ee ee ee
THE ae
AMERICAN JOURNAL
SCIENCE AND ARTS.
EDITORS,
JAMES D. DANA, B. SILLIMAN, ann E. 8. DANA.
ASSOCIATE EDITORS,
Prorrssors ASA GRAY, WOLCOTT GIBBS anp
J. P. COOKE, Jr., or CamBriner,
Prorrssors H. A. NEWTON, 8. W. JOHNSON, G. J. BRUSH
anv A. E. VERRILL, or New Haven,
Prorressor GEORGE F. BARKER, or PuiLapELpHtia.
THIRD SERIES.
VOL. XV.—[WHOLE NUMBER, CXV.]
- Nos. 85—90.
JANUARY TO JUNE, 1878.
WITH TWO PLATES.
NEW HAVEN: EDITORS.
1878.
MISSOURI BOTANICAL
AROEN LIBRARY
|
a
CL ae a ere eee) oe
P
Art. I.—Contributions to primed 2h being results derived
CONTENTS OF VOLUME XV.
NUMBER LXXXV.,
from an examination of the Observations of the United
States Signal Service, pee from other sources ; ae Exias
Loomis, Eighth paper. With plates 1 and 2,.-_____._- 1
—Under-water Oceanic Temperature; by G. E. Betknap, 27
Ag
IV. oopeaaieg Effect of Electric Convection ; ; by H. A. Row-
VE si: sipitex and its Satellites; by Marra Mrrenet, __._ ~~. 38
VI.—Revision of the Atomic Weight of Anemos: oe
an F COORE te we a 41
Jos
Vil. By fophusphnciias n Anhydrous Pyrophosphate of
Lime from the West india: ; by C. U. Suusparp, Jr.,.... 49
SCIENTIFIC INTELLIGENCE.
e Direct Combustion of Fe itrogen,
hemistry and Ph nm, KAMMERER: On
the Relative Beng aigsice of Caves fs for Hydrogen a d Carbonous oxide, Horsr-
MANN, 51.—On the Sulphides of Platinum, Rrpan, 52 .—On the Destructive Dis-
tillation of Phat and Chlo’ ett. ra KRAMERS: Boracic Acid, M. L ULAPAIT,
53.—Photo-electric Phenomena, R. BornsTetN, 54, HANKEL, 5. 55.—Specifie Heat
of air at constant pressure and constant yolume, H. Kayser : Fluorescence of
the Retina, 55.
of Wi in, 61. :
Biberisn Steppes: co Physiographie der massigen Gesteine, H.
Rosensuscu, 65.—A Guide to the Determination of Rocks, by E. Jannetaz:
Tables seal the Seuiiisetion ot Minerals, by P. FRAZER, Jr.: Tridymite in Ire-
land: ennsylvania, 66.
ee —The Different Forms of Flowers on Plants of the same Spe-
cies, c DarRwIs, 67.—Ferns of North America, D. C. Eaton: Notes on
Botrychium simplex, G. E. DAVENPORT, 72.— Researches in in regard to the in-
fluence of light i radiant heat upon transpiration in plants, J. WIESNER:
Ueber Botrydium granulatum; J. Rosrarinski and M. Worontn, 73,—Om
Spetsbergens marina Klorofyll forande — 74. —Felei e Bi ay .
ae affini — a Borneo: Notes on Botrychium simp
te on the Habits of young Tinie, a AGassiz, 75. nie Se.
sn of ena a from the Jurassic; O. C. Mars
Astronomy.—The Nag Meteors: On Schmidt’s en Cygni, 76.--The Report |
of Professor Pickeri
—Norwegian Exploring eg ther sone ogi
Miscellaneous Scientific ee nana
of Weisbach’s Mechanics, 78.—A New Treatise on Steam Engineering, ete. :
List of Writings relating to | , MERRIMAN:
Elements of the Method of Least Squares, by M. MERRIMAN: Royal Society, 79.
Obituary.—Jared Potter Kirtland, 86.
iv CONTENTS.
N UMBER LXXXVI.
Arr. her —Photometric comparison of Light of aitrdny |
colores by U.N. eon, (25. eon ae 81 '
IX.—Echinoid fauna of Braz il; by Ricnarp Ratu : 82 :
X. Stiga sin Aa in the tail of Coggia’s Cosas, ae |
Sve eee ee ee ee 84
XI. = Suede extinction of the light of a Solar Protuberance; |
L. Trou 85
eer) Reger Seta Ng He es elon bal Rati a
and its relation to tae force find vital liesit S, LuContrs, 99
XV.—Revision of the Atomic Weight of Antimony ; by
Jostan P. Coo KE, Jr. (concluded), --__.._. - 1
X VI.—Two new species of Primordial Fossils; ; by! S. W, Foro, 124
XVIL—N Note on mailed colata; by.
XVIII.
; byS. W. Fo RD, 129
XIX. —Schweitzer’s “New Aid Ammen Sulphates ; “ge by
HNSON and R. H. Currrenpen, -.__ .-.--__ 2. 131
XX, = Poplar of North America ; by SERENO Watson, ---. 135
SCIENTIFIC INTELLIGENCE.
Chemistry and Physics.—Viquefaction of Oxygen, M. Raout Pictet, 137.—Lique-
faction of Oxygen, ehh ee and Hydrogen, 141.—Liquefaction ‘of Rewyiene,
Nitrogen
ioxide, and obebly Marsh gas, (LLETET, 142.—Flame-tempera-
s ETT M um Wor'! E ‘ — n
ealled Idryl, GOLDscHMIEpDT, —Determination of Nitrogen in Nitroglycerin,
Laur a R: Aromatic Hydantoins, Sc , 145.—Behavior of Be
acid in the Organism of Birds, Jarre: Le Sage’s Theo eory of Gravitation, J.
Crout, 146.—Thermal Conduetivity and Diathermancy of Air and H ydrogen, H.
Burr, 147. “Se Sacre of the Electric Spark in compressed gases, Cazin and
Wiruxer, 14
and Mi ebay La —Silurian tbe by Leo LEsQUEREUX: Modified dri
New Hatioate © y W. UPHAM, 1 mig vse das Krvstallsystem aa die Winkel
des Glimmers, von N. v. Sproles : Die Glimmergru
FELD, 153.—Beitrage zur Bntvwickelungsgeschichte de “aor — by E. Stan.:
Acetabularia Mediterraneanea, by A. DE BARY E. STRASBURGER, 155.—
Entwickelh hichte reat Prothalliums von Cvddeneene leptophylla, by
K. GorpeL: New Species of Parasitic ey : by E. P. cee
Transpiration in Plants: Japanese Lingula an ds, E.
ig iets ae = Le aa ey i eee le 2 eR ee eR ee oe
Rr TT a5 oN OPN SO Re R RG e ye EE ee eS Ty Re eas ree
S. Morsg,
—The American Naturalist: Bulletin of the r uttall Ornithological Club: 3 eae
foie “the me 158.
Meteors observed in Cambridge, Mass.: Prize for the discovery of
> Oana 158. —Index posta tp a and Sombie relating to Nebule and
Clusters, &c.. ly E. i tae
Miscellaneous Scienti, —teephon in England, 159.—Manual of Heat-
ing and Ventilation, Peng comme esmerism, Spiri , ete., historically
Se a by W. B. CarPENTER: The Telephone : Auguste
os de la Rive, 160.— Rhumkorff, 160.
RSE ce ot oe a P eamey UE ea ay ™ Pate mene Sears
CONTENTS. Vv
schecassecee LXXXVIL.
xL—
‘ture ; Phys eory of Cote, by . Norton,.- 161
XXU.—Transmission of Earth Waves; by H. L. Apso A eR
XXIII. Sec oreamey of Chemical Notation ; by Brrtuexor and
NEARIGNACE 2 20 ee ae eo ae eee 184
epee —Renction of Silver Chloride and Bromide; by M. C.
pec teate ss 189
XXV. ot ournal Friction at Low Speeds; y A. S. Kiwparn, 192
XXVI.—Brightness of the Satellites of Uranu iit bomsel bah 5
XX VIL—Decomposition of Chromic Iron; by E. F. Smrrn,. 198
IL. B. Wison,-
XXIX.—Tantalite from Coosa Co., Alabama; by J. L. Smrru, 203
XXX.—Am sug ines Silver Nitrate; by W. G. Mrxrer,_ 205
XXXI—C lization of Variscite ; by = = CHESTER,... 207
XXXII.—A Ney Planet ; by C. H. F. 208
XXXIIL—New Dinosaurian Reptiles ; sie "0. ro Marsu,.--. 241
SCIENTIFIC INTELLIGENCE.
og wrant J and Physics.—New mode of determining Vapor Densities, ve ndecoes NN,
—New Oxide of Sulphur, Peteatphatis — BERTHELOT, 209.—Formation
fs ‘Ammonium Nitrite in Combustion, ZOLLER and GRETE: Fiuoranthrene, a
r TT ;
ratory of the Johns Hopkins University, 2
Geology and Mineralogy. —W isconsin ae Socioers Geological Survey of New
Jersey, 216.—United States Geological and Geograpl hical Survey, sacle .—Geo
fm
2
+
b
a2
°
eee
Boers
a
gees
ae
a2
a
oF.
Te
38 3
gs
@
ernary beds of Grinn A
Leda Clay ee pe or beds) of a Ottawa valley: Mineralogy and Petrography
a an DSWORTH: " Setunrekite from Mitchell Co., North
as ate ils i slaeelasters Note to the Review of Darwin’s “ Forms
Flo 221.—Historia Filicum, 222. i F
wers,” ria Filicum, 222 Pires of North America: List woth!
found in the vicinity of Boston, 223.—Journal of the ean Society: Guide du
Botaniste in Belgique: Insect-fertilization in , 224.—Botanical Ne-
crology of 1877 aoa et ogoniese, 225 Cg new Species ime
from rican wa Dr. Warring’s a on the
growth-rings of eee plants a proof of siorublanis seasons,
Astronomy. oe of the Sun, J. Crobu, 226- ee By the Cordoba Obser-
_ vatory, B een 230.—-Moon’s Zodiaca | Light, E. S. Houpen, 231.
Miscellaneous Scientific Intelligence —Address of the President of the Royal Society,
231. cetaniatbone weld Flasks Pye on the Alps, ota Dog as of Tight
upon Bacteria and beara Or vEs and T
ditures for Universities in Germany, cot —Earthqake of of Nov. “tb. 187% 238.—
Geological — of repaect: Palzeon teer Weat er Service .
Beiblatter n Annalen der Physik und oat pone
Obituary. iste César Becquerel, 239.—Henri Victor Regnault, 240.
vil CONTENTS.
NUMBER LXXXVIII.
Pi
ART. oa ae —Surface Geology of Southwest Pennsylvania ;
2
xv eb WTEC RNMON (cs. ays ks ok So ees 5
xX a Driftless Interior of North America; by J. D.
Ba ee UES ss es eee ee oe ia 50
XXXVI ~The Ancient Outlet of Great Salt Lake; by G. K.
Gotnuer: 53s n ba ce ceed oe a eo 256
XXXVIL—Projection of Microscope Photographs; by J. C.
Dinar et oes ei oe a ws aa 59
XXXVIIL. iy Pee Silurian Fossils in Limestone associated
with Hydromica slates in Pennsylvania; by F. Pri, Jr., 261
XX XIX.—Influence of Temperature on the ‘Optical Cousomes
of Glass; by C. 8. Hastings, - -
XLI.—Intrusive Nature = ~ Triassic finer of New
gerepy > by Lo iotseeemrs, 3g Sek et 277
XLIT. eres Unit of "Blcctrical Resistance; by H. A.
POOWEAWON or ce eke og ae 281
XLIT. Groll’s H a = the Origin of Solar and Sidereal
Heat; by D. RWOOR Sos bce as ES ie 291
XLIV. —Chemieal Composition of Guanajuatite, a Selenide of
Bismuth from Guanajuato; by J. W. Maier, .__.___- 294
LV. ge on Solar Victories and Optical Sindics: ; by
8. RROGIN Serio ey ecient. ce tees 297
XLVI.—Tree-like Fossil Plant, AL h came in —_— Upper
Silurian Rocks of Ohio; by E. W. Crave
poumiinns eee
Chemistry and Physics.—Fundame: RTHELOT, 304.—
Data, Br -
Relations ‘between the ‘Koa: pe of = ce nts, WACHTER: Prepara-
ion n, GATEHOUSE: Method of separating Crystallize spe-
from Silicates, LAUFER, 305.—Stannous Chlori the analysis
of Nitro-compounds, Lue T: Catalytic action of Carbon Disulphide, HELL
and 306.—Conversion of Nitriles into Amides, PINNER an
Que a Pentacid Alcohol, Homa Acids o utter, Kinezert, 307
TT,
New Class of Acid ge ViLiieRs: Electro-Magnetic and Calorimetric Absolute
Measur Ek: Chemi ynamies, C. R. A. Wrieut and A. P.
Lurr, 308. aa For ae? : Haloid ae of Antimony, J. P. Cooks, Jr.,
310.—The Telephone, an Instrument of Pre ion, G. Fo = 12.
srishatin = Teen Shake of ay ortho R. D. sarees, 313.—
; 315.
New Jersey, 316.—First and Second lacial Eras of s with
flowers from the Coal-region r Pemmepoae : Mineral Caves of Biches
Peru, H. SEwELt, 317. ~Homilite, 318,
Botany and Zoology.—Flora o rhea Nae Africa, 318.—Ferns of Nerth America
_ Fossil Plants of pean Norma 339. -Elias Magnus Fries : Pourage of the Phar-
7 eras of parestbes 1877, Dawson,
rederick Hartt: Hagel Sees - *
. citing pee Geet
XL.— —Experiments with Floating Magnets s; by A. M YER, 276
ae
. Ee . * z ¥ : ss a esha aes ee
LE Ge RPE ee eR Ee Oe SN, RT, EE Oe en OST TEES OM PRR SRe SOMES 2 eee RE PU LP Lee eT EIN Se er ee TE Ee Ne Stl
Fe ee a et Re
CONTENTS. vil
NUMBER LXXXIX.
Page
Arr. XLVIL. gag eet. on the Absolute Unit of Electrical
Resistance ; by y A. Row ji cteeee ces eee
XLVIIT.—Meteorie fron peo Vieginia: by J. W. Matiet,.. 337
rift Fo
L.—Geographical and Geological Survey of the Rocky
Mountain Region, under the direction of J. W. Powell,. 342
LL—Just Tacsnaton 3 in Music ; by H. Warp Poots,.----- 359
LII.—Brachiopoda in the Swedish Primordial: ; by 8. Ww. Forp, 364
LIT.—On the “ Geodes” of the Keokuk Formation, and the
Genus popes by Samoms J. WALLACE, . 2 J...242. 366
LIV.—The Coralline, or Magars Timestove ‘of the Appala-
chian ed. e PAREBTES, coor ee oe neces 370
LV.—Isopoda from ow England ; ee Oscar Harcer,. ---- 373
L monio-argentic Iodide; by M. Carry Lra,.---- 9
—Am y M. y Lea
LVII.—Fossil Passerine Bird from Colorado; by. J. A, 'ALLEN, 381
LVIUI.—Terrestrial Electrical Currents; by W. L. Brovun,.. 385
LIX.—Notice of New Fossil Reptiles ; by O. C, Marsn,.... 409
SCIENTIFIC INTELLIGENCE.
Chemistry and Physics.—Specific Heat of Beryllium, Nitson and Perrersson: Syn-
thesis of Olefines, E:rexorr, 386.— Transformation of Olefine bromides into bro-
les DEM
etc. eae 387. — Distillation of _ and resin acids with zine dust,
ean Sa tains eed the Falls of the Ohio, James Hatt, —
—Fossil Plants of the Se yowsiager Gravel Deposits of the Sierra Nevada,
LEsQurrEvx: Fossil wood from the Keokuk form oe S. J. WaLtace: has
accompanying the Report of the Getlogics! Exploration of the Fortieth hie
C. Kine, 396.—Geological and Geographical Atlas oF bart F. :
Botany and Zoology.—Synoptical Flora of North America, Gray: Bibhographical
are to North American ager case ‘Ss. Wamso N, 400.—Some points in the Morph-
of Prim hy of Floral Aistivations, etc., G.
H
U. *
mioe 401.—Floral Stru sare a and k ‘Affinities of Sapotaceze, ag M. Hartoe:
North American Plants: Spore-Formation of the Me esocarpex, V B. Wrrrrock,
402.—Non-Sexu al O spegcapee — on Fern Proth oe 403. —Cata logue of the Flower-
ants wi s of Yale College
Astronomy.—Der ae x Persei, ete., H. . ee OGEL, 404. Reo eerie Jouraes 3
of Mathematics : Publications of the Cin cinnati Observatory, 406.
mre gy vents
on Chemistry, H. e and C. Rep
tendent of the Coat Boasts for 1874: Minneahe peice. of Nai atural
oe Re tions to North Ame bsacig tomy
8. Powers, 407. a ey ARLES PICKERING, 408.
vill CONTENTS.
NUMBER XC.
Art. LX.—Transmission of eee and Volition eG
the Nerves; by MoM, Gakvans. oo0 oe sere
Page
"43 0
EXIIL.—Ancient Outlet of Great Salt zake ie C. Prats, 439
Lx
ANGL 457
LXVIUL—Fossil Mammal from the Jurassic of ‘the somes >
y O. C. Marsa,
LXIX.—Shale recently discoverd pos the Devonian ee!
Cat
stones at Independence, Iowa; by S. igh Pe apatite Spa 460
fim Xone, UNE LL Dic. ay ted a 462
LXXI.—Letter from B. A. Goup, Director of the Cordoba
We ee ee
SCIENTIFIC INTELLIGENCE.
hemistry and P. —Expansion of the Solid Elements a Function of their :
Atomic weight, ma 472.—Gallium, LEcog DE BoIsBauUDRAN, 473.—Dimethyl- ;
ethylene, or pe: Butylene, Erarp, 474.—Oil of Tansy and Oil of Valeri :
BR inates
5.—Xanthin-li odies uminates in Pancreatic Diges-
tion, apa Present Condition of Electrical Meteorology, PALMIERI, 476.
Floa‘ t ote on ting Magnets, A. M. Ma
Geology and eralogy.—Supplement to the Second Edition of Acadian Geology,
J. W. Dawson, 478.—Recherches expérimentales sur les cassures qui traversent
te
vom RaTH: Das Erdbeben von Herzogenrath am 24 Juni, 1877, Dr. von 4
: Die 2. i
Botany and Zoology.—Karly Introduction and Spread of the Barberry in viet
New England, 482.—Ferns of North America, D. C. Eaton, 483.—Dictionnai
_= Botanique: Vargas considerato como Botanico: Dr. Thomas mas Thomson, 484.
istry: Smithsonian Institution: a Association
emigre Rate of Earthquake Wave Transit, 48
AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES.]
*
Art. L—Contributions to Meteorology, being results derived from
an examination of the Observations of the United States Signal
Service, and from other sources; by Ex1as Loomts, Professor
of Natural Philosophy in Yale College. Eighth paper.
With plates I and Il.
[Read before the National Academy of Sciences, New York, October 24, 1877.]
The origin and development of storms.
In order to determine the circumstances under which storms
originate, and ultimately acquire their full intensity, I selected
from the published volumes of the Signal Service observations
(September, 1872, to May, 1874), all those cases in which the
barometer fell below 29°25 inches at any station. It was found
that the barometer on Mt. Washington was frequently very
much lower than at the neighboring stations, Burlington and
Portland, indicating some peculiarity of this station.
these cases were therefore set aside, and reserved for separate
examination. During the entire period under discussion, the
mean height of the barometer at Virginia City was nearly a
third of an inch lower than at the neighboring stations, and
these observations were therefore eliminated from my list.
There remained one hundred and forty-eight cases in which
the barometer fell below 29-25 inches at some one of the other
stations. Sometimes at the same hour the barometer was
below 29-25 inches at a considerable number of stations all
included within the same low area. In such cases only one of
the stations is included in the table, viz., the station at which
the barometer was lowest. These one hundred and forty-eight
cases correspond to forty-four different storms, and are shown
in the following table, in which column Ist shows the number
of the storm; column 2d shows the date at which the barome-
ter was below 29:25 inches; column 3d shows the least height.
of the barometer observed at that hour; column 4th shows the
Am. Jour. ee Serres, Vou. XV, No. 85.—Jan., 1878.
2 Li. Loomis— Observations of the U. S. Signal Service.
name of the station at which the given height was observed ;
column 5th shows the total rain-fall (in inches) for the preced-
ing eight hours, at all the stations included within the area of
low barometer; column 6th shows the date of the storm’s
origin so far as can be determined from the observations;
locality named in column . Several additional columns
which I had prepared, I am obliged to omit in order to reduce
the table to the limits of the page of this Journal.
Barometer below 29°25 inehes.
Bar. Rain | Storm originated.| High on Eastside.’ | High on Westside _
No. Date. low- Station. ‘in fa n oe
| est. low. | When. | Where.| **"-| Bar. |Direction| Dist.| Bar. | Direction. DB)
1872. ea a
Nov. 7.2.29°12)Portland, Me.| 6-00,Nov. 3 Wy. 0 |30.25)S, 70° B.| 850 30°18|N.72° W.| 927
; 7.3, -13/Quebec 2°43 3
8.1} -07;/Quebec 6°75
8.2) *19| Quebec “25
ee | 30.1} -10/Quebee 2°-26/Nov. 28n. Mi. | 0] -‘38/S. 56 BL] 71) West
3 Dee. 24.1) -15|Portland, Or. | 1-84/Dec. 23'n. W. “70| East Py
4 27.1) -17|Halifax ‘T5\Dec. 23.G.M. | 0 | -35'Hast “T0IN. 12 W.il
6-09\Jan. 1N.M./| 0| -42\N.80E. “15|N. 82 W.|
5-62 a
“12 i
74 Jan. 25 Col. 0} 365: “1T| West A
} jJan. 28n. Mo.| 0 | 72/8. 54 EL 18) West 6 >
2°54\Feb. 50. Mo.| 0/| ‘308.49 EL) “4118. 20 W. |LI®
39, -29|N. 62 E.| | *48|N. 79 W.|20
bo
3
ty
Sy
f-r)
b>
P
156 Feb. 20.N.M. | -o1] -341N.70K.|1100| -59|N, 62 W.j20F
i)
‘Mar. 14\Dak. | -02| -46/S.78 E.| 930; -36| West
Barometer below 29°25 inches.
1090
a Rain | Storm originated.’ High on Eastside. | High on West side.
low: Station. in Rain
esi. | low. | When. | Where all.) Bar. Direction Dist.) Bar. | Direction.| Dist.
¥ ‘ | Ne
Mar. 21.1/29 19|Por tland, Me. 4°63 Mar. 16)n. Mo. 0 |30°44 S.58°E.!} 820/30714'S, 40° W.| 900
21.2} *19\Portland, Me. | 1-78!
26.3 16 Portland, Me, |} 2°98 M: 23in. T. 0 ‘41 N.16E.| 960) . °14'N. 74 W.!1200
19.2)29 hes ego 10°42/ Mar. 26in. Mo. 0 *37S. 84 E.) 650) °11.8.41 W.| 900
29,3 28°80B lingto 5°13
30.1/28°87 Portland, Me.} 2°78
30.2 29°20) Portland, Me. | 1°40
. 24.2) 29°03) Halif; 112,Ang. 23/A. 0. 0 -36 N. 54 W.'1000
24 3/28-99| Halifax "3|
25.3|29°18) Yankton 1°70|Sept. 23) Dak. 0 ‘118.83 BE.) 435) -10;West 1080
26.2} °20)Fort Garry 3
6.2 0'Punta Rassa | 6°40/Oct. 5/Cub. O01)" -39,N. 33 W./1600
6.3} °02/Punta Rassa | 5°46
17.2} °23/St. Paul 5-94'Oct. 16\n. D. 0 318.70 E.| 680) -41) West 1200
17.3| *02|Duluth 4 |
27.2| °22)Portland, Me.| 8°41/Oct. 25 Col. ‘04, “50 N.74E.' 710; -47'N. 72 W.) 920
8.2! *14| Eastport 10|Nov. 4:n. W. 0 | 42 East {1200
8.3/29°12/H. 1 |
9,1)2: ic pe sier 6
13.1)28°99 Cape Rosier | 3°78|Nov. 10|Neb. 0 “24 N. 73 440| °38 West 850
17.1, 29-00; Wilmin ngton 91|Nov. 13;n. Mo. 0 358. 31 E./1520| °12S. 16 W.| 440
17.2) 28°82! Norfolk 23
17.3)28°82/Cape "32
18.1|28°66|New London | 8°23
18.2/28°47| Eastpo: 9°12
ds 284 Chatham 2°16
.1/28°97\Cape Rosie’ 1°98
243 29-09|Bastpo 3°14'Noy. 21/N. M. 0 398.82 E.|1460; ‘14 N. 52 W.)1090
25.1/28°82 Hal 4531
25.2/28°80, Sy y 79
aan cranes 0°66
26,1) 28-85 Sydney 0-78
26.2 29°17 Sydney 0-07
3.3/ 29-08) Escanaba 13-99|Nov. 30 Mon. 0 “70'S. 83 E.| 1650:
1 ba oo 3°67
4.1/2 0:°95'Dec. 11|N. M. | 0| °37S.82 E1500) -28N. 51 W.
ae 28.128. 88 Porta, Me.| 2°52 24 n. W. 09' -51\East 1075
2:28°91| Eastport 4°29 )
3853 28-98\srdene ‘49
31,2 29-23|/Fort Garry ~ 20 i W. 0| ‘63S. 74 E1400
2.2) -09) . Blin. Mo.| 0} °64S.60 E./1750
232
2)
3.3 | .
16. . 1 . | 10) 5ON. 765. 900) 87 N. 47 W.
15.3, an. 14/P.0.-| ‘Oi ast |1070 |
16.1
16.2
16.3 |
17.1 hie
4.1 31N.M. | -03| -64.N.55E.| 950} -20.N. 82 W.| 900 —
4.2 oe
10.3 8'G. M. | -04| -64N.20E,|1480| -22.N. 70 W.
see 28° “8 Syiney |
9.0. 0 548. 81 E.1200
sda ee
Barometer below 29-25 inches.
.
ar, Rain | Storm originated.|_ _—_—| High on Kast side. High on West side,
No. Date. low- Station. in hain. -
est. low. | When. | Where.| fll.) Bar, |Direetion Dist.| Bar. | Direction.
1874, |
Feb. 16.3 29:09|Quebec 1-76/Feb. 12/Or. 0 30.53 Kast 1060
17.1| ‘0T|\Cape Rosier "30
17.2; °12/\Cape Rosier 06 i
35 - Mar. 1.2) °23/Fort Garry *02\Feb. 28\n. Mo. 0 38'S. 72° E.|1800/30-25'S. 15° W,) 4
1.3) ‘05 Fort Garry 09 :
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-16| Fort Sully
||Fort Sully
Observations of the United States Signal Service. 5
Of these forty-four storms, thirty-two occurred during the five
months from November to March, and only two occurred dur-
ing the four months from June to September.
The third column of the following table shows the number
of cases in which a storm originated in each of the different
localities named in column 2d. The first column shows the
letters by which the locality was designated in column 7th of
the table on pages 2 to 4.
Symbol.! Where storm originated. | Cases. ||symbot.! Where storm originated. | Cases.
P. 0. |Pacifie Ocean, north of n. D. |North of Dakota. 1
Washington Territory. 2 |/Dak. Dakota. 4
n. W. |North of Wash’n Terr. 4 |\Neb. |Nebraska. 1
Or. 1 |in. T. |Northern Texas. 1
Ut. ta 1 jin. Mi. [North of Michigan. 1
n. Mo. |North of Montana. 7 ||Ark. |Arkansas. 1
Mon. |Montana. 5 |iG. M. ‘Gulf of Mexico. 2
Wy. yoming. 2 ||Ala. |Alabama. 1
Col. Colorado. 2 |\Cub. |Near Cuba. 1
N. M. |New Mexico. 5 ||A. O. |Atlantic O.,nearlat 37°.) 1
nate north of latitude 36°.
The first stage in the development of each of these storms was
an area several hundred miles in diameter, over which the height
of the barometer differed but little from thirty inches, with an
area of high barometer both on the east and west sides, and at
a distance of about 1,000 miles. In the few cases in which a
high barometer is not reported on both sides of the origin, It 1s
6 LE. Loomis—Results derived from an examination of the
because the area of the observations was not Pig po! Bs oe
tended. The mean value of the high barometer on the ea
side was 80°42 inches, and the mean distance 1,033 miles; on
the west side the values were 80°31 inches and 977 miles. If
the area of the observations had been sufficiently extended
towards the north, it is presumed there would sometimes have
been found three areas of high barometer within a distance of
1,000 miles from the locality where the storm originated. On
Hoffmeyer’ s storm charts we frequently find three areas of high
barometer and occasionally four areas of high barometer sur-
rounding an area of low vpn sa
tendency of the air towards an intermediate point, and the
currents thus set in motion are deflected to the right by the
earth’s rotation, whence results a diminished pressure over the
central area. is diminished recta causes a still stronger
inward flow of the air, which results in a still greater ea
sion of the barometer. Sinise the air shicahies in on all s
towards this area of low barometer, the area tends to ssdieten
an oval form, which may become sensibly circular if the winds
are very violent, and the wee force resulting from this
revolving motion causes a still further fabio of the bar-
ometer. This partial vacuum would be soon filled, and the
inward movement of the air would sane wor it not for an
upward motion by which the inflowing air escapes. The air in
its upward motion, eg ae: with it a large amount of aqueous
vapor, is cooled, and its vapor is condensed, producing rain.
'The heat which is liberated in the condensation of this vapor
causes a further expansion of the air, and increases the force of
the inward movement of the wind. Rain is then one of the
circumstances which increases the force of a storm, and it
invariably attends. storms when they have aM! to consider-
able _ as is shown by the rain-fall m column 5th
the table on page 2. This table chicrpten shows a large rain-
fall whenever the storm is so situated as to permit observations
on its eastern side; but when the center of the storm passes
beyond our stations of observation, the observed rain-
fall rapidly diminishes. See Nos. 1, 9, 10, 11, 28, 34, 36
and 37.
I have shown in my 7th paper, pp. 14, 15, that an area of
of considerable m
low barometer agnitude may be formed and
continue for several a with vay little rain ; but in these
cases the barometer was never observed to fall as low as 29°25
rei ree: it will be’ sioniaieds that some rain was invariabl
ed barometer
RE Pee isi. est Sine ee
enever:the: fell below 29-4 inches, an
Observations of the United States Signal Service. 7
generally there was some rain reported whenever the barometer
fell below 29°5 inches. I have found no storm of great violence
which was not accompanied by a considerable fall of rain.
Rainfall is not, however, generally the cause of that first move-
ment of the wind which results in a great barometric depres-
sion. This appears from column 8th of the table on page 2,
which shows that over a circle of 600 miles in diameter sur-
rounding the locality where the storm originated, in thirty-one
cases no rain for the preceding eight hours was reported from
any station, and in only one instance did the total rain-fall
within this circle exceed one-tenth of an inch. It may be said
that in the neighborhood of these localities the stations were
few in number, and that rain-fall may have occurred at inter-
mediate points from which we have no reports. But in at least
a quarter of all the cases, this circle of 600 miles in diam-
eter included as many as four or five stations, so that we
seem fully justified in concluding that generally the inward
movement of the air toward a central area begins before there
is any considerable precipitation of vapor.
ter an area of low barometer has been formed, it soon
begins to change its position. This movement appears to be
mainly determined by the same causes which control the general
circulation of the atmosphere. Throughout the United States
(with the exception of the extreme southern margin) the aver-
age annual progress of the wind is from west to east, and this
movement is determined by causes which are general in their
operation, and cannot be permanently changed by the influence
of local storms. When an area of low barometer is formed,
the wind sets in both from the east and west sides to restore
storm, and generally extends much beyond these limits, and at
ll points is exerted nearly in parallel lines. Moreover, the
disturbance of the atmosphere by storms is mainly confined to
the lower half of the atmosphere, while the regular movement
of the upper half is much less disturbed. The force of this
pr current from the west, combined with that of the lower
f of the atmosphere, pressing upon the west side of an =
ha
8 . Loomis—Results derived from an examination of the
vails within an area of low barometer takes piaen principally
on the east side of the low center, as is indicate iti
of the rain-areas described in my 7th paper. By this upward
the west side of the low center. Thus the low center is
steadily transferred toward the east, or the storm travels
east
ward.
The areas of- high barometer which uniformly mark the
commencement of a storm, invariably attend it during its pro-
gress eastward. During the progress of the storms recorded in
the table on page 2, the average value of the high barometer
on the east side was 30°39 inches, and on the west side 30°32
inches, which numbers are almost identical with the values
n
atmosphere, and this supply evidently comes from the areas of
low barometer. In other words, during the progress of storms
barometer.
An inspection of column 4th of the table on page 2, shows
that these cases of low barometer occur most frequently in the
neighborhood of the Atlantic Ocean. This will appear from
the following table, in which the stations are SS into three
classes; one class including the stations near the Atlantic
coast or the Gulf of St. Lawrence, a second class including the
‘stations between the preceding class and the meridian of 92°
from Greenwich, the hind clase including stations west of the
sridian of 92°. |
MDM aii ten a estas <tare), SVE The As Pie Neer WEARS so Meh aay Abo OW Pi) ake, Noe hie SS Soy ot PR
Observations of the United States Signal Service. 9
Near the Atlantic coast.
From the coast to long. 92°. | West of longitude 92°.
|
Station. Lat. |Cases.|| Station. Lat. |Cases.| Station. Lat. |Cases.
Cape Rosier |48°52’| 11 | Marquette /46°33’| 3 ||Fort Garry (49°51’} 8
Father Point |48 31 6 ||Escanaba 45 46 2 ||Fort Benton |47 52 1
Chatham 7 eae 2 ||Montreal 45 31 1 |\Duluth 46 48 vu
Quebec 46 48 | 17 ||Ottawa 45 26 | 2 !/Portland, Or. |45 30 | 4
Sydney 46 8/| 17 || Alpena 45 5} 2 ||St. Paul 4463] 1
Eastport 44 55 9 ||Grand Haven !43 5 1 ort Sully 44 39 | 17
alifax 11 ||Milwa’ 3{ 3 |/Yankton 42.45 | 1
Burlington 29 | 1 ||Buffalo 42 53 1 |Omaha 4116) 3
Portland, Me. 43 40} 9 ||Dubuque 42 30 | 2 |\Leavenworth |39 19 | 2
B 21 | 1 ||Oswego 42 28] 1
New London |41 22] 1 ||Keokuk 40 23 | 1
Cape May 38 56] 1
Norfolk 36 51 1
Wilmington (34 11 1
Punta Rassa |26 29 2
We see that cases of low barometer occur most frequently at
the northern stations, and none have occurred south of latitude
39° except on the Atlantic coast. The cases of low barometer
appear to be pretty uniformly distributed along the different
meridians until we come within two hundred miles of the
Atlantic coast, with but one exception, viz. Fort Sully.
There is reason to suspect that in 1874 the readings of the
barometer at this station were too low. During the first six
months of 1874 the mean height of the barometer at this station
was more than one-tenth of an inch below that of the neigh-
boring stations Duluth, Breckenridge and Yankton. If we
apply this correction to the observations reported at Fort Sully,
the number of cases at this station below 29°25 inches will be
reduced to four, which accords yery well with the results at
other western stations. The observations at Cape Rosier,
Father Point and Sydney did not commence until November,
1873, and those at Chatham in October, 1878. There is then
a sudden increase in the violence of storms on approaching the
Atlantic coast, and this may be ascribed to the increased sup-
ply of aqueous vapor coming from the ocean and the Gulf
Stream. This increased supply of vapor results in an increas
fall of rain ; that is, increased expansion of the air, causing an
increased violence of the wind, and hence diminished pressure.
In nine of the cases included in the table on page 2, the
velocity of the wind was reported zero, and in thirty-one cases
the velocity did not exceed five miles per hour, showing that
near the center of an area of low pressure there is usually a
period during which the air is almost entirely calm. mie
Tn fifty-three of the cases included in the table, no rain was
reported for the preceding eight hours at the station where the
barometer was lowest; and in seventy-eight of the cases the
10 £. Loomis— Results derived from an examination of the
rain-fall was less than one-tenth of an inch, showing that the
principal rain-fall does not take place at the center of a low
rea, but considerably to the east of that center.
An area of low barometer may have considerable progres-
sive motion when there is no rain-fall, as is shown in several
examples quoted in my 7th paper; but the abundant rain-fall
which usually accompanies great barometric depressions tends
greatly to modify the movement of the storm’s center. Since
this rain-fall takes place chiefly on the east side of the low
center, the heat which is liberated in the condensation of the.
aqueous vapor causes a stronger inflow of air on the east side and
a continued fall of the barometer on that side. If there should
be a great precipitation of vapor on the west side of the center of
least pressure, this must be accompanied by ascending currents
of air on that side which would oppose the establishment of
the equilibrium of pressure on that side, and the center of the
Precipitation, March 9-14, 1874.
9.1; 9.2 9.3 10.1{10.2/10.3/11 1/11.2/11.3/12.1/12.2)12.3/13.1/13.2113.3 14.1
Rochester ng tee i Ge) 8 Gat 02) -01 *22| *04/ -02| °10| -09| -03) -u4! -
Montreal s 10) 03) +20) 20} -07 “01 “01
Ottawa 20}: 10)... *30) -10
Quebec | 20 30 20) -10) 20
Father Point OL) -05) - 02 33)
Cape Rosier 57} 03) -19) - 10) -15} 05) 10} -30) 10
Chatham LC tkU BO | O01) “O01
to about one foot of snow, and this snow-fall exispied a
.
Observations of the United States Signal Service. 7
extended over so large an area on the west side of the low
centre, is believed to have been the cause of the slow eastward
progress of the storm.
This unusual precipitation on the west side of the storm is
ascribed in part to an east wind which prevailed at a moderate
elevation above the earth’s surface, while a strong wind from
the west or northwest prevailed at the surface of the earth.
This fact is shown by the following observations of the wind
and the upper clouds at Portland, Eastport and Halifax.
Date. Station. Wind. Clouds.
March 11.2 |Eastport N. W. E.
11,2 |Halifax Ss.
11.3 |Halifax W 8.
12.1 |Kastpo ‘ E.
12.1 |Portland We N. &.
__ The precipitation on the west side of the low center ceased
March 14th, and after that date the low center traveled rapidly
eastward. From the 14th to the 15th its average progress was
twenty-nine miles per hour, from the 15th to the 16th it was
forty-seven miles per hour, from the 16th to the 17th it was
thirty-six miles per hour, from the 17th to the 18th it was only
thirteen miles per hour, and from the 18th to the 19th when off
North Cape it was only eight miles per hour. The progress of
this storm from Montana to the North Cape is shown on
, and the isobaric curves show that there was a sudden in-
crease in the violence of the storm on approaching the Atlantic
eres
No. 10 of the table on page 2 presents another example of a
nearly stationary storm. From February 22d to the 24th the
center of this storm remained for forty-eight hours near Quebec,
and for the next two days the storm traveled very slowly, but
I have no means of determining the exact position of the low
center. The following observations show that at this time
there was an unusual precipitation on the west side of the
storm’s center.
Precipitution, February 22-26, 1873.
22.1, 22.2) 22.3 23.1) 23.3) 25.1) 25.3) 26.1) Sum
Mt. Washington] °15 50 | 32 45 | 50 | 1-92
~ Quebec | -40 | -30| O01 61 | 2-02
“60| 20
No. 40 of the table on page 2 presents another example of
the same kind. The center of this storm remained near Father
Point from the morning of April 30th for about two days, and
it was four days in reaching St. Johns, Newfoundland. In
12 £. Loomis—Results derived from an examination of the
this case also there was an unusual precipitation of vapor on
the west side of the center of low pressure, as is shown by the
following table :
Precipitation, April 30—May 3, 1874.
30.1/ 30.2) 30.3) 1.1] 1.2] 1.3} 2.11 2.2] 2.3] 3-11] 3.2/Sum
Montreal 06 "80 01 87
Quebec 50 | -40/ 50} 30 10 1:80
Chatham "21 | -02 12 | °06| °02; -31] -12}| -06} -04 96
Cape Rosier | °21| -27| ‘Ol 10! -15} 40} -20} -20 1°54
Sydney *34| -23 oY a a
A still more remarkable example of the same kind occurred
on the Atlantic Ocean in the winter of 1874-5. <A st
the 80th of December, 1874, there was a low center (barometer
28°7 inches) a short distance south of Greenland, with an area
west (bar. 30°8). January Ist the low was ir stationary
28°7), with a high on the east (bar. 30°5) and another low on
the west (bar. 28°9) followed on the west side by a high (bar.
305). January 4th the two low areas had blended into a sin.
gle low area (bar. 28-9), and the center of least pressure was
_ able to consider the great depression of January 4th to be the
continuation of that of December 30th. January 5th the low
Observations of the Unued States Signal Service. 13
low pressure which was advancing from the west. January 9th
the low area was nearly stationary (bar. 28°7), with a high on
the east much reduced (har. 30°3) and an equal high on the
west. January 10th low stationary (bar. 28-7) with a high on
the east (bar. 30°5), with a small low on the west (bar. 29:5)
and a high further west (bar. 30°6). January 11th the two
low areas coalesced and the resulting center of least pressure
was thereby carried 650 miles westward (bar. 28°), with a
high on the east (bar. 30°7) and a high on the west (bar. 30-4).
In this case there was a subordinate low center (bar. 29°3)
about 2,000 miles in a northeast direction, which has the
epression, and the area of low pressure (below 30 inches)
stretched entirely across the Atlantic Ocean, including the
whole of Newfoundland on the west and the whole of Great
Britain on the east, extending southward to latitude 32° and
northward beyond latitude 70°. Plate II represents the isobars
for January 12th and also the path of the storm’s center from
December 30th to January 18th. January 13th the center
was nearly stationary, January 14th it had moved a little east-
ward, January 15th it had moved a little northward, and dur-
ing the three following days it moved a little eastward. Thus
on January 18th the center of the storm was only 900 miles
eastward of its position on December 30th, and it was 200
miles westward of its position January 3d. The principal
westerly motion of the storm center appeared to result from the
influence of another low center advancing from the west and
uniting with the former. This result took place January 4th
center, attended by extensive precipitation, which on the
western side consisted chiefly of snow and sleet, with very low
temperature, the thermometer on the American coast remain-
ing much of the time near zero of Fahrenheit, and at stations
but little removed from the coast sinking more than 20° below
zero. This precipitation is believed to have taken place chiefly
er the ocean, where its amount could not be measured. The
following table shows the precipitation in Newfoundland, New
Brunswick and its vicinity, and also shows the lowest tempera-
14 E. Loomis— Results derived from an examination of the
ture observed each day at two of the stations in New Bruns-
wick and one in Manitoba.
Precipitation, Jan. 1-18, 1875. Lowest Temperature.
St. Char- | Frede-| Chat- Frede-| Chat- | Winni-
Johns. | Sydney.)jottet’n.'rickton.| ham. |Quebec.|'rickton.| ham. | peg.
Jan, 1 0-04 — 1%4!— 0°-5| -16°°6
2 16 | 0°35 | 0°48 | 0°75 | 0°40 ||\— 3:3|/— 3°0|—27°8
3]; 1:00 “49 *35 “15 26 65/— 10 26°:
4 01 — 95/— 6°6!—22°9
5 10 “06 ol — 34!—10°0 |—30°4
€ —12°6 |—11°3 |—29°5
y 03 10 | 06 12 |}— 65 |—11°3 |—24°5
8} 120 | 1:55 | 1°60 “93. | 1°45 ‘ — 65|— 5-6 |—45'5
0 “15 28 1°00 || —13°1 |--15°3 |—39°2
10} 1-00 “31 16 t1S 5) SES? — 18|— 4°6|—33°8
1] 01 || —20-7T | —16°3 |—36°0
1: 02 —28°9 |—17-0 |—36°3
x “60 “Ol “70 15°8 |—14°3 | —36°5
14 “25 36 55 02 “64 30 0-0 |—34
45 — 75 88 |—29°9
€ 40 — 33 05 |—31'l
17 *30 09 “09 — 18/— 1°3 |—34°2
1g — 54\/— 65 |—34°8
Sum #31) Sil: 335) 3°93 | 4:65 | 2-93
Over the Atlantic Ocean near the parallel of 30°, eeeapens
the month of January the mean height of the baro
about 30:1 inches. During the twenty days now he oe
amination there were only four days in which the pressure in
that region fell below 30°38 inches. Throughout these twenty
aye | there was always an area of high pressure on the east,
from 30°4 to 30°8 inches, and generally at a eee of about
1,500 miles ; but on five days its Aguas was een 3,000
miles. It is not known whether there was an area of hich
ressure on the north, but we know that jens this period
the pare nan ae at the north was extremely low. roughout
this entire there was therefore a cause to produce a wind
from four drat directions towards the center of this storm,
and the foree was sufficient to set the air in motion over an
immense area. The usual phenomena attendin areas of low
barometer must therefore follow, viz: high wind
barometer, and a precipitation of vapor. the present
occasion these phenomena were exhibited in aad intensity,
becau use the center of low pressure was directly over the Gulf
e
Observations of the United States Signal Service. 15
Stream, where the temperature of the water in January is
nearly 60°, and the air which flowed in from the north and
west was excessively cold. It seems probable that this cold
northwest wind pushed under the warmer wind from the south-
east as was observed in the storm of March 11, 1874, and that
this was one cause of the unusual precipitation on the west
side of the storm-center. This extensive precipitation on the
west side of the low center is believed to have been the prin-
d.
cipal cause of the slow progress of the storm eastwar
Violent Winds.
In order to determine the laws which govern the velocity of
the wind I selected from the published volumes of the Signal
Service observations (September, 1872, to May, 1874,) all those
cases in which the velocity of the wind amounted to forty
miles per hour. The number of these cases was 250, excluding
_ the observations at Mount Washington and Pike’s Peak, where
high velocities are very common. Of these 250 cases, eighty-
two were reported at 7:35 A. M., ninety-one at 4:35 P. M., and
seventy-seven at ll p.m. These results indicate a slight influ-
Month.| Cases. | Month.| Cases. | Month.| Cases.
Jan. 22 | May 5 ||Sept.
Feb. 12 \lJune 1 |jOct. 6
March| 21 | July 3 ||Nov. | 23
April 20 ||Aug. 2 |\Dec. 9
Thus we see that during the six months, from November to
most violent winds.
‘The following table shows the number of cases in which the
wind blew from each of the eight principal points of the com-
pass at the time of these high velocities. We see that violent
winds come from a northern quarter twoand a half times as
frequently as they do from a southern quarter, and they sel-
dom come directly from the south.
*
16 EF. Loomis—Results derived from an examination of the
North 43 cases. South 6 cases.
Northesst so... ... 48...“ Southwest ._.....- bE Sais
jas yi WORbeS cua. eee 3
Southeast ig Northwest 20 5a- =
The following table shows all the stations at which these vio-
lent winds were reported in more than two cases, and it also
shows the number of cases for each of the eight principal
points of fhe com pass :
N. | NE.) E, |S.E.| S. | S.W.| W. IN. W.) Sum.
Quebec _._-_-- 33 9 4 1 6
Breckenridge _.| 4 9 15 | 28
Indianola_-____- 22 1 23
Fort Sully -..-. 6 5 1 1 5 | 18
Pe ie Re 2 f 1 8 | 15
Ro : 3 l 4 4 TTk
Father Point 1 2 x 4} 10
Fort Benton _.- 5 1 1 7
eport 2c 5 2 7
La Sel pence = 2 a! 6
Pine es 5 5
Grand Haven — 4 4
heyenne _ .--- £35: oe
Milwaukee , 1 1 1 3
Pes 1 1 1 fen.
Omaha. 2.5.0: 1 2 3
Knoxville ____- z 2 3
Fort Gibson ___ 1 2 3
veston _.... 2 1 3
Key West ___-- 1 1 ] 3
The observations at Cape Rosier and Father Point embrace
only a period of seven months. A comparison o bh
servations indicates a decided preponderance of high velocities
at the more northern stations. In order to determine whether
the force of the wind gene increases with an increase of
latitude, I determined the mean velocity of the wind at all the
ignal Service stations and classified the observations according
to the latitude of the stations. The elaxig table shows the
results at all the stations utiing of latitude 30°, except Mount
Washington and Pike’s
———
pene stations. miles per hour.
30°—34° 15 7-07
35°-39° 26 8-57
40°44" | 36 916
45°-49°| 10 8-28
These observations indicate that in North America the aver-
Observations of the United States Signal Service. 17
Throughout an extensive region east of the Rocky Mountains
the annual rain-fall is very small. The winds of this region are
therefore dry winds, while the air of the Mississippi valley con-
tains an. abundance of vapor. The difference in the specific
gravity of the air over the two localities is sufficient to accel-
erate considerably the west and northwest winds which sweep
over the dry prairies west of the Mississippi river. _
same causes which affect the average velocity of the
winds affect also the frequency of occurrence of the most vio-
lent winds. The region where violent winds are of most fre-
uent occurrence is near the Gulf of St. Lawrence. It has been
mentioned that the observations at Cape Rosier and Father
‘oint embrace a period of only seven months, and should
therefore be multiplied by three in order to render them com-
parable with observations at the other stations. An important
reason for the greater violence of the winds in this region, is
the greater magnitude of the barometric fluctuations and the
unusual contrast which exists between the warm and moist
18 E. Loomis—Results derived from an examination of the
four miles per hour, and also November 18th, 1873, when the
wind at Indianola was fifty miles per hour. In these and many
similar cases, there was an area of high barometer in Dakota,
causing northerly winds at all places on the south side of this
center from Dakota to the Gulf of Mexico. The frequency of
violent winds in this region is ascribed to two causes, viz., the
country is generally destitute of forests and the air is uncom-
monly dry.
The frequency of violent winds at Indianola is specially re-
markable. In order to discover the cause of this phenomenon
I have prepared the following table, in which column 1st shows
the dates at which the winds attained a velocity of forty miles
r hour; column 2d shows the velocity observed; column 3d
shows the direction of the wind ; column 4th shows the height
of the barometer; column 5th shows the rain-fall in inches
during the preceding eight hours; column 6th shows the tem-
perature of the air at Indianola; column 7th shows the aver-
Violent winds at Indianola.
Wind. Thermometer. High on North.
Barom.' Rain —
Vel. | Direc. tmp. mp. Differ.; Barom. | Direction.| Dist.
1872, Oct. 7. ] 29°99 {0°13 | 70°) 82°;—12°) 30-23 .45°W.| 1200
Nov. 6.2} 40 29°7 6| 57 8 "15 |N. 43 E. 7
cA ae ase 2 29°83 02; 63 | 18 |—26 "31 [N.45 W.! 1200
14.1} 46 |; N. 30°06 0} 41 i8 |—37 “87 .31 W.| 1500
14, 8 s 30°14 0| 49 ig 29 *88 .31 W.| 1500
Dec. 10.1) 40 - 29°86 |2°14] 47 14 | —27 “65 (32 690
1873, Jan. 28.1} 43 Fe 30°20 | -05| 30 14 |—44 "BS ay ease 750
28. . 30°33 0} 23 (44 +5 4 IN. 7 E. 750
30°42 0} 20 | 74 |—54 42 IN et Ee, 750
30°17 0} 6 74 |—20 “AE .10 W.} 1100
30-2: 0; 560 | 75 |—25 | ‘93 IN.10 W.| 1100
29°91 0; 6 » |—18 “76 .10 W.| 1100
30°32 0; 48 | 75 |—2T 44 | North | 1200
N. 29°93 0; 48 | 8L |—33 4% .10 W.} 1100
N. 30°19 0| 56 —25 5] .31 W.| 1500
N. |} 29°96 0| 58 3 '—20 “42 .10 W.| 1100
N.E.} 30°16 0| 57 t |—17 26 IN. 31 E. 300
N. | 30°22 0| 57 L j—17 ‘46 N.45 W.| 1200
N. |} 30°12 | -15| 49 | 74 |—25 50 IN. 4 Wi) 970
N, | 30°25 0} 44 L | —30 “4 10 E. 500
| N. | 30°17} 0} 43 | 81 |—38 3 10 E.| 600
a - | 29°70 | -08| 55 | 81 |—26 46 | North | 1
LN. | 30°05 © 0° 58! 81 i—23 "38 'N.32 E.' 1300
Observations of the United States Signal Service. 19
e see that in each of these cases there was an area of high
inwacter on the north, and this P ressure was generally suffi-
cient to urge the wind with considerable force towards Indian-
ola. We also see that in each case the temperature of the air
at Indianola was below that of the water on the south side, and
generally very much below it; and moreover the air over the
Gulf contained an abundance of va por. This cause alone
would be sufficient to produce a fresh breeze from the north at
Indianola.
The reason that violent winds are more common at Indianola
than at stations further east on the Gulf of Mexico may be the
greater dryness of the air near the Rocky Mountains. The
annual rain-fall decreases from the Mississippi River to the
ocky Mountains. and the winds must be dryer near Hi moun-
tains than they are near the cee eed River. We find a cor-
responding increase in the mean velocity of the winds as we
advance westward from Mobile. At Mobile the mean veloc-
ity of the wind is 6-0 miles per hour; at New Orleans it is 73
ose at Galveston it is 9:3 miles ; and at Indianola it is 13°7
mies,
At several of the stations, one of the most noticeable pecu-
liarities of these violent winds is the great oe of
w
sorthernst, ete. This seems to indicate that the diate of the
wind is somewhat a by the configuration of the surface
of the surrounding country.
A high velocity « of the wind is not invariably associated with
alow barometer. In fifty-seven cases (out of 250) the yey so
was above thirty inches; in sixteen cases it was a 0°25
inches ; and in three cases it was as high as 30°5 bashed; The
following are the extreme cases:
Wind.
No. Date. Stations. Barom. Direc.| Fore. Temp.
1 (1873, —~ 7 Breckenridge | 30°75 | N. | 40 | —17°
2 2) Quebec 30°56 |N.E.| 41 1
3 1872, Dec. ae Breckenridge | 30°50 N.W.! 40 | —23
Tn each of these cases there was an area of low barometer
within the limits of the United States, and also an area of hig
barometer ; but in cases No. 1 and No. 3 the pressure at. Breck:
ing
vation, which seems to indicate that at the former date the
center of high pressure was northwest of Breckenridge. |
20 =. Loomis— Observations of the U. 8. Signal Service.
Breckenridge and Florida, and in a difference of 89°
This was doubtless an important part of the moving force
which gave the wind such velocity. No d 3 are remark
Barometric Gradient.
I have determined the barometric gradient for each of the
250 cases of high velocity of the wind, and a comparison of
the results shows that the gradient increases with the latitude
Latitude 29°-3 Distance 98 miles.
is% Rive *
5 ‘a 66 “
“ 42 ce “ 62 “ce
47 J ‘i 50 ot
The observations also indicate that the gradient is less in
summer than in winter; but the observations are too few in
number to furnish a satisfactory value of the gradient in sum-
mer for these high velocities.
tude of the stations employed is about 45°. The first part of
the table is taken from my second paper, page 18.
C. G. Rockwood—Recent American Karthquakes. 21
Relation between the velocity of the wind and the distance between
the isoburs.
Veloc. | Dist. 1 Veloc, | Dist. | Veloc. | Dist. | Veloc. | Dist. | Veloc. | Dist.
2
3
4
5
6 125 16 100 26 92 36 63 46 46
t 7
8
9
10
There are thirty-five cases reported of velocities exceeding
fifty miles per hour, one of them amounting to seventy-one
determined from observations at stations distant 100 miles from
each other. Such exceptional velocities may result from a
strong upward movement of the air in the neighborhood of the
station of observation.
In preparing the materials for this article I have been
assisted by Mr. Henry A. Hazen, a graduate of Dartmouth
College of the class of 1871.
Art. IL.—WNotices of Recent American Earthquakes. No. 7;
by Professor C. G. Rockwoon, Jr., College of New Jersey.
In the following notices, those based upon single newspaper
reports, and which could not be otherwise verified, are p
in smaller type, and the source of the information is in icated.
For information received I am indebted to John M. Batchelder
of Boston, Fred. E. Goodrich of the Boston Post, Principal J.
W. Dawson of Montreal, Professor E. T. Quimby of Dartmouth
College and others.
- 1876.—May 10. A shock at Santa Barbara, Cal.—(U. 8. Sign.
erv.) :
Aug. 16. At 1.15 p.m. The bark Forest Queen experienced a
heavy shock of fifteen seconds duration in lat. 41° 55' N., long.
126° 25’ W.., off the southern part of Oregon.—(U. 8. Sign. Serv.)
22 C. G. Rockwood—Recent American Earthquakes,
Aug. 16. At 11.25 p. m., at Lower Brule Indian Agency, Dakota
T., a shock of seven seconds duration with loud rumbling noise.—
(U.S. Sign. Serv.)
Sept. 21. A shock about 11.80 p. M., felt at Newport, R. £.
and at Fall River and New Bedford, Mass., and adjacent places.
At Fort Adams, R. L, it was reported to be “ apparently from
east to west and lasting about ten seconds,”
Sept. 25. Two distinct and heavy shocks with an interval of
about fifteen minutes between them were felt about midnight
of 24th and 25th throughout southern Illinois and Indiana, from
St. Louis, Mo. to Indianapolis, Ind., and Louisville, Ky. The
Sept. 26. A slight shock reported at Friendsville, Tl.—(U. 8.
Sign. Serv.)
Oct. 6. Two shocks at San Francisco at 9.20 and 10.08 P. w.
The first and heavier, lasting ten seconds, with a motion from
N. W. to S.’E. was felt also at Oakland, San José and Angel
Tsland.
Noy. 20. A shock at Eastport, Me., at 1 p. m—(U. S. Sign. Serv.)
Dec. 11. About 7 Pp. M. at Silver Mountain, Cal., a series of
A slight shock was also reported at 8 o’clock next morning
at the same place.
Dec. 12. A slight shock in the City of Charleston, S. C., in the
evening.—(U. 8. Sign. Serv.)
Dec. 21. A shock at Wytheville, Va., at 10.30 a. wa—(U. 8.
1877.—Jan. 10, A slight shock about 1.15 Pp. w. at Los Angeles,
Cal., which at Benedict Cafion near there, was felt as three dis-
tinct shocks preceded by a loud report.—(Los Angeles Express, in
. Y. Times.
Jan: 138.) A heavy earthquake abont , forty-five miles south
east of San Diego, Cal. ‘The reverberations were from east to
west, and extended throughout the mountains to the borders of
Cajou Valley.”—(N. Y. Times.) ae
Feb. 17. A heavy shock at Quincy, Plumas Co., Cal., in the
morning. ee
Feb. 18. A distinct shock at 2.20 Pp. Mm. at Portland, Me.,
with rumbling sound. -
C. G. Rockwood—Recent American Earthquakes. 23
Feb. 24. The Honolulu Gazette of Feb. 28th reports a sub-
marine volcanic outbreak in Kealakeakaua Bay at 3 A. M., Feb.
24. During the same night a severe earthquake was felt at
Koawalsa and Kell. E
March 8. Two light shocks about 2 a. M., and a few minutes
before 5 a. m. at Helena, Montana.—(Helena Independent, in N. Y.
es.
March 19. A shock at Kingston, Jamaica, at 12.55 A. M.
April 17. A slight shock of short duration at Panama at 5.50
A. M.- i
April 23. A slight shock at Auburn, N. H., at 11 a. u., from
; S. E——(U. S. Sign. Serv.)
April 26. A slight shock at Franklin, N. C., at 5 p. m—(U. S.
)
May 2. A shock “lasting eight or ten seconds” at 10.20
P. M. at Oshawa, Ontario.
May 9. At 8.30 p. M., a series of severe shocks, lasting four
or five minutes, and followed by a destructive tidal wave, were
felt on the coast of Peru, Bolivia and Chili. The center of
disturbance appeared to be the neighborhood of the volcano
Ilaga, on the borders of Peru and Bolivia, in lat. 21°S. The
shocks were felt along the coast from beyond Arequipa, Peru, to
Valparaiso, Chili, but were most violent and destructive from
quique, where the duration was 4 m. 20 sec., to Cobija,
Mexillones and Chavanago, Bolivia. The disturbance does not
appear to have extended very far inland. The sea wave how-
_ ever spread over the entire Pacific, being felt along the coast of
Mexico and California (whence it was reported by the signal
service a day before news of the shock was received), at the
Sandwich Islands, the Marquesas Islands, Japan and Australia.
n the Peruvian and Bolivian coasts the wave was from twenty
Francisco 348 miles, to Honolulu 408 miles and to Australia
378 miles per hour. :
On the Peruvian coast lighter shocks continued at intervals
for some days, and later reports indicate that the whole coast
has suffered a considerable permanent upheaval. :
t San José, Costa Rica, a feeble shock was felt at 5.28 A. M.
of the 10th (local time) or 9" 54™ after the shock at Iquique.
In the Sandwich Islands the volcano of Kilauea exhibited
24 C. G. Rockwood— Recent American Earthquakes.
unusual activity, and eruptions of lava with occasional earth-
quake shocks occurred during the week preceding the tidal
wave, especially one at 2.45 P. M., May 4th.
More detailed local reports of the phenomena may be found
in this Journal, III, xiv, p. 77, U.S. Weather Review, May,
1877, Scientific American, vol. XXXvli, pp. 3, 345, Nature, vol.
Xvi, pp. 112, 174, 198.
May A slight shock in the afternoon in Schenectady and
Schoharie Counties, :
May 14. A severe shock at Lima and Callao, lasting twenty-
two seconds.
ay 15. From Port Stanley, Ont., it is reported that a wave
five feet high, apparently due to some earthquake shock, swept
along the northern shore of Lake Erie, followed for an hour by
smaller ones,
May 25. A shock at Knoxville, Tenn.—(U. S. Sign. Serv.)
May 26. A shock at 3 P. u. at New Harmony, Ind.—-(U. S.
Sign. Serv.
May 30. A heavy shock between 2 and 8 4. M., at Pasa
Robles, Cal.
June ll. A voleanie eruption, smoke and boulders, in the
mountains near Flowing Wells Station, Southern Pacific R. R.,
about sixty miles from Yuma, preceded by a violent vibration
of the earth. :
June 18. At Milwaukee, Wis., at 7.80 P. M., the water in
Lake Michigan fell two feet in half an hour and rose again
more quickly.—(U. S. Sign. Serv.
June 28. A shock about 11.30 P. M. at Bakersfield, Cal.
“It seemed to be in the nature of an upheaval rather than
vibratory.”
July 9. Ashock at Sacramento, Cal., lasting one minute. Oscil-
lations, E. and W.—(U. S, Sign. Serv.)
July 14. Two shocks at 6.40 Pp. M., at Memphis, T'enn., last-
ing several seconds, vibrations from S. W. or W. to N. EK. or E.
July 15. Three shocks apparently from the west, and lasting
five seconds, at Carbondale, Il.—(U. 8. Sign. Serv.)
July 17. A sharp shock at 8 4. M., lasting about thirty
seconds, at River du Loup, Canada.
Aug. 10. A shock lasting several seconds at Florence, N. J.—
(U. 8. Sign. Serv.)
Aug.17. A slight shock about 11 4. ., felt in Detroit,
Mich., and a few neighboring towns. It lasted from thirty
conds to one minute, and was accompanied by a rumbling
sound,
C. G. Rockwood— Recent American Earthquakes, 25
——. At7.30 P.M, of the same day a heavy shock, lasting
fifteen seconds, was felt at Campo, Cal.—(U. 8. Sign. Serv.)
Aug. 23. Shocks of an alarming nature were felt at Cobija,
Bolivia, at 1.40 P. M., fee at Tquique at 5 Pp. M., and a few days
earlier at Copiapo, Chili.
Sept. 1. A slight shock at 11 a. M. at Latonsville, Sandy
Springs, Brookville, Laurel and other points in Prince George's
Sept. 7. A shock at 10 p.m. at Yuma, Arizona,—(U. S. Sign.
Serv.)
Sept. 10. A shock at 9.59 a. m., felt in the valley of the
Delaware River from Trenton to Philadelphia. Tt affected an
extent of country, about thirty-five miles along the river cM
twenty miles wide, and having its center at Burlington, N. J.
lasted thirty or forty seconds, had an apparent motion consid
the southwest, and was accompanied by a rumbling noise.
Sept. 18. Panama advices of this date say, Shocks of earth-
quake were continuously felt in some of the southern ports of
Peru.
Sept. A shock at Campo, Cal., at 2.30 p. m., lasting five
seconds, with low rumbling.—(U. 8. Si ign. Serv.)
Oct. 9. A severe shock at 2.20 A. Mm. at Lima and Callao,
Peru; felt also in Pisco, Ica and Chincha, where two shocks
were reported. The vibration was from north to south.
Oct. 12. Quite severe shocks were felt in Oregon, occurring
in Portland at 1.58 P. M., two shocks being noticed; at Ma rsh-
hy Clackamas Co., at 145 P. M.; and at Cascades at 1.52
M. (Another shock was felt at Cascades at 9 A. mM.) The vibra-
ei were in each case from north to south and were sufficiently
violent to overthrow chimne
tien, A. M. of the same day a slight earthquake
was felt on the Isthmus of Panama.
Oct. 26. Between 5 and 6 p. M. the schooner Leo felt a
severe earthquake shock, continuing about ten seconds, in lat.
43° 13’ N., long 128° W., the vessel being 300 or 400 miles
from the coast of Oregon.
Nov. 4. About 2 A. M. a rather severe earthquake was felt
renaterws a And part of Canada, New York and New Eng-
along the Connecticut River ; re Burlingios and Benni nington,
vi. ‘Plattsbur 2, Whitehall and Saratoga, N. Y., and the valley
26 C. G. Rockwood— Recent American Earthquakes,
of Lake Champlain and the Hudson as far south as Albany ;
and finally from Utica, Rome, Auburn and the Mohawk Valley.
It was probably felt throughout the whole Adirondack region
which is thus enclosed, but whence no reports could be ex-
pected. It would thus seem to have been felt over an irregular
trapezium, whose angles are marked by Pembroke, Ont., Three
Rivers, P. Q., Hartford, Conn., and Auburn, N. Y.; and which
is therefore some 200 miles on its northern and southern sides,
about 800 on the east and 175 on the west. In regard to the
exact time of the shock the reports differ too much among
themselves, and are mostly of too vague a nature to permit any
deductions therefrom as to the direction or rate of progress of
the vibration. Comparing the reports from thirty-six localities
in which the time is given, and rejecting three as quite wide of
the truth, we find them cluster closely about 2 Aa. M., none
earlier than 1.45, none later than 2.10, most being between 1.50
a 2 local time. The ~ ones, however, which cee to
iably accurate are Montreal 1.50 a. (J. W. Dawson),
Hartford 1.56 (Ed. Hartford Courant)=1.52 idsatroat time, and
Dudley observatory, AJbany, 1.53 = 1.54 Montreal time. The
Hartford record is also confirmed by an apparently careful
report from Windsor, Conn., giving 1.55 a M (25
reports give in a general way Sa about 2 A. M.,” etc.
The duration in Montreal was about "twenty seconds. The
other reports of its duration vary from four or five seconds to
two or three minutes and in one case five minutes. Most of
them however gree about half a minute. ch seems to have been
current testimony of three observers. In some places a rum-
bling noise and in others two or several shocks were re
at Dudley observatory “a severe shock of ten seconds duration,
followed after an interval of thirty seconds by a lighter one ;” at
Hanover, “a succession of five or six waves, increasing in inten-
sity for the first third of the time and then decreasing ;” in
Montreal “a low rumbling sound followed by a sharp soploaas
and then a tremor.”
In compiling the — I have been able to compare reports
from fifty-eight station
Nov. 14. A slight ion at 9.40 a. m. at Cornwall, Ont.
Nov. 15. About noon several shocks were felt in Iowa and
adjoining portions of Kansas, Nebraska and Dakota. The
- times given were: i loon Gity 1: 12.30 P. M., Council Bluffs 12.15,
G. E. Belknap— Under-water Oceanic Temperature. 27
movement H. to W., Omaha 11.40 a. m., three shocks lasting
ten gos oe apes and Atchison, Ks., 12 M., and Yankton,
De Py Fy
These eas are plainly oe but at this distance no
data are available for correcting
Nov. 16. A slight shock issuly 2.20 a. M. at Knoxville,
Denk.
Noy. 18. A shock about 5 A. M. in the Bermuda Islands —
(N halle Daily Advertiser).
Princeton, N. J., Nov. 30, 1877.
ART. He aeons on under-water So 1 siiaais ;
Captain G. E. Beuxnap, U.S. N.
[When, many years ago, it was announced by eee
Maury and others, that a cold enban might exist in the o
between two adj cent warmer ones, or vice versa and that there
might be a succession of such conditions between the surface a
n e
cases of a similar character. A similar observation was made b
Captain Belknap, of the U. 8. seen while in command of the
. steamer Tuscarora, during her famed cruise in the Pacific ; and
by the courtesy of Commodore Ammen, chief of the Bureau of Nav-
igation, we are permitted to present an abstract of a report made
- that officer on the 2d of September, 1874.—Eps. ]
TubDY of the surface and under-surface temperatures, a
sb Pacific Ocean, has yielded some interesting results. Grea
care was taken to make the observations as accurate ery
any marked change in temperature, the observations were
always — In ing the under-surface temperatur
along the urile Islands, the indications of the Miller-Casella
thermometers were sometimes so startling and perplexing, the
indicated temperatures being so low, that ‘the observations —
often duplicated to verify their accuracy; if the second o!
vation confirmed the first, the results were accepted as aia: :
otherwise they were
roceeding in this way, a 1 cold stratum between two warm
strata, was found to exist quite near the surface, between the
28 G. EF. Belknap—Under-water Oceanic Temperature.
from 20° F. to 28° F.; temperatures manifestly impossible.
There can be no doubt, however, of the existence of the cold
stratum described above, as no temperature was recorded until
repeated observations with different thermometers confirmed its
accuracy.
the coldest surface water was found alone the Kurile Islands,
between the parallels of 45° and 47 ° north latitude. The tem-
there, though the range of latitude traversed was nearly eight
egrees higher. The current in that locality was found to be
setting in a southerly direction, and undoubtedly pouring out
k.
e surface temperatures along the Aleutian Islands show
considerable variation, both in the Pacific and in Behrino’s Sea,
doubtless attributable to tidal influences, the direction of the
wind, and the meeting of different currents.
In passing from Behring’s Sea to the Pacific, through Onni-
mak Pass, on the morning of the 17th of August, the surface
temperature rose seven degrees in one hour, some five to seven
miles inside of the Pass, the current at the time setting with
moderate strength into the sea.
The lowest surface temperature along the Kurile group was
36°-4 F.; along the Aleutian Islands the surface temperatures
ranged from 41°-6 F. to 49° F. and along the continuation of
the line, across the Gulf of Alaska, to Cape Flattery, the range
of temperature was found to be from 50° F. to 59° F., indica-
ting in the most unmistakable manner the influence of that
G. E. Belknap—Under-water Oceanic Temperature. 29
mak Pass is cleared, the temperature of the water rises, and
the current is found to be setting to the southwestward.
The following table will show some of the differences of
temperature observed on the line sounded from Honolulu to
the Bonin Islands, and that part of the northern line from the
emg point of Kamtchatka to Onnimak Pass in Behring’s
ea:
Southern Line, Northern Line,
Central North Pacific. North Pacific and Behring’s Sea.
Surface, ec te 78. 8: 36°-4 to49° F,
Under Surface 30 f’ms,70°°8) — 73°°5 31°°5 41°°9
- BO: * 6875... 727% 31°°9 89°°7
me 100.2": GE 70° 31°°1 38°°5
. 200 “* 48°%5 — 58° 34°°3 37°°9
"3 $00" 64 6075 34°°4 37°°3
. 500 “ 88°9 40°°6 34°°8 35°°9
. 1000 “ 35° 5 33°°5 33°°8
ee 2000: “33° 33°°9 33°°5 33°°8
ns S000. 38°. 7. 83.8 art 33°'3
The very low temperatures noted at the depth of 30
fathoms to 206 fathoms are some of those observed in the cold
stratum already described in this report.
he serial temperatures observed on this northern line were
not so extended as could have been wished, owing to the loss
and breakage of thermometers and to the fact that two of the
instruments furnished had to be thrown aside as worthless. In
the latter case the mercury would crowd up past the needle,
rendering the indications valueless, and that defect in those
instruments could not be overcome.
The thermometers sent down at the 3,664 fathom cast came
up unharmed, and as some of the “ Challenger’s” instruments
broke at a depth of 3,875 fathoms the maximum pressure
which the Miller-Casella thermometers will bear must be some-
where between those depths, or a pressure of about four and
three-fourths tons per square inch.* The temperature indicated
at 3,664 fathoms is 33°°8 F.
I should take into consideration, however, the fact that
using hempen line and time intervals for sounding, that the
depths found by the “Challenger” were not so accurate as those
obtained by the “Tuscarora” with piano wire and dynamo-
meter.
* From later results obtained by the Challenger this deduction is probably
incorrect, as I believe she received whole thermometers back on one or two occa-
sions from a depth of over 4,000 fathoms.
30 H. A. Rowland—Magnetic Effect of Electric Convection.
Art. IV.—On the Magnetic Effect of Electric Convection 7 by
Henry A. Rowuanp of the Johns Hopkins University,
Baltimore.
current. Hence an experiment is of v
well, in his “ Treatise on Electricity,” Art. 770, has computed
The apparatus employed consisted of a vulcanite disc 21-1
and ‘} centimeter thick which could
be made to revolve around a vertical axis with a velocity of
61: turns per second. On either side of the disc ata distance
of 6 cm. were fixed glass plates having a diameter of 38-9
em. and a hole in the center of 7-8 em. The vulecanite disc
readily and there should be no uncertainty as to the electrifica-
ion. The outside plates were usually connected with the earth ;
and the inside dise with an electric battery, by means of a point
not discharge unless there was a difference of potential between
it and the edge. Between the electric battery and the disc, a
were of non-magnetic material.
Over the surface of the dise was suspended, from a bracket
in the wall, an extremely delicate astatic needle, protected from
electric action and currents of air by a brass tube. The two
es were 15 cm. long and their centers 17-98 em. distant
od
other. readings
The opening in the tube for observing t
* The experiments described were made in the laboratory of the Berlin Uni-
versity through the kindness of Professor Helmholtz, to whose advice they are
; ir com : idea of the experiment first occurred
to me in 1868 and was in a note book of that date.
H. A. Rowland—Magnetic Effect of Electric Convection. 31
from electrical action by a metallic cone, the mirror being at its
vert So perfectly was this accomplished that no effect of
electrical action was apparent either on charging the battery or
reversing the electrification of the disc. The needles were so
far apart that any action of the disc would be many fold greater
on the lower needle than the upper. The direction of the nee-
dles was that of the motion of the disc directly below them,
that is, perpendicular to the radius drawn from the axis to the
needle. As the support of the needle was the wall of the lab-
oratory and revolving disc was on a table beneath it, the needle
was reasonably free from vibration.
In the first experiments with this apparatus no effect was
observed other than a constant deflection which was reversed
with the direction of the motion. This was finally traced to
many weeks, the needle always answered to a change of electri-
fication of the disc. Also on raising the potential above zero
the action was the reverse of that when it was lowe elow.
The swing of the needle on reversing the electrification was
about 10° or 15- millimeters and therefore the point of equili-
brium was altered 5 or 74 millimeters. This quantity varied
with the electrification, the velocity of motion, the sensitive-
ness of the needle, ete.
The direction of the action may be thus defined. Calling
the motion of the dise +- when it moved like the hands of a
axis, and on changing the electrification, the north pole moved
away from the axis. With — motion and + electrification, the
north pole moved away from the axis, and with — electrifica-
tion, it moved toward the axis. The direction is therefore that
in which we should expect it to :
To prevent any suspicion of currents in the gilded surfaces,
382 H. A. Rowland—Maynetic Effect of Electric Convection.
the latter, in many experiments, were divided into small por-
tions by radial scratches, so that no tangential currents could
take place without sufficient difference of potential to produce
sparks. But to be perfectly certain, the gilded disc was re-
placed by a plane thin glass plate which could be electrified by
Neb on one side, a gilder induction plate at zero potential
eing on the other. With this arrangement, effects in the same ©
direction as before were obtained, but smaller in quantity, see-
ing that only one side of the plate could be electritied.
The inductor plates were now removed, leaving the disc per-
fectly free, and the iatter was once more gilded with a continu-
ous gold surface, having only an opening around the axis of
35cm. The gilding of the dise was connected with the axis
and so was ata potential of zero. On one side of the plate,
two small inductors formed of pieces of tin-foil on glass plates,
were supported, having the disc between them. On electrifying
these, the disc at the points opposite them was electrified by
induction but there could be no electrification except at points
near the inductors. On now revolving the disc, if the induc-
tors were very small, the electricity would remain nearly at rest
and the plate would as it were revolve through it. Hence in
this case we should have conduction without motion of elec-
8.
electricity is being constantly conducted in the plate so as to
retain its position. Now the function which expresses the po-
tential producing these currents and its differential coefficients
must be continuous throughout the disc, and so these currents
must pervade the whole disc.
To calculate these currents we have two ways. Hither we
ean consider the electricity at rest and the motion of the dise
through it to produce an electromotive force in the direction of
motion and proportional to the velocity of motion, to the elec-
trification, and to the surface resistance; or, as Professor Helm-
oltz has suggested, we can consider the electricity to move
with the dise and as it comes to the edge of the inductor to be
set free to return by conduction currents to the other edge of
the inductor so as to supply the loss there. The problem is
eapable of solution in the case of a dise without a hole in the
center but the results are too complicated to be of much use.
Hence scratches were made on the disc in concentric circles
about °6 em. apart by which the radial component of the cur-
rents was destroyed and the problem became easily calculable.
For, let the inductor cover Me the part of the circumference
_of any one of the conducting circles; then, if C is a constant,
:
i |
Hi, A. Rowland—Moagnetie Hffect of Electric Convection. 33
the current in the circle outside the inductor will be oS and
inside the area of the inductor -C On the latter is su-
perposed the convection current equal to +C. Hence the
- motion of electricity throughout the whole circle is re what it
would have been had the inductor covered the whole circle.
In one experiment 2 was about 8. By comparison with the
other experiments we know that had electric conduction alone
presence of so many disturbing causes. o effect was dis-
deflection of the astatic needle as follows. Turning the two
needles with poles in the same direction and observing the
number # of vibrations, and then turning them opposite and
finding the number n’ of vibrations in that position, we shall
find, when the lower needle is the strongest,
n?- 4
n? tn’? — n2 +n? D (1)
Where X’ and X are the forces on the upper and lower needle
respectively, 4 the deflection, D the distance of the scale and
H the horizontal component of the earth's magnetism. As X’
and n’ are very small the first term is nearly X—X’. The tor-
sion of the silk fiber was too small to affect the result, or at
least was almost eliminated by the method of experiment.
The electricity was in the first experiment distributed nearly
uniformly over the dise with the exception of the oe in
the center and the excess of distribution on the edge. The
surface density on either side was
Am. Jour. isi sas! esses. Vou. XV, No. 85.—Jan., 1878,
384 H. A. Rowland—Magnetic Effect of Electric Convection.
V-V'
es 27(B—p) (2)
V—V’ being the difference of potential between the disc and
the outside plates, 6 the thickness of the disc and B the whole
distance apart of the outside plates. The excess on the edge
was (Maxwell’s Electricity, Art. 196, Eq. 18),
BC 4
E=2(V—V’) xB) log, (2 cos 3B) (3)
where C is the radius of the disc.
x= eee '_(o+@)dedy _
— D Aeryply (a2 2:2 4yt)t
perme Om (b-+-2)VC?2—(b-x)?
© IS 04y (a? a?) Va? + C2 —b2 — 26a"
where a is the distance of the needle from the disc and } that
from the axis; N is the number of revolutions of the disc per
second and v=28,800,000,000 centimeters per second according
to Maxwell’s determination. The above integral can be. ob-
tained exactly by elliptic integrals, but as it introduces a great
variety of complete and incomplete elliptic integrals of all three
orders, we shal] do best by expanding as follows:
_t2No
4aNo
X= Pa" (A, FAL +A; + he), (4)
C-—b C+) M
A,=20( are tan arg -+- are tan mE ) — a log, N’
M
A,=—S( (648) log, 5: gare 20),
. M
A= ; —4Cs-+ (3s?-+-2sb+-a?) log, N
4Cb
+-(582+-36"b--at(s42) Joe | &e, &e.,
2 C2—f2
M>=a?-+(C+6)?, N=a?+(C—2)2,
H. A. Rowland— Magnetic Effect of Electric Convection. 35
From this must be subtracted the effect of the opening in the
center, for which the same formula will apply.
The magnetic action of the excess at the edge may be caleu-
lated on the supposition that that excess is concentrated in a
circle of a little smaller diameter, C’, than the disc;
NE ak 2—k?
WAG:
where ae at ia a and F(x) and K(#) are complete ellip-
tic integrals of the second and first orders respectively.
he determination of the potential was by means of the
spark which Thomson has experimented on in absolute meas-
ure. For sparks of length 7 between two surfaces nearly plane,
we have on the centimeter, gram, second system, from Thom-
son’s experiments,
V—V'=117°5(7+ 0135),
and for two balls of finite radius, we find, by considering the
distribution on the two sheets of an hyperboloid of revolution,
r V/r+1+1
Wrpi 9 VSrpi-l
where r is the ratio of the length of spark to diameter of balls
and had in these experiments a value of about 8. In this case
V—V'=109°6 (74-0135). (6)
A battery of nine large jars, each 48-¢. m. high, contained
the store of electricity supplied to the disc, and the difference
of potential was determined before and after the experiment by
charging a small jar and testing its length of spark. Two
determinations were made before and two after each experi-
ment, and the mean taken as representing the potential during
the experiment.
The velocity of the dise was kept constant by observing a
governor. The number of revolutions was the same, nearly,
as determined by the sizes of the pulleys or the sound of a
beck siren attached to the axis of the disc; the secret o
this agreement was that the driving cords were well supplied
with rosin. The number of revolutions was 61: per second.
In such a delicate experiment, the disturbing causes, such as
the changes of the earth’s magnetism, the changing temperature
of the room, &c., were so numerous that only on few days could
numerical results be obtained, and even then the accuracy
could not be great. The centimeter, gram, second system, was
used
V—V'=117'5 (J-+--0135) log.
First Series. a=205, b=9-08, n=-697, D=110, H—-182
nearly, B=1°68, 6=50, C=1055, N—61+, v=28,800,000,000;,
n' =-0533, C’=10.
86 H. A. Rowland—Magnetic Effect of Electric Convection.
Deflection on
Direction of | Electrifica- [Scale reading; reversing Length of
motion. tion of disc. in mm, electrifcat'n spark.
99-
+ + 1075 7°25 "295
_ 101°5
68°5
se — 165 8°25 290
= 68-0
® + 97
+ a 91°5 7-00 282
- 100:
ne 59°
pa _ 65°5 6°75 265
. a 58°5
+ 92°65
ee _ 85° 6°75 290
- 91-0
+ 52°5
ee a 57-5 5°50 285
_ 515
+ 82°0
+ _ 760 5°85 285
+ 81-7
+ 36°5
ces —_ 43°0 6°50 275
55 36°5
+ 68°0
re as 61-0 7-00 290
1 68-0
+ 27°5
= 33°5 6°50 “288
~ 26°5
Mean values. | 6435 | 2845
"6735
Hence, 4=—,- ='337 and /=°2845.
From equation (1),
X—99 X’= nee =00000327.
~~ 305700"
By calculation from the aoe oe we find
—-99 X’=—_—— = 00000337.
xX—°99 —— ea: 0337.
The effect on the upper needle, X’, was about ;', of that on
.
the lower
Second 3 Everything the same as before except the
following. b=7°65, n’=0525.
Hf, A. Rowland—Magnetic Effect of Electric Convection. 37
Deflection o
Direction of | Electrifica- +
main Lipeetaeal eae alent | engin of
+ 172°5
+ _ 165°5 7-0 “300
172°5
+ 120°0
aes _ 127°5 ‘i
+ 121°5 fi ~~
= 129°0
_ 163°5
+ 170°5 x i,
- “a aa 1-25 297
fe 170°5
+ 118°0
_ 127-0 3 x
2 pets 8-25 270
—_— 127°5
Mean values. 7°50 "2955
s 22 Sia, t= -2955.
Hence for this case we have from equation (1),
X—-'99 X’= eee, Sonor -00000317.
~~ 315000°
And from the electrification,
x—'99 X’— : ——-==°00000349.
286000"
Series. Everything the same as in the first series,
etieet vs =8'1, n’=-0521, D=114.
Direction of | Electrifi Scale reading yg on a Length of.
motion. tion of disc. be mm. elecirifieat’n spark.
+ 151-0
— 158°5 7°50 "287
- 151°0
+ 192°0
mo —_ 185°5 726 292
ee 193°5
_ 1575
Ss - 148°5 : ;
ee 1575 8°25 295
- 150°0
_ 185:0
+ 192°5
+ a. 185°5 7-45. 302
+ 193°5
—_ 151°0
_— ad 143°5 7-25 287
— 150°5
Mean values. 760 486| =| 2926
38. M. Mitchell— Observations on Jupiter and its Satellites.
° Ate "380, f= *20926.
For this case Fri equation (1)
1
— 99 X’—— —_ — 000 0339,
x < 295000° ‘niet
and from the electrification
X—-°99 X’=— -— =="00000355.
sais00.
The error amounts to 38, 10 and 4 per cent respectively in the
three series. Had we taken Weber's value of v the agreement
would have been still nearer. Considering the difficulty of
the experiment and the many sources of error, we may con-
sider the agreement very satisfactory. The force measured is,
we observe, about 50000: of the horizontal force of the earth’s
magnetis
The difenenes of readings with + and — motion is due to
the magnetism of rotation of the brass axis. This action is
eliminated from the resu
meters per r second satisfies the first and last series of the experi-
ments the best.
Berlin, February 15th, 1876.
Art. V.—Notes of Observations on Jupiter and its Satellites ; by
| Maria MITCHELL.
THE following observations were made at the observatory of
Vassar College; longitude 45 55™ 38s, latitude 41° 41’ 18”.
The instrument used was the Equatorial telescope; the power
usually 230.
1874, May 2.—Observations on Jupiter began at 10% 18™.
The seeing was excellent. With a power of 600 the ruddiness
of the equatorial belt was brought out; two Janae dark spots
on its upper portion were —— striking in appearance, the
ted space between them being conspicuously white.
The shadow of the 4th satellite was near egress. It touched
the limit of the planet, in internal contact at 105 37™ 10s3,
ore was last seen at 11" 2m 4588. At times during the hour I
ht the shadow was followed by a companion s
at rh May 3.—The 3d satellite of Jupiter was occulted a
95 11m 98-5. [This observation is by Miss Fisher iealents
with a small telescope.]
556 ee
M. Mitchell— Observations on Jupiter and its Satellites. 39
1874, May 7.—The ingress of the Ist satellite of Jupiter was
observed. The satellite was in external contact at 105 50" 39s.
The internal contact was at 105 55™ 7s,
1874, May 14.—Observations on Jupiter began at 8 P. M.
The broad equatorial belt was rosy and was seen fully out to
the following limb. The shadow of the 3d satellite was upon
the disc. The shadow was dark but not black. I could not~
call it circular; the longer diameter was nearly parallel with ~
the equatorial belt. It left the planet’s disc at 10 1™ 118-1.
1874, May 19.—The noticeable peculiarity of the planet's
disc is that of a large white spot on the broad belt near the
center at 8410™ p.m. At 95 45™ no trace of this spot could
be found, although the equatorial belt was seen out to the
preceding limb.
1874, May 22.—There was a very decided change in the
spots from dark to light between 95 6™ Pp. M. and 95 35™ P, M.
1874, May 28.—The planet was unusually striped. The broad
belt was much spotted and its upper part heavily shaded.
There was a rosy tinge over the whole belt. The 3d satellite
touched the limb of Jupiter, at ingress, at 9" 56" 44s p.m. Its
internal contact was at 10° 6™ 15° p. M. Although it entered
on a part of the planet which was not bright, it could be fol-
lowed only ten minutes.
1874, June 2—There were peculiar white markings on the
lower part of the equatorial belt of Jupiter; these were beyond
the center-at 8" 25™. The 2d satellite touched the limb in
The internal contact with limb was at 0° 46" 16%. The satel-
lite was last seen 1" 2™ 51°, although it was upon the dark belt.
The shadow was followed for some six minutes longer.
1875, April 23.—The 8d satellite of Jupiter was wholly off
from the dise of the planet at 7°15" 2° p.m. The shadow of
the 3d satellite touched the limb, at egress, at 7° 43™ 7° P. M.
The shadow was wholly off at 8° 1™ 51° p. M. Measurements
were made of both satellite and shadow. The diameter of the
satellite measured 2’"17, of the shadow 17°95. :
1875, April 30.—The 3d satellite touched the following
limb of Jupiter at 8° 21™ 19°-3. The internal contact was at
8" 40™ 24*-3. The shadow of the satellite was fully upon the
disc at 9" 48" 9*-3. The equatorial belt was slightly ruddy,
and dark and white spots could be seen upon it. The Ist and
4th satellites were so nearly of the same size that I could dis-
tinguish them only by position. :
1875, May 10, 8 to 9.30 P. Mi—A white loop extended diag-
onally over more than half the equatorial belt of Jupiter.
40 M. Mitchell—Observations on Jupiter and its Satellites.
1875, June 2.—Observations began at 7°55" p. M. A very
remarkable white spot was at once seen, nearly at the center of
Jupiter’s disc. It was followed by a very dark shading, so
that it strongly resembled a satellite and shadow in transit.
The white spot was so well defined as to be easily measured.
ve escisa'g diameter (oblique to equatorial belt) was 1’'°7.
. . the white spot was approaching the limb of the
tess stnidag a es with the planet, and was followed
y one ate and less distinet.
5, —Observations began at 7° 30" P. M. At
Ya oa no Petites spot could be seen. At 3 15™ the white spot
with the _ appearance of shadow eee could be
seen, as on June 2. It was, at this time, 4 of t iameter of
Jupiter, distant from the following limb. At gh 15™ the sec-
ond white spot was seen, following the first, as on June 2.
The 1st satellite touched the limb of Jupiter at 8" 21™ 24* Pp. M.
The internal contact was at 8" 26™ 19° p. m. The satellite
entered upon the planet below the broad belt, very white,
more brilliant than the spot, but smaller and scarcely more
conspicuous. The vipa 3 of the satellite was first seen upon
the disc at 9° 23™ . M.
1876, May 30. LOBbertaons began at 9" 39" p. Mm. The
broad belt on the dise of J upiter was mostly above the equator.
lt was mottled with large white spots, somewhat rose-tinged.
th 1st satellite as it approached the planet was of a dazzling
whiteness; it entered upon the disc above the lower margin of
the equatorial belt, yet it could be seen for only twelve min-
utes. The shadow entered on the disc about sixteen minutes
later very black, but not round, the longer diameter bein
=~ a perpendicular to equatorial belt. 1st satellite touched
limb of . at 9" 538™ 26° Pp. M.; was at internal contact
. 59™ 22°. ‘The shadow was wholly on the disc at 10" 15™ 128
ca The satellite was seen at 10° 11™ 32*p.m. It is poets
that the satellite was faintly seen at 10° 34™ 2°.
1876, May 31.—The peculiarity in the appearance of Jupiter
is the presence of bright white spots on the upper portion of
the disc, markings resembling facule on the he first
satellite was seen to come out of eclipse at 9" 44™ 41°-99.
1876, June 15.—Observations on Jupiter began at 8" 20™ P. M.
The first satellite was known to be in transit, but could not be
seen upon the disc. The shadow of the Ist satellite was
wholly within the limb at 9" 34" 51°9. At 9" 55™ 36°9 the
3d satellite was seen to come out from eccultation. At 9" 58”
11*-9 the 3d satellite was wholly out and shining with brilliant
white light. At 9" 20™ 42° the Ist satellite was found, a
ing the preceding limb, a dull gray figure, elliptic in shape, the
major axis being perpe equatorial belt. When this
J. P. Gooke—Atomic Weight of Antimony. 41
satellite reached the limb it was as white as the 8d satellite, and
rou e transit was made across the brightest part of the
disc, and where there were no perceptible variations of brillianey.
The 1st satellite’s last contact with limb was at 10" 2™ 47®
1876, June 22.—Observations began at 10°12" p.m. The
Ist satellite, known to be upon the disc, could not be found.
The shadow was wholly on at 10°26" 56%. The satellite was
seen, dusky, oval and gray, from 10" 55" 33° to 11" 10™ 33°.
1877, June 13.—The shadow of the 2d satellite was seen,
wholly entered upon the disc, at 11° 20" 45%. The satellite
itself touched the limb at 11" 36™ 07°; was at internal contact
at 11" 43™ 30°.
1877, June 19.—The 8d satellite touched the limb of the
lanet at 10° 47"58°. The internal contact was at 10" 59™ 10%.
he 1st satellite reappeared from occultation at 11" 4™ 51%.
The ruddiness of the equatorial belt was noticed by several
observers.
Art. VI.—Revision of the Atomic Weight of Antimony; by
JosraH P. Cooks, Jr.
[Abstract of a paper, in the Proceedings of the American Academy of Arts and
Sciences, xiii, 1, prepared by the Author.]
antimony glance by means of hydrogen and his investigation
was a model of its kind. In his paper* all the details of the
experimental work are given and it is evident that every precau-
tion was taken which the circumstances required. In 1857,
this result was apparently closely confirmed by Dumas, whose
analyses of antimonious chloride gave almost precisely 122.
he present investigation was undertaken with the view of
reconciling if possible the large discrepancy between the results
suggested by the method, devised by the author, of precipitating
sulphides which was described in a previous number of this
* Poggendorff’s Annalen, xcviii, 455, June, 1856. i c, 563, April, 1857.
+ Ann. Chem. et de Phys., II, lv, 175, Feb, 1859. § This Journal, If, xiii, 427.
42 J. P. Cooke—Atomic Weight of Antimony.
from the circumstance that the antimonious sulphide as usually
precipitated occludes a small amount of tartaric acid on the
one hand and of oxichloride of antimony on the other. These
occlusions tend to produce errors in opposite directions, for
when, before weighing, the red antimonious sulphide is heated
to the point of its conversion into the gray modification, the
tartaric acid is charred, and the carbonaceous residue increases
the apparent weight of the product; while on the other hand
the oxichloride of antimony is decomposed at the same tem-
perature and the antimonious chloride, which volatilizes, tends
to diminish the weight of the product. In the earlier deter-
minations these causes of error were balanced as nearly as
possible by regulating the conditions of the precipitation; but
it was subsequently found to be possible to entirely prevent the
occlusion of antimonious oxichloride, and in all the later deter-
minations allowance was made for the small amount of carbon-
lowing determinations of the specific gravities of the different
C., on
the assumption that the coefficient of cubic expansion for anti-
mony between 0° and 100° C. is for each degree 0:0000838, as
bserved by Kopp. The letters here given will be used
throughout the table to designate the various specimens. As
might be supposed, the specimens were prepared at different
times and at different stages of the investigation, but the results
are united here for the convenience of comparison and of refer-
ence.
Spreciric Graviries oF Butrons or Pure Metatiic ANTIMONY.
Observations of J. P. C., Jr. Observations of W. Dexter.
A ie 1000 | DL. . 6°7087
Be 70s |) 6 ee 6°7026
» 6°6957 | ¢ . .6°6987
D 6°7070 | d 6°7102
Bec Se Oe ee 6°7047
Rea, Re Aeien ee 6700S) SiS Se 6°7052
Mean...... -. ....6°7022 | Mean 6°7050
The processes used in preparing the several buttons just
referred to, the method by which the metal was brought into
solution in its lowest condition of quantivalence, and the man-
ner in which the antimonious sulphide was precipitated, col-
lected, dried and ene are all described at length in the
original paper. The following table shows the results which
were obtained.
*Poggendorff’s Annalen, ¢, 564 (I. c.).
Synruesis oF SULPHIDE OF ANTIMONY,
Wt. of red ee oat Wt. of black Wg pr
No. Wt. in day of Wt. dissolved Total weight Sb,8, Per seb of 8 gal {Sb Sb,S, dried at Per cent. of S Ape f Sb
Sb taken from balls. of Sb used, dried at 180°C. in same. 1en ‘pasa 210° C. in same. hen 839,
1, A. 2 0036 0°2023 2°2059 8°0898 aie ee 79 3088 28°57 "hue-0c
2,. Be 20017 02662 2°2679 3°1778 28.63 119°64 3°1764 28°60 119°82*
$ KE, 2°0113 00853 2°0966 2°9383 28°65 119°56 2°9350 28°57 120.03*
4, A, 1°09 00798 20771 2°9051 28°50 120°41 2°9021 28°43 120°85
5, E. 2°0019 01087 2°1106 2°9508 28°47 120°57 2°9486 28°42 120°89+
Mean se Determinatiote 3... °°" > SK. 28572 119°994 wee eo 28°518 120°32
G -AY .1'768 00430 1°8068 2°5301 28°59 119°91 got OS e eiee ae
7 Ag «2 ers 00894 2°1169 2°9639 28°57 Pie ee, Om ae. 2 Be 5 ae
8 B. 20116 00188 2°0304 2°8423 28°57 120°04 2°8410 28°53 120 238
9, -B. 2 20027 0°1000 2°1027 2°9429 28°55 120°13 2°9409 28°50 120°41
10, 22015 01424 2°1439 3°0025 28°58 119°94 2°9931 28°49 ~ -120°47
11, E. 2:0038 0°3379 2°3417 3°2792 28°59 119°90 3°2788 38°58 119°95
12. E. 20014 02168 2°2182 31061 28°59 119°92 3°1022 28°50 120°44
Mean of ot & Determigations -25. 2." 5, S..s<. 28°576 716-086. = So. 28°520 120°298
13, 6 0°3787 2°3843 3°3369 28°55 120°34 _ 83369 28°51 120°14||
Mean of the 18 Determinations <...2°. 4; =k Babiab. - $1094. 9 =4-.2- 28°522 120°295
Large residue of eB small sublimate. | No sublimate or loss of weight on drying and conversion. Residue large,
We ight of black bey Sam ound. be made under conditions.
Hit ie sidue of ca ea sublimate. but weighed and subtracted. The best determination, and as perfect as can
Both residue and sublimate see
44 J. P. Cooke—Atomic Weight of Antimony.
We were for some time in doubt in what condition the sul-
phide of antimony ought to be weighed, in order to obtain the
most accurate results. Our final judgment was that the errors
already referred to would best be balanced, while others would
be avoided, by weighing the sulphide, after it had been dried,
at from 180° to 200° , but before it was actually converted into
the gray sulphide "This conversion takes place between 210°
and 220°, varying to that extent in different cases. The change,
as we infer, is attended with a sudden evolution of heat, and
the action is quite violent. Small particles of the material are
See projected from the vessel, and we sometimes noticed
that the surface of the platinum nacelle became coated with the
familiar sublimate of sulphide of antimony. If there is oxi-
chloride in the precipitate, there may be an additional volatiliza-
tion of chloride of antimony at this time; but the main loss, as
we have constantly observed, ee place before the point of
conversion is reac e therefore concluded that more
trustworthy results could be deduedl from the wees of the
red sulphide dried, as we have described, than from that of the
gray ; and, as will ‘be seen, this judgment was fully confirmed
by subsequent experiments on the haloid compounds. We
have, however, in all but two instances weighed the sulphide
in both con ditions, and we give the results of both yelptiaes :
and on comparing these results in determinations eight to
thirteen inclusive of the table on page 48, which were made
under the nearly identical conditions we have above indicated,
it will be seen that the differences are far smaller with the red
sulphide than with the gray, which shows conclusively that
additional causes of error must have affected the last weights,
—a circumstance which sustains our judgment.
n the first twelve determinations we did not estimate the
amount of the carbonaceous residue, which is assumed to
without the usual occlusion — een onde In this case, there
was no evidence . sublimation nor loss during conversion, but
a proportionally large carbonaceous residue, which was deducted
from the ncaa of the sulphide; and the result of this deter-
mination, as ‘will be seen, still further corroborates our conclu-
sion. The same is true of the analyses of chloride of antimony
made more recently, in which we dissolved crystallized chloride
of antimony in a concentrated aqueous solution of tartaric acid,
without using any excess of hydrochloric acid. In these cases
, the drying of the precipitate, and the conversion from the
red to the gray modification, were attended with no appearance
J. P. Cooke—Atomic Weight of Antimony. 45
of sublimation. Were we to repeat the investigation with our
— knowledge, we should follow the indications of these
ast analyses; and instead of attemping to make the two chief
errors as small as possible, and balance them, we should seek
to remove from the solution all the free hydrochloric acid, and
thus eliminate the error due to the occlusion of oxichloride. It
would then, of course, be necessary to determine in all cases
the carbonaceous residue, which might however be very large,
without impairing the accuracy of the result. Still, our experi-
ence with shea antimony determinations would lead us to fear
that we might thus raise up as many hindrances as we avoided,
and the determination we have given as No. 13 is sufficient for
all purposes of comparison.
his point in our investigation was reached in the spring of
1876, and the results given above were presented to the Ameri-
can Academy of Arts and Sciences at their meeting of June
14th, 1876. But although they agreed so closely with the
results of Schneider, and although the close confirmation of his
analysis thus furnished by our synthesis seemed so conclusive,
ier we could not rest satisfied so long as the great discrepancy
tween this value of the atomic weight and the higher number
obtained by Dumas remained unexplained. We therefore
chloride, and the r are united in the following table.
Beginning with crystallized chloride of antimony obtained from
different dealers, an in a commercial sense, we first
further peso by repeated crystallizations from fusion. As
e
latent heat), it is easy to arrest the process at any point, and
ed off the still liquid portion from the erystals which have
iormed. The
46 J. P. Cooke—Atomic Weight of Antimony.
repeated, and so on indefinitely as long as the material lasts.
In this way, from several ‘kilograms of the commercial
chloride we obtained the few grams of beautifully clear and
perfect crystals used in our analyses. In the fifth preparation,
the crystals were obtained not by fusion, but by cooling a
saturated solution of the previously distilled chloride in purified
sulphide of carbon. Such a solution, saturated at the boiling
point of sulphide of carbon, deposits the larger part of the
chloride, when cooled to the ordinary temperature. Naturally,
every precaution was taken during the course of these prepara-
tions to protect this exceedingly hygroscopic substance from
contact with moist air, and all the transfers were made in a
portable photographic developing chamber, the air of which
was kept dry by dishes of sulphuric acid. The portions for
analysis were transferred, in this chamber, to tightly fitting
weighing tubes; and, after the weight was taken, they were
dissolved in a concentrated aqueous solution of tartaric acid,
using about five grams of tartaric acid to each gram of chloride
of antimony. Thesolutions were then diluted
in an air bath at temperatures varying from 110° to 120°.
They were weighed with the small dis k of paper used in this
H. ay and, ‘the excess of this reagent having Beene ved by
warming the filtrate with a small eae: of ferric aie: the
bea abies tallized chloride of Veron and Fontaine, Paris, which was
Purified in the manner described above,
6 Was made from a erystallized chloride marked Rousseau Fréres, Paris, purified
as before.
c Was tasters again distilled and crystallized.
d, The same c, after ten additional distillations.
u
et eee
J. P. Cooke---Atomic Weight of Antimony. 47
e, The same as d, again distilled below 100° in a current of dry hydrogen gas.
f Was made with a crystallized chloride from Merck of Dermoid purified by
ulphide of car-
g, Same as f, but in this determination the antimony was first precipitated from
the solution
ANALYsis OF ANTIMONIOUS CHLORIDE.
DETERMINATION OF CHLORINE.
% of Chlorin
SbCl, AgCl. C1=35'5 At. Wt. of Sb
No. grams. grams. g=108. =35
LG 1°5974 yielded 3°0124 46°653 121°78
2a 1°2533 = 2°3620 46°623 121°93
3 a. 0°8876 v2 1°6754 46°696 121°57
4b, 0°9336 is 15674 46°516 122°46
5 6. 0°5326 #: 1°0021 46°446 122°30
6 0°7270 34 1°3691 46°588 122-10
TSG 1°2679 se 2°3883 46°599 122°04
8 « 1°9422 oa 3°6646 46°678 121°66
9e 1°7702 Ke 3°3384 46°655 121°77
10d. 2°5030 oe 4°7184 46°635 121°87
11 d. 2°1450 ng 4°0410 . 46°616 121°96
12 e 1°7697 . 3°3281 46°524 122°42
13 @. 2°3435 3 4°4157 46°613 121°98
14 f. 1°3686 ss 2°5813 46°659 121°75
157. 18638“ 3°5146 46°650 121°79
16 f. 2°0300 e 3°8282 46°653 121°78
17 g. 2°4450 “ 4°6086 46°630 121°89
Mean value for all analyses 46°620 121°94
Theory when Sb = 122 46608 122°
: “g: == 120 47-020 120°
If in calculating the per cent of chlorine from the results of
the above determinations we use the atomic weights for silver
and ehladne obtained by Stas (namely, Cl=35°457 and Ag=
107-93), these per cents will be in each case very nearly 0-020
lower, and we shall obtain for the mean value 46°600 instead
of 46-620. pons on this assumption the atomic weight of
antimony, deduc m Dumas’s cag of the chloride, would
be 121-95 foatead of 199 Again, if we use Stas’s value of the
atomic weight of sul has (S=32-074) in pA ee tlfe atomic
weight of antimony rom ourown results, on the synthesis of the
sulphide, we should para 120-28 instead of 120; and, lastly, the
values Sb=120-28 Cl=85'457 give for the per cent of
ehlorine i . antimonious chloride the value 46-931.
ere, then, is a most striking result: for these determina-
tions Nitin the value of the atomic weight of pulicoat
48 J. P. Cooke—Atomic Weight of Antimony.
obtained by Dumas as closely as did the previous determina-
tions confirm that obtained by Schneider. Evidently, there
was a large constant error in one case or the other. Moreover,
it appeared improbable that in either case any error could arise
in the chemical process employed: for, in the first instance, we
had a synthesis by one method confirming an analysis by a
wholly different method ; and, in the second instance, the analy-
tical process employed is regarded as one of the most accurate
known to science, and we had apparent’). shown that its accu-
racy was not impaired under the peculiar conditions present.
It appeared, therefore, reasonable to assume that the results did
truly indicate both the actual proportion of antimony in the
sulphide of antimony and of chlorine in the chloride of anti-
mony analyzed, and to look for the cause of the discrepancy to
some impurity in one or the other compound. e therefore
next sought to determine how much sulphide of antimon
could be obtained from a given weight of chloride of antimony,
hoping that by thus bringing the relations of antimony to
chlorine and sulphur into close comparison the source of the
error might be indicat
The following table exhibits the results of these antimony
determinations, as well as the general result of the assumed
complete analysis of antimonious chloride. The per cent of
chlorine taken is the mean of the first thirteen determinations
of the previous table, as these only had been made at the time
the second table was drawn up, and it therefore exhibits the
results exactly as they were presented to us at this stage of the
investigation.
ANALYSIS OF ANTIMONIOUS CHLORIDE.
DETERMINATION OF ANTIMONY.
SbCl, taken in Sb,S, obtained ¢ of = irra mem when @ of Antimony if
grams. in grams. = S=-120: 42.* Sb: S=122 : 32.+
15. 3°8846 2°8973 53°275 53°525
26. 5°1317 3°8417 53°473 53°725
36, 44480 3°3201 53°316 53°567
4 b. 506 3°4009 53°882 53°633
56. 4°8077 3°6072 53°593 53°845
6 774 3°1958 . 53°367 53°618
Mean of all Analyses 53-401 53°652
: MEAN RESULTS OF COMPLETE ANALYSIS.
Antimony, the mean of six determinations 53°401 53°652
Chlori «“ thirteen “ 46°611f 46°61 er,
100°012 100°263
*Or wie that of the gray sulphide is antimony, as deduced from actual
> sain generall. pted theory.
En Oe ee aed 1g=1G8. Cocttaing © Dewie:
C. U. Shepard, Jr.—A new mineral, Pyrophosphorite. 49
As they at first repented themselves to us, these new results,
so far from throwing light on the subject, only rendered the
problem the more obscure and baffling. Towards interpreting
value our own spe eriments and those of Schneider might have
in fixing the atomic weight of antimony, they had at least
established, SR: all doubt, the proportion of this element in
the gray sulphide weighed in our antimony determinations.
For if we assumed, as those experiments indicated, that five-
sevenths of the gray sulpbide was antimony, then the amounts
of antimony and chlorine found in the analysis of antimonious
chloride just made almost exactly supplemented eac
while on the other hand, if this material was, as generally
believed, pure Sb,S,, in which Sb:S=122: 32, then our deter-
minations of one or the other of these elements must be greatly
erroneous, and the excess obtained far too great to be explained
y any known or probable imperfections of our Of
course, although the gray sulphide might contain, on the aver-
age, five-sevenths of its weight of ne ape it was a possible
etDpomnos that it rca also occlude a constant amount of
and taken into the account, and in our later determination even
this had been reduced to sosmall an amount as to be wholly
insignificant
[To be continued. ]
Art. VII.—On a new ecineral Pyrophosphorite: an Anhydrous
Pyrophosphate ve Lime from the West Indies ; by CHARLES
UpHaM SHEPARD, Jr., Professor of Chemistry in the Medi-
cal College of ne State of South Carolina
TurovuGu the kindness of Mr. C. C. Wyllie of London, Eng-
land, I have been put in the possession of a few small fragments
of a mineral phosphate from a new locality in the West Indies.
Commercial considerations forbid at present the aes a of
the precise position of this deposit, but later I hope to
to announce it, as also to give iatorseten with regard to the
— amen of occurrence, and so 0
R. Scr.—TutepD Sees Von. XV, No. * —Jan., 1878.
50 CU. Shepard, Jr.—A new mineral, Pyrophosphorite.
The mineral is generally snow-white and opaque, with here
and there aslight tinge of bluish-gray. The white portion is =
and has an earthy fracture like magnesite; the grayish—c
stituting perhaps one-third of the mass—is small- bothyoidal
like gibbsite, and is somewhat the harder of the two.
The specific gravity varies between 2°50 and 2°58; hardness
between 3 and 8°. Before the blowpipe it melts with diffi-
culty on the eles to a whitish enamel.
The following are the results of several chemical analyses of
the mineral, as ‘executed on two different portions of material :
1st Series. 2d Series. Mean.
ee on imitans. wie OBOO. 6 eas 0°390
Rar os Sot Bes Se 44°50 44°424 44°462
Ma: meee (AL a. eet 3°141 3°090
Stloberie WGd 0°57 0°687 0°628
Eoeephoric A010. ods aes « BOOT 50°629 50°799
Silic =i pe gp OE | ge 0°434 0°367
Oxide of iron and alumina .--- 0°437 0°437
100°1738
If we add together the adventitious ingredients, viz: the
pyrophosphates of iron oe alumina (taking an equal portion
of phosphoric acid as the oxide of iron sehen the
sulphate of lime, silica and ‘cs on ignition, we obtai
ae sank
BLA sole aay of iron and alumina -_-.---- 0°874
Sulph Mie siud oak Peelers ee ee
Silica Siwalesse bas eee ee Ce Bee 0°367
AO Ob, SOWICION 5 0 as 2 a ns oe ee
2°699
There remain,
t.
Mare tid co's apie 44°022 or 45°16
ee 3°090 3°17 | on raising the
Phasphoris acid 50°362 51°67 2 ihe 4 per cent.
ee 0 per cent,
97°474 100°00
The above composition agrees with the formula
2MgO, P,0,+4(5Ca0, 2P,0,)* or2MgO, P,0,+4 } ocaO FO"
which would require the following amounts of
By calculation. Actually found.
Ene ors sas 45°20 per cent. 45°16 per cent.
Magnesia. --- ---- oo 8°17
Pheaphicks baa 51°57 51°67
100-00 | 100-00
: Ca,P,0
* Expressed according to atomic system Mg,P,0, +44 Cro ;
Chemistry and Physics. 51
The mineral therefore is (essentially) s protvar ortho-
pyrophosphate of lime with pyrophosphate of magnes
absence of water naturally suggests that its popoatiits must
have — in contact with some igneous formation. The p
SCIENTIFIC INTELLIGENCE.
I. CHEMISTRY AND PHysIcs.
1. On the Direct Combustion of Nitrogen.—K&mMERER has
described an interesting lecture e experiment to show the direct
union of the nitrogen and ox ygen of air. Ina cylinder or globe
about two liters capacity filled with air, a piece of burning
magnesium ribbon about thirty to forty centimeters long, is
laced. When the combustion of the magnesium is ended, a
intense odor of nitrogen tetroxide is sancti and when the soe
nesium oxide has deposited, the characteristic color of this gas
: oO
color when starch tion | is added.— Ber. Berl. Chem. Ges., x,
1684, lear 1877. “2. B,
2. the Relative — of Oxygen for Hydrogen and
Oardonous oxide.—Bun n his “ Gasometric Methods,” has
e
hydrogen and carbonous oxide are mixed with oxygen in quantity
insufficient to burn them both completely, and exploded; from
which he draws the ons that the atomic ratio of the com-
ee products (H,O:CO,) is always oe by simple
changing from one to the other per saltum as the
portion of hydrogen varies. Horstmann has experimented anew
in this direction and has obtained quite different results. ©
finds: 1st. That when electrolytic gas and carbonous oxide are
carbon
ing ratio. Thus while the hydrogen, relatively to the carbonous
oxide, varied from 0°25:1 to 2°33:1, from 20 to 70 per cent of
the mixture being burned, the ratio.of the combustion- products
(H,0: CO,) varied from 0°8:1 to 45:1. Nothing like a sudden
change of ratio was anywhere observed. 2d. That when to a
mixture of carbonous oxide and hydrogen, increasing quantities
52. = Scientific Intelligence.
of oxygen are added and the whole exploded, as in E. v. Meyer’ 8
method, ‘aqueous vapor and carbon dioxide are formed in a con-
oxygen between-these two combustible gases does not take place
according to the law laid down by Bunsen. As to the cause of
the discrepancy, he says that’ | while his experiments were made
with dry gases in dry tubes, he has observed that see aqueous
vapor is hag in the tube, less hydrogen n and more carbonous
oxide is burned. e ratio of H,O: CO, is always Teena and
the more, ‘the reater the amount of moisture present. On the
other hand, in presence of carbon dioxide, more hydrogen and less
earbonous oxide is burned. Now v. Meyer's experiments were
with moist gases. Moreover, the variation in the ratio of the com-
es is peculiar. As the oxygen increases, this ratio
at ncreases, reaches a maximum, when the amount of com-
bustible gases burned is about 30 to 35 per cent, and then falls
uniformly — to the limiting value reached when the coma late
bonous oxide in the unburned residue. Since therefore relatively
more lane. is always b Ae than carbonous oxide, the attrac-
tion of o eater oe ‘she former than for ~ _— ges
Chemistry and Physics. 53
various special devices, such as pouring a solution of platinic
chloride into a sulphide, drop by drop, or in fusing platinic sul-
ammonium, thus resembling copper; 5th, t platinous sulphide
y be considered soluble or insoluble according to hysical
state and the nature of the sulphide used us salts occur
G. F. B.
4. On the Destructive Distillation of Phenol and Chlorbenzene.
amined th d
ceived were fractionated and yielded benzene, toluene, xylene,
naphthalene, anthracene, and phenanthrene. Chlorbenzene thus
treated gave diphenyl, parachlordiphenyl, paradichlordiphenyl
and an isomer of it, and diphenylbenzene.—Liebig’s Annalen,
elxxxix, 129, 135, October, 1877. . F. B,
. Boracic Acid.—In the Annales de Chemie et de Physique,
he calls the normal sea water, and he opens his paper with the
following broad generalization: ‘Toutes les substances, salines
existant en amas et en couches dans les terrains s¢dimentaires ont
fait primitivement partie d’une mer normale. D’un autre cote, a
In order to establish this conclusion in the case of the borates he
gives in the first place experimental evidence that the water of
the Mediterranean contains at least two decigrams of boracic acid
in each cubic meter, and, further, that on evaporating the brine
racic acid accumulates in the bittern until after the deposition
of carnallite. In the second place, he insists that in the very
characteristic deposits of Stassfurt the borates are found above
e carnallite as we should expect, if these deposits were formed
54 Scientific Intelligence.
as assumed, by the drying up of extensive salt lakes. Again,
aving confirmed the previous statements that the chief salt beds
of the world are found on two geological somal the Lias and
the middle Tertiary, he ah evidence t the aremma of
beds—heated ‘it is ek b vetosnts aie —determines well-
known chemical changes, from which result the peculiar acid va-
pors there discharged. But we can only give here the barest out-
boracic acid. rejects the test aco turmeric as menlarcirieyae
in the presence of such a mass of salts as are found in bittern, an
he finds the flame reaction by far the most sensitive as well as the
most trustworthy of all the tests with which he has ri er aang
When the Bunsen lamp is supplied with pure hydrogen,
that the flame reaction will indicate the one-millionth of a gram of
boracic acid. His method of applying the test is as follows: The
material to be tested is first m with an excess of oil of vitriol,
and this ea held in a loop of mpbichnrit wire is brought near—
hin four millimeters—but never nearer than two millimeters
to the visible mantle of the hydrogen se? so that the flame may
not be colored in the least by sodium always present. If the
assay contains boracic acid, th states green coloration
appears, which can be identified with absolute certainty, by means
of a spectroscope, and the coloration can be most delicately ob-
served by looking through the mantle of the dame oo
P
6. Photo-electric Phenomena.—R. BornsTEIN enktiib es veins 8 ex-
periments on the influence of light on the electrical tension in
metals, and shows that the effect is not a thermo-electric one.
The -Photo-electric series of the metals runs in this order :—Alu-
minium, gold, copper, platinum, silver. While the thermo-electric
series is as follows :—Silver, platinum, copper, gold, aluminium.
His conclusions are as follows
(1.) In a hee oma of 1 two different metals, a photo-
electric current merated whenever the two junctions are ex-
posed to arileeton jeaiacioms of different nro tee
(2.) When the same junction is exposed in one case to an in-
temperature, and in sauces to a more javeane illumina-
Geology and Mineralogy. 55
tion, the thermo-electric and photo-electric currents Teepeckirely
generated i in these cases are opposed to each other in direction.
Phil. Mag., Nov., 1877, p. 330. J. T.
NKEL concludes from a series of experiments upon the
photo-electricity of varieties of fluor-spar, that the pes ao phe-
nomena are largely due to the influence of the chemical rays of
the spectrum, which cause chemical changes in the eoqatinee ae of
the crystal. —Ann. der Physik und Chemie, No. 9, 1877, p. 66.
a eae soe of air at constant pressure and constant vol-
—li. K R has erence the specific heat of air at con-
by
the transverse aes of steel nae excited by a wichopalia
bow. A
were compared with those of a tuning fork. H. Kayser conelndss
from his experiments that the true value of the velocity of sou
in free air is 332-5 m. The value of &, the specific heat, has been
— assigned as will be seen from the following table:
Maso 220 ete 2A ew Cand Biss 25S ee. 1°41
Weisbach Se Fay ees 74005 ~Rontpér i222 2S its 1°405
H, Kayser concludes ee the true value is k=1°4106. rah
alnn., No. 10, 1877, p. 218.
worescence of the Retina.—M. von Bezold and Dr. hn
Mag., Nov., 1877, p. 397; Trans. from Berichte d. baier. bane
Math h. Phys., June, July 7, 1877.
Il GroLoGgy aND MINERALOGY.
1. Reports of the United States dtl 8a Surveys west of
the ‘One-hundredth meridian, in charge of First Lieutenant Guo.
Wueerer, Corps of Engineers U. 8. Army, under the diree-
tion of Brig. -Gen. A. A. Humpar nys, Chief of Engineers, U. S.
Vol. LV. Paleontology; quarto with 83 plates. Washing-
ton, 1877, Engineer department, U. S. Army.—This large vol-
ume, a contribution to the science of the country from the
Wheeler expedition, Bane ae War Department, comprises two
important memoirs, as foll
(1.) Report =e the Invertebrate Fossils collected in portions of
Nevada, Utah, Colorado, New Mexico and Arizona, by pa rties of
the Expeditions ‘of 1871, 1872, 1873 and 1874; by € Cuar.es A.
Warre, M.D.: comprising general observations upon the collec-
tions and the periods they represent; a general view of the classi-
fication adopted; and descriptions, in successive chapters, of the
56 Scientific Intelligence.
fossils of the Primordial, Canadian, Trenton, Subcarboniferous,
Carboniferous, Jurassic, — ous and Tertiary Periods ; and
illustrated by twenty-one plate
(2.) Report upon the extinct Vortebreta obtained in New ora’
by parties of the Expedition of 1874; f,
AED fossils of the Mesozoic periods, and geology of Meso-
oic and Tertiary beds; (2) fossils of the Eocene; (3) fonetls of
the Loup Fork group; and illustrated by sixty-two plates
rof. White’s valuable re ods has already been psielly “noticed
in vol. xii of this Journal (18
Prof. Cope’s report ren descriptions of a large number of
vertebrate fossils, including species of fishes, ge Pq and
mammals. Some ‘of t e general saute arrived at w regard to
the species of the Eocene of New Mexico are pres ones in vol.
xii of this Journal, asre, p- 297). The Loup Fork (or Loup
River) group, a s Dr. Cope observes, has now been identified at
three widely eratietie" localities: by "Dr. Hayden in the Upper
Missouri region, and by Dr. Cope in Colorado, and in New
its the Santa Fé a first studied by Dr. Hayden, bein ng
f this horizon. The group underlies the “ White River group”
in the Missouri region, and has been regarded as Pliocene. Dr.
Cope has described thirty-four species of Vertebrates from these
those of the White River beds, they appear to be somewhat older
in oe geological relations than —_ and hence, he has sug-
ed (first in 1875) that they may be Upper Miocene, Th
= favoring this supposition are stated to be Amphieyon,
elaepe Hippotherium, Aceratherium (Aphelops), 2 Mastodon
of M. angustidens, Pseudelurus, Steneo The
tice "Fy the White River and Loup Fork — differ, widely
in genera from those of the Eocene. The 6 2 lithographic plates
of fossils illustrating Prof, Font s Memoir are crowded with good
gures. Nineteen of them are occupied with figures of parts o
skeletons of different species of oe (Bathmodon of Cope
1872-1875) named by Dr. Cope, CU. cuspidatus, C. lobatus, ©.
et C. radians, C. latidens, C. elepha ntopus, C. molestus,
C. simus. Prof. Cope discusses several controverted points,
Shak we leave without no
2. Summary of field pee ve the United States Geological
and Geographical Survey of the Territories, under the charge of
Dr. AYDEN, for the season of 1877.—The work of the
United States Geological and Geographical Survey of the Terri-
tories in charge of Dr. F, V. Hayden has been prosecuted with
— success during the past year. The surveys in Uolorado
g been completed psn the previous year, the parties
png Ae: their work ina belt of country lying mainly in the
western half of Wyoming, but also embracing piissead pact
of Utah ae Idaho; all lying immediately north of the region
embraced in the e Survey of the 40th Parallel by Clarence King.
The parties “all took the field on the first of June.
Geology and Mineralogy. 57
The primary-triangulation party, upon the work of which that
of all the topographical parties is based, was, as usual, in charge
of Mr. A. D. Wilson, Chief Topographer. He took the field at
The area embraces about 28,000 square miles, and within it twenty-
tant. From these, connections were made at six points with the
triangulation of the Survey of the 40th parallel.
In addition there were three other fully equipped divisions for
topographical and geological work, and another under the direc-
tion of Dr. C. A. White, for special geological and paleontological
work.
The party first surveyed that portion of the district which is
ohn y j i )
sedimentary origin. A comparatively small space is occupied by
strata of Silurian age; the others range from Carboniferous to
beds of the Green River and Bridger groups, probably of Eocene
age. Coal was found to exist in large quantity on Upper Bear
River and its tributaries, and also on some of the branches of
Green River, being especially abundant between Twin Creek and
Ham’s Fork. In the Malade valley, Dr. Peale observed deposits
that are of later age than the Bridger group, but still, probably of
Tertiary age, : :
The Sweetwater division in charge of Mr. G. B. Chittenden,
* A map showin ri trian ions of this survey has quite recently
been published. $e te
58 Scientific Intelligence.
with Dr. F. M. Endlich as geologist, covers rectangle No. 57, which
is bounded by meridians 107° and 109° 30’, and parallels 41° 45’
d 43°, embracing about 10,800 square miles. The k
the field at Salt Wells station, on the Union Pacific Railroad, and
been of late Tertiary outflow, and quite extensive, the region is
occupied by sedimentary or stratified rocks; which he refers to
Lower Silurian, Carboniferous, J ura-T'riassic, Cretaceous and Ter-
tiary ages. Th
all parts of the district. Besides these, he mentions other deposits
in the valley of Snake River, later than the Tertiary strata just
referred to, but still probably of Tertiary origin. It seems
y
eale, may prove to be of the same age as the Lake Beds of Dr.
Hayden in Middle Park, the Uinta Group of Mr. King, &e.
Geology and Mineralogy. 59
. A. W
paleontologist of this survey, and he took the field at the begin-
ning of the past season, continuing his labors until its close. He
has pursued his researches with such success as to demonstrate
the necessity of continuing this class of investigations by various
lines of travel across what is generally known as the great Rocky
Mountain region, especially those portions of it that have been
surveyed, as well as those in which the surveys are now in pro-
Rivers; thence, crossing Green River, he pushed his investiga-
tions westward along the southern base of the Uinta chain, as far
as Great Salt Lake. Thence recrossing the Wasatch Mountains,
he carried his work eastward across the Green River basin.
continuous within what is now that part of the continent, from
the earliest to the latest of the epochs just named. uring the
progress of the field work, large and very important collections
of fossils were made, which are now being investigated. :
Messrs. S. H. Scudder of Cambridge and F. C. Bowditch of
ton spent two months in Colorado, Wyoming and Utah, in
making collections and observations in fossil and recent entomol-
ogy, with very gratifying results. Mr. Scudder is making arrange-
ments to add materially to his labors in this department, in connee-
tion with the survey. :
Professor Joseph Leidy spent some time during the season in
Green River Basin, making observations and collections for his
large work on Rhizopoda, which is to form one of the quarto
volumes of the survey. :
e botany of the survey was represented during the past sea-
son by the two great masters, Sir Joseph D. Hooker, Director of
the celebrated gardens at Kew, England, and Professor Asa Gray
60 Scientific Intelligence.
partment, was directed to visit and report upon those ruins, in
connection with his usual work; which he did, and the results
h l
en up, and added to his department, the work of repro-
ducing these models as well as those of ancient pottery found
with them. In furtherance of this work he visit Nort ern
, the dwell-
ings of the forgotten people; forgotten, because the builders of
; et i
:
Geology and Mineralogy. 61
But in February,
1876, it again passed into the hands of able geologists through
the substitution of Prof. T. C. Chamberlain, of Beloit College,
and under this arrangement, the new volume, above announced,
to order. Dr, Lapham was displaced, unreasonably, in 1875,
Dr. O. W. White.
ney being vol. I) contains Dr. ham’s annual reports for 1873,
1874, and Dr. White’s for 1875 as introductory to the reports of
IL On the Geology of Western Wisconsin, by Prof. Roland D.
ages.
Ill. On the Geology and Topography of the lead region, by
es
ese R
with ability and care, and with a full appreciation of what both
science and the econ
8
are the subjects of valuable ee and then the distribution
and characteristics of the severa
are stated ; ts
“Stand” Rock, of Potsdam Sandstone, which is almost as remark-
able as anything of the kind in Rocky Mountain scenery. The
post
usual interest. The third report, on the lead region, is, as its
author states, much briefer than the subject demands. It serves
62 Scientific Intelligence.
to supplement and extend the account by Prof. Whitney, adding
the results afforded by the more recent mining operations and a
further study of the regions.
e Atlas consists of a series of colored plates, illustrating in
sections the geology of the State; and others for eastern Wi
think, for the small amount of detail in the geology.
e cite from the volume the following facts and conclusions
relating to the Wisconsin drift.
In the first place the facts with regard to the driftless region,
which covers Southwestern Wisconsin and the borders of Minne-
st ‘
and Iowa adjoining, described a d rof. J. D.
Whitney, are brought out with additional observations; and th
view of Dr, Percival, its first describer, an f. itney is sus-
southeast town of Minnesota—that of Houston. The former
absence of the ice is proved by the absence of gravel and stones,
which suddenly cease on entering the region, and, as Prof. Irvin
states, by the character of the hills and ravines and the existence
over it of numerous fragile sandstone peaks. The origin of this
2
? .
latter brings out, in his report, a new theory in explanation of it.
According to the observations of Prof. Irving, in connection
h
h
west (3) along a Keweenaw Bay depression, west of southwest
: depression, as a ;
reached to Illinois. While those of the Keweenaw Bay depres
sion and Western Lake Superior continued westward and south-
Geology and Mineralogy. 63
ward over Minnesota, and thence, as N. H. Winchell has shown,
south to Iowa, where it was connected with the ice over northern
Tilinois.
The independence of the glacier-mass of the Michigan Bay de-
— and that of the long Green Bay valley is well proved by
of.
of ponds and pools over its surface. It is one to ten miles wide,
west outlines of the Green Bay valley glacier. It consists of gravel,
bowlders, sand and clay, unstratified, but with portions here and
h
glacial scratches made by the Michigan and Green Bay ice-
c
Bay side and a southeast on that of the Green River Valley, thus
pointing to the range as a moraine ridge between the two ice-
masses or along their blending borders. Again, on the west side
of the Green Bay Valley the glacial scratches run southwest-
ward (while southeastward on the east side) and terminate in the
edly have an undermining action and may have produced part of
the depressions, Over the regions of Wisconsin between the Green
gion was left iceless and driftless. He states that the surface is
not higher than that of Wisconsin to the east, and is lower than that
of Minnesota to the west; and hence that no argument can be
rawn in favor of its escape from the ice by its altitude or by an
elevation of the land. The explanation, though different, is closely
64 Scientific Intelligence.
related to that given by Professor N. H. Winchell, in his Minne-
sota Geological Report for 1876, (published in 187 7)* and that the
hills of the granitic =. stretching sacar aie from
Keweenaw Point, and from the south shore of Lake Superior
farther west, prevented the Spasaasie of shes great glacier from
Lake Superior i in that dire
Both Professor Chamberlain and Professor Irving state that
there is abundant evidence that during the Glacial era the continent
in that part was higher above the sea-level than now; and that
this elevation was followed by a depression below the present | level
—that of the Champlain period. The former states that “some
of the streams have cut channels from one to three RE feet
deeper than those they now rola DASE oy pointing to the fact of
greater elevation during the Glacial e
The chapters on the drift contain numerous facts with regard
ba the sources of the — proving ee coe for 100 to 300
The observations on the Champlain deposits and terraces are also
highly interesting.
wo other facts we cite here. The Milwaukee brick have
a cream-white color and this has been attributed to the absence
of iron. But Professor Chamberlain states that the clay is red,
and contains, according to analyses of the brick, nearly jive per
cent of oxide of iron; and that the absence of color must be due
to the formation of a silicate of lime and iron, lime being also
present in the ¢ [The eee. is probably a variety of epee,
the formation of Which 3 in the Triassic red sandstone of the Con
necticut valley where it adjoins "Ses dikes has often been oleckvad
the writer to be connected with a discharge of the red color
of the sandstone.
The Niagara fimestone of southern Wisconsin includes two
distinct varieties of limestone which were of simultaneous origin;
and, according to Professor _ Chamberlain, sa "oe ah kind
ral reef seas,
and the granular to the beach sand-rock, sik is ations
made along the shores of the coral reef regions out of — sands.
. D. De
Jo
+ Mr. A. H. Wo rthen states, in the first volume of hie palace rhe , of
i pean to
oelow Galena within the driftless area but not far north of its southern limits) he
observ: . Beebe informed
in Lucas county, near the middle of southern Iowa, which weighed more than
beg pounds. Galena is about 350 miles ina straight line south southwest from
sl an era w copper region, and Lucas county is 170 miles southwest-by-west
arom Cralens, or about 465 miles southwest-by-south from the Keweenaw region.
prRreneyy
a
di
lise
ae
ee
&,
Geology and Mineralogy. 65
4, Probabie pion — of the Great Salt Lake,—It is be-
lieved that the explorations of the survey under the direction of
r. Hayden, the past satan have determined the probable an-
cient outlet of the great lake that once filled the Salt ‘ake Basin.
t the head of Marsh Creek, which occupies the valley, continu-
ing directly south from that of the lowest Portneuf, is the lowest
pass between the Great Basin and the drainage of the Columbia.
In fact so low and flat is it, that a marsh directly connects the
two streams, one flowing to the Bear River and the other to the
Portneuf and Snake Rivers.
This fact was observed by the Survey in 1871 and 1872, but
this district has been carefully examined the past season by Mr.
oe and Dr.
Siberian Steppes. —Professor John Milne, in a paper enti-
tled “Across Europe and Asia, Part V, from Ekaterinburg to
Tomsk” (Geol. Mag., ages ree ar suggests that the material of ~~
ted b
great — of Siberia y the rivers while t
were r floods paused oy Abi being dammed about hae
shouths 3 in eekaeaaides of the ice of the stream not having there
melted. He shows that although ae — of — of the wa-
ters in autumn differs but a week o in the more northern and
asiot heat parts of the rivers, the Gies of saclline i in the spring often
Iife nth Consequently the ice toward the mouth of the
their norther were
neath the sea—more or less constantly coin alah a lake of tur-
bid water.” Floods ra this source occur now in Siberia. This
One, plain accompanies it; and as it expands in flowin
northward, so with the plai The widening “ se plains con-
= until they unite to — that ge aa which
a Mikroskopiache Piysiographie de pases Gesteine, von
Rosenpuscu. 6 pp. 8vo. Stuttgart, 1877. (E. Schweiger-
~ sche Verlagshandlng. apna presen t work forms ane operly a
Am. Jour. S8cl.—Tuirp Serres, Vou. XV, No. Se
5
Nat emes | Tea Sacie aaies ae
66 Scientific Intelligence.
method of classification adopted is as follows:—(i) orthoclase
rocks ; (2) orthoclase-nepheline, and orthoclase-leucite rocks; (3)
plagioclase rocks; (4) plagioclase-nepheline, and plagioclase-leu-
cite rocks; (5) nepheline rocks; (6) leucite rocks; (7) olivine, or
chrysolite rocks. The special system of ercesiaarn ot thes se
ular, syenites, or (2) Abe porphyries ‘with no ‘iit
Secondly, the younger rocks (I) ie a * sore. and are (1) gran-
ular or porphyritic, liparites, or (2) glussy, obsidian, trachytic
pitchstone, perlite, eooreeds or Ries are (II) without quartz, includ-
“— the trachytes and e glassy rocks
The description of the i individual rocks are very a ieee espe-
cially the references to their microscopic character. valuable
portion of the work is the list of books and memoirs on nef aeraan
cal subjects covering about thirty pages. E. 8. D.
7. A Guide to
oe of Rocks, being an intro-
duction to Litholo ee by E. Janyeraz. Translated from the
French by G. W. Pl mpton, C.E., A.M. 165 pp. 8vo. New
see 1877. (D. Van Nostrand.)—This little book has some very
escribed as due to the ‘ ria eay of fragments of the rock
in which wos — found,” (p. 36); pyrites (FeS,) j is said to be
reduc o FeS (p 109) ete. Besides, such words as
Cordveritfels, Cavite, lopfstein, Gallinace, ete., do not belong
to the English language.
8. Zubles for the Determination of Minerals. Based upon the
tables of Weisbach; enlarged, and furnished with a set of mineral
formulas, a column o: of 8 specitic gravities and some of the character-
istic blowpipe reactions; by Persiror Frazer, Jr., A.M. 119 pp.
8vo, Philadelphia, 1878. _(- B. Lippincott ’& Co ne —The first
‘eine ix of this J urnal. e revised wor ides numerous cor- _
rections and minor sadieign ns, contains s some new fe. atures, as for
instance, the indication of the comparative rarity of the less
aes species
_ 9. Tridymite in Ireland.—Prof. A. von Lasaulx reports the dis-
covery, of tridymite in the trachyte-porphyry of onl Antrim,
10. Anihracite of Pennsylvania.—Mr, E. T, Hardman, in a
n the Journal of the Royal Geological Society of Ireland
= 200, 1876), attributes the change to anthracite in eatin
series of trap-dikes to the eastward—not tec
ae at that these upriibes are Triassic or Jurassic in yin pe
the nearest over fifteen miles distant from the coal.
Botany and Zoology. 67
III. Borany anp Zooroey.
1. C, Darwin. The Different Forms of Flowers on Plants of the
same Species. (London, Murray ; New York, D. Appleton & Co.
1877.) 12mo, 352 pp.—Circumstances have prevented an earlier
notice of this volume, Mr, Darwin’s last work upon the fertilization
ting qualifications. He a 8, moreover, succinct notices of what
as been done by others in the same field.
Six of the chapters relate to dimorphous blossoms, such as those
of Primrose and Houstonia, including also the trimorphic cases, as
of Lythrum Salicaria and some species of Oxalis. The seventh
chapter discusses Pol gamous, Dicecious Diccious
ygam: , and Gyno-
Plants; the eighth and closing chapter is devoted to Cleisto-
Flow
sexual organs themselves (calyx, corolla, ete., being alike in the
two sorts),—Mr. Darwin adopts Hildebrand’s term of heterustyled.
rm, a Oo
and pistils, not in the floral enve opes, and avoids the erroneous
implication of the term heterostyled, that the style is only or mainly
‘ ;
gonous. We were too late to ensure its adoption in this work. A
fairly good term once in use ought not to be exc anged for a new
one without very sufficient reason ; and for the present purpose the
this
botany as a part of the character, of the genera or species which
we shall write Flores hermaphroditi, Didi moncecet, dicecei,
Jyno-dicecei, polygami, as the case may be. ;
One good set of terms for phytography we owe to Mr. Darwin
-
ne g
and the present book, i. e., that of gyno-dicecious and gyno-monc-
68 Scientific Intelligence.
cious, for the case of those plants which produce their two kinds
of blossoms as hermaphrodites and females, either on distinct indi-
viduals or on the same plant. ‘So, likewise, the term andro-mone-
cious and andro-diecious for the case of hermaphrodite and male
flowers, on the same or on separate individuals. As to andro-dice-
ism, Mr. Darwin ‘remarks that, after making enquiries from sev-
eral ‘bouaAintie I can hear of no such cases. The last summer
brought one such case to light in our Cambridge Botanic Garden,
perhaps exceptionally, but it raises the inquiry whether Diospyrus
Virgiiana, our Persimmon tree, may not be of this character. A
solitary female tree here, and wi ith no male tree in the town, sets
fruit more or pith n most seasons ; ; but the persimmons are under
sized and seedless. This year it was loaded with full-sized fruit;
well furnished with seeds, the latter with a good embryo.: The
female gp always bear stamens; but these are generally
thought to be impotent; perhaps they besten produce some
pollen ; they doubtless did so upon this oc
.
Darwin asserts, it would be Prenat and conduce to
ric i
and
females co-exist. This ur in two ways, and possibly in
three. The English Ash, as he remarks, is tricecious, or has the
three kinds on as many individual trees ; while some Maples bear
all three on the same tre
If we rightly read a sheaiivit on p.10, it implies that proterandry
and en are known to occu r only i in “some few hermaphro-
dite plants.” But it can hardly mean that, cases of it being com-
mon and abvions s in many natural orders
The first chapter of this volume is dev oted to Primula and its
allies; the second, to hybrid Primulas, mainly to the Oxlip, which
is shown to bea spontaneous hybrid between the Cowslip eit: the
Prim A note is added on some wild hybrid Verbascums, spe-
cially tho those babtbeen Verbaseum Thapsus and V. Liyehoiteid which
cross with the greatest ficility, and produce a series of forms
which almost connect these two widely distinct species
lly
hybrids of the first generation almost wholly self-sterile.
ch cases as this and that of the Oxlip, which was
thought to prove that the ee and the Primrose were
varieties of one speci “ show, as Ir. Darwin remarks, “ that bot-
ben Gini particulart those of some s ax of
stonia, Mitchella, and other Rubia “The fourth chapter
discusses the t fl wers of the same ere ah stars
Botany and Zoology. 69
striking case was first brought to light. Our Vesa verticillata
is also referred to, the trimorphous species of Oxalis Aaaee eek, and
finally Pontederia, the only monocotyledonous genus now known
to be heterogone. e trimorphism in this genus was dacacie a
data, our common Pickerel-weed. by Mr. Leggett of New “York.
Chapter VI is a detailed discussion of experiments on the illegiti-
mate offspring of heterogone flowers; i. e., offspring produced by
breeding shea the danse ofthe same ‘form, short-sty ed with long-
' stamened, or th The conclusion is that in all points
e con
“the patallelison | is moudeetals close between the effects of illegit-
imate and hybrid fertilization. It is hardly an exaggeration to
assert that seedlings from an Fh ager aay cde fertilized —
of Lythrum or Primula for the sake of ascertaining whether the
were specifically distinct, and he found that they could be united
nly with some di culty, that their offspring were i’
whole series of tions crossed species and Lad Ae brid off
spring, he might maintain that his oe had b roved to
be good and true species ; but he w be co mpletely deceived.”
The cause of this sterility between gre iduals w may h
sprung from the very same parent or parents an from the
same = must evidently in their 1 e organs
reproductiv
n some recondite incompatibility of their sexual ele-
ments, ase in any general difference of structure or constitution.
And Mr. Darwin effectively argues that the same holds in ca
of distinct species of the same genus. “ We are indeed led to
this same conclusion,” he adds, “ the impossibility of detecting
any differences sufficient to account for certain species crossing
with the —— ease, whilst other state allied se cannot
be crossed, or can be crossed only with extreme di
are led to this. conclusion euigie more forcibly by causitienie the
great difference which often exists in the facility of crossing
reciprocally the same two § sea: or it is manifest in this case
ility of hybrids ceas es to be a criterion of specie
The 6th ee follows up the subject in a series of pee penis
remarks. It refers to those cases of more or less recip
rocal differences i in stamens and style which are una prt
any difference in size or form of pollen-grains; and it tabulates
the difference in pollen-grains of the two sorts. “ With all the
oe in which the grains differ in diameter, there is no excep-
to the rule, that those from the anehaee of the short-styled
*
70 Serentifie Intelligence.
form, the tubes of which have to penetrate the longer pistil of
the long-styled form, are larger than the grains from the other
form.” “This curious relation led Delpino (as it formerly did me)
to believe that the larger size of the grains is connected with the
greater supply of matter needed for the development of their
on ubes.” But it proved that, in many cases where the
pollens differ mach in size, the styles differ moderately in length
1
?
a ce versa, and that in plants generally, there is no close
relationship between size of pollen and length of style (the grains
ing of the same size in Datura arborea and in Buckwheat
while the style of the one is nine inches long and of the other
very short); yet still “it is difficult quite to give up the belief
that the pollen grains from the longer stamens of heterostyled
plants have become larger in order to allow of the development
i
and it would have been of little use to such plants to beco
heterostyled e can thus understand why it is that not a single
enera are mentioned which ‘have probably passe
on from the heterogone condition to the diwcious, Coprosma is
tendencies in the same direction. On the other han , Mr. Dar-
8 observations on Ewonymus Europeeus are “ very interesting,
h :
obvious tendency towards dicecism, the principal illustrations are
: : .
, ete,
The eighth and last — is devoted to Cleistogamic flowers.
nds of flowers are evidently arran
~
a n
howy blossoms, produce others which fertilize and fructify with-
Botany and Zoology. ; 71
of the ordinar y flowers self-fertilize without expanding or full
rine their development; but in others these comparatively .
nute and ever-closed flowers are profoundly modified paca
Narsityss in reference to — function. Dr. Kuhn, in 1867, gav
them the appropriate name of flores ea teh cleistogamic, or
as we prefer auepainoushe flow The literature of the subject
gathered
known of these blossoms is condensed. e cannot here attempt
a recapitulation. In brief, “ they are conastenida for their small
size and fi rer opening so that they resemble buds; their
e
petals are rudimentary or quite aborted; their stamens are often .
; F
educed in number, with the anthers of very small size, contain-
ing few pollen-grains, ee have remarkably thin transparent
coats, and which generally emit their tubes while still enclosed
within the anther-cells; and lastly the pistil is much reduced in
~~ with the stigma ‘in some cases hardly a . “es oo
quently insects do not visit them; nor if they “id aan see find
h flow
an entrance. Suc wers are therefore invariably self-fertilized ;
Indee :
insects ; in some, such as Orchids, they are dependent upon this
agency for such fertility as peat possess.
Cleistogamous flowers are known in about twenty-four natural
orders, yet not ina larg caabed of genera. The list given by
y
enlarged; but in one particular it may be diminished, for Auellia,
Dipteracanthus, and Cryphiacanthus are really all of one genus.
original pula — and irrespective of this var
rushes and grasses, ” Among the latter, it is singular that one of
the earliest: ee n and strongly marked cases, that of Ampht-
carpum (Milium amplicanpem Pursh), — be overlooked.
Since this notice was written, Mr. Pringle has announced to us
the serbia ’ a flowers re regularly ooeunriny within
the leaf-sheaths of Danthonia spicata a
and other on
72 : Scientific Intelligence.
which figures give for the study of Ferns. _ Books of this kind, of
various pretension and merit, abound in Great Britain, and there
is evidently a great demand for them. But our own fern-fanciers
are becoming numerous and active, and this work will aid them
and bring many more into the field. At least our botanists and
botanical students want it. And this work seems to us well plan-
ned to meet all these requisitions. Well executed it certainly is,
the
specimens of chromo-lithography. Plate II, representin etlan-
thes vestita and C. Coopere (a new species, detected in California °
by Mrs. Elwood Cooper, whose name it bears), is to o in
best ; and the synopsis of the species of the genus, arranged und
the sections, was a thought. The figure of A um ser
ratum, a tropical American Fern, recently discovered in Fl
r. Garber, is well managed and characteristic ; amp-
light the green is too blue. Under the same conditions the Ly-
godium, which is well chosen for a leader, seems too pale and dull.
A little more practice will set this all right. The prospectus in-
ter. We hope, and we do not doubt, that the sale will warrant
A. G
3. Notes on Botrychium simplex, by Grorcx E. Davenrort,
1877.—Here is more Fern-lore, an exhaustive mono
e frond. Two large quarto plates crowded with figures (48
in number), illustrate the forms which these two peci ein
this country, and the account of them fills 22 pages of letter-press
of th: i The result of this thorough treatment is to con-
the figures are heliotype reproductions of Mr. Emerton’s outline
drawings. It is stated that “if the publication of these notes shall
Botany and Zoology. 73
prove to be of any service to fern-students [which it surely will],
_ they will owe it entirely to the generosity of Mr. Robinson.’
4, Researches in regard to the influence of light and vadiaie
heat upon transpiration in plants, by J. Wimsnur ameerey .
Ann. d. Se. Nat., Sept., 1877, from ‘Sitzun ngsb. der k. Akad.
Wissensch., 1876, t. 74). Wiesner prefaces his memoir ae a ee
historical account, of which we here give an abstract. Near the
middle of the last century, Guettard demonstrated by rude ex-
periments that light favors transpiration. Unger, and, later,
Sachs have supposed that the movements of sto mata under the
quent excitation.
Wiesner, in the memoir now noticed, gives a detailed account
periments, and presents the following conclusions.
A part of the light, which has traversed chlorophyll is trans-
e
- feeble in the dark, although the stomata were
widely open. Also that th rk heat-rays are less active in
transpirat the luminous rays, and that the ultra-violet
rays have no influence at all; that, whatever may nature
of - rays, they act solely by elevating the ee of the
tiss
5. kes Botrydium granulatum ; by J. eeckeeninics and M.
Worontn.—This is an interesting paper which appeared in the
Botanische Zeitung of Oct. 12. The investigations were carried
on simultaneously by Rostafinski in Strassb and Woronin in
St. - fect the i peng which are beautifully done, being drawn
by Wor As is well known Botrydium granulatum is a unicel-
74 Scientific Intelligence.
lular Alga of a more or less pyriform shape, from whose smaller
end grows a branching root-like process by which the plant is
fastened in the moist ground. Small as it is, it is amply provided —
with reproductive bodies as will be seen by the following : ere
The contents of the pyriform portion may change into a lar,
number of zodspores each provided with a cilium. 2d. If the PER
becomes somewhat dry the pyriform portion shrivels, and the root
fibres ave up into a apretea: of cells which m sc be transfor med
which, after —* from the spore, unite in twos or some larger
number so as to form what Rostafineki would call an isospore or,
as is more cesenily expressed, a zygos
The cells of Botrydium sometimes bud out at the ere and the
budding processes, labs a time, send out hyaline _— and finally
separate from the mother cell, forming a new indivi - In this
connection, we would refer toa plant “which we Seals jena the
past summer at Eastport, Maine, and Gloucester, Mass., where it
was not rare on rocks and wharf at seid ring The species seems
to be identical with Celiolum gregurium A. Br., found by Brown
and afterwards by Pringsheim at icligeland, in company with
least C. gregarium, should be included in Botrydium. w.
6. Om gars aca marina Klorofyll firande Thalloph rte
By Dr. F. R. Kjellma
Ueber die — Vajetatio des Murmanschen Meeres. By Dr.
F. R. Kjellm
Bidrag til Shanealeial af Kariska hafvets Algvegetation. By
Kjellman.
Bed. hE:
The above named articles, which are extracted from the proceed-
ings of the Swedish Royal "Academy are important contributions
to our knowledge of arctic Algw. Dr. Kjellman as botanist of
coast, in striking contrast to that of Norway, that there is
an aiacet entire absence of littoral Fuci and ora, of all littoral
*
Botany and Zoology. | 75
species whatever. The most prolific region was in water about
ten fathoms deep. W. G. F.
7. Leleie Specie nei Gruppi affini raccolte a Borneo. By Vin-
cenzo Cesati. Prospetto delle Felei raccolte dal Signor O, Beccari
nella Polinesia. By Vincenzo Cesati, Napoli.—The former article
forms a pamphlet of forty-one pages, with four plates, in pea the
writer enumerates the higher er yptogam s of Borneo and describes
a number of new species. The latter aetials is much shorter and’
contains descriptions of about thirty new species and = es.
w.
. Notes on Botrychium simplex nner ; by GrorcE E Day
opel 1877. Salem, Mass. 4to, pp. tab. 2.- o. Bacrehiaa.
simplec i is a little Fern which was sch atari docnaag and figured
in this Journal in 1823 (vol. vi, p. 103), by President Hitchcock.
For many years it was very little known, and was confused with
several other species of the same genus. "Dr. Milde, in vol. xxvi,
of the Nova Acta Acad. Nat. Curiosorum, was the first to cle early
define it, to associate with it forms more ‘hi ighly developed than
the specimens known to hae Hitchcock, and to illustrate the
species with ny se its several forms and Speen fe cea
results of his studies upon other species. D. C. EATON.
that when collecting fossils he finds large numbers of Trilobites
on their back;* from this he argues that they died in their nat-
ural position, and that when living they probably swam on their
acks. He mentions, in support of his view, the well known fact
that position. I have for several summers kept young horse-shoe
erabs in my j and have noticed that besides thus often swim-
hon on their Reoke, they will remain in a similar position for
hours, perfectly quiet, on the bottom of the jars where mg are
kept. When disy cast their skin it invariably keeps the same
attitude on the bottom of the jar. It is not an uncommon thing
to find on beaches, where Limulus is common, hundreds of skins
thrown up and left dry by the tide, the greater part of which are
turned on their backs, ‘An additional point to be brought for-
Sea Lye. “Wat Hist., -xi, p. 155, dein: Twenty-eighth Report N. Y. State
Museum, Dec., 1876. :
0 aaa
76 Scientific Intelligence.
browsing, as it were, upon w what — find in their road, and
washing away what they do not need Bo means = a pow erful
current produced by their abdominal apy d
by the hor.
10. New Species of Cer atodus, from the Jurassic ; by O. C.
Marsu.—Among the interesting vertebrate remains recently found
in the Jurassic of Colorado is a tooth of a Ceratodus, in good
projections, which are separated by four notches. The front pro-
Jection is longest, and most pointed. The et is attached to a
portion of the dentary bone, as shown in the accompan ou
The length of this “dental plate i is 20
mm., and the transverse diameter 11 mm.
The species is the first Mesozoic Cerato-
dus found in this spied aud hence of
: much interest. It may be named Cerat-
Ceratodus Giintheri. odus Giintheri, in aun of Prof.
Natural size Giinther of the British Museum, The
eam usc of this species is in the Atlantosaurus beds of
ve
upper Jurassic.— Communicated by the Author.
' JV. Astronomy.
The phish Meteors.— At my request, Messrs. Benjamin
Vail and John P. Carr, students in the State University, kept
watch last night for the November meteors. The earl part of
the night was too cloudy for observations, but tefokS. ta o’clock
this morning (the 14th) the sky had become quite clear. In one
hour and fifty minutes—from 1.55 to 3.45—fifty-four meteors
were oe gia by the two observers. is was at the rate of
thirty per hour. Nearly all were Leonids—that is, the ee from
which they radiated was in the constellation Leo. <A few of the
number were as large as first magnitude ae and left trains
which continued luminous for several seconds. e appearance,
of so large a number ten or eleven years after the maximum dis-
plays of 1866 and 1867 is — bigs gus
Bloomington, November 14, 1 NIEL KIRKW
2. On Schmidt's Nib Conae —Mr. Cin baad. in a taki to
the Astronomische Nachrichten, Naty Lord Lindiay” *s Observatory
at Dunecht, dated September 5, : “On September 2, 1877,
ivi this star with the 1 siirich refractor of this observatory.
tint, especially when viewed in the same field with the reddish star
.+42° 4184 which it precedes by about 25% Viewed raed a
low power eye-piece and a powerful direct vision prism, held be-
tween the eye and the ee see ee light of the star was found to
be absolutely monochrom e prism Browning spectro-
scope with a slit, but wittiout a cylindrical gave a star-like
image without a trace of continuous s A few hurried
measures were all that esta be see hey indicated a wave-
eer) bic
Astronomy. 77
length of 512 mm.; but great uncertainty attaches to this deter-
mination as a slight derangement of the spectroscope prevented
the introduction of a comparison spectrum. On September 3,
very reliable result was ‘6 mm. single measure of min
gave 4961. It will be at once seen that the light of this remnants
nd
found 500°8 mm, and 493°5 as limiting wave-lengths between which
the whole width of the line must be enclosed. Bearing in min
the history of this star from the time of its discovery by Schmidt
it would seem certain that we have an instance before us in
which a star has changed into a owenets —— of small angu-
lar diameter. At least it may ely affirmed that no astrono-
mer discovering the object in its iochnat atene would, after view-
ing it through a prism, hesitate to pronounce as to its present neb-
ulous character. Judging from the brightness of the star in the
finders of 33 inch aperture it is probable that a refractor of 5
inches aperture a sufficient to show the monochromatic
aoe of its light when viewed through a small direct-vision
e "The Report of Professor Pickering, Director of the Harvard
College Observatory, to the Visitors, Nov. 26, 1877, has been pub-
lished. It has been decided to devote the large refractor to
photometric work and some results of general interest have been
r d g
¥
giving the cians to which the primary must be reduced to
render it no brighter than the satellite, or the diameter of the lat-
ter, if it reflected light in the same proportion as the planet. This
is, in fact, probably the only estimate we can ever make of the
true diameter of these bodies, An approximate reduction of the
. . co
from the holes, gives its equivalent diameter at about 5-9 =e
: his
ay
inner satellite give its diameter as 65 miles. The direct compari-
son of the two gives their relative diameters as in the ratio of
10 to 9. These figures will be somewhat altered in the final re-
duction. As the darker color of the outer satellite somewhat
diminishes its light, it is probably safe to call it about six miles
in diameter, and the inner satellite seven miles
This photometer has since been used upon various other objects.
A large number of measurements of seven of the rage ee of
object
Saturn have been obtained, including the very faint
78 Miscellaneous Intelligence.
ards will thus be established for the fainter stars, with which
observers hereafter can compare other minute objects. Several
asteroids ‘have been compared in like manner, and will give some
reliable data regarding the true diameters of these bodies.
V. MisceLLaNnrous ScrENTIFIC INTELLIGENCE.
e
with a bottom temperature of 28-4°, the lowest yet found by the
expedition.— Harper's Weekly, October 27, 1877.
ranslation of Weisbach’s Mechanics.—Professor DuBois
has translated that part of volume second, section second of
Weisbach’s Mechanics that treats of Hydraulics and Hydraulie
otoers. ‘Though complete in itself it is also intended as a con-
tinuation of Coxe’s translation of volume I, and it is to be soon
wed by a translation of that part of volume II that treats of
it, Steam and the Steam Engine. It is hoped that the transla-
-
Miscellaneous Inteliigence. 19
tion of volume III will soon follow. The part now issued forms a
es me of lviii arid 675 pages. It is published by J. Wiley
on
. A new Treatise on Steam Engineering, Physical age tt
of permanent Gases, and of different kinds of Vapor ; by Joun
ystrom, C.E. 185 pp. 8vo. New York, 1876. (
oe s Sons. )—This work contains many formulas and tables
relating to combustion, steam pressure and so on, which will be
useful to the practi tical engineer. The author makes a vigorous
attack upon many of the co mmonly accepted terms in mechanics, as
he has done in his eaumogen of Mechan cs. A lar e number )
taleeaebe
this memoir Mr. ie tds, ives over 400 titles of volumes or
memoirs relating to the Method of Least Squares, beginning with
aed rule, published in 1722, and ending with the year 1876.
The work is however not a mere list of titles. He has given
Sen upo d abstracts of all the more important papers
About one-fifth of the titles are quoted at second hand. These
inor importance. e
has been able to examine in the libraries of Yale College. The
su pgeme ey of this list with rent mee of papers is a contribu-
io hoe value to exact scie
. ts of the Method of. — Squares ; by ae
Miser 198 pp. 8vo. London, 1877. (Macmillan & Co.)—
Merriman treats the subject of Least Squares in two sections. are
the first he a the least amount of theory possible, the
*&
object being to give and explain the practical rules. In the second -
he detelave ae theor
6. Royal Society. —In their award of medals for the present
year, the Council of the Royal Society have taken a wide view,
for four of the five rea chosen for the honor are foreigners
Copley medal goes to Professor J. D. Dana, of New Haven, Conn.
for his biological, vestovaick sia mineralogical investigations, ei
ried on through half a century, and for the valuable works
which his ree spa have nea published. ~ F. el,
wald Heer, of “Zurich for his numerous researches aa ritings on
the Tertiary plants of Europe, of the North Atueiie North Asia,
and North America, and for his able generalizations respecting
their affinities and their geological and climatic relations. For
the first award of the e Davy Medal, aber Wilhelm Bunsen, of.
Heidelberg, and Gustay Robert Kirchoff, of Berlin, are select
i
_ The Sil
other weal
80 "Miscellaneous intelligence.
This is a good beginning with a medal which is, perhaps,
destined to become famous in the history of science. There will
be no question as regards the custody of the golden prize, for each
of the two learned professors will have a medal.— Athenceum.
ver Country or the Great Southwest. A review of the Mineral and
th, the attractions and material development of the former kingdom of
ew Spain, comprising Mexico and the Mexican Cessions to the United States in
1848, and 1853, by A. D. Anderson. 221 pp. 8vo. New York, 1877. (G. P.
Putnam’s Sons).
Journal of the American Electrical Society ; including original and selected
papers on Telegraphy and Electrical Science. Vol. i, No. 2, Chicago, 1877.
OBITUARY.
Jarep Rorrer Kirrianp, M.D., LL.D.—Dr. Kirtland died at
his residence in East Rockfort (near Cleveland), Ohio, December
10, 1877, at the advanced age of eighty-four years, having been
born in Wallingford, Connecticut, November 10th, 1793, In
ory.
Dr. Kirtland was a man of untiring industry, devoted to the
duties of an arduous practice in medicine, and tho P
fessor of the theory and practice of his art in more than one
stores of exact id varied knowledge afforded an unfailing source
of enjoyment. He retained his intellectual powers undimmed to
Journal in 1818, and his name has stood on its books to the close
of the last year, being, so far as appears, the last member of that
original number, reas
.
*
*
STORM OF MARCH 5-18, 1874.
50 30° 3 oy
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AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES]
Art. VIIL—On the Photometric comparison of Light of different
colors ; by Professor O. N, Roop, of Columbia College.
[Read before the National Academy of Sciences, Oct. 24th, 1877.]
THe comparison of the intensities of light of different colors
has long been considered one of the most difficult o
may not be without interest to those whose studies lie in this
direction. The luminosity of card-board painted with vermilion,
was, for example, measured as follows: a circular dise of the
vermilion card-board was attached to the axis of a rotation-
brightness till the observer again became doubtful, when a
directions, but remaining in ignorance of the results to the end.
82 R. Rathbun—Echinoid fauna of Brazil.
as 100. In this experiment and in all those that follow, proper
corrections were made for the amount of white light reflected
by the black disc, this having been previously ascertained, in a
manner which will be described in a future communication.
In order to test the correctness of the final result, oe lumin-
the vermilion, was next measured in the same way; it poral
26 ats
a0 black card-board, measured. The gray thus obtained had
a luminosity of 24°54, that of white card-board being 100.
Nexi, the value of this same gray was calculated from the
measured luminosities of the two colored discs, and the propor-
tions of these colors required to produce a pure gray by mix-
ture on the rotation apparatus; the calculated value was 25°47.
This agreement proves the correctness of the photometric
s assumption, that the Sota
poeta confirmation.
Corresponding measurements were made with a green, and
its complementary purpie disc; also with a blue, and its com-
plementary yellow disc; the results are given below.
Luminosity. Gray (observed.) Gray (calculated.)
MOEMINOD; .... = =. —- 23°38 } : ze
lue-green, -..----- 26°56 ( 24°54 25°47
Chrome yellow, ----80°3 :
Cobalt las, ale ee 5°38 t 54°51 53°92
Ga ere Seen ee 11
Purple, 14°83 t 24°94 26°56
Arr. 1X.—The Geological Commission of Brazil. eon to
the Echinoid fauna of Brazil; by RicHARD RaTuBu
THouGH the Geological sasig a a has busied itself in
investigating the marine fauna at almost every point on the
coas razil where its jnbote ave extended, yet in a group
like that of the Echinz, the different shore species of which are
- so readily found and collected by all travelers, it has been able
to add very little that is new. In its collections, however, are
three species which do not seem to have been recorded from
Brazil before. They are: Diadema setosum Gray, Hipponot
R. Rathbun— Echinoid fauna of Brazil. 83
but it was found in great abundance by Mr. J. C. Branner, on
the shores of the island of Fernando de Noronha, situated nearly
recorded by Mr. Agassiz, it was limited to the main shores and
islands of the seas between North and South America, and to
the Bermudas.
The third and last species mentioned, Me/lita sexforis, was
dredged from the shallow water inside of Fort Villegagnon, in
the harbor of Rio de Janeiro, by Professor E. Selenka, who has
kindly presented the Commission with several specimens. ey
are very numerous in this one locality, but, so far as we know,
have not been obtained from any other part of Brazil this
of the specimen from Cape Verde Isles, figured by Agassiz (op.
cit., pl. 1d), and varies much in the length and strength of the
Spines, which are usually more or less overgrown with calcare-
ous sea weeds. Though Fernando de Noronha is not 200 miles
distant from the main coast, yet there intervenes a great depth
Water, as ascertained by recent exploration ; the marine fauna
of the island, however, seems to be very similar to that of the
The following list probably contains all the littoral species
of Echini at present known from Brazil, all of which, with the
84 L. Trouvelot—Undulations in the tail of Coggia’s Comet.
exception of Strongylocentrotus Gaimardi A. Agassiz, have been
found by the Geological Commission. The localities at which
they were obtained are so nearly those recorded by Mr. Alex.
Agassiz in his Revision of this group, that it would be of no
value to enumerate them again here. ‘The species are as follows:
Cidaris tribuloides B1., Hipponoé esculenta A. Agassiz,
Arbacia pustulosa Gray, Clypeaster subdepressus L. Agassiz,
Diadema setosum Gray, HMellita testudinata Klein,
Echinometra subangularis Desml., Mellita sexforis A.
Agassiz,
Strongylocentrotus Gaimardi A. Agassiz, Encope emarginata L. Agassiz.
Toxopneustes variegatus A. Agassiz,
It has been noticed that Mellita testudinata is brilliantly phos-
phorescent at times, when it has been removed from the water
or a few hours, though it be still wet and apparently alive.
The phosphorence is very apparent over the entire body. I
indebted to Mr. Alex. Agassiz for kindly examining and veri-
fying the determinations of a collection of the above Hchint
sent to the United States, excepting Mellita sexforis, which has
been found only very recently.
Art. X.—Undulations observed in the tail of Coggia’s Comet,
1874; by L. TrRovuvetor.
On the evening of July 21, 1874, at 95 0™, the moon being
in her first quarter, and the sky remarkably clear even close to
the horizon, my attention was attracted by a bright ray of light
darting from the northwestern horizon, way up in the constel-
lations. Taking it for an auroral phenomenon, I went in for
the spectroscope ; but on my return, after a few seconds, to my
disappointment I found no more trace of it. Soon, however,
it reappeared, and darted up in an instant after the manner of
certain auroral rays, and vanished again after ten or fifteen
seconds. I then Scenis aware of my error, and found with
surprise that the phenomenon was taking place in the tail of
Joggia’s Comet, the head of which was then plunged under
the horizon.
During the whole time that I observed this interesting phe-
nomenon, I saw the comet’s tail shortening and extending,
lightning up and extinguishing like the rays of certain auroras.
Extended undulations, rapid vibrations, ran along it in succes-
sion from the horizon to its extremity, giving it the appearance
of a fine gauze wavering in a strong breeze. The. pulsations
and the waves of light were of unequal duration; some being
rapid, while others lasted a longer time. For over one hour
the comet's tail kindled and extinguished more than one hun-
dred times; the extinction being sometimes so complete that
L. Trouvelot—Sudden extinction of the Light, etc. 85
y Ursee Majoris
Be it coincidence-or not, at the moment that this phenomenon
was occurring, a strong magnetic perturbation was going on in
Cambridge, where the declination needle oscillated through an
angle of 1° 27’, although no auroral light was seen; and by
the kindness of Mr. Cleveland Abbe, of the Signal Corps, I
learn that no aurora was reported for that night.
It is not a new thing to see vibrations and pulsations ran-
ning along the tail of comets. Many observers have seen this
eeepothen hs among others Longomontanus, Vandelin, Snel-
ius and Father Cysat, who are reported to have seen undula-
tions taking place on the border of the Comet of 1618, as if it
was agitated by the wind. Hevelius observed analogous mo-
tions in the Comets of 1652 and 1661. Pingré asserted that he
distinctly saw in the long tail of the Comet of 1769, “des
ondulations semblables a celles que les aurores boréales pré-
sentent.”* According to Winnecke, from the 5th to the 12th
of October, 1858, the rays forming the superior part of Donati’s
comet spread and contracted suddenly like the rays of the
aurora,
Cambridge, Jan. 5, 1877.
Art. XI.— Sudden extinction of the light of a Solar Protuberauce ;
by L. TROUVELOT.
_ ON the 26th of June, 1874, while making my daily observa-
tions of the sun with the spectroscope at the Harvard College
Observatory, Il saw an unusual phenomenon, which may be
worth recording. The narrow slit of the instrument was di-
rected on the preceding side, about 270°, just above a group of
Spots which was then very near the limb, when I saw a ril-
hant protuberance partly projected on the spectrum, on the side
of the rays of less refrangi bility. In shape, this hydrogen flame
resembled an elongated comma, having its acute extremity
directed toward the sun, where it terminated just a little above
the chromosphere. The chromosphere under this protuberance
formed several slender and acute aigrette-shaped flames, none
of which, however, reached it. The large prominence, which
was slightly inclined to the limb, had a height of 3’ 37”, and
about 3° in its greatest width.
* Arago, Astro. pop., vol. ii, p. 439, Paris, 1855.
86 L. Trouvelot—Sudden extinction of the
When the slit was set wide open, so as to allow the whole
protuberance to be seen between its jaws, the comma-shaped
flame appeared perfect, and showed plainly its texture. But
when it was observed with a narrower slit it became partly
invisible on the C line; only a short and jagged portion being
seen in it on the red side. When the slit was carried along the
protuberance by means of its screw, the portion visible on the
C line did not remain constant, but either extended or con-
tracted of a small quantity; the maximum portion visible on
the C line never being more than one-fourth the width of the
slit, while sometimes it was not seen at all on this line.
The portion of the protuberance projected on the spectrum
was considerably more brilliant than the spectrum itself, and
about one-third only of its whole iength was visible. As the
slit was carried along it, the visible parts became invisible near
the C line, and invisible parts appeared on the spectrum; and
the area of the visible portion either contracted or extended,
when seen in different parts.
no motion of any kind, no extension, no contraction, could be
perceived before or at the moment this phenomenon took place,
and as the light did not go out of it gradually, but as suddenly
as a flash of lightning, it does not seem that a change of posi-
tion was the cause of its disappearance, but rather because the
light which rendered it visible abandoned it in an instant.
According to theory, this protuberance was moving rapidly
away from the earth at the moment of the observation, as it
was projected upon the less refrangible side of the spectrum ;
yet this would fail to explain its sudden disappearance, since
for this it should have moved out of sight with an unconceiv-
able velocity.
For over half an hour I watched attentively the same spot in
Light of a Solar Protuberance. 87
cannot be conceived as being due to the reflection of light, as
in the case of the clouds in our atmosphere: it is the protuber-
ance itself which is rendered luminous by some change taking
place in it. These observations would seem to indicate that on
the sun there are sometimes dark and non-luminous protuber-
ances, which may cause the spots of absorption often observed
in the vicinity of spots.
The phenomenon of the gradual illumination of a protuber-
ance was observed in 1869, at Des Moines, Iowa, during the
total eclipse of the sun, by Professor William A. Rogers, who
accompanied Dr. C. H. F. Peters, on the Litchfield Eclipse Ex.
ition. Professor Rogers was observing a large protuber-
ance on the sun with a 9-inch-aperture refractor, when he saw
several protuberances form gradually in the vicinity of the
large flame, and at a considerable height above the chromo-
e
ere.
The projection of the hydrogen flames on the spectrum is
not a very rare phenomenon during the period of maximum of
sun-spots, and it has been observed several times. However,
ei
On Sept. 10th, 1872, at 125 33™, I was anaes smal] nar-
row flame forming an arch on the chromosphere, the height of
n
Jike a rope. For a few seconds, it continued to ascend, at the
same time growing wider; and at 12" 37™, it had attained its
sunk to a level with the chromosphere and was lost in it.
_ At the same instant that the are of hydrogen was distended,
it was seen rojected on the spectrum opposite the sun, to-
wards the violet. The figure of this protuberance appea
exactly the same, whether it was projected on the spectrum or
Seen between the wide-open jaws of the slit. However, when
the slit was narrow, the flame became invisible on the C line,
although it remained projected on the spectrum. When the
protuberance, after having reached its greatest altitude, de-
88 L. Trouvelot—Moon's Zodiacal Light.
this did not seem to affect the position of the flame on the spec-
trum.
Cambridge, January 12, 1877.
_ Art. XIL—The Moon's Zodiacal Light ; by L. Trouvenor.
Durine the evening of April 3, 1874, the “ Zodiacal Light’
was particularly brilliant; especially close to the horizon, where
it appeared as a segment of a circle, having an irregular wavy
outline, giving it a vague resemblance to the beams of a faint
aurora. Although the sky was clear, it was found impossible
to observe with the telescope on that night, on account of the
great disturbance of the atmosphere. At 9» 45™, the declina-
tion needle indicated a very strong magnetic perturbation in
Cambridge, oscillating through an angle of 3° 22’. However,
no aurora was visible at this time, although the phenomena
usually attending them were manifested during the evening by
the tremulous appearance of the telescopic images.
ile going home, I remarked in the east a strange conical
light rising obliquely from the top of the roof of a building,
behind which the moon, then about 15° or 20° above the
utes, when it gradually faded away until it almost totally dis-
appea ve minutes later, although the sky was clear. A
quarter of an hour after, the sky was overcast with dense
yapors, which continued for nearly an hour. ©
- At 11 Om the sky had cleared up, and the moon shone
brightly. The luminous appendage was still visible, and even
appeared more brilliant than before. In order to ascertain
C. Marignac—Chemical Equivalents and Atomic Weights. 89
e tim
totally invisible, although the sky remained clear. i
The fact that the zodiacal light had been unusually brilliant
and the aurora. The result of my observations of the zodiacal
light and the aurora during the last seven years also seems to
indicate some such connection, as when the zodiacal light was
observed to be particularly bright, it has generally been fol-
lowed by auroral phenomena. But only a long series of obser-
vations in this direction can solve the problem.
ridge, Nov. 2, 1877.
.
Art. XII. —Chemical Equivalents and Atomic Weights con-
sidered as bases of a system of Notation; by C. MARIGNAC.
(Translated from Moniteur Scientifique of Quesneville for September, 1877, by
Mr. P. Casamajor.)
THE Academy of Sciences of Paris has witnessed lately, at
Several of its sittings, an interesting discussion, in which sey-
eral eminent chemists, among its members, have taken part.*
This discussion related to two questions which have often
been brought before it, and which will probably be brought
before it again many times.
One subject of discussion was a principle, stated in 1811 by
-* Messrs, Sainte Claire Deville, Wirtz, Berthelot, Fizeau.
90 ©. Marignac—Chemical Equivalents and Atomic Weights.
an Italian philosopher, Avogadro, on the equality of the mole-
cules of all bodies in a gaseous state. This principle is hal
placed in opposition to the law of Gay Lussac, on the simple
relations which exist between volumes of gases, capable oe com-
bining with one another, which law was established a few years
before, and which, to tell the truth, is not in contradiction with
the hypothesis of deenireaie From this question arose another,
on the relative merits = the chemical notations, expressed in
equivalents or in atom
For the present, I will not discuss the first of these 5 vie
The truth of the principle of Avogadro can only be admitted
on the condition of supposing that the atoms of Peaplé gases
cannot exist in a free state, but are welded together in_ pairs,
forming molecules occupying two volumes, like the molecules
and for phosphorus and arsenic, whose molecules must contain
four atoms.
This hypothesis is not absurd in itself. It may account for
certain chemical rine such, for instance, as the greater energy
of action that bodies possess in a nascent state, or before their
atoms have coed biel two by two to form molecules; also for
the ease with which certain reactions take place, as pointed o out
by M. Wiirtz. It also explains several physical facts, such as
the equality of specific heat for the same volume of simple or
compound gases, whose molecule is formed of two atoms, as
carbonic oxide, hydrochloric acid. It found lately an important
poe gm in the researches of Messrs. Kundt and Warburg*
gases. We must acknowledge, however, that these considera-
tions Go not constitute sufficient proofs.
On the other hand, there are some compound bodies whose
ress densities are in contradiction with the principle of Avo-
We should be forced to admit that all these compounds
suffer decomposition when they seem to be reduced to vapor,
so that, instead of measuring their volume, we measure that of
their elements, -or of the products of their wr Sd pit
Although this decomposition has been ascertained in some
cases, it has not in one
seen, the principle of Avogadro gives rise to
serious objections, ihe without being convinced of its worth-
lessness, like my eminent friend, M. Deville, I acknowledge
that it is as yet but an hypothesis, in contradiction with facts,
which have not been satisfactorily explained. But, I repeat
Berichte der deutschen Chemischen Gesellschaft, 1875, p. 945.
C Marignac—Chemical Equivalents and Atomic Weights. 91
to have them discussed in the presence of the scientific body
which has the greatest authority, with the object of maintaining
the established system, or of introducing the other.
To enter into this discussion, it is doubtless advisable, in the
first instance, to detine what is understood by these equivalents
and these atomic weights, which are placed in opposition to
one another.
equivalents, I see that M. Berthelot tells us that
3 } tion.” Unfortunately he
? is S
vf any, at least of any that is precise and general. Doubtless
bromine and iodine, the definition of their relative equivalents
18 perfectly clear, as the term equivalent is its own definition.
ut when we deal with bodies which have not a similar
. . x a = nd
; University, comprising faculties of letters, medicine, law a
Govlogy , lycées for Manan instruction and schools of primary instruction.—
92 @C. Marignac—Chemical Equivalents and Atomic Weights.
analogy, and particularly if they do not perform the same
functions, the idea of equivalence has no meaning. I defy
anybody to give a general definition of equivalents which
justifies the weight 14, adopted for nitrogen. In volume, it
eure to the equivalents of hydrogen and of chlorine,
t it has not the same chemical value. It has the same
wictanah value as the equivalents of phosphorus and arsenic,
t
equivalents of oxygen, of reac gael and of most metals) Why
then should this number exist ?
If, instead of starting Pain a general definition, which does
not exist, we try to find the meaning of equivalents in the
methods employed i in determining them, we are led to the
following conclusion
It is proved by experience that we may assign to a body,
it simple or compound, various weights, ‘multiples of the same
number, and that these weights express the proportions accord-
ing to which all bodies combine with one another. We ma
choose one of these weights to express the equivalent of the
body. All combinations may then be represented as the
and, if the equivalent is — ented by a symbol (in general
the first letter of the name of oe element), combinations may
represented by foeeh olen which are not generally compli-
eated. This is, after all, the only condition required of equiv-
— and hence the only general definition, although not
very precise, which can be given is that the equivalent repre-
—— for a element or Sceeey: Sing nd body one of the weights
en bodies are an nai and have the same chemical
denice their equivalents are represented by the weights
which replace each other in analogous combinations. Let us
note, however, that this rule is not followed for compound
bodies, such as bases and acids, whose so-called equivalents
are weights which often have: very sean values of com-
‘undamental principle of equivalents has been entirely aban-
doned for compound bodies, and, in its stead, a method has
been adopted, which has been borrowed from the atomic
C. Marignac—Chemical Equivalents and Atomic Weights. 98
theory, by taking for their weights the sum of the equivalents
of the elements which they contain.
I believe I am not in error when I affirm this, as M. Ber-
thelot* says: ‘One equivalent of phosphoric acid corresponds
to three equivalents of nitric acid, when it forms a tribasic
phosphate.
2. Equivalents are chosen in such a way that compounds,
which offer the greatest analogies, are represented by similar
formulas. This principle served as a guide in determining the
equivalents of aluminum and of copper. It is often in contra-
diction with the preceding. For instance, aluminum and mag-
nesium, which are both powerful deoxidizing agents, do not
replace each other in the proportions indicated by the equiva-
lents adopted for these two metals.
| When neither of these rules is applicable, or when the
lead to complicated formulas, the equivalent of a body is chosen
in such a way as to give the simplest possible formulas for its
most important combinations. This rule justifies the adoption
of the equivalents of nitrogen, phosphorous, arsenic and of some
other elements,
e may see by the above that the equivalents constitute a
purely conventional and arbitrary system, without any scien-
tific value.
The explanation I have given of equivalents is somewhat
different from that which my illustrious teacher, M. Dumas, gave
in his lessons of chemical philosophy. This eminent chem-
ist took as his starting point the equivalents of bases, as deter-
mined by their true chemical equivalence, founded on the same
quantity of oxygen contained in the base. The equivalents of
acids are rigorously deducted from the weights necessary to
neutralize an equivalent of base. Afterwards, he seeks to es-
tablish the equivalents of the elements by considerations which,
he acknowledges, are often arbitrary. This method of deter-
mining equivalents however, has been either never adopted, or
entirely abandoned, doubtless because it led to formulas which
are inadmissible. I have given the meaning of equivalents,
such as they have been adopted, and not such as they might
have been.
* Meeting of the Académie des Sciences of June 4th, 1877. I cannot in any
manner accept what he says, in the same place, that this equivalent of phosphoric
pendrin to one equivalent of nitric acid in sic phosphates, or two
€quivalents in bibasic phosphates, To admit such expressions, we must deny to
Ae nitred serte that all chemists attribute to it in these salts, since the publication
°f Graham’s researches.
94 ©. Marignac—Chemical Equivalents and Atomic Weights.
If we refer to the fundamental hypothesis of the atomic theory,
which supposes that the a of bodies is not indefinite,
but that they are formed by the agglomeration of excessively
small but indivisible particles, or atoms, the theoretical defini-
tion of atomic weights is of the simplest, as they are the relative
weights of these ultimate particles. But, however simple the
definition may be, the determination of the weights is sur-
rounded with great difficulties,
thesis of the existence of atoms accounts in such a
simple manner for that < hs ag equivalent proportions for
elements which play t me part, that we are natura
at first sight, to mueiter icas proportions as representing their
relative _— weights, although this consequence is not rigor-
ously necessary. It is evident, however, that as neither this
consideration of chemical equivalence, nor any other considera-
tio rawn from chemistry alone, has led to a complete and
arti: cpitanh of chemical equiva alents, we cannot by such con-
siderations be gui in the choice of all the atomic weights,
and as these. on account of the hypothesis that is made on their
nature, cannot be arbitrary, like equivalents, it has become
necessary to study the physical properties of the elements and
of compound bodies to find motives for this determination of
the atomic weights. Among the properties which can be ap-
pealed to, the most important are the densities of gases and
vapors, . the specific heats and isomorphism.
I acknowledge that in some very rare cases these three orders
of physical properties do not lead to the same result, and [agree
with Mr. Berthelot that between these three data we must make
a choice. I am, however. in complete disagreement from him
in the conclusion that I draw Sane this. If he does not say So
expressly, his whole argument proves that, in his opinion, no
account is to be taken of these physical properties, when they
disturb the usage established for weights that have been adopted
‘or a long time in chemical notations. On the contrary, I think
that great account should be taken of these physical properties,
and that when they all agree we must have eno fear of modifying
a few formulas which have only long usage in their favor, par-
re if the necessary modification is unimportant. If,
oreover, the physical properties do not agree, it is necessary
i. cite the facts with the greatest care, and see if, in some
cas isagreement can be explained and then choose the
vaabe which spite ot i digs the general properties of the
elements and its
Is it thipoobes to oe this? The best proof that it is not, and
that there is even no serious difficulty in determining the atomic
weight which agrees the best with the physical pro properties, vf -
be found in this circumstance that there is no disagreem
C. Marignac— Chemical Equivalents and Atomic Weights. 95
among chemists, who accept this system of notation, as to the
atomic weights, except for a few bodies that are not, as yet,
sufficiently known; whose physical properties have not been
sufficiently studied, and for which, besides, the idea of equiva-
ents is quite as uncertain as that of atomic weights.
I am perfectly aware that the majority of chemists, who have
adopted atomic formulas, believe that they are now able to give
a rigorous definition of atomic weights. Starting from mole-
cules, which they define as the smallest quantity of a body,
simple or compound, which can exist in the state of liberty ;
admitting as an axiom the principle of Avogadro, which states
the equality of volume of all molecules in a gaseous state, from
which may be deducted their relative weights, they define the
atom as the smallest quantity of a body which may enter into
the composition of a molecule. This definition allows them to
determine the atomic weights with certainty, at least for those
bodies that enter into volatile combinations. I have not given
great weight to this consideration because, not more than
rthelo
obtained by considerations based on the physical properties.
the atomic
established, nor indeed had their equivalents. This observa-
tion might be appealed to as the strongest proof of the accuracy
of the definition of atomic weights, but I have no wish to admit
it, as constituting a sufficiently sure base for the determination
of atomic weights.
I have here to answer an objection, which I acknowledge to be
Serious, and which I believe is at the bottom of the opposition
of erthelot. The atomic weights rest on an hypothesis
which has never been, and, in fact, can never be demonstrated,
which many scientific men do not consider as verisimilar, that
of the existence of atoms. in :
_Tam nearly ready to agree with M. Berthelot in his opposi-
tion, and I have certainly no idea of defending the atomic
atomic weights. My answer to the objection stated above is
that the existence of atoms is only useful in justifying the
on the indivisibility of atoms; consequently we may consi
atomic weights as entirely independent of this indivisibility.
96 @. Marignac—Chemical Equivalents and Atomic Weights.
In reality, I consider atomic weights, and I believe that many
chemists agree in this, as being only equivalents, in the deter-
mination of which arbitrary Sidi ventions have been replaced
by scientific considerations, based on the study of physical
properties.
et us now sum up the advantages that atomic notations
same e divergence exists for equivalents.
Atomic weights are exactly nes Shee to the specific pi
of simple gases, that are not liquifiable, which agreement
not exist for equivalents. According to the law of Dulong atid
Petit, the specific heats of the atoms of all simple bodies, either '
solid or liquid, are nearly the same, except for three bodies,
carbon, boron and silicon, whose ‘physical properties offer
Equivalents do not offer this concordance. I will not insist on
the objection raised by M. Berthelot, and founded on this, that
the equality of specific heats of atoms is far from being absolute,
as he was sufficiently answered b . Wiirtz and Fizeau. I
will merely add that if we only admitted physical laws that are
absolute, we should have to reject them all. Even the law of
volumes of Gay Lussac would have to be dropped, as it has
been ascertained that all gases have not the same coéfficient of
expansion, so that the existence of simple ratios in combina-
tions by volume are not strictly accurate.
As to compound bodies, the molecular formulas, based on
the use of seis weights, present the same advantages, perhaps
to a ghee degree, when we compare them to the formulas in
equiv:
Phe ito use of atomic weights allows us to simplify the formulas
of a great number of co mpounds by dividing them by two.
Particularly is this the « case with organic compounds. Not
only does the formula become simpler, but there is an impor-
tant advantage gained, that the formulas of almost all com-
ands correspond to the same volume, which is double the
volume of the simple atom. The only exceptions are for a
very limited number of bodies, generally belonging to types of
complex wed i such as salts of ammonia and of bases
derived from ammonia; even for these it has not been proved
that they a not regulated by any law, even if M. Deville is
C. Marignac—Chemical Equivalents and Atomic Weights. 97
right in thinking that the irregularities they present are not due
to the decomposition of their vapors. On the other hand, the
formulas by equivalents teach us nothing on the vapor densi-
ties of compound bodies, as their equivalents may correspond
to two, four or eight volumes of vapor, perhaps even of six, i
the old equivalent of silicon is kept, as is done by many of
those who prefer the notations by equivalents. Molecular
formulas also agree with the specific heats of compound bodies
in the solid state. According to the law of Woestyn, molecu-
lar heats are proportional to the number of atoms contained
in the molecule, which law has the same degree of approxima-
tion as that of Dulong and Petit. Formulas by equivalents do
not show these properties. :
Finally, the system of notation, based on atomic weights,
gives the explanation of several cases of isomorphism which
are incomprehensible with the notation based on equivalents.
For instance, in the case of perchlorates and permanganates,
and in the case of chloride and sulphide of silver when com-
pared to protochloride and protosulphide of copper. | I may
also recall that it was by considerations of the same kind that
I was led to discover oxygen in fluorine compounds of niobium,
where its presence had not been suspected, and that the formu-
las of these compounds, expressed in equivalents, would never
have suggested this idea.
n presence of these advantages, we may as hat are
those that are offered by the system of equivalents and its
seven, which would have given it the same volume as oxygen,
or 14 which would have accounted for its value of combination
toward hydrogen and the metals, we may readily believe that
there will never be a sufficient motive to replace it by one of
these numbers. The determination of equivalents not being
governed by any fixed rule, they will not be necessarily modi-
ed when we come to have a more accurate knowledge of the
properties of bodies. : :
In the second place, as, in their determination, no account 1s
taken of the physical properties of bodies, greater attention can
given to their chemical equivalence, when it exists. This
presents some advantages in practical chemistry. :
These considerations are doubtless of some value; but if we
examine things a little closer, we may easily see that, in this
i there is really very little difference between the two
stems.
Am. Jour. Sct.—Turrp Serres, Vou. XV, No. 86.—Fss., 1878.
7
98 ©. Marignac—Chemical Equivalents and Atomic Weights.
It is true that there was a time when atomic weights
had to be changed, and it is doubtless, on this account, that
atomic weights were dropped and equivalents adopted. Never-
theless, the history of chemistry shows that for more than
thirty years no changes have been judged necessary for well
known bodies, and that those which have been admitted for
elements, whose properties or whose combinations had previ-
ously been raises nown, were so thoroughly justified by
their chemical properties, that even the equivalents of these
bodies have had to be modified. Such was the case for bis-
state; on the specific heat of their combinations, or on isomor-
phism as was done in the first instance by M. Regnault.* We
may see by this that, on the score of invariability, the two
systems are on a par.
As to the advantage which results from the fact that equiva-
lents express ratios of real chemical equivalence, in cases
where they are not indicated by atomic weights, it would be
an important one if chemical equivalence were indicated in all
cases; but we know that this is not so. It is really not more
difficult to conceive and to remember that an atom of oxygen
is worth two of chlorine, and an atom of lead two of silver
than to know that an equivalent of nitrogen is worth three of
oxygen, and that two equivalents of aluminium are worth
three of magnesium. So there is really no advantage, on these
two heads, which can counterbalance those which I have
shown for atomic notations.
It may be said that the preceding is a contradiction of what
I said before. I said that the system of equivalents presents
conditions of invariability that are not presented by atomic
weights. Further on I have shown that every change of atomic
weight had necessitated a corresponding change in equivalents.
If we look for the cause of this apparent contradiction, it
seems to me that we shall be led to make an observation whic
gives the kev to the discussion actually going on. It is that,
in reality, if we keep out of sight every question as to the
origin of the terms equivalents and atomic weights, there is no
difference between the two systems, and the partisans of equiva-
and occur with great frequency.
* Annales de Chimie et de Physique, 1841, III, vol. i, p. 191.
J. LeConte—Glycogenic function of the Liver. 99
Art. XIV.—Some thoughts on the Glycogenie function of the
Liver and its relation to vital force and vital heat; by JosEPH
L
[Read before the National Academy of Sciences, New York, October, 1877.]
THE great size of the liver and its persistence as a conspicu-
ous organ, as we go down the animal scale even to a very low
position, clearly demonstrate the great importance of its func-
tions. This conclusion is entirely confirmed by the very grave
effects on the health produced by its disorders. But in spite of
its acknowledged importance, great obscurity still hangs about
the true nature of its functions. The function of the liver is
not simple, like that of the lungs or the kidneys, but very
complex. The liver isthe manufactory of both bile and sugar.
The bile is both a secretion used in the digestive preparation
of food, and an exeretion, separating poisonous matters
the blood. The sugar, too, has doubtless as many and as com-
e€ ‘
usually acknowledged facts connected with this function.
1. The portal blood of flesh-fed animals contains no sugar,
but the same blood, after passing through the liver, i e., the
blood of the hepatic vein, contains always a notable quan-
tity of this substance. Evidently, therefore, i is manufactured
in the liver.
veins until every trace of sugar is removed, and then the liver
be allowed to stand a while, on recommencing the transmission
of water the first that passes is decidedly sugary. The same pro-
cess may be repeated several times with the same result, until
the material out of which the sugar is made is finall exhausted.
8. If the liver of any animal be kept a considerable time
before cooking, the amount of sugar which accumulates in its
100 J. LeConte— Glycogenie function of the Liver.
substance is so large as to be easily detected by the taste. The
liver is decidedly sweet. I have very often detected this sweet-
ness. I have not seen attention drawn to the fact.
4. Evidently, therefore, the liver is constantly forming “—
from some insoluble or feebly soluble substance, which o
This substance has been isolated by Claude Bernard and oth-
ers, and its properties determined. It is a white, feebly-soluble,
tasteless, amorphous substance, having the composition of
starch or dextrin. It changes easily and rapidly into sugar by
mere contact of blood or other albuminoid ferment. It is
called glycogen or sugar-maker. It is a kind of animal starch.
The quantity of glycogen in the liver varies much with the
food, Hee greatest (17 per cent) with amyloid food, and least
(7 per cent or even only 2 per cent) with albuminoid food.
(Pavy.).
5. The sugar formed from glycogen (liver-sugar) is closely
allied, perhaps in composition sone with glucose; but ap-
parently differs from this and all other forms ot sugar in being
more unstable, i. e., more easily rater and especially more
easily burned or oxidized in the blood. Tt therefore probably dif-
fers Pot glucose in molecular structure if not in chemical com-
pect i throw light on t rs oppiait sad which therefore we
1. The-a amount of amyloids which may be taken, and often
is kee is food, by a healthy man in the course of a day, is
certainly one or two pounds. The whole of this is converted
into sugar before it can be taken up. Two pounds of sugar,
therefore, may be taken into the blood of a man who is fed
largel on amyloid f
$i his artiount - sugar in is blood would make or
J. LeConte—Glycogenic function of the Liver. 101
of the sugar is arrested in the liver, changed into a less soluble sub-
Jrom circulation and stored in the liver. The stored amylod is
then slowly re-changed to sugar, but in the more oxidable form of
liver-sugar,and_ re-delivered, little by little, to the blood by the
hepatic vein, as the necessities of combustion for animal heat
and vital force require.
The views thus far presented have been held with more or
less firmness by most physiologists since Bernard’s discovery of
this function. In what follows I have attempted only to push
these views to what seems to me their legitimate conclusions.
It will be observed that there is here a double change in op-
posite directions. The liver seems to change sugar by dehy-
dration into glycogen only to change by rehydration glycogen
ack again into sugar. At first sight there seems to be, there-
fore, a waste of force such as never occurs in the animal body.
This has been urged by Pavy and others as an objection to
this double change, as a fact. But there are at least two good
Teasons for this double change. First: A large quantity of
sugar (glucose) in. the blood is very hurtful. The experiments of
Dr. Wier Mitchell, of Philadelphia, have prov that large
102 J. LeConte—Glycogenic function of the Liver.
quantities of sugar in the blood produce, among other hurtful
effects, cataract and blindness. ‘The cataract, socommon amon
diabetie patients is doubtless due to this cause. Plainly, there-
fore, there is needed a reservoir to receive and detain the flood
of glucose poured into the blood after every full meal of
amyloids. The liver is that reservoir. A second reason for
this double change—(and this is probably the fundamental rea-
son)—is that the sugar is re-delivered to the blood not as glu-
cose but as liver-sugar, and therefore in a more oxidable form—
as a better fuel than previously.
For thesake of greater clearness, we have spoken thus far as
if glycogen were made only from sugar. Most of it is un-
doubtedly made in this way in all animals except carnivora.
But it seems certain that the liver has the power of making gly-
cogen from albuminoids also; for animals fed on albuminoids
alone still continue to make sugar from glycogen. Therefore—
and this is a very important point—albuminoids are decompused
in the liver into glycogen and some nitrogenous matter, which is
separated and excreted partly in the bile, but probably mostly
restored to the blood to be excreted as urea by the kidneys.
In this way the excess of albuminoid food, over and above what
is necessary for tissue-building is reduced to a condition suitable for
easy combustion.
But if this view be correct—if this be the way in which
albuminoid food in excess of the requirements of tissue-build-
ing is disposed of, then it is certain that waste tissues also are
eliminated in the same way, for these are also albuminoid.
The first step in the elimination of these takes place in the
liver where they are decomposed into glycogen to be burned as
sugar and eliminated through the lungs, and a nitrogenous res-
idue to be eliminated mostly by the kidneys. If so, then ani-
mals starved to death ought to make glycogen and liver-sugar
to the last. Now, according to Chauvean, horses and dogs after
six days fasting still continued to make liver-sugar.*
Again: we have spoken thus far only of the dissolved food
taken up by the portal capillaries and distributed through the
liver before entering the general circulation. By far the larger
part undoubtedly takes this course; but a small portion also is
taken up by the lacteals. This enters the general circulation
through the thoracic duct, little by little, in proportion as it is
taken up. But this also must pass, though not so directly,
through the liver by the hepatic artery or by the mesenteric
artery and portal vein and is doubtless also arrested there in
the form of glycogen. /
There are, then, three sources of glycogen, and therefore of
liver-sugar, viz: 1. The whole of the amyloid food. 2. All
: . * Comptes Rendus, vol. xliii, p. 1008.
J. LeConte—Glycogenie function of the Liver. 103
albuminoid food in excess of what is required for tissue-building ;
and 8. All wasie tissues. But since in the mature animal waste
nated: partly as the nitrogenous matter of the bile, but mostly
as urea by the kidneys. There are also the same three sources
of vital force and vital heat, viz: 1. Combustion of amyloi
f 2. Combustion of the combustible portion of albumin-
oid food-excess. And 8. Combustion of the combustible por-
tion of waste tissues. And, for the reason already assigned, this
is exactly equivalent to combustion of the combustible portion
of the whole food. Therefore, the sole object of the glycogenic
are led to anticipate that the failure of this function must
entirely sap the vitality of the system. That such is a fact we
shall presently see.
There are several important conclusions to be drawn from
the above to which I would next call attention. i
1. The real function of the liver in this connection is not
glycogenie or sugar-making as usually supposed, but glyco-
genic or glycogen-making. Glycogen-making is a true vital
changes are descensive only. These two opposite processes 1D
the liver are fully recognized by Claude Bernard, although for
convenience both processes are called glycogenic.
104 J. LeConte—Glycogenre function of the Liver.
2. In the well-known and usually fatal disease, diabetes,
sugar is excreted in large quantities by the kidneys. But the
kidneys are not the organ in fault. On the contrary they do
all they can to remedy the evil. Sugar in the blood is ex-
tremely hurtful; the kidneys remove it as fast as they can.
Some have supposed that the lungs are in fault. e sugar
contributed by the liver to the blood, they say, is not burned
up as fast as received (as it ought to be) on account of deti-
ciency of oxygen taken in by the lun ut the true organ
directly in fault is undoubtedly the liver. In diabetic patients
the liver seems to have Jost its glycogen-making power. The
sugar taken up by the portal capillaries is not arrested in the
liver, but allowed to pass straight through unchanged into the
general circulation, whence it must, of course, be eliminated
by the kidneys. The difficulty is not too much sugar-making
but failure to arrest the sugar as glycogen. This is proved b
cases of traumatic diabetes. It is well known that puncture
of the floor of the fourth ventricle of the brain produces dia-
betes. In such cases, even though sugar be ingested in large
quantities there is no glycogen formed in the liver; the glu-
cose having been allowed (probably on account of paralysis of
the vaso-motor nerves) to pass straight through unchanged
into the general circulation. The extreme gravity of patho-
logical diabetes, therefore, is partly the result of the directly
hurtful effects of sugar in the blood, as shown by diabetic cat-
aract, but chiefly owing to serious disorder of a very impor-
tant function of the liver—a function on which wholly depends
animal heat and animal force of all kinds, viz: the prepara-
tion of food and waste-tissue for easy combustion. The use of
reconverted into the soluble form of sugar.
In a work entitled “‘ Digestion Végétale,” published in 1876,
J. LeConte—Glycogenic function of the Lnver. 105
universal among organisms. But, as we have already shown,
the true analogue both of starch-formation and starch-solution
in plants is found in the glycogenic function of the liver. Di-
building material: of course, therefore, a re-conversion
into sugar it must be again re-converted into insoluble cellu-
use as fuel for force-making. Plants do not require it for force
for they draw their force from the sun. Animals do not require
it for tissue-building for their tissues are wholly aibuminoid.
. We have seen that albuminoids, whether food or waste tis-
Sues, are probably split in tbe liver into glycogen and some
hitrogenous residuum. The glycogen is changed into sugar and ~
106 J. LeConte—Glycogenic function of the Liver.
then by oxidation into CO, and H,O and eliminated by the
lungs. The nitrogenous residuum if it is not at first urea is at
least easily changed into urea and eliminated by the kidneys.
We see then the close relation between the functions of the
liver and kidneys. Now in going down the animal scale, we
find in many cases, as for example in insects, that the same
organ performs both functions. In the process of evolution urea
was at first formed and excreted at once by the same organ.
Afterwards these two processes were differentiated.
7. We have already stated that Foster found a large percent-
age of glycogen in the tissues of entozoa.* He asks, “ Of what
use is this glycogen?” and answers, “ No respiratory use” is
possible, for “having a constant temperature secured to them”
by the body of their host, “they are the very last creatures to
need respiratory or calorifacient material.” He, therefore,
inclines to the view of Pavy, that glycogen is not respiratory
material at all, but material on its way to become fibrin. On
the contrary, we, for our part, see in this observation of the
presence of stored amyloid in an animal not needing any inter-
often or too strongly enforced that the prime object of com-
bustion in the animal machine, as in the steam engine, is not
heat-making but force-making. Heat is only a concomitant, often
useful, but sometimes useless and even distressing. Careful
experiments have over and over proved this; the doctrine of
conservation of force absolutely requires it; and yet pbysiolo-
gists still go on serenely talking of respiratory food as only heat-
making, as if vital force were something wholly unrelated to
other forces of nature and therefore requiring no explanation at
all. e vital force created by combustion ma
largely in mechanical power, as in the higher animals, or almost
wholly in the vegetative functions of digestion, assimilation,
secretion, &c., as in the more sluggish lower animals suc
many mollusea and entozoa.
Postseript.—Since finishing this article in April last, I have
read with deep interest a very remarkable paper by Professor
é * Proc. Roy. Soc., xiv, 543.
J. P. Cooke—Atomic Weight of Antimony. 107
Schiff,* entitled “‘ A new function of the liver,” in which the
author demonstrates in the most convincing manner by means
of experiments on dogs and frogs conducted in the physiologi-
eal laboratory in Geneva, that the liver has the power of completely
decomposing poisonous matters generated by the wasting of tissues.
Ligation of the vessels of the liver, especially of the portal vein,
death in the course of one to three hours. In frogs, it is true, liga-
tion produced little effect, but this is only because of the slow-
ness of the changes in their tissnes; for the blood of dogs dead
of ligated livers injected into the circulation of frogs quickly
destroyed life if their livers are ligated, but produced no effect if
the livers are unligated. Moreover many other organic poi-
sons were shown to be either wholly or partly destroyed and
rendered innocuous by the liver. Doubtless this is the true
rather an extension of the glycogenic function, throwing upo
it a new light and giving it a new significance. It is precisely
this new significance which I have attempted to set forth in the
foregoing paper.
Berkeley, Cal., Oct. 15, 1877.
Art. XV.—Revision of the Alomic Weight of Antimony; by
Jostan P. Cooke, Jr.
(Concluded from page 49.)
_ AFTER a long series of experimeuts, which threw but little
light on the cause of the discrepancy that had now become so
prominent, although they yielded very interesting subsidiary
results which are described in detail in the original paper, we
Made a series of analyses of antimonious bromide with the
hope that if there was, as we suspected, a_
error in the analyses of anitimonious chloride, the same influ-
weswould affect the analyses of the corresponding bromide to
* Arch. des Sciences, lviii, 293, March, 1877.
108 J. P. Cooke—Atomic Weight of Antimony.
We prepared the bromide of antimony by adding in small
— at a time the pulverized metal to a strong solution of
romine in sulphide of carbon. The retort containing the so-
water bath; and then, replacing the water bath with a gas
delicate tests which we possess for all three of these elements so
frequently associated with commercial antimony and bromine,
failed to show the least trace of either in the bromide of anti-
mony we analyz The determinations of bromine were
made in all respects like those of chlorine. Great care was
taken not to add more than a very slight excess of argentic
nitrate, and we found that under these conditions the superna-
tant liquid cleared more readily above the precipitate in the
case of bromide of silver than with the corresponding chloride,
and for this reason the first could be washed more quickly than
the last. The results of these determinations are embodied in
the table on the following page.
Here, as before, the letters indicate different preparations: @
was made and purified as described above; 6 was the same ma-
terial as a redistilled and again crystallized from bisulphide of
carbon; c was another portion of the same material several
times redistilled and twice recrystallized from the same sol-
vent; d was a separate preparation from the start; e was
another separate preparation purified with extreme care. In
the last case there was over a kilogram of the crude pro-
duct, which was reduced by the fractional distillation and crys-
tallization—each process repeated from ten to twenty times—
J. P. Cooke—Atomic Weight of Antimony. 109
to the few grams used in the analyses.) These methods of
ert the substance were thus pushed to their utmost
imits.
ANALYSES OF ANTIMONIOUS BROMIDE.
DETEMINATION OF BROMINE.
Wt. of SbBr, taken .Wt.of AgBr ¢ of Bromine
in grams. obtained.
No. Br=80, Ag 108.
l, a. 1°8621 2°9216 66°765
2, a. 0°9856 1°5422 66°584
3, 5. 1:8650 2°9268 66°79 :
4, b. 1°5330 2°4030 66°703
5, b. 1°3689 2°1445 66°663
6, ¢. 1°2124 1°8991 66°655
7, ¢. 0°9417 1°4749 66°647
8, d. 2°5404 3°9755 66°593
9, d. 1°5269 2°3905 66°623
10, e. 1°8604 2°9180 66°743
11, ¢. 1°7298 2°7083 66°624
12, ¢. 3°2838 5°1398 66°604
13, ¢. 2°3589 3°6959 66°671
14, €. 1°3323 2°0863 66°635
15, ¢. 26974 4°2285 66°708
Mean value from last six determinations, 66°664
Mean value from all the determinations, 66°6665
Theory Sb 120 requires, ......--------- 66°6666
TOOTS SAPS oO eee ou ieee 66°2983
whether we take Stas’s or Dumas’s values for the atomic
weights of bromine and silver, the atomic weight of antimony
deduced from the above determinations is exactly 120-00.
_This is certainly a remarkably close confirmation of our pre-
vious conclusion. Indeed the wonderful coincidence between
the observed and the theoretical results must be to a certain
extent accidental ; for no process of chemical analysis is capa-
ble of the accuracy which this agreement would imply. Still
table errors of the process, so
far as they are indicated by the variations from the mean
110 J. P. Cooke—Atomic Weight of Antimony.
must depend on the extraordinary attraction of this substance
for moisture. Before, however, fully following out the clew
thus obtained, we made a similar study of the iodide of anti-
mony.
The iodide of antimony was prepared like the bromide, by
shaking up in a glass flask a solution of iodine in bisulphide of
carbon with finely pulverized metallic antimony. On filtering
and decanting, after the color of the iodine is discharged, a
solution having a pale greenish-yellow color is obtained, from
which on cooling or on evaporation red crystals of iodide of
antimony are deposited. The substance may be purified by
recrystallization from the same solvent; but iodide of anti-
mony is far less soluble in bisulphide of carbon than the chlo-
ride or bromide, and cannot therefore be so advantageously
treated in this way, nor can tbe small amount of carbonaceous
impurity which the crystals acquire from the solvent be so
easily rem . Moreover, iodide of antimony cannot be so
readily distilled as the chloride or bromide, on account of its
high boiling point, which is above that of metallic mercury.
But another property of iodide of antimony which, so far as
ful phenomenon. So also when the greenish-yellow solution
(above described) of the iodide in bisulphide of carbon is ex-
1 tothe air and light, it rapidly becomes colored red f
J. P. Cooke—Atomic Weight of Antimony. 111
deposition of the insoluble oxi-iodide. Even the crystals of
iodide of antimony, when kept in the light, slowly become
opaque from the formation of the same oxi-iodide; while the
odor and staining of the stopper of the bottle furnish abundant
proof of the liberation of iodine. « The study of these phe-
nomena was most interesting, and the results obtained will be
described in another paper. It is sufficient for the present to
say that they pointed out to us a great source of impurity in
iodide of antimony, and fully explained the want of accordance
in our analyses of the crystals of this substance as first pre-
pared. It was evident that we could only hope to purify the
material by distilling or subliming it in an atmosphere o.
Inert gas; and we devised the apparatus represented in the ac-
companying figure for this purpose, which we have since found
very generally useful forall sublimations where the temperature
required does not exceed that which can be measured with a
lated temperature the precipitates of sulphide of antimony,
aa: was so arranged that the character of
112 J. P. Cooke—Atomic Weight of Antimony.
it reaches its melting point, 167°, the evaporation becomes very
marked. Assoon as melted, it sublimes quite rapidly ; and we
obtained the best results by ‘keeping the temperature between
180° and 200°, and by shifting the adapters we used as receiv-
ers, it was —_ to collect the different portions of the subli-
te. thus obtained crystals of two isomeric modifications
of iodide of antimony : the more abundant in large hexagonal
plates, often half an inch or more in diameter, perfectly trans-
parent, and of the most brilliant ruby-red color ; the other in
small — — ee the same peculiar greenish: yellow
color as the solution of the iodide already mentioned. The
Ganaat of the bee was always small, but it was ae in pro-
portion as the temperature was lower. This new and most
interesting product will be described in the paper just referred
to. Of these crystals, the most brilliant, chiefly of the red va-
riety, were selected for analysis. The iodine determinations
were conducted in all respects like those of chlorine and bro-
mine. The iodide was first dissolved by a very concentrated
solution of tartarie acid, and then the solution was diluted to
the required extent. The same care was taken not to add
tion in so far as it was a product of a separate sublimation ;
but the material sublimed was essentially the same in all cases,
—a mixture of the products of many crystallizations from the
crude material made as described above. The results are col-
lected in the following table :
ANALysis oF IopipEe or ANTIMONY.
IopINE —e.
No, Wt ofSbl,, Wt. of Agl, nigew roves Variety.
i 171877 16727 76°110 Pure red.
2. 0°4610 0°6497 767161 tesa yellow.
3. 3°2527 45716 75°956 Pur re
4, 1°8068 2°5389 75°939 ure
5. 15970 2°2456 75°990 Red ind 1 yellow.
6. 2°3201 3°2645 76°C40 Pure re
‘* 0°3496 0°4927 76°161 Chiefly anew
Mean -wAlRes kines ca bocdiociwniness 76°051
Theory Sb==120, requires a inne 76°047
Theory Sih 82,.. <5 oi eerie nate ne: 75°744
If in calculating the results of these iodine determinations we
use the atomic — of Stas, I=126°85 and Ag=107'93, the
mean value would be 76-034, and the corresponding atomic
weight of antimony 119-95.
J. P. Cooke—Atomic Weight of Antimony. 113
The difference (0°004) between the first mean value and
theory—corresponding to only about 2; of a milligram in the
largest amount of argentic iodide weighed—is evidently insig-
nificant, so that these results confirm the lower value of the
atomic weight of antimony as closely as did the analyses of the
bromide.
As we have already intimated, our analyses of the iodide
of antimony, as first crystallized from bisulphide of carbon,
vielded very discordant results. These we give in the table
below, not, as before, in the exact order in which the analyses
Ww ade, but in the order of the several values, so as to
exhibit the distribution of the errors.
ANALYSES OF CRYSTALLIZED Antrmontous IopIDE, RED VARIETY.
No. ' % of Iodine.
Be ee ete ee ae oe. eT
D tech wht tes big eats i ok Tae
Beis ce a Eee 75°78
Be ee ee ee ee 75°80
Bik ve ae eae ee ee
| AGN i aca eet ON Ui ong gee Boel 75°85
ey Etiini 75°87
Sof ee es ee ee ee
Vie er Pe ee oe ee eee
PERO VOlR ce cis ne .-75°83
Lheory Sbiai09.) 2) <2 eee 75°74
Theory Sb=-190.. 2 oe ee
The cause of this discordance we attributed, as we have inti-
mated, chiefly to the remarkable readiness with which iodide of
antimony undergoes oxidation in contact with the air, resulting
A the formation of oxi-iodide of antimony and free iodine,
us :—
28bI, + O-O = 2SbOI + 21L-1
While the free iodine escapes, the oxi-iodide remains as an im-
purity in the preparation, and the effect is a replacement of a por-
tion of its iodine by oxygen. Now, since eight parts of oxygen
replace one hundred and twenty-seven parts of iodine, it can
readily be seen that an otherwise almost imperceptible amount of
oxidation would be sufficient to produce all the variation from the
normal composition which the above results present. A simple
calculation will show that an absorption of only 7#2,ths of one
per cent of oxygen, or less than half a milligram by each gram
of iodide of antimony, would reduce the per cent of iodine from
the theoretical val ue, 76-047, to the mean of the above results,
Am. Jour, Sct.—Turp Serres, Vou. XV, No. 86.—Fxs., 1878.
8
114 J. P. Cooke—Atomic Werght of Antimony.
75832 ; and that a corresponding absorption of three-quarters
of a milligram would reduce the per cent to 75-700, the lowest
observed. It is not, therefore, surprising tbat we could obtain
concordant results only with material wbich had been both
purified by crystallization and also recently sublimed.
Returning now to discuss again the cause of the disagree-
ment of the analyses of antimonious chloride with our otherwise
consistent results in regard to the atomic weight of antimony,
it was obvious that the strong hygroscopic power of the chloride
must lead to a replacement precisely similar to that which is
shyly in the iodide by direct oxidation; for, as we have
fore said, the crystals of antimonious chloride cannot be
exposed to the atmosphere for an instant without absorbing a
perceptible amount of moisture, and every molecule of water
thus absorbed reacts on a molecule of the chloride, thus:—
SbCl, + H,O = SbOCI + 2HCL
And when the antimonious chloride is boiled, the hydrochloric
acid formed is given off, while the oxichloride remains behind,
dissolved in the great mass of the liquid. Indeed, it seems
impossible, with our ordinary appliances, to prepare or purify
antimonious chloride without its becoming contaminated with
oxichloride; and our experiments would indicate that when
once it has been formed, as above described, in the mass of the
material, it cannot be wholly removed by distillation or crys-
tallization, however often these processes may ,
aturally, our attention was very early called to this obvious
source of impurity in the antimonious chloride we prepared:
and we noticed from the first that, even after the material had
been many times distilled, there was always left, on repeating
the process, a very small amount of dark-colored residue.
had examined the residue, and found that it was a mixture of
chloride and oxichloride of antimony, colored by a trace of car-
bonaceous material; and we had made a long series of analyses
for the purpose of studying the effect produced by the action
we have described. The result of these analyses is given in
the following table. We started with material already purified
by fractional distillation and crystallization, and distilled it ten
imes in succession ; not, however, carrying the distillation to
absolute dryness, but leaving, so far as we could judge by the
eye, about the same amount of residue in the retort each time.
These residues we analyzed, as we did also the final distillate.
The material first distilled was the same as that marked ¢ in
the table on page 47, and we assumed that the average of the
results there given truly represented its composition.
J. P. Cooke—Atomic Weight of Antimony. 115
ANALYSES OF ANTIMONIOUS CHLORIDE.
RESIDUES AND DISTILLATES.
@ of Chlorine.
The original purified preparation ..._..........-..--.-- 46°64
Mle fecidue of lst distillate. |. 0.2 (612i baron ee oi Si 45°71
a 2d Misti val it Boies eo BE. Bie 45°66
4 3d Bs othe Mage see Tas ee oe 46°03
x, 4th ick Soe aeu AGE eee he 46°26
. 5th 2 ie dos hh cae eee oe eee BE
sal 6th © oo URN SEs ae BU RD ale oe 00
- 7th e etek Be a i ee 2 ee a ee
x3 8th GOS ice perience nmr iicge 45°94
i 9th SS gah ens deeds ees
“ CO Goeeit Eh eon iagegs Oak aa ee ere 45°99
Pee ent distillate. oc Ae 46°6
transfers between the several distillations necessarily involved.
But, on the other hand, the very remarkable fact that these ten
on the final result; and this opinion was still further strength-
upon us by the subsequent results of the investigation, =
turning to the subject after our experiments with iodide
action on the iodide. It ends in replacing a small amount of
orine by oxygen; and although, in consequence of the
116 J. P. Cooke—Atomic Weight cf Antimony.
smaller atomic weight of chlorine, it requires in this last case a
larger replacement to produce a corresponding change of per-
centage composition, yet still the amount required to make all
the difference in question is very small; so that, when we come
to sum up the supposed completed results (as on page 47), it
might easily be covered up by slight inaccuracies of the
analytical work. An easy calculation will show that the sub-
stitution of but ;',°, of one per cent of oxygen for the equiva-
lent amount of chlorine would reduce the per cent of this last
element in the chloride from 47-020, corresponding to Sb=120,
to 46-608, which corresponds to Sb=122; and such a substitu-
tion would result from the absorption of only 1,4, milligram of
water by each gram of the chloride. The composition of the
material would then be as follows :—
Composition OF ANTIMONIOUS CHLORIDE WITH 745, PER CENT OF
O wHEN CL=35°5 anp Sp=120.
RmONteRiLait. Sou ces. celui. 22 a aii 26606
MpeGR swodid. ress ee Ca eo ae ee
BRNNIONG Sia. 8 a a ee hl eee
100°000
Now it will be seen by referring to the tables, on pages 47 and
48, that these percentages do not differ from the mean of the
results of our previous analyses as much as these results differ
among themselves; and we therefore determined to repeat these
analyses, hoping that the experience we had acquired in both
chlorine and antimony determinations would now enable us to
obtain results sufficiently sharp to show evén the small ditfer-
ences of composition which the substitution in question would
produce.
termined. For this purpose, we used first crystallized SbOCl,
tages. Th
decomposition began between 167° and 175°, but was not com-
ing both stages, chloride of antimony sublimed; and there was
left in the nacelle at the close of the process beautiful crystals
J. P. Cooke—Atomic Weight of Antimony. 117
of Sb,O,. In another experiment, we used crystallized
First stage: 5SbOCI=Sb,0,Cl,+SbCl, ; (1)
Second stage: 3Sb,0,Cl,=5Sb,0,+2SbC1,; (2)
larger sublimate of chloride, we varied the apparatus in our
. third experiment so far as to place the nacelle in a tube of the
shape represented in the accompanying figure. This tube was
weighed with the nacelle, and was so
selected that it quite closely fitted the — SS)
combustion - tube within which it was S Fits, AeA ot
placed for heating, as shown in figure b dotted lines. <And it
is evident that, while with this arrangement the SbCl, would
be swept by the CO, gas into the colder portion of the combuas-
tion-tube, the greater part at least of the sublimed oxide would
be retained in the small tube, which was of course at each stage
wesned with the nacelle, as at first. Our results were as fol-
Ows :—
Weight of SbOCI.- TS UE: 04939 grams,
Loss at 280° _.. 01271 :
Required by theory of reaction 1, if Sb=120_. .0°1305
Total loss at red heat; that is, in both stages .--.0°2179 ©
Required by theory of reactions 1 and 2--.-- -- . .0°2174
It was evident from this determination that the order of the
ecomposition was precisely that indicated by our reactions,
although the end of the first stage was not quite so sharply
marked as the end of the second; and this would naturally be
expected.
showed, when further heated, precisely the same order of phe-
it was plain that the residue left on evaporating the chloride at
a temperature not exceeding 120° was chiefly at least SbOCI ;
but that this when heated more intensely was converted into
118 J. P. Cooke—Atomic Weight of Antimony.
our preparations of chloride of antimony by distilling a weighed
amount from a platinum nacelle at as low a temperature as pos-
sible in a current of dry carbonic acid, and heating the residue
to a temperature of about 275°. We thus obtained the follow-
ing results :-—
No. Wt. of SbCl,. Residue. % of residue Sb,0,Cly.
t, 6°7286 0°0212 0°315
Zs 4°5150 0°0151 0°334
3. 7°9320 0°0258 0°325
In order to yield 0°146 per cent of oxygen, which would
reduce the per cent of chlorine in the preparation from 47-020
to 46-608, as in the scheme on page 116, there would be required
1:155 per cent of Sb,O,Cl,.
Although the results of the above determinations accord
within a few per cent of the quantity estimated, yet it was per-~
fectly clear during the course of theexperiments that they did not
at all represent the total quantity of the oxichloride present in
the preparation examined. Not only was the composition of
the preparation not materially altered by the slow distillation,
—a fact shown by the determinations marked e in the table on
page 47, and by which we were misled at the outset,— but also
the product from our distillation yielded when distilled again
apparently as much residue as before. In a word, we foun
the same phenomena repeated in these distillations at a low tem-
rature which had been so noticeable when the chloride was
danger, and we had taken unusual precautions on both these
points, the explanations suggested did not seem to us sufficient ;
and we came to the conclusion that the oxichloride must distil
over with the chloride of antimony to a certain limited extent,
and that it was only an excess above this definite amount which
was left behind as residue. Of course, SbOCI not only is not
volatile, but is at once decomposed by heat; and we do not
suppose that this compound by the tension of its own vapor is
arried over in distillation. It isa very dilute solution, as it
were, of SbOCl] in SbCl, which thus distils; and the distilla-
tion of the oxichloride may resemble the carrying over ©
J. P. Cooke—Atomic Weight of Antimony. 119
boracie acid by the vapor of water, and similar phenomena, the
result, as it is has always appeared to us, of a feeble kind of
chemical union which has been usually designated by the term
“molecular combination.” Such a theory would account for
the remarkable constancy which we have found in the chlorine
determinations of the various preparations of antimonious chlo-
ride purified by distillation. But, on account of the very great
difficulty of removing all possible disturbing causes, we found
it impossible to obtain a rigid experimental demonstration of
our theory without much more time and labor than we could
then command. We hope to return to the subject hereafter.
Meanwhile, however, it was evident that we could place no reli-
ance whatever on the results just obtained. Nevertheless, the
determinations were of value on account of the contrast
tween these results and those of a similar series of experiments
on the residues from antimonious bromide which we collect in
‘the following table :—
y Residue chiefly
No. Wt. of SbBrs. Sb,0,Bro. % of residue.
if 2°8342 “ 0°035
2, 2°0220 0°0006 0°030
3. 4°6730 0°0010 0°021
As will be seen, this residue is less than one-tenth of that
obtained from the chloride, and is practically insignificant.
_ Evidently, then, in the determination of the atomic weight of
antimony more accurate results may be expected from the anal-
ysis of the bromide than from the analysis of either the chlo-
ride or the iodide of thiselement. The intermediate position of
the bromide renders it, ina very remarkable way, the most
Stable of the three compounds. It absorbs moisture far less
eagerly than the chloride, and it absorbs oxygen far less read-
ily than the iodide, and is thus in great measure protected
against each of these two sources of the same impurity.
_ We come finally to the new analyses of antimonious chlo-
ride we had undertaken. Fortunately, some of the old prepara-
tion that had been distilled so often had been preserved. It
been boiled for along time since the last analyses were
120 J. P. Cooke—Atomic Weight of Antimony.
acts in this way, as we found out in more than one instance to
our cost
Detaits oF AnTIMONY DETERMINATION.
The antimonious chloride was first transferred to a very care-
fully dried weighing tube, and thence to the large flask in
which it was dissolved. ‘he transfer to the weighing tube was
made in a dry atmosphere, and only required two or three sec-
onds. It is evident, however, that a slight absorption of mois-
ture at this point is not important; for, even if it increased the
apparent weight of the assay by several milligrams, it would
only reduce to a barely perceptible extent the percentages of
all the constituents leaving the relative values wholly un-
changed. It is only when, on boiling the chloride, after such
an absorption, the chlorine is driven off, that the essential
change of composition results.
Weight of tube and antimonious chloride --20°9609 grams.
* “ after transfer to flask - - -- -- 16°3920
“+ @hloride analysed. 220520221005. -. 45689 “
The weight of the tube and chloride while on the balance
pan remained invariable for a sufficient length of time to give
positive assurance of the constancy of the weights. The chlo-
ride was dissolved in a saturated solution of tartaric acid con-
taining about 15 grams of the pure acid, and then diluted with
carbonic acid and water and precipitated as before described. »
The precipitate, having been washed and collected as before,
was dried in an air bath, at about 110°. ;
Weight of small filter................ 0°0434 grams.
- porcelain crucible —s0Laiee
101-2566“
2, crucible and precipitate.....104°6762
“ red sulphide of antimony.-.. 34196 “
A portion of the dried precipitate dissolved in hydrochloric
aeid gave no residue. The rest was then transferred to a pla-
J. P. Cooke—Atomie Weight of Antimony. 121
tinum nacelle, and heated, as has been described, in a current
of dry carbonic dioxide gas. No sublimate was formed, and
only a very slight empyreumatic odor could be perceived.
Weight of platinum nacelle ---..2.. 2. 21.22. 6-2493 grams.
= nacelle and dried precipitate -- ------- 95273 “
- portion taken. (2c 2. 2c ci jee! _.8°2780 *
nacelle and precipitate after heating to
285° for over half an hour --..-.-.9°5234 “
Loss of weight of portion taken-...------.-----0°0039 “
Corresponding loss for whole precipitate ---. ---. 00041 “
Weight of red sulphide as above----- .--------- 3°4196 *
Fs gray sulphide. :.. 60. - 43 -5s2 sen $4155
The carbonaceous residue left on dissolving this whole
amount of gray sulphide in hydrochloric acid was barely per-
ceptible. It was collected, however, as usual, on a weighed
paper disk, and estimated.
Weight of small paper filter......-.---.--- ----0°0198 grams.
* Bamé with Tresidte 2 2022 45 220 ce 02127 %
5 tesidueorustiieo hides seer ES ae 00014
Calculated for whole precipitate... .-------- ---- 0°0015 :
Weight of gray sulphide as above...----------- 3°4155
Total weight of gray sulphide. --- 34140 “
Corresponding weight of antimony ditsaad to be
¥ of the sulphide. _.-_..----- -- -- EE ol er
Per cent of antimony in the antimonious chloride
ion .. orate
.
under examinatio
tion, the lower is the more exact. nti
oming next to the chlorine determinations, we noticed, for
rocess, as employed in the analysis of chloride of antimony.
a precipitate of argentic chloride that had been deposited
122 J. P. Cooke—Atomie Weight of Antimony.
from an unusually concentrated solution of antimonious chloride
in tartaric acid, and had stood over night, our attention was
called to some crystalline grains, which, on examination, proved
to be a compound of tartaric acid, antimony and silver. We
soon found that this product could be readily obtained by
concentrating the filtrate from the precipitate of argentic
chloride, and adding to it, while still warm, an excess of
argentic nitrate. On coo ing, the new crystals form in abun-
d hey have not yet been measured, but under the
microscope they have the general aspect of right rhombic plates
or prisms, with hemihedral modifications,—a general form which
is so characteristic of the tartrates, and which we ourselves
have previously studied in our crystallographic determinations
of the tartrates of rubidium and cesium.* We obtained for
the amount of silver in the acca as a mean of three analyses,
26°30 per cent. The compound Ag, SbO.H,=0,=(C,
H,O would require 26°34 ues cent. “The crystals may there-
they appear to have prepared the substance only in an amor-
phous condition. At least, in the description quoted, no men-
tion is made of any crystalline form.
These crystals of argento-antimonious tartrate are apparently
not acted upon in the least by cold water, and only slightly by
boiling water; and finding this on insoluble material mixed
with the precipitated chloride of silver, under the conditions
stated, we were led to fear that “ft might be occluded to some
extent by this precipitate, even when formed in much more
dilute solutions of antimony and tartaric acid. The phenom-
non was very similar to that we had already studied in the
occlusion of the oxichloride by the sulphide of antimony; and
there was reason to fear that, as in the previous case, an occlu-
sion of this double tartrate might canis even when the ale
t, s] aby tated, w
had always taken great care not to add more than the slightest
possible excess of sapie i sikinta, and this was especially true
in our more recent determinations. Now, however, we were
* Am. Jour. of Science and Arts, II, xxxvii, 70.
+ Gmelin Handbook, Cavendish Edition, x, 326.
J. P. Cooke—Atomic Weight of Antumony. 123
on our guard, and in the following determinations very great
pains were taken to add just the requisite amount of the silver
salt, and the argentic chloride was subsequently examined for
traces of any such occlusion. But, excepting this close atten-
tion to well-known precautions, the determinations were made
in the same way as before.
ANALYsIS OF ANTIMONIOUS CHLORIDE.
No. Wt. of SbOl,. Wt. of AgCl. % of Chlorine.
Ey 22220 4°1682 46°407
2; 1°9458 3°6512 46°420
Mean value She 46438
calculating what would be the composition of a preparation of
antimonious chloride in which ;,'%, of a per cent. of oxygen
had replaced an equivalent amount of chlorine, assuming, of -
course, Sb = 120 an = 35°5,—-we obtain the following very
striking accordance :—
Analysis. Sb = 120, Gl = 35°5
Ghlotine: «ce. dc ke 46°413
4ygen a Rs 213
Antimony eRe ee ig ee | 53°369
100°000 * 1007000
The general conclusions, then, which we deduce as the
results of this investigation, are—
First, that the value of the atomic weight of antimony found
by Schneider in 1856—Sb=120 3—must be accurate within a
few tenths of a unit, but that the most probable value of this
.-. as deduced from our experiments, is Sb=120, when
Secondly, that the apparent disagreement with this result,
presented by the partial analyses of antimonious chlori e, is
probably due to the constant presence of oxichloride in the
preparations of this compound.
The investigation from the first: has been a study of constant
124. S W. Ford—Two new species of Primordial Fossils.
whose influence we have been able to trace, although we have
not been able to define them as clearly as we could desire, it
would be presumptuous in us to express too great confidence
either in the correctness of our theories or even in the conclu-
siveness of our experimental results. Of this, however, we feel
assured, that more trustworthy results cannot be expected from
a repetition of the same processes until a more complete and
accurate knowledge has been acquired of the substances em-
ployed. We have therefore proposed to ourselves a more
thorough investigation of the haloid compounds of antimony,
and the first results of this investigation we shall shortly pub-
lish. After the requisite data have been thus collected, we
hope to return to the old problem with such definite knowledge
of the relations involved as will enable us to obtain at once
more sharp and decisive results than are now possible.
During the course of this investigation, we have been suc-
cessively aided in the experimental work by Dr. F. A. Gooch,
- Mr. GC. Richardson and Mr. W-H. Melville, at the time students
in this laboratory; and without their assistance we could not
have accomplished the great amount of labor it involved.
Harvard College Laboratory, June 12th, 1877.
Arr. XVI.—Descriptions of two new species of Primordial Fos-
sils; by S. W. Forp.
places, and are seen to be thin and delicate. The outer wall
has been almost wholly removed and the portions of it that re-
main are much weathered. The material presented for study
consists, therefore, of the solid moulds of the interseptal spaces,
the cup filled with limestone, a small number of the septa, @
. * This Journal, March, 1873.
S. W. Ford—Two new species of Primordial Fossils. 125
transverse section of the inner wall and the impression of a
considerable portion of the outer wall. The latter shows that
the external surface when perfect was longitudinally furrowed
as in Archeocyathellus. In that genus, however, so far as
known, there are two rows of pores along each of the furrows,
one on either side of the septa; whereas, in the present genus
there appears to have been but one, and that placed
directly on the line of the septa. The evidence of this
consists of rudely circular holes placed at regular intervals
along the middle of each furrow in the cast. ese ap-
pear to me to argue the existence of funnel-like projections
mward of.the outer wall at the place of the openin t
they mark the position of orifices leading into the interior ap-
ears to me in the highest degree probable. Their position is,
owever, so remarkable, that I was for a long time unable to
understand the meaning of them.
On one side of the specimen there are a small number of the
interseptal moulds that project beyond the others and one of
these shows one of its lateral faces for a considerable distance
lengthwise, and also nearly down to the outer surface of the
inner wall. An examination of this face shows that the cavi-
ties observed along the furrows extend but
a short distance inward, and that the septa
arched around the funnel-like projections which
they represent from below, striking the outer
wall only at the intervening spaces (the spaces
between the dots in the figure). It is further
shown that these cavities are directed slightly
the orifices were proportionally considerably larger than those
ies of Are ellus (A. Rensselaert-
cus), while their position is such as to present no obstacle in
the way of regarding them as having communicated simulta-
neously with two of the interseptal spaces. —
The fossils of this group have, in their septate structure
* Fig. la.—A few of the interseptal moulds of Protocyathus rarus enlarged to
show the position of the suppest external orifices; 6, enlarged outline of a lat-
eral face of one of the moulds designed to show the direction of the cavities c, c.
126 S. W. Ford—Two new species of Primordial Fossils.
much the appearance of corals; but the peculiar poriferous
structure known to characterize a good typical species, the uni-
form presence of a large walled central cavity, and the exist-
ence in one species Ea ab Minganensis) of branched
spicule would seem t y them more nearly to the spon
By the late lamented Mr. Billings, to whom we owe our first
knowledge of these singular forms, and who has discussed their
affinities at considerable length, they were classed provisionally
with the sponges; but in conclusion he remarks that ‘The re-
semblance between the whole structure and that of the paleozoic
corals seems also to show that in the Lower Silurian seas forms
— combining the characters of the Protozoa and the Ce-
lenterata.”* The existence of such forms in our older deposits
is a ais of much interest, and it is to be hoped that contin-
ued researches will add still further to our knowledge of them.
This species occurs in conglomerate-limestone of the Lower
Potsdam group at Troy, N. Y.
Solenopleura nana, sp. nov.—Of this species I havea num-
ber of specimens of the head, but they are all more or less im-
perfect. The largest and best preserved specimen consists of a
nearly perfect glabella and the greater portion of the fixed
cheeks, and is but two lines in length. The glabella is nearly
four-fifths the total length of the head and is especially charac-
terized by its great relief. It is obtusely conical, slightly
widest ome and is well defined all around by the dorsal fur-
ws. a specimen two lines in length its highest point is
nearly one and one-half lines above the base of the fix
cheeks. It is marked on either side by two or three faint fur-
rows. The fixed cheeks are notably convex, but their relief
does not exceed one-third of that of the glabella. The eyes
lar fillet. The dintance from the. eye to ‘the glabella is
nearly equal to the width of the glabella at - mid length.
The front margin is narrow and is bounded by a feebly convex
rim, inside of which there is a narrow furrow hich gradually
deepens on either side of the median line in passing outwart
Between this furrow and the glabella there is a somewhat angu-
lar ridge which widens in passing outward to the sutures.
The course of the facial suture is nearly the same with that
of Solenopleura brachymetopa of Angelin (Paleontologia Scan-
dinavica, Pl. xix, fig. 1), but is directed slightly more inward
in front of the eye. The neck-furrow is continuous all across.
The exact form of the neck-segment cannot made out,
owing to the damaged condition of all of the sections at this
point. It is seen, however, to be less elevated than in the ma-
* Pal. Boss., vol: i, p. 357.
S. W. Ford—Note on Lingulella celata. 127
jority of the species, not rising above the surface of the fixed
eks. The entire surface is covered witha fine regular gran-
ulation.
This species is the second one of the genus, so far as I am
aware, that has been described from American rocks, the first
one having been obtained from strata of the Acadian epoch
in Newfoundland and described by Mr. Billings. It occurs in
both even-bedded and conglomerate limestone of the Lower
otsdam group at Troy, N. Y., associated with Olenellus, Cono-
coryphe and Microdiscus. It is principally interesting on account
of its affording another generic link between the already
closely related faunz of the Acadian and Lower Potsdam.
New York, Oct. 13th, 1877.
Art. XVIL—Note on Lingulella celata ; by S. W. Forp.
THE above mentioned species, occurring in the Troy Pri-
mordial, has hitherto been set down by me as an Obviella, but
the evidence now in hand shows tbat it should be referred to
the genus Lingulella of Salter. The following are the principal
characters :
The ventral valve is somewhat elongate-ovate, with the beak
pointed, slightly elevated and conspicuously channeled for the
peeeee of the pedicle. The convexity is moderate and nearly
position the large lateral scars of the ventral valve of certain
species of Obolelia (e. g., O. chromatica.) The other impressions
of this valve have not been made out.
The dorsal valve is more rotund than the ventral and has the
beak much depressed. The convexity increases with increas-
ing age, and in adult specimens is such as to sometimes give
the valve a semi-globose appearance. A shallow depression
extends in all the specimens from the beak to the front margin,
but in fully grown forms it is often inconspicuous. On the
inside there are four prominent ridges. Of these the more cen-
tral twocommence close to the median line a short distance in —
front of the beak and extend into the forward third of the
shell slightly diverging throughout, while the lateral pair take
their rise close to the beak and reach to points a little in ad-
vance of the mid-length. There is also a short slender ridge
directly beneath the beak on the median line. The central por-
tion of the valve in the upper half is slightly excavated. The
description of the interior of this valve has been mainly drawn
up from an excellent natural internal moul
128 S. W. Ford—Note on Lingulella celata.
The surface of both valves is ornamented with moderately
conspicuous radiating and concentric lines, the latter irregularly
series alternating with those of the next, and so on, as first
pointed out by Professor Hall in his description of the dorsal
valve (Pal. N. Y., vol. i, p. 290, pl. 79, fig. 9). The effect of this
style of ornamentation is very beautiful ; and when, as is usu-
ally the case, the shells have a dark, polished aspect, with a
setting of light-colored limestone, few handsomer fossil objects
can be named. The shell is thick and of a finely lamellar
structure. The usual length of the ventral valve is about
three and one-half lines.
This is one of the best marked fossils of the Troy Primor-
dial and may be easily identified by means of very small frag-
meuts.
The species known as Obolella crassa of the Troy beds may
also be briefly noticed in this connection. It includes the
species already widely known under the name of O. desquamata
from the same locality, this latter, as may be shown, having been
founded upon the dorsal valve of the former. The ventral valve
is always more acutely pointed at the beak than the dorsal, but
beyond this feature there is nothing, so far as I have been able
to discover, by which they may be distinguished from each
other externally. The surface of each, when perfect, is both
radiately and concentrically striated. As a rule, however, the
imbricating edges of the successive layers of growth are the
only markings visible. :
f the interior of the ventral valve an excellent figure was
given by Mr. Billings on page 355 of this Journal for May, 1872;
but the interior markings of the dorsal valve have nowhere, to
my knowledge, yet been accurately shown. The scars are nearly
the same with those of the dorsal valve of 0. chromatica,* but
the smaller pair close to the beak are here, in the majority of
cases, distinctly connected with the larger pair directly beneath
them ; while the central pair, instead of running parallel with
each other throughout, diverge at the mid-length of the valve,
and extend onward in slender falcate forms into the anterior
fourth of the shell. Their parallel portions are, however, the
. only parts usually seen, and it was only after collecting the
species for a number of years that I obtained evidence that
what had come to be looked upon as wholes were, in reality,
only parts of much more extensive impressions.
The species of Brachiopoda at present known to me from
the Troy Primordial are the following: Obolella crassa, O. gem-
*“On the structure of Obolella chromatica,” by E. Billings, F.G.S. This
Journal, March, 1876. :
S. W. Ford—Development of Olenellus asaphoides. 129
ma* (Billings sp., or a species which I am unable to distinguish
from this form by any good characters), O. nitida, Lingulella
celata, and asmall species of Orthis yet undescribed. This latter
species is about one-third smaller than Orthis Billingsi of the
Acadian groupt which it otherwise much resembles, except
that the ribs do not dichotomize as in that species. None o
the specimens yet obtained are sufficiently perfect to admit of
a full description.
New York, Oct. 31st, 1877.
Art, XVIIL—WNote on the Development of Olenellus asaphoides ;
by S. W. Forp.
SINCE the publication of my paper giving an account of the
metamorphoses of this remarkable trilobite,t I have obtained
at Troy a number of specimens further illustrating and confirm-
ing the fact of the metamorphoses. Among the more impor-
tant of these is a beautifully preserved cephalic shield showing
the manner in which the appendages that I have called the
inter-ocular spines were finally lost. As this specimen supplies
one of the most important links in the demonstration and ully
confirms what was inferred from the structure of previously
known specimens representing other phases of the development,
the more interesting features which it presents may be briefly
noticed at this time. :
he specimen in question is almost exactly intermediate
between the forms represented by figures 3 and 4 of my former
paper. Excepting the neck-furrow and the second pair of fur-
rows in advance, none of the glabellar furrows reach the median
line; while the inter-ocular spines, still further reduced in size,
are seen to be entirely cut off from the swollen spaces between
the eye-lobes and glabella, by the furrows immediately within
the eye-lobes extending completely across them, and uniting
with the marginal furrows. There can be scarcely a doubt but
that the next moult would result in a bead destitute of these
appendages, as in fact, we find the forms next in order of in-
creasing size to be. The dwarfed proportions of the appendages
lead also to the conclusion that they are examples of atrophied
Organs, as has likewise been suggested to me by M. Barrande.
I know of no instance of this—the suppression of spinous
* This Journal, Ma:
me ? iV, 187 . 355.
{ Acadian Geol., Tigaee 1868, p. 644. Also Dana, Man. of Geol., 1874, p,
130 = S. W. Ford—Development of Olenellus asaphoides.
appendages beyond the contour—in any other species of
trilobite.
The surface of the cheeks in the specimen under wipiig is
beautifully ornamented with fine, waved, radiating lines as
the adult.
I may also add, that several of the different stages of growth
observed are shown to be represented by two distinct forms,
respectively a long and a broad form. The same thing has
been stated by Barrande for a large number of Bohemian
species. Some of the ~~ forms were very diminutive, the
smallest specimen now in my possession being one-third smaller
than the smallest axiniple yet illustrated. I have also observed
oe specimen the width of which did not exceed ;',th of an
neh
.
eee York, December 10th, 1877.
* Neither the small trilobite scorers ph a a by G. Linnarsson under the n
of Paradoxides aculeatus isha ransaction e Geol. Soc. of Stockholm for 1877, | ‘
aaa nor the Hage previously de ribo s as Paradoxides Kjerulfi by J. G. O. Lin-
on furnish, in ilobi
n roof of
oumgeat in their structure, a generic identity with Olenellus asaphoides. Moreover,
I greatly question ‘whether the two Swedish species above mentioned are truly
—_——_ i 0 i oly
mn
There is nothing, to my mind, in the structure of the specimens figured. to ead to a
comparison of the posterior spines of P_aculeatus wtth the smaller pair of P. Kjerulji.
In regard to Mr. Linnarsson’s somewhat extended, but, as it appears to me, too
sa
reason to change any o of the statements Seer in my former paper. hatever
L son’s P% le ove to be, I fid spiaiert
that Olenellus a is et a true Par Wheat the development of some
species of Paradoxides shall have been any on (if, indeed, any of the species ever
sustained gee we shall probably , able to satisfy ourselve os more fully upon
this point. The smaller spines of the posterior margin of P. mag — :
a ece n with the in cathe tects cakes and G. Li
was the first to perceive this; but at present I think it axeeey doubtful wbeaiae
they can be properly regarded as homologous. ‘This will become the ache ge
¢ i is
4 and
it may, the relations of the two genera are manifestly very close, and the Sw
beds fortunately promise to contribute and toward working them out to com-
leteness. Mr. Linnarsson considers peg ar and
. aculeatus, one example of which he owe figures, an picheginka form of t 7 same
— but finding that the forms of my young not his
e thinks my account most probably deeply in fault. Were his conclusions
and ame, 8 portray: yep by a better array of facts drawn from his own speci
field of observation they pen possess greater fitness and value.
hated ie
Johnson and Chittenden—New Acid Ammonium Sulphates. 181
Art, XIX.—On Schweitzer’s “New Acid Ammonium Sulphates ra
by S. W. Jounson and R. H. Cuirrenpen. Contributions
from the Sheffield Laboratory of Yale College. No. Ll.
Dr. Paul Schweitzer, in a paper “On some New Acid Am-
monium Sulphates, read before the American Chemical Society,
July 6, 1876,* has given the results of some partial analyses of
residues remaining after subjecting ammonium sulphate to
several degrees of ignition, and has inferred: 1. That exposure
to a heat a little higher than that of the boiling point of mer-
cury converts ammonium sulphate into ammonium bisulphate
with loss of one-half of its ammonia. 2. That a temperature
somewhat below incipient redness occasions further loss of
ammonia and sulphuric acid and leaves a salt of the formula
(NH,),H,(SO,),. 3. That probably an intermediate salt is
formed having the formula (NH,),H,(SO,),
These conclusions are based on the fact that the residues of
ignition at the temperatures named yield such percentages of
SO, as the above formule require. We have repeated most
of Dr. Schweitzer’s experiments, and so far as we have gone,
have fully verified his observations. The formule which he
deduces from his estimations of SO, are, however, inconsistent
with the usually received atom-fixin wers of the elements
involved, and we have made further investigation of the sub-
stances to which he has called attention, in order to ascertain
whether they are really exceptions to the laws of valence, and
therefore possibly serviceable means of enlarging our generaliza-
tions, or have a composition different from that which Dr,
Schweitzer has inferred.
and after fifteen minutes further igpinan “ted aap a =
. urther heating at the same
as the ignition is prolonged. second sample gave in the
ee
+ Made Pedigrees rg. —*, akc } onium carbonate, and analyzed
With following results :
Found, Calculated.
60°70 60°60
go
(NH,),0 39°28 39°39
182 Johnson and Chittenden—New Acid Ammonium Sulphaies.
first analysis 68°95 per cent and after a second ignition 69°41
per cent To make the analyses more complete, ammonia
was estimated in both samples by distillation with sodium hy-
droxide, and in the second sample hydrogen was determined by
combustion with lead chromate and metallic copper and found
to be 4°67 per cent.
the basis of the ammonia estimation we have the follow-
ing statement.
Found. Found. Calculated for
z 2. pisulphate.
SO 70°08 69°41 69°56
NH, 17°00 17°08 14°78
Difference 12°92 13°51 H,O 15°66
100°00 100°00 100°00
The ultimate composition, reckoning oxygen by difference,
is——
Found. Found. Calculated for
i: 2. bisulphate.
Ss 28°01 27°76 Ziec
oO 53°49 55°65
N 14°01 14°08 1217
H 4°34
100°00 99°98
On dissolving in water the solution has an acid reaction,
addition of strong alcohol to the saturated solution throws
down a crystalline precipitate which is normal ammonium sul-
phate and yielded in the results of two successive determinations
25 r cent and 25°65 per cent of 3. Theory requires
The analyzed substance compared with the salts just named
in respect to atomic ratios gives the following results, eight
atoms of sulphur being assumed in each case for convenience.
Normal
Seweitzer’s 1st
sulphate. Bisulphate. Pyrosulphate. substance.
oe 8 8
N=16 8 12 9°3
H=s4 40 26 43
O==32 32 24 30°8
Inspection of the above figures makes evident that the ana-
lyzed substance must contain besides normal sulphate, a cer-
Johnson and Chittenden—New Acid Ammonium Sulphates. 188
tain proportion of bisulphate in order to bring down the
nitrogen below twelve and also some pyrosulphate to reduce
the oxygen below thirty-two.
Calculation shows, in fact, that the substance is a mixture
of nearly one molecule of pyrosulphate (NH,),S,0,, one
molecule of sulphate, (NH,),SO,, and three molecules of bi-
sulphate 3(NH,HSO,). Such a mixture would have the fol-
lowing empirical expression: S,0,,N, H,, and its centesimal
composition compares closely with our analyses.
Calculated. Found.
i;
6S 27°86 28°01 27°76
230 53°41 53°49
IN 14°22 14°01 14°08
31H 4°50 67
99°99 100°00
Our examination of the so-called “ biammonium tetrahydrogen
sulphate” obtained by subjecting ammonium sulphate to near
incipient redness demonstrates that it also is a mixture. Th
facts given by Professor Schweitzer agree substantially with
those observed by us.
e found in the residue after two successive heatings
54 and
zer's formule, but indicate that the substance is very
nearly a mixture of two molecules of ammonium bisulphate
(NH,)HSO, with one molecule of pyrosulphate (NH,),5,0,.
Such a mixture is represented empirically by S,0,,N,H,,.
The percentages required by it and those found in our analyses
are subjoined.
Found.
Calculated. ome = 2. 3.
48 28°96 29°05 29°01 28°81
150 54°29 53°85 53°78
4N 12°67 12°94 12°94 12-96
8H 4°07 4°16 4°
On adding a little aleohol (98 ad cent) and agitating, oily-
appearing drops separated, whic
134 Johnson and Chittenden—New Acid Ammonium Sulphates.
crystals formed. These B were separated and dried at 100 C.
These crystals proved to be normal ammonium sulphate.
They yielded by analysis—
A B Calculated.
(NH,),. 39°33 39°46 39°39
The alcoholic mother-liquor was evaporated on the water-
bath and left a small fluid residue, which on cooling deposited
a few crystals, apparently of normal sulphate. The few drops
of liquid remaining were intensely acid and had all the char-
acters of sulphuric acid discolored by organic matters. Treat-
ment with aqueous alcohol thus resolves both the bisulphate
(two molecules) and the pyrosulphate into normal sulphate and
sulphuric acid, or in part probably into sulphethylic acid.
In the first stage of the decomposition of ammonium sul-
phate at a temperature “a little higher than the boiling point of .
mercury” the vapors are alkaline. The chemical change would
appear to involve six molecules of the sulphate, which lose five
molecules of ammonia gas and one molecule of water vapor,
leaving as solid residue a mixture of one molecule of unchanged
sulphate, one of pyrosulphate and three of bisulphate.
a a le rir! Opal
(NH,).S,0,-+(NH,).50,
In these changes two molecules of sulphate yield one mole-
cule of pyrosulphate with loss of one water- and two ammonia-
molecules,* while three molecules of sulphate yield, each, a
molecule of bisulphate, with loss of a molecule of ammonia,t
and the sixth molecule of sulphate comes out unaltered.
In the second stage of heating (near incipient redness) the
fumes are at first alkaline, but shortly become acid, and con-
tinued so as long as that temperature is maintained.
The changes are empirically expressed as follows:
S,0,,N,H,,—[280,+2H,0+3NH,]=S,0,,N.Hie,
or rationally—
[3(NH,HSO,)+(NH,).S,0, + (NH,),S0,] —[2S0,+2H,0+
3NH, |=2(NH,HSO,)+(NH,).8,0,.
The rise of temperature from 350° to 520° C. appears not to
alter the pyrosulphate and bisulphate, but the chemical change
to result from a molecule of sulphate reacting on a mole-
cule of bisulphate, whereby both are decomposed, thus—
NH,HSO,+(NH,),80,=280,4+2H,0+3NH,.
It would be interesting to study the reactions at other
tem peratures.
ONH.
80s<oxn* 80, / ONH,
* NE, gs 0+2NH,]=<, >0
ONH. ? 3+" S80,
SO.< : ~ONH,
+ 380,<0N Ht —3NH,=380:<On-
S. Watson—Poplars of North America. 1385
Art. XX.—The Poplars of North America; by SERENO
WATSON.
THE following incomplete synopsis of the species of Populus
is based upon the material in several of our principal herbaria,
and is published for the purpose of drawing the attention o
botanists during the coming season to this still very imperfectly
known genus. Flowers and fruit even of the common species
are too rare in collections, and are much needed for their satis-
factory definition.
§ 1. Styles two, with two or three narrow or filiform lobes:
capsules small, thin, oblong-conical, two-valved: seeds very
small: leaves ovate.
* Petioles flattened: bracts silky: stamens six to twenty.
1. P. tremuloides Michx. 2. P. grandidentata Michx.
** Petioles terete: bracts not silky: stamens twelve to sixty.
3. P. heterophylla L.
. Styles two to four, with dilated lobes: capsules large,
often thick, subglobose to ovate-oblong, two to four-valved :
bracts mostly glabrous.
* Leaves cordate or ovate to lanceolate, crenate; petioles
terete: stamens twelve to thirty: seed a line lon
4. P. balsamifera L. Leaves whiter beneath, ovate-lanceo-
late, acuminate, glabrous ; petioles one-half to two inches long,
thombie-ovate to narrowly lanceolate, mostly cuneate at base,
often small ; petioles one-half inch long or less (rarely one
136 S. Watson—Poplars of North America.
and extensively planted in Utah, but the wood considered
worthless,
+t t Capsule tomentose, three-valved.
6. P. trichocarpa Torr. and Gray. Leaves broadly ovate,
acuminate, cordate, often whiter beneath with age, puberulent
when young; petioles one or two inches long: rhachis pubes-
villous: pedicels a line or two long.—S. California to W.
Nevada and British Columbia.
* * Leaves deltoid, sinuate-crenate ; petioles flattened: sta-
mens sixty or more: seed one and one-half or two lines long:
capsule three or four-valved : rhachis and disk glabrous.
7. P. monilifera Ait. Leaves with numerous serratures and
narrow very acute acumination, broadly truncate-deltoid, some-
times ovate, rarely cordate; petioles two to four inches long:
ament usually long (two to seven inches): disk rarely two
lines broad: capsules rather thin, oblong-ovate, four or five
lines long, on slender pedicels one to five lines long.—New
England to Florida, Louisiana,-and the base of the Rocky
Mountains in Colorado and Wyoming. Most flowering and
fruiting specimens seen from east of the Mississippi have four,
rarely three, distinct styles and a four-valved capsule; a single
a peltate stigma, and the capsule three-valved. The more
western specimens have all three distinct styles and a three-
valved capsule. ere are no apparent differences otherwise,
and it remains to be seen whether these forms can be specilic-
t
P. Fremonti Watson. Leaves with few serratures (four
ad aeute
lines broad, and pedicels eight to ten lines long: pistillate
a ree ur inches long: disk three lines broad: cap-
sules ovate, thick-coriaceous, three-valved, on stout pedicels two
(two to six inches long), the disk two or three lines broad, and
the somewhat angled capsules three- or usually four-valved, on
slender pedicels two to eight lines long.—The phat form
from N. California to S. Utah; the variety from S. California
to the Rio Grande. 3
- ze ip
Chemistry and Physics. 187
SCIENTIFIC INTELLIGENCE.
I. CHEMISTRY AND PHysIcs.
1, Liquefaction of Oxygen ;* by M. Raovut Picret.—The ob-
ject which I have had in view for more than three years is to
demonstrate experimentally that molecular cohesion js a general
property of bodies, to which there is no exception.
the permanent gases are not capable of liquefying, we must
conclude that their constituent particles do not attract each other,
and thus do not conform to this law.
Thus, to cause experimentally the molecules of a gas to approach
each other as much as possible, certain indispensable conditions
are necessary, which may be expressed thus :—
(1.) To have the gas absolutely pure, with no trace of foreign gas.
ts} To be able to obtain extremely energetic pressures.
3.) To obtain intense cold, and to subtract heat at these low
temperatures,
(4.) To utilise a large surface for condensation at these low tem-
peratures,
(5.) To be able to utilise the rapid expansion of the gas from
extreme condensation to the atmosphere pressure—an expansion
which, added to the preceding means, will compel liquefaction.
Having fulfilled these five conditions, we may formulate the
oa alternative :—
e
Satisfy these different conditions, and I have chosen the compli-
cated apparatus of which the following 1s a brief description :—
» ing E
Couple these pumps in such a way that the exhaustion of one
Corresponds to the compression of the other. The exhaustion °
the first communicates with a tube (R) of 1°1 metres long and 12°
138 Scientific Intelligence.
centimeters in diameter, nig filled with liquid sulphurous acid.
Under the influence of a good vacuum the temperature of this
so rapidly sinks to —65°, and even to —73°, the extreme limit
SThioegh this tube of eke as acid passes a second smaller
tube (s), of six pigeon diameter, and the same length as the
envelope. These two tubes are lonil by a common base.
In the central pre is retained compressed sarionls acid pro-
duced by the reaction of hydrochloric acid on Carrara marble.
This gas, being dried, is stored in an oil gasometer (@) of one
cubic meter capacity.
t a pressure of from four to six oe oo carbonic acid
easily liquefies under these circumstance The resulting liquid
is led into a long — tube (B), four cma in jength and four
ne more in diamete
o pumps, P pes ae , coupled together like the first, exhaust
dartonls acid either fro om ‘the penn? (c) or from the long tube
lowest obtainable temperature. These two long tubes are con-
nected by the ends of the carbonic ate tube, consequently oo
ore tube extends about one meter beyond the other. I hav
rved this portion downward and given the two long tubes .
slightly inclined position, but still very near the horizontal, as I
have shown in the accompanyin wee
cine small central tube is curved at a, and screws into the neck
howitzer shell, c, the ane “of which are thirty-five
pailinietans thick ; the height is is ee centimeters, and the
the
up, and introduced into the shell perfectly dry. When the double
circulation of the sulphurous and carbonic acids has lowered the
Chemistry and Physics. 139
DESCRIPTIONS OF THE DRAWINGS.
4. A tu meters | 14 millimeters external diameter, and 4 millim
Wioenat P Bence in hic the o vane 5 condenses. It is furnished we é a
w-tap, 7, from which the liquid oxygen jets out. Ap’ gauge, M,
measures the pressure up to 800 atmospheres.
B.A fade: 4 + meters long, .; which is solid carbonic acid. The stock of carbonic
acid i ined in a gaso cymes G, of 1 cubic cir gh capaci es three-way
tap, , nate it when desired in munication with the appara :
ri shell : f chlorate of potash mixed with
ng age potassium. It is heated with gas. : crn ee
the tube B or the gasometer G, according to the position of the,
8. A tube, 60 anillinaeters diameter and 1°] meter long, in which is condensed the
the pumps. This liquefied gas returns by
gr sue 125 ie Pence " diameter and 1-1 meters long, containing liquid
acid.
oa P,. Doubleaction exhaustion and force pumps, exhausting sulphurous acid
the tube rR.
Q. A tubular condenser of sulph compressed by the pumps. This body,
ar na returns by the smal Es the tube R. The cold water for
acid passes through the apertures E E.
ic acid caused by the suction of the pumps.
140 Scientific Intelligence.
fo giisg eine . the — depres, I heat the shell over a series
of gas-burn The decomposition of the chlorate of potas
takes place a “first ceieniy, iad rather suddenly towards the
end of the vperation. A pressure-gauge, M, at the extremity of
a long tube, lets me constantly observe the pressure and the pro-
gress of the reaction. This gauge is graduated to 800 atmos-
pheres, and was made for me expressly by Bourdon, of Paris.
hen the reaction is terminated the pressure exceeds 500
atmospheres; but it almost immediately sinks a ase and stops
at 320 atmospheres. If at this moment I open the screw-tap, 7,
which terminates the tube, a jet of liquid is distinotly ae seen to 0 spirt
out with extreme violence. I close the tap, and in the course of a
few moments a second jet—less abundant, however—can be ob-
tained.
Pieces of charcoal, slightly incandescent, put in this jet —_
spontaneously with inconceivable violence. have not yet s
ittle of this liquid.
ee ot I repeated this experiment before the majority of the
mbers of our Physical gone moat e had three successive
Z
posal, worked by a steam-engine.
Geneva, December 25, 1877.
en—among
expressly to assist at ehis important experim
At 10 o’clock in the evening the m nanieeater, which had risen to
560 atmos —- a few ssinutes to 505, and remained
this diminution in the pressure that part of the gas had assumed
the liquid form under the fattaanes of the 140 degrees of cold to
which it was exposed. The tap closing the orifice of the reve was
then — and a jet of oxygen spirted out with extraordinary
violence
A ray of electric light being thrown on the sae’ 2 showed
that it was chiefly composed of two parts ;—one central, and some
centimeters long, the whiteness of which showed that the element
was liquid, or even solid; the other exterior, the blue tint of
Chemistry and Physics. 141
which indicated the presence of oxygen compressed and frozen in
the gaseous state.
The success of this remarkable and conclusive experiment called
forth the applause of all present.
We understand that Messrs. Pictet & Co., of 22, Rue de Gram-
mont, Paris, are fitting up apparatus with the intention of having
these experiments repeated at their Freezing-Machine Works, at
Clichy, in Paris.— Chemical News, . 4.
‘ Liquefaction of Oxygen, Nitrogen and Hydrogen.
Experiments of M. Cailletet. (From Nature, of January 3d
of 300 atmospheres and at a temperature 0 This result
was ommunicated to the Acade at t was con-
signed to a sealed packet on account of M. Cailletet being then a
candidate for a seat in the Section of Mineralog ence, then,
credited to both, on the ground that the researches of each were
absolutely independent, both pursuing the same object, creating
compressed. The remainder of the space in the large cylinder is
occupied by mercury. M. Cailletet’s process consists in com-
Was at once formed. The same result has since been obtained
Without the employment of sulphurous acid, by giving the gas
time to cool after compression.
142 Screntific Intelligence.
MM. Pictet has done; on being separated from its enormous pres-
sure it has merely put on on the — of a cloud.
M. Cailletet first introduced pure nitrogen gas into the appa-
ratus, Undera pressure of 200 atmospheres the tube was opened,
and a number of drops of liquid nitrogen were formed. Hydro-
n was hext experimented with, and this, the lightest and most
difficult, of all gases, was 8 reduce to the form of a mist at 280
present at the experiment estimated it at —300
Although oxygen and nitrogen h ad both been liquefied, it was
deemed of interest to carry out the process with air, and t
eo was filled with the latter, carefully dried and freed from
carbonic acid. The xp yielded the same
3. On the Lie Soctiee ‘of Acetylene, Ethyl hydride, Nitrogen
dioxide and ly Mars. AILLETET, studying the com-
pressibility ot acetylene, seeds a amarked departure from the law
f Mariotte in its behavior, and, pushing the condensation still
further, succeeded in liquefying it. The apparatus consisted of a
ac a i the temperature bei ais gens tans 1
seen to form and run down the walls of the tube, under a pre
of eighty-three atmospheres. R the pressure gradually,
ragerelty a pears to hl refractive, and is lighter than water
which ais soluble Eas | proportions. It dissolves paraffin
and fats. Cooled to zero in presence of water and linseed oil, it
forms a white compound like snow, which decomposes on heating
or lowering the pressure. The tension of the acetylene vapor
is as follows: at +1°, 48 pera sar at 2°5, 50; at 10,
63; at 18°, 83; at 25°, 94; at 31° Com omparing t the tensions
of acetylene, ethylene, and ethyl i (C,H,) which con-
tain in equal volumes, equal weights ts of carbon united to increas-
ing quantities of hydrogen in the ratio 1:2: 3, the author finds
the tension of acetelyne at 1°, as above, to be "forty-four atmo-
spheres ; that of ethylene at 0° according to Semen: being forty-
six atmospheres, and that of ethylene hydride—now liquefied for
Chemistry and Physics. 143
the first time by Cailletet—at 4° being forty-six atmospheres, its
liquefaction taking place at a pressure a little less than that of
acetyle
e.
a subsequent paper, CAILLETET announces the liquefaction of
nitrogen dioxide, by a pressure of 104 atmospheres at —11°. At
> Rha ae Bigg
u
and so remained up to a hei ht of four or five centimeters, Teach-
ing 650° at the height of six centimeters. Mixtures of air and
Sid in a Bunsen burner closed below, and the
temperature measured in the hottest part of the flame. For one
one volume of gas and three of air, 1116° ith four volumes
of air the mixture would no longer burn in a Bu ;
and burned from a at-wing burner gav mapera-
and one-half CO,, a temperature of 1000°; one volume gas and
two of CO, gave 860°; moe with three of CO, 780°. With four
Hommes CO,, the mixture burned only in contact with a flame.—
az. Chim. Ital., vii, 422, Sept. 1877. 2, 2 Sa
5. On the nciple of Maximum Work, as illustrated by the
Spontaneous decomposition of Barium perhydrate.—As & funda-
144 Scientific Intelligence.
mental deduction from his thermochemical researches, BERTHELOT
proved long ago the tendency of chemical systems toward that
composition which corresponds to the maximum evolution of heat.
He now notes an excellent illustration of this law in the case of
barium perhydrate, which decomposes spontaneously, while
barium peroxide is permanent. A specimen of BaO, prepared
in 1874 contained 9:4 oxygen in excess, and in 1877, 9°2 of this
oxygen; showing its permanence. The hydrate however, BaO,
(H,O),, prepared pure and kept moist, gradually decomposes,
gas bubbles of oxygen developing in the mass, generating a pres-
sure in the vessel, and forming a crystalline mass o
hydrate BaO, (H,O),,. This decomposition is even more rapid
under water. A specimen prepared in 1874 and kept moist, had
spontaneous decomposition of barium perhydrate is not to be
found in any symbolic considerations, drawn from a figurative
arrangement of atoms; but is explained by very simple and very
obvious principles, resulting from the regular action of molecular
mechanics,”— Bull. Soc. Ch., I, xxviii, 502, Dec. 1877. G. F. B.
6. On the Hydrocarbon called Idryl.—Gotpscumiept has sub-
ul was the alcoholic extract of the chamber deposit, and fused
from 75° to 86°. By solution in alcohol, difficultly soluble flocks
were observed which were filtered off and marked A. They fused
at about 200°. From the filtrate, or from the more fusible por-
dissolved in aleohol and mixed with a
solution of picric acid. Red crystalline precipitates were thus
nt. On concentration, additional picrate was obtained but
ighter in color as it was more soluble. The portions having
Chemistry and Physics. 145
nearly the same fusing point were united and recrystallized till
this point was constant; eighty fractions being in this way con-
i ee. The first ( in dark red i
fusing at 220°; the second (D) was in large bright red_ brittle
needles, fusing at 185°; the third AE) was in oot: yellow fine deli-
cate needles, which fused at 144°. On examin ing the fractions
obtained A yielded a small care of a body insoluble in ben-
fraction D a new hydrocarbon having the formula C a whisk
though not Gas al with Bédecker’s substance—this being pro
ably a mixture of pyrene and phenanthrene—the author proposes
to call idryl. Further researches lagp 8 its constitution are in
progress.— Ber. Berl. Chem. Ges., x, 2022, Dec
1. Onthe Determination of Nitrogen in Ni troglycerin. —LAUER
and Apor have made a series of experiments to ascertain the best
method of determining nitrogen | in be POLL eh Solution of the
of the nitrogen by Reichhardt’s method, gave too low results. The
dynamite was then shaken with water, the deposited nitroglycerin
dissolved in alcohol, the alcoholic solution treated with potash and
on ssiwnesly and yielded she, theoretical ‘quantity, 18°5 ap: ia —
rl. Chem. Ges., x, 1982, Dec
8. On Anis Hydantoins. gtr we direct union of pono
acid and glycocoll, hydantoic acid is produced : door *4+CONH
=Cco<NH By loss of water, hydantoin is formed
NH.CH ,COOH.
ee
CONV H CH,” Hydantoin and its homologues methyl-hydan-
toin, may also be formed by fusing nectar g Heo H. or the corre
sponding homologues of it with urea: d 5% OH “CONT
=€o< ieee me at *+H.O+NH,. Scuweser has succeeded
in forming a Ladi a en by fusing together phenyl-glycocoll
NH
with | Phenvl-hydantoic acid was not
urea: CO omy yl-hy aa
obtained. When how ever, ™” acani dea e ata
and Phenyl-elyoocall in aqueous . solution are allowed to stand for
some days at 40° the filtrate after separation of the a m
ce esl “ie alcohol, on abundance of phenyl-by —
Ber. Berl, Chem. 2045, Dec. 1877. F. B.
‘hai. ri Scr.—Tutrp eal: Vou. XV, No. 86.—Fes., 1878.
10
146 Scientific Intelligence.
9h On the Behavior fl a acid in the Organism of Birds.
FFE has taken up anew the question of the ¢ change which
“ins acid undergoes in the organism of birds, first investigated
y Meissner and Shepard. He confirms the result of these latter
chemists that no isopiiein acid is geen but that an acid is ex-
creted which like hippuric acid is a paired benzoic acid. To this
acid he gives the name ornithuric ary e prepares it by ex-
tracting with alcohol the fresh excreta of hens fed on benzoic acid,
evaporating the alcohol, = ew ing again with hot absolute alcohol,
and evaporating. ame? sre dedi aegis liquid is mixed wit
thuric acid separates in crystalline ‘ikea having when pare the
empirical formula C,,H,,N,O,. Boiled with hydrochloric acid it
gives benzoic acid and a new base C (NH, ):0» inn
acid.— Ber. Berl. Chem. Ges., x, 1925, Nov. . B
9. Le Sage 8 Theory of Gravitation ; J by ae Seeds LLD.,
F.R.S.—Le Sage’s Theory of Gravitation is at present exciting a
good deal of attention among physicists. ag is perhaps to a
considerable extent due to the fact that some of the —
arbitrarily assumed by Le Sage in his ent othesis, have
ogc to follow as necessary consequences from the kinetic ene
e
one case at least he seems to me to have failed.* It isa necessary
condition of Le Sage’s theory, in order that gravity may be pro-
portional to mass, that the total volume of the free spaces In a
apa in the form of interstices between the molecules a
t compared with the total volume of matter containe
- fiolbenles themselves. This condition of free interstices Mr.
Preston considers to be satisfied by assuming the molecules to be
small as compared with their mean distances
Were we at liberty to make any assu ssumptions we chose in refer-
ence to the smallness of the molecules of matter and their distance
* In an interesting article on Kinetic Theories of Gravitation by Mr. W. B.
ttayslot-pabiiahed in the Smithsonian Report for 1876, he lays down six funda-
characteristics of of gravitation with which every theory, he says, must
six requirements, Le Sage’s theory he maintains satisfies but
Chemistry and Physics. 147
them. This subject has recently been investigated by Sir William
Thomson, who has given full details of his result in a remarkable
paper in “Nature” vol. i, p.551. Sir William says the diameter
of the molecule cannot be less than z59,54y,a57 Of a centimeter.
The number of molecules in a cubic centimeter of a liquid or a
solid may, he says, be from 3X10" to3X10*. This gives the dis-
tance from center to center of two consecutive molecules to be
aaivsor of a centimeter. Now, if we take
theory appears therefore to be utterly irreconcilable with Sir
But even supposing we were to assume, what we are ha ar-
ranted in doing, that the molecules are 10,000 times smaller and
their distances 10,000 times greater than Sir Willi omson
concludes, still this would not assist the or c
Mag., Jan., 1878. :
10, On the Thermal Conductivity and Diathermancy of Air
and Hydrogen.—Dr. Henry Borr, Professor of Physics in the
University of Giessen has undertaken the revision of the wo
rong eeigp Tyndall and others upon this subject. The apparatus
could be filled with any gas at any pressure. A thermometer was
luserted through a tubulature about 50 mm. below the thin glass
plate placed in a horizontal position. e upper vessel was filled
ed
he found that the temperature akeny"s pyoabad ie: ,
even at ordin atmospheric pressure it had greater dlatherman
than a ane He batt “8 ly concluded that hydrogen was
Similar to the metals in to conducting power. Dr, Buff’s
#
148 Scientific Intelligence.
apparatus was similar to that of Magnus, with the exception that
a brass cylinder was cemented upon the glass vessel; instead of
the thin glass plate a polished metallic surface, constituting the
bottom of the brass vessel, faced the enclosed thermometer, a
double wall surrounded the cylinder filled with cotton wool to pre-
vent too rapid cooling. The glass cylinder was 20 em. high and
7°5 em. in diameter-—its lower edge was ground so as to fit air-tight
upon the plate of an air pump. The thermometer in Magnus’
d of
air.” —Phil. Mag., Dec. 1877, page 401.
11. & of the Electrie Spark in compressed gases.—CAZIN
and Winer have been experimenting separately upon the sub-
ject. Cazin resses his results as follows: The electric spark
resembles an ordinary gas flame. In both sources of light there
are, beside the peculiar vaporous particles which give line spectra,
e admixture of the last which arises from the character of the
electrodes and sides of the containing vessel increases with the
pressure, so that finally the line spectrum upon the higher con-
tinuous spectrum disappears. In the so-called aureole the mate-
Geology and Mineralogy. 149
ich were not perceptible at ordinary pressures, together with
the always present sodium lines an um line which ap-
clusions of Cazin that the continuous spectrum 1s
: c
IL GroLtoagy AND MINERALOGY.
1. Silurian Plants ; by Leo Lesquereux. 12 pp. 8vo. From
the Proceedings of the Amer. Phil. Soc., Oct, 19, 1877.—Mr. Les-
quereux has here published, with a plate for illustration, his latest
cinnati group, first brought out in 1876, gives additional maport.
ance and interest to the earlier discoveries 1n Ohio. M . Lesqu
reux calls the species he first described Protostigma sigillaroides :
nd adds now, from the same rocks—the Cincinnati group, near
Cincinnati, Sphenophyllnm primevum Lesqx., Psilophytum gra-
cillimum Lesqx. (near Covington, Ky., opposite Cincinnati). :
In thi er Mr. Lesquereux also describes a Fungus (Bhi
zomorpha sigillarice Lesqx.), found in connection with a Sigilla-
ria in cannel coal at Cannelton, Beaver Co., Kentucky.
: ; 2 by WarrEN Upuam.
150 Scientific Intelligence.
study of these Quaternary deposits, carried on while acting as
assistant geologist in the survey of the State. The conclusions
here brought out with regard to the long gravel deposits of the
larger valleys, which had been called kames, or eskers, are given
at length in the last volume of this Journal, in an article contrib-
uted by himself. All parts of the subject are worked up with
- thoroughness and the facts are given with full details in the vol-
u ons.
é as
von N. v. Koxscnarow.—The monograph of the eminent Russian
4. Die Glimmergruppe ; 1 Theil, von G. Tschermak.—The me-
moir by Prof. Tschermak upon the mica family, of which the first
ical relations to a second paper. The exact determination of their
optical characters has enabled the author to prove that all the
micas, although a variation in angle from the orthorhombic form
may not be established, are nevertheless monoclinic.
e micas are divided into two groups; with the first the plane
of the optic ages is perpendicular to the plane of symmetry and
with the second is parallel to it; they are as follows:—
— i Anomite. Meroxene, Lepidomelane.
— Phlogopite, Zinnwaldite.
Muscovites:— Lepidolite. ;
FP
Margarites:— Margarite.
The name Merorene, first introduced by Breithaupt, is em-
ployed by the author to include all the nlagnesia micas of Wr eivitia:
and also all other magnesia micas closely related to them and not
falling into the other divisions. On the other hand the magnesia
micas which fall into the second class as defined above are called
anomite (Gr. avouéo) ; in this class falls the mica of L. Baikal,
and that of Greenwood Furnace, N. Y.— Vienna Academy.
E. 8.
dD.
Botany and Zoology. 151
II Botany AND ZooLoey.
1. The Hybridization of Lilies ; by Francis Parkman.—In
No. 15 of the second volume of the Bulletin of the Bussey Insti-
tution, under the above title, Mr. Parkman gives a summary of his
experiments, during ten or twelve years, in crossing Lilies. One
d |
name of Lilium Parkmanni. The interesting physiological point
which Mr. Parkman here records is, that this striking novelty
h
rent, L. speciosum. That
these plants were truly hybrids, notwithstanding, is well made
g
parent.
It would naturally be thought that this slight but evident im-
pression of the character of the male parent might be deepened
y iteration. That was tried next year, when the flowers of
several of these plants were fertilized with the pollen of L. awratum
precisely as their female parent had been fertilized, The result
was an extremely scanty crop of seed, “ but there was envagh to
_ ren experiment proceeded one generation
farther. “In the following year I set some of them apart from
152 Scientific Intelligence.
the — and applied to them, as to their mother before ont the
po n of several species of lilies. This time the seeds were ex-
Genely mat: A few, however, were reebased but the oleate
and flowers that resulted Ce them were, to all appearance, Z.
superbum pure and s
In trials of other spines results intermediate between these two
cases were obtained. For instance the pure white of the perianth
the herbag
unaffected ; but in that or the next ‘generation “ distinct stapes
could be seen of the eet of alien pollen” in the changed color of
many of the anthers, and in the abortion of others. They “ass
showed differences of habit among themselves, some being ve
sae and vigorous, oe others compact and bus shy, W with a tendency
o bloom in clusters; but these ma y have been mere seedling
veeldthoria with whieh the dipbeldinetioi had nothing to do.” Yet
some of these marks correspond with known results of hybridiza-
tion
That offspring should partake ster oe of the characters of the
two A sone is a matter of commo: observation. That in the genus
in forty i nstance “yr = fifty take
shown, is verre remarkable. That, in not a few instances it should
take them al
should be rey resented = cases — extraordin ae ‘
the name of the two parents, t shat of the male ing. The
plan had the double advantage of indicating the origin of the
cross, and of distinguishing rt ae om species in nomenclature ;
in practice it proves insufficien
Botany and Zoology. 153
.
would be broken up. But it is now stated (Gard. Chron., Dee. 15
of all countries, specially those of dry regions. .G.
3. Dr. Engelmann’s new botanical Papers in the Transactions
of the Acad. Sci. St. Louis, vol. iii, Nov.—Dec., 1877.--The most
Important of these papers is an appendix to that on The Oaks
of the United States, read in the spring of 1876, and pub-
lished soon afterward. A full notice of it appeared in this
of the section Sabina, which fills ten pages with the discussion
of our nine s ecies, Mexican and West Indian being included.
The third paper is a small one on The Flowering of Agave Shawii,
with a plate illustrating floral details. It must suffice merely to
announce these publications, which are indispensable to working
botanists. ee
A new range for two Orchids is given by the Rev. Dr.
Wizse of Oswego, New York, who sends Listera australis and
Habenaria leucophlia, gathered by him in “Lily Marsh,” nine
miles east of Oswego. ‘The first was not known north of the pine
arrens of New Jersey, and is a southern plant. The secon
longs to the district from central Ohio west, but Mr. Hankenson
tals, AG
ay e€
Work is full of interesting facts and observations and is excel-
154 Scientific Intelligence.
lently illustrated. Had it been shortened by one-half, it would
ha en easier reading, certainly for foreigners. As it is, it is
and spores of Coprinus are produced directly from the mycelium
by a vegetative process without the intervention of any sexual
ns, i t thi i
sclerotium, the stipe, and the pileus and places them in conditions
favorable to farther growth. Now, if the fruit-bearing body is
) Hence there can be no sexual organs either in the sclero-
tium, stipe or pileus. The mycelium and the hymenium in
see about the first attempt to refer different species of fungi to a
hypothetical type which was the common ancestor. This method
which has been used with such advantage by zoologists is not
Botany and Zoology. 155
likely to answer as well in fungi of which almost no definite fossil
remains exist. W. G. F,
5. Beitrdge zur Entwickelungsgeschichte der Flechten, Part II.
Ueber die Bedeutung der Hymenialgonidien ; by Dr, E. Srant.
Leipsic,, 1877. 8°.—An admirable essay, excellently planned,
and beautifully written. In the first part of this work whic
already been noticed in the Journal, Stahl gave an account of the
sexual organs of lichens. In the present, he considers the signifi-
cation of the hymenial gonidia of course in its bearings on the
menial gonidia are derived from the thalline gonidia and present
a different aspect simply from their different surround
the spores are Sacheused some the nial gonidia are
ways dischar ith them. the res germinate, thei
hyphe fasten themselves upon the gonidia which then increase
more rapidly tha re. In from four to five months Stahl suc-
ceeded in raising n rithecia and spores by his culture of the
y producing the lichen-fruit in his cultures, Stahl removes this
o e
notice the statement in the number of Just’s Jahresbericht that
156 : Scientific Intelligence.
°
+
mM
}
ia
feed
@
~T
oo
>
Ry
e
&.
eel
®
Qu
9
°
re)
ro)
Ps
=]
ea
%,
e
=a
oO
ae)
ber
}
4
ct
>
°
ba
ae
o
fas)
several months and attain a considerable size. Ww. G F.
anew Species of Parasitic Green Alga belonging to the
Chlorochytrium = found b Prot. Wright on several plants,
the parasite which is very common on Keto rpi of o
coast. At the end of the second article is a consideration of the
iferent forms of sporangia found in British species of Eetocarpus.
.
that his method is free from errors, he submits the following ex-
spiration are the ones absorbed by chlorophyll
trauspiration be ee mee to their own convertible energy ; it
t with greater energy, although only partly ab-
sorbed by chlorophyll, than can a blue ray, pene inca orific radia-
e a é bsorbed. ah @ ;
; apanese Lingula and Shell Mounds.—At a meeting 0
= Boston Society of Natural History, December 19, Professor
WARD 8. Morse communicated some of the results of his work
Botany and Zoology. 157
in Japan. His main object in visiting Japan was to study more
fully a group of animals upon which he has been at work for a
long time—the Brachiopoda.
Accepting an appointment as professor of Zoology in the Impe-
rial University of Tokio he established a Zoological station on the
coast for the purpose of collecting material for the University
Museum and for the training of Japanese assistants in the work.
Ilis studies of Lingula have brought out many points new to
science. The discovery of audito In ss
been changed twice since August 20th, and yet no specimen
died. This illustrated more fully the vitality of Lingula than the
experiments he had made on the North Carolina Lingula several
years since. :
A description was also given of an ancient shell-mound discov-
ered by Professor Morse at Omori near Tokio, and photographs of
many of the vessels exhumed were exhibited. The general aspects
of the deposit were like those described by Steenstrup in Denmark,
’ ates coast.
The implements were mostly horn. Only three rude stone imple-
ments were discovered. The pottery was remarkable in showing
=
Low |
a
<4
oO
oe
°
Laur)
°
J
S
)
5
fae)
5
E
=)
5
+
5
s
emt
cr
=
EA
<
d
F
Qu
®
~
=]
In the character of the raised knobs for handles on the edge of
the vessels it shows the closest resemblance to pottery discovered
by Professor Hartt in Brazil. Mr. Morse was not pre
whether it was early Aino or a race which ‘ the Ainos
and which the Ain i in their occupation of the island
158 Scientific Intelligence.
The American Naturalist.—The January number of this sci-
entific monthly comes to us from Philadelphia, where this Journal
is to be published hereafter by Messrs. McCalla & Stavely.
Protessor E. D. Cope is now associated with Professor Packard
in the editorial management of the journal. It has always been
successful in combining the scientific and popular in its articles,
and has contributed greatly to scipnoeeducation 4 in the country as
well as to the progress of geet ; and the Prospectus states that
this will, be still its aim. It is also announced that the depart-
ment of birds will be edited by Dr. Coues, and that of micros-
copy by Dr. R. oe Ward; and that Professor O. ia poe will
interest, maki an attractive journa mateur as well
as the man of science. It has for its mata a a beautiful col-
ored plate of Baird’s Bunting,—Passerculus of Coues,—
illustrating a paper by Dr. Elliot Coues, U.S. A. Professor J.
A. Allen has a paper on An inadequate “ The birds’ nests,”
in which, after stating various facts, expresses the following
conclusion: ‘“ surprising thing about Mr. allace’s
‘theory of birds’ nests’ is its inadequacy and its irrelevancy to the
as proposed to explain; espect it was
a >a for the Bulletin is only two dollars
Nests of “ the dener.”—In the Annali ai Stori ria naturale
ael pt Civico di Genova, the illustrious traveller and botanist,
Prof. eccari, describes the wonderful gallery or bower-con-
structions of the Amblyornis inornata, observed by himself in
the Arfak Mountains. The huts and gardens, as built and laid
out by this bird, which is called “the gardener,” to surpass
any production of intelligence and taste for the waniited hitherto
described and observed in birds of the Paradise family.— Nature,
Dee. 6, p. 110.
IV. Astronomy.
tie Meteors observed in Cambridge, Mass,, November 3, 1877.
m
the d same radian. which was near 0 Mars, pea! their directions
were towards the S.W., all Avene Is to the ‘Mere radiant.
B.A me Ps. H.
. Prize for the discovery of Comets,—The ye my
of aSrideni at Vienna has resolved to continue, un raat notice,
the prizes, Belecte se Since 1872, for the discovery of telescopic
of such a prize, consisting, according to
the wish of the receiver, either in a gold medal or in its money
Miscellaneous Intelligence. 159
value of twenty Austrian ducats, is connected with the following
conditions :
(1.) Prizes are awarded only for the first eight successful dis-
coveries of each calendar year; for comets that, at the time of
their discovery, were telescopic, i. e., invisible to the naked eye,
that had not been seen before by any other observer, and the
c
be supplemented at the next occasion by later observations. (4.)
If the comet should not have been verified by other observers,
the prize will be awarded only when the observations of the dis-
coverer are sufficient for determining the orbit. (5. e prizes
each year. If the first notice of the discovery a t
the first March and the last May, the prize will be decided in the
gene ay session of the Academy in the next year. )
Application for the prize is to be made within three months after
e ews of the discovery has arrived at the Imperial Acad-
emy. Later applications will not be considered. (7.) The
astronomers of the observatory of the University at Vienna will
be judges, whether the conditions contained in arts. 1,3 and 4
have been fulfilled. ;
3. Index Catalogue of Books and Memoirs relating to Nebule
and Clusters, de. ; by Epvwarp S. Hotpey. Smithsonian Institu-
tion, Washington, 1877. 8°, pp. ix and 111.—About half of this
Holden is devoted to the catalogue
: a list of books and
memoirs relating to the nebula in Orion; a similar list of those
Nebule and Clusters.
V. MisceELLANEOUS SCIENTIFIC INTELLIGENCE.
1. Telephone in England.—Col. W. H. Reynoxps has concluded
a contract with the English Government by which the Post Office
Department has. adopted the Bell telephone as a part of its tele-
was heard through the telephone, and individual voices were dis-
tinguished. This important experiment was conducted by Mr. J.
Bourdeaux, of the Submarine Telegraph Company. very
Successful experiments. were made with the telephone on Saturday
160 Miscellaneous Intelligence.
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made wit th ol ane Bell’s instruments The Berlin correspondent
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sult is awaited with great curiosity in military cirolee. e
Cologne Gazette denies that any telephone is‘in exueee e between
Varzin and Bismarck’s eat Berlin. Our ontem porary says
that the distance, 363 kiloractara. is too lange using a pinciais g
with any advantage.—Natur e, Dee. 6, *
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Scuumann, C.E., U. 8. Treasury Department. 89 pp. 8vo. New
York, 1877. (D. Van Nostrand. )—This little book contains the
formulas and data required by architects and engineers in putting
to practice in the ac bey af buildings, the theoretical sally
erism, Suieitoctisi, ete, historically and scientifically
eeaoty sag being two Lectures delivere a the London Institu-
tion, with Preface and Appendix; by W ARPENTER, C.B
E.RS. 15 8 pp. 12mo. New York, is77. “(D. Appleige & Co.)
—The learned physiologist of Lon don , Dr. Carpenter, has show
goo = thorough knowledge and excellent ee in sake
lectures.
at _ = a
E.—The number of the Bibliothéque
Uaivenais fp cesses in ‘Sei Phys. et Nat.) for September, pie iT,
has its 254 pages occupied with a biographical notice of the emt
nent Swiss Physicist, Auguste de la Rive, who died, at the age rt
seventy-two, = the 27th of N ovember, 1873.
Proteus, or Unity in Nature, by Charles Bland Radcliffe, M.D. 214 pp. 8v0-
London. ‘(Mac acMillan & Co.
The Physiology of Mind. By Henry Maudsley, M.D. 544 pp. 8vo. New
fein (D. Appleton & Co.)
atetheaial Researe! By William Ferrel. Part I. On the Mechanics
scat thi, Gomeeuk iasthema ot the Atmosphere. 50 pp. 4to. With 6 charts. U. 5.
Coast Survey, OC. P. Patterson, Superintendent. Washington. 1877. An en
tant memoir discussing mathematically, from meteorological data with referen
to the whole earth’s sorties.
OBITUARY.
Ruum«KorrF died in Paris on the 20th of December at the a
of seventy-four. He gave his first “ Ruhmkorff Coil” to the wor d
in 1851, and received for it from the French Exhibition in 1855
prize of 50,000 francs.
THE
AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES]
rs
>
Art. XXI.—Coggia’s Comet—its Physical Condition and Struc-
ture. Physical Theory of Comets; by Prof. W. A. Norton.
ments of the pa ted by M.
Schulhof (Astr. Nachr., No. 2003). T=1874, July 885664,
G. M. T., 7=271° 6 195, O=118° 44’ 25’°3, 1=66° 20’
58’6, log. g=9°829826, which gives, per. dist. g=0-67581.
Motion direct. °
Nature and Condition of the Cometic Matter.—The following
are the general results of. the observations made with the spec-
troscope and polariscope* with the view of ascertaining the
nature and condition of the matter of the comet; in the nucleus .
and coma or envelopes, and as more widely diffused in the tail.
(1.) The light of the tail and coma was partially polarized in
a plane through the axis of the tail.
(2.) The spectrum of the comet consisted of three or more
bright bands on a continuous spectrum. This continuous spec-
trum was faint on July 7, but became much brighter by July
14. The three bright bands were identical with those obtained
by passing a spark from an induction coil through gaseous
* Month. Not. . Soc., 187 489 to 491; 1874-5, p. 83.
Aatz. Nachr,, No. 2018 9p. 181082
Am, Jour. Scr.—Tarrp Senet. Vou. XV, No. 87.—Maxcu, 1878,
162 W. A. Norton—Coggia’s Comet.
dioxide of carbon (carbonic acid gas). Other experiments
have shown that the volatile hydro-carbons give, with the
electric spark, the same spectroscopic bands; and that these
are wholly due to the momentary incandescence of the carbon
molecules of the compound. - Several other comets have given
the same “carbon bands.” Brorsen’s comet, a faint circular
nebula, invisible to the naked eye, proved to be an exception.
Three bright bands were observed in its spectrum, but they
differed in position and other features from the carbon bands.
(3.) “The spectrum of the nucleus was continuous, but it
appeared to have traces of numerous bright bands, and three
or four dark lines also were seen.”
(1.) From the bright bands observed we may infer that the
vapor of some hydro-carbon. ;
‘ é e light of incandescence of the gaseous particles,
which furnished the bands, must have been of electric origin;
since the heat of the sun could not have been sufficient to
ignite the most inflammable vapor.
(3.) The continuous spectrum on which the three, carbon
bands were seen, affords no decisive evidence of the presence 2
the coma of discrete solid particles, since it may have resulted
from the solar light reflected from the gaseous particles. Such
light would not have been sufficiently intense to give the dark
solar lines.
(4.) The “traces of bright bands” seen in the spectrum of
the nucleus reveal the presence of vapors at its surface shining
by electric light. The bright continuous spectrum may have
wholly due to reflected solar light (since dark solar lines
were not wanting), or partly to discrete solid particles render
luminous by electric discharges. The light reflected from the
solid nucleus, or from dense vapors or clouds near its surface,
may well have been of sufficient intensity to make the gaseous
n bands resulting from electric discharges inconspicuous.
(5.) The spectroscope did not give any decisive evidence
with to the state of the matter in the tail—whether
gaseous or composed more or less of discrete solid particles;
but since the tail was formed of matter flowing in continuous
streams from the head, we must suppose that it was made up
chiefly of gaseous particles, like the head.
j (6.) The light of the tail was exclusively reflected solar
ight. Si
-
W. A. Norton—Coggia’s Comet. 163
e ‘
The experiments of Professor Arthur W. Wright, of Yale
College, on the: gases from stony meteorites,* have furnished
strong evidence in support of the hypothesis first propounded
by him, that the cometic substance is gaseous carbon dioxide.
He found that “in meteorites of the stony kind, the character-
istic gas is carbon dioxide, and this, with a small proportion of
carbonic oxide (oxide of carbon), makes up more than nine-
tenths of the gas given off at the temperature of boiling water,
and about half that evolved at a low re 4 e spectrum
of the gases, obtained by passing an electric spark through a
small tube containing the gases at a low tension, consisted of
the hydrogen and carbon spectra together. The three bright
bands of the carbon spectrum were éoincident in position with
those in the spectra of comets, and had the same relative order
of intensity. The close relationship now known to subsist
between comets and meteors renders it highly probable, as sug-
ested by Professor Wright, that the cometic matter is iden-
tical with the gaseous matter found associated with stony mete-
orites, and consists chiefly of carbon dioxide disengaged from
the nucleus of the comet by the heat of the sun.
If we adopt this hypothesis with regard to the nature and
origin of the cometic substance, the question arises in what
condition does the carbon dioxide exist, in its association with
the matter of the nucleus? We may at once admit, with Pro-
of approaching the sun, the increasing amount of heat received
from the sun should give rise to copious evolutions of the
* This Journal, III, vol. ix, July, 1875, p. 44.
164 W. A. Norton—Coggia’s Comet.
carbon-dioxide in the gaseous form—either continuously or in-
termittently—and these may occur either simultaneously over
large areas, or in limited streams or jets. A portion of the
vapor evolved may be condensed into solid particles by the cold
resulting from the rapid evaporation. In so far as the gas is in
intimate physical association with the solid matter of the nu-
cleus, it would seem that the heat of the sun would not at the
perihelion distance of either Coggia’s Comet, the great comet of
1861, Donati’s Comet, or, indeed, of any of the conspicuous
comets with a few exceptions, be intense enough to occasion
such copious evolutions of gaseous matter as have been actually
observed. Evolutions of occluded gas may, however, consti-
tute the chief phenomena, produced by the solar heat, in the
cases of the inconspicuous comets of short period, which, in re-
treating from the sun do not pass sn the limits of the
planetary system.
The conclusions that have now been reached apply strictl
only to the comets that have been spectroscopically observed,
but they may be regarded as probably applicable also to other
comets that do not differ greatly from these in the circumstan-
ces of their approach to the sun and recess from him, and in
the physical phenomena they have presented. The great
comets of 1848 and 1860, that approached very near the sun,
may have given off, in great abundance, aqueous or other
forms of yaporous matter, derived from the liquefaction and
the earth, permeated by free electricity increasing in tension
from the surface of the nucleus upward; and that whatever
Physical — of the Comet.—From numerous published
the comet, I select that in which its peculiar
eatures are most conspicuous. The cut is a copy of a drawing
W. A. Norton— Coggia’s Comet. 165
communicated by R. S. Newall to A. C. Ranyard, showing
the aspect of the comet, as seen at Ferndene on July 12th. In
the accompanying description* it is stated that “the nucleus
was very bright, with a disk tolerably well defined. In front
of the nucleus (i. e. on the side toward the sun) was a fan-
shaped light which seemed to arise from the overlapping or du-
plication of the two tails, which streamed away behind (the
nucleus) for a length of about 15°, forming, as it were, two
luminous veils, delicate, transparent and flickering, having be-
tween them a black space well defined up to the nucleus. The
edges of these tails appeared to be brighter than the middle
part, and crossing over the nucleus they formed the sides of the
; the outside edges also crossing over formed the top of the
fan and head of the comet. In front of this was another cov-
ering semicircular and brightest in the preceding part, and in
front of that was again another fainter envelope or cloud.
This outer faint envelope, or duplex envelope, has been a no-
ticeable feature in the aspect of other comets (e. g. Donati’s).
et
I.
Physical structure and condition of the Comet.—Upon the vari-
ous drawings made by different observers, Mr. Ranyard has
the following remarks:+ ‘The drawings that were made o
Coggia’s comet during the early part of July, 1874, show that
although there was but one small almost stellar nucleus, there
were two sets of parabolic envelopes situated side by side,
ently overlapping one another just in front of the nucleus.
* Month. Notices of Astr. Soc., 1875-6, p. 279. + Ibid.
166 -W. A. Norton— Coggia’s Comet.
were shown in the drawings made by Mr. Huggins and Mr.
Christie. They are also to be seen in Mrs. Newall’s drawing
(see cut, p. 165), and they were described by Mr. Lockyer in a
letter published in the Times, of July 16th, on the structure of
the comet. When the comet was again visible in the Southern
hemisphere, the inner duplicate structure was still visible, but
the outer ares had been dissipated.” The duplicate structure
here referred to is a highly significant fact. That it may be
uly appreciated it must be borne in mind that at the period
when this structure was observed, the line of sight from the
earth to the nucleus was inclined under a small angle to the
since the ere contrast between the dark space behind the
nucleus and
W. A. Norton—Coggia’s Comet. 167
from the region exposed to the normal incidence of the sun’s
rays, it appears, then, altogether fails of application to Coggia’s
. comet. It gives the single hollow paraboloidal tail without
duplication, which is entirely at variance with the facts of ob-
servation.
Physical Theory of cometary phenomena.—Now, if there be,
in fact, two systems of jets, eminating from opposite hemis-
pheres of the nucleus, and passing over from one to the other,
we can look for the origin of such a state of things only in a
supposed magnetic condition of the nucleus, and in the hypoth-
esis that the lines of initial discharge lie in the direction of the
. lines of the magnetic force ; or in lines having a certain relation
to these. This consideration brings us to the proper point of
view for the presentation of the definite physical theory of com-
nucleus. This envelope, consisting of a diamagnetic gas, is
traversed by the ideal lines of magnetic force proceeding from
the nucleus, which are also lines of electric conduction through
the diamagnetic gas. The electricity set free by the ascending
currents of the gas, by reason of the diminished gaseous pres-
sure, is propagated along these lines; and the impulsive force
of the electric currents detaches streams of successive mole-
cules of the gas, in the direction of the lines of conduction.
La Rive’s well-known experiment of transmitting electricity
through an attenuated gas or vapor surrounding a magnet,
showed that the lines of force in the magnetic field were also
Operate on other molecules not thus detached, with an intensity
‘sufficient to overcome their gravitation toward the nucleus.
' In my mathematical discussion of Donati’s comet* I reached
the result that the tail of the comet was made up of matter of
which a portion was solicited by an effective solar repulsion,
* This Journal, Il, vol. xxxii, No. $4, July, 1861.
168 W. A. Norton—Coggia’s Comet.
Frying Mer Aap
showed that the ‘columnar structure” of the tail, signalized
by Prof. Bond, was attributable to considerable variations, at
short intervals, in the quantity of matter detached from the
head of thecomet ; while the limits of variation of the effect-
between the limits, repulsion=1-415 A and attraction=0°786 A.
orce of Cosmical Repulsion.—Several hypotheses have been
propounded with regard to the nature and origin of this force.
But none of them appear to be free from serious objections.
Several years since (1861) I suggested the hypothesis that the
solar repulsion might consist in the repulsive action of free
statical electricity. We have abundant evidence of electric
excitation both at the surface of the sun and in the cometa
sun as an electro-magnet + on the gaseous molecules of the comet.
- - F. Zollner, in two elaborate papers published in the Astronomische
Nachrichten, No. 2057-2060 and No. 2082-2086, has endeavored to remove the
force of the several objections urged by Dr. Zenker to the electric theory of the
lar repulsion, and gang the adequacy of this theory. Dr. Zenker has pub-
our =m ‘
y A discus-
sion, it does not appear that the above-mentioned objection has been set aside. It
must be admitted, I think, that at present the tric theory rests under a
of doubt. As for Dr. Zenker’s own reaction theory, to mention no other objec-
tions, it is certainly wholly inapplicable to the case of a co ming as near the
sun as did the comets of 1843 and 1860; and it obviously affords no explanation
ee oe ure of ia’s comet.
e term electro-magnet is meant a magnet which derives its magnetic
condition from the continued operation of some external cause. ae
W. A. Norton—Coggia’s Comet. 169
It_ was conclusively established by Faraday, by a series of careful
experiments, that the gases, with the exception of oxygen, are
rapidly changing one, in approximate correspondence with the
varying rate of the orbital motion. The circular magnetic cur-
Inequality of the Solar Repulsion.—Faraday established that
the diamagnetism of a gas increased with its temperature. But
by changes of temperature. But may not material variations
oO
diamagnetic condition result from the ewe discharges to —
which the gaseous molecules are expose
Looking at the matter from the general point of view I have
taken in my papers on Molecular Physics, it appears that such dis-
* This Journal, II, vol. xli, Jan., 1866.
170 W. A. Norion—Coggia’s Comet.
cometic particles may differ greatly in size or mass. This
coma. But both of these suppositions seem to be irreconcilable
with certain facts of observation.
Explanation of General and Special Phenomena.—It should be
repulsion, whatever may be its origin, is exerted normally, or
approximately so, to the surface of the body, and that the radial
impulses of this force take effect unequally on different gaseous
bly on solid cometic particles differing in size or mass. A mag-
netic condition of the nucleus, sufficiently decided to determine
e
field, is however an essential feature of the theory.
The precise character of the phenomena should depend, to
s of rotation of the
m this position there will be two efficient causes of special
phenomena to be considered : (1) the point of maximum evap-
W. A. Norton—Coggia's Comet. - 171
orating effect of the sun’s rays will probably fall at some point
of either the northern or the southern hemisphere of the nucleus,
instead of on the equator; (2) the magnetic poles will not coin-
cide with the poles of rotation, and the magnetic equator will
be more or less inclined to the plane of the equator of rotation,
as well as to that of the orbit. From this it follows that the
lines of force will, in general, be more or less inclined to the
astronomical meridian planes of the nucleus; and hence that
the initial directions of the jets of cometic matter will be in-
clined to these planes b
a meridian should result from the cold produced by a copious
evaporation and the intercepting action of the vapors already
be supposed :
tor, and extend gradually both north and south. The Neti,
directions of the discharges, and therefore also of the initi
side, the gedaera becomes parallel to the equator (ecg), and
thus to the radius vector (ce). From 0° to 35
172 _ W. A. Norton—Coggia’s Comet.
this line, and beyond 385° diverges from it under a larger and
larger angle. If the initial velocity is constant, as well as the
solar repulsion, the escaping molecule should attain to its great-
_est distance from the nucleus when the discharge occurs from
the latitude of 35°, and in the precise direction of the sun, If
then the process of electric dischar egin near the equator,
and extend gradually to the north and south, the outer surface
of the envelope formed will gradually move away from the
nucleus, and attain its greatest distance when the process reaches
the latitude 35°. The jets that issue from latitudes greater
than that (about 35°) at which the direction is parallel to the
radius vector, do not pass sensibly beyond the boundary line of
the jets that proceed from points between 0° and 35° of the
other aay wed, unless for such jets the projectile velocity is
greater, or the solar repulsion less.
BR
2
What has now been stated should be the precise result if the
molecules after receiving a projectile velocity were exposed
only to the retarding force of the solar repulsion. The effect-
ive action of the nucleus would obviously modify somewhat
the curve for each initial direction, and alter the limiting lati-
tude for which the recess in the assumed direction is a maxi-
mum. If this effective action is attractive, this latitude will
exceed 35°, if it is repulsive, it will be less than 35°.
*
Ei ye, tiie
W. A. Norton—Coggia’s Comet. | 173
distance to which the jets recede in the direction of the sun.
We may then regard any expelled particle as issuing from the
small sphere of sensible action of the nucleus with an initial
velocity resulting from the projectile force of the electric dis-
charge, and the retarding force of the nucleus (or accelerating
force if the effective action should be repulsive); and as subse-
quently retarded by the solar Pe Heeiate s we have seen, p.
the solar repulsion, its velocity and direction of emergence
from this sphere, becomes thei{initial velocity and direction.
RR Ie
3. : :
As, for any one molecule, the solar repulsion is sensibly constant
t
within the extent of the head of the comet, the p j
molecule will be parabolic. If we regard the initial velocity
est rec d
which suffer the greatest retardation should form a similar
luminous surface at a lower depth. The latter would eventu-
174 _ W. A. Norton—Coggia’s Comet.
form the following side. The time required for any receding
particle receiving an initial velocity in the line of direction of
the sun, to reach its point of greatest recess, must have been
less than twenty-four hours, in the cage of the two comets
(Donati’s and Coggia’s) for which the intensity of the actual
solar repulsion has been determined.
Let nes gq (Fig. 3) represent the nucleus, or more strictly the
surface of projectile discharge, and n’e’ s’q’ the sphere of sen-
sible action of the nucleus ; e g being the equator and ce R the
direction of the sun. The point p is at lat. 35°, and ris the
point of projection of the jet which issues from the sphere
n’e’ s'q’ in the direction 7’ A parallel toce R. The jets pro-
ceeding from the are er issue from this sphere at various
points from u to 7’. One of these jets proceeding from a certain
point near e will have at v a direction at right angles to ce R,
+
If the jet discliarge extend beyond r to some point z the jet
proceeding from z will emerge trom the sphere n
erge
the same sphere between 7’ and z’. Now letn’e’s' 7 (Fig. 4)
any jet emerging from this sphere to the line n’cs' perpendic-
ular to the radius vector ce’ &. Sup a Cosiated from
W. A. Norton—- Coggia’s Comet. 175
shown in the diagram. The jets proceed from n’ ve’r’, and
_were projected from the lower latitudes of the right hemis-
phere, or between e¢ and r (Fig. 8). Jets issuing from the corre-
sponding are e r, of the other hemisphere, would form a similar
set of curves to the right of ce’ #. Other sets of parabolic
jets are projected from latitudes above 35°, or from the ares r z
and r, « (Fig. 8); but these will have sensibly the same outer
boundary as those from e7’ ander, unless the initial velocity
or the solar repulsion is different. It is to be observed that ce
is so small a fraction of ce’ (Fig. 8) and ce’ so small a fraction
of ¢ V (Fig. 4) that we may without material error regard v as
coincident with n’, and 7’ as coincident with e’.
° ‘g
oa’ 100 nie
he
1B0
5,
The hypothesis made in the construction of Fig. 4, that the
solar repulsion is constant for all values of a, or in other wo
magnetic needle on the earth’s surface, and varies, we may su
pose, with the latitude according toa similar law. Let it be
denoted by £.
176 _ W. A. Norton—Coggia’s Comet.
In Fig. 5 the solar repulsion is assumed to be inversely pro-
portional to sin 6. The change of direction of the jet while
passing through the sphere of sensible action of the nucleus is
neglected in the application of this law. Two systems of
curvilinear jets are shown—one answering to values of a varying
by 10° from 50° to 90°, and emanating from latitudes less than
35° of the right hemisphere, or from a portion of the arc er
(Fig. 3); and another answering to values of a varying by 10°
from 90° to 180°, and estimated from right to left. These em-
anated from latitudes greater than 35° of the left hemisphere,
or from a portion of the are r, x (Fig. 8’. The other corres-
ponding systems of jets, emanating from portions of er, and r 2,
would form the other half of the comet. If we consider all
the jets issuing from the right hemisphere as forming one sys-
tem, and all those issuing from the left hemisphere as forming
another system, then for each system a will vary from 50° to
180°: and will increase from left to right for the first, and from
right to left for the second. They answer to the supposition
that the outstreaming extends from latitude 174° to 574°, in
each hemisphere. It will be seen that the jets proceeding
from the latitudes higher than 35°, for which a varies from 90°
to 180°, recede to greater distances from the nucleus than those
emanating from latitudes less than 35°, for which a varies from
50° to 90°. This of course results from the greater values of
sin 6 that obtain for the first-mentioned set of jets. Thus, for
the 130° jet sin 6=0-953, while for the 50° jet sin 6=0534.
_ The envelope, Vaéd, or outer boundary of the latter system of
jets thus falls within that, Va’ d’ a’, of the other system. The
overlapping of the two systems of jets should accordingly be
conspicuously visible, and an appearance presented similar to
at of Coggia’s comet on July 12th, as shown in the drawing
on page 165.
Certain comets have presented peculiarities of appearance which
I find, on a careful examination, admit of pisisdocsoty explanation
on the hypothesis that the equator of the nucleus was inclined to
*
W. A. Norton—Coggia’s Comet. 177
the two branches of the normal tail, in connection with an anom-
alous curvature of the first portion of the longer branch, when the
comet was viewed from certain positions of the earth relative to
the plane of the orbit, observed in the case of Comet II, 1862, and
elaborately discussed by Prof. Schiaparelli and Prof. Bredichin.
n this case we have only to suppose that the sun was vertical
to points of one of the hemispheres, and as a consequence the jet
discharges were mostly confined to that hemisphere. The longer
branch of the tail was composed of jets issuing from the lower
latitudes, while the less copious and more fluctuating discharges
of matter subject to a diminished solar repulsion (p. 176) from
r.
The anomalous curvature of the former system of jets, and their
interlacing with the other system, was a simple consequence of
the greater intensity of the solar repulsion in operation on the
former than on the latter.
e curious phenomenon of the oscillation of jets first observed
by Bessel in the head of Halley’s comet, and of which he offered
in explanation the improbable hypothesis of a polar attractive
force exercised by the sun upon the nearer portion of the nucleus,
planes of different local meridians on the nucleus. As the planes
* To illustrate, if the outstreaming were perm Be right perpen we (Fig.
: : : us
thoes easing Pe ress oc oul oor
Am. Jour. Sci.—Tuirp Serres, Vou. XV, No. 87.—Maxcu, 1878.
12
£.
Ue Vthe
178 H. L. Abbot—Transmission of Earth Waves.
Art. XXIIL—On the Velocity of Transmission of Earth Waves ;
by General H. L. Assor, Corps of Engineers.
ADVANTAGE was taken of the explosion of 50,000 pounds of
dynamite at Hallet’s Point, on September 24th, 1876, to meas-
ure the velocity with which the shock was transmitted through
the ground, both across Long Island and along the south bank
of Kast River. The results were embodied in a paper read by
me before the National Academy of Sciences, on October 18th,
1876, and subsequently again read and printed as one of the
papers of the Essayons Club of the Corps of Engineers.
n the number of the London, Edinburgh and Dublin Phi-
losophical Magazine, for October, 1877, appeared a short review
of this paper from the pen of Mr. Robert Mallet, F.R.S., a gen-
tleman well known for his numerous and able contributions to
seismology. In this article, he suggested reasons which |
him to doubt the value and accuracy of the Hallet’s Point
resu
Even if I had felt disposed to enter into a controversy upon
the subject, 1 should have been quite disarmed by the conclud-
ing sentence of this article, which expresses views so just an
liberal that it may well be quoted as an exemplar of the man-
ner in which scientific questions should be considered. He
writes :
“Tn these objections I wish to be clearly understood as hav-
ing no a priord difficulty in accepting a higher velocity of wave
transit than the highest attained experimentally by myself. It
is highly probable that such may be elicited by future experi-
‘ment. But should such cases arise, their results like all great
physical truths, should only be credited upon unexceptionable
observations or experimental evidence. While feeling justi-
fied in making these objections, I wish to disclaim all contro-
versial spirit or intention; loss of sight, indeed, and diminished
energy would prevent my engaging in any scientific contro-
versy, were any called for.”
Believing, at the date of my first paper, that the data secured
at the Hallet’s Point explosion demonstrated the necessity for
more exact and comprehensive knowledge of the subject, I
have, during the past season, taken advantage of the facilities
offered by large sub-aqueous explosions at the School of Sub-
marine Mining at Willet’s Point, to continue the investigation ;
and, on October 23d, 1877, I read a second paper before the
National Academy of Sciences, giving the results thus obtained.
As only a brief abstract of this paper has appeared in print, I
ropose now to give a summary a ie conclusions suggested
y the whole series of experiments and, incidentally, to explain
H. L. Abbot—Transmission of Earth Waves. 179
my reasons for believing that Mr. Mallet has not quite under-
stood the parts of my first paper to which he has taken excep-
tion.
Limited space forbids any detailed explanation here of the
method adopted for measuring the time of transmission of the
shocks; especially as this is fully given in my printed paper,
together with the notes of the observers in full. Suffice it to
say that the instant of explosion and the time of arrival of the
tremors, were electrically recorded on the same moving paper
with extreme precision. The following table exhibits the data,
of which only the first six observations were known to Mr.
Mallet when he wrote his article.
88 3 3s Peer et .
33 Date, Observer. Cause of shock. 53 Se ; “Traperale
ok e| ° | on.
“ ele CCC
miles. sees. secs. |ft. per sec.
1 |Aug. 18, '76.'Capt. Livermore |200 Ibs. dynm. + |B} 5 + 5280 +
2 |Sept. 24,°76.\Lieut. Young /[Hallet’s Pt. ex.| 5-134/A.| 7 +634 | 3873 +
3| “ “ & |Tieut. Griffin “ «| g-330/ B.| 63 |72°3 | 8300
4; “ “ ‘Lieut. Kingman] “ “ “ | 9-333) A./10°9 |23°5 | 4521
5} “ * |Tieut. Leach “ «& & 119-769| B. {12-7 |19°0 | 5309
6 |Oct. 10, '76.'Lieut. Kingman |70 Ibs. powder.| 1°360| A.| 5-8 |inst.| 1240
7 \Sept. 6, "77. Lieut. Kin Ibs. dynm.| 1°169| A.| 1°8 | 78 | 3428
8| “ “ & ‘Lieut. Leach © & "& 1 7-169|B.| O-7% [178 |; 8814
9 |Sept. 12, 77. Lieut. Griffin [200 lbs. dynm.| 1-340| A.| 1-05| 8:8 | 6730
a a hed Lieut, h « «© "«& | 4-349} B.| O8L)17-1 | 8730
1l| “ “ & |Tjieut. Griffin /70 Ibs. powder.) 1-340| A.| 1°27] 4°8 | 5559
| Dr eee Hplt # 1:340'B. | 0-84'15°1 | 8415
Mr. Mallet’s results
mat ed
Royal Society, and unquestionabl
were reported many
years ago to the
y are to be accepted as exhib-
figures :
in sand : Be eee Boma.
in discontinuous and much shat-
te (tec i AR.
Velocity in ft. per second
- “ “
ve 5
‘in more solid granite .--. .-.--
in quarries at Holyhead (mean) 1320 ft.
The extraordinary differences between these rates and those
measured at the Hallet’s Point explosion, and the apparent dis-
crepancies of the latter among themselves, led me to so plan
the new observations as to throw light upon two points: Ist,
Does a telescope of high power detect a tremor in the mercury
in advance of the one first revealed by a lower power? 2d, Is
“ is
bd “ “cc
180 H. L, Abbot—Transmission of Earth Waves.
there a difference in the rate of transmission of the shocks, due
to differences in the intensity of the initial explosion
The method adopted was to station two observers near each
other at a carefully selected inland position; each observing a
mercury seismometer, and holding in his hand the key of an
accurate Morse register to record the instant of arrival and the
duration of the tremor. These seismometers were the same
instruments used at the Hallet’s Point explosion. They dif-
fered from each other only in the optical power of the telescope,
that designated A in the table having a magnifying power of 6,
and that marked B of 12.
A fuse in the electrical circuit which fired the torpedo, was
bedded in the cartridge of a field gun directed toward the ob-
sion of the shock, the rejection of all the observations made
with type A follows as a matter of course. They are valuable
as exhibiting the rate of advance of waves having a certain in-
Lieut. Leach, using a power of 12, recorded of the second
observation of September 12th (No. 12), “ The gunpowder wave
was peculiar, in having a much more gradual increase than has
been observed in dynamite shocks. I should say it was at
least two seconds in attaining a maximum, whereas the dynam-
H. L. Abbot—Transmission of Earth Waves. 181
ite usually reaches its maximum in a very small fraction of a
second.”
of the tremor was much less. The reason is, that the initial
earth waves were far more violent in the latter case, when the
torpedo lay on the bottom in thirty feet of water, than in the
former, when the charge was only submerged five feet in water
thirteen feet deep, and thus expended much of its energy in
throwing a huge jet of water 330 feet into the air. s
Thus it will be seen that these records, and the velocities
observed on the two days, all tend to confirm the idea that a
slow-burning explosive, like gunpowder, generates a series of
gradually increasing tremors which, at a distance of a mile, are
at first quite invisible with the less sensitive seismometer ;
and are only detected by it when near their maximum inten-
sity. If Lieut. Leach’s estimate of time for the arrival of the
orgie wave be accepted, we have, therefore, for the first
ile:
’
( Power of 12 gives 8415 feet per second.
p rpedo j “ce 6e “ 59 “ “ i
(70 lbs.) Estimated mini- | o4g9 «@ «we
er gi
m pow ves
Shallow torpedo; actual minimum t 1240 “« « “
(70 Ibs.) power gi
by No. 6and No. 11 has been already pointed out. Fora
power of 12, the table shows that for the first mile:
400 Ibs. of dynamite give 8814 feet per second.
200: 2 a one
70“ “powder (deep) 8415 “ “ “*
__If it be admitted also that the velocity of the wave dimin-
ishes with its advance, all the data become accordant. Thus:
182 H. L. Abbot—Transmission of Earth Waves.
200 lbs. of dynamite give for 1 mile, 8730 ft. per second.
oe 6s oc “ “ “ce 5 “c ¢ oe 6 ce
50.000 “* *& “ oe “cc 8 “6 8300 “be oe
% en 2 “cc se “cc 134 (74 5300 OG “cs
In fine, I believe that the following general conclusions are
suggested by these measurements: Ist, igh magnifying
4th,
are complex, consisting of many short waves first increasing
and then decreasing in amplitude; and, with a detonating explo-
sive, the interval between the first wave and the maximum wave,
at any station, is shorter than with a slow-burning explosive.
summary of the objections suggested by Mr. Mallet to
the Willet’s Point observations will now be given ; although,
in the new light thrown upon the subject by these subsequent
measurements, perhaps he might not desire to press them. __
Mr. Mallet considers that the explosion at Hallet’s Point
furnished data ill suited to determine the delicate physical
problem of the rate of progression of a wave of disturbance
through the earth’s crust, for the reason that the initial impulse
was due to the combined effect of many small charges, and not
of one single mass of dynamite; hence, as he states : :
‘\I conceive it, therefore, impossible with sufficient exacti-
tude to assign the instant at which the wave of shock sta
in this instance; and to assume the appearance of disturbed
water above the seat of explosion, or the shock felt from the
ground closely adjacent to it, as marking that instant seems to
me, in either choice, to neglect many sources of error.
ing unable to read my paper personally, he has not fully
understood the manner in which the instant of the starting of
the wave was fixed. The great mine was fired by a mecban-
ical drop, which closed simultaneously all the twenty-three elec-
trical circuits. One extra pin and mercury cup in this drop was
provided by General Newton for my use, and the signal was
absolute instant of closing the a A circuits was elevtrically
i t is impossible that this
records among themselves invalidate their accuracy. I have
just shown how these apparent discrepancies are explained by
Hi. L. Abbot—Transmission of Earth Waves. 183
the later observations at Willet’s Point; and have thus an-
swered this argument which, when the results were first col-
lated, suggested itself to my own mind.
. Mallet next mentions certain objections that show him
not quite to understand the geography and geology of the
region separating Hallet’s Point from the four stations; which,
in the absence of a map to illustrate the paper, is very natural.
The straight line to Willet’s Point follows the shore and waters
of East River, offering both a land and water route to the
wave of disturbance. The other three stations lie in the in-
terior of Long Island, with no water between them and Hallet’s
Point. The intermediate country consists of low rolling hills
formed of deposits of the clay, sand and boulders characteristic
of drift, the geological formation to which they belong. The
rated :
rock, (3) by the fall of the water; and also to the wave-diffu-
sion experienced in traversing long distances. He argues,
therefrom, that the distances were too great for satisfactory
ati Now the records show both the beginning and
end of the mercury vibration, as well as the automatic signal
sent by the explosion. The first and last determine the veloc-
184 Systems of Chemical Notation.
served; and no absolute personal equation machine was avail-
able. The officers were trained observers; and their distances
greater will be the number of important facts developed ; and
Mallet’s results and those here described to inaccuracy of obser-
vation. Differences in the material traversed by the waves, and
in the method of ubserving, may possibly explain them. If
Mr. Mallet’s health will permit him to publish the details of his
mode of observing, and to give the whole subject a general
discussion, the paper will certainly find interested readers.
Willet’s Point, N. Y. Harbor, Jan. 14, 1878.
Art. XXIII.—On Systems of Chemical Notation. Letter of M.
BERTHELOT to M. Marignac* (from the Moniteur Scientifique
of December, 1877).
has not been generall y accepted in France, it is because it has
not succeeded, so far, in obtaining the good opinion of the
majority of scientists; but, notwithstanding, imputations have
not been spared that the partisans of equivalents are anima
with a retrograde spirit.
* An answer to the ae ; e
Journal, February, ref igre tsemecag 2 Scientifique, September, 1877. (See this
Systems of Chemical Notation. 185
Allow me, in the next place, to point out some observations
on the fundamental part of the question under discussion. It
presented itself before the Paris Academy of Sciences under
two heads: the system of atoms, and the language or notation
of atomic weights. You were right in separating these two
things. I had tried to do the same thing, but with less dis-
tinctness, in my last work, On Chemical Synthesis, in whic
explained the system very fully, but without adopting it, and I
said that the notation by atoms possesses certain advantages, but
also some disadvantages. The discussion recently raised could
not, in the nature of things, assume this methodical form; but
I believe that I kept about the same ground, as I always said
that the two languages expressed the same ideas in the same
way, in most cases, except that special advantages belonged to
each system of notation. Your conclusions seem to be about
- the same as mine.
The definition of equivalents, which you accuse me of not °
giving, was nevertheless presented during the discussion, and I
will take the liberty of reproducing it: ‘ Equivalents express,
in my opinion, the ratios of weight according to which bodies
combine or substitute themselves for one another.” These
ratios may be determined by the balance with infinitely as #4
base with those of the sesquioxides. It is only in a subordinate
way, and for the purpose of giving greater precision to chemt-
cal analogies, which are often somewhat vague, that physical
oduced, such as the gaseous density,
t, the crystalline form, the molecular volume in
the solid state, ete.
186 Systems of Chemical Notation.
ratios as in the gaseous state, it is for one of the two following
reasons, either the specific heats of the solid elements change
unequally with the temperature, as I believe is the case, or two
gaseous molecules are united in one solid molecule, as the atom-
ists suppose. In either case, it seems to me that the specific
heats of solids must be put aside in the determination of abso-
lute equivalents.* :
L insist the more on this point that the new equivalents, if
we attribute to this word the extensive meanin that you
rightly give to it, introduce an undeniable complication in
chemical reactions. In your classical researches on the specific
heats of saline solution you found yourself obliged to double
the atomic weights of hydrochloric and of nitric acid and of
their salts, with the object of expressing with greater clearness
the analogies and parallelism of their properties. You wrote:
: H°Ccr’; Na’Cl’; N?0°, H*0; N*0°, K’0,
and in the same manner you were led to double acetic acid and
the acetates :
C*H’O*, H’O ; C*H*0*, K’0.
The same necessity has been felt by all those who have had
to express the equivalent ratios of acids, of water and of bases,
* I cannot accept your opinion on the absolute value of the law of Weestyn in
calculation of the specific heats of solid . You know very well
that M. Kopp, who went to the bottom of this question in 1864, found himself
obliged, in verifying this relation, to attribute to the solid elements in their com-
bination specific heats varying from 6°4 (silver, chlorine, nitrogen), down to 4
(oxygen), 2°3 (hydrogen), and 1-8 (carbon).
Systems of Chemical Notation. 187
as may be seen in the remarkable papers of Mr. Thompson on
Thermo-chemistry, and even in the new edition of Gmelin, now
cringe) in Germany (see, among other things, iodie acid
oO; HO).
believe that it would be advisable, in the future, to set aside all
promise such rich harvests of discoveries
Benzeval-sur-Dives (Calvados), August 10th, 1877.
ANSWER oF M. MARIGNAC.
lot, while opposing this doctrine, seems to me to confirm it, as
e was obliged to give a double definition. Sometimes these
itutio
ea st ~~
still this is not the value that has been chosen for its equivalent.
188 Systems of Chemical Notation.
As M. Berthelot himself observes, we only differ in the opin-
ion that each of us has formed on the part and relative im-
acid. But if this has led me to group together two molecules
of an alkaline chloride or nitrate, I was obliged, for the same
reason, when taking the specific heats of sulphate of alumina or
of alkaline iti i
and phosphoric acid PhOS, and that the equivalents of alumin-
be and phosphorus should be modified accordingly.
ties of bodies by referring them to chemically equivalent
weights, in cases where these — neither to molecular
weights nor to the equivalents usually adopted, but we cannot
conclude from this “that those weights ought to be adopted as
symbols of notations,
M. C. Lea—Reactions of Silver Chloride and Bromide. 189
Apart from all these things, I agree with M. Berthelot that it
is not advisable to exaggerate the importance of these ques-
tions, the solution of which cannot affect the important laws
and theories of chemistry, and about which we can only reach
a conclusion when we have arrived at more complete knowl-
edge of the molecular constitution of compound bodies. This
constitution itself will be doubtless revealed to us by researches
on molecular mechanics, such as those on Thermo-chemistry,
through which this eminent scientist aids so powerfully the
advancement of science. ~
Art. XXIV.—On some Reactions of Silver Chloride and Bro-
mide; by M. Carey Lea, Philadelphia.
long continued action of nitric acid was there any decomposition
of the darkened chloride, and even then, traces only of silver
were taken up by the acid. :
It therefore appears that the substance produced by the action
of light on silver chloride is of a much more permanent char-
acter than in the case of the other silver haloids) Some other
reactions noted in the course of the examinations which appear
not devoid of interest, are given below.
altered substance, and completely change its character.
As to the first point—the small proportion of material actually
altered by light. It is generally thought that silver chloride ts
by the action of light to a sub-chloride containing half
190 M. C. Lea—Reactions of Silver Chloride and Rromide.
as much chlorine as the normal white chloride. _ Yet the loss of
chlorine has been found too small to be weighed. Fresenius
doubts if a loss in weight could be detected by the most delicate
balance, and Von Bibra in the investigation above referred to,
could not find the slightest loss in weight. .
With a view to obtain some quantitative indication in the
matter, the following determination was made.
Silver chloride was precipitated with an excess of hydro-
chloric acid, was well washed, and exposed to bright sunlight
for five days. During this time it was spread in a very thin
layer over the bottom of a large white porcelain basin, was fre-
quently stirred up to bring constantly new surfaces to the
light, and was kept moistened with water.
Of the resulting dark powder two grams were taken and
were thoroughly treated with sodium hyposulphite to remove
the unaltered chloride. Previous experience had shown that
extraordinary precautions were necessary to effect this thor-
oughly, as the removal of the last portions of normal silver
chloride is very difficult. Accordingly the strong solution of
hyposulphite was many times renewed, each time being left to
act for from twelve to twenty-four hours. Finally the gray
residue (metallic silver) was washed, dried and weighed, an
found to amount to twenty-one milligrams.
It thus appears that as the result of five days’ action of
strong sunshine, with frequent stirring up and mixing to bring
fresh portions to the light, about one per cent only of the silver
chloride was acted upon. And if we suppose this action to con-
sist in removing one-half the chlorine, then the whole loss 12
weight by the action of the light should be but little over one-
tenth of one percent. This proportion is of course not inap-
preciable, and the observations of Fresenius and of V. Bibra
above quoted must be taken as referring to shorter exposures.
It was mentioned that another difficulty in verifying the
nature of the action of light lay in the fact that those sub-
stances which can “is or dissolving out the unaltered
chloride, also unfortunately attack the altered substance.
The two reagents most effectual for this removal are sodium
ts s The facts here mentioned lead to the curious reflection that the permanency ¢
ordinary : prints is greatly diminished by the fixing process. FOF
M. C. Lea— Reactions of Silver Chloride and Bromide. 191
When cold nitric acid, sp. gr. 1:28, is poured over a goansity
C
quickly whitened by aqua regia, it is reasonable to conclude
that the dark matter contain less chlorine than the normal,
and is either a subchloride or an oxychloride. Beyond this,
we know nothing with certainty
When the dark substance was boiled for several minutes
with the same nitric acid, no silver was extracted. But when
the vessel was placed on a sand bath and kept at or near boiling
point for eighteen hours, renewing the acid as it escaped, a dis-
tinct effect was produced. The substance became a little lighter
in color, and the acid was found to have taken up enough sil-
ver to show a strong opalescence by addition of hydrochloric
acid ; not enough however to give an immediate precipitate.
monia and sodium hyposulphite have this in common,
that both leave metallic salien behind when the darkened
chloride is submitted to their action. In the case of the sodium
salt, it is of course understood that it is presented in strong
solution and very large excess.
Silver Bromide.
Silver bromide was precipitated with excess of KBr and
well washed, and exposed to light.
When cold nitric acid, sp. gr. 1°28, was allowed to stand for
‘One minute over the darkened bromide it took up silver abun-
dantly. Allowed to act for an hour at a heat considerably be-
low 212° the color of the darkened bromide had considerably
changed and at the end of seven or eight hours, com plete decom-
position had taken place. The resulting AgBr is lemon yellow
and has more the general appearance of iodide than of bromide.
Philadelphia, Jan., 1878.
influences. To a considerable on this v
substitution of gold for the metallic silver. <
The use of a fixi “reatment can of course never be dispensed as it is
essential to remove the unaltered chloride. But it is evident that if a substance
sage be found which would remove the te : chlo mechs nega reg
wh by li a great advan
ing that which has been da pores fem ti apgardiaggir: Ges
Stopped when the right strength was obtained, without being
allow for nite effect sf the fixing agent, and the print obtained w
probabl: be alwa: perfectly permanent. ~ ee :
The fact that both sodium ky posulphite and ammonia in removing the unaltered
chloride, reduce the altered to metallic silver, explains why the gold toning opera-
tion succeeds much better when applied after the fixing operation, than before it.
192 A. 8. Kimball—Journal Friction at Low Speeds.
Art. XXV.—On Journal Friction at Low Speeds; by A. S
KIMBALL, Professor of Physics in the Worcester Free In-
stitute.
experiments consisted of—Ist. A pair of cone pulleys giving
i the work shop.
w
with a pulley by which it was driven. The journals on this
shaft were seven-eighths of an inch in diameter; they revolved
in cast iron boxes three and .one-half inches long, truly bored
and polished. A thin cut was planed from the upper half of
each box, so that when resting upon its journals it was not
quite in contact with the lower half Above each box was 4
lever of the second class, by means of which it was possible to
apply any desired pressure to the revolving journals. The
A. 8 Kimball—Journal Friction at Low Speeds, 198
course of the experiment is obvious. The experimental shaft,
loaded with a known weight, was driven at different speeds, the
rewired power noted, and the coefficient of friction calculated.
he results of seven series of experiments are shown in the
following table, in which the first column shows the velocity of
the circumference of the journal in feet per minute, the seven
following columns giving the correspunding coefficients of fric-
tion. Since it was found impossible to maintain the same state
of lubrication for any great length of time, every series which
could not be completed in one half day was left unfinished.
Taste I.
Af a. b C. d. é. Fo g-
5 is (-° aes 0° WPS 6: Hines 7 SPC) | RT a |
2°17 “153 150 l 131 129 114 109
5°15 122 128 122 “080 "080 097 “083
10°99 “089 086 “069 067 080 060
Sd ae ot "068 058 “066 052 053
42°86 “068 “060 "045 "041
In spite of the irregularities to be seen in this table, the law
as stated above is clearly shown. Some of the discrepancies
are doubtless due to variations in the state of lubrication of the
journals. The pressure on the lower boxes in series a, ¢, d an
e, was 180 pounds; in series 6, fand g, 210 pounds. Ina, 8,
c,d and e, the journals were lubricated by wiping them with a
handful of waste saturated with sperm oil. In / and g, as
experimental shaft:
Taste IL
Speeds, 59’. 217. 616 10°99! 19°71’. 42°86"
(55 4°3 3°5 2°5 2-0 2-0
54 4°2 3°6 26 1°9 19
. 5°38 4°3 3°6 2°5 1°9 1°9
Differences | 54 44 3°5 2°5 2-1 1-9
ie PES wuae ers ae 24 19 2-0
: 5-5 4°3 3°5 2°3 2-0 2-0
5-4 4°3 3°6 2°5 2-0 2-0
54 4°3 3°6 2°5 1°9 1°9
Averages, 5°41 4°28 3:65 2°47 1°96 1-96.
Coefficients, 187. "148 "122 "086 068 068
The variation in observations taken at the same some is
nearly identical in every series with that shown in Table
Am. Jour, So. —Turep Serres, Vor. XV, No. 87.-- Manon, +78.
13
.
194 A. S. Kimball—Journal Friction at Low Speeds.
In order to eliminate as far as possible gradual changes in
the condition of the rubbing surfaces, the following order of
observation was adopted in each series. Calling the slowest
speed No. 1, four observations were made alternating
between Nos. 6 and 1.
“ .T4 2.
7. BE ees
(74 6
5, ete.
1,
a
&
me ho OH Ee
a
“cc 6.
lower speeds were decisive. The most probable values of the
coefficient as shown by a graphical construction of all these ex-
periments is shown in
BLE III.
Speed, Noe 48 47 10 AG ay 40" 40. 60° 00
Coefficient, 150 *122 -104 -093 -079 -066 -058 ‘054 053 °052 -051 050
Thus we see that the conditions under which journal friction
usually occurs are such that the maximum coefficient will be
found at a very low speed. While using a journal 6” in diam-
is great in comparison, or on the other hand so great as to pro-
duce abrasion. An experimental examination of this point
turbing slightly the adjustment of the machine. These results’
as the specific pressure on the journal increases even when the,
pressures are quite large.
Brightness of the Satellites of Uranus. 195
Taste IV.
Pressures are given in pounds on a square inch of longitudinal
journal section.
Fr; Coef’ts at 59” per min. Coef’ts at 2°17’ per min.
"154 "159 136 0
23°5 15
36°8 157 "156 138 130
50°1 149 147 119 124
63°4 149 153 117 127
76°7 153 “152 108 126
90°0 151 "150 109 123
103°3 155 "150 111 127
116°6 149 "145 113 124
129°9 147 "146 112 "123
143°2 145 "146 113 121
156°5 147 "147 113 124
169°8 146 "146 112 121
183°1 145 "148 109 124
196°4 144 "145 111 125
The larger part of the experiments referred to were made by
esper, a student of the Institute, whose patience and care
deserve especial mention.
ArT. XXVI.— Observations of the Brightness of the Satellites of
-_ Oranus.
[Communicated by Rear-Admiral John Rodgers, U.S.N., Superintendent U. 8.
Naval Observatory.]
It was surmised by Professor Newcomb that the brightness
of Ariel varied in different parts of its orbit (Wash. Ast. O
1874, Appendix I, p. 48,) and that it was least bright in
p=180°+ duri 74. koe
There have been observed in 1874-5-6-7 nineteen position
angles of Ariel: of these, seven were 180°, and twelve
were 0°+. : :
A better test is the following: on fifteen nights this satellite
was bright enough to allow of measures of distance. On six 0
these ee e nine the
196 Brightness of the Satellites of Uranus.
Dr. H. C. Vogel has suggested that Titania also is of varying
brightness in different parts of the orbit. arly attention was
ven to this point. The following extracts from the observing
Cooke may be of use, when an exact photometric determination
comes to be made. The weight indicates the steadiness of the
images, five being perfectly steady. The epee given are to
the nearest degree in p and nearest second in s.
1875. Jan. 26. Titania; p=260°, s=19”. We 4, Titania is
fainter than I have ever seen it—HN.
1875. March 4. Four stars visible besides Oberon and Titania.
Oberon, p23ie: s= 26°
Titania, p= 184° gosz 85"
Star 1, p= 350°+ s= 80°
Star 2, p= 20° s= 100’4
Star 3, p= 130°+ s=130°4+
Star 4, p= 95°+ $= 200°+
Order of brightness ; 4, 1, 8, 2; and 2 somewhat brighter than
Titania.—HN.
1875. May 25. Oberon: p=230°, s=31”.
Titania: p=21°, s=30".
on very faint [and therefore as nothing is said of bright-
-_ ci ptsies Titania brighter than Oberon at same dis-
S76. fan. 14. Oberon: p=11°, s=28"")
Titania: p=48°, s=2T7" §
Titania much brighter than Oberon. Moonlight.—HN.
1376. Jan. 20. Oberon: p=821°, s=27”
Titania : p= 186°, s=34”
| Ser of Oberon quite difficult [and of Titania not so. }—HN.
1876. Jan. 25. — ; p=181", s=44” Wt=2.
= 852°, s=31"
Oberon easier = see (brighter) than Titania.—HN.
1876. Jan. 26. Titania in p=310°, s=16”. Wt. 5.
— is son the smallest distance at which Titania has been
1876. Jan. 31. ~— a =716°, s=17” | w
riel: p=29°, s=12” Sut
Titania is at ot twice as bright as Ariel. Ti ~— is
decidedly brighter than the satellite of Neptune. It is easier
to see (under these conditions, Wt=5) within 16” of Tenino:
than the satellite of Neptune within 16” of Neptune.—HN.
1876. Feb. 2. Oberon : p=888°, s=88" |
tlania; p=T°, s= =34"{
After careful examination with 800 A and 400 A, I cannot
decide which is brighter, Oberon or nee but if there is any
differe’ Titania is the brighter.—
Brightness of the Satellites of Uranw; - 197
1876. Feb. 18. Oberon : : ee it
Titania | Wt=4t.
1876. Feb. 20. Star near aco - p=89°, s= 27’. Wt=1.
This star is about ‘she brightness of ey. = Titania.
an Oberon Lae ice for Thence p=lbl°+)
1876. March 3. Two stare, eo Uranus, fos slightly
righter than Oberon. Star = 280°, s=
Sta : ere s=50” estinated.
Not much difference in the brightness of Oberon ani. Awana.
[For Oberon p=236°, for Titania p=268° +}.
Umbriel: p=23°, s=20" Wt=3.
Ariel: p=173°, s=13” “a
Umbriel i ‘5 more steadily seen than Ariel but nat aed more 80.
Then reduced aperture to. fifteen inches. _Umbrie was cer
tainly seen and its position eould haye been mcngarel poy
was not certainly seen. Sky
azy. Bright m
Mar. 4. Ariel: p=’, s=18". “Mooolightand a
ta:
Titania is decidedly prance han Ob her f
1876. March 18. Oberon? ps , 8 cy 05'S
Titania: palo’, s=80"S oe eda
Oberon is Baki? than Titanta,—H. Aine agi ike’ oy.
1876. March 14. a R penes g=1
mbri pale’ s=19"
Titania : p=126°, s=18"
one speci e327"
1876. March 22. Conon Ea =78°, cit ne Se
sa Titania : p=161°, s=26" vat ene
Titania much ogee pai, “3, ue
1876. March 23 : p= s if :
SS Titania : es pt We=8
Oberon ogi nae than Titania —# j u
e we
Titania: paar om’
Oberon brighter than Titania.-# <a
It is not desirable to draw any’ es aaticiaual ab
vations as yet. They are here recorded as hey we of ser-
Vice in photometric observations, and the sare
as occasion offers.
tees E F. Smith— Decomposition of Chromic Iron.
Akt. XX7A new method for - ante of Chromic
fron > by Epear F. Sur
» Recen*ry I was’ led to try the action of bromine and sodium
hydrate Hy nae fuivétibed chromic iron, and as the amount of
un extracted in this manner was rather surprising, the
ia followin oi dx penitent were made, to ascertain a effect. bro-
: mine aloe would have upon the same substan
» L Mocerate rately fine chromic iron (+1500 sine was placed in
a tube o hard ‘and after adding dilute bromine water and
roles | the tube, the latter was placed in an ai ir-bath and <<
a twele Bi 2, at a temperature about 180° C. When cool
thet its contents sear upon a “filter.
- The tubhele jeaided was théroughly washed by decantation,
oe and upe the filter, with hot water. The filtrate after concen-
peal vas treated yf a slight excess of ammonium hydrate,
; he -precipi of aluminum hydrate, etc. The Jat-
solored filtrate then vs
Panag
The predpitate formed, after protracted digestion, was sltdveod
to settle key the dei ar Itered. After washing, the pre-
was'"dissol lved few drops of dilute Agee
cid an ‘ecipita “Operation was repeated and the
recipit 5 ‘Ynally transferred to a filter, washed, dried and
ed. The amount of ahresne pete found | ereee
E. F. Smith— Decomposition of Chromis, iron, 199
stance appeared to be perfectly desoreppnet, the solution was
remove Ac ge the sat and evaporatedin a — to expel
the large excess of moet upon the, spradual. disgp distnnearance of
which a dark powder showeditself., The solution was st strongly
diluted with water and filtered. The insolubje pesidue was
thoroughly washed with hot gyater. Dried am Eva this
weighed ‘0140 grams.
condition. To this end the:material that h
an impalpable powder in an, agate mortar was €le-~oted, hen
dried and two distinct portions of 1600 grams e:ch placed in
good hard glass tubes. To each portion was acle] 4 rather
large quantity of bromine water_am from ten to Wave e dcppe
af bro omine. Both tubes were heated for one day % 139°
For two successive days the temperature was mailsined at
170°C. At the atone of a third ga ox of i fies
and opene
was removed from the oven ) ape eer to I ra
complete was to have the chiens iron in an foo: the
The whole was pou a beaker * Sorated,
water added and PN ag The eet was thorou ile ashed,
dried and ignited, then transferred to a beaker an ‘pith
dilute hydrochloric acid. The entire mass dissol¥' at
and without a residue. The veer eatiahtd was, ierefore
complete
The Bitcats from the iron oxide was evaporated ‘a me
dryness after the addition of an excess of ammonium iydrate,
then diluted and filtered. The sokivor was reduc with
The second tube, evel at On ng pe the fst id
a large amount of separated ferric oxid
off the chromium solution also dissolved very readily warm,
dilute hydrochloric acid, oe ‘pot the least trace o° Lig e.
ae from. this, after be mg. similarly treated Babove,
lelded 62:83 chromium ox!
. These results accord with those of Garrett, who an), bec
ore from Texas, red nisi ‘ btained a about GB: cent
same
chromic oxide. & yey te hae ad
200 EB Wilson— New genera of Pyenogoni
scdetes al te ‘water were heated t 125° C., but invaria-
bly exploded before wae decomposition was completed, and
therefore 10 farther attempts | were made to use the alkali to
ons me
» Allthat is to effect the complete decomposition of
chromic i Ne sentiag this method is that the substance be ex:
ingly fine card, that the same be exposed with bromine toa
temperaturef 180°C. from two to three ders The addition
of near dogs pens anton the decomposition
idedly
Dacincd by the ignitioks of the
may be brought into solution again by
| acl eat m2 ue in a beaker.
of Pennsylvania, Dec.
Descriptions of two new genera. of Pyenogonida ;
Witson. Brief Contributions to, Zoology
certain genera (e. lene
ulated to the hae us and
ann by means of which le
marillare tes Tiveitebeitll -
250, Pi be 1874 (non Stimpson)
E. B. Wilson—New genera of Pycnogonida. 201
Oculiferous segment broad, as long as the two following seg-
ments taken together, not emarginate between the bases of the
antenne. Neck swollen. Posterior segment of body very
slender. Abdomen rather more than twice as long as broad,
slightly bifid at the extremity.
Ocutiferous tubercle prominent, acute, placed on the anterior
portion of the first segment. Eyes four, ovate, varying in
color from light brown to black.
Rostrum very large, longer than the oculiferous segment, con-
stricted at base, thus appearing somewhat clavate. The extrem-
ity is subglobose.
Antenne hairy, long and slender, their bases closely approxi-
mated. Basal joint. extending beyond extremity of rostrum.
Chela stout, hairy. Dactylus very stout, smooth on margin.
Ovigerous legs stout, roughened by
minute tubercles, the outer joints with
many strong hairs, most of which are di-
rected backward. The two basal joints
are very thick; the first is shorter than
its width, the second about twice the
rst. The succeeding joints are much
more slender. The third is nearly two
and a half the second, somewhat cla-
vate, and suddenly constricted a short
distance from the base. Fourth joint
half the third. Fifth considerably less
than fourth. Terminal joint much
Fig. 1.—Anoplodactylus witus.
Terminal joints of leg; 6, ov-
igerous leg.
considerably longer and clavate. The three following joints
are much longer, the sixth being the longest. The seventh
is a series of much smaller stout spines. The dactylus is stout,
about two-thirds as long as the propodus. The whole surface
of the body is scabrous. ‘The legs bear a few scattered hairs,
which are more numerous on the outer joints.
e genital orifices are situated on the lower side of the
second joint of the legs, near the external margin. The sexes
resemble each other closely except in the absence, in the male,
of the ovigerous legs. ‘The males are also, as a rule, slightly
larger than the females. ‘It is most frequently deep purple
in color, but gray and brown specimens are often met with.
( Verrill).
This species is common in Vineyard Sound, but does not
202 F. B. Wilson—New genera of Pycnogonida.
near the base of the third joint for an articulation.
Length of body in largest specimens (inclusive of rostrum
and abdomen), 7 millimeters. Legs, 30 millimeters.
Pseudopallene, (gen. nov.).
Body robust. Neck broad and thick. Rostrum more or less
acute. Antenne three-jointed, chelate. Palpi wanting. Oviger-
ous legs composed of eleven joints. Legs nine-jointed. Dactylus
lus is armed with two very large auxiliary claws. A Pallene,
probably be referred to Pseudopallene. Having seen no speci-
mens of these species, I have been unable to verify this.
O
collection of the Peabody Museum, dredged by the United States
ish Commission in Johnson’s Bay, near Eastport, Maine, in 12
fathoms rocky bottom. Stimpson records it from deep water off
rand Menan, “on Asridie callose.” His description being in-
y very broad, oval, neck not constricted. Oculiferous
tuburcle small, rounded four, ovate, light brow
Oculiferous segment half as long as t nd and
J. L. Smith—Tantalite from Alabama. 203
Rostrum as long as oculiferous segment, with a constriction
on each side below, giving it the appearance of being articu-
lated at this point, acute-conical, with a rosette of filamentary
processes around the terminal mouth.
Antenne hairy, stout and swollen, about twice as long as the
rostrum, tipped with amber color. Basal joints enlarged near
their attachment. The second joint has a prominent rounded
tubercle on the lower end, behind which the dactylus closes.
Ovigerous legs slender, eleven-
jointed, terminal joint ‘elaw-like,
trifid. Fifth joint somewhat cla-
vate, considerably smaller than
the fourth. The four outer joints
are armed with three or four stout,
smooth, curved spines.
Legs very stout, the three basal
joints short, overlapping each other
in an imbricated manner. Fourt
joint as long as the three basal
joints taken together, much di
tended by the ovaries in the speci- Dias
men described. Fifth, aslong as Fig. 2
the fourth but much more slender. 4 Terminal apart Se
Sixth, longer and more slender. eee a
Seventh (tarsus) very short, nearly triangular. Kighth slightly
curved, armed with five or six spines on the inner (concave)
margin. Dactylus slender, curved, acute, without accessory
claws, about two-thirds as long as the preceding joint. :
All of the legs bear more or fewer prominent, conical, spiny
tubercles. These are arranged in longitudinal rows on some
of the joints, particularly on the fifth and sixth, which appear
deeply serrate on the external margin. The entire surface of
the body is rough, and more or less hairy.
Genital orifices small, on the second joint of the legs.
Length (inclusive of rostrum and abdomen) 3 millimeters.
Legs, 7°5 millimeters. Ovigerous legs, 3°7 millimeters.
_—Pseudopuliene hispida.
Art. XXIX. —7anitalite from Coosa County, Alabama, its mode
of occurrence and composition ; by J. LAWRENCE SMITH,
Louisville, Ky.
WHILE coluinbite has been long known from a number of
localities in the United States and at some of them it is found
in great abundance, the related mineral tantalite has never
been identified, until recently I proved the fact of its eggs BOE
in Alabama. Professor Kénig has described (Proc. Acad.
204 J. L. Smith—Tantalite from Alabama.
Nat. Sci. Philadelphia, 1876) a mineral which he considered to
be tantalite from Yancey County, North Carolina. There must
however have been some mistake about the matter, for he states
the specific gravity of the mineral to be 5807. If this deter-
mination was given correctly this could not have been tantalite.
I have found columbite from the North Carolina localities with
specific gravities from 5°6 to 6°38, varying according to the
amount of tantalic acid present with the columbic acid. There
is no instance. that I know of where tantalite has as low a spe-
cific gravity as 7. Z
I am indebted to Professor Eugene Smith, State Geologist of
Alabama, for the specimen of tantalite that first came under
my observation; he suspected it to be tantalite and sent it to
me for verification; he had obtained the specimen from Judge
Bently, to whom we owe what we know about the manner of
its occurrence.
It is found in Coosa County, Alabama, detached from any
rock, lying loose with “bowlders” (as Judge Bentley calls
them) of granite more or less disintegrated. As, however, this
region belongs to the older series of rocks (Professor Eugene
Smith has not yet explored it) these blocks of granite are doubt-
less not bowlders, but detached masses, weather worn. They are
found both under and on the surface for miles, ranning north-
east and southwest. cross these in a direction northwest and
southeast runs a ridge filled with quartz and flint rocks and at
the intersection of the two, over about an acre of surface, some
fifty specimens of tantalite have been collected, from the size
of a pea to a lump one and a quarter pounds in weight. —
araci -emens.—They are irregular masses, without
the slightest indication of crystalline form, just such pieces as I
have obtained from the locality at Limoges; they are more or
ess rounded, with a ready cleavage in one direction; the spect-
mens although long exposed, have undergone but little altera-
tion, as indicated by examination made on several specimens.
The specific gravity varied from 7°305 to 7°401.
n analysis it was found to consist of:
ee 9°65 :
eee Lc. pieces 1°10 } 81°62 metalic acids.
Stee Se ge
Manganese protoxide, ..____- 3°72
Tron me A ce 13°51
Copper Gxule,. 6... “89
99°74
The tantalic acid contains very little columbic acid.
_ Judging from the discoveries already made, and the large
size of some of the pieces of tantalite, we may expect some
important results from the future explorations in Alabama.
Ee
W. G. Mixter—Amylidenamine Silver Nitrate. 205
Arr. XXX.—On Amylidenamine Silver Nitrate; by
W. G.
MIXTER. Contributions from the Sheffield Laboratory of Yale
College, No. XXX.
STRECKER (Liebig’s Ann., cxxx, p. 220) states that silver
nitrate produces in alcoholic solutions of valeralammonia, a
white precipitate, which slowly turns black in the cold, but he
says nothing as to the composition of the substance. I have
obtained what is doubtless the same compound by the spon-
taneous evaporation of alcoholic ammonia solutions of valeral-
ammonia to which an excess of silver nitrate had been added.
and then adding thirty grams of hydrous valeralammonia, from
105
for
Ist Series Qd Series. ©, ,Hg3N,0s4g-
Carbon. ...... 4211 42°26 3
Hydrogen ..... _ 7°89 7°90 7°76
Nitrogen ...--. 3°24 13-18 13-18
paves: 25°26 25°19 25°41
Oxygen ...... . [11°50] [11°47] 11°30
100°00 100700 Re -
The equation 3(C Tr ,ONH,)+AgNO =C,,H,,N,0,Ag
+3H "O doabilees represents the formation of the substance
in question. It is not possible to give a gravimetric proof on
206 W. G. Mixter—Amylidenamine Silver Nitrate.
account of some decomposition which occurs during the evapo-
ration. The compound dissolves with but partial separation
of silver in boiling water. The clear aqueous solution evapo-
rated on a water bath leaves a slight black residue and a very
soluble crystalline mass, which contains silver, reacts for am-
monia and gives red fumes when heated with oil of vitriol. By
distilling with ammonia water crystals are obtained in the distil-
late which reduce silver. Hot dilute acids decompose it with
the separation of an oil which has the odor of valeral, and hot
oil of vitriol evolves nitrous fumes from it. The reactions
show that the substance contains the amyliden, ammonio and
nitro groups and that it is an amine analogous to Rose’s
3NH,AgNO,, thus:
H,N C,H, ,—NH
H,N } AgNO, C,H,,=NH } AgNO,
H,N (sooNE
The name amylidenamine silver nitrate is perhaps the best
that can be given to the substance until more is known of its
constitution. If the corresponding ammonio compound be
gentammonium nitrate (Graham—
Otto, iti, 840) the derivative from valeralammonia may be
arded as di-amylid i tamylid ium
= 5
Oo af
nitrate, thus:
Ag Ag
I |
a0 —O-NO, C,H,,=N—O-NO,
|
H,N C21, NG
l
“ C,H, ,=NH,
Amylidenamine silver nitrate is insoluble in water, ammonia
4 ; :
Calculated for.
Carbon 32.023 4:99 Oo, 65°79
drogen ____. 11-25 ot 10°97
Nitrogen __.__. 9°53 Ny 9°21
Sulphur _...-._ 14-01 Ss 14°03
99°78 100.00
A, H. Chester—Crystallization of Variscite. 207
The results indicate a mixture of C,,H,,N, and 2(C,H, ,S).
The oil has the odor of thiovaleral, and decomposes when dis-
tilled. Hydrochloric acid added to the concentrated etherial
solution of it produces a white curdy mass which was not ob-
tained free from adhering oi]. This last product is soluble in
alcohol, ether, and with the separation of an oil in hot water.
Platinic chloride produces at once in the alcoholic solution a
small light yellow precipitate and in a few minutes a dark
brownish red curdy precipitate which yields to water, platin-
chloride of ammonium. ‘The red precipitate after washing
with water and alcohol, reacts for platinum, sulphur and a hydro-
carbon. Lack of material prevented further investigation of the
oe a from amylidenamine silver nitrate by the action of
ydrogen sulphide.
New Haven, January 10, 1878.
ArT. XXXI.—WNote on the Crystallization of Variscite ; by
ALBERT H. CHESTER.
A MicroscoPic examination of certain small crystals of the
mineral variscite from Arkansas reveals the following facts with
reference to its method of occurrence and crystallization.
The crystals are rarely distinct, but are usually found in
complicated groups, sometimes forming clusters of a sheaf form.
Very rarely single prismatic crystals are found, sufficiently dis-
1. 2. tinct to admit of measurement.
Fig. 1 AoE the most common
ee form, belonging to the orthorhom-
bic system, and showing faces of
J, %, it and O. In this crystal
I,f=114° 6’. In general but
one termination is seen, but crys-
tals showing both ends aré some-
times found lying on the quartz
matrix, the bases being similar
to each other. The face 7 is
very small and therefore easily
overlooked, and 7% is about the same size as J, so that these
crystals may readily be mistaken for hexagonal prisms. Crystals
showing a simple termination like that in fig. 1 are seldom seen.
More frequently the basal plane is like fig. 2, or still more
complicated. ‘These planes are often covered with a thin
Opaque white coating, probably of quartz. :
striking peculiarity of this mineral is its high lustre, like
that of beryl, which it much resembles when viewed under a
low power.” The crystal figured above is 0°3 mm. in diameter,
and is about the average size of those examined.
Hamilton College Laboratory, January 19th, 1878.
208 Scientific Intelligence.
ArT. XXXII. —Discovery of a New Planet ; by C. H. F. Perers.
(From a letter to one of the Editors.)
In the night of February 3-4, in revising one of my Zodi-
acal Charts, I found a star that I could not have omitted, as
being of the tenth magnitude. Some measures therefore were
immediately taken, which showed that the object is a planet
hitherto unknown. Its position was,
Feb. 3, 13" 46" 478 m. t. a@=10" 1™ 38*-08. 6=-+11° 23’ 34”°1,
from ten comparisons with Dm. +11°.2173,—the place of this
star being determined by differentiation from LL. 19882, of
which there are several modern determinations, viz: W. 105.91,
R. 3090, Arg. +11°.2190, Berlin Mer. Cir. in A. N., No. 1388.
Last night it clouded up, before the planet could be re-ob-
served. But from the measurements of the preceding night fol-
lows the hourly motion —1*-75.and 4-270, or the daily motion
—42s and +11’, so that there will be no difficulty in finding
the planet again, it having now already entered upon Chacor-
nac’s chart.
There has been some confusion of late in the numbering of
planetoids, arisen from neglect of prompt communication. But
it seems this new member will’ have to carry the number 180.
If the priority of discovery remains to me, I propose the name
Hunike, in commemoration of the glorious victories won by the
Russian armies in their strife for humanity.
Litchfield Observatory of Hamilton College, Clinton, N. Y., Feb. 5, 1878.
ed
SCIENTIFIC INTELLIGENCE.
I. CHEMISTRY AND PuHysics.
y
ties, founded upon the well established a
‘d- not miscible with a given liquid are distilled with this
ui gv
liquid, the quantity of the two bodies in the distillate, is, at @
constant temperature of ebullition, in a constant ratio. Since, 00
the mechanical theory of gases, the vapor-tension, other things
being equal, depends on the number of molecules which the vapor
sions of these constituents in the vapor mixture. results
confirm completely the hypothesis and establish the ———
law: The ratio of the quantities of the substances in the disti
late, expressed in molecular weights, is equal to the ratio of the
vapor-tensions of these constituents in the vapor mixture, meas-
Chemistry and Physics. 209
ured at the temperature of ebullition. If g is the weight of one
substance in the distillate, m its molecular weight and p its vapor
tension at the boiling point ¢ and under the barometric pressure
6; and if G be the weight of the other constituent, M its molec-
ular weight and P its vapor tension also at the boiling point, we
have, by the above law,
An extended series of experimental results are given, which estab-
lish the equality of these two ratios. From this equation it fol-
lows that M= =_— If one of the substances be water, m= 18,
_ t= 98°2°, the tension of aqueous vapor p = 712-4 mm. and hence
the naphthalene vapor tension P =6 —p = 733—712°4 = 20°6 mm,
The molecular weight of water m= 18. Substituting these values,
_ 18X8°9X712°4 _ ‘ ees oat:
M = Tsog = 118 The formula C,H, requires 1
This is an extreme case, but the result shows that the above
formula, and not any multiple or submultiple of it, is correct. The
method is capable of indefinite extension.— Ber. Berl. Chem. Ges.,
X, 2098, Jan., 1878. GARE ALE oe
2. Ona new Oxide of Sulphur, Persulphuric oxide.— BERTHE-
Lor has described a new oxide of sulphur which he calls persul-
.
phuric oxide, corresponding to perchromic and permanganic
: ric
of absolutely dry sulphurous oxide and oxygen uty oA §
e electrolysis of con-
centrated sulphuric acid, and has been confounded with the so-
s also fe
les, many centimeters long and of an apprec -
often crossing the tube. It resembles sulphuric oxide, but th -
ter is opaque, in finer needles, shorter and narrower. It
4 considerable vapor tension and sublimes spon
* Ann. Chim. Phys., V, xii, 463, December, 1877.
Au, Jour. Sct.—TaIrD sees ts Vou. XV, No. 87.—Mancu, 1878.
210 Serentific Intelligence.
tubes containing it. Its composition was determined by synthe-
sis and by analysis. Synthetically, the residual gas after the ac-
tion was withdrawn by a mercury pump and measured; it was
one-eighth of the original gas, corresponding to the equati
foe ; or in volumes 4-+-4 originally and 1 finally.
Analytically by opening the tube under a titered stannous chlo-
ride solution, the excess of oxygen was determined; and y pre-
cipitation with barium chloride, the sulphuric acid was ascer-
ained. The ratio obtained was SO,:O::10:1; the theoretical
ratio 8,0,=(SO,),: O or 160: 16. The same result was reached
oxygen rapidly in presence of platinum sponge. Treated with
sulphurous acid, hyposulphuric acid is formed. Barium hydrate
gives barium persulphate, which is soluble in water—C. R.,
hundred cubic centimeters of this water distilled from pure baryta,
ecm
gave a distillate in which platinice chloride produced a precipitate.
— Ber. he B.
ae : . : = Ks eee erg Bae
With zine dust, it gives fluorene, and with lime, diphenyleneketone.
Chemistry and Physics. 211
Hence the _— is diphenyleneketonecarbonie acid, with the formula
CAN Go
cu , and the hydrocarbon has the constitutional formula
osy CO
C,H.—CH—C
et | The authors give the hydrocarbon, therefore,
C,H,—-—-C
the name fluoranthrene, ee attention to the fact that Schmitz
has proved the identity of ier’s fluorene with diphenyleneme-
thane. In a postscript, Fittig says that he has just seen the paper
of Goldschmiedt upon idryl, and has no doubt that the hydrocar-
n C_H. there described is identical wr his rina eran
5. 5. Simple synthesis of Formic acid. = Mae and Denes Shine
Studied the reaction of carbonous oxide upon caustic alkali, ob-
an instructive class experiment. This synthesis is important in
view of the fact that the hydrogen solidified by — was pre-
pared by fusing together sodium hydrate and form
NaOH+H.COONa =CO<ON* +H, The fusion ore place in
the generator.—Ber. Berl. Chem. Ges., x, 2117, Jan., = -
pyridine, Hence the acid is pyridine-carbonie aci
COOH.— Ber. Berl. Chem. Ges., x, 2136, Jan., 1878. G. F. B.
7. Chemical Philosophy.—As “recent discussions i in the French
Academy, Soper with the paper of Marignac, translated in the
f this J
of molecular mechanics. ‘This epartment of P obyeies involves the
eee age theory of heat and the kinetic —— of g yes
ve been developed by such masters as R \ Claadian, 300
212 Scientific Intelligence.
and Maxwell, and it is not too much to say that these theories—
essentially one and the same—rest to-day on as firm a foundation
gases the t eaphe of Avogadro isa pve consequence and
must be true unless this whole theory is a delusion. It is not how-
ever at present important to consider whether the absolute truth
of the pag will probably be hereafter vindicated or the reverse.
For the moment the only question is whether the kinetic theory
of gases ¥¢ a age ES basis for the system of modern chemistry,
and we are surprised that any scholar, who appreciates the pres-
ent position of the theory should not acquiesce in the decision in
which the great body of working chemists—certainly of those out-
side of France—agree. e two great uses of systems, or theo-
ries, in science are to direct yh aa and to facilitate the ac-
quisition of knowled e. Of the vane of the molernlyy theory in
stated and youtniecs developed... ... Of course we are far
from believing that the ideas ex prevailing are necessnr rily true,
clear SORES 8 and that in nee ng to clarify our ideas and
the changes of molecular structure, which evidently 1 very con-
ose
which aba as rae teams aed te Saad don our pee oe
tions and hitherto safe gui ides on account of a few anomalies,
a
2 ee
Chemistry and Physics. 213
in the debate in the French Academy, greatly surprises us. Cer-
. : “
many the study of chemistry has been during the last ten years
almost solely directed by theories of molecular structure, and that
uring this period the German chemists, thus guided, have done
more to advance their science than all the other nations of the
and if the present science of “molecular mechanics” is a legiti-
mate branch of knowledge, then the so-called “Law of a-
is held by the great masters of modern chemical philosophy.
3.7, IR.
ence was not ready for them, have lain neglected since 1863. The
position of the h droxyl group, he finds, has a marked effect on
whole amount of ether which it is possible to form from second-
ary alcohols, varying from 61°5 to 66°65 per cent of the theory, is
affect the initial rate, which is the same for all its pena
W easily explained exceptions, but do influence the limit,
214 Scientific Intelligence.
most curious fact observed in this research—benzyl and cinnamyl
alcohols have the same Se rate as allyl alcohol in spite of the
wide differences between the aromatic compounds and those of
i 0
except their alcoholic nature: it follows from these facts that new
alcohols can easily be referred to their proper class by determin-
ing their initial rate of etherification. Menschutkin’s somewhat
len ngthy discussion of the relative rate, i. e., the rate referred to
the limit seems rather unnecessary, as it i s of course a mere fune-
tion of the limit, but it is not worth while to dwell on the single
and of valuable suggestions for ~~ research, notably those in
regard to the bearing of isomerism on the rate ‘and limit, which it
is to be hoped he will follow out “thorongly, as soon as he has
finished the tertiary alcohols annem COH) with which he is
now at work.— Ber. Deutsch. Chem. Gres., x, 1728, 1898. L. Js
9. Solid Hi Aad giabe Density of “iguit | Ox “ygen.— W ith the ap-
paratus described i e last number of this Journal, M. Prcrer
has succeeded in ech liquefying and solidifying hydrogen, and
appearance, and destecides ah the opinion long since expressed by
Dumas, that hydrogen is a gaseous metal. M. Pictet prepared
M.
density of chee oxygen based on many factors, but gy on the
im i
tube was not quite filled, the agreement is still closer. This
density is about one-half of Jet of sulphur, and the result is re-
umes of oxygen and sulphur must be equal when in the same state
of aggregation. As the atomic weight of oxygen is one-half of
that of sulphur, Dumas po concluded that the densities of the
two substances w o each other the same ratio.
In Nature for Jan. 31 ‘aay be seen a large wood-eut represen-
Chemistry and Physies. 215
tation of the apparatus used by M. Caillelet in his experiments
described in our last number. Sie Oy BR
10. The effect of Light and Heat upon the electrical resistance
of Selenium.—W. Stwmens has undertaken a long ecg upon
i at it
scale, but without much success. He hopes, however, that other
observers with better means may be more successful.— Amn. der
Physik und Chemie, No. 12, 1877, p. 521. J.T.
12. On Electromagnetic and Calometric absolute measurements.
—Prof. H. T. Weer in a paper not yet concluded, discusses the
various results, obtained by different observers for the value of
’ resistance unit, and concludes from three independent
Wilh. Weber, F. Kohlrausch and L. Lorenz, are a ted with
rs of observation. Prof. H. T. Weber finds for the value of
e
Siemens’ resistance unit the expression
1S. M. U, = 0-950 x 101°(
Weber concludes his first paper as follows :-— :
“(1.) The fundamental ee itherto recognized of induced Se?
rents of variable intensity represent with great precision the :
facts. The opinion of M. Lorenz, that the B soo difference | “i
tween the results found by M.M. Weber, F._ ohlrausch and the
physicists of the British Resistance Committee was the conse
—
.
me)
sec
216 Scientific Intelligence.
quence of our imperfect knowledge of the laws of such induced
currents, finds no confirmation at all in the above sarge ments.
(2.) Absolute measurements of resistance can with the means
of galvanic observations nowadays at our disposal, be carried out
= such exactness and certainty “ can only be attained in few
rtments of physics. The notion widely accepted —
phioiieiate: that absolute measurements of resistance belong t
ists, supplied with the most perfect instruments and _ localities,
will not be able to bt abaokite resistance measurements that
sensiién of experiment. rdi Peter these me
urements can be effected with tolerable accuracy with en scant
means ro in moderately equipped localities,”— Phil. Jan.,
1878, J. Ts
13. i ie Srom the Chemical Laboratory of the Johns —
kins ae Nos. 4-8, 22 pp. 8vo. Baltimore, Decem
n the oxidation of Recnaishpdeskeans and of ee
substitution-products, b N. Morse and L Remsey; No. 5
MSE» ’
n of xylenesulphonic acids, by M. W. Inxs and I.
— N; No. 6, on acetylamidophenols, by H. N. Morse; No. 7,
a correction, by 'L Remsen ; ; No. 8, a Lecture-experiment, id.
II. GroLocy AND MINERALOGY.
1, Annual Report of the Wisconsin Geological — for the
year 1877; by T. C. CaampBertatn, Chief — ae — Besides valu-
able notes on the local geology of portions of a ‘State, this
Report contains brief descriptions of new Bitutibe fossils of Wis-
consin. The Potsdam sandstone afforded the species Bellerophon
antiquatus, and new — of each of the following genera of Trilo-
bites: Conocephalites, Crepicephalus, a is, Agraulos, Ario-
nellus and Eilliptocephalus ; and the Lower magnesian limestone
trilobites, of the genera Dicellocephalus (omer Bathyurus of Bill-
oe and I/lenurus, beside Mapeigakabit, and s species of Sceevogyr4,
ee and Leptena. A —_ - new species also are
who had one of the assistant pane ra of the meee
Cislogtiade Survey o <8 : nnual Report of
i. : H. © , State G or the year 1877 .—The final
yield of clay in some parts is 10,000 tons an acre, and single acres
ave egree 40,000 tons ; a ina — year 265, ness tons 0
Geology and Mineralogy. 217
of Paterson. The southern edge of the drift in New Jersey is
stated to pass along the line of Short Hills extending from Perth
Amboy, on the north side of the Raritan, to the First Mountain.
Between First and Second Mountains it fills the valley ~ less
than half a mile south of the Morris and Essex railroad. say
thence be traced to Long Hill, ieee a Dover and on the
Delaware below i é whole line of ‘due moraine is
vi
hagerents plain and well define
. Bulletin of the United rant Geological and i
ge. Vol. iv, No
r . V. Haypen, Geologi
- This number of the Bulletin contains papers by G. B. Samwurr
on the Ornithology of the Rio Grande; by E. D. Corx on Creta-
oo on t e Ma: anh of Fort Sisseton, Dakota; by R.
Ripgeway of oe Ansiioan Herodiones; by 8S. HI. ScuppER on
the Butterflies of Southern Utah and peau ER ; mira Coves and
Yarrow on the Herpetology of Dakotah and y
E. Coves on the Consolidation of the hoofs in the Vi irginian deer,
and on a breed of solid-hoofed pigs apparently established in
exas,
In the case of the deer the consolidation is confined to the horny
Substance of the true hoof.
With regard to the pigs of Texas, the animal is completely
and the anchylosis of the terminal phalanges of the
eet of horny ouleunaiiat — is curiously like the frog of
the horse’s hoof. The breed is so firmly established that no ten-
dency to revert to the oniginal partes eae form is observable.
mens and ‘facts to Dr. Coues
oofed boar with a sow of the ordinary type, a majority of the
. litter have the peculiarity of the male parent.
218 Scientific Intelligence.
artiodactyle than before; for the two toes are still present as
uch as before, although coalesced at extremity; and the fourth,
the outer of the two, equals the third—which is the grand charac-
teristic of artiodactyles and determines that even stroke of the
alescence of the two
metacarpal or metatarsal bones into a “cannon” bone. J. D. D.
4. Report on the Geographical and Geological Survey of the
: ion ; by Major J. W. Powe t, in charge of
Tuomrson and the topographic in two parties, under Mr. W. H.
Graves and Mr. J. R. Hunsaawe. Geological investigations were
carried forward by Major Powett, Mr. J. K. Gu.serr and Captain
: TT The results also include researches in the depart-
reference to the rise and fall of Great Salt Lake. Le.
n the variations of the Decortieated Leaf-scars of certain
Sigillarie ; and on the variations of the Leaf-sears of Lepido-
es
species,
6. Elements of Geology ; a text-book for Colleges and the
eneral read “ Religion and
Geology and ‘Mineralogy. 219
7. Contributions to the Fossil Flora of the Western Territories.
Part Il. The Tertiary Flora ; by Leo LesQqueREvx. Te pp.
cs
iv 3}
plate) deserves particular mention. The discovery of some of
these remains was recorded in this Journal, for January, 1874;
contribution from the Sheffield Laboratory* on the above named
subject, the writer gave analys
from the so-called “Chloritic formation,” and pointed out the
resemblance in composition between these rocks and basic igneous
rocks, By the aid of the microscope the rocks were inferred to be
pyroxenic. On a further examination with better facilities, I
have found that the mineral, sup to be pyroxene, is horn-
blende, and that the rocks belong therefore to the diorite group.
. Le
ical survey, in which analogous roc
and in which a revision of my previous studyt+ upon these rocks
will be found. :
9. Elevated Quaternary beds of Grinnell Land and North
Greenland.—The December number of the Annals and Magazine
se evidences of former
Frt_pEN, naturalist to
the late Arctic Expedition. The author spea of his Oe ae
lished in the Journal of the Royal
orth, that “the land which surrounds the Nort
ing a general movement of upheaval; or, to be perfectly
* This Journal, Feb., 1876. + Ibid., Aug., 1876.
220 Scientific Intelligence.
we find on it, in all directions, evidences that there has been a
movement of upheaval since there was any subsidence.” In Grin-
nell Land and North Greenland shell beds in some localities rest
on “ Miocene strata, and extend to an elevation of not less than a
thousand feet above their level,” proving, as he states, that since
the Miocene there has been “a subsidence of over a thousand
feet, and a subsequent Sohontel to a similar altitude.” The
beds overlie also the other rocks of the country. The shells are
Lawrence River and the Labrador and Maine coasts: such as,
Saxicava rugosa, Mya truncata, Cardium Islandicum, Tel-
lina ealearia, Astate bo satiek Pecten Groenlandieus and others.
Hb : ‘ie *
10. A Seal from the Leda Clay Shot gone sia of the Ot-
tawa valley.—Dr. Dawson describes this he common
Greenland species, Phoca Greenlandica. It sg atlen in ate clays of
Green’s creek, which have “afforded beautiful specimens of the
Capelin and other fishes, and also of eeere shells of northern and
cold-water types.”— Canadian Natur
11. Notes on Ag Mineralogy and ok om capprtinch ee
bye by M. Epwarps Wap swortH.—The r ned
y%
as “ diorytes,” “ syenites,” ete. e microscopical examination
has shown that the no ae and essential constituents of the
rocks are augite, feldspar, and magnetite; they contain also
apatite, sage pyrite, h peal nde, and perhaps biotite. The
*ks fr of the localities are marked by a greater or less
degree of aocalea. in some the change being slight, while in
others the decomposition. roduct “ viridite” forms with magnetite
the mass of the rock e rocks which have previously been
called “ diorite” and “ trap” are isa e to be identical and of
the same age, while the “ greenstones” which show more altera-
tion are regarded as older. The Sond es for the different rocks
examined, are stated, and the microscopical characters given with
care an | minuteness.
Mr. Wadsworth gives in the beginning of his paper a list, cov-
ering six pages, of the published articles upon subjects connected
with the mineralogy an geology of Eastern Massachusetts. —Proe.
Boston Nat. Hist. Soc., xix, 217, M
A ay, 1877.
- Analysis of Samarskite from Mitchell C hoes Caro-
rof. C. F. Ramu Nort |
RG,
Srenste.. ia y been analyzed by Miss E. Hl i a Prof.
O. D. Allen and Dr. J. Lawrence Smith (see this Journal, IIL, xiii,
362, and xiv, 1 Prof. Rammelsberg, who has contributed so
30). -
much to our knowledge of this group of minerals, has also pub-
rain an analysis of the same Babe It is as follows :——
Botany and Zoology. 221
Cb.0; Ta.0, Sn0, UO; Fe,0;(Mn20s3) Ce,03* Y¥.0; ErO Sid,
41°07 14°36 0°16 10°90 14°61 2°37 6°10 10°80 0°56
* With a little Di. =100°93
The formula deduced from the above is 8R,Nb,0,, +F#,U,0,,
where R=Y,, Fe,, Ce,(Er,), each double atom having an equiv-
alence of six (Y= 92, Ce=138). The American samarskite differs
from the Uralian mineral in the high percentage of tantalic acid,
Phys i
and of the element erbium.—Ann. Phys. u. Chem., II, ii, 663.
Ill Borany AnD ZooLoey.
1. Supplementary Note to the Review of Darwin’s “ Forms of
Flowers,” (In No, 7~-71.)—A contributor to the
i anced the i
d) bodil
the closed flowers, and would therefore cross-fertilize them: 2,
that there was a neat adaptation for ulterior self-fertilization ; the
n
iverged, and became revolute, a ee of the :
i e abundant pollen; es this
Th
may call for a brief remark. He states that Gen
in his neighborhood behaves differently, and that the flowers
“do not last a long while.” Between this an
y is not v ‘ t
done away with by the statement following, that “ the ovarium,
d soon pushes itself through the
mouth of the corolla, exposing the stigmatic surfaces which remain
” - *
cross-fertilized before this, its day is long passed. __
ollows this: “The only difficulty with me 1s, that I do
hot see where the pollen to cross-fertilize is to come from, Mr.
i from
lon.” This is equivalent to saying that there is no “ practical”
(meaning useful) cross-fertilization if the plants grow near enough
for a bee to fly from the one to the other; which is making what
iT9
222 Scientific Intelligence.
then returning, and agai ing back, continuou spec and
coming, as a ene ae so beautifully arranged by
nature, shoul whatever heats m 3 do elsewhere.” Cer-
were ever thought to do so.
e article continues thus: “ However, it is well to recognize
the fact, that plants, _ no doubt insects, behave differently i in
‘ “te :
induction of a general rule, t plants and insect e
depended upon for behavior,-—is inferred © instances, one
of which has been metagem o18 ake Arion and n
0., 1875; re-issued 1877. 12mo, pp. 429. And with 30 litho-
graphic plates.—The title page proceeds to state, that this vol-
ume contains a review of the principles upon n which renera are
founded, and the systems of classification of the principal authors ;
with a new general arrangement; characters of the genera; re-
marks on their reln¢ionshi to one another, their species, reference
to authors, geographical diseeabutiot: &c. The plates, drawn on
stone by Fitch, illustrate the tribes and leading genera. Mr.
Smith , perhaps, t the oldest ee preridologst, and while he
had his ¢ eyesight was one of the best. No else was so inti-
mately and extensively sha ualekad with Benin} in a living state.
In him unusual practical oo was miata ei with no mean
me
f venti ion, wish Brown had cau-
first t o
_Sously suggested for the definition of genera, and he may be said —
Botany and Zoology. 223
to use them with better judgment than Presl, upon an ampler
_ store of materials. His papers, published in 1841-1843, were
thought very valuable; an has since endeavored to make his
“the chief aim of the work being the definition of gen d
their classification, on the different modes of growth,
venation, and fructification.” It has good indexes, a list of Fern
useful book both to woes andamateurs. To those who do no
possess a considerable botanical library, it would appear to be in-
dispensable. A Ge
3. Ferns of North America. By Prof. Dantet C. Eaton,
enters the etymology of generic names, and is altogether a
h
and plates and letter-p are ever. commendable. The
latter extends to p. 4 e three plates illustrate, Asplenium
ebeneum, the ambiguous A. ebenoides, B chium Lunaria, la
mark at the close of the account of Asplenium ebeneum, we sug-
gest that the best of all reasons for adhering to this specific name,
is that it is the earliest given for this Asplenium as such. A. G.
Remarks, &c. From Bulletin of the B .
pp. 224-252.—The principal bulk and chief interest of this article
will be found in what are called the “ Remarks,” which are criti-
cal studies of development, synonymy, &c., of various interesting
n
ssed for an Uredo, and
noth i e only new species described is his
genus ; but, what is better for science, a goodly number of species
are reduced and pro erred; for instance, £ sidium
yi Andromede of
Peck, and E. discoideum of Ellis. The synonymy of various spe-
cies of Uromyces is given in detail, and various newly proposed
Species are referred to Schweinitzian origin: ce
224 Screntific Intelligence.
5. Journal of the Linnean Society.— The last two numbers, con-
taining together almost 200 pages, are filled with the Spicilegium
aroccane, by John Ball, based on the collections made
n Marocco by Sir Joseph Hooker and himself; a critical pie:
illustrated by plates of some new or rare spe cies. Thus hae
— the beginning of the Umbelliferce. ike
6. Guide du Botaniste in Belgique (Plantes vivantes rr Sos-
dl
siles), par Francots Criprx. Bruxelles and Paris, 1878
d g
just the information he most needs, and which, without such
help at the outset, he will 1 be a long while in obtaining ;—details
for herborization ; Ap capcom of specimens; formation of her-
ariam; arrangement for exchanges; nature and characteristics
of different sorts of “botanical books, ‘and how to use them; 5 h
to write them, mo ;and a useful section on the correction of
proofs; the denwhias's tare and what it must needs contain ;
selection of some of the einitpal floras _ botanical iets of
the day ; a choice of European Zesiccate ; sketch of the princi-
ples and methods of vegetable saleueelray; with detailed instruc-
tions for collecting and managing specimens ; systematic lists of
etc. This all be-
eral.
Herbaria, etce.; then the ee botany of the pee te
a catalogue of its fossil flora; full instructions for herborizations in
different parts of Belgium, with enumeration of the choice plants
of each Settens the same for the fossil flora; and
logue of all the works of Belgian botanists, or those who have
sojourned in Belgium long enough to be so accounted, from
Anselme de Boodt, 1640, st Clusius, downward. No other
country has such a hand-bo A. G
. A eurious adaptatio aes insect-fertilization in Trichostema
is described in a letter from Mr. I. J. Isaman, of Bangor, Cali-
Mr, ionuian —— of the two states of the blossom
to illustrate his account of the process, which he describes as
ws:
“ The tube of the an is bent upon itself when in its normal
condition. On inserting a pin or a small splint, the tube is
meatehtened; and the stamens and pistil are thrown forward,
and strike very forcibly upon the back of any intruding insect.
I have watthed bees for hours, gathering honey from these
plants, and have heen very much amused bet ~ dengan ee “
The sketches well Show how the o may take hee
—_
Botany and Zoology. 225
of position; also to he e seeds os raising the plant; for this
species is not in cultivation. Our two Eastern species should
likewise < examined in “ahis regard.
8. Botanical Necrology of 1877.—This contains an aenidiel
number of noted names. e following are the principal.
Mrs. Marra Eva Sar widow of the late Dr. J. E. wee
tra R 1872, a cryptogamic penn of. much
SHEDS died fapaasy 22, 187 7, in his 71st yea
WitHetm HormetsTer, Professor at Tiibingen, a most. distin-
he rea anatomist, died, January 12, 1877, in the 53d
year of his age s death was noticed in last year’s necrolog
ALEXANDER n, Professor of ge, died, 4 at Berlin preys
er.
OURGEAU, one of the best and most persevering botanical
collectors of our da , who crossed the American continent at the
north with sy el ‘and made his. last collection in Mexico dur-
at the age o
Hue = nN WEDDELL, English i in birth, French by adop-
tion, author of a hi He Chloris Andina, and of monographs
of the Urticee, Podostemacee, and. Cinchona, a first-class rere
Solna, died in August last, of heart-disease, at the a age °
PO
aad author of a Flora Helier er a pe 0 the
ber 9, at the age of 6
Prof, thease ot author of a Botany of the Southern
United States, died i in case last, at the age of 73, An obituary
hotice appeared in the December pte 3 of this Journal. a. ¢.
9. I. Desmidiee et CEdogonice ; by O. Norvsrept and V.
ITrRock. If. Bohuslinds CEdogonieer. IL. Nonnullee ae
aque dulcis Brasilienses ; by O. NorpsTEDT.— —The three papers
just named appeared in the Proceedings of of the Academy of Sci-
ence of Stockholm, rang each is accompanied by a plate. e
Species described the first named paper were collected by
Am. Jour. foxTn, on Vou. XV, No. 87.—Manrcu, 1878.
226 Scientific Intelligence.
Nordstedt himself in Italy and the Tyrol. The desmids were
determined by Nordstedt and the GEdogonie by Wittrock. The
species from Brazil, which with two exceptions are desmids, were
collected by A. Glaziou and E. Warming. Ww. GF.
10. A new Species of Chimera from American Waters ; by T.
Gitt.—One of the most unexpected discoveries recently made
in American ichthyology is that of a species of the genus Chi-
mera, of which a specimen has lately been sent to the Smithso-
nian Institution. It was caught southeast of the La Have bank,
in lat. 42° 40’ N., lon. 63° 23’ W., at a depth of 350 fathoms,
with a bait of halibut. A close comparison of the specimen with
individuals of the European Chimera monstrosa renders it evi-
dent that it does not belong to that species, but is an entirely dis-
tinct specific form. It may be named Chimera plumbea, and
diagnosed as follows:—A Chimera with the snout acutely pro-
little above the level of the inferior margin of the orbit ; the dor-
sals close together; the dorsal th its anterior surface
rounded; the ventrals trian and pointed; the pectorals
ormly plumbeous. By these characters the species is readily
separable from the Chimara monstrosa and other species of the
genus.—Proc. Phil. Soc,, Dec. 22, 1877, Washington.
11, Dr. W. M. Gabb on Dr. Warring’s paper on the growth-
rings of exogenous plants a proof of alternating seasons, in the
3
clusions arrived at by the Doctor are e only demu
at one ave never seen an exogen without rings (3).- ¢
ny tree grows here at the average rate of one inch
_ The mahoga
diameter per annum. Now the one-half inch radius certainly
contains an average of three rings—which cannot in any manner
might go farther: Santo Domingo is eighteen to nineteen de-
grees north of the Equator. But I have seen the same facts
amply proven ten degrees farther south, where there is practically
no variation of temperature, where the rainy season lasts twelve
months in the year, and where the trees are, to all appearances,
ually vigorous at all seasons of the year,
IV. Astronomy.
1. On the age of the Sun in relation to Evolution ; by JAMES
/ROLL.—One of the most formidable objections to the theory of
evolution is the enormous length of time which it demands. On
Astronomy. 297
this point Professor Heckel, one of the highest authorities on the
subject, in his “ History of Creation,” has the following :—* Dar-
Wwin’s theory, as well that of Lyell, retiders the assumption of im-
ense periods absolutely necessary. . . . If the theory of
development be true at all there must certainly have elapsed im-
mense periods, utterly inconceivable to us, during which the
gradual historical development of the animal and vegetable pro-
ceeded by the slow transformation of species. . . . t ri-
ods during which species originated by gradual transmutation,
must not be calculated by single centuries, but by hundreds and
by millions of centuries. Every process - development is the
ast,
deavors to answer this question and to meet the objections urged
against the enormous lapse of time assumed for evolution. :
ig g leave to remark,” he says, “that we have not a single
rational ground for conceiving the time requisite to be limited in
any Way. . % t is absolutely impossible to see what can in
any way limit us in assuming long periods of time . . .
From a strictly philosophical point of view it makes no difference
whether we hypothetically assume for this process ten millions or
ten thousand millions of years n the same way as the
distances between the different planetary systems are not caleu-
ated by miles but by Sirius-distances, each of which comprises
millions of miles, so the organic history of the earth must not be
calculated by thousands of years, but by paleontological or geo-
logical periods, each of which comprises many thousands of years,
nd perhaps millions or milliards of thousands of years.”
Statements more utterly opposed to the present state of modern
at.
rsally appealed to as the only
e sun could have obtained its
228 Scientific Intelligence.
Professor Heckel may make any assumption he chooses about
the age of the sun, but he must not do so in regard to the age of
the sun’s heat. One who believes it inconceivable that matter can
either be created or annihilated may be allowed to maintain that
the sun existed from all eternity, but he cannot be permitted to
her source, in addition, at least, to
in a heated condition then in condensing it would have to part
not merely with the heat of condensation, but also with the heat
it originally possessed.
The question then arises—By what means could the nebulous
mass have become incandescent? From what source could the
heat have been obtained? The dynamical theory of heat affords,
as was shown several years ago (Phil. Mag. for May, 1868), an
easy answer to this question. The answer is that the energy 1n
the form of heat » y the mass may have been derived
from motion in space. i
les per second, would, by their concussion, generate In a single
moving with a velocity of 476 miles per second, would possess
4,149 10” foot-pounds of kinetic ener. , and this, converted into
heat by the stoppage of their motion, would give out an amount
of heat which would cover the present rate of the sun’s radiation
for a period of 50,000,000 years,
There is nothing very extraordinary in the velocity which we
have found would be required to generate the 50,000,000 years’
heat in the case of the two Supposed bodies. A comet having an
orbit extending to the path of the planet Neptune, approaching
Ss
5 Saar
Astronomy. 999
so near the sun as to almost graze his surface in passing, would
have a velocity of about 390 miles per second, which is within
eighty-six miles of that required. ;
t must be borne in mind, however, that the 476 miles per sec-
ond is the velocity at the moment of collision. But more than
one-half of this velocity, or 274 miles per second, would be derived
om their mutual attraction as they approached each other. We
have consequently to assume an original or projected velocity of
only 202 miles per second. If the original velocity was 678 per
second, this, with the 274 derived from gravity, would generate
an amount of heat which would suffice for 200,000,000 years.
ence? It is just as easy to conceive that they always existed in
motion as that they always existed at rest. In fact, this is the
only way in which energy could remain in a body without dissipa-
tion into space. Under other forms a certain amount of it is
ace.
_ The theory that the sun’s heat was originally derived from mo-
tion in space is, therefore, for this reason, also more In harmony
n
the sun could have derived his heat. e one is gravitation, the
other motion in space. The former could have afforded only
about 20,000,000 or 30,000,000 years’ heat, but there is in reality
no absolute limit to the amount which may have been derived from
velocity of motion. And when we take into consideration the
magnitude of the stellar universe, the difference between a motion
of 202 miles per second, and one of 1,700 miles to a great ex
na a and the one velocity becomes about as probable as
e other.
It may be urged as an objection to the theory that we have no
experience of bodies moving in space with such enormous —
ties as the above. This objection, for the following reason, 18 ©
No body moving with a velocity exceeding 400 miles per secon
i er of our solar system; and beyond our nia
tem there is nothing visible but the stars and_ bule. se
Stars, however, are suns like our own,
230 Scientific Intelligence.
the occasion of receiving from the Governor of the Province of
Cordoba the premiums awarded at the Philadelphia Centennial
Exhibition to the Observatory for Lunar and Stellar Photographs,
e
ours, and will probably long continue to claim the ;
Much of the credit of the stellar photographs is due to the
pure air of Cordoba, which is incredibly transparent on those not
very numerous occasions when the sky is truly clear. The
impressions on glass which I exhibited were of six different
am as
unprepared to state. Since it is important that all the images
should be opiate round, without the slightest perceptible elon-
Say and si ; i
as
e have already secured measurable photographic impressions
objects, of which ninetee
the undertaking remain paralyzed in its resent state, the results
may be regarded as richly worth the labo
the planets Jupiter, Mars and Saturn have awe been photo-
graphed with sufficient distinctness to show clearly the details
of light and color on the surfaces of the two former, and the
Miscellaneous Intelligence. 231
existence of the ring in the latter; but these images have not
been sufficiently sharp to permit of successful photographic
enlargement.”
3. Moon’s Zodiacal Light ; note by E. S. Hotpen. From a
letter to the Editors, dated Naval Observatory, Washington,
+ February 4, 1378.—In your Journal for February, 1878, p.
88, is a note by M. Trouvelot, on “the Moon’s Zodiacal Light,” in
which he describes a conical luminous appendage about 4$° long,
extended on both sides of the moon, which was seen by him April
3, 1874,
In this connection an observation of a similar phenomenon by
Messier, in the Mémoires de l’ Académie Royale des Sciences, 1771,
p. 434, is noteworthy. In this memoir, Messier gives a roug
wood-cut of its appearance, from which its length on each side of
the moon is shown to be about 24°.
_ The condition of the sky, as described by Trouvelot and Mes-
Sler, appears to have been the same. ;
In the Comptes Rendus, July 2, 1877, p. 44, M. Hugo describes
a similar phenomenon which he saw above the lunar dise, about 4°
in length, and in this case, also, the sky appears to have been sim-
ilarly affected. These are the only cases known to me.
V. MISCELLANEOUS SCIENTIFIC INTELLIGENCE.
1. Address of the President of the Royal Society, at the Anni-
versary Meeting, November 30, 1877.—The first part of the ad-
i g
the biological results, appeared to have quite come up
ations, iderin
232 Miscellaneous Intelligence.
much higher latitude than has elsewhere been explored botanically,
he spe-
a
ertain warm gales and warm currents that were experienced in
lat. 82° and 83° May not these phenomena of vegetation and
temperature indicate the existence of large tracts of land clothed
with vegetation in th rior of nland, far within the
competent and willing workers in most of the departments, while
their association with such naturalists as Agassiz and Hecke
Miscellaneous Intelligence. 233
cannot fail to be gratifying to themselves and assuring to the
public.” * * *
The remainder of the President’s address was occupied with
reference to some of the American institutions he visited during
his recent tour, followed by some remarks on the flora. These he
gave in more of a narrative form than characterized the formal
case as to the natural history museums generally. In fact his
whole time was given to field-work in the region west of the Great
Plains. The commendation of the U.S. scientific surveys would
one here so highly and justly praised was the only one which the
President had had the opportunity to become personally acquainted
wi
tinued,—The most important scientific results hitherto derived
from the labors of Dr. Hayden and his parties are unquestionably
the geological: such as the delineation of the boundaries of the
a De
retaceous an rtiary seas and lakes that a fee more than
mains oO Oo g, ’
things, referable to so many orders of sponte and animals, and
often
States, with museums vastly larger than our own, are at a loss
fectionery and fruit at the stalls of the railway stations, from the
eastern base of the Rocky Mountains all the way to California,
ing. i :
over many hundred miles, observes that the character of its sok
Ontological, as well as of its strictly geological contents is such,
234 Miscellaneous Intelligence.
be placed in the lower Tertiary or upper 1s
most probable that the testimony of paleontologists will always
be as conflicting as it is at present. Profe sh, one of the
mals afford a satisfactory solution of the difficulty. ‘ Invertebrate
remains,’ he says, ‘throw little light on the question ;’ and he is
obliged to assume that ‘ the line, if line there be, must be drawn
where the dinosaurs and other Mesozoic vertebrates disappear,
early condition of the higher plants as compared with the higher
animals. Other, and perhaps even more cient, reasons for
ee, To way
related, become too often fallacious guides. Another result, fore-
t of t le
fessor Marsh in respect of the vertebrates, is that all the Tertiary
Sarat
older data than the corresponding ones in Europe. This, though
apparently supported by his conclusions that the main migrations
of animals was from the American to the Asiatic continent (which
he deduces from the American, as compared with the European,
life-histories of the Edentata, Marsupialia, Ungulata, Rodentia,
en Primates, is a ve eneralization. ”
reference is made to “a few of the magnificent collections of veg-
etable remains, Cretaceous and others, that have been studied and
ace ical Survey, and in Separate wi issued under its
auspices ;” and a series ritical remarks upon vegetable pale-
ontology and its peculiar difficulties and liabilities follow. We
Miscelianeous Intelligence. 235
continents. How great
mate and natural features of India had its trigonometrical or
revenue surveys been carried out in the same catholic spirit ?
And what scientific literature can England and its colonies show
to compare with that of the United States surveys?” _
These extracts were taken from the report in the Times news-
paper, of November 30, in advance of the official copy in the
Royal Society’s Proceedings.
2. Observations on Hermetically-sealed Flasks opened on the
Alps. Ina letter to Professor Huxiey, from Professor TyNDALL,
dated Alp Lusgen, September 18th, 1877.—Though the question
wo
but for six weeks fifty of the flasks remained perfectly clear.
Spirit-lamp, and to keep my body
Snipped off their sealed ends. ae
he two groups of flasks were then placed in our — _
hen, where the temperature varied from about 65° to
Fahrenheit.
.
236 Miscellaneous Intelligence.
deductions which we draw from these simple “experiments may be
summed up as follows :—
1.) Light is inimical to the development of Bacteria and the
microscopic fungi associated with putrefaction and decay, its action
- the latter organisms being apparently less rapid than upon the
ormer.
(2.) Under favorable conditions it wholly prevents that develop-
under less favorable it may only retard
rays of the spectru ;
5. e fitness of a cultivation-liquid to act as a nidus is not
impaired by insolation.
6.) The germs originally present in such a liquid may be wholly
destroyed <i : ondenigar: fluid perfectly preserved by the un-
gat,
though there are many vital phenomena, both of plant-life
confine ourselves to the plain facts of our observations,
and have studiously avoided speculation and theory. We cannot,
however, refra rom offering one comment on the striking
to special circumstances, and differing essentially in its vital phe-
nomena from the true cellular tissue of the plant and its proto-
It appears to us that the organisms which have been the subject
of our research may be regarded simply as individual “ cells 7 oF
ae
themselves may be in operation throughout the vegetable and
perhaps also the animal, kingdom wherever light has direct access
Miscellaneous Intelligence. 237
to protoplasm? On the one hand we have chlorophyl, owing its
very existence to light, and whose functions are deoxidizing;
solar rays are not only non-essential, but even devitalizing and
injurious.
This suggestion we advance provisionally and with diffidence ;
nor do we wish to imply that the relations of light to protoplasmic
matter are by any means so simple as might be inferred from the
above broad statement.
To this the following is added by the authors as the inference
from other experiments described in a postscript.
This remarkable fact, then, appears to follow as a deduction,
that a vacuum (or approximation to such) which of itself is a
condition antagonistic to the development of Bacteria, neverthe-
4. Expenditures for Universities in Germany.—Some inter-
esting details, on the contributions of the State to the univer-
sities, as well as on other points, were given in a recent num-
ber of the Academy by Professor ie. Lankester :—
erman States on the twenty
from fees) of a professor in a German university ran es from”
£100 to £600 a year. Asa rule, at the age of five-and-thirty, a
man in this career may (in Germany) cc
come of £400 a year (with retiring pension). The expenditure
on attendants, libraries, laboratories and officials may be caleu-
lated as being (in a well-conducted university) more than equal
average German professorial stipend at only £200 a year, we find
teen universities in this
“In order to equip and carry on pee age ting ae
e
country which should bear comparison w
* We wish, however, to make it clear that we by no means insist on this ex-
ion; the i admit of other explanations.
tie, We presume professors strictly so-called, exclusive of “ privat-docenten.”
238 Miscellaneous Intelligence.
ties, we require not less than an immediate expenditure of
£1,000,000 sterling in building and apparatus, and an annual ex-
penditure of from £500,000 to £800,000.”
When we add to the Government subsidy the income of the
universities from other sources, the sum is enormously increased.
The half-million, moreover, does not include the occasional grants
Erection of the German Industrial Museum, 998,000 mk. ; erection
versity, erection of an Herbarium,: 422,000 mk.; of a Clinic,
1,955,000 mk.; of a new building for a second Chemical Labora-
tory, as well as of a Technical and Pharmaceutical Institute,
967,000 m
the nature and extent of the scientific teaching in German
m ea ma ormed
logical Museum in Berlin, 1,800,000 mk.; and for the Berlin Uni-
; He ff
gives no adequate idea of the means at the command of a German
University for training its students in science. The number of
oe of its large and comprehensive library. In connection with
erlin alone there are twenty-three scientific “ Anstalten,” as they
.
een seen that higher
; : nsas and Missouri on the
nto Dakota and Minnesota on the North. In Omaha
Miscellaneous Intelligence. 239
three, and in North Platte, Lincoln and West Point, Neb., two
shocks were felt. In North Platte and Columbus, Neb., and in
Sioux City, Iowa, walls of buildings were cracked. The times
given are still very discordant, varying all the way from 10.40
A. M., to 12.20 Pp. M., Omaha time i
A. M., is probably not far from correct. The December number of
Peterman’s Mittheilungen, contains a long article on the Iquique
earthquake of May 9, 1877, giving valuable data in regard to
and ocean wave. Ue
6. Memoirs of the Geological Survey of India, Paleontologia
Indica, Section Il, No. 2, contains Jurassic (Liassic) flora of
of Washington University, St. Louis, which will be recognized as
the “central station.” The circular issued is signed by William
S. Eliot, President of the University, and Francis E. Nipher, Pro-
su workers in this branch of science,
the literature would be otherwise inaccessible, can hardly be over-
estimated,
OBITUARY.
M. Antoine Cfsar Brcqueret died on the 19th of January,
at the advanced age of nearly ninety years. ite was born at
Chatillon-sur-Loing (Loiret) on the 7th of March, 1788.
as educated in the Polytechnic School, which he left as
icer i 8. He served in Spain and took part in
several sieges under the orders of Marshal Suchet. In 1814 M.
Beequerel was named Inspector of the Polytechnic School, and he
quitted the army in 1815. es:
da Member of the Académie des Sci-
M. Beecquerel was elected a Me Se uabesof tas Rees
240 Miscellaneous Intelligence.
on different branches of electricity, to which M. Becquerel de-
voted his especial attention, will be found in the Comptes Rendus
of the Academy of Sciences. e may more particularly name
Mémoire sur les Caractares Optiques des Minéraux (183+), Sur les
Propriétes Teenchiienidies des Corps Simples et leurs Applica-
tions aux s (1841), and Mémoires sur la Reproduction Arti-
ficielle des econ Minéraux, 4 aide de Courants Electriques
trés faibles (1852). His researches on animal heat t, and other
applications of physics to physiology, on which subjects memoirs
will be found in the Comptes Rendus, were % a high see
Becquerel was a voluminous writer on science, the most
n the several divisions of electrical science, to which the father
and s son had devoted the largest portion of their lives. Atheneum,
an. 26.
M. Re uEr—M. Henri Victor Regnault died at sa almost
simultaneously with M. Becquerel, on the 2ist of January.
M. Re was born on the 2\st of Jul 1810, at Aix-la-
Chapelle He was a student of the Polytechnic School, and
shortly after leaving that school he became Ingénieur en Chef
s Min In 1 ; Physics
College of France and of Chemistry in the Polytechnic School.
In the same year he was elected a Member of the Académie des
ences soGebeines par Ordre de M. le Ministre des Travaux ate
a Vanes et Baa la Proposition de la inieianoe Centrale des Machines
These main a standard authority upon
all ede relating 2 the thedey and practice of the use e of
Steam as a motive
. Regnault was the father of the ge a seh painter who fell,
fighting for his country, at he siege of Pa
egnault published a Cours Elémentaire de Chimie, in four
volumes. Premiére Notions de Chimie, and a Traité de payee
The Cours Elémentaire has been translated into several European
languages, and the other works of M. Regnault are highly appre
ciated in this country as in France.— Ibi, id.
APPEND.
Art. XX XII1.—WNotice of New Dinosaurian Reptiles ;
by Professor O. C. MARSH.
IN addition to the Jurassic reptiles already described by the
writer,* several others of interest are now represented in the
Yale Museum. Among these are a number of Dinosaurs of
gigantic size, and others of diminutive proportions. Nearly all
are from the Atlantosaurus beds of the Rocky Mountains. Most
tinct third trochanter. The proximal end and upper half of
the shaft are compressed transversely. he inner condyle of
the distal end is proportionally large, and on the outer one,
62 This femur is over eight feet
(98 inches, or 2,500™") in length. The transverse diameter
ave the same pro-
and fifteen feet!
* This Journal, xiv, pp. 87, 254, 513, 514,
Am. Jour. Sct.—THIRrD geet Vou. XV, No. 87.—Maroxu, 1878.
1
242-0. C. Marsh—Notice of New Dinosaurian Reptiles.
The only remains of this monster at present known are in
the Yale College Museum. They are from the Upper Jurassic
of Colorado.
extend below the inferior surface of the centra. The latter
are also more fully ossified than in Atlantosaurus. The first
Vv
ve.
The present species is represented by various remains, the
Eran Gth of waereie it Soe = ee ti is ARS ays Sy 535°"
Transverse diameter of anterior articular face....__..... 215°
Transverse diameter of posterior articular face..._....... 190°
Expanse of transverse processes of second vertebra ------ 395°
science is indebted for many important discoveries in the
Rocky Mountain region. :
Allosaurus lucaris, sp. nov.
The peculiar genus named by the writer Allosaurus proves
to be very different from the Dinosaurs found with it, and to
excavated that only a narrow keel is left below, and there are
large cavities in the interior. The length of this centrum is
9mm ; the vertical diameter of the anterior face, 81-°™™; and
the width of this face, 33™, The articulation for the rib is at
the anterior border, just below the suture of the ait
his speci he
Mountains, and belonged to a reptile eighteen or twenty feet
in length.
0. C. Marsh— Notice of New Dinosaurian Reptiles. 248
Creosaurus atrox, gen. et sp. nov.
This genus is nearly allied to Dryptosaurus (Lelaps), “i
was the carnivorous enemy of the huge Adlantosauride. It1
indicated by various remains in oteeat ae rvation, amon "
them the ilium represented be The teeth referred to the
present species have the crowns more or ia trihedral, and the
cutting edges crenulated. The metapodial bones preserved are
me “and the terminal phalanges supported sharp claws.
The vertebrae known are biconcave, and the terminal caudals
are iiach elongated.
Inferior view. Both one-tenth natural size.
The following measurements indicate the size of this reptile :
Antero-posterior diameter of left ilium---.--- .---------. 700™™
Wivtinn! Giatnatar: ee es 425°
ngth of metatarsal - ee ee ae 277"
Transverse diameter of proximal ‘Get ee 72°
Transverse diameter of distal end. ------- ---- ---- ----- 79°
Length of distal canda ees
Transverse diameter of eer oe 2 -e e 33°
Transverse diameter of distal end. --.--------- ---- ----- -
This zara was about twenty feet in length. The —
at present wn are from the same horizon as those
described, ad were vatleatad by Mr. 8. W. Williston.
244 =O. C. Marsh—Notice of New Dinosaurian Reptiles.
Laosaurus celer, gen, et sp. nov.
The present genus is indicated by various remains of small
Dinosaurs, of two or more species. The long bones are not
the cavities small. e vertebree preserved are biconcave, and
the neural arches loosely united to the centra. The dorsal and
anterior caudals are more elongated than in most Dinosaurs.
The phalanges are so avian in character, that they would read-
ily be taken for those of birds. The anterior limbs were much
smaller than the posterior.
he following are some of the dimensions of the present
species
Length of median caudal vertebra. __.__._.__..._.__..- so"
Vertical diameter of anterior articulation.._....._...._-- 17
a PaUNWehe CibtehO gs 16°
Greatest diameter of provimal end.of ulna: .....2. 20.2. 19°5
Length of proximal phalanx of pes ._____- 29°
Length of second phalanx es a. en, SE
Length of third phalanx. __.._.___ reece |
The remains at present known indicate an animal about as
large as a fox. ey are from the same horizon as the species
described above.
Laosaurus gracilis, sp. nov.
A second species, much smaller than the above, is represented
- by well preserved remains of various parts of the skeleton.
size is indicated by the following measurements :
Length of lumbar verte We er 16°"
Transverse diameter of anterior face... _..._._......... 1°
Transverse diameter of posterior face iv
Lengt medintl Gaudal vertebra 16°
Transverse diameter anterior face es ae
Greatest diameter of proximal end of ulna_......_..___.. 17°
The present species is from the same locality and horizon as
the one above described.
_ This reptile is the smallest known Dinosaur, with the excep-
‘ton of the diminutive species of Nanosaurus (N. agilis and
N. victor). The latter cenus possesses some very peculiar
characters, and represents a distinct family, Nanosauride.
’ Yale College, New Haven, February, 1878.
AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES.]
ArT, XXXIV.—On the Surface Geology of Southwest Pennsyl-
vania, and adjoining portions of Maryland and West Virginia ;
by Joun J. Srevenson, Professor of Geology in the Uni-
versity of New York.
THE following article contains a brief summary of the re-
sults obtained by me during three years’ labor in connection
with the Second Geological Survey of Pennsylvania. The de-
tailed statement will appear elsewhere.
e area in which observations were made covers in all
more than 10,000 square miles. It embraces that portion of
Pennsylvania lying south from the Ohio and Conemaugh Rivers
and west from the Alleghanies; includes a large part of West
Virginia and Maryland lying on both sides of the Alleghanies
of Virginia; and has the channel-ways of four great rivers, the
Monongahela, Cheat, Youghiogheny and Potomac, lying partly
t
oF
within it.
main streams, :
A second series of benches appears throughout this whole
region and seems to be characteristic of a much wider area
than that in which observations were made. The benches of
this series evidently differ in origin from those of the lower se-
nes ; their detrital coating contains little clay, no transpo
fragments and consists almost wholly of sand. They are almost
absolutely horizontal ; they do not merge into the lower series,
Am. Jour. Sct.—Tutrp Sertzs, Vou. XV, No. 88.—APRIL, 1878.
17
246 J. J. Stevenson—Surface Geology of Pennsylvania.
The Horizontal Benches.
Benches belonging to this series have been fully recognized
over the whole area examined. The altitudes are as follows :—
Above tide. Above tide. Above tide.
1, 2,580 feet. 8. 1,570 feet. 15. 1,290 feet.
2, 2,40 S 1520 > 16. 1,270 .*
Bi 2308... ©. 10, 1.475 . * 17, 3,240. ©
4, 2.288 “ tt, ooo. * 18, ‘t,100 2*
5; 3.083" * 13, ¥420 ° = 18. 1160
6. 1,820 “ 12, Tee0 | * 20. 1,100 “
i. 1,600 = 14, 1,850 “
Of these benches, those below No. 11 were recognized at
many localities within an area of more than 5,000 square miles ;
extreme variation in level is barely twenty feet in any case and
in most of the benches the altitude is accurately the same at all
places. No. 17 shows a variation of eighteen feet, and I am
much inclined to believe that I have confounded two benches
a long distance north and south and is broken only by gaps
which the pales streams make through this small ridge on
i the Monongahela River. He sees also that this
plain is the divide between two valleys, one at the east between
this and Chestnut Ridge, and the other at the west, in which
an plain of Brush Ridge, as well as by lower benches which
veak its continuity and convert it into'a succession of basins.
J. J. Stevenson—Surface Geology of Pennsylvania. 247
From the summit-plain of this Brush Ridge, the surface falls off
in regular steps.
If, now, the observer turn his attention to the region lying
directly west from the Monongahela River, he will see that No.
16 is a broad continuous plain beyond that river, but that still
farther back toward the west, the fourteenth bench, on an islan
of which he is standing, forms a similar plain, while stil] farther
back, No. 18, with an altitude of 1,380 feet above tide, stretches
_ northward and southward and is broken only by the narrow
valleys in which the larger streams flow.
Should the observer's position be changed to Hillsborough,
fifteen miles west from the Monongahela River, where the ele-
vation is about 1,500 feet above tide, he will see that No. 13 is
of great extent north and south, while back of it the country
rises to a still higher level, again and again, until it reaches No.
Li at 1,445 feet above tide.
From the river westward to Hillsborough, or rather to a
ridge passing nearly north and south at three miles east from
that village, the surface rises in a succession of steps which are
beautifully marked. From the hill-top at Hillsborough, the
descent to the river is very handsomely shown. :
That these benches are simply the result of remodeling val-
leys formed long before the agent making the benches began to
work, is shown by the distribution of the benches themselves ;
for these benches line the sides of long narrow valleys reaching
far inland from the rivers, and breaking through ridges bearing
valleys began, I believe, even before the anticlinal axes had
been elevated sufficiently to affect the topography. he main
streams of the present drainage system break through all the
bol anies of Virginia. 4
d axes west from the Alleghanies a oy lene faoin their
condition of preservation. If they had been of ancient origin
ette county.
The whole structu re of t
: : : age iate vicinity. They exten
ae toeiten died ee 2? ee oot Be the Alleghanies
248 «oS. J. Stevenson—Surface Geology of Pennsylvania.
them by the draining away of a great lake or by the action of a
great flood sweeping over the whole region. They can be no
other than sea-beaches, marking stages in the withdrawal of the
ocean. This supposition involves a submergence of the land to
a depth of fully 2,600 feet, if we regard the higher benches as due
the same cause with the lower ones, and the submergence
would have to be somewhat greater to account for the even
crests of the Alleghanies and other ridges of the Appalachian
region west from the Blue Ridge
The River Terraces.
The persistent terraces are five in number and their relations
are shown at the junction of Cheat and Monongahela Rivers.
Three or four miles north from the West Virginia line, they are
as follows :—
Above river. Above river.
1. 280 feet. 4, 80 feet.
210" = SL
a 180.
The absolute elevation of the highest terrace at this locality is
1,050 feet above tide.
ese fall down stream and are covered by detritus, consist-
ing of irregularly bedded sand, clay or gravel, in which are
po
streams, being divided by the channel-way just as the present
“bottom” is divided. In some instances a terrace is wanting
on one side; but there it is clear enough that that corrasion
was confined to one side, for the terrace is unusually wide on
the other. The same condition is often seen in the Hood plain
of the river now.
in my report for 1875, these terraces are simply
n the rock on which rests a thin coat of detritus. Mr.
Gilbert, in his memoir on the geology of the Henry
Mountains (not yet published), describes similar terraces as 0C-
curring there, though it does not appear that they are found at
the same height on both sides of the streams.
The terraces on the Ohio, below Pittsburg, consist largely of
northern drift brought down by the Allegheny and Beaver
Rivers, so that they certainly date from a time later than that
shelves i
G.
J. J. Stevenson—Surface Geology of Pennsylvania. 249
at which the drift was spread over northern Pennsylvania.
Along the Monongahela and other rivers south from the Ohio, no
such material occurs, but the deposits afford sufficient evidence
of another kind to enable us to fix their origin within compara-
tively recent times. At New Geneva on the Monongahela near
the West Virginia line, the highest terrace has a thick coating,
in which a layer known as the “swamp clay” holds much half
rotted wood, such as is frequently seen in peat . In the
same neighborhood the third terrace shows many Unio shells in
an advanced stage of decay. A similar condition exists on the
same terrace at Morgantown, farther up the river in West Vir-
ginia. At Belvernon, on the same river, near the northern line
of Fayette county, this terrace yields many fragments of wood.
In this way it can be shown that the deposits on the first, third,
fourth and fifth benches are of recent origin.
Since these deposits are of recent origin, there would seem to
be good reason for supposing that the valleys through which
their streams flow are also of recent origin, at least so much of
them as lies below the level of the highest terrace. But it has
been suggested that these terraces are only the result of re-
working the sides of thé valleys, which had been eroded pre-
vious]
the sides are gently sloping, whereas below it they become steep
at once. Above the line of that terrace, the smaller valleys a
very few miles of its mouth. ;
ese river terraces are relics of river beds, which at one
time stretched across the valleys, just as the river “ bottoms
now do; and the valleys below the line of the highest terrace
have been eroded since the drainage system was reésta ‘ished
by withdrawal of the ocean below the lines of the former
stream beds.
Conclusions.
The general conclusions to which I have come are :—1. That
he erosion, to which is due the general configuration of th
surface above the highest river terrace, began even before the
elevation of the anticlinal axes and con Papi
region was submerged in post-glacial time. 2. That t it orl-
zontal benches are due to re-working of preéxisting valleys,
250 = J. D. Dana—Driftless Interior of North America,
and that they mark stages of rest during emergence of the con-
tinent from the ocean which covered it. 8. That the river ter-
races and the valleys which they line, were formed after the
drainage system had been reéstablished by withdrawal of the
“yer to a level below that at which the streams had previously
owed.
ArT. XXXV.—On the Driftless Interior of North America ; by
JAMES D. DANA.
1. Driftless area of Central and West-Central North America,
€ portions of two of Mr. Schott’s charts (see
beyond); one (No. 1) giving the lines of equal precipitation for
*Vol. ix, p. 312. Further, vol. x, p. 385, and vol. xiii, p. 80. The connection
between the distribution of the ice and the amount of peal paisiiod is appealed to
also in ibid., v, 206, 1873, and illustrated from Mr. Schott’s chart.
J. D. Dana—Driftless Interior of North America. 251
cover the whole area (some mountain ridges not being con-
i the Sierra Nevada ;
from Iowa and Minnesota to Salt Lake City ; and from Minne-
sota northward and westward. The line of four inches, as
the copied portion of the chart shows, passes along the eastern
ter diverges eastward—continues northward along the summit
of the mountains. i
In contrast with this, the winter precipitation over New
England is 8 to 12 inches; over New York, 6 to 10 inches;
over Ohio and Indiana, 8 to 10 inches; over the Southern
States, from Virginia to Georgia and Louisiana, 10 to 20 inches.
On the chart No. 2 is given the amount of annual precipita-
tion for this same region. While this amount is 40 to 45
inches in New England; 40 to 50 inches from Pennsylvania
southwestward; and 40 to 45.over Ohio and Indiana, the line
of 20 inches (half the average for New England, Pennsylvania,
hio, and Jess than half for the more Southern States) crosses
Western Minnesota and passes just west of Iowa; and the
line of 16 inches enters Minnesota. Mr. Schott’s chart shows
less up to 16 inches embraces (exclusive of parts of the
lines, and especially those of the summer, bend far ire ne
over the dry region. The climate consequently woul piles
necessarily occasioned over this central and western eepn ee
_ continent, only a small amount of precipitation m - th ee :
~ era; and all the observed glacial facts prove positively tha
+S a wares portions, the line 2 of No. 1, and 16, 20 and 24 of No. 2, are,
according to Mr, Schott, only approximati
* \¢ 7
K Kant
CAAA,
WSN
ae.
7
1. Lines OF Equal WINTER PRECIPITATION.
See,
\ . Ai
SS Q's
SS
SOS SS ws
Ts SAS
Ce
.
SS AC
RASS “~
_
ASS WS
S
\
AY _—
wk *
. AN SSN
SK
Lives or Equal ANNUAL PRECIPITATIO
254d. D. Dana—Drifiless Interior of North America.
was too small for the production of a southward moving
glacier. The southwestward direction of the scratches and of
the bowlder-movement over the area from Wisconsin to Lake
Winnipeg not only sustains this, but shows also that the ice
had its greatest height over the region of greatest precipitation
somewhere between the line from Wisconsin to Lake Winnipeg
and beyond, and that of the Atlantic coast. More facts
needed before the northern limit of the glacierless and driftless
area can be laid down.
2. Driftless area in Wisconsin.
The charts accompanying this paper have been introduced
here partly to exhibit the bearing of the climatal facts on the
question as to the origin of the “driftless area” in Wisconsin,
a description of which is given, from Professor Irving’s Report,
winter chart (No. 1) the driftless area is almost wholly in-
cluded within the area which has only 2 to 4 inches for the
4area. Ag
(No. 2), this driftless area (excepting its south end) is the driest
found in Lucas County, Southern Iowa,
is distant four aA S and sixty miles from Keweenaw Point, »
its probable source. From Iowa the ice stretched eastward
across Illinois to the Lake Michigan region.
is southwestward prolongation of the glacier from the
western half of Lake Superior over a region as dry as that of
a
J. D. Dana—Drifiless Interior of North America. 255
the Wisconsin driftless area appears to be a consequence, as
Professor Irving urges, of the great depth of the Lake Superior
trough—over a thousand feet below the present surface of the
water—and its lying in a southwest-by-west (or about 8. 55° W.
direction, which was nearly that of the glacier motion in that
part of North America. For this would have determined the
nesota and Iowa to Missouri, a distance of five hundred miles,
this being shown by the bowlders of copper. Whatever the
pitch along that course, it was twice as great toward the Wis-
consin driftless area, since the northern border of the area is
hardly half as far. Down Lake Michigan the pitch continued
into Illinois and Indiana; but the Kettle Range west of Lake
Michigan, running along the east front of the driftless area,
marks out, as Professors Chamberlain and Irving show, its
moraine termination in that direction. d
The eastern parallel branch of the Kettle Range lying
between the Green Bay Valley and Lake Michigan, which,
according to these geologists, is also a moraine ridge, is evi-
dence, as they observe, that at the time when it was formed,
the glacier of Green Bay Valley was distinct from that of
ke Michigan. It seems probable that when the Glacial era
was at its height, the two were merged in one glacier; but that
later, as the ice diminished, the former became independent,
and that then the eastern Kettle Range was made.
3. The earth's axis had the same position in the Glacial era as
now, if the driftless character of the Wisconsin area depended on
the climatal conditions explained. The concordance between
the limits of the drier areas of the Glacial era and those of the
present time, and especially the fact in this respect with regard
to the isolated area in Wisconsin sustains this proposition.
The probability that such was the trath was long since made
Apparent by the observation that the southern termination of
e glacier in North America and Europe was very nearly
along what is now the course of the same identical oe
The position and extent of the Wisconsin driftless area affo:
more precise and positive evidence.
s
256 G. K. Gilbert—Ancient Outlet of Great Salt Lake.
Art. XXXVI.—The Ancient Outlet of Great Salt Lake; a
letter to the Editors, by G. K. GILBERT.
Great Salt Lake has no outlet, and its fluctuating level is
determined by the balance between inflowing streams and
solar evaporation. On the surrounding mountains there are
water-lines rising in steps to a thousand feet above its sur-
face, and showing that in ancient times a great body of water
occupied its basin. This ancient body, known as Lake Bonne-
finding it in Idaho, at the north end of Cache Valley, the locality
being known as Red Rock Pass. The circumstances were suc
as to leave no doubt in my mind that I had determined the
actual point of outflow, and on my return to the East I made
the announcement without reservation in a communication to
ell has charge. t, in 3
January, 1878 (p. 65), there sa a statement (apparently on
Dr. F. V. Hayden, but without signature)
.
: season, h
etfs ancient outlet of the great lake that once filled
ence and position of the ancient outlet beyond question.
If Lake Erie were to dry away, and a Beologat of the future
should examine its basin, he would easily trace the former shore-
line around it. At two points he would find this line interrupted.
At Detroit and at Buffalo he would meet with narrow, trough-
iy ee
G. K. Gilbert—Ancient Outlet of Great Salt Lake. 257
like passes, depressed somewhat below the level of the shore line,
and leading to other basins. Following the Detroit P% e
would be led to the Huron basin and would find there a shore
line so nearly on a level with the Erie that he could not readily
determine which was the higher. Following the Buffalo Pass
he would find a continuous descent for many miles to the Onta-
rio basin, and in that basin he would find no water-line at the
level of the Erie shore. In each case he would learn from the
form of the passage that it had been the channel of a river,
and in the latter case he would learn from the direction and
continuity of descent, and from the absence of corresponding
shore lines, that it had been the channel of an outflowing river.
in regard to Lake Bonneville. To discover its outlet it
was necessary to find a point where the Bonneville shore line
was interrupted by a pass of which the floor was lower than the
shore line, and which led to a valley not marked by a continu-
ation of the shore line. These conditions are satisfied at
Rock Pass, and, in addition, there is a continuous descent from
the pass to the Pacific ocean. All about Cache Valley the
Bonneville shore line has been traced, and it is well marked
within a half mile of the pass. The floor of the Pass at the
the conclusion is irresistible that here the ancient lake outflowed.
At the divide a portion of each wall of the ancient channel
is composed of solid limestone, and its floor is interrupted by
knolls of the same material. It is evident, too, that the chan-
nel has lost something in depth, for Marsh Creek and some
smaller streams at the south have thrown so much debris into
it as to divide it into several little basins occupied by ponds
and marshes. It is not improbable that twenty or thirty feet
have thus been built upon the floor and that the original bed of
the channel where it crosses the limestone is 360 or 370 feet
lower than the highest Bonneville beach. Still we must not
coexistent level of the lake, but rather that during the exist-
ence of the outlet its channel was slowly excavated to that ex-
is sustained in a very striking manner by the phenomena of the
shore lines.
on
258 G. K. @ilbert—Ancient Outlet of Great Salt Lake.
cumstances asserts its supremacy and clearly marks the longest
lingering of the water. It has been called the “ Provo Beach,”
and it runs about 365 feet below the Bonneville Beach. When
the discharge of the lake began, its level was that recorded by
the Bonneville Beach. The outflowing stream crossed the
unconsolidated gravels that overlay the limestone at Red Rock
ass, and cut them away rapidly. The lake surface was low-
ered with comparative rapidity until the limestone was exposed,
but from that time the progress was exceedingly slow. Fora
long period the water was held at nearly the same level, and
the Provo Beach was produced. Then came the drying of the
climate, and the outflow ceased ; and slowly, with many linger-
ings, the lake has shrunk to its present size.
In Dr. Hayden’s Preliminary Report of the field work of his
Survey for the season of 1877, noticed on page 56 of the cur-
geological observations, but it is to be hoped that the idea will
not be advocated in that gentleman’s report. The divide
referred to is near Malade City, and separates Malade Valley
from Marsh Valley. The Bonneville Beach is well marked all
about Malade Valley, and nowhere more strongly than in the
afforded passage to the water.
Eilon who visited the locality in 187 2, expressed the half
formed opinion that it had been a point of outflow, but he de-
J. C. Draper— Projection of Microscope Photographs. | 259
scribed no channel of outflow ; and it is evident, moreover, that
he gave little thought to the subject, for he made the somewhat
astonishing suggestion that four outflowing streams might have
coéxisted—one at the Soda Spring Pass, one at Red Rock, one
near Malade City, and one at the head of the Malade River. If
he had seen the channel at Red Rock, I do not doubt that he
Art. XXXVII.—On the Projection of Microscope Photographs ;
ty JOHN CHRISTOPHER Draper, M.D., LL.D., Professor of
atural History in the College of the City of New York.
IN the lanterns that are constructed for the projection of pho-
tographic or other images on a screen, the support or stage on
which the photographic slide is placed is close to, and at an in-
variable distance from, the condensing lens. So long as the ob-
jects to be projected are nearly equal in size to the diameter of
the condenser, this is the only adjustment that can be made to
illuminate the whole surface of the object; but, when the
diameter of the field occupied by the object is only one-half, or
one-quarter of the diameter of the condensing lens, the_bril-
lianey of the result obtained upon the screen may be greatly in-
creased by removing the supporting stage or object carrier to a
greater distance from the condenser, so that a convergent beam
of light may fall on the object to be projected. T'o accomplish
this I have constructed the following form of lantern:
In the figure, a is a zirconia light, mounted on an adjustable
base (see American Journal of Science and Arts, Sept., 1877,
page 208), which may be used with a condensing lens of very
short focus, since the zirconia is not burrowed into cavities
Where the oxyhydrogen flame impinges, as happens with lime
cylinders, and causes the flame to be reflected upon the con-
densing lens and thereby destroys it. In the jet employed, the
gases are mixed just before they are ignited. 4, , is a short
focus condensing lens. ¢, the stage or support carrying the pho-
tographie or other design to be projected. d, the projection
260 J. C. Draper—Projection of Microscope Photographs.
lens formed of three sets of lenses and giving a perfectly flat
rectilinear fie a, c,d, are mounted on a base board e,
istance between d and ¢, required in giving the correct focus,
may be obtained. The base e, f, is attached to a second or
_ When a series of objects of very different sizes is to be pro-
jected, as is the case with microscopic photographs taken under
or ot
objects as clearly visible at considerable distances as are the
t.
In closing this brief communication I desire is aaa that I
have made phowenphs of Frustulia saxonica under a power of
: ‘ he photographs in question were made 1n
the City aa 2 building by a one-twentieth inch immersion
e light was from the sun, reflected by a helio-
stat, through ammonio-sulphate of copper solution, and con-
F.. Prime, Jr.—Lower Silurian Fossils. 261
densed on the object at an angle of 80° to 40°. The photo-
graph in question was direct, by which I mean that there was
no intermediate or secondary enlargement of a first photograph.
With this photograph and the lantern described, I awe shown
Frustulia saxonica magnified more than half a million diame-
ters; a result which must be seen to be appreciated.
Art. XXXVIII.— On the Discovery of Lower Silurian Fossils in
Limestone associated with Hydromica slates, and on other points
in the Geology of Lehigh and Northampton Counties, Eastern
Pennsylvania ; by FREDERICK PRIME, Jr., Professor of Metal-
lurgy at Lafayette College, Easton, Pennsylvania.
erles were made lies near the eastern verte of the State, south-
idge. Th
ings of the Philosophical Society for December 21, where it appears
under the title “ On the Paleozoie Rocks of Lehigh and North-
ampton Counties, Pennsylvania.—s. D. D.
THE Paleozoic rocks of Lehigh and Northampton counties
are: The Potsdam Sandstone (No. I); Magnesian or Aurorz
Limestone (No. II); Trenton Limestone (No. II); Utica Shale
(No. III); Hudson River or Matinal Slate (No. IIT). | :
The Potsdam sandstone is first found in the outlying penin-
sula of the South Mountains, known as Ridge, where it
Am. Jour. ee Vou. XV, No. 88,—APRIL, 1878.
262 F. Prime, Jr.—Lower Silurian Fossils,
occurs on the northwest flank of the hill and undoubtedly has
a northwest dip. It next occurs in two small patches on the
northern flank of the main range of the South Mountain near
Macungie (formerly Millerstown). A small patch of it is also
found associated with the gneiss, where the latter crops out
through the limestone in the gorge of the Little Lehigh Creek
at Jerusalem Church, two miles northwest of Emaus. But it
is first seen to any great extent along the north flank of the
main range just south of Emaus, where its occurrence is con-
stant, but of varying thickness, and continues for a distance of
four and a half miles, after which it can no longer be traced.
It occurs again at the ridge of the South Mountain, close to
Allentown, which forms the southern barrier of the Lehigh
to the oxidation of the ferrous oxide it contains. The change
‘om a pudding-stone to a compact quartzite in the sandstone
shows that there has been a a sinking of the earth's crust
and an increase in the depth of the sea, thus preparing the way
for the subsequent deposition of the limestone.
e Potsdam sandstone often, as elsewhere, contains Scolithus.
Next above the Potsdam sandstone oceur hydromica slates,
which Rogers has called the Upper Primal Slates, but which
really form a portion of the No. LI limestone, and gradually pass
into this. They lie along the north flank of the South Mountain
and cverlie the Pots Jam conformably wherever this is visible,
eing far more persistent in their occurrence, continuing with
few intervals the entire distance from the western boundary of
Lehigh county to the Delaware River. They are of great eco-
nomic importance as carrying the lowest range of brown hem-
atite iron ores, to be mentioned later. :
se slates are composed in t part of the mineral
damourite and occur of a pink, Sigil and yellow color.
F.. Prime, Jr.— Lower Silurian Fossils, 263
When exposed to the weather they very rapidly decompose to
soft unctuous plastic clays in a few days, and some of these
will in time probably become valuable in the manufacture of
coarse kinds of pottery. Generally they contain more or less of
the carbonates of lime and magnesia, and silica, mixed with the
damourite.* Hydromica slate also occurs the greater portion of
the distance from the western boundary of Lehigh county to
the Delaware River, at the junction of the No. IT limestones
with the No. III slates, here also carrying brown hematite ores
in extensive deposits.
It also occurs intercalated in the limestone, forming layers
from the thickness of a sheet of paper to several feet, and these
layers are innumerable. Their existence has been seen both in
rock outcrops as well as in wells which have been sunk.
The clay to which the hydromica slate decomposes is gener-
ally of a white color, although sometimes brown from the pres-
d
Overlying the hydromica slates, and conformable with these and
the Potsdam sandstone, is the No. II or Magnesian limestone ( u-
roral of Rogers), which extends as a great inass varying Jrom six to
It disappears, however, in the upper stra
The limestone varies fr i ? ‘
being for the most part compact to semi-crystalline, while there
are occasionally shaly beds. In composition it varies much.
often approaching a true dolomite, again a pure limestone. But
from the isolated analyses made it would seem as if or per-
centage of magnesia was less in the upper beds than the lower
ones. The limestone is always siliceous, often very much
and hence much care is now being taken by many of the iron-
i i s of it, which are low in silica, so as to
masters in selecting beds of it, whic Oo nak vdeo
Tt often contains minute
i i : f Penn., p. 12.
* Report of Progress for 1874 of Lehigh Dist. Geol. Survey :
+ See Geology of Tennessee, by Safford, pp. 215, 218.
264 F. Prime, Jr.—Lower Silurian Fossils.
grains of pyrite disseminated through it, which weather out on
exposure, leaving minute cavities behind. Numerous analyses
have shown the presence of ferrous carbonate varying in amount
from 0°588 to 1°305 per cent.
A peculiarity of the limestone is that it is often brecciated,
the fragments being composed exclusively of limestone, cemented
together by calcite or dolomite. The brecciated appearance is
rarely visible on fresh fracture, being usually brought to view
y weathering. When seen in place it will usually be found
that one or more brecciated beds occur between two others
which do not exhibit this peculiarity. As the beds of the No.
II limestone have been much disturbed by the force which ele-
vated the South Mountain range, the probable explanation of
this brecciation is that a very hard, unyielding bed occurs be-
tween two more pliable ones; that these, when subjected to the
lateral thrust of the uprising mass of the South Mountains,
have couformed themselves to the folds of the strata, while the
harder one, being unable to do this, has been fractured and re-
cemented in sitt by the percolation of calcareous waters.
stone (according to these observers) having been formed from
the lower, the brecciated limestones are adduced as evidences
of upheaval and shore action.
The explanation I have offered of the formation of the bree-
ciated limestone is both more in accordance with the facts ob-
served and with the generall accepted view of the deep-sea
formation of limestone than the hypothesis above stated ; for
the brecciated limestones are as common near the base of the
series as at the top.
ides, the genus Monocraterion found in the Lehi
limestone belongs to the same family as Scolithus, saat is there-
fore no greater proof of age than the latter; and it occurs in
o. II, being not more
than fifty to one hundred feet from the overlying Calciferous
and Trenton.
_humber a dozen specimens, and have been found in but four
localities. At Helfrich’s Spring, about two and a half miles
west end of the hill, near
of the creek forming the s
species of Monocraterion, as yet undescribed. Of this half a
F. Prime, Jr.—Lower Silurian Fossiis, 265
dozen casts have been found; but all efforts to discover the
fossil itself have been hitherto unsuccessful. This discovery is
the more interesting as the genus Monocraterion has hitherto
only been known to occur in Sweden.
About half a mile northeast of this five or six specimens of
a Lingula were found in John Schadt’s quarry, but it is impos-
sible to determine its species. About half a mile west o l
frich’s Spring a single specimen of an Orthoceratite was found
_ close to the Jordan, just north of Scherer’s Tavern, but so im-
perfect that its species is undeterminable. Finally a specimen
of Huomphalus was found on Nero Peters’ farm, two miles east
of Ballietsville.
Not a single fossil has thus far been found in the No. IL
limestone of Northampton county.
The No. II limestone, like the Magnesian limestone of the
Mississippi Valley, is exceedingly soluble. Streams constantly
isappear in the ground, forsaking their original beds except
when the volume of water is too great to be carried off by the
subterranean channels, only to reappear again as springs at
eater or less distances. The effects due to this solution of the,
action could begin. The different beds too are soluble in very
different degrees; some apparently yield at once to the eroding
action of water, while others afford a resistance to this operation
for reasons as yet unknown, but which are probably rather me-
chanical or physical than chemical. Knowing as we
little of the conditions, under which the different layers of
limestone, almost or quite identical in composition, were
formed, we can only speculate that those layers which resisted
erosion were more compact, hard, and dense, perhaps more
metamorphosed by a subsequent crystallization than the others,
while we actually have no facts on W ich to base such theories.
No better illustration of the darkness amidst which geologists
other. We can explain alternations of shale,
limestone by changes in depth of the sea in which they were
formed ; but such an explanation does
266 F.. Prime, Jr.— Lower Silurian Fossils.
continuity have occurred, to be succeeded by another layer of
the same material?
While the greater portion of the limestone has in all proba-
bility been formed in deep water, we have one instance in a
quarry at Uhlersville on the Delaware where it must have been
formed as a beach, since we find here distinct traces of ripple
marks along the entire face of the quarry, some sixty feet high
and fifty feet deep, the strata being tilted nearly vertically.
It has been generally supposed that the limestone dips almost
universally southward; and while this view holds good for
orthampton county, except at the junction of No. II with the
No. III slates and ‘along the north flank of the South Moun-
tains, it is not the case in Lehigh county; for here we find
northwest dips, more especially along an axis which is pro-
longed some distance into Northampton county, a short distance
As a general thing the limestones pass conformably under the
“No. III slates, and the few exceptions where the slates dip
toward the limestones, and the latter away from the slates can
readily be explained by an overturning of the beds toward the
south, by which means as in the slate ¢ uarry close to and south
of Ironton the slate apparently passes conformably below the
limestone.
Overlying the No. IT limestone occurs the Trenton limestone
which is more fossiliferous and contains such characteristic
fossils as Cheetetes Lycoperdon and Orthis pectinella as well as the
stems of an encrinite. It was first found about a mile south of
This limestone resembles. in appearance the No. II, being
however more compact and not at all crystalline, and of a gray
black color.
There has been no apparent sudden break between the two,
but the transition has been a nal one, This was to be ex-
pected if the subsidence of the sea-bottom was steady and slow.
_ An examination of the beds between Ironton in Lehigh county
and the Delaware River, as close to the junction of the limestone
+
F. Prime, Jr.—Lower Silurian Fossils. 267
proportion of alumina which it contains. This also was to be
expected if the subsidence continued, as signaling an approach
to the era of slate-formation and open-sea deposition. These
limestones are utilized on the Lehigh river in the manufacture
of hydraulic cements and lately Portland cement has been made
at the Copley Cement Works, which is said to be nearly or quite
equal to the imported. Careful search and the demand for it
will no doubt cause this variety of the limestone to be explored
at various other points in the two counties, and will in time
render us independent of the cement now sent from the Hudson
River. The limestone is of a dull, earthy appearance, entirely
free from any crystalline texture and of a dark gray color.
Before closing our discussion of the limestone it is necessary
to speak of the large and numerous deposits of brown hematite
iron-ore which occur in it, and which form the main support of
the extensive iron furnaces of the Lehigh and Schuylkill
Valleys. : ;
The brown hematite iron-ore occurs almost exclusively in
two irregular lines of deposition; the one along the northern
flank of the South Mountain Range, the other at or near the
junction of the No. II limestone with the No. III slates. A
few other localities, at which the ore is found, but these are 1n-
significant in number compared to the two lines mentioned.
with damourite; the same _ else
brown hematite is found zn Joco originale. its ar
however found which have evidently been pockets or cavities in
the limestone into which the masses of limonite have been
ing the Drift Period.
let
more especially potash, points to :
from Archzean rocks containing orthoclase
ecomposition of these three
all the oxides above mentioned
have been derived from iron pyrites,
268 F. Prime, Jr.—Lower Silurian Fossils.
which the latter offers to chemical change of any kind when
exposed to the action of air and water, and its unaltered condi-
tion and fresh, bright appearance in rivers and on the seashore.
But the question as to how the brown hematite got into its
present condition and whether it was deposited cotemporane-
ously with the rocks containing it, or subsequently to these, is
hydromica region of Connecticut. Hence we must have recourse
to other sources. It seems most doubtful that the mineral,
ates. Whence was it derived? I have already stated that
the limestone contains varying proportion of ferrous carbonate
and of pyrite, and when we consider the enormous erosion
which the limestone has undergone, the wonder is not that the
eposits of iron ore should be so great, but rather that they
should be so small. The ferrous carbonate and the pyrite oxl-
dised to ferrous sulphate being both soluble in water, the former
when the wa
became later decomposed by the action of aerated
water to hydrated ferric oxide and free silica, which latter we
where the No. ITI limestones oce
_ It is well here to emphasize the fact that these brown hema-
tite ores all belong to the Lower Silurian limestone formation,
|
|
|
C. 8. Hastings—Optical Constants of Glass. 269
since, in 1874, Dr. Sterry Hunt, after a cursory examination
of Ziegler’s Mine in Berks County, situated at the junction of
the No. II limestone and the No. III slates, made the mistake,
in a paper on “The Decay of Crystalline s” before the
National Academy of Science, of supposing that the hydromica
slates belonged to the Huronian Period :—a mistake into which
so eminent an observer as himself would never have fallen had
he been better acquainted with the region.
At intervals along the junction of the limestones and slates
there occurs a black carbonaceous shale, often decompose
black or dark blue clay, which I have supposed to be the rep-
resentative of the Utica shales. It consists of a very carbona-
ceous hydromica slate (containing damourite), without any fos-
sils and may not belong to the Utica Period at all. In no
instance has it been found more than one to twelve feet thick,
but it sometimes carries pyrite from which a portion of the iron
ores, just mentioned, may have been derived. These shales
are of no economic im
opened at various points for the purpose of extracting them, as,
however, they have been but very slightly examined, during the
progress of the present Geological Survey of the State, I shall
defer a more detailed description of them to some future time.
Art. XXXIX.—On the Influence of Temperature on the Optical
Constants of Glass ; by CHARLES S. Hastines, of the Jobns
Hopkins University.
A FORMULA connecting the refractive power of a body with
its density, established by Newton, 1s well known. This,
er. :
More recently rear: Gladstone have made an extensive
study of the changes produced in the refractive and as cor
powers of various liquids by increase of temperature; @ study
270 C. S. Hastings— Optical Constants of Glass.
ever, to much less accordant results. Rudberg, in investigating
the optical properties of several crystals, found that in arrago-
nite and quartz, the variations in density and refractive index
are in the same direction, but that with -calcite the case is
different, the index for the ordinary ray seeming inde-
pendent of changes in tem erature, and for the extra-
r
an elegant and celebrated method. I shall quote later, some
- es ees the only quantitative ones which I have been able
o find.
The instrument with which the following determinations were
made, is the large spectrometer by Meyerstein, belonging to
the Physical Laboratory of the Johns Hopkins University.
The circle is 12 inches in diameter, divided to 6’, and reads by
two microscopes to 2”. The probable error of one division is
1”-48, and its larger periodic errors are expressed in the formula
=2"°386+7''82 sin (2+62° 36’)+2.1 sin (2 z2+157°)
+432 sin (3 2+328°)+0’-46 sin (4 z+122°)
N being the corrected and z the immediate reading.
Much labor was expended in putting the instrument in so
satisfactory a state, for in order to secure uniformity of reading
it was found necessary to re-grind the axis. The collimating
telescope too, was, by inexcusable carelessness in construction,
directed nearly one-fourth of an inch away from the axis, thus
vitiating all determinations of double deviations by the intro-
duction of unknown errors of aberration in the object glass.
rea
‘two verniers to single minutes of are. This platform turns
independently of the large circle with inconsiderable friction,
and upon it is placed the prism to be studied. The methods
adopted to adjust the instrument and prism, and to measure
the angle of the prism were exceedingly accurate and perhaps
& proper place for description here.
:
|
se amcecmemnmeaaeeae eee
cee en eee a a aD
C. & Hastings—Optical Constants of Glass. 271
In the focal plane of the positive eye-piece was a reticle con-
sisting of lines on glass ruled as follows :—a system of two
airs of parallel iines crossing at center of field, one pair being
orizontal and the other vertical, the angular distance (measured
from objective) between the components of each pair being
about 1’; and a single line, vertical and about 25’ to the right
of the vertical pair. Over this single line was placed a small
totally reflecting prism, one of its faces turned toward an open-
ing in the eye-tube. The advantage of this arrangement is at
once evident, for it was possible to get a strongly illuminated
image of the single line, reflected by a plane beyond the
objective, between the two vertical lines, at the same time
avoiding the annoyance of waste light reflected from the eye-
lenses on the one hand, since the mirror was within the eye-
piece, and from the objective on the other, owing to the eccen-
tric position of the mirror. :
instrument was put in adjustment by means of a piece
of plane-parallel glass placed vertically upon the platform, ie,
so that its plane was parallel to the axis of the instrument.
Then the glass was turned 180°. If the image of the horizontal
lines corresponded with the lines themselves it was aes ; if not,
the correction was divided between the glass and the telescope.
Proceeding in this way, it was easy to adjust the telescope so
that once sighting the reflected image it would be again visible
i i lass 180°, and that inde-
pendently of the azimuth of the platform as referred to the
axes of the instrument and platform are parallel, while that of
the telescope is perpendicular to both. The proper adj ustment
of the collimating telescope as regards focus and direction, is so
evidently attainable from these that it is not worth while
describing it spevially.
i i i ” in the prism
same intensity, and that a motion of but 30” in
would carry the reflected line from one of the pair to the other.
272 C. 8. Hastings—Optical Constants of Glass.
The next step was to rotate the great circle, and with it the
prism, until the other face took exactly the same position ; the
reading then would clearly be the supplement of the desired
angle ; in practice, however, the angle was repeated by turning
back the platform independently of the circle, the repetition
being carried usually to six times, and then back over the same
ground for verification. This method was well adapted to this
work as the mass moved independently was small, and turned
with little friction. It failed however, as might be expected, in
measuring later the angles of deviation, for here the joints to be
turned were much larger, and that limit of accuracy which is
always reached so easily and quickly by the method of repeti-
tion, was not below that of a single reading of the microscopes.
f the adjustment of the prism for measuring the double
angle of deviation for the different Fraunhofer lines, little need
be said except that, besides the care taken in placing the sur-
exist in every lens save for rays of a single wave length, or, in
rare cases, of two wave lengths. :
The position of the prism for minimum deviation of a single
line was carefully determined on the small circle attached to
the platform, by experiment, while those of the other lines
observed wefe computed after an approximate measurement
of the angle of deviation.
point the telescope upon the particular Fraunhofer line which
as to be ism in i
etermined, with the prism in its first position of
ation and in, the difference of readings being the
double deviation required. With this observation was also
put the temperature of the prism at the pido mepri
thermometer reading to quarter degrees, estimated, however, to
tenths, and then filled with water. The reading of the barom-
ay
daneieaunt
4
;
j
:
;
C. S. Hastings—Optical Constants of Glass. 273
amount determined from the formula given above. The prisms
were as follows
I, Of Feil’s flint glass, No. 1237, sp.
-» D554,
of prism, 60° 4' 56"-210"'18,
ng
III, Of Feil’s crown glass, No. 1219, sp. gt, 2°482.
Angle of prism, 60° 10’ 9”°04+-0"°23.
IV, Flint glass, sp. gr., 3°497.
Angle of prism, 50° 7’ 53”°01-0"-20.
V, Crown glass, sp. gr., 2°510.
Angle of prism, 59° 48’ 127-404-0"-08.
The materials of IV and V have been in my possession a
long time, and there is no way to determine what they are
except from their optical properties, and the statement of the
optician from whom I procured them, that the first is of French
and the second of English manufacture. I suppose IV to be a
flint glass of Feil’s making, while V is doubtless of the so-called
‘soft crown” of Chance Brothers.
he temperature affecting the observations ranges from
14°-9 ©. to 29° C., though most of the lines were measured
with a maximum difference of 10° C.
The reduction of the observations on the first three prisms
to a temperature of 20° C. and barometric height of thirty
inches gave the following indices of refraction :
Temperature, 20° C. Barometric height, 30 inches.
i IL. TL
Line. n e n e n ée
A 1°615258 +3 1572464 | +6 1512456 | +3
B 1-618706 3 1575332 7 1514369 3
CG 1620482 3 1576815 6 1515334 3
2 1°62542 3 1°580905 6 [517965 3
5614 1°628001 2 17583024 6 1519292 3
1°631893 2 1586214 ' 521274 3
1637756 2 1°590989 5 524182 3
4548 1°643524 3 1595660 , 526981 3
1°649086 3 1°600129 Y 1°529597 3
h 1°654848 3 1604749 y 1°532251 3
3951 1°659757 2 | 1608658 V4 1°534458 3
which the indices of refraction, in columns hea n, reter.
The last line is beautifully defined and lies nearly midwa
between H, and H,. The columns under e give the probable
errors of each determination in units of the sixth place decimal.
It should be remarked here that the larger probable errors 10
the determinations of prism II arise from the greater probable
error in the determination of its refracting angle, hence the
27+ C. 8. Hastings—Ortieal Constants of Glass.
values are relatively, though not absolutely, as accurate as the
ers.
The following table contains, in the columns under #
’
increase of refractive index also in units of sixth place, corres-
ponding to an increase of 1° C. in temperature.
is ii FEE
Line. i’ k Kk’ k ke K
A 4°12 3°79 1:70 1°74 caf — "iT
B 4°04 4°22 2°35 2°04 = <oe — 53
C 3°96 4°45 277 2719 — 06 — ‘i
D, 5°12 5°07 2°43 2°61 — 00 — '08
5614 6°58 5°40 2°56 | 2°84 + “04 ee le
E 54> 5°87 2°68 3°16 + 36
F 5°69 6:57 3°52 3°63 — °09 + “14
4548 7:24 4°32 4°09 +111
G 8°53 7°85 3°86 4°51 +1°26 +144
h 8°03 8°48 4°78 493 +1°05 +1°78
3951 9°2] 8:99 6-04 5°28 + 3°22 + 2°06
It is evident at a glance that the values of k’ increase in each
case with the decrease of wave length; and it was found that
the quantities could be embodied, within the limits of error of
the observations, by a formula of the form
1\2
The significance of the constants a and # is clearly that the
first is the change in refractive power for light of indefinitely
great wave length, or briefly, the change in refractive gt
z
SE Aue Pew Rene eS fen 1°875-+-1°1105,.
1
i 8 eae k= 4424. “15555:
i
Ill nie --k=—1'813-+0°6045,.
: f glass, computed in the
ordinary way, are as 9:8:6 nearly, while the coefficients 10
|
|
.
Fal ea
Ser Re Mae ka kee Se Re
eee ies eC ka ee ee
C. 8. Hastings— Optical Constants of Glass. - 275
question are as 9:6:5 nearly; hence if this relation holds
approximately for all optical glasses, as is probable, an achro-
combination good for one temperature is good for all
others within moderate limits.
Fizeau found, in the researches before alluded to, values for
the refractive increment for 1°C., not unlike our own, namely :
Crown glass (zinc), sp. gr., 2°626, Ap>=0°00.
Common flint glass, sp. gr., 3°584, Ap>=2°6.
Dense flint glass, sp. gr., 4°14, Ap=6°87.
The magnitudes of the quantities £ show at once the importance of
observing the temperature of the prism in every accurate deter-*
mination of refractive indices, neglect in so doing generally viti-
ating the fifth decimal place. It may be remarked, too, that
ordinary variations in barometric pressure cannot be neglected
when it is desired to limit the errors to the sixth decimal place.
The prisms IV and V were not studied to determine the
Temperature, 20° C. Barometer, 30 inches.
Line. IV. Vv.
A 1°603945 509607
B 1607306 611584
C 17609041 512580
“Ds 1°613843 515288
5614 1°616333 [516673
1°620103 518719
F 1°625751 521696
G 1°636702 1°527300
h 2 284 1°530075
3951 1°647048 1°532381
The probable errors were not computed, for the reason that the
temperature corrections were assumed; but as regards their
accuracy, the values under IV are perhaps quite as good as
those which go before; those under V, on the other hand,
have much larger errors, though probably in every case below
two units in the fifth place. Ti is finds its explanation in the
fact that the material was not homogeneous, thus giving less
perfect definition than the others, though the surfaces of the
ing the theory of the astronomical objective.
Johns Hopkins University, January, 1878.
276 A. M. Mayer—Experiments with Floating Magnets.
Art. XL.—A note on Experiments with floating Magnets ; showing
the motions and arrangements in a plane of freely moving bodes,
acted on by forces of attraction and repulsion ; and serving in
the study of the directions and motions of the lines of magnetic
force ; by ALFRED M. Mayer.
For one of my little books of the Experimental Science
Series I have devised a system of experiments which illustrate
the action of atomic forces, and the atomic arrangement in
‘molecules, in so pleasing a manner, that I think these experi-
ments should be known to those interested in the study and
teaching of physics.
A
Four floating needles take these two forms
Five a“ a“ “c “i “ 4“
.*
Six ab “ sé nm ae ti F
.
Seven “ “ sb “we ““
I have obtained the figures up to the combination of twenty
ree needles. Some of these forms are stable; others are
unstable, and are sent into the stable forms by vibration.
hese experiments can be varied without end. It is cer-
tainly interesting to see the mutual effect of two or more
I. CG. Russell—Triassie Trap Sheets of New Jersey. 277
vibrating systems, each ruled more or less by the motions of its
own superposed magnet; to witness the deformations and
decompositions of one molecular arrangement by the vibrations.
of a neighboring group, to note the changes in form which take
place when a larger magnet enters the combination, and to see
the deformation of groups produced by the side action of a
magnet placed near the bowl.
n the vertical lantern these exhibitions are suggestive of
much thought to the student. Of course they are merely sug-
as to the grouping and mutual actions of molecules in space.
1 will here add that I use needles floating vertically and
horizontally in water as delicate and mobile indicators of mag-
netic actions; such as the determination of the position of the
oles in magnets, and the displacement of the lines of magnetic
orce during inductive action on plates of metal, at rest and in
motion.
The vibratory motions in the lines of force in the Bell-tele-
phone have been studied from the motions of a needle (float-
ing vertically under the pole of the magnet), caused by moving
to and fro through determined distances, the thin iron plate in
front of this magnet. These experiments are worth repeating
by those who desire clearer conceptions of the manner of action
of that remarkable instrument.
Art, XLL—On the Intrusive Nature of the Triassic Trap Sheets
of New Jersey; by I. CO: RUSSELL.
ALTHOUGH the trap sheets which traverse the Triassic rocks
of New Jersey and of the Connecticut Valley are commonly
spoken of as being dikes of igneous rocks, yet the proof of
tary rocks, is very positively shown.
The rid nee See Jase have a general north and
south direction, usually conformable with the strike of the
associa sa
of the Triassic formation. The trap rocks, also, seem neually
to be conformable in dip with the stratified rocks above and
below them. ‘These facts, together with the consideration of
278) «=. C. Russell—Triassic Trap Sheets of New Jersey.
the rare occurrence of the exposure of the junction of the trap
rocks with the stratified rocks that overlie them—owing to the
removal of the latter by denudation, and to the line of contact
‘being covered with drift or overgrown by vegetation—have led
to the supposition that the sheets of trap were not intrusive, but
were formed cotemporaneously with the shales and sandstones
as a bed or stratum of igneous rock, which was spread out in a
molten condition at the bottom of the shallow sea in which the
strati rocks were being deposited. The question in hand,
then, is to determine (1) whether the plutonic rocks of the
Triassic were spread out as a sheet of molten matter and allowed
to cool and consolidate before the rocks that rest upon them
were deposited, both, therefore, belonging to the same geolog-
ical period; or (2) were the trap rocks forced out in a fused state
among the sedimentary strata after their consolidation, which,
consequently, would make them more recent than either the
rocks above or below them.
ewark Mountain, for some twenty miles of its course in the
neighborhood of Plainfield, New Jersey. We hoped by making
t.
2d. To determine, if possible, if the trap sheets seem in all
eases to be conformable in bedding with the stratified rocks
with which they are associated.
_ It is not difficult to find the junction of these igneous rocks
with the shales and sandstones that underlie them. In all such
of places in the shales and sandstones beneath the trap rocks in
eo Plainfield, New Jerse :
ese 0 indi
I. C. Russell—Triassic Trap Sheets of New Jersey. 279
were at one time inclined to suppose, before the sandstones and
shales above them were deposited, then, of course, the rock
ain,
Jersey, and near the little deserted village of Feltville, the de-
sired junction is very plainly shown. We there found one
page of the history of the Triassic formation clearly legible.
At this locality the stratified rocks are well exposed in the
sides of a deep ravine which has been carved out by a smal]
brook that flows down the western slope of the mountain.
overlying rocks. The outside of these masses present a scorla-
ceous or slag-like appearance; in the interior the cavities are
filled with Re illtchted misenia The shales that rest directly
have been intensely metamorphosed, and are scarcely to be dis-
tinguished from the trap itself In hand specimens It 1s fre-
quently impossible to determine from their appearance alone
which is trap and which is metamorphosed shale. Ata distance
of six or eight feet above the trap the shales are still very much
é ightly, if at
trap, the shales and sandstones are changed but slightly, if at
all, from their normal condition. A bed of limestone teh bs
to three feet in thickness, which is here interstratified with the
shales and sandstones—a very rare occurrence In the Triassic
280 =. € Russell—Triassic Trap Sheets of New Jersey.
formation of New Jersey—where it approaches the trap is con-
siderably altered and forms a mass of semi-crystallized carbon-
ate of lime. :
cia have been filled by infiltration with calcite and zeolites.
This interesting material seems to have a history somewhat
similar to that of the “ friction breccias,” mentioned by Von
otta, as occurring at the margins of eruptive igneous rocks,
and formed at the time of their eruption. ;
the igneous 8, composing the First Newar n, were
intruded in a molten state between the layers of the stratified
r subsequent to their consolidation. As these mountains
may be that one is thousands of years older than its neighbor.
As regards the conformability of the trap sheets with the
associated sedimentary rocks, we have but little information to
offer, independent of the section at Feltville which we have
already described. The curved course which a number of the
trap ridges in New Jersey follow, seems to indicate that they
ust cut across the strata of the sedimentary rocks, which,
throughout the whole Triassic area in New J ersey, have a
nearly uniform dip of from twelve degrees to fifteen degrees
toward the northwest.
H. A. Rowland—Absolute Unit of Electrical Resistance. 281
Art. XLIL.—Research on the Absolute Unit of Hlectrical Resist-
ance; by Henry A. Row.anp,* Professor of Physics in the
Johns Hopkins University, Baltimore, Md.
Preliminary Remarks.
SINCE the classical determination of the absolute unit of elec-
ment, the induction current was uced by reversing the
main current, and in Kirchhoff’s by removing the circuits to a
distance from each ot And ms to me that this
In the carrying out of the experiment I have partly availed
f my own instruments and have partly drawn on the
he experiment was performe :
house near the University, which was reasonably free trom
* I am greatly indebted to Mr. Jacques, Fellow of the University, who is -
excellent Sherrer for his assis uring the experiment, particularly in read
the nt gal
282 Hf. A. Rowland—Absoiute Unit of Electrical Resistance.
sary to select a region entirely free from such disturbance.
The small probable error proves that sufficient precaution was
taken in this respect. a
The result of the experiment that the British Association
unit is too great by about ‘88 per cent, agrees well with Joule’s
experiment on the heat generated in a wire by a current, and
makes the mechanical equivalent as thus obtained very nearly
that which he found from friction: it is intermediate between
the result of Lorenz and the British Association Committee;
and it agrees almost exactly with the British Association Com-
mittee's experiments, if we accept the correction which I have
applied below.
The difference of nearly three per cent which remains be-
tween my result and that of Kohlrausch is difficult to explain,
but it is thought that something has been done in this direc-
tion in the criticism of his method and results which are en-
tered into below. My value, when introduced into Thomson’s
light: but experiments on this ratio have not yet attained the
highest accuracy.
History.
The first determination of the resistance of a wire in absolute
stan stance. However we know that the wire was of
copper and the temperature 0° R. and that the result obtained
* Bestimmung der Constanten von welcher die Intensitat inducirter elektrischer
Stréme abhangt. Pogg. Ann, Bd. 76, S. 412,
+ Elektrodynamische Maasbestimmungen; or Pogg. Ann., Bd. 82, 8. 337.
H, A, Rowland—Absolute Unit of Electrical Resistance. 288
the damping of a swinging needle. Three experiments gave
for the resistance of the circuit 1903-108, 1898-108, and 1900-108
mine ; ° .
—, but it is to be noted that a correction of five eighths per
cent was niade on account of the time, two seconds, which it.
took to turn the earth-inductor, and that no account was taken
of the temperature, although the material was copper. He finds
for the value of the Jacobi unit, 598-107 a Three years after
that, in 1853, Weber made another determination of the spe-
cific resistance of copper.* But these determinations were
more to develop the method than for exact measurement, and
it was not until 1862+ that Weber made an exact determina-
tion which he expected to be standard. In this last determin-
ation he used a method compounded of his first twoemethods
by which the constant of the galvanometer was eliminated, and
the same method has since been used by Kohlrausch in his
experiments of 1870. The results of these experiments were
embodied in a determination of the value of the Siemens unit
and of a standard which was sent by Sir Wm. Thomson. As
The matter was in this state when a committee was appointed
by the British Association in 1861, who, by their so pevenen 4
which have extended through eight years, have done so mac
in the magnetic meridian also causes re
volving coil which deflects the needle from that —
Whenever a conducting body moves in a magnetic le is
rents are generated in it in such direction that the total re-
* Abb. d. Kon. Ges. d. Wissenschaften zu Gottingen, Bd. 5. : :
+ Zar Creivimcstattie; Gattingen, 1862. Also Abh. d. K. Ges. d. Wis. zu Got-
tingen, Bd. 10.
984 H. A, Rowland—Absolute Unit of Electrical Resistance.
sultant action is such that the lines of force are apparently
dragged after the body as though they met with resistance
in passing through it: and so we may regard Thomson's
method as a means of measuring the amount of this dragging
action.
' But, however beautiful and apparently simple the method
may appear in theory, yet when we come to the details we find
many reasons for not expecting the finest results from it.
Nearly all these reasons have been stated by Kohlrausch, and I
ean do barely more in this direction than review his objections,
point out the direction in which each would affect the result,
and perhaps in some cases estimate the amount.
In the first place, as the needle also induced currents in the
coil which tended in turn to deflect the needle, the needle must
have a very small magnetic moment in order that this term may
be small enough to be treated as a correction. For this reason
the magnetic needle was a small steel sphere 8 mm. diameter,
and not magnetized to saturation. It is evident that in a qui-
escent magnetic field such a magnet would give the direction
of the lines of force as accurately as the large magnets of Gauss
and Weber, weighing many pounds. But the magnetic force
due to the revolving coil is intermittent and the needle must
show as it were the average force, together with the action due
to induced magnetization. Whether the magnet shows the
dragged with the coil, and hence makes the deflection greater
than it should be, and the absolute value of the Ohm too small
e.
: The mere fact that this small magnet was attached to a com-
paratively large mirror which was exposed to air currents
could hardly have affected the result, seeing that the disturb-
ances would have been all eliminated except those due to air
currents from the revolving coil, and which we are assured did
not exist from the fact that no deflection took place when the coil
was revolved with the circuit broken. In revolving the coil in
posite directions very different results were obtained, and the
H. A, Rowland—Absolute Unit of Electrical Resistance. 285
and the deflection was diminished by its torsion 00132. No
mention is made of the method used for untwisting the fiber,
and we see that it would require only 2°11 turns to deflect the
needle 1° from the meridian. To estimate the approximate
effect of this, we may omit from Maxwell’s equation* all the
other minor corrections and we have
__GKw cos p =} a ae ft ) nearly,
where we have substituted g—f for g in Maxwell's equation
in the term involving 4 In this equation 7 is measured from
the magnetic meridian; but let us take # as the angle from the
point of equilibrium. en p’=g’+a and et ad where
~’ and g’ are for negative rotation and #” and @” for positive
1
R=}
rotation and a= are sin =—
14+¢
Let ‘oa eect
. —~ GKw
Then CR
= tan p(1+#)’
; 1
CR ite
; R=3(R'+R’).
Where R’ and R” are the apparent values of the resistance as
calculated from the negative and positive rotations, and R, is
the mean of the two as taken from the table published by the
British Association Committee. If R is the true resistance,
1 |
OR= oe
sin a’ ‘ es
tan @'(1-H0)(14 <) tan 9'(40(1~ in =)
We shall then find approximately
oS 1+ tan yp’ tana Be: —— —
F sin a tana ii ei
R14 sin 3) (1- tan yp" . (: sin p" ( a tan?
When a is small compared with #” or y’, and when these are
also small, we have
RER(parat—W)tes)
So that b¥ taking the mean of positive and negative rotations,
the pedis of bortibs is almost entirely aiimpinated. Ne
the angle by which the needle is deflected ge t = mag
meridian by the torsion and its value is 3 (1-7) nearly,
+ « Reports on Electrical Standards,” p. 103.
1—tany” tana
286 H. A. Rowland—Absolute Unit of Electrical Resistance.
when @ is small, and this, in one or two of their experiments,
exceeds unity or a exceeds 28°°6, which is absurd. Taking
: R ;
even one of the ordinary cases where —‘=1'02 and + is about
zo, We a=12° nearly, which is a value so large that it
would surely have been noticed. e may conclude
that no reasonable amount of torsion in the silk fiber could
these currents, but has failed to consider the theory of them.
Now, from the fact that after any number of revolutions the
number of lines of force passing through any part of the appa-
ratus is the same as before, we immediately deduce the fact
that, if Ohm’s law be correct, the algebraical sum of the cur-
rents at every point in the frame is zero, and hence the average
magnetic action on the needle zero. But although these cur-
rotation, the effect is nearly but not quite eliminated. The
amount of the effect is evidently dependent upon the velocity
of rotation and increases with it in some unknown proportion,
and the residual effect is evidently in the direction of making
the action on the needle too small and thus of increasing R.
- these currents are the cause of the different values of R
a ta with positive and negative rotation, we should find
at if we picked out those experiments in which this difference
was the greatest, they should give a larger value of R than the
others. Taking the mean of all the results} in which this dif-
Reports on Electrical egrysa London, 1873, p. 191.
and hare thong probate that te ae tre Sein Sl nt i a
column should read 1:0032 and 1-0065 instead of 1:0040 and ‘9981, and in my
discussion I have considered them to read thus. i ii
H.. A. Rowland—Absolute Unit of Electrical Resistance. 287
ference is greater than one per cent, we find for the Ohm
10083 earth quad.
sec.
earth quad.
sec.
, and when it is less than one per cent, 9966
, Which is in accordance with the theory, the aver-
age velocities being 49.2 and 44° nearly. But the individual
observations have too great a probable error for an exact
colnparison. Sie
But whatever the cause of the effect we are considering, the
following method of correction must apply. e experiments
show that R is a function of the velocity of rotation, and hence,
by Taylor's theorem, the true resistance R, must be
R,=R(1+Aw+Bw?-+ &c.),
and when R is the mean of results with positive and negative
rotations,
R,=R(1+Bu?+Du!+&c.).
Supposing that all the terms can be omitted a the first
two, and using the above results for large and small velocities,
we find R, = 9926 =e But if we reject the two results
in which the difference of positive and negative rotations is
over seven per cent, we find
R,="9034 sahanns,
The rejection of all the higher powers of w renders the cor-
rection uncertain, but it at least shows that the Ohm is some-
what smaller than it was meant to be, which agrees with my
ex periments. : :
t is to be regretted that the details of these experiments
have never been published, and so an exact estimate of their
value can never be made. Indeed, we have no data for deter-
mining the value of the Ohm from the experiments of 1863.
All we know is that, in the final result, the 1864 experiments
had five times the weight of those of 1868, and that the two
results differed ‘16 per cent, bat which was the larger is not
stated. Now the table of results published in the report of the
1864 experiments contains many errors, some of which we can
find out by comparison of the columns. The following cor-
rections seem probable in the eleven at
fifth columns, read 1:0032 and +082 in place of 1-0040 an
+0-40. No. 11, fourth and fifth columns, read 10065 =
+0°65 in place of 09981 and —0'19. Whether we make
288 H. A. Rowland—Absolute Unit of Electrical Resistance.
' With the corrections the mean value of the 1864 experiments
is 1 Ohm = 1-00071 St auae’
fourth column, it is 100014. With the corrections the dif
ference between fast and slow rotation is ‘6 per cent.
, and without them, using the
being one formed out of a combination of Weber’s two methods
of the earth inductor and of damping, by which the constant of
the galvanometer was eliminated, and is the same as Weber
used in his experiments of 1862. His formula for the resist-
ance of the circuit, omitting small corrections, is
_ 3282T?2,(A—A,) AB
= ?K (A2--B?)?
where S is the surface of the earth inductor, T is the bori-
zontal intensity of the earth’s magnetism, K the moment of
inertia of the magnet, ¢, the time of vibration of the magnet,
A the logarithmic decrement, and A and B are the ares in the
method of recoil.
an
wv
approximately,
wire occupied two per cent of the radius of the coil, making it
uncertain to what point the radius should be measured. As
the coil is wound, each winding sinks into the space between
the two wires beneath, except at one spot where it must pass
it would diminish the value of S? 1:4 per cent, and make
Kohlrausch’s result only °6 per cent greater than the result of
the British Association Committee. ~
‘Three other quantities, T, A and K, are very hard to deter-
mine with accuracy, and yet T enters as a square. It is to
H. A. Rowland—Absolute Unit of Electrical Resistance. 289
be noted that this earth-inductor is the same as that used by
Weber in his experiment of 1862; and which also gave a larger
value to the Ohm than those of the British Association Com-
mittee. Indeed, the results with this inductor and by this method
form the only cases where the absolute resistance of the Ohm has
Association Committ
There seems to be a small one-sided error in A and B which
Kohlrausch does not mention, but which Weber, in his old
experiments of 1851, considered worthy of a 6 per cent cor-
been found greater than that from the experiments of the British
tee.
Needle by the earth-inductor, and y is the velocity as deduced
from the ordinary equation for the method of recoil, I find
pon) CA et
more exact to substitute
4 (fy f"s sin t di==4 (=)
a/J a
in the place of 72. The formula then becomes
2 \2\ 1-44
emis (6) (at) pt
re exact when A is small than when it
is large, but it is sufficiently exact in all a to give —
: how long it took him to
Source. Kohlrausch does not state g halk about
290 H. A. Rowland—Absolute Unit of Electrical Resistance.
7 yz, and as A=$ nearly, we have
-¥ —1.0008,
which would diminish the value of the resistance by ‘16 per
ce
n
As the time we have allowed for turning the earth-inductor
is probably greater than it actually was, the actual correction
will be less than this.
The correction for the extra current induced in the inductor
and galvanometer, as given by Maxwell’s equation,* has been
shown by Stoletow to be too small to affect the result appre-
ciably. :
We may sum up our criticism of this experiment in a few
words. The method is defective because, although absolute
resistance has the dimensions of “F“, yet in this method the
fourth power of space and the square of time enter, besides
other quantities which are difficult to determine. The instru-
ments are defective, because the eurth-inductor was of such
poor proportion and made of such large wire that its average
radius was difficult to determine, and was undoubtedly over-
estimated.
It seems probable that a paper scale, which expands and
contracts with the weather, was used. And lastly, the results
with this inductor and by this method have twice given greater
results than anybody else has ever found, and greater than the
known values of the mechanical equivalent of heat would
indicate.
The latest experiments on resistance have been made by
Lorenz of Copenhagen,+ by a new method of his own, or rather
by an application of an experiment of Faraday’s. It consists
im measuring the difference of potential between the center and
edge of a disc in rapid rotation in a field of known magnetic
intensity.
A lengthy criticism of this experiment is not needed, seeing
that it was made more to illustrate the method than to give a
new value to the Ohm. The quantity primarily determined
by the experiment was the absolute resistance of mercury, and
which it revolved.
* “ Electricity and Magnetism,” Art. 762.
t Pogg. Ann., Bd. cxlix, (1873), p. 251.
PORT al St he eg Oe
D. Kirkwood—Solar and Sidereal Heat. .- Bet
In conclusion I give the following table of results, a
the
as nearly as possible to the absolute value of Ohm
earth quad. ,
ame ;
Date. Observer. Value of Ohm. Remarks,
1849 |Kirchhoff__.-.--- 88 to ‘90 Approximately.
S051" Weber 2-22.52. = *95 to ‘97
18 1-088 From Thomson’s un
62 [Weber -....-... } 1075 From lange s fale ] Siemen’s unit.
1863 ; § 10000 Mean of a ts.
—4/B. A. Committee. ) 993 Corrected ris a zero velocity of coil.
1870 |Kohlrausch 10196
970 Taking ratio of quicksilver unit to Ohm
1873 |Lorenz 962.
980 Taking ratio of quicksilver unit to Ohm
1876 [Rowland ----..- ‘9912 Prom a preliminary comparison with the
: B. A. uni
[To be continued. }
Art. XLIII —On Croll’s Hypothesis of the Origin of ae and
Sidereal Heat ; by Professor DANIEL KirRKWwoo
THE Quarterly Journal of Science for July, 1877, contains
an able and interesting article by James Croll, LD., F.RS.,
on the age and origin of the sun’s heat. The theory of as
Croll may be regarded as a compromise between the mathema-
ticians, represented by Thomson, Tait and Newcomb, ine the
geologists of the uniformitarian school, represented by ‘Playfair,
Lyell, Darwin, etc. The principal points of this remarkable
paper a
1. That, as had been estimated by Sir William Thomson and
others, but twenty million years’ heat could be produced by
the —_ epee of the sun’s mass.
w determination has — made by H. F. Weber
great accuracy. The result
* Since
of Zuri ults a befe ae
at ih, i in “eho ths the the diferent an agree with comparison seems to a been
made simply with a nas4 of resistance coils and snot with standa modern
oe n’s Mepis seem to be reasonably exact, bu’ m the table published by the
tish Association » Oomiadeee in 1864, it seems cue vat that time cer-
en nearer Fess
tainty as to its value. He obtains 1 S. U. = ‘9550 —_-——, wileh 18 grea
or than the British Association determinati i. mae we take the dif-
ferent ratios of the Siemen's to the British path unit, ranging from “14
— whee to 1°92 per cent below. In any
Well with my own. The apparatus used does Sand ot seem to have been of the best
i con e mes
Pair of coils is used, seeing that in that case the constant, both of magn effect
tnd of induction, depend on the ej Sc it nat tt
cient detaile
292 D. Kirkwood—Solar and Sidereal Heat.
2. That not less than five hundred millions of years have
been required for the stratification of the earth’s crust at the
present rate of subaérial denudation ; and hence that the grav-
itation theory of the origin of the sun’s heat is incompatible
with geological facts.
we suppose two solid opaque bodies, each equal to half
the sun’s mass, to fall together in consequence simply of their
mutual attraction, the collision would instantly generate suffi-
cient heat to reduce the entire mass to a state of vapor. If, in
addition to the motion resulting from their mutual attraction,
we suppose the bodies to have had an original or independent
motion towards each other of 202 miles per second, the con-
cussion would produce 50,000,000 years’ heat; a motion of 678
miles per second, together with that due to their mutual at-
traction, would generate 200,000,000 years’ heat ; and a velocity
of 1,700 miles per second would generate an amount of beat
which would keep up the supply at the present rate for 800,-
000,000 years.
4. The sun and all visible stars may have derived their heat
from the collision of cold, opaque masses thus moving in space.
The nebulz are the products of the more recent impacts, and
the stars have been formed by the condensation of ancient
nebulee.
5. This theory, while accepting the doctrine of the conser-
vation of energy, indicates at the same time a possible supply
of heat for several hundred millions of years; thus satisfying
all moderate demands for geological time.
The mathematical correctness of the theory here stated will not
be called in question. We shall consider merely the probability
of the facts assumed as its basis. To the present writer the
hypothesis seems unsatisfactory for the following reasons:
_ L The existence of such sidereal bodies as the theory assumes
is purely conjectural, unless it be claimed that lost or missing
stars have become non-luminous, of which we have no conclu-
sive evidence.
and in no case exceeding 200 miles per secon
3. If the two iia whose collision the sun is supposed
to have been formed were very unequal, as would be most
Siete the amount of heat generated would be correspond-
ingly less.
4. Such collisions as the theory assumes are wholly hypo-
thetical. It is infinitely improbable that two cosmical bodies
should move in the same straight line; and of two moving in
different lines, it is improbable that either should impinge
ee ee i st -_ ei
D. Kirkwood—Solar and Sidereal Heat, 298
against the other. Comets pass rownd the sun without collision
containing one-half the matter of the solar system, were ap-
proaching one another in the same straight line, each at the
rate of 1,70 miles per second ;* that on meeting, their motion
was transformed into heat; and that their united mass was at
once reduced to vapor: the great question yet remains—How
much of the period represented by these 800,000,000 years’ heat
can be claimed as geological time? The nebula formed by the
collision would extend far beyond the present orbit of Nep-
tune. The amount of heat radiated in a given time from so
vast a surface would doubtless be much greater than that now
emitted in an equal period. No considerable contraction could
occur until a large proportion of the heat produced by the
’
inevitable that much the greater part of the 800,000,000 years
pon the whole, it seems more difficult to grant the demands
of Dr. Croll’s hypothesis than to believe that in former ages the
stratification of the earth’s crust proceeded more rapidly than
at presen ormer, as we have seen, has no sufficient
basis in the facts of observation. On the other hand, if our
planet has cooled down from a state of igneous fluidity, the
great heat of former times must doubtless have intensified b
aqueous and atmospheric agencies in producing modifications
of the earth’s exterior.
Bloomington, Indiana, March, 1878.
* This i ity mentioned by Dr. Croll. An
mation would of pase Ras lB more heat, but the hypothesis
+ Proc. Kan Phil 860, vol. xvi, pp. 329-333 and National Quarterly Review,
March, 1877, p. 292.
Am. Jour. wijees dace ya: Vou. XV, No. 88.—APRIL, 1878.
increased rate of
would be open to
294 J. W. Mallet—Selenide of Bismuth from Guanajuato.
Art. XLIV.—On the chemical composition of Guanajuatite, or Sel-
entde of Bismuth, from Guanajuato, Mexico; by J. W. MALLET,
University of Virginia.
THIS mineral seems to have been first noticed by Sefior Cas-
tillo in March, 1878, and was by him partially described* as
a sulpho-selenide of bismuth.
In the Guanajuato journal ‘La Republica” for July 18,
1873, Fernandez t published a full description, giving to the
mineral the name Guanajuatite, and stating that it is solely a
selenide of bismuth, a small amount of sulphur found being
attributed to admixture with a little pyrite. In the same year
or 1874 Rammelsbergt obtained as the result of a partial exam-
imation on a very small quantity,
EEE EES ae Se OE 16°7
ee Oak
82°1
and suggested the Phase of zinc. The mineral was more
fully examined by Frenzel,§ whose analysis yielded,
mencere ss 24°13
Rupee oe. Se es - 6°60
Wiemuth e250. ey ee 67°38
98°11
whence the formula has been deduced—2Bi,Se, . Bi,S,.
In the 2d Appendix to the 5th edition of Dana’s Mineral-
ogy | the name Frenzelite was proposed for the species, but
this has subsequently been retracted | in favor of the prior
claim of the name Guanajuatite given by Fernandez.
The above are up to this time, I believe, the only published
notices of the mineral in question. They leave two doubts in
regard to its composition, namely, whether sulphur is really a
constituent or only found from accidental admixture, an
whether zinc is present or not.
At the Bascessedl pres Exhibition of 1876, my friend Sefior
.
the Mexican Commission, was kind enough
* Naturaleza, ii, 174 (1873); Jahrb. Min. (1874), 225,
in this Journal, April, 1877, p.
Mine!
, p- 319.
p App. to 5th ed. Dana’s Mineralogy (March, 1875), p. 22.
Loe. cit.
Min. (1874), 679.
{ This Journal, loc. cit.
J. W. Mallet—Selenide of Bismuth from Guanajuato. 295
tempting to settle the above questions by careful repetition of
the chemical analysis. The already pulverized specimen was
chiefly used, but was supplemented by a portion of the other
—neither was altogether free from the hydrous silicate of
aluminum which constitutes the gangue.
The method employed was the following. Water having
been driven off by careful heating in a slow stream of carbon
dioxide gas, collected and weighed, the mineral was mixed
with ten times its weight of potassium cyanide and fused in an
atmosphere of hydrogen. The mass on cooling was trea
with water, and the solution filtered ; the residue on the filter
dried and again fused with the cyanide to ensure complete de-
composition, repeating the treatment with water and filtration.
From the mixed filtrates selenium was thrown down by addi-
tion of hydrochloric acid in excess, filtered after thirty-six
hours on a weighed filter, cautiously dried and weighed ; it
was then burned, and a minute amount of silica left behind
was determined. The solution from which the selenium had
used) an inum were now precipitated by ammonium sul-
phide, and separated by barium carbonate, the alumina being
deter The original residue of bismuth, left on the filter
fusion with potassium cyanide, and weighed as me
ay
Silentniss.o: cuue cede aoe
ulphur ......-.-------+-+--- “61
Biante is fo ss TCE OS 59°92
abe ee Ec nae 2°53
Webra OF kkk aii cee trace
4 ee ee een 3°47
Ne ee | OO
99°63
Zinc was specially looked for, both in the general analysis and
using a separate portion for this purpose alone, but none could
296 J. W. Mallet—Stlenide of Bismuth from Guanajuato.
be found. Possibly, as Rammelsberg had but a very small
quantity of material on which to work, he may have been led
to suspect the presence of zinc by a precipitate of aluminum
hydrate derived from gangue.
0 evidence, physical or chemical, could be found of the
presence of pyrite; the trace (unweighable) of iron appears to
belong to the gangue,
It is stated that this gangue is galapectite (Halloysite) ; if the
amount of such mineral present be calculated from the alumina
the above figures represent the specimen as composed of—
Guanajuatite 1.220 22. u... 92°17
Gaasan Halloysite___..__. 6°72
gee ae 56
Moisture---_. 18
99°63
and the Guanajuatite in the pure state would consist of
Rrebonetina. 20254. Soe oo 34°33
Sulphur -. "66
Re se i ck 65°01
100°00
Hence we have the atomic ratio,
Bi: Se: S= 310: 432; 21,
or, uniting the sulphur with selenium,
Bi:Se= 310: 453 = 2:000: 2-922,
It seems clear that the mineral in question must be viewed
as sesqui-selenide of bismuth, with isomorphous replacement
to a variable extent of selenium by sulphur.
It is also mentioned (this Journal, April, 1867) that Fernan-
dez has described a second selenide of bisesteh from the same
locality, and has derived from his analyses of more or less pure
Janssen Solar Photograph and Optical Studies, 297
Art. XLV.—On the Janssen Solar Photograph and Optical
Studies ; by S. P. LANGLEY.
Mr. JANSSEN, in papers lately presented to the French Insti-
tute* has given an account of recent results in solar-photo-
graphy, obtained by him at the observatory of Meudon, and
from the comments of Messrs. Huggins, Lockyer, De la Rue
and other competent judges, it has been understood that
remarkable advances have been made over any before pro-
duced. A copy has been published in the Annuaire du
or rice-grain-” like forms as had been commonly sup-
posed. The term “rice-grain,” it was carefully explained, was
Incorrect, and as an illustration imperfect.
* Comptes Rendus, Oct. 29th and Dec. 31st, 1877.
298 Janssen Solar Photograph and Optical Studies. :
of the foliate form and subdivision, specially calling attention
to them in the plate, where they are found in two squares sur-
rounded by a heavy outline. It is necessary to insist on the fact
that purely optical methods had informed us of the nature of
the constituents of the surface with a minuteness which photo-
graphy has not even now attained. It was also stated in the
first of these articles that the estimated mean distances between
the centers of these composite objects ranged from 2°57 to 1-42
according to the degree of disintegration introduced by magnify-
ing power, and the very important conclusion was reached that
the light of the sun comes to us chiefly from an extremely small
part of its surface—an indefinitely small part, but which is at
any rate less than one-fifth of the whole. M. Janssen’s impression
that the true form and relative area of these has first been shown
by the Aner is a misapprehension, though arising most
naturally in part from the vicious nomenclature of the subject.
: na closer view we see t rse vague macula-
tions or marblings* (formed as it seems to me by waves in the
solar a ing regions of greater thickness and
the plate is hardly possible, but as the individual “ grains”
* This is seen in the Albertype on removing it five or six yards from the eye
where details are lost. The ae ie igi
Brace tho ove itctt) vagueness of the aggregations is in the original
_t Indicated all over the Albertype lates, and shown in specific details in the
two designated squares. —"
Janssen Solar Photograph and Optical Studies. 299
may be here counted, I have placed on the positive a Rogers’
reticule, consisting of very small squares, engine-divided on
glass, which had been actually used on the sun for a similar
purpose; and with its aid counted the “grains” in different
should M. Janssen succeed in future in enlarging his photo-
graph while retaining his present wonderful definition, that
nition is as sharp and clear as we have escrl d it. ow,—a
question evidently to be asked,—is this bad definition something
in the solar atmosphere or our own? oes it mean a tremen-
away from the facule as seen on the edge? I believe there
has been, from telescopic study, a somewhat uncertain recog-
nition that the photospheric structure differed at different times,
if once recognized, would be visible to the telescope, if sought,
granulations varied at different times from solar causes; but with
the telescope we lack the facility for deliberate comparison of
one part of the disc with another, we obtain here, since owing
to the undulations which we do know without doubt, are in our
own atmosphere, our best vision is but momentary, an —
we can turn from one part of the sun to compare It with another
the opportunity is gone. The “omg Eaoereraieg as it is, in
800 Janssen Solar Photograph and Optical Studies.
the thousandth exposure may fall in the brief instant of defi-
nition the observer patiently watches for, and then the results
nomenon, or (what might conceivably be the case) some unde-
tected causes of minute instrumental error. The difficulty of
presence of residual phenomena, which, however minute, were
i ty of distinguishing by @
single plate, the exact limits between the effects of solar and
tremities of filaments; extremities whi aggregated,
fs sg and which lifted higher than their fellows cause the
* Comptes Rendus, Sept. 6, 1875, p. 438.
Janssen Solar Photograph and Optical Studies. 301
tosphere to a field of grain in which from a bird's-eye view, we
see, in a calm, only the rounded summits of the wheat. ta
wind blow fitfully over the surface, bending the crests here and
there and showing more of the form of the straws. This is, it
seems to me, the suggested explanation of the elongated form of
the “grains” shown in such an interesting manner in M. Jans-
nomena, and it would be doubtless desirable, if possible, that
before us, demand not only the finest mechanical and chem-
ical methods and still more the highest skill, but atmospheric
conditions so brief as to rarely or never last during even the
short time mentioned.
Finally, then, though without two pen ia Of equal-ehr
es er, it is perhaps
Allegheny, Penn., March 14, 1878.
302 E. W. Claypole—Tree-like fossil plant, Glyptodendron.
Art. XLVI.—On the occurrence of a Tree-like fossil plant, Glyp-
todendron, in the Upper Silurian (Clinton) Rocks of Ohio; b
Professor E. W. Cuaypour, B.A., B.Se. (London), of Anti-
och College, Yellow Springs, Ohio.
In the month of July, 1877, while on a geological excursion
in company with one of my students, Mr. Leven Siler, in the
vicinity of Eaton, in Preble County, Ohio, the latter picked up
and banded me a slab bearing the impression'of a vegetable
stem, which proved, on closer examination, to be that of a
plant allied to Lepidodendron. As the beds in which we were
working at the time lie at the very base of the “Clinton” of
the Ohio Survey, and within a few feet of the break which
marks the summit of the Cincinnati group of the Lower Silu-
rian, the specimen immediately assumed unusual interest and
importance ; no indisputable traces of land-plants having then
come to light from so low an horizon in America, and no re-
mains of arborescent vegetation being known with certainty from
strata of so old a date in the New or Old World.
The slab containing the impression was not taken out of the
solid rock, but lay loose on the bank of Clinton limestone.
This fact will naturally raise some question concerning its age
in the mind of every geologist. Fortunately, however, we are
not in this instance dependent upon such evidence. To any
one practically familiar with the Clinton rocks as they crop out
the Cincinnati uplift no doubt can arise. The stone 1s
a piece of yellow, rough, encrinital limestone, considerably
weathered, with the characteristic appearance of the Clinton at
Eaton and here. Moreover, by the side of the impression there
me imens. But further
re Boe the fossil and its nearest allies among the Sigillarids
and Lepidodendrids has induced me to place it by itself in a
new genus, which seems to form a connecting link between some
other paleozoic genera. I append the following description :—
E. W. Claypole—Tree-like fossil plant, Glyptodendron. 308
GLYPTODENDRON. ‘Tree-like; stem cylindrical; surface
marked with two parallel sets of ridges running spirally up the
stem in opposite directions, crossing each other and thus forming
thomboidal areoles. Lower portion of areole depressed and prob-
ably representing or containing a leaf-scar. Depressed porece
of areole (leaf-scar?) symmetrical (i. e. alike on the right and
left sides.) Vascular scars, leaves, fruit, etc., unknown. The
name is from the Greek yAdga, I engrave, and alludes to the
depressed areoles.
Glyptodendron Eatonense. Stem thick and trunk-like; the
specimen from which this description was made measured when
complete about six inches in diameter. Surface divided into
rhomboidal areoles by two sets of narrow ridges parallel and
- peadaier vag running spirally up the stem in opposite directions.
ese ridges cross bas other nearly at right angles. The are-
oles thus formed measure about seven-sixteenths of an inch
along each diagonal. Lower portion of areole deeply and
evenly depressed and probably Hi ul a sunken leaf-scar.
Upper border of depressed portion rounded in outline and ele-
vated, equalling in height the spiral ridges. No trace of the
vascular scars can be seen in consequence of the roughness of
He says, “ The marks on your specimen, at
rags sight, resemble those of the Lepidodendra of the type of the
have belonged to a plant of the nature of a Tree-fern, or of a
Sigillaria allied to ‘s Menardi, rather than to a true Lepidoden-
304 Scientific Intelligence.
dron.” ‘In speaking of the areoles, I take it for granted that
the curvature of the cast represents that of the stem.” “The
specimen may, however, have been a bit of bark pressed out
of shape.”
My own opinion, after a careful examination of the original,
is that the curvature of the cast does represent that of the stem,
and consequently that Dr. Dawson’s remarks on its resemblances
are wellfounded. The bark of Lepidodendra, etc., when pressed
as usually occurs in the Coal-measures, is constantly flattened.
In a subsequent communication, Dr. Dawson alludes to the
possibility suggested above, that the fossil may exhibit a com-
posite character partaking of the character of more than one
existing genus. The wide diffusion of the type which it most
resembles in the Lower Carboniferous is good reason for be-
lieving that it is very ancient, and therefore its occurrence so low
as the Clinton limestone is the less surprising.
In conclusion, I gladly express my indebtedness to Dr. J. W
Dawson, of Montreal, for valuable aid cheerfully rendered, and
Mr. Leo Lesquereux, of Columbus, in this State, for prompt
and kind replies to letters of enquiry.
SCIENTIFIC INTELLIGENCE.
I. CHEMISTRY AND PHYsICcs. 2
1. On certain Fundamental Thermo-chemical Data.—BERvHE-
Lot has re-determined with great care the heat data belonging to
certain chemical reactions, using an improved calorimeter for the
purpose, described in the memoir. The heat of formation of
sulphurous oxide, although determined many times, was not UP
to this time accurately known. Thus sixteen grams of sulphur
burned to gaseous sulphurous oxide gave Dulong 41°6 calories,
Hess 41-1, Andrews 36°9, and Favre and Silbermann 35°6, the
.
glass, and the sulphur used the octahedral variety. The mean
result was, for sixteen oe of sulphur, 34°55 calories. From
lates the heat of formation of sulphuri¢
diamond, in burning to C,O, evolves 94, C, in burning to C,0,
evolves 94 —68 2=25°8, or for amorphous carbon 28°8. Ethy lene
twenty-eight grams, yields 334-5 calories, acetylene twenty-5!*
Chemistry and Physics. 805
grams, 317°5, and benzene seventy-eight grams, 776 calories. In
the formation of the hydrogen compoun nds of bromine and iodine
H+Br gas=HBr gas yields 13:1 calories, while H+Br liquid
=HBr gas gives 9°5, H+I gas =H gas gives Aggy 9 calories, and
H-+I solid =HI gas ives —6°3. The heat of formation of
bromic acid is —21-2, and * hypobromous PI ga gh tig
Chim. Phys., V, xiii, ‘ Jan.
2. Relations between the pipe Weights of the Ble neat
WarcuTER has described certain additional relations between the
(i. e., one positive and the other Pein) are a equal to one
fusing and the boiling points of the elements, so far as known,
increase With increasing atomic weights and increas ig V3 ge
fr
atomic weights, the greater, the higher the valence. 6th.
crass of the negative metallo ids—fluorine to silicon—for the
e roper, diminishes be * Rae atomic weight and an
increasing valence.—Ber. B Fes., Xi, 11, Jan. Ne
B.
8. New Method for the Preparation of Nitrogen. s eesaes SE
has observed that when ammonium nitrate and manganese perpide
are heated together up to the fusing point ais the former (about
180°) a violent reaction age the mass mes red hot and
nitrogen is evolv the temperature be oe t between 180°
ee 200°, yea nitrogen is entirely pure, being formed according to
€ equatio
On H NO,),+Mn0, =Mn(NO,),+(H,9).+N.
One experiment, three grams NO, heated with an equal
weight of MnO, in a acti & bath kept at 205°, yielded 630
cubic centimeters of gas, nearly a theoretical quantity. If the
nous nit
temperature rises above 216° 8 decomp —
giving sachin vapors and ox sg At td the gas contai
sp og per t of oxygen.— Bull. Soe. Ae, Eh xxi, a —
187 P.
i “On a Method 0 separating Crystallized Silica, patois
Quart, from Siltoaten- —Lavurer has suggested an improvement
os
306 Scientific Intelligence.
5. On the use of Stannous Chloride in the analysis of Nitro-
compounds,—Limpricut, noticing the facility with which an acid
solution of stannous chloride reduced nitro-compounds, made a
series of experiments to ascertain whether the reaction could not
made use of to
stannous chloride solution of known strength, the nett (tt)
0 oO :
SnCi,+(H,0), B titrition the quantity of stannous chloride
an
Stototte salt in a liter of water; (3) starch solution diluted and
="0059 gr. Sn, =0-0007666 gr. NO,; (5) Permanganate solution,
made and titered as usual. In the analysis, 0°2 h
m
10 c.c. of the tin solution, and warmed. After cooling the flask
is filled to the mark with water, 10 ¢.c. is removed with a pipette,
aced in a er, dil mixed with the soda solution until
the precipitate at first produced is re-dissolved, and after adding
some starch solution, titered with the iodine solution until the
blue becomes permanent, ‘numerous results given show the
panne to be accurate.—Ber. Berl. Chem. Ges., xi, 35, Jan
1 G. ¥
B.
6. On a so-called Catalytic action of Carbon Disulphide.
Chemistry and Physics. 307
water bath in sealed tubes for forty hours, have not the slightest
n on each other, — addition of a small quantity of carbon
disulphide to the mixture so facilitates the reaction that even in
six hours it is ees and in one case the tube exploded from
the evolved hydrogen bromide, in two hours, Further investiga-
tion showed that the presence of the disulphide was not abso-
lutely necessary, ‘oie for the formation of the addition or the
renee products of bromine and acetic acid, but that it facil-
ted the formation of both to an extraordinary degree, the time
required for the action to be completed being in the exact inverse
ratio of the amount of CS, present. The precise mode of action
of the disulphide, the authors are now engaged in 1 iexastgatnie:
—Ber. Berl. Chem. Ges., xi, 241, Feb. 1878. G. F. B.
7. On. the Conversion of Nitriles into Amides.—Prsner and
Kietn showed a short time ago that any nitrile may be made to
combine directly with = alcohol, by passing gaseous HCl or
HBr into a mixture of the two. There is first formed the salt of
an fotiockinnne
_RCN+R’0H-+(HCl),=RC OW HC)
which immediately loses HCl and becomes a salt of an imide.
Thus benzonitrile and isobutyl alcohol when thus treated give the
hydrochlorate of benzimidobutyl ether, C.H,C | OCH, wee By
the action of alcoholic ammonia, the free benzimidobuty] ether
C.H C} 06, H, and benzimido-amide (or benzenylamimide)
C.H,C HCl are obtained. The authors now describe ben-
siidborade and its silver compound, and the action of ethyl
iodide and of acetic oxide u upon it, and also benzimidobutyl ether.
so a polymer of Lggrorrtice termed kyaphenin. meee
= Ges. Nes 4, Jan. 1
Wislicenus’s laboratory, which go to prove this sugar a
pentacid alcohol the prolonged action of acetic oxide upon
quercite in sealed tubes at 100° to 120°, a pent tate w
obtained as amorphous brittle mass, having ae farina
OCH H,O),. Saponification with barium hydrate confir
sition. The tetra and the ean cd are Liao a
‘Uuming h eae acid was without action.—Liebig’s Ann.,
exe, 282, gyro bi . F. B.
9. On the cids of Cocoa Butter.—Kixezert has exa
ae chemical racicoa A of the Cocoa butter of —o hav-
a fusing point of about 30° C. . was as y sodium
a the sodium salt converted into a barium salt, this decom-
308 Scientific Intelligence.
sed by HCl in presence of ether one the fatty acids obtained
by distilling off the ether, were repeatedly crystallized from alco-
y re serene the fractional crystallization, there was
Shenae beside olei acid, an acid of the formula C,,H,,O, and
fusing point 57°5° as one extreme, and —— C,,H,,,0,, of fusing
128" 29
point. 72°2° as the other, both of which are new. To the latter
J. Ch.
the pegs anne the name Theobromic acid.— Soc., xxxiii,
38, Jan. G. F. B
10. On. a new Class of Acid tain iar ee has studied a
new class of ee salts, the acid acetates which acetic acid’
itself plays the part of water of cotinine, Their general
formula of the sodium salts is C,H,Na0,(C,H,0 )—H, oO, where
n
= = or 3.- Thus, a salt crystallizing in small flat efflorescent
prisms has the formula C,H sNaO,(C,H ,0,)4(H,O)$. Another of
the second class, where ~ Mas, is in small efflorescent prisms
of the formula C,H,NaO,(C,H,O,)3(H ,O)42.— Bull. Soc. ~*~ be
xxix, 153, Feb. 1 1878.
ll. Electro- Magnetic and pheno imetric Absolute Mumwoneda
ae the continuation of a paper with the above title, Professor
F, WEBER Psat ia that the seg of the Siemen’s mercury
unit of resistance lies between 0°9536 x 10° ("a) ‘oad
0°9550 * 10” ( Teen) and that the value of the British unit is
the value asserted, 101° et . Professor Weber also dis-
ome the experiments of Favre on the quantities of heat devel-
by various electromotive forces in their circuits during the
i f zinc. F
of a mercury calo rimeter, an instrument which Weber sz aeattg”
os ee. Mauien 1878 ape a
12 agri Ee lobstessare ER Wricut and Mr. =
Mary’s Hos ital Tondon, pet made a first report
to the Like Chemical y* of their _investigation on this
chief point established by their paper is the general
principle that “ ‘that reduc agent begins to act cat the lowest
of ¢ experiments are given on — reduction of ¢ cupric ‘oxide and
Chemistry and Physics. 309
ferric oxide by carbonic oxide, by hydrogen and by carbon re-
c
tion of carbon, hydrogen, and carbonic oxide with sixteen grams
of oxygen are taken as 47°78, 57°82 and 68°35 respectively. The
effect of the different physical states both of the metallic oxides
and of the charcoal used is likewise carefully discussed.
nh connection with the above paper, Mr. M. M. Pattison Muir,
of Caius College, Cambridge discusses the “influence exerted b
time and mass in certain reactions in which insoluble salts are
produced.” The author following a previous suggestion of Glad-
pipet 4
ally becomes more and more slow.” 2, “that the equation
CaCl, +M,CO,=2MCIi+CaCoO,
does not furnish a full expression of the action of sodium or po-
tassium carbonate upon calcium chloride. en the two salts
are mixed in the proportion expressed by their respective formule,
4,
w f 9
that elevation of temperature tends to increase and on the other
d increase the excursions of the
our. Scl.—Turrp Series, Vou. XV, No. 88.—APRIL, 1
21
310 Scientific Intelligence.
residual molecules of sodium or potassium carbonate and of calcium
chloride, would also increase the chances in favor of collision oc-
¢
the excursions of these residual molecules, or tending to increase
the number of molecules which take no part in the production of
calcium carbonate, and hence to decrease the chances of the sodium
or potassium carbonate and the calcium chloride molecules coming
into collision, wenld also tend to diminish = amount of calcium
t m
solutions would tend to decrease the chances of snme hea
the two sets of molecul
13. eS a —In the Journal of the Ciethinal: Society jet
err
Mintz (Compt. rend., lxxxiv, 301). These experimenters ha
sought to establish two points firs t, that rapes vapors prevent
nitrification; secondly, that ibisificasion may be induced by seed-
ing in many cases sufficient t oad oy all the germ nie chitiek in
an organic hey while tina solution kept in darkness developed
bacteria fr earing of this observation on the fact that
The pase ‘retards or even prevents nitrification is obvious.
e oor of light on nitrification was not apparently quite
known ; it is twice hinted at in Gmelin’s Chemistry es ‘endish
Translation, > 68, vii, =} but it is not mentioned to oT
ubjec
t. Reczunination re some of Haloid laioniec of An *
Cooks, Jr. (Proceedings of the Amert-
eda oF. of Aria and Blcies vol. xiii. Boston, 1877).—
paper co:
Ieal and ci yveadinurrahiegs relbtiuaih of the iodide of antimony in
particular, but also of the chloride, bromide, and the oxichlorides,
oxibromides, and oxi-iodides. The chloride and the bromide of |
Chemistry and Physics. 311
antimony were both obtained by several different methods, in dis-
tinct crystals. These were extremely deliquescent, but, notwith-
)
tained in three crystalline conditions—hexagonal, orthorhombic
and monoclinic. The hexagonal crystals have a deep ruby-re
color; their specific gravity is 4-848, and the melting point is 167°.
The orthorhombic crystals have a greenish-yellow color; they are
formed when the iodide is volatilized at a low temperature—be-
low 114°, and when subjected to a higher temperature they
on
ling the orthorhombic crystals of foliated minerals frequently imi-
tions parallel to each they would form crystals having a rhombic
d g :
312 Screntific Intelligence.
the following manner :—A solution _ the iodide in carbon disul-
phide, after jt has been exposed for some hours to the action of
the sunlight, undergoes partial ss a ag some iodine being set
free, this ‘solution i is then distilled over a water bath, and the pro-
ate of 4°768. That ee are true isomers of the other forms
it the monoclinic iodide in pure carbon disulphide the hex-
onal iodide is obtained, as —— a small quantity of minute rhom-
bic plates, whose.ang] e 60° and 120° om these facts it
he suggestion is made that possibly the supposed orthorhom-
bic — may prove upon more exact determination on better
material, to be really monoclinic, so that the difference between
the two Yellow varieties that have been = would exist ee |
in habit. This would not, however, affect the general result
reached as to the sorte of their form to the Pea ae kind and
the reason for its existen
The “ molecular snieling® which has been ‘explained is quite dis-
tinct from the “interlaminar macling,” described by the orale in
his paper upon the Vermiculites, and alluded to above. The la
involves no essential change in "substance ; the former teeter se a
15. The Telephone, an Instrument of Mbcthetont —The “applica-
tions to which the te beat aye may in future be put cannot yet
all foreseen ay had its value shown to me ina
remarkable ae hi 1 tir a Rieribo-cloctrie: intermittent current
by drawing a — end of copper wire alon ng a rasp completing the
cirenit. A tel ephone was ae into the circuit, in another room,
and every time that the wire was drawn along the rasp a hoarse
eae Sine: was heard in the telephone. 2. I used a thermopile
n burner shining on it from a distance of six feet.
The curr ent was rendered intermittent by the file, and the sound
was most distinctly heard. A Thomson’s reflecting galvanometer
was introduced into the circuit which showed that the currents.
Geology and Mineralogy. 813
still the effects were faintly audible. Here the galvanometer,
which was still in circuit, hardly gave any indication.
In these experiments only one telephone is used, viz: at the
i ith a powerful current
and short dashes of the Morse alphabet.
_ I ought to mention that I believe the
as Prof. Tait.
Grorce Forses, Andersonian College, Glasgow, February 13.
—From Nature of Feb. 28.
Il GroLtogy AND MINERALOGY.
l. Origin of the Driftless Region of the Northwest; by
np D. Irvinc.—In a notice of vol. ii of the Geology of
the explanation
I have offered for the existence of the riftless region of Wiscon-
Report for 1876. I am informed, also, that
ritten for a Chicago journal
Page which’ I have not myself seen —has said that my explana-
on i i in-
worth, they are wholly my own. Possibly they are wo
more because analogous to those reached independently by some
314 Scientific Intelligence.
one else. The matter has long excited my attention, the entire
inadequacy of the older views having forced itself upon me when
first engaged in field-work in Wisconsin.
However, though cheerfully acknowledging the priority of
IPs vi
the Green Bay Valley and Lake Superior. The crystalline rock
region is no such lofty one as he appears to suppose, is mnie
; but, because of ;
size and force, and of their westerly direction, they left the region
farther south untouched. ‘
_ Professor Winchell’s view was reached by noticing the relation
in position of the driftless region and the area of crystalline
Wisconsin. At the time that I wrote, the proofs of a’similar state
of affairs for the Lake Superior country were nearly as good, and
be seen when the reports on that country
come to be published.
University of Wisconsin, February 18, 1878.
2. Second Geological Survey of Pennsylvania. :
(1) Report of Progress in the Fayette and Westmoreland district
of the Bituminous Coal Fields of We nsylvania ; by
: Western Pen
J.J. Srevensoy. Part 1, Eastern Allegheny County and Fayette
Geology and Mineralogy. 315
and Westmoreland oo west from Chestnut Ridge. 438 pp.
8vo, with maps and se —Professor Stevenson’s Report gives
first an account of he "phytical features and general geology of
the district, and then describes with detail the stratification of the
bed. The coals and iron ores are described, and many analyses
are ie = spe latter.
(2.) Report of Pr ogress in the Cambria and Somerset District
sale the Fituntaoud Coal Fields of Western Pennsylvania ; by .
ews :G, Pra Part II, Somerset.
vate , Pa.—The region he scribed lies to the southeast of
1858 to occur i the bottom “of the Barren oe and at the top
of the Lower Productive Coal series, has no > and opt it
should fer fpr from that report wherever it occurs, an
from Lesley’s “ Manual of Coal.” The Report is ‘lustrated by
numerous wood-cuts, and six maps and sections.
(3.) wy Well trot dens and Levels ; by Joun F. a 348
Pp. 8vo. Harrisburg, Pa.—This Report is a very Vv. e sys-
temnatiied statement of facts connected with the oil Broan of
Western Pennsylvania. It contains the geological and geograph-
ical positions and depths of all the oil openings, and sections of
the rocks in each case as far as oe By were obtainable. _ The work
316 Scientific Intelligence.
they contain, it takes up in succession the life of the periods in
geological history, commencing with the oldest. Its many illus-
trations are not as well engraved as they should be. The author
is a zoologist as well as geologist, and the student will find his
work a very valuable help toward obtaining a comprehensive
knowledge - the progress of life on the globe
Reports of the United States Exploration ‘of the 40th parallel,
Fog ai Kine, Geologist in charge. Submitted to the Chief of
Engineers and published by order of the Secretary of War, under
authority of Congress. ‘Two volumes of these Reports, on the re-
gion in the vicinity of the 40th parallel cae the Sierra Nevada
and the Front Range of the Rocky Mountains, have recently been
issued. They add greatly to our knowledge of Rocky Mountain
geology, and are hastening on the time when we shall ae com-
sata map of the great territories. These two volumes are num-
red volumes ii and iv. Volume iii, by Mr, King, is one in the
press, and will soon be ready for delivery.
Volume ii, contains the “ Descriptive Geology” by ARNOLD
Haguz and §. F, Em MONS; it is an octavo volume of 890 pages
and is lasted ay twenty-six plates. A Soars of it-is deferred
to another number of this
olume iv, ck sore rs 670 pages, consists of three reports
or parts: I, "Paleontology, by Fick mae K, illustrated by seven-
teen plates; II, Paleontology, by Jam : Has and R. P. Wurt-
FIELD, illustrated by seven plates, and ll, Ornithology by RopeRrt
Ripeway. The Report of the late Mr. Meek contains fossils
the Tavis District, Nevada; and the west side of Degouly
Mountain, White Pine District, Nevada. They include Brachio-
pods, of aes gonere spisopines Lingulepis, Kutorgina and a
=
3
7
$5
113
is
a
z
3
=
+
w
belong to the upper portion of the Lower Silurian, the Devonian,
Carboniferous, Triassic and Jurassic formations.
regions ‘and their faunas i is presented, and lists of the species of
each, which we propose to notice in a future number
5. Report on the Clay Deposits of Woodbridg e, South Am-
boy, and other places in New Jersey, together swith their uses for
brick, po ne etc., by Grorar H. Cook, State Geologist of
New Jersey. 2 pp. 8 8vo. phen N. J., 1878.—This valua-
ble volume, on a Jersey deposits, is published by 5
as a part of the results of yo Geological Survey. It give
ed
Geology and Mineralogy. 8317
se
southwest to Trenton, on the Delaware. The second is a large
colored map, giving special details with regard to the northeast-
e ing
contains a colored chart, showing the condition of Europe in the
fi d se cial
range. The chart is interesting as exhibiting the supposed condi-
tion of Europe, according to one believing in the iceberg theory of
the drift.
7. Cordaites with flowers from the Coal region of Pennsylvania,
i f
arlin
and leaves attached to the stems of Cordaites. “Sternberg in
R » . . .
to publish last fall his splendid monograph of the Cordattes in his
i a, Mr. Mansfield has now obtained a splendid
some y illustrating the relation of this
remarkable group.”—Amer. Phil. Soe., Feb. 1, 1878.
above the sea, and 4000 feet above the town of Huallanea.
region was reached after an arduous journey across the Andes
318 Scientific Intelligence.
from the port of Casma; in the course of it, it was necessary to
cross several parallel ranges, one of them 16,800 feet in altitude,
9. On the new Mineral Homilite—In December, 1876, M.
Paijkull published an account of a new mineral, associated with
1
are totally isotropic. M. Damour has analyzed the m eral an
his analysis (2) is here quoted together with that of M. Paijkull (1).
SiO. BO; Al,0O,; Fe.0; FeO MnO Ce.0,* MgO CaO Na.O K,0 H,O
(1) 31-87 pate 150: 2°15 © 16°26) -- 0°62 27-28 1-09 0°41 0°85 =100°
(2) 33°00 [15-21 18°18 0-74 2°56 27°00 1°01 -. 2°30 =100°
* With La,0s;, Di.O0;.
The h : t
From the fact that the analyses do not afford any simply atomic
~ fr e . »
1. Flora of Tropical Africa ; by Danret Outver. Vol. Il.
Tinhelbifors es pr sand edie s a
work Professor Oliver has secured an efficient collaborator in Mr.
Hiern, who has not only taken the Ebenacee, of which he has
formerly published a classical monograph, but also the Umbel-
DERE eS a Te ee ae
rts ail
Botany and Zoology. 319
lifere, Rubiacee and Dipsacee, and has borne a part in the elabo-
ration of the Composite,
more genera than would be expected, namely 117, and 17 are
Gertn., replaces Webera of Schreber, being three years older ;
also Chomelia Linn., is said to be the correct name, but Chomeliu
of Jacquin is kept up. Canthivm Lam., is restored in good time
for that important genus, much to the relief of the nomenclature,
and the original Plectronia of Linneus is said to be Olinia!
The Liberian coffee, the seed of Coffea Liberica, “is said to be
>
Psychotria, with 61 species, is made to include Chasalia, and to
one, and another plant named Richardia, in honor of L. C.
Richard, and the present state of things having been acquiesced
im for more than half a century, this certainly is a case to whic
z d
posits of the Sierra Nevada; by Leo Lesquerevx. i
10 plates, 4to. 1878. (Vol. vi, No. 2 of the Memoirs of the
Museum of Comparative Zoology at Harvard College.)—A me-
Specimens figured are impressions of is ¢ a fine-
ained whitish clay or soapstone,” mainly from a collection
made r, Voy, of Oakland, California, which was sec red and
resented to the California University by the liberality of Mr. D.
O. Mills, remains are of special interest from the
320 Scientific Intelligence.
may pt i : ge ch
University will receive and forward any American collections des-
tined for it. S
number of years ago, he had been led to an observation on the
none. He @
first soppoese the ants had all been destroyed, but in the attic he
observed a few feasting on some dead house flies, which led him
ai a :
sweet cake. He accordingly distributed through the house pieces
of bacon, which were afterw:
rds found swarming with a astra
a ith the same result for several days, when, in like
manner with the cake, the ants finally ceased to visit the bacon.
leces of cheese Were next tried, with the same results; but yin
an undoubted thinning in the multitude of ants. When the
ee SNE Se ee EN PET Gt
Miscellaneous Intelligence. 821
cheese proved no longer cpt recollecting the feast on dead
flies in the attic, dead grasshoppers were su pplie ed from the gar-
much for
ced ag appear to have been thoroughly oe nor has
the e since been —_— with them.— Proc. Acad. Nat. Sci
Philodelphia 1877, p. 3
8. ‘arboniferous pooiee’s tes of Illinois.—At the Baten, 4
the Boston Society of ren History for December 5, 1877,
S. H. Scudder showe rawings of interesting Argoeietes
from the pad sae ‘eke of Illinois. The first represented a
Species of white ani, showing a wing without reticulation; the
second, the terminal scinneiis of a eriiacent belonging to a genus
allied to Dithyrocaris, but which he had at first taken for some
extraordinary form of insect.
A Manual of the Anatomy of Invertebrated Animals, by
Tuomas H. Huxtey , F.R.S. 596 pp. 8vo. (New York: Apple-
ton & Co.)—The best and latest students’ manual of the inverte-
brates in the English language.
0. Nomenclature in Zoology and AR by W. H. Dat, U.
5. Coast Survey.—Mr. Dall, as chairman of the committee of the
American Association on Zoological Nomendlaturs has been doing
€ >
principles of cislogioa! and botanical nomenclature into one sym-
metrical system. Mr. Dall’s statement of this og is a great
twenty-four days, but gra adually regained its usual powers an
- habits of flight, and its ability to feed itself and drink. Only one
such case is on record. He argued for the propriety an
hess of such operations from the acknowledged gee ey waieteabie
ties of the science—Proc. Amer. Phil. Soc., Feb. 1, 18
V. MisceELLANEOUS SCIENTIFIC INTELLIGENCE.
Hist
Dawson, LL.D., F.R.S. the Canadian epheat te yol. ¥
first. series will be found firs on the earthquake of October 17,
322 Miscellaneous Intelligence.
1860, with a summary of facts relating to the previous shocks
recorded in Canada, a
local peculiarities and probable causes. subject was con-
tinued in vol. i, of the new series, in connection with the earth-
a
wide-spread disturbances of the earth’s crust in the present
autumn,
On January 4, 1871, a shock was experienced at Hawkesbury,
Ontario, but was not reported from any other place. A more
ve been noticed from time to time, but did not attract much
attention, and I have preserved no details in relation to them.
at of the present month was probably the most considerable
since 1871. It occurred at Montreal, at ten minutes before two on
the morning of Sunday, November 4. At Montreal there was
only one distinct shock, preceded by the usual rumbling noise,
and sufficiently severe to be distinctly felt, and to shake window-
>
southern side, about 300 miles on the eastern side, and 175 on the
western.” So far as can be learned from the reports, the shock
seems to have been most severely felt on the north side of the valley
of the St. Lawrence and abo i i
nd some general remarks on their periods, -
b The j
Miscelianeous Intelligence. 323
If we add to the table of earthquakes in Eastern America,
given in vol. v of the Naturalist, the more recent earthquakes
observed in Canada, the proportion for the several months will
stand as follows :—
Ma u
8; November, 15; December, 8. Total, 78.
Thus of seventy-eight recorded Canadian and New England
earthquakes, fifteen, or nearly one-fifth, occurred in November;
forty, or more than half of the total number, in the third of the
rel extending from October to January inclusive. The pub-
ished catalogues show that similar ratios have been observed
elsewhere, at least in the Northern hemisphere.
nh some earthquakes a low state of the barometer has been
observed, as if a diminution of atmospheric pressure was con-
rust causing vibration. In the present case no very decided
suc
high for the season, and this rapid fluctuation was accompanied
with much atmospheric disturbance in the region of the lakes and
the St. Lawrence Valley. e weather map issued by the War
Dep
shows a low barometer in the Gulf of St. Lawrence and a high
barometer in the Middle States—the area of the earthquake being
about half way between the extremes.
n sre nit f with previous earthquakes it has been observed
that the greatest intensity of the shocks appeared near the june-
tion of the Laurentian with the Silurian formations. This would
Wave propagated through the S : ,
sipabinik ee aetiakltn and eastern sides of the Laurentian region,
324 Miscellaneous Intelligence.
or a shock Sa ase under the Laurentian of these regions had
extended itself from them into the Silurian rocks to the south and
east. If the ptovaiting'i impression stated in the eet that the
vib a passed from W. to E. or N.W. to S.E,, is — the
latter would be the more probable supposition. Tt i is, however,
very difficult to attain to any certainty as to the actual direction
of the disturbance, and some observers give it as precisely the
opposite of that above stat
On the 14th of Moeahens a slight shock was felt at Cornwall,
Ontario, and on the 15th of November earthquake shocks oc curred
over a wide area in Kansas, Iowa, Dakota and Nebraska.
OBITUARY,
CHARLES ce ee Harrr.—Professor Hartt, according to a
telegram from Rio Pak died of yellow fever soon after the
ee
i o Sxccui, the Astronomer and Director of the Observa-
tory at the Collegio gf at_ Rome, Italy, died on the 26th of
February last. Father Secchi, in the years 1848 and 1849, was
connected with the Observatory of Georgetown none. near
Washington. In 1850 he returned to Eur ope and entered on hi
labors at Rome. His papers on astronomical and physical subjects
are very numerous and of great value.
ig eases
ieee aires Stine a RR
AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES.]
*
Art. XLVII.—Research on the Absolute Unit of Electrical Resist-
ance; by Henry A. RowLAND, Professor of Physics in the
Johns Hopkins University, Baltimore, Md.
[Continued from page 291.]
Theory of the Method.
WHEN a current is induced in a circuit by magnetic action
of any kind, Faraday has shown that the induced current is
proportional to the number of lines of force cut by the circuit
and inversely as the resistance of the circuit. If we have two
Circuits near each other, the first of which carries a current,
and the second is then removed to an infinite distance, there will
be a current in it proportional to the number of lines of force
cut. Let now a unit current be sent through the second cir-
cuit and one of strength E through the first; then, on removing
the second circuit, work will be performed which we easily see
is also proportional to the number of lines of force cut. Hence,
if EM is the work done, Q is the induced current, and R is the
resistance of the second circuit,
g=cr™
where C is a constant whose value is unity on the absolute
System.
When the current in the first circuit is broken, the lines of
force contract on themselves, and the induced current is the
same as if the second circuit had been removed to an infinite
distance. If the current is reversed the induced current is
twice as great; hence in this case
E M E
=—2E— or R=2M—.
pees Q
Am. Jour. Sc1.—Turp Serres, VoL. XV, No. 89.—Mar, 1878,
22
326 H. A. Rowland—Absolute Unit of Electrical Resistance.
Hence, to measure the absolute resistance of a circuit on this
method, we must calculate M and measure the ratio of Q to E.
M is known as the mutual potential of the two circuits with
unit currents, and mathematical methods are known for its
calculation.
The simplest and best form in which the wire can be wound
for the calculation of M is in parallel circular coils of equal
size and of as small sectional area as possible. For measuring
E a tangent galvanometer is needed, and we shall then have
B= tan 6,
where H is the horizontal intensity of the earth’s magnetism at
the place of the tangent galvanometer, and G@ the constant of
the galvanometer.
or measuring Q we must use the ballistic method, and we
ve
A cid
Biot Ei ge tT! Ig. avaer
hse aad EES 2 sin $0
Qa = che ‘2 sin $0,
which for very small values of A becomes
be ee
Ne eg GO antand 1
Te G Tsin$@1+4A—4A2’
where H’ is the horizontal component of the earth’s magnetism
at the place of the small galvanometer, G’ its constant, T
the time of vibration of the needle, and A the logarithmic
decrement. '
The ratio of H’ to H can be determined by allowing a needle
to vibrate in the two positions. But this introduces error, and
by the following method we can eliminate both this and the
distance of the mirror from the scale by which we find 6 and
eter, before and after each experiment. Let a and a’ be the
deflections of the tangent galvanometer and the other galva-
be
— tan a= ae tana’,
and we have finally
\>7 G tana’ tané
R=Mz
TG’ tana sing# 1445-42?
Hf, A. Rowland—Absolute Unit of Electrical Resistance, 327
which does not contain H or H’, and the distance of the mirror
from the scale does not enter except as a correction in the ratio
of sin $6’ and tan a’; and, as a and 6 can be made nearly
equal, the correction of the tangent galvanometer for the
length of needle is almost eliminated. When the method of
1
recoil is used, we must substitute 1+4 A\° for the term in-
7
volving A, and sin $A’+sin $B’ in the place of sin 46, A’ and
B’ being the greater and smaller arcs in that method. This is
on the supposition that A is small.
The ratio of G’” to G must be so large, say 12,000, that it is
difficult to determine it by direct experiment, but it is found
readily by measurement or indirect comparison. —
It is seen that in this equation the quantities only enter as
the first powers, and that the only constants to be determined
which enter the equation are M, G and @”, which all vary in
simple proportion to the linear measurement. It is to
noted also that the only quantities which require to be reduced
to standard measure are M and T, and that the others may all
be made on any arbitrary scale. No correction is needed for
temperature except to M. Indeed, I believe that this method
exceeds all others in simplicity and probable accuracy and its
freedom from constant errors, seeing that every quantity was
varied except G’” and G, whose ratio was determined within
probably one in three thousand by two methods.
Having obtained the resistance of the circuit by this method,
we have next to measure it in ohms. For this purpose the
resistance of the circuit was always adjusted until 1t was equal
to a certain German silver standard, which was afterward care-
fully compared with the ohm. This standard was about thirty-
five ohms.
By this method, the following data are needed.
1. Ratio of constants of galvanometer and circle.
2. Ratio of the tangents of the two deflections of tangent
galvanometer. :
8. Ratio of the deflection to the swing of the other gal-
vanometer, :
4. Mutual potential of induction coils on each other.
5. Time of vibration of the n
6. Resistance of standard in ohms.
For correction we need the following:
1. The logarithmi
4. Rate of chronometer.
5. Correction to reduce to standard meter. .
828 H. A. Rowland—Absolute Unit of Electrical Resistance.
6. aN of the resistance of German silver with the
emaperse
7.» Perhporabare of standard resistance.
Arc of swing when the time of vibration is determined.
9. Length of needle in ee and other galvanometer
ary! compensated by the me
Onin variation of saaietsada of circuit during the experi-
Be
The i i errors are compensated by the method of
experim
1. The Teal and daily variation of the earth’s magnetism.
2. The variation of the magnetism of the nee
3. The magnetic and inductive action of the parts of the
apparatus on each other
4. The rea for length of needle in the tangent gal-
vanometer (nearly).
The axial displacement of the wires in the coils for
induction
6. The error due to not having the coils of the galvanom-
eter and the. circle parallel to the needle.
7. Scale error (partly).
8. The zero error ot pe
Caleulation of Constants.
Circle.—For obtaining the ratio of G to G”, it is best to cal-
culate them separately and then take their ratio, though it
might be found by Maxwell’s method (“Electricity,” Article
753). But as the ratio is great, the heating of the resistances
would produce error in this latter method.
For the simple cir
4
I EE (13(5) + &e.)
(A? 4+B2)2 A
where A is its radius aan ~ the distance of the plane of the
circle to the needle on its
Galvanometer for Jue 7. the more sensitive
its sensitiveness. If we make the galyanometer of two cir-
cular coils of rectangular section whose depth is to its width as
to 100, and whose centers of sections are at a radius apart
from each other, we shall have Maxwell’s modification of
Helmholtz’s arrangement. The oon He can then be found
by calculation or comparison with another coi
axwell’s formule are only adapted to coils ‘of small section.
Hence we must investigate a new formula.*
* A formula involving the first two We
peci ame ot ead the cente: wo tems of my sores, but ep erie siete tion, 18
— Elektrodynamische Maasbestimmungen inbesondere
H. A, Rowland—Absolute Unit of Electrical Resistance. 829
Let N be the total number of windings in the galvanometer.
Let R and r be the outer and inner radii of the coils.
Let X and = be the distances of tl:e planes of the edges of the
coils from the center.
t a be the angle subtended by the radius of any winding at
the center.
Let 5 be the length of the radius vector drawn from the center
to the point where we measure the force.
Let 6 be the angle between this line and the axis.
Let ¢ be the distance from the center to any winding.
Let w be the potential of the coil at the given point.
Then (Maxwell's “ Electricity,” Art. 695), for one winding,
te=—2n{1—c08 a-+-sinta( 20, (a) Q,(0)-+3(5) 2(a)Q()4+-&e.) |
t
and for two coils symmetrically placed on each side of the
origin,
‘ 1/b\" 5 1/d\*,
w=47 cos a—sin’a() 3) Q, (2)0+4(3) Q, (2) Q(0)-+&e.)
where Q, (9), , &c., denote zonal spherical harmonics, and
Q,’(@), Ss a oO denote the differential coefficients of spheri-
cal harmonics with respect to cos a. ;
As the needle never makes a large angle with the plane of
the coils, it will be sufficient to compute only the axial com-
nent of the force, which we shall call F. Let us make the
rst computation without substitution of the limits of integra-
tion, and then afterward substitute these:
Fates sa MI ae
N
F=3R—opy (X—=) Jt war,
and we ean write
oe 22N 2 6 H lik & °
F=——yx=a | H,+H,27Q,(4)+H,0Q.+ &
where H,==2 loge (r+a/z?+r")
He 13:5. (2é—1) sin? 1 ee ee na ltisen € &e. |
2 SPIN aA eae ge 2i—1 2—3
A st
2i-4 i(¢-1)(i—2
B=A oe ( )(¢—2)
‘M—1 = (241) 2
2i—6 , i(i—1)(i—2) .. (@—-4)
C=B ast (2i—1)(2¢—3)2.4
pac 428 i= 8)
=“ 37—5 (2i—i) (2i—3) (27-5) 2.4.6
E= &e., &.
330 H. A. Rowland—Absolute Unit of Electrical Resistance.
Substituting the limits for z, 7 and a, we find
R+V7X?2+R?2
r+V7X2472 one r+ a2 + 7?
H,=xX log,
R? r 1 R* -
=—1} Me a cake |
1 Rs
H,=— =a z (20X*+4-7X?R?+ 2R*) —
X!(X'-R)}?
— (20X'4 7X4 ant) —_B’_ (n+ 1a? R*+ 2B")
X*(X? +r’)? : se* (a? +R?)
r
4 yd or
The needle consisted of two parallel lamina of steel of length,
l, and a distance, W, from each other. As the correction for
length is small, we may assume that the magnetism of each
lamina is concentrated in two points at a distance n / from each
other, where n is a quantity to be determined.
ence
where cos # Ta tana wat seeing that the needle hangs par-
nt)” A
allel to the coils. In short thick magnets, the polar distance
is about 3 J and the value of n will be about 4 For all other
magnets it will be between this and unity. In the present case
n= nearly. ‘
As all the terms after the first are very minute, this approx!-
mation is sufficient, and will at least give us an idea of the
amount of this source of error.
Induction Coils.
The induction coils were in the shape of two parallel coils of
nearly equal size and of nearly square section.
Let A and a be the mean radii of the coils. Let 5 be the
Was distance apart of the coils.
t
2n/ Aa
young
V(A+a)?403°
Supposing the coils concentrated at their center of section we
know that
M,=42V Ka} (S—e) F(e)—2K(6) }
where F(c) and E(c) are elliptic integrals.
Seem eae CE is ed) de
H. A. Rowland—Absolute Unit of Electrical Resistance, 331
Ift¢ and 7 are the depth and width of each coil, the total
value of M will be, when A=a nearly,
1 | d?M d?M
M=Moti | Gantt geet f ete
and we find
d?
a ri 4 E(c) 4b7c* pm ie
dat =~ 34 aati OA Ro" hp s )
F(c) (c+
@M, _—- xe :
db? ~ A(1—c’)
6? c? ;
F(o)(2U—-e8)— gare ))—
1—c?-c4
B(o)(2—e8 eto mety t
Corrections.
Calling # and 6 the scale deflections corresponding to tan a’
and sin 40’, we may write our equation for the value of the
resistance
p) +4(5)
1-(£) "445
; K tand 6 (5 D
=Ttan a 6 d\? G\:U+A+ ete.)
1—35(5) +'22(5
where R’ is the resistance of the circuit at a given temperature
17-0° C., and K=20ME 14 a+b-+ete.) i ahah hy BD, ole.
and a, b, ete. are the variable and constant corrections respec-
tively.
a. Correction for damping,
a=—sA+4,A°.
R
b. Torsion of fiber. ne
The needle of the tangent galvanometer was sustained on a
point and so required no correction. e co
torsion in the other galvanometer 1s the same for # and 6 and
hence only affects ‘T. Therefore, if ¢ is the coefficient of
ie b= —Ht.
ce. Rate of chronometer. :
Let p be the number of seconds gained in a day above the
normal time
e=—+_.
86400 :
d. Reduction to normal meter. The portion of this Sai
tion which depends on temperature must be treated under ih
variable corrections. Let m the excess of the meter u
above the normal meter, expressed in meters; then
| d=+m.
332 H. A. Rowland—Absolute Unit of Electrical Resistance.
e. Correction of T for the are of vibration. This are was always
the same, starting atc, and being reduced by damping to aboute,,
—_— Tue =
c= + iyenn Ca” —%")s
where c, and ¢, are the total ares of oscillation.
f. Correction for length of needles. For the tangent gal-
vanometer, the correction is variable. For the circle it is
q
S= +1( :
where 7 is half the distance between the poles of the needle and
A radius of circle. For the other galyanometer it 1s
included in the formula for G.
uction to normal meter. As the dimension of R is a
velocity and the induction coils were wound on brass, the cor-
rection is
=-+-y('—?’)
where y is the coefficient of expansion of brass or copper, ¢
the actual and ¢” the normal temperature.
orrection of standard resistance for temperature. Let
M be the variation of the resistance for 1° C., ¢’” be the actual
and ¢v the normal temperature 17°°0 C.; then
B>=— p(t" —#"),
C. Correction for length of needle in tangent galvanometer,
x 15. ' e\ !
Vas += sin (a+ a)(r) (a’—a)
where 7’ is half the distance between the poles of the needle
No. 3. By the introduction of commutators at various points
all ge isturbance of instruments could be compensated.
io. a . .
No. 6. The circle was always adjusted parallel to the coils of
the galvanometer. Should ‘hes not be parallel to the needle,
G and G” will be altered in exactly the same ratios and will thus
not affect the result. The same may be said of the deflection
of the magnet from the magnetic meridian due to torsion.
H. A. Rowland—Absolute Unit of Hlectrical Resistance. 333
No. 7. 8 and é both ranged over the same portion of the
scale and so scale error is partly compensated.
o. 8. The zero-point of all galvanometers was eliminated
by equal deflections on opposite sides of the zero-point.
Instruments,
Wire and coils.—The wire used in all instruments was quite
small silk-covered copper wire, and was always ound
accurately turned* brass grooves in which a single layer of
Wire just fitted. The separate layers always had the same
number of windings, and the wire was wound so carefully that
the coils preserved their proper shape throughout. r
was used between the layers. As the wire was small, very
little distortion was produced at the point where one layer had
to rise over the tops of the wires below. Corrections were
made for the thickness of the steel tape used to measure the
circumference of each layer; also for the sinking of each layer
into the spaces between the wires below, seeing that the tape
measures the circumference of the tops of the wires. The steel
The advantages of small wire over large are many ; we know
exactly where the current ; it adapts itself readily to the
cm. long and its position was read on a circle 20° cm. diam-
eter, graduated to 15’. The graduated circle was raised so
that the aluminium pointer was on a level with it, thus avoid-
ing parallax. The needle and pe only weighed a gram
or two, and rested on a point at the center which was so nicely
made that it would make several oscillations within 1° and
ometer, which was made to order in ;
before 1 , and much time was lost before finding out the source of the difficulty.
334 H. A. Rowland—Absolute Unit of Electrical Resistance.
ment of weak currents. It was entirely of brass, except the
wooden base, and was large and heavy, weighing twenty or
twenty-five pounds. It could be used with a mirror and scale
or as a sine galvanometer. It will be necessary to describe
here only those portions which affect the accuracy of the
present experimen
The coils were of the form described above in the theoretical
porien, and were wound on a brass cylinder about 82 cm
ong and 11-6 cm. diameter in two deep grooves about 3° em.
deep and 25 cm. wide. The opening in the center for the
ale.
The coils contained about five pounds of No. 22 silk-covered
copper wire in 1790: turns.
wo needles were used in this galvanometer, each con-
structed so that its magnetic axis should be invariable; this
was accomplished by affixing two thin laminw of glass-hard
steel, to the two sides of a square piece of wood, with their
planes vertical. This made a sort of compound magnet very
strong for its length, and with a constant magnetic axis. The
first needle had a near] rectangular mirror 2°4 by 1°8 cm. on
the sides and -22 em. thick. The other needle had a circular
mirror 2-05 cm. diameter and about 1 mm. thick. The nee-
dle of the first was 1-27 em. and of the second 1-20 cm. long,
and the pieces of wood were about -45 cm. and °6 cm. uare
length of 49 cm. and 42 em. respectively.- The total weights
were 5-1 and 5-6 grams and the times of vibration about 7°
sp ipeimenneninaaeaaiinee hed Toa teen meee
H. A. Rowland— Absolute Unit of Electrical Resistance. 3385
and 11:5 seconds. They were suspended by three single fibers
of silk about 48 em. long.
In front of the needle was a piece of plane-parallel glass.
This and the mirrors were made by Steinheil of Munich, and
were most perfect in every way.
In the winding of the coils every care was taken, seeing that
a small error in so small a coil would produce great relative
error. And for this reason the constant was also found by com-
parison with another coil. The following were the dimensions:
Mean radius 4°3212 c. m.
212 r= 30212
X=3°475565 w= “935565
R-r=2°6000 X—wr=2°54000
N=1790°
whence
F=1832-25—1-70 52Q, (0) —4°50 b4Q, (A)+ 90 5°Q, (0) — &e.
Taking the mean dimensions of the two needles, we have
1=1°23, w='52, n=}, cosi’=748.
Q,(4)=+'339, Q,()=—354, Q,(W)=— 275.
.. G@=1832°25—"083-+- 071 — 002 + &c.=1832°24.
The coil with which this galvanometer was compared was
the large coil of an elec ynamometer similar to that de-
scribed in Maxwell’s “ Electricity,” Art. 725, but smaller. The
coil was on Helmholtz’s principle with a diameter of 27° cm.,
and was very accurately wound on the brass cylinder. There
was a total of 240 windings in the coil. The constant of this
coil was 78-371 by calculation.
T’o eliminate the difference of intensity of the earth’s mag-
netism, an observation was first made and then the positions of
the instruments were changed so that each occupied exactly
the position of the other: the square root of the product of the
coils together and the other with them separate. The results
were for the ratio of the constants
23'3931 and 23°4008,
which give
G=1833°37 and 1833°98.
The mean result is
1833-67 - °09,
and this includes seven determinations with two reversals of
instruments. This result is one part in thirteen hundred
greater than found by direct calculation, which
accounted for by the small size of the galvanometer ¢
is to be
oils and
336 H. A. Rowland—Absolute Unit of Electrical Resistance.
the consequent difficulty of their accurate measurement. A
comparison with the electro-dynamometer has such a small
probable error, and as it is a much larger coil, it seems best to
give this number twice the weight of that found by calcula-
tion: we thus obtain
G = 1833-19
as the final result.
It does not seem probable that this can be in error more than
one part in two or three thousand.
lescope, scale, &c.—The telescope, mirrors and plane-par-
nations was the mean distance. In using the coils they were
always used in all four positions. The probable error of each
set of twelve readings was +001 mm. The data are as fol-
lows, naming the coils A, B and C:
Mean radius of A=13°710, of B=13°690, of C=13°720.
Mean distance apart of A and B=6°534, of A and C=9°574, of
B and C=11°471.
N=154 for each coil, E=-90, n=-84.
For A and B we have
M=3774860°+ 3, (74250°—665 10°)=3775500°
The remaining terms of the series are practically zero, as was
found by dividing one of the coils into parts and calculating
the parts separately and adding them.
or A and C
M=25614 10°-+-1,(34000- —27230°)=2561974°
For B and C
M=2050600-+-1,(27500°— 19800°)—=2051320°
The calculation of the elliptic integrals was made by aid of the
tables of the Jacobi function, g, given in Bertrand’s “Traité de
Calcul Integrale” as well as by the expansions in terms of the
modulus after transforming them by the Landen substitution.
[To be continued.]
:
:
J. W. Mallet on Meteoric Iron from Virginia. 337
Art. XLVIII.—On a fourth mass of Meteorie Iron from Augusta
County, Virginia; by J. W. MALLET.
In 1871 I described * three masses of meteoric iron found
a few miles from Staunton in this State; still another has
lately been brought to light under the following circumstances.
About the year 1858 or 1859 a negro man, named Alf, belong-
it, but no one considered it curious or valuable enough to pay
the price asked, a dollar. This man is dead, and it cannot now
be ascertained where he found the specimen, but probably on
r. Van Lear’s land, and undoubtedly in his immediate neigh-
borhood. Failing to sell the mass, Alf threw it away in a
vacant plot of ground behind a blacksmith’s shop. Here it
lay for several years, until it was used, with some other loose
material, to build a stone fence. On account of its irregular
shape and great weight it soon fell out of the fence, and was
then thrown aside in the rear of a dentist’s house. He used it
for some time as an anvil on which to hammer metals and
orite before it was sent to Rochester, and have furnished me
weight was 152 pounds, or 68.950 grams. The crust was not
as thick as that upon the masses from the same locality previ-
ously examined, and at a number of points the metallic luster
* This Journal, III, ii, 10. : :
*The above account of the history of the meteorite was furnished by Mr.
Miller.
338 J. W. Mallet on Meteoric Iron from Virginia.
i . t i
n Lil hii rho ct Litt |
sti bits
ig 20 30 40 50,.C.m.
n analysis made by Mr. J. R. Santos of Guayaquil, Ecua-
dor, now working in this laboratory, gave the following results.
he a 91:490 Sulphur ........-43 -n-+ 018
Nickel ...:........... .7:659 Ohlorine nit ee
RNG ict. a ED ORIDOR 0 on 5 pnd an 20 }
Copper...-....-.----- ‘021 Silicon (counted as silica) 108
a ee os ee a so trace
Pnosonoras 6005'S. 06 99°963
The chlorine occurs as ferrous chloride, soluble in water.
87°5 grams of iron was used for the analysis, so as to render
ar’
tial examination of another specimen, however, showed that,
n such masses,
and probably of the nickel in the alloy, is not altogether unt-
form. The average amount of nickel is somewhat less than in
University of Virginia, March 6, 1878.
W. J. McGee—Drift Formations in Northeastern Iowa. 389
Arr. XLIX.—On the Relative Positions of the Forest Bed and
associated Drift Formations in Northeastern Iowa; by W. J.
McGEE. ti
and within ‘it are ada remains of the mammoth, the masto-
don, of Castoroides ohioensis, Bison lafrons, and their contem-
poraries. In most of the localities just mentioned the Forest
Bed is overlaid by a partially stratified deposit, regarding the
origin and age of which there is some doubt.. e condition
of the superficial deposits in the ribaghiborliood of the residence
of the writer is such as to throw much light on the question o
the true geological position of this formation. A few sections
nded.
are appen
I. A well in Farley, Towa.
Stirface ‘poll 7st a eS Se 2 feet.
Clean ay ‘wath occasional grainte mon feck ei ck .
Olay with bowlders, gravel and flint... -.------------
Thin-bedded, black, pci not als clay, with fag
ments of wood - Sans oe owe
: Thiek-bedded do., with "‘much-alecomposed fragments a
ood. Undisturbed by glacier -_----..----------- ‘
. Hard yellow clay, sometimes with bowlders. .- Posctan i e
D ravel and small bowlders-..----:---------- 2
: oe fiaeed ne.
e of the wood found in this well—probably Willow
) though not we i determined—was so well pre-
2 PN
oe an
1. Surface soil... 3 feet.
2. pe ay with occasional ua nite “bowld Aste bea Otek 10
; Same as in I OE ee oS ee oa acne < wae aoe np
7, | Yellow clay with sand, gravel and small bowlders --. 4 re
é Niagara oe
hio Geol. Rep., 1874, pt. I, vol. ii, p. 3.
340 W. J. McGee—Drift Formations in Northeastern Iowa.
Pieces of the soft shaly substance from the lower part of No.
4 were found to be slowly combustible, but contained too
much earthy matter to burn readily. Charred wood and sticks
burned off at one end were found in this well.
IIL A well two miles northwest from last.
Stratification not personally observed. At about twenty feet
a large stump of a tree identified as Red Cedar (Juniperus vir-
gintana) was struck in one side of the well. Below it a stra-
tum of the older glacial Drift several feet in thickness was
penetrated. The stump retained so much of its organic char-
acter as to render the water unfit for use when it rose to its
level.
IV. A well half a mile northeast from last.
1. Surface soil. --- - Ae Ceo es et. 4 feet.
2. Clay witha granite bowlder weighing 500 pounds ----- fat
8. Clay with gravel ._....- nou wid Jeli 8.1%
3 oe
ee ee ee ee ee ad
V. A well two miles northeast from last.
Stratification not observed personally. At about fifty feet
fragments of wood, one partially burned, were found inter-
mixed throughout a hard, blackish, laminated clay. Below
is the usual yellow clay, with gravel, sand and small bowl-
ders was found resting on Niagara limestone.
VI. A well quarter of a mile southeast of last.
1. Surface accumulation
2. (Absent, owing to denudation).
3. Clay with gravel, sand and bowlders..--.--- .------- 16e*
4, pe denice shaly clay, with fragments of wood, one
isturbe
5.§ identified doubtfully as Sumac. Disturbed by
glacial and alluvial action .............---------- 6 “
: t Yellow Clay, With Bravel, etn. : 5... i. 25.5 ------ 47
8. Niagara limestone.
topography beneath the Forest far as it has been
determined, is not greatly different from that of the present
surface. The wells given are but ples of all excavated
orest Bed or both it and the older Drift have been remov
or modified. The interesting fact is, that the uppermost de-
posit is in all cases the same, and is beyond the shadow of @
SO ee eo ere
W. J. McGee—Drift Formations in Northeastern Iowa. 341
metamorphic rocks from far to the northward. ‘These, hov
ever, are quite abundant. In some fields it has been necessary
however. Perhaps one in a thousand shows plainly grooves
and deep scorings; but many others are less distinctly marked.
Still not more than one-tenth exhibit any other marks of glacial
action than a rounded form.
The Forest Bed is found at many other localities in Iowa,
and within it the bones of the mastodon and beds of peat
have been discovered.+ The writer has also seen crania of
Bison iatifrons from the same horizon. It has generally been
considered to be—in other places as well as in Iowa—a post-
must be of interglacial age; and from a recent examination
the writer is convinced that the overlying deposits in Illinois
the slow retreat of the glacier. In Nebraska this carbonaceous
stratum has been found resting on glacial Drift and overlaid
WM both the Drift of the later glacier and the Loess of the
Missouri Valley.t The similarity of the organic remains found
in this stratum wherever exposed indicates a like age for its
deposits over the whole territory in which it 1s found.
* Dr. 0. A. White’s Geol. Rep. (of Iowa), 1870, vol. i, p. 87.
en c., pp. L17, 118, 119, and 339. :
“Superficial Deposits of Nebraska;” from Hayden's Report for 1874, p. 5.
Farley, Iowa, March 12th, 1878.
M, JOUR, vomnedsones Series, Vou. XV, No. 89,—May, 1878.
B42 J.W. Powell's Survey of the Rocky Mountain Region.
Art. L.— Geographical and Geological Survey of the Rocky
_ Mountain Region under the direction of Professor J. W. Powell.
_ Account of work performed during the year 1877.
AxsouT the middle of last May, the surveying corps again
took the field. This year the rendezvous camp was at Mount
Pleasant, a little town in Utah about 125 miles south of Salt
Lake City. Three parties were organized under the direction of
Professor A. H. Thompson, one to extend the triangulation and
two for topographic purposes, the latter being under charge of
Mr. W. Graves and Mr. J. H. Renshawe respectively, and
the former under the immediate direction of Professor Thomp-
son, assisted by Mr. O. D. Wheeler.
The area designated for the season’s work lies between 38°
and 40° 30’ north latitude, and between 109° 30’ and 112° west
longitude, Greenwich, and is embraced in atlas sheets 86 and 75.
angulation.—The triangulation party left Mount Pleasant
in June. The work of this year being a continuation of the
expansion from the Gunnison Base Line measured in 1874, it
was desirable to first visit some of the geodetic points established
in previous years but the unprecedented amount of snow yet
remaining in the high plateaus and mountains rendered this im-
practicable, and the first part of the season was spent in establish- -
ing stations on the T’a-va-puts Plateau west of the Green River.
In midsummer the party was able to visit the high plateaus and
connect the work of past years with that of this season. ter
the triangulation was extended to the east joining the work of
the United States Geological and Geographical Survey of the
Territories under charge of Dr. F. V. Hayden and to the north
to join the work of the United States Geological Exploration
of the 40th Parallel, Clarence King, United States Geologist in
charge. The whole area of the season’s work embraces some-
thing more than 13,000 square miles. The instrument used was
the theodolite hereafter described. The points sighted to on
‘the geodetic stations were either artificial monuments or well
defined natural points, and all stations were marked by stone
cairns,
:
sininihdia di le bie di ee
J.W. Powell's Survey of the Rocky Mountain Region, $48
a narrow valley through which passes the only practicable
route of travel between Central Utah and Western Colorado.
sands and deep tortuous cafions giving to the landscape an
appearance strange and weird.
he Book Cliffs rise to an average altitude above their base
of 3,000 feet, and about 8,500 feet above the sea-level, and the
country from the southern crest inclines gently northward to
the valleys of the White and Uinta Rivers. This gigantic ter-
race, called the Ta-va-puts Plateau, is cut in twain from north
to south by profound gorges through which the Green River
runs, known as the cafion of Desolation and Gray Cafion. The
drainage of the plateau is northward from the brink of the
cliffs through deep narrow cafions for many miles, but at last all
these enter the Cafion of Desolation a few miles from its head.
North of the Ta-v4-puts Plateau are the valleys of the White
and Uinta Rivers. Nearly all the latter and a large portion
of the lower course of the former are within the boundaries of
Mr. Graves’ work.
considerable bodies of irrigable lands are found along the Grand,
Green, San Rafael and Price Rivers; and in the valleys of the
Uinta and White Rivers, are other large tracts, on which the
waters of the streams named can be conveyed at slight cost.
Mr. Graves determined the extent, character and location of
these lands, and the amount of water carried by the streams
throughout the area embraced in his work.
On the Ta-va-puts Plateau are small forests of pine and fir,
but generally Mr. Graves’ district possesses no more timber than
sufficient to meet the future local requirements of actual settlers.
Topographic Work by Mr. Renshawe—The district assigned
344 oJ. W. Powell's Survey of the Rocky Mountain Region.
and drained from its very western edge toward the east by the
Fremont, San Rafael, Price and Uinta Rivers. The western
portion includes broad valleys, abrupt ranges of mountains, and
one plateau of considerable extent. The principal valleys in
this part are the San Pete, Juab and Utah, all having a general
northern and southern trend, an average elevation of about
5,000 feet, and all are drained by the San Pete River and the
streams flowing into Utah Lake. The mountain ranges standing
between the valleys are the Wasatch, rising in its highest peaks
to 12,000 feet, the Lake Mountains and the Tintic Hills each
reaching an altitude of nearly 7,500 feet.
The lofty table land called Gunnison Plateau has an area of
about 750 square miles, and an average elevation of 8,000 feet.
It is bounded on three sides by almost vertical walls, and is
extremely rugged and difficult to traverse.
There is but little irrigable land in the eastern portion of
Mr. Renshawe’s district, but the broad valleys of the western
contain large areas of excellent lands, and the numerous streams
furnish a good supply of water.
Mr. Renshawe determined the volume of water in every con-
siderable stream as well as the extent and localities of the irri-
gable lands throughout his district.
On the plateaus and mountain ranges are large quantities of
excellent timber. “
* On the head waters of the Price River and on Huntington
Creek are extensive beds of coal, and on that portion of the
Wasatch Range included in Mr. Renshawe’s district are deposits
of silver and galena.
. Renshawe extended the secondary triangulation over the
whole district assigned him, making stations at an average dis-
tance of about eight miles, and measuring all the angles of
nearly every triangle in the extension. He also made a con
nected plane-table map of the whole area, and complemented
his work with a complete set of orographic sketches.
etry—The hypsometric work of this season rests on
a primary base established at the general supply and rendezvous
camp at Mount Pleasant, and connected by a long series of
observations with the station of the United States Signal Service
at Salt Lake City. At the base station observations were made
with mercurial barometers four times each da: , and for eight
ercu-
ri barometers were carried y each field party, and observa-
tions made to connect every camp with the base station. All
the geodetic points and topographic stations were connected by
observations with mercurial barometers either with the camps
or directly with the base stations or both. All the topographic
stations were also connected with each other by angulation, and
\
SESE te eee
J.W. Powell's Survey of the Rocky Mountain Region. 345
from these stations the altitudes of all located points were de-
termined by the latter method.
Instruments. Base-measuring Apparatus. — The apparatus
used in measuring the base lines from which the primary trian-
gulation is developed consists essentially of wooden rods aligned
and leveled on movable trestles or tripods, the contact being
The line of coincidence is marked upon both plates and contact
is determined by a magnifier. A delicate spirit-level is attached
to each case to adjust it horizontally and a thermometer inserted
to determine the temperature of the rod. Two steel pins by
which the rods are aligned are fixed on the cases directly over
the center of the ends of the rods.
which a sliding cross-piece is clam by thumb screws.
Above this cross-piece parallel to and carried with it, is a sec-
atheodolite. The line is first ranged out and stakes set 500
feet apart along its length, then with six men to work the appa-
ratus, 3,000 feet per day can be measured with all the accuracy
d.
Theodolite.—The theodolite used in the triangulation is of a
new pattern, embracing a number of improvements demanded
by the character of the work. So far as possible the number
346 JW. Powell's Survey of the Rocky Mountain Region.
a
inches in diameter, and reads by double verniers to five sec-
the scale adopted by the
é ry for
Interior Department for the hysical atlas of the Rocky Moun- -
eo region, that is, a scale of four miles to the inch.
ments of its optical axis are recorded. The telescope rotates
about a vertical and about a horizontal axis similarly to the
telescope of a theodolite, and is connected by simple mechan-
ism with a pencil which rests on a sheet of paper attached to
the platen. When the topographer moves the telescope so as
to carry its optical axis over the profiles of the landscape, the
pencil traces a sketch of the same. This sketch being mechan-
ically produced, is susceptible of measurement, and is a definite
and authoritative record of the angular relations of the objects
presses Co loeeh cetre ae gee eaeea
J.W. Powell's Survey of the Rocky Mountain Region. 347.
sketched. The instrument is also furnished with a graduated
circle on which horizontal angles may be read to the nearest
half minute, and this circle is used for the secondary triangula-
tion. The orograph and plane-table are used conjointly, and
their results furnish data for the production of contour maps.
It is believed that by their introduction the quality of topo-
graphic work has been much improved, without addition to its
cost. hen a topographer takes the field with these two
instruments and plane-table sheets on which the primary trian-
gulation has been previously plotted, he returns with a map on
which all of the geographic features to be delineated have been
determined by their angular relations and the scenic character:
istics necessary to give proper effect to the maps, have been
outlined by instrumental means. In this manner the subse-
quent construction of maps at the office ready for the engraver is
reduced to a minimum of labor, while for the proper accuracy
the topographer is not necessitated to resort to his memory for
the appearance of the landscape, but only to the definite record.
rometers.—T he instruments used in the hypsometric work
yehrom-
’
are Green’s mercurial mountain barometers, Green’s ps
Classification of Lands by Mr. Gilbert—The Survey under
the se. of ee Powell has been extended over the
348 J. W. Powell's Survey of the Rocky Mountain Region.
to which it is practicable to convey them by canals, and these
lands were measured in order to determine the agricultural
eanals. Five million dollars is probably a moderate estimate
of the cost of redeeming the 500,000 acres that are susceptible
of reclamation, and the requisite capital will have to be con-
centrated upon a small number of large canals.
Since the first settlement of the territory in the year 1847
PRA OE ies sce 0
J. W. Powell's Survey of the Rocky Mountain Region. 849
the water supply has increased. It is reported by the citizens
that each stream is now capable of irrigating a greater area of
land than when it was first used. Creeks that once scan-
tily watered a few acres of ground now afford an ample supply
or double, treble, and even fifty times the original area. This
increase has been accompanied by a rise of Great Salt Lake,
which having no escape for its water except by evaporation
has stored up the surplus from the streams.
or the purpose of investigating the extent and the cause of
the increase of the streams, Mr. Gilbert made a study of the
fluctuations of the lake. It was a matter of common report
that the surface of the water had been subject to considerable
changes and that on the whole it bad greatly risen since its
shores were first settled; but previous to the year 1875 no sys-
tematic record of its movements had been kept. In that year
a series of observations was inaugurated by Dr. John R. Park
of Salt Lake City, at the suggestion and request of the Secre-
tary of the Smithsonian Institution. A small pillar of granite,
graduated to feet and inches, was erected at the water's edge
near a rocky islet known as Black Rock. The locality was then
a popular pleasure resort, and the record was undertaken by
r. J. T. Mitchell. Observations were made at frequent inter-
vals for more than a year, but were then interrupted by reason
of the disuse of the locality as a place of resort, and they have
not since been resumed in a systematic way. To obviate a
similar difficulty in the future, Mr. Gilbert caused a new record
post to be established near the town of Farmington, where the
work of observation has been undertaken by Mr. Jacob Miller,
and it is anticipated that in the future there will be no break in
the continuity of the record. ; 3
In the interval from 1847 to 1875, during which no direct
observations were made, there was nevertheless a considerable
amount of indirect observation incidental to the pursuits of the
citizens. The islands of the lake were used for pasturage,
testimony of the boatmen was compiled by Mr. Jacob Miller
and a history of the oscillations was deduced.
A similar and corroborative history has been derived by Mr.
Gilbert from an independent investigation. Two of the islands
used for pasturage are joined to the main Jand by broad, flat
bars, and during the lower stages of the lake these bars being
350 J. W. Powell's Survey of the Rocky Mountain Region.
either dry or covered by a moderate depth of water, have
afforded means of communication. It happens that the Ante-
lope Island bar was in use until 1865, when it became so deeply
covered that fording on horseback was impracticable ; and that
the Stansbury Island bar was first covered with water in 1866,
and has been used as a ford, with slight exception, ever since.
By the compilation of the testimony of those who have made
use of these crossings, a continuous record was derived, which
cannot deviate very widely from the truth, and the work was
checked by making careful soundings to ascertain the present
depth of water on the Antelope Island bar.
From 1847 to 1850 there was little change beside the annual
tide variation dependent upon the spring floods, and which
akes the summer stage in each year from one to two feet
higher than the winter. Then the water began to rise and so
continued until in 1855 and 1856 its mean stage was four feet
higher than in 1850. This progressive rise was followed by a pro-
gressive fall of equal amount, and in 1860 the lake had returned
to its first observed level. In 1862 there began a second rise
which continued for eight years and carried the water ten feet
above the original level. Since 1869 there has been no great
. change, bnt the mean height has fluctuated through a range of
about two feet.
the water surface increased from 1,750 to 2,166 square miles, or
nearly twenty-four per cent. By this expansion the surface
for evaporation was increased so that the lake could return to
the atmosphere the surplus thrown into it by the augmented
streams.
Whatever land is at any time flooded by the lake becomes
saturated with salt, and if the water afterward retires, remains
barren of vegetation for many years. The highest level reached
the last great rise of the lake, the storm line was six feet lower
than at present, and the intervening belt of land still retains
the stumps and roots of bushes that have been killed by the
Piet
*
J. W. Powell's Survey of the Rocky Mountain Region. 351
sage brush. The whole period is as likely to have been meas-
ured by centuries as by decades.
Thus it appears that the last twelve years have witnessed an
extension of the lake, which is not only without precedent in
the experience of the citizens of Utah but is clearly an anomaly
in the history of the lake. To explain it and to explain at the
same time the increase of the streams, there are two general
theories worthy of consideration.
he first is that there has been a change of climate in Utah
whereby the atmosphere is moister, so that the fall of rain and
snow has become greater and the rate of evaporation has be-
come slower. The second is that the industries of the white
man, which have been steadily growing in importance for the
last thirty years, have so modified the surface of the land that
a larger share of the snow and rain finds its way into the
water-courses and a smaller share is returned to the air by
thus check the evaporation from their surfaces, and the streams
which he thereby rescues from dissipation are used In irriga-
tion for a few months only, while for the remainder of the year
they pay their tribute to the lake. The destruction of grasses
he
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increase. :
- Geological work by Mr. Gilbert—During the preceding sum-
mer Mr. Gilbert had discovered a peculiar series of phenomena
852 J. W. Powell's Survey of the Rocky Mountain Region.
roduced by recent orographic displacements, and he has this
year found opportunity to study them in numerous new local-
ities. It appears that the system of faults and flexures—the
system of upward and downward movements— by which the
mountain ranges and the valleys of Utah and Nevada were
produced have continued down to the present time. Evidence:
of recent movement has been discovered on the lines of many
Idaho and Nevada, and demonstrating that the ancient outlet
he had discovered the preceding summer at Red Rock Pass was
the only one by which the lake had ever discharged its water
to the Snake River.
‘e Henry Mountains constitute a small grovp in South-
eastern Utah and stand quite by themselves. They are of
the earth, in the usual way, failed to penetrate the upper
tc of the crust and formed subterranean lakes or chambers.
he strata ying above the lava lakes were upbent in the form
les, and from these bubbles of sandstone and shale
with their cores of trap, the erosive agents of the air have
‘
J. W. Powell's Survey of the Rocky Mountain Region. 853
district in plaster, exhibiting the forms due to upheaval as they
would appear if unmodified by degradation. He prepared also
a topographic model, exhibiting the same forms as actually
modified; and the two models will be reproduced by photo-
graphy to illustrate the report.. The treatment of the second
element of structure is of a thorough character and includes a
discussion of the general principles which control the sculpture
of the land surfaces of the earth by rains and rivers. The vol-
ume is ready for the binder.
Geological work by Captain Dution—Captain Dutton resumed
his exploration of the same field which he has been studying
for three years, having recognized in it a certain unity which
renders it eminently adapted to an important monograph. The
region explored by him is centrally situated in the territory of
Utah, extending from Nebo in the Wasatch nearly southward
a distance of about 180 miles and having a maximum breadth
of about 60 miles. It possesses certain features which serve to
distinguish it both topographically and geologically, and he
roposes to call it the District of the High Plateaus of Utah.
It consists of a group of uplifts now standing at altitudes be-
tween 9,000 and 11,500 feet above sea-level, while the general
platform of the country is from 5,000 to 7,000 feet high. The
plateaus have been carved out of this platform by great faults,
and the general structure corresponds closely to that escribed
by Professor Powell under the name of the Kaibab structure
and illustrated by*him in his section of the region travers
the Grand Caiion of the Colorado. The relations of this belt
of high plateaus to the regions adjoining are of special interest.
At the close of the Cretaceous, the country lying to the east-
ward of it by gradation from an oceanic to a lacustrine
condition, the intermediate stage presenting doubtless a strict
analogy to the condition of the Baltic. This Kocene lake area
Colorado River. During Cretaceous and Eocene time the area
now occupied by the Great Basin was dry land, and its dennda-
tion must have furnished a large part of the sediments which
were spread over the bottom of the great lake. The movements,
which took place during the Eocene, at last resulted in the
desiccation of the lake, and though a strict chronological correla-
tion to European and other divisions of time cannot be made
with certainty, it may be provisionally inferred that this desicca-
tion was completed before the commencement of the Miocene.
It was brought about by the more rapid uplifting of the lake
area than that of the Great Basin until at last the former area
became the loftier of the two, thus reversing their relative alti-
tudes. The lake area is now a portion of the so-called Plateau
Country and since the commencement of the Miocene (para-Mio-
354 JW. Powell's Survey of the Rocky Mountain Region.
cene) has been subject to a great and continuous erosion. The
district of the High Plateaus occupies a portion of a narrow
belt separating the Plateau Country from the Basin Province
and therefore stands upon the locus of the ancient shore line
which in the lacustrine stage bounded the two areas. To that
shore line they stand in an intimate and remarkable relation.
To its trend the great displacements maintain not merely gen-
eral parallelism but an approximation to strict parallelism both
in totality and in detail which would not have oie anticipated
and which cannot be purely accidental, and seems to point to
some definite determinative association between the littoral
from the arched, flexed and tilted types prevailing in other
disturbed localities. There is an abrupt transition from this
preserved.
But of all the features displayed by the High Plateaus the
most remarkable are the manifestations of former volcanic
activity. Both in area and thickness the volcanic emanations
ve. They cover more than 5,000 square miles,
‘SS &
ter pa
lace after the lake basin had been ned or had shrunken to
imits outside of the district, for sedimentary beds have not been
found intercalated between the various flows but always under-
he them. It is therefore impossible to fix with great precision
the commencement of the outbreaks, but the general indications
Neericey,
i) Syren aa
J. W. Powell's Survey of the Rocky Mountain Region. 355
are, that they began very soon after the close of the lacustrine
period, and they may have commenced still earlier. The erup-
ive epoch was undoubtedly a long one. The individual flows
are very numerous and represent all the great groups of eruptive
rocks. In many cases the quantity of material extravasated is
so great that the eruptions may we called massive, not
however of such marvellous extent as asserted to have been
ave ema-
nated during recent or modern times from any existing volcanic
and precision. so vast are the accumulations and so expansive
are the sheets, and at the same time so numerous that whereso-
ever they were emitted the earlier vents must have been buried
by later deluges of lava, and even the more recent vents, except
in the case of the latest basalts, have been swept away by slow .
erosions in the long period which has elapsed since their activity
was extinguished. There are, however, still remaining, distinct
a certain sense uneonformity of the various eruptions, and
greater irregularities in their bedding as compared with the
¥. y
ency took place after the close or during the decadence of the
tean Province occurred. During its progre I
must have taken place, and their later age 18 readily identifia-
356 J. W. Poweli’s Survey of the Rocky Mountain Region.
long enough after the close of the Eocene to allow for the accu-
mulation of these vast bodies of voleanic beds. This may
carry the period of faulting far into the Miocene period, or pos-
sibly as far as the commencement of the Pliocene. But while
One point which during the study of this region has engaged
the careful attention of Captain Dutton, has been to ascertain
whether it presents any such sequence in the lithological char-
acter of the eruptions as is asserted by Baron Richthofen to
prevail in the voleanic districts of Europe, South America,
Asia Minor, and the Sierra Nevada. This asserted sequence
has engaged the profound attention of most vulcanologists and
is of great importance in relation to all questions bearing upon
that the high plateaus of Utah exhibit in a deci anner
essentially the e sequence which Richthofen claims for
ther volcanic he earliest eruptions consist of roc
the great displacements and partly through the agency of ero-
sion, and wherever found it is seen to occupy the lowest posi-
J.W. Powell’s Survey of the Rocky Mountain Region. 3857
tinued to have its seat through a long cycle in and about the
same locality. The propylite is succeed a rock answering
to Richthofen’s description of hornblende andesite, which is
usually overlaid by a rock rich in augite with triclinic feldspar,
which may be termed augitic andesite. Still higher in the
series are found immense masses of trachyte which, however,
is frequently intercalated with dolerite. The variety of the
trachytes is very great—so great indeed that were it not for
the persistence of certain mineralogical as well as textural
characteristics, which are universally accepted as being dis-
tinctive of that group of rocks, one might feel strongly
tempted to make numerous subdivisions of them. ex-
tremes of the varieties of the trachytes might be represented
ing of well-developed orthoclase feldspar imbedded in a fine
paste highly charged with peroxide of iron, Between these
Tn the lithological scale, propylite and hornblendic andesite are
very nearly intermediate between the extremes of acid roc
pe "
toward the acid end of the scale, and on the other toward the
Sense independently of each other, so. that they intercalate ;
the acid becoming at one end more acid with the progress of
the volcanic cycle, and the basic rocks becoming more basic.
, series seems to pursue its own order and to be subject to
its own law, so that being originally divergent, they become
more and more widely separated in their lithological charac-
Am. Jour. oe ae Vou. XV, No. 89.—May, 1878.
858 J. W. Powell's Survey of the Rocky Mountain Region.
ters, as the cycle proceeds. Thus at the commencement of the
activity we have propylite and hornblendic andesite, which are
closely assimilated to each other in their physical characteris-
tics; at the middle stage we have trachytes and moderately
basic dolerites, which are moderately separated, and at the close
we have rhyolites and basalts, which stand at the opposite ends
of the scal
and to correspond with each relief map a stereogram in plaster
18 constructed on the same scale, designed to exhibit such sur-
[To be continued. ]
‘
H. Ward Poole on Just Intonation in Musie. 359 ©
Art. LI.—Just Intonation in Music. Its Notation and Instru-
ments; by HENRY WaRD Pootg, M.A., of South Danvers,
Massachusetts; and Professor in the National College of
Mexico.
Ir is evident that there is a general want of intelligence con-
cerning the fundamental laws of Musical Intonation, the consti-
comma, etc., can be recognized and sung. Without reference to
previous times, I can declare from abundant personal knowl-
edge, and actual demonstration, that the chord of the seventh
is most agreeable and easy to give with the just ratio of 4:7,
and that there is no practical difficulty in singing in just in-
tervals. There appears to be a general desire expressed for
such perfect intonation, and in consequence the following obser-
vations may be interesting. . :
However complicated this subject may appear when studied
in books which do not have any primary definitions or canons,
it can be made as clear and orderly as naturally it would be
supposed, in view of the fact that music is based upon the
mathematics. :
Classification of Musical Tones into three Principal Orders.—
Admitting into music only the prime numbers 2, 3, 5, 7, and
considering the 2 as auxiliary, forming octaves, and inversions,
Harmonic), 4:7. A series (each a fifth from the next,) is
ormed of each of these kinds, and we have three Prime Series.
A-due mixture of the notes of each is necessary for harmony.
Using the letters, C, D, E, etc., we may express: the series to
which each belongs in various ways. In common notation it
360 H. Ward Poole on Just Intonation in Music.
the First series with Red: giving to the e, and all of the Second
series, the Yellow, which, to show well by artificial light will
e well done by gold. In like manner, the Third series, that
of the Sevenths, indicated pie a gothic ugha will be colored
Blue.* Nothing remains but to call the tones by distinctive
names. The syllables of Guido answered 1 this purpose when
there was no “modulation within the key,” and no account
made of Perfect sevenths. T'o the modern syllables re two,
which were not in the original i in the “Ut queant laxis ;” to wit,
the “Do,” and the “Si.” Keeping the Do as it is, and changing
the initial Tether of the si, so as not to confuse it hereafter with
that of sol, we may find a common ending to all the notes of the
first series, or that of the Fifths. These are the Ist, 2d, 4th and
5th. Preserving the lst and 5th as they are, but rejecting be
final letter of the sol, and making the rest conform, we shall h
Do, Ro, Fo and So. Their class is known by the abiding ;
the place of each in the scale by the initial consonant. For the
second class, that of the Thirds, mi, la, si, we preserve also the
present termination of the majority, and have mi, li, and Zi.
-For the Perfect sevenths or Third series, which are generally
sounded by the termination of e (Italian), we preserve the same,
and zi flat is Ze. And the dominant seventh, lower than Fa,
will be Fe. There are two different Diatonic Scales oreuel
as the Seventh 4:7, is introduced or not; they will be ex
in reference to their syllables for singing, their letters. Fol,
relative vibrations and intervals, as follows:
TRIPLE Dratonic SCALE.
a aiaae Chords als C, G and F.
Fo : : -
In key of C, Ci 5 F G
Colo Red Red Yellow Red Red Yellow Yellow Red
Relative Vibrations, 48 54 —s«GO 64 72 90 «96
Intervals, 8:9 9:10 15:16 8:9 9:10 8:9 15:16
Dovuste Diatonic Scae.
Common Chord ay C; Chord of Seventh ap arg on G.
Fo » So i Ze Bs Fo
a of C (Tonic ¥), -@ B’ ri
lors, Yellow Hue Red Red Yellow Red
Beletirs Vibrations, se chciag 6 ye gs a eS
48 Shoo: 60 6312 81 0: 1%
Intervals, | | 8:9 9:10 20:21 7:8, 8:9, 9:10 .16:16
* Thad selected for the three Prime Chords, the colors generally considered 38
eainel
as nearly as could mination, with the Prime Chord of
Third. ow, Green, and Blue being as Do, Ro, mi and Fe (the
t 7th), or as + the num! the le «semen Seale 32 40, 42,
the Violet approxi 6 Sn 8 a joe Selle tabl
‘in ¢ 7 Pr ‘ diraaia” AO saat den
in the ‘
2
PRR iB
H. Ward Poole on Just Intonation in. Music. 361
The Double Diatonic Scale has two notes differing from two
of the triple scale on the same tonic—which is F; although its
tones are all in the key or scale of C, being identical with the
Triple Diatonic of C, with the exception of the change of b into
B’. But its ending and tonic is F. Having thus provided for
the notation and distinction of these different series of Primary
st
effective ring. Especially in duets is this observed; the two
voices are constantly giving pairs.of different colors. The
duplicates or notes of the remaining series—there being three—
monious, 6:7, and d
n ¥,
“grave second ” of the old theorists, and is the sixth of the:
e of F, and
“modulations within the key.
Scale of C, harmonized,
~ ODeFGabc ChaGFeDC
unison b Cae F Ge eG FedC b unison
The instruments of just intonation are those of free tones,
as the voice, the violin class, and the trombones, etc., and those
of fixed tones, as the organ and other instruments to be
described. . . ey
The Enharmonic Key-board for organs, etc., described in this
Journal in July, 1867, while preserving its essential principles,
is capable of being varied to embrace more or less series of
362 H.. Ward Poole on Just Intonation in Music.
sounds, and to give to each the prominence desired. I shall
describe one which embraces the three series of Prime chords,
and, in addition, a Fourth, of the leading notes to the Thirds of
eries IT, which are used in ornamental passages and the
digitals will fall upon these lines, and will be understood by
reference to the diagram, the mutual relation being the same in
-Dragram.—Simply to show the relative position of the Digitals of the four
Series ; their exact si ing as follows:
@ = 6°5 inches + 24 (= 0-27). b= 0°9.
: th.
Wid Length.
L. (C, D) 4a (and 3a) 4
IL. tg d, e) 2a 3b
IT. (C', E57) 2a 1d
IV.( cH, a 26
all parts of the boards. The digitals of each signature are ele-
vated one-tenth of an inch as they go backward. The base of
the digital C, with its 3d, e, and d#, (leading note to e,) and its
seventh B are ,'; of an inch higher than F, a, g# and EB’, and
the same distance lower than G, b, a and F. The white keys
ae ee a
H. Ward Poole on Just Intonation in Music. 363
of Series I being at this level, the black keys rise 0°45; the
orange keys, (Series IV,) are 0°75; and the blue keys of Series
III are 0-90, All the elevated keys are reduced in width, down
to the base, so as to allow the finger to enter freely between
them. The number of digitals being 48, each lever is taken at
the half of these primary 24 divisions, and all lie in one level
at the rear of the key-board. In construction, the number of
pipes (or vibrators, in the cabinet organs) is reduced by using
the same for those which being at the distance of 8 Fifths an
1 Third are practically identical. (§ 29, 30 this Journal, July,
186
Justly-Intoned Pianofortes.—It is desirable to obtain a loud
and full tone by a single wire, large and at full tension. Then
with an enharmonic key-board and the triple sets of wires, the
whole will be easily kept in tune, and will sound louder than
if they were tempered. i ;
Wind Instruments of the class of the horn, cornet, etc.,
depend, for the fundamental tone, on the length of the tube,
and for the harmonies, on the tension of the lips. The funda-
mental length may be varied by the common cornet valves or
“pistons” and corresponding supplementary tubes to give the
tones of series I. These valves are arra in the order of
the fifths, or thus: F,C, G, D, A, E, B, ete. To play the
triple diatonic scale of C will be used the valve of C (or the
simple tube of the whole instrument, if so constructed) and
those of F and G, on its right and left; the order of these dom-
inants, etc., is the same in every key. For the sake of economy
?
364 S. W. Ford—Forms of Brachiopoda.
Art. LIL—On certain Forms of Brachiopoda oceurring in the
Swedish Primordial; by S. W. Forp.
; ing to M. Linnarsson’s
description, in the absence of the longitudinal *slit of Discina,
the perforation of the apex of the ventral valve, and in its inte-
rior markings so far as these have been made out. The shell
substance is corneous. . Linnarsson considers the most
nearly related genera to be Obolella and Acrotreta, but at the
acea the presence of an umbonal orifice is always readily recog-
nizable. The interior of this valve, so far as known, shows 00
trace whatever of muscular scars or imprints.
In that subdivision of the American Primdedial known as the
Lower Potsdam, and which is considered to lie above the Para-
dowides-bearing strata of this continent, we have at Troy, N. Y.,a
species of Lingulella (L. coelata), very closely resembling in the
interior markings of its dorsal valve the dorsal valve of Linnars-
son's A. coriacea, and in the same formation, both in New York
and Canada, another form bearing an equally strong resemblance
to his A. granulata. This latter American form is the operculum
gy a Pt i. Its true character was first ascertained by Mr.
illings, who described it, together with the shell to which it
belongs, in the Canadian Naturalist for December, 1871, under
the name of Hyolithellus micans.+° It is usually circular in
31, Om faunan ilagren med Paradomides dlandicus;” af G. Linnarsson. pines
‘oreni -i Stockholm Farh Als. o. .
¥ Boo alao this Journel for May,1872. CR penne
S. W. Ford—Forms of Brachivpoda. 365
form, rarely broad+ovate longitudinally, and has an excentric
apex or nucleus. Around this point the surface lines are
arranged concentrically. Some of the specimens show also the
existence of fine radiating lines in the nucleal region. The
oramen does not appear to be a constant feature. The inte-
rior of A, granulata has not been observed and the dorsal valve
1s in doubt. The form is nearly cireular, the deviation from
and H. impar,* permit us to observe the interior of this piece.
In neither do we find any trace of muscular scars. In this
- fe preg rnal for June, 1872. ;
ae Pingel sg adi oari~ pred poda of Bohemian Basin,
an a ition; Lut such a compositic 0 eer
tively stated to characterize any of them (Systéme Silurienne, &e., iii, 1867, p. 66).
t Bull. Soe. Geol. Fr., t. xvii, p. 532, pl. vim, fig. 2.
866 S. W. Wallace—“Geodes” of the Keokuk Formation.
Ido not intend by the foregoing observations to assert that
the dorsal valve of M. Linnarsson’s A. coriacea is the dorsal
valve of a Lingulella, or that what he sets down as ventral
valves of A. coriacea and A. grunulata are both, or either of
and Swedish forms compared, and which appear to me to be
sufficiently pronounced to at least. suggest the question whether
the Swedish species noticed. may not, as a whole or in part, be
susceptible of a more rigorous determination.
New York, January 22, 1878. |
Arr. LIIL—On the.“‘Geodes” of the Keokuk Formation, and the
_ Genus Biopalla, with some Species; by SaMUEL J. WALLACE,
of Keokuk, Iowa.
THE large hollow stone balls, set inside with myriads of
brilliant crystals, which are found in the upper beds of the
Keokuk Formation (Subcarboniferous), are well known for
their beauty and as curiosities, under the names of Geodes,
Niggerheads, etc. They are very plentiful, of various sizes,
from a few lines to over two feet, where that part of the forma-
tion is exposed in the Mississippi Valley, and in the lower
Drift and the Alluvium derived from it.
nessee. ‘Tio the we ,
sibly reappears in the geodes found by Professor Comstock in
the Wind River region, Government Survey. z
_ ‘Phe matrix bed is generally shale, varying sometimes to lime-
stone and to porous rotten stone. The lower layers are lime-
stone but not so pure as the next layer below, which here is the
S. W. Wallace—“ Geodes” of the Keokuk Formation. 367
best quarry rock of the Keokuk Formation. Stratification
marks often show over and around the es similar to those
around bodies in mud banks formed by currents. The shale
seems to be but the remains of original deposits several times
thicker, which have evidently béen dissolved out, leaving the
insoluble portion to be compressed to the present shale. e
limestone portions have not been compressed so much.
The geodes themselves are merely crystalline shells formed
from percolating water around the walls of vacant cavities.
The outer shell is silica, generally chalcedony, with crystals of
various minerals, principally silica and calcite, pointed inward in
great variety and beauty. The external forms are sharply
t. .
__ The Indiana Geological Report, 1873, 278, gives the
idea that they owe their origin to animal remains. This is
evident by the peculiar family likeness through a great variety
of sizes and forms; and by the lack of any other cause for
them in such remarkable numbers, shapes and sizes.
- An extended study of thousands of specimens and exposures,
by the writer, confirms this by the recognition of peculiarities
of growth and nature. It seems that the cavities were formed by
the rotting out of sponges which had become covered by de-
Sponges of trade, but without stems or apparent means of
attachment. They may have of ‘
drifting along on the soft bottom, and often became covered in
368 SW. Wallace—Geodes” of the Keokuk Formation.
the soft deposits. They also often grew in fixed positions, as
they are found crowded and fitting together in beds, wit
angular forms. It is evident that only those which became
covered by deposits would leave any remains in the strata.
There is a great variety of forms and markings, but they are
mainly of a few general and related types. The principal
type is that of a massive peculiar cushion-like figure, with in-
are similar, but the top is usually distinct from the lateral sides.
They are frequently nearly round, sometimes higher than wide,
but usually have three different diameters, the shortest of
which is vertical, and so form a flattened oval.
_ There are indications that the structure was fibrous; the
fibers mainly running conformable to the surface and to the
a large crinoid stem. It has split the column in five parts, bend-
ing them apart to fit its form, into which they are imbedded up
the sides. This is well preserved and curious. ;
lany fine as well as large specimens. exist in collections
here, and enough for many car-loads have been ship away.
The largest, showing the outside markings finely, is owned by
R. F. Bower. It is twenty-six inches across. A larger one,
| generally arises
mineral sponges, or from their having been silicified before
ppea
Wseiaie EELS Nea ee eee ee
S. W. Wallace— Geodes” of the Keokuk Formation. 369
non-mineral substance, and many parts formed of lime, have
first entirely disappeared, so as to leave vacant cavities. me
of these are still vacant. But most have been afterward filled
by crystals from water containing bicarbonate of lime and silica,
which show no internal structure of the original body. i
includes not only these grades, but a large proportion of the
crinoids, skells and corals, that originally arias lind: so that
this is not so strange for the non-mineral sponges as for those.
The following is the principal distinct type:
BIOPALLA (new genus).
inches, varying from one line to over two feet; no foot-stalk
marked peculiar cushion-like figure.
Named from the Greek, féo¢, life, and zadda, a ball.
There is uncertainty as to the distinction of species, but I
venture to name the following:
“eke very distinct, few to medium, symmetrical and regular.
nterspaces large, swelling lobe-like. A few largest indrawn
ion.
Biopalla’ Wortheni—Size medium to large; form varied ;
vertical and lateral faces different. Markings on top more or
less sharp and crowded; on lateral sides, less numerous, and
ehinngatol vertically ; on bottom not so sharp as on top; other-
wise more or less varied, as in B. Keokuk.
From Hamilton, Ill.; Drift ; and other places.
Biopalla Woodmani.—A peculiar form from the Drift, Keo-
kuk, Iowa, supposed to be from the northward. Found as
370 Barreti—Coralline Limestone from Montague, New Jersey.
Biopalla Heckeli.—Size medium to ——. Form sometimes
flattened. Markings often distinct. Surface with more or less
open gash-shaped cup-like cells, differing in size with the body,
one-third to one inch in longest diameter, in directions conform-
able to those of the furrows.
flattened, lateral edges thin and centers more or less projecting.
Markings generally not deep; often pit-like marks; sometimes
an indrawn furrow runs diagonally from bottom to to
around, with centers along it. Often beautifully translucent,
with peculiar markings. :
From Drift, Keokuk, Iowa, ete.
Biopalla palmata.—Size medium to ——. : Form flattened.
Markings not deep on top and bottom, but elongated toward
the edges; the edge deeply serrated by projecting interspaces,
and deeply indrawn vertical furrows.
rare and peculiar form. Keokuk, Iowa, Drift.
Art. LIV.—The Coraline, or Niagara Limestone of the Appala-
chian System as represented at Nearpass’s Chiff, Montague, New
Jersey ; by Dr. S. T. Barrert, Port Jervis, N. Y. :
Oe ae
:
|
:
F
.
|
|
:
'
Barrett—Coralline Limestone from Montague, New Jersey. 371
former communication,* and the Tentaculite limestone with its
two divisions of dark blue and quarry stone occupy the upper
twenty feet of this cliff, while below the Tentaculite, and pale-
ontologically connected with it, are nearly horizontal. strata,
about thirty feet in vertical thickness, apparently referable to
Water Lime division of the Lower Helderberg group.
Lying below the Water Lime are fifty feet vertical thickness
fe which contain species characteristic of the
Coralline limestone at Schoharie, with a larger proportion of
Niagara species than are reported from that locality, a few
Clinton types and some perhaps new or peculiar species,
hese species as far as identified are as follows:
Coralline limestone species: Cyathophyllum inequale= Colum-
naria inequalis, Strophodonta —— = Leptena —— of Plate 74,
figs. 8a and 384, Pal. N. Y., vol. ii, Ahynchonella lamellata=
Atrypa lamellata, Meristella nucleolata=(Atrypa) nucleolata, Caly-
mene camerata; all of which were identified by Mr. Whitfield ;
Stromatopora constellata, Tellinomya(?) aequilatera and Avicula
securiformis, identified by myself. oo:
Niagara species : Halysites agglomeratus, Favosites pyriformis,
Cladopora seriata, Cyatho Shumardi, Rhynchonella pisa; identi-
fied by Mr. Whitfield; Halysites catenulatus, Syringopora mul-
ticaulis, Favosites venustus, F. purasiticus, Stromatopora concen-
trica, Trematopora tuberculosa, Aulopora precius, Spirorbis wnor-
it Pholodops ovalis and Ambonychia acutirostra, identified
y myself. ;
Cini species: Caninia bilateralis by Mr. Whitfield, Ten-
taculites minutus and Beyrichia lata by myseli
A very beautiful Proetus of about the size and general out-
line, as far as can be conjectured from the fragments in my
possession, of the P. Si (2), Pal. N. Y., vol. ii, Pl. 67, occurs,
very rarely, throughout this lower fifty feet. The pygidium is
subsemicircular, narrowly rounded behind, margined. bes
subequal, mesial lobe elevated, obtuse posteriorly, number of
segments thirteen or fourteen, continued backward to the end.
Surface of the cheeks and margin of the pygidium vermicu-
i i as known, granulate. Inferior
marginal portions of the pygidium and cephalic shield incras-
ith i lize, appearing much as represen
species doubtfully referred by Professor Hall to the Proetus
Stokesii of Murchison, but differs very much from the figures
and description there given. I have named it, provisionally,
Proetus pachydermatus.
* This Journal, vol. xiii, pp. 385 and 386. The Stromatopora Limestone is best
seen at Mr. Sandford Nearpass’s Quarry, ¢ mile northeast of Nearpass s Cliff.
872 Barrett—Coralline Limestone from Montague, New Jersey.
The Strophodonta* (Leptena) of Pl. 74, figs. 3a and 3b,
Pal. N. Y., vol. ii, is very abundant in the lower beds of this
Coralline or Niagara limestone. Its ventral valve has the
surface characters represented enlarged in fig. 30,+ its dorsal
valve has the flat radiate strise and the concentric, crowded,
thread-like strize represented in fig. 6d of the same plate. Both
valves have a denticulated hinge line, the cast of the interior of
the ventral valve resembles fig. 4a, the cast of the interior of
the dorsal valve is near figs. 6a and 6 of the same plate. The
impression of the cast of the interior of the dorsal valve shows
widely divergent socket-ridges,t with three subparallel ridges in
the bottom of the shell, the mesial longest and extending two-
thirds the length of the valve toward the front. Old shells
have about the size and form of fig. 4a. Shell flat, undulated,
inequale and the Strophodonta (Ne
the other species being represented by a very few depauperate
N. Y. Pal for the Niagara group. The mural pores show
plainly in thin vertical sections, or, better yet, in sections cut
obliquely transverse to the axis of growth.
* T have labelled it provisionally S. Nearpassii
os
.
more arenate
t Cardinal processes not apparent.
= eek hapa ga ieccolendatamucliate nee > 2 eh a IRA
SE Saar 24 c=
:
t
ne EE nee ee eT nT NRE ie Lee,
O. Harger—Isopoda from New England. 373
Art. LV.—Descriptions of new Genera and Species of Isopoda,
from New England and Adjacent Regions ; by OSCAR HARGER,
Brief Contributions to Zoology from the Museum of Yale College,
No. XXXVI
THE genera and species described in the present paper are,
except the first, marine and were, mostly, collected by the
United States Fish Commission, along the New England coast.
More complete descriptions with figures of all the new, and
most of the old species, are nearly ready for publication in the
Report of the Commissioner. As it seems desirable, however,
to give a wider publication to the genera and species believed
to be new, the following diagnoses are here inserted.
Actoniscus, gen. nov.*
oO
A. ellipticus, n. sp. Body oval. Head with a prominent
angular median lobe, and broadly rounded, divergent late
lo Eyes oval, longitudinal, prominent, black. Antennulee
rudimentary. Antenne nine-jointed ; first segment short; sec-
ond strongly clavate; third smaller, clavate ; fourth flattened-
cylindrical; fifth longest, slender, bent at the base ;
shorter than the fifth segment, composed of four subequal seg-
ments, tipped with sete. Terminal segment of maxillipeds
elongate triangular, ciliated and slightly lobed near the tip.
First thoracic segment excavated in front for the head, shorter
above than the following segments except the last, which is short-
est. Legs small, scarcely spiny. Pleon continuing the regular
oval outline of the thorax, apparently with four pairs of lamel-
lar cox, the last pair are, however, the enlarged seg-
ments of the uropoda and are notched on their inner margins
for the short outer rami, while the more slender inner rami are
borne lower down on the under surface. The rami scarcely pro-
Ject beyond the general outline. :
Wis ties iG been collected by Professor A. E. Verriil, at
Savin Rock, near New Haven, and also at Stony Creek, in com-
pany with Philoseia vittata Say.
* From axr#, the beach, and Oniscus.
Am. Jocr. Sc1.—Tamp — Vou. XV, No. 89.—May, 1878.
3874 O. Harger—Isopoda from New England.
Chiridotea,* gen. nov.
First three pairs of legs terminated by prehensile hands, in
each of which the carpus is short and triangular, the propodus
is robust and the dactylus capable of complete flexion on the
pro Antenne with an articulated flagellum. Head
dilated laterally. Operculum vaulted, with two apical plates.
is genus is founded on Ch. ceca (Idotea ceca Say), which
occurs on this coast from Florida to Halifax, Nova Scotia.
It includes Ch. Tujisii (Idotea Tufisit Stimpson), of the New
England coast from Long Island Sound to the Bay of Fundy,
and, as constituted above, would also include Ch. entomon
(/dotea entomon Bosc.), from the Baltic and other European local-
ities, and Ch. Sabini (Idothea Sabini Kroyer), from the Arctic.
e above mentioned species ought certainly to be separated
from Idotea tricuspidata Desm., which may properly be regarded
as the type of the genus Jdotea Fabr.
Synidotea,t gen. nov.
Astacilla Americana, sp. nov.
Body nearly uniform in size throughout in the female, with
the fourth thoracic segment narrow in the male, tuberculated.
Head united with the first thoracic segment, and, together with
slightly surpassing the second segment of the antennz in the
female, nearly attaining the middle of the third in the male;
basal segment swollen, nearly as long as the next two which
are much more slender, last or flagellar segment shorter than
the peduncle in the female, longer than the peduncle in the
male. Antenne about three-fourths as long as the body,
fourth segment longest, then the fifth and third; first two seg-
ments short; flagellum three-jointed, short. First thoraci¢
* From xép, a hand, and Idotea. + From ctv, with or together, and Idotea.
|
|
O. Harger—Isopoda from New England. 375
females being generally considerably larger than the males, but
More specimens are necessary to prove the constancy of this
proportion. :
The specimens of this species were found adhering to Prim-
noa, from St. George’s Bank. :
Astacilla Fleming, is synonymous with Leacia (Leachia) John-
ston, which is preoccupied.
exceeding the propodus; second pair longer than
third and fourth increasing slightly in length; carpus and pro-
876 O. Harger—Isopoda from New England.
podus subequal in all, armed, in the second pair only, with
spines. Swimming legs (last three pairs) robust, carpus sub-
circular, dactylus usually about half as long as the propodus.
Pleon broader than long. Uropoda short, rami cylindrical,
spiny at the tip; the outer more slender but not shorter than
the inner. Length of body 45mm. Carpus of first pair 1mm. ;
propodus 0°6mm.; of second pair, carpus 1‘5mm., propodus
‘6mm.; of fourth pair, carpus 15mm., propodus 1‘7mm.
Color, in alcohol, pale honey-yellow.
This species was dredged in 220 fathoms, in the Gulf of St.
Lawrence, by Mr. J. F. Whiteaves.
Aigathoa loliginea, sp. nov.
Body elongate oval, not suddenly narrower at the base of
the pleon, which is slightly dilated at the last segment. Head
passi1 2
nearly alike throughout, first pair a little more robust, last pair
slightly the longest, all with strongly curved dactyli. Pleon
longer than the thorax, tapering to the fifth segment. First
pair of pleopoda with the basal segment large, nearly square;
last pair, or uropoda, surpassing the telson; basal segment tri-
angular with the inner angle acute but scarcely produced ; ram
flat, the outer with slightly divergent sides, chiiansl y rounded
at the end; the inner broader, triangular, with the outer side
longest ; cilia very short almost rudimentary. Length 13mm.,
breadth 86mm. Color in alcohol yellowish with minute black
specks, most abundant on the pleon. ac
The only specimen in the collection was obtained by Mr.
S. F. Clark, at Savin Rock, near New Haven, from the mouth
of a squid (Leligo Pealit), whence the specific name.
Ptilanthura, gen. nov.*
Antennul with the flagellum remarkably developed, multi-
articulate, second and Slow segments provided with a
incomplete, dense whorl of fine slender hairs. This whorl is
interrupted in each segment upon its internal or anterior side,
* From rriAév a plume, and Anthura. :
O, Harger—Isopoda from New England. 377
. . NOV.
broadest at the base of the pleon. Head broader but shorter
than the first thoracic segment, narrowed to a point in front and
less acutely behind. Eyes prominent, black, within the margin
of the head. Antennuls, when reflexed, attaining the third
thoracic segment; first segment large but not longer than the
second ; third shorter than the second, followed by a short first
flagellar segment, second and following segments about twenty
im number, obconic, fitting into each other, flattened and naked
on one side, which is the outer and somewhat inferior side in the
reflexed organ, densely elongate-ciliate distally, except on the
flattened side ; cilia attaining about the fifth following segment.
Antenne hardly surpassing the peduncle of the antennule,
eight-jointed. Maxillipeds with a quadrate basal segment, emar-
pete externally for the subtriangular external lamella, and
earing a single scarcely smaller terminal segment, truncate and
ciliate at the tip. Thoracic segments slender, margined, the
seventh but little over half as long as the others, First pair
of legs moderately enlarged, segments well separated, dactylus
Strong, shorter than the inner margin of the propodus; remain-
ing pairs of legs slender. Pleon about as long as the last three
_ thoracic segments, first five segments consolidated along the
median line, each rising into a low broad tubercle on each side
of the median line; last segment as long as the preceding five ;
telson elongate-ovate obtusely pointed. Uropoda equaling the
telson. Length 11mm., breadth 0°9mm., color in life brownish
and somewhat mottled above, lighter below.
This species has been found on the New England coast
from Noank Harbor, Conn., to Casco Bay, Maine.
Paraianais algieola, sp. nov.
Tanais filum Harger, Rep. U. S. Com. Fish and Fisheries,
part 1, p. 578. 1874, non Stimpson. _
Eyes conspicuous, black, plainly articulated, larger in the
males, Antennule in the females three-jointed, tapering,
Setose at the tip, first segment as long as the last two which
are subequal ; elongated and eleven-jointed in the male, the
first segment long, curved upward near the base, last eight
segments with olfactory sete. Antennw short, five-jointed,
deflected, fourth segment longest. First pair of legs robust,
hand short and stout in the female, digital process scarcely
toothed, bearing three sete near its inner margin; hand in
males strongly chelate, digital process elongated, curved, two-
toothed; dactylus curved, slender, with about seven setiform
Spines on its inner margin ; carpus in the males long and stout.
378 0. Harger—Isopoda from New England.
Second pair of legs elongated, basis flattened and curved, dac-
tylus slender but shorter than the propodus. Bases of last
three pairs of legs swollen. Uropoda bearing sete at the tips
of the segments, biramous; outer ramus short, scarcely if at all
surpassing the basal segment of the inner ramus which is six-
jointed and tapering. Length 2°2mm., breadth 0.83mm. Color
nearly white.
his species is rather abundant among eelgrass and alge
at Noank an oods-Holl, and probably other localities on
the southern shore of New England. I formerly considered it
as identical with Zanazs filum Stimpson and supposed its range
to extend as far as the Bay of Fundy. I now regard that as
error, as it is probable that 7. filum is a true Tanais with
simple uropoda, though I have as yet seen no specimens from
the Bay of Fundy, nor any fully answering to Stimpson’s
description.
Paratanais limicola, sp. nov.
long as the third. The dactylus of the second pair of legs,
with its slender, acicular, terminal spine is longer than the
propodus. The pleon is not dilated at the sides. The uro-
poda have the outer ramus two-jointed, slender, and surpass-
ing the basal segment of the inner ramus which is five-jointed,
peas the basal segment long and imperfectly divided. Length
‘Smm.
This specie was obtained on a soft muddy bottom in forty-
eight fathoms, Massachusetts Bay, off Salem, in the summer
of 1877, by the United States Fish Commission.
the antenns, basal segment subquadrate, hand or propodus less
robust than the carpus; digital process of Saobia
dactylus short. Second (first free) thoracic segment two-thirds
as long as the third, which is equal to the fourth and fifth ; sixth
and seventh progressively shorter. Second pair of legs scarcely
more slender than the following pairs, basal segment not curv:
M. C. Lea—Ammonia-argentic Lodide. 379
ing around the basal segments of the first pair. leon six-
jointed; uropoda short, biramous, each ramus two-jointed, the
outer more slender than the inner, half its length and bearing
a long bristle at the tip. Length 25mm. - |
This species was taken along with P. dimicola and unfortu-
nately only a single specimen is as yet known,
Yale College, April, 1878.
Art. LVL.—Ammonio-argentic Iodide ; by M. Cary Lexa.
WHEN silver iodide is exposed to ammonia gas it absorbs
3°6 per cent, and forms Bets to Rammelsberg a compound
in which an atom of ammonia is united to two of Ag] Liquid
ammonia instantly whitens AglI, every trace of the strong lemon-
yellow color disappears. The behavior of the ammonia iodide
under the influence of light differs singularly from that of the
plain iodide, and will be here described.
The affinity of AgI for ammonia is very slight. If the
white compound be thrown upon a filter and washed with
water, the ammonia washes quickly out, the yellow color re-
appearing. If simply exposed to the air, the yellow color
returns while the powder is yet moist, so that the ammonia is
held back with less energy than the water. So long, however,
e€ ammonia is present, the properties of the iodide are
entirely altered.
Agl precipitated with excess of KI does not darken by ex-
posure to light even continued for months. But the same
iodide exposed under liquid ammonia rapidly darkens to an
intensé violet-black, precisely similar to that of A
to light, and not at all resembling the greenish-black of Agi
exposed in presence of excess of silver nitrate. (This differ-
ence no doubt depends upon the yellow of the unchanged AgI
mixing with the bluish-black of the changed, whereas in the case
of the ammonia iodide the yellow color has been first destroyed.)
the exposure is continued for some time, the intense
violet-black color gradually lightens again, and finally quite
disappears, the iodide recovers its original yellow color with
perhaps a little more of a grayish shade. This is a new reac-
tion and differs entirely from anything that has been hitherto
observed. It has been long known that darkened AglI washed
over with solution of KI and exposed to light, bleached. This
ast reaction is intelligible enough for KI in solution expo
washed well with water (during which operation it passes
380 M. C. Lea—Ammonia-argentic Iodide.
from violet-black to dark-brown), and may then be exposed
to light either under liquid ammonia or under pure water, in
either case the bleaching takes place, though in the latter case
more slowly.
If the experiment be performed in a test-tube, the bleaching
under ammonia requires several hours, under water from one
to three days. But if the iodide be formed upon paper, and
this paper be exposed to light, washing it constantly with
liquid ammonia, the darkening followed by the bleaching
requires little more than a minute. In this case, however, the
depend hee the escape of ammonia, for if the darkened am-
monia iodide
washed with water, and this water gave distinct indications of
iodine. The iodine present is in so small quantity that it may
easily be overlooked, but it is certainly there. The washing
given to the AgI was so thorough that it seemed impossible to
admit that traces of KI remained attached to the AgI, but in
When Ag! is blackened under ammonia in a test-tube, and
the uncorked test-tube is set aside in the dark for a day or two,
the AgI assumes a singular pinkish shade. It thus appears
that AgI under the influence of ammonia and of light gives
indications of most of the colors of the spectrum. Startin,
ays, seem to give hope of
te method of heliochromy-
ae
J. A. Allen—Fossil Passerine Bird from Colorado. $81
Art. LVI.—Description of a Fossil Passerine Bird from the
Insecthearing Shales of Colorado; by J. A. ALLEN.*
THE species of fossil bird described in this paper is based on
some beautifully preserved remains from the insect-bearing
shales of Florissant, Colorado. They consist of the greater
part of a skeleton, embracing all of the bones of the anterior and
posterior extremities, excepting the femora. Unfortunately,
the bill and the anterior portion of the head are wanting, but
the outlines of the remainder of the head and of the neck are
distinctly traceable. The bones are all in situ, and indicate be-
yond question a high ornithic type, probably referable to the
Oscine division of the Passeres. The specimen bears also re-
markably distinet impressions of the wings and tail, indicating
not only the general form of these parts, but even the shafts
and barbs of the feathers. Mis
n size and in general proportions, the present species differs
little from the Scarlet Tanager (Pyranga rubra) or the Cedar-
ird (Ampelis cedrorum). The bones of the wings, as well as
the wings themselves, indicate a similar alar development, but
the tarsi and feet are rather smaller and weaker ; and hence in
this point the agreement is better with the short-legged Pewees
(genus Contopus). These features indicate arboreal habits and
well-developed powers of flight. The absence of the bill ren-
ders it impossible to assign the species to any particular family,
a the fossil on the whale gives the impression of Fringilline
affinities,
Paleospiza beila, gen. et sp. nov.
Wings rather long, pointed. Tail (apparently) f about two-
thirds the length of the wing, rounded or graduated, the outer
feathers (as preserved) being much shorter than the inner.
ne side shows distinctly six rectrices. Tarsus short, its
length a little less than that of the middle toe. Lateral toes
subequal, scarcely shorter than the middle one. Hind toe
about two-thirds as long as the middle toe. Feet and toes
strictly those of a perching bird, and the proportionate length
of the bones of the fore and hind limbs is the same as in
ordinary arboreal Passeres, especially as represented by the
Ta nagride,
* From the Bulletin of the Geological and Geographical Survey of the Terri-
tories, vol. iv, No. 2, page 443, April, 1578. : coe ee
The character of the tail is given with reservation, since it is not Lm te cer
tain that the whole of the tail, or that the exact form of the ne Pe ion, 18
shown, especially as the preserved impression is somewhat unsymme
.
382
J. A. Allen—Fossil Passerine Bird from
Colorado.
J. A. Allen—Fossil Passerine Bird from Colorado. 388
One of the specimens affords the following measurements :
Inches. Inches.
Humerus, length. .-..--.. 0°80} Middle toe and claw-_-..-- 0°6
Forearm, length....--- . 0°95 | Claw alone AG: 020
Manus, length --....----- 1°02 | Hind toe and claw-..---- 0°37
Coracoid, length---- .---- 0°72 | Claw alone Fie IS
Clavicle, length_--.--.--- 063; Wing .2css ue cl ol) 80
een, WenOth. 22 sce 1:00 | Tail (approximate) -....... 2
mareus, length. .: ... 2... 0°60 | Total length (approximate) 6°85
The bones still rest in the original matrix, and, being some-
what crushed and flattened, do not admit of detailed descrip-
tion and comparison with other types. e furculum is well
Another specimen from the same locality, and probably
representing the same species, consists of the tip of the tail
and about the apical third of a half-expanded wing. (Fig.2.) In
The larger specimen, first described, is divided into an
upper and a lower half, the greater part, however, adhering to
884. J. A. Allen—Fossil Passerine Bird from Colorado.
the lower slab. The bones adhere about equally to the two
faces. The drawing is made from the lower slab, with some
of the details filled in from the upper one. The feather im-
pressions are about equally distinct on both, and where in
either case the bones are absent, exact molds of them remain,
so that the structure can be seen and measurements taken almost
equally well from either slab, except that nothing anterior to
the breast is shown on the upper slab.
The species here described is of special interest as being the
first fossil Passerine bird discovered in North America,
Professor O. C. Marsh in 1872, from the Lower Tertiary of
Wyoming Territory. Probably the insect-bearing shales of
Colorado will afford, on further exploration, other types of the
higher groups of birds.
For the opportunity of describing these interesting specimens
I am indebted to Mr. S. H. Scudder, who obtained them during
Professor O. C. Marsh in 1870,* who refers to it as “the distal
portion of a large feather, with the shaft and vane in excellent
preservation.”
*This Journ., II, vol. xi, p. 272, 1870.
W. L. Broun—Terrestrial Electrical Currents. 885
Art. LVIII.—Experiment for Illustrating the Terrestrial Elec-
trical Currents ; by Professor Wu. LERoy Brotn.
THE following experiment enables a lecturer to exhibit to a
large audience, in a very simple way, the action of the currents
of electricity that pass around the earth. The experiment was
suggested on reading an article by Professor om
in the Philosophical Magazine for November, 1877.
section three by two centimeters, whose sides were in length a
fraction over a meter, and in breadth three-fourths of a meter.
About the perimeter of this rectangular frame were wrapped
twenty coils of insulated copper wire: each extremity of the
wire was made to terminate near the center of one of the
shorter sides, and passing through the wooden frame was
fastened and cut off about three centimeters from the frame.
This rectangular frame was then so suspended, in a horizontal
position, by wires attached to the frame of an ordinary hydro-
static balance, that the longer sides were at right angles with
the beam. By adjusting weights in the pans the index of the
balance was brought to the zero point. Two small orifices
bored in a block of wood, a centimeter apart, served as
When the current was reversed the deflection was in the oppo-
site direction. By breaking and closing the circuit at proper
intervals to augment the oscillations, the large frame was readily
made to oscillate through an arc of five degrees. When the sides
of the rectangle were placed northeast and southwest the current
produced no sensible effect. A bichromate of potas
of sixteen cells with plates of zinc and carbon, twenty-five by
Six centimeters, was used. a
With a rectangle containing a larger number of coils of
Wire, attached to a very delicate balance, by using a consfant
acting battery, the variation in the magnetism of the earth
might thus be advantageously observed.
386 Scientific Intelligence.
SCIENTIFIC INTELLIGENCE.
I. CHEMISTRY AND PHysics.
1
the naked eye distinctly prismatic, often aggregate in dendritic
masses of the color and luster of steel.
0 by
sulphur, and burns readily in a current of chlorine formmg the
chloride. On analysis, the metal gave of beryllium 87-09 per cent;
between 0° and 100° C. As the result of four experiments, the
specific heat of pure beryllium was obtained as 0°4107, 0°4144,
t
=. be
if the atomic weight be assumed as 13°8, it follows that beryllium
belongs, not to the magnesium group, but to that of aluminum,
that its atomic weight is 13-8, its specific heat 0°4079, and that
llium oxide is Be,O, as Berzelius claimed.— Ber. hem.
18
Ges., xi, 381, March, 1878, G. F. B.
2. On a new is of nes.—ErEekorr has succeeded in
effecting a new synthesis of hydrocarbons of the general
ath yy ng together for seven or eight hours molecular
>
: m
which aiatillcd sompletcte between 36° and 85°, consisted to t
70° to 83°. This fraction combined energetically with bromine,
yielding a solid compound fusing at 139°-140°, volatile with par-
tial decomposition, and having the formula C,H,,Br,. 0 wit
uric acid, a liquid and a solid body separating out on dilu-
Chemistry and Physics. 387
tion, the latter having a characteristic camphor-like odor, easily
volatile in a current of steam, crystallizing from weak alcohol
at 75°-76° and ing the formula
xi, 412, March, 1878
3. Tr
wh | . : :
a C=O. On boiling the bromide with water, a crys-
4 .
tallized acid was obtained, which was bromacetic acid. Tribro-
minated ethylene also absorbs oxygen under similar conditions,
and yields dibromacetyl bromide.—Bull. Soe. Ch., Il, xxix, 204,
arch, 1878, : G. F. Be
4. Ona Remarkable Reaction of Boric acid and Borax with
poses car j
above named polyatomic alcohols in solution, be mixed with
solution of boric ‘acid, so dilute that it no longer reddens litmus,
h . .
388 Scientific Intelligence.
his experiments to test the extreme delicacy of the boric acid
reaction. If one cubic centimeter of a solution iF ot acid
gg percept poe — to test paper) be mixed with 10 c. ¢. of a
5 per cent solu of mannite, a strong acid cg is de-
slips turning tients paper onion-red at once. A yyy, solu-
tion of borax, which is neutral, when 2 ¢. c. are mixed with 10 ¢ ¢.
7. the mannite solution, ie a bright-red at once. Five c. c. of
& typ 000 SOlution added to 5 c. c, of the mannite solution, gave a
decided acid reaction at Wire end of a minute. Quantitative ex-
periments showed that the alkali required to neutralize the acidity
roduced, was the exact quantity needed to form the mono-
metaborate.— Bull. Soc. Ch., Il, xxix, 195, 198, March, i
. B.
5. On the Products of the Distillation ow, Resins a resin
Acids with Zine dust.—Ctamictan has studied the products
From 600 grams abietic acid, 250 cubic a ds of distillate
were obtained, which on fraction ning, gave toluene, metaethyl
methyl-benzene, naphthalene, methyl-naphthalene, and methyl-
anthracene. Colophony itself, when iis distilled gave the same
products, and in about the same proportion with the exception of
toluene, which was present in much smaller quantity. On istill-
ing gum-benzoin with zine dust, toluene, xylene, naphthalene,
and a ehehaene were obtained.— Ber. Berl. yes te
xi, 269, 878.
oily body, having the formula C “HO, fo fo .
stance with alkalies, and boils at 285°. Treated with acetic
oxide, it t yields an acetyl derivative C pH (CH.O0. which =
bromine gives a bromo-compound ©,,H,,Br,(C,H,O)O,. Hea
to 130° with hydrochloric acid, torrents 8 of. methyl chloride pe
evolved, and a crystallized body is obtained hav ving the formula
C,H,,0,. This Sancapie regan as a higher homologue of pyro-
an ¢ OH
gallic acid, thus C,H, one the methyl derivative C,,H,,O, be
OCH, OCH,
ing C,H, . OCH, and its acetyl compound ©,H,4 OCH, . Since
: OH OC,H,0
Chemistry and Physics. 389
propylated trioxybenzene, or dimethyl propyl-pyrogallate. On
O, and thie on reduction a
hydroquinone C, » § The th
wood tar was isolated with difficulty and had the formula
affording a crystallized substance of the formula C,H,O,, which
was pyrogallic acid (pyrogallol).
was the dimethyl ether of pyrogallic acid C,H, OCH,. By the
action of oxidizing agents, most conveniently potassium dichro-
mate, it is converted into the magnificent steel-blue needles of
cedriret. In proof of this as the origin of the cedriret of Reichen-
bach, Hofmann prepared this dimethyl ether synthetically and
found that it gave identically the same product on oxidation,—
Ber. Berl. Chem. Ges., xi, 329, Feb. 1878. G. F. B.
. he Constituents of Corallin——ZvuLKowsky has ex-
amined the corallin of commerce and finds it to be a mixture of
at least six different bodies: 1st, a coarsely crystalline garnet-red
body with blue luster, of the composition C,,H,,0, ; 2d, a deriva-
this, a deep red amorphous powder, showing metallic luster, re-
8. On Curarine.—Sacus has examined the active substance of
curare and finds it to be an alkaloid of the composition C,H,
Ww
Am, Jour. Sc1.—THIRD ——” Vou. XV, No. 89.—May, 1878.
390 ; Screntifie Intelligence.
while the water obtained from the steam is perfectly potable. M.
Hétet gives evidence that his method has been thoroughly tried
with entire success.— Ann. de Chim. et de Phys. (5), xiii, 29.
J. P.O, TR
9. Boracie Acid.—M, Avrrep Drrre (Ann. de Chim. et Phys.,
(5), xiii, 67) has made some new determinations of the “heat of
solution” of boric hydrate, and also of the “heat of hydration”
of boric oxide, which have led to remarkable results, It appears
€
units of heat, and that one equivalent (35 grams) of boric oxide
(fused boracic acid) in combining with water absorbs 6254°7
the heat was dissipated, the temperature of the mass would
raised t itte finds that for the specific gravity of
O1
mined the corresponding values for boric hydrate.
At 0° 6=1°5463 Between 12° and 60° &=0°00154
12 12° and 80° &=0°00148
Further, it appears that the mean density of the boric oxide
and ice, which may be regarded as united in the hydrate, is
siti while that of boric hydrate at 0° is 1:5463, ‘There must,
Chemistry and Physics. 391
would be 136° and the amount of heat absorbed 2982-2 units.
Evidently then less than one-half of the heat of hydration is due
to this cause. M. Ditte has also determined the solubility of
e
thermometer, but it was found possible to simplify very greatly
the details of the process without seriously impairing the accu-
ble investigation of the boiling point of s at different
emperatures, the observations of temperature are undoubtedly
accurate to this extent, but Regnault’s own n of these
own more accurately; for even when withim the range of a
mercury thermometer an observation of a g point to be
accurate to a tenth of a centigrade de attentio
The glass thermometer bulb used in our bi sc age is repre-
sented in the accompanying figure of one-hal the
‘its linear dimensions. The longer stem was made of fine ther-
mometer tube, and a shorter stem was added to the opposite end
of the bulb in order to facilitate the cleaning, drying, filling, or
emptying of the interior—all of which was easily accomplished
by the aid of a Bunsen pump. The shorter stem was of course
sealed after the bulb Kad been dried and made ready for use, and
before it was immersed in the medium whose temperature was to
measured. After an equilibrium had been established at this
unknown temperature T°, the protruding end of the longer stem
892 Scientific Intelligence.
was sealed, and at the same time the height of the barometer H
was noted. The bulb was then taken to a room of uniform tem-
perature provided in the laboratory for gas analysis, and after
being mounted on a convenient support, the end of the stem was
broken off under mercury, and the apparatus left to itself for a
time to secure a perfect equilibrium of temperature. This tem-
perature (T’°) was then observed by means of a standard ther-
mometer hanging near the bulb; also the height (h) to which
the mercury had risen in the bulb was measured by a cathetom-
eter, and in addition the height H’ of the barometer (hanging in
the same room) was again noted. Closing now the open stem
with the finger, the bulb was quickly inverted and the pistes |
mercury drawn out into a tared vessel and weighed (nipping o
the end of the shorter stem in order to admit the air). Thi
T?+273°2=(I"°-4-273°2) alr —T')°k}.
It will be noted that as the mercury columns, including the
heights of the barometer, were all measured at the same constant
temperature, and, as we are dealing with relative values only, no
reductions are necessary. Moreover, an error of one-tenth of a
millimeter in the value of Hy Would make in determining the
boiling point of sulphur (448°) a difference of only one-eighth of
a degree, so that measurements of these heights are sufficiently
close if accurate to one-half a millimeter, and might even be
ith a common rule. The most uncertain element in the
formula is the expansion of glass, but if the bulbs are made of
flint glass (lead glass) tubing, such as is used for ornamental
glass 8 to soften. e rate of expansiou of flint glass is not
only less than that of crown, but it is also more constant and
pared with the results of Regnault reduced to the corresponding
pressures :
Chemistry and Physics. 393
Boiling Point of Sulphur.
Barometer.
Height at 0°. Bennett. Regnault. Diff.
758°8 :
A verage difference, 05
ing as ‘alee the two ester e or the poo we obtain
values for the boiling point of sulphur differing by more than a
degree, and hence, as we have already said, there is still an
evident, Mr. Bennett’s observations confirm very closely the inter-
y ourselves, but since the boilin point of sulphur has become
such an important constant we propose to have the observations
repeated under the most favorable condita we can comman
After the accuracy irae ur method had been thus placed be-
yond doubt within the limits require d, Mr. Bennett made three
dete: ee herpeeeie i the boiling point of antimonious iodide with
the follow resu
tise Height at 0°. Boiling Point SbI;.
758-1 millimeters. 400-4
T1584 400°-9
401°-9
159°3
Proba bably only ae sal art of the differences between ee
observations depends on the variations of pressure, and 401
the nearest whole eh of degrees to the neenne point of so
Monious iodide at the normal pressure of the
*This Journal, II, xiv, 484
394 Scientific Intelligence.
The method we have here described we can most confidently
recommend as a most efficient and accurate means of determining
J. C. P., JR.
11. The Influence of the density of a body upon its ‘Light-
ries -
bing power.—Professor Guan has conducted a se ot ex
any change of absorption with change of density that it must be
very small. He is inclined to think that his results give evidence
varies greatly
85° the effects are very faint; between 75° and 60° they are com-
t
the analyzer from extinction, and so forward.
subject to exceptions.— Phil. Mag., March, 1878, p. 161
he Velocit i
A. Micuetson, Ensign U. S. Navy, Instructor in Physics and
sak
any distance. the figure, S is a division ore scale ruled on
ed M, a revolving plane mirror; L, an achromatic lens; 8", 2
xed plane mirror, at any distance from :
The point S is so situated that its image §’ reflected in the mir
Geology and Mineralogy. 395
ror M, is in one focus of the lens L, while ine image of S' oe
cides with the mirror 8”, which is placed at the conjugate foc
With this arrangement, when M turns alomty, the light from S” is
reflected back through the lens, so that an image is formed —
coincides with S. en, however, the mirror rotates rapidly,
the position of M will — changed ‘while the light travels from
M to 8” and back again, so oes the image is displaced in the
eh of rotation of the mirr
L
s! s
Let iy; be the ranma d of light; D, twice the distance M 8”; n,
the number urns per second; 7, the distance M S and 6 the
4nrn
é
deflection ; then V is found by the formula V=
In a preliminary experiment the deflection amounted to five
millimeters when the mirror revolved 128 times per second.
IL GroLtoecy AND MINERALOGY.
1. On the Limestones of the Falls of the Ohio, by Jamzs
Hatt. 16 pp. 4to. Advance sheets of vol. ‘v, part 2, of the Paleon-
tology of New York.—Professor Hall reviews the facts with ref-
erence to the beds at the Falls of the Ohio v4 their fossils, gives
the results of personal eS a s at the conclusion
that en —_ include—beginnin -
(1.) Niagara — Ty _ Upper Silurian, which are the “ Cate-
nipora beds” of S$. 8
(2.) Upper Helderbe deni to which bel ong the next follow-
ing strata, (a) Coral sh (6) Turbo bed, (c) Nucleocrinus bed,
d (d@) Spirifer bed, of Lyon.
“@) — 30 feet of Hamilton beds, which are of impure mag-
limestone, and comprise a the Hydraulic limestone, and
the Encrinital limestone, of Lyon.
(4.) The “ Black Slate,” which, after a special discuss sais of the
ous intercalations a “ shales at its base, thins ree a
—— the
396 Scientific Intelligence.
2. Report on the Fossil Plants of the Auriferous Gravel
Deposits of the Sierra Nevada; by L. Lesquerrvx. Memoirs
of the Museum of Comparative Zoology at Harvard College.
Vol. vi, No, 2. 58 pp. 4to, with ten double plates. — Professor Les-
quereux here describes fifty species, and gives figures of the leaves
on which they are based. He concludes:
(1.) The species are related by some identical or closely allied
forms to the Miocene, and still more intimately by others to the
present flora of the North American continent.
(2.) The North American facies is traced by some species to the
Miocene, the Eocene, even the Cretaceous of the Western Territo-
vies. Hence it is not possible to persist in considering the essen-
tial types of the present North American flora as derived by
migration from Europe or from Asia, either during the prevalence
the Miocene or after it. This flora is connatural and autoch-
quent to the Glacial period. is remarkable fact, so clearly dem-
onstrated by nature, may serve as an exemplification of the causes
os the disconnection of some of the other groups of our geological
oras.
_3. Memorandum of a fossil wood from the Keokuk formation
Keokuk, Iowa ; by Samuxt J. Watuace, of that place.—A por-
i kuk
tion, Subcarboniferous, at Keokuk, Iowa, March 6th, 1878. age
a section nearly three feet long; one end disappearing in
external or bark markings, but rather those of woody fiber, possi-
from the best quarry layers of the Keokuk Formation, five feet
i d,” and from the center of a solid 18-inch
> layer, on a horizon of numerous shells, fish teeth, etc.
Is not this among the first distinct land plants from this forma-
tors.
tion ?—From a letter to the Edi
_4, Atlas accompanying the Report of the Geological Explora-
tion of the Fortieth Parallel ; by ga ont Kiva, U.S. Geologist
Geology and Mineralogy. .
in charge. Made by authority of the Hon. Secretary of War,
under the direction of Brig. and Brevt. Major-General A. A.
Humphreys, Chief of Engineers, U.S. A. 1876.—One of the maps
of this Atlas has already been noticed in this Journal in volume xi
(page 161). The completed atlas has recently been issued. It is
top
region nearly fifty miles wide either side of the fortieth parallel from
western Nevada to eastern Colorado. e atlas is a grand con-
tribution to the Geology of the continent, and bears testimony to
the very great care and thoroughness of the surveys under Mr.
King. The five colored geological maps present not only the
distribution of the several areas of igneous, granitic, and stratified
trac
the study of which in the field, by Mr. King, has been supple-
mented by the exceedingly valuable volume of descriptions by
Professor Zirkel, forming part of the Reports of the Survey.
The plates are from the establishment of J. Bien, New York,
sage land, coal land, gold districts and silver districts; a general
geological map; six sectional geological maps, and as many topo-
graphical, on a scale of four miles to the inch; two maps of geo-
logical sections and one of panoramic views. e areas of the
memoirs, representing the following species: ©. pune
Wariolars, é. ‘illatedleis, C. obtusus, C. levis, C. vigilans, C. sex-
costatus, C. nereus, and C. verrucosus. The limits of the genus
are those accepted by Eichwald in 1840. It includes Enerinurus,
and Cybele and Atractopyge are made subgenera under it.
$98 (tix Scientific Intelligence.
ra garteutfanes and Upper Silurian fossils of Illinois and
Indiana,—Dr. C. A. Waite has published descriptions of some
invertebrate ore in the Proceedings * oe Academy of Natu-
ral Sciences of Philadelphia for it p. 2
ate naib - Ostrauer und Walden burger Schichten
von D. 366 4to.—An ok Arne memoir on the fossil
gow es the: Lower Carboni iferous formation of Moravia, illustrated
a large and beautiful plates, a map, and two plates
ot secti The lower Culm includes av oe rboniferous lime-
stone with Productus giganteus Sow. rring in Altwasser,
Neudorf near Silberberg, Hausdorf, ete., natn which ihe 4 Culm-
Dachschiefer,” containing Posidonomya Becheri Br. is equiva-
lent; and the upper Culm, the Ostrau and Racvncaes shales,
Ome of the specimens of plants figured are of remarkable size
and os pa
of the Musk Ox (Ovibos moschatus) have been
found in she. less of the Rhine near Unkel, according to F.
mer.—Zts. geol. Ges., xxix, 592.
10. Notice of three new Phosphates ease py co
Connecticut ;* by Groren J. Brusu and Ep
(1). Eosruorrre, Usually observed in pileipatis a am
obtuse angle measures 1044°, and which probably belong to the
orthorhombic system. The crystals are uniform rmly terminated by
two pyramids in different vertical zones. —- maacesling nee
nearly seers Also commonly — mass Hardness
ated Al,O,: RO: 10 = 1 1:2 saa Th
corresponds to the ¢ empirical formula 0.) 40,0:
ee oe The compact v eae tain quartz an and other
is of a whitish compact specimen by Horace
me | Wells som 14°41 of insoluble ee and the remainder
= oT atomic ratio of eosphorite.
2.) TRrrprorprre, Occurs in erystalline a tes whose struc
ture is parallel-fibrous to arm also di onda and again con-
fusedly fibrous to nearly co mpact massive. Isolated prismatic
erystals are occasionall ahead imbedded in quartz. Inv
- cases these crystals have been detached with their termina-
ons preserved; the crystallogra hie data thus obtained show
that the mineral is ere related in form to wagnerite. Hard-
* Communicated by the A:
Geology and Mineralogy. 399
ness=4'5-5,. Specific gravity=3°697. Luster vitreous to greasy-
adamantine. Color yellowish to reddish brown, the crystals -
occasionally topaz- to wine-yellow. Transparent to translucent.
Fuses in the naked lamp-fiame, and B. B. in the forceps colors the
flame pale green. Completely soluble in the fluxes, giving reac-
tions for iron and manganese. uble in nitric and hydrochloric
acid. Analyses by 8. L. Penfield have proved it to be a hydrous
eee of manganese and iron, giving the atomic ratio of
?,0,: RO: H,O of 1: 4:1. This corresponds to the formula
R,P,0,, H,O=R,P,0,+H,RO,. The mineral in external charac-
ter has a marked resemblance to triplite, and this fact is expressed
in the name which has been given it
NSONITE curs foliated massive; often lamellar
radiate, the laminw being sometimes straigh t more often
rv ne instance observed in tabular crystals with stri-
Before the blowpipe in the forceps fuses at 1 to a black magnetic
globule, and colors the flame pale-green with an occasional faint
tinge of red ith the fluxes gives reactions for iro an-
¥ the
nese, Soluble in acids. The chemical i now in progress
y S. L. Penfield indicates it to be a hydrous phosphate of iron and
manganese with alkalies, the spectroscope showing the presence
of both soda and lithia. ‘ 5
The above species are from a deposit of manganese minerals in
avein of coarse albitic granite which has been quarried for mica.
Associated with them is a considerable amount of a ferriferous
ganese; all these apparently are products of the oxidation of the
her minerals. e have also determined the presence of vivi-
anite, hebronite, apatite, and some other phosphates whose com-
position needs further investigation before a final conclusion in
the ne sles, y
iade. wi Wi d all the facts in regard to
made, with sone still in progress, an i a ttake alle
11. Mineralogy: Vol. 1, The General Principles of Mineralogy :
by J. H. Gece F.G.S. 206 pp. 8vo. New York, 1878. (G. P.
400 Scientific Intelligence.
properties of minera system of Miller, is principally <a
in the chapters upon crystallography, shovgh the symbols o
mann are also given value s portion of the wena is
III. Botany AND ZooLoGy.
1. Synoptical Flora of North America ; by Asa Gray.—The
first part of this work is expected to be published before May-
day. Tt will form a bound eee of itself, with index, ete.; but
it is only the first part of vol. i p biieation begins» ith
vol. ii, because it takes up the sledilick Flora w the Flora of
North America by Torrey and Gra ray — ns five and thirty
n
the first volume of the new wor e present publication in
cludes all the es Seine after Composite, and fills over 400 com
pact imperial 8vo pages. The price is fixed so as barely to recover
the cost of the edition. For this sam ($6), it will be sent by mai
to any part of the United States, post-paid, if ordered from the
or of Harvard University Herbarium, Cambridge, Mass.
In the trade it is published by Messrs. Ivison, Blakeman, Taylor
& Co., New York.
2. Biblioyraphical Index to North American Botany ;
Citations of pees all the Recorded Indigenous and Nat
uralized Species of the
siblice ra ra as in similar instances. ian be recompensed only by
the consciousness of having done "useful work, won helpful to
fellow-laborers and those who are to come after them. The Sec-
retary, in his advertisement, states that this work “is eager
_by the Smithsonian Institution, at the request of the leading bot-
Geology and Mineralogy. 401
anists of the United States, who have also contributed to the
expense of its preparation.” But the contributions must have
been few and of comparatively small amount, while the labor has
been protracted.
The portion now issued covers the ground of the first volume
of Torrey and Gray’s Flora of North America, i. e. of je fh ate
petalous pe and ve therefore be regarded as a com-
plete portion or volume. It is very pe a bibliography, but
taking might suffice ; but it is a critical ovat and re-Investiga-
into strong cloth binding; and that these may be obtained, from
me curator of the Ha ae University Herbarium, at the addi-
thre
ot the bibliography of the subject. bhe placenta of Primulacee
is con cluded to be “a direct prolongation of the receptacle or
Trane The forms ee Be are cla — under eight re. sr
lent kinds, five of which we — nnaiee ies or varieti
of the imbricative; the term convolute ( n place of contorted) is
this + Se, the degrees of frequency of the various kinds are
indicated; the mode in w whiall they may pass into each other is
speculated upon
shown ; their origination under evolution with
402 Scientific Intelligence.
ingenuity ; the cruciferous flower is conceived to have arisen by
+ ig metrical —_ of fives to fours, etc. ; the hypothesis that
e corolla o ula is an outgrowth of the andrecium is
controverted, more parsicnlasly on the ground that the develop-
ment of the parts of normal flowers is by no means always cen-
“a tal.
. Floral Structure and Affinities of Sapotacee ; by Maxcus
M. ‘Harroe, M.A., ete.—A short paper in Trimen’s Journal of
Botany, for March, 1878. Observations made at the Botanic
Garden at Peradeniya, Ceylo n, and very neatly cclend out. As
to the ovules, “ the impre sion” is that the ey are the axillary buds
of the carpels. owers almost — 2 gape volu-
from the periphery inwards.” ach new member arises in
front of the widest intervals between the next oldest members.
If the intervals be wide, the new separ are formed in front of
the widest intervals between the members of the next oldest
whorl and those of the next but one, a both falling under Hof-
meister’s generalizations. The order nearest to Sapotacee is Myr-
sinacee ; and Styracacee: (Symplocex: being separated) nearer than
t Berlin. Profe
ee Tibingen, takes the new chair of Physiological uietene: at
6. Curtiss: Nort h American Pilants.—The first part
oe of dried plants of our Southern sep hope species,
ie Yat arg Meri announced a year re ago, 18
issued. t supplied to the Harvard Tecanos Flecbariam
enables us us to anne that the apeniensng are well chosen, copious
and perfect, are carefully put up, all named, with printed tickets
in neat form and taste; and that these sets are cheap at the price,
viz: twenty dollars for 250 species. To favor this laudable enter-
pose and to facilitate their acquisition by botanists, some sets
ave been aclostane at the Harvard University Herbarium, the
Curator of which will receive applications for them.
7. On the Spore-Formation of the Mesocarpew, and Sine of
the» ! trrock.—In the
something like a knee-joint, and divide into three parts, in the
central one of which the spore is formed directly, without conju-
A RG, geo aa aaa
Botany and Zoology. 403
gation. Dr. Wittrock observed a rotation of the chlorophyll-
he 9 are sometimes formed in three different ways, sup-
posed to be cbtadweteniatle of the three different genera, seas
asap" Vicctasaenne and Staurospermum
. Non-Sexual Outgrowths on Fern Prothalli.—The dadkvens
of ee non-sexual production of the Fern-plant from the pro-
thallus, by Dr. Farlow, when a pupil of De Bary at Strasburg,
as been extended to numerous instances. The facts and bearings
of the case were reported to the Society of German N aturalists,
at the late meeting at Munich, by Professor De Bary, as follows :
“Investigation has shown that’ som e Ferns, mi Pteris Cre-
ticu, Aspidium faleatum, and Aspidin m Flix as, var. vris-
tatum , form on the prothalli normal antheridia but apni no
bryo, the: ica described by Farlow. In those ee which
develop archegonia no such outgrowth has been obsery e
thallus, there is formed an axial punctum pi bo ap on which a
second and the successive later leaves appeat. At the base of
the first leaf there is formed, endogenou 7a So the vascular bundle,
the first root. As soon as ei second lea Recing i the bud grows
i ring in reat from
the normal mode of growth are not uncommon. nique tly the
prothalli form branches similar to themselves ( secondary —
oo can Pion sige leaves and shoots in a great variety o
place
Pte pagation, oa pe benod batten suckers, etc. The numerous bulb-
ets of the higher phanerogams, species of AZium, Dentaria and
= like, are fe a s of this, as well as of the successive degrees
of differenc pi ca a 3 Closer observation of the = piers
404 Scientific Intelligence.
9. A Catulogue of the Flowering Plants and higher Cryptogams
owing without cultivation within t “= miles of Yale College.
Published by the Berzelius Society, New Haven, 1878, pp. 72,
8vo, and an outline map.—This i es has reached us barely
in time for announcement here. Its form and typography are
aap and the editors (whose names are not mentioned),
appear to have ioe their work admirably, under the auspices of
Professor Eaton, who adds an introduction, with interesting his-
Lage details. The catalogue extends to the Musei and re mic
the summary of species gives the total number of 1
A. G
IV. AsTRONOMY.
i “ati Sternhaufen x Persei, etc., von Dr. H. C. Voce.
Leipzig, 1878. 4to, pp. 36.—Dr. Vog el, of the Potsdam Observa-
for any pair are Srlgeticat thus: Ist, four measures of p; four
measures of s; 2d, determination of parallel; the next pair is
then observed as follows : Ist, four measures s of P;
of 4 ; 2d, determination of parallel ; and so on throughout the
night.
$2 contains an i ae Te of the position-circle ; and of the
value of the revolution of the micrometer. The zero of “the micro-
aaa stars less t n 10th e were determined from meas-
ures of p and s with four rclecte stars of the group. These four
were connected by and s and also Aa and Ad; and
atee stars of the cluster Perse?,
they were further clase wit
which had been observed with the Bonn meridian-circle. The
Botany and Zoology. 405
pairs of stars were stern alternately on different threads, the
hose of
zeros determined under the same circumstances as t the
coe the position iil easured by turning the circle
in ways. From four to six measures of p and s were made
each’ siotit and for each pair of the brighter stars at least four
nights observations were made, i. e., at least sixteen measures of
pands. The reductions are complete, and the observations are
reduced oe 1870 0.
§ 4 deals with the accuracy re the observations ; for the brighter
stars, the probable error of a si. ngle observation is found to
in 8, “0"228, in p (reduced) +0":306. The probable errors for
within less than 1” in each coérdinate, which Dr. Vogel considers
sufficient for his purpos
§5 treats of the determinations of the brightness of the star.
of this cluster. ptt a stars of the cluster range between the
6°5 and Ae ma
ined by ave estimates of itude 5 times; the pro
able error of the mean is +0714 eerie * the brighter stars
were determined on several evenings e, and on two
Ԥ 6 gives the srl of the stars (in tabular <a ed wig
Results, A difference eniehon the Spring and Aut serva
tions, in Both Aw and Ad, of one of the stars indicates vas peaeivty a
parallax of about 07:3.
§7 gives the Observations of the Fundamental Stars ; and Cat-
alogue of the 30 brightest stars. The observations are of relative
Aa and Ad of the four sage stars, and of two of Arge-
lander’s stars in A Perseé and also meridian observations. These
last also iididate a nb to cand star 6. None of the stars
appear to have a large proper motio
8 deals in the sane ray with Oheeoattorl of the fainter stars ;
and Catalogue of all the stars of the cluster. "This is followed by
two charts, one of the brighter stars and the plan of triangulation,
the other of the whole cluster.
AM. Jour, $c1,—Tuirp — Vou. XV, No. 89.—May, 1878.
406 Scientific Intelligence.
other researches of the author in the sam re all
models of what such investigations should be, and leave nothing
to be desired in methods bservation or reduction, in the u-
E. 8. H.
2. American Journal of Mathematics Pure and Applied.
Published under the auspices of the Johns Hopkins University.
Vol. i, No.1. 4°, 104 pp. Baltimore, 1878.—We are glad to greet
, Hddy, Weichold, Cayley, Rowland, Peirce, Sylvester.
bx two longest articles are b Mr. G. W. Hill, Researches in the
The
S
J
ge
3
a
+
3
oe
mM
Le)
rs)
-
=
<
o
n
eo
o
5
V. MiscELLANEOUS ScIEnTIFIC INTELLIGENCE.
1. Drifiless Region of Wisconsin. (Communication to the
Editors.) —There are one or two sentences in Professor Dana's
paper on the “ Driftless Interior of North America,” in the
°
the theoretical conclusions as to the glacial phenomena of the
en given in volume ii of the Geology of Wisconsin. As
reports themselves, I give, therefore, a brief statement of the
acts. In 1874, Professor T. C. Chamberlin investigated the
already known Potash Kettle Range of Eastern Wisconsin, -
ce
ward again, and carried it to the southern boundary of the district
under my charge. In June, 1875, he furnished me with a map
Miscellaneous Intelligence. 407
on which he had marked the probable position of the continuation
in the Central Wisconsin District. Afterward I verified this and
located the range as mapped in my report; and in studying out
my own observations on the Glacial Drift, found them to harmonize
so thoroughly with his theory that the Kettle Ranges are contin-
uous moraines, that I yielded to his idea and used it in explaining
the phenomena observed in my own district—among them the
existence of the Driftless Region. The honor of the first recogni-
tion of these great moraines as such, and of their great value as
indicators of the positions and size of the various glaciers, and of
glacial movements generally, must be given entirely to Professor
Chamberlin. Should this idea stand the test of investigation, it
will, beyond doubt, lead to some important conclusions.
ROLAND D. IRVING.
2. A Treatise on Chemistry ; by H. E. Roscor, F.R.S. and
C. Scuortemmer, F.R.S., Professors of Chemistry in Owens Col-
lege. Vol. I. The Non-metallic Elements. 769 pp. 8vo ew
sf
also another by J. E. Hilgard, Assistant, on the determinations of
Transatlantic Longitudes of 1872, being the final Report, giving
a review of previous determinations. :
4. Minnesota Academy of Natural Sciences.—The Bulletin
for 1877 contains a catalogue, with notes, of the Mycological flora
of Minnesota, by A. E. Johnson, M.D., occupying 100 pages.
5. Matter and Motion; by J. CLerk Maxwett, M.A., LL.D.,
etc. 224 pp.12mo. New York, 1878. (D. Van Nostrand—Van
ost
and May numbers of Van Nostrand’s Magazine. It is a very clear
Statement of some of the fundamental principles of physics by a
most eminent authority.
6. Contributions to North American Ethnology: Tribes of
California ; by Stpuen Powers. Department of the Interior,
U.S. Geographical and Geological Survey of the Rocky Mountain
Region, J. W. Powell in charge. 636 pp. 4to, with a map and
habits, weapons, implements, etc. Many of
pages of the volume are occupied by vocabularies from various
Sources, edited by Prof. Powell.
Report of the Chief of Engineers for the year 1877. PartsIand IL 1456
Pages, 8yo. 1878.
408 Miscellaneous Intelligence.
OBITUARY.
Dr. Cuartes Pickertne.—Dr, Pickering died in Boston on
the 17th of March, of pneumonia, at the age of seventy-three. He
was a grandson of Col. Timothy Pickering, who was a member
of Washington’s cabinet and one of the most distinguished men of
his day. He was a member of the class of 1823 at Harvard Col-
g was appointed one of the Naturalists of
the United States Exploring Expedition under the command of
ilkes, U. 8. N. ition gave him good oppor-
tunities for pursuing his favorite studies. And these opportunities
for original observation were further enlarged; for, soon after his
return from this voyage, on the 11th of October, 1843, he left for
Egypt, Arabia, India, and the eastern part of Africa, in order to
gam a
th
lished, in 1848, The Races of Men, and their Geographical Dis-
of his own Existence, was only recently completed, and is now
passing through the press. ;
. Pickering was untiring and most conscientious in scientific
research, and of great and varied learning. His works are reposi-
tories of carefully observed facts on the subjects he had laboriously
phan geen along with the conclusions to which he had been led.
a
and was a most genial traveling companion, though naturally
peo. among those with whom he was not familiar.
Fae
ese
sah
APPENDIX.
Art. LIX.—Notice of New Fossil Reptiles ; by Professor
O. C. Marsu.
lent preservation, and among them are several genera, having
the more important characters of the Rhynchocephala, of which
Central ossifications apparently exist in all the Reptilia yet
found in this new fauna, and hence serve to distinguish it.
With this character is another of hardly less interest. The
anterior rib-bearing vertebre preserved have three separate
tubercle. In the implantation of the teeth and their succes-
sional development, these Reptiles resemble the Mosasuria.
Am. Jour. Sot.—Tarrp Series, Vou. XV, No. 89.—Mar, 1878.
a7*
410 O. C. Marsh—Notice of New Fossil Reptiles.
These characters, with others mentioned below, indicate two
distinct families, which may be called Nothodontide and Sphen-
acodontide, from the typical genera here described.
Nothodon lentus, gen. et sp. nov.
This genus of Reptiles may readily be distinguished by the
dentition. In each separate premaxillary there are two slender
pointed teeth. In front of the maxillary there are one or two
similar teeth, followed by a number with narrow transverse
crowns, resembling in form the premolars of some carnivorous
. These crowns, when unworn, have a central cusp,
and on each side a tubercle, somewhat like that on the premolars
of the genus Canis. In the present species the first and last of
the transverse teeth are smaller than the middle ones. The
aengue Of Migiivary bone 2... et Pe coe
Space occupied by ten maxillary teeth ---- .--- -- 55°
Height of crown of second maxillary tooth -_-. -- 14°
Height of crown of third maxillary tooth .-..... 9%
Antero-posterior diameter............---...--. 3
araGaverse diameter cc. ccsci) cco 604m vce-% 8
Antero-posterior diameter of eighth tooth ------- 5
ranavorse Giameter. soci. cn sw. bcs cin eee 15
The present species was about five or six feet in length, and
herbivorous in habit. It was apparently slow in movement,
and probably more or less aquatic. The remains at present
own are from New Mexico.
Sphenacodon ferox, gen. et sp. nov. :
I the present genus the anterior teeth are somewhat like
those of the reptile described above, but the posterior, or more
characteristic ones, are totally different. The crowns are much
compressed, and have very sharp cutting edges, without crenula-
tions. In the present species the carnivorous teeth are crowd
together, and the crowns placed slightly oblique, and twist
The jaws were comparatively short and massive. The rami of
the lower jaws were apparently united. by cartilage only, and
the symphysis was short. The vertebra are deeply biconcave.
Measurements from the type of this species are as follows:
Length of dentary bone: 221 2: os. eee is 1502
Space occupied: by teeth. 3. oi i 130°
Extent of four anterior caniniform teeth... ___- 25°
O. C. Marsh—Notice of New Fossil Reptiles. 411
Height above jaw of second lower tooth ---..--- 16=°
Depth of dentary bone at symphysis. ---------. 26°
Height of crown of compressed tooth..-. ..-. -- 8:
‘Transverse diameter... of o5.cedlcs ages 4°
This reptile was about six feet in length, and carnivorous in
habit. Its remains are from the same locality in New Mexico
that yielded those of Nothodon.
Ophiacodon mirus, gen. et sp. Nov.
Extent of anterior sixteen teeth in dentary -- ----- aa
Extent of anterior five lower teeth .-------------- :
Height of crown of fourth lower tooth ----------- 10
Dep lower jaw at sym PEE Ge +
Extent of seven anterior maxillary teeth 33
Height of crown of first maxillary tooth --.-.-.---- 9
Antero-posterior diameter of crown --------.~----- 3
This species was about as large as those described above, and
is from the same geological horizon in New Mexico.
Ophiacodon grandis, sp. nov.
A second larger species of apparently the same genus is rep-
resented by portions of the jaws, and teeth, and various parts
of the skeleton. In this species the dentary bone is angular at
its anterior extremity, and triangular in section. Its external
surface is rugose, as in the Crocodiles. The crowns of the teeth
are striate at the base, and the latter is furrowed vertically.
The teeth are not so thickly set as in the smaller species, and
the bases of the crowns are somewhat transverse.
Measurements.
Space occupied by ten anterior lower teeth ------- 140™™
Depth of lower jaw at symphysis - --------------- 129°
Antero-posterior extent of symphysis .--.-------- 25°
Depth of dentary bone below seventh tooth - ----- 30°
Width of dentary at this point ------------------ 20°
The present species was about ten feet in length, and the
largest reptile yet found in this fauna. The remains are from
New Mexico.
Yale College, New Haven, April, 1878.
Ry Ont sg
pte!
Bah
ane
Ne ae ae ee
as There
AMERICAN
JOURNAL OF SCIENCE AND ARTS.
[THIRD SERIES]
*
>
Art. LX.— On the Transmission of Sensation and Volition
through the Nerves.* Contribution from the Physical Labora-
tory of the Cornell University; by M. M. Garver, B.S., Pro-
fessor of Natural Science in Mercersburg College, Pa.
_ During the winter of 1875-6 some experiments were made
in the Physical Laboratory of the Cornell University, under the
direction of Professor Wm. A. Anthony, to determine the rate
of transmission through the nerves. The experiments were
continued for a period of several months, during which some
interesting and, as far as the writer’s knowledge goes, new
results were obtained.
screw and worked in a fixed nut; consequently when the
handle was turned the cylinder gradually advanced in the
direction of its axis. The tuning-fork, which was kept in
vibration and regulated by one of Kénig’s automatic break-
Pieces, bore upon one of its prongs a flexible style of brass
which was placed in contact with the blackened paper. Then
when the tuning-fork was set to vibrating and the cylinder
*This arti inci of extracts from a presented by the
author for eheatunc bt ctisk dacleanh commencement of the Cornell Univer-
414 M. M. Garver—Sensation and Volition through the Nerves.
turned, an undulating line was traced spirally round the cylin-
der; each one of the undulations corresponding to a known
interval of time. The base of the tuning-fork was connected
with one wire from the induction coil and the cylinder with
the other, so that when the primary circuit was broken a spark
would pass from the end of the style through the paper to the
cylinder, displacing the lampblack in its passage and leaving a
small dot in the undulating line or trace.
The method of using the apparatus was as follows: the wire
of the secondary circuit connected with the tuning-fork was
conducted to one side and used to give the signals by placing
a short break in the wire in contact with the part of the body
desired, the flesh of the body completing the circuit. The
resistance in the primary circuit was so regulated that th
dots,—the fractions of vibrations being estimated in tenths by
M. M. Garver—Sensation and Volition through the Nerves. 415
In experimenting upon myself the time required to answera
signal given on the left hand, as deduced from one hundred
and nine single observations, was found to be 0°1572’--0009” ;
when the signal was given upon the shoulder, the time e as
obtained from sixty observations, was 0°1482”+--0010". The
difference is 0-009" and the distance, as measured, twenty-three
inches, hence the velocity from the data, was in this case
213° le 28°6 feet per seco
The results can abst best be shown in a table (see table
I.) All the series from which these results were obtained are
not given because they would swell the proportions of this.
article to an undue extent; and also because the establishment
of the reliability of the numerical results obta _ it is
expected, can be shown to be of minor importance.
TABLE I.
Pe Vee mired | Diff Velocity in
posiaenS2 | 5% | anna ot | "me Eooure® | Pimanee) Vege) Vane
Zes signal. answer. time. nerve.
Fowler (1),| 30 | Left foot, |0-1707” ae
0412 33°7
46 | Leté check, ee ee ee
9-1296
Garver (2),) 109 | Left hand, (0°1572"+ 0009") ).o» ‘ :
“i '| 60 |Left shoulder,|0-1482" x-0010"| 0? | 28 1% s13 5356
(3),| 53 | Left hand, |01686"+-0017"| . c,ar| 9; oe ae
- 51 |Left shoulder, 1632" £0017! 01546",; 2] in. | A1sat1T-4
Left foot, |0°1866"+-0014"| | 141.
105 | Left hip, |017557+-0012"| 111 | 36 im 3T0°T + 45
Ol ated oimeumtlt tea 108 0008 | 0130" | 164 in. | 105° +101
cs
=
mo
S
ve
Back, ;
wee po isa" +0010 0098" | 36 in. | 30744476
-1542 By ety :
(| 356 lLattsheulder(o-1saaa¢ 7 | 00003" | 28.tm. |. 6000-7
t will be noticed that the time in (4) and (6) differs con-
sidtersb iy in the two sets of observations, although taken from
the same person. The difference can hardly be owing to errors
in “eee erage for the sum of the — errors is less than
003”, while the differences refe ‘0061’ and 0074”.
There seg evidently a change in the pinch power of the
nerve, or in the mental status of the individual during the
interval of time which elapsed before the last series were taken.
Number (4) was taken Jan. 8th ; number (6) a week later.
Number (7) | gives an extraordina nary result. It is so very
large that it can hardly be regarded otherwise than as erroneous.
Doubtless there was a change in condition while taking the
observations, for all the observations from the hand were taken’
before any were taken from the shoulder, and the fatigue inci-
dent upon taking so large a number of observations is con-
siderable, so pi at can hardly be claimed that the experiments
416 M. M. Garver—Sensation and Volition through the Nerves.
were made under exactly the same conditions. If, however,
the observations had been taken alternately from hand and
shoulder, any change in condition would have affected both
alike, and although the mean time might have increased or
diminished, the differences would not have <i materially
affected. It is unfortunate that the order of the observations
was not stage for then the whole series wold have been
broken up, and the change, if any, detected. This series will
be again referred to hereafter.
Xperiments were also made to determine the relative time
uired for receiving sensations through the eye and ear.
Table II exhibits the results obtained from four different
individuals.
TABLE ITI.
Time from Time from Difference in
Name. “sight to hand.” ** ear to hand.” favor of the ear.
Lee 01628" + 0011’ 0°1327" +0009" 0301"
_ 071793" + 0012” 071359" +0019” 0434"
Gare. oc os 0°1856" + 0015 651" +-0016" 0205”
Wh ove... eue | 071808" + °0035” 0°1364" +-0020" 0444"
Hasse 0°1809” + -0018” 9" +-0015" 0370"
It will be noticed that the time required to hear a sound is
in all cases less than that required to see a light; and the dif-
ference is sufficient to allow a sound to traverse a distance of
light ene from the same
ear, _ the time registered as in the thie eases. In findi
” it was necessary to siinrinate
the soa of the spark, and in order to accomplish this a small
tube was fitted with platinum wires so as to give a spark
about an inch in length, and partially exhausted of air. If
the exhaustion be properly regulated, the spark is sharp and
distinct, but perfect cctly noisel eae 3
It would seem that
experimenters in attempting to determine
the velocity of nervous transmission, have generally assum
that under the same circumstances the ra te of transmission is
constant. us analyze a few series of es hecnpert an
what light they throw on the subject.
If the constant, or if the oe of the sre
maples ~ — elements than those eperine measuring ®
x
a curve approximating to that shown in fig. 1,
well-known curve of probability. And she asilnge it must be
M. M. Garver—Sensation and Volition through the Nerves, 417
x
0
1. The curve of probability. (From
ah Constructed from the equation
1
este Bice where e is the base of the
Napierian system of logarithms, y the proba-
bility, and A G e., x) the value of ore errors.
The scale of the ordinates is m ur times
that of the La cissee in order to sdk the
eer of the curve more distinctly.
each
eared was as follows, the sign = ste betas used instead of the
he
i appeared :”
Fowler.
2 E
Té=t 24-7
Wz =
18= 26=0
19=—4 zi=0
202235 98=1
21 290
22—0 30=-1
33=—
evident that if the “er-
not accidental,
but are governed by some
other law, the form of the
The readings were taken
in vibrations and tenths,
f
nals were given on the left
foot and answered as in
every case by flexing the
index finger pe at right
a> =a h mber
num shee ap-
Fowler,
: IL
16= 2 22=1
Si 93==8:
18= 4 4—2
fh cer 25-1
20=10 26=2
vb fei
There were tenths in many instances, but for the sake of
mitted.
brevity they have been o
Y
wate ca
22 23 2% 25
x
ee Oe Oe
3
49 20 a
Pi
mall Re come under the second e case. (See figs. 2 rand 13)
by *
418 M. M. Garver—Sensation and Volition through the Nerves.
about ;; of a second. And here is another peculiarity to
which attention is particularly called, for it may serve to
3.
AN
2 ¢ \7 Ol 7 Wy 18 la,
Meche tT ESE, Ae SOR OR AN oF ES 9b Bg xX
explain the anomalous results obtained in some particular
ca he maxima in I (fig. 2) occur at 21 and 24, while in
Il (fig. 3) they appear at 20 and 23, showing an evident change
in the condition of the nerve. The observations in I were
taken the day after those in I, otherwise the conditions were
apparently the same. It is impossible to tell when the change
took place or to tell the cause, but if such a change should
occur during the time occupied in taking the observations, it
is manifest that the results would be materially affected an
the peculiar periodicity of the results more or less destroyed.
more examples showing a periodicity will be given,
but instead of plotting out in curves, it will be sufficient to
indicate the groups by braces. The numbers at the right indi-
approximately the difference between the means of the
groups; 23 vibrations being equivalent to a little less than 3s
of a second.*
ae ee Is
“Sightto “Sight to s rt «Bene to s Hoe to “Shoulder to
. se hand.” hand.”* hand.” hand.”
We-2: 19= “1t= 6 v= 16= 12 1
20= 4 se ins Viz
21=10 2I=1| 24° 19=11 19= 0 i8= 16=2
=16 = 5 f vib 4 20= 0 19=10 w=
23=12 tae. = 9 Sis 2 mal 18 24
a= 4472-1 99-61 3 o9— a— 6) 7 19=5 + vip
25=10) 25= 0 23— 7) Vo. 1 2 oo—140
= 1° 96st 24— = 6) YP o3— 5 21=6
27= 1 27> 2 2=— 0 = 24—- 4 22=%
28= 1 =1 =0 26= 1 25= =3
27= 2 =. ako 24=1
pad © 28= 0 30— 1 25=0
_* The exact rate of the fork during these experiments was 128-1 vibrations pe?
6, the fork underwent
WM. M. Garver—Sensation and Volition through the Nerves. 419 —
The difference between VII and VIII is very marked, and
by simple inspection, noticing the position of the maxima, we
can determine pretty closely the difference in time between
hand and shoulder. It appears to be two vibrations, corre-
sponding very closely to the difference between the means,
which was found to be 1-98 vibrations.
In the same way let us examine the experiments which gave
the anomalous results before mentioned.
ies Hand ‘wo a ys Shoulder to hand.”
14> 0 23=10 14> 19=32
Lise 6 94=— 6 os 20=25
16=10 = Meat 21-31) 36
17=28 36— 2 li=78 22a, 1 | Vib.
18=—40 =f 18=34 BEA? i pond |
1954; $81 ti P|
20==22 7 24
2i=i4 aaa 1 77 1 vib
23=19
which he esti-
mated the “norm” or mean. The periodicity is evidently the
wee Die physiologische Diagnostik der Nervenkrankheiten, Leipzig,
420 M. M. Garver—Sensation and Volition through the Nerves.
same as that obtained in our experiments, and must have its
foundation in the same cause.
XI. XIL XIII. XIV. aN;
Right foot. Left foot. Right hand. Ear. XII dors. vert.
5=1 9=1 10=4 16=1 10=3
9=2 10=5 1i=3 M3
10=3 11=4 12=9 18=4 Penta
1= 12=5 13=10 19=7 is=35
13==6 13=8 14= 4 14=3 o
= 14 tas 1638 bee QS 3 18:5 *°
=3 tas =10 16=2 9=2 (25 16=4
6=10 5°" *> 16— tats 17=8 93=—4 Li=3
= 17=8 [°° 18=—3 =1 18=3
1%=7 18=0 19=2 19=0
]8=4 19=
i9—3
From the many examples of the occurrence of these periods,
it would appear that they have their origin in the physical or
mental action of the individual, but their physiological or psy-
chological significance is not known, and the complete elucida-
tion can be hoped for only through the aid of more extended
investigations,
I
some principally, perhaps, on account of the imperfect working
wregular intervals so as to avoid anything like rhythm, thus
requiring an act of perception and an act of volition for eac
observation; and from what has been shown, it appears that
these two acts cannot be performed with any great deg
regularity. In order then, if possible, to obviate this difficulty,
the pendulum of a clock was made to give the signals at inter-
vals of a , each beat of the clock giving a signal which
was red upon the smoked surface. The other coil in
registe.
connection with the answering key was used to register the
answers. ‘T'wo coils are necessary because when but one 18
M. M. Garver—Sensation and Volition through the Nerves. 421
and, if the rate of niet is uniform, will be proportional
to the length of then
The first nic was made. by simply trying to beat time
with the index finger of the right band to signals given on the
back of the left hand. Great care was taken to prevent any
idea of the time belle received except through the nerves expert-
mented upon. On examining the register after the first set of
observations was oh it was found that the answers some-
times followed and sometimes preceded the signals and did not
have the regularity expected. Upon noticing that the signal
had been frequently Shusieeiad I made a_ new effort, taking
_ great pains tobe sure that the signal was elt each time before
answering. A few observations were then taken, and after
stopping a short time to examine the effect, a few more were
taken. The following was the result, the tuning-fork making
127-8 vibrations per secon
XVI. XVII.
33 46 45-2
38°5 28°4 43
44 32-4 31-2 427
30 oor 40 42°5
35 35°5 . Al 43°5
38°8 33°5 36°5 42
33°5 43
Mean=34°8 49 425
Here then, we have two sets of observations salah within a
few minutes of each other, the external conditions to all in-
&S
the mean of the first (XVI) by nearly 25 per cent. The differ-
ence is probably due, at least in part, to an error in judgment
or pe she to recognize the exact instant at which the signal
was give
a
32 42 31-7
35 445 32°4
29° 44-2 27-3
33-7 40°5 23%
34 38 25
35-4 31-3 26
35-6
37-5
Pe more sets (X VIII and aie taken two days afterwards,
der early as possible the same external conditions, ex-
hibit another phase. Here it is seen that "XIX, taken a few
utes after XVIII, commenced as on the previous day, with
a marked increase over the preceding values, but gradually
decreased nearly one-half in oe few observations.
422 M. M. Garver—Sensation and Volition through the Nerves.
obtained; the coil would simply cease working. It gave
‘accurate results or none at all.”
ere are too few observations in any one of the last series,
to give any marked indication of the periodicity noticed in the
results obtained by the first method; but nevertheless, series
, on analysis, shows a tendency to break into three groups,
differing by six and a half vibrations. Thus:
XVI.
Garver “ Hand to hand.”
3)—4 ° 43=3
36=2 } 1
apa 46=1 64 vib.
40=1 +64 vib. 47=1
41=1 48=0
oe 49=3
It is very improbable, to say the least, that certain values
should be selected and certain others be rejected in this way
without some cause beyond that of mere accident.
The period, it will be noticed, differs somewhat in different
individuals but is almost constant in the same individual. The
doubling may be caused by the obliteration of one of the nor-
mal groups, or as it appears sometimes, by the rejection of the
intermediate values. ;
It may not be amiss to suggest an explanation of the “ per!-
odicity * however liable it may be to be overthrown by further
investigation. ,
It seems that when an individual is experimented upon as 1n
most attention upon the point of application of the signal, I was
sometimes aware that the signal was not answered as soon as It
going too far to assume that the variation is entirely cereb
Could not such a periodicity have its origin in
is to resemble an “ increment to the judgment.
urg, March, 1878.
conceivable that such might be the case and be of such a nature
bl
af
Mins
J. J. Stevenson—Upper Devonian Rocks of Pennsylvania. 428
Art. LXI.—TZhe Upper Devonian Rocks of Southwest Pennsyl-
vania ; by JoHN J. SrEVENSON, Professor of Geology in
the University of New York.
TuE Vespertine or Pocono sandstone of the Pennsylvania
Survey is a massive sandstone from 350 to 450 feet thick in
stones, interstratified with red to gray and olive shales.
representing the Upper Devonian. During the hasty examina-
tion of 1876, I was unable to make any close study of the sec-
tion, and so provisionally regarded the lower rocks as belonging
to the same series with the upper. i
in my report to Professor Lesley for 1876. But the examina-
tions made in the several gaps during 1877 showed the previous
conclusion to be erroneous, and that the lower portion of the
section from the very base of the Pocono sandstone is Devonian
and not Lower Carboniferous. :
A general section of the Devonian rocks, as observed in the
gaps mentioned above, is as follows :—
1. Shales and thin sandstones--.. --- ----------
2. White to BRET aot sandstones with some shale--. 70 “
we ewer eee
aes san: wc in i i a ae ee i a EO -
424 J. J. Stevenson— Upper Devonian Rocks of Pennsylvania.
Lithologically, the top portion, No. 1 of the section, is a
transition mass, more closely related to the overlying than to
the underlying rocks. But its relations are clearly shown by
the fossils which occur in it. This part of the section is well
exposed in the several gaps referred to,-as well as on the
National Road as it winds up the western side of Chestnut
Ridge in Fayette County. At all localities examined it shows
the same character, the sandstones are light-gray to brown and
in thin beds, while the shales vary from brown to dull blue.
but in both gaps of the Youghiogheny there are compact gray
sandstones, good enough to be used for building purposes. On
the National Road, ten or twelve miles south from the Youghio-
gheny River, the shale and micaceous sandstones re-appear as
on the Conemaugh. These micaceous sandstones are reddish-
arder layers have their upper surfaces covered by a close mat
of fucoids. :
A curious conglomerate, from ten to twenty feet thick,
sistent, having been seen under Chestnut Ridge on the Cone-
maugh and Youghiogheny rivers as well as on the National
are much larger than those seen in any other conglomerate
exposed within southwest Pennsylvania. They are oval, thor-
oughly rounded and polished as by long rolling in water.
Most of the larger pebbles are quartz, but with them are others
of felsite-porphyry, quite soft, which had been blackened exte-
riorly before they were embedded in the material cementing
mass,
Relations of these Rocks.
In the final report of the First Geological Survey of Penn-
sylvania, Formation IX, the red Catskill of New York, is
mentioned as occurring in the district under consideration.
Following that report, I intimated in my second annual report
to Professor Lesley that the rocks described in this article
might be referred to that formation; on the maps accompany-
ing my third annual report, now assing through the press, the
areas are colored as Catskill. This which was done to pre-
J. J. Stevenson— Upper Devonian Rocks of Pennsylvania, 425
serve unity in the maps of the survey, is not in full accord
with the facts.
To determine the relations of rocks one may be guided by
lithological characters and relative position, or if possible he
may trace the rocks to some typical locality, or should fossils
be present he may make his determinations by means of those.
For the most part, geologists are satisfied to abide by the last
test, as itis of universal application and saves a great expendi-
ture of time and labor. But some geologists are disposed to
think the simpler method inaccurate, and seem inclined to rebel
against an imagined assumption on the part of paleontologists.
It is desirable then to ascertain whether or not the relations of
these rocks can be determined by tracing or by lithological
characters.
The bold anticlinal axes of southwest Pennsylvania are the
Alleghany Mountains, Negro Mountain, the Viaduct axis,
Laurel Ridge and Chestnut Ridge, all mountainous for the
greater portion of their extent within the State of Pennsyl-
vania. Under these axes alone may one look for exposures of
the lower strata, for away from them the surface rocks belong
to the Coal Measures.
An exposure under the Alleghanies in Maryland reaches
below the Pocono or Vespertine sandstone, but northward
there is no described exposure anywhere on the west side of
those mountains in Somerset County of Pennsylvania;.and, as
be ascertained from the report of Mr. Platt’s close
survey, the deepest gorge on that side is cut down only to the
rocks of Formation XI, the Umbral. But in Cambria County,
which is immediately north from Somerset, the exposures
The Viaduct axis separates itself from the Negro Mountain
in northern Maryland and continues as a strong axis through
Somerset, Cambria and Clearfield Counties of Pennsylvania.
But it nowhere shows anything below the upper portion of
Formation X, as appears from the reports made by Messrs. F.
and W. G. Platt.
Laurel Ridge, at the line between Pennsylvania and West
Virginia, niente only the upper portion of the Umbral, XI,
but at the Youghiogheny River, the upper part of the Devonian
is reached, its section being ex by the railroad cuts.
Here and there, northward from the Youghiogheny, a deep
426 J. J. Stevenson—Upper Devonian Rocks of Pennsylvania.
gorge is cut down to the Devonian, but owing to the thick
coat of debris, no exposures oceur and no section can be
obtained south from the Conemaugh River. The fold declines
north from that river, so that the gaps made within Cambria
County by Chest and Black Lick Creeks reach barely to
Formation X, and no gap in Clearfield County, south from that
of the west branch of the Susquehanna, seems to expose any
lower rock. These facts are gathered from the reports of
Messrs. F. and W. G. Platt on Cambria, Somerset and Clearfield
Counties, and from my own careful observations in Fayette
and Westmoreland.
Chestnut Ridge first shows the Devonian rocks near the
National Road in Fayette County, but thence northward the
axis diminishes in strength, a given stratum being fully 1,000
feet lower at the Conemaugh than at the National Road.
Between that road and the Youghiogheny River, several
gorges are cut down to the Devonian, but no section can be
obtained until the Youghiogheny River is reached. North
from the river, owing to the decline of the axis in that direc-
tion, the deepest gorges soon fail to reach the Devonian and
no exposure exists between the Youghiogheny and the Cone-
maugh. North from the Conemaugh the fold still decreases in
strength, as is well shown by the fact that the Lower Coals
creep constantly higher up its sides, so that the gaps made by
Black Lick and other streams cannot do more than barely to
reach Formation X, especially since the great Conglomerate of
XII thickens very materially in that direction, as abundantly
age from the report on Clearfield County by Mr. Franklin
latt.
There is no exposure whatever for more than fifty miles
along the west slope of the Alleghany Mountain; no exposure
ceurs in Negro Mountain or the Viaduct axis, so that no
e
thirty-five miles. . Surely under such circumstances one may
hesitate before accepting any conclusion based on mere strati-
graphy. 3
But is lithology any better? At all exposures to which
reference has been made, except those in Clearfield County,
respecting which I have no knowled e, rocks more or less
similar in appearance are found Ssaibilinacy below Formation
X, which is believed to represent the gray Catskill of New York.
As they are at the top of the Devonian, they are likely to be
J. J. Stevenson— Upper Devonian Rocks of Pennsylvania. 427
Catskill or Chemung, or to represent both groups, unless indeed
those have thinned out. Professor H. D. Rogers thus describes
the Chemung and Catskill of Pennsylvania :—
‘““VERGENT SERIES.
“Vercent Fiacs (Portage flags of New York).—A rather
fine-grained gray sandstone in thin layers, parted by thin
alternating bands of shale. It abounds in marine vegetation.
Thickness in Huntingdon 1,700 feet.
“VERGENT SHALES (Chemung group of New York),.—A thick
mass of gray, blue and olive-colored shales, and gray and
brown sandstones. The sandstones predominate in the upper
part, where the shales contain many fossils. Thickness in
Huntingdon 3,200 feet.
‘‘ PONENT SERIES.
“Ponent Rev SANDSTONE (Catskill group of New York).—
In its fullest development this is a mass of very thick alternat-
ing red shales with red and gray argillaceous sandstones. It
has very few organic remains. Among them is oloptychius,
and one or two other remarkable fossil fishes, of genera dis-
tinetive of Old Red Sandstone. This formation has its maxi-
mum thickness in its southeastern outcrops, where it measures
more than 5,000 feet.”—Final Rep. First Geol. Surv. Penn.,
vol. 1, p. 108.
On pages 140, 141 and 142 of the same volume, Professor
Rogers gives some further details respecting the lithological
characters of the rocks. In the northwest belt, the Vergent or
Portage flags consist of dark gray flaggy sandstones parted by
thin layers of blue shale, with large marine plants and a
Nucula as the chief fossils, while in the next belt toward the
west they are made up of thin-bedded, fine-grained, siliceous
gray sandstones, intimately alternating with blue and greenish
shales,
In the middle belt, the Vergent Shales or the Chemung con-
sists of gray, red to olive sandy shales, with gray and red
argillaceous sandstones, but no details are given respecting this
“aie in the belts west or northwest from the Alleghany
ountains. :
In the northwest belt, the Ponent or Catskill consists of fine
and argillaceous sandstones, with an increase of red and green
shale and with some calcareous layers.
On page 798 of vol. ii of the same report, Professor Rogers
points out the similarity between the deposits of the Ponent
and Vergent, and states that the sediments of the former are
quite as impalpable as are those of the latter.
all these descriptions ~be compared with those already
given of the rocks occurring in the gaps of the Youghiogheny
*
428 J. J. Stevenson—Upper Devonian Rocks of Pennsylvania.
and Conemaugh through Laurel and Chestnut Ridges, it will
be seen that, as far as lithological characters are concerned,
those rocks may be either Catskill or Chemung, though indeed
the evidence seems to be rather in favor of their being Che-
mung, for if one wished to describe them briefly and compre-
hensively, he could do no better than to combine Professor
Rogers’ descriptions of the Portage and Chemung, thus :—
“A rather fine-grained gray and brown sandstone in thin
layers parted by alternating bands of gray, blue, olive and red
shales. It abounds in marine vegetation, and in the upper part
the shales contain many fossils.”
Since it would be excessively difficult to determine the rela-
tions of these rocks by mere stratigraphy, and since the litho-
logical characters fail to throw any distinct light upon the
matter, the third test must be employed.
What are the fossils?
In the Summer of 1877, while making examinations in the
Conemaugh Gap through Chestnut Ridge, I found, almost mid-
way in the section given on another page, numerous specimens
of Spirifer Verneuilir, Rhynchonella Stephani and Streptorhynchus
Chemungensis, associated with many lamellibranchs and poorly
preserved brachiopods, which could not be determined at the
time. Further examination showed that these species occur up
to within — inches of the undoubted Pocono sandstone, or
The
In order that no doubt might remain respecting these species,
I sent some specimens to Professor Hall, who has made out the
Langula, sp. ; 2. Discina grandis or D. Alleghaniensis ; 3.
Streptorhynchus Chemungensis; 4. Rhynchonella Stephani ; 5.
pirifera. Verneuilii; 6. Paicwoneilo maxima ; 7. Sanguinolites
rigida ; 8. S. clavulus; 9. S. ventricosa? 10. Mytilarca Che-
mungensis ; 11. Pteronites, sp.;.12. Pteronites, sp. ; 13. Actino-
a recta ; 14. New form, undt.; 15. Orthoceras crotalum 2.
These were collected at one locality and in haste, the only
object aig Ba obtain a few specimens of the more common
forms. Of the list, Nos. 6 and 18 are found in New York only
in the Hamilton rocks, while No. 15 is ve closely allied to a
Hamilton species and may be identical wit it; but reaping,
the other forms there is no doubt—they are Chemung... Allo
these forms occur also in the layers interstratified with those
containing the fucoids, They are not stray specimens, such as
might have been washed from the older into the newer rocks,
:
;
J. J. Stevenson— Upper Devonian Rocks of Pennsylvania. 429
for they are found in great abundance throughout the section
and they are as well preserved as Chemung fossils usually are
in New York. With these are immense quantities of fucoids,
such as are characteristic of the Portage or lower Chemung in
New York. But in the whole section there is not an Anodonta,
not a fish-plate, not any fossil of any sort which can in any way
be identified as belonging to the red Catskill of New York.
It is more than probable that the section represents only the
lower portion of the Chemung and that not only the red Cats-
kill, but also the upper portion of the Chemung is wanting in
this part of Pennsylvania.*
What then has become of the great Catskill group? €
upper or gray Catskill is represented, no doubt, by the Pocono
or Vespertine sandstone, but the lower or red Catskill has dis-
<a s Nor is this disappearance at all strange. It is sim-
ply what might have been expected.
Professor H. D. Rogers, on pp. 141 and 142 of vol. i, of his
Final Report, shows with what rapidity the Ponent or red
Catskill thins out toward the northwest; that it is 5,000 to
6,000 feet thick in the southeast belt; 2,500 to 1,000 feet in
the northwest belt; and 400 to 0 feet in the fifth belt; the
diminution in each belt being distinct as one goes nor’
or even west. No details are given respecting the variations of
the group in a due west direction or towards the southwest,
most probably because no possibility of tracing the group ex-
isted then any more than now. The presence of Ponent rocks
is incidentally mentioned in notes upon the southern Allegha-
nies and the gaps through Chestnut and Laurel Ridges, but these
observations were evidently regarded as too detached and too
unimportant to be of value, since no reference 1s made to them
in the general summary of the group given in vol. 1 of the
Final Report. : ath: :
All the evidence points in one direction. Itis impossible by
any stratigraphical work to make direct connection between the
localities under consideration and those where the age of the
rocks is settled beyond dispute; the lithological characters of
* In the Proceedi erican Philosophical Society, vol. xvii, p. 270, it is
stated that at 200 feet below the Pittsburg bal y in the Lower Bar-
e .
No explanation is necessary further than to say that the species were wrongly
identified. I haye examined the specimens and have recognized the following:
Species :—
Lophophyllum proliferum M’C., Athyris subtilita H., Spirifer planoconvecus Shum.,
Orihis carbonaria Swal., Chonetes granuifera Owen, Productus pertenuis Meek ?,
Hemi } M. and H., Lima retifera Shum., Astartella vera
These are usually thought to be quite characteristic of the Coal measures.
Am. Joon. Sc1.—TuHirp _— Vou. XV, No. 90.—Jung, 1878.
430 H. A. Rowland—Absolute Unit of Electrical Resistance.
the rocks in question are much like those of the Chemung,
while the fossils, both animal and vegetable, are unquestionably
of Chemung age. But one conclusion remains—the rocks are
Chemung and, as already stated, probably represent only the
lower Chemung; the great Catskill group has so far thinned
out, that it is represented only by its upper or gray member,
the Vespertine of Pennsylvania.
Art. LXIl—Research on the Absolute Unit of Electrical Resist-
ance; by Henry A. Rowianp, Professor of Physics in the
Johns Hopkins University, Baltimore, Md.
[Concluded from page 336.]
em. broad, 1°8 thick and 82-7 em. diameter. As the room had
no fire in it, the circle remained perfect throughout the experi-
ment. The wire was straightened by stretching and measu
before placing on the circle, which last was done with great
care to prevent stretching ; after the experiment it was meas-
ured and found exact to ;, mm. ‘
The circle was adjusted parallel and concentric with the coils
galvanometer, but at a distance of 1-1 cm. to one side,
in order to allow the glass tube with the suspending fiber to
pass. The length of wire was 259-58 cm. which gives a mean
radius of 41313844 cm. These data give G’= -151925. Pre
liminary results were also obtained by use of another circle.
C. meter.—To obtain the time of vibration, a marine
chronometer giving mean solar time was used. The rate was
onl. a second per day. ;
e dge.—To compare the resistance of the cireult
with the arbitrary German silver standard, a bridge on Jenkins
plan, made by Elliott of London, was used. A Thomson gal-
vanometer with a single battery cell gave the means of accurately
adjusting the resistance, one division of the scale representing
one part in fifty thousand.
aon Fagg Se Fred Paper T have criticised the use of wooden circles val
needle Ty Wnpebded Some te cance SE et See F
|
|
H. A. Rowland—Absolute Unit of Electrical Resistance. 431
Thermometers.—Accurate thermometers graduated to half
degrees were used for finding the temperature of the standard.
The arbitrary standard.—This was made of about seventy
feet of German silver wire, mounted in the same way as the
temperature was taken as 17° C.
To obtain the accurate resistance of this standard in ohms, I
had two standards of 10 ohms and one of 1, 100, and 1,000
ohms. The 1-ohm, and one of the 10-ohm standards, were made
by Elliott of London, and the others by Messrs. Warden, Muir-
head and Clark of the same place. But on careful comparison
I found that Warden, Muirhead and Clark’s 10-ohm standard
was 1:00171 times that of Messrs. Elliott Bros. On stating these
facts to the two firms I met no response from the first firm, but
the second kindly undertook to make me a standard which
should be true by the standards in charge of Professor Max-
well at Cambridge.* At present I give the result of the com-
parison with these standards, as well as some others, and also
with a set of resistance coils by Messrs. Elliott Bros.
Ci tat N tators except those having mercury
connections were used, and those in the circuit whose resist-
ance was determined were so constructed as to offer no appre-
ciable resistance. The commutator by which the main current
was reversed, could be operated in a fraction of a second, so
as to cause no delay in the reversal.
Connecting wires,—These were of No. 22 or No. 16 wire and
were all carefully twisted together. The insulation was tes
and found to be excellent. ean
Inductor for damping.—This has already been described in
my first paper on “Magnetic Permeability,” and merely con-
sisted of a small horse-shoe magnet with a sliding coil, which
was introduced into the secondary circuit. By moving it back
and forth, the induced current could be used to stop the vibra-
tions of the needle and make it stationary at the zero point.
This is necessary in the method where the first throw of the
galvanometer needle constitutes the observation, but in the
method of recoil it is not necessary to use it very often. I
refer the method of the first throw as a general rule, but I
ave used both methods. :
This method of damping will be found much more efficient
than that of the damping magnet as taught by Weber, and
practice a single movement will often bring the needle
exactly to rest at the zero point.
* i and as I cannot tell when the standard will
sive: Cpe paren cioteeanrs a Secale hoping to make a more exact
comparison in future.
432 H. A. Rowland—Absolute Unit of Electrical Resistance.
Arrangement of apparatus.—Two rooms on the ground floor
of a small building near the University were set aside for the
experiment, making a space 8 m. long by 8°7 m. wide. e
plan of the arrangement is seen at fig. 1. The current from
° 1 2 2 4 5 6 7 :
re
the battery, in the University, entered at A, the battery being
eighteen one-gallon cells of a chromate battery, arranged two
abreast and eight for tension. The resistance of the circuit
was about 20 ohms, and of the whole battery about 4 ohm,
thus insuring a reasonably constant current.
At B some resistance could be inserted by withdrawing plugs
so as to vary the current.
At C is the tangent galvanometer with commutator on @
brick pier. The nearness of the commutator produces no error,
seeing that we only wish to determine the ratio of two currents.
The effect of currents in the commutator was, however, van-
ishingly small in any case.
At D is the principal commutator which reversed the cur-
rent in the induction coils, L, or in the circle, F, when it: was
in the circuit. |
Che secondary circuit included the induction coil, L, the
damping inductor, M, and the galvanometer G. ‘
t H was the Jenkin’s bridge, with standard at P, in a
beaker of water, and a Thomson galvanometer at J K. The
‘he telescope and scale, E, were on a jaca wooden table,
and the two galvanometers on brick piers with marble tops. _
A row of gas-burners at Q illuminated the silvered scale in
the most perfect manner.
H, A, Rowland—Absolute Unit of Electrical Resistance. 488
Adjustments and tests.—The circle, F, must be parallel to coils
of galvanometer, G. The circle and coils of galvanometer
were first adjusted with their planes vertical and then adjusted
in azimuth by measurement from the end of the bar, R. to the
sides of the circle, F. e adjustment was always within 30’,
which would only cause an error of one part in 25
e needle must hang in the magnetic meridian by a fiber
without torsion, and the coils must be parallel to it. These
adjustments were carefully made, but, as has been shown, the
error from this source is compensated.
The needle must hang in the center of the galvanometer
coils and on the axis of the circle. The error from this source
is vanishingly small. ;
The scale must be perpendicular to the line joining the zero
point and the galvanometer needle, it must be level and not too
much below the galvanometer needle. All errors from this
source are partially or entirely compensated by the method of
experiment. ‘
The induction coils, L, must be horizontal, and at the same
level as the two galvanometers, so as not to produce any mag-
netic action on them. The error from this source is exactly
practically zero. The insulation of
tators was carefully tes
Method of Kaperiment.—As has been stated before, the
method generally used was that of the first throw of the needle,
though the method of recoil was also used. For the successful
use of the first method a quickly vibrating needle and the
damping inductor are indispensable, seeing that with a slow
moving needle we can never be certain of its being at rest. By
this method it is not necessary to have the needle at rest at the
zero point, but, if it vibrates in an arc of only a millimeter or
two, we have only to wait till it comes to rest at its point of
greatest elongation on either side of the zero point and then
reverse the commutator. The error by this method is in the
direction of making the throw greater in proportion of the
The smallest throw used was
4384 H. A. Rowland—Absolute Unit of Electrical Resistance.
n 7°8 seconds, but the time of vibration was too short and
se needle was constructed vibrating in 11°5 seconds, which
was a sufficiently long period to be used successfully after
practice.
There seems to be no error introduced by the time taken to
reverse the commutator in the method of recoil, seeing that the
breaking of the current stops the needle and the making starts
it in the opposite direction. As the time was only a fraction
of a second the error is minute iu any case.
hile the current is broken in the reversal, the battery may
recuperate a little and there is also some action from the extra
current, but there seems to be no doubt that long before the
four or six seconds which the needle takes to reach its greatest
elongation everything has again settled to its normal condition
and the current resumes its original strength. Hence the error
from these sources may be considered as vanishingly small.
Some experiments were made by simply breaking cscs current
and they gave the same result as by reversal.
The ovewieg is the order of observations corresponding to
each experim
“$3 he ene of —— of needle was observed.
. The = was around the circle, F, so as to
sa B and a. Sirmnitanenaa readings were taken at the
two galvanometers. The commutator at the tangent galvan-
ometer was then reversed and readings again taken. After
that the ea paren to the circle was reversed and the operation
s gave four readings for the circle and eight for
the tangent arid claire as both ends of the needle were read.
n some cases these were pore ey six and twelve respect-
ively. This operation was repeated three times with currents
of different eR coristitubing three observations each of 4
and fp. T nate any action due to the induction coils, they
were sometimes korisented in one way and sometimes in the
opposite w
BG.
H. A. Rowland—Absolute Unit of Electrical Resistance. 485
respect to each other, followed by another comparison of resist-
ance with standard.
5th. Biestrediaub of a and # were again made as before.
6th. The time of vibration was again determined.
The observations as here explained furnished data for three
computations of the resistance of the circuit, one with each of
the three currents. In each of these three a ete a was
the mean of 16 readings, 8 of 8 or sometimes 12, @ of 16 and d
of 16. Ta using the method of recoil nearly the same order
was observe
The time of vibration was determined by allowing the needle
to vibrate for about ten seconds and making ten observations
of transits before and after that period. During the experiment,
I usually observed at the telescope and Mr. Jacques at the tan-
gent galvanometer.
The methods of obtaining the corrections require no explan-
ation.
Results.
The constant corrections are as follows for the first needle.
a= —A+1°= —-00711
b= Meee ~ Sh
sal Cy oe + °00003
f= + 00003
a fy Pes ore e+f= —-00718,
For method of recoil it becomes — 00016.
Hence for A and B, log K=11-45360380
‘ A and C, log K=11-2852033
“ — * Band C, log K=1171886619
For method of recoil using A and B, log K=11°4566630.
For second needle and method of recoil,
a=—} z)= — 000050
J= +00
a+b+ ai ee ye —-00017
For A and B, log K=11°4566587
* A and C, log K=11-2882590
“ B and on log K=11 1917176
The distance oF the mirror from the scale varied between
192-3 and 193°5 cm
Table of Results.
hab Rest ee I sgitancen
“ton” Method. v Said B 4 - 8 , B D eee farth quad. Error. ‘centage
. +-000| —00 | +:00 |—-00 _ ‘
‘9 | goo! 187 22017) 170-29 [40 19°44 [43 32°56) 19 | 075 | 036 | 22. | 34°672 )
A&C|) 0 “ « |495-61; 14128 |35 29:06 |37 22-94) “ « | 999 | “ | 34-784 $| 34-748 |+-029|+-083
0 uc “ 1473-83] 13140 |33 43°56 {35 28°01; “ « | 995 | « ‘187
0 | 7800! 20:3 (292-20; 137-07 |40 27°81 [42 49°81} 21 | 145 | 036 | 74 | 34760
B&O} 0 u « |186-66 11370 |35 41-94 |37 33°69) « | 999 | « | 34-680 }| 34714 |~-005 |—-014
0 u “ (144-64! 105-71 (83 55°87 |35 35°94) « | 995 | « | 34-402
0 | 7-806} 21-0 | 219 16816 |40 7°56 |42 1806) 22 | 176 | 035 | 44 | 34-762
A&C|) 0 « « {184-99| 139-65 {35 26°37 (37 T3847) “ « | 995 | « | s425 6} 34473 |+-0n4 | +-155
0 “ « 1473-20) 129: 33 40°75 |35 13-06) « | 994 | & | 34-831
pe 0 | 1822} 2447 208 23598 [38 41°87 [40 56-13, 29 | 334 | O34 | 44 | 34-700 : ;
‘& BI 4 6-31] § 119°20 ) (34 10°50 : « | yoo | & can ¥| 84716 |—-003 |—-00
B « | | 165+ yiiast 2 be oT atl ae | age ee Bees
9 | 7-26] 25:4 |211-15' 12929 |39 3-87 |41 19:19) 32 | 370 | 034 | 44 | 34-730
B&C |, o 4 « |178-01| 107-48 (34 27°31 |36 13-25] « | 997 | « | 34-493 6) 84-718 |~—-001 |—-003
0 “ « |166-98| 100-27 |32 4612 |34 19°87) “ « | 995 | “ | 34-700
0 | 7928! 25-9 |210-53! 237-74 |39 1-69 {41 11°62} 32 | 392 | 034 | 43 | 34-665
A&B|I 0 “ « 1477-73] 19772 134 2400 (36 150) « | 996 | « | 34-704 $] 34-685 |—-084|—-098
0 “ « | 166-32; 184:35 |32 40:00 |34 1456) “ « | 924 | “ | 34-686
R [13-488] 198 |219°62| | 4 4o7 ) [40 0-16 21 | 123 | 039 | 33 | 34-701
A&BIL R “ « | 18515 | vai 20°82 4 \49 14:85} « | 308 | “ | 34-667 $1 34-688 |—-031 |—-089
a “ 1173-64 33 37°31 “ « | 399 | «© | 34-697
R 11-487} 206 | 216-8¢ 39 37°43 22 | 158 | o30 | 22 | 34-724
A&CIIR “ « | 193-38) { 56 ‘059 ¢ (28 ost bj41 35-29) + « | yoo | & | 34-795 6) 34-712 |—-007 |—-020
R “ «| yoga) (56 33 81-25 “ « | jor | « | 34-688 ‘
34°7192 +°0070
‘sounjsisay JDn.uyIapy fo RUQ anjosgyY—punmoy “WY A 9SF
H. A. Rowland—Absolute Unit of Electrical Resistance. 437
Should we reject the quantity 34-831 in the third experiment
so as to make the mean result of that experiment 34-744 instead
of 34:778, we should obtain as a mean result of the whole
34°7156+°0053,
which has a less probable error than when the above observa-
tion is retained. ‘The number of plus and minus errors are also
more nearly equal and the greatest difference from the mean 1
part in 1100. However the two results do not differ more than
1 part in 10,000.
We shall take
earth quad. Z
R=34°719-+-'007 iena at.17°C.
as the final result.
Discussion.
On glancing over the table we see that the number of nega-
tive errors greatly exceed the number of positive, but, if we
take only the four errors which are greater than 1 part in 5,000,
we shall find two of them negative and two positive.
Combining the results with the different coils we have
A ond 6... Se 34°696-+°005
A sed 2 ee 34°744-+4 ‘011
B and C 34°716-+- 007
Had we no other results to go by, we might suppose that the
value of M might not have been found as exactly for these
coils as we have supposed them to be. But if we include the
eager: results rejected on account of the imperfect circle
ll find
used, we sha
Aie0 Bs tee 34°704+°006
mane t oe as 34°718+017
Sie 84°758-+ ‘016
which has the greatest error in an entirely different place. _
From the first series the probable error of each determination
errors which are about equal to +;,'s5, the real probable error
of M must be about 1 part in 2,500. The
tions is however too small for an exact estimate of the probable
errors.
Taking the results with currents of different strengths, we
find
For strongest current.....--.-++--++> 34716
“ medium Bas Sis 6s oe so 84-715
ie. lt. ee mes Ree Sek eee 34-727
which are almost perfectly accordant. Taking the results from
the method of recoil and the ordinary method, we find
For ordinary method....... Sue acne 34726010
“ method of recoil.......---++++-> 84:705 + 006
438 H. A. Rowland—Absolute Unit of Electrical Resistance.
If the probable error is subtracted from the first and added to
the second they will very nearly equal each other. Hence the
difference is probably accidental. Indeed, by the combination
of the results it does not seem possible to find any constant
source of error, and therefore the errors should be eliminated
by the combination of the results.
In the final result
R=34°7192+-°0070
the probable error, +*0070, includes all errors except the ratio
of é to G’. Wemay estimate the probable error of G at
s3,'55 and of G” at +5555.
Hence the final probable error of R, including all variables,
iS +5355, Or +°04 per cent,
or R=34°719+--015.
The probable error of the British Association determination
was + ‘08 per cent, not including the probable error of the con-
stants; and of Kohlrausch’s determination +°33 per cent, in-
cluding constant errors.
Comparison with the Ohm.
The difficulty in obtaining proper standards for comparison
has been explained above and I shall have to wait until the
arrival of the new standard before making the exact comparison.
At present I give the following results, which seem to warrant
the rejection of Messrs. Elliott Bros’. 10-ohm standard and to
make that of Messrs. Warden, Muirhead and Clark correct. I
shall designate the coils by the letter of the firm and by the
number of ohms. Experiment gave the following results :
W (10)=1-00171 X E (10), experiment of June 8, 1877.
Ww (10)=1°00166 xX E (10 i eo ee Ben, 28, 1875.
W (1,000) : W (100) :: W (10): -999876 E (1), experiment of
February 23, 1878, '
Now the greatest source of error in making coils is in passing
from the unit to the higher numbers. As the reproduction of
single units is a very simple process the single ohm is without
much doubt correct, anid as the above proportion is correct
within one part in 8,000 of what it should be, it seems to point
to the great exactness of the standards then used, seeing that
the exactness of the proportion could hardly have been acci-
dental. It is also to be noted that Messrs. Warden, Muirhead
& Clark’s 10-ohm standard agreed more exactly with a set of
coils by Messrs. Elliott Bros. than their own unit E (10).
The resistance of my coil as derived from the different stand-
ards is as follows: 3
From Elliott Bros. resistance coils.......... 34-979 ohms.
ue 7, RO AUR BOOS: 35083 “*
a WM & C's...“ 2 85-0
“ W., M. & C.’s 100-ohm “ 35°0385 =“
ee es sees
A. C. Peale—Ancient Outlet of Great Salt Lake. 439
Te give for my determination the values of the ohm as
ollow
From Elliott Bros. resistance coils, °99257
i * 10- ohm standard, "98963 .
ea Ws M& 07s 99129
Se WM) rad ¢100-ohm . ‘99098
For the reasons given above I accept the mean of the last
two results as the value of the ohm.
To preserve my standard I have made two extra copies of
it, the one in German silver and the other in platinum silver
alloy. The comparisons are given below. No. 1 is in German
silver, and the other in platinum silveralloy. The temperature
LEG:
earth quad.
sec,
Ne Devore, 20S 1. Pees June, 1877.
Noe Dy ct vie. ed 100029 Feb., 1878
No: Hh eos es Ses 99630 June, 1877.
Ov Hicueesihs Seb 99932 Feb., 1878
These are the mer of the copies in terms of the original
earth quad.
standard whose resistance is 34°719
From these results it would seem that the German silver of
several years and seems to have reached its constant state.
he final result of the experiment is
earth quad.
1 ohm = 9911 sep ae
Arr. LXTIL—The Ancient Outlet of Great Salt Lake; by A.C.
PEALE.
In this Journal for April, 1878, pp. 256-259, is an article
entitled “The Ancient Outlet of Great Salt Lake; a letter to
the editors by G. K. Gilbert.” In this article Mr.
states that “‘ previous to 1876 the outlet was not discover ed, or
if Mosbeeted: its position was not announced,” and that “in
the summer of that year” he “had the great pleasure re of find-
ing it in Idaho, at the north end of Cache Valley, the locality
being known as Red Rock Pass.” He says also that the
announcement was made by him “without reservation in a
communication to the Philosophical Society of Washington,’*
* At the 116th meeting of the Society, January 13, 1877, “Mr. G. K. Gilbe
¢ fossil lake of Utah. tle
described an ancl oudet of the Tako at” Hed Hock Pass near the town of
440 A. C. Peale—Ancient Outlet of Great Salt Lake.
and — the ee was also made for him “in the
same unequivocal manner” “in the Smithsonian Report for
1876” ( (p. 61), ni ‘in Baird’s Annual of Scientific Discovery
for 1876’* (p. 206), and that “ there seemed to be no occasion
for further publication ame the matter should receive its full
discussion in the Reports of the Survey of which Professor
Powell has charge,” but owing to a statement + in this Journal
for January, 1878, p. 65, ‘it seems proper” to him “to defend”
his “ positive assertions by setting forth the facts which appear”
to him “ to place the existence and position of the ancient out-
let beyond question.
As Red Rock Pass, the point of Mr. Gilbert’s discovery (?),
is within the area assigned during the season of 1877 to Mr.
Gannett’s division of the United States Geological Survey of
the Territories, with which I was connected as geologist, it
seems proper that I should call attention to several errors in
Mr. sea statements.
In the fi lace, his so-called discovery is not a discovery on his
part. The fi fact that Red Rock Pass was an outlet for the lake
that once filled the Salt Lake Basin and adjoining valleys §
Oxford, Idaho, by which its waters were discharged into Snake River. During
and since the desiccation of on lake, the land which it covered has been — a
the north aes common with the region of the Laurentian lakes and the eas
and w seaboard.” (Bulletin of the Philosophical Soci ‘ety of Weshington
for. 1817, P. 18)
equivocal” announcement referred to by Mr. Gilbert, is stated in
peti hy ‘same. » words in both pallioateon, pl is eng in re followin g rather
vague manner. “Before commencing the main work of the season, M r. Gilbert
ng excursion in search of the outlet of tate Bon neville, the creat f ey
lake of Utah.” * * * “The search for the point of outlet wa
was ook at the north end of Cache Valley, a cag soiies es beyond te Bondar of
in the Territory of Idaho. —— Report rd of Regents of the
Smithsonian Institution for 1876. Washington, at tee and (Annual Record
of —— and Industry for 1876, edited by Spencer F. vpaird. New York, 1877,
p. 260
The statement referred as is the pierre: # Toad is believed that the explora-
tions of the survey under the direction of Dr. Hayden, the past season, et
determined the probable icin a. of the great lake that once filled the
Lake Basin.” dager Journal, yi Spite 1878,
italics in p
The i$ paragra)
The following extracts pag the Report of the Survey for 1870, written by
Dr. sapere show that as early as that time the extent of the great i t inland basin
and its phony ey itions were y spprocsited by him.
a moment a a bint bare view of the great inland basin of which
Columbia on the north, and that of the Colorado e
region has no visible ow composed of # multi-
tude of smaller basins or h of which has its little lakes,
ce of the vallevd ‘sed fol that Goan oF the m are much above
the waters of Great Salt Lake.” (p. 172.)
fresh-water lake ounce occupied all this immense basin
ranges ins were scattered over it as isolated mands,
A. C. Peale—Ancient Outlet of Great Salt Lake. 441
was not only recognized, but well known five years prior to
Mr. Gilbert’s supposed discovery. On page 202 of the Annual
Report of the Survey for 1872 * is the following statement by
Professor F. H. Bradley: ‘The level of the divide between the
head of Marsh Creek and the Bear River drainage, at Red
Rock Pass, as ascertained by the party of 1871, indicates that
this was probably another point of outflow ;” and on the fol-
lowing page (203) the following sentence in relation to the ter-
races in Marsh Creek Valley, which extend northward from
Red Rock Pass: ‘They are on too large a scale, and the valley
is too wide, to have resulted from merely the drainage of the
small area of mountains about the head of the stream; and I
am strongly of the opinion that this must have been at one
time the channel for a large outflow from the Great Basin.”
It seems to me that this places the discovery where it belongs
beyond question.
It appears also that Mr. Gilbert ignores some of his own
statements. In his report to Lieutenant Wheeler,t he says
that Professor O. C. Marsh informed him that he had discov-
ered on the northern shore of the lake an outlet leading to
Snake River, and in a foot note on the same page says, “ Pro-
fessor Frank H. Bradley mentions four points of possible out-
flow from the northeast margins.—(United States Geological
Survey of the Territories, 1872, p. 202.)
In the second place, Red Rock Pass was not the outlet of Lake
Bonneviille.
Lake Bonneville extended over the whole of Marsh Creek
Valley and its outlet was more than forty miles farther north
than Mr. Gilbert ever went. Red Rock Pass was only a point
ancient lake outflowed.” This sentence implies that he went
into Marsh Creek Valley. Had he done so or had he even
ascended one of the numerous points that command the view
. Vi
lake. (Report United States Geological Survey for 1871, p. 19.) ie
ee Sixth 5 gedee Report of the United States Geological Survey of the Territories
1872, Washington, 1873.
Report upon Geographical and Geological Explorations west of the 100th
inte in nee of ee Lieutenant Geo. M. Wheeler. Vol. iii, Geology.
Washington, 1875, p. 91.
442 A. C. Peale—Ancient Outlet of Great Salt Lake.
of both valleys (Cache, and Marsh Creek) the relation of the
two must have been apparen
The ‘gentle alluvial slopes” mentioned by Mr. Gilbert (on
page 257) as being “divided for several miles by a steep-sided,
flat-bottomed, trench-like passage a thousand feet broad, and
descending northward from the divide” are white sandstones
similar to those in the bottoms of Cache and other valleys of
the Salt Lake Basin. The following elevations on the terraces
in Marsh Creek Valley were obtained by barometrical observa-
tions.
Two miles — of Red Rock Pass on the east side of the
valley, 5,187 fee
ix miles = a Red Rock Pass on the edge of Marsh Val-
ley, 5 pe -
wenty-six miles ogee Red Rock Pass on the west side of
the owen: ‘5, 117 fe
The elevation of ie Bonneville beach is 5,185°7 feet + and
it is evident that the Red Rock Gap (the walls of which do not
exceed the elevation of 5,000 feet) could not have been a bar-
rier to Lake Bonneville. The conclusion is therefore irresisti-
ble that the result of Mr. Gilbert’s four or five years’ search is
a mistake.
In the third place Red Rock Pass was an outlet, but it was
the outlet probably when the lake was at the level indicated by the
rove Beach, When the barrier at the northern end of the
Bonneville Lake was removed, that portion of the lake occupy-
ing Marsh Creek Valley was completely drained, and Red Rock
Gap became the barrier of the lake that remained. Then
it was that the course of Marsh Creek began to be outlined,
and the lowering of the lake was doubtless comparatively rapid
until the level of the Provo Lake was reached. The line of
the Provo Beach indicates a period of comparative permanence,
but when the pass became lower than the lake, of course the
lake was dramed. The elevation of the pass as obtained by
rane level i ws 4,7 - feet, and the Provo Beach, according to
65 feet below the Bonneville Beach,t
which would an an eden of 4,820°7 feet for the former.
In the fourth place I wish to call attention to two more of
Mr. Gilbert's statements. On page 258 he says, ‘In Dr. Hay-
den’s Preliminary Report of the field work of his survey for
*I am indebted to Mr. Henry Gannett for all the elevations I use and for other
sedosbie icdoraon har ‘while in the feld.
t This slexatiots | is obtained athe adding 967-7 feet (the height of the one
given r. Gilbert i se)
on oe Ss mest of the ct oe vol. pg Ty 1218 fet,
Union Pacifie Railroad.
_} This Journal, vol. xv, April, 1878, p. 258.
Le oe we be tae
A. C. Peale—Ancient Outlet of Great Salt Lake. 443
the season of 1877, noticed on page 56 of the current volume
of this Journal, there is no mention of the observations at Red
Rock Pass, but the omission appears to have been accidental, &c.”
The portion of this statement that I have italicised is a gratui-
tons assumption. The omission was not accidental. I did not
believe that the outlet was at Red Rock Gap, and in the Pre-
liminary Report (page 7), I made the following statement:
“The lower valley of the Portneuf is interesting from the fact
that it is the probable ancient outlet of the great lake that
once filled the Salt Lake Basin.”™
Mr. Gilbert also hopes that I “will not advocate in” my
“report the idea that the divide between the Malade and
Marsh Creek was one of the old outlets of the ancient Salt
Lake when its waters were at the highest level.”
Had I been writing a final report on the subject I would
perhaps have used the word overflow instead of outlet. It
summit, although” he “bad undertaken last summer to examine
every divide between the Columbia and Salt Lake Basins, that
might have afforded passage to the water.”
In all his investigations he seems never to have noted any
evidences of a lake having a higher level than his Lake Bonne-
ville. Such evidences, however, do exist. On both sides of
the Portneuf where it comes into Marsh Creek Valley an upper
terrace is seen, and in 1872 Professor F. H. Bradley also
readily identified an upper terrace in Marsh Creek Valley at
the lev bo n
Report
no warrant for the statement that he made the “ astonishing
* Preliminary Report of the field work of the United States Geological and
perce Sea i of the Territories for the season of 1877. Washington,
1877, p. 7. ; {
+This Journal, vol. xv, April. 1878, p. 258. Mr. Gilbert appears to take it
for granted that the point of outlet must necessarily be found at one of the exist-
ing divides between the Great Basin and the Columbia.
The railroad profile from the bluffs on Bear River in Cache Valley to Red Rock
Pass (a distance of fifteen miles) shows a difference of elevation of only eleven
f the descent of Marsh Creek from Red Rock Pass to a point twenty-six
ly 1°07 feet per
draining of Lake Bonneville — easily have
present the divide for several miles is a swamp. 2
¢ Sixth Annual of the United States Geological Survey, for 1872.
Washington, 1873, p. 203.
444 EF. H. Storer—Ferment-theory of Nitrification.
suggestion that four outflowing streams might have coexisted.”
The italics are my own.
In conclusion I wish to state that this paper is based on the
special reference to finding an outlet of the ancient Salt Lake.
Mr. Gilbert has spent portions of at least two seasons in the
study of this special subject in the northern portion of the
basin, and it is evident that his investigations are still unsatis-
factory.
Art. LXIV.—WNote on the Ferment-theory of Nitrification; by
F. H. Storer, Harvard University.
THE results of the following experiments bear so immedi-
ately upon the recent observations of Schliésing* and Waring-
ton,t noticed in the April number of this Journal, that I am
led to publish them by themselves, out of their legitimate con-
nection with other experiments upon which I have been for
some time engaged. My experiments were made for the pur-
- ; No. 6 ammonium chloride,
black oxide of manganese nd
a
peat and pure water; No, 8 leached peat and ammonium chlo-
* Comptes Rendus, ixxxiv, 301.
Journal of London Chem Soc., 1878, i, 44.
+ In the manner described in the note on page 182 of vol. xii of this Journal.
F. H. Storer—Ferment-theory of Nitrification. 445
chemicals, and the absence of nitrates and nitrites was proved
by testing each of the solutions and mixtures with iodo-stareh,
at the beginning of the experiment.
The bottles were about half filled with liquid, i. e., each of
them contained about 250 ce. of the solution or mixture allot-
ted to it.
The “leached peat” was prepared from some bog-meadow
mud from the Bussey farm, which had been kept in barrels in
a dry store-room for three or four years. This thoroughly air-
dried substance was percolated with pure water until the fil-
trate gave no reaction for nitrites or nitrates.
ic and ferrous hydrates were used in the recentl
precipitated condition; they were made from the correspond-
ing chlorides by precipitating with ammonia-water, in the cold.
e bottles were connected with one another, in the order
indicated, with short pieces of caoutchouc tubing in such man-
ner that by aspirating at No. 1 air could be made to bubble
through the water in each member of the series. The corks of
the bottles and the caoutchoue connectors were covered with
ilar bulbs hited with potash-lye to remove nitrates and
nitrites; through a dry bottle, to catch liquid drawn forward
from the potash bulbs; and through a large drying tube
charged for two-thirds its length with calcium chloride and one-
third with soda-lime.
and 10 namely gave immediate and strong reactions for the
nitrogen oxides, while the contents of Nos. 1, 2, 3. 4, 5, 6, and
1 gave no reaction whatsoever. No. 7 gave a reaction, but
not a very strong one. The reaction seemed to be strongest In
Am. Jour. Sci.—TsimD — Vou. XV, No. 90,—Junz, 1878.
446 F. H. Storer—Ferment-theory of Nitrification.
the contents of No. 10. It appeared from these results that
there had been formation either of a nitrate or nitrite in each
of the bottles which contained humus, and no such formation
in either of the other bottles; but the thought suggested itself,
that the small amount of nitrogen oxides found in No. 7 may
perhaps have been dragged over mechanically from No. 8 by
the current of air.
A second series of tests was made upon Nos. 8, 9 and 10,
to see which of them gave the weakest reaction, 25 ce. of liquid
being taken from each bottle and diluted with pure water to
the volume of 100 cc. before applying the test. It appeared
again that No. 10 gave the strongest reaction and that No. 8
gave the weakest. Roughly estimated, the strength of the
reactions from jars Nos. 10, 9 and 8 were to one another as
It may here be said that humus was employed in these exper-
iments for the sake of testing the old observation of Millon,*
who noticed that ammonium salts are changed to nitrates when
in contact with oxidizing humus, and who argued that the
chemical action originated by the coming together of humus
and oxygen, was communicated to the ammonium compound.
In his own words: “The oxidation of the humic acid is the
cause of the oxidation of the ammonia.”
e
chloride; No. 14 pure water; No. 15 pure water, the same
warming the laboratory. The current of air passed this time in
the direction from No. 1 to No. 15; it was maintained constantly
* Kopp and Will’s Jahresbericht der Chemie, 1860, xiii, 101 and 1864, xvii, 158.
wl
F. H. Storer—Ferment-theory of Nitrification. 447
during ten days, and the contents of the bottles were then
tested as before for nitrites and nitrates. But no reaction was
obtained in either instance, with the exception of No. 12 (cot-
ton rags, etc.), which gave a faint coloration of a not very sat-
isfactory character. After the application of the test those of
the bottles which still contained a sufficiency of liquid were
re-attached to the aspirator and air was drawn through them
continually during another week, when the test for nitrites and
nitrates was again applied. But in no case was there any reac-
tion, with the exception of bottle No. 8 whose contents gave a
faint coloration.
tents of the bottles were then tested for nitrites and nitrates,
but no reaction was obtained in either case. To make sure
that the absence of the reaction was not due to any interference
caused by the presence of the peat or the chemicals, a fresh
portion of liquid was taken from each of the bottles, enough
nitrate of potash to amount to 0-001 gram of N,O, was added,
and the test for nitrites and nitrates was applied in the usual
way: reactions were now obtained immediately in every
instance. : :
In the light of the facts observed by Schldsing, the natural
inference from the results of these experiments is that the for-
mation of nitrates or nitrites in bottles Nos. 7 to 10 of the first
series of experiments was due to the presence of living organ-
isms which the peat had harbored, and that the absence of
nitrification in the other series of experiments is to be attrib-
uted to the destruction of the ferment-germs by the hot acid
with which the peat employed in these gh one had been
treated. It is to be observed, moreover, that the formation of
nitrogen oxides in the bottles Nos. 7 to 10 is in nowise out 0
448 F. H. Storer—Ferment-theory of Nitrification.
accord with the important fact observed by Warington, that
darkness* is essential to the action of the nitrifying germs, for
although my bottles were not shielded from cise’ Gay hans
the mixtures of peat and water which the tained were
practically dark-colored muds, not ill-fitted to Moles the germs
from the light.
It is possible of course that the colder weather which pre-
vailed during the later trials may have had an influence upon
their results; but if this be so, the fact must be counted as an
additional argument in favor of the ferment-theory. More-
that is needed to induce nitrification, the heating of the liquids
by day in the third series of experiments would have been suf-
he ie though both the strong heat and the cooling of the
nies would have tended to prevent the growth of
ee organism
the Coca of the ferment-theory, it would have been
well to control the meen: ew above given by trials with
mixtures of the purified peat and carbonate of lime, for peat
ich has been treated ah muriatic acid has always a slight
wed reaction, due I suppose to free humic acid, no matter how
thoroughly it may have been washed with water, and it is to
be supposed that this acid peat, devoid withal of phosphatic
and other saline matters, is not favorable for the growth of the
ferment. But as was said before, my experiments were made
to test the oxidizing action of certain chemicals, not to culti-
vate living organisms.
It may be added that I have not as yet found any evidence
* The following statement has a certain interest for analysts as bearing U
the stability of dilute solutions of — pps chloride. In February, 187 sy 7a
it was
noticed by my assistant, Mr. Lewis, solution of ammonium chloride which
had been prepared ten or twelve ase previously for use in connection with
Nessler’s test, by dissolving the salt at the rate of 3°15 grams to the liter, now
gave a strong reaction for nitrites, although f a solutions, made in
the same way from like ma gave no reaction. e old solution was con-
tained in a glass-stoppered bottle which was about cae filled by it, and it had
n kept most of the time in a as cupboard.
Acting on the supposition that the change of the ammonium salt to a
had been caused by the growth of some fungus in the liquid and that sale fun-
gus might pickers be Le at in other bottles in the neighborhood, I a as
many different specimens of moulds as could be found growing in the various
saline soltions apt kept in in th the laboratory, and, after sliding with pure water, "placed
them in a series of half-gallon bottles, into which had been poured from half to
ee
,
i
eo Pixie
J.W. Powell's Survey of the Rocky Mountain Region. 449
that solutions of ammonium compounds can be oxidized to
nitrites or nitrates by means either of ferric oxide, of black
oxide of manganese or of gypsum. I can say with Millon,*
that, in spite of all that has been written in favor of the oxida-
tion of ammonium by ferric oxide, “I owe it to truth to state
that though the most varied attempts have been made to oxi-
ize ammonia in the cold (i. e. in the wet way), by peroxide of
iron, they have all proved unavailing.”
I am indebted to my assistant, Mr. D. S. Lewis, for his care-
ful attention to the details of these experiments.
Bussey Institution, Jamaica Plain, Mass., April, 1878.
Art. LXV.—Geographical and Geological Survey of the Rocky
Mountain Region under the direction of Professor J. W. Powell.
Account of work performed during the year 1877.
[Concluded from page 358.]
was secured. : )
vey, prepared a paper on the tribes of Alaska, and edited other
papers on certain tribes of Oregon and Washington Territory.
map to accompany his paper, including on it the latest geo-
1 ination from all available sources. His long
residence and extended scientific labors in that region pecu-
liarly fitted him for the task, and he has made a valuable con-
t f
The volume also contains a Niskwalli vocabulary with extended
rammatic notes, the last great work of the lamented author.
n addition to the map above mentioned and prepared by Mr.
Dall, a second was made, embracing the western portion of
Washington Territory and the northern part of Oregon. The
map includes the latest geographic information, and is colored
sonian, and turned over to Professor Powell, to be consolidated
with materials collected by members of bis corps.
- * Chemical News, 1860, ii, 337, from Comptes Rendus.
450 oJ. W. Powell's Survey of the Rocky Mountain Region.
These papers form a quarto volume of 861 pages, entitled
Contributions to North American Ethnology, volume I, the
first of a series to be published on this subject.
Volume II, relating to the tribes of the eastern portion of
Washington Territory and the State of Oregon, was partially
prepared for the printer, but it was thought best to withhold
its publication until further materials were collected from that
region.
The third volume of the series has been published. This
relates to the Indians of California. Mr. Stephen Powers, of
small chieftaincies, speaking diverse languages, and belonging
to radically different stocks, and the whole subject was one of
Smithsonian Collection are published with those of Mr. Pow-
ers. The linguistic portion of the volume was edited by Pro-
fessor Powell.
sonable progress towards civilization, together with which in
_ Many instances their numbers have increased. No final publi-
J.W. Powell’s Survey of the Rocky Mountain Region. 451
cation on the subject has yet been issued, but he has read
papers before the Philosophical Society of Washington and
other scientific bodies, to invite the attention of ethnologists to
the subject. He has also been engaged in preparing the his-
tory and bibliography of the Klamath, Chinook, Wayiletpu,
Sahaptin, and other families of Oregon, and his papers on this
subject will appear in the second volume of Contributions to
North American Ethnology.
In March last, Mr. Albert S. Gatschet was employed to assist
in the study of Indian languages, and during the spring months
his time was occupied as an assistant in compiling the bibliog-
raphy of the North American languages. During the summer
and autumn months he visited a number of tribes in Oregon,
for the purpose of collecting vocabularies and grammatic notes.
On his way to the field he stopped at Ogden, where he found a
tribe of Shoshone Indians, from whom he procured a vocabu-
lary of about five hundred words.
In Chico, Butte County, California, he stopped one week, to
visit the Michépdo Indians, a branch of the Maidu stock, where
he collected linguistic material of value. From Chico he pro-
ceeded directly to the Klamath Agency, in Southern Oregon,
words from Modok Indians visiting Washington and New
York, and his work at the Klamath Agency was a continua-
tion of such study. Altogether he has collected a vocabulary
of about five thousand words, also many sentences and texts
on historic and mythologic subjects arranged with interlinear
translations. ‘ ;
The numerical system of this language 1s quinary,. and the
numerals above eleven have incorporat particles giving them
a gender or classifying significance, apparently based upon
form. The subject and object pronouns are not incorporated
in the verb; the personal pronouns differ from the possessive ;
and a true relative pronoun exists. An im} rtant character-
istic of the language is the use of prefix-particles in nouns and
verbs indicating form, and the reduplication of the first sylla-
ble, which is usually the radical syllable, for the purpose of
showing distribution. It is often equivalent to our plural. It
occurs in the singular of adjectives indicating shape and color,
in augmentative and diminutive nouns and verbs, 1n iterative
and frequentative verbs; and forms the distributive plural of
many substantives, adjectives, numerals, verbs and adverbs.
From the Klamath Agency, Mr. Gatschet proceeded to the
Grande Ronde Agency, in the northwestern part of Oregon.
On his way he stopped at Dayton, and made collections of
452 J. W. Powell's Survey of the Rocky Mountain Region,
Shasta and Umpqua words, from reliable Indians. On the
Grande Ronde Agency are found a large number of tribes and
remnants of tribes which were collected there after the Oregon
war of 1855-6; and with the exception of the Klikatats they
are all from Western Oregon. The following is a classification
of the linguistic stocks now on this reservation: Tinnéh, Silets,
Wayiletpu, Shasta, T’sinuk, Sahaptin, Selish, Modok and Kal-
apuya. The Kalapuya once occupied almost the whole extent
of the beautiful and fertile Willamette valley, and one branch
of this stock, the Yonkalla, even extended into the Umpqua
Mr. Gatschet also collected vocabularies and sentences of the
spilowing lepguazen. Shoshoni, Achomawi, Shasta, Wintun,
W: éssisi, Waska, Klakamas, Mélele, Nestucca, Yamhill,
ayuk and Ahantchuyuk. In the collection of all these
vocabularies, the “Introduction to the Study of Indian Lan-
Ne: prepared for the Smithsonian Institution by Prof. J.
W. Powell was us
Dr. H. C. Yarrow, U.S. A., now on duty at the Army Medi-
cal Museum in Washington, has been engaged during the past
year in the collection of material for a monograph on the cus-
_ toms and rites practised in the disposal of the dead among the
J.W. Powell's Survey of the Rocky Mountain Region. 453
North American Indians. To aid him in this work, circulars
of inquiry have been widely distributed among ethnologists and
other scholars throughout North America, and much material
has been obtained which will greatly supplement his own ex-
tended observations and researches.
During the summer some interesting work was done in the
examination of the stone graves of Tennessee, and valuable col-
- lections were made. Professor Powell has codperated with the
Institution in providing for a more thorough examination of
the archwology of the islands off the shore of southern Cali-
fornia. This exploration was made by Rey. Stephen Bowers,
of Indianapolis, Indiana, and his report will be published with
the papers of the survey.
A small volume, entitled “Introduction to the Study of
Indian Languages,” has been prepared. This book is intended
for distribution among collectors. In its preparation, Prof.
Powell was assisted by Prof. W. D. Whitney, the distinguished
philologist of Yale College, in that part relating to the repre-
sentation of the sounds of Indian languages. ew prelimi-
nary copies have been printed and distributed among gentlemen
interested in the study of Indian languages for such addition
and emendations as may be suggested preparatory to final pub-
lication. A tentative classification of the linguistic families of
the Indians of the United States has been prepared. This will
It is believed that the labors in this direction will not be void
of useful results.
was made of the Black Hills of Dakota, by Mr. Walter P.
Jenny, with ;
honorable Secretary of the Interior. On the return of the
the spread of civilization over a region inhabited by savages.
geographical and geological report was unfinished at that time.
This fi work a left in the hands of Mr. Henry A. New-
ton, his geological assistant, to be completed. On May 28th,
1877, at the request of Mr. Newton, the completion of the
454 J.W. Powell's Survey of the Rocky Mountain Region.
should visit the field again for the purpose of determining
certain doubtful points in the geological structure, and to in-
sert on the maps the position of the several towns and roads
established in that region since the discovery of gold, and Mr.
ewton was employed for this purpose. He had been in the
field but a short time when he was prostrated by the sick-
ness which resulted in his death. Previous to his departure he
completed his report on the geology of that country, and the
po A been placed in the hands of the engraver; the whole
embodying all the facts discovered up to that time. Thus,
happily, his work will not be lost. It is expected that his
report will be published during the present winter, in the
shape in which it was left by him.
The death of Mr. Newton makes a serious break in the
ranks of the younger and more active geologists of America.
€ possessed rare abilities, had much experience in field opera-
‘ions, and had received thorough and wise training, and his
work in other fields had exhibited his ability. But the great
work of his short life will doubtless be his report on the geol-
ogy of the Black Hills of Dakota.
During the past six years one branch of the work of the
survey has been considered of paramount importance, namely,
the classification of lands and the subjects connected therewith.
The object has been to determine the extent of irrigable lands,
timber lands, pasturage lands, coal lands and mineral lands.
In general the lands that are cultivable only through irrigation
are limited by the supply of water. There are some excep- -
tions to this. Where streams are found in narrow valleys or
run in deep cafions, the limit of agricultural land is determined
by the extent of the areas to which the water can be conducted
with proper engineering skill. In the study of this subject
interesting and important problems have arisen, an
many valuable facts have been collected.
From the survey of the timber lands one very important
fact appears, that the area where standing timber is actually
found is very much smaller than the areas where the condi-
tions of physical geography are such that timber should be
found as a spontaneous growth—that is, the area of timber is
but a small fraction of the timber region. The destruction of
timber in such regions now found naked, is due to the great
fires that so frequently devastate these lands: and the amount
of timber taken for economic purposes bears but an exceed-
ingly small ratio to the amount so destroyed. Hence the
Important problem to be solved is the best method by which
these fires can be prevented.
J. Rodgers— Observations on the Transit of Mercury. 455
Another subject which has received much attention is the
utilization of the pasturage lands; and still another, the best
methods of surveying the mineral lands for the purpose of
description and identification, that the owners of mines may be
relieved of the great burden of litigation to which they are
subjected by reason of the inaccurate and expensive methods
now in vogue.
Arr. LXVL— Observations on the Transit of Mercury. Letter
to the Editors from JoHn Rop@ers, Rear Admiral U.5.N.,
Superintendent of the United States Naval Observatory,
dated May 11, 1878.
Ir may interest your readers to learn that the transit of Mer-
cury, occurring on May 5-6, was very successfully observed
at the Naval Observatory, and throughout the country gen-
erally. Satisfactory observations of all the contacts were made
here, and good observations of the contacts have been reporte
from the observers of the United States Coast Survey in
Washington, and in different parts of the country. Reports of
observations of the contacts have been received from
observatories at Cambridge and at Ann Arbor, Professors
Pickering and Watson, kindly undertook the work of making
i ies: and a set of the instru-
photographs was the same as that followed in the case of the
transit of Venus. The dry-plate process Was, however,
adopted in the present case, in place of the wet-plate process
used in the transit of Venus. The great advantage of the
dry-plate process, if it can be used successfully, 1s evident.
The plates were all prepared here by Mr Joseph A. Rogers ;
and seventy-two plates were sent to each of the observatories,
where they were exposed and then returned here for develop-
ment. The same number of plates were exposed here by Mr.
accurately ; and we think they will furnish data for a very
exact determination of the latitude and longitude of the planet
photographing the transit. These gentlemen report a snow
storm during the early part of the day, but clear weather in the’
afternoon, during whvol a good number of photographs was
ured.
Our experience in photographing transits of planets, and in
measuring the photographs, indicates that while the American
method is correct in theory, the apparatus needs some change.
In order to obtain good measures, the picture should be sharp,
and the exposure short. It is probable, therefore, that the
reflectors, which now lose about nineteen-twentieths of the
light, will have to be changed.
_ A comparison of the observations of contact with the
eee of the American and English Nautical Almanacs
shows that the English Almanac is much nearer the truth.
Since the ephemeris of the American Almanac is based on
Leverrier’s old theory, and that of the English Almanac on his
recent one, the result of the present observations appears to be
a confirmation of Leverrier’s theory with respect to an intra-
mercurial planet.
United States Naval Observatory, Washington.
S. P. Langley—Transit of Mercury of May 6th, 1878. 457
4
Art. LXV1L—Transit of Mercury of May 6th, 1878; by S. P.
LANGLEY.
in their natural colors and relative brightness.
I had the fortune, at ingress, of an unusually blue and trans-
parent sky, and aided by this, saw with the polarizing eye-piece
the entire disc of Mercury outside the sun about one-half a
minute before first external contact. Presumably it might
have been seen even earlier, had not time been lost in searching
for it, through lack of means to designate the precise position-
angle, the position filar-micrometer not being adaptable to this
eye-piece. After a pause to verify the reality of the phenome-
non by revolving the eye-lens, etc., the chronograph key was
struck at 21 52m 398-45 Allegheny mean time, to record the
observation. As this was really made earlier, and the disc was
seen throughout its circumference, it seems clear that the
coronal back-ground is bright enough to produce this effect at
least fifteen seconds of arc from the solar limb, and in spite of
the atmospheric glare. .
As a partial substitute for the filar micrometer, there was in
the field a glass reticule, ruled (by Prof. Rogers, of hapa
in squares whose sides represented here 15°’8, and this enable
—not a measurement—but a fair comparison to be made of the
apparent size of the planet before and after it entered on the
sun. The contrast was striking, as on a back-ground very little
brighter than itself its diameter was, if anything, greater than
one of the sides of these squares, while as soon as It entered on
the sun it seemed to shrink by more than one-fifth of this.
First external contact was noted on the chronograph at 21» 52™
505-48. First internal contact was noted when the sunlight
could be seen unmistakably between the disc and limb at 21°
55m 478-95, These entries, 1 believe to have been made in both
cases nearly two seconds late. The limb just at second contact,
was steady. I saw no “black drop” or “ ligament”
As the dise advanced on tbe sun it was closely scrutinized,
Without at any time any “bright point” or “annulus” being
458 S. P. Langley—Transit of Mercury of May 6th, 1878.
spot nuclei, being gray, slightly inclining toward a blue, like
; t may be that this
measurements with a Jamin photometer were unsatisfactory.
Subsequently, by another method, a trustworthy value was
fixed fora minimum. It was thus found that the light actually
received on the paper apparently from the so-called “ black”
body of the planet, at any rate exceeded eight per cent of that
from direct sunlight, and measures taken by the thermopile and
pcpbbveeasn showed that heat was coming from the same
irection.
* Monthly Notices R. A. S., vol. xxix, p. 26,
+ I presume that even in absolutely perfect definition there would be theo-
- al, ae prety Seen
0. C. Marsh—Notice of a new Fossil Mammal. 459
It is evident, for instance, that from the facts here stated we
can estimate, photometrically, the intrinsic brightness of the
corona, since it was undoubtedly this, acting as a back-ground,
which enabled the planet, though itself involved to a calculable
extent in atmospheric glare, to be seen before it reached the
solar limb.
The observations were interrupted by haze in the afternoon
and egress was so nearly invisible that the apparent times of
contact are not worth giving.
Allegheny Observatory, May 7, 1878.
Arr. LXVIIL—Fossil Mammal from the Jurassic of the Rocky
Mountains ; by Professor O. C. MaRsH.
ONE of the most interesting discoveries made in the Rocky
Mountain region is the right lower jaw ot a small mammal
recently received at the Yale College Museum. The specime
was found in the Atlantosaurus beds of the Upper Jurassic,
and the associated fossils are mainly Dinosaurs.
This specimen is in fair preservation, althou sh most of the
teeth have been broken off in removing it from the rock. The
as the corresponding molar of Chironecies variegatus Illiger.
The angle of the jaw is imperfect, but there are indications that
The principal dimensions of this specimen are as follows:
Space occupied by seven posterior tebth cc occl. ico
Depth of jaw below last molar -------- -------- “4
Transverse diameter ..------- ---- -------+---- 1°8
Height of crown of penultimate molar... 45+ i
Transverse diameter ------------- ---------"-- 15
The present specimen indicates an animal about as large as
a weasel. It is of special interest, as hitherto no Jurassic
mammals have been found in this country.
Yale College, New Haven, May 13, 1878,
460 S. Calvin—Shale at Independence, Towa.
Art. LXIX.—On some dark Shale recently discovered below the
Devonian Liimestones at Independence, Iowa; with notice of the
Fossils at present known to be in it; by S. Canvin, Professor
of Geology, State University of Iowa.
THE Devonian deposits of Iowa, as now known, may be
roughly represented by the annexed diagram, in which 1 indi-
cates the position of a member of the
3 | group recently discovered at Independence,
consisting of dark argillaceous shales wit
2| some thin beds of impure, concretionary
limestone. It has been explored to a depth
1| of twenty or twenty-five feet. No. 2
represents all of what is usually included
under the head of the Devonian limestones of Iowa, and is
made up largely of limestone with some associated beds of
light-colored shales ; estimated thickness, 150 feet. No. 3 isa
od of argillaceous shales exposed at and near Rockford, Iowa,
and is referred to frequently as the Rockford Shales. It
abounds in fossils, and weathers, on exposure, into a stiff clay
that has been utilized in the manufacture of brick; observed
thickness, seventy feet.
Until recently, Nos. 2 and 3 of the above section were sup-
pest to make up the entire thickness of Devonian rocks in
owa. No. 2 not only varies, as already indicated, in lithologi-
cal characters, but the grouping of fossils differs widely in
equivalent of the New York Chemung. On the other hand, Dr.
C. A. White, Geology of Iowa, 1870, vol. i, p. 187, is of opinion
S. Calvin—Shale at Independence, Iowa. 461
x ese, two are not
determined and five others are new to science, but the chief
interest attaches to certain species that have hitherto been
known only from the shales of bed No. 3, near Rockford,
Iowa. For the purpose of indicating the relationship of the
new shale to the other Devonian deposits of lowa, we shall
arrange the specimens in three groups, using my manuscript
: ’
era subumbona Hall.
II. Species ranging through all the Devonian deposits, and
so common to beds 1, 2 and 3: Aérypa reticularis Lin.
_ IIL. Species common to beds 1 and 3, but not known to oecur
in the intervening limestones: Strophodonta vata, D. Sp.,
S arcuata Hall, 8. Canace Hall and Whitfield, S. reversa Hall,
Am. Jour. Sct.—THIrD Serres, Vou. XV, No. 90.—JuNz, 1878.
31
462 . Joseph Henry.
Atrypa hystrix Hall,* and Productus (Productella) dissimitlis
Hall.
It is an interesting fact that of the twelve determined species,
six occur only in the shaly deposits at the opening and close of
‘the Devonian, ac eg rd these deposits are separated by
150 feet of limestones. Only one species is known to
from the lower shale into she uriadiend above, and even that
appears under a form so altered that specimens from the two
beds may be distinguished as readily as if they were distinct
the Atrypa reticularis of No. 1, also finds its nearest representa-
tive, not in ws limestones immediately above, but in the
shales at Roe
itions more favorable to them a iy the deposition of the
Rockford Shales
The intimate felation between the two extremes of the group
ean but strengthen the conclusion of Dr. White, that all the
Devonian strata of Iowa belong to a single epoch.
JosepH Henry, LL.D.
Proressor HENRY died, on the thirteenth of May, 1878,
at his home in the Smithsonian Institution, Washington City.
For over half a century Professor Henry has been one of the
remost men of science in the United States ; and his name is
well known in all countries where science »: cultivated. He
was, it is believed, the last of that band of the older men
of science in America, dating from the last century, baving
been the associate during his ato of Hare, Silliman, Bache,
— and others of the sa epoch. His eminent attain-
ts and important niisaweczion early gave him a well earn
reputation as an original heresy Later his skill as an
* The fo as A. hys ffers conspicuously from the
form described in the hte gee Towa, 1858, bos i, part 2, p. 515, under the name
ie te ale i is last form is very abundant in tl
Independence Shale are
The specimens cal with |
the form presented by this pening in the Rockford s one For eoomondian of
nnual Report of Board
this specific name to this special form. see Tw:
of Regents on New York Stato Cabinet, p Hr gesepere
Joseph Henry. 463
administrator of great public trusts in the interests of science,
and his rare personal qualities, made him universally respected
and beloved. His noble presence and cultivated bearing
were always conspicuous, however distinguished the pate
about him, and manifested truly the high morale which
him a dignity rarely equalled. His genial reo not Jenminghed
with a certain reserve, will never be fo n by those who
enjoyed his friendship or came into familiar wai with him.
Fortunately, a fine portrait painted quite recently, by order of
the trustees of the Smithsonian Institution, will eon his
well known features and render them familiar to posteri
Professor Henry was born December 17, 1797, at AToahy
New York, where also much of his early life was “passed, e
had at first the advantages of only a commo ool educa-
tion; later, after two years of work asa aaiieres he came
under the training of the Albany Academy, where he developed
ree of mathematical talent which, in 1826, led to his
Selection for the duties of instructor in mathematics in that
institution. Prior to this, having had some experience in the
which A tieaect was ‘saa ted as the radix—a contrivance
which is hardly known, even by name, to the present genera-
tion of chemists. Thus, while Professor Henry’s original con-
tributions. to science were chiefly physical, his first scientific
work was in the department of chemistry. His work with Dr.
Beck enabled him, after his removal to Princeton—where he
became Professor of Natural Philosophy in 1832,—to take up
the duties of the chemist, Dr. John Torrey, when that well
known teacher was disabled for a time by ill h
It was in the interval, between 1828 and 1837, wen the most
important work of his life was accomplished in the line of
strictly scientific research. These results are chiefly reco
in the Transactions of the sen Institute, the volumes of
this Journal for the period, and the Transactions of the Ameri-
can y Heian a His ci : Gaiaiatigne to Electricity
and collected in a separate volume in 1839.
The aanlyein of shone important reseitreies; and the >isdustior
464 Joseph Henry.
of the questions of priority connected with them, will be the
duty of the academician to whom shall be assigned the prepara-
tion of a memoir or eulogy of the distinguished author.
Without assigning dates we give the following brief enume-
ration of his memoirs and discoveries, taken from a communi-
Witt, the organization of the meteorological system of the
State of New York.
. The development, for the first time, of magnetic power,
sufficient to sustain tons in weight, in soft iron, by a compara-
tively feeble galvanic current.
-he first application of electro-magnetism as a power, to
produce continued motion in a machine.
. An exposition of the method by which electro-magnetism
might be employed in transmitting power to a distance, and the
demonstration of the practicability of an electro-magnetic tele-
graph, which, without these discoveries, was impossible.
6. The discovery of the induction of an electrical current in
a long wire upon itself, or the means of increasing the intensity
of a current by the use of a spiral conductor.
. The method of inducing a current of quantity from one
of intensity, and vice versa.
8. The discovery of currents of induction of different orders,
and of the neutralization of the induction by the interposition
of plates of metal.
; substances.
12. Investigations on molecular attraction, as exhibited in
liquids, and in yielding and i
_the theory of soap bak bak
= called upon to investigate the causes of the bursting of the
great gun on the United States Steamer Princeton.]
EGE eat ce Nor + 9 ot eer 4
Joseph Henry. A465
13. Original experiments on and exposition of the principles
of acoustics, as applied to churches and other public buildings
14. Experiments on various instruments to be used as fog
signals.
5. A series of experiments on various illuminating materials
for light-house use, and the introduction of lard oil for lighting
the coasts of the United States. This and the preceding in his
office of Chairman of the Committee on Experiments of the
Light-House Board.
16. Experiments on heat, in which the radiation from clouds
and animals in distant fields was indicated by the thermo-elec-
trical apparatus applied to a reflecting telescope.
17. Observations on the comparative temperature of the sun-
spots, and also of different portions of the sun’s disk. thes
experiments he was assisted by Professor Alexander.
18. Proof that the radiant heat from a feebly luminous flame
is also feeble, and that the increase of radiant light, by the in-
troduction of a solid substance into the flame of the compound
lowpipe, is accompanied with an equivalent radiation of heat,
and also that the increase of light and radiant heat in a flame
of hydrogen, by the introduction of a solid substance, is attended
with a diminution in the heating power of the flame itse]
19. The reflection of heat from coneave mirrors of ice, and
its application to the source of the heat derived from the moon.
0. Observations in connection with Professor Alexander, on
the red flames on the border of the sun, as observed in the
annular eclipse of 1838.
Experiments on the phosphorogenic ray of the sun, from
which it is shown that this emanation is polarizable and refran-
gible, according to the same laws which govern light.
to the philosophical hall in the attic, on which was screwed
firmly a rude imitation of a fiddle at the top near the ceili
while to the other end negro Sam bad a real fiddle attach
466 Joseph Henry.
Ona bell signal from the Professor, Sam would saw away with
his bow in the cellar, the Professor calling the attention of the
class to the weird music his fiddle discoursed in the lecture-
room. On these occasions Professor Henr always remarked
To the above enumerated papers should be added an impor-
tant series of communications, made chiefly to the National
Academy of Sciences during the past four or five years, upon
the laws of acoustics as developed in the course of investiga-
fog-signals. These investigations have been carried forward
close personal attention during many weeks of each season.
?
of electricity, as exhibited in the thunder-storm.
_ Professor Henry remained at Princeton, in the chair of Nat-
ural phectiag sa until his removal to Washington in 1846, to
e duties of Secretary of the Smithsonian Institu-
Favored by nature with a vigorous constitution, he enjoy ed
__ through his long life. almost uninterrupted good health. His
cial labor which fell to his share as the head of the Smithson-
ian Institution ; of the Light-House Board; of the National
oe
Fo Bl ee ee eae ot = eel ter, ie et eae |) Ty ts
- Chances of investinents,
Joseph Henry. 467
Academy of Science; and as the adviser of the Government in
matters of science.
It was while engaged in discharge of certain experimental
work on Staten Island last December, connected with the pho-
tometric laboratory of the Light-House Board, that he experi-
enced a partial paralysis, which yielded soon to treatment, but
was doubtless the precursor of the nephritic attack to which he
succumbed, In April he presided at the opening meeting of the
session of the National Academy of Sciences held in the rooms
of the Secretary of the Smithsonian, and submitted an address
to his associates, read by the Home Secretary, recounting with
touching simplicity his recent decline of power, and express-
ing his desire to be relieved from the cares of the office of Pres-
ident. Asa mark of affectionate respect, the Academy unan-
imously requested him to retain this post during his life—leay-
ing the duties to be discharged by the Vice-President. It was
on this occasion that the announcement was made to the Acad-
emy, by Professor Henry, and, subsequently, in fuller details,
by Professor Fairman Rogers, the Treasurer, of the creation of
an endowment to be called “the Joseph Henry fund.” This fand
consists of forty thousand dollars, securely invested, the income
of which is for the support of Professor Henry and that of his
family, during the life of the latest survivor. Afterwards the
fund is to be transferred, in trust, to the National Academy of
Sciences, the income to be forever devoted to scientific research.
No more graceful and well-merited tribute of respect and affec-
tion was ever bestowed upon a man of science, by the sponta-
neous offerings of personal friends and associates. Alas! that
affairs at the seat of government. By force of his earnest
determination that the will of the Testator should be carried
is large t
original fand paid over to the United States. The policy upon
468 Letter from B. A. Gould.
reports. That this long period of activity, over thirty years,
devoted so largely to work almost purely administrative, was a
Severe tax upon a man of Professor Henry’s great productive
power and ability in original research can hard] y be questioned.
On the other hand, it rarely falls to the lot of any man of
science to do so much for the best interests of the entire body
of scientific workers, or to succeed so well in securing respect
and methods. This is conspicuous in many ways in the his-
its guidance.
rofessor Henry leaves a wife and three unmarried daughters,
who have been assiduous helpers in the scientific work of their
father, making good to a degree the loss of an only son, whose
death in early manhood, was a sad disappointment of parental
va and youthful promise.
rofessor Henry was buried May 16th, in the Rock Creek
governmental explorations during the past twenty years, under
d
Cemetery, near Georgetown, D. C. The President of the
United States, the cabinet officers, diplomatic corps and mem-
of Congress and of the Natioual Academy, were among
the mourners. B. 8.
Art. LXXI.—Letter to the Editors from Dr. B. A. Gout, of
the Cordoba Observatory, dated Cordoba, March 20, 1878.
I Ave before me the first part of three different letters to you,
which I have begun during the last eighteen months, but the
ceaseless pressure of labor in collecting and arranging materials
during this interval has left little opportunity for elaborating, and
_ tions are ‘Tned. the part which remains is but the computa-
Hon and publication of these results, and is going forward
_ Fapidly as the nature of the case permits.
‘
Letter from B. A. Gould. 469
Meteorological Office, is already printed—the only one yet pub-
ies—and
results to which I allude, and which are there discussed in detail.
e difficulties which have attended previous
be in other places,
Bu ires.
the wind, and deducting its effects from the mean tem
hi
of the sun-spot so closely as scarcely to leave a ing more to be
d the
470 Letter from B. A. Gould.
Thus if we denote by 7 the relative number corresponding to
the mean s inpeniarcs as observed, to have been 16°°47 in 1870,
and 17°°51 in 1875, while those which result from the formula are
16° shee sae 17°49 memset. The difference 0°°16 for the first
and the excessive deflection of the mean direction of the wind in
1870 afford what seems to me a sufficient explanation of the rela-
tive largeness of the residual.
It is manifest that if the variations of the terrestrial tempera-
d
ndence observed bet
variations of the magnetic declination, all necessity for assuming
any direct and transcendental o-eimeti wid gti this latter and
It is a source of regret that 1 have oot at disposal here any
i nn me t
which the investigation may be made, viz: Bahia Blanca, just to
the north of the Patagonian coast, and this I intend to investigate
as soon as time and gc ascercvee
rai
or in other in that component of the mean annual direction
belonine is spepeodionias to the meridian. Se ag conan without —
fon.
periods are respectively a quart er saa the third part rt of pee
elr existence
2 es Wg and yet more “marked cycle shows itself in ate
frequency of the storms, which are so well known and charac
teristic of the La Plata. Whether we consider the annual num-
ber of winds of force five, or six, or seven and ut wards, or the
mean supnal. force, the same result manifests itself, viz: a periodic
Letter from B. A. Gould. 471
ears, The form of the corresponding curve is such
to that comprised in the series of observations, that
we fixed with accuracy. But I am inelined to
~_— it will be found not to differ much from twenty-two years,
n which event we have still another case of near commensura-
bility with the mean period of the sun-spots.
s regards the astronomical work there is little to communicate
as yet. The Uranometry is not yet egies and Iam fea
that it was a mistake to undertake the printing in this lien.
ell ele
remedy these difficulties, but it is of course at_ much expense of
ergy: Th
drawings having been obviated by the skill and assiduity of the
hotolithugrapher, Mr. ere Bien of New York. My first
assistant, Mr. John M. Thome, to whom more than to any other is
ue w at accuracy the iereaniastons of magnitude may possess
attended to the proofs. He returned a few weeks since, bringing
with him some advanced copies, with which I am quite satisfied.
The Atlas consists of thirteen charts, on the scale of a globe of
is added a fourteenth as a sort of a Index-Map, to show the limits
of the individual charts, the course of the Milky Way, and the
general distribution of the stars. _ is sbi a Se course comprises
ing as those between the meri dina ns of right ascension increase,
The configurations are necessarily distorted, but the degree of
aggregation of the stars is correctly given.
S- As mentioned in former letters I have ventured upon rather a
eo bold reformation of the boundaries of the constellations, whieh I
ae earnestly hope may find approval with astronomers gene rally.
Wherever possible, meridians and parallels (equinox of ght
2 have been employed as boun lines, and in other
circles so far as might well be. Yet the principle has been i
lously followed that no important star, and none habitually
designated by a Greek letter, should be t ransferred to a different
constellation. By aslight sacrifice of this principle the symme |
of the adopted boundaries might have been essentially increas
= yet I have preferred to err upon what the safe side,
: The text will be in English as well as se 05 but the Latin
names of the constellations have been n preserv e only basis
for international accordance in nomenclature.
SOUS aceecpep pare MAU oe eee tars
472 Scientific Intelligence.
to have been felt in neither instance by persons in this vicinity.
ne of these cases was at the time of the great earthquake which
destroyed the town of Iquique, and produced so much destruc-
tion along the coast of Peru, Bolivia and Northern Chile. The
other was at the time of the severe mene ka ae ndoza. The
moments at Cordoba were of course very ot ately given
by the clock itself, and accounts caneally obt eae from the
points of chief disturbance give the same result as former
on
occasions, viz: that the interval of time re se the manifesta-
tions at these Siri and at Cordoba was less than the snare
of the watches. This you may remember was the case
sa when the shock was eee y felt in Cordoba, althou zh the
tele
nly a da
two previous, and the time as shown the dial agreed with that
Ww WW
can be measured without special preparation and sani seren
SCIENTIFIC INTELLIGENCE.
J. CHEMISTRY AND PHysIcs.
1. The sion of the Solid Elements a Function of their
ctiong weight. “since all gases, ve similar physical conditions,
contain in saat umes the same number of molecules, they
must ‘al have the “ists coeificising of expansion, because this
eir atomic weights. The quotient of the density of any such
postmen referred to water as unity, divided by its atomic vee
e
gives the space occupied by one atom of that element. If
ratio if this value be the Seetoat of expansion be obtained,
ing re S appear, as is shown in tabular form for
some s§!
twenty-six solid Savahita: In the first column the symbols are
en, in the second the density, i in the pitt the ig thee So
in the fourth the expansion-coefficient expressed in parts im
hundred million at 40° C., and i in the fifth ie ratio of this to thé
to atomic Vouk Thes se Saouite coefficients often
| iw Simple relizotis for seca Be allied elements; thus the value is
Chemistry and Physics. 473
the same for iron, cobalt and nickel, the numbers for arsenic, anti-»
mony an ismuth areas 1:3: 4, those for zinc and cadmium as 2: 3,
ete; If shaob coeflicients be regarded from the stand point of
Lothar Meyer’s law of the periodicity of the properties of the ele-
ments, and be graphically represented as a function of the atomic
weight, they give a curve similar to that of the atomic volume, in
which members of natural families have an analogous position.
Hence the author concludes that the absolute expansion of the
atom is a periodic function of its atomic weight.— Ber gyorg hem.
os xi, — April, 1878, . Bs
‘0 ew Metal, Gallium.—In connection wish Jou
aaa oc DE BoisBaupRAN, the —— of gallium, has
worked up the residues obt ained from 4,300 kilograms of the
Bensberg zine blende, to obtain more e of the hew metal.
blende was first pulveriaed and varie roasted, the product treated
te times, the spectroscope ing — to detect the metal,
In this way, the gallium became concentrated in a residue weigh-
ing 100 kilograms. ‘This was dissolved in sulphuric acid, purified
with hydrogen sulphide, and treated with ammonium acetate, the
25 being continued. ‘The zinc sulphide thus precipitated, carried
o . .
ram, Purified ae vd of gal aa a cloth, agitating with
ee and ak oe tt whe obtained as a hard,
a latinum wire havi oe a bit of solid eee on ne Pe pers
shag erystals are obtained, their summits modified by the basal
planes. Gallium leaves a bluish y mark on paper, is perma-
gra
nent in the air, remains brilliant even in boiling water, but
tarnishes slightly in aerated water. In fusion it is white like tin
or silver, but becomes blue-green on solidifying. Chlorine attacks
it readily, evolving inion heat and producing a well crystallized,
474 Scientific Intelligence.
very fusible and — — 0 a pure and deli-
quescent. Bromine acts less pow y, giving rise to a white
bromide, and iodine a white ibdide, both of iiich resemble the
chloride. The atomic weight the authors determined to be 69° 9.
Durr, —— received a portion of the metal, has undertaken
: and to be
covered with a bluish gray ellicke, At a bright red, this pellicle
is thicker, a feeble sublimate being formed. Treat ed with strong
nitric acid at 40° or 50° , it dissolves ; and the solution heated to
110°, loses nitric acid. Redissolved in water, evaporated to a
63°8 per cent in weight, thus proving it to be a nitrate of the
sesquioxide, At a higher temperature the nitrate melts, decom-
ite fri
ermangan. nee is ioc baby a rata salt ; a view a euieiet
y the fact fe it does not form an ammonium alum as does the
sesquioxide sulphate. At a bright red heat, ae nae sre reduces a
= n of the oxide to the metallic state—C. F., lxx —_ wi
577, 720, 756, Feb., March, 1878.
3. On Dime eth yl-ethylene, bape | Butylene.—The aa ie
of co , as is well known, is a mixture in variable proportions
of active or aiiviiecthyEStiiyt alcohol ch | CH—HH, OH and
inactive or isopropyl-ethyl alcohol cH Le CH—CH, —CH, OH.
Dehydrated by zine chloride in the ordinary way, it furnishes an
“cea re consisting of four different bodies: two soluble in
peed woid dil uted — = its volume of water, e this
tied the ordinary process by placing the zinc oe about 500
grams, in ee spacious metal 4 a — it in a gas furnace to full
fusion an d running in a thin stream of amyl alcohol, the “—
a ina pind worm. The amylene on
‘product, boiled between 35° and 38°, re com-
arias aioe by bromine, and with the exception of 3 or 4 per
cent, consisted of isopropyl-ethylene / CH, * | CH- CH=CH,, pro-
duced from the corresponding aleohol. The associated ethyl
methyl-ethy! alcohol as well as the admixed propyl and butyl
aleohols came over sierra Bat small sceminiases of a deg?
, diamylene only being isolated.
Chemistry and Physics. 475
Wishing to try this method with butyl alcohol, in order to
obtain normal butylene, Lx Bet and Greene allowe d this alcohol
C
mixed with traces of OH Br CBr. 8 No ethyl-vinyl
was formed in the reaction. Treated with sodium the reaction
was violent, and the products collected in hydriodic acid yielded
25 secondary butyl iodide, CH ,—CHI-~ CH, —CH,, thus prov-
two normal butylenes, i. e., those in which the carbon atoms are
united to no more than two others; one of these is ethyl-
vinyl, CH,~CH, —CH=CH, vee the other dimethyl-ethylene
CH, _CH=CH= ~CH ,. Upon e hypothesis. that in es
with a hydracid, the hydrogen ov the haloid play the
as the hydrogen in the saturated molecule and hence theta all the
hydrogen atoms attached to the same carbon atom have the
same value, both these bodies should yield the same hydriodate
CH, —CH, —CHI—CH, ; while if the hydrogen of the HI hoe a
different value, the two hydriodic compounds will be isomeric.
Preparing carefully the two bodies the ey were found to be identical
in properties, both boiling at 118°-121", and both yielding a buty-
lene by the action of ete potash which gave a bromide dis-
oo einer ee d 160°.—C. &., Ixxxvi, 488, Feb. ; spas
Soe. Ch., Tl, xxix, 306, ‘Apri; 1878.
jo Chemie al P-Composistin of Oil of Tansy and Oil of wale
—Bruytants has submitted to proximate analysis the oils
of cay and of valerian The former is a mobile yellow liquid,
of sp. gr. 0°923 at 15°, begins to boil at 192° and distils Panel.
between 194° and 207°, the thermometer rising finally to 270°-280
leaving a resinous mass about a tenth of the whole. Treated
to which the vapor roti 5°07 corresponds; it is thus an isomer
urel cam re y t iw action mt the acu hydride
ahead Ss a Ort s20 by abstraction of H,0, it gives
eym roHdia, by action of —, chloride, tanacetene
dichloride, "tanacetene mniancblotdenad cymene, and with ammo-
476 Scientific Intelligence.
nio-silver nitrate it gives the sages characteristic of an aldehyde,
Oxidized with chromic acid i t gives acetic and propionic acids,
with a it — ca mpborie acid. The eee. of the oil not
pght. 7. GHO,, C,H, .C,H,0,; Croll Cs H eGaant (t) ethyl:
borneol oxide, C, Hy .O.C, tha — Ber. Be ri. Chem. .
449, March, 1878
Panereatie est N has succeeded by the pion of
the pean ine ferment u ve eo blood fibrin, in preparing hyp
xanthin an ably also xanthin itself. ormer has
easiest: mes as a ee of putrefaction hitherto.— Ber.
ek Chom hem. Ges., xi, 574, April, 1878, eB
8. The present Condition of Sa a Meteorology. —Pataiert,
the Director of the observatory upon Vesuvius, has published in
the Atti della R. Accad. di Napoli, VII, p. 1-20, 1877, a resume
of his observations upon the electricity of the air, which he has
conducted during the past twenty-seven years e also gives a
description of the apparatus which he has found best suited to his
purpose. The electrometer resembles, at first sight, that of Dell-
man; it differs, however, essentially from the latter. The suspen-
sion of the needle is bifilar and the repulsion between the fixed arm
and the needle is not due to the repulsion of two bodies charged
by conduction to the same amount, but is the result of induced
cha
by means of a minnaa The chief peculiarity of the conductor
consists in this, that it ends in a plate twenty-seven centimeters in
diameter, and the connection with the electrometer is broken just :
as the conductor reaches the limit of the height to which it is
raised, which is about 1°5 meters, :
ith feeble electrical condition the first swing of the needle is
the double of its final deflection. With large differences of
potential the fall ¢ of deflection is less. This diminution of indica-
sean electroscope an
The ada ‘lieve that
Chemistry and Physics. 477
air over the apparatus. Si a ohana upon the
observatory of the University and at t odimonte in Naples,
also at the observatory upon Vesuvius. ge mse distant observa-
tions upon the little St. Bernard and in Moncalieri have impressed
the author with the belief that with dry clear air, in which the
pe eeten of + electricity is regular, the strength of the influ-
nee diminishes with increasing height.—Beibldtter Physik und
‘Chemie, vol. ii, no. 3, i 5. us
10. Floating Magnet —Nature, for May 2, contains a
3 Sir William homens son, in which he observes that Professor
a
a: iootog: sonata ee Professor A. M. Mayzr.
(From a ag er to the Editors, dated South Orange, New Jersey,
ay 21, 1878.)—I was much gratified to cate that my experi-
interes
covered a week or agi apr I sent you the Aes note shuns these
experiments, published on page 276. These laws are as follows:
the configurations of the floating magnets - divided es prim-
ary, secondary, pares quaternary, etc., classes, and the con-
figurati ons of one class form the ” nuclei to th
following are the primary configurations :
Am, Jour. 8c1.—Taimp = ey Vou. XV, No. 90.—Junz, 1878.
478 Scientific Intelligence.
The configuration found of 9 magnets begins the secondaries ;
and this configuration has 2 for its nucleus. The secondaries
have for nuclei the stable primaries, i. e. pachlaesedcts numbered
2, 3, 4, 5a, 6a, 7 and 8a. The tertiaries have the secondaries for
nuclei ; the quaternaries, the tertiaries, ete.
the configuration be made with the superposed magnet at a
constant vertical oe it will be a — _— the same
II. Grotocy anp MINERALOGY.
1. Supplement to the Second Edition of Acadian Geology ; by
J. W. Dawson, LL.D., F.R.S. 102 pp.*—This publication con-
tains the new matter added to the third edition of “Acadian
Geology,” just issued ; and which is published separately in this
form for o~ _— of those who alre ady possess the second edi-
tion. It reviews the new facts which have been discovered in the
Maritime Peesurs of the Dominion of Canada since 1868.
ginning with the later deposits, the author endeavors to vindicate
by new facts his former conclusion that the cold of the Glacial
eae was not connected with a a glacier, but with
ocal glaciers on the higher lands and ice-drif ft by Arctic currents
over the plains, then en weee se nee the Post-pliocene
deposits as follows, in ascending ord
(a.) Peaty sevréetriat surface schcnee = bowlder clay.
‘a Lower stratified gravels and sands.
{e. stare elay and neater sands with bowlders. Fauna,
present, extremel
(d.) kiwis] Austins laclay, witha se Eon number of nthe oe Arctic shells,
such as are now found only in perm tly ice-laden
(e.) Upper indd clay and sand, or ada: ron Oe holding many
ote or boreal shells similar to those of the Labrador
few littoral shells, of bore
After some notice of the Trias, aksemabety developed in Prince
Edward Island, where it has afforded the remains of one Dinosau-
rian Reptile. and several land plants, and which in Western Nova
Scotia is so remarkable for its great. a beds, a large spac
is devoted to the Carboniferous, and more especially to the recog-
‘nition of an Upper “ Permo-carboniferous ” or perhaps truly Per-
* New York: Van Nostrand. We are indebted for this notice to Dr. Dawson,
the author of the work.
tp
(f-) demic: sand and gravel, send ee or with a
r Acadian types.
Geology and Mineralogy. 479
mian member, pent rh Ppa vl of red sandstones, and hold-
ing a somewha t p ora akin to that of the Lower Permian
of Europe. Deta ‘ls sate illustrations are also given of new s
of Batrachians, Fishes, Insects, and Crustaceans, recently discov-
ered, and an ana ysis. and comparison with other countries, is
made of the remarkable develupment of the Lower Carboniferous
series of Nova Scotia and New Brunswic
After a short notice of the Devonian, which, in the region re-
ferred to, is chiefly remarkable for its rich flora, in the main: dis-
tinct from that of the Lower Carborniferous, and now numberin
125 described species, the author proceeds to discuss the diffioul
ties attending the study of the Silurian and Cambrian formations,
in a region where they are much disturbed and a and asso-
ciated with igneous beds of very varied character. On this sub-
ject he remarks:
“In the Acadian Provinces, as in some other parts of Eastern
America, the great igneous outbursts, evidenced by the masses
and dykes of granite which cut the Lower Devonian rocks, make
a strong line of distinction between the later and older Paleozoic.
here of these series are also , often very irregular in
tribution, and there is little to distinguish mire from each pare
— when their ages ma circum-
ANCES 0) many y difficulties to the élshaifieation of all the pre-
Decmiae rocks of Nova Scotia a and New Brunswick, difficulties as
et very imperfectly overcome.”
I 4 tig seemomar and in Eastern Maine, it appears that the
me es Upper Silurian rocks are capped by felsites, chloritic
schists and agglomerates of great berctagin- me having an aspect
not unlike that of the older ioe while in _— Nova
Scotia bag rocks appear arg hana the st 4
Siluria all the ai - en the Low eects Silurian pe
seems om ego been alncunseaied by tbs of similar a7
‘
480 Scientific Intelligence.
capic rocks, constituting, with a series of avenge metalliferous
slates, the “ Cobequid group” of the author, and resembling much
more the Skiddaw and Borrowdale formations of the English
geologists, than the contemporaneous Lower Silurian groups o
inland America. There are, however, Leng ee points of resem-
blance sti these paculinn Silurian rocks o cadia
Provinces and those of New England, saat her. constitute a re-
uuilcabie’ ius of the difference that may obtain in contem-
poraneous deposits belonging to areas of quiet aqueous sedimenta-
and of igneous activity. They show very clearly how unsafe
it may be, without proper whi ie to apply the geological types
of one area to those of anot
Below these peculiar Silurian rocks, are thick deposits of Cam-
brian age, on the whole less modified by con temporaneous igneous
—. and in some places richly poor me In Cape Breton
ere have recently been recognized fossils indicating
Carebrian horizon, resembling that of the ‘English i hos
Below this is the Acadian series, so rich in Conoe
and other forms of the Menevian type, é tage © of
Barrande. Still lower, , according to the author, are the quartzites
on these points, and references to the field geologists who have
been working them out, will be found in the publication itself.
2. Recherches expérimentales cassures qui traversent
Pécorce terrestre, particulidrement celles ui sont connues pour les
noms de joints et et de failles par M. Daverke. (Comptes Rendus,
lxxxvi, 1878).—M. Daubrée, whose experiments relative to meteor-
ites were re toina recent number of this Journal (vol. xiv,
occurrence in rock-mai
iomets, ‘gee eraser Se e — hist he was as sions a plate
aes bstance 2 form ned an ae
“producing facture pitbcansc honk eet as 20°.
The Sar wesliy see Goistiok caets pine oree ont 90 cm.
a
Geology and Mineralogy. 481
fissures w races on the er surfaces of the plate were
approximately parallel; there were often two conjugate series of
hese fissures, crossing one ano at an angle varying from 90°
to 70°, or less,
the fissure-surfaces, there were also a small number of other planes
represents a pla
te which has been subje
cted to the torsion.
= >
i = an, Ss
= = =
—Se ~N . ‘~ J
The above results obtained by the torsion or twisting of a plate
of ice are shown by M. Daubrée to be closely analogous to the
phenomena of faults and joints observed in rock-masses. There is
the same approximate parallelism among them; and this is true
been submitted, torsion is one wh a
part in connection with the production of faults gg ee
P te !
i which has played a prominent
3. Notice of a fourth new Phosphate from
onnecti y Gro
e
mineral is salmon-colored and proved on examination to be a
phosphate analogous to triphylite in composition. It occurs
482 Scientific Intellagence.
immediately associated with spodumene and albite and a mineral
resembling Shepard’s cymatolite. It has _ omnes a bright
salmon color and a sub-resinous luster. Hardness =4. Specific
gravity —3°424. B.B. fuses at 1 to 1°5 acpi the flame bright
lithia red, with streaks of green, and reacts with the fluxes for iron
and mangane se. Analysis by Horace L. Wells proves it to be a
phosphate of manganese and lithia — about con per cent of
iron, giving the formula LiMnPO, or at We
propose to name this new mineral Lithidlite. A full description
bok analyses will be given in an early number of this Journ
4. Mineralogische Mittheilungen (Neue Folge); von G. ese
Ratu. (From the Zeitschrift fir Rayetallogtaphic, i, 6, 1877.)—
Prof. vom Rath describes :—a remarkable compou und crystal. of
bournonite, consisting of four individuals, but not a true twin;
also some new forms upon calcite erystals of Bergen Hill, New
Jersey; and stals of a new mineral, Krennerite. This last
mineral, a telluride of gold, was first described by Krenner under
the name of “ Bunsenin;” as this name has already been used for
another species, vom Rat th, who describes the pap Joram ——
. s the name Krennerite after the discoverer.
5. Das Rritebon von Herzogenrath am 24 Juni, 1877: > llins
seismologische bare von “te A. vo aero 77 pp. 8vo. Bonn,
of P
in its s phenomena much similarity with the former one, and it has
been investigated in the same careful and systematic manner. As
the results of the investigation it is concluded that the point from
which the shock went forth was at a depth of 16-85 English miles,
and that the Meta of propagation was 17-7 miles per minute,
the general direction being southwest and northeast. The occur
rence of the eaethatinke is regarded as more or less intima ately
connected with the great mountain-fissure—the “ Feldbiss,” vice
nof
crosses the coal formati the region of the Wurm in a bere
nearly normal to its strike.
6. Die Mineralogie von Franz von Kovett. sai edition,
252 pp. veer pa ipzig, 1878. (Friedrich Brandstetter.)—The Min
eral pore is neti too well known to need commenda-
tion he present edition the article upon the chemical
constitution is hd aby has been altered to some extent with refer-
ence to the now accepted chemical principles.
Ill. Botany AND Zoouoey.
Botany and Zoology. 483
the great loss and Wete, of the inhabitants of this province; be
it therefore enacte
reputation. An apparent justification of this ill odor of the Bar-
(among the agriculturists we mean) a be found in this
Journal, vol. xlix of the second series, 1870, p. 406. Mr.
of Salem, the hare sie: ts: old Province Sara who called our
attention to this
e barberry had poveanin been widely and pean ys prop-
in in the older settlements, during the century or century
and a quarter of their 2 ig and it is a to suppose
that attempts to exterminate the bushes were not limited to the
period of this act’s porate When the nlbanetion of wheat
particularly, declined, the farmers, probably, relaxed their efforts
against the barberry, and hence may we not account for its pres-
ent comparative abundance in the sanais of the older towns,
which were near the seaboar I remember, when a boy, of
i from
largely Essex
eastern ne and that the bush appeared as thrifty as any -
had ever seen in Essex County. The preamble of this act, per-
haps, explains the mystery ; for there is no reason to doubt that
the ‘experience’ of the farmers therein mentioned was neither
recent nor confined to a few, in 1754, when the ei it neces repre-
to
It has been suggested that the barberry never Malls damaged
the grain-crops of New England, at least to any nota table extent ;
but that the settlers, bringing with them from England the PoPy
lar fear of it, legislated _upon that. But if so, we pee a curio
illustration of the precarious nature of testimony. For be incon:
this colonial legislation has passed into history as independent
evidence that the barberry did damage grain in New England.
2. Ferns of North America ; by Prof. D. C. Eaton. Parts IV
and V, issued together, a up the seagenea to p. 113, and
the illustrations to plate 15. All but two of these plates carry a
couple of species, and the letter-press grows more copious.
Aspidium Nevadenee well fills a plate, and is capitally managed ;
it isa new species of the Sierra Nevada, the joint discovery of
Mrs. Austin and Mrs. Pulsifer Ames, whose names are rig
identified with California botany. Pelivea densa, 0
California (which does well in cultivation), and "Pp. pets seers a
484 _ Serentific Intelligence.
species which extends from Peru to Western Texas, make a good
plate. The supposed raphides of the upper surface of sate —
ota be cystoliths. Cheilanthas viseida of Davenport
es of Mr. Lemmon’ : a and C. Clevelandit of Eaton
for analysis of both i is wretched. - Ge
Dictionnaire de Botanique; par M. H. Bax Pax
(Hachett & Co.).—This work has tt sar to the eighth facials;
to p. 640, and to near the end of Ca. The affluence of sy tra-
tion continu ots
5. Vareas considerado como tai see por A. Exxon:
Caracas, pees 1877. 4to.—This is a memorial discourse upon
Dr. Varga , pronounced before she Meesiinade Society of the
Physical pas Natural Sciences, upon the occasion of the transla-
tion of his remains to the —— Pantheon. To this is oie
Vargas having b heen ‘suppresse ssed by the present writer, a new
ee 8, sera of Ternstremi sgn near ea and
cateinn dese
Dr. s Tuo: oMSON, the school-mate and associate, in aeaeal
and pibsioation on Indian Botany, of Sir Joseph Hooker, son of
the distinguished chemist and professor at Glasgow half a century
0, died at London, April 18th, after a long illness.
Gardener s Chronicle of April of, gives an appreciative —
otice.
TV. AsTronomy.
1. Transit of Mercury.—The transit of Mercury was observed
at New Haven on ee 6th of May by Messrs. J. J. Skinner, W.
F. Beebe and H. The following are the results 0
o tions in Washin on mean time; the phases being those
described in the Washington instructions. Clouds prevented
observations at some of the contacts.
Phase Phase Phase |Diam. Loca-
I. IL IIL. glass.| Power. Obs.! tion.
dom s:)h mos fh om
“22 7 1t [22 7 32 laa 7 42- ‘eink oo fe =
- | 5 33 58: | 5 33 48: | 5 33 18° (+6 = Hall.
. , Athen.
22 7 loaien 7 sealaa 22 at io s-in,| 180 | B, Aste
bee A s. 8. S.
| 38 67-8! 6 33 49°8| 6 3a 30-82 ™| 210 | H | Obs
Miscellaneous Intelligence. 485
V. MISCELLANEOUS SCIENTIFIC INTELLIGENCE.
. The International Geological Congress.—The time for the
nine of this Congress in Paris is now finally fixed, by the local
committee, for the 29th of August, and the Congress will remain
in session about a fortnight. Further details as to organization
and place of meeting will soon be made public. Meanwhile, it is
announced that from the 20th of August to the 15th of September,
the library and reading-rooms of the Geological Society of France,
o. 7 rue des ea Se AE I mae will be at the service of
subscription of twelve francs, required for each member, may
sent to Dr. Bioche, treasurer. Ladies are admitted to the Congress.
The local committee add to the above announcement as follows :
There is reason to believe that the numerous collections of geology
and paleontology (minerals, ir fossils, "apn plans, sections,
prepare a special ——_ of them for the use of the Congress.
Srerry Hunt, Secretary of the i ranermenany
2. Session of a National Academy of Sciences in A
List of papers read before the N asain Academy of. Sciences,
at the April session, 1878:
Formation and structure of Alacrane Lissa on the Yucatan Bank; by A. AGASsIz.
The theory of waterspouts M FERREL.
Report on the sabite of abe onal ites of Mate by ASAPH Hau
On the relation of loess an d drift to secular disintegration; by R. PUMPELLY.
On th central zoo-geographical province
of the United States; by A. S PACKARD, J!
On an optical ocean-salinometer: by J. E. H
Pre’ eliminary report on the deep sea dredgings ‘of pag U.S Coast Survey steame
“Blake” during the past winter in the Gulf Stream and the Gulf of Mexico; wt
ALEXANDER AGASSIZ.
Abrasions on the northwest coast of “tig Sg by George DAVIDSON.
On the law of Boyle and Marriotte; by Wi
Abstract of a gana on the intersection of circles and the intersection of
spheres; by All AMIN ALVORD. ics
Biographical memoir of Louis — second part. Relating to his life and
Tica; by ARNOLD GUY:
Biographical memoir of Jeffrie Wyn by A. S. Paokarp, Jr.
On the force of effective gree st action; by WrLiam A. Norton.
s on the value of the result obtained for | for the solar parallax from the
English telescopic sins ; by C. H.
On the ye cbobrae fauna of the Permian period of ergs United States ; by E. D.
Cop OPE. :
Report o: ee “oxygen in the sun;” oh etd ¥ DRAPER.
aoe comparisons of the components of close double stars; by E. ©.
‘On the Aiolionlica of geographical names; by F. V. HaYpDEN.
486 Miscellaneous Intelligence.
Characteristics of some of the lower spectral lines; by 8. FE LANGLEY.
A new element of the cerium group; vy J. Law WRENCE SMI
On Oe pie imary zoo-geographical divisions of the globe nad their relations; by
aos LL.
Wallace and Mr. Allen on geographical distribution, with special reference
to tho niger renege g of the Nearctic region; by Euiiorr Ss.
n the re and origin of mountains, with specia ay reference to recent
Fass to a nee theory age Josep LECoNT
Photometric measures of certain nt faint stars zs satllitos by E. C. PicKERING.
Contributions et meteo eorology seprry OT eas
ents in ; by GK. E
Si he laws saneinad the secant of re hoe Mountain locusts; by ©. V.
Supplementary notice on the paper, ‘* Whence came ii inner satellite of Mars,”
read at the October session, 1877; by StepHen ALEXANDER.
3. Bulletin of the United States National ccc Department
of the Interior. No. 10, Contributions to North American Tchthy-
ology, by D. 8. Gorpan. No.2. 120 pp. 8vo, with 45 plates.
4. Payen’s Manual of Industrial Chemistry, vodied by B. H.
Pavt. 987 p PP. 8vo, with 698 Pacts in wood. New York, 1878.
cid processes.
t American methods in te shiney is not a sur rise. The work
is still indispensable to all ogres in the industrial chemistry.
5. Smithsonian Institu oe office of Secretary of the
Smithsonian Institution, left vacant by the decease of Professor
Henry, bas been filled by syriiksicneies of Professor S. F. Baird,
who has for a lon: ‘hie | e ion of Assistant Secretary,
and is eminently fitted for the higher place by his long and ac ctive
ms agg se in the affairs of the ongrseers
American Association.—The American Association for the
Advaniebueae of Science will hold its eo meeting in St.
commencing with the third Wednesday in August. Professor
Marsh is - President of the Association for the meeting and the
; a Mocks for Mey. Mr. Mallet has a wh to
: piey i » Abbot’s paper on page 178 of this volume.
a oe ee ee ee eee | A Te ae
le Sep a RE
ey ge
PN DEX FOU V VLC aT
A
Abbot, H. L., transmission of earth waves,
Academy, National, titles at April meet-
neat » Sch Minnesota, Bull., 407.
Acid, benzoic, i in Srgsne of tinds, 146.
boracic , Os,
boric, eatibins of, 387.
ermal conductivi vity of, 1
Allen, J. A., fossil Passerine on: 381.
American Joerne of Mathematics, 406.
Na
Aiijbotto-arsehite "Woaide, Lea, 319.
Ammonium nitrite in combustion, 210.
Amylidenamine silver nitrate,
Antimony, atomic weight of, Cooke, 41,
“biting p point of Leena of, 391.
mpounds of, 310.
potter hg American, bien
ing, eae
British, notice of meeting, 48
Atomic waa of the elements, ate.
B
Beri i, Farag of Botany, 483.
um rh a
" y spe ieal abstracts, 51,
182, 208 30 386, 472.
Barrett, S. coralline limestone of
Montague, i. J., 370.
men te . de, Acetabularia Mediterranea,
9 APE der Physik
: nak Penk
Beiknap, G. z. ene oceanic tem-
sand
of meet-
Boisbaudran, gallium, 4
a a Aen nope 54.
"Acetabularia M ee 155.
£
a
J
Bacteria, oa of light on, 236.
Barberry in New England, 482.
Botrydium granulatum, 73.
Fern a — non-sexual outgrowths
aeons, apie of, 67, 221.
ids, range nr it 153.
irate of if N. America, Watson, 135.
Primulacez, morphology of, 400.
Transpiration in plants, 73, 156.
| 402.
Thuret’s t's garden 153.
:; insect-fertilization, 224.
Plants, 404.
ren
we Eee baten from Fair-
sare normal, wir
Cc
vias rsicaigie ys of oxygen, i dak 141.
quefaction of acetylene, etc, 142.
Caistae S., shale ai t Independence, Towa,
Carbon apes action of, 306.
ra
pace ypt re of antimony, 391. Carll, J. F., oil well records, 315.
Berthelot, maximum work,” 143. ED ee vig Bed x spir
systems emical notation. Par e
Cearnid cleaniias hit a Goeree m of the electric spark,
_ persulphuric oxide, 20 i
Beryllium, specific heat of, ake ual €. botanical works noticed,
Boilers, potetio of marine 380. | Chamberlain, T C, geal Fe. Absa
488 INDEX,
Chemical dynamics, 308.
heat data, 304
211.
pats "ouere ae of varis-
R. = new acid ammonium
noe ek I3
EW, Glyptodendron, 302.
resins, 388.
Collins, J. H., Minera eer a0
— Coggia’s, roses =i Norton,
eak prize for discovery of, 158.
Cook, G. th geol. rep. N. J., 216, 316°
Cooke dF. i ah atomic ie of anti
chem cal phompiys at
haloid compounds of ale 310.
chemical and physical notes, 53, 214,
389,
Cope, E. Dv rtebrate fossils from New
Copeland, Schmit eS a oo 76.
Corallin, co:
Croll, "T, teSaee’ 8 se ore rac
146.
age of the sun, 226,
tac North American Plants, 402.
D
Dall, W. H., nomenclature in zoology
and botany, 321.
Dana, E. S., new Lag es te Fair-
rage unt, = 398,
tices, 65, oo 319, 482,
Dans, J rg D, swat hoofed pigs, 2
driftless interior of N. Ame oii and
region of Wisconsin, 2
as Forms of flowers, 67, 221.
PI and light-absorbi
Dieulafait. DOERCIE acid, 53,
boracic acid, 390.
ote A. E., ‘he er eatery 160.
Downes, A., effect of li ight on Bacteria,
Draper, J. ©, ————
ae A. J., Weisbach’ 's Mechanics, 78.
Fluoranthrene,
Fe
wd apes 394, |
E
Reign wet . Nov. S, oo 238.
of Nov. 4, 1877,
of Her: ht aa "Fi 24, "TT, seg
Barthquakes, recent Amer ., foe Jewood,2
arth wa s, transmission of, Bt , 180.
Eaton, D. "C. botanical noti
Ferns 0 Amer., 72, 223, 26, 483,
Electric convection, magnetic effect
nd,
rrents, aie yr Broun, 385.
rsteoroleey.
resistance, unit of, Rowland, 281,
325, 430
Electro - ~ magnetic absolute measure-
ments, 3|
Eltekoff, oe eynthess of olefines, 386.
" emeeds , oo 2 po $9 9 Geology of
the 4oth P * ag
n. pu nRticatiaae of, 153.
Ethers, at et foraation of, 213.
Fairchild, H. L., leaf-scars of Sigillariz,
218.
— W. G., botanical notices, 73, 153,
Feilden, H. W., quaternary beds of Grin-
nell Land, 219,
Feistmantel. O0., Geol. Surv. India, 239.
Fittig, fluoranthrene, 210
Flame sheen eicigens bey 143.
» the telephone an instrument
Ford, 8. W., new Primordial fossils, 124.
note o e Teeuiclia were 127.
Olenellus asaphoides, 129.
Brachiopoda, 2ieknes Primordial, 364.
Fossil, see
GEOLOG
Frazer, ?.. war. Tables for the determina-
bes ‘of mi
on ora eo low speeds, Kimball,
G
— W. M., growth-rings in exogens,
226.
Gallium, 47
Garver, Me * sensation and volition
through
2 SURVEYS—
New Hampshin e, 149.
New Jersey. a 316.
Rocky (Powell), 218, 342,407,449.
Territories (Hayden), 56, 217, 7, 397.
r—— 1ooth Meri dian (Wheeler), 55-
40th Parallel, 316, 396.
INDEX.
GEO Semel
Acadian, 478.
Bird, fossil Passerine, Allen, 381.
Brachiopoda, forms of Swedish, 364
fi
ormations
— — of North America,
at Fa nue Northwest, Jrving, 313.
of Le sagen 61, 254, 406.
Falls of the piety
Faults and join
yee plants rj ‘the re se “Nevada,
tae ‘from the Keokuk, Wudllace,
396.
Geodes of the Keokuk, pea 366.
Glacial eras of Euro
ge Ohio, ‘ionpble 302.
a. ancient outlet of, 65,
ry of, 219.
fol tet bt bed Ca
ee.
i=]
ass Russell, 8t%
Olenailas asaphotdes, Ford, 129.
geology of, Ste-
venson, 2
"Sloan fossils in limestone of,
a Devonian: Z
athus, Ford, 124.
Reptiles, new fossil, Marsh, 241, 409.
e Leda clay, 2
Siberian sheriee 65.
Silurian plants, 149, 219, 302.
Solenopleura, new, "For d,
ancient outlet of Great
be
56.
— T., new American
Chimeera, 2
Glan, density and light-absorbing Ponce
394,
Gravitation, ers Aaayak lak
, botanical notices, 67, 151, 219,
221, 318, 40 401, 404, 482.
489
H
See H., glacial eras of Europe,
Hague. A., descriptive geology, 3
Ohi 35 J, Limestones of the Falls = the
4M., Sapotacese, 4
‘astings, C. S., , optical caveat of glass,
69,
Hausema mona Tt pate cengecs properties of
me
Hawes, G. W. chloritic formation of the
New Haven re regio
Hayden, F. V., field work of on 56.
publications of expeditions under,
217, 219, 3
atlas of hei 397.
Heat, and sidereal, Ki
Heil, ss of ret ae 306.
Hofmann, ‘ens of east tar, 388,
Holden, E. ’s zodiacal light, 231.
caecens ical no’
index of works on nebulz, 159.
Holmes, E. M., phurmaceutical catalogue,
320.
Homann, quercite a pentacid aleohol, 307.
Huxley, T. H. , anatomy of invertebrata,
rt raeatolan, rorie 145
423. Fad a
rmal conductivity of, 147.
seo bth
Tron, chromic, decomp. of, Smith, 198.
drving, R. D., driftless region of North-
west, 313.
Jsaman, I. J., on trichostema, 224.
J
Jaffe benzoic acid in birds, 146.
annetaz, E., Guide to the Determination
sy
Kayser, specific heat of air, 55.
Kerr, refeetion of polarized light from a
magnet, 394.
490
—— A. §&., journal friction at low
speed 192.
King, C. ee Surv. 40th page 316.
Atl 0th Paralle 1, 39
: orks on alge, 74,
reaction of ‘ces e acid,
Kobell, F. v., Mineralogy, oy ed., 482.
Kokscharow, N. v., crystallization of
micas, 150.
Kramers, phenol and chlorbenzene, 53.
L
Laboratory notes of Johns Hopkins Uni-
versity, 216.
Laiblin, constitution of nicotine, 211.
ti
7
ammonio-argentic iodide, 379.
LeBel, normal butylene, 474.
LeConte, J., glycogenic function of the
ver, 99,
Elements of Geology, 218.
Leidy, J, cire of ants, vad
Lesquereux, L., Cordaites with flowe
317.
Siluria
Tertiary
urian plants, 149, 219.
metric com}
Phase gi plants of &. Nevada, te 396.
Rood, |
Mats, photo!
m of net 394.
saeates of, 394
icht, analysis of nitro-compounds,
Linnean aswel f woe of, 224,
— glycogenic function of, LeConie,
Loomis, E., contrib. to to meteorology, 1.
INDEX.
eon J. C., Matter and Motion, 407.
—_ ane tg rye nts with floating
wed ah formation in north-
eastern Towa,
Meek, F. B., pa leontology (40th parallel),
re
Men schutkin , formation of ethers, 213.
seven transit of, 455, 457, 484.
Merri .) ML etho d of least squares,
79.
erz, synthe pet ape acid, 211
Metals, photo-electri c properties of, ae
M Mall 83
Meteorology, contributions to, Leo
Meteors, Cambridge, Nov. 3, 1877, we
ovember, 6.
Michelson, velocity o ~ 394.
ros ¥ Siberian sie 3
Mine pera ser 482.
150.
Anthracite of wei Aig 55 6.
Dickinsonite, Brush and Dana, 399.
Kosphori . Brush se Peet
Guanajuatite t, 2
milite, 318.
Meaestiacn, Rath, 48
Lithiolite, Brush sa Duna, 482,
Meroxene, 150.
Micas, erystalization of, 150.
Pyrophosphori
Samarskite, N orth Caroling 220.
Tantalite, bama, Smith, 203.
Tetrahedrite, _
bn’ in: Ieclend; 06
Trpbidive, Denk and Dana, 398.
Variscite, cyrstallizati of, Chester,
207.
Mitchell, M., Jupiter and-its satellites, 38.
| Mizter, W. G., am ylidenamine silver ni-
—* 205.
Moon, zodiacal — of, 88, 231.
Morse, E. S., Sapa se Lingula and shell
mounds, 156.
National, Bulletin. 486.
, just intonation in, Poole, 359.
Laff A. P., chemical dynamice, 308. N
Nawmann, vapor densities, 208.
We <6 Nerves, rate of trausmission through,
Magnets. Mayer, 216, 477. 413,
usenet: in — Nicholson, H. A., Ancient life-history of
_. me pangs irginia, 33 the earth, 315.
Marignac, C., chemical notation, 89, i. Nicotine, constitution of, 211-
“> 0. C., new species of Ce eratodus, | nee a aed endl pra
Nitro-compounds, anal , 306.
Nitrogen, direct combustion of, 51.
F
iP 4%:
INDEX.
Nitroglycerin, nitrogen i
Nordstedt, O , botanical pte ie 225...
Norton, W. A +» Coggia’s sencadt 161.
Norwegian explo ring expedi 8.
3 Ornith. Club, bulletin rat 158.
Nys ’ gin-
ena
OBITUARY—
Becquerel, A. C., 239.
arlato
Pickering, Dr Charo, 408.
gg Mi
: Fags eo
Ruhikorf N, 160.
Secchi, A., 3
— Mrs. Pleasance, 225.
mae Thomas, 484.
Weddell, H » 225.
a cmlonad publ. of, 406.
Cordoba, | from, 468.
bon ae oxi
— of liquid ag
iquefaction of, 13
Palmieri, pg 476.
Parkman, F., hy “ert of gies, 151.
Os ag 8 a Tonlauetel Chemistry, not., 486.
Peale, A. C., ancient outlet of Great Salt
Peters, C. H. F., a new planet, 208
Letterssun, specie heat of bery lium, 3 386.
Phenol, distillation of, 53.
491
Platt, F., and W. G., bituminous coal of -
tern rm Pennsylvania, 315.
eo H. W., just intonation in music,
Prime, F., Jv.. Lower alr fossils,
261,
Q
Quartz, separation of from mie 305.
Quereite a pentacid alcohol, 3
R
‘ammelsberg 2 cs samarskite, 22
Rat
Palen "sition
Reti uorescence
Riban. the sulphides of pstinum
Ridgway, R., Ornitho 0th par,)16 ,i18
Rockwood, C. G., recent fies erica
quakes, 21.
earthquake of Nov. 15, 1877, 238.
es ea <2 oe leendieg of = us, 195.
of Mercu
the 2 tinal ox, 398.
m of
‘ Rood, “0. N,, pce compariso:
light of different ered 81.
emistry,
Rosenbusch, H., _ieroscopi hears:
fe of rocks, 65
mperatures, 143
ockatibaki J., Botrydium granulatum,
3.
A., magnetic effect of elec-
tric eronreton, 30.
of electrical resistance, 281,
“| Royal’ Soctety. address of president, 231.
medals o:
.
Russell, I. C., Triage tap sinets of ew
Jersey, 277.
Sachs, curarine, 389. 4
, ©. pe miei of a
tie hydantoins, 145.
gar vires new acid ammonium sul-
phates, 13
Sewell, H., mineral caves of Huallanca,
Pern, 317
rs, see METEORS.
properties of se-
. | Shepard, dla mace ie
08. | Shooting Sta
lenium, 215.
492
Silliman, B., Joseph Henry, 4
Silver chloride and bromide, len 189.
ith ecomposition of chromic
: be ee Filicum, 223.
Smith, J. fos cay from Alabama, 203.
Smithsonian Inst., secretary of, 486.
Solar, s oo Soe:
Solids, Pati Pee of, 472.
es f the electric spar
148.
tahl, E., pitti of hens, 155.
Bhar, , Schmidt's Nova Cygni, 7
on, J. J., surface Soler of Penn-
pivakin, 245.
U Pper Devonian rocks of Pett as
geological survey of P
artes 2 H, ferment. Shao of tie
Strasborgher, E., Acetabularia Mediter-
ranea,
Stur, ee ee Carboniferous plants of
Moravia, 398.
ona, : new oxide of, 2
Sun, age of, Croll, 226; Kirkwood 291.
oe oO
ye Beas sudden Sek of,
Trouvelot,
3
Telephone, an npetaaes test, 312.
woh ype
Trouvelot. L, undolaton in the. tail of
Sopa s comet, 8
don extinction of a solar protu-
’s zodiacal light, 88.
oe f: papaieal notices, 54, 147,
215, 308, 394. e
ermak, G., die Glimmergruppe, 1
a, J. flasks opened on the rei
the moon
Universities in Germany, 237.
Up av modified drift in
N. Hamp-
Uranus, ialliins of, Rodgers, 195.
.
INDEX.
WwW
Wadsworth, M. E gain gs of and Pe-
trography of Bos
echter, atomic weights of the elements,
305.
Wallace, S. J., ““Geodes” of the Keokuk
formation, 366.
fossil wood from the Keoknk. 396.
Watson, S., poplars of N. America, 136.
Tndex to N. America n botany 400.
Weather service, volunteer, 2
cond re ss elec pce. a calor-
asurements, 215,
Weisbach’s Mechani cs, 78.
Wheeler, G. M., gecl. report ¢ of, 55.
s, 5
5.
Carboniferous and Upper Silurian
fossils of gate and Indiana, 398.
bleraes = P., paleontology (40th par-
Wibbe a sent Tange for two orchids, 153.
Wi solids, 472.
Wisner, J., influence of light and heat on
comer eae = ae nts, 73.
Wilson, E. B.
id
v. B., Mesocarpex, 4
Wood tar, triacid eva of, 3
Ba oes C. R. A., chemi ax Fach 308.
Wright, E. P., botanical publications of,
156.
Wiiliner, spectrum of the electric spark,
148,
x
Xanthin-like bodies in digestion, 476.
Zéller, ammonium nitrite in combustion,
210.
ion of, 320.
Pyenogonida, new, now, Wilson, 200.
See further under GEOLOG
Zulkowsky, constitu cross of aoaliin an