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5f 

no. 200 
c>l 


STATE  OF  ILLINOIS 

WILLIAM  G.  STRATTON,  Governor 

DEPARTMENT  OF  REGISTRATION  AND  EDUCATION 

VERA  M.  BINKS,  Director 

DIVISION  OF  THE 

STATE     GEOLOGICAL     SURVEY 

JOHN  C.  FRYE,  Chief 
URBANA 


CIRCULAR    200 


PRELIMINARY  REPORT  ON  URANIUM 
IN  HARDIN  COUNTY,  ILLINOIS 


BY 


J.  C.  BRADBURY,  M.  E.  OSTROM,  and  L.  D.  McVICKER 


PRINTED  BY  AUTHORITY  OF  THE  STATE  OF  ILLINOIS 


URBANA,  ILLINOIS 

1955 


ILLINOIS  ULOLOGICaL 
SURVEY  LIBRARY 

SEP  28  1955 


Digitized  by  the  Internet  Archive 

in  2012  with  funding  from 

University  of  Illinois  Urbana-Champaign 


http://archive.org/details/preliminaryrepor200brad 


^7 


PRELIMINARY    REPORT    ON    URANIUM 
IN    HARDIN    COUNTY,    ILLINOIS 

by 
J.  C.  Bradbury,  M.  E.  Ostrom,  and  L.  D.  McVicker 


ABSTRACT 


Hicks  dome  in  Hardin  County,  111.,  is  an  eroded  structural 
dome  whose  specific  mode  of  formation  is  not  clear.    Associated 
with  it  are  explosion  breccias  and  pendotite  dikes.    The  central 
part  of  the  dome  is  an  area  of  about  1   1/2  square  miles  underlain 
by  rocks  of  Devonian-New  Albany  age,  principally  limestone  and 
chert  bordered  by  black  shale.    The  bedrock  in  the  central  areas 
of  the  dome,  as  well  as  in  other  adjacent  areas,  is  covered  by  red 
and  yellow  clays  believed  to  be  a  residuum  resulting  from  the 
leaching  of  cherty  Devonian  limestone.    Chert  breccias,  cemented 
by  secondary  silica,  also  are  present. 

Tests  of  about  200  samples  taken  from  the  dome  and  through- 
out the  county  suggest  that  the  residual  clays  and  breccias  within 
the  Devonian-New  Albany  area  of  the  dome  are  generally  more 
radioactive  than  samples  elsewhere,  though  there  are  some  ex- 
ceptions.   Samples  of  fluorspar,  zinc  and  lead  ores,  and  concen- 
trates from  these  ores  have  little  or  no  radioactivity  as  measur- 
ed by  a  laboratory  Geiger  counter.     U308  determinations  made  by 
chemical  procedures  on  25  samples  having  some  of  the  higher 
uranium  equivalent  values  were  all  lower  than  the  uranium  equiv- 
a  ent  values.    All  the  samples  analyzed  for  UjOg  contained  less 
of  this  compound  than  the  minimum  of  0.1  percent  for  which  prices 
are  quoted  by  the  Atomic  Energy  Commission. 

INTRODUCTION 

by  J^teV"*  SlX  mTh3  C°nSiderable  Publ-  -terest  has  been  aroused 

County    m      Contre8enCe         radi°aCtive  ™te»*ls  on  Hicks  dome  in  Hardin 

men"  Ld  s  C°f  "mn*  lntereSt  has  bee"  maintained  by  reports*  that  have 

4  and  tren7leS  '™*ln*  fr°m  °-10%  *°  °-21%  U3°8.  and  leasing,  test  pit- 
<g  and  trenching,  and  sampling  has  been  under  way  in  the  area 

nois  gS  CiT  °f  any  "^  POtential  min«al  resource  in  the  State,  the  Illi 

for  th f  C  dCPOSltS  f°r  the  benefit  of  owners  and  prospectors  and 

:^n"a0f  aU  citizens  °f  the  state-  A  large  number  of  a"pi" 

"tivity  ha     t     rat,0metHCally  and  S°me  of  those  that  showed  higher  radio- 
!_i^yhave  been  chemically  analyzed  for  uranium. 

Hardin  County  Independent,  March   17,    1955,  p.    1. 


o      Sample 


^    Sample    from    breccia 


•      Sample    from     dike 


Fig.   1  -  Sketch  map  showing  sample  locations  on  Hicks  Dome  and  vicinity     ^s  are  show, 
g  by  solid  lines.    The  approximate  limits  of  the  area  underlain  by  rocks  of 

Devonian-New  Albany  age  are  indicated  by  a  dotted  line. 


URANIUM  IN  HARDIN  COUNTY  3 

Because  of  the  widespread  public  interest  in  Hicks  dome,  this  progress 
report  has  been  prepared  to  make  available  the  Geological  Survey's  informa- 
tion as  of  this  date.    As  our  investigations  are  incomplete,  all  deductions  and 
hypotheses  expressed  herein  are  subject  to  revision  as  investigations  proceed 
further  and  additional  data  become  available.     The  basic  analytical  data  pre- 
sented here,  however,  are  of  more  lasting  value. 

GEOLOGY    OF   HICKS  DOME 

Hicks  dome,  which  is  both  a  structural  and  a  topographic  feature,  is  lo- 
cated about  7  1/2  miles  north  of  Rosiclare,  centering  in  sec.  30,  T.   11  S.,  R. 
8  E.    Although  the  beds  dip  outward  for  several  miles  from  the  center  of  the 
dome,  for  the  purposes  of  this  report  the  term  "Hicks  dome  area"  will  be  given 
the  approximate  geographic  limitations  shown  on  the  map  (fig.  1).     The  central 
part  of  the  dome,  referred  to  in  this  report  as  "Hicks  dome,"  is  an  area  of 
about  1  1/2  square  miles;  most  of  the  prospecting  for  uranium  has  been  con- 
centrated there.    It  is  underlain  by  Devonian  limestone  and  chert  identified 
from  drilling  as  the  Clear  Creek  formation  (Brown  et  al.,   1954).     The  surface 
is  now  covered  by  red  cherty  clay,  a  residue  from  the  weathering  of  the  cherty 
limestone. 

A  circular  belt  about  1/4  to  3/8  mile  wide  around  the  central  part  of  the 
dome  is  underlain  by  black  carbonaceous  New  Albany  shale,  which  shows  some 
radioactivity.    Information  on  the  rocks  at  depth  is  contained  in  the  log  of  the 
Fricker  well  on  the  southeastern  side  of  the  dome  (Weller  et  al.,   1952)  and  in 
the  report  by  Brown  et  al.  (1954)  on  the  Hamp  well,  an  oiltest  on  the  central 
part  of  the  dome. 

Exposures  of  two  mica-peridotite  dikes  and  three  occurrences  of  explo- 
sion breccia  are  evidences  of  igneous  activity  in  the  Hicks  dome  area.    In  ad- 
dition, a  well  (the  Hamp  well)  was  drilled  through  explosion  breccia  from   1725 
feet  to  the  bottom  of  the  well  at  2925  feet.    All  exposures  except  a  dike  on  the 
Joiner  farm  are  shown  on  figure   1.     The  Joiner  farm  dike  is  shown  on  the  geo- 
logic map  in  Illinois  Geological  Survey  Bulletin  76  (Weller  et  al.,   1952)  as  oc- 
curring in  the  SE  1/4  sec.  25,  T.  1 1  S.,  R.  7  E.,  but  it  apparently  no  longer  crops 
out. 

Faults  are  difficult  to  recognize  because  of  the  nature  of  the  materials  ex- 
posed on  Hicks  dome,  but  it  is  believed  that  such  faults  as  may  be  present  are 
small  and  of  limited  extent.    A  chert  breccia  in  slickensided  wall-like  bodies 
s  found  at  scattered  places.     One  such  outcrop  protrudes  several  feet  above 
>e  ground  for  a  distance  of  about  75  feet.    Most  of  the  slickensided  walls  had 
a  general  northeast  strike,  ranging  from  N.  20  E.  to  N.  60  E.     This  is  the  pre- 
vailing trend  of  the  faults  in  Hardin  County. 

The  exact  origin  of  Hicks  dome  is  not  completely  known.     Its  upward  arch- 
ing may  have  been  associated  with  the  structural  movements  that  produced  the 
siting  that  is  common  in  Hardin  County  and  adjacent  parts  of  Kentucky  and  is 
^ly  complex.    An  alternate  hypothesis  is  that  the  dome  reflects  the  localized 
trusxon  of  a  mass  of  igneous  material  at  considerable  depth,  from  which  the 
ndotite  dikes  and  explosion  breccia  are  offshoots.    A  third  hypothesis  (Brown 
H.>  1954)  also  involves  a  molten  mass  at  depth  but  suggests  that  the  doming 
caused  by  gases  evolved  from  the  igneous  rock  or  by  steam  from  ground- 


4  ILLINOIS     STATE     GEOLOGICAL     SURVEY 

water  heated  by  the  intrusion.    Thus  the  explosive  release  of  the  gases  may 
r        !!d thl  breccias  found  on  the  dome.    However,  occurrences  of  explo- 
breccfafn  areas  away  from  the  dome,  for  example,  near  Sparks  Hill  and 
r  mile  wea8;  of  Ro^iclarl,  throw  doubt  on  the  significance  of  such  breccia  in 
the  formation  of  Hicks  dome. 

METHOD   OF  SAMPLE  ANALYSIS 
The  sampled  materials,  described  below,  were  crushed  in  a  jaw  crusher 
to  approximately  1/8  inch.    Radiometric  analyses  of  the  samples  were  made 
wi*  a  laboratory  model  Geiger  counter  which  had  been  calibrated  again,, :  sam 
Ties  of  known  U,08  content  obtained  from  the  Atomic  Energy  Commission. 
P        Dominations  of  U308  were  made  according  to  the  Atomic  Energy  Com- 

I',  booklet    -Manual  of  Analytical  Methods  for  the  Determination  of 
UrTium  ana  Thorium  in  Their  Ore's."    A  Beckman  Model  DU  spectrophotom- 
eter with  10  cm.  Corex  cells  was  used  for  the  color  measurement 

A  standard  curve  of  transmittance  was  prepared  by  analysis  °f  various 
dilutions  of  a  sample  of  phosphate  rock  of  known  U308  content  obta  ned  from 
the  Atomic  Energy  Commission.    Results  of  the  Illinois  Survey  analyses  of 
ftandarT  samples  compared  satisfactorily  with  the  Atomic  Energy  Commis- 
sion's  values  for  the  same  samples. 

OCCURRENCE  AND   NATURE   OF   MATERIALS   SAMPLED 
FROM  HICKS  DOME  AREA 
All  types  of  earth  materials  present  at  the  surface  in  the  Hicks  dome  are 
and  in  tesTpits  and  trenches  up  to  20  feet  deep  were  tested  in  the  field  with  a 
Portable  Ge'iger  counter  and  sampled  for  analysis  in  the  Surve Y  Intone. ^ 
Included  in  the  field  examination  were  red,  yellow,  and  brown  clay    chert,  sar 
stone  (minor  amount),  fault  (?)  breccia,  explosion  breccia    peridotite  dikes 
black  marine  shale  (New  Albany),  massive  limonite,  and  calcite  and ^  luorite^ 
Only  the  clays,  some  of  the  fault  (?)  breccia,  and  some  of  the  New  Albany  shj 
showed  appreciable  radioactivity.    Some  pieces  of  the  explosion  breccia  sho^ 
weak  radioactivity  whereas  others  showed  none.    The  dikes  were  very  weakl, 
radioactive.    The  rest  of  the  material  showed  little  to  no  radioactivity. 


Clays 


Most  of  the  cherts  and  the  clays,  which  are  principally  red  or  yellow,  ap 
pear  to  be  residual  from  the  weathering  of  a  limestone  that  contained  chert 
nodules  and  beds  as  much  as  several  feet  thick.    The  red  clay  present  over 
of  the  dome  has  the  typical  color  and  appearance  of  residual  clay  from  1  me 
X-ray  diffraction  patterns  of  the  minus  2  micron  or  clay-size  fraction  of  tw 
samples  (nos.   18  and  38,  table   1)  established  the  absence ^ofanyc ^racterist 
cally  crystalline  clay  mineral  in  sufficient  abundance  to  be  identified.    Heter 
geneous  weathered  assemblages  of  this  nature  are  often  observed  in  clays  r< 
sidual  from  limestone.*    As  sample   18  was  moderately  radioactive  and  sam 

*Bradley,  W.  F.,  personal  communication. 


URANIUM     IN     HARDIN     COUNTY  5 

pie  38  was  virtually  nonradioactive,  there  is  apparently  no  relationship  be- 
tween clay  mineralogy  and  radioactivity. 

On  the  central  part  of  the  dome,  the  yellow  clay  occurs  as  vertical  "veins" 
and  irregular  masses  in  the  red  clay  and  commonly  carries  much  higher  val- 
ues in  radioactivity  than  the  surrounding  red  clay.     The  yellow  clay  is  different 
in  appearance  and  physical  properties  from  the  red  clay.    It  dries  to  a  rather 
powdery  mass  which  feels  silty;  the  red  clay  typically  dries  to  a  hard  substance 
resembling  brick.    Size  analyses  of  the  red  and  yellow  clays  (table  2)  show  that 
sample  72,  the  yellow  clay,  carries  twice  as  much  silt  (-325  +  2  microns)  as 
the  two  red  clays  and  much  less  clay-size  material  than  sample   18,  a  red  clay. 
The  relative  scarcity  of  clay-size  particles   in  the  other  red  clay,  sample  38, 
is  probably  due  to  the  fact  that  a  large  part  of  that  sample  was  composed  of 
chert  fragments.     Otherwise  sample  38  is  similar  to  sample   18  -  in  color,  tex- 
ture, and  drying  characteristics. 

An  x-ray  diffraction  pattern  of  the  minus  2  micron  fraction  of  the  yellow 
material  showed  the  same  characteristics  as  the  red  clays.     The  yellow  clay 
occurring  in  "veins"  probably  came  from  an  overlying  layer  of  yellow  residual 
clay  which  has  been  completely  eroded.    As  cracks  opened  in  the  underlying  red 
clay,  possibly  from  slumping  into  sink  holes  in  the  limestone,  the  yellow  clay 
was  washed  into  the  fissures.    As  these  fissures  were  also  watercourses,  ra- 
dioactive substances  in  the  groundwater  may  have  become  concentrated  in  the 
yellow  clay  "veins"  by  adsorption  on  the  clay  minerals.     The  data  in  table  2 
suggest  some  sort  of  relationship  between  the  amount  of  the  clay  fraction  and 
radioactivity. 

On  the  eastern  flank  of  the  dome,  in  the  vicinity  of  the  Robinson  dike  (sam- 
ple 130),  a  bulldozer-cut  exposed  a  yellow  residual  clay  overlying  Mississip- 
pian  Osage  chert.    The  yellow  clay  on  the  Robinson  property  was  radioactive 
only  at  the  contact  with  the  underlying  chert  bedrock  (sample   175),  indicating 
a  concentration  by  groundwater  at  the  surface  of  the  bedrock.    Sample   176  was 
taken  from  a  two-foot  wide  radioactive  zone  in  broken  chert  at  the  southeastern 
side  of  the  dike  as  exposed  in  the  trench.     The  dike  itself  had  been  weathered 
in  place  to  a  soft  material  that  was  easily  cut  by  the  bulldozer.     The  material 
of  sample   176  showed  as  strong  a  reading  on  the  portable  Geiger  counter  in  the 
wall  of  the  trench  as  did  that  of  sample   175,  but  when  tested  five  days  later  by 
a  laboratory  counter  it  was  only  weakly  radioactive  (see  table  3).    As  the  ma- 
terial had  been  sampled  as  soon  as  it  was  exposed  by  the  bulldozer,  the  radio- 
activity may  have  been  caused  by  radon  gas. 

Another  type  of  yellow  clayey  material  is  exposed  for  about  1000  feet  along 
a  stream  and  its  tributaries  on  the  northwestern  flank  of  the  dome  in  the  NW 
74  sec.  25  and  the  NE  1/4  sec.  26  (samples   131  to  133  and  168).    It  is  moder- 
tely  radioactive  in  spots  and  is  composed  mainly  of  fragments  of  weathered 
chert,  although  an  occasional  fragment  of  sandstone  or  shale  can  be  found.     The 
material  is  soft  except  for  the  few  sandstone  fragments,  and  the  chert  offers  no 
more  resistance  to  a  knife  blade  than  does  the  interstitial  clayey  material. 
Some  stratification  can  be  found  and  is  contorted  in  places.    Apparently  the  ma- 
terial is  a  strongly  weathered  chert  gravel.    No  differences  in  included  mate- 
rials, texture,  or  structure  could  be  found  between  the  radioactive  and  nonra- 
noactive  portions. 


6  ILLINOIS     STATE     GEOLOGICAL     SURVEY 

Chert  and  Sandstone 
The  chert  exposed  in  trenches  and  as  an  occasional  outcrop  does  not  ap- 
pear to  be  significantly  radioactive  (table  1)  with  the  exception  of  sample  72D. 
This  sample  is  from  a  one -foot  bed  of  soft  weathered  white  chert  with  brown 
laminations  exposed  in  the  wall  of  a  trench.    The  only  sandstone  foundwasa 
few  blocks  in  a  sinkhole  exposed  in  a  trench  and  one  small  piece  on  a  hallsade 
(sample  88,  table   1).    None  of  it  was  radioactive. 

Fault  (  ? )  Breccia 

The  material  called  fault  (?)  breccia  is  composed  of  chert  or  other  silic- 
ified  rock  fragments  cemented  by  fine-grained  to  macrocrystalline  quartz     Th 
breccia  generally  occurs  as  slickensided  wall-like  bodies  which  may  protrude 
above  the  ground  (sample  localities   10  (11)  and  25)  or  be  completely  covered 
bv  residual  clay  (locality  of  samples  1  through  6  and  77). 

The  breccia  fragments  appear  to  have  come  from  the  immediately  sur- 
rounding  rocks,  which  seem  to  have  been  only  fractured  with  none  of  the  grand 
ang  expectable  from  a  large  amount  of  movement  along  a  fault.    No  stratagrapl 
evidence  of  faulting  was  found  because  of  the  scarcity  of  outcrops.    However, 
we  saw  no  difference  in  the  soil  or  residuum  surrounding  the  breccia  outer  opt 
from  one  side  of  the  outcrop  to  the  other,  so  that  movement  on  the  faults  was 
not  sufficient  to  have  brought  different  kinds  of  rock  into  contact 

An  alternative  theory  of  formation  of  the  breccia  is  one  invoking  explosiv 
gases.    The  fault  (?)  breccia  would  merely  represent  a  lesser  degree  of  dis-. 
turbance  than  that  shown  by  the  explosion  breccia.    The  slickensides,  which 
transect  the  cement  as  well  as  the  rock  fragments,  could  have  been  caused  b> 
minor  adjustments  along  the  plane  of  the  disturbance  after  the  explosive  ac- 

tivity  had  ceased.  , 

Appreciable  radioactivity  in  the  fault  (?)  breccia  was  detected  only  at  th 
locality  of  samples   1  through  6,  a  ridge  exposed  in  a  test  pit.    One  sample  <n< 
12)  from  boulders  on  the  opposite  side  of  the  same  hill  also  showed  moderate 
radioactivity,  but  all  samples  from  other  localities  showed  only  weak  or  no  r| 
dioactivity     The  great  variation  in  amount  of  radioactivity  between  samples 
from  the  same  locality  indicates  that  the  distribution  of  the  radaoactaye  mate 
rial  in  the  breccia  is  "spotty."    It  suggests  that  the  lack  of  appreciable  radio 
activity  shown  by  samples  from  the  other  localities  may  be  due  to  the  chance 
missing  of  radioactive  segregations  during  sampling.    Such  is  not  believed  tc 
be  the  case  because  all  breccia  outcrops  were  checked  with  the  portable  Gel  f 
counter  and  only  localities  of  samples   1  through  6  and  12  had  shown  a  count  ( 
more  than  twice  background. 

A  microscopic  examination  of  the  breccia  failed  to  reveal  the  presence* 
uranium  minerals,  but  an  ever-present  iron-oxide  stain  could  hide  any  powd. 
coatings  of  normally  brightly  colored  secondary  uranium  minerals.    As  tt 
chert  itself  is  not  radioactive,  the  radioactivity  must  be  related  to  the  fine- 
grained quartz  cement.     The  cementing  material  is  generally  vesicular  and 
here  and  there  is  present  only  as  a  drusy  coating  around  the  chert  frag™en  ' 
Generally  there  is  not  sharp  boundary  between  the  cementing  quartz  and  the 
chert,  indicating  some  replacement  of  the  chert  by  the  quartz.     Whether 


URANIUM     IN    HARDIN     COUNTY  7 

quartz  of  the  cement  was  deposited  from  hydrothermal  solutions  related  to  the 
igneous  activity  or  from  circulating  groundwater  cannot  be  determined  at  pre- 
sent, but  the  great  quantity  of  silica  available  in  the  Devonian  chert  certainly 
makes  a  hydrothermal  source  unnecessary.    That  groundwater  is  an  adequate 
carrier  of  silica  is  attested  by  the  quartz  veinlets  and  druses  associated  with 
many  Siliceous  sediments  as  well  as  the  well-crystallized  quartz  found  in  many 
geodes.  7 

Explosion  Breccia 

The  terms  explosion  breccia  and  intrusive  breccia  have  been  used  in  Har- 
din County  to  designate  a  rock  composed  of  pieces  of  sedimentary  and  igneous 
rocks  in  a  fine-grained  altered  matrix  which  includes  fragments  of  the  minerals 
feldspar,  mica,  pyroxene,  and  apatite  (Weller  et  al„  1952).    Brown  et  al    (1954) 
concluded  that  the  breccia  in  the  Hamp  well  also  was  an  explosion  breccia,  al- 
hough  it  contained  no  recognizable  igneous  material.     The  breccia  at  sample 
localities  37,  50  (125),  and  128  was  called  explosion  breccia  in  the  field  because 
of  its  similarity  in  appearance  to  described  occurrences  of  that  breccia  else- 
where in  Hardin  County. 

Sample  locality  50  (125)  is  a  small  steep-sided  rounded  hill  several  hun- 
dred feet  in  diameter  liberally  sprinkled  with  boulders  of  a  material  composed 
of  angular  fragments  of  chert  in  a  fine-grained  matrix.    In  places  the  matrix 
appears  to  be  composed  largely  of  iron  oxide,  but  generally  the  cementing  ma- 
terial is  fine-grained  to  microcrystalline  quartz.    The  included  fragments  vary 
>n  size  from  about  6  inches  down  to  the  granular  material  of  the  matrix 
1     ,w,?vneral  comP°sition  the  breccia  of  locality  50  (125)  is  similar  to  the 
■ault  (?)  breccia  described  earlier  but  differs  in  degree  of  brecciation  and  in 
irea  and  shape  of  outcrop.    The  fault  (?)  breccia  appears  to  be  composed  of 
ragments  about  1/2  inch  or  larger  whereas  the  material  of  locality  50  (125) 
:ontains  areas  in  which  the  fragments  measure  no  more  than  a  millimeter  or 
o.    The  differences  in  area  and  shape  of  outcrop  of  the  two  occurrences  are 
real  and  appear  to  suggest  different  modes  of  origin.    If  the  hill  of  locality  50 
125)  is  underlain  entirely  by  the  breccia,  as  would  appear  to  be  the  case  from 
he  absence  of  other  kinds  of  rock  either  as  float  blocks  or  outcrops,  the  brec- 
cia has  an  outcrop  area  roughly  circular  in  plan  and  several  hundred  feet  in 
uameter.    Such  an  outcrop  area  would  be  expected  from  a  pipe -like  body.    By 
ontrast    the  more  typical  fault  (?)  breccia  occurs  in  narrow  wall -like  bodies 
bout  2  to  3  feet  wide  and  up  to  75  feet  long,  suggestive  of  fault  outcrops. 

The  other  two  occurrences  designated  as  explosion  breccia  in  figure   1  are 
rtermediate  in  amount  of  brecciation  between  the  fault  (?)  breccia  and  the 
reccia  plpe.    T^y  are  both  chert  breccias  cemented  by  sU.ca  and  .ron  ^.^ 

.eeZTVVi  "t'  i28  1S  Sma"'  ^  n°-  "  iS  reP"^d  °nly  as  boulders,  so 
nof  T?fi      t^°dXeS  iS  n0t  known-     The  existence  of  breccia  of  the  character 
Lt  ,1',  it    !  '  ln  a  S6nSe  transiti°nal  between  the  two  extremes,  suggests 

at  all  the  breccia  of  the  Hicks  dome  area  might  have  originated  from  the  same 
rce  -  explosive  release  of  gases. 

The  radioactivity  of  the  explosion  breccia  was  found  to  be  low,  both  in  out- 
,  op  measurements  and  in  representative  samples  tested  in  the  laboratory. 
|>wever,  analyses  of  eight  25-foot  samples  of  cuttings  from  the  breccia  portion 


,  ILLINOIS     STATE     GEOLOGICAL     SURVEY 

„  ,T>  *  „i      iqc;4t  showed  four  to  be  moderately  radioactiv 

^TZr^JTZZl^V™  0.0!%  eU  to  0.03%  eU.    The  low  leve 

^^rrco^ai::  Iferg'ato8:  of  radioactive  material.  The  generally  low 
"luefof  LT  c^mlcJUyses  for  uranium  of  the  Hamp  samples  show  that 
the  radioactive  material  is  something  other  than  uranium. 

Peridotite  Dikes 
Two  occurrences  of  mica  ^f^^^Z^^O^^ 
Se^ictl  Su°;:eery  BulTetm^  (Wel^r  ~-l..  1952).    Samples  collected  by  Gro 
gan  w   re    ound  Jbe  hut  slightly  radioactive  (sample   147).    On  the  Robinson 
farm  on  the  east  side  of  the  dome  a  weathered  dike  is  exposed  in  a  test  pit 
simple  130)  and  in  the  bulldozer  trench  from  which  clay  samples  175  and  17 
lerTtaken      The  dike  strikes  N.  57°  E..  in  contrast  to  the  northwestward  strt 
If  a  1  other  known  dikes  in  Hardin  County.    The  only  recognizable  mineral  re- 
manning  in  this  thoroughly  weathered  dike  is  mica,  in  books  and  plates  up  to 
T/2  inch  wide.    The  weathered  material  was  even  less  radioactive  than  the 
Joiner  dike. 

New  Albany  Shale 
The  New  Albany  shale,  which  encircles  the  central  part  of  Hicks  dome  ^ 
a  band  1/2  to  3/8  mile  wide,  is  a  black  carbonaceous  marine  shale.    Samples 
70a  tough  70e  represent  successive  5-foot  vertical £«££, -f -«  «»  out- 
crop  in  the  creek  just  off  the  bend  in  the  road  in  the  NW   1/4  SE  1/ 1  ••«•«• 
A  shear  zone  one  foot  wide,  containing  traces  of  fluonte,  showed  abnormal ,, 
dioactivity  in  the  field,  but  in  the  laboratory  a  sample  from  this  zone  tested 
no  higher  than  the  other  shale  samples. 

Miscellaneous  Materials 
Boulders  of  massive  limonite  up  to  one  foot  in  diameter  (sample  45)  and 
calcite  and  fluorite  (sample  92)  were  only  weakly  radioactive. 

MATERIAL  SAMPLED   IN   OTHER  HARDIN  COUNTY    LOCATIONS 
In  an  attempt  to  find  whether  or  not  there  is  any  definite  association  **• 
dioactive  anomalies  with  specific  types  of  geologic  phenomena,  such  as  faul 
ing  or  igneous  activity,  materials  were  sampled  at  various  localities  througl 
out  the  Fluorspar -producing  district  of  Hardin  and  Pope  counties.    The  samp 
included  clays  and  shales  from  fault  zones,  residual  clays  from  -disturb ed 
limestone  and  sandstone,  peridotite  dikes  and  explosion  breccias  and ^clay. 
overling  them,  ores  of  fluorspar,  lead,  and  zinc,  and  concentrates  from 
ores.    Results  of  tests  on  these  samples  are  shown  in  table  3. 

In  general,  of  the  types  of  clays  sampled,  only  *ose  from  fault  zone.  • 
ed  more  than  very  slight  radioactivity.    Clay  sample  66  from  the  Rosiclare 


URANIUM     IN    HARDIN     COUNTY  9 

system,  clay  sample  55  and  shale  sample  54  from  t h~  td  ♦ 

its  outcrop  along  Route   146,  a„d  Mack  shale   slZ  f    S, ^  T?' 
fluorspar  prospect  shaft  on  the  Wolrab  Mill  fault  near  S™S  \- n    P  *  a 

nearly  twice  background  on  the  laboratorv  d  P  *""  registe"d 

sample  65  from  the  Rosiclare  vein  syttZ  S?!,*  C°Unt6r-    ?°WeVer'  Clay 
side  near  the  junction  of  the  Wa^'lST^w/rtS     h  "?  **  ^ 
radioactivity.  otewart  taults  showed  very  slight 

One  occurrence  of  radioactive  residual  clav  is  «„  => 
burg  sandstone  on  the  Karbers  Ridge  road      ThJ    V  "*  '"  *e  Hardins 

in  a  zone  6  to  12  inches  thick  in  thT    u  radioactivity  was  concentrated 

bedrock.    Apparently  this  was  a  con  ^  °yeS'duaI  ^  *'  fte  t0?  °f  the  sh^ 
that  the  source  of  the  ra dioTtiv mat'         ,         ¥  gr°Undwater-    "  «  Possible 
beds  that  occur  at  intervals  in  &eT         r^  **'  ^^^  ™S  the  black  sl>ale 
known  in  the  ^  "^nit ^^t^^"™ .1    N°  ^  *" 

A  bulldozer-cut  in  the  M11«mT       1,1  W6re  V1Sible  in  the  outcrop. 

from  a  stream  cut  on  the  strike  of  th,  AT'  P  red  °lay'  no-  110> 

of  the  outcrop  was  only  ^tl^J^l^^  "8  **  15°  *«  •«— • 

.ng  themZweTL^rto1::  r^ft^^8  ^  ""  -  *«  cla^  overly- 
table  3,  the  outcrrp  tocaHties  of  Z ?  Y'  ■  addm°n  t0  *'  SampleS  Sh°™  * 
-  Oeiger  counter'  ^^A^^^n.*:^^  *?«"*«  ^ 

"tL-rrr burrows  and  by  -^  ^ » --  rdneyP:hdditionai 

Hot,  the  CavT;„  R0 lU°dL^Parct°reSdar  C°"ateS  '««  the  Rosiclare  dis- 

-  tested  but  sho::rv;ra^r  ^io\uSyEmpire  district  in  p-  c°^ 

SUMMARY    OF   RESULTS   OF  ANALYSES 

-al  JetlmiL^ns  T^^f^  S^  ^^  ^  *""  "*  «*"" 

*al  radioactivity  of  the  sarnies  e™  "ramum  equivalent  data  indicate  the 

hus  they  indicate  th     anZn of  uT  "  '"^  °f  U3°8  (UraniUm  °*ide>- 

stances  present.     The  cheLi   a"  det        '■  T^  PlUS  ^  ^  radi°active 
dde.  e  chemical  determinations  of  U308  show  only  uranium 

\^Z£z^ix>5£r?? types  of  materiais  tested  a- 

Ua  underlain  by  Devoman  '    '  J       T»"  fr°m  exPosures  *«hi.  the 

<  u)  those  outsrd°  hTs  a;er  TLrifr  tAlbany  shaie  on  Hicks  dome  <««•  o. 

*  Albany  area  often  is  referred    *  ^T      *  1S  made  because  the  Devonian- 
'>  dome."  referred  to  popularly  as  the  "dome"  or  as  being  "on 


10  fLLINOIS     STATE     GEOLOGICAL     SURVEY 

The  most  radioactive  materials  are  generally  red  and  yellow  clays      It 
^t  the  clays  and  breccias  within  the  Devonian  area  are  somewhat 
appears  that  the  clays  and  d  elsewhere  in  the  county,  though 

more  radioactive  *an  "mUar  ma teria J-  ^  and  lead  ores>  and 

there  are  °°™^™J*™1  "  £f™  J  radioactivity.    The  U308  con- 

rT:fa?isam;rststed0for  both  uranium  equivalent  and  U308  was  consid- 
tent  of  all  samples  te  ,  d  algo  was  below  the  minimum 

erably  below  the  -^^^23^  Atomic  Energy  Commission, 
of  0.1  percent  on  which  prices  are  quoteu     y 

SOURCE   OF  RADIOACTIVE   MATERIAL 

The  source  of  the  radioactive  material  is  an  unsolved  problem  at  the  pre - 
The  source  °  possible  sources  exist  -  sedimentary  and  hy- 

Tth  rTal      The  NewTlbany  sha'le,  which  encircles  and  at  one  time  covered 
£S^p5%V  -e    offers  a  ^^-^1. 
™?^^;^^7^^  of  samples^  thro. 

rderate  ffisrss  -  jsr^s^^  - -^  -- i 

?r»  c".*  a"   Rol^clare  fault  systems  may  well  be  due  to  Hydrothermal 

directly  related  to  fluorspar  mineralization. 

The  oresent  radioactive  concentrations  give  little  hint  as  to  the  orig 
the  rad  oa     ^materials.    As  virtually  all  the  ^o^^^J^ 
work    the  only  radioactive  materials  exposed  are  clays  and  weathered  chert 
recci-  Ve  radioactivity  in  the  clays  is  almost  certainly  due ,  toc«c« Ra- 
tion by  groundwater,  judging  from  the  concentrations  in  fissures  and  at ^ .u 
face  of  the  bedrock.    The  one  occurrence  of  radioactive  fault  (?)  breccia    re 
larded  by  some  observers  as  the  weathered  outcrop  of  a  hydrothermal  vein 
couMhav'e  acquired  its  radioactivity  from  E"^"*^^^^ 
vesicular  quartz  cement  or  even  from  groundwater  that  may  have  deposited 

"""The  best  evidence  for  a  hydrothermal  origin  is  in  the  distribution  of :  th. 
mor f  radioactive  samples.    Those  inside  the  ring  of  ^^     ^Zs^Z 
their  radioactivity  from  the  weathering  of  the  shale    but  the  three       tSide  (a 
above)  the  shale  more  reasonably  would  be  assumed  to  have  ^T^"^ 
A8  there  is  no  black  carbonaceous  shale  within  1000  feet  «*£*^^  ^   . 
the  lower  Mississippian  formations  at  the  three  localities,  the  weathering 
drothermal  veins  is  a  likely  source  of  the  radioactivity 

Only  prospecting  at  deeper  levels  will  determine  whether  there  is  any 
ward  exLLJof  suspected  veins,  or  whether  the  radioactive  ~c«.«*^ 
merely  concentrations  by  groundwater  from  the  weathering  of  weakly 


tive  rocks. 


URANIUM     IN     HARDIN     COUNTY 


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ILLINOIS     STATE     GEOLOGICAL     SURVEY 


Table  4.  -  Summary  of  Data  for  Samples  within  the 
Devonian-New  Albany  Area 


Uranium  equivalent 

u3o8 

Material 

No. 
samples 

Range 

Av. 

No. 
samples 

Range 

Av. 

Red  clay 

37 

.000-. 144 

.011 

8 

.002-. 014 

.006 

Yellow  clay 

5 

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5 

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.010 

Red  and  yellow 

clay 

2 

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2 

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Gray  clay 

1 

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1 

.002 

Black  shale 

6 

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.015 

3 

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Chert 

4 

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.018 

1 

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Chert  breccia 

14 

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.010 

4 

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Explosion  breccia 

3 

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.005 

Peridotite  dike 

1 

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Limonite 

1 

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URANIUM     IN     HARDIN     COUNTY 

Table  5.  -  Summary  of  Analyses  of  Samples  outside  the 
Devonian-New  Albany  Area 


21 


Material 

Red  clay* 

Yellow  clay 

Red  and  yellow  clay 

Black  shale 

jreen  shale 

3hert 

"hert  breccia 

Explosion  breccia 

>eridotite  dike 

luorspar  ore 

inc  ore 

luorspar  concentrate 

inc  concentrate 

2 ad  concentrate 


Uranium  equivalent 
No.  Range  Av. 

samples 

.000-. 019      .003 
.000-. 072      .019 
.000-. 050      .010 
.008 
.002-. 008      .005 
.000-. 002      .001 
.000-. 008      .004 
.000-. 007      .002 
.000-. 021      .006 
.000 
.000-. 005      .002 
.000 
.000 
.000 


43 

10 
7 
1 

3 

3 

8 
10 

8 

1 

3 
3 
2 
2 


No. 
samples 


U3°8 


Range  Av. 


.013 


fitting  sample  162,  which  was  so  high  as  to  distort  other  data. 


REFERENCES 

Brown,  J.  S.,  Emery,  J.  A.,  and  Meyer,  P.  A.,   1954,  Explo- 
sion pipe  in  test  well  on  Hicks  dome,  Hardin  County, 
Illinois:     Econ.  Geol.,  v.  49,  p.  891-902. 

Weller,  J.  M.,  Grogan,  R.  M.,  and  Tippie,  F.  E.,   1952,  Ge- 
ology of  the  fluorspar  deposits  of  Illinois:    Illinois  Geol. 
Survey  Bull.  76. 


ILLINOIS 


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CIRCULAR    200 


ILLINOIS   STATE  GEOLOGICAL  SURVEY 


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