-£"
t
Given By
U. S. SUPT. OF DOCUMENTS
^
UNITED STATES TARIFF COMMISSION
SYNTHETIC
ORGANIC CHEMICALS
UNITED STATES PRODUCTION
AND SALES
1939
REPORT No. 140
SECOND SERIES
BOSTON PUBLIC LIBRARY
3 9999 06317 193 6
RECENT REPORTS OF THE UNITED STATES
TARIFF COMMISSION
Earthen Floor and Wall Tiles, Report No. 141, Second Series, 1940 In press
Glues, Gelatins, and Related Products, Report No. 135, Second Series, 1940 .... $0.25
Italian Commercial Policy and Foreign Trade, Report No. 142, Second Series,
1940 In press
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Starches and Dextrines, Report No. 138, Second Series, 1940 In press
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Grapes, Raisins, and Wines, Report No. 134, Second Series, 1939 60
Incandescent Electric Lamps, Report No. 133, Second Series, 1939 25
Changes in Import Duties Since the Passage of the Tariff Act of 1930, Miscel-
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Rules of Practice and Procedure and Laws Relating to the United States Tariff
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For Sale by the Superintendent of Documents, Government Printing Office, Washington, D. C,
at the prices indicated
UNITED STATES TARIFF COMMISSION
SYNTHETIC ORGANIC CHEMICALS
UNITED STATES PRODUCTION
AND SALES
1939
REPORT No. 140
SECOND SERIES
UNITED STATES
GOVERNMENT PRINTING OFFICE
WASHINGTON : 1910
For Bale by the Suiie'intendent of Documents, Washington, D. C, Price 10 cents
U. S. SUPERINTENDENT OF OOGUMEN^
OCT 14 1940
UNITED STATES TARIFF COMMISSION
RAYMOND B. STEVENS, Chairman
OSCAR B. RYDER, Vice Chairman
EDGAR B. BROSSARD
E. DANA DURAND
A. MANUEL FOX
SIDNEY MORGAN, Secretary
Address All Communications
UNITED STATES TARIFF COMMISSION
WASHINGTON, D. C.
CONTENTS
TEXT
Acknowledgment v
Introduction , ^ 1
PARTI
Summary, 1939 1
PART II
Production and sales by groups, 1939:
Coal-tar crudes 5'.
Coal-tar intermediates 6
Coal-tar dyes 16
Color lakes and toners 31
Medicinals 34
Flavors and perfume materials 3S
Resins 42
Rubber chemicals 43
Miscellaneous chemicals 4&
APPENDIXES
A. Research expenditures 57
B. Imports 57
C. Directory of manufacturers of sj'nthetic organic chemicals, 1939 58^
STATISTICAL TABLES
1. Comparison of United States production of tar and production and
sales of certain crudes, average 1925-30, annual 1936-39 2
2. Intermediates, dyes, and other coal-tar chemicals: Summary of United
States production and sales, 1939 g:
3. Intermediates, dyes, and certain other classes of coal-tar chemicals:
Comparison of United States production and sales, average 1925-30,
annual 1936-39 4
4. Synthetic organic chemicals of non-coal-tar origin: Summary of United
States production and sales, 193i9 4
5. Synthetic organic chemicals of non-coal-tar origin: Comparison of
United States production and sales, average 1925-30, annual 1936-
39 5-
6. Coal-tar crudes: United States production and sales, 1939 6
7. Coal-tar intermediates: United States production and sales, 1939 7'
8. Comparison of United States production and sales of dj'es by classes of
application, average 1925-30, annual 1938 and 1939 16
9. Coal-tar dyes: United States production and sales, by types, 1939 17
10. Color lakes and toners: United States production and sales, 1939 32"
11. Synthetic medicinals: United States production and sales, 1939:
(A) Coal-tar 34
(B) Non-coal-tar ST
12. Svnthetic flavors and perfume materials: United States production and
'sales, 1939:
(A) Coal-tar ._ 39
(B) Non-coal-tar^ .-. 40
13. Synthetic resins: United States production and sales, 1939:
(A) Coal-tar 42'
(B) Non-coal-tar 43
14. Synthetic rubber chemicals: United States production and sales, 1939:
(A) Coal-tar 43-
(B) Non-coal-tar 45-
15. Miscellaneous synthetic organic chemicals: United States production
and sales, 1939:
(A) Coal-tar 4r
(B) Non-coal-tar 48-
16. Imports of finished coal-tar products, classified by uses, and of coal-tar
intermediates, into the United States, 1939 and 1938 hT
III
ACKNOWLEDGMENT
In the preparation of this report, the Commission had the services
of W. F. SterHng and Bertha M. Robertson of the Chemical Division,
and of others.
SYNTHETIC ORGANIC CHEMICALS, UNITED STATES
PRODUCTION AND SALES, 1939
INTRODUCTION
The United States Tariff Commission's twenty-third annual report
on the production and sales of synthetic organic chemicals in the
United States includes all synthetic organic chemicals grouped under
the following classifications: Coal-tar crudes, intermediates, dyes,
color lakes, and toners; coal-tar and non-coal-tar medicinals, flavors,
and perfume materials, resins, rubber chemicals, and miscellaneous
chemicals. For the first time separate figures are shown for non-coal-
tar rubber chemicals, and for plasticizers, both coal-tar and non-
coal-tar. Among the synthetic products reported first in 1939 are
synthetic ephedrine, sulfapyridine, and hormones.
Many of the basic products included in this report are essential to
national well-being and to national defense. Toluol (p. 6) and
phenol (p. 14) are the raw materials for the very important military
explosives, trinitrotoluene and picric acid, and are considered by the
War Department to be critical materials.
Incidental to the collection of production and sales statistics, the
Commission has from time to time compiled data on research ex-
penditures by the synthetic organic chemical industry in order to
obtain information on the relationship between research and develop-
ment in the industry. A summary of research expenditures in 1939
is shown in appendix A of this report.
The Tariff Commission also cooperates with the Department of
Commerce in the analysis of imports of coal-tar intermediates and
finished products. These data are issued semiannually by the De-
partment of Commerce.^ A summary of the data obtained in these
analyses for 1938 and 1939 is given in appendix B.
Three hundred and six companies reported production and sales of
synthetic organic chemicals in 1939. Appendix C is a directory of all
manufacturers who have given permission to be identified as producers.
PART L— SUMMARY, 1939
Activity in the synthetic organic chemical industry, as a whole,
increased sharply in 1939 over 1938, and exceeded that in the previous
peak year, 1937.
The acceleration in the rate of coke-oven operations resulted in an
increase of almost a third in coal-tar production. Greater market
demand caused increased production of crude products from tar.
The output of toluene or tuluol, the raw material for the military
explosive, trinitrotoluene, commonly called T. N. T. was the highest
on record.
I United States Imports for Consumption of Dves, Aromatic Chemicals, Medicinals, Intermediates, and
other Coal-Tar Products, as defined in Paragraphs 27 and 28 of the TaritI Act of 1930, Semiannual Statement
No. 2865.
UNITED STATES TARIFF COMMISSION
The production of coal tar, and the production and sales of crudes
produced in large volume are shown in table 1 for the years 1939,
1938, 1937, 1936, and the average for the period 1925-30.
Table 1. — Comparison of United States production of tnr and production and sales
of certain crudes, average 1925-30, annual 1936-39
[Production and sales in thousands of gallons, value in thousands of dollars]
Product
Average,
1925-30
1936
1937
1938
1939
Increase,
1939 over
1938
Tar produced
630, 536
22, 257
22, 257
4,651
96, 879
96, 879
15, 920
44, 762
44, 762
581
95, 443
95, 443
11,742
560, 386
19, 413
19, 145
2,676
85, 673
84, 762
7,629
89, 536
74, 054
1,466
101, 758
93, 216
10, 294
603, 053
26, 795
22, 141
2,928
95, 527
93, 767
8.385
115,979
109, 394
2,535
107, 294
107, 485
12, 472
419, 580
17, 745
17, 176
2,317
61, 903
61,221
6,064
53, 584
50, 693
979
88, 067
88, 713
10, 820
554, 406
30, 470
26, 628
3,618
86, 246
81, 672
7,679
104, 086
87, 837
1,517
110,242
101. 487
12, 385
Percent
32.1
Benzol:
Production . - _. .
71.7
Sales .. ...
55.0
Sales value . .. .-_
56.2
Motor benzol:
Production
Sales
Sales value . ... .
39.3
33.4
26.6
Naphthalene:
Production '
Sales 1 .
94.2
73.3
Sales value
55.0
Creosote oil:
Production
Sales
Sales value . .
25.2
14.4
14.5
1 Thousands of pounds.
Source: Compiled from data reported to the Tariff Commission and to the Bureau of Mines.
The combined sales of all synthetic organic chemicals in 1939 were
valued at $384,343,000, and not only exceeded by 39 percent those in
1938, a year of poor chemical sales, but surpassed the value of sales
in any preceding year. The increase in sales value of coal-tar chemicals
over 1938 was 42 percent, or from $130,462,000 to $184,645,000, and
in non-coal-tar synthetic organic chemicals 36 percent, or from
$146,435,000 to $199,698,000. The groups showing the largest
percentage increase in sales value were intermediates, medicinals,
and synthetic resins. The peak activity in synthetic organic chemi-
cals in 1939 resulted from improved business conditions, a building
up of inventories by both producers and consumers, and increased
exports in the last quarter, particularly to countries whose imports of
synthetic chemicals formerly came chiefly from the European bel-
ligerents. Although official export statistics do not give a total for
all synthetic organic chemicals, it is known that exports of these
synthetic products advanced considerably in 1939. The value of
exports of all coal-tar chemicals was $9,891,000 in 1938 and
$14,612,000 in 1939.
No significant increases in unit values of sales of synthetic organic
chemicals occurred in 1939. Virtually all important raw materials for
synthetic organic chemicals are abundant in the United States and in
general have not advanced in price.
In 1939 a large part of the output of synthetic organic chemicals
was consumed, as in preceding years, by producers in the manufacture
of other chemicals. More than half of the coal-tar mtermediates and
of miscellaneous non-coal-tar chemicals, as well as smaller fractions
of some of the other groups, was thus consumed by the producing com-
panies. Accordingly the quantity of production is in excess of the
SYNTHETIC ORGANIC CHEMICALS 3
quantity of sales in some group totals and in many individual com-
modities appearing in the tables in this report.
Each product reported by the manufacturers is listed in the de-
tailed tables shown in this report. Statistics of production and sales
are given for as many separate chemicals as is possible without
disclosing information concerning the operations of individual com-
panies. The Commission withholds statistics for a product or a
group of products unless at least three firms report, and unless the
total production and sales are well distributed among the three or
more firms. In nearly all instances the absence of numerical data
indicated by a blank in the detailed tabulations is not because of a
lack of production or sales figures, but because these data are con-
fidential. All such figures, however, are included in their respective
group totals.
Sales statistics given in the tables are intended to reflect only sales
of chemicals produced by the seller. Every effort has been made to
eliminate resales of purchased merchandise and intercompany
transfers.
Group totals for 1939 are comparable with those for 1938 except in
one instance. The total of non-coal-tar rubber chemicals, heretofore
included under the total of the miscellaneous chemicals group, is
shown separately in 1939. This change, however, is a minor one and
does not affect appreciably the miscellaneous non-coal-tar chemicals
total for comparative purposes.
The production and sales of intermediates and finished coal-tar
products in 1939 are summarized in table 2, and a comparison of pro-
duction and sales in 1939 with 1938, 1937, and 1936, and with the
1925-30 average is shown in table 3.
Table 2. — Intermediates, dyes, and other coal-tar chemicals: Suminary of United
States production and sales, 1939
[Production and sales in thousands of pounds, value in thousands of dollars]
Number
of manu-
facturers
Produc-
tion
Sales
Product
Quantity
Value
Value per
pound
Intermediates-
63
221
607, 175
437, 867
269, 084
353, 604
38. 489
146, 156
$0.14
Finished products, total . .
.41
Dyes:
Classified ...
99, 564
20, 627
95, 074
19, 420
48, 018
22, 206
.50
Unclassified .
1.14
43
48
44
30
64
10
51
Total..
120, 191
114, 494
70, 224
.61
Color lakes and toners ..
18, 154
15, 188
5.349
179,338
29, 966
69, 681
15, 577
12, 932
4,938
128. 420
20, 965
56, 278
11,785
1.3, 711
4,447
23, 028
10, 081
12,880
.76
Medicinals
Flavors and perfume materials
1.06
.90
.18
.48
Miscellaneous!
.23
• Includes benzoate of ammonia, benz.oate of soda, benzoyl peroxide, biological stains and chemical indi-
cators, poisonous and tear gases, synthetic insecticides, photographic cliemicals, plasticizers, synthetic
tanning materials, textile chemicals, and others.
252005—40 2
4 UNITED STATES TARIFF COMMISSION
Table 3. — Intermediates, dyes, and certain other classes of coal-tar chemicals:
Comparison of United States production and sales, average 1925-30, annual
1936-39
[Production and sales in thousands of pounds, value in thousands of dollars]
Product
Average,
1925-30
1936
1937
1938
1939
509, 706
223,119
31, 806
575, 893
242, 194
35, 639
401, 943
171,514
26, 090
607, 175
269.084
38, 489
336, 348
287, 276
120, 765
373, 063
315,742
128, 736
276, 387
245, 340
104, 372
437, 867
353, 604
146, 156
119,523
117, 573
63. 686
122, 245
118,046
64, 613
81, 759
87, 803
53, 096
120, 191
114. 494
70, 224
12, 034
10, 079
9,763
14, 800
1 1, 989
11, 496
11,097
8,885
9,509
15, 188
12, 932
13, 711
3,481
3,437
3,220
4, 356
3,907
3,983
3.837
3, 664
3,368
5, 349
4,938
4,447
117,302
86, 214
17,056
142, 025
109, 201
20, 582
106, 923
84, 764
15, 811
179, 338
128,420
23,028
Increase,
1939 over
1938
Intermediates:
Production
Sales
Sales value
Finished coal-tar products: '
Production
Sales _.-
Sales value
Dyes:
Production
Sales -
Sales value
Medicinals:
Production
Sales
Sales value
Flavors and perfume materials:
Production
Sales
Sales value
Resins:
Production
Sales
Sales value
267, 492
109, 133
22, 408
138,078
133, 964
65, 027
94, 003
92, 207
39, 428
4,508
4,106
7,464
3,966
3,919
2,901
J 24, 442
» 22, 135
2 7, 766
Percent
51.1
56.9
47.5-
58.4
44.1
40.0
47.0
30.4
32.3
36.9
45.5
44.2
39.4
34.8
32.0
67.7
51. C
4.5.6
' Includes color lakes, rubber chemicals, and miscellaneous coal-tar products not shown separately.
2 1927-30 averasre.
The production and sales in 1939 of the several groups of synthetic
organic chemicals not of coal-tar origin are shown in table 4. The
bulk of such chemicals are solvents and other industrial chemicals
classified as miscellaneous. In table 5 production and sales of all non-
coal-tar synthetic organic chemicals in 1939 are compared with those
in 1938, 1937, and 1936, and with the average for 1925-30.
Table 4. — Synthetic organic chemicals of non-coal-tar origin: Summary of United
States production and sales, 1939
[Production and sales in thousands of pounds, value in thousands of dollars]
Number
of
manu-
facturers
Produc-
tion
Sales
Product
Quantity
Value
Value per
pound
Medicinals .
39
30
19
8
89
1,668
2,137
33, 690
13, 122
2, 984, 038
1,483
2,233
34, 877
11,896
1, 481, 874
6,120
1,588
15, 983
3,086
172, 921
.$4. 13
Flavors and perfume materials
.71
Resins.. ... . _
.46
Rubber chemicals
.26
Miscellaneous
.12
Total
3, 034, 655
1, 532, 363
199, 698
.13
SYNTHETIC ORGANIC CHEMICALS {>.
Table 5. — Synthetic organic chemicals of non-coal-tar origin: Comparison of United
States production and sales, average 1925-30, annual, 1936-89
[Production and sales in thousands of pounds, value in thousands of dollars]
Item
Averaee,
1925-30
1936
1937
1938
1939
Increase,.
1939 over
1938
Production
379, 972
264, 006
44,499
2,041,455
1,034,921
105, 832
2, 529, 650
1, 168, 149
119, 420
2, 409, 456
1, 121, 608
1 146, 435
3, 034, 655
1, 532, 363
199, 698
Percent
25.9
Sales
36.6
Sales value.- -
36-4
' Adjusted so as to be on the same value basis as 1939.
PART II.— PRODUCTION AND SALES BY GROUPS, 1939
COAL-TAR CRUDES
An upswing in coke oven operations resulted in an increase in the'
production of coal tar from 419,580,000 gallons in 1938 to 554,406,000
gallons in 1939. Sixty-two percent of the output was sold in 1939 in
comparison with 72 percent in 1938. Tar distilled by purchasers
thereof in 1939 amounted to 334,871,000 gallons, or 17 percent more
than in the preceding year.
Total production of toluene increased from 16,090,000 gallons in
1938 to 24,355,000 gallons in 1939. No toluene of nitration grade
was produced commercially from petroleum in 1939. A solvent^
however, containing approximately 50 percent toluene was produced
in substantial quantities by two oil companies. Figures for this
product are not included in this report.
The output of crude naphthalene increased 94 percent to 104,086,000
pounds, and the production of creosote oil advanced 25 percent to
110,242,000 gallons. Increased demands, particularly from syn-
thetic resin manufacturers, were responsible for an increase in the
recovery of crude cresylic acid and other crude tar acids. For the
first time, one company reported cresylic acid produced in conjunction
with petroleum refining.
Statistics of domestic production and sales of coal tar, crude light
oil, and the crude products made from them, as well as the quantities
of the several kinds of tar distilled are shown in table 6. These
statistics represent a combmation of data reported to the Tariff
Commission by the distillers of purchased tar, and of data reported
to the Bureau of Mines by coke-oven operators who distill tar produced
by themselves.
b UNITED STATES TARIFF COMMISSION
Table 6. — Coal-tar crudes:^ United States production and sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on p. 58.
An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information with regard- to individual firms]
Tar distilled by purchasers; thereof :2 Gallons
Oil-gas tar 16,230,837 $809,362
Water-gas tar 21, 320, 255 958, 079
Coal tar 297,320,098 15,892,717
Total 334,871,190 17,660,158
Manufacturers' identifica-
tion numbers of com-
panies reporting to
Tarifl Commission (ac-
cording to list on p. 58)
Production
(quantity)
Sales
Product
Quantity
Value
Unit
value
Tar 3 __gallons--
554, 406, 216
170, 993, 376
30, 470, 459
86, 245, 584
24, 355, 116
7, 468, 386
4, 089, 090
6, 684, 622
104, 085, 593
344, 534, 382
9, 397, 726
26, 627, 639
81, 671, 632
24, 683, 051
7, 093, 186
4, 393, 400
4, 562, 135
87, 836, 963
$16, 585, 734
730, 591
3, 617, 953
7, 678, 770
4, 952, 453
1, 355, 079
1, 018, 589
443, 469
1, 517, 240
$0,048
Light oil and derivatives:
Crude light oil., .gallons..
Benzol (except motor ben-
57, 103, 116, 171, 180, X....
8, 22, 62, 153, 171
.078
.136
zol) gallons..
Motor benzol do
22, 171, X
.094
Toluol, crude and refined
gallons..
Solvent naphtha, crude
and refined gallons. .
Xylol 3. . do -
8,22,62,107,153,171
8, 22, 62, 122, 153, 179, 180, X.
.201
.191
.232
Other light oil products
gallons
8,22,62,153
.097
Naphthalene, crude (solidify-
ing under 79° C.) <... pounds..
Anthracene, crude Qess than
30 percent) 2 . _ ...pounds
22, 57, 116, 122, 171, 179, 180,
184, X.
179
.017
Cumene2 . gallons
22
Cresylic acid, crude (less than
75 percent) 2 gallons
22,204
Pyridine.- .. do
22,122,179
217, 517
110,241,843
164, 256
101, 486, 998
269, 831
12, 384, 939
1.64
Creosote oil... ..do
Coal tar sold or consumed in
11, 22, 56, 57, 68, 103, 107,
109, 116, 122, 124, 153, 179,
180, 184, X.
11,22,122
.122
Tars, crude and refined 2. do
Tars, road 2 .do
Other distillates s do
Pitch of tar tons..
Pitch of tar coke 2 do
11, 22, 57, 62, 103, 122, 153,
171, 179, 180, 184, X, X.
11, 22, 68, 103, 109, 122, 124,
171, 179, 180, 184.
22, 56, 103, 116, 122, 166, 179,
180, 184, X, X, X.
11, 22, 56, 57, 68, 103, 109,
116,122,124,166,179,180,
184, X.
22,68,109,122,179,180
33, 957, 602
149,835,943
42, 680, 447
668, 153
90, 124
32, 258, 215
137, 696, 311
10, 740, 339
306, 457
81, 443
2, 181, 744
11,191,316
1, 542, 251
4, 358, 507
1, 016, 351
.068
.081
.144
14.22
12.48
Total
71, 419, 156
' Data for coke ovens reported to Bureau of Mines, and for tar refineries and others, to United States Tariff
Commission unless otherwise noted.
2 Reported to United States Tarifl Commission only.
3 Reported to Bureau of Mines only.
* Includes refined naphthalene reported to Bureau of Mines.
6 Includes crude tar acids reported to United States Tarifl' Commission and phenol, sodium phenolate,
and certain other products reported to Bureau of Mines.
COAL-TAR INTERMEDIATES
The production of 607,175,000 pounds of coal-tar intermediates in
1939 was the highest on record, exceeding by 51 percent the output in
1938, and by 5 percent the previous peak in 1937. Sales in 1939 were
269,084,000 pounds valued at $38,489,000, or an average of 14 cents
per pound. The difference between production and sales of inter-
mediates is due almost entirely to the large consumption by the
producers in the manufacture of finished coal-tar products.
The production of intermediates used in the manufacture of syn-
thetic resins increased more proportionately than did the total
SYNTHETIC ORGANIC CHEMICALS 7
production of intermediates; the output of phthalic anhydride and
phenol increased 60 percent and 54 percent, respectively. The pro-
duction and sales of virtually all intermediates used in the manufacture
of dyes and medicinals were considerably higher in 1939 than in 1938;
the output of 41,775,000 pounds of the basic commodity, aniline oil,
was 56 percent more than in the preceding year. Among the many
other intermediates that advanced in production were H acid 46
percent, p-dichlorobenzene 21 percent, dimethylaniline 52 percent,
a-naphthylamine 39 percent, and sulfanilic acid and salt 25 percent.
Statistics of production and sales of coal-tar intermediates are
shown in table 7.
Table 7. — Coal-tar intermediates: United States -production and sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on p. 58.
An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information with regard to individual firms.
The figures thus concealed, however, are included in the total]
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Acetanilide, tech _
44,60,62,85,138
85
Pounds
487, 606
Pounds
Acetanilide-p-sulfonic acid
Acetoacetanilide..
36,218 --
Acetoacet-o-anisidide .-.
218
Acetoacet-o-chloranilide
218
Acetoacet-m-xylidide
218
Acetotoluide
8,144,218
5-Acetylamino salicylic acid
1
Acetyldiaminoanthraquinone
6.
Acetyl-1 :4-naphthalcne-diamine-6 and
144...
7 sulfonic acid (acetylamino Cleve's
acid).
Acetyl-p-phenylenediamino (p-amino
44,62,85,144....
254,293
acetanilide).
Acetyl-p-phenylenediaminc sulfonic
85
acid.
Acetvl-p-toluidine
62,99,X,X
854, 789
Acridine yellow
62,144
Adipic acid
X._
a-Aminoanthraquinone and salt
62,85,144
255, 914
624, 118
197, 305
137, 527
b-Aminoanthraquinone,..
62,85,144
6,8,44,62,85,144,165...
6,8,44,62,.85,144,165._.
6,144
Aminoazobenzene and hydrochloride...
Aminoazo benzene sulfonic acid
Amia&azobenzene disulfonic acid
p-Aminoazobenzcne disulfonic acid
44..__
Aminoaaotoluene
8,44,62,85,144,165
85,144
373, 193
Aminoaaotoluene mono sulfonate
Aminoazoxvlene
6,85,144.... -
.\minoazoxyleno-toluidine ..
8
8-Aniino-I:2-henzacridone
62
o-Aminobenzoicacid (anthranilicacid)..
7,60,62- _.
p-Aminobenzoic acid. ..
62
A m ino-5-bcnzo vlani inoanthraquinone
62
ra-Aminobenzovl J acid
6,62,144,165
6,62,85,144,165
62
27, 570
79,400
p-Ariiinobcnzoyl J acid
p-Aminobenzovl-m-phenylenediamine
m-Aminobenzoyl-p-tolvlenediamine
62
l-Amino-2-bromo-4-p-toluidine anthra-
62
qumone.
Aminobutyrylaminodiethyl hydroqui-
none.
.\raino-4-chlorophenol
165
144
2-Amino-4-chlorotoluene
62, 144
2-Amino-6-ehlorotoluene
62, 144
m-Aminocresol methvl ether
44
l-Aniino-2:4-dibromoanthraquinone
p-Aminodiethvl benzaldehvde
62,144
62
2-Amino-5-diethylaminotoluene hydro-
X
chloride.
p-Aminoiliethvlaniline
8.'i, X
p-Aminodimcthylaniline
69
p-Aminodiphenylamine
62
UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales, 19S9 — Con.
Manufacturers' iden-
tificaiion numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Jk.minodiphenvianiine sulfonic acid
6,44,85,144
Pounds
Pounds
165
3-Ainino-4-hydroxyplionyl arsonic acid.
1 _
4-Amino-3-methoxy diphenylamine-2-
44
sulfonic acid.
1 "7-Aniinonaphthol
62
l-Amino-2-naphthol-4-sulfonic acid
44,62,85,144
1,083,317
44,62,144..
44,62,144...
152, 487
3, 664, 378
639, 114
1,042,278
(Chicaeo acid).
1- Amino-8-naphthol-3 :6-disulfonic acid
(H acid)
2-Amino-5-naphtliol-7-sulfonic acid (J
acid) .
2- Amino-8-naphthol-6-s u If o n i c acid
(gamma acid).
-2!-Amino-8-naphthol-3:6-disulfonic acid
(2 R add).
62,85,142,144....
6,44,62,85,144
46,964
184, 549
$81,407
156, 533
$1.73
6,44,62,85,144
.85
62,144
62, 69, 225, 234, X
44,144
19, 910
15, 931
21, 798
1.37
o-Aminophenol sulfonic acid
p-Aminophenol and hydrochloride
p- Aminophenylammonium-hydroxide .
m-Aminophenylpyrazolone carboxyhc
acid.
p-Aminophenyl-p-tolylamine sulfonic
acid.
8, 62, 69, 225, 234, X
X .-
1,012,442
439, 131
257, 676
.59
165
44
165.X
176..
6,44,144
85
44
44
142
191
191
l-Anilido-2-carboxyIic acid anthraqui-
none.
Aniline disulfonic acid
62
44,62,144,165-
52, 788
Aniline hydrochloride and sulfate
8,X
165
A^niline oil ._
8, 60, 62, 138, 142, 144, X.
62,144,165
41, 775, 370
13, 348, 564
1, 436, 023
.11
X
62,142
6,144,165
62, 142,144 -
Anthranilic acid (See o-Aminobenzoic
acid).
179
Anthraquinone (100 percent)
8,144
El- Anthraquinone hydrazine disulfonate_
85
85,144
85
Anthraquinone-l :5-disulfonic acid
Anthraquinone-1 :8-disulfonic acid
Anthraquinone-2:6-disulfonic acid
Anthraquinone-l :8-potassium disulfo-
nate.
Anthraquinone-1-sodium sulfonate
Anthraquinone-2-sodium-sulfonate (sil-
ver salt).
62,85
85
62, 85, 144
62
62
6,62,144
62
1 :9-A nthrathiazol-2-carbony 1 chloride . - -
62
X
165
25,X,X..
85
102...
6,8,62,85,144,161
62
278, 279
142
44,62,69, 144
8, 62, 69, 85, 144
1, 540, 628
165
6,44, 165, X - . ..
7,822
222, 483
62,85, 102, 142, 209, X...
102
246, 481
93,253
.38
Benzotrichloride
102, 142, X
117,930
124, 415
16, s66
.13
SYNTHETIC ORGANIC CHEMICALS 9
.Table 7. — Coal-tar intermediates: United States production and sales, 1939 — Con.
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Benzoyl acetanilide .
X
Pounds
Pounds
l-Benzoylamino-4-chloroanthraQuinone-
85
l-Benzoylamino-5-chloroanthraquinone.
62.144
.5-Benzoylamino-I:l-dianthramide
62
l-Benzoylamino-5-p-toluene sulfonic an-
62
thraquinone.
Benzoyl benzoic acid.. -. . ...
8,62,144
Benzoyl chloride
102,142 _
Benzoyl J Acid
44 ..
Benzylamine
102
Benzyl chloride -
25, 102, 142, X
Benzyl disulfide .-
102
Benzylidine aminopyrazolone
X_
Beta gamma picoline
22,179..
Broenner's acid (See 2-Naphthylamine-
6-sulfon)cacid).
Bromamine acid
62,144
Bromobenzanthrone
62
Bromobenzene..- _
60,69..
p-Bromomethvlamiuoanthraquinone- -
85
p-Brorrfophenol . _ _ .
X .
Butyl phenol (p-tertiary)
60
Carbazole, refined . -. .. .
179
Chicago Acid (See l-Amino-8-naphthol-
2:4-disulfonic acid).
o-Chloroacetoacetanilide,
36
Chloroacetoacetvlnaphthylamide--
165
l-Chloro-5-aminoanthraquinone
144
l-Chloro-8-aminoanthraquiuone
62
o-Chloroaminobenzoic acid
85, X ._.
Chloroaminophenol sulfonic acid ...
44, 62,85 -.
5-Chloro-2-aminotoluene hydrochloride.
62
Chloroaniline:
(Jrtho
142,225
Meta
85,142
Para ... -
62,142
o-Chloroaniline sulfonic acid
165
p-Chloroaniline sulfonic acid
6,44,62
7,317
102
Chloroanthraquinone ...
8.62,85,144
430, 361
116,098
o-Chlorobenzaldehyde.
62,85,144 .....
Chlorobenzanthrone
144. _
60.62,71,102,142,199...
3, 480, 163
$127, 249
$0 04
o-Chlorobenzoic acid
85,144,X
23,135
1, 096, 212
Ohlorobenzovl benzoic acid
8,62,85,144
Chlorobenzyl disulfide^
102
l-Chloro-2-carboxv anthraquinone
62 _ _
p-Chloro-m-cresol ,.
22
2-Chloro-l:4-dihvdroxy anthraquinone
6,144
(chloroquinizarin).
Chlorometanilic acid
62, 144
Chloromethvlanthraquinone
8,62,85,144
114, 187
102, X- _
o-Ohloro-p-nitroaniline
8, 60, 62, X
p-Chloronitroaniline _.
60,62,144 . .
p-Chloro-o-ni troaniline
225
l-f'hloro-5-nitroanthraquinone
144
62 .-
6-Chloro-2-nitrotoluene
62,144
o-Chlorophenol
142,X .
p-Chlorophenol
142
f!5
2-rhloro-6-phenvlphenol and sodium
60.
salt.
Chlorosulfophenvlmethylpyrazolone
62
Chloro symmetrical xylenol
22
Chlorotoluene
62,102,144
142, X
144.
4-Chloro-2-tohiidine
165 -
8,44,62,X, X
345, 638
72, 672
64,786
.89
2-Chloro-4-tnluidine-.'i-sulfonic acid
62..
ChlorofnlvUhiuelvcfillic acid ..
62, 85, 144
67, 624
Chloro-4-xvlolsiiIfii('hl()ride
85
p-rhloroxyhithioclveollic acid.
85 ..:.
Chroraotropie acid (See l:8-Dihydroxy-
naphthalene-3:fi-disulfonicacid).
Cleve's acid (See l-Naphthylamine-6
and "-sulfonic acid).
10 UNITED STATES TARIFF COMMISSION
Table 7.-^— Coal-tar intermediates: United States production and sales, 19S9 — Con.
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
62
Pounds
Pounds
Cresols:
Ortho - ...
22, 179, X
1, 320, 543
1, 259, 872
$132, 491
$0. 11'
Meta
22,X
Para
22,209
Meta-para .
22, 179
Ortho-meta-para .
8,22, 122, 180, 209, X....
60
13, 177, 035
14, 593, 732
1, 077, 318
.07"
Cresylic acid (refined)
8,22,122, 179, 180, X..._
142
14, 179, 392
14, 475, 446
892, 023
.06.
23,144
X
142
142
Dehy drothio-p-toluidine
Dehydrothio-p-toluidine sulfonic acid
62
44,62,144
225
37, 173
6,62,85
124, 587
59, 099
62,85,144
62
62
4"4-Diamino-2:2-dimethyldiphenylmeth-
62,144
ane.
l:8-Diapiino-4:5-dinitroanthraquinone..
62
6,44
8
176
62, 85, 144
62
boxy lie acid(dicarboxylic-anthraqui-
none) .
44,62
l:l-Dianthraquinone imine
l:l-Dianthraquinone Imine diamino
l"l-Dianthraquinone imine-4:4-diben-
62, 144
62,85,144
62,144
xoyl diamino.
62,144 ._
zoyi diamino.
I:l-Dianthraquinone imine dinitro
62
85
l-Diazo-2-naphthol-4-sulfonic acid
44,144
62, 144
8,62
62
13 13-Dibenzanthronyl
62
4:5-Dibenzoy]amino-l:l-dianthraquino-
nylamine.
85
209
62 -.
62,85
60
Dibromodihydroxynaphthalene.-
Dibromopyranthrone
X
62
36
44,62,102,142,144,225-,
62,85,144,165
62
140, 455
47, 749
1 :5-D ichloroan thraquinone
l:8-Dich]oroanthraquinone
l:8-Dichloroanthraquinone - 4:6 - disul-
fonie acid.
62,85
85
62
60,62,71,102,142
60,62,71, 102, 142, 199.. _
44, 62, 144
4, 998, 203
15, 796, 756
4,411,109
15, 577, 113
234, 267
1. 452, 198
.05
p-Dichlorohenzene- .
.09'
l:8-Dichloro-4:,')-dinitroanthraquinone--
2:4-Dichlorophenol
Dichlorophenylhydrazine sulfonic acid. _
Dichlorophenylpyrazolone carboxylic
acid.
Dichlorosulfophenylpyrazolone
Diciilorosulfophenylmetliylpyrazolonc
62
142
165
165
44
62, 165
X
142
62
85, 144
62, X . .
Diethvlaniline
62,144
Diethylaniline-m-sulfonic acid
62, X
Diethyl-m-toluidine
X
SYXTHETIC ORGA^^IC CHEMICALS 11
Table 7. — Coal-tar intermediates: United States production and sales, 1939 — Con.
Manufacturers' Iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Dihydroaminoantliraquinone _. .
85
Pounds
Pounds
l:4-Dihydroxv anthraquinone (quini-
6,8,16,62.85,144,236...
62,85, 144, X
351,312
245, 376
zarin).
l:5-Dihydroxy anthraquinone (anthra-
rufin).
l;8-Dihvdroxy anthraquinone (chrvsa-
85
zin).
p-p-Dihydroxydiphenyldimethylme-
60
thane (bis-phenol).
5:5-Dihvdroxv-7:7-disulfonic-2:2-dinaph-
62,165
thylamine (Rhoduline acid).
5:5-Dihvdroxy-7:7-disulfonic-2:2-dinaph-
44,62,85,144
187, 695
thylurea (J acid urea).
Dihvdrn.\veth-\Ianiline
6,85,144
Dihvdroxvethvl-m-chloroaniline
6
Dihvdroxyethyl-m-toluidine. --
6
Dih vdroxyeth vl-3-toluidine
85
l:5-Dihydroxynaphthalene
62,85
1 : 8 - Dihydroxynaphthalene - 3 : 6 -disul-
6,44, 82, 144
133, 025
fonic acid (chromotropic acid).
5:5-Dihvdroxy-di-b-naphthvlamine-7:7-
144
disulfonic acid (I acid imide).
2:5-Dimethoxy aniline
62
Dimethyianihne ... .
8,62,65, 144
4, 159, 348
99, 019
148, 787
Diraethvldianthraauinonyl
8,62,85, 144
Dinitroanilinc- .-_ .
6.8,62, 142
Dinitroanthraquinone
62
4:8-Dinitroanthrarufin
62
Dinitroanthrarufin disodium sulfonate. _
62,85
Dinitrobenzene.- .
8,62,85, 144
1, 831, 502
Dinitrobenzene sulfonic acid
44
Dinitrochlorobenzene
8,62,85,142,144
203
7, 403, 225
Dinitro-o-cresol
Dinitro-o-cvclohex vl phenol
60
DinitrodibenzanthronyL._
62
4:8-Dinitro-l:.5-dinitrophenyl ether an-
62
thraquinone.
Dinitrohvdroxvdiphenylaminc -,-
44,85
Dinitr(ii)hi'tiol, tech
62,85, 144
Dinitrostilbcne disulfonic acid
62,85, 144
Dinitrotetramethyldiaminodiphenylme-
85, 165.... ._
thane.
Dinitrotoluene
62.144
Dicxamic acid 85
Dioxv dibenzanthrone
62
Dioxy S acid
6.62
Diphenoxy anthraquinone
6
l:5-Diphenoxy anthraquinone
62
Diphenyl __.
60, 142
Diphenyl derivatives:
p-Amino
142
p-Nitro
142
Polvchloro- -, ._ _-_
142
Sodium chloro-o-phenylphenate
60
Diphenylamine
60,62
Diphenyl eiisilon acid -
62, 144, X
42, 881
Dipvrazol dianthrone
62
Distilbenediphenol
144
Disulfn dicarboxy benzidine
165
l:9-Di-p-toluidine anthraquinone _.
62
l:4-Di-p-tolvlaminoanthraquinone^ .
62
Dodecyl benzene
142 -. .. . .
6-Ethoxy-3-hydroxy thionaphthalene - - -
62
Ethylaminobenzoate . .
X...
Ethyl-o-amino-p-cresol-..
62, X
Ethylanilinc (mono)
62. 144
Ethvlbenzene .
60
Ethylbenzoyl acetate
X
Ethylbenzovl benzoate .
X
Ethvlbenzdv! cvclohexvlamine- .
142
Ethylbonzv'laiiiHne .. ._
62, 144
Ethylhi'iizxlaniline .sulfonic acid
44, 62,85, 144
457, 587
Ethvlbenzvl-ni-toluidine
62,144-
Ethylbenzyl-m-toluidine sulfonic acid..
62,85, 144
Ethyl salicyl carbonate
60
Ethvl-o-toluidine.-. - . . ...
62..
Ethyl-o-toluidine-p-sulfonic acid
62
252005—40-
12
u:nited states tariff commissio:^
Table 7. — Coal-tar intermediates: United States production and sales, 1939—
-Con,
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value-
Ethyl-m-toluidine
62, 144
Pounds
Pounds
■
Fluorescein
99, 148
Fumaric acid ..
144..-
Gamma acid. (See 2-Amino-8-naph-
thol-6-suIfonic acid.)
H acid. (See l-Amino-8-naphthol-3:6-
disulfonic acid.)
Hexachlorobenzeno
102
Hexaclilorodiptienvl oxide.- - . . -
60
Hexamethylenediamine- ..
X
2:1-2: 1-Hydrazine dibromoanthraqui-
62.
none.
Hydroquinone, tech
X, X
85
Hydroquinone dimethyl ether - .
85
6, 144
62
b-Hydroxy naphthoic acid
l-Hv(lroxy-4-Ditroanthraquinone ._.
62,85, 144, X
62
982, 426
704, 488
$^7, 451
$0. 98i-
p-Hydroxyphenyl arsonie acid
1
Indo])henol (blue and green) . . .
62, 144
Isatin
144
62 - -
acid.
Iso resinduline _ ....
62
Iso violanthrone
6, 62.
Laurent's acid (Seel-Naphthylamine-
5-SMlfonic acid) .
Lead trinitroresorcinale (lead styph-
X
nale).
62
none. _
62
6,62,144
38, 878
2, 227, 613
7, 142, 144
2, 410, 738
586, 656
.2*
144
Metanilic acid
8, 44,62, 144, X
62 .
Methvlaminoanthraquinone
85
4-M e t hyl-4-aminodiphenylamine-2-sii]-
144
fonic acid.
S, 62, 144
144 .
Methylcvclohexylamine
142
o-Methyleyclohexylamine
X
2-Mcthyl quinoline (quinaldine)
22, 144, X
X
Michler's hydrol. (See Tetramethyldi-
aminobenz hydrol.)
Michler's ketone. (See Tetramethyldi-
aminobeuzophenone.)
Naphthalene, solidifying 79° C. or
above (reflned, flake).
8, 22, 62, 179, 194, 232,
X, X.
59, 465, 247
31, 704, 522
27, 760, 725
363, 997
35, 499, 488
1,899,254
.05
44, 62, 85, 144
85
85
62, 144, X
85
144
Naplithalene-b-thioglycollic acid ---
Naphthalene-1 :3:6-trisulfonic acid
Naphthionic acid. (See 1-Naphthyl-
amine-4-sulfonic acid.)
a-Naphthol
62, 85
85 .
44,62,85. 144
757, 747
426, 356
218, 353
.51
44, 144
8, 144, X
l-Kai)hthol-8-ch)oro-3:6-disulfonic acid
(cliloro Jl acid).
l-N;i|ihthol-4-<;ulfonic acid (Nevile &
■Wintli'T's acid).
144
44, 62, 144
219, 310
166, 704
44,62, 85, 144
62
2-Naphthol-C-sulfonic acid (Schaeffer's
acid).
8,44,62,85,144
44,62, X
185,004
66, 807
42, 913
27, 237
20,157
30, 793
.47
1.13-
2-Naphthol-8-sulfonic acid
44
SYNTHETIC ORGANIC CHEMICALS 13
Table 7. — Coal-tar intermediates: United States production and sales, 1939 — Con.
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
2-Naphthol-3:6-disulfoiiic acid .
44, 62, 85, 144, X.
44,62,85, 144
Pounds
601, 098
1, 102, 116
Pounds
184, 765
$92, 635
$0.50
2-Naphthol-6:8-disulfonic acid
Naphthsulton disulfonic acid 1:8:3:6
44
a-Naphtbvlamine ._ ___
62,85, 144 --.
a-Naphthylamine disulfonic acid .
62
b-Naph thylamine
8,62, 144
l-Naphthylamine-2-sulfonic acid (o-
62, X
naphthionicacid).
l-Naphtliylamine-4-siilfonic acid (naph-
6,44,62, 144..
thionic acid).
l-Naplithylamine-5-sulfonic acid
8,44,62,85, 144
62, 144
133, 709
(Laurent's acid).
1-Nai)iith vlamine-6-su!fonic acid
l-Naphthylamine-6 and 7-sulfonic acid
8,44,62,85
245, 577
(Cleve's acid).
l-Naplitliylamine-7-sulfonic acid
44,62, 144
]-Naphthylamine-8-su!fonic acid
8,44,62,85, 144
44,62, 144
303. 811
67, 882
398, 827
4, 738, 923
1, 354, 206
l-Naphthylaminp-3:8-disulfonic acid
l-Naphthylamine-4-8-disulfonic acid
44,62, 144
l-Naphthylamine-3:6:8-trisulfonic acid
62,85,144
2-Naphtiiylamine -1-sulfonic acid
(Tobias acid).
2-Napiitliylamine 6-sulfonic acid
8, 44, 62, 99, X, X
44, 144, X --
699, 631
386, 963
.55,
(Broenner's acid).
2-Naphthvlamine-3:6-disulfonic acid
44,144
2-Naphtlivlamine-4:8-disulfonicacid
44,62,85,144
169, 794
1, 125, 887
1, 450, 950
2-Napiithvlamine-5:7-disulfonic acid__ ^
44,62,85,144
2-Naphthylamine-6:8-disulfonic acid- ..
44,62,144
"~
2-Naphthylamine-2:3:6-trisulfonicacid.-
144
l-NaphthyIamino-2-carboxylic acid an-
62,144
thraquinone.
p-Nitroacetanilide.
44,85
3-Nitro-4-aminoanisole
144
4-Nitro-2-aminoanisole
62,144
5-Nitro-2-aminoanisole
62
Nitroaminophenol-
8,44,144
p-Nitro-o-aminophenol .
62,85
4-Nilio-4-amino-2-sulfodiphenylamine.-
144
o-Nitroaniline . . ,
142
m^Nitroaniline --
8,44,62,144,225
6,142.228
129, 442
94, 844
59, 876
63'
p-Nitroaniline- _-_ --
p-Nitroaniline sulfonic acid
8,44,62
58, 801
m-Nitro-p-anisidine -
62,144
6,62,85,144.
62, 461
3-Nil:ro-4-anisidine-
85...
5-Nitro-2-anisidiiie-
85 -
o-Nitroanisole -
62,142
p-Niti"oanisole
62,144
Nitrobenzene . .-
8, 62, 85, 144, 165, X
44,62,85,144
44
57, 256, 976
273, 150
Nitrobenzene sulfonic acid
Nitrobenzene-2:.5-disulfonic acid _
6-Nitrobenzimidazole
X
ni-Nitrobenzoic acid
62
p-Nitrobenzoic acid
62..
m -N it robenzovl ch loride
62,102
p-Ni 1 robenzovl chloride
62, 102, X...
p-Nitrobenzovl J acid
62,85
3-Nitrobenzovl-3-nitroaniline
85
m-Nitrobenzovl sulfonic acid.
6 ._
Nitrobutyrylaminodiethyl hydroqui-
165
none.
O-Nitrochlorobenzene
62,142.
o-Nit rochlorobenzene sulfonic acid
44
o-Nitrochlorobenzene-p-sulfonic acid
144
•
m-Nitrochlorobenzene
62,142
p-Nitrochlorobenzene - -
62,142
p-Nitrochlorobenzene-o-sulfonic acid
6,44,62,144
201, 292
2-Ni tro-4-ehlorotoluene
144 _
m -N i trocresol
1,62
m-Nitro-p-cresol . .- - .
44
8-Ni(ro-l-diazo-2-naphthol-4-sulfonic
85, 144.
acid.
Ni tro-p-dichlorobenzene
44, 142, 144, 225
Nitrodiphenvl ether
165
3-Nitro-4-hvdroxv-l-phenvl arsenic acid.
1
Nitronaphthalene
62,85,144
14
UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales
, 19S9—
Con.
Name of intermediate
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Quantity
"Value
Unit
value
l-Nitronaphthalene-8-sulfonic acid
85
Pounds
Pounds
2-Nitronaphthalene-4:8-disulfoiiic acid.-
44,85,144
85
94, 799
1-Nitronaphthalene trisulfonic acid
62
62, 225, X
62, 142, 225
165
Nitrophenyl pyrazolone carboxylic acid.
165 _ - _
85
6,85,144
Nitrosoethvlbenzylaniline -. --
85
X
8,20,44,62,85,144,234.
62,144
386, 173
62,85,144
6,44
62,144
62,144
44,62,85,144
967, 747
1
8, 62, 99, X, X, X
8, 62
785, 535
722, 026
$872, 904
$1.21
5-Nitro-2-toluidine
165
44, 62, 144
62,85, 144
62, 144
62,85, 144
Oxydichlorobenzoyl benzoic acid
144
62, 85, 144
102
Pentachlorophenol and sodium salt
60, 142
62, 142
62, 142, X
8, 22, 60, 122, 142, 179,
180, X.
6, 44, 62, 85, 144, 165,
X.
6, 44, 62, 85, 144, 165,
X.
X
68,577,421
88, 509
20, 701
59, 857, 139
6,111,442
.10
Phenyl - 2-amino - 5 - naphthol-7-sulfonic
acid (phenyl J acid).
Phenyl -2-amino - 8 - naphthol-6 - sulfonic
acid (phenyl gamma acid).
36
36
25, X
1, 25, X
6,8,44,62, 144, 172._-_
44, 62, 85, 144
783, 004
81,090
m-Phenylenediamine sulfonic acid
8, 228
p-Phenylenediamine sulfonic acid
44, 85
62
60, 62, 144
5, 420, 072
Phenylhydrazine and hydrochloride
60, 69, 182
85
Phenylhydrazine-p-sulfonic acid
Phenyl malonic diethyl ester
Phenylmethylpyrazolone
l-Phenyl-3-methyl-5-pyrazolone (devel-
oper Z).
Phcnyl-l-naphthylamine-8-sulfonic acid.
85, 165, 206
1
6, 8, 60, 62, 85, 165, X
62, 165
8, 62, 85, 144
299, 978
60
60 ..
62, X --
Phthalic acid and anhydride
7, 22, 62, 142, 144
62
44, 274, 430
20, 380, 004
2, 786, 372
.14
142
22, 179
8, 62, 144
140, 132
81, 986
53, 868
.66
62, 102, 142
44,85,144
85, 161
X
62
6
179
Quinaldine (See 2-Methyl quinoline).
Quinaldine yellow, base
Quinoline
144
22
X
85
62, X
Rhoduline acid (See 5:5-Dihydroxy-7:7-
disulfonic-2:2-dinaphthylamine).
SYNTHETIC ORGANIC CHEMICALS 15
Table 7. — Coal-tar intermediates: United States production and sales, 1939 — Con.
Manufacturers' iden-
tification numbers
(according to list on
p. 58)
Produc-
tion
Sales
Xame of intermediate
Quantity
Value
Unit
value
Salicylic acid, tech__
60,62
Pounds
Pounds
Salicylic anilide (Shirlan)
62-.
Schaeffer's acid (see 2-Naphthol-6-sul-
fonicacid).
Silver salt (see Anthraquinone-2-sodi-
um sulfonate) .
Sodium 2-bromo-4-phenylphenate- -_ .
60 -
Sodium naphthionate. -.-
62
Sodium pentachlorophenate -
60
Sodium tetrachlorophenate
60
Sodium trichlorophenate
60
Succinic acid and anhydride
144, X
Sulfanilic acid and salt
6, 8, 44, 62, 144
1,878,982
o-Sulfobenzaldehyde - - -
62, 144
p-Sulfo-o-benzoyl benzoic acid (sulfo BB
62
acid.)
Sulfophenvlmethylpvrazolone
62
Sulfophenylmethylpyrazclone carbox-
165
ylic acid.
Tetraaminoditolylmethane ..
144
1 :8:4:5-Te trachloroanthraquinone.
62,85,144
Tetrachloro benzene. . _-_
102
Tetraethyldiaminobenzophenone (ethyl
62,144
ketone).
Tetramethyldiaminobenzhydrol (Mich-
62,85 -
ler's hydro]).
Tetramethyldia mlnobenzophenone
62,85,144-.-
(Michler's ketone).
Tetramethyldiaminodiphenylmethane
8, 62, 85, 144, X
856, 956
Tetramethyldiaminodiphenylmethane
144-
sulfonate.
Thioaniline - .. --
8,62,144.
Thioaniline disulfonicacid--
144
Tolazine, base.-
144
Tolidine and salts .-
44,62,69,144
248, 119
Tolidine disulfonic acid
6,165
o-Toluene sulfamide.
142
p-Toluene sulfamide
142
p-Toluene sulfocbloride
142--.
p-Toluene sulfonic acid
142, X
p-Toluene .sulfonic acid ethyl ester
225
Toluidine. - -
8
Toluidine disulfonic acid
44
o-Toluidine ..-
8,62,85,144.
o-Toluidine omega sulfonic acid
6,144
o-Toluidine sulfonic acid
8,62,85,144
118, 355
o-Toluidine-m-sulfonicacid -
165 -
m-Toluidine
62
p-Toluidine
62,85,144
p-Toluidine sulfonic acid ..
44,62,85,144
8,62,85,144
67, 227
308, 108
1, 089, 446
p-Tolyl-o-benzoic acid
m-Tolylenediamine
8,44,62,85,144-
323,817
$211, 418
$0.65
m-Tolylenediamine sulfonic acid
144
p-Tolylenediamine--
8
p-Tolylenediamine sulfate -
8
Tolyl-l-naphthylamine-8-sulfonic acid
8,62,85,144
58,558
(tolyl peri acid).
Tribromophenol . .
60
Trichloro benzene ..- .
60,102,142
1, 153, 723
1, 225, 691
89,264
.07
Trichlorophenoxy ethoxy ethyl chloride
60 -.
Trinitrophenol .
62,144
2:4:6-Trinitroresorcin (styphnic acid)
X
l:2:4-Trioxyanthraquinone
85
Vinyl benzene (styrene)
60
m-Xylene
X
Xylenols. . _
8, 22, 179, 180
Xylidine and salt ._-
44,62,144
m-Xylidine
62 144
m-Xvlidine acetate
144
m-Xylidine sulfonic acid- _
62,144
Xylidine, ortho and para
8,144
Xylyl disulfide
102
Other intermediates..- ...
1,62, X .
Total intermediates:
For which individual statis-
383,889, 962
190, 957, 265
20. 149. 628
.11
tics are shown.
For which individual statis-
223,285, 331
78,126,386 18,339,722
.23
tics cannot be shown.
Grand total
607, 175, 293
269,083,651
38, 489, 350
.14
16
UNITED STATES TARIFF COMMISSION
COAL-TAR DYES
The production of 120,191,000 pounds of coal-tar dyes in 1939 was
47 percent more than in the preceding year. Sales were 30 percent by
quantity and 32 percent by value above those in 1938. Since sales
in 1938 were in considerable part from inventories, the increase shown
for production in 1939 is much greater than that for sales. A decided
betterment in export trade, particularly during the last quarter,
contributed to the improvement in sales. After satisfying the
American market, dye producers had a considerable surplus for export.
The quantity exported was limited largely by plant capacity.
Unclassified ^ dyes constituted 17 percent of sales quantity and 32 per-
cent of sales value of all dyes in 1939, as compared with 16 percent and
32 percent, respectively, in 1938. Sales of the bulk color, synthetic
indigo, decreased somewhat in value, but increased slightlv in quan-
tity, from 11,738,000 pounds m 1938 to 11,950,000 pounds in 1939.
The average value per pound of all dyes sold was $0.60 in 1938 and
^0.61 in 1939. A continuation of the steady trend toward a greater
production of the higher priced dyes, especially vats and azoics,
more than offset a reduction of 1 cent per pound on synthetic indigo
iind decreased unit values in the groups of acetate silk dyes and azoic
dyes. Research resulted in the development of a number of new dyes
in 1939.
Production and sales of dyes by classes of application are shown
in table 8; and of individual dyes, grouped, as far as practicable by
chemical classes, in table 9. Totals of chemical classes that can be
shown without revealing confidential information are given.
Table 8. — Comparison of United States production and sales of dyes, by classes of
application, average 1925-30, annual 1938 and 1939
Class of application
Production
Quantity
Average
1925-30
1938
1939
Percent of total
Average
1925-30
1938
1939
Acetate silk.
Acid—
Azoic
Basic
Direct
Lake and spirit-soluble
Mordant and chrome..
Sulfur
Vat, total....
(a) Indigo
(6) other
Unclassified
Total..
> Not shown separately during 1925-30.
Pounds
(')
11,813,941
0)
4, 833, 382
17,983,751
1,947,124
3, 611, 608
20, 004, 635
33,221,072
27, 128, 311
6, 092, 761
587, 657
Pounds
2,072,375
11, 699, 020
2, 687, 725
4, 473, 033
21,060,655
2, 284, 620
3, 058, 926
11,459,927
22, 346, 618
11, 000, 829
11,345,789
615,949
Pounds
2, 584, 873
17, 700, 432
3,317,761
6, 415, 693
31, 438, 399
3, 304, 687
5, 236, 683
18, 650, 898
30, 034, 981
12, 474, 777
17, 560, 204
1,506,281
12.6
5.1
19.1
2.1
3.8
21.3
2.5
14.3
3.3
5.5
25.8
2.8
3.7
14.0
28.9
6.5
.6
94,003,170
81,758,848
120,190,688
100.0
100.0
1 Not classified according to Colour Index numbers.
2.2
14.7
2.8
5.3
26.2
2.7
4.4
15.5
10.4
14.6
1.2
100.0
SYNTHETIC ORGANIC CHEMICALS
17
'Table 8. — Comparison of United States production and sales of dyes, by classes of
application, average 1935-30, aruiual 1938 and 1939 — Continued
Class of application
Sales
Quantity
Percent of total
Pounds
(')
11, 699, 667
(0
4, 709, 926
17, 580, 927
1, 896, 821
3, 558, 732
19, 810, 565
32,429,018
27.111,575
5, 317, 443
521,625
Pounds
2, 029, 625
12,416,001
2, 591, 306
4, 417, 627
21,967,120
2, 339, 341
3, 452, 169
12, 855, 450
25, 031, 204
11, 738, 149
13,293,055
702, 991
Pounds
2, 402, 148
17,062,522
3, 144, 736
5, 975, 859
30, 421, 364
3, 278, 102
5, 325, 074
17, 310, 556
28, 135, 476
11,949,582
16, 185, 894
1,438,131
2.3
14.1
3.0
6.0
25.0
2.7
3.9
14.7
2.1
Acid - -.
Azoic -
12.7
14.9
2.7
Basic
5.1
19.1
2.1
3.8
21.5
5.2
26.6
Lake and spirit-soluble
2.9
Mordant and chrome --
4.7
Sulfur .
15.1
Vat, total
(a) Indigo --
29.4
5.8
.5
13.4
15.1
.8
10.4
(6) Other
14.1
Unclassified _.
1.3
Total
92, 207, 281
87, 802, 834
114.493.968
100.0
100.0
100.0
Sales
• Class of application
Value
Percent of total
Average
1925-30
1938
1939
Average
1925-30
1938
1939
Acetate silk..
(')
$8,651,526
(0
3, 977, 258
9, 076, 783
1,681,736
2, 212, 390
3, 928, 982
9,114,973
3, 741, 314
5, 373, 659
784, 604
$2, 001, 844
9, 841, 787
4, 151, 107
4,152,496
11,968,976
1,766,708
1,727,669
3,215,621
13, 578, 125
1, 849, 621
11, 728, 504
691, 230
$2, 210. 758
13, 295, 598
4, 707, 546
5, 593, 109
16,649,109
2, 298, 367
2, 664, 749
4, 656, 536
16, 789, 372
1,842,718
14, 946, 654
1, 358, 457
3.8
18.5
7.8
7.8
22.5
3.3
3.3
6.1
3.2
Acid
21.9
18.9
Azoic -.
6.7
Basic. .-
10.1
23.0
4.3
5.6
10.0
8.0
Direct
23.7
l»ake and spirit-soluble
3.3
Mordant and chrome
3.8
Sulfur
6.6
Vat, total
(a) Indigo..
9.5
13.6
2.0
3.5
22.1
1.3
2.6
(6) Other
21.3
Unclassified
1.9
Total
39, 428, 252
53,095,563
70,223,601
100.0
100.0
100.0
' Not shown separately during 1925-30.
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939
IThe numbers in the third column refer to the numbered alphabetical list of manufacturers printed on page
68. An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the fourth, fifth, and sixth columns indicate that the statistics
of production or sales cannot be published without revealing information with regard to individual firms.
The figures thus concealed, however, are included in the total]
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
•)
Classified Dyes
NITROSO DYE3
85
Pounds
Pounds
5
8
10
KITRO DYES
8,44 144
16
A7.0 DYE3
Monoazo dyes
6,85
17
Spirit yellow R . . . .
0,8,54,79,85,144
6,8,54,79,85,144
8,54,85. 144
53,733
31, 748
49,616
34, 215
$39,954
22,587
$6.81
19
Butter vellow
.60
20
21
Chrysoidine R .. ....--
8,85,144
179,925
121,616
40. 810
.34
23
64
124
Sudan I
6,8,54,62,85,144
332, 7i3
338,368
158,649
.47
18
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production
and sales
, by types
, 1939—
Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc- -
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
26
Classified Byes — Continued
Azo DYES— continued
Mouoazo dyes— Continued
44,144
Pounds
Pounds
27
8,44,62,85,144
144
184, 500
179, 517
$84, 377
$0. 47"
29
30
6,144
31
Amido naphthol red G - - -
6,8,44,62,85,144
6,8,44,85
475, 277
86, 460
84, 246
24, 012
90, 767
462, 995
116,348
72, 463
21, 493
93, 554
152, 695
50, 889
39, 915
9,080
58, 755
.33
36
.44
40
6,8,44,85
.55
52
6,44,85
.42
53
8,44,62,85,144
X
.63
54
56
44,144
57
6,8,44,62,85,144
197
447, 108
436, 384
172, 238
.39
69
73
6,8,54,79,85,144
79
Ponceau 2R .. --
8, 44,62,85, 144, 148.- _
62,85 .
380, 964
373, 656
151, 172
.40
84
88
8,44,85,144
152, 250
137, 049
62, 853
.46
90
62
98
8,44,85 .
99
85
101
8, 172, X
105
62
110
85
113
79
114
62,85
119
62
122
44
126
Direct pink E2GN
62
128
85,144
130
Direct pink EBN
62
138
Metanil yellow . .
6,44,62,85,144
62
423, 976
445, 307
237, 465
.53-
142
145
85
146
6,85,144
62,000
70,971
41, 676
.59
148
8,85,144
151
Orange II . _ -.
8,44,85,99,144,148...
8,44,62,144
1, 446, 763
233, 028
i, 398, 618
251, 071
379, 106
72,744
.27
161
.29
163
44,62,144
165
Lake red C (100 percent)
8,62
167
144
168
44, 144__.
169
44,85,144
13, 431
15,600
11, 560
.74
170
Chrome black PV
85,144
172
85
175
85
176
Fast red A .
8,44,62,85,144
6,44,62,85,144
8,44,85,144
169,804
169, 698
194, 355
145, 372
172, 338
176, 061
69, 340
87, 971
91, 836
.48
179
Azo rubine - -.
.51
180
Fast red VR ._
.52
183
44
184
6,44,144
48,341
40,250
73, 974
19, 581
33,481
.49
185
8,44,85,144
.45
189
Lake red R (100 percent)
197
195
44,85,144
22, 796
10, 212
.45
197
6,44,144
201
44,85,144
202
Chrome blue black U
44,62,85,144
44,62,85, 144_..
1,700,360
660, 724
144, 243
127,533
47, 980
1, 729, 643
483, 275
.2S
203
Chrome black T
204
Chrome black A
44,85,144,172
8,62,144
160, 246
118,314
37, 849
67, 508
60, 130
24, 346
.42
208
.51
209
62,85,144
.64
214
Lake red D (100 percent)
197 ...
216
Chrome red B . ..
8,44,62,85,144
62,85, X.. .-
93, 758
78,230
39, 195
.50
219
225
62
234
Disazo dyes
6,8,44,62,85,144,235
6,8,44,54,85,144,235
62
404, 828
125, 756
346, 870
125, 602
175, 737
85, 540
.51
235
Rcsorcin dark brown
.68
238
246
Acid black lOB
6, 8, 44, 62, 85, 144, 235.
44,54,62
2,190,688
1, 992, 899
751, 530
.38
247
Cloth red R
Brilliant croceine -.
Cloth red 3Q
44
252
256
8,44,62,85,144
8,62
371,270
404, 898
306,797
.76
SYNTHETIC ORGANIC CHEMICALS
19
Table 9. — Coal-tar dyes: United States production and sales, by type
s, 1939-
-Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
258
Classified Dyes — Continued
Azo DYES— continued
Disazo dyes— Continued
Sudan IV
44,54,62,79,85,144...
Pounds
Pounds
262
Cloth red 2B
6,44,85,144
62, X
81,616
79, 41 i
$45, 288
$0.57
267
Neutral gray G
Milling orange G
Cloth scarlet G
274
6,8,44,85
28, 168
30,811
4,811
188, 690
27,084
72, 906
481, 226
15, 095
4,551
388, 559
27, 057
45, 279
272, 157
.49
275
6,8,44,62,235
.95
278
Direct fast red 8BL . .
6, 8, 27, 62, 85, 144,
165, 235, X.
6,85,144
170,032
31, 402
76, 595
539,0.32
2.06
280
Scarlet EC
Fast cyanine G.
Fast cyanine 5R
Naphthalene acid black 4B
Acid black B
Chrome black F ..
1.00
288
289
290
8,85, 144, X
8, 62, 85, 144, X
85
.62
.57
294
144
299
44,62,85,144
175, 763
81,375
.46
302
Chrome blue green B
Fast acid black N2B
8,62
304
44,62,85
306
Fast acid black F
Fast cvanine black B. _
85
307
8, 62, 85, 144, X
85
165,025
170,982
111,106
.65
308
Naphthylamine black D
Developed blue NA
Developed blue B _
316
44,62,85,144
44,62,85,144
234,738
317
319
Direct fast heliotrope 2B
Developed brilliant orange GR
Diamine brilliant violet B
62,85
324
62, 85, 165, X . .
325
6,85
326
Direct fast scarlet, _ . -
44, 62, 85, 144, X
44,85
543, 425
590, 429
626, 559
1.06
327
Direct fast scarlet 4BS
331
Bismarck brown
Bismarck brown 2R .
8,62,85,144
114, 030
846, 785
86,305
824, 511
30, 094
307,644
.35
332
8,44,62,85,144
85 . . .
.37
336
Acid chrome black F
Chrome fast vellow C
343
8
346
Direct fast vellow 5QL
8,62,85
349
Benzo fast yellow 4GL
Direct fast pink 2BL
X
353
8, 62,85, 144
53, 937
236,229
32, 767
226, 641
58, 970
170,071
1.80
364
Paper yellow
Chrvsophenine G
8, 62, 85, 144
.75
365
62, 85, 144 .
370
62, 144
374
Direct orange TA
144
375
Congo corinth G
6, 8, 44, 62, 85, 144,
235.
44, X
405, 599
361, 123
234, 779
.65
376
Direct rubine
Direct scarlet B
382
6,8,44,85,144,235,X.
44
179,385
195, 864
174, 367
.89
385
Direct violet..
387
Direct violet B
44, 62, 144
394
395
Direct violet N
Developed black R0_.
6,8,44,62,85, 144...
6...
118, 910
108, 342
98, 200
.91
401
Developed black BHN
6, 8, 44, 62, 85, 144,
235.
144
2, 308, 990
2, 367, 172
768, 918
.32
405
Direct cyanine R
Direct blue 2B
406
6, 8, 44, 54, 62, 85,
144, 235.
62
1, 035, 626
1, 172, 448
236, 579
.20
409
410
Chrysamine G
Cresotine yellow G
Direct orange R
62 ...
411
44, 144, 235
415
44, 62, 85
419
Direct fast red F
6, 8, 27, 44, 62, 85,
144, 235.
6, 8, 44, 62, 85, 144,
235.
8, 235 ..
444, 089
566, 046
398, 342
501, 936
254, 722
236,469
.64
420
Direct brown M
.47
423
430
Polar red C
44,62,85, 144, X, X.
62
431
436
Direct brilliant red 8B.
Chrome fast yellow RD
Milling red 2G
Direct orange RT
44
441
85
443
6, 44
446
6, 144
448
Benzopurpurine 4B
44, 62, 144
732, 410
733,664
371, 925
.61
464
62
468
Direct mauve B
144
471
Direct blue 3R
44, 144
472
Direct blue BX.
44, 62, 144..
20,663
18,930
145, 144
6,698
37, 507
.35
477
Direct blue 3B
44, 54, 62, 144
.26
478
Direct orange O
6, 44, 144
487
Acid milling red B
6,8,44,85, 165, X...
44, 62, 144
6, 44, 62, 85, 144, 235.
60,292
43,806
57, a38
33. 592
47, 527
28.877
94,729
.83
495
Benzopurpurine lOB .
.86
502
Direct azurine Q
175,701' 170,333
.56
20
UNITED STATES TARIFF COMMISSIOlSr
Table 9. — Coal-tar dyes: United Stales production and sales, by types, 1939—
-Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
SOS
Classified Z)j»es— Continued
Azo DYES — continued
Disazo dyes— Continued
Direct brilliant blue G
62
Pounds
Pounds
612
Direct blue RW
6, 44, 62, 85, 144
144
136, 555
143, 037
$110, 217
$0.7r
615
Direct blue B
616
Chicago blue B.
85
618
Direct pure blue 6B
6,44,62,85, 144
8, 44, 62, 85, 144
6, 44, 62
648, 750
109, 269
600, 294
94, 103
472, 278
46,091
.79'
.WO
Trisazo dyes
Direct pure blue
.49-
633
Direct fast blue FR
634
Naphthogene blue 4R...
85
.639
Direct fast black FF
8,44,62,86, 144
85
419, 496
356, 926
171,395
.48-
644
Pluto black 5BS
66?
Diazo black RS
62, 144
661
Direct brown BT. .
6, 27, 62, 85, 144, 165,
235, X.
44
155, 089
192, 361
232, 208
1.21'
.667
Direct fast blue R..
676
Direct fast blue B .
44,62, 144
677
Direct brown T2G
8
.681
Direct black EW
8,44, 62,85, 144,235.
8,44,62,85, 144,235.
6, 8, 44, 62, 85, 144,
235
8, 44,'62, 8.M44, 235.
62....
8, 750, 343
857, 953
222, Oil
167, 493
8,465.150
741, 087
186, 350
175, 489
2, 031, 443
202, 947
66, 587
61,397
.24
.68?
Direct black RX._.
.27
683
Direct green ET
.36
.689
Chloramine green B .
.29-
690
Direct steel blue Q
693
Direct green B.
6, 8, 44, 62, 85, 144,
172, 235.
8,44,62, 144,235
85
819, 676
102, 794
756, 163
107, 553
260,462
43, 512
.34
694
Direct green Q
.40'
696
Direct olive G
696
Direct brown 3G0
6, 8, 44, 62, 85, 144,
235.
6,44,62,85,144
62
1, 013, 873
143, 779
928, 208
146, 252
302, 332
68,743
.3$^
698
Congo brown G
.47'
601
Congo brown R .
606
Tetrakisazo dyes
Direct brown G..
8,85,235.
Total classified azo dyes - .
39, 493, 294
13, 820, 165
38, 300, 354
13, 167, 898
16, 650, 980
14, 096, 081
.43'
Total unclassified azo dyes...
1.07
Total azo dyes
53, 313, 459
51, 468, 252
30, 747, 061
.60'
STILBENE DYES
Direct yellow R
8,44.55,62.85,144....
8,44,62,8.6,144
8,62,85-
620
345, 036
143, 176
367, 698
145, 437
184, 618
96, 166
.50-
621
Chloramine orange G
.66
622
Stilbene yellow
628
Diphenvl catechine Q
144....
631
Direct chrysoine G
44
636
PYRAZOLONE DYES
Fast light yellow 2G--
6,62,85,144,165
639
Fast light yellow...
6, 27, 44, 62, 85, 144,
165, X.
6,8,85,99.144,165....
85 . .- ...
298, 105
616, 841
315, 004
647, 298
269, 445
433, 486
.86-
640
Tartrazine
.67"
661
652
Chrome red B
8,44,62.85, 144, X....
6,144,165
205,784
210, 257
179, 876
.86»
653
Pyrazol orange G
654
Developed fast yellow 2Q . ...
62
Total pyrazolone dyes '
1, 259, 721
1, 304, 386
1, 064, 570
,82r
KETONIMINE DYES
Auramine
8, 62, 144, X
655
1, 008, 364
931, 634
814, 074
.87-
Includes unclassified dyes of this group.
SYNTHETIC ORGANIC CHEMICALS
21
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Classified Jii/f*— Continued
TRIPHENYLMETHANE AND DIPHENTL-
NAPHTHYLMETUANE DYES
Malachite green
Rhoduline blue 6Q
Brilliant green
Setocyanine
Acid green B
Fast acid green B
Acid light green.
Acid glaucine blue
Para fuchsine
Magenta
Methyl violet and base.
Crystal violet...
Ethyl violet
Spirit blue2B.__
Fast green bluish
Fast acid violet lOB
Acid violet
\cUl fast violet BG
Alkali blue 6B
Methyl blue
Methvl cotton blue
Soluble blue
Patent blue
Patent blue A
Eriochrome azurol B
Eriochrome cyanine R
Aurine
Victoria blue R
Victoria blue B
Naphthalene green V
Wool green S
Total triphenylmethane and
diphenylnaphthylmethane
dyes.i
XANTHENE DYES
Rhodamine B.
Rhodamine B cone
Rhodamine 6Q cone
Fast acid violet A2R
Uranine
Eosine
Tetrabromofluorescein
acid) .
Erythrosine
Erythrosine B
Phloxine B
Rose bengale
Rose bengale B
(bromo
Total xanthene dyes.
ACRIDINE DYES
Acridine orange A.
Phosphine
Phosphine2G
Euchrysine
QUINOUNE DYES
Quinoline yellow
Quinoline yellow KT.
THIAZOLE DYES
Primuline ,
Direct pure yellow M.
Direct fast yellow ,
Thioflavine T.
Manufacturers'
identification
numbers (according
to list on p. 58)
8. 65, 144, X.
85,144
8,65, X
85
8,44,62,85,144
8,85,144
62,85
62,85,144
8, 148, X
8, 148, X
8, 62, 65, 85, 101, 144,
X.
62,65,85,144
62,85
85
6
62, X
8, 44, 62, 85, 144, X.
144
85
148
148.-.-
8,85, X
85,144
85,144
62,8.5, 144, X
85, 144, X
62
62,85
62,85,144
62, 144, X
8,62,85....
62.__
62, X...
62, X...
X
8,99,148
8, 99, 144, 148.
8,99,111,148.
148
148.
148.
85,165....
8, 44, 62, 85, 144, 165.
165....
85,165
62, 144, X.
X
44,62,144
62
44,62,85,144,161.
62....
Direct brilliant flavine S.. 161.
' Includes unclassified dyes of this group.
Produc-
tion
Pounds
357, 355
38, 068
105,311
39, 135
19, 686
1, 012, 828
256, 158
81, 571
117, 650
222, 735
4, 316, 386
47, 867
380, 395
609, 786
163, 756
103, 471
380,374
Sales
Quantity
Pounds
358, 435
41, 719
114, 374
36, 558
18, 564
40, 369
1, 010, 353
270, 121
73, 303
124, 683
194, 091
4, 075, 911
46, 937
306, 979
557, 507
141, 040
118, 454
331, 676
Value
$405, 729
58, 802
Unit
value
83, 409 . 73
81, 951 2. 24
34, 254
74, 305
639, 112
250, 470
118,611
205, 809
100, 173
4, 433, 808
68,920
368,788
992,086
101, 173
155, 405
300, 351
22
UIsriTED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production
and sales, hy types, 1939—
-Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
833
Classified Dj/es— Continued
AZINE DYES
Wool fast blue GL..
85, 144, X
Pounds
130, 564
272, 839
Pounds
133, 190
$203, 379
$1.53
841
Safranine
8,62,85,144
853
Acid cyanine BF
62
860
Induline (spirit-soluble)
8,85,144
52, 875
42, 760
1, 284, 394
1, 364, 325
54, 679
49, 732
1,272,311
1, 328, 458
20, 780
33, 131
356, 010
469, 220
38
861
Induline (water-soluble)
8,85,144
67
864
Ni^rosine (spirit-soluble)
8,85,144
28
865
Nigrosine (water-soluble)
8,85,144
.35
871
ANILINE BLACK AND ALLIED DYES
Diphenyl black base.-
85
873
New fast gray
8,62,165
875
Fur black
8,85
883
OXAa^NE DYE3
Gallocyanine.
8,144,236
909
Cotton blue
6,8,144..
88,783
74, 206
92, 267
1.24
913
Nile blue BX.
85
m?.
THIAZINE DYES
Methylene blue
8,62,65,85,144
8,144
539, 396
621, 877
468, 175
.90
924
Methylene green B
5)27
New methylene blue..
8_
931
BrUliant chrome blue
85
969
SULFIDE DYES
Carbazole vat blue R
62,85
(')
(2)
11, 975, 466
2, 562, 489
1, 793, 126
958, 615
629, 615
176, 820
48, 090
171, 302
335, 375
(2)
(2)
10, 797, 002
2, 481, 508
1, 793, 805
931,498
625, 106
158, 431
36, 967
187, 020
299, 219
(2)
(2)
1, 814, 402
1, 164, 397
496, 940
652, 219
285, 920
46, 834
14. 061
54, 216
127, 547
971
Carbazole vat blue G
62,85
Sulfur black
8,20,62,85,144,200...
8, 20, 44, 62, 85, 106,
144, 200.
8, 20, 44, 55, 62, 85,
106, 144, 200.
8, 20, 62, 85, 106, 144_.
8, 62, 85, 144
.17
Sulfur blue
.47
Sulfur brown
.28
Sulfur green.
.70
Sulfurmaroon
.46
Sulfur olive
8, 20, 55, 62, 85, 106,
144, 200.
44,62,85, 144
8, 20, 44, 55, 62, 85,
106.
8, 20, 44, 62, 85, 106,
144, 200.
.30
Sulfur orange
.38
Sulfurtan...
.29
Sulfur yellow ...
.43
Total sulfide dyes..
18, 650, 898
17, 310, 556
4, 656, 536
.27
ANTHRAQUINONE DYES
Alizarin. „ . .
8, 85, 144 - .
1027
1034
Alizarin red S-.-
6, 8, 144
46, 113
49, 889
84, 069
1.69
1035
Alizarin brown
144, 236
1040
Alizarin SX.
144
1043
Pseudopurpurine
85
1053
Acid alizarin blue SE . . .
62, 85, 144, X
8, 16, 62, 85, 144, 236,
X, X.
16, X
44, 695
747, 675
61, 825
715, 601
122, 652
1, 097, 863
1.98
1054
Acid alizarin blue B
1.53
1060
Anthracene blue SWGG
1062
Anthracene blue WR_.
85, 144, X ..
1063
Anthracene blue WES
16
1073
Alizarin irisol R
16, 62...
.
1075
Alizarin astrol B
62,85 ..
1076
Cyananthrol R
62
1078
Alizarin cyanine green E .
6, 8, 16, 62, 85, 144,
236, X.
16, 62
357, 586
330, 008
574, 761
1.74
1080
Acid anthraquinone violet B
Anthraquinone blue black B
Acid anthraquinone blue B
Acid alizarin rubi no
1085
1088
6,85, 144, 236, X
62,85, 144 .
151, 830
80, 793
157, 109
59, 846
233, 694
185, 433
1.49
3.10
1091
85
Total anthraquinone dyes ■..
2, 417, 229
2, 394, 534
3, 726, 580
1.56
> Includes unclassified dyes of this group.
' Totals not included under sulfide dyes. In dyes classified by method of application, this dye is included
with the vat dyes.
SYNTHETIC ORGANIC CHEMICALS 23
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
1095
Classified Dyes— Continued
ANTHEAQUINONE VAT DYES
(SINGLE STRENGTH)
Anthraauinone vat yullow QC
(121,-2 percent).
Anthraquinone vat golden orange
G (121 2 percent).
Anthraquinone vat golden orange
R (12M percent).
Anthraquinone vat scarlet GS
(16^^ percent).
Anthraquinone vat dark blue BO,
(25 percent) .
Anthraquinone vat jade green (6
percent) .
Anthraquinone vat green B and
black B ( 12 Vo percent).
Anthraquinone vat violet R (25
percent) .
Anthraquinone vat violet RR
(121.2 percent).
Anthraquinone vat violet B (25
percent) .
Anthraquinone vat blue RS (10
percent).
Anthraquinone vat blue 3G (10
percent).
Anthraquinone vat blue GCD
(8 i-i percent).
Anthraquinone vat blue BCS (20
percent.
Anthraquinone vat yellow Q (123-^
percent) .
Anthraquinone vat brown B (22
percent).
Anthraquinone vat pink R (12i-^
percent) .
Anthraquinone vat yellow R (12i^
percent).
Anthraquinone vat red FF, extra
(121 2 percent).
Anthraquinone vat brilliant violet
215 (121 2 percent).
Anthraquinone vat brilliant violet
R (123-2 percent).
Anthraquinone vat olive R (12)2
percent).
Anthraquinone vat brown R (12}/^
percent) .
Anthraquinone vat brown G (12} 2
percent).
Anthraquinone vat red violet
RRN (12}.^ percent).
Anthraquinone vat red BN, extra
(121-2 percent).
Anthraquinone vat violet BN (25
percent).
Anthraquinone vat yellow R (I21.2
percent).
Anthraquinone vat blue green B
(12^2 percent).
INDIGOID AND THIOINDIGOID DYES
Indigo, synthetic (20 percent)
Indigo white (20 percent) --
8,62,85
Pounds
635, 438
272, 528
Pounds
662, 833
241,072
$616, 506
322, 210
$0.93
1.34
1096
8,62,85, 144
1097
62,144
1098
8,85, 144
1099
1101
6,8,62,85,144, 161..
62
300, 321
274, 949
313, 713
1.14
1102
1103
8, 62, 8.5, 144, 161
85
342, 939
360, 782
147, 737
.41
1104
1105
6,62,85, 144
85
183, 532
185, 680
306. 768
1.65
1106
8,62,85
1109
62 _
1113
1114
60, 6ii, 85, 144
6, 8, 62, 85, 144
1,011,299
917, 234
1, 110, 127
544, 407
1, 234, 766
.59
1 11
1118
62, 85, 144
1120
62
11?8
85
1132
6,62
1133
62..
1134
62-...
1135
62
1150
62,85,144
1151
62,85, 144
1152
02,144...
1161
62,85
1162
62, 144....
1163
62 _
1170
62.... -
1173
161...
1177
60, 62, 144
12, 474, 777
11,949,582
1,842,718
.15
1178
144
1180
62, 144
1183
Tribroinindigo RB (20 percent)
Broniindigo blue 2BD (16 percent).
Vat blue 5B (20 percent) - -
60, 144
1184
60,85, 144
1186
60 . .
1207
Ciba pink B (2U percent)
60
1210
Vat red B (12i.-. percent)
85
1212
Vat red 3B (20 percent)
60,62,85, 144
8,62,85, 137, 144
60
192, 605
469, 268
184,115
416, 754
237, 176
395, 600
1.29
1217
.95
1228
Vat fast scarlet O (20 percent)
Vat red R (10 percent).. -
1229
60....
24
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production
and sales
, by types, 1939—
-Con.
Col-
our
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
In-
dex
No.
Quantity
Value
Unit
value
^2
Classified iJj^es— Continued
FOOD DYES
Yellow AB
66, 144
Pounds
Pounds
61
Yellow OB
66, 144
80
23, 121, 144
150
23, 121, 144, 206, 229..
23, 121, 144, 206, 229..
23, 121, 144, 206, 229..
23, 144, 229
85, 121
118,988
106, 542
88, 495
114, 738
100, 095
,$199, 370
275, 757
250, 029
$2.25
184
2.40
640
2.50
666
670
Light green SF (yellowish)
23, 144, 229
773
2.3, 121, 144,206
23, 121, 206
8,876
7,644
97, 829
12.80
1180
Brilliant blue FCF
23,144,229
3,656
5,946
58,851
9.90
Fast green FCF
229
144,229
Sunset yellow FCF
23,121,144,206,229...
58, 369
57, 860
138, 150
2.39
483, 227
478, 386
1, 375, 792
2.88
Totali classified dyes
99, 563, 360
95,074,041
48,018,116
.50
Unclassified Dyes
2, 584, 873
2, 402, 148
2, 210, 758
.92
Amacel brilliant blue B
6 .-
6
6...
Black, AD, AS,AZ, B, BAM,
BBN, BDN, BG, BGD,
BNF, BNS, BZA, DY,
GFS, 3G, 3GNJ\ GY, J,
JN, LNB, NAZ, NBZ, NS,
, NSJ, RB, SS, III, IV, IV
dbl.3
Blue B, BB, G, R, 5RB, III,
IV, XIII.
6, 8, 62, 79, 85, 144,
167, 235, X, X.
6, 62,85, 137
1,369,927
1, 292, 982
785, 345
.61
8
Brilliant blue, B, D, 2G, R
8,62,167,236
94, 889
78,657
125, 750
1.60
62
Brown BR, Y
62__
62.
Direct blue S
8
Direct orange R
X
Direct red 3B
X
Direct sapphire blue G
Direct sky blue GA
X
X
Direct yellow GA
X
Fast black B, BTN
85 ..
Fast blue AF, B, 3BFU, FFR,
GG, GR.
Fast brown 3R, 5R
6,85
85
62...
Fast navy blue B, BR
85
85
Fast red GG
85 .
Fast red violet RN
85
85
Fast yellow G, GL, GR, RR..
Green BS
62,85 .
62 --
Green blue II
6
Heliotrope I
6
6
Navy blue B, BN cone, BP
cone, BX, R.
Orange, BL, OR, R, RR, 3R,
4R, I, II, III, ex.
Pink II
6, 62
6, 8, 62, 79, 85, 137,
167,2.35.
6
64, 473
70, 640
67, 738
.96
Pure blue BR, BR cone - -
62
6
Red, BR, 3B, 6B, FSI. GG,
R, RP. 2Y, I, III, V. VI-X,
VII, VIII.
Red violet R, Y
6,8,62,85,167
62
70, 296
69, 009
76, 988
1.12
Rubine B, G, IX
6,62,79,235
Scarlet, B BN, III
6,8,62,79,85
27, 105
20, 022
21, 885
1.09
Sky blue B
62
Turquoise MG
85
2 Includes black, developed black, and cellitazole black.
SYNTHETIC ORGANIC CHEMICALS 25
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified Dyes — Continued
Acetate silk dyes — Continued.
Violet, B, BR, (jB, CB, RL,
RR, 11.
Violet blue FSI^.
Yellow, FSI, G, GG, 5G,
VIII.IX, XI, XII.XIII.
Other
Acid alizarin fireen B
Acid anthracene brown PG
Acid anthracene yellow GR ex
Acid black, AR. BR supra., 8B.
8BN, ,3G, GRF, GRF cone, J,
RB, TL, WA, 640, 773.
Acid blue, BL, 2G..
Acid blue black RC
Acid Bordeaux R
Acid brilliant blue 3B, RR
Acid brilliant green lOG
Acid brilliant red 2BA, 4BL, SB,
G.
Acid brown, FN, MF, N, R
cone.
Acid ceresine .-.
Acid chromal brown AKB
Acid chrome blue 2R, 2RA..-
Acid fast black BBN
Acid fast blue B, G. IB, NB
Acid fast brown CGS
Acid fast light red BL cone, 4BL..
Acid fastoranep LW
Acid fast red BL, CY
Acid fast yellow JY, RS
Acid flavine cone _.
Acid garnet GR cone
Acid green BL, GR, S
Acid light rubine BL
Acid milling brown R supra
Acid milling yellow G, 20X, R....
Acid naphtliol blue black
Acid navy blue cone, B, B cone,
M4B.
Acid neutral red 3G ex. cone
Acid neutral yellow GNS.
Acid olive Q
Acid orange G, GS, R, 2R, 4R,
SGS, YF.
Acid red, 3B, OA
Acid sapphire G
Acid scarlet G cone, Y
Acid spirit black
Acid spirit orange R
Acid spirit yellow 2R
Acid violet B, BS, RNL, RL,
2R, 2RX.
Acid wool blue BL
Acid yellow, cone, O, 2G, 5G, R..
Alizarin L
Alizarin blue AR, A20, GS
Alizarin fast blue RB.
Alkali fast green lOQ _.
Anthracene blue SWN'
Anthracene chrome brown RL
Anthraquinone blue BGA, 3Q,
SBF, SWB, WSA.
Anthraquinone vat black 2Q, J, R.
Anthraquinone vat black brown
V.
Anthraquinone vat blue CLX,
GCL, GR, R, RCX.
Anthraquinone vat blue green B,
FFB, V.
Anthraquinone vat brilliant orange
GR, RK.
Anthraquinone vat brilliant red B..
6, 62, 85, 167, 236.
6.
Pounds
34, 851
Pcnivds
35, 061
$63, 089
6,8,62,79,85, 167- -.
X
72, 603
87, 831
84, 635
1.80
'.96
236
85
X
6, 8, 54, 62, 85, 144, X.
165, 172, X.
62
X
6,62
62
6,62, 144, X.
8,165-
44
44.85--
62
62. 144-
62
62, X..
8,62....
6,8
172
172
165,172-
85
6
8,44,165...
44
6. 8, 62, 235.
6,633
6,464
18, 466
10, 462
.97
.57
6, 8, 62, 85, 144, 165,
X.
44,165
X
165
,417
56, 311
61, 616
1.09
8, 44, 165, 172, 235.
62.
8, 44, 165.
50, 367
45, 225
29,019
.64
8.5, 144.
144--..
85
144-.-.
236--..
62
8,144-
85...-
60, 62, 144.
62,8.5,144-
85
62
122, 842
140, 257
1.14
26 UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Unclassified Di/es— Contioued
Anthraquinone vat brilliant scarlet
BGN.
Anthraquinone vat brilliant yellow
4G.
Anthraquinone vat brown BE,
NR, RR, VR.
Anthraquinone vat dark brown R . .
Anthraquinone vat deep black
Anthraquinone vat direct black 3G_
Anthraquinone vat fla vine GC
Anthraquinone vat golden orange
3G.
An<hraquinone vat golden yellow
GK, GO.
Anthraquinone vat gray GD,
M3G, R, RL.
Anthraquinone vat green IB W
Anthraquinone vat khaki, GG
Anthraquinone vat navy blue, BN,
BR, G,3G.
Anthraquinone vat olive G,- GGL_ _
Anthraquinone vat olive green B _ . .
Anthraquinone vat pink B
Anthraquinone vat printing black
B suprafix, TL suprafix.
Anthraquinone vat printing brown
TM suprafix.
Antliraquinone vat printing green
BG suprafix.
Anthraquinone vat red G2B
Anthraquinone vat red brown R —
Anthraquinone vat scarlet 3B,
GGN.
Anthraquinone vat violet FFBN— .
Anthraquinone vat yellow 8G _
Artificial silk black, G, R, 2R
Azo Bordeaux 2BL,7B
Azo brown
Azo cosine 2B._ _.
Azo fast blue 2R
Az 0 fast orange G
Azo fast violet.--
Azo fast yellow GN.GR
Azo green 3G
Azo oil black-
Azf oil blue black B
Azo orange GN, GR, GXA, RS,
3RP.
Azo red 7BL
AzoscarletG, RB, RP-
Azoanthrenedyes:
Black N
BlueG, L,S
Blue green B
Green G -
Navy BR, GW
Orantre R
Red7B
RubineB,S
Scarlet G,Y
VioletB-
Yellow R,S
Azoic dyes and their components,
total.
Dyes:
Rapid fast:
Orange, RH
RedRH
ScarletlLH
Rapidoeene:
Black DM, MG
Black brown IT
Blue.BN, D, GN, N,
R.
Bordeaux, MR, RN..-.
Manufacturers'
identification
numbers (according
to list on p. 58)
85 -
62-
62, 85, 144-
62-.
85.-
62..
144-
85--
85
8, 62, 85-
85
62, 85, 144.
6,8,62,85.
62.-
144-
85--
85
62-
44, 85, 235-
165
165
62
144
85
144
85
165
144
144
165
165-
165.
8,62,85-
62,85...
62
62,85
85
62, 85, 165.
62, 85, 165.
Produc-
tion
Pounds
316, 793
136, 824
3,317,761
Sales
Quantity
Pounds
268, 156
3, 144, 736
Value
$249, 252
4, 707, 546
Unit
value
3.93
1.50
SYNTHETIC ORGANIC CHEMICALS
27
Table 9. — Coal-tar dyes: United States production and sales, by types, 1989 — Con.
Name of dye
Unclassified Z)j/e«— Continued
Azoic dyes and their components
— Continued.
Dyes— Continued.
Rapidogene— Continued.
Brown, ON, IB, IPT..
Calconyl red G _
Calconyl scarlet R
Dark brown AR
G, double,
Golden yellow MRS,
R.
Orange G, R
Red, BB, FFO, FFR,
G, GB, OS, M2B, R.
Scat\et, FFR, R, RBY,
R, S
Yellow, FF2G, G, 2G,
GS.
Components:
Fast color bases:
Fast garnet GBC
Fast red B, GL, KB,
TR.
Fast scarlet GG, R-..^
Fast color salts:
Black B
Blue B, BB
BlueBN
Bordeaux, BD. GP...
Garnet GBC, GC
Orange, GC
Red, AL. B, G, 30,
GL, 3GL, KB, RC,
TR.
Scarlet GO--
Scarlet R
Variamine blue BD..
Naphthols:
Naphthol AS
Naphthol AS, BO
Naphthol AS, BR-_-_
Naphthol AS, BS
Naphthol AS. D
Naphthol AS. OL
Naphthol AS, OP
Naphthol AS, PH...-
Naphthol AS, RL
Naphthol AS, SW....
Other
Basic orange 3RN
Benzoform red 7B, O
Benzoform violet BB
Brilliant benzo violet B.
Brilliant blue 5B
Brilliant milling blue B _
Brilliant milling green B cone
Brilliant milling vellow 50
Brilliant wool blue BN, FFR. G ex.
Chromatc blue black B
Chromato brilliant brown RL
Chromate brown, EB, EBR, BBS
cone
Chromate red 20..
Chrome black 30, NSE, P2B, PV,
SW
Chrome blue ATX, ECR
Chrome brilliant orange 2R
Chrome brown B, BC, 3B, EB.
EBL, G, O.PG, RII cone, 4RC
Chrome garnet R
Chrome green B, CB, G
Chrome leveling brown B..
Chrome orange 3R
252005—40 5
Manufacturers'
identification
numbers (according
to list on p. 58)
85, 165-
8
62
85
62, 85-
62.85
62, S5, 165-
62, 85, 165-
62, 85, 165.
X_
85, 144-
85, 165, X
85, 137, 144-..
85, 137, 144, X.
X
85,144,165-...
8.5, 144, X
85, 144, 165, X.
85, 144, X
85-
6,8,85, 144-..
6, 85, 144
6, 85 --- -
6, 62.85, 144- -
6. 85, 144, 165.
85. 165---
165
85
85
6,8,5, 144
6,85...-
62
85
62- - - -
144..-
62, 85.
62
85. 144-
44
X
8, 62, 235, 236, X.
236
62, 144, X.
62
6, 8, 44, 62, 85, 144.
X -
44, 144-
fi
144----
Produc-
tion
Pounds
176, 074
270, 025
759, 814
Sales
Quantity
Pounds
170,380
191,668
239, 828
707. 897
93, 940 104, 878
36.000 2«,05S
206, 043
197, 938
Value
$168, 698
179,617
174, 871
745, 650
82. 051
15.688
181.991
Unit
value
$0.99
.94
.73
.56
.92
28 UNITED STATES TARIFF COMMISSION
Table 9. — Coal-iar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Unclassified Dyes— Continued
Chrome yellow, 2G, 30, DS, OD,
R-105, SW
Ciba black
Cloth fast blue R
Cloth red 2R, Y
Cotton black 3G
Croceine scarlet F P cone _ _ .
Developed black G, GA, NSB, OB,
OB ex., OT, ZV cone
Developed blue B, BR, BR cone,
BR ex., BRG, 5GL, 6G.
Developed Bordeaux 7B, 7B cone,
2BL, BGL, RB.
Developed brilliant green 3B, 3G.
Developed brilliant orange G. GG.
ON.
Developed brilliant scarlet 2BL,
2BLex. cone, 5BL, RO.
Developed brown 60, NR, R,
3RB
Developed dark brown B
Developed fast blue B
Developed fast brown RK
Developed fast red 7BL
Developed fast violet BL, 2RL
Developed iast yellow 2G
Developed garnet RD
Developed green BL, 2GL, GW..-
Developed indigo blue 4GL
Developed orange, OR, R, 2R, 3R,
RFW, WD.
Developed red BFW, 7BL, 7BL
cone.
Developed rubine B, B special
Developed scarlet A, 2BL, DIS,
FW, GFW, R.
Developed sky blue B , 3G L
Developed violet BRD, 2R
Developed yellow 4G
Diamond green SS
Diazophen red
Diazophen yellow
Direct black 3G, 3GR, 5G, NCW_.
Direct blue BB, FF, 3G, 5G, NR..
Direct blue green CW
Direct Bordeaux B, 6B
Direct brilliant blue BFL_ ..-.
Direct brilliant cerise . _ _
Direct brilliant red 12B cone
Direct brilliant violet B, 4B, R.._.
Direct brown CWR, CSW, FW,
GB, G2R, G3R, K, R, RB, RY,
S.
Direct catechine, GS, 3G, G cone.
Direct chrome black blue B
Direct chrome blue black B
Direct chrome brown BS
Direct copper blue BR, RR, RRX
Direct dark blue Sli
Direct fast black B, FA, FOR ex.
dbl., FRG, FOR, FTC, O, L, L
cone, PG ex. FGR, VE.
Direct fast blue FF, 3GL, 4GL,
8GL, LB, RR, LG. R, RL. SRL.
Direct fast brown BRL, BRLN,
4GL, LBR, LG, L3R, R, 2RL,
4R, 3YL.
Direct fast gray BL, GL, 2GL, R
Direct fast green 2Y
Direct fast light blue FF..
Direct fast olive brown RL
Direct fast orange EG, E30, ER,
G, 2G cone, 4G cone,2GL, GL
ex., L5G, L7G, L3R, RE, 6R, S.
Manufacturers'
identification
numbers (according
to list on p. 58)
8, 44, 62, 85, 144, 165 .
60
44
44, 144.
6, 44, 62, 85, 144, X_
6, 44, 62, 144, X
6, 62, 85, 144, X.
85, 144
85
62, 85, X.
62,85
X
44
62
62, X
62, X
85, 144....
6.
62
62,85
6, 62, 144.
6, 62, 144 _
85, X
62, 144, X.
85...
6,62.
62...
85...
44, 85, 144, 235-
6,62,144
144
6,85, 144
144
144
6,44
6, 8, 44, 54, 144, 235,
X.
6,62,144
X
85, 144.
62, 85.
X...
6, 44, 62, 85, 144, 235,
X.
62, 85, 144, X.
62, 85, 144, X.
62, 85, 144.
62
44
6.
8, 62, 85, 106, 144, X
Produc-
tion
Pounds
60, 343
326, 739
205, 658
82. 040
9,450
118, 425
84, 966
224, 489
118, 910
655, 634
287, 110
150, 376
37, 847
Sales
Quantity
Pounds
57, 061
123, 463
70, 012
213, 935
100, 468
545, 465
315, 787
143, 784
29, 552
241, 093
Value
$24, 842
201, 278
282, 158
161,117
55, 134
74, 738
69, 472
328, 892
404, 969
210, 002
52, 304
294, 494
Unit
value
.44
.63
1.34
.45
1.07
.79
.60
1.28
1.46
1.77
SYNTHETIC ORGANIC CHEMICALS 29
Table 9.^ — Coal-tar dyes: United States production and sales, by types, 19S9 — -Con.
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified Dyes — Continued
Direct fast red 5BL, 8BLN,
8BLSW.
Direct fast rubine 23, B cone
Direct fast turquoise 8GL
6, 44, 144, X
Pounds
Piiunds
6, 144
62
Direct fast violet BB, F
8,85
Direct fast yellow 4GL. 5QL, LR,
L5G,KL.
Direct gray BBC, G, Z
44,62,85,144
54, X
159, 034
159, 952
$263, 931
$1.65
Direct green GB, 5GSC
6,8
Direct green black,. ,_
44
Direct light yellow RL_ _ ...
44
Direct navy 4B, G, R_
6, X
Direct navy blue B, BF, BW, DB,
R, RY.
Direct orange B, R ._ _.. ...
8, 44, 62, 144,235
6,44,85
143, 305
127,588
90,163
.71
Direct red G-- . _ __
6
Direct reseda green .
6.
Direct rhoduline red B .
62.. . . .
Direct rubine B, Q _
6
Direct sapphire B
Direct scarlet G
Direct silk blue NR
Direct sky blue B
Direct speck dye red SW . _ .
X
6
85
44
144-
Direct violet BB, BRL, 2R
Direct violet black ,,- _.
6, 8, 144 - .
44
Direct viscose blue RS_ .__ .
85
Direct yellow R _ _._
6
Discharge brown RB
Drug and cosmetic colors
Fast acid black BR .
62
144
85
Fast acid blue R, WF
85, 144
85 .
Fast acid Bordeaux B
Fast acid brown RQ
144
Fast acid light red B
44
Fast acid orange RW ..
44
Fast acid red 3B, 20
Fast acid violet ERR ex
Fast acid yellow R ..
85
62 .
85
Fast black V
Fast crimson R
Fast light red B, 4B, BL, QL
Fast light rubine BL
62 ..
144
85, 144....
144
Fast light violet
236
Fast wool violet B
144
Fast wool yellow GS . .
144
Fluorol 5GR .
85
Fluoroleum supra
62 ..
Formal fast black Q
44 ..
Formaldehyde black GR ex
Formaldehyde red B
Formaldehyde scarlet Y
Formanol black RW
Formvl black Q
27
44
44
X
8 ..
Formyl blue B
8
Formyl brown
8
Gas yellow
8
Hansa yellow G
62, 85
Helio red RMT
85
Heliogen blue B, G
85
Heliogen green G
85
Hydroform navy blue
Hydroform yellow 3G
Indigo vat brown, G ..
161
161
8, 62, 144, X
8, 62, 137, 144.
144
313,015
372, 297
298, 948
399,889
329. 641
423,435
1.10
Indigo vat pink FB, FF
1.06
Indigo vat scarlet 2GN
Indocyanine B
Indophenal tan R
85
X
Indophenol black,.
Indophenol blue
X
X . ...
Jet black APX
62
Lake blue G, 6G
62
Lake fast blue BL cone
Lake fast orange G
62
62.
30 UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified Dj/es— Continued
Lake fast yellow lOG
Lake orange OTP
Lake pink RL
Lake red 2B
Lake scarlet 2YL
Lake yellow O, PL
Leather brown RR
Metalized azo gray G
Milling fast garnet R
Milling fast red B cone, FF
Milling fast yellow 5GL cone
Milling navy blue 4B
Milling red B, B cone, R
Milling yellow GN, 2GC W, 3G, O
cone, R, XN
Monastral fast blue BS-N, GS
Monastral fast green GS
Mordant green SN
Naphthol navy blue M
Naphthylamine black V
Neutral blue G
Neutral brown RD, 2RS, RX
Neutral silk brown RA, RWA
Neutral silk yellow CGA
Neutral yellow RX
Nigrosine base B, N, R, 2R
Oil blue
Oil bronze
Oil brown D, G, M, #79, #102
Oil fast black
Oil fast blue B, R
Oil fast orange A cone
Oil fast red M, Y
Oil fast yellow EG, 3G
Oil green
Oil orange, 0, 2R, soluble, #30, #67.
Oil pink B
Oil red, EG, EGN, G, O, OB, RO,
soluble, #322
Oil violet
Oil yeUow, N, PHW
Orange Y
Paper red AP
Patent blue B cone
Phenamine violet B
Phenanthrene brown CR
Phospbine R
Pigment rubine G, 3G
Plutoform black AM..
Polyform dyes:
Blue BRF
Dark brown 3BF
Dark maroon GF
Orance RF
Scarlet 2GF, RF
Yellow GF
Pyrazoline black
Pyrazoline blue 4GL, 8GL
Pyrazoline red BLW
Pyrazoline yellow 4GL, R
Rayon colors:
Black B
Bordeaux B
Brown G, M
Navy blue N
Violet 3B
Resin brilliant orange RR
Resin brilliant red R...
Resin brown Z
Resorcin brown YX
Rosanthrene A, R...
Rosanthrene orange
Rubber colors -
Safranine 8B
Pounds
Pounds
62
62
144
62
62
62, 144_
62
X
X
X
144
144, 165 _
62, 144, 165 _
62
62
20,030
44
62
165
8,62, 144, X
X
X
X
144
236
62
79,144
144
6, 144
J44
144
62, 144
236
8, 54, 79, 144, 233.
144
31, 563
25, 697
$37, 825
$1.47
28,280
28,059
23, 152
.83
6, 8, 54, 79, 144, 233 _
236
8,62,236
54
85
144
85
165
85
85.
85
153, 906
144, 486
62..
62..
62..
62-.
62_-
62.-
165-
165-
165-
165-
62..
62--
62.-
62-.
62..
144.
144.
144-
54..
62..
62..
62.-
144-
SYNTHETIC ORGANIC CHEMICALS 31
Table 9. — Coal-tar dyes: United States production and sales, by types, 1939 — Con.
Name of dye
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified D2/e«— Continued
Silk black 4BF, G, R
27,44
Pounds
Pounds
Silk blue lOG
62
Silk brown G, R
X-. ...... _-
Silk fast blue 3G
62
Silk fast brown R
27
Silk fast yellow G
27
Silk red 2B, 4B, 3BX, lOB
Stilbene brown 3GXij
Stilbene orange EG.-- --
27, 44, X-.
7,677
$11,481
$1.50
8
8
Sudan corinth B --- ..
85
Sudan orange FL, RT -
85
Sudan red 4B -__ -
85
Sulfon yellow RS
85
Supranol red PB -
85
Supranol yellow GG.
85
Wool blue CGG
Wool navy blue B
144
144
Wool red special
Zambesi black BG, D, PC, V. ..
Another .
165
44,85, 144
62, X, X..
409, 056
440, 334
. 242, 336
.55
Total unclassified dyes
20, 627, 328
19, 419, 927
22,205,485
1 14
Total dyes:
Those for which individ-
ual statistics are shown.
Those for which individ-
ual statistics cannot be
shown -
88, 122, 738
32, 067, 950
84, 926, 053
29, 567, 915
40, 696, 744
29, 526, 857
48
1 00
Grand total
120, 190, 688
114, 493, 968
70, 223, 601
61
COLOR LAKES AND TONERS
Improvement in the surface-coatings and decorating trades in 1939
accelerated trade in color lakes and toners. Production was 18,154,000
pounds, and sales were 15,577,000 pounds, valued at $11,785,000. In
1938 the output was 14,407,000 pounds, of which 12,658,000 pounds
were sold for $9,403,000. In both 1938 and 1939 toners, or full-
strength colors, constituted 67 percent of the value of total sales
of the group, lakes and extended colors were 29 percent, and reduced
toners 4 percent.
Statistics of production and sales of color lakes and toners in 1939
are shown in table 10.
32
u:nited states tariff commission
Table 10.— Color lakes and toners: United States production and sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on p. 58.
An X signifies that the manufacturer did not consent to the publication of his identification number with
the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics of pro-
duction or sales cannot be published without revealing information with regard to individual firms. The
figures thus concealed are, however, included in the total]
Name of product
Manufacturers' identification numbers
(according to list on p. 58)
Produc-
tion
Sales
Quantity
Value
LAKES AND EXTENDED
COLORS
Alizarin
Azo Bordeaux.
Black _
Blue--
Brown
Eosine and phloxine-
Fast light yellow
Green
Helio fast rubine -
Litholrubine
Maroon^
Methyl violet
Naphthol yellow.
Orange
Peacock blue -
Persian orange .
12, 62, 99, 112, 118, 121, 134, 139, 169, 197,
216, 217, 236, X, X, X, X, X, X.
3, 12, 29, 62, 67, 99, 101, 121, 139, 169, 216,
217 XXX
51, 94,' 121, 134, 216, 217, 236, X, X
12, 29, 51, 62, 67, 74, 77, 94, 112, 118, 121,
134, 208, 216, 217, 233, X, X, X, X, X,
x,x,x,x.
12, 51, 77, 101, 121, 134, 216, 217, 233, 236,
X.
12, 29, 35, 67, 74, 77, 94, 111, 121, 134, 197,
208, 217, X, X, X, X, X, X, X.
12, 77, 99, 101, 121, 134, 208, 217, X, X, X,
X X
12, 29, 51. 62, 67, 74, 77, 94, 112, 116, 118,
121, 134, 208, 216, 217, X, X, X, X, X,
x,x,x.
12, 29, 51, 62, 101, 116, 118, 208, X, X, X,
x,x.
12, 29, 51, 62, 74, 77, 112, 121, 197, 208, X,
x,x,x,x.
12, 35, 62, 67, 94, 101, 121, 134, 139, 233,
XXX
12, 29, 51, 62, 67, 77, 94, 101, 121, 134, 197,
208, 216, 217, 236, X, X, X, X, X, X,
X.
12, 74, 77, 121, 217, 236. X, X
29. 35, 51, 62, 67, 94, 101, 118, 134, 217, X,
X, X,X, X.
12, 29, 35, 51, 62, 74, 77, 99, 101, 111, 121,
134, 197, 208, 216, 217, 236, X, X, X, X,
X X X X X X
12, 35, 62, 74, 77, 99, 'ill, 121, 134, 197, 208,
216. 217, X, X, X, X, X, X, X, X, X,
Phosphomolybdic acid
lakes, total:
Blue-' ■-
Brown i
Green
Purple--
Red.
Violet
Phosphotungstic acid
lakes:
Blue
Pounds
153, 981
373, 498
126, 021
478, 362
48, 464
197, 317
215, 946
325, 264
54, 546
325, 714
655, 937
177, 263
22, 250
198, 531
1, 353, 943
436, 108
09,040
35,77, 116, 208, X,X,X-
118
51, 62, 77, 118, X, X
29,51,67,77
29,51,X
35 --..
Pounds
100,538
333, 293
105, 897
323, 772
24,442
190, 320
46, 285
250, 966
41, 173
330, 613
644, 566
174, 134
18, 125
169, 237
1, 080, 108
315, 861
56,957
$128, 126
105, 295
48, 041
182, 748
6,204
135, 539
32,323
143, 909
95, 749
148, 342
86,541
13, 895
50, 262
614, 959
129, 582
31, 263
Green.
Purple .
Red...
Pigment scarlet -
Quinoline yellow -
Red
Scarlet 2R.
Tartrazine.
Violet
Yellow . - .
All other-
Total lakes and
extended colors.
8, 12, 29, 51, 62, 74, 77, 94, 101, 112, 118,
121, 134, 197, 208, 217, 236, X, X, X. X.
8, 29, 51, 62, 67, 94, 101, 112, 134, 217, X,
XXX
29, 51, 94, 101, 134, 197, 208, 217, X, X,X.
8, 12, 28, 29, 35, 51, 62, 74, 77, 94, 101, 112,
118, 134, 197, 217, X. X, X.
12, 29, 62, 77, 101. 121, 134, 169, 197, 216,
217, 236, X,X, X, X.
12,99, 111, 121, 197,208, X,X,X
29, 35, 51, 62, 67, 74. 77, 101, 118, 121, 1.34,
197, 208, 217, 233, X, X, X, X, X, X, X.
3, 12, 29. 35, 62, 94, 116, 121, 169, 197, 216,
217, 233, X, X, X. X, X, X, X, X.
35, 77, 99, 101, 111, 121, 1.34, 197, 208, 217,
X X X X X X
12,51^62,77,94,101.118,233
12, 35, 51. 62, 77, 118. 134, 217, X, X
28, 51, 74, 99, 1.34, 2,36, X, X, X
398, 185
202, 547
41,510
228, 904
333, 486
28, 586
439, 880
909, 822
191, 688
16, 133
148, 419
104, 200
8, 255, 545
394,
169,
36,
194,
23,
395,
843,
178,
16,
132,
44,
336,
28,
114,
127, 895
18,
209,
234,
99,
12,
41.
49,
6, 894, 974
3, 381, 712
SYNTHETIC ORGANIC CHEMICALS 33
Table 10. — Color lakes and toners: United States production and sales, 1939 — Con.
Name of product
Manufacturers' identification numbers
(according to list on p. 58)
Sales
Produc-
tion
Quantity Value
Unit
value
TONERS OR FULL-
STRENGTH COLORS
Eosine and phloxine
Oreen
Hansa yellow
Lake red C
Lake red D
Lithol
Lithol rubine -.
Maroon
Methyl violet
Orange
Para red
Permanent orange.
Phosphomolybdic acid
toners:
Blue
Green
Purple
Another
Phosphotungstie acid
toners:
Blue-
Green
Purple
Red....
Bed
Toluidine red _..
Yellow
iVU other
Total toners or
full-strength
colors.
REDUCED TONERS
Lake red C and D
Lithol..
Para red
Toluidine red
Another
Total reduced
toners.
Total color lakes
and toners.
1 Included in all other
12, 74, 77, 99, 197, 208, 217, 236, X, X, X
X.
12, 62, X, X
12, 35, 62, 99, 101, 111, 112, 121, 236, X, X
XXX
8, 12, 35,' 51,' 62, 74, 77. 99, 101, 111, 121, 1.34
197, 208, 216, 217, 236, X, X, X, X, X
X.
35, 121, 197, 2.36, X_ .
12, 35, 51, 62, 74, 77, 99, 101, 121, 197, 216
217, 233, 236, X, X, X, X, X, X.
12, 29, 51, 62, 74, 77, 99, 101, 116, 121, 197
X X X X X X
12, 62, 74, 101, 'lie' 121, 169, 216, 233, 236
X X X X X
8, 12, 29,'65, 74, 77, 94, 99, HI, 121, 208
216, 217, X, X, X.
12, 74, 77, 99, 112, X, X. X
3, 12, 29, 35, 51. 62, 74, 99, 101, 116, 121
169 197, 216, 217, 233, X, X, X, X, X
X X X X X
8, 77, 99, 101 r 116, 236, X _.
29, 35, 62, 77, 99, 101, 121, 216, X, X, X..
35, 99, 101, 121, 216, X .
29, 51, 62, 65, 101, 208, 216, X, X
29, 35, 51, 99, 101, 121, 134, 208
12, 29, 51, 62, 74, 77, 101, 116, 121, 1.34, 197,
20S, 217. 236, X, X, X, X, X, X, X.
29, 51, 62, 67, 74, 77, 101, 121, 134, 169, 197
208, 217, 236, X. X, X. X, X, X, X, X
12. 29, 51, 62, 101, 134, 197, 208, 217, 236
X X X X X X
12, 29," 51, 62, 74, 77, 101, 121, 134, 197, 217
236 X X X X X
8, 29,'51,'62,'77,'99,' 101, 121, 233, 236, X
X X X X X
3, 12, 35,'51,V>2,'67, 74, 99, 101, 116, 121, 169
197, 216, 217, 23.3, 236, X, X, X, X, X
X, X, X, X, X, X.
12, 51, X, X
8, 29, 74, 99, 101, 121, 208, X, X, X
12, 35. 62, 74, 94, 101, 121, 134, 197, 208, 217,
X, X.
12, 29, 51, 62, 74, 77. 94, 101, 121, 197, 208,
217, 236, X, X, X, X.
3, 12, 29, 35, 62, 74, 101, 116, 121, 169, 216,
217, 233, X, X, X, X, X, X.
3, 12, 28, 29, 35, 62. 67, 74, 94, 101, 112, 116,
121, 169, 208, 216, 217, X, X, X, X, X,
X, X.
3, 12, 28, 51, 62, 94, 101, 134, X, X, X.._.
Pounds
270, 877
47, 183
244,750
533, 742
11,503
2, 843, 295
160, 259
519, 152
241, 385
28,756
1, 162, 691
125, 405
17, 148
16, 455
26, 120
30. 095
113,664
91, 154
85, 291
52, 336
383. 041
950, 291
75,917
8, 620, 406
56, 419
307, 460
407, 924
214, 904
291, 149
1, 277, 856
18, 153, 807
Pounds
153, 041
32, 170
205, 997
414,417
7,398
2, 551, 064
151,415
506, 723
219, 179
26, 997
991, 996
114,853
9,475
(')
23, 659
30, 013
100, 116
76, 601
68, 605
44, 699
360, 244
846, 626
74, 028
543, 405
7, 552, 721
54, 671
286, 875
400,195
165, 820
222, 090
1,129,651
15, 577, 346
$224, 399
39, 082
276, 031
414, 074
6,938
1, 448, 926
175, 943
1, 136, 340
240, 040
27, 180
725, 685
98, 045
30, 371
(')
21, 679
73, 683
298, 572
226, 646
138, 356
162, 279
360, 171
1, 030, 223
111,075
680, 013
7, 945, 751
30, 174
107, 732
61,613
46, 094
211,972
457, 585
11, 785, 048
34
UliflTED STATES TAEIFF COMMISSIOIsr
MEDICINALS
Synthetic medicinals, both coal-tar and non-coal-tar, increased in
production and sales in 1939.
In the coal-tar group the output in 1939 was 15,188,000 pounds,,
and sales were 12,932,000 pounds, valued at $13,711,000, compared
with production of 11,097,000 pounds and sales of 8.885,000 pounds,
valued at $9,509,000 in 1938. The 5,372,000 pounds of aspirin manu-
factured in 1939 represents an increase of 38 percent over 1938. Pro-
duction and sales of sulfanilamide about doubled. The average sales,
value dropped from $1.79 a pound in 1938 to $1.28 a pound in 1939.
Sulfapyridine, used in the treatment of certain types of pneumonia, and',
synthetic ephedrine, were reported for the first time. Prior to 1939'
the entire domestic supply of ephedrine had been extracted from
medicinal plants imported from the Orient.
The production of non-coal-tar synthetic medicinals in 1939 was
1,668,000 pounds. Sales were 1,483,000 pounds, valued at $6,120,000.
In 1938 the output was 1,379,000 pounds, and sales were 1,137,000
pounds, valued at $2,278,000. The much larger increase in sales value
than in sales qviantity in 1939 was due to a greater increase in sales
of certain high-priced products than in the lower-priced commodities
of the group and to the inclusion for the first time of figures for the
very high-priced synthetic horjtnones in the group total.
Statistics of production and sales of synthetic medicinals in 1939
are shown in table 1 1 ,
Table 11. — Synthetic medicinals: United States production and sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 58. An X signifies that the manufacturer did not consent to the publication of his identification num-
ber with the designated product. Blanks in the third, fourth, and fifth columns indicate that the sta-
tistics of production or sales cannot be published without revealing information in regard to individual
firms. The figures thus concealed, however, are included in the total]
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAR
Acetanilide -_.-- ._..__-
46, 60, 138, 142.....
60, 142, 209, X
Pounds
427, 983
Pounds
496, 482
$116,412
$0.25
Acetphenetidin _ .. .__ .
Acetylamino-hydroxy-phenyl arsonic acid and
salts (Acetarsone) (Stovarsol).
Acetylsalicylic acid (Aspirin)
p-Aminobenzosulfonamide (Sulfanilamide)
p-Aminobenzoyl di-n-butylamino propanol
1, 140, X
60, 142, X, X, X...
8, 32, 83, 140, 142,
X.
1
5, 371, 682
709, 148
5. 343, 234
'711,099
2, 520, 282
911,938
.47
1.28
(Butyn base).
p-Aminobcnzoyl di-n-butylamino propanol
sulfate (Butyn sulfate).
p - Aminobenzoyldiethylaminoethanol ( P r o -
caine).
p- Aminobenzoyldimethylaminomethyl bu-
tanol hyiliocliloride (Tutocain).
m-Amino-|i-hydr(ixyphcnylarsine oxide hy-
drochloride (Mapharsen).
Ammonium mandelate
1
1, 25, 83, 155, 209,
X, X.
X
9,218
10, 588
293, 478
27.72
X
201
Amvl-m-cresol
X
Antipyrine
60 . .
1, 140
Arsphenamine
1, 69, 132, 140, 201,
X.
X, X
328
233
27, 782
119. 24
Barbituric acid derivatives:
Cyclohexcnylmethylmethyl barbituric acid
and salt.
Phenobarbital ...
1, 25, 83, 132, 140,
209, X,
25....
109, 825
131, 182
514, 262
3.92:
Phenobarbital calcium
SYNTHETIC ORGANIC CHEMICALS
35
Table 11. — Synthetic medicinals: United States production and sales, 1939 — Con.
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAE— continued
Barbituric acid derivatives— Continued.
Phenobarbital sodium, _
1, 25, 83, 132, 140,
209.
X
Pounds
12, 780
Pounds
13, 539
$49, 219
$3.64
Phenylethylmethyl barbituric acid
Phenylethylmethyl urea sodium
X
"Benzaldehyde
X, X
Benzidine hvdrochloride ..... ....
X
3enzochrome
187 ..
Benzoic acid- .-_-_- _
62, 142, 209
Benzovl - tetramethyldiamino - ethvl - isopro-
X
panol hydrochloride.
Benzylmethyl ketone
X
Bismethvl benzylidine
X
Bismuth betanaphthoL
140
Bismuth tribromophenol .
140
60
n-Butyl-p-aminobenzoate (Butesin)
1
p-Butylaminobenzovl dimethylaraino ethanol.
X
a-Butvloxycinchoninic acid diethylethylone
X
diamide and hydrochloride.
Caffeine sodium benzoate -.. -.. -.
132, 140, 149, X ...
Caffeine sodium salicvlate
140
'Calcium cresol sulfonate
X .
Calcium iodoxybenzoate
X
Calcium mandelate
1, 132, 140 .
10, 914
9,721
17,668
1.82
'(Colchicine salicylate
140 .
m-Cresyl acetate (Cresatin)
190
2:5-Diaminetoluene sulfate
69. .
Dibenzyl ketone
X.... .. .
Di - n - butyl - p - aminobenzoate trinitrophenol
1
(Butesin picrate).
n-Difithy lam inoiso pent vl-8-amino-6-methoxy
X ...
quinoline.
3:4 - Dihydroxy phenyl ethylmethylamine
32
(Epinine).
4-Dimethylamino antip>Tine (Aminopyrine)
144, X
62
Dioxv anthranol (Anthralin)
1 .
Disodiumhydroxymercurisalicyloxy acetate
X
(Mercurosal).
Disodium -4-sulfaminophenyl -2-azo -V-acetyl-
X-
amino-l-hydroxynaphthalene-Sie-disulfonate.
Dyes, medicinal, total
46, 688
46,234
1,130,004
24.44
144...
Brilliant green
144
3:6-Diamino acridine sulfate (Proflavine)
1, 144
1, 144
(Acriflavine).
104
um salt (Mercurochrome).
'Gentian violet
144 . .
Hexalet
140
Methylene blue
8, 144
Methyl violet
144
Parafuchsine
144 . .
Phenolsulfonphthalein
25, 104
Phenylazo-diamino pyridine hydrochloride
(Pyridium).
Scarlet red
176
144
Sulfosalicylic acid
140
140
Ephedrine, svnthetic
140, X .
Eserine salicvlate
140
Ethocaine borate (Borocaine)
190, X
Ethyl-p-amino benzoate (Benzocaine) (Anes-
thesine).
Ethylenediamine mandelate
1, 25, 83, 140, 155,
209, X, X.
X
11,899
15,295
49,205
3.22
Qamma-diethylaminopropylcinnamate hydro-
chloride (Apothesine).
Guaiacol (liquid)
X
142, X ...
1
(Salihexin).
190
Homatropine and salts
140
X
1
8-Hydroxyquinoline (Oxyquinoline base)
25, 140
36 UNITED STATES TARIFF COMMISSION
Table 11. — Synthetic medicinals: United States production and sales, 1939 — Con,
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAK— continued
8-Hydroxyquinoline-5-sulfonic acid
25, 140, X...
Pounds
Pounds
o-Iodobenzoicacid__
69, X
o-Iodosobenzoic acid
X
lodoxyquinoline sulfonicacid (Yatrenacid)
X, X
Laevo-methylaminoethanol catechol (Epin-
X
ephrine).
Lithium benzoate ...
x...
Lithium salicylate
X
Magnesium benzoate
X
Magnesium salicylate
60, 132, X .
3,791
42, 423
4,656
37, 274
$4,691
68, 509
$1. 01
Mandelicacid
1, 132, 140
1.84
Menthyl salicylate ._
209, X
2-Methyl-6-chloro-9-diethylaminopentylamino
X
anisidine.
Methyl-m-amino-p-hydroxy benzoate (Ortho-
X
form).
Methylene-citrylsalicvlic acid (Novaspirin)
X
Methylene disalicylic acid derivative (Formi-
X
dine).
p-Methylphenyl cinchoninic ethyl ester (Neo-
1,8, 25
5,560
4,747
47, 152
9.93
cinchophen).
Mono n-amvlaminoethyl p-aminobenzoate
155
(Amylcaine).
Monoisobutylaminoethyl p-aminobenzoate
155
(Monocaine).
Neoarsphenamine -
1, 69, 132, 140, 201,
X.
1
9,686
9,609
903,685
94.05
Neo-silver arsphenamine - - -
Neo-synephrin hydrochloride
X.... _
Nicotinic acid
83,86, 140, 149
Nicotinic acid amide -
86
Oxyquinoline benzoate
25, 140
Oxyquinoline citrate
140
Oxyquinoline sulfate . . .
25, 140
Oxyquinoline tannate
25
Phenolphthalein
142, 164, X
Phenolsulfonates (calcium, sodium, zinc, etc.)..
Phenyl isocyanate ..
132, 140
69..
b-PhenyHsopropyl amine and sulfate
X.. .. .
Phenyl, mercuric acetate
70, 93
Phenyl mercuric benzoate
93 :. .
Phenyl mercuric chloride .
93
Phenyl mercuric hydroxide
70, 93...
Phenyl mercuric nitrate
70,93
Phenvl-propanolamine hydrochloride (Pro-
190
padrin hydrochloride) .
2-Phenylquinoline-4-carboxylic acid (Cincho-
8, 25
phen) (Phenyl cinchoninic acid).
Potassium oxyquinoline sulfate
26..
Propyl p-aminobenzoate -
X
Pyramidon and trichloroethvl alcohol ure-
X
thane compounds.
Pyridine-b-carboxylic acid diethylamide
X
Resorcinol
62, X
Resorcinol monoacetate
69, 140, X
4,299
4, 259, 675
3,575
2, 307, 174
9,057
662, 437
2.53
Salicylic acid
60, 142, X
.24
Salicylic acid acetyl-p-amino phenolate
Salol
X
60
Silver arsphenamine . .
1, X
Sodium diphenyl hydantoinate (Dilantin)
Sodium o-iodohippurate
X, X
132
Sodium methylene sulfonamino-hydroxy-
phenyl arsoaate (Aldarsone).
Sodium salicylate
1
60, 142, X
497, 234
519, 266
215, 028
.41
Sodium p-toluene sulfochloramide (Chlora-
mine T).
Sodium succinate
142
140
Strontium salicylate
60, 132, X
2-Sulfanilamido pyridine (Sulfapyridine)
mide).
Sulfoarsphenamine ...
8, 140
1, 59, 132, 140, X..
60
169
135
20,987
155. 46
Tetrachlorophenol
Tetraiodophcnolphthalein and sodium salt
(lodeikon) (Antinosin).
25, 32, 69, 132, 140,
144.
132, 140, 149 .
11, 192
6,250
101, 643
16.26
Theocalcin
140
Theophylline calcium salicylate
140
SY]!^THETIC ORGANIC CHEMICALS 37
Table 11. — Synthetic medicinals: United States production and sales, 1939 — Con.
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Theophylline sodium salicylate
132, 140
Pounds
Pounds
p-Tolqene sulfodichloramide (DichloramineT)-
142
60
32
Total coal-tar medicinals:
Those for which individual statis-
11.497, 806
3,690,472
9, 624, 059
3,307,652
$6,433,435
7, 277, 462
$0.67
tics are shown.
Those for which individual statis-
2.20
tics cannot be shown.
Grand total.
15,188,278
12,931,711
13,710,897
1.06
X
(B) NON-COAL-TAR
Acetannin (Tannigen) (Tannyl acetate)
69
Aminoacetic acid (Glycocol) (Glycine)
p-Amino di-n-butylaminopropanol hydrochlo-
ride (Butyn hydrocloride).
Amyl nitrite (Isoamyl nitrite)
5, 25, 60, 62, 83,
163, 209.
1
69, 132, X
Ascorbic acid ...
100,140,164
1
15, 654
16, 405
707,844
43.15
Barbituric acid derivatives, total
167, 393
87, 607
600, 975
6.86
1
Cyclohexenyl ethyl barbituric acid and
salts.
Diallylbarbituric acid and salts
X
X, X
Dibromobarbituric acid and salts (Dibro-
min).
X
1, 83, 100, X
tal).
1 126
salts.
Ethyl-1-methyl butyl thiobarbituric acid
and salts.
1
X
salts.
Hexylethyl barbiturate sodium (Ortal
sodium).
Isoamyl ethyl barbituric acid and salts
X
126
X
X
Monoethvl-othyl malonic acid
1
Pentobarbital sodium
X . ...
Propyl-methyl-carbinyl-allyl-barbiturate
sodium.
Benzoic acid ester of a-estradiol (Progynon-B) . .
126
186
60 132
X
Butyl ethyl malonic ester (n and sec.)
1 - .
164
X, X
Cami)hor (synthetic). (See table 15 (B).)
X
140, 142
Chloroform. (See table 15 (B).)
140
186
1.
Disodium of Sr.S-diiodo-n-methylchelidamic-
2:6-dicarboxylic acid (Neo-iopax) .
186
1
Ethyl chloride. (See table 15 (B).)
Ethy] ethor. (See table 15 (B).)
186
186
X
Ethyl iodide
69, 70, 132, 140.-
1, 100 -
1
Ethyl nitrite... . - - -.-
80, 132, 140
X
13,940
15,305
10,673
.70
X
69, 132
142, X
Hexamethylenetetramine
62, X
38 UNITED STATES TARIFF COMMISSION"
Table 11. — Synthetic medicinals: United States production and sales, 1939 — Con.
Name of medicinal
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Hexamethylenetetramineanhydromethylene
X..
Pounds
Pounds
^ citrate.
Hexamethylenetetramine tetra iodide
X.
132,140,149
X.
12, 498
11, 479
$42, 224
$3.68
lodomethane sulfate sodium
108
Menthol (synthetic)
209, X, X
Menthol ester of valeric acid (Validol)
155, X
Methyl iodide -
69,70, 132, 140
X
1,513
1,215
4,725
3.89
Methylene citric acid .
Methylene iodide . ._ . . .
69, 140, X...
Progesterone (Proluton) . . ._
186
Sodium bismuth-thioglycollate (Thiobismol).—
X
Sodium formaldehyde sulfoxylate
X- ..
Sulfonethylmethane
132 .
132
62, 97, 140, X
186
75, 081
66, 236
22, 355
.34
Testosterone (Oreton-F).- . .
Testosterone propionate (Oreton)
186
Theobromine sodium acetate
132, 149
Theophylline and derivatives:
Base - --
25, 132, X.. -
Ethylenediamine ( Aminophylline)
Methylglucamine (Glucaphylline)
10, 25, 61, 83, 140,
173,X,X,X,X.
1
16, 294
6,958
91, 880
13.20
Sodium acetate
83, 132, X
Thiamin chloride (Vitamin B)
100, 140-. .-
Thioethamyl sodium ...
X.
Thvmol -
X, X
Thymol iodide. .
132, 140,149
60, X
5,829
7,155
24, 575
3.43
Tribromomethane (Bromoform)...
Tribromotertiarybutyl alcohol (Brometone)
X
Trichloroacetic acid
60
Trichlorotortiarybutyl alcohol (Chloretone)
(Chlorobutanol).
25, 140, X, X, X, X
70
18, 068
7,799
23, 111
2.96
Total non-coal-tar medicinals:
Those for which individual statis-
158,877
1, 509, 349
132, 552
1, 350, 040
927, 387
5, 192, 326
7.00
tics are shown.
Those for which individual statistics
3.85
cannot be shown.
Grand total
1, 668, 226
1, 482, 592
6, 119, 713
4.13
FLAVORS AND PERFUME MATERIALS
Synthetic flavors and perfume materials, both those derived from
coal tar and those obtained from non-coal-tar raw materials, advanced
m production and sales in 1939. Of the output in 1939 of 5,349,000
poundsof those of coal-tar origin, 4,938,000 pounds were sold for $4,447,-
000, representing increases of 39 percent in production, 35 percent in sales
quantity, and 32 percent in sales value over 1938. Sales of coumarin
advanced 45 percent with a decline in value from $2.51 a pound in
1938 to $2.34 a pound in 1939. Sales of vanillin increased 33 percent
by quantity and 19 percent by value.
The output of non-coal-tar flavors and perfume materials in 1939
was 2,137,000 pounds. Sales were 2,233,000 pounds valued at
$1,588,000. Production was 45 percent more than in 1938, while
sales were up 72 percent by quantity and 101 percent by value.
Among the products that advanced in production and sales were
anisic aldehyde, citral, geraniol, geranyl acetate, ionone, and terpineol.
The production of heliotropin was less in 1939 than in 1938.
Statistics of production and sales of synthetic organic flavors and
perfume materials in 1939 are shown in table 12.
SYNTHETIC ORGAIS^IC CHEMICALS
39
Table 12. — Synthetic flavors and perfume materials: United States production and
sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 58. An X signifies that the manufacturer did not consent to the publication of his identification
number with the designated product. Blanks in the third, fourth, and fifth columns indicate that the
statistics of production or sales cannot be published without revealing information in regard to individual
firms. The figures thus concealed, however, are included in the total]
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(A) COAL-TAR
Acetophenone .- _..
82, 1]5,X,X
Pounds
Pounds
Amyl benzoate
76,78,220
178
67, 932
83, 165
Amyl cinnamic aldehyde ---
76, 78, 115, 220, 224, X,
X, X, X.
60, 78, 115, 196, X, X,
x,x.
102
66, 815
80, 818
$96, 047
37, 884
$1 44
Amyl salicvlate .. - ...
47
Belzal chloride ..- .
Benzal glycerin _ .. _
X
Benzophenone
Benzyl acetate .
82, 115, X, X, X
78, 115, 196, X, X, X.-
47, 032
40, 154
30, 825
.77
Benzyl alcohol . .
102, 115, 196, X, X, X,
X.
78, 115, 196, 209, X, X,
X.
76, 78, X, X ...
149, 217
54, 554
189
130, 174
56, 118
335
66, 041
37, 243
557
.51
Benzyl benzoate
.66
Benzyl butyrate. . . . .
1 66
Benzyl cinnamate. - ..
78,82,X,X
Benzyl eugenol...
224
Benzyl formate . .
78, 220, X.. .-
89
97
292
3 01
Benzyl isoeugenol .
78, 224, X_.
Benzyl propionate .
76, 78,224, X,X,X,X-_
78,82,220,224, X,X,X_
76,78
2, 381
18, 830
2,144
20, 451
3,256
29, 736
1.52
Benzyl salicvlate
1 45
Benzyl valerate .. .
Benzylidine acetone
220, X,X
Bromstvrol
25,X,X
Butylphenyl acetate
76
Carvacro! (isopropyl-o-cresol)
209 ....
Cinnamic acid . ...
82, X,X
Cinnamic alcohol
82,X,X
Cinnamic aldehyde
196, X, X-
Cinnamvl acetate
76,78,224,X,X,X._...
76
353
307
1,649
5.37
Cinnamyl anthranilate
Cinnamyl isobutyrate . ... .
76,X,X
36
63
Cinnamyl iso valerianate ..
76, X, X
Cinnamvl propionate
224..
Cinnamyl valerianate
78 .
Coumarin (synthetic)
60,62,138,142
235, 633
225, 068
525, 695
2.34
p-Cresyl acetate .- ...
78, X
p-Cresylmethyl ether ...
x,x
p-Cresylphenyl acetate
78, 224, X
Diethyl succinate
X . - - ..
Dimethyl acetal of phenylacetaldehyde..
Dimethyl anthranilate
82, X
76, X
Dimethvlbenzyl carhinol
78,220
Dimethvlhenzvl oarbinol acetate
220, 224
62, X . .
Diphenvlmethane-. .
X
■
Diphenyl oxide . ..
60, 78, X
Ethyl anthranilate . .
76,78,X
78, 154, 220, X, X
78,220
218
1,173
159
1,145
510
1,352
3.21
Ethvl benzoate .
1.18
Ethyl cinnamate
Ethylmethylphenyl glycidate
76, X
Ethylphonyl acetate
2.5, X
Ethyl salicvlate
78, X, X
231
209
.90
Ethvl vanillin (Vanaldol)
138, 142, X
Oeranyl benzoate
224
Guaiacol acetate
76
p-Hydro.\y benzoic acid esters (Asepto-
form) .
X
117 .-
78
Isobutyl benzoate
76, X
76, 78, 220, X
78,224
Linalyl anthranilate
78.224
224
224
Menthvl benzoate
102
Methvl acetophenone..
78,82, 115, X.X..
60,62, X
78, 154, 209, 220, X, X,
X.
7, 253
26,940
11,147
25,416
10,928
42, 806
.98
Methyl anthranilate . . . .
1.68
Methyl benzoate
40
UNITED STATES TARIFF COMMISSION
Table 12. — Synthetic flavors and perfume materials: United States production and
sales, 1939 — Continued
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Methyl cinnamate-
25, 220, X, X, X, X, X,
76, 78, X
Pounds
22, 249
111
Pounds
21, 731
$25, 707
$1.18
Methyl p-cresoL-
Methylnaphthyl ketone
78, 82, X, X .
3,636
6,458
1.78
Methylphenyl acetate
25,82, X,X,X
Methylphenyl carbinol
82, X
Methylphenyl carbinyl acetate
82, X
Methvl salicylate- .
60, 142, 209, X, X_...
62, X, X
1, 684, 619
1, 664, 740
489, 102
.29
Musk ambrette .
Musk ketone
62, X, X .
Musk xylol-- .-- -
62, X, X
90, 891
81, 404
70, 699
.87
-b-Naphth vl ethyl ether (Nerolin)
82, 115
b-Naphthyl methyl ether (Yara yara) . ..
82, 115
Phenylacet acetal
76
Phenvlacetic acid
25,82, 115,220, X
78, 82, X .
5,629
5,295
6,155
1.16
Phenylacetic aldehyde .-- .. .
Phenylethyl acetate
1, 78, 115, 220, X
60, 115, 220, 225, X....
78
22, 589
147, 522
Phenylethyl alcohol
153, 983
267, 373
1.74
Phenvlethvl butyrate
Phenylethyl formate ..
224, X
Phenylethylphenyl acetate
78, X
Phenylethyl propionate
220, X.
Phenylethyl salicylate
62, 76
Phenylethyl valerate.
76, X, X .
97
100
696
6.06
Phenylpropyl acetate.
224, X
Phenylpropyl propionate
76
Propyl cinnamate
76
Saccharin. --
142 .
Salicyl aldehyde
60,62
Tolyl acetate--
X
Tolyl aldehyde
X
Trichloromethylphenyl carbinol acetate
X
(Rosetone).
Vanillidine
X
Vanillin
138, 142, 185, X, X, X..
608,614
604, 972
1, 198, 153
1.98
Total coal-tar flavors and perfume
materials:
Those for which individual
3, 277, 557
2, 071, 565
3, 196, 440
1, 741, 572
2, 949, 373
1, 497, 754
.92
statistics are shown.
Those for which individual
.86
statistics cannot be shown
Grand total
5, 349, 122
4, 938, 012
4, 447, 127
.90
76, X
Aldehyde: ^«^ non-coal-tar
C 7 (Heptyl)
C 10 (Decyl)
220 ..
Allyl caproate
76, 78, X, X .
Allyl propionate
76....
Amyl butyrate. .
33,76,X
Amyl caproate .
X
Amyl formate
X
Amyl laurate. ..
X
Anethol
97,147
Anisic aldehyde (Aubepine)
Anisyl formate
62, X, X, X, X....
76
32, 852
30, 834
70, 535
2.29
Butyl anthranilate
76
n-Butyl butyrate
76, 78, 80, 154
76
Capryl butyric acid.
78
Capryl butyric ether
78
Cedrvl acetate .. ..
224 .
Cedrvl butyrate
224..
Cedryl formate -
224. .
Cetyl alcohol
224. . .
Citral
33, 62, 76, 128, 220, X,
X, X, X, X, X, X,
X.
76, 224. X, X
33, 384
29,976
43, 719
1.46
Citronellal
•Citronellol
62, 82, 115, 209, 220,
224, X, X, X, X.
78, X
43, 176
44,144
59, 842
1.36
Citronellyl acetate
Citronellyl formate
224
Citronellyl propionate
76 .
224
Diacetyl
25, X
Dlbutyl carbinol
X
Dihydrovanillone
78
SYNTHETIC ORGANIC CHEMICALS
41
Table 12.
-Synthetic flavors and perfume materials: United States production and
sales, 1939 — Continued
Manufacturers'
identification
numbers (according
to list on p. 58)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Dihydroxy citronellic ketone
78
Pounds
Pounds
Dimethyl octanol
209, X
Ettiyl butyrate - - . -
76,80, 154, X, X
154, X
44, 930
47,231
$29, 712
$0.63
Ethyl iso valerate
154, X, X
Ethvl laurate
76
Ethyl myristate
X
Ethyl oenanthate
76,78, 154, X.X
76, 78, 128, 220
7,218
10, 767
4,851
11, 346
3,581
7,033
.74
Ethyl oxyhydrate
.62
Ethyl sebacate
76, X
Ethvl n-valerate
78, 80
Eugenyl acetate
224
224
Formate:
C-10
76
C-I2
76
Geraniol.- .. . . .
62, 76, 82, 115, 209, 214,
220, 224, X, X, X,
XXX
62, 76, 78, 82, 115, 209,
220, 224, X, X, X.
78, 224, X
348,324
26, 712
355, 739
27, 622
236, 596
24,970
.66
Geranyl acetate. -.
.90
Geranvl butvrate
78, 224, X
Geranyl propionate
76
X, "x, X
28,035
62, X, X
Hydroxy citronellal diethyl acetal
X .
Hydroxy citronellal dimethyl acetal
76, X, X
lonone
62, 138, 220, 225, X, X,
X, X, X, X.
78, 80, 154, X
■ 78, 366
7,023
91,642
6,125
277
1,200
169, 790
4,493
224
1,665
1.85
.73
Isoamyl formate
78, 154, X
.81
Isoamyl iso valerate
76, 80, 154, X, X
80, X, X
1,284
1.39
Isoamyl propionate
62
62, 76
Isobutyl acetate .. .
76, 78, 154
341
Isobutyl butyrate
78
76
Isoeugenol
76, 224, X, X, X
224
Isopropyl caproate ... . ...
76...
Isopulegol
62, 82, 209, X
Lavadin acetate
224
Linalyl acetate
76, 78, 220, X, X
76,78
209
Menthone
78, 209, X
209
76, 224, X, X
62, 138, 220, 225, X, X,
X.
76, 224, X
70, 508
73,491
161,977
2.20
Methyl isoeugenol
224
224
Octyl acetate
224
Octyl butyrate
X, X
76
Peppermint oil (synthetic)
209
Khodinol--
62, 76, 78, 82, 128, 214,
220, 224, X, X, X, X,
X.X.
76 224, X
10, 274
31
6,661
75, 748
11.37
Rhodinyl acetate
76, 224
Rhodinyl propionate
224
Santalvl acetate
224 ...
224
Terpineol
62,76, 147, X
694,242
872, 115
190,068
.22
62
Terpinyl acetate
62, 76, 224, X
76, X
Vertiwrol acetate
76,224,X,X
Total non-coal-tar flavors and per-
fume materials:
1,437,467
699, 677
1,603,254
629,666
1,079,953
507,986
.67
tistics are shown.
Those for which individual sta-
.81
tistics cannot be shown.
Grand total
2, 137, 144
2,232,920
1,587,939
.71
42
UNITED STATES TARIFF COMMISSION
SYNTHETIC RESINS
The total production of 213,028,000 pounds of synthetic resins
(coal-tar and non-coal-tar) in 1939 was the highest on record, exceeding
by 82,669,000 pounds the output in 1938, and by 49,997,000 pounds
the previous peak in 1937. The 1939 production, by principal uses,,
was 54,807,000 pounds for molding and casting, 18,411,000 pounds for
laminating, 100,180,000 pounds for paints and varnishes, and 39,-
630,000 pounds for other uses. Corresponding figures for 1938 are
33,538,000 pounds for molding and casting, 10,189,000 pounds for
laminating, 56,528,000 pounds for paints and varnishes, and 30,104,-
000 pounds for other uses.
The 179,338,000 pounds of resins of coal-tar origin in 1939 exceeded
by 68 percent the output in 1938. Alkyd resins were up 87 percent
and tar acid resins 58 percent.
The production of non-coal-tar synthetic resins in 1939 was 33,690,-
000 pounds, or 44 percent more than in 1938. The rapid expansion
in the use of urea resins for surface coatings resulted in an increase
in their production of more than 100 percent. An increase of several
fold in sales of the vinyl acetyl resins, higher in price than other non-
coal-tar resins, resulted in a change in the average unit value of sales
of all non-coal-tar resins from $0.41 in 1938 to $0.46 in 1939. The
average value per pound of sales of urea resins decreased from $0.44
to $0.36 during the year.
Statistics of production and sales of synthetic resins m 1939 are-
shown in table 13.
Table 13. — Synthetic resins: United States production and sales, 1939
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 58. An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics-
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus concealed, however, are included in the total]
Manufacturers' identification
numbers (according to list
on p. 58)
Produc-
tion
Sales
Name of resin
Quan-
tity
Value
Unit
value
(A) COAL-TAE
Alkyd:
Maleic anhydride
7, 34,97, 113, 125, 207, X, X, X,
X, X, X.
2, 7, 31, 62, 88, 98, 113, 131, 169,
178, 181, 207, 219, X, X, X,
X, X, X,X, X,X,X, x,x,
X, x,x,x,x,x,x,x,x.
22, 146
Pounds
6, 263, 642
70, 208, 098
Pounds
4, 929, 403
33, 161, 064
$925, 048
6, 925, 898
$0.19
Phthalic anhydride
.21
62 -- -
X ... .
142
Tar acids:
Cresols or cresylic acid
Phenol:
For casting
18, 64, 88, 159, 179, 213, X, X,
X, X, X, X, X, X.
38, 110, 133, 142, X, X
18, 48, 52, 64, 88, 179, X, X, X,
X X
7, 18, 34', 38, 64, 88, 98, 125, 178,
181, 207, X, X, X, X, X, X,
X, X.
88 131, 181, X, X, X, X, X
10, 515, 557
8, 517, 368
19, 421, 778
27, 785, 891
7, 893, 863
8, 252, 263
17, 396, 556
25, 766, 207
1, 063, 772
3, 152, 444
2, 571, 930
3, 738, 052
.13-
.38-
For molding .
.15
.14
88, X, X, X, X
442, 899
88, X, X, X
Total coal-tar resins
179,337,857
128,419,871
23, 028, 083
.18-
SYNTHETIC ORGANIC CHEMICALS 43
Table 13. — Synthetic resins: United States production and sales, 1939 — Continued
Manufacturers' identification
numbers (according to list
on p. 58)
Produc-
tion
Sales
Name of resin
Quan-
tity
Value
Unit
value
(B) NON-COAL-TAR
97, X
Pounds
Pounds
62, 181, X ..
X
Petroleum _
X, X .
Polyamide . --
62
X
7, 62, 178, 181, X, X, X, X
X
16, 569, 343
14, 556, 232
$5, 288, 767
$0.36
62, X . _
Vinyl acetate and chloride
36, 60,89, X - .
33, 689, 691 34. 876. 766
15,983,405
.46
RUBBER CHEMICALS
With the increase in the manufacture of rubber products, partic-
ularly tires, synthetic organic chemicals for use in compounding
rubber increased greatly m production and sales in 1939. Coal-tar
rubber chemicals were up 60 percent in production. The increase in
those used as accelerators was 47 percent, and in those used as anti-
oxidants 69 percent.
Statistics of total production and sales of non-coal-tar rubber
chemicals are shown separately for the first time. Heretofore these
data have been included under the miscellaneous non-coal-tar chemi-
cals group to avoid revealing confidential information. These non-
coal-tar rubber chemicals increased considerably in production and
sales, but less than did those of coal-tar origin.
Statistics of production and sales of synthetic rubber chemicals
are shown in table 14.
Table 14. — Synthetic rubber chemicals: United States production and sales, 1939
JThe numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 58. An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus concealed, however, are included in the total]
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Produc-
tion
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR
Accelerators, total. _
Pounds
12, 090, 444
Pounds
7, 772, 922
$3,543,376
$0.46
62, 142, X
Aldehyde-amines:
Acel aldehyde aniline
Butvrrildelivde aniline .-.
62,89, 142, X
X
524,422
235, 018
154, 380
.66
Elhyl b-iiro]jylacryl aniline..
Hepttildehvde aniline
41
X
Methylene aniline (anhydro-
formaldehvde aniline'),
other:
62, 142
89 . .
89
X
ate.
252005—40-
44
UNITED STATES TARIFF COMMISSION
Table 14. — Synthetic rubber chemicals: United States production and sales\.
1939 — Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Sales
Name of chemical
Produc-
tion
Quantity
Value
Unit
value
(A) COAL-TAK
Accelerators— Continued.
Other— Continued.
Benzothiazole thiobenzoate .. -.-
142
Pounds
Pounds
X, X
Benzothiazyl-ethvl-thiocarbonate
X
Benzothiazyl-2-sulphenethylam-
X
ide.
Carbon disulfide on methylene
142
dimethylcyclohexylamine.
Carbon disulfide on methylene
142
dipiperidine.
p-p'Diaminodiphenylmethane
X
Dibenzothiazyl dimethyl thiol-
142
urea.
D Ibenzothiazyldimethylthiol-
142 ..-.
urea, diphenylguanidinephthal-
ate and anhydroformaldehyde
aniline.
X
Dimethylethylenediphenyl-
41
dithiocarbamate lead salt.
Dinitrophenylbenzothiazvl sul-
142
fide plus diphenylguanidine
acetate.
Dinitrophenyldimethyldithio-
carbamate.
Dinitrophenyl ester of mercapto-
benzothiazole.
Diphenylcarbamyl dimethyldi-
thiocarbamate.
X -. .-
142
X
7,60,62, 142
142
1, 852, 136
1, 234, 817
$412, 183
$0.33
Diphenylguanidine acetate
Diphenylguanidine oxalate
Diphenylguanidine phthalate
Diphenylguanidine and dinitro-
phenyl ester of mercaptobenzo-
thiazole.
Diphenylguanidine phthalate,
diphenylguanidine and dinitro-
phenyl ester of mercaptobenzo-
thiazble.
X
142, X
142
142
62, X
62
Hexamethylenetetramine ester of
mercaptobenzothiazole.
142
142, X .
Mercaptobenzothiazole on benzyl
chloride addition of hexa-
methylenetetramine.
Mercaptobenzothiazole-cyclo-
hexylamine.
Mercaptobenzothiazole methyl-
ene aniline.
Mercaptobenzothiazole methyl-
ene-o-to)uidine.
MercaptohenzotMazole lead salt-.
Mercaptobenzothiazole sodium
salt.
Mercaptobenzothiazole zinc salt_.
Methylene mercaptobenzothia-
zole.
Methylene-p-toluidine (anhydro-
formaldehyde p-toluidine).
Pi[)eridine penta methylene
dithiocarbamate and pota.s-
sium salt.
Reaction product, mercaptoben-
zothiazole-formaldehyde-cresy-
lic acid-hevamethylenetetramine.
62
142
X
X
62
142, X
62 142 X X
142
62
62 X, X
X
62,144
142,144
144 --
Other accelerators
X .—
SYNTHETIC ORGANIC CHEMICALS
45
Table 14. — Synthetic rubber chemicals: United States production and sales,
1939— Continued
Manufacturers'
identificatio n
numbers (ac-
cording to list
on p. 58)
Produc-
tion
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Antioxidants, total
Pounds
17, 875, 981
Pounds
13. 191. 775
J6, 537, 726
$0.50
X_...
,
Acetaldehyde aniline
p-Aminodiphenyl acetone compound.
142
Aniline-acetone
142
Aniline-acetone, acid derivatives
142 ._ .
Aniline-b-naphthol
62
Antox. _^ . _ ._. _-- -
62
Croton vlidine-a -naphthylamine
89
142
b-Di-p-hvdroxy phenvlpropane-
X
Dimethoxy diphenylamine
62
Diphenvlamine acetone
X
Diphenylamine acetone formalde-
X
hyde.
Diphenvl ethvlenediamine--- -
41
s-Di (b-naphthol) p-phenvlenediamine.
89
Diphenvl-p-phenvlenediamine --
62,89,X
1, 101, 640
Diphenyl-p-phenvlenediamine and
142
p-aminodiphenyl acetone com-
pound.
Diphenvl-p-phenvlenediamine and
142
aniline acetone, acid derivatives.
Ditolvlamines . ._ _
89
Di-o-tolvlethvlenediamine.- -
41
Di-o-tolylguanidine salt of dicatechol
62
borate.
Hydrogenated phenyl-b-naphthyla-
X...
mine.
p-Hvdroxv diphenvlamine
62
Hydroxyphen vl morpholine
62
Isopropoxv dinhen vlamine
89
Methvlene-b-naphthol _ _- _.
X .
p-Methyl-p-(p-tolylsulfonylamino)
X
diphenylamine.
Mono benzvl ether of hydro quinone.-
89
Phenol-cvclohexanone compound
142.
Phenvl-a-naphthvlamine.
62, 144
Phenvl-b-naphthvlamine
62, 85, 89
Phen vl-b-naphth vlnitrosamine - -
X
Polvethvlene polynamine plus b-
X
naphthol.
Thiophenvl-b-naphthvlamine-.-
X ..
2:2:4-Trimethyldihydroquinolineand
89
polymers.
Other antioxidants
41, X
Total coal-tar rubber chemicals
29, 966, 425
20. 964. 697
10, 081, 102
.48
62,142
(b) non-coal-tar
Accelerators:
Aldehvde ammonia
Dimethvlaminodimethyldithiocar-
142
bamicacid zinc salt.
Dipena methylene thlouramtetra
62
sum le.
Dithijcarbamatcs:
Amvl-ammonium-zinc dimethyl..
X
Diethyl ammonium-diethyl
X
234..
Selenium diethyl
234
Selenium tetra diethyl
X ...
Tolluriinn diethyl
234
Zinc dihutvl .-
234, X..
Zinc diethyl . .. ..
234.x
::::::::::::::::::
Zinc dimcthvL.
X,X...
p-Nitroso(iimcthvIamine .
62 . ..
Tetraamvlthiouram monosulfide
X
Tetramethylthiouram sulfide and
disulfide.
Triethyl trimethylenetriamine
62, 142,X,X
X
471, 699
369, 984
851, 518
2.30
46
UNITED STATES TARIFF COMMISSION
Table 14. Synthetic rubber chemicals : United States production and sales,
i 939— Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Accelerators— Continued.
Xanthates:
Chloronaphtha
142 -
Pounds
Pounds
Di-n-butvlxantho disulfide
X
60,142
60,X
60,142
Potassium isopropyl
60, X
Potassium pentasol
60
Sodium butyl
X
60 .-
x,x
X
Total non-coal-tar rubber chemi-
13,122, 206
11, 896, 450
$3, 086. 119
$0.26
cals.
MISCELLANEOUS CHEMICALS
The miscellaneous coal-tar chemicals group includes all unrelated
commodities and groups of commodities not properly classifiable under
any of the specified groups. Although the groups are comparable for
1938 and 1939 as to classifications of individual commodities, a com-
parison of group totals is of little significance because of the heteroge-
neous nature of the products making up these totals. The production
of coal-tar textile chemicals increased from 5,791,000 pounds in 1938
to 9,452,000 pounds in 1939. Sales advanced proportionately. Hy-
droquinone, shown under photographic chemicals, is the photographic
grade only. The technical grade is included under coal-tar interme-
diates. Plasticizers of coal-tar origin are shown separately as a sub-
group for the first time.
The miscellaneous non-coal-tar group includes the bulk of the non-
coal-tar synthetic products and consists of industrial chemicals that
cannot be grouped as meclicinals, aromatic chemicals, rubber chemi-
cals, or resins. The output of miscellaneous non-coal-tar synthetic
organic chemicals in 1939 was 2,984,038,000 pounds as compared with
2,383,168,000 pounds in 1938. In this group sorne of the important
products that advanced in production were acetic acid 23 percent,
acetic anhydride 58 percent, butyl alcohol 56 percent, carbon tetra-
chloride 16 percent, and isopropyl alcohol 27 percent. Sales of ace-
tone were up 50 percent, and of synthetic methanol 39 percent.
Commodities representing a large part of the total production of mis-
cellaneous non-coal-tar products cannot be shown separately without
revealing confidential information. Among such products in 1939
were: Synthetic camphor, crotonaldehyde, synthetic ethyl alcohol,
ethyl chloride, ethylene dibromide, ethylene dichloride, ethylene gly-
col, synthetic methanol, and tetraethyl lead. Non-coal-tar plasticiz-
ers are shown as a subgroup for the first time.
Statistics of production and sales of miscellaneous synthetic organic
chemicals are shown in table 15.
SYNTHETIC ORGANIC CHEMICALS
47
Table 15.
-Miscellaneous synthetic organic chemicals:
sales, 1939
United States production and
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 58. An X signifies that the manufacturer did not consent to the publication of his identification
number with the designated product. Blanks in the third, fourth, and fifth columns indicate that the
statistics of production or sales cannot be published without revealing information in regard to indi-
vidual firms. The figures thus concealed, however, are included in the total]
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR
Amino diethyl hydroquinone
X -
Pounds
Pounds
Benzoate of ammonia
102, 142
Benzoate of soda
62, 102, 142, 209,
X.
X
Benzoyl peroxide
Benzylated phenol (Santophens)
142 .. _
Biological stains and chemical indicators
96, 123, 144, 211,
X, X.
142
Butyl catechol
CyclanoL . . . .
62...
Cyclohexane ^. .
22
Cyclohexanone
22, X
Cyclohexanyl acetate -
224
Decahydrogaphthalene (Decalin).
62 .
Diamylhvdroquinone
142
Diphenylethane poiymer - . -. --.
X
a-a-Dipvridyl ._ .
70
Gases (poisonous, tear, etc.):
Chloroacctophenone
75
Chloropicrin . _.; .
X, X
Diphenylamine chlorarsine.- -
X
Gasoline antioxidants
62
Hexalin (Cyclohexanol)
22, 102, X
Insecticides (synthetic) :
Aromatic thiocyanates
102, 117
Other
203
Lauryl pyridinium chloride -
102
Methyl cyclohexane
22
Methvl cyclohexanone,-. ...
22,62, 102
Methyl hexalin (Methyl cvclohexanol)
22, 62, 102
Naphthanil red for printing
62 ...
Naphthanil scarlet for printing
62
o-Phenyl mercaptobenzothiazole
142
Phenylmercuric acetate
93 . .
Phenvlmercuric chloride
93 ...
Phloroglucinol . .
70
Photographic chemicals, total..
2, 121, 041
1, 716, 241
$1,847,694
$1.08
p-Aminophenol sulfate
70 ..
Benztriazol
70
Catechol (Pyrocatechin)
142, X
Chloro hydroquinone
70, 236
70, 225
dol) .
Hydroquinone'
62, 225, 236, X,
X.
69, 70, X, X -
1,441,329
1, 389, 022
1, 139, 880
.82
p-Hvdroxy phenylglycine
Methyl p-aminophenol sulfate (Me-
tol) (Rhodol).
N-N'-N"tri (2-methylcyclohexyl) di-
62, 69, 225, 236,
X, X.
X...
275, 186
290, 537
636, 319
2.19
ethylenetriamine.
225-. -
Phthalidc . -
62
Plasticizers, total
23,839,211
19, 299, 337
4,089,378
.21
Ethyl ortho-para-toluene sulfona-
142
mide (SanticizerS).
Phthalates, total
15,753,079
11, 334, 218
2,227,078
.20
Carbitol
157
Diamvl
115, 218
Dibutoxy ethyl
62, 157
Dibutyl
7,53,62,115,142,
218.
62
7, 923, 771
5,661,733
942,134
.17
Dicyclohexyl
Diethoxy ethyl
157 . .
Diethyl
7, 53, 115, 142,
218, X.
62, 157
1, 812, 925
1,373,457
240,072
.17
Dimethoxy ethyl
Dimethyl
7, 53, 115, 142,
218, X.
1 Photographic grade only.
48
UNITED STATES TARIFF COMMISSION
Table 15. — Miscellaneous synthetic organic chemicals: United States production and
sales, 1939 — Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAE— continued
Plasticizers— Continued.
Phthalates, total— Continued.
Dimetliyl cyclobexyl .
62
Pounds
Pounds
Diphenyl
142
2-Ethylhexyi
157
62
62
Phthalyl glycollate
142
Toluene sulfonamide ortho-para mix-
142 -
ture (Santicizer 9) .
39, 142, 157, X._.
60. 142, X
62 _.
144
69, 140
236, X
32, 69, 189
62
Sodium dicresyldithiophosphate...
X
Sodium ethyl butvl phthalate
62
7, 22, 44. 85, 142,
144, X, X,
X.
Tetrahydronaphthalene (Tetralin)
6, 7, 02, 85, 142,
144, 203, X, X.
142 ...
9. 452, 163
9, 045, 103
$1,969,284
$0.22
o-Tolyl biguanide
141, 142, X ..
Total miscellaneous coal-tar chem-
icals:
Those for which individual
20, 905, 374
48, 775, 089
7, 759, 852
48, 518, 690
4, 927, 689
7, 952, 138
.64
statistics are shown.
Those for which individual
.16
statistics cannot be shown.
69, 680, 463
56, 278, 542
12, 879, 827
.23
97
(B) NON-COAL-TAR
36, 150, X, X
Acetaldol ( 41dol)
150
60, 150, X
36, 53, 150, 218,
X.
36, X, X, X
85, 99, 117
119, 652, 650
181, 156, 152
Acetic anhydride (from all sources) (100
percent) .
36, 53, 17., 194,
218. X.
69, 140
100, 935, 422
4, 384, 757
.04
36... .
87, 10?, X
70, 194
60, 89, 70
194
Allyl isothiocyanate (synthetic mustard
oil).
70, X
226
... 1,487,643
1, 399, 353
753, 710
.54
191
Butyl:
191
Di
62, 191
62, 191
62
Ethyl:
191
Di
191, 234
Methyl:
5, 53, 62, X
T)i
53, 62, X
Tri
62, X
87 --
X ... .
Ammonium stearate -
X
SYNTHETIC ORGAXIC CHEMICALS
49
Table 15. — Miscellaneous synthetic organic chemicals: United States production and
sales, 1939 — Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
A.myl acetate:
Normal (90 percent)
53, 62, 171, 191,
218.
X..._
Pounds
Pounds
Secondary (60 percent)
Iso (90 percent) .. .. .
80, 117, 154, X,
X.
191,218
A myl alcohol:
Normal (100 percent)- -
Secondary (100 percent) .- -
X
Iso (100 percent) -_.
62, 80, 117, X, X.
191
Amyl chloride.
Amyl ether --.
191
Amyl mercaptan
191
Amyl propionate.. _
218
Butadiene .-. .. .
60 .-
Butyl acetate^lotal ...
77, 734, 214
68, 158, 368
$4, 690, 362
$0 07
Normal (90 percent) . .. .
36, 53, 142, 154,
174, 218.
194, X
Secondary (90 percent)
Iso (90 percent) ...
62,80
Butylacetyl rieinoleate ...
53 - ..
Butyl alcohol, total _
127, 010, 364
72, 736, 886
52, 590, 016
45, 836, 362
3, 548, 824
3, 182, 229
.07
Normal (100 percent)
36,53, 174,218.--
194, X
.07
Secondary (100 percent) .. .. ...
Tertiary (100 percent)
194
Iso (100 percent) . .. ._
36,62 .-
Butyl aldehyde
36, 53. X
n-Butyl bromide
1,69, 70, 189
Butyl bromide, sec ...
X
Butyl chloride .
191...
Butyl lactate ._. ...
53 - -
Butyl oleate -- ...... ..
53
Butyl propionate (100 percent) .
80,218
n-Butvric acid_.
36, 154, X
Butyric anhydride
36, X --..
Butyrvl chloride
102
Caffeine (from Theobromine)
138, 142
Calcium lactate . .
9, 193
Calcium propionate . _ ....
62
Campho carboxylic acid .. . .
1
Camphoric anhydride.. .
132..- -
n-Caproic acid .
36, 132, 154
Carbon tetrachloride
60, 152, 212, 231,
X.
102, 151
90, 535, 580
84,023,750
3,284,664
.04
Carbonyl chloride (Phosgene) .
Chlorinated solvents
24 .
Chloroacetic acid (mono)
60 -.
Chloroacetone .
X
Chloroacetvl chloride
60
Chloroform (tech and USP) .
24,30,60,62--..-
46, 140, X
193
2,933,322
13, 440, 323
Citric acid, refined (fermentation)
Copper lactate ...
11,652,711
2, 420, 986
.21
Crotonaldehvde
36, 150
Crotonic acid
150
Cyanoacetamide
25
117
117
Diacetone alcohol
36,53, 142, 194...
36, 53
3, 220, 729
2,393,125
187, 616
.08
Dibutvl ether (n-Butyl ether) . .
Dicbloroethvl ether
36
Dichloroisopropvl ether
36
119
119
Dichlorotetnlluoroethane
119
Dicvandiamid
X
Dicvlopentadiene - . .
36
Diethanolamine .
36 -.
Diethyl acetic acid
36
Diethyl carbonate (Diatol)
Diethyl sulfate
218 ...
36
Diethvlaminoethanol
36 69
Diethvlene clvcol
36, 60
36
157
Diethyleneplvcol iiionohutvl ether
36...
50
UNITED STATES TARIFF COMMISSION
Table 15. — Miscellaneous synthetic organic chemicals: United States production and
sales, 19S9 — Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Diethylene glycol monobutyl ether
36
Pounds
Pounds
acetate.
Diethvlene glycol monoethyl ether
36
Diethylene glycol monoethyl ether
36
acetate.
Dietnylene glycol monoethyl ether
36
maleate.
Diethylene glycol monomethyl ether .
36
Diethylene oxide (Dioxan)
36
Diglycol laurate . _-_ -.
X
Diglycol oleate
X, X
Diisobutylene. ._. -
X
Diisobutyl ketone . ...
36
Dimethoxy ethyl adipate - -.
62
Dimethyl ether ..
62
Dimethyl formamide .-
62
Dimethyl glyoxime
69,182
Dimethyl sulfate,.
62
Dioctylamine. . _
36
Dipropyl ketone
36
Dipropylene glycol
36
DulcitoL - - - .
19
Epichlorohydrin. . .
62
Ethyl acetate (85 percent)
36,53,62, 80, 142,
174, 218, X, X.
36,218 . -
67, 897, 408
51, 622, 492
$2, 706, 497
$0.05
Ethyl acetoacetate .
Ethyl alcohol (synthetic) - .
36,62
Ethyl benzoyl acetate
218
Ethyl bromide. ._
1,60
Ethyl bromo acetate
60
E thyl butyl acetate ...
36
Ethyl butyl alcohol. .
36
Ethyl butyraldehyde ...... .
36
Ethyl chloride (tech and USP)
60,62,73,84
Ethyl chlorocarbonate
218
Ethyl cvanoacetate ..
25
Ethyl ether (tech and USP). .
36, 132, 140, 201 . .
Ethyl formate ... .
63, 78, 80, 132,
154, 218, X,X.
36
a-Ethyl hexanal.
36
Ethyl hexoic acid
36 -
36 -
Ethyl lactate . .. .
X ..
Ethyl malonate . .
25 ...
132
76 ..
Ethyl oleate . .
117 ....
Ethyl oxalate (Diethyl oxalate)
25,80
62, 76, 80, 218, X
X.
36
Ethyl silicate
Ethylene chlorohydrin
36
Ethylenediamine (med and tech)
26,36
Ethylene dihromide
60, 72, 231
Ethylene dichloride
36,60
Ethylene glycol
36, 60, 218, X
Ethylene glycol diacetate
36
Ethylene glycol diethyl ether
36
36
157
ate (Butoxy ethyl stearate).
Ethylene glycol monoethyl ether
36
36
Ethylene glycol monomethyl ether
Ethylene glycol monomethyl ether ace-
tate.
36
36 80
157
ate (Methoxy ethyl oleate).
Ethylene glycol monophenyl ether.
Ethylene oxide
36
36 60
X
Fatty alcohols (containing more than 8
carbon atoms).
Fenchone
62
147
SYNTHETIC ORGANIC CHEMICALS
51
Table 15.
-Miscellaneous synthetic organic chemicals:
sales, 1939 — Continued
United States production and
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAE— continued
Ferrous lactate
132, 193
Pounds
Pounds
Formaldehyde (40 percent)
Formamide _. _ _ ._.
45,62, X,X
62
134, 478, 827
91, 159, 551
$4,060,666
$0.04
Formic acid (90 percent) . _ ---
62,226
Furfural
177
Furfural derivatives:
177,X
177
Ilvdrofuramide
177
Tetrahydrofurfuryl alcohol
177, X
Gallic acid, tech
69,132,236
50,117, X,X ..
145, 338
117
Glyceryl monooleate
50
Glyceryl trihydroxy stearate
62
X
50, 117, X
X
36
Heptane . .
36
llcxachloroethane
60
Ilexaldehyde
36
62, X
62 ..
36,62, X
Higher acetates (above hexvl)
X
Higher alcohols (containing more than 5
carbon atoms).
62, X
62
Higher methacrylates (above methyl)...
62
182
62
Hydroxyethyl ethylenediamine
36
Hvdroxylamine hydrochloride
182, X
Hydroxylamine sulfate
182
115, 203, 218, X..
62
62
Isobutyric acid
62
Isophorone
36
Isopropanolamines
36
36, 194, X
Isopropyl alcohol (Isopropanol) _
36, 194, X
60, X
179,062,266
18, 407, 564
816, 373
.04
Isopropvl chloride
102
36, 194, X
Lactic acid:
Edible (100 percent)
9,14,47,62,193...
14,62
1,609,094
1, 280, 235
270, 327
.21
Technical (100 percent)
9,14,47,62,193...
62
1, 530, 456
1, 439, 401
168, 572
.12
Laurvlamine and hydrochloride
X
60, X
19
Mannitol
19
Melamine
X
36,53,194
62
36,45,53,62
136, 407, 086
4, 836, 639
.04
62,150
Methvl acptnncetate
36
62
60
1
Methyl chloride (Chloromcthane) (100
percent).
62, 168, 227, X..-.
X
3, 021, 078
2, 947, 513
981, 926
.33
53,62,115
36
36
36, 194
53
62
X
102 X
Methyl succinate
X
52
UNITED STATES TARIFF COMMISSION
Table 15.-
-Miscellaneous synthetic organic chemicals:
sales, 1939 — Continued
United States production and
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Methylamyl ketone
36
Pounds
Pounds
Methylethyl ketone-
36, 194, X
Methylene chloride (Dichloromethane)..
24,60,62,227
Monoethanolamine and hydrochloride.. -
36
Mcrpholine.
36
Mucochloric acid
X
Nickel formate -..
226 -
Organic mercury compound (Seed dis-
X
infectant).
87, 143, 158, 226,
X.
150
10, 416, 269
11, 854, 176
$1, 168, 369
$0.10
Paracetaldehyde
Paraformaldehyde.-- -
62, X
Pelviren acid _ -- -
X
Pentachloroethane - --- .
62
Pentaerythritol
150
Phorone... --.-.. ._-
36
Plasticizers, total _- - ,
6,031,548
5,069,738
1,674,049
3$
Butyl stearate..
53,117
Camphor (synthetic) .--
62, 147
Dibutyl oxalate
53,218
Dibutvl sebacate -..
53,62,181
Dibutvl tartrate.- - - ._. ..
53,62,117
50, 117
23,354
23,197
10, 197
.44
Diethylene glycol monostearate
Diethylene glycol distearate .-- -.
50, 117
Glyceryl tripropionate .-- --.
X . -
Tributy] borate ..- -..
53
Tributyl citrate .- ---
53 -
Tributyl phosphate - ..- -
142
Triethyl citrate
164
Triethyl phosphate . - - - .-
53, 142 - -
Triethylene glycol dihexoate
36
Triglycol dioctoate .- - . - -
36 .
Polyethylenearaines -----
26, 36
Polyethylene glycol - - .
36
Polvglvcerol . .- ---
142
Polyglycerol-abietic acid compound
142
Polypropylene glycol-.-
36
62, X
Propionic anhydride..- -- -.
36, X
Propionyl chloride - -
102
n-Propvl acetate - .. .
62
n-Propvl alcohol (Propanol)
62
Propylene chlorohydrin
36
Propylene diamine.. . -
26,36
Propylene dichloride -.
36,60
Propylene glycol
36.62
Propylene glycol monolaurate -
117
Propylene glycol monostearate -- ..
117 ---
Propylene oxide .. -.
36
Pyrogallic acid (Pyrogallol) .-
69, 132,236
32, 69, 189
49, 770
60, 807
84,955
1.40
Research chemicals - ..
Rubber, synthetic
60.62
Sodium formate --- -- .--
132, 226, X
Sodium lactate
132, 193
Sodium methylate
136
Sodium oxal acetate.-.
218
Sodium oxalate
87,132,226
Sodium propionate
62
Sorbitol . - -
19
Sorbitan monolaurate ...
19
Soybean fatty acids monoglvceride
117
Sucrose octa acetate
150
Sulfated fatty alcohols, acids, etc. (Qar-
dinols, Ipepons, Intramines, Mapros,
Xynomines).
Sulfoacetic acid
36. 44. 62, 85, 144,
X, X.
X .
12, 527, 302
10, 660. 181
3,037,975
.28
Sulfonated thiocarbanilide acetaldehyde
142
ammonia compound.
Tetrabromoethane (Acetylene tetra-
60
bromi(ie).
62, 231
chloride).
Te t rn ch 1 oroethylene( Perchloroethylene)
60, 62
36
Tetraethyl lead
73 -...
.-- - l::
SYNTHETIC ORGANIC CHEMICALS
53
Table 15. — Miscellaneous synthetic organic chemicals: United States production and
sales, 19S9 — Continued
Manufacturers'
identification
numbers (ac-
cording to list
on p. 58)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Tetraethylene glycol dimethyl ether
36
Pounds
Pounds
Tributyl phosphite
62
Trichloroethvlene _ _ .
62, 231
Trichloromonofluoromethane
119
Triethanolamine
36 _
Triethylene glycol
36
Triglvcol dichloride
36
Triisobutylene
X
Triisopropanolamine
36
Trimethvlene bromide
60
Undeeanol
36
Undecylenic acid
X
Urea (solid)
62
Urea in urea-ammonia solution
62
Urea in solid fertilizer
62
Vanillin (See table 12 (A) p. 40).
Vinyl acetate
150, X
Vinyl chloride. -_
36
Waxes (synthetic) . .-- ._ . _
62
Xanthates (See table 14 (B) p. 46).
Other miscellaneous non-coal-tar chem-
62, X, X, X, X..
icals.
Total miscellaneous non-coal-tar
chemicals:
Those for which individual
894,436,804
2,089,601,004
570,703,573
911,170,222
$31, 602, 748
141,317,907
$0.06
statistics are shown.
Those for which individual
.16
Grand total
2, 9'!4, 037, 808
1, 481, 873, 795
172, 920, 655
.12
APPENDIXES
A. Research expenditures.
B. Imports.
C. Directory of manufacturers of synthetic
organic chemicals, 1939.
55
APPENDIX A.— RESEARCH EXPENDITURES
Producers of synthetic organic chemicals employed 2,197 techni-
cally tramed research workers m 1939, according to figures reported
by the industry. The average annual salary was $3,113 as compared
with $3,328 in 1938. This lower average salary figure indicates
increased placement of younger men rather than a lowering of techni-
cal salary levels. The gross cost of research was $14,077,000, and the
net cost $13,064,000.^ This net cost of research was 3.5 percent of
sales of all synthetic organic chemicals m 1939, as compared with
4.3 percent in 1938. Although research expenditures increased con-
siderably in 1939, sales increased much more.
APPENDIX B.— IMPORTS
The TarifJ Commission cooperated with the Department of Com-
merce in 1939 as m previous years, in compiling from original customs
documents import data on coal-tar intermediates and finished coal-tar
products. These statistics are released to subscribers semiannually
by the Department of Commerce in Import Statement No. 2865, and
are shown in greater detail than in the annual publication "Foreign
Commerce and Navigation of the United States." Table 16 is a
summary of the issues of Import Statement No. 2865 for 1938 and
1939, and shows imports of dutiable coal-tar products for those years,
classified according to use.
Table 16.
-Imports of finished coal-tar products, classified by uses, and of coal-tar
intermediates into the United States, 1939 and 1938
1939
193S
Product
Quantity
Foreign
invoice
value
Quantity
Foreign
invoice
value
Coal-tar dyes:
Acid
Pounds
1, 092. .569
1, 683, 367
458, .'")96
1, 488, 748
190, 667
158. 431
67, 461
59, 656
12, 962
$1,489,200
1,912,022
543, 119
1, 992, 930
207, 284
172,384
62, 637
111,273
4.091
Pounds
603, 145
1, 128, 146
255, 601
824. 924
129, 357
119,295
44, 792
39, 816
4,444
$764, 029
Vat
1, 497, 712
Mordant and chrome
300, 144
Direct '
1,053,088
Artificial silk
177. 444
Basic
138, 0S2
Sulfur
33, 427
Color-lake and spirit-soluble
75, 858
other
8,744
Total coal-tar dyes
.5, 212, 457
6, 554, 940
3, 149, 520
4, 049, 128
Finished coal-tar products other than dyes:
Aromatic cheminals
69, 893
29,786
7,824
302.551
3, 096, 354
105, 538
215, 643
6, 465
354, 770
2, 827, 470
48, 570
36, 721
5,096
15.S,595
2, 387, 003
71,271
Medicinals and pharmaceuticals
170,806
Color lakes
3,554
Other products
342, 008
Intermediates
1, 862, 344
' Includes Rapid Fast Dyes.
Source: United States Imports for Consumption of Dyes, Aromatic Chemicals, Medicinals, Interme-
diates, and Other Coal-Tar Products in Paragraphs 27 and 28 of the Tariff Act of 1930. Semiannual State-
ment No. 2865.
' The net cost figure is obtained by deducting from gross cost the credits for salable products obtained in
the course of research.
57
58
UNITED STATES TARIFF COMMISSION
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, 1939 (ALL COMPANIES WHICH HAVE GIVEN
PERMISSION TO BE IDENTIFIED AS PRODUCERS)
Name of company
Office address (location of plant given in
parentheses if not in same city as office)
Abbott Laboratories
Advance Paint Co
Alston-Lucas Paint Co
Althouse Chemical Co
Amecco Chemicals, Inc
American Aniline Products, Inc-
American Cyanamid Co
American Cyanamid Co., Calco Chemical
Division.
American Maize-Products Co
American Pharmaceutical Co., Inc
American Tar & Chemical Co
Ansbacher-Siegle Corporation
Ansul Chemical Co
Apex Chemical Co., Inc.
Arco Co
Arnold, Hoffman & Co., Ine.
Aromatic Products, Inc
Artifex Products Co-
Atlas Powder Co
Augusta Chemical Co_
Bakelite Corporation..
Barrett Co
Bates Chemical Co
Belle Alkali Co
Benzol Products Co
Bersworth, F. C, Laboratories.
Bick & Co., Inc
Birge Co., Inc
Brooklyn Color Works, Inc
Brown Co
Brown, Andrew, Co
Burroughs Wellcome & Co., Inc..
Bush, VV. J., & Co., Inc
California Flaxseed Products Co.
California Ink Co., Inc
Carbide & Carbon Chemicals Corporation.
Carus Chemical Co., Inc
Catalin Corporation of America
Celluloid Corporation
Chemical Manufacturing Co., Inc
Chemico, Inc
Childs Pulp Colors, Inc
Ciba Pharmaceutical Products, Inc
Cincinnati Chemical Works, Inc
Cities Service Oil Co
Citro Chemical Co
Clinton Co
Colasta Co., Inc
Coleman & Bell Co
Colloid Chemical Laboratories, Inc
Collway Colors, Inc
Colt's Patent Fire Arms Manufacturing Co
Commercial Solvents Corporation
Commonwealth Color & Chemical Co
Cooks Falls Dye Works, Inc
Coopers Creek Chemical Corporation
Crown Tar Works— Division of Public
Service Co. of Colorado.
Devoe & Raynolds Co., Inc
Diarsenol Co., Inc
Dow Chemical Co
Dubin, H. E., Laboratories, Inc
14th St. and Sheridan Rd., North Chicago, 111.
545 West Abbott St., Indianapolis, Ind.
1031 North Throop St., Chicago, 111.
540 Pear St., Reading, Pa.
75 Rockwood St., Rochester, N. Y.
50 Union Square, New York, N. Y. (Lock Haven,
Pa.)
30 Rockefeller Plaza, New York, N. Y. (Bound
Brook and Warners, N. J., Bridgeville, Pa.)
Bound Brook, N. J.
100 East 42d St., New York, N. Y. (Roby, Ind.)
525 West 43d St., New York, N. Y.
5910 Freemont St., Duluth, Minn.
92 Chestnut Ave., Rosebank, S. I., New York,.
N.Y.
P. O. Box 231, Marinette, Wis.
225 West 34th St., New York, N. Y. (Elizabeth-
port, N. J.)
7301 Bessemer Ave., Cleveland, Ohio.
55 Canal St., Providence, R. I. (Dighton, Mass.)
15 East 30th St., New York, N. Y. (Springdale,-
Conn )
Delaware Ave. and Elm St., Camden, N. J.
Wilmington, Del. (Atlas Point, Del., Stamford,
Conn.)
P. O. Box 660, Augusta, Ga.
247 Park Ave., New York, N. Y. (Bloomfleld and
Bound Brook, N. J.)
40 Rector St., New York, N. Y. (plants throughout
United States)
Scottdale Rd., Lansdowne, Pa.
Belle, W. Va.
237 South St., Newark, N. J. (Piscataway, N. J.)
609 Waverly St., Framingham, Mass.
12th and Bern Sts., Reading, Pa.
390 Niagara St., Buffalo, N. Y.
Morgan and Norman Aves., Brooklyn, N. Y.
404 Commercial St., Portland, Maine (Berlin,
N. H.)
5431 South Riverside Drive, Los Angeles, Calif.
9 East list St., New York, N. Y. (Tuckahoe, N. Y.)
11 East 38th St., New York, N. Y. (Linden, N. J.)
3135 East 26th St., Los Angeles, Calif.
545 Sansome St., San Francisco. Calif. (Berkeley,.
Calif.)
30 East 42d St., New York, N. Y. (South Charles-
ton, W. Va., Niagara Falls, N. Y., Whiting,
Ind.)
1377 Eighth St., La Salle, 111.
1 Park Ave., New York, N. Y. (Fords, N. J.)
290 Ferry St., Newark, N. J.
Ashland, Mass.
475 Dorchester Rd., Akron, Ohio.
43 Summit St., Brooklyn, N.Y.
Lafayette Park, Summit, N. J.
P. O. Box 20, Evanston Station, Cincinnati, Ohio
(Norwood and St. Bernard, Ohio)
Bartlcsville, Okla. (Tallant, Okla.)
Maywood, N. J.
Clinton, Iowa.
Mechanic St., Hoosick Falls, N. Y.
Main and Waverly Aves., Norwood, Ohio.
21 West St., New York, N. Y. (Guttenberg, N. J.)
15 Market St., Paterson, N. .7.
17 Van Dvke Ave., Hartford, Conn.
17 East 42d St., New York, N. Y. (Terra Haute,.
Ind., Peoria, 111., Agnew, Calif.)
Nevins, Butler & Baltic Sts., Brooklyn, N.Y.
70 Pine St., New York, N. Y. (Cooks Falls, N. Y.)'
West Conshohocken, Pa.
900 15th St., Denver, Colo.
P. O. Box 328, Louisville, Ky.
72 Kingsley St., Buffalo, N. Y.
Midland, Mich. (Pittsburg, Calif.)
250 East 43d St., New York, N. Y.
SYNTHETIC ORGANIC CHEMICALS
59
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, 1939 (ALL COMPANIES WHICH HAVE GIVEN
PERMISSION TO BE IDENTIFIED AS PRODUCERS)— Continued
Num-
ber
Name of company
Office address (location of plant given in
parentheses if not in same city as office)
62
63
du Pont de Nemours, E. I., & Co., Inc
Durez Plastics & Chemicals, Inc
Wilm'ngton, DeL (Carney's Point, New Bruns-
wick, Perth Amboy, Arlington, and Newark,
N. J., Belle, W. Va., Waynesboro, Va., Niagara
Falls, N. Y., El Monte, Calif.)
Walck Road, North Tonawanda, N. Y
64
Durite Plastics, Inc
.5000 Summerdale Ave., Philadelphia, Pa.
924 Bersren Ave., Jersey City, N. J.
65
Dye Specialties Corporation _
66
11th and Monroe Sts., St. Louis, Mo.
67
Eakins, ,T. S. & W. R., Inc
55 Berry St., Brooklyn, N. Y.
68
Eastern Tar Products Corporation
69
Eastman Kodak Co. -. ._- -.- - -
343 State St., Rochester, N. Y. (Kingsport, Tenn.)
70
Edwal Laboratories, Inc
732 Federal St., Chicago, 111.
71
Elko Chemical Works, Inc-- .
66 Lister Ave., Newark, N. J.
72
Ethyl Dow Chemical Co -
Wilminston, N. C. (Kure Beach, N. C.)
73
74
Federal Color Laboratories, Inc .
4633 Forest Ave., Norwood, Ohio
75
Federal Laboratories, Inc. - .
185 41st St., Pittsburgh, Pa. (Tunnelton, Pa.)
76
Felton Chemical Co., Inc
599 Johnson Ave., Brooklyn, N. Y.
77
Fine Colors Co
21-29 McBride Ave., Paterson, N. J.
78
1513-33 Olmstead Ave., New York, N. Y.
79
Foster-Heaton Co - -
833-39 Magnolia Ave., Elizabeth, N. J.
80
Franco- American Chemical Works-
Berrv Ave., Carlstadt, N. J.
81
Fries Bros . _ _ ..
92 Reade St., New York, N. Y. (Bloomfleld, N. J.)
82
83
Fries, George G., & Co., Inc
Gane's Chemical Works, Inc .-. -..
68 Beekman St., New York, N. Y. (Long Island
City, N. Y.)
43 West 16th St., New York, N. Y. (Carlstadt,
84
Gebauer Chemical Co _ . __. ___
N.J.)
9410 St. Catherine Ave., Cleveland, Ohio.
85
86
General Aniline & Film Corporation, Gen-
eral Aniline Works Division.
General Biochemicals, Inc
435 Hudson St., New York, N. Y. (Rensselaer,
N. Y., Grasselli. N. J.)
Chaerin Falls, Ohio.
87
General Chemical Co
40 Rector St., New York, N. Y. (Claymont, DeL,
88
General Electric Co .
Buffalo, N. Y.)
1 River Road, Schenectady, N.Y. (Pittsfield, Mass.)
89
90
Goodrich, B. F., Co
Goodyear Tire & Rubber Co. .-
500 South Main St.. Akron, Ohio.
1144 East Market St., .\kron, Ohio.
91
92
93
Guyan Color & Chemical Works
Halowax Corporation
Hamilton Laboratories, Inc
P. O. Bo.x 1088, Huntincton, W. Va.
247 Park Ave., New York, N. Y. (Wyandotte,
Mich.)
Hamilton, Ohio.
94
ITampden Color & Chemical Co
161 Armory St., Springfield. Mass.
95
96
Harmon Color Works, Inc
Hartman Leddon Co - -
P. O. Box 1158, Paterson, N. J. (Haledon, N. J.)
6010 Haverford Ave., Philadelphia, Pa.
97
Hercules Powder Co . . . ..
Delaware Trust Bldg., Wilmington, DeL
98
822 South 14th St.. Manitowoc, Wis.
99
Hilton-Davis Chemical Co.
Langdon Farm Rd.. Cincinnati, Ohio.
100
101
102
Hoffmann-La Roche, Inc
Holland Aniline Dye Co
Hooker Electrochemical Co
Kin?sland Rd. and Bloomfield Ave., Nutley, N. J.
Holland, Mich.
Buffalo Ave. and 47th St., Niagara Falls, N. Y.
103
Hugftins, .Tames & Son . _ . .
239 Medford St., Maiden. Mass.
104
105
106
Hynson, Westcott & Dunning. Inc
Imperial Paper & Color Corporation, Pig-
ment Color Division.
Industrial DyestulT Co., Inc .
1030 North Charles St., Baltimore, Md.
Glens Falls, N. Y. (Queensbury, N. Y.)
Massasoit Ave., East Providence, R. I.
107
Inland Steel Co .. .- -
38-Sout,h Dearborn St., Chicago, 111. (Indiana Har-
108
.Tamieson, C. E. & Co
bor, Ind.)
1962-80 Trombly Ave.. Detroit, Mich.
109
Jennison-Wright Co .
2463 Broadwav. Toledo. Ohio.
110
.Toanite Corp
10-02 44th Driv£, Lon« Island City, N. Y.
111
Johnson. Charles Eneu, & Co -- -
10th St. at Lombard St., Philadelphia, Pa.
112
Joliet Wall Paper Mills .-- --
Logan Ave., Joliet, 111.
113
1481 South 11th St.. Louisville, Ky.
114
Kay & Ess Co
820 Kiser St.. Davton. Ohio.
115
116
117
Kay-Fries Chemicals, Inc -
Kentucky Color & Chemical Co
180 Madison Ave., New York, N. Y. (West Haver-
iitraw. N. Y.)
34th St. South of Bank St., Louisville, Ky.
Delaware .'^ve. <t Mifflin St., Philadelphia, Pa.
118
Keystone Color Works, Inc
151 West Gay Ave., York, Pa.
119
120
121
122
123
Kinetic Chemicals, Inc
Knoedler, A., Co
Kohnstamm, H., & Co., Inc _.
KoppersCo., Tarct Chemical Division
LaMotte Chemical Products Co .
duPont Bldg., Wilmington, Del. (Pennsgrove,
N.J.)
717 North Prince St.. T/aneastcr. Pa.
87 Park Place. -New York, X. Y, (Brooklyn. N. Y.)
Koppers Bldg., Pittsburgh, Pa. (Plants throughout
the Ignited States.)
McCormick Bldg., Baltimore, Md. (Towson, Md.)
124
Lehigh Briquetting Co
Universal Bldg., Fargo, N. Dak. (Dickinson, N.
Dak.)
60
UNITED STATES TARIFF COMMISSION
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, 1939 (ALL COMPANIES WHICH HAVE GIVEN
PERMISSION TO BE IDENTIFIED AS PRODUCERS)— Continued
Office address (location of plant given in
parentheses if not in same city as office)
Lewis, John D., Inc
Lilly, Eli, & Co
Lucidol Corporation
Lueders, George, & Co
Macher, William & Son
Magruder Color Co., Inc
Makalot Corporation
Mallinckrodt Chemical Works _-. ._
Marblette Corporation
Marx, Max, Color & Chemical Co
Maschmeijer, A., Jr., Inc
Mathieson Alkali Works, Inc
May, Otto B., Inc
Maywood Chemical Works —
Mepham, Geo. S., Corporation
Merck & Co., Inc
Minercc Corporation
Monsanto Chemical Co
Mutual Chemical Co. of America
National Aniline & Chemical Co., Inc
Naugatuck Chemical, Division of United
States Rubb?r Co.
Neville Co
Newport Industries, Inc
New York Color & Chemical Co., Inc., Di-
vision of American Dyewood Co..
New York Quinine & Chemical Works, Inc
Niacet Chemicals Corporation
Niaeara Chlorine Products Corporation
Niagara Smelting Corporation
Nord & Schulich, Inc
Northwestern Chemical Co
Novoeol Chemical Mfg. Co., Inc
Nubian Paint & Varnish Co.
Ohio-Apex, Inc .-
Oldbury Electro Chemical Co
Panelyte Corporation
Patent Chemicals, Inc
Peerless Color Co
Pennsvl vania Coal Products Co
Pfanstiehl Chemical Co
Pfizer, Chas., & Co., Inc
Pharma Chemical Corporation
Philadelphia Gas Works Co
Phoenix Color & Chemical Co
Pittsberg Chemical Co
Pittsburgh Plate Glass Co
PlaskonC(j.,Inc
Portland Gas & Coke Co
Poughkeepsie Dyestuff Corporation
Premo Pharmaceutical Laboratories, Inc..
Publicker, Inc
Pylam Products Co., Inc
Pyridium Corporation
Quaker Oats Co
Reichhold Chemicals, Inc
Reilly Tar & Chemical Corporation...
Republic Creosoting Co
Resinous Products & Chemical Co ,
Rogers, Allen E., Laboratories, Inc
Rohra & Haas Co .-
Rubcroid Co
Salvo Chemical Co
Schering Corporation
68 Traverse St., Providence, R. I. (Mansfield,
Mass.)
Indianapolis, Ind.
293 Larkin St., Buffalo, N. Y.
427 Washington St., New York, N. Y.
1533 West Clearfield St.. Philadelphia, Pa.
2385 Richmond Terrace, Port Richmond, S. I., N. Y.
262 Washington St., Boston, Mass. (Waltham,
Mass.)
3600 North 2d St., St. Louis, Mo.
37-21 Thirtieth St., Long Island Citv, N. Y.
192-4 Coit St., Irvington, N. .1.
43 West 16th St., New York, N. Y. (Newark, N. J.)
60 East 42d St., New York, N. Y. (Niagara Falls.
N. Y.)
198-214 Niagara St., Newark, N. J.
100 West Hunter Ave., Maywood, N. J.
2001 Lynch Ave., East St. Louis, 111.
Rahway, N. J. (Philadelphia, Pa.)
120 Broadway, New York, N. Y. (Baltimore, Md.)
1700 South 2d St., St. Louis, Mo. (St. Louis, Mo.,
Nitro, W. Va., Springfield and Everett, Mass.,
Edgewater, N. J., Monsanto, 111., Anniston, Ala.)
270 Madison Ave., New York, N. Y. (Jersey Citv,
N.J.)
40 Rector St., New York, N. Y. (Buffalo, N. Y.)
1790 Broadway, New York, N. Y. (Naugatuck,
Conn.)
Neville Island, Pittsburgh, Pa.
P. O. box 911, Pensacola, Fla.
Main & Joralemon Sts., Belleville, N. J.
99 North 11th St., Brooklyn, N. Y.
4700 Pine Ave., Niagara FalLi, N. Y.
Mill St., Lockport, N. Y.
420 Lexington Ave., New York, N. Y. (Niagara
Falls, N. Y.)
Foot of Blanchard St., Newark, N. J.
1263 North 70th St., Wauwatosa, Wis.
2923 Atlantic Ave., Brooklyn, N. Y.
1856 North LeClaire Ave., Chicago, 111.
Nitro, W. Va.
P. O. Box 346, Niagara Falls, N. Y.
230 Park Ave., New York, N. Y. (Trenton, N. J.)
57 Wilkinson Ave., Jersey City, N. J.
521-35 North Ave., Plainfield, N. J.
Petrolia, Pa.
104 Lakeview Ave., Waukegan, 111.
81 Maiden Lane, New York, N. Y. (Brooklyn,
N. Y.).
949 Broadway, New York, N. Y. (Bayonne, N. J.)
1800 North 9th St., Philadelphia, Pa.
24}.^ Van Houten St., Paterson, N. J.
Central Tower, San Francisco, Calif. (Vernon,
Calif.)
235 East Pittsburgh Ave., Milwaukee, Wis.
2112 Sylvan Ave., Toledo, Ohio.
Public Service Bldg., Portland, Oreg.
77 North Water St., Poughkeepsie, N. Y.
443 Broadway, New York, N. Y.
1800 West Lehigh Ave., Philadelphia, Pa.
799 Greenwich St., New York, N. Y.
21 Grey Oaks Ave., Nepora Park, N. Y.
141 W. Jackson Blvd., Chicago. 111. (Cedar Rap-
ids, Iowa.)
601 Woodward Heights Blvd., Detroit, Mich.
(Elizabeth, N.J.)
1615 Merchants Bank Bldg., Indianapolis, Ind.
(Plants throughout the United States.)
1615 Merchants Bank Bldg., Indianapolis, Ind^
(Plants throughout the United States.)
222 West Washington Square, Philadelphia, Pa.
72 Grnnd Ave., Brooklyn, N. Y.
222 West Washington Square, Philadelphia, Pa.
(Bridesburgand Bristol, Pa.)
500 Fifth Ave., New York, N. Y. (Erie, Pa.,.
Jolict. Til.)
Rothschild, Wis.
86 Orange St., Bloomfield, N. J.
SYNTHETIC ORGANIC CHEMICALS
61
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, 1939 (ALL COMPANIES WHICH HAVE GIVEN
PERMISSION TO BE IDENTIFIED AS PRODUCERS)— Continued
Num-
ber
Name of company
OfBce address (location of plant given in
parentheses if not in same city as office)
187
190
191
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
Schering & Qlatz, Inc
Seeley & Co., Inc
Sepin Laboratories -.
Sharp & Dohme, Inc
Sharpies Solvents Corporation.
Shawiniean Resins Corporation
Sheffield By-Products Co
Shell Chemical Co
Sherwin-Williams Co
Simons, Harold L., Inc -.
Sinclair & Valentine Co
Smith, Kline & French Laboratories
Solvay Process Co
Southern Dyestufl Corporation
Squibb, E. R., & Sons—.
Standard Alcohol Co —
Standard Chemical Products, Inc
Standard Oil Co. of Cahfornia
Standard Ultramarine Co -.
Stange, Wm. J., Co
Stroock & Wittenberg Corporation
Sun Chemical & Color Co. Div. General
Printing Ink Corporation.
Swann &Co —
Synthetic Chemicals, Inc
Synthetical Laboratories
Taylor Chemical Corporation
Taylor Fibre Co -- -
Todd, A. M., Co - -.
Trubek Laboratories, Inc -
Uhlieh, Paul, & Co., Inc.
United Color & Pigment Co
v. S. Industrial Chemicals, Inc
Valentine & Company, Inc. -
van Ameringen-Haebler, Inc
Van Dyk <t Co., Inc
Varcum Chemical Corporation.
Velsicol Corporation _
Verley Chemical Co
Verona Chemical Co
Victor Chemical Works -..
Virginia Smelting Co
Wannamakcr Chemical Co
Warner-Jenkinson Mfg. Co
Watertown Mfg. Co
Westvaco Chlorine Products Corporation . .
WhiteTarCo. ofN. J.,Inc
Wilhelm, A., Co. Division of the Qlidden
Co.
Wolfl-Alporr Chemical Corporation
Young Aniline Works, Inc
Zinsser & Co., Inc.- --
113 West 18th St., New York, N. Y.
22 Albany St., New York, N. Y. (Farmingdale,
N. Y.)
P. 0. box 18.5, station A, San Diego, Calif. (San-
tee. Calif.)
640 North Broad St., Philadelphia, Pa.
23d & Westmoreland Sts., Philadelphia, Pa.
(Wyandotte, Mich.)
Springfield, Mass. (Indian Orchard, Mass.)
524 West 57th St., New York, N. Y. (Hobart, N. Y.)
100 Bush St., San Francisco, Calif. (Martinez and
Domineuez, Calif.)
101 Prospect Ave., N W., Cleveland, Ohio (Chicago,
111.)
11-25 Forty-fourth Rd., Long Island City, N. Y.
611 West 129th St., New York, N. Y.
105 North 5th St., Philadelphia, Pa.
Syracuse, N. Y. (Geddes, N. Y.)
P. O. box 1045, Charlotte, N. C. (Sodyeco, N. C.)
745 Fifth A vc, New York, N. Y. (New Brunswick,
N. J., Brooklvn, N. Y.)
P. O. box 243, Elizabeth, N. J. (Linden, N. J.)
1301 Jefferson St., Hoboken, N. J.
225 Bush St., San Francisco, Calif. (Richmond,
Cahf.)
Huntington, W. Va.
2536 West Monroe St., Chicago, 111.
60 East 42d St., New York, N. Y. (Newark, N. J.)
309-21 Sussex St., Harrison, N. J. (East Rutherford,
N.J.)
205 South 32d St., Birmingham, Ala.
57 Wilkin.son Ave., Jersey City, N. J.
5558 Ardmore Ave., Chicago, 111.
Phillipsburg, N. J. (Wyandotte, Mich.; Penn
Yan, N. Y.)
Norristown, Pa. (Betzwood, Pa.)
1717 Douglas Ave., Kalamazoo, Mich.
State Highwav No. 2, East Rutherford, N. J.
157 Chambers St., New York, N. Y. (Brooklyn,
N. Y.)
McClellan St., Newark, N. J.
60 East 42d St., New York, N. Y. (Baltimore, Md.>
11 East 36th St., New York, N. Y. (Brooklyn,
N. Y.)
315 Fourth Ave., New York, N. Y. (Elizabeth,
N.J.)
57 Wilkinson Ave., Jer.sey City, N. J.
P. O. box 433, Niagara Falls, N. Y.
3542 North Kimball Ave., Chicago, 111. (Marshall,
111.)
1621 West Carroll Ave., Chicago, 111.
26 Verona Ave., Newark, N. J.
141 West Jackson Blvd., Chicago, 111. (Chicago
Heights. 111.)
West Norfolk, Va.
Orangeburg, S. C.
2526 Baldwin St., St. Louis, Mo.
127 Echo Lake Rd., Watertown, Conn.
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