UNITED STATES TARIFF COMMISSION
SYNTHETIC
ORGANIC CHEMICALS
UNITED STATES PRODUCTION
AND SALES
1940
REPORT No. 148
SECOND SERIES
BOSTON PUBLIC LIBRARY
3 9999 06317 195 1
RECENT REPORTS OF THE UNITED STATES TARIFF COMMISSION
Price
Crab Meat, Report No. 147, Second Series, 1941 $0.10
Wheat and Wheat Flour, Report No. 145, Second Series, 1941 10
Hogs and Hog Products, Report No. 143, Second Series, 1941 25
Regulation of Imports by Executive Action, Miscellaneous Series, 1941 15
Latin America as a Source of Strategic and Other Essential Materials, Report
No. 144, Second Series, 1941 50
Italian Commercial Policy and Foreign Trade, Report No. 142, Second Series,
1941 30
Earthen Floor and Wall Tiles, Report No. 141, Second Series, 1940 25
Glues, Gelatins, and Related Products, Report No. 135, 1940 25
Starches, Dextrines, and Related Products, Report No. 138, Second Series, 1940 . . .30
Silverware, Report No. 139, Second Series, 1940 25
Changes in Import Duties Since the Passage of the Tariff Act of 1930, Mis-
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Rxiles of Practice and Procedure and Laws Relating to the United States Tariff
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(For sale by the Superintendent of Docmnents, Government Printing Office,
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UNITED STATES TARIFF COMMISSION
tr
SYNTHETIC ORGANIC CHEMICALS
UNITED STATES PRODUCTION
AND SALES
1940
REPORT No. 148
SECOND SERIES
UNITED STATES
GOVERNMENT PRINTING OFFICE
WASHINGTON : 1941
For sale by the Superintendent of Documents, Washington, D. C. -••••••• Price 10 cents
<'■ ^'>. iiUPERiNTENDENT OF ;
^£B 9 1942
UNITED STATES TARIFF COMMISSION
RAYMOND B. STEVENS, Chairman
OSCAR B. RYDER, Vice Chairman
EDGAR B. BROSSARD
E. DANA DURAND
E. M. WHITCOMB, Acting Secretary
Address all communications
UNITED STATES TARIFF COMMISSION
WASHINGTON, D. C.
CONTENTS
PaE«
Acknowledgment v
Introduction 1
PART I
Summary, 1940 1
PART II
Production and sales by groups, 1940:
Coal-tar crudes 5
Coal-tar intermediates &
Coal-tar dyes 17
Color lakes and toners 34
Mediciiials 36
Flavors and perfume materials 42
Resins 46
Rubber chemicals 48
Miscellaneous synthetic organic chemicals 50-
APPENDIXES
A. Research expenditures 59
B. Imports 59
C. Directory of manufacturers of synthetic organic chemicals, 1940 61
STATISTICAL TABLES
1. Comparison of United States production of tar and production and
sales of certain crudes, average 1934-38, annually 1939 and 1940 2
2. Intermediates, dyes, and other coal-tar chemicals: Summary of United
States production and sales in 1940 3
3. Intermediates, dyes, and certain other classes of coal-tar chemicals:
Comparison of United States production and sales, average 1934-38,
annually 1939 and 1940 4
4. Synthetic organic chemicals of non-coal-tar origin: Summary of United
States production and sales in 1940 4
5. Synthetic organic chemicals of non-coal-tar origin: Comparison of
L^nited States production and sales, average 1934-38, annually 1939
and 1940 4
6. Coal-tar crudes: United States production and sales in 1940 6
7. Coal-tar intermediates: United States production and sales in 1940 7
8. Comparison of United States production and sales of dves, by classes of
apphcation, average 1934-38, annually 1939 and 1940 18
9. Coal-tar dyes: United States production and sales, by types, in 1940- . 19
10. Color lakes and toners: United States production and sales in 1940 34
11. Synthetic medicinals: United States production and sales in 1940:
(A) Coal-tar 37
(B) Non-coal-tar 40
12. Synthetic flavors and perfume materials: United States production and
sales in 1940:
(A) Coal-tar 42
(B) Non-coal-tar 44
13. Svnthetic resins: United States production and sales in 1940:
(A) Coal-tar 47
(B) Non-coal-tar 47
14. Synthetic rubber chemicals: United States production and sales in 1940:
(A) Coal-tar 48
(B) Non-coal-tar 50
15. Miscellaneous synthetic organic chemicals: L^nited States production
and sales in 1940:
(A) Coal-tar 51
f B) Non-coal-tar 53
16. Coal-tar intermediates, and finished coal-tar products classified by
uses: United States imports for consumption, 1938-40, and 6 months
of 1941 60
m
ACKNOWLEDGMENT
In the preparation of this report, the Commission had the services
of W. F. Sterling, Bertha M. Robertson, and James H. Hibben of the
Chemical Division, and of others.
V
SYNTHETIC ORGANIC CHEMICALS, UNITED STATES
PRODUCTION AND SALES, 1940
INTRODUCTION
The United States Tariff Commission's twenty-fourth annual
report on the production and sales of synthetic organic chemicals in
the United States is of special significance at this time since it includes
statistics on many products essential to national defense and to the
public health. Among these are toluol and phenol, which are basic
raw materials for military explosives; phenol, urea, formaldehyde,
styrene, and acrylates — some of the basic materials used in the manu-
facture of resins and plastics for airplane turrets and to replace
valuable metals; such chemotherapeutic agents as sulfapyridine, sul-
fanilamide, and sulfathiazole, and the synthetic vitamins, nicotinic
acid amide, and vitamin C, ascorbic acid, essential to the public health.
The products included in this report are grouped, as far as prac-
ticable, according to use under the following classifications: Coal-tar
crudes, mtermediates, dyes, color lakes and toners, coal-tar and non-
coal-tar medicinals, flavors and perfume materials, resins, rubber
chemicals, and miscellaneous chemicals.
In order to obtain information on the relationship between research
and development m the chemical industry, the Commission has, from
time to time, compiled data on expenditures for research by the
synthetic organic chemical mdustry. Appendix A of this report
contains a summary of such expenditures.
The Tariff Commission also cooperates \nth the Department of
Commerce m an analysis of imports of coal-tar intermedia,tes and
finished products.^ A" summary of the import data obtained for
1938-40 and 1941 (6 months) is given in appendix B.
The statistics of production and sales for 1940 were compiled from
returns of 314 companies. Appendix C is a directory of all manu-
facturers who have given permission to be identified as producers.
Every effort has been made to avoid duplicating either production or
sales statistics. In order not to disclose the operations of individual
companies, statistics of production and sales are, in certain cases,
included only in the group totals.
PART I.— SUMMARY, 1940
Production and sales of all classes of coal-tar and non-coal-tar
chemicals in 1940 exceeded those of any previous year. Acceleration
in the rate of coke-oven operations resulted in an increase of more
than 20 percent over the 1939 output of coal tar and of about 38
percent over the 1934-38 average. The sales and production of some
1 U. S. Imports for Consumption of Dyes, aromatic Chemicals, Medicinals, and Other Coal-Tar Prod-
ucts in Paragraphs 27 and 28 of the Tarifl Act of 1930, Semi-Annual Statement No. 2865.
2 UNITED STATES TARIFF COMMISSION
of the prmcipal coal-tar crudes increased in 1940 over thosetof 1939
and preceding years because of the greater demand for refined'coal-tar
products. This demand approached the output capacity for such
products in 1940. By early 1941, capacity was so nearly reached that
there could be little increase in output without plant expansion.
The production of coal tar and the production and sales of some of
the principal coal-tar crudes are shown in table 1 for the years 1939
and 1940, and the average for the period 1934-38.
Table 1.— Comparison of United States production of tar and production and sales
of certain crudes, average 1934-38, annually 1939 and 1940
[Production and sales in thousands of gallons; value in thousands of dollarsl
Product
Average
1934-38
1939
1940
Increase,
1940 over
1939
488,407
22, 376
20, 273
2,822
70, 306
69, 303
6,363
68, 935
61,618
1,239
92, 397
93, 332
10, 140
17, 571
17, 269
4,568
554,406
30, 470
26, 628
3,618
86, 246
81, 672
7,679
104, 086
87,837
1,517
110, 242
101, 487
12, 385
24, 355
24, 683
4,952
673, 287
36, 556
33, 376
4,305
101, 140
95, 330
8,038
159, 637
145, 914
2,920
119, 679
107, 716
13, 030
30, 440
29, 524
7,298
Percent
21.4
Benzol:
20.0
Sales
25.3
Sales value
19.0
Motor benzol:
17.3
Sales
16.7
Salesvalue .
4.7
Naphthalene:
53.4
Sales ' . .-
66.1
Salesvalue -
92.5
Creosote oil:
8.6
Sales
6.1
5.2
Toluol:
Production
25.0
Sales
19.6
47.4
1 Thousands of pounds.
Source: Compiled from data reported to the Tariff Commission and to the Bureau of Mines.
The total sales of synthetic organic chemicals in 1940, including
sales of finished coal-tar products, intermediates and non-coal-tar
chemicals, were valued at $483,417,000, an increase of 26 percent over
the sales in 1939, which, in turn, exceeded those of any previous year.
The increase in sales value of coal-tar chemicals, including inter-
mediates in the same period was from $184,645,000 in 1939 to
$218,110,000 in 1940, or 18 percent, and in non-coal-tar chemicals
from $199,698,000 to $265,307,000, or 33 percent.
The groups advancing most in sales value and in production were
the coal-tar resins, medicinals, and mtermediates. In 1940, as m
preceding years, about one-half of the output of intermediates and
non-coal-tar chemicals and smaller fractions of other groups were not
sold as such but were consumed by producers in further processing.
The peak activity in both sales and production m this year reflected
improved business activity, some of which was inspired by increased
civilian consumption and some by uidirect demands for military
purposes. In the first half of 1940 consumption for direct military
use was not an important factor. In the second half of 1940, however,
and in 1941, the production of synthetic organic chemicals for defense
purposes steadily increased.
SYNTHETIC ORGANIC CHEMICALS 6
Other factors influencing production were the accumulation of
inventories of both consumers and producers, and an increase in
exports, together with a decrease in imports of organic chemicals.
The value of exports of coal-tar products reached $28,449,000 in 1940,
the highest figure on record. Imports of coal-tar products decreased
in value from the 10-year high of $18,942,000 reached in 1939 to
$9,034,000 in 1940— the lowest since 1919. Virtually all important
raw materials for synthetic organic chemicals were abundant in the
United States in 1940 and, in general, prices of dyes, intermediates,
and finished products advanced only moderately. The average value
per pound of coal-tar dyes increased from 61 cents in 1939 to 62 cents
in 1940; intermediates from 14 cents to 15 cents; and finished prod-
ucts from 41 to 43 cents. Production and sales of intermediates,
dyes, and other coal-tar chemicals are summarized in table 2, and
comparisons thereof are made in table 3 by groups for 1939, 1940,
and the average for 1934-38. Similar statistics for non-coal-tar
chemicals, grouped according to their uses, are shown in tables 4 and
5. The value per pound of all non-coal-tar chemicals remained at
13 cents, although the unit values of some individual groups, such as
medicinals, resins, and flavors and perfumes, increased appreciably.
Table 2. — Intermediates, dyes, and other coal-tar chemicals: Summary of United
States production and sales in 1940
[Quantity in thousands of pounds; value in thousands of dollars]
Number
of manu-
facturers
Production
(quantity)
Sales
Product
Quantity
Value
Value per
pound
Intermediates
69
225
805. 807
522, 851
315. 967
402, 325
$46, 428
171, 682
.$0. 15
Finished products, total - - -
.43
Dyes:
Classified
104, 539
23, 295
100, 793
21, 884
51, 430
25, 002
.51
Linclassified
1.14
Total
46
127, 834
122, 677
76. 432
.62
Color lakes and toners,
45
52
30
66
11
51
19, 213
18, 214
5. 485
222, 943
37. 139
92, 023
16, 786
15,010
5.062
153, 521
28, 025
61,244
12,512
17. 774
4,751
33, 378
1.3. 600
13, 235
.75
Medicinals
1.18
Flavors anr] pprfnme mntpfifils
.94
Pesins _ .. .
.22
Rubber chemicals
.49
Miscellaneous '
.22
J Includes benzoate of ammonia, benzoate of soda, benzoyl peroxide, biological stains and chemical indi-
cators, poisonous and tear gases, synthetic insecticides, photographic chemicals, plasticizers, synthetic
tanning materials, textile chemicals, and others.
416161 — 41-
4 UNITED STATES TARIFF COMMISSION
Table 3. — Intermediates, dyes, and certain other classes of coal-tar chemicals:
Comparison of United States production and sales, average 1934-38, annually
1939 and 1940
[Production and sales in thousands of pounds; sales value in thousands of dollars]
Product
1934-38
average
1939
1940
Increase,
1940 over
1939
Intermediates:
Production __ _ _ .
462, 614
197, 918
28,305
292, 873
251, 838
106, 800
102, 528
101, 137
55, 227
11,596
9,625
9,412
4,041
3,757
3,354
102, 644
77, 891
15, 271
607, 175
269, 084
38, 489
437, 867
353, 604
146, 156
120, 191
114, 494
70, 224
15, 188
12, 932
13,711
5,349
4,938
4,447
179, 338
128, 420
23, 028
805, 807
315, 967
46, 428
522, 851
402, 325
171, 682
127, 834
122, 677
76, 432
18, 214
15. 010
17, 774
5,485
5,062
4,751
222, 943
153, 521
33, 378
Percent
32.7
Sales ----
Sales value - . _ .
17.4
20.6
Finished coal-tar products: '
Production
19.4
Sales
13.8
Sales value ._
17.5
Dyes:
Production ___
Sales
6.4
7.1
Sales value
8.8
Medicinals:
Production
Sales . .-
19.9
16. 1
Sales value. ..
29.8
Flavors and perfume materials:
Production
2.5
Sales
Sales value .. ... .
2.5
6.8
Resins:
Production
Sales
24.3
19.5
Sales value
44.9
Includes color lakes, rubber chemicals, and miscellaneous coal-tar products not shown separately.
Table 4. — Synthetic organic chemicals of non-coal-tar origin: Summary of United
States production and sales in 1940
[Quantity in thousands of pounds; value in thousands of dollars]
Number
of manu-
facturers
Production
Sales
Product
Quantity
Quantity
Value
Value per
pound
Medicinals
Flavors and perfume materials .
37
30
22
9
92
2,246
2,510
53, 871
16,915
3, 857, 541
1,727
2,129
47, 579
15, 353
1, 922, 496
$7, 587
1,925
25, 990
3,747
226, 058
$4.39
.90
Resins
.55
Rubber chemicals.. .
.24
Miscellaneous chemicals.
.12
Total
3. 933, 083
1, 989, 284
265, 307
.13
Table 5. — Synthetic organic chemicals of non-coal-tar origin: Comparison of United
States production and sales, average 1934-38, annually 1939 and 1940
[Production and sales in thousands of pounds; value in thousands of dollars]
Item
Average
1934-38
1939
1940
Increase,
1940 over
1939
Production . .. . .. . . ..
1,941,220
951, 158
106, 171
3, 034, 655
1, 532, 363
199, 698
3, 933, 083
1, 989, 284
265, 307
Percent
29.6
Sales
29.8
Sales value
32.9
SYNTHETIC ORGANIC CHEMICALS 5
PART II.— PRODUCTION AND SALES BY GROUPS, 1940
COAL-TAR CRUDES
Coal-tar crudes, obtained from coal tar, are the basic raw materials
from which the synthetic coal-tar chemicals are manufactured. An
increase in coke-oven operations in 1940 brought about an mcrease of
21.4 percent in the output of coal tar above the amount produced in
1939, or from 554,406,000 gallons to 673,287,000 gallons, according to
statistics collected and compiled by the Bureau of Mines. The
quantity of coal tar, water-gas tar, and oil-gas tar distilled in 1939 by
the purchasers thereof, as reported to the United States Tariff Com-
mission, was 334,871,000 gallons. The quantity so distilled in 1940
was 346,792,000 gallons — a gain of 3.5 percent. Fifty-two percent
of the coal tar produced in 1940 was sold by the producers, as com-
pared with 62 percent in 1939 and 72 percent in 1938.
The output of crude and refined toluene in 1940 was an increase of
25 percent over the preceding year, or from 24,355,000 gallons to
30,440,000 gallons — the largest output on record. The increase was
no doubt stimulated by consumption for military uses. No com-
mercial production of toluene of nitration grade from petroleum was
reported in 1940, but it is likely that in 1941 the quantity so derived
will approach the combined production from byproduct coke ovens
and from coal-tar distillation. Other light oil products, such as
benzol, motor benzol, and xylol, showed substantially increased
production in 1940,
The production of crude naphthalene increased from 104,086,000
pounds in 1939 to 159,637,000 pounds in 1940, an increase of 53.4
percent. Increased demand, particularly from manufacturers of
phthalic anhydride resins, and decreased imports (41,000,000 to
6,000,000 pounds) were no doubt responsible for the larger output in
1940. Increased demand for creosote oil for waterproofing and for
resin manufacture have resulted in greater recovery of crude cresylic
and other tar acids.
Table 6 shows domestic production and sales of coal tar, crude light
oils, and crude products made from them, as well as of naphthalene,
cresylic acid, creosote oil, and several kinds of distillate and residue
tar. These statistics are a combination of the data reported to the
Bureau of Mines by coke-oven operators who distill or partially distill
(top) tar produced by themselves, and those reported to the Tariff
Commission by distillers of purchased tar.
6 UlSnTED STATES TARIFF COMMISSION
Table 6. — Coal-tar crudes: ^ United States production and sales in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61 . An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information with regard to individual firms.]
UnU
Tar distilled by purchasers thereof: ^ Gallons Value value
Oil-gas tar 5,247,209 $235,766 $0,045
Water-gas tar 41,579,643 1,830,923 .044
Coal tar 299,965,061 15,461,612 .052
Total 346,791,913 17,528,301 .050
Product
Tar 3 gallons..
Light oil and derivatives:
Crude light oil do —
Benzol (except motor benzol) _ .
gallons.
Motor benzol ' do
Toluol, crude and refined
gallons.
Solvent naphtha, crude and
refined. gallons.
Xylol 3 do
Other light oil products ^.do
Naphthalene, crude (solidifying
under 79° C.)5 pounds.
Anthracene, crude (less than 30
percent) 2 pounds.
Cresylic acid, crude (less than 75
percent) 2 gallons.
Cumene 2 do
Pyridine, crude and refined 3 . do
Creosote oil do
Coal tar sold or consumed in coal-
tar solution. 2 gallons.
Tars, crude and refined 2 do
Tars, road 2. _do
Other distillates " do....
Pitch of tar tons..
Pitch of tar coke 2 do
Total
Identification numbers of
manufacturers reporting
to Tariff Commission (ac-
cording to list on p. 61)
58, 109, 121, 178, 187,
198, X, X.
8,22, 159, 178, 198
8,22, 159, 178,198
8, 22, 127, 159, 169, 187,
8, 22, 159, 58, 109, 121, 159,
178, 187, 188, 198, X, X.
22,,58, 127, 159, 178,187,188,
194, X.
187
22, 217.
22
8, 11, 22, 57, 58, 68, 109, 115,
121, 127, 129, 159, 187,
188, 194, X, X.
11, 22, 121, 127, 187, 188....
22, 58
178,
11, 22,
187,
8, 11,
173,
X.
11, 22,
121,
188,
11, 22,
, 109, 121, 127, 159,
187, 188, 194, X, X.
68, 109, 115, 127, 178,
188, 194.
22, 57, 109, 121, 127,
187, 188, 194, 198, X,
57, 58, 68, 109, 115,
127, 129, 173, 187,
194, X.
68, 115, 127, 187, 188..
Production
(quantity)
286, 517
617, 985
555, 643
140, 079
440, 324
9, 230, 139
645, 993
689, 253
159, 637, 499
241, 075
678, 785
215, 152
718, 000
523, 083
631, 609
707, 082
90, 906
Sales
Quantity
Value
691, 110
324, 670
376, 216
329,911
524, 248
8, 496, 302
335, 574
561, 159
5,
9,
145, 914, 455
218, 165
107, 715, 986
4, 274, 152
23, 173, 506
152, 737, 701
13, 091, 194
391, 741
87, 177
$16, 051, 496
3 829, 031
4, 304, 574
8, 037, 526
7, 297, 790
1, 239, 603
956, 102
2, 920, 029
296, 441
13, 030, 307
249, 224
1, 678, 895
10, 511, 926
1, 983, 027
4, 988, 049
1, 009, 219
77, 258, 333
Unit
value
$0,046
.080
.129
.084
.247
.179
.232
.100
.020
1.359
.121
.058
.072
.069
.151
12. 733
11. 580
• Data for coke ovens reported to Bureau of Mines, and for tar refineries and others, to United States Tarifl
Commission unless otherwise noted.
2 Reported to United States Tariff Commission only.
3 Reported to Bureau of Minos only.
< Includes production and sales of motor benzol, and xylol , and sales of crude light oil reported to the Tariff
Commission and other light oil products reported to Bureau of Mines.
' Includes refined naphthalene reported to Bureau of Mines.
6 Includes crude-tar acids and pyridine reported to United States Tariff Commission and phenol, sodium
phenolate, and certain other products reported to Bureau of Mines.
COAL-TAR INTERMEDIATES
The production of coal-tar intermediates in 1939, then the highest
on record, was surpassed in 1940 by 32.7 percent, amounting to
607,175,000 pounds in 1939 and to 805,807,000 pounds in 1940. Sales
amounted to 315,967,000 pounds, or an increase of 17.4 percent over
those of 1939. The difference between production and sales is almost
entirely due to the large consumption by producers in the manufacture
SYNTHETIC ORGANIC CHEMICAL'S 7
of finished products. The distinction between finished products and
intermediates is, at times, arbitrary since many products may be
classified as either an intermediate or a finished product. When a
coal-tar product falls logically into more than one category, it is
usually classified by the producer as an intermediate.
The increase in output of intermediates used in the manufacture of
synthetic resins was largely responsible for the increase in total output.
Thus phthalic anhydride and phthalic acid production rose from
44,274,000 pounds in 1939 to 57,946,000 in 1940, or 31 percent; phenol,
both natural and synthetic, from 68,577,000 to 96,155,000 pounds, or
40 percent. The output of maleic acid and anhydride reached
4,497,000 pounds, which was more than double that of the preceding
year. While the production of refined naphthalene decreased slightly
in 1940, there was an increase of 53.4 percent in crude naphthalene
production. Of the refined naphthalene produced in 1940, amounting
to 58,250,000 pounds, 52,095,000 pounds were from domestic crude
and 6,155,000 from foreign crude, as compared with 31,705,000 from
domestic and 27,761,000 from foreign crude in 1939. Production of
aniline oil, the basic intermediate used in the manufacture of dyes,
was 55,720,000 pounds in 1940, an increase of 13,944,000 pounds over
the 1939 production.
Other important intermediates showing considerable gain in 1940
over the 1939 output are: Benzoic acid, 43 percent; cliloroanthra-
quinone, 72.5 percent; dimethylaniline, 70 percent; dinitrochloro-
benzene, 32 percent; dinitrobenzene, 44 percent; trichlorobenzene,
116 percent; and refined cresylic acid, 30 percent. Newly installed
equipment for increasing the capacity to produce phenol was in
operation only part of the year.
Statistics of production and sales of coal- tar intermediates in 1940
are shown in table 7.
Table 7. — Coal-tar intermediates: United States production and sales in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed
on p. 61. An X signifies that the manufacturer did not consent to the publication of his identification
number with the designated product. Blanks in the third, fourth, and fifth columns indicate that the
statistics of production or sales cannot be published without revealing information with regard to indi-
vidual firms. The figures thus concealed, however, are included in the total.]
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Acetanilide, tech__ , __.
45,60,62,87,145
87
Pounds
398, 833
Pounds
Acetanilide-p-sulfonic acid
Acetoacetanilide _ .
37,230 -
230
p-Acetoaeetchloroanilide(aeetoacet-p-chlo-
230
roanilide).
o-Acetoacetotoluide(acetoacet-o-toluidide).
Acetoaceto-m-xvlide (acetoacet-m-xyli-
230
230
dide).
5-Acetylamino salicylic acid
1
o-Acetaniside (acetvl-o-anisidine)
6
105
Acetvldiaminoanthraquinone
6
Acetvl-l,4-naphthalenediamine-6 and 7-
150
sulfonic acids (aeetylamino Cleve's
acid).
87
Acetylsulfanilic acid
6
Acetyltoluidine (acetotoluide)
Acetyl-p-toluidine
8, 150
62, 105,X,X
8 UNITED STATES TAKIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Acridine yellow
62,150 .._-
Pounds
Pounds
Adipicacid __
62 ..._
m-Aminoacetanilide (aeetyl-m-aminoani-
6
line).
p-Aminoacetanilide (acetyl-p-phenylene-
45,62,87,150
298, 881
427, 415
747, 360
diamine).
l-Aminoanthraquinone and salt _
6,62,87,150
2-Aminoanthraquinone--
62,87,150
l-AminoanthraQuinonc-2-sulfonicacid
87
Aminoazobenzene and hydrochloride
6, 8, 45, 62, 87, 150, 172.
6,87, 150
6, 8, 45, 62, 87, 150, 172.
6, 8, 45, 62, 87, 150, 172.
6,87,150 -.._
206, 457
35, 014
175, 325
449, 029
Aminoazobenzene disulfonic acid...
Aminoazobenzene sulfonic acid
Aminoazotoluene
Aminoazotoluene mono sulfonic acid and
salt.
Aminoazoxylene
6,87.150
Aminoazoxylene-toluidine
8,150 .__
8-Amino-l,2-benzacridone
62_-_-
o-Aminobenzoic acid (anthranilic acid)...
7,60,62 ...
130, 615
$101,904
$0.78
p-Aminobenzoic acid
62
o-Aminobenzoio-p-sulfonic acid...
87
Amino-5-benzovlaminoanthraqmnone
62,87
m-Aminobenzoyl J acid
6,62,150,172
6,45,62,87,150,172...
24, 816
'"
p-Aminobenzoyl J acid._ ,_
p-Aminobenzoyl-m-phenvlenediamine
62
m- Aminobenzoyl-p-tol vlenediamine
62
l-Amino-2-bromo-4-p-toluidine anthra-
62
quinone.
Aminobutyrylaminodiethyl hydroquin-
172
one.
3-Amino-4-ch]orobenzoyl benzoic acid
87
Aminochlorodiphenyl ether
172
■2- Amino-4-chloro toluene
62, 150 -
62, 150 ..
m-Aminocresvl methyl ether
45
l-Amino-2,4-dibromoanthraquinone _
62,150
2-Amino-l,4-diothoxy benzene _ _
87
X
chloride.
p-Aminodiethylaniline
69, 87
2-Amino-l,4-dimethoxy benzene .
87
69
62
Aminodiphenylamine sulfonic acid
45, 87, 150 . .
Aminodiphenyl ether ....
172
1
6_.
4-Amino-3-methoxy diphenylamine-2-sul-
45 ...
fonic acid.
87
1,7-Aminonaphthol
62
l-Amino-8-naphthol-2,4-disulfonic acid
45,62,150
178, 471
4, 309, 188
(Chica!!o acid).
l-Amino-8-naphthol-3,6-disulfonic acid
(H acid).
•2-Amino-8-naphthol-3,6-disulfonic acid
(2Racid).
l-Amino-2-naphthol-4-sulfonicacid
l-Amino-8-naphthol-4-sulfonicacid
•2-Amino-5-naphthol-7-sulfonic acid (J
acid).
2-Amino-8-naphthol-6-sulfonic acid
(gamma acid).
45,62,87,149,150
62, 150
45,62,87,150
835. 754
37, 065
884, 054
1, 302, 585
32, 137
674, 643
45, 62, 150
6,45,62,87,150
6,45,62,87,150
62,69,237,246, X
8, 62, 69, 237, 246, 248,
X.
45,62,150 -
64,129
154,092
28, 968
273, 009
109, 133
129, 224
40, 259
177, 370
1.70
.84
1.39
p-Aminophenol and hydrochloride
.65
p-Aminophenylammonium hydroxide
m-Aminophenylpyrazolone carboxylic
acid.
p-Aminophenyl-p-tolylamine sulfonic
acid.
X
62
45 X
172 . .
184, X -.
6,45,150 . -
17, 768
87
45
Amino violanthrene
87
SYNTHETIC ORGANIC CHEMICALS 9
Tablk 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Amy benzyl cvclohexyl amine
149
Pounds
Pounds
Amyl naphthalenes . ..
202 -
Amyl phenol (p-tertiary) .
202 -
Aniline disulfonic acid
45,62,150,172
8
70, 332
Aniline hydrochloride and sulfate .
Aniline methane sulfonic acid
87,172
8, 60, 62, 145, 149,
150,151.
62,150,172
55, 719, 733
20, 074, 178
$2,182,948
$0.11
Aniline omega sulfonic acid
Anisic acid -- - -
X
o-Anisidine .
62,149 -
p-Anisidine -
62,149,150 --
o-Anisidine omega sulfonic acid
150,172
Anthranilic acid (see o-Aminobenzoic
acid) .
Anthracene, refined -- .-
187
Anthraquinone (100 percent) . . . _
8,150
Anthraquinone-2,r)-disulfonate-. __
62,87
Anthraquinone 2.7-disulfonate -
150
Anthraquinone-l,5-disulfonic acid _. -_-
62,87
Anthraquinone-l,8-disulfonic acid -
62,87
Anthraquinonp-2,6-disulfonic acid
150
o-Anthraquinone hydrazine disulfonate.-.
87,150 --
Anthraquinone-l,8-potassium disulfonate.
62
Anthraquinone-1-sodium sulfonate.- . __
62
Anthraquinone-2-sodium sulfonate (silver
6,62,150
salt).
1-Anthraquinone sulfonic acid...
87 .-. — — -
2-Anthraquinone sulfonic acid
87 -
1 ,9- Anthrathiazol-2-carbonyl chloride
62 . -
X
Azoxvaniline _ - _
172 — -
Benzaldehyde, tech
25, 100, X .-- -
Benzaldehyde disulfonic acid -- -
87 —
Benzaldehyde monosulfonic acid--
87 .
BenzamidC- .. .. __
87, 108
Benzanthrone-- . _. -. . .
6,8,62,87,150,167
62
477, 161
Benzene sodium disulfonate _. . _. .
Benzene sulfonamide ... .
149
Benzene sulfonic acid . --
149-
Benzene sulfonyl chloride.--
69,149
Benzidine, base - -- -
20,45,62,150
Benzidine disulfonic acid -. - ------
6, 45, 87, 172, X
8,62,87,150
21, 377
1,626,424
Benzidine hydrochloride and sulfate
Benzidine sulfonic acid ..-
45
Benzoic acid, tech - - . - _ ..
62,100,104,108.149.-
87,108 -
318, 849
281, 202
108, 556
.39
Benzoic anhydride . -- - .
Benzotrichloride
104,108,149 . -
166, 176
137, 685
20, 022
.15
Benzoyl acetanilide -
X
l-Benzoylamino-4-chloroanthraquinone
87
l-Benzoylamino-5-chloroanthraquinone
62, 150
2-Benzovlamino-l,4-diethoxybenzene
87 .-
2-Benzoylamino-l,4-dimethoxybenzene
87 —
5-Benzoylaniino-2-nitro-hydroquinone
87
diethylether.
l-Benzovlamino-5-p-toluene sulfonic an-
62
thraquinone.
Benzoyl benzoic acid . .
8,62.87,150. -
Benzoyl chloride . . -
60,108,149
Benzoyl J acid . .. .
45
Benzyl chloride _
25, 108, 149, X
25 -
2,377,768
Benzyl cyanide ...
Benzyl disulfide -. .-
108 .-
Benzylidine aminopyrazolone
X - .
Broenner's acid (see 2-Naphthylamine-
6-sulfonicacid).
Bromamine acid .. .--_--
62, 87, 150
6,62,87
35, 877
Bromobenzanthrone
60,69,78
p-Bromomethylaminoanthraquinone
1-Bromonaphthalene
87
78
3-Bromophthalic acid
X .- -.
60
Butyl phenyl phosphite
149
Carbazole, refined
187
Carbazole ethoxy pyrazolone
87 --
Chicago acid (see l-Amino-8-naphthol-
2,4-disulfonicacid).
10 UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
X
Pounds
Pounds
2-Chloro-3-acetamino anthraquinone
87
37.230
172
l-Chloro-5-aminoanthraquinone -
62,150
l-Chloro-8-aminoantliraquinone
62
87
62,87,150, X
Chloroaminophenol sulfonic acid
45,87,150
5-Chloro-2-aminotoluene hydrochloride
62
149,237
62,149
62,149
87,172
6,45,62
28, 188
108,150,237
172
8,62,87,150
742, 508
89, 445
62,105,150
6,150
60, 62, 71, 108, 149,
211, X, X.
87 .
4, 938, 286
$190, 671
$0 04
87
62,150, X
87
14, 867
l-Chloro-5-benzovlaniino anthraquinone .
87
8,62,87,150
1, 570, 790
108
l-Chloro-2-carboxy anthraquinone
62,150
22
2-Chloro-l,4-dihydroxy anthraquinone
(chloroquinizarin).
62,150
6 . . _
X
62, l.TO .-- _.
8,62,87,150
129, 721
108, X
8-Chloro-l-naphthol-3,6-disulfonic acid- -
87 -
8,60,62
101, 393
p-Chloronitroaniline
p-Chloro-o-nitroaniline..
60,150,237
62
87
l-Chloro-5-nitroanthraquinone
l-Chloro-8-nitroanthraquinone
62,150
62
87
Chloronitrodiphenyl ether
172
62,87
62,150
149, X
60,149 - - -.
X -
Chlorophpnylhydrazine-p-suifonic acid - - -
87
172
Chlorosulfophenylmethylpyrazolone .
62,87
22
62,105,108,150
o-Chloro-p-toluene sodium sulfonate
149, X
87
150
172
8,45, 62, X
247, 641
36,896
29,930
.81
62
62,87, 150
6
85, 434
87
Chromotropic acid (see 1, 8-Dihydroxy-
naphthaIene-3,6-disulfonic acid) .
Cleve's acid (see l-Naphthylamine-6 and
7-snlfonicacid).
62
22, 187, 188, X
22 - --
1, 329, 199
1, 370, 169
152, 785
.11
22,222
22, 187, 188
8, 22, 127, X ._.
60
16,049,525
16,023,297
1, 209, 428
.08
Cresylic acid (refined)
8,22, 127, 187, X
18, 371, 261
18, 048, 382
i, 234, ii3
.07
SYNTHETIC ORGANIC CHEMICALS H
Table 7.- — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Cresvl glycol - - ---
87
Pounds
Pounds
o-Cresyl-p-toluene sulfonate
149
Cumidine,_ ..
23, 150
Cvanoacetvlcoumarone... _ --_
X
Cyclohexvlamine. . .
149
Decvl benzene .
149
Dehvdrothio-p-toluidine
62
Dehydrothio-p-toluidine sulfonic acid ..
45.62, 150
24, 372
m-Diaminoanisole __. _ . _ . . ...
237
Diaminoanthraquinone. . .
6, 45, 62, 87, 150
62, 150
212, 498
2,6-D iaminoanthraquinone
Diaminoanthrarufin ...
62
Diaminodiacetic acid... .
172
D iaminodibenzanthronyl
62
4,4' - Diamine - 2.2' - dimethyldiphenyl-
150
methane.
l,8-Diamino-4,5-dinitro anthraquinone..
62
Diaminodiphenvlamine sulfonic acid
6,45
DiarainophenetoL ___ ._ _,-
8..
Diaminostilbene disulfonic acid. .. . ...
62, 87. 150
261, 481
1 ,5-D ianilidoanthraquinone-o-o-dicarbox-
62,87
ylic acid.
Dianisidine .-. . .
45,62
1,1-Dianthraquinone imine .
62,150
1,1-Dianthraquinone imine diamino
62,87,150
1 , 1-D ianthraquinone imine-4,4-dibenzoyl-
62,150
diamino.
1,1-Dianthraquinone imine 4,5-dibenzoyl
62,150
diamino.
1,1-Dianthraquinone imine dinitro _._
62
1,1-Dianthraquinylamine.
87
l-Diazo-2-naphthnl-4-sulfonic acid.
45,150
Diazosalicvlic acid- - . . _ .
62.87,150
8,62
48, 790
Dibenzanthrone . . .
2.2-DibenzanthronyL_ .. _:
62
13,13-Dibenzanthronyl..
62
4,.5-Dibenzoylamino-l, 1-dianthraquino-
87
nylamine.
Dibenzvl .. .._ . ...
100 .
Dibenzvl aniline .. . .
62-
D ibromoaminoanthraquinone
62,87
p-Dibromobenzene
60
Dibromodiliydroxvnaphthalene
X
Dibromopyranthrone ...
62
Dichloroacetoacetanilide
37
45, 62, 108, 149, 150,
237.
6,62,172
293, 902
148, 308
$62, 761
$0.42
Dichloroaniline sulfonic acid
1,5-Dichloroanthraquinone ..
62,150
1,8-Dichloroanthraquinone. ^ .-
62,87
l,8-Dichloroanthraquinone-4, 5-disulfonic
87
acid.
2,6-Dichlorobenzal chloride. .
62
2,6-Dichlorobenzaldehyde- . _.
150
o-Dichlorobenzene
60, 62. 71, 108, 149,
211, X. X.
60, 62, 71, 108, 149,
211.x, X.
45,62,105, 150
5, 849, 618
15, 086, 726
4, 375, 884
14, 165, 109
220, 285
1, 207, 143
.05
09
Dichlorobenzidine
l,8-Diehloro-4,5-dinitroanthraquinone
62
2,4-DichlorophenoL ... .. . ..
149
Dichlorohvdrazine
172
D ichlorophenvlpyrazolone carboxylic acid.
172
Dichlorosulfophenylmethylpyrazolone...
45,62,172
Di-o-cresol _ __ ... ...
X
Dicvclohexvlamine ... ..
149
2,5-Diethoxy aniline. .
60, 62
3-Diethvlaminoacetanilide
87
Diethvlaminobenzaldehyde ... .
87, 150
3-Diethvlaminophenol. _ . .
62, 139
Diethvlaniline ..
60,62, 150
Diothvlaniline-m-sulfonic acid
62, 139
Diethyl-m-toluidine.- _ _ _-
62
Dihydroxyaminoanthraquione .
87
l,4-Dihydroxyanthraquinone(quinizarin).
6, 8, 17, 62, 87, 150,
248.
62, 87, 150,X
341, 912
198, 114
1,5-Dihydroxyanthraquinone (anthraru-
fln).
416161—41 3
12 UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United Slates production and sales in 1940— Con.
Manufacturers' iden-
tiflcation numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
1,8-Dihydroxyanthraquinone (chrysazin) .
l,5-Dihydroxy-4,8-clinitroanthraquinone
(4,8-dinitroanthrarufin) .
6,5' - Dihydroxy - 7,7' - disulfonic - 2,2' -di-
naphthylamiae (Rhoduline acid).
6,5' - Dihydroxy - 7,7' - disulfonic - 2,2' - di-
naphthylurea (J acid urea).
Dihydroxyethylaniline
62, 87
Pounds
Pounds
6,62
45,62,87, 172
6,45,62,87, 150
37, 87
35, 427
329, 764
87
87
62, 87, 150
29, 007
107, 540
l,8-Dihydroxynaphthalene-3,6-disulfonlc
acid (chromotropic acid).
2,3-DihydroxynaphthaIene-6-sulfonicacid.
5,5'-Dihydroxy-di-/3-naphthylamine-7,7'-
disulfonic acid (I acid imide).
6, 45, 62, 150
87
150 - - -
87
62
8,60,62,65,150
8, 62, 87, 150
7, 049, 741
79, 407
69
87
8, 149
6,62
62, 87
8,62, 150
2, 642, 074
45, 87 - -----
6, 8, 62, 87, 149, 150-
87
9, 753, 665
1, 786, 274
$181, 001
$0.10!
25, 150, 215
92, 870
39, 807
.43;
60 -- ---
62
45, 87, 150-
44,981
6, 62, 87, 150-- -
62, 87, 150 - - -
495, 911
62, 150 .
87
87
150 . - .
62
6, 45, 62
12, 326
6 --
62
60, 62 .
Diphenyl and derivatives:
60, 149
149 - --- ---
149
60
2-Chloro-6-phenylphenol and sodium
salt.
60 - .
149
149
149
60
62 150, X
57, 857
62 87
150 -
62
l|4-Di-p-toiylaminoantbraquinone
62
149 -
6-Ethoxy;3-hydroxy thionaphthalene
62
87.x
62, 139 -
60,62,150
60
X
149
62, 150
45. 62, 87, 105, 150—.
02, 150 -
453, 799
Ethylbenzyl-m-toluidiae sulfonic acid
62 87, 150
19, 010
60
62
62, 139
62, 150
Fluorescein
105, 154
SYNTHETIC ORGANIC CHEMICALS 13
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufactui'crs' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Gamma acid (see 2-Amino-8-naphthol-6-
Pounds
Pounds
sulfonic acid).
H acid (see I-Amino-8-naphthol-3,6-disul-
fonic acid).
Hexachlnrobenzene -- -
108
Hexachlorodiphenvl oxide
60
Hexamethylenediamine -. --
62
Hexaraethylene diammoniura adipate
62
2,1-2,1-Hydrazine dibromoanttiraquinone-
62
38, 237, X
Hvdroquinone diethyl ether . -
87
Hydroquinone dimethyl ether.
87, X -
1-H ydrox y-4-aminoanthraquinone
l-HydroxyanthraQuinone.- -
87 ■-
6,150
Hydroxy "ethylethvlaniline - --
62,87
Hydroxy ethylmethylaniline
87
62,87, 150, X..-
62
1, 331, 807
665, 007
$642, 489
$0.97
p-Hydroxyphenyl arsenic acid
1
4-Hydroxyphenyl-2-naphthylamine
87
X
Indophenol (blue and green) .-.
20,62, 150
325, 139
150
Isopropyl ester of p-toluidine sulfonic acid.
62
Iso violanthrone
6
Laurent's acid (see 1 -Naphthylamine-5-
sulfonic acid).
Lead trinitrorosorcinate (lead styphnate) .
X
Leuco-l,4-dimethvldiaminoanthraquinone
62
62
Leuco quinizarin - ._ -- - -- ---
6, 62, 150
7, 37, 149, 150
150
4, 497, 216
2, 922, 619
718, 935
.25
Malic acid -
Metanilic acid
8, 45, 62, 87, 139, 150.
87
681, 181
2-Methoxv-4-amino-diphenylamine-2-sul-
fonic acid.
1-Methoxyanthraquinone
87
2 - Methoxv - 4 - nitrodiphenylamine - 2-
87
sulfonic acid.
4 - Methoxv - 4 - nitrodiphenylamine - 2-
87
sulfonic acid.
Methoxy omeca sulfonic acid .
62
Methyl acetanilide_ ._.
87
Methylaminoanthraquinone.
62, 87, 150
4 - Methyl - 4 - aminodiphenylamine - 2-
150
sulfonic acid.
2-Meth vlanthraquinone -
8,62, 150
2-Methvlbenzanthrone .-
150
Meth vlevclohexylamine
149
Methylene bismethvl ._. __-
X
N-Methvl naphthoquinoline (n-methyl
87
anthrapyridine).
2-Methylquinoline (quinaldine)
22, 150
Methyl stvrenc . .-. ..-
X
Michler's hvdrol (see Tetramethvldi-
aminobenzhydrol).
Michler's Icetone (see Tetramethyldiam-
inobenzophenone)
Naphthalene, solidifying 79° C or above
(refined, (lake).
From domestic crude naphthalene
8, 22, 53, 62, 187, 205,
244, X, X.
58, 249, 891
52, 094, 527
6, 155, 364
274, 298
31, 669, 868
1, 839, 601
.06
From imported crude naphthalene
1,5-Naphthalene disulfonic acid --
45,62,87, 150
87 .
1,6-Naphthalene disulfonic acid
2,7-Naphthalene disulfonic acid .. .
62, 150, X
Naphthalene sodium sulfonate ._-
87
Naphthalene sodium trisulfonate
X
2-NaphthaIene sulfonic acid
87, 149, 150
31,414
Naphthalene-i8-thio2;lvcnllic acid ..
62, 87
Naphthalene-l,3,6-trisulfonie acid
87 ,..
Naphthionic acid (seel-Naphthylamine-1-
sulfonic acid).
a-Naphthnl
45, 62, 87, 150
8, 150, X...
558. 859
0-Naphthol, tech
l-Naphthol-3,6-disulfonic acid _- -..
45, 150
l-Naphthol-8-chloro-3,6-disulfonic acid
150
(chloro H acid).
;[4 UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Name of intermediate
&
2-Naphthol-3,6 disulfonle acid
2-Naphthol-6, 8-disulfonic acid
Naphthsulfochloride
l-Naphthol-4-snlfonic acid (Nevile
Winther's acid).
l-Naphthol-5-sulfonic acid
l-Naphthol-8-sulfonic acid
2-Naphthol sulfonic acid
2-Naphthol-6-sulfonic acid (Schaeffer's
acid).
2-Naphthol-7-STJlfonic acid
2-Naphthol-8-siilfonic acid
1,8-Naphthosultone
l,8-Naphfhosultone-3,6-disulfonic acid
l,8-Naphthosultone-3-sulfonic acid
a-Naphthylamine
(S-Naphthylamine
a-Naphth\iamine disulfonic acid
l-Naphthvlamino-3.8-disulfonic acid
l-Xaphthvlamine-4, 7-disulfonic acid
l-Naphthylamine-4, 8-disulfonic acid
2-Naphthylamine,3, 6-disulfonic acid
2-Naphthylaraine-4, 8-disuKonic acid
2-NaiihthvIamine-5, 7-disulfonic acid
2-Naphth vlamine-fi. 8-disulfonic acid
l-Naphthy!amine-2-sulfonic acid (o-naph-
thionic acid) .
l-Naphthylamine-4-sulfonic acid (naph-
thionic acid).
l-Naphthylamine-5- sulfonic acid
(Laurent's acid).
1-N aph th y lam ine-fi-sulf onic acid
l-Naphthylamine-6 and 7-sulfonic acid
(Clevo's acid).
l-NaphthyIamine-7-sulfonic acid
l-Naphthylamine-8-sulfonic acid
2-Naphthylamine-l-sulfonic acid (Tobias
acid).
2-Naphthylamine-.'i-sulfonic acid
2-Naphthylamine-G-sulfonic acid (Broen-
ner's acid).
2-Naphthvlamine-8-sulfonic acid.
l-Naphthvlaraino-3,R,8-trisulfonic acid_.-
2-Naphthylamine-2,3,6-trisulfonic acid —
l-Naphthylamino-2-carboxylic acid an-
thraquinone.
m-Nitroacetanilide
p-Nitroacetanilide
Nitroaminodiphenylamine sulfonic acid-
Nitroarainopheno!
p-Nitro-o-aminophenol
6-Nitro-2-aminoDhenol-4-sulfonic acid
4-Nitro-4-amino-2-sulfodiphenylamine . _.
5-Nitro-2-aminotoluene
o-Nitroaniline
m-Nitroaniline
p-Nitroaniline
p-Nitroaniline sulfonic acid
3-N itro-4-anisid ine (3-N i tro-4-amiiioani-
sole) .
4-Nitro-2-anisidine (4-nitro-2-aminoani-
sole) .
.')-Nitro-2-anisidine (5-nitro-2-aminoani-
sole) .
o-Nitroanisole
p-Nitroanisole
1-N itroanthraqu inone-2-carbonic-acid - . .
Nitrobenzene
Nitrobenzene-2,5-disulfonic acid
Nitrobenzene sulfonic acid
m-Nitrobenzoic acid
p-Nitrobenzoic aci.l
m-Nitrobcnzoyl eiiloride
p-Nitrobeii/.oyl chloride..-
m-Nitrobciizoyl ,1 acid
p-Niti(il)cnz(i.\l J acid
m-N'itr<itn'n/ lyl sulfonic acid
Nitroboiizyl ether
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
45, 62, 87, 150, X.
45,62,87,150
45,62,150---
45, 62, 87, 150.
87
Produc-
tion
Sales
Pounds
553, 200
1, 370, 964
62
8,45,62,87,150-
45,62, X.
45
87
45
87
62, 87, 150-
62, 150
62
45, 62, 87, 150-
150
62, 150-
45,
150
45, 62, 87, 150-
45,62,87,150-
6,45,62,150-
62
6,45,62, 150, X-
8, 45, 62, 87, 150.
62,150
231, 165
117,818
198, 922
Quantity
Value
Pounds
169, 445
20, 918
102, 096
227, 186
1,477,269
1, 982, 909
8, 45, 62, 87, 150-
167, 444
18, 857
580, 666
$87, 192
12, 570
143, 637
Unit
value
$0. 51
.60
45,62,150
8,45,62,87,150—
8,45,62, 105, X,X.
87
45, 150.
87,150
45. 62, 87, 150-
150
87
45,87
6,87
8, 45, 1.50.
6,62,87.-
87
150
172-
149-
150, 887
353. 836
1, 879, 169
4, 740, 909
937, 068
501,488
93, 986
8, 45, 62, 87, 150, 237.
6,149,150,240
8,45,62.87
62,87,105,150
6, 62, 87, 150-
62, 87.
62. 149-
62. 150-
87.
79, 770
49, 355
109, 987
143, 812
8, 62, 87, 1.50, 151 69, 105, 449
45
45,62,87,139,150 477,563
62
62
62,108.--
62, 108, X.
87
62, 87, 172.
6
172
87, 098
SYNTHETIC ORGANIC CHEMICALS 15
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
172
Pounds
Pounds
6 62, 149
62,149
p-Xitrochlorobenzene
6, 62, 149
45
'
150
6,45,62,87,150
87 - -
318, 399
Nitro-p-chlorotoluene
6
150
1,62
45 _ . .
62
8-Nitro-]-diaz()-2-naphthol-4-sulfonic acid-
87 150
45 150 237
87
172 .
1 .. .
l-Nitro-2-methylanthraquinone
Nitronaphthalene
87
62 87 150
2-Nitroiiaphthalene-4,8-disulfonic acid
l-Nitronaphthalene-8-sulfonic acid
45 87
87
87
o-Nitrophenetol
62
o-NitrophenoI
62, 237, X
90,827
p-Nitrophenol
8,62,149,237
Nitrophenvlenediamine
87
Nitropyrazolone
172
Nitrosodiethvlaniline
87,150 .
Nitrosodimethylaniline
6 65
Nitrosoethvlbenzylaniline
87
4-Nitroso-hydroxy-ethylethylaniline
Nitroso-0-naplUhol
87
78 X
Nitrosophenol
8,20,45,62,87, 150.__.
8.62,150
328, 143
Nitrotoluene
o-Nitrotoluene
62,150
m-Nitrotoluene
62 -
p-Nitrotoluene
62,150
87
2-Nitrotoluene-4-suIfo-dimethylamiiie
o-NitrotoIuene sulfonic acid
87
6,45,87
p-Nitrotoluene-o-suIfonic acid
45,62,87,150
1, 182, 521
Nitrotoluidine
1
m-Nitro-p-toluidine
p-Nitro-o-toluidine
8, 62, 87, 105, 150, X,X
62
763, 361
740,261
$737, 766
$1.00
5-Nitro-2-toluidine
172
Nitrotoluidine sulfone
172 - --
Nitroxylene
45 62, 150
560, 237
87
Oxalyl-p-nitroaniline
62
62 150 172
Oxalvl-p-phenylenediamine
62,87 - --
150
Penta anthramide
62,87,150 - - ---
108, 805
Pentachlorobenzene
108
Pentachlorophenol and sodium salt
60 149
o-Phenefidine
62 149
p-Phenetidine
62 149 222 X
Phenol:
Natural.
8,22, 127, 187, 188, X._
22 60 149, X
23, 967, 560
72, 187, 520
23,625,053
2, 150, 551
.09
Synthetic
Phenol sulfonic acid
X - - -
Phenyl acetic acid and ester
X
Phenyl-2-aniino-5-naphthol-7-sulfonicacid
(phenyl J acid).
Phenyl-2-amino-8-naphthol-6-sulfonicacid
(phenyl gamma acid).
p-Phenylammonium naphtholate
6,45,62,87,150,172.^.
6,45,62,150,172
X
137, 137
51, 389
6, 8, 45, 62, 87, 150,
179.
8, 150,237, 240
822, 604
p-Phenylenediamine
45 62, 87
65, 532
45 87
62
Phenyl ethanolamine
37
Pheny lethyl malonic diethyl ester
Phenylgylcine, sodium salt
1,25, X
60,62, 150
319, 537
4,195,886
16 UNITED STATES TARIFF COMMISSION
Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
Phenylhiydrazine and hydrocliloride
60,69, 78,87
Pounds
Pounds
Phenylliydrazine sulfonic acid . . .
172 . -
Phenylliydrazine-2-sulfonic acid
87.
Plaeny Ihy rdazine-3-sulf()nic acid
87
Phenylhydrazine-4-sulfonic acid
87,172,219..
Phenylmetliylpyrazolone
8, 60, 62, 172, X. ..
l-PlienyI-3-methyl-5-pyrazolone (devel-
6,62, 172
oper Z).
Phenylmethylpyrazolone-3-sulfonic acid. .
87
PhenylnietIiylpyrazoIone-4-suIfonieacid..
87
Phenyl-l-naphthvlamine-8-sulfonic acid _
8,45, 62,87, 150
62, X
255, 423
Phtlialamide ._. . ... ..
Phthalic acid and anhydride. -- .. .
7, 22, 62, 149, 150, 186.
62 ..
57, 946, 415
28,346,067
$3,899,151
$0.14
PhthaloiJitrile
Phthalyl ciiloride
149.
a-Picoline
22 .
Picoline (beta, gamma)
22
Picramic acid and salt _
8,62. 150.
62, 108, 149
112,656
82, 564
83, 951
54, 725
.65
Piperidine .
Primuline, base...
45,87, 150
Primuline sulfonic acid .
87, 167
Propiophenoiie .
X
Pyrazol anthrone . . .
62, 87
Pyrazolone
6 -
Pyrazolone T
6
Pyridine, refined
22, 87, 187
■Quinaldine (see 2-Methyl quinoline).
Quinaldine yellow, base .
150.
Quinizarin sulfonic acid
6 .
Quinoline
22 ...
Quinolinic acid
X . .
Red KB, base .
62,87
Rpsoccinol, tech
62, 154, X
/3-Resorcylic acid
X
Rhoduline acid (see 5,5'-Dihydroxy-7,7'-
disulfonic-2,2'-dinaphthylamine).
Salicylic acid, tech..
60,62
Salicylic anilide (Shirlan)
62
SchaelTer's acid (see 2-Naphthol-6-sul-
fonicacid).
Silver salt (see Anthraquinone-2-sodium
sulfonate).
Sodium naphthionate
62
Sodium oxyethane sulfonate.- -_. .
87 - -
Sodium pentaehlorophenate. .
60
Sodium succinate
137
Sodium tetrachlorophenate
60
Sodium trichlorophenate
60
Sodium xylene sulfonate
149
Succinic acid and anhydride
150, X
Sulfanilic acid and salt
6,8,45,78,150,237-...
62
1,941,126
o-Sulfobenzaldehyde
p-Sulfo-o-benzoyl benzoic acid (sulfo BB
acid).
l-Sulfo-S-nitroanthraquinone
62
62
Sulfophenvlmethvlpyrazolone
45, 62, 87, 172
20,417
Tetraaminoditolylmethane
150
1,4,5,8-Tetrachloroanthraquinone
62,87,150
34, 419
Tetrachlorobenzene .
60
Tetraethyldiaminobenzhydrol
87, 139
Tetraethy Idiaminobenzophenone (ethyl
62, 65, 105, 150
ketone) .
Tetraethyldiaminodiphenvlmethane
8, 139
Tetramethyldiaminobenzhydrol (Mich-
62,139
ler's hydrol).
Tetramethy Idiaminobenzophenone
(Michler's ketone).
62, 65, 87, 105
131,653
716, 714
62,65,139,150
150
Tetramethyldiaminodiphenylmethane
sulfonate.
Thioaniline
8, 150
150
87
Thiogly collie acid.
172
Tolazine, base
45, 150
Tolidine and salts ......
45,62, 150
353, 709
19, 849
Tolidine disulfonie acid
6,45,87,172. ---.
149
p-Toluene sulfamide
149—
::::;::::::r:::::::::
SYNTHETIC ORGANIC CHEMICALS 17
'Table 7. — Coal-tar intermediates: United States production and sales in 1940 — Con.
Manufacturers' iden-
tification numbers
(according to list
on p. 61)
Produc-
tion
Sales
Name of intermediate
Quantity
Value
Unit
value
•p-Tolucne sulfoehloride
149.x
Pounds
Pounds
p-Tolueue sulfonic acid
149,X
p-Toluene sulfonic acid ethyl ester
237
Toluidine _. .
8
o-Toluidine -.- . -
8,62,150
m-Toluidine
62
p-ToIuidine
62,150 . . .
o-Toluidine omega methane sulfonic acid. .
6
«-Toluidino omesa sulfonic acid, . .
150
4-To)uidine-2-sulfanilid . .
87
Toluidine sulfoehloride- - - ...
172
2-Toluidine-4-sulfo-dimcthylamine _.
87
o-Toluidine sulfonic acid . _.
8,150
o-Toluidine-m-sulfonicacid .
62,172
p-Toluidine sulfonic acid__. .
62,87,150
3-Toluidine-6-sulfonic acid
87
p-Tolyl-o-benzoic acid
8,62,87,150
8,45,62,87,150
8 .
502, 276
1, 081, 595
m-Tolylenediamine
p-Tolylenediaminc
332,214
$222, 760
$0.67
p-Tolvlenedianiine sulfate
8 .
m-Tolvlenediamine sulfonic acid
62,150
2,6-Tolylenediamine-4-sulfonic acid —
87 . -. -
Tolyl-l-naphthvlamine-8-sulfonic acid
8,62,87,150
44, 139
f (tolyl peri acid).
Trialkylphenvl phosphite
149
Tribromophenol
60 . -
Trichlorobenzene
60, 108, 149 .
2,498,791
2,618,291
171,828
.07
TricMorophenovy ethoxy ethyl chloride
60 .
62,150
2,4,6-Trinitroresorcin (styphnic acid)
X .
87
22, 60, X
87 --
m-Xvlene
62, X
Xylcnols
8, 22, 187, 188
45,62,150
6,62,150
6,150
m-Xylidine sulfonic acid-
6,62,150
Xylidine.ortho and para
Xylvl disulfide
6, 8, 150
108
Other intermediates
1, 62, X, X
Total intermediates:
For which individual statistics
474, 599, 293
331, 207, 606
175, 003, 450
140, 963, 988
18, 676, 547
27,751,672
.11
are shown.
For which individual statistics
.20
cannot be shown.
Grand total .. . .
805, 806, 899
315, 967, 438
46, 428, 219
.15
COAL-TAR DYES
Production of coal-tar dves in 1940 was 127,834,000 pounds, and
sales were 122,677,000 pounds valued at $76,432,000, or 62 cents per
pound. An increase of 96 percent in exports of coal-tar products un-
doubtedly contributed to the improvement in sales. Tlie output of
classified dyes amounted to 104,539,000 pounds, or 82 percent of the
total.
Production and sales of coal-tar dyes by classes of application dur-
ing 1939 and 1940 and average annual statistics for the period 1934-38
are shown in table 8 ; production and sales by types are shown in table 9.
A comparison of production and sales of dyes by classes of applica-
tion in 1940 and 1939 indicates only small changes. Direct dyes, the
largest single group, in 1940 accounted for 25.8 percent of the total
quantity produced. Sulfur dyes accounted for 16.9 percent; vat dyes
18
UNITED STATES TARIFF COJNIMISSION
other than indigo, 14.8 percent; and acid dyes, 13.5 percent. No other
single class accounted for more than 9 percent. Indigo dyes in 1940
comprise a smaller portion of the total dye production than formerly.
■ Food, drug, and cosmetic dyes, amounting to 559,057 pounds in
1940, were classified separately in that year for the first time.
The average value of all dyes increased from 61 cents in 1939 to 62
cents per pound in 1940.
Table 8. — Com-parison of United States production and sales of dyes, by classes of
application, average 1934-38, annually 1939 and 1940
Production
Class of application
Quantity (1,000 pounds)
Percent of total
1934-38
average
1939
1940
1934-38
average
1939
1940
Acetate silk - -
1,961
13, 849
1 1,077
5,149
25, 780
2,765
5,262
16, 619
29, 234
15, 378
13, 856
831
2,585
17, 700
3,318
6,415
31, 438
3,305
5,237
18, 651
30, 035
12,475
17, 560
1,506
2,548
17, 179
3,*" 29
6,926
32, 8' 3
3,883
6,957
21, 561
30, 076
11.133
18, 943
2,212
1.9
13.5
1.1
5.0
25.1
2.7
5.1
16.2
2.2
14.7
2.8
5.3
26.2
2.7
4.4
15.5
2.0
Acid - -
13.5
2.8
5.4
Direct
25.8
3.0
5.4
Sulfur -
16.9
Vat total
15.0
13.5
.9
10.4
14.6
1.2
8.7
(6) other .- ■_
14.8
1.7
Total
102, 527
120, 190
127, 834
100.0
100.0
100.0
Sales
Class of applicati n
Quantity (1,000 pounds)
Percent of total
1934-38
average
1939
1940
1934-38
average
1939
1940
Acetate silk .
1,716
13, 501
1996
4,878
25, 261
2,612
5,080
17, 070
29, 204
15,510
13, 694
819
2,402
17,063
3,145
5,976
30, 421
3,278
5,325
17,311
28, 135
11,949
16, 186
1,438
2,481
15, 937
3,533
6,235
30, 626
3,538
6,230
21,016
31,038
12, 009
19, 029
2,043
1.7
13.4
1.0
4.8
25.0
2.6
5.0
16.9
2.1
14.9
2.7
5.2
26.6
2.9
4.7
15.1
2.0
13.0
2.9
Basic
5.1
Direct ---
25.0
2.8
Mordant and chrome
5.1
Sulfur -- -
17.1
Vat total
15.3
13.5
.8
10.4
14.1
1.3
9.8
(6) Other
15.5
Unclassified
1.7
Total
101, 137
114,494
122, 677
100.0
100.0
100.0
Value (1,000 dollars)
Percent of to
tal
Acetate silk .
1,934
10, 509
1 1,664
4,421
13, 685
1, 794
2,481
3,880
14, 107
2,609
11,498
752
2,211
13,296
4,708
5, 593
16, 649
2,298
2,665
4,657
16, 789
1,843
14, 946
1,358
2,293
13, 072
5,164
5,707
17, 198
2,675
3,286
5,348
19,810
1,880
17,930
1,879
3.5
19.0
3.0
8.0
24.8
3.3
4.5
7.0
3.2
18.9
6.7
8.0
23.7
3.3
3.8
6.6
3.0
Acid
17.1
6.7
7.5
Direct .
22.5
3.5
4.3
Sulfur
7.0
Vat total
4.7
20.8
1.4
2.6
21.3
1.9
2.5
(6) Other
23.4
2.5
Total -'-
55, 227
70, 224
76, 432
100.0
100.0
100.0
1 2-year average.
SYNTHETIC ORGANIC CHEMICALS
19
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940
[The numbers in the third column refer to the numbered alphabetical list of manufacturers printed on page
61. An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the fourth, fifth, and sixth columns indicate that the statistics
of production or sales cannot be published without revealing information with regard to individual firms.
The figures thus concealed, however, are included in the total.]
Name of dye
Classified Dyes
NITROSO DYES
Fast printing green
Naphthol green
NITRO DYES
Naphthol yellow S .__
Amido yellow E
AZO DYES
Monoazo dyes
Acid yellow G
Spirit yellow R_
Butter yellow
Chrysoidine Y
Chrysoidine R _
Oil orange
Sudani
Croceine orange
Orange G
Chromotrope 2R
Fast acid fuchsine B
Amido naphthol red O
Brilliant sulphon red B__.
Chrome yellow 2G
Chrome yellow R
Mordant yellow 4G
Victoria violet ..-
Lanafuchsine
Chromotrope 6B
Amido naphthol red 6B...
Toluidine red RL
Sudan II
Ponceau 2R-..
Double ponceau R
Bordeaux B
Chromotrope 10B_.
Chrome brown R
Palatine chrome green G..
Chromate brown B
Acid chrome brown R
Chrome flavine G
Oil scarlet
Azo cosine Q
Eosamine G
Chrome yellow 5G
Direct pink E2GN
Direct pink
Direct pink EBN
Metanil yellow
Methyl orange
Azo flavine 2R
Azo yellow
Resorcin yellow
Orange II
Orange R.-
Lake red 4B
Lake red C
Acid chrome brown B
Acid chrome garnet R
Chrome violet R
Chrome black PV
Acid alizarin black R
Acid brown R
416161—41 4
Manufacturers'
identification num-
bers (according to
list on p. 61)
8,45.
87...
6,8, 87
6, 8, 55, 80, 87, 150.
6, 8, 55, 62, 80, 87,
150.
8, 55, 87, 150, 154_.
8,87, 150, 154
55
6,8,55,62,87,150..
45, 150
8, 45, 62, 87, 150_...
150
6, 150
6, 8, 45, 55, 62, 87,
150.
247
6, 8, 45, 87
6,8,45,87
6,45,87, 150
8, 45, 62, 87, 150—.
X
45, 150
6,8,45,62,87,150-.
209
6,8,55,80,87,150-
8, 45, 62, 87, 150,
154.
62,87
8,45,87, 150
62
45,87.
87
8,41, 179
62
41,87
80
62,87
62
45
62
87, 150
62
6,45,62,87,150---.
62
87
6,87, 150
8,87, 150
8, 45, 87, 105, 150,
154.
8,45,62, 150
45, 62, 150
150
45, 87, 150.
45, 150
87, 150
87
87
Produc-
tion
Pounds
69, 389
420, 740
109. 188
313, 353
' 154,576
402, 771
224, 119
67,418
265, 580
87, 592
306, 291
413, 986
'140,' 986
1, 743, 652
226, 739
Sales
Quantity
Pounds
58, 883
397, 110
142,512
295, 383
'i82,'936
394, 638
167, 127
73, 065
214, 556
88, 667
294, 247
370, 509
'iio.'gig
541, 693
47, 098
'i,'544,'248
223, 881
Value
$47, 754
144, 581
46, 810
138, 312
"80,'3i7
131, 687
79, 489
38, 803
93, 448
58, 340
128, 351
152, 685
"so,' 840
298, 569
27, 853
'4i5,'400
65, 100
59, 099
Unit
value
$0.81
.33
.55
20
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
Quantity
^'■alue
Classified i)j^e«— Continued
Azo DYES— continued
Monoazo dyes— Continued
Fast red A
Azo rubine
Fast red VR
Croceine scarlet 3BX.
Amaranth
Cochineal red
Lake red R ---
Mordant yellow
Chrome yellow RN...
Chrome blue black B_
Chrome blue black U .
Chrome black T
Chrome black A
Fast acid blue R
Fast acid blue B
Lake red D
Chrome red B
Eriochrome flavine A.
Direct pink R
Disazo dyes
Resorcin brown B .
Resorcin dark brown.
Acid chrome brown O.
Acid black lOB -..
Acid dark green A..
Cloth red R
Brilliant croceine
Cloth red 3G
Sudan IV
Cloth red 2B
Neutral gray G
Milling orange Q
Cloth scarlet G
Direct fast red 8BL.
Scarlet EC.
Fast cyanine G
Fast cyanine 5R
Naphthalene acid black 4B
Acid black B..
Chrome black F
Chrome blue green B
Fast acid black N2B
Fast acid black F...
Fast cyanine black B
Naphthylamine black D
Developed blue NA
Developed blue B
Direct fast heliotrope 2B
Developed brilliant orange GR.
Diamine brilliant violet B.
Direct fast scarlet
Direct fast scarlet 4BS
Bismarck brown
Bismarck brown 2R
Acid chrome black F
Chrome, fast yellow C
MillingredG
Direct fast yellow 5GL
Benzo fast yellow 4QL
Para fast brown GR
Direct fast pink 2BL
Paper yellow ,
Chrysophenine O
Congo red ^
Congo corinth Q
8, 45, 62, 87, 150.
6, 45, 62, 87, 150.
8,45,87,150..--
45
6,45,150
8,45,87,150.--.
209
45,87,150
6,45,150
45,87,150
45,62.87,150--
45,87,150
45,87,150.179..
8,62,87,150.---
62,87,150
209
8, 45, 62, 87, 150.
62,87, 150, X._.
62,167.
Pounds
219,818
164, 689
127,612
Pounds
186, 893
160, 624
121,570
$92, 523
82, 952
60,234
111,691
96, 200
46, 349
39, 567
16, 474
1, 300, 780
95, 423
136, 338
27, 484
1, 170, 438
652, 849
96, 918
120, 086
25, 122
330, 117
219,316
41,237
63, 258
16, 433
65, 325
137, 394
71,642
37, 598
6, 8, 45, 02, 87, 150,
247.
6, 8, 45, 55, 87, 150.
247
62
352,031
84, 143
373, 629
85, 625
200, 722
59, 529
6,8,45,62,87,150,
247.
45,55,62
45
1, 545, 924
1, 457, 329
570, 865
8,4,5,62,87,150
8,62
45, 55, 62, 80, 87, 150
6,45,87,150..
41,62
6,8,45,87
6,8,45,217
6, 8, 28, 41, 62, 87,
150, 172, 247.
6,87,150...
8,41,45,87,150
8,62,87,150
87
448, 123
375, 594
314, 649
87, 002
81, 332
47, 671
36, 416
190, 322
58, 474
478, 128
32, 856
2,350
154, 735
13, 519
71,672
532, 058
15, 599
2,083
317,961
12, 198
44, 631
320, 040
150.
45. 62, 87, 150-
8,62
45,62,87
87
171,949
179, 480
87, 489
8, 41, 62, 87, 150.
133, 998
105, 517
45,62,87,150....
45.62,87,150
62,87
41,62,87,172....
6,87
6,41,45,62,87,150..
45 --
8,62,87,150
8,45,62,87,150-
87
837,016
750, 036
770, 455
89, 466
807, 834
109,811
794, 687
42. 647
300, 635
41
8. 62, 87-
28,41.--
87
82, 261
83, 559
124, 222
8.62,87,150.-
8,62,87,1.50
62,87.150
8,62,150
6, 8, 45, 62, 87, 150,
247.
21. 682
222, 058
30. 178
206, 690
56, 059
155, 983
363, 482
386, 731
259, 232
SYNTHETIC ORGANIC CHEMICALS
21
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
D
Quantity
Value
Unit
value
376
Classified Dj/e«— Continued
AZO DYE3— continued
Disazo dyes— Continued
45,X ...
Pounds
Pounds
377
150
382
6,8,45,87,150,247..
45
236, 926
182, 358
$163,911
$0. 90
385
387
45,62,150
394
Direct violet N
6,8,45,62,87, 150.- _
6
92, 604
84, 878
81, 271
.96
395
401
Developed black BHN
6, 8, 28, 45, 62, 87,
150, 247.
150
2, 741, 955
2, 458, 443
800, 747
.33
405
406
Direct blue 2B
6, 8, 45, 55, 62, 87,
150. 247.
62 ....
1, 464, 023
1, 345, 330
297, 364
.22
409
410
62
411
45, 150, 247
415
Direct oranse R .
45,62,87,150
6, 8, 28, 45, 62, 87,
150, 247.
6, 8, 45, 62, 87, 150,
247.
8,247
121, 385
420. 663
506, 958
115.0.35
411,434
496, 877
43.010
256, 058
239, 835
.37
419
Direct fast red F._. ... . .
.62
420
Direct brown M _.
.48
423
430
Polarred G .
41, 45, 62, 87, 150,
247.
62
168, 785
128, 656
105, 302
.82
431
436
Direct brilliant red 8B
45
441
87
443
Milling red 2Q
6, 8, 45
446
6, 150
448
45,62,150
840, 517
816, 354
432, 736
.53
464
Direct blue R
62
468
Direct mauve B
150
471
Direct blue 3R
45, 150
472
Direct blue BX
45,62,150
33, 660
215,038
21, 549
195, 589
7,461
50, 596
.35
477
Direct blue 3B
45,55,62,150
6,45, 150
.26
478
487
Acid milling red B . ...
6,8,41,45,87, 172. _.
45,62,150,247
6, 45, 62, 87, 150, 247_
62
61,321
24, 988
200, 194
49, 557
23. 740
187, 079
40, 615
20, 907
104, 830
.82
495
Benzopurpurine lOB ..
.88
502
Direct azurine G _..
.56
508
512
Direct blue RW
6.28,45,62,87,150.-
150
161, 936
136, 973
105, 510
.77
515
516
87...
518
Direct pure blue 6B ...
6,28,45.62,87,150-.
8,28.45,62,87,150-.
6.62
685, 805
100, 499
665, 938
104, 889
514, 309
49, 396
.77
520
Trisazo dyes
Direct pure blue
.47
533
Direct fast blue FR
534
87
539
Direct fast black FF
8,45,62,87,150
87
263, 667
302, 408
146, 946
.49
544
Pluto black 5BS
552
Diazo black RS
62, 150
561
Direct brown BT
6, 28, 62, 87, 150,
172, 247, X.
45
214, 704
189, 045
227, 115
1.20'
567
Direct fast blue R
576
Direct fast blue B
45, 62, 150
581
Direct black EW
8,45,62,87,150,247-
8,45,62,87,150,247-
6, 8, 45, 62, 87, 150,
247.
8, 45, 62, 87, 150, 247-
62
8, 482. 298
603, 441
229, 345
8, 016. 991
688, 426
164, 584
107, 157
2, 057, 738
197, 823
57, 225
31, 771
.26
582
Direct black RX_
.29
583
Direct green ET . .
.35
589
Chloramine green B
.30
590
Direct steel blue G
Direct green B
593
6, 8. 45, 62, 87, 150,
179, 247.
8,45,62,150,247-.--
87
607, 597
104, 438
634, 914
112, 768
225, 140
45, 950
.35
594
595
Direct green G
.41
596
Direct brown 3G0
6, 8, 45, 62, 87, 150,
247.
6, 45, 62, 87, 150, 167.
62
923, 399
124, 585
905, 417
133, 871
299, 543
63, 084
.33
598
Congo brown G . . . .
.47
601
Congo brown R
22
UNITED STATES TARIFF COMMISSION
Table 9.
-Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Manufacturers'
identification num-
bers (accordinc to
list on p. 61)
Produc-
tion
Sales
5 X
O O)
Quantity
Value
Unit
value
606
Classified Dyes— Continued
Azo DYES— continued
Tetrakisazo dyes
Direct brown G
8,87,247
Pounds
13, 056
Pounds
16, 214
$13. 806
$0 85
Total classified azo dyes .
40, 386, 642
15,314,635
37, 669, 619
14, 160, 408
16, 945, 254
15, 413, 389
45
Total unclassified azo dyes .
1 09
Total azo dyes.--
55, 701, 277
51,830,027
32, 358, 643
62
STILBENE DYES
Direct yellow R .
8,45,62,87,150
8,45,62,87,150
8,62,87
6?n
434, 538
130, 862
423, 0%
146, 727
192. 951
97, 622
46
621
622
Chloraminp orange Q
Stilbene yellow . _-.
.67
628
Diphenyl catechine G
150
631
Direct chrysoine G
Total stilbene dyes i
45
1, 017, 379
1, 025, 773
676, 239
.66
PYRAZOLONE DYES
Fast light yellow 2G
62,87,150,172
636
639
Fast light yellow _ - --
6, 41, 45, 62, 87, 150,
172.
6, 8, 28, 87, 105, 150,
172.
87..._ ..-
335, 576
573, 785
252, 502
551,311
225, 110
362, 513
89
640
Tartrazine, .-- .-
.66
647
Dianil yellow 3G
651
Pigment fast yellow G-__
Chrome red B. ._ -. _ .
87
652
8, 41, 45, 62, 87, 150 .
6,160,172
156, 543
20, 657
140, 942
20, 103
122, 586
24, 653
.87
653
Pyrazol orange G
Developed fast yellow 2Q
1.23
654
62
Total pyrazolone dyes ' ..
1, 218, 593
1, 086, 377
906, 185
.83
KETONIMINE DYES
Auramine
TRIPHENYLMETHANE AND DIPHENYL-
NAPIITHYLMETHANE DYES
Malachite green
Rhoduline blue 60
8,62,139,150
8,65,139,150
6.5,87,105,150-
8,65,139
655
657
658
1, 122, 294
351, 808
10, 235
1, 108, 724
317, 770
899, 501
346, 834
.81
1.09
66?
Brilliant green
Setocyanine-
Acid green B
Fast acid green B
Acid light green
Acid glaucine blue
Para fuchsine --
77, 112
106, 973
1.39
663
87
666
667
8,45,62,87,150
8, 87, 150 -
87, 915
28, 523
85, 965
34, 840
61,006
77, 573
.71
2.23
670
62,87 .--
671
62,87,105,150
8, 154, X
478, 568
676
677
Magenta
Methyl violet and base
8,45, 154, X
680
8, 62, 65, 87, 107, 150,
X.
62, 65, 87, 105, 150 - -
1, 321, 677
1,097,669
680, 927
.62
681
Crystal violet
Ethyl violet
682
62,87
689
Spirit blue 2B.
Fast green bluish
87
6P1
6
696
Fast acid violet lOB .
62, 139
698
699
Acid violet
Acid fast violet BG -
8,41,45,62,87,150-.
150
243, 019
231,153
217, 173
.94
703
Alkali blue 6B
Methyl blue
Mothvl cotton blue
87, 154
705
154 --
706
8,154
707
Soluble blue
8,87,X
59, 186
108, 579
1.83
712
Patent blue
Patent blue A. _
87,150 - .
714
8,87.150
62,87, 150, X
87, 150, X
62
97, 240
153, 263
23, 021
720
Eriochrome azurol B
123, 469
195, 178
1.58
722
Eriochrome cyanine R.
724
Aurine
Victoria blue R
728
62,87,105
2,332
4,956
2.13
729
Victoria blue B
62,87,105,150
' Includes unclassiCed dyes of this group.
SYNTHETIC ORGANIC CHEMICALS
23
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
H
Name of dye
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
•3 ■a
O
Quantity
Value
Unit
value
735
Classified Dj/es— Continued
TKIPHENYLM ETHANE AND DIPHENYL-
NAPHTHYLMETHANE DYES— COn.
Naphthalene green V -.. ..
62,139,150.
Pounds
95. 593
139, 961
Pounds
737
8,62,87
148, 155
$74, 102
$0.50
Total triphenylraethane and
diphenylnaphthylmethane
dyes.'
XANTHENE DYES
Rhodamine B --.
4, 663, 540
3, 943, 527
4, 271, 972
1 08
62
749
749
Rhodamine B cone
62,139
752
Rhodamine 6G cone. -- _ -
62,139
758
Fast acid violet A2R
X ^
766
8, 105, 154. X
6,8, 105, 150, 154, X.
8, 105, 117, 154, X__
8, 154 -
4,315
62, 143
356, 168
4,686
50, 53&
8,759
70, 503
I 87
768
768
Eosino
Tetrabromofluorescein (bromo acid).
Erythrosine B . .- _ .. .
1.39
773
774
Phloxine B _.-
151
779
Rose bengale B .-
8, 154-
788
ACRIDINE DYES
Acridine orange A
87, 172 .
793
8,45,62,87,150,172.
172 ---
104, 127
133, 475
96, 194
72
794
Phosphine 2Q .
797
Euchrysine -
87, 172
801
QUIXOLINE DYES
Quinoline yellow. . .
62, 139, 150
802
Quinoline yellow KT ._ .. .
139
Total quinoline dyes 1 . .
273, 675
208, 729
342, 038
1 64
THTAZOLE DYFS
Primuline - -. -- -.-
45,62, 150
812
813
Direct pure yellow M_
62 . -—
814
815
Direct fast yellow
Thioflavine T . _-
45, 62, 87, 150, 167..
62 _
398, 258
335,046
306, 778
.92
810
Direct brilliant flavine S -.
167
Total thiazole dyes '
971, 631
908, 010
740, 929
82
AZINE DYES
Woolfast blue GL ..
87, 150, X
8,62,87, 150
62, 87
833
196, 508
282, 035
172, 068
271, 354
255, 559
336, 546
1 49
841
1 24
853
Acid cyanine BF
860
8, 87, 150
75, 342
41, 746
1, 324, 849
1,178,941
79, 552
36, 91 1
1, 261, 519
1, 200, 801
27, 626
24. 505
355, 006
436, 093
.35
861
Induline (water-soluble) _ .
8, 87, 150
.66
864
8, 87, 150 .
.28
865
Nigrosine (water-soluble) _
8,87, 150 -
.36
871
ANILINE RLACK AND ALLIED DYES
Diphenvl black base _- -
S7
873
New fast gray
8, 172 — -
875
Fur black .
8, 87
883
OX.AZINE DYES
8, 248
909
Cotton blue
6,8,150 -. —1 61. 102J 68.054
80, 679
1.19
913
Nile blue BX
87
1—
1 Includes unclassified dyes of this group.
24
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States -production and sales, by types, in 1940-
Continued
H
Name of dye
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
922
Classified i)2/e«— Continued
THIAZINE DYE3
Methylene blue _ - -
8, 62, 65, 87, 150—.
8, 150
Pounds
542,232
■Pounds
489, 286
$437, 130
$0.89
924
Methylene green B . . ._
927
New methylene blue -- _ -
8
'931
Brilliant chrome blue
87. -
969
SULFIDE DVE3
62,87
(2)
(2)
14, 633, 496
2,469,214
1,806,099
969, 613
623, 333
251, 267
76, 891
239, 073
491, 689
(2)
(2)
14, 603, 084
2, 346, 369
1, 797, 812
774, 303
497, 950
231, 039
75, 270
247, 028
443, 340
(2)
(2)
2, 499, 843
1, 185, 120
508, 274
582, 111
241,743
68, 810
21, 534
72. 969
167, 889
971
62,87
8, 20, 62, 87, 150,
212.
8,20,45,62,87,112,
150, 212.
8, 20, 45, 56, 62, 87,
112, 150, 212.
8,20,62,87,112,150.
8,20,62,87.150.--.
8, 20. 56, 62, 87, 112,
150. 212.
45,62,87,150
8,20,45,62,87, 112 .
8,20,45,62,87,112,
150, 212.
Sulfur black - -
.17
Sulfur blue
50
.28
Sulfur green - _ . ..
75
49
Sulfur olive --
30
.29
30
Sulfur yellow - -
.38
Total sulfide dyes
21.560,675
21.016,195
5, 348, 323
.25
1027
ANTIIRAQUINONE DYES
8,87,150
1034
6,8,150
46, 942
74, 151
1.58
1035
150,248
1040
150 -
1043
87
1053
Acid alizarin blue SE ...
8,62, 87, 150, X._.
50,086
i05, 140
2 10
1054
Acid alizarin blue B .
8, 17, 41, 62, 87, 150,
248, X.
17.
1060
Anthracene blue SWGG
634, 669
607, 397
916, 813
1.51
1062
Anthracene blue WR ...... ._ ..
41,87,150
1063
Anthracene blue WRS .
17.
1073
17,62
1075
62,87
1076
Cyananthrol R
62
1078
6,8,17,41,62,87,150
248.
17.62 .
, 235, 364
220, 503
372, 409
1.69
1080
Acid anthraquinonc violet B .
1085
Anthraquinone blue black B... . .
6, 8, 41, 87, 150, 179,
248.
62 87,150 . ..
423, 252
47, 322
353, 612
48, 565
517, 896
155, 739
1.46
1088
Acid anthraquinone blue B
3 21
1091
87
Total anthraquinone dyes '
ANTHRAQUINONE VAT DYES
(SINGLE strength)
Anthraquinone vat yellow GO (12'/'2
percent).
Anthraquinone vat golden orange G
(12J'2 percent).
Anthraquinonc vat golden orange R
02? 2 percent).
Anthracjuinone vat scarlet GS (16%
jercent).
Anthraquinone vat dark blue BO
(25 percent).
Anthraquinone vat jade green (6 per-
cent).
Anthraquinone vat green B and
black B (1232 percent).
Anthraquinone vat violet R (25 per-
cent) .
Anthraquinone vat violet 2R (12}^
percent).
Anthraquinone vat violet B (25 per-
cent).
8,62,87
3, 421, 174
3, 191, 144
3. 609. 253
1.13
1095
696, 687
320, 771
711,550
331, 634
656, 219
440, 630
.92
1096
1097
8,62,87,150...
62, 150
1.33
1098
8,87,150 ■-
1099
1101
8,62,87,150,167....
62 ..
265, 561
253, 786
288,874
1.14
1102
1103
8,62,87,150,167....
87 ..
641, 657
580, 293
. 233,205
.41
1104
1106
6,62,87,150
87
286,555
286,952
462, 383
1.61
1 Includes unclassified dyes of this group.
2 Totals not included under sulfide dyes. In dyes classified by method of application, this dye Is included
with the vat dyes.
SYNTHETIC ORGANIC CHEMICALS
25
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
o <o
O
Name of dye
Manufacturers'
identification num-
bers (accordincr to
list on p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
3106
Classified Dyes— Continued
ANTHRAQUINONE VAT DYES
(single stkength)— continued
Anthraquinone vat blue RS (10 per-
cent).
Anthraquinone vat blue 3G (10 per-
cent).
Anthraquinone vat blue QCD (83-^
percent).
Anthraquinone vat blue BCS (20
percent).
Anthraquinone vat yellow G (12}-^
percent).
Anthraquinone vat brown B (22 per-
cent).
Anthraquinone vat pinli R (123^
percent).
Anthraquinone vat yellow R (12>2
percent).
Anthraquinone vat red FF, extra
(123 2 percent).
Anthraquinone vat brilliant violet
R (1232 percent).
Anthraquinone vat olive R (123^ per-
cent).
Anthraquinone vat brown R (123^2
percent) .
Anthraquinone vat brown G (1232
percent).
Anthraquinone vat red violet RRN
(1232 percent).
Anthraquinone vat red BN, extra
(12>2 percent).
Anthraquinone vat violet BN (25
percent).
Anthraquinone vat yellow R (123^^
percent).
Anthraquinone vat blue green B
(123/^ percent).
INDIGOID AND THIOINDIGOID DYES
Indigo, synthetic (20 percent)
Indigo white (20 percent)
Indigo extract -.- - . .-.
8,62,87
Pounds
Pounds
1109
62
1113
62,87,150
776, 181
1, 359, 155
253, 244
841, 820
1, 327, 088
253, 868
$479, 259
1,411,191
244, 212
$0.57
1.06
96
1114
1118
8,62,87,150
62, 87, 150 .
1120
62,150
11?^
87
1132
62
1133
62
1135
62 L
1150
62,87,150
1151
62,87,150
1151^
62,150..
llfil
62,87
1162
62,150
1163
62
1170
62,167
1173
167
1177
60, 62, 150.
11, 133, 161
12, 009, 307
1, 880, 128
.16
1178
150
1180
62,150
1183
Tribromindigo RB (20 percent)
Bromindigo blue 2BD (16 percent)-..
Vat blue 5B (20 percent)
Cibapink B (20 percent)
Vat red B (1232 percent)
Vat red 3B (20 percent)
60.150
1184
60,87,150
1180
60
1?07
60
1?\0
87
1212
8,60.62.87,150
8,62,87,144
60
261,305
415, 700
235, 563
434, 698
237, 823
418, 751
1.03
1217
Vat orange R (10 percent)...
.96
1?2S
Vat fast scarlet G (20 percent)
Vat red R (lO percent)
3229
60
FOOD, DRUG, AND COSMETIC DYES
Blue#l
23,150,241
6,950
67, 980
9.78
Blue #2
23,126,219
Green #1, #2, #3
23,150,241
Orange #1
Orange #2
23, 126, 150, 219, 241.
150
97, 091
87,542
186, 900
2.13
Red #2
23,126,150,219,241.
23,126.150,219
23,126,150,241
145,474
10, 740
135, 257
10,881
320, 570
158, 762
2 37
Red #3
Red#l,#4
Yellow #3, #4
14.59
66. 150
Yellow )!i5
Yellow #6
23,126,150,219,241.
23, 126, 150, 2X9, 241.
114,923
61,545
109, 718
60, 375
270, 995
138, 748
2.47
2 30
Total food, drug, and cosmetic
dyes
559, 057
518, 252
1,535,602
2.96
26
UNITED STATES TARIFF COMMISSION
Table 9. — -Coal-tar dyes: United States production and sales, by types, in 1940-
Continued
Name of dye
Classified Dyes — Continued
DRUG AND COSMETIC DYES
Black #1
Blue #1. #4. #6, #9
Brown #1 .
Gre('n#l,#5.#6.#7_.
Orange #1, #3, #4, #5, #8, #10, #11, #14,
#15 #17
Red #1, #2, #3, #5, #7, #8, #9, #10, #11,
#17, #18, #19, #20, #21, #22, #28, #29,
#30, #33, #37.
Violet #1, #2
Yellow #1, #5, #6, #7, #8, #10, #11
DRUG AND COSMETIC DYES, EXTERNAL
Blue#l
Green #1
Red #1, #3, #8, #10, #11, #13.
Yellow #1, #5
Total classified dyes-
Undassified Dyes
Acetate silk dyes, total
Black, AD, AS, AZ, B, BBN,
BDN, BO, BOD, BNF. BNS,
BZA,3B, DY,GFS,3G.3GNF,
J, NAZ, NBZ, NS, NSJ, NZD,
ONS, RB,III, IV, IVdbl.3
Blue 2B. G, 2Q, GGN, OR, R,
5RB, III, IV, XIII.
Bordeaux
Brilliant blue, B, 2G, R
Brilliant orange G
Brilliant red
Brown BR, Y
Direct blue S
Direct orange R
Direct red SB, YC
Direct sapphire blue G
Fast black B, BTN
Fast blue AF, B, 3BFU, FFR__.
Fast blue green B, BG
Fast Bordeau.x B
Fast brown 3R, 5R-
Fast navv blue B, BR
Fast pink B, FF3B
Fast red, 20
Fast red violet RN
Fast rubine B, 3B
Fast vollow G, GL, OR, 2R
Green blue II
llelidtrcipe I ---.
Light orange FSI
Navv blue B, BP cone, BX, R .
Orange BL, OF cone, QFN,
OR, JER, R, 2R, 3R, 4R,
SRC, extra, I, II, III.
Pink B, 3B, II
Pure blue BR, BR cone, BR
extra.
Pure vello w I, II
Red, "BR, 3B, DM, FSI, 20,
NB, R, RP, Y, I, III, V, VI-X,
VII, VIII.
Red violet R
Rubine B, O, IX
Saphirole blue FFO _
Scarlet, B, BN, BS, CSB, III...
Manufacturers'
identification num-
bers (according to
list on p. 61)
150.---. __.
126,150.-.-
150
126, 150, X.
126, 150, X.
117, 126, 150, X.
150, X._..-
126, 150, X.
150
150
150
126, 150.
6, 8, 4], 62, 80, 87,
150, 247, X.
6,62,87,150.
6,8,62,174,248.
41
62
62
Produc-
tion
Pounds
Sales
Quantity
Pounds
104, 539, 151 100, 793, 143
2, 548, 080
1, 246, 740
100, 755
41
8, X...
X
87
87
87
41
87
87
87
87, 248-
87
87
62, 87.-
6
6
6,8,62
6, 8, 62, 80, 87, 150,
174, 247.
6, 150.
6, 62..
6, 8, 62, 87, 150, 174.
62
6,62,80,247
41
6, 8, 41, 62, 80, 87,
150, 247.
97, 602
76, 720
23, 873
2, 481. 144
1, 230, 370
92, 365
Value
$51,429,918
2, 293, 2,54
698, 561
122, 975
Unit
value
$0.51
.92
.57
1.33
108, 467 108, 566
72, 509
23, 562
36, 057
34, 378
79, 642
28, 636
37, 566
1.00
^Includes developed black and cellitazole black.
SYNTHETIC ORGANIC CHEMICALS
27
Table 9. — Coal-tar dyes: United States -production and sales, by types, in 1940-
Continued
Name of dye
Manufacturers'
identification num-
bers (according: to
list on p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified Dyes — Continued
Acetate silk dyes — Continued.
Sky blue B
Turquoise G, MG
Violet, B, 4B, 6B, 6BA, CB, RL,
2R, 3R, 4R, II.4
Violet blue FSI
Yellow, F, FSI, G, GX, 20, 5G,
JT, VIII, IX, XI, XII, XIII.
Other
Acid alizarin green B
Acid anthracene brown PG, SWG..-
Acid anthracene yellow GR extra
Acid black AR, BR supra, SB, ORF,
GRF cone, 3G, J, RB, RYC, TL,
WA, 640, 773.
Acid blue, 2G, RS
Acid blue black BR, RC
Acid Bordeaux R
Acid brilliant blue 3B, 2R
Acid brilliant green lOG
Acid brilliant red BBA, 4BL, 5B, G.
Acid brown B, FN, MF, N, R
Acid ceresine
Acid chromal brown AEB
Acid chrome blue 2R, 2RA
Acid chrome blue black B
Acid fast black BBN _..
Acid fast blue B, BN, G, IB
Acid fast brown CGS
Acid fast light red BL cone... _.
Acid fast orange LW
Acid fast red BL, CY
Acid fast rubine BL
Acid fast yellow JY, N, RS
Acid flavine cone
Acid f uchsine 6B
Acid garnet GR cone
Acid golden yellow R cone
Acid green BL, S
Acid light red 4BL
Acid light rubine BL
Acid milling brown R supra
Acid milling yellow G, GN, 2GX, R.
Acid naphthol blue black
Acid navy FN
Acid navy blue cone, B cone, M4B.
Acid neutral red 3G extra cone
Acid neutral yellow GNS
Acid olive Q
Acid orange G, GS, R, 2R, 4R, 4RN,
SGS, YF.
Acid pink N
Acid red, GL, OA
Acid sapphire G
Acid scarlet G cone, 2R, Y
Acid spirit black
Acid spirit orange R
Acid spirit yellow G, 2R
Acid violet B, BS, RL, RNL, 2R,
2RX, ERR extra.
Acid wool blue BL
Acid yellow, OR, 2G, 5G, R
Alizarin blue GS
Alizarin direct blue A2G, AR
Alizarin fast blue RB
Alizarin fa'^t gray BBL
Alizarin aray DG
Alizarin L
Alizarin supra blue A, C
Alizarin supra skv R
Alkali fast green iOG
Amido naphthol brown 3G
Anthracene blue SWN
62
6.87
6, 41, 62, 87, 150,
248.
Pounds
Pounds
6, 8, 62, 80, 87, 150,
174.
X
22, 241
114,943
27, 306
'94,' 582
$50, 650
$1.85
100, 561
1.07
248
87
41
6, 55, 62, 87, 150,
247, X.
172, 179, X..
62, 179
X
6,62
62
6, 41, 62, 150-
8,87, 172
102, 422
52, 022
.58
8,203
4,805
5,106
6,001
6,760
1.25
1.32
45
45, 87
45
62
8, 62, 150.
62
41
8, 62.
6,8.
179.
41..
179.
172.
179.
62.-
87-
6...
8, 45, 62, 172.
45
247
8,62,247
6
6... .---
24,766
18, 271
.96
6, 8, 62, 87, 150,
172, X.
47, 000
39, 371
L25
28, 45, 172.
X
6, 172
8, 45, 62, 172, 179,
247.
62
8,45,172
150
94, 132
86, 620
.63
150.
87-
150.
6—
87.-
87..
87-
87.-
150-
• Includes purple and fast violet.
416161—41-
28
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Unclassified Di/ps— Continued
Anthracene chrome brown RL
Anthracene indieo blue N
Anthraquinone hUie BOA, 3G, SBF,
SWB, SWF, WSA.
Anthraquinone vat black 20, J, R_..
Anthraquinone vat black brown V_.
Anthraquinnne vat blue CLX,
OCL. GR, IBC, 04B, RCX.
Anthraquinone vat blue green B,
FFB, Y.
Anthraquinone vat Bordeaux ORR-
Anthraquinone vat brilliant orange
GR, RK.
Anthraquinone vat brilliant red B__.
Anthraquinone vat brilliant scarlet
BGN.
Anthraquinone vat brilliant violet
3B.
Anthraquinone vat brilliant yellow
4G.
Anthraquinone vat brown BR, CR,
NR, RR, VR.
Anthraquinone vat dark brown R...
Anthraquinone vat deep black RD..
Anthraquinone vat direct black, 3G,
RB.
Anthraquinone vat flavine GO
Anthraquinone vat golden orange 3Q,
YL.
Anthraquinone vat golden yellow
GK, GO.
Anthraquinone vat gray GD, M,
M3G, R, RL, 3R.
Anthraquinone vat green 2BL, IBW.
Anthraquinone vat khaki, GG
Anthraquinone vat navy blue, BN,
BRP, G,3G.
Anthraquinone vat olive G, GGL, T.
Anthrquinone vat olive green, B,
BA.
Anthraquinone vat pink B
Anthraquinone vat printing black B,
2B,TL.
Anthraquinone vat printing brown
TM suprafix.
Anthraquinone vat printing green
BG suprafix.
Anthraquinone vat red G2B
Anthraquinone vat red brown R
Anthraquinone vat red violet RRN_
Anthraquinone vat scarlet 3B, BBN
suprafix, GGN.
Anthraquinone vat violet FFBN
Artificial silk black, G, R, 2R
Azoanthreno dyes:
Black N..
Blue G
Blue green B
Clarets
Dark brown DW
Golden orange R
Green G
Navv BR, CW
R blue T/, S
Rcd3BW
Rubine B, S
Scarlet O, Y
Violet B
Yellows
Azo Bordeaux 2BL, 4BL, 7B cone.
Azo brown BY
Azo cosine 2B
Azo fast blue 2R
Azo fast orange G, GRN
Azo fast violet
Allanufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
248.
62....
8,150.
87.-..
62,87,150-.
62,87,150..
62.
62, 87, 150, 172.
62
87
62,87,150.
87.
8,62,87,150-
62,87
62,87,150
8,8,62,87
62,87...
6, 62, 87.
Pounds
170, 427
27, 369
957, 637
245, 035
62 _
150.
6_.
87
45, 87, 247.
X-.
X..
X-.
x_.
X_-
X--
X..
X..
X..
X..
X-.
X..
X..
x_.
172.
172.
62..
150.
87.-
150.
Sales
Quantity
Pounds
190, 896
979, 141
235, 461
Value
$259, 259
1, 084, 392
219, 020
Unit
value
1.36
1.11
.93
SYNTHETIC ORGANIC CHEMICALS
29
Table 9. — Coal-tar dyes: United States -production and sales, by types, in 1940 —
Continued
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
Name of dye
Quantity
Value
Unit
value
Unclassified J>2/e«— Continued
87
Pounds
Pounds
172
Azoic dyes and their components:
Total
3, 628, 561
3, 533, 150
$5, 163, 563
$1.46
Dyes:
Rapid fast:
Orange, G, RH. --
8,62,87,172
Red RH
62,87
Scarlet ILH
62,87
Rapidogene:
Black DM, MG
62,87
Black brown IT
87
Blue, BN, D, GN, MSG,
62,87,172
N, NR, R.
Bordeaux, MR, RN
62.87,172
37, 694
86, 068
2.28
Brown, GN, IB, IPT— .
87,172
Dark brown AR---
62
G, double
87
Golden yellow MRS, R,
62,87
3R.
Navy blue FFR, R
87
Orange G, R
62.87
Red,2B, FFG, FFR, G,
GS, M2B, R.
Red violet 2R
8,62,87,172
87
160, 831
179, 617
376, 690
2.10
Scarlet, FFG, FFR, R,
RBY, RS.
Yellow, FFGG, Q, GS,
8,62,87,172
62,87,172
81, 823
111, 675
88, 662
112, 172
191, 741
292. 784
2.16
2.61
2G.
Components:
Fast color bases:
Black LB
87
Blue B, 2B
84.87,172
Bordeaux FGP, GP,
GPR.
Garnet GBC, GC_
84, 87, 144, 172, X_..
87, 144, X -
19, 377
54,588
18, 381
52, 993
52, 851
42,806
2.88
.81
Orange GC-
87,X
Red B, D, GL, KB, TR.
84,87, 144, 172, X.-^
Scarlet A, C, R, RC
87, 144, 172, X
Fast color salts:
Black B -
150
Blue B, BN, 2B
84. 87, 144, 150, 172,
X.
84, 87, 144, 150,
172, X.
87, X, X
Bordeaux BD, GP, GPN.
Garnet GC, GBC
152, 261
52, 135
138, 361
62, 386
128, 261
40, 947
.93
.78
Orange FR, GC, GR.-_-
84, 87,150, X
Red AL, B, FR, F2G,
84, 87, 144, 150,
172, X.
84
410, 897
G, GL, 3G, 3GL, KB,
KBN,RC,RCN,TR.
Rubine FG
Scarlet G, GGN, 2G, R,
RL, RN.
Variamine blue BD, RT.
84, 87, 144, 150,
172, X.
87
462, 972
487, 212
309, 708
.04
Other -
87
Naphthols:
Naphthol AS _
6, 8, 87, 150
737, 146
703,044
711,239
1.01
Naphthol AS, BG
Naphthol AS, BO
Naphthol AS, BR
87
6,87,150 .
6, 62,87 . - .- - _
Naphthol AS, BS
Naphthol AS, BT
6, 87, 150
87
Naphthol AS, BZ
Naphthol AS, D
87 - -
6,87,150,172
87
35, 972
Naphthol AS, E .
Naphthol AS, EX.
87
Naphthol AS, G
87
Naphthol AS, MXA
87
Naphthol AS, OL .
87, 172
Naphthol AS, OP
172 . .
Naphthol AS, PH
87
Naphthol AS, RL
6,87 _--
Naphthol AS, SW . .
6, 87, 150 .
218, 648
Other
6,87
30
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940-
Continued
Kame of dve
Unclassified Di/e«— Continued
Azo oil black
Azo oil blue black B _
Azo orange ON, GR, OXA, QXCW,
RO, RNC, RS, 3RP.
Azo red 7BL
Azo scarlet G, RB, RP
Basic orange 3RN
Benzoform dves:
Blue BBL, 2Q
Blue green B
Orange FGL
Red7B, G
Rubine B
Violet 2B
Yellow 30
Brilliant acid blue 3B
Brilliant benzo violet B
Brilliant blue 5B
Brilliant indocyanine G
Brilliant milling blue B
Brilliant milling green B cone
Brilliant milling yellow 5G
Brilliant sulfo flavine FF
Brilliant wool blue BN, FFR, FFRS
extra, G extra.
Carbolan blue B
Chromate brilliant brown RL
Chromate brown, EB, EBR, EBS
cone.
Chromate red 2G . . _
Chrome black, 3G, NSE, P2B, SW.
Chrome black blue G
Chrome blue ATX, ECR
Chrome brilliant orange 2R
Chrome brown B, BC, ECS, SB,
EB, EBL, ECB, G, O, PG, RH
cone, 4RC.
Chrome fast red 2RL ._
Chrome garnet R
Chrome green B, CB, G
Chrome orange RL, 3R
Chrome red FG
Chrome verdon S.
Chrome violet B, FB
Chrome yellow, DS, 2G, 00 supra,
R, SW.
C i ba black .._
CibablueBR, 2B
Cloth red 2R, Y
Cotton black 3G
Croceine scailet FP cone
Developed black G, OB, OB extra,
OT, ZV cone.
Developed blue B, BR, BR extra,
5GL, fiO, RFW, 4RL.
Developed Bordeaux 2BL, 7B, 7B
cone, BGL, RB.
Developed brilliant green 3G
Developed brilliant orange G, QNX,
ORN, 2G.
Developed brilliant scarlet, 2BL,
5BL, RO.
Developed brown 6G, NR, R, 3RB,
3RN.
Developed fast black PG extra
Developed fast blue B. . __
Developed fast brown RK
Developed fast red 7BL
Developed fast violet BL
Developed fast yellow 2G, 3G
Developed garnet RD
Developed green BL, GW, 2GL
Developed indigo blue BRR, 4GL..
Developed orange, GR, R, RFW,
2R, 3R, WD.
Manufactur Ts'
identification num-
bers Caccording to
list on p. 61)
150.
150.
172.
172.
172.
62..
87..
87-.
87.-
87.-
87..
87..
87-.
150.
62-.
150-
87-
62, 87.
62
6
87
87, 150.
62
41
8, 41, 62, 248.
248
41,62,150.
87 ---
62
6, 8, 45, 62, 87, 150,
247.
62
41
45, 150-
62, 150-
87
8
41,87
8, 45, 62, 87, 150,
172.
60... --
45, 150.
150
6, 45r6'2V87,'i5b"-
6,45,62,150
6,41, 62, 87, 150- .
87,150-
87
41, 62, 87-
62,87..-.
62
45
62
41,62
62
41,87,150-
6
62
62,87....
6,62,150-
Produc-
tion
Pounds
146,327
358, 991
208, 912
301, 037
208, 719
Quantity
Pales
Value
Pounds
133, 165
20, 709
326, 989
126, 480
308, 194
198, 873
$103, 877
12,788
52,506
206, 167
250, 056
Unit
value
$0.78
.62
1.02
.67
1.26
SYNTHETIC ORGANIC CHEMICALS
31
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Manufacturers'
identification num-
bers faccording to
listen p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
Uncfassified Z)j/e«— Continued
Developed red BFW, 7BL, lOBL....
Developed rubine B
Developed scarlet A, AE, 2BL, FW,
GFW, R.
Developed skv blue B, 3GL
6,62,150
41,87
Pounds
17, 319
Pounds
18,020
$27, 458
$1.52
62,150
87
Developed violet BRD, 2R
6,62
Diamond green SS __
Diazophen red
87
8
Diazophen vellow
Direct black CW, 30, 3CiR, 50,
NOW, NR extra.
Direct blue A, 2B, 5B, FF. 2GN, 3G,
5G, NR.
Direct blue green CW
Direct Bordeaux B, 6B, 7B
8
45, 87, 160, 247
6, 62, 150, 174, 247..
150
109, 997
100, 809
98, 474
.98
6,87,150
191,149
152,914
.80
Direct brilliant blue BFL
150
Direct brilliant Bordeaux 6B
150
Direct brilliant cerise ._
8
Direct brilliant red 12B cone
Direct brilliant violet B, 4B. R
Direct brown CSW, CWR, FW,
GB, GR, K, N, R, RB, RY. VG..
Direct catechine, GS, G cone, 30
Direct chrome black blue B
Direct chrome blue black B
150
6,45 - ..
6, 8, 45, 55, 87, 150,
247, X
6, 62, 150
93, 981
165, 312
83, 776
197,644
53, 342
150, 131
.64
.67
87, X
150
8 ...
Direct copper blue BR, RRX, 3R...
Direct dark blue SR
Direct dark brown G
62,87
X
87
Direct fast black B, FOR, FTC, O,
L, L cone. VE.
Direct fast blue, FF, FEB, FEE,
4GL, 8GL, LBRR, LG, R, RL,
SRL.
Direct fast Bordeaux 6BL.-
6, 41, 45, 62, 87, 150,
247
6, 41, 45, 62, 87, 150..
87
482, 553
573, 946
439, 996
454, 509
274, 358
537, 430
.62
1.18
Direct fast brown BRL, 40L, LBR,
LG, L3R, R, 2RL, 4R, 3YL.
Direct fast gray BL, GL, 2GL, LR._
Direct fast light blue FF . ...
41,62,87,150
62, 87, 150
148, 888
31, 643
160, 433
36, 587
243, 843
68, 530
1.52
L87
45
Direct fast olive brown RL
Direct fast orange EG, ER, E3G, G,
GL, 20 cone, 2GL, 4G cone,
LGGL, L3R, L5G, L7G, RE,
4RL, 5RL, 6R, S.
Direct fast red 5BL, 8BLN, 8BLSW,
8BLW.
Direct fast rubine B cone, LB, 2B..
Direct fast turquoise 8GL
Direct fast turquoise blue LGL
Direct fast violet BB, BL
Direct fast yellow 4GL, 5GL, LR,
L5G, RL.
Direct gray BBC, G
Direct green G, GB, 5GSC, 2Y
Direct green black
6
8, 41, 62, 87, 112, 150.
6,41,45,150
290, 164
270, 810
196, 908
325, 727
255, 776
1.20
1.30
6,150
62
87
6,87
45,62,87,150. _
55, X
154, 251
135,814
238, 951
1.76
6, 8, 62
45- -
Direct indigo blue
6
Direct light yellow RL _
45
Direct navy G, R, 4R
6
Direct navy blue BF, BW, DB, R,
RY.
Direct orange B, 2G, R
8,62,150,247
6,45,87 .
91, 314
94, 564
8,339
67, 937
9,542
.72
1.14
Direct pure blue B .._ _._ . .
6
Direct reseda green
6
Direct rhoduline red B .
62
Direct royal blue . . __ ...
6
Direct rubine B, Q
6
Direct sapphire B- _
X
Direct scarlet G ._
6
Direct silk blue NR
87
Direct sky blue B
Direct speck dye red SW_,_ __
45
150
Direct violet BRL, BCW, 2B, 2R_.-
Direct violet black . .
6, 8, 150, 174
45
Direct viscose blue GS, RS
87
Fast acid black BR
87
Fast acid blue R, WF
87,150
32
imiTED STATES TARIFF COMMISSION
Table 9. — -Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dyo
Manufacturers'
identification num-
bers (according to
list on p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified Dyes— Continued
Fast acid Bordeaux B
Fast acid brown RG
Fast acid light red B
Fast acid orange RW
Fast acid red BBL, 3B, GO
Fast acid yellow GS, R
Fast black V
Fast blue GGN, 5RN
Fast chrome brown RB
Fast claret RN
Fast crimson R
Fast light red B, BL, 4B, GL
Fast light rubine BL
Fast light violet
Fast marine blue REN
Fast orange RN
Fast pink BN
Fast printing yellow Q
Fast red RN
Fast violet 3RN, 5RN
Fast wool violet B
Fast yellow ELN
Fluoroleum supra
Fluorol 50, 5GR
Formal blue 2B _ .
Formaldehyde black GRX
Formaldehyde red B
Formaldehyde scarlet Y
Formal fast black G
Formalide brown RD
Formalide deep blue R
Formanol black RW
Formyl black G
Formyl blue B
Formyl brown
Fur colors
Gas yellow
Hansa yellow G, 3R
Helio red RMT
Heliogen blue B, Q
Heliogen green O
ITydroform navy blue
Indamine navy blue 2B
Indigo vat blue B
Indigo vat brown, G
Indigo vat pink FB, FF
Indigo vat scarlet 2GN
Indigo vat yellow 8Q
Indocyanine B
Indophenol black
Indophenol blue black ... _ ..
Jet black APX-...
Lake blue G, 6G
Lake fast blue BL cone
Lake fast orange G
Lake fast yellow lOG
Lake orange OTP.
Lake pink RL . _ .
Lake red BP, 2B, CSP
Lake scarlet 2YL
Lake yellow O. PL
Leather brown 2R, 5RT
Levelling brown B
Lithol yellow G
Metalized azo gray Q. . ..
Milling black B
Milling fast garnet R
Milling fast red FF
Milling fast yellow 5GL cone
Milling navy blue 4B
Millins? rod B, B cone, R . .. .
Milling yellow 2GCW, 3G, O cone.
R, RG, XN
Monastra! fast blue B, G
Monastral fast green G
87
150-._.
45
45
87
87, 150.
62
87
172.-..
87
150 --_
87, 150-
150 -.-
248. ___
87
87
87
150-__.
87
87
150_-_-
87
62
87
41
28
45
45
45
247-...
247.-..
X
Pounds
Pounds
41-
62, 87.
87--..
87-...
87--..
167...
84
8,62, 150, X_-
8, 62, 144, 150-
150
62
87
X
X
62
62
62
62
62
62
150
62
62
62,87, 150
62,87
6
87
340, 640
538, 355
296, 188
498, 546
$321,854
519, 442
$1. 09
1.04
150
41
41
41
150
150, 172-
150, 172..
62
62
SYNTHETIC ORGANIC CHEMICALS
33
Table 9. — Coal-tar dyes: United States production and sales, by types, in 1940 —
Continued
Name of dye
Unclassified Dj/es— Continued
Mordant green SN
Naphthol navy blue M
Naphthylamine black V
Neutral blue G
Neutral brown RD, RX, 2RS
Neutral silk brown..
Neutral silk yellow CGA
Neutral silk yellow RX
Nigrosine base B, N, R, 2R -..
Oil blue
Oil bronze
Oil brown D, M, Y, #79, #102
Oil fast black
Oil fast blue B, R
Oil fast orange A cone.
Oil fast red M, Y
Oil fast yellow SO, EG
Oil green
Oil orange, soluble, RH, 2R, #30, #67.
Oil pink B
Oil red, soluble, EG, EGN, G, O,
OB, RO, #322.
Oil scarlet --
Oil violet
Oil yellow, PHW
Orange Y
Paper red AP
Patent blue B cone
Phenamine violet B
Phosphine R
Pigment rubine Q, 3Q
Polyform dyes:
Blue BRF, 2RF
Dark brown 3BF
Dark maroon GF
Orange RF
Scarlet 2GF, RF
Yellow GF
Pyrazoline dyes:
Black
Blue 4GL, 8GL, R
Brown BRL
Gray GL cone
Red BLW
Yellow 4GL, R
Rayon dyes:
Black B
Bordeaux B
Brown G, M
Navy blue N
Violet 3B
Resin brilliant orange 2R
Resin brilliant red R
Resin brown Z
Resin violet B
Resorcin brown YX
Rosanthrene A, R
Rosanthrene orange
Rubber colors
Safranine 8B
Scarlet crystals
Silk black 4BF, R
Silk blue lOG
Silk brown G, R
Silk fast blue 3G
Silk fast brown R
Silk fast yellow G
Silk red 2B, 3BX, 4B, lOB
Stilbene brown 3GXL
Stilbene orange EG
Sudan corinth B
Sudan orange FL, RT
Sudan red 4B
Sulfon yellow RS
Supranol orange R
Manufacturers'
identification num-
bers (according to
list on p. 61)
45
62
172
62, 150, X
41
41
X
150
248
62
80, 150
150
6, 150
150
150
62.150
248
8,55,80,87,245-..-
150
6, 8, 55, 80, 150, 245.
248...
8,248.
55.-..
87.--.
150-..
87..--
87..-.
87..-.
172-
172.
172-
172.
172-
172.
Produc-
tion
Pounds
15, 307
21, 503
163,' 434
62....
62.-..
62....
62..-.
62.--.
150...
150.--
150--
150...
55...-
62..-.
62....
62..--
150---
87.---
28, 45-
62..--
X--..
62....
28
28, 45, X_
Sales
Quantity
Pounds
8,338
21, 696
158, 854
Value
$13,434
15, 710
150, 409
5,502
Unit
value
$1.61
.72
.95
1.36
34
UNITED STATES TARIFF COMMISSION
Table 9. — Coal-tar dyes: United States production and sales, hy types, in 1940 — -
Continued
Name of dye
Manufacturers'
identification num-
bers (accord insr to
list on p. 61)
Produc-
tion
Sales
Quantity
Value
Unit
value
Unclassified i)yes— Continued
Supranol red PB- ..-
87 -
Pounds
Pounds
Supranol yellow GG
Vat khaki OG
Wool blue CGG
Wool green B
Wool navy blue B
Wool red XH
87
X
150
150
150
28 -
Zambesi black BG, D, PC, V
All other
Total unclassified dyes
45,87,150..
381,952
407,006
$222, 842
$0.56
62,X
23,294,429
21, 884, 293
2."; nm 810
1.14
Total dyes:
Those for which individual
statistics are shown.
Those for which individual
statistics cannot be
shown.
Grand total
94, 051, 224
33, 782, 356
91, 589, 782
31, 087, 654
45, 091, 694
31, 340, 034
.49
1.01
127, 833, 580
122,677,436 76.431.728
.62
COLOR LAKES AND TONERS
Increased demand for surface coatings and for decorating resulted
in an increase of 5.8 percent in the output of color lakes and toners in
1940, as compared with 1939. Production in 1940 w^as 19,213,000
pounds, sales 16,786,000 pounds, and the average value per pound,
75 cents. Lakes and extended colors accounted for 43 percent of the
production, full-strength toners 50 percent, and reduced toners 7
percent.
Statistics of production and sales of color lakes and toners in 1940
are shown in table 10.
Table 10. — Color lakes and toners: United States production and sales, in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on p.
61. An X sisinifies tliat the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth colunms indicate that the statistics
of production or sales cannot be published without revealing information with regard to individual firms.
The figures thus concealed are, however, included in the total.]
Manufacturers' identification num-
bers (according to list on p. 61)
Produc-
tion
Sales
Name of product
Quantity
Value
Unit
value
LAKES AND EXTENDED
COLOKS
Alizarin ..
13, 62, 123, 126, 143, 146, 176, 209,
228, 229, X, X, X, X. X.
13, 31, 62, 107, 121, 176, 228, 229, X,
X.
51, 97, 126, 143, 228, 229, 248, X, X..
13, 31, 51, 62, 74, 77, 97, 107, 121,
123, 143, 186, 221, 228, 229, 245,
X, X, X, X, X, X, X, X, X, X.
13, 51, 126, 143, 228, 229, 248, X
13, 31, 62, 74, 77, 97, 117, 143, 209,
221,229, X, X, X, X, X, X.
13 77, 143, 221, 229, X, X . .- .
Pounds
185, 444
242, 189
188,119
495, 714
43, 214
114,056
32,794
318, 980
Pounds
164, 253
252,471
162, 140
392, 957
20, 768
109, 846
29,092
269, 481
$168, 673
76,661
72, 107
205, 415
11.460
80, 957
21, 151
139, 247
$1.03
Azo Bordeau.K . ..
.30
Black
.44
Blue
.52
.55
Eosine and phloxine
Fast light yellow
Green
.74
.73
13, 29, 31, 51, 62, 74, 77, 97, 121, 123,
126, 143, 186, 221, 228. 229, 245,
x,x,x,x,x,x,x,x.
.52
SYNTHETIC ORGANIC CHEMICALS
35
Table 10. — Color lakes and toners: United States production and sales, in 1940-
Continued
Manufacturers' identification num-
bers (according to list on p. 61)
Produc-
tion
Sales
Name of product
Quantity
Value
Unit
value
LAKES AND EXTENDED
COLORS— continued
Lithol rubine
13, .31, 51, 62, 74, 121, 126, 186, 209,
221,229,X,X,X,X, X.
13, 31, 51, 62, 97, 107, 126, 143, 186,
209, 221 , 228, 248, X, X, X, X, X,
XXX
1.3, 74^77, 126, 248, X, X
Pounds
347, 223
151,282
10, 992
188, 480
1, 668, 967
314,717
50, 556
Pounds
346, 128
137, 904
10.012
165. 754
1,357,396
252, 743
$106,310
76, 192
7.433
51,040
745, 994
107, 094
.$0. 31
55
Naphthol yellow.. _-.
74
31, 36, 51, 62, 77, 97, 12?, 143, 229,
245, X. X, X, X, X, X. X.
13, 31, 36, 51, 62, 74, 77, 105, 107, 1 17,
126, 143, 186, 209, 221, 228, 229,
248, X, X, X, X. X, X, X, X, X.
13, 36, 62, 74, 77, 105, 117, 126, 143,
186, 209, 221, 228. 229, X, X, X,
x,x,x,x.
31
.55
42
Phosphomolybdic acid, to-
tal.
Blue
77, 107, 221, X
Brown.- '
123
Green .
51,62,143
Purple. - . -
31, 36, 51, 107, 143
Red
31, X _
Violet
126 .
Phosphotungstic acid:
Blue
8, 13. 31, 51, 62, 74, 97, 105, 107, 143,
209, 221, 229, 248, X, X, X. X.
8, 31, 51, 62, 77, 97, 107, 143, 229, X,
X X X X X X
31, 51, 97, 107,' 143, 209, 221, 229, 24S,
X X X X
8, 13, 29, 31, 51, 62, 77, 97, 107, 123,
143, 209, 229, 248, X, X, X, X, X.
74, 143, X .
359, 585
169, 340
75, 522
209, 731
433
434,919
26. 161
518, 789
1,081,170
155, 193
10, 432
195, 060
717, 610
267, 833
129, 543
65, 950
175, 904
237
220, 381
66,675
52, 522
102, 878
318
82
Green .
51
Purple. --- ._ . .
80
Red -
58
Other --
1 34
Pigment scarlet .
13, 31, 51, 62, 107, 126, 143, 176, 186,
209, 228, 229, 248, X, X. X. X.
13. 51, 105, 117, 126, 209, 221, X, X,
X.
31, 51, 62, 74, 77, 121, 123, 12C, 143,
186, 209, 221, 229, 245, X, X, X,
X X X X X
13^ 62, 97,' 121* 126, 186, 209, 228,
229, 245, X, X, X, X. X.
51, 77, 105, 107, 117, 126, 143, 209,
221,229,X,X, X, X, X, X.
13, 51, 62, 97, 107, 123. 229, 245
13, 51 62 77 123 143 229 XXX
21, 628
492, 858
993, 222
145, 614
9,514
99, 446
1, 130, 695
17, 594
248, 225
270. 766
83, 326
7.269
34, 2.57
389, 212
81
Red
50
Scarlet 2R
27
57
Violet
Yellow
.76
34
Another .
3, 13, 31, 36, 51, 62, 97, 107, 121, 123,
126, 143, 146, 186, 221, 228, 245, X,
x,x,x,x,x,x.
34
Total lakes and ex-
8, 306, 681
7, 203, 392
3, 363. 187
.47
tended colors.
TONERS OR FULL-STRENGTH
COLORS
Alkali blue .-
8, 221, X, X
549, 204
298, 365
51,301
237, 141
581, 805
9,762
3, 261, 949
212,937
768, 674
Eosine and phloxine
Green
Hansa yellow
13, 74, 77, 105, 186, 209, 221, 229, 248,
X, X.
13,62, 186,X
13, 62, 105, 107, 117, 186, 248, X, X,
X, X, X, X.
8, 13, 36, 51, 62, 74, 77, 105, 107, 117.
126, 143, 186, 209, 221, 228, 229,
248, X, X, X, X, X,X.
36, 209, 248, X ..
13, 36, 51, 62, 74, 77, 105, 107, 126,
186, 209, 228, 229, 245, 248, X, X,
X X X X
13, 31, 51, 62, 74, 77, 105, 107, 121,
126, 186, 209, 245, X. X, X, X,
X X
13, 62, i21, 126, 176, 186, 228, 245,
248, X, X, X, X.
192, 527
38, 937
236,410
421, 013
6,922
2, 933, 945
198, 004
732, 584
232, 442
54, 269
308, 428
351, 368
6,149
1, 542, 792
218, 742
1, 797, 779
1.21
1.39
1.30
83
Lake red D
Lithol
Lithol rubine
Maroon
.89
.53
1.10
2.45
36
UNITED STATES TARIFF COMMISSION
Table 10. — Color lakes and toners: United States production and sales, in 1940 —
Continued
Manufacturers' identification num-
bers (according to list on p. 61)
Prrtduc-
. tion
Sales
Name of product
Quantity
Value
Unit
value
TONERS OR FULL-STKENGTH
COLO R s— continued
Methyl violet .-
8, 13, 31, 51, 65, 74, 77, 105, 107, 117,
186, 221, 228, 229, X, X, X.
13,74,77, 105, 186, X,X, X
3, 13, 31, 36, 51, 62, 74, 105, 107, 121,
126, 176, 186, 209, 228, 229, 245, X,
X, X, X, X, X,X, X, X.
8, 77, 105, 121, 248, X, X
Pounds
284, 632
26, 264
1, 142, 532
135, 565
16, 994
18, 732
29,317
5,209
28, 383
102, 095
83, 262
76, 935
46, 846
421, 122
998, 907
182, 425
44, 670
Pounds
252, 243
19, 644
999, 610
128,915
14, 364
17, 346
24, 030
4,371
$256, 303
20, 938
699, 326
108, 914
44, 573
49, 940
23, 591
16, 030
$1.02
1.07
.70
84
Phosphomolybdic acid:
Blue -
31, 36, 62, 105, 107, 126, 248, X, X__
31,36, 105, 107, 126, 248, X
31, 62, 107, 121, 221, 248, X, X, X, X-
31,51,105,248
3.10
Green
Purple
2.88
.98
Red
3.67
Violet •
31, 36, 65, 77, 126, 143
Phosphotungstic acid:
Blue
13, 31, 51, 62, 74, 77, 107, 121, 126,
143, 209, 221, 228, 229, X, X, X,
XXX
31. 51" 62, 74, 77, 107, 121, 126, 143,
176, 209, 221, 228, 229, X, X, X,
X X X X
13, 31, 51, 62, 107, 121, 126, 143, 209,
221, 228, 229, X. X, X, X, X, X.
13, 31, 51, 62, 74, 77, 107, 126, 143,
209, 228, 229, X, X, X.
8, 31, 51, 62, 105, 107, 121, 126, 186,
245, 248, X, X, X, X, X.
3, 13, 36, 62, 74, 105, 107, 121, 126,
176, 186, 209, 228, 229, 245, X, X,
X, X, X, X, X, X, X, X.
13, 51, 186, X, X, X
31, 51, 74, 77, 105, 186, 209, X, X_.._
80, 529
72, 863
61,690
41,651
400, 749
812, 866
155, 982
516, 018
281, 813
209, 170
126, 490
153, 007
390, 750
■ 827,413
192, 085
675, 715
3.50
2.87
Purple - --
2.05
Red
3.67
Red -
.97
Toluidine red -
1.02
Yellow
1.23
All other
1.31
9, 615, 028
8, 363, 213
8, 588, 027
1.03
strength colors.
13, 62, 74, 107, 126, 143, 209, 221, 229,
XXX
13, 31, 51, 62, 74, 77, 107, 126, 186,
209, 229, X, X.
3, 13, 31, 51, 62, 74, 107, 121, 126, 176,
186, 228, 229, 245, X, X, X, X, X.
13, 29, 31, 62, 97, 107, 126, 176, 221,
228, 229, 245, X, X, X, X, X, X,
X.
13, 29, 62, 97, 107, 126, 143, X, X, X_
REDUCED TONERS
Lake red C and D
53, 978
342, 763
361, 116
239,316
293, 912
54, 232
370, 280
368, 381
187, 231
239, 399
28, 975
136, 742
51, 400
60,285
283, 327
.53
Lithol
.37
Para red
Toluidine red
All other
.14
.32
1.18
1,291,085
1,219,523
560, 729
.46
Total color lakes and
19, 212, 794
16, 786, 128
12,511,943
.75
toners.
MEDICINALS
Synthetic medicinals are invaluable to public health. Production
and sales of both coal-tar and non-coal-tar medicinals in 1940 were
greater than in 1939. In the coal-tar group the output of 18,214,000
pounds in 1940 was an increase of 20 percent, and sales, amounting
to 15,010,000 pounds, were an increase of 16 percent. Aspirin and
salicylic acid accounted for 63 percent of the total production in 1940
in terms of quantity. Sulfanilamide, in 1940, showed a decrease of
23 percent in production and of 30 percent in sales, possibly because
of increased competition from other newly developed chemo thera-
peutic agents. The output of sulfapyridine and its salts, reported
SYNTHETIC ORGANIC CHEMICALS
37
for the first time in 1940, was 102,196 pounds, and sales were 76,171
pounds valued at $1,134,097. Sales of sulfathiazole, also given for
the first time in 1940, were 91,907 pounds valued at $1,332,283.
Nicotmic acid amide, a pellegra-preventive vitamin, was produced
in the amount of 3,791 pounds in 1940.
The production of non-coal-tar medicinals in 1940 was 2,246,000
pounds, and sales were 1,727,000 pounds valued at $7,587,000. This
output represents an increase of 35 percent over 1939. The produc-
tion of non-coal-tar barbituric acid and derivatives increased during
the year from 167,000 pounds to 353,000 pounds, and the output of
iodoform likewise nearly doubled. Considerable quantities of both
these materials are used by the Army and Navy Medical Depart-
ments. The output of ascorbic acid (vitamin C) in 1940 was 33,373
pounds; sales were 26,714 pounds, valued at $31.83 per pound.
Statistics of production and sales of synthetic medicinals are show^n
in table 11.
Table 11. — Synthetic medicinals: United States production and sales in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61. An X signifies that the manufacturer did not consent to the publication of his identification number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus concealed, however, are included in the total.]
Manufacturers'
identification
numbers (accord-
ing to list on p. 61)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAR
Acetanilide... _ -
47,60, 145, 149
60, 145, 149, 222, X
Pounds
735, 568
Pounds
483, 449
$129, 156
$0.27
Acetophenetidin (Phenaeetin)
p-Acetylaminobenzene sulfonchloride
149.
Acetvlamino-hydroxy-phenyl arsenic acid
1, 147, X
and salts (Acetarsone) (Stovarsol).
78, X, X
Acetylsalicylic acid (Aspirin)
Amidoxyl benzoate
60, 149, X, X, X
1
6, 409, 824
6,245,053
2, 861, 752
.46
p-Aminobenzoyldiethylaminoethanol (Pro-
caine) .
p - Aminobenzovldimethylaminomethylbu-
1, 85, 161, X, X, X,
X, X.
X
23, 801
20, 370
394, 361
19.36
tanol hydrochloride (Tutocain).
X . .
drochloride (Mapharsen).
Ammonium salicylate
60
Antipvrine
60
Arsanilic acid
1, 147
Arsphenamine _ . . _ . _
1,59,137, 147, 213, X_
X
264
24, 733
93.69
Barbituric acid derivatives:
salt.
X
acid and salt.
Cyclopal
X
Hexylethyl barbiturate sodium (Ortal
sodium).
Phenobarbital .
X
1, 25, 85, 137, 147, 222,
X.
25
161, 773
159, 189
621, 357
3.90
Phenobarbital calcium
Phenobarbital sodium
1, 25, 85, 137, 147.-..
X
24,896
23, 523
82, 577
3.51
Benzaldehyde
100, X, X
X
197 - - ..
Benzoic acid
60, 62, 149
X
panol hydrochloride.
X
X
147
Bismuth campho earboxylate -.
1
38
UNITED STATES TARIFF COMMISSION
Table 11. — Synthetic medicinals: United Stat'is production and sales in
1940— Continued
Name of medicinal
(A) COAL-TAR — Continued
Bismuth tribromophenol
m-Bromoaceto phenyl benzoate (Neoxyn)..
n-Butyl-p-aminobenzoate (Butesin)
p-Butylaminobenzoyl dimethylamino etha-
nol.
a-Butyloxycinchoninic acid diethylethylene
diamide and hydrochloride.
2-Butyloxy-2,6-diamino-5,5-azopyridine(Nl-
azo).
Caffeine sodium benzoate
Caffeine sodium salicylate
Calcium cresol sulfonate
Calcium iodoxybenzoate
Calcium salicylate
Chloromercury-4-n itro-o-cresol
Colchicine salicylate..-
m-Cresyl acetate (Cresatin)
2,5-Diaminotoluene sulfate
Dibenzyl ketone
Di-n-butyl-p-aminobenzoate trinitrophenol
(Butesin picrate).
Di-n-butylaminopropyl-p-aminobe n z a t e
(Butyii base).
Di-n-butylaminop ropyl-p-aminoben-
zoyl sulfate (Butyn sulfate).
n - biethylaminoisopentyl - 8 - amino - 6-
methoxy quinoline.
3,4-Dihydroxy phenyl ethylmethylamine
(Epinine).
3,5-Diiodo-4-pyridon n-acetic acid diethanol-
amino.
4-Dimethylamino antipyrine (Aminopyrine)
Dinitroplienol . -
Dioxy anthranol (Anthralin)
Disodiumhydroxymercurisalicyloxy acetate
(Mercurosal).
Disodium-4-sulfaminophenyl-2-azo-7-acetyl-
amino-l-hydroxy-naphthalene-3, 6-di sul-
fonate.
Dyes, medicinal, total
Acriviolet
Brilliant green
3,6-Diaraino acridine sulfate (Profla-
vine) .
3,6-Diamino-lO-methyl acridine chloride
(Acriflavine).
Dibromohydroxymercurifluorescein so-
dium salt (Mercurochrome).
Gentian violet
FTexale t
Methylene blue
Methyl violet
Phenylazo-diamino pyridine hydrochlo-
ride (Pyridium).
Scarlet red ... .
Sulfosalicylic acid
Try parsamide
E phedrine, synthetic
Eserine salicylate
a-Estradiol-S-ben/.oate (Progynon B)
E thocaine borate ( Borocaine)
Ethyl-p-amino benzoate (Benzocaine) (An-
aesthesine).
Gamma-diethylaminopropylcinnaraate hy-
drochloride (Apothesine).
Guaiacol (liquid) ..
Hexamethyleneamine acetamino salicylic
acid (Salihexin).
Hexylresorcinol
Homatropinp and salts
Homatropipp ir.(>thyl bromide
Hydr(ixyiii('rcury-4-iiitro-o-cresol anhydride.
p-IIydroxy pheiiylisopropyl amino hydro-
bromide.
8-Hydroxyquinoline (Oxyquinoline base)...
8-Hy droxyquinoline-5-sulfonic acid
Manufacturers'
identificati on
numbers (accord-
ing to list on p. 61)
147.
60. _
1...
X..
196,
137, 147, 155, X.
137, 147.
X
X
60
I _
147-.
201
69
X
1
Produc-
tion
Pounds
150, X_
62
1
X
150 -.
150 ..
1, 150.
1, 150-
110-..
150
147
8, 65, 150.
150
184
150
78,147
147,213
85,147
147
196
1,201,X
1,25,85, 147, 161, X,
X, X, X.
X
104, 149.
1
201.
147-
X..
1...
X..
25, 147.
25, X..
Sales
Quantity
Pounds
1,802
Value
$5, 583
45, 648
16, 313
20, 185
43, 587
17, 291
39
16, 795
Unit
value
$3.10
972, 949
34, 338
755
57, 041
22.32
19.36
3.40
SYNTHETIC ORGANIC CHEMICALS
39
Table 11.— Synthetic medicinals: United States production and sales in
1940 — Continued
Manufacturers'
identification
numbers (accord-
ing to list on p. 61)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAR— continued
X, X
Pminds
Pounds
X
7-Iodo-8-hvdroxyquinoline-5-sulfonic acid
1
lodopvrine . - -. --. .-
137
X..
lodoxvquinoline sulfonic acid (Yatren acid)
25,30,X
\, 804
and salt.
Laevo-methvlaminoethanol catechol (Epi-
X
nephrine).
Lithium benzoate - -
X
X
X
Magnesium salicylate
60, 104, 137
Mandelic acid and compounds
1,137, 147, 184, 213, X
x,x
60, 044
62, 299
$168, 831
$2.71
Menthyl salicylate
Methyl-m-amino-p-hydroxv benzoate (Or-
X
thoform).
2-Methyl-6-chloro-9-diethylaminopentylam-
ino acridine.
X
X
X
madine).
2-Methyl-l,4-naphthol quinone
1,213
p-Methylphenyl cinchoninic ethyl ester
(Neocinchophen) .
Mono n-amylaminoethvl p-aminobenzoate
1,8,25
6,946
5,485
53, 876
9.82
161..
(Amylcaine).
Monoisobutylaminoethyl p-aminobenzoate
161
(Mnnocaine).
(3-Napiithyl benzoate
78
fl-Naphthyl salicylate
78
1, 59, 137, 147, 213, X.
1
10, 585
9,298
820, 605
88.26
Neo-silver arsphenamine ._....
Neo-synephrin hydrochloride
X ,
Nicotinic diethylamide _ _ . . .
1, X
Oxyquinoline benzoate
25,147
Oxyquinoline citrate .. ..
147
25,147
Oxj'quinoline tannate
25
Phenolphthalein _ - .. ..
149, X,X
Phenolsulfonates (calcium, sodium, zinc.
60,137,147
etc.).
110
Phenylethylmethy urea sodium
X
Phenvlis(]cvanate -__ _
69 _-._
^-Phenvlisopropvl amine and sulfate
X
Phenyl mercuric acetate _
26,70,96
Phenyl mercuric benzoate .
96
Phenyl mercuric borate
96
Phenyl mercuric chloride
26,96
Phenyl mercuric nitrate. _
26,70,96
100
3,221
32.21
Phenyl-propanolamine hydrochloride (Pro-
201
padrin hydrochloride) .
2-Phenylquinoline-4-carboxylic acid (Cin-
8,25
chophen) (Phenyl cinchoninic acid).
Potassium oxyquinoline sulfate. _
25
Propyl p-aminobenzoate
X
Pyramidon and trichloroethyl alcohol ure-
X
thane compounds.
Pyridine-^-carboxylic acid diethylamide--.
X
ResorcinoL-- .- _ _
62, X
Resorcinol monoacetate
69,78,147.x
60,104,149 ...
3,613
5, 068, 010
3,373
3,075,135
8,133
762, 564
2.41
Salicylic acid- _ -__ __ _ .. .
.25
Salol
60 ..
Silyer arsphenamine ._ . _ -
1,X
Sodium carbolate . _ .
78
Sodium diphenyl hydantoinate (Dilantin)
X.X .
Sodium o-iodohippurate
137
Sodium methylene sulfonamino-hydroxy-
1
phcnyl arsenate (Aldarsone).
Sodium salicylate.
60,104,149
147
734, 123
684, 702
289,803
.42
Sodium succinate. -_ _ . _ . . . . ..
Sodium p-toluene sulfochloramide (Chlora-
149 - .
mine T).
Strontium salicylate
60,104,137
40
UNITED STATES TARIFF COMMISSION
Table 11. — Synthetic medicinals: United States production and sales in
1940 — Continued
Manufacturers'
identificati on
numbers (accord-
ing to list on p. 61)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Sulfanilamide (p-Amino-benzosulfonamide) .
Sulfapyridine and salt (2-Sulfanilamido
pyridine) .
Sulfathiazole and salt (2-Sulfanilamido-
thiazole).
Sulfoarsphenamine
Tetraiodophenolphthalein and sodium salt.
Theobromine and sodium salicylate
8, 33, 147, 149, X
8, 147, X,X, X
8,147,213, X
Pounds
543, 802
102, 196
Pounds
494, 983
76, 171
91, 907
232
6,494
$670, 311
1, 134, 097
1, 332, 283
33, 431
91, 687
$1.35
14.89
14 50
1, 59, 137, 147, 213, X-
25, 33, 69, 137, 147,
150.
137,147,155
351
4,856
144. la
16.69
147
137,147
78
p-Toluene sulfodichloramide (Dichlora-
mineT).
Vinethene (Divinyl ether) - - . .
149
147
Vitamins:
K . -
147
38, 85, 88, 147, 155,
207.
1.85,88,147,207
147
3,791
2,931
68, 085
23. 23
Pyridoxine (Be) - -
33
Total coal-tar medicinals: _
13, 932, 480
4,281,954
11,479,885
3, 530, 283
9, 648, 580
8, 125, 163
.84
tics are shown.
Those for which individual statis-
2.17
tics cannot be shown.
18, 214, 434
15,010,168 17.773.743
1.18
78,X
(B) NON-COAL-TAR
Acetannin CTannigen) (Tannyl acetate)
69 ---
Aminoacetic acid (Qlvcocol) (Glycine)
25,60,85,170
p-Amino di-n-butylaminoyiropanol hydro-
chloride (Butyn hydrochloride).
1
69.137, X
196
196
353, 157
141, 327
686, 030
4.85
1 .
Allyl isooropyl barbituric acid
106... - .
1
85, X
X -
bromin'> .
Diethylbnrbituric acid (Barbital) and
SBltS.
Ethyl-l-methyl butyl barbituric acid
and salts.
Ethyl-l-methyl butyl thiobarbituric
acid and salts.
Ethyl secondary butyl barbituric acid
and vSalts.
Lsoamyl ethyl barbituric acid and salts..
Isopropyl ethyl barbituric acid and
salts.
1,85, 106, X.
1, 131
1
X
131
X
1 - .
X, X
Propyl-methyl-carbinyl allyl-barbitu-
rate sodium.
131
60, 137
X - .
Butyl ethyl malonic ester (n and see)..
Calcium acetyl elycollate
X
207
X
78, X
Calcium pantothenate dextrorotatory
147
78
Camphor (synthetic). {See table loB.)
78, X
147, 149
Chloroform. {See. table 15B.)
SYNTHETIC ORGANIC CHEMICALS
41
Ti^BLE 11. — Synthetic medicinals: United States production and sales in
1940 — Continued
Manufacturers'
identification
numbers (accord-
ing to list on p. 61)
Produc-
tion
Sales
Name of medicinal
Quantity
Value
Unit
value
(B> (NON-COAL-TAR— continued
Chlorothvmol . . _ _
147 -_ -
Pounds
Pounds
Cystein hydrochloride __ _ .
78 ..
Desoxvcorticosterone acetate fCortate')
196
196 ..
oxyl 2,R-dicarboxylie acid (Neo-iopax).
Diureidc of Clyoxvlic acid _ _. .. _
1
Ethvl chloride. (See table 15B.)
Ethyl ether. (See table 15B.)
o-Estradiol (Progynon DH)
196.
" " "
a-Estradiol dipropionate (Progynon DP)
196
X
Ethvl iodide
69, 70, 137, 147
Ethyl malonate (Malonic ester)
1, 85, 106
276, 249
Ethyl-1-methyl butyl malonic ester
1
Ethyl nitrite
81, 137, 147
16,931
14,350
$9, 715
$0.68
X
X
Gallic acid . . _ ._ ..
69, 137... ._
Glycerophosphorio acid and salts
104, 149
Hexamethylenetetramine
62. 104 .
Hexamethylenetetramineanhydromethy-
lene citrate.
Hexamethylenetetramine tetra iodide
78, X
X
207 -.
Iodoform. . _.. . . . -
137, 147, 155
X .
22, 030
22, 304
92. 657
4.15
lodomethane sulfate sodium
Lithium lactate
114 .
222, X, X _ .
X
78, X . .
Methylene iodide
69, 147, X ...
Methvl iodide . . ..
69, 70. 137, 147
147
3,381
3,303
11,616
3.52
2-Methyl naphthoquinone
Methyl testosterone (Oreton M)
196
196
Sodium bismuth-thioglycollate (Thiobis-
mol).
X
137 — .
137 .
Tcr()in hydrate
62, 102, 147
67, 354
21, 400
.32
Testosterone (Oreton-F)
196
190
137, 155
Theophylline (1,3-DimethyIxanthine) and
derivatives:
25, 85, 137
Ethylenediamine (Aminophylline)
Methyl glucamine (Glucaphylline)
10,25,61,85,147,180,
X, X, X.
1
21, 602
10, 227
103, 392
10. 11'
85, 137, X
Thioethamyl sodium
X . - .
Thymol
X, X
Thymol iodide
137, 147, 155
4,910
6,117
20, 190
3.30
60, X .
TribroTUotertiary butyl alcohol (Brometone)
Trichloroacetic acid
X
60 - -
Trichlorotertiarybutyl alcohol (Chloretone)
(Chlorobutanol).
25.147,X,X,X,X..
78
21, 504
7,890
18, 246
2.31
Uric acid and potassium acid salt
70 - -
Vitamins:
A.scorbic acid (C)
106. 147, X
33, 373
26, 714
850, 315
31.83
Riboflavin (G)
147, X . .
Thiamin chloride (Bi)
100, 147
106, 147 .- . -
All other
X
Total non-coal-tar medicinals:
399, 980
1, 845, 899
158, 259
1, 569, 030
1, 127, 531
6, 459, 749
7.12
tistics are shown.
4.12
tistics cannot be shown.
Grand total -
2, 245, 879
1, 727, 289
7, 587, 280
4.39
42
UNITED STATES TARIFF COMMISSION
FLAVORS AND PERFUME MATERIALS
Flavors and perfume materials of coal-tar origin were produced and
sold in slightly greater quantities in 1940 than in 1939; those of non-
coal-tar origin increased in production but declined somewhat in sales.
The 1940 output of flavors and perfume materials derived from coal
tar was 5,485,000 pounds; sales were 5,062,000 pounds valued at
$4,751,000. Of those of non-coal-tar derivation, production was
2,510,000 pounds and sales were 2,129,000 pounds valued at $1,925,000.
Some increases in production were noted for anisic aldehyde, citral,
geranyl acetate, ionone, terpineol, and heliotropin. In terms of
quantity output, methyl salicylate is the most important member of
this group, followed by terpineol and vanillin. In terms of value of
sales, vanillin is the most important. Production of vanillin decreased
in 1940 as compared with 1939, but sales increased.
Statistics of production and sales of flavors and perfume materials
in 1940 are shown in table 12.
Table 12. — Synthetic flavors and perfume materials: United States production and
sales in 1940
:[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61. An X signifies that the manufacturer did not consent to the publication of his identification num-
ber with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus concealed, however, are Included in the total.]
Manu f acturers '
ident iflcation
numbers (according
to list on p. 61)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(A) COAL-TAR
83, 120, X, X
Pounds
Pounds
Amyl benzoate
Amy 1 cinnamic aldehyde
Amyl salicylate - .
76, 79, 232, X, X
76, 79, 120, 141, 232,
236, 237, X, X.
79, 141, 208, X, X, X —
76, X
323
82, 307
65, 193
263
77, 991
66, 907
$516
107, 345
32, 709
$1.96
1.38
.49
108
199
Benzophenone - - -
83, 120, 141, X, X, X--
79, 120, 141, 208, X, X-
108, 120, 141,208, X,X-
79, 120, 141, 208, X, X..
76. 79,232, X, X, X---
79, 141, X, X
34, 518
246. 887
107, 336
78, 426
818
38, 269
250, 973
121,084
77, 927
590
27, 801
86, 894
67, 836
57,118
1,161
.73
Benzyl acetate _ _.-
.35
Benzyl alcohol . . ._
.56
Benzyl benzoate . . . . .
.73
Benzyl butvrate - - -._.-.-.
1.97
Benzyl cinnamate
Benzyl eugenol
236
Benzyl formate
76, 79, 141, 232, X
76
536
397
892
2.25
79, 236, X, X -
Benzyl propionate
18, 76, 79, 141, 232, 236,
X, X, X.
79, 83, 141, 236, X, X —
79
4,256
23, 773
3,200
23, 381
4,456
29, 128
1.39
Benzyl salicylate ---------
1.25
Benzyl valerate
141, 232, X
Bromstyrol
25, 141
76
236
83, 232, X, X
•
83, 141,232, X
141, 208, X, X
Cinnamyl acetate
18, 76, 79, 141,236, X—
76
397
321
1,905
5.93
Cinnamyl anthranilate
76, 199, X
45
76, 199, X
199
79
Coumarin (synthetic)
60, 62, 145, 149
245,688
217, 634
506,221
2.33
79, 232, X
236
p-Crcsvlnicl hvl ether
79, 141, X
p-rresyli)lienyl acetate
76, 79, 141, 236, X -
SYNTHETIC ORGANIC CHEMICALS
43
Table 12.-
-Synthetic flavors and perfume materials: United States production and'
sales in 1940 — Continued
M a n u a c t u r e r s '
identificati o n
numbers (according
to list on p. 61)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Dimethyl acetal of phenylacetalde-
18, 83, X..
Pounds
5,479
787
Pounds
hyde.
Dimethyl anthranilate
62, 76, 141, X
Dimethvlbenzyl carbinoL, _.
79,232,236
Dimethvibenzvl carbinol acetate -
232,236
Dimethyl hvdr()(iuinone-__ .._ . _..
62, X
Dimethylijht'iivl carbinoL. __ _
236 --
Dimethylphenvl carbinol acetate.. -.
236
Dinicthvlphonvl carbinol butyrate
236
Diphcnvhiicthane
X -..
Diijhcnvl Kxide _ _
60, 79, X
Ethyl anthranilate. . . .
76, 79, 141 ...
162
1,831
145
1,635
$652
1,498
$4. 50'
Ethyl benzoate
79, 160, X,X, X
236 .
.92
Ethylbenzvl carbinol acetate.
Ethvl cinnamate ... ........
79, X, X .
453
1,314
1,433
11, 083
3.16-
Ethvliiicthvlphenvl glycidate
76, 199, 232, X, X, X...
25, 141, 232
1,611
8. 43
Ethvlphrnvl acetate
Ethyl salicylate
60, 79, X, X .-
679
400
365
.91
Ethyl vanillin,.
145, 149, X, X .
p-Hydroxy benzoic acid esters (Asepto-
X
form).
Isobutvl p-aminobenzoate
122
Isobutvl anthranilate
79.
lobutvl bcnzoate .
76,232 .-
Isobutvl cinnamate . .
76 .- . .
Isobutvlphcnyl acetate . ..
76, 79, 232, X, X
Isobutvl salicylate-
79, X, X
Isopropyl-o-eresol (Carvacrol)
X
Linalvl anthranilate. ...
79, 236
Linalyl benzoate ...
236
Linalyl cinnamate ..
236
Methoxy acetophenone (Novatone)
X
Methyl acetophenone
79, 83, X, X
Methyl anthranilate
60,62,141
79, 104, 108, 141, 160,
232, X, X, X.
25, 83, 141, X, X, X
X
42, 110
67, 412
14, 407
33, 078
56, 895
1.72-
Methyl benzoate .... .. ...
Methyl cinnamate
15, 619
18,288
1.17
Methvl p-cresol
Mothvl nafihthyl ketone
79, 83, 141, X, X
25, 83, 141, 232, X, X
5,800
7,563
12, 751
1.69
Methvlphi'nvl acetate
Methylphenyl carbinol-.- ---
83,X
Methylphenyl carbinyl acetate- - . .
83,X
Methyl salicylate
60, 104, 149, X
1, 641, 571
1,486,791
446,989
.SO-
Musk ambrette . . .
141, X
Musk ketone ...
141, X .
Musk xylol _ ..
62, 141, X
104, 032
91, 596
.88
0-Naphthyl anthranilate ...
76
^-Naphthvl ethyl ether (Nerolin)
83, 120
(3-Naphthyl methyl ether (Yara yara)
83,120 . . .
Phenylacet acetal . .
76
Phenylacetic acid ...
25, 83, 120, 232, X
79,83,X
11, 326
9,910
11,285
1.14
Phevnlacetic aldehyde . .
Phenyl acetone
83
Phenvlethyl acetate ...
1, 79, 120, 232, X, X
Phenylethyl alcohol
Phenvlethyl anthranilate...
60, 120, 232, 237, X
236
193, 149
171, 668
327, 915
1.91
Phenylethyl benzoate
232
Phenvlethyl butyrate ....
79
Phenylethyl cinnamate . . . .
236 - .
Phenylethyl formate . ...
18, 232, 236, X .
140
115
800
6.96-
Phenvlethvlphenvl acetate
79 232, X
Phenylethyl propionate
141, 232, 236, X
596
595
2,953
4.96-
Phenylethyl salicylate
62 236
Phenylethyl valerate
199 X
Phenylnropyl acetate
76. 232, 236, X
Phenylpropyl alcohol - .
83
Phenylpropyl propionate . .. .
76,232 . -
Propyl cinnamate
76
Saccharin .
149, X
Salicvl aldehyde ... ........
60,62
Styrallyl acetate
232
Styrallyl alcohol . .
232
Tolyl acetate . .
X
Tolyl aldehyde
X
44
UNITED STATES TARIFF COMMISSION
Table 12.
^Synthetic flavors and perfume materials: United States production and
sales in 1940 — Continued
Manufacturers'
identificati o n
numbers (according
to list on p. 61)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(A) COAL-TAE— continued
Trichlaromethvlphenyl carbinol ace-
X
Pounds
Pounds
tate (Rosetone).
Vanillin _.
145, 149, 195, X, X
236
576, 708
619, 407
$1, 249, 459
$2.02
Other
Total coal-tar flavors and per-
fume materials:
Those for which individual
3, 454, 270
2, 030, 335
3, 331, 662
1, 730, 219
3, 157, 944
1, 592, 822
.95
statistics are shown
Those for which individual
.92
statistics cannot be shown.
Grand total - . -
5, 484, 605
5, 061, 881
4, 750, 766
04
(B) NON-'COAL-TAR
Acetates:
C 9
76
C 10 ._
76
C 12
62,76,X
Acetvl propionyl
236
Aldehydes:
C 6 (Hexyl)
236
7 (Heptyl)
76, 151, X
C 8 (Octyl)
X
C 9 (Nonyl)
X
'C 10 (Decyl)
232,236, X - -
C 12 (Duodccvl)
236, X . . .
C 14 (Tetradecyl)
236
C 16 (Hexadecyl)
236,X
Allyl caproate, _
76, 79, 199, 232, X, X, X.
76
1,605
Allvl propionate . . . . .
Amvl butvrate. ..... .......
7fi, X
Amyl caproate
199
Amvl formate ..
76, X
Anethol.-- -
153,X,X,X
Anisic aldehvde (Aubepine)...
18,62, X,X,X . -
42, 218
32, 101
77, 133
2.40
Bornvl acetate _
76
-n-Butvl butyrate
76, 79, 81, 160, X
106
87
.82
Butyl isovalerate - . ..
76
Caprone .
236
Capryl butyric acid
79 . -
Capryl butyric ether .
79
Cedryl acetate
232, 236
Cetyl alcohol
62, 236, X
Citral
Citral acetate-- .-. ..
34, 62. 76, 133, 232, 236,
x,x,x,x,x.
236
39, 930
32, 151
51,890
1.61
Citral citron (synthetic)
236
Citronellal ..
18, 76, 141, 226, 232,
236, X, X.
62, 83, 141, 232, 236, X,
X.
79,236
Citronellol
Citronellyl acetate
53, 633
51, 779
76, 947
1.49
Citronellyl propionate
232 .. ...
236
Cyclo-ijeraniol - . .
236
236
Diacetyl
25,69,236
Dibutvl carbinol
199
78, 199
79
Dihvdroxv citronellic ketone
79 ..
Dimethyl octanol .. .
199, 222
Dimethyl ortanyl acetate ..
236
Ethyl amyl ketone .
236
Ethyl butyrate .__
76, 81, 160, X, X
76. 160,X
160, X, X .
50, 291
427
47, 668
29, 649
.62
Ethyl isovalerate
Ethyl laurate
122, X
Ethyl mvristate ....
122, 199
Ethyl oenanthate
76, 79, 160, 232, X.X....
76, 79, 133, X
5,937
15. 224
4,529
12,910
3,272
8,834
.72
Ethyl oxyhydrate :
.68
SYNTHETIC ORGANIC CHEMICALS
45
Table 12. — Synthetic flavors and perfume materials: United States production and
sales in 1940 — Continued
Manufacturers'
identificati o n
numbers (according
to list on p. 61)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(B) NON-COAL-TAE— continued
Ethyl pelargonate.
34.76, 232, X
Pounds
Pounds
Ethyl sebacate. .. ._ ..- .- .
76,X
Ethyl n- valerate -. - -
79
Eugenyl acetate -
236
236 -._
Formate: C 12 ..
76
18, 62, 76, 83, 141, 199,
222, 226, 232, 236, X,
x,x,x,x.
18, 62, 76, 79, 83, 141,
222, 232, 236, X.
76, 79, 236, X
306, 435
28, 150
275, 772
26, 396
$220, 432
30, 198
$0.80
1.14
Geranyl butvrate . . . .
Geranyl fortnate ._ - -
76,79, 236, X
59
76
76,X
76
x,x,x
34, 132
Hydrotropvl acetate
232
Hydroxy citronellal .
18, 62, 199, X
"'
Eydroxy citronellal dimethyl acetal ..
199, X
Hydroxy dimethylacetal.
62 _
62, 141, 145, 199, 232,
237,X,X,X.
79,81, 160, X
82, 568
74, 739
6,469
155, 740
4,642
2.08
.72
Isoamvl caproate.- . -- .
76
79 160, X
489
309
211
.68
76, 81, 160, X, X
Isoainyl propionate
81,X
62
62
76,79,160 .. . .
76,79 -
76
Isoeusenol .. . - -
76,236,X,X,X,X
X
25, 248
76 .
Isopropvl pelargonate
76 -
62, 83, 222, 236, X
2,197
1,924
.88
236
232 --
18, 76, 79, 199, 232, 236,
x,x,x.
236,X,X
24, 248
21, 017
65, 647
3.12
76, 79, 236, X, X
232 X
63
44
206
4.68
X/inalyl propionate
Menthone
79,141,222,236
76,236,X,X
141
378
Methyl heptin carbonate
Methyl ionone -
62, 145, 232, 236, 237,
x,x,x.
76,236,X,X
61, 157
847
60,949
136, 306
2.24
Methvl nonvl acetaldehyde.
236
236
Nonalactone .. -. -
X
X
236
Pelargonic acid
76
Peppermint oil (synthetic)
160
76
Rhodinol
18, 62, 76, 79, 133, 226,
232, 236, X, X, X,
X,X.
18,76,236
9,967
9,366
127, 176
13.58
Rhodinyl acetate - -
18, 76, 236
Santalal ...
236
Santalvl acetate . -. ...
76,X
Shiu oil acetate
232, X
Terpineol
62, 76, 153, X
766, 705
771, 247
157,490
.20
Terpinolene.. --- . .. ..
62,X
Terpinvl acetate
18, 62, 76, 236, X, X, X.
X
Tributyrin .
Undecalactone
76, 232, X, X, X, X
734
498
2,840
5.70
Vanillin. (See coal-tar, p. 44.)
46
UNITED STATES TARIFF COMMISSION
Table 12.
-Synthetic flavors and perfume materials: United States production and
sales in 1940 — Continued
M a n u f acturers '
identification
numbers (according
to list on p. 61)
Produc-
tion
Sales
Name of flavor or perfume material
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Vertiverol acetate
18, 76, 232, 236, X, X,
X.
236,X
Pounds
Pounds
Vcrtivert acetate
Otlier
76,236 --_
Total non-coal-tar flavors and
perfume materials:
Those for which individual
statistics are shown.
1, 550, 445
959, 588
1, 430, 247
698, 947
$1, 150, 624
774, 632
$0.80
1. n
statistics cannot be shown.
Grand total
2, 510, 033
2, 129, 194
1, 925, 256
.90
SYNTHETIC RESINS
The production of synthetic resins is of current interest because of
the demand for resins and plastic materials in national defense. The
output of coal-tar resins in 1940 was the largest on record, amounting
to 222,943,000 pounds, which is 24 percent greater than the former
peak output of 179,338,000 pounds in 1939; non-coal-tar resin pro-
duction reached a high of 53,871,000, or 60 percent more than the out-
put of 33,690,000 pounds in 1939.
Of the alkyd resins, the maleic anhydride resins were produced in
slightly greater quantity, but the phthalic anhydride resin increased
from 70,208,000 pounds to 91,446,000, or about 30 percent. The
amount of cresol or cresylic acid resins produced in 1940 was slightly
more than in 1939. Phenolic resins for molding increased in output
from 19,422,000 pounds to 26,418,000, or 36 percent, while those for
casting decreased from 8,517,000 pounds to 6,953,000 pounds.
The average value of coal-tar resins advanced 4 cents per pound in
1940, or 22 percent over 1939. Non-coal-tar resins advanced 9 cents
per pound, or 19.5 percent in the same period. The output of urea
increased from 16,569,000 in 1939 to 21,492,000 pounds in 1940.
Some of the increased demand for resins in 1940 was stimulated by
war purchases, but the larger portion was due to increased busmess
activity in general.
Statistics of production and sales of synthetic resins in 1940 are
shown in table 13.
SYNTHETIC ORGANIC CHEMICALS
47
Table 13. — Synthetic resins: United States production and sales in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61. An X sisnifies that the manufacturer did not consent to the publication of his identification num-
hi'T with the designated product. Blanks in the third, fouith, and fifth columns indicate that the statis-
tics of production or sales cannot be published without revealins information in regard to individual firms.
The figures thus concealed, however, arc included in the total.]
Manufacturers' identifica-
tion numbers (according to
list on p. 61)
Production
Sales
Name of resin
Quantity
Value
Unit
value
(A) COAL-TAR
Alkyd:
Maleic anhydride
Phthalic anhydride
Coumarone and indene .
7, 102, 118, 130, 140, X,X,X,
X, X,X,X, X. X.
7,12,62,90, 103, 118, le.-^, 176,
186, 189, 231, X, X, X, X,
X, X,X, X, X, X, X, X,
X, X, X, X, X, X, X, X,
X, X, X.
22, 152, 169
Pounds
6, 476, 883
91, 446, 195
24, 131, 733
Pof/nds
5,418,875
42, 400, 005
22, 976, 705
$1, 008, 8.35
7, 774, 730
1, 576, 907
$0.19
.18
.07
Polystyrene -_ -
60.x .
149 .
Tar acids:
Cresols or cresylic acid
64, 90, 187, 190, X, X, X, X,
X, X, X, X, X.
39, 103, 116, 125, 1.38. 149, X..
49, 52. 64, 90, 149, 187, 190,
X X X X X
7, 64*, 90,'lO3', 130, 186, 189, 190,
225, X,X,X, X, X, X,X,
X, X, X, X.
90, 1.36, 189, X, X, X, X, X .
X _ -
11,978,763
6, 9.53. 103
26, 417, 693
26, 957, 636
21, 126, 005
Phenol:
For casting
6, 696, 008
25,117,472
24, 234, 563
3, 175, 589
7, 869, 678
4, 822, 729
.47
For molding _ _
.31
For other uses
Phenols and cresols
.20
Terpenes and phenols
Xylenols . _._
X, X, X . _.
Xylenols and cresols _ .
00, X, X, X - -
Other
X .
Other hydrocarbon resins ..
62
Total coal-tar resins .
222, 913, 118
153, 520, 805
3,3, 378, 406
.22
102, X ...
(B) NON-COAL-TAR
Abietie acid -. __
Acrylic acid esters
62, X, X -
Melamac _
X .
Petroleum
X, X
Polyamide .. -_ _ .
62 _.
Poly vinvl alcohol ..
62
Sebacic acid.. -
X-. ..
Terpenes
169, X
Urea - __ .
7, 62, 103, 186, 189, X, X, X,
X.
X
21, 491, 653
19, 300. 685
7, 445, 483
.39
Urea and thiourea.. _._
Vinyl acetal and vinyl
62, X .
butyral.
Vinvl acetate and chloride . _
37, 60, 62, 92, X
Vinvlidine chloride polymer
60
Other . _
90
Total non-coal-tar resins.
53, 871, 245
47, 578, 845
25, 989, 933
.55
48
UNITED STATES TARIFF COMMISSION
RUBBER CHEMICALS
Synthetic organic chemicals used in compounding rubber are
responsible in no minor degree for the improved quality of rubber
products, particularly tires. The amount and kind of chemicals used
in compounding rubber depends on the individual rubber manufac-
turer. With increased manufacture of rubber products, the use of
synthetic organic chemicals has also greatly increased. Rubber
chemicals derived from coal tar show an increase in production from
29,966,000 pounds in 1939 to 37,139,000 pounds in 1940, and those of
non-coal-tar origin from 13,122,000 pounds to 16,915,000 pounds.
Accelerators and antioxidants are the principal rubber chemicals.
Of these, accelerators of coal-tar origin increased 38 percent in produc-
tion and antioxidants 14 percent, and accelerators of non-coal-tar
origin 29 percent.
Statistics of production and sales of rubber chemicals are shown in
table 14.
Table 14. — Synthetic rubber chemicals: United States production and sales in
1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61. An X signifies that the manufacturer did not consent to the publication of his ilentifieatioa number
with the designated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus concealed, however, are included in the total.]
Manufacturers
identification
numbers
(according to
list on p. 61)
Produc-
tion
Sales
Name of chemical
Quantity
Value
Unit
value
(a) coal-tar
Pounds
16,736,874
Pounds
12, 998, 019
$6, 370, 558
$0. 49-
62,149,151
Aldehyde-amines:
Acetaldehyde aniline --
Butyraldehvdo aniline
62,92,149,151..
X
482, 964
Crotilidinc aniline
Etiivl ^-propvlacrvl aniline
42
Heptaldehyde aniline-
151
Methylene aniline (anhydroformalde-
62,149
hyde aniline).
other:
Aminobenzothiazole
92
Benzal diraethvldithiocarbamate
X .. -
Benzothiazole thiobenzoate
149 .
Benzothiazvl disulfide
X,X,X . .
Benzothiazvl-ethvl-thiocarbonate
X
149
melthylcyclohcxylainiiKv
Carbon disulfide on methylene dipip-
149
eridine.
p-p'Diaminodiphenvlmethane
X
149
149
phenylguanidinc jihthalate and an-
hydroformaldeliyde aniline.
151-.
X .
thiocarbamate.
Dimethylethylenediphenyldith io-
42
carbamate lead salt
Dinitrophcnylbenzothiazyl sulfide
plus diphenylguanidine acetate.
Dinitrophcnyl dimethyldithiocarba-
mate.
Dinitrophcnyl ester of mercaptoben-
zothiazole.
Diphenylcarbamyldimethyldithiocar-
bamate.
149
X
149 ..
X
7,60,62,149..-.
149
1, 448, 504
1, 279, 701
427, 086
.33
Diphenylguanidine acetate - . .
SYNTHETIC ORGANIC CHEMICALS
49
Table 14. — Synthetic rubber chemicals: United States production and sales in
1940— Continued
Manufacturers'
identification
nun bers
(according to
list on p. 61)
Produc-
tion
Sales
. Name of chemical
Quantity
Pounds
Value
TTnit
value'
(A) COAL-TAR— continued
Accelerators— Continued.
Other — Continued.
Diplienvlguanidine and dinitrophenyl
149
Pounds
ester of mercaptobenzoihiazole.
Diphenvlguanidine oxalate
X
Diphenylguanidine phthalate. ..
149,151
Diphenylguanidine phthalate-di-
149
phonylguanidine acetate and iner-
captobenzothiazole disulfide.
Diphenvlguanidine phthalate, di-
149
phenylguanidine and dinitrophenyl
ester of mereaptobenzothiazole.
Di-o-tolvlguanidine -_ ._ ...
62, X
Di-o-tolyl thiourea
62
5-E thoxy-2-mercaptobenzothiazole
X
Hexamethylenetotramine ester of mer-
149
eaptobenzothiazole.
Mereaptobenzothiazole
]49,151,X, X._
62
5, 438, 933
Mereaptobenzothiazole on benzyl chlo-
ride addition of hexamethylenetet-
ramine.
Mereaptobenzothiazole cyclohexyla-
149
mine.
Mereaptobenzothiazole lead salt
62
Mereaptobenzothiazole methylene ani-
X
line.
Mereaptobenzothiazole methylene-o-
X
toluidine.
Mereaptobenzothiazole sodium salt
149, X
Mereaptobenzothiazole zinc salt
62, 151, X
Methylene mereaptobenzothiazole ...
149
Methylene-p-toluidine (anhydroform-
62
aldehyde-p-toluidine) .
Piperidine penta methylene dithio-
62, 151
earbamate and potassium salt.
Reaction product, mereaptobenzothia-
zole - formaldehyde - cresylic acid -
hexamethvlenetetramine -- _.
X
Thiocarbanilide
62,149,150
150 .-
404, 838
Thiocarbtoluide.-- ..
Triphenylguanidine __ _
150 ..
Tris-(diphenyldithiocarbamyl methyl)
92
amine.
Urea butyraldehyde aniline
X
Antioxidants, total . .
20, 402, 520
15, 026, 750
$7, 229, 202
$0 48
X .. . ...
Acetaldehyde aniline i..--
p-Aminodiphenyl acetone compound
149
Aniline-acetone -
149
Aniline-acetone, acid derivatives ._ ..
149
Aniline-^-naphthol
62
Antox,.-
62
Crotonvlidine-a-naphthvlamine
92
2,4-Diaminodiphenvlamine
149
/S-Di-p-hydroxy phenvlpropane
60,X
Dimethoxy diphenylamine.
62
Diphenylamine acetone- -
X
Diphenylamine acetone formaldehyde --
X .. -- .
Diphenyl ethvlenediamine
42
s-Di (j3-naphthol) p-phenylenediamine
92
Diphenyl-p-phenylenediamine -
62,92,151
149
1, 281, 841
Diphenyl-p-phenvlenediamine and p-ami-
nodiphenyl acetone compound.
Diphenyl-p-phenylenediamine and aniline
149
acetone, acid derivatives.
Ditolvlamines-
92
Di-o-tolvlethylenediamine -
42 - .-
Di-o-tolylguanidine salt |of dicatechol bo-
62
rate.
p-Hydroxy diphenylamine . - ..
62,92 -
Hydroxyhenyl morpholine
62
Isopropoxy diphenylamine . ---
92
Methylene-di-/3-naphthol _- -_
X
p - Methyl - p - (p - tolylsulfonylamino) di-
X
phenylamine.
50
UNITED STATES TARIFF COIMMISSION
Table 14.- — Synthetic rubbe?- chemicals: United States production and sales in
1940 — Continued
Manufacturers'
identification
numbers
(according to
list on p. 61)
X
Produc-
tion
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Antioxidants — Continued.
Pounds
Pounds
chloride and hydroeenated o-toluidine.
Mono benzvl ether of hvdroquinone . . ..
92
149
62
Phenyl-/3-naphthvlaniine
62, 87, 92
Phenvl-^-naphthvlamine acetone
X
X
Polyethylene iiolvamine plus /9-naphthol
X
Thiophenyl-^-naphthvlamine
X -
2,2,4- Trimethyldihydroquinoline and
92 _.
polymers.
Total coal-tar rubber chemicals - --
37, 139, 394
28. 024, 769
$13, 599, 760
$0.49
62,149 ..
(B) NON-COAL-TAR
Accelerators:
Aldehyde ammonia
92
Diiiethvlaminodimethvldithiocarbamic
149
acid zinc salt.
Dipenta methylene thiouramtetrasulflde.-
Dithiocarbaraates:
62
X
X
62
Lead dimethyl . -.
246
Selenium diethyl
246
246
246
246, X,X
X,X
51, 775
62
62
X
Tetrabu^vlfhiouram monosulfide .
X
246
Tetramethylthiouram sulfide and disulfide^
Triethyltrimetheylenetriamine
Xanthates:
62, 149, 151, X_.
X
567, 517
433, 397
935, 328
2.16
149
Di-n-butylxantho disulfide
X
60, 149
60, X .
60,149
60, X
60
X
60
X, X
16, 915, 139
15, 353, 009
3,747,437
.24
MISCELLANEOUS SYNTHETIC ORGANIC CHEMICALS
Miscellaneous synthetic organic chemicals include all chemicals not
classified under specific groups. Among those derived from coal tar,
the plasticizers are the most important in terms of quantity. In 1939
the production of plasticizers — chiefly phthalates — was 23,839,000
pounds, and in 1940, 28,429,000 pounds. Coal-tar textile chemicals
increased in output from 9,452,000 pounds in 1939 to 13,176,000
pounds in 1940, or 39 percent. The production of all miscellaneous
coal-tar chemicals increased in 1940, as compared with 1939, by
32 percent, but sales increased only about 9 percent. The heter-
ogeneous nature of the products composing these groups makes a
SYNTHETIC ORGANIC CHEMICALS
51
comparison of group totals of little signiiicance, although individual
commodities in the group are comparable.
The non-coal-tar group of miscellaneous chemicals are chiefly sol-
vents, raw materials for the manufacture of chemical products, and
other chemicals used in industry. The output of these chemicals in
1940 was an increase of nearly 1,000,000,000 pounds, or 29.3 percent
above that of 1939, that is, from 2,984,000,000 pounds to 3,858,000,000
pounds. Sales increased proportionately but amounted to less than
50 percent of the production in 1940, the remainder of the output
being used by producers in further processing. Among non-coal-tar
chemicals of this group, acetic acid production increased by 56 percent
in 1940; butyl alcohol, 30 percent; carbon tetrachloride, 11 percent;
formaldehyde, 35 percent; isopropyl alcohol, 23 percent; and sales of
synthetic methanol increased 17 percent.
A large part of the total production of miscellaneous non-coal-tar
products cannot be shown by separate items without disclosing the
operations of individual companies. Among such chemicals produced
m 1940 are camphor, ethylene glycol, tetraethyl lead, some of the
halogen derivatives of aliphatic hydrocarbons, urea, and many other
important industrial chemicals.
Statistics of production and sales of miscellaneous synthetic organic
chemicals are shown in table 15,
Table 1.5. — JMiscellaneous synthetic organic chemicals: United States production
and sales in 1940
[The numbers in the second column refer to the numbered alphabetical list of manufacturers printed on
p. 61 . An X signifies that the manufacturer did not consent to the publication of his identification number
with the desienated product. Blanks in the third, fourth, and fifth columns indicate that the statistics
of production or sales cannot be published without revealing information in regard to individual firms.
The figures thus coacealed, however, are included in the total.]
Manufacturers'
identification
numbers (accord-
ing to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR
Amino diethyl hvdroquinone .. . , .
X
Pounds
Pounds
Benzoate of ammonia
108, 149, X -
Benzoate of soda
38, 42, 62, 108, 149
69
X
Benzylated phenol (Santophens)
149 .
Biological stains and chemical indica-
tors.
Butyl catechol
69, 78, 101, 128, 150,
X,X,X.
149
9,648
8,585
$98,020
$11.42
Cyclanol
62
Cvclohexane.._ . .
22,60,62
Cyclohexanone
22,62
22,62, X
Cyclohexyl phosphite
22
Decahvdronaphthalene (Decalin)
62
DiamvlhvdroQuinone
149 .
X
Diphenvlthiocarbazone
69
Gases (poisonous, tear, etc.), total
91, 633
104, 557
106, 868
1.02
75, X
60,X, X . .
Diphenyl chlorarsine. ._. .._
X
Diphenvlamine chlorarsine
X
62
Insecticides, total _._ _. . _ ... . _._
287, 510
77, 452
.27
Benzyl thiocyanate
108
Phenothiazin ...
60
Xanthone.. ..
89
other
215
52
UNITED STATES TARIFF COMMISSION
Table 15.
-Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Lauryl pyridinium chloride..
108
Pounds
Pounds
Methyl cyclohexane .
22
Methyl cyclohexanol (methyl hexalin) .
22,62,108
22,62,X
25,696
$13, 040
$0 61
Mono methyl hvdroquinone
X
Naphthalene acetic acid _,_
X
Naphthanil red for printing
62
Naphthanil scarlet for printing
62
Nitrosophenyl hydroxylamine (Cup-
69
ferron).
n-Phenyl acetate _. _ _. _ _
78.--
o-Phenyl mercaptobenzothiazole
149-
Phenylmercuric acetate.
96
Phcnylmercuric chloride...
96-
Phloroglucinol .
70 .
Photographic chemicals, total .
i, 747, 445
1,196,508
1,323,002
1.11
p-Aminophenol sulfate
70 .
Benztriazol .
70
Catechol (Pvrocatechin)
70, 149, X
. .. .
Chloro hydroquinone
248
Diaminophenol hydrochloride
237 --..
(Amidol).
38, 62. 69, 237, 248,
X.
62, 69, 70, X ...
1, 288, 647
935, 719
3,003
233, 371
761, 748
8,603
499, 364
.81
p-Hydroxy phenylglycine . .
2.86
Methyl p-aminophenol sulfate
(Metol) (Rhodol).
Phthalonicacid .- . ..
62,69,237,248, X.--
70
330, 952
2.14
Plasticizers, total _. _.
28, 428, 530
21,460,328
4, 543, 433
.21
/3-Chloro-0'-(2-xenoxy) diethyl ether
60
Di (p-tert-hntyl phenyl) mono
60
phenyl phosphate.
Di (p-teH butyl phenyl) mono-
60
(b-tert butyl 2-xenyI) phosphate.
Di (o-chloro phenyl) mono phenyl
60
phosphate.
Di (o-xenyl) mono phenyl phos-
60
phate.
Ethyl ortho-para-toluene sulfona-
149
mide (Santicizer 8).
Isopropyl benzene
60
Phthalates, total.
18, 727, 424
12, 765, 297
2, 532, 705
.20
C.arbitol _
X -.
Castor oil.. ... .. ..
62
Diamvl.-- - .-
120. 230...
Dibutoxy ethyl
62,163
Dibutyl
Dicyclohexyl ...
7, 54, 62, 120, 149,
230.
62
8, 799, 528
5, 506, 098
947. 658
.17
Diethoxy ethyl __. _. .
163
Diethyl
7, -H 120, 149,230, X
62 . -
2, 306, 063
1,869,683
333, 167
.18
Di lorol
Dimethoxv ethyl . .
62,163
Dimethyl
7, 54, 120, 149, 230, X
62 .... .. -- _
Dimethyl cyclohexyl
Diphcnyl... ._.
149..
2-F,thvlhexyl _
163
High boiling alcohols
62
Hydroeenated castor oil
62
Isobutyl.. ... ... ._
62
Lorol butyl ....
62
Mannitan
19
Potas.sium butyl . ._
62 . -
Sodium hutvl
62
Phthaly] slvcollate
149
Toluene sulfonamide ortho-para
149
mixture (Santicizer 9).
Tri tert hntvlphonyl phosphate
60
Tricres\i]ih"ns|)hato .. .
40, 149, 163, X
Triphenvlphosphate... . ..
60, 149, X
Quinhvdrone ........
38,69, 147
Quinone _.. . ... .
248. X
Research chemicals
33,09,78
' Photographic grade only.
SYNTHETIC ORGANIC CHEMICALS
53
Table 15. — Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
dentification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(A) COAL-TAR— continued
Sodium diercsyldithiophosphate
X
Pounds
Pounds
69
7, 22, 45 87, 1'19,
Tetrahy dronaphthalene (Tetralin)
150, X,X.
62 -. — -
149
6,7,41,62,87, 149,
150,215,X,X.
69
13, 175, 777
12, 751, 293
$2, 792, 779
$0.22
Tin sulfurized tri wax phenolate
149
149
X - .
Other - -
148, X
Total miscellaneous coal - tar
chemicals;
Those for which individual
25,910,615
66-112,67.1
21, 333, 448
39,910,970
5, 454, 379
7, 780, 241
.26
statistics are shown.
.19
statistics cannot be shown.
92, 023, 290
61, 244, 418
13, 234. 620
.22
102
(b) non-coal tar
37, 156,X,X
156 .
201, 484, 831
Acetaldol (Aldol)
156
37, 54, 156, 230, X,
X, X.
37 X X
186, 364, 384
Acetic anhydride (from all sources)
(100 percent).
87, 105, X
Acetone - -
37,54,181,205,230.-
147, 156 .-- ---
201, 506, 331
121, 172, 975
5, 571, 188
.05
37 - -
89 108, X
60 X
AUyl alcohol
70.205 -
60.69.70
70 205
AUyl isothiocyanate (synthetic mus-
70 X
238
1,969,441
1,746,288
927, 962
.53
Allyl
70
202
Butyl:
202 -
62
37
Ethyl:
202
Di
202,246
Methyl:
54 62, X
Tri
62 X
X
89 137
X
X
Amyl acetate:
54, 181, 202, 230
81, 122. 160,X,X_.-
202, 230
194, 757
Amyl alcohol:
X
Tertiary (100 percent)
X .
62, 81, X, X
202
202
202 - .
Butadiene
37, 60, 205, X
1 369,085
) 276, 554
98,363
.36
54
UNITED STATES TARIFF COMMISSION
Table 15. — Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Pounds
86,721,057
Pounds
78, 864, 644
74, 457, 452
$5, 903, 842
5, 624, 323
$0.07
37, 54, 78, 149, 181,
230.
205, X
.08
62
.54
Butyl alcohol, total
164, 568, 813
100, 412, 850
61,313,850
54, 434, 432
4, 621, 665
4, 200, 248
.08
37,54,181,230
205, X
.08
Tertiary (100 percent)
205 . - .
37,62
37,X
1,60.69,70,78
60, X
4,205
60
202
54
54
Butyl propionate (100 percent)
81, 230
37, 160, X -
37,X
108
145, 149
9,204
33 . . ..
62
1
Camphor (see Plasticizers).
n-Caproicacid _. ^
37, 137, 160
60. 158, 224, 243, X,
X.
108, 157
100,811,330
79, 674, 547
3, 093, 415
.04
24,60
Chloroacotic acid (mono, di, tri)
60
X
60
Chloroform (tech and USP)
24,32,60,62
47, 147, X--
3, 078, 521
2, 226, 952
415, 560
.19
Citric acid, refined (fermentation)
204
37,156
156
25
137
37,54,149,205
37,54
4,671,512
2, 832, 591
225, 275
.08
124 -
37,60
37
37
124 -
124 .
X
X
37
37
37,202
230 -.
37, 60, 230
Diethyleno glycol diethyl ether..
Diethylcnc glycol dipropionate
Diethylene glycol monobutyl ether
Diethylene glycol monobutyl ether
acetate.
Diethylene glycol monoethyl ether
Diethylene glycol monoethyl ether
acetate.
Diethylene glycol monomethyl ether..
Diethylene oxide (dioxan)
37
163
37
37
37
37
37
37
27, 37
37
X, X
X
X --
Diisobutyl ketone
37--..
SYNTHETIC ORGANIC CHEMICALS
55
'Table 15. — Miscellaneous synthetic organic chemicals: United States production
and salts in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
62
Pounds
Pou nds
62
62
69, X
Dimethyl sulfate
62 - -
Dipropylene glycol
37 - -
Dulcitol - -
19
62, 205 .
78, X
Ethyl acetate (85 percent) - -
37, 54, 62, 81, 149,
181, 230, X, X,
X.
37, 230 ..
75, 368, 803
60, 632, 757
$3, 571, 439
$0.06
37, 62 .. -
Ethyl benzoyl acetate .
230
Ethyl bromide
1, 60
Ethyl bromo acetate
60
Ethyl butyl alcohol
37
37
Ethyl chloride (tech and USP) - -
60, 62, 73, 86
230
Ethyl cvanoacetate
25
Ethylene chlorohydrin
37
Ethylenediamine (med and tech)
27, 37
Ethylene dibromide
60, 72, 243
37, 60 - -
37,60,62, 230, X.--
Ethylene glycol diacetate _ . _.
37
Ethylene glycol diethyl ether
37
Ethylene glycol monobutyl ether
37
163
arate (butoxy ethyl stearate).
Ethylene glycol monoethyl ether
Ethylene glycol monoethyl ether
37
37
acetate.
37
Ethylene glycol monomethyl ether
acetate.
Ethylene glycol monomethyl ether
37
163
oleate (methoxy ethyl oleate).
37
37, 60
Ethyl ether (tech, USP and absolute)
37, 137, 147, 213,
230, X.
54, 79, 81, 137, 160,
230, X, X.
37
Ethyl formate
37 - . . _.
37
o-Ethylhexyl acetate
37
X
Ethyl lactate
X
25 ....
137
Ethyl monochloro acetate
76
Ethyl oleate
122
25 81 230
62, 76, 81, 230, X,
X.
37
Ethyl silicate
Fatty acids (synthetic)
108 . . . -
62
8 carbon atoms) .
1.53 . .
Ferrous lactate
137 204
Formaldehyde (40 percent)-. .. . .
40,62, 104, X
62
180, 884, 573
107, 999, 713
4, 558. 666
.04
Formic acid (90 percent)
62. 238
Fumaric acid
150
Eurfural and derivatives:
185
Furfuryl alcohol
185, X
185 - -
185
Tetrahvdrofurfuryl alcohol
185, X
56
UNITED STATES TARIFF COMMISSION
Table 15. — Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-roAL-TAR— continued
Gallic acid, tech ..
69,137,248
X
Pounds
213,511
Pounds
Gluconic acid Ccriide) ._
Olvcerin chlorohydrin .
X
Glycerin dichlorohydrin
205
Glycerin monochlorohydrin
205
Glyceryl distearate._
122.
Glj'ceryl monomyristate.._ _. _.
122
Glyceryl monostearate
Glyceryl trihvdroxy stearate .
122,215,X,X,X...
62
172, 610
159,973
$40, 155
$0. 25
Glycol bori-borate_..
X
Glycol diformate
37
Glycol stearate. . . .
122, X
Olycolicaeid .._
37
Guanidine nitrate. _
X
Guanvl-nitrosamine-suanyl-tetrazene. .
X
Heptadecanol _. _ _ . _.
37 .. .
Heptane- .._ _. ...
37 ... ...
Hexachloroethane
60
Hexaldehvde.. ..
37
Hexamethylenetetramine, tech..
62,101
Hexvl acetate (sec) . _ .. ..
62 . .
Hexyl alcohol (n and sec)
37
Hexvl ether .. ..
37
Higher alcohols (containing more than
62, X..
■■> carbon atoms;.
Higher ketones .. _
62 .. .
Higher methacrylates (above methyl).
62
Hydrazine hydrate. ...
70
Hydrazine sulfate
70
Hydrocarbons (high boiling)
62
Hydroxy acetic acid ..
62
-
Hydroxyethyl ethylenediamine
37
Hydroxylamine hydrochloride
X
Insecticides ... .
120, 230, X
Isobutyl propionate ... .
62
Isobutyraldehvde ..... ...
62
Isobntyric acid... ..
62
Isophorone .
37 . - .
Isoprene and piperylene
X
Isopropanolaniines .
37
Isopropyl acetate .......
37, X
Isopropyl alcohol (Isopropanol).
37, 205, X
219,925,900
39, 673, 760
1, 563, 541
.04
Isopropyl bromide
60
Isopropyl chloride . .
108
Isopropyl ether . . . . .
37, 205, X
814,449
1, 492, 301
32, 040
309, 324
.04
Lactic acid:
Edible (100 percent).
9,15,48,62,204
.21
Medicinal (100 percent)...
15.62
Technics] (100 percent)
Laurylamine and hydrochloride .. ..
9,15,48,62,204
62
1, 869, 365
1, 671, 237
212, 276
.13
Magnesium lactate... .
204 ...
Malonic acid
X
Mannitan borates . _ .
19 — .
19 ._ ..
Mannitan oleates.. ...
19
Mannitan palmitates.. .. ..
19 ...
Mannitan stearates ..
19..
Mannitol ... . . - ..
19 ... - . .
Melamine
X
. .
Mesityl oxide
37, 54, 205
Methacrylic acid .. ..
62
Methallyl chloride
205
Methanol (synthetic)
37.46,54,62
159, 271, 316
5, 222, 425
.03
Methyl acetate
62, 156, X
37 -
Methylamyl ketone
37
Methyl borate
62
Methyl bromide
60
1-Methyl butyl bromide . . .
1 .
Methylbutyl ketone . .
X
Methyl chloride (chloromethane) (100
percent).
Methyl dichlorostearate
62, 175, 239, X
X
3,041,661
3,123,484
971, 882
.31
Methylethyl ketone
37,206, X.
SYNTHETIC ORGANIC CHEMICALS
57
Table 15. — Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
Methylene chloride (dichloromethane)
24,60,62,239 . .
Pounds
Pounds
(100 percent).
54,62,120
Methvl isobutyl carbinol- -
37 --_.
Methyl isobutyl carbinol acetate
37
Methvl isobutyl ketone -
37, 205
Methvl lactate - .
54 .
Methyl methacrvlate _
62...
X
X
Methyl stearate . ...
108
X
37 .
Monoethanolamine sulfite -.-.__
137
Morpholine - .
37
X
238
62
Organic mercury compound (seed dis-
62, X
infectant).
Oxalic acid . -- . .
89, 164, 238, X
156
12, 921, 227
62,104
X
62
Pentaerythritol -
156
Phorone . . .
37
8, 474, 052
6, 880, 775
$2, 483, 484
$0.36
54,62,X
62,153 . .
230
Dibutyl sebacate -
54,62, X
Dibutyl tartrate -- -
54,62,120,122
X
28,318
26, 976
10,305
.38
X
Methvl cellosolve acetyl ricin-
X
oleate.
Sucrose octa acetate .
156
54
Tributyl citrate
54, X
54,149
Triethyl citrate -
X
Triethylene glycol dihexoate
37
149 ......
Triglvcol dioctoate . .
37
37
37
149 . -
Polypropylene glycol -
37 . .
X
62
62, X
37 X
108
62,78
62
60
37
Propylene diamine
27
60 . .
37,60
37 62
122
Propylene glycol monostearate
122 -
37
Pyrogallic acid (pyrogallol) . .
69,137,248
68, 275
62, 767
95,697
1.52
33,69,200
Rubber (synthetic)
60, 62, 92, X, X
X
70,78
137, 238, X
1.37,204
42
142
Sodium oxal acetate.
230.
58
UNITED STATES TAKIFF COMMISSION
Table 15. — Miscellaneous synthetic organic chemicals: United States production
and sales in 1940 — Continued
Manufacturers'
identification num-
bers (according
to list on p. 61)
Production
Sales
Name of chemical
Quantity
Value
Unit
value
(B) NON-COAL-TAR— continued
89,137,238
Pounds
Pounds
62
19
19
19 __.
19
19
19,X .
122
137
Sulfated fatty alcohols, acids, etc. (gar-
dinols, igepons, intramines, mapros,
xynomines).
37, 45, 62, 87, 191,
215, X.
X
16, 201, 261
14, 782, 253
$4, 021, 390
$0.27
149
hyde ammonia compound.
Tetrabromoethane (acetylene tetra-
bromide).
Tetrachloroethane (acetylene tetra-
chloride).
Tetrachloroethylene (perchloroethyl-
ene).
60,78
62, 243
60,62,243 .
37
Tetraethyl lead
73
37
Tetraethylene glycol dimethyl ether
37 -
37
69
87, 149
62
Trichloroethane (methyl chloroform) . -
60
60,62,243
124
37
37,62
37
X
37
60
60 - -
37
Undecylenic acid
X
62
62
62
Vanillin (see table 12A, p. 42).
156, X
37 92
60 --
62
Xanthates (see table 14B, p. 50).
62 78, X, X
icals.
Total miscellaneous non-coal-tar
chemicals:
Those for which individual
1, 309, 593, 317
2, 547, 947, 435
724, 786, 489
1, 197, 709, 628
39, 837, 512
186,220,459
.05
statistics are shown.
.16
statistics cannot be shown.
3, 857, 540, 752
1, 922, 496, 117
226, 057, 971
.12
APPENDIXES
APPENDIX A.— RESEARCH EXPENDITURES
According to figures reported by the industry, the synthetic organic
chemical industry in 1940 employed 2,692 persons at an average
salary of $2,979, as compared with 2,197 teclniically trained workers
at $3,113 per amium in 1939 and 1,603 such workers at $3,328 per
annum in 1938. The decrease in the average salary is not due to any
reduction in salary scale but to increased employment of less experi-
enced technical workers at lower salaries. The gross cost of research
in 1940 was $17,500,000 and the net cost $16,200,000, which was equal
to 3.3 percent of sales of all organic chemicals in that year.
APPENDIX B.— IMPORTS
The Tariff Commission cooperated with the Department of Com-
merce in 1940, as in previous years, in compiling from original customs
documents import data on coal-tar intermediates and finished coal-tar
products. These statistics are released to subscribers semiannually
by the Department of Commerce in Import Statement No. 2865,
where they are shown in greater detail than in the annual publication
"Foreign Commerce and Navigation of the United States." A sum-
mary of the issue of Import Statement No. 2865 for the years 1938-40
and for 1941 (6 months) is shown in table 16. This summary shows
imports of dutiable coal-tar products, classified according to use. In
1940 imports of intermediates, in terms of quantity, were only
28 percent of the 1939 imports. The large increase in quantity im-
ported during the first 6 months of 1941 and the corresponding drop
in unit value of imports from 96 K cents per pound to 64 cents is largely
due to heavy imports of dinitrotoluene from Canada for further
processing in the United States. The large increase in imports of
other products from 108,876 pounds in 1940 to 1,125,998 pounds
during the first 6 months of 1941 is due principally to imports of
trinitrotoluene from Canada.
59
60
UNITED STATES TARIFF COMMISSION
13
s
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SYNTHETIC ORGANIC CHEMICALS
61
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS IN 1940
[All companies which have given permission to be identified as producers]
Name of company
Office address (location of plant given in parentheses if not
in same city as office)
Abbott Laboratories __.
Advance Paint Co
Alston-Lucas Paint Co
Althouse Chemical Co
Amecco Chemicals, Inc
American Aniline Products, Inc
American Cyanamid Co
American Cyanamid Co., Calco
Chemical Division.
American Maize-Products Co
American Pharmaceutical Co., Inc..
American Tar & Chemical Co
Andrew Brown Co
Ansbacher-Siegle Corporation
Ansul Chemical Co
Apex Chemical Co., Inc
Arco Co -
Arnold. Hoffman & Co., Inc
Aromatic Products, Inc
Atlas Powder Co
Augusta Chemical Co
Bakelite Corporation
Barrett Co
Bates Chemical Co...
Belle Alkali Co
Benzol Products Co..
Berk, F. W., & Co., Inc., Wood
Ridge Division.
Bersworth, F. C, Laboratory
Bick & Co., Inc
Birge Co., Inc
BischolT, Ernst, Co., Inc
Brooklyn Color Works, Inc
Brown Co
Burroughs Wellcome & Co., Inc
Bush, W. J., & Co., Inc
California Flaxseed Products Co
California Ink Co., Inc.
Carbide & Carbon Chemicals Cor-
poration.
Carus Chemical Co., Inc
Catalin Corporation of America
Celluloid Corporation
Chemical Manufacturing Co., Inc
Chemico, Inc
Childs Pulp Colors, Inc
Ciba Pharmaceutical Products, Inc..
Cincinnati Chemical Works, Inc
Cities Service Oil Co
Citro Chemical Co
Clinton Co
Colasta Co., Inc . .
Coleman & Bell Co _.
Collway Colors, Inc.
Colt's Patent Fire Arms Manufac-
turing Co.
Combined Chemical Corporation
Commercial Solvents Corporation...
Commonwealth Color & Chemical
Co.
Cooks Falls Dye Works, Inc
Coopers Creek Chemical Corporation
Crown Tar Works, Division of Pub-
lic Service Co. of Colorado.
Diarsenol Co., Inc
Dow Chemical Co
Dubin, H. E., Laboratories, Inc
du Pont de Nemours, E. I., & Co.,
Inc.
Hth St. and Sheridan Rd., North Chicago, 111.
545 West Abbott St., Indianapolis, Ind.
1031 North Throop St., Chicago, 111.
540 Pear St., Reading, Pa.
75 Rockwood St., Rochester, N. Y.
50 Union Square, New York, N. Y. (Lock Haven, Pa.).
30 Rockefeller Plaza, New York, N. Y. (Bound Brook and
Warner, N. J., Bridgeville, Pa., Maynard, Mass.).
Bound Brook, N. J.
100 East 42d St., New York, N. Y. (Roby, Ind.).
525 West 43d St., New York, N. Y.
5910 Freemont St., Duluth, Minn.
5431 South Riverside Drive, Los Angeles, Calif.
92 Chestnut Ave., Rosebank, S. I., New York, N. Y.
P. O. Box 231, Marinette, Wis.
225 West 34th St., New York, N. Y. (Elizabethport, N. J.).
7301 Bessemer Ave., Cleveland, Ohio.
55 Canal St., Providence, R. I. (Dighton, Mass.).
15 East 30th St., New York, N. Y. (Springdale, Conn.).
Wilmington, Del. (Atlas Point, Del., Stamford, Conn.).
P. O. Box 660, Augusta, Ga.
30 East 42d St., New York, N. Y. (Bloomfleld and Bound
Brook, N. J.).
40 Rector St., New York, N. Y. (Plants throughout United
States).
Scottdale Rd., Lansdowne, Pa.
Belle, W. Va.
237 South St., Newark, N. J. (Piscataway, N. J.).
Wood Ridge, N. J.
609 Waverly St., Framingham, Mass.
1820 North 12th St., Reading, Pa.
390 Niagara St., Buffalo, N. Y.
Main St., Ivoryton, Conn.
Morgan and Norman Aves., Brooklyn, N. Y.
404 Commercial St., Portland, Maine (Berlin, N. H.).
9 East 41st St., New York, N. Y. (Tuckahoe, N. Y.).
11 East 38th St., New York, N. Y. (Linden, N. J.).
3135 East 26th St., Los Angeles, Calif.
545 Sansome St., San Francisco, Calif. (Berkelev, Calif.).
30 East 42d St., New York, N. Y. (South Charleston, W.
Va., Niagara Falls, N. Y., Whiting, Ind.).
1377 8th St., LaSalle, 111.
1 Park Ave., New York, N. Y. (Fords, N. J.).
290 Ferry St., Newark, N. J.
Ashland, Mass.
1745 Front St., Cuyahoga Falls, Ohio (Akron, Ohio).
43 Summit St., Brooklyn, N. Y.
Lafayette Park, Summit, N. J.
P. O. Box 20, Evanston Station, Cincinnati, Ohio (Nor-
wood and St. Bernard, Ohio).
Bartlesville, Okla. (Tallant, Okla.).
Maywood, N. J.
Clinton, Iowa.
1 Mechanic St., Hoosiek Falls, N. Y.
Main and Waverlv Aves., Norwood, Ohio.
15 Market St., Paterson, N. J.
17 Van Dyke Ave., Hartford, Conn.
67 Broad St., New York, N. Y. (Wilmington, Del.).
17 East 42d St., New York, N. Y. (Terre Haute, Ind.,
Peoria, 111., Agnew, Calif.).
223 Nevins St., Brooklyn, N. Y.
70 Pine St., New York, N. Y. (Cooks Falls, N. Y.).
West Conshohocken, Pa.
900 15th St., Denver, Colo.
72 Kingsley St., Buffalo, N. Y.
Midland, Mich. (Pittsburg, Calif.).
250 East 43d St., New York, N. Y.
Wilmington, Del. (Carney's Point, New Brunswick,
Perth Amboy, Arlington, and Newark, N. J., Belle,
W. Va., Waynesboro, Va., Niagara Falls, N. Y., El
Monte, Calif.).
62
UNITED STATES TARIFF COMMISSION
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, IN 1940— Continued
Name of company
Office address (location of plant given in parentheses if not
in same city as office)
Dure?, Plastics & Chemicals, Inc
Durite Plastics, Inc
Dye Specialties Corporation
Dvkem Co
Eakins, J. S. & W. R., Inc
Eastern Tar Products Corporation,..
Eastman Kodak Co
Edwal Laboratories, Inc
Elko Chemical Works, Inc- - _.
Ethyl-Dow Chemical Co -.. ._.
Ethyl Gasoline Corporation...
Federal Color Laboratories, Inc
Federal Laboratories, Inc
Felton Chemical Co., Inc
Fine Colors Co
Fine Orcanics, Inc
Florasynth Laboratories, Inc
Foster, Heaton Co
Franco-American Chemical Works,
Inc.
Fries Bros
Fries, George G., & Co., Inc
Fulton Aniline Corporation..
Gane's Chemical Works, Inc
Gebauer Chemical Co
General Aniline Works, Division of
General Aniline & Film Corpora-
tion.
General Biochemicals, Inc
General Chemical Co
General Electric Co
Glidden Co ..
Goodrich, B. F., Co
Goodyear Tire & Rubber Co
Guyan Color & Chemical Works.
Halowax Corporation
Hamilton Laboratories, Inc
Hampden Color & Chemical Co..
Hardesty, W. C, Co., Inc
Harmon Color Works, Inc
Harris Chemical Co., Inc
Hartman Leddon Co
Hercules Powder Co
Heresite & Chemical Co
Heyden Chemical Corporation.
Hilton-Davis Chemical Co
HotTmann-La Roche, Inc
Holland Aniline Dye Co
Hooker Electrochemical Co
Hussins, James, & Son
Hynson, Westcott & Dunning, Inc...
Imperial Paper & Color Corporation,
Picment Color Division.
Industrial Dvestuff Co
Inland Steel Co
Jamieson, C. E., & Co
Jennison-Wrisht Corporation
Joanite Corporation
Johnson, Charles Eneu, & Co
Jones-Dabney Co., Division of Devoe
& Ravnolds Co.
Kay & Ess Co
Kay-Fries Chemicals, Inc
Kentucky Color & Chemical Co.
Kessler Chemical Co., Inc
Keystone Color Works, Inc
Kinetic Chemicals, Inc
Knoedler, A., Co
Kohnstamra, H., & Co., Inc
Koppers Co., Tar & Chemical Divi-
sion.
LaMotte Chemical Products Co
Lehigh Briquetting Co
Walck Rd., North Tonawanda, N. Y.
5000 Summerdale Ave., Philadelphia, Pa.
924 Bergen Ave., Jersey Citv, N. J.
2301 North 11th St., St. Louis, Mo.
55 Berry St., Brooklyn, N. Y.
Lexington Bldg., Baltimore Md. (Norfolk, Va.).
343 State St., Rochester, N. Y. (Kingsport, Tenn.).
732 Federal St., Chicago, 111.
66 Lister Ave., Newark, N. J.
Wilmington, N. C. (Kure Beach, N. C).
405 Lexington Ave., New York, N. Y. (North Batoa
Rouge, La., Deepwater, N. J.).
4633 Forest Ave., Norwood, Ohio.
185 41st St., Pittsburgh, Pa. (Tunnelton.'Pa.).
599 Johnson Ave., Brooklyn, N. Y.
21-29 McBride Ave., Paterson, N. J.
211 East 19th St., New York, N. Y.
1513-33 Olmstead Ave., New York, N. Y.
8,33-39 Magnolia Ave., Elizabeth, N. J.
Berry Ave., Carlstadt, N. J.
92 Reade St., New York, N. Y. (Bloomfleld, N. J.).
68 Beekman St., New York, N. Y. (Long Island City,.
N. Y.).
10 High St., Boston, Mass. (Woonsocket, R. L).
43 West 16th St., New York, N. Y. (Carlstadt, N. J.).
9410 St. Catherine Ave., Cleveland, Ohio.
435 Hudson St., New York, N. Y. (Rensselaer, N. Y.,
Grasselli, N. J.).
Chagrin Falls, Ohio.
40 Rector St., New York, N. Y. (Claymont,'Del., Buffalo,.
N. Y.).
1 River Rd., Schenectady, N. Y.
11001 Madison Ave., Cleveland, Ohio.
500 South Main St., Akron, Ohio.
1144 East Market St., Akron, Ohio.
P. O. Box 1088, Huntington, W. Va.
30 East 42d St., New York, N. Y. (Wyandotte, Mich.).
601 North B St., Hamilton, Ohio.
161 Armory St., Springfield, Mass.
41 East 42d St., New York, N. Y. (Dover, Ohio, Los
Angeles, Calif.).
P. O . Box 1158, Paterson, N. J. (Haledon, N. J.).
14 Mill St., New Haven, Conn.
6010 Haverford Ave., Philadelphia, Pa.
Delaware Trust Bldg., Wilmington, Del.
822 South 14th St., Manitowoc, Wis.
50 Union Square, New York, N. Y. (Garfield and Perth
Amboy, N. J.).
2235 Langdon Farm Rd., Cincinnati, Ohio.
Kingsland Rd. and Bloomfleld Ave., Nutley, N. J.
Holland, Mich.
Buffalo Ave. and 47th St., Niagara Falls, N. Y.
239 Medford St., Maiden, Mass.
1030 North Charles St., Baltimore, Md.
Glens Falls, N. Y. (Queensbury, N. Y.).
Massasoit Ave., East Providence, R. I.
38 South Dearborn St., Chicago, 111. (Indiana Harbor, Ind.)i
1962-80 Tromblv Ave., Detroit, Mich.
2463 Broadwav, Toledo, Ohio.
10-02 44th Drive, Long Island City, N. Y.
10th and Lombard Sts., Philadelphia, Pa.
1481 South 11th St., Louisville, Ky.
P. O. Box 968, Dayton, Ohio.
180 Madison Ave., New York, N. Y. (West Haverstraw,
N. Y.).
34th St., south of Bank St., Louisville, Ky.
Delaware Ave. and Mifflin St., Philadelphia, Pa.
151 West Gay Ave., York, Pa.
duPont Bldg., Wilmington, Del. (Lower Penns Neck
Township, N. J.).
717 North Prince St., Lancaster, Pa.
87 Park PI., New York, N. Y. (Brooklyn,. N. Y.)
Koppers Bldg., Pittsburgh, Pa. (Plants throughout United
States.)
McCormick Bldg., Baltimore, Md. (Towson, Md.).
Universal Bldg., Fargo, N. Dak. (Dickinson, N. Dak.).
SYNTHETIC ORGANIC CHEMICALS
63
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, IN 1940— Continued
Name of company
Office address (location of plant given in parentheses if not
in same city as office)
Lewis, John D., Inc
Lilly, Eli, & Co
Lucidol Corporation
Lueders, George, & Co., Inc
Macher, Wra., & Son
Magruder Color Co., Inc
Makalot Corporation
Mallinclirodt Chemical Works
Marblette Corporation _
Marietta Dyestulls Co
Marietta Paint & Color Co
Maschmeijer, A., Jr., Inc
Mathieson Alkali Works, Inc..
Marx, Ma.x, Color & Chemical Co...
May, Otto B., Inc
Maywood Chemical Works
Mepham, Geo. S., Corporation
Merck & Co., Inc
M inerec Corporation
Monsanto Chemical Co
National Aniline & Chemical Co.,
Inc.
Naugatuck Chemical Division of
United States Rubber Co.
Neville Co
Newport Industries, Inc
New York Color & Chemical Co.,
Inc., Division of American Dye-
wood Co.
New York Quinine & Chemical
Works, Inc.
Niacet Chemicals Corporation
Niagara Chlorine Products Corpora-
tion.
Niagara Smelting Corporation
Nord & Co., Inc
Northwestern Chemical Co
Novocol Chemical Manufacturing
Co., Inc.
Nubian Paint & Varnish Co
Ohio- Apex, Inc
Oldbury Electro Chemical Co
Parafflne Companies, Inc
Patent Chemicals, Inc
Peerless Color Co
Pennsylvania Coal Products Co
Pennsylvania Industrial Chemical
Corporation.
Pfanstiehl Chemical Co
Pfizer, Chas., & Co., Inc
Pharma Chemical Corporation.
Philadelphia Gas Works Co
PhoenLx Color & Chemical Co
Pittsberg Chemical Co
Pittsburgh Plate Glass Co., Paint
Division.
Plaskon Co., Inc
Portland Gas & Coke Co
Poughkeepsie DyestufiE Corporation..
Premo Pharmaceutical Laboratories,
Inc.
Publicker, Inc
Pure Oil Co
Pylam Products Co., Inc..
Pyridiura Corporation.
Quaker Oats Co
Reichhold Chemicals, Inc
Reilly Tar & Chemical Corporation..
Republic Creosoting Co
Resinous Products & Chemical Co...
Resiston Plastics, Inc
Richards Chemical Works, Inc
68 Traverse St., Providence, R. I. (Mansfield, Mass.).
Indianapolis, Ind.
1740 Military Rd., Buffalo, N. Y.
427 Washington St., New York, N. Y.
1533 West Clearfield St., Philadelphia, Pa.
2385 Richmond Terrace, Port Richmond, Staten Island,
New York, N. Y.
262 Washington St., Boston, Mass. (Waltham, Mass.).
3600 North 2d St., St. Louis, Mo.
37-21 30th St., Long Island City, N. Y.
401-2 Peoples Bank Bldg., Marietta, Ohio.
Greene and Acme Sts., Marietta, Ohio.
43 West 16th St., New York, N. Y. (Newark, N. J.).
60 East 42d St., New York, N. Y. (Niagara Falls, N. Y.,
Lake Charles, La., Saltville, Va.).
192-4 Coit St., Irvington, N. J.
198-214 Niagara St., Newark, N. J.
100 West Hunter Ave., Maywood, N. J.
2001 Lynch Ave., E.ast St. Louis, 111.
Rahway, N. J. (Philadelphia, Pa.).
120 Broadway, New York, N. Y. (Baltimore, Md.).
1700 South 2d St., St. Louis, Mo. (Springfield and Everett,
Mass., Nitro, W. Va., Monsanto, 111., Anniston, Ala.).
40 Rector St., New York, N. Y. (BufTalo, N. Y.).
1230 6th Ave., New York, N. Y. (Naugatuck, Conn.).
Neville Island, Pittsburgh, Pa.
P. O. Box 911, Pensacola, Fla.
Main and Joralemon Sts., Belleville, N. J.
99 North 11th St., Brooklyn, N. Y.
4700 Pine Ave., Niagara Falls, N. Y.
Mill St., Lockport, N. Y.
420 Lexington Ave., New York, N. Y. (Niagara Falls.
N. Y.).
830 Broad St., Newark, N. J.
1263 North 70th St., Wauwatosa, Wis.
2923 Atlantic Ave., Brooklyn, N. Y.
1856 North LeClaire Ave., Chicago, 111.
Nitro, W. Va.
P. O. Box 346, Niagara Falls, N. Y.
475 Brannan St., San Francisco, Calif.
57 Wilkinson Ave., Jersev City, N. J.
521-35 North Ave., Plainfield, N. J.
Petrolia, Pa.
Clairton, Pa.
104 Lakevicw Ave., Waukegan, 111.
81 Maiden Lane, New York, N. Y.
949 Broadwav, New York, N. Y. (Bayonne, N. J.).
1800 North 9th St., Philadelphia, Pa.
24 Van Houten St., Paterson, N. J.
609 South Grand Ave., Los Angeles, Calif. (Vernon, Calif.).
235 East Pittsburgh Ave., Milwaukee, Wis.
2112 Sylvan Ave., Toledo, Ohio.
Public Service Bldg., Portland, Oreg.
77 North Water St., Poughkeepsie, N. Y.
443 Broadway, New York, N. Y.
1800 West Lehigh Ave., Philadelphia, Pa.
35 East Wacker Drive, Chicago, 111. (Heath, Ohio, Cabin
Creek, W. Va.).
799 Greenwich St., New York, N. Y. (Norwalk, Conn.).
21 Gray Oaks Ave., Yonkers, N. Y.
141 West Jackson Blvd., Chicago, 111. (Cedar Rapids,
Iowa.)
601 Woodward Heights Blvd., Detroit, Mich. (Elizabeth,
N. J., Brooklyn, N. Y.).
1615 Merchants Bank Bldg., Indianapolis, Ind. (Plants
throughout United States.)
1615 Merchants Bank Bldg., Indianapolis, Ind. (Plants
throughout United States.)
222 West Washington Square, Philadelphia, Pa.
Delaware Ave. and Elm St., Camden, N. J.
Warren and Morris Sts., Jersey City, N. J.
64
UNITED STATES TARIFF COMMISSION
APPENDIX C— DIRECTORY OF MANUFACTURERS OF SYNTHETIC
ORGANIC CHEMICALS, IN 1940— Continued
Num-
ber
Name of company
Office address (location of plant given in parentheses if not
in same city as office)
192
193
194
195
196
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
240
241
242
243
244
245
246
247
248
Rid-0-Moth Corporation _..
Rohm & Haas Co
Ruberoid Co
Salvo Chemical Corporation
Sobering Corporation
Scheringr & Olatz, Inc.
Seattle Gas Co
Seeley & Co., Inc., Van Brunt
Division.
Sepin Laboratories
Sharp & Dohme, Inc
Sharpies Solvents Corporation,. _
Shawinigan Resins Corporation
Sheffield By-Products Co
Shell Chemical Co
Sherwin-Williams Co
Sidlcy Chemical Co., Inc
Simons, Harold L., Inc
Sinclair i^ Valentine Co
Smith, Kline & French Laboratories..
Solvay Process Co
Southern Dvestufl Corporation
Squibb, E. R., & Sons
Standard Alcohol Co
Standard Chemical Products, Inc
Standard Naphthalene Products Co..
Standard Oil Co. of California
Standard Ultramarine Co
Stange, Wm. J., Co
Stroock & Wittenberg Corporation...
Sun Chemical & Color Co., Division
General Printing Ink Corporation.
Swann & Co
Synthetic Chemicals, Inc
Taylor Chemical Corporation
Tavlor Fibre Co.
Todd, A. M., Co
Truhek Laboratories
Uhlich, Paul, & Co., Inc
United Color <fe Pigment Co., Divi-
sion of Interchemical Corporation.
U. S. Industrial Chemicals, Inc
Valentine & Co., Inc
van Amerineen-Haebler, Inc
Van Dyk &'Co., Inc
Varcum Chemical Corporation
Velsicol Corporation
Verley Chemical Co
Verona Chemical Co
Victor Chemical Works
Virginia Smelting Co
Wannamaker Chemic.al Co., Inc
Warner-Jenkinson Manufacturing Co
Watertown Manufacturing Co..
Westvaco Chlorine Products Cor-
poration.
W-hite Tar Co. of N. J., Inc.-
Wilhelm, A., Co., Division of the
Glidden Co.
Wolff- Alport Chemical Corporation..
Young Aniline Works, Inc
Zinsser & Co., Inc
Jacobus Ave., South Kearny, N. J.
222 West Washington Square, Philadelphia, Pa. (Brides-
burg and Bristol, Pa.).
500 5th Ave., New York, N. Y. (Erie, Pa., Joliet, HI.).
Rothschild, Wis.
86 Orange St., Bloomfield, N. J.
113 West 18th St., New York, N. Y.
1511 4th Ave., Seattle. Wash.
22 Albany St., New York, N. Y. (Farmingdale, N. Y.).
P. O. Box 185, Station A, San Diego, Calif. (Santee, Calif.).
640 North Broad St., Philadelphia, Pa.
23d and Westmoreland Sts., Philadelphia, Pa. (Wyandotte,
Mich.).
644 Monsanto Ave., Springfield, Mass.
524 West 57th St., New York, N. Y. (Hobart, N. Y.).
100 Bush St., San Francisco, Calif. (Martinez and Domin-
guez, Calif.).
101 Prospect Ave., NW., Cleveland, Ohio. (Chicago, 111.).
207 West 25th St., New York, N. Y.
11-25 44th Rd., Long Island Citv, N. Y.
611 West 129th St., New York, N. Y.
105 North 5th St., Philadelphia. Pa.
Syracuse, N. Y. (Geddes, N. Y.).
P. O. Box 1045, Charlotte, N. C. (Sodyeco. N. C).
745 5th Ave., New York, N. Y. (Brooklyn, N. Y., New
Brunswick, N. .!.).
P. O. Box 243, Elizabeth, N. J. (Linden, N. J.).
1301 Jefferson St., Hoboken, N. J.
Jacobus Ave., South Kearnv, N. J.
225 Bush St., San Francisco, Cahf. (Richmond, Calif.).
Huntington, W. Va.
2.'i36 Monroe St., Chicago. 111.
60 East 42d St., New York, N. Y. (Newark, N. J.).
309-21 Sussex St., Harrison, N. J. (East Rutherford, N. J.).
205 South 32d St., Birmingham, Ala.
57 Wilkinson Ave., Jersey Citv, N. J.
Phillipsburg, N. J. (Penn Yan, N. Y., (Wyandotte, Mich.).
Norristown, Pa. (Betzwood, Pa.)
1717 Douglas Ave., Kalamazoo, Mich.
State Highwav No. 2, East Rutherford, N. J.
157 Chambers St., New York, N. Y. (Brooklyn, N. Y.).
Mt. Olivet St., Newark, N. J.
60 East 42d St., New York, N. Y.
11 East 36th St., New York, N. Y. (Brooklyn, N. Y.).
315 4th Ave., New York, N. Y. (Elizabeth, N. J.).
57 Wilkinson Ave., Jersey Citv, N. J.
P. O. Box 433, Niaeara Falls. N. Y.
3542 North Kimball Ave., Chicago, HI. (Marshall, El.).
1621 Carroll Ave.. Chicago, 111.
26 Verona Ave., Newark, N. J.
141 West Jackson Blvd., Chicago, 111. (Chicago Heights
111.)
West Norfolk, Va.
Russell St., Orangeburg, S. C.
2526 Baldwin St., St. Louis, Mo.
127 Echo Lake Rd., Watertown, Conn.
405 Lexington Ave., New York, N. Y. (South
Charleston, W. Va.. Newark, Calif.)
1201 Koppers Bldg., Pittsburgh, Pa. (Kearny, N. J.).
Third and Bern Sts., Reading, Pa.
1127 Irving Ave., Brooklyn, N. Y.
2701-33 Boston St., Baltimore, Md.
Hastings-on-Hudson, N. Y.
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