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UNITED  STATES  TARIFF  COMMISSION 


DYES  AND  OTHER  SYNTHETIC 

ORGANIC  CHEMICALS  IN 

THE  UNITED  STATES 

1937 


REPORT  No.  132 

SECOND  SERIES 


\\ 


BOSTON  PUBLIC  LIBRARY 


3  9999  06317  191  0 


UNITED  STATES  TARIFF  COMMISSION 


DYES  AND  OTHER  SYNTHETIC 

ORGANIC  CHEMICALS  IN 

THE  UNITED  STATES 


1937 


REPORT  No.  132 

SECOND  SERIES 


HI 


UNITED  STATES 

GOVERNMENT  PRINTING  OFFICE 

WASHINGTON  :  1938 


For  sale  by  the  Superintendent  of  Documents,  Washington,  D.  C.    --     ........     Price  10  cenlt 


UNITED  STATES  TARIFF  COMMISSION 


RAYMOND  B.  STEVENS,  Chairman 
HENRY  F.  GRADY,  Vice  Chairman 
EDGAR  B.  BROSSARD 
OSCAR  B.  RYDER 
E.  DANA  DURAND 
A.  MANUEL  FOX 

SIDNEY  MORGAN,  Secretary 


Address  All  Communications 

UNITED  STATES  TARIFF  COMMISSION 

WASHINGTON,  D.  C. 


CONTENTS 

TEXT 

Page 

Acknowledgment v 

Introduction 1 


Part  I 


Summary  of  United  States  production  and  sales  of  dyes  and  other  synthetic 
organic  chemicals,  1937: 

Coal-tar  crudes 3 

Coal-tar  intermediates 3 

Coal-tar  dyes 4 

Color  lakes  and  toners 4 

Medicinals 4 

Flavors  and  perfume  materials 4 

Resins 4 

Chemicals  for  rubber 5 

Miscellaneous  chemicals 5 

Summary  of  production  and  sales  of  coal-tar  products 5 

Summary  of  production  and  sales  of  synthetic  organic  chemicals  not  of 

coal-tar  origin 6 

Part  II 

Production  and  sales  of  synthetic  organic  chemicals  in  the  United  States, 
1937: 

Coal-tar  crudes 9 

Coal-tar  intermediates 10 

Coal-tar  dyes: 

Production  and  sales  by  types 20 

Production  and  sales  by  classes  of  application 33 

Color  lakes  and  toners 34 

Medicinals 36 

Flavors  and  perfume  materials 41 

Resins 44 

Rubber  chemicals 45 

Miscellaneous  chemicals 48 

APPENDIX 

Directory  of  manufacturers  of  dves  and  other  synthetic  organic  chemicals, 

1937 1 54 

STATISTICAL  TABLES 

1.  Comparison  of  United  States  production  of  tar  and  production  and 

sales  of  certain  crudes,  1925-30,  1936,  and  1937 „_  3 

2.  Intermediates,  dyes,  and  other  coal-tar  chemicals:   Summary  of  United 

States  production  and  sales,  1937 5 

3.  Intermediates,  dyes,  and  certain  other  classes  of  coal-tar  chemicals: 

Comparison  of  United  States  production  and  sales,  1925-30,  1936, 

and  1937 -—  6 

4.  Synthetic  organic  chemicals  of  non-coal-tar  origin:  Summary  of  United 

States  production  and  sales,  1937 6 

5.  Synthetic  organic  chemicals  of  non-coal-tar  origin:     Comparison  of 

United  States  production  and  sales,  1925-30,  1936,  and  1937 7 

6.  Coal-tar  crudes:   United  States  production  and  sales,  1937 10 

7.  Coal-tar  intermediates:   United  States  production  and  sales,  1937 11 

8.  Coal-tar  dyes:  United  States  production  and  sales,  by  types,   1937_._  20 

m 


IV  CONTENTS 

Page; 
9    Comparison  of  United  States  production  and  sales  of  dyes  by  classes  of 

application,  1925-30,  1936,  and  1937 33 

10.  Color  lakes  and  toners:  United  States  production  and  sales,  1937 34 

11.  Synthetic  medicinals:   United  States  production  and  sales,  1937: 

(A)  Coal-tar 37; 

(B)  Non-coal-tar 39 ; 

12.  Synthetic  flavors  and  perfume  materials:  United  States  production  and 

sales,  1937: 

(A)  Coal-tar 41 

(B)  Xon-coal-tar 43 

13.  Synthetic  resins:   United  States  production  and  sales,  1937: 

(A)  Coal-tar 44 

(B)  Non-coal-tar 45 

14.  Synthetic  rubber  chemicals:   United  States  production  and  sales,  1937: 

(A)  Coal-tar 46 

(B)  Non-coal-tar 47 

15.  Miscellaneous   synthetic    chemicals:     United    States   production    and 

sales,  1937: 

(A)  Coal-tar ■ 48 

(B)  Non-coal-tar 49 


ACKNOWLEDGMENT 

In  the  preparation  of  this  report,  the  Commission  had  the  services 
of  P.  K.  Lawrence  and  Bertha  M.  Robertson,  of  the  Chemical  Division, 
and  of  others. 


DYES   AND   OTHER    SYNTHETIC   ORGANIC 
CHEMICALS 


INTRODUCTION 

The  data  on  the  domestic  production  and  sales  of  dyes  and  other 
synthetic  organic  chemicals  for  1937  contained  in  this  annual  report 
were  collected  and  compiled  by  the  United  States  Tariff  Commission. 
The  Commission  considers  that  the  value  of  such  information  to  gov- 
ernmental agencies  and  to  the  public  warrants  its  collection  and  publi- 
cation. 

This  report  has  been  abridged  in  order  to  expedite  publication  and  to 
effect  economies  in  printing.  Detailed  tabulation  of  imports  of  dyes 
and  other  coal-tar  products  into  the  United  States  has  been  omitted 
to  avoid  duplication  of  the  semiannual  list  of  imports,  published 
jointly  by  the  Department  of  Commerce  and  the  Tariff  Commission. 
Statistics  of  imports  and  exports  as  published  in  Foreign  Commerce 
and  Navigation  of  the  United  States  have  also  been  omitted. 

The  grouping  of  coal-tar  crudes,  intermediates,  dyes,  and  color  lakes 
and  toners  follows  that  of  the  Tariff  Act  of  1930  and  conforms  in  gen- 
eral, although  not  in  every  detail,  to  common  practice.  Azoic  dyes, 
formerly  listed  under  the  heading  "Unclassified  dyes,"  and  their  com- 
ponents, formerly  included  under  "Miscellaneous  coal-tar  products," 
have  been  combined  under  "Azoic  dyes  and  their  components"  as  a 
subgroup  of  "Unclassified  dyes."  The  practice  of  grouping  other  syn- 
thetics, both  coal-tar  and  non-coal-tar,  by  principal  application,  as  was 
done  in  the  1936  report,  is  continued  herein.  This  procedure  applies 
to  medicinals,  flavors  and  perfume  materials,  resins,  rubber  chemicals, 
and  miscellaneous  products. 

The  statistics  for  1937  were  compiled  from  returns  of  308  companies 
and  are  thought  to  form  a  complete  record  of  the  manufacture  of  such 
products  in  the  United  States.  Data  for  separate  items  are  given  in  as 
great  detail  as  is  possible  without  disclosing  the  operations  of  individ- 
ual manufacturers.  The  policy  of  the  Commission  is  to  omit  produc- 
tion and  sales  figures  for  a  product  or  group  of  products  unless  at  least 
three  firms  report  a  substantial  output.  If  the  total  is  not  well  dis- 
tributed among  three  or  more  manufacturers,  production  or  sales  fig- 
ures are  not  published.  Every  effort  is  made  to  avoid  duplication  of 
figures  and  it  is  believed  that  there  is  no  duplication  of  production  or 
sales  statistics  either  for  individu.il  oroducts  or  groups  of  products. 


Part  1 


SUMMARY  OF  UNITED  STATES  PRODUCTION  AND  SALES 
OF  DYES  AND  OTHER  SYNTHETIC  ORGANIC  CHEMICALS, 

1937 


COAL-TAR  CRUDES 

The  output  of  coal  tar  in  the  United  States  in  1937,  as  reported 
to  the  Bureau  of  Mines,  was  603,053,000  gallons  as  compared  with 
560,386,000  gallons  in  1936.  Sales  totaled  386,648,000  gallons  at  an 
average  of  4.8  cents  per  gallon.  About  50  percent  of  the  1937  pro- 
duction was  distilled  for  the  recovery  of  the  several  constituents  and 
in  addition  substantial  quantities  were  topped  to  recover  naphthalene 
and  the  tar  acids.  Some  crude  tar  was  burned  as  fuel  at  or  near  the 
point  of  production. 

Table  1  compares  the  production  and  sales  of  coal  tar,  benzol, 
motor  benzol,  naphthalene,  and  creosote  oil  in  1937  with  1936  and 
with  the  average  for  1925-30. 

Table  1. — Comparison  of  United  Stales  production  of  tar  and  production  and  sales 
of  certain  crudes,  1925-30,  1936,  and  1937 


Product 


192.5-30 
average 


1936 


1937 


Percent 

increase 

1937  over 

1936 


Tar  produced thousands  of  gallons.. 

Benzol: 

Production do 

Sales -do 

Sales  value ..thousands  of  dollars.. 

Motor  benzol: 

Production ...thousands  of  gallons.. 

Sales. do 

Sales  value thousands  of  dollars.. 

Naphthalene: 

Production thousands  of  pounds.. 

Sales do 

Sales  value. .thousands  of  dollars.. 

Creosote  oil: 

Production thousands  of  gallons.. 

Sales do 

Sales  value ..thousands  of  dollars. . 


630,  536 

22,  257 

22,  257 

4,651 

96, 879 
96, 879 
15,920 

44,  762 

44,  762 

581 

95,  443 

95,  443 
11,742 


560, 386 

19,413 
19,145 
2,676 

85,  673 

84,  762 

7,629 

89,  536 

74, 054 

1,466 

101,  758 
93.  216 
10,  294 


603. 053 

i  26,  795 

22, 141 

2,928 

95,  627 

93,  767 

8,385 

115,979 

109,  394 

2,535 

107,  294 

107,  485 

12, 472 


7.9 

38.0 
15.6 
9.4 

11.5 
10.6 


29.6 
47.7 
72.9 

5.4 
15.3 
21.2 


i  Includes  5,135  thousand  gallons  reported  to  the  U.  S.  Tariff  Commission.    This  amount  accounts  for 
26.4  percent  of  the  increase. 

COAL-TAR  INTERMEDIATES 

Peak  production  of  intermediates,  both  in  quantity  and  variety, 
was  reported  for  1937.  The  output  totaled  575,893,000  pounds,  or 
about  13  percent  more  than  for  1936.     Most  of  the  intermediates 

86997—38 2  3 


4  UNITED    STATES    TARIFF    COMMISSION 

were  produced  in  greater  quantities  although  those  used  in  synthetic 
resins  show  the  largest  gains.  As  compared  with  1936,  phenol 
production  increased  35  percent,  phthalic  anhydride  45  percent,  andi 
outstanding  increases  are  shown  for  the  substituted  phenols,  meta- 
cresol,  cresylic  acid,  chlorinated  diphenyls,  maleic  anhydride,  and 
the  xylenols. 

COAL-TAR  DYES 

Coal-tar  dyes  were  produced  in  slightly  greater  quantity  in  1937.! 
Sales  of  classified  dyes  decreased  about  1.5  percent  in  quantity  and 
2.2  percent  in  value,  while  the  unclassified  dyes  show  a  14  percent; 
increase  in  sales  quantity  and  an  11  percent  increase  in  sales  value  i 
over  the  preceding  year. 

The  components  for  azoic  dyes,  formerly  included  in  "Miscella- 
neous coal-tar  products"  are  included  in  the  azoic  dyes  under  the; 
heading  "Unclassified  dyes."  This  transfer  accounts  for  a  large 
part  of  the  increase  in  1937. 

COLOR  LAKES  AND  TONERS 

The  output  of  color  lakes  and  toners  in  1937  was  18,041,000  pounds 
or  17.5  percent  more  than  in  1936.  Sales  totaled  15,263,000  pounds 
valued  at  $11,812,000,  or  12  percent  by  quantity  and  16  percent  by 
value  over  the  previous  year.  More  detail  as  to  types  is  shown  in 
this  report,  and  phosphomolybdic  acid  lakes  and  toners  are  shown 
separately  for  the  first  time. 

MEDICINALS 

This  important  group  of  synthetics  continues  to  increase  in  quantity 
and  variety.  Production  of  medicinals  of  coal-tar  origin  in  1937 
totaled  14,800,000  pounds  and  those  of  non-coal-tar  origin  1,814,000 
pounds.  Sales  of  coal-tar  medicinals  were  11,989,000  pounds  valued 
at  $11,496,000  and  those  not  of  coal-tar  origin  amounted  to  1,442,000 
pounds  valued  at  $2,408,000.  Sales  of  aspirin  increased  25  percent 
in  quantity  over  the  preceding  year.  Outstanding  increases  are  noted 
for  sulfanilamide  and  mandelic  acid,  both  of  which  were  minor  items 
in  1936. 

FLAVORS  AND  PERFUME  MATERIALS 

In  1937  the  output  of  coal-tar  flavors  and  perfume  materials  in- 
creased 25  percent  and  those  not  of  coal-tar  origin  increased  more 
than  50  percent  over  the  preceding  year.  Sales  of  those  of  coal-tar 
origin  totaled  3,907,000  pounds  valued  at  $3,983,000,  or  14  percent 
more  by  quantity  and  24  percent  more  by  value  than  in  1936.  Sales 
of  non-coal-tar  flavors  and  perfume  materials  increased  35  percent 
by  quantity  and  19  percent  by  value  over  1936. 

RESINS 

Increased  production  and  sales  of  synthetic  resins  are  again  re- 
ported and  several  new  types  have  appeared  on  the  market.  Resins 
from  coal  tar  increased  21  percent  in  production  to  an  all-time  peak 
of  142,025,000  pounds  (net  resin),  and  those  not  derived  from  coal 
tar  increased  in  output  to  21,006,000  pounds  or  35  percent  over  1936. 

The  only  group  showing  decreased  activity  in  1937  was  the  cast 


DYES   AND    OTHER   SYNTHETIC    ORGANIC    CHEMICALS  O 

phenolic  resins,  the  output  of  which  declined  about  11  percent  as 
compared  with  the  preceding  year. 

CHEMICALS  FOR  RUBBER 

These  important  synthetics,  as  a  group,  were  produced  in  somewhat 
smaller  quantities  in  1937  than  in  1936.  Except  for  coal-tar  anti- 
oxidants, the  output  of  which  increased  about  5  percent  over  1936, 
all  groups  report  less  activity  during  the  past  year. 

MISCELLANEOUS  CHEMICALS 

Miscellaneous  synthetic  chemicals  consist  of  products  not  properly 
classified  under  any  of  the  foregoing  groups.  Like  other  groups,  they 
are  divided  into  those  of  (a)  coal-tar  origin,  and  (b)  non-coal-tar 
origin.  Those  of  coal- tar  origin  include  individual  products  and 
groups  of  products,  which  if  imported  would  be  classified  as  inter- 
mediates under  paragraph  27  of  the  Tariff  Act  of  1930,  and  others 
which  would  be  classified  as  photographic  chemicals,  synthetic  tanning 
materials,  and  others  under  paragraph  28.  Those  of  non-coal-tar 
origin  include  many  important  but  unrelated  products  widely  used  in 
industry  and  the  arts. 

SUMMARY  OF  PRODUCTION  AND  SALES  OF  COAL-TAR  PRODUCTS 

Table  2  summarizes  the  production  and  sales  of  coal-tar  products 
in  1937,  and  table  3  compares  the  production  and  sales  in  1937  with 
1936  and  with  the  average  for  1925-30. 


Table  2. — Intermediates,  dyes,  and  other  coal-tar  chemicals:   Summary  of  United 
States  production  and  sales,  1937 

Number 
of  manu- 
facturers 

Production 

Sales 

Quantity 

Value 

Unit 
value 

Intermediates 

55 
230 

Pounds 
575, 893,  133 
373,  063,  335 

Pounds 
242,  194,  435 
315,742,113 

$35,  638,  618 
128,  735,  576 

$0. 15 

|  Finished  products,  total ' 

.41 

Dyes: 

Classified.. 

104,  499,  596 
17,  744, 983 

101,  585, 568 
16, 460,  559 

45,  452,  524 
19, 160, 390 

.45 

Unclassified  > 

1. 16 

Total 

43 

50 
47 
28 
71 
10 
43 

122,  244,  579 

118,046,127 

64,  612, 914 

.55 

Color  lakes  and  toners 

18, 040,  575 
14,  799, 821 
4, 356.  293 
142, 024,  541 
29,  202, 343 
42,  395,  183 

15,  262, 876 
11,989,359 
3,907,217 
109,201,349 
20, 909,  372 
36, 425, 813 

11,812,200 
11,496,045 
3,  982,  507 
20,  582, 156 
8, 193, 890 
8, 055, 864 

.77 

Medicinals 

.96 

Flavors  and  perfume  materials.. 

1.02 

Resins1 

.  19 

Rubber  chemicals 

.39 

Miscellaneous  chemicals  3_. 

.22 

1  Does  not  include  resins  from  adipic  ac 
i and  sulfonamides. 

2  Includes  azoic  dyes  (rapid  fast  and  rapid 
'AS  derivatives). 

3  Includes  benzoate  of  ammonia,  benzoa 
indicators,  poisonous  and  tear  gases,  synth 
tanning  materials,  textile  assistant'-,  and  ot 

d,  coumar 

ogene  dyes 

te  of  soda 
;tic  insecti 
tiers.    Doe 

one  and  inden 

)  and  their  com 

,  benzoyl  perc 
;ides,  phthalat 
3  not  include  c 

e,  hydrocarbor 

ponents  (fast  c 

xide,  biologies 
es,  photograph 
jmponents  for 

,  styrol,  succi 

olor  salts  and  e 

il  stains  and  < 
ic  chemicals,  s 
azoic  dyes. 

aic  acid, 

aphthol 

hemical 
ynthetie 

6  UNITED   STATES   TARIFF    COMMISSION 

Table  3. — Intermediates,   dyes,   and  certain  other  classes  1   of  coal-tar  chemicals 
Comparison  of  United  States  production  and  sales,  1925-30,  1936,  and  1937 


1925-30 
aver- 
age 


Increase, 

1937  over 

1936 


Intermediates: 

Production thousands  of  pounds.. 

Sales do 

Sales  value. thousands  of  dollars.. 

Finished  coal-tar  products: 

Production thousands  of  pounds.. 

Sales. do 

Sales  value thousands  of  dollars.- 

Dyes: 

Production... .thousands  of  pounds.. 

Sales .- do 

Sales  value thousands  of  dollars.. 

Medicinals: 

Production thousands  of  pounds.. 

Sales do 

Sales  value ..thousands  of  dollars.. 

Flavors  and  perfume  materials: 

Production ...thousands  of  pounds. . 

Sales do 

Sales  value thousands  of  dollars.. 

Resins: 

Production.. thousands  of  pcunds.. 

Sales do 

Sales  value thousands  of  dollars.. 


267, 492 
109, 133 
22, 408 

138, 078 
133, 964 
65, 027 

94,  003 
92,  207 
39, 428 

4,508 
4,106 
7,464 

3,966 
3,919 
2,901 

8  24, 442 
8  22, 135 
s  7,756 


509,  706 

223, 119 

31, 806 

2  3  336,  348 
2  3  287,  276 
2  3  120,  765 

«  119,523 

«  117,  573 

a  63, 686 

12, 034 
10, 079 
9,763 

3,481 
3.437 
3,220 

3  117.302 
3  86,  214 
3  17,056 


575, 893 

242, 191 

35,639 

2  *  373, 063 
2  4  315,  742 
2  *  128,  736 

> «  122. 245 

5  8  118,046 

5 «  64, 613 

14, 800 
11,989 
11, 496 

4,356 
3,907 
3,983 

4  142, 025 
4  109,  201 
4  20,  582 


Percent   , 
13.  or 

8.51 

12.  1 

10.9 
9.9 
6.6 

P> 

o 

o 

23.0 
19.0 
17.8 

25.1 
13.7 

23.7 

21.1 
26.7 
20.7 


1  See  text  for  changes  in  classifications  made,  from  time  to  time,  in  the  groups  listed  above. 

2  Includes  color  lakes  and  toners,  rubber  chemicals,  and  miscellaneous  coal-tar  chemicals  not  shown 
separately. 

3  Does  not  include  resins  from  coumarone  and  indene,  hydrocarbon,  styrol,  and  sulfonamides. 

4  Does  not  include  resins  from  adipic  acid,  coumarone  and  indene,  hydrocarbon,  styrol,  succinic  acid, 
and  sulfonamides. 

5  Includes  azoic  dyes  (rapid  fast  and  rapidogene  dyes)  formerly  included  in  the  miscellaneous  group. 

6  Includes  components  for  azoic  dyes,  formerlyi  ncluded  i  n  the  miscellaneous  group. 

7  Not  on  comparable  basis. 

8  Average  for  1927-30. 

SUMMARY  OF  PRODUCTION  AND   SALES  OF   SYNTHETIC    ORGANIC 
CHEMICALS  NOT  OF  COAL-TAR  ORIGIN 

Table  4  summarizes  the  production  and  sales  in  1937  of  the  several 
groups  of  synthetic  organic  chemicals  not  of  coal-tar  origin.  Only  a 
small  part  of  the  total  output  can  be  broken  down  into  the  several 
subgroups.  Table  5  compares  the  output  and  sales  of  all  non-coal-tar 
synthetics  in  1937  with  the  preceding  year  and  with  the  average  for 
the  period  1925-30. 


Table  4. — Synthetic  organic  chemicals  of  non-coal-tar  origin:  Summary  of  United 
Slates  production  and  sales,  1937 


Number 
of  manu- 
facturers 

Production 

Sales 

Quantity 

Value 

Unit 
value 

Medicinals 

Flavors  and  perfume  materials 

Resins 

37 
27 
16 
89 

Pounds 

1, 814,  035 

1, 802,  767 

21,005,869 

2,  505, 027, 014 

Pounds 

1,  442, 070 

1,  560,  469 

18,  891,  277 

1, 146,  255, 397 

$2, 408, 371 

1,024.435 

5,  680,  GOO 

110, 306, 424 

$1.67 
.66 
.30 

Miscellaneous '.. 

.10 

Total 

2,  529,  649,  685 

1, 168, 149,  213 

119,419,830 

.10 

1  Includes  non-coal-tar  rubber  chemicals  and  all  other  non-coal-tar  synthetic  organic  chemicals. 


DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  7 

Table  5. — Synthetic  organic  chemicals  of  non-coal-tar  origin:  Comparison  of  United 
States  production  and  sales,  1925-30,  1936,  1937 


Production thousands  of  pounds.. 

Sales thousands  of  pounds. . 

Sales  value.. thousands  of  dollars.. 


1925-30 
average 


379, 972 
264, 006 
44,  499 


1936 


2.041,455 

1,034,921 

105,  832 


1937 


2,  529,  050 

1, 168, 149 

119,420 


Increase, 

1937  over 

1936 


Percent 
23.9 
12.9 
12.8 


Part  II 

PRODUCTION  AND  SALES  OF  SYNTHETIC  ORGANIC  CHEMI- 
CALS IN  THE  UNITED  STATES,  1937 


COAL-TAR  CRUDES 

Statistics  of  production  of  coal  tar  in  1937,  collected  and  compiled 
by  the  Bureau  of  Mines,  show  an  output  of  603,053,000  gallons  as  com- 
pared with  560,386,000  gallons  in  1936.  Sales  totaled  386,648,000 
gallons  or  about  64  percent  of  the  output.  The  unit  sales  price  in 
1937  was  4.8  cents  per  gallon  as  against  4.3  cents  in  1936. 

Tar  distilled  by  purchasers  thereof  amounted  to  335,434,000 
gallons,  or  4  percent  more  than  in  1936. 

The  output  of  crude  naphthalene  was  115,979,000  pounds  as  com- 
pared with  89,536,000  pounds  in  1936.  Average  sales  price  was  2.3 
cents  per  pound  in  1937  and  2  cents  per  pound  in  1936.  Continued 
increasing  demand  for  tar  acids,  principally  by  makers  of  synthetic 
resins,  resulted  in  sharp  increases  in  the  output  of  phenol,  the  cresols, 
and  cresylic  acid.  An  important  development  in  raw  materials  for 
synthetic  resins  in  1937  was  the  first  commercial  production  of  para- 
cresol. 

Table  6  shows  statistics  of  domestic  production  and  sales  in  1937  of 
coal  tar,  the  quantities  of  the  several  lands  of  tar  distilled,  the  pro- 
duction and  sales  of  light  oil  and  derivatives  thereof,  and  of  the 
products  of  tar  distillation  and  processing.  These  data  were  collected 
ifrom  producers  of  tar  by  the  Bureau  of  Mines  and  from  purchasers  of 
tar  by  the  Tariff  Commission. 


10 


UNITED    STATES    TARIFF    COMMISSION 


Table  6. — Coal-tar  crudes: x   United  States  production  and  sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on  p. 
64.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  numbeii 
with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  statistics, 
of  production  or  sales  cannot  be  published  without  revealing  information  with  regard  to  individual  firms.'.! 

Tar  distilled  by  purchasers  thereof: 2 

Oil-gas  tar,  13,033,678  gallons $680.  465 

Water-gas  tar,  17,441,254  gallons „ --- 822,  434 

Coal  tar,  304.959,372  gallons - 16,737,898J 

Total,  335,434,304  gallons- - 18,  240,  797; 


Manufacturers'  identifica- 
tion numbers  (according 
to  list  on  p.  54) 


Production 
(quantity) 


Sales 


Quantity 


Value 


Unit 
value! 


Tar 3 ...gallons.. 

Light  oil  derivatives: 

Crude  light  oil do 

Benzol  (except  motor  ben- 
zol)  do 

Motor  benzol3 do 

Toluol,     crude    and    re- 
fined3  do — 

Solvent  naphtha do 

Xylol3 do.... 

Other  light  oil  products4 
do_... 
Naphthalene,   crude   and   re- 
fined 6_ pounds.. 

Anthracene,  crude  (less  than 

30  percent)2 do — 

Cumene  2 gallons.. 

Cresylic  acid  (less  than  7"o  per- 
cent)2  do 

High  residue  oils  2 do 

Pitch  paint 2 .do 

Pyridine  2 ..do 

Creosote  oil do 


Tars,  crude  and  refined  2.do— 

Tars,  road  2 do... 

Other  distillates  6 do... 

Pitch  of  tar tons... 

Pitch  of  tar  coke2... do- 


ll, 58, 69, 106, 119,  X. 
22,34,64,158,178—. 


22, 34,  57,  64, 124, 158, 185, 186. 


22,34,64, 158, 178 

22,  58, 119, 124, 178, 185, 186, 189 


603,  053, 288 

187, 103, 087 
26,  795, 497 

95, 526, 695 

20, 896, 724 
7,077,114 
4, 562, 344 

12,842,115 

115,979,238 


386,  648, 478 

11,153,337 

3  22,140,936 

93, 767, 208 

20, 173, 723 
6, 343,  220 
4,  245, 316 

11, 806, 798 

109, 394, 319 


$18, 456, 483 

962, 836 
3  2, 928, 471 

8, 384, 863 

5,  350, 087 

1,  295,  500 
1, 176,  723 

1,871,115 

2,  534,  526 


185. 
22.. 


22,186 

124 

185 

22  185 

ll|  22, "27," 57,"  58769," \W>, 

113,  119,  124,  127,  158, 

186,  189,  X. 
22,  27,  57,  58,  106,  113, 

124,  158,  178,  185,  186, 
11,  22,  69,  106,  113,  124, 

185,  186,  189,  X. 
11,  22,  57,  69,  106, 119, 124, 

185,  186,  189,  X,  X. 
11,22,27,57,58,69,  106, 

119, 124, 127, 185, 186,  15 
11,  22,  69,  113,  124,  172, 

186. 


110,' 
185, 

119, 

189. 
178, 

172, 

113, 
9,  X 
185, 


107,  293,  751 

23,  756,  212 

155, 088,  720 

34, 550, 805 

893, 715 

181, 495 


107, 485, 199 

23, 144,  241 

155,  745,  590 

8, 313, 627 

315, 443 

91, 983 


12, 472,  500 

1, 711, 437 
12, 907,  947 
1, 406,  736 
4, 382, 466 
1,131,812 


$0.  048' 


.  086j 

.132 


.265 
.204 

.277 

.158 
.023 


.116 

.074 
.083 
.169 
13.89 
12.30 


Total. 


76, 973,  502 


i  Data  for  coke  ovens  reported  to  Bureau  of  Mines,  and  for  tar  refineries  and  others  to  United  States 
Tariff  Commission,  unless  otherwise  noted. 

2  Reported  to  United  States  Tariff  Commission  only. 

3  Reported  to  Bureau  of  Mines  only. 
*  Includes  motor  benzol,  toluol,  xylol,  and  sales  of  benzol  reported  to  United  States  Tariff  Commission 

and  other  light  oil  products  repoited  to  Bureau  of  Mines. 

s  Includes  crude  and  refined  naphthalene  reported  to  Bureau  of  Mines  and  crude  naphthalene  reported 
to  United  States  Tariff  Commission. 

6  Includes  crude  tar  acids,  reported  to  United  States  Taiiff  Commission,  and  Bureau  of  Mines,  and 
phenol  and  sodium  phenolate  reported  to  Bureau  of  Mines. 

COAL-TAK   INTERMEDIATES 


The  peak  production  of  575,893,000  pounds  of  coal-tar  inter- 
mediates represents  an  increase  of  13  percent  over  1936.  Sales  totaled 
242,194,000  pounds  valued  at  $35,639,000,  or  an  average  of  15  cents  per 
pound.  The  difference  between  production  and  sales  is  due  to  large 
consumption  by  the  maker  in  the  manufacture  of  finished  products. 
There  were  55  makers  of  intermediates  in  1937  as  against  58  makers 
in  1936. 


DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


11 


Outstanding  gains  in  this  group  are  shown  by  intermediates  used  in 
synthetic  resins.  Phenol  output  totaled  65,690,000  pounds,  or  35  per- 
cent more  than  in  1936,  and  was  a  peak  peace-time  production. 
Production  of  phthalic  anhydride  increased  45  percent  over  the 
preceding  year  to  45,211,000  pounds.  The  cresols  and  maleic  anhy- 
dride, shown  separately  for  the  first  time,  both  record  appreciable 
increases  in  output.  Commercial  production  of  several  phenol 
derivatives  was  reported  for  the  first  time.  Other  raw  materials  for 
synthetic  resins  made  in  increased  quantity  include  tertiary  amyl 
phenol,  tertiary  butyl  phenol,  chloro-o-phenyl  phenol,  bis-phenol 
(p-p-dihydroxy  diphenyl -dimethyl  methane),  and  dichorophenol. 

Production  of  technical  benzoic  acid  increased  about  30  percent, 
mixed  cresols  more  than  30  percent,  paradichlorobenzene  22  percent, 
and  b-hydroxy  naphthoic  acid  21  percent.  Other  outstanding  gains 
are  noted  for  benzotrichloride,  benzyl  chloride,  cliloronapthalene, 
diphenyl  and  its  derivatives,  and  the  xylenols.  Most  of  the  inter- 
mediates for  dyes  were  produced  in  slightly  greater  quantities  than 
in  1936. 

Table  7  shows  production  and  sales  of  coal-tar  intermediates  in  1937. 


Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1987 

|The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  num- 
ber with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  sta- 
tistics of  production  or  sales  cannot  be  published  without  revealing  information  with  regard  to  individual 
firms.    The  figures  thus  concealed,  however,  are  included  in  the  total] 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
value 

p- Acetaminobenzene  sulfonamide 

p-Acetaminobenzene  sulfonyl  chloride 

X. 

Pounds 

Pounds 

X 

45,64,86,141 

37,219 

210, 848 

Acetoacet-o-chloroanilide ... 

64,219 

70  

Acetotoluide. 

34,148 

7 

Acetyl-p-phenylenediamine  (p-amino  acet- 

anilide). 
Acetyl-p-phenylenediamine  sulfonic  acid 

5, 45,  64,  86, 148 

86      - - 

239,  756 

64, 16S,  X... 

64,  148 

l-Amino-4-acetylamino-6   and   7-naphthyl- 
amine  sulfonic  acid  (acetylamino  Cleve's 
acid). 

148. 

64,86,148 

64,86, 148-.- 

Aminoazobenzene  and  hvdrochloride 

7,  34, 64, 86, 148 

7,  34,  45,  64,  86,  148, 

171. 
7,148 

173,461 
122,011 

Aminoazobenzene  disulfonic  acid 

34,  45,  64,  86,  148, 

171. 
64, 148. 

216,  391 

86,148  .. 

7,34 

64 

o-Aminobenzoic  acid  (anthranilic  acid) 

62, 64, 86. 

64                                        

Amino-5-benzovlaminoanthraquinone 

2(4-Aniinobenzoylamino)  5-aminotoluene 

64... 

64 

148                                    -- 

64.171 

64, 86, 148, 171                    50, 593 
64 

p-Aminobenzovl-m-phenvlenediamine _ 

m-Aminobenzoyl-p-tolylenediamine 

64. 1 

86997—38 3 


12  UNITED   STATES   TARIFF    COMMISSION 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — C( 


Name  of  intermediate 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 


Produc- 
tion 


Sales 


Quantity 


Value 


Unit 
valui 


l-Amino-2-bromo-4-p-toluidine    anthraqui- 

none. 
Aminobutyrylaminodiethyl  hydroquinone  - 

l-Amino-6-chloroanthraquinone 

Amino-4-chlorophenol... 

2-Amino-4-chlorotoluene- 

2-  Amino-3-chlorotoluene 

m-Aminoeresol  methyl  ether 

l-Amino-2:4-dibromoanthraquinone 

2-Amino-5-diethylaminotoluene  hydrochlo- 
ride. 

p-Aminodiethylaniline 

p-Aminodiethyl  benzaldehyde 

p-Aminodimethylaniline 

p-Aminodiphenylamine 

Aminodiphenylamine  sulfonic  acid 

Aminodiphenyl  ether 

p-Aminoethylbenzylaniline  sulfonic  acid 

l-Amino-2-methyl-4-p-toluidine  anthraqui- 
none. 

1:7-Aminonaphthol 

l-Amino-2-naphthol-4-sulfonic  acid 

l-Amino-8-naphthol-l-sulfonic  acid 

l-Amino-8-naphthol-2:4-disulfonic  acid  (Chi- 
cago acid). 
l-Amino-8-naphthol-3:6-disulfonic  acid   (H 

acid). 
2-Amino-5-naphthol-7-sulfonic  acid  (J  acid). 
2-Amino-8-naphthol-C-sulfonic  acid  (gamma 
acid). 

Amino-2-naphthol-6:8-disulfonic  acid 

2-Amino-8-naphthol-3:6-disulfonic  acid  (2  R 

acid) . 
Amino-l-naphthylamine-6    and    7-sulfonic 
acid  (amino  Cleve's  acid). 

o-Aminophenol 

o-Aminophenol  sulfonic  acid 

p-Aminophenol  and  hydrochloride 

p-Aminophenylammonium -hydroxide 

m-Aminophenylpyrazolone  carboxylic  acid. 
p-Aminophenyl-p-tolylamine  sulfonic  acid.. 

Aminopyrazolone-— 

Aminosalicylic  acid 

Amyl  naphthalenes 

Amyl  phenol  (p-tert  iary) 

l-Anilido-2-carboxylic  acid  anthraquinone.. 

Aniline  disulfonic  acid 

Aniline  hydrocholride  and  sulfate 

Aniline  methane  sulfonic  acid 

Aniline  oil 

Aniline  omega  sulfonic  acid 

Anisic  acid _. 

o-Anisidine 

c-Anisidine  omega  sulfonic  acid 

p-Anisidine „ 

Anthracene,  refined 

Anthranilic    acid.     (See    o-Aminobenzoic 

acid.) 

Anthraquinone  (100  percent) 

A nthraquinone-a-sulfonic  acid 

Anthraquinone-l:5-disulfonic  acid. 

Anthraquinone-l:8-disulfonic  acid 

A nthraquinone-2:6-disulfonic  acid 

Anthraquinone-l:8-potassium  disulfonate... 

Anthraquinone- 1-sodium  sulfonate 

Anthraquinone-2-sodium  sulfonate   (silver 

salt). 

Anthraquinone-2:fi-disulfonate 

A nthraquinone  2:7-disulfonate 

1 :9-Anthrathiazol-2-carbonyl  chloride 

Azobenzene 

Azoxyaniline ~ 

Benzaldehyde,  tech ..I.I" 

Benzaldehyde  disulfonic  acid '..'..'. 

Benzanthrone.. 


64. 


Pounds 


Pounds 


171 

64 

148 

64, 148. 
64, 148. 

45 

64, 148. 
70 


70,86 

64 

70,224.... 

64 

45, 86, 148. 

171. 

64 

64. 


64.. 

45,  64, 86, 148. 
45,64,148.... 
45,64,148.... 


64, 86, 145, 148. 


5,45,64,148-. 
45, 64, 86, 148_ 


1,367,419 
74, 161 
181,431 

3. 382, 396 

551, 956 
1,081,751 


64, 148_ 


IA 


64,70,224,232 

45,148 

34,  45,  64,  70,  224, 

232. 
X 


19, 226 


$21,541 


$1. 12 


743, 321 


461, 984 


.  65 


171 

45 

171,  X.... 
7,  45,  148. 
X... 


20,665 


X 

64 

45,64,  148 

34,  X 

86,  171 

34,  62,  64,  141,  145, 
148,  X. 

148,  171 

X 


24, 892 


38, 850,  344 


14,720,211 


1,  667,  159 


64,  145 

86,  148,  171. 
64,  145,  148. 
185 


13,  682 


34,  148 

86,  148.... 

64,86 

86 

86,  148.... 

64- 

64 

7,  64,  148. 


64 

148.... 

64 

X 

171 

101,  X. 


7,  34,  64,  86,   148, 
167. 


DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  13 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con. 


Name  of  intermediate 


Benzene  sodium  disulfonate 

Benzidine,  base 

Benzidine  hydrochloride  and  sulfate 

Benzidine  sulfonic  acid 

Benzidine  disulfonic  acid 

Benzoic  acid,  tech 

Benzotrichloride 

l-Benzoylamino-4-chloroanthraquinone 

l-Benzoylamino-5-chloroanthraquinone 

5-Benzoylamino-l:l-dianthramide 

l-Benzoylamino-5-p-toluene  sulfonic  anthra- 

quinone. 

Benzoyl  benzoic  acid 

Benzoyl  chloride -. 

Benzoyl  J  acid -. 

Benzyl  chloride 

Benzyl  disulfide 

Broenner's  acid.    (See  2-Naphthylamine-6- 

sulfonic  acid.'). 

Bromobenzanthrone 

Bromobenzene 

p-Bromomethylaminoanthraquinone 

p-Bromophenol 

Butyl  phenol  (p-tertiary) 

Chicago    acid.    (See    l-Amino-8-naphthol- 

2:4-disulfonic  acid.). 

o-Chloroacetoacetanilide 

Chloroacetoacetylnaphthylamide 

l-Chloro-5-aminoanthraquinone 

l-Chloro-8-aminoanthraquinone 

o-Ch!oroaminobenzoic  acid 

Chlcroaminopheuol  sulfonic  acid 

5-Chloro-2-aminotoluene  hydrochloride 

m-Chloronailine --- 

o-Chloroaniline - 

p-Chloroaniline 

p-Chloroaniline  sulfonic  acid. 

2-0  hloroaniline-5-sulfonic  acid 

Chloroanisidine 

Chloroanisidine  methylene 

Chloroanthraquinone .. 

o-Chlorobenzaldehyde... 

Chlorobenzanthrone... 

Chloro  benzene  (mono) 

o-Chlorobenzoic  acid 

Chlorobenzoyl  benzoic  acid.. 

l-Chloro-2-carboxyanthraquinone 

p-Chloro-m-cre'sol 

2-Chloro-l:4-dihydroxy  anthraquinone 

(chloroquinizarin) 

Chlorometanilic  acid 

Chloromethylanthraquinone 

Chloronaphthalenes 

o-Chloro-p-nitroaniline 

p-Chloronitroaniline 

l-Chloro-5-nitroanthraquinone 

l-Chloro-8-nitroanthraquinone 

4-Chloro-2-nitrotoluene 

6-Chloro-2-nitrotoluene 

o-ChlorophenoL - 

p-Chlorophenol --- 

Chlorophenylhydrazine-p-sulfonic  acid 

Chlorophenylmethylpyrazolone    sulfonic 

acid 

2-Chloro-o-phenylphenol 

2-Ohloro-6-phenylphenol  and  sodium  salt.. 

4-Cbloro-fi-phenylphenol 

Chlorosulfophenylmethylpyrazolone 

Chloro  symmetrical  xylenol 

Chlorotoluene 

o-Chloro-p-toluene  sodium  sulfonate. 

Chloro-o-toluidine 

4-Chloro-2-toluidine  methylene 

Chlorotoluidine  sulfonic  acid 

,  2-Chloro-4-toluidine-5-sulfonic  acid 

Chlorotolylthioglycollic  acid 

p-Chloro-p-xylidine 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 


64 

45,64,  148 

5,  34,  64,  70,  86,  148. 

7,45 

45,  145,  171,  X 

64,  101,  105,  145_... 

101,  105,  145 

64,86 

64 

64... 

64 


34,64,  148 

105,  X 

45 

101,  105,  X,  X. 
105 


62,  70. 


37 

171 

64,  148... 

64 

X.. 

45,  64,  86. 
64 

86,  145.... 
145,  224... 
145,  224... 


105,  171,224. 

171 

34,64,86,  148 

86,  148 

7,  148 

62,64,105,145,201. 

148.X 

34,64,86,  148 

64 

22. 


7,  148. 

64,  148 

34,  64,  148. 

105,  X 

34,62,64.. 

64,  224 

64 

64. 

64.... 

64,  148 

145 

62,  145 

86... 


62 

62 

64 

22 
64\T05~,~148\~. 

145 

64,148 

171 

34,  45,  64,  X. 

64 

64,86,  148... 
64 


Produc- 
tion 


Pounds 


1,  539,  383 


6,165 
125,  444 


1,181,079 


337,  650 


1,115,075 


52, 862 


186,  691 


304,  240 


312,  205 


Quantity 


Pounds 


121,  394 


Value 


$43,  607 


Unit 
value 


$0.  36 


14 


UNITED   STATES   TARIFF    COMMISSION 


Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
vain 

p-ChloroxylylthioglycolIic  acid 

64,86 

Pounds 

Pounds 

Chronotropic   acid.      (See    l:8-Dihydroxy 
naphthalene-3:6-disulfonic  acid.) 

Cleve's  acid.    (See  l-Naphthylamine-6  and 
7-sulfonic  acid.) 

•Copper  phthalocyanine urea salt 

64 

64 

m-Cresol 

22,  X 

22,  185,  X 

22,  209 

22,  185,  X 

22,  34,  124,  185,  X.. 
62,  148 

13,  745,  271 

13,  251,  345 

$1,071,965 

$6.d 

o-Cresotinic  acid.    

Cresylie  acid  (refined) 

22,  124,  185,  X 

23,  148,  207 

70 

Cvclohexvlamine  _.-  

145 

64 

Dehydrothio-p-toluidine  sulfonic  acid 

64,  148. 

224 

7,  64,  148 

64 

64 

171. 

Diaminodiinethvlphen\lacridine 

171... 

4'4-l>iannno-2:2-diniethvldiphenvlniethane. 

148 

Diaminodiphenylamine  sulfonic  acid 

5,  45 

7,  171 

l:8-I>iamino-4:5-dimtro  anthraquinone 

64 

34 

Diaminostilbene  disulfonic  acid 

64,86,  148 

180, 819 

l:5-I)ianilidoanthraquinone-o-o-dicarboxylic 
acid  (dicarboxylic-an thraquinone) 

64... 

45,  64 

64 

64 

l:l-Dianthraquinone   imine-4:4-dibenzoyl 

64. 

l:l-Dianthraquinone    imine    4:5-dibenzoyl 

64 

64. 

86 

45,  64,  148 

64,86,  148 

64 

34,  64 

64 

64 

64 

64 

64 

62 

64 

171 

37 

45,  64, 105, 145, 148, 

224. 
86 

231,  308 

79, 387 

31,  309 

.39 

64,86,148,171 

64,86 

35, 776 

64.. 

64 

62,64,105,145 

62,64,105,145,201.. 
64 

3,  209,  179 
11,  705,  376 

2,  881, 138 
11, 118,  594 

147.  129 
1,095,118 

.05 

.10 

171 

l:8-Dichloro-4:.")-(linitroanthraquinone 

64. 

171 

171 

145. 

171. 

Dichlorosulfopheuvlpvrazolone 

45 

Dichlorosulfophenvlmethylpyrazolone 

64 

145 

Diith  vlaminobenzaldehyde 

70,86,148. 

Disthvl-m-aminophenol    . 

64,  X  . 

Diethvlaniline _ 

64,  148 

Diethylaniline-m-sulfonic  acid 

G4.X. 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  15 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con. 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
value 

l:4-Dihydroxyantbraquinone  (quinizarin).. 

l:5-Dihydroxy  anthraquinone  (anthrarufin). 
l:8-Dihydroxy  anthraquinone  (chrysazin)  _ . 
p-p-Dihydroxydiphenyldimethylme  thane 

(bis-phenol). 
5:5-Dihydroxy-7:7-disulfonie-2:2-dinaph- 

thvlamine  (Rhoduline  acid). 
5:5-Dihydroxy-7:7-d  is  u  1  f  o  n  i  c-2:2-d  i  na  p  h- 

thylurea  (J  acid  urea) . 

5,  7,  16,  64,  86,  148, 

171,234 
64,86,  148, 171,  X... 
64,86 

Pounds 
205,  544 

162, 127 

Pounds 

62 -.. 

5,64.. 

45,64,86,148.. 

64,86,148 

207,  396 

l:8-Dihydroxynaphthalene-3:6-disulfonic 

acid  (chromotropic  acid). 
5:5-Dihydroxy-di-b-naphthylamine-7:7-di- 

sulfonic  acid  (I  acid  imide). 

45,64,148 

148 - 

64            

34,  64,  148  . 

3,  510, 106 
55,  983 

34,64,86,148 -- 

34,64,145,  148- 

7              

64                

Dinitroanthrarufin  disodium  sulfonate 

64.  . 

34.64,148      

1,  873, 430 

45,86-..   

34,64.86,145,148.-. 
64            

7, 009,  768 

4:8-Dinitro-l:5-dinitrophenyl  ether  anthra- 
quinone. 

64     

45,86     

7,64,86,148 -- 

64,86,148     

344,688 

64, 148 

86 

l:5-Dioxamino-4:8-dinitroanthraquinone 

64 

64              

64                   

64     .       . 

62, 145, 171 

Diphenyl  derivatives: 

145          

145                

3-Broruo-4-hydroxy  and  sodium  salt 

62 

145 

64 

64  148,  X 

44,590 

64 

148 

64 

l:8-Di-p-toIuidine  anthraquinone 

64     . 

64 

-6-Ethoxy-3-hydroxy  thionaphthalene 

64 

X 

64 

64,  148 

62 

X               

64,  148 

45,  64,  86,  148 
64,  148 

425, 979 

Ethylbenzyl-m-toluidine  sulfonic  acid 

64,  86,  148  .. 

62,  X 

64,  148 

64 

64 

37 

Fast  yellow  L 

5  . 

64 

102,  152 

171 

Gamma  acid.    (See  2-Amino-8-naphthol-6- 

sulfonic  acid.) 
Hacid.    (See  l-Amino-8-naphthol-3:6-disul- 

fonic  acid.) 

62               

2:1-2: 1-IIydrazine  dibromoanthraquinone... 
a-Hydroxyanthraquinone 

64            

7,64-.. 

16 


UNITED    STATES    TARIFF    COMMISSION 


Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con, 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
value 

1 

64 

Pounds 

Pounds 

64,  86,  148  . . 

996, 909 

486, 894 

$482,  352 



$0.  99- 

64 

5 

5,  64 

Isopropyl  ester  of  p-toluidine  sulfonic  acid.. 

64 

64 

7,  64  . 

Laurent's  acid.     (See  l-Naphthylamine-5- 

sulfonic  acid.) 
Lead  trinitroresorcinate  (lead  styphnate) ... 

X 

Leuco-l:4-dimethyldiaminoanthraquinone.. 

64 

Leuco  indophenol  BCFN 

64... 

5,  7,  64,  X  .. 

8,  145,  148 

2. 114, 176 

Malic  acid 

148 

Metanilic  acid 

5,  45,  64,  86,  148 

171 

523,  561 

Methoxychlorobenzene  diazoamino  carboxy 

pyrrolidine. 
Methoxy  omega  sulfonic  acid 

64. 

l-Methylamino-4-brornoanthraquinone 

64... 

4-Methy]-4-aminodiphenylamine-2-sulfonic 

86 

acid. 
1  -  Meth vlamino  -  4  -  p  -toluidine  anthraqui- 

64 

none. 
Methvlaminoanthraquinone. 

86     

b-Methylanthraquinone 

34,  64 

148,  X 

Methylene  bismethyl 

X 

Michler's    hydrol.      (See    Tetramothyldi- 

aminobenzhydrol.) 
Michler's    ketone.      (See    Tetramethyldi- 

aminobenzophenone.) 
Naphthalene,  solidifying  79°  C.  or  above 

(refined,  flake). 
From  domestic  crude 

22,  34,  57,  64,  185, 
196,  205,  230,  X. 

52, 194,  379 

24,  999,  732 
27, 194,  647 

29,  656, 585 

1,893,257 

.06 

From  imported  crude 

Naphthalene  sodium  sulfonate 

86 

Naphthalene-! ■.fi-disodium  sulfonate 

148  .. 

b-Naphthalene  sulfonic  acid 

64,  86.  148... 

1:5  Naphthalene  disulfonic  acid . 

45,  64,  86.  148 

64,  148,  X 

305, 804 

2:7-Naphthalene  disulfonic  acid... 

Naphthalene-h-thiodvcollic  acid 

64,  86 

Naphthalene-l :3:6-trisulfonic  acid 

86 

Naphthionic  acid.    (See  1-Naphthylamine- 

4-snlfonic  acid.) 
a-Naphthol 

45,  64,  86,  148. 

45 

1,159,511 

830,  355 

425,816 

.51 

a-Naphthol-3:6-disulfonic  acid 

b-Naphthol,  tech 

34,  148,  X 

l-Naphthol-4-sulfonic     acid      (Nevile     & 

5,  45,  64,  148 

45,  64,  86,  148 

148 

146,  302 
121,457 

Winther's  acid). 
l-Naphthol-5-su'  fonic  acid 

l-Naphtho'-8-chloro-3:6-disulfonicacid(chloro 

Hacid). 
2-Naphthol  sulfonic  acid 

64 

2-Naphthol-6-sulfonic  acid  (Schae tier's  acid). 
2-Naphthol-7-sulfonic  acid 

5.  34,  45,  64,  148 

45,  64,  X     . 

175,  749 

24,  374 

10,  617 

.44 

2-Naphthol-8-sulfonic  acid 

45 

2-Naphthol-3:6  disulfonic  acid 

45,  64,  86,  148,  X.._ 

45,  64,  86,  148 

45 

522,  222 
1,  199,  034 

153,  466 

82, 491 

.54 

2-Naphthol-6:8-disulfonic  acid 

Naphthsulton  sulfonic  acid  1:8:3 

45 

b-Naphthovlacetonitrile _ 

70..  . 

a-Naphthyiamine 

64,  86,  148 

3,  281, 458 

387, 678 

127,  228 

.33 

a-Naphthylamine  disulfonic  acid 

64 

b-Naphthylamine 

64,  148 

l-Naphthylamine-2-sulfonic  acid    (o-naph<- 

64... 

thionic  acid). 

45,  64,  148,  X 

onicacid). 
l-Naphthyiamine-5-sulfonicacid  (Laurent's 

5,  64,148 

acid). 
l-NaphthyIamine-6-sulfonic  acid 

64,  148 

l-Naphthylamine-6    and    7-sulfouic    acid 

5,  45,  64,  86     . 

(Cleve's  acid). 
l-Naphthylamine-7-sulfonic  acid 

45,  64,  148       

5,  64,  86,  148 

45,64,148 

246.  053 
86. 842 

l-Naphthylamine-3:8-disulfonicacid 

DYES   AND    OTHER   SYNTHETIC    ORGANIC    CHEMICALS  17 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con. 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
value 

1-Napht h vlamine4:8-disulfonic  acid __ . 

45,64,  148. 

Pounds 
409,  235 

Pounds 

b-Naphthvlamine-2:3:6-disulfonic  acid 

45. 

l-Naphthvlami'ie-3:6:8-trisulfonic  acid 

64,86,  148 

4, 649, 858 
1, 155, 494 

2-Naphthylamine-l-sulfonic    acid    (Tobias 

acid). 
2-Naphthvlamine-6-sulfonic    acid    (Broen- 

5,  34,  45,  64,  X 

64,  148... 

564, 978 

$365,211 

$0.61 

ner's  acid). 
2-Napht  hylamine-3:6-disulfonic  acid _  _ 

148 

2-Naphthylamine-48-disulfonic  acid 

64,  86,  148 

109, 460 

993. 920 

1, 624,  271 

2-Naphthylamine-5:7-disulfonic  acid 

45,  64,  148 - 

2-Naphthylamine-6:8-disu]fonic  acid 

45.64,148 

2-Naphthvlamine-2:3:6-trisulfonic  acid 

148... 

l-Naphthylamino-2-carboxylic     acid     an- 

64. 

thraquinone. 

5,45,86       

Nitroacetoacetylnaphthylamide 

171 

148... 

148— 

64 

Nitroaminodiphenylamine-o-sulfonic  acid.  .. 

7 

p-N  i  t  r  o-p-  aminodiphenylamin  e-o- 
sulfonicacid. 

5 

34,45,86,  148 

64 

106,  583 

148 

34,45,64,224 

145 

185,  780 

113,462 

73, 037 

.64 

7,  64,  X   ... 

34,  64,  86,  148 

64.. 

77, 329 

86 

64,  86 

64,  145    

64,148      

34,  64,  145,  148,  X.. 
45,  64,  86,  148,  171.. 
64 

53,  301,  541 
171,441 

4, 480, 146 

322, 953 

.07 

64 

64,  105 

7 

64,  105 

64.  86 

Nitrobutyrylaminodiethyl  hydroquinone.-. 

171 

171 

64,  145 

64,  145 

o-Nitrochlorobenzene-p-sulfonicacid 

148 

64,  145 

p-Nitrochlorobenzene-o-sulfonic  acid 

7,  45,  64,  86,  148 

148 

287, 036 

64 

1 

45 

64 

8-Nitro-l-diazo-2-naphthol-4-sulfonic  acid ... 

86,  148    - 

45,  148,  224 

171 

64,  86,  148 

4, 608, 601 

2-Nitronaphthalene-4  : 8-disulfonic  acid. 

64,  70,  171 

2,732 

34,  45,  64,  70,  148— 
34,  64,  86,  148 

650,711 

7,  45    — 

p-Nitrotoluene 

64,  148 

18                                UNITED    STATES    TARIFF    COMMISSION 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — 

Con. 

Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit  i 
value 

5,  45,  64,  86,  148. ... 
1 

Pounds 
981,  764 

Pounds 

34,  45,  64,  168,  X... 
64,  171 

801, 152 

731,971 

$919,  289 

$1.26 

171 

64,  14S__ 

N.  N.  Dihydroxydiethyl-m-toluidine 

64 

64,  86... 

64,  148. 

64,  86 

148 

64,  86 

105 

62,  145 

5,  64,  145  . . 

62,  64,  145       

22,  34,  62,  124,  145, 

185,  X. 
45,  64.  148 

65,  689,  782 
71,  122 
11,  549 

57, 175,  514 

6, 152,  843 

.11 

Phenvl-2-amino-5-naphthol-7-sulfonic  acid 

(phenyl  i  acid). 

5,45,64,  171 

X 

(phenyl  gamma  acid). 

X  .. 

1 

7,  34,  45,  64,   148, 
179. 

45,  64,  86,  148 

34,  45  . 

782, 065 
105,  693 

45,  86 

64  .. 

62,  64,  148 

7,  257,  445 

62,  70,  171,  188  .. 

86,  171,  207 

1 

14,  695 

34,  62,  64,  171,  X.__ 
64,  171. 

166, 064 

Z). 

5,64,86,  148 

62    ... 

230, 682 

62  .. 

Phloroglucinol.    (See  table  15.) 

X     . 

Phthalates.    (See  table  15.) 

8,  22,  64,  145,  148... 
64  .. 

45, 210,  784 

17,  565, 905 

2, 492, 473 

.14 

Phthalvl  chloride 

145  .. 

22  .. 

Picramic  acid  and  salt.. 

34,  64,  148 

64,  105,  145 

Primuline,  base . 

64,  148      

86,  167 

171 

168 

64 

Quinaldine.    (See  2-Methyl  quinoline.) 

148 

Quinoline 

22 

Quinoline  derivatives 

X 



86 

64,  168 

Rhoduline   acid.     (See   5:5-Dihydroxy-7:7- 

disulfonic-2:2-dinaphthylamine.) 
Rubber  chemicals.    (See  table  14.) 

62,  64...  . 

64 

Schaeffer's    acid.    (See    2-Naphthol-6-sul- 

fonic  acid.) 
Silver  salt.     (See  Anthraquinone-2-sodium 

sulfonate.) 

62 

Sodium  naphthionate.. 

64 

Sodium  pentachlorophenate... 

62 

Sodium  o-phenvlphenate... 

62 

Sodium  tetrachlorophenate... 

62 

Sodium  trichlorophenate 

62 

Sodium  xylene  sulfonate.. 

DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  19 

Table  7. — Coal-tar  intermediates:   United  States  production  and  sales,  1937 — Con. 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  intermediate 

Quantity 

Value 

Unit 
value 

Succinic  acid  and  anhydride 

148,  X 

Pounds 

Pounds 

Sulfanilic  acid  and  salt. 

7,  34,  45,  64,   148, 

224. 
64,86 

1, 712,  984 

o-Sulfobenzaldehyde 

p-Sulfo-o-benzoyl  benzoic  acid   (sulfo  BB 

64 

acid). 
l-Sulfo-5-nitroanthraquinone 

64 

Sulfophenylmethvlpyrazolone 

45,64,  171. 

Sulfophenylmethylpyrizolone      carboxylic 

171 

acid. 
Tetraaminoditolvlmethane 

148,  171. 

2:4:5:6-Tetrachlorophenol 

62 

Tetraclilorophthalic  anhydride 

148 

Tetraethyldiaminobenzophenone       (ethyl 

64 

ketone). 
Tetrameth  vldiaminoacridine 

171 

Tetramethyldiaminobenzhydrol  (Michler's 

64,86 

hydrol). 
Tetrameth vldiaminobenzophenone  (Mich- 

64,86, 148 

ler's  ketone). 
Tetramethyldiaminodiphenylmethane 

34,  64,  86,  148,  171, 

X. 
148 

691,900 

Tetramethyldiaminodiphenylinethane  sul- 

fonate. 
Thioaniline .. 

5,64,  148 

Thioaniline  disulfonic  acid 

148 

Thiocarbanilide.    (See  table  14.) 

148 

45,  64,  70.  148 

7,  171,  X 

301,  657 

145 

145 

p-Toluene  sulfonic  acid  ethvl  ester. 

224 

34,  64 

171 

64,  148 

34.  64,  148 

o-Toluidine  omega  sulfonic  acid... 

148 

34,  64,  148. 

p-Toluidine 

64.  148 

p-Toluidine  sulfonic  acid 

45,  64,  148 

p-Tolyl-o-benzoic  acid. 

34,  64,  148.. 

149, 882 
1, 142, 040 

34,45,64,  148 

64,  148 

360,  597 

$234,  683 

$0.65 

m-Tolylenediamine  sulfonic  acid. 

p-Tolylenediamine  sulfate 

34 

p-Tolyl-b-naphthylamine 

64 

Tolyl-l-napthylamine-8-sulfonic  acid  (tolyl 

5,  86.  148 

peri  acid). 
Tribromophenol 

62 

62  . 

41,  145,  161 

Trinitropbenol 

64,  148 

2:4:6-Trinitroresorcin  (styphnic  acid) 

X... 

l:2:4-Trioxvanthraquinone 

86  .. 

Triphenylphosphate... 

62,  145,  X 

m-Xvlene 

64,  X 

34,  185 

3:5-Xvlenol 

22 

64,  148 

64,  148. 

m-Xylidine  acetate 

148 

7,  64,  148 

7,  34,  64,  148... 

1,  64,  171,  X... 

Total  intermediates: 

For  which  individual  statistics 

352,141,921 
223,751,212 

155,215,204 
86, 979,  231 

17, 958,  474 
17, 680, 144 

.12 

are  shown. 
For  which  individual  statistics 

.20 

cannot  be  shown. 

Grand  total 

575,893,133 

242,194.435 

35,  638, 618 

.15 

20 


UNITED    STATES    TARIFF    COMMISSION 


COAL-TAR  DYES 


PKODUCTION  AND  SALES  BY  TYPES 


Coal-tar  dye  production  in  1937  totaled  122,245,000  pounds,  or  2.3 
percent  greater  than  in  1936.  Sales  increased  less  than  1  percent  in 
quantity  and  slightly  over  1  percent  in  value  to  118,046,000  pounds, 
valued  at  $64,613,000.  Sales  of  classified  (Colour  Index)  dyes 
decreased  1.5  percent  in  quantity  and  2.2  percent  in  value,  while  new 
and  unclassified  dyes  show  a  14  percent  increase  in  quantity  and  11 
percent  increase  in  value  of  sales.  A  large  part  of  this  increase  is  due 
to  the  inclusion  of  azoic  dye  components  in  this  group  for  the  first 
time.  The  unclassified  dyes  account  for  14  percent  of  the  sales 
quantity  and  30  percent  of  the  sales  value  of  all  dyes  in  1937. 

Production  of  synthetic  indigo  increased  slightly  to  18,417,000 
pounds,  while  sales  quantity  declined  slightly  to  17,791,000  pounds, 
valued,  at  $2,965,000.  Output  of  13,615,000  pounds  of  sulfur  black 
was  7  percent  less  than  in  1936. 

In  1937  production  of  food  dyes  increased  to  425,000  pounds,  as 
compared  with  409,000  pounds  in  1936.  Average  sales  price  dropped 
to  $2.86  per  pound  from  $3  per  pound  in  1936. 

There  were  43  makers  of  dyes  in  1937  and  41  makers  in  1936. 

Table  8  shows  production  and  sales  of  coal-tar  dyes,  by  tvpes,  in 
1937. 


Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 

The  numbers  in  the  third  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  num- 
ber with  the  designated  product.  Blanks  in  the  fourth,  fifth,  and  sixth  columns  indicate  that  the  statis- 
tics of  production  or  sales  cannot  be  published  without  revealing  information  with  regard  to  individual 
firms.    The  figures  thus  concealed,  however,  are  included  in  the  total] 


Colour 

Name  of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Index 
No. 

Quantity 

Value 

Unit 

value 

2 

CLASSIFIED  DYES 

Nitroso  Dyes 

Fast  printing  green 

86... 

Pounds 

Pounds 

5 

Naphthol  green 

5,  34 

10 

NlTRO  DYES 

Naphthol  yellow  S 

34,45 

16 

Azo  Dyes 

MONOAZO  DYES 

Acid  yellow  G 

7,86.... 

17 

Spirit  yellow  R 

7,  34.  55,  80,  86, 148. 
7,34,55,80,86,148.. 
7, 34,  55, 86, 148 
34,86,148.. 

54, 960 

28,678 

441,451 

120, 802 

55, 854 
30, 096 

$46, 093 
19,  642 

$0.83 

19 
20 

Butler  yellow ... 

Chrysoirline  Y 

.65 

21 

Chrysoidine  R_ 

23 

Oil  orange 

55 

24 

Sudan  I 

7,34,55,64,86,148.. 

7,45,148 

312,  224 

298, 116 

145,  401 

.49 

26 

Croceine  orange... 

27 

Orange  Q 

34,45,64,86,148.... 
148... 

190,  364 

184, 035 

87, 136 

.47 

29 

Chromotrope  2R 

30 

Fust  acid  fuchsine  B 

7,148 

31 

Amido  naphthol  red  Q 

5,  7,  34,  45,  64,  86, 

148. 
7,34,45,86 

476,  775 

166,  332 
95,  726 

438, 227 

128,330 
82,  761 

144,  246 

60,621 
41, 173 

.33 

36 

Chrome  yellow  2Q 

.47 

40 

Chrome  yellow  R._ 

7,  34,  45, 86, 216 
7,45,86 

.50 

52 

Mordanl  yellow  4G 

53 

Victoria  violet 

34,45,64,88,148 

X 

106,  652 

98,  251 

54,  45S 

.55 

54 

Lanafuchsine 

DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  21 

Table  8.- — Coal-tar  dyes:  United  States  'production  and  sales,  by  types,  1937 — Con. 


Name  of  dye 


CLASSIFIED  DYES— Contd. 

Azo  Dyes— Continued 

monoazo  dyes— continued 

Azo  coralline 

Chromotrope  6B 

Amido  naphthol  red  6B 

Toluidine  red  RL 

Sudan  II 

Ponceau  2R 

Double  ponceau  R... . 

Bordeaux  B 

Chromotrope  10B 

Chrome  brown  R 

Palatine  chrome  green  G 

Chromate  brown  B 

Acid  chrome  brown  R 

Chrome  flavine  G 

Azo  eosine  G 

Eosamine  G 

Chrome  yellow  5G 

Direct  pink  E2GN 

Direct  pink 

Direct  pink  EBN 

Metanil  yellow - 

Methyl  orange 

Azo  flavine  2R 

Azo  yellow - 

Resorcin  yellow. 

Orange  II 

Permanent  orange  R 

Orange  R 

Lake  red  4B - 

Lake  red  C  (strength  100%)... 

Acid  chrome  brown  B 

Acid  chrome  garnet  R 

Chrome  violet  R.. 

Chrome  black  PV 

Acid  alizarin  black  R 

Acid  brown  R -- 

Fast  red  A 

Azo  rubine 

Fast  red  VR 

Croceine  scarlet  3BX. 

Amaranth 

Cochineal  red 

Lake  red  R  (strength  100%) 

Mordant  yellow 

Chrome  yellow  RN._ 

Chrome  blue  black  B 

Chrome  blue  black  U 

Chrome  black  T 

Chrome  black  A 

Fast  acid  blue  R 

Fast  acid  blue  B 

Lake  red  D  (strength  100%) 

Chrome  red  B 

Eriochrome  flavine  A 

Direct  pink  R 

D1SAZO  DYE3 

Resorcin  brown  B.. 

Resorcin  dark  brown. 

Acid  chrome  brown  G 

Acid  black  10B... 

Acid  dark  green  A 

Cloth  red  R 

Brilliant  croceine 

Cloth  red  3G 

Sudan  IV... 

Cloth  red  2B. 


Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 


45,148 

5,  7,  34,  45,  64,  86, 

148. 
199 

7,  34,"55,"s6,S6,"l48- 
5,  7,  34,  45,  64,  86, 

148. 
64,86 

34,45,86,14S 


45,86... 

86 

34.179.X 

64 

86 

64.... 

64 

45 

64 

148 

64 

7,45,64,86,148. 


86 

7.86,148 

5,34,86,148 

34,  45, 86, 102, 148. 

X 

34,64,148 

45,64,148 

34,64 

148 

45,86,148 

45,64,148 

86, 14S 


86 

34,45,64,86,148 

7,45.64,86,148 

34,45,86.148 

45 

7,45.148 

34.  45.86,148 

148,199 

7,45,86,148. 

5,7,86,  148 

45,  64.  86,  148 

7,  45,  64,  86,  148.... 

45,86,  148 

45,  86,  148,  179 

5,64,86.  148 

64,86,  148 

199 

5,  45,"64"86,"l<B7 
234. 

64,  86,  X 


5,  7,  34,  45,  64,  86, 

148,  233. 
5,  7,34,  55,86,  148. 

64 

5,  7,  34,  45,  64,  86, 

148,  233. 

45,  55,  64... 

45.... 

34,  45,  64,  86  148— 

64 

45,  55,  64,  8'     148— 
7,45,86,  148 


Produc- 
tion 


Pounds 


326, 827 


15,  749 
322,  629 


125,  531 


381,  356 


85,  949 

15, 094 

1,  272,  475 


106, 669 
132,  703 
113,893 


44,  756 
107, 903 


1, 994,  962 


243,  808 
129,  224 


136,  780 


346, 745 
119, 167 


1,  623,  721 


413,  682 


53,  377 


Sales 


Quantity 


Pounds 


283, 6S2 


15,951 
345,  525 


126,  604 


423,  634 


76,  833 

12, 125 

1,  272,  777 


250, 031 


23,  56S 


102,  756 
141,  748 
104, 902 


90,  078 


1, 838, 149 


128,  276 
"  120,"  423 


368, 1S4 
95, 427 


1,  494, 496 


422, 063 


51, 176 


Value 


$116, 967 


14,  245 
137,  360 


55,  08U 


22:i,s.;s 


15.  347 

6.426 

342, 241 


72,8(19 


20, 034 


50.  25fi 
73.  553 
52, 007 


40,  589 


520, 013 


66,  558 
"63,"  509 


210, 755 
67,  493 


597, 842 


308,  375 


29,  562 


22                                 UNITED    STATES    TARIFF    COMMISSION 
Table  8. — Coal-tar  dyes:  United  Slates  production  and  sales,  by  types 

1937— 

Con. 

Col- 

Name  of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Index 
No. 

Quantity 

Value 

Unit  : 

value. 

267 

CLASSIFIED  DYES— Continued 
Azo  Dyes — Continued 
disazo  dyes — continued 

64.  X 

Pounds 

Pounds 

274 

5,  7,  34,  45,  86 

7,  34,  45,  64,  233 

20,  564 

26. 344 

5,538 

170,  526 

20,  382 

32,810 

496,  501 

$13,  399 

5,  575 

331,  274 

18. 864 

23, 069 

297.  559 

$6.  51 1 
1.01 1 

1.941 

275 

278 

Direct  fast  red  8BL 

5,  7,  34,  64,  86,  148, 

233,  X. 
7,86,  148  

175, 237 

38, 270 

39,  613 

497,  737 

280 

Scarlet  EC    .    

288 

5,86,  148,  X 

5,  64,  86,  148,  X.... 
86 

289 

290 

294 

148 

299 

Chrome  black  F 

45,  64,  86,  148 

302 

Chrome  blue  green  B 

5,64 

304 

Fast  acid  black  N2B 

45,  64,86 

306 

Fast  acid  black  F  .     

86 

307 

5.  64,  86,  148,  X.... 
86 

211,  375 

240,  153 

151,002 

.63 

308 

316 

Developed  blue  NA 

7,  64,  86,  148 

317 

Developed  blue  B 

64,86,  148 

319 

64,86 

324 

Developed  brilliant  orange  OR 

Diamine  brilliant  violet  B 

64,86,  171 

325 

86 

326 

45,  64,  86,  148,  X... 
45,86 

534, 467 

531, 103 

541,  686 

1.02 

327 

Direct  fast  scarlet  4BS 

331 

34,  64,  86,  148 

34,  45,  64,  86,  148... 
7,86 

98,  752 
878,  796 

94,  264 
836,  343 

35,  321 
307, 862 

.37 

.37 

332 

336 

Acid  chrome  black  F 

343 

Chrome  fast  yellow  C 

5 

346 

Direct  fast  vellow  5GL 

64,  86 

353 

Direct  fast  pink  2BL 

5,  64,86,  148 

34,  64,86,  148 

64,86,  148 

23.  530 
208,  369 

19.  581 
196,  691 

33,  567 
147,  510 

1.71 
.75 

364 

Paper  vellow 

365 

Chrvsophenine  G— 

370 

5,  64,  148 

374 

Direct  orange  TA. 

148 

375 

Congo  corinth  G 

5,  7,  34,  64,  86,  148, 

233. 
45,  X 

242,  256 

222,  844 

150, 368 

.67 

376 

Direct  rubine 

382 

Direct  scarlet  B 

7,  34,  45,  86,   148, 

233,  X. 
45 

184, 856 

147, 919 

139,  567 

.94 

385 

Direct  violet. ... 

387 

Direct  violet  B 

45,  64,  148 

394 

34,  45,  64,  86,  148... 
7 

94, 425 

87,  564 

75,  587 

.86 

395 

Developed  black  RO 

401 

Developed  black  BHN 

7,  34,  45,  64, 86,  148, 

233. 
148_ 

2,  563, 481 

2, 329,  965 

762,  645 

.33 

405 

Direct  cvanine  R 

406 

Direct  blue  2B. 

5,  7.  34,  45,  55,  64, 

86,  148,  233. 
64 

1,242,112 

1,223,143 

259, 138 

.21 

409 

Direct  orange  DB 

410 

Chrvsamine  G 

64,  X 

411 

Cresotine  vellow  G 

45,  148,  233 

26, 023 

76,411 

351,  736 

544, 799 

5,105 

11,655 

31,154 

230, 114 

265, 195 

4,695 

.45 

.41 
.65 

.49 

.92 

415 

Direct  orange  R 

45,  64,  86     . 

64, 966 
331,845 

588,  702 

419 

Direct  fast  red  F 

5,  7,  34,  45,  64,  86, 

148,  233. 
5,  7,  34,  45,  64,  86, 

148,  233. 
5,  34,  233     . 

420 

Direct  brown  M. 

423 

Direct  brown  B . 

430 

Polar  red  G 

45,  64,  86,  148,  X, 

X. 
64 

431 

Acid  chrome  red 

436 

Direct  brilliant  red  8B 

45  .. 

441 

Chrome  fast  vellow  RD 

86 

443 

Milling  reVl  2G 

5,  7,  34,  45,  X— 

446 

7,  148 

448 

Benzopurpurine  4B__ 

45,  64,  148 

743,  368 

656, 104 

323,  493 

.49 

464 

Direct  blue  R 

64  .. 

468 

Direct  mauve  B 

148 

471 

Direct  blue  3R 

45,  148 

472 

Direct  blue  BX 

45,64,  148 

7,  45,  55,  64,  148.... 
7,  45,  148     . 

22, 598 
179, 287 

31, 680 
143,  678 

12, 288 
36,  899 

.39 
.26 

477 

Direct  blue  3B 

478 

Direct  orange  G .   

487 

Acid  milling  red  B_. 

7,  34,  86,  171,  X.... 

45,64,  148 

7,45,64,86,148,233. 

40, 981 
34, 003 
90,  619 

38,  532 
29,  673 
117,  699 

31.917 
25.  353 
72.  247 

.83 
.85 

.61 

495 

Benzopurpurine  10B 

502 

Direct  azurine  G 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  23 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Col- 

Name  of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Index 

No. 

Quantity 

Value 

Unit 
value 

508 

CLASSIFIED  DYES— Continued 

Azo  Dyes— Continued 

disazo  dyes — continued 

Direct  brilliant  blue  G 

61 

Pounds 

Pounds 

512 

Direct  blue  IUV       

7,  45,  64,  86,  148.... 
148 ._ 

169.  337 

170.986 

$129, 805 

$0. 76 

515 

Direct  blue  B 

518 

7,  45,  64,  86,  14S 

5,  45,  64,  86,  14S 

64 

566,  826 
87,  643 

525.  216 
91,  757 

401,  631 
46, 160 

76 

520 

TRISAZO  DYES 

50 

533 

Direct  fast  blue  FR 

534 

Naphthogene  blue  4R     

86 

539 

Direct  fast  black  FF 

45,64,86,  148 

544 

Pluto  black  5BS. - 

86 

552 

Diazo  black  RS_ 

64,  148 

561 

7,  64,  86,  148,  171, 

233,  X. 
45 

283, 373 

248,  751 

300,  997 

567 

Direct  fast  blue  R - 

576 

Direct  fast  blue  B 

45,64,  148 

577 

Direct  brown  T2G 

31. 

581 

Direct  black  EW 

7,   34,    45,    64,   86, 

lis.  233. 
34,  45,  64,  86,  148, 

233. 
5,  7,  34,  45,  64,  86, 

118,  233. 
34.  4.r),  64,  86,  148, 

233. 
64.... 

8, 708,  305 
746, 198 
123, 160 
119, 132 

S.  117.  729 
712,  351 
111,690 
88,  270 

2, 165,  764 
199, 790 
42,  361 
30,  805 

26 

582 

Direct  black  RX 

28 

583 

Direct  green  ET 

38 

589 

35 

590 

Direct  steel  blue  G   

593 

5,  7,  34,  45,  64,  86, 
118,  179,233. 

5,  34,  45,  64,   148, 
233. 

86 

762, 754 
96, 809 

721.  351 
101. 772 

238, 404 
42,907 

33 

594 

41 

595 

Direct  olive  G_. 

596 

Direct  brown  3GO„_ _ 

5,  7,  34,  45,  64,  86, 

148,  233. 
7,  45,  64,  88,  148,  X. 
64 _ 

1,111,578 
232,  500 

1,015,305 
230,  454 

322,  979 

HO.  659 

31 

598 

48 

601 

Congo  brown  R_   

606 

Direct  brown  G_   

34,  86,  233.. 

2i.  899 

21.128 

90 

Total  classified  azo  dyes  

38,  708, 193 

37, 151, 678 

15  983.  009 

.43 

Stilbene  Dyes 
Direct  vellow  R 

5,  45,  64,  86,  148.... 
5,  34.  64,  86,  148.... 
34,64,  86 

620 

399.  621 

148.015 
316,  509 

383, 858 
123.  666 
311,961 

117.111 
82,  290 
179, 630 

.38 

621 

Chloramine  orange  G.. 

.67 

622 

Stilbene  vellow 

.58 

628 

Diphenyl  catechine  G 

148 

631 

Pyrazolone  Dyes 
Direct  chrysoine  G.   

45 

636 

Fast  light  yellow  2G 

64,  86,  148,  171 
34,  45,  64,  86,  148, 

171,  X. 
7,  34,  86,  102,  148, 

171. 
86 

64,  552 

64,  096 

64,  799 

1.01 

639 

Fast  light  yellow 

640 

Tartrazine . 

613,018 

648,  505 

435.810 

.67 

651 

Pigment  fast  vellow  G 

652 

Chrome  red  B 

7,    34,   45,    64,   86, 

14S,  X. 
7,  148.  171     . 

653 

35,  195 

654 

Developed  fast  vellow  2G 

64  ._ 

655 

KETONIMINE  DYES 

34,  64,  148,  X 

34,  66,  118 

86,  148 

S54,  665 
294,  339 

830.  800 
275, 130 

730.  020 
300,  973 

.88 

657 

TRIPHENYLMETHANE  AND   DlPHENYL- 
NAPHTHYLMETHANE   DYES 

Mai  ichite  green 

1.09 

658 

Rhodnline  blue  6 G 

662 

34,  66.-. 

663 

86  --. 

666 

Acid  green  B._ 

34,  4.5,  64,  86,  148... 

94,  348 

01,  228 

78,828 

.8 

24 

Table 


UNITED    STATES    TARIFF    COMMISSION 
-Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Col- 

Name  of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Index 
No. 

Quantity 

Value 

Unit 

value 

667 

CLASSIFIED  DYES— Continued 
Tripdenylmethane  and  Diphenyl- 

NAPHTHYLMETHANE   DYES— Contd. 

Fast  acid  green  B.__ 

34,86,  148 

Pounds 

Pounds 

670 

64,  86 

671 

64,  86,  148 

418.151 
20, 364 

438. 179 
19,  080 

$390,  795 
33,  559 

$0. 89 

676 

34,  152,  X 

1.76 

677 

34,  45,  X 

680 

681 

Methyl  violet  and  base 

34,  64,  66,  86,  104, 

148,  X. 
64,  86,  148 

902,  370 

909,  543 

583,  596 

.64 

682 

Ethyl  violet 

Spirit  blue  2B 

64,86.... 

689 

86 

691 

7 

695 

Acid  violet  4BN 

34 

696 

Fast  acid  violet  10B 

64,  X 

698 

45,  64,  86,  148,  X... 
148 

260, 047 

240,  161 

218,  813 

.91 

699 

Acid  fast  vio!et  BG 

Alkali  blue  6B 

703 

86 

705 

152... 

706 

152 

707 

34,  86,  X 

73,  756 

64,  858 

108,  138 

1.67 

712 

86,  148 

714 

86,  148 

720 

64,  86,  148,  X 

86,  148,  X 

75,690 

73,  586 

119,748 

1.63 

722 

724 

64 

728 

64,  86 

729 

64,  86,  148 

735 

64,  148,  X... 

89,517 
127,  231 

737 

34,  64,  86 

136,  746 

70,297 

.51 

Total  triphenylmethane  and  diphenyl- 

3,  507, 379 

3,  270, 668 

3,  662, 097 

1.12 

Xanthene  Dyes 
Rhodamine  B 

64 

749 

749 

Rhodamine  B  cone 

64,  X 

752 

64,  X 

758 

Fast  acid  violet  A2R 

X 

766 

Uranine . - 

7,  34,  102,  152,  181- 
7,  34,  102,  148,  152, 

181. 
7.  34,  102,  115,  152, 

181. 
152     . 

5,629 
56,  636 

341,  893 

4,756 
£5,  092 

329, 100 

8,859 
78,  472 

389,  722 

1.86 

768 

1.42 

768 
772 

Tetrabromofluorescein  (broino  acid) . . . 

1.18 

773 

34  .. 

774 

Phloxine  B 

152... 

777 

152... 

779 

34 

788 

Aceidine  Dyes 

86,  171 

793 

34,  45,  64,  148,  171.. 
171     . 

119,738 

127,  533 

99,  632 

.78 

794 

797 

86,  171  .. 

801 

Quinoline  Dyes 

64,  148,  X. 

112,646 

92,  459 

135,  681 

1.47 

802 

148 

812 

Thiazole  Dyes 

45,  64,  148,  167 

813 

64  . 

814 

64,  86,  148,  167 
64 

365,  660 

337, 165 

296,  722 

.88 

815 

ThioflavineT 

816 

Direct  brilliant  flavine  S 

167 

DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  25 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Name  of  dye 


Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 


Produc- 
tion 


Sales 


Quantity 


Value 


Unit 
value 


CLASSIFIED  DYES— Continued 
Azine  Dyes 


Wool  fast  blue  GL. 

Safranine 

Acid  cyanine  BF 

Induline  (spirit-soluble)... 
Induline  (water-soluble).. 
Nigrosine  (spirit-soluble)- 
Nigrosine  (water-soluble) . 


Aniline  Black  and  Allied  Dyes 


New  fast  gray. 
Fur  black. 


Oxazine  Dyes 


Delphine  blue  B. 

Gallocyanine 

Cotton  blue 

Nile  blue  BX_... 


Total  oxazine  dyes 

Thiazine  Dyes 


Methylene  blue 

Methylene  green  B 

New  methylene  blue.. 
Brilliant  chrome  blue. 


Sulfide  Dyes 


Carbazole  vat  blue  R. 
Carbazole  vat  blue  O. 
Sulfur  black 


Sulfur  blue. . . 
Sulfur  brown. 


Sulfur  green 

Sulfur  maroon. 
Sulfur  olive 


Sulfur  orange. 
Sulfur  tan 


Sulfur  yellow. 


Total  sulfide  dyes 

Anthraquinone  Dyes 


Alizarin 

Alizarin  red  S 

Alizarin  brown 

Alizarin  GI. 

Alizarin  SX 

Pseudopurpurine 

Acid  alizarin  blue  SE 

Acid  alizarin  blue  B 

Anthracene  blue  SWGG. 

Anthracene  blue  WR 

Anthracene  blue  WRS... 

Alizarin  irisol  R.. 

Alizarin  astrol  B 

Cyananthrol  R... 

Alizarin  cyanine  green  E. 


Acid  anthraquinine  violet  B. 
Anthraquinone  blue  black  B. 


8fi,  148,  X. 
34,  64,  148. 
64 

34,  86,  148. 
34,  86,  148. 
?4,  86,  148. 
34,  86,  148. 


Pounds 
111,822 
281, 891 


Pounds 
79, 434 


$117, 400 


68, 969 


76,728 


35,  210 


1,  353,  733 
1,  302, 479 


1,265,679 
1,  335, 135 


350,  940 
478,  851 


Diphenyl  black  base 86 


34,64,171. 
34,86 


5,957 


148 

34,234... 

7,  34,  148. 


103, 810 


109, 899 


148.  219 


34,  64,  66,  86,  148. 

34 

34 


64,86 

64,86.... 

20,  34,  64,  86,  148, 

202. 
5,  20,  34,  45,  64,  86, 

109.  148. 
20.  34,  45,  56,  64, 86, 

109,  148,  202. 
5,34,64,86,109,148. 
5,34,64,86,148.... 
20,  34,  56,  64,  86, 

148,  202. 

45,  64.  86,  148 

5,  20,  34,  45,  56,  64, 

86,  109. 
5,  20,  34,  45,  56,  64, 

86,  109,  148,  202. 


0) 

0) 

13, 614,  708 

2,  473, 340 

2,  536, 841 

250, 138 
926,  442 
147,  299 

49,  330 
269,  224 

261,  220 


0) 

0) 

14, 304, 516 

2, 120,  099 

2, 352,  613 

232,  320 

780,  271 
129,  821 

51,  653 
237,  035 

246,  901 


2,  317,  965 

877, 853 

654,  337 

160, 831 
376,  729 
37, 444 

18,282 
69,  327 

96,  390 


20,  528,  542 


20,  455,  232 


4,  609, 158 


34,  148.... 
7,  34,  148. 
148.  234... 

64 

148. 


49,  503         46,  846 


86... 

64,86,  X 

64,86,  148,  234,  X. 

16,  X 

86,  X... 

16 


76,  940 


429, 614 


7,  16,  64. 
64,  86.... 
64. 


3,876 


5,7,  16,64,86,  148, 

234,  X. 

16,64 

7,   16,  64,  86,  148, 

231,  X. 


115,268 


156,  917 


30,  613 
465,  289 


61,  264 
772, 071 


7,035 


19, 860 


111,227 


222, 652 


165, 863 


249,  795 


1  Totals  not  included  under  sulfide  dyes.    In  the  dyes  classified  by  method  of  application  these  2  dyes 
are  included  in  the  vat  dyes. 


26  UNITED    STATES    TARIFF    COMMISSION 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Col- 

Name of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

our 

Inde> 
No. 

Quantity 

Value 

Unit 
value 

CLASSIFIED  DYES— Continued 
Anthraquinone  Dyes— Continued 
Acid  anthraquinone  blue  B__ 

64,  86,  148. 

Pounds 
44,814 

Pounds 
40,912 

$130, 947 

$3.20 

64,  86 

1,  270, 982 

1,  385,  654 

1, 988,  878 

1.44 

Anthraquinone  Vat  Dyes  (single 
strength) 

Anthraquinone  vat  yellow  GC  (12V£%). 
Anthraquinone  vat  golden  oiange  G 

(12^%)- 
Anthraquinone  vat  golden  orange  R 

(12M%). 

Anthraquinone  vat  scarlet.  GS  (16%%). 
Anthraquinone  vat  dark  blue  BO  (25%). 

Anthraquinone  vat  jade  green  (6%) 

Anthraquinone  vat  green  B  and  black 
B  (12'..',). 

Anthraciuinone  vat  violet  R  (25%) 

Anthraquinone  vat  violet  RK  (12J  2%)  — 

Anthraquinone  vat  violet  15  (25%) 

Anthraquinone  vat  blue  RS  (10%) 

Anthranuinone  vat  blue  3G  (10%)  

Anthraquinone  vat  blue  G  C  D  (834%)  -  - 

Anthraquinone  vat  blue  BCS  (20%) 

Anthraquinone  vat  yellow  G  (123/2%)___ 

Anthraquinone  vat  brown  B  (22%) 

Anthraquinone  vat  pink  R  (12H%)  

Anthraquinone  vat  yellow  R  (123/2%)-- . 
Anthraquinone    vat    red    FF,    extra 

(12H%)- 

Anthraquinone  vat  brilliant  violet  2B 

(123  2%). 
Anthraquinone  vat  brilliant  violet  R 

(12H%)- 

Anthraquinone  vat  olive  R  (123 2%) 

Anthraquinone  vat  brown  R  (12'   '  , 
Anthraquinone  vat  brown  G  (1. 
Anthraquinone  vat  red  violet  RRN 

(12.1  ..  ,    . 
Anthraquinone    vat    red    BN,    extra 

(12.',',  1. 
Anthraquinone  vat  violet  BX  (25' 
Anthraquinone  vatorange  R  (123 
Anthraquinone  vat  yellow  R  (1232%)--- 
Anthraqujnone    vat    blue    green    B 

(1232%). 

Indigoid  and  Thioinpigoid  Dyes 
Indigo,  synthetic  (20%) 

34,  64,  86,  167. 

34,  64,  86,  148 

34,  64,  148 

1095 
1096 

1097 

798,  028 
199,  751 

793,  224 
167, 067 

883,  806 
225,  089 

1.11 
1.35 

1098 

86,  148 

1099 
1101 

34,64,86,  148,  167.  . 
64 

174, 231 

165,  504 

191, 989 

1.16 

34,64,86,148,167.. 

1103 

86 

1104 

7,64.86,148 

86 

218.401 

1105 

1106 

64,86 

1109 

64 

1113 
1114 

7,64,86,148 

7,64,86,148 

818,911 

769,  267 
802. 884 

445,  446 
860,  773 

.58 
1.07 

1118 

64,86, 14S 

1120 

64 

1128 

86 

1132 

64 

1133 

64 

1134 

61 

1135 

64  

1150 

64,86,148 

1151 

64,86,  148 

:::::::::::: 

1152 

64,  148 

1161 

64,86 

1162 

64,148 

1163 

64 

1169 

64  ..         

1170 

64 

1173 

148 

1177 

62,  64,  148 

18, 416, 903 

17,  790, 949 

2,  965,  248 

.17 

1178 

Indigo  white  (20%) 

148 

1180 

64,  148 

1183 

Tribron.indigo  RB  (20%) 

62,  148 

1184 

Bromindigo  blue  2BD  (16%) 

62,  86,  148 

11S9 

Brilliant  indigo  40  (20%) 

64 

1210 

Y:,t  red  B  (123 

86 

1212 

Vat  red  3B  (20%)... 

62.64,86,148 

34.64,86,  148.X... 
62 

76,  366 
605, 131 

82, 772 
553, 075 

114,584 
641,851 

1.38 

1217 

Vat  orange  R  (10%) 

1.16 

1222 

Vat  violet  B  (10%1.   ... 

1228 

Vat  fast  scarlet  G  (20%) 

62 

1229 

Vat  red  R  (10%) 

62 

22 

Food  Dyes 
Yellow  AB.. 

67,  148 

61 

Yellow  OB 

67,  148    

80 

23,  148,  207 

150 

Orange  I 

23,123,148,207,227. 
23,123.  148,207,227. 
23,  123,  148,  207.... 
23,  148,  227   

90,  265 
114,720 
102, 409 

86,  684 
108,  230 
97,066 

191,517 
262,  7S5 
241. 105 

2.21 

184 

2.43 

640 

Tartrazine _  

2.  4S 

666 

670 

23,  148,  227  . 

773 

Erythrosine 

23,  123,  148,  207.... 
23,  123,  207 

6,878 

7,182 

100, 117 

13.94 

1180 

Brilliant  blue  FCF 

23,  148,  227 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  27 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Col- 
our 
Index 
No. 


Name  of  dye 


CLASSIFIED  DYES— Continued 
Food  Dyes— Continued 


Fast  green  FCF 

Ponceau  SX 

Sunset  yellow  FCF. 


Total  food  dyes 

Total  classified  dyes 

UNCLASSIFIED  DYES 


Acetate  silk  dyes,  total 

Amacel  blue  GG,  GR 

Black  (B,  BDN,  J,  JN,  W,  III, 

IV,  IVdbl.). 
Blue  (BB,  B  cone,  G,  3G,  R,  5RB 

cone.  Ill,  IV,  XIII,  XIII  dbl.). 

Bordeaux 

Brilliant  blue  (B,  FFG,  2G) 

Brilliant  orange 

Brilliant  red 

Brilliant  yellow  (W) 

Brown  (BR,  Y) 

Cellitazole  (AZ,  BNS,  BZ,  NAZ, 

NBZ,  NS,  NZD.  NSJ,  STN). 
Developed  black  (AD,  AS,  BAM, 

GA,  GD,  GN,  S.T). 

Developed  navy  blue  (RD) 

Developed  red  3B 

Developed  sapphire  blue  G 

Direct  blue  S 

Direct  orange  R 

Direct  red  YC 

Fast  black  (B,  BTN) 

Fast  blue  (AF,  B,  FFR,  2RA) 

Fast  blue  green  B 

Fast  brown  (3R,  5R) 

Fast  light  yellow 

Fast  navy  blue  (B,  BR) 

Fast  orange  2R  supra 

Fast  pink  B 

Fast  red  2G 

Fast  red  violet  RN 

Fast  rubine  B 

Fast  violet  (B,  6B,  6BA) 

Fast  yellow  (G,  GL,  GR,  RR)__. 

Golden  orange  (I,  III) 

Golden  yellow  (F,  FSI,  VIII,  VIII 

cone, 'IX,  XI,  XII,  XIII). 

Green  BS 

Green  blue  II 

Heliotrope  I 

Light  orange  FSI 

Navy   blue    (B,    BN   cone,    BP 

cone,  BX,  CBR  cone,  R). 
Orange    (GF   cone,    GFN,    GR, 

JER,   RR,   3RC,   I,   II,   III,   4, 

extra) . 

Pink  II 

Pure  blue  (BR,  BR  cone.) 

Pure  yellow  (I,  II) 

Purple 

Red    (BR,   BY,   3B,   2BC,   DM, 

FSI,  R,  RP,  Y,  YR,  I,  III,  V, 

VI-X,  VII,  VIII). 

Red  violet  R 

Rubme  (B,  IX) 

Sapphire  blue  2G --- 

Scarlet  (B,  BN,  BR,  III,  III  cone) 

Skvblue  (B,  G,  GA) 

Violet  (CB,  RR,  II) 

Violet  blue  FSI 

Yellow  (C,  G,  GC,  GG,  GX,  5G). 


Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 


SZl 

148,  227 

123,  148,  207,  227- 


86097—38- 


5,7,34,64,80,233. 
7,64,86,  X 


5 

5,  64,  173. 

173 

64,  173.... 

5,  173 

64 

S6 


5,  34,  64,  X,  X. 


5,64. 
X... 

X... 

5--- 
X... 
34... 


86,  X. 


3,  X. 


7— 

5,7. 


64 

7. 
7- 
7_ 
7,34 

5,7, 
X 


Produc- 
tion 


Pounds 


37,  3G8 


425  272 


104,499,596 


2, 191, 881 


372,211 


273,  571 


Sales 


Quantity 


Pounds 


34, 942 


405, 104 


101,585,568 


2,  099,  587 


441, 645 


282, 939 


,64 

34,  64,  86,  233, 


7 

64 

7 

64 

5,  7,  34,  64,  ! 


64 

7,64 

34 

5,  7,  34,  64,  80,  86. 
5,  64,  X 

7,64.— 


5,  7,  34,  64,  80,  86. . 


112,36" 


21,  484 


Value 


Unit 
value 


$82, 16; 


1,160,244 


45, 452,  524 


2,  314,  350 


292, 651 


214, 468 


94, 349 


$2.35 


2.86 
.45 


1.10 


.66 


.76 


74, 827 


40,912|        43,832         61,157      1.40 


28  UNITED    STATES    TARIFF    COMMISSION 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1987 — Con. 


Col- 

Name of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

our 
Index 
No. 

Quantity 

Value 

Unit 
value 

UNCLASSIFIED  DYES— Con. 

234... 

Pounds 

Pounds 

86 

Acid  anthracene  yellow  GR  extra 

Acid  anthraquinone  blue  (BGA,  3G, 

SBS,  SWB,  WSA). 
Acid  black  (AR,  BR  supra,  8B,  8BN, 

GRF,  GRF  cone,  3G,  J,  NBJ,  RB. 

TL,  640,  773). 
Acid  blue  (D,  2G)  .  - -- 

X 

64 

5,  7,  34,  55,  64,  86, 
148. 

171.X 

77,828 

X 

Acid  brilliant  blue  (3B,  RR) 

7,  64.... 

64 

Acid  brilliant  red  (BBA,  5B,  G,  4BL). 
Acid  brown  (FN,  MF,  N,  R) 

7,64.  148.X 

34,  171 

34 

45 

45,86. 

Acid  fast  black  (BBN,  WAN).. ._ 

64.86 

Acid  fast  blue  (B,  G,  IB,  NB) 

64,  148 

64 

7 

34,64 

7,  34 

179 

179 

171,  179 

64. 

86 

7 

34 

45.. 

Acid  milling  yellow  (G,  2GX,  R) 

34,  45,  171 

45 

Acid  navy  blue  (cone,  B,  B  cone,  M, 
M4B). 

7,  34,  45,  64,  233... _ 
7 

15,  467 

14,  607 

$8,  586 

$0.59 

34 

Acid  orange  (OS,  R,  2R,  4R,  YF) 

Acid  red   (B  3B,  OA)   -_. — 

34,  171,  X 

45,  171 

X 

171 

34 

34 

Acid  violet  (B,  BS,  RL,  2R,  2RX) 

34.  45,  171,  179 

64 

34,  45,  171 

148 

Alizarin  direct  blue  (AR,  A2G) 

86                       

148... 

86  .. 

7 

86  . 

148     . 

Anthracene  chromate  brown  EBS  cone 

X  .. 

234 

86 

Anthraquinone  vat  black  (J,  R) 

Anthraquinone  vat  blue  (CLX,  RCX). 
Anthraquinone  vat  blue  green  (FFB, 

Y). 
Anthraquinone  vat  brilliant  green  BN.. 
Anthraquinone    vat    brilliant    orange 

(GR,  RK). 
Anthraquinone    vat    brilliant    scarlet 

BGN. 
Anthraquinone  vat  brilliant  yellow  4G 
Anthraquinone  vat  brown   (BR,   G, 

RR,  VR). 
Anthraquinone  vat  dark  brown  (R, 

RG,  RT). 

Anthraquinone  vat  deep  black  BD 

Anthraquinone  vat  direct  black  3G 

Anthraquinone  vat  flavine  GC ... 

Anthraquinone  vat  golden  orange  3G__ 
Anthraquinone  vat  golden  yellow  (GK, 

GOW). 

Anthraquinone  vat  green  IBW 

Anthraquinone  vat  khaki  (GG) 

34,  148 

64 

64,  86    - 

86 

86 

86 

64 

64,  86    . 

64,86 

86 

64 

148 

DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  29 

Table  8. — Coal-tar  dyes:  United.  States  production  and  sales,  by  types,  1937 — Con. 


Col- 

Name of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

our 
Index 
No. 

Quantity 

Value 

Unit 
value 

UNCLASSIFIED  DYES— Con. 

Anthraquinone  vat  navy  blue  (BN, 
G,  3G). 

7,34,64,86-. 

64     

Pounds 
190, 806 

Pounds 
167,  326 

$164,  255 

$0.98 

Anthraquinone  vat  olive  green  B 

86               

64 

Anthraquinone  vat  printing  black  (B 

suprafix,  TL). 
Anthraquinone  vat  printing  green  BQ 

suprafix. 

86 

86 -- 

64  -- - 

Anthraquinone  vat  scarlet  (3B,  GGN). 
Anthraquinone  vat  violet  FFBN 

86      

86 

64     

Artificial  silk  black  (G,  R,  RR) 

45,  86 

171     

64 

148     

86 

148 

86 - 

148    

171     -.          

Azo  red  (7BL  F) 

5,  171.. 

171        

Azoic  dyes  and  their  components,  total. 
Dyes: 

Rapid  fast: 

2,  699, 643 

2, 391,  318 

4, 168,  537 

1.74 

34 

64,86 

Red  GZH 

86        

Red  RH 

64,  86 

34 

Scarlet  ILH 

64,  86    

Rapidogene: 
Black  DM 

64        

Black  MG 

86    .     

86     

Blue 

171  

Blue  BN,  D.  N 

86      

Blue  GN,  GNN,  R 

64,  86 

171 

86 

171  .. 

Brown  GN,  IB,  IPT 

86    

64 

86 

86     . 

171 

64,  86 

86 

Red 

171  .. 

Red  GH,  GS 

86     . 

Red  G,  M2B,  R 

64              

Scarlet  RS 

86    . 

171  .. 

Yellow  G 

Yellow  G,  GO,  OS,  GGN. 
Components: 

Fast  color  salts: 
Black  salt  B 

86 

Blue  salt  B,  BB 

Blue  salt  BN 

Oransre  salt  GC 

Red  salt  AL,  B 

Red  salt  O,  3G.  TR 

Red  salt  GL,  3GL 

148                   

Scarlet  salt  GG 

Yariamine  blue  salt  BD 

Naphthols: 

Naphthol  AS 

86              

7,34,  86,  148 

Naphthol  AS,  BO 

Naphthol  AS,  BR 

7,  86 

Naphthol  AS   BS 

7,  64,  86,  148 

Naphthol  AS,  D 

30  UNITED    STATES    TARIFF    COMMISSION 

Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Name  of  dye 


UNCLASSIFIED  DYES— Contd. 

Azoic  dyes  and  their  components— Con. 
Components— Continued. 
Naphthols— Continued. 

NaphtholAS,  OL 

NaphtholAS,  OP 

NaphtholAS,  PH 

Naphthol  AS,  RL 

NaphtholAS,  SW 

Brilliant  benzo  violet  B 

Brilliant  milling  blue  B 

Brilliant  milling  green  B  cone 

Brilliant  milling  yellow  5G 

Brilliant  wool  blue  (FFR.  FRS  special, 

G  extra,  N). 

Chromate  blue  black  B 

Chromate  brilliant  brown  RL 

Chromate  brown,  (EB,  EBR) 

Chromate  red  2G 

Chrome  black  (3G,  NSE,  P2B,  PV, 

SW). 

Chrome  blue  (ATX,  ECR) 

Chrome  brilliant  orange  2R 

Chrome  brown  (B,  BC,  BS,  3B,  EB, 

EBL,  G,  O,  PG,  RH,  RH  cone). 

Chrome  fast  garnet  R 

Chrome  garnet  R 

Chrome  gray  DG 

Chrome  green  (B,  CB,  G) 

Chrome  orange  3R 

Chrome  yellow  (DS,  2G,  3G,  5G,  SW). 

Ciba  black 

Cloth  red  2R 

Cotton  black  3G 

Croceine  scarlet  FP  cone 

Developed  black   (G,    OB,   OT,   ZV 

cone). 
Developed  blue  (B,  BR,  BR  cone,  6G, 

5GL). 
Developed    Bordeaux   (2BL,   7B,    7B 

cone,  RB). 

Developed  brilliant  green  3G_. 

Developed  brilliant  orange  (G,  GG)._. 
Developed  brilliant  scarlet  (2BL,  2BL 

extra,  5BL,  RO). 
Developed  brown  (6G,  NR,  R,  3RB)... 

Developed  dark  brown  B 

Developed  fast  blue  (B,  2RW) 

Developed  fast  Bordeaux  2BL 

Developed  fast  brown  RK 

Developed  fast  red  7BL 

Developed  fast  rubine  B 

Developed  fast  violet  (BL,  2RL) 

Developed  fast  vellow  2G 

Developed  green  (BL,  2GL,  GW) 

Developed  indigo  blue  (BRR,  4GD... 
Developed  orange  (GR,  R,  RR,  RFW, 

WD). 

Developed  red  (BFW,  7BL) 

Developed  rubine  B 

Developed  scarlet  (A,  FW,  GFW,  R)_. 

Developed  sky  blue  (B,  3GL) 

Developed  violet  (BRD,  RR) 

Diamond  green  SS 

Diazaphen  red 

Diazaphen  vellow 

Direct   black    (G,   3G,   3GR,   NCW; 

CSW). 

Direct  blue  (B,  FF.  G,  NR). 

Direct  blue  green  CW 

Direct  Bordeaux  (B,  6B) 

Direct  brilliant  blue  BFL 

Direct  brilliant  cerise 

Direct  brilliant  red  (12B,  12B  cone)... 

Direct,  brilliant  violet  (4B,  R) 

Direcl    brown    (CSW,    CWR,    FW, 

GB,  G2R,  G3R,  k,  K.  RY,  S). 
i  >irecl  eatechine  (FF,  GS,  Gconc.,3G). 

Direct,  chrome  black  blue  B 

Direct  chrome  blue  black  B 


Manufacturers8 
identification  num- 
bers  according  to 
list  on  p.  54) 


86,  171. 
171 


Produc- 
tion 


Pounds 


7,  86 

7,  86,  148. 

64 

64,  86 

64 

7 

86,  148 


45 

X 

5,  34,  64,  234. 

234 

64,  148,  X... 


5,  7,  34,  45,  64, 

148. 
45 


X 

148 

45,  148 

148 

5,  34,  45,  64,  148.... 

62.... 

148 

34 

148 

7,  45,  64,  86,  148.... 


45,  64,  148,  X. 
7,  64,  86,  148- 


14,  803 


86 

64,  86,  X. 


64,  86. 
X 

45 


64 

64,  X.. 
X 

64,  X._ 

86,  148. 

64 

64,  86.. 
04,  148. 

64,  148. 

86 

64,  148. 

86 

7,  64.... 


31 

34 

5,  45,  86,  148,  X. 


5,  64,  148. 

148 

7,  86,  148. 

148 

5—. 


5,  148 

7 

5,  45,  55,  148,  233, 
X. 

7,64,148 

X 

86,  148 


76, 880 


283,419 


93, 817 


109,116 


111.273 


136,  983 
280,  978 


Sales 


Quantity     Value 


Pounds 


90,  209 


9,371 


72,  296 


253,  455 


172,201 
93, 620 


108,  382 


131, 


\  lis 


5.800 


30,  631 


158, 951 


87, 127 
83, 120 


80,  871) 


77, 160 


Unit 
value 


$0.76 


.  62 


.51 
.89 
"."75 


.59 


DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  31 

Table  8. — Coal~tar  dyes:  United  States  production  and  sales,  by  types,  1937 — Con. 


Col- 

Name of  dye 

Manufacturers' 
identification  num- 
bers  according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

our 
index 

No. 

Quantity 

Value 

Unit 

value 

UNCLASSIFIED  DYES— Contd. 
Direct  copper  blue  (RR,  RRX) 

64,  86 -. 

Pounds 

Pounds 

X 

Direct  fast  black,  (B,  FOR,  FTC,  G,  L, 

Lconc,  PG  extra,  VE). 
Direct  fast  blue  (FF,  2GL,  4GL,  8GL, 

LBR,  LG,  R,  RL,  SRL). 
Direct  fast  brown  (BRL,  4GL,  LBR, 

l.<  '.  L3R,  R,  4R,  2RL,  4RL,  3YL). 
Direct  fust  gray  (BL,  GL,  2GL,  R) 
Direct  fast  light  blue  FF 

7,  45,  64,  86,   148, 

233,  X. 
45,  64,  86,  148 

64,  86,  148,  X 

64,  86,  148 

569,  752 
346,  864 
147, 143 

559,  063 
321,  321 

117,958 

$371, 860 
368,  219 
180, 734 

$0.67 
1.15 
1.53 

45 

Direct  fast  orange  (EG,  ER,  E3G,  G, 
2G  cone,  2GL,  4G  cone,  L3R,  L5G, 
L7G,  R,  RE,  2R,  6R,  7R,  S). 

Direct  fast  red  (5BL,  8BLN,  8BLSW).. 

34,  45,  64,  86,  109, 
148,  X. 

45,  148,  X     

292,  480 

243, 401 

278,  629 

1.14 

148 

Direct  fast  violet  (BB,  F) 

5,  86 

Direct  fast  yellow   (GA  extra,  4GL, 
5GL,  LR,  L5G,  RL). 

5,45,64,86,148 

45 

167, 048 

155,  576 

246, 813 

1.59 

Direct  gray  (BBC   BL,  G,  Z) 

55,  148,  X 

Direct  green  (54FS,  5G,  2Y) 

5,  64.. 

45- 

45 

Direct  navy  blue  (BF,  B\V,  4B,  DB, 

R,  RY). 
Direct  orange  (B   GL,  D2R) 

5,  34,  64,  148,  233, 

X. 
86,  148,  X   

111,  133 

Direct  red  (B  3B   G) 

5,  45 

34 

64... 

X 

86      

148     

Direct  vioiet  (2B,  2R) 

5,  148 -._ 

45       

64     

Fast  acid  black  BR 

86 

Fast  acid  blue  (R,  WF) 

86,  148 

86     - 

148 

45 

Fast  acid  red  (3B,  GG) 

86          

Fast  acid  violet  (ERR  extra,  VR) 

64,  171 

86        

Fast  black  V 

64 

148 

Fast  light  red  (B,  4B) 

86 

Fast  silk  vellow  G 

5 

Fast  wool  red  (BL,  GL) 

148 

148          

148 

64 

64 

Fluorol  5G 

86                  ;-- 

45 

X 

34 

64,  86    . 

Heliored  RMT 

86 

86 

167 

5 

34,  148,  X 

175,  301 
466,  502 

173,955 
410, 848 

179,  250 
498, 132 

1.03 

Indigo  vat  pink  (FB,  FF) 

34.  64,  148,  X 

1.21 

86 

181 

Jet  black  APX 

64 

Lake  blue  (G,  6G) 

64     . 

64 

64 

64 

Lake  red  2B 

64     . 

Lake  scarlet  2YL 

64 

34 

'  Milling  fast  garnet  R 

UNITED    STATES    TARIFF    COMMISSION 


Table  8. — Coal-tar  dyes:  United  States  production  and  sales,  by  types,  1987 — Con. 


Col- 

Name  of  dye 

Manufacturers' 
identification  num- 
bers (according  to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Index 
No. 

Quantity 

Value 

Unit 
value 

UNCLASSIFIED  DYES— Contd. 

X 

Pounds 

Pounds 

148 

64,  148 --- 

148 

Milling  yellow  (GN,  3G,  2GCW,  0 
cone,  XN). 

64,  148,  171   .   

64 

5 

86  ..     

64     . 

Neutral  brown  (RD,  2RS)~ 

5,64,148     

5          

Nigrosine  base  (B,  N,  R,  2R). 

148  .              

Oil  black           

181 

Oil  blue  (116R)     

181,234     

64 

Oil  brown  (D,  M,  Y,  #79,  #102) 

80,  148    . 

148 

Oil  fast  blue  B    .     

148 

148 

Oil  fast  red  (M,  Y)         

148 

Oil  fast  vellow  (EG,  3G) 

64,  148.. - 

234 

Oil  orange  (0,  2R,  #30,  #67) 

34,55,80,148,231.. 
148 -- 

55, 805 

47,  725 

$42, 496 

$0.89 

Oil  pink  B 

Oil  red  (EG,  EGN,  G,  I  1471,  N  1700, 
O,  OB,  RO,  #322). 

7,  34,  55,  80,  148, 

231. 
234      

75, 842 

90, 067 

82, 449 

.92 

Oil  vellow  (N,  PHW) - 

34,64 -. 

55                -- 

86                

148                

Pigment  ruhine  (O,  3G) 

86                

X 

Rayon  dyes: 

Black  B          - 

64              -. 

Black  GDW - 

80                   

Blue  BB           

80                

Bordeaux  B,  3B   

64 

64 

Brown  RB     

80 

64 

Violet3B         -.- -- 

64 

148 

148 

148     . 

45,  55      . 

64 

64 

64 

148 

Silk  black  (4BF,  G) 

45 

Silk  blue  10G            

64 

Silk  brown  (B,  G,  R) 

45,  X 

Silk  fast  blue  3G - 

64 

Silk  red  (2B,  4B,  10B) 

45,  X.  . 

Stilbene  brown  3GLX 

34 

34 

85 

Sudan  orange  (IT,  RT) 

86 

Sudan  red  4B 

86 

86 

86 

86 

86 

Vat  blue  BR 

62 

Wool  blue  (CG,  CGG)__. 

148 

148 

Zambesi  black  (B,  D,  G,  PC,  V) 

45,  86,  148   -- 

64,  X,  X 

Total  unclassified  dyes 

17,744,983 

16, 460, 559 

19, 160,  390 

1.16 

Total  dyes: 

Those  for  which  individual  sta- 
tistics are  shown. 

Those  for  which  individual  sta- 
tistics cannot  be  shown. 

88,  810. 983 
33, 433, 596 

85,  531, 022 
32,515,105 

34.661,513 
29, 951, 401 

.41 

.92 

122.2-»4.f>79 

118046.127 

34  R12  914 

55 

DYES   AND    OTHER   SYNTHETIC    ORGANIC    CHEMICALS  33 

PRODUCTION  AND   SALES  OF  DYES  BY  CLASSES  OF  APPLICATION 

Table  9  compares  the  production  and  sales  of  dyes  by  classes  of 
application,  in  1937  and  1936,  with  the  average  for  the  period  1925-30. 


Table  9. 


-Comparison  of  United  States  production  and  sales  of  dyes,  by  classes  of 
application,  1925-30,  1936,  and  1937 


Production 

Class  of  application 

Quantity 

Percent  of  total 

1925-30 
average 

1936 

1937 

1925-30 
average 

1936 

1937 

Pounds 

(') 

11,813,941 

(2) 

4, 833, 382 

17,983,751 

1, 947, 124 

3,611,608 

20,  004, 635 

33, 221, 072 

27, 128,  311 

6,092,761 

587, 657 

Pounds 
2,  389, 885 
15, 974, 423 

(2) 

5,  727,  303 

*  29,907,  029 

2,  722, 807 

6,639,112 

20,  717,  289 

34,449,513 

18. 039, 419 

16, 410, 094 

995, 185 

Pounds 

2,191,881 

15,  343. 304 

32,699,643 

5,  775,  239 

30,  595,  183 

3, 157, 406 

6, 192, 888 

20,  528,  542 

34, 501, 413 

18, 416, 903 

16,084,510 

1, 259, 080 

2.00 
13.38 

1.79 

12.57 

12.  55 

2.21 

5.14 
19.13 
2.07 
3.84 

21.28 

4.79 
25.02 
2.28 
5.55 
17.33 

4.73 

25.03 

2.58 

5.07 

Sulfur 

16.79 

Vat,  total  -.- 

28.86 

6.48 

.63 

15.09 

13.73 

.83 

15.06 

(6)  Other --- - 

13.  16 

Unclassified.- 

1.03 

Total. 

94, 003, 170 

119,523,146 

122,  244,  579 

100.  00 

100.  00 

100. 00 

Sales 

Quantity 

Percent  of  total 

Pounds 

(') 
11,699,667 

(2) 

4, 709, 926 

17,  5S0, 927 

1,896,821 

3,  55S,  732 

19,810,565 

32, 429, 018 

27,  111,  575 

5,  317, 443 

521, 625 

Pcunds 
1, 943,  406 

15,  528, 825 

(2) 

5, 465, 227 

• 29,495,  273 

2, 624, 777 

6, 234, 937 

20,812,369 

34,  557, 262 

17, 848, 853 

16,  708, 409 
910,  747 

Pounds 

2, 099,  587 

14,911,413 

3  2,391,318 

5, 433, 966 

29, 152, 360 

2, 949, 908 

6, 008, 996 

20, 455, 232 

33,  406,  528 

17,  790, 949 

15, 615,  579 

1,236,819 

1.65 
13.21 

1.78 

12.69 

12.63 

2.03 

5.11 
19.07 
2.06 
3.86 
21.48 

4.65 
25.09 
2.23 
5.31 
17.70 

4.60 

Direct - 

24.69 

2.50 

5.09 

Sulfur  

17.33 

Vat,  total 

29.40 

5.77 
.56 

15.18 

14.21 

.77 

15.07 

(6)  Other. 

13.23 

1.05 

Total 

92,  207, 281 

117,572,823 

118,046,127 

100. 00 

100.  00 

100. 00 

Sales 

Value 

Percent  of  total 

0) 
$8, 651,  526 

(2) 
3, 977, 258 
9, 076, 783 
1, 681, 736 
2, 212,  390 
3, 928, 982 
9,114,973 
3,  741,  314 
5,  373, 659 
784, 604 

$2, 473,  296 
11,933,721 

(?) 

4, 905,  755 

« 17,497,  791 

1,714,916 

3,116,262 

4, 635,  256 

16,  611, 526 

?,  889, 105 

13,  722, 421 

797, 034 

$2, 314,  350 
11,461,325 
3  4, 168,  537 
5, 059, 983 
15,138,355 
1, 853, 690 
2, 880, 527 
4,  609, 158 
16,075,211 
2, 965,  248 
13, 109, 963 
1, 051, 778 

3.88 
18.74 

3.58 

Acid— 

21.94 

17.74 

6.45 

Basic -. 

10.09 
23.02 
4.27 
5.61 
9.96 

7.70 

27.48 

2.69 

4.89 

7.28 

7.83 

Direct - 

23.43 

2.87 

4.46 

Sulfur 

7.13 

Vat,  total 

(a)  Indigo 

9.49 
13.63 
1.99 

4.54 

21.55 

1.25 

4.59 

(6)  Other. 

20.29 

Unclassified 

1.63 

Total 

39,  428,  252 

63, 685,  557 

64,612,914 

Kin.  (id 

100. 00 

100. 00 

1  Not  shown  separately  during  1925-30. 
'  Not  shown  separately  prior  to  1937.    . 

« Includes  azoic  dyes  (rapid  fast  and  rapidogene  dyes)   and  their  components  (fast  color  salts   and 
naphthol  AS  derivatives). 
•  Includes  rapid  fast  dyes  and  rapidogene  dyes. 


34 


UNITED    STATES    TARIFF    COMMISSION 


COLOR  LAKES  AND  TONERS 

The  50  domestic  makers  of  color  lakes  and  toners  report  an  output 
of  18,041,000  pounds,  with  sales  of  15,263,000  pounds,  valued  at 
$11,812,000,  or  an  average  of  77  cents  per  pound.  This  activity  is 
an  increase  of  17.5  percent  in  production,  12  percent  in  sales  quantity, 
and  16  percent  in  sales  value  over  the  preceding  year. 

Toners  or  full  strength  colors  are  the  most  important  class  of  this 
group,  followed  by  lakes  and  extended  colors,  and  by  reduced  toners. 

Table  10  shows  production  and  sales  of  color  lakes  and  toners  in 
1937. 

Table  10. — Color  lakes  and  toners:  United  States  production  and  sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  num- 
ber with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  sta- 
tistics of  production  or  sales  cannot  be  published  without  revealing  information  with  regard  to  individual 
firms.    The  figures  thus  concealed  are,  however,  included  in  the  total] 


Name  of  product 


LAKES  AND  EXTENDED 
COLORS 

Alizarin 

Azo  Bordeaux 

Black. 

Blue.. 

Brown 

Eosine  and  phloxine 

Fast  light  yellow 

Green 

Helio  fast  rubine 

Lithol  rubine  and  maroon 


Methyl  violet 

Naphthol  yellow 

Orange 

Peacock  blue 

Persian  orange 

Phosphomolybdic   acid 
lakes,  total. 

Blue 

Brown 

Green 

Purple 

Red 

1  Included  in  all  other. 


Manufacturers'  identification  num- 
bers (according  to  list  on  p.  51) 


12,  64,  97, 123, 126, 138, 142, 157, 176, 

199,  217,  218,  234,  X,  X,  X,  X,  X, 

XXX 
2,  12,  29,  64,  104,  126,  138,  142,  176, 

218  XXX 
44,  73'  97,  123,"  138,  217,  218,  234,  X. 
12,  29,  44,  64,  73,  97,  104,  119,  123, 

138,  157,  208,  217,  218,  231,  X,  X, 

X,  X,X,X,  X,  X. 

138,  217,  218,  231,  234,  X 

29,  36,  44.  64,  73,  77,  97, 115,  123, 126, 

138,  199,  208,  217,  218,  X,  X,  X, 

X,  X. 
12,  77,  104,  123,  138,  208,  218,  X,  X, 

X  X 
12,  29,  44,  64,  73,  77,  97, 104,  123,  126, 

138,  157,  208,  217,  218,  X,  X,  X, 

X,  X,  X,  X,  X,  X,  X,  X,  X,  X. 
12,  29,  64,  104,  123,  138,  208,  X,  X, 

X  X  X  X   X 
12,  29,  36,  44,  64,  73,  77,  97,  104,  119, 

123,  126,  142,  157,  197,  199,  208, 

217,  218,  231,  X,  X,  X,  X,  X,  X, 

X. 
12,  29,  44,  64,  66,  77,  97, 104, 123,  126, 

138,  199,  208,  218,  234,  X,  X,  X, 

X,  X. 
12,  73,  77,  123,  218,  234,  X,  X,  X.. 
29,  36,  44,  64,  77,  97,  104,  115,  123, 

138,  217,  218,  231,  X,  X,  X,  X, 

XXX 
12,  29f36,  44,  64,  73,  77, 102, 104,  123, 

126,  138,  199,  208,  217,  218,  234,  X, 

X  X  X  X  X  X 
12,  36,  64,  73,  77,  102,' 123,  126,  138, 

199,  208,  218,  X,  X,  X,  X,  X,  X, 

X,  X,  X. 


12,  36,  77,  104,  208,  X,  X. 

X 

12,  77,  157,  X 

12,  36,  X 

12,  157,  X 


Produc- 
tion 


Pounds 
144,  602 


367,615 


78.  573 
295,  723 


41,030 
140, 040 

162, 606 
333,  246 

48, 657 
911,003 


30,  783 
221, 157 


1,562,411 
500,  594 
86, 159 


Sales 


Quantity 


Pounds 
125, 976 


66, 357 
160, 994 


(') 
129,  922 


53,  309 
221, 440 

26,  586 
911,361 

148,  271 


30,  805 
135,  409 


1,  214, 120 

335, 487 

63, 422 


Value 


$154, 900 


89,  912 

34,  790 

86,  870 


(>) 
110,112 


39,  660 
112,  253 

44,412 
238, 910 

77,  359 


21,  708 
38, 147 


675, 796 
134, 856 
51,  227 


Unit 
value 


$1.23 


.27 


.52 
.54 


.74 
.51 

1.67 
.26 

.52 


.56 
.40 
.81 


DYES   AND    OTHER   SYNTHETIC    ORGANIC    CHEMICALS  35 

Table  10. — Color  lakes  and  toners:  United  States  production  and  sales,  1937 — Con. 


Manufacturers'  identification  num- 
bers (according  to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  product 

Quantity 

Value 

Unit 
value 

LAKES  AND  EXTENDED 

colors — continued 

Phosphotungstie  acid  lakes: 
Blue 

29,  34,  44,  64,  77,  97,  104,  119,  123, 

126,  138,  199,  208,  218,  234,  X.  X, 

X,  X,  X,  X. 
29,  34,  44,  64,  77,  97,  104,  123,  126, 

138,  218,  234,  X,  X,  X,  X,  X,  X, 

X. 
29,  44,  126,  199,  218,  234,  X,  X,  X-. 
44,  64,  73,  77,  97,  104,  126,  138,  199, 

218,  234,  X,  X,  X,  X,  X,  X,  X, 

X. 

73,  97,  138,  217,  X,  X 

12,  29,  64,  77,  102,  104,  123,  126,  138, 

176,  199,  217,  218,  234,  X,  X,  X, 

X,  X,  X. 
12,  123,  199,  208,  X,  X,  X 

Pounds 
493, 314 

208,  538 

28, 082 
147, 257 

5,824 
449,  521 

22,  845 
330, 261 

783, 305 

239,  212 

31,  698 
216, 182 

104,  252 

Pounds 
484,  207 

200,  933 

30, 231 
125, 822 

1,473 

206,  607 

24,  659 
301, 276 

697, 768 

218, 110 

24,424 
116,  093 

57,  620 

$389, 036 
124,  847 

31,  565 

65,  649 

2,264 
140, 081 

18,  260 
134, 625 

202,  249 

125, 085 

12,  572 
37,  552 

20, 945 

$0.80 

.62 

1.04 

Red 

.52 

All  other 

1.54 

.68 

.74 

Red...  

29,  64,  73,  77,  97,  104,  119,  138,  199, 

208,  217,  218,  231,  X,  X,  X,  X, 

X,  X,  X,  X,  X. 
2,  12,  29,  36,  44,  64,  97,  119,  123,  126, 

176,  199,  217,  218,  231,  X,  X,  X, 

X. 
12,  36,  77,  102,  104,  123,  138,  199, 

208,  218,  X,  X,  X,  X,  X. 
12,  64,  77.  97,  104,  138,  217,  231,  X,  X_. 
12,  64,  104,  115,  138,  218,  X,  X,  X, 

X,  X. 
36,  119,  138,  217,  218,  231,  234,  X,  X, 

X. 

.45 

Scarlet  2R 

.29 

Tartrazine.. 

.57 

Violet 

.51 

Yellow 

.32 

All  other 

.36 

8,  139,  988 

6,  440,  125 

3,  215,  642 

.50 

tended  colors. 

34,  208,  X,  X 

TONEES  OR  FULL  STRENGTH 
COLORS 

645,  207 
405, 948 

235,  579 

546, 862 

2,  561, 744 

105,  265 
356,  213 
200,  620 

47,  288 
1,  271,  309 

106,  143 

84,728 

629,  045 
217,  648 

183, 928 

485,  329 

2,  426,  522 

90,  922 

351,  318 

171,  420 

43,  562 

1,  136,  743 

105, 776 
64,  753 

682,  035 
338,  945 

244, 855 

444,823 

1,614,989 

104,  335 
799,  081 
228,  048 
39, 746 
852,  432 

87,  046 
190, 193 

1.08 

Eosine  and  phloxine 

12,  73,  77,  97,  102,  123,  126,  199,  208, 

218,  234,  X. 
12,  36,  102,  104,  115,  123,  199,  234,  X, 

x,x,x,x. 

12,  34,  36,  64,  73,  77,  102,  104,  115. 

123,  126,  138,  199,  208,  218,  234,  X, 

X  X  X  X 
12,  36,  64, '73,77,  102,  104,  115,  119, 

123,  126,  199,  217,  218,  231,  234,  X, 

X,  X,  X. 
12,  64,  73,  77,  102,  119,  123,  126,  199, 

X,  X,  X,  X. 
12,  64,  73,  77,  102,  119,  123,  126,  176, 

217,  231,  234,  X,  X,  X,  X,  X. 

12,  29,  34,  73,  77,  97,  104,  115,  126, 

208,  217,  218,  234,  X,  X,  X,  X. 
12,  77,  102,  104,  119,  126,  199,  217, 

218,  X,  X. 

2,  12,  29,  36,  64,  73,  102,  119,  123,  126, 
176,  199,  217,  218,  231,  X,  X,  X, 
X,  X,  X,  X,  X,  X. 

34,  102,  234,  X 

1.56 
1.33 

Lake  Red  C  and  D 

.92 

Lithol 

.67 

1.15 

Maroon 

2.27 

Methyl  violet 

1.33 

Orange 

.91 

Para  red _. 

.75 

.82 

2.94 

ers,  total. 
Blue 

12,  36,  64,  73,  77,  102,  104,  123,  X,  X. 

Red 

Phosphotungstie  acid  ton- 
ers: 
Blue 

29,  64,  73,  77,  102,  104,  123,  126,  138, 
199.  217,  218,  234,  X,  X,  X,  X,  X, 
X. 

29,  44,  64,  77,  102,  104,  115,  123,  126, 
138,  176,  199,  208,  217,  218,  234,  X, 

X,  x,x,x,x,x. 

140,  426 
118,772 

125,  852 
107,  647 

432,  721 
292,  551 

3.44 

Green 

2.72 

36  UNITED   STATES   TARIFF    COMMISSION 

Table  10. — Color  lakes  and  toners:  United  States  production  and  sales,  1937 — Con. 


Name  of  product 


TONERS  OR  FULL  STRENGTH 

colors— continued 

Phosphotungstic  acid  ton- 
ers—Continued. 
Purple 


Ked. 


Red 

Toluidine  red. 

All  other 


Total  toners  or  full 
strength  colors. 

REDUCED  TONERS 

Lake  red  C  and  D 

Lithol 


Para  red 

Toluidine  red- 


All  other - 

Total  reduced  toners. 


Total  color  lakes  and 
toners. 


Manufacturers'  identification  num- 
bers (according  to  list  on  p.  54) 


29,  64,  77,  102,  104,  126,  138,  176,  199, 
208,  217,  218,  X,  X,  X,  X,  X. 

29,  44,  64,  73,  77,  104,  126,  138,  199, 
218   XXX 

29,  34,  64,  102,  104,  208,  231,  234,  X, 
XXX 

2,  12,  36,  64,  73,  102,  104,  119,  123, 
126,  176,  199,  217,  218,  231,  X,  X, 
X,  X,  X,  X,  X,  X,  X,  X,  X. 

12,  64,  73,  102,  104,  119,  X,  X 


12,  36,  64,  73,  97,  104,  123,  126,  138, 

199,  208,  218,  234,  X,  X,  X. 
12,  29,  64,  73,  77,  97,  104,  123,  126, 

138,  199,  20S,  217,  218,  231,  234, 

X   X   X  X  X   X 
2,  12,  29,  36',  64'  73*  97,'  104,  123,  126, 

176,  217,  218,  231,  X,  X,  X,  X,  X, 

X  X 
2,  12,  29,  36,  64,  73,  97,  104,  119,  123, 

126,  176,  208,  217,  218,  231,  X,  X, 

X,  X,  X,  X,  X,  X,  X,  X. 
2,  12,  64,  97,  138,  218,  X,  X,  X 


Produc- 
tion 


Pounds 
84, 352 

97,  325 

282,  280 
940, 047 

120,  680 


8, 350,  788 


101,  898 
401,  249 

630,  909 

267,  258 

148,  485 


1,  549,  799 


18,  040,  575 


Sales 


Quantity 


Pounds 
79,  050 

94,401 

275, 826 

807,  034 

119,  340 


7,  516,  116 


93,  721 
393,  735 

525,  149 

222,  263 

71,  767 


1, 306,  635 


15,  262, 876 


Value 


$137,  016 

120, 177 

282,  769 

1,  081,  923 

177,  432 


8,  151,  117 


54,  660 
150,  437 

89,  507 

77, 485 

73,  352 


Unit 
value 


445,  441 


11,  812,  200 


$1.  73 
1.27 
1.03 
1.34 

1.49 
1.08 

.58 
.38 

.17 

.35 

1.02 
.34 
.77 


MEDICINALS 

Synthetic  medicinals  were  produced  in  increased  quantity  in  1937. 
The  47  makers  of  coal-tar  medicinals  produced  14,800,000  pounds, 
with  sales  of  11,989,000  pounds,  valued  at  $11,496,000.  Aspirin  sales 
increased  25  percent  to  a  peak  of  5,144,000  pounds.  Sulfanilamide, 
a  minor  item  in  1936,  showed  sales  of  267,000  pounds,  valued  at  $1,322,- 
000  in  1937,  the  average  value  being  $4.95  per  pound.  Mandelic 
acid  and  salts  increased  more  than  200  percent  in  output.  Among 
the  outstanding  changes  were  sharp  decreases  in  the  prices  of  the 
arsphenamines  and  the  several  medicinal  dyes. 

Production  of  non-coal-tar  synthetic  medicinals,  by  37  makers, 
totaled  1,814,000  pounds,  with  sales  of  1,442,000  pounds,  valued  at 
$2,408,000,  or  an  average  of  $1.67  per  pound.  Amino  acetic  acid,  a 
relatively  new  product  in  this  group,  increased  more  than  100  per- 
cent in  production,  90  percent  in  sales  quantity,  and  100  percent  in 
sales  value  over  1936.  Average  sales  price  was  $1.86  per  pound,  as 
compared  with  $4.89  per  pound  in  1933.  Further  decline  in  the 
production  and  sales  of  certain  barbituric  acid  derivatives  is  noted. 

Table  11  shows  production  and  sales  of  synthetic  medicinals  in 
1937. 


DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


37 


Table   11. — Synthetic  medicinals:   United  States  production  and  sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  num- 
ber with  the  designated  product.  Blan  ks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  statistics 
of  production  or  sales  cannot  be  published  without  revealing  information  in  regard  to  individual  firms. 
The  figures  thus  concealed,  however,  are  included  in  the  total] 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  medicinal 

Quantity 

Value 

Unit 
value 

(A)  COAL-TAR 

47,  62,  141,  145 

62,  145,  X 

Pounds 
986, 429 

Pounds 
950,  827 

$189,  739 

$0  20 

Acetylamino-hydroxy-phenyl-arsonicacid. 

1,  X 

Acetyl-p-aminophenyl    salicylate    (Salo- 

X.... 

phen). 
Acetyl  phenylhydrazine... 

188 

62,  145,  X,  X,  X, 

X. 
1,  34,   64,  84,   143, 

145,  153,   X,  X, 

X. 
1 

4, 997, 453 
355,  369 

5, 143, 672 
267, 104 

2,  624, 133 
1, 322, 412 

.51 

p-Aminobenzosulfonamide        (Sulfanila- 
mide). 

p-Aminobenzovl    di-n-butvlamino    pro- 

4.95 

panol  (Butyn  base). 
p-Aininobenzoyl  di-n-butvlamino  propa- 

1 

nol  sulfate  (Butyn  sulfate). 
p-Aminobenzoyldieth  ylaminoethanol 

(Procaine). 
p-Aminobenzovl  dime  thylaminomethyl 

1,  84,  160,  164,  209, 
X,  X. 
X.... 

13, 456 

13, 154 

381, 390 

28.99 

butanol  hydrochloride  (Tutocain). 

X 

hydrochloride  (Mapharsen). 
Ammonium  mandelate 

X 

Amyl-m-eresol 

X 

Antipyrine. 

62. 

Arsanilic  acid 

1,  X_. 

Arsphenamine 

Barbituric  acid  derivatives: 

Cvclohexenvlmethvlmethvl      barbi- 

1,60,136, 143.X,  X. 
X. 

237 

266 

36, 423 

136. 93 

turic  acid  and  salt. 
Phenobarbital... 

1,  84,  136,  143,  209, 

X   X 
1,  84,' 136,  143,  209, 

X. 
X. 

94, 195 
9,301 

92, 171 
10,  527 

419, 390 
40, 958 

4.55 

Phenobartital  sodium.. 

3.89 

Phenvlethylmethyl  barbituric  acid... 

l-p-Tolyl-5:5-ethyl-n-butyl  barbituric 

X 

acid. 
Benzaldehvde 

101,  209,  221,  X 

192 

73, 086 

65, 744 

54,  144 

.82 

Benzoic  acid 

64,  145,  209 

Benzoyl-tetramethvldiamino-ethyl-iso- 

X. 

propanol  hydrochloride. 
Benzylmethyl  ketone 

X. 

Benzyl  phthalimide 

X 

192. 

Bismethvl  benzylidine 

X 

Bismuth  betanaphthol.   

153,  X 

X 

62... 

n-Butyl-p-aminobenzoate  (Butesin) . 

1... 

X... 

ethanol. 
Caffeine  sodium  benzoate 

136,  143,  153,  192... 
153  .. 

1,805 

1,269 

3,640 

2.87 

X 

X  .. 

193 

191.  . 

chloride. 

X 

X 

1... 

nol  (Butesin  picrate). 

X 

thoxy  quinoline. 

X        

(E  pi  nine). 

X 

X. 

X 

X 

X 

38  UNITED    STATES    TARIFF    COMMISSION 

Table  11. — Synthetic  medicinals:  United  States  production  and  sales,  1987 — Con. 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  medicinal 

Quantity 

Value 

Unit 
value 

(a)  coal-tar — continued 
3:4-Dimethoxy  phenylpropionic  acid 

X 

Pounds 

Pounds 

4-Dimethylamino  antipyrine  (Aminopy- 

148,  X 

rine). 
Dinitrophenol 

64.. 

Dioxy  anthranol  (Anthralin)..   

1 

X 

Disodiumhydroxymercurisalicyloxy  ace- 

X  

tate  (Merenrosol). 
Dyes,  medicinal,  total.. 

40, 104 

38, 089 

$759,  299 

$19.  93 

Acri  violet 

148. 

Brilliant  green 

148. 

3:6-Diamino    acridine    sulfate    (Pro- 

148  

flavine). 
3:6-Diamino-10-methyl  acridine  chlo- 

1, 148.... 

ride  (Acriflavine). 
Dibromohydroxymercurifluorescein 

107 

sodium  salt  (Mercurochrome). 
Gentian  violet 

148 

Hexalet  

X... 

Methylene  blue 

34,  148 

Methyl  violet 

148... 

Phenolsulfonphthalein 

107,  X 

Scarlet  red 

148 

Stovarsol  and  salts 

X 

Sulfosalicylic  acid 

70,  X.... 

Trvparsamide 

X 

Ethocaine  borate  (Borocaine) 

193,  X 

Ethyl-p-amino    benzoate    (Benzocaine) 

(Anesthesine). 
Ethylenediamine  mandelate 

1,  84,  143,  160,  192, 

209,  X,  X,  X. 
174.... 

15, 149 

12, 444 

44,  054 

3.54 

Gamma  -  diethvlaminopropvlcinnamate 

X. 

hydrochloride  (Apothesine). 
Guaiacol  (liquid) 

101,  145... 

Hexylresorcinol 

193.. 

8-Hydroxyquinoline  (Oxvquinoline.  base). 

X.  X.... 

8-Hydroxyquinoline-5-sulfonic  acid 

X 

o-Iodobenzoic  acid 

70,  X. 

o-Iodosobenzoic  acid.  

X 

Iodoxyquinoline   sulfonic    acid    (Yatren 

X,  X 

acid) . 
Laevo-methvlaminoethanol   catechol 

x__ 

(Epinephrine). 
Lithium  benzoate 

x_ 

Lithium  salicylate 

X  .. 

Magnesium  salicylate 

62,  101,  136 

5,487 
121,  932 

5,482 
242,  210 

1.00 

Mandelic  acid  and  salts 

1,84,136,143,153... 
X. 

14S,  408 

1.99 

Menthvi  salicylate 

2-Methoxv-6-chloro-9-d<ethylaminopentyl- 

X... 

amino-acridine. 
Methyl-m-amino-p-hvdroxy    benzoate 

x._ 

(Orthofoim). 

X 

pirin). 
Methylene    disalicylic    acid    derivative 

X 

(Formidine). 
p-Methylphenvl  cinchoninic  ethyl  ester 

1,  34,  X 

(Neocinchophen) . 

160 

ate  (Amylcaine). 

160 

ate  (Monocaine). 
Neoarsphenamine 

1, 60, 136, 143,  X,  X. 
1 

8,797 

8,238 

1, 083,  991 

131.58 

X... 

X,  X    . 

Oxvquinoline  citrate   

X,  X... 

Oxyquinoline  sulfate.  - 

X,  X... 

Oxyquinoline  tannate_   . 

X... 

Phenobarbital  (see  Barbituric  acid  deriva- 
tives). 
Phenolphthalein 

145,  X,  X 

460,  400 

Phenolsulfonates  (calcium,  sodium,  zinc, 

136,  X 

etc.). 
Phenylazo-diamino  pyridine  hydrochlo- 

182  

ride  (Pyridium). 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS  39 

Table   11. — Synthetic  medicinals:  United  States  production  and  sales,  1987 — Con. 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  medicinal 

Quantity 

Value 

Unit 
value 

(A)  coal-tar— continued 
Pnenvlethvlmethyl  urea  sodium.   

X 

Pounds 

Pounds 

Phenvl  isocyanate 

70 

b-Phenylisopropyl  amine  and  suliate 

X... 

Phenyl  mercuric  acetate - 

71,  96.... 

Phenvl  mercuric  benzoate ._ 

96.. 

Phenvl  mercuric  chloride 

96 

Phenyl  mercuric  hydroxide... 

71,  96.... 

Phenvl  mercuric  nitrate 

71,96 

Phenylmethvlisopropyl  antipyrine  (Iso- 

103 

propyl  antipyrine). 
Phenylpropanolamine    hydrochloride 

193 

(Propadrin  hydrochloride) . 
2-Phenylquinoline-4-carboxylic  acid  and 

34,  X 

salts  (Cinchophen)  (Phenyl  einchoninic 
acid) . 

X 

X 

Pyramidon    and    trichloroethyl    alcohol 

X 

urethane  compounds. 

64,  168 

70,  143,  192 

62, 101,  145,  X 

62 

4, 402, 889 

2,  283, 420 

$610,  549 

$0.27 

Salol - 

Silver  arsphenamine 

1,  X 

Sodium  o-iodohippurate  . 

136 

Sodium  methylene  sulfonamino-hydroxy- 

1 

phenyl  arsonate. 
Sodium  salicylate ..  _  . 

62,  101,  145 

Sodium  p-toluene  sulfochloramide  (Chlo- 

145 

ramine  T). 
Strontium  salicylate 

62,  101,  136 

Succinic  peroxide 

X 

Sulfanilamide.    (See  p-Aminobenzosulfo- 
namide.) 

1, 60, 136, 143,  X,  X. 
191 

325 

291 

49,323 

169.  49 

Tetrabromo-o-cresol 

Tetraiodophenolphthalein    sodium    salt 

(Iodeikon)  (Antinosin). 
Theobromine  and  sodium  salicylate.. .  .. 

70,136, 143,  148,  X, 

X 
136,  143,  153 

5,997 

4,940 

73, 018 

14.78 

Theophylline  calcium  salicylate. 

X 

Theophylline  sodium  salicylate 

X... 

Thymol  p-aminobenzoate  .. 

160... 

p-Toluene  sulfodichloramide   (Dichlora- 

145. 

mine  T) . 

X 

All  other  medicinals  of'coal-tar  origin 

1,  X 

Total  coal-tar  medicinals: 

11,573,296 
3,  226,  525 

8,  981, 486 
3, 007,  873 

7, 180,  S56 
4, 315, 189 

.80 

statistics  are  shown. 
Those    for    which    individual 

1.43 

statistics  cannot  be  shown. 

14,  799, 821 

11,989,359 

11,  496, 045 

.96 

(B)    NON-COAL-TAR 

Adenine  sulfate 

70 

Aminoacetic  acid  (Glycocol)  (Glycine) 

Amvl  nitrite  (Isoamyi  nitrite) .. 

6,  62,  64, 169,  209,  X. 
70,  136.  X 

116,  344 

105,  405 

195, 879 

1.86 

Ascorbic  acid...     .      

X,  X. 

119,83c 

67,  844 

419,  457 

6.18 

103 

103 

Butyl  ethyl  barbituric  acid  and  salts. 

1 

Calcium  isopropyl  ethyl  barbituric 

X 

acid  and  salts 

X 

and  salts. 

X 

X 

(Dibromin). 

1,  84,  103,  X. 

bital). 

X 

onic  acid. 

40  UNITED    STATES    TARIFF    COMMISSION 

Table  11. — Synthetic  medicinals:   United  States  production  and  sales,  1937 — Con 


Manufacturers' 
identification 
numbers  (accord- 
ing to  list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  medicinal 

Quantity 

Value 

Unit 
value- 

(b)  non-coal-tar— continued 

Hexylethyl  barbiturate  sodium  (Ortal 

sodium). 
Isoamyl  ethyl  barbituric  acid  and  salts. 

Isopropyl  ethyl  malonic  ester 

Monoethyl-ethyl  malonic  acid 

Propyl-methyl-carbinyl-allyl-barbitu- 

rate  sodium. 

X 

Pounds 

Pounds 

129 

X. 

1 

129 

62,  130.. 

43,  X 

X 

X 

Calcium  lactate.    (See  table  15.) 

X  

Camphor  (synthetic).    (See  table  15.) 

X 

145,  X 

143,  X,  X,  X 

Chloroform.     (See  table  15.) 

X 

70 

Diethyltiromoacetyl     bromide     (Bromo 

acid). 
Ether,  absolute.    (See  table  15.) 
Ethyl  chloride.    (See  table  15.) 
Ethyl  ether.    (See  table  15.) 

X  .. 

X  . 

X 

70,71,130,143  . 

1 

81.136,143 

24, 629 

16, 776 

$10,537 

SO.  63 

174 

174     . 

174 

70,136... 

101, 145  .. 

64, 101 

Hexamethylenetetramineanhydromethy- 

lene  citrate. 
Hexamethylenetetramine  tetra  iodide 

X  . 

174 

136,143,153 

X 

12, 537 

Lactic  acid.    (See  table  15.) 

111 

139,209,  X... 

160 

70,71,136,143 

X 

515 

459 

2,319 

5.05 

70, 143,  X 

X 

bismolV 

X 

136 

136 

64,99,143... 

75, 475 

153 

Theophylline  and  derivatives: 

84, 136,  X,  X 

Ethylenediamine  ( Aminophy lline) . .  - 

10,  63,  84,  135,  X, 

X,  X,  X,  X. 
136,  X 

8,810 

X 

136,143,153 

X 

7,507 

6,000 

18, 603 

3.10 

62,  X 

62 

Tribromotertiarybutyl   alcohol    (Brome- 

tone) . 
Trichlorotertiarybutyl   alcohol    (Chlore- 

tone). 
Other  medicinals 

X 

X 

Total  non-coal-tar  medicinals: 

245, 817 
1,  568,  218 

128, 640 
1, 313, 430 

227,  338 
2,181,033 

1.77 

statistics  are  shown. 

1.66 

statistics  cannot  be  shown. 

Grand  total 

1, 814, 035 

1,442,070 

2, 408, 371 

1.67 

DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


41 


FLAVORS  AND  PERFUME  MATERIALS 

These  important  synthetics  were  produced  in  increased  quantity  and 
variety  in  1937.  Production  of  those  of  coal-tar  origin  amounted  to 
4,356,000  pounds,  or  25  percent  more  than  in  1936.  The  28  makers 
report  sales  of  3,907,000  pounds,  valued  at  $3,983,000,  or  14  percent 
more  by  quantity  and  24  percent  more  by  value  than  in  the  preceding 
year.  Among  the  outstanding  features  of  this  group  in  the  past  year 
are  a  36  percent  increase  in  sales  of  coumarin,  and  a  26  percent  increase 
in  sales  quantity  and  33  percent  in  sales  value  of  vanillin.  It  should  be 
noted  that  vanillin  from  whatever  source  is  included  under  coal-tar 
flavors. 

Synthetic  flavors  and  perfume  materials  not  of  coal-tar  origin  were 
produced  by  27  makers  in  1937,  and  the  output  totaled  1^,803,000 
pounds,  or  51  percent  increase  over  1936.  Sales  were  1,560,000 
pounds,  valued  at  $1,024,000,  or  35  percent  more  by  quantity  and  19 
percent  more  by  value  than  in  the  preceding  year.  Unusual  increases 
are  noted  for  geraniol,  methyl  ionone,  and  terpineol.  Sales  of  geraniol 
increased  60  percent  by  quantity  and  37  percent  by  value,  while  sales  of 
methyl  ionone  increased  63  percent  and  of  terpineol  more  than  50  per- 
cent in  both  quantity  and  value. 

Table  12  shows  production  and  sales  of  synthetic  flavors  and  per- 
fume materials  in  1937. 

Table  12. — Synthetic  flavors  and  perfume  materials:  United  States  production  and 

sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number 
with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  statistics  of 
production  or  sales  cannot  be  published  without  revealing  information  in  regard  to  individual  firms. 
The  figures  thus  concealed,  however,  are  included  in  the  total] 


Manufacturers'  iden- 
tification numbers 
(according  to  list  on 
p.  54) 

Produc- 
tion 

Sales 

Name  of  flavor  or  perfume  material 

Quantity 

Value 

Unit 
value 

(A)   COAL-TAR 

Acetophenone 

78,  83,  X,  X,  X,  X 

209 

Pounds 
16,  585 

Pounds 

Amino-carvacrol 

Arnyl  benzoate 

78 

Amyl  cinnamic  aldehyde 

75,  78,  139,  221,  X,  X, 

X,  X. 
62,  78,  198,  X,  X,  X,  X . 
105 

50, 187 
50,285 

48, 198 
49, 955 

$86, 985 
24,  224 

$1.80 

Amyl  salicylate 

.48 

Benzal  chloride 

X 

Benzophenone 

64,  78,  83,  X... 

Benzoyl  isoeugenol 

75... 

Benzyl  acetate 

78,  139,  198,  209,  X 

Benzyl  alcohol 

78,  105,  139,  198,209,  X. 
78,  139,  198,  209,  X,  X  _ 
75,78,  X,  X 

78,  X 

33,  672 
236 

32, 126 
178 

26,127 
269 

.81 

Benzyl  butyrate 

1.51 

Benzyl  cinnamate 

78,  221 

Benzvl  isobutyrate 

75 

Benzyl  isoeugenol 

75,  78 

Benzylphenyl  acetate 

75 

Benzyl  propionate 

75,  78,  139,  221,  X,  X.. 
78,  83,  139,  221,  X 

75,  78      . 

1,429 
7,157 

1,247 
7,214 

2,089 
11, 149 

1.68 

Benzyl  salicylate. .. 

1.55 

Benzyl  valerate 

Benzylidine  acetone.. 

221... 

Bromstyrol... 

X  .. 

Butylphenyl  acetate 

75  .. 

Carvacrol 

209 

Carvacryl  acetate 

209    . 

Carvo-menthoL ;.. 

209 

Carvo-menthone 

209  .. 

Cinnamic  acid 

83,  209,  X 

Cinnamic  alcohol... 

78,  83,  141. 

Cinnamic  aldehyde 

78, 139, 209.X,  X.X.X- 

27,  477 

17, 185 

16,  282 

.95 

42 


UNITED    STATES    TARIFF    COMMISSION 


Table  12. 


-Synthetic  flavors  and  'perfume  materials:  United  States  production  and 
sales,  1937 — Continued 


Manufacturers'  iden- 
tification numbers 
(according  to  list  on 
P.  54) 

Produc- 
tion 

Sales 

Name  of  flavor  or  perfume  material 

Quantity 

Value 

Unit 
value 

(A)  coal-tar— continued 

75,  78 

Pounds 

Pounds 

75 

75.  78 

62,  64,  78,  141,  145 

78,  221 

216,  767 

186,  325 

$488,  939 

$2.62 

139 

75,  78 

X 

Dimethyl  acetal  of  phenylacetaldehyde 

83,  X 

75,  78 

78,  221 

Dimethyl  hydroquhione... 

64,  78,  X 

Diphenylmethane 

X 

62,  78,  X 

75,  78,  X 

78,  159,221,  X,  X,  X.. 
78,  221 

1,797 

1,653 

1,620 

.98 

75,  X 

X 

62,  78,  X 

599 

432 

423 

.98 

141,  145,  X 

75. 

p-Hydroxy  benzoic  acid  esters  (Asepto- 

X 

form) . 

75 

78 

78 

78,  X 

75,  78... 

78. 

209 

78,  83,  X,  X,  X 

62,139 

4,280 

2,864 

3,374 

1.18 

78,  101,  105,  159,  221... 

209,  221,  X 

Methyl  p-cresol 

75,78.-_ 

78,83.X 

Methvlphenyl  acetate 

83,  221,  X,  X,  X,  X 

S3 

1,183 

1,056 

1,475 

1.40 

83    . 

62,78. 101, 145,  X,  X 

64,  139,  X,  X... 

1,  677, 329 

1, 538, 599 

497,  504 

.32 

64,  139,  X,  X... 

8,131 

55,  9 15 

29,  843 
60,  765 

3.67 

64, 139,  X,  X     . 

56, 741 

1.09 

75 

b-Naphthyl  ethyl  ether  (Nerolin) 

S3,X 

b-Naphthyl  methyl  ether  (Yara  yara).. 

83,  X. 

75  „ 

Phenvlacetic  acid 

83,  221,  X,  X,  X... 

Phenylacetic  aldehyde 

78 

X  

Phenylacetic  ketone 

78 

1,  78,  221.  X     . 

Phenvlethvl  alcohol.. 

62,  78,  221,  224,  X,  X 

78      

107,  320 

137, 091 

251,973 

1.84 

X... 

78.  221 

64.221. 

75.X... 

75     . 

145.  . 

62.64 

X 

X 

X 

(Rosetone). 

Vanillidine 

X 

Vanillin 

141, 145,  190,  X,  X 

368, 330 

370. 930 

1,213,052 

3.27 

Total   coal-tar   flavors  and   per- 
fume materials: 
Those  for  which   individual 

2,621,374 
1,734,919 

2,  459, 129 
1, 448, 088 

2,  716,  093 
1,  266,  414 

1.10 

si  at  is!  ics  are  shown, 
Those  for  which  individual 

.87 

statistics  cannot  be  shown. 

Grand  total 

4, 356,  293 

3,907,217 

3. 982,  507 

1.02 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


43 


Table  12. — Synthetic  flavors  and  perfume  materials:  United  States  production  and 

sales,  1937 — Continued 


Manufacturers'  iden- 
tification numbers 
(according  to  list  on 
p.  54) 

Produc- 
tion 

Sales 

Name  of  flavor  or  perfume  material 

Quantity 

Value 

Unit 
value 

(B)   NON-COAL-TAB 

Acetate: 

C  10     „ 

75... 

Pounds 

Pounds 

C  12                  -. 

75 

Aldehyde:  C  7  (Heptyl) 

75,  X 

75,  78,  X 

75 

33,  75,  X 

X... 

75,X 

99,151.. 

78,  X,  X... 

75  . 

78,159 

78 

78 

Citral - 

33,  64,  75,  78,  131,  139, 
209,  221.X,  X,  X,  X, 
X. 

75,  221,  X,  X,  X 

36,  472 

33,  232 

$51, 852 

$1.56 

64,  78,  83,  139,  209,  221, 

X,  X. 
75,  78,  X.... 

15,  319 
38 

11, 083 
22 

16,  354 
62 

1.48 

2.82 

X 

78 

78. 

209,  X 

X... 

33,  75,81,  159,  X,  X... 
159,  X 

38,611 

36, 483 

23, 848 

.65 

81,  159,  X... 

75 

75,  78,  159,  X,  X,  X 

75,  78,  131,  221 

4,773 
15, 779 

4,526 
13, 652 

3,416 
9,494 

.75 

.70 

33,  221 

75 

78.X 

Formate:  C  12 

75 

64,  75,  78,  83,  139,  209, 
214,  221,  X,  X,X,X, 
X   X 

64,  75,  78,  83,  139,  209, 
X,  X. 

75,  78 

368, 866 
14, 921 

328, 125 
11, 093 

212,  578 
11, 956 

.65 

1.08 

75,  78,  X 

X,  X,  X 

41,884 

64,  X    . 

Hydroxy  citronellal  dimethyl  acetal 

X 

75 

64,   139,   141,  209,  221, 

224,  X,  X. 
78,  81,  159,  X     . 

52, 393 

48,  605 

89, 392 

1.84 

78,  159,  X 

552 
1,284 

310 
881 

282 
1,496 

.91 

75,  159,  X,  X 

1.70 

X,  X,  X 

64 

75,  X,  X,  X,X. 

83,  209 

10, 095 

9,449 

24,  231 

2.56 

75,  78,  221,  X,  X,  X 

5,873 

3,679 

8,010 

2.18 

64,   139,   141,  209,  221, 
224,  X. 

32, 902 

26,  780 

68, 018 

2.54 

Octyl  alcohol  (sec)  (Capryl  alcohol) 

64,  75,  78,  131,  214,  221 
X,  X,  X,  X,  X 

6,642 

4,743 

64,980 

13.70 

44 


UNITED    STATES    TARIFF    COMMISSION 


Table  12. — Synthetic  flavors  and  perfume  materials:  United  States  production  and 

sales,  1937 — Continued 


Manufacturers'  iden- 
tification numbers 
(according  to  list  on 
p.  54) 

Produc- 
tion 

Sales 

Name  of  flavor  or  perfume  material 

Quantity 

Value 

Unit 
value 

(B)  non-coal-tar— continued 

75.X 

Pounds 

Pounds 

Rhodinyl  acetate 

75,  X 

75 

64,  99,  X,  X 

781, 152 

733, 070 

$147,  798 

$0  20 

64 

64,  75,  X,  X.. 

Undecalactone 

75.X 

75,  X,  X,  X 

Total  non-coal-tar  flavors  and  per- 
fume materials: 
Those  for  which  individual 

1, 427,  575 
375, 192 

1, 265, 733 
294,  736 

733,  765 
290,  670 

.58 

statistics  are  shown. 

99 

statistics  cannot  be  shown. 

1, 802,  767 

1,  560, 469 

1, 024,  435 

.66 

KESINS 

Activity  in  the  production  of  synthetic  resins  continues  to  increase 
with  a  record  output  exceeding  160  million  pounds  in  1937,  or  23  per- 
cent more  than  in  1936.  Production  of  resins  from  coal  tar  exceeded 
141  million  pounds,  of  which  tar  acid  resins  were  the  most  important, 
followed  by  the  alkyd  resins.  Tar  acid  resin  production  increased 
15  percent  to  80,771,000  pounds,  while  alkyd  resin  increased  30  percent 
to  61,254,000  pounds.  Cast  phenolic  resins  show  decreased  produc- 
tion and  sales  compared  with  the  preceding  year. 

Resins  not  of  coal-tar  origin  increased  35  percent  in  output  to 
21,006,000  pounds,  with  sales  of  18,891,000  pounds  valued  at  $5,681,000, 
or  28  percent  in  quantity  and  58  percent  in  value  as  compared 
with  1936. 

Table  13  shows  production  and  sales  of  synthetic  resins  in  1937. 

Table  13. — Synthetic  resins:   United  States  production  and  sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
page  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification 
number  with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the 
statistics  of  production  or  sales  cannot  be  published  without  revealing  information  in  regard  to  indi- 
vidual firms.    The  figures  thus  concealed,  however,  are  included  in  the  total] 


Manufacturers'  identification 

numbers  (according  to  list  on 

p.  54) 

Produc- 
tion 

Sales 

Name  of  resin 

Quantity 

Value 

Unit 
value 

(a)  coal-tar 
Adipic  acid 

88. 

Pounds 
(') 

2, 803, 987 

58, 450, 032 

0) 

Pounds 
(') 

2, 154, 988 
32,  583,  307 

0) 

Alkyd: 

Maleic  anhydride 

Phthalic  anhydride 

8,  35,  38,  89,  99,  117,  128,  184, 
X    X   X    X 

8,  19,  24,  31,  38',  64,  88,  117,  134, 
176,  184,  220,  X,  X,  X,  X, 
X,  X,  X,  X,  X,  X,  X,  X,  X, 
X,X,X,X,X,  X,  X,X,  X- 
X. 

X 

$418, 183 
6,445,511 

$0.19 
.20 

Succinic  acid 

•  Not  included  in  total. 


DYES   AND    OTHER   SYNTHETIC    ORGANIC    CHEMICALS  45 

Table   13. — Synthetic  resins:  United  States  production  and  sales,  1937 — Contd. 


Name  of  resin 

Manufacturers'  identification 

numbers  (according  to  list  on 

p.  54) 

Produc- 
tion 

Sales 

Quantity 

Value 

Unit 

valne 

(a)  coal-tar — continued 

22,  150,  X 

Pounds 
(') 
(') 
0) 
0) 

10,  701, 463 

5,  459.  654 
47,  898,  203 

14, 086,  283 

651, 979 
1,  972,  940 

Pounds 
(') 
0) 
0) 
0) 

8,  466, 610 

5,  335,  746 
45,  750,  777 

13,  277,  663 

654,  318 
977, 940 

64 

Styrol _ 

62,  X 

145 

Tar.acids: 

Cresol  or  cresylic  acid 

Phenol: 

Cast. 

65,  88,  184,  213,  X,  X,  X,  X,  X, 
X,  X. 

40,  64,  76, 114, 122. 137,  X 

8,  24,  35,  49,  53,  65,  79,  88,  128, 
184,  185,  X,  X,  X,  X,  X,  X, 
X,  X,  X,  X,  X,  X,  X. 

88, 100, 134, 187,  X,  X,  X,  X,  X, 
X. 

88,  X,  X,  X 

$976,  549 

2, 180,  620 
6, 812,  799 

3, 464,  791 

122, 137 
161,  566 

$0.12 
.41 

Other 

.15 

.26 

.19 

Xylenols  and  cresols 

18,  88,  X,  X... 

.17 

142,024,541 

109,201,349 

20,  582, 156 

.  19 

(b)  non-coal-tar 
Abalyn-hydrogen-nitrogen . 

99 

99,  X 

64,  X,  X 

X 

X... 

99  .. 

8,  64,  184,  X,  X,  X,  X,  X,  X... 

X 

Vinyl  acetate  and  chloride 

Wood  rosin-methyl  alcohol 

37,  64,  76,  91 

99 

21,  005,  869 

18, 891,  277 

5,  680,  GOO 

.30 

RUBBER  CHEMICALS 

Synthetic  rubber  chemicals  were  produced  in  somewhat  smaller 
quantities  in  1937.  The  10  makers  report  production  of  29,202,000 
pounds  of  coal-tar  rubber  chemicals,  of  which  15,166,000  pounds  were 
accelerators  and  14,036,000  pounds  antioxidants. 

Statistics  of  production  and  sales  of  non-coal-tar  rubber  chemicals 
arc  not  publishable  since  the  figures  would  reveal  the  activity  of  indi- 
vidual firms. 

Table  14  shows  production  and  sales  of  synthetic  rubber  chemicals 
in  1937. 


46 


UNITED    STATES    TARIFF    COMMISSION 


Table  14. — Synthetic  rubber  chemicals:  United  Stales  production  and  sales,  1937 

[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on  p.  54. 
An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  his  identification  number  with 
the  designate'!  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  statistics  of 
production  or  sales  cannot  be  published  without  revealing  information  in  regard  to  individual  firms. 
The  figures  thus  concealed,  however,  are  included  in  the  total] 


Manufac- 
turers' iden- 
tification 
numbers  (ac- 
cording to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(A)   COAL-TAR 

Pounds 
15, 166, 301 

Pounds 
10,  782, 910 

$4,  503,  236 

$0.42 

64,  145,  X___ 

Aldehyde-amines: 

64,91,145,  X. 

X 

Ethyl  b-propylacryl  aniline .. 

X  .. 

X 

Methylene   aniline    (anhydroformaldehyde 
aniline). 
Other: 

64,145 .. 

91            

145 

X 

X 

Carbon  disulfide  on  methylene  dipiperidine. 

145        

X 

145     . 

145 

guanidine  phthalate  and  anhydroformalde- 
hyde aniline. 

X    

Dimethylethylenediphenyldithiocarbamate 

lead  salt. 
Dinitrophenylbenzothiazyl  sulfide  plus  di- 

phenylguanidine  acetate. 

Dinitrophenvldimethyldithiocarbamate 

Dinitrophenyl  ester  of  mercaptobenzothiazole 
Diphenylcarbamyldimethyldithiocarbamate- 

X    . 

145,  X 

X    . 

145 

X 

8,  62,  64,  145_ 
145     

1, 862, 029 

1,267,226 

416, 205 

.33 

145 

Diphenylguanidine  and  dinitrophenyl  ester 
of  mercaptobenzothiazole. 

Diphenylguanidine    phthalate,     diphenyl- 
guanidine  and  dinitrophenyl  ester  of  mer- 
captobenzothiazole. 

145    

145     

64,  X 

64    

Hexaniethylenetetramine  ester  of  mercapto- 
benzothiazole. 

145 

145,  X,  X... 

Mercaptobenzothiazole  on  benzyl  chloride 
addition  of  hexamethylenetetramine. 

Mercaptobenzothiazole  methylene  aniline. .. 

Mercaptobenzothiazole     methylene-o-tolui- 
dine. 

Mercaptobenzothiazole  potassium  salt 

64 

X      

X    . 

64 

145     . 

64,  145,  X_. 

64         . 

145 

X  .. 

Methylene    p-toluidine    (anhydroformalde- 
hyde p-toluidine). 

Piperidine  penta  methylene  dithiocarbamate 
and  potassium  salt. 

64 

64        

64, 145, 148 
64,  14S 

371,256 

207,565 

47, 820 

.23 

X 

14, 036, 042 

10, 126, 462 

3,  690, 654 

.36 

X 

145..- 

145  .. 

145 

64  .. 

Antox. 

64 

.:::::  ::::i::. 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


47 


Table  14. — Synthetic  rubber  chemicals:  United  States  production  and  sales,  1937 — 

Continued 


Manufac- 
turers' iden- 
tification 
numbers  (ac- 
cording to 
list  on  p.  54) 

Produc- 
tion 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(A)  coal-tar — continued 

Antioxidants— Con. 

Crotonyiidine-a-naphthvlamine 

91 

Pounds 

Pounds 

2:4-Diaminodiphenylamine 

145 

b-Di-p-hydroxy  phenjipropane 

X 

Dimethoxv  diphenvlamine 

64 

X     

X     . 

Diphenyl  ethvlenediamine  - 

X 

91 

Diphenyl-p-phenylenediamine .  ... 

64,  91,  X 

145 

688, 065 

Diphenyl-p-phenylenediamine     and     p-amino- 
diphenyl  acetone  compound..    ._  ._  .    ..  ... 

Diphenyl-p-phenylenediamine  and  aniline  ace- 
tone, acid  derivatives 

145 

Ditohiamines... 

91.. 

Di-o-tolvlethylenediamine .  . 

X 

Di-o-tolvlguanidine  salt  of  dicatechol  borate..  .. 

64 

64 

04 

Isopropoxy  diphenylamine 

91 

p-Methyl-p-(p-tolylsulfonylamino)   diphenyl- 
amine..        _  ..  

X 

91  

Phenol-cvelchexanone  compound ... 

X 

Phenyl-a-naphthvlamine 

64,  148 

Phenv  1-b-naphthylamine 

64,86,91 

X 

Polyethylene  polyamine  plus  b-naphthol 

X 

Thiophenvl-b-naphthylamine       .'-  

X  

2:2:4-Trimethvldihydroquinoline  and  polymers. . 

91. 

Other  coal-tar  rubber  chemicals 

X... 

Total  coal-tar  rubber  chemicals 

29, 202,  343 

20,  909,  372 

$8, 193,  890 

$0.39 

64,145. 

(b)  non-coal-tar 
Accelerators: 

Aldehyde  ammonia 

Dimethylaminodimethyldithiocarbamicacid, 
zinc  salt _.  __  .     _  

X 

Dipenta  methylene  thiouramtetra  sulfide 

64 

Dithiocarbamates: 

Lead  dimethyl 

232 

Zinc  dibutvl 

X 

Zinc  diethvl 

232,  X 

Zinc  dimethyl 

X,  X 

p-Nitrcsodimethylarnine..   .     

64 

Tetramethylthiouram  sulfide  and  disulfide 

Trieth  vlt  rimethylenetriamine 

64,  X,  X,  X. 
X 

400, 299 

326,  071 

742,  115 

2.28 

Xanthates: 

Di-n-butvlxantho  disulfide 

X 

Dixanthogen       .      

93 

Potassium  amy] 

93,  145 

Potassium  butvl 

8,  93,  145 

93,  145    . 

Potassium  isopropyl ...... 

93,X 

93 

Sodium  butvl.     

X  .. 

Sodium  ethyl 

93,  145 

Zinc  butyl-     .  ... 

X,  X 

X 

144 

X  X 

0  ther  rubber  chemicals 

X 

Total  non-coal-tar  rubber  chemicals.1 

1  Not  publishable.    Included  in  "Miscellaneous"  synthetic  chemicals  of  non-coal-tar  origin. 


48 


UNITED    STATES    TARIFF    COMMISSION 


MISCELLANEOUS  CHEMICALS 

Miscellaneous  coal-tar  chemicals  were  produced  by  43  makers,  and 
those  not  of  coal-tar  origin  by  89  makers,  in  1937.  Table  15  shows 
production  and  sales. 

Coal-tar  products  included  herein  are  unrelated  commodities  and 
minor  products  not  properly  classified  under  any  of  the  other  groups. 
Statistics  of  production  and  sales  for  these  miscellaneous  groups  are 
not  comparable  with  those  for  earlier  years  because  of  the  inclusion 
of  products  heretofore  classified  elsewhere  or  the  transfer  of  subgroups 
to  other  classifications.  Diazo  salts  and  naphthol  AS  derivatives 
formerly  classified  here  are  combined  with  the  azoic  dyes  under  unclas- 
fied  dyes  in  this  report. 

Many  increases  in  quantity  occurred  in  the  products  of  the  group 
not  of  coal-tar  origin.  The  record  output  of  2,505,027,000  pounds 
was  24  percent  more  than  in  1936.  Sales  totaled  1,146,255,000  pounds 
valued  at  $110,306,000.  Production  of  acetic  anhydride  increased 
30  percent  and  the  increase  in  output  of  synthetic  acetic  acid  was 
even  greater.  Acetone  increased  31  percent,  the  butyl  alcohols  65 
percent,  and  carbon  tetrachloride  23  percent  in  1937  over  1936. 
Ethyl  acetate  production  declined  about  5  percent  and  isopropyl 
alcohol  about  6  percent. 


Table  15. 


-Miscellaneous  synthetic  chemicals:  United  States  production  and  sales, 
1937 


[The  numbers  in  the  second  column  refer  to  the  numbered  alphabetical  list  of  manufacturers  printed  on 
p.  54.  An  X  signifies  that  the  manufacturer  did  not  consent  to  the  publication  of  has  identification  num- 
ber with  the  designated  product.  Blanks  in  the  third,  fourth,  and  fifth  columns  indicate  that  the  statis- 
tics of  production  or  sales  cannot  be  published  without  revealing  information  in  regard  to  individual 
firms.    The  figures  thus  concealed  are,  however,  included  in  the  total] 


Manufacturers' 
identification 

numbers 
(according  to 
list  on  p.  54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(A)  COAL-TAR  ' 

Amino  diethyl  hvdroquinone 

X 

Pounds 

Pounds 

Benzoate  of  ammonia 

105,  145 

Benzoate  of  soda. 

64,  105,  145.X 

Benzoyl  peroxide  _ 

X    

Benzylated  phenol  (Santophens) 

145 

Biological  stains  and  chemical  indica- 

125, 148,  211,  X 

tors. 
Butvl  catechol 

X. 

Cresophan 

X 

Cyclanol 

64 

Oyclohexane 

64 

Cyclohexanone 

64 

Decahydronaphthalene  (Decalin) 

64 

Diamvl  hvdroquinone 

70,  145 

a-a-Dipyridy] 

71 

Ethylene  glycol  monophenyl  ether 

37 

Gases  (poisonous,  tear,  etc.): 

Chloroaeetophenone 

74- 

74,  X  .. 

Diphenylamine  chlorarsine 

74,168 

Hexalin  (C yclohexanol) 

64,  105 

Insecticides  (synthetic):  Aliphatic  thi- 

X 

ocyanates. 
Methyl  cvclohexanone 

64 

Methyl  hexalin  (Methyl  cyclohexanol) 

64,  105 

Naphthanil  red  for  printing 

64 

Naphthanil  scarletfor  printing.. 

64  .. 

o-Phenyl  mercaptobenzothiazole... 

X 

Phloroglucinol    

71 

1 

1  Fast  color  salts  and  naphthol  AS  derivatives  are  included  in  unclassified  dyes  under  azoic  dyes  and 
their  components. 


DYES   AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


49 


Table  15. — Miscellaneous  synthetic  chemicals:  United  States  production  and  sales, 

1 937—  Continued 


Manufacturers' 
identification 

numbers 
(according  to 
list  on  p.  54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(A)  coal-tar — continued 
Photographic  chemicals,  total 

Pounds 
1,  762,  201 

Pounds 
1,  443, 755 

$1,  516,  327 

$1  05 

71.... 

C atechol  ( Pyrocateehin) 

145,168 

Diaminophenol  hydrochloride 

224 

(Amidol). 

54,  70,  224,  234.X... 
70,  7J,X,  X 

L,  220  253 

1, 133, 139 

816,337 

.72 

p-Hvdroxy  phenylglycine 

Methyl     p-aminophenol     sulfate 

64,  70,  224,  X,  X 

X... „ 

205,  987 

(Metol)  (Rhodol). 
Tertiarybutvl  pyrogallol  (Rubinol) 

Phthalates,  total 

15, 082,  440 

13,  282, 818 

2,  496,  314 

.19 

Diamyl       

120,  219,  X.... 

Dibutoxy  ethvl 

161 

Dibutyl 

8,  54,  64,  120,  145, 

219,  X. 
64 

6,  963,  625 

5,  760, 967 

986,  295 

.17 

Dicyclohexyl 

Diethoxy  ethyl. 

161 

Diethyl 

145,  219,  X,X 

64,  161 

1, 288,  491 

1, 106, 939 

193,  426 

.17 

Dimethoxy  ethyl 

Dimethyl 

8,  54, 145,  219,  X,  X. 
64 

Dimethyl  cyclohexyl 

Diphenyl 

145 

Potassium  butyl 

64 

Sodium  butyl 

64 

Sodium  ethyl  butyl 

64 

Other 

64 

Phthalyl  glycollate  plastieizer 

145 

Printsol  colors: 

Blue  B 

148 

Bordeaux  R 

148    

Orange  G 

148 

Red  G 

148 

Scarlet  B. 

148. 

Quinhydrone 

70.X... 

Quinone       

70 

Research  chemicals 

6.70,  169.X 

Sodium  dicresyld ithiophosphate 

X 

Tanning  materials  (synthetic) 

8,  22,  45,  86,   145, 

148,  154,  X,  X. 
64..            

Tetrahydronaphthalene  (Tetralin) 

Textile  chemicals,  total 

Other  products 

7, 8,  64,  86, 145, 148, 
X,X. 
64,  70,  145 

3, 080,  251 

2, 952, 293 

779,  674 

.26 

Total     miscellaneous     coal-tar 
chemicals: 
Those  for  which  individual 

statistics  are  shown. 
Those  for  which  individual 
statistics  cannot  be  shown. 

Grand  total 

12,  758,  607 
29,  636,  576 

10,  953,  338 
25,  472,  475 

2,  775,  732 
5,  280,  132 

.25 

.21 

42, 395,  183 

36,425,813 

8,  055, 864 

.22 

(B)   NON-COAL-TAE 

37,  154,  X 

154 

62,  105 

37,  54,  154,  219,  X._ 
37,  62,  70,  X,  X.___ 

86,  102,  X 

125,509,931 
177,  488, 353 

144,  152 
124,  012,  187 

Acetic  anhydride  (from  all  sources  (100 

percent). 
Acetin  (mono,  di,  tri) 

130,  080 
68,  772,  268 

40,  378 
3.  586,  971 

.31 

37,    54,    180,    196, 

219,  X. 
70,  X        

.05 

87,  X 

70,  71 

70,  71.  . 

Allyl  isothiocyanate  (synthetic  mus- 
tard oil). 
Aluminum  formate 

X 

154,225 

1 -- 

50 


UNITED    STATES    TARIFF    COMMISSION 


Table  15.- 


-  Miscellaneous  sy?ithetic  chemicals:  United  States  production  and  sales 
1937—  Continued 


Manufacturers' 
identification 

numbers 
(according  to 
list  on  p.  54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(b)  non-coal-tar— continued 

Amines: 

Amyl  (mono,  di,  tri) 

X.... 

Pounds 

Pounds 

Butyl: 

Di 

X... 

Tri 

64,  X 

Ethyl: 

Mono 

28-.. 

Di __ 

232 

Methyl: 

Mono 

6,  54,64 

Di.... 

54,  64 

Tri 

64.... 

Ammonium  oxalate.   

87 

Ammonium  stearate 

X 

Amyl  acetate,  total 

11,796,710 

$1,  236,  678 

$0  10 

Normal  (90  percent) 

54,  64,  180,  194,  219. 
X.. 

Secondary  (90  percent) 

Iso  (90  percent) 

81, 120,  159,  219,  X, 
X. 

^myl  alcohol,  total 

14,  205,  997 

Normal  (100  percent). 

04,  194,  219 

Secondary  (100  percent) 

X 

Iso  (100  percent) 

SI,  120,  X,  X 

Amyl  chloride 

X 

X  .. 

Amyl  mercaptan 

X 

Amyl  propionate 

81 

Butyl  acetate,  total ". 

76,  352, 160 

62,  167,  685 

5,  382, 888 

.09 

Normal  (90  percent) 

37,  54,  64,  81,  145, 

180,  219. 
X 

Secondary  (90  percent) 

Iso  (90  percent) 

64,  X 

Butylacetyl  ricinoleate 

54 

Butyl  alcohol,  total 

124,  464,  656 

40, 806,  856 

3,  322,  689 

.08 

Normal  (100  percent) 

37,  54,  159,  180,  219. 
196,  X 

Secondary  (100  percent) 

Tertiary  (100  percent) 

64,  196 

Butyl  aldehyde 

37,  54 

n-Butyl  bromide... 

70,  188 

Butyl  chloride 

64,  105-.. 

Butyl  lactate.  

54 

n-Butyl  methacrylate 

64 

Butyl  oleate 

54... 

Butyl  propionate  (100  percent) 

81,  219 

Butyl  stearate . 

54,  120 

n-Butyric  acid 

37,  70,  159  . . 

Butyric  anhydride 

37 

Butyryl  chloride  

105... 

Caffeine  (from  Theobromine)—    . 

141,  145 

Calcium  lactate 

9,  195...  . 

Calcium  malonate 

X 

Calcium  propionate 

64  .. 

Camphor  (synthetic) 

64,  151 

n-Caproic  acid.. 

136,  159 

Carbon  tetrachloride 

62,93,156,212,229,X. 
155... 

84, 112,  245 

74,417,244 

3, 046,  448 

.04 

Carbonyl  choloride  (Phosgene)... 

Chlorinated  solvents 

25... 

Chloroacetic  acid  (mono  and  di) 

62... 

Chloroacetone 

70 

Chloroacet vl  chloride 

62  .. 

Chloroform  (tech.  and  U  S  P) 

30,62,64,93 

171.. 

2,  657, 167 

1, 948,  656 

335, 437 

.17 

Chloromethoxy   bis   diazoethylenedi- 

amino  diacetic  acid. 
Citric  acid,  refined  (fermentation) 

47,  143,  X 

Copper  lactate. 

195 

Crotonaldeh  vde 

37,  154 

Crotonic  acid 

154  .. 

Diacetone  alcohol 

37,  54,  145,  196 

37,  70 

3, 063, 136 

Diacetyl 

Diaminodiacetic  acid  . 

171  . 

Diaminoisopropanol 

62  .. 

n-Dibutylamine  diaminoisopropanol-.. 

64 

Dibutyl  ether  (n-Butvl  ether) 

54... 

Dibutyl  oxalate  

219 

Dibutyl  sebar-ate.. 

6,  161,209 

» 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


51 


Table  15. — Miscellaneous  synthetic  chemicals:  United  States  production  and  sales 

1987—  Continued 


Manufacturers' 
identification 

numbers 
(according  to 
list  on  p.  54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(b)  non-coal-tar — continued 
Dibutvl  tartrate 

54,  64,  120 

209 - 

Pounds 
22,058 

Pounds 

Dicapryl  alcohol 

209 - 

121 

37 

64 

37 - 

121 

121. 

X 

37 

37,  X 

219 

X... 

37 

37,  70 

37 

37  .. 

161— 

37.  „ 

37  .. 

acetate. 

37 

37 

acetate. 

37 

37 

28 

X 

X 

X 

37 

64    . 

6,  70,  169,  188  .. 

64     . 

64 

X 

37,  54,  64,  79,  81, 

145,  180,  219. 
37,  219 

69, 637, 571 

44,  339,  330 

$2, 910, 222 

$0.07 

37 

1,  62... 

62 

37 

Ethyl  butvl  alcohol- 

37 

37 

Ethvl  chloride  Ctech.  and  USP) 

62,  64, 81, 85,  X 

219 

Ethvl   ether    (tech.,    USP    and    ab- 

37, 64, 136, 143,  X 

solute.) 

54,  78,  81,  136,  159, 

219,  X,  X. 
37 

37 

37 

37 

Ethvl  lactate 

X 

136 

62,  75 

81,  219 

75,  81,  219,  X,  X  .. 

37 

37 

Ethylenediamine  (medicinal  and  tech.) 

28  37 

171 

62,  72,  229 

37,  62 

37,  62 

37..            

37 

37 

161 

stearate  (Butoxy  ethyl  stearate) . 

Ethylene  glvcol  monoethvl  ether 

Ethylene    glycol     monoethyl     ether 

acetate. 

37          

37,  81 

52 


UNITED    STATES    TARIFF    COMMISSION 


Table  15. — Miscellaneous  synthetic  chemicals:  United  States  production  and  sales: 

1937 — Continued 


Manufacturers' 
identification 

numbers 

(according  to 

list  on  p.  54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
valut, 

i 

(B)  non-coal-tar— continued 

Ethylene  glycol  monomethyl  ether 

Ethylene    glycol    monomethyl    ether 

acetate. 
Ethylene    glycol    monomethyl    ether 

oleate  (Methoxy  ethyl  oleate). 

37 

Pounds 

Pounds 

: 

37 

161 

37 

1 

X 

I 

112 

64 

8  carbon  atoms). 

151 

! 

46,  64,  101 

64 

64,  225 

183 

Furfural  derivatives: 

183,  X 

183. 

183_._ 

I 

183,  X... - 

70,  136,234 

51 

263,  756 

51,  X 

X 

70 

X.. 

. 

51,  X 

37... 

37 

75 

62,  93 

37 

Hexameth vlenetetramine,  tech 

64,  101,  X 

X 

37,64,  X 

X 

Higher  alcohols  (containing  more  than 

64,  X 

5  carbon  atoms. 
Hydroxylamine  hydrochloride . 

188,  X 

188.. 

X. 

64... 

Isobutyr  aldehyde 

64 

64 

37,  219,  X 

Isopropyl  alcohol  (Isopropanol) 

37,  196,  219.  X 
105 

131,462,298 

Isopropyl  chloride 

Isopropyl  ether 

37,  196,  X 

3, 978, 267 

Ketones,  mixed 

64 

Lactic  acid: 

Edible  (100  percent).- 

9,  14,  48,  64,  195.... 
14,  64 

927, 329 

883, 961 

$195, 855 

$0.22 

Medicinal  (100  percent) 

Technical  (100  percent) 

9,  14,  48,  64,  195.... 

Levulinic  acid 

X. 

Malonic  acid-- 

X 

Mannitol— 

19 

Mesityl  oxide 

37,  54 

Methacrylic  acid 

64 

Methanol  (synthetic) 

37,  46,  54,  64 

125, 313, 631 

4, 827,  626 

.04 

Methyl  acetate  ..- 

154 

Methyl  acetoacetate -.. 

37 

Methyl  bromide 

62,93 



Methyl     chloride     (Chloromethane) 

(100  percent). 
Methyl  dichlorostearate 

64,  175,  226,  X 

X 

3, 404, 079 

3, 374,  955 

1, 074,  665 

.32! 

Methyl  formate 

54,  64,  X 

Methyl  isobutyl  carbinol 

37 



Methyl  isobutyl  carbinol  acetate 

37 

Methyl  isobutyl  ketone . 

37 

Methyl  lactate 

54    . 

Methyl  methacrylate 

64... 

Methyl  propyl  ketone 

196,  X 

Methyl  stearate.. 

105  . 

Methyl  succinate 

X... 

Methylamyl  ketone 

37  .. 

1-Methvlbutyl  bromide.. . 

1... 

Methylbutyl  ketone 

X... 

DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


53 


Table   15. 


-Miscellaneous  synthetic  chemicals:  United  States  production  and  sales 
1937 — Continued 


Manufacturers' 
identification 

numbers 
(according  to 
list  on  p. 54) 

Production 

Sales 

Name  of  chemical 

Quantity 

Value 

Unit 
value 

(B)  non-coal-tar— continued 
Methylene  chloride  (Dichloromethane) 

25,  62,  64,93. 

Pounds 

Pounds 

Methylethyl  ketone 

37,  196,  X 

37 

37 

87,  163,  225,  X 

154 

10,  247, 541 

9, 605, 180 

$1,030,137 

$0.11 

64,  101 

75 

X... 

Pentachloroethane - 

64... 

Pentaerythritol.. 

154 

64... 

Phorone.--  .  

37 

37  .. 

145  .. 

Polyglyeerol-abietic  acid  compound 

145... 

64,  70    . 

Propionic  anhydride .. 

37,  70 

Propionyl  chloride 

105 

n-Propyl  acetate 

X... 

64  .. 

37  ..             

28                

37,  62 

37,  64... 

37                     

70,  136,234 

70,  154,  X   . 

115,027 

99,812 

118,614 

1.19 

Rubber,  synthetic 

64,  X 

Sebacic  acid... 

209,  X.... 

64,  136,  225,  X.  . 

Sodium  lactate.. 

195      

219 

Sodium  oxalate.. 

87,  136,  225 

Sorbitol 

19 

154 

37,  64,  86,  X,  X,  X. 
X            

(Gardinols,  Igepons,  Intramines). 

145 

hyde  ammonia  compound. 

Tetrabromoethane    (Acetylene   tetra- 
bromide). 

Tetrachloroethane    (Acetylene    tetra- 
chloride). 

62 

64,  229  

62     

37    . 

Tetraethvl  lead 

64     . 

Tetraethylene  glycol  dimethy  ether... 

37 

54 

54 

64    . 

::::::::::::  .: 

62 

64,  229 

121 

37 

X 

54,  145  .. 

37 

37 

Triethylenetetramine 

28 

196,  X... 

62 

64  .. 

64 

Vanillin.    (See  table  12.) 

X 

37 

64,  X    . 

Xanthates.    (See  table  14.) 

64,  211,  X,  X 

Total  miscellaneous  non-coal-tar 
chemicals: 
Those  for  which  individual 

statistics  are  shown. 
Those  for  which  individual 
statistics  cannot  be  shown. 

952, 067, 910 
1,552,959,104 

443, 656,  368 
702,  599, 029 

27, 108, 608 
83, 197, 816 

.06 

.12 

2,505,027,014  1 1,146,255,397 

110,306,424 

.10 

1  Includes  non-coal-tar  rubber  chemicals. 


54  UNITED    STATES    TARIFF    COMMISSION 

APPENDIX 

Directory  of  manufacturers  of  dyes  and  other  synthetic  organic  chemicals,  1987 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Abbott  Laboratories 

Alston  Lucas  Paint  Co 

Althouse  Chemical  Co... 

Aluminum  Industries,  Inc 

Amalgamated     Dyestuff    &     Chemical 
Works,  Inc. 

Amecco  Chemicals,  Inc 

American  Aniline  Products,  Inc 

American  Cyanamid  Co 

American  Maize-Products  Co 

American  Pharmaceutical  Co.,  Inc 

American  Tar  &  Chemical  Co.. 

Ansbacher-Siegle  Corporation 

Ansul  Chemical  Co 

Apex  Chemical  Co.,  Inc... 

Arco  Co 

Arnold,  Hoffman  &  Co.,  Inc 

Aromatic  Products,  Inc 

Artifex  Products  Co 

Atlas  Powder  Co 

Augusta  Chemical  Co 

Bakelite  Corporation 

Barrett  Co 

Bates  Chemical  Co 

Beck,  Roller  &  Co..  Inc.. 

Belle  Alkali  Co 

Benzol  Products  Co 

Berkheimer,  J.  E.,  Manufacturing  Co... 

Bersworth,  F   C,  Laboratories 

Brooklyn  Color  Works,  Inc 

Brown  Co 

Brown,  Andrew,  Co 

Burroughs  Wellcome  &  Co.,  Inc 

Bush,  W.  J.,  &  Co.,  Inc 

Calco  Chemical  Co.,  Inc 

California  Flaxseed  Products  Co 

California  Ink  Co.,  Inc 

Carbide  &  Carbon  Chemicals  Corpora- 
tion. 

Carbogen  Chemical  Co 

Cams  Chemical  Co 

Catalin  Corporation  of  America 

Celluloid  Corporation 

Chemical  Manufacturing  Co.,  Inc 

Chemical  Specialties,  Inc 

Childs  Puip  Colors,  Inc 

Cincinnati  Chemical  Works,  Inc 

Cities  Service  Oil  Co 

Citro  Chemical  Co 

Clinton  Co 

Colasta  Co.,  Inc 

Coleman  &  Bell  Co 

Colloid  Chemical  Laboratories 

Collway  Colors,  Inc 

Colt's  Patent  Fire  Arms  Manufacturing 

Co. 
Commercial  Solvents  Corporation 

Commonwealth  Color  &  Chemical  Co 

Cooks  Falls  Dye  Works,  Inc 

Coopers  Creek  Chemical  Co 

Crown  Tar  Works   (division  of  Public 
Service  Co.  of  Colorado). 

Devoe  &  Raynolds  Co.,  Inc 

Diarsenol  Co.,  Inc 

Dodge  &  Olcott  Co 

Dow  Chemical  Co 

Dubin,  H.  E.,  Laboratories,  Inc.. 

du  Pont  de  Nemours,  E.  I.  &  Co 


14th  St.  and  Sheridan  Rd.,  North  Chicago,  111. 

1029  North  Throop  St.,  Chicago,  111. 

540  Pear  St.,  Reading,  Pa. 

2438  Beekman  St.,  Cincinnati,  Ohio. 

75  Hudson  St.,  New  York,  N.  Y.  (Newark,  N.  J.). 

75  Rockwood  St.,  Rochester,  N.  Y. 

50  Union  Square,  New  York,  N.  Y.  (Lock  Haven,  Pa.).  , 

30  Rockefeller  Plaza,  New  York,  N.  Y.  (Bound  Brook  ! 

and  Warners,  N.  J.,  Bridgeville,  Pa.). 
100  East  42d  St.,  New  York,  N.  Y.  (Roby,  Ind.). 
525  West  43d  St.,  New  York,  N.  Y. 
5910  Fremont  St.,  Duluth,  Minn. 
92  Chestnut  Ave.,  Rosebank,  Staten  Island,  N.  Y. 
Box  231,  Marinette,  Wis. 
225  West  34th  St.,  New  York,  N.  Y.  (Elizabethport, 

N.  J.). 
7301  Bessemer  Ave.,  Cleveland,  Ohio. 
55  Canal  St.,  Providence,  R.  I.  (Dighton,  Mass.). 
Springdale,  Conn. 

Delaware  Ave.,  and  Elm  St.,  Camden,  N.  J. 
Wilmington,  Del.  (Atlas  Point,  Del.,  Stamford,  Conn.). 
Box  660,  Augusta,  Ga. 
247  Park  Ave.,  New  York,  N.  Y.  (Bloomfleld  and  Bound 

Brook,  N.  J.). 
40  Rector  St.,  New  York,  N.  Y.  (Plants  throughout  the 

United  States). 
Scottdale  Rd.,  Lansdowne,  Pa. 
601  Woodward  Heights  Blvd.,  Detroit,  Mich.  (Ferndalo, 

Mich.). 
Belle,  W.  Va. 

237  South  St.,  Newark,  N.  J.  (Piscataway,  N.  J.). 
Kenton  Station,  Portland,  Oreg. 
609  Waverly  St.,  Framingham,' Mass. 
129-43  Cherry  St.,  Brooklyn,  N.  Y. 
404  Commercial  St.,  Portland,  Me.  (Berlin,  N.  H.). 
5431  South  Riverside  Drive,  Los  Angeles,  Calif. 
9  East  41st  St.,  New  York.  N.  Y.  (Tuckahoe,  N.  Y.). 
11  East  38th  St.,  New  York,  N.  Y.  (Linden,  N.  J.). 
Bound  Brook,  N.  J. 
3135  East  26th  St.,  Los  Angeles,  Calif. 
545  Sansome  St.,  San  Francisco,  Calif.  (Berkeley,  Calif.). 
30  East  42d  St.,  New  York,  N.  Y.  (South  Charleston, 

W.  Va.,  Niagara  Falls,  N.  Y.  (Whiting,  Ind.). 
South  Ave.,  Garwood,  N.  J. 
1377  8th  St.,  La  Salle,  111. 
Fords,  N.  J. 

290  Ferry  St.,  Newark,  N.  J. 
Ashland,  Mass. 

16  East  Sth  St.,  Holland,  Mich. 
43  Summit  St.,  Brooklyn,  N.  Y. 

P.  O.  Box  20,  Evanston  Station,  Cincinnati,  Ohio  (Nor- 
wood and  St.  Bernard,  Ohio). 
Bartlesville,  Okla.  (Tallant,  Okla.). 
Maywood,  N.  J. 
Clinton,  Iowa. 

Mechanic  St.,  Hoosic  Falls,  N.  Y. 
Main  and  Waverly  Aves.,  Norwood,  Ohio. 
21  West  St.,  New  York,  N.  Y. 
15  Market  St.,  Paterson,  N.  J. 

17  Van  Dyke  Ave.,  Hartford,  Conn. 

230  Park  Ave.,  New  York,  N.  Y.  (Terre  Haute,  Ind., 

Peoria,  111.,  Agnew,  Calif.). 
Nevins,  Butler,  and  Baltic  Sts.,  Brooklyn,  N.  Y. 
Cooks  Falls,  N.  Y. 
River  Rd.,  West  Conshohocken,  Pa. 
900  15th  St.,  Denver,  Colo. 

1  West  47th  St.,  New  York,  N.  Y.  (Louisville,  Ky.). 

72  Kingsley  St.,  Buffalo,  N.  Y. 

180  Varick  St.,  New  York,  N.  Y.  (Bayonne,  N.  J.). 

Midland,  Mich. 

250  East  43d  St.,  New  York,  N.  Y. 

Wilmington,  Del.  (Carneys  Point,  New  Brunswick, 
Perth  Amboy,  Arlington,  and  Newark,  N.  J.,  Car- 
rollville.  Wis'..  Belle,  W.  Va.,  Niagara  Falls,  N.  Y., 
El  Monte,  Calif.). 


DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


55 


Directory  of  manufacturers  of  dyes  and  other  synthetic  organic  chemicals,  1987- 

Continued 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Durite  Plastics,  Inc 

Dye  Specialties  Corporation 

Dyestuffs  &  Chemicals,  Inc 

Eakins,  J.  S.,  &  W.  R.,  Inc.— 

Eastern  Tar  Products  Corporation. 

Eastman  Kodak  Co 


Edwal  Laboratories,  Inc 

Ethyl-Dow  Chemical  Co 

Federal  Color  Laboratories,  Inc 

Federal  Laboratories,  Inc 

Felton  Chemical  Co.,  Inc 

Fiberloid  Corporation 

Fine  Colors  Co 

Florasynth  Laboratories,  Inc 

Ford  Motor  Co .. 

Foster-Heaton  Co 

Franco-American  Chemical  "Works- 
Fries  Bros... 

Fries,  George  G.,  &  Co.,  Inc 


Gane's  Chemical  Works,  Inc. 

Gebauer  Chemical  Co 

General  Aniline  Works,  Inc 


General  Chemical  Co. 
General  Electric  Co... 


General  Paint  Corporation 

General  Plastics,  Inc 

Goodrich,  B.  F.,  Co 

Goodyear  Tire  &  Rubber  Co... 

Great  Western  Electro-Chemical  Co. 

Guyan  Color  &  Chemical  Works 

Halowax  Corporation 

Hamilton  Laboratories,  Inc 

Hampden  Color  &  Chemical  Co 

Harmon  Color  Works,  Inc 

Hercules  Powder  Co 

Heresite  &  Chemical  Co 

Heyden  Chemical  Corporation 


Hilton-Davis  Chemical  Co 

HofTmann-LaRoche,  Inc 

Holland  Aniline  Dye  Co 

Hooker  Electrochemical  Co 

Huggins,  James,  &  Son 

Hynson,  Westcott  &  Dunning,  Inc 

Imperial    Paper    &    Color    Corporation 
(Pigment  Color  Division). 

Industrial  Dvestufl  Co 

Inland  Tar  Co 


Jamieson,  C.  E.,  &  Co 

Jasco,  Inc 

Jennison-Wright  Co 

Joanite  Corporation 

Johnson,  Charles  Eneu,  &  Co. 

Joliet  Wall  Paper  Mills 

Jones-Dabney  Co... 

Kay-Fries  Chemicals,  Inc 


Kentucky  Color  &  Chemical  Co.. 

Kessler  Chemical  Corporation.. 

Kinetic  Chemicals,  Inc 

Knoedler,  A.,  Co 

Kohnstamm,  H.  &  Co.,  Inc 

Koppers  Co.  (Tar  &  Chemical  Division) 


LaMotte  Chemical  Products  Co. 

Lavanburg,  Fred  L.,  Co.,  Inc 

Lehigh  Briquetting  Co 

Lewis,  John  D.,  Inc 

Lilly,  Eli,  &  Co.... 

Lucid ol  Corporation 

Lueders,  George,  &  Co.. 

Macher,  William,  &  Son 

Magruder  Color  Co.,  Inc 

Makalot  Corporation „.. 

Mallard,  A.  E_ 

Mallinckrodt  Chemical  Works.. 


5000  Summerdale  Ave.,  Philadelphia,  Pa. 

3  Bennett  St.,  Jersey  City,  N.  J. 

11th  and  Monroe  Sts.,  St.  Louis,  Mo. 

55  Berry  St.,  Brooklyn,  N.  Y. 

Lexington  Bldg.,  Baltimore,  Md.  (Baltimore,  Md., 
Norfolk,  Va.). 

343  State  St.,  Rochester,  N.  Y.  (Rochester,  N.  Y.,  Kings- 
port,  Tenn.). 

732  Federal  St.,  Chicago,  HI. 

Wilmington,  N.  C. 

4633  Forest  Ave.,  Norwood,  Ohio. 

185  41st  St.,  Pittsburgh,  Pa.  (Tunnelton,  Pa.). 

599  Johnson  Ave.,  Brooklyn,  N.  Y. 

Worcester  St.,  Indian  Orchard,  Mass. 

21-29  McBride  Ave.,  Paterson,  N.  J. 

1513-33  Olmstead  Ave.,  New  York,  N.  Y. 

3674  Schaefer  Rd.,  Dearborn,  Mich. 

833-39  Magnolia  Ave.,  Elizabeth,  N.  J. 

342  Madison  Ave.,  New  York,  N.  Y.  (Carlstadt,  N.  J.) 

92  Reade  St.,  New  York,  N.  Y.  (Bloomfield,  N.  J.). 

68  Beekman  St.,  New  York,  N.  Y.  (Long  Island  City, 
N.  Y.). 

43  West  16th  St.,  New  York,  N.  Y.  (Carlstadt,  N.  J.). 

826  Hanna  Bldg.,  Cleveland,  Ohio. 

435  Hudson  St.,  New  York,  N.  Y.  (Rensselaer  N.  Y., 
Grasselli,  N.  J.). 

40  Rector  St.,  New  York,  N.  Y.  (Buffalo,  N.  Y.). 

1  River  Rd.,  Schenectady,  N.  Y.  (Schenectady,  N.  Y., 
Pittsfield,  Mass.). 

3000  Sand  Springs  Rd.,  Tulsa,  Okla. 

Walck  Rd.,  North  Tonawanda,  N.  Y. 

500  South  Main  St.,  Akron,  Ohio. 

1144  East  Market  St.,  Akron,  Ohio. 

9  Main  St.,  San  Francisco,  Calif.  (Pittsburg,  Calif.). 

P.  O.  Box  1088,  Huntington,  W.  Va. 

247  Park  Ave.,  New  York,  N.  Y.  (Wyandotte,  Mich.). 

Hamilton,  Ohio. 

161  Armory  St.,  Springfield,  Mass. 

P.  O.  Box  1158,  Paterson,  N.  J.  (Haledon,  N.  J.). 

Delaware  Trust  Bldg.,  Wilmington,  Del. 

822  South  14th  St.,  Manitowoc,  Wis. 

50  Union  Square,  New  York,  N.  Y.  (Garfield  and  Perth 
Amboy,  N.  J.). 

Langdon  Farm  Rd.,  Cincinnati,  Ohio. 

Nutley,  N.  J. 

Holland,  Mich. 

60  East  42d  St.,  New  York,  N.  Y.  (Niagara  Falls,  N.  Y.). 

239  Medford  St.,  Maiden,  Mass. 

1030  North  Charles  St.,  Baltimore,  Md. 

Glens  Falls,  N.  Y.  (Queensbury,  N.  Y.). 

Massasoit  Ave.,  East  Providence,  R.  I. 

38  South  Dearborn  St.,  Chicago,  111.  (Indiana  Harbor, 

Ind.). 
1962-80  Trombly  Ave.,  Detroit,  Mich, 
c/o  Standard  Oil  Co.,  of  La.,  Baton  Rouge,  La. 
2463  Broadway,  Toledo,  Ohio. 
1002  44th  Drive,  Long  Island  City,  N.  Y. 
10th  St.  at  Lombard  St.,  Philadelphia,  Pa. 
Logan  Ave.,  Joliet,  111. 
1481  South  11th  St.,  Louisville,  Ky. 
180  Madison  Ave.,  New  York,  N.  Y.  (West  Haverstraw, 

N.  Y.). 
34th  St.  South  of  Bank  St.,  Louisville,  Ky. 
Delaware  Ave.  and  Mifflin  St.,  Philadelphia,  Pa. 
duPont  Bldg.,  Wilmington,  Del.  (Carney's  Point,  N.  J.). 
717  North  Prince  St.,  Lancaster,  Pa. 
87  Park  Place,  New  York,  N.  Y.  (Brooklyn,  N.  Y.). 
Koppers  Bldg.,  Pittsburgh,  Pa.  (Plants  throughout  the 

United  States). 
MeCormick  Bldg.,  Baltimore,  Md. 
105  Bedford  Ave.,  Brooklyn,  N.  Y. 
Universal  Bldg.,  Fargo,  N.  D.  (Dickinson,  N.  D.). 
68  Traverse  St.,  Providence,  R.  I.  (Mansfield,  Mass.). 
Indianapolis,  Ind. 
293  Larkin  St.,  Buffalo,  N.  Y. 

427  Washington  St.,  New  York,  N.  Y.  (Brooklyn,  N.  Y.). 
1533  West  Clearfield  St.,  Philadelphia,  Pa. 
2385  Richmond  Terrace,  Staten  Island,  N.  Y. 
262  Washington  St.,  Boston.  Mass.  (Waltham,  Mass.). 
3021  Wabash  Ave.,  Detroit,  Mich. 
3600  North  2d  St.,  St.  Louis,  Mo. 


56 


UNITED    STATES    TARIFF    COMMISSION 


Directory  of  manufacturers  of  dyes  and  other  synthetic  organic  chemicals,  1937 — 

Continued 


Name  of  company 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Marblette  Corporation 

Marx,  Max,  Color  &  Chemical  Co 

Maschmeijer,  A.,  Jr.,  Inc 

May,  Otto  B.,  Inc 

Maywood  Chemical  Works 

Mepham,  Geo.  S.,  Corporation... 

Merck  &  Co.,  Inc 

Minerec  Corporation 

Monsanto  Chemical  Co 

Moser,  Chas.,  Co 

Mutual  Chemical  Co.  of  America 

National  Aniline  &  Chemical  Co.,  Inc 

Naugatuck  Chemical  (division  of  United 

States  Rubber  Products,  Inc.). 

Neville  Co 

Newport  Industries,  Inc 

New  York  Color  &  Chemical  Co.,  Inc. 

(division  of  American  Dyewood  Co.). 
New  York  Quinine  &  Chemical  Works, 

Inc. 

Niacet  Chemicals  Corporation 

Niagara  Chlorine  Products  Corporation.. 
Niagara  Smelting  Corporation 

Niagara  Wall  Paper  Co 

Nord  &  Schulich,  Inc 

Northwestern  Chemical  Co 

Novocol  Chemical  Manufacturing  Co.»lnc. 

Ohio- A  pex,  Inc . 

Ohio  Chemicals,  Inc 

Oldbury  Electro  Chemical  Co 

Organic  Chemicals,  Inc 

Patent  Chemicals,  Inc 

Peaslee-Gauibert  Paint  &  Varnish  Co 

Peerless  Color  Co 

Pennsylvania  Coal  Products  Co 

Pfanstiehl  Chemical  Co 

Pfizer,  Chas.  Co 

Pharma  Chemical  Corporation.. 

Philadelphia  Gas  Works  Co 

Phoenix  Color  &  Chemical  Co 

Pitman-Moore  Co.,  Inc 

Pittsberg  Chemical  Co 

Pittsburgh  Plate  Glass  Co 

Plaskon  Co..  Inc 

Portland  Gas  &  Coke  Co.. 

Poughkeepsie  DyestufI  Corporation 

Publicker,  Inc 

Pylam  Products  Co.,  Inc 

Pyridium  Corporation 

Quaker  Oats  Co 

Rauh,  Robert,  Inc 

Reilly  Tar  &  Chemical  Corporation 

Republic  Creosoting  Co. 

Resinox  Corporation 

Rogers,  Allen  E.,  Laboratories,  Inc 

Ruberoid  Co 

Salvo  Chemical  Corporation 

Schering  &  Glatz,  Inc 

Seydel  Chemical  Co 

Sharp  &  Dohme,  Inc 

Sharpies  Solvents  Corporation 

Sheffield  By-Products  Co 

Shell  Chemical  Co 

Sherwin-Williams  Co.. 

Simons,  Harold  L.,  Inc.. 

Sinclair  &  Valentine  Co .. 

Smith,  Kline  &  French  Laboratories 

Solvay  Process  Co 

Southern  DyestufI  Corporation 

Squibb,  E.  R.,  &  Sons 

Standard  Alcohol  Co... 


37-21  30th  St.,  Long  Island  City,  N.  Y. 

192-4  Coit  St.,  Irvington,  N.  J. 

43  West  16th  St.,  New  York,  N.  Y.  (Newark,  N.  J.). 

198-214  Niagara  St.,  Newark,  N.  J. 

100  West  Hunter  Ave.,  Maywood,  N.  J. 

2001  Lynch  Ave.,  East  St.  Louis,  111. 

Rahway,  N.  J.  (Rahway,  N,  J.,  Philadelphia.  Pa.). 

120  Broadwav,  New  York,  N.  Y.  (Baltimore,  Md.). 

1700  South  2d  St.,  St.  Louis,  Mo.  (St.  Louis,  Mo.,  Mon- 
santo, 111.,  Everett,  Mass.,  Anniston,  Ala.,  Nitro, 
W.  Va.). 

21,5-27  East  9th  St.,  Cincinnati,  Ohio. 

270  Madison  Ave.,  New  York,  N.  Y.  (Jersey  City,  N.  J.). 

40  Rector  St.,  New  York,  N.  Y.  (Buffalo,  N.  Y.). 

1790  Broadway,  New  York.     (Naugatuck,  Conn.). 

Neville  Island,  Pittsburgh,  Pa. 
P.  O.  Box  1612,  Pensacola,  Fla. 
100  East  42d  St.,  New  York,  N.  Y.  (Belleville,  N.  J.). 

99-117  North  11th  St.,  Brooklyn,  N.  Y. 

4700  Pine  Ave  ,  Niagara  Falls,  N.  Y. 

Mill  St.,  Lockport,  N.  Y. 

420  Lexington  Ave.,  New  York,  N.  Y.  (Niagara  Falls, ' 

N.  Y.). 
Walnut  Ave.  and  2d  St.,  Niagara  Falls,  N.  Y. 
Foot  of  Blanchard  St.,  Newark,  N.  J. 
1263  North  70th  St.,  Wauwatosa,  Wis. 
2923  Atlantic  Ave.,  Brooklyn,  N.  Y. 
Nitro,  W.  Va. 

475  Dorchester  Rd.,  Akron,  Ohio. 
P.  O.  Box  346,  Niagara  Falls,  N.  Y. 
211  East  19th  St.,  New  York,  N.  Y. 
57  Wilkinson  Ave.,  Jersey  City,  N.  J. 
15th  and  Lvtle  Sts.,  Louisville,  Ky. 
521-35  North  Ave.,  Plainfield,  N.  J. 
Petrolia,  Pa. 

104  Lakeview  Ave.,  Waukegan,  111. 

81  Maiden  Lane,  New  York,  N.  Y.  (Brooklyn,  N.  Y.). 

949  Broadway,  New  York,  N.  Y.  (Bayonne,  N.  J.). 

1800  North  9th  St.,  Philadelphia,  Pa. 

24  Van  Houten  St.,  Paterson,  N.  J. 

1220  Madison  Ave.,  Indianapolis,  Ind. 

703  Market  St.,  San  Francisco,  Calif.  (Los  Angeles,  Calif.> 

235  East  Pittsburgh  Ave.,  Milwaukee,  Wis. 

2112  Sylvan  Ave.,  Toledo,  Ohio. 

Public  Service  Bldg.,  Portland,  Oreg. 

77  North  Water  St.,  Poughkeepsie,  N.  Y. 

260  South  Broad  St.,  Philadelphia,  Pa. 

799  Greenwich  St.,  New  York,  N.  Y.  (Norwalk,  Conn.). 

21  Grey  Oaks  Ave.,  Nepera  Park,  N.  Y. 

141  West  Jackson  Blvd.,  Chicago,  111.  (Cedar  Rapids, 
Iowa) . 

480  Frelinghuysen  Ave.,  Newark,  N.  J. 

1615  Merchants  Bank  Bldg.,  Indianapolis,  Ind.  (plants 
throughout  the  United  States). 

1615  Merchants  Bank  Bldg.,  Indianapolis,  Ind.  (plants 
throughout  the  United  States). 

230  Park  Ave.,  New  York,  N.  Y.  (Edgewater,  N.  J.). 

72  Grand  Ave.,  Brooklyn,  N.  Y. 

500  Fifth  Ave.,  New  York,  N.  Y.  (Erie,  Pa.,  Joliet,  111.;. 

Rothschild,  Wis. 

113  West  18th  St.,  New  York,  N.  Y. 

86  Forrest  St.,  Jersey  City,  N.  J. 

640  North  Broad  St.,  Philadelphia,  Pa. 

23d  and  Westmoreland  Sts.,  Philadelphia,  Pa.  (Wyan- 
dotte, Mich.). 

524  West  57th  St.,  New  York,  N.  Y.  (Hobart,  N.  Y.). 

100  Bush  St.,  San  Francisco,  Calif.  (Martinez  and 
Dominguez,  Calif.). 

101  Prospect  Ave.,  N.  W.,  Cleveland,  Ohio  (Chicago,  111.). 
11-25  44th  Rd.,  Long  Island  City,  N.  Y. 

611  West  129  th  St.,  New  York,  N.  Y. 

105  North  5th  St.,  Philadelphia,  Pa. 
Svracuse,  N.  Y.  (Geddes,  N.  Y.). 
P.  O.  Box  1045,  Charlotte,  N.  C. 

745  Fifth  Ave.,  New  York,  N.  Y.  (Brooklyn,  N.  Y., 

New  Brunswick,  N.  J.). 
26  Broadway,  New  York,  N.  Y.  (Linden,  N.  J.). 


DYES    AND    OTHER    SYNTHETIC    ORGANIC    CHEMICALS 


57 


Directory  of  manufacturers  of  dyes  and  other  synthetic  organic  chemicals,  1937- 

Continued 


No- 


Name  of  company 


Standard  Naphthalene  Products  Corpora- 
tion. 

Standard  Ultramarine  Co .. 

Stange,  William  J.,  Co 

Sun  Chemical  &  Color  Co.  (division  of 
General  Printing  Ink  Corp.) 

Swann  <fe  Co 

Synthetic  Chemicals,  Inc 

Synthetical  Laboratories 

Taylor  Chemical  Corporation -. 

Taylor  Fibre  Co 

Todd,  A.  M.,  Co 

Trubek  Laboratories,  Inc 

Turner  &  Hefler  Co 

Uhlich,  Paul,  &  Co.,  Inc 

United  Color  &  Pigment  Co.,  Inc 

U.  S.  Industrial  Chemical  Co 

Valentine  &  Co.,  Inc ..- 

van  Ameringen-Haebler,  Inc 

Van  Dyk  &  Co.,  Inc . 

Varcum  Chemical  Corporation 

Verona  Chemical  Co 

Victor  Chemical  Works 

Virginia  Smelting  Co r 

Warner-Jenkinson  Manufacturing  Co 

Watertown  Manufacturing  Co 

Westvaco  Chlorine  Products  Corporation 

White  Tar  Co.,  of  N.  J.,  Inc 

Wilhelm,  A.,  Co.  (division  of  Glidden  Co.) 
Wolff  Alport  Chemical  Corporation... 

Young  Aniline  Works,  Inc 

Zinsser  &  Co.,  Inc 


Office  address  (location  of  plant  given  in  parentheses  if 
not  in  same  city  as  office) 


Jacobus  Ave.,  South  Kearny,  N.  J. 

Huntington,  W.  Va. 

2536  West  Monroe  St.,  Chicago,  111. 

309-21  Sussex  St.,  Harrison,  N.  J.  (East  Rutherford  and 

Harrison,  N.  J.) 
3205  Avenue  B,  Birmingham,  Ala. 
57  Wilkinson  Ave.,  Jersey  City,  N.  J. 
5558  Ardmore  Ave.,  Chicago,  111. 
Phillipsburg,    N.   J.    (Wyandotte,    Mich.,    Penn    Yan, 

N.  Y.) 
P.  O.  Box  470,  Norristown,  Pa.  (Betzwood,  Pa.). 
1717  Douglas  Ave.,  Kalamazoo,  Mich. 
State  Highwav  No.  2,  East  Rutherford,  N.  J. 
3fi  Barrv  St.,  Hyde  Park,  Mass. 

157  Chambers  St.,  New  York,  N.  Y.  (Brooklyn,  N.  Y.) 
McClellan  St.,  Newark,  N.  J. 

60  East  42d  St.,  New  York,  N.  Y.  (Baltimore,  Md.). 
11  East  36th  St.,  New  York,  N.  Y.  (Brooklyn,  N.  Y.). 
315  Fourth  Ave.,  New  York,  N.  Y.  (Elizabeth,  N.  J.). 
57  Wilkinson  Ave.,  Jersey  City,  N.  J. 
P.  O.  Box  433,  Niagara  Falls,  N.  Y. 
26  Verona  Ave.,  Newark,  N.  J. 
141  We,st  Jackson  Blvd.,  Chicago,  111.  (Chicago  Heights, 

111.). 
West  Norfolk,  Va. 
2526  Baldwin  St.,  St.  Louis,  Mo. 
127  Echo  Lake  Rd.,  Watertown,  Conn. 
405  Lexington  Ave.,  New  York,  N.  Y.  (South  Charleston, 

W.  Va.). 
1201  Koppers  Bldg.,  Pittsburgh,  Pa.  (Kearny,  N.  J.). 
Third  and  Bern  Sts.,  Reading,  Pa. 
1127  Irving  Ave.,  Brooklvn,  N.  Y. 
2701  Boston  St.,  Baltimore,  Md. 
Hastings-on-Hudson,  N.  Y. 


o