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Full text of "Water quality data for Ontario lakes and streams, Volume XXVI Northwestern Region 1990"

WATER QUALITY DATA 
ONTARIO LAKES AND STREAMS 
1990 

VOLUME XXVI 
NORTHWESTERN REGION 



AUGUST 1994 



® Ontario 



Ministry of 
Environment 
and Energy 



ISSN 0843-5863 



WATER QUALITY DATA 

ONTARIO LAKES AND STREAMS 

1990 

VOLUME XXVI 

NORTHWESTERN REGION 



AUGUST 1994 







Cette publication technique 
n'est disponible qu'en anglais. 

Copyright: Queen's Printer for Ontario, 1994 

This publication may be reproduced for non-commercial purposes 

with appropriate attribution. 



PIBS 2986 



Copyright: Queen's Printer for Ontario, 1992 

Additional copies of this publication may be obtained by contacting 
the Ontario Ministry of Environment & Energy, Public Information 
Centre, 135 St. Clair Avenue West, Toronto, Ontario, M4V 1P3. 
Telephone (416) 323-4321. 

Permission to republish must be obtained in writing from: 

The Director 

Environmental Monitoring & Reporting Branch 

Ontario Ministry of Environment & Energy 

125 Resources Road 

Etobicoke, Ontario M9P 3V6 

Parts of this publication may be quoted if credit is given. It is 
recommended that reference to this volume be made in 'the following 
form: 

Ontario Ministry of Environment & Energy, 1992. Water Quality Data 
Ontario Lakes and Streams, 1990, Volume XXVI, Northwestern 
Region. 

Every possible effort is made to ensure the accuracy of the 
information contained in this publication. Verification of any 
suspect data may be obtained by contacting the Surface Water 
Surveillance Section, Environmental Monitoring & Reporting Branch, 
Etobicoke, Ontario (235-6254) 



- II - 



TABLE OF CONTENTS 

Page 

INTRODUCTION. . V 

NETWORK MAP SHEETS i ...... XI 

INTERPRETATION OF DATA XX 

A. Analyses and Measurements Conducted at the 

Sampling Site XX 

6. Analyses and Measurements Conducted at the 

Laboratory • .- XXII 

1) Microbiological Analyses XXII 

2) Chemical and Physical Analyses XXIII 

3 ) Radiochemical Analyses XL 

4) Synthetic Organic Analyses XLIV 

STATION IDENTIFIER CODES, QUALIFYING REMARK CODES AND 

ABBREVIATED PARAMETER HEADINGS XLVII 

OTHER ABBREVIATIONS . LV 

GLOSSARY OF TERMS LVII 

SELECTED REFERENCES LVIII 

ABBREVIATIONS AND REMARKS USED ON REPORTS LVIX 

WATER QUALITY DATA 1 

SAMPLING STATION DIRECTORY (ALPHABETICAL INDEX) 158 



LIST OF FIGURES 
FIGURES Page 

1. Regions and Offices in Ontario - Ministry of 
Environment & Energy ..;..... VI 

2 . Southern Ontario Terminal Basins -. IX 

3 . Northern Ontario Terminal Basins X 

4 . Network Index Map of Southern Ontario XII 

5. Network Index Map of Northern Ontario ................ XIII 

6. Northwestern Region Network Map NW-1 XIV 

7 . Northwestern Region Network Map NW-2 . . — XV 

8 . Northwestern Region . Network Map NW-2 A , . XVI 

9 . Northwestern Region Network Map NW-3 XVII 

10. Northwestern Region Network Map NW-4 ... XVIII 

11. Northwestern Region Network Map NW-5 XIX 



- IV 



INTRODUCTION 

"Water Quality Data Ontario Lakes and Streams, 1990, Volume XXVI, 
Northwestern Region", is one of an ongoing series published by the 
Environmental Monitoring & Reporting Branch of the Ontario Ministry 
of Environment & Energy. The data presented in this publication 
were collected by the Water Resources Assessment Units of this 
Ministry's six Regional Offices (Figure 1) with the assistance of 
local Conservation Authorities in some regions. The information 
provided in this publication is compiled and published by the 
Surface Water Surveillance Section of the Environmental Monitoring 
& Reporting Branch. The data result from a routine sampling 
program designed to provide a long-term record of the water quality 
information at specific points on rivers and inland lakes in 
Ontario. 

Sampling station locations have been selected to meet one or more 
of the following requirements: (l) to measure quantitatively and 
qualitatively the materials discharged from tributary streams to 
the terminal basins; (2) to monitor the effects of wastewater 
discharges on a watercourse; (3) to provide data that can be 
considered generally representative of water quality conditions in 
a certain area. 

The information is used by the Ontario Ministry of Environment & 
Energy to maintain surveillance over water quality conditions and 
to provide supporting data used in the analysis and prediction of 
water quality for planning and other purposes. The data are also 
made available to any person or agency concerned with the quality 
of Ontario's rivers and lakes. The booklet "Water Management 
Goals, Policies, Objectives and Implementation Procedures of the 
Ministry of Environment", 1978 (Revised May, 1984) outlines the 
current policies 'including the Provincial Water Quality Objectives 
(PWQO) for many of the parameters in this report for water 
management in Ontario. 



- V - 



Scimples are analyzed for some or all of the following parameters: 
coiints of total and fecal coliforms, enterecoccus , Pseudomonas 
aeruginosa and escherichia coliforms, concentrations of biochemical 
oxygen demand, total phosphorus, filtered reactive phosphate, 
filtered eunmonia, total Kjeldahl nitrogen, filtered nitrite and 
nitrate forms of nitrogen; total suspended and dissolved solids; 
levels of conductivity and turbidity; concentrations of chlorides, 
sulphates, unfiltered reactive silicates, acidity, alkalinity; 
units of pH; concentrations of total iron, phenols, hardness, 
calcium, magnesium; units of colour; concentrations of potassium, 
sodium, total organic carbon, chemical oxygen demand, solvent 
extractables, arsenic, mercury, aluminium, chromium, copper, lead, 
cadmium, zinc, manganese, nickel, fluoride, cyanide and cobalt. 

In addition, radiochemical analyses are conducted on selected 
samples and the results are expressed as levels of ionizing 
radiation (i.e. the number of nuclear disintegrations per second) . 
Selected samples are analyzed for some or all of the following 
radiochemical parameters:, gross alpha, gross beta, radiTam-226, 
total uranium, cesium-137, cesium-134, cobalt-60, tritium and 
iodine 131. 

Some samples are also analyzed for some or all of the following 

synthetic organic parameters: concentrations of PCB, PC? and 

2,4,5-T. 

The complete list of parameters are described in the section 

dealing with "station identifier codes qualifying remark codes and 

abbreviated parameter headings". 

The water quality monitoring program commenced in July 1964 in 
Southern Ontario and currently consists of a total of 703 stations 
throughout Ontario. The following maps (figures 2 and 3) show the 
Southern and Northern Ontario Terminal Basins which are used to 
identify the sampling station locations. Definitions or brief 
descriptions are provided for the more common parameters of water 
quality under the section entitled Interpretation of Data. 

- VII - 



other ambient water quality monitoring programs such as the Sport 
Fish Contaminant Monitoring Program which is co-ordinated by the 
Ontario Ministry of Environment & Energy with participation by the 
Ministries of Natural Resources and Labour are not discussed in 
this publication. A summary of health implications of contaminants 
in fish with a listing of test results from each fish sampling 
Ideation can be found in the Ministry publication, "Guide to Eating 
Ontario Sport Fish". This publication is updated annually and is 
available free of charge from the Ministry of Environment & Energy, 
Environmental Monitoring & Reporting Branch , 125 Resources Road 
Etobicoke, Ontario, M9P 3V6 , telephone (416) 314-7886. Further, 
there are also additional ministry surveillance programs, including 
Drinking Water Surveillance, Great Lakes Surveillance and APIOS 
Programs . 

The streamflow station network in Ontario is not discussed in this 
publication. Whenever streamflow data exists at tributary 
locations which are coincident with the water quality monitoring 
station locations, data on mean daily discharges are available from 
Water Survey of Canada. The collection of hydrometric data in 
Ontario has been carried out under a Memorandum of Agreement 
between the Government of Canada and the Province of Ontario since 
April, 1975. The Province of Ontario is represented in the 
Agreement by the Ministry of Environment & Energy, the Ministry of 
Natural Resources and Ontario Hydro. These agencies meet at 
regular intervals with the Water Survey of Canada to administer the 
Agreement. Streamflow data for Ontario are published annually, 
details of individual stations and related reocrds as well as 
recent data which have not yet been published, may be obtained upon 
application to: 

Water Resources Branch 

Federal Building 

7 5 Farquhar Street 

Guelph, Ontario 

NIH 3N4 

Tel: No. (519) 821-0110 




niiiaitiiKi Mil 




WHITEFISHJfl 

ST. MARYS R. 

15 
LAKE GEORGE- 



FIGURE 3 
NORTHERN ONTARIO TERMINAL BASINS 

19- (tSIN lOENTIFICtTIOK CODE 



- X 



NETWORK MAP SHEETS 

Individual station locations are identified on specially prepared 
network maps. These network maps have been drawn to Conform 
approximately to the boundaries of the Ministry's Regions, and are 
grouped according to Regions. Two index maps (Figures 4 and 5) 
illustrate individual map .sheet coverages within the Province. 

The following procedures were used in the preparation of the maps. 
Individual base maps within a Region were assembled using the 
National Topographic Series maps at a scale of 1:250,000. in 
northern Ontario, this was reduced to a scale of 1:500,000 in the 
Lake Superior and Nelson River basins, and to a scale of 
1:2,000,000 in the Hudson Bay basin. For each base map, an overlay 
of the river systems was prepared, showing major watershed and 
Ministry of the Environment & Energy Regional boundaries. Numeric 
terminal basin and stream codes were added, and active water 
quality monitoring stations were located on each overlay and 
referenced with station numbers. The overlays were then reduced to 
approximately 40% of their original size for purposes of this 
publication. 

The previously mentioned terminal basin and stream code, when 
combined in sequence with a given station number, together form a 
unique station identifier which appears as the "Station ID". The 
"Station ID" is listed for all active monitoring stations within 
the Region in the "Sampling Station Directory", an alphabetical 
listing of terminal streams monitored in Northwestern Region, (See 
Sampling Station Directory) . 

The location of stations in the Northwestern Region are shown in 
figures 6, 7, 8, 9, 10, & 11. The locations of the other stations 
^n the other regions and in other parts of Ontario such as those 
located on the Great Lakes or those operated by the Water Quality 
Branch, Ontario Region, Environment Canada, are not included. 



XI 





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•XIV- 




•XVIII- 




•XIX- 



INTERPRETATION OF DATA 



The definition of the parameters measured in the Provincial Water 
Quality Monitoring Program are described in the following pages. 
The significance of each measurement in regard to specific water 
uses can be determined by referring to the booklet "Water 
Management, Goals, Policies, Objectives and Implementation 
/Procedures of the Ministry of Environment, November, 1978". 
^Revised, May 1984). 



A. ANALYSES AND MEASUREMENTS CONDUCTED AT THE SAMPLING SITE 

RtrAMm Condition 

The physical condition of the body of water is described from an 
on-site examination at the time of sampling and is represented by 
a one-digit number from one to zero as follows: . 

1. Stream dry 

2. Frozen to stream bed 

3. Stream in flood condition 

4. Sampled through ice 

5. Suspended algae 

6 . No apparent algae 

7. Profuse weed growth 

8. Normal • 

9 . Oil scum or floating matter 
0. Objectionable odours 

Under some circumstances a combination of up to three of the above 
conditions may be shown for a given sample at an individual 
station. 



- XX - 



Streamflow 

Streamf low information at or near a water quality monitoring site 
is an important factor when interpreting and employing water . 
quality data. The product of streamflow and concentration defines 
the mass of material passing a point. Streamflow is also a useful 
r-eference when comparing water quality data for different periods 
of the year (e.g., spring flood versus summer drought). 

Flows in many of the streams sampled are measured by the Water 
Survey of Canada, Inland Waters Directorate, Environment Canada. 

Temperature 

Water temperature is an important factor when a number of water 
<3uality parameters are being evaluated. Temperature directly 
affects the solubility of gases (e.g., dissolved oxygen) and 
significantly affects biological and chemical reaction rates. 

Temperature is measured at the sampling site with an electronic 
thermistor or a mercury thermometer. 

Dissolved Oxycren 

Dissolved oxygen in water originates directly from the atmosphere 
or through photosynthesis in aquatic plants. Ample dissolved 
oxygen is necessary to maintain satisfactory conditions for fish 
and other biological life in water. Organic wastes and some 
inorganic materials exert, upon decomposition, an oxygen demand 
which may deplete the dissolved oxygen below levels required by 
aquatic life. 

Dissolved oxygen is measured at the sampling site with an 
electronic meter or by a chemical titration. 



XXI - 



B. ANALYSES AKD MEASUREMENTS CONDUCTED AT THE LABORATORY 

1. MICROBIOLOGICAL ANALYSES 

Total Coliform 

The Membrane . Filter (MF) technique is used to obtain an 
approximation of the concentration of total coliform organisms. 
These organisms are normal inhabitants of soils and the intestines 
of man and other weirm-blooded animals. They are always present in 
large numbers in sewage and fecal matter, and are often found in 
watercourses adjacent to industrial, agricultural and other 
pollution sources. 

Results are reported as MF count per 100 mL of sample. 

Background Count 

The background count estimates the number of organisms, other than 
coliforms, . that occur in the total coliform analysis of a scunple. 
The results are used in the interpretation of total coliform 
counts. High background counts are generally indicative of ppor 
water quality. 

Fecal Coliform and Fecal Streptococcus (Enterococcus) Organisms 

Fecal coliform and Enterococcus organisms are generally found in 
the alimentary tract of warm-blooded animals. They are indicative 
of sanitary waste intrusion and/or fecal contamination from 
warm-blooded animals. 

Pseudomonas aeruginosa 

Pseudomonas aeruginosa are pathogens found in sewage that can be 
readily isolated. These organisms are sometimes found in bathing 



XXII 



waters and are the major pathological agent In otitis externa 
(earaches) and skin infections. ^ 

Escherichia Colifonn (E. Coll) 

E. Coli is the predominant, facilitative bacterial species in the 
large bowel and is thus the coliform most directly related to fecal 
pollution. Some species of E. Coli are pathogenic to man (e.g., 
urinary tract infections) but is primarily em indicator organism in 
water bacteriology. 



2. CHEMICAL MUD PHYSICJO. J^KMiYSES 

Biochemical Oxygen Demand (BOD) 

In itself, BOD is not a pollutant and presents no direct harm to 
the aquatic environment. It is, however, a measure of the unstable 
organic matter present in water which, through aerobic 
decomposition, oxidizes to a stable inorganic form utilizing the 
oxygen resources of a watercourse. The level of BOD is an 
important parameter in assessing the potential concentrations of 
dissolved oxygen in water. 

Five-day biochemical oxygen demand (BOD5) is a laboratory 
measurement of the amount of oxygen consumed in a sample incubated 
for five days at 20*'C. 

Total Phosphorus 

Phosphorus is a primary nutrient for plant and animal life and like 
nitrogen passes through cycles of decomposition and photosynthesis. 
This element is commonly found in nature in the form of inorganic 
phosphates and organically bound phosphorus. Total phosphorus 
includes orthophosphate, condensed phosphates and organically bound 
phosphorus in both the dissolved and particulate form. Untreated 

- XXIII - 



or treated sewage, some industrial wastes and agricultural and 
urban drainage contain significant concentrations of phosphorus. 

Although there is no firm criterion for phosphorus, it is generally 
considered that to eliminate excessive plant growths in rivers and 
streams, total phosphorus should not exceed 0.D3 mg/L. To avoid 
nuisance concentrations of algae in lakes, average total phosphorus 
concentrations for the ice-free period should not exceed 0.02 mg/L. 

Filtered Reactive Phosphate 

Filtered reactive phosphate is that phosphorus which passes through 
a 1-2 micrometre filter and responds to a colorimetric 
orthophosphate determination. It is a combination of simple 
orthophosphate and readily hydrolyzed phosphate primarily in the 
dissolved form. 

Filtered reactive phosphate is generally considered to be readily 
available for aquatic plant growth. 

Filtered Ammonia Nitrogen 

Filtered ammonia nitrogen (ammonia NHj and ammonium NH^) is the 
soluble product in the anaerobic decomposition of nitrogenous 
organic matter. It is also formed when nitrites and nitrates are 
reduced either biologically or chemically. Small cimounts of 
ammonia nitrogen may be taken out of the atmosphere by rain water. 

Total Kieldahl Nitrogen 

Total Kjeldahl nitrogen is a measure of the total nitrogenous 
matter present, excluding nitrate and nitrite. The total Kjeldahl 
nitrogen concentration, less the ammonia nitrogen concentration, 
gives a measure of the organic nitrogen present. 



XXIV 



Ammonia and organic nitrogen are . important in assessing . the 
availability of nitrogen for biochemical utilization. 

Filtered Kitrite 

Nitrite is an intermediate oxidation product of ammonia and also an 
intermediate form in the denitrification process from nitrate to 
nitrogen gas. The significance of nitrites, therefore, varies with 
their amount, source and relation to other constituents of samples 
(notably the relative magnitude of ammonia and nitrate present). 

Since nitrite is rapidly and easily converted to nitrate, its 
presence in concentrations greater than a few micrograms per litre 
is generally indicative of active biological processes in the 
water. 

Filtered Nitrate 

Nitrate is the end product of the stabilization of organic nitrogen 
which occurs primarily through aerobic biochemical processes. 
Nitrate is usually found in polluted waters that have undergone 
some degree of self -purification. Nitrates can also occur in 
watercourses intercepting drainage from fertilized agricultural 
areas. 

Nitrogen in the form of nitrate is readily utilized by aquatic 
plants and algae. 

Inorganic Nitrogen 

Inorganic nitrogen is a calculated value and represents the sum of 
the concentrations of filtered ammonia nitrogen and filtered 
(nitrate plus nitrite) nitrogen. 



XXV 



Organic Nitrogen 

Organic nitxogen is a calculated value and represents the 
difference between the concentrations of total Kjeldedil nitrogen 
and filtered ammonia nitrogen. 

Total Nitrogen 

Total nitrogen is a calculated value and represents the sum of the 
concentrations of total Kjeldahl nitrogen and filtered (nitrate 
plus nitrite) nitrogen. Nitrogen is a common constituent of 
decomposition products, treated sewage, fertilizers and industrial 
discharges. Nitrogen compounds are present in most plant and 
animal materials. 

Solids 

Total solids, suspended and dissolved solids are presented as 
separate parameters in this report. The solids analyses are gross 
measurements of the amounts of particulate matter and dissolved 
materials found in water. Solids enter the watercourse from 
virtually every source, the most familiar being sewage treatment 
plant effluent, municipal storm drainage, industrial discharges and 
soil erosion. 

Solids significantly affect water uses. Highly turbid water is 
undesirable for municipal and industrial supply, fish and aquatic 
life, recreation and aesthetics. Suspended solids can also 
transport significant quantities of organic and inorganic trace 
contaminants . 

Conductivity 

The conductivity test provides a measure of the electrolytic 
properties of water. The presence of dissolved ions (in solution) 
such as chlorides, sulphates and calcium, renders water conductive. 

- XXVI - 



Conductance, the reciprocal of resistance, is recorded in the unit 
mho and in order to avoid inconvenient decimals, data are reported 
in micromhos per cubic centimetre. In many waters there is a 
direct linear relationship between dissolved solids concentrations 
and conductivity. 

Conductivity serves as a control parameter and is an excellent 
indicator of water-quality changes since it is relatively sensitive 
to variations in dissolved-solids concentrations. 

Turbidity 

The turbidity of water is attributable to suspended and colloidal 
matter such as micro-organisms, detritus, clay and other mineral 
substances which reduce clarity and diminish the penetration of 
light. 

Turbidity is undesirable in surface waters used for domestic and 
industrial supply and for recreation. Often some of the suspended 
matter has to be removed to prevent interference with disinfection 
processes and abrasion to equipment. By interfering with the 
penetration of light, turbidity does seriously affect aquatic 
biological communities. 

Chlorides 

Chlorides are found in practically all natural waters. They may be 
of natural mineral origin but in general the largest contributions 
can be traced to domestic sewage discharge, municipal storm 
drainage, road salting, and industrial wastes. 

While not harmful to health in moderate quantities, high 
concentrations of chlorides make water unfit for municipal and 
industrial supplies and livestock watering. In addition to 
imparting an objectionable taste to water, high chloride levels are 
responsible for increased corrosiveness of water. Furthermore, 

- XXVII - 



chloride, being toxic to many plants, may render water \indesirable 
for irrigation. 

Sulphate . . 

Sulphates may occur naturally in waters and may be contained in 
industrial wastes. They are produced from the final oxidation 
stage of sulphides, sulphites and thiosulphates. Sulphates, under 
anaerobic conditions, can be reduced to hydrogen sulphide which is 
malodorous (the odour of rotten eggs) and highly corrosive. 

Sulphide 

Sulphide is formed by bacterial reduction of sulphate and organic 
sulphur compounds under anaerobic conditions. It is therefore, 
commonly found in domestic wastewater, industrial wastewater, 
sludge, hypolimnion of stratified lakes and any other aquatic 
systems where anaerobic conditions prevail. As a result, 
concentrations in surface waters are usually negligible. 

Unfiltered Reactive Silicate 

Silicon occurs in sand or quartz as silica and as silicates in 
feldspar, kaolinite and other minerals. Silicon dioxide, or 
silica, is insoluble in waters or acids, except hydrofluoric acid, 
but it may occur in natural waters as finely divided or colloidal 
suspended matter. Silica is widely employed in industry for making 
glass, silicates, ceramics, abrasives, enamels, petroleum products, 
etc . 

In concentrations found in natural and treated waters, silica or 
silicates have no adverse physiological effects. Silicates are 
essential to the growth of many aquatic organisms. 

The data which appear under the heading "Reactive Silicate" should 
properly be referred to as "Unfiltered Reactive Silicate" and are 



reported as Silicon (Si). Data in this series of publications 
prior to 1975 were reported as Silica (SiOj) • 

Acidity 

Acidity in surface or ground waters may be attributable to natural 

■ ■ • ■ 

causes, such as humic acids extracted from swcimps or peat beds, or 

industrial wastes such as pickling liquors, effluent from the 

manufacture of explosives, acid mine drainage or sulphite waste 

liquors. It may also be affected by atmospheric inputs. 

Acidity is best interpreted in conjunction with the pH and 
alkalinity, as well as any other analyses which identify the acidic 
components of water. 

Alkalinity 

Alkalinity in general, is the sum of all the components in the 
water system that act to buffer the water against changes in pH. 
The alkalinity of natural waters is caused by three major classes 
of materials which may be ranked in order of their effect on pH as 
follows: 

1. Hydroxides (rarely present in Ontario) 

2. Carbonates 

3 . Bicarbonates and other salts of weak acids 

The alkalinity of water has little sanitary significance but is of 
importance in water and waste treatment practices. Waters with 
high alkalinity under natural conditions are undesirable because of 
their associated excessive hardness. 



The symbol pH is used to designate the logarithm (base 10) of the 
reciprocal of the hydrogen-ion concentration. It is an index of 

- XXIX - 



the acidity or alkalinity of the solution. The practical pH range 
extends from 0, very acidic, to 14, very alkaline, with the middle 
value of pH 7 corresponding to exact neutrality at 25»C. 

The pH is important in determining the appropriate treatment of 
water supplies. 



Iron 



Iron is one of the most abundant elements in the earth's crust and 
it is a constituent of many industrial wastes. 

When sufficient iron is added to water in the presence of salts 
(chlorides, nitrates, sulphates), ferrous or ferric oxide 
precipitates (iron hydroxides) causing low pH values which are 
toxic to aquatic life. Iron in water may also result in the growth 
of iron bacteria causing unpalatable taste, discolouration of 
cloths and plumbing fixtures, and the formation of scales in water 
mains. 

Phenols 

The phenolic compounds, collectively referred to as phenols, are 
those hydroxyl derivatives of benzene or its condensed nuclei, 
which are determined by the 4-amino antipyrine method. The results 
are reported from many industrial processes and may also be 
released from aquatic plants and decaying vegetation. 

Depending on the concentration, the presence of phenolic compounds 
may be toxic to fish, and may taint the flesh of fish. Phenols in 
very minute concentrations will combine with chlorine to produce 
tastes and odours in water which are usually described as medicinal 
or chemical. 



- XXX 



Hardness 

Water hardness relates to a water's capability to produce lather 
from soap. The higher the hardness, the less lather will be 
formed. Heurdness in water is caused by dissolved divalent metal 
ions, calcium and magnesium being the most common. Natural 
hardness occurs most freiguently in limestone areas. The limestone 
is dissolved by contact with ground and surface water and releases 
calcium and magnesium ions and traces of contaminant metals. 

Hard water, though not considered a health hazard, is undesirable 
for industrial and domestic water supplies because it has a number 
of detrimental effects, the most common being the formation of 
scale in boilers, pipes and water heaters, excessive soap 
consumption in home and commercial laundering, and adverse affects 
in textile, plating and canning industries. 

Results appear under either the heading "Hardness" and "Calculated 
Hardness", depending on the analytical procedure. The former 
results are obtained through titration with ethylene-dieimine-tetra 
acetic acid (EDTA) , the latter by calculation from magnesium (Mg) 
and calcium (Ca) results determined by Atomic Absorption 
Spectrophotometry (AAS) . 

Calcium 

Calcium is relatively abundant in the earth's crust and readily 
soluble in water so that calcium salts and calcium ions are among 
the most commonly encountered substances in water. They may result 
from the leaching of soil and may be contained in sewage and 
industrial wastes.. 

Excessive calcium and magnesium in drinking water have been 
implicated as factors pre-disposing to the formation of concretions 
in the body, such as kidney or bladder stones. On the other hand, 
there is also evidence of adverse physiological effects from an 

- XXXI - 



insufficiency of calcium in water. The calcium ion is a major 
contributor to hardness and is often responsible for boiler scale 
deposits on cooking utensils and excessive soap requirements in 
washing and laundering. Where water is used for irrigation, 
calcium is beneficial to plant growth. 

Ma ernes i\m 

Magnesium is an abundant element and a common constituent of 
natural waters. Magnesium ranks with calcium as a major cause of 
hardness. The effects of magnesium of water used for consumption 
and irrigation are generally the same as those of calcium. 
Magnesium is considered relatively non-toxic to man and not a 
public health hazard because before toxic concentrations are 
reached in water, the taste becomes quite unpleasant. 

Colour 

Colour in water, may be of natural mineral or vegetable origin 
caused by metallic substances such as iron and manganese compounds, 
humus material, peat, tannins, algae, weeds, and protozoa. Waters 
may also be coloured by inorganic or organic soluble wastes from 
industries, such as steelworks, mining, refining, pulp and paper, 
chemicals, and others. Returned irrigation water also contributes 
to colour. 

Colour from natural origin is not considered harmful from a health 
standpoint. However, in domestic water, colour is undesirable 
because of aesthetic considerations. 

Potassium 

Potassium occurs in many minerals and potassium salts exist in 
natural waters as a result of contact with potassium-bearing soils 
and the introduction of certain industrial wastes. The common 



- XXXII 



salts of potassium are highly soluble in water. They resist 
separation from water by natural processes other than evaporation. 

In limited concentrations, potassiiim is an essential nutrifent. 
Excessive amounts of certain potassixim salts in water may have 
detrimental effects on the digestive and nervous systems. 

Bod-ium 

Sodium salts are common to all natural waters and may be present in 
high concentrations in wash waters softened by exchanging calcixim 
and magnesium ions for sodium. Sodium is also found in many 
industrial process effluents, domestic wastes and salts used in 
road de-icing. 

Concentration of salts such as sodium chloride impact objectionable 
tastes and may render water unpalatable. 

Total Organic Carbon (TOO 

Total organic carbon (TOG) , the most significant carbon measurement 
from a water-quality assessment viewpoint, is the arithmetic 
difference between total carbon (TC) and total inorganic carbon 
(TIC) . 

Total organic carbon usually has a direct relationship with 
Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) 
values, but the relationship varies with the composition of the 
organic material present. The carbon tests are rapid and suitable 
for the evaluation of organic pollution levels, assessment of waste 
treatment efficiencies and to a limited extent, the potential 
demand of a waste discharge on the oxygen resources of a water 
body. 



XXXIII 



Dissolved Organic Carbon (DOC) 

The organic content of lakes and rivers depends primarily on the 
products of plants and animals which those water bodies support. 
Most of the organic carbon in water is composed of humic substances 
and partly degraded plant and animal materials, some of which is 
refeistant to microbial degradation. Runoff from agricultural land 
and industrial discharge from industries such as pulp and paper 
will add organic carbon to the water. The degradation of large 
eunounts or organic matter causes depletion of the dissolved oxygen 
concentration and hence, organic carbon is also measured on sewage 
and industrial waste samples. 

Chemical Oxygen Demand (COD) 

The chemical oxygen demand is used in measuring the strength of 
sewage and industrial wastes. The major advantage of this test is 
that laboratory results can be obtained in about three hours 
compared to five days for the five-day biochemical oxygen demand 
test. The chief limitation of the COD analysis is its inability to 
differentiate between biologically oxidizable and biologically 
inert organic matter. The COD almost always exceeds the 
biochemical oxygen demand. 

Solvent Extractables 7 

The solvent extractable test measures the total quantity of 
substances present in a water sample that is readily soluble in an 
appropriate organic solvent. Such substances include fatty acids, 
petroleum products, oils, greases and resins. They are generally 
found in effluents of oil refineries, meat packing plants, 
slaughter houses, dairies, canneries, and a variety of other 
industries. 



XXXIV 



Solvent soluble materials greatly increase the oxygen depletion 
rate in receiving waters and will hinder oxygen exchange with the 
atmosphere by forming slicks. 

Araenic 

Areenic occur naturally, to a small extent, mostly as sulphides and 
as arsenides of metals. Elemental arsenic. is insoluble in water; 
but many of the arsenates are highly soluble. Highest levels of 
arsenic in Onteurio are found in watercourses downstreeun of 
wastewater discharges from metal smelting operations. 

Arsenic is very toxic to humans and the trivalent forms are largely 
retained in the body tissues. Low concentrations of arsenic 
stimulate plant growth but higher concentrations destroy 
chlorophyll in the foliage. 

Mercury 

Mercury may occur naturally as a free metal or as mercuric salts, 
the most common being cinnabar, HgS. Both elemental mercxiry and 
HgS are insoluble in water and are not likely to occur as water 
pollutants. Many synthetic organic salts of mercury are used 
commercially and these salts are highly soluble in water. 

/ 
Mercury is cumulative and toxic to humans and can be concentrated 
and transferred up the food chain to a point where commercial and 
game fish may become unsuitable for human consumption. 
Micro-organisms can methylate inorganic mercury under both aerobic 
and anaerobic conditions to produce a more toxic substance. 

Altminium 

Aluminium occurs in many rocks and ores but never as a pure metal 
in nature. In streams, the presence of aluminium ions may result 



XXXV 



from industrial wastes or more likely from wash water from water 
treatment plants. 

Chromixm 

Few waters contain chromium from natural sources since chromium is 
generally present in rocks and soils as insoluble chromic oxide 
which is strongly sorbed to particulate matter. Chromate or 
dichromate salts are used extensively in metal pickling and plating 
operations, in anodizing aliiminium, in the leather industry as a 
tanning agent, and in the manufacture of paints, dyes, explosives, 
ceramics, paper and many other substances . Chromic or chromite 
salts on the other hand, are used much less extensively, being 
employed as mordants in textile dyeing, in the ceramic and glass 
industry and in photography. Chromium compounds may be present in 
wastes from many of these industries or may be discharged in 
chromium-treated cooling waters where the chromium is used as a 
corrosion inhibitor. 

There is no evidence that chromium salts are ' essential or 
beneficial to human nutrition. Salts of trivalent chromium are not 
considered to be physiologically harmful; however, large doses of 
chromates lead to corrosive effects in the intestinal tract and to 
nephritis. Both the chromic and chromate ions are toxic to plants 
and interfere with the uptake of essential elements. 

Copper 

Copper salts occur in natural surface waters in trace 
concentrations and may occur in industrial waste discharges. 
Copper is used as an algicide for the control of undesirable algae 
growth and in the treatment of soils as a fungicide. 

Copper compounds are toxic to plants and aquatic life. 



- XXXVI - 



iead 



Some natural, waters contain lead in solution. Lead may be 
introduced into water as a constituent of various wastes including 
industrial and mining effluents, lead plumbing and automobile 
exhaust. Certain lead salts, such as acetate and chloride, are 
readily soluble. However, lead which occurs in the carbonate, 
hydroxide and sulphate forms is sparingly soluble and will not 
remain long in natural waters. 

Lead is a cumulative poison that tends to be deposited in the bone. 
The intake that can be regarded as safe cannot be stated definitely 
because the sensitivity of individuals to lead differs 
considerably. Studies on fish indicate that in water containing 
lead salts, a film of coagulated mucus forms over the gills and 
then the entire body, probably as a result of a reaction between 
lead and an organic constituent of mucus. Subsequently, the fish 
will die due to suffocation. The toxic effects of lead on fish 
decreases with increasing hardness and dissolved oxygen. 

Cadmium 

In the elemental form, cadmium is insoluble in water. It occurs in 
nature largely as a sulphide salt, greenockite or as a cadmium 
blend and often as an impurity in zinc-lead ores. 

Cadmium salts are cumulative and highly toxic to man, and have been 
implicated in some cases in the cause of food poisoning. 
Consumption of cadmium salts causes cramps, nausea, vomiting, and 
diarrhea. Cadmium affects reproduction in fish and zooplankton; 
however, the toxic effects vary with species and time of exposure. 



- XXXVII 



Generally, zinc occurs only in trace amounts in surface waters. 
The zinc ion is believed to adsorb strongly and permanently on 
particulate matter (e.g. silt) which settles out of suspension. 

Zinc has no known adverse physiological effects upon man except at 
very high concentrations. At such concentrations, zinc gives water 
a milky appearance and causes a greasy film on boiling, thus making 
it unattractive for domestic water supply. Zinc is toxic to 
aquatic organisms and its toxicity decreases with increasing 
hardness. 

Manganese 

Manganese is similar to iron in that it is found in many industrial 
wastes and occurs in soils as manganic and manganous compounds. 
Under anaerobic conditions the manganic ion is reduced to soluble 
nitrate, sulphate, and chloride salts of manganese and is leached, 
along with iron, into ground and surface waters. Like iron, its 
presence may indicate domestic or industrial pollution. 

Water with high manganese content is undesirable for its taste, 
colour and tendency to form deposits on cooking utensils. 

/ • '• • 

Nickel 

Nickel in ores and minerals is insoluble-; but as a salt (nickel 
ammonium sulphate, nickel nitrate, nickel chloride) is highly 
soluble. Electroplating wastes may contain substantial amounts of 
nickel salts. 

Nickel and its salts have generally proven to be non-toxic to man 
even at very high levels. Contact with nickel salt solutions may 
result in dermatitis and repeated inhalations of nickel compounds 
can cause lung cancer. 

- XXXVIII - 



Fluoride 

Fluorides in high concentrations are not a common constituent of 
natural suriface waters, but may naturally occur in detrimental 
concientrations in ground waters. 

Excess concentrations affect animal breeding efficiency and may 
have detrimental effects on some plants. 

Cyanide 

One of the major sources of cyanide in Northern Ontario is 
associated with the gold mining and milling industry. Also cyanide 
is likely to occur in effluent from gas works and coke ovens/ from 
the scrubbing of gases produced from blast furnaces, in wastes from 
other chemical industries. 

Cyanide in water is toxic to biological life, the lethal 
concentration depending on water quality, temperature, type and 
size of organism. The toxicity of cyanide increases with decreases 
in dissolved oxygen below the saturation level . 

Cobalt 

Cobalt occurs naturally in t^e minerals cobaltite, smaltite and 
•erythrite. It is widely used in the manufacture of alloys, the 
tungsten carbide tool industry and as pigments used in glass 
staining. 

Cobalt is an essential element at trace levels for both animals and 
plant nutrition. It is known to be one of the main constituents of 
Vitamin B, 
high concentrations. 



- XXXIX 



3 . RADIOCHEMICAL ANALYSES 

All elements are made up of atoms i each of which consists of a 
central nucleus surrounded by a number of electrons. Some nuclei 
are radioactive; they emit excess energy in the form of ionizing 
radiation as a result of nuclear disintegrations. The three types 
of ionizing radiations which are of principal interest in 
environmental studies are referred to as alpha, beta and gamma 
radiations. 

1. Alpha rays are streams of fast moving helium nuclei. These 
are particles which can travel only a few centimetres in air 
and can be stopped by a sheet of paper or a layer of skin. 

2. Beta rays are streams of fast moving electrons which are very 
much lighter than helium nuclei. The maximum range of most 
common beta rays is a few metres in the air or one to two 
centimetres in the human body. 

3. Gamma rays are highly penetrating electromagnetic radiation of 
the same family as radio waves and x-rays. Like x-rays, gamma 
mass rays can pass right through the human body. 

The number of nuclear disintegrations occurring in a substance per 
second is a measure of ,its radioactivity. The unit of 
radioactivity used in this report is becquerel (Bq) . One becquerel 
equals one nuclear transformation per second and corresponds to 
approximately 27 picocuries (a measure of radioactivity used in 
previous reports) . Radiological half life is the length of time 
required for one half of the unstable atom to disintegrate or 
change (i.e., radioactive decay). 

Exposure to radiation is characterized by the transfer of energy to 
molecules of the cells which make up body tissues and organs. This 
can affect the normal function of the cells, resulting in damage to 
the tissues and organs. Exposure to the small doses of radiation 

- XL - 



which might be encountered in the environment will not result in 
immediate detectable damage; however, long-term effects may result. 
These effects are in the apparently random occurrence of induced 
cancers and genetic defects in a small proportion of the exposed 
population. The numbers of effects induced are considered to be 
directly proportional to the amount of absorbed radiation. 

Gross-alpha 

Gross-alpha is a measure of the total radioactivity of all the 
alpha emitting materials in a sample. Measurements of gross-alpha 
activity provide useful reference points to enable trends to be 
detected. However, the results cannot be used to determine 
radiation dose or health effects since the short range of alpha 
particles means that some will not be detected, thereby causing an 
underestimation of the total activity. Also, the alpha particles 
may be emissions from a mixture of materials that are 
radiologically and biologically different. 

Gross-beta 

Gross-beta is a measure of the total radiation of all the beta 
emitting materials in a sample. Measurements of gross-beta 
activity provide useful reference points to enable trends to be 
detected but cannot be used to determine radiation dose or liealth 
effects. 

Radium-226 

Radium-226 is a naturally occurring alpha-particle emitter formed 
from the decay of uranium-238 and has a radiological half life of 
1602 years. 



XLI - 



Uranitun- total 

Total uranium exists primarily as the isotope uranium-238 with less 
than 1% occurring as iiranium-235. Uranium is a naturally occvirring 
alpha-particle emitter which was formed at the same time as the 
earth (about 5 x lo' years) and is still present in significant 
quantities due to its extremely long radiological lialf-life (4.5 x 
10 years) . 

Cesitimm-137 



Gesium-137 is a beta-particle emitter formed as a fission product 
in nuclear weapons detonation and atomic reactor operation. 
Cesium-137 is readily adsorbed and retained by biological systems. 
Its radiological half life is 30 years. 

Cesium-134 

Cesium-134 is a beta-particle emitter also formed as a fission 
product in nuclear weapons detonation and atomic reactor operation. 
Cesium-134 is of less importance than Cesium-137 as its 
radiological half-life is only 72 hours. 

Cobalt-60 

I 
Cobalt-60 is primarily foirmed in atomic reactor operation due to 
the neutron activation of trace quantities of cobalt-59 found in 
steel. Insignificant quantities are also formed from nuclear 
weapons detonation. Cobalt-60 has a radiological half life of 5.3 
years and emits both beta and gamma radiation. 

Tritium 

Tritium exists fairly uniformly in the environment as a result of 
natural production by cosmic radiation and residual fallout from 



XLII 



nuclear weapons tests. Thiis background level is gradually being 
increased by the use of nuclear reactors to generate electricity. 

Current tritium from the nuclear power industry comprises a small 
proportion of environmental tritium in comparison with that from 
nuclear weapons fallout and jiatur ally produced tritium. However, 
nucleeur reactors and fuel-processing plants are localized sources 
of tritium because of discharges during normal operation. This 
industry is expected to become the major source of environmental 
tritixim contamination some time in the future if present growth 
trends continue and nuclear explosion in the atmosphere is not 
resximed. Tritium is produced in light water nuclear reactors by 
ternary fission, neutron capture. in coolant additives, control rods 
and plates, and activation of deuterium. About 1% of the tritium 
in the primary coolant is released in gaseous form to the 
atmosphere; the remainder is eventually released in liquid waste 
discharges. Most of the tritium produced in reactors remains in 
the fuel and is released when the fuel is reprocessed. 

Naturally occurring tritium is most abundant in precipitation and 
lowest in aged water because of its physical decay by beta emission 
to helium. 

Iodine 

Iodine is a chemical oxidant. It disinfects in a manner similar to 
chlorine. Iodine is the least soluble of all the halogens, hence 
it is the least likely to be hydrolized by water. It also has the 
lowest oxidation potential, that is, it reacts more slowly with 
organic compounds than chlorine. Because of this stability, iodine 
does not react with nitrogenous compounds as does chlorine. Iodine 
remains effective through a wider range than chlorine; chlorine 
becomes less stable at pH of 8 as compared to iodine at pH of 10. 



4. SYNTHETIC ORGANIC ANALYSES 

The synthetic organic compounds referred to in this section are 
classified as pesticides and industrial chemicals. These compounds 
contain linked carbon atoms in their chemical structure and are, 
for the most pairt, synthesized from common chemicals. Furthermore, 
thfey may be subdivided into chemical families of compounds sharing 
common characteristics. For example, organochlorine compo\inds 
(chlorinated hydrocarbons) contain chlorine, hydrogen and carbon in 
their structure; they have a tendency to accumulate in the fatty 
tissues of animals and are stable compounds (i.e. , persistent). 

Until recently, only a few classes of synthetic organic compounds 
such as drugs, food additives and pesticides were controlled by 
legislation. For example, the only pesticides which may be of fered 
for sale in Ontario are those which have been registered under the 
authority of the Pest Control Products Act which is administered by 
Agriculture Canada. The term pesticide includes insecticides, 
herbicides and fungicides which are chemical compounds used to 
control insects, weeds or fungi (i.e., "pests") that attack crops, 
animals and man. In contrast to the regulation of pesticides, 
thousands of unregistered synthetic organic chemicals are in daily 
use as raw materials, products and additives. Very little is known 
about their possible health and environmental effects because of 
their sheer number and diversity of use. Many are not hazardous, 
but the adverse effects already encountered by some have created 
concern for preventative measures of both known and potentially 
hazardous substances. 

Pclychlorinated Biphenvls (PCBs) 

PCBs are a range of industrial chemicals produced by direct 
chlorination of biphenyl. The North American products in this 
family are sold under the name Aroclor. Aroclors are characterized 
by a four digit number, such as (Aroclor 1242, or Aroclor 1254, of 
which the last two digits refer to the weight percentage of 

- XLIV - 



chlorine in the products. There are 208 possible compounds which 
could be formed by this reaction. Each product is a different 
mixture of up to 100 of these, each with its own unique physiqal, 
chemical and biological properties. 

The main characteristics of PCBs are their chemical, physical, 
biological inertness and electrical insulating properties. They 
have been widely used in transformers and capacitors, as heat 
exchange fluids or plasticizers, and is present in inks, paint, 
lubricants, and many other products. Spills and waste disposal 
practices have resulted in very large inputs of these chemicals to 
all facets of the environment. 

PCBs are lipophilic, and thus continuing environmental inputs have 
led to biological uptake and concentration. Of particular concern 
are the excessive levels detected in some fish. lievels in water 
and air to date have not demonstrated a threat to human health, as 
might arise from fish consumption. PCBs have been shown to be both 
acutely and chronically toxic, carcinogenic and teratogenic (to 
cause developmental malformations) . Limits for huinan consumption 
have been set on the basis of tests on monkeys and rats. The 
present acceptable level of PCBs in fish is 2.0 ppm. However, 
0.1 ppm has been suggested as a level for protection of the 
fisheries resource from reproductive failure. Long-term use of 
PCBs, at elevated temperatures, and inefficient incineration of 
these materials have been shown to produce the highly toxic 
chlorodibenzofurans, closely related to dioxins. 

Trichlorophenoxvacetic Acid (2.4,5-T) 

2,4, 5-T is a chlorophenoxy acid herbicide. Other members of this 
family include 2,4-D and 2,4,5-TP which were introduced as 
selective weed killers at the end of World War II. Their uses 
include weed control in cereal crops, lawns, along roadsides, hydro 
and railroad rights-of-way, and control of aquatic weeds. 



The human toxicity of these herbicides is low; effects on livestock 
and wildlife from current environmental levels would appear to be 
negligible and no discernible toxic effects have been reported in 
fish at levels below 100 mg/L. 

However, 2,3,7,8-tetrachlorodibenzo-dioxin (TCDD) , an extremely 
toxic compo\uid, has been detected in 2,4,5-T formulations as a 
by-product of its manufacture, thus raising doubts as to the human 
safety of the use of 2,4,5-T, and the related herbicide 2,4,5-TP 
(Silvex) . A tolerance level of 0.1 ppm 2,3,7,8-TCDD in 2,4,5-T 
formulation has been set, but the adequacy of the safety factor is 
still under discussion. 

Pentachlorophenol (PCP) 

Pentachlorophenol is used as a defoliant, insecticide, fungicide 
and wood preservative. The salts, esters and ethers of PCP are 
also effective herbicides. 

PCP is considered relatively toxic to wildlife and fish and its 
presence in water can cause tainting of fish flesh, reducing its 
palatability. PCP can be harmful to man if inhaled and absorbed 
through the skin. There is no known antidote to PCP poisoning. 

In addition to its inherent 'toxicity, a further problem is posed 
by the presence of high chlorinated dioxins, (octachlorodioxin, 
heptachlorodioxin, hexachlorodioxin) in PCP formulations. 



XLVI 



STATION IDENTIFIER CODES. OUT^IFYING REMARKS CODES 
AND ABBREVIATED PARAMETER HEADINGS 



Station Identifier Codes 

The station identifier codes which appear in the index and the top 
right-hand corner of the data pages are numerical descriptions of 
the sampling station locations and are used primarily for 
electronic data processing of the water quality data. The eleven 
digit figure is decoded as follows: the first two digits refer to 
the terminal basins (see figures 2 and 3), the following four 
digits refer to the river basin (each river basin in a terminal 
basin is assigned a unique number) , the next three digits refer to 
the station number within the river basin and the last two digits 
refer to the type of sample (e.g. 01-lake sample, 02-stream sample, 
82 to 89-composite sample, e.g. .83 - 3 part composite across a 
station sampling range) . 

Oualifying Remark Codes 

Distance 

The distance in kilometres is measured along the centre line of a 
watercourse to the sampling station location from the junction of 
the related terminal stream arid terminal basin. 



XLVII 



Abbreviated Headings 



BOW 

STN NO 

LAT 

LONG 

UTM . 

SAMP DTE DY MO YR 

HODR LMT 

STN DIST FEET 

STN BRG 



SAMP DEPTH MTRS 
PJ 



body of water 

base station number 

latitude 

longitude 

Universal Transverse Mercator Grid 

sample date; day, month, year 

hour(s) local mean time (2400 hour 

clock) 
distance from base station (in feet) 

(not applicable) 
bearing of sampling point (deg N) 
from base station (not 

applicable) 
sample depth (in metres) 
project (not applicable) 



Abbreviated Parameter Headings 

The following list are alphabetic codes, appearing as parameter 
headings, are a series of unique codes used for computer 
processing. Each alphabetic code identifies a particular water 
quality parameter analyzed by the laboratory* 



- XLVIII 



PAGE FOR TEST NAME DESCRIPTION 



XLIX 



TEST NAME 


DESCRIPTION 


TEST 




NAME 


DESCRIPTION OF TEST 


010ACE 


D10-ACENAPHTHENE 


010PHE 


D10-PHENANTHRENE 


D12CHR 


D12-CHRYSENE 


D12PER 


D12-PERYLENE 


08NAPH 


D8-NAPHTHALENE 


Die 


CARBON. DISSOLVED INORGANIC 


DO 


DISSOLVED OXYGEN 


OOC 


CARBON. DISSOLVED ORGANIC 


ECIGMF 


ESCHERICHIA COLI MF--IG 


ECMF 


ESCHERICHIA COLI MF 


ECMPN 


E.COLI BY MPN 


FCXF 


FECAL COL I FORM MF 


FEUT 


IRON, UN FILTERED TOTAL 


FSMF 


FECAL STREPTOCOCCUS MF 


FWPH 


PH FIELD 


FWSTRC 


STREAM CONDITION 


FUTEMP 


TEMPERATURE, WATER 


HARDT 


HARDNESS, TOTAL 


HGUT 


MERCURY, UNFILTERED TOTAL 


lONCAL 


ION BALANCE CALCULATION 


KKUR 


POTASSIUM, UNFILTERED REACTIVE 


HGUR 


MAGNESIUM, FILTERED REACTIVE 


MNUT 


MANGANESE, UNFILTERED TOTAL 


MOIST 


MOISTURE 


MOUT 


MOLYBDENUM, UNFILTERED TOTAL 


NAUR 


SOOIUM, UNFILTERED REACTIVE 


NIUT 


NICKEL, UNFILTERED TOTAL 


NNHTFR 


AMMONIUM, TOTAL FILTER.REAC 


NNHTUR 


AMMONIUM, TOTAL UNFIL.REAC 


NN02FR 


NITRITE, FILTERED REACTIVE 


NN02UR 


NITRITE, UNFILTERED REACTIVE 


NN03FR 


NITRATE, FILTERED REACTIVE 


MN03UR 


NITRATE, UNFILTERED REACTIVE 


NNOTFR 


NITRATES TOTAL, FILTER.REAC 



UNITS OF MEASURE 

MICROGRAM PER LITRE 

MICROGRAM PER LITRE 

MICROGRAM PER LITRE 

MICROGRAM PER LITRE 

MICROGRAM PER LITRE 

MILLIGRAM PER LITRE AS CARBON 

MILLIGRAM PER LITRE AS OXYGENM 

MILLIGRAM PER LITRE AS CARBON 

COUNTS PER 100 ML 

COUNTS PER 100 ML 

RESULT = 1 MEANS COMPOUND PRESENT 

COUNTS PER 100 ML 

MILLIGRAM PER LITRE AS IRON AS (FERRUM) 

COUNTS PER 100 ML 



DEGREES CELCIUS 

MILLIGRAM PER LITRE AS CALCIUM CARBONATE 

MICROGRAM PER LITRE AS MERCURY (HYDRARGYRUM) 

MILLIGRAM PER LITRE AS POTASSIUM (KALIUM) 
MILLLIGRAM PER LITRE AS MAGNESIUM 
MILLIGRAM PER LITRE AS MANGANESE 
PERCENT 

MILLIGRAM PER LITRE AS MOLYBDENUM 
MILLIGRAM PER LITRE AS SOOIUM 
MILLIGRAM PER LITRE AS NICKEL 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 
MILLIGRAM PER LITRE AS NITROGEN 



TEST NAME 


DESCRIPTION 


TEST 
NAME 


DESCRIPTION OF TEST 


NNTKUR 


NITROGEN, TOT, KJELOAHL/UNF.REA 


P1ALDR 


ALDRIN 


P1BHCA 


HEXACLOROCYCLOHEX,ALPHA-BHC 


P1BHCB 


HEXACLOROCYCLOHEX,BETA-BHC 


P1BHCG 


HEXACLOROCYCLOHEX , GAMMA - BHC 


P1CHLA 


CHLORDANE, ALPHA 


P1CHLG 


CHLORDANE, GAMMA 


P10IEL 


OIELDRIN 


P10M0T 


OMOT METHOXYCHLOR 


P1EN01 


ENOOSULFAN I 


P1EN02 


ENDOSULFAN II 


P1ENDR 


ENORIN 


P1ENDS 


ENDOSULFAN, SULPHATE 


P1EN0T 


ENDOSULFAN, TOTAL (CACULATED) 


P1HEPE 


HEPTACHLOREPOXIDE 


P1HEPT 


HEPTACHLOR 


P1MIRX 


MI REX 


P10CHL 


OXYCHLOROANE 


P10P0T 


OP-DDT 


P1PC8T 


PCS TOTAL 


P1PP00 


PP-DDD 


P1PP0E 


PP-DDE 


P1PPDT 


PP-OOT 


P1T0X 


TOXAPHENE 


P2ATRA 


ATRA2INE 


P2CYAN 


CYANAZINE 


P2CYPR 


CYPRAZINE 


P2DATR 


ATRA2INE,DEETHYLATED 


P2PRCX 


PROMETONE 


P2SENC 


SENCOR 


P2SIM 


SIMA2INE 


P3245T 


245 TRICHLOROPHNOXYACETIC 


P324D 


24 OICHLOROPHENOXYACETIC 


P32A.DB 


24 DICHLOROPHENOXYBUTYRIC 


P324DP 


24 OP 



UNITS OF MEASURE 

MILLIGRAM PER LITRE AS NITROGEN 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 

NANOGRAM PER LITRE 



LI 



TEST NAME 


DESCRIPTION 


TEST 
NAME 


DESCRIPTION OF TEST 


P30ICA 


DICAM8A 


P3MCPA 


MCPA 


P3MCPB 


MCPB 


P3MCPP 


MECOPROP 


P3PICL 


PICLORAM 


P3SILV 


SILVEX 


P4CLFN 


CHLOROFENVINPHOS 


P40EMT 


DEMETON 


P40IAZ 


OIAZINON 


P401ME 


DIMETHOAK 


P40URS 


DURSBAN 


P4ETH1 


ETHION 


P4GUTH 


GUT HI ON 


P4LEP0 


LEPTOPHOS 


P4MALA 


MALATHIOM 


P4PAL0 


PHOSALONE 


P4PA(tA 


PARATHION 


P4PMET 


PHOSMET 


P6CAR8 


CARBOFURAN 


P6CARY 


CARBARYL 


P6CYCL 


CYCLOATE 


P6EPTM 


. EPTAM 


P6H0LI 


MOLINATE 


P6PEBU 


PEBULATE 


P6SUTN 


SUTAN 


P6VERN 


VERNOLATE 


PBUT 


LEAD, UNFILTERED TOTAL 


PH 


PH (-LOG H* CONCN) 


PHHOL 


PHEMOLICS, UNFILERED REACTIVE 


PNACNE 


ACENAPHTHENE 


PNACNY 


ACEHAPHTHYLENE 


PNANTH 


ANTHRACENE 


PNBAA 


BENZO(A)ANTHRACENE 


PNBBF 


BEN20 C8) FLUORANTHENE 


PNBKF 


BENZO (K) FLUORANTHENE 



UNITS OF MEASURE 

NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
MILLIGRAM PER LITRE AS LEAD (PLUMBUM) 

MICROGRAM PER LITRE AS PHINOL 
MICROGRAM PER LITRE 
MICROGRAM PER LITRE 
MICROGRAM PER LITRE 
MICROGRAM PER LITRE 
MICROGRAM PER LITRE 
MICROGRAM PER LITRE 



LII 



TEST NAME 


DESCRIPTION 










TEST 
NAME 


DESCRIPTION OF TEST 


UNITS OF 


MEASURE 




PHCHRY 


CHRYSENE 


MICROGRAM 


PER 


LITRE 




PNOAHA 


OIBENZO(AH)ANTHRACENE 


MICROGRAM 


PER 


LITRE 




PNFLAN 


FLUORANTHENE 


MICROGRAM 


PER 


LITRE 




PNFLUO 


FLUORENE 


MICROGRAM 


PER 


LITRE 




PNGHIP 


BENZO(G,H.I) PERYLENE 


MICROGRAM 


PER 


LITRE 




PNINP 


INDENO(1,2.3-CD) PYRENE 


MICROGRAM 


PER 


LITRE 




PNNAPH 


NAPHTHALENE 


MICROGRAM 


PER 


LITRE 




PNPHEN 


PHENANTHRENE 


MICROGRAM 


PER 


LITRE 




PNPYR 


PYRENE 


MICROGRAM 


PER 


LITRE 




POALA 


ALACHLOR 


NANOGRAM 


'ER 


LITRE 




POMET 


HETALACHLOR 


NANOGRAM 


»ER 


LITRE 




PP04FR 


PHOSPHATE, FILTERED REACTIVE 


MILLIGRAM 


PER 


LITRE AS 


PHOSPORUS 


PP04UR 


PHOSPHATE, UNFILTERED REACTIVE 


MILLIGRAM 


PER 


LITRE AS 


PHOSPORUS 


PPUT 


PHOSPHORUS, UNFtLTERED TOTAL 


MILLIGRAM 


PER 


LITRE AS 


PHOSPORUS 


PSAMF 


PSEUDOMON. AERUGINOSA MF 


COUNTS PER 100 ML 




RSF 


RESIDUE, FILTERED 


MILLIGRAM 


PER 


LITRE 




RSP 


RESIDUE, PARTICULATE 


MILLIGRAM 


PER 


LITRE 




RST 


RESIDUE, TOTAL 


MILLIGRAM 


PER 


LITRE 




RSTLOI 


RES I DUE, TOTAL, LOSS ON IGNIT. 


MILLIGRAM 


PER 


LITRE 




SBUT 


ANTIMONY, UNFILTERED TOTAL 


MILLIGRAM 


PER 


LITRE AS 


ANTIMONY 


SEUT 


SELENIUM, UNFILTERED TOTAL 


MILLIGRAM 


PER 


LITRE AS 


SELENIUM 


SI03UR 


SILICATES, UNFILTERED REACTIVE 


MILLIGRAM 


PER 


LITRE AS 


SILICON 


SOLEXT 


SOLVENT EXTRACTABLES 


MILLIGRAM 


PER 


LITRE 




SOLSXT 


SOLVENT EXTRACT SOXHLET 


MILLIGRAM 


PER 


LITRE 




SRUT 


STRONTIUM, UNFILTERED TOTAL 


MILLIGRAM 


PER 


LITRE AS 


STNITIUM 


SS04UR 


SULPHATE, UNFILTERED REACTIVE 


MILLIGRAM 


PER 


LITRE AS 


NIOBIUM 


TCMF 


COL I FORM, TOTAL MF 


COUNTS PER 100 MLM 




TOC 


CARBON, TOTAL ORGANIC 


MILLIGRAM 


PER 


LITRE AS 


CARBON 


TURB 


TURBIDITY 


FORMAZIN TURBIDITY UNIT 


UUUT 


URANIUM, UNFILTERED TOTAL 


MILLIGRAM 


PER 


LITRE AS 


THORIUM 


X1HC8D 


HEXACHLOROBUTAOIENE 


NANOGRAM PER LITRE 




X1HCCP 


HEXACHLORO CYCLO PENTADIENE 


MICROGRAM 


PER 


LITRE 




X2123 


TRICHLOROBENZENE 1,2,3 


NANOGRAM PER LITRE 




X21234 


TETRACHLOROBENZENE 1,2,3,4 


NANOGRAM PER LITRE 




X21235 


TETRACHLOROBENZENE 1,2,3,5 


NANOGRAM PER 


.ITRE 





LIII 



OTHER ABBREVIATIONS 



ARITH MEAN 


arithmetic mean 




AVE. 


avenue 




AVG OR GEOM MN 


arithmetic mean or geometric mean 


(denoted by *) 


BLVD. 


boulevard 




BR. 


branch, bridge or brook 




CX)RP . 


corporation 




CAN." 


Canadian 




C.N.R. 


Canadian National Railway 




CO. 


county or company 




CONG. 


concession 




C.P.R. 


Canadian Pacific Railway 




CR. 


Creek 




DR. 


drive 




FT. 


feet 




GEOM MEAN 


geometric mean 




HWY. 


highway 




JNT. 


junction 




L. 


left 




MG 


milligram (s) 




MG/L or mg/L 


milligrams per litre 




ML 


millilitre(s) 




N. 


north 




NG/L 


nanogram (s) per litre 




NO /OF SAMPLES 


number of samples 




PT. 


part or point 




Q.E.W. 


Queen Elizabeth Way 




R. 


river or right 




RD. 


road 




R.R. 


railroad 




RW.. 


railway 




S. 


south 




STD DEV 


standard deviation 




S.T.P. 


sewage treatment plant 




TWP. 


township 




UG/L 


micrograms per litre 




W.P.C.P. 


water pollution control plant 




WW. 


water-works 





TEST NAME DESCRIPTION 



TEST 

NAME DESCRIPTION OF TEST 



X2124 

X212A5 

X213S 

X2HCB 

X2HCE 

X20CST 

X2PNCB 

X2T236 

X2T245 

X2T26A 

X3234 

X323A5 

X32356 

X3245 

X3246 

X3PCPH 

ZNUT 



TRICHLOROBENZENE 1,2,4 
TETRACHL0R0BEN2ENE 1.2,4,5 
TRICHLOROBENZENE 1,3,5 
HEXACHLOROBENZENE 
HEXACHLOROETHANE 
OCTACHLOROSTYRENE 
PENTACHLOROBENZENE 
TRICHLOROTOLUENE 2,3.6 
TRICHLOROTOLUENE 2,4,5 
TRICHLOROTOLUENE 2, 6. A 
TRICHLOROPHENOL 2,3,4 
TETRACHLOROPHENOL 2,3,4,5 
TETRACHLOROPHENOL 2,3,5,6 
TRICHLOROPHENOL 2.4,5 
TRICHLOROPHENOL 2.4,6 
PENTACHLOROPHENOL 
ZINC. UN FILTERED TOTAL 



UNITS OF MEASURE 

NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
MILLIGRAM PER LITRE AS ZINC 



- LIV - 



TEST NAME 


DESCRIPTION 


TEST 
NAME 


DESCRIPTION OF TEST 


X2124 


TRICHLOROBEHZENE 1,2,4 


X21245 


TETRACHL0R0BEN2ENE 1,2,4,5 


X2135 


TRICHLOROBENZENE 1,3,5 


X2HCB 


HEXACHLOROBEMZENE 


X2HCE 


HEXACHLOROETHANE 


X20CST 


OCTACHLOROSTYRENE 


X2PNCB 


PENTACHLOROBENZENE 


X2T236 


TRICHLOROTOLUENE 2,3,6 


X2T245 


TRICHLOROTOLUENE 2,4,5 


X2T26A 


TRICHLOROTOLUENE 2, 6, A 


X3234 


TRICHLOROPHENOL 2,3,4 


X323A5 


TETRACHLOROPHENOL 2,3,4.5 


X32356 


TETRACHLOROPHENOL 2,3,5,6 


X3245 


TRICHLOROPHENOL 2,4,5 


X3246 


TRICHLOROPHENOL 2.4.6 


X3PCPH 


PENTACHLOROPHENOL 


2NUT 


ZINC, UNFILTERED TOTAL 



UNITS OF MEASURE 

NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
NANOGRAM PER LITRE 
MILLIGRAM PER LITRE AS ZINC 



LIV 



OTHER ABBREVIATIONS 



ARITH MEAN 


arithmetic mean 


AVE. 




avenue 


AVG OR GEOM MN 


arithmetic mean or geometric i 


BLVD. 




boulevard 


BR. 




branch, bridge or brook 


CORP. 




corporation 


CAN. 




Canadian 


C.N.R. 




Canadian National Railway- 


CO. 




county or company 


CONC. 




concession 


C.P.R. 




Canadian Pacific Railway 


CR. 




Creek 


DR. 




drive 


FT. 




feet 


GEOM MEAN 


geometric mean 


HWY. 




highway 


JNT. 




junction 


L. 




left 


MG 




milligram(s) 


MG/L or 


mg/L 


milligrams per litre 


ML 




millilitre (s) 


N. 




north 


NG/L 




nanogram (s) per litre 


NO/OF SAMPLES 


number of samples 


PT. 




part or point 


Q.E.W. 




Queen Elizabeth Way 


R. 




river or right 


RD. 




road 


R.R. 




railroad 


RW. 




railway 


S. 




south 


STD DEV 




standard deviation 


S.T.P. 




sewage treatment plant 


TWP. 




township 


UG/L 




micrograms per litre 


W.P.C.P 




water pollution control plant 


WW. 




water- works 



LV 



An "Exponent" is used to move the decimal point to the right when 
the result is greater than 7 digits or to the left if the result is 
measured to more than three decimal places. 

EXPONENT = + 4 multiple result by io,000 
= + 3" •' " 1,000 
' = + 2" " " 100 

= + 1" " "10 
= - 1 divide result by 10 
= - 2" " " 100 
= - 3" " " 1,000 
= - 4" " •• 10,000 



LVI 



Arithmetic Mean 



GLOSSARY OF TERMS 

The nth quotient of the sununation of n 
observations . The equation for the arithmetic 
mean (X) can be expressed as: 

X, * X, * X3 +... * X, 



Detection Limit 



The amount of analyte required to be present 
to ensure that when it is 'absent' it will not 
be reported as 'present'. 



Geometric Mean 



The nth root of the product of n observations. 
The equation for the geometric mean (G ) can be 



expressed as: 



G. = 



V X, X X, 



X X„ 



antilog 



(log X, log Xj 



log X,) 



Standard Deviation 



A measure of variability or dispersion. For 
a set of n observations, X,-; i = 1, . . . , n. The 
standard deviation is given as: 



S = V DCx. - X) / (n - 1) 



LVII 



SELECTED REFERENCES 



Environment Canada, Inland Waters Directorate, Water Survey of Canada 
"Surface Water Data, Ontario". 



Ontario Ministry of Environment, 1978. (Revised 1984) "Water Management 
- Goals, Policies, Objectives and Implementation Procedures of the 
Ministry of Environment". 



Ontario Ministry of Environment, Lciboratory Services Branch, 1981. 

"Outlines of Analytical Methods, A Guide to the Occurrence, 
Significance, Sampling and Analytical of Chemical and 
Microbiological Parameters in Water, Sediment, Soil, Vegetation and 
Air.". 



Ontario Ministry of Environment and Ministry of Natural Resources, 1988. 
"Guide to Eating Ontario Sport Fish." 



LVIII 



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