtures of electrolytes.) [Inor-
ganic ]
98a. J. O. W. Barratt Zeit. Elektrochem. 16, 130-132, (1910).
Ueber die Konstanten der ersten und zweiten DiBSOziation des Chinins.
T = 16*'to 18^ xaq.=9XlO-«.
Meas, Barth; see 668.
A. Barth see A. Hantzsch.
Meas, C. Barth; see 729.
99. (A. BartoU. Gaz. Chun. Ital. 13, 27-34, (1883).
Sulla costituzione degli elettroliti.) [Theoretical and general.]
100. A. BartoU. Gaz. Chim. Ital. 14, 516-522, (1884).
La conducibilit^ elettrica delle combinazioni del carbonio. [Same as 116 and
126.]
101. A. BartoU. Gaz. Chim. Ital. 14, 522-526, (1884).
Di un singolare fenomeno elettrico osservato neU'alcool cetilioo solido. [Same
as 116. See 110.]
898 AUTHOR LIST
102. A. Bartoli. Gaz. Chim. Ital. 15, 392-397, (1885).
La oonduoibilitli dettrica delle oombinazioni del carbonio ed in ispeeie sulla
oonducibilitA delle ammidi, dei nitrodeiivati eoc. [Same as 117 and 127].
108. A. BartoU. Gas. Chim. Ital. 15, 397-^99, (1885).
Sulla dipendenza della oonducibilitA elettrica della dietilammina dalla tem-
peratiira. [Same as 119 and 180. Qualitatiye. ]
T--10*'to +80**.
104. A. BartoU. Gaz. Chim. Ital. 15, 40(M03, (1885).
La oonducibilit^ elettrica di alcuni oompoeti organici alio stato solido. [Same
as 118 and 129.]
106. A. BartoU. Gas. Chim. Ital. 15, 41(M16, (1885).
La conducibiUt^ elettrica deUe mescolanse di oombinazioni organiche. [Same
as 120 and 128.]
T=-40*»tol20*.
106. A. BartoU. Gaz. Chim. Ital. 24, II, 156-172, (1894).
Sulla dipendenza della oonducibiUt^ elettrica degU eteri oompoeti dalla tem-
peratura. [Same as 112 and 126. ]
T = 13*»to210^
107. A. BartoU. Gaz, Chim. Ital. 25, I, 205-207, (1895).
Sulla oonduttivit^ elettrica di alcuni oomposti in prossimit^ della tempera-
tura critica. [Same as 113. QuaUtative.]
106. A. BartoU. Atti Accad. Gioenia. (4), 2, 45-80, (1889-1890).
Sulla oonducibiUt^ elettrica di alcuni mescugU naturaU di compoeti organici
ed in partioolare suUa conducibiUt^ elettrica degli olii, dei grassi, deUe cere,
delle essenze, dei balsami e delle resine. [Same as 124. ]
T=0*'to300^
109. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 4, 4-8, (1889).
Sulla conducibilitA elettrica, etc. [An abstract of 108. QuaUtative.]
110. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 23-24, 12-13, (1892).
Abstracted in Beibl. Ann. Phys. 17, 1085, (1893).
Spiegazione delle anomaUe che presenta la conducibiUtA elettrica deU'etaUo.
T=0*»tol04^
111. A. BartoU. Bol. Accad. Gioenia. (N. S.), Fasc. 26-28, 4m5, (1892).
La conducibilit^ elettrica di alcuni Uquidi molto viscosi, dopo raffreddamenti
rapidi, e dopo lenti raffreddamenti. [Qualitative. ]
112. A. BartoU. Rend. R. 1st. Lombardo. (2), 27, 490-503, (1894).
Sulla dipendenza della conducibiUt^, etc. [Same as 106 and 126.]
118. A. BartoU. Rend. R. 1st. Lombardo. (2), 28, 246-248, (1895).
Sulla conduttivit^ elettrica, etc. [Same as 107.]
114. A. BartoU. Nuovo Cim. (3), 15, 203-210, (1884).
Relazione fra la conducibiUt^ elettrica e la oomposizione dei caiboni di varie
specie.
115. A. BartoU. Nuovo Cim. (3), 16, 64-69, (1884).
La conducibilit^ elettrica, etc. [Same as 100 and 126.]
116. A. BartoU. Nuovo Cim. (3), 16, 70-74, (1884).
Sopra un singolare fenomeno osservato nel misurare la oonducibiUt& elettrica
deU'etalio. [Same as 101. See 110.]
117. A. BartoU. Nuovo Cim. (3), 19, 43-48, (1886).
La oonducibiUtA elettrica delle combinazioni, etc. [Same as 102 and 127*]
118. A. BartoU. Nuovo Cim. (3), 19, 48-52, (1886).
La conducibiUtjt di alcuni, etc. [Same as 104 and 129.]
119. A. BartoU. Nuovo Cim. (3), 19, 52-54, (1886).
Sulla dipendenza deUa conducibilit^, etc. [Same as 108 and 180.]
AUTHOR LIST 899
180. A. BartoU. Nuovo Cim. (3), 19, 55-61, (1886).
La oonducibililA elettrica delle mesoolaiuie, etc. [Same as 106 and 188.]
121. A. BartoU. Nuovo Cim. (3), 20, 121-125, (1886).
Sulla oonducibililA elettrica delle oombinazioni dd carbonio alio stato liquido,
ed in ispecie su la oonducibilit^ delle oombinasioni dei radicali acidi con gli
alogeni, dei rodanati, delle essenze di senape, dei nitrili, dei solfuri e delle oom-
binazioni organometalliche. [Same as 1S4. Qualitative.]
182. A. BartolL Nuovo Cim. (3), 20, 125-136, (1886).
Sulla dipendenza della conducibilitii elettrica dalla temperatura nelle soluzioni
degli alcoli CnHzn+zO nei liquidi poco conduttori od isolanti. [Qualitative.
Same as 182.]
123. A. BartoU. Nuovo Cim. (3), 20, 136-139, (1886).
La oonducibilit^ elettrica al punto critico. [Same as 138.]
124. A. BartoU. Nuovo Cim. (3), 28, 25-40, (1890).
Sulla conducibilit^ elettrica di alcimi mescugli naturali di composti organid
ed in partioolare sulla conducibilit^ elettrica degli olii, dei graasi, delle cere,
deUe essenze, dei balsame e deUe resine. [Same as 108.]
T»0*»to300^
126. A. BartoU. Nuovo Cim. (3), 36, 57-70, (1894).
Sulla dipendenza della conducibilit^, etc. [Same as 106 and 112.]
126. A. BartoU. Rend. Accad. Linoei. (3), 8, 334-337, (1883-1884).
La condudbilltli elettrica, etc. [Same as 100 and 116.]
127. A. BartoU. Rend. Accad. Lincei. (4), 1, 546-550, (1884-1885).
Sulla oonducibilit^ elettrica deUe combinazioni, etc. [Same as 102 and
117.]
128. A. BartoU. Rend. Accad. Lincei. (4), 1, 550-555, (1884-1885).
La conducibilit^ elettrica delle mescolanze, etc. [Same as 106 and 120.]
129. A. BartoU. Rend. Accad. Lined. (4), 1, 569-572, (1884r'1885).
La conducibilitJl dettrica di alcuni composti, etc. [Same as 104 and 118.]
180. A. BartoU. Rend. Accad. Lined. (4), 1, 572-573, (1884-1885).
Sulla dipendenza della conducibilit^, etc. [Same as 108 and 119. Error in the
title, dimetil for dietil, is corrected in 108. ]
181. A. BartoU. Rend. Accad. Lined. (4),^ 1, 586-^90, (1884-1885).
La oonducibilit^ dettrica deUe resine.
182. A. BartoU. Rend. Accad. Lined. (4), 2, II, 122-129, (1885-1886).
SuUa dipendenza della conducibilit^, etc. [Same as 122.]
188. A. BartoU. Rend. Accad. Lincei. (4), 2, 11, 129-131, (1885-1886).
La condudbiliti elettrica al punto critico. [Same as 128.]
184. A. BartoU. Rend. Accad. Lincei. (4), 2, II, 132-135, (1885-1886).
Sulla oondudbilitA elettrica, etc. [Same as 121.]
186. (A. BartoU, G. Pi^asogU. Gaz. Chim. Ital. 13, 35-37, (1883).
SuU'dettrolid dell'acqua e deUe soluzioni di acido borico.) [Electrolytic]
186. (A. BartoU, G. PapasogfU. Gaz. Chim. Ital. 13, 37-^5, (1883).
Ricerche sulla dettrolisi con elettrodi di carbone delle soluzioni dei composti
binarii e di vari altri composti acidi e salini.) [Electrolytic]
187. (A. BartoU, G. PiqMSOgU. Gaz. Chim. Ital. 13, 281-286, (1883).
Elettrolisi deUe soluzioni di ammoniaca e dd sali ammoniacaU, con elettrodi
di carbone.) [Electrolytic]
188. (A. BartoU, G. Pl^asogU. Gaz. Chim. Ital. 13, 287-293, (1883).
Elettrolisi ddla gUcerina con elettrodi di carbone e di platino.) [Electrolytic]
H. P. Bassett see H. C. Jones.
J. P. Batey see £. Knecht
400 AUTHOR LIST
189. B. Bauer. Zeit. Phys. Chem. 56, 21&-222, (1906).
Ueber die Dissociationskonstanten schwacher S&uren.
T=25^
Meas. Bauer; see 1849.
B. Bauer see P. T. MuUer.
140. (H. Bauer. Jour. Prakt. Chem. (2), 72, 201-210, (1905).
Beitrag zur Natur der Kohlenstoffdoppelbindung.) [Quoted.]
Meas. M. Bauer; see 1720.
141. E. Baur. [Probably same as Bauer]. Ann. Chemie. 296, 95-100,
(1897).
Ueber die Leitf&higkeit des Nitramids.
T=0^ Xoaq. = 1.99XlO-^.
142. A. E. Baur. [Same as E. Baur]. Zeit. Phys. Chem. 18, 183-1 84, (1895).
Bestimmung einiger Leitffihigkeiten. [Corrected in 143.]
T=25^
143. E.Baur. [This is A. E. Baur. ] Zeit. Phys. Chem. 23, 409-416, (1897).
Bestimmung der Affinit&tsgrGssen und Dissooiationsw&rmen einiger Stick-
stoff s&uren. [Given in 146.]
T=0*' to 40^ xjo aq.«2.5XlO-^; sub.
144. £. Baur. Zeit. Elektrochem. 11, 936-938, (1905).
Ueber die Beziehung swischen clektrolytischer Dissociation und Dielektri-
zit&tskonstante.
146. B. Baur. [This is A. E. Baur.] Dis. MOnchen. (1897).
Bestimmungen von Umwandlungspunkten, Affinitatsgrossen, Dissoziations-
w&rmen, etc., auf elektrischem Wege. [Same as 143, with addition of azotet-
razole, acetic acid and nitroamide. ]
T=0**to40^ xaq. sub.
£. Baur see W. Kerp.
146a. W. M. BayUss. Arch. Fisiol. 7, 357-^68, (1909).
The dissociation of salts of weak acids with weak bases.
T = ll*»to40^ R. O.
145b. W. M. BayUss. Jour. Physiol. 36, 221-252, (1907-1908).
' Researches on the nature of enzyme action. I. On the causes of the rise in
electrical conductivity under the action of trypsin.
T = 10*'to40^ R. O.
146. £. Beckmann, [B. Held.] Arch. Pharm. 247, 110-120, (1909).
Beitr&ge zur Beurteilung von Drogen.
T=25^
147. (£. Beckmann, G. Lockemann. Zeit. Phys. Chem. 60, 385-398, (1907).
Ueber Molekulargewichts- und Leitfahigkeitsbestimmungen in Nitrobenzol.)
[Inorganic]
T = 18^
147a. £. Beckmann, P. Waentig. Zeit. Anorg. Chem. 67, 17-61, (1910).
Kryoskopische Bestimmungen bei tiefen Temperaturen (—40^ bis —117°).
T=-51**to -120^
148. H. Becquerel. Compt. Rend. 136, 1173-1176, (1903).
Conductibilit^ et ionisation rdsiduelle de la parafl^e solide, sous Tinfluenoe du
rayonnement du radium.
149. R. Behrend. Zeit. Phys. Chem. 11, 466-191, (1893).
Elektrometrische Analyse.
A. Beisswenger see F. Fichter.
160. I. BeUucci. Gaz. Chim. Ital. 35, I, 343-355, (1905).
Sui composti solfocianici del palladio. [Same as 161. ]
T=25^
AUTHOR LIST 401
151. I. Bellucd. Rend. Accad. lincei. (5), 13, II, 386-^93, (1904).
Sui compoeti, etc. [Same as 150. ]
I. Bellucd see A. MiolatL
J. Bence see A. v. KorftnyL
152. A. BenedicentL Arch. Fisiol. 1, 403-409, (1904).
Sui mutamenti fisico-chimici del sangue nelle variazioni della pressione san*
guigna.
T=25^ R. O.
163. A. Benedicenti. Arch. Fisiol. 3, 309-316, (1906).
Sui mutamenti fisico-chimici del sangue arterioso e venoso nelle variazioni della
pressione sanguigna.
164. L. Benoist, D. Hurmuzescu. Jour. Phys. (3), 5, 110-111, (1896).
Nouvelles propri^t^ des rayons X.
165. (L. Benoist, D. Huxmuzescu. Jour. Phys. (3), 5, 358r-362, (1896).
Action des rayons X sur les corps Electrifies.) [Inorganic. ]
166. (A. Benrath. Zeit. Phys. Chem. 64, 693-706, (1908).
Ueber die elektrische Leitfahigkeit von Sahsen und Salzgemischen.) [Inor-
ganic]
Meas. A. Benrath ; see 440.
166a. R. L. Benson, H. G. Wells. Jour. Biol. Chem. 8, 61-76, (1910).
The study of autolysis by physico-chemical methods.
T. Bentiyoglio see G. Magnanini.
Meas. Benz; see 487.
167. F. Bergius. Zeit. Phys. Chem. 72, 338-361, (1910).
Ueber absolute Schwefelsaure als Losungsmittel. [Different from 167a.]
T «25**. R. O. X of solvent sub.
157a. F. C. R. Bergius. Dis. Leipzig. (1907).
Ueber absolute Schwefelsaure als Ldsungsmittel.
T = 25**. X of solvent sub.
Meas. F. C. R. Bergius; see 760.
168. Earl of Berkeley, £. G. J. Hartley, J. Stephenson. Trans. R. Soc.
London. A. 209, 319-336, (1909).
On the osmotic pressures of calcium ferrocyanide solutions. Part II. Weak
solutions.
T = 0.00** ± 0.01 ^ R. O. Xoaq.= l-2XlO-«.
169. (E. Berl. Ber. Deutsch. Chem. Ges. 37, 325-^31, (1904).
Beitrage zur Kenntniss der Elektrolyse geschmolzener organischer Salze.)
B. BerU see £. Bamberger.
MeoB. W. Bemays; see 667.
160. G. Bemdt. Ann. Physik. (4), 23, 932-950, (1907).
U^er den Einfluss des Magnetfeldes auf den Widerstand von Elektrolyten.
[Summary given in 161, 162 and 163.]
T=34.2^
161. G. Bemdt Jour. Phys. 7, 221-223, (1908).
Influence dW champ magn^tique siur la resistance des Electrolytes. [Given
in 160. Same as 162.]
162. G. Bemdt Phys. Zeit. 8, 778-779, (1907).
Ueber den Einflufia des Magnetfeldes auf den Widerstand von Elektrolyten.
[Given in 160. Same as 161.]
163. G. Bemdt Verhand. Deutsch. Phys. Ges. 9, 240-242, (1907).
Ueber den Einfluss des Magnetfeldes auf den Widerstand von Elektrolyten.
[Given in 160.]
Meas, Bersch; see 1374.
A. Bertheim see A. Rosenheim.
402 AUTHOR LIST
164. D. Bertfaelot Ann. Chim. Phys. (6), 23, 1-115, (1891).
Recherches sur les conductibilit^ ^lectriques des addes organiques et de leura
sels.
T = 16.3** to 22*. X aq. not sub.
165. D. Berthelot. Ann. Chim. Phys. (6), 24, 1-45, (1891).
fitude sur la neutralisation des acides et des bases par la m^thode des conducti-
bilit^ ^lectriques.
T = 14^
166. D. Berthelot Compt. Rend. 109, 801^804, (1889).
Sur Temploi des conductibUit^s ^lectriques pour 6tudier les d^placements et
partages des acides & fonction oomplexe.
T=20^
167. D. Berthelot Compt. Rend. 109, 864-867, (1889).
Conductibilit^ ^lectriques et afiSnit^ multiples de Tacide aspartique.
T = 12°andl4°.
168. D. Berthelot Compt. Rend. 110, 703-705, (1890).
Sur les conductibilit^s des phenols et des acides oxybenzoiques.
T = 10^
169. D. Berthelot Compt. Rend. 110, 1066-1069, (1890).
Sur les oonductibilit^ des oombinaJsons de Tammoniaque et I'aniline avec les
acides o^benzoiques.
170. D. Berthelot Compt. Rend. 112, 46-48, (1891).
Sur les conductibilit^ des acides organiques isom^res et de leurs sels.
T = 17°.
171. D. Berthelot Compt. Rend. 112, 287-289, (1891).
Sur la basicity des acides organiques, d'apr^ leur conductibilit^. Acides
monobasiques et bibasiques.
T = 17°.
172. D. Berthelot Compt. Rend. 112, 335-337, (1891).
Sur la oonductibilit^ des acides organiques tribasiquee; caract^ristique nou-
velle de la basicity.
178. (D. Berthelot Compt. Rend. 113, 851-854, (1891).
Sur les trois basicity de Tacide phosphorique.)
T-17^
174. (M. Berthelot, W. C. Matignon. Compt. Rend. 113, 672-679, (1891).
Sur la chaleur de formation de I'hydrazine et de I'acide azothydrique.)
P. Berti see G. Bnmi.
A. Besredka see N. Zelinsky.
176. H. O. Bethmann. Zeit. Phys. Chem. 5, 385-422, (1890).
Ueber die Affinit&tsgrdssen einiger organischen S&uren und ihre Beziehungen
zur Konstitution derselben.
T=25^
Meaa. H. G. Bethmann; see 71, 728, 1178.
176. (M. BettL Gaz. Chim. Ital. 37, II, 5-13, (1907).
Costituzione chimica e potere rotatorio. II. Sull'influenza della funzione
chimica dei gruppi sostituenti.)
177. H. H. Beveridge. Proc. R. Soc. Edinburgh. 29, 64&-667, (1908-1909).
Hydrolysis of salts of amphoteric electrolytes.
T=0°and25'. R. O. x^s aq.=0.8-1.3XlO-«.
Meas. H. H. Beveridge; see 818.
H. H. Beveridge see J. Walker.
Bezr^dka see Besredka.
178. (O. Biach. Zeit. Phys. Chem. 50, 43-64, (1905).
Ueber Regelmassigkeiten in homologen Reihen.) [Theoretical and quoted.]
AUTHOR LIST 408
179. B. Bidutt. Bui. Soc. Nancy. (2), 11, Bui. des Stances. T", 16-18, (1891).
Sur la r^istanoe ^lectrique des dissolutioiiB d'adde tartrique et des tartrates.
T=0*'to42^ U=ohm.
Mea8. S. L. Bigelow; see 1099.
179a. B. BiiUiuum. Ber. Deutsch. Chem. Ges. 43, 568-580, (1910). Meaa.
N. Bjerrum,
Ueber die isomeren Zimts&uren.
'p— 25®. R. O. xaQ.=2XlO~*.
180. J. BiUitzer. Monatsh. 20, 666-678, (1899).
Ueber die AfiBnit&tsgrdssen ges&ttigter Fetts&turen. [Same as IBS.]
T=25°. xaq. = 2.4XlO-«.
181. J. BiUitzer. Monatsh. 23, 489^501, (1902).
Ueber die saure Natur des Acetylens. [No conductivity. Same as 184.]
182. J. BiUitzer. Monatsh. 23, 502-.511, (1902).
Ueber die F&higkeit des Kohlenstofifes, lonen zu bildm.
183. J. BiUitzer. Sitzber. Akad. Wien. 108, 2 b, 416-128, (1899).
Ueber die Affinitatsgrdssen, etc. [Same as 180. ]
184. J. BUUtzer. Sitzber. Akad. Wien. Ill, 2 b, 221-233, (1902).
Ueber die saure Natur des Acetylens. [Same as 181. ]
185. (W. BUtz. Zeit. Phys. Chem. 40, 185-221, (1902).
Zur Kenntnis der Ldsiingen anorganischer Salze in Wasser.)
186. W. BUtz, A. V. Vegesack. Zeit. Phys. Chem. 68, 357-382, (1909).
Ueber den osmotischen Druck der KoUcnde. Erste MitteUung; Ueber die
RoUe der Elektrolyte bei der Dialsrse von KoUoiden.
T=25''. xaq.=2Xia-«.
186a. W. BUtz, A. v. Vegesack. Zeit. Phys. Chem. 73, 481-512, (1910).
Meas. Pfenning.
Ueber den osmotischen Druck der KoUoide. Zweite MitteUung; Der osmo-
tische Druck einiger Farbstofflosungen.
T=25°.
187. E. C. Bingham. Dis. Johns Hopkins. (1905).
The conductivity and viscosity of solutions of certain salts in mixtures of
acetone with methyl alcohol, with ethyl alcohol, and with water. [Same as
904.]
B. C. Bingham see H. C. Jones.
Meas, A. Binz; see 1899.
188. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 1041-1049, (1891).
Ueber Trimethylbemsteinsaure.
189. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 1050-1064, (1891).
HlMeas. P. Waiden,
Ueber Aethyl-, Propyl-, und Benzyldimethylbemsteins&ure.
190. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 24, 1064-1074, (1891).
Meas, P. Walden.
Weitere Beitr§ge zur Kenntniss der substituirten Bemsteinsauren.
191. C. A. Bischoff. Ber. Deutsch. Chem. C^. 24, 2001-2025, (1891).
Meas. P. Walden,
Weitere Beitr&ge zur Kenntniss der Fumars&iu^reihe.
192. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 33, 924-931, (1900). Meas,
Centnerszwer.
Phenoxypropions&uren und Derivate.
193. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 33, 931-939, (1900). Meas,
Centnerszwer,
a-Phenoxy-Butters&ure, -Isobuttersaure und -Isovalerians&iure und deren
Ester.
404 AUTHOR LIST
194. C. A. Bischoff. Ber. Deutsch. Chem. Ges. 40, 3150-3177, (1907).
Studien tiber Verkettungen. Bis-nitrophenoxy-malonsaureester, Bis-nitrophen-
oxy-acetylentetracarbonsaureester und unerwartete iBomeriefalle bei ersteren.
195. C. A. Bischoff, A. HausdOxfer. Ber. Deutsch. Chem. Ges. 25, 2280-
2290, (1892). Mea8. P. Walden.
Ueber Paratolylglycin und seine Derivate.
196. C. A. Bischoff, E. Hjelt. Ber. Deutsch. Chem. Ges. 21, 2089-2097,
(1888). Meas. P. Walden.
Ueber symmetrische Di&thylbemsteins&uren.
197. C. A. Bischoflf, K. Jaunanicker. Ber. Deutsch. Chem. Ges. 23, 339^
3409, (1890). Mea8, P, Walden,
Ueber Pimdinsauren verschiedenen Ursprungs.
198. C. A. Bischoff, N. Iffintz. Ber. Deutsch. Chem. Ges. 23, 3410-3413,
(1890). Meas, P. Walden,
Ueber Aethyldimethylbemsteinsaure. [The measurement of Zelinsky referred
to here, is given in 2018.]
199. (C. A. Bischoff, N. Mintz. Ber. Deutsch. Chem. C^. 25, 2326-2334,
(1892).
Ueber Anilidoisobuttersauren.) [Quoted.]
200. C. A. Bischoff, P. Walden. Ber. Deutsch. Chem. Ges. 22, 1819-1822,
(1889).
Ueber bisubstituirte Bemsteins&uren. [Probably republished by P. Walden
in 1838.]
201. C. A. Bischoff, P. Walden. Ber. Deutsch. Chem. Ges. 23, 1950-1958,
(1890).
Ueber das Leitvermogen der substituirten Bemsteinsauren und Glutarsauren.
Hg. U.
202. C. A. Bischoff, P. Walden. Ber. Deutsch. Chem. Ges. 26, 1452-1460,
(1893).
Die Anwendung der dynamischen Hypothese auf Ketons&urederivate.
K. Bittner see R. Wegscheider.
Meas. N. Bjeirum; see 179a.
208. (P. Blackman. Chem. News. 93, 284, (1906).
Relative strengths of acids.) [Theoretical.]
204. (P. Blackman. Chem. News. 94, 164, (1906).
Molecular conductivities; quantitative relation). [Theoretical and quoted.]
205. (P. Blackman. Chem. News. 94, 176, (1906).
Ionic conductivities at 25°.) [Theoretical and quoted.]
206. P. Blackman. Jour. Phys. Chem. 13, 144-153, (1909).
Tables of molecular conductivities. [Calculated from measurements by him-
self and by others. ]
T = 18*'and25^
207. P. Blackman. Jour. Phys. Chem. 13, 609-629, (1909).
An electrionic theory. [Summary and enlargement of 203 to 206.]
206. (P. Blackman. Phil. Mag. (6), 11, 416^18, (1906).
Quantitative relation between molecular conductivities.) [Theoretical and
inorganic. ]
209. (P. Blackman. Phil. Mag. (6), 12, 150-152, (1906).
Atomic conductivities of the ions.) [Theoretical. ]
210. (P. BUckman. Phil. Mag. (6), 14, 21&-216, (1907).
Electrical ionic conductivities.)
210a. D. De BlasL Arch. Fisiol. 7, 501-510, (1909).
Sul oomportamento delle emazie di cane in miscela isotoniche di cloruro di
sodio e saccarosio.
AUTHOR LIST 406
811. L. Bleekrode. Ann. Physik. (3), 3, 161-196, (1878).
Ueber die Electricitatsleitung und Electrolyse der chemischen Verbindungen.
[Same as 212 and 218 together. ]
212. L. Bleekrode. Phil. Mag. (5), 5, 375-389, (1878).
On the electric conductivity and electrolysis of chemical compounds. [Same
as first part of 211. ]
218. L. Bleekrode. Phil. Mag. (5), 5, 439-451, (1878).
On the electric conductivity and electrolysis of chemical compounds. [Same
as last part of 211. ]
Blom see Oker-Blom.
214. R. Blume. Dis. Rostock. (1904).
Ueber die Einwirkung von Benzylamin und Methylbenzylamin auf das Chlor-
methylat des l-Phenyl-3-methyl-5-Ghlorpyrazols. [Same as 1266.]
T = 18^ X aq.=6.72XlO-«.
Meaa, Blume; see 1266.
214a. J. B6eseken. Rec. Trav. Chim. 29, 27&-292, (1910). »Meas, H.
Convert.
Sur les produits de Taction des amines piimaires sur les dinitrosacyles (glyox-
imeperoxydes).
T=25^
A. BOhi see R. Lorenz.
216. C. Btthm-Wendt, £. v. Schweidler. Phys. Zeit. 10, 37^382, (1909).
Ueber die spezifische Geschwindigkeit der lonen in fltkssigen Dielektrikas.
216. W. B6ttger. Zeit. Phys. Chem. 46, 521-619, (1903).
Ldslichkeitsstudien an schwer l5slichen Stoffen.
T«19.96^ X aq.=0.92-1.18XlO-«.
217. W. BSttger. Zeit. Phys. Chem. 66,^83-94, (1906).
Loslichkeitsstudien an schwer losllchen Stoffen. II. Die Ldslichkeit von Sil-
berchlorid, -bromid und -rhodanid bei 100^.
T = 100°. R. O.
S. Bogdan see P. A. Guye.
218. S. I. Bogdan. Dis. Oendve. (1902).
Application des m^thodes ph3rsico-chimique8 k I'analyse des liquides physi-
ologiques. [Probably same as 708.]
219. (A.Bogojawlensky,G.Tanmuuiii. Zeit.Phys.Chem. 23, 13-23, (1897).
Ueber den Einfluss des Drucks auf die Reaktionsgeschwindigkeit in homogenen
fliissigen Systemen.)
220. A. Bogojawlensky, G. Tammann. Zeit. Phys. Chem. 27, 457-473,
(1898).
Ueber den Einfluss des Drucks auf das dektrische Leitvermdgen von Losungen.
T = 0*». Hg. U. X aq. = 5.52 X 10-^; also 2.9 X 10-^.
221. (A. Bogorodskij. Jour. Russ. Phys.-chem. Soc. 40, 192-197, (1908).
Specific electrical conductivity of molten KNO3 and NaNOx.)
222. G. Boizard. Ann. Chim. Phys. (8), 13, 289-361, (1908).
Sur la conductibilit^ ^lectrique dans les melanges d'acide ou de base et d'eau.
[Same as 224 and 226. Text much fuller.]
T = 18®.
228. G. Boizard. Ann. Chim. Phys. (8), 13, 433-479, (1908).
Sur la conductibilit^ ^lectrique dans les melanges d'acide ou de base et d'eau.
T=s25°.
224. G. Boizard. Jour. Phys. (4), 7, 119-135, (1908).
Sur la conductibilit^ 61ectrique dans les melanges d'acide (ou de base) et d'eau.
[Given in 222 and 226.]
T = 18^
406 AUTHOR LIST
226. G. Boizard. Bui. Soc. Franc. Phys. (1907), 308-^24.
Sur la oonductibilit4 ^ectrique dans les melanges d'acide (ou de base) et d'eau.
[Same as 222 and 224.]
T = 18''
L Bolin see H. Buler.
226. E. G. de BoUemont Bui. Soc. Chim. (3), 25, 28^^38, (1901).
Cithers oxym^thdne-cyanao^tiques. [k same as 227. A also is given here.]
T=26^ R. O.
227. £. G. de BoUemont Compt. Rend. 129, 50-53, (1899).
£tude de I'oxymethyldne-cyanac^tate de m^thyle et de quelques-uns de
ses homologues. [For A and A of sodium salt see 226. Only k is given
here.]
E. Bond! see R. Wegscheider.
228. S. Bondi. Zeit. Physiol. Chem. 53, 8^13, (1907).
Beitr&ge zur Chemie der Galle. II. Mitteilung. Ueber die Starke der Glyko-
chols&ure.
T=25^ xaq. = 1.55XlO-«.
229. W. A Bone, H. Henatock. Jour. Chem. Soc. 83, 1380-1391, (1903).
The elimination of hydrogen bromide from bromo-gem-dimethylsuccinic acid
and from bromotrimethylsuccinic anhydride, [k, with slightly different value,
but no A, given in 230. ]
T=25^
280. W. A. Bone, H. Henstock. Proc. Chem. Soc. 19, 247-248, (1903).
The elimination of hydrogen bromide, etc. [k slightly different from 229. No
A given here. ]
281. W. A. Bone, W. H. Perkin, Jr. Jour. Chem. Soc. 67, 10^119, (1895).
Meas, J. Walker.
The condensation of ethylic trimethylenedicarboxylate with ethylic malonate.
282. W. A. Bone, W. H. Perkin, Jr. Jour. Chem. Soc. 67, 416-433, (1895).
Meas. J, Walker,
Trimethylsuccinic and aai-dimethylglutaric acids.
288. (W. A. Bone, W. H. Perkin, Jr. Jour. Chem. Soc. 69, 268-269, (1896).
Note on the aai-dimethylglutaric acids.)
284. W. A. Bone, C. H. G. SpnmkUng. Jour. Chem. Soc. 75, 839-864,
(1899).
Researches on the alkyl-substituted succinic acids. Part I. Methods of prep-
aration.
T =25''. [In the original, T is misprinted 23''; see 286.]
286. W. A. Bone, C. H. G. SpnmkUng. Jour. Chem. Soc. 77, 654-673,
(1900).
Researches on the alkyl-substituted succinic acids. Part II. s-Dipropyl,
s-diisopropyl, and aai-propylisopropyl-succinic acids, [k, but not /u, is given
in 289 and 240 together, except for esters.]
T=25^
286. W. A. Bone, C. H. G. Sprankling. Jour. Chem. Soc. 77, 1298-1310,
(1900).
Researches on the alkyl-substituted succinic acids. Part III. Dissociation
constants, [k, but not /i, is given in 241.]
T = 25*.
287. W. A. Bone, C. H. G. Sprankling. Jour. Chem. Soc. 81, 29-50, (1902).
The synthesis of alkyl tricarbaUylic acids, [k, but not /i, \& given in 242.]
T=25^
AUTHOR LIST 407
238. W. A. Bone, C. H. G. Spnmkling. Jour. Chem. Soc. 83, 1378-1380,
(1903).
Dissociation constants of trimethylenecarboxylic acids. \k, but not /u, with
slightly different values, is given in 843.]
T=25°.
239. W. A. Bone, C. H. G. Sprankling. Proc. Chem. Soc. 15, 149, (1899).
The symmetrical di-isopropylsuocinic acids. \k is given in 235. No n
here.]
240. W. A. Bone, C. H. G. Spnmklisg. Proc. Chem. Soc. 16, 71-72, (1900).
The sym-dipropyl, sym-diisopropyl, and aa^-propylisopropylsucdnic acids,
[k is given in 236. No fi is given here. ]
241. W. A. Bone, C. H. G. SpnmkUng. Proc. Chem. Soc. 16, 184-185,
(1900).
Researches on the alkylrsubstituted succinic acids. III. Dissociation con-
stants, [k is same as 236. No /x is given here. ] _
242. W. A. Bone, C. H. G. Sprankling. Proc. Chem. Soc. 17, 215-216,
(1901).
The synthesis of alkyl-substituted tricarballylic acids, [k is same as 237. No
fjL is given here. ]
243. W. A. Bone, C. H. G. Sprankling. Proc. Chem. Soc. 19, 247, (1903).
Dissociation constants of trimethylenecarboxylic acids. [The values of k
differ slightly from 238. No /x is given here. ]
244. W. A. Bone, J. J. Sudborongh, C. H. G. Sprankling. Jour. Chem. Soc.
85, 534r-555, (1904).
The acid esters of methyl substituted succinic acids.
T=:25°.
246. (W. A. Bone, J. J. Sudboroagh, C. H. G. SpnmkUng. Proc. Chem.
Soc. 20, 64, (1904).
Acid esters of methylsuccinic acids.) [Qualitative.]
Bonomi da Monte see DaMonte.
246. V. BoreUi. Gaz. Chim. Ital. 38, I, 361-426, (1908).
Delia costituzione di alcuni oomposti mercurid con cationi complessi. [Given
in 248.]
T = 25°.
247. V. BoreUi. Gaz. Chim. Ital. 39, I, 455-477, (1909).
Delia costituzione di alcuni composti mercurici con cationi complessi. [Given
in 248.]
T=25^
248. V. BoreUi. Mem. Accad. Torino. (2), 58, 451-560, (1908).
Sulla costituzione di alcuni composti mercurici con cationi complessi. [Same
as 246 and 247 together.]
T=25^
249. (I. Bosi. Nuovo Cim. (4), 5, 249-266, (1897).
SuUa resistenza elettrica delle soluzioni saline in movimento.) [Inorganic. ]
260. F. BottazzL Arch. Fisiol. 3, 416-146, (1906).
Sulla regolazione deUa pressione osmotica negli organismi animali. Nota 1^.
Pressione osmotica e conduttivit^ elettrica dei liquidi di animah' acquatici.
T = ll^to30^
261. F. BottazzL Arch. Fisiol. 3, 547-^556, (1906).
Sulla regolazione della pressione osmotica negli organismi animah'. Nota 3*.
Pressione osmotica e oonduttivit^ elettrica del succo musculare, del siero di
sangue e deU'orina dei pesci.
T=21.5^
408 AUTHOR LIST
262. F. BottazxL Arch. Fisiol. 5, 24^-252, (1908).
Rioerche sulla regolazione della presedone osmotica negli organismi animali.
Nota 4*. Origine dell'urea nei Selacii.
T=21''to22^
262a. F. BottazzL Arch. Fisiol. 7, 579-637, (1909).
Ricerche sopra soluzioni di colloid! organici.
268. F. Bottazzi. Ergebn. Physiol. 7, 161-402, (1908). lUMeaa. NicoUm,
Osmotischer Druck und elektrische Leitf&higkeit der FItkssigkeiten der ein-
zelligen, pflanzlichen und tierischen Orgaiiismen. [Contains a bibliography of
osmotic pressure, freezing-point and conductivity of plant and animal fluids. ]
T = 18° to 36°.
264. F. Bottazzi. Rend. Accad. Lincei. (5), 18, II, 87-90, (1909).
Sul trasporto elettrico del glicogeno (e dell'amido).
T«20°.
266. F. Bottazzi, G. Buglia, A. Jappelli. Rend. Accad. Lincei. (5), 17, II,
49-57, (1908).
Ricerche chimioo-fisiche sui liquidi degli animali- III. Variazioni della con-
duttivitjl elettrica, viscositjl e tensione superficiale del siero del sangue durante
la dialisi.
T=37°.
266. F. Bottazzi, 6. D'Errico. Arch. Gesammt. Physiol. 115, 359-385,
(1906).
Physiko-chemische Untersuchungen Uber das Glykogen.
T=37°. R. O.
267. F. Bottazzi, G. D'Errico, G. Jappelli. Biochem. Zeit. 7, 431-470,
(1907).
Wirkung des Adrenalins auf die Speichel- und Hamabsonderung.
T=29.5°and37°.
268. F. Bottazzi, A. Jappelli. Biochem. Zeit. 11, 331-345, (1908).
Physiko-chemische Eigenschaften des Blutes und der Lymphe nach Trans-
fusion homogenen Blutes.
T=:37°.
269. F. Bottazzi, N. Scalinci. Rend. Accad. Lincei. (5), 17, II, 153-159,
(1908).
Ricerche chimico-flsiche sulla lente cristallina.
260. F. Bottazzi, N. Scalinci. Rend. Accad. Lincei. (5), 17, II, 305-316,
(1908).
Ricerche chimioo-fisiche sulla lente cristallina.
260a. F. Bottazzi, C. Victorow. Rend. Accad. Lincei. (5), 19, II, 7-14,
(1910.)
Sulle propriety colloidali, e particolarmente sul trasporto elettrico dell'amido.
261. (W. R. Bousfleld. Zeit. Phys. Chem. 53, 257-313, (1905).
lonengrdssen in Beziehung zur Leitfahigkeit von Elektrolyten.) [Inorganic. ]
262. (W. R. Bousfleld, T. M. Lowxy. Proc. R. Soc. London. 71, 42-54,
(1902-1903).
Influence of temperature on the conductivity of electrolytic solutions.) [In-
organic. ]
268. E. Bouty. Ann. Chim. Phys. (6), 27, 62-94, (1892.)
Sur la coexistence du pouvoir di^lectrique et de la conductibilit^ 61ectrolytique.
[Same as 266.)
264. (E. Bouty. Compt. Rend. 114, 533-535, (1892).
Sur la coexistence du pouvoir di^lectrique et de la oonductibilit^ 41ectroly-
tique.) [Dielectric constants.]
AUTHOR LIST 409
265. (E. Boaty. Compt. Rend. 114, 1421-1423, (1892).
Sur la coexistence du pouvoir di^Iectrique et de la conductibilit^ ^lectroly-
tique.) [Dielectric constants. ]
266. E. Bouty. Bui. Soc. Franc. Phys. (1892), 244r-258.
Sur la coexistence, etc. [Same as 268.]
267. (G. Bredig. Ber. Deutsch. Chem. Ges. 37, 4140, (1904).
Die Theorie der amphoteren Elektrolyte.) [A priority claim. ]
268. O. Bredig. Zeit. Elektrochem. 6, 33-^6, (1899-1900). Meaa. K.
Winkelblech.
Ueber amphotere Elektrolyte und innere Salze. [Qualitative. See 1984 and
1986 for measurements. ]
269. G. Bredig. Zeit. Phys. Chem. 11, 829-^1, (1893).
Die Dissociation des Wassers.
S. U. X aq. sub.
270. G. Bredig. Zeit. Phys. Chem. 13, 191-288, (1894).
Beitrfige zur Stochiometrie der lonenbeweglichkeit.
T=25°. S. U. X aq.=2-4XlO-«; sub.
271. G. Bredig. Zeit. Phys. Chem. 13, 289-326, (1894).
Ueber die AffinitatsgrOssen der Basen. [The values of k are about 16% too
high, because of the value used for A( <» ) of OH. ]
T=25.0^ S. U. xaq. = l-2XlO-«;notsub.
Meaa, Bredig; see 81, 603.
272. (G. Bredig, W. FraenkeL Zeit. Elektrochem. 11, 525-528, (1905).
Eine neue, sehr empfindliche Wasserstoffionen-Katalyse.)
273. G. Bredig, A. Usofif. Zeit. Elektrochem. 3, 116-117, (1896-1897).
1st Acetylen ein Elektrolyt?
T = 25** for part of this.
274. J. Bredt Ann. Chemie. 366, 1-70, (1909). Mecw. E. ScUm.
Untersuchungen iiber die Constitution des Kamphers und seiner Derivate.
276. M. B. Breed. Dis. Bryn Mawr. (1901).
The polybasic acids of mesitylene.
T « 26**. X aq. = 2.2 X 10-«.
276. OEt. Brefiosa. Mem. R. Acad. Madrid. 24, 1-488, (1906).
La polarizaci6n rotatoria de la luz.) [Quoted. ]
277. (M. Brillouin. Ann. Chim. Phys. (8), 7, 289-320, (1906).
Considerations th4oriques sur la dissociation 61ectrolytique. — Influence du
dissolvant sur la stability des molecules dissoutes.)
A. Bringhenti see G. Carrara.
C. Brittlebank see V. Kohlschfitter.
278. J. Brode, W. Lange. Arbeit, k. Gesundh. 30, 1-54, (1909).
Beitr&ge zur Chemie des Essigs mit besonderer Beriicksichtigung seiner Unter-
suchungsverfahren.
279. A. C. Brown, J. Walker. Ann. Chemie. 261, 107-128, (1891).
Elektrolytische Synthese zweibasischer Sauren. [Same as 288.]
T=25°.
280. A. C. Brown, J. Walker. Ann. Chemie. 274, 41-71, (1893).
Elektrolytische Synthese zweibasischer S&uren. [Same as 284. k, but not At,
is given in 281 and 282.]
T-25^
281. C. Brown, J. Walker. Proc. R. Soc. Edinburgh. 18, 95-97, (1890-
1891).
Electrolytic synthesis of dibasic adds. Alkyl derivatives of succinic acid.
[This Brown is A. C. Brown. Same as first part of 280 for k.]
410 AUTHOR LIST
882. C. Brown, J. Walker. Proc. R. Soc. Edinburgh. 19, 243-248, (1891-
1892).
SynthesiB by means of electrolysis. (This Brown is A. C. Brown. Same as
last part of 280 for k.]
283. A. C. Brown, J. Walker. Trans. R. Soc. Edinburgh. 36, 211-224,
(1889-1891).
Electrolytic synthesis of dibasic acids. [Same as 279. ]
T=26°. Hg. U.
284. A. C. Brown, J. Walker. Trans. R. Soc. Edinburgh. 37, 361-379,
(1891-1895).
Electrolytic synthesis of dibasic acids. [Same as 280.]
285. W. M. Bruce. Jour. Am. Chem. Soc. 26, 419^136, (1904).
On the oxygen ethers of ureas. [Same as part of 287.]
286. W. M. Bruce. Jour. Am. Chem. Soc. 26, 449-464, (1904).
On the oxygen ethers of ureas. [Same as part of 287.]
T«25'**0.01°. R. O.
287. W. M. Bruce. Dis. Chicago. (1904).
On the oxygen ethers of urea. [Same as 286 and 286 together.]
288. (J. W. Briihl. Ber. Deutsch. Chem. Ges. 24, 3701-3737, (1891).
Untersuchungen tlber die Terpene und deren Abkdmmlinge.)
289. J. W. Briihl, H. Schr5der. Ber. Deutsch. Chem. Ges. 37, 2512-2524,
(1904).
Physiko-chemische Untersuchungen der Camphocarbons&ure, ihrer Salze,
Ester und Estersalze.
T = 17^
290. J. W. Briihl, H. Schrttder. Zeit. Phys. Chem. 50, 1-42, (1905).
Ueber Salzbildungen in Ldsungen, inbesondere bei tautomerisierbaren Kdr-
pem (PseudoB&uren, Pseudobasen).
290a. B. BrunaccL Arch. Fisiol. 8, 421-457, (1910).
Sulla funzione secretoria della parotide nell'uomo. Nota prima. Influenza
della qualitjl dello stimolo sulle propriety fisico-chimiche della saliva parotidea.
T«37^
R. F. Brunei see A. Michael.
291. L. Bruner. Ber. Deutsch. Chem. Ges. 36, 3297-^298, (1903). Meas.
J. Kozaky and G, Mariasz,
Ueber Nitromethan als Losungsmittel.
T « 18**.
291a. (L. Bruner. Zeit. Elektrochem. 16, 204-205, (1910).
Ueber die Leitf&higkeit der Halogene in Nitrobenzol.)
292. (L. Bruner. Bui. Acad. Cracov. (1901), 464-473.
Ueber die Dissociation des Chloralhydrates und Chloralalkoholates in Ld-
sungen.)
293. (L. Bruner. Bui. Acad. Cracov. (1907), 731-738.
Ueber die elektrolytische Leitfahigkeit von Brom und Jod in Nitrobenzol-
idsungen.) [Inorganic]
T=7*'and20^
294. 6. Bruni. Zeit. Elektrochem. 14, 701-706, (1908). Meaa, A, Aita.
Vergleichende Untersuchungen tiber Salzbildung und Uber die Basizitat der
S&iuen vom physiko-chemischen Standpunkte. [Acetic, formic and chloro-
acetic acids are given in 296. See 1716. ]
T — 25®. X aq. = 1 X 10"* sub. when necessary.
296. G. Bruni. Zeit. Elektrochem. 14, 729-734, (1908). Meaa, A. Aita.
Vergleichende Untersuchungen iiber Salzbildung und fiber die Basizitat der
S&uren vom physiko-chemischen Standpunkte. [See 1716.]
AUTHOR LIST 411
896. G. Bnmi, A. Aita. Rend. Accad. Lined. (5), 17, II, 295-^303, (1908).
Gontributi alio studio dei fenomeni di salificazione dal punto di vista chimico-
fisioo. [Given in 294. ]
T»25^
897. G. Bnini, P. Berti. Gas. Chim. Ital. 30, II, 151-157, (1900).
Sulle propriety dell'ipoasotide come solvente. [Qualitative. Same as
898.]
898. G. Bnini, P. Berti. Rend. Accad. Lined. (5), 9, 1, 321^26, (1900).
Sulle propriety, etc. [Same as 397. ]
899. G. Bnmi, C. Sandonnini. Zdt. Elektrochem. 14, 82^^25, (1908).
Vergldchende Untersuchungen tiber Salsbildung und Uber die Basicit&t der
Sauren vom physiko-chemisehen Standpunkte.
X aq. a3Xl0~* sub. when necessary.
899a. G. Bnmi, C. Sandonnini. Zeit. Elektrochem. 16, 223-227, (1910).
Vergleichende Untersuchungen Uber Salzbildung vom physikochemischen
Standpunkte.
T=25^
B. R. de Bmyn see A. F. HoUeman.
800. C. A. L. de Bruyn. Rec. Trav. Chim. 18, 299-301, (1899). Meas, G.
V, d, Sleen,
Sur la demonstration de la force relative des acides. [Full tables of A and k
are given in 1688 and 1684.]
C. L. de Bruyn see E. Cohen.
L. de Bruyn, E. Cohen. Verslag. Akad. Amsterdam. (1902-1903). See
E. Cohea, C. L. de Bruyn.
801. G. B. Bryan. Phil. Mag. (5), 45, 253-272, (1898).
On the determination of the conductivity of liquids in thin layers.
T=9°tol2^
Meas, K. Bube; see 607.
808. X. Budu Ber. Deutsch. Chem. Ges. 41, 692-695, (1908).
Ueber Ammonium-phenolat.
T=25^
808a. Kh Buch. Zdt. Phys. Chem. 70, 6&-87, (1910).
Die Hydrolyse der Ammoniumsalze flUchtiger S&uren.
T=25^
808. K. Buchka, A. MagalhaSs. Ber. Deutsch. Chem. Ges. 24, 674-680,
(1891). Mea8, Nemst.
Ueber das Cytisin.
T = 18^ Hg. U.
Meas, M. Buchner; see 786, 781, 1094.
L. Btichstab see N. ZeUnsky.
804. E. Buckingham. Zeit. Phys. Chem. 14, 129-148, (1894).
Ueber einige Fluoreszenzerscheinungen.
T«25^
806. E. Buckingham. Trans. Am. Electrochem. Soc. 9, 265-276, (1906).
The settling of suspensions.
T=13°to25^ R. O.
806a. C. BiUow, (K. Haas). Ber. Deutsch. Chem. Ges. 43, 3401-3412,
(1910).
Synthese von Derivaten des 1,2,7-Pyrazo-pyridins, einer neuen Ordnung
homo-(C. C.)-kondensierter, bisheterocydischer Verbindungen.
T=25^
B. Bfirkle see H. Goldschmidt
412 AUTHOR LIST
806. G. Biiglia. Arch. Fisiol. 4, 56-66, (1907).
Variazioni fisico-chimiche del siero di sangue durante rinvecchiamento.
T=30°.
a07. G. BisglUu Biochem. Zeit. 13, 400-439, (1908).
Ueber die Reguliening der physiko-chemischen Eigenschaf ten dee Blutes nach
Injektionen von verschiedenen Ldsungen.
308. G. Buglia. Zeit. Chem. Ind. KoUoid. 2, 353-354, (1908).
Ueber einige physikalisch-chemische Merkmale der homogenisierten Milch.
T=37^
G. Buglia see F. BottazzL
" " see L. SabbatanL
809. G. Buglia, L. Karczag. Rend. Aocad. Lincei. (5), 18, II, 374r^80,
(1909).
Influenza dcJla oonfigurazione stereochimica su alcune propriety flsioo-chi-
miche dei oolloidi organici.
T«37^
810. (G. Buglia, L. Karczag. Rend. Accad. Lincei, (5), 18, II, 474-181,
(1909).
Influenza della configurazione stereochimica su alcune proprietjl fisico-chi-
miche dei coUoidi organici.)
810a. F. J. J. Buijtendijk. Verslag Akad. Amsterdam. 18, 261-204, (1909).
Verslag Akad. Amsterdam, English translation, 12, 377-380.
Over de veranderingen in het bloedserum van haaien na verbloeding.
•p— 25**.
810b. F. J. J. Buijtendijk. VerslagAkad. Amsterdam. 18, 264r-267, (1909).
Verslag Akad. Amsterdam, English translation, 12, 380-383.
Over de samenstelling der urine van haaien, bij normale en versterkte diurese.
T==25°.
O. D. E. Bunge see A. Michael.
O. Burger see J. Sand.
811. (C. H. Burgess, D. L. Chapman. Jour. Chem. Soc. 85, 1305-1317,
(1904).
The nature of a solution of iodine in aqueous potassium iodide.) [Inorganic. ]
812. (C. H. Burgess, D. L. Chapman. Proc. Chem. Soc. 20, 62-63, (1904).
The nature of, etc.) [Same as 811.]
818. E. F. Burton. Phil. Mag. (6), 17, 58^-697, (1909).
The action of electrolytes on copper colloidal solutions.
T = 18^ xaq.=2XlO-«.
814. M. Busch, G. Mehrtens. Her. Deutsch. Chem. Ges. 38, 4049-4068,
(1905) . * Meas. Jordia.
Ueber Endiminotriazole.
T=25^
Bz see Tijmstra Bz.
C.
815. H. P. Cady. Jour. Phys. Chem. 1, 707-713, (1896-1897).
The electrolysis and electrolytic conductivity of certain substances dissolved
in liquid ammonia.
T=-34^
816. P. Cahn-Speyer. Monatsh. 28, 803-817, (1907). Meas. N. L. MuUer,
Untersuchungen uber die Veresterung unsymmetrischer zwei- und mehrbasis-
cher Sauren. XVI. Abhandlung; Ueber Abkdnmilinge der Aminotereph-
thalsaure. [Same as 817.]
AUTHOR LIST 418
317. P. Cahn-Speyer. Sitzber. Akad. Wien. 116, 2b, 705-719, (1907).
Meaa. N, L. MOler,
Untersuchungen Qber die VeresteruDg, etc. [Same as 316.]
318. J. C. Cain. Jour. Chem. Soc. 91, 1049-1056, (1907). Meas. H. H.
Beveridge.
The constitution of the diazo-compounds.
319. P. Calame. Zeit. Phys. Chem. 27, 401-420, (1898). Meas. Brauer,
Dittrichy Martin^ SmUh, Winkdblech.
Ueber die Dissociation mehrwertiger Salze. [Same as 320. ]
T=26'.
320. P. Calame. Dis. Leipzig. (1898). Meaa. as 319.
Ueber die Dissociation, etc. [Same as 319].]
320a. G. Calcagni. Rend. Accad. Lined. (5), 19, II, 290-293, (1910).
Sul lattato di berillio.
T=25^
320b. G. Calcagm. Rend. Accad. Lined. (5), 19, II, 33^-337, (1910).
Studii sulla capacity degli ossidrili alcoolici a formare complessi.
Meaa. B. P. Caldwell; see 1981.
B. P. Caldwell see H. C. Jones.
321. K. S. Caldwell. Chem. News. 96, 75-76, (1907).
On the conductivity of electrolytes in p3nidine and other solvents. [Given in
764.]
K. S. Caldwell see A. Hantzsch.
322. R. J. Caldwell. Proc. R. Soc. London. A, 78, 272-295, (1906).
Studies of the processes operative in solutions. Part I. The sucroclastic ac-
tion of acids as influenced by salts and non-electrol3rtes.
R. O.
323. (R. J. Caldwell, R. Whymper. Proc. R. Soc. London. A, 81, 112-117,
(1908-1909).
The determination of optical rotatory power.)
324. R. J. Caldwell, R. Whymper. Proc. R. Soc. London. A, 81, 117-140,
(1908-1909).
The changes effected by the reciprocal interference of cane-sugar and other
substances (salts and non-electrolytes) in aqueous solutions.
Xs6 aq. less than 2X10~^.
326. C. Camichel. Jour. Phys. (4), 4, 873-^84, (1905).
Fluorescence.
T = 16°to21^
326. G. Campenhausen. Dis. Heidelberg. (1896). Meaa, A, PJaff.
I. Ud[)er Oxytrimethylbemsteinsaure. [Same as 64.]
G. V. Campenhausen see K. Auwers.
327. (A. Campetti. Nuovo Cim. (3), 35, 225-234, (1894).
Sull'influenza del solvente sulla velodt^ degli ioni.) [Inorganic]
328. (A. Campetti. Atti Accad. Torino. 38, 64r-75, (1902-1903).
Sul calore di dissociazione elettrolitica.)
329. (A. Campetti. Atti Accad. Torino. 43, 1071-1094, (1907-1908).
Sulla variazione del grado di dissociazione di alcuni elettroUti colla tempera-
tura.) [Inorganic. ]
330. (A. Campetti, M. Nozaii. Atti Accad. Torino. 40, 177-185, (1904-
1905).
Sulla variazione del grado di dissociazione elettrolitica colla temperatura.)
[Inorganic. ]
T. Carlson see P. Klason.
414 AUTHOR LIST
881. (A. Gante y CaimoiUL Rev. R. Acad. Madrid. 8, 70-04, (1009-1910).
Sobre la conductibilidad de disoluciones de CIK y ClNa en mezclas de agua
y alcohol metflico. (VariacioneB con el tanto por ciento de alcohol, la ooncen-
trati6n y la temperatura).) [Inorganic. ]
T«0*to50^
882. N. Care, H. Grossmaim. Chem. Ztg. 33, 734-735, (1009). Meas,
Magnus.
Znr Kenntnis der chemischen Natur dee Dicyandiamids.
388. (O. Carrara. Gaz. Chim. Ital. 23, II, 587-595, (1893).
SuUa dissociazione elettrolitica in relasione col potere rotatorio ottico.)
[Quoted. ]
884. O. Carrara. Gaz. Chim. Ital. 24, II, 504-535, (1804).
Dissociazione elettrolitica e legge della diluizione nei aolventi organici. [Same
as 840.1
T=25^
885. G. Carrara. Gaz. Chim. Ital. 26, I, 119-195, (1896).
Per la teoria della dissociazione elettrolitica in solventi diversi dall'aoqua. I.
Alcool metilico.
T=25^ X alcohol sub.
886. G. Carrara. Gaz. Chim. Ital. 27, 1, 207-222, (1897).
Per la teoria della dissociazione elettrolitica in solventi diversi dall'acqua. II.
Acetone.
X acetone sub.
887. G. Carrara. Gaz. Chim. Ital. 27, I, 422-140, (1897).
SuUa dissociazione elettrolitica dell'alcool metilico e dell'acqua in esso disci-
olta. [In two cases Carrara distilled the alcohol over sodium. Cf. Loomis
1128 and 1124. ]
888. G. Carrara. Gaz. Chim. Ital. 33, 1, 241-^11, (1903).
Per la teoria della dissociazione elettrolitica in solventi diversi dall'acqua.
III. Influenza del solvente sopra i numeri di trasporto. [Same as 841. ]
[T probably 25^] R. O.
839. (G. Carrara. Gaz. Chim. Ital. 37, I, 525-561, (1907).
Mettrochimica delle soluzioni non acquose.) [Same as 842.]
840. G. Carrara. Rend. Accad. Lincei. (5), 3, II, 383-^90, (1894).
Dissociazione elettrolitica, etc. [Same as 884.]
841. G. Carrara. Mem. Accad. Lincei. (5), 4, 338 and 339-387, (1901).
Per la teoria della dissociazione, etc. [Same as 888.]
842. (G. Carrara. Mem. Accad. Lincei. (5), 6, 268-291, (1906-1008).
Elettrochimica delle soluzioni non acquose.) [A review of work done up
to date on the electrical conductivity of non-aqueous solutions. Same
as 889.]
848. G. Carrara, L. D'Agostini. Atti Ist. Veneto. 62, II, 793-802, (1902-
1903).
Sul grado di dissociazione elettrolitica dell'alcool metilico.
844. G. Carrara, A. Bringhenti. Gaz. Chim. Ital. 38, 1, 698-708, (1908).
Sopra i potenziali di scarica degli ioni oontenuti nelle soluzioni di alcoolati
alcalini. [Same as 845.]
845. G. Carrara, A. Bringhenti. Rend. R. Ist. Lombardo. (2), 40, 1190-
1200, (1907).
Sopra i potenziali, etc. [Same as 844.]
846. (G. Carrara, M. G. Levi. Gaz. Chim. Ital. 30, II, 197-217, (1900).
Sopra elettrostrizione degli ioni in solventi organici.) [Quoted. See 848. ]
847. G. Carrara, M. G. Levi. Gaz. Chim. Ital. 32, II, 36-53, (1902).
Sui coefficienti di temperatura della conducibilit^t elettrica delle soluzioni in
AUTHOR LIST 415
aoqua e Bolventi organici. influenza della soprafusione e del massimo di
density. [Same as 349.]
T--3^to26^ R. O.
848. (G. Carrara, M. G. Uvi. Nuovo Cim. (4), 12, 284-288, (1900).
Sopra elettrostrixione, etc.) [The text is an abridgement of 346. ]
349. G. Carrara, M. G. Levi. Atti 1st. Veneto. 61, II, 525-542, (1901*
1902).
Sui coefficienti di temperatura, etc. [Same as 347. ]
350. G. Carrara, U. Rosd. Gaz. Chim. Ital. 27, II, 505-532, (1897).
Sopra I'energia di alcune basi a funzione mista. [Same as 351, 852 and 353
together.]
X aq. sub.
351. (6. Carrara, U. Rossi. Rend. Accad. Lincei. (5), 6, II, 152-158, (1897).
Sopra I'energia, etc.) [Same as first part of 350.]
352. G. Carrara, U. Rossi. Rend. Accad. Lmcei. (5), 6, II, 208-216, (1897).
Conducibilit^ elettrica di alcune basi a funzione mista e del loro doridrati.
[Same as middle part of 350. ]
353. G. Carrara, U. Rossi. Rend. Accad. Lincei. (5), 6, II, 219-226, (1897).
Catalisi dell'acetato di metile per mezzo dei sali di alcune basi a funzione mista.
[Same as last part of 350. The affinity constants given here are not ionization
constants; see 1864.]
354. P. Carr6. Bui. Soc. Chim. (3), 33, 1314-1316, (1905).
Sur ia conductibilit6 mol^culaire des others phosphoriques. [Same as 355.]
T=25^ R. O. X aq. =0.6X10-'.
355. P. Carr4. Compt. Rend. 141, 764-766, (1905).
Sur la conductibilit^, etc. [Same as 354. ]
356. (C. G. Carroll. Am. Chem. Jour. 36, 594-599, (1906).
Ionic velocity and ionic hydration.)
357. C. G. Carroll. Dis. Johns Hopkins. (1904).
I. A study of the conductivity of certain electrolytes, eto. [Same as 908.]
C. G. Carroll see H. C. Jones.
G. A. Carse see T. H. Laby.
358. (G. A. Carse, T. H. Laby. Proc. Cambridge Phil. Soc. 14, 1-12,
(1907-1908).
A relation between the velocity and volume of organic ion& in aqueous solu-
tions.)
359. (W. Cassie. Pioc. R. Soc. London. 46, 357-358, (1889).
On the eifect of temperature on the specific inductive capacity of a dielectric.)
360. C. Cattaneo. Rend. Accad. Lincei. (5), 2, 1, 295-298, (1893).
Coefficiente negativo di temperatura per la conduoibilit^ elettrica delle solu-
zioni eteree. [Given in 366.]
T=0^to25^ Hg. U.
361. C. Cattaneo. Rend. Accad. Lincei. (5), 2, II, 112-119, (1893).
Sulla conducibilit^ elettrica dei sali disciolti in glicerina.
T=0**to24.8^
362. C. Cattaneo. Rend. Accad. Lincei. (5), 4, II, 6^-70, (1895).
Sulla conducibilit^ elettrica dei sali in vaii solventi.
T = 18^ Hg. U.
363. (C. Cattaneo. Rend. Accad. Lincei. (5), 4, II, 73-77, (1895).
Considerazioni sulla conducibilitiL elettrica dei sali in vaii solventi.) [Inor-
ganic and quoted. ]
364. (C. Cattaneo. Rend. Accad. Lincei. (5), 5, II, 207-214, (1896).
Dell' influenza del solvente sulla velocitjl degli joni.) [Inorganic]
416 AUTHOR LIST
365. (C. Cattaneo. Rend. Accad. Lincei. (5), 6, I, 279-286, (1897).
Sul numero di trasporto del cloro dell'acido cloridrico in solvent! diversi.)
[Inorganic. ]
366. C. Cattaneo. Atti Accad. Torino. 28, 617-631, (1892-1893).
Sulla conducibilitiL elettrica dei sali in varii solventi. [Part is in 860. ]
Hg. U.
Centaexiver see Centaerszwer.
367. M. Centaerszwer. Jour. Russ. Phys.-chem. Soc. 33, 545-547, (1901).
Some properties of liquid cyanogen. [Same as part of 369.]
368. M. Centnerszwer. Jour. Russ. Phys.-chem. Soc. 33, 547-549, (1901).
The ionizing properties of liquid hydrogen cyanide. [Same as part of 869. ]
T=O^S. U.
869. M. Centnerszwer. Zeit. Phys. Chem. 39, 217-224, (1902).
Ueber losende und dissociierende Eigenschaften des fltissigen Cyans und des
fltissigen Cyanwasserstoffs. [Same as 867 and 368 together. ]
T=0^ S. U.
Meas. M. Centnerszwer; see 192, 193, 1848.
M. Centnerszwer see P. Walden.
370. E. £. Chandler. Jour. Am. Chem. Soc. 30, 694-713, (1908).
The ionization constants of the second hydrogen ion of dibasic acids. [Cor-
rected in 1917. ]
T=0°and25°*0.01^ R. O.
871. A. M. Chanoz. Jour. Phys. (4), 6, 114-127, (1907).
£tude sur les contacts liquides directs. [Given in 372.]
872. A. M. Chanoz. Ann. Univ. Lyon. I, Fasc. 18, 1-99, (1906).
Recherches exp^rimentales sur les contacts liquides. [Contains also meas-
urements not given in 871.]
D. L. Chapman see C. H. Burgess.
378. J. Chandler. Ann. Chim. Phys. (8), 15, 67-140, (1908).
Sur les propri^t^s ^lectro-optiques des liqueurs mixtes.
374. J. Chaudier. Jour. Phys. (4), 8, 422-439, (1909).
£tude exp^rimentale des propri^t4s 41ectro-optiques des liqueurs mixtes.
876. G. Chavanne. Ann. Chim. Phys. (8), 3, 507-574, (1904).
Sur I'acide isopyromucique.
376a. H. Chick, C. J. Martin. Jour. Physiol. 40, 404-430, (1910).
On the '' heat coagulation " of proteins.
376. A. Chilesotti. Gaz. Chim. Ital. 34, II, 493-503, (1904).
Di due sali complessi di moUbdeno.
T=25°.
876a. A. Chistoni. Arch. Fisiol. 8, 193-204, (1910).
Influenza dello jodo sulle costanti fisico-chimiche del sangue.
T«25^
Chroushtchoff see Chroustchoff.
877. P. Chroustchoff. Compt. Rend. 108, 1003-1006, (1889).
Sur r^tude de conductibilit^ ^lectrique des dissolutions salines, appliqu^
aux probl^mes de m^canique chimique. [Most of the measurements are
same as 880, but T varies slightly in some cases, and formic acid is not
given here. ]
T = 18**to2r.
878. P. Chroustchoff. Compt. Rend. 108, 1100-1102, (1889).
De la conductibilit^ 61ectrique des dissolutions salines. D^plaoement r6ci-
proques des acides.
T-18°to21**.
AUTHOR LIST 417
379. P. Chroustchoff. Compt. Rend. 108, 1161-1162, (1889).
Sur r6tude de la conductibilit^ ^lectrique des dissolutions salines, appliqu^e
aux probl^mes de m6canique chimique. Doubles decompositions.
T=20^
380. P. Chroustchoff. Jour. Russ. Phys.-chem. Soc. 22, 115-116, (1890).
Electrical conductivity of aqueous solutions of some salts and acids. [Almost
the same as 877. ]
881. P. Chroustchoff , V. Pachkoff. Compt. Rend. 108, 1162-1164, (1889).
Sur la conductibilite ^lectrique des dissolutions salines contenant des melanges
de sels neutres. [Same as 882. ]
882. P. Chroustchoff, V. Pachkoff. Jour. Russ. Phys.-chem. Soc. 22, 110-
115, (1890).
Electrical conductivity of solutions of mixtures of some neutral salts. [Same
as 381.]
Chroutschoff see Chroustchoff.
ChruSSov see Chroustchoff.
383. G. di Ciommo. Phys. Zeit. 3, 373-374, (1901-1902).
Ueber die elektrische Leitungsfahij^keit von isolierenden Fltissigkeiten und
ihren Mischungen. [Apparently an abridgement of 386. ]
384. G. di Ciommo. Phys. Zeit. 4, 291-293, (1902-1903).
Ueber die ionisierende Kraft einiger nichleitenden organischen Fltissigkeiten.
385. G. di Ciommo. Nuovo Cim. (5), 2, 81-87, (1901).
Sulla conducibilit^ elettrica degli idrati di sodio e potassio in soluzioni gli-
ceriche.
Hg. U.
386. G. di Ciommo. Nuovo Cim. (5), 3, 97-121, (1902).
Sulla conducibilit^ elettrica dei liquid! isolanti e dei loro miscugli. [Ab-
stracted in Zeit. Phys. Chem. 44, 508, (1903). See 383.]
Hg. U.
387. L. Claisen. Ann. Chemie. 297, 1-98, (1897). Meas. HoUeman.
Untersuchungen tiber die Oxymethylenverbindungen.
T=2.6**to23.5^
Meas. R. W. L. Clarke; see 1061, 1062.
P. Claussner see A. Wohl.
388. J. A. Clmch. Dis. Gdttingen. (1904).
Ueber einige anorganische Kolloide und Metallacetylacetonate.
X aq. sub.
A. M. Clover see P. C. Freer.
388a. A. M. Clover, H. C. Jones. Am. Chem. Jour. 43, 187-223, (1910).
The conductivities, dissociations, and temperature coefficients of conductivity
between 35° and 80° of solutions of a number of salts and organic acids.
T=35°to80°. S. U. xaq.«2.0Xia-«; sub.
389. G. Coffetti. Gaz. Chim. Ital. 30, II, 235-246, (1900).
Sopra Tenergia di alcuni acidi brganici non carbossilici. [Fiorini is quoted.
See 677 for original. ]
T=25°.
390. (G. Coffetti. Gaz. Chim. Ital. 33, 1, 53-68, (1903).
Contributo alia conoscen^a delle relazioni fra la natura e la propriety del
solvente e la sua forza ionizzatrice. Conducibilit^ elettrica e suoi coefficient!
di temperatura in solventi organici.) [Inorganic]
391. £. Cohen. Zeit. Phys. Chem. 25, 1-45, (1898).
Experimentaluntersuchung Uber die Dissociation geloster Kdrper in Alkohol-
Wassergemischen.
T = 18°. Hg. U. xwaq. is less than 0.24 XlO-«.
418 AUTHOR LIST
892. B. Cohen. Zeit. Phys. Chem. 37, 69-83, (1901). Meas. F. Osaka.
Studien Qber die Inversion.
Meas, B. Cohen; see 11.
393. B. Cohen, C. L. de Bruyn. Verelag Akad. Amsterdam. 11, 621-626,
(1902-1903). Verslag Akad. Amsterdam, English translation, 5, 551-
656, (1902-1903).
Het geleidingsvermogen van hydrazine en van daarin opgeloete stoffen.
T=25*. X26 aq.=2.8XlO-«.
Cohn see Lassar-Cohn.
394. F. Cojazzi. Gaz. Chim. Ital. 30, 1, 187-188, (1900).
Suirenergia di alcuni acidi ossisolfonici.
396. U. CoUan. Zeit. Phys. Chem. 10, 130-140, (1892).
Ein Beitrag zur Kenntnis der Autokatalyse. [Same as 896.]
T=25^
396. U. Collan. Ofvers. Finska Vet^Soc. Fdrhand. 34, 249-262, (1891-
1892).
Ein Beitrag, etc. [Same as 896.]
Meas. U. CoUan; see 62; 826, 827, 880, 1888.
397. J.N. Collie. Jour. Chem. Soc. 77, 971-977, (1900). Meas. J.Walker,
Dehydracetic acid. [Same as 898. ]
398. J. N. Collie. Proc. Chem. Soc. 16, 147, (1900). Meas. J. WaUcer.
Dehydracetic acid. [Same as 397. ]
399. J. N. Collie, T. P. HUditch. Jour. Chem. Soc. 91, 787-789, (1907).
An isomeric change of dehydracetic acid. [Same as 400.]
400. J. N. CoUie, T. P. HUditch. Proc. Chem. Soc. 23, 92, (1907).
An isomeric change of dehydracetic acid. [Same as 899.]
401. J. N. CoUie, T. Tickle. Jour. Chem. Soc. 75, 710-717, (1899). Meas.
Kelias.
The salts of dimethylpyrone, and the quadrivalence of oxygen.
L. H. Cone see M. Gombeig.
402. B. J. Constam, J. White. Am. Chem. Jour. 29, 1-49, (1903).
Physico-chemical investigations in the pyridine series.
T=«25^ S. U. xaq.«0.9-1.5XlO-«; sub.
Meas. H. C. Cooper; see 1341b.
H. C. Cooper see A. A. Noyes, A. C. Melcher.
408. N. Coos. Ber. Deutsch. Chem. Gee. 35, 4109-4112, (1902).
Ueber Selendilactylsauren.
T-25^ S.U.
404. A. Coppadoro. Gaz. Chim. Ital. 32, I, 537-572, (1902).
Sulla grandezza di affinity degli acidi ossibenzoici alogenati in rapporto alia
loro costituzione.
T=24^ X aq. =3X10-«; probably sub.
406. V. V. Cordier. Monatsh. 27, 697-729, (1906).
Ueber einen Fall von wahrscheinlicher Stereoisomerie beim Guanidin. [Same
as 406 and 407.]
T-20^
406. V. V. Cordier. Sitzber. Akad. Wien. 115, 2b, 497-529, (1906).
Ueber einen Fall, etc. [Same as 406 and 407.]
407. V. V. Cordier. Verh. Gee. Deutsch. Naturf . Aerate. 76, II, 1, 105-108,
(1904).
Ueber eine wahrscheinliche Stereoisomerie, etc. [Same as 406 and 406.]
W. Cormack see J. Walker.
AUTHOR LIST 419
406. B. Comec. Compt. Rend. 149, 676-678, (1900).
£tude cryoBcopique de la neutralisation de quelques acides.
T. Costa see R. Nasini.
H. R. Courtman see J. C. Philip.
Meaa. H. Coavert; see 214a.
Coy— McCoy, q. v.
409. D. C. Crichton. Jour. Chem. See. 91, 1793-1797, (1907).
Hydrates of some quaternary bases.
Meas. D. C. Crichton; see 1858, 1879.
410. J. C. Crocker. Jour. Chem. Soc. 91, 593-612, (1907).
The velocity of hydrolysis of aliphatic amides.
T«63.2^ R. O. X aq.-2.7X10-«.
411. (J. C. Crocker. Proc. Chem. Soc. 23, 63, (1907).
The velocity of hydrolysis of aliphatic amides.) [No data.]
412. J. C. Crocker, F. H. Lowe. Jour. Chem. Soc. 91, 952-962,
(1907).
The velocity of hydrolysis of the aliphatic amides by alkali.
T =-40.06^ 63.2** and 95.9**. R. O.
413. A. W. Crossley, W. H. Peikin, Jr. Jour. Chem. Soc. 73, 1-44, (1898).
Meas. T, Etoan,
Decomposition of camphoric acid by fusion with potash or soda.
D. Crothers see H. E. Armstrong.
414. A. C. Cumming. Zeit. Phys. Chem. 57, 574-599, (1906).
Die Affinitatskonstanten amphoterer Elektrol3rte. II. Methylderivate der
Ortho- und Metaamidbenzoes&ure. [Same as 416.]
T=25**. X25 aq. not more than 1.5 XIO"*.
416. A. C. dimming. Proc. R. Soc. London. A, 78, 103-139, (1906).
The afl^ty constants of amphoteric electrolytes. II. Methyl derivatives of
ortho- and meta-aminobenzoic acids. [Same as 414.]
416. J. A. Cimningham. Piroc. Cambridge Phil. Soc. 11, 431-433, (1900-
1902).
On an attempt to detect the ionisation of solutions by the action of light and
Rontgen rays.
417. P. Curie. Compt. Rend. 134, 420-423, (1902).
Conductibilit^ des di^ectriques liquides sous Fijofluence des rayons du radiimi
et des rayons de Rdntgen.
418. R. S. Curtiss. Am. Chem. Jour. 28, 315^26, (19Q2).
On an acid derivative of ethyl anilinomalonate.
T - 19** and 19.5^
419. T. Curtius, R. Radenhansen. Jour. Prakt. Chem. (2), 43, 207-208,
(1891). Meaa. W. Oaiwald,
Zur Kenntniss der Stickstoffwasserstoffs&ure.
D.
L. D'Agostini see 6. Carrara.
420. P. DaUe. Rec. Trav. Chim. 21, 123-154, (1902).
Sur le trim^thyl^no-carbinol et ses d^vds. [Same as 421.]
T-25^
421. P. Dalle. Bui. Acad. Belg. (1902), 36-79.
Sur le trim^thyltoo-carbinol, etc. [Same as 420.]
422. W. van Dam. Zeit. Physiol. Chem. 58, 295-330, (1908-1909).
Beitrag zur Kenntnis der Labgerinnung.
420 AUTHOR LIST
428. P. B. DaMonte, A. Zoso. Gaz. Chim. Ital. 27, II, 467-475, (1897).
Sulla energia di alcuni acidi solfonici del toluolo e del xilolo.
T==25^
424. (H. Danneel. Zeit. Elektrochem. 11, 249-252, (1005).
Notiz tkber lonengeschwindigkeiten.) [Inorganic]
H. Davidsohn see L. Michaelis.
Meas, W. B. Davidson; see 781, 736, 776, 1729.
W. B. Davidson see A. Hantzsch.
426. W. B. Davidson, A. Hantzsch. Her. Deutsch. Chem. Ges. 31, 1612-
1648,(1898). fH Meaa. Kissel.
Physikochemische Untersuchungen Uber Diazoniumsalze, Diazoniumhydrat
und normale Diazotate.
T=0^ r and25^
R. O. £. Davis see C. H. Herty.
426. H. M. Dawson. Zeit. Phys. Chem. 69, 110-122, (1909).
On the nature of ammoniacal solutions of cupric hydroxide.
T = 18^
de; see under the letter beginning the next word, e, g,, de Bruyn, see
under Bruyn.
427. S. Deakin, M. Scott, B. D. Steele. Zeit. Phys. Chem. 69, 123-135,
(1909).
On the complex oxalates of cobalt and nickel.
De Blasi see Blasi.
428. G. Dedichen. Her. Deutsch. Chem. Ges. 39, 1831-1856, (1906).
Affinitatsgrossen einiger cyclischer Basen.
(T probably 25^] R. O.
429. (C. D^guisne. Ann. Physik. (3), 52, 604-606, (1894).
Ueber die Frage nach einer Anomalie des Leitvermdgens wasseriger Losungen
bei 4^.) [Inorganic]
430. C. D^guisne. Dis. Strassburg. (1895). Abstracted in Beibl. Ann.
Physik. 20, 996-997, (1896).
Temperaturkoeffizienten des Leitvermogens sehr verdtinnter wfisseriger
Losimgen.
de la; see under the letter beginning the next word, as for de.
431. M. Del^pine. Bui. Soc Chim. (4), 3, 643-652, (1908).
Composes sulfur^s et azotes d6riv63 du sulfure de carbone (XII). Thiosulfo-
carbamates m^talliques. [Same as 482. ]
432. M. DeMpine. Compt. Rend. 146, 981-984, (1908).
Propri^t^s des thiosulf ocarbamates m^talliques. [Same as 481. ]
H. Demierre see P. Dutoit.
433. C. DempwolfF. Phys. Zeit. 5, 637-641, (1904).
lonenwanderung im Methylalkohol cJs Ldsungsmittel.
T = 18^
434. H. G. Denham. Jour. Chem. Soc. 93, 41-63, (1908).
The electrometric determination of the hydrolysis of salts.
T=25^ X aq. = 1.2-2.5XlO-«.
436. R. B. Denison, B. D. Steele. Jour. Chem. Soc 89, 999-1013,
(1906).
A new method for the measurement of hydrolysis in aqueous solution based
on a consideration of the motion of ions. [See correction in 436. k at 25° is
given in 437. ]
T = 18*»and25^
436. R. B. Denison, B. D. Steele. Jour. Chem. Soc. 89, 1386-1387, (1906).
A new method for the measurement of hydrolysis in aqueous solution based
AUTHOR LIST 421
on a consideration of the motion of iona. A correction. Pc at 25** is same as
in i36. The correction is for 18^1
T = 18** and 25^
437. R. B. Denison, B. D. Steele. Proc. Chem. Soc. 22, 162-163, (1906).
A new method, etc. [k at 25^ same as i36. No A given here. ]
i38. R. Dennhardt Ann. Physik. (3), 67, 325-344, (1899).
Ueber Beziehimgen zwischen Fluidit&t und elektrolytischer Leitfilhigkeit
von Salzlosungen sowie tiber die Leitfahigkeit von Oelsfture und deren Alka-
lisalzen in Wasser bez. Alkoholen bei verschiedenen Temperaturen.
T-O** to 60^ R. O. X aq. = 1.0-2.2XlO-«; sub.
439. J. H. Derby. Am. Chem. Jour. 39, 437-473, (1908).
Studies in catalysis. IV. The catalysis of imidoesters. [k same as in part of
1656 and 1657.]
T = 18**and25***0.0r. Hg. U.
Meaa. L H. Derby; see 1657.
I. H. Derby see J. Stieglitz.
D'Errico see Errico.
des; see under the letter beginning next word, as for de.
C. H. Desch see A. Hantzsch.
440. J. Deschauer. Dis. Heidelberg. (1905). Meas, A. Benrath.
Ueber die Kondensation von Aceton mit Bemsteinsaureester.
[Probably R. O. ] x aq. « 6.23 X 10-^
441. E. Deussen. Zeit. Anorg. Chem. 44, 300-340, (1905).
Zur Kenntnis der Flusss&ure. [Same as 442.]
T=25^
442. E. Deussen. Habilitschr. Leipzig. (1905).
Zur Kenntnis der Flusss&ure. [Same as 441. ]
443. E. Deussen, 6. Heller, O. NOtzel. Ber. Deutsch. Chem. Ges. 40,
1300-1303, (1907).
Leitfahigkeit wassriger Ldsungen von N-Isatin-natrium und isatinsaurem
Natrium.
T=25^
444. A. Devrient. Dis. Leipzig. (1897).
Isomere der Camphorons&ure.
T=25^
J. Dewar see J. A. Fleming.
445. J. Dewar, J. A. Fleming. Proc. R. Soc. London. 61, 2-18, (1897).
Note on the dielectric constant of ice and alcohol at very low temperatures.
T=-185^
445a. C. Dh6r6, M. Gorgolewski. Compt. Rend. 150, 934-936, (1910).
Sur la preparation et sur quelques propriety physicochimiques de la gelatine
d^mineralis^e.
xaq. = 1.5XlO-«.
445b. C. Dh6r6, M. Gorgdewski. Compt. Rend. 150, 993-996, (1910).
Sur Tobtention, par dialyse ^lectrique, d'un s^rum extrdmement appauvri en
Electrolytes.
446. (H. C. Dibbits. Zeit. Analyt. Chem. 13, 137-146, (1874).
Ueber die Loslichkeit des schwefelsauren Bleioxydes in Ldsungen von essig-
saurem Natron.)
H. Diesselhorst see F. Kohlrausch, L. Hdbom.
447. O. Dimroth. Ann. Chemie. 335, 1-112, (1904).
Ueber desmotrope Verbindungen. [See 653.]
T=25**and50^ R. O.
422 AUTHOR LIST ^
448. O. Dimroth. Ann. Chemie. 338, 143>182, (1905). {Meas. H. Stahl.l)
Ueber desmotrope Verbindungen.
T=25.** [ProbablyR. O., cf. 447.]
449. C. Dittrich. Zeit. Phys. Chem. 29, 449-490, (1899).
Die Uranylsaize vom physikalisch-chemischen Standpunkte aus betrachtet.
T= 26^ Hg. U. xaq.-2-3.2XlO-«; sub.
Meaa, C. Dittrich; see 1029, 1678, 1674.
460. (H. Ditz. Chem. Ztg. 25, 1, 109-112, (1901).
Ueber einige Reactionen des Kobalts und Eisens und den Einfluss der Alkohole
und anderer organischer Stoffe auf die elektrol3rti8che Dissociation der Salze
in wfisseriger Losung.)
J. Dodt see J. Tafel.
F. B. DoUftts see A. Hantzsch.
IMeaa. Doogier; see 1108.
Dongier see Lesage.
461. Dongier, Lesage. Compt. Rend. 134, S34r-835, (1902).
Valeurs de la resistance ^lectrique, de Tindice de refraction et du pouvoir ro-
tatoire de scrums sanguins normaux. [Coirected for typographical errors in
Compt. Rend. 134, 932.]
T = 16.7^
462. (F. G. Donnan. Phil. Mag. (5), 45, 520-532, (1898).
The Thomson effect in a binary electrol3rte.)
468. (F. G. Donxian. Phil. Mag. (6), 3, 305^10, (1902).
Condensation of the vapours of organic liquids in presence of dust-free
air.)
F. G. Domian. Phil. Mag. 15, 305, is the preceding reference.
464. O. Dony-H^nault. Bui. Acad. Belg. (1909), 342-409.
Contribution k F^tude m^thodique des oxydases.
T=25^
Meas, A. Dom; quoted in 7.
Doroschewsky see Doroftevskij.
466. A. G. Doroievskij, M. S. Ro2dest7eiiflkij. Jour. Russ. Phys.-chem.
Soc. 40, 739-740, (1908).
The electrical conductivity of mixtures of alcohol and water. [A summary
of 466.]
T = 15•andl8^ R. O.
466. A. G. Doroievskij, M. S. Rozdestvenskij. Jour. Russ. Phys.-chem.
Soc. 40, 887-908, (1908).
The electrical conductivity of mixtures of alcohol and water. [A summary
is given in 466.]
T = 15**andl8*. R. O.
466a. S. van Dorssen. Rec. Trav. Chim. 29, 368-393, (1910).
Contribution k la connaissance des acides nitro- et amidosulfobenzolques.
T-25^ R. O.
467. (J. M. Douglas. Dis. Johns Hopkins. (1901).
The dissociation of certain acids, bases and salts at different temperatures.)
[Same as 909.]
J. M. Douglas see H. C. Jones.
468. Dreser. Zeit. Elektrochem. 10, 65&-660, (1^904).
Die Gefrierpunkt»- imd Leitf&higkeitsbestimmung des Hams in einigen phar-
makologischen Ergebnissen.
469. (K. Drucker. Zeit. Elektrochem. 13, 81-83, (1907).
Beweglichkeit von lonen in Wasser.)
AUTHOR LIST 428
460. K. Drucker. Zdt. Phys. Chem. 49, 56a^589, (1904).
Messungen und Berechnungen von Gleichgewichten stark dissozlierter S&uren.
T=»18'*=*»0.05^ R. O. xi8 aq. -1.3X10-*; sub.; also gives data without
sub.
461. K. Drucker. Zeit. Phys. Chem. S2, 641-704, (1905).
Studien an wasserigen Ldsungen aliphatischer Sfiuren. [Same as 462. ]
T =0** and 25**. R. O. X26 aq. « 1.7 X 10-«; sub.
462. K. Drucker. Habilitschr. Leipzig. (1905).
Studien an w&sserigen, etc. [Same as 461.]
Meas, K. Drucker; see 1079.
K. Drucker see V. Rothmund.
468. M. Dubouz. Dis. Lausanne. (1908).
Contribution k Tanalyse physico-chimique des vins. [See P. Dutoit, M.
Duboux, Compt. Rend. 147, 134 and 351, (1908), for use of this method.]
T-25^ R. O.
M. Dubouz see P. Dutoit
464. J. DucUux. Zeit. Chem. Ind. Kolloid. 3, 126-134, (1908).
Die Filtration koUoider Losungen. [Contains a bibliography of measure-
ments of the electrical conductivity of colloidal solutions to date. ]
466. A. Dunuuudd. Jour. Russ. Phys.-chem. Soc. 39, 137^1391, (1907).
The electrical conductivity of electrolytes in aqueous solutions of gdatin.
[Same as 467 and 468.]
T=25^
466. A. V. Dunuuudd. Jour. Russ. PhyB.-chQpi. Soc. 41, 252-258, (1909).
Mendelejeff number.
Influence of colloids on the electrical conductivity of electrolytes.
467. A. Dunuuudd. Zeit. Chem. Ind. Kolloid. 2, Suppl. Heft 1, 18-22,
(1908).
Ueber die Leitfahigkeit der Elektrolyte in wftsserigen Ldsungen von Gelatine.
[Same as 466 and 468.]
T=25*.
468. A. DumansHi. Zeit. Phys. Chem. 60, 553-562, (1907).
Ueber die Leitf&higkeit der Elektrolyte in wSsserigen Losungen von Crelatine.
[Same as 466 ^d 467.]
Dumanakij see DumansM.- . ^
Dumansky see Dumanski.
H. Duperthuis see P. Dutoit
469. E. L. Durand. Dis. Geneve. (1902). ""
Recherches exp^rimentales sur la solubility des malonates alcalino-terreux et
sur quelques constantes physico-chimiques. de leurs solutions.
T=22'*to40^ R. O. xaq. sub.
470. P. Dutoit Jour. Chim. Phys. 1, 617-656, (1903).
Conductibilit^, dissociation et propri^t^s des ^Electrolytes dans les dissolvants
autres que Feau. [Contains a full review of the literature to date. ]
471. P. Dutoit Zeit. Elektrochem. 12, 642-644, (1906). Meas, OUiker.
Ueber molekulare Leitfahigkeit, Betrag und Gesetze der Dissociation organi-
scher und unorganischer Losungsmittel.
472. P. Dutoit Bui. Soc. Vaudoise. Compt. Rend. June (1906), I.
Les conductibilitds et les reactions des Electrolytes dans les dissociants autre
que Feau.
478. P. Dutoit Bui. Soc. Vaudoise. Proc. Verb. 41, VI-XI, (1904-
1905).
L'acide isosalicylique.
424 AUTHOR LIST
474. P. Dvtoit, E. Aston. Compt. Rend. 125, 240-243, (1897).
Relation entre la polymerisation des corps liquides et leur pouvoir dissociaat
sur les eiectrol3rte8.
T-20^
476. P. Dutoit, H. Demierre. Jour. Chim. Phys. 4, 565-575, (1906).
Reactions ioniques dans Tao^tone.
T usuaUy 37.5''. S. U.
478a. P. Dtttoit, M. Dubouz. Bui. Soc. Vaudoise, (5), 45, 417--461, (1909).
Quelques rteultats de Tanalyse physioo-chimique dee vins.
476. P. Dutoit, M. Dubouz. Bui. Soc. Vaudoise. Compt. Rend. (1908), IV.
Determination des bases volatiles du vin.
477. P. Dutoit, M. Dubouz. Bui. Soc. Vaudoise. Proc. Verb. 45, 43-44,
(1908-1909).
Acidite r6elle dans les vins.
478. P. Dutoit, H. Dupertfauis. Jour. Chim. Phys. 6, 699-725, (1908).
Meaa. Crognaux; OUiker.
CbaleuTB de dissociation de quelques eiectroljrtes dans des dissolvants orga^
niques.
T=0*»to80^ S. U.
479. (P. Dutoit, H. Duperthnis. Jour. Chim. Phys. 6, 726-731, (1908).
Viscosit^ et conductibilit^s limites.)
480. P.DutoitfH.Dupei11iui8. Bui. Soc. Vaudoise. Compt. Rend. (1908), I.
Relations qui existent entre les oonductibilit^s limites et la visoosite. [Qual-
itative.]
T=0'*to80^
481. P. Dutoit, H. Dttperthuis. Bui. Soc. Vaudoise. Compt. Rend. (1908),
V.
Conductibilit^s moieculaires limites. [Qualitative.]
T=0**to80^
462. P. Dutoit, L. Fziderich. Bui. Soc. Chim. (3), 19, 321-337, (1898).
Sur la oonductibilite des electrolytes dans les dissolvants organiques.
T=0^25**and50^ R. O.
488. P. Dutoit, L. Gagnauz. Arch. Sci. Phys. Nat. (4), 23, 213-214, (1907).
Conductibilite de quelques electrolytes binaires dans Tether acetylacetique,
I'alcool isobutylique et I'alcool isoamylique. [Same as 484.]
484. P. Dutoit, L. Gagnauz. Bui. Soc. Vaudoise. Compt. Rend. (1906-
1907), III.
Les conductibilites de quelques electrolytes binaires dans Tether aoetylaoetique
etc. [Same as 488. ]
486. P. Dutoit, E. Gyr. Jour. Chim. Phys. 7, 189-203, (1909).
Conductivites eiectriques de solutions trte dilueos dans Tajihydride sulfureux.
[Same as 704. Abstracted in 486.]
T«-15^ R. O.
486. P. Dutoit, £. Gyr. Bui. Soc. Vaudoise. Compt. Rend. April, (1906),
I-II.
Les conductibilites moieculaires limites dans Tanhydride sulfureux & —5^.
[Given in full in 486 and 704.]
487. P.Dutoit,A.Levier. Jour. Chim. Phys. 3, 435-454, (1905). fItMeaa.
Bern,
Conductibilites limites de quelques eiectrol3rtes binaires dans I'acetone.
T = 18^ S. U.
488. P. Dutoit, Ottiker. Arch. Sci. Phys. Nat. (4), 23, 215. (1907).
Dissociation des electrolytes dans Talcool propylique et la pyridine. [Same
as 489. Qualitative.]
AUTHOR LIST 426
489. P. Dutoit, Ottiker. Bui. Soc. Vaudoise. Compt. Rend. (1906-1907),
V.
La dissociation des Electrolytes dans I'aloool propylique et la pyridine. [Same
88 488.]
490. P. Diitoit, H. lUppeport. Arch. Sci. Phys. Nat. (4), 24, 417-418,
(1907).
Ck>nductibilit^ limites de quelques sels dans I'alcool Ethylique. [Given in
491 and 1470.]
T = 18^ S. U.
491. P. Dutoit, H. Rappeport Jour. Chim. Phys. 6, 545-551, (1908).
Conductivit^s limites de quelques Electrolytes dans Talcool Ethylique. [Given
in 1470. Part is same as 490.]
T-18^ 8. U.
B.
6. W. Eastman see A. A. Noyes, A. C. Melcher, H. C. Cooper.
492. F. P. Bbersbach. Zeit. Phys. Chem. 11, 608-632, (1893).
Ueber die Affinitatsgrdssen aromatischer Amidosulfonsfiuren.
T=25^
Meas. F. P. Bbersbach; see 604.
O. Ecker see F. Straus.
Bffendi see Sald-B£fendi.
493. (H. E. Eggers. Jour. Phys. Chem. 8, 14-36, (1904).
On the dielectric constants of solvents and solutions.)
494. R. Ehrenfeld. Zeit. Elektrochem. 9, 335-342, (1903). Meas, TF.
Storer.
Ueber die Bildung von Wasserstoffionen aus den Methylengruppen der
Bemsteinsaure, der Malonsaure und Glutarsaure.
T=20.3^
496. R. Ehrenfeld. Zeit. Elektrochem. 10, 3-9, (1904).
Ueber die Veranderung der spezifischen Leitfahigkeit von Salsldsungen durch
Alkalilauge.
T=20.3^
496. F. H. Eijdnum Fils. Rec. Trav. Chim. 25, 83-95, (1906).
Sur la coIorim6trie et sur une m^thode pour determiner la constante de dis-
sociation des acides. [Same as 497.]
497. F. H. Eijdnum Jr. Verslag Akad. Amsterdam. 14, 97-107, (1905-
1906). Verslag Akad. Amsterdam, English translation, 8, 166-175,
1905-1906).
Over oolorimetrie en over een oolorimetrische methode om de dissociatie^con-
stante van zuren te bepalen. [Same as 496.]
498. (G. F. Emery. Proc. R. Soc. London. 55, 356^73, (1894).
Thermo-electric properties of salt solutions.)
499. R. Emrich. Dis. Erlangen. (1902).
Ueber die Mnwirkung von Dichloressigsaiuie auf Anilin. [See 798 for correc-
tion. The a- and /3- acids here should be interchanged.]
R. O.
Meas. R. Emrich; see 798.
C. Ende see L. W. Andrews.
600. A. Engler. Ber. Deutsch. Chem. Ges. 33, 218&-2190, (1900).
Antidiazonaphtahnsalze und Naphtylnitrosamin.
T=0^
A. Engler see A. Hantzsch, M. Sch&nann.
426 AUTHOR LIST
601. A. Bugler, A. Hantzsch. Ber. Deutsch. Chem. Ges. 33, 2147-2158,
(1900).
Diazoniumhydrate und Diasohydrate. [Corrected in 787.]
T-0^
602. J. B. Bnklaar. Rec. Trav. Chim. 24, 419-443, (1905).
Nouvelles recherches sur Taction des bases sur Thydrate de chloral.
T-0.65**. R. O. xo.66 aq. =2.5 and 2.4X10-*; not sub.
608. A. Bppens. Dis. MUnchen. (1892). Meas. G. Bredig,
Ueber das Campher-Phoron. [981 gives no numerical data. ]
A. Bppens see W. Koenigs.
604. H. Erdnuuin. Ann. Chemie. 275, 184-^309, (1893). Meaa, F. P.
Eberahctch,
Allgemeines Qber Scheidung und Constitution der isomeren Naphtalinver-
bindungen.
606. (T. Erhard. Chem. Ztg. 23, 1, 283-284, (1899).
VerdUnnte Ldsungen und elektrolyt. Dissociation.)
606. (T. Erhard. Chem. Ztg. 23, 1, 285-287, (1899).
Verdiinnte Ldsungen und elektrolyt. Dissociation.)
607. B. Erienmeyer. Ber. Deutsch. Chem. Ges. 42, 2655-2675, (1909).
Meas. K. Bube.
Die Abh&ngigkeit der Unterschiede bei den Zimts&uren von dem Ausgangs-
material.
T =25.00** *0.04^
O. Erler see H. Ley.
607a. G. D'Errico. Arch. Fisiol. 8, 177-186, (1910).
Influenza dell'inanizione e dell'ingestione di sostanze non elettroliti sulla
pressione osmotica e la conduttivit^ elettrica del sangue.
T=37.2^
D'Errico see F. Bottazzi.
608. (J. A. Erskuie. Ann. Physik. (3), 62, 454-459, (1897).
Ueber das electrische Leitungsvermogen der Electrolyte fur sehr schnelle
electrische Schwingungen). [Inorganic]
609. A. Esmann. Dis. Leipzig. (1905).
Zwei stereoisomere Butentricarbonsauren aus Natriummalonsfiureester und
den beiden o-Bromcrotons&ureestem.
T=25^ S. U.
A. Euler see H. Euler.
610. H. Euler. Ber. Deutsch. Chem. Ges. 36, 1854-1860, (1903).
Ueber Silberanmioniakbasen und Silbercyanwasserstofifsaure.
T = 18^ R. O.
611. H. Euler. Ber. Deutsch. Chem. Ges. 37, 2768-2773, (1904).
Ueber Complexbildung. II. Pyridincomplexe.
T = 18^
612. H. Euler. Ber. Deutsch. Chem. Ges. 39, 344-350, (1906).
Die Aldehyde als S&uren.
T=0*»tol8^
618. H. Euler. Ber. Deutsch. Chem. Ges. 39, 1607-1615, (1906).
Zur Kenntniss der Pseudosauren. [Same as 621. ]
T = l^ 10*»andl8^
614. (H. Euler. Ber. Deutsch. Chem. Ges. 39, 2265-2269, (1906).
Ueber Pseudosauren. Antwort auf Hm. Hantzsch' Kritik.)
614a. H. Euler. Ergebn. Physiol. 9, 241-333, (1910).
Die chemische Dynanuk der Enzymreaktionen. [Quotes J. Sjdqvist.]
AUTHOR LIST 427
616. H. Buler. Zeit. Phys. Chem. 21, 257-271, (1896).
Ueber die Abh&ngigkeit des Diasociationsgrades einiger S&uren von der Tem-
peratur und tkber ihre Dissociationsw&rme.
T =0** to 50*. X aq. not sub.
616. (H. Enler. Zeit. Phys. Chem. 25, 536^542, (1898).
Ueber die innere Reibung elektrolytischer Losungen.)
617. H. Euler. Zeit. Phys. Chem. 28, 619-^28, (1899).
Ueber den ZiiBammenhang zwischen der dissociierenden Kraft, der Dielek-
trizit&tskonstanten und der molekularen Beschaffenheit von FlUssigkeiten.
[Qualitative.]
618. (H. Euler. Zeit. Phys. Chem. 29, 603--612, (1899).
Dissociationsgleichgewicht starker Elektrolyte.) [Inorganic. ]
619. H. Euler. Zeit. Physiol. Chem. 51, 213-225, (1907).
Fermentative Spaltung von Dipeptiden. [Part is same as 622 and 628.]
T = 18**and25^
620. H. Euler. Aikiv Eemi. 1, 77-91, (1903-1904).
Ueber Ammoniak und Metallammoniakbasen I. [Inorganic. ]
621. H. Euler. Arkiv Kemi. 2, no. 22, 1-13, (1905-1907).
Zur Kenntms der Pseudos&uren. (Same as 618. ]
622. H. Euler. Arkiv Kemi*. 2, no. 31, 1-10, (1905-1907).
Fermentative Spaltung von Dipeptiden. [Part is same as 619.]
T«18**and25^
628. H. Euler. Arkiv Kemi. 2, no. 39, 1-13, (1905-1907).
Zur Kenntnis der alkalischen Verdauung. [Part is same as 619.]
T = 18*and37^
624. H. Euler, I. Birfin. Zeit. Phys. Chem. 66, 71-77, (1909). MMeaa. H.
LurMn.
Ueber die Dissociationskonstanten der Dioxybenzole.
T=0** and 18^ xu aq.-l.6XlO-'; sub.
626. H. Euler, I. Bolin. Zeit. Phys. Chem. 69, 187-202, (1909).
Ueber die chemische Zusanunensetzung und die biologische Rolle einer Oxy-
dase.
T- 17^ Xi7. 5 aq. = 1.8X10-*.
626. H. Euler, A. Euler. Ber. Deutsch. Chem. Gee. 36, 4246-4253,
(1903).
Ueber die EUnwirkimg von Amylnitrit auf /S-Aminocrotonsaiueester.
627. H. Buler, A. Euter. Ber. Deutsch. Chem. Ges. 36, 4253-4256,
(1903).
Ueber die Bildung hydrirter Osotriazole. [See 680 for full measurement.
Only k is given here, no A.]
628. H. Euler, A. Buler. Ber. Deutsch. Chem. Ges. 38, 2551-2560, (1905).
Zur Kenntniss des Formaldehyds und Formiatbildung. [See 629 and 68. ]
T=0^
629. H. Buler, A. Buler. Ber. Deutsch. Chem. Ges. 39, 36-39, (1906).
Nachtrag zu unserer Mittheilung Uber Formaldehyd und Formiatbildung.
680. H. Euler, A. Buler. Arkiv Kemi. 1, 111-126, (1903-1904).
Ueber die Bildung von aliphatischen Isonitrosoverbindungen und Osotriaaolen
aus /3-Amino-Crotonsftureester. [627 gives k without tables of A.]
T = 18**and21.5^
681. H. Buler, A. Hantzsch. Ber. Deutsch. Chem. Ges. 34, 4166-4169,
(1901).
Ueber ein festes Diazoniumcyanid und tkber Diazojodide.
T = 18^
428 AUTHOR LIST
682. H. Enler, B. af Ugglas. Zdt. Phys. Chem. 68, 498-^510, (1909).
Hydrolyse und ReaktioDsgeschwindigkeit in w&sserig-alkoholische Losungen.
[Same as 038. 1
Ts= —50** to +30**.
638. H. Euler, B. af UggUs. Arkiy Kemi. 3, no. 21, 1-14, (1908-1910).
Hydrol3r8e, etc. [Same as 682.]
684. P. Erersheim. Ann. Physik. (4), 8, 539-567, (1902).
Bestimmung der Leitfahigkeit und Dielektricitatsconstanten yon Losungs-
mitteln und deren Ldsungen in ihrer Abh&ngigkeit yon der Temperatur bis
liber den kritischen Punkt. [Same as 687. ]
T«20**tol96^
686. P. Eversheim. Ann. Physik. (4), 13, 492-511, (1904).
Verhalten yon Leitfahigkeit und Dielektrizitatskonstanten einiger Substanzen
yor und in dem kritischen Zustand.
686. P. Eversheim. Phys. Zeit. 4, 503-507, (1902-1903).
Leitfahigkeit und Dielektrizitatskonstante yon Ldsungen und Ldsungsmittel
im kritischen Zustande.
687. P. Eyersheim. Dis. Bonn. (1902).
Bestimmuns der Leitf&higkeit, etc. [Same as 684.]
E. Evieuz see L. Vignon.
688. T. Ewan. Jour. Chem. Soc. 69, 96-97, (1896).
Note on the electrolytic conductivity of formanilide and thioformanilide.
T-25*. S. U.
689. (T. Ewan. Proc. Chem. Soc. 12, 8, (1896).
Note on the electrolytic conductivity of formanilide and thioformanilide.)
[Qualitative. ]
640. T. Ewan. Proc. R. Soc. London. 57, 117-161, (1894-1895). Meas.
vanH Hoff.
On the absorption spectra of dilute solutions.
T = 14.1^
Meaa. T. Ewan; see 418, 1411.
Eydman see Eijdnian.
641. J. F. Eykman. Ber. Deutsch. Chem. Ges. 24, 1278-1303, (1891).
Ueber die Shikimisaure.
T«9**tol9^
Meas, J. F. Eykmann; see 888.
P.
642. L Fanjung. Zeit. Phys. Chem. 14, 673-700, (1894).
Ueber den Einfluss des Druckes auf die Leitfahigkeit von Elektrol3rten.
T = 14** to 19**. X aq. sub. for salts.
648. G. Farkas. Arch. Gesammt. Physiol. 98, 551-576, (1903).
Ueber die Concentration der Hydroxylionen in Blutserum.
T = 19**to22^
644. G. Farkas, E. Sdpiades. Arch. Gesammt. Physiol. 98, 577-587,
(1903).
Ueber die molekularen Concentrationsverhfiltnisse des Blutserums der Schwan-
geren, Kreissenden und Wdchnerinnen und des Fruchtwassers.
T = 18^ R. O.
646. R. C. Fanner. Jour. Chem. Soc. 79, 863-870, (1901).
A new method for the determination of hydrolytic diissociation.
T=25^
R. C. Farmer see P. F. FranUand.
AUTHOR LIST 429
646. R. C. Fanner, A. Hantzsch. Ber. Deutsch. Chein. Ges. 32, 308&-3101,
(1899).
Die Constitution der sogen. OxyarokOrper.
T=25^
647. R. C. Farmer, A« Hantzsch. Ber. Deutsch. Chem. Ges. 32, 3101-^109,
(1899).
o-Oxinudoketone und Chinonoxime als Pseudos&uren.
T=25^
648. R. C. Fanner, F. J. Warth. Jour. Chem. Soc. 85, 1713-1726, (1904).
The affinity constants of aniline and its derivatives.
T = 6** and 25^
649. (R. C. Fanner, F. J. Warth. Proc. Chem. Soc. 20, 244, (1904).
The affinity constants of aniline and its derivatives.) [Only comparative.
No data.]
660. F. Fasshender. (A. Werner.) Zeit. Anorg. Chem. 15, 123-142, (1897).
Beitrag zur Konstitution anorganischer Verfoindungen. VIII. Mitteilung.
Ueber die Anderson'sche Reaktion. [Same as 661. ]
661. F. Fassbender. Dis. Zttrich. (1896).
Untersuchungen Qber die Anderson'sche Reaction und tkber die isomeren
Platoeoxals&uren. [Same as 660. ]
662. C. E. Fawsitt Zeit. Phys. Chem. 41, 601-629, (1902).
Die Zersetzung des Hamstoffs. [Same as 666. ]
T= 99.2** for part. R. O. x aq. = 1.8-2.1 X10-«; sub.
663. C. E. Fawsitt Zeit. Phys. Chem. 48, 585-592, (1904).
Physikalisch-chemische Untersuchimgen in der Amidgruppe. [Same as 664.]
T=25**and34.2^
664. C. E. Fawsitt Proc. R. Soc. Edinburgh. 25, 1, 51-60, (1903-1905).
Physico-chemical investigations in the amide group. [Same as 668. ]
666. C. E. Fawsitt. Dis. Leipzig. (1902).
Die Zersetzung des Hamstoffs. [Same as 662. ]
666. A. FSdorov. Jour. Russ. Phys.-chem. Soc. 35, 651-652, (1903). Ab-
stracted in Beibl. Ann. Physik. 28, 969, (1904).
Electrical conductivity of solutions of oxahc acid in the presence of neutral
salts.
667. F. Feist Ann. Chemie. 257, 253-297, (1980). Mea8. G. Magnanini.
Ueber Dehydracets&ure.
668. F. Feist Ber. Deutsch. Chem. Ges. 25, 315-335, (1892). Meaa.Barih.
Ueber neue S3mthesen mittelst Dehydracets&ure.
669. F. Feist Ber. Deutsch. Chem. Ges. 26, 747-764, (1893). Mea8. A.
MidaH.
Ueber den Abbau des Cumalinringes.
660. (B. Fels. Zeit. Elektrochem. 10, 208-214, (1904).
Studien iiber die Indikatoren der Acidimetrie und Alkalimetrie.)
661. (H. J. H. Fenton, H. O. Jones. Jour. Chem. Soc. 79, 91-101, (1901).
Relationships of oxalacetic acid.) [Qualitative. Same as 662. See correction
in 926 and 027.]
662. (H. J. H. Fenton, H. 0^ Jones. Proc. Chem. Soc. 16, 205, (1900).
Relationships of oxalacetic acid.) [Same as 661.]
663. (H. J. H. Fenton, H. O. Jones. Proc. Chem. Soc. 17, 24-26, (1901).
Note on a method for comparing the affinity values of acids.) [Continuation
of 662. See also 926 and 927.]
664. F. Fichter. Verhand. Naturf. Ges. Basel. 16, 245-298, (1903).
Ueber unges&ttigte S&uren. [A siunmary of 666, 668 and 671.]
480 AUTHOR LIST
664a. F. Fichter. Arch. Sci. Phys. Nat. (4), 27, 40&-410, (1900).
Conatantes d'affinit^ des acides bibasiques non satur^s. [Given with tables
of A in 671a. ]
666. F. Fichter, A. Beisawenger. Ber. Deutsch. Chem. Ges. 36, 1200-1205,
(1903).
Die Reduction des Glutars&ureanhydrids zum 5-Valerolacton.
T«25^ R. 0.
666. F. Fichter, B. Giaiger. Ber. Deutsch. Chem. Ges. 42, 4707-4710,
(1909).
Ueber /^Methyl-pentens&uren. [Same as 642 for acids, k is given in 669.
No salts are given here.]
T=25^ R. O. X26aq.-3.6XlO-«.
667. F. Fichter, W. Latzko. Jour. Prakt. Chem. (2), 74, 327-332, (1906).
Studien an ungesfittigten S&uren. Div. VII. Ueber Diphenylvinylessigs&ure.
[Latzko's name appears only under Div. VII. See 1068 for full tables of A
and k. Only k is given here. ]
T=25^
668. F. Fichter, B. Miihlhaiiaer. Ber. Deutsch. Chem. Ges. 35, 341,
(1902).
Messungen an der o^Aethylidenglutarsaure. [Same as 1291 for k; no tables
of A are given here. ]
T«25^ R. O.; also S. U. for sodium salt.
669. F. Fichter, H. MilUer. Ann. Chemie. 348, 256-259, (1906). Meas.
E. Giaiger, and H. Obladen.
Affinit&tsmessungen an einbasischen unges&ttigten Fettsfturen. [For tables
of A and k see 666 and 670. Same as 1292. ]
T=25^ R. O. X26aq.-3.5XlO-«.
670. F. Fichter, H. Obladen. Ber. Deutsch. Chem. Ges. 42, 4703-4707,
(1909).
Ueber OrAethyl-pentens&uren und dber Xerons&ureanhydrid. [Same as
1847. Only k is given in 669. ]
T=25^ R. O. xaq.»3.5XlO-«.
671. F. Fichter, A. Pfiater. Ann. Chemie. 334, 201-210, (1904). ^Meaa.
E. FUeg and E, Rudin,
Leitf&higkeitsmessungen an ungesattigten Sfiuren. [Part is same as 622. ]
T=25^ R. O.
671a. F. Fichter, H. Probst Ann. Chemie. 372, 69-79, (1910).
Leitfahigkeitsmessungen an zweibasischen, ungesattigten structurisomeren
Sauren. [k only, is given in 664a.]
T=26^
672. F. Fichter, J. Schwab. Ann. Chemie. 348, 251-256, (1906).
Ueber /3-Methylglutaconsauren. [Same as 1608.]
T=25^ R. O. xaq.=3X10-«.
673. F. Fichter, F. Sonnebom. Ber. Deutsch. Chem. Ges. 35, 938-943,
(1902).
Ueber Vinylessigsaure. [Given with full tables of A in 1640.]
T=25^ R. O.
D. Filippi see R. Luzzatto.
674. A. Findlay, W. E. S. Turner, G. E. Owen. Jour. Chem. Soc. 95, 938-
942, (1909).
Affinity constants of hydroxy- and alkyloxy-acids. [k, but no A, is given in
4(76.]
T=25^
AUTHOR LIST 481
676. A. Findlay, W. £. S. Tomer, O. B. Owen. Proo. Chem. Soc. 25, 146,
(1909).
The aflSnity constants of hydroxy- and alkyloxy- acids. [Given in 674.]
T=26^
676. (J. Fink. Ann. Physik. (3), 26, 481-617, (1885).
Ueber den Tginflnaa des Druckes auf den electrischen Leitungswiderstand von
Electrolyten.) [Inorganic]
677. C. Fiorini. Gaz. Chim. Ital. 31, 1, 33-39, (1901).
Sugli spettri di assorbimento degli acidi cloranilico, bromanilico e dei loro sali
alcalini. [Quoted in 389. ]
678. W. M. Fischer. Zeit. Phys. Chem. 65, 61-69, (1908-1909).
Ueber die Kinetik der Bildung und Verseif ung von Salpetrigs&ureestem.
Mea8, W. Fischer; see 764.
679. R. Fittig. Ann. Chemie. 330, 292-^1, (1904). Meas, P. JM.
Ueber Umlagerungen bei den unges&ttigten Saure. [Same as 886.]
T-20^ R. O.
680. T. C. Fitzpatrick. Phil. Mag. (5), 24, 377-391, (1887).
On the action of the solvent in electrolytic conduction.
T varies; usually 15** to 18*. U=legal ohm.
Mean, Flaschner; see 1246, 1247.
J. A. Fleming see J. Dewar.
681. J. A. Flemhig, J. Dewar. Proc. R. Soc. London. 61, 290-316, (1897).
On the dielectric constants of certain frozen electrolytes at and above the
temperature of liquid air.
682. J. A. Fleming, J. Dewar. Proc. R. Soc. London. 61, 316-^30, (1897).
On the dielectric constants of pure ice, glycerine, nitrobenzol and ethylene
dibromide at and above the temperatiure of liquid air.
688. B. Fliirscheim. Jour. Chem. Soc. 95, 718-734, (1909).
The relation between the strength of acids and bases and the quantitative
distribution of affinity in the molecule.
T*17*and25^
684. B. FliirscheinL Jour. Chem. Soc. 97, 84-97, (1910).
The relation between the strengths of acids and bases, and the quantitative
distribution of affinity in the molecule. [m-Toluidine is given qualitatively
in 686.]
T=25^ Kw = 1.18XlO-".
686. (B. Fliirschehn. Proc. Chem. Soc. 25, 22-23, (1909).
The relation between the strength of acids and bases and the quantitative
distribution of affinity in the molecule.)
686. B. Fliirscheim. Proc. Chem. Soc. 25, 193-194, (1909).
The relation between, etc. [Given in 684.]
687. C. Foil Arch. Fisiol. 3, 369-415, (1906).
La reasione dei liquid! dell'organismo determinata col metodo elettrometrico
(pile di concentrazione).
686. A. Fock. Zeit. Ver. Rtlbenzuck. Ind. (1889), 710. Abstracted in
Zeit. Analyt. Chem. 29, 35-56, (1890).
Die Anwendung des elektrischen LeitungsvermOgens zu quantitative Bestim-
mung.
T= 25^ S. U. xaq.= 6.37X10-^.
Meas, Foote; see 1661, 1664.
689. (H. W. Foote, N. A. Martin. Am. Chem. Jour. 41, 453^57, (1909).
On the molecular condition of salts dissolved in a fused salt. II. The electrical
conductivity of salts in fused mercuric chloride.)
482 AUTHOR LIST
590. J. S. Fordf J. M. Gatbrie. Jour. Chem. Soc. 89, 76-92, (1906).
The influence of certain amphoteric electrolytes on amylolytic action.
T=25^ R. O. xaq. = 1-1.5X10-*; not sub.; given only for one meas-
urement.
P. V. d. Forst see H. Grossmann.
591. W. Poster. Ph]^. Rev. 8, 257-281, (1899).
The conductivity and dissociation of some electrolytes.
T = 18^ S. U. andR. O. xis aq. is about lXlO-«.
592. £. Fouard. Bui. Soc. Chim. (4), 3, 836-840, (1908).
Siur les propri6t6s colloldales de I'amidon. [Given in 595. ]
598. E. Fouard. Bui. Soc. Chim. (4), 5, 828-834, (1909).
La solubilisation de Tamidon colloidal sous Faction des alcalis.
T=30^
594. E. Fouard. Compt. Rend. 144, 1366-1368, (1907).
Siur les propri^t^ colloldales de Tamidon.
595. E. Fouard. Compt. Rend. 146, 978-981, (1908).
Siur les propri^t^ de Pamidon en rapport avec sa forme coUoIdale. [Gives
more details of measurements than 592.]
T = 25^ X aq. = 2.785 X lO"*.
596. (G. Foussereau. Ann. Chim. Phys. (6), 15, 533-544, (1888).
Siur la decomposition des hyposulfites par les acides.) [Inorganic]
597. G. Foussereau. Jour. Phys. (2), 4, 450-456, (1885).
Sur la h^sistance ^lectrique de I'alcool.
T = 15^
598. (W. Fraenkel. Zeit. Phys. Chem. 60, 202-236, (1907).
Zur chemischen Kinetik des Diazoessigester.)
W. Fraenkel see G. Bredig.
599. L. Francesconi, A. Miled. Gaz. Chim. Ital. 32, 1, 425-436, (1902).
Sulla formazione della cetossima.
[T apparently is 11**.]
Meas, £. Francillon; see 1401.
600. R. T. Frank. Am. Jour. Physiol. 14, 466-468, (1905).
A note on the electric conductivity of blood during coagulation.
601. E. Franke. Zeit. Phys. Chem. 16, 463-492, (1895).
Beitrage zur elektrischen Leitfahigkeit von Salzen und Sauren in wassriger
Losung.
T= 25^ Hg. U. xaq.=2-3XlO-«; sub.
Mea8. £. Franke; see 1212.
602. P. F. Frankland, R. C. Fanner. Jour. Chem. Soc. 79, 1356-1373,
(1901).
Liquid nitrogen peroxide as a solvent.
T=0°.
608. (P. F. FranUand, R. C. Farmer. Proc. Chem. Soc. 17, 201, (1901).
Liquid nitrogen peroxide as a solvent.) [Qualitative.]
604. E. C. Franklin. Zeit. Phys. Chem. 69, 272-^03, (1909).
The electrical conductivity of liquid ammonia solutions. III.
T=-44'' to -33^ R. O.
605. E. C. Franklin, H. D. Gibbs. Jour. Am. Chem. Soc. 29, 1389-1396,
(1907).
The electrical conductivity of methylamine solutions.
[T is probably 20.3°.] R. O.
606. £. C. Franklin, C. A. Kraus. Am. Chem. Jour. 20, 820-836, (1898).
Liquid ammonia as a solvent. [Qualitative.]
AUTHOR LIST 488
607. E. C. FrankUn, C. A. Kraus. Am. Chem. Jour. 23, 277-313, (1900).
The electrical conductivity of liquid ammonia solutions. [The measure-
ments are given in abridged form in 612. ]
T=-38^ R. O.
608. The reference under this number has been omitted intentionally.
609. £. C. Franklin, C. A. Kratis. Am. Chem. Jour. 24, 83-93, (1900).
The conductivity temperature coefficient of some liquid ammonia solutions.
T=23*to363^
610. £. C. Franklin, C. A. Eraus. Jour. Am. Chem. Soc. 27, 191-222,
(1905).
The electrical conductivity of liquid ammonia solutions.
T=-33^ R. O.
611. (£. C. Franklin, C. A. Kraus. Proc. Am. Ass. Advanc. Sci. 47, 215-
217, (1898).
Some properties of liquid ammonia.) [An abstract. No data. ]
612. £. C. Franklin, C. A. Kraus. Proc. Am. Ass. Advanc. Sci. 48, 157-159,
(1899).
The electrical conductivity, etc. [Given in 607.]
613. (W. S. Franklin, L. A. Freudenbeiger. Phys. Rev. 25, 294--302, (1907).
Measurement of electrolytic resistance.) [Inorganic]
614. J. C. W. Frazer. Am. Chem. Jour. 30, 309-323, (1903).
On relations between the color and the composition and constitution of the
alkali salts of the nitrophenols. [Same as 615. ]
T=25^
615. J. C. W. Frazer. Dis. Johns Hopkins. (1901).
On the relations between, etc. [Same as 614.]
616. (C. Fredenhagen. Ann. Physik. (4), 17, 285-331, (1905).
Entwurf einer allgemeinen Theorie elektrolytischer Ldsungskonstanten und
Spannungsreihen, sowie der Ldslichkeit und Dissoziation von Sauren und
Basen.)
617. P. C. Freer, A. M. Clover. Am. Chem. Jour. 25, 390-413, (1901).
On the constituents of Jamaica dogwood.
T=25**.
617a. W. Frci. Zeit. Chem. Ind. KoUoide. 6, 94-103, (1910).
Ueber Leitimgshenmiimg durch Kolloide nebst Bemerkungen zum Serumleit-
vermogen.
T=35^
L. A. Freudenbeiger see W. S. Franklin.
L. Friderich see P. Dutoit.
618. (H. Friedenthal. Zeit. Elektrochem. 10, 113-119, (1904).
Die Bestimmung der Reaktion einer FlUssigkeit mit Hilfe von Indikatoren.)
[Quoted. ]
H. Friedenthal see A. Auerbach.
" " see £. Salm.
619. J. FriedlHnder. Zeit. Phys. Chem. 38, 385-440, (1901).
Ueber merkwtirdige Erscheinungen in der Umgebung des kritischen Punktes
t^weise mischbarer Flussigkeiten. [Same as 620. ]
T = 17^to43^ R. O.
620. J. Friedlllnder. Dis. Leipzig. (1901).
Ueber merkwurdige Erscheinungen etc. [Same as 619.]
621. A. Fuchs. Verb. Ges. Deutsch. Naturf . Aerzte. 76, II, 2, 292, (1904).
Untersuchungen des Liquor cerebrospinalis, mit spezieller Berticksichtigung
der Chemie desselben.
Meas. £. Fiieg; see 571.
484 AUTHOR LIST
888. G. Ffleg. Dis. Basel. (1904).
I. Ueber l-Phenyl-3-methyl-5-pyrazolidonp3-carboiis&ure.
II. Ueber OrMethyl- 7^penten8&ure. [This is the same FQeg as in 571| and
the same measurement.]
T-25^
Mea8, L. Oagnaux; see 478.
L. Gflgnauz see P. Dutoit
Meaa. R. D. Gale; see 1888.
638a. G. Galeotti. Arch. Fisiol. 7» 418-420, (1G09).
Sui fenomeni elettrici della mucosa stomacale della rana.
T-12*to 14^
688. G. Galeotti. Zeit. Biol. 43, 289-340, (1902).
Ueber die elektrische Leitf&higkeit der tierischen Gewebe.
T«12^to38^
634. G. Galeotti. Zeit. Biol. 45, 65-78, (1904).
Neue Untersuchimgen Uber die elektrische Leitfahigkeit imd den osmotischen
Druck der tierischen Gewebe.
T « 18^
686. A. Gamgee. Chem. News. 85, 145-147, (1902).
On certain chemical and physical properties of haemoglobin. [Same as
686.]
T = 0** to 39*. R. O. X aq. not over 2.5 X 10-«.
686. A. Gamgee. Proc. R. Soc. London. 70, 79-83, (1902).
On certain chemical, etc. [Same as 686.]
686a. B. Gardella. Arch. Fisiol. 8, 408-420, (1910).
Le costanti fisico-chimiche del siero di sangue di cane dopo Tablazione dell'ap-
parato tiro-paratiroideo.
T=25^
687. (J. A. Gardiner. Proc. Trans. R. Soc. Canada. (3), 2, Sect. Ill, 37-52,
(1908).
On the conductivity of mixtures of dilute solutions.) [Inorganic. ]
688. (D. D. Gardner, D. G. Gerassimoff. Jour. Russ. Phys.-chem. Soc.
36, 605, (1904).
On the determination of the solubility of salts of weak acids by the measure-
ment of the electrical conductivity.) [An abstract of 639 and 680.]
689. (D. D. Gardner, D. G. Gerassimoff. Jour. Russ. Phys.-chem. Soc. 36,
746-753, (1904).
On the determination of the solubility of salts of weak acids by the measure-
ment of the electrical conductivity.) [Same as 680. Inorganic]
680. (D. D. Gardner, D. Gerassimoff. Zeit. Phys. Chem. 48, 359-364,
(1904).
Ueber die Bestinmiimg der Loslichkeit von Salzen schwacher S&uren durch
Messung der Leitfahigkeit.) [Same as 689.]
681. F. Garelli. Rend. Soc. Chim. Roma. 1, 74-80, (1903).
Dissociazione elettrolitica in soluzioni acquose e in solventi organici ed inor-
ganici.
683. (A. £. Garrett. Proc. Phys. Soc. London. 20, 584r-606, (1905-
1907).
Electrical conductivity produced by heating salts.) [Inorganic. ]
688. (A. E. Garrett, R. S. WiUows. Phil. Mag. (6), 8, 437-454, (1904).
Chemical dissociation and electrical conductivity.) [Same as 684. Inorganic. ]
AUTHOR LIST 486
684. (A. £. Garrett, R. S. Willows. Proc. Phys. Soo. London. 19, 325-^2,
(190a-1905).
GhemicjEj diseociation, etc.) [Same as 688].
V. Garuti see L. Pelet
Garz6n see Carmona.
684a. W. W. H. Gee, F. Brotherton. Mem. Proo. Manchester Lit. Phil.
Soc. 54, Mem. 13, (1909-1910).
The electrical resistance of the human body.
684b. (W. W. H. Gee, W. Hanison. Trans. Faraday Soc. 6, 42-62,
(1910).
The electrical theory of dyeing.)
A. Generosow see N. Zelinsky.
Gerasimov see Gerassimoff.
D. G. Gerassimoff see D. D. Gardner.
686. D. Gerilowski, A. Hantzscfa. Ber. Deutsch. Chem. Ges. 29, 743-755,
(1896).
Weiteres Uber die stereoisomeren Salze aus Diacosulfanilsaure.
T=0^
686. P. Gerlinger. Ber. Deutsch. Chem. Ges. 37, 3958-^963, (1904).
Zur Umlagerung echter Farbbasen in Carbinolbasen und echter Farbstoff-
cyanide in Leukocyanide. [Correction of 770.]
F. H. Getman see H. C. Jones.
687. H. D. Gibbs. Jour. Am. Chem. Soc. 28, 1395-1422, (1906).
Liquid methylamine as a solvent, and a study of its chemical reactivity.
[Qualitative. ]
H. D. Gibbs see £. C. Franklin.
688. (J. Gibson. Proc. R. Soc. Edinburgh. 26, 234r-237, (1905-1906).
Preliminary note on the conductivity of concentrated aqueous solutions of
electrolytes.)
689. (J. Gibson. Trans. R. Soc. Edinburgh. 45, 241-259, (1905-
1907).
On the relationship between concentration and electrolytic conductivity in
concentrated aqueous solutions.) [Quoted.]
640. A. Gillaov. Jour. Russ. Phys.-chem. Soc. 28, 501-509, (1896).
Synthesis of tertiary trimethylethylene lactic acid.
T=25^
641. Gin, Leleoz. Compt. Rend. 120, 917-920, (1895).
Sur la resistance 61ectrique des liquides sucr6s.
O. Girard see H. Goldschmidt.
642. £. Gisiger. Dis. Basel. (1905).
Ueber /^Methyl-jSy-pentensaure und /3-Methyl-aj3-pentensaure. 11. Ueber
Tolilsaure. [Same as 666 for acids, but sodium salt is also given here. Same
as part of 569 for k, but also gives A.]
T=25^ R. O. X26aq.=3.6XlO-«.
Meaa, E. Gisiger; see 669.
£. Gisiger see F. Fichter.
648. £. Glimm. Dis. Freiburg. (1902).
Ueber die dlonstitution Formaldehydschwefligsaurer Salse. 11. Ueber die
Affinitatsgrosse aromatischer Oxyaldehyde. [The values for the hydroxy-alde-
hydes are probably too high. Cf. 1897c.]
T=25^ xaq. sub.
A. Glogau see R. Wegscheider.
486 AUTHOR LIST
644. W. H. Glover. Dis. Leipzig. (1905).
Ueber die Kdrperfarbe von Chinon- und Ketonderivaten sowie von Oxyaso-
k5rpern. [Same as 768.]
Mea8, W. H. Glover; see 768. '
W. H. Glover see A. Hantzscli.
646. R. Gnehm, T. Scheutz. Jour. Prakt. Chem. (2), 63, 40&-427, (1901).
JJeber alkylirte Amidobenzolsulfos&uren und Metamidophenole. [Same as
1686.]
646. T. Gnesotto. Atti Ist. Veneto. 59, II, 987-1006, (1899-1900).
Considerazioni e ricerche intomo alia anomalia della resistenza elettrica delle
soluzioni acquose in prossimitA dei 4°.
T-0.16°to7.43^
647. T. Godlewski. Jour. Chim. Phys. 3, 393-434, (1905).
Sur la dissociation des 61ectrol3rte8 dans les solutions alcooliques. [Same as
648.]
T s 18° =*^0.V. R. O. X of alcohol not sub. except for acetic acid.
648. T. Godlewski. Bui. Acad. Cracov. (1904), 239-276.
Sur la dissociation des ^lectrol3rte8 dans les solutions alcooliques. [Same as
647. Abstracted in Zeit. Phys. Chem. 51, 751, and Zeit. Elektrochem, 11, 121. ]
648a. (J. B. Goebel. Zeit. Phys. Chem. 71, 652-666, (1910).
Ueber einige Beziehungen zwischen den Gefrierpunktsemiedrigungen, lonen-
konzentrationen und Leitf&higkeiten der Elektrolyte.)
A. G6rtz see £. Lellmann.
£. G. Goldberg see A. W. Speranskij.
649. F. Goldschmidt. Phys. Zeit. 1, 287-289, (1899-1900).
Ueber das Leitvermdgen wfissriger Animoniakldsungen.
660. F. Goldschmidt. Zeit. Anorg. Chem. 28, 97-139, (1901).
Physikalisch-chemische Studien an wfisserigen Anmioniakldsungen. [Same
as 662.]
T=25''=*=0.05'*. xaq.=3.5X10-«; notsub.
661. (F. Goldschmidt. Zeit. Elektrochem. 10, 221-222, (1904).
Ziur Theorie der Verseifung.)
662. F. Goldschmidt. Dis. Breslau. (1901).
Physikalisch-chemische Studien, etc. [Same as 660.]
663. (H. Goldschmidt. Zeit. Elektrochem. 11, 5-7, (1905).
Ueber Desmotrope Verbindungen.) [An analysis of 447.]
664. H. Goldschmidt. Zeit. Elektrochem. 15, 5-10, (1909). Meas. Udby.
Untersuchungen Uber Esterbildung.
T=25^
666. H. Goldschmidt. Zeit. Phys. Chem. 17, 145-163, (1895).
Die molekulare Ldslichkeitserhohung.
T=23.7°to50.1^
666. H. Goldschmidt. Zeit. Phys. Chem. 25, 91-99, (1898). Meas. G. v.
Maarseveen,
Ueber die Beziehung zwischen Losungswarme, Loslichkeit imd Dissociations-
grad. [Same as 1161.]
T = 25^
666a. H. Goldschmidt. Zeit. Phys. Chem. 70, 627-^643, (1910).
Ueber Esterbildung mit schwachen Sauren als Katalysatoren.
T=25^
667. H. Goldschmidt, £. Biiikle. Ber. Deutsch. Chem. Ges. 32, 355-^78,
(1899). Meaa. W, Bemays.
Dynamische Untersuchimgen uber die Bildung der Azof arbstoffe.
AUTHOR LIST 487
668. (H. G<^d8chinidt| O. Giraid. Ber. Deutsch. Ghem. Gee. 29, 1224-
1242, (1896).
Kryoskopische Versuche mit Phenolsalzen.)
669. H. Goldscliinidt, K. Ingebrechtsen. Zeit. Phys. Cfaem. 48, 435-466,
(1904).
Ueber die Reduktion von Nitrokdrpem durch Zinnhalogentire.
660. H. Goldschmidt, H. Keller. Ber. Deutsch. Chem. (]^. 35, 3534^549,
(1902). mMeas.M.Miindler.
Dynamische Untersuchungen Uber die Bildung der Azofarbstoffe. [Part is
given in 967; part in 1293.]
66(Hu H. Goldschmidt, H. Larsen. Zeit. Phys. Chem. 71, 437-512, (1910).
Die Reduktion der Nitrogruppe durch Schwefelwasserstoff. Bin Beitrag zur
Kenntnis der Katalyse.
T-25^
661. H. Goldschmidt, L. Oslan. Ber. Deutsch. Chem. (]^. 32, 3390-3399,
(1899).
Zur Kenntniss des Acetessigesters. [Same as 1356 for 25®.]
T=25^
662. H. Goldschmidt, L. Oslan. Ber. Deutsch. Chem. Ges. 33, 1140-1152,
(1900).
Zur Kenntniss des Acetessigesters.
T=25^
663. H. Goldschmidt, L. R6der. Ber. Deutsch. Chem. Ges. 28, 2013-2020,
(1895).
Zur Kenntniss der Aldoximsalze.
664. H. Goldschmidt, R. M. Salcher. Zeit. Phys. Chem. 29, 89-118, (1899).
Studien tiber die Aminolyse. [Same as 1568. ]
T=25^
665. H. Goldschmidt, V. Schols. Ber. Deutsch. Chem. Ges. 36, 1333-1341 ,
(1903).
Ueber Verseifimgsgeschwindigkeit und Affinitatsgrosse des Malons&uredia-
tfaylesters.
666. H. Goldschmidt, V. Scholz. Ber. Deutsch. Chem. Ges. 40, 624-641,
(1907).
Ueber die Verseifungsgeschwindigkeit einiger Keto- und Gxysaureester.
[Given in 1594.]
T=25^
667. H. Goldschmidt, B. Sunde. Ber. Deutsch. Chem. Ges. 39, 711-725,
(1906).
Ueber Esterbildung.
T=25^
668. M. Gomberg. Am. Cfaem. Jou^. 25, 317-^5, (1901).
On trivalent carbon.
669. M. Gomberg. Ber. Deutsch. Chem. Ges. 35, 2397-2408, (1902).
Ueber Triphenylmethyl. Ein Beitrag ziur Kenntniss der Carboniumsalze.
T=-18®to -10^
670. (M. Gomberg. Ber. Deutsch. Chem. Ges. 36, 3927^930, (1903).
Ueber die Existenzfahigkeit einer Klasse von Kdrpem, die dem Triphenyl-
methyl analog sind.) [Quoted. ]
M. Gomberg see N. £. Tousley.
671. M. Gomberg, L. H. Coae. Ber. Deutsch. Chem. Ges. 37, 2033-2051,
(1904).
Ueber Triphenylmethyl. [(Corrected in 678.]
T=«0^
488 AUTHOR LIST
678. M. Oomberg, L. H. Co&e. Ber. Deutach. Ghem. Gee. 37, 3539^547,
(1904).
Vfber Triphenylmethyl.
678. M. Gombergy L. H. Cone. Ber. Deutsch. Ghem. Gee. 38, 1333-1344,
(1905).
Ueber Triphenylmethyl. [Also corrects 671.]
674. (H. M. Goodwin, H. T. Kalmus. Phys. Rev. 27, 322-328, (1908).
On the conductance and fluidity of fused salts.) [Inorganic. ]
676. (H. M. Goodwin, R. D. Mailey. Phys. Rev. 25, 46^-489, (1907).
On the density, electrical conductivity and viscosity of fused salts and their
mixtures.) [Inorganic. Abstract given in 677.]
676. (H. M. Goodwin, R. D. Mailey. Phys. Rev. 26, 28-60, (1908).
On the density, electrical conductivity and viscosity of fused salts and their
mixtures.) [Inorganic]
677. (H. M. Goodwin, R. D. Mailey. Trans. Am. Electrochem. Soc. 11,
211-223, (1907).
On the density, electrical conductivity, and viscosity of fused salts.) [An
abstract of 676.]
678. (H. M. Goodwin, M. de K. Thompson. Phys. Rev. 8, 38-48, (1899).
On the dielectric constant and electrical conductivity of liquid anmionia.).
679. (H. M. Goodwin, H. A. Wentworth. Phys. Rev. 24, 77-92, (1907).
On the ionization of fused salts.) [Inorganic. ]
M. GorgolewsU see C. Dh€r6.
680. H. Gorke. Zeit. Phys. Ghem. 61, 495-502, (1907-1908).
Ueber die Leitf&higkeit von Pikrinsaurelosungen und die Beweglichkeit des
H-_Ions.
T-0^ 18* and 25**. x^ aq. -0.8X10-*; sub.
681. H. Gorke. Dis. Leipzig. (1905).
Ueber Ldsungen stark dissoziierter Elektrolyte. II. Ueber die angeblichen
Isomerieen bei Phosphiten und Hypophosphiten. III. Ueber chinotde aci-
Nitrophenol&ther.
Meaa, H. Goike; see 1092.
S. V. Gorski see S. v. Laszczyaski.
682. U. Gouttefangeas. Ann. Ghim. Phys. (8), 17, 51&-525, (1909).
Sur la conductibilit^ ^lectrique des flammes sal^.
Meas. W. Graf; see 788.
W. Graf see A. Hantzsch.
683. O. Gntul. Dis. Wttrzburg. (1898).
Ueber isomere Salze aus Aethylnitrols&ure. [Most measurements are given
in 684.]
T=0^ /Liaq.-1.9XlO-*.
Meaa, O. Graul; see 733, 776.
684. O. Graul, A. Hantzsch. Ber. Deutsch. Ghem. (ks. 31, 2854-2879,
(1898).
Ueber isomere Salze aus Aethylnitrols&ure. [Most measurements are given
in 683.]
T-0^
686. (W. H. Green. Jour. Ghem. Soc. 93, 2023-2048, (1908).
Studies on the viscosity and conductivity of some aqueous solutions. Part I.
Solutions of sucrose, hydrogen chloride, and lithium chloride.)
686. W. H. Green. Jour. Ghem. Soc. 93, 2049-2063, (1908).
Studies on the viscosity and conductivity of some aqueous solutions. Part. II.
Mixtures of solutions of sucrose and lithium chloride. A contribution towards
AUTHOR LIST 489
the elucidation of the connexion between ionic mobility and the fluidity of
the solution.
T-25.00^
Gregory ^MacGregory, q. v.
687. H. Greinacher. Phys. Zeit. 10, 086-^7, (1G09).
Ueber die Erhdhung der Leitf&higkeit fltkasiger Dielektnka durcfa OrStrahlen.
H. Gross see £. Lellmann.
688. (H. Grossmann. Zeit. Anorg. Ghem. 54, 4(M4, (1907).
Zur Komplexbildung in Molybd&ns&urelOsungen.)
H. Grossmann see N. Caro.
689. H. Grossmann, P. y. d. Forst Ber. Deutsch. Ghem. Ges. 37, 4141-
4144, (1904).
Die Doppelcyanide des Quedodlbers.
T=25^
690. H. Grossmann, P. y. d. Forst. Zeit. Anorg. Ghem. 43, 94-110, (1905).
Die Doppelcyanide des Kupfers.
T=25^
691. H. Grossmann, H.Krimer. Ber. Deutsch. Ghem. Ges. 36, 1606-1610,
(1903).
Ueber die Slinwirkung organischer S&uren auf die Leitf&higkeit der gelben
Molybd&ns&ure. [The measurements are given more fully in 692 and 1023. ]
R. O. xaq.-1.5-2XlO-«; sub.
692. H. Grossmann, H. Krimer. Zeit. Anorg. Ghem. 41, 43-60, (1904).
HHMeas. A. Roaenheiin,
Ueber einige Komplexverbindungen der Molybd&n- und WoKrams&ure mit
organischen Sfiuren. [See also 1023.]
T = 15**and25^ R. O.
H. Grilnbaum see A. Rosenheim.
E. Griineisen see F. Kohlrausch.
698. P. Griitzner. Arch. Gesammt. Physiol. 68, 168-175, (1897).
Die Gasetnausf&llung, ein einfaches Mittd, um die Acidit&t von S&uren su
bestimmen.
694. L. Gmnmach. .\nn. Physik. (4), 28, 217-258, (1909).
Bestimmung der Oberfl&chenspannung und anderer physikalischer Konstanten
von Essigs&ure-Wassermischungen.
T « 19.00* and 20.00^ [R. O.? ]
696. F. Gudzent Zeit. Physiol. Ghem. 60, 25-37, (1909).
PhysikaUscb-chemische und chemische Untersuchungen Uber das Verhalten
der Hams&ure in Ldsungen.
T -37**. R. O. Xi8 aq. -O.O-l.OXlO"'; sub. unless otherwise stated.
696. F. Gudzent Zeit. Physiol. Ghem. 60, 3S-68, (1909).
PhysikaUscb-chemische Untersuchungen Uber das Verhalten der hamsauren
Salze in Ldsungen.
R. O. Xi8 aq. =0.9-1.0X10^.
A. Giinther see T. PauL
697. (G. GttgUelmo. Atti Accad. Torino. 17, 543-565, (1881-1882).
Sull'uso dell'elettrometro nella misura della resistenza dei liquidi col metodo di
Mance e con quello di Wheatstone e sulla resistenza di alcune soluzioni al-
oooliche di potassa.) Abstracted in Beibl. Ann. Physik. 6, 803-804, (1882).
[Inorganic, j
698. J. Guinchant. Gompt. Rend. 120, 1220-1223, (1895).
Gonductibilit^ de quelques others /^o^toniques. [Given in 700.1
T=25^ [S.U.I
440 AUTHOR LIST
699. J. Guinchant Compt. Rend. 121, 71-73, (1895).
Preparation et conductibilit^ de nouveaux others cyanom^thiniques. [Given
in 700.]
T=25^ [S.U.I
700. J. Guinchant Zeit. Phys. Chem. 24, 174-177, (1897).
Studien Uber die sauren Eigenschaften der Methen- und MethLnverbindungen.
R. O. [This ifi an abstract of Guinchant's thesis, Paris, (1897). The
measurements are given in 698 and 699 together, but A of the sodium
salts is given in full here. ]
701. J. Guinchard. Ber. Deutech. Chem. Ges. 32, 1723-1741, (1899).
Ueber die farbigen Salze aus Violurs&ure und anderen ringfdrmigen Oximi-
doketonen. [Given in 702 with more details. ]
T«0*to64.1^
702. J. Guinchard. Dis. Uppsala. (1899).
Beitriige zur Kenntniss labiler Atomgruppirungen und ihrer Umlagerung.
[Same as 701 with more detailed measurements. ]
J. M. Guthrie see J. S. Ford.
708. P. A. Guye, S. Bogdan. Arch. Sci. Phys. Nat. (4), 15, 502-513, (1903).
M6thodes rapides pour Fanalyse physico-chimique des liquides physiologiques.
[Probably same as 218. ]
704. E. Gyr. Dis. Lausanne. (1907).
Conductibilit^s limites dans quelques dissolvants inorganiques. [Same as 486. ]
T=-16'*=fc0.2^ S. U. X S02sub.
£. Gyr see P. Dutoit
H.
K. Haas see C. Billow.
Mean, XL. Haas; see 1080, 1081.
706. H. HXdrich. Zcit. Phys. Chem. 12, 476-497, (1893).
Optiscfaes Drehvermdgen und elektrolytische Dissociation.
R. Haertel see H. Stobbe.
Meaa, HSuptli; see 77.
706. (A. Hagenbach. Ann. Physik. (4), 5, 276-312, (1901).
Ueber die Aenderung der Leitf&higkeit von Salzldsungen in fittssiger schwefliger
S&ure mit der Temperatur bis Uber den kritischen Punkt. Elektrolytische
Ijeitung in Gasen und D&mpfen. Absorptionsspectra von Losungen mit
Jodsalzen.) [Inorganic]
707. (A. Hagenbach. Phys. Zeit. 1, 481-483, (1899-1900).
Ueber elektrolytische Leitimg in Gasen beim kritischen Punkte.) [Inorganic. ]
708. F. Haiser, F. Wenzel. Monatsh. 30, 377-^386, (1909).
Ueber Kamin und Inosins&ure. [Same as 708a.]
T=25°,
708a. F. Haiser, F. Wenzel. Sitzber. Akad. Wien. 118, 2b, 153-162, (1909).
Ueber Kamin imd Inosins&ure. [Same as 708.]
709. W. Hallwachs. Ann. Physik. (3), 68, 1-45, (1899).
Ueber ein Doppeltrogrefractometer imd Untersuchimgen mit demselben an
Ldsungen von Bromcadmium, Zucker, Di- und Trichloressigsaure, sowie
deren Kaliumsalze. [Same as 710.]
T = 12.5^
710. W. Hallwachs. Sitzber. Ges. Isis. Dresden. (1898), 49-81.
Ueber ein Doppeltrogrefractometer, etc. [Same as 709.]
W. Hallwachs see F. Kohlrausch.
F. J. Hambly see J. Walker.
Meoi, F. Hamburger; see 1616.
AUTHOR LIST 441
711. (W. Hampe. Chem. Ztg. 11, 816, (1887).
Ueber die electrolytische LeitungiBfahigkeit der Haloidverbindungen.)
712. (W. Hampe. Chem. Ztg. 11, 846-847, (1887).
Ueber die electrolytische Leitimgsf&higkeit der Haloidverbindimgen.)
713. (W. Hampe. Chem. Ztg. 11, 904r-905, (1887).
Ueber die electrolytiaohe Leitungsf&higkeit der Haloidverbindungen.)
714. (W. Hampe. Chem. Ztg. 11, 934r-936, (1887).
Ueber die electrolytische Leitimgsf&higkeit der Haloidverbindmigen.)
715. (W. Hampe. Chem. Ztg. 11, 1109-1110, (1887).
Ueber die electrolytische Leitmigsf&higkeit der Haloidverbindungen.)
[Quoted. ]
716. (W. Hampe. Chem. Ztg. 11, 1158, (1887).
Ueber die electrolytische Leitungsfahigkeit der Haloidverbindungen.)
717. (W. Hampe. Chem. Ztg. 11, 1549-1550, (1887).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindimgen.)
718. (W. Hampe. Chem. Ztg. 12, 4r-5, (1888).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindungen.)
719. (W. Hampe. Chem. Ztg. 12, 23-24, (1888).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindungen.)
720. (W. Hampe. Chem. Ztg. 12, 106, (1888).
Ueber die electrolytische Leitimgsf&higkeit der Haloidverbindimgen.)
721. (W. Hampe. Chem. Ztg. 12, 122, (1888).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindungen.)
722. (W. Hampe. Chem. Ztg. 12, 140, (1888).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindungen.)
728. (W. Hampe. Chem. Ztg. 12, 171-173, (1888).
Ueber die electrolytische Leitungsf&higkeit der Haloidverbindungen.)
724. M. Handa. Ber. Deutsch. Chem. Ges. 42, 3179-3182, (1909).
Zur Charakterisierung von Indicatoren.
724a. H. Handovsky. Biochem. Zeit. 25, 510-538, (1910).
Untersuchungen Uber physikalische Zustandsanderungen der Kolloide. X.
Mitteilung. Die Einwirkung von organischen Basen und amphoteren Elek-
trolyten auf Eiweiss.
T-25^
H. Handovsky see W. Pauli.
725. A. Hantzsch. Ann. Chemie. 296, 84-94, (1897). Meaa. H. Ley.
Ziur Kenntniss der S&ureamide.
T=0^
726. (A. Hantzsch. Ann. Chemie. 296, 111-119, (1897).
Bemerkungen Uber Nitramid.) [Corrects 765.]
727. A. Hantzsch. Ber. Deutsch. Chem. Ges. 22, 2827-2840, (1889).
Meas. W, Oatwald,
Umwandlung von Derivaten des Pentamethylens in solche des Benzols,
Pyiidins und Thiophens.
728. A. Hantzsch. Ber. Deutsch. Chem. Cks. 23, 148a-1489, (1890). Meas.
G, Beihmann,
Zui Spaltung des Pentamethylenringes.
729. A. Hantzsch. Ber. Deutsch. Chem. Ges. 25, 827-841, (1892). Meas.
C. Barth.
Ueber die Spaltungsproducte der Anils&uren.
780. A. Hantzsch. Ber. Deutsch. Chem. Ges, 28, 1734r-1753, (1895).
Diazoniumverbindungen und normale Diazoverbindungen.
T-rand26^
442 AUTHOR LIST
781. A. Hantzsch. Ber. Deutsch. Chem. Ges. 30, 33^^347, (1897). Meas.
W. B, Davidwn.
Zur Kenntniss nomuder Diazoverbindungen.
782. (A. Hantzsch. Ber. Deutsch. Chem. Qes. 32, 575-600, (1899).
Zur Constitutionsbestimmung von Kdrpem mit labilen Atomgruppen.)
[Quoted.]
788. A. Hantzsch. Ber. Deutsch. Chem. Ges. 32, 3066-3088, (1899).
Meas, 0. Graid.
Zur Charakteristik von schwachen S&uren und von Pseudos&uren. [The
values given here are too high; see 788.]
T -0^ 25** and 35**. x aq. not sub.
784. A. Hantszch. Ber. Deutsch. Chem. Ges. 33, 752-760, (1900).
Zur Kenntniss der Salze und Basen aus Triphenyhnethanfaibstoffen.
T-25^
786. A. Hantzsch. Ber. Deutsch. Chem. Ges. 33, 2161-2179, (1900).
Meas. Schamannf Oastoald, Davidson,
Syndiazocyanide und Diazoniumcyanide.
T-0^
786. A. Hantzsch. Ber. Deutsch. Chem. Ges. 35, 265-268, (1902). Meas.
Af . Buchner.
Affinit&tsconstanten einiger Nitramine und Isonitramine.
T=0^and26^
787. A. Hantsch. Ber. Deutsch. Chem. Ges. 36, 2069-2075, (1903).
Ziur Atomwanderung bei Diazoverbindungen. [Corrects 601.]
788. A. Hantzsch. Ber. Deutsch. Chem. Ges. 37, 1076-1084, (1904).
MeoB, W, Graf, S. Pilot, P. Wiegner.
Notiz Uber amphotere Elektrolyte und speciell tiber Kakodylsfiure.
T-25^
789. A. Hantzsch. Ber. Deutsch. Chem. Ges. 37, 2705-2708, (1904).
Berichtigungen zu Hm. v. Zawidzki's Arbeit Uber Kakodyls&ure. [See SOU. ]
740. A. Hantzsch. Ber. Deutsch. Chem. Ges. 38, 1045-1048, (1905).
Zur Molekuhu*gr6sse von Salzen in indifferenten Ldsungen.
741. A. Hantzsch. Ber. Deutsch. Chem. Ges. 38, 2143-2154, (1905).
Ueber Oxonium- und Ammonium- Salze.
T-25^
742. A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 139-153, (1906). Meaa.
F. Hofmann, and Af . Lehmann.
Die Cyanurs&ure als Pseudos&ure.
T=25^
748. (A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 2098-2112, (1906).
Ueber Hm. Euler's Arbeit " Zur Kenntniss der Pseudos&uren.'') [See 618
and 614.]
744. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 330-351, (1907). Meaa.
N, Rosanoff.
Ueber Isomeric von Nitrophenolsalzen und die Existenz von Metachinoiden.
T«25^
746. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 1523-1532, (1907).
Meaa. A. Salway.
Ueber farblose, gelbe und rote Sabse aus Nitroketonen. [Given in 1667.]
746. A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 1556-1572, (1907).
Meaa. W, Praetonua.
Ueber Konstitution und Kdrperfarbe der Nitrophenole und speziell des Nitro-
hydrochinon&thers.
X aq. sub.
AUTHOR LIST 443
747. A. Hantzfldk Bet. Deutsch. Chem. Ges. 42, 69-85, (1G09). Meaa. H.
LeupM.
Polymerie als Uraache der Farbverschiedenheit von Haloidsalzen und Sulfiten.
[Given in 1075.]
T=25^
748. A. Hantzscfa. Zeit. Anorg. Chem. 25, 332-340, (1900).
Ueber den EinflnaB von Nichtelektrolyten anf das Leitvermdgen von Elek-
trolyten.
T=25^
749. (A. Hantzsch. Zeit. Phys. Chem. 56, 57-64, (1906).
Bemerkungen Uber Pseudosauren und amphotere Elektrolsrte.)
760. A. Hantzscfa. Zeit. Phys. Chem. 61, 257-^312, (1907-1908). Meaa.
F. C. R, BergiuSy M. Lehmann.
Ueber den Zustand von Stoffen in abeoluter Schwefelsaure.
T=25'. R. O. X solvent sub.
751. (A. Hantzscfa. Zeit. Phys. Chem. 65, 41-60, (1908-1909).
Ueber den Zustand von Stoffen in abeoluter Schwefelskure.) [For a criticism
of 760 and 751 see 1848 and Oddo, Scandola, Gaz. Chim. Ital. 40, II, 163-209,
(1910); also A. Hantzsch, Gaz. Chim. Ital. 39, II, 512, (1909), and Zeit. Phya.
Chem. 68, 204, (1909).]
A. Hantzsch see S. M. Auld.
W. B. Davidson.
A. Bngler.
H. Euler.
R. C. Fanner.
D. GerilowskL
O. Graiil.
H. Ley.
K. H. Meyer.
752. A. Hantzscfa, A. Barth. Ber. Deutsch. Chem. Ges. 35, 210-226, (1902).
fUMeaa. W, Praetarvus,
Charakteristik von Pseudos&uren durch abnorme Beziehungen zwischen der
Affinitatsconstante und der Hydrol3rse ihrer Salze.
T=0**and25^ x aq.=0.6XlO-«.
753. A. Hantzscfa, X:. S. Caldwell. Zeit. Phys. Chem. 58, 575-584, (1907).
Ueber abnorm grosse lonenbcweglichkeiten.
T=25^
764. A. Hantzscfa, K. S. Caldwell. Zeit. Phys. Chem. 61, 227-240, (1907-
1908). fUMeas, TF. Fischer,
Vergleich von S&uren und Pseudosauren in Pyridinldsung. [The conclusions
and some qualitative statements are given in 321.]
T=25^ R. O.
755. A. Hantzscfa. W. B. Davidson. Ber. Deutsch. Chem. Gres. 29, 1522-
1536, (1896).
Ueber Diazophenole.
T=25^ xaq.=3XlO-«; sub.
756. A. Hantzscfa, C. H. Descfa. Ann. Chemie. 323, 1-31, (1902).
Ueber farbige organische Ferriverbindungen.
T =0° and 25**. x aq. sub.
757. A. Hantzscfa, F. £. DoUfos. Ber. Deutsch. Chem. Ges. 35, 226-265,
(1902).
Charakteristik von Pseudos&uren durch die '' Ammoniakreaction."
T=20**and25^
444 AUTHOR LIST
7S8. A. Hantzsch, W. H. Glorer. Ber. Deutsch. Chem. Gee. 40, 4344-4350,
(1907). Meas. H. Qlover.
Zur KoDstitution und K5rperfarbe von Derivaten der Dioxime des o-Bexuo-
chinons und Naphthochinons. [Same as 644.]
T=25^
769. A. Hantzsch, W. Graf. Ber. Deutsch. Chem. Ges. 38, 2154-2161,
(1905).
Ueber Additionsproducte terti&rer Amine.
T«25^
760. A. Hantzsch, H. Hibbert Ber. Deutsch. Chem. Ges. 40, 150&-1519,
(1907). m Meas. G, Schick.
Ueber Additionsprodukte von Trialkylphoephinen, -arsinen und -stibinen.
T=25° for one compound.
761. (A. Hantzsch, A. HoIL Ber. Deutsch. Chem. Ges. 34, 3430-3445,
(1901).
Ueber das sogen. Sulfimid.) [Inorganic. ]
762. A. Hantzsch, P. C. C. Isherwood« Ber. Deutsch. Chem. Gres. 42,
98^1000, (1909).
Ueber Salze imd Ester der Violurs&ure-Gruppe.
T=25^
768. A. Hantzsch, M. Kalb. Ber. Deutsch. Chem. Ges. 32, 310^-3131,
(1899).
Ueber Pseudoammoniumbasen.
T=0''and25^ x aq.=2.lX10-«.
764. A. Hantzsch, M. Kalb. Ber. Deutsch. Chem. Ges. 33, 2201-2208,
(1900).
Cotamincyanid als Pseudosalz.
T=0°to40^
766. (A. Hantzsch, L. Kaufmann. Ann. Chemie. 292, 317-340, (1896).
Zur Kenntniss der untersalpetrigen Saure.) [Qualitative; see 726.]
T=0^
766. A. Hantzsch, H. Kissel. Ber. Deutsch. Chem. Ges. 32, 3137--3148,
(1899).
Ueber Derivate von Nitros&uren und die Reactionen der Nitrokdrper.
T=25^and0^
767. A. Hantzsch, M. Lehmaim. Ber. Deutsch. Chem. G^es. 33, 3668-
3685, (1900).
Ueber Bisazoxyessigs&ure, Bisazoxymethan und Hydraziessigs&ure.
T=25^
767a. A. Hantzsch, K. H. Meyer. Ber. Deutsch. Chem. Ges. 43, 336-^40,
(1910).
Ueber die Bildung farbloser lonen aus Triphenylmethylbromid. [Part is
same as part of 1260.]
T=25^
768. A. Hantzsch, A. Miolati. Zeit. Phys. Chem. 10, 1-33, (1892).
Ueber die Beziehimgen zwischen der Konfiguration und den Affinitatsgrossen
stereoisomerer Stickstoffverbindungen.
T=0**and25^
769. A. Hantzsch, G. Osswald. Ber. Deutsch. Chem. Ges. 32, 641-650,
(1899).
Ueber Cyanoform.
T=0*and25^
AUTHOR LIST 446
770. A. Hantzschy G. Osswald. Ber. Deutsch. Chem. Gee. 33, 278-^317,
(1900).
Ueber die Umwandlung von Farbbasen in Pseudoammonium-Hydrate, -Cya-
nide und -Sulfons&uren. [Corrected in 686.]
T-0^
771. A. Hantzsch, N. Pictoii. Ber. Deutsch. Chem. Ges. 42, 2119-2128,
(1909).
Ufber den Chromophor der Salze aus Polynitrobenzol-Derivaten.
772. A. Hantzachy A. Rinckenbeiger. Ber. Deutsch. Chem. Gres. 32, 628-641,
(1899).
Ueber Nitroform.
T=0'*and26*.
773. A. Hantzach, R. Robison. Ber. Deutsch. Chem. Ges. 43, 92-^5, (1910).
Notiz fiber Purpursaure.
T=0^
774. A. Hantzsch, M. Schumann, A. Engler. Ber. Deutsch. Chem. Ges.
32, 1703-1716, (1899).
Antidiazohydrate und prim&re Nitrosamine. [Part is same as 1602.]
T=0'*and25^
776. A. Hantzach, O. W. Schultze. Ber. Deutsch. Chem. Ges. 29, 2251-
2267, (1896). Meaa, W, Davidson.
Ueber Isomeric der Nitrokorper.
T=0°and25^
776. A. Hantzach, F. Sebaldt Zeit. Phys. Chem. 30, 258-299, (1899).
Meas. O. Graul,
Ueber den Zustand w&sseriger Ammoniak- und Aminldsungen.
T=0^to50^ ^,
777. A. Hantzschy C. H. Siuiter. Ber. Deutsch. Chem. Ges. 39, 162-166, ^ *
(1906).
Zur Kenntniss der isomeren Nitroso-orcine.
T=25^
778. (A. Hantzach, B. C. Stuer. Ber. Deutsch. Chem. Ges. 38, 1022-1043,
(1905).
Neue Reactionsproducte aus Ammoniak und Sulfurylchlorid.) [Inorganic]
779. A. Hantzach, A. Vagt. Ann. Chemie. 314, 339-369, (1901). HHMeas.
M. Schumann,
Ueber das sogenannte Diazoguanidin.
T=25^
780. A. Hantzach, A. Veit Ber. Deutsch. Chem. Ges. 32, 607-627, (1899).
Zur Kenntniss der Isonitrokdrper.
T=0**and25^
781. A. Hantzach, E. Voegelen. Ber. Deutsch. Chem. Ges. 34, 3142-3163,
(1901). fUMeas, M, Buchner,
Zur Kenntniss der sogenannten Isoamide und der echten Saureamide.
T-25^
782. A. Hantzach, E. Voegelen. Ber. Deutsch. Chem. Ges. 35, 1001-1009,
(1902). iHMeaa. W, PraeUmua,
Charakteristik von Pseudosauren durch Leitf&higkeit in wassrigem Alkohol.
T=25''. X aq. not sub.
783. W. Hardt Dis. Eriangen. (1901).
Spektroskopisches Verhalten und elektrische Leitf&higkeit des Kobaltchlorids
in verschiedenen Losimgsmitteln.
T = 18'*and20^ R. O.
446 AUTHOR LIST
788a. W. B. Hardy. Jour. Physiol. 33, 251-337, (1905-1906).
Colloidal solution. The globulins.
T» 18^ R. O. xaq.=3XlO-«.
W. B. Hardy see T. B. Wood.
784. C. Harries, P. Hohenemser. Ber. Deutsch. Chem. Ges. 41, 255-260,
(1908).
Ueber den monomolekularen Sucdndialdehyd.
[T=20**?l
W. Harrison see W. W. H. Gee.
786. T. Harth. Zeit. Anorg. Chem. 14, 323-353, (1897).
Ueber Quecksilberhalogen-Doppelverbindungen.
£. G. J. Hartley see Berkeley.
786. H. Hartley, N. G. Thomas, M. P. Applebey. Jour. Chem. Soc. 93,
538-560, (1908).
Some physico-chemical properties of mixtures of pyridine and water.
T«0*and25^ R. O. Xoaq. = 1.2XlO-«.
787. K. Hartwig. Ann. Physik. (3), 33, 58-80, (1888).
Die electrische Leitimgsf&higkeit von Ldsungen einiger Glieder der Fett-
s&urereihe in Wasser imd einigen Alkoholen. [See 788.]
T=0*to30^ Hg. U.
788. K. Hartwig. Ann. Physik. (3), 43, 839-840, (1891).
Ueber die moleculare Leitungfsf&higkeit von Ldsungen einiger Glieder der
Fetts&urereihe in Wasser und einigen Alkoholen, sowie der Oxals&ure in
Aethylalkohol. [Chiefly a recalculation of the measurements in 787.]
T = 18^
789. K. Hartwig. Progr. NQmberg. (1886). Abstracted in Beibl. Ann.
Physik. 11, 101-102, (1887).
Die electrische LeitungsfUhigkeit der wfisserigen und alkoholischen Lteungen
des Phenols und der Oxals&ure.
T-18*to41^ Hg. U.
790. (F. Hasenoehrl. Sitzber. Akad. Wien. 105, 2a, 460-476, (1896).
Ueber den Temperaturooefficienten der Dielektricit&tsconstante in FlGssig-
keiten und die Mosotti-Clausius'sche Formel.)
791. (R. V. Hasslinger. Monatsh. 28, 173-207, (1907).
Ueber das Wesen metallischer und elektrolytischer Leitung.) [Inorganic]
A. HausdOrf er see C. A. Bischoff.
792. F. De F. Heald. Science. (N. S.), 15, 457, (1902).
The electrical conductivity of plant juices. [Qualitative.]
798. W. Hechler. Ann. Physik. (4), 15, 157-173, (1904).
Fluiditftt imd Leitf&higkeit einiger konzentrierter w&sseriger Salildsungen
unterO^ [Same as 794 with some corrections.]
T= -20.86* to ^-7.17^ R. O.
794. W. Hechler. Dis. MOnster. (1904).
Fluiditat und Leitffihigkeit, etc. [Same as 798 except for some slight
errors.]
J. Hecht see R. Wegscheider.
795. £. P. Hedley. Ber. Deutsch. Chem. G^es. 41, 1195-1204, (1908).
Spektroscopische Untersuchung isomerisierbarer Nitrokdrper im Ultraviolett.
[Measurements given in 796.]
796. £. P. Hedley. Dis. Leipsig. (1908).
Spektroskopische Untersuchung, etc. [Qualitative statement given in
795.]
T«0* and 25*. R. O. x aq. =0.7 -1.0X10-*; sub.
AUTHOR LIST 447
797. B. Heiten. Die. Bonn. (1907).
Ueb^ Saccharin und Saccharinate und ihre Bildungpsgeechwindigkeit aus
Zuckerarten unter dem Einfliim von Alkalien. [Same as 1498.]
T«25^ R. O. xaq. sub.
B. Heiten see B. Rimbach.
B. Held see B. Beckmann.
798. (6. Heller. Ann. Chemie. 332, 247-804, (1904). f» Meas, R. Emrich.
Ueber die E^wirkung von Dichloressigs&ure auf Anilin und die Toluidine.)
[See 499 for measurement. A correction is made here. ]
6. Heller see B. Deussen.
799. A. de Hemptinne. Zeit. Phys. Chem. 31, 35-41, (1899).
Sur lee vitesses de reaction.
T about 24*.
H6nault see Dony-Hfoault.
800. (L. J. Henderson. Am. Jour. Physiol. 21, 173-179, (1908).
Concerning the relationship between the strength of acids and their capacity
to preserve neutrality.)
801. (L. J. Henderson. Am. Jour. Physiol. 21, 427-448, (1908).
The theory of neutrality regulation in the animal organism.) [Inorganic]
802. (L. J. Henderson. Jour. Am. Chem. Soc. 30, 954r-960, (1908).
A diagrammatic representation of equilibria between acids and bases in solu-
tion.) [Quoted; and theoretical.]
808. L. J. Henderson. Ergebn. Physiol. 8, 254-^325, (1909).
Das Gleichgewicht zwischen Basen und Sauren im tierischen Organismus.
808a. (L. J. Henderson, A. Forbes. Jour. Am. Chem. Soc. 32, 687-^9,
(1910).
On the estimation of the intensity of acidity and alkalinity with dinitro-
hydroquinone.) [Indicators.]
804. L. J. Henderson, K. Spiro. Biochem. Zeit. 15, 105-113, (1908-
1909).
Zur Kenntnis des lonengleichgewichts im Organismus. I. Teil. Ueber Basen-
und S&uregleichgewicht im Ham.
806. H. Henkel. Dis. Berlin. (1905).
Beitrfige zur Kenntnis der physikalisch-chemischen Eigenschaf ten verddnnter
Glyoerinlosungen und zur Analyse derselben. [Same measurements in 806. ]
T = 18*. R. O. xi8 aq. = 1.36 XlO-«; sub.
806. H. Henkel, A. W. Roth. Zeit. Angew. Chem. 18, II, 1936-1941,
(1905).
Chemische und physikalische Methoden zur Analyse verdCUmter rein wasser-
iger GlycerinlGsungen. [Same as 806. ]
T « 18*. R. O. xi8 aq. - 1.36 X 10-«; sub.
807. V. Henri, L. des Bancels. Compt. Rend. 136, 1088-1090, (1903).
Loi de Taction de la trypeine sur la gelatine.
T-44*.
808. V. Henri, L. des Bancels. Compt. Rend. 136, 1581-1582, (1903).
Loi de Taction de la trypsine sur la gelatine.
T=44*.
809. F. Henrich. Ber. Deutsch. Chem. Ges. 37, 1406-1415, (1904).
Ueber die Constitution der Orsellins&ure. ^
T«25®. '
810. F. Henrich. Monatsh. 18, 142-188, (1897).
Ueber zwei Modificationen des Mononitrosoorcins. [Same as 811.]
811. F. Henrich. Sitzber. Akad. Wien. 106, 2b, 155-201, (1897).
Ueber zwei Modificationen, etc. [Same as 810.]
448 AUTHOR LIST
818. P. Henry. Zeit. Phys. Chem. 10, 96-129, (1892).
Ueber die wechfielseitige Umwandlung der Laktone und der Ozysfturen.
H. Hehstock see W. A. Bone.
813. H. Henstock^ C. H. 6. SpranUing. Jour. Chem. Soc. 91, 354r-360,
(1907).
aa7-Trimethyl- and 0077- tetramethyltricarballylic acids and a7-dimethyl-
butane- a/3 ^tricarboxylic acid.
T-25°.
814. H. Henstock, B. B. WooUey. Jour. Chem. Soc. 91, 1954-1958, (1907).
The action of phosphorus pentachloride on hydroxytrimethylsuccinic ester.
1 : 2-Dimethylcyclopropane-l : 2-dicarboxylic acid. (1 : 2-Dimethyltrime
thylene-1 : 2-dicarfooxylic acid).
T=25*.
B. Hepner see A. Michaelifi.
C. Herty see A. Werner.
816. C. H. Herty, R. O. E. Davis. Jour. Am. Chem. Soc. 30, 1084-1089,
(1908).
The character of the compound formed by the addition of ammonia to ethyl-
phospho-platino-chloride.
T=25^
J. Hertzmann see A. Rosenheim.
816. H. Herwig. Ann. Physik. (2), 159, 61-93, (1876).
Ueber den Durchgang starker Inductionsstr6me durch FlQssigkeiten.
Meas, Herwig; see 847.
817. 6. Heiin. Dis. Leipzig. (1897). Meaa. Smith.
Ueber die Producte der Condensation des Acetophenons mit dem Diaethyl-
Ester der Bemsteinsfture und Malonsaure unter dem Einfluss des Natrium-
aethylates.
817a. G. ▼. Hevesy. Zeit. Elektrochem. 16, 672-673, (1910).
Ueber die Elektrolyse in P3rridin geloster Erdalkalijodide.
T=26°.
818. J. T. Hewitt Analyst. 23, 85^90, (1908).
The constitution of indicators used in acidimetry.
819. A. Heydweiller. Ann. Physik. (4), 28, 503^12, (1909).
Ueber lonisationswarme und lonisationskonstante des Wassers.
Hg.U.
820. A. Heydweiller. Ann. Physik. (4), 30, 873-904, (1909). Meaa. J.
Wigger.
Ueber physikalische Eigenschaften von Ldsungen in ihrem Zusammenhang.
I. Dichte imd elektrisches Leitvenndgen w&sseriger Salsldsungen.
T = 18°. R. O. »
881. (A. Heydweiller. Verhand. Deutsch. Phys. Ges. 11, 37-44, (1909).
Eine einfache Beziehung zwischen Dichte und Dissoziationsgrad waaseriger
Salzldsungen.) [Quoted. See 1714.]
A. Heydweiller see F. Kohlnuisch.
H. Hibbert see A. Hantzsch.
" '' see A. Michael.
S. Higuchi see W. L5b.
822. J. HUdebrand. Zeit. Elektrochem. 14, 349^53, (1906).
Das Kdnigsche Spektralphotometer in neuer Anordnung und seine Verwen-
dung zur Bestimmung chemischer Gleichgewichte.
T-25*.
T. P. Hilditch see J. N. CoUie.
AUTHOR LIST 449
822a. A. £. HOI. Jour. Am. Chem. Soc. 32, 1186-1193, (1910).
The inooDstancy of the solubility product.
T =25.00'' *0.03^ xisaq. «2.9XlO-«.
823. E. G. Hill. Jour. Chem. Soc. 89, 1273-1289, (1906).
The hydrolysiB of ammonium salts by water.
T = 18**. xi8 aq. = 1 .5 X 10-«, or less.
824. (G. D. Hmrichs. Ck>mpt. Rend. 143, 549-550, (1906).
La m^caiiique de Tionisation par solution.)
F. W. Himichsen see E. Rasch.
826. W. ma, T. Paul. Zeit. Physiol. Chem. 31, 1-12, (1900-1901).
Physikalisch-chemische Untersuchungen tlber das Verhalten der Hams&ure
und ihrer Sake in Losimgen.
T=b18^ R. O. X aq. — 1.0X10~*; measurements given both with and
without sub.
826. £. Hjelt Ber. Deutsch. Chem. Ges. 25, 488-491, (1892). Meaa, U.
Colian.
Allylathyl- und Allylmethylbemsteins&uren. [For tables of /i and of k of the
allylethyl succinic acids, see 880 and 1888.]
827. E. Hjelt Ber. Deutsch. Chem. Ges. 25, 524-525, (1892). Meas. U.
Colian.
Notiz uber Benzylalkohol-o-carbonsaure.
T=25^
828. E. Hjelt Ber. Deutsch. Chem. Ges. 29, 1855-1859, (1896). Meas.
R. Malmstr&m.
Ueber einige alkylsubstituirte Valerolactone. [For full tables of /i and k see
881. This only gives k. ]
829. (E. Hjelt Ber. Deutsch. Chem. Ges. 31, 1844-1847, (1898).
Ueber die relative Verseif ungsgeschwindigkeit der Ester der normalen Sauren
der Ozals&urereihe.) [Quoted. ]
880. E. Hjelt Ofvers. Finska Vet.-Soc. Forhand. 34, 7-10, (1891-1892).
Meaa. U. CoUan.
Undersdkningar ofver 83rnmietrisk allyl-etylbemstenssjrra. [Given in 1888.
Same as part of 826, but contains full tables of /i and k. ]
881. E. Hjelt Ofvers. Finska Vet.-Soc. Forhand. 38, 132-139, (1895-1896).
Meas. R. Malmstram.
Ueber einige alkylsubstituirte Valerolactone. [Same as 828 but contains full
tables of /i and k. ]
E. Hjelt see C. A. Bischoff.
882. (P. Hodge. Phys. Rev. 26, 540-541, (1908).
A study of photo-electric cells containing a fluorescent electrolyte.) [A sum-
mary of 838.]
833. P. Hodge. Phys. Rev. 28, 25-44, (1909).
An experimental study of photo-active cells with fluorescent electrolytes. I.
T»0° and room temperature.
884. B. Hodgson. Phil. Mag. (6), 18, 252-258, (1909).
The conductivity of dielectrics under the action of radium rays.
836. R. H6ber. Arch. Gesammt. Physiol. 81, 522-539, (1900).
Ueber die Hydroxylionen des Blutes.
836. R. H6ber. Arch. Gesammt. Physiol. 99, 572-593, (1903).
Ueber die Hydroxylionen des Blutes.
886a. R. H6ber. Arch. Gesammt. Physiol. 133, 237-253, (1910).
Eine Methode die elektrische Leitf&higkeit im Innem von Zellen zu
messen.
460 AUTHOR LIST
836b. (R. HOber. Zeit. Elektrochem. 16, 681-686, (1910).
Fortschritte in den Beziehungen zwischen phyBikalischer Chemie und Physiol-
ogie. II. Die Beteilung von Wasserstoff- und Hydroxylionen bei physiolo-
gischen Vorgangen.)
887. (J. H. van't Hoff. Zeit. Phys. Chem. 18, 300-304, (1895).
Ueber das Verdtinnungsgesetz bei Salzen.) [Quoted.]
Meas, J. H. van't Hoff; see 640.
888. J. H. van't Hofif, L. T. Reicher. Zeit. Pbys. Chem. 2, 777-781, (1888).
$ Mei8, J. F, Eykmann.
Ueber die Dissociationstheorie der Elektrolyte.
T = 14.1'' and 19.1". Hg. U. x aq. not sub.
889. J. H. van't Hoff, L. T. Reicher. Zeit. Phys. Chem. 3, 19&-202,
(1889).
Beziehung zwischen osmotischem Druck, Gefrierpunktsemiedrigung und
elektrischer Leitf&higkeit.
T«14^ Hg. U. xaq. sub.
Meas. F. Hofmann; see 742, 1187.
840. K. A. Hofmuuii H. Kinnreuther, A. Thai. Ber. Deutsch. Chem. Ges.
43, 183-188, (1910).
Carboniumperchlorate (2. Mitteilung) und das Ldsungsvermdgen der gechlor-
ten Aethane.
T = 17^18**andl9^
P. Hohenemser see C. Harries.
C. Hohmann see W. Nemst
L. Holbom see F. Kohlrausch.
841. K. Holdermann. Arch. Pharm. 243, 600-617, (1905).
Ueber Quecksilberoxycyanid.
T =25". ^25 aq. «6.6 XlO~^; measurements made with and without sub.
A. Holl see A. Hantzsch.
842. R. J. Holland. Ann. Physik. (3), 50, 261-292, (1893).
Ueber die Aenderung der electrischen Leitfahigkeit einer Losimg durch Zusats
von kleinen Mengen eines Nichtleiters.
T = 18". Hg. U.
848. C. Hollander. Dis. MOnchen. (1902). Meas, V. Rothmund.
Synthese der Ecgoninsaure. Studien zur Synthese des Hygrins. [Same as
1078.]
T=25".
C. Hollander see R. Willstiltter.
844. A. F. HoUeman. Rec. Trav. Chim. 14, 121-130, (1895).
Recherches sur le ph6nylnitrom^thane.
T=24.9".
846. A. F. HoUeman. Rec. Trav. Chim. 16, 162-171, (1897).
Sur les acides nitrobarbit\urique et dim^thylnitrobarbiturique.
T=24.5"to25.0".
846. A. F. HoUeman. Rec. Trav. Chim. 21, 56-58, (1902). [Meas, O. L.
Voerman?]
Quelques observations sur Facide chloro-amidobenzolque.
R. O.
847. A. F. HoUeman. Rec. Trav. Chim. 21, 432-447, (1902). ft^Meas.
Herwig.
Sur la preparation des dinitroph^nob et des dinitranisols, et sur qudques-unes
de leurs propri^tds physiques.
T=25.0^
AUTHOR LIST 461
848. A. F. HoUeman. Zeit. Phys. Chem. 12, 125-139, (1893).
Bestimmungen der LGslichkeit sogenannter unlOslicher Salze.
T-irto26^ S. U. xaq.-8Xl(H; sub.
Meas. HoUeman; see 79, 887.
849. A. F. Hollemani^B. R. de Bruyn. Rec. Tray. Chim. 20, 380-364,
(1901).
Sur la oonductdbilit^ ^ectiique das addes chloio- et bromonitrobensolques.
A. F. HoUemaiiy H. A. Siiks, see 1828.
A. F. HoUeman, 6. L. Voennan, see 1812.
860. B. Hobnbefg. Ann. Chemie. 353, 131-138, (1907).
Ueber MethintrithioglyooLs&ure.
861. B. Hobnberg. Ann. Chemie. 359, 81-99, (1908).
Organische Polysulfide.
T=25^ R. O.
862. B. Hobnbefg. Jour. Prakt. Chem. (2), 71, 264r-295, (1905).
Esters&uren von schwefelsubstituierter Kohlens&ure mit aliphatischen AUco-
hols&uren.
T=25^ X aq. = 1.3X10-«; not sub.
868. B. Hohnb^. Jour. Prakt. Chem. (2), 75, 169-187, (1907).
Esters&uren von schwefelsubstituierter Kohlens&ure mit aliphatisdien Alko-
hols&uren.
864. B. Hobnberg. Jour. Prakt. Chem. (2), 79, 253-270, (1909).
Esters&uren von schwefelsubstituierter Kohlens&uren mit aliphatischen Alko-
hols&uren.
866. B. Hobnbefg. Zeit. Phys. Chem. 62, 726-730, (1908).
Zur Kenntnis der amphoteren Elektrolyte.
T » 25.0*. X aq. not over 2 X 10-«.
866a. B. Hobnberg. Zeit. Phys. CJhem. 70, 153-157, (1910).
Ueber den amphoteren Charakter der Kakodyls&ure.
T-25*. Xj5aq.-1.4-1.5XlO-«.
860. B. Hobnberg, K. Mattisson. Ann. CJhemie. 353, 123-130, (1907).
Zur Kenntnias einiger Mercaptals&uren.
R. O.
867. (J. Hobnes, P. J. Sageman, Jour. Chem. Soc. 95, 1919-1943,
(1909).
Contributions to the theory of solutions.)
£. Holzweiflsig see H. Ley.
868. (S. Hoakbig. Phil. Mag. (6), 7, 469-184, (1904).
The electrical conductivity and fluidity of solutions.) [Inorganic]
869. T. van Hove. Bui. Acad. Belg. (1909), 282-294.
fitude dynamique de deux d^riv^ alkyl69 de Tacide phosphorique.
T-25*.
869a. H. B. Howe. Phys. Rev. 30, 453-459, (1910).
The electrical conductivity of fluorescent anthracene vapor.
T=200''to250*.
860. W. T. H. Howe. Am. Chem. Jour. 18, 390-401, (1896).
On the existence of two orthophthalic acids. [Untrustworthy. See Am. Chem.
Jour. 18, 829.]
86L F. H. Howies, J. F. Thofpe. Proc. CJhem. Soc. 15, 103-104, (1899).
Meas. Lidbwry.
/3-Isopropylglutaric acid.
862. (W. Huiakamp. Zeit. Physiol. Chem. 34, 32-54, (1901-1902).
Ueber die Electrolyse der Salze des Nucleohistons und Histons.)
462 AUTHOR LIST
868. E. Humphrey. Dis. ZOrich. (1901).
Ueber die BindungsBtelle der Metalle in ihren Verbindungen und ttber Dini-
tritodi&thylendiaminkobaltisabse. [Same as 1948.]
£• Humphrey see A. Werner.
D. Hurmuzescu see L. Benoist
864. (M. Huybrecbts. Ann. Chim. Phys. (8), 11, 68-101, (1907).
Sur la Vitesse des ions des Electrolytes; sulfate de magndsium et acide sulfurique
en solutions aqueuses dilutes.) [Inorganic]
K. Ingebrechtsen see H. Goldschmidt.
H. Ingle see J. Thiele.
866. J. K. H. Inglis, L. E. Knight. Jour. Chem. Soc. 93, 1595-1600, (1908).
The conductivities of the a-Oximino-fatty acids.
T«26^ [R. 0.1 xaq.-2.lXlO-«.
866. J. K. H. IngUs, L. E. Knight. Proc. Chem. Soc. 24, 191, (1908).
The conductivities of the a-oximino-fatty acids. [Qualitative. A summary
of 866.]
W. Isajew see N. Zelinsiky.
Isaposhmkow see Sapoznikov.
P. C. C. Isherwood see A. Hantzsch.
867. H. Itzig. Dis. Erlangen. (1899).
Ueber einige complexe Salze der Wein- und Aepfels&ure von hoher specifischer
Drehung. [Same as 1521.]
T=25*.
H. Itzig see A. Rosenheim.
Izgaruishev see Izgaryiev.
N. Izgaiysev see N. Zelinsiky.
J.
L. L. Jackson see K. Auwers.
868. A. Jacob. Dis. Heidelberg. (1894). Meas, H, Wialicenus.
Ueber zwei stereochemisch isomere Butantetracarbons&uren. [Same as 66
for acids, with tables of /i- 1
A. Jacob see K. Auwers.
869. C. A. Jacobson. Dis. Johns Hopkins. (1908).
The conductivity and ionization of electrolytes in aqueous solutions as con-
ditioned by temperature, dilution and hydrolysis. [Same as 911.]
T=0'*to36°. xaq. sub.
C. A. Jacobson see H. C. Jones.
870. (G. Jlger. Sitzber. Akad. Wien. 104, 2a,.408^125, (1895).
Ueber die elektrolytische Leitf&higkeit yon wasserigen Ldeungen, inbesondere
deren Abh&ngigkeit von der Temperatur.) [Inorganic. ]
871. (G. Jlger. Sitzber. Akad. Wien. 104, 2a, 671-^79, (1895).
Zur Theorie der Dissociation der Gase.)
872. G. Jaff«. Ann. Physik. (4), 25, 257-284, (1908).
Ueber die lonisation flUssiger Dielektrika durch Radiumstrahlen.
878. G. Jaff«. Ann. Physik. (4), 28, 326-370, (1909).
Die elektrische Leitf &higkeit des reinen Hexans.
T=0^to40^
AUTHOR LIST 458
878a. G, Jaff4, Ann. PhyBik. (4), 32, 148-178, (1910).
Ueber die spezifische Geechwindigkeit und Wiedervereinigung der lonen in
Hexan.
874. G. Jaff«. Jour. Phys. (4), 5, 263-270, (1906).
Sur la conductibilit^ ^lectrique de Pother de p6trole sous Taction du radium.
876. H. Jahn. Zeit. Phys. Chem. 16, 72-90, (1895). Meas, E, Sckrdder.
Ueber die Abh&ngigkeit des Dissociationszustandes einiger S&uren der Fett-
reihe von der Temperatur.
T»10**to64^* 0.1^ 8. U. xaq. sub.
876. (H. Jahn. Zeit. Phys. Chem. 58, 641-658, (1907).
Ueber die Wanderungsgeschwindigkeit der lonen in verdCUmten Ldsungen.)
[Inorganic]
877. A. A. Jakowkin. Zeit. Phys. Chem. 29, 613-657, (1899).
Ueber die Hydrolyse des Chlors.
T=25^and0^
877a. (A. A. Jakowkin. Zeit. Phys. Chem. 70, 158-197, (1910).
Zur Theorie der Losungen.)
878. A. JappeUi. Zeit. Biol. 51, 435-459, (1908).
Untersuchungen Uber die Speichelabsonderung. IV. Einfluss einiger Nicht-
Elektrolyten auf die physiko-chemischen Eigenschaften des Blutes und des
Speichels und auf die Speichelsekretion.
A. JappeUi see F. Bottazzi.
** " see F. Bottazzi, G. Buglia.
879. G. JappeUi. Zeit. Biol. 48, 398-431, (1906).
Ueber die physiko-chemischen Bedingungen der Speichelabsonderung.
880. G. JappeUi. Zeit. Biol. 51, 42-78, (1908).
Untersuchungen tkber die Speichelabsonderung. II. Speichelvarietaten und
Einfluss des Reizungsortes auf die physiko-chemischen Eigenschaften des
Unterkieferspeichels.
881. G. JappeUi. Zeit. Biol. 51, 127-176, (1908).
Untersuchungen tkber die Speichelabsonderung. III. Einfluss der Frequenz,
Intensitat imd Dauer der elektrischen Reize auf die physiko-chemischen
Eigenschaften des Speichels.
T=37^
881a. A. Jaques. Trans. Faraday Soc. 5, 225-243, (1910).
Contributions to the study of ionisation in aqueous solutions of lead acetate
and cadmium acetate.
T=25^
882. G. F. Jaubert. Ber. Deutsch. Chem. Ges. 28, 1578-1585, (1895).
Meas, A. Miolati.
Ueber Beziehungen der Safranine zu den Mauvelnen und InduHnen.
T-25^
888. (G. Jaumann. Ann. Physik. (4), 3, 578-617, (1900).
Zur Theorie der Ldsungen.) [Same as 884.]
884. (G. Jaumann. Sitzber. Akad. Wien. 109, 2a, 512^553, (1900).
Zur Theorie der L^ungen.) [Same as 833.]
K. Jaunsnicker see C. A. Bischoff.
W. P. Javorskij see J. I. Michajlenko.
886. P. Jehl. Dis. Strassburg. (1901).
Ueber die sechs stereoisomeren Phenylparacons&uren. [Same as 679.]
T-20^ R. O.
Meas, P. Jehl; see 679.
464 AUTHOR LIST
886. S. M. j5rgMiBeii. Zeit. Anorg. Chem. 19, 109-157, (1899). Meat. E,
Petersen,
Zur Konstitution der Kobalt-, Chrom- und Rhodiumbaaen.
T=25^
F. M. G. Johnson see J. W. Walker.
887. F. M. 6. Johnson, D. Mcintosh. Jour. Am. Chem. See. 31, 1138-1144,
(1909).
Liquid chlorine.
T below -34^
J. M. Johnson see S. F. Acree.
888. J. Johnston. Ber. Deutsch. Chem. Ges. 37, 3625^3627, (1904).
Ueber den amphoteren Charakter der Kakodylsaure.
T= 25*. xi8aq.= 0.65X10-*; not sub.
889. J. Johnston. Jour. Am. Chem. Soc. 31, 1010-1020, (1909).
The change of the equivalent conductance of ions with the temperature.
890. J. Johnston. Zeit. Phys. Chem. 57, 557-n573, (1906).
Die AfiOuut&tskonstanten amphoterer Elektrolyte. I. Methylderivate der
p- Amidobenzoesaure und des Glykokolls. [Same as 891.]
T=25^ X26aq. =1.5XlO-«; not sub.
891. J. Johnston. Proc. R. Soc. London. A, 78, 82-102, (1906).
The affinity constants of amphoteric electrolytes. 1. -Methyl derivatives of
para-aminobenzoic acid and of glycine. [Same as 890.]
Meas. J. Johnston; see 1868, 1877.
J. Johnston see A. A. Noyes.
892. (S. M. Johnston. Trans. R.Soc.Edinburgh.45, 193-240, (1905-1907).
On the elevation of the boiling points of aqueous solutions of electrolytes.)
[Inorganic. ]
893. (S. M. Johnston. Trans.R.SocEdinburgh. 45, 855-^84, (1905-1907).
The boiling and freezing points of concentrated aqueous solutions, and the
question of the hydration of the solute.) [Inorganic]
T=0^and99.4^
Jolivet see Pelet-Jolivet
894. H. C. Jones. Am. Chem. Jour. 16, 1-19, (1894).
On the combination of sulph\uric acid with water in the presence of acetic
add. [Same as 900.]
T=25^ S. U.
896. H. C. Jones. Am. Chem. Jour. 18, 623-624, (1896).
The conductivity of solutions of acetylene in water. [A correction of 902.]
896. (H. C. Jones. Am. Chem. Jour. 25, 232-249, (1901).
The dissociating power of different solvents. A siunmary.) [A fairly com-
plete review of the literature up to that date. ]
897. (H. C. Jones. Am. Chem. Jour. 35, 445-450, (1906).
The bearing of hydrates on the temperature coefficients of conductivity of
aqueous solutions.) [Same as 899. Inorganic. ]
898. (H. C. Jones. Am. Chem. Jour. 41, 19-^7, (1909).
The present status of the solvate theory.) [A summary of his work done with
others.]
899. (H. C. Jones. Chem. News. 93, 274-275, (1906).
The bearing of hydrates on the temperature coefficients of conductivity of
aqueous solutions.) [Same as 897.]
900. H. C. Jones. Zeit. Phys. Cheo^. 13, 419-436, (1894).
Ueber die Verbindung von Schwefels&ure mit Wasser in Gegenwart von
Essigsaure. [Same as 894. ]
T=25^ S. U.
AUTHOR LIST 466
901. H. C. Jones. Zdt. Phys. Chem. 55, 385-434, (1006).
Die annahemde Zusammensetsuiig der Hydrate, weiche von verschiedenen
Elektrolyten in w&aBeriger Ldeung gebildet werden. [This seems to be a
summary of his previous work with others. ^See 903 and 910.]
T-0^and25^ 8. U.
901a. (H. C. Jones. Zeit. Phys. Chem. 74, 325-370, (1910).
Im hiesigen Laboratorium wfthrend der vergangenen xwdlf Jahre erhaltene
Anhaltspunkte fUr die Existens von Solvaten in L(teung.) [Conclusions drawn
from work by himself and others. See 894 and the references that follow. ]
H. C. Jones see A. M. Clover.
'' '' '' see M. R. Schmidt
*« " " see G. F. White.
902. H. C. Jones, C. R. Men. Am. Chem. Jour. 18, 375-^77, (1896).
Meas. C. R, AUen.
The conductivity of solutions of acetylene in water. [See correction in 895.]
T is about 0**. S. U.
908. H. C. Jones, H. P. Bassett Am. Chem. Jour. 34, 290^349, (1905).
The approximate composition of the hydrates formed by a number of electro-
lytcB in aqueous solutions; together with a brief general discussion of the re-
sults thus far obtained.
T=0^and25^ S. U.
904. H. C. Jones, E. C. Bingham. Am. Chem. Jour. 34, 481-554, (1905).
ItiMeaa. L. McMaster,
The conductivity and viscosity of solutions of certain salts in mixtures of
acetone with methyl alcohol, with ethyl alcohol, and water. [Same as 187.
Given in 906 and 906. ]
T=25^ S. U.
906. H. C. Jones, E. C. Bingham, L. McMaster. Zeit. Phys. Chem. 57,
193-243, (1906).
Ueber Leitf&higkeit und innere Reibung von LAsungen gewisser Salze in
den Lasimgsmittelgemischen; Wasser, Methylalkohol, Aethylalkohol und
Aceton.
T=:0*and25^ xoaq. = lXlO-«. S. U. [This is a sunmiary of work by
Jones and the others. See 904 and 918. ]
906. H. C. Jones, E. C. Bingham, L. McMaster. Zeit. Phys. Chem. 57,
257-320, (1906).
Ueber Leitf ahigkeit und innere Reibung von Ldsungen gewisser Salse in den
L69ungsmittelgemischen; Waeser, Methylalkohol, Aethylalkohol und Aceton.
T=0° and 25°. S. U. [A continuation of 906. See 992 for correction
regarding priority. ]
907. H. C. Jones, B. P. Caldwell. Am. Chem. Jour. 25, 349-^90, (1901).
Contribution to the study of aqueous solutions of double salts. IV. Iodides,
cyanides, nitrates and sulphates.
T=25^ S. U. xaq.«1.10-3.0Xl0-*; sub.
906. H. C. Jones, C. 6. Carroll. Am. Chem. Jour. 32, 521-^583, (1904).
A study of the conductivities of certain electrolsrtes in water, methyl and ethyl
alcohols, and mixtures of these solvents. Relation between conductivity and
viscosity. [Same as 867. Given in 918.]
T«0''and25°. S. U. x of solvent is sub.
909. (H. C. Jones, J. M. Doofi^. Am. Chem. Jour. 26, 428-453, (1901).
The dissociation of certain acids, bases and salts at different temperatures).
[Same as 467. Inorganic]
T-0•to35^
466 AUTHOR LIST
910. H. C. Jones, F. H. GetnuuL Am. Chem. Jour. 32, 30&-338, (1904).
The existence of hydrates in solutions of certain non-electrol3rtes and the non-
existence of hydrates in solutions of organic acids.
T=0^ S. U.
Oil. H. C. Jones, C. A. Jacobson. Am. Chem. Jour. 40, 355-410, (1908).
The conductivity and ionisation of ele<Strolytes in aqueous solutions as con-
ditioned by temperature, dilution and hydrolysis. [Same as 869.]
T-0% 10% 25** and 35^ S. U. x,6 aq. = 1.6-2.2XlO-«; sub.
918. H. C. Jones, C. F. Lindsay. Am. Chem. Jour. 28, 329-370, (1902).
A study of the conductivity of certain salts in water, methyl, ethyl, and propyl
alcohols, and in mixtures of these solvents. [Same as 1109. Given in 913.]
fi.U.
913. H. C. Jones, C. F. Lindsay, C. 6. CarrolL Zeit. Phys. Chem. 56, 129-
178, (1906).
Ueber die Leitf&higkeit gewisser Salse in gemischten L^sungsmitteln; Wasser,
Methyl-, Aethyl- und Propylalkohol. [A siunmary of 908 and 912.]
T varies. S. U. x aq.= 2-0.8 XlO-«.
914. (H. C. Jones, E. Mackay. Am. Chem. Jour. 19, 83-118, (1897).
A contribution to the study of water solutions of some of the alums.) [In-
organic]
916. (H. C. Jones, E. G. Mahin. Am. Chem. Jour. 41, 433-442, (1909).
The conductivity of solutions of lithium nitrate in ternary mixtures of ace-
tone, methyl alcohol, ethyl alcohol, and water; together with the viscosity
and fluidity of these mixtures.) [Inorganic. ]
916. H. C. Jones, £. G. Mahin. Zeit. Phys. Chem. 69, 38^-418, (1909).
Conductivity and viscosity of dilute solutions of lithium nitrate and cadmium
iodide in binary and ternary mixtures of acetone with methyl alcohol, ethyl
alcohol and water.
T=0^and25^ S. U. Xo aq.«1.2XlO-«.
917. H. C. Jones, L. McMaster. Am. Chem. Jour. 35, 316-326, (1906).
On the formation of alcoholates by certain salts in solution in methyl and
ethyl alcohols.
S. U.
918. H. C. Jones, L. McMaster. Am. Chem. Jour. 36, 325-409, (1906).
The conductivity and viscosity of solutions of certain salts in water, methyl
alcohol, ethyl alcohol, acetone and binary mixtures of these solvents. [Given
in 906 and 906.]
T = 0** and 25^ S. U. x« aq. - 1.5 -2.0 X 10-*.
919. (H. C. Jones, J. N. Pearce. Am. Chem. Jour. 38, 683-743, (1907).
Dissociation as measured by freezing point lowering and by conductivity.
Bearing on the hydrate theory. The approximate composition of the hydrates
formed by a number of electrolsrtes.) [Inorganic]
920. H. C. Jones, C. A. Rouiller. Am. Chem. Jour. 36, 427-487, (1906).
The relative migration velocities of the ions of silver nitrate in water, methyl
alcohol, ethyl alcohol and acetone, and in binary mixtures of these solvents,
together with the conductivity of such solutions.
T=0*»and25°. S. U. Xo aq. = 1.0XlO-«.
921. (H. C. Jones, C. M. Stine. Am. Chem. Jour. 39, 313-402, (1908).
The effect of one salt on the hydrating power of another salt present in the
same solution.) [Inorganic]
982. H. C. Jones, W. R. Veazey. Zeit. Phys. Chem. 61, 641-697, (1907-
1908).
Die Leitf&higkeit und innere Reibung von Ldsungen gewisser Saize in Wasser,
AUTHOR LIST 457
Methylalkohol, AethybUkohol, Aoeton imd binfiren GezniBchen dieser Losungs-
mittd. [Same as 1772.]
T = 0** and 25*'. S. U. xu aq. - 1.&-2.5 X 10-*.
988. H. C. Jones, W. R. Veazey. Zeit. Phys. Chem. 62, 44-58, (1908).
Die Leitf&higkeit und innere Reibung von Tetra&thylammoniumjodid in
Wasser, Methylalkohol, Aethylalkohol, Nitrobencol und bin&ren Gemischen
dieser Lteungsmittel.
T=0*'and25^
984. H. C. Jones, A. P. West Am. Chem. Jour. 34, 357-422, (1905).
A study of the temperature coefficients of conductivity in aqueous solutions
and on the effect of temperature on dissociation. [Same as 1968.]
T=0*'to35^ S. U. xisaq. = 1.5-2.0X10-*.
H. O. Jones see H. J. H. Fenton.
986. (H. O. Jones, O. W. Richardson. Jour. Chem, Soc. 81, 1140-1158,
(1902).
The decomposition of oxalacetic acid phenylhydrazone in aqueous and acid
solutions, and a new method of determining the concentration of hydrogen
ions.) [A correction of 661 and 663. See also 986 and 987.]
986. H. O. Jones, O. W. Richardson. Jour. Chem. Soc. 81, 1158-1160,
(1902).
The dissociation constants of oxalacetic add and its phenylhydrazone. [Same
as 989. See correction in 1991.]
T=25^
987. (H. O. Jones, O. W. Richardson. Proc. Cambridge Phil. Soc. 11,
337-339, (1900-1902).
Note on a method for determining the concentration of hydrogen ions in solu-
tion.) [Corrects 663. An abstract of 986.]
988. (H. O. Jones, O. W. Richardson. Proc. Chem. Soc. 18, 140-141,
(1902).
The decomposition of oxalacetic hydrazone in aqueous and acid solutions, and
a new method of determining the concentration of hydrogen ions in solution.)
[An abstract of 986.]
989. H. O. Jones, O. W. Richardson. Proc. Chem. Soc. 18, 141, (1902).
The dissociation constants, etc. [Same as 986. ]
Meas, Jordis; see 814.
980. (P. Joubin. Ck>mpt. Rend. 124, 228-229, (1897).
Sur la conductibilit^ moldculaire des sels en dissolution ^tendue.)
981. 6. Just Zeit. Elektiochem. 10, 202-204, (1904).
Ueber Benzinbr&nde.
T about 15^ R. O.
K.
988. I. Kablukoff. Jour. Russ. Phys.-chem. Soc. 23, 391-422, (1891).
On the electrical conductivity of hydrochloric acid in different solvents and
on the electrical conductivity of acids dissolved in aqueous alcohol.
T»10^ to 80°. [Almost the same as 938, but haa more measurements.]
988. (L Kablukoff. Zeit. Phys. Chem. 4, 429-434, (1889).
Ueber die elektrische Ldtfahigkdt von Chlorwasserstoff in verschiedenen
Losungsmitteln.) [Same as 988, except that there is no measurement of the
chloroacetic acids.]
Kablukov see Kablukoff.
984. L. Kahlenberg. Jour. Phys. Chem. 5, 339-^92, (1901).
The theory of electrolytic dissociation as viewed in the light of facts recently
ascertained. [Chiefly theoretical; the measurements are qualitative.]
468 AUTHOR LIST
9S0. L. KahlenbMg. Jour. Phys. Chem. 6, 1-14, (19Q2).
Instantaneous chemical reactions and the theory of cdectrolytic disBOciation.
[Qualitative.]
986. L. Kahlenbwg. Jour. Phys. Chem. 6, 45-49, (1902).
Nitriles as solvents in molecular weight determinations. [Qualitative.]
987. (L. KaUenberg. Phil. Mag. (6), 9, 214-229, (1905).
Recent investigations bearing on the theory of electroljrtic dissociation.)
988. L. Kahlenberg. Zeit. Phys. Chem. 17, 577-619, (1895).
Ueber komplexe Tartrate und gewisse alkalische Losungen des Kupfers und
des Bleies.
989. L. Kahlenberg. Zeit. Phys. Chem. 46, 64-69, (1903).
On the electrical conductivity of solutions in sulphocyanates and mustaxd
oils.
T=:25^ R. O.
940. (L. Kahlenberg. Trans. Am. Electrochem. Soc. 13, 265-272, (1908).
On the nature of electroljrtic conductors.) [Theoretical; with some qualitative
statements.]
941. L. Kahlenberg, A. T. liacoln. Jour. Phys. Chem. 3, 12-^, (1899).
The dissociative power of solvents. [Given in 1107.]
T»25^
942. L. Kahlenberg, O. B. Ruhoff. Jour. Phys. Chem. 7, 254-258, (1903).
On the electrical conductivity of solutions in amyl amine.
T=25^ R. O.
948. L. Kahlenberg, H. Schlundt Jour. Phys. Chem. 6, 447-462, (1902).
Solubility, electrolytic conductivity and chemical action in liquid hydrocyanic
acid.
T-0°. R. O.
944. L. Kahlenbeig, O. Schreiner. Zeit. Phys. CJhem. 20, 547-568, (1896).
Ueber Borsaure und ihrer Salze.
946. L. Kahlenberg, O. Schreiner. Zeit. Phys. Chem. 27, 552-566, (1898).
Die wfisserigen Losungen der Seifen.
T-25^; for part is 25*» to 80^ S. U.
M. Kalb see A. Hantzsch.
946. (F. Kalkow. Dis. Halle. (1897).
Ueber die Formaldehyd- Verbindimg des Hydroresorcins.) [No conductivity. ]
F. SUdkow see D. Voriander.
H. T. Kalmus see H. M. Goodwin.
" " " see R. Lorenz.
947. A. Kanitz. Arch. Gesammt. Physiol. 118, 539^546, (1907).
Die Affinit&tskonstanten des Tyrosins und des Phenyialanins.
T-25^ S. U. xaq.=2.2XlO-«; sub.
946. A. Kanitz. Zeit. Physiol. Chem. 47, 476-495, (1906).
Die Affinit&tskonstanten einiger Eiweissspaltungsprodukte.
T =25'' =fc0.05^ S. U. X aq. = 1.6 -2 X 10-«; not sub. unless so stated.
949. C. W. Kanolt Jour. Am. Chem. Soc. 29, 1402-1416, (1907).
Ionization of water at 0**, 18** and 25° derived from conductivity measure-
ments of the hydrolysis of the ammonium salts of diketotetrahydrothiazole.
T=0.00% 18.00° and 25.00° *0.01°. R. O. Xm aq.= 0.15-0.60 XlO-«;
sub.
C. W. Kanolt see J. L. R. Moigan.
T. Karaulow see L. Asher.
L. Karczag see 6. Buglia.
B. Kaxp see L.
AUTHOR LIST 469
960. J. H. Kastie. Am. Chem. Jour. 33, 46-^9, (1905).
A method for the determination of the affinities of acids colorimetrically, by
means of certain vegetable coloring matters.
961. J. H. Kastle, B. C. Keiser. Am. Chem. Jour. 17, 443-449, (1895).
On the determination of the affinities of adds oolorimetrically by means of
potassium dichromate.
Meas, T. Kato; see 1341.
T. Kato see A. A. Noyes.
962. ( H. Kaiiffmann. Ber. Deutsch. Chem. Ges. 37, 2468-2469, (1904).
Zur Theorie der Pseudosauren.)
968. (H. KauilmAnn. Ber. Deutsch. Chem. Ges. 41, 4396-1412, (1906).
Ueber den Nitro-hydrochinondimethylather und zur Theorie der Ldsungen.)
964. (H. Kauffnuum. Zeit. Phys. Chem. 47, 618-624, (1904).
Zur Theorie der Pseudosauren.) [Quoted.]
F. Kaufler see R. Lorenz.
L. Kaufmann see A. Hantzsch.
966. W. Kawalki. Ann. Physik. (3), 52, 166-190, (1894).
Untersuchungen dber die DifFusionsf&higkeit einiger Electrolyte in Alkohol.
T = 18®.
966. W. kawaUd. Ann. Physik. (3), 52, 300-327, (1894).
Untersuchungen fiber die Diffusionsfahigkeit einiger Electrolyte in Alkohol.
S. A. Kay see J. Walker.
966a. F. Kehrmann. Ann. Chemie. 372, 287-^5, (1910). Mea8. W. J.
MHUer.
Xanthen und Triphenylmethan. [Measurement of the free ester is given in
1898a.] •
T-0®andl8^
B. C. Keiser see J. H. Kastle.
Meas. Kellas; see 401.
967. H. KeUer. Dis. Heidelberg. (1902).
Dsmamische Untersuchungen tiber die Bildimg von Asofarbstoffen. [Same as
600, but contains also the constant of dipropylaniline.]
T=25^
H. KeUer see H. Goldschmidt
968. A. Kerier. Dis. Erlangen. (1894).
Molekulargewichtsbestimmungen von Salxen in Methyl- und Aethylalkohol
nach der Siedemethode ndl>en Bestimmungen der molekularen Leitfahigkeit
derselben Salze in obigen L6sungsmitteln und in Wasser.
969. W. Kerp, £. Baur. Arbeit, k. Gesundh. 26, 231-268, (1907).
Zur Kenntnis der gebundenen schweffigen S&uren.
T = 25**. R. O. X aq. « 0.6 [ X 10-«? ]; sub. for sodium salt.
960. (W. Kerp, B. Baur. Arbeit, k. Gesundh. 26, 297-300, (1907).
Ueber die elektrol3rtische Dissoziationskonstante der schweffigen Saure.)
T = 25**. R. O. X aq. = 5.8 X 10"^
961. W. Kerp, P. WShler. Arbeit, k. Gesundh. 32, 89-119, (1909).
Zur Kenntnis der gebundenen schweffigen S&uren. IV. Abhandlung; Ueber
die Verbindungen der schweffigen S&ure mit dem Citronellal und dem Zimt-
aldehyd.
963. W. Kerp, P. WShler. Albeit, k. Gesundh. 32, 120-143, (1909).
Zur Kenntnis der gebundenen schweffigen Sauren. V. Abhandlung; Ueber
Sulfitzellulose- Ablauge und furfurolschweffige S&ure.
T=25*.
968. R. Kieseritzky. Zeit. Phys. Chem. 28, 385-123, (1899).
Elektrometrische Konstitutionsbestimmungen. [Same as 964.]
460 AUTHOR LIST
964. R. Kieseritzky. Dis. LeipEig. (1899).
Elektrometrische KonstitutionsbeBtiimnuiigen. [Same as 96S.]
966. F. S. Kipping. Jour. Chem. Soc. 67, 139-155, (1895). Mtas. J. Walker,
Stereoiflomeric aa'-dimethylpimelic acids.
H. Kinnreuther see K. A. Hofmann.
966. A. KirpaL Monatsh. 18, 461-166, (1897).
Zur Kenntniss der Hemipinsfture iind der isomeren Esters&uren der Papaver-
ins&ure. [Same as 968.]
T=25^ xaq.-1.7Xl(H.
967. A. Kirpal. Monatsh. 28, 439-145, (1907).
Leitf&higkeitsmessungen an den isomeren Esters&uren der Chinolin- und
Cinchomerons&ure. [Same as 969.]
K ao. ^2.24XlO~*.
968. A. Kirpal. Sitzber. Alcad. Wien. 106, 2b, 460-165, (1897).
Zur Kenntniss der Hemipinsaure, etc. (Same as 966.]
969. A. Kirpal. Sitzber. Alcad. Wien. 116, 2b, 337-343, (1907).
Leitf&higlceitsmeesungen an den isomeren Esters&uren, etc. [Same as 967.]
Meas, Kissel; see 425.
H. Kissel see A. Hantzsch.
" " see H. Ley.
Kisfiakovskij see Kistiakowsky.
970. W. Kistiakowsky. Jour. Russ. Phys.-chem. Soc. 22, 411-430, (1890).
Aqueous solutions of double salts. [Same compounds as in 971, but with
additional measurements.]
T = 18** and 25^ xw aq. about 2.1X10-*; [probably sub.].
971. W. Kistiakowsky. Zeit. Phys. Chem. 6, 97-121, (1890).
Die wfisserigen Losungen von Doppelsalzen. [Given in 970.]
T = 18** and 25**. xw aq. about 2.1 X 10-*; [probably sub. ].
972. P. Klason, T. Carlson. Ber. Deutsch. Chem. (3les. 39, 732-738,
(1906).
Zur Kenntniss der Thioglykols&ure. [Same as 973.]
T=25^ R. O. Xj8aq. = 1.6X10-*; not sub.
973. P. Klason, T. Carlson. Arkiv Kemi. 2, no. 19, 1-9, (1905-1907).
Zur Kenntnis der Thioglykols&ure. [Same as 972.]
C. Kleber see F. Stohmann.
974. (Z. Klemensiewicz. Bui. Acad. Craoov. (1908), 485-494.
AntimonchlorOr als ionisierendes L(teung8mittel.) [Inorganic. ]
Meaa, R. Klien; see 1947.
976. A. Kling. Ann. Chim. Phys. (8), 5, 471^559, (1905).
Contribution & T^tude des alcools o^toniques. [Measurements same as 976»
but table also is given.]
T = 10.7** and 10.8^
976. A. KUng. Bui. Soc. Chim. (3), 33, 755-760, (1905).
Sur les solutions aqueuses d'ao^tol. [Curve of measurements same as 976,
but no table. ]
976a. B. Knecht, J. P. Batey. Jour. Soc. Dyers Colour. 25, 194r-203»
(1909).
On the condition of some dyestuffs in aqueous solution.
T = 18**and90^ R. O.
976b. B. Knecht, J. P. Batey. Jour. Soc. Dyers Cok>ur. 26, 4-5, (1910).
\ On the condition of Indigo White in aqueous solution. [Given accurately ia
976c]
T-18^ R.O.
AUTHOR LIST 461
076c. E. Enecht, J. P. Batey. Jour. Soc. Dyers Colour. 26, 171-173, (1910).
On the condition of Indigo White in aqueous solution. [The measurements in
076b are of an impure compound. ]
T = 18^ R. O.
L. E. Knight see J. K. H. Inglis.
977. L. Enorr. Ber. Deutsch. Chem. Ges. 28, 706-714, (1895). '
Ueber Abkdmmlinge der Phenolform des l-Phenyl-3-methyl-5-pyrazolons.
[Qualitative. ]
L. D. Kobozev see V. F. Timofejev.
078. K. R. Koch. Ann. Physik. (3), 50, 482-484, (1893).
Notiz Uber eine einfache Methode, um dielectrische Flttssigkeiten auf ihr
Leitungsvermdgen zu untersuchen.
E. Kdbner see K. Auwers.
%Meaa. R. Koefoed; see 1689b.
979. K. KoeUchen. Zeit. Phys. Chem. 33, 129-177, (1900).
Die chemische Dynamik der Acetonkondensation. [Same as 980.]
980. K. KoeUchen. Dis. Leipzig. (1900).
Die chemische Dynamik der Acetonkondensation. [Same as 979.]
981. (W. Koenigs, A. Eppens. Ber. Deutsch. Chem. C^es. 26, 810-81 1, (1893).
Ueber das Campherphoron.) [See 608 for measurements.]
982. (J. Koenigsberger. Phys. Zeit. 8, 833-836, (1907).
Ueber die Elektrizit&tsleitung in festen Kdrpem und die Elektronentheorie
derselben.)
988. (J. Koenigsberger. Zeit. Elektrochem. 15, 97-105, (1909).
Ueber Elektrizitatsleitung.)
983a. J. Koenigsberger, K. Schilling. Ann. Physik. (4), 32, 17^230, (1910).
Ueber Elektrizit&tsleitung in festen Elementen und Veribindungen.
•j»_20® to 302^.
984. (F. K5rber. Zeit. Phys. Chem. 67, 212-248, (1909).
Ueber den Einfluas des Druckes auf das elektrolytische Leitvermdgen von
Losungen.) [Inorganic. Some bibliography. See 1164, for priority claim. ]
985. (F. Kohlrausch. Ann. Physik. (3), 66, 785-825, (1898).
Die Beweglichkeiten electrischer lonen in verdttnnten wasserigen Ldsungen
bis zu 1-10 normaler Concentration bei 18^.) [Quoted.]
986. F. Kohkausch. Ann. Physik. Erganz. 8, 1-16, (1878).
Ueber das elektrische Leitimgsvermogen des Wassers und einiger anderer
schlechter Leiter.
S. U.
987. (F. Kohlrausch. Zeit. Elektrochem. 13, 333-344, (1907).
Ueber lonenbeweglichkeiten im Wasser.)
986. (F. Kohlrausch. Zeit. Elektrochem. 14, 12^133, (1908).
Der Temperaturkoeffizient der lonenbeweglichkeiten im Wasser als Funktion
der Bew^lichkeit selbst.) [Inorganic]
989. (F. Kohlrausch. Zeit. Phys. Chem. 18, 662, (1895).
Ueber die Formel von van't Hoff ftlr das Verdtinnungsgesetz bei Salzen.)
990. F. Kohlrausch. Zeit. Phys. Chem. 44, 197-249, (1903). %Mea8. F.
Rose,
Ueber ges&ttigte wfissrige Ldsungen schwerlOslicher Salze. I. Teil; Die elek-
trischen Leitvermdgen.
T = 18^ R. O. xaq. sub.
991. F. Kohlrausch. Zeit. Phys. Chem. 50, 355-i356, (1905).
Die Ldslichkeit einiger schwerldslicher Salze in Wasser bei 18^ [This is a
revision of 1004.]
T = 18^
462 AUTHOR LIST
992. (F. Eohlrausch. Zeit. Phys. Chem. 58, 630-631, (1907).
Ueber den Temperaturgang dee Leitvenndgens einer Losung.) [A coirection
of 906 regarding priority. ]
998. F. Eohlrausch. Zeit. Phys. Chem. 64, 129-169, (1908).
Ueber gesattigte wSsserige Losungen schwerldslicher Salze. II. TeQ; Die
gddsten Mengen mit ihrem Temperaturgang.
T=0°to38^ xaq. sub.
994. F. Eohlrausch. Sitzber. K. Preuss. Akad. Berlin. (1900), 1002-1008.
Ueber das elektrische Leitvermdgen von Ldsiingen der Alkali- Jodate und eine
Formel zur Berechnung von Leitvermdgen. [Inorganic. ]
996. (F. Eohlrausch. Sitzber. K. Preuss. Akad. Berlin. (1901), 1026-1033.
Ueber den Temperatureinfluss auf das elektrische Leitvermdgen von Ldsungen,
insbesondere auf die Beweglichkeit der einzelnen lonen in Wasser.)
996. (F. Eohlrausch. Sitzber. K. Preuss. Akad. Berlin. (1902), 572-580.
Ueber die Temperaturcoefficienten der lonen im Wasser, insbesondere uber
ein die einwerthigen Elemente umfassendes Gesetz.)
997. F. Eohlrausch, E. GrOneisen. Sitzber.K. Preuss. Akad. Berlin. (1904),
1215-1222.
Das Leitvermdgen wasseriger Ldsungen von Elektrolyten mit zweiwertigen
lonen. *
998. (F. Eohlrausch, W. HaUwachs. Ann. Phyaik. (3), 50, 118-126, (1893).
Ueber die Dichtigkeit verdtlnnter w&sseriger Ldsimgen.)
999. F. Eohlrausch, A. Heydweiller. Ann. Physik. (3), 53, 209-235, (1894).
Ueber reines Wasser. [Same as 1000 and 1001.]
T=-3°to +61.0^ Hg. U.
1000. F. Eohlrausch, A. Heydweiller. Zeit. Phys. Chem. 14, 317-330,
(1894).
Ueber reines Wasser. [Same as 999 and 1001.]
1001. F. Eohlrausch, A. Heydweiller. Sitzber. K. Preuss. Akad. Berlin.
(1894), 295-308.
Ueber reines Wasser. [Same aa 999 and 1000.]
1002. (F. Eohlrausch, L. Holbom, H. Diesselhorst Ann. Physik. (3), 64,
417-455, (1898).
Neue Gnmdlagen fUr die Werthe der Leitvermdgen von Electrolyten.)
1003. F. Eohlrausch, F. Mylius. Sitzber. K. Preuss. Akad. Beriin. (1904),
1223-1227.
Ueber wassrige Ldsimgen des Magnesiumoxalats.
T = 18**
1004. F. Eohlrausch, F. Rose. Ann. Physik. (3), 50, 127-137, (1893).
Die Ldslichkeit einiger schwer Idslicher Kdrper im Wasser, beurtheflt aus der
electrischen Leitimgsf&higkeit der Ldsungen. [Same as 1006 and 1006. See
991 for correction. ]
T=2**to42^ Hg. U. xaq. sub.
1006. F. Eohlrausch, F. Rose. Zeit. Phys. Chem. 12, 234-243, (1893).
Die Ldslichkeit einiger schwer Idslicher Kdrper, etc. [Same as 1004 and
1006.]
1006. F. Eohlrausch, F. Rose. Sitzber. K. Preuss. Akad. Berlin. (1893),
453-462.
Die Ldslichkeit einiger schwer Idslicher Kdrper, etc. [Same aa 1004 and 1006. ]
1007. F. Eohlrausch, H. v. Steinwehr. Sitzber. K. Preuas. Akad. Berlin.
(1902), 581-587.
Weitere Untersuchimgen liber das Leitvermdgen von £lektrol3rten aus ein-
werthigen lonen in wasseriger Ldsung.
T = 18^
AUTHOR LIST 468
1006. v. Eohlschiltter, C. BritttetMUik. Ann. Chemie. 349, 232-268, (1906)
Ueber Thiohanistoffcuprosake.
T»26^
1009. H. EoUer. Phil. Ma^. (5), 27, 526-527, (1889).
On the passage of electricity throus^ bad conductors. [An abstract of
1010.]
1010. H. Keller. Sitzber. Akad. Wien. 98, 2a, 201-266, (1899).
Ueber den Durchgang von Elektricit&t durch sehr schlechte Leiter. [Ab-
stracted in 1009.]
8. U.
Meas, EoUer; see 1471.
Konovaloff see Konowalow.
KonoTalov see Konowalow.
lOlL D. Konowalow. Ann. Physik. (3), 49, 733-760, (1893). fUMeaa.
Isaposhnikow.
Ueber die Eigenschaften der LOsungen, welche Amine mit S&uren bilden.
[This contains both 1012 and 1013.]
T=21* and 16°. Hg. U.
1012. D. Konowalow. Jour. Russ. PhyB.-chem. Soc. 24, 440-450, (1892).
On the electrical conductivity of solutions. [Same as part of 1011. ]
T-21** and 16^ Hg. U.
1013. D. Konowidow. Jour. Russ. PhyB.-chem. Soc. 25, 192-201, (1893).
M Meas, Sapoznikov.
On the electrical conductivity of solutions. [Same as part of 1011. ]
1014. (D. Konowalow. Jour. Russ. Phys.-chem. Soc. 25, 211-222,
(1893).
Heat phenomena produced by mixtures of amines with acids.)
Meas. L Koppel; see 1616.
1016. (J. Koppel. Zeit. Anorg. Chem. 28, 461-473, (1901).
Alkoholhaltige Chromihalogenv^indungen.) [Inorganic]
T-0**to70^
1016. A. v. Koiinyi, J. Bence. Arch. Gesammt. Physiol. 110, 51^^532,
(1905).
Physikaliscl^chemische Untersuchungen Uber die Wirlcung der Kohlensaure
auf das Blut.
1017. F. Koritschoner. Zeit. Angew. Chem. 20, 641-645, (1907).
Beitrage zur Kenntnis der Abietinsaure.
T=25^
F. Korten see £. Rimbach.
1018. F. L. Kortright Am. Chem. Jour. 18, 365-371, (1896).
The heat of electrolytic dissociation of some acids.
Ts0°. Xo aq. » 1.7X10~^; not sub. from acids, sub. from salts.
1019. (J. Kossonogoff. Phys. Zeit. 3, 207-208, (1901-1902).
Zur Frage der DielelctrilEa.)
1020. (J. KowalskL Bui. Acad. Cracov. (1891), 255-258.
Ueber den Einfluss des Druclces auf die elektrische Leitungsf&higkdt der
Elelctrolyte.) [Inorganic.]
1021. J. de Kowalsfed, B. Zdanowski. Arch. Sci. Phys. Nat. (4), 18,
105-134, (1904). Abstracted in Zeit. Elelstrochem. 11, 118-120,
(1905).
Nouvelle m^thode pour la mesure des resistances ^ectrolytiques liquides et
plusieurs de ses applications. [Part is in 1022.]
T = 18.9^ R. O.
464 AUTHOR LIST
1022. J. Eowalsld, B. Zdanowaki. Bui. Acad. Craoov. (1903), 793-794.
Nouvelle m^thode pour la mesure, etc. [An abstract of 1021, but without
tables of A.]
Meas, J. JC'>zak; see 291.
H. kxttmer see H. Grossmann.
1028. J. Kraemer. Dis. Mttnster. (1904). fUMeas. A, Rosenheim. Ab-
stracted in Zeit. Elektrochem, 10, 930-931, (1904).
Beitra^ zur Kenntnis der Leitf&higkeit molybd&n- imd wolframsaurer organ-
ischer Complexe. [This appears to be the same Kramer as in 691 and 692.
Same measurements as in 691 and 692, with addition of succinic acid with
Na,W04.]
T-25'**0.05^ R. O. xaq.=2-1.5XlO-«; sub.
1024. E. Krannhals. Zeit. Phys. Chem. 5, 250-258, (1890).
Elektrische Leitungsf&higkeit einiger Ldsungen bei Temperaturen swischen
18** und 100^
Ti8aboutl8^61^ 82*and99^ S. U. xaq.-8X10-«.
Krapivin see Krapiwin.
S. Krapiwin see N. Zelinsky*
1026. (C. A. Kraus. Phys. Rev. 18, 40-56, (1904).
The electrical conductivity of solutions in methyl alcohol in the neighborhood
of their critical point.) [Inorganic]
1026. (C. A. Kraus. Phys. Rev. 18, 8^103, (1904).
The electrical conductivity of solutions in methyl alcohol in the neighborhood
of their critical point.) [Inorganic. ]
C. A. Kraus see E. C. Franklin.
A. Kreichgauer see R. Schenck.
B. Kr5nig see T. Paul.
1027. O. Kiihling. Ber. Deutsch. Chem. Ges. 38, 1638-1646, (1905).
Meaa. W. A, Roth.
Ueber die Elektrolyse des Glykocolls.
1028. F. W. Kiister. Sitzber. Ges. Natmw. Marburg. (1896), 24-28.
Ueber die Konstitution der Pentachlorpentdiens&ure, hergeleitet aus ihrer
elektrischen Leitf &higkeit. [Same as 2080. ] *
Mea8. F. Kiister; see 2080. [This is the same KOster as in 1028.]
1029. W. Kiister. Ann. Chemie. 315, 174r-218, (1901). Meas. DiOrich.
Ueber die Constitution der H&matins&uren.
T-25°.
1080. W. Kiister. Ann. Chemie. 345, 1-^59, (1906). Meas. Haas and
Mezger.
Ueber die Constitution der H&matins&uren.
T=25^
1081. W. Kiister. Ann. Chemie. 346, 1-27, (1906). Meas. K. Haas.
Ueber die Constitution des H&mopyrrols.
T=25^
1082. W. Kaster. Ber. Deutsch. Chem. Ges. 35, 1268-1273, (1902).
Meas. Westhausser.
Beitr&ge zur Kenntniss der Gallenfarbstoffe. [Qualitative.]
1088. W. Kiister. Ber. Deutsch. Chem. Ges. 35, 2948-2954, (1902). Meas.
O. Megger.
Beitrage zur Kenntmss des Hamatins. [Same as 1262.]
T=25^
1084. L Kukalesko. Jour. Russ. Phys.-chem. Soc. 28, 293-299, (1896).
Meas. SzyszhowsH.
The preparation and properties of a-dimethyl-jS-isobutylethylenelactie add.
AUTHOR LIST 466
1086. C. EuUsren. Zeit. Phys. Chem. 37, 613<^22, (1901).
Ueber die Einwirkuiig von Nichtelektrolyten bei Verseif ung von Aethylaoetat.
[Same as 1087.]
T-20.7*.
1086. C. Kullgren. Zeit. Phys. Chem. 41, 407-426, (1902).
Studien Uber die Invenion. [Same as 1088.]
T=20^
1087. C. EuUijeii. Bihang Svenflk. Vet.-Akad. Hand. 24, Afd. 11, no. 3,
1-26, (189&-1899).
Idie-elelctrolyterB inverkan rk reaktionshastigfaeten vid saponifilcation af
etylacetat. [Same as 1086.]
1088. C. Kiillgren. Bihang Svensk. Vet.-Akad. Hand. 27, Afd. II, no. 2,
1-41, (1902-1903).
Studien iiber die Inversion. [Same as 1086.]
T=20^
1089. C. Kullgren. Dis. Uppsala. (1904).
Om metaHsalters hydrolys.
1040. (J. Kunz. Compt. Rend. 135, 788-790, (1902).
Sur la oonductibilit^ des dissolutions aux basses temperatures.) [Same as
1041. Inorganic. ]
1041. (J. Kunz. Zeit. Phys. Chem. 42, 591-596, (1902-1903).
Ueber die Abhftngigkeit der dektiolytischen Leitfahigkeit von der Temper-
atur imter O"".) [Same as 1040.]
T«-69*»to0^
1042. B. Kuriloff. Zeit. Phys. Chem. 23, 90-94, <1897).
Anwendimg des Massenwirkungsgesetses zur Untersuchimg der organischen
Additionsprodukte. Die Reaktion swischen Pikrins&ure und /3-Naphtol in
der wfissrigen Ldsung.
T=25^ X aq. =0.35XlO-«; not sub.
£. E. Eurovskij see S. M. Tanatar.
1048. J. J. van Laar. Zeit. Phys. Chem. 12, 742-750, (1893).
Ueber die Dissociationskonstante des Wassers und der Cyanwasserstoffs&ure.
1044. (J. J. van Laar. Zeit. Phys. Chem. 58, 567-574, (1907).
Ueber den Dissociationsgrad gesfittigter Ldsungen eines Elektrolyten in ver-
schiedenen Lasungsmitteln, und von Ldsungen, welche im Teilungsgldchge-
wicht stehen.)
1046. (J. J. van Laar. Zeit. Phys. Chem. 59, 212-217, (1907).
Ueber die Ldslichkeit von Elektrolyten.) [Quoted.]
1046. (J. J. van Laar. Arch. Mus6e Teyler. (2), 7, 5^95, (1902).
Sur la loi de diluation chez les dectrolytes fortement dissoci^es.) [Quoted.]
1047. S. Labendzinski, R. Abegg. Zeit. Elektrochem. 10, 77-81, (1904).
Zur Kenntnis der Konstitution von Salzldsungen.
Meas. H. Labhardt; see 1612, 1644, 1646.
T. H. Laby see G. H. Carse.
1048. (T. H. Laby, O. A. Carse. Proc. Cambridge Phil. Soc. 13, 288-295,
(1904-1906).
On a relation between the velocity and the voltune of the ions of certain organic
acids and bases.) [Theoretical and quoted.]
W. S. Landis see J. W. Richards.
466 AUTHOR LIST
1049. (W. Landsberger. Zeit. Anorg. Chezn. 17, 43S^-^M^, (1898).
Ein neues Verfahren der MolekelgewichtebeBtimmung nach der Siedemethode.)
H. Langbein see F. Stohmaim.
'^ '^ see F. Stohnuum, C. Kleber.
W. Lange see J. Brode.
1060. A. Lapwortb. Jour. Chem. Soc. 85, 1206-1214, (1904). Me<u. J.
Walker.
ReactioDS involving the addition of hydrogen cyanide to carbon compounds.
Part II. Cyanohydrins regarded as complex acids. [Qualitative.]
1061. A. Lapwortb. Jour. Chem. Soc. 93, 2187-2203, (1908). Meas. R.
W. L. Clarke,
An examination of the conception of hydrogen ions in catalysis, salt forma-
tion, and electrolytic conduction.
1062. A. Lapwortb. Proc. Chem. Soc. 24, 275, (1908). Meas, R, W, L.
Clarke.
An examination of the conception of hydrogen ions, etc. [Summary of 1061. ]
1063. £. Laqueur. Beitr. Chem. Physiol. Pathol. 7, 273-297, (1905-1906).
Ueber das Kasdn als Saure imd seine Unterschiede gegen das durch Lab
veranderte KaseSn. (Parakasein). Theorie der Labwirkung.
T-25^ R. O.
1064. E. Laqueur, O. Sadcur. Beitr. Chem. Physiol. Pathol. 3, '193-224,
(1902-1903).
Ud)er die S&ureeigenschaften imd das Molekulargewicht dee Kasdns und
seine Spaltung beim Trocknen. [Part given in 1666.]
T=25^ R. O. xaq.= 2.6X10-*; sub.
H. Larsen see H. Goldschmidt.
1066. Lassar-Cohn. Ann. Chemie. 251, 335-359, (1889).
Electrolyse der Ldsungen organischer Kaliumsalze imd des geschmolzenen
Kaliumacetats.
1066. S. v. LaszczyiiskL Zeit. Elektrochem. 2, 55-^7, (189&-1896).
Ueber die Leitf&higkeit der Loeungen einiger Salze in Aceton.
T=::18^
1067. S. v. Laszczynski, S. v. Gorski. Zeit. Elektrochem. 4, 290-293,
(1897-1898).
Leitfahigkeit von Loeungen einiger Salze in Pyridin.
T = 18**.
1068. W. Utzko. Dis. Basel. (1904).
Ueber /37-Diphenylvinylessig8&ure imd ihre Verwandten. [k is given in 667»
but no tables of A are there. ]
T=25^ R. O.
W. Latzko see F. Fichter.
1069. (B. Lean. Jour. Chem. Soc. 65, 1024^1028, (1894).
Note on the affinities of polybasic acids.) [Same as 1060. Theoretical and
quoted. ]
1060. (B. Lean. Mem. Proc. Manchester lit. Phil. Soc. (4), 9, 19-30,
(1895).
On the affinities of polybasic acids.) [Same as 1069.]
Meas. M. Lehmann; see 742, 760.
M. Lehmann see A. Hantzsdi.
Leleux see Gin.
1061. £. Lellmann. Ann. Chemie. 270, 20^208, (1892).
Ueber die Affinitatsgrdssen der S&uren.
1063. £. UUmann, A. Geirtz. Ann. Chemie. 274, 121-141, (1893).
Ueber die Affinitatsgr()6sen der Basen.
AUTHOR LIST 467
106S. B. Lellmaniiy H. Gross. Ann. Chemie. 260, 26^289, (1800).
Ueber die Affinit&tsgrOflsen der Basen.
lOM. B. Ldlmaim, H. Gross. Ann. Chemie. 263, 286-299, (1891).
Ueber die Affinit&tsgrOssen der Basen.
1065. £. LeUmann, A. Liebmann. Ann. Chemie. 278, 141-152, (1894).
Ueber die Affinit&tsgrdssen der Basen.
1066. B. LeUmann, A. Liebmann. Ann. Chemie. 278, 152-173, (1894).
Ueber die Affinit&tsgrOssen der S&uren.
1067. £. LeUnuum, J. Schliemann. Ann. Chemie. 270, 208-235, (1892).
Ueber die Afi&nit&tsgrOssen der S&nren.
1066. B. Leilmann, J. Schliemann. Ann. Chemie. 274, 141-156, (1893).
Ueber die Affinit&tsgrdssen der S&uren.
1069. B. LeUmann» J. Schliemann. Ann. Chemie. 274, 156-173, (1893).
Ueber die Afi&nit&t8gr68sen der S&uren.
N. Lemcke see L. Pissarjewsky.
Lemke see Lemcke.
1070. H. Lemme. Progr. Glauchieiu. (1897).
Aoeton als Lteungsmittel fOr Salse in chemischer und physikalischer Hinsicht.
T - 18^ and 25^
1071. R.Lenz. Mem. St. Petersburg. (7), 30, (1882). Abstracted in
Beibl. Ann. Physik. 7, 399-406, (1883).
Ueber das galvanische Leitungsvermdgen alkoholischer L6sungen. [Original
not examined. The title is that of the abstract. ]
Lesage see Dongier.
1072. Lesage, Dongier. Compt. Rend. 134, 612-614, (1902).
£tude de la fermentation lactique par Tobservation de la resistance ^lectrique.
T = 16.7^
1073. Lesage, Dongier. Compt. Rend. 135, 111-113, (1902).
R^sistivitds 61ectriques de scrums sanguins pathologiques et d'^panchements
sdreux ches Thonmie.
T = 16.7^
1074. R. Leasing. Dis. Gottingen. (1902). Meas. V. Rothmund.
Ueber l,4-N-Methylpyrrolidindicarbons&iue. Ueber eine Bildung yon Phenyl-
cydohexan aus Chinit. [Corrected in 1979.]
R. O.
R. Lesshig see S. B. Schryver.
'' '* see R. Willstiltter.
1076. H. Leupold. Dis. Leipzig. (1908).
Polymeric als Ursache der Farbverschiedenheit yon Acridin- und Chinolin-
salsen. [A of sulphate is given in 747.]
T=25*.
Meas. H. Leupdd; see 747.
M. G. Levi see G. Carrara.
A. Levier see P. Dutoit.
1076. W. Levy. Dis. Berlin. (1904).
Studien fiber Molekularverbindungen. I. Doppelsalsbildung unges&ttigter
Ketone, Aldehyde und S&uren. II. Ueber Platinphosphorhalogenveibin-
dungen und ihre Derivate. [Part is same as 16SB« but this also gives
Aat0^]
T=25*and0^
W. Levy see A. Rosenheim.
1076a. (G. N. Lewis. Zeit. Phys. Chem. 70, 212-219, (1910).
The use and abuse of the ionic theory.) [Theoretical and inorganic]
468 AUTHOR LIST
1077. (O. N. Lewis, L. W. Sargent Jour. Am. Chezn. Soc. 31, 355-363,
(1909).
The potential of the feno-ferricyanide electrode.)
1078. G. N. Lewis, L. W. Sargent Jour. Am. Chem. Soc. 31, 363-367,
(1909).
Potentials between liquids.
T=25^
1079. (G. N. Uwis, P. Wheeler. Zeit. Phys. Chem. 56, 17^192, (1906).
Die elektrische Leitf&higkeit von Lteungen in flOssigem lod.) [Same as 1080*
Inorganic. ]
1080. (G. N. Lewis, P. Wheeler. Proc. Am. Acad. Arts Sci. 41, 417-432,
(1905-1906).
The electrical conductivity of solutions in liquid iodine.) [Same as 1079.]
1081. (W. E. Uwis. Zdt. Phys. Chem. 63, 171-176, (1908).
Eine Methode zur Berechnimg von lonenkonzentrationen aus Potentialme^
sungen von Konzentrationsketten.) [Inorganic and theoretical.]
1082. (H. Ley. Ber. Deutsch. Chem. Ges. 30, 2192-2196, (1897).
Ueber die hydrol3rtische Dissociation.) [Inorganic. ]
1088. H. Ley. Ber. Deutsch. Chem. Ges. 34, 2620-2631, (1901).
Ueber Oxyamidine.
T = 25**. S. U. X aq. = 0.8 X 10-«; not sub.
1084. H. Ley. Ber. Deutsch. Chem. Ges. 38, 973-978, (1905).
Ueber Quecksilbemitroform; ein Beitrag zur Constitution von Salzldsungen.
[T probably 25^] R. O.
1086. H. Ley. Ber. Deutsch. Chem. Ges. 38, 2199-2203, (1905).
Ueber coUdfdales Kupferoxyd.
T=25^ R. O.
1086. H. Ley. Ber. Deutsch. Chem. Ges. 42, 354r-376, (1909).
Beitrage zur Theorie der inneren Komplexsalze.
T=25^ R. O. X aq. averages 1.2X10-*; not sub.
1087. H. Ley. Zeit. Elektiochem. 10, 954-956, (1904).
Ueber innere Metall-Komplexsalze.
T=25^ R. O.
1088. H. Ley. Zeit. Phys. Chem. 30, 193-257, (1899).
Studien ilber die hydrolytische Dissociation der Salzldsungen. [Same as
1089.]
T = 25**. X aq. - 1.3 X 10-'; sometimes sub.
1089. H. Ley. Habilitschr. Wtirzbui]g. (1899).
Studien (Iber die hydrolytische Dissociation der Salzldsungen. [Same as 1088. ]
Mea8. H. Ley; see 726.
1090. H. Ley, O. Erler. Zeit. Anorg. Chem. 56, 401-421, (1907).
Ueber Salz- imd Komplexsalz-Bildung bd hydroxylhaltigen organischen
S&uren. [See 1346 and 1716. ]
T=25^ R.O.
1091. H. Ley, O. Erler. Zeit. Elektrochem. 13, 797-799, (1907).
Leitfahigkeitsmessimgen bei Natriumsalzen der isomeren Oxybenzoesatkren;
zur Frage nach der Wanderungsgeschwindigkeit isomerer Anionen. [See
1346 and 1716.]
T=25^ xaq. = 1.0 -1.5X10-*; sub.
1092. H. Ley, A. Hantzsch. Ber. Deutsch. Chem. Ges. 39, 3149^160,
(1906). MeoB, H. Gorke and A. H. Salvxty,
Ueber den Zustand der Pseudosauren in wftssriger Ldeung. [Part is given in
1667.]
T=0*and25*. R. O, x aq. sub.
AUTHOR LIST 469
1008. H. Ley, R. Holzweissig. Ber. Deutsch. Chem. Qes. 36, 18-24,
(1903).
Ueber Oxyamidine.
T-25^ S. U.
1004. H. Ley, H. KlsseL Ber. Deutsch. Chem. Gee. 32, 1357-136S, (1899).
mi Meat, Buckner.
Beitr&ge zur Chemie des Quecksilbers.
Ts25°. [Probably for all measurements. Not stated in some cases.]
X aq. » 1.3 X 10~*; not sub.
1006. H. Ley, K. Schaefer. Ber. Deutsch. Chem. Ges. 35, 1309-1316,
(1902).
Beitr&ge zur Chemie des Quecksilbers. [Given in 1007; not quite so full here. ]
rr probably 25^1 R. O.
1096. H. Ley, K. Schaefer. Ber. Deutsch. Chem. Ges. 39, 1259-1266,
(1906).
Ueber Silbersalze von S&ureamiden und S&ureimiden. 11.
T=25^ R. O. xaq.=«1.5XlO-«; notsub.
1007. H. Ley, K. Schaefer. Zeit. Phys. Chem. 42, 690-704, (1902-
1903).
XJntersuchimgen fiber die Dissociation von Schwermetallsalzen. I. Ueber
Quecksilberstickstoffsabe. [Same as 1096 with a few additional measure-
ments.] ^
T«25^ R. 0. xaq.« 1.0X10-*; not sub.
1098. G. T. LhuilUer. Compt. Rend. 121, 345-^48, (1895).
Sur la conductibilit^ des melanges de limailles m6talliques et de di^lectriques.
1090. D. M. lachty. Ann. Chemie. 319, 369-390, (1901). m^Meas, S, L.
Bigdow,
Die Geschwindigkeit der Esterbildung und die elektrische Leitf&higkeit der
a-f /3-, 7- imd 6- Halogenfetts&uren. [See 1908.]
T=25^ S. U.
Meas, Lidbuzy; see 861.
1100. (C. Liebenow. Zeit. Elektrochem. 8, 933-938, (1902).
Ueber die Dissociation der Elektrol3rte.)
1101. (C. Liebenow. Zeit. Elektrochem. 11, 301-306, (1905).
Zur Frage der Dissociation der Elektrolyte.) [Theoretical and inorganic]
1102. C. Liebermann. Ber. Deutsch. Chem. Ges. 23, 512^16, (1890).
Meas. W, Ostwald,
Ziu" Kenntnis der Isozimmts&ure. [See 1S73.]
1108. C. liebermann. Ber. Deutsch. Chem. Ges. 24, 1101-1110, (1891).
Meas, W. Ostwald.
Ueber AUozinmits&ure.
1104. C. liebermann. Ber. Deutsch. Chem. Ges. 28, 120-134, (1895).
Meas, Paul.
Ueber Allof urfuracryls&iure.
1106. C. Liebermann. Ber. Deutsch. Chem. Ges. 36, 176-183, (1903).
Meas. W. Ostwald.
Zur Frage nach der Isozimmts&ure.
T is about 25*.
O. liebknecht see A. Rosenheim.
A. liebmann see E. Lellmann.
1106. A. T. lincohi. Jour. Phys. Chem. 3, 457-494, (1899).
The electrical conductivity of non-aqueous solutions. [Given in 1107.]
T=25^ Hg. U.
470 AUTHOR LIST
1107. A. T. Lmcoln. Trans. Wisoonsin Acad. 12, II, 39&^53, (1898-
1899).
The electrical conductivity of non-aqueous solutions. [Part is in 941, the rest
is in 1106.]
T-26*.
A. T. Lincoln see L. Kahlenberg.
1108. L. Lindet Compt. Rend. 138, 508-510, (1904). Meas, Dangier?
Sur rinversion du sucre.
1109. C. F. Lindsay. Dis. Johns Hopkins. (1902).
A study of the conductivity of certain salts in water, methyl, ethyl and propyl
alcohols, and mixtures of these solvents. [Same as 912.]
C. F. Lindsay see H. C. Jones.
1110. £. O. v. Lippmann. Ber. Deutsch. Chem. Ges. 34, 3747-3750, (1901).
Zur Inversion des Rohrzuckers. [Qualitative. ]
A. lipschitz eee R. Wegischeider.
G. Lockemann see £. Beckmann.
K. Lockemann see H. Pauly, K. SchiibeL
W. Lodter see £. Bamberger.
1111. M. Loeb, W. Nemst Zeit. Phys. Chem. 2, 948-963, (1888). Meas.
W. Nemst.
Zur Ejnetik der in Ldsimg befindlichen K5rper. II. Udberf Qhrungszahlen und
Leitvermdgen einiger Silber^ze.
T-25''. Hg. U. xj6aq.=2.5XlO-«; sub.
Ulla. W. L6b, S. Higuchi. Biochem. Zeit. 24, 92-107, (1910).
^Ueber lonenkonzentrationen in Organfltissigkeiten.
1112. (K. F. L6we. Ann. Physik. (3), 66, 390^10, (1898).
Experimental-Untersuchung tlber electrische Dispersion einiger organischer
Sauren, Ester, und von zehn Glassorten.) [Dielectric constants. ]
1113. (K. F. L6we. Ann. Physik. (3), 66, 582-596, (1898).
Experimental-Untersuchung Uber electrische Dispersion einiger organischer
S&uren, Ester imd von zehn Glassorten.)
1114. (R. Ltfwenherz. Zeit. Phys. Chem. 15, 389^98, (1894).
Ueber die Verseifungsgeschwindigkeit einiger Ester.)
1116. R. L6wenherz. Zeit. Phys. Chem. 20, 282-302, (1896).
Ueber den Einfluss des Zusatzes von Aethylalkohol auf die dektrolytische
Dissociation des Wassers.
1116. R. L6wenherz. Zeit. Phys. Chem. 25, 385-418, (1898).
Bestinmiimg von Dissociationskonstanten durch L6slichkeitserhdhung.
T«25^
1117. W. Loewenstamm. Dis. Berlin. (1901).
Ueber Metallsalzverbindungen des Schwefelhamstoffs, ein Beitrag zur Kennt-
nis der komplexen Verbindungen einwertiger Metalle. [Same as 1624 for 25^. ]
T=25^
W. Loewenstamm see A. Rosenheim.
1118. J. H. Long. Jour. Am. Chem. Soc. 28, 372-384, (1906).
Some investigations on salts of casein.
T=20^
1119. J. H. Long. Jour. Am. Chem. Soc. 29, 223-230, (1907).
On some phenomena observed in the peptic digestion of caseins.
T=20^
1120. J. H. Long. Jour. Am. Chem. Soc. 29, 1334-1342, (1907).
On the combining power of casein with certain acids.
T=20**
AUTHOR LIST 471
1121. J. H. Long. Jour. Am. Chem. Soc. 30, 881-895, (1008).
Observations on the stability of lecithin.
Ta20^ X aq. not sub.
1122. £. H. Loomis. Ann. Physik. (3), 60, 523-546, (1897).
Der Gefrierpunkt verdtlnnter wftsseriger LOsungen. [Same as 1126.]
Hg.U.
1123. E. H. Loomis. Ann. Physik. (3), 60, 547-551, (1897).
Ueber das specifische Gewicht und das electrische Leitungsvermdgen der
Normalldsimgen von Natrium- und Kaliumhydroxyd, von Salzsaure, Sdiwef el-
s&ure, Salpeters&ure und Oxals&ure. [Same as 1124.]
T-18***o.05^ Hg. U. a<4^
1124. £. H. Loomis. Phys. Rev. 4, 252-255, (1896-1897).
On the specific gravity and electrical conductivity of the normal solutions of
sodium and potassium hydroxides, and hydrochloric, sulphuric, nitric and
oxalic acids. [Same as 1123. ]
T = 18*=fc0.05^ Hg. U. at 4^
1126. E. H. Loomis. Phys. Rev. 4, 273-296, (1896-1897).
The freezing-points of dilute aqueous solutions. [Same as 1122.]
T = 18^ Hg. U.
1126. R. C. Lord. Jour. Phys. Chem. 11, 173-200, (1907).
An investigation of the double cobalt malonatee.
T = 18**. Hg. U. xis aq. =2 X 10-« or less.
1127. (R. Lorenz. Ber. Deutsch. Chem. Ges. 40, 3308-3311, (1907).
Die elektrol3rtische Dissoziation geschmolzener 9alze.) [Inorganic. ]
1128. (R. Lorenz. Ber. Deutsch. Chem. Ges. 40, 4378-4380, (1907).
Die elektrolytische Dissoziation geschmolzener Salze.)
1128a. (R. Lorenz. Zeit. Phys. Chem. 70, 230-238, (1910).
Ueber die Anwendung der Theorie der elektrolytischen lonen auf die
geschmolzenen Salze.) [Inorganic]
1129. R. Lorenz, A. BlOii. Zeit. Phys. Chem. 66, 733-751, (1909).
Beitr&ge zur Theorie der elektrolytischen lonen. II. Die elektrolytische
Dissociation des Wassers.
1130. (R. Lorenz, H. T. Kalmus. Zeit. Phys. Chem. 59, 17-30, (1907).
Das Leitvermdgen einiger geschmolzener Salze und Uber die Methode der
Bestimmung desselben.) [Inorganic]
1181. (R. Lorenz, F. Kaufler. Ber. Deutsch. Chem. Ges. 41, 3727-3738,
(1908).
Der Molekularzustand der geschmolzenen Salze.) [Inorganic]
1182. (R. Lorenz, W. Ruckstuhl. Zeit. Anorg. Chem. 52, 41-47, (1907).
Untersuchungen tiber die Wanderung der lonen bei der Elektrolyse eines
geschmolzenen Salzpaares.) [Inorganic]
W. Lotz see H. Rupe.
^ '' see H. Rupe, M. Ronus.
1133. J. M. Lov6n. Zeit. Phys. Chem. 13, 550^560, (1894).
Ueber die Affinit&tsgrossen einiger schwefelhaltigen Substitutionsderivate von
der Essigs&ure und der Propionsaure.
T-25^
1184. J. M. Lov6n. Zeit. Phys. C^iem. 19, 456-464, (1896).
Affinit&tsgrossen einiger orgamschen S&uren.
1136. (J. M. Lovfo. Zeit. Phys. Chem. 21, 134-136, (1896).
Notiz aber die Trithiodilaktylsaure.) [Quoted.]
F. H. Lowe see J. C. Crocker.
T. M. Lowiy see W. R. Bousfleld.
472 AUTHOR LIST
1186. J. Lublin. Ber. Deutsch. Chem. Ges. 37, 3467-^469, (1904).
Dinitrile und Amylnitiit. [Qualitative. ]
1187. A. LuoAS. Ber. Deutsch. Chem. Ges. 32, 3179-3182, (1899). Meaa.
F, Hofmann,
Ueber Nitroaceton.
T=25*.
1187a. A. B. Luckfaardt Am. Jour. Physiol. 25, 345^353, (1909-1910).
Ck)ntributions to the physiology of lymph. X. The comparative electrical
conductivity of lymph and serum of the same animal, and its bearing on the-
ories of lymph formation.
T = 35.3**. Special unit.
1188. J. S. Luinsden. Jour. Chem. Soc. 87, 90-98, (1905).
The physical properties of heptoic, hexahydrobenzoic, and benzoic acids and
their derivatives.
T=25®.
1189. H. Lund^n. ArkivKemi. 2, no. 11, 1-44, (1905-1907).
Ueber amphotere Elektrolyte. [Same as 1160.]
1140. (H. Lund^ Arkiv Kemi. 2, no. 18, 1-6, (1905-1907).
Bemerkimgen zur Theorie der amphoteren Elektrolyte.) [Theoretical. ]
1141. H. Lund6n. Arkiv Kemi. 2, no. 28, 1-10, (1905-1907).
Die Kriterien der Pseudos&uren.
T=25^ X2B aq. = 1.3XlO-«; not sub.
1142. H. Lundfo. Jour. Biol. Chem. 4, 267-288, (1908).
Amphoteric Electrolytes. [Same as 1148.]
1148. H. Lund6n. Jour. Chim. Phys. 5, 145-185, (1907).
Siu- la relation entre les coefficients d'affinit^ et I'hydrolyse des sels des c^tones
isonitrosto. [Same as 1146.]
T = 15% 25° and 40^ X2b aq. = l.l-1.6XlO-«; sub. as a rule.
1144. H. Lund^n. Jour. Chim. Phys. 5, 574^^08, (1907).
Hydroljrse des sels des acides faibles et des bases faibles et sa variation avec
la temperature. [Same as 1147.]
T=8'*to50^ X25aq.-1.0-1.3XlO-«; sub.
1146. (H. Lund^n. Jour. Chim. Phys. 6, 681-^98, (1908).
Influence de la temperature siu- T^nergie interne et T^nergie libre des dissoci-
ations eiectrolytiques des acides et bases faibles.) [Same as 1149.]
1146a. H. Lund6n. Jour. Chim. Phys. 8, 331-336, (1910).
La constante de dissociation de la tropine et sa variation avec la temperature.
T«10^ 25°, 50°. X26 aq. = 1.0 -1.4X10-*; sub.
1146. H. Lunden. Med. Nobelinst. 1, no. 7, 1-38, (1906-1909).
Sur la relation, etc. [Same as 1148.]
1147. H. Lund6n. Med. NobeUnst. 1, no. 8, 1-^, (1906-1909).
Hydrolyse des sels, etc. [Same as 1144.]
1148. H. Lundln. Med. Nobelinst. 1, no. 11, 1-21, (1906-1909).
Amphoteric electrolytes. [Same as 1142.]
1149. (H. Lunden. Med. Nobelinst. 1, no. 12, 1-16, (1906-1909).
Influence de la temperature sur Tenergie interne et Tenergie libre, etc.) [Same
as 1146.]
1160. H. Lunden. Zeit. Phys. Chem. 54, 532-^68, (1906).
Ueber amphotere Elektrolyte. [Same as 1189.]
T = 15°to45°. R.O. xuaq. = 1.2-1.5Xia-«; notsub.
1160a. H. Lund6n. Zeit. Phys. Chem. 70, 249-255, (1910).
Phenol and m-nitrophenol as acids. *
T = 10°to50°. R. O. X26aq.=1.00XlO-«; sub.
Meaa. H. Luiid6n; see 624.
AUTHOR LIST 478
1161. (S. Lossana. Nuovo Cim. (3), 34, 217-226, (1893).
La resistenfla elettrica ddle soliudoni acquoae e sua variazione in oorrispon-
denza al massimo di density.) [Inorganic. Same as 1166.]
1163. (S. Lussana. Nuovo Cim. (4), 5, 357-^385, (1897).
Ck>ntributo alio studio della resistenza elettrica delle soluzioni, oonsiderata
come funzione della pressione e della temperatura.) [Inorganic]
1168. (S. Lussana. Nuovo Cim. (4), 5, 441-159, (1897).
Contributo alio studio della resistenza elettrica delle soluzioni, considerata
come funzione della pressione e della temperatura.) [Inorganic. ]
1164. (S. Lussana. Nuovo Cim. (5), 18, 170-172, (1909).
Suirinfluenza della pressione e della temperatura sulla resistenza elettrolittica.)
[Correction of 1161-1168; also a priority daim; see 984.]
1166. (S. Lttssaxia. Atti 1st. Veneto. 51, 1466-1481, (1892-1893).
La resistenza elettrica delle soluzioni acquose e sua variazione in oorrispon-
denza al massimo di densitjl.) [Same as 1161.]
1166. O. Ltttz. Ber. Deutsch. Chem. Ges. 35, 2460-2466, (1902).
Ueber einige F&Ue von Sauerstoffwanderung in der Molekel.
T-25^
1167. O. Lutz. Ber. Deutsch. Chem. Ges. 35, 2549-2554, (1902).
Ueber die Einwirkimg von Ammoniak auf halogensubstituirte Malons&uren.
[Same as 1169.]
T=25^
1168. O. Lutz. Ber. Deutsch. Chem. Ges. 35, 4369-4377, (1902).
Ueber einige F&lle von Sauerstoffwanderung in der Molekel. II. Einwirkung
von Ammoniak auf alkylsubstituirte Monobrombemsteinsauren.
1169. O. J. Lutz. Dis. Rostock. (1899).
Ueber die Einwirkimg von Ammoniak und Aminbasen auf Halogenbemstein-
sauren. [Same as 1167.]
JIfecu.P.Luz; see 1912, 1918, 1914, 1936, 1927, 1928, 1982, 1988, 1940,
1940a.
P. Lux see R. Wegscheider.
1160. R. Luzzatto, D. Fflippi. Arch. Fisiol. 6, 250-264, (1909).
I ooddetti oompoeti jodotannici.
T = 18«.
1161. G. W. P. van Maarseveen. Dis. Zurich. (1897).
Ueber die Beziehimg zwischen Ldsungswfirme, Ldslichkeit und Dissociations-
grad. [Same as 666.]
T=25^
Mea8. O. W. P. van Maarseveen; see 666.
1162. J. Maas. Dis. MUnchen. (1909).
Hexarhodanatosalze des Molybd&ns. [Part given in 1168.]
T=25^
1168. J. Maas, J. Sand. Ber. Deutsch. Chem. Ges. 41, 1500-1514, (1908).
Die Hexarhodanatosalze des Molybd&ns. [Given in 1162. See 1164. ]
T=25^ R. O.
1164. J. Maas, J. Sand. Ber. Deutsch. Chem. Ges. 41, 3367-3376, (1908).
Die Hexarhodanatosalze des Molybd&ns.
T=0^ R. O.
[For A criticism of 1168 see A. Rosenheim, Ber. Deutsch. Chem. Ges. 41,
2386, (1908), and 42, 149, and 2295, (1909). Answered in 1164 and
Ber. Deutsch. Chem. Gee. 42, 2642, (1909).]
474 AUTHOR LIST
lies. (J. G. MacGregor. Phil. Ma^. (5), 41, 276-287, (1806).
On the calculation of the conductivity of mixtures of electrolytes.) [Theoret-
ical.]
1166. (J. G. MacGregor. Phys. Rev. 8, 129-140, (1899).
On the applicability of the dissociation theory to the electrolysis of aqueous
solutions containing two electrolytes with a common ion.) [Inoiganic and
theoretical. ]
1167. (J. G. MacGregor. Zeit. Phys. Chem. 33, 529^539, (1900).
Ueber die Bestimmung der Dissociation von zusammengesetzten Ldsungen
von gegebener Komtentration imd Uber das umgekehrte Problem.) [Inor-
ganic and theoretical. ]
1168. (J. G. MacGregor. Proc. Trans. R. Soc. Canada. (2), 2, Sect. Ill,
65-82, (1896).
On the calculation of the conductivity of electrolsrtes.) [Inorganic and the-
oretical. ]
1169. (J. G. MacGregor. Proc. Trans. R. Soc. Canada. (2), 4, Sect. Ill,
117-148, (1898).
On the calculability of the results of electroljrsis in solutions containing two
electrolytes with one ion in oonmion.) [Inorganic and theoretical. ]
1170. (J. G. MacGregor. Proc. Trans. Nova Scot. 9, 101-119, (1894-1898).
On the calculation of the conductivity of mixtures of electrolytes.) [Inoiganic
and theoretical. ]
1171. (J. G. MacGregor. Proc. Trans. Nova Scot. 10, 67-78, (1898-1902).
On finding the ionization of complex solutions of given concentration, and
the converse problem.) [Inorganic and theoretical.]
1172. (J. G. MacGregor, £. H. Archibald. Phil. Mag. (5), 45, 151-157,
(1898).
On the calculation of the conductivity of aqueous solutions containing two
electrolytes with no common ion.) [Inorganic and theoretical. ]
1178. (J. G. MacGregor, £. H. Archibald. Phil. Mag. (5), 46, 509-^19,
(1898).
On the conductivity method of studjring moderately dilute aqueous solutions
of double salts.) [Inorganic and theoretical.]
1174. A. C. MacGregory. Ann. Physik. (3), 51, 126-139, (1894).
Die electrische Leitfahigkeit einiger Ldsimgen von Salzen, besonders des
Calciums, Strontiums, und Bariums. [Same as 1176. ]
T = 18.00** *0.02^ Hg. U. xaq.= 0.75 -1.5X10-*; sub.
1176. A. C. MacGregory. Phys. Rev. 2, 361-^72, (1894-1895).
Determination of the electric conductivity of certain salt solutions. [Same
as 1174.]
£. Mackay see H. C. Jones.
1176. G. M. J. MacKay. Proc. Trans. Nova Scot. 11, 324-^7, (1902-
1906).
Contribution to the study of hydroxylamine.
T = 18.00° *0.02^ R. O. xaq. = 1.05-1.6X10-*; sub.
W. MacPherson see H. A. Torrey.
1177. T. Madsen. Zeit. Phys. Chem. 36, 290-304, (1901).
VersQche Uber die Abhangigkeit der Hydrolyse von der Temperatur.
T. Madsen see S. Anhenius.
A. MagalhaSs see K. Buchka.
1178. H. Mager. Ann. Chemie. 275, 356-366, (1893). Meas.G. BMmann,
Ueber die Constitution des Suberons und tlber die Ringketone der PimeUns&ure
und Azeli^bisaure. [This is a chapter in an article by J. Wislicenus, pages
309-382.]
AUTHOR LIST 475
1179. O. Magnmifai. Gas. Chim. Ital. 20, 428-140, (1890).
Sul oomportamento della mannite rispetto all'acido borico. [Qiyea in 1189.
Same as 1198.]
T«25®.
1180. G. MagnaiiiiiL Gaz. Chim. Ital. 20, 441-147, (1890).
Sulla oonducib]lit& dettrica delle soltuioni di acido borioo in presenza di dnlcite.
[Same as 1196.]
T=26^
1181. G. Magnaninl. Gas. Chim. Ital. 20, 448-452, (1890).
Sulla oonducibilitji dettrica deUe solusioni aoquose di acido borioo in presensa
degli alooli polivalenti.
T=s25°.
1182. G. MagnaninL Gas. Chim. Ital. 20, 453-158, (1890).
Influenza deU'acido borico sulla conducibilit& dettrica delle solusioni acquoee
di acido tartarico.
1188. G. MagnanmL Gas. Chim. Ital. 21, II, 134-141, (1891).
Sul punto di oongdamento delle solusioni acquoee di acido borioo e mannite.
T«20^to50^
1184. G. MagnanmL Gas. Chim. Ital. 21, II, 21&-228, (1891).
Influensa dell'acido borico sulla conducibilit^ dettrica delle soluzioni acquose
degli acidi organici.
T=25^ X aq. =0.0034; not sub.
1186. G. MagnaninL Gaz. Chim. Ital. 22, I, 541-^58, (1892).
Influenza dell'acido borioo sulla conducibilit^ dettrica delle solusioni idroal-
cooliche degli addi organici.
T=25**.
1186. G. Magnanini. Gas. Chim. Ital. 23, I, 197-251, (1893).
Ricerche ulteriori intomo alia influensa dell'acido borico sulla conducibilitik
dettrica ddle solusioni acquoee degli acidi organid. [Same as 1191.]
Ts25^ X aq. less than 0.004; not sub.
1187. G. MagnaninL Gaz. Chim. Ital. 24, 1, 48-56, (1894).
Intomo alia ipotesi della colorazione degli joni. [Same as 1190 and 1196.]
Hg. U.
1188. G. MagnaninL Gaz. Chim. Ital. 26, II, 92-96, (1896).
Intomo alia ipotesi della colorazione degli joni. [Same as 1197.]
1189. G. Magnanini. Zeit. Phys. Chem. 6, 58-70, (1890).
Ueber das Verhalten des Mannits gegen Borsaure. [Part is same as 1179 and
1198.]
T-25^
1190. G. MagnanmL Zeit. Phys. Chem. 12, 56-62, (1893).
Ueber die Hypothese der Farben der lonen. [Same as 1187 and 1196.]
T for potassium salt is 18^. Hg. U.
1191. G. Magnanini. Atti Accad. Gioenia. (4), 5, Mem. Ill, 1-^1, (1892-
1893).
Ricerche ulteriori, etc. [Same as 1186.]
1192. G. Magnanini. Mem. R. Accad. Modena. (2), 11, 259-270, (1895).
Dissociazione dettrolitica e colorazione.
T=25".
1198. G. Magnanini. Rend. Accad. Linoei. (4), 6, I, 260-266, (1890).
Sul oomportamento della mannite rispetto all'acido borico. [Same as 1179.
Given in 1189.]
1194. (G. Magnanini. Rend. Accad. Lined. (4), 6, I, 411-416, (1890).
Sulla conducibilitji dettrica ddle soluzioni acquose di addo borico in presenza
di mannite.) [Theoretical and quoted.]
476 AUTHOR LIST
1196. G. MacnaniiiL Rend. Aocad. Lincei. (4), 6, 1, 457-483, (1890).
Sulla conduoibilitji elettrica delle soluzioni di acido borico in presensa di dul-
cite. [Same as 1190.]
1196. G. Magnanini. Rend. Accad. Lincei. (5), 2, I, 369-^76, (1893).
Intomo alia ipotesi della oolorazione degli joni. [Same as 1187 and 1190.]
1197. G. MagnaninL Rend. Accad. Lincei. (5), 4, II, 60-63, (1895).
Intomo alia ipoteei della colorazione degli joni. [Same as 1188. ]
Meas. G. Magnanini; see 667.
1198. G. Magnanini, T. BentivogUo. Gaz. Chim. Ital. 23, II, 444r-451,
(1893).
Intomo alio spettro di assorbimento delle soluzioni di alcuni cromoossalati
della serie bleu. [Same as 1200.]
T=25^ Hg. U.
1199. G. Magnanini, T. Bentivoglio. Gaz. Chim. Ital. 23, II, 451-457,
(1893).
Conducibilit^ elettrica delle soluzioni dei sali di acidi organici in presenza di
acido borico. [Same as 1201.]
1200. G. Magnanini, T. Bentivofi^o. Rend. Accad. Lincei. (5), 2, II, 17-23,
(1893).
Intomo alio spettro di assorbimento, etc. [Same as 1198. ]
1201. G. Magnanini, T. BentivogUo. Rend. Accad. Lincei, (5), 2, II, 54-58,
(1893).
Conducibilit^ elettrica delle soluzioni dei sali, etc. [Same as 1199.]
1202. G. Magnanini, M. Scheidt. Gaz. Chim. Ital. 22, I, 43&-44S,
(1892).
Sul comportamento dell'acido deidrodiacetillevulinioo rispetto alia feniUdra-
zina ed alia idrossilamina e sopra im nuovo derivato deU'acido deidrodiaoe-
tillevulinico. [Same as 1203.]
1208. G. Magnanini, M. Scheldt Rend. Accad. Lincei, (5), 1, 1, 169-174,
(1892).
Sul comportamento, etc. [Same as 1202.]
Meaa, Magnus; see 832.
1204. (G. Magri. Rend. Accad. Lined. (5), 16, I, 171-178, (1907).
Ricerche sopra solventi inorganici a basse temperature. Disposizione
sperimentale.)
1206. (G. Magri. Rend. Accad. Lincei. (5), 16, I, 518-^25, (1907).
Ricerche sopra il solvente H2S liquefatto.) [Inorganic]
T«-60°.
G. Magri see U. Antony.
£. G. Mahin see H. C. Jones.
R. D. Mailey see H. M. Goodwin.
1206. L. Maldds. Ann. Chim. Phys. (8), 16, 153-236, (1909).
Recherches exp6rimentales sur les di^lectriques.
1207. G. Malfitano. Compt. Rend. 139, 1221-1223, (1904).
Sur la conductibilit^ 61ectrique des solutions coUoidales.
1208. (G. Malfitano. Compt. Rend. 148, 1045-1047, (1909).
Sur les propri^tds physioo-chimiques des particules ooUoidales dites micelles.)
1209. G. Malfitano, L. MicheL Compt. Rend. 146, 338-341, (1908).
Sur rhydrolyse du perchlorure de fer. Effet de la valence des ions negatifs.
T=50°.
1209a. G. Malfitano, A. N. Moachkoff. Compt. Rend 151, 817-819,
(1910).
Sur la purification de Famidon.
AUTHOR LIST 477
1210. (R. MalmstrOm. Ann. Physik. (4), 18, 413-449, (1005).
Versuch einer Theorie der elektrolytischen Diaaoziation unter Berftcksichti-
gung der dektrischen Energie.) [Theoretical and inorganic. ]
Afeos. R. Malm8ti5m; see 828, 881.
1211. M. £. Maltby. Zeit. Phys. Chem. 18, 133-158, (1895).
Methode zur Bestimmung grosser dektrolytischer Widerst&nde.
1212. O. Manasse, H. Rupe. Her. Deutsch. Chem. Ges. 27, 1818-1822,
(1894). Meas, Franke and Patd,
Ueber die Oxydation des Menthons.
MandaU see Oliveri-MandaU.
1218. W. Manthey. Ber. Deutsch. Chem. Ges. 33, 3081-3086, (1900).
Ueber die Condensation der a-Bromallozimmtsaure. [Same as 1214.]
T=25^ xaq.=8Xl(H.
1214. W. Manthey. Dis. Berlin. (1900).
Ueber die Kondensation von a-Bromallozimmts&ure, sowie tiber die Konsti-
tution des Truxons und seiner Derivate. [Same as 1218.]
1216. L. MarciUy. Bui. Soc. Chim. (3), 31, 119-130, (1904).
Sur Tacide oxypivalique. [Same as 1216.]
T=25^
1216. L. Hardily. Dis. Nancy. (1903).
£tude des acides aa-Dialcoylhydracryliques. [Same as 1216.]
Meas. G. Mariaaz; see 291.
MaikovnIkoY see Markowniko£f.
1217. W. Maikowniko£f. Jour. Prakt. Chem. (2), 49, 409-144, (1894).
Afeos. N. Zelinsky.
Untersuchung des Suberons. [Same as 1218 and 1219 together. Zelinsky's
measurement is really quoted from 2018.]
1218. (W. Markownikoff. Jour. Russ. Phys.-chem. Soc. 25, 364-378, (1893).
Investigation of suberone.) [Same as part of 1217.]
1219. W. Markowmko£f. Jour. Russ. Phys.-chem. Soc. 25, 547-564, (1893).
Investigation of suberone. [Same as part of 1217. Zelinsky is quoted from
2018.]
1220. C. J. Martin, O. Maaaon. Jour. Chem. Soc. 79, 707-714, (1901).
The influence of cane sugar on the conductivities of solutions of potassium
chloride, hydrogen chloride, and potassium hydroxide, with evidence of salt
formation in the last case.
T = 18*. R. O.
N. A. Martin see H. W. Foote.
S. Mascetti see A. Miolati.
O. Masson see C. J. Martin.
1221. (P. Massoulier. Compt. Rend. 130, 773-775, (1900).
Relations entre la conductibilit6 ^lectrolytique et le frottement interne dans
les solutions salines.) [Inorganic]
1222. P. Maasoulier. Compt. Rend. 143, 218-220, (1906).
Sur la relation qui existe entre la resistance ^lectrique et la viscosity des solu-
tions dlectroljrtiques.
T=0^and25^
Master »McMa8ter» q. v.
1228. J. H. Mathews. Jour. Phys. Chem. 9, 641-681, (1905).
On the relation between electrolsrtic conduction, specific inductive capacity and
chemical activity of certain liquids (with a bibliography of dielectric constants).
T=25^
W. C. Matignon see M. Berthelot
K. Mattisson see B. Holmberg.
478 AUTHOR LIST
1224. P. Mauz. Dis. TQbingen. (1904).
Physikalisch-chemische Untereuchungen Uber Alkaloide.
T«-18^ R. O. X aq. sub.; A also given without sub. of aq.
fUMecui, P. Mauz; see 1891a.
1226. A. Mayer. Compt. Rend. 143, 515-516, (1906).
Sur les complexes de Talbumine pure.
1226a. A. Mayer, G. Schae£fer. Arch. Fisiol. 7, 457-489, (1909).
Contribution k I'^tude des acidalbumines, particulidrement des acidalbumines
d^acides gpras.
1226b. H. Mayer. Jour. Phys. (4), 9, 584^99, (1910).
Nouvelle m6thode ^lectrique pour mesurer Finfluence de la lumidre sur la
chromogdlatine.
1226c. H.Mayer. Zeit.Chem.Ind.KoUoide.Beiheft 1, 58-00, (1909-1910).
XJeber eine elektrische Methode sur Messung der durch Belichtung in Chro-
matgelatineschichten verursachten Ver&nderungen.
T-20^
1226. H. Mayer. Zeit. Phys. Chem. 66, 33-70, (1909).
Ueber eine elektrische Methode zur Messung der durch Belichtung in Chronukt-
gelatineschichten verursachten Ver&nderungen.
T-20**to30^
1227. A. Mazzucchelli. Rend. Soc. Chim. Roma. 3, 80-96, (1906).
Sopra la oosidetta '' regola di valemsa " dei sali polibasici.
T=25^and28^ R. O.
1228. A. MazzttCcheUi. Rend. Soc. Chim. Roma. 6, 344-346, (1908).
Sulle curve di neutralizzasione graduate degli addi. [Priority claim; and
criticism of 1718.]
1229. (J. W. McBain. Proc. Waehington Acad. 9, 1-78, (1907).
The experimental data of the quantitative measurements of electrolytic mi-
gration. To the end of the year 1905.) [Gives a critical bibliography, with
tables of experimental values found by each author.]
1229a. J. W. McBain, M. Taylor. Ber. Deutsch. Chem. Ges. 43, 321-322,
(1910).
Ueber die elektrische Leitfahigkeit von Seifenldsungen.
T-89.75^
1280. H. N. McCoy. Am. Chem. Jour. 31, 503-521, (1904).
On the ionization constants of phenolphthalein and the use of this body as
an indicator.
1281. H. N. McCoy. Jour. Am. Chem. Soc. 30, 688-694, (1908).
Two new methods for the determination of the secondary ionization constants
of dibasic acids.
T=20^
1282. (H. N. McCoy. Jour. Am. Chem. Soc. 30, 1074^1077, (1908).
The relation between the ionizing power and the dielectric constants of sol-
vents.)
1288. W. McCracken. Am. Chem. Jour. 39, 586-613, (1908).
Studies in catalysis. The catalysis of imidoesters. [k same as in part of 166G
and 1667.]
T=25**=fc0.01®. R. O. X aq.-=4XlO-«; sub. for neutral solutions, but
not -for acid solutions.
Meas, W. McCracken; see 1667.
1288a. D. Mcintosh. Jour. Am. Chem. Soc. 32, 542-547, (1910).
The basic properties of oxygen: compounds of dimethylpyrone and the halogen
hydrides.
T- -100^ and -78*.
AUTHOR LIST 479
ISai. D. Mcintosh. Jour. Phys. Chem. 11, 306^17, (1907).
The physical properties of liquid and solid acetylene.
1285. (D. Mcintosh. Phil. Mag. (6), 41, 510^16, (1896).
On the calculation of the conductivity of mixtures of electroljrtes having a
conunon ion.) [Same as 1286. Inorganic and theoretical. ]
1286. (D. Mcintosh. Proc. Trans. Nova Scot. 9, 120-133, (1894-1898).
On the calculation, etc.) [Same as 1286.]
D. Mcintosh see S. H. Archibald.
" '* see F. M. G. Johnson.
" " see B. D. Steele.
'* ** see J. W. Walker.
1287. D.McIntoflh,B.D.Ste^e. Proc. R.Soc. London. 73,450-453,(1904).
On the liquefied hydrides of phosphorus, sulphur, and the halogens as con-
ducting solvents. [Qualitative. ]
1288. The reference under this number has been omitted intentionally.
1289. A. McKenzie. Jour. Chem. Soc. 75, 753-770, (1899). Meaa. W.
[A,] Roth.
Active and inactive phenylalkylozyacetic adds.
T-25^ Hg. U.
Meaa, L. McMaster; see 904.
L. McMaster see H. C. Jones.
** *' see H. C. Jones, S. C. Bisghsm.
G. Mehrtens see M. Bnsch.
A. C. Melcher see A. A. Noyes.
1289a. J. Mellanby. Jour. Physiol. 35, 473-499, (1906-1907).
The physical properties of horse serum.
T-20*to70*.
1289b. J. Mellanby. Jour. Physiol. 36, 288-333, (1907-1906).
The precipitation of the proteins of horse serum.
1240. J. W. MeUor. Jour. Chem. Soc. 79, 126-134, (1901).
Some a-alkyl substitution products of glutaric, adipic, and pimeUo adds.
T is about 24*.
1241. R. H. Mennicke. Dis. Ldpzig. [Probably 1897].
Ueber fraktionirte F&llung organischer Basen. [The accuracy of the values
given is doubtful.]
T=25^ S. U. xaq.«0.7-1.5X10-«; notsub.
1242. (N. MenschutUn. Zeit. Phys. Chem. 6, 41-57, (1890).
Ueber die Affinit&tskoefl^enten der Alkylhaloide und der Amine.) [Velodty
of reaction in organic solvents.]
E. Merritt Phys. Rev. 27, 367-399, (1906). See £. L. Nichols, £.
Menitt.
S. Menitt see S. L. mchols.
1248. P. H. ▼. d. Menlen. Rec. Trav. Chim. 15, 323-348, (1896).
L'action des alcools sur les isoimides. [Full tables of A in 1244. Only k is
given here. ]
T=25*.
1244. P. H. ▼. d. Menlen. Dis. Basel. (1896).
Zur Kenntniss dniger Derivate der Camphers&ure und Hemipins&ure. [Has
full tables of A, otherwise same as 1248.]
T=25®.
1246. W. MeuseL Dis. HaUe. (1900).
Ueber Acetphenylgly cin-o-carbons&ure. [Part given in I8I89 1814 and 1817. ]
T=25.0^ R. O. X aq. =2.3-3.0XlO-«.
Meaa. W. Mensel; see 1818.
480 AUTHOR LIST
F. 7. Meyenburg aee K. Auwers, E« KObnen
1246. H. Meyer. Monatsh. 28, 1231-1237, (1907). Meas, FUuchner.
Die KonstitutioDsbestimmung der isomeren Orthoketons&urederivate. [Same
as 1247.]
1247. H. Meyer. Sitzber. Akad.vWien. 116, 2b, 1137-1143, (1907). Meas.
FUuchner,
Die Konstitutionsbestimmung, etc. [Same as 1246.]
1248. J. Meyer. Ber. Deutsch. Chem. Ges. 36, 3599-3601, (1903).
Zur Kemitnifls der Citronens&ure.
T-26^
1249. J. Meyer. Zeit. Elektrochem. 13, 494-506, (1907).
Zur Kemitnis der nmkehrbaren Realctionen erster Ordnmig.
T is about 25.0**.
1260. K. H. Meyer. Dis. Leipzig. (1907).
Untersuchungen fiber Halochromie. [Most is given in 767ai the rest is same
as 1261.]
T=25^ R. O.
EL H. Meyer see A. Hantzsch.
1261. K. H. Meyer, A. Hantzsch. Ber. Deutsch. Chem. Ges. 40, 3479-
3488, (1907).
Ueber die Halochromie dee Phenolphthaleins und seiner Ester. [Given in
1260.]
T=25^ R. O.
V. Meyer see P. Askenasy.
V. J. Meyer see A. Rosenheim.
Meas. W. Meyeifaoffer; see 1907, 1921.
1262. O. Mezger. Dis. Tubingen. (1902).
Beitrage zur Kenntnis des H&matins. [Same as 1038.]
T«25^
Meas. O. Mezger; see 1080, 1088.
1268. (A. Michael, R. F. Brunei. Am. Chem. Jour. 41, 11^148, (1909).
On the relative ease of addition in the alkene group.)
1264. A. Michael, O. D. £. Bunge. Ber. Deutsch. Chem. Ges. 41, 2907-
2913, (1908).
Ueber den stereochemischen Verlauf der Addition von Chlor zu Crotonsfiure.
X aq.=* 0.6X10"'.
1266. (A* Michael, H. Hibbert Ber. Deutsch. Chem. Ges. 41, 1080-1091,
(1908).
Ueber die vermeintUche Beziehung zwischen Dielektrizit&tskonstante und iso-
merisierender Kraft orgamscher Losimgsmittel bei Enol-Keton-Desmotropen.)
1266. A. Michaelis. Ann. Chemie. 339, 117-193, (1905). Meas. Blume.
Ueber 5-Aminopyrazole und Qber Iminopyrine. [Same as 214.]
1267. (A. Michaelis, E. Hepner. Ber. Deutsch. Chem. Ges. 36, 3271-3279,
(1903).
Ueber Anilopyrin und Phenyl-methyl-anilino-pyrazol.)
1268. L. Michaelis. Biochem. Zeit. 19, 181-185, (1909).
Die elektrische Ladung des Serumalbumins und der Fermente.
L. Michaelis see P. Rona.
1268a. L. Michaelis, H. Davidsohn. Biochem. Zeit. 28, 1-6, (1910).
Die isoelektrische Konstante des Pepsins.
1268b. L. Michaelis, B. Mostynski. Biochem. Zeit. 24, 79-^1, (1910).
Die isoelektrische Konstante und die relative Acidit&tskonstante des Sorum*
albumins.
T = 18^ kw-0.60XlO-^*atl8^
AUTHOR LIST 481
1268c. L. Michaelis, B. MostynskL Biochem. Zeit. 25, 401-410, (1910).
Die innere Reibung von Albuminldsungen. [See criticism by Pauli, Wagner,
Biochem. Zeit. 27, 296, and reply by Michaelis, Biochem. Zeit. 28, 353.]
1259. L. MichaeUs, P. Rona. Biochem. Zeit. 18, 317--339, (1909).
Elektrochemische AlkalinitatsmcBsungen an Blut und Sermn.
T = lO*' to 40^
1269a. L. Michaelis, P. Rona. Biochem. Zeit. 23, 61-67, (1909-1910).
Der Einfluss der Neutralsalze auf die Indicatoren.
1269b. L. MichaeUs, P. Rona. Biochem. Zeit. 23, 364-369, (1909-1910).
Beitrage z\ir Frage der Glykol3r8e. I. Die Alkaliempfindlichkeit des Trau-
benzuckers.
1269c. L. Michaelis, P. Rona. Biochem. Zeit. 27, 38-52, (1910).
Beitrage zur allgemeinen Eiweisschemie. I. Die Koagulation des denaturier-
ten Albimiins als Ftmktion der Wasserstoffionenkonzentration und der Salze.
1260. L. Iftichaelis, P. Rona. Zeit. Elektrochem. 14, 251-253, (1908).
Zur Frage der Bestinunung der H'-Ionenkonzentration durch Indikatoren.
1261. J. I. Michajlenko. Jour. Russ. Phys.-chem. Soc. 30, 466-475, (1898).
Action of zinc on a mixture of bromoisobutyric ether and formic ether.
T=25^
Meaa, J. L Michajlenko; see 1476.
1262. J. I. Michajlenko, W. P. Javorskij. Jour. Russ. Phys.-chem. Soc.
32, 328^346, (1900).
Action of zinc on a mixture of bromoisobutyric ether and formic ether.
T-25^
L. Bfichel see G. Malfitano.
1262a. (G. Mie. Ann. Physik. (4), 33, 381-399, (1910).
Hydratisierung und Molekularwarme der lonen in sehr verdfUmten wfisserigen
Lasungen.) [Inorganic]
A. Milesi see L. Francesconi.
1263. A. Minozzi. Gaz. Chim. Ital. 29, I, 421^39, (1899).
Sopra Tafl^tH fra alcuni acidi ed alcune basi in alcool metilico.
[T probably 25^1
1264. N. Mintz. Dis. Leipzig. (1891). Meas. [P.]Walden,
Ueber Aethyldimethylbemsteins&ure und symmetrische Aethylmethylglutar-
sauren.
N. Mintz see C. A. Bischo£f.
1266. A. MioUti. Ber. Deutsch. Chem. Ges. 26, 1788-1790, (1893).
Zur Kenntniss des Parafuchsins. [Same as 1267.]
T=25'*.
1266. A. MioUti. Ber. Deutsch. Chem. Ges. 28, 1696-1701, (1895).
Ueber die Constitution der Fuchsine. [Same as 1268 with abridged text. ]
1267. A. MioUti. Gaz. Chim. Ital. 23, II, 18-21, (1893).
Sulla costituzione della parafucsina. [Same as 1266.]
T=25^ S. U.
1268. A. IftioUti. Gaz. Chim. Ital. 25, II, 217-232, (1895).
Sulla costituzione delle fucsine. [Same as 1266.]
T=25®.
1269. A. IftioUti, (R. PizzigheUi). Jour. Prakt. Chem. (2), 77, 417-156,
(1908).
Zur Kenntnis der komplexen Sfturen. I. Ueber die Leitf&higkeit von molyb*
dans&urehaltigen Gemischen.
T»25^. X aq. very small; not sub.
Mea8. A. Bfidati; see 669, 882.
A. MioUti see A. Hantzsch.
" " see A. Werner.
482 AUTHOR LIST
1270. A. MioUti, I. Bellucd. Zeit. Anorg. Chem. 26, 209-221, (1001).
Ueber die Pentacblorplatinfl&ure.
T=25^ R. O.
1271. (A. IftioUti, S. MascettL Gaz. Chim. Ital. 31, I, 93-139, (1901).
Contributo alia conoecenza di alcuni acidi inorganici.) [Inorganic]
1272. A. Mittasch. Zeit. Phys. Chem. 46, 37-12, (1903).
Einige Beobachtungen fiber Ldsungsverrndgen und elektrische Leitf&higkeit
von fltkssigem Nickelkohlenoxyd.
T=0®; for qualitative measurements » —20® to +20 ^
1273. J. A. Mj5en. Ber. Deutsch. Chem. Ges. 30, 1227-1240, (1897).
Ueber die Polymethacryls&ure. [Same as 1274.]
T=25®.
1274. J. A. MjSen. Dis. Leipzig. (1894).
Ueber die Polymethacryls&ure. [Same as 1273.]
1275. M. Moest Dis. Basel. (1899).
Ueber die elektrische Leitfahigkeit von Oxychinonen und Salzen derselben.
T=26^ S. U. xaq. notover 1X10"«.
1276. P. B. Mojolu. Dis. Lausanne. (1909).
I. Determination des poids mol^culaires a T^tat liquide. II. Dosage et
separation par oonductivite eiectrique des halog^nes et des m^taux alcali-
no-terreux.
Monte «DaM<mte, q. v.
Mea8. Montemartini; see 76.
1277. (V. Monti. Nuovo Cim. (3), 36, 75-81, (1894).
Sulla relazione fra la oonducibilitjl elettrica e I'attrito intemo degli dettroliti.)
[Inorganic. An abstract, with data, of 1278.]
1278. (V. Monti. Atti Accad. Torino, 28, 476-487, (1892-1893).
Sulla relazione fra la conducibilit^ elettrica e Tattrito intemo degli dettroliti.)
[Inorganic]
1279. V. Monti. Atti 1st. Veneto. 50, 1705-1714, (1891-1892).
Sulle conducibOit^ moleoolari di alcuni sali alcalini disciolti in mescolanze
d'acqua e glicerina.
T = 18^ Hg. U.
1280. V. Monti. Atti. 1st. Veneto. 51, 1482-1488, (1892-1893).
Di alcuni casi anomali di dissociazione elettrohtica.
T=18^
1281. (B. E. Moore. Phys. Rev. 3, 321-334, (1895-1896).
On the viscosity of certain salt solutions.) [Quoted.]
1282. (T. S. Moore. Jour. Chem. Soc. 91, 1373-1378, (1907).
A method for the determination of the equilibrium in aqueous solutions of
amines, pseudo-acids and -bases, and lactones.) [Theoretical. Abstract in
1284.]
1283. T. S. Moore. Jour. Chem. Soc. 91, 1379-1384, (1907).
The " true " ionisation constants and the hydration constants of piperidine,
ammonia, and triethylamine. [Abstract in 1285.]
1284. (T. S. Moore. Proc. Chem. Soc. 23, 154, (1907).
A method for the determination, etc.) [An abstract of 1282.]
1286. T. S. Moore. Proc. Chem. Soc. 23, 154, (1907).
The " true " ionisation constants, etc. [An abstract of 1283, with data. ]
T. S. Moore see N. V. Sidgwick.
1286. A. Morello. Gaz. Chun. Ital. 30, I, 257-264, (1900).
Energia di alcuni acidi sciolti in miscugli di solventi organici ed aoqua.
T=25^
AUTHOR LIST 488
1287. J. L. IL Morgan. Zeit. Phys. Chem. 17, 513-535, (1895).
Die Bestimmung von Cyanionen auf dektrometrischem Wege. [Same as
1288.]
T-17.5•tol9^
1288. J. L. R. Morgan. Dis. Leipzig. (1895).
Die Bestimmung von Cianionen auf elektrometrischem Wege. [Same as
1287.1
1289. (J. L. R. Morgan, C. W. Kanolt Jour. Am. Chem. See. 28, 572-588,
(1906).
The combination of a solvent with the ions.)
1289a. G. MonizzL Biochem. Zeit. 22, 232-243, (1909).
Untersuchungen fiber die Gelatinierung des Eiweisses.
T=25*.
1289b. G. MorazzL Biochem. Zeit. 28, 97-105, (1910).
Ueber die Aenderungen der durch Hamstoff in eiweisshaltigen Fltkssigkeiten
hervorgerufenen inneren Reibung und elektiischen Leitf&higkeit.
T=25^
A. N. Moschkoff see G. Malfitano.
B. Mo8t3mski see L. MichaeliBi
W. R. Mott see H. E. Patten.
1290. (P. F. Mottelay. Trans. Am. Electrochem. Soc. 13, 453-479, (1908).
Bibliography of electrochemistry and allied subjects.)
1291. B. Miihlhauser. Dis. Basel. (1902).
A. Ueber Untersuchungen in der Acridinreihe. B. Zur Kentnniss der a-Ae-
thylidenglutars&ure. [Same as 668 for k; gives also tables of A. ]
T=25^ R. O.
B. MiQilhatiser see F. Fichter.
1292. H. MiUler. Dis. Basel. (1905).
Die Reductionsprodukte des 2,4-Dimtrorhodanbenzols. Affinit&tsmessungen
an einbasischen Fetts&uren. [Same as 669. No details of conductivity meas-
urements are given here, but measurements of saponification are given in
fuU.]
H. MiiUer see F. Fichter.
Meas. N. L. MfiUer; see 316, 317, 1916, 1929.
P. Mflller see A. Rosenheim.
1292a. W. J. MiiUer. Ber. Deutoch. Chem. Ges. 43, 2609-2613, (1910).
Ueber die Geschwindigkeiten der Umlagerung von Oxoniumbasen, Farbbasen
und -cyaniden in die Carbinolbasen und Leukocyanide. [Given in 966a.]
T-0^
MmiB. W. J. MfiUer; see 968a.
1298. M. Mflndler. Dis. Heidelberg. (1901).
Ueber Aminol3r8e. [Part of these measurements is given in 660.]
T=25^
Meas, M. Mflndler; see 660.
1294. P. T. MuUer. Bui. Soc. Chim. (3), 17, 390, (1897).
[An abstract with no title. Measurements given in full in 1296.]
1296. P. T. MuUer. Bui. Soc. Chim. (3), 27, 1011-1014, (1902).
Etudes physico-chimiques sur la fonction acide oximid^. (I). Conductibilit^
dlectrique des others oximidocyanao^tiques. [Abstract given in 1294. ]
T=25^ R. O.
1296. P. T. Muller, S. Bauer. Jour. Chim. Phys. 2, 472-497, (1904).
Determination de la chaleur de dissociation de quelques acides isonitros^
(pseudo-acides) par la m^thode des conductibOit^.
T^O"* to 40^ xti aq. » 1.24 Xl(H; not sub. for adds, sub. for salts.
484 AUTHOR LIST
1897. P. T. MttUer, M. PauL Bui. Soc. Chim. (3), 35, 197-198, (1906).
[An abstract with no title. Measurements given in full in 1890.]
T=25^and36^
1296. S. P. Mulliken. Am. Chem. Jour. 15, 523-^533, (1893).
A new class of organic electrosyntheses.
1299. S. P. Mulliken. Dis. Leipzig. (1890).
Ueber die Konstitution der Chlorzimmts&uren. [Quoted in 168S.]
1800. O. Mumm. Zeit. Phys. Chem. 62, 589-600, (1908).
Die Kinetik des Diazoessigesters und das VerdOnnungsgesets.
1801. £. Mumme. Dis. Halle. (1901).
Ueber die Einwirkung von Chloressigs&iu^ auf Anthranils&ure. [Qualitative.
Same as 1817. See 1246 for measurements.]
Meas, £. Mumme; see 1816.
E. Mumme see D. Vorltnder.
F. Mylitts see F. Kohlrauach.
N.
1802. R. Nadni, T. Costa. Gaz. Chim. Ital. 21, 1, 554-^565, (1891).
Ricerche sopra i derivati solfinici e loro confronto con le combinasioni degli
ammonii organici. [Same as 1804. ]
1808. (R. Nasini, T. Costa. Rend. Accad. Lincei, (4), 6, 11,284-291,
(1890).
Sul potere rif rangente di alcimi derivati della trietilsolfina.) [No conductivity. ]
1804. R. Nasini, T. Costa. Rend. Accad. Lincei, (4), 7, 1, 623-631, (1891).
Ricerche sopra i derivati solfinici, etc. [Same as 1802.]*
1806. R. Nasini, A. Pezzolato. Gaz. Chim. Ital. 23, I, 43-58, (1893).
Spostamento della nicotina dai suoi sali e azione dell'alcool sopra di essi.
[Same as 1806 and 1807.]
T=25^
. 1806. R. Nasini, A. Pezzolato. Zeit. Phys. Chem. 12, 501-504, (1893).
Die Verdrangung des Nikotins aus seinen SaLzen und die Wirkung des Alkohols
auf dieselben. [Same as 1806 and 1807.]
T«25^
1807. R. Nasini, A. Pezzolato. Rend. Accad. Lincei. (5), 1, II, 332-343,
(1892).
Spostamento della nicotina dai suoi sali, etc. [Same as 1806 and 1806.]
1808. (A. Naumann. Ber. Deutsch. Chem. Ges. 32, 999-1004, (1899).
Ueber Reactionen in nichtwfissrigen Lfisungsmitteln.)
1809. (A. Naumann, A. Rflcker. Jour. Prakt. Chem. (2), 74, 209-217,
(1906).
Seitherige Verfahren zur Bestimmung der Hydrolyse.) [Bibliography of
methods of determining hydrolysis. ]
1809a. R. Naumann. Zeit. Elektrochem. 16, 772-778, (1910).
Ueber die Hydrolyse des Cyans.
T»0*' and 18^ R. O.
1810. (J. U. Nef. Ann. Chemie. 270, 267-335, (1892).
Ueber das zweiwerthige Kohlenstoffatom.) [Quoted.]
F. Neger see H. v. Pechmann.
1811. Negreano. Compt. Rend. 106, 1665-1668, (1888).
Mesure de la vitesse d'^th^rification k I'aide des oonductibilit^ ^ectriques.
[Qualitative. ]
C. Neizert see £. Rimbach.
AUTHOR LIST 485
1812. (P. NeU. Ann. Physik. (4), 18, 323-^7, (1905).
Studien Qber Diffuaionsvorg&nge w&Bseriger Loeungen in Gelatine.) [Inor-
ganic]
1318. V. V. Neminskij, W. A. Plotnikow. Jour. Russ. Ph3r8.-chem. See.
40, 337, (1906).
The electrolysis of compounds of aluminum bromide with toluene and ben-
zene. [Summary of 1814.]
1814. V. V. Neminskij, W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc.
40, 391-396, (1908).
The electrolysis of compounds of aluminum bromide with toluene and benzene.
[Sunmiary given in 1818.]
T-18^ R. O.
1816. W. Nemst Zeit. Phys. Chem. 14, 155-156, (1894).
Zur Dissociation des Wassers.
T = 18^
1816. W. Nemst Zeit. Phys. Chem. 14, 622-^63, (1894).
Methode zur Bestimmung von Dielektrizit&tskonstanten.
Meas, W. Nemst; see 808^ 1111.
W. Nemst see M. Loeb.
1817. W. Nemst, C. Hohmann. Zeit. Phys. Chem. 11, 352^90, (1893).
Bildung der Amylester aus S&uren und Amylen.
T = 18.5^
1818. W. Neimuum. Zeit. Physiol. Chem. 45, 216-251, (1905).
Ueber Peptone. [Same as 1819.]
R. O.
1819. W. NeumAim. Dis. I^eipzig. (1905).
Ueber Peptone. [Same as 1818. ]
1820. £. L. Nichols, B. Merritt Phys. Rev. 18, 447-449, (1904).
The efifect of light upon the absorption and the electrical conductivity of fluo-
rescent solutions. [Same as 1821. The text is abridged. ]
1821. £. L. Nichols, £. Merritt Phys. Rev. 19, 396-421, (1904).
Studies of luminescence. IV. The influence of light upon the absorption and
electrical conductivity of fluorescent solutions. [Same as 1820.]
1822. (E. L. Nichols, £. Merritt Phys. Rev. 27, 367-399, (1908).
[This article is by Merritt alone, though both names are given. ]
Studies in luminescence. Nichols and Merritt. X. The phenomena of phos-
phorescence considered from the standpoint of the dissociation theory.)
1828. M. NicoUier. Dis. Lausanne. (1907).
Conductibilitds limites de 2 Electrolytes binaires dans quelques dissolvants
organiques.
T=:25^ 8. U.
1824. M. NicoUier, P. Dutoit Bui. Sod. Vaudoise. Compt. Rend. April
(1906). II.
Variation de conductibilit^ des solutions d'iodures et bromures alcalins dans
les dissolvants organiques, sous I'influence de la lumidre. [Same as 1826.]
1826. M. NicoUier, P. Dutoit Bui. Soc. Vaudoise. Proc. Verb. 42, VI,
(1905-1906).
Variation de conductibilit^, etc. [Same as 1824.]
Mea8, Nicdosi; see 268.
1826. F. Nicolosi-RoncatL Rend. Accad. Sdenz. (Napoli). (3*), 13, 357-
364, (1907).
Ricerche su la conduttiviUl elettrica e la pressione osmotica nei vegetaU.
T-25^to28*.
486 AUTHOR LIST
1827. S. 7. Niementowaki, J. ▼. RoszkowakL Zeit. Phys. Chem. 22, 145-
169, (1897).
Ueber die Diazotiening des Anilins.
T-26*.
1328. (S. NiementowsU, J. RoszkowskL Bui. Acad. Craooy. (1896), 324-
325.
Ueber die Diasotirung des Anilins.) [An abstract. No data. See 1827 for
measurements.]
S. Nirdlinger see S. F. Acrae.
O. N6tzel see S. Deuasen, G. Heller.
1829. J. F. Norris. Am. Chem. Jour. 38, 627-642, (1907).
On the base-Corming property of carbon.
1880. V. NoTik. Phil. Mag. (5), 44, 9-20, (1897).
Specific electric conductivities and freezing-points of solutions of water in
formic acid.
T«8.52^ Hg. U.
1881. A. NowizkL Dis. Heidelberg. (1898).
Ueber den Einfluss der Temperatur auf die ZurQckdr&ngung der Ltelichkeit
schwer Idslicher SaLse durch Zusatz eines gleichionigen Elektrolyten.
T=26*'and35*. Hg. U.
1882. A. A. Noyes. Jour. Am. Chem. Soc. 30, 33^-353, (1908).
The conductivity and ionization of salts, acids and bases in aqueous solutions
at high temperatures. [Same as 1888.]
T = 18**to306^ R. O.
1882a. (A. A. Noyes. Jour. Am. Chem. Soc. 32, 815-^1, (1910).
Quantitative application of the theory of indicators to volumetric analysis.)
1888. A. A. Noyes. Jour. C^him. Phys. 6, 505-^523, (1908).
La conductibilit^ et Tionisation des sds des bases et des acides en solution
aqueuse aux temperatures ^lev^es. [Same as 1882.]
1884. A. A. Noyes. Zeit. Phys. Chem. 6, 241-267, (1890).
Ueber die gegenseitige Beeinflussung der Loslichkeit von dissodierten Kdrpem.
1885. A. A. Noyes. Zeit. Phys. Chem. 11, 495-500, (1893).
Ueber die Wasserstoffionabspaltung bei den sauren Salzen.
1886. (A. A. Noyes. Zeit. Phys. Chem. 26, 699-710, (1898).
Ueber die Zuverlasmgkeit der mittels der elektrischen Leitf &higkeit bestimmten
Dissociationswerte.) [Theoretical and quoted. ]
1887. A. A. Noyes, C. G. Abbot Zeit. Phys. Chem. 16, 125-138, (1895).
Eine Priif ung der Prinzipe der Loslichkeitsbeeinflussung und ein Vergleich der
daraus und aus der elektrischen Leitf&higkeit berechtneten Dissociationswerte.
T=39.75^ Hg. U. X4oaq. = 1.7-2.4XlO-«.
1888. A. A. Noyes, J. Johnston. Jour. Am. Chem. Soc. 31, 987-1010,
(1909). Meas. R. D, Gale.
The conductivity and ionization of polybasic salts.
T=0**tol56^ R. O. xaq.«0.6-0.7XlO-«; sub.
1889. A. A. Noyes, T. Kato. Jour. Am. Chem. Soc. 30, 318-334, (1908).
The equivalent conductance of hydrogen-ion derived from transference ex-
periments with nitric acid. [Same as 1840.]
1840. A. A. Noyes, T. Kato. Zeit. Phys. Chem. 62, 420-439, (1908).
UeberfOhrungsversuche mit Salpetei> und Salzs&ure. [Same as 1889.]
1841. A. A. Noyes, T. Kato, R. B. Sosman. Jour. Am. Chem. Soc. 32,
159-178, (1910). Meas, Y. Kato, R. B. Sosman.
The hydrolysis of ammonium acetate and the ionization of water at high tem-
peratures. [Same as 1841a.]
T = 18*to306^
AUTHOR LIST 487
1841a. A. A. NoyeB» T. Kato, R. B. Sosman. Zeit. Phys. Chem. 73, 1-24,
(1910).
Die Bydrolyse von Ammoniumacetat und die loniaation von Wasser bei hohen
Temperaturea [Same as 1341.]
IMlb. A. A. NoyeBy A. C. Melcher, H. C. Cooper, G. W. Baatman. Zeit.
Phys. Chem. 70, 335-377, (1910). Meas. H, C. Cooper,
The conductivity and ionization of salts, acids and bases in aqueous solutions
at high temperatures. [See also 1S32. ]
T = 18* to 306^
1842. A. A. NoyeB» G. V. Saminet Zeit. Phys. Chem. 43, 513-^538,
(1903).
Elxperimentelle PrCkfung der thermodynamischen Besiehung zwischen der
Losungsw&rme und der Aenderung der Ldslichkeit mit der Temperatur im
Falle dissociierter Substanzen.
T=0*to30^ R. O.
1848. A. A. Noyes, W. H. Whitcomb. Jour. Am. Chem. Soc. 27, 747-759,
(1905).
The solubility of lead sulphate in ammonium acetate solutions.
T-25^ R. O.
M. Nozari see A. CampettL
1844. A. Oberbeck. Ann. Physik. (2), 155, 595-602, (1875).
Ueber eine Methode die Leitungsf&higkeit von Flilssigkeiten fttr Elektricitat
zu bestimmen.
1845. J. Obenniller. Her. Deutsch. Chem. C}es. 40, 3623-3647, (1907).
Ueber die Einwirkung von Schwefels&ure auf Phenol.
1846. J. Obenniller. Zeit. Anorg. Chem. 59, 7^-81, (1908).
Die Acidit&t der verschiedenen Phenolsulfons&uren. [Criticizes adversely
1090 and 1091. See also 1715. Measurements given in 1846.]
1847. H. ObUden. Dis. Basel. 1-iO, (1906).
Ueber a-Aethyl-/9Y-pentens&ure und a-Aethyl-a/3-pentensfiure. [Same as
670. Same as part of 669 for k, but also gives A.]
T=25^ R. O. X aq.=3.5XlO-«.
Afecw. H. Obladen; see 669.
H. Obladen see F. Fichter.
1848. (G. Oddo, E. ScandoU. Gaz. Chim. Ital. 39, II, 1-21, (1909).
Sullo stato delle sostanze in soluzione in acido solforico assoluto.) [Criticism
of 760 and 761.]
1849. B. Oehler. Dis. MOnchen. (1896). Meas. Bauer,
Abkommlinge von Menthon und Tetrahydrocarvon.
1860. H. V. Oettingen. Zeit. Phys. Chem. 33, 1-38, (1900).
Ueber die Zersetzung des Natriiunthiosulfats durch S&uren.
T=20^
P. Offenhauer see F. Stohmann, C. Kleber, Langbein.
1861. M. Oker-Blom. Arch. Gesammt. Physiol. 79, 111-145, (1900).
Thierische Safte und Gewebe in phsrsikalisch-chemischer Beziehung. I. Die
elektrische Leitf&higkeit des Blutes.
1362. M. Oker-Blom. Arch. Gesanmit. Physiol. 79, 510-533, (1900).
Thierische Safte und Gewebe in physikalisch-chemischer Beziehung. II. Die
Abh&ngigkeit der elektrischen Leitfahigkeit des Blutes von den Blutkorper-
chen. Beitrag zur Lehre von der Lieitfahigkeit der Suspensionen.
488 AUTHOR LIST
1S08. M. Oker-Blom. Arch. Gesammt. Physiol. 81, 167-221, (1900).
Thierische S&fte und Gewebe in physikalisch-chemischer Beziehung. III.
M ittheilung. Die Durchlfiasigkeit der rothen Blutkdrperchen f 0r venschiedene
Stoffe, beurtheilt nach der elektrischen Leitf&higkeit.
1368a. £. OUyeri-MandallL Gas. Chim. Ital. 40, I, 10^107, (1910).
Conduttivitil elettrica di alcuni acidi idrofl^ammici.
[Probably 25^] x,* aq.«1.6Xl0-«.
1854. Y. Osaka. Zeit. Phys. Chem. 35, 661-706, (1900).
Ueber die Birotation der d-Glukose.
1866. (T. Osaka. Zeit. Phys. Chem. 36, 639-542, (1901).
BesiehuDg zwischen der Dissociationskonstante und dem Diasociationsgrade
eines Elektrolyts in Gegenwart anderer Elektrolyte.)
M eos. T. Osaka; see 892.
1866a. W. A. Osborne. Jour. Physiol. 27, 398-406, (1901-1902).
Caseinogen and its salts.
T-25*'to48.8^
1866. L. Oslan. Dis. Heidelberg. (1901).
Dynamische Untersuchungen Qber die Verseifung des Acetessigesters und
seiner Methylsubstitutionsprodukte. [Same as 661 for 25^, but gives also
measurements at 1^ and 35^.]
T = 1^25^and35^
L. Oslan see H. Goldschmidt.
Mea8, G. Osswald; see 786.
G. Osswald see A. Hantzsch.
1867. W. Ostwald. Jour. Prakt. Chem. (2), 30, 93-95, (1884).
Notiz Qber das elektrische LfeitungsvermOgen der S&uren.
1868. W. Ostwald. Jour. Prakt. Chem. (2), 30, 225-237, (1884).
Elektrochemische Studien. Die elektrische Leitungsffihigkeit der S&uren.
T «25*'. Special unit for conductivity; see also 1868.
1869. W. Ostwald. Jour. Prakt. Chem. (2), 31, 219-223, (1885).
Ueber die Zuverlfissigkeit elektrischer Widerstandsbestimmungen mit Weehsd-
strdmen.
T=25^ Special unit.
1860. W. Ostwald. Jour. Prakt. Chem. (2), 31, 307-317, (1885).
Studien zur chemischen Dynamik. Die Inversion des Rohrzuckers.
T-25^ Special unit.
1861. W. Ostwald. Jour. Prakt. Chem. (2), 31, 433-462, (1885).
Elektrochemische Studien. Das Verdtlnnungsgesetz.
T=25^ Special unit.
1862. W. Ostwald. Jour. Prakt. Chem. (2), 32, 300-374, (1885).
Elektrochemische Studien. Ueber den Einfluss der Zusanmiensetzung und
Constitution der S&uren auf ihre elektrische Leitfahigkeit.
Ts25°. Special unit. [Multiply by 4.248 to change to Hg. U.; see
1868.] In the tables, all the measurements quoted from this article
have been changed to Hg. U.
1868. W. Ostwald. Jour. Prakt. Chem. (2), 33, 352-370, (1886).
Elektrochemische Studien. Die elektrische Leitfahigkeit der Basen.
T=25^ Hg. U.
1864. W. Ostwald. Jour. Prakt. Chem. (2), 35, 112-121, (1887).
Studien zur chemischen Dynamik. Ueber die Affinitatsgrdssen der Basen.
T=25^
1866. W. Ostwald. Zeit. Phys. Chem. 1, 61-«2, (1887).
Ueber die Natur der chemischen Verwandschaf t.
T=25^
AUTHOR LIST 489
1866. W. Ostwald. Zeit. Phys. Chem. 1, 74-86, (1887).
Elektrochemische Studien. Ueber das Gesets von F. Kohlrausch.
T=26^ Hg. U.
1867. W. Ostwald. Zeit. Phys. Chem. 1, 97-109, (1887).
Elektrochemische Studien. Ueber das Gesets von F. Kohlrausch.
T-26^ Hg. U.
1868. W. Ostwald. Zeit. Phys. Chem. 2, 270-283, (1888).
Ueber die Dissodationstheorie der Elektrol3rte.
T-26^ Hg. U. xaq.-1.8-2.0XlO-^
1868a. W. Ostwald. Zeit. Phys. Chem. 2, 840-851, (1888).
Elektrochemische Studien.
T-25^ Hg. U. X aq.- 1.^2.0 XlO-« sub.
1869. W. Ostwald. Zeit. Phys. Chem. 2, 901-904, (1888).
Ueber die Bestimmung der Basicit&t der S&uren aus der dektrischen Leit-
f&higkeit ihrer NatriumsaLEe.
T=26°. Hg. U.
1870. W. Ostwald. Zeit. Phys. Chem. 3, 170-197, (1889).
Ueber die Affinit&tsgrGssen organischer S&uren und ihre Beziehungen zur
Zusammensetzung und Konstitution derselben. [Given in 1877.]
T=25^ Hg. U.
1871. W. Ostwald. Zeit. Phys. Chem. 3, 241-288, (1889). %MeM, P.
Ueber die Affinit&tsgrOssen organischer S&uren und ihre Beziehungen zur
Zusammensetzung und Konstitution derselben. [Given in 1877.]
T=25^ Hg. U.
1872. W. Ostwald. Zeit. Phys. Chem. 3, 369-122, (1889).
Ueber die Affinit&tsgrOssen organischer Sfiuren und ihre Beziehungen zur
Zusanmiensetzung und Konstitution derselben. [Given in 1877.]
T=25^ Hg. U.
1878. W. Ostwald. Zeit. Phys. Chem. 5, 268, (1890). Mea«. Boder,
Ueber die Isozimmtsaure, eine in den Nebenalkaloiden des Cocalns vorkom-
mende Saure. [This is a review of 1108 and the measurement by Bader is the
same as in 1108.]
1874. W. Ostwald. Zeit. Phys. Chem. 8, 427-428, (1891). ilfea«. Ber^ch.
[The value of k, without a table of A, is given in a review of 166.]
1876. (W. Ostwald. Zeit. Phys. Chem. 9, 553-^562, (1892).
Ueber mehrbasische S&uren.) [Same as 1878. Quoted.]
1876. W. Ostwald. Zeit. Phys. Chem. 11, 521-528, (1893).
Die Dissociation des Wassers.
1877. W. Ostwald. Abhand. Kdn. S&chs. Ges. Wis. 15, 95-241, (1889).
%Meai, P. Walden,
Ueber die Affinit&tsgrOssen organischer S&uren und ihre Beziehungen zm*
Zusammensetzung und Constitution derselben. [Same as 1870, 1871 and
1872, together.]
1878. (W. Ostwald. Ber. Verhand. S&chs. Ges. Wis. 43, 228-238, (1891).
Ueber mdirbasische S&uren.) [Same as 1876.]
[It is probable that the following measurements, stated to have been made
by Ostwald, were in many cases made by students in his laboratory and are
published elsewhere. ]
itfseur. W. Ostwald; see 68, 72, 419, 727, 1102, 1108, 1106, 1648.
A. Oswald see K. Auwers.
490 AUTHOR LIST,
1879. K. Ott Dis. Mtknchen. (1906).
Ueber Sulfide und Sulfine.
ISaO. J. D. Otten. Dis. Mtknchen. (1887).
Die dectrische Leitungsf fthigkeit der Fetts&uren und ihre AbhAngigkeit von
der Temperatur. [Abstracted in Beibl. Ann. Physik. 12, 25»-260, (1888).
Original not examined by me. ]
Metu. Ottiker; see 471, 478.
Ottiker see P. Dutoit
G. S. Owen see A. FindUy, W. S. S. Tomer.
P.
V. Pachkoff see P. Ghroostelioff.
1861. M. Padoa, B. Savaxi. Gas. Chim. Ital. 36, 1, 313-321, (1906).
Sulla natura del ioduro d'amido. [Same as 1888.]
T-18^
1888. M. Padoa, B. Savaxi. Rend. Accad. Linoei (5), 14, I, 467-476,
(1906).
SuUa natura del ioduro d'amido. [Same as 1881.]
H. H. Paine see W. C. D. Whetham.
F. C. Palazzo see A. Peratoner.
Meca. S. Palitzsch; see 1689b.
1888. W. Palmaer. Zeit. Phys. Chem. 22, 492-504, (1897).
Ueber das Verhfiltnis swischen Inyendonsgeschwindigkeit und Konzentration
der Waaserstoffionen.
T=20*.
ilfecM. C. S. Palmer; see 1697.
G. Papasogli see A. BartolL
1884. N. PairaYano, A. Pasta. Gas. Chim. Ital. 37, 11, 252-264, (1907).
Sopra alcimi bicromati di metalli bivalenti con le basi organiche.
1886. N. Parravano, G. TommasL Gas. Chim. Ital. 39, II, 60-^64,
(1909).
I sali dell'acido feniltioglicolico.
^ 1886. C. L. Parsons. Jour. Phys. Chem. 11, 659-680, (1907).
Solution in a dissolved solid.
T»25^ R. O.
1886a. J. R. Partington. Jour. Chem. Soc. 97, 1158-1170, (1910).
Ionic equilibrium in solutions of electrolytes.
F. Paschke see S. Wedekind.
1886b. Paschkow. Dis. Charkow. (1892). [Original not examined by me. ]
Quoted in 1848.
1887. W. P. Paschkow. Congr. russ. Naturf. Aerz. Abstracted in Chem.
Ztg., 14, 1, 126, (1890).
Ueber die electrische Leitungsffthigkeit einiger organischer S&uren und deren
Salze mit Alkalimetallen.
V. Pashkoff see V. Pachkoff.
Paikov see Pachkoff.
A. Pasta see N. Parravano.
W. A. Patrick see E. H. Archibald.
1888. H. S. Patten. Jour. Phys. Chem. 6, 554-600, (1902).
Influence of the solvent in electrolytic conduction.
T=25^ R. O. xaq.=4XlO-«.
AUTHOR LIST 491
1889. H. £. Patten, W. R. Mott Jour. Phys. Chem. 12, 49-74, (1908).
Decomposition curves of lithium chloride in pyridine and in acetone — the
effect of water.
1890. M. Paul. Dis. Nancy. (1906).
Contribution k T^tude de la dissociation ^lectrolytique en milieu hydroaloo-
olique. [This gives data and tables of A for 1897.]
T =25** and 36°. R. O. Xu aq. = 1 X 10-«.
M. Paul see P. T. Muller.
1891. T. PauL Arch. Pharm. 239, 48-90, (1901).
Untersuchungen tiber Theobromin und Koffein und ihre Salzbildung. [Co>
rected in Zeit. Phys. Chem. 36, 749, foot-note. (1901).]
T«18** and 25^ R. O. x aq.^1.0 and l.lXl0-«; sub.
Mea8. T. Paul; see 60, 68, 68, 69, 1104, 1212, 1898, 1670, 1672.
T. Paul see W. His.
1891a. T. Paul, A. Giinther. Arbeit, k. Gesundh. 29, 218-271, (1908).
%Meas, P, Mauz.
Untersuchungen tlber den S&uregrad des Weines auf Grand der neueren The-
orien der Losungen.
T = 76^
1892. T. Paul, B. Kr6nig. Zeit. Phys. Chem. 21, 414^50, (1896).
Ueber das Verhalten der Bakterien zu chemischen Reagentien. [Qualitative. ]
1898. W. Pauli. Beitr. Chem. Physiol. Pathol. 7, 531-547, (1905-1906).
Untersuchungen tiber physikalische Zustandsanderungen der KoUoide. Ftinf te
Mitteilung. Die elektrische Ladung von Eiweiss.
1894. W. PauU. Beitr. Chem. Physiol. Pathol. 10, 63-79, (1907).
Untersuchungen uber phjrsikahsche Zustandsanderungen der Kolloide.
Sechste Mitteilung. Die Hitzekoagulation von S&ureeiweiss.
1896. W. Pauli. Naturwis. Rundsch. 21, 3-5, (1906).
Ueber die elektrische Ladung von Eiweiss und ihre Bedeutung.
1896. W. PauU. Naturwis. Rundsch. 21, 17-20, (1906).
Ueber die elektrische Ladung von Eiweiss und ihre Bedeutung.
1897. W. PauU, H. Handovsky. Biochem. Zeit. 18, 340-371, (1909).
Untersuchungen tiber physikalische Zustands&nderungen der Kolloide. VIII.
Mitteilung. Studien am S&ureeiweiss.
♦1897a. H. Pauly, J. Weir. Ber. Deutsch. Chem. Ges. 43, 661-670, (1910).
Ueber die einseitige Esterbildung der Benzoyl-asparagins&ure.
T=25^
*1897b. W. PauU, H. Handovsky. Biochem. Zeit. 24, 239-262, (1910).
Untersuchungen tiber physikalische Zustands&nderungen der Kolloide. IX.
Mitteilung. Studien am AlkaUeiweiss.
T=25^
n897c. H. Pauly, K. Schiibel, K. Lockemann. Ann. Chemie. 383, 288-^7,
(1911).
Ueber die ReaktionsfShigkeit der Phenolgrappen in den Phenolaldehyden.
T=25^ R. O. X2iaq.=8.7Xl(>-^
J. N. Pearce see H. C. Jones.
1898. H. ▼. Pechmann. Ber. Deutsch. Chem. Ges. 33, 3323^3341, (1900).
Meaa, T. Paul.
Ueber Dicrotons&ure.
1899. H. ▼. Pechmann, F. Neger. Ann. Chemie. 273, 186-214, (1893).
Ueber die Einwirkung von Essigs&ureanhydrid auf Acetondicarbons&ure.
Pelet see Pelet- JoUvet
* Theee aie out of order on account of late insertion.
492 AUTHOR LIST
1400. L. Pelet-JoUvet Bui. Soc. Vaudoise. (5), 45, 7S-152, (1909).
Ctudes thtoriques sur les ph^nom^nee de teinture. [Same as 1408 and 1404,
except that no measurement is given for Congo Red. ]
T=25^ R. O.
1401. L. Pelet, V. Garuti. Bui. Soc. Vaudoise. (5), 43, 1-29, (1907). Meaa.
E. FrancdUm,
Dosage volum^trique des mati^res colorantes. Dosage des mati^res colorantes
basiques au moyen des matidres colorantes acides.
1408. L. Pelet-JoUvet, A. Wild. Bui. Soc. Chim. (4), 3, 1087-1094, (1908).
Eltudes des mati^res colorantes en solution. [Same as 1404. Same as 1400,
except that measurement of Congo Red is given here. Summary with some
data is given in 1403.]
T=25^ R. O.
1403. L. Pelet-JoUvet, A. Wild. Compt. Rend. 147, 683-^85, (1908).
Cltat de mati^res colorantes en solution. [Given in 1400, 1408 and 1404.]
T=25^ R. O.
1404. L. Pelet-JoUvet, A. Wild. Zeit. Chem. Ind. KoUoid, 3, 174-177,
(1908).
Untersuchungen Uber die Farbstoffe in Ldsung. [Same as 1408. See 1400
and 1403.]
T=25^ R. O.
1406. (H. PeUat Compt. Rend. 144, 902-904, (1907).
Determination directe de la valeur absolue de la charge dlectrique d'un ion
eiectrolytique monovalent. — Diamdtre d'un atome.)
1406. (H. PeUat. Jour. Phys. (4), 7, 195-203, (1908).
Sur la th^rie de M. Nemst concemant la difference de potentiel entre elec-
trode et electrolyte.)
1407. A. Peratoner, F. C. Palazzo. Gaz. Chim. Ital. 36, 1, 7-13, (1906).
SuUa costituzione dell'acido comenico. [Same as 1406 and 1409.]
1406. A. Peratoner, F. C. Palazzo. Giom. Sci. Nat. Econ. 25, 245-251,
(1905).
Sulla costituzione deU'acido comenico. [Same as 1407 and 1409.]
1409. A. Peratoner, F. C. Palazzo. Rend. Soc. Chim. Roma, 1, 40-41,
(1903).
Sulla costituzione dell'acido comenico. [Same as 1407 and 1403.]
1410. W. H. Perkin, Jr. Jour. Chem. Soc. 65, 572-591, (1894). Meas, J.
Walker,
The cis- and trans- modifications of l;2-tetramethyienedicarboxyIic acid, and
l;2-pentamethylenedicarboxyUc acid.
1411. W. H. Perkin, Jr. Jour. Chem. Soc. 69, 1457-1506, (1896). Meas.
T, Ewan, and J. Walker,
Some derivatives of propionic acid, of acryUc acid, and of glutaric acid.
W. H. Perkin, Jr. see W. A. Bone.
" " " " see A. W. Crossley.
1418. W. H. Perkin, Jr., B. Prentice. Jour. Chem. Soc. 59, 818-852, (1891).
Meas. J. Walker.
Synthesis of homologues of pentanetetracarboxyUc acid luad of pimelie
acid.
1418. W. H. Perkin, Jr., J. L. Simonsen. Jour. Chem. Soc 91, 840-848,
(1907).
The action of tribromopropane on the sodium derivative of ethyl malonate.
Part II. Formation of A^ heptadi-inene-d-carboxylic acid (^m-toluic
acid), (CHiC.CHj), C(CO>H)j.
AUTHOR LIST 498
1414. W. H. PerUn, Jr., W. Sinclair. Jour. Ch&n, Soc. 61, 36-66, (1892).
Meas. J. Walker.
The synthetical formation of closed carbon chains. Part II. Derivatives of
tetramethylene.
1416. E. Petersen. Zdt. Phys. Chem. 22, 410-423, (1897).
Ueber die Anzahl der lonen in einigen Kobalt-AmmoniaJEverbindungen.
T=0**and25^ X25 aq.= 2.7X10-*; sub.
1416. E. Petersen. Kong. Danske Vids. Selsk. Skrift. (6), 7, 303-336,
(1890-1894).
Om den elektrolytiske Dissociationsvarme af nogle Syrer.
T-21.5^
Meaa. E. Petersen; see 886.
1417. (J. Petersen. Zeit. Phys. Chem. 10, 580-592, (1892).
Einige Versuche, die physischen Verh<nisse der Metallammoniakverbin-
dungen betrefifend.)
T = 18^
A. Pezzolato see R. Nasini.
1418. A. Pfaff. Dis. Heidelberg. (1897). [In autobiography gives the
name as A. E. Pfaff.]
Ueber die elektrische Leitfahigkeit organischer S&uren.
T=25^
Mea8. A. Pfaff; see 61, 64, 826.
1419. E. Pfetffer. Ann. Physik. (3), 25, 232-245, (1885).
Ueber die electrische Leitungsfahigkeit der Mischungen von Wasser und
Alkohol.
T =0' to 16'.
14a0. E. Pfeiffer. Ann. Physik. (3), 26, 31^14, (1885).
Ueber die electrische Leitungsf fihigkeit des absoluten Alkohols.
T=RoomTand30^
1421. B. W. R. Pfetffer. Ann. Physik. (3), 26, 226-239, (1885).
Ueber die electrische Leitungsf&higkeit der Mischungen von Aethylalkohol
mit Aethyl&ther.
Hg. U. T«15*and30'.
Meaa. Pfenning; see 186a.
Meas. A« Pflster; see 1647.
A. Pflster see F. Fichter.
Meaa, A. Pheophilaktowa; see 1670.
1422. J. C. PhiUp. Jour. Chem. Soc. 93, 925-927, (1908).
The dissociation constants of triazoacetic and ortriazopropionic acids.
Ts25^ xs6 aq.»2X10~*; sub. only for sodium salts, [k, but not A
given in 1423. ]
1428. J. C. PhiUp. Proc. Chem. Soc. 24, 114-115, (1908).
The dissociation constants of, etc. [Same as 1422 for k. ]
142Sa. J. C. Philip, H. R. Coiirtman. Jour. Chem. Soc. 97, 1261-1271,
(1910).
Behaviour of two salts with a common ion, when dissolved in an organic sol-
vent. [A qualitative statement is given in 1428b.]
T »25*'. X of solvent is sub.
1428b. J. C. Philip, H. R. Courtman. Proc. Chem. Soc. 26, 140, (1910).
Behaviour of two salts, etc. [Qualitative. Given in 1428a with full
data.T
1424. (A. Picdni. Zeit. Anorg. Chem. 8, 115-120, (1895).
Ueber die Ldsungen des grUnen Chromchlorids CrCla.6HsO.) [Inorganic]
494 AUTHOR LIST
1426. N. Picton. Dis. Leipzig. (1908).
Ueber Umlagerungen aromatischer Nitrok5rper.
N. Ptcton see A. Hantzsch.
1426. (B. PieBch. PhU. Mag. (5), 38, 336, (1894).
Alterations of the electrical resistance of aqueous solutions and of galvanic
polarisation with pressure.) [An abstract of 1427 without data.]
1427. B. PieBch. Sitsber. Akad. Wien. 103, 2a, 784-808, (1894).
Aenderungen des elektrischen Widerstandes wfisseriger Ldsungen und der
galvanischen Polarisation mit dem Drucke. [See 1426.]
T«RoomT. S. U.
1428. S. Pilat Dis. Leipzig. (1905).
Intramoleculare Ver&nderungen der Cyanursfiure und ihrer Salze.
T«25*'to96.2^
Meas. S. Pllat; see 788.
1429. W. Pip. Dis. Heidelberg. (1898).
I. Ueber die elektrische Leitf&higkeit einiger aromatischer S&uren. II. Ueber
die FarbstofFbildung aus Diazobenzolsulfosaure und salzs&urem Mono&thyl-
p-toluidin.
T=25*. xaq.= 2.6X10-*; [probably sub. ]
Pisarzeyskij see Pissarjewsky.
1430. (L. Pissarjewsky, E. Karp. Jour. Russ. Phys.-chem. Soc. 40, 564-
565, (1908).
Relations between the constant of diffusion, the internal friction and electrical
conductivity.) [Summary of 1481 without data.]
1481. (L. Pissarjewsky, B. Karp. Jour. Russ. Phy8.-chem. Soc. 40, 599-
611, (1908).
Relations between the constant of diffusion, the internal friction and electrical
conductivity.) [Same as 1432. See 1430.]
1432. (L. Pissarjewsky, B. Karp. Zeit. Phys. Chem. 63, 257-268, (1908).
Die Beziehung zwischen der Diffusionskonstante, der innem Reibung und
dem elektrischen Leitvermdgen.) [Same as 1481. Inorganic]
1433. L. Pissarjewsky, N. Lemcke. Jour. Russ. Phys.-chem. Soc. 37, 492-
502, (1905).
Electrical conductivity and internal friction. [Same as 1434.]
T=25''.
1434. L. Pissarjewsky, N. Lemcke. Zeit. Phys. Chem. 52, 479-493, (1905).
Der Einfluss des Ldsungsmittels auf die Gleichgewichtskonstante und die
Beziehung zwischen dem elektrischen Leitvermogen und der innem Reibung.
[Same as 1433. ]
T=25^
1434a. L. Pissarjewsky, A. Sapovalenko. Jour. Russ. Phys.-chem. Soc. 42,
905-938, (1910).
The electrical conductivity of KBt and KAg(CN)2 in mixtures of glycerol
with alcohols.
T=25**and45^
R. PizzigheUi see A. MioUti; 1269.
Piotnikov see Plotnikow.
1436. W. A. motnikow. Ber. Deutsch. Chem. Gee. 39, 1794-1804, (1906).
Ueber die Verbindungen von Dimethylp3rron mit Trichloressigs&ure.
Elektrisches Leitvermdgen der Ldsungen in Aethylbromid, Chloroform und
Benzol. [Tables of A and conclusions same as in 1439 and 1440 together,
except that potassium trichloroacetate in ethyl bromide is not given
here.]
T = 18*. R.O.
AUTHOR LIST 496
1486. W. A. PlotiiikctW. Ber. Deutsch. Chem. Ges. 42, 1154-1158, (1908).
Ueber die Verfoindungen von Dimjethyl-p3rron mit Tiibrom-esBigs&ure. [Same
88 1442.]
T-18^
1487. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soo. 34, 4d&-472, (1902).
The electrical conductivity of solutions in ethyl bromide.
T = 18^
1488. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 35, 794r-810, (1903).
The electrical conductivity of bromine solutions. [Same as 1446.]
T = 18^
1489. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 37, 318-337, (1905).
Investigation of the electrical conductivity of non-aqueous solutions. IV.
The electrical conductivity of solutions in ethyl bromide. On compounds of
dimethylp3rrone with acids. [Tables of A and conclusions are given in I486. ]
1440. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 37, 875-^1, (1905).
Investigation of the electrical conductivity of non-aqueous solutions. V. The
electrical conductivity of solutions of compounds of dimethylpyrone and tri-
chloroacetic acid in chloroform and l>enzene. [Tables of A are given in
I486.]
1441. W. A. Piotnikow. Jour. Russ. Phys.-chem. Soc. 38, 1096-1104,
(1906).
Investigation of the electrical conductivity of non-aqueous solutions. VI.
Bromine and ether. [Same as 1447. ]
T=18*and0^
1442. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1238-1243,
(1908).
The electrical conductivity of solutions of tribromoacetic acid dimethyl pyro-
nates in ethyl bromide. [Same as I486.]
T-18^
1448. (W. A. Piotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1243-1247,
(1908).
Anomalies of the direction of curves which express the change in molecular
electrical conductivity in connection with the concentration.) [Theoretical
and quoted. ]
1444. (W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 40, 1247-1257,
(1908).
The decomposition of complex ions.)
1444a. W. A. Plotnikow. Jour. Russ. Phys.-chem. Soc. 42, 1589-1596,
(1910).
The electrical conductivity of non-aqueous solutions. VIII. Aluminum brom-
ide and nitrobenxol.
T=25^
1446. W. A. Plotnikow. Zeit. Anorg. Chem. 56, 53-57, (1907).
Ueber die Verbindung von Aluminiumbromid mit Aether.
1446. W. A. Plotnikow. Zeit. Phys. Chem. 48, 220-236, (1904).
Das elektrische Leitvermdgen der Ldsungen in Brom. [Same as 1488. ]
T = 18® R O
1447. W. A. Plotaikow. Zeit. Phys. Chem. 57, 502-506, (1906).
Die elektrische Leitf&higkeit der Gemische von Brom und Aether. [Same as
1441.]
W. A. Plotnikow see V. V. Neminskij.
1447a. G. Polara. Atti Accad. Gioenia. (5), 3, Mem. 6, (1901).
Sulla conducibilitd. elettrica della saliva mista dell'uomo.
T = 18^
496 AUTHOR LIST
1448. C. Pomenmz. Monatah. 18, 575-^1, (1897).
Zur Kenntmss dee Pinacolins. |Same as 1449. ]
1449. C. Pomenmz. Sitsber. Akad. Wien. 106, 2b, 679-^585, (1897).
Zur Kemitnias des Pinaoolins. [Same as 1443.]
1450. K. T. PospischOl. Ber. Deutsch. Chem. Gee. 31, 1950-1957, (1898).
Ueber die beiden stereoisomeren l,3-Peiitamethendicarboiis&uren. [Same as
1461.]
1461. K. T. Pospischm. Die. Leipsig. (1896).
Ueber die beiden stereoisomeren, etc. [Same as 1460.]
Meas, A. Postinkor; see 1760iu
1462. A. Praetorius. Monatsh. 28, 767-802, (1907).
Ueber die alkoholische Verseifung der BenaolsulfoB&ureesta*. [Same as
1463.]
T-60^ R. O.
1463. A. Praetorius. Sitsber. Akad. Wien. 116, 2b, 669-704, (1907).
Ueber die alkoholische Verseifung der Benrolsulfos&ureester. [Same as 1468. ]
Meas, W. Praetorius; see 746, 762, 782.
B. Prentice see W. H. Perldn, Jr.
H. Probst see F. Fichter.
1464. D. Protopopov, S. Reformttsky. Jour. Ru^. Phys.-chem. Soc. 33,
242-246, (1901).
Synthesis and properties of Orisopropyl-jS-isobutylethylenelactic add.
1466. (P. F. S. ProvenzalL Atti Pont. Accad. Nuov. Uncei. 43, 58,
(1890).
Presentazione di una memoria manoscritta sulle relazioni fra le proprietA
ottiche dei oorpi, e la loro faooltd. oonduttrioe per I'elettrioo.) [Summary of
1466.]
1466. (P. F. S. Provenzali. Mem. Pont. Accad. Nuov. Lincei. 6, 7-23,
(1890).
Sulle relazioni fra le propriety ottiche dei oorpi.) [Inorganic]
1467. (M. Prud*homme. Bui. Soc. Chim. (4), 1, 562-569, (1907).
Relations entre la conductibiUt^ mol^ulaire des Electrolytes et la dilution.)
[Same as 1468 and 1460. Quoted. ]
1468. (M. Prud*homme. Jour. Chim. Phys. 5, 386-397, (1907).
Relations entre la conductibilitE, etc.) [Same as 1467 and 1460.]
1469. (M. Prud'homme. Jour. Chim. Phys. 5, 497-510, (1907).
Sur les demi-61ectrolytes.) [Quoted.]
1460. (M. Prud'homme. Zeit. Elektrochem. 13, 471-474, (1907).
Beziehungen zwischen der molekularen Leitfahigkeit von Mektrolyten und
der Verdthmung.) [Same as 1467 and 1468.]
1461. L. Prussia. Gaz. Chim. Ital. 28, II, 113-122, (1898).
Ricerche sul cianuro di mercurio. [Qualitative. ]
Q.
1462. 6. Quagliariello. Rend. Accad. Lincei. (5), 18, II, 217-222, (1909).
Modificazioni delle proprietii chimico-fisiche del siero di sangue nscaldato a
55^-60^ C.
T=37^
1462a. P. Quinet Compt. Rend. 147, 203-206, (1908).
Formation de composes dans les solutions d'acide tartrique et de molybdate
de sonde. [Given in 1463. ]
T=20.5**0.5^
AUTHOR LIST 497
1463. P. QQinet Jour. Phys. (4), 8, 278-290, (1909).
Formation de composes dans les solutions d'adde tartrique et de molybdates.
[1462a gives only sodium molybdate.]
T=20.5**0.5^
R.
1464. A. V. Raalte. Rec. Trav. Chim. 18, 378-107, (1899).
Sur le phenyl- et le parachlorph^nyl- nitrom^thane.
T=l.l^to25.2^
1464a. P. Rabe. Ber. Deutsch. Chem. Ges. 43, 2964-2971, (1910). Meas.
C, Roy,
Ueber Mutarotation und elektrische Leitffthigkeit bei Zuckern. I. Mitteilung;
Ueber den Traubenzucker.
T - 20^ X aq. = 2.07 X 10^; not sub.
R. Radenkauaen see T. Curttus.
1466. L. Ramberg. Ber. Deutsch. Chem. Ges. 40, 258^2589, (1907).
Notiz ilber die Aethyl-thioglykolsaure.
T=25^ R. O. X aq.=2XlO-«; not sub.
1466. L. Ramberg. Zeit. Anorg. Chem. 50, 439-445, (1906).
Ueber die Platosaise einiger schwefelhaltigen organischen S&uren. [Qualitar
tive. ]
1467. L. Ramberg. Zeit. Phys. Chem. 34, 561-592, (1900).
Ueber die Einwirkung y6n Brom auf Phenylsulfonessigs&ure imd o^Phenylsul-
fonpropions&ure in w&sseriger Losung, ein Beitrag zur chemischen Kinetik.
1468. C. Ranken, W. W. Taylor. Proc. R. Soc. Edinburgh. 27, 172-180,
(1906-1907).
The physical properties of mixed solutions of independent optically-active
substances.
T = 15'and25^ R. O.
1469. (F. M. Raoult Compt. Rend. 107, 442-445, (1888).
Sur les tensions de vapeur des dissolutions faites dans I'aloool.)
1470. H. Rappeport Dis. Lausanne. (1907).
Conductibilitds limites dans quelques dissolvants organiques. [Most is given
in 491.]
T = 18^ s. u.
H. Rappeport see P. Dutoit
1471. B. Rasdi, F. W. Hinrichsen. Zeit. Elektrochem. 14, 41-46, (1908).
Mea8. KoUer.
Ueber eine Beziehung zwischen elektrischer Leitf&higkeit imd Temperatur.
T=.297**to408°.
1471a. A. Rassenfosse. Bui. Acad. Belg. (1909), 995-1007.
Contribution k T^tude des ph^nomdnes de conductibilit6 ^ectrolytique des
solutions fluorescentes.
1472. F. Ratz. Zeit. Phys. Chem. 19, 94-112, (1896).
Ueber die Dielektrizitatskonstante von FlUssigkeiten in ihrer Abhfingigkeit
von Temperatur imd Druck.
T=0^to60^
Reformatskij see Refonnatsky.
1478. S. Refonnatsky. Ber. Deutsch. Chem. Ges. 28, 3262-3265, (1895).
Neue Darstellungsmethode der a,a-Dimethylglutar8&ure aus der entsprechen-
den Oxys&mre. [Same as 1474, but does not state that Szyszkowski made the
measurement. ]
T=25^
498 AUTHOR LIST
1474. S. Refomuitsky. Jour. Rubb. PhyB.-chem. Soe. 28, 140-158, (1896).
Meas, Sgystkatoski,
New method of obtaining a,a-dimethylglutarie acid from the ooiresponding
oxyacid. [Same as 1478.]
T=25^
1476. S. RefomiAtsky. Jour. Rubb. PhyB.-chem. Soe. 30, 453-466, (1898).
AfetM. J, I, Michajlenko,
Preparation and properties of a,a-dimethy]-/^xyglutaric add.
8. Refonnatsky see D. Protopopov.
'' " see B. SzyazkowskL
1476. K. Regner. Phys. Zeit. 4, 862^865, (1902-1903).
Ueber die Frage der Widerstandsfinderung von w&Bsetigen Salslteungen durch
Bestrahlung.
1477. M. Reich. Dis. Berlin. (1900).
Ueber elektrische Leitung reiner Substansen.
T-13•to22^
L. T. Reicher see J. H. Tint Hoff.
1478. B. Reicheit Zeit. Analyt. Chem. 28, 1-25, (1889).
Anwendung des elektrolytischen Leitungsvennogens su quantitatiyen Bestim-
mungen.
T -18^*0.1''. S. U.
1479. B. B. Reid. Am. Chem. Jour. 41, 483^10, (1909).
The aicoholysis or esterification of acid amides.
1480. A. W. Reinold. Nature. 48, 624-626, (1893).
The thicknesB and electrical conductivity of thin liquid films.
T = 17•to27^
1481. F. Reitzenstein. Zeit. Anorg. Chem. 11, 254-263, (1896).
Ueber etnige Metallsalie mit organischen Basen.
T « 18^
1488. F. Reitzenstetn. Zeit. Anorg. Chem. 18, 253-304, (1898).
Anmioniak-Pyridinsalie und Hydrate bivalenter Metalle.
T«0^
F. Reizenstein. Zeit. Anorg. Chem. 11, 254, should be ReHxenstein.
1488. (A. Reychler. Jour. Chim. ¥hys, 7, 58-«7, (1909).
Sur r^uilibre de dissociation des ^ectrolytes btnaires.)
1484. (J. W. Richards, W. 8. Landis. Trans. Am. Electrochem. Soe. 16,
85-91, (1909).
The practical conductance of dectiolytes.) (Inorganic]
O. W. Rkhardsoa see H. O. Jones.
I486. B. Rieger. Zeit. Eld&tiochem. 7, 871-^6, (1900-1901).
Ueber die Konstitution halbkomplezo' Sake nach ifarer d^trdytiscfaen
UeberfOhrung. [Same as I486.]
1486. B. Rieger. Dis. Brcslau. (1901).
Ueber die Ezistens komplexer lonoi in Doppdsalaen anf Gnmd von Ueber-
fuhrungsbestimmungen. [Same as I486.]
1487. B. H. Riesenfeld. Ber. Deutsch. Chem. Ges. 41, 3536-3552, (1906).
Meas. A. Wesck.
Habere Ox3rdationsprodukte des Chroms. 4. Mitteihmg. Ueber Chiomte-
trozyd- Verbindungen. [Same as 19B.]
T-18*. R.O. jraq.-l.8XlO-* and 5.8X10-*.
1488. B. H. Riesenfeld. Zeit. Phys. Chem. 41, 34^-^52, (1902).
Ueber den Molekulanustand von Jodkalium in Phe&oL
T=25•and43^
AUTHOR LIST 499
1489. (A. RighL Jour. Phys. (4), 7, 589-617, (1908).
Sur quelques ph^nom^es dus aux rencontres entre Electrons, ions, atomeS et
mol^ules.) [Gases; and theoretical.]
1490. A. Righi. Nuoyo Cim. (5), 10, 113-122, (1905).
Sulla diminuzione di resistenza prodotta nei cattivi conduttori dai raggi del
radio. [Same as 1491. Qualitative.]
1491. A. Rigfai. Rend. Accad. Lincei. (5), 14, II, 207-214, (1905).
Sulla diminuzione di resistenza, etc. [Same as 1490.]
1492. E. Rimbach. Zeit. Phys. Chem. 16, 671-676, (1895).
Dissociation und optische Drehung aktiver Salzl5sungen.
T=20^
1498. E. Rimbach, E. Heiten. Ann. Chemie. 359, 317-^35, (1908).
Ueber Eigenschaften, inbesondere das Drehungsvermogen des Sskccharins und
der Alkalisaocharinate. [Same as 797. ]
T=25^ R. O. xaq. sub.
1494. E. Rimbach, F. Korten. Zeit. Anorg. Chem. 52, 406-415, (1907).
Ueber einige Verbindungen dss Iridiums.
T=25^
1496. E. Rimbach, C. Neizert Zeit. Anorg. Chem. 52, 397-405, (1907).
Zur Komplexbildung in Molybdans&ureldsungen.
T=25^ R. O. xaq. sub.
1496. E. Rimbach, A. Schubert. Zeit. Phys. Chem. 67, 183-200, (1909).
Loalichkeit einiger schwerldslicher Salze seltener Erdmetalle. [Same com-
pounds with additional measurements given in 1600. ]
T = 19**to27^ R. O. X aq. = 1X10-^ or less; measurements given =fc xaq.
1497. E. Rimbach, O. Weber. Zeit. Phys. Chem. 51, 473-493, (1905).
Ueber Einwirkung anorganischer Substanzen auf die Drehung von L&vulose
und Glukose.
[T probably 20**.] R. O. x aq. not over 2X10"*; sub.
E. Rimini see A. Angeli.
A. Rinckenberger see A. Hantzsch.
1498. W. E. Ringer. Zeit. Physiol. Chem. 60, 341-363, (1909).
Zur Additat des Hams.
T = 18*.
1499. P. Rivals. Ann. Chim. Phys. (7), 12, 501-674, (1897).
Recherches thermochimiques sur quelques composes chlords des series ac^
tique, benzoique et salicylique. [Same as 1600.]
T = 16^ S. U.
1600. P. Rivals. Compt. Rend. 125, 574r-576, (1897).
Sur la oonductibilit4 ^lectrolytique de Tacide trichlorac^tique. [Same as 1499. ]
A. C. D. Rivett see N. V. Sidgwick.
1600a. A. C. D. Rivett, N. V. Sidgwick. Jour. Chem. Soc. 97, 732-741,
(1910).
The rate of hydration of acetic anhydride.
T=25°. R. O. xaq.=0.6-1.5XlO-«.
1600b. A. C. D. Rivett, N. V. Sidgwick. Jour. Chem. Soc. 97, 1677-1686,
(1910).
The rate of hydration of acid anhydrides; succinic, methylsuccinic, itaconic,
maleic, citraconic, and phthalic. [k, but no cond. is given in 1500c. ]
T=25°.
1500c. A. C. D. Rivett, N. V. Sidgwick. Proc. Chem. Soc. 26, 200, (1910).
The rate of hydration, etc. [Only k is given here. Tables of cond. are given
in 1600b.]
D. J. Roberts see J. J.* Sudborough.
600 AUTHOR LIST
1501. T. B. Robertaon. Jour. Biol. Chem. 2, 317-383, (1906-1907).
Studies in the chemistiy of the ion-proteid compounds. IV. On some chem-
ical properties of casein and their possible relation to the chemical behavior
of other protein bodies, with especial reference to hydrolysis of casein by
ti3rp6Ui«
1601a. T. B. Robertwm. Jour. Biol. Chem. 7, 351-357, (1909-1910).
Concerning the relative magnitude of the parts played by the proteins and
by the bi-carfoonates in the maintenance of the neutrality of the blood.
T-34^
1002. (T. B. Robertwm. Jour. Phys. Chem. 10, 524-^582, (1906).
On the conditions of equilibrium of an associating amphoteric electrolyte in
the presence of any number of non-amphoteric dectrolytes.) [Theoretical.
Gives also a bibliography of the dissociation of proteins.]
1808. T. B. Robertwm. Jour. Phys. Chem. 11, 437-459, (1907).
On the dissociation of serum globulin at varying hydrogen ion concentrations.
T usually 20*. R. O. x aq.- 7.3X10-*; sub.
1504. T. B. Robertson. Jour. Phys. Chem. 11, 542-552, (1907).
On the dissociation of solutions of the neutral caseinates of sodium and am-
monium.
T=25*. R. O. xaq.«8XlO-«; sub.
1506. T. B. Robertson. Jour. Phys. Chem. 12, 473^183, (1908).
On the dissociation of solutions of the " basic " caseinates of sodium and am-
moniimi.
1606. T. B. Robertson. Jour. Phys. Chem. 13, 469-489, (1909).
On the refractive indices of solutions of the caseinates and the add- and
alkali-equivalents of casein.
1506a. T. B. Robertson. Jour. Phys. Chem. 14, 528-568, (1910).
Studies in the electrochemistry of the proteins. I. The dissociation of po-
tassium caseinate in solutions of varying alkalinity.
T=30^ R. O. X aq. not over 8X10"«; not sub.
1606b. T. B. Robertson. Jour. Phys. Chem. 14, 601-611, (1910).
Studies in the electrochemistry of the proteins. II. The di£BOciation of solu-
tions of the " basic " caseinates of the alkaline earths.
T«30^ R. O. xaq.= 4.5X10-*; sub.
1606c. T. B. Robertson. Jour. Phys. Chem. 14, 709-718, (1910).
Studies in the electrochemistry of the proteins. III. The dissociation of the
salts of ovo-mucoid in solutions of varying alkalinity and acidity.
;^=20^ r. o.
R. Robison see A. Hantzsch.
L. R5der see H. Goldschmidt
1606d. H. RShler. Zeit. Elektrochem. 16, 419-436, (1910).
Untersuchungen iiber Formamid als Lteungsmittel fUr anorganische Salze
und iiber die Elektrolyse dieser LOsungen. [Same as 1507.]
T=26»®
1507. H. RShler. Dis. Ldpsig. (1909).
Untersuchungen iiber Formamid als Losungsmittd, etc. [Same as 1606d*]
1608. H. Roemer. Dis. Miinster. (1907).
Bestimmung der Basizitat durch Titration mittels Leitf&higkeitsmessung mit
besonderer BerUcksichtigung hydroxylhaltiger aromatischer Verbindungen.
[Most is given in 1718. ]
T=25^ R. O. X aq.=9.5Xl0-«; not sub.
H. Roemer see A. ThieL
'' '' see A. Thiel, A. Schumacher.
AUTHOR LIST 601
1509. W. C. ROntgen. Ann. Fhysik. (3), 52, 59S-603, (1894).
Ueber die Einfluss dee Dnickes auf die Dielectricit&tsoonstante des Waasen
und des Aethylalcohols.
1610. (W. C. Rttntgen. Nachr. Ges. Wis. Gattingen. (1893), 505-^511.
TJfber den Einfluss des Dnickes auf das galvanische LeitungBverm5gen von
Electrolyten.) [Inorganic]
1611. (W. C. Rttntgen. Sitzber. Phys.-med. Ges. WQrzburg. (1895), 132-
141.
Ueber eine neue Art von Strahlen.)
P. Rona see L. Micfaaelis.
1611a. P. Rona, L. Micliaelis. Biochem. Zeit. 21, 114r-122, (1909).
Ueber den Zustand des Caldums in der Milch.
T»25'.
1611b. P. Rona, L. MicliaeUs. Biochem. Zeit. 28, 193-199, (1910).
Beitr&ge sur allgemeinen Eiweisschemie. II. Mitteilung. Ueber die FftUung
der Globuline im isoelektrischen Punkt.
Roncati see Nicolosi-RoncatL
1612. M. Ronus. Dis. Basel. (1901). Meas. H. Labhardt.
Ueber Cineolsaure. [Same as 1546.]
T»20^
M. Ronus see H. Rupe.
1618. (E. B. Rosa. PhH. Mag. (5), 31, 188-207, (1891).
Specific inductive capacity of electrolytes.) [Temperatmre coefficients.]
Meas. N. Rosanoff ; see 744.
Roschdestvensky see Roidestvanskij.
Meas. F. Rose; see 090.
F. Rose see F. Kohlraoach.
1614. (A. Rosenheim. Zeit. Anorg. Chem. 11, 175-222, (1896).
Ueber die Einwirkung anorganischer Metalls&uren auf organische S&uren.)
1616. A. Rosenheim. Zeit. Anorg. Chem. 11, 225-248, (1896). Meas. F.
Hamburger,
Ueber die Einwirkung anorganischer Metalls&uren auf organische S&uren.
[See 1616 for more accurate measurements.]
T = 18^
1616. A. Rosenheim. Zeit. Anorg. Chem. 21, 1-18, (1899), Meas. /.
Koppd.
Ueber die Einwirkung anorganischer MetaUs&uren auf organische S&uren.
T-25*.
1617. A. Rosenheim. Zeit. Anorg. Chem. 54, 97-103, (1907).
Untersuchungen Hber die Halogenverbindungen des Molybd&ns und Wolframs.
T-25^
Meas. A. Rosenheim; see 69S, 1028.
1618. A.Rosenhehn,A.Bertheim. Zeit. Anorg. Chem. 34, 427-447, (1903).
Die Hydrate der Molybd&ns&mre und einige ihrer Verbindungen.
T=25^
1619. A. Rosenheim, H. Grfinbaum. Zeit. Anorg. Chem. 61, 187-201,
(1909).
Ueber tetragene Doppelsalse des Antimonfluorids.
T— 0®. aq. is " purest conductivity aq."
1620. A. Rosenheim, J. Hertzmann. Ber. Deutsch. Chem. Gres. 40, 810-
814, (1907).
Zirkoniimatetrachlorid und koUoidales Zirkoniumhydroxyd.
T=0''and25^ R. O.
602 AUTHOR LIST
1621. A. Rosenheim, H. Itzig. Ber. Deutsch. Chem. Ges. 32, 3424r-^440,
(1899).
Ueber einige complexe Sake der WeinB&ure und Aepfels&uie und ihr specie
fischee Drehungsvermdgen. [Same as 867.]
T=25^
1622. A. Rosenheim, W. Levy. Zeit. Anorg. Chem. 43, 34-47, (1905).
Ueber Platinphoephorhalogenverbindmigen und ihre Derivate. [Part is same
as 1076, but has no measurement at 0^.]
T=25^
1628. A. Rosenheim, O. Liebknecht Ber. Deutsch. Chem. Ges. 31, 405-
414, (1898).
Ueber alkylschwefligs&ure Sake.
T-0°and25^
1624. A. Rosenhehn, W. Loewenstsmm. Zeit. Anorg. Chem. 34, 62-81,
(1903).
Ueber die Thiocarbamidverbindungen einwertiger Metallsalze. [Same as
1117 for 25^ ]
T=25*'and0^
1626. (A. Rosenheim, W. LoewenstamnL Zeit. Anorg. Chem. 37, 394r-406,
(1903).
Ueber Platinphosphorhalogenverbindungen imd ihre Derivate.) [Inorganic. ]
1626. A. Rosenheim, V. J. Meyer. Zeit. Anorg. Chem. 49, 13-27, (1906).
Ueber die Thiokarbamidverbindungen zweiwertiger Metallsalce.
T=25^
1627. A. Rosenheim, V. J. Meyer. Zeit. Anorg. Chem. 49, 28^3, (1906).
Notiz liber die Absorptionsspektra von Ldsungen isomerer komplexer Ko-
baltsalze.
T=25^
1628. A. Rosenheim, P. Miiller. Zeit. Anorg. Chem. 39, 175-186, (1904).
Ueber Ferriacetoverbindungen.
T=25^
1629. A. Rosenheim, W. SUdler. Ber. Deutsch. Chem. Ges. 38, 2687-2690,
(1905).
Die Thioapf elsaure und ihre Salze.
T=25^
1680. A. Rosenheim, W. SUdler. Zeit. Anorg. Chem. 49, 1-12, (1906).
Ueber Verbindungen des Thiokarbamids imd Xanthogenamids mit Salzen des
einwertigen Kupfers.
T=25^
1680a. A. Rosenhehn, M. Weuiheber. Zeit. Anorg. Chem. 69, 261-265,
(1910).
Ueber Tellurss&ureoxalate.
T=25°.
1681. W. H. Ross. Proc. Trans. Nova Scot. 11, 95-114, (1902-1906).
Contribution to the study of hydroxylamine and its salts.
T = 18^ Hg. U. xi8 aq. is about l.lX10-«; sub.
1682. 6. Rossi. Arch. Fisiol. 1, 500-504, (1904).
La viBOOsitd. e la resistenza elettrica del siero di sangue a temperature diverse
e prossime a quella dell'organismo.
T=30•*to60^
U. Rossi see 6. Carrara.
J. V. Roszkowski see S. v. Niementowski.
A. W. Roth see H. Henkel.
AUTHOR LIST 508
1538. W. A. Roth. Ber. Deutsch. Chem. Ges. 33, 2032-2035, (1900).
Affinit&tsooiiBtanten einiger S&uren mit Kohlenstoffsiebenring.
T=25^ R. O. xm aq. = 1.3-1.6X10^; not sub. Alao gives k with
aq. sub.
1B34. W. A. Roth. Zeit. Phys. Chem. 42, 209-224, (1902-1903).
Elektrisches Leitvermdgen von Kaliiunchlorid in Wasser-Aethylalkoholgem-
ischen.
T = 18'. R. O.
Meaa, W. A. Roth; see 1087, 1239, 1642.
1686. V. Rothmund. Monatsh. 26, 1545-1558, (1905).
Ueber die Einwirkung des Acetons auf Alkalisulfite.
T=25*. R. O.
Meas. V. Rothmund; see 848, 1074, 1974, 1976, 1976, 1977, 1978, 1979.
1686. V. Rothmund, K. Drucker. Zeit. Phys. Chem. 46, 827-^2, (1903).
Ueber die elektrol3rti8che Dissociation der Pikrins&ure.
T=25^ R. O. xt5aq. = 1.5XlO-*;not8ub.
C. A. Rouiller see H. C. Jones.
Meas, C. Roy; see 1464a.
M. S. RoidestvensUj see A« 6. Doroftevskij.
W. Ruckstuhl see R. Lorenz.
Mea8. E. Rudin; see 671.
1687. M. Rudolphi. Zeit. Phys. Chem. 17, 277-^00, (1895).
Ueber Losungs- und Dissociationsw&rmen.
T =25** to 60°. S. U. X aq. sub.
1688. (M. Rudolphi. Zeit. Phys. Chem. 17, 385-426, (1895).
Ueber die GtUtigkeit der Ostwaldschen Formel zur Berechnung der Affinit&tB-
konstanten.) [Quoted. ]
1689. G. Rudorf. Zeit. Phys. Chem. 43, 257-304, (1903).
Zur Kenntnis der Leitfahigkeiten und innem Reibungen yon Lteungen.
IBameas 1640.]
T =25" *0.05^ X aq. about 4 X 10-«; not sub.
1640. 6. Rudorf. Dis. Breslau. (1903).
Zur Kenntnis der Leitf&higkeiten, etc. [Same as 1689.]
A. Riicker see A. Naimiann.
1641. (H. Raping. Dis. Erlangen. (1897). Abstracted in Bdbl. Ann.
Physik. 22, 412, (1898).
I. Beitr&ge zur Kenntnis der Ketomenthylsaure und Menthoximsfture.
II. Leitf&higkeit wasserig-alkoholischer Salzlosungen.) [Inorganic]
1642. O. Ruff. Ber. Deutsch. Chem. Gea. 32, 550-560, (1899). Meaa. W.
[A,] Roth,
d- und r-Arabinose.
T=25^
O. E. Ruhoff see L. Slahlenberg.
1648. H. Rupe. Ann. Chemie, 256, 1-28, (1890). Meaa. W. OOwald.
Ueber die Reductionsproducte der Dichlormuconsaure.
[Baeyer's name is not in the title of this article. ]
1644. H. Rupe. Ber. Deutsch. Chem. Ges. 33, 112^1140, (1900). Meas.
Labhardt,
Ueber Cineols&ure.
T = 18".
H. Rupe see O. Manasse.
1646. H. Rupe, W. Lotz. Ber. Deutsch. Chem. Ges. 36, 2796-2802, (1903).
Ueber einige Condensationen mit Citronellal. [Qualitative. Conected in
Ber. Deutsch. Chem. Ges. 40, 281^-2817, (1907).]
504 AUTHOR LIST
1546. H. Rttpe, M. Roniu. Ber. Deutech. Chem. Ges. 34, 2191-2206,
(1901). Meaa. H. Labhardt.
Ueber Cineolsfture. [Same as 1612.]
T=20^
1647. H. Rttpe, M. Ronus, W. Lotz. Ber. Deutsch. Chem. Ges. 35, 4265-
4272, (1902). Meaa. A. PfiMer,
Ueber die Darstellimg von imgesattigten aliphatischen S&uren mit einer
Doppelbindung in der a,j3-Stellung.
1548. This reference has been omitted intentionally.
1649. E. Ruppin. Zeit. Phys. Chem. 14, 467-185, (1894).
Volum&nderungen bei der Neutralisation starker S&uren und Basen.
P. V. Rudnov see R. Wegscheider.
1550. F. Rttss. Zeit. Anorg. Chem. 31, 42-91, (1902).
Ueber Nioboxals&ure.
K. Russwonn see H. Stobbe.
S.
1551. (B. Sabat Bui. Acad. Craoov. (1906), 62-79.
Ueber den KinflusB der Radiumstrahlen auf das Leitvermdgen der Elektrolyte.)
[Inorganic. ]
1552. (L. Sabbatani, 6. Bnglia. Arch. Fisiol. 3, 154-163, (1906).
Velocitd. di coagulazione al calore di liquidi albuminosi.)
1552a. A. Sachanov. Jour. Russ. Phys.-chem. Soc. 42, 683-690, (1910).
The electrical conductivity of solutions in aniline, methylaniline and dimethyl-
aniline.
T=25^ R. O.
1553. O. Sackur. Ber. Deutsch. Chem. Ges. 35, 1242-1252, (1902).
Ueber die basischen Eigenschaften des vierwerthigen Sauerstoffs.
T = 15^and22°. R. O.
1554. O. Sackur. Zeit. Phys. Chem. 38, 129-162, (1901).
Ueber den Einfluss gleichioniger Zus&tse auf die elektromotorische Kraft von
Flttssigkeitsketten. Ein Beitrag zur Kenntnis des Verhaltens starker EHek-
trolyte.
T-18•and25^
1555. O. Sackur. Zeit. Phys. Chem. 41, 672-680, (1902).
Das elektrische Leitvermdgen und die innere Reibimg von Ldsungen des
Caseins. [An abridgement of 1054. No measurement of wocas^ln is given
here.]
T«25^ R. O. xaq.- 2.6X10^; sub.
O. Sackur see E. Laqueur.
P. J. Sageman see J. Holmes.
1556. Sald-Eifendi. Compt. Rend. 68, 1565-1567, (1869).
Mesure de la conductibilit^ 61ectrique des liquides consid^r^s jusqu'i present
comme isolants.
1557. J. Sakurai. Jour. Chem. Soc. 69, 1654r-1662, (1896).
Molecular conductivity of amidosulphonic acid.
T = 25.00° «fc0.05'*. X aq. « 1.9 X 10-«; not sub. for acid, sub. for salt.
1558. R. Salcher. Dis. Heidelbo^. (1899).
Studien Qber die Aminolyse. [Same as 664.]
T-25'.
R. M. Salcher see H. Goldschmidt
1559. (W. Salessky. Zeit. Elektiochem. 10, 204-208, (1904).
Ueber Indikatoren der Acidimetrie und Alkalimetrie.)
AUTHOR LIST 606
1660. (B. Salm. Zeit. Elektrochem. 10, 341-^46, (1904).
Die Bestimmung des H'-Gehaltes einer Losung mit Hilfe von Indikatoren.)
1061. B. Salm. Zeit. Elektrochem. 12, 99-101, (1906).
Kolorimetrische Affinitatsmessungen. [Given in 1662.]
1662. E. Salm. Zeit. Phys. Chem. 57, 471-^501, (1906).
Studie Uber Indikatoren. I. Teil. Die Verwendung der Indikatoren zu
AffinitfitBmessungen. [Same as 1661| but contains also camphoronic
acid.] ;
T^lS^tolO*.
1668. E. Salm. Zeit. Phys. Chem. 63, 83-108, (1908).
Messungen der Affinit&tsgrSssen organischer Sauren mit Hilfe von Indikatoren.
T = 18^
Mea8, E. Salm; see 274.
1664. (B. Salm, H. Fliedenthal. Zeit. Elektrochem. 13, 125-130, (1907).
Zur Kenntnis der Acidimetrischen und Alkalimetnschen Indikatoren.)
1666. (R. Salvadori. Gaz. Chim. Ital. 26, 1, 237-254, (1896).
DiBsociazione elettrolica in relazione coUe variazioni della temperatmtt. I.
Studi crioscopi ed ebullioscopici sopra le soluzioni cMsquose e in alcool metilico
di alcuni cloruri.) [Inorganic]
1666. (R. Salvadori. Gaz. Chim. Ital. 30, II, 544-^8, (1900).
Riconoscimento della dissociazione idrolitica per mezzo della oonducibilit^
eiettrica.) [Inorganic]
1667. A. H. Salway. Dis. Leipzig. (1906).
Ueber farbige Salze aus farblosen Nitrokdrpem. [Part is given in 746; part in
1092.]
T-0*and25'.
Meas, A. H. Salway; see 746, 1092.
1668. M. Samec Monatsh. 26, 391^11, (1905).
Kondensation von Formisobutyraldol mit Dimethylanilin.
T=25°and0^
6. V. Sammet see A. A. Noyes.
1669. J. L. Sammis. Jour. Phys. Chem. 10, 593-625, (1906).
On the relation of chemical activity to electrolytic conductivity.
T«25'', except for a few measurements at 7** and 7.5 ^
1670. A. SamojlofiF. Biochem. Zeit. 11, 210-225, (1908). Meas, vnth A.
PheophUaktotva,
Ueber den KinfliLss der Gerinnung des Blutes auf die Leitfahigkeit desselben.
T=25*and38.9^
1671. J. Sand. Her. Deutsch. Chem. Ges. 38, 3642-3654, (1905).
Salze der Erystallviolettgruppe.
J. Sand see J. Maas.
1672. J. Sand, O.j^Bnxger. Ber. Deutsch. Chem. Ges. 39, 1761-1770,
(1906).
Reduction von Molybd&nsaure in rhodanwasserstoffsaurer Ldsung.
1678. J. Sand, O. Burger. Ber. Deutsch. Chem. Ges. 39, 1771-1779,
(1906).
Oxydation von Chromosalzen.
T=24*. R. O.
C. Sandonnini see 6. Bruni.
1678a. C. Sandonnim. Zeit. Elektrochem. 16, 227-229, (1910).
Vergleichende Untersuchungen Uber Salzbildung vom physikochemischen
Standpunkte.
T=25^
606 AUTHOR LIST
1674. H. Sandqvist Ann. Chemie. 369, 104-117, (1909).
Ueber Phenanthr^-3-sulfo6&iire imd einige ihrer DcNtivate.
T « IS.OO**. R. O. xie aq. = 1.8 X lO"*.
Saposchnikoff see Sapoinlkov.
Saposchnikov see SapoSnikov.
A« Sapovalenko see P. Pissarjewsky.
1676. W. Sapoinlkov. Jour. Russ. Phy8.-ch6m. See. 25, 626-631, (1893).
On the electrical conductivity of foimic acid.
T=8.3°tol8.8^
Meas, W. SapoSnikov; see 1011, 1018.
L. W. Sargent see 6. N. Lewis.
1676. W. Sarow. Dis. Berlin. (1905).
Ueber die Konstitution der schwefligen S&ure und ihrer Derivate. Versuche
tiber das Sulfamid.
T=26^ xaq.=4.9Xl0-«.
B. Savar^ see M. Padoa.
N. Scalind see F. BottazzL
B. Scandola see G. Oddo.
1677. H. SchUfer, R. Abegg. Zeit. Anorg. Chem. 45, 293^323, (1905).
Untersuchungen Uber die Elektroaffinit&t der Anionen. 1. Das Oxalat-Ion.
T = 15.5^ 18.5° and 25^
K. Schaef er see H. Ley.
1678. C. Schall. Zeit. Elektrochem. 14, 397--405, (1908).
Ueber organische und geschmolzene Salse.
T = 17**toll3* R O
1679. C. SchaU. Zeit. Phys. Chem. 14, 701-708, (1894).
Ueber die Abnahme der molekularen Leitf&higkeit einiger starken, organischen
S&uren bei Ersatz des Ldsungswassers durch Alkohole. [See 1660.]
T'=25®.
1660. C. SchaU. Zeit. Phys. Chem. 19, 699-700, (1896).
Nachtrag zur Letzten Abhandlung. [Supplementary to 1679.]
1681. R. SchaUer. Zeit. Phys. Chem. 25, 497-524, (1898).
Messungen der elektrischen Leitf&higkeit an verdiinnten Losungen bei Tem-
peraturen bis 100°. [The values of k are only approximate values.]
T=25° to 99°. X aq. not over 1.5 X10-«; not sub.
1681a. C. Schi^er. Zeit. Phys. Chem. 72, 308-322, (1910).
Ueber das Oxydationspotential der Oxalate des Eisens und des Oxalations.
T = 17° to 30°.
1682. B. Schapire. Zeit. Phys. Chem. 49, 513-541, (1904).
Beitrag zur Kenntnis des elektrischen Leitvermogens von Natrium- imd
Kaliumchlorid in Wasser-Aethylalkoholgemischen. [Same as 168S.]
T = 18°. R. O. Xi8 aq. = 1.25 X 10-«.
168S. B. Schapire. Dis. Berlin. (1904).
Beitrag zur Kenntnis des elektrischen Leitvermdgens, etc. [Same as 1682. ]
M. Scheldt see 6. MagnaninL
1684. R. Schenck, [A. Kreichgatter]. Sitzber. Ges. Naturw. Marburg.
(1899), 43-47.
Ueber den KinfluBs von Sauren auf das optische DrehimgsvermSgen von
Asparaginldsungen.
1666. T. Scheutz. Dis. ZOrich. (1901).
Ueber alkyherte Amidobenzolsulfos&uren und Metamidophenole. [Same as
646.]
T. Scheutz see R. Gnehm.
MeoB, G. Schick; see 760.
AUTHOR LIST 607
1686. (U. Schiff. Gaz. Chim. Ital. 28, 1, 49-64, (1808).
Intorno a oomposti poliaspartici.) [No conductivity.]
K. Schilling see J. Koenigsberger.
1687. R. ▼. Schilling. Dis. HaUe. (1899).
Die elektrolytische Leitfahigkeit der Hydroresorcine und d-Ketons&uren.
[Same as 1688, with some additional measurements of succinic and 7-acetyl-
butyric acids. ]
1688. R. ▼. Schilling, D. Vorllnder. Ann. Chemie. 308, 184-202, (1899).
Die elektrolytische Leitfahigkeit der Hydroresorcine und d-Ketons&uren.
[Given in 1687.]
T=25^ R. O. xaq.=2.1-3.4XlO-«; notsub.
1689. A. Schlamp. Zeit. Phys/ Chem. 14, 272-285, (1894).
Zur Dissociationstheorie der Ldsungen.
T = 15.6^
1690. H. I. Schlesinger. Am. Chem. Jour. 39, 719-771, (1908).
Studies in catalysis. VI. The catalysis of imidoesters.
T=0^ R. O.
J. Schliemann see E. LeUnuum.
H. Schlundt see L. Kahlenberg.
1690a. E. W. Schmidt Zeit. Phys. Chem. 75, 30&-336, (1910-1911).
Ueber den Einfluss des Druckes auf das elektrolytische Leitvermdgen von
Ldsungen in verschiedenen Ldeungsmitteln.
T=0^to60^
1691. (M. R. Schmidt. Am. Chem. Jour. 40, 305^13, (1908).
The basicity of acids as determined by their conductivities.) [Inorganic]
1692. M. R. Schmidt, H. C. Jones. Am. Chem. Jour. 42, 37-95, (1909).
Conductivity and viscosity in mixed solvents containing glycerol.
T=25^and35^ S. U. x aq. = 1.2-1.5X10-«.
1693. O. Schmidt Dis. Bonn. (1898).
Ueber die Konatitution der Einwirkungsprodukte von Diazoverbindungen
auf prim&re Nitrokorper und Uber stereoisomere Hydrazone. [Same as 82.]
T=0^ and 25**. X25 aq. =3XlO-«; not sub.
MeoB, O. Schmidt; see 78, 82.
O. Schmidt see E. Bamberger.
R. Schmidt see F. Stohmann.
1694. V. Scholz. Dis. Heidelberg. (1902).
Dynamische Untersuchungen iiber die Verseif tmg von S&ureestem und die
Affinitatsoonstanten derselben. [Part is given in 666.]
v.* Scholz see H. Goldschmidt
O. Schreiner see L. Kahlenberg.
Meas. E. SchrMer; see 876.
H. SchrSder see J. W. BrOhl.
1696. (I. F. SchrSder. Jour. Russ. Phys.-chem. Soc. 30, 33^-334, (1898).)
[No title. This is in a report of a meeting. The subject is the conductivity
of anunonium nitrate in anunonia. ]
1696. J. Schroeder. Ann. Phy^. (4), 29, 125-152, (1909).
Das Verhalten des Aethyl&thers beim Durchgange eines elektrischen Stromes.
T-1% 18^and30^
1697. S. B. Schxyver. Jour. Chem. Soc. 63, 1327-1345, (1893). Meas, C.
S. Palmer.
Researches on the oxidation products of turpentine oil. [k is given in 1698*
but no table of fi and k. ]
T=25^
608 AUTHOR LIST
1608. S. B. Sduyrer. Proc. Chem. Soc. 9, 187, (1893).
Studies of the oxidation products of turpentine. [Same as 1697 for k.]
1609. S. B. Sduyyer, R. Lessing. Jour. Soc. Chem. Ind. 28, 60-67,
(1909).
A physico-chemical method for comparing the antiseptic value of disinfectants.
T-37^
leOO. A. Schubert Dis. Bonn. (1908).
Ldslichkeitsbestimmimgen an schwerloslichen Salzen seltener Erdmetalle.
[Most is given in 1496.]
T = 18^ to 26^ R. O. xu aq.«2XlO-*; sub.
A. Schubert see E. Rimbach.
Meas, A. Schubert; see 1749.
K. Schiibel see H. Pauly.
1601. M. SchOmann. Ber. Deutsch. Chem. Ges. 33, 527-533, (1900).
Zur Kenntniss des Diazotierungsprocesses und der salpetrigen Saure.
T=20^
1602. M. Schilnuuin. Dis. WtU-zburg. (1899).
Zur Kenntnis des Diazotierungs-Processes und der Verfoindungen R.NiOH.
[Given in 774.]
T=0^
Meas. M. Schiimaim; see 786, 779.
M. Schiimann see A. Hantzsch.
Meaa. A. Schugowitsch; see 1916.
O. W. Schultze see A. Hantzsch.
A. Schumacher see A. ThieL
1608. J. Schwab. Dis. Basel. (1904).
I. Ueber die stereoisomeren /3-Methyl|^utaoons&uren. II. Ueber o-Diamlno-
guajacol und sein Oxydationsprodukt. [Same as 672.]
T=26*. R. O. xaq.=3Xl0-«.
J. Schwab see F. Fichter.
1604. E. V. Schweidler. Ann. Physik. (4), 4, 307-315, (1901).
Ueber das Verhalten flUssiger Dielektrika b^m Durchgange eines elektnschen
Stromes. [Same as 1607.]
1606. E. V. Schweidler. Ann. Physik. (4), 5, 483-486, (1901).
Ueber das Verhalten flUssiger Dielektrika beim Durchgange eines elektnschen
Stromes.
R. O.
1606. (E. V. Schweidler. Ann. Physik. (4), 24, 711-770, (1907).
Studien Uber die Anomalien im Verhalten der Dielektrika.) [Same as
1608.]
1607. E. V. Schweidler. Sitzber. Akad. Wien. 109, 2a, 964-973, (1900).
Ueber das Verhalten, etc. [Same as 1604.]
1608. (E. V. Schweidler. Sitzber. Akad. Wien. 116, 2a, 1019-1080,
(1907).
Studien liber die Anomalien, etc.) [Same as 1606.]
E. V. Schweidler see C. B6hm-Wendt
E. Scipiades see G. Farkas.
M. Scott see S. Deakin.
1609. (H. Scudder. Jour. Phys. Chem. 7, 269-299, (1903).
The reliability of the dissociation constant as a means of determining the iden-
tity and pinity of organic compounds.) [Quoted. ]
F. Sebaldt see A. Hantzsch.
AUTHOR LIST 609
leOOa. (S. W. S^rkov. Zeit. Phys. Chem. 73, 557-577, (1910).
Die dektriache Leitf&higkeit von Ldsungen und der Zustand des geldsten
Stoffes.) [Inorganic]
S. Seydel see H. Stobbe.
Meas, O. H. Shadinger; see 16.
G. H. Shadinger see S. P. Acree.
1610. (W. N. Shaw. Proc. Cambridge Phil. Soc. 7, 21-31, (1880-1892).
On the relation between viscosity and oonductiyity of electrolytes.) [Quoted. ]
1610a. J. Shields. Zeit. Phys. Chem. 12, 167-187, (1893).
Ueber Hydrolyse in wfisserigen Salsldsungen. [Saponification of esters.]
T -24.1^ and 24.2^
1611. P. L. Shinn. Jour. Phys. Chem. 11, 201-224, (1907).
On the optical rotatory power of salts in dilute solutions.
[T is probably 25''.] x aq. is about 2 X 10-«; sub.
1612. P. L. Shinn. Jour. Phys. Chem. 11, 537-541, (1907).
On the electrical conductivity of solutions in ethyl amine.
T=0^ R. O.
1618. L Shnkoff. Ber. Deutsch. Chem. Ges. 38, 2691-2693, (1905).
Beitrag zur Kenntniss der metallorganischen Verbindungen.
T=25^
N. V. Sidgwick see A. C. D. Rivett.
1614. N. V. Sidgwick, T. S. Moore. Jour. Chem. Soc. 95, 889-898, (1909).
The rate of reaction of the triphenylmethane dyes with acid and alkali. Part
II. Brilliant-green and malachite-green. [Same as 1616 for k. Measurements
given in full here. ]
1616. N. V. Sidgwick, T. S. Moore. Proc. Chem. Soc. 25, 123-124, (1909).
The rate of reaction, etc. [Same as 1614 for k. ]
1616. N. V. Sidgwick, T. S. Moore. Zeit. Phys. Chem. 58, 385-408, (1907).
Zur Dynamik der Tautomeric. I. Brillantgrttn.
1617. N. V. Sidgwick, A. C. D. Rivett Jour. Chem. Soc. 95, 899-908, (1909).
The rate of reaction of the triphenylmethane dyes with acid and alkali. Part
III. Diaminotriphenylcarbinol. [Same as 1618 for k. Measurements given
in full here. ]
1618. N. V. Sidgwick, A. C. D. Rivett Proc. Chem. Soc. 25, 124r-125,
(1909).
The rate of reaction, etc. [Same as 1617 for k.]
1618a. N. V. Sidgwick, H. T. Tizard. Jour. Chem. Soc. 97, 957-972, (1910).
The colour and ionisation of cupric salts. [Qualitative statement in 1618b.]
T = 18^ R. O. xi8 aq. =* 1-1.5 X 10-*.
1618b. N. V. Sidgwick, H. T. Tizard. Proc. Chem. Soc. 26, 67, (1910).
The colour and ionisation of cupric salts. [Qualitative. Given in 1618a with
full data.]
1618c M. Siegfried. Ergebn. Physiol. 9, 334-350, (1910).
Die Carbamino- und Hydroxylkohlensaurereaktion.
1619. M. Siegfried. Zeit. Physiol. Chem. 46, 401^14, (1905).
Ueber die Bindung von Kohlens&ure durch amphotere Amidokdrper.
T=25^ Xi6aq.= 2.5X10-*; sub.
1620. H. P. Sill. Zeit. Phys. Chem. 51, 577-602, (1905).
Ueber das Gleichgewicht zwischen einer StickstofiEbase und organischen S&uren
in verschiedenen Losungsmitteln. [Same as 1621. ]
1621. H. F. Sill. Dis. Leipzig. (1905).
Ueber das Gleichgewicht zwischen einer StickstofiEbase und organischen S&uren
in verschiedenen Losungsmitteln. [Same as 1620.]
Meas. E. Siller; see 1764, 1760.
610 AUTHOR LIST
1(128. I. Simon. Arch. Fisiol. 4, 594-604, (1907).
Ricerche sulla ooagulazione delle albumine. I. Variaiioni fiaioo-chemiche del
siero per aggiunta di aloool.
T=*25®.
1028. I. Simon. Arch. Fisiol. 6, 394^1, (1908).
Ricerche sulla ooagulazione delle albumine. II. Variasioni fisico-chimiche
del siero per aggiunta di acetone.
T=25®.
1(124. I. Simon. Arch. Fisiol. 5, 402-106, (1908).
Ricerche sulla ooagulazione delle albumine. UI. Variadoni fisioo-chimiche
del siero per aggiunta di alcool metiUco.
T=25®.
1626. I. Simon. Arch. Fisiol. 5, 470-476, (1908).
Ricerche sulli^ coagulazione delle albumine. IV. Variasioni fisioo-chimiche
del siero per aggiunta di alcool propilico.
T'«25*.
1626. I. Simon. Arch. Fisiol. 5, 477-478, (1908).
Ricerche sulla coagulazione delle albumine. V. Variadoni fisioo-chimiche del
siero per aggiunta di alcool allilico.
T=26®.
1626a. I. Simon. Arch. Fisiol. 8, 361-382, (1910).
Ricerche sulla coagulazione! delle albumine. VII. Variasioni fisioo-chimiche
del siero per aggiunta di sali di metalli pesanti.
T=25^
J. L. Simonsen see W. H. Parkin, Jr.
W. Sinclair see W. H. PerUn, Jr.
1627. H. A. Sirks. Rec. Trav. Chim. 27, 207-250, (1908).
fitudes sur les six acides dinitrobenzolques. [Same as 1628 for k. Tables of
A also given here. ]
T=25°to40^ R. O. xisaboutlXlO-*.
1628. H. A. Sirks. Verslag Akad. Amsterdam. 15, 264-270, (1906-1907).
Verslag Akad. Amsterdam, English translation, 9, 280-286, (1906-
1907.)
De zes isomere dinitrobenzoSzuren. [Same as 1627 for k. It is indexed, as,
Holleman, Sirks.]
SifikoTsidj see Szjrszkowski.
P. Sisley see P. Barbier.
J. SjOqvist Ergebn. Physiol. 9, 241-333, (1910). See H. Euler.
1629. S. Skinner. Jour. Chem. Soc. 73, 483-490, (1898).
Affinity constants of dihydroxymaleic, dihydroxyfumaric, dihydroxytartaric,
and tartronic acids.
T-25**. Hg. U. X aq. not sub.
1630. Z. H. Skraup. Monatsh. 12, 107-145, (1891).
Ueber die Umwandlung der Maleins&ure in Fumarsaure. [Same as 1682.]
T=22^58^and96^ S. U.
1681. Z. H. Skraup. Monatsh. 15, 775-786, (1894).
Ueber die Affinit&t einiger Basen in alkoholischer Ldsung.
T=25*.
1682. Z. H. Skraup. Sitzber. Akad. Wien. 100, 2b, 124-162, (1891).
Ueber die Umwandlimg der Maleins&ure in Fumars&ure. [Same as 1680.]
1688. G. ▼. d. Sleen. Rec. Trav. Chim. 21, 209-251, (1902).
L'acide vinylglycolique (but^nolique 1, 3) et ses transformations. [Same
1684. k, but no A, is given in 800.]
R. O. X aq. sub.
AUTHOR LIST 611
1684. G. ▼. d. Sleen. Dis. Basel. (1901).
Ueber die ct-Oxybutens&ure (Vinyl-glycols&ure) und ihre Umlagerungen.
[Same as 1633. See 800.]
Meas. O. ▼. d. Sleen; see 800.
1634a. (W. H. Sloan. Jour. Am. Chem. Soc. 32, 946-^9, (1910).
On the conductivity of some concentrated aqueous solutions at zero.) [In-
organic]
C. H. Sluiter see A. Hantzsch.
D. D. Van Slyke see L. L. Van Slyke.
1636. L. L. Van Slyke, D. D. Van Slyke. Am. Chem. Jour. 38, 383-456,
(1907).
The action of dilute acids upon casein when no soluble compounds are
formed.
T=25**=fc0.03^ xaq.- 1-1.8X10-*; sub.
1636. L. L. Van Slyke, D. D. Van Slyke. Am. Chem. Jour. 38, 619-626,
(1907).
The hydrolysKB of the sodium salts of caseiQ.
T=25**=*=0.03^ xaq.-l-1.8XlO-«; sub.
1637. (W. A. Smith. Zeit. Phys. Chem. 25, 144-177, (1898).
Ueber die stufenweise Dissociation zweibasischer organischer S&uren.) [Same
as part of 1639.]
1638. W. A. Smith. Zeit. Phys. Chem. 25, 193-264, (1898).
Ueber die stufenweise Dissociation zweibasischer organischer S&uren, II.
[Same as part of 1639.]
T=25^ J^xaq. sub.
1639. W. A. Smith. Dis. Leipzig. (1898).
Ueber die stufenweise Dissociation zweibasischer organischer S&uren. [Same
as 1637 and 1638 together.]
MeoB. W. A. Smith; see 817, 1661, 1662.
1639a. This reference has been omitted intentionally.
1639b. S. P. L. Sttrensen. Biochem. Zeit. 21, 131-^304, (1909). Meas, S.
Palitach and R. Koefoed,
Enzymstudien. II. Mitteilimg. Ueber die Messung und die Bedeutung der
Waaserstoffionenkonzentration bei enzymatischen Prozessen.
T - 18^ kw at 18** = 0.72 X 10"".
W. Sokoloff see L. Tschugaeflf.
M. Solimene see G. AbatL
1640. P. Sonnebom. Dis. Basel. (1902).
Zur Kenntnis der Vinylessigs&ure. [Only vinylaoetic acid and its sodium salt
are given in 673.]
F. Sonnebom see F. Pichter.
Meaa. R. B. Seaman; see 1841.
R. B. Seaman see A. A. Neyes, Y. Kate.
J. P. Spencer see R. Abegg.
1641. A. W. Speranskij. Jour. Russ. Phys.-chem. Soc. 28, 329-334,
(1896).
On chromium thiocyanates.
T«25^
1642. (A. W. Speranskij, E.G. Goldberg. Jour. Russ. Phys.-chem. Soc. 32,
797-804, (1900).
Electrolysis of solutions of metallic salts in organic solvents.)
Speransky see Speranskij.
Speyer see Cahn-Speyer.
K. Spire see L. J. Hendersen.
612 AUTHOR LIST
1643. W. Spitzer. Arch. Gesammt. Physiol. 50, 551-^73, (1891).
Ueba* die Benutzung gewisser Farbstoffe zur Bestimmung Affinit&ten.
C. H. G. Sprankling see W. A. Bdiae.
" " " " see W. A. Bone, J. J. Sudborough.
•' « •• " see H. Henstock.
1M4. W. Spnick. Dis. ZOrich. (1898).
Ueber Additionsprodukte v. Aethylendiamin an Salze zwdwertiger Metalle.
[Same as 1946.]
Meaa. W. Spnick; see 1946.
W. Stadler see A. Rosenheim.
7Mea8, H. Stahl; see 448.
B. D. Steele see S. Deakin, M. Scott
'' " '' see R. B. Denison.
" •• " see D. Mcintosh.
1646. B. D. Steele, D. Mcintosh. Proc. Chem. See. 19, 220-221, (1903).
Ck)nductivity of substances dissolved in certain liquified gases. Preliminary
notice. [Qualitative. ]
1646. B. D. Steele, D. Mcintosh, E. H. Archibald. Zeit. Phys. Chem. 55,
129-199, (1906).
Die Halogenwasserstoffs&uren als leitende Ldsungsmittel. [Same as 1647.]
T=-100% -81^ and -50^
1647. B. D. Steele, D. Mcintosh, E. H. Archibald. Trans. R. Soc. London.
A, 205, 99-167, (1906).
The halogen hydrides as conducting solvents. Part I. The vapour pressures,
densities, surface energies and viscosities of the pure solvents. Part II. The
conductivity and molecular weights of dissolved substances. Part III. The
transport numbers of certain dissolved substances. Part IV. The abnormal
variations of molecular conductivity, etc. [Same as 1646.]
1648. L. Stein. Dis. Bonn. (1906).
Ueber die Drehungs&nderungen a]£tiver Ozys&uren durch Zirkon- und Zinn-
verbindimgen.
T=25^ R. O.
1649. K. Stehiitz. Dis. Berlin. (1906).
Ein Beitrag zur Beeinflussung des Leitvermdgens schwacher Elektrolyte in
Wasser durch Zusatze von anderen nicht leitenden Substanzen.
T « 25** =*=0.02'*. R. O. X aq. =« 1.25 X 10-«, or less; not sub.
1660. (H. V. Steinwehr. Zeit. Elektrochem. 7, 685-^86, (1900-1901).
Ueber die Gtdtigkeit des Massenwirkungsgesetzes bei starken Elektrolyten.)
H. V. Steinwehr see F. Kohlrausch.
1651. D. Stenquist Zeit. Elektrochem. 12, 860^62, (1906).
Bestinmiimg der elektrischen Leitf&higkeit des Jod-, Brom- und Chlorkaliums
in Aethyl- imd Methylalkohol. [Same as 1652.]
T=0^
1652. D. Stenquist. Arkiv Kemi. 2, No. 25, 1-8, (1905-1907).
Best&mning af elektnska ledningsform&gan for jod-, brom- och klorkalium
i etyl- och metylalkohol. [Same as 1661.]
1653. (C. Stephan. Ann. Physik. (3), 17, 67^701, (1882).
Beitrfige zu den Beziehungen zwischen Fluiditat und galvanischem Leitungs*
vermogen.) [Inorganic]
J. Stephenson see Berkeley, E. G. J. Hartley.
1664. E. Stem. Zeit. Phys. Chem. 50, 513^559, (1905).
Die chendsche Kinetik der Benzoinsynthese (Cyanionenkatalyse). [Same aa
1666.]
T-0^25*and60^ R. O.
AUTHOR LIST 618
1666. E. Stem. Die. Heidelberg. (1904).
Die chemische Kinetik der Bensoinsyntheee (CyanionenkatalyBe). [Same aa
1664.]
1666a. G. N. Stewart Jour. Physiol. 24, 211-238, (1899).
The behaviour of the haemoglobin and electrolytes of the coloured corpuscles
when blood is laked. *
1666b. G. N. Stewart. Jour. Physiol. 24, 46(M63, (1899).
The effect on the molecular concentration and electrical conductivity of muscle
extracts of removal of the proteids.
T=6^ R. O.
1666c. G. N. Stewart. Jour. Physiol. 26, 470-496, (1900-1901).
The conditions that underlie the peculiarities in the behaviour of the coloured
blood-corpuscles to certain substances.
T=6^ R. O.
1666. J. Stieglitz. Am. Chem. Jour. 39, 29-63, (1908).
Studies in catalysis. I. The cataljrsis of esters and of imidoesters by acids.
[See 439 and 1233 for measurements. ]
1667. J. Stiei^tz. Am. Chem. Jour. 39, 166-183, (1908). MeoB, by /. H,
Derby and W. McCracken,
Studies in catalysis. II. The catalysis of imidoesters. [k is same as in 439
and 1233 together.]
1668. (J. Stieglitz. Jour. Am. Chem. Soc. 30, 946-^54, (1908).
Note on the solubility product.)
1669. J. Stieglitz, I. H. Derby. Am. Chem. Jour. 31, 449-458, (1904).
A study of hydrolysis by conductivity methods.
T=25**=fc0.01^ X aq.=2.0Xia-«.
1660. J. Stieglitz, H. T. Upson. Am. Chem. Jour. 31, 458-502, (1904).
Meca, H. T, Upson,
The molecular rearrangement of aminophenyl alkyl carbonates.
T^O**. Hg. U. kw = 1.2X10-". [The values of k calculated with kw
for 0^, are about 0.1 of those given in this article.]
C. M. Stine see H. C. Jones.
1661. H. Stobbe. Ann. Chemie. 308, 114-155, (1899). Meas. FoatSf and
W. A, Smith,
Condensation Acetophenons mit Bemsteinsaiureester.
1662. H. Stobbe. Ann. Chemie. 321, 105-126, (1902). Meas.W, A.Smith.
Condensation des Aethylmethylketons mit Bemsteinsfiureester.
1663. H. Stobbe, R. HaerteL Ann. Chemie. 370, 9^129, (1909).
Lichtabsorption, Basenstfirke, Constitution und Salze der Ketone der Dibenz-
alaceton- imd Dibenzalcyklopentanonreihe.
1664. H. Stobbe, K. Russwurm. Ann. Chemie. 308, 156-174, (1899).
Meaa. Foote,
Condensation des Desoxybenzoins mit Bemsteinsaureester.
1666. H. Stobbe, S. Seydel. Ann. Chemie. 370, 129-141, (1909).
Lichtabsorption, Basenstarke, Constitution und Salze einiger unges&ttigter
cyklischer Ketone, Ketons&uren und Ketonsaiu'eester.
1666. F. Stohmann, C. Kleber. Jour. Prakt. Chem. (2), 45,475-499,(1892).
Calorimetrische Untersuchungen. Hydrirung geschlossener Ringe; die Con-
stitution der Camphersfiure vom thermo-chemischen Standpunkte.
1667. F. Stohmann, C. Kleber, H. Langbein, P. (Mfenhauer. Jour. Prakt.
Chem. (2), 49, 9^129, (1894).
Calorimetrische IJntersuchimgen. Ueber den W&rmewerth der aliphatischen
Sfiuren. [Same as 1668.]
614 AUTHOR LIST
1668. F. Stohmann, C. Kleber, H. Langbein, P. Offenhauer. Ber. V^haiuL
S&chs. Ges. Wis. 45, 604-658, (1893).
Ueber den Warmewerth der aliphatischen S&uren. [Same as 1667.]
1669. F. Stohmann, H. Langbein. Jour. Prakt. Chem. (2), 49, 483-501,
(1894). Mea8, [H.] Wislicenus.
Calorimetrische Untersuchungen. Ueber die thennischen Vorg&nge bei der
Bildung einiger Aminsauren und Nitrile. [Same as 1671. Qualitative.]
1670. F. Stohmann, H. Langbein. Jour. Frakt. Chem. (2), 50, 388-400,
(1894). fUMeaa, Paul.
Calorimetrische Untersuchimgen. Uel)er den Warmewerth isomerer Sauren
yon der Zusanmiensetzimg C7H6O3 und CgHsOi. [Same as 1672, except that
A of o-oxy-o-toluic acid is not given here. ]
1671. F. Stohmann, H. Langbein. Ber. Verhand. Sachs. Ges. Wis. 46, 49-
72, (1894). Meas. [H.] Wislicenus.
Udber die thennischen VorglUige, etc. [Same as 1660.]
1672. F. Stohmann, H. Langbein. Ber. Verhimd. S&chs. Ges. Wis. 46,
226-251, (1894). $Meas. Paul.
Ueber den Warmewerth, etc. [Same as 1670 with addition of A of o-oxy-o-
toluic acid.]
1678. F. Stohmann, R. Schmidt Jour. Prakt. Chem. (2), 53, 345-^69,
C1896). Meas. H. Wislicenus, and DiUrich.
Calorimetrische Untersuchimgen. Udber den W&rmewerth der Hippursaure,
ihrer Homologen und der Anisurs&ure. [Same as 1674.]
1674. F. Stohmann, R. Schmidt. Ber. Verhand. S&chs. Ges. Wis. 47, 375-
399, (1895). Meas. H. Wislicenus, and DiUrich.
Ueber den W&rmewerth der Hippurs&ure, ihrer Homologen und der Anisur-
saure. [Same as 1678.]
1676. (L. Storch. Zeit. Phys. Chem. 19, 13-19, (1896).
Ueber das Verdilnnungsgesetz der Elelctrolyte.) [Inorganic]
Meas. W. Storer; see 494.
1676. F. StrauB, O. Bcker. Ber. Deutsch. Chem. Ges. 39, 2977-3006, (1906).
Ueber Dibenzalaceton und Triphenylmethan.
T=0^
1676a. W. Strecker. Ber. Deutsch. Chem. Ges. 43, 1131-1144, (1910).
Einwirkimg von Organomagneeiumverbindimgen auf Bortrichlorid, Chlor-
schwefel, sowie auf das Chlorid und die E^ter der schwefligen S&ure.
T»25®.
1677. (F. Streintz. Ann. Physik. (4), 3, 1-19, (1900).
Ueber die elektrische Leitf&higkeit von gepressten Pulveni.) [Inorganic.
Same as 1679.]
1678. (F. Streintz. Ann. Physik. (4), 9, 854-885, (1902).
Ueber die elektrische Leitf&higkeit von gepressten Pulvem.) [Same as 1680.
Inorganic. ]
1679. (F. Streintz. Sitzber. Akad. Wien. 109, 2a, 221-241, (1900).
Ueber die elektrische, etc.) [Same as 1677].
1680. (F. Streintz. Sitzber. Akad. Wien. Ill, 2a, 345^78, (1902).
Ueber die elektrische, etc.) [Same as 1678.]
1681. (N. Strindberg. Zeit. Phys. Chem. 14, 161-162, (1894).
Ueber die Aenderung der Leitf&higkeit einer Ldsung durch Zusatz von kleinen
Mengen eines Nichtleiters.) [Inorganic]
1662. D. StrOmhoim. Ber. Deutsch. Chem. Ges. 32, 2892-2911, (1899).
Ueber Di&thylendisulfidthetin.
B. C. Stuer see A. Hantzsch.
J. J. Sudborough see W. A. Bone.
AUTHOR LIST 616
1683. J. J. Sudbonmgh, D. J. Roberts. Jour. Chem. Soc. 87, 1840-1854,
(1905).
Esterification constants of substituted acrylic acids. Part I. [Quoted from
1209.1
H. Siiss is same as J. H. Siiss.
1684. J. H. Siiss. Monatsh. 26, 1331-1342, (1905).
Leitf&higkeitsmessungen an organischen Sauren. [Same as 1685.]
R. O.
1685. J. H. Siiss. Sitzber. Akad. Wien. 114, 2b, 867-878, (1905).
Leitf&higkeitsmessungen an organischen Sauren. [Same as 1684. 1
ilfeod. [J.] H. Sass; see 1906, 1934, 1986.
1686. O. Sole. Zeit. Phys. Chem. 32, 625-629, (1900).
Leitf&higkeit einiger natriumsubstituierter Nitroparaffine.
T=25*. X aq. about 2Xl0-«; not sub.
1687. £. C. Sullivan. Zeit. Phys. Chem. 28, 523-545, (1899).
Studien tkber einige Jodverbingungen.
T=25^
E. Sunde see H. Goldschmidt
1687a. (A. F. Sundell. Zeit. Phys. Chem. 70, 539-550, (1910).
Elektrolysen betraktad ur energetisk synpunkt.)
1688. (W. Sutherland. Phil. Mag. (6), 3, 161-177, (1902).
Ionization, ionic velocities, and atomic sizes.) [Quoted. ]
1689. (W. Sutherland. Phil. Mag. (6), 14, 1-35, (1907).
Ionization in solutions and two new types of viscosity.) [Quoted.]
1690. F. Swarts. Rec. Trav. Chim. 25, 244r-252, (1906).
Sur Tacide difluorchlorac^tique. [Same as 1699.]
T=25^
1691. F. Swarts. Zeit. Phys. Chem. 16, 118-124, (1895).
Einige Betrachtungen tlber elektrische Leitfahigkeitskurven. [Qualitative.]
1692. (F. Swarts. Bui. Acad. Belg. (3), 28, 130-131, (1894).
Sur la conductibilit^ ^lectrique de Tacide dichlorfluorac6tique.)
[Published in full in 1700.]
1693. F. Swarts. Bui. Acad. Belg. (3), 31, 675-688, (1896).
Sur I'acide fluorac6tique.
S. U. xaq. = 1.5X10-*.
1694. F. Swarts. Bui. Acad. Belg. (3), 35, 849^868, (1898).
Sur Tacide dibromfluorac6tique.
T =25.1^ and 25.2^ S. U.
1696. F. Swarts. Bui. Acad. Belg. (1902), 731-760.
Sur Talcool bifluor^.
S.U.
1696. F. Swarts. Bui. Acad. Bdg. (1903), 597-633.
Sur Tacide difluorac^tique.
T=25^ R. O.
1697. F. Swarts. Bui. Acad. Belg. (1904), 762-801.
Sur quelques amines k radical aloooUque fluor^.
[T probably 25^] R. O. x aq. =2X10-^; sub.
1698. F. Swarts. Bui. Acad. Belg. (1904), 955-^9.
Sur quelques amines k radical alcoolique fluor6.
[No data of T nor of unit, but see 1697.]
1699. F. Swarts. Bui. Acad. Belg. (1906), 42-51.
Sur Tacide difluorchlorac6tique. [Same as 1690.]
T=25^
616 AUTHOR LIST
1700. F. Swarts. M6m. Acad. Belg. 51, M6m. 3. (1894r-1895).
Sur la conductibilit^ ^lectrique de Tacide dichlorfluorao^tique. [Abstract in
1692 is qualitative.]
T is about 26^ 8. U. x aq. = 1.49 -1.6 XlO-«.
1701. F. Swarts. M6in. Acad. Belg. 54, M6m. 2, (1896).
Sur I'acide fluorchlorbromac6tique.
T=25^ S. U. xaq. = 1.9X10-*.
R. Swinne see P. Walden.
1702. E. C. Szarvasy. Jour. Chem. Soc. 77, 603-608, (1900).
Electrolysis of the nitrogen hydrides and of hydroxylamine.
1703. B. Szyszkowski. Jour. Russ. Phys.-chem. Soc. 28, 664-683, (1896).
The question of the dissociation constants of organic acids. [Same as
1704.]
T=25^
1704. B. Szyszkowski. Zeit. Phys. Chem. 22, 173-188, (1897).
Ueber die Affinit&tsgrdssen organischer S&uren und ihre Beziehungen zur
Konstitution derselben. [Same as 1708.]
T=25^
1706. B. ▼. Szysdcowski. Zeit. Phys. Chem. 58, 420-424, (1907).
Beitrag zur Kenntnis der Neutralsalzwirkung. [Indicators. ]
1706a. B. ▼. Szyazkowaki. Zeit. Phys. Chem. 73, 269-283, (1910).
Ueber das Wesen der Neutralsalzwirkung. [Indicators.]
Mea8, B. Szyszkowski; see 1034, 1474.
1706. B. Szyszkowski, S. Reformatsky. Jour. Russ. Phys.-chem. Soc. 33,
168-163, (1901).
Synthesis and properties of a-dimethyl-/3-ethylethylenelactic acid.
T.
1707. J. Tafel, J. Dodt Ber. Deutsch. Chem. Ges. 40, 3757-3759, (1907).
Acidit&t der Desoxyxanthine.
T=25^
1708. G. Tammann. Ann. Physik. (3), 69, 767-780, (1899).
Ueber die Abh&ngigkeit des elektrischen Leitvermdgens vom Druck.
T=0^to40^
1708a. G. Tammann. Zeit. Elektrochem. 16, 592-599, (1910).
Ueber den Einfluss des Druckes auf das elektrisohe Leitvermdgen von Ldsun-
gen.
T=0^
1709. G. Tammann. Zeit. Phys. Chem. 6, 237-240, (1890).
Ueber das Leitvermdgen von Niederschlagmembranen.
T = 18.5^
1710. (G. Tammann. Zeit. Phys. Chem. 17, 725-736, (1895).
Ueber den Einfluss des Drucks auf das elektrische Leitvermogen von L58un-
gen.) [Quoted. ]
G. Tammann see A. Bogojawlensky.
1711. S. M. Tanatar, E. K. Kurovskij. Jour. Russ. Phys.-cfaem. Soc. 39,
936-943, (1907).
Some salts of beryllium and zirconium. [The existence of many of these salts
is denied by Parsons, Sajrgent, Jour. Am. Chem. Soc. 31, 1202, (1909).]
1712. S. M. Tanatar, £. K. Kurovskij. Jour. Russ. Ph3rs.-chem. Soc. 39,
1630-1632, (1907).
Benzoyl salts of beryllium and zirconium. [See criticism under 1711.]
AUTHOR LIST 617
1718. B. Tarugi, G. TomasinellL Arch. Fisiol. 5, 581-590, (1908).
Costanti fisico-chimiche del sudore dell'uomo ottenuto ool bagno di luce.
T=25^
M. Taylor see J. W. McBain.
W. W. Taylor see C. Ranken.
1714. (S. Tereschin. Verhand. Deutsch. Phys. Ges. 11, 211-214, (1909).
Ueber die Beziehung zwischen Dichte und DissoziatioiiBgrad wfisseriger
Salzlosungen.) [Quoted. A simplification of 821.]
Tessarin see Zanninoyich-Tessarin.
A. Tlial see K. A. Hofmann, H. Kinnreuther.
1716. (A. ThieL Zeit. Anoig. Chem. 59, 371-372, (1908).
Notiz betreffend die Starke der zweiten Stuf e von Phenolcarbon- und Phenol-
sulfons&uren.) [Criticism of 1346. See 1718 for measurements.]
1716. (A. ThieL Zeit. Elektrochem. 15, 1-1, (1909).
Ueber das Leitf&higkeitsminimum in der Titrationskurve mittelstarker und
schwacher Sauren.) [Theoretical. See 294 and 296.]
1717. A. Thiel, H. Roemer. Zeit. Phys. Chem. 61, 114-126, (1907-
1908).
Ein Beitrag zur Kenntnis der Verteilung einer Base zwischen zwei S&uren.
T-25**. R. O.
1718. A. Thiel, H. Roemer. Zeit. Phys. Chem. 63, 711-761, (1908).
Vergleichende Untersuchungen tlber Basizit&t und St&rke von Sauren und
Phenolen. [Most is given in 1508. Some new measurements are given here.
See 1228.]
T =25**. R. O. X aq. is about 1 X 10"*.
1719. A. Thiel, A. Schumacher, H. Roemer. Ber. Deutsch. Chem. Gres. 38,
3860-3862, (1905).
Zur Kenntniss der sauren Function des aromatischen Hydroxyls. [Qualita-
tive.]
1720. J. Thiele, H. Ingle. Ann. Chemie. 287, 23^265, (1895). Meas. M.
Bauer.
Ueber einige Derivate des Tetrazols.
T=25^
1721. O. Thiele. Zeit. Physiol. Chem. 37, 251-301, (1902-1903).
Ud>er Uroferrins&ure. [Qualitative.]
N. G. Thomas see H. Hartley.
M. deK. Thompson see H. M. Goodwin.
1722. (J. J. Thomson. Jour. Phys. (3), 5, 165-167, (1896).
D^harge de I'^lectricit^ produite par les rayons de Rdntgen, efifets produits
par ces rayons sur les di^lectriques qu'ils traversent.) [Same as 1723.]
1728. (J. J. Thomson. Proc. R. Soc. London. 59, 274-276, (1895-1896).
On the discharge of electricity produced by the Rdntgen rays and the effects
produced by these rays on dielectrics through which they pass.) [Same as
1722.]
J. F. Thorpe see K. Auwers.
" " see F. H. Howies.
T. Tickle see J. N. Collie.
1724. S. J. Tijmstra Bz. Zeit. Phys. Chem. 49, 345-367, (1904).
Leitfahigkeitsbestimmungen an Ldeungen von Natrium in absoluten und mit
Wasser verdtlnnten Alkoholen und in Gemischen von zwei Alkoholen. [Part
is same as 1726. Propyl alcohol and mixtures of ethyl and methyl alcohols
are also given here. ]
T = 18^ R. O. xaq. = 1.3XlO-«.
518 AU;rHOR LIST
17S5. S.Tijm8traBz. VenlagAkad. Amsterdam, 12, 166-169,(1903-1904).
Verslag Akad. Amsterdam, English translation, 6, 104-107, (1903-
1904).
De electrolytische geleidbaarheid van oplossingen an natrium in mengsels van
aethyl of methylalcohol+ water. [Given in 1724.]
T = 18^
Timof^eflf see Timofejev.
1726. (V. F. TImofejev. Jour. Russ. Phys.-chem. Soc. 41, 241-244, (1909).
MendelejefiF number.
The influence of the functional distinctions of the ingredients of the solution
on the curve of the solution.)
1727. (V. F. TimofejeVy L. D. Kobozev. Jour. Russ. Phys.-chem. Soc. 36,
265-276, (1904).
Decomposition of trichloroacetic acid and some of its salts in aqueous solution.)
[Velocity of reaction. ]
1728. A. Tingle. Jour. Am. Chem. Soc. 21, 792-803, (1899).
The influence of substituents on the electrical conductivity of benzoic
acid.
T = 25*. Hg. U. Mean x aq. = 4.4 X 10-*; sub.
Meas. L Ti&£enko; see 1760a.
1729. A. W. Titherley. Jour. Chem. Soc. 79, 391-411, (1901). Meas, W.
B, Davidson.
Preparation of substituted amides from the corresponding sodamides.
T=26^
1729a. H. T. Tizard. Jour. Chem. Soc. 97, 2477-2490, (1910).
The colour changes of methyl-orange and methyl-red in acid solution, [k is
given in 1729c.]
T = 18" and 25^ kwXlO"=0.6 at 18**; -1.1 at 25^
1729b. H. T. Tizard. Jour. Chem. Soc. 97, 2490-2495, (1910).
The hydrolysis of aniline salts measured colourimetrically.
T=25^ kwXlO" = l.lat25^
1729c. H. T. Tizard. Proc. Chem. Soc. 26, 225, (1910).
The colour changes, etc. [Given in 1729a.]
H. T. Tizard see N. V. Sidgwick.
G. Tomasinelli see B. TanigL
G. Tommasi see N. Parravano.
1780. H. A. Torrey, W. MacPherson. Jour. Am. Chem. Soc. 31, 579-^583,
(1909).
Some azo dyes from p-aminoacetophenone.
1781. M. TorteUi. Ber. Deutsch. Chem. Ges. 28, 1702-1707, (1895).
Zur Constitution der Fuchsine. [Text an abridgement of 1782, but has fuU
tables of A. ]
1782. M. TorteUi. Gaz. Chim. Ital. 25, n, 233-248, (1895).
Sulla costituzione delle fucsine. [Same as 1781.]
1788. N. E. Tousley, M. Gomberg. Jour. Am. Chem. Soc. 26, 1516-1523,
(1904).
Some tri-i>-tolylmethane derivatives.
T=20^
1784. O. F. Tower. Jour. Am. Chem. Soc. 22, 501-i521, (1900).
The precipitation of the sulphides of nickel and cobalt in an alkaline tartrate
solution, together with an investigation into the nature of certain tartrates
of these metals. [The measurements in 1785 are more accurate.]
T-18^ R. O.
AUTHOR LIST 619
1786. O. F. Tower. Jour. Am. Chem. Soc. 24, 1012-1023, (1902).
On the constitution of certain organic salts of nickel and cobaJt as they exist
in aqueous solutions. [Also corrects 1734.]
T = 18^*0.1^ R. O. xaq.=2.0-3.0XlO-«; sub.
1786. O. F. Tower. Jour. Am. Chem. Soc. 27, 386-391, (1905).
Note on the constitution of certain organic salts of nickel and cobalt as they
exist in aqueous solution.
T - 18*. R. O. X aq. « 1.8 X 10-«; sub.
1787. O. F. Tower. Zeit. Phys. Chem. 18, 17-60, (1895).
Studien tiber Superoxyd-Elektroden.
T-16^
*1788. (I. Traube. Ber. Deutsch. Chem. Ges. 42, 86-94, (1909).
Ueber den Haftdruck. Beitrag zur Theorie der Ldsungen.) [Summary of
1789.]
n789. (I. Traube. Verhand. Deutsch. Phys. Ges. 10, 880^30, (1908).
Der Haftdruck. Beitrag sur Theorie der Ldsimgen.) [Summary with data
in 1788.]
1740. (J. Traube. Ann. Physik. (3), 62, 490-606, (1897).
Ueber osmotischen Druck und electrolytische Dissociation.) [Theoretical.]
1741. J. Traube. Ber. Deutsch. Chem. Ges. 24, 1859-1864, (1891).
Zur Dissociationshypothese. Ueber elektrisches Leitungsvermogen und Ge-
frierpunkt.
T = 15'*andl8^ Hg. U. x aq. sub.
1742. (J. Traube. Ber. Deutsch. Chem. Ges. 25, 2989-2993, (1892).
Die Hypothesen der elektrolytischen Dissociation und der Jonisation.)
1748. (J. Traube. Chem. Ztg. 26, 2, 1071-1074, (1902).
Ud>er die modemen Ldsimgstheorien. Die osmotische Theorie und die elek-
trolytische Dissociationstheorie.)
1744. (J. Thiube. Phil. Mag. (6), 8, 158-165, (1904).
A theory of solutions.)
1746. J. B. Trevor. Zeit. Phys. Chem. 10, 321<^53, (1892).
Ueber die Messimg kleiner Dissociationsgrade.
1746. H. Trey. Zeit. Phys. Chem. 22, 424-463, (1897).
Ein weiterer Beitrag zur Birotation der Glykose.
T=25°. S. U. Xj6 aq.=2X10-*; sub.
1747. H. Trey. Zeit. Phys. Chem. 46, 620-719, (1903).
Ein Beitrag zu den Rotationserscheinungen der Laktose.
T=25^ S. U.
1748. P. A. TrUbsbach. Zeit. Phys. Chem. 16, 708-728, (1895).
Die Ajffinit&tsgrdssen der Ureide und Isonitrosoderivate.
T — 25^. X aq. s 1.5—2.5 X 10~^; sub. for some compounds; no statement
in other cases.
1749. P. Trummel. Dis. Bonn. (1908). Meas, with A, Schubert.
Beitrage zur Kenntnis der Konstitution der Citraconsaure und ihrer Homo-
logon.
R. O. X aq. less than 2X10~^; sub.
1750. L. Tscfaugaeff. Ber. Deutsch. Chem. Ges. 38, 289^2914, (1905).
Ueber complexe Verbindungen organischer Imide. Succinimidkupfer-Deri-
vate.
T=25^
1761. L. Tschugaeflf. Ber. Deutsch. Chem. Ges. 39, 2692-2702, (1906).
Uel>er Kobaltidioximine.
T=25^
* I. Traube is the same name as J. Traube.
620 AUTHOR LIST
1752. L. TsdiiigaeflF. Ber. Deutech. Chem. Gee. 39, 3100-^201, (1906).
Ueber oomplexe Verbindungen organische Imide; Succinimidiiickel-Derivate.
[Part bin 1758.]
T«26^
1753. L. Tschugaeflf. Ber. Deutsch. Chem. Ges. 40, 3498-3504, (1907).
Ueber Kobalti-dioxinime. [Given in 1759.]
T-26^
1754. L. Tschiigaeflf. Ber. Deutech. Chem. Ges. 41, 2226-2232, (1908).
Meas. E, Siller.
Ueber eine neue Komplexs&ure. (Studien Qber Kobaltidioximine III). [Same
afl 1760.]
T=25".
1755. L. A. Tschiigaeflf. Jour. Rusb. Phys.-chem. Soc. 39, 1262-1323,
(1907).
Investigations in the sphere of complex compounds. I. Complex compounds
of organic imides.
T-25^
1756. L. A. Tschttgaeff. Jour. Russ. Phy8.-chem. Soc. 41, 285-286, (1909).
Mendelejeff number.
A new series of complex acids.
T-25^
1757. L. A. Tschogaeff. Jour. Russ. Phys.-chem. Soc. 41, 184-252, (1909).
Investigations in the sphere of complex compounds. III. Metallic derivatives
of Ordioximes.
T=25^
1758. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 253-287,
(1909).
Investigations in the sphere of complex compoimds. IV. On the conditions
of formation of complex compounds of the metal-ammonia type. [Given in
1752.]
T=25^
1759. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 1332-1354,
(1909).
Investigations in the sphere of complex compounds. V. The non-ionized
cobalt dioximines. [Part is same as 1753.]
T=25^
1760. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 41, 1355-1368,
(1909). Meaa. E, Siller.
Investigations in the sphere of complex compounds. VI. A new series of
complex acids. [Same as 1754.]
T=25^
1760a. L. A. Tschugaeff. Jour. Russ. Phys.-chem. Soc. 42, 1466-1487,
(1910). Meas. A. Pastinkav and I. Ti&enko.
Investigations in the sphere of complex compounds. VII. On some complexes
made from dioximines.
T=26^
1761. L. Tschugaeff. Zeit. Anoig. Chem. 46, 144-169, (1905).
Ueber komplexe Verbindungen der a^Dioxime.
T-25^
1762. L. Tschugaeff, W. Sokoloff. Ber. Deutsch. Chem. Ges. 40, 3461-
3465, (1907).
Ueber einige Komplexverbindungen des optisch-aktiven 1-Propylendiamins.
T=25°.
AUTHOR LIST 621
1763. C. Tubandt Ann. Chemie. 339, 41-03, (1905).
Quantitative Bestimmung des Natriumalkoholats mit Menthon. [Given in
1766.1
T=25^ xaq.=3.7Xl(H.
1764. (C. Tubandt Ann. Chemie. 354, 259-324, (1907).
Zur Kenntniss der Reactionskinetik in nichtw&asrigen Ldsungen.) [Inversion
of menthone by alcohols and acids. Given in 1766.]
1765. C. Tubandt Dis. HaUe. (1904).
Die Inversionsgeschwindigkeit des Menthons. [Same as 1768 and 1764
together. ]
1766. B. B. Tomer. Am. Chem. Jour. 40, 559-574, (1908).
The limiting conductivity and degree of ionisation of alcoholic solutions.
T=0^to50^ R. O.
1767. D. Turner. Nature. 60, 245, (1899).
The electrical resistance of the blood. [Abstract of 1760.]
T=60**F. [ = 15.6^]
1768. D. Turner. Nature. 66, 127, (1902).
The electrical resistance of the blood.
1769. D. Turner. Trans. R. Scot. Soc. 16, 6-7, (1906).
On an apparatus for measining the electrical resistance of the blood, with
some deductions therefrom. [Abstract is given in 1767.]
T«60*»F. [ = 15.6**].
W. E. S. Turner see A. FSndlay.
Tymstra see Ti jmstra.
U.
Meas. Udby; see 664.
B. td Ugglas see H. Buler.
Mea8. H. T. Upson; see 1660.
H. T. Upson see J. Stieglitz.
A. Usoff see G. Bredig.
V.
A. Vagt see A. Hantzsch.
1770. P. Vaillant Compt. Rend. 137, 84^-851, (1903).
Sur la couleur des solutions aqueuses de m^thylorange et le changement qu'y
d^terminent les acides.
T=25®.
1771. C. Valine. Ann. Chim. Phys. (8), 15, 331-432, (1908).
Recherches sur les isocyanates de ph^nyle, de naphtyle et de menthyle.
van see the letter beginning the next word, as under de.
1772. W. R. Veazey. Dis. Johns Hopkins. (1907).
The conductivity and viscosity of solutions of certain salts in water, methyl
alcohol, ethyl alcohol, acetone and binary mixtures of these solvents. [Same
as 982.]
T=0*and25*. S. U. x aq. is about lXlO-«.
W. R. Veazey see H. C. Jones.
A. V. Vegesack see W. Biltz.
A. Veit see A. Hantzsch.
1778. V. H. Veley. Jour. Chem. Soc. 91, 153-175, (1907).
The affinity constants of aminocarboxylic and aminosulphonic acids as de-
termined by the aid of methyl-orange. [See 1781 for method. Gives only
relative values. Abstract in 1788.]
622 AUTHOR LIST
1774. V. H, Veley. Jour. Chem. Soc. 91, 1246-1251, (1907).
The affinity constants of aminosulphonic acids as determined by the aid of
methyl-orange. [Gives only relative values. Abstract given in 1794. ]
1775. y. H. Veley. Jour. Chem. Soc. 93, 662-666, (1908).
The affinity constants of bases as determined by the aid of methyl-orange.
T = 12°to 18^
1776. V. H. Veley. Jour. Chem. Soc. 93, 2114r-2122, (1908).
The affinity of certain alkaloids for hydrochloric acid. [Summary in 1787 is
qualitative. ]
T = 10" to 20^
1777. V. H. Veley. Jour. Chem. Soc. 93, 2122-2144, (1908).
The affinity constants of bases as determined by the aid of methyl-orange.
T = 10** to 20**.
1778. V. H. Veley. Jour. Chem. Soc. 95, 1-8, (1909).
The affinity values of tropine and its derivatives. [Abstract in 1789 has some
data.]
T = 14** to 18^
1779. V. H. Veley. Jour. Chem. Soc. 95, 758-767, (1909).
The affinity values of certain alkaloids. [Summary given in 1790.]
T = 15**to20^
1780. (V. H. Veley. Phfl. Mag. (6), 11, 73^1, (1906).
A modified form of apparatus for the determination of the dielectric constants
of non-conducting liquids.)
1781. V. H. Veley. Zeit. Phys. Chem. 57, 147-167, (1906).
Ueber die Reaktionen zwischen S&uren und Methylorange.
1782. (V. H. Veley. Zeit. Phys. Chem. 61, 464-467, (1907-1908).
Ueber die Reaktionen swischen S&uren und Methylorange.)
1783. (V. H. Veley. Proc. Chem. Soc. 22, 31^-314, (1906).
The affinity constants of aminocarboxylic and aminosulphonic acids as de-
termined by the aid of methyl-orange.) [No data. See 1773.]
1784. (V. H. Veley. Proc. Chem. Soc. 23, 179-180, (1907).
The affinity values of aminosulphonic acids, etc.) [An abstract of 1774.]
1785. (V. H. Veley. Proc. Chem. Soc. 23, 284-285, (1907).
The affinity constants of bases as determined by the aid of methyl-orange.)
1786. (V. H. Veley. Proc. Chem. Soc. 24, 50, (1908).
The affinity constants of bases as determined by the aid of methyl-orange.)
[Qualitative. A summary of 1775. ]
1787. (V. H.;Veley. Proc. Chem. Soc. 24, 234-235, (1908).
The affinity of certain alkaloids for hydrochloric acid.) [Summary of 1776. ]
1788. (V. H. Veley. Proc. Chem. Soc. 24, 238, (1908).
The affinity constants of bases as determined by the aid of methyl-orange.)
[Summary of 1777.]
1789. V. H. Veley. Proc. Chem. Soc. 24, 280-281, (1908).
The affinity values of tropine and its derivatives. [Summary of 1778 with
some data. ]
1790. V. H. Veley. Proc. Chem. Soc. 25, 115-116, (1909).
The affinity values of certain alkaloids. [Summary of 1779.]
1791. A. Vesterberg. Arkiv Eemi. 2, no. 37, 1-18, (1905-1907).
Fdrsdk dfver hydrolys af Salter i vattenhaltig alkohol.
T = 18^
1792. (G. Vicentini. Atti Accad. Torino. 19, 832 and 897-^98, (1883-1884).
Sulla conducibilitjl elettrica delle soluzioni alcooliche di alcuni cloruri.) [In-
organic. A summary of 1794. ]
AUTHOR LIST 628
1798. (G. Vicentiiii. . Atti Accad. Torino. 20, 869-895, (1884-1885).
Sulla oonducibilitil dettrica dei sail in soluzioni acquose molto diluite.) [In-
organic. ]
1794. (G. Vicentini. Mem. Accad. Torino. (2), 36, 385-404, (1885).
Sulla conducibilitil elettrica delle soluzioni alcooliche di alcuni cloruri.) [In-
organic. Summary given in 1792. ]
1795. (G. Vicentini. Atti 1st. Veneto. (6), 2, 1699-1726, (1883-1884).
Sulla conducibilitd. elettrica delle soluzioni saline acquose molto diluite.) [In-
organic]
1796. L. Vignon. Bui. Soc. Chim. (4), 1, 273-279, (1907).
Teinture et ionisation. [Same as 1799 and 1800a for A, but also gives x. ]
T = 18**to90^ Legal ohms.
1797. L. Vignon. Bui. Soc. Chim. (4), 5, 492-495, (1909).
Sur les propri^t63 colorantes et tinctoriales de I'acide picrique. [Same as 1800
T = 18^ 70** and 80^ and 1800c. ]
1798. L. Vignon. Bui. Soc. Chim. (4), 5, 495^500, (1909).
Conductibilit^ ^lectrique de certains bains de teinture. [Same as 1800b.]
T = 15°tol00°.
1799. L. Vignon. Compt. Rend. 144, 81-83, (1907).
Teinture et ionisation. [Same as 1796 for A. Same as 1800a.]
1800. L. Vignon. Compt. Rend. 148, 844-846, (1909).
Sur les propri6t6s colorantes, etc. [Same as 1797 and 1800c.]
1801. L. Vignon, £. £vieux. Bui. Soc. Chim. (4), 3, 1012-1019, (1908).
Chaleur de neutralisation de Tacide ac^tique et de I'acide benzolque par Fani-
line en milieu benzdnique. [Part is same as 1803. Salts of toluidines are also
given here. ]
1802. L. ^^gnon, £. £vieux. Bui. Soc. Chim. (4), 3, 1019-1030, (1908).
Chaleur de neutralisation de Tacide picrique par diverses bases aromatiques
en milieu benz^nique. [Part is same as 1804.]
1803. L. Vignon, £. Evieux. Compt. Rend. 146, 1316-1318, (1908).
Chaleur de neutralisation de Tacide ac^tique, etc. [Given in 1801.]
1804. L. Vignon, £. fivieux. Compt. Rend. 147, 67-70, (1908).
Chaleur de neutralisation de Tacide picrique, etc. [Given in 1802.]
1806. £. Villari. Nature. 56, 91, (1897).
Influence of Rdntgen rays upon electrical conductivity.
V. Villiger see A. Baeyer.
1806. G. Vind. Arch. Fisiol. 6, 41-56, (1909).
Contributo alia conoscenza della linfogenesi. I. Sulle propriety fisico-chimiche
deUa linfa della linforrea sperimentale.
T«25^
£. Voegelen see A. Hantzsch.
1807. B. V6Umer. Ann. Physik. (3), 52, 328-^6, (1894).
Die electrische Leitfahigkeit von einigen Salzen in Aethyl- und Methylalkohol.
[This is 1808 with additions.]
T = 10% 18''and26^ S. U.
1808. B. Vmimer. Dis. Halle. (1892).
Die molekulare elektrische Leitfahigkeit von einigen alkoholischen Ldsungen.
[Original not examined by me. This title is from an abstract in Zeit. Phys.
Chem. 10, 668-669, (1892). See 1807.]
1809. B. VOUmer. Festschr. Halle. (1898).
Das dektroljrtische Verhalten einiger Losungen von essigsaurem Kali in
Essigsaure. [Original not examined by me. This title is from an abstract in
Zeit. Phys. Chem. 29, 187, (1899).]
T-20*and30^
524 AUTHOR LIST
1810. G. L. VoemiAii. Rec. Trav. Chim. 23, 265-;»2, (1904).
Recherches sur quelques anhydrides d'acides bibasiques satur^s, en connexion
avec la th^orie de tension de v. Baeyer. [Probably same as 1812a of which it
is an extract. ]
T«25^ R. O. X28aq. = 1.6Xl(H; notsub.
1811. G. L. VoennAn. Rec. Trav. Chim. 26, 293-310, (1907).
Sur les acides monocarboniques du thioph^ne. [Same as 1812 for ci-acid, but
gives also a table of A for j3-acid. ]
T=25**? R. O. X aq. less than 2Xl0-«.
1812. G. L. Voeiman. Verslag Akad. Amsterdam, 15, 545-555, (1906-
1907). Verslag Akad. Amsterdam, English translation, 9, 514-524.
(1906-1907).
Het a- en het jS-thiopheenzuur. [Indexed as Holleman, Voerman. Same as
1811 fork.]
1812a. G. L. Voerman. Dis. Groningen. (1904). [Not examined by me.
See 1810.]
IMeas. G. L. Voefman; see 846.
von see under the letter beginning the next word, as under de.
1813. D. Vorlltnder. Ann. Chemie. 320, 66-98, (1902). Meas. Meusd.
Kohlenstoffdoppelbindung und Carbonyl. [Given in 1246.]
T=25^ R. O. xaq.=2.6XlO-«.
1814. D. Vorlltnder. Ber. Deutsch. Chem. Ges. 35, 1683-1698, (1902).
Indoxylbildung aus Phenylglycin-o-carbons&ure. [These measurements were
apparently made by Meusel. See 1246 for tables of A and k.]
T=25^
1816. D. Vorlltnder. Ber. Deutsch. Chem. Ges. 36, 26^-281, (1903). Meca.
E. Mumme.
Die sauren Eigenschaften des Malonsftureesters.
T=25^ xaq.=2.8X10-«.
D. Voriftnder see R. v. Schilling.
1816. D. VorUlnder, F. Kalkow. Ann. Chemie. 309, 356^74, (1899).
Die Formaldehydverbindung des Hydroresorcins. [Qualitative.]
1817. D. Vorlltnder, £. Mumme. Ber. Deutsch. Chem. Ges. 33, 3182-3183,
(1900).
Ueber Anildiessig-o-carbonsfture. [Qualitative. For tables of A and k see
1246. Same as 1801.]
W.
1818. P.Waentig. Zeit.Phys. Chem. 68,513-571, (1909). Meas. Hermdorf.
Ueber den Zustand des geldsten Jods.
T=20^
P. Waentig see £. Beckmann.
1819. J. Wagner. Zeit. Phys. Chem. 12, 314r-321, (1893).
Ueber die Farbe der lonen. [Qualitative. ]
1820. A. J. Wakeman. Zeit. Phys. Chem. 11, 49-74, (1893).
Das Verhalten einiger Elektrolyte in nichthomogenem Ldsungsmittel.
1821. A. J. Wakeman. Zeit. Phys. Chem. 15, 159-182, (1894).
Ueber die Beeinflussung der Molekular-Leitf&bigkeit der Essigs&ure durch
kleine Mengen anderer elektroljrtischer Substanzen. Anwendung der Theorie
der isohydrischen Ldsungen. [Same as 1822.]
1822. A. J. Wakeman. Dis. Leipzig. (1894).
Ueber die Beeinflussung, etc. [Same as 1821.]
Meas, A. Wakeman; see 1904.
AUTHOR LIST 626
1825. P. Walden. Ber. Deutsch. Chem. Gee. 24, 2025-2039, (1891).
Zur Eenntniss der Tetiina&ure, Oxytetrins&ure und ihrer Homologen. [Given
in 1881.]
T=26^
1824. P. Walden. Ber. Deutsch. Chem. Ges. 29, 1692-1707, (1896).
Zur Charakteristik optisch-isomerer Verbindungen.
1826. P. Walden. Ber. Deutsch. Chem. Ges. 31, 3167-^174, (1898).
Ueber die vermeintliche Identit&t des Tannins mit der o^Digallussaure.
T=25^
1826. P. Walden. Ber. Deutsch. Chem. Ges. 32, 2862-2871, (1899).
Ueber ein neues, anorganisches, ionisirendes Losungsmittel. [Given more
accurately in 1855.]
T=0^
1827. P. Walden. Ber. Deutsch. Chem. Ges. 34, 4185-4202, (1901).
Ueber die basischen Eigenschaften des Sauerstoffes.
T-0''and26^ x aq.=3.46XlO-«.
1828. P. Walden. Ber. Deutsch. Chem. Ges. 35, 1764-1772, (1902).
Ueber den mehrwerthigen Sauerstoff .
T=0**and25^ R. O.
1829. P. Walden. Ber. Deutsch. Chem. Gee. 35, 2018-2031, (1902).
Ueber die basischen Eigenschaften des Kohlenstoffs.
T=0^ R. O.
1880. P. Walden. Ber. Deutsch. Chem. Ges. 38, 345-409, (1905).
Ueber das Drehungsvermdgen optisch-activer Edrper.
T=26^ R. O.
1831. P. Walden. Jour. Russ. Phys.-chem. Soc. 23, 632-652, (1891).
The question of the structure of DemarQay's adds. [Same as 1823 with a few
additions. ]
1832. P. Walden. Zeit. Anorg. Chem. 23, 373-377, (1900). ^Mecw. [J.]
V. Zawidzki,
Ueber einige zusammengesetzte Rhodan- und Cyanverbindungen.
T=25^
1838. P. Walden. Zeit. Anorg. Chem. 25, 209-226, (1900).
Ueber einige anorganische Losungs- und lonisierungsmittel.
T=25^and0*.
1834. P. Walden. Zeit. Anorg. Chem. 29, 371-395, (1902).
Ueber anorganische Losungs- und lonisierungsmittel.
T = 25'' and 33'. [Probably R. 0. ]
1885. (P. Walden. Zeit. Elektrochem. 14, 713-724, (1908).
Ueber die Schmelzw&nne, spezifische Kohasion und MolekulargrOsse bei der
Schmelztemperatur.)
1886. P. Walden. Zeit. Phys. Chem. 1, 529-549, (1887).
Ueber die Bestimmung der MolekulargrSssen von Salzen aus der elektrischen
Leitf&higkeit ihrer wftsserigen Ldsungen.
T-25^ Hg. U.
1887. P. Walden. Zeit. Phys. Chem. 2, 49-77, (1888).
Ueber die Bestinmiimg der Molekulargr68sen von Salzen aus der elektnschen
Leitfahigkeit ihrer wasserigen Ldsungen.
T-25^
1888. P. Walden. Zeit. Phys. Chem. 8, 433-503, (1891). [fliMeas. U.
CoUan. See 826.]
Ueber die Affinitatsgrdssen organischer S&uren und ihre Beziehungen zur
Konstitution derselben.
T =25^. S. U. aq. very well purified.
626 AUTHOR LIST
1889. P. WaldeiL Zeit. Phys. Chem. 10, 56^-579, (1802).
Ueber die Affinitfttsgrossen organischer Saiiren und ihre Beziehungen zur
Konstitution derselben. II. Teil; Trikarbons&uren. [Continuation of 1888. ]
1840. P. Walden. Zeit. Phys. Chem. 10, 638-664, (1892).
Ueber die Affinitatsgrossen organischer S&uren und ihre Beziehungen zur Kon-
stitution derselben. III. Teil; Monokarbonsauren. [Continuation of 1889. ]
1841. P. Walden. Zeit. Phys. Chem. 15, 196-208, (1894).
Ueber die optische Drehung der lonen.
T=26**.
1842. P. Walden. Zeit. Phys. Chem. 43, 385-464, (1903).
Ueber abnorme Elektrolyte.
T«-10^0^and25^ R. O.
1848. P. Walden. Zeit. Phys. Chem. 46, 103-188, (1903). »Mea8,
Centnerszwer,
Ueber organische Ldsungs- und lonisierungsmittel. I.
T«0^and25^ R. O.
1844. P. Walden. Zeit. Phys. Chem. 54, 129-230, (1906).
Ueber organische Ldsimgs- und lonisierungsmittel. II. Teil. Messungen der
elektrischen Leitf&higkeit.
T=0°to25^ R. O.
1846. P. Walden. Zeit. Phys. Chem. 55, 207-249, (1906).
Ueber organische Ldsungs- und lonisienmgsmittel. III. Teil. Innere Reibung
und deren Zusammenhang mit dem LeitvermOgen.
T=0*'and25^ R. O.
1846. P. Walden. Zeit. Phys. Chem. 55, 281-302, (1906).
Ueber organische Ldsung&- und lonisierungsmittel. IV. Teil. Ebulliosko-
pische Messungen.
T«25*'andl30^
1847. P. Walden. Zeit. Phys. Chem. 55, 683-720, (1906).
Ueber organische Losungs- und lonisierungsmittel. V. Teil. Ldsungsvermdgen.
T=0^and25^
1848. P. Walden. Zeit. Phys. Chem. 58, 479^11, (1907).
Ueber organische L5sung&- und lonisierungsmittel. VI. Teil. Lteungsw&rmen.
T=0°and25. R. O. x solvent sub.
1849. P. Walden. Zeit. Phys. Chem. 59, 192-211, (1907).
Ueber organische LOsungs- und lonisierungsmittel. VII. Teil. Loeungs- und
Dissociationsw&rmen.
T=0^and25^
1850. (P. Walden. Zeit. Phys. Chem. 59, 385-415, (1907).
Ueber organischs Ldsungs- und lonisierungsmittel. VIII. Teil. Lichtbrech-
imgsvermdgen und elektrolytische Dissociation.) [Quoted.]
1861. P. Walden. Zeit. Phys. Chem. 60, 87-100, (1907).
Ueber organische Losungs- und lonisierungsmittel. IX. Teil. Elektrostriktion.
T=25®.
1862. (P. Walden. Zeit. Phys. Chem. 61, 633-639, (1907-1908).
Ueber organische Ldsungs- und lonisierungsmittel. X. Teil. Ldeende Kraft
und Dielektrizit&tskonstante.)
1863. (P. Walden. Zeit. Phys. Chem. 65, 129-225, (1908-1909).
Ausdehnungsmodulus, spezifische Kohasion, Oberfl&chenspannung und Mole-
kulargrdsse der Ldsungsmittel.)
1863a. P. Walden. Zeit. Phys. Chem. 73, 257-268, (1910).
Ueber die elektroljrtische Leitf&higkeit nicht^fftsseriger LQsungen bei tiefen
Temperaturen.
T« -112'' to +103**. R. 0. K solvent sub.
AUTHOR LIST 627
ISSSb. P. Walden, (R. Swinne). Zeit. Phys. Chem. 75, 555-577, (1910-
1911).
Ueber einige abnonne Temperattirkoeffizienten der molekularen Oberfl&chen-
d(7V%)
energie — -ri — von organischen Stoffen.
T=25^ R. 0.
Mea8, P. Walden; see 62, 67, 189, 190, 191, 196, 196, 197, 198, 1264,
1371, 1377.
P. Walden see C. A. Bischoif.
1863c. P. Walden. Trans. Faraday Soc. 6, 71-78, (1910).
Is water an electrolyte?
T-O** and 25**. R. O. x of solvent is sub.
1864. P. Walden, M. Centnerszwer. Zeit. Anorg. Chem. 30, 145-250,
(1902).
Flfissiges Schwefeldioxyd als Ldsungsmittel. [Same as 1866 and 1866a. More
accurate than 1826. ]
T=-74^to +175^ S. U.
1866. P. Walden, M. Centnerszwer. Zeit. Phys. Chem. 39, 513-596,
(1902).
Flilssiges Schwefeldioxyd als L5sungsmittel. [Same as 1864 and 1866a.]
T--75**to +175^ S. U.
1866. (P. Walden, M. Centnerszwer. Zeit. Phys. Chem. 42, 432-468,
(1902-1903).
Udi>er Verbindungen des Schwefeldioxyds mit Salzen.)
A. P. Walker see J. Walker.
1867. J. Walker. Ber. Deutsch. Chem. Ges. 34, 411&-4118, (1901).
Ueber Sauersto£Fbasen. [Qualitative. ]
1868. J. Walker. Chem. News. 94, 138-139, (1906). Meas. D, C. CrichUm.
A method for determining velocities of saponification. [Same as 1879.]
1869. J. Walker. Jour. Chem. Soc. 61, 696-717, (1892).
The dissociation constants of organic acids.
T»25°. X aq. compared favorably to specially prepared aq.; sub.
1860. J. Walker. Jour. Chem. Soc. 61, 1088-1096, (1892).
The methyl salts of camphoric acid. [Gives 1873 correctly.]
T=25^ xaq. sub.
1861. J. Walker. Jour. Chem. Soc. 63, 495-510, (1893).
The electrolysis of sodium ortho-ethyl camphorate. [See 1862 for correction
of part of this.]
T=25^
1862. J. Walker. Jour. Chem. Soc. 67, 347-348, (1895).
" Camphothetic " acid; a correction. [See 1861.]
1863. (J. Walker. Jour. Chem. Soc. 83, 182-184, (1903).
The state of carbon dioxide in aqueous solution.)
1864. J. Walker. Zeit. Phys. Chem. 4, 319-343, (1889).
Zur Affinitatsbestimmung organischer Basen.
T-25^
1866. J. Walker. Zeit. Phys. Chem. 32, 137-141, (1900).
Ueber die Beziehung zwischen den Dissociationskonstanten schwacher S&uren
und der Hydrolyse ihrer Alkalisalze. [Measiurements same as 1868.]
1866. J. Walker. Zeit. Phys. Chem. 46, 30^6, (1903).
The determination of avidity by the polarimetric method.
1867. (J. Walker. Zeit. Phys. Chem. 49, 82-94, (1904).
Theorie der amphoteren Elektrolyte.) [Same as 1876. Quoted. ]
628 AUTHOR LIST
1868. J. Walker. Zeit. Phys. Chem. 51, 706-716, (1905). Meas, J. John-
ston,
Theorie der amphoteren Elektrolyte. [Same as 1877.]
1869. (J. Walker. Zeit. Phys. Chem. 66, 675-576, (1906).
Bemerkung sm- Theorie der amphoteren Elektrolyte.) [Theoretical.]
1870. (J. Walker. Zeit. Phys. Chem. 67, 600-610, (1906).
Die Affinit&tskonstanten amphoterer Elektrolyte. III. Methylirte Amino-
sam^n.) [Theoretical. A summary of 416 and 890. Same as 1878.]
1871. (J. Walker. Proc. R. Soc. Edinbm^h. 20, 255-263, (1892-1895).
Hydrolysis in some aqueous salt solutions.) [Quoted.]
1872. (J. Walker. Proc. Chem. Soc. 8, 137, (1892).
The dissociation constants of organic acids.) [No data. ]
1878. J. Walker. Proc. Chem. Soc. 8, 156, (1892).
The methylic salts of camphoric acid. [Evidently intended to be same as
1860, but the names of the compounds are interchanged and kXlO* for one
is given as 9.75 instead of the correct value 7.95.]
1874. J. Walker. Proc. Chem. Soc. 10, 94-95, (1894).
Note on the constitution of glycodne. [Qualitative. ]
1876. (J. Walker. Proc. Chem. Soc. 18, 246, (1902).
State of carbon dioxide in aqueous solution.)
1876. (J. Walker. Proc. R. Soc. London. 73, 156-165, (1904).
Theory of amphoteric electrol3rte8.) [Same as 1867.]
1877. J. Walker. Proc. R. Soc. London. 74, 271-280, (1904-1905). Meas.
J. Johnston,
Theory of amphoteric electrolytes. [Same as 1868.]
1878. (J. Walker. Proc. R. Soc. London. A, 78, 140-149, (1906).
The afiSnity constants of amphoteric electrolytes. III. Methylated amino-
acids.) [Same as 1870.]
1879. J. Walker. Proc. R. Soc. London. A, 78, 157-160, (1906). Meas.
D. C. CrichUm.
A method for determining velocities of saponification. [Same as 1868.]
MeoB, J. Walker; see 44, 231, 232, 897, 898, 966, 1060, 1410, 1411, 1412, 1414.
J. Walker see A. C. Brown.
1880. J. Walker, £. Aston. Jour. Chem. Soc. 67, 676-586, (1896).
Affinity of weak bases.
T-60^
1881. (J. Walker, E. Aston. Proc. Chem. Soc. 11, 112, (1896).
Affinity of weak bases.) [No data. A summary of 1880. ]
1882. J. Walker, H. H. Beveridge. Jour. Chem. Soc. 91, 1797-1802, (1907).
para-Toluidine monohydrate.
1888. J. Walker, W. Cormack. Jour. Chem. Soc. 77, 5-21, (1900).
The dissociation constants of very weak acids. [Same measurements in
1866.]
T = 18". S. U. Xi8 aq. less than 0.65 X 10-*.
1884. J. Walker, F. J. Hambly. Jour. Chem. Soc. 71, 61-72, (1897).
Electrical conductivity of diethylammonium chloride in aqueous alcohol.
T =25**. S. U. X26 aq. - 1.5 X 10-«; sub.
1886. (J. Walker, F. J. Hambly. Proc. Chem. Soc. 12, 246, (1896).
Electrical conductivity of diethylammonium chloride in aqueous alcohol.)
[No data.]
1886. J. Walker, S. A. Kay. Jour. Chem. Soc. 71, 489-508, (1897).
Velocity of urea formation in aqueous alcohol.
T=32^
AUTHOR LIST 629
1887. J. Walker, A. J. Robertson. Proc. R. See. Edinburgh, 24, 363-^79,
(1901-1903).
Freezing-point depression in electrolytic solutions.
T-0^ S. U.
1888. J. Walker, A. P. Walker. Jour. Chem. Soc. 87, 961-M7, (1905).
Tetrethylsuccinic acid.
T=25^
1889. J. Walker, J. K. Wood. Jour. Chem. Soc. 77, 383^90, (1900).
Configuration of the camphoric acids. [Same as 1891 for k, but also gives /a. ]
T«25^
1890. J. Walker, J. K. Wood. Jour. Chem. Soc. 83, 484-491, (1903).
Hydrolysis of urea hydrochloride. [Same as 1892 for k.]
T=25^
1891. J. Walker, J. K. Wood. Proc. Chem. Soc. 16, 59-60, (1900).
The configuration of the camphoric acids. \k same as 1889.]
1892. J. Walker, J. K. Wood. Proc. Chem. Soc. 19, 67, (1903).
Hydrolysis of urea hydrochloride. [Same as 1890 for k. ]
1898. J. W. Walker. Jour. Chem. Soc. 85, 1082-1098, (1904).
lonisation and chemical combination.
T = 18^ R. O.
1894. J. W. Walker, F. M. G. Johnson. Jour. Chem. Soc. 87, 1597-1600,
(1905).
The electrical conductivities of some salt solutions in acetamide.
T « 100^
1896. (J. W. Walker, F. M. G. Johnson. Proc. Trans. R. Soc. Canada.
(2), 11, Sect. Ill, 29-30, (1905).
The electrical conductivity of salt solutions in acetamide.) [No data.]
1896. (J. W. Walker, F. M. G. Johnson. Proc. Chem. Soc. 21, 233, (1905).
The electrical conductivities of some salt solutions in acetamide.) [No data. ]
1897. J. W. Walker, f>. Mcintosh, E. H. Archibald. Jour. Chem. Soc. 85,
1098-1105, (1904).
lonisation and chemical combination in the liquefied halogen hydrides and
hydrogen sulphide. [Qualitative. ]
T« -50°, -80° and -100°.
1898. (J. W. Walker, D. Mcintosh, £. H. Archibald. Proc. Chem. Soc. 20,
134, (1904).
lonisation and chemical combination in the liquefied halogen hydrides and
hydrogen sulphide.) [No data. ]
1899. O. Wallach. Ann. Chemie. 269, 326-^347, (1892). Meaa, A, Bim.
Zur Kenntniss der Terpene und der &therischen Oele.
T = 18°. S. U.
1900. £. Warburg. Ann. Physik. (3), 54, 39(M33, (1895).
Ueber electrische Leitung und Convection in schwach leiteniden verdllnnten
Losungen.
T = 16°tol8°.
F. J. Warth see R. C. Fanner.
1901. (E. W. Washburn. Jour. Am. Chem. Soc. 31, 322-355, (1909).
The hydration of ions determined by transference experiments in the presence
of a non-electrolyte.) [Inorganic and theoretical. Same as 1902.]
1902. (E. W. Washburn. Zeit. Phys. Chem. 66, 513-554, (1909).
Bestimmung der Hydratation von lonen durch Ueberftthrungsversuche in
Gegenwart eines Nichtelektrolyten.) [Same as 1901.]
Meaa. O. Weber; see 78.
O. Weber see E. Rimbach.
680 AUTHOR LIST
1908. E. Wedekind. Ber. Deutsch. Chem. Ges. 32, 3561-3569, (1899).
Zur Charakteristik stereoisomerer Ammoniumsalze.
T=25^
1903a. £. Wedekind, F. Paschke. Zeit. Phys. Chem. 73, 118-128, (1910).
Zur Kinetik des ZerfaUs quart&rer Ammoniumsalze in Chloroform.
T=25^ xaq.«3XlO-*.
1904. J. B. Weems. Am. Chem. Jour. 16, 569-588, (1894). fUMeaa. A.
Wakeman.
On electro63mthe8es by the direct union of anions of weak organic acids.
[Qualitative. ]
1906. (H. Wegelius. Zeit. Elektrochem. 14, 514-^18, (1908).
Ueber den Einfluss der Konzentration auf die Optimumtemperatur der ekk-
trischen Leitfahigkeit der schwachen Elektrolyte mit negativer Dissoziations-
w&rme.) [Inorganic]
1906. R. Wegscheider. Ber. Deutsch. Chem. Ges. 36, 1541-1544, (1903).
Meaa. H. SiUs.
Ueber die Tautomeric der o-Aldehydsfturen.
1907. R. Wegscheider. Monatsh. 16, 75-152, (1895). Meaa. W. Meyer-
koffer.
Untersuchungen fiber die Hemipinsaure und die Esterbildung. [Same as 1921. ]
[T probably 25^] S. U. xaq.«7Xl(H».
1906. R. Wegscheider. Monatsh. 23, 287-316, (1902).
Ueber den Einfluss der Constitution auf die Affinit&tsconstanten organischer
Sauren. [Calculated from Lichty; see 1099. Same as 1922.]
1909. R. Wegscheider. Monatsh. 23, 317-^56, (1902).
Untersuchungen fiber die Veresterung uns3anmetrischer zwei- und mehr-
basischer S&uren. IV. Abhandlung; Udi)er die Leitfahigkeit einiger Sauren
und Estersauren. [Same as 1923.]
T=25*'=fc0.05^ R. O. xaq.«0.6-1.3X10-«; [notsub.? On page 325
it is stated that aq. is sub. for one compound.]
1910. (R. Wegscheider. Monatsh. 23, 357-368, (1902).
Untersuchungen liber die Veresterung uns3anmetrischer zwei- und mehr-
basischer Sauren. V. Abhandlung; Ueber die Constitution einiger Estersau-
ren.) [Same as 1924. Quoted. ]
1911. (R. Wegscheider. Monatsh. 23, 599-668, (1902).
Ueber die stufenweise Dissociation zweibasischer S&uren.) [Same as 1925.
Values of second k^ are calculated. ]
1912. R. Wegscheider. Monatsh. 26, 1231-1234, (1905). Meas. P. Lux,
Ueber die Konstitution der o-Aldehydsauren in wasseriger Ldsung. [Same as
1926.]
1913. R. Wegscheider. Monatsh. 26, 1235-1239, (1905). Meas. P. Lux,
Ueber die stufenweise Dissoziation zweibasischer S&uren. [Same as 1927. ]
1914. R. Wegscheider. Monatsh. 26, 1265-1276, (1905). Meas, P. Lux
and J, H. Suss,
Ueber die Affinitatskonstanten der Aminosauren. [Same as 1928. ]
1916. R. Wegscheider. Monatsh. 28, 819^24, (1907). Meas. N, L.
MMer,
Untersuchungen fiber die Veresterung unsynmietrischer zwei- und mehrba-
sischer S&uren. XVII. Abhandlung; Ueber Aminoterephtalesters&uren.
[Same as 1929.
1916. R. Wegscheider. Zeit. Elektrochem. 14, 510-512, (1908). Meas. A.
SckugowUsch.
Ueber den Farbeniunschlag des Phenolphthaleins.
T=22''to24^
AUTHOR LIST 681
1917. IL Wegscheider. Zeit. Elektrochem. 14, 740-741, (1908).
Die lonisationskonstanten des zweiten Waaserstoffions zweibasischer Sauren.
[Ck>]Tect8S70.]
1918. (R. Wegscheider. Zeit. Phys. Chem. 69, 60^-629, (1909).
Ueber die Anomalie der starken Eldctrolyte und die Gtiltigkeitsgrenzen des
VerdtlimungBgefletzes.) [Quoted. ]
1919. (R. Wegscheider. Verhand. Deutsch. Phys. Ges. 11, 544-545,
(1909).
Gtiltigkeitsgrenzen des Ostwaldschen Verdflnnimgagesetzes. ) [Qualitative.
See 1918.]
1920. (R. Wegscheider. Sitzber. Akad. Wien. 104, 2b, 111-116, (1895).
Ueber die Affinitatsconstanten der mehrbasischen S&uren und der Ester-
8&uren.) [Quoted. ]
1921. R. Wegscheider. Sitzber. Akad. Wien. 104, 2b, 117-194, (1895).
Metis, W, Meyerhoffer,
Untersuchungen tlber die Hemipins&ure und die Esterbildung. [Same as
1907.]
1922. R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 67-96, (1902).
Ueber den Einfluss der Constitution auf die Affinit&tsconstanten organischer
Sauren. [Same as 1908.]
1923. Jt. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 97-136, (1902).
Untersuchungen tiber die Veresterung unssrmmetrischer zwei- und mehr-
basischer S&uren. IV. Abhandlung; Ueber die Leitfahigkeit einiger S&uren
und Estersauren. [Same as 1909. ]
1924. (R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 154-165, (1902).
Untersuchungen tkber die Verestenmg unsymmetrischer zwei- und mehr-
basischer Sauren. V. Abhandlung; Ueber die Constitution einiger Ester-
sauren.) [Same as 1910.]
1926. (R. Wegscheider. Sitzber. Akad. Wien. Ill, 2b, 441-510, (1902).
Ueber die stufenweise Dissociation zweibasischer S&uren.) [Same as
1911.]
1926. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 765-768, (1905).
Meets, P, Lux.
Ueber die Konstitution der o-Aldehyds&uren in w&sseriger Losung. [Same
as 1912.]
1927. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 769-773, (1905).
Meas, P. Lux.
Ueber die stufenweise Dissoziation zweibasischer S&uren. [Same as 1918.]
1928. R. Wegscheider. Sitzber. Akad. Wien. 114, 2b, 801-812, (1905).
Meas. P. Lux and J. H. Suss,
Ueber die Affinit&tskonstanten der Aminos&uren. [Same as 1914.]
1929. R. Wegscheider. Sitzber. Akad. Wien. 116, 2b, 721-726, (1907).
Meas. N. L. MuUer.
Untersuchungen Uber die Veresterung, etc. [Same as 1916.]
Meas. R. Wegscheider; see 1980, 1931, 1938, 1939, 1941, 1942.
1930. R. Wegscheider, K. Bittner. Monatsh. 21, 638-654, (1900). Meas.
B. Wegscheider.
Untersuchungen tiber die Veresterung unsynmietrischer zwei- und mehrba-
sischer S&uren. II. Abhandlung; Ueber die Veresterung der Brom- und der
Oxyterephtals&ure. [Same as 1931.]
1931. R. Wegscheider, K. Bittner. Sitzber. Akad. Wien. 109, 2b, 523-539,
(1900). Meas. R. Wegscheider.
Untersuchungen Uber die Veresterung, etc. [Same as 1930.]
682 AUTHOR LIST
1982. R. Wegscheider, E. BondL Monatsh. 26, 103^1068, (1005). Meas.
P. Lux,
UntersuchuDgen Uber die Verestenmg unsymmetrischer zwei- und mehrba-
sischer Sauren. XIII. Abhandlung; Ueber Esters&uren 4H9ub6tituierter
Phtals&uren. [Same as 1983.]
1988. R. Wegscheider, E. Bondi. Sitzber. Akad. Wien. 114, 2b, 573-602,
(1905). Mean, P. Lux.
Untersuchungen fiber die Veresterung, etc. [Same as 1988.]
1984. R. Wegscheider, A. Glogau. Monatsh. 24, 915-958, (1903). Meas.
H. Su88,
Untersuchungen tiber die Veresterung uns3nnmetri8cher zwei- und mefar-
basischer Sauren. XII. Abhandlung; Ueber die Veresterung der Phtalon-
saure und der Homophtals&ure. [Qualitative. Same as 1986. Measurements
given in 1684.]
1986. R. Wegscheider, A. Glogau. Sitzber. Akad. Wien. 112, 2b, 749-792,
(1903). Meas. H, SUss.
Untersuchungen Uber die Veresterung, etc. [Same as 1984.]
1986. R. Wegscheider, J. Hecht Monatsh. 24, 413-433, (1903).
Untersuchungen tlber die Veresterung imsymmetrischer zwei- und mehr-
basischer S&uren. X. Abhandlung; Ueber Phenylbemsteins&ure und ihre
Veresterung. [Same as 1987. ]
R. O. xaq. = 2.lXlO-«.
1987. R. Wegscheider, J. Hecht. Sitzber. Akad. Wien. 112, 2b, 241-261,
(1903).
Untersuchungen Uber die Veresterung, etc. [Same as 1986. ]
1988. R. Wegscheider. A. Lipschitz. Monatsh. 21, 787-^12, (1900). Meaa.
R, WegBcheider.
Untersuchungen tlber die Veresterung unsynmietrischer zwei- und mehr-
basischer Sauren. III. Abhandlung; Ueber die Veresterung der 3- und 4-
Nitrophtalsaure. [Same as 1989. Corrected in 1909. ]
1989. R. Wegscheider, A. Lipschitz. Sitzber. Akad. Wien. 109, 2b, 586-
611, (1900). Mea8, R, Wegscheider.
Untersuchungen Uber die Veresterung, etc. [Same as 1988. ]
1940. R. Wegscheider, P. Lux. Monatsh. 30, 411-445, (1909). Metu. P.
Lux.
Die Sulfonsauren und das Ostwald'sche VerdUnnimgsgesetz. [Same as
1940a.]
T=25***0.05^ R. 0. X aq. = l-1.8XlO-*; sub. in some cases.
1940a. R. Wegscheider. P. Lnz. Sitzber. Akad. Wien. 118, 2b, 189-223,
(1909). Meas. P. Lux.
Die Sulfons&uren, etc. [Same as 1940.]
1941. R. Wegscheider, P. v. Rufinov. Monatsh. 24, 375-390, (1903).
Meas. R. Wegscheider.
Untersuchungen Uber die Veresterung unsjrmmetrischer zwei- und mehrba-
sischer Sauren. XI. Abhandlung; Verhalten der Hemipinestersauren gegen
Hydrazinhydrat und gegen Thionylchlorid. [Same as 1942.]
R. O.
1942. R. Wegscheider, P. v. RuSnov. Sitzber. Akad. Wien. 112, 2b, 207-
222, (1903). Meas. R. Wegscheider.
Untersuchungen Uber die Veresterung, etc. [Same as 1941.]
M. Weinheber see A. Rosenheim.
J. Weir see H. Pauly.
H. G. Wells see R. L. Benson.
AUTHOR LIST 588
IMS. (R. C. Wells. Jour. Am. Chem. Soc. 31, 1027-1035, (1909).
The electrical conductivity of ferric sulphate solutions.) [Inorganic and
quoted.]
Wendt see Bdhm-Wendt.
H. A. Wentworth see H. M. Goodwill.
F. Wenzel see F. Haiser.
1944. A. Werner. Ann. Chemie. 322, 296-351, (1902).
Ueber die Constitution der Oxoniumsalze.
1946. (A. Werner. Zeit. Anorg. Chem. 15, 1-41, (1897).
Beitrag zur Eonstitution anoiganischer Verbindimgen. VII. Mitteilung.
Ueber die MolekulargrOsse anorganischer Salze.) [Inorganic]
A. Werner. Zeit. Anorg. Chem. 15, 123-142, (1897), see under
Fassbender.
1946. A. Werner. Zeit. Anorg. Chem. 21, 201-242, (1899). Mea8. W.
Spruck,
Beitrag zur Konstitution anorganischer Verbindungen. XVIII. Mitteilung.
Ueber Aethylendiamin- und Propylendiaminverbindungen von Salzen zwei-
wertiger MetaUe. [Same as 1644.]
1947. A. Werner. Zeit. Anorg. Chem. 22, 91-157, (1900). HiMeas. R.
Klien.
Beitrag zur Konstitution anorganischer Verbindungen. XV. Mitteilung.
Ueber rhodanatokobaltiake und strukturisomere Salze.
1948. A. Werner, C. Herty. Zeit. Phys. Chem. 38, 331^352, (1901).
Beitrfige zur Konstitution anorganischer Verbindungen.
T=25^
1949. A. Werner, E. Humphrey. Ber. Deutsch. Chem. Ges. 34, 1719-1732,
(1901)..
Ueber stereoisomere Dinitritodiaethylendiaminkobaltsalze. [Same as 868. ]
1950. (A. Werner, A. Ifiolati. Zeit. Phys. Chem. 12, 35-^55, (1893).
Beitrfige zur Konstitution anorganischer Verbindungen.)
1961. (A. Werner, A. Miolati. Zeit. Phys. Chem. 14, 506-521, (1894).
Beitr&ge zur Konstitution anorganischer Verbindungen.)
1962. A. Wesch. Dis. Freiburg. (1908).
Ueber Chroms&urederivate. [Same as 1487.]
T = 18'. R. 0. xaq.«5.8XlO-«.
Meas. A. Wesch; see 1487.
1963. A. P. West Dis. Johns Hopkins. (1905).
A study of the effect of temperature on dissociation and on the temperature
coefficients of conductivity in aqueous solutions. [Same as 924.]
A. P. West see H. C. Jones.
1963a. A. P. West, H. C. Jones. Am. Chem. Jour. 44, 508-544, (1910).
The conductivity, dissociation and temperature coefficients of conductivity
at 35^, 50** and 65** of aqueous solutions of a number of salts.
T=35^50^65^ S. U.
1964. C. A. West Jour. Chem. Soc. 77/ 705-707, (1900).
The dissociation constant of azoimide (hydrazoic acid).
T=25^ S. U. X aq. =5.85XlO-«; sub.
Meas, Westhaosser; see 1032.
£. Wheeler see H. £. Armstrong.
P. Wheeler see G. N. Lewis.
1966. (W. C. D. Whetham. Chem. News. 98, 98-100, (1908).
The electroljrtic properties of dilute solutions of sulphuric acid.) [Given in
1967.]
584 AUTHOR LIST
1966. W. C. D. Whefham. Phil. Mag. (5), 38, 392-396, (1894).
On the velocities of ions and the relative ionisation-power of solvents.
1967. W. C. D. Whetham. Phil. Mag. (5), 44, 1-9, (1897).
The ionizing power of solvents.
T - 18** and 60^ C. G. 8. units.
1968. (W. C. D. Whetham. PhU. Mag. (6), 5, 279-290, (1903).
The theory of electrolytic dissociation.)
1969. W. C. D. Whetham. Zeit. Phys. Chem. 33, 344r-352, (1900).
Die Dissociation verdiinnter Ldsungen beim Gefrierpunkte. [Same as 1960.
Given in 1963.]
T-0'. C.G.S. units, x aq. sub.
1960. W. C. D. Whefham. Proc. R. Soc. London. 66, 192-203, (1899-1900).
The ionisation of dilute solutions at the freezing-point. [Same as 1969. .Given
in 1968.]
1961. (W. C. D. Whetham. Proc. R. Soc. London. 71,332-338, (1902-1903).
The electrical conductivity of solutions at the freezing-point of water.) [In-
organic. ]
1962. W. C. D. Whetham. Trans. R. Soc. London. A, 186, 507-^22, (1895).
On the velocities of ions.
T = 16' to 18^ C. G. S. units.
1968. W. C. D. Whetham. Trans. R. Soc. London. A, 194, 321-^60, (1900).
The ionization of dilute solutions at the freezing point. [Same as 1969 and
1960 with one additional table of A of KsFe(CN)«. ]
T =0**. C. G. S. units. Xig aq. about 0.9 X lO"*; sub. except in one table.
1964. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 118-120, (1908).
The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic.
Given in 1967.]
1966. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 127-130, (1908).
The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic.
Given in 1967.]
1966. (W. C. D. Whetham, H. H. Paine. Chem. News. 98, 158-159, (1908).
The electroljrtic properties of dilute solutions of sulphuric acid.) [Inorganic.
Given in 1967.]
1967. (W. C. D. Whetham, H. H. Paine. Proc. R. Soc. London. A, 81»
58-80, (1908-1909).
The electrolytic properties of dilute solutions of sulphuric acid.) [Inorganic.
Stune as 1966, 1964, 1966 and 1966 together.]
W. H. Whitcomb see A. A. Noyes.
1968. G. F. White, H. C. Jones. Am. Chem. Jour. 42, 520-541, (1909).
The effect of temperature and dilution on the conductivity of organic acids
in aqueous solution.
T-0^to35^ S. U. x«aq. = 1.2-1.7XlO-«.
1968a. G. F. White, H. C. Jones. Am. Chem. Jour. 44, 159-199, (1910).
The conductivity and dissociation of organic adds in aqueous solution at
different temperatures.
T«0*'to35^ S. U.
J. White see E. J. Constam.
R. Whymper see R. J. Caldwell.
1969. G. Wicke. Dis. Erlangen. (1898).
Beitrag zur Kenntnis des Pulegons und Menthons.
Hg. U.
Afecw. P. Wiegner; see 738.
Meas, J. Wigger; see 820.
A. Wild see L. Pelet-Jolivet
AUTHOR LIST 535
1970. M. Wildemuum. Zeit. Phys. Chem. 14, 231-246, (1894).
Die methode von KohlrauBch in ihrer Anwendung zur Untersuchung der elek-
trischen Leitf&higkeit schwach diasociierter Stoffe.
T = 18^ S. U.
1971. M. Wildemuum. Zeit. Phys. Chem. 14, 247-271, (1894).
Ueber eine weitere Methode zur Bestimmung der elektrischen Leitffihigkeit
schwach dissociierter Stoffe.
T=25'**0.05^ Xj6 aq.=2.83Xl(H.
1972. M. Wildennann. Zeit. Phys. Chem. 15, 337-^57, (1894).
Der experimentelle Beweis der van't Hoffschen Konstante, des Arrheniusschen
Satzes, des Ostwaldschen Verdtknnungsgesetzes in sehr v^tUmten Ldsungen.
1973. M. Wildennann. Zeit. Phys. Chem. 19, 233-250, (1896).
Experimenteller Beweis der van't Hoffschen Konstante, des Arrheniusschen
Satzes, des Ostwaldschen Verdunnungsgesetzes, des Daltonschen Gesetzes
u. 8. w. in sehr verdiinnten Ldsungen.
1973a. E. G. Willcock. Jour. Physiol. 37, 27-36, (1908).
Crystalline egg-albumin.
R. S. Willows see A. E. Garrett
1974. R. Wmstittter. Ber. Deutsch. Chem. Ges. 28, 3271-3292, (1895).
Meas. V. Rothmund.
Ueber die Aufspaltung der Tropins&ure. [Same as 1977.]
1976. R. Willstittter. Ber. Deutsch. Chem. Ges. 31, 1534r-1553, (1898).
Meas. V. Rothmund.
Ueber die Constitution der Spaltungsproducte yon Atropin und Cocaln.
T-25^ R. O.
1976. R. Wlllstfttter. Ber. Deutsch. Chem. Ges. 32, 1635-1641, (1899).
Meas. V. Rothmund.
Ueber einige Derivate des Ecgonins.
T=25^ R. O. xaq. sub.
1977. R. Willstfttter. Habilitschr. MOnchen. (1896). Meas. V. Rothmund.
Untersuchungen in der Tropingruppe. [Same as 19741.]
1978. R. WlllstiUter, C. Hollander. Ann. Chemie. 326, 79-90, (1903).
Meas. V. Rothmund.
S3mthe8e der Ecgoninsaure. [Same as 848.]
T=25^
1979. R. Willstiitter, R. Leasing. Ber. Deutsch. Chem. Ges. 35, 2065-2073,
(1902). Meas. V. Rothmund, and Drucker.
Ueber N-Methylpsrrrolidin-ai-ardicarbons&ure. [Same as 1074 with cor-
rections.]
T=25*. R. O.
1980. E. Wilson. Proc. R. Soc. London. 71, 241-243, (1902-1903).
Some dielectric properties of solid glycerine.
T=-81°to -hl3^
1981. F. P. Wilson. Dis. Johns Hopkins. (1899). Meas. B. P. CaldweU.
I. Orthosulphaminebenzoic acid. II. Orthocarbaminebenzenesulphonic acid.
T=25^
1982. (J. H. Wilson. Am. Chem. Jour. 35, 78^^, (1906).
Some concentration cells in methyl and ethyl alcohols.) [Inorganic and
quoted. ]
1988. T. M. Wilson. Am. Jour. Physiol. 16, 438-167, (1906).
On the comparison of conductivity and freezing points of small quantities of
body fluids in health and disease.
686 AUTHOR LIST
1084. K. Wkkelblecli. Zeit. Phys. Chem. 36, 546-595, (1901).
XJeber amphotere Elektrolyte und innere Sake. [Same as 1986.]
T=25^ S. U. X aq. less than 3X10-*; sub.
1986. K. Wlnkelblech. Dis. Leipzig. (1901).
Ueber amphotere Elektrolyte und innere Sake. [Same as 1984.]
ilfecM. K. ^Wlnkelblech; see 268.
ilfeos. H. WisUcenus; see 66, 868, 1669, 1671, 1673, 1674.
1986. L. WOhler. Ber. Deutsch. Chem. Ges. 38, 1351-1359, (1905).
Die Molekulargrdsse der Knalls&ure.
T=0*. R. O. X aq. = 1.73X10-*; not sub.
P. W({hler see W. Kerp.
1987. J. Woelfer. Ann. Physik. (3), 57, 91-111, (1896).
Die Siedepunktserhdhung von einigen aethyl- und methylalkoholischen Sals-
lOsungen. [Part is same as 1988.]
Hg.U.
1968. J. Woelfer. Dis. HaUe. (1894).
Ueber die Erhdhung des Siedepunktes von absolutem Alkohol durch Losung
einiger Sake. [Given in 1987.]
1989. (A. WOnnann. Ann. Physik. (4), 29, 194-200, (1909).
Die Temperaturkoeffizienten der elektrischen Leitf&higkeit einiger S&uren und
Basen in w&sseriger Ldsung.) [Inoiganic. Corrected in 1990.]
T-0*to32^
1990. (A. W5nnann. Ann. Physik. (4), 29, 62^-624, (1909).
Berichtigung zu der Mitteilung '' Die Temperaturkoeffizienten der elektrischen
Leitf&higkeit einiger S&uren und Basen in w&sseriger Ldsung.") [Corrects
1989.]
1991. A. Wohl. Ber. Deutsch. Chem. Ges. 40, 2282-2293, (1907).
Ueber Oxyfumar- und Ozymaleinsaure. [Corrects 926.]
1992. A. Wohl, P. ClAussner. Ber. Deutsch. Chem. Gee. 40, 2308-2312,
(1907).
Messimgen an der Oxymalein- und Oxyfuman&ure.
T = 17^
1998. H. Wolf. Zeit. Elektrochem. 8, 117-119, (1902).
Zur Eenntnis der Leitf&higkeit von Ldsungen gemischter Elektrolyte. [Qual-
itative. Given with complete data in 1994.]
1994. H. Wolf. Zeit. Phys. Chem. 40, 222-255, (1902).
Beitrag zur Kenntnis der Leitf&higkeiten gemischter Lteungen von Elektro-
lyten.
T=25^»*:0.05*. X aq. -2.0XlO-«.
1996. J. K. Wood. Jour. Chem. Soc. 83, 568^78, (1903).
The affinities of some feebly basic substances. [Same as 1998.]
T=40.2^
1996. J. K. Wood. Jour. Chem. Soc. 89, 1831-1839, (1906).
The acidic constants of some ureides and uric acid derivatives.
T =25^ R. O. xj6 aq. not over 1.5 XlO"*.
1997. J. K. Wood. Jour. Chem. Soc. 89, 1839-1847, (1906).
The affinity constants of xanthine and its methyl derivatives.
T =40.1*' and 25^
1998. J. K. Wood. Proc. CJhem. Soc. 19, 67-68, (1903).
The affinities of some feebly basic substances. [Same as 1996.]
1999. (J. K. Wood. Proc. Chem. Soc. 22, 271, (1906).
The acidic constants of some ureides and uric acid derivatives.) [No data. ]
AUTHOR LIST 687
9000. (J. K. Wood. Proe. Chem. Soo. 22, 271-272, (1906).
The affinity oonstants of xanthine and its methyl derivatiyes.) [No data.]
J. K. Wood see J. Walker.
8001. (R. W. Wood. Am. Chem. Jour. 15, 663-670, (1893).
The action of salts on acids.)
2002. R. W. Wood. Am. Chem. Jour. 16, 313^25, (1894).
The affinity constants of weak acids and the hydrolysis of salts.
[T=66*?]
2008. R. W. Wood. Phil. Mag. (5), 41, 117-120, (1896).
On the dissociation degree of some electrolytes at 0^ [Same as 2004.]
T=0** and 25*. S. U. x aq. sub.
2004. R. W. Wood. Zeit. Fhys. Chem. 18, 521-523, (1895).
Notiz liber den DiBsociationsgrad einiger Electrolyte bei Null Grad. [Same
as 2003.]
T»0** and 25^ 8. U. x aq. sub.
2005. T. B. Woody W. B. Hardy. Proc. R. Soc. Soc. London. B, 81, 3^-43,
(190&-1909).
Electrolytes and colloids. The physical state of gluten.
B. E. WooUey see H. Henstock.
2003. R. G. Wright Dis. Basel. (1902).
Zur Kenntnis des Aiuramins G.
T-0*and25*.
Z.
2007. U. Zanninowich Tessaiin. Gas. Chim. Ital. 26, 1, 311-323, (1896).
DisBociazione elettrolitica deUe solusioni in acido formico. [Same as 2003.]
T-25^
2008. H. Zanninovich-TessaiJn. Zeit. Phys. Chem. 19, 251-260, (1896).
Elektrolytische Dissociation der L(38ungen in Ameisens&ure. [Same as 2007. ]
2009. J. V. ZawidzkL Ber. Deutsch. Chem. Ges. 36, 3325-3337, (1903).
Ueber den amphoteren Charakter der Kakodyls&ure. [Corrected in 2010.]
T=25*and0^ 8. U. x aq. sub.
2010. J. V. ZawidzkL Ber. Deutsch. Chem. Ges. 37, 153-154, (1904).
Ueber den amphoteren Charakter der EjJcodyls&ure. [A correction of 2009.]
2011. J. V. ZawidzkL Ber. Deutsch. Chem. Ges. 37, 2289-2298, (1904).
Ueber die basischen Eigenschaften der Kakodyls&ure und des Hamstoffs.
[See 789.]
T-26*.
2012. (J. V. Zawidzki. Ber. Deutsch. Chem. Ges. 37, 2298-2301, (1904).
Zur Theorie der Pseudos&uren.)
2018. J. V. ZawidzkL Zeit. Phys. Chem. 42, 612-616, (1902-1903).
Ueber Saponinschaum.
T-25^ S. U. X aq. probably sub.
Meas, J. V. Zawidzki; see 1882.
B. Zdanowsld see J. KowalfkL
2014. F. ZecchinL Gas. Chim. Ital. 23, II, 601-607, (1893).
Esperienze sul potere rotatorio della ooniina e dei suoi sali. [Same as 2018. ]
T-26*.
2018. F. Zeccfaini. Rend. Accad. Lined. (5), 2, II, 168-173, (1893).
Esperienze sul potere rotatorio, etc. [Same as 2014.]
Zelinskij see Zelinsky.
2016. N. Zelinsky. Ber. Deutsch. Chem. Ges. 24, 3997-4005, (1891).
Ueber die stereoisomeren Dimethyladipins&uren und Dimethylpimelins&uren.
688 AUTHOR LIST
3017. N. Zelinsky. Ber. Deutsch. Chem. Ges. 29, 616-618, (1896).
Zur Kenntniss der stereoisomeren DimethyltricarbaUylaauren.
2018. N. Zelinsky. Jour. Russ. Phys.-chem. Soc. 23, 612-632, (1891).
Electrolytic conductivity of aqueous solutions of stereoisomeric acids and
their mixtures.
T=25°.
2019. (N. D. Zelinsky. Jour. Russ. Phys.-chem. Soc. 26, 608-^11, (1894).)
[No title. A report on the electrolysis of potassium salts of nitro-organic
compounds. ]
2020. (N. D. Zelinsky. Jour. Russ. Phys.-chem. Soc. 26, 611--612, (1894).)
[No title. A report on the electrolysis of sodium salts of nitromethane.]
Meas. N. Zelinsky; see 1217.
2021. N. Zelinsl^, A. Besredka. Ber. Deutsch. Chem. Ges. 24, 459-478,
(1891).
Ueber das gegenseitige Verhalten der Dimethylglutar- und Trimethylbem-
steinsauren und Uber die stereoisomeren Trimethylbemsteins&iu'en. [Same
as 2022.]
2022. N. Zelinsky, A. Besredka. Jour. Russ. Phys.-chem. Soc. 23, 126-147,
(1891).
Of the mutual relation of isomeric dimethylglutaric and trimethylsuccinic acids
and of stereoisomeric trimethylsuccinic acids. [Same as 2021. ]
2028. N. Zelinsky, L. Buchstab. Ber. Deutsch. Chem. Ges. 24, 1876-1880,
(1891).
Ueber stereoisomere Phenylmethylbemsteins&uren.
2024. N. Zelinsky, A. Generosow. Ber. Deutsch. Chem. Ges. 29, 729-733,
(1896.)
Untersuchungen in der Hexamethylenreihe.
2020. N. Zelinsky, W. Isajew. Ber. Deutsch. Chem. Ges. 29, 819-820,
(1896).
Ueber stereoisomere Dimethyldioxyadipins&uren.
2026. N. Zelinsky, N. Izgaxyfiev. Jour. Russ. Phys.-chem. Soc. 40, 1379-
1388, (1908).
The electrolytic dissociation constants of cycloparaffin acids.
2027. (N. Zelinsky, S. Krapiwin. Jour. Russ. Phys.-chem. Soc. 28, 414-
416, (1896).
On the electrol3rtic condition of some salts and some acids in methyl-alcohol.)
[This is a report of 2028. ]
2028. N. Zelinsky, S. Krapiwin. Jour. Russ. Phys.-chem. Soc. 28, 579-593,
(1896).
On the electrolytic state of solutions of salts and some acids in methyl alcohol.
[Same as 2029.]
T=25^ xaq. sub.
2029. N. Zelinsky, S. Krapiwin. Zeit. Phys. Chem. 21, 35-52, (1896).
Ueber den elektrolytischen Zustand der Lteungen von Salzen und einiger
Sfturen in Methylalkohol. [Same as 2028.]
Meas, Zengelis; see 80.
2080. T. Zincke. Ann. Chemie. 296, 135-158, (1897). Meas. F. KHster.
Ueber die Einwirkung von Chlor auf o-Amidophenole und o-Dianune. [Same
as 1028.]
2081. L. 2lobicki. Bui. Acad. Cracov. (1907), 1009-1016.
Ueber den Einfluss des Radiums auf die elektrolytische Leitf&higkeit kol-
loidaler Ldsimgen. [The organic solvents used were not chemically pure. ]
T = 18**to24^ R. O.
AUTHOR LIST 689
2032. L. Zoja. Zeit. Chem. Ind. KoUoid. 3, 249-269, (1908).
Physikftlisch-chemische UntersuchuDgen der Reaktionen swiachen EiereiweisB
und Easigjsaure.
T-16*, 25•and42^
A. Zo80 see P. B. DaMonte.
SUBJECT INDEX.
In using this index, it is advisable to look through all the headings and con-
sider the definitions and illustrations given, since no two persons would agree
on exactly the same arrangement.
In cases of doubt, and in cases open to legitimate difference of opinion, the
reference is given under all the possible headings.
For the sake of brevity, consecutive references to the same author are some-
times given inclusively, thus 1-^, instead of giving each number separately.
These inclusions are never used if the numbers cover more than one name.
When the same measiu-ements are published in more than one journal, the
key number given here is to the most accessible article. In the author list,
after the title of this article, are given references to the less accessible articles.
SUBJECT INDEX.
ACIDS AND THEIR SALTS.
Cazboxylic; as acetic and benzoic adds. Non-carboxylic; as hydrocyanic,
ferrocyanic, thiocyanic; and barbituric, croconic and uric adds.
a) No substituting group.
1, 8, 7, 10, 11, 23, 36, 30, 43, 44, 45, 32, 60, 61, 62, 63, 66, 66,
67, 68, 69, 70, 71, 72, 76, 81, 98, 94, 106, 114, 189, 141, 146,
146a, 146b, 147a, 167, 167a, 164, 166, 168, 169, 170, 171
176, 177, 179a, 180, 188, 189, 190, 191, 196, 197, 198, 200
202, 211, 216, 220, 222, 223, 229, 231, 232, (233), 234, 236
237, 238, 244, 246, 247, 270, 274, 276, 278, 279, 280, 289
294, 296, 299, 319, 347, 364, 360, 362, 366, 370, 372, 376
378, 379, 381, 386, 386, 387, 388a, 889, 391, 397, 399, 401
408, 413, 420, 427, 430, 438, 440, 444, 449, 464, 461, 468
469, 482, 491, 494, 496, 496, 602, 608, 607, 608, 613, 616
632, 640, 642, 666, 667, 668, 669, 666, 666, 667, 668, 669
671, 671a, 672, 673, 679, 688, 691, 601, 602, 606, 619, 636
640, 642, 646, 647, 666, 682, 691, 693, 694, 698, 699, 701
760, 768, 764, 768, 782, 787, 788, 789, 793, 796, 799, 804
813, 814, 817, 823, 826, 827, 828, 838, 848, 860, 861, 866
881a, 889, 894, 908, 910, 911, 924, 926, 931, 932, 934, 936
946, 961, 966, 968, 966, 966, 986, 991, 993, 996, 997, 1003, 1004,
1011, 1017, 1018, 1023, 1029, 1030, 1031, 1033, 1043, 1047, 1066,
1078, 1086, 1088, 1094, 1102, 1103, 1104, 1106, 1111, 1122, 1123,
1126, 1138, 1143, 1144, 1160, 1174, 1178, 1184, 1186, 1186, 1199,
1202, 1209, 1211, 1212, 1213, 1217, 1223, 1227, 1229a, 1231, 1240,
1246, 1246, 1248, 1261, 1264, 1270, 1273, 1276, 1279, 1280, 1330,
1331, 1332, 1336, 1338, 1341, 1341b, 1343, 1349, 1360, 1367-
1362, 1367, 1368, 1368a, 1369, 1370, 1371, 1372, 1373, 1380, 1386,
1386b, 1387, 1388, 1390, 1391a, 1398, 1399, 1407, 1410, 1411, 1412,
172,
201,
236,
290,
377,
403,
466,
617,
670,
637,
738,
810,
876,
943,
1413
1480
1687
1620
1661
1711
1747
1824
1869
1907
1962
2002
1414, 1416, 1418, 1419, 1427, 1429, 1448, 1460, 1470, 1473,
1496, 1496, 1600a, 1600b, 1603, 1618, 1619, 1620, 1683,
1639, 1643, 1644, 1646, 1646, 1647, 1664, 1662, 1663, 1669,
1673a, 1676, 1677, 1679, 1681, 1681a, 1688, 1690a, 1697, 1618a,
1630, 1636, 1636, 1638, 1639b, 1640, 1643, 1646, 1649, 1664,
1662, 1664, 1666, 1666, 1667, 1673, 1684, 1704, 1708, 1708a,
1712, 1717, 1718, 1728, 1729b, 1736, 1736, 1737, 1741, 1746,
1781, 1791, 1801, 1807, 1809, 1810, 1813, 1820, 1821, 1823,
1831, 1834, 1836, 1837, 1838, 1839, 1840, 1842, 1843, 1844, 1863c,
1860, 1861, 1862, 1866, 1866, 1887, 1888, 1889, 1897, 1899,
1909, 1911, 1912, 1934, 1936, 1941, 1963a, 1964, 1966, 1967,
1968, 1968a, 1969, 1971, 1974, 1976, 1976, 1991, 1993, 1994,
2008, 2016-2018, 2021, 2023, 2024, 2026, 2029.
642 SUBJECT INDEX
CnHnNn; as hydrocyanic acid; and CnHnOnNn; as pyridine carboxylic acid,
cyanic add and uric acid.
18, 23, 70, 77, 80, 142, 143, 146b, 175, 216, 228, 246, 313, 368,
443, 447, 448, 499, 610, 627, 652, 601, 604, 606, 607, 610, 631, 637,
683, 684, 696, 696, 701, 733, 742, 762, 766, 764, 767, 768, 782, 826,
841, 866, 907, 943, 963, 967, 1043, 1086, 1092, 1094, 1097, 1106,
1160, 1166, 1177, 1186, 1188, 1190, 1246, 1287, 1309a, 1363a,
1369, 1372, 1397a, 1422, 1428, 1461, 1645, 1646, 1664, 1747, 1748,
1814, 1840, 1843, 1863c, 1866, 1886, 1894, 1978, 1979, 1984, 1986,
1996.
Metallo-cyanic adds; as ferro- and ferri-cyanic adds.
149, 160, 168, 220, 313, 372, 376, 468, 610, 604, 606, 689, 690,
889, 889, 901, 903, 907, 924, 943, 971, 1024, 1838, 1362, 1434a,
1486, 1494, 1617, 1709, 1832, 1836, 1837, 1963a, 1969.
Thiocyanic.
216, 217, 468, 471, 474, 478, 482, 487, 491, 606, 681, 793, 820,
911, 922, 943, 990, 993, 1004, 1007, 1066, 1067, 1070, 1106, 1162, 1163,
1164, 1192, 1276, 1337, 1362, 1392, 1470, 1626, 1627, 1673, 1641,
1747, 1762, 1826, 1832, 1844, 1856, 1944, 1947, 1948.
b) Amino-, anilino-, imino- etc., including adds with substitution of H
in the NHs or NH group; as, aminoacetic add CHs(NHt).COsH,
amlinobutyric acid £t.CH(NHPh).COsH, acetylamino-acetic add
(MeC0)NH.CH,.C02H.
23, 30, 79, 142, 143, 145a, 146b, 164, 166, 167, 170, 176, 177,
186a, 191, 196, 228, 268, 271, 302a, 316, 360, 414, 439, 443, 466a,
492, 496, 499, 604, 619, 622, 623, 627, 690, 601, 606, 637, 645,
846, 864, 865, 890, 947, 948, 963, 1027, 1029, 1086, 1087, 1134,
1160, 1167, 1168, 1184, 1186, 1227, 1233, 1243, 1246, 1318, 1334,
1363a, 1367, 1368a, 1370, 1371, 1372, 1374, 1397a, 1407, 1608, (1667),
1663, 1690, 1619, 1639b, 1669, 1673, 1682, 1684, 1718, 1720, 1749,
1773, 1774, 1776, 1814, 1817, 1824, 1838, 1840, 1868, 1874, 1918,
1914, 1916, 1968, 1968a, 1978, 1979, 1981, 1984, 1996.
c) Ck>mplex.
These complexes, formed (for the most part) by the combination of organic
and inorganic compounds, are chiefly of the types established by Wer-
ner, Tschugaeff and others. In most cases, only the salts are known.
88, 89, 149, 246, 247, 320a, 320b, 427, 660, 691, 692, 708, 766,
785, 816, 938, 1023, 1060, 1086, 1094, 1096, 1096, 1097, 1162,
1163, 1164, 1192, 1198, 1269, 1386, 1468, 1486, 1487, 1494, 1495,
(1614), 1616, 1616, 1617, 1618, 1619, 1620, 1621, 1527, 1630a,
1660, 1572, 1673, 1577, 1581a, 1641, 1648, 1709, 1711, 1721, 1760-
1767, 1769, 1760a, 1761.
d) Cyano; as cyanoacetic add CHs(CN).C02H.
226, 294, 296, 647, 698, 699, 754, 768, 943, 1296, 1296, 1370,
1371, 1390, 1820, 1821, 1831, 1897.
SUBJECT INDEX 548
e) Halogen; as biomoacetic acid CH2Br.C0sH.
, 48, 68, 79, 167, 167a, 176, 220, 228, 270, 291, 294, 296,
297, 386, 886, 847, 870, 871, 872, 404, 441, 448, 449, 460, 461,
474, 476, 492, 616, 641, 668, 677, 684, 602, 606, 647, 664, 666a,
667, 698, 709, 727, 728, 729, 760, 764, 782, 828, 888, 846, 849,
869, Sn, 911, 982, 989, 948, 961, 1011, 1018, 1021, 1084, 1094,
1099, 1116, 1184, 1184, 1186, 1186, 1228, 1264, 1268, 1286, 1299,
1817, 1867, 1868, 1868a, 1870, 1871, 1872, 1416, 1486, 1486, 1487,
1489, 1499, 1606, 1668, 1679, 1681, 1688, 1648, 1690, 1691, 1698,
1694, 1696, 1700, 1701, 1717, 1718, 1728, 1748, 1820, 1824, 1827,
1881, 1888, 1884, 1888, 1840, 1841, 1842, 1844, 1866, 1897, 1908,
1909, 1911, 1980, 1967, 1970, 1971, 1972, 1978, 1994, 2004, 2008,
2029, 2080.
f) Hydroxy- with their ethers; as glyoollic acid CH2(OH).C02H and
methoxy.4U)etic add CH2(0Me).C0sH.
11, 28, 80, 46, 64, 70, 98, 94, 146a, 160, 164, 166, 168, 169,
170, 171, 176, 179, 192, 198, 194, 200, 202, 220, 228, 226, 229,
270, 274, 800, 806a, 809, 819, 820a, 820b, 860, 866, 871, 872,
Sn, 878, 887, 888a, 889, 894, 896, 404, 418, 480, 447, 448, 449,
468, 478, 474, 482, 492, 496, 616, 626, 627, 682, 641, 642, 668,
674, 688, 606, 617, 640, 648, 647, 667, 691, 692, 698, 701, 706,
727, 728, 729, 742, 764, 782, 804, 809, 812, 828, 827, 848, 863,
889, 910, 911, 934, 988, 948, 947, 966a, 966, 1028, 1034, 1066,
1090
1202
1317
1407
1492
1663
1649
1747
1869
1969
1091, 1004, 1122, 1184, 1182, 1184, 1186, 1186, 1189, 1199,
1216, 1228, 1281, 1239, 1248, 1249, 1261, 1262, 1276, 1316,
1846, 1867, 1362, 1366, 1367, 1368, 1368a, 1370, 1371, 1372,
1411, 1418, 1429, 1464, 1463, 1466, 1466, 1468, 1473, 1476,
1493, 1496, 1496, 1608, 1618, 1619, 1621, 1642, 1664, 1662,
1669, 1681, 1689, 1629, 1633, 1636, 1638, 1640, 1648, 1648,
1670, 1672, 1684, 1704, 1706, 1718, 1719, 1784, 1736, 1736,
1781, 1820, 1821, 1828, 1824, 1826, 1886, 1888, 1889, 1842,
1866, 1899, 1906, 1907, 1909, 1911, 1982, 1941, 1968, 1968a,
1970, 1991, 1992, 1994, 2018, 2026.
g) Nitre and nitroso; as nitrobenzoic acid NO2.CftH4.CO2H and nitroso
or oximino-acetic acid H.C:N0H.C02H.
80, 176, 194, 466a, 492, 616, 626, 602, 606, 807, 687, 647, 666,
660a, 764, 766, 768, 772, 844, 846, 849, 911, 943, 960, 1092,
1094, 1186, 1186, 1296, 1296, 1842, 1366, 1866, 1367, 1368a, 1370,
1371, 1390, 1608, 1663, 1681, 1627, 1684, 1718, 1748, 1781, 1820,
1886, 1888, 1840, 1906, 1909, 1982, 1938, 1972, 1973.
h) Acids containing sulphur; as benzene sulphinic acid Ph.S02H, phenol
sulphonic acid HO.CeH4.HSOs, thioacetic acid Me.COSH. Thiocyanic
acid has been given under a separate heading.
18, 23, 64, 70, 148, 149, 167, 176, 186a, 220, 270, 894, 423,
431, 466a, 492, 496, 604, 606, 607, 636, 637, 643, 646, 660a,
731, 764, 768, 774, 781, 782, 818, 860, 861, 862, 868, 864, 866,
949, 960, 969, 972, 976a, 1090, 1111, 1138, 1184, 1846, 1367,
1866, 1867, 1870, 1872, 1886, 1401, 1402, 1466, 1466, 1467, 1608,
644 SUBJECT INDEX
1628, 1029, (1M7), 1562, 1674, 1630, 1718, 1721, 1748, 1770,
1773, 1774, 1796, 1811, 1836, 1841, 1842-1844, 1909, 1911, 1940,
1968, 1968a, 1981, 1984.
i) Unclassified.
142, 806a, 606, 683, 684, 733, 738, 762, 764, 766, 767, 768, 769,
773, 782, 888, 948, 976c, 1063, 1064, 1094, 1118, 1119, 1120,
1188, 1363a, 1663, 1676a, 1697, 1720, 1748, 1771, 1837, 1996.
ALCOHOLS; as ethyl alcohol Et.OH.
18, 20, 21, 29, 30, 34, 46, 68, 74, 101, 106, 107, 110, 133, 146b,
147a, 263, 289, 290, 301, 306, 322, 336, 337, 338, 343, 844, 347,
361, 362, 366, 386, 391, 392, 418, 426, 433, 438, 446, 466, 466,
478, 491, 612, 632, 680, 682, 697, 606, 637, 647, 666a, 741, 760,
764, 760, 764, 770, 783, 787, 799, 606, 816, 840, 842, 887, 904,
908, 912, 916, 917, 918, 920, 922, 941, 943, 944, 966, 966, 976,
979, 986, 1010, 1021, 1036, 1036, 1061, 1098, 1106, 1107, 1108,
1110, 1160, 1177, 1179, 1180, 1181, 1183, 1189, 1222, 1269b, 1279,
1316, 1344, 1364, 1388, 1390, 1419-1421, 1423a, 1434, 1434a, 1462,
1464a, 1470, 1472, 1497, 1609, 1618, 1634, 1666, 1669, 1679, 1680,
1682, 1689, 1690a, 1692, 1614, 1620, 1627, 1649, 1661, 1696, 1724,
1746, 1763, 1766, 1777, 1791, 1800, 1807, 1816, 1829, 1842-1844,
1849, 1863a, 1884, 1897, 1900, 1903a, 1970, 1971, 1980, 1987,
1994, 2029, 2031.
ALDEHYDES; as acetaldehyde Me.CHO.
16, 68, 78, 602, 612, 617, 628, 629, 632, 633, 638, 606, 607,
637, 643, 663, 741, 760, 784, 941, 943, 969, 961, 962, 1106, 1107,
1388, 1608, 1668, 1669, 1690a, 1664, 1718, 1719, 1741, 1842-1844,
1847, 1863a, 1897.
AMIDES; as acetic add amide Me.CONHt.
17, 33, 70, 102, 141, 143, 146, 146a, 149, 211, 214a, 286, 286,
332, 410, 412, 662, 663, 604, 606, 606, 607, 610, 637, 660, 726,
746, 748, 760, 764, 767, 761, 779, 781, 782, 943, 963, 1008,
1061, 1094, 1096, 1097, 1166, 1248, 1289b, 1318, 1371, 1372,
1479, 1606d, 1624, 1626, 1680, 1676, 1646, 1684, 1729, 1741, 1747,
1748, 1791, 1842-1844, 1863b, 1863c, 1864, 1380, 1890, 1894, 1897,
1904, 1944, 1981, 1983, 1984, 1996, 1996, 2011.
ANHYDRIDES AND LACTONES.
1, 3, 7, 202, 211, 223, 360, 414, 443, 623, 679, 606, 701, 733,
741, 760, 764, 864, 890, 1029, 1030, 1031, 1186, 1249, 1262, 1493,
1600a, 1600b, 1644, 1646, 1662, 1690a, 1810, 1823, 1838, 1839,
1840, 1843, 1844, 1976, 1984, 1991, 2018.
ANHJDES etc.; as acetaniiide.
, 606, 637, 1996.
SUBJECT INDEX 646
BASES COirrAINING IVintOOEN, AND THEIR SALTS.
a) No substituting group; as ethyl amine and amline.
19, 87, 82, 88, 44, 89, 76, 86, 98a, 102, 108, 146a, 146b, 166, 169,
177, 186, 269, 270, 271, 286, 286, 299a, 808, 804, 806, 814, 886,
886, 847, 860, 898, 401, 402, 406, 409, 420, 426, 426, 428, 484,
486, 489, 478, 486, 492, 604, 610, 611, 618, 620, 682, 648, 684,
698, 699, 606, 606, 610, 687, 646, (649), 660, 660, 664, 706, 784,
740, 741, 747, 748, 760, 768, 764, 769, 768, 764, 767a, 770, 776,
779, 786, 817a, 822a, 888, 882, 928, 986, 986, 948, 977, 979,
1011. 1067, 1076, 1084, 1098, 1106, 1116, 1148, 1144, 1160, 1176,
1176
1821
1472
1678
1669
1778
1884
1884
1228, 1224, 1287, 1241, 1266, 1266, 1266, 1288, 1298, 1816,
1827, 1882, 1864, 1868, 1864, 1388, 1889, 1891, 1402, 1428a,
1476, 1477, 1481, 1681, 1662a, 1668, 1662, 1669, 1671, 1676,
1690a, 1601, 1611, 1612, 1614, 1616, 1617, 1681, 1646, 1646,
1660, 1707, 1729b, 1781, 1766, 1760a, 1770, 1776, 1776, 1777,
1779, 1791, 1796, 1798, 1801, 1802, 1828, 1828, 1829, 1838,
1842, 1844, 1846-1849, 1861, 1868a, 1866, 1864, 1880, 1882,
1897, 1900, 1908, 1908a, 1996, 1997, 2006, 2014, 2029.
b) Alkaloids; as bnicine.
98a, 146b, 177, 270, 271, 803, 804, 426, 426, 698, 606, 660, 706,
768, 764, 776, 948, 948, 979, 1106, 1228, 1224, 1241, 1288, 1806,
1611, 1620, 1681, 1646, 1707, 1776, 1776, 1778, 1779, 1842, 1864,
1897, 1978, 1996, 1997, 2014.
c) Complex; or in complex compounds.
69, 149, 610, 611, 620, 660, 816, 886, 948, 1008, 1076, 1884,
1416, 1417, 1481, 1482, 1622, 1680, 1672, 1760-1767, 1769, 1760a,
1761, 1762, 1946-^1949.
d) Halogen; as bromoamline.
270, 271, 428, 492, 648, 684, 606, 660, 1298, 1601, 1697, 1698,
1777, 1864.
e) Nitro and nitroso; as nitroaniline NO2.C6H4.NH1 and nitroso-methyl-
aniline NO.CeH4.NHMe.
102, 492, 648, 688, 604, 606, 610, 637, 669, 660a, 788, 736, 764,
767, 782, 1094, 1116, 1802, 1848, 1844, 1868c, 1864, 1897, 1996.
f) Containing sulphur; as thiourea.
149, 177, 271, 860, 748, 943, 1008, 1802, 1868, 1402, 1624, 1626,
1649, 1748, 1826, 1864, 1880.
g) Unclassified.
601, 648, 788, 948, 1088, 1098, 1266, 1601, 1660, 1687, 1707,
1777, 1996, 1997.
646 SUBJECT INDEX
CARBOHYDRATES.
45, 146b, 310a, 264, 266, 260a, 822, 324, 892, 682, 688, 690,
698, 694, 696, 606, 637, 641, 686, 741, 788a, 1086, 1086, 1089,
1108, 1110, 1160, 1177, 1209a, 1220,1222, 1864, 1381, 1888, 1468,
1478, 1497, 1669, 1746, 1747, 1843, 1988.
DIAZO-COMPOUnDS.
77, 142, 143, 318, 426, 600, 601, 681, 686, 780, 781, 786, 786,
737, 766, 774, 779, 1601, 1720.
DILUTION LAW.
16, 84, 478, 488, 486, 488, 647, 837, 989, 994, 1046, 1100, 1800,
1886a, 1488, 1688, 1660, 1676, 1868, 1918, 1940.
DYES.
The references indexed here include both conductivity and all other measure-
ments.
76, 86, (87), 146, 186, 186a, 826, 416, 606, (684b), 636, 637,
667, 660, 784, 741, 763, 770, 833, 882, 943, 976a, 976c, 1266,
1266, 1321, 1401, 1402, 1471a, 1476, 1661, 1662, 1668, 1671, 1614,
1616, 1617, 1706a, 1729a, 1730, 1731, 1796, 1798, 2006.
ESTERS.
16, 18, (88), 70, 106, 141, 148, 146a, 146b, 149, 176, 826, 236,
236, 237, 244, 270, 286, 286, 289, 806, 860, 864, 860, 866, 887,
404, 414, 418, 489, 447, 448, 478, 488, 626, 627, 678, 606, 610,
661, 662, 666, 666, 667, 668, 698, 699, 700, 746, 748, 760,
764, 766, 767, 762, 766, 768, 774, 782, 799, 844, 864, 869, 887,
890, 939, 941, 948, 960, 966a, 966, 967, 1061, 1092, 1097, 1106,
1107, 1111, (1114), 1188, 1228, 1233, 1246, 1296, 1296, 1298, 1311,
1366, 1366, 1371, 1372, 1388, 1390, 1397a, 1428, 1470, 1623, 1680,
1669, 1688, 1690, 1694, 1646, 1666, 1667, 1660, 1666, 1684, 1776,
1777, 1779, 1814, 1816, (1818), 1828, 1829, 1830, 1831, 1884, 1838,
1842-1844, 1846, 1847, 1849, 1868a, 1868, 1869, 1860, 1864, 1879,
1888, 1889, 1897, 1907, 1909, 1914, 1916, 1930, 1982, 1934, 1936,
1938, 1941.
ETHERS; of alcohols, as ethyl ether EtCEt; and of phenols, as anisidine
NH2.C6H4.OMe.
33, 46, 70, 188, 278, 806, 360, 862, 866, 601, 681, 584,
586, 648, 606 807, 648, 786, 746, 760, 760, 816, 887, 948, 986,
1010, 1061, 1098, 1816, 1844, 1421, 1446, 1447, 1606, 1666, 1569,
1696, 1601, 1646, 1718. 1777, 1805, 1842-1844, 1847, 1867, 1898,
1897, 2031.
FLAMES.
682.
Conductivity of flames containing organic compoimds.
SUBJECT INDEX 547
FLUORESCENCE.
Effect of fluoresoenoe on conductivity.
825, 888, 859a, 1821, 1471a, 1476.
GUMS, OILS, RESINS, WAXES etc
111, 124, 181, 145b, 606, 981, 1010, 1471, 1491.
HALOGEN DERIVATIVES OF ACIDS; as acetyl cUoride.
1842-1844, 1898, 1897.
HYDROCARBONS.
a) No substituting group.
105, 107, 188, 147a, 181, 182, 211, 268, 278, 801, 805, 888, 884,
886, 417, 500, 606, 687, 669, 671, 672, 678, 842, 859a, 872, 873,
878a, 895, 902, 985, 986, 941, 948, 978, 988a, 1010, 1021, 1098,
1228, 1234, 1314, 1844, 1888, 1491, 1556, 1569, 1604, 1605, 1829,
1880, 1842, 1888, 1898, 1897, 2031.
b) Halogen; as chlorobenzene and ethyl iodide.
27, 78, 211, 291, 805, 884, 386, 534, 604, 606, 687, 668, 669,
740, 767a, 775, 780, 796, 840, 872, 943, 1223, 1250, 1329, 1388,
1437, 1464, 1477, 1569, 1676, 1733, 1829, 1880, 1842, 1893, 1897.
c) Nitro; as nitrobenzene.
105, 149, 291, 517, 604, 606, 607, 610, 637, 683, 684, 752, 754,
771, 772, 775, 780, 782, 795, 796, 844, 928, 941, 1092, 1094,
1106, 1107, 1223, 1388, 1423a, 1425, 1464, 1553, 1569, 1590a,
1646, 1686, 1848, 1844, 1858a, 1897.
d) Containing sulphur; as thiophene.
1388, 1897.
IMIDES; as sacdnimide.
149, 818, 606, 607, 610, 687, 754, 781, 963, 1029, 1032, 1085,
1094, 1095, 1096, 1097, 1143, 1750, 1752, 1755, 1778, 1838, 1996.
INDICATORS; as phenolphthalein.
57, 70, 186, 268, 278, 299, 825, 382, 473, 496, 524, 532, 560,
590, 598, 594, 595, 606, 618, 637, 724, 738, 746, 750, 803a,
818, 822, 833, 847, 882, 986, 943, 950, 1116, 1143, 1144, 1160,
1160, 1230, 1250, 1251, (1259a), 1260, 1265, 1266, 1275, 1321,
(1332a), 1381, 1402, 1471a, 1476, 1506, 1559, 1560-1564, 1643, 1705,
1705a, 1729a, 1770, 1777, 1782, 1796, 1798, 1842, 1897, 1916, 1984.
IONIZATION CONSTANT.
I. Constant of second H and OH ion in polybasic acids and bases.
178, 870, 1281, 1885, 1838, 1745, 1775-1779, 1866, 1911, 1918,
1917.
648 SUBJECT INDEX
II. Ionization constant of water.
46, 269, 819, 822, 949, 999, 1048, 1116, 1129, 1144, 1269, 1816,
1841, 1376, 1777.
III. Measurements of the ionization constant by methods other than by the
electrical conductivity of a dilute solution of the acid or the base. Most
of these are measurements of the hydrolysis of salts. They are classified
by the method used.
a) Absorption of ammonia and of carbon dioxide.
189, 802, 802a, 661, 926.
b) Elevation of the boiling-point.
292, (892), (898), 917, (1049), 1987.
c) Catal3rBis and saponification.
16, 17, 19, 48, 177, 272, 860, 892, 409, 414, 428, (698), (661),
661, 662, 666, 666, 724, 788, 762, 864, 866, 866ft, 890, 1043,
1141, 1148, 1160, (1800), 1864, (1690), 1694, 1691, 1707, 1864,
1890, 1996, 1996, 1997.
d) Colorimetric.
74, 98a, 214a, 274, 278, 489, 496, 804, 822, 960, 961, 1061, 1061-
1069, 1148, 1280, 1846, 1606, 1662, 1668, 1614, 1616, 1617, 1648,
1668, 1666, 1729a, 1729b, 1780, 1778-1779, 1781, (1782), 1916.
e) Electrical conductivity of salts.
177, 269, 270, 271, 860, 870, 409, 486, 486, 489, 682, 664, 1086,
1148, 1160ft, 1288, 1298, 1690, 1666-1660, 1964, 2009.
f) Depression of the freesing-point.
68, 177, 186, 292, 297, 408, 461, 612, 628, 629, 668, 688, (761),
(898), (919), 1802, 1972, 1978, 1988, 2011.
g) Creneral and unclassified.
272, 296, 410, 412, 486, 624, 668, 698, 926, 1177, (1809), 1666-
1660, 1718, 1779, 1827, 2002, 2009, 2011.
h) H ion concentration by measurement of electromotive force.
177, 848, 484.
i) Optical rotation.
768, 869, 1086, 1681, 1687, 1746, 1866, 1880, 1890, 2009, 2011.
j) Partition.
870, 646, 648, 688, 684, 890, 1281, 1820, 1866.
k) SolubiUty.
428, 669, 660, 890, 967, 1116, 1997.
SUBJECT INDEX 649
KETONES; as acetone and benzophenone.
87, 46, 09, 74, 147a, 806, 884, 886, 847, 862, 887, 888, 476,
478, 487, 647, 606, 687, 669, 698, 762, 764, 766, 780, 782, 799,
844, 887, 904, 916, 918, 920, 922, 941, 948, 1086, 1061, 1066,
1070, 1092, 1106, 1187, 1141, 1148, 1296, 1298, 1828, 1886, 1888,
1428a, 1477, 1686, 1668, 1669, 1688, 1690a, 1620, 1646, 1668, 1666,
1676, 1748, 1768, 1880, 1842-1844, 1847, 1868a, 1897, 1904.
LIGHT.
Influence of light on conductivity.
176, 276, 826, 878, 874, 416, 471, 888, 1226b, 1226c, 1226, 1821,
1822, 1824, 1471a, 1476.
MAGNETIC FIELD.
Influence of magnetic field on conductivity.
160.
MOLTEN SALTS.
(40), (41), (42), (66), 100, 110, (166), (169), (221), (689), (674),
(676), (676), (679), (711-728), 977, 988a, 1066, (1127), (1128),
(1128a) (1180-1182), 1176, 1488, 1678, 1711, (1886), 1894.
NEUTRALIZATION.
This includes the measurement of the effect on electrical conductivity, of
the addition of an acid to a base or vice versa.
166, 168, 169, 170, 171, 172, (178), 294, 296, 299, 299a, 408, 464,
468, (476a), 476, 477, 494, 496, 499, 612, 622, 628, 624, 628,
682, 668, 976, 1017, 1086, 1227, 1228, 1260, 1261, (1271), 1401,
1608, (1649), (1691), 1686, 1716, 1717, 1718, 1719, 1868.
NTTRILES.
88, 70, 482, 617, 681, 606, 610, 669, 688, 684. 698, 786, 768,
769, 779, 948, 1060, 1084, 1106, 1107, 1828, 1888, 1428a, 1669,
1688, 1690a, 1646, 1788, 1842-1846, 1847, 1849, 1868a, 1864, 1880,
1897, 1996.
OZIMES.
70, 176, 647, (699), 604, 606, 686, 687, 688, 783, 762, 764, 768,
768, 782, 866, 1160, 1188, 1190, 1748, 1848, 1844, 1996.
PHENOLS and their ethers and salts; as phenol Ph.OH, anisole Ph.OMe
and soditmi phenolate Ph.ONa.
27, 29, 70, 106, 147a, 166, 168, 169, 297, 299, 802, 802a, 402,
449, 460, 492, 496, 601, 612, 624, 681, 646, 647, 648, 677, 602,
604, 606, 607, 609, 614, 687, 648, 664, 666, 668, 661, 680, 729,
788, 786, 744, 746, 760, 768, 764, 766, 766, 777, 782, 789, 810,
550 SUBJECT INDEX
847, 911, Ml, 948, 978a, 978c, 1017, 1042, 1048, 1071, 1118, 1144,
1160, 1160a, 1184, 1280, 1260, 1261, 1882, 1888, 1487, 1488, 1608,
1688, 1682, 1689, 1679, 1680, 1688, 1801, 1820, 1718, 1719, 1747,
1748, 1777, 1798, 1797, 1798, 1802, 1818, 1823, 1827, 1888, 1842,
1886, 1898, 1897, 1918.
PHENYLH7DRAZ0NES; as nitro-acetaldehyda phenylhydrazone.
78, 82^ 176, 648, 928.
PRESSURE.
Effect of pressure on conductivity.
(219), 220, 642, (678), (984), (1020), (1162), (1168), (1164), 1427,
1472, 1609, (1610), 1690a, 1708, 1708a, (1710).
QUINONES; as benzoquinone and croconic add.
889, 624, 648, 647, 677, 608, 887, 729, 768, 1060, 1276, 1662.
RADIO-ACTIVITY, X- RAYS ETC.
E^ffect on conductivity.
148, 164, (166), 216, 418, 417, 887, 884, 872, 878, 874, 1478,
1491, (1611), 1661, 1722, 1806, 2081.
SALTS.
a) Of acids.
10, 11, 18, 48, 46, 64, 88, 70, 98, 94, 142, 148, 146a, 146b, 149,
160, 168, 160, 184, 186, 188, 187, 188, 189, 170, 171, 172, 179, 188a,
191, 194, 218, 217, 220, 222, 228, 228, 228, 248, 247, 270, 276,
289, 294, 299, 818, 816, 819, 820a, 820b, 386, 888, 870, 872,
376, 877, 878, 879, 881, 888, 888a, 889, 891, 894, 414, 418, 428,
427, 480, 488, 448, 447, 448, 449, 464, 468a, 468, 488, 488, 489,
471, 474, 478, 482, 487, 491, 494, 496, 602, 610, 618, 616, 628,
626, 628, 682, 640, 642, 662, 668, 668, 666, 688, 671, 678, 688,
690, 601, 804, 608, 807, 810, 817, 886, 887, 842, 848, 846, 847,
666, 660a, 681, 682, 689, 890, 696, 899, 701, 706, 729, 781, 788,
742, 762, 768, 768, 784, 786, 789, 772, 778, 774, 781, 798, 796,
810, 820, 828, 826, 889, 841, 844, 848, 869, 886, 876, 881a,
889, 890, 901, 908, 907, 908, 911, 922, 924, 931, 982, 936, 948,
946, 947, 948, 949, 966, 968, 969, 988, 971, 978c, 990, 991, 993,
996, 997, 1008, 1004, 1007, 1011, 1028, 1024, 1047, 1068, 1064,
1068, 1067, 1066, 1070, 1078, 1084, 1088, 1087, 1088, 1090, 1091,
1094, 1097, 1108, 1111, 1118, 1128, 1184, 1148, 1144, 1166, 1162,
1163, 1184, 1174, 1188, 1190, 1192, 1199, 1209, 1218, 1216, 1227,
1229a, 1273, 1276, 1278, 1279, 1280, 1296, 1296, 1309a, 1381, 1882,
1837, 1888, 1841, 1841b, 1848, 1866, 1887, 1388a, 1869, 1386, 1888b,
1888, 1890, 1892, 1898, 1402, 1418, 1427, 1484a, 1487, 1489, 1461,
1466, 1488, 1470, 1480, 1486, 1492, 1498, 1494, 1496, 1606a, 1608,
1616, 1618, 1617, 1619, 1628, 1627, 1687, 1639, 1646, 1660, 1689,
1673, 1673a, 1677, 1681, 1689, 1818a, 1820, 1888, 1840, 1841,
1846, 1848, 1864, 1690, 1898, 1694, 1896, 1700, 1701, 1709, 1711,
SUBJECT INDEX 651
1717, 1718, 1720, 1728, 1734, 1735, 1736, 1737, 1747, 1748, 1749,
1762, 1791, 1796, 1807, 1809, 1823, 1826, 1832, 1834, 1836, 1837,
1838, 1839, 1841, 1844, 1866, 1886, 1894, 1940, 1944, 1947, 1948,
1963a, 1966, 1969, 1962, 1969, 1984, 1986, 1994, 2009.
b) Of bases.
32, 33, 44, 86, 146a, 146b, 166, 186, 269, 270, 271, 286, 299a,
304, 314, 3^6, 336, 360, 401, 402, 406, 428, 434, 436, 439, 486,
613, 632, 690, 699, 606, 610, 660, 660a, 734, 738, 740, 741, 747,
763, 769, 763, 764, 767a, 770, 822a, 882, 923, 943, 948, 966a, 1011,
1076, 1083, 1086, 1093, 1143, 1144, 1224, 1237, 1266, 1266, 1266,
1293, 1327, 1388, 1402, 1423a, 1631, 1662a, 1671, 1678, 1690a,
1601, 1611, 1646, 1669, 1680, 1697, 1698, 1731, 1775-1779, 1791,
1801, 1802, 1826, 1823, 1829, 1833, 1834, 1842, 1844, 1841^1849,
1861, 1863a, 1866, 1864, 1884, 1903, 1903a, 1984, 2006, 2029.
c) Complex salts and salts of complex compounds. Salts both of acids
and of bases are given here, and complexes as of aluminmn bromide
with benzene.
69, 88, 89, 149, 246, 247, 320a, 320b, 427, 611, 620, 660, (688),
691, 692, 708, 766, 786, 816, 836, 938, 1008, 1023, 1060, 1076,
1086, 1094, 1096, 1096, 1097, 1162, 1163, 1164, 1192, 1198, 1269,
1314, 1379, 1384, 1386, 1416, 1417, 1436, 1436, 1437, 1446, 1446,
1447, 1463, 1481, 1482, 1486, 1487, 1494, 1496, (1614), 1616,
1616, 1617, 1618, 1619, 1620, 1621, 1622, 1624, 1626, 1627, 1628,
1630, 1630a, 1660, 1672, 1673, 1677, 1681a, 1641, 1648, 1709,
1711, 1760-1767, 1769, 1760a, 1761, 1762, 1944, 1946-^1949.
SOLUBILITY.
This includes only electrical measurements of solubility. Measurements
of the conductivity of difficultly soluble compounds are also given.
10, 216, 217, 469, (630), 666, 848, 990, 991, 993, 1008, 1004,
1174, (1331), 1496.
Measurements of conductivity in
SOLVENTS OTHER THAN WATER.
a) Inorganic solvents.
16, 27, 29, 30, 32, 33, 147a, 167, 167a, 222, 223, 297, 316, (393),
470, 471, 472, 486, 602, 604, 606, 807, 609, 610, 660, 669, 671,
672, 673, (706), 760, 887, 943, (974), (1079), (1204), (1206), 1233a,
1237, (1348), (1446), 1446, (1696), 1646, 1646, 1676, 1733, 1826,
1827, 1828, 1829, 1833, 1834, 1842, (1863c), 1866, 1897, (1946).
b) Organic solvents. — Not diluted.
16, 18, 20, (34), (38), 73, 76, 82, (90), 122, (147), (223), 289,
290, 291, (291a), (293), 321, 326, (327), 334, 336, 336, (337),
338, 339, 344, 346, (347), 360, (361), (362), (363), (364). (366).
662 SUBJECT INDEX
866, 869, (886), (890), 418. 485, 481, (488), 488, 470, 471, 472,
474, 476, 478, 480, (481), 488, 488, 487, 488, 491, (680), (680),
606, 687, 647, 664, 666a, 667, 668, 669, (697), (711-728), 740,
746, 768, 764, 764, 767a, 782, (788), 787, 788, 789, (817a), 888,
840, (842), (904), 908, (912), (916), (916), (918), (920), 922, 923,
981, 982, (988), 984^ 986, 986, 989, (941), (942), 948, 968, 1012,
1018, (1016), 1021, 1022, (1026), (1026), (1044), (1061), 1056, 1057,
1070, 1071, 1084, 1106, 1228, 1250, (1255), 1268, (1278), 1280,
(1808), 1811, 1814, 1816, 1821, (1828), (1824), 1829, 1879, 1886b,
1888, (1889), 1890, 1421, 1428a, (1482), 1484a, 1485, 1487, 1444a,
(1445), (1469), 1470, (1477), (1488), 1506d, 1526, 1580, (1584),
1652a, 1569, 1579, 1580, 1589, 1590a, (1592), (1609a), (1612),
1620, 1622-1626, (1661), 1654, 1712, 1724, 1788, 1746, 1769, 1768,
(1764), (1766), (1794), 1797, 1801, 1802, 1807, 1809, 1816, (1818),
1827, 1880, 1884, 1842, 1848, 1844, (1846), 1846, 1847, 1848, 1849,
1851, 1858a, (1858c), 1884, (1898), 1894, 1900, 1908a, 1904, 1970,
1971, (1987), 1991, (1998), 2008, 2029, (2081).
c) Organic solvents. — Diluted with water.
16, 46, 82, 94, 228, (881), 844, 891, 613, 582, 647, 656a, 754,
764, 777, 782, 822, (876), 908, (912), (915), (916), (918), (920),
922, 923, 926, 932, 1066, 1071, 1185, (1221), 1279, 1280, 1286,
1298, 1816, 1390, 1419, 1452, 1464, (1488), 1508, (1541), 1579,
(1582), (1609a), 1627, 1649, (1653), 1654, (1681), 1718, 1724, 1746,
1768, 1791, 1820, 1841, 1884, 1886, (1916), 1994.
SPECIFIC coNDucTivrry of pure compounds.
a) Acids.
44, 211, 847, 860, 862, 369, 517, 681, 694, 763, 787, 894, 908,
943, 966, 1830, 1880, 1888, 1419, 1470, 1575, 1848, 1844, 1858c,
1957, 2008.
b) Alcohols.
18, 20, 21, 263, 289, 290, 806, 836, 837, 888, 847, 861, 862, 866,
891, 418, 426, 488, 456, 456, 478, 491, 680, 597, 647, 656a, 754.
764, 783, 787, 842, 904, 908, 912, 916, 917, 918, 920, 922, 941,
955, 956, 986, 1010, 1021, 1106, 1107, 1816, 1844, 1388, 1390,
1419, 1420, 1421, 1423a, 1484a, 1470, 1472, 1684, 1556, 1569,
1579, 1580, 1589, 1690a, 1592, 1620, 1649, 1651, 1724, 1746, 1766,
1791, 1800, 1807, 1848, 1844, 1849, 1853a, 1884, 1900, 1903a, 1970,
1971, 1987, 2029, 203L
c) Aldehydes.
517, 784, 941, 1106, 1107, 1888, 1669, 1590a, 1842-1844, 1847, 1858a.
d) Amides.
211, 1506d, 1848, 1844, 1858b, 1853c, 1894.
SUBJECT INDEX 658
e) Anhydrides.
211, 1090a, 1848, 1844.
f) Bases — containing nitrogen.
211, 806, 847, 898, 478, 806, 764, 786, 817a, 942, 948, 1067,
1084, 1106, 1176, 1260, 1816, 1888, 1889, 1472, 1477, 1669, 1612,
1848, 1844, 1868c, 1900.
g) Esters.
806, 860, 866, 989, 941, 1106, 1107, 1228, 1888, 1470, 1669, 1880,
1884, 1848, 1844, 1847, 1868a.
h) Ethers.
806, 860, 862, 866, 684, 686, 816, 986, 1010, 1098, 1816, 1844,
1421, 1666, 1669, 1696, 1842-1844, 2081.
i) Halogen derivatives of acids; as acetyl chloride.
1842, 1848, 1844.
j) Hydrocarbons.
211, 268, 291, 806, 884, 886, 617, 684, 740, 842, 872, 878a, 928,
986, 941, 978, 988a, 1010, 1098, 1106, 1107, 1284, 1844, 1888,
1428a, 1487, 1477, 1666, 1669, 1690a, 1604, 1606, 1880, 1843,
1844, 2081.
k) Ketones.
806, 884, 886, 847, 862, 476, 478, 487, 904, 916, 918, 920, 922,
941, 1066, 1070, 1106, 1828, 1888, 1428a, 1477, 1669, 1690a, 1620,
1880, 1848, 1844, 1847, 1868a.
1) Nitnles.
867, 869, 482, 617, 669, 1064, 1106, 1107, 1828, 1888, 1428a, 1669,
1690a, 1788, 1842, 1848, 1844, 1846, 1847, 1849, 1868a.
m) Oximes.
lo43, lo4s.
n) Compounds containing sulphur. This includes CSs.
268, 801, 806, 884, 886, 417, 872, 989, 1010, 1098, 1106, 1228,
1844, 1888, 1491, 1666, 1806, 1848, 1844, 1846, 1847, 1868a.
o) Unclassified.
28, 211, 868, 1272, 1669.
SULPHUR COMPOUNDS; as mercaptans, sulphides etc
Sulphinic and sulphonic acids are not given here, but under the head of
ACIDS containing sulphur.
149, 268, 270, 801, 806, 884, 886, 886, 860, 869, 884, 886, 417,
481, 604, 606, 762, 760, 872, 989, 948. 1010, 1098, 1228, 1802,
654 SUBJECT INDEX
1U4, 1868, 1879, 1888, 1487, U91, 1649, 1656, 1806, 1888,1842,
1848, 1844, 1868a, 1866, 9089.
TBUPBRATURB.
Under this heading are arranged in four groups those references bearing
on the effect of temperature on conductivity, or containing measurements of
the ionization constant or of conductivity at temperatures other than those
generally used. The author list shows, whenever possible, the particular
temperatures or the limits of temperature.
a) At or near the critical temperature.
107, 188, 684, 686, 686, 610, (706), (707), (1086), (1086), 1866.
b) Gleneral articles.
868, 889, 880, 616, (870), 876, 889, (909), (1162), (1168), (1164),
1177, 1471, 1472, (1666), (1906), 1968.
c) High temperature (above 26^).
(19), 48, 44, 62a, 64, 108, 106, 106, 110, 122, 124, 148, 146a,
146b, 160, 164, 179, 217, 260, 268, 266, 266, 267, 268, 290a,
806, 807, 806, 809, (881), 876a, 888a, 410, 412, 488, 447, 469,
476, 478, 480, (481), 482, 607a, 616, 628, 682, 684, 686, 662,
668, 698, 609, 617a, 619, 626, 666, 696, 701, 788, 764, 776, 787,
789, 807, 808, 869a, 873, 876, (876), 880, 881, (909), 911, 924,
982, 946, 976a, 988a, 998, 1004, (1016), 1024, 1187a, 1148, 1144,
1160, 1188, 1209, 1226, 1227, 1229a, 1289a, 1269, 1296, 1826,
1881, 1882, 1887, 1888, 1841, 1841b, 1842, 1866a, 1866, 1890,
1891a, 1428, 1484a, 1462, 1462, 1471, 1472, 1488, 1606a, 1606b,
1606c, 1682, 1637, 1670, 1678, 1681, 1690a, 1692, 1696, 1699,
1627, 1664, 1708, (1766), 1796, 1797, 1796, 1800, 1809, 1884, 1843,
1844, 1846, 1868a, 1866, 1880, 1886, 1894, 1968a, 1967, 1968, 1968a,
(1969), 1996, 1997, 2002, 2082.
d) Low temperature (below 17^).
27, 29, 80, 82, (48), 82, 88, 108, 106, 106, 110, 122, 124, 141,
148, 146a, 146b, 147a, 168, 164, 166, 167, 168, 177, 179, 220,
260, (298), 801, 816, 826, (881), 347, 860, 861, 369, 370, 387,
426, 438, 446, 461, 466, 461, 478, 480, (481), 482, 486, 600, 601,
602, (612), 618, 616, 624, 628, 632, 640, 641, 642, (680), 681, 682,
697, (6997), 602, 604, 607, 610, 622a, 626, 636, 646, 669, 671,
680, 683, 684, 701, 709, 726, 780, 733, 736, 736, 762, 766, 763,
764, (766), 766, 768, 769, 770, 772, 773, 774, 776, 776, 780,
786, 787, 793, 796, 833, 838, 839, 848, 873, 876, (876), 877, 887,
901, 902, 903, (906), 908, (909), 910, 911, 916, 918, 920, 922,
923, 924, 982, 943, 949, 966a, 976, 998, 1004, (1016), 1018, (1041),
1076, 1092, 1148, 1144, 1160, 1164, (1206), 1222, 1283a, 1269,
1272, 1296, 1309a, 1380, 1838, 1842, 1366, 1416, 1419, 1464, 1468,
1472, 1477, 1482, 1499, 1619, 1620, 1628, 1624, 1663, 1668, 1669,
1676, 1677, 1690, 1690a, 1696, 1612, 1684a, 1646, 1661, 1664,
SUBJECT INDEX. 555
1668A-1665C, leeO, 1676, 1708, 1706a, 1787, 1741, (1766), 1769,
177^1779, 1798, 1807, 1826, 1887, 1888, 1829, 1888, 1842, 1843,
1844, 1846, 1847, 1848, 1849, 1868a, 1863c, 1866, 1887, 1897,
1969, (1961), 1962, 1968, 1968a, 1980, 1986, (1989), 2004, 2006,
2009, 2032.
THIN LAYERS.
GonductiTity of thin layers.
801, 416, 1480.
JOURNAL LIST.
This gives a complete list of all the journals examined.
The journals are arranged in alphabetical order, disregarding particles such
as, andy de, der, etc.
After the title of each journal is given the number and date of the last vol-
ume examined, with the page number, or division number, if the complete
volume has not been examined.
Journals having the title preceded by the sign fH (as, ^ Annates de, etc.)
are not complete through the year 1910 either because it has been impossible
to examine one or more volumes, or because the volume covering the year 1910
has not been issued. A note of the number or of the date of missing volumes
is given.
At the end is added a list of the authors of articles in the Journal of the
Russian Physico-chemical Society, arranged chronologically, with the page
numbers of the articles. This is given because the variations in names, due
to different systems of transliteration, make checking of references to this
journal slightly difficult.
JOURNAL LIST.
Abhandlungen der k5niglicheii Gesellschaf t der Wissenschaften bu G5ttingen.
Math.-Phys. Klasse.
Through N. F., Volume 0, no. 2, (1011).
Abhandlungen der koniglich preussiachen Akademie der Wissenschaften.
(Berlin).
Through (1910).
Abhandlungen der kdniglich s&chsisehen Gesellschaft der Wissenschaften.
Mathematisch-physische Classe.
Through Volume 32, page 506, (1010-1911).
Abhandlungen der mathematisch-physikalischen Classe der kdniglich bayer-
ischen Akademie der Wissenschaften. (MQnchen).
Through Volume 25, no. 10, (1909-1912),
American Chemical Joiurnal.
Through Volume 44, (1910).
The American Joiunal of Physiology.
Through Volume 27, (1910-1911).
The American Journal of Science.
Through Volume 30, (1910).
The Anal3rst.
Through Volume 35, (1910).
Annaes scientifioos da academia polytecnica do Porto. (Coimbra).
Through Volume 5, (1909-1910).
Annalen der (Dhemie. (Justus Liebig's).
Through Volume 378, (1910).
Annalen der Ph3rsik.
[This journal is often referred to by the name of the editor, first Poggen-
dorff, then Wiedemann, then Drude. There has been a board of
editors since the year 1909. Before the beginning of the fourth
series the title was, Annalen der Physik und Chemie.]
Through Series 4, Volume 33, (1910).
Annalen der Physik und Chemie. Ergftnzungsband.
Through Volume IX.
Annales de chimie et de physique.
Through Series 8, Volume 21, (1910).
at Annates de Tuniversit^ de Lyon.
Through N. S., Fascicule 29, (1909).
Annals of the New York Academy of Sciences.
Through Volume 20, (1910).
Arbeiten aus dem kaiserlichen Gesundheitsamte.
Through Volume 36, (1910-1911).
Archiv ftUr Anatomie und Physiologie. Physiologisohe Abteilung.
Through (1910).
Archiv f Or die gesammte Physiologie des Menschen und der Tiere. (PflQger'8
Archiv).
Through Volume 135, (1910).
668 JOURNAL LIST
Archiv der Phannasie.
Through Volume 248. (1910).
Archives du Muate Teyler. (Haarlem).
Through Series 2, Volume 11, (1907-1900).
Archives nto'landaises des sciences ezaotes et naturelleBr
Through Volume 15, (1910).
Archives des sciences physiques et natureHes. (BibliothdquQ universelle).
Through Series 4, Volume 30, (1910).
Archivio di fisiologia.
Through Volume 8, (1909-1910).
Ariciv fdr kemi, minendogi och geologi.
Throu^ Volume 3, (1908-1910).
Arkiv f5r matematik, astronomi och fysik.
Through Volume 6, (1910-1911).
Atti della accademia Gioenia di sdenae naturali in Catania.
Through Series 5, Volume 3, (1910).
Atti della pontificia accademia lomana dei nuovi Lined.
Through Volume 63, (1910).
Atti della reale accademia dei Ldnoei. Memorie. See Memorie della reale
accademia, etc.
Atti della reale accadenua dei Lincei. Rendiconti. See Rendiconti della
reale accademia, etc.
m Atti della reale accademia delle sdenae fidche e matematiche. SodetiL reale
di Napoli.
Through Series 2, Volume 14, (1909).
Atti della reale accademia di sdenze, lettere e belle arti di Palermo.
Through Volume 9, (1912).
Atti della reale accademia delle sdense di Torino.
Through Volume 45, (1909-1910).
Atti dd reale istituto veneto di science, lettere ed arti.
Through Volume 69, (1909-1910).
Beitr&ge zur chemischen Phydologie und Pathologic. Zdtschrift fOr die
gesamte Biochemie.
Through Volume 11, (1908). Publication discontinued.
Berichte der deutschen chemischen Gesdlschaft.
Through Volume 43, (1910).
Berichte der deutschen physikalischen Geselkchaft see Verhandlungen der
deutschen physikalischen Gesdlschaft.
Through Volume 8, (1910).
Berichte der naturforschenden Gesdlschaft su Freiburg.
Through Volume 18, (1909-1910).
Berichte tlber die Verhandlungen der kdniglich sachsischen Gesellschaft der
Wissenschaften zu Ldpzig. Mathematisch-physische Klasse.
Through Volume 62, (1910).
Bihang till kongl. svenska vetenskaps-akademiens handlingar. (Stockholm).
Through Volume 28, (1902-1903). Publication discontinued.
Biochemische Zeitschrift.
Through Volume 28, (1910).
BoUettino delle sedute della accademia Gioenia di scienze naturali in Catania.
Through N. S., Fasc. 15, (1911).
Bulletin de Tacad^mie royale des sciences, des lettres et des beaux-arts de
Bdgique. Bulletins de la classe des sciences. [The volumes are not
numbered after the year 1898.]
Through (1910).
JOURNAL LIST 569
Bulletin of the Chicago Academy of Sciences.
Through Volume 3, no. 5, (190^1^).
Bulletin international de I'acad^mie des sciences de Craoovie. Sdrie A; scien-
ces math^matiques. S6rie B; sciences naturelles.
Through A, (1910).
" B, (1910).
Bulletin des stances de la soci6t6 fran^aise de physique. [Before 1893 the
title was, Stances de la soci6t^ frangaise de physique.]
Through (1910).
Bulletin des stances de la soci^t6 des sciences de Nancy.
Through Series 3, Volume 11, (1910).
Bulletin de la soci^t6 chimique de France. [Before 1910 the title was, Bulletin
de la soci^t6 chimique de Paris.]
Through Series 4, Volume 7, (1910).
Bulletin de la 80ci^t6 des sciences de Nancy. [Continued in, Bulletin des
stances de la soci^t^ des sciences de Nancy.]
Through Series 2, Volume 16, (1899).
Bulletin de la soci6t6 vaudoise des sciences naturelles. (Lausanne).
Through Series 5, Volume 46, (1910).
The Chemical News.
Through Volume 102, (1910).
Chemiker-Zeitung.
Through Volume 34, (1910).
Comptes rendus hebdomadaires des stances de Tacad^mie des sciences. (Paris).
Through Volume 151, (1910).
Denkschrif ten der kaiserlichen Akademie der Wissenschaf ten. Mathematisch-
naturwissenschaftliche Klasse. (Wien).
Through Volume 86, I, (1911).
Drude's Annalen see Annalen der Physik.
EIrgebnisse der Physiologic.
Through Volume 9, (1910).
Forhand linger i Videnskabs-Selskabet i Christiania.
Throug^ (1910).
Gazzetta chimica italiana.
Through Volume 40, (1910).
Giomale di scienze naturali ed economiche. (Palermo).
Through Volume 28, (1911).
Gdteborgs kungl. vetenskaps- och vitterhetssamh&lles handlingar.
Through Series 4, Volume 13, (1910).
Helios. Organ des naturwissenschaftlichen Vereins des Regierungsbezirkes.
(Frankfurt).
Through Volume 26, (1910).
Hoppe-Seyler's Zeitschrif t see Zeitschrift fiir physiologische Chemie.
Isis see Sitzimgsberichte und Abhandlungen etc.
The Joiu-nal of the American Chemical Society.
Through Volume 32, (1910).
The Journal of Biological Chemistry.
Through Volume 8, (1910).
Journal of the Chemical Society. (London).
Through Volume 97, (1910).
Journal de chimie ph3rsique.
Through Volume 8, (1910).
The Journal of Industrial and Engineering Chemistry.
Through Volume 2, (1910).
560 JOURNAL LIST
The Journal of Physical Chemistry.
Through Volume 14, (1910).
The Journal of Physiology.
Through Volume 40, (1910).
Journal de ph3rsique.
Through Series 4, Volume 9, (1910).
Journal fUr praktische Chemie.
Through Series 2, Volume 82, (1910).
Journal of the Russian Physico-chemical Society.
Through Volume 42, (1910).
See also the end of this section.
The Journal of the Society of Chemical Industry.
Through Volume 29, (1910).
The Journal of the Society of Dyers and Colourists.
Througji Volume 26, (1910).
Justus Liebig's Annalen see Annalen der Chemie.
KoUoidchemische Beihefte see Zeitschrift fUr Chemie und Industrie der
Kolloide.
Kolloid Zeitschrift see Zeitschrift ftlr Chemie imd Industrie der Kolloide.
Det kongelige danske videnskabemes Selskabs Skrif ter.
Throu^ Series 7, Volume 8, (1909-1911).
Kungliga svenska vetenskapsakademiens handlingar.
Through N. F., Volume 46, (1910-1911).
Liebig's Annalen see Annalen der Chemie.
The London, Edinburgh and Dublin Philosophical Magazine see PhiloBophi-
cal Magazine.
Meddelanden fr&n k. vetenskapsakademiens Nobelinstitut.
Through Volume 1, (1906-1909).
M^moires de Facad^mie nationale des sciences, arts et belles-lettres de Caen.
Through (1910).
M^moires de Tacad^mie des sciences, belles-lettres et arts de Lyon.
Through Series 3, Volume 11, (1911).
M^moires couronn^ et autres m^moires public par Vacad^mie royale des
sciences, des lettres et des beaux-arts de Belgique. In 8^. Classe
des sciences.
Through Series 2, Volume 2, (1907-1910).
M^moires de la soci^t§ royale des sciences de Li^ge.
Through Series 3, Volume 9, (1912).
Memoirs of the American Academy of Arts and Sciences.
Through N. S., Volume 13, (1908).
Memoirs and Proceedings of the Manchester Literary and Philosophical
Society.
Through Volume 54, (1909-1910).
m Memorias de la real academia de ciencias exactas, ffsicas y naturales de
Madrid.
Through Volume 26, (1908).
Memorie della pontificia accademia romana dei nuovi Lined.
Through Volume 28, (1910).
Memorie della reale accademia dei Lincei. Classe di scienze fisiche, mate-
matiche e naturali.
Through Series 5, Volume 7, (1908-1910).
Memorie della reale accademia delle scienze dell'istituto di Bologna.
Through Series 6, Volume 7, (1909-1910).
JOURNAL LIST 561
Memorie della reale accademia delle scienxe di Torino. Science fisiche/mate-
matiche e naturali.
Through Series 2, Volume 60, (1010).
Memorie della regia accademia di scienze, lettere ed arti in Modena.
Through Series 3, Volume 0, (1010).
Mitteilungen der naturforschenden Gesellschaft in Bern.
Through (1010).
Monatshefte ftlr Chemie.
Through Volume 31, (1010).
Nachrichten von der kdnigl. Gesellschaft der Wissenschaften lu Gdttingen.
Mathematisch-physikalische Klasse.
Through (1010).
Nature.
Through Volume 85, (1010-1011).
Naturwissenschaftliche Rundschau.
Through Volume 25, (1010).
Nova acta regiae societatis scientiarum upsaliensis.
Through Series 4, Volume 2, (1007-1011).
II nucvo cimento.
Through Series 5, Volume 20, (1010).
Ofversigt af finska vetenskaps-societetens fdrhandlingar. (Helsingfors).
Through Volume 52, (1000-1010).
Ofversigt af kongl. vetenskaps-akademiens foriiandlingar. (Stockholm).
Through (1001-1002).
Oversigt over det kongeUke danske videnskabemes Selskabs Forhandlinger.
(Copenhagen).
Through (1010).
Pfliiger's Archiv see Archiv gesammte Physiologic.
The London, Edinburgh and Dublin Philosophical Magazine and Journal of
Science.
Through Series 6, Volume 20, (1010).
Philosophical Transactions of the Royal Society of London see Transactions
of the Royal etc.
The Physical Review.
Through Volume 31, (1010).
Physikalische Zeitschrif t.
Through Volume 11, (1010).
Poggendorff's Annalen see Annalen der Physik.
Proceedings of the American Academy of Arts and Sciences.
Through Volume 45, (lOOO-lOlO).
Proceedings of the American Association for the Advancement of Science.
Through Volume 61, (1010).
Proceedings of the American Philosophical Society.
Through Volume 40, (1010).
Proceedings of the Birmingham Natural History and Philosophical Society.
Through Volume 12, no. 5, (1007-10—).
Proceedings of the California Academy of Sciences.
Through Series 3, Volume 4, (1005).
Proceedings of the Cambridge Philosophical Society.
Through Volume 15, (1000-1010).
Proceedings of the Chemical Society. (London).
Through Volume 26, (1010).
662 JOURNAL LIST
Proceedings of the Davenport Academy of Sciences. (Davenport, Iowa).
Through Volume 12, (1907-1910).
Proceedings of the Indiana Academy of Sciences.
Through (1910).
Proceedings of the Iowa Academy of Sciences.
Through Volume 17, (1910).
Proceedings of the Physical Society of London.
Through Volume 22, (1910).
Proceedings of the Royal Dublin Society see Scientific Proceedings of, etc.
Proceedings of the Royal Irish Academy.
Through Volume 28, (1909-1910).
Proceedings of the Royal Physical Society. (Edinburgh).
Through Volume 18, (190&-1912).
Proceedings of the Royal Society of Edinburgh.
Through Volume 30, (1909-1910).
Proceedings of the Royal Society of London.
Through A, Volume 83, (190^1910).
" B, Volume 82, "
The Proceedings and Transactions of the Nova Scotian Institute of Science.
Through Volume 12, (1907-1909). [Volume 12 contains one paper dated
1911.]
Proceedings and Transactions of the Royal Society of Canada.
Through Series 3, Volume 4, (1910).
Proceedings of the Washington Academy of Sciences.
Through Volume 12, (1910).
Proc^verbaux des stances de la soci6t6 des sciences physiques et naturelles
de Bordeaux.
Through (190^1910).
Recueil des travaux chimiques des Pays-Bas et de la Belgique.
Throiigh Volume 29, (1910).
Rendiconti della reale accademia dei Lincei. Classe di scienze fisiche, mate-
matiche e naturali.
Through Series 5, Volume 19, (1910).
Rendiconti. Reale istituto lombaxdo di scienze e lettero.
Through Series 2, Volume 43, (1910).
Hf. Rendiconti della society chimica di Roma.
Through Volume 6, (1908).
Rendiconto dell' accademia delle science fisiche e matematiche (sezione della
society reale di Napoli).
Through Series 3% Volume 16, (1910).
^ Rendiconto delle sessioni della reale accademia delle science dell'istituto di
Bologna.
Through N. S., Volume 14, (190^1910).
The years 1889 to 1896 inclusive have not been examined.
Revista de la real academia de ciencias exactas, fisicas y naturales de Madrid.
Through Volume 9, (1910-1911).
Schrif ten des naturwissenschaftlichen Vereins fOr Schleswig-Holstein.
Through Volume 15, page 222, (190^1911).
Science.
Through N. S., Volume 32, (1910).
The Scientific Proceedings of the Royal Dublin Society.
Through Volume 12, (1909-1910).
The Scientific Transactions of the Royal Dublin Society.
Through Series 2, Volume 9, (1905-1907). Publication discontinued.
JOURNAL LIST 668
SitsungBberichte und Abhandlimgen der naturwisseDschaftlichen Gesellschaft
Isis'in Dresden.
Through (1910).
SitsuDgsberichie derGesellschaft sur Befdrdenmg der gesammten Naturwissen-
Bchaften. (Maibuig).
Through (1010).
Sitsungsberichte der kdniglich bdhmiBcheii GeseUschaft der WiBsenschaften.
Mathematisch-naturwiasenschaftliche Classe. (Prag).
Through (1910).
Sitsungsberichte der kOniglich preussischen Akademie der Wissenschaften.
(Berlin).
Through (1910).
Sitzungsberichte der mathematisch-naturwissenachaf Uichen Classe der kaiser-
lichen Akademie der Wissenschaften. (Wien).
Through Volume 119, (1910).
Sitzungsberichte der mathematisch-physikalischen Klasse der kdniglich bay-
erischen Akademie der Wissenschaften zu MUnchen.
Through Volume 40, (1910).
Sitsungsberichte der physik-med. (jesellschaft su WQrzburg.
Through (1910).
Transactions of the Academy of Science of St. Louis.
Through Volume 19, (1910).
Transactions of the American Electrochemical Society.
Through Volume 20, (1911).
Transactions of the American Philosophical Society.
Through N. S., Volume 21, (1905-1908). [Volume 22 begins with the
year 1911.]
Transactions of the Cambridge Philosophical Society.
Through Volume 21, (1908-1912).
Transactions of the Connecticut Academy of Arts and Sciences.
Through Volume 16, (1910).
Transactions of the Faraday Society.
Through Volume 6, (1910).
Transactions of the Kansas Academy of Science.
Through Volume 24, (1911).
Transactions of the New York Academy of Sciences.
Through Volume 16, (1896-1897). Publication discontinued.
Transactions of the Royal Dublin Society see Scientific Transactions, etc.
Hf Transactions of the Royal Scottish Society of Arts.
Through Volume 18, (1908-1909).
Transactions of the Royal Society of Edinburgh.
Through Volume 47, (1908-1911).
Philosophical Transactions of the Royal Society of London.
Through Series A, Volume 210, (1910).
" " B, " 201, (1910).
Transactions of the Texas Academy of Science.
Through Volume 11, (1911).
$ Transactions of the Wisconsin Academy of Sciences, Arts and Letters.
Through Volume 16, (1908-1909).
1H Travaux scientifiques de Tuniversit^ de Rennes.
Through Volume 6, (1907).
University Studies. (University of Nebraska).
Through Volume 10, (1910).
564 JOURNAL LIST
Verhandelingen der koninklijke akademie van wetenschappen. (Amsterdam).
Through Series 2, Volume 11, no. 2, (1010-19—).
Verhandlungen der deutschen physikalischen Gesellschaft. [This is some-
times bound with the Berichte der deutschen physikalischen Cresell-
schaft under that title, but with a double title page.)
Through Volume 12, (1910) = Volume 8 of Berichte, etc.
Verhandlungen der Gesellschaft deutscher Natiurforscher und Xrzte.
Through Volume 82, (1910).
Verhandlungen der naturforschenden Gesellschaft in Basel.
Through Volume 20, (1909-1910).
Verhandlungen der physikalischen Gesellschaft zu Berlin. [Ck>ntinued as
Verhandlungen der deutschen physikahschen Gesellschaft.]
Through Volume 17, (1898).
Verslag van de gewone vergaderingen der wis- en natuurkundige afdeeling.
Koninklijke akademie van wetenschappen te Amsterdam.
Through Volume 18, (1909-1910).
Wiedemann's Annalen see Annalen der Physik.
Zeitschrift fUr analytische Chemie.
Through Volume 49, (1910).
Zeitschrift ftir angewandte Chemie.
Through Volume 23, (1910).
Zeitschrift f iir anorganische Chemie.
Through Volume 69, (1910).
Zeitschrift ftir Biologic.
Through Volume 64, (1910).
Zeitschrift fUr Chemie tmd Industrie der Kolloide. (KoUoid-Zeitschrift).
Through Volume 7, (1910).
Kolloidchemische Beihefte.
Through Volume 1, (1909-1910).
Zeitschrift fUr Elektrochemie und ajigewandte physikalische Chemie.
Through Volume 16, (1910).
Zeitschrift fOr die gesamte Biodiemie see Beitrfige sur chemischen Physiolo-
gie und Pathologic.
Zeitschrift ftir Naturwissenschaften.
Through Volume 82, (1910).
Zeitschrift fiir physikalische Chemie.
Through Volume 76, (1910-1911).
Zeitschrift ftir physiologische Chemie. (Hoppe-Seyler's).
Through Volume 69, (1910).
Journal of the Russian Physico-chemical Society.
Through Volume 42, (1910).
1890. Vol.22.
110-116 Chroustchoff, PachkoflP.
115-116 Chroustchoff.
411-430 Kistiakowsky.
1891. VoL28.
126-147 Zelinsky, Besredka.
391-422 Kablukoff.
612-632 Zelinsky.
632-662 Walden.
440-450 Konowalow.
192-201 Konowalow.
(211-222 Konowalow).
(364^78 Markownikoff).
547-564 Markownikoff.
626-d31 Sapolnikov.
(608-611 Zelinsky).
(611-612 Zelinsky).
JOURNAL LIST 665
1892. Vol. 24.
1898. VoL25.
1894. VoL26.
1896. Vol.28.
149-158 Refonnatsky.
293-299 Kukulesko.
329-334 Speranduj.
(414^16 Zelinsky, Krapiwin).
501-509 Gillaov.
579^93 Zelinsky, Krapiwin.
664-683 Szyszkowski.
1898. VoLSO.
(333-334 SchrSder).
453-466 Refonnatsky.
466-175 Michajlenko.
190a VoL82.
328^346 Michajlenko, Javorskij.
(797-804 Speranskij, (3oldb«rg).
1901. V0L88.
158-163 Szyszkowski, Refonnatsky.
242-246 Protopopov, Refonnatsky.
545-547 Centnerszwer.
547-549 Centnerszwer.
466-472 Plotnikow.
651-652 Fedorov.
794-810 Plotnikow.
1902. Vol.84.
1908. Vol.86.
1904. Vol 86.
(255-275 Timofejev, Kobozev).
(605 Gardner, Grerassimoff).
(746-753 Gardner, Gerassimoff).
566
JOURNAL LIST
1906.
Vol 87.
318-337 J
Plotnikow.
492-602 ]
E^ssarjewsky, Lemcke.
875-881 ]
Plotnikow.
1906.
Vol.38.
109^1104
Plotnikow.
1907.
Vol. 89.
936-943
Tanatar, EurovRkij.
1262-1323
Tschugaeff.
1379-1391
Dumanski.
1630-1632
Tanatar, Kurovskij.
1908.
VoL 40.
(192-197
Bogorodfikij).
337
Neminakijy Plotnikow.
391-396
Neminskij, Plotnikow.
(564r-565
Pissarjewsky, Karp).
(599-611
PiRBarjewsky, Karp).
739-740
DoroSevskij, Roidestvenskij.
887-^08
DoroSevskij, Roidestvenskij.
1238-1243
Plotnikow.
(1243-1247
Plotnikow).
(1247-1257
Plotnikow).
1379-1388
Zelinsky, Izgarydev.
1909.
Vol. 41.
(241-244
Timofejev). 1
252-258
Diimannki. Tn the MendeJejefT numbcsr.
285-286
Tschugaeff. J
184-252
Tschugaeff.
253-287
Tschugaeff.
1332-1354
Tschugaeff.
1355-1368
Tschugaeff.
1910.
Vol.48.
683-690
Sachanov.
905-938
Pissarjewsky, Sapovalenko.
1466-1487
Tschugaeff.
1589-1596
Plotnikow.
ADDENDA.
TO AUTHOR UST.
1800iu L. Vignon. Bulletin Soci^t^ Industrielle Mulhouse. 77, 82-84,
(1907).
Teinture etc. [Same as 1709. Same as 1796 for A. ]
1800b. L. Vignon. Bulletin Soci^t^ Industrielle Mulhouse. . 70, 133-139,
(1909).
Conductibilit6 61ectrique etc. [Same as 1798.]
1800c. L. Vignon. Bulletin Soci^t^ Industrielle Mulhouse. 79, 139-142,
(1909).
Sur les propri^t^ etc. [Same as 1797 and 1800.]
1866a. P. Walden, M. Centnerszwer. Bulletin Acaddmie Imp6riale
Sciences St. P^tersbourg. (5), 15, 17-119, (1901).
flUssiges Schwefeldioxyd etc. [Same as 1864 and 1866.]
TO JOURNAL LIST.
The American Journal of Pharmacy.
Through Volume 82, (1910).
Bulletin de I'acad^mie imp^riale des sciences de St. P6terebourg.
Through Series 6, Volume 4, (1910).
Bulletin de la soci^t^ chimique de Belgique.
Through Volume 24, (1910).
Bulletin de la soci^t^ industrielle de Mulhouse.
Through Volume 70, (1910).
Bulletin de la soci^t^ industrielle de Rouen.
Through Volume 38, (1910).
Bulletins of the Minnesota Academy of Science.
Through Volume 4, (1892-1910).
Forhandlingar see alao Ofvereigt etc.
Handlingar see Bihang till kongl. svenska etc., Gdteborgs kungl. etc. and
Kungliga svenska etc.
Journal of the Academy of Natural Sciences of Philadelphia.
Through Series 2, Volume 14, (1909-1912).
Journal and Proceedings of the Royal Society of New South Wales.
Through Volume 44, (1910).
The Kansas University Quarterly.
Through Volume 10, (1901). Publication continued in the following
journal.
The Kansas University Science Bulletin.
Through Volume 6. (1910-1911).
Det kongelige norske videnskapers Selskaps Skrifter.
Through (1910).
568 ADDENDA
M^moiree de I'acad^mie imp^riale dee sciences de St. P^tersbourg. Classe
des sciences physiques et mathtoatiques.
Through Series 8, Volume 25, (1910).
M^moiree de la soci^t^ des sciences physiques et naturelles de Bordeaux.
Through Series 6, Volume 6, Fasc. 1, (1910-19—).
Papers and Proceedings of the Royal Society of Tasmania.
Through (1910).
Precis analytique des travaux de Facad^mie des sciences, belles-lettres et
arts de Rouen.
Through (1910-1911).
Proceedings of the Academy of Natural Sciences of Philadelphia.
Through Volume 62, (1910).
The Proceedings of the Colorado Scientific Society.
Through Volume 9, (1908-1910).
Proceedings of the Royal Society of Queensland.
Through Volume 22, (1910).
Proceedings of the Royal Society of Victoria.
Through N. S., Volume 23, (1911).
Sammelschrift der mathematisch-naturwissenschaftlich-ftrKtlichen Sektion
der ^vSenko-Gesellschaft der Wissenschaften in Lemberg.
Through Volume 14, (1910).
Skrifter see Kongelige duiske etc. and Kongelige norske, etc.
Transactions and Proceedings and Report of the Royal Society of South
Australia.
Through Volume 34, (1910).
Transactions of the Royal Society of Victoria.
Through Vohmie 5, (1910).
University of Illinois. The University Studies.
Through Volume 3, (1908-1910).
University of Missouri Studies. Science Series.
Through Volume 2, No. 2, (1911).
University Studies. University of Cincinnati.
Through Series 2, Volume 6, (1910).
FINIS
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